6002_Mecklenburg_HolbrooksRoad_MSWLF_Feb20GW_FID1395532_20200406

ENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR I I Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Mecklenburg County Solid Waste Services
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Amber R. Grzymski, P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Holbrooks Road Landfill 15401 Holbrooks Road 60-02 .0500 March 10-11, 2020 and
March 19, 2020
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring Q Detection Monitoring Assessment Monitoring Q Corrective Action
e of data submitted: (Check all that apply)
Ix
Groundwater monitoring data from monitoring wells �X Methane gas monitoring data
Groundwater monitoring data from private water supply wells O Corrective action data (specify) HRW-18 MNA sampling
Leachate monitoring data
Surface water monitoring data Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑X Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Amber R. G mski, P.G. Project Manager 980-314-3855
Facilil epresen tive (Print) Title (Area Code) Telephone Number
4/6/2020 Affix NC 0 �e0, IW 6�ssional Geologist Seal
Sigriature Date
o®�O
o®
2145 Suttle Ave, Charlotte, NC 28208 e
Facility Representative Address v > SEAL
0 187T
NC PE Firm License Number (if applicable effective May 1, 2009) 09° gNGE G
Revised 6/2009 °0400e000 5"e°0

v�NBURc O
RTN CAROr
MECKLENBURG COUNTY
Land Use and Environmental Services Agency
Solid Waste Services
April 6, 2020
Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70
Swannanoa, NC 28778
Subject: Holbrooks Road Landfill Permit 60-02
Semi-annual Monitoring and Monitored Natural Attenuation Results
Dear Ms. Drummond:
Mecklenburg County conducted semi-annual water quality monitoring at the closed
Holbrooks Road Landfill March 10-11, 2020 in accordance with the approved sample
and analysis plan dated March 27, 2003. This report details the results of that monitoring
event. Laboratory analytical data, field -measured data table of values exceeding 2L
standards is contained on the electronic data deliverable submittal.
Mecklenburg County Solid Waste requested permission to use HydraSleeve samplers for
this sampling event for the monitoring wells that do not have dedicated bladder pumps.
HydraSleeve samplers were used in the following monitoring wells: HRW-8, HRW-9R,
HRW-10, HRW-I IR, HRW-13, HRW-16.
Samples were collected from eleven (11) monitoring wells (HRW-7, HRW-8, HRW-9R,
HRW-10, HRW-I IR, HRW-13, HRW-16, HRW- 18. HRW-19, HRW-20 and HRW-21)
and three (3) surface -water sampling locations (HRSW-2, HRSW-3 and HRSW-4).
Samples were analyzed for metals and volatile organic compounds ("VOCs") listed in
Appendix I of 40 CFR Part 258.54 "Detection monitoring program". Samples were also
analyzed for 1,4-Dioxane as required as of July 1, 2018. Field measurements of
temperature, pH, and specific conductivity were made at each sampling location using a
calibrated instrument. Additionally, measurements of dissolved oxygen were made at
each surface -water sampling location.
Samples f'or the Corrective Action Plan (CAP), approved November 9, 2018, were
collected from HRW-18 on March 10, 2020. The parameters collected include: Nitrate,
Iron, Sulfate, Sulfide, BOD, COD, Ethane/Ethene, ORP, Volatile Fatty Acids, Hydrogen,
CO2, Chloride, Alkalinity and TOC. The field parameters collected include Dissolved
Oxygen, pH, Temperature and Specific Conductivity. These samples were collected to
satisfy the monitored natural attenuation portion of the approved CAP.
PEOPLE -PRIDE - PROGRESS - PARTNERSHIP
2145 Suttle Ave • Charlotte, North Carolina 28208 • [phone] Fax [phone]
www.wipeoutwaste.com

Page 2
The electronic data deliverable package containing the monitoring data is labeled to
reflect the units used for reporting. Surface water standards listed are the water quality
standards established for freshwater classification for aquatic life as outlined in 15A
NCAC 2B "Classification and Water Quality Standards Applicable to Surface Waters of
North Carolina". Groundwater standards listed are the standards outlined in 15A NCAC
2L "Classification of Water Quality Standards applicable to the Groundwaters of North
Carolina". If the sample is reported in parts per billion, then the standard is also reported
in parts per billion.
Surface -water samples:
Barium was detected in all 3 stream sampling locations. The following table summarizes
the metals detections for the surface water sampling locations.
Sample Location
Barium
u /1
HRSW-2 upstream
32.8
HRSW-4 mid -stream
33.0
HRSW-3 downstream
36.4
No VOCs were detected in any of the samples collected from the three surface -water
sampling locations (HRSW-2, HRSW-4 and HRSW-3). All field -measured parameters
were within the established regulatory limits. The following table summarizes field -
measured parameters for surface water samples.
Sample Location
Temp.
°C
pH
S.U.
Specific Conductivity
ms/cm
Dissolved Oxygen
mg/1
HRSW-2 upstream
14.1
7.2
0.217
11.23
HRSW4 mid -stream
13.7
7.1
0.216
12.26
HRSW-3 downstream
12.5
6.9
0.236
11.05
Groundwater samples:
Vanadium, cobalt and cadmium were detected in various wells above the 21 standard.
The following table summarizes metals detection for groundwater samples.

Page 3
Well ID
As
ug/l
Ba
ug/1
Be
ug/1
Cd
ug/1
Cr
ug/1
Co
ug/l
Cu
ug/1
Pb
ug/l
Ni
ug/l
Se
ug/1
Vn
ug/l
Zn
ug/1
HRW-7
-----
105
-----
6.4
-----
-----
8.0
-----
-----
-----
-----
24.7
HRW-8
-----
56.9
-----
-----
5.2
-----
8.3
-----
-----
-----
15.4
-----
HRW-9R
-----
328
-----
-----
-----
5.2
6.2
-----
-----
-----
-----
-----
HRW-10
-----
117
-----
-----
-----
-----
5.6
-----
9.5
-----
-----
-----
HRW-11R
-----
418
-----
-----
-----
5.8
8.7
-----
45.2
-----
-----
-----
HRW-13
------
31.4
-----
-----
5.3
-----
7.6
-----
-----
-----
6.5
-----
HRW-16 -----
110
-----
-----
-----
-----
-----
-----
-----
-----
7.1
-----
HRW-18
-----
351
-----
-----
-----
-----
----- -----
11.4
-----
-----
-----
HRW-19
-----
85.6
-----
-----
-----
-----
----- -----
-----
-----
-----
-----
HRW-20
-----
112
-----
-----
-----
-----
-----
-----
-----
-----
6.7
-----
HRW-21
-----
66.8
-----
-----
-----
-----
-----
-----
-----
-----
5.1
-----
2L Std.
10
700
4
1 2
10
1
1,000
15
100
20
0.3
1,000
Note: Results shown in bold
exceed
the 21, standard.
VOCs were detected in six monitoring wells; HRW-7, HRW-9R, HRW-10, HRW-11R,
HRW-18 and HRW-20. The following table summarizes VOC detections.
Well ID
Volatile Constituent
Concentration
2L Standard
u /1
(ug/1)
Cis-1,2-Dichloroethene
1.5
70
HRW-7
Trichloroethene
2.1
3
HRW-9R
Acetone
41.5
6000
2-Butanone (MEK)
20.5
4000
Chlorobenzene
2.4
50
Chloroethane
1.8
3000
1,2-Dichlorobenzene
5.1
20
1,4-Dichlorobenzene
7.6
6
1,1-Dichloroethane
34.7
6
1,2-Dichloroethane
2.3
0.4
Cis-1,2-Dichloroethane
54
70
1,2-Dichloropropane
3.0
0.6
Trichloroethene
1.5
3
Vinyl Chloride
7.2
0.03
1,4-Dioxane
11.2
3
HRW-10
1,4-Dioxane
6.5
6.2
3
HRW-11R
Chlorobenzene
50
Chloroethane
1.3
3000
1,4-Dichlorobenzene
1.3
6
1,4-Dioxane
135
3

• , •
Well ID
Volatile Constituent
Concentration
u /1
2L Standard
(u /1
Benzene
3.0
1
HRW-18
Chlorobenzene
4.9
50
1,1-Dichloroethane
2994
6
1,2-Dichloroethane
1.1
0.4
cis-1,2-Dichloroethane
L6
70
1,2-Dichloropropane
497
0.6
1,4 Dichlorobenzene
6.9
6
Trichloroethane
1.3
3
Trichlorofluoromethane
3.1
2000
Vinyl Chloride
14.1
0.03
1,4-Dioxane
10.7
3
HRW-20
1,1-Dichloroethane
6.8
6
Note: Results shown in bold exceed the 2L standard.
Monitoring well HRW-18 was sampled for the monitored natural attenuation parameters
required by the Corrective Action Plan approved November 9, 2018. The table below
shows the results of the additional sampling:
MNA Parameter
Concentration
Ethane
<40 u /1
Ethene
<40 u /1
Methane
36700 u /1
Iron
2320 u /1
Alkalinity
823 mg/1
Sulfide
< 0.10 m /l
BOD
<2.0 m /l
Oxidation/Reduction Potential
78.3 mV
Chloride EPA300.0
32.9 m /l
Nitrate as N
< 0.10 mg/1
Sulfate
17.2 mg/1
Chloride SM4500
36.7 m /l
COD
<25.0 mg/1
TOC
5.4 in /1
Dissolved Oxygen
1.92 mg/1
H
6A SU
Specific Conductance
1.476 ms/cm
Carbon Dioxide
310 mg/1
Hydrogen
4.5 nM
Lactic Acid
<0.20 mg/1
Acetic Acid
0.28 mg/1
Pro ionic Acid
0.15 m /l
Formic Acid
<0.50 mg/1
Butyric Acid
0.062 m /l J*
P ruvic Acid
<0.10 mg/1
i-Pentanoic Acid
<0.10 mg/1
Pentanoic Acid
0.071 mg/1 J*
i-Hexanoic Acid
<0.20 mg/1
Hexanoic Acid
<0.20 mg/1

Page 5
* J Value — Estimated Concentration
The values for the Monitoring Natural Attenuation (MNA) Parameters indicate that
natural attenuation through anerobic digestion is occurring in the area of HRW-18. The
MNA parameters will be collected again in 3 years and additional analysis will be
conducted at that time.
Measurements of pH were more acidic than the 2L standard range %J 6.5 to 8.5 standard
units at HRW-7, HRW-8, HRW4 1 R, HRW4 3, HRW4 6, HRW4 8, HRW4 9, HRW-20
and HRW-21. Field- measured parameters for groundwater samples are summarized in
the following table.
Sample Location
UM.Specific
Conductivity ms/cm
HRW-7
17.6
5.8
0.364
HRW4
13.2
6.0
0.049
HRW-9R
16.0
6.6
1.104
HRW-10
14.3
6.7
0.656
HRW41 R
14.3
6.2
1.022
HRW-13
13.0
6.3
0.119
HRW-16
13.8
5.6
0.123
HRW-18
16A
6.4
1.476
HRW-19
15.0
6.3
0.337
HRW-20
15.1
6.0
0.357
HRW-21
14.9
6.2
0.469
Note: Results shown in bold are outside of the 2L standard range of 6.5 - 8.5 S.U.
Please call me at [phone] if you have any questions regarding this report.
Sincerely,
R. Grzymski,
Project Manager
Solid Waste Services

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leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 23, 2020
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 10, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 28

lacieAnalyfical'f'
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Huntersville, NC 28078
[phone]
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
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REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
HOLBROOKS RD LF PERMIT#60-02
92468925
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92468925001
HRW 7
EPA 601OD
SH1
15
PASI-A
EPA 6020
AMS
1
PASI-O
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92468925002
HRW 19
EPA 601OD
SH1
15
PASI-A
EPA 6020
AMS
1
PASI-O
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92468925003
HRW20
EPA 601OD
SH1
15
PASI-A
EPA 6020
AMS
1
PASI-O
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92468925004
HRW21
EPA 601OD
SH1
15
PASI-A
EPA 6020
AMS
1
PASI-O
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92468925005
TRIP BLANK
EPA 8260D
CL
52
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 28

leAnalyiical
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9800 Kincey Ave. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 7 Lab ID: 92468925001 Collected: 03/10/20 11:15 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:21
7440-38-2
Barium
105
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:21
7440-41-7
Cadmium
6.4
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:21
7440-43-9
Chromium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-48-4
Copper
8.0
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-50-8
Lead
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7439-92-1
Nickel
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-02-0
Selenium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:21
7782-49-2
Silver
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-22-4
Thallium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:21
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:21
7440-62-2
Zinc
24.7
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:21
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010
Thallium
ND
ug/L
1.0
1
03/16/2011:41 03/22/2018:45
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 00:40
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 00:40
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 00:40
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 00:40
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 00:40
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 00:40
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 00:40
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 00:40
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 00:40
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 00:40
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 00:40
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 00:40
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 00:40
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 00:40
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 00:40
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 00:40
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 00:40
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 00:40
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:40
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:40
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 00:40
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:40
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:40
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:40
75-35-4
cis-1,2-Dichloroethene
1.5
ug/L
1.0
1
03/21/20 00:40
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:40
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 7 Lab ID: 92468925001 Collected: 03/10/20 11:15 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 00:40
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:40
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:40
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 00:40
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 00:40
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 00:40
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 00:40
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 00:40
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 00:40
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:40
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:40
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 00:40
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 00:40
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:40
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:40
79-00-5
Trichloroethene
2.1
ug/L
1.0
1
03/21/20 00:40
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 00:40
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 00:40
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 00:40
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 00:40
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 00:40
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 00:40
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 00:40
95-47-6
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
03/21/20 00:40
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
03/21/20 00:40
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
03/21/20 00:40
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/11/20 19:33
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
97
%
50-150
1
03/11/20 19:33
17060-07-0
Toluene-d8 (S)
99
%
50-150
1
03/11/20 19:33
2037-26-5
Date: 03/23/2020 04:11 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 19 Lab ID: 92468925002 Collected: 03/10/20 10:25 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:24
7440-38-2
Barium
85.6
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:24
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:24
7440-43-9
Chromium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-48-4
Copper
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-50-8
Lead
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7439-92-1
Nickel
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-02-0
Selenium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:24
7782-49-2
Silver
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-22-4
Thallium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:24
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:24
7440-62-2
Zinc
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:24
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010
Thallium
ND
ug/L
1.0
1
03/16/2011:41 03/22/2018:47
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 00:57
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 00:57
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 00:57
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 00:57
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 00:57
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 00:57
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 00:57
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 00:57
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 00:57
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 00:57
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 00:57
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 00:57
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 00:57
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 00:57
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 00:57
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 00:57
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 00:57
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 00:57
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:57
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:57
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 00:57
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:57
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:57
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:57
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:57
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:57
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 19 Lab ID: 92468925002 Collected: 03/10/20 10:25 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 00:57
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:57
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:57
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 00:57
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 00:57
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 00:57
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 00:57
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 00:57
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 00:57
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:57
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:57
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 00:57
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 00:57
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:57
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:57
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 00:57
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 00:57
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 00:57
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 00:57
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 00:57
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 00:57
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 00:57
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 00:57
95-47-6
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
03/21/20 00:57
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
03/21/20 00:57
17060-07-0
Toluene-d8(S)
102
%
70-130
1
03/21/20 00:57
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/11/20 19:54
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
97
%
50-150
1
03/11/20 19:54
17060-07-0
Toluene-d8 (S)
98
%
50-150
1
03/11/20 19:54
2037-26-5
Date: 03/23/2020 04:11 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 20 Lab ID: 92468925003 Collected: 03/10/20 10:45 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:27
7440-38-2
Barium
112
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:27
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:27
7440-43-9
Chromium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-48-4
Copper
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-50-8
Lead
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7439-92-1
Nickel
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-02-0
Selenium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:27
7782-49-2
Silver
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-22-4
Thallium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:27
7440-28-0
Vanadium
6.7
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:27
7440-62-2
Zinc
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:27
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010
Thallium
ND
ug/L
1.0
1
03/16/2011:41 03/22/2018:50
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 01:14
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 01:14
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 01:14
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 01:14
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 01:14
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 01:14
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 01:14
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 01:14
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 01:14
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 01:14
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 01:14
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 01:14
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 01:14
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 01:14
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 01:14
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 01:14
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 01:14
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 01:14
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:14
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:14
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 01:14
110-57-6
1,1-Dichloroethane
6.8
ug/L
1.0
1
03/21/20 01:14
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 01:14
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:14
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:14
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:14
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 20 Lab ID: 92468925003 Collected: 03/10/20 10:45 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 01:14
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 01:14
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 01:14
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 01:14
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 01:14
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 01:14
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 01:14
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 01:14
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 01:14
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 01:14
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 01:14
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 01:14
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 01:14
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 01:14
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 01:14
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 01:14
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 01:14
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 01:14
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 01:14
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 01:14
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 01:14
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 01:14
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 01:14
95-47-6
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
03/21/20 01:14
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
03/21/20 01:14
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
03/21/20 01:14
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/11/20 20:13
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
100
%
50-150
1
03/11/20 20:13
17060-07-0
Toluene-d8 (S)
101
%
50-150
1
03/11/20 20:13
2037-26-5
Date: 03/23/2020 04:11 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 21 Lab ID: 92468925004 Collected: 03/10/20 10:05 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:30
7440-38-2
Barium
66.8
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:30
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/17/20 01:27
03/19/20 19:30
7440-43-9
Chromium
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-48-4
Copper
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-50-8
Lead
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7439-92-1
Nickel
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-02-0
Selenium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:30
7782-49-2
Silver
ND
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-22-4
Thallium
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:30
7440-28-0
Vanadium
5.1
ug/L
5.0
1
03/17/20 01:27
03/19/20 19:30
7440-62-2
Zinc
ND
ug/L
10.0
1
03/17/20 01:27
03/19/20 19:30
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020 Preparation Method: EPA 3010
Thallium
ND
ug/L
1.0
1
03/16/2011:41 03/22/2018:53
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 01:32
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 01:32
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 01:32
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 01:32
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 01:32
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 01:32
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 01:32
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 01:32
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 01:32
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 01:32
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 01:32
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 01:32
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 01:32
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 01:32
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 01:32
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 01:32
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 01:32
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 01:32
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:32
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:32
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 01:32
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 01:32
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 01:32
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:32
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:32
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:32
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: HRW 21 Lab ID: 92468925004 Collected: 03/10/20 10:05 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
m&p-Xylene
o-Xylene
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 03/23/2020 04:11 PM
Analytical Method: EPA 8260D
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
ND
ug/L
102 %
98 %
99 %
Analytical Method: EPA 8260D Mod
ND ug/L
100 %
97 %
1.0
1
03/21/20 01:32
78-87-5
1.0
1
03/21/20 01:32
10061-01-5
1.0
1
03/21/20 01:32
10061-02-6
1.0
1
03/21/20 01:32
100-41-4
5.0
1
03/21/20 01:32
591-78-6
20.0
1
03/21/20 01:32
74-88-4
5.0
1
03/21/20 01:32
75-09-2
5.0
1
03/21/20 01:32
108-10-1
1.0
1
03/21/20 01:32
100-42-5
1.0
1
03/21/20 01:32
630-20-6
1.0
1
03/21/20 01:32
79-34-5
1.0
1
03/21/20 01:32
127-18-4
1.0
1
03/21/20 01:32
108-88-3
1.0
1
03/21/20 01:32
71-55-6
1.0
1
03/21/20 01:32
79-00-5
1.0
1
03/21/20 01:32
79-01-6
1.0
1
03/21/20 01:32
75-69-4
1.0
1
03/21/20 01:32
96-18-4
2.0
1
03/21/20 01:32
108-05-4
1.0
1
03/21/20 01:32
75-01-4
1.0
1
03/21/20 01:32
1330-20-7
2.0
1
03/21/20 01:32
179601-23-1
1.0
1
03/21/20 01:32
95-47-6
70-130 1
70-130 1
70-130 1
2.0 1
50-150 1
50-150 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
03/21/20 01:32 460-00-4
03/21/20 01:32 17060-07-0
03/21/20 01:32 2037-26-5
03/11/20 21:13 123-91-1
03/11/20 21:13 17060-07-0
03/11/20 21:13 2037-26-5
Page 11 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: TRIP BLANK Lab ID: 92468925005 Collected: 03/10/20 09:30 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
Acetone
ND
ug/L
25.0
1
03/20/20 23:48
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/20/20 23:48
107-13-1
Benzene
ND
ug/L
1.0
1
03/20/20 23:48
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/20/20 23:48
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/20/20 23:48
75-27-4
Bromoform
ND
ug/L
1.0
1
03/20/20 23:48
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/20/20 23:48
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/20/20 23:48
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/20/20 23:48
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/20/20 23:48
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/20/20 23:48
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/20/20 23:48
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/20/20 23:48
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/20/20 23:48
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/20/20 23:48
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/20/20 23:48
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/20/20 23:48
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/20/20 23:48
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/20/20 23:48
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/20/20 23:48
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/20/20 23:48
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/20/20 23:48
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/20/20 23:48
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/20/20 23:48
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/20/20 23:48
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/20/20 23:48
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
1
03/20/20 23:48
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/20/20 23:48
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/20/20 23:48
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/20/20 23:48
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/20/20 23:48
591-78-6
lodomethane
ND
ug/L
20.0
1
03/20/20 23:48
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/20/20 23:48
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/20/20 23:48
108-10-1
Styrene
ND
ug/L
1.0
1
03/20/20 23:48
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/20/20 23:48
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/20/20 23:48
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/20/20 23:48
127-18-4
Toluene
ND
ug/L
1.0
1
03/20/20 23:48
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/20/20 23:48
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/20/20 23:48
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/20/20 23:48
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/20/20 23:48
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/20/20 23:48
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/20/20 23:48
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/20/20 23:48
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/20/20 23:48
1330-20-7
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM
without
the written consent
of Pace Analytical Services, LLC.
Page 12 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
Sample: TRIP BLANK
Lab ID: 92468925005 Collected: 03/10/20 09:30
Received: 03/10/20 15:11 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
m&p-Xylene
ND ug/L
2.0
1
03/20/20 23:48
179601-23-1
o-Xylene
ND ug/L
1.0
1
03/20/20 23:48
95-47-6
Surrogates
4-Bromofluorobenzene (S)
100 %
70-130
1
03/20/20 23:48
460-00-4
1,2-Dichloroethane-d4 (S)
97 %
70-130
1
03/20/20 23:48
17060-07-0
Toluene-d8 (S)
99 %
70-130
1
03/20/20 23:48
2037-26-5
Date: 03/23/2020 04:11 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 28

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QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
QC Batch: 530802 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92468925001, 92468925002, 92468925003, 92468925004
METHOD BLANK: 2834381 Matrix: Water
Associated Lab Samples: 92468925001, 92468925002, 92468925003, 92468925004
Blank Reporting
Parameter Units Result Limit
Analyzed
Antimony
ug/L
ND
5.0
03/19/2018:37
Arsenic
ug/L
ND
10.0
03/19/2018:37
Barium
ug/L
ND
5.0
03/19/2018:37
Beryllium
ug/L
ND
1.0
03/19/2018:37
Cadmium
ug/L
ND
1.0
03/19/2018:37
Chromium
ug/L
ND
5.0
03/19/2018:37
Cobalt
ug/L
ND
5.0
03/19/2018:37
Copper
ug/L
ND
5.0
03/19/2018:37
Lead
ug/L
ND
5.0
03/19/2018:37
Nickel
ug/L
ND
5.0
03/19/2018:37
Selenium
ug/L
ND
10.0
03/19/2018:37
Silver
ug/L
ND
5.0
03/19/2018:37
Thallium
ug/L
ND
10.0
03/19/2018:37
Vanadium
ug/L
ND
5.0
03/19/2018:37
Zinc
ug/L
ND
10.0
03/19/2018:37
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2834382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
516
103
80-120
Arsenic
ug/L
500
489
98
80-120
Barium
ug/L
500
506
101
80-120
Beryllium
ug/L
500
510
102
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
518
104
80-120
Lead
ug/L
500
509
102
80-120
Nickel
ug/L
500
504
101
80-120
Selenium
ug/L
500
508
102
80-120
Silver
ug/L
250
247
99
80-120
Thallium
ug/L
500
491
98
80-120
Vanadium
ug/L
500
504
101
80-120
Zinc
ug/L
500
488
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 28

leAnalyiical
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9800 Kincey Ave. Suite 100
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QUALITY CONTROL DATA
Project:
Pace Project No.:
HOLBROOKS RD LF PERMIT#60-02
92468925
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2834383
2834384
MS
MSD
92468589001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
519
106
104
75-125
2
Arsenic
ug/L
ND
500
500
500
493
100
98
75-125
2
Barium
ug/L
17.8
500
500
530
518
102
100
75-125
2
Beryllium
ug/L
ND
500
500
519
506
104
101
75-125
3
Cadmium
ug/L
0.70J
500
500
524
513
105
102
75-125
2
Chromium
ug/L
ND
500
500
520
509
104
102
75-125
2
Cobalt
ug/L
ND
500
500
512
502
102
100
75-125
2
Copper
ug/L
ND
500
500
521
509
104
102
75-125
2
Lead
ug/L
ND
500
500
516
506
103
101
75-125
2
Nickel
ug/L
ND
500
500
514
505
103
101
75-125
2
Selenium
ug/L
ND
500
500
537
529
107
106
75-125
2
Silver
ug/L
ND
250
250
257
253
103
101
75-125
1
Thallium
ug/L
ND
500
500
479
472
95
94
75-125
1
Vanadium
ug/L
ND
500
500
514
499
103
100
75-125
3
Zinc
ug/L
ND
500
500
513
506
102
101
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
QC Batch: 618152
Analysis Method: EPA 6020
QC Batch Method: EPA 3010
Analysis Description: 6020 MET
Associated Lab Samples: 92468925001, 92468925002,
92468925003, 92468925004
METHOD BLANK: 3359830
Matrix: Water
Associated Lab Samples: 92468925001, 92468925002,
92468925003, 92468925004
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Thallium ug/L
ND 1.0
03/22/20 20:48
LABORATORY CONTROL SAMPLE: 3359831
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Thallium ug/L
50 51.4
103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3359832 3359833
MS MSD
35537215001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Thallium ug/L 0.11 U
50 50 50.7
50.8 101 102 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
QC Batch: 531753 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92468925001, 92468925002, 92468925003, 92468925004, 92468925005
METHOD BLANK: 2839240 Matrix: Water
Associated Lab Samples: 92468925001, 92468925002, 92468925003, 92468925004, 92468925005
Blank Reporting
Parameter Units Result Limit Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,1-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
1,2,3-Trichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
03/20/20 23:30
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,4-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
2-Butanone (MEK)
ug/L
ND
5.0
03/20/20 23:30
2-Hexanone
ug/L
ND
5.0
03/20/20 23:30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/20/20 23:30
Acetone
ug/L
ND
25.0
03/20/20 23:30
Acrylonitrile
ug/L
ND
10.0
03/20/20 23:30
Benzene
ug/L
ND
1.0
03/20/20 23:30
Bromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromodichloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromoform
ug/L
ND
1.0
03/20/20 23:30
Bromomethane
ug/L
ND
2.0
03/20/20 23:30
Carbon disulfide
ug/L
ND
2.0
03/20/20 23:30
Carbon tetrachloride
ug/L
ND
1.0
03/20/20 23:30
Chlorobenzene
ug/L
ND
1.0
03/20/20 23:30
Chloroethane
ug/L
ND
1.0
03/20/20 23:30
Chloroform
ug/L
ND
5.0
03/20/20 23:30
Chloromethane
ug/L
ND
1.0
03/20/20 23:30
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
Dibromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Dibromomethane
ug/L
ND
1.0
03/20/20 23:30
Ethylbenzene
ug/L
ND
1.0
03/20/20 23:30
lodomethane
ug/L
ND
20.0
03/20/20 23:30
m&p-Xylene
ug/L
ND
2.0
03/20/20 23:30
Methylene Chloride
ug/L
ND
5.0
03/20/20 23:30
o-Xylene
ug/L
ND
1.0
03/20/20 23:30
Styrene
ug/L
ND
1.0
03/20/20 23:30
Tetrachloroethene
ug/L
ND
1.0
03/20/20 23:30
Toluene
ug/L
ND
1.0
03/20/20 23:30
Qualifiers
v2
IK
IH
IK,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
METHOD BLANK: 2839240 Matrix: Water
Associated Lab Samples: 92468925001, 92468925002, 92468925003, 92468925004, 92468925005
Blank Reporting
Parameter Units Result Limit Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/20/20 23:30
Trichloroethene
ug/L
ND
1.0
03/20/20 23:30
Trichlorofluoromethane
ug/L
ND
1.0
03/20/20 23:30
Vinyl acetate
ug/L
ND
2.0
03/20/20 23:30
Vinyl chloride
ug/L
ND
1.0
03/20/20 23:30
Xylene (Total)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane-d4 (S)
%
97
70-130
03/20/20 23:30
4-Bromofluorobenzene (S)
%
100
70-130
03/20/20 23:30
Toluene-d8 (S)
%
99
70-130
03/20/20 23:30
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
55.4
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.9
98
70-130
1,1,2-Trichloroethane
ug/L
50
58.1
116
70-130
1,1-Dichloroethane
ug/L
50
55.5
111
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
46.1
92
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.0
94
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.9
102
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
51.5
103
70-130
1,2-Dichloropropane
ug/L
50
54.9
110
70-130
1,4-Dichlorobenzene
ug/L
50
49.1
98
70-130
2-Butanone (MEK)
ug/L
100
102
102
64-135
2-Hexanone
ug/L
100
91.1
91
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
96.6
97
61-157
Acrylonitrile
ug/L
250
270
108
61-143
Benzene
ug/L
50
53.5
107
70-130
Bromochloromethane
ug/L
50
61.0
122
70-130
Bromodichloromethane
ug/L
50
56.0
112
70-130 v1
Bromoform
ug/L
50
50.6
101
70-130lK
Bromomethane
ug/L
50
57.6
115
38-130lH
Carbon disulfide
ug/L
50
63.0
126
68-130
Carbon tetrachloride
ug/L
50
57.0
114
70-130
Chlorobenzene
ug/L
50
50.5
101
70-130
Chloroethane
ug/L
50
52.9
106
37-142 IK,v1
Chloroform
ug/L
50
56.6
113
70-130
Chloromethane
ug/L
50
43.3
87
48-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
LABORATORY CONTROL SAMPLE:
2839241
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
cis-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.4
117
70-130
Dibromochloromethane
ug/L
50
58.9
118
70-130
Dibromomethane
ug/L
50
59.3
119
70-130
Ethylbenzene
ug/L
50
48.6
97
70-130
lodomethane
ug/L
100
105
105
40-130
m&p-Xylene
ug/L
100
96.7
97
70-130
Methylene Chloride
ug/L
50
50.8
102
67-132
o-Xylene
ug/L
50
49.3
99
70-131
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
51.5
103
69-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.2
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
59.2
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
53.8
108
35-189
Trichloroethene
ug/L
50
54.3
109
70-130
Trichlorofluoromethane
ug/L
50
54.5
109
63-130
Vinyl acetate
ug/L
100
115
115
55-143
Vinyl chloride
ug/L
50
60.7
121
70-131
Xylene (Total)
ug/L
150
146
97
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.7
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
19.1
96
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.3
101
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-135
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-139
1,1-Dichloroethene
ug/L
ND
20
16.1
80
70-154
1,2,3-Trichloropropane
ug/L
ND
20
19.2
96
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.7
93
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.7
103
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.2
101
70-133
1,2-Dichloroethane
ug/L
ND
20
18.2
91
70-137
1,2-Dichloropropene
ug/L
ND
20
20.8
104
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.7
103
70-133
2-Butanone (MEK)
ug/L
ND
40
35.6
89
60-139
2-Hexanone
ug/L
ND
40
39.0
97
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.0
93
65-135
Acetone
ug/L
ND
40
34.1
85
60-148
Acrylonitrile
ug/L
ND
100
89.4
89
64-147
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Benzene
ug/L
ND
20
20.0
100
70-151
Bromochloromethane
ug/L
ND
20
21.4
107
70-141 v1
Bromodichloromethane
ug/L
ND
20
20.3
101
70-138
Bromoform
ug/L
ND
20
17.6
88
63-1301K
Bromomethane
ug/L
ND
20
12.1
61
15-152 IH,v3
Carbon disulfide
ug/L
ND
20
16.1
80
69-149 v1
Carbon tetrachloride
ug/L
ND
20
21.6
108
70-143
Chlorobenzene
ug/L
ND
20
21.9
109
70-138
Chloroethane
ug/L
ND
20
15.0
75
52-1631K
Chloroform
ug/L
ND
20
20.0
100
70-139
Chloromethane
ug/L
ND
20
5.3
26
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
19.0
95
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.1
100
70-137
Dibromochloromethane
ug/L
ND
20
22.1
110
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.0
105
66-153
Iodomethane
ug/L
ND
40
24.1
60
20-138
m&p-Xylene
ug/L
ND
40
41.9
105
69-152
Methylene Chloride
ug/L
ND
20
16.6
83
42-159
o-Xylene
ug/L
ND
20
21.2
106
70-148
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
20.8
104
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
18.2
91
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
14.7
73
47-135
Trichloroethene
ug/L
ND
20
20.3
101
70-147
Trichlorofluoromethane
ug/L
ND
20
14.8
74
70-148
Vinyl acetate
ug/L
ND
40
36.0
90
49-151
Vinyl chloride
ug/L
ND
20
10.6
53
70-156 M1
Xylene (Total)
ug/L
ND
60
63.0
105
63-158
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2839242
92469069002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
34.7
30.9
12
1,1-Dichloroethene
ug/L
ND
ND
1,2,3-Trichloropropane
ug/L
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 28

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
5.1
5.3
1,2-Dichloroethane
ug/L
2.3
2.0
1,2-Dichloropropane
ug/L
3.0
2.9
1,4-Dichlorobenzene
ug/L
7.6
7.5
2-Butanone (MEK)
ug/L
20.5
17.9
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
41.5
35.4
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
.84J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
2.4
2.5
Chloroethane
ug/L
1.8
1.5
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
54.0
47.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
.67J
Toluene
ug/L
ND
.52J
trans-1,2-Dichloroethene
ug/L
ND
.79J
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
1.5
1.5
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
7.2
6.3
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
92
4-Bromofluorobenzene (S)
%
100
99
Toluene-d8(S)
%
100
97
RPD Qualifiers
3
13
2
1
14
16
v1
IK
I K,v2
v1
4
17 IK
13
0
13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
QC Batch: 529802 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92468925001, 92468925002
METHOD BLANK: 2829610
Associated Lab Samples: 92468925001, 92468925002
Parameter Units
1,4-Dioxane (p-Dioxane) ug/L
1,2-Dichloroethane-d4 (S) %
Toluene-d8 (S) %
Matrix: Water
Blank Reporting
Result Limit
Analyzed
ND 2.0
03/11/2012:20
97 50-150
03/11/2012:20
97 50-150
03/11/2012:20
Qualifiers
LABORATORY CONTROL SAMPLE: 2829611
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.9 105 70-130
1,2-Dichloroethane-d4 (S) % 98 50-150
Toluene-d8(S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2829612
2829613
MS
MSD
92468253001 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 23.0
24.3 108
115
50-150 5
1,2-Dichloroethane-d4 (S)
%
96
96
50-150
Toluene-d8(S)
%
98
100
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
QC Batch: 529805 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92468925003, 92468925004
METHOD BLANK: 2829617
Associated Lab Samples: 92468925003, 92468925004
Parameter Units
1,4-Dioxane (p-Dioxane) ug/L
1,2-Dichloroethane-d4 (S) %
Toluene-d8 (S) %
Matrix: Water
Blank Reporting
Result Limit
Analyzed
ND 2.0
03/11/2012:40
98 50-150
03/11/2012:40
97 50-150
03/11/2012:40
Qualifiers
LABORATORY CONTROL SAMPLE: 2829618
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 21.9 109 70-130
1,2-Dichloroethane-d4 (S) % 95 50-150
Toluene-d8(S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2829619
2829620
MS
MSD
92468925003 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 21.4
21.2 105
104
50-150 1
1,2-Dichloroethane-d4 (S)
%
95
97
50-150
Toluene-d8(S)
%
98
99
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 28

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: HOLBROOKS RD LF PERMIT#60-02
Pace Project No.: 92468925
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-O Pace Analytical Services - Ormond Beach
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
HOLBROOKS RD LF PERMIT#60-02
92468925
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92468925001
HRW 7
EPA 3010A
530802
EPA 6010D
530823
92468925002
HRW 19
EPA 3010A
530802
EPA 6010D
530823
92468925003
HRW 20
EPA 3010A
530802
EPA 6010D
530823
92468925004
HRW 21
EPA 3010A
530802
EPA 6010D
530823
92468925001
HRW 7
EPA 3010
618152
EPA 6020
618287
92468925002
HRW 19
EPA 3010
618152
EPA 6020
618287
92468925003
HRW 20
EPA 3010
618152
EPA 6020
618287
92468925004
HRW 21
EPA 3010
618152
EPA 6020
618287
92468925001
HRW 7
EPA 8260D
531753
92468925002
HRW 19
EPA 8260D
531753
92468925003
HRW 20
EPA 8260D
531753
92468925004
HRW 21
EPA 8260D
531753
92468925005
TRIP BLANK
EPA 8260D
531753
92468925001
HRW 7
EPA 8260D Mod.
529802
92468925002
HRW 19
EPA 8260D Mod.
529802
92468925003
HRW 20
EPA 8260D Mod.
529805
92468925004
HRW 21
EPA 8260D Mod.
529805
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/23/2020 04:11 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 28

aceAnalytica!
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑
Sample Condition- tiient Name:
„Upon Receipt
_ Mel: k lnnbu r� (U �n
Courier: []Fed Ex Flips ❑LISPS
❑ Commercial [pace ❑Other:
Custody Seal Present? ❑Yes [2No Seals Intact? []Yes
Huntersville ❑ Raleigh[] Mechanicsville❑
❑Client 1111111llllllllllllll
92468925
oNa -Zo A M P
Date/Initials Person Examining Contents:
Packing Material: []Bubble Wrap [Bubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: ❑Yes ❑No []N/A❑IR Gun 10: 92T060 Type of Ice: QUVet []Blue ❑None
Cooler Temp ('Q: Correction Factor: Add/Subtract ('C) Q(}
Temp should be above freezing to 6°C
Cooler Temp Corrected ( ❑Samples out of temp criteria. Samples on ice, cooling process
hasbegun
USDA Regulated Soil (aN/A, water sample)
Did samples orlginate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate From a foreign source (internationally,
ii,.__ f'l— ineludlra Hawaii and Puarrn Rlrn)? l^IYes FlNo
Comments/Dlscrepancy:
`Chain of Custody Present? ,' ''
Ores
❑No
❑N/A
1.
Samples Arrived within Hold Time?
QYes
❑No
❑N/A
2.
iShortHold Time Analysis (<72'Kr.)?
❑Yes
EfNo
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
[2No
[]N/A
4,
Sufficient Volume? ! -
Oyes
[]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
['[Yes
DYes
[:]No
(—]No
❑N/A
❑N/A
6.
Containers Intact?
[yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
[N/A
8.
Sample Labels Match COC?
[1yes
❑No
❑N/A
9.
v
-Includes Date/Time/ID/Analysis Matrix:
�v
Headspace in VOA Vials (>5-6mm)?
❑Yes
nNo
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[Yes
[]Yes
[:]No
ffNo
❑N/A
N/A
11.
COMMENTS/SAMPLE DISCREPANCY field Data Required? []Yes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RMLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date;
Project Manager 5RF Review: Date:
Page 26 of 28

y
.�acekalyftal
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
F•CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box Is to list number of bottle
Project# Wo## : 92468925
Due Date: 03/24/20
CLIENT: 92-MECK CO
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pH Adjustment Log for Preserved Samples
Sample iD
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Nate: Whenever there is a discrepancy affecting North Carollna compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Cut of hold, Incorrect preservative, out of temp, incorrect containers.
Page 27 of 28

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Page 28 of 28

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 27, 2020
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 25

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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Holbrooks Road Landfill
92469065
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92469065001
HRW 10
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469065002
HRW 11R
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469065003
HRW 13
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469065004
Trip Blank
EPA 8260D
CL
52
PASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 3 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 10 Lab ID: 92469065001 Collected: 03/11/20 11:00 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:03
7440-38-2
Barium
117
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:03
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:03
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-48-4
Copper
5.6
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7439-92-1
Nickel
9.5
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:03
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:03
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:03
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:03
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:41
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 02:41
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 02:41
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 02:41
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 02:41
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 02:41
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 02:41
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 02:41
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 02:41
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 02:41
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 02:41
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 02:41
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 02:41
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 02:41
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 02:41
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 02:41
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 02:41
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 02:41
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 02:41
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:41
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:41
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 02:41
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:41
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:41
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:41
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:41
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:41
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 25

leAnalyiical
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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 10 Lab ID: 92469065001 Collected: 03/11/20 11:00 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 02:41
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:41
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:41
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 02:41
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 02:41
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 02:41
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 02:41
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 02:41
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 02:41
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:41
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:41
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 02:41
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 02:41
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:41
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:41
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 02:41
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 02:41
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 02:41
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 02:41
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 02:41
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 02:41
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 02:41
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 02:41
95-47-6
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
03/21/20 02:41
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
03/21/20 02:41
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
03/21/20 02:41
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
6.5
ug/L
2.0
1
03/13/20 18:53
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
50-150
1
03/13/20 18:53
17060-07-0
Toluene-d8 (S)
99
%
50-150
1
03/13/20 18:53
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 11R Lab ID: 92469065002 Collected: 03/11/20 09:30 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:06
7440-38-2
Barium
418
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:06
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:06
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-47-3
Cobalt
5.8
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-48-4
Copper
8.7
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7439-92-1
Nickel
45.2
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:06
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:06
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:06
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:06
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:46
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 02:58
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 02:58
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 02:58
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 02:58
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 02:58
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 02:58
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 02:58
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 02:58
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 02:58
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 02:58
56-23-5
Chlorobenzene
6.2
ug/L
1.0
1
03/21/20 02:58
108-90-7
Chloroethane
1.3
ug/L
1.0
1
03/21/20 02:58
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 02:58
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 02:58
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 02:58
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 02:58
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 02:58
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 02:58
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:58
95-50-1
1,4-Dichlorobenzene
1.3
ug/L
1.0
1
03/21/20 02:58
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 02:58
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:58
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:58
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:58
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:58
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:58
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 11R Lab ID: 92469065002 Collected: 03/11/20 09:30 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 02:58
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:58
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:58
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 02:58
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 02:58
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 02:58
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 02:58
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 02:58
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 02:58
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:58
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:58
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 02:58
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 02:58
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:58
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:58
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 02:58
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 02:58
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 02:58
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 02:58
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 02:58
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 02:58
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 02:58
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 02:58
95-47-6
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
03/21/20 02:58
460-00-4
1,2-Dichloroethane-d4 (S)
95
%
70-130
1
03/21/20 02:58
17060-07-0
Toluene-d8(S)
101
%
70-130
1
03/21/20 02:58
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
135
ug/L
5.0
2.5
03/13/20 22:29
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
2.5
03/13/20 22:29
17060-07-0
Toluene-d8 (S)
96
%
50-150
2.5
03/13/20 22:29
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 13 Lab ID: 92469065003 Collected: 03/11/20 10:10 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:15
7440-38-2
Barium
31.4
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:15
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:15
7440-43-9
Chromium
5.3
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-48-4
Copper
7.6
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:15
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:15
7440-28-0
Vanadium
6.5
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:15
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:15
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:55
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 03:16
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 03:16
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 03:16
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 03:16
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 03:16
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 03:16
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 03:16
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 03:16
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 03:16
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 03:16
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 03:16
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 03:16
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 03:16
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 03:16
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 03:16
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 03:16
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 03:16
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 03:16
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 03:16
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 03:16
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 03:16
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 03:16
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 03:16
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:16
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:16
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:16
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: HRW 13 Lab ID: 92469065003 Collected: 03/11/20 10:10 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 03:16
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:16
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:16
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 03:16
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 03:16
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 03:16
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 03:16
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 03:16
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 03:16
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:16
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:16
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 03:16
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 03:16
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:16
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:16
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 03:16
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 03:16
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 03:16
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 03:16
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 03:16
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 03:16
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 03:16
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 03:16
95-47-6
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
03/21/20 03:16
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
03/21/20 03:16
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
03/21/20 03:16
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 19:13
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
1
03/13/20 19:13
17060-07-0
Toluene-d8 (S)
97
%
50-150
1
03/13/20 19:13
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: Trip Blank Lab ID: 92469065004 Collected: 03/11/20 09:07 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 00:05
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 00:05
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 00:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 00:05
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 00:05
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 00:05
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 00:05
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 00:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 00:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 00:05
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 00:05
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 00:05
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 00:05
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 00:05
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 00:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 00:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 00:05
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 00:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:05
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 00:05
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 00:05
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:05
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:05
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:05
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 00:05
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:05
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:05
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 00:05
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 00:05
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 00:05
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 00:05
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 00:05
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 00:05
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:05
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:05
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 00:05
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 00:05
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:05
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:05
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 00:05
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 00:05
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 00:05
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 00:05
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 00:05
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 00:05
1330-20-7
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM
without
the written consent
of Pace Analytical Services, LLC.
Page 10 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
Sample: Trip Blank
Lab ID: 92469065004 Collected: 03/11/20 09:07
Received: 03/11/20 14:24 Matrix: Water
Parameters
Results Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
m&p-Xylene
ND ug/L
2.0
1
03/21/20 00:05
179601-23-1
o-Xylene
ND ug/L
1.0
1
03/21/20 00:05
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99 %
70-130
1
03/21/20 00:05
460-00-4
1,2-Dichloroethane-d4 (S)
96 %
70-130
1
03/21/20 00:05
17060-07-0
Toluene-d8 (S)
101 %
70-130
1
03/21/20 00:05
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
QC Batch: 531025 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92469065001, 92469065002, 92469065003
METHOD BLANK: 2835486 Matrix: Water
Associated Lab Samples: 92469065001, 92469065002, 92469065003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
1.0
03/19/20 22:19
1.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2835487
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
475
95
80-120
Arsenic
ug/L
500
469
94
80-120
Barium
ug/L
500
483
97
80-120
Beryllium
ug/L
500
493
99
80-120
Cadmium
ug/L
500
481
96
80-120
Chromium
ug/L
500
478
96
80-120
Cobalt
ug/L
500
475
95
80-120
Copper
ug/L
500
472
94
80-120
Lead
ug/L
500
478
96
80-120
Nickel
ug/L
500
482
96
80-120
Selenium
ug/L
500
464
93
80-120
Silver
ug/L
250
242
97
80-120
Thallium
ug/L
500
458
92
80-120
Vanadium
ug/L
500
468
94
80-120
Zinc
ug/L
500
488
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Holbrooks Road Landfill
92469065
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2835488
2835489
MS
MSD
92468969001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
518
508
104
101
75-125
2
Arsenic
ug/L
ND
500
500
517
508
103
102
75-125
2
Barium
ug/L
8.1
500
500
514
507
101
100
75-125
1
Beryllium
ug/L
ND
500
500
517
510
103
102
75-125
1
Cadmium
ug/L
ND
500
500
522
510
104
102
75-125
2
Chromium
ug/L
19.1
500
500
519
512
100
98
75-125
1
Cobalt
ug/L
ND
500
500
490
480
98
96
75-125
2
Copper
ug/L
ND
500
500
511
504
101
100
75-125
1
Lead
ug/L
ND
500
500
494
484
99
97
75-125
2
Nickel
ug/L
ND
500
500
502
492
100
98
75-125
2
Selenium
ug/L
ND
500
500
519
512
103
102
75-125
1
Silver
ug/L
ND
250
250
262
258
105
103
75-125
1
Thallium
ug/L
ND
500
500
440
425
88
85
75-125
4
Vanadium
ug/L
ND
500
500
493
488
98
97
75-125
1
Zinc
ug/L
0.015
500
500
527
517
102
100
75-125
2
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
QC Batch: 531033
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92469065001, 92469065002,
92469065003
METHOD BLANK: 2835502
Matrix: Water
Associated Lab Samples: 92469065001, 92469065002,
92469065003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Thallium ug/L
ND 0.10
03/26/2013:02
LABORATORY CONTROL SAMPLE: 2835503
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Thallium ug/L
10 10.1
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835504 2835505
MS MSD
35535316001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Thallium ug/L 0.060U
10 10 10.1
10.1 101 101 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
QC Batch: 531753 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92469065001, 92469065002, 92469065003, 92469065004
METHOD BLANK: 2839240 Matrix: Water
Associated Lab Samples: 92469065001, 92469065002, 92469065003, 92469065004
Blank Reporting
Parameter Units Result Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,1-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
1,2,3-Trichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
03/20/20 23:30
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,4-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
2-Butanone (MEK)
ug/L
ND
5.0
03/20/20 23:30
2-Hexanone
ug/L
ND
5.0
03/20/20 23:30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/20/20 23:30
Acetone
ug/L
ND
25.0
03/20/20 23:30
Acrylonitrile
ug/L
ND
10.0
03/20/20 23:30
Benzene
ug/L
ND
1.0
03/20/20 23:30
Bromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromodichloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromoform
ug/L
ND
1.0
03/20/20 23:30
Bromomethane
ug/L
ND
2.0
03/20/20 23:30
Carbon disulfide
ug/L
ND
2.0
03/20/20 23:30
Carbon tetrachloride
ug/L
ND
1.0
03/20/20 23:30
Chlorobenzene
ug/L
ND
1.0
03/20/20 23:30
Chloroethane
ug/L
ND
1.0
03/20/20 23:30
Chloroform
ug/L
ND
5.0
03/20/20 23:30
Chloromethane
ug/L
ND
1.0
03/20/20 23:30
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
Dibromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Dibromomethane
ug/L
ND
1.0
03/20/20 23:30
Ethylbenzene
ug/L
ND
1.0
03/20/20 23:30
lodomethane
ug/L
ND
20.0
03/20/20 23:30
m&p-Xylene
ug/L
ND
2.0
03/20/20 23:30
Methylene Chloride
ug/L
ND
5.0
03/20/20 23:30
o-Xylene
ug/L
ND
1.0
03/20/20 23:30
Styrene
ug/L
ND
1.0
03/20/20 23:30
Tetrachloroethene
ug/L
ND
1.0
03/20/20 23:30
Toluene
ug/L
ND
1.0
03/20/20 23:30
Qualifiers
v2
IK
IH
IK,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
METHOD BLANK: 2839240 Matrix: Water
Associated Lab Samples: 92469065001, 92469065002, 92469065003, 92469065004
Blank Reporting
Parameter Units Result Limit
Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/20/20 23:30
Trichloroethene
ug/L
ND
1.0
03/20/20 23:30
Trichlorofluoromethane
ug/L
ND
1.0
03/20/20 23:30
Vinyl acetate
ug/L
ND
2.0
03/20/20 23:30
Vinyl chloride
ug/L
ND
1.0
03/20/20 23:30
Xylene (Total)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane-d4 (S)
%
97
70-130
03/20/20 23:30
4-Bromofluorobenzene (S)
%
100
70-130
03/20/20 23:30
Toluene-d8 (S)
%
99
70-130
03/20/20 23:30
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
55.4
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.9
98
70-130
1,1,2-Trichloroethane
ug/L
50
58.1
116
70-130
1,1-Dichloroethane
ug/L
50
55.5
111
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
46.1
92
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.0
94
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.9
102
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
51.5
103
70-130
1,2-Dichloropropane
ug/L
50
54.9
110
70-130
1,4-Dichlorobenzene
ug/L
50
49.1
98
70-130
2-Butanone (MEK)
ug/L
100
102
102
64-135
2-Hexanone
ug/L
100
91.1
91
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
96.6
97
61-157
Acrylonitrile
ug/L
250
270
108
61-143
Benzene
ug/L
50
53.5
107
70-130
Bromochloromethane
ug/L
50
61.0
122
70-130
Bromodichloromethane
ug/L
50
56.0
112
70-130 v1
Bromoform
ug/L
50
50.6
101
70-130lK
Bromomethane
ug/L
50
57.6
115
38-130lH
Carbon disulfide
ug/L
50
63.0
126
68-130
Carbon tetrachloride
ug/L
50
57.0
114
70-130
Chlorobenzene
ug/L
50
50.5
101
70-130
Chloroethane
ug/L
50
52.9
106
37-142 IK,v1
Chloroform
ug/L
50
56.6
113
70-130
Chloromethane
ug/L
50
43.3
87
48-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
LABORATORY CONTROL SAMPLE:
2839241
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
cis-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.4
117
70-130
Dibromochloromethane
ug/L
50
58.9
118
70-130
Dibromomethane
ug/L
50
59.3
119
70-130
Ethylbenzene
ug/L
50
48.6
97
70-130
lodomethane
ug/L
100
105
105
40-130
m&p-Xylene
ug/L
100
96.7
97
70-130
Methylene Chloride
ug/L
50
50.8
102
67-132
o-Xylene
ug/L
50
49.3
99
70-131
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
51.5
103
69-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.2
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
59.2
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
53.8
108
35-189
Trichloroethene
ug/L
50
54.3
109
70-130
Trichlorofluoromethane
ug/L
50
54.5
109
63-130
Vinyl acetate
ug/L
100
115
115
55-143
Vinyl chloride
ug/L
50
60.7
121
70-131
Xylene (Total)
ug/L
150
146
97
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.7
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
19.1
96
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.3
101
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-135
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-139
1,1-Dichloroethene
ug/L
ND
20
16.1
80
70-154
1,2,3-Trichloropropane
ug/L
ND
20
19.2
96
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.7
93
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.7
103
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.2
101
70-133
1,2-Dichloroethane
ug/L
ND
20
18.2
91
70-137
1,2-Dichloropropene
ug/L
ND
20
20.8
104
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.7
103
70-133
2-Butanone (MEK)
ug/L
ND
40
35.6
89
60-139
2-Hexanone
ug/L
ND
40
39.0
97
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.0
93
65-135
Acetone
ug/L
ND
40
34.1
85
60-148
Acrylonitrile
ug/L
ND
100
89.4
89
64-147
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Benzene
ug/L
ND
20
20.0
100
70-151
Bromochloromethane
ug/L
ND
20
21.4
107
70-141 v1
Bromodichloromethane
ug/L
ND
20
20.3
101
70-138
Bromoform
ug/L
ND
20
17.6
88
63-1301K
Bromomethane
ug/L
ND
20
12.1
61
15-152 IH,v3
Carbon disulfide
ug/L
ND
20
16.1
80
69-149 v1
Carbon tetrachloride
ug/L
ND
20
21.6
108
70-143
Chlorobenzene
ug/L
ND
20
21.9
109
70-138
Chloroethane
ug/L
ND
20
15.0
75
52-1631K
Chloroform
ug/L
ND
20
20.0
100
70-139
Chloromethane
ug/L
ND
20
5.3
26
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
19.0
95
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.1
100
70-137
Dibromochloromethane
ug/L
ND
20
22.1
110
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.0
105
66-153
Iodomethane
ug/L
ND
40
24.1
60
20-138
m&p-Xylene
ug/L
ND
40
41.9
105
69-152
Methylene Chloride
ug/L
ND
20
16.6
83
42-159
o-Xylene
ug/L
ND
20
21.2
106
70-148
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
20.8
104
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
18.2
91
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
14.7
73
47-135
Trichloroethene
ug/L
ND
20
20.3
101
70-147
Trichlorofluoromethane
ug/L
ND
20
14.8
74
70-148
Vinyl acetate
ug/L
ND
40
36.0
90
49-151
Vinyl chloride
ug/L
ND
20
10.6
53
70-156 M1
Xylene (Total)
ug/L
ND
60
63.0
105
63-158
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2839242
92469069002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
34.7
30.9
12
1,1-Dichloroethene
ug/L
ND
ND
1,2,3-Trichloropropane
ug/L
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 25

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
5.1
5.3
1,2-Dichloroethane
ug/L
2.3
2.0
1,2-Dichloropropane
ug/L
3.0
2.9
1,4-Dichlorobenzene
ug/L
7.6
7.5
2-Butanone (MEK)
ug/L
20.5
17.9
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
41.5
35.4
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
.84J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
2.4
2.5
Chloroethane
ug/L
1.8
1.5
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
54.0
47.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
.67J
Toluene
ug/L
ND
.52J
trans-1,2-Dichloroethene
ug/L
ND
.79J
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
1.5
1.5
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
7.2
6.3
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
92
4-Bromofluorobenzene (S)
%
100
99
Toluene-d8(S)
%
100
97
RPD Qualifiers
3
13
2
1
14
16
v1
IK
I K,v2
v1
4
17 IK
13
0
13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
QC Batch: 530451 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92469065001, 92469065002, 92469065003
METHOD BLANK: 2832866
Matrix:
Water
Associated Lab Samples:
92469065001, 92469065002, 92469065003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
03/13/20 15:38
1,2-Dichloroethane-d4 (S)
%
97
50-150
03/13/20 15:38
Toluene-d8 (S)
%
98
50-150
03/13/20 15:38
LABORATORY CONTROL SAMPLE: 2832867
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 21.0 105 70-130
1,2-Dichloroethane-d4 (S) % 90 50-150
Toluene-d8(S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832868
2832869
MS
MSD
92468855001 Spike
Spike MS MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 191 80
80 269 274 97
103
50-150 2
1,2-Dichloroethane-d4 (S)
%
93
96
50-150
Toluene-d8(S)
%
99
100
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 25

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Holbrooks Road Landfill
Pace Project No.: 92469065
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 25

leAnalyiical
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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Holbrooks Road Landfill
92469065
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92469065001
HRW 10
EPA 3010A
531025
EPA 6010D
531052
92469065002
HRW 11 R
EPA 3010A
531025
EPA 6010D
531052
92469065003
HRW 13
EPA 3010A
531025
EPA 6010D
531052
92469065001
HRW 10
EPA 3010A
531033
EPA 6020B
531056
92469065002
HRW 11 R
EPA 3010A
531033
EPA 6020B
531056
92469065003
HRW 13
EPA 3010A
531033
EPA 6020B
531056
92469065001
HRW 10
EPA 8260D
531753
92469065002
HRW 11 R
EPA 8260D
531753
92469065003
HRW 13
EPA 8260D
531753
92469065004
Trip Blank
EPA 8260D
531753
92469065001
HRW 10
EPA 8260D Mod.
530451
92469065002
HRW 11 R
EPA 8260D Mod.
530451
92469065003
HRW 13
EPA 8260D Mod.
530451
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 22 of 25

ace Analytical �— - - _- - -----
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2016
Page 1 of 2
---
— - I stung_Authvtity:-----
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood
° Client Nance:
Courier: ❑Fed Ex
❑ Commercial d;ace
Custody Seal Present? Des
Huntersville Er Raleigh[] Mechanicsville❑
PFeject WO#:92469065
[]Client 1111111111111111111111
92469065
AmpDate/initials Person Examining Contents: ` � L —ZU iA m p
Packing Material: ❑Bubble Wrap ❑Bubble Bags QNone ❑ Other Biological Tissue Frozen?
Thermometer. Type of Ice: �Ivet []Blue ❑None ENS ❑No EN/A
❑IR Gun !D: 92TO60
Cooler Tern ('C): Correction Factor: Add/Subtract (°C) 0.0
` Temp should be above freezing to 6°C
Cooler Temp Corrected {°C}: ` (-]samples out of temp criteria. samples on ice, cooling process
has begun
USDA Regulated Soil (Er N/Al water sample)
Did samples bHginatie In a quarantine zone within the united States: CA, NY, or SC (check maps)? Did samples originate from a foreign source lintemationally,
nYpc hlNn Includlne Hawaii and Puerto Riral? l-IYes r
�4cJr t-USG Wi.���
❑UPS EIUSPS
❑Other:
QNo Seats Intact? []Yes
Comments/Discrepancy;
�haill of CusWb Pres' 01
QYes
❑No
❑N/A
I.
Samples Arrived within Hold Time?
[34es
❑No
❑N/A
2.
°Short Hold Time Analysis (QYlir.]7
[]Yes
E3 o
❑N/A
3.
Rush Turn Around Time'Requested?
❑Yes
[3la
❑N/A
4.
'Sufficient Volume?❑Yes
❑No
❑NIA
S.
Correct Containers Used?
-Pace Containers Used?
[3fes
(]4es
❑No
❑No
❑N/A
❑N/A
6.
Containers Intact?
©'res
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
ONO
ON/A
S.
Sample Labels Match COC?
[/]Yes
[]No
❑NIA
4.
Includes Date/Time/ID/Analysts Matrix:
Headspace in VOA Vials (>S-6mm)?
❑Yes
{INO
❑N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
❑Yes
[-]No
QNo
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑yes -]No
Lot In of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
Date:
Page 23 of 25

Document Name:
Document Revised: February 7, 2018
a
Sample Condition Upon Receipt(5CUR)
Page 1 of 2
Document No.:
Issuing Authority:
aceAnaiytical
F-CAR-CS-033-Rev.06 i
Pace Carolinas Quality Office
*Check marls top half of box if pal and/or dechlorination is Project # F W�# . 92469065
verified and within the.acceptance range for preservation
samples. Rm : MWB Due Date: 03�,25/20
EMcepttons: VOA, Coiiform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: 92—MECK CO
**Bottom half of box is to list number of bottle
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservatlon adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot M
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina t7EHNR Certification Office [i.e.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 24 of 25

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Page 25 of 25

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 27, 2020
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Holbrooks Road Landfill
92469069
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92469069001
HRW 8
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469069002
HRW 9R
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469069003
HRW 16
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 3 of 23

leAnalyiical
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 8 Lab ID: 92469069001 Collected: 03/11/20 12:35 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:18
7440-38-2
Barium
56.9
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:18
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:18
7440-43-9
Chromium
5.2
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-48-4
Copper
8.3
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:18
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:18
7440-28-0
Vanadium
15.4
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:18
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:18
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 15:19
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 03:33
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 03:33
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 03:33
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 03:33
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 03:33
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 03:33
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 03:33
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 03:33
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 03:33
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 03:33
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 03:33
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 03:33
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 03:33
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 03:33
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 03:33
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 03:33
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 03:33
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 03:33
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 03:33
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 03:33
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 03:33
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 03:33
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 03:33
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:33
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:33
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:33
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 8 Lab ID: 92469069001 Collected: 03/11/20 12:35 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 03:33
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:33
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:33
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 03:33
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 03:33
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 03:33
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 03:33
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 03:33
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 03:33
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:33
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:33
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 03:33
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 03:33
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:33
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:33
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 03:33
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 03:33
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 03:33
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 03:33
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 03:33
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 03:33
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 03:33
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 03:33
95-47-6
Surrogates
4-Bromofluorobenzene (S)
101
%
70-130
1
03/21/20 03:33
460-00-4
1,2-Dichloroethane-d4 (S)
94
%
70-130
1
03/21/20 03:33
17060-07-0
Toluene-d8 (S)
101
%
70-130
1
03/21/20 03:33
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 19:32
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
1
03/13/20 19:32
17060-07-0
Toluene-d8 (S)
97
%
50-150
1
03/13/20 19:32
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 9R Lab ID: 92469069002 Collected: 03/11/20 12:50 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:21
7440-38-2
Barium
328
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:21
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:21
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-47-3
Cobalt
5.2
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-48-4
Copper
6.2
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:21
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:21
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:21
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:21
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 15:24
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
41.5
ug/L
25.0
1
03/21/20 03:50
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 03:50
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 03:50
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 03:50
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 03:50
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 03:50
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 03:50
74-83-9
IH,v2
2-Butanone (MEK)
20.5
ug/L
5.0
1
03/21/20 03:50
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 03:50
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 03:50
56-23-5
Chlorobenzene
2.4
ug/L
1.0
1
03/21/20 03:50
108-90-7
Chloroethane
1.8
ug/L
1.0
1
03/21/20 03:50
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 03:50
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 03:50
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 03:50
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 03:50
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 03:50
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 03:50
74-95-3
1,2-Dichlorobenzene
5.1
ug/L
1.0
1
03/21/20 03:50
95-50-1
1,4-Dichlorobenzene
7.6
ug/L
1.0
1
03/21/20 03:50
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 03:50
110-57-6
1,1-Dichloroethane
34.7
ug/L
1.0
1
03/21/20 03:50
75-34-3
1,2-Dichloroethane
2.3
ug/L
1.0
1
03/21/20 03:50
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:50
75-35-4
cis-1,2-Dichloroethene
54.0
ug/L
1.0
1
03/21/20 03:50
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 03:50
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 9R Lab ID: 92469069002 Collected: 03/11/20 12:50 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
3.0
ug/L
1.0
1
03/21/20 03:50
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:50
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 03:50
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 03:50
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 03:50
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 03:50
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 03:50
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 03:50
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 03:50
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:50
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 03:50
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 03:50
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 03:50
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:50
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 03:50
79-00-5
Trichloroethene
1.5
ug/L
1.0
1
03/21/20 03:50
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 03:50
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 03:50
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 03:50
108-05-4
Vinyl chloride
7.2
ug/L
1.0
1
03/21/20 03:50
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 03:50
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 03:50
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 03:50
95-47-6
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
03/21/20 03:50
460-00-4
1,2-Dichloroethane-d4 (S)
97
%
70-130
1
03/21/20 03:50
17060-07-0
Toluene-d8(S)
100
%
70-130
1
03/21/20 03:50
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
11.2
ug/L
2.0
1
03/13/20 20:12
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
1
03/13/20 20:12
17060-07-0
Toluene-d8 (S)
98
%
50-150
1
03/13/20 20:12
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 16 Lab ID: 92469069003 Collected: 03/11/20 11:20 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:25
7440-38-2
Barium
110
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:25
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:25
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-48-4
Copper
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:25
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:25
7440-28-0
Vanadium
7.1
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:25
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:25
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 15:28
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 04:08
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 04:08
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 04:08
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 04:08
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 04:08
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 04:08
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 04:08
74-83-9
IH,v3
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 04:08
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 04:08
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 04:08
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 04:08
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 04:08
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 04:08
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 04:08
74-87-3
M1
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 04:08
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 04:08
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 04:08
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 04:08
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 04:08
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 04:08
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 04:08
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 04:08
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 04:08
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 04:08
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 04:08
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 04:08
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
Sample: HRW 16 Lab ID: 92469069003 Collected: 03/11/20 11:20 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 04:08
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 04:08
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 04:08
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 04:08
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 04:08
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 04:08
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 04:08
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 04:08
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 04:08
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 04:08
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 04:08
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 04:08
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 04:08
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 04:08
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 04:08
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 04:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 04:08
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 04:08
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 04:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 04:08
75-01-4 M1
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 04:08
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 04:08
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 04:08
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
03/21/20 04:08
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
03/21/20 04:08
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
03/21/20 04:08
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 19:52
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
94
%
50-150
1
03/13/20 19:52
17060-07-0
Toluene-d8 (S)
98
%
50-150
1
03/13/20 19:52
2037-26-5
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
QC Batch: 531025 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92469069001, 92469069002, 92469069003
METHOD BLANK: 2835486 Matrix: Water
Associated Lab Samples: 92469069001, 92469069002, 92469069003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
1.0
03/19/20 22:19
1.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2835487
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
475
95
80-120
Arsenic
ug/L
500
469
94
80-120
Barium
ug/L
500
483
97
80-120
Beryllium
ug/L
500
493
99
80-120
Cadmium
ug/L
500
481
96
80-120
Chromium
ug/L
500
478
96
80-120
Cobalt
ug/L
500
475
95
80-120
Copper
ug/L
500
472
94
80-120
Lead
ug/L
500
478
96
80-120
Nickel
ug/L
500
482
96
80-120
Selenium
ug/L
500
464
93
80-120
Silver
ug/L
250
242
97
80-120
Thallium
ug/L
500
458
92
80-120
Vanadium
ug/L
500
468
94
80-120
Zinc
ug/L
500
488
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Holbrooks Road Landfill
92469069
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2835488
2835489
MS
MSD
92468969001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
518
508
104
101
75-125
2
Arsenic
ug/L
ND
500
500
517
508
103
102
75-125
2
Barium
ug/L
8.1
500
500
514
507
101
100
75-125
1
Beryllium
ug/L
ND
500
500
517
510
103
102
75-125
1
Cadmium
ug/L
ND
500
500
522
510
104
102
75-125
2
Chromium
ug/L
19.1
500
500
519
512
100
98
75-125
1
Cobalt
ug/L
ND
500
500
490
480
98
96
75-125
2
Copper
ug/L
ND
500
500
511
504
101
100
75-125
1
Lead
ug/L
ND
500
500
494
484
99
97
75-125
2
Nickel
ug/L
ND
500
500
502
492
100
98
75-125
2
Selenium
ug/L
ND
500
500
519
512
103
102
75-125
1
Silver
ug/L
ND
250
250
262
258
105
103
75-125
1
Thallium
ug/L
ND
500
500
440
425
88
85
75-125
4
Vanadium
ug/L
ND
500
500
493
488
98
97
75-125
1
Zinc
ug/L
0.015
500
500
527
517
102
100
75-125
2
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
QC Batch: 531033
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92469069001, 92469069002,
92469069003
METHOD BLANK: 2835502
Matrix: Water
Associated Lab Samples: 92469069001, 92469069002,
92469069003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Thallium ug/L
ND 0.10
03/26/2013:02
LABORATORY CONTROL SAMPLE: 2835503
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Thallium ug/L
10 10.1
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835504 2835505
MS MSD
35535316001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Thallium ug/L 0.060U
10 10 10.1
10.1 101 101 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
QC Batch: 531753 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92469069001, 92469069002, 92469069003
METHOD BLANK: 2839240 Matrix:
Associated Lab Samples: 92469069001, 92469069002, 92469069003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,1-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
1,2,3-Trichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
03/20/20 23:30
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,4-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
2-Butanone (MEK)
ug/L
ND
5.0
03/20/20 23:30
2-Hexanone
ug/L
ND
5.0
03/20/20 23:30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/20/20 23:30
Acetone
ug/L
ND
25.0
03/20/20 23:30
Acrylonitrile
ug/L
ND
10.0
03/20/20 23:30
Benzene
ug/L
ND
1.0
03/20/20 23:30
Bromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromodichloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromoform
ug/L
ND
1.0
03/20/20 23:30
Bromomethane
ug/L
ND
2.0
03/20/20 23:30
Carbon disulfide
ug/L
ND
2.0
03/20/20 23:30
Carbon tetrachloride
ug/L
ND
1.0
03/20/20 23:30
Chlorobenzene
ug/L
ND
1.0
03/20/20 23:30
Chloroethane
ug/L
ND
1.0
03/20/20 23:30
Chloroform
ug/L
ND
5.0
03/20/20 23:30
Chloromethane
ug/L
ND
1.0
03/20/20 23:30
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
Dibromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Dibromomethane
ug/L
ND
1.0
03/20/20 23:30
Ethylbenzene
ug/L
ND
1.0
03/20/20 23:30
lodomethane
ug/L
ND
20.0
03/20/20 23:30
m&p-Xylene
ug/L
ND
2.0
03/20/20 23:30
Methylene Chloride
ug/L
ND
5.0
03/20/20 23:30
o-Xylene
ug/L
ND
1.0
03/20/20 23:30
Styrene
ug/L
ND
1.0
03/20/20 23:30
Tetrachloroethene
ug/L
ND
1.0
03/20/20 23:30
Toluene
ug/L
ND
1.0
03/20/20 23:30
Qualifiers
v2
IK
IH
IK,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
METHOD BLANK: 2839240 Matrix:
Associated Lab Samples: 92469069001, 92469069002, 92469069003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/20/20 23:30
Trichloroethene
ug/L
ND
1.0
03/20/20 23:30
Trichlorofluoromethane
ug/L
ND
1.0
03/20/20 23:30
Vinyl acetate
ug/L
ND
2.0
03/20/20 23:30
Vinyl chloride
ug/L
ND
1.0
03/20/20 23:30
Xylene (Total)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane-d4 (S)
%
97
70-130
03/20/20 23:30
4-Bromofluorobenzene (S)
%
100
70-130
03/20/20 23:30
Toluene-d8 (S)
%
99
70-130
03/20/20 23:30
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
55.4
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.9
98
70-130
1,1,2-Trichloroethane
ug/L
50
58.1
116
70-130
1,1-Dichloroethane
ug/L
50
55.5
111
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
46.1
92
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.0
94
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.9
102
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
51.5
103
70-130
1,2-Dichloropropane
ug/L
50
54.9
110
70-130
1,4-Dichlorobenzene
ug/L
50
49.1
98
70-130
2-Butanone (MEK)
ug/L
100
102
102
64-135
2-Hexanone
ug/L
100
91.1
91
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
96.6
97
61-157
Acrylonitrile
ug/L
250
270
108
61-143
Benzene
ug/L
50
53.5
107
70-130
Bromochloromethane
ug/L
50
61.0
122
70-130
Bromodichloromethane
ug/L
50
56.0
112
70-130 v1
Bromoform
ug/L
50
50.6
101
70-130lK
Bromomethane
ug/L
50
57.6
115
38-130lH
Carbon disulfide
ug/L
50
63.0
126
68-130
Carbon tetrachloride
ug/L
50
57.0
114
70-130
Chlorobenzene
ug/L
50
50.5
101
70-130
Chloroethane
ug/L
50
52.9
106
37-142 IK,v1
Chloroform
ug/L
50
56.6
113
70-130
Chloromethane
ug/L
50
43.3
87
48-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
LABORATORY CONTROL SAMPLE:
2839241
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
cis-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.4
117
70-130
Dibromochloromethane
ug/L
50
58.9
118
70-130
Dibromomethane
ug/L
50
59.3
119
70-130
Ethylbenzene
ug/L
50
48.6
97
70-130
lodomethane
ug/L
100
105
105
40-130
m&p-Xylene
ug/L
100
96.7
97
70-130
Methylene Chloride
ug/L
50
50.8
102
67-132
o-Xylene
ug/L
50
49.3
99
70-131
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
51.5
103
69-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.2
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
59.2
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
53.8
108
35-189
Trichloroethene
ug/L
50
54.3
109
70-130
Trichlorofluoromethane
ug/L
50
54.5
109
63-130
Vinyl acetate
ug/L
100
115
115
55-143
Vinyl chloride
ug/L
50
60.7
121
70-131
Xylene (Total)
ug/L
150
146
97
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.7
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
19.1
96
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.3
101
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-135
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-139
1,1-Dichloroethene
ug/L
ND
20
16.1
80
70-154
1,2,3-Trichloropropane
ug/L
ND
20
19.2
96
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.7
93
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.7
103
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.2
101
70-133
1,2-Dichloroethane
ug/L
ND
20
18.2
91
70-137
1,2-Dichloropropene
ug/L
ND
20
20.8
104
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.7
103
70-133
2-Butanone (MEK)
ug/L
ND
40
35.6
89
60-139
2-Hexanone
ug/L
ND
40
39.0
97
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.0
93
65-135
Acetone
ug/L
ND
40
34.1
85
60-148
Acrylonitrile
ug/L
ND
100
89.4
89
64-147
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Benzene
ug/L
ND
20
20.0
100
70-151
Bromochloromethane
ug/L
ND
20
21.4
107
70-141 v1
Bromodichloromethane
ug/L
ND
20
20.3
101
70-138
Bromoform
ug/L
ND
20
17.6
88
63-1301K
Bromomethane
ug/L
ND
20
12.1
61
15-152 IH,v3
Carbon disulfide
ug/L
ND
20
16.1
80
69-149 v1
Carbon tetrachloride
ug/L
ND
20
21.6
108
70-143
Chlorobenzene
ug/L
ND
20
21.9
109
70-138
Chloroethane
ug/L
ND
20
15.0
75
52-1631K
Chloroform
ug/L
ND
20
20.0
100
70-139
Chloromethane
ug/L
ND
20
5.3
26
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
19.0
95
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.1
100
70-137
Dibromochloromethane
ug/L
ND
20
22.1
110
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.0
105
66-153
Iodomethane
ug/L
ND
40
24.1
60
20-138
m&p-Xylene
ug/L
ND
40
41.9
105
69-152
Methylene Chloride
ug/L
ND
20
16.6
83
42-159
o-Xylene
ug/L
ND
20
21.2
106
70-148
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
20.8
104
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
18.2
91
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
14.7
73
47-135
Trichloroethene
ug/L
ND
20
20.3
101
70-147
Trichlorofluoromethane
ug/L
ND
20
14.8
74
70-148
Vinyl acetate
ug/L
ND
40
36.0
90
49-151
Vinyl chloride
ug/L
ND
20
10.6
53
70-156 M1
Xylene (Total)
ug/L
ND
60
63.0
105
63-158
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2839242
92469069002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
34.7
30.9
12
1,1-Dichloroethene
ug/L
ND
ND
1,2,3-Trichloropropane
ug/L
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
5.1
5.3
1,2-Dichloroethane
ug/L
2.3
2.0
1,2-Dichloropropane
ug/L
3.0
2.9
1,4-Dichlorobenzene
ug/L
7.6
7.5
2-Butanone (MEK)
ug/L
20.5
17.9
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
41.5
35.4
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
.84J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
2.4
2.5
Chloroethane
ug/L
1.8
1.5
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
54.0
47.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
.67J
Toluene
ug/L
ND
.52J
trans-1,2-Dichloroethene
ug/L
ND
.79J
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
1.5
1.5
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
7.2
6.3
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
92
4-Bromofluorobenzene (S)
%
100
99
Toluene-d8(S)
%
100
97
RPD Qualifiers
3
13
2
1
14
16
v1
IK
I K,v2
v1
4
17 IK
13
0
13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
QC Batch: 530451 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92469069001, 92469069002, 92469069003
METHOD BLANK: 2832866
Matrix:
Water
Associated Lab Samples:
92469069001, 92469069002, 92469069003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
03/13/20 15:38
1,2-Dichloroethane-d4 (S)
%
97
50-150
03/13/20 15:38
Toluene-d8 (S)
%
98
50-150
03/13/20 15:38
LABORATORY CONTROL SAMPLE: 2832867
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 21.0 105 70-130
1,2-Dichloroethane-d4 (S) % 90 50-150
Toluene-d8(S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832868
2832869
MS
MSD
92468855001 Spike
Spike MS MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 191 80
80 269 274 97
103
50-150 2
1,2-Dichloroethane-d4 (S)
%
93
96
50-150
Toluene-d8(S)
%
99
100
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Holbrooks Road Landfill
Pace Project No.: 92469069
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:24 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Holbrooks Road Landfill
92469069
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92469069001
HRW 8
EPA 3010A
531025
EPA 6010D
531052
92469069002
HRW 9R
EPA 3010A
531025
EPA 6010D
531052
92469069003
HRW 16
EPA 3010A
531025
EPA 6010D
531052
92469069001
HRW 8
EPA 3010A
531033
EPA 6020B
531056
92469069002
HRW 9R
EPA 3010A
531033
EPA 6020B
531056
92469069003
HRW 16
EPA 3010A
531033
EPA 6020B
531056
92469069001
HRW 8
EPA 8260D
531753
92469069002
HRW 9R
EPA 8260D
531753
92469069003
HRW 16
EPA 8260D
531753
92469069001
HRW 8
EPA 8260D Mod.
530451
92469069002
HRW 9R
EPA 8260D Mod.
530451
92469069003
HRW 16
EPA 8260D Mod.
530451
Date: 03/27/2020 01:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 23

aceArral ida]
T�-.— �---.__—_--
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page I of 2
--.---------DQGumeffLNn.:
-. IsSuingAllth>Z[itlt�__
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑
Client Name:
Courier: []Fed Ex []UPS LISPS
❑ Commercial [pace ❑tither:
Custody Seal Present? ❑Yes ONo Seals Intact? Des
Huntersville d Ralelgh❑ Mechanicsville❑
—44oi" #; . WQ## : 92469069
nt
92469059
Date/lnitlals Person Examining Contents: 7" L —Zv YC1v1
Packing Material: ❑Hubble Wrap []Bubble Bags ❑None ❑ Other Blologkal Tissue Frozen?
Thermometer: ❑Yes []No[rN/A
❑IR Gun lD: j92T! O6fl Type of Ice: [ Net ❑Blue []Name
Cooler Temp (°C): ! Correction Factor: Add/Subtract (°C) 0.0
Temp should be above freezing to VC
Cooler Temp Corrected (°C): L ❑Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soll (Z N/A, water sample)
Cid samples originate in a g6drantihe'zone within the United States: CA, NY, or SC (check maps)7 old samples originate from a foreign source I intern atlon ally,
I—IYac I—INn .. Includln Hawaii and Puerto Rlcol? r_lYes MNo
Comments/Discrepancy:
:Chain of Custor3y PreseriC r'"'' ' '`
Q"ves ❑No
❑N/A
3.
Samples Arrived within Hold Time?
[31es
❑No
❑N/A
2.
'Short Hold Time Analysis (<72'tir:p
❑Yes
[ago
❑N/A
3.
SRush Turn Around Time Requested?
❑Yes
[31 o
❑N/A
4.
Sufficient Volume? i
OY'es
[]No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
Des
RYes
❑No
❑No
❑N/A
❑N/A
6.
Containers Intact?
Z'5es
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
[]Yes [—]No
[ N/A
B.
Sample Labels Match COC?
❑Yes
❑No
[]NIA
9.
-Includes Date/Time/lo/Anafysls Matrix-
Headspace in VOA Vials {>5-6mm)7
[]Yes
EffNo
❑N/A
10.
Trip Blank Present?,
Trip Blank Custody Seals Present?
Yes
[]Yes
[]No
©No
El N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Datefrime:
Project Manager SCURF Review: Date:
Project Manager SRF Review: Date:
Field Data Required? ❑Yes []NO
Page 21 of 23

Document Name:
I,�lCc7�L Upon Recelpt(SCUR)
zaceAnalonditlon
Y` Document No.:
Document Revised: February 7, 2019
Page 1 of 2
issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
Project # r WO#
92466
Exceptions: VOA, Cvliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: 92—MECK Co
**Bottom half of box Is to list number of bottle L
Date: 03/25/20
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot a
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certiflcation Office (i.e.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 22 of 23

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Page 23 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
April 03, 2020
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: HRW-18-Revised Report
Pace Project No.: 92468923
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 10, 2020. The results relate only to
the samples included in this report. Results reported herein conform to the applicable TNI/NELAC Standards and the
laboratory's Quality Manual, where applicable, unless otherwise noted in the body of the report.
The test results provided in this final report were generated by each of the following laboratories within the Pace Network:
• Pace Analytical Services - Asheville
• Pace Analytical Services - Charlotte
• Pace Analytical Services - Kansas City
• Pace Analytical Services - Ormond Beach
This revision was issued on 04/03/20 to report requested metals.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 45

lacieAnalyfical'f'
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Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: HRW-18-Revised Report
Pace Project No.: 92468923
Pace Analytical Services Ormond Beach
8 East Tower Circle, Ormond Beach, FL 32174
Alaska DEC- CS/UST/LUST
Alabama Certification #: 41320
Arizona Certification# AZ0819
Colorado Certification: FL NELAC Reciprocity
Connecticut Certification #: PH-0216
Delaware Certification: FL NELAC Reciprocity
Florida Certification #: E83079
Georgia Certification #: 955
Guam Certification: FL NELAC Reciprocity
Hawaii Certification: FL NELAC Reciprocity
Illinois Certification #: 200068
Indiana Certification: FL NELAC Reciprocity
Kansas Certification #: E-10383
Kentucky Certification #: 90050
Louisiana Certification #: FL NELAC Reciprocity
Louisiana Environmental Certificate #: 05007
Maryland Certification: #346
Michigan Certification #: 9911
Mississippi Certification: FL NELAC Reciprocity
Pace Analytical Services Kansas
9608 Loiret Boulevard, Lenexa, KS 66219
Missouri Inorganic Drinking Water Certification #: 10090
Arkansas Drinking Water
Arkansas Certification #: 20-020-0
Arkansas Drinking Water
Illinois Certification #: 200030
Iowa Certification #: 118
Kansas/NELAP Certification #: E-10116
Louisiana Certification #: 03055
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification M M-NC030
North Carolina Drinking Water Certification M 37712
CERTIFICATIONS
Missouri Certification #: 236
Montana Certification #: Cert 0074
Nebraska Certification: NE-OS-28-14
New Hampshire Certification #: 2958
New Jersey Certification #: FL022
New York Certification #: 11608
North Carolina Environmental Certificate #: 667
North Carolina Certification #: 12710
North Dakota Certification #: R-216
Oklahoma Certification #: D9947
Pennsylvania Certification #: 68-00547
Puerto Rico Certification #: FLO1264
South Carolina Certification: #96042001
Tennessee Certification #: TN02974
Texas Certification: FL NELAC Reciprocity
US Virgin Islands Certification: FL NELAC Reciprocity
Virginia Environmental Certification #: 460165
West Virginia Certification #: 9962C
Wisconsin Certification #: 399079670
Wyoming (EPA Region 8): FL NELAC Reciprocity
Nevada Certification #: KS000212020-2
Oklahoma Certification #: 9205/9935
Florida: Cert E871149 SEKS WET
Texas Certification #: T104704407-19-12
Utah Certification #: KS000212019-9
Illinois Certification #: 004592
Kansas Field Laboratory Accreditation: # E-92587
Missouri SEKS Micro Certification: 10070
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 2 of 45

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[phone]
SAMPLE ANALYTE COUNT
Project: HRW-18-Revised Report
Pace Project No.: 92468923
Analytes
Lab ID Sample ID
Method
Analysts
Reported
Laboratory
92468923001 HRW-18
RSK 175 Modified
MAD
3
PASI-C
EPA 601OD
SH1
16
PASI-A
EPA 6020
AMS
1
PASI-O
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
LMS1
1
PASI-A
SM 521OB-2011
SMK
1
PASI-A
SM 2580B
MAP
1
PASI-K
EPA 300.0 Rev 2.1 1993
BRJ
3
PASI-A
SM 4500-CI-E-2011
KDF1
1
PASI-A
SM 5220D-2011
JP1
1
PASI-A
SM 531OB-2011
ECH
1
PASI-A
PASI-A = Pace Analytical Services - Asheville
PASI-C = Pace Analytical Services - Charlotte
PASI-K = Pace Analytical Services - Kansas City
PASI-O = Pace Analytical Services - Ormond Beach
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 45

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[phone]
ANALYTICAL RESULTS
Project: HRW-18-Revised Report
Pace Project No.: 92468923
Sample: HRW-18
Lab ID: 92468923001 Collected:
03/10/20
13:05
Received: 03/10/20 15:11 Matrix: Water
Parameters
Results Units Report
Limit
DF
Prepared
Analyzed
CAS No.
Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Pace Analytical Services - Charlotte
Ethane
ND ug/L
40.0
4
03/17/2012:55
74-84-0
Ethene
ND ug/L
40.0
4
03/17/2012:55
74-85-1
Methane
36700 ug/L
40.0
4
03/17/2012:55
74-82-8
6010 MET ICP
Analytical Method: EPA 6010D Preparation
Method:
EPA 3010A
Pace Analytical Services -Asheville
Antimony
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-36-0
Arsenic
ND ug/L
10.0
1
03/17/20 01:27
03/19/20 19:18
7440-38-2
Barium
351 ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-39-3
Beryllium
ND ug/L
1.0
1
03/17/20 01:27
03/19/20 19:18
7440-41-7
Cadmium
ND ug/L
1.0
1
03/17/20 01:27
03/19/20 19:18
7440-43-9
Chromium
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-47-3
Cobalt
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-48-4
Copper
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-50-8
Iron
2320 ug/L
50.0
1
03/17/20 01:27
03/19/20 19:18
7439-89-6
Lead
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7439-92-1
Nickel
11.4 ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-02-0
Selenium
ND ug/L
10.0
1
03/17/20 01:27
03/19/20 19:18
7782-49-2
Silver
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-22-4
Thallium
ND ug/L
10.0
1
03/17/20 01:27
03/19/20 19:18
7440-28-0
Vanadium
ND ug/L
5.0
1
03/17/20 01:27
03/19/20 19:18
7440-62-2
Zinc
ND ug/L
10.0
1
03/17/20 01:27
03/19/20 19:18
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020 Preparation Method: EPA 3010
Pace Analytical Services - Ormond Beach
Thallium
ND mg/L
0.0010
1
03/16/20 11:41
03/22/20 22:05
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical Services - Charlotte
Acetone
ND ug/L
25.0
1
03/21/20 00:22
67-64-1
Acrylonitrile
ND ug/L
10.0
1
03/21/20 00:22
107-13-1
Benzene
3.0 ug/L
1.0
1
03/21/20 00:22
71-43-2
Bromochloromethane
ND ug/L
1.0
1
03/21/20 00:22
74-97-5
v1
Bromodichloromethane
ND ug/L
1.0
1
03/21/20 00:22
75-27-4
Bromoform
ND ug/L
1.0
1
03/21/20 00:22
75-25-2
IK
Bromomethane
ND ug/L
2.0
1
03/21/20 00:22
74-83-9
IH
2-Butanone (MEK)
ND ug/L
5.0
1
03/21/20 00:22
78-93-3
Carbon disulfide
ND ug/L
2.0
1
03/21/20 00:22
75-15-0
Carbon tetrachloride
ND ug/L
1.0
1
03/21/20 00:22
56-23-5
Chlorobenzene
4.9 ug/L
1.0
1
03/21/20 00:22
108-90-7
Chloroethane
ND ug/L
1.0
1
03/21/20 00:22
75-00-3
IK,v1
Chloroform
ND ug/L
5.0
1
03/21/20 00:22
67-66-3
Chloromethane
ND ug/L
1.0
1
03/21/20 00:22
74-87-3
1,2-Dibromo-3-chloropropane
ND ug/L
5.0
1
03/21/20 00:22
96-12-8
Dibromochloromethane
ND ug/L
1.0
1
03/21/20 00:22
124-48-1
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HRW-18-Revised Report
Pace Project No.: 92468923
Sample: HRW-18 Lab ID: 92468923001 Collected: 03/10/20 13:05 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Pace Analytical
Services - Charlotte
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 00:22
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 00:22
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 00:22
95-50-1
1,4-Dichlorobenzene
6.9
ug/L
1.0
1
03/21/20 00:22
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 00:22
110-57-6
1,1-Dichloroethane
29.4
ug/L
1.0
1
03/21/20 00:22
75-34-3
1,2-Dichloroethane
1.1
ug/L
1.0
1
03/21/20 00:22
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:22
75-35-4
cis-1,2-Dichloroethene
1.6
ug/L
1.0
1
03/21/20 00:22
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 00:22
156-60-5
1,2-Dichloropropene
4.7
ug/L
1.0
1
03/21/20 00:22
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:22
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 00:22
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 00:22
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 00:22
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 00:22
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 00:22
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 00:22
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 00:22
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:22
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 00:22
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 00:22
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 00:22
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:22
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 00:22
79-00-5
Trichloroethene
1.3
ug/L
1.0
1
03/21/20 00:22
79-01-6
Trichlorofluoromethane
3.1
ug/L
1.0
1
03/21/20 00:22
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 00:22
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 00:22
108-05-4
Vinyl chloride
14.1
ug/L
1.0
1
03/21/20 00:22
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 00:22
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 00:22
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 00:22
95-47-6
Surrogates
4-Bromofluorobenzene (S)
102
%
70-130
1
03/21/20 00:22
460-00-4
1,2-Dichloroethane-d4 (S)
96
%
70-130
1
03/21/20 00:22
17060-07-0
Toluene-d8 (S)
102
%
70-130
1
03/21/20 00:22
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
Pace Analytical
Services - Charlotte
1,4-Dioxane (p-Dioxane)
10.7
ug/L
2.0
1
03/13/20 21:10
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
50-150
1
03/13/20 21:10
17060-07-0
Toluene-d8 (S)
100
%
50-150
1
03/13/20 21:10
2037-26-5
Date: 04/03/2020 06:12 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: HRW-18-Revised Report
Pace Project No.: 92468923
Sample: HRW-18 Lab ID: 92468923001 Collected: 03/10/20 13:05 Received: 03/10/20 15:11 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
2320B Alkalinity
Analytical Method: SM 2320B-2011
Pace Analytical Services -Asheville
Alkalinity, Total as CaCO3
823 mg/L
5.0
1
03/20/20 16:25
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Pace Analytical Services -Asheville
Sulfide
ND mg/L
0.10
1
03/13/2019:49
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521OB-2011
Pace Analytical Services -Asheville
BOD, 5 day
ND mg/L
2.0
1
03/11/20 05:00 03/16/20 12:04
Oxidation/Reduction Potential
Analytical Method: SM 2580B
Pace Analytical Services - Kansas City
Oxidation/Reduction Potential
78.3 my
1.0
1
03/23/20 11:55
H6
300.0 IC anions 48hr
Analytical Method: EPA 300.0 Rev 2.1 1993
Pace Analytical Services -Asheville
Chloride
32.9 mg/L
1.0
1
03/11/2016:23
16887-00-6
Nitrate as N
ND mg/L
0.10
1
03/11/20 16:23
14797-55-8
Sulfate
17.2 mg/L
1.0
1
03/11/2016:23
14808-79-8
4500 Chloride
Analytical Method: SM 4500-CI-E-2011
Pace Analytical Services -Asheville
Chloride
36.7 mg/L
1.0
1
03/17/2011:37
16887-00-6
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Pace Analytical Services -Asheville
Chemical Oxygen Demand
ND mg/L
25.0
1
03/17/20 23:03 03/18/20 06:00
5310B TOC
Analytical Method: SM 531OB-2011
Pace Analytical Services -Asheville
Total Organic Carbon
5.4 mg/L
1.0
1
03/23/20 18:59
7440-44-0
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 45

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 530881 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92468923001
METHOD BLANK: 2834592
Matrix:
Water
Associated Lab Samples: 92468923001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Ethane
ug/L
ND
10.0
03/17/2011:54
Ethene
ug/L
ND
10.0
03/17/2011:54
Methane
ug/L
ND
10.0
03/17/2011:54
LABORATORY CONTROL SAMPLE:
2834593
Parameter
Units
Ethane
ug/L
Ethene
ug/L
Methane
ug/L
MATRIX SPIKE SAMPLE:
2834595
Parameter
Units
Ethane
ug/L
Ethene
ug/L
Methane
ug/L
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
658 579 88 70-130
1120 1020 90 70-130
396 456 115 70-130
2630017002 Spike MS MS % Rec
Result Conc. Result % Rec Limits Qualifiers
ND 658 634 96 70-130
ND 1120 1240 110 70-130
ND 396 466 118 70-130
SAMPLE DUPLICATE: 2834866
2630017003 Dup
Parameter Units Result Result
Ethane ug/L ND ND
Ethene ug/L ND ND
Methane ug/L ND ND
RPD Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 530802 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2834381
Associated Lab Samples: 92468923001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
Antimony
ug/L
ND
5.0
03/19/2018:37
Arsenic
ug/L
ND
10.0
03/19/2018:37
Barium
ug/L
ND
5.0
03/19/2018:37
Beryllium
ug/L
ND
1.0
03/19/2018:37
Cadmium
ug/L
ND
1.0
03/19/2018:37
Chromium
ug/L
ND
5.0
03/19/2018:37
Cobalt
ug/L
ND
5.0
03/19/2018:37
Copper
ug/L
ND
5.0
03/19/2018:37
Iron
ug/L
ND
50.0
03/19/2018:37
Lead
ug/L
ND
5.0
03/19/2018:37
Nickel
ug/L
ND
5.0
03/19/2018:37
Selenium
ug/L
ND
10.0
03/19/2018:37
Silver
ug/L
ND
5.0
03/19/2018:37
Thallium
ug/L
ND
10.0
03/19/2018:37
Vanadium
ug/L
ND
5.0
03/19/2018:37
Zinc
ug/L
ND
10.0
03/19/2018:37
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2834382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
516
103
80-120
Arsenic
ug/L
500
489
98
80-120
Barium
ug/L
500
506
101
80-120
Beryllium
ug/L
500
510
102
80-120
Cadmium
ug/L
500
503
101
80-120
Chromium
ug/L
500
507
101
80-120
Cobalt
ug/L
500
507
101
80-120
Copper
ug/L
500
518
104
80-120
Iron
ug/L
5000
5080
102
80-120
Lead
ug/L
500
509
102
80-120
Nickel
ug/L
500
504
101
80-120
Selenium
ug/L
500
508
102
80-120
Silver
ug/L
250
247
99
80-120
Thallium
ug/L
500
491
98
80-120
Vanadium
ug/L
500
504
101
80-120
Zinc
ug/L
500
488
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 8 of 45

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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
HRW-18-Revised Report
92468923
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2834383
2834384
MS
MSD
92468589001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
528
519
106
104
75-125
2
Arsenic
ug/L
ND
500
500
500
493
100
98
75-125
2
Barium
ug/L
17.8
500
500
530
518
102
100
75-125
2
Beryllium
ug/L
ND
500
500
519
506
104
101
75-125
3
Cadmium
ug/L
0.70J
500
500
524
513
105
102
75-125
2
Chromium
ug/L
ND
500
500
520
509
104
102
75-125
2
Cobalt
ug/L
ND
500
500
512
502
102
100
75-125
2
Copper
ug/L
ND
500
500
521
509
104
102
75-125
2
Iron
ug/L
72.5
5000
5000
5320
5190
105
102
75-125
2
Lead
ug/L
ND
500
500
516
506
103
101
75-125
2
Nickel
ug/L
ND
500
500
514
505
103
101
75-125
2
Selenium
ug/L
ND
500
500
537
529
107
106
75-125
2
Silver
ug/L
ND
250
250
257
253
103
101
75-125
1
Thallium
ug/L
ND
500
500
479
472
95
94
75-125
1
Vanadium
ug/L
ND
500
500
514
499
103
100
75-125
3
Zinc
ug/L
ND
500
500
513
506
102
101
75-125
1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 618152 Analysis Method: EPA 6020
QC Batch Method: EPA 3010 Analysis Description: 6020 MET
Laboratory: Pace Analytical Services - Ormond Beach
Associated Lab Samples: 92468923001
METHOD BLANK: 3359830
Associated Lab Samples: 92468923001
Parameter Units
Thallium mg/L
LABORATORY CONTROL SAMPLE: 3359831
Parameter Units
Thallium mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.0010 03/22/20 20:48
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.05 0.051 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 3359832 3359833
MS MSD
35537215001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Thallium mg/L 0.11 U 0.05 0.05 0.051 0.051 101 102 75-125 0
ug/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 45

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 531753 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92468923001
METHOD BLANK: 2839240
Associated Lab Samples: 92468923001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,1-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
1,2,3-Trichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
03/20/20 23:30
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,4-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
2-Butanone (MEK)
ug/L
ND
5.0
03/20/20 23:30
2-Hexanone
ug/L
ND
5.0
03/20/20 23:30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/20/20 23:30
Acetone
ug/L
ND
25.0
03/20/20 23:30
Acrylonitrile
ug/L
ND
10.0
03/20/20 23:30
Benzene
ug/L
ND
1.0
03/20/20 23:30
Bromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromodichloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromoform
ug/L
ND
1.0
03/20/20 23:30
Bromomethane
ug/L
ND
2.0
03/20/20 23:30
Carbon disulfide
ug/L
ND
2.0
03/20/20 23:30
Carbon tetrachloride
ug/L
ND
1.0
03/20/20 23:30
Chlorobenzene
ug/L
ND
1.0
03/20/20 23:30
Chloroethane
ug/L
ND
1.0
03/20/20 23:30
Chloroform
ug/L
ND
5.0
03/20/20 23:30
Chloromethane
ug/L
ND
1.0
03/20/20 23:30
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
Dibromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Dibromomethane
ug/L
ND
1.0
03/20/20 23:30
Ethylbenzene
ug/L
ND
1.0
03/20/20 23:30
lodomethane
ug/L
ND
20.0
03/20/20 23:30
m&p-Xylene
ug/L
ND
2.0
03/20/20 23:30
Methylene Chloride
ug/L
ND
5.0
03/20/20 23:30
o-Xylene
ug/L
ND
1.0
03/20/20 23:30
Styrene
ug/L
ND
1.0
03/20/20 23:30
Tetrachloroethene
ug/L
ND
1.0
03/20/20 23:30
Qualifiers
v2
IK
IH
IK.v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 45

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
METHOD BLANK: 2839240
Associated Lab Samples: 92468923001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
Toluene
ug/L
ND
1.0
03/20/20 23:30
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/20/20 23:30
Trichloroethene
ug/L
ND
1.0
03/20/20 23:30
Trichlorofluoromethane
ug/L
ND
1.0
03/20/20 23:30
Vinyl acetate
ug/L
ND
2.0
03/20/20 23:30
Vinyl chloride
ug/L
ND
1.0
03/20/20 23:30
Xylene (Total)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane-d4 (S)
%
97
70-130
03/20/20 23:30
4-Bromofluorobenzene (S)
%
100
70-130
03/20/20 23:30
Toluene-d8 (S)
%
99
70-130
03/20/20 23:30
LABORATORY CONTROL SAMPLE: 2839241
Qualifiers
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
55.4
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.9
98
70-130
1,1,2-Trichloroethane
ug/L
50
58.1
116
70-130
1,1-Dichloroethane
ug/L
50
55.5
111
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
46.1
92
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.0
94
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.9
102
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
51.5
103
70-130
1,2-Dichloropropane
ug/L
50
54.9
110
70-130
1,4-Dichlorobenzene
ug/L
50
49.1
98
70-130
2-Butanone (MEK)
ug/L
100
102
102
64-135
2-Hexanone
ug/L
100
91.1
91
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
96.6
97
61-157
Acrylonitrile
ug/L
250
270
108
61-143
Benzene
ug/L
50
53.5
107
70-130
Bromochloromethane
ug/L
50
61.0
122
70-130
Bromodichloromethane
ug/L
50
56.0
112
70-130 v1
Bromoform
ug/L
50
50.6
101
70-130lK
Bromomethane
ug/L
50
57.6
115
38-130lH
Carbon disulfide
ug/L
50
63.0
126
68-130
Carbon tetrachloride
ug/L
50
57.0
114
70-130
Chlorobenzene
ug/L
50
50.5
101
70-130
Chloroethane
ug/L
50
52.9
106
37-142 IK,v1
Chloroform
ug/L
50
56.6
113
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 45

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
LABORATORY CONTROL SAMPLE:
Parameter
2839241
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Chloromethane
ug/L
50
43.3
87
48-130
cis-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.4
117
70-130
Dibromochloromethane
ug/L
50
58.9
118
70-130
Dibromomethane
ug/L
50
59.3
119
70-130
Ethylbenzene
ug/L
50
48.6
97
70-130
lodomethane
ug/L
100
105
105
40-130
m&p-Xylene
ug/L
100
96.7
97
70-130
Methylene Chloride
ug/L
50
50.8
102
67-132
o-Xylene
ug/L
50
49.3
99
70-131
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
51.5
103
69-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.2
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
59.2
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
53.8
108
35-189
Trichloroethene
ug/L
50
54.3
109
70-130
Trichlorofluoromethane
ug/L
50
54.5
109
63-130
Vinyl acetate
ug/L
100
115
115
55-143
Vinyl chloride
ug/L
50
60.7
121
70-131
Xylene (Total)
ug/L
150
146
97
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
Parameter
2839243
Units
92469069003
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.7
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
19.1
96
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.3
101
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-135
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-139
1,1-Dichloroethene
ug/L
ND
20
16.1
80
70-154
1,2,3-Trichloropropane
ug/L
ND
20
19.2
96
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.7
93
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.7
103
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.2
101
70-133
1,2-Dichloroethane
ug/L
ND
20
18.2
91
70-137
1,2-Dichloropropane
ug/L
ND
20
20.8
104
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.7
103
70-133
2-Butanone (MEK)
ug/L
ND
40
35.6
89
60-139
2-Hexanone
ug/L
ND
40
39.0
97
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.0
93
65-135
Acetone
ug/L
ND
40
34.1
85
60-148
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 45

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
MATRIX SPIKE SAMPLE:
Parameter
2839243
Units
92469069003
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Acrylonitrile
ug/L
ND
100
89.4
89
64-147
Benzene
ug/L
ND
20
20.0
100
70-151
Bromochloromethane
ug/L
ND
20
21.4
107
70-141 v1
Bromodichloromethane
ug/L
ND
20
20.3
101
70-138
Bromoform
ug/L
ND
20
17.6
88
63-1301K
Bromomethane
ug/L
ND
20
12.1
61
15-152 IH,v3
Carbon disulfide
ug/L
ND
20
16.1
80
69-149 v1
Carbon tetrachloride
ug/L
ND
20
21.6
108
70-143
Chlorobenzene
ug/L
ND
20
21.9
109
70-138
Chloroethane
ug/L
ND
20
15.0
75
52-1631K
Chloroform
ug/L
ND
20
20.0
100
70-139
Chloromethane
ug/L
ND
20
5.3
26
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
19.0
95
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.1
100
70-137
Dibromochloromethane
ug/L
ND
20
22.1
110
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.0
105
66-153
Iodomethane
ug/L
ND
40
24.1
60
20-138
m&p-Xylene
ug/L
ND
40
41.9
105
69-152
Methylene Chloride
ug/L
ND
20
16.6
83
42-159
o-Xylene
ug/L
ND
20
21.2
106
70-148
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
20.8
104
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
18.2
91
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
14.7
73
47-135
Trichloroethene
ug/L
ND
20
20.3
101
70-147
Trichlorofluoromethane
ug/L
ND
20
14.8
74
70-148
Vinyl acetate
ug/L
ND
40
36.0
90
49-151
Vinyl chloride
ug/L
ND
20
10.6
53
70-156 M1
Xylene (Total)
ug/L
ND
60
63.0
105
63-158
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result RPD
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
34.7
30.9 12
1,1-Dichloroethene
ug/L
ND
ND
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 45

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result
1,2,3-Trichloropropane
ug/L
ND
ND
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
5.1
5.3
1,2-Dichloroethane
ug/L
2.3
2.0
1,2-Dichloropropane
ug/L
3.0
2.9
1,4-Dichlorobenzene
ug/L
7.6
7.5
2-Butanone (MEK)
ug/L
20.5
17.9
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
41.5
35.4
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
.84J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
2.4
2.5
Chloroethane
ug/L
1.8
1.5
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
54.0
47.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
.67J
Toluene
ug/L
ND
.52J
trans-1,2-Dichloroethene
ug/L
ND
.79J
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
1.5
1.5
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
7.2
6.3
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
92
4-Bromofluorobenzene (S)
%
100
99
Toluene-d8(S)
%
100
97
RPD Qualifiers
3
13
2
1
14
16
v1
IK
I K,v2
v1
4
17 IK
13
a
13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 530451 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Laboratory: Pace Analytical Services - Charlotte
Associated Lab Samples: 92468923001
METHOD BLANK: 2832866
Matrix:
Water
Associated Lab Samples: 92468923001
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
03/13/20 15:38
1,2-Dichloroethane-d4 (S)
%
97
50-150
03/13/20 15:38
Toluene-d8 (S)
%
98
50-150
03/13/20 15:38
LABORATORY CONTROL SAMPLE: 2832867
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 21.0 105 70-130
1,2-Dichloroethane-d4 (S) % 90 50-150
Toluene-d8 (S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832868
2832869
MS
MSD
92468855001 Spike
Spike MS
MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 191 80
80 269
274 97
103
50-150 2
1,2-Dichloroethane-d4 (S)
%
93
96
50-150
Toluene-d8(S)
%
99
100
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 531672 Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011 Analysis Description: 2320E Alkalinity
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2838528
Associated Lab Samples: 92468923001
Parameter Units
Alkalinity, Total as CaCO3 mg/L
LABORATORY CONTROL SAMPLE: 2838529
Parameter Units
Alkalinity, Total as CaCO3 mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 5.0 03/20/20 15:09
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
50 53.4 107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2838532 2838533
MS MSD
92468668067 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 106 50 50 159 160 106 108 80-120 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2838535 2838536
MS MSD
92468668068 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Alkalinity, Total as CaCO3 mg/L 20.3 50 50 72.2 72.6 104 104 80-120 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 530440 Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011 Analysis Description: 4500S2D Sulfide Water
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2832791
Associated Lab Samples: 92468923001
Parameter Units
Sulfide mg/L
LABORATORY CONTROL SAMPLE: 2832792
Parameter Units
Sulfide mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 0.10 03/13/2019:37
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
0.5 0.46 92 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832793 2832794
MS MSD
2629916001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfide mg/L ND 0.5 0.5 0.42 0.42 83 83 80-120 0
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832795 2832796
MS MSD
2629916002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Sulfide mg/L ND 0.5 0.5 0.41 0.41 81 80 80-120 1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 529637 Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2829030
Associated Lab Samples: 92468923001
Parameter Units
BOD, 5 day mg/L
LABORATORY CONTROL SAMPLE: 2829031
Parameter Units
BOD, 5 day mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 2.0 03/16/20 09:42
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
198 212 107 84.6-115
SAMPLE DUPLICATE: 2829033
92468805001 Dup
Parameter Units Result Result
BOD, 5 day mg/L 23.3 22.1
RPD Qualifiers
5
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 645350 Analysis Method: SM 2580B
QC Batch Method: SM 2580B Analysis Description: Oxidation/Reduction Potential
Laboratory: Pace Analytical Services - Kansas City
Associated Lab Samples: 92468923001
SAMPLE DUPLICATE: 2621847
92468923001 Dup
Parameter Units Result Result
Oxidation/Reduction Potential my 78.3 78.2
RPD Qualifiers
H6
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 529704 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2829209
Matrix: Water
Associated Lab Samples: 92468923001
Blank Reporting
Parameter
Units
Result Limit
Analyzed Qualifiers
Chloride
mg/L
ND 1.0
03/11/2015:55
Nitrate as N
mg/L
ND 0.10
03/11/20 15:55
Sulfate
mg/L
ND 1.0
03/11/2015:55
LABORATORY CONTROL SAMPLE: 2829210
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Chloride mg/L 50 49.5 99 90-110
Nitrate as N mg/L 2.5 2.4 96 90-110
Sulfate mg/L 50 51.7 103 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2829211
2829212
MS
MSD
92468923001 Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result Conc.
Conc.
Result
Result
% Rec
% Rec
Limits RPD Qual
Chloride mg/L
32.9 50
50
83.1
83.3
100
101
90-110 0
Nitrate as N mg/L
ND 2.5
2.5
2.5
2.5
100
101
90-110 1
Sulfate mg/L
17.2 50
50
68.5
68.8
103
103
90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 45

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 530845 Analysis Method: SM 4500-CI-E-2011
QC Batch Method: SM 4500-CI-E-2011 Analysis Description: 4500 Chloride
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2834432
Associated Lab Samples: 92468923001
Parameter Units
Chloride mg/L
LABORATORY CONTROL SAMPLE: 2834433
Parameter Units
Chloride mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 03/17/2011:12
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
20 20.7 104 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834434 2834435
MS MSD
92468860002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 124 10 10 135 134 110 98 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2834436 2834437
MS MSD
92468864002 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chloride mg/L 87.2 10 10 97.7 97.2 104 100 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 531005 Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2835437
Associated Lab Samples: 92468923001
Parameter Units
Chemical Oxygen Demand mg/L
LABORATORY CONTROL SAMPLE: 2835438
Parameter Units
Chemical Oxygen Demand mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 25.0 03/18/20 05:56
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
750 766 102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835439 2835440
MS MSD
92468777008 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 116 100 100 214 218 98 103 90-110 2
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835441 2835442
MS MSD
92468789001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Chemical Oxygen Demand mg/L 2400 100 100 2790 2850 385 447 90-110 2 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: HRW-18-Revised Report
Pace Project No.: 92468923
QC Batch: 531941 Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011 Analysis Description: 5310E TOC
Laboratory: Pace Analytical Services -Asheville
Associated Lab Samples: 92468923001
METHOD BLANK: 2839822
Associated Lab Samples: 92468923001
Parameter Units
Total Organic Carbon mg/L
LABORATORY CONTROL SAMPLE: 2839823
Parameter Units
Total Organic Carbon mg/L
Matrix: Water
Blank Reporting
Result Limit Analyzed Qualifiers
ND 1.0 03/23/20 15:06
Spike LCS LCS % Rec
Conc. Result % Rec Limits Qualifiers
25 23.5 94 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2839824 2839825
MS MSD
2630017001 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 23.8 23.6 92 91 90-110 1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2839826 2839827
MS MSD
92467528032 Spike Spike MS MSD MS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
Total Organic Carbon mg/L ND 25 25 23.9 23.9 95 95 90-110 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: HRW-18-Revised Report
Pace Project No.: 92468923
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
ANALYTE QUALIFIERS
H6 Analysis initiated outside of the 15 minute EPA required holding time.
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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Date: 04/03/2020 06:12 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 45

leAnalyiical
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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
HRW-18-Revised Report
92468923
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92468923001
HRW-18
RSK 175 Modified
530881
92468923001
HRW-18
EPA 3010A
530802
EPA 6010D
530823
92468923001
HRW-18
EPA 3010
618152
EPA 6020
618287
92468923001
HRW-18
EPA 8260D
531753
92468923001
HRW-18
EPA 8260D Mod.
530451
92468923001
HRW-18
SM 2320E-2011
531672
92468923001
HRW-18
SM 4500-S2D-2011
530440
92468923001
HRW-18
SM 5210E-2011
529637
SM 5210B-2011
529678
92468923001
HRW-18
SM 2580E
645350
92468923001
HRW-18
EPA 300.0 Rev 2.1 1993
529704
92468923001
HRW-18
SM 4500-CI-E-2011
530845
92468923001
HRW-18
SM 5220D-2011
531005
SM 5220D-2011
531059
92468923001
HRW-18
SM 5310E-2011
531941
REPORT OF LABORATORY ANALYSIS
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g
_ ace Analytical
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑
Greenwood ❑
Huntersville
❑ Raleigh[] Mechanicsville❑
Sample Condition Client Name:WO#:92468923
Upon
C oUn j
Pralect
Courier: ❑Fed Ex ❑UPS ❑USPS I
[]Client
❑ Commercial [Pace
❑Other:
1 1 1
92468923
Custody Seal Present? ❑Yes E*
Seals Intact? []Yes
[DNo
_ �� —ZU A i3 /'�
Date/Initials Person Examining Contents: ri`�"�'1�
Packing Material: ❑Bubble Wrap
['Bubble Bags ❑None
❑ Other
BlologicaI Tissue Frozen?
❑IR Gun ID: Thermometer: 92TO60
Type of Ice: E'wet ❑slue
❑Yes []No 2N/A
❑None
Cooler Temp ('Q: ' . Correction
Factor: Add/Subtract (°C)
0.0
Cooler Temp '" '?
Temp should be above freezing to 6°C
Corrected ('Q; -
❑Samples out of temp Criteria. Samples an ice, coaling process
has begun
USDA Regulated Sol! ( [ `N/A, water sample)
Did samples oilginate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
Did samples originate from a forelgn source ;internationally,
I—IYes FIN.
Inrludlne Hawaii and Puerto Flcol? nYes nNo
Comments/Discrepancy:
'Chain�of Custody Present'? ,'°
[3es
❑No
❑NIA
1.
Samples Arrived within Hold Time?
[jYes
❑No
❑N/A
2.
Short HofdTime Analysis (<72,hr.)?
E]Ies
❑No
❑NIA
3.
Rush Turn Around Time Requested?
❑Yes
[31�o
❑N/A
4.
Sufficient Volume? ! -
[arYes
❑No
[]N/A
S.
Correct Containers Used?
-Pace Containers Used?
[aYes
QYes
[:]No
❑No
❑N/A
❑N/A
6.
Containers Intact?
[j�fes
❑No
❑NIA
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
❑fi/A
S.
Sample Labels Match COC?
©Yes
[:]No
[]N/A
9.
-Includes Date/Time/iD/Analysis Matrix:
�/ T
Headspace in VOA Vials (>5-6mm)?
❑Yes
76
El N/A
ID.
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
[]Yes
ffNo
[3No
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
1 vial cake/
If fv,\
Lot 10 of spilt containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Date:
Date:
Field Data Required? []Yes [:]No
Page 27 of 45

Document Name:
e Condition Upon Recel
Document Revised: February 7, 2018
Pace 1 of 2
3-Rev.D6
*Check mark top half of box If pH and/or dechlorination is
verified and within the -acceptance range for preservation
Pace Carolinas Quality Office
Project# WO# : 92468923
PM. MWB Due Bata. eV19i 20
Exceptions: VOA, Caliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLH8 il� CLIENT: 92—MECK CO
"Bottom half of box is to list number of bottle f'
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lacmnalyficalo
March 26, 2020
Matt Brainard
Pace Analytical Huntersville
9800 Kincey Ave
Suite 100
Huntersville, NC 28078
RE: 92468923
Pace Workorder. 33227
Dear Matt Brainard:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Friday, March 13, 2020. Results
reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in
the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 03/26/2020
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 33227 - 1269300
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 15
Page 1 of 13
Page 31 of 45

Pace Analytical Energy Services LLC
220 William Pitt Way
.,-- A__1.X__1 o Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
MEMENNESSEEMIL-
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 33227 - 1269300
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 13
Page 32 of 45

lacmnalyficalo
SAMPLE SUMMARY
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Workorder: 33227 92468923
Lab ID Sample ID Matrix Date Collected Date Received
332270001 HRW-18 Water 3/10/202013:05 3/13/202011:00
332270002 HRW-18 Bubble Strip 3/10/2020 13:05 3/13/2020 11:00
Report ID: 33227 - 1269300 Page 3 of 13
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 33 of 45

lacmnalyficalo
PROJECT SUMMARY
Workorder: 33227 92468923
Batch Comments
Batch: DISG/8154 - AM20GAX Bubble Strip QC
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
The percent recovery for the closing calibration verification analysis was above laboratory control limits. Analytes Hydrogen.
Results associated to the analytes in samples may be biased high. Those samples affected by this specific verification have been
flagged.
Batch: EDON/4393 -Low Level Volatile Fatty Acids
The matrix spike and/or spike duplicate, recovery or relative percent difference; accuracy influenced by the concentration of the
reference sample 332190001. All analytes except iso-Hexanoic acid. Batch acceptance based on laboratory control sample
recovery.
Batch: EDON/4395 - Low Level Volatile Fatty Acids
The matrix spike and/or spike duplicate, recovery or relative percent difference; accuracy influenced by the concentration of the
reference sample 332130001. All analytes except iso-Hexanoic acid. Batch acceptance based on laboratory control sample
recovery.
Report ID: 33227 - 1269300
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 4 of 13
Page 34 of 45

lacmnalyficalo
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 332270001
Sample ID: HRW-18
Date Received: 3/13/2020 11:00 Matrix: Water
Date Collected: 3/10/2020 13:05
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.0851.11 mg/I
0.20
0.085 1
3/22/2020 02:11
KB
M3,M5
Acetic Acid
0.28 mg/I
0.10
0.043 1
3/22/2020 02:11
KB
M3,M5
Propionic Acid
0.15 mg/I
0.10
0.0010 1
3/22/2020 02:11
KB
M3,B,M5
Formic Acid
0.121.11 mg/I
0.50
0.12 1
3/22/2020 02:11
KB
M5
Butyric Acid
0.062J mg/I
0.10
0.0090 1
3/22/2020 02:11
KB
M3
Pyruvic Acid
0.014U mg/I
0.10
0.014 1
3/22/2020 02:11
KB
M3
i-Pentanoic Acid
0.00701.11 mg/I
0.10
0.0070 1
3/22/2020 02:11
KB
M5
Pentanoic Acid
0.071J mg/I
0.10
0.0050 1
3/22/2020 02:11
KB
M3,M5
i-Hexanoic Acid
0.0101.11 mg/I
0.20
0.010 1
3/22/2020 02:11
KB
Hexanoic Acid
0.0201.11 mg/I
0.20
0.020 1
3/22/2020 02:11
KB
M3
RISK - PAES
Analysis Desc: AM20GAX
Analytical Method: AM20GAX
Carbon Dioxide
310 mg/I
5.0
0.47 1
3/14/2020 14:15
TD
n
Report ID: 33227 - 1269300 Page 5 of 13
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 35 of 45

lacmnalyficalo
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 332270002 Date Received: 3/13/2020 11:00 Matrix: Bubble Strip
Sample ID: HRW-18 Date Collected: 3/10/2020 13:05
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 4.5 nM 1.0 0.75 1 3/16/202013:48 TD M1,n
Report ID: 33227 - 1269300 Page 6 of 13
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 36 of 45

lacmnalyficalo
ANALYTICAL RESULTS QUALIFIERS
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
n The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
B The analyte was detected in the associated blank.
M1 The continuing calibration verification recovery was outside laboratory control limits.
M5 The matrix spike duplicate sample recovery was outside laboratory control limits.
M3 The matrix spike sample recovery was outside laboratory control limits.
Report ID: 33227 - 1269300
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 7 of 13
Page 37 of 45

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/8152
Analysis Method:
AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 332270001
METHOD BLANK: 66329
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Carbon Dioxide mg/I
0.47U
0.47 n
LABORATORY CONTROL SAMPLE & LCSD:
66331
66333
Spike
LCS LCSD LCS
LCSD % Rec Max
Parameter Units
Conc. Result Result % Rec
% Rec Limit RPD RPD Qualifiers
Carbon Dioxide mg/I
120
130 130 113
115 80-120 1.9 20 n
Report ID: 33227 - 1269300
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 8 of 13
Page 38 of 45

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/8154
Analysis Method:
AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 332270002
METHOD BLANK: 66337
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Hydrogen nM
0.75U
0.75 n
LABORATORY CONTROL SAMPLE & LCSD:
66338
66339
Spike
LCS LCSD LCS
LCSD % Rec Max
Parameter Units
Conc. Result Result % Rec
% Rec Limit RPD RPD Qualifiers
Hydrogen nM
25
26 27 107
110 80-120 2.2 20 n
Report ID: 33227 - 1269300
.4r-tielac�,
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 9 of 13
Page 39 of 45

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 33227 92468923
QC Batch: EDON/4393 Analysis Method: AM23G
QC Batch Method: AM23G
Associated Lab Samples: 332270001
METHOD BLANK: 66414
Blank Reporting
Parameter Units Result Limit Qualifiers
EDonors
Lactic Acid
mg/I
0.085U
0.085 M3,M5
Acetic Acid
mg/I
0.043U
0.043 M3,M5
Propionic Acid
mg/I
0.00111
0.0010 M3,B,M5
Formic Acid
mg/I
0.12U
0.12 M5
Butyric Acid
mg/I
0.0090U
0.0090 M3
Pyruvic Acid
mg/I
0.014U
0.014 M3
i-Pentanoic Acid
mg/I
0.0070U
0.0070 M5
Pentanoic Acid
mg/I
0.0050U
0.0050 M3,M5
i-Hexanoic Acid
mg/I
0.010U
0.010
Hexanoic Acid
mg/I
0.020U
0.020 M3
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY CONTROL SAMPLE:
66415
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Lactic Acid
mg/I
2
2.1
106
70-130
M3,M5
Acetic Acid
mg/I
2
2.2
111
70-130
M3,M5
Propionic Acid
mg/I
2
2.1
107
70-130
M3,B,M5
Formic Acid
mg/I
2
2.1
106
70-130
M5
Butyric Acid
mg/I
2
2.1
106
70-130
M3
Pyruvic Acid
mg/I
2
1.9
97
70-130
M3
i-Pentanoic Acid
mg/I
2
2.1
106
70-130
M5
Pentanoic Acid
mg/I
2
2.0
100
70-130
M3,M5
i-Hexanoic Acid
mg/I
2
2.0
103
70-130
Hexanoic Acid
mg/I
2
1.9
95
70-130
M3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 66416
66417
Original:
332190001
Original Spike
MS
MSD MS
MSD
% Rec Max
Parameter
Units
Result Cone.
Result
Result % Rec
% Rec
Limit RPD RPD
Qualifiers
EDonors
Lactic Acid
mg/I
0 2
0.28
0.21 14
10
70-130 29 30
M3,M5
Acetic Acid
mg/I
320 2
0.0431-1
0.043U -16000
-16000
70-130 0 30
M3,M5
Report ID: 33227 - 1269300
Page 10 of 13
F`
CERTIFICATE OF
ANALYSIS
ne"`~
This report shall
not be reproduced,
except in full,
without the written consent
of Pace Analytical
Energy Services LLC.
Page 40 of 45

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
66416
66417
Original:
332190001
Original
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Cone.
Result
Result
% Rec
% Rec
Limit RPD
RPD
Qualifiers
Propionic Acid
mg/I
160
2
0.0010U
0.0010U
-7900
-7900
70-130
0
30
M3,B,M5
Formic Acid
mg/I
0.69
2
2.7
3.5
101
141
70-130
26
30
M5
Butyric Acid
mg/I
10
2
9.2
12
-39
93
70-130
25
30
M3
Pyruvic Acid
mg/I
1.7
2
3.1
3.9
67
110
70-130
25
30
M3
i-Pentanoic Acid
mg/I
0.43
2
2.5
3.2
103
141
70-130
27
30
M5
Pentanoic Acid
mg/I
7.4
2
6.7
8.5
-36
56
70-130
24
30
M3,M5
i-Hexanoic Acid
mg/I
0.049
2
1.8
2.3
86
113
70-130
27
30
Hexanoic Acid
mg/I
3.3
2
4.5
5.7
63
123
70-130
23
30
M3
Report ID: 33227 - 1269300
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 11 of 13
Page 41 of 45

lacmnalyficalo
QUALITY CONTROL DATA QUALIFIERS
Workorder: 33227 92468923
QUALITY CONTROL PARAMETER QUALIFIERS
The analyte was detected in the associated blank.
M3 The matrix spike sample recovery was outside laboratory control limits.
M5 The matrix spike duplicate sample recovery was outside laboratory control limits.
The analyte concentration was determined from a dilution.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 33227 - 1269300
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 12 of 13
Page 42 of 45

lacmnalyficalo
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 33227 92468923
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Analysis
Lab ID
Sample ID
Prep Method Prep Batch Analysis Method
Batch
332270001
HRW-18
AM20GAX
DISG/8152
332270002
HRW-18
AM20GAX
DISG/8154
332270001
HRW-18
AM23G
EDON/4393
Report ID: 33227 - 1269300
.4r-tielac�,
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 13 of 13
Page 43 of 45

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Cooler Receipt Form
J Client Name:
Project: �<y `" Lab Work Order: -3302
�C.c�C� _
A. Shipping/Container Information (circle appropriate response)
Courier: FedE UPS USPS Client Other: Air bill Present: Yes No
Tracking Number:
Custody Seal on Cooler/Box Present: Yes/No)' Seals Intact: Yes No
Cooler/Box Packing Material: le Wrra� Absorbent Foam
Type of Ice: Wet Blue None Ice Intact• Yes Melted
Cooler Temperature: �, Radiation Screened: Yes No)
Comments:
B. Laboratory Assignment/Log-in (check appropriate response)
Other:
Chain of Custody Present: Y s No
YES
NO
N/A
Comment
Reference non -Conformance
Chain of Custody properly filled out
Chain of Custody relinquished
Sampler Name & Signature on COC
Containers intact
Were samples in separate bags
Sample container labels match COC
Sample name/date and time collected
Sufficient volume provided
PAES containers used
Are containers properly preserved for the requested testing?
(as labeled)
If an unknown preservation state, were containers checked?
Exception: VOA's coliform
If yes, see pH form.
Was volume for dissolved testing field filtered, as noted on
the COO Was volume received in a preserved container?
Headspace present?
Comments:
ENV-FRM-PITTS-0006 Rev 00
Cooler contents examined/received by: Date: 2-0 2_0
r+
Project Manager Review: Date: Zt�
r
Page 45 of 45

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
March 27, 2020
Amber Grzymski
Mecklenburg County Solid Waste
2145 Suttle Avenue
Charlotte, NC 28208
RE: Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Dear Amber Grzymski:
Enclosed are the analytical results for sample(s) received by the laboratory on March 11, 2020. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Matthew Brainard
[e-mail]
[phone]
Project Manager
Enclosures
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Pace Analytical Services Charlotte
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Pace Analytical Services Asheville
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Holbrooks Road Landfill
92469061
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92469061001
HRSA 2
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469061002
HRSA 3
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92469061003
HRSA 4
EPA 6010D
SH1
15
PASI-A
EPA 6020E
BG2
1
PASI-A
EPA 8260D
CL
52
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 3 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA2 Lab ID: 92469061001 Collected: 03/11/2012:10 Received: 03/11/2014:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:53
7440-38-2
Barium
32.8
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 22:53
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 22:53
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-48-4
Copper
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:53
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:53
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:53
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:53
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:27
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 01:49
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 01:49
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 01:49
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 01:49
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 01:49
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 01:49
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 01:49
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 01:49
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 01:49
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 01:49
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 01:49
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 01:49
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 01:49
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 01:49
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 01:49
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 01:49
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 01:49
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 01:49
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:49
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 01:49
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 01:49
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 01:49
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 01:49
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:49
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:49
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 01:49
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA2 Lab ID: 92469061001 Collected: 03/11/2012:10 Received: 03/11/2014:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 01:49
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 01:49
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 01:49
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 01:49
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 01:49
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 01:49
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 01:49
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 01:49
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 01:49
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 01:49
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 01:49
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 01:49
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 01:49
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 01:49
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 01:49
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 01:49
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 01:49
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 01:49
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 01:49
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 01:49
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 01:49
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 01:49
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 01:49
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
03/21/20 01:49
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
03/21/20 01:49
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
03/21/20 01:49
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 21:29
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
95
%
50-150
1
03/13/20 21:29
17060-07-0
Toluene-d8 (S)
97
%
50-150
1
03/13/20 21:29
2037-26-5
Date: 03/27/2020 01:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA3 Lab ID: 92469061002 Collected: 03/11/2010:30 Received: 03/11/2014:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:56
7440-38-2
Barium
36.4
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 22:56
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 22:56
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-48-4
Copper
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:56
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:56
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 22:56
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 22:56
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:31
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 02:06
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 02:06
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 02:06
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 02:06
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 02:06
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 02:06
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 02:06
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 02:06
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 02:06
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 02:06
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 02:06
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 02:06
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 02:06
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 02:06
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 02:06
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 02:06
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 02:06
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 02:06
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:06
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:06
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 02:06
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:06
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:06
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:06
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:06
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:06
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA3 Lab ID: 92469061002 Collected: 03/11/2010:30 Received: 03/11/2014:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 02:06
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:06
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:06
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 02:06
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 02:06
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 02:06
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 02:06
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 02:06
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 02:06
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:06
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:06
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 02:06
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 02:06
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:06
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:06
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 02:06
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 02:06
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 02:06
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 02:06
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 02:06
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 02:06
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 02:06
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 02:06
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
03/21/20 02:06
460-00-4
1,2-Dichloroethane-d4 (S)
100
%
70-130
1
03/21/20 02:06
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
03/21/20 02:06
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 21:50
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
93
%
50-150
1
03/13/20 21:50
17060-07-0
Toluene-d8 (S)
98
%
50-150
1
03/13/20 21:50
2037-26-5
Date: 03/27/2020 01:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA4 Lab ID: 92469061003 Collected: 03/11/20 11:45 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-36-0
Arsenic
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:00
7440-38-2
Barium
33.0
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-39-3
Beryllium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:00
7440-41-7
Cadmium
ND
ug/L
1.0
1
03/18/20 01:00
03/19/20 23:00
7440-43-9
Chromium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-47-3
Cobalt
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-48-4
Copper
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-50-8
Lead
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7439-92-1
Nickel
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-02-0
Selenium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:00
7782-49-2
Silver
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-22-4
Thallium
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:00
7440-28-0
Vanadium
ND
ug/L
5.0
1
03/18/20 01:00
03/19/20 23:00
7440-62-2
Zinc
ND
ug/L
10.0
1
03/18/20 01:00
03/19/20 23:00
7440-66-6
6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A
Thallium
ND
ug/L
0.10
1
03/18/20 01:56 03/25/20 14:36
7440-28-0
8260D MSV Low Level Landfill
Analytical Method:
EPA 8260D
Acetone
ND
ug/L
25.0
1
03/21/20 02:24
67-64-1
Acrylonitrile
ND
ug/L
10.0
1
03/21/20 02:24
107-13-1
Benzene
ND
ug/L
1.0
1
03/21/20 02:24
71-43-2
Bromochloromethane
ND
ug/L
1.0
1
03/21/20 02:24
74-97-5
v1
Bromodichloromethane
ND
ug/L
1.0
1
03/21/20 02:24
75-27-4
Bromoform
ND
ug/L
1.0
1
03/21/20 02:24
75-25-2
IK
Bromomethane
ND
ug/L
2.0
1
03/21/20 02:24
74-83-9
IH
2-Butanone (MEK)
ND
ug/L
5.0
1
03/21/20 02:24
78-93-3
Carbon disulfide
ND
ug/L
2.0
1
03/21/20 02:24
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
1
03/21/20 02:24
56-23-5
Chlorobenzene
ND
ug/L
1.0
1
03/21/20 02:24
108-90-7
Chloroethane
ND
ug/L
1.0
1
03/21/20 02:24
75-00-3
IK,v1
Chloroform
ND
ug/L
5.0
1
03/21/20 02:24
67-66-3
Chloromethane
ND
ug/L
1.0
1
03/21/20 02:24
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
1
03/21/20 02:24
96-12-8
Dibromochloromethane
ND
ug/L
1.0
1
03/21/20 02:24
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
1
03/21/20 02:24
106-93-4
Dibromomethane
ND
ug/L
1.0
1
03/21/20 02:24
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:24
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
1
03/21/20 02:24
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
1
03/21/20 02:24
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:24
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
1
03/21/20 02:24
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:24
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:24
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
1
03/21/20 02:24
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 23

leAnalyiical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
Sample: HRSA4 Lab ID: 92469061003 Collected: 03/11/20 11:45 Received: 03/11/20 14:24 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill Analytical Method: EPA 8260D
1,2-Dichloropropane
ND
ug/L
1.0
1
03/21/20 02:24
78-87-5
cis-1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:24
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
1
03/21/20 02:24
10061-02-6
Ethylbenzene
ND
ug/L
1.0
1
03/21/20 02:24
100-41-4
2-Hexanone
ND
ug/L
5.0
1
03/21/20 02:24
591-78-6
lodomethane
ND
ug/L
20.0
1
03/21/20 02:24
74-88-4
Methylene Chloride
ND
ug/L
5.0
1
03/21/20 02:24
75-09-2
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
1
03/21/20 02:24
108-10-1
Styrene
ND
ug/L
1.0
1
03/21/20 02:24
100-42-5
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:24
630-20-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
1
03/21/20 02:24
79-34-5
Tetrachloroethene
ND
ug/L
1.0
1
03/21/20 02:24
127-18-4
Toluene
ND
ug/L
1.0
1
03/21/20 02:24
108-88-3
1,1,1-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:24
71-55-6
1,1,2-Trichloroethane
ND
ug/L
1.0
1
03/21/20 02:24
79-00-5
Trichloroethene
ND
ug/L
1.0
1
03/21/20 02:24
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
1
03/21/20 02:24
75-69-4
1,2,3-Trichloropropane
ND
ug/L
1.0
1
03/21/20 02:24
96-18-4
Vinyl acetate
ND
ug/L
2.0
1
03/21/20 02:24
108-05-4
Vinyl chloride
ND
ug/L
1.0
1
03/21/20 02:24
75-01-4
Xylene (Total)
ND
ug/L
1.0
1
03/21/20 02:24
1330-20-7
m&p-Xylene
ND
ug/L
2.0
1
03/21/20 02:24
179601-23-1
o-Xylene
ND
ug/L
1.0
1
03/21/20 02:24
95-47-6
Surrogates
4-Bromofluorobenzene (S)
99
%
70-130
1
03/21/20 02:24
460-00-4
1,2-Dichloroethane-d4 (S)
98
%
70-130
1
03/21/20 02:24
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
03/21/20 02:24
2037-26-5
8260D MSV SIM
Analytical Method:
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1
03/13/20 22:09
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
1
03/13/20 22:09
17060-07-0
Toluene-d8 (S)
97
%
50-150
1
03/13/20 22:09
2037-26-5
Date: 03/27/2020 01:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
QC Batch: 531025 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92469061001, 92469061002, 92469061003
METHOD BLANK: 2835486 Matrix: Water
Associated Lab Samples: 92469061001, 92469061002, 92469061003
Blank Reporting
Parameter Units Result Limit
Antimony
ug/L
ND
Arsenic
ug/L
ND
Barium
ug/L
ND
Beryllium
ug/L
ND
Cadmium
ug/L
ND
Chromium
ug/L
ND
Cobalt
ug/L
ND
Copper
ug/L
ND
Lead
ug/L
ND
Nickel
ug/L
ND
Selenium
ug/L
ND
Silver
ug/L
ND
Thallium
ug/L
ND
Vanadium
ug/L
ND
Zinc
ug/L
ND
Analyzed
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
1.0
03/19/20 22:19
1.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
5.0
03/19/20 22:19
10.0
03/19/20 22:19
Qualifiers
LABORATORY CONTROL SAMPLE:
Parameter
2835487
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
475
95
80-120
Arsenic
ug/L
500
469
94
80-120
Barium
ug/L
500
483
97
80-120
Beryllium
ug/L
500
493
99
80-120
Cadmium
ug/L
500
481
96
80-120
Chromium
ug/L
500
478
96
80-120
Cobalt
ug/L
500
475
95
80-120
Copper
ug/L
500
472
94
80-120
Lead
ug/L
500
478
96
80-120
Nickel
ug/L
500
482
96
80-120
Selenium
ug/L
500
464
93
80-120
Silver
ug/L
250
242
97
80-120
Thallium
ug/L
500
458
92
80-120
Vanadium
ug/L
500
468
94
80-120
Zinc
ug/L
500
488
98
80-120
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Holbrooks Road Landfill
92469061
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE:
2835488
2835489
MS
MSD
92468969001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Parameter Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Qual
Antimony
ug/L
ND
500
500
518
508
104
101
75-125
2
Arsenic
ug/L
ND
500
500
517
508
103
102
75-125
2
Barium
ug/L
8.1
500
500
514
507
101
100
75-125
1
Beryllium
ug/L
ND
500
500
517
510
103
102
75-125
1
Cadmium
ug/L
ND
500
500
522
510
104
102
75-125
2
Chromium
ug/L
19.1
500
500
519
512
100
98
75-125
1
Cobalt
ug/L
ND
500
500
490
480
98
96
75-125
2
Copper
ug/L
ND
500
500
511
504
101
100
75-125
1
Lead
ug/L
ND
500
500
494
484
99
97
75-125
2
Nickel
ug/L
ND
500
500
502
492
100
98
75-125
2
Selenium
ug/L
ND
500
500
519
512
103
102
75-125
1
Silver
ug/L
ND
250
250
262
258
105
103
75-125
1
Thallium
ug/L
ND
500
500
440
425
88
85
75-125
4
Vanadium
ug/L
ND
500
500
493
488
98
97
75-125
1
Zinc
ug/L
0.015
500
500
527
517
102
100
75-125
2
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
QC Batch: 531033
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92469061001, 92469061002,
92469061003
METHOD BLANK: 2835502
Matrix: Water
Associated Lab Samples: 92469061001, 92469061002,
92469061003
Blank Reporting
Parameter Units
Result Limit
Analyzed Qualifiers
Thallium ug/L
ND 0.10
03/26/2013:02
LABORATORY CONTROL SAMPLE: 2835503
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Thallium ug/L
10 10.1
101 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2835504 2835505
MS MSD
35535316001
Spike Spike MS
MSD MS MSD % Rec
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD Qual
Thallium ug/L 0.060U
10 10 10.1
10.1 101 101 75-125 0
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 23

leAnalyiical
www.pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
QC Batch: 531753 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92469061001, 92469061002, 92469061003
METHOD BLANK: 2839240 Matrix:
Associated Lab Samples: 92469061001, 92469061002, 92469061003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,1-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1,2-Trichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,1-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
1,2,3-Trichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
03/20/20 23:30
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloropropane
ug/L
ND
1.0
03/20/20 23:30
1,4-Dichlorobenzene
ug/L
ND
1.0
03/20/20 23:30
2-Butanone (MEK)
ug/L
ND
5.0
03/20/20 23:30
2-Hexanone
ug/L
ND
5.0
03/20/20 23:30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
03/20/20 23:30
Acetone
ug/L
ND
25.0
03/20/20 23:30
Acrylonitrile
ug/L
ND
10.0
03/20/20 23:30
Benzene
ug/L
ND
1.0
03/20/20 23:30
Bromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromodichloromethane
ug/L
ND
1.0
03/20/20 23:30
Bromoform
ug/L
ND
1.0
03/20/20 23:30
Bromomethane
ug/L
ND
2.0
03/20/20 23:30
Carbon disulfide
ug/L
ND
2.0
03/20/20 23:30
Carbon tetrachloride
ug/L
ND
1.0
03/20/20 23:30
Chlorobenzene
ug/L
ND
1.0
03/20/20 23:30
Chloroethane
ug/L
ND
1.0
03/20/20 23:30
Chloroform
ug/L
ND
5.0
03/20/20 23:30
Chloromethane
ug/L
ND
1.0
03/20/20 23:30
cis-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
cis-1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
Dibromochloromethane
ug/L
ND
1.0
03/20/20 23:30
Dibromomethane
ug/L
ND
1.0
03/20/20 23:30
Ethylbenzene
ug/L
ND
1.0
03/20/20 23:30
lodomethane
ug/L
ND
20.0
03/20/20 23:30
m&p-Xylene
ug/L
ND
2.0
03/20/20 23:30
Methylene Chloride
ug/L
ND
5.0
03/20/20 23:30
o-Xylene
ug/L
ND
1.0
03/20/20 23:30
Styrene
ug/L
ND
1.0
03/20/20 23:30
Tetrachloroethene
ug/L
ND
1.0
03/20/20 23:30
Toluene
ug/L
ND
1.0
03/20/20 23:30
Qualifiers
v2
IK
IH
IK,v1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
METHOD BLANK: 2839240 Matrix:
Associated Lab Samples: 92469061001, 92469061002, 92469061003
Blank
Parameter Units Result
Water
Reporting
Limit
Analyzed
trans-1,2-Dichloroethene
ug/L
ND
1.0
03/20/20 23:30
trans- 1,3-Dichloropropene
ug/L
ND
1.0
03/20/20 23:30
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
03/20/20 23:30
Trichloroethene
ug/L
ND
1.0
03/20/20 23:30
Trichlorofluoromethane
ug/L
ND
1.0
03/20/20 23:30
Vinyl acetate
ug/L
ND
2.0
03/20/20 23:30
Vinyl chloride
ug/L
ND
1.0
03/20/20 23:30
Xylene (Total)
ug/L
ND
1.0
03/20/20 23:30
1,2-Dichloroethane-d4 (S)
%
97
70-130
03/20/20 23:30
4-Bromofluorobenzene (S)
%
100
70-130
03/20/20 23:30
Toluene-d8 (S)
%
99
70-130
03/20/20 23:30
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.5
107
70-130
1,1,1-Trichloroethane
ug/L
50
55.4
111
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
48.9
98
70-130
1,1,2-Trichloroethane
ug/L
50
58.1
116
70-130
1,1-Dichloroethane
ug/L
50
55.5
111
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
46.1
92
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
47.0
94
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.9
102
70-130
1,2-Dichlorobenzene
ug/L
50
49.0
98
70-130
1,2-Dichloroethane
ug/L
50
51.5
103
70-130
1,2-Dichloropropane
ug/L
50
54.9
110
70-130
1,4-Dichlorobenzene
ug/L
50
49.1
98
70-130
2-Butanone (MEK)
ug/L
100
102
102
64-135
2-Hexanone
ug/L
100
91.1
91
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
103
103
70-130
Acetone
ug/L
100
96.6
97
61-157
Acrylonitrile
ug/L
250
270
108
61-143
Benzene
ug/L
50
53.5
107
70-130
Bromochloromethane
ug/L
50
61.0
122
70-130
Bromodichloromethane
ug/L
50
56.0
112
70-130 v1
Bromoform
ug/L
50
50.6
101
70-130lK
Bromomethane
ug/L
50
57.6
115
38-130lH
Carbon disulfide
ug/L
50
63.0
126
68-130
Carbon tetrachloride
ug/L
50
57.0
114
70-130
Chlorobenzene
ug/L
50
50.5
101
70-130
Chloroethane
ug/L
50
52.9
106
37-142 IK,v1
Chloroform
ug/L
50
56.6
113
70-130
Chloromethane
ug/L
50
43.3
87
48-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
LABORATORY CONTROL SAMPLE:
2839241
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
cis-1,2-Dichloroethene
ug/L
50
55.1
110
70-130
cis-1,3-Dichloropropene
ug/L
50
58.4
117
70-130
Dibromochloromethane
ug/L
50
58.9
118
70-130
Dibromomethane
ug/L
50
59.3
119
70-130
Ethylbenzene
ug/L
50
48.6
97
70-130
lodomethane
ug/L
100
105
105
40-130
m&p-Xylene
ug/L
100
96.7
97
70-130
Methylene Chloride
ug/L
50
50.8
102
67-132
o-Xylene
ug/L
50
49.3
99
70-131
Styrene
ug/L
50
51.3
103
70-130
Tetrachloroethene
ug/L
50
51.5
103
69-130
Toluene
ug/L
50
53.5
107
70-130
trans-1,2-Dichloroethene
ug/L
50
55.2
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
59.2
118
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
53.8
108
35-189
Trichloroethene
ug/L
50
54.3
109
70-130
Trichlorofluoromethane
ug/L
50
54.5
109
63-130
Vinyl acetate
ug/L
100
115
115
55-143
Vinyl chloride
ug/L
50
60.7
121
70-131
Xylene (Total)
ug/L
150
146
97
70-130
1,2-Dichloroethane-d4 (S)
%
93
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.7
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
19.1
96
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
20.3
101
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.2
106
70-135
1,1-Dichloroethane
ug/L
ND
20
18.7
94
70-139
1,1-Dichloroethene
ug/L
ND
20
16.1
80
70-154
1,2,3-Trichloropropane
ug/L
ND
20
19.2
96
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.7
93
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.7
103
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.2
101
70-133
1,2-Dichloroethane
ug/L
ND
20
18.2
91
70-137
1,2-Dichloropropene
ug/L
ND
20
20.8
104
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.7
103
70-133
2-Butanone (MEK)
ug/L
ND
40
35.6
89
60-139
2-Hexanone
ug/L
ND
40
39.0
97
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
37.0
93
65-135
Acetone
ug/L
ND
40
34.1
85
60-148
Acrylonitrile
ug/L
ND
100
89.4
89
64-147
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
MATRIX SPIKE SAMPLE:
2839243
92469069003
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Benzene
ug/L
ND
20
20.0
100
70-151
Bromochloromethane
ug/L
ND
20
21.4
107
70-141 v1
Bromodichloromethane
ug/L
ND
20
20.3
101
70-138
Bromoform
ug/L
ND
20
17.6
88
63-1301K
Bromomethane
ug/L
ND
20
12.1
61
15-152 IH,v3
Carbon disulfide
ug/L
ND
20
16.1
80
69-149 v1
Carbon tetrachloride
ug/L
ND
20
21.6
108
70-143
Chlorobenzene
ug/L
ND
20
21.9
109
70-138
Chloroethane
ug/L
ND
20
15.0
75
52-1631K
Chloroform
ug/L
ND
20
20.0
100
70-139
Chloromethane
ug/L
ND
20
5.3
26
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
19.0
95
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.1
100
70-137
Dibromochloromethane
ug/L
ND
20
22.1
110
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.0
105
66-153
Iodomethane
ug/L
ND
40
24.1
60
20-138
m&p-Xylene
ug/L
ND
40
41.9
105
69-152
Methylene Chloride
ug/L
ND
20
16.6
83
42-159
o-Xylene
ug/L
ND
20
21.2
106
70-148
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
20.8
104
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
18.2
91
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.4
102
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
14.7
73
47-135
Trichloroethene
ug/L
ND
20
20.3
101
70-147
Trichlorofluoromethane
ug/L
ND
20
14.8
74
70-148
Vinyl acetate
ug/L
ND
40
36.0
90
49-151
Vinyl chloride
ug/L
ND
20
10.6
53
70-156 M1
Xylene (Total)
ug/L
ND
60
63.0
105
63-158
1,2-Dichloroethane-d4 (S)
%
90
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2839242
92469069002
Dup
Parameter
Units
Result
Result
RPD
Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
1,1,1-Trichloroethane
ug/L
ND
ND
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
1,1,2-Trichloroethane
ug/L
ND
ND
1,1-Dichloroethane
ug/L
34.7
30.9
12
1,1-Dichloroethene
ug/L
ND
ND
1,2,3-Trichloropropane
ug/L
ND
ND
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
SAMPLE DUPLICATE: 2839242
Parameter
Units
92469069002
Result
Dup
Result
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
1,2-Dibromoethane (EDB)
ug/L
ND
ND
1,2-Dichlorobenzene
ug/L
5.1
5.3
1,2-Dichloroethane
ug/L
2.3
2.0
1,2-Dichloropropane
ug/L
3.0
2.9
1,4-Dichlorobenzene
ug/L
7.6
7.5
2-Butanone (MEK)
ug/L
20.5
17.9
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
41.5
35.4
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
.84J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
2.4
2.5
Chloroethane
ug/L
1.8
1.5
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
54.0
47.5
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
m&p-Xylene
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
o-Xylene
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
.67J
Toluene
ug/L
ND
.52J
trans-1,2-Dichloroethene
ug/L
ND
.79J
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
1.5
1.5
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
7.2
6.3
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
97
92
4-Bromofluorobenzene (S)
%
100
99
Toluene-d8(S)
%
100
97
RPD Qualifiers
3
13
2
1
14
16
v1
IK
I K,v2
v1
4
17 IK
13
0
13
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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[phone]
QUALITY CONTROL DATA
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
QC Batch: 530451 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92469061001, 92469061002, 92469061003
METHOD BLANK: 2832866
Matrix:
Water
Associated Lab Samples:
92469061001, 92469061002, 92469061003
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
03/13/20 15:38
1,2-Dichloroethane-d4 (S)
%
97
50-150
03/13/20 15:38
Toluene-d8 (S)
%
98
50-150
03/13/20 15:38
LABORATORY CONTROL SAMPLE: 2832867
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 21.0 105 70-130
1,2-Dichloroethane-d4 (S) % 90 50-150
Toluene-d8(S) % 97 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2832868
2832869
MS
MSD
92468855001 Spike
Spike MS MSD MS
MSD
% Rec
Parameter
Units Result Conc.
Conc. Result Result % Rec
% Rec
Limits RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 191 80
80 269 274 97
103
50-150 2
1,2-Dichloroethane-d4 (S)
%
93
96
50-150
Toluene-d8(S)
%
99
100
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 03/27/2020 01:25 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 23

Pace Analytical Services, LLC
lac,
Analyilcal ® 9800 Kincey Ave. Suite 100
Huntersville, NC 28078
www.pacelabs.com [phone]
QUALIFIERS
Project: Holbrooks Road Landfill
Pace Project No.: 92469061
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IH This analyte exceeded secondary source verification criteria high for the initial calibration. The reported results should be
considered an estimated value.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Holbrooks Road Landfill
92469061
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92469061001
HRSA 2
EPA 3010A
531025
EPA 6010D
531052
92469061002
HRSA 3
EPA 3010A
531025
EPA 6010D
531052
92469061003
HRSA 4
EPA 3010A
531025
EPA 6010D
531052
92469061001
HRSA 2
EPA 3010A
531033
EPA 6020B
531056
92469061002
HRSA 3
EPA 3010A
531033
EPA 6020B
531056
92469061003
HRSA 4
EPA 3010A
531033
EPA 6020B
531056
92469061001
HRSA 2
EPA 8260D
531753
92469061002
HRSA 3
EPA 8260D
531753
92469061003
HRSA 4
EPA 8260D
531753
92469061001
HRSA 2
EPA 8260D Mod.
530451
92469061002
HRSA 3
EPA 8260D Mod.
530451
92469061003
HRSA 4
EPA 8260D Mod.
530451
Date: 03/27/2020 01:25 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 23

— a ceAna! rcal
_ -- -
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
_ _DocumentNo.:— ___ --..--
___ lssuingAuthor.ity:_- _..-_---
Laboratory receiving samples:
Asheville ❑ Eden❑
Sample Condition Client Name:
Courier: [-]Fed Ex []UPS
Greenwood ❑
❑ Commercial ace ❑1
Custody Seal Present? []Yes �o Seals Intact?
Huntersville L'J Raleigh[] Mechanicsville❑
140jeaM H : JL4bUUb1
[]client 1111111111111111111111
92459061
Date/Initials Person Examining Contents: zo yM P
Packing Material: ❑Bubble Wrap ❑Bubble Bags QNone ❑ Other Biological Tissue Frozen?
DL.'qPS
her:
—
[]Yes
Thermometer: Dyes ❑No [rN/A
❑IR Gun ID: 92TO60 Type of Ice: Erwet [—]Blue ❑None
Cooler Temp ('Ci: W Correction Factor: Add/Subtract ('C) 0.0
Temp should be above freezing to 6'C
Cooler Temp Corrected (°C):
❑Samples outof temp criteria.5amples on ice, cooling process
hasbegun
USDA Regulated Sall ([a N/A, water sample)
Did samples originate In a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign sowce (internationally,
nYPs nNn Indudlne Hawaii and Puerto Rico)? nYes nNo
Comments/Dlscrepancy:
chain of Custody Present?-i'"' <
[Yes
❑Na
❑NIA
1.
Samples Arrived within Hold Time?
[31es
❑No
El N/A
2.
short Hold Time Analysis (<72-. ir:)?
❑Yes
QNo
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
D60
❑N/A
4.
Sufficient Volume?
0-Yes
[]No
[-I N/A
5.
Correct Containers Used?
-Pace Containers Used?
❑i Fes
Q�es
[]No
❑No
❑N/A
❑N/A
6.
Containers intact?
QYes
❑No
❑N/A
7,
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
l&/A
B-
Sample Labels Match COC?
❑Yes
[]No
❑N/A
9.
Y
-Includes Date/Tirne/ID/Analysis Matrix:
Headspace in VOA Vials (>S-6mm)?
❑Yes
CNo
❑N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
❑Yes
❑Na
❑/ No
❑N/A
[]N/A
11.
COMMENTS/SAMPLE DISCREPANCY field Data Required? [_]Yes [—]No
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split Containers:
Date:
Date:
Page 21 of 23

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aWnavical
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page I of 2
Document No. -
Issuing Authority:
*Check mark top half of box if pH and/or dechlorination is Project #1
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, 011 and Grease, DRO/8015 (water) DOC, LLHg I
**Bottom half of box is to Ilst number of bottle Qj\ \1;0—
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31
pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
bate preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot d
Note: Whenevef there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Carolina ❑EHNR Certification Office (ire.
Out of hold, Incorrect preservative, out of temp, incorrect containers.
Page 22 of 23

N
C
0
O
WITEM
m m e o n
C
0o _m n cj
o -
n ➢-__-
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a Q 0
2
2
2
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3 0 W C
3 N m n
n ;y C w
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C Z A
m m m
C o0 Y
En y
a
z
Y
N
rn m
A A
\ m
1
m
T
fG
a
TEMP in C
Received on
Ice
(YIN)
Sealed
Eocle�
(YIN)
Samples
Intact
(YIN)
0
'o
m
S
m m
o a
�• O
rt
m
yk z
o 7
IL
MATRIR CODE (see valid codes to left)
3
� n
#
C W
c
3 8
6
SAMPLE TYPE (G=GRAB C=COMP)
ox
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`S)
D
m
F
3
o
m
w
F
7
�
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v
a
F!
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W
m O
m
SAMPLE TEMP AT COLLECTION
# OF CONTAINERS
Unpreserved
b
rq
V1
a
H250A
HNO3
HC1
NaOH
Na2S203
c'
N
Methanol
Other
Analyses Test
YIN
Metals by 6D1016020
8260
8260SIM 1,4-Dioxare
Trip BLANK
Residual Chlorine {Y!N)
1-0
3,
n
CD
rn
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7
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Page 23 of 23