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MO-88110_88110_CA_MRP_20200326_Semiannual Monitoring Report
JACOBS March 26, 2020 Delivered via FedEx Overnight Ms. Trudy Beverly North Carolina Department of Environmental Quality Division of Waste Management Underground Storage Tank Section 610 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 www.jacobs.com Subject: Semiannual Monitoring Data Submittal (October 2019 and January 2020 Monitoring Events) Plantation Pipe Line Company Poplar Tent Road Site Concord, Cabarrus County, North Carolina NCDEQ Groundwater Incident No. 88110 Dear Ms. Beverly, On behalf of Plantation Pipe Line Company (Plantation), this Semiannual Monitoring Data Submittal for the subject site has been prepared in accordance with the Corrective Action Plan Addendum (CH2M, 20141). The following semiannual monitoring activities were conducted during this reporting period: • Groundwater gauging and monitoring event in October 2019 Soil vapor monitoring event at Lots 6 and 7 in October 2019 • Groundwater monitoring event in January 2020 On behalf of Plantation, Jacobs met with the North Carolina Department of Environmental Quality (NCDEQ) on April 30, 2019, to discuss site remediation progress and a proposed path forward. During that meeting, NCDEQ agreed to allow suspension of biosparging and soil vapor extraction (SVE) system operations for one year to monitor for the potential rebound of petroleum constituents under static groundwater conditions. Accordingly, biosparging and SVE system operations were suspended on May 1, 2019. Quarterly monitoring events began on July 30, 2019, and will continue through April 2020. Groundwater Gauging and Monitoring Liquid levels in site monitoring wells were gauged on October 14, 2019. The locations of the monitoring wells are shown on Figure 1. Groundwater elevation data, including supplemental gauging data collected to monitor light nonaqueous phase liquid (LNAPL) thicknesses, are presented in Table 1. LNAPL was only detected in two wells (PZ-1 and RW-9) at thicknesses of less than 0.3 foot in October 2019. 1 CH21VI HILL. 2014. Corrective Action Plan Addendum, Plantation Pipe Line Company Poplar Tent Road Site, Concord, Cabarrus County, North Carolina, NCDENR Incident No. 88110. January 20. Jacobs Engineering Group Inc. PPS0325202135CLT Ms. Trudy Beverly March 26, 2020 Page 2 of 3 JACO BS Groundwater samples were collected from 18 monitoring wells and surface water samples were collected from three locations (SW-101, SW-102, and SW-103) on October 15, 2019. Additionally, quarterly groundwater samples for rebound monitoring were collected from six monitoring wells on January 22, 2020. Groundwater and surface water samples were sent to SGS Accutest Laboratories in Scott, Louisiana (SGS Accutest) for analysis of benzene, toluene, ethylbenzene, xylenes (BTEX), and naphthalene by U.S. Environmental Protection Agency (EPA) Method 8260B. Table 2 presents a summary of the semiannual groundwater and surface water analytical data. Analytical laboratory reports are included in Attachment A. Analytical results for BTEX and naphthalene are presented on Figure 2 for the water table wells and surface water locations, and on Figure 3 for the deep and transition zone wells. Previous monitoring activities have also included collection of groundwater samples from nearby water supply wells WSW-13 and WSW-14 (Figure 4). However, the property containing WSW-14 was unoccupied in October 2019, and a sample was not collected. On October 15, 2019, samples were collected from WSW-13 and shipped under chain -of -custody control to both SGS Accutest in Scott, Louisiana and TestAmerica in Pittsburgh, Pennsylvania for analysis of BTEX and naphthalene by EPA Method 8260B. Groundwater samples were collected directly from the wellhead prior to any pressure tanks or water conditioning systems. The well was purged for 15 minutes prior to sample collection. Table 2 presents a summary of the semiannual water supply well analytical data. Analytical laboratory reports are included in Attachment A. Soil Vapor Monitoring Soil vapor samples were collected from vapor monitoring points SV-5R, SV-10R2, SV-12R, and SV-14R (Figure 1) on October 17, 2019, and shipped under chain -of -custody control to Eurofins TestAmerica in Knoxville, Tennessee, for analysis of BTEX by EPA Method TO-15 and naphthalene and 2-methyl naphthalene by EPA Method TO-17. A soil vapor sample could not be collected from soil vapor monitoring point SV-13R during the October 2019 monitoring event because water was observed in the sample tubing during the vapor purge, indicating that water, likely perched groundwater from infiltrating precipitation, was present in the screened interval of the soil vapor monitoring point. The results of this monitoring event are provided in Table 3. Analytical laboratory reports are included in Attachment A. On November 11, 2019, on behalf of Plantation, Jacobs provided the analytical results from the October 2019 soil vapor monitoring event to the homeowners of Lots 6 and 7. Future Work A discussion of the analytical results, historical data trends, and remedial system operational data will be provided in a comprehensive annual monitoring report following the annual groundwater monitoring event scheduled for April 2020. If you have any questions regarding this data submittal or need additional information, please call me at 704.543.3285, or Jerry Aycock with Plantation at 770.751.4165. Regards, -i%&'O&A-pc Mike Skeean, P.E. Senior Project Manager PPS0325202135CLT Ms. Trudy Beverly March 26, 2020 JACOBS' Page 3 of 3 Copies to: Mr. Jerry Aycock, P.E., PPL—AO (via electronic transmittal) Ms. Jessica Toll, Esq., PPL—LKWD (via electronic transmittal) Mr. Ric Morton, Esq., WCSR (via electronic transmittal) Ms. Susan Cooper, Esq., WCSR (via electronic transmittal) Mr. Brian Pace, Laureldale, LLC (via electronic transmittal) Mr. and Mrs. Derek Wilson, Property owner of Lot 6 (via electronic transmittal) Mr. and Mrs. Nicholas Nestora, Property owner of Lot 7 (via electronic transmittal) Mrs. Pam Mercer (via electronic transmittal) Mr. Edward Perez, D.R. Horton, Inc. (via electronic transmittal) Mr. Jason Goldstein, Amec Foster Wheeler (via electronic transmittal) Attachments: Table 1 — Liquid Level Measurements (October 2019) Table 2 — Groundwater, Water Supply Well, and Surface Water Analytical Results (October 2019 and January 2020) Table 3 — Soil Vapor Analytical Results (October 2019) Figure 1 — Biosparging/SVE System As -Built Figure 2 — Shallow Groundwater and Surface Water Analytical Results, BTEX and Naphthalene (October 2019 and January 2020) Figure 3 — Deep Groundwater Analytical Results, BTEX and Naphthalene (October 2019 and January 2020) Figure 4 — Water Supply Wells Attachment A — Laboratory Analytical Data PPS0325202135CLT Tables Table 1. Liquid Level Measurements (October 2019) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina M W-1 op of Casing 676.65 Ground Surface Elevation 677.01 Total Well Depth 38 Screened Interval 23-38 10/14/2019 Depth 26.32 Depth to Water NM Groundwater 650.33 NM NA M W -1 T 677.15 677.46 78 68-78 10/14/2019 26.84 NM 650.31 NM NA M W-2 667.04 667.37 28 13-28 10/14/2019 18.15 NA 648.89 ND NA M W-3 658.66 659.13 23 8-23 10/14/2019 12.99 NM 645.67 NM NA M W -3D 659.04 659.28 52 47-52 10/14/2019 12.75 NM 646.29 NM NA M W-4 649.49 649.95 17 2-17 10/14/2019 4.71 NM 644.78 NM NA M W -4D 650.56 650.95 50 45-50 10/14/2019 5.49 NM 645.07 NM NA M W-5 651.23 651.90 23 8-23 10/14/2019 6.81 NM 644.42 NM NA M W-6 663.38 664.23 28 13-28 10/14/2019 16.61 NM 646.77 NM NA M W-7 655.82 656.28 27 12-27 10/14/2019 12.01 NM 643.81 NM NA M W -7D 655.93 656.17 55 50-55 10/14/2019 12.06 NM 643.87 NM NA M W-8 646.65 647.10 17 2-17 10/14/2019 3.08 NM 643.57 NM NA M W -8D 648.13 648.42 47 42-47 10/14/2019 3.99 NM 644.14 NM NA M W -8T 647.19 647.57 95 85-95 10/14/2019 3.13 NM 644.06 NM NA M W-9 662.09 662.48 25 10-25 10/14/2019 15.49 NA 646.60 ND NA M W -10 653.30 653.83 20 5-20 10/14/2019 4.81 NM 648.49 NM NA M W -11 653.47 654.03 19 4-19 10/14/2019 5.61 NM 647.86 NM NA M W -11 D 654.28 654.49 43 38-43 10/14/2019 5.69 NM 648.59 NM NA MW-12 664.15 664.86 27 12-27 10/14/2019 Unable to locate M W -13 650.61 650.92 17 2-17 10/14/2019 1.85 NM 648.76 NM NA M W -14 673.64 673.97 33 18-33 10/14/2019 24.49 NM 649.15 NM NA M W -15 659.66 659.93 22 7-22 10/14/2019 11.12 NM 648.54 NM NA M W -16 656.27 656.52 19.5 4.5-19.5 10/14/2019 7.68 NM 648.59 NM NA M W -17 651.07 651.17 19 4-19 10/14/2019 7.21 NM 643.86 NM NA M W -17D 650.71 651.27 50 45-50 10/14/2019 7.09 NM 643.62 NM NA M W -18 649.38 649.57 17 2-17 10/14/2019 1.02 NM 648.36 NM NA M W -19 644.59 644.62 17 2-17 10/14/2019 2.66 NM 641.93 NM NA M W -19D 644.59 644.89 43 38-43 10/14/2019 2.90 NM 641.69 NM NA M W -20 651.88 652.10 26 11-26 10/14/2019 9.14 NM 642.74 NM NA M W -20D 651.39 651.54 49 44-49 10/14/2019 9.10 NM 642.29 NM NA M W -23 650.81 651.03 17 2-17 10/14/2019 6.56 NM 644.25 NM NA PT-1 660.45 660.73 22 7-22 10/14/2019 11.62 NM 648.83 NM NA PT-2 659.70 660.19 22 7-22 10/14/2019 10.90 NM 648.80 NM NA PT-4 662.94 663.34 25 10-25 10/14/2019 13.59 NA 649.35 ND NA PT-5 656.19 656.41 19 4-19 10/14/2019 7.62 NM 648.57 NM NA PT-6 656.86 657.13 19 4-19 10/14/2019 8.20 NM 648.66 NM NA PZ-1 669.46 669.77 28 13-28 10/14/2019 20.71 20.53 648.75 20.49 0.22 PZ-2 668.13 668.39 28 13-28 10/14/2019 19.22 NA 648.91 ND NA PZ-3 666.36 666.70 25 10-25 10/14/2019 17.79 NA 648.57 ND NA PZ-5 667.22 667.64 25 10-25 10/14/2019 18.32 NA 648.90 ND NA PZ-6 667.37 667.74 25 10-25 10/14/2019 18.53 NA 648.84 ND NA PZ-7 669.10 669.49 25 10-25 10/14/2019 20.10 NA 649.00 ND NA PZ-8 673.36 673.84 33 18-33 10/14/2019 23.90 NM 649.46 NM NA PPS0325202135CLT Page 1 of 2 Table 1. Liquid Level Measurements (October 2019) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina PZ-12 op of Casing 663.15 Ground Surface Elevation 663.45 Total Well Depth 23 Screened Interval 8-23 10/14/2019 Depth to Water Groundwater Depth 14.40 NM 648.75 NM NA PZ-15 673.62 673.94 30 15-30 10/14/2019 24.32 NA 649.30 ND NA P-2 640.29 640.81 7 5-7 10/14/2019 Unable to locate RW-1 668.39 668.86 30 10-30 10/14/2019 19.81 NA 648.58 ND NA RW-2 667.44 667.86 30 10-30 10/14/2019 17.99 NA 649.45 ND NA RW-3 667.31 667.85 30 10-30 10/14/2019 17.86 NA 649.45 ND NA RW-4 667.48 667.82 30 10-30 10/14/2019 17.94 NA 649.54 ND NA RW -5a 669.86 670.69 40 20-40 10/14/2019 20.59 NA 649.27 ND NA RW-6 669.67 671.02 30 10-30 10/14/2019 20.62 NA 649.05 ND NA RW -7a 669.51 670.04 40 20-40 10/14/2019 20.43 NA 649.08 ND NA RW-8 668.49 669.91 30 10-30 10/14/2019 19.60 NA 648.89 ND NA RW-9 669.62 671.09 30 10-30 10/14/2019 20.82 20.58 648.80 20.53 0.29 RW-10 667.92 669.24 29.5 9.5-29.5 10/14/2019 18.95 NA 648.97 ND NA RW-11 a 668.96 669.66 40 20-40 10/14/2019 > 18.83 DRY RW -12 668.82 670.46 30 10-30 10/14/2019 19.73 NA 649.09 ND NA RW -13 665.11 666.70 30 10-30 10/14/2019 16.29 NA 648.82 ND NA RW -14 668.00 669.35 30 10-30 10/14/2019 19.08 NA 648.92 ND NA RW -15 666.55 668.13 30 10-30 10/14/2019 17.85 NA 648.70 ND NA RW-16a 667.46 668.09 40 20-40 10/14/2019 18.26 NA 649.20 ND NA Notes: a Well installed at approximately 40-degree angle; depth to water has been calculated to represent vertical depth. When applicable, depth to water corrected using 82% of LNAPL thickness subtracted from uncorrected depth to water. ft bgs = feet below ground surface ft btoc = feet below top of casing ft msl = feet above mean sea level LNAPL = light nonaqueous phase liquid NA = not applicable ND = not detected using an oil -water interface probe with an accuracy of 0.01 foot NM = not measured with an oil -water interface probe PPS0325202135CLT Page 2 of 2 Table 2. Groundwater, Water Supply Well, and Surface Water Analytical Results (October 2019 and January 2020) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina MW 2 .. 10/15/2019 0.23 J 0.41 J ND < 1.0 1.3 J 0: 1.7 J 01/22/2020 ND < 1.0 ND < 1.0 ND < 1.0 0.58 J ND < 5.0 M W-3 10/15/2019 2.4 0.24 J ND < 1.0 ND < 2.0 9.2 01/22/2020 2.3 0.38 J ND < 1.0 0.46 J 11.8 MW-31D 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-4 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-41D 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-8 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-81D 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 01/22/2020 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-8T 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW 9 10/15/2019 0.41 J ND < 1.0 ND < 1.0 ND < 2.0 1.6 J 01/22/2020 0.35 J ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 MW-10 10/15/2019 4.3 ND < 1.0 ND < 1.0 ND < 2.0 0.72 J 01/22/2020 0.34 J ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 MW-14 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 MW-15 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-16 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-17 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-17D 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 MW-18 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 MW-23 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 PZ-12 10/15/2019 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 01/22/2020 ND<1.0 ND<1.0 ND<1.0 ND<2.0 ND<5.0 WSW-13 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 NCGWQS 1 600 600 500 6 SW-101 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 SW-102 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 SW-103 10/15/2019 ND < 1.0 ND < 1.0 ND < 1.0 ND < 2.0 ND < 5.0 Surface Water Standard 51a'` 97' 11b 670' 12' Notes: NCSWQS - North Carolina Administrative Code Section 213 Surface Water Quality Standards - Human Health b NCSWQS - North Carolina Administrative Code Section 213 Surface Water Quality Standards - Freshwater Aquatic Life ° Human health standard is based on consumption offish only North Carolina Protective Values for Surface Waters - Freshwater Aquatic Life Bold = exceeds NCGWQS pg/L = micrograms per liter J = estimated value NCGWQS = North Carolina Administrative Code Section 2L Groundwater Quality Standards ND = not detected above reporting limit PPS0325202135CLT Page 1 of 1 Table 3. Soil Vapor Analytical Results (October 2019) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina Benzene Toluene Ethylbenzene rn,p-Xylene o-Xylene Naphthalene naphthalene Sample ID DD SV-5R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.7b ND <2.6b SV-5RD-101719a 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.7b ND <2.6b SV-14R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.7b ND <2.6b SV-10R2-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.7b ND <2.6b SV-12R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.7b ND <2.6b Soil Gas Screening Criteria° 120 34,800 374 695 695 20.9 NS Soil Gas Screening Criteria 120 35,000 370 700 700 21 NS Notes: a Duplicate sample collected on SV-5R for both TO-15 and TO-17 analysis. bThe method detection limit is presented for samples analyzed by TO-17 in October 2019. February 2018 NC Division of Waste Management Residential Vapor Intrusion Screening Levels for Sub -Slab and Soil -Gas (AF = 0.03). https://files.nc.gov/ncdeq/Waste%20Management/DWM/SF/RiskBasedRemediation/Feb2018_Res_VISLs.pdf d EPA Vapor Intrusion Screening Levels (VISLs) Calculator (AF = 0.03), TRL = 10-5 or THQ = 0.2, accessed July 25, 2018. https://epa-visl.ornl.gov/cgi-bin/visl_search pg/m3 = micrograms per cubic meter AF = attenuation factor J = estimated value NA = not analyzed ND = not detected NS = no soil gas screening criteria available THQ = target hazard quotient TRL = target risk level PPS0325202135CLT Page 1 of 1 Figures 24'p / LLB TREE 1,000 GALLON IUU TRANSFORMER STORAGE TAf £ \ CONRETE PAD �a 0 T BIOSPARGING AND SVE \ BUILDING / EQUIPMENT BUILDING J HOUSE SVE/BIOSPARGING CONVEYANCE LINES 1/ I TRENCH 1 1 36 I I Kam) WALNUT C�JMF I I I II \ J TREE O I / UNDERGROUND; D G — �I DRAIN I BIOSPARGING D �\ CONVEYANCE LINES 6" PLASTIC j UNDERGROUND \\ \ \\ TRENCH DRAIN \\ fII OUTLET I PZ-14 \ GATE ^RAVEL -- / EXISTING DPE TRENCH \\\\\ — W— 4 -� HBS-1 SV-15�1 `''�------------- ---------------- -- -- -- ------ --- PZ_1 _ - --- LOCATION OF HBg 2 1976 RELEASE — ° ro—ro—ro— RW 99 1 o - - — z MW-1 T PZ-8 _ 3 HORIZONTAL BIOSPARGING WELL 298, RISER 216' SCREEN 514' TOTAL 60' DEPTH FROM ENTRY POINT OR ZO T L BIOSPARGING WELL 304' RISER 298' SCREEN 602' TOTAL 60' DEPTH FROM ENTRY POINT FORMER DPE WELLS OPERATING AS SVE (RW-7,RW-15,RW-16, RW-12, RW-13 AND SVE / BIOSPARGING CONVEYANCE LINES ►j. (HDD UTILITY BORE) \ DRAINAGEWAY 430' TOTAL 21.5' MAX. DEPTH II \MW-11 SVE/BIOSPARGING \\\ �W-11D 4 C-1 ACCESS \ VAULT \\ \ \ SV-16A ` SV-16 • W-75 PT— W-16 MW-9-------------------------- - � -- —°—°—°—°°—EMw�O o—°—°—° MW-18 k2I \\ \'\ \S----------- PZ-5 — a LOT 6 LOT 7 0 q,. 6901111 V,N HORIZONTAL SOIL VAPOR EXTRACTION WELL 18' RISER 120' SCREEN 136' TOTAll T-13' DEPTH frNJ P,191 zzz m i SURVEY BY TAYLOR WISEMAN & TAYLOR 20' SD I -4D MW-4 �V-,1,o. SV�1 V-10R SV-1 V SVE- V-1 0 0 o-_ SV-14 SVE-3 TRENCH (TO SVE CONVEYANCE LINES :LEANOUTS/VERTICA BIOSPARGING WELLS) 18" 1 DEPTH DEEP VERTICAL BIOSPARGING WELLS 7,1'-74' DEPTH _ MW-70 ' 7776�- MIDDLECREST DRIVE IIIWARGING 60' PUBLIC R/W CONVEYANCE I TRENCH s/ LEGEND O$ SANITARY SEWER MANHOLE FIRE HYDRANT CURB INLET CONCRETE CURB Y LIGHT POLE CONCRETE WOOD WALKWAY — — — PROPERTY LINE ----- RIGHT OF WAY — SANITARYSEWER ""— WATERLINE -------- STORM SEWER EXISTING 26" U/G GASOLINE LINE —°—°—G°— EXISTING 10" U/G FIBER OPTIC LINE EXISTING 14" U/G DIESEL FUEL LINE UNDERGROUND ELECTRIC OVERHEAD ELECTRIC TREE LINE SMW-8 SHALLOW MONITORING WELL Q�MW-80 DEEP MONITORING WELL ®MW-8T TRANSITION ZONE MONITORING WELL OPZ-9 PIEZOMETER +SW-101 SURFACE WATER SAMPLING LOCATION ❑° RECOVERY WELL — + — DPE ANGLED WELL 4SV-5R SOIL VAPOR MONITORING POINT SVE-2 ❑ VERTICAL SVE WELL SVE ACCESS VAULT ■ SOURCE AREA SVE WELL VERTICAL BIOSPARGING WELL CONVEYANCE PIPING ASSOCIATED WITH THE BIOSPARGING SYSTEM CONVEYANCE PIPING ASSOCIATED WITH THE SVE SYSTEM SCREENEDINTERVAL = INSTALLATION VIA HDD / MW-19D 1 \ /0 30 60 120 APPROXIMATE SCALE IN FEET Figure 1. Biosparging/SVE System As -Built Poplar Tent Rood Site Plantation Pipe Line Company JACOBS® Concord, North Carolina KinderMorgan\358526PoplarTent\Reports\Groundwater Monitoring Reports\2018 Annual Report\Figures\CADD\FigureOl-BS-SVE-AsBuilt_Revl.dwg MW-15 10/15/2019 B ND<1.0 /� _72 TRANSFORMER T ND < 1.0 Il / / l/ / / / & /11, CONCRETE PAD E ND < 1.0 II X ND<2.0 MW-1,3 / N ND<5.0 I I . // \ II MW-9 1 1 1 SVE/BIOSPARGING SW-101 MW-2 10/15/2019 1/22/2020 I /. II I I I CONVEYANCE LINES MW-16 10/15/2019 B ND < 1.0 T ND < 1.0 E ND < 1.0 X ND < 2.0 N ND < 5.0 )/15/2019 1/22/2020 B 0.41J 0.35J (HDDUTILITY BORE) \ 0.23J ND<1.0 T ND<1.0 ND<1.0 ii ND<1.0 ND<1.0 E ND<1.0 ND<1.0 u/ �I(S 0.411 ND<1.0 X ND<2.0 ND<2.0 I I \ 1.3J 0.58J EA N 1.6J ND<5.0 II I I s\ 11I \ ---- ------� 1.7J ND<5.0 ------ I---� = _ _ _ _ - - - _ - _ tea_ \ " C2 ,y - -�1v1W-17D / u MW-14 C- " 10/15/2019 �� �78 ' B ND < 1.0 PZ-14 Pz-13 c ca F T ND < 1.0-EXISTING DPE c _ � \ � ` VAULT - 14 SV-16A E ND < 1.0 � X ND <2.0 _ _ _ 1- SV-15�1 �\ N \\ Mw-75 - - - - - - - - - ------------ N ND <5.0-------- - - --- --_\ -- 16B ------ --- Ift\ a PZ-1.Se - __-__-_ - ---- Mw-g -- °_°° ---------------�° °s R 6 / PZ= „MW-70 1976 RELEASE`°� MW-1 1�-------__-_ ------ MW-7T PZ-8 PZ-12 10/15/2019 1/22/2020 B ND < 1.0 ND < 1.0 T ND < 1.0 ND < 1.0 E ND < 1.0 ND < 1.0 X ND<2.0 ND<2.0 N ND<5.0 ND<5.0 G� OPLAR TENT R /�GOE I--- AID VPRIPg rA 1� I'I ✓-3 19 1/22/2020 2.3 ND < 1.0 0.38 J 0.46 J 118 0' S D E 5". Z-12 M -3 MW-3D SVE-1 \ ASV-10 Sv_SV-5R(o�� ` s 0 SV- SV-1 `=\ m SURVEY BY TAYLOR WISEMAN & TAYLOR MW-8 10/15/2019 B N D < 1.0 T N D < 1.0 E N D < 1.0 X N ND<2.0 ND<5.0 SW-101 10/15/2019 B ND<1.0 T ND<1.0 E ND<1.0 X ND < 2.0 N ND < 5.0 MW-10 10/15/2019 1/22/2020 B 4.3 0.34 J T ND<1.0 ND<1.0 E ND<1.0 ND<1.0 X ND<2.0 ND<2.0 N 0.72J* ND<5.0 DRAINAGEW PLANTATION PIPE LIN O. EASEMENT __- - \ - ---- ----- MW-18 50' \ -MW-5 w- MW-4_-__ _ _ ___- PLANTATION PIPE LINE CO. N 16 es-7 SW-102 pp B 2 \ �W 2 W-8D suE- M -8T_8 12 MW-1 E-3 BS 4 \ BS-3 - W-17D MW-18 10/15/2019 B ND < 1.0 T ND < 1.0 E N D < 1.0 X ND<2.0 N ND<5.0 MW-4 10/15/2019 B N D < 1.0 T ND < 1.0 E ND < 1.0 X ND<2.0 N ND<5.0 SW-102 10/15/2019 B ND < 1.0 T ND < 1.0 E ND < 1.0 X ND<2.0 N ND<5.0 B ND < 1.0 T < 1.0 E ND < 1.0 LND X ND<2.0 N ND<5.0 MW-17 10/15/2019 B ND<1.0 T ND<1.0 E ND<1.0 X N D < 2.0 N ND < 5.0 MW-20� \ MW-1 � \ \ �m MW-204 MW-19D SW-103 10/15/2019 B ND < 1.0 T ND < 1.0 E ND < 1.0 X ND < 2.0 N ND < 5.0 LEGEND SMW-8 SHALLOW MONITORING WELL BMW-8D DEEP MONITORING WELL ®MW-8T TRANSITION ZONE MONITORING WELL OPZ-9 PIEZOMETER +SW-101 SURFACE WATER SAMPLING LOCATION 68S-3 VERTICAL BIOSPARGING OR SVE WELL ❑° RECOVERY WELL - + - DPE ANGLED WELL B BENZENE T TOLUENE E ETHYLBENZENE x XYLENE N NAPHTHALENE (8260 B) i ESTIMATEDVALUE NCGW4S NORTH CAROLINA GROUNDWATER QUALITY STANDARDS O SANITARY SEWER MANHOLE a.3 INDICATES EXCEEDANCE OF NCGWQS FIRE HYDRANT CURB INLET CONCRETE CURB LIGHT POLE CONCRETE WOOD WALKWAY PROPERTY LINE RIGHT OFWAY (R/W) -- -- -- UTILITY EASEMENT s s s s SANITARY SEWER WATERLINE EXISTING 26 U/G GASOLINE LINE ° EXISTING 10 U/G FIBER OPTIC LINE EXISTING 14" U/G DIESEL FUEL LINE STORM SEWER UNDERGROUND ELECTRIC - - OVERHEAD ELECTRIC TREE LINE NOTES: 1. ALL CONCENTRATIONS REPORTED IN i1g/L (I Lg/L - MICROGRAMS PER LITER) 2. ND <1 - ANALYTE NOT DETECTED ABOVE LABORATORY REPORTING LIMIT 3. MONITORING WELLS MW-12, PZ-4, PZ-13, PZ-14 WERE BURIED DURING NEIGHBORHOOD CONSTRUCTION ACTIVITIES * DENOTES ANALYTICAL DATA FROM A DUPLICATE SAMPLE o7 0 30 60 120 SW-703 APPROXIMATE SCALE IN FEET Figure 2. Shallow Groundwater and Surface Water Analytical Results BTEX and Naphthalene (October 2019 and January 202 Poplar Tent Road Site Plantation Pipe Line Company JACOBS Concord, North Carolina KinderMorgan\358526PoplarTent\Reports\Groundwater Monitoring Reports \ 2020 Semi -Annual Report\Figures\CADDFigure02-BTEX-NaphShaIlow _Oct_2019_ and_Jan_2020.dwg TRANSFORMER CONCRETE PAD MW-13 MW-3D 10/15/2019 B ND < 1.0 T ND < 1.0 E ND < 1.0 X ND < 2.0 N ND < 5.0 SURVEY BY TAYLOR WISEMAN & TAYLOR DRAINAGEWAY MW-4D 10/15/2019 B ND < 1.0 T ND < 1.0 E ND < 1.0 X ND<2.0 N ND < 5.0 �V��✓✓�I_vI%",.PI VI\I V1_ IV VV 60' PUBLIC R/W M W-8D 10/15/2019 1/22/2020 B ND < 1.0 ND < 1.0 T ND < 1.0 ND < 1.0 E ND < 1.0 ND < 1.0 X ND < 2.0 ND < 2.0 N ND < 5.0 ND < 5.0 MW-8T 10/15/2019 B ND < 1.0 T N D < 1.0 E N D < 1.0 X ND<2.0 N ND<5.0 M W-17D 10/15/2019 B ND<1.0 T ND<1.0 E ND<1.0 X ND < 2.0 N ND < 5.0 LEGEND SMW-8 SHALLOW MONITORING WELL Q�MW-SD DEEP MONITORING WELL ®MW-8T TRANSITION ZONE MONITORING WELL 0PZ-9 PIEZOMETER RECOVERY WELL DPE ANGLED WELL ® BS-3 VERTICAL BIOSPARGING OR SVE WELL B BENZENE T TOLUENE E ETHYLBENZENE X XYLENE N NAPHTHALENE (8260 B) i ESTIMATED VALUE NCGWQS NORTH CAROLINA GROUNDWATER QUALITY STANDARDS O SANITARY SEWER MANHOLE FIRE HYDRANT CURB INLET CONCRETE CURB LIGHT POLE 0 CONCRETE WOOD WALKWAY PROPERTY LINE RIGHT OF WAY (R/W) UTILITY EASEMENT --__--- SANITARY SEWER " WATER LINE EXISTING 26" U/G GASOLINE LINE EXISTING 10" U/G FIBER OPTIC LINE - EXISTING 14" U/G DIESEL FUEL LINE UNDERGROUND ELECTRIC OVERHEAD ELECTRIC STORM SEWER TREE LINE NOTES: 1. ALL CONCENTRATIONS REPORTED IN gg/L (µg/L - MICROGRAMS PER LITER) \ 2. ND<1.0 - ANALYTE NOT DETECTED ABOVE \�jr, ,r, LABORATORY REPORTING LIMIT MW-20� 15, m MW-19�q MW-20DQ� 1WW-19D� 2��S sW 1'j 0 30 60 120 \+ I I I APPROXIMATE SCALE IN FEET SG-2 Figure 3. Deep Groundwater Analytical Results BTEX and Naphthalene (October 2019 and January 2020) Poplar Tent Road Site Plantation Pipe Line Company JACOBS® Concord, North Carolina KinderMorgan\358526PoplarTent\Reports\Groundwater Monitoring Reports \ 2020 Semi -Annual Report\Figures\CADD\Figure03-BTEX-NaphDeep_Oct_2019 and Jan_2020.dwg 13 row- 1.2 = WSW-15\, 7`q_ 11 RF �.: r. I wsw-11 14 VVo �,� Pry Alm WSW-1 - - WSW-12 o +� Approximate Location of SitUhl 06 e N� WSW-3 , wsw 4 Villa es at Sk brook North Amenity Center WSW wsw 1 , \ .j wsw-s WSW-6 '! St0 eY+aw . i J Water Supply Well (WSW-1) (Approximate Location) Release Location oil Hunter Contour -10' Interval svllle Co . +� . cord Rd Drainageway qq County Boundary Approximate Parcel Boundary Q 1500' Radius Parcel Boundary Source: Cabarrus County GIS and Mecklenburg County GIS, accessed March 2, 2017 (All boundaries are approximate). N Figure 4. Water Supply Wells Contour Source: US Geological Survey, National Elevation Dataset (NED), 2013. Poplar Tent Road Site Aerial Imagery Source:Esri, DigitalGlobe, GeoEye, i-cubed, USDA, USGS, Plantation Pipe Line Company AEX, Getmapping, Aerogrid, IGN, IGP, swisstopo, and the GIS User Community, 0 100 200 400 600 800 Concord, North Carolina May 23, 2016, accessed September 6, 2017. Feet Note: All property boundaries are approximate. WSW-4 and WSW-5 are not 1 inch = 400 feet operational (electricity disconnected). JACOBSm ATL \\CANOPUS\GROUPS\GIS\00 PROM KINDER MORGAN\KM POPLARTENTRD\MAPS\FIGURE4 WATERSUPPLYWELLS10 3.MXD AUTHOR: MWACH 9/6/2017 Attachment A Laboratory Analytical Results JACOBS Memorandum 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 www.iacobs.com Subject Data Validation Summary — Plantation Pipe Line Poplar Tent Road Site Project Name Plantation Pipe Line Poplar Tent Road Site Attention Kelly Gutowski/CLT, Jacobs Mike Skeean/CLT, Jacobs From Tiffany Davis/GNV, Jacobs Date February 14, 2020 Copies to Juan Acaron/GNV, Jacobs 1. Introduction The purpose of this memorandum is to present the results of the data validation process for the groundwater samples collected at the Plantation Pipe Line Company (PPL) Poplar Tent Road. The samples were collected in October 2019 and January 2020. Samples were submitted to SGS North America Inc. in Scott, Louisiana for the following analyses: • SW8260B Volatile Organic Compounds (VOCs) These data were validated for compliance with the analytical method requirements. This process included a review of these data to assess the accuracy, precision, and completeness based upon procedures described in guidance documents such as the Environmental Protection Agency (EPA) National Functional Guidelines for Organic Data Review (EPA 2017). The Quality assurance/quality control (QA/QC) summary forms and data reports were reviewed and the resulting findings are documented within each subsection that follows. During the data validation, if QA/QC parameters were not within the acceptance limits, associated sample results were appended with a primary qualifying flag that indicated a possible anomaly with these data. The qualifying flags originated during the data review and validation processes. This qualification also included the use of secondary sub -qualifier flags. The secondary qualifiers provide the reasoning behind the assignment of a qualifier to these data. The definitions of the primary qualifiers are presented below. 2. Validation Flag Definitions The following primary qualifiers were used to qualify the data: [_]: Detected. The analyte was analyzed for and detected at the concentration shown. [J]: Estimated. The analyte was present but the reported value may not be accurate or precise. [U]: Undetected. The analyte was analyzed for but not detected above the method detection limit. [UJ]: Detection limit estimated. The analyte was analyzed for but qualified as not detected; the detection limit is estimated. [R]: Rejected. The data are not useable. [X]: Excluded. Data were not used due to another value being more appropriate. JACOBS5 Data Validation Summary — Plantation Pipe Line Poplar Tent Road Site I Organic Parameters 3.1 Quality Control Review The following list represents the QA/QC measures that were reviewed during the data quality evaluation procedure for organic data: • Holding Times — The holding times are evaluated to verify that samples were extracted and analyzed within holding times. • Blank samples — Method blank, equipment blank, and trip blank samples were provided for this project. Blank samples enable the reviewer to determine if an analyte may be attributed to sampling or laboratory procedures, rather than environmental contamination from site activities. • Surrogate Recoveries — Surrogate Compounds are added to each sample and the recoveries are used to monitor lab performance and possible matrix interference. • Lab Control Sample (LCS) — These samples are a "controlled matrix", laboratory reagent water, in which target compounds have been added prior to extraction/analysis. The recoveries serve as a monitor of the overall performance of each step during the analysis, including sample preparation. • Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples — Spike recovery is used to evaluate potential matrix interferences, as well as accuracy. Precision information is also determined by calculating the reproducibility between the recoveries of each spiked parameter. • Field Duplicate Samples — These samples are collected to determine precision between a native and its duplicate. This information can only be determined when target compounds are detected. 4. Volatile Organic Compound Analyses The QA/QC parameters for VOC analyses by SW-846 8260B for all samples were within acceptable control limits with the exceptions listed below. A brief overview of the data evaluation follows: 4.1 Holding Time All holding time requirements were met. 4.2 Field Duplicates Duplicate field samples were collected and submitted to the laboratory for analysis. There are two conditions under which the native and field duplicate are deemed outside acceptance criteria. For condition one, if a result for the native and field duplicate are less than five times the reporting limit, the two results must be within one times the reporting limit to meet acceptance criteria. In condition two, if the result is greater than five times the reporting limit, the two results must agree to within 20 percent relative percent difference to meet acceptance criteria. All field duplicate precision criteria were met. 4.3 Recoveries - Surrogate, MS/MSD and LCS/LCSD Surrogates, MS/MSD, and LCS/LCSD recoveries all met acceptance criteria with the exception of spiked sample MW-8 which did not meet RPD criteria between the MS and MSD for several target analytes. All sample results were non -detect, therefore no data were affected. 4.4 Analytical Blanks Toluene was detected in the equipment blank (0.44ug/L J) for October sampling. Naphthalene was detected in the method blank (0.38ug/L J) for October sampling and in the trip blank (0.87ug/L J) for January sampling. Affected data are qualified in Attachment 1. Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site JACOBS" 5. PARCC Precision is defined as the agreement between duplicate results, and was estimated by comparing duplicate MS recoveries, and field duplicate sample results. The precision between the native and field duplicate sample results for all analyses were within acceptable criteria indicating that the sample matrix did not interfere with the overall analytical process. Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter. In the case of VOC analysis, each of the samples were spiked with a surrogate compound with a known concentration before preparation. The surrogate and MS/MSD data provides a measure of the matrix effects as they may affect accuracy and precision of the analytical method. The LCS results demonstrate accuracy of the method. Spike recoveries were mostly within the method acceptance limits, showing no evidence of matrix interferences that affect the usability of the data. Representativeness criteria are a qualitative measure of the degree to which sample data accurately and precisely represent a characteristic environmental condition. Representativeness is a subjective parameter and is used to evaluate the efficacy of the sampling plan design. Representativeness was demonstrated by providing full descriptions in the project scoping documents of the sampling techniques and the rationale used for selecting sampling locations. Completeness is defined as the percentage of measurements that are judged to be valid compared to the total number of measurements made. There were no data rejected and or seen as not usable due to quality control or sampling issues. Comparability is another qualitative measure designed to express the confidence with which one data set may be compared to another. Factors that affect comparability are sample collection and handling techniques, sample matrix type, and analytical method. Comparability is limited by the other PARCC parameters because data sets can be compared with confidence only when precision and accuracy are known. Data from this investigation are comparable with other previous data collected at the site due to the laboratories use of EPA or appropriate methods to analyze the samples and supported by the results of the laboratory's analytical reports. 6. Conclusion A review of the analytical data submitted regarding the investigation of PPL Poplar Tent Road groundwater sampling event in October 2019 and January 2020 by Jacobs has been completed. The validation demonstrated that the analytical systems were in control and all data results can be used in the decision -making process. Attachment 1. Summary of Affected Data, October 2019 and January 2020 Parameter Class Analytical Method Parameter Sample ID Matrix Lab Result Lab Qual Final Result Final Qual Units Reasons VOCs SW8260B Naphthalene MW-2 Water 0.57 J 5 U pg/L TBL VOCs SW8260B Naphthalene PZ-12 Water 0.51 J 5 U pg/L TBL VOCs SW8260B Naphthalene MW-9 Water 2.2 J 5 U pg/L TBL Notes: Only the January 2020 data were affected during data validation. pg/L = micrograms per liter TBL = Detection in trip blank less than reporting limit VOC = volatile organic compound ffm Scott, LA The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0 Automated Report Technical Report for Kinder Morgan CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC 03158700. B. PN. GEN. PT. EM SGS Job Number: LA58555 Sampling Date: 10/ 15/ 19 Report to: Jacobs CH2M 14120 Ballantyne Corporate Place Charlotte, NC 28277 mike. skeean@jacobs. com; kelly. gutowski@jacobs. ATTN: Mike Skeean Total number of pages in report: 47 Ac Fp Ar . Test results contained within this data package meet the requirements Ron Benj a illl n of the National Environmental Laboratory Accreditation Program Lab Director and/or state specific certification programs as applicable. Client Service contact: Ralph Frye 337-237-4775 Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31), NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775 SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about Unauthorized modification of this report is strictly prohibited. how we can serve you better at: Review standard terms at: http://www.sgs.com/en/terms-and-conditions EHS.US.CustomerCare@sgs.com 1 of 47 LA58555 Sections: Table of Contents -I- Section1: Sample Summary................................................................................................... 3 Section2: Summary of Hits.................................................................................................... 6 Section3: Sample Results........................................................................................................ 9 3.1: LA58555-1: MW-14..................................................................................................... 10 3.2: LA58555-2: MW-2....................................................................................................... 11 3.3: LA58555-3: MW-9....................................................................................................... 12 3.4: LA58555-4: PZ-12........................................................................................................ 13 3.5: LA58555-5: MW-15..................................................................................................... 14 3.6: LA58555-6: MW-16..................................................................................................... 15 3.7: LA58555-7: MW-3....................................................................................................... 16 3.8: LA58555-8: MW-31) .................................................................................................... 17 3.9: LA58555-9: MW-10..................................................................................................... 18 3.10: LA58555-10: MW-10 DUP........................................................................................ 19 3.11: LA58555-11: MW-18................................................................................................. 20 3.12: LA58555-12: MW-41) ................................................................................................ 21 3.13: LA58555-13: MW-4................................................................................................... 22 3.14: LA58555-14: MW-81) ................................................................................................ 23 3.15: LA58555-15: MW-8................................................................................................... 24 3.16: LA58555-16: MW-8T................................................................................................. 25 3.17: LA58555-17: MW-17................................................................................................. 26 3.18: LA58555-18: MW-17D.............................................................................................. 27 3.19: LA58555-19: EB-1015-19.......................................................................................... 28 3.20: LA58555-20: MW-23................................................................................................. 29 3.21: LA58555-21: TB-01................................................................................................... 30 3.22: LA58555-22: SW-103................................................................................................ 31 3.23: LA58555-23: SW-102................................................................................................ 32 3.24: LA58555-24: SW-101................................................................................................ 33 3.25: LA58555-25: SW-101 DUP........................................................................................ 34 Section4: Misc. Forms............................................................................................................ 35 4.1: Chain of Custody........................................................................................................... 36 Section 5: MS Volatiles - QC Data Summaries..................................................................... 41 5.1: Method Blank Summary................................................................................................ 42 5.2: Blank Spike/Blank Spike Duplicate Summary.............................................................. 44 5.3: Matrix Spike/Matrix Spike Duplicate Summary........................................................... 46 W, SGS North America Inc. Sample Summary Kinder Morgan Job No: LA58555 CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Project No: 03158700. B. PN. GEN. PT. EM Sample Collected Matrix Client Number Date Time By Received Code Type Sample I D This report contains results reported as ND = Not detected. The following applies: Organics ND = Not detected above the MDL LA58555-1 10/15/19 10:30 TH/VVYiO/16/19 AQ Ground Water MW-14 LA58555-2 10/15/19 10:40 TH/VWIO/16/19 AQ Ground Water MW-2 LA58555-3 10/15/19 10:50 TH/VWIO/16/19 AQ Ground Water MW-9 LA58555-4 10/15/19 11:00 TH/VWiO/16/19 AQ Ground Water PZ-12 LA58555-5 10/15/19 11:05 TH/V)M 0/ 16/19 AQ Ground Water MW-15 LA58555-6 10/15/19 11:15 TH/VW10/16/19 AQ Ground Water MW-16 LA58555-7 10/15/19 11:25 TH/V)M 0/ 16/19 AQ Ground Water MW-3 LA58555-8 10/15/19 11:30 TH/VWiO/16/19 AQ Ground Water MW-3D LA58555-9 10/15/19 11:40 TH/V)M 0/ 16/19 AQ Ground Water MW-10 LA58555-10 10/15/19 11:45 TH/VWIO/16/19 AQ Ground Water MW-10 DUP LA58555-11 10/15/19 11:50 TH/VWIO/16/19 AQ Ground Water MW-18 LA58555-12 10/15/19 13:15 TH/VWi0/16/19 AQ Ground Water MW-4D 6 3 of 47 LA58555 SGS North America Inc. Sample Summary (continued) Kinder Morgan Job No: LA58555 CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Project No: 03158700. B. PN. GEN. PT. EM Sample Collected Matrix Client Number Date Time By Received Code Type Sample I D LA58555-13 10/15/19 13:25 TH/VWIO/16/19 AQ Ground Water MW-4 LA58555-14 10/15/19 13:50 TH/VWIO/16/19 AQ Ground Water MW-8D LA58555-15 10/15/19 13:55 TH/VWiO/16/19 AQ Ground Water MW-8 LA58555-15D 10/15/19 13:55 TH/VWIO/16/19 AQ Water Dup/MSD MW-8 LA58555-15S 10/15/19 13:55 TH/VW10/16/19 AQ Water Matrix Spike MW-8 LA58555-16 10/15/19 14:10 TH/VW10/16/19 AQ Ground Water MW-8T LA58555-17 10/15/19 14:15 TH/VWI0/16/19 AQ Ground Water MW-17 LA58555-18 10/15/19 14:20 TH/VWI0/16/19 AQ Ground Water MW-17D LA58555-19 10/15/19 14:40 TH/VWi0/16/19 AQ Equipment Blank EB-1015-19 LA58555-20 10/15/19 13:30 TH/VWIO/16/19 AQ Ground Water MW-23 LA58555-21 10/15/19 00:00 TH/VWIO/16/19 AQ Trip Blank Water TB-01 LA58555-22 10/15/19 15:20 TH/VWIO/16/19 AQ Ground Water SW-103 LA58555-23 10/15/19 15:25 TH/VWi0/16/19 AQ Ground Water SW-102 6 4 of 47 LA58555 SGS North America Inc. Sample Summary (continued) Kinder Morgan Job No: LA58555 CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Project No: 03158700. B. PN. GEN. PT. EM ;ample Collected Matrix Client lumber Date Time By Received Code Type Sample I D LA58555-24 10/15/19 15:30 TH/VW10/16/19 AQ Ground Water SW-101 LA58555-25 10/15/19 15:35 TH/VVYiO/16/19 AQ Ground Water SW-101 DUP 6 5 of 47 LA58555 Summary of Hits Job Number: LA58555 Account: Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Collected: 10/ 15/ 19 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA58555-1 MW-14 No hits reported in this sample. LA58555-2 MW-2 Benzene 0.23 J 1.0 0.23 ug/l SW846 8260B Ethylbenzene 0.41 J 1.0 0.23 ug/l SW846 8260B Xylene (total) 1.3 J 2.0 0.39 ug/l SW846 8260B Naphthalene 1.7 J 5.0 0.30 ug/l SW846 8260B LA58555-3 MW-9 Benzene 0.41 J 1.0 0.23 ug/1 SW846 8260B Naphthalene 1.6 J 5.0 0.30 ug/1 SW846 8260B LA58555-4 PZ-12 No hits reported in this sample. LA58555-5 MW-15 No hits reported in this sample. LA58555-6 MW-16 No hits reported in this sample. LA58555-7 MW-3 Benzene 2.4 1.0 0.23 ug/l SW846 8260B Ethylbenzene 0.24 J 1.0 0.23 ug/l SW846 8260B Naphthalene 9.2 5.0 0.30 ug/l SW846 8260B LA58555-8 MW-3D No hits reported in this sample. LA58555-9 NW-10 Benzene 4.3 1.0 0.23 ug/l SW846 8260B Naphthalene 0.59 J 5.0 0.30 ug/l SW846 8260B Page 1 of 3 6 6 of 47 LA58555 Summary of Hits Job Number: LA58555 Account: Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Collected: 10/ 15/ 19 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA58555-10 MW-10 DUP Benzene Naphthalene LA58555-11 NM-18 No hits reported in this sample. LA58555-12 MW-4D No hits reported in this sample. LA58555-13 MW-4 No hits reported in this sample. LA58555-14 MW-8D No hits reported in this sample. LA58555-15 MW-8 No hits reported in this sample. LA58555-16 MW-8T No hits reported in this sample. LA58555-17 MW-17 No hits reported in this sample. LA58555-18 MW-17D No hits reported in this sample. LA58555-19 EB-1015-19 Toluene LA58555-20 MW-23 No hits reported in this sample. 4.0 1.0 0.23 ug/l 0.72 J 5.0 0.30 ug/l 0.44 J 1.0 0.23 ug/l SW846 8260B SW846 8260B SW846 8260B Page 2 of 3 6 7 of 47 LA58555 Summary of Hits Job Number: LA58555 Account: Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Collected: 10/ 15/ 19 ,ab Sample ID Client Sample ID Result/ Lnalyte Qual RL MDL Units Method LA58555-21 TB-01 No hits reported in this sample. LA58555-22 SW-103 No hits reported in this sample. LA58555-23 SW-102 No hits reported in this sample. LA58555-24 SW-101 No hits reported in this sample. LA58555-25 SW-101 DUP No hits reported in this sample. Page 3 of 3 6 8 of 47 LA58555 FM Scott, LA Sample Results Report of Analysis i Section 3 6 9 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-14 Lab Sample ID: LA58555-1 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 j File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451033.D 1 10/17/19 18:58 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 105% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 94% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 10 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-2 Lab Sample ID: LA58555-2 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 N File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451035.D 1 10/17/19 19:25 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 0.23 1.0 0.23 ug/1 J 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene 0.41 1.0 0.23 ug/1 J 1330-20-7 Xylene (total) 1.3 2.0 0.39 ug/1 J 91-20-3 Naphthalene 1.7 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 103% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 11 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-9 Lab Sample ID: LA58555-3 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 w File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451037.D 1 10/17/19 19:51 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 0.41 1.0 0.23 ug/1 J 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 1.6 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 104% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 97% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 12 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: PZ-12 Lab Sample ID: LA58555-4 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451039.D 1 10/17/19 20:17 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 102% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 97% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 13 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-15 Lab Sample ID: LA58555-5 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451041.D 1 10/17/19 20:43 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 104% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 96% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 14 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-16 Lab Sample ID: LA58555-6 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451043.D 1 10/17/19 21:09 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 105% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 94% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 15 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-3 Lab Sample ID: LA58555-7 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451045.D 1 10/17/19 21:36 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 2.4 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene 0.24 1.0 0.23 ug/1 J 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 9.2 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 104% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 97% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 16 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-3D Lab Sample ID: LA58555-8 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 w File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2QO451051.D 1 10/17/19 22:54 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 109% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 94% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 17 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-10 Lab Sample ID: LA58555-9 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451053.D 1 10/17/19 23:21 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 4.3 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 0.59 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 108% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 96% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 18 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-10 DUP Lab Sample ID: LA58555-10 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451055.D 1 10/17/19 23:47 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 4.0 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 0.72 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 105% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 95% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 19 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-18 Lab Sample ID: LA58555-11 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451057. D 1 10/ 18/ 19 00:13 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 108% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 93% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 20 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-4D Lab Sample ID: LA58555-12 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451059.D 1 10/18/19 00:39 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 111% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 90% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 21 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-4 Lab Sample ID: LA58555-13 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451061.D 1 10/18/19 01:05 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 113% 81-120% 2037-26-5 Toluene-D8 101% 93-105% 460-00-4 4-Bromofluorobenzene 93% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 22 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-8D Lab Sample ID: LA58555-14 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451063.D 1 10/18/19 01:31 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 113% 81-120% 2037-26-5 Toluene-D8 97% 93-105% 460-00-4 4-Bromofluorobenzene 92% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 23 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-8 Lab Sample ID: LA58555-15 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451049.D 1 10/17/19 22:28 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 106% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 94% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 24 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-8T Lab Sample ID: LA58555-16 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2Q0451047.D 1 10/17/19 22:02 CP n/a n/a V2Q2506 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 106% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 95% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 25 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-17 Lab Sample ID: LA58555-17 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085556.D 1 10/18/19 18:25 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 109% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range w j V J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 26 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-17D Lab Sample ID: LA58555-18 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085558.D 1 10/18/19 18:51 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 110% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range w j 00 J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 27 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: EB-1015-19 Lab Sample ID: LA58555-19 Date Sampled: 10/15/19 Matrix: AQ - Equipment Blank Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085540.D 1 10/18/19 14:50 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene 0.44 1.0 0.23 ug/1 J 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 107% 81-120% 2037-26-5 Toluene-138 98% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 28 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: MW-23 Lab Sample ID: LA58555-20 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085560.D 1 10/18/19 19:18 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 109% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 29 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: TB-01 Lab Sample ID: LA58555-21 Date Sampled: 10/15/19 Matrix: AQ - Trip Blank Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085542.D 1 10/18/19 15:17 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 112% 81-120% 2037-26-5 Toluene-138 100% 93-105% 460-00-4 4-Bromofluorobenzene 97% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 30 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: SW-103 Lab Sample ID: LA58555-22 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085562.D 1 10/18/19 19:45 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 109% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 31 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: SW-102 Lab Sample ID: LA58555-23 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085564.D 1 10/18/19 20:12 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 114% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 32 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: SW-101 Lab Sample ID: LA58555-24 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085566.D 1 10/18/19 20:38 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 116% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 101% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 33 of 47 LA58555 SGS North America Inc. Report of Analysis Client Sample ID: SW-101 DUP Lab Sample ID: LA58555-25 Date Sampled: 10/15/19 Matrix: AQ - Ground Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085568.D 1 10/18/19 21:05 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 116% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 34 of 47 LA58555 i SGS Scott, LA Section 4 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody 6 35 of 47 LA58555 PAGE I OF 3 CHAIN OF CUSTODY S North America Inc - Scott L Q„ 500 Ambasai3dor Caffery Parkway, Scott, LA 70583 TEL.3 17.237.4775 FAX: 337.237.7838 r www.sgs.com/ehsusa Tre FED -EX 9N Bpme Ober ConVaN sw ouowx scs.lob# Client I Reporting Information Project Information Requested Analysis see TEST CODE sheet Matrix Codes Company Name Prolect Name: W p q bl GW .�Water.nd W W -Water SW-Sur1_Water SO -Sal SL- Sludge sEoseou "' LIO - Other Liquid soLaotharsaia WP-Wlpe FB-Fiel Field nk EB-eq Rln. tank RB-Rinse Blank TB - Trip Blank Street A rd5a /LL// //��,,,a�������1���� ����//��p� '�..� 7� (Aa1Lr*1 MP 6W, Sy/" $ae91 I ,,�� p ..,,[�/�- q /5/r/" /WIVI%i /v" lam- : BIIIin Informagon (if different hom Report le) CBy Suite Lhy 6 wr_ y(_ 2 2� (]ty Stalel /dVn/+�` JN��E fj% Company Name ®G oN PIPELINE Proles Contact E-mail 1(Fu Prolect# -31S 7-01). a. F(V Clt/ I Smun Address 5'Vls KIA IDDf) VVIrvDWAyU CoNCiXkSf- Ph on -'r r� y�-32/1`5 Client Purchase Order# /C1ity //�/^q Bute/ Zip /T�ir%r7T�-ErrA c�# .3xo.s Phone# rr"lTUL ! �. WrGiJA S P�roi�tea M /an�age, �i ���,�f IM M1- W"r' � Allentlon: n n �/ fir/ I )7".-F F( 717 sangpa Field ID / Point of Collection Conaclion Num-apmsanedwal eomplcren Dale —a.-P. Moms xa Domed i o 2 S 55 LAB USE ONLY ✓t"%t'✓'2 /hw-15 7loS I vtlw-Ib 1//s w-3 1/as I w-3u 1/30 ( 3 Mw -10 M w-lo-Du �� ,vow- I� l/S� li ✓ i Mw - S Tuma, ound rme I Business da 7 :III _ Data Deliverable Information Comments /Special Irstructiore :. -- ' 210B, mess Days Approved ay(SGSPM):IDab:�+sLLLL El 5 Business Days RUSH r. -t ' t . rl 4 Business. Days RUSH i- �/ `yam.+ 3 Buslnass Days RUSH ❑ 2 BusinosDays RUSH 1 Business. Day EMERGENCY El Other ro Emergent Rush TIA data available via Labllnk. Approval needed for RUSH/Emergency TAT IL Q Commercial "A' (Leve11) 0 TRRP Q Commercial "B" (Lovel2) Q RECAP I Q FULLTI ( Lava 3+4) State Forms ! Q REDTi (Love13+S) Q EDD Format Q Commercial"C" Q Omer I Commercial "A' =Results Only, Commercial 'W=Results+OC Summary Commercial Sum + Partial Raw Dale me ma Note: Sample inventory is verified upon receipt in the Laboratory �fS Iki—rs g� _ ; 7 p !k� Sx IY`�, ��GCi•- /� Tay � aGo.� �rl,C V I w+ r11i L Sample Custody must be docume kited below each time samples change possession, including courier delivery. iRo msaP sem r omeD-Im'S 1��Rlecm.ea ev: ZcaneuHnea powlnm.: 2 ae. R ulsM1 DV--P. Date Time: Re Re qu 4 nn dBy: al Tim*: - y 4 Pllnqulahed Dy: 5 DeU ITImP: Rap by: 5 � Custody Seal# ble one ceerorr.mp. ❑Intact Pm rca 11-1a ❑not nua ❑ ADpm V� r. EHSA-OAC-0()M. 0-FORM-Scott-Standard COC http:/lwww.sgs.com/enfterm nd-condigons. LA58555: Chain of Custody Page 1 of 5 6 36 of 47 LA58555 CHAIN OF CUSTODY PAGE 2 OF 3 RAB un.. Ammfca Inn. q — _T_.._.-... 500 Ambas9�dor Caffery Parkway, Scott, LA 70583 TEL.3 7.237.4775 FAX: 337.237.7838 —"gs.com/ehsusa FEDEXTkiftA Boas ONer Conbelx scs o�o�. n scs aobp Client / Reporting Information ". Act Information Requested Analysis .see TEST CODE sheet Matrix Codes Company Name Project Name. p = g 1C� i ,.v DW-Ddnlbng Water GW-Ground Water W W - Water Sw - Sari.. Water SO - Soil SL-Sludge SEDSediment OI-Oil LIO - Other Liquid AIR - Air SOL-Other Solid WP-wipe Fa. Field frank R-EBW -Rnt 8Bla in -Rin E RE TB -TOP Blank Street Address Sveet 811112 informatlon(if different from Report to) city Stab Zip City Stale, Company Name Protect Contact E-mail Project# Street Address Phone Cllenl Pumhaae Order# City Sure ZIP Samplers) Nernst.) Phone# Nernst.), Protect Mmager i Attention. sanokr Field ID / Point of Collection Col.— Numbararproeenad acmes Comp/cmb Date r:ne s.mple�§y Me. ar bonus E i ° o c i LAB USE ONLY w - I o 'IS 13lMA,tA/ 5-5 € V 'Mw- gr 3 Aw�12-Dz3 F33 T ,ro Tumeround T re Business ea ) ' Data Deliverable lefte—ton Comments / S cial Irrslrucdons Standard tB Businoss Days Approved By (SGS PMla Den; �i ❑ S easiness Deys RUSN I 4 Business Days RUSH ll 3 Business Day: RUSH l 2 Business Days RUSH I 1 Business Day EMERGENCY �I Other Emerge,S Rush TIA data available via La link. Appmal needed for RUSH/Emergency TAT II Q c c medal "A" (Level l) O TRRP Q C:can—ial'S' (Leve12) Q RECAP Q FULLTt ( Level 3+4) 0 State Forms Q REDTt (Level3+i) Q Epp Format Q Commercial "C" Q Other- Commercial -A- Results Only, Core-1.1'a' = R.:uIts +OC Summary Commercial 'C'= Remits ♦OC Summary +Pardal Raw Data Note: Sample inventory is verified upon receipt in the Laboratory Sample Custody must be docum jrted below each time samples change possession, including courier delivery. wsa p wJ.l Tl ,1 g �.?OU 1 c—day: f 2 11naman3rT—P Gi o /rims: g ne d by Sam Da Tlmx: RepeNed ay: ` 3 f ReNnbulehad 4 By: OaN/Time: ecrlved By: 4 ullnbulenotlb: 5 eklTlnm: Raulvede 5 Cuamdys_# ❑ Inkm Pmaarvetl wham epplkebM On kp ❑ naxkct ❑ Ahesnl O �( htfp:/ANWw.sgs.wmleniterms-ands nditons. 1t (l EHSA-OACA026-00-FORM-Scott-Standard COC t LA58555: Chain of Custody Page 2 of 5 6 37 of 47 LA58555 1, COAINAOF (CUSTODY PAGE OF 500 Ambassador .--------------1--- TEL.#7.237.4775 Caffery Parkway, Scott, LA 70583 FAX: 337.237.7838 wv+w.sgscom/ehsusa FED -Ex Trackin9a eouo ordar com�mro scs oeaea sss.rma J Client / Reporting Information Pro ct Information Requested Analysis see TEST CODE sheet)Matrix MatrixCodes Company Name Project Name S1R'7 I a qQ 'i DW-Drinking Water GW -Ground Water W W - Water SW - Surface Water So -Soil SL-Sludge BED- Sediment OI - Oil Ln-Omer Liquid AIR - Alt SOL-Other Solid Wipe FB-Fie Field E&Equp lBlank RB - Rinse Blank TS - Trip Blank Street Address Skeet Billie Information If different from Report to) City State 21p City Sta Company Name Proied Come. E-mail Proied# (� Street Address Phone# Client Pumhase Order# �) li City Stale zip SampleNs)Name(s) Phone # Proied Maneper Attantion: —&- Field ID / Point of Collection DOIIe(tion ' Num§bmorivexrved BaWea cdmucmb De. Time semvlea� Mao-u ko - r.. USE ONLY SW — /o 3 6 /0 fS!`y lrau 7;i tW sw 1 3 A� Situ 153 o E w /ol -61/11 AEJ� 35 C 3 I C r I I TurnaunTi rod me Business days) ;! Data Deliverable In(Drma#on Comments / B ecu Instructions .mdmd to Business Days Approvee ey (BGB PM):I pab: E Business Days RUSH ❑ 4 Business Days RUSH 3 Business Days RUSH ll i 2 Business Days RUSH IBusiness Day EMERGENCY Other Emer onnyBRush T/Adatnavailablevia Lablink. Approval needed fm RUSWEme n TAT O Commeroial "A" (Lave)1) O TRRP O Commemial'B" ( Level 2) Q RECAP O FULLTt (Laves 3 4) Q State Forms REDTt Level3. Q ( E) Q EDO Forma[ O Commemial'C' Q Other Commercial'A'= Results Only, C.—wolal'B' = Results. OC Summary Commerolal"C'= Results a OC Surema +Partial Raw Data Note: Sample inventory is verified upon receipt in the Laboratory f,� - • l./ f Beim le CuBlody must be documented below each time samples change possession, including courier dellvery. ll geuwm By: Znngmah.e ev: R /C9 2 edbysp f 3 Da Zma: Recal d € 3 E R.inq.1—ol By: 4 DeW/time: emlvetl'By: q elln.ulahad by: Data/Time: Reword By: 5 -- Cua dy Boal# Pmaerved wM1ere applicable On kc /y ❑ ❑ l ❑NnthWct ❑Apsom Them 10: iY. EHSA-0AC-0026.00-FORMSoott-Standard COC http:/Aw .ags.com/en/terms-and-conditions. LA58555: Chain of Custody Page 3 of 5 6 38 of 47 LA58555 pPAi' 9 *'.;�4i'2ugpi�t.CCrtETy9�: G7P.,) : I + cmE O a I N N I ! y 124 O mN H ca Q: SU6i=i J Li s �� _ cm 0 N6Up pp y 4 •COD O a Q.a 00 +� + m 0° oa �= LU a y O © U IV QC/0 LU M1�ILL, O EW.. COJN � d P -_ _ G �-• d !piQ `rv�ltUi1� U 65 O x W,a WW W. f CS C) LL J M Z-1 C r.. 5 = LSD C=)Aj J _ G Cfl IjI O _Q N cl*lj -� LA58555: Chain of Custody Page 4 of 5 6 39 of 47 LA58555 SGS Sample Receipt Summary Job Number: LA58555 Client: JACOBS Date / Time Received: 10/16/2019 8:45:00 AM Delivery Method: Cooler Temps (Initial/Adjusted): #1: (3.4/3.4): DV440 Cooler Security Y or N Y or N 1. Custody Seals Present: ❑d ❑ 3. COC Present: 2 ❑ 2. Custody Seals Intact: W ❑ 4. Smpl Dates/Time OK W ❑ Cooler Temperature Y or N 1. Temp criteria achieved: ❑� ❑ 2. Thermometer ID: DV439; 3. Cooler media: Ice (direct contact) 4. No. Coolers: 1 Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: 0 ❑ ❑ 2. Trip Blank listed on CDC: 0 ❑ ❑ 3. Samples preserved properly: W11 ❑ 4. VOCs headspace free: 0 ❑ ❑ Fed Ex Project: POPLAR TENT RD. Airbill Xs: 8129 2368 0656 Sample Integrity - Documentation 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: Sample Integrity - Condition 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Y or N ❑� ❑ o ❑ ❑� ❑ Y or N ❑� ❑ o ❑ Intact Y or N N/A ❑� ❑ ❑ 0 ❑� ❑ ❑ ❑ ❑O ❑ ❑ ❑J LA58555: Chain of Custody Page 5 of 5 A 0 6 40 of 47 LA58555 ffm Scott, LA MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries i no Section 5 6 41 of 47 LA58555 Method Blank Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X3846-MB2 1X0085532.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: Method: SW846 8260D LA58555-17, LA58555-18, LA58555-19, LA58555-20, LA58555-21, LA58555-22, LA58555-23, LA58555-24, LA58555-25 CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/l 100-41-4 Ethylbenzene ND 1.0 0.23 ug/l 91-20-3 Naphthalene 0.38 5.0 0.30 ug/l J 108-88-3 Toluene ND 1.0 0.23 ug/l 1330-20-7 Xylene (total) ND 2.0 0.39 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 100% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% 6 42 of 47 LA58555 Method Blank Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2Q2506-MB2 2Q0451031.D 1 10/17/19 CP n/a n/a V2Q2506 The QC reported here applies to the following samples: Method: SW846 8260B LA58555-1, LA58555-2, LA58555-3, LA58555-4, LA58555-5, LA58555-6, LA58555-7, LA58555-8, LA58555-9, LA58555-10, LA58555-11, LA58555-12, LA58555-13, LA58555-14, LA58555-15, LA58555-16 CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/l 100-41-4 Ethylbenzene ND 1.0 0.23 ug/l 91-20-3 Naphthalene ND 5.0 0.30 ug/l 108-88-3 Toluene ND 1.0 0.23 ug/l 1330-20-7 Xylene (total) ND 2.0 0.39 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 100% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 95% 89-107% 6 43 of 47 LA58555 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X3846-BS2 1X0085534.D 1 10/18/19 CP n/a n/a V1X3846 V1X3846-BSD2 1X0085536.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: Method: SW846 8260D LA58555-17, LA58555-18, LA58555-19, LA58555-20, LA58555-21, LA58555-22, LA58555-23, LA58555-24, LA58555-25 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/1 % RPD Rec/RPD 71-43-2 Benzene 20 22.6 113 21.4 107 5 82-119/14 100-41-4 Ethylbenzene 20 21.5 108 21.0 105 2 82-120/15 91-20-3 Naphthalene 20 24.1 121 24.5 123 2 60-137/24 108-88-3 Toluene 20 22.5 113 21.8 109 3 82-118/15 1330-20-7 Xylene (total) 60 69.4 116 67.6 113 3 82-122/15 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 103% 103% 81-120% 2037-26-5 Toluene-D8 98% 99% 93-105% 460-00-4 4-Bromofluorobenzene 100% 103% 89-107% * = Outside of Control Limits. 6 44 of 47 LA58555 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC ample File ID DF Analyzed By Prep Date Prep Batch Analytical Batcl. 72Q2506-BS1 2Q0451025.D 1 10/17/19 CP n/a n/a V2Q2506 72Q2506-BSD1 2Q0451027.D 1 10/17/19 CP n/a n/a V2Q2506 The QC reported here applies to the following samples: Method: SW846 8260B LA58555-1, LA58555-2, LA58555-3, LA58555-4, LA58555-5, LA58555-6, LA58555-7, LA58555-8, LA58555-9, LA58555-10, LA58555-11, LA58555-12, LA58555-13, LA58555-14, LA58555-15, LA58555-16 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/1 ug/l % ug/l % RPD Rec/RPD 71-43-2 Benzene 20 20.4 102 19.9 100 2 82-119/11 100-41-4 Ethylbenzene 20 21.4 107 21.2 106 1 82-120/11 91-20-3 Naphthalene 20 17.4 87 16.8 84 4 60-137/15 108-88-3 Toluene 20 21.0 105 20.3 102 3 82-118/12 1330-20-7 Xylene (total) 60 57.3 96 56.5 94 1 82-122/11 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 95% 96% 81-120% 2037-26-5 Toluene-D8 102% 100% 93-105% 460-00-4 4-Bromofluorobenzene 103% 103% 89-107% * = Outside of Control Limits. 6 45 of 47 LA58555 Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC ample File ID DF Analyzed By Prep Date Prep Batch Analytical Batcl ,A58555-15MS 2Q0451065.D 2 10/18/19 CP n/a n/a V2Q2506 ,A58555-15MSD 2Q0451067.D 2 10/18/19 CP n/a n/a V2Q2506 ,A58555-15 2Q0451049.D 1 10/17/19 CP n/a n/a V2Q2506 The QC reported here applies to the following samples: Method: SW846 8260B LA58555-1, LA58555-2, LA58555-3, LA58555-4, LA58555-5, LA58555-6, LA58555-7, LA58555-8, LA58555-9, LA58555-10, LA58555-11, LA58555-12, LA58555-13, LA58555-14, LA58555-15, LA58555-16 LA58555-15 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD 71-43-2 Benzene ND 40 43.9 110 40 35.1 88 22* 41-155/14 100-41-4 Ethylbenzene ND 40 45.0 113 40 35.0 88 25* 50-147/15 91-20-3 Naphthalene ND 40 29.2 73 40 24.1 60 19 30-153/24 108-88-3 Toluene ND 40 41.0 103 40 33.2 83 21* 40-153/15 1330-20-7 Xylene (total) ND 120 114 95 120 89.0 74 25* 46-154/15 CAS No. Surrogate Recoveries MS MSD LA58555-15 Limits 17060-07-0 1,2-Dichloroethane-D4 99% 97% 106% 81-120% 2037-26-5 Toluene-D8 96% 98% 98% 93-105% 460-00-4 4-Bromofluorobenzene 102% 101% 94% 89-107% * = Outside of Control Limits. 6 46 of 47 LA58555 Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1 Job Number: LA58555 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch LA58554-1MS 1X0085572.D 2 10/18/19 CP n/a n/a V1X3846 LA58554-1MSD 1X0085574.D 2 10/18/19 CP n/a n/a V1X3846 LA58554-1 1X0085570.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: Method: SW846 8260B LA58555-17, LA58555-18, LA58555-19, LA58555-20, LA58555-21, LA58555-22, LA58555-23, LA58555-24, LA58555-25 LA58554-1 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD 71-43-2 Benzene ND 40 42.1 105 40 41.7 104 1 41-155/14 100-41-4 Ethylbenzene ND 40 42.6 107 40 39.9 100 7 50-147/15 91-20-3 Naphthalene ND 40 41.1 103 40 43.6 109 6 30-153/24 108-88-3 Toluene ND 40 41.2 103 40 40.4 101 2 40-153/15 1330-20-7 Xylene (total) ND 120 133 ill 120 127 106 5 46-154/15 CAS No. Surrogate Recoveries MS MSD LA58554-1 Limits 17060-07-0 1,2-Dichloroethane-D4 114% 114% 117% 81-120% 2037-26-5 Toluene-D8 98% 100% 98% 93-105% 460-00-4 4-Bromofluorobenzene 105% 104% 102% 89-107% * = Outside of Control Limits. 6 47 of 47 LA58555 ffm Scott, LA The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0 Automated Report Technical Report for Kinder Morgan CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC KMPT SGS Job Number: LA61104 Sampling Date: 01/22/20 Report to: Jacobs CH2M 14120 Ballantyne Corporate Place Charlotte, NC 28277 mike. skeean@jacobs. com; kelly. gutowski@jacobs. ATTN: Mike Skeean Total number of pages in report: 22 Ac Fp Ar . Test results contained within this data package meet the requirements Ron Benj a illl n of the National Environmental Laboratory Accreditation Program Lab Director and/or state specific certification programs as applicable. Client Service contact: Ralph Frye 337-237-4775 Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31), NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775 SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about Unauthorized modification of this report is strictly prohibited. how we can serve you better at: Review standard terms at: http://www.sgs.com/en/terms-and-conditions EHS.US.CustomerCare@sgs.com 1 of 22 LA61104 Sections: Table of Contents -I- Section1: Sample Summary................................................................................................... 3 Section2: Summary of Hits.................................................................................................... 4 Section3: Sample Results........................................................................................................ 5 3.1: LA61104-1: MW-2....................................................................................................... 6 3.2: LA61104-2: PZ-12........................................................................................................ 7 3.3: LA61104-3: MW-9....................................................................................................... 8 3.4: LA61104-4: MW-3....................................................................................................... 9 3.5: LA61104-5: MW-8D.................................................................................................... 10 3.6: LA61104-6: MW-10..................................................................................................... 11 3.7: LA61104-7: MW-10 DUP............................................................................................ 12 3.8: LA61104-8: EB-012220............................................................................................... 13 3.9: LA61104-9: TB-012220............................................................................................... 14 Section4: Misc. Forms............................................................................................................ 15 4.1: Chain of Custody........................................................................................................... 16 Section5: MS Volatiles - QC Data Summaries..................................................................... 19 5.1: Method Blank Summary................................................................................................ 20 5.2: Blank Spike/Blank Spike Duplicate Summary.............................................................. 21 5.3: Matrix Spike/Matrix Spike Duplicate Summary........................................................... 22 W, SGS North America Inc. Sample Summary Kinder Morgan Job No: LA61104 CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Project No: KMPT Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID This report contains results reported as ND = Not detected. The following applies: Organics ND = Not detected above the MDL LA61104-1 01/22/20 12:30 JH 01/23/20 AQ Ground Water MW-2 LA61104-2 01/22/20 12:45 JH 01/23/20 AQ Ground Water PZ-12 LA61104-3 01/22/20 13:05 JH 01/23/20 AQ Ground Water MW-9 LA61104-4 01/22/20 13:15 JH 01/23/20 AQ Ground Water MW-3 LA61104-5 01/22/20 13:40 JH 01/23/20 AQ Ground Water MW-813 LA61104-6 01/22/20 14:35 JH 01/23/20 AQ Ground Water MW-10 LA61104-7 01/22/20 14:40 JH 01/23/20 AQ Ground Water MW-10 DUP LA61104-8 01/22/20 14:50 JH 01/23/20 AQ Equipment Blank EB-012220 LA61104-9 01/22/20 13:00 JH 01/23/20 AQ Trip Blank Water TB-012220 6 3 of 22 LA61104 Summary of Hits Job Number: LA61104 Account: Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Collected: 01/22/20 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA61104-1 MW-2 Xylene (total) 0.58 J 2.0 0.39 ug/1 SW846 8260B Naphthalene 0.57 J 5.0 0.30 ug/1 SW846 8260B LA61104-2 PZ-12 Naphthalene 0.51 J 5.0 0.30 ug/1 SW846 8260B LA61104-3 MW-9 Benzene 0.35 J 1.0 0.23 ug/1 SW846 8260B Naphthalene 2.2 J 5.0 0.30 ug/1 SW846 8260B LA61104-4 MW-3 Benzene 2.3 1.0 0.23 ug/l SW846 8260B Ethylbenzene 0.38 J 1.0 0.23 ug/l SW846 8260B Xylene (total) 0.46 J 2.0 0.39 ug/1 SW846 8260B Naphthalene 11.8 5.0 0.30 ug/l SW846 8260B LA61104-5 MW-8D No hits reported in this sample. LA61104-6 MW-10 Benzene 0.34 J 1.0 0.23 ug/l SW846 8260B LA61104-7 MW-10 DUP Benzene 0.34 J 1.0 0.23 ug/l SW846 8260B LA61104-8 EB-012220 No hits reported in this sample. LA61104-9 TB-012220 Naphthalene 0.87 J 5.0 0.30 ug/l SW846 8260B Page 1 of 1 6 4 of 22 LA61104 FM Scott, LA Sample Results Report of Analysis i Section 3 6 5of22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-2 Lab Sample ID: LA61104-1 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 j File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090354.D 1 01/23/20 22:15 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) 0.58 2.0 0.39 ug/1 J 91-20-3 Naphthalene 0.57 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 89% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 6 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: PZ-12 Lab Sample ID: LA61104-2 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 N File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090352.D 1 01/23/20 21:49 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 0.51 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 84% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 7 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-9 Lab Sample ID: LA61104-3 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 w File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090350.D 1 01/23/20 21:22 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 0.35 1.0 0.23 ug/1 J 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 2.2 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 85% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 103% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 8 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-3 Lab Sample ID: LA61104-4 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090348.D 1 01/23/20 20:56 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 2.3 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene 0.38 1.0 0.23 ug/1 J 1330-20-7 Xylene (total) 0.46 2.0 0.39 ug/1 J 91-20-3 Naphthalene 11.8 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 87% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 9 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-8D Lab Sample ID: LA61104-5 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090346.D 1 01/23/20 20:29 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 87% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 10 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-10 Lab Sample ID: LA61104-6 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090344.D 1 01/23/20 20:03 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 0.34 1.0 0.23 ug/1 J 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 88% 81-120% 2037-26-5 Toluene-D8 100% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 11 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: MW-10 DUP Lab Sample ID: LA61104-7 Date Sampled: 01/22/20 Matrix: AQ - Ground Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090342.D 1 01/23/20 19:36 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene 0.34 1.0 0.23 ug/1 J 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 87% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 12 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: EB-012220 Lab Sample ID: LA61104-8 Date Sampled: 01/22/20 Matrix: AQ - Equipment Blank Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 w File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090340.D 1 01/23/20 19:10 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene ND 5.0 0.30 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 89% 81-120% 2037-26-5 Toluene-138 99% 93-105% 460-00-4 4-Bromofluorobenzene 101% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 13 of 22 LA61104 SGS North America Inc. Report of Analysis Client Sample ID: TB-012220 Lab Sample ID: LA61104-9 Date Sampled: 01/22/20 Matrix: AQ - Trip Blank Water Date Received: 01/23/20 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Page 1 of 1 P File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0090338.D 1 01/23/20 18:43 CP n/a n/a VIX4039 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/1 108-88-3 Toluene ND 1.0 0.23 ug/1 100-41-4 Ethylbenzene ND 1.0 0.23 ug/1 1330-20-7 Xylene (total) ND 2.0 0.39 ug/1 91-20-3 Naphthalene 0.87 5.0 0.30 ug/1 J CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 88% 81-120% 2037-26-5 Toluene-138 100% 93-105% 460-00-4 4-Bromofluorobenzene 100% 89-107% ND = Not detected MDL = Method Detection Limit RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 14of22 LA61104 ffm Scott, LA Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody 1 Section 4 6 15of22 LA61104 CHAIN OF CUSTODY PAGE I OF 500 Ambassador Caffery Parkway, Soon, LA 70583 ._....__ _._ �'_.._.. TEL 337.237.4775 FAX. 337.237.7838 - www.sgs.com/ehsusa FE0.Ex Trachin9e Boma aaercomolp I A- sos opoma so ,, .Client l Reporting Information Project Information Requested Analysis see TEST CODE sheet Matrix Codes Company Name ProJed Name. q S S -b°r GWinkinWater GW.G-Graund Water ww-wakr sw-Swface Water s0-Sol SEOS.Odeent LIO-ONer LieWd SOLA'OMl Solid WP-Wipe Fa -Fialtl Bknk E&Ecuipinent Blank RB-Ririe elrk TB-Tdp Blank street Adtlreas t„I..�,l 1`nz, 6,f1 �h nx f�a-/� I M 9 'V I ZtlU Street Shhh,g lnfprmau—(11 dinemnt from Report to) Cit�y"" 11�� Btate t�� 21p CPatry!'i'I-e NC ISO Z% CityStele Company Name rvlt-AckM �t��l JL 1/ Project Collect Email M1Ze �L • T4 CnM Phonek PreleMe Dllenl Purchase Orderd street dress Sacra 1�w w,4waa cPV\UWU V-t J C' Stele, Samplar(s)Na Phonap .JT7�'sJrJr�n�E±i Prol �MeneB� M J..n. Atkndon: rf Y samoa Field ID/ Point of Collection Cpllecapn Numaarafpnanwa Bomea LAB USE ONLY comp/crae Dale Tlme sampes B ly Mao-d Ix6.2 drR111w bvmas g q i o AAW-2— 01 5 Q- '3 P— 2 i Zzr� 2H5 G; 3 3 -v M - 9zu 1305 L, 3 3 cI Mw- 2t2r 615 -j'k tw, 13 1v —8D No c-1 3 3 1 13 MIA. -ID I135 ? 3 Mw— U—avo �j610 3 3 F,g-- 0122zv 1450 D:. 3 3 3 ' 1(i - 0 (222v [3 0o r.AfS 3 i " :;', T—Bruund Tlme(Businesed s) '! Data DelNerable lMormelion Comments/B etial lnstluMions ShndaW to Business Daya pp vva 9y lses vent ro,ro: 6 Raciness Days RUSH 4 Business Days RUSH a Business Days RUSH 2 Business Days RUSH 1 Buslnecc Day EMERGENCY Other Emer9ency8 Rush TlA data available via Labl'ink.A mvalneeaedfm RUSHIEmemen TAT QCommercMl"A^(Level t) QTRRP Q Commercial "B" (Level2) Q RECAP 0 FULLTt (Level—) Q State Forms 0 REDT1(Lw,13+$) Q EDD Format Q Commerclal"C" Q Otlrer_ Commprcial'A" = Resuss Onl, Commercial "B" v Resuss • OC Summary Commerdal"C"=Resulls•OC Summa +Penal Raw Data Note: Sample inventory is verified upon rec ipt in the Laboratory % a L Sam le Custody �a Vio 114 must be documented below each time sam I noss on, Includin c er delivery. aaa00y \ 3Relineulahs Dv 1 Ra Ralin f 4 y: 6 a /Tlma: Rate aBy, 8 a Fsl ay mservea la on ea •Tamp. QTi ❑ wmwd ❑ Aesem P Tnwm in --.. M cuca.narmsam.FnBra_c�xl. RbnaaM CDC -FINAL PVyf http:/Aw .sgs.wm/en/terms-and-conditions. LA61104: Chain of Custody Page 1 of 3 6 16 of 22 LA61104 erw; rnvnur v.em,. ORIGIN IDLFTA:. F704) 574-4040 SHIP DATE: 05DEC1S NATO UME ACTNGTr 4.50 LB NATO83 �CAD;:0330040/CAFE3211 14CI20 BRLLRNTYNE CORPORATE PLACE DIM14xIOx I4 IN CHARLOTTE, NC 28277 UNITED STATES US _ TO SAMPLE MANAGEMENT SGS NORTH AMERICA e 109 COMMISSION BLVD e LAFAYETTE LA 70508 (837 237-4775 REF: RF 12319 16/Ee bEpl ENVIRONMENTAL RMA: III IIII III + r + 4 Feffxl Express ! ...Ef1 i ' ti� IRI RFTLIRNS MON-SAT RetlEx THU - 23JAN 10,304' 011: 4920 6964 8142 PRIORITY OVERNIGH XH LFTAn 7050 LA -us LFf .iD99i 01I22 66DJC/DFCC/IC4P• LA61104: Chain of Custody Page 2 of 3 6 17 of 22 LA61104 SGS Sample Receipt Summary Job Number: LA61104 Client: JACOBS Date / Time Received: 1/23/2020 8:45:00 AM Delivery Method: Cooler Temps (Initial/Adjusted): #1: (2.43/2.43)i Cooler Security Y or N Y or N 1. Custody Seals Present: ❑d ❑ 3. COC Present: 2 ❑ 2. Custody Seals Intact: W ❑ 4. Smpl Dates/Time OK W ❑ Cooler Temperature Y or N 1. Temp criteria achieved: ❑� ❑ 2. Thermometer ID: DV439; 3. Cooler media: Ice (direct contact) 4. No. Coolers: 1 Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: ❑ ❑ ❑d 2. Trip Blank listed on CDC: ❑ ❑ ❑d 3. Samples preserved properly: ❑1 ❑ 4. VOCs headspace free: ❑d ❑ ❑ Fed Ex Project: POPLAR TENT ROAD Airbill Xs: 4920 6964 8142 A Sample Integrity - Documentation Y or N :A 1. Sample labels present on bottles: ❑ 2. Container labeling complete: ❑ 3. Sample container label / COC agree: 0 ❑ Sample Integrity - Condition Y or N 1. Sample recvd within HT: ❑ 2. All containers accounted for: ❑ 3. Condition of sample: Intact Sample Integrity - Instructions Y or N N/A 1. Analysis requested is clear: ❑� ❑ 2. Bottles received for unspecified tests ❑ ❑� 3. Sufficient volume recvd for analysis: ❑� ❑ 4. Compositing instructions clear: ❑ ❑ W 5. Filtering instructions clear: ❑ ❑ ❑J LA61104: Chain of Custody Page 3 of 3 6 18 of 22 LA61104 ffm Scott, LA MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries i no Section 5 6 19 of 22 LA61104 Method Blank Summary Page 1 of 1 Job Number: LA61104 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X4039-MB2 1X0090312.D 1 01/23/20 CP n/a n/a V1X4039 The QC reported here applies to the following samples: Method: SW846 8260B LA61104-1, LA61104-2, LA61104-3, LA61104-4, LA61104-5, LA61104-6, LA61104-7, LA61104-8, LA61104-9 CAS No. Compound Result RL MDL Units Q 71-43-2 Benzene ND 1.0 0.23 ug/l 100-41-4 Ethylbenzene ND 1.0 0.23 ug/l 91-20-3 Naphthalene ND 5.0 0.30 ug/l 108-88-3 Toluene ND 1.0 0.23 ug/l 1330-20-7 Xylene (total) ND 2.0 0.39 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 83% 81-120% 2037-26-5 Toluene-D8 99% 93-105% 460-00-4 4-Bromofluorobenzene 101% 89-107% 6 20 of 22 LA61104 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA61104 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X4039-BS1 1X0090306.D 1 01/23/20 CP n/a n/a V1X4039 V1X4039-BSD1 1X0090308.D 1 01/23/20 CP n/a n/a V1X4039 The QC reported here applies to the following samples: Method: SW846 8260B LA61104-1, LA61104-2, LA61104-3, LA61104-4, LA61104-5, LA61104-6, LA61104-7, LA61104-8, LA61104-9 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD 71-43-2 Benzene 20 20.2 101 19.3 97 5 82-119/11 100-41-4 Ethylbenzene 20 20.8 104 19.9 100 4 82-120/11 91-20-3 Naphthalene 20 21.8 109 21.5 108 1 60-137/15 108-88-3 Toluene 20 20.5 103 19.3 97 6 82-118/12 1330-20-7 Xylene (total) 60 65.0 108 62.0 103 5 82-122/11 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 89% 91% 81-120% 2037-26-5 Toluene-D8 100% 100% 93-105% 460-00-4 4-Bromofluorobenzene 101% 100% 89-107% * = Outside of Control Limits. 6 21 of 22 LA61104 Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1 Job Number: LA61104 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Ground Water), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch LA61079-6MS 1X0090334.D 5 01/23/20 CP n/a n/a V1X4039 LA61079-6MSD 1X0090336.D 5 01/23/20 CP n/a n/a V1X4039 LA61079-6 1X0090320.D 1 01/23/20 CP n/a n/a V1X4039 The QC reported here applies to the following samples: Method: SW846 8260B LA61104-1, LA61104-2, LA61104-3, LA61104-4, LA61104-5, LA61104-6, LA61104-7, LA61104-8, LA61104-9 LA61079-6 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD 71-43-2 Benzene ND 100 94.4 94 100 94.9 95 1 41-155/14 100-41-4 Ethylbenzene ND 100 98.4 98 100 96.5 97 2 50-147/15 91-20-3 Naphthalene ND 100 93.9 94 100 98.2 98 4 30-153/24 108-88-3 Toluene ND 100 94.5 95 100 94.0 94 1 40-153/15 1330-20-7 Xylene (total) ND 300 303 101 300 296 99 2 46-154/15 CAS No. Surrogate Recoveries MS MSD LA61079-6 Limits 17060-07-0 1,2-Dichloroethane-D4 89% 90% 87% 81-120% 2037-26-5 Toluene-D8 100% 99% 100% 93-105% 460-00-4 4-Bromofluorobenzene 100% 99% 100% 89-107% * = Outside of Control Limits. 6 22 of 22 LA61104 JACOBS Memorandum 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 Subject Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site Soil Vapor Project Name Plantation Pipe Line Poplar Tent Road Site Attention Kelly Gutowski/CLT, Jacobs Mike Skeean/CLT, Jacobs From Tiffany Davis/GNV, Jacobs Date November 4, 2019 Copies to Juan Acaron/GNV, Jacobs 1. Introduction The purpose of this memorandum is to present the results of the data validation process for the soil vapor samples collected at the Plantation Pipe Line Company (PPL) Poplar Tent Road Site located in Concord, North Carolina. The samples were collected on October 17, 2019. Samples were submitted to Eurofins TestAmerica, Knoxville in Tennessee for the following analyses: • T015 SIM Volatiles • T017 Volatiles These data for Sample Delivery Groups (SDGs) J17050 and J17112 were validated for compliance with the analytical method requirements. This process included a review of these data to assess the accuracy, precision, and completeness based upon procedures described in guidance documents such as the Environmental Protection Agency (EPA) National Functional Guidelines for Organic Data Review (EPA 2017) and the USEPA, Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA 1999). The Quality assurance/quality control (QA/QC) summary forms and data reports were reviewed and the resulting findings are documented within each subsection that follows. During the data validation, if QA/QC parameters were not within the acceptance limits, associated sample results were appended with a primary qualifying flag that indicated a possible anomaly with these data. The qualifying flags originated during the data review and validation processes. This qualification also included the use of secondary sub -qualifier flags. The secondary qualifiers provide the reasoning behind the assignment of a qualifier to these data. The definitions of the primary qualifiers are presented below. 2. Validation Flag Definitions The following primary qualifiers were used to qualify the data: [_]: Detected. The analyte was analyzed for and detected at the concentration shown. [J]: Estimated. The analyte was present, but the reported value may not be accurate or precise. [U]: Undetected. The analyte was analyzed for but not detected above the method detection limit. [UJ]: Detection limit estimated. The analyte was analyzed for but qualified as not detected; the detection limit is estimated. JACOBS' Data Validation Summary- Plantation Pipe Line Poplar Tent Road Site Soil Vapor [R]: Rejected. The data are not useable. [X]: Excluded. Data were not used due to another value being more appropriate. 3. Organic Parameters 3.1 Quality Control Review The following list represents the QA/QC measures that were reviewed during the data quality evaluation procedure for organic data: • Holding Times — The holding times are evaluated to verify that samples were extracted and analyzed within holding times. • Blank samples — Method blank samples were provided for this project. Blank samples enable the reviewer to determine if an analyte may be attributed to sampling or laboratory procedures, rather than environmental contamination from site activities. • Surrogate Recoveries — A surrogate compound is added to each sample and the recovery is used to monitor lab performance and possible matrix interference. • Lab Control Sample (LCS) — These samples are a "controlled matrix", such as humidified nitrogen, in which target compounds have been added prior to extraction/analysis. The recoveries serve as a monitor of the overall performance of each step during the analysis, including sample preparation. • Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples — Spike recovery is used to evaluate potential matrix interferences, as well as accuracy. Precision information is also determined by calculating the reproducibility between the recoveries of each spiked parameter. • Field Duplicate Samples — These samples are collected to determine precision between a native and its duplicate. This information can only be determined when target compounds are detected. 4. Volatile Organic Compound Analyses The QA/QC parameters for VOC analyses by EPA Methods TO-15 and TO-17 for all samples were within acceptable control limits with the exceptions listed below. A brief overview of the data evaluation follows: 4.1 Holding Times (and Sample Receipt) All holding time requirements were met. 4.2 Analytical Blanks No target analytes were detected in the blanks. 4.3 Recoveries — Surrogates, MS/MSD, LCS/LCSD Surrogates and LCS/LCSD recoveries all met acceptance criteria. A MS/MSD set was not collected for this event. 4.4 Field Duplicates Duplicate field samples were collected and submitted to the laboratory for analysis. There are two conditions under which the native and field duplicate are deemed outside acceptance criteria. For condition one, if a result for the native and field duplicate are less than five times the reporting limit, the two results must be within one times the reporting limit to meet acceptance criteria. In condition two, if the result is greater than five times the reporting limit, the two results must agree to within 20 percent relative percent difference to meet acceptance criteria. All acceptance criteria were met. Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site Soil Vapor JACOBS 5. PARCC Precision is defined as the agreement between duplicate results, and was estimated by comparing duplicate LCS recoveries, and field duplicate sample results. The precision between the native and field duplicate sample results for all analyses were within acceptable criteria indicating that the sample matrix did not interfere with the overall analytical process. Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter. In the case of VOC analysis, each of the samples were spiked with a surrogate compound with a known concentration before preparation. The surrogate data provides a measure of the matrix effects as they may affect accuracy and precision of the analytical method. The LCS results demonstrate accuracy of the method. Spike recoveries were within the method acceptance limits, showing no evidence of matrix interferences that affect the usability of the data. Representativeness criteria are a qualitative measure of the degree to which sample data accurately and precisely represent a characteristic environmental condition. Representativeness is a subjective parameter and is used to evaluate the efficacy of the sampling plan design. Representativeness was demonstrated by providing full descriptions in the project scoping documents of the sampling techniques and the rationale used for selecting sampling locations. Comparability is another qualitative measure designed to express the confidence with which one data set may be compared to another. Factors that affect comparability are sample collection and handling techniques, sample matrix type, and analytical method. Comparability is limited by the other PARCC parameters because data sets can be compared with confidence only when precision and accuracy are known. Data from this investigation are comparable with other previous data collected at the site due to the laboratories use of EPA or appropriate methods to analyze the samples and supported by the results of the laboratory's analytical reports. Completeness is defined as the percentage of measurements that are judged to be valid compared to the total number of measurements made. There were no data rejected and or seen as not usable due to quality control or sampling issues. 6. Conclusion A review of the laboratory's analytical data submitted regarding the investigation of PPL Poplar Tent Road soil vapor sampling event in October 2019 by Jacobs has been completed. The validation demonstrated that the analytical systems were in control at the time of sample analyses and all data results can be used in the decision -making process as qualified by the data validation process. urofins Environment Testing TestAmerica ANALYTICAL REPORT Eurofins TestAmerica, Knoxville 5815 Middlebrook Pike Knoxville, TN 37921 Tel: (865)291-3000 Laboratory Job ID: 140-17050-1 Client Project/Site: Poplar Tent Road CH2M Hill, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, North Carolina 28277 Attn: Mike Skeean Authorized for release by. 1013012019 5:12:29 PM Jamie McKinney, Senior Project Manager (865)291-3000 jamie.mckinney@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Table of Contents Laboratory Job ID: 140-17050-1 CoverPage .............................................. 1 Table of Contents ......................................... 2 Definitions/Glossary....................................... 3 Case Narrative ........................................... 4 Detection Summary ........................................ 5 Client Sample Results ...................................... 6 Default Detection Limits .................................... 9 Surrogate Summary ....................................... 10 QC Sample Results ........................................ 11 QC Association Summary ................................... 12 Lab Chronicle ............................................ 13 Certification Summary ...................................... 15 Method Summary ......................................... 16 Sample Summary ......................................... 17 Chain of Custody .......................................... 18 Receipt Checklists ......................................... 20 Eurofins TestAmerica, Knoxville Page 2 of 20 10/30/2019 Definitions/Glossary Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. a Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Eurofins TestAmerica, Knoxville Page 3 of 20 10/30/2019 Case Narrative Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Laboratory: Eurofins TestAmerica, Knoxville Narrative Job ID: 140-17050-1 0 Job Narrative 140-17050-1 Comments No additional comments. Receipt The samples were received on 10/18/2019 10:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice. Air - GC/MS VOA Methods TO 15 LL, TO-14A, TO-15: EPA methods TO-14A and TO-15 specify the use of humidified "zero air" as the blank reagent for canister cleaning, instrument calibration and sample analysis. Ultra -high purity humidified nitrogen from a cryogenic reservoir is used in place of "zero air" by Eurofins TestAmerica Knoxville. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Eurofins TestAmerica, Knoxville Page 4 of 20 10/30/2019 Detection Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 ENo Detections. Client Sample ID: SV-10R2-101719 INo Detections. Client Sample ID: SV-14R-101719 LNo Detections. Client Sample ID: SV-5R-101719 ENo Detections. Client Sample ID: SV-5RD-101719 1 No Detections. This Detection Summary does not include radiochemical test results. F Job ID: 140-17050-1 Lab Sample ID: 140-17050-1 Lab Sample ID: 140-17050-2 Lab Sample ID: 140-17050-3 Lab Sample ID: 140-17050-4 Lab Sample ID: 140-17050-5 Page 5 of 20 Eurofins TestAmerica, Knoxville 10/30/2019 Client Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: SV-12R-101719 Lab Sample ID: 140-17050-1 Date Collected: 10/17/19 11:44 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyzed Dil Fac 10/21/19 23:26 1 u 10/21/19 23:26 1 10/21/19 23:26 1 10/21/19 23:26 1 10/21/19 23:26 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/21/19 23:26 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/21/19 23:26 1 Toluene ND 4.5 2.9 ug/m3 10/21/19 23:26 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/21/19 23:26 1 o-Xylene ND 3.5 0.65 ug/m3 10/21/19 23:26 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 96 60 - 140 10121119 23:26 1 Client Sample ID: SV-10R2-101719 Lab Sample ID: 140-17050-2 Date Collected: 10/17/19 14:51 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene Surrogate 4-Bromofluorobenzene (Surr) Analyzed Dil Fac 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac ND 2.6 0.26 ug/m3 10/22/19 00:13 1 ND 3.5 0.56 ug/m3 10/22/19 00:13 1 ND 4.5 2.9 ug/m3 10/22/19 00:13 1 ND 3.5 1.3 ug/m3 10/22/19 00:13 1 ND 3.5 0.65 ug/m3 10/22/19 00:13 1 %Recovery Qualifier Limits Prepared Analyzed Dil Fac 95 60 - 140 10122119 00:13 1 Client Sample ID: SV-14R-101719 Lab Sample ID: 140-17050-3 Date Collected: 10/17/19 15:10 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.80 0.080 ppb v/v 10/22/19 00:59 1 Ethylbenzene ND 0.80 0.13 ppb v/v 10/22/19 00:59 1 Toluene ND 1.2 0.78 ppb v/v 10/22/19 00:59 1 m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v 10/22/19 00:59 1 o-Xylene ND 0.80 0.15 ppb v/v 10/22/19 00:59 1 Eurofins TestAmerica, Knoxville Page 6 of 20 10/30/2019 Client Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: SV-14R-101719 Lab Sample ID: 140-17050-3 Date Collected: 10/17/19 15:10 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 00:59 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 00:59 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 00:59 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 00:59 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 00:59 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac C 4-Bromofluorobenzene (Surr) 94 60 - 140 10122119 00:59 1 Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17050-4 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyzed Dil Fac 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 01:47 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 01:47 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 01:47 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 01:47 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 01:47 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 60 - 140 10122119 01:47 1 Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17050-5 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.80 0.080 ppb v/v 10/22/19 02:34 1 Ethylbenzene ND 0.80 0.13 ppb v/v 10/22/19 02:34 1 Toluene ND 1.2 0.78 ppb v/v 10/22/19 02:34 1 m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v 10/22/19 02:34 1 o-Xylene ND 0.80 0.15 ppb v/v 10/22/19 02:34 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 02:34 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 02:34 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 02:34 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 02:34 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 02:34 1 Eurofins TestAmerica, Knoxville Page 7 of 20 10/30/2019 Client Sample Results Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17050-5 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 60 - 140 10122119 02:34 1 Eurofins TestAmerica, Knoxville Page 8 of 20 10/30/2019 Default Detection Limits Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte RL MDL Units Benzene 0.080 0.0080 ppb v/v Benzene 0.26 0.026 ug/m3 Ethylbenzene 0.080 0.013 ppb v/v Ethylbenzene 0.35 0.056 ug/m3 m-Xylene & p-Xylene 0.080 0.029 ppb v/v m-Xylene & p-Xylene 0.35 0.13 ug/m3 o-Xylene 0.080 0.015 ppb v/v o-Xylene 0.35 0.065 ug/m3 Toluene 0.12 0.078 ppb v/v Toluene 0.45 0.29 ug/m3 Eurofins TestAmerica, Knoxville Page 9 of 20 10/30/2019 Surrogate Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Matrix: Air Prep TVDe: Total/NA BFB Lab Sample ID Client Sample ID (60-140) 140-17050-1 SV-12R-101719 96 140-17050-2 SV-10R2-101719 95 140-17050-3 SV-14R-101719 94 140-17050-4 SV-5R-101719 99 140-17050-5 SV-5RD-101719 99 LCS 140-34462/1002 Lab Control Sample 97 MB 140-34462/4 Method Blank 90 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Percent Surrogate Recovery (Acceptance Limits) 0 Eurofins TestAmerica, Knoxville Page 10 of 20 10/30/2019 QC Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Lab Sample ID: MB 140-34462/4 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA Analysis Batch: 34462 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.080 0.0080 ppb v/v 10/21/19 11:26 1 Ethylbenzene ND 0.080 0.013 ppb v/v 10/21/19 11:26 1 Toluene ND 0.12 0.078 ppb v/v 10/21/19 11:26 1 m-Xylene & p-Xylene ND 0.080 0.029 ppb v/v 10/21/19 11:26 1 o-Xylene ND 0.080 0.015 ppb v/v 10/21/19 11:26 1 Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene MB MB Result Qualifier ND ND ND ND ND MB MB Surrogate %Recovery Qualifier 4-Bromofluorobenzene (Surr) 90 Lab Sample ID: LCS 140-34462/1002 Matrix: Air Analysis Batch: 34462 Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene RL MDL Unit D Prepared Analyzed Dil Fac 0.26 0.026 ug/m3 10/21/19 11:26 1 0.35 0.056 ug/m3 10/21/19 11:26 1 0.45 0.29 ug/m3 10/21/19 11:26 1 0.35 0.13 ug/m3 10/21/19 11:26 1 0.35 0.065 ug/m3 10/21/19 11:26 1 Limits Prepared Analyzed Dil Fac 60 - 140 10/21/19 11:26 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 1.00 1.00 1.00 2.00 1.00 Spike Added 3.2 4.3 3.8 8.7 4.3 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 97 60 - 140 LCS Result LCS Qualifier Unit D %Rec %Rec. Limits 0.831 ppb v/v 83 70 -130 0.865 ppb v/v 86 70 -130 0.895 ppb v/v 90 70 -130 1.71 ppb v/v 86 70 -130 0.887 ppb v/v 89 70 -130 LCS LCS %Rec. Result Qualifier Unit D %Rec Limits 2.65 ug/m3 83 70 -130 3.76 ug/m3 86 70 -130 3.37 ug/m3 90 70 -130 7.44 ug/m3 86 70 -130 3.85 ug/m3 89 70 -130 Page 11 of 20 Eurofins TestAmerica, Knoxville 10/30/2019 QC Association Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17050-1 Air - GUMS VOA Analysis Batch: 34462 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 140-17050-1 SV-12R-101719 Total/NA Air TO 15 LL 140-17050-2 SV-10R2-101719 Total/NA Air TO 15 LL 140-17050-3 SV-14R-101719 Total/NA Air TO 15 LL 140-17050-4 SV-5R-101719 Total/NA Air TO 15 LL 140-17050-5 SV-5RD-101719 Total/NA Air TO 15 LL MB 140-34462/4 Method Blank Total/NA Air TO 15 LL LCS 140-34462/1002 Lab Control Sample Total/NA Air TO 15 LL Eurofins TestAmerica, Knoxville Page 12 of 20 10/30/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 Date Collected: 10/17/19 11:44 Date Received: 10/18/19 10:00 Job ID: 140-17050-1 Lab Sample ID: 140-17050-1 Matrix: Air F Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 50 mL 500 mL 34462 10/21/19 23:26 S1K TAL KNX Instrument ID: MR Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 14:51 Date Received: 10/18/19 10:00 Batch Batch Prep Type Type Method Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 15:10 Date Received: 10/18/19 10:00 Batch Batch Prep Type Type Method Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-5R-101719 Date Collected: 10/17/19 15:59 Date Received: 10/18/19 10:00 Lab Sample ID: 140-17050-2 Matrix: Air Dil Initial Final Batch Prepared Run Factor Amount A- --mount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 00:13 S1 K TAL KNX Lab Sample ID: 140-17050-3 m Matrix: Air Dil Run Factor Initial Amount Final Amount Batch Number Prepared or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 00:59 S-1—K TAL KNX L Batch Batch Prep Type Type Method Run Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-5RD-101719 Date Collected: 10/17/19 15:59 Date Received: 10/18/19 10:00 F Batch Batch Prep Type Type Method Run Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: Method Blank Date Collected: N/A Date Received: N/A Lab Sample ID: 140-17050-4 Matrix: Air FR- Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 01:47 S1 K TAL KNX Lab Sample ID: 140-17050-5 Matrix: Air Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 02:34 S1 K TAL KNX Lab Sample ID: MB 140-34462/4 Matrix: Air Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 500 mL 500 mL 34462 10/21/19 11:26 S 1 K TAL KNX Instrument ID: MR Eurofins TestAmerica, Knoxville Page 13 of 20 10/30/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-34462/1002 Date Collected: N/A Matrix: Air Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 500 mL 500 mL 34462 10/21/19 09:50 S1K TAL KNX Instrument ID: MR Laboratory References: TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 Eurofins TestAmerica, Knoxville Page 14 of 20 10/30/2019 Accreditation/Certification Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Laboratory: Eurofins TestAmerica, Knoxville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date AFCEE N/A ANAB Dept. of Defense ELAP L2311 02-14-22 ANAB Dept. of Energy L2311.01 02-14-22 ANAB ISO/IEC 17025 L2311 02-13-22 Arkansas DEQ State 2423 06-16-20 California State 2423 06-30-20 Colorado State TN00009 02-29-20 Connecticut State PH-0223 09-30-21 Florida NELAP E87177 06-30-20 Georgia (DW) State 906 04-13-20 Hawaii State NA 04-13-20 Kansas NELAP E-10349 10-31-19 Kentucky (DW) State 90101 12-31-19 Louisiana NELAP 83979 06-30-20 Louisiana NELAP 83979 06-30-20 Louisiana (DW) State LA019 12-31-19 Maryland State 277 03-31-20 Michigan State 9933 04-13-20 Nevada State TN00009 07-31-20 New Hampshire NELAP 2999 01-17-20 New Hampshire NELAP 299919 01-17-20 New Jersey NELAP TN001 06-30-20 New York NELAP 10781 03-31-20 North Carolina (DW) State 21705 07-31-20 North Carolina (WW/SW) State 64 12-31-19 North Carolina (WW/SW) State Program 64 12-31-19 Ohio VAP State CL0059 08-28-20 Oklahoma State 9415 09-01-20 Oregon NELAP TN I O189 01-01-20 Pennsylvania NELAP 68-00576 12-31-19 Tennessee State 02014 04-13-20 Texas NELAP T104704380-18-12 08-31-20 US Fish & Wildlife US Federal Programs 058448 07-31-20 USDA US Federal Programs P330-19-00236 08-20-22 Utah NELAP TN00009 07-31-20 Virginia NELAP 460176 09-15-20 Washington State C593 01-19-20 West Virginia (DW) State 9955C 12-31-19 West Virginia DEP State 345 04-30-20 Wisconsin State 998044300 08-31-20 Job ID: 140-17050-1 Eurofins TestAmerica, Knoxville Page 15 of 20 10/30/2019 Method Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Method Method Description Protocol TO 15 LL Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) EPA Protocol References: EPA = US Environmental Protection Agency Laboratory References: TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 F Job ID: 140-17050-1 Laboratory TAL KNX L Eurofins TestAmerica, Knoxville Page 16 of 20 10/30/2019 Sample Summary Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 140-17050-1 SV-12R-101719 Air 10/17/19 11:44 10/18/19 10:00 Air Canister (I-Liter)#34002420 140-17050-2 SV-10R2-101719 Air 10/17/19 14:51 10/18/19 10:00 Air Canister (I-Liter)#11885 140-17050-3 SV-14R-101719 Air 10/17/19 15:10 10/18/19 10:00 Air Canister (I-Liter)#11540 140-17050-4 SV-5R-101719 Air 10/17/19 15:59 10/18/19 10:00 Air Canister (1-Liter) #11871 140-17050-5 SV-5RD-101719 Air 10/17/19 15:59 10/18/19 10:00 Air Canister (I-Liter)#11726 14 Eurofins TestAmerica, Knoxville Page 17 of 20 10/30/2019 I V 0 c Y N Y E•• O a N N in cc M c8, M co 63 0 N U W u O o X Lu uCO Y� a u_ E y £ N41N G OU Z Q U m z E a C9 (6 U uo. `� (uollues selou ul hpaeds sseeld) a0410 seo 114pOel _ OAS) uolloealx3 aodeA lloS C� i SUE) IIuSICY gelS-goS v NWIN AM JUslgwV/jlV aoopul I adi( a�tlale ` p� (uolloas selou ul Ajpeds eseeld) J0410 K/96 Vd3 v, 9t,W0 W1SV z- i •� 09Z Vd3 �_ •--y / 0E Vd3 (� WIS 9VO1 , G (lanai MO / paepuelS) 96/17 of > > � m �❑ ��-TNT �� V a D !n d O a� a ti c ° f CT \✓ 'v 'd ''a's E E 0 N w w U Ma f y E x a o E-" "1i1e3 A c c� s vN _LO �U1' E ` c N;= cva ya T- E o l(i `T �T N ( ° Fes- n �) wFvim+ � m O `o_ `o_ F- F F US waas N y o j E c c a •R w LL c s M l°/O A Fs :.j1 'C a 't awl 11 U V)SIR v s E V c S 0 l `n a otl zzIN ..J E a 0 T e 4b - E�+- c E CL EL c 'El]" a E o �%�� J 1 1 y S c ar d c J CL O. C O '�O L Q O` O_- iL G CEO t� c ¢U au aina ti to: ) Page 18 of 20 10/30/2019 -d rn N C4 '� A O d y d y •� ei is Z x a�aWdI'm r• o U UU d d U d cUA° a Ri ZZ U �' q oO a. o a o +•+ a y q o � a. c� a Cd ° o a O d o ed a lw 'L� i. •p 'O 14 H Z .d r: Z � rai z L. q `{ 4Oq^, q uUUU U*ci �UUU U iti d °oU as 00o � O5 g000.O ex �UU 000 urn v�U 0to000 U ❑�❑❑ r. ❑U❑�❑❑U❑❑❑❑❑❑v❑❑❑❑ ❑ ❑❑s❑❑❑ ❑❑ z e z r ai •� d b; .� aqi � � � •� C, ^_ � c• 'c� o, a' � chi �' n U u• U 9," w^ q w° O °0 U aQi O ai �.• �'�' t' cv cOd c� q o O +�v+ �„ a 'b � O is W O S1 N N ° U N o F. .cd y t�/� •�+ w �. N Q, p N W `" avi y ^ ? 0 00 ^- 3 p ° A O� `r. dO N N ° U N N ti Qvi CO �+ N CO N N N b bA O O. N CV .M .,q. �t U vi t\ 00 O\ .-� .-� �-r .-� r-+ V1 .-� �G H .--� C�. l� •--i 00 .--i Oi .--i N W M Page 19 of 20 10/30/2019 Gauge ID: Date: G5 10/19/2019 TestAmerica Knoxville - Air Canister Initial Pressure Check Analyst Sample ID Asset # Cleaning Job Cert Size (L) Pressure @ Receipt (-in Hg or +psig) Time Comments BKK 140-17050-A-1 34002420 16760 B 1 -4.5 11:35 BKK 140-17050-A-2 11885 16621 B 1 1 -1.3 11:36 BKK 140-17050-A-3 11540 16760 B 1 -4.8 11:37 BKK 140-17050-A-4 11871 16760 B 1 -6.0 11:38 BKK 140-17050-A-5 11726 16760 B 1 -5.5 11:39 ❑ Receiving —Air Can —Calve Open (NCM # ) ❑ Air - Can P -24 to -25 " - Flow Contr. Works (NCM# ) ❑ Air - Can P -24 to -25 " - Flow Contr. Faulty (NCM# ) ❑ Air - Can P Out -26" - Flow Contr. Works (NCM# ) ❑ Air - Can P Out -26" - Flow Comr. Faulty (NCM# ) ❑ Air - Can P Low -24 to -25 " - Grab Sample (NCM# ) ❑ Air - Can P Low -26 "- Grab Sample (NCM# ) 16 101113MIl.UM Page 20 of 20 MS038 r14, 6/19/15 10/30/2019 urofins � Environment Testing TestAmerica ANALYTICAL REPORT C Eurofins TestAmerica, Knoxville 5815 Middlebrook Pike Knoxville, TN 37921 Tel: (865)291-3000 Laboratory Job ID: 140-17112-1 Laboratory Sample Delivery Group: WO 1910445 Client Project/Site: Poplar Tent Road Foi CH2M Hill, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, North Carolina 28277 Attn: Mike Skeean 't_ 0- �4c? r Authorized for release by: 1012412019 2:51:19 PM Jamie McKinney, Senior Project Manager (865)291-3000 jamie.mckinney@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Table of Contents Laboratory Job ID: 140-17112-1 F SDG: WO 1910445 U CoverPage .............................................. 1 Table of Contents ......................................... 2 Definitions/Glossary....................................... 3 Case Narrative ........................................... 4 Detection Summary ........................................ 5 Client Sample Results ...................................... 6 Surrogate Summary ....................................... 7 QC Sample Results ........................................ 8 QC Association Summary ................................... 9 Lab Chronicle ............................................ 10 Method Summary ......................................... 12 Sample Summary ......................................... 13 Chain of Custody .......................................... 14 Eurofins TestAmerica, Knoxville Page 2 of 14 10/24/2019 Definitions/Glossary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Qualifiers Subcontract Qualifier Qualifier Description U COMPOUND ANALYZED FOR BUT NOT DETECTED ABOVE THE DETECTION LIMIT Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Job ID: 140-17112-1 SDG: WO 1910445 Eurofins TestAmerica, Knoxville Page 3 of 14 10/24/2019 Case Narrative Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17112-1 Laboratory: Eurofins TestAmerica, Knoxville Narrative Job ID: 140-17112-1 SDG: WO 1910445 0 Job Narrative 140-17112-1 Comments No additional comments. Receipt The samples were received on 10/18/2019 9:45 AM; the samples arrived in good condition, properly preserved and, where required, on ice. T017 A sampling volume of 0.250 L was used to convert ng to ug/m3 for the associated Lab BLank. No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. Eurofins TestAmerica, Knoxville Page 4 of 14 10/24/2019 Detection Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 ENo Detections. Client Sample ID: SV-14R-101719 INo Detections. Client Sample ID: SV-10R2-101719 LNo Detections. Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID: 140-17112-1 Lab Sample ID: 140-17112-2 Lab Sample ID: 140-17112-3 Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17112-4 ENo Detections. Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17112-5 F ENo Detections. F This Detection Summary does not include radiochemical test results. Eurofins TestAmerica, Knoxville Page 5 of 14 10/24/2019 Client Sample Results Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 Date Collected: 10/17/19 11:59 Date Received: 10/18/19 09:45 Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID: 140-17112-1 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1912:45 10/18/1912:45 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1912:45 10/18/1912:45 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 91 50 - 150 10118119 12:45 10118119 12:45 1.00 Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 13:02 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-2 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1914:33 10/18/1914:33 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1914:33 10/18/1914:33 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 80 50 - 150 10118119 14:33 10118119 14:33 1.00 Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 15:24 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-3 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1913:51 10/18/1913:51 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1913:51 10/18/1913:51 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed DY Fac NAPHTHALENE-D8 84 50 - 150 10118119 13:51 10118119 13:51 1.00 Client Sample ID: SV-5R-101719 Date Collected: 10/17/19 16:09 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-4 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1915:15 10/18/1915:15 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1915:15 10/18/1915:15 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 78 50 - 150 10118119 15:15 10118119 15:15 1.00 Client Sample ID: SV-5RD-101719 Date Collected: 10/17/19 16:18 Date Received: 10/18/19 09:45 Method: TO17 - General Subcontract Method Analyte Result Qualifier 2-METHYLNAPHTHALENE ND U NAPHTHALENE ND U Surrogate NAPHTHALENE-D8 RL MDL Unit 20 2.6 UG/M3 20 1.7 UG/M3 %Recovery Qualifier Limits 87 50-150 Lab Sample ID: 140-17112-5 Matrix: Air D Prepared Analyzed Dil Fac 10/18/19 15:57 10/18/19 15:57 1.00 10/18/19 15:57 10/18/19 15:57 1.00 Prepared Analyzed Dil Fac 10118119 15:57 10118119 15:57 1.00 Eurofins TestAmerica, Knoxville Page 6 of 14 10/24/2019 Surrogate Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method: T017 - General Subcontract Method Matrix: Air ATHALEN Lab Sample ID Client Sample ID (50-150) Job ID: 140-17112-1 SDG: WO 1910445 Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) 140-17112-1 SV-12R-101719 91 140-17112-2 SV-14R-101719 80 140-17112-3 SV-10R2-101719 84 140-17112-4 SV-5R-101719 78 140-17112-5 SV-5RD-101719 87 Surrogate Legend C NAPHTHALENE-D8 = NAPHTHALENE-D8 Method: T017 - General Subcontract Method Matrix: AIR Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) ATHALEN Lab Sample ID Client Sample ID (50-150) 1910445-06A Method Blank 90 1910445-08A Lab Control Sample 90 1910445-08AA Lab Control Sample Dup 92 Surrogate Legend NAPHTHALENE-D8 = NAPHTHALENE-D8 Eurofins TestAmerica, Knoxville Page 7 of 14 10/24/2019 QC Sample Results Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method: T017 - General Subcontract Method Lab Sample ID: 1910445-06A Matrix: AIR Analysis Batch: 11101801 Blank Blank Analyte Result Qualifier RL MDL Unit 2-METHYLNAPHTHALENE ND U 20 UG/M3 NAPHTHALENE ND U 20 UG/M3 Blank Blank Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 11101801_P D Prepared Analyzed Dil Fac 10/18/19 11:29 10/18/19 11:29 1.00 10/18/19 11:29 10/18/19 11:29 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 90 50 - 150 10118119 11:29 10118119 11:29 1.06 Lab Sample ID: 1910445-08A Client Sample ID: Lab Control Sample C Matrix: AIR Prep Type: Total/NA Analysis Batch: 11101801 Prep Batch: 11101801_P Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits 2-METHYLNAPHTHALENE 100 95 UG/M3 95 70-130 NAPHTHALENE 100 93 UG/M3 93 70-130 LCS LCS Surrogate %Recovery Qualifier NAPHTHALENE-D8 90 Lab Sample ID: 1910445-08AA Matrix: AIR Analysis Batch: 11101801 Analyte 2-METHYLNAPHTHALENE NAPHTHALENE LCS Dup LCS Dup Surrogate %Recovery Qualifier NAPHTHALENE-D8 92 Limits 50-150 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Prep Batch: 11101801 P Spike LCS Dup LCS Dup %Rec. RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 100 94 UG/M3 94 70-130 1.0 25 100 92 UG/M3 92 70-130 1.1 25 Limits 50-150 Eurofins TestAmerica, Knoxville Page 8 of 14 10/24/2019 QC Association Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Subcontract Analysis Batch: 11101801 Lab Sample ID Client Sample ID 140-17112-1 SV-12R-101719 140-17112-2 SV-14R-101719 140-17112-3 SV-10R2-101719 140-17112-4 SV-5R-101719 140-17112-5 SV-5RD-101719 1910445-06A Method Blank 1910445-08A Lab Control Sample 1910445-08AA Lab Control Sample Dup Prep Batch: 11101801_P Lab Sample ID Client Sample ID 140-17112-1 SV-12R-101719 140-17112-2 SV-14R-101719 140-17112-3 SV-10R2-101719 140-17112-4 SV-5R-101719 140-17112-5 SV-5RD-101719 1910445-06A Method Blank 1910445-08A Lab Control Sample 1910445-08AA Lab Control Sample Dup F Job ID: 140-17112-1 SDG: WO 1910445 Prep Type Matrix Method Prep Batch Total/NA Air T017 11101801—P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA AIR T017 11101801 P Total/NA AIR T017 11101801_P Total/NA AIR T017 11101801_P Prep Type Matrix Method Prep Batch Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA AIR NONE Total/NA AIR NONE Total/NA AIR NONE Eurofins TestAmerica, Knoxville Page 9 of 14 10/24/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: SV-12R-101719 Lab Sample ID: 140-17112-1 Date Collected: 10/17/19 11:59 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 13:02 Date Received: 10/18/19 09:45 Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 15:24 Date Received: 10/18/19 09:45 Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 11101801 10/18/1912:45 Eurofins _P 1.00 11101801 10/18/1912:45 SU Eurofins Ldu Jdfitple ILJ: I'FU- I / I IL-L Matrix: Air Dil Initial Final Batch Prepared F Factor Amount Amount Number or Analyzed Analyst Lab M 1 11101801 10/18/1914:33 Eurofins _P 1.00 11101801 10/18/1914:33 SU Eurofins Lab Sample ID: 140-17112-3 Matrix: Air C Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1913:51 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1913:51 SU Eurofins Instrument ID: Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17112-4 Date Collected: 10/17/19 16:09 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1915:15 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1915:15 SU Eurofins Instrument ID: Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17112-5 Date Collected: 10/17/19 16:18 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1915:57 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1915:57 SU Eurofins Instrument ID: Page 10 of 14 Eurofins TestAmerica, Knoxville 10/24/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: Method Blank Lab Sample ID: 1910445-06A Date Collected: N/A Matrix: AIR Date Received: N/A Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 11101801 10/18/1911:29 Eurofins _P 1.00 11101801 10/18/1911:29 SU Eurofins Client Sample ID: Lab Control Sample Date Collected: N/A Date Received: N/A Batch Batch Dil Initial Prep Type Type Method Run Factor Amount Total/NA Prep NONE 1 Total/NA Analysis T017 1.00 Instrument ID: Client Sample ID: Lab Control Sample Dup Date Collected: N/A Date Received: N/A L-dri adrnpiu iu: iy iuwfa-uom Matrix: AIR Final Batch Prepared F Amount Number or Analyzed Analyst Lab M 11101801 10/18/19 09:23 Eurofins _P 11101801 10/18/19 09:23 SU Eurofins Lab Sample ID: 1910445-08AA Matrix: AIR C Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1910:05 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1910:05 SU Eurofins Instrument ID: Laboratory References: Eurofins = Eurofins Air Toxics, 180 Blue Ravine Road, Suite B, Folsom, CA 95630 Page 11 of 14 Eurofins TestAmerica, Knoxville 10/24/2019 Method Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method Method Description Protocol Subcontract T017 - naphthalene and 2-methylnaphthalene None Protocol References: None = None Laboratory References: Eurofins = Eurofins Air Toxics, 180 Blue Ravine Road, Suite B, Folsom, CA 95630 F Job ID: 140-17112-1 SDG: WO 1910445 Laboratory Eurofins L Eurofins TestAmerica, Knoxville Page 12 of 14 10/24/2019 Sample Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 140-17112-1 SV-12R-101719 Air 10/17/19 11:59 10/18/19 09:45 140-17112-2 SV-14R-101719 Air 10/17/19 13:02 10/18/19 09:45 140-17112-3 SV-10R2-101719 Air 10/17/19 15:24 10/18/19 09:45 140-17112-4 SV-5R-101719 Air 10/17/19 16:09 10/18/19 09:45 140-17112-5 SV-5RD-101719 Air 10/17/19 16:18 10/18/19 09:45 Eurofins TestAmerica, Knoxville Page 13 of 14 10/24/2019 CD M CD cr cr 0- < C 1 i (D a ^�gsN fY 1 F : CD m --41 CD -� p � (D€(D(D 7J ( 17 Q Q Q N � p*1 � b] Q �n _0 c m c� m CD m m (D 3 m 3 (D 3'CD the (:t CD Ed°i F� CD Vi CL d, : _ s D 0 0 0 0 O `0 p 0 a m ncp O [D N o > S ((DD 6 N D T In — C I 0 r m CL cmamv a +t 0 ♦ I O m z o X 3 f7C]NOgS7il: ro m-o T- e„ =r 0- - -i cu CD � W n �� 3 c 0 N o u mao�m �c m m2L0 W -6 8 0 - m m n Z � § cc p y ro 0 ID ' J_j B� p Q O p 0m�'o a tD' IDm Z o 4*: OmW'< a. "—" 3 3 O m Q2.4Q ep oR m� m CD M,!± 5 0,cn -� `A00 W ID m —fQ .. .... O CL \ c 7p � sm :3n CD CL m c° a n m c C - � © m ©gin s s Q❑❑ �'�'' o p C -� Z -- N' (o.o' I" n m (D O — a ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ I Indoor Air ca c a CO cn C i =1 ❑ ❑ ❑ ❑ L ❑ ❑ G ❑ I ❑ I outdoor Air F C- Soil Vapor - t ©o®o©ram®a®a Page 4 of O m o 03 JACOBS Memorandum 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 Subject Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site Project Name Plantation Pipe Line Poplar Tent Road Site Attention Mike Skeean/CLT, Jacobs From Tiffany Davis/GNV, Jacobs Date October 30, 2019 Copies to Juan Acaron/GNV, Jacobs 1. Introduction The purpose of this memorandum is to present the results of the data validation process for the water supply well samples collected at the Plantation Pipe Line Company (PPL) Poplar Tent Road. The samples were collected in October 2019. Samples were submitted to SGS North America Inc. in Scott, Louisiana and Test America Laboratories in Pittsburgh, Pennsylvania for the following analyses: • SW8260B Volatile Organic Compounds (VOCs) These data were validated for compliance with the analytical method requirements. This process included a review of these data to assess the accuracy, precision, and completeness based upon procedures described in guidance documents such as the Environmental Protection Agency (EPA) National Functional Guidelines for Organic Data Review (EPA 2017). The Quality assurance/quality control (QA/QC) summary forms and data reports were reviewed and the resulting findings are documented within each subsection that follows. During the data validation, if QA/QC parameters were not within the acceptance limits, associated sample results were appended with a primary qualifying flag that indicated a possible anomaly with these data. The qualifying flags originated during the data review and validation processes. This qualification also included the use of secondary sub -qualifier flags. The secondary qualifiers provide the reasoning behind the assignment of a qualifier to these data. The definitions of the primary qualifiers are presented below. 2. Validation Flag Definitions The following primary qualifiers were used to qualify the data: [=]: Detected. The analyte was analyzed for and detected at the concentration shown. [J]: Estimated. The analyte was present but the reported value may not be accurate or precise. [U]: Undetected. The analyte was analyzed for but not detected above the method detection limit. [UJ]: Detection limit estimated. The analyte was analyzed for but qualified as not detected; the detection limit is estimated. [R]: Rejected. The data are not useable. [X]: Excluded. Data were not used due to another value being more appropriate. JACOBS" Data Validation Summary- Plantation Pipe Line Poplar Tent Road Site I Organic Parameters 3.1 Quality Control Review The following list represents the QA/QC measures that were reviewed during the data quality evaluation procedure for organic data: • Holding Times — The holding times are evaluated to verify that samples were extracted and analyzed within holding times. • Blank samples — Method blank and trip blank samples were provided for this project. Blank samples enable the reviewer to determine if an analyte may be attributed to sampling or laboratory procedures, rather than environmental contamination from site activities. • Surrogate Recoveries — Surrogate Compounds are added to each sample and the recoveries are used to monitor lab performance and possible matrix interference. • Lab Control Sample (LCS) — These samples are a "controlled matrix", laboratory reagent water, in which target compounds have been added prior to extraction/analysis. The recoveries serve as a monitor of the overall performance of each step during the analysis, including sample preparation. • Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples — Spike recovery is used to evaluate potential matrix interferences, as well as accuracy. Precision information is also determined by calculating the reproducibility between the recoveries of each spiked parameter. • Field Duplicate Samples — These samples are collected to determine precision between a native and its duplicate. This information can only be determined when target compounds are detected. 4. Volatile Organic Compound Analyses The QA/QC parameters for VOC analyses by SW-846 8260B for all samples were within acceptable control limits with the exceptions listed below. A brief overview of the data evaluation follows: 4.1 Holding Time All holding time requirements were met. 4.2 Field Duplicates Duplicate field samples were collected and submitted to the laboratory for analysis. There are two conditions under which the native and field duplicate are deemed outside acceptance criteria. For condition one, if a result for the native and field duplicate are less than five times the reporting limit, the two results must be within one times the reporting limit to meet acceptance criteria. In condition two, if the result is greater than five times the reporting limit, the two results must agree to within 20 percent relative percent difference to meet acceptance criteria. No field duplicates were included in this data set. 4.3 Recoveries - Surrogate, MS/MSD and LCS/LCSD Surrogates, MS/MSD, and LCS/LCSD recoveries all met acceptance criteria. 4.4 Analytical Blanks Naphthalene (0.38ug/L J) was detected in the method blank. All sample results were non -detect, therefore no data were affected. 5. PARCC Precision is defined as the agreement between duplicate results, and was estimated by comparing duplicate MS recoveries, and field duplicate sample results. The precision between the duplicate and MS recoveries were within acceptable criteria indicating no matrix interference. Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter. Each of the samples were spiked with a surrogate compound with a known concentration Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site JACOBS before preparation. The surrogate and MS/MSD data provides a measure of the matrix effects as they may affect accuracy and precision of the analytical method. The LCS results demonstrate accuracy of the method. Spike recoveries were within the method acceptance limits, showing no evidence of matrix interferences that affect the usability of the data. Representativeness criteria are a qualitative measure of the degree to which sample data accurately and precisely represent a characteristic environmental condition. Representativeness is a subjective parameter and is used to evaluate the efficacy of the sampling plan design. Representativeness was demonstrated by providing full descriptions in the project scoping documents of the sampling techniques and the rationale used for selecting sampling locations. Completeness is defined as the percentage of measurements that are judged to be valid compared to the total number of measurements made. There were no data rejected and or seen as not usable due to quality control or sampling issues. Comparability is another qualitative measure designed to express the confidence with which one data set may be compared to another. Factors that affect comparability are sample collection and handling techniques, sample matrix type, and analytical method. Comparability is limited by the other PARCC parameters because data sets can be compared with confidence only when precision and accuracy are known. Data from this investigation are comparable with other previous data collected at the site due to the laboratories use of EPA or appropriate methods to analyze the samples and supported by the results of the laboratory's analytical reports. 6. Conclusion A review of the analytical data submitted regarding the investigation of PPL Poplar Tent Road sampling event in October 2019 by Jacobs has been completed. The validation demonstrated that the analytical systems were in control and all data results can be used in the decision -making process. ffm Scott, LA The results set forth herein are provided by SGS North America Inc. a-Hl ydcopy 2. 0 Automated Report Technical Report for Kinder Morgan CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC 03158700. B. PN. GEN. PT. EM SGS Job Number: LA58554 Sampling Date: 10/ 15/ 19 Report to: Jacobs CH2M 14120 Ballantyne Corporate Place Charlotte, NC 28277 mike. skeean@jacobs. com; kelly. gutowski@jacobs. ATTN: Mike Skeean Total number of pages in report: 16 Ac Fp Ar . Test results contained within this data package meet the requirements Ron Benj a illl n of the National Environmental Laboratory Accreditation Program Lab Director and/or state specific certification programs as applicable. Client Service contact: Ralph Frye 337-237-4775 Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31), NC(487), SC(73004001), NJ(LA007), TX(T104704186-18-16), WV(257) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775 SGS is the sole authority for authorizing edits or modifications to this document. Please share your ideas about Unauthorized modification of this report is strictly prohibited. how we can serve you better at: Review standard terms at: http://www.sgs.com/en/terms-and-conditions EHS.US.CustomerCare@sgs.com 1 of 16 LA58554 Sections: Table of Contents -1- Section1: Sample Summary................................................................................................... 3 Section2: Summary of Hits.................................................................................................... 4 Section3: Sample Results........................................................................................................ 5 3.1: LA58554-1: WSW-13................................................................................................... 6 3.2: LA58554-2: TRIP BLANK.......................................................................................... 7 Section4: Misc. Forms............................................................................................................ 8 4.1: Chain of Custody........................................................................................................... 9 Section 5: MS Volatiles - QC Data Summaries..................................................................... 13 5.1: Method Blank Summary................................................................................................ 14 5.2: Blank Spike/Blank Spike Duplicate Summary.............................................................. 15 5.3: Matrix Spike/Matrix Spike Duplicate Summary........................................................... 16 W, SGS North America Inc. Sample Summary Kinder Morgan Job No: LA58554 CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Project No: 03158700. B. PN. GEN. PT. EM ample Collected Matrix Client lumber Date Time By Received Code Type Sample ID This report contains results reported as ND = Not detected. The following applies: Organics ND = Not detected above the RL LA58554-1 10/15/19 09:45 TH/VVY10/16/19 AQ Water WSW-13 LA58554-ID 10/15/19 09:45 TH/VW10/16/19 AQ Water Dup/MSD WSW-13 LA58554-IS 10/15/19 09:45 TH/VWiO/16/19 AQ Water Matrix Spike WSW-13 LA58554-2 10/15/19 00:00 TH/VWiO/16/19 AQ Trip Blank Water TRIP BLANK 6 3of16 LA58554 Summary of Hits Page 1 of 1 Job Number: LA58554 Account: Kinder Morgan Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Collected: 10/ 15/ 19 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA58554-1 WSW-13 No hits reported in this sample. LA58554-2 TRIP BLANK No hits reported in this sample. 6 4of16 LA58554 i SGS Scott, LA Section 3 Sample Results Report of Analysis 6 5of16 LA58554 SGS North America Inc. Report of Analysis Client Sample ID: WSW-13 Lab Sample ID: LA58554-1 Date Sampled: 10/15/19 Matrix: AQ - Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Page 1 of 1 j File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085570.D 1 10/18/19 21:32 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL Units Q 71-43-2 Benzene ND 1.0 ug/l 108-88-3 Toluene ND 1.0 ug/l 100-41-4 Ethylbenzene ND 1.0 ug/l 1330-20-7 Xylene (total) ND 2.0 ug/1 91-20-3 Naphthalene ND 5.0 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 117% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 102% 89-107% ND = Not detected RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 6of16 LA58554 SGS North America Inc. Report of Analysis Client Sample ID: TRIP BLANK Lab Sample ID: LA58554-2 Date Sampled: 10/15/19 Matrix: AQ - Trip Blank Water Date Received: 10/ 16/ 19 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Page 1 of 1 N File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1X0085538.D 1 10/18/19 14:24 CP n/a n/a VIX3846 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL Units Q 71-43-2 Benzene ND 1.0 ug/l 108-88-3 Toluene ND 1.0 ug/l 100-41-4 Ethylbenzene ND 1.0 ug/l 1330-20-7 Xylene (total) ND 2.0 ug/1 91-20-3 Naphthalene ND 5.0 ug/l CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 104% 81-120% 2037-26-5 Toluene-138 101% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% ND = Not detected RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound 6 7of16 LA58554 ffm Scott, LA Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody 1 Section 4 6 8of16 LA58554 SGS Noet i America Inc - Orlando Cain of Custody SGS - ORLANDO JOB # : PAGE OF --I— -- _— .407425- 700 FAX' 407425-0707 SGS - ORLANDO Quote # SKIFF # J�5jl ✓F�Matrix Client / Reporting Information an Com Name: + p yL�I Project Name Project Information ,� ,/� F—D �+ � 'X- �11 5 Analytical Information Codes - nn mg water GW Ground water WW-Water sw Water Water so - soil SL- Sludge 01-Oil CIO- Other Liquid AIR - Air SOL -OI f Solid Addess:/ y 120 gA ryn�E L c 4,&lWSu/Tj:MDree/Sr1 0 POPG/trt iY�l20 City: State: Zip: �IHIit26oiTE NL Z$Z /111w7%XS-rate State c Proe Co t: E is ��t'� Cturvt✓Sk/ Gunvsxr �-91wsr. Project# �58 0' . Pf�; �,P� � p'" Phone #:,,�o _ �-/ ? Z1 7 (J Fax # �I Sampler(s) Name(s (Printed) V✓ /frL / Sam lar 1: Sampler 2: t)r IIII-1/1"f Client Purch a Order # o SGS OrlandoOF sample # Field ID I Point of Coll 'on COLLECTION CONT MERMFORMATION r LAB USE ONLY GATE TIME SAt�LED I yy MATRI% Torur BOTTLES € O '3 g 1n/Sw - �3 R1s /;; d �9y5 vJ y li 'I i I I Turnaround Time Business days) s Data Deliverable Information -" -Comments /Remarks 10 Day (Business) Approved By: / Date: 7 Day 5 Day l° 3 Day RUSH 2 Day RUSH 1 Day RUSH Other Rush TIA Data Available VIA Email or Lablink QCOMMERCIAL "A" (RESULTS ONLY) COMMERCIAL "B" (RESULTS PLUS QC) REDTt (EPA LEVEL 3) I FULLT1 (EPA LEVEL 4) EDD'S I �l �I Sam le Custody must be dot unua ted below each time samples change possession including courier delivery. e q ishgdpy Sa pler/Affiliation 1 Lf� ��� Date Time Received By/Afflliatio f Relinquished B�/gifiliat' n 3 Date Time: X c, R eiv By/AH' i tlon 4 R mqu' hetl b I tion L 5 Da TI (in i eceived By/ ifiliati . S Relinquished By/Affiliation Date Time: received B A iation Lab Use Onl : Cooler Temperature s) Celsius (corrected): hdc'//www sas m / n/terms-and-conditions OR II / ID-SMT-WOi-03-FORM-COC(1) Rev 031318 V-J LA58554: Chain of Custody Page 1 of 4 6 9of16 LA58554 _ 2368 p690 ft cf., Fess® Packa,i'61l 'm 8129 USA { 1 From Dace ! • ! 5 � samara � �j<�%rJ'r � `•'' I t. t l FCk �y �Pkona Neme t Com o.ar' 1 �ta(iU i Add reae LP f f Y" 'T p YBurintemalBilling Reference ` Phone 3 To �? Reciplerds o Name wqw E cam a�1�°anm'aN°`.. (337)237-47751"—Rold So Address S Po.em.°w.o.zn w-- INC — C,.� 1 1 [] aamdmo " " ORTH AMEBIC SGS Na �aawene. gLVD Adneeaa" '°°nn109 CONIMISSI nr i AFAYET(E t1'!'�"v�� �0 02�❑ �'�--- "~`� PackedesuP to l5alhs °m •TeMx�pp°'' "NUFa'Wn �in °I,Uf°xa' q 6cpressPacka9eseMce , �~ '' Fed6c20a�A ❑ skx,ew,n ❑ �� Frst�em""�xxm� s.weno.w°rvxmmaW^ I rsrro° d ,aa.xe ❑ FedExP ❑ "wwb " r s" ommx= _ a uxwn�'.m ❑ �&W;,�xeenu Saver 'u""°e yam,.°,m,rrtorma.uc Q• FvmE�mvS9.nB^vre"ight 3i •o�.a..xmem PedEs ❑ Bdter io'', p 5 Packaging FedEs ❑ Tu6e 3 ❑ ❑ Fed&EnveloPe" FedEx Pak" ❑ Bos p tons w..n.r•wry sum.r.eus.M..swa. � � � . B Special Haadlin9 and 136WeNSi9nawze Pi OeliveN rer,m.rn>a-a,r.eua�om�srx �` , • ❑dm°f.rnrar,sma.�eom�am, �n.aoM" t No SiBnawraRe9uired ❑ �rxo.aeam ,c,;e,.n.r tkis .. aToj r Doasshipmetdc°^taios!o*dsln den9 o.eae*nc"mcu.cs•° ---� BNtVIca �tx Ves � OxxMlm ❑ MkeOxtNa QNo ❑ ^sr°A°"'.❑y.aw. Cargo AircrahBnN —. �d°¢¢xmY .VPYrveOTNW No a 7 pw"t Bill yeo.wr.lNnUxeo.udw+-- —'1 ❑ a a C.sWC^eek creaac Ser�dar, sew ❑ ReciPieM Third Pa^y ❑ l'!col TozelWaght pt1Ta ToplPecka9es � (,44 �pexm;nreea�3.MnGWeabem>s �;.' w,.a>m,=mra,..�..axaaaara=.aax LA58554: Chain of Custody Page 2 of 4 6 10 of 16 LA58554 Company DeptdFloor/Suite/Room Street Address We cannot deliver to PA. boxes or Po. zip codes. City State Zip Country ORIGIN 1D: SRWR (B03) 203-4214 8 V RIC OHA WILLIANS a� SHIP DFlTE: ACTWGT:. R 15007 p� 18 12' SCOTT, LA 70583 UNITED STATES US BILL ILL THIRD PARTY TO SAMPLE RECIEVING SGS NORTH AMERICA INC SCC 109 COMMISSION BLVD LAFAYETTE LA 70508 �803) 238-4121 CEF: nu: no: oEnr III IIIIIIIIIIIIIIII I ILIIIII Iili I IIII III I III IIII IIIIIII i I1111111I I111111 (y FedEx JJ � i i� Ir I Exprea8 FEI� WED:, - 16 OCT 3:OOP TRHN IO2O01 8129 2368 0690 STANDARD OVERNIGHT AHS XH LF7 70508 tn# LA-�S LFT L J - LA58554: Chain of Custody Page 3 of 4 6 11 of 16 LA58554 SGS Sample Receipt Summary Job Number: LA58554 Client: JACOBS Date / Time Received: 10/16/2019 8:45:00 AM Delivery Method: Cooler Temps (Initial/Adjusted): #1: (2.1/2.1): DV440 Cooler Security Y or N Y or N 1. Custody Seals Present: ❑d ❑ 3. COC Present: 2 ❑ 2. Custody Seals Intact: W ❑ 4. Smpl Dates/Time OK W ❑ Cooler Temperature Y or N 1. Temp criteria achieved: ❑� ❑ 2. Thermometer ID: DV440; 3. Cooler media: Ice (direct contact) 4. No. Coolers: 1 Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: 0 ❑ ❑ 2. Trip Blank listed on CDC: 0 ❑ ❑ 3. Samples preserved properly: W11 ❑ 4. VOCs headspace free: 0 ❑ ❑ Fed Ex Project: POPLAR TENT RD. Airbill Xs: 8129 2368 0690 Sample Integrity - Documentation 1. Sample labels present on bottles: 2. Container labeling complete: 3. Sample container label / COC agree: Sample Integrity - Condition 1. Sample recvd within HT: 2. All containers accounted for: 3. Condition of sample: Sample Integrity - Instructions 1. Analysis requested is clear: 2. Bottles received for unspecified tests 3. Sufficient volume recvd for analysis: 4. Compositing instructions clear: 5. Filtering instructions clear: Y or N ❑� ❑ o ❑ ❑� ❑ Y or N ❑� ❑ o ❑ Intact Y or N N/A ❑� ❑ ❑ 0 ❑� ❑ ❑ ❑ ❑O ❑ ❑ ❑J LA58554: Chain of Custody Page 4 of 4 A 0 6 12 of 16 LA58554 i SGS Scott, LA Section 5 MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries � 13 of 16 LA58554 Method Blank Summary Page 1 of 1 Job Number: LA58554 Account: KINDERGA Kinder Morgan Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X3846-MB2 1X0085532.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: LA58554-1, LA58554-2 CAS No. Compound Result RL Units Q 71-43-2 Benzene ND 1.0 ug/l 100-41-4 Ethylbenzene ND 1.0 ug/l 91-20-3 Naphthalene 0.38 5.0 ug/l J 108-88-3 Toluene ND 1.0 ug/l 1330-20-7 Xylene (total) ND 2.0 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 100% 81-120% 2037-26-5 Toluene-D8 98% 93-105% 460-00-4 4-Bromofluorobenzene 99% 89-107% Method: SW846 8260D 6 14 of 16 LA58554 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA58554 Account: KINDERGA Kinder Morgan Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1X3846-BS2 1X0085534.D 1 10/18/19 CP n/a n/a V1X3846 V1X3846-BSD2 1X0085536.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: Method: SW846 8260D LA58554-1, LA58554-2 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/l % RPD Rec/RPD 71-43-2 Benzene 20 22.6 113 21.4 107 5 82-119/14 100-41-4 Ethylbenzene 20 21.5 108 21.0 105 2 82-120/15 91-20-3 Naphthalene 20 24.1 121 24.5 123 2 60-137/24 108-88-3 Toluene 20 22.5 113 21.8 109 3 82-118/15 1330-20-7 Xylene (total) 60 69.4 116 67.6 113 3 82-122/15 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 103% 103% 81-120% 2037-26-5 Toluene-D8 98% 99% 93-105% 460-00-4 4-Bromofluorobenzene 100% 103% 89-107% * = Outside of Control Limits. 6 15 of 16 LA58554 Matrix Spike/Matrix Spike Duplicate Summary Page 1 of 1 Job Number: LA58554 Account: KINDERGA Kinder Morgan Project: CHMHNCC: PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch LA58554-1MS 1X0085572.D 2 10/18/19 CP n/a n/a V1X3846 LA58554-1MSD 1X0085574.D 2 10/18/19 CP n/a n/a V1X3846 LA58554-1 1X0085570.D 1 10/18/19 CP n/a n/a V1X3846 The QC reported here applies to the following samples: LA58554-1, LA58554-2 Method: SW846 8260B LA58554-1 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD 71-43-2 Benzene ND 40 42.1 105 40 41.7 104 1 41-155/14 100-41-4 Ethylbenzene ND 40 42.6 107 40 39.9 100 7 50-147/15 91-20-3 Naphthalene ND 40 41.1 103 40 43.6 109 6 30-153/24 108-88-3 Toluene ND 40 41.2 103 40 40.4 101 2 40-153/15 1330-20-7 Xylene (total) ND 120 133 ill 120 127 106 5 46-154/15 CAS No. Surrogate Recoveries MS MSD LA58554-1 Limits 17060-07-0 1,2-Dichloroethane-D4 114% 114% 117% 81-120% 2037-26-5 Toluene-D8 98% 100% 98% 93-105% 460-00-4 4-Bromofluorobenzene 105% 104% 102% 89-107% * = Outside of Control Limits. 6 16 of 16 LA58554 urofins U Environment Testing TestAmerica ANALYTICAL REPORT L Eurofins TestAmerica, Pittsburgh 301 Alpha Drive RIDC Park Pittsburgh, PA 15238 Tel: (412)963-7058 F Laboratory Job ID: 180-97304-1 Client Project/Site: Poplar Tent Road Foi CH2M Hill, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, North Carolina 28277 Attn: Mike Skeean Authorized for release by: 1012512019 2:56:46 PM Jamie McKinney, Senior Project Manager (865)291-3000 jamie.mckinney@testamericainc.com This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. PA Lab ID:02-00416 Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Table of Contents Laboratory Job ID: 180-97304-1 CoverPage .............................................. 1 Table of Contents ......................................... 2 Case Narrative ........................................... 3 Definitions/Glossary....................................... 4 Certification Summary ...................................... 5 Sample Summary ......................................... 7 Method Summary ......................................... 8 Lab Chronicle ............................................ 9 Client Sample Results ...................................... 10 QC Sample Results ........................................ 11 QC Association Summary ................................... 13 Chain of Custody .......................................... 14 Receipt Checklists ......................................... 15 Eurofins TestAmerica, Pittsburgh Page 2 of 15 10/25/2019 Case Narrative Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 180-97304-1 Laboratory: Eurofins TestAmerica, Pittsburgh Narrative Job Narrative 180-97304-1 Comments No additional comments. Job ID: 180-97304-1 Receipt The samples were received on 10/16/2019 9:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the cooler at receipt was 3.41 C. GC/MS VOA Method 8260B: The continuing calibration verification (CCV) analyzed in batch 180-295298 was outside the method criteria for the following analyte: Naphthalene (LOW). A CCV standard at or below the reporting limit (RL) was analyzed with the affected samples and found to be acceptable. As indicated in the reference method, sample analysis may proceed; however, any detection for the affected analyte is considered estimated. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Eurofins TestAmerica, Pittsburgh Page 3 of 15 10/25/2019 Definitions/Glossary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Qualifiers GC/MS VOA Qualifier Qualifier Description J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value. Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Job ID: 180-97304-1 0 Eurofins TestAmerica, Pittsburgh Page 4 of 15 10/25/2019 Accreditation/Certification Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Laboratory: Eurofins TestAmerica, Pittsburgh All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date Arkansas DEQ State 19-033-0 06-27-20 California State 2891 04-30-20 Connecticut State PH-0688 09-30-20 Florida NELAP E871008 06-30-20 Georgia State PA 02-00416 04-30-20 Illinois NELAP 004375 06-30-20 Kansas NELAP E-10350 03-31-20 Kentucky (UST) State 162013 04-30-20 Kentucky (WW) State KY98043 12-31-19 Louisiana NELAP 04041 06-30-20 Minnesota NELAP 042-999-482 12-31-19 Nevada State PA00164 07-31-20 New Hampshire NELAP 2030 04-04-20 New Hampshire NELAP 2030 04-04-20 New Jersey NELAP PA005 06-30-20 New York NELAP 11182 04-01-20 North Carolina (WW/SW) State 434 12-31-19 North Dakota State R-227 04-30-20 Oregon NELAP PA-2151 02-06-20 Pennsylvania NELAP 02-00416 04-30-20 Rhode Island State LAO00362 12-30-19 South Carolina State 89014 04-30-20 Texas NELAP T104704528 03-31-20 US Fish & Wildlife US Federal Programs 058448 07-31-20 USDA Federal P-Soil-01 06-26-22 USDA US Federal Programs P330-16-00211 06-26-22 Utah NELAP PA001462019-8 05-31-20 Virginia NELAP 10043 09-15-20 West Virginia DEP State 142 01-31-20 Wisconsin State 998027800 08-31-20 Job ID: 180-97304-1 Eurofins TestAmerica, Pittsburgh Page 5 of 15 10/25/2019 Accreditation/Certification Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Laboratory: Eurofins TestAmerica, Knoxville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date AFCEE N/A ANAB Dept. of Defense ELAP L2311 02-14-22 ANAB Dept. of Energy L2311.01 02-14-22 ANAB ISO/IEC 17025 L2311 02-13-22 Arkansas DEQ State 2423 06-16-20 California State 2423 06-30-20 Colorado State TN00009 02-29-20 Connecticut State PH-0223 09-30-21 Florida NELAP E87177 06-30-20 Georgia (DW) State 906 04-13-20 Hawaii State NA 04-13-20 Kansas NELAP E-10349 10-31-19 Kentucky (DW) State 90101 12-31-19 Louisiana NELAP 83979 06-30-20 Louisiana NELAP 83979 06-30-20 Louisiana (DW) State LA019 12-31-19 Maryland State 277 03-31-20 Michigan State 9933 04-13-20 Nevada State TN00009 07-31-20 New Hampshire NELAP 2999 01-17-20 New Hampshire NELAP 299919 01-17-20 New Jersey NELAP TN001 06-30-20 New York NELAP 10781 03-31-20 North Carolina (DW) State 21705 07-31-20 North Carolina (WW/SW) State 64 12-31-19 North Carolina (WW/SW) State Program 64 12-31-19 Ohio VAP State CL0059 08-28-20 Oklahoma State 9415 09-01-20 Oregon NELAP TN I O189 01-01-20 Pennsylvania NELAP 68-00576 12-31-19 Tennessee State 02014 04-13-20 Texas NELAP T104704380-18-12 08-31-20 US Fish & Wildlife US Federal Programs 058448 07-31-20 USDA US Federal Programs P330-19-00236 08-20-22 Utah NELAP TN00009 07-31-20 Virginia NELAP 460176 09-15-20 Washington State C593 01-19-20 West Virginia (DW) State 9955C 12-31-19 West Virginia DEP State 345 04-30-20 Wisconsin State 998044300 08-31-20 Job ID: 180-97304-1 Eurofins TestAmerica, Pittsburgh Page 6 of 15 10/25/2019 Sample Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Job ID: 180-97304-1 Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 180-97304-1 WSW-13 Water 10/15/19 09:45 10/16/19 09:00 180-97304-2 TRIP BLANK Water 10/15/19 00:00 10/16/19 09:00 C 0 Eurofins TestAmerica, Pittsburgh Page 7 of 15 10/25/2019 Method Summary Client: CH2M Hill, Inc. Job ID: 180-97304-1 Project/Site: Poplar Tent Road Method Method Description Protocol Laboratory EPA 8260B Volatile Organic Compounds (GC/MS) SW846 TAL PIT 5030B Purge and Trap SW846 TAL PIT Protocol References: SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates. Laboratory References: TAL PIT = Eurofins TestAmerica, Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058 Eurofins TestAmerica, Pittsburgh Page 8 of 15 10/25/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 180-97304-1 Client Sample ID: WSW-13 Lab Sample ID: 180-97304-1 Date Collected: 10/15/19 09:45 Matrix: Water Date Received: 10/16/19 09:00 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis EPA 8260E 1 5 mL 5 mL 295298 10/18/19 13:54 PJJ TAL PIT Instrument ID: CHHP10 Client Sample ID: TRIP BLANK Lab Sample ID: 180-97304-2 Date Collected: 10/15/19 00:00 Matrix: Water Date Received: 10/16/19 09:00 • Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis EPA 8260E 1 5 mL 5 mL 295298 10/18/19 14:21 PJJ TAL PIT Instrument ID: CHHP10 Laboratory References: TAL PIT = Eurofins TestAmerica, Pittsburgh, 301 Alpha Drive, RIDC Park, Pittsburgh, PA 15238, TEL (412)963-7058 Analyst References: Lab: TAL PIT Batch Type: Analysis PJJ = Patrick Journet Page 9 of 15 Eurofins TestAmerica, Pittsburgh 10/25/2019 Client Sample Results Client: CH2M Hill, Inc. Job ID: 180-97304-1 Project/Site: Poplar Tent Road Client Sample ID: WSW-13 Lab Sample ID: 180-97304-1 Date Collected: 10/15/19 09:45 Matrix: Water Date Received: 10/16/19 09:00 Method: EPA 8260B - Volatile Organic Compounds (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethylbenzene ND 5.0 2.2 ug/L 10/18/1913:54 1 Benzene ND 5.0 2.0 ug/L 10/18/1913:54 1 m,p-Xylene ND 5.0 1.9 ug/L 10/18/1913:54 1 Naphthalene ND 5.0 3.9 ug/L 10/18/1913:54 1 o-Xylene ND 5.0 2.4 ug/L 10/18/1913:54 1 Toluene ND 5.0 1.7 ug/L 10/18/1913:54 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 91 58- 139 10/18/19 13:54 1 4-Bromofluorobenzene (Surr) 73 64 - 122 10118119 13:54 1 Dibromofluoromethane (Surr) 102 70 - 127 10118119 13:54 1 Toluene-d8 (Surr) 105 71- 125 10118119 13:54 1 Client Sample ID: TRIP BLANK Lab Sample ID: 180-97304-2 Date Collected: 10/15/19 00:00 Matrix: Water Date Received: 10/16/19 09:00 Method: EPA 8260B - Volatile Organic Compounds (GC/MS) C Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethylbenzene ND 5.0 2.2 ug/L 10/18/1914:21 1 Benzene ND 5.0 2.0 ug/L 10/18/1914:21 1 m,p-Xylene ND 5.0 1.9 ug/L 10/18/1914:21 1 Naphthalene ND 5.0 3.9 ug/L 10/18/1914:21 1 o-Xylene ND 5.0 2.4 ug/L 10/18/1914:21 1 Toluene ND 5.0 1.7 ug/L 10/18/1914:21 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 102 58- 139 10118119 14:21 1 4-Bromofluorobenzene (Surr) 77 64 - 122 10118119 14:21 1 Dibromofluoromethane (Surr) 110 70 - 127 10118119 14:21 1 Toluene-d8 (Surr) 107 71- 125 10118119 14:21 1 Eurofins TestAmerica, Pittsburgh Page 10 of 15 10/25/2019 QC Sample Results Client: CH2M Hill, Inc. Job ID: 180-97304-1 Project/Site: Poplar Tent Road Method: EPA 8260B - Volatile Organic Compounds (GC/MS) Lab Sample ID: MB 180-295298/7 Client Sample ID: Method Blank Matrix: Water Prep Type: Total/NA Analysis Batch: 295298 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Ethylbenzene ND 5.0 2.2 ug/L 10/18/19 09:52 1 Benzene ND 5.0 2.0 ug/L 10/18/19 09:52 1 m,p-Xylene ND 5.0 1.9 ug/L 10/18/19 09:52 1 Naphthalene ND 5.0 3.9 ug/L 10/18/19 09:52 1 o-Xylene ND 5.0 2.4 ug/L 10/18/19 09:52 1 Toluene ND 5.0 1.7 ug/L 10/18/19 09:52 1 MB MB F Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 1,2-Dichloroethane-d4 (Surr) 97 58- 139 10118119 09:52 1 ED 4-Bromofluorobenzene (Surr) 77 64 - 122 10118119 09:52 1 Dibromofluoromethane (Surr) 107 70 - 127 10118119 09:52 1 LToluene-d8 (Surr) 114 71- 125 10118119 09:52 1 Lab Sample ID: LCS 180-295298/4 Client Sample ID: Lab Control Sample Matrix: Water Prep Type: Total/NA Analysis Batch: 295298 Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits Ethylbenzene 10.0 10.8 ug/L 108 73 -127 Benzene 10.0 9.86 ug/L 99 72 -118 m,p-Xylene 10.0 10.6 ug/L 106 73 -125 Naphthalene 10.0 5.29 ug/L 53 10 -150 o-Xylene 10.0 10.7 ug/L 107 72 -124 Toluene 10.0 10.5 ug/L 105 69 -125 LCS LCS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 98 58- 139 4-Bromofluorobenzene (Surr) 91 64 - 122 Dibromofluoromethane (Surr) 110 70 - 127 Toluene-d8 (Surr) 110 71- 125 Lab Sample ID: 180-97304-1 MS Client Sample ID: WSW-13 Matrix: Water Prep Type: Total/NA Analysis Batch: 295298 Sample Sample Spike MS MS %Rec. Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits Ethylbenzene ND 10.0 9.75 ug/L 98 73 -127 Benzene ND 10.0 9.81 ug/L 98 72 -118 m,p-Xylene ND 10.0 10.1 ug/L 101 73-125 Naphthalene ND 10.0 3.95 J ug/L 40 10 -150 o-Xylene ND 10.0 9.80 ug/L 98 72 -124 Toluene ND 10.0 9.60 ug/L 96 69 -125 MS MS Surrogate %Recovery Qualifier Limits 1,2-Dichloroethane-d4 (Surr) 111 58- 139 4-Bromofluorobenzene (Surr) 94 64 - 122 Dibromofluoromethane (Surr) 119 70 - 127 Eurofins TestAmerica, Pittsburgh Page 11 of 15 10/25/2019 QC Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Method: EPA 8260B - Volatile Organic Compounds (GC/MS) (Continued) Lab Sample ID: 180-97304-1 MS Matrix: Water Analysis Batch: 295298 MS MS Surrogate %Recovery Qualifier Toluene-d8 (Surr) 110 Lab Sample ID: 180-97304-1 MSD Matrix: Water Analysis Batch: 295298 Sample Sample Analyte Result Qualifier Ethylbenzene ND Benzene ND m,p-Xylene ND Naphthalene ND o-Xylene ND Toluene ND Surrogate 1,2-Dichloroethane-d4 (Surr) 4-Bromofluorobenzene (Surr) Dibromofluoromethane (Surr) Toluene-d8 (Surr) MSD MSD %Recovery Qualifier 99 86 106 101 Limits 71- 125 Spike Added 10.0 10.0 10.0 10.0 10.0 10.0 Limits 58 - 139 64 - 122 70- 127 71_125 MSD MSD Result Qualifier Unit 9.26 ug/L 9.06 ug/L 9.29 ug/L 4.33 J ug/L 9.35 ug/L 9.17 ug/L F Job ID: 180-97304-1 Client Sample ID: WSW-13 Prep Type: Total/NA L Client Sample ID: WSW-13 Prep Type: Total/NA %Rec. RPD D %Rec Limits RPD Limit 93 73-127 5 20 91 72.118 8 20 93 73-125 8 20 m 43 10-150 9 35 93 72-124 5 20 92 69-125 5 20 Page 12 of 15 Eurofins TestAmerica, Pittsburgh 10/25/2019 QC Association Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 180-97304-1 GC/MS VOA Analysis Batch: 295298 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 180-97304-1 WSW-13 Total/NA Water EPA 8260B 180-97304-2 TRIP BLANK Total/NA Water EPA 8260B MB 180-295298/7 Method Blank Total/NA Water EPA 8260B LCS 180-295298/4 Lab Control Sample Total/NA Water EPA 8260B 180-97304-1 MS WSW-13 Total/NA Water EPA 8260B 180-97304-1 MSD WSW-13 Total/NA Water EPA 8260B Eurofins TestAmerica, Pittsburgh Page 13 of 15 10/25/2019 c A v � o t0� c Oo0°v ° a x °(�°p C c Z 0v)a uU w x z a z z z= F¢ no u c .t O G E E m E mz Oa 0o_co 1i ` w E U U 0 00 o c N O n ¢ U w _ a '° u¢Ox �'n C d 0)o zN t� x ¢ L)O¢ cxOL u ��¢ --mmE 0/ o o U O N OI d O m w ❑p 'n S Z N 2 z¢ Q o p W W c OU V a a p 2 Q Q] U p W LL (7 S- Y p • 0 j 5 f ueulquoo jo aegwnN Igo, al of w Q ` O' d E E d E v d v zmi L. m m V m o w N y y U 7 Oi CO m O w n m a � o E N c O � 1 C M U o U N `w E U)O O u m a r a E Q 01 + 991W + X318 WOW) - 009Z9 ceuajeyjydeN u u o > > c Y U) co eN+cse NautoO"allow a aE E cYi � „o E E m _1 0 U 0 U 0 U is ac° `� E o i V) U 4 ri°- co 9 E E E — T uO h p cn ~ 3 p a o d ¢ 2 r o o d `w� :! u� E E c o ¢ ii c'� O 0 o 0 3 0 E m. _ m t du t d k v w a o' ra- a y 0 a 0 c � U � O O A N Z m U7 L_ U) > c — o d E �L ` U _ - y 7 U O `l = _0 O U O _ y N o E N N m m w o a Q y d y 4- a n in y E cCO '7 N CUB C v;o Z o Nm v rnz — +� N Z d >, - - y d T n N W N w N o = >. m N O_ o o E m � ' .> d a E .Q - .� 7 U C.iUY UU ¢ c�U inZ a� E w�c as .- in R L1 O W Page 14 of 15 10/25/2019 Login Sample Receipt Checklist Client: CH2M Hill, Inc. Job Number: 180-97304-1 Login Number: 97304 List Number: 1 Creator: Say, Thomas C Question List Source: Eurofins TestAmerica, Pittsburgh Answer Comment Radioactivity wasn't checked or is </= background as measured by a survey True meter. The cooler's custody seal, if present, is intact. True Sample custody seals, if present, are intact. True The cooler or samples do not appear to have been compromised or True tampered with. Samples were received on ice. True Cooler Temperature is acceptable. True Cooler Temperature is recorded. True COC is present. True COC is filled out in ink and legible. True COC is filled out with all pertinent information. True Is the Field Sampler's name present on COC? True There are no discrepancies between the containers received and the COC. True Samples are received within Holding Time (excluding tests with immediate True HTs) Sample containers have legible labels. True Containers are not broken or leaking. True Sample collection date/times are provided. True Appropriate sample containers are used. True Sample bottles are completely filled. True Sample Preservation Verified. True There is sufficient vol. for all requested analyses, incl. any requested True MS/MSDs Containers requiring zero headspace have no headspace or bubble is True <6mm (1/4"). Multiphasic samples are not present. True Samples do not require splitting or compositing. True Residual Chlorine Checked. N/A Eurofins TestAmerica, Pittsburgh Page 15 of 15 10/25/2019 Beverly, Trudy From: Skeean, Mike/CLT <Mike.Skeean@jacobs.com> Sent: Thursday, March 26, 2020 11:43 AM To: Beverly, Trudy Subject: RE: [External] Plantation Pipe Line Company - Poplar Tent Road Site - Semiannual Monitoring Data Submittal • I email. Do not click links or open attachment „emu verify. Send all suspicious email as an attachment to nc. ov Hi Trudy. I posted the Poplar Tent data submittal to the FTP site here: ftp://207.4.64.25/CAB/MO/ [207.4.64.251. Thanks Mike From: Beverly, Trudy <trudy.beverly@ncdenr.gov> Sent: Thursday, March 26, 2020 10:45 AM To: Skeean, Mike/CLT <Mike.Skeean@jacobs.com> Subject: RE: [External] Plantation Pipe Line Company - Poplar Tent Road Site - Semiannual Monitoring Data Submittal Mike — We have had a change in document submittals as of last Friday. I will forward you the notice in a separate email. They may have missed some consultants. Trudy Trudy Beverly, L.G. Hydrogeologist, Division of Waste Management _ North Carolina Department of Environmental Quality ���r UST Section, Mooresville Regional Office 01 704.235.2182 (Office) Trudy. B everlykncdenr. gov Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Office Mailing Address: 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Branch's Underground Storage Tanks Website Address: https://deq.nc.gov/about/divisions/waste-management/ust Branch's Above Ground Storage Tanks Website Address: https://deg.nc.gov/about/divisions/waste-management/ust/ast-program INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES: httDs:Hdea.nc. gov/about/divisions/waste-management/waste-management-rules-data/waste-management-eis-mans File Review Procedures: httos://deq.nc. gov/about/divisions/waste-manaaement/ust/file-review-procedures#mooresville-regional-office ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche): https://deg.nc.gov/about/divisions/waste-management/laserfiche Document Submittal & UST File Names for Laserfiche Policies: https:Hfiles.nc.eov/ncdeg/W aste%2OMana2ement/DWM/UST/WhatsNew/Final-Electronic-Document-Submittal-Policy.odf hgps:Hfiles.nc.gov/ncdeq/Waste%20Management/D WM[UST/Corrective%2OAction/UST%20file%20names%20for%2OLaserfiche.docx From: Skeean, Mike/CLT [mailto:Mike.Skeean@iacobs.com Sent: Thursday, March 26, 2020 10:29 AM To: Beverly, Trudy <trudy.beverly@ncdenr.gov> Cc: ierry aycock@kindermorgan.com; Jessica Toll (iessica toll@kindermorgan.com) <iessica toll@kindermorgan.com>; rmorton@wcsr.com; SuCooper@wcsr.com; Brian Pace <bpace@pacedevelop.com>; wilsodg@gmail.com; Debbie Nestora <ndlnestora@aol.com>; pam bernard@bellsouth.net; Ed Perez <EPerez@drhorton.com>; 0ason.goldstein@amecfw.com; Corporate Environmental Group<CorporateEnvironmentalGroup@drhorton.com> Subject: [External] Plantation Pipe Line Company - Poplar Tent Road Site - Semiannual Monitoring Data Submittal �R External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to report.spam@nc.gov All, Please find attached an electronic copy of the Semiannaul Monitoring Data Submittal (October 2019 and January 2020 Monitoring Events) for the Plantation Pipe Line Company Poplar Tent Road Site. Please let me know if you have any questions regarding the submittal. Trudy, a hard copy and electronic version with the NCDEQ-required file name will arrive in your office tomorrow. Thank you, Mike Mike Skeean, P.E. I Jacobs [iacobs.coml I Senior Project Manager 0:+1.704.543.3285 1 M:+1.704.206.0869 I mike.skeean(cDoacobs.com 14120 Ballantyne Corporate Place, Suite 200 1 Charlotte, NC 28277 1 USA NOTICE - This communication may contain confidential and privileged information that is for the sole use of the intended recipient. Any viewing, copying or distribution of, or reliance on this message by unintended recipients is strictly prohibited. If you have received this message in error, please notify us immediately by replying to the message and deleting it from your computer. NOTICE - This communication may contain confidential and privileged information that is for the sole use of the intended recipient. Any viewing, copying or distribution of, or reliance on this message by unintended recipients is strictly prohibited. If you have received this message in error, please notify us immediately by replying to the message and deleting it from your computer.