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HomeMy WebLinkAbout7407_Pitt_CandDLandfillInc_20200331_Dec2019GW_FID1395018wood. WATER QUALITY MONITORING REPORT DECEMBER 2019 SEMIANNUAL SAMPLING EVENT CONSTRUCTION AND DEMOLITION DEBRIS LANDFILL, PITT COUNTY FACILITY PERMIT NO. 7407-CDLF-2001, 2009 Prepared For: C&D Landfill, Inc. Prepared By: Wood Environment & Infrastructure Solutions, Inc. Wood Project No.: 6480-19-9035 March 26, 2020 wood. March 26, 2020 Ms. Jackie Drummond, Hydrogeologist North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 2090 US Highway 70 Swannanoa, North Carolina 28778 Subject: C&D Landfill, Inc., Phases 1 and 2 Facility Permit Number 7407-CDLF-2001, 2009 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No.: 6480-19-9035 Dear Ms. Drummond: On behalf of C&D Landfill, Inc., Wood Environment & Infrastructure Solutions, Inc. (Wood; formerly Amec Foster Wheeler) is submitting the enclosed Water Quality Monitoring Report for the December 2020 semiannual monitoring event. The monitoring event was performed between December 11 and 16, 2019. This sampling event included analyzing groundwater samples from each of the active wells for Appendix II constituents, selected natural attenuation parameters, and 1,4-dioxane. This report provides details of the field activities, recommendations based on current and historical data May 2020. laboratory analyses, and presents conclusions and The next semiannual monitoring event is scheduled for Please call Sheri Knox at 919-381-9913 if you have any questions or comments. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Damian Hriciga, PG Senior Geologist Enclosed: Water Quality Monitoring Report cc: Judson Whitehurst David Garrett Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 Tel: (919) 381-9900 / Fax: (919) 381-9901 www.woodplc.com Licensure: NC Engineering F-1253 / NC Geology C-247 Sheri Knox, PE, PMP Associate Project Manager i ENR USE ONLY ❑Paper Re9ort ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reoortina Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Sheri Knox Phone: 919.389.9913 E-mail: sheri.knox(ilwoodDlc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) C&D Landfill, Inc. 802 Recycling Lane 7406-CDLF- December 11, 12, 16, 2019 CDLF Phases 1&2 Greenville, NC 27834 2001, 2009 .0500 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring OX Assessment Monitoring Corrective Action Type of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data ❑ Other(specify) X Surface water monitoring data Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Damian Hriciga / Senior Geologist 919.381.9000 Facili resentAtive Name (Print) Title (Area Code) Telephone Nu Signature Date 4021 Stirrup Creek Drive, Suite 100, Durham, NC 27703 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) Affix NC Lirseh 6� l�eci; kjr.2 if 4f G15 _ � ..1 NR Seal wood. WATER QUALITY MONITORING REPORT DECEMBER 2019 SEMIANNUAL SAMPLING EVENT CONSTRUCTION AND DEMOLITION DEBRIS LANDFILL, PITT COUNTY FACILITY PERMIT NO. 7407-CDLF-2001, 2009 Prepared For: C&D Landfill, Inc. 802 Recycling Lane Greenville, North Carolina 27834 (252) 757-0023 Prepared By: Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 (919) 381-9900 Woodplc.com Registered in North Carolina Engineering and Land Surveying License No. F-1253 Wood Project No.: 6480-19-9035 March 26, 2020 Damian Hriciga, PG Senior Geologist Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 Durham, North Carolina 27703 Tel: (919) 381-9900 / Fax: (919) 381-9901 www.woodplc.com Licensure: NC Engineering F-1253 / NC Geology C-247 Sheri Knox, PE, PMP Associate Project Manager Water Quality Monitoring Report wood. December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 Table of Contents 1.0 INTRODUCTION............................................................................................................ 1 2.0 GROUNDWATER AND SURFACE WATER MONITORING ACTIVITIES ......................... 2 3.0 GROUNDWATER LEVELS AND FLOW........................................................................... 3 4.0 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS ............................... 3 4.1 Volatile Organic Compounds (VOCs)............................................................... 3 4.2 Semi -Volatile Organic Compounds (SVOCs) and Pesticides ........................... 4 4.3 Metals................................................................................................................ 4 4.4 Inorganics and other Constituents................................................................... 5 5.0 DISCUSSION OF CONTAMINANTS OF CONCERN....................................................... 6 5.7.7 Volatile Organic Compounds.................................................................... 6 5. 7.2 Appendix 1 and 11 Metals........................................................................... 7 6.0 CONCLUSIONS.............................................................................................................8 TABLES Table 1 — Groundwater Level and Flow Data — December 2019 Table 2 — Summary of Field Parameters — December 2019 Table 3 — Summary of Groundwater Analytical Data — VOCs, SVOCs, and other Contaminants — December 2019 Table 4 — Summary of Surface Water Analytical Data — December 2019 Table 5 — Summary of Groundwater Analytical Data, Metals, Inorganics, and other Constituents — December 2019 FIGURES Figure 1 — Site Location Map Figure 2 — Monitoring Well and Surface Water Sampling Location Map Figure 3 — Groundwater Elevation Map — December 2019 Figure 4 — Groundwater and Surface Water Standard Exceedance Map — December 2019 APPENDICES Appendix A — Laboratory Analytical Reports Appendix B — Historical Analytical Data and Groundwater Elevations Appendix C — Mann -Kendall Trend Analyses Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 1.0 INTRODUCTION wood. C&D Landfill, Inc. owns and operates the Construction and Demolition Debris Landfill located at 802 Recycling Lane, Greenville, Pitt County, North Carolina (Site; Figure 1). Phase 1 became operational in 2001 and Phase 2 became operational in 2009. The landfill is permitted by the North Carolina Department of Environmental Quality (NCDEQ), Division of Waste Management (DWM), Solid Waste Section (SWS) under Permits 7407-CDLF-2001 and 7407-CDLF-2009. Groundwater and surface water monitoring have been performed at Phase 1 since May 2001, and at Phase 2 since August 2009. Both phases are in the assessment stage of the Assessment and Corrective Action Program for C&DLF Facilities and Units. An Assessment of Corrective Actions (ACM) Report was prepared for the Site in October 2017. Based on the ACM, a permit modification application was submitted to the SWS on December 6, 2019, indicating that the selected groundwater remedy for the Site was monitored natural attenuation (MNA) supported by landfill capping upon closure. On March 9, 2020, the SWS approved the permit modification request and selected groundwater remedies and indicated that a Corrective Action Plan (CAP) was due to be submitted for the Site within 90 days. This report presents the results of the second semiannual monitoring event for year 2019. Analytical data are compared to Groundwater Protections Standards (GWPSs) and Surface Water Protections Standards (SWPSs). GWPSs are either the 15A NCAC 02L .0202 Groundwater Standards (2L Groundwater Standards) or Interim Maximum Allowable Concentrations (IMACs). SWPSs include the 15A NCAC 02B Water Quality Standards for Surface Water (213 Surface Water Standards), North Carolina In -Stream Target Values for Surface Waters (Target Values) or EPA National Recommended Water Quality Criteria for Aquatic Life & Human Health, as appropriate. Phases 1 and 2 of the landfill are separated by a channelized central drainage feature that originates onsite and predates either phase of the landfill. Phase 2 is located north of the drainage feature, while Phase 1 is located to the south. Both phases are isolated from their surroundings by tributaries to Grindle Creek and wetlands. Permitting studies have established the adjacent water bodies as on -site discharge points for the uppermost aquifer. Downgradient areas consist of agricultural and wooded marshland leading to Grindle Creek and on to the Tar River. Much of the downgradient area is beneath the 100-year flood level and is not anticipated to undergo development. No groundwater users have been identified down gradient of the site. The groundwater in the uppermost aquifer is intercepted by the surface streams within and just beyond the facility boundary. The October 2017 ACM Report identified an Area of Concern (AOC) centered on the channelized drainage feature where volatile organic compounds (VOCs) have been reported in groundwater samples. The AOC originates north of the drainage feature, along the south side of Phase 2, and extends south from the drainage feature near MW-8 to the southwest corner of Phase 1 near MW-3S. In 2014 and 2015, an Alternate Source Demonstration (ASD) was performed that focused on the soils within and near the drainage feature, however, the results were inconclusive. The groundwater monitoring network consists of 12 wells within Phase 1 and 10 wells within Phase 2. Within Phase 1 there is one upgradient, background well (MW-1 S), eight downgradient compliance wells (MW-2S, MW-3S, MW- 4, MW-5, MW-6, MW-7, MW-3A, and MW-8), and three deeper wells (MW-1 D, MW-2D, and MW-3D). Within Phase 2 there are three upgradient wells (MW-9A [background], MW-16, and MW-17), six down gradient compliance (MW-10, MW-11, MW-12S, MW-13, MW-14S, and MW-15), and one deeper well (MW-14D). Well construction data is summarized in Table 1 and well locations are illustrated in Figure 2. Four surface water sampling locations have been defined at the Site (SW-1, SW-2, SW-3, and SW-4). Sampling locations SW-1 and SW-2 monitor the tributary on the south side of Phase 1, which originates offsite to the east with SW-1 monitoring background conditions. Sampling locations SW-3 and SW-4 monitor the tributary (itself Page 1 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. partially channelized) on the west side of Phase 2, which originates offsite to the north with SW-4 monitoring background. The surface water sampling locations are illustrated in Figure 2. 2.0 GROUNDWATER AND SURFACE WATER MONITORING ACTIVITIES Groundwater and surface water monitoring activities were conducted by Environment 1, Inc. (Environment 1) and are summarized in this section as reported by Environment 1. Groundwater samples were collected from 22 groundwater monitoring wells and 4 surface water sampling locations between December 11 and 16, 2019. The sampling event was conducted in accordance with the Sampling and Analysis Plan dated May 2008, the Groundwater Assessment Work Plan dated June 2009, and the SWS Guidelines for Groundwater, Soil, and Surface Water Sampling. Prior to sampling the monitoring wells, the wellheads were inspected and the depth to water in each was were measured using an electronic water level meter. Depth to water measurements were recorded after a sufficient time for water levels within the wells to have equilibrated with atmospheric pressure. Groundwater was purged and sampled using a peristaltic pump and low -flow methodology. Temperature, pH, dissolved oxygen, oxidation/reduction potential (ORP), and turbidity were measured and recorded. Surface water samples were collected by direct submersion of sample containers into the streams at designated locations. Field parameters measured during the collection of groundwater and surface water samples are summarized in Table 2. Each sample was placed into laboratory -supplied sample bottles by a technician wearing new nitrile gloves. The samples were preserved according to the requirements for the type of analysis, chilled, and returned to Environment 1 in Greenville, North Carolina within the appropriate holding times under chain -of -custody protocols. Environment 1 is a North Carolina certified water quality laboratory (Certification 10). The laboratory analyzed each groundwater sample for the constituents listed in 40 CFR Part 258 Appendix II (Appendix II), plus tetrahydrofuran. Additionally, each groundwater sample was analyzed for 1,4-dioxane in accordance with the SWS May 29, 2018 memorandum. Each surface water sample was analyzed for the constituents in 40 CFR Part 258 Appendix I (Appendix 1), plus tetrahydrofuran. Following the completion of baseline monitoring of MNA parameters in July 2019, Wood requested approval from the SWS to modify the MNA parameter monitoring schedule in a letter dated October 30, 2019. The SWS approved the request in a letter dated November 8, 2019. In accordance with the modification, MNA will be assessed on a semi-annual basing using the following parameters: • Temperature • Turbidity • Dissolved Oxygen 0 Conductivity • Oxidation/Reduction Potential 0 Sulfate • Sulfide 0 Nitrate • Alkalinity Other MNA parameters as specified in SWS guidance will be collected on a three-year schedule. Page 2 0 Water Quality Monitoring Report wood. December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 3.0 GROUNDWATER LEVELS AND FLOW Depth to groundwater measurements were collected at 22 wells during the December 2019 monitoring event. Relative to elevations measured in July 2019, elevations measured in December 2019 were higher in some areas of the site and lower in others, typically within 1 to 1.5 feet of the previous measurements. The horizontal direction of groundwater flow was generally to the south and locally away from the landfill phases, which is consistent with historical observations. Groundwater elevation data is summarized in Table 1 and elevation contours are illustrated on Figure 3. Estimated values for hydraulic conductivity and porosity, as well as the horizontal hydraulic gradients and groundwater flow velocities, are presented in Table 1. The horizontal hydraulic gradients near MW-3A, MW-10, MW-11, and MW-12S were calculated based on data from Figure 3 and vary from approximately 0.001 feet per foot (ft/ft) upgradient of MW-12S to 0.007 ft/ft upgradient of MW-3A; Table 1). Comparison of elevation data at MW-2S and MW-2D, and MW-3S and MW-3D indicated the presence of downward vertical gradients of -0.03 ft/ft and 0.01 ft/ft, respectively. Vertical gradients at the site are typically downward. 4.0 GROUNDWATER AND SURFACE WATER ANALYTICAL RESULTS Reported concentrations of groundwater constituents were compared to the 2L Groundwater Standards or IMACs. Concentrations of surface water constituents were compared to the 2B Surface Water Standards or other applicable water quality criteria for Class C surface waters. Reported concentrations that are greater than the laboratory method detection limit (MDL), but less than the laboratory method reporting limit (MRL) are estimated and are indicated with a "J" qualifier. Note that for tabulated data prior to the discontinuation of the Solid Waste Section Limit (SWSL) in 2018, "J" qualified data indicates that a concentration was greater than the MDL, but less than the SWSL. Contaminants are summarized below and discussed in Section 5 in context with historical data and natural attenuation parameters as appropriate. The laboratory reports, with chain -of -custody documentation and the electronic data deliverables (EDDs) are included in Appendix A. Historical analytical results for selected contaminants are summarized in Appendix B. 4.1 Volatile Organic Compounds (VOCs) Volatile organic compounds (VC)Cs) in groundwater samples reported at concentrations that exceeded their GWPSs during the December 2019 monitoring event included benzene, 1,2-dibromoethane, 1,1,2,2-tetrachloroethane, vinyl chloride (VC), and 1,4-dioxane (Table 3 and Figure 4). Reported benzene concentrations exceeded the 1 pg/L 2L Groundwater Standard in the samples from MW-3S (1.81 pg/L), MW-3A (1.49 pg/L), MW-8 (1.13 pg/L), MW-10 (1.28 pg/L), MW-11 (2.56 pg/L), MW-12S (2.12 pg/L), and MW-14S (1.47 pg/L). Estimated J-flagged concentrations of 1,2-dibromoethane reported in the samples from MW-2S (0.07 J pg/L) and MW-3S (0.05 J pg/L) exceeded the 0.02 pg/L 2L Groundwater Standard. The 0.22 pg/L 1,1,2,2-tetrachloroethane concentration reported in the sample from MW-8 exceeded the 0.2 pg/L 2L Groundwater Standard. Reported VC concentrations exceeded the 0.03 pg/L 2L Groundwater Standard in the samples from MW-10 (0.33 pg/L), MW-11 (0.57 pg/L), MW-12S (1.25 pg/L), and MW-14S (2.53 pg/L). Page 3 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. Reported 1,4-dioxane concentrations exceeded the 3 pg/L 2L Groundwater Standard in the samples from MW-1S (4.39 pg/L), MW-2S (129 pg/L), MW-3S (326 pg/L), MW-3A (257 pg/L ), MW-5 (31.7 pg/L), MW-6 (25.3 pg/L ), MW- 7 (8.51 pg/L ), MW-8 (218 pg/L ), MW-10 (10.5 pg/L), MW-11 (25.2 pg/L), and MW-12S (27.4 pg/L), MW-14S (3.71 pg/L), and MW-15 (3.69 pg/L). Other VOCs that were reported in December 2019 at concentrations below their 2L Groundwater Standards included: • Acetone • 1,2-Dichloroethane • 1,2-Dichloropropane • Toluene • Cis-1,2-Dichloroethene • 1,4-Dichlorobenzene • Naphthalene In addition to the VOCs noted above, tetrahydrofuran was reported in the samples from 12 wells at concentrations ranging from 2.47 pg/L (MW-7) to 122 pg/L (MW-1 D). Analysis for this constituent is required because the VOC is a common constituent of groundwater at construction and debris landfills; however, a GWPS has not been established for tetrahydrofuran. In the surface water samples, toluene was reported at concentrations of 1.13 pg/L in the sample from location SW- 1, below the 11 pg/L 2B Standard (Table 4). 1,4-Dioxane was reported in the sample from location SW-1 at concentration of 4.14 pg/L, below the 80 pg/L North Carolina In -Stream Target Value for Surface Water (Fresh and Salt). Tetrahydrofuran was reported in the sample from location SW-1 at concentration of 4.22 pg/L and 0.93 J pg/L in the sample from location SW-2. No other VOCs were reported in the surface water samples collected during the December 2019 monitoring event. 4.2 Semi -Volatile Organic Compounds (SVOCs) and Pesticides Based on the laboratory analytical report, concentrations of semi -volatile organic compounds (SVOCs) did not exceed GWPSs in groundwater samples collected during the December 2019 monitoring event (Table 3). Estimated J-flagged concentrations of acenaphthene were reported in the samples from MW-2S (2.88 J pg/L), MW-2S (5.57 J pg/L), and MW-3A (3.3 J pg/L). No other SVOC concentrations were reported in the groundwater samples collected during the December 2019 monitoring event. Pesticide concentrations were not reported in the groundwater samples collected during the December 2019 monitoring event. 4.3 Metals Based on the laboratory analytical report, metals concentrations in groundwater samples that exceeded GWPSs during the December 2019 monitoring event included arsenic, chromium, cobalt, iron, manganese, selenium, thallium, and vanadium (Table 5). Concentrations that exceeded the GWPSs are summarized below. • Arsenic concentrations reported in the samples from MW-2S (16 pg/L), MW-3S (22 pg/L), MW-3A (20 pg/L), MW-8 (28 pg/L), and MW-12S (29 pg/L) exceeded the 10 pg/L 2L Groundwater Standard. Page 4 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. • Chromium concentrations reported in the samples from MW-3S (25 pg/L), MW-3A (15 pg/L), MW-5 (11 pg/L), MW-6 (12 pg/L), MW-7 (15 pg/L), MW-8 (23 pg/L), MW-10 (21 pg/L) and MW-12S (44 pg/L) exceeded the 10 pg/L 2L Groundwater Standard. • Cobalt concentrations reported in the samples from MW-2S (3.4 pg/L), MW-3S (6 pg/L), MW-3A (7 pg/L), MW-5 (2 pg/L), MW-6 (4 pg/L), MW-7 (4 pg/L), MW-8 (4.1 pg/L), MW-10 (2.6 pg/L), MW-11 (2.4 pg/L), MW-12S (3.3 pg/L), and MW-14S (1.8 pg/L) exceeded the 1 pg/L IMAC. • Iron concentrations reported in the samples from MW-1 S (505 pg/L), MW-1 D (2,541 pg/L), MW-2S (14,540 pg/L), MW-3S (11,990 pg/L), MW-3A (22,520 pg/L), MW-4 (866 pg/L), MW-5 (11,560 pg/L), MW-6 (16,360 pg/L), MW-7 (1,731 pg/L), MW-8 (23,240 pg/L), MW-9A (3,528 pg/L), MW-11 (327 pg/L), MW-12S (24,410 pg/L), MW-13 (577 pg/L), MW-14S (14,240 pg/L), MW-15 (21,100 pg/L ), MW-16 (51,400 pg/L), and MW- 17 (1,700 pg/L) exceeded the 300 pg/L 2L Groundwater Standard. • Manganese concentrations reported in the samples from MW-1 D (159 pg/L), MW-2S (613 pg/L), MW-3S (1,145 pg/L), MW-3A (695 pg/L), MW-4 (84 pg/L), MW-5 (251 pg/L), MW-6 (449 pg/L), MW-8 (713 pg/L), MW-9A (250 pg/L), MW-10 (150 pg/L) MW-11 (418 pg/L), MW-12S (570 pg/L), MW-14S (1,664 pg/L), MW- 15 (187 pg/L ), MW-16 (340 pg/L), and MW-17 (116 pg/L) exceeded the 50 pg/L 2L Groundwater Standard. • The selenium concentration reported in the sample from MW-3S (27 pg/L), exceeded the 20 pg/L 2L Groundwater Standard. • The thallium concentration reported in the sample from MW-14S (0.31 J pg/L), exceeded the 0.2 pg/L IMAC. • Vanadium concentrations reported in the samples from MW-1 S (5 pg/L), MW-1 D (0.7 J pg/L), MW-2D (0.39 J pg/L), MW-2S (4 pg/L), MW-3S (5 pg/L), MW-3A (4 pg/L), MW-4 (3 pg/L), MW-5 (5 pg/L), MW-6 (7 pg/L), MW-7 (0.86 J pg/L), MW-8 (5 pg/L), MW-9A (1 pg/L), MW-10 (11 pg/L), MW-11 (3 pg/L), MW-12S (40 pg/L), MW-13 (1 pg/L), MW-14S (4 pg/L), MW-14D (0.5 J pg/L), MW-15 (15 pg/L ), MW-16 (11.2 pg/L), and MW-17 (3.3 pg/L) exceeded the 0.3 pg/L IMAC. In the surface water samples, the reported concentrations of arsenic (30 pg/L), cobalt (8.9 pg/L), copper (41 pg/L), lead (46 pg/L), selenium (5.4 J pg/L) and zinc (202 pg/L) in the sample from location SW-1 exceeded the SWPSs of 13 pg/L, 4 pg/L, 7 pg/L, 25 pg/L, 5 pg/L, and 50 pg/L, respectively (Table 4). The surface water sample collected from SW-1 was relatively turbid (335 nephelometric turbidity units [NTUs]; Table 2), which may have caused the higher metals detections. No other reported metals concentrations exceeded the SWPSs in during the December 2019 monitoring event. 4.4 Inorganics and other Constituents Inorganics and other groundwater constituents reported by the laboratory at concentrations that exceeded GWPSs during the December 2019 monitoring event included Nitrate and sulfate. Concentrations that exceeded the GWPSs are summarized below. The nitrate concentration reported in the sample from MW-7S (43,300 pg/L) exceeded the 10,000 pg/L 2L Groundwater Standard. Page 5 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. • The sulfate concentration reported in the sample from MW-17 (268,000 pg/L) exceeded the 250,000 pg/L 2L Groundwater Standard. Inorganics concentrations in groundwater samples are summarized in Table 5. 5.0 DISCUSSION OF CONTAMINANTS OF CONCERN Contaminants of concern identified in the 2017 ACM Report are discussed in the following sections with historical context and in relation to natural attenuation parameters in the following sections. Mann -Kendall statistical analysis was used to assess trends in selected VOC concentrations over time since November 2015. The Mann -Kendall analysis documentation, which includes time versus concentration graphs, is provided in Appendix C. 5.1.1 Volatile Organic Compounds Benzene has historically been reported in samples from wells MW-3A, MW-3S, MW-8, and MW-12S at concentrations that exceed the 2L Groundwater Standard. Benzene has also been reported in samples from MW- 10 since May 2016, MW-11 since December 2017. Benzene was first reported in a sample from MW-14S during the current sampling event. Mann -Kendall trend analysis of concentrations in samples from MW-3A, MW-3S, MW- 8, and MW-12S since November 2015 indicate that concentrations are increasing at MW-12S, stable at MW-3S, and that trends cannot be identified at MW-3A and MW-8 (i.e., similar to stable). Trends are also not evident at MW-10 and MW-11 since benzene was first detected the wells; however, more data is necessary to determine if these more recent detections represent a long-term increasing trend. The Mann -Kendall analysis documentation is provided in Appendix C. Field measurements reported during the December 2019 monitoring event suggest that groundwater conditions at wells where benzene is reported are mostly anaerobic and not conducive to aerobic biodegradation of benzene; however the absence of increasing concentration trends (with the exception of MW-12S) suggests that benzene is naturally attenuating at these locations at a rate roughly equivalent to the "input" of mass to the aquifer system. Vinyl chloride (VC) concentrations that exceed the 2L Groundwater Standard have been consistently reported in samples from MW-10 since 2016 and MW-12S since 2012. Mann -Kendall trend analysis indicates that VC concentrations since November 2015 are stable at MW-12S and a trend cannot be identified at MW-10. Since June 2019, VC concentrations exceeding the 2L Groundwater Standard have been reported in samples from MW-11 and MW-14. Sporadic exceedances have also been reported in samples from MW-3A, MW-3S, MW-6, MW-7, and MW- 8. The Mann -Kendall analysis documentation is provided in Appendix C. VC in groundwater is often the result of the reduction of larger chlorinated ethenes, such as trichloroethylene (TCE) and cis-1,2-dichloroethylene (cis-1,2-DCE). Based on the historical presence of these compounds at the Site and considering the reducing groundwater conditions observed, this reduction may be the source of VC at the Site and may be evidence of natural attenuation processes. The current absence of larger chlorinated ethenes in groundwater samples suggests that additional VC source mass may not be present, and that the VC is attenuating naturally. 1,4-Dioxane concentrations exceeded the 2L Groundwater Standard in shallow samples from across the Site with the exceptions MW-13 and the wells on the northern side of Phase 2. The highest concentrations were reported in samples from MW-3S (326 pg/L), MW-3A (257 pg/L) and MW-8 (218 pg/L) within the AOC. 1,4-dioxane was commonly used as stabilizer for other VOCs, but the compound can be found in a variety of household products Page 6 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. and materials. The December 2019 sampling event was third event in which samples were analyzed for 1,4-dioxane and a minimum of four samples is necessary to estimate a trend using Mann -Kendall. 1,4-Dioxane was reported in a surface water sample (SW-1) for the first time during the December 2019 sampling event, at a concertation below the 80 pg/L North Carolina In -Stream Target Value for Surface Water (Fresh and Salt). 5.1.2 Appendix I and It Metals Each of the metals discussed below occur naturally at the Site and are present in background samples. Changes in the concentrations of these metals likely reflect changing groundwater conditions beneath the landfill and may result from the reducing conditions indicated by field measurements and other natural attenuation parameters. Arsenic has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-2S, MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, and MW-12S. Currently, samples from MW-2S, MW-3S, MW-3A, MW-8, and MW-12S were reported to contain arsenic concentrations above the 2L Groundwater Standard. Barium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Concentrations exceeding the 2L Groundwater Standard have been reported in MW-3S, MW-6, MW-7, and MW-12S. Currently, concentrations above the 2L Groundwater Standard were not reported in samples from any well. Chromium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Historically, elevated chromium concentrations reported in samples from several wells decreased over time to below the 2L Groundwater Standard. More recently, chromium concentrations reported in samples from MW-3S, MW-3A, MW-5, MW-7, MW-8, MW-10, and MW-12S have exceeded the 2L Groundwater Standard. Currently, samples from MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-10, and MW-12S were reported to contain chromium concentrations above the 2L Groundwater Standard. Cobalt has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Reported cobalt concentrations typically exceed the IMAC in samples from MW-2S, MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-12S, and MW-14S. Currently, samples from MW- 2S, MW-3S, MW-3A, MW-5, MW-6, MW-7, MW-8, MW-10, MW-11, MW-12S and MW-14 were reported to contain cobalt concentrations above the 2L Groundwater Standard. Selenium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. The selenium concentration reported in the sample from MW- 3S in December 2019 was the first reported selenium concentration to exceed the 2L Groundwater Standard. Thallium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Reported concentrations have been detected as "J" values indicating estimated values and appear to fluctuate over time and occasionally exceed the low 0.2 pg/L IMAC; however, detections are less frequent in the deep wells. Page 7 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6480-19-9035 wood. Vanadium has been reported in samples from each Site monitoring well and surface water sampling location, including those monitoring background conditions. Reported concentrations fluctuate over time and generally exceed the low 0.3 pg/L IMAC; however, exceedances are less frequent in the deep wells. Higher concentrations are reported in samples from MW-12S more consistently than in samples from other wells. 6.0 CONCLUSIONS The VOCs benzene and VC are consistently reported at concentrations exceeding their 2L Groundwater Standards in samples from shallow site monitoring wells, particularly within and around the AOC; however, these concentrations have generally been stable over recent years and appear to be attenuating naturally. Benzene concentrations at MW-12S are statistically increasing but remain within an order of magnitude of the 2L Groundwater Standard. Benzene has been detected relatively recently at MW-10 and MW-11; however, the concentrations have not demonstrated increasing trends since first detected. Groundwater samples have been analyzed for 1,4-dioxane using EPA Method 8260 SIM since December 2018 and reported concentrations have exceeded the 2L Groundwater Standard in wells along the southern sided of Phase 2 and across Phase 1. VOC concentration trends in groundwater will continue to be monitored. Reported VOC concentrations did not exceed SWPSs in surface water samples. Various SVOC concentrations are reported sporadically in samples from shallow monitoring wells, but the concentrations do not typically exceed GWPSs. SVOC concentrations in groundwater did not exceed the GWPS in December 2019. SVOC concentration trends will continue to be monitored. Concentrations of pesticides are reported sporadically in samples from shallow monitoring wells, but the concentrations do not typically exceed GWPSs. Pesticides were not reported in groundwater samples in December 2019. The trends for pesticides will continue to be evaluated. Several metals are reported in samples from shallow monitoring wells at concentrations that exceed their 2L Groundwater Standards. These metals can occur naturally at the Site, and the elevated concentrations are likely related to the moderately reducing groundwater conditions indicated by the natural attenuation monitoring. Trends in groundwater conditions at the Site, and their effect on metals concentrations will continue to be evaluated. Groundwater and surface water monitoring will continue on a semi-annual schedule in accordance with the Assessment and Corrective Action Program. Page 8 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 TABLES wood. Table 1 Groundwater Level and Flow Data - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Well ID MW-1S (Well #1) TOC (feet MSQ 20.91 DepthElevation Well (feet BGS) 13 Screjene (feet BGS) 3 -13 Depth (feet TOC) 8.18 (feet MSQ 12.73 MW-25 (Well #2) 21.44 13 3 -13 11.35 10.09 MW-35 (Well #3) 23.02 18 8-18 12.74 10.28 MW-3A 21.93 20 5-20 11.65 10.28 MW-4 18.42 13 3 -13 9.78 8.64 MW-5 17.90 18 3 - 18 6.70 11.20 MW-6 20.03 13 3 -13 9.73 10.30 MW-7 19.40 13 3 -13 8.51 10.89 MW-8 21.21 18 3 - 18 9.85 11.36 MW-9A 20.58 20 5-20 5.96 14.62 MW-10 16.61 20 5-20 3.82 12.79 MW-11 14.49 20 5-20 3.62 10.87 MW-12S 16.18 20 5-20 5.26 10.92 MW-13 20.69 20 5-20 9.75 10.94 MW-14S 16.60 20 15 - 20 5.51 11.09 MW-15 19.67 20 15 - 20 6.33 13.34 MW-16 NA 20 NA 5.90 NA MW-17 20.74 20 15 - 20 7.15 13.59 MW-14D 17.45 40 35 - 40 6.10 11.35 MW-1 D 21.14 50 40 - 50 8.86 12.28 MW-21D 21.80 49 39 - 49 12.67 9.13 MW-31D 22.83 50 40 - 50 12.90 9.93 Water Level Reference Vertical Horizontal Elevation Elevation Change Change K Well ID (feet MSQ (feet MSQ (feet) (feet) (feet/day) (feet/foot) I v (feet/day) MW-3A 10.28 11 0.72 101 0.805 0.08 0.007 0.0717 MW-10 12.79 13 0.21 53 0.116 0.05 0.004 0.0092 MW-11 10.87 11 0.13 85 0.009 0.04 0.002 0.0003 MW-12S 10.92 11 0.08 60 0.322 0.06 0.001 0.0072 Notes: Depth To Water was measured between December 11 and 16, 2019. TOC = top of casing. BGS = below ground surface MSL = mean sea level K - hydraulic conductivity. Values obtained from slug testing performed by EFM, Inc. n - effective porosity. Values approximated based on grain size data from Phase II Design Hydrogeologic Report. I - hydraulic gradient. Determined by dividing head change by horizontal distance to nearest contour line at each well location. v - flow rate; GW flow rate calculated based on the modified Darcy equation: v = (K*I)/n. Page 1 of 1 Table 2 Summary of Field Parameters - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Well or Surface Water Location ID -AM Conductivity at Field Parameter Temperature Turbidity (*C) (NTU) NE NE ORP (mV) NE Dissolved ff(PX Ygm GWPS 6.5 - 8.5 NE NE MW-is 6.0 613 13 2.80 141 1,740 MW-2S 6.8 2,790 16 5.98 110 480 MW-3S 6.9 3,477 18 6.87 111 980 MW-3A 6.8 2,679 16 6.66 101 1,790 MW-4 6.6 405 14 2.48 81 400 MW-5 6.7 1,151 10 46.2 129 540 M W-6 6.8 2,670 15 1.93 121 1,770 MW-7 7.0 2,076 15 5.02 126 540 MW-8 6.7 4,238 17 1.99 145 1,900 MW-9A 7.1 653 14 7.24 55 990 MW-10 6.6 2,526 14 7.82 119 2,240 MW-11 6.7 1,743 11 7.55 87 290 MW-12S 6.7 3,956 14 1.74 123 1,060 MW-13 6.4 609 17 6.88 49 400 MW-14S 6.5 2,008 18 8.24 93 810 MW-15 5.8 669 19 4.63 54 780 MW-16 6.1 1,155 17 7.79 97 1,260 MW-17 5.7 555 16 6.60 112 950 MW-14D 7.6 521 20 1.07 66 530 MW-lD 6.5 400 15 7.51 115 330 MW-2D 8.0 423 16 2.64 62 720 MW-3D 7.7 527 17 1.14 121 2,570 SWPS 6-9 NE NE 50 NE NE SW-1 6.9 943 10 335 NS NS SW-2 6.6 184 5 440 NS NS SW-3 6.0 385 7 22.8 NS NS SW-4 6.8 156 10 14.1 NS NS NOTES: Groundwater samples were collected on December 11, 12, and 16, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Surface Water Standard = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters, EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Life, or North Carolina Protective Values for Surface Waters Bold font indicates concentration beyond range of GWPS or SWPS. NE = Not Established. S.U. = Standard Units. NS/cm = microsiemens per centimeter. NTU = Nephelometric Turbidity Units. Page 1 of 1 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte Group Acetone 6,000 9.06 U 11.30 J 9.06 U 11.20 J Phase 1 Monitoring Wells 9.06 U 9.06 U 9.48 J 9.06 U 17.40 J 9.06 U 9.06 U 9.06 U Benzene 1 0.24 U 0.44 J 1.81 1.49 0.24 U 0.24 U 0.24 U 0.24 U 1.13 0.24 U 0.24 U 0.24 U 1,2-Dichloroethane 0.4 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 0.02 U 1,2-Dibromoethane 0.02 0.03 U 0.07 J 0.05 J 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Cis-1,2-Dichloroethene 70 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dichloropropane 0.6 0.04 U 0.04 U 0.04 J 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U VOCs (Ng/L) Naphthalene 6 0.47 U 4.14 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Toluene 600 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.24 J 0.23 U 0.23 U 1,1,2,2-Tetrachloroethane 0.2 0.03 U 0.12 J 0.13 J 0.19 J 0.03 U 0.03 U 0.03 U 0.03 U 0.22 0.03 U 0.03 U 0.03 U 1,4-Dichlorobenzene 6 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Vinyl chloride 0.03 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U 0.12U Tetrahydrofuran NE 0.39 U 27.90 23.10 20.50 0.39 U 2.48 14.70 2.47 32.90 122.00 0.39 U 0.39 U 1,4-Dioxane 3 4.39 129.00 326.00 257.00 2.71 U 31.70 25.30 8.51 218.00 1 2.71 U 2.71 U 2.71 U SVOCs (Ng/L) lAcenaphthene 80 1 2.66 U 1 2.88 J 1 5.57 J 1 3.30 J 1 2.66 U 1 1 2.66 U 1 2.66 U 2.66 U 1 2.66 U 2.66 U 2.66 U Page 1 of 3 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Analyte Group VOCs (Ng/L) Parameter Acetone IL owl GWPS 6,000 it ., 9.06 U 9.06 U 12.30 J Phase 2 Monitoring 12.70 J 9.06 U Wells 9.06 U 9.06 U W 9.06 U 9.06 U ,, 9.06 U Benzene 1 0.24 U 1.28 2.56 2.12 0.24 U 1.47 0.24 U 0.24 U 0.24 U 0.24 U 1,2-Dichloroethane 0.4 0.02 U 0.21 0.27 0.15 J 0.02 U 0.111 0.02 U 0.02 U 0.02 U 0.02 U 1,2-Dibromoethane 0.02 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Cis-1,2-Dichloroethene 70 0.25 U 0.25 U 0.52 J 0.34 J 0.25 U 0.46 J 0.25 U 0.25 U 0.25 U 0.25 U 1,2-Dichloropropane 0.6 0.04 U 0.08 J 0.15 J 0.08 J 0.04 U 0.05 J 0.04 U 0.04 U 0.04 U 0.04 U Naphthalene 6 0.47 U 0.60 J 0.47 U 1.56 J 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U 0.47 U Toluene 600 0.23 U 0.37 J 0.26 J 0.50 J 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 0.23 U 1,1,2,2-Tetrachloroethane 0.2 0.03 U 0.03 U 0.04 J 0.07 J 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 1,4-Dichlorobenzene 6 0.39 U 0.39 U 0.39 U 0.50 J 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U 0.39 U Vinyl chloride 0.03 0.12 U 0.33 0.57 1.25 0.12 U 2.53 0.12 U 0.12 U 0.12 U 0.12 U Tetrahydrofuran NE 0.39 U 31.20 43.80 40.10 0.39 U 10.50 0.39 U 0.39 U 0.39 U 0.39 U 1,4-Dioxane 3 2.71 U 10.50 25.20 27.40 2.71 U 3.71 3.69 2.71 U 2.71 U 2.71 U SVOCs (Ng/L) jAcenaphthene 80 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 2.66 U 3.24 J 2.66 U Page 2 of 3 Table 3 Summary of Groundwater Analytical Data VOCs, SVOCs, and other Contaminants - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina NOTES: Table 3 lists analytes detected in the groundwater samples. Please refer to Environment 1, Incorporated laboratory analysis report for further details. Groundwater samples were collected on December 11, 12, and 16, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. ND = Not Detected. NE = Not Established. Bold font indicates concentration exceeds 2L Standard or IMAC. * indicates associated GWPS is an IMAC Page 3 of 3 Table 4 Summary of Surface Water Analytical Data - December 2019 Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina Metals (pg/L) Antimony 640 0.40 J 0.05 J 0.09 J 0.04 J Arsenic 10 30 0.08 U 2.3 J 0.08 U Barium 21,000 1,725 48.4 155 60.0 Beryllium 6.5 1 0.02 U 0.28 J 0.06 J Cadmium 2 2 0.04 U 0.12 J 0.04 U Cobalt 4 8.9 0.26 J 2.0 0.44 J Chromium 50 18 0.12 U 0.12 U 0.12 U Copper 7 41 6.1 J 8.4 J 4.8 J Lead 25 46 0.30 J 7.2 0.64 J Nickel 88 13.7 1.2 J 2.9 J 1.0 J Selenium 5 5.4 J 0.54 J 0.99 J 0.26 J Silver 0.06 0.22 U 0.22 U 0.22 U 0.22 U Thallium 0.47 0.46 J 0.02 U 0.111 0.02 J Vanadium NE 84 0.9 J 11 2 Zinc 50 202 4.2 J 31 3.0 J VOCs (pg/L) 1,4-Dioxane 80 4.14 2.71 U 2.71 U 2.71 U Toluene 11 1.13 0.23 U 0.23 U 0.23 U Tetrahydrofuran 110,000 4.22 0.93 J 0.39 U 0.39 U NOTES: Table 4 lists detected compounds in the surface water. Please refer to Environment 1, Incorporated laboratory report for further details. Surface samples were collected on December 12, 2019. Surface Water Standard = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters, EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Life, or North Carolina in Stream Target Values for Surface Water J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U = indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. NE = Not Established. Bold font indicates analyte detection above the Surface Water Standard. Page 1 of 1 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina December 2019 Analyte Group Parameter Antimony* GWPS 1 MW-is (Well #1) 0.03 U MW-2S (Well #2) 0.03 U MW-3S (Well #3) 0.03 U MW-3A 0.03 U MW-4 0.03 U Phase 1 Monitoring MW-5 0.03 U Wells MW-6 0.03 U MW-7 0.03 U MW-8 0.03 U MW-1D 0.03 U MW-2D 0.03 U JMW-3D 0.03 U Arsenic 10 0.08 U 16 22 20 0.08 U 3.2 J 10 2.8 J 28 0.08 U 0.08 U 0.08 U Barium 700 43 331 650 299 72 119 535 234 475 25 13 8 J Beryllium* 4 0.42 J 0.32 U 0.32 U 0.32 U 0.36 J 0.02 U 0.02 U 0.02 U 0.02 U 0.38 J 0.32 U 0.32 U Cadmium 2 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U 0.04U Chromium 10 3 J 5.7 25 15 3 J 11 12 15 23 1.3 J 4 J 1.05 U Cobalt* 1 0.32 U 3.4 6 7 0.82 J 2 4 4 4.1 0.76 J 1 1 Copper 1,000 1.47 U 7.8 J 4 J 2 J 1.47 U 2 J 1.47 U 7 J 5 J 1.47 U 1.47 U 1.47 U Iron 300 505 14,540 11,990 22,520 866 11,560 16,360 1,731 23,240 2,541 203 134 Metals (pg/L) Lead 15 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U 0.03 U Manganese 50 22 613 1,145 695 84 251 449 36 713 159 7 J 3 J Mercury 1 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 J 0.05 J 0.05 J 0.05 U 0.06 J 0.06 J 0.05 U Nickel 100 7.9J 0.32U 5J 51 3J 10 7J 8J 13.4 5J 5J 2J Selenium 20 0.05 U 14 27 19 2.2 J 5.8 J 10 9.2 J 17 0.05 U 0.05 U 0.05 U Silver 20 0.51 U 0.51 U 0.51 U 0.51 U 11 11 0.6 J 0.22 U 0.22 U 0.52 J 1.3 J 11 Thallium 0.2 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U 0.02U Tin 2,000 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Vanadium 0.3 5 4 5 4 3 5 7 0.86 J 5 0.7 J 0.39 J 0.2 U Zinc 1,000 13 3.5J 31 3J 11 11 4J 51 5J 7J 8J 5J Nitrate (as N) 10,000 100 210 2,660 9 U 9 U 90 1,000 44,300 50 60 290 260 Inorganics Sulfide NE 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 100 U 422 J 100 U 100 U (pg/L) ISulfate 1 250,000 1 143,000 1 183,000 1 125,000 1 86,300 1 5,200 1 105,000 1 5,200 1 50,600 1 123,000 1 5,000 U 1 18,500 1 5,000 Alkalinity (CaCO3) NE 154,000 1 1,070,000 1 1,430,000 1 840,000 1 403,000 1 376,000 1 1,230,000 1 860,000 1 1,680,000 1 163,000 1 175,000 1 228,000 Page 1 of 3 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina December 2019 Antimony* 1 0.05J 0.18J 0.36J 0.31J Phase 2 Monitoring 0.111 Wells 0.18J 0.06J 0.18J 0.06J 0.22J Arsenic 10 0.08 U 5.5 4.6 J 29 0.08 U 0.58 J 0.10 J 3.9 J 0.08 U 0.08 U Barium 700 62 267 131 589 77 332 255 394 49.2 9 J Beryllium* 4 0.02 U 0.02 J 0.04 J 0.02 U 0.02 U 0.02 J 0.12 J 0.05 J 0.04 J 0.02 U Cadmium 2 0.04 U 0.05 J 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.04 U 0.06 J Chromium 10 0.12U 21 0.12U 44 0.12U 1.11 0.12U 5 1.2J 0.12U Cobalt* 1 0.51J 2.6 2.4 3.3 0.49J 1.8 0.71J 0.9J 0.8J 0.14J Copper 1,000 2 J 5 J 2 J 3 J 1.47 U 2 J 1.47 U 2.0 J 5.0 J 2 J Iron 300 3,528 327 24,410 1,710 577 14,240 21,100 51,400 1,700 221 Metals (Ng/L) Lead 15 0.06 J 0.05 J 0.05 J 0.03 U 0.16 J 0.22 J 0.32 J 0.08 J 0.12 J 0.06 J Manganese 50 250 150 418 570 25 1,664 187 340 116 3 J Mercury 1 0.05 U 0.05 J 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U 0.05 U Nickel 100 5.2J 18.0 14.6 14.7 8.2J 14.2 3.0J 2.8J 2.6J 2.5J Selenium 20 0.62J 7.4J 3.5J 16 1.4J 2.7J 4.1J 3.4J 0.65J 0.31J Silver 20 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U 0.22 U Thallium 0.2 0.06 J 0.05 J 0.02 J 0.02 U 0.04 J 0.31 J 0.10 J 0.09 J 0.06 J 0.02 J Tin 2,000 0.16 J 0.05 U 0.19 J 0.60 J v.UD 0.16 J 0.10 J 0.05 U 0.05 U 0.20 J Vanadium 0.3 1 11 3 40 1 4 15 11.2 3.3 0.5 J Zinc 1,000 8J 6J 1.4J 8J 7J 3J 13 2.4J 1.8J 91 Nitrate (as N) 10,000 9 U 9 1, 9 U 9 U 1,110 9 U 9 U 9 U 9 U 250 Inorganics Sulfide NE 100 U 849 J 100 U 100 U 592 J 100 U 100 U 100 U 226 J 100 U (pg/L) Sulfate 250,000 107,000 45,200 197,000 5,400 124,000 135,000 133,000 59,300 268,000 5,000 U Alkalinity (CaCO3) NE 198,000 1,090,000 828,000 1,580,000 190,000 1,140,000 130,000 240,000 51,000 205,000 Page 2 of 3 Table 5 Summary of Groundwater Analytical Data Metals, Inorganics, and other Constituents Construction and Demolition Debris (C&D) Landfill (Permit #74-07), Pitt County, North Carolina December 2019 NOTES: Table 5 lists analytes detected in the groundwater samples. Please refer to Environment 1, Incorporated laboratory analysis report for further details. Groundwater samples were collected on December 11, 12, and 16, 2019. GWPS = Groundwater Protection Standard: NCAC Title 15A Subchapter 2L Groundwater Standards or Interim Maximum Allowable Concentration (IMAC) J indicates the reported result is estimated between the laboratry method detection limit and reporting limit. U indicates analyte not detected at indicated method detection limit. pg/L = micrograms per liter. ND = Not Detected. NE = Not Established. Bold font indicates concentration exceeds 2L Standard or IMAC. * indicates associates GWPS is an IMAC Page 3 of 3 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 FIGURES wood. _ ` r Fr � — �- � ■ u air.• l — ! a _ • s # { ' a #a !S'�8 _ F •Pa�taiuS I r ' -'� � fiam,� , r - �* f � f ,4.`��,t F fig a 4 z f hw y26 IL;Car+ k 1i c r 1 e * t _ .1J +•1{��} " w:ate- �1 1YYY� 14L'-14 _ _ Phase 2 N-1 _ Phase.1 -} a a,, ITIP f i h i _—— — — _ _' — - - - }� .*#ems_ I �.• — - .� ir + ♦ C'8 �� - fdF 0 2,000 - 4,000 Legend .* _ - �I : Feet Site r Copyright:.© 2013 National Geographic Society, i-cubed SITE: TITLE: Figure C8YD Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 SITE LOCATION MAP CLIENT: W 0 0 w C8YD LANDFILL INC. SCALE: 1 "=2,00 bATE: 05/01/2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: S. Knox Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142—P R\Figures C DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures MW-14S MW-14D' MW-13 ' Phase 2 _ A �6e' rip r d'r" *., MW-12S r •� mw-u I 1 FP � MW-2S - MW-6 M Legend SW ®Surface Water Sampling Location • Shallow Monitoring Well Deep Monitoring Well y Approximate Stream Location , r ' ` Feet Site Boundary Source Esri, Digi I'�I oEye, Earthstar Geographics, CNES/Airbus AeroGRID, IGN, nd the GISa��ser Community SITE: Figure TITLE: FI C&D Landfill 9 802 RECYCLING LANE GREENVILLE, NC 27834 MONITORING WELL AND SURFACE WATER SAMPLING LOCATION MAP CLIENT: ^ wood* C8JD LANDFILL INC. SCALE: 1 " = 200 ' DATE: 05/01 /2019 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: D. Hriciga CHECKED BY: S. Knox Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142P t RTig\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figures SITE: Figure TITLE: FI C&D Landfill J 802 RECYCLING LANE GROUNDWATER ELEVATION MAP GREENVILLE, NC 27834 - DECEMBER 2019 CLIENT: ^ wood* C&D LANDFILL INC. SCALE: SCALE: 1 " = 200 ' DATE: 03/23/2020 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: LAW CHECKED BY: D. Hriciga Durham, NC 27703 (919) 381-9900 LOCATION: P.\Government\State\NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\ Figure s Metals concentrations in excess of standards are not illustrated. Units are micrograms per liter (mg/L). NE = No exceedances of applicable groundwater or surface water standards were reported. NS = Not Sampled J = Estimated value below the laboratory reporting limit ■ i NE 014 MW-16 f' 1 rs� � -b7 MW-9A ... NE MW-15 .1 1,4-Dioxane 3.69 i MW-14D NE MW-13;' i N E rl- MW-14S Benzene 1.47 Vinyl Chloride 2.53 1,4-Dioxane 3.71 Benzene 1.28 Vinyl Chloride 0.33 1,4-Dioxane 10.5 ,' , / Phase 2 MW-12S MW-11 Benzene 2.12 Benzene 2.56; Vinyl Chloride 1.25 Vinyl Chloride 0.57 1,4-Dioxane 27.4 1,4-Dioxane 25.2 4A+' ` '.. SWW;' r ' , wo MW-3S MW-3D 1 Benzene 1.81 1,2-Dibromoethane 0.05 J NE 1,4-Dioxane 326 ,i MW-3A Benzene 1.49 6 r 1,4-Dioxane 257 F te Legend ® Surface Water Sampling Location • Shallow Monitoring Well Deep Monitoring Well ----- Approximate Stream Location Site Boundary Benzene 1.13 1,1,2,2-TCA 0.22 «- 1,4-Dioxane 218 Phase 1 NE MW-6 1,4-Dioxane 25.3 4 MW-2S 1,2-Dibromoethane 0.07 J 1,4-Dioxane 129 f � ' &W-1 D NE is MW-1S 1,4-Dioxane 4.39 Ell MW-4 LINE SW-1 NE 200 400 Feet us DS, IHSDA, USGS, SITE: Figure TITLE: FI C&D Landfill J 802 RECYCLING LANE GREENVILLE, NC 27834 GROUNDWATER AND SURFACE WATER STANDARD EXCEEDANCE MAP - DECEMBER 2019 CLIENT: wood* C&D LANDFILL INC. 4 SCALE: 1 " = 200 ' DATE: 03/23/2020 PROJECT: 6480199035 Wood Environment & Infrastructure Solutions, Inc. 4021 Stirrup Creek Drive, Suite 100 DRAWN BY: LAW CHECKED BY: D. Hriciga Durham, NC 27703 (919) 381-9900 LOCATION: 56548 142—PA \Fig NC\NC DENR DSCA\DSCA Projects\DC640004 - CleanCleanDrycleaners\ 565480142_PAR\Figure s SW-2 NE 0 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Appendix A Laboratory Analytical Reports wood. Environment 1, Incorporated GREENVILLE, N.C. 27858 JUDSON WHITEHVRST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PAAAMBTHR9 NDL PA (field m u e ent), Unite Nitrate Nitrogen as N, mg/1 0.009 Alkalinity (to pH 4.5), mg CaCO3/1 1.0 Cyanide, ug/l 5.0 Sulfate, mg/1 5.0 Antimony, ug/1 0,03 Antimony, ug/1 0,03 Arsenic, ug/1 0108 Arsenic, ug/1 0.08 Barium, ug/l 0.32 Barium, ug/1 0,32 Beryllium, ug/1 0.02 Beryllicm, LLB/1 0,02 Cadmium, ug/1 0,04 Cadmium, ug/1 0,04 Cobalt, ug/l 0,02 Cobalt, ug/l 0.02 Total Chromium, ug/1 0,12 Total Chromium, ug/1 0.12 Copper, ug/l 1.47 Copper, ug/1 1,47 Iron, ug/1 12,08 Iron, ug/1 12.08 Manganese, ug/l 0,31 Manganese, ug/1 0.31 Lead, ug/1 0,03 Lead, ug/1 0.03 Mercury,.ug/l 0005 Nickel, ug/1 0,03 Nickel, ug/1 0003 Selenium, ug/1 0005 Selenium, ug/1 0.05 Silver, ug/1 0,22 Silver, ug/1 0,22 Thallium, ug/1 0.02 Thallium, ug/1 0,02 Tin, ug/1 0905 Tin, ug/1 0.05 Vanadium, ug/1 0.20 Vanadium, ug/1 0.20 zinc, ug/l 1,10 zinc, ug/l 1,10 MW-9 MW-5 MRL as 6water IDI 30 PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 DATE COLLECTED: 12/12/19 DATE REPORTED : 02/21/20 REVIEWED BY: A MN-6 MN-7 MW-k Analysis Method 6.6 6.7 6.8 7.0 Date Analyst Code J = Estimated value between the MUL and MRL, U Below ALL Quantltetion Limits. Environment 1, InR 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 PAAANBTRRB Sulfide, ug/l Conductivity (at 2501 uNhos/cm Dissolved Oxygen, mg/l Temperature, °C Static Water Level, feet Well Depth, feet DRP, m Turbidity (Field), NTU WaeteWater YDr lU PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 DATE COLLECTED: 12/12/19 DATE REPORTED : 02/21/20 REVIEWED BY: sype MW-4 MW-5 MW-6 MW-7 MW- Analysis Method MDL MRL Date Analyst Code 100 1000 --- U --- U --- U --- U --- U 12/16/19 LFJ 4500S2D-11 1.0 1.0 405 1151 2670 2076 4238 12/12/19 PJC 2510B-11 0.1 0.1 0.40 0.54 1,77 0.54 1.9D 12/12/19 PJC 450000-11 14 10 15 15 17 12/12/19 BF 2550E-10 9.79 6.70 9,73 8,51 9.55 12/12/19 BF 15.98 9.50 16,65 16.33 20,26 12/12/19 BF +81 +129 +121 +126 +145 12/12/19 BF 2500B-11 1,0 1.0 2,48 46.2 1,93 5,02 1.99 12/12/19 BF 2130E-11 J = Estimated value between the MDL and Mitt, U = BelON ALL Quantitation Llmite. Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 wastewater PHONE (252) 756-6208 PAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: PESTICIDES AND PCB'S L+T7:l17, Nf30.7A RU (t171 PARAMETERS, ug/1 Date Analyzed MDL MHL 01/03/20 Mw-4 01/04/20 Mw-5 01/04/20 MW-6 01/04/20 MW-7 Ol/09/20 MW-8 1, 2. 3, 4. 5. 6, 7. 8. 9, 10, 11. 12, 13, 14, 15. 16. 17, IS, 19. 20. Aldrin Alpha-HHC Beta-BHC Delta-HRC Gamma-BHC (Lindane) Chlordane 914-DDD 4,4-DDE 4r4-DDT Dieldrin Endosulfan I Endosulfan II Endosulfan Sulfate Hndrin Endrin Aldehyde Heptachlor Heptachlor Hpoxide Methoxychlor Pcb'a (Aroolore) Toxaphene 0,029 0,032 0,031 0,030 0,032 0.320 0.051 0.049 0,052 0,042 0.056 0.046 0,072 0,053 0.068 0,039 0.042 0.530 0.500 0.690 0.050 0.050 0.050 0.050 0.050 0,500 0.300 0,100 0,100 0,075 0,100 0.300 0.100 0.100 0,100 0,050 0,075 1.000 2.000 1,500 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- U U u U U U U u U U U U U U U U U U U U --- --- "- •-- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --• •-- U U U u V U U U U U U U U U U U U U V V --- --- '"" --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- U V U U V U U U U U U U U U U U V U V U --- --- - --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- U U u U U U U V U U V U U U U U U U U U --- --- - --- --- --- --- --- --- --- --- --- - --- --- --- --- --- --- •-- U U ❑ U U U U U U U U U U U U U U U U U NOTE: EPAnIdETHODp8081E R2 (07): Final Continuing CRIi6ration verification exceeded control limit for Heptachlor. This analyte was not detected in sJ npleHsetlmat�ed vaU ueee�etwean the MDL and MRL, U e Below ALL UuantltatSon LimiEe. Environment 1, Incorporated I OAKMON I DRIVE GREENVILLE, N.C. 27858 Weetewater Tali IV PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: BIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/17/19 DATE ANALYZED: 01/01/20 REVIEWED BY: 4eDATE REPORTED: 02/21/20 LANDFILL APPENDIX II RVA MRTAOD 8151A R1(96) MW-4 MW-5 MW-6 MW-7 MW-E PARAMETERS. Ug/l MDL MRL 1, 2.4-D 0.36 2.000 --- u --- 0 --- u •-- u --- u 2. DSnaeeb 0.54 1.000 --- U --- U --- D -- u "- u 3. 2,9j5-TP 0,42 2,000 --- U --- u --- U --- u --- U 4, 2t9, 5-T 0.49 2.000 --- U --- V M. II -- u U J = Eetlmated value between the MDL and MRL, U = HelON ALL Vuantitation Limits. Environment 1, Incorporated GREENVILLE, NI 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 ANALYST: JAP DATE COLLECTED: 12/12/19 DATE EXTRACTED: 12/16/19 DATE ANALYZED: 01/23/20 DATE REPORTED: 02/21/20 SEMI -VOLATILE ORGANICS 7Vh MRTRnn R97()R R6 (181 Page: 1 PARAMETERS, ug/1 MDL MRL MW-4 MW-5 MW-6 MW-7 MW-8 1. Acenaphthene 2,66 10,000 --- U --- U --- U --- U •-- U 2. Acenaphthylens 2.60 10,000 --- U --- U --- U --- U --- U 3, Anthracene 2,97 10,000 --- U --- U --- U --- V --- U 4, Benzo[alantrhacene 4.16 10.000 --- U --- U --- U --- U --- U 5, Benzo[blfluoranthene 3,32 10,000 --- U --- U --- V --- U --- U 6, Benzo[klflucranthens 4.23 10,000 --- U --- U --- u --- U --- U 7, Benao[g,h,i)perylene 2,61 30,0o0 --- U --- U --- V --- U --- U 8, Benzo[alpyrens 3.27 10.000 --- U --- U --- U --- U --- U 9, 4-BromOPhenyl Phenyl Ether 2,63 10,000 --- U --- U --- U -•- U --- U 10, Butyl Benzyl Phthalate 5478 10.000 --- U --- U --- V --- V --- U 11, Bis(2-Chloroethoxy) Methane 3,14 10,000 --- U --- U --- U --- U --- U 12. Bis(2-Chloroethyl) Ether 2,59 10,000 --- U --- U --- U --- U --- U 13, Bis(2-Chloro-l-methylethyl) Ether 2458 10,000 --- U --- U --- U --- U --- U 14. 2-Chloronaphthalens 2,17 10.4000 --- U --- U --- u --- U --- U 15, 4-Chlorophenyl Phenyl Ether 2442 10,000 --- U --- V --- U --- V --- U 16. Chry eene 4.09 10.000 --- U --- U --- U --- U --- U 17, USbenzo(a,hlanthracens 2,78 10,000 --- U --- U --- U --- U •-- U 18, Di-N-Butyl Phthalate 3009 104000 --- U --- U --- U --- U --- ll 19. Dimethyl Phthalate 3.78 10,000 --- U --- U --- U --- U --- U 20, Diethyl Phthalate 3,92 10,000 --- U --- U --- U --- U --- V 21, 2,4-DinitrotolUene 3.95 100000 --- U --- U --- U --- U --- U 22, 2,6-Dinitrotoluene 3,98 10.D00 --- U --- u --- U --- U --- U 23, Di-N-Octyl Phthalate 2,81 10.000 --- U --- U --- U --- U --- U 24. Bie-(2-Ethylhexyl) Phthalate 9497 15,000 --- U --- V --- U --- U --- U 25, Fluaranthene 3492 10.000 --- U --- ❑ --- U --- U --- V 26, Fluorene 2,95 104000 --- U --- U --- U --- U --- U 27, Hexachlorobenzene 2.61 10,000 --- U --- U --- U --- U --- U 28, Hexachlorocyclopentadiene 4,16 10.000 --- U --- U --- U •-- U --- U 29, Indeno[l,2,3-Cd1pyrena 2,91 10,000 --- U --- U --- U --- U --- U 30. Isophorone 3,74 104000 --- V --- U --- V --- U --- U 2,85 104000 --- U --- U --- U --- U --- U 31, Nitrobenzene 32, N-Nitroeodimethylamine 4,25 10.000 --- U --- U --- U --- U --- U 33, N-Nitrosodiphenylamine 3.95 10,000 --- U --- U --- u --- U --- U 34% N-Nitroeodi-N-Propylamine 4106 10,000 --- U --- U --- U --- V --- U 3,24 10,000 --- u --- U --- U --- U '-- U 35, Phenanthrene 36, Pyrene 3,63 104000 --- U --- U --- U --- U --- U 37. 4-Chloro-3-Methylphanol 3.79 20.000 --- U --- U --- U --- U -'- U 38. 2-Chlorophen0l 2.75 10,000 --- U --- U --- U --- U --- u 39, 0-Cresol 3,68 10,000 --- U --- U --- U --- U --- U 40. P-Cresol 4,12 10,000 --- U --- U --- U --- U --- U 41, 2,4-Dichlorophenol 5.19 10,000 --- U --- u --- U --- U --- U 42. 2,6-Dichlorophenol 4.89 10,000 --- U --- U --- U --- U --• U 43. 2,4-Dlmethylphenol 3,21 10.000 --- U --- U --- U --- U --- U 44. 4,6-Dinitro-2-Methylphenol 4,77 50,000 --- U --- U --- U --- U --- U 45. 2,4-Dlnitrophenol 4,37 501000 --- U --- u --- U --- U --- U 46, Ethyl Methaneeulfonate 5,26 20,000 --- V --- U --- U --- U --- U 47, Nethyl Methaneaulfonate 4.92 10,000 --- U --• U --- U --- V --- U 48. 2-Nitrophanol 3,64 10.000 --- U --- U --- U --- U --- V J = Estimated value between the MDL and MRL, U Below ALL QuantlC atian Llmite. Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 Wastewater ID: 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST %C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE ANALYZED: 01/23/20 REVIEWED BY: - DATE REPORTED: 02/21/20 SEMI -VOLATILE ORGANICS ova mvmunn R77nR R6[lAl Page: 2 PARAMETBRB, ug/l MDL MRL MW-4 NW-5 MW-6 MW-7 NW-8 49, 50, 51. 4-Nitrophenol Pentachlorophenol Phenol 3,17 5,33 1,86 50,000 25,000 10.000 --- --- --- u u V -•- --- --- u U U --- --- --- U u u --- --- --- u u u --- --- --- u u u 52, 53. 54, 55. 56, 57, 58, 59, 60, 61, 62, 63. 69. 65. 66, 67. 68, 69, 70, 71, 72. 73, 74, 2,3,4,6-Tetrachlorophenol 2,4,5-Triahlorophenol 2,4,6-Triahlorophenol Acetophenone 2-Aaetylaminofluorens 4-Aminobiphenyl eenzyl Alcohol 4-Chloroaniline Chlorobenzllate Diallate Dibenzoturan 3,31-Dichlorobenzidine DSmethoata P-Dimethylaminoazobenaene 7,12-Dimethylbenz[a]anthracene 3,3-Dimethylbenzidlne 1,3-Dinitrobenzens Diphenylamine Uleult0ton Famphur Hexachloropropene Tsosafrole Nepone 3A2 4,17 3.84 2,89 3.98 4,12 4,47 3,36 5.12 2,90 4,28 4,22 3.98 2,89 5,26 3,21 2,89 5.10 4.28 3,98 4,31 2,88 2.78. 10,000 10.000 10.000 10.000 20,000 20400 20,000 20.000 10,000 10,000 10,000 20.000 20.000 104000 10,000 10,000 20,000 10,000 10,000 20.000 10.000 10.000 20,000 --- --- --- --- --- --- --- --- --- --- --- --- ___ --- --- •-- --- --- --- --- --- --- --- u u u u u U u V a V u V u U u u U u U V u u u --- --- --- --- --- --- --- --- --- --- --- --- ___ -•- --- --- --- --- --- --- --- --- --- u u u u u V v V u U V u u u V u u V v u u u u --- --- --- --- --- --- --- --- •-- --- --- --- .__ --- --- --- --- --- --- --- --- --- --- u u u u u u u a u u u u u u V V u u u U U V V --- --- --- --- --- --- --- --- --- --- --- --- ___ •-- --- --- --- --- --- --- --- --- --- U u u V V V v u u U U V u u u U u u U U v u u --- --- --- --- --- --- --- --- --- --- --- --- ___ --- --- --- --- --- --- --- --- --- --- u u u u u u v u u u u U u 0 v u u u u u u u u 75. 76, 77, 78. 79, 80, 81, 92, 83, 84, 85, 86. 97, 00, 89. 90, 91, 92. 93, 94, 95. 96, Methapyrilene 3-Methylcholanthrene 2-Methylnaphthalene Nethyl Parathion m-Cresol 1,4-Naphthequlnone 1-Naphthylamine 2-Naphthylamine 2-NitroanSline 3-NitroanSline 4-NitroanSline 5-Nitro-O-Toluidine N-Nitroeodl-n-butylamine N-Nitrosadiethylamine N-Nitroeomethylethylamine N-Nitroaopiperidine N-Nitrosopyrrolidlne Parathion Pentachlorobenzene Pentachloronitrobenzene Phenaaatin 1,4-Benzenediamine 3.54 4.21 3,79 4,32 3,81 4,00 5.61 4,62 3,61 4,81 4,22 4.01 3,63 3,83 3.83 5.19 2.89 3.12 3,92 3,71 4,41 2099 1004000 10.000 10.000 104000 10,000 10,000 10,000 10.000 50,000 50,000 20,000 10.000 10,000 20,000 10,000 20,000 10,000 30.000 104000 20400 20.000 10,000 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ___ --- --- --- --- u u u ❑ U V u u u u v u u u v V u u U v u u --- --- --- --- --- --- --- --- --- --- --- -•- --- --- --- --- --- ___ •-- --- --- --- V u V u U V u u u u u u V U V u V U u v U u --- --- --• --- --- --- --- -•- --- --- --• -•- --- --- --- --- --- ___ --- --- --- --- u U U u u U U v V u u u ❑ V u u V U u v u U --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- ___ --- --- --- --• u V V u V u V u u u u V u u V u V U u v u of --- --- --- --- --- --- --- --- --- --- --- --- --- --- -•- --- --- ___ --- --- --- --- u V V U U U u u u U v V u u V u u u u u u V ,7 estimated value between the MDL and MRL, U Below ALL Quantltatlon Limits. Environment 1, Incor GRuElmvl E, N.C.27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT 4021 STIRRUP DURHAM, NC & INFRASTRUCTURE CREEK DR. STE 100 27703 ANALYST: DATE COLLECTED: DATE EXTRACTED: JAP 12/12/19 12/16/19 REVIEWED BY: DATE ANALYZED: DATE REPORTED: 01/23/20 02/21/20 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) Page: 3 PARAMETERS, ug/1 MDL HRL MW-4 MW-5 MW-6 MW-7 MW-S 97, Phorate 3,86 10,000 --- W --- U --- U --- V --- U 98, Pronamlde 3.69 30.000 --- U --- V ___ u ___ V ___ V 99, Sa¢role 4,12 10,000 --- U --- V --- U --- u --- U 100, 1,2,4,5-Tetrachlorobenzene 5.01 10,000 --- a --- U --- U --- U --- V 101, Thionaaln 4,62 20.000 --- V --- V --- U U --- V 102. 0-Toluldlna 4,11 10.000 --- U --- U --- U --- U --- V 103, 1,3, 5-Trinitrobanaene 3,90 10.000 --- V --- v -- u --- u --- v 104. 0,0,0-Triethyl Phoophor0thloate 3,61 10.000 --- U --- V --- u --- V --- u 105, Hexachloroethane 1.49 10.000 --- U --- V --- U --- U --- U 106, Ieodrin 3,11 10.000 --- a --- V --- V --- U •-- U J Batlmated value between the MDL and MAL, U Bolow ALL Vuantitation Limlte. Environment 1, 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 W9Btewetor IDi PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 REVIEWED 8Y: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) Pages 1 PARAMETBAe, ug/1 MDL MRL MW-4 MW-5 MW-6 MW-7 MW-8 1, Chloromethane 0,77 3,000 --- U --- U --- V --- V --- U a. Vinyl Chloride 0,12 0.200 --- U --- U --- U --- V --- U 3. eromomethane 0.67 30.000 •-- U --- V --- U U U 9, Chloroethana 0.48 30.000 --- V --- U --- U --- U --- U 5, Trichlorofluoromethane 0,24 1.000 --- U --- U --- U --- U --- V 6. 1,1-Dichloroethene 0.17 5.000 --- U --- U --- U --- U --- U 7. Acetone 9.06 1006000 --- U --- U 9,48 J --- U 17,40 J 8. Iodomethane 0,26 10.000 --- U --- U W. U --- U --- U 9, Carbon Disulfide 0,23 100.000 --- U --- V --- U --- U •-- U 10, Methylene Chloride 0.64 1.000 --- U -•- U --- U --- U --- U 11. trans-1,2-Dichloroethene 0,23 5.000 --- U --- U --- U --- U --- U 12, 1,1-Dichloroethene 0.20 5,000 --- U --- U --- U --- U --- U 13, Vinyl ApetaEe 0,20 50.000 --- U --- U --- U --- U --- U 14. Cie-1,2-Dichloroethene 0.25 5.000 --- U --- U --- U --- U --- U 15, 2-Butanone 2,21 100.000 --- U --- U --- U --- U --- U 16, Bromochloromethane 0,27 3.000 --- V --- U --- V --- U --- V 17, Chloroform 0.15 5.000 --- U --- U --- U --- U --- U 18, 1, 1, 1-Triohloroethane 0.19 1.000 --- U --- U --- U --- U --- U 19, Carbon Tetrachloride 0.04 0.200 --' U --- U --- U -"" U --- V 10, Benzene 0.14 1.000 --- U --- U --- U --- U 1,13 21. 1,2-Dichloroethene 0.01 0.200 --- U --- U --- U U --- U 12, Triohloroethane 0.13 1.000 --- U --- U ___ U __. V ___ U 23, 1,2-Diahloropropans 0,04 0,200 --- U --- V --.- U --• U --- U 24. Bromodichloromethane 0.04 0,200 --- U --- U --- U --- V -•- V 25. Cie-1,3-Dichloropropene 0.06 0.200 --- U --- U --- U --- U --- U 26, 4-Methyl-2-Pentanone 1919 300.000 --- U --- V --- U --- U --- U 27, Toluene 0,23 1.000 --- U --- V --- U --- U --- U 28, tzans-1,3-Dichloropropene 0,04 0,200 --- U --- U --- U --- U --- U 29, 1,1,2-Trichloroethane 0.03 0,200 --- V --- U --- V --- U --- V 30, Tetrachloroethene 0.10 0.200 --- U --- U --- U --- U --• U 31, 2-Hexanone 1.57 50,000 --- U --- U --- U --- U --- U 32, Dibromochloromethane 0,03 0,200 --- U --- U --- V --- U --- V 33, 1,1-Dibromoethane 0.03 0.200 --- U --- U --- V --- U --- U 34, Chlozobenzena 0.30 3,000 __. U ___ U ___ U ___ U ___ U 35, 1,1,1,2-Tetrachloroethene 0.12 1.000 --- U --- U --- U --- U --- U 36, Bthylbenzene 0,21 1.000 --- U --- U --- u --- U --- V 37. xylenee 0.68 5.000 --- U --- U --- U --- U --- U 38, Dibromomethane 0,29 10,000 --- U --- U --- U --- V --- U 39. Styrene 0.19 1.000 --- U --- U --- U --- U --- U 40, Bromoform 0,20 3,000 --- U --- U --- U --- V --- U 41, 1,1,2,2-Tetrachloroothens 0,03 0.200 --- U --- U --- U --- V 0,22 42, 1,1,3-Trichloropropane 0.09 0,200 --- U --- V --- U --- U --- U 43. 1,4-DSchlorobenzene 0.39 1.000 --- U --- U --- U --- V --- U 44. 1,2-Dichla robenxene 0.32 5.000 --- II --- U --- V U U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.200 --- U --- U --- U --- U --- U 46, Acrylonitzile 2,72 200.000 --- V --- U --- U --- U --- U 47. trans-1,4-Dichloro-2-Butene 0,42 100,000 --- U --- U --- V --- U --- U 48. ACrolein 1.97 4.000 --- U --- U --- U --- V --• U J = Estimated value between the MDL and MAL, U Below ALL Ouantitation Limits. Enviroi�inent 1, 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II R.PA MRTRnn A26nn R4 (18) PHONE (252) 756-6208 FAX (252) 756.0633 CLIENT ID: 6003 ANALYST: JAP DATE COLLECTED: 12/12/19 DA DAT TE ANALYZED: 12/18/19 E REPORTED: 02/21/20 Page: 2 PARAMETERS, ug/1 MDL MEL MW-4 MW-5 MW-6 MW-7 MW-8 49, Allyl Chloride 0,20 10.000 --- U --- U --- V --- u -•- U 50, Chloroprene 0,21 20,000 --- U --- u --- a --- U --- U 51. 1,3-Dichlorobenrene 0.41 5.000 --- V --- U --- u •-- U --- U 52, Diehlorodifluoromethane 0.51 5.000 --- u --- u --- u --- V --- u 53, 1,3-Dichloropropane 0,29 1.000 --- U --- V --- u --- U --- u 54, 2,2-Dichloropropane 0,17 15.000 --- u --- V --- u --- u --- u 55, 1,1-Dichloropropane 0,22 5.000 --- u --- U --- u --- V --- u 56. Ethyl Mathaorylate 0116 10.000 --- U --- u --- u --- u --- u 57, Hexachlorobutadiene 0.10 0.200 --- u --- u --- u --- u --- u 50, Ieobutyl Alcohol 12,80 100,000 --- V --- u --- V --- u --- V 59, Methaorylonitrile 1,93 100,000 --- U --- a --- V --- U --- U 60, Methyl Methacrylate 0,25 30.000 --- U --- u --- U --- U --- u 61, Naphthalene 0,47 64000 --• u --- u --- u --- U --- u 62, Propionitrile 3,26 150,000 --- u --- U --- u --- u --- U 63. 1,2,4-Trichlorobenzene 0.50 10,000 --- U --- U --- u --- u --- u 64, Acetonitrile 36.29 55.000 --- U --- u --- V --- U --- U 65, Tetrahydrofuran 0,39 1.000 --- u 2,49 14,70 2.47 32,90 66, 1,4-Dioxane 2,71 3.000 --- U 31,70 25,30 8,51 218,00 S = 8etimeted value between Che MHL and MAL, U Helow ALL Quantltation Limlte, Environment 1, Inco rated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 ANALYST: JAP DATE COLLECTED: 12/12/19 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 PARAMETERS, U9/1 MDL MRL Trip Blank 1, Chloromethane 0,77 3.000 --- V 2, Vinyl Chloride 0.12 0.200 --- V 3, Bromomethane 0,67 104000 --- U 4, Chlorcethane 0.40 10,000 --- U 5, Trichlorofluoromethane 0,24 1.000 --- V 6, 1,1-DSchloroethene 0,17 5.000 --- V 7, Acetone 9,06 100400 --- V 8. Iodomethane 0,26 104000 --- U 9, Carbon Disulfide 0,23 1009000 --- U 106 Methylene Chloride 0,64 14000 --- U 11, trans-1,2-Dichlaroethene 0,23 5,000 --- V 12. 1,1-Dichloroethane 0,20 5.000 --- U 13, Vinyl Acetate 0,20 50,000 --- V 14, Cie-1,2-Dichloroethene 0.25 5.000 --- U 15. 2-Butanone 2,21 100,000 --- U 16, Bromochloromethane 0,27 3,000 --- U 17, Chloroform 0,25 5.000 --- U 18. 1,1,1-Trlchloroethane 0.19 16000 --- U 19, Carbon Tetrachloride 0,04 0.200 --- V 20, Benzene 0,24 1.000 --- U 21. 1,2-Dichlor0ethane 0,02 0,200 --- U 22, Trichloroethene 0.23 1,000 --- V 23. 112-Dichloropropane 0,04 0,200 --- V 24. Bromodichloromethans 0,04 0,200 --- U 25, Cie-1,3-Dichloropropane 0.06 0,200 --- U 26, 4-Methyl-2-Pentanone 1,19 100,000 --- U 27, Toluene 0,23 1,000 --- U 28. trans-1,3-Dichloropropene 0,04 0,200 --- U 29. 1,1,2-Trichloroathane 0,03 0,200 --- U 30, Tatrachloroethane 0.10 0.200 --- U 31. 2-Hexanons 1.57 50,000 --- U 32, Dibromachloromethane 0.03 0,200 --- ll 33, 1,2-Dibromoethane 0,03 04200 --- U 34, Chlorobenzene 0,30 3.000 --- V 35. 1,1,1,2-Tetrachloroethane 0,22 1.000 --- U 36, Ethylbenzene 0,21 1.000 --- U 37. %ylenee 0,68 5.000 --- V 38. DSbromomethane 0,28 10,000 --- U 39, Styrene 0.19 1.000 --- U 40, Bromoform 0420 3,000 --- U 41, 1,1,2,2-Tetrachloroethane 0,03 0,200 --- U 424 1,2,3-Trichloropropane 0.09 0,200 --- V 43. 1,4-Dichlorobanzens 0.39 14000 •-- V 44, 1,2-Dichlorobenzene 0,32 5.000 --- U 45. 1,2-Dlbromo-3-Chloropropane 0407 0,200 --• U 46, Acrylonitrile 2,72 200,000 --- U 47. trans-1,4-Dlchloro-2-Butens 0,42 1004000 --- U 48, Acrolein 1.97 4,000 --- U Page: 3 S = Estimated value between the MDL and MRL, U Below ALL Quantltatlon Llmite. Environment 1, Incorporated GREENVILLE1 N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT ID: 6003 ANALYST: JAP DATE COLLECTED: 12/12/19 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 PARAMETERS, ug/1 MDL MEL Trlp Blank 49, Allyl Chloride 0.20 10.000 --- U 50, Chloroprene 0,21 20.000 --- U 51. 1,3-Dichlorobenzene 0,41 5,000 --- U 52, Dichlorodlfluoromethane 0.51 5.000 --- U 53, 1,3-Dlchloropropane 0,20 1.000 --- U 54, 202-Dichloropropane 0.17 15.000 --- U 55, 1,1-Dichloropropene 0,22 5.000 --- U 56, Ethyl Methacrylate 0.16 10,000 --- U 57. Hexachlorobutadiene 0.30 0.200 --- U 58. Ieobutyl Alcohol 12,80 1004000 --- U 59, Methacrylonitrile 1,93 100,000 --- U 60. Methyl Methacrylate 0.25 30,000 --- U 61. Naphthalene 0,47 6.000 --- U 62, Propionitrile 3,26 150.000 --- U 63, 1,2,4-Trichlorobenzene 0.50 10,000 --- U 64, Acetonitrile 36,29 55,000 --- U 65, Tetrahydrofuran 0.39 1.000 --- U 66, 1,4-Dioxane 2.71 3,000 --- U Page: 4 J = Hetimated Value between the MDL and MRL, U = Below ALL QuantltatlOR Llmlte. W V LTI N N o y r>C m ]] ]J n D ' b t~ O < ~ CPSI W O k1 z, txj m a O D c O c O oo A 2 m p@ m O 2 m O o - C�ii S�yss rr-�l ED tz C x 9 �7y1 C $i C -� O m m m W W C o W m m m TOTAL CHLORINE, mg/I C7 m m m OR ug/I AT COLLECTION o < n o o - - TEMPERATURE m n AT COLLECTION 7O A O a a rn o. oo OF CONTAINERS 8260D App. II 2 G] d 8260D App. II 3 m 0 8260D App. It 4 G] N 8151A Landfill Gi 0 0 o t 8151A Duplicate oar 9 ro m m %<s ... m O w PARAMETERS/TESTS O 0 S D C �° D 2 O n = r0 P vw, v O (7 D z 2 n z 4 T = = Z m m .90 O Om m O m y � a0 m m c� m m o < m 24 ➢ z m O o m �lS Z n m r�r -n_-I ul m O O x Z z D O ro n a m O m z m D m p 0 v 3 � � Q � m m N m o°' � ri w o' o < o m 3 m ti w d � w � o m w cS � o' a Z !O W V to N W � � � �' i'� o � !� z z z i n � c�n7�(mj M� d � (n m e '7A? �� z I m m m � O z U� o x (14"z� ;'? ivrt� < < � �A�� o v.� � W��°�� � �� o x�ry �� n d ?'viz� � 9 �y d �� � .'` N r � � t, v _ D A � ICJ N Y n G O S/ OD - _ _ � O � � v� ➢ s � r � - O — � � � _.. o � rn m m o m .L � � �> S �' w m TOTAL CHLORINE, mgll � � � � ty m OR ug/I AT COLLECTION � � m m 0 0 0 � '- — TEMPERATURE,°C O < x m J � � < < < AT COLLECTION m o H � � �_ �' a a � � � � � lIOFCONTAINERS Field � ro ... ... :.. .... ... pH Nitrate 9 ro .. .. :.:. :i�. :... Alkalinity 9 'b .. ... ... ... .... � � ;:az»" Cyanide C ro ... . `,3 ... .... ... N N oD . o Sulfate � ro nI ... :.:. .:. .:.. „ s<ti Metals � ro � � � 7.`:'; ��'? �` .... m m m ... Sulfide hn ro V ... .... ... ... :.:. o ;ss'> Conductivity 9 'd ... .... ,,. � Temperature a 'ti :, ._,_ ._. _, ..,, €:�;�. Field Parameter .,, ,,,, .,, °y<i EPA 8270E a � ., :_, .:;Pi _.. "`��.°' 8270E Dnp. 1 Y G� .., ,... ., .,.. EPA 80818 � G] . .:. .:.. ... .. BOB1B Duplicate a G� :,, In sag 8260D App. II � � � .,, .. .. ,,, .. ..< ,,. .. ., ,, ...... ,., .<o i e PARAMETERS/TESTS y � n s � � � ��+ n � 7 . umi o umi � � � � � � � m D � m � x m m � � ? z o � C) O Gl C In p o � Cl � � 31 Z � m cn Or S O z � m � < -V'i' � z � � � °' � Z � a � < � � z � T D G� G� T m a � D -o G� ,� D C] a< Z� m m y m =� D Z � O O O p 7 D � � m �' n � Z n� -r- z�z. -Di 9 O 2 �n z � z � � z P � � zo ci x� y 'dC '<_ o � - x d v � � z�� ��� ��5 o '•' 0 e ro n m 0 IN Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: FAX (252) 756-0633 6003 JP 12/12/19 12/17/19 - 12/18/19 02/21/20 PARAMETERS, ug/1 MDL MRL Concentxatioh 1. Chloromethane 0.77 3.00 -- U 2. Vinyl Chloride 0,12 0,20 --- U 3. Bromomethane 0.67 10.00 -- U 4. Chloroethane 0,48 10.00 -- U 5. Trichlorofluoromethane 0.24 1.00 - U 6. 1,1-Dichloroethene 0,17 5.00 --- U 7, Acetone 9.06 100.00 -- U B. Iodomethane 0,26 10.00 -- U 9, Carbon Disulfide 0,23 100,00 - U 10. Methylene Chloride 0,64 1.00 --- U 11. trans-1,2-Dichloroethane 0,23 5.00 --- U 12. 1,1-Dichloroethane 0,20 5.00 --- U 13. Vinyl Acetate 0,20 50.00 --- U 14. cis-1,2-Dichloroethane 0,25 5.00 --- U 15. 2-Butanone 2,21 100,00 - U 16. Bromochloromethane 0.27 3.00 -- U 17. Chloroform 0.25 5,00 - U 18. 1,1,1-Trichloroethane 0.19 1.00 --- U 19, Carbon Tetrachloride 0,04 0,20 - U 20, Benzene 0,24 1.00 -- U 21. 1,2-Dichloroethane 0,02 0,20 --- U 22. Trichloroethee 0,23 1.00 -- U 23, 1,2-Dichloropropane 0.04 0,20 --- U 24. Bromodichloromethane 0,04 0,20 -- U 25, cis-1,3-Dichloropropene 0.06 0.20 --- U 26. 4-methyl-2-Pentanone 1.19 100.00 --- U 27. Toluene 0,23 1,00 - U 28. trans-1,3-Dichloropropene 0.04 0.20 --- U 29. 1,1,2-Trichloroethane 0.03 0.20 --- U 30. Tetrachloroethene 0.10 0.20 - U 31. 2-Hexanene 1,57 40,00 - U 32, Dibromochloromethane 0.03 0.20 -- U 33, 1,2-Dibromoethane 0.03 0.20 --- U 34. Chlorobenzene 0,30 3.00 -- U 35. 1,1,1,2-Tetrachlcroethane 0,22 1.00 --- U 36. Ethylbenzene 0,21 1.00 --- U 37. Eylenes 0.68 5.00 --- U 38, Dibromomethane 0.28 10,00 - U 39, Styrene 0.19 loco --- U 40. Bromoform 0,20 3.00 - U 41. 1,1,2,2-Tetrachloroethane 0.03 0,20 --- U 42. 1,2,3-Trichloropropane 0.09 0,20 --- U 43, 1,4-Dichlorobenzene 0.39 1100 --- U 44. 1,2-Dichlorobenzene 0,32 5.00 --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0,20 --- U 46. Acrylonitxile 2,72 200,00 --- U 47. trans-1,4-Dichloro-2-Butene 0.42 100.00 --- U 48, Acrolein 1.97 4.00 -- U 49. Allyl Chloride 022 50.00 --- U 5oprene0. Chlor 0..21 20,00 1--- U Environment 1, Inco 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT 6 INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS (continued) 6003 JP 12/12/19 12/17/19 12/18/19 02/07/20 PARAMETERS, ug/1 MDL MRL Concentration 51, 1,3-Dichlorobenzene 0.41 5,00 --- U 52. Dichlorodifluoromethane 0.51 5.00 --- U 53, 1,3-Dichloropropane 0.28 1.00 --- U 54. 2,2-Dichloropropane 0,17 15.00 --- U 55, 111-Dichloropropene 0,22 5.00 --- U 56. Ethyl Methacrylate 0,16 10.00 --- U 57. Hexachlorobutadiene 0.10 0,20 --- U 58. Isobutyl Alcohol 12,00 100,00 --- U 59. Methacrylonitrile 1,93 100.00 --- U 60, Methyl Methacrylate 61. Naphthalene 62, Propionitrile 63. 102,4-Trichloxobenzene 64, Acetonitrile 65. Tetrahydrofuran 66, 1,4-Dioxane Environment 1, Incorporated GREENVILLE0 N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) SURROGATE RECOVERY RESULTS FAX (252) 756-0633 JP 12/12/19 12/17/19 - 12/18/19 02/21/20 Sample Name Limita (% recovery) 1,2-DCA-d4 (E recovery) Toluene-d8 (8 recovery) 4-HFH (b recovery) Continuing Calibration std. 70-130 100 100 101 Method Blank 70-130 102 102 101 MN-4 70-130 104 100 99.7 MW-5 70-130 104 100 101 MW-6 70-130 105 101 100 MW-7 70-130 104 102 101 MW-8 70-130 104 100 102 Trip blank 70-130 104 102 101 6003 MW-1S M.S. 70-130 99.1 98.4 98.2 6003 MW-iS M.S.D. 70-130 99.4 98.6 99.8 Environment 1, Incorporated GREENVILLE, N.C. 27858 E (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS Sample Spiked: (6003) blw-la Spike Amount Ug/1 Sample Result Ug/1 Spike Result Ug/1 Spike Recovery (70-130%) Spike Dup. Result Ug/1 Spike Dup. Recovery (70-130%) MS/MSD RPD (20%) 1,1-Dichloroethene Benzene 20.0 20.0 -- U -- U 21,33 22.04 107 110 21,60 22.68 108 113 1.3 2.9 Trichloroethene 20 .0 - U 22.02 110 22.84 114 3.7 Toluene 20.0 - U 21.47 107 22.48 112 4.6 Chlorobenzene 20.0 - U 20.83 104 21.76 109 4.4 LABORATORY CONTROL SAMPLE RESULTS Sample Compound: Spike Amount Ug/l spike Result Ug/l Spike Recovery (70-130%) 111-Dichloroethene 20.00 20.83 104 Benzene 20.00 20.49 102 Trichloroethene 20.00 20.83 104 Toluene 20,00 21.02 105 Chlorobenzene 20.00 20.44 102 Environment 1, Incorporated Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 MW-1s PARAMETERS MIA MRL PH (field m rement), Unite 6.0 Nitrate Nitrogen as N, mg/1 0.009 0,04 0.10 Alkalinity (to pH 4.5), mg CRC03/1 1.0 1.0 154 Cyanide, ug/1 5.0 5.0 --• U sulfate, mg/l 5.0 5.0 143 Antimony, ug/l 0,03 1,0 --- U Armenia, ug/1 0.08 5.0 --- U Barium, ug/l 0,32 10.0 43 Barium, ug/l 0.32 10.0 Barium, ug/l 0.32 10.0 Beryllium, ug/1 0,32 1.0 0,42 J Beryllium, Ug/1 0,32 1.0 Cadmium, ug/1 0,04 1.0 --- U Cobalt, ug/1 0,32 1.0 --- U Cobalt, ug/1 0,32 1.0 Cobalt, ug/1 0,32 1.0 Total Chromium, ug/1 1.05 5.0 3 J Total Chromium, ug/1 1.05 5.0 Total Chromium, ug/l 1.05 5.0 Total Chromium, ug/1 1.05 5.0 Copper, ug/l 1,47 10.0 --- U Copper, ug/1 1,47 10.0 Copper, ug/1 1,47 10.0 Iron, ug/1 12,08 50.0 505 Manganese, ug/l 0.31 10.0 22 Manganeee, u9/1 0,31 10.0 Manganeee, ug/1 0.31 10.0 Lead, ug/l 0.03 5,0 --- U Mercury, ug/1 0.05 0.20 --- U Nickel, ug/l 0,32 10.0 7.9J Nickel, ug/l 0,32 10.0 Nickel, ug/1 0,32 10.0 selenium, ug/1 0.05 10.0 --- U Silver, ug/1 0.51 5.0 --- V silver, ug/1 0,51 5.0 Silver, ug/l 0.51 5.0 Thallium, ug/l 0.02 1.0 --- U Tin, ug/l 0.05 100.0 --- U vanadium, u9/1 0,20 1.0 5 Vanadium, ug/1 0,20 1.0 Vanadium, ug/1 0,20 1.0 zinc, ug/l 1.10 10.0 13 zinc, ug/1 1.10 10.0 zinc, ug/1 1.10 10.0 FAX (252) 756-0633 ID#: 6003 A DATE COLLECTED: 12/11/19 DATE REPORTED 02/07/20 A/ REVIEWED BY: MW-1D MW-2S MW-2D MW- Analysis Method Data Analyst Code 6.5 6.8 8.0 6.9 12/11/19 PJO 4500HB-ll 0.06 0.21 0.29 2,66 12/12/19 DTL 353.2 R2-9 163 1070 175 1430 12/16/19 ONB 2320B•il U --- U --- U --- U --- 183 --- 16 V U --- U 18.5 --• U --- ❑ --- U 125 --- U 22 12/18/19 SBJ 12/12/19 s8J 01/24/20 HAD 01/23/20 NAB 12/23/19 LFJ 450OCNE-11 4500804281 EPA200.8 EPA200.8 EPA200.7 25 13 12/30/19 LPJ SPA200.7 331 650 01/22/20 NAB EPA200.8 0,38 J --- U 12/30/19 LFJ HPA200.7 U --- U 01/08/20 LFJ SPA200.7 --- U --- V --- U --- U 01/24/20 HAD 12/26/19 LPJ BPA200.8 EPA200.7 0.76 J 1 12/30/19 LFJ EPA200.7 3.4 6 01/22/20 NAB EPA200.8 12/26/19 LFJ BPA200.7 1434 12/31/19 LFJ EPA200.7 5.7 02/03/20 NAB HPA200.8 4 J 25 12/30/19 LPJ EPA200.7 12/23/19 LFJ BPA200.7 -__ U 7.81 ___ U 4 J 12/30/19 LFJ 01/24/20 NAB EPA200.7 SPA200.8 2541 14540 203 11990 01/03/20 WAS 3111B-11 12/26/19 LFJ SFA200v7 139 7 J 12/30/19 LFJ BPA200.7 613 1145 01/08/20 LFJ SPA200o7 --- U 0.06 J --- --- V U --- U 0.06 J --- U --- V 01/22/20 NAB 12/26/19 MTM HPA200.8 245.1 R3-9 12/23/19 LFJ SPA200.7 5 J 5 J 12/30/19 LFJ BPA200.7 --- U 14 U --- U 5 J 27 01/08/20 LFJ 01/22/20 NAB 12/23/19 LFJ EPA200.7 BPA200v8 EPA200.7 0.52 J 1.3J 12/30/19 LFJ SPA200.7 -•- U --- V --- --- U U U --- U --- U --- U --- U --- U 01/24/20 NAB 01/22/20 NAB 01/22/20 NAB 12/23/19 LFJ EPA200.8 BPA200.8 EPA200.8 BPA200.7 0.7 J 0,39 J 12/30/19 LPJ BPA200.7 4 5 01/22/20 LFJ EPA200.7 12/26/19 LFJ HPA200.7 7 J 8 J 12/30/19 LFJ BPA200.7 3.5J 3 J 01/24/20 NAB BPA200.8 J estimated value between the MDL and MRL, U Below ALL Quantit atlon Limits. Environment 1, Incorporated D ri nking Water ID, 37715 114 OAKMONT DRIVt GREENVILLE, N.C. 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM ,NC 27703 HulYlde, ug/1 Conduotivi ty (at 25e), uHhoe/om Dissolved Oxygen, mg/l Temperature, °C Statio Water Level, feet Well Depth, fast ORP, m Turbidity (Field), NTU MW-18 MW-1D NDL MRL 100 1000 --- V 422 J 1.0 1.0 613 400 0.1 0.1 1.74 0.33 13 15 8.18 8.86 17,21 33.75 +141 +115 1.0 1.0 2.so 7.51 --- U 2790 0.48 16 11,35 1fi .57 110 98 5. PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 A DATE COLLECTED: 12/11/19 DATE REPORTED : 02/07/20 REVIEWED BY: MW-2D MW-3H Analysis Method J = setlmated value between the MDL and MRL, V Below ALL UuantltaClon LSmlte. Data Analyst Code --- U --- U 12/12/19 LFJ 450DS2D-11 923 3477 12/11/19 PJC 2510E-11 0 .72 0.9E 12/11/19 PJC 4500DD-21 16 18 12/11/19 PJC 2550E-10 12.67 12,74 12/11/19 PJC 38.17 22,24 12/11/19 PJC +62 +111 12/11/19 PJC 2580E-11 2.64 6,87 12/11/19 PJC 21308-11 Drinking Water Ins 37715 114 OAKMONT DRIVE PHONE (252) 756-6208 GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 A JUD SON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 12/11/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED 02/07/20 DURHAM ,NC 27703 REVIEWED BY: MW-3D MW-3A Trip Analysis Method PARAMETERS MDL MEL Blank Date Analyst Code PH (field measurement), Units 7*7 6.8 12/11/19 PJC 4500HB-11 Nitrate Nitrogen as N, mg/1 0.009 0.04 Oo26 --- U 12/12/19 DTL 353.2 R2-93 Alkalinity (to pH 405), mg CaCO3/1 1.0 1.0 228 840 12/16/19 DNB 2320B-11 cyanide, ug/1 5.0 5.0 --- U --- V 12/1B/19 SEJ 4500CNB-11 Sulfate, mg/l 5.0 5.0 Soo 86.3 12/12/19 SEJ 45000042311 Antimony, ug/l 0oO3 110 --- U --- U 01/24/20 NAB RPA200.8 Arsenic, coca 5.0 --- U 20 01/23/20 NAB EPA200oa ug/1 Barium, ug/1 0432 10.0 B J 299 12/30/19 LFJ EPA200.7 Beryllium, ug/1 0,32 1.0 --- u --- U 12/30/19 LFJ BPA200.7 Cadmium, ug/l 0004 1.0 --- U --- U 01/24/20 NAB BPA200oB Cobalt, ug/1 0,32 140 1 7 12/30/19 LFJ BPA200o7 Total Chromium, ug/l 1405 540 --- U 15 12/30/19 LFJ SPA200.7 Copper, ug/1 1,47 10.0 --- U 2 J 12/30/19 LFJ BPA200o7 ;ron, ug/1 12o08 50o0 134 22520 01/03/20 NAB 3111E-I1 Manganese, ug/l 0.31 10.0 3 J 695 12/30/19 LFJ EPA20047 Lead, ug/l 0,03 540 --- U --- U 01/22/20 NAB SPA200o8 Mercury, ug/1 0405 0,20. --- u --- U 12/26/19 MTN 245o1 R3-94 Nickel, ug/l 0,32 10.0 2 J 5 J 12/30/19 LFJ EPA200.7 Selenium, ug/l 0.05 10.0 --- V 19 01/22/20 NAB EPA200.8 Silver, ug/1 0,51 5.0 1 J --- U 12/30/19 LPJ EPA200.7 Thallium, ug/1 0o02 1.0 --- U --- U 01/22/20 NAB BPA200o8 Tin, ug/1 0.05 10000 --- U --- U 01/22/20 NAB SPA200oB Vanadium, ug/l 0*20 1.0 --- U 4 12/30/19 LPJ BPA200.7 Zinc, ug/1 1410 10*0 5 J 3 J 12/30/19 LFJ BPA200o7 Sulfide, ug/1 100 1000 --- U --- U 12/11/19 LFJ 450082D-11 Conductivity (at 25c), uMhos/cm 140 1.0 527 2679 12/11/19 PJC 2530E-11 Dissolved Oxygen, mg/l 0.1 Uol 2*57 1.79 12/11/19 PJC 450000-11 Temperature, °C 17 16 12/11/19 PJC 2550E-10 Static Water Level, feet 12,90 11,65 12/11/19 PJC Well Depth, feet 52930 23,44 12/11/19 PJC ORP, my +121 +101 12/11/19 PJC 25B08-11 Turbidity (Field), NTU 1.0 1.0 1,14 6.66 12/11/19 PJC 213OB-11 J = Estimated value between the MDL and MRL, U e eelOW ALL QuflRtltation Limits. Environment 1, Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST %C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: PESTICIDES AND PCB'S van mvmxnn RnR1n R2(07) CLIENT ID: ANALYST: DATE COLLECTED: DATE EXTRACTED: DATE ANALYZED: DATE REPORTED: Drinking Water Ing 37715 PHONE (252) 756-6208 FAX (252) 756-0633 6003 A HIC 12/11/19 12/12/19 12/30/19 02/07/20 Page: 1 PARAMETERS, ug/l MDL HRL Mw-1H Hw-1D Mw-as Mw-an Mrr-3a 1, 2, 3. 4, 5. 6, 7. 8. 9, lo. 11, 12. 13. 14, 15, 16, 17, 18. 19. 20. Aldrin Alpha-BHC Beta-BHC Delta-BHC Gamma-BHC (Lindane) Chlordane 414-DDD 4,4-DDE 4,4-DDT Dieldrin Endoeulfan I 8ndoeulfan II Endoaulfan Sulfate Endrin Endrin Aldehyde Heptachlor Heptachlor Epoxide Methoxychlor Pcb'S (Aroclore) Toxaphene 0.029 0.032 0.031 0.030 0.032 0.320 0.051 0.049 0,052 0.042 0.056 0.046 0.072 0.053 0.068 0.039 0.042 0.530 0.500 0.690 0.050 0.050 0.050 0.050 0.050 0.500 0.100 0.100 0.100 0.075 0.100 0.300 0.100 0.100 0.100 0.050 0.075 1.000 2.000 1.500 --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- 1 U D U V U U U v U U U U U U U U U U U U --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- U U U U U U U U U U U U U U U U V U U U --- --- --- --- --- --- --- --- --- --- --- •-- --- --- --- --- --- --- --- --- U U U U V U U U U U V U U U U U U U U U --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- --- U U U U U U U V V U U U U U U U U U V U --- --- --- --- --- --- --- --- --- --- --- ---U --- --- --- --- --- --- --- --- U U U U U U U U U U U U U U V U U U U J 8etlmated value between Che MOL and MRL, U BelON ALL Vuantitatlon LSmite. Environment 1, Incorporated Drinking Water ID: 37715 1140AKMUNT UHIVt GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE EXTRACTED: 12/12/1.9 DATE ANALYZED: 12/30/19 REVIEWED BY: DATE REPORTED: 02/07/20 PESTICIDES AND PCB'S Fvn MMTHOn RORIE R2(07) PARAMETBRSs ug/l HDL MRL MW-3➢ MW-3A 1. Aldrin 0,029 00050 -•- U --- U 2, Alpha -HNC 0,032 0.050 --- V --- U 3. Beta-BHC 0,031 0.050 --- U --- U 4, Delta-BHC 0.030 09050 --- U --- U 5. Qamma-BHC (Lindane) 0,032 0.050 --• U --- U 6, Chlordane 0.320 0.500 --- U --- U 7. 4f4-DDD 0.051 0.100 --- U --- V S. 4,4-DDE 0,049 0.100 --- U --- U 9. 4,4-➢DT 0,052 0,100 --- U --- U 10. Dieldrin 0,042 0.075 --- U --- V 11. Bndoeulfan I 0.056 00100 --- U --- U 124 Bndoaulfan II 0,046 0,100 --- U --- U 13. Endooulfan Sulfate 0.012 0.100 --- U --- U 14, Endrin 0,053 0.100 --- U --- U 15. Endrin Aldehyde 0.068 0.100 --- U --- U 16, Heptachlor 0.039 0.050 --- U --- U 17, Heptachlor Epoxide 0,042 0,075 --- U --- U 13. Methoxychlor 0,530 1.000 --- U --- U 19. Pob's (Aroolore) 0.500 2.000 --- U --- U 20, Toxaphene 0.690 1.500 --- U --- V J = Estimated value between the MDL and MRL, U Eelow ALL Quantstation Limits. Pale: 2 Environment 1, Incorporated GREENVILLE, N.C. 27856 Drinking Water ID; 37715 as "Water IDi 10.. CNE (252) 756-6208 FAX (252) 756-0633 CLIENT: JVDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE EXTRACTED: 12/17/19 DATE ANALYZED: 01/01/20 REVIEWED BY: z DATE REPORTED: 02/07/20 LANDFILL APPENDIX II wva MF.TUnn 8151A R1(96) Page: 1 MW-19 Mw-1D MW-2E KW-2D W-3E PARAMETERSo ug/1 MDL MRL 1, 2t4-D 0.36 2.010 --- D --- U --- V --- U --- U 2, Dinoeeb 0.54 1.000 --- U --- U --- U --- V --- U 3, 2,4,5-TP 0A 2.000 --- U --• U --- U --- V --- U 4. 2,4,5-T 0.47 2.000 --- D --- U --- U --- V --- U J � Estimated value between the MDL and MALE V Below ALL QRentitfltlOR Llmite. Environment 1, Inco Drinking Water ID: 37715 GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: OVDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE EXTRACTED: 12/17/19 DATE ANALYZED: 01/01/20 REVIEWED EY$ DATE REPORTED: 02/07/20 LANDFILL APPENDIX II EPA METHOD 8151A R1(96) MW-3D MW-3A PARAMHTHRS, ag/l MDL MRL 1, 2,4-D 0,36 2.000 --- u --- D 2, DinOeeb 0,54 1.000 --- U --- U 3, 2,4r5-TP 0.42 2,000 --- U --- U 4, 2,4,5-T 0,47 2.000 --- U --- U J = Hetlmated value between the MDL and MRLr U = HeloW ALL puantitation LSmiE6. Page: 2 Environment 1, Incorporated Drinking Water IDi 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 Page: 1 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/07/20 REVIEWED BY: SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l Date MDL Analyzes MEL 12/27/19 MW-IS 12/27/19 MW-1D 01/22/20 MW-28 01/23/20 MW-2D 01/23/20 MW-3S 1, Aoenaphthene 2,66 10.000 --- u --- U 2,88 J --- U 5,57 a 2. Acenaphthylene 2.60 10,000 --- U --- U --- V --- u --- U 3, Anthracene 2,97 10,000 --- U --- U --- U --- U --- U 4. Benzo[a]antrhacene 4,16 10.000 --- U --- U --- U --- u --- U 5, Benzo[b]Eluoranthene 3,32 10,000 --- U --- U --- U --- U --- u 6. Benzo[k]fluoranthene 4,23 10,000 --- U --- u --- U --- U --- u 7. Benzo[g,h,i]parylene 2,61 10,000 --- V --- U --- u --- V --- U 8. Benzo [a]pyrena 3.27 30.000 ___ u -__ U ___ U ___ V ___ Q 9, 4-Bromophenyl Phenyl Ether 2,63 10.000 --- U --- V M. U --- U --- U 10, Butyl Benzyl Phthalate 5.76 10,000 --- u --- U --- U --- V --- U 11, Bie(2-Chloroethoxy) Methane 3.14 10.000 --- U --- U --- V --- u --- U 12, Bie(2-Chloroethyl) Ether 2.58 10,000 --- U --- U --- U --- U --- U 13. Bie(2-Chloro-l-methylethyl) Ether 2.58 10,000 --- U --- U --- U --- U --- U 14. 2-Chloronaphthalene 2.17 10,000 --- V --- U --- U --- u --- u 15. 4-Chlorophanyl Phenyl Ether 2.42 10,000 --- V --- U --- U M. U --- V 16, Chryeene 4.04 10,000 --- V --- U --- U --- U M. V 17. Dibenzo(a,h]anthracene 2,78 10,000 •-- U --- u --- U --- U --- U 18, Di-N-Butyl Phthalate 3,09 10.000 --- U --- U --- V --- u --- V 19, Dimethyl Phthalate 3,78 10,000 --- U --- U --- U --- U --- V 20. Diethyl Phthalate 3,92 10,000 --- V --- U --- U --- U --- U 21, 2,4-DSnitrotoluene 3,95 10.000 --- U --- V --- V --- U --- U 22, 2,6-DSnitrotoluene 3,88 10.000 --- U --- U --- U --- u --- V 23, Di-N-Datyl Phthalate 2.81 10.000 --- U --- U --- U --- u --- U 24. Hie-(2-Ethylhexyl) Phthalate 9.97 15.OD0 --- U --- U --• U --- U --- U 25, Fluoranthene 3,92 10.000 --- U --- U --- u --- U --- U 26, Fluorene 2.95 10.000 --- U --- U --- V U --- U 27. Hexachlorobenzene 2,61 10.a00 --- U M. u --- U --- U --- U 28, Hexachlorooyclopentadiene 4.16 10,000 --- U --- V --- U --- U --- V 29, Indeno(1,2,3.Cdlpyrene 2,91 10,000 --- u --- U --- U --- u --- u 30. IeoDhorone 3.74 10.000 --- U --- V M. U __ u u 31. Nitrobenzene 2.85 10,000 --- U --- V --- U -- u U 32. N-Nitroeadimethylamine 4,25 10,000 --- V --- U --- U --- U --- V 33. N-Nitroeodiphenylamine 3,95 50.000 --- V --- V --- U --- U --- U 34, N-Nitroeodi-N-Propylamine 4.06 10,000 --- U --- u --- V --- U --- U 35. Phenanthrene 3.44 10.000 --- V --- U --- U --- U --- U 36, Pyrane 3663 10.000 --- V --- U --- u --- U --- U 37. 4-Chl ors-3-Methylphenol 3.79 20.000 --- U --- V "- U U U 38. 2-Chlorophenol 2,75 10,000 --- U --- u --- U --- U --- U 39, 0-Creeol 3.68 10.000 --- V --- u --- V --- U --- V 40. P-Cresol 4.12 30,000 --- U --- V --- V V V 41. 2,4-Dichlarophenol 5,19 10.000 --- U --- U --- U --- U --• U 92. 2,6-Dichlo rophanol 4,89 30.000 --- V --- V --- u --• U --- V 43. 214-Dimethylphenol 3.21 10.000 --- U --- U --- U --- V --- U 44. 4,6-Diaitro-2-Methylphenol 4,77 50,000 --- U --- U --- u --- V --- U 45. 2,4-Dinitrophanol 4,37 50.000 --- U --- V --- U --- u --- V 46, Ethyl Methaneaulfonate 5,26 20.000 --- V --- U --- U --- u --- U 47, Methyl Methaneaulfonate 4.92 10.000 --- U --- U --- U -- u U J = Estimated value between the MDL and MRL, ll = Below ALL Quantitation Limits. Environment 1, Incorporated Drinking Water ID: 37715 Wastewater ID: 10 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/07/20 REVIEWED BY: SEMI -VOLATILE ORGANICS mvn mzrmunn A17nF. pAtiR1 Page: 2 PARAMETERS, ug/1 Data MVL Analysed MRL 12/27/19 MW-19 12/27/19 MW-lp 01/22/20 MW-20 01/23/20 NN-2D 01/23/20 MW-39 48. 2-Nitrophenol 3,64 10.OD0 --- U --- U --- V --- U --- u 49. 4-Nitrophenol 3,17 50.000 --- U --- U --- V --- U --- U 50, Pentachlorophenol 5,33 25,000 --- U --- U --- U --- V --- U 1.86 10.000 --- U --- U --- U --- V --- U 51, Phenol 52, 2,3,4,6-Tetra0hl0r0phsn0l 3,12 10,000 --- U --- U -•- U --- U --- U 53. 2,4,5-Triohlorophenol 4,17 10,000 --- U --- U --- U --- U --- V 54. 2,4,6-Trlchlorophanol 3,84 10,000 --- U --- U --- V --- U M. U 55, Acetophenone 2.89 10,000 --- U --- U --- V --- U --- U 3,98 20,000 --- U --- U --- U --- U --- U 56. 2-Acetylaminofluorene 57. 4-Aminobiphanyl 9,12 20,000 --- U --• U --- u •-- U --- U 58, Eenzyl Alcohol 4,47 20,000 --- U --- U --- u --- U --- U 59. 4-Chloroaniline 3,36 20,000 --- U --- U --- U --- U --- V 60, Chlorobenzilate 5,12 10,000 --- U --- u --- U --- U --- V 61, Diallato 2,98 10,000 --- U --- V --- U --- U --- U 62, Dibensofuran 4,28 10,000 --- U --- V --- U --- U --- V 63, 3,3$-Dichlorobanzidine 4,22 20,000 --- U --- U --- U --- U --- V 64, Dimethoate 3,99 20,000 --- V --- U --- U --- U --- U 65, P-Dimethylaminoazobenzene 2,89 10,000 --- U --- U --- U --- U --- U 66. 7,12-Dimethylbenz[a]anthracene 5,26 10,000 --- u --- U --- U --- U --- U 67, 3,3-Dimethylbenzidine 3,21 10,000 --- u --- U •-- U --- U --- U 68, 1,3-Dinitrobenzene 2,89 20,000 --- U --- U --- U --- U --- U 69, Diphenylamine 5.10 10,000 --- U M. U --- U --- V --- U 4,28 10,000 --- u --- U --- U --- U --- U 70, Disulfotcn 71, Famphur 3,98 20.000 --- V --- U --- U --' U --- U 72, Hexachloropropens 4,31 10,000 --- D --- V --- U --- U --- U 2,88 104000 --- V --- U •-- U --- U --- V 73, Iaosafrole 74, Eepone 2,78 20,000 --- U --- U --- U --- U --- U 75, Hethapyrilene 3,54 100,000 --- U •-- U --- U --- U --- U 76, 3-Methylcholanthrene 4.21 10,000 --- U --- U --- U --- U --- U 77, 2-Methylnaphthalene 3.79 104000 --- U --- U --- U --- U --- U 18, Methyl Parathion 4,32 10,000 --- V --- U --- U --- V --- V 79. m-Cresol 3,81 100000 --- U W. U --- U --- U --- U 80. 1,4-Naphthoquinons 4,00 109000 --- U --- U --- U --- V --- U 81. 1-Naphthylamine 5.61 10,000 --- U --- U --- U --- U --- V 82. 2-Naphthylamine 4,62 10,000 --- U --- U --- U --- V --- U 83, 2-Nitroanillne 3,61 50,000 --- U --- U --- V --- U --• U 84, 3-Mitroaniline 4.81 504000 --- U --- U --- u --- U --- U 85. 4-Nitroaniline 4,22 20.000 •-- U --- U --- u M. V --- U 06. 5-Nitro-O-Toluidine 4.01 30.00o --- V --- U "' U --- u --- U 87, N-Nitrosodi-n-butylamine 3,63 30.000 --- u --- V --- U --- U --- U 88, N-Nitroeodiethylamine 3.83 20.000 --- ❑ --- U --- U --- U --- U 89. N-Nitroeomethylethylamine 3.83 10,000 --- U --- U --- U --- U --- U 90, N-Nitrosopiperidine 5,19 20,000 --- U --- U --- U --- U --- V 91, N-Nltrosopyrrolidine 2.99 10,000 --- V --- U --- U --- U --- V 92, Parathion 3.12 104000 --- U --- U --- U --- U --- U 93. Pentachlorobenzene 3,92 10,000 --- U --- U --- U --- U --- V 94, Pentachloronitrobenzene 3,71 20,000 --- U --- U --- V --- V --- U T Estimated value between the MDL and MRL, U Below ALL UuantiCatlon Limits. Environment 1, @d Drinking Water ID, 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 Page: 3 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/07/20 REVIEWED BY: SEMI -VOLATILE ORGANICS won upmunT R91nv RA (1.R) PARAMETERS, ug/l Date MDL Analyzed MEL 12/27/19 MW-16 12/27/19 MW-lD 01/22/20 MW-29 01/23/20 MW-2D 01/23/20 MW-33 95, Phenacetin 4,41 20,000 --- U --- U --- U --- U '-- U 96. 1,4-Benzenediamine 2.99 30.000 --- U •-- U --- U --- U --- U 97. Phorate 3.86 10.000 --- U --- U --- U --- U --- U 96, Pronamide 3,69 10,000 --- U --- U --- U --- U --- U 99, 9afrole 4,12 10.000 --- U --- U --- U --- U --- D 100. 1,2,4,5-Tetraahlorobenzene 5.01 10,000 --- U --- U --- U --- U --- U 101, Thionazln 4.62 20.000 --- U --- U --- U --- U --- U 102, 0-Toluidine 4.11 10,000 --- U --- U --- U --- U --- U 103, 1,3,5-Trinitrobenzene 3.98 10.000 --- U --- U --- U --- U --- U 104. 0,0,0-Triethyl Phosphorothloate 3,61 10.000 --- U --- U --- U --- U --- U 105, Hexaohloroethane 1.49 10,000 --- U --- U --- U --- U --- U 106, xoodrin 3,11 20.000 --- U --- U --- U --- U --- U J e 8etimated valLLe between Che MOL antl MRL, U = Below ALL Quarttitation LSmSte. Environment 1, Incorporated 114 0AKMON 1 DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: DURHAM, NC 27703 DATE EXTRACTED: DATE REPORTED: REVIEWED BY: SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) Drinking Water ID, 37715 PHONE (252) 756-6208 FAX (252) 756-0633 6003 A JAP 12/11/19 12/16/19 02/07/20 PARAMETERS, ug/l Date MDL Analyzes MRL 01/23/20 MW-3D 01/23/20 MW-3A 1. Acenaphthene 2,66 10.000 --- U 3,30 a 2. Acenaphthylene 2,60 10,000 --- U --- V 3, Anthracene 2.97 10,000 --- U --- V 4, Benzo(a)antrhacene 4,16 10,000 --- U --- U 5. Benzo[b][ luoranthene 3,32 10,000 --- u --- U 6. eenzo[k)tluoranthene 4,23 10,000 --- V --- U 7. eenzo[g,h,i)perylene 2,61 10,000 --- V --- U B. Benzo[a)pyrene 3,27 10,000 --- U --- U 9. 4-Bromophenyl Phenyl Ether 2,63 10,000 --- U --- V 10, Butyl Benzyl Phthalate 5,78 10,000 --- U --- U 11. Ble(2-Chloroethoxy) Methane 3.14 10.000 --- U --- U 12. Bia(2-Chloroethyl) Ether 2,58 10.000 --- U --- U 13. Bia(2-Chloro-l-methylethyl) Ether 2,58 10,000 --- U --- U 14, 2-Chloronaphthalene 2,17 10.000 --- U --- U 15, 4-Chlorophenyl Phenyl Ether 2.42 10.000 --- U --- U 16, Chryaene 4,04 10,000 --- U --- U 17, Dibenzo[a,hlanthracene 2,78 10,000 --- U --- V 1B. Di-N-Butyl Phthalate 3,09 10.000 --- U --- U 19, Dimethyl Phthalate 3,78 10.000 --- V --- U 20. Diethyl Phthalate 3.92 10,000 --- U --- V 21. 2,4-Dinitrotoluene 3.95 10.000 --- U --- U 22. 2,6-Dinitrotoluene 3.88 10,000 --- V •-- U 23. Di-N-Octyl Phthalate 2,81 10.000 --- V --- U 24. Bin-(2-Ethylhexyl) Phthalate 9.97 15.000 --- U --- V 25. Pluoranthene 3.92 10,000 --- U --- U 26, Fluorene 2.95 10.000 --- U --- U 27, Hexachlorobenzene 2,61 10,000 --- U --- V 28, Rexachlorocyclopentadiene 4,16 10,000 --- V --- U 29, lnden0[1,2,3-Cd3pyrene 2,91 10,000 --- U --- U 30, I6ophorone 3,74 10,000 --- U --- U 31, Nitrobenzene 2085 10.000 --- V --- U 32, N-Nitroeodlmethylamine 4.25 10.000 --- U --- U 33, N-Nitroeodiphanylamine 3,95 10,000 --- U --- U 34. N-Nltroeodi-N-Propylamine 4.06 10,000 --- U --- U 35. Phenanthrene 3,24 10.000 --- U --- U 36, Pyrene 3.63 10,000 --- U --- U 37, 4-Chloro-3-Methylphenol 3.79 20,000 --- U --- V 38. 2-Chlorophenol 2.75 10,000 --- U --- U 39. 0-Creeol 3,68 10,000 --- U --- U 40, P-Cresol 4,12 10,000 --- U --- U 41. 2,4-Dichlorophanol 5.19 10,000 --- V --- V 42, 2,6-Dichloraphenol 4,89 10.000 --- V --- U 43, 2,4-Dimethylphenol 3,21 10,000 --- U --- U 44. 4,6-Dinitro-2-Methylphenol 4,77 50.OD0 --- U --- U 45, 2,4-Dinitrophenol 4,37 50,000 --- U --- U 46, Ethyl Methaneeul[onate 5.26 20,000 --- U --- U 47, Methyl MethaneeulEonate 4.92 10.000 --- u --- U ,T estimated value between the MDL and MRL, U Below ALL Ouantitatlon Limlta. Page: 4 Environment 1, I Drinking Water ID: 37715 Waotewater IDi 10 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DRa STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/07/20 REVIEWED BY: 407 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMHT8R9, ug/l Date MDL Analyzed MRL 01/23/20 KW-3D 01/23/20 MW-3A 48. 2-Nitrophenol 3,64 10,000 --- U --- U 49. 4-Nitrophen01 3,17 50,000 --- U --- U 50, Pentaohlorophenol 5,33 25,000 --- U •-- U 51, Phenol 1,86 104000 --- U --- U 52, 2,3,4,6-Tatrachlorophenol 3,12 10,000 --- U --- U 53. 2,4,5-Triahlorophenol 4,17 10,000 --- U --- U 549 2,4,6-Triahlorophenol 3,84 101000 --- U --- V 55, Acetophenone 2.89 109000 --- V -•- V 56, 2-Acetylaminofluorene 3.98 20,000 --- V '-- U 57, 4-Aminobiphenyl 4,12 20,000 --- U --- U 58, Henzyl Alcohol 4,47 20.000 --- V --- U 59, 4-Chloroaniline 3,36 20,000 --- V --- U 60, Chlorobenzilate 5,12 10,000 --- V --- V 61. Dialiate 2,98 10.000 --- U --- U 62, Dibenzofuran 4,29 104000 --- U --- U 63, 3,3`-Dichlorobenzidine 4,22 20,000 --- U --- U 64, Dimethoate 3,98 20.000 --- U --- U 65, P-Dimethylaminoazobenzene 2,09 10,000 --- U --- U 66, 7,12-Dimethylbenz[alanthracene 5126 10,000 --- V --- U 67, 3,3-Dlmethylbenzidine 3,21 10,000 --- U --- U 68, 1,3-Dinitrabenzene 2,89 20.000 --- U --- U 691 Diphenylamine 5,10 10,000 --- U --- U 70, Diaulfoton 4,28 10,000 •-- U --- U 71, Famphur 3,98 20,000 --- V --- U 72. Hexachloropropene 4,31 100000 --- U --- U 73, Ieoeafrole 2,88 100000 --- U --- U 74. Repone 2,78 20,000 --- U --- U 75, Methapyrilene 3,54 100,000 --- U --- ❑ 76, 3-Methylcholanthrene 4,21 10,000 --- U --- U 77, 2-Mathylnaphthalene 3,79 30,000 --- U --- U 78, Methyl Parathion 4,32 10,000 --- U --- U 79, m-Cresol 3,81 10,000 --- U --- U 80. 1,4-Haphthoquinone 4.00 104000 --- U --- U 81. 1-Naphthylamine 5,61 10,000 --- V --- U 92. 2-Naphthylamine 4,62 30.000 --- U --- V 83. 2-Nitroaniline 3.61 50.000 --- U --- U 84. 3-Nitroaniline 4,81 50,000 --- U --- U 859 4-Nitroaniline 4,22 20.000 --- V --- U 86, 5-Nitro-O-Toluidine 4,01 10,000 --- U --- V 87. N-Nitroeodi-n-butylamine 3,63 10,000 --- U --- V 88. N-Nitroeodiethylamine 3,63 20,000 --- U --- U 89, N-Nitroeomethylethylamine 3.83 100000 --- U --- U 90, N-Nitroeopiperidine 5,19 20,000 --- U --- U 91. N-Nitroeopyrrolidina 2,89 10,000 --- U --- U 92, Parathion 3,12 109000 --- U --- V 93, Pentachlorobenzene 3.92 10,000 --- U --- U 94, 2entachloronitrobenzene 3,71 20,000 --- U --- U J Hetimated value between the MDL and MRL, U • Below ALL Quantitation Limits. Page: 5 Environment 1, I IIME 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 7703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/07/20 REVIEWED HY: SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS, ug/l Date MDL Analyzes MRL 01/23/20 MW-3D 01/23/20 MW-3A 95, Phenacetin 4.41 20,000 --- U --- U 96. 1,4-Ban zenedlamine 2,99 10,000 --- u --- B 99, Phorate 3,06 10,000 •-- U --- U 90. Pronamide 3,69 10,000 --- D --- U 99, Safrole 4.12 10,000 --- U --- U 100, 1,2,4,5-Tetrachlorobenzene 5.01 10,000 --- U --- U 101, Thionazin 4.62 20.000 --- U --- U 102, 0-Toluidine 4.11 10,000 --- U --- U 103. 1,3,5-Trinitrobenzene 3.9E 10,000 --- U --- U 104, 0,0,0-Triethyl Phoephorothloate 3.61 10,000 --- U --- U 105. Hexachloroethene 1.49 10,000 --- u --- D 106, Ieodrin 3.11 20400 --- D --- B J = Estimated value between the MDL and MR[., U = eelOW ALL Quantitatlon Limlte. Page: 6 Drinking Water ID: 37715 Wastewater I➢: 10. GREENVILLEI N.C. 27858 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DRa STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE REPORTED: 02/07/20 REVIEWED BY: LANDFILL APPENDIX II F.DA MRTFnn R260D R4(18) Page: 1 PARAMHTERS, ug/1 Date MOL Analyzed HAL 12/17/19 Mw-IS 12/20/19 Mw-1D 12/19/19 MW-2s 12/18/19 MW-2D 12/18/19 Mw-39 1, Chloromethane 0.77 3,000 --- U --- U --- U --- U --- U 2, Vinyl Chloride 0.12 0.200 --- U --- U --- U --- U --- U 3, Bromomethane 0.67 10.000 --- V --- U --- U --- U --- U 4, Chloroethane 0.40 30.000 --- U --- V --- U --- U --- U 5, Trichlorofluoromethane 0,24 1.000 --- U --- U --- U --- V --- U 6. 1,1-Dichloroethene 0,17 5.000 --- V --- U --- U --- U --- U 9,06 100,000 --- U --- U 11.30 J --- U --- U 7, Acetone B. Iodomethane 0.26 10.000 --- U --- U -•- U --- U --- U 9, Carbon Disulfide 0,23 100,000 --- U --- U --- U --- U --- U 10. Methylene Chloride 0*64 1.000 --- U --- V --- U --- U --- U 11. trans-1,2-Dichloroethene 0,23 5,000 --- V --- U --- U --- V --- U 12. 1,1-Dichloroathane 0,20 5.000 --- U --- U --- V --- U --- V 13. Vinyl Acetate 0,20 50,000 --- U --- U --- U --- U --- V 14. Cis-1,2-Dichloroethene 0.25 5.000 --- U --- U --- U --- U --- V 2.31 300.000 --- V --- D --- U --- U --- V 15. 2-eutanone 0.27 3.000 --- U --- U --- V --- U --- U 16. 17, Bromochloromethane Chloroform 0.25 5.000 --- U --- U --- U --- V --- V 18, 1,1,1-Trlchloroathane 0,19 1.000 --- U --- U --- U --- U --- U 19, Carbon Tetrachloride 0,04 0,200 --- V --- U --- U --- U --- U 0,24 1.000 --- V --- V 0.44 J --- U 1.81 20, Benzene 21, 1,2-Dichloroathane 0.02 0.200 --- U --- U --- U --- U --- U 22, Trichloroethene 0,23 1,000 --- U --- U --- U --- V --- U 23, 1,2-Diohloropropane 0.04 0,200 --- U W. U --- U --- U 0.04 J 24, Bromodichloromethane 0,04 0,200 --- U --- U --- U --- U --- U 25. Cie-1,3-Dichloropropens 0.06 0.200 --- U --• V --- V --- U --- U 26, 4-Methyl-2-Pentanone 1.19 1004000 --- U --- U --- U --- U --- U 0,23 1.000 --- U 0.24 J --- U --- U •-- V 27, Toluene 28. trans-1,3-Dlchloropropens 0,04 0.200 --- U --- U --- V --- U --- U 29, 1,1,2-Trichloroethane 0,03 0.200 --- U --- U --- U --- V --- U 30, Tetrachloroethene 0.10 0.200 --- U --- U --- V --- U --- U 31. 2-Hexanone 1,57 50,000 --- U --- U --- U --- V --- U 32. Dibromochloromethane 0,03 0,200 --- U --- U --- U --- V --• U 0.03 0,200 --- U --- U 0,07 J --- U 0.05 J 33. 1,2-Dibromoethane 34, Chlorobenzene 0.30 3,000 --- U --- V --- U --- U --- U 35. 1,1,1,2-Tetrachloroethane 0,22 1.000 --- U --- U --- U --- V --- U 36, Ethylbenzene 0.21 1.000 --- U --- U --- U --- U --- U 37, Aylenes 0.68 5.000 --- V --- U --- U --- U --- U 38. Dibromomethane 0,28 10,000 --- V --- U --- U --- U ••- U 39. Styrene 0.19 1.000 --- U --- U --- U --- U --- U 40, Bromoform 0.20 3,000 --- U --- U --- V --- V --- U 0,03 0,200 --- U --- U 0.12 J --- V 0,13 J 41, 1,1,212-Tetrachloroethane 42, 1,2,3-Trichloropropane 0.09 0.200 --- U --- V --- V --- V --- V 43, 1,4-Diohlorobenzene 0,39 1,000 --- U --- V --- U --- U --- U 44. 1,2-Diohlorobenzene 0,32 5.000 --- U --- U --- U --- U --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0,200 --- V --- U --- U --- V --• U 46, Acrylonitrile 2.72 200.000 --- U --- U --- U --- V --- U 47, trans-1.4-Dichloro-2-Butene 0,42 100.000 --- U --- U --- V --- U --- U J Estimated value between the HDL and MRL, U ealow ALL Quantltation Llm Ste. �6l�C�Of�Do u @d Drinking Water IDS 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) C7rIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 Page: 2 DURHAM, NC 27703 DATE REPORTED: 02/07/20 REVIEWED BY: LANDFILL APPENDIX II F.PA M12THOD 8290D R4 (18) PARANETHRS, ug/l Date NDL Analyzed NRL 12/17/19 NN-18. 12/21119 1 NN-lD 12/18/19 NE 12/10/19 NW-2D 12/18/19 NN-38 48, Acrolein 1,97 4.000 --- U --- U --- U --- V --- U 49. Allyl Chloride 0,20 10,000 --- D --- U --- U --- V --- U 50. Chloroprene 0,21 20,000 --- U --- U --- U --- U --- U 52. 1,3-Dichlorobenzene 0,41 5.000 --- U --- U --- U --- V --- V 52. Dichlorod151uoromethane 0.51 5.000 --- U --- U --- U --- U --- U 53. 1,3-Dichloropropane 0,26 1.000 --- U --- U --- U •-- U --- U 54, 2,2-Dichloropropane 0.17 15.000 --- p --- U ___ D --' U '-- u 55, 1,1-Dichloropropane 0.22 5.000 --- U --- U --- U --- V --- U 56, Ethyl Nethacrylate 0.16 10.000 --- U --- U --- U --- U --- U 57, Hexachlorobutadiene 0.10 0,200 --- V --- V --- U --- V --- V 58, IBobutyl Alcohol 12,80 100,000 --- V --- U --- U --- U --• V 59, Nethacrylonitrile 1,93 100,000 --- U --- U --- u --- U --- U 60, Methyl Nethacrylate 0.25 30.000 --- V --- U --- U --- U --- U 61, Naphthalene 0,47 6.DD0 --- U --- U 4,14 C --- U --- u 62, Propionitrile 3,26 150,000 --- U --- ❑ --- U --- U --- u 63. 1,2,4-Trichlorobenzene 0.50 10,000 --- U --- U --- U --- U --- U 64, Acetonitrile 36,29 55v00D --- V --- D --- U --- V --- U 0,39 1.000 --- U 122,00 27.90 --- V 23.10 65, Tetrahydrofuran 66, 1,4-Dioxane 2,71 3.000 4,39 --- U 129.00 --- U 326,00 S = Setlmated value between the NDL and MRL, U HeLow ALL Cuentltation L1mitB. Environment 1, Incorporated Drinking Water ID: 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 ENE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DRe STE 100 DATE COLLECTED: 12/11/19 DURHAMp NC 27703 DATE REPORTED: 02/07/20 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PARAMSTERS, ug/l Date MDL Analyzed MRL 12/18/19 MW-3D 12/10/19 MW-3A 12/18/19 Trip Blank 1, Chloromethane 0,77 3,000 --- V --- U --- U 2, Vinyl Chloride 0,12 0.200 --- U --- U --- U 3, Bromomethane 0.67 10.000 M. V --- V --- U 4, Chloroethane 0,48 10,000 --- U --- U -'- U 5. Trichlorofluoromethane 0.24 1.000 --- U --- D --- U 6. 1,1-Dichloroethene 0.17 5.000 --- U --• U --- U 7, Acetone 9.06 100.000 --- U 11,20 J --- U 8, Iodomethane 0,26 30.000 --- U --- V --- V 9, Carbon Disulfide 0,23 100,000 --- u --- U --- U 10. Methylene Chloride 0.64 1.000 --- U --- U --- U 11, trans-1,2-Dichloroethene 0,23 5.000 --- U --- U --- V 12. 1,1-Dichloroethane 0,20 5.000 --- u --- V --- U 13, Vinyl Acetate 0.20 50,000 --- u --- U --- U 14, Cie-1,2-Dichloroethene 0.25 5,000 --- U --- V --- U 15, 2-Butanons 2.21 1004000 --- V --- U --- 16. Bromochloromethans 0627 3,000 --- U --- U --- V 17. Chloroform 0.25 5.000 --- u --' U --- U 18, 11111-Trichloroethane 0.19 1.000 --- U --- U --- U 19, Carbon Tetrachloride 0,04 0,200 --- V -•- U --- U 20, Benzene 0,24 1.000 --- V 1,49 --- U 21. 112-Dichloroethane 0,02 0,200 --- U --- U --- U 22, Trichloroethane 0.23 1.000 --- U --- U --- U 23. 1,2-Dichloropropane 0.04 0,200 --- U --- V --- V 24, eromodichloromethane 0.04 0,200 --- U --- U --- U 25. Cie-1,3-1pichloropropane 0.06 0.200 --- U --- U --- U 26. 4-Nethyl-2-Pentanone 1.19 1009000 --- U --- U --- U 27, Toluene 0,23 1.000 --- U --' U --- U 28, trans-1,3-Dichloropropane 0,04 0.200 --- U U --- U 29. 1,1,2-Trichloroethane 0.03 0,200 --- U •-- U --- U 30. Tetrachloroethens 0.30 0,200 --- U --- U --- V 31, 2-Rexanone 1.57 50,000 --- V --- U --- V 32. Dlbromoc hloromethane 0.03 0.200 --- V U --- U 33, 1,2-Dibromoethane 0.03 0,200 --- U --- V --- U 34, Chlorobenzene 0.30 3.000 --- U --- U --- 0 35. 1,1,1,2-Tetrachloroethans P.22 1.000 --- V --- U --- V 36. Ethylbenzens 0,21 1.000 --- U --- U --- V 37. Sylenes 0.68 5.000 --- U --- U --- U 38. Dlbromomethane 0.28 30.000 ___ U -__ U ___ U 39. Styrene 0.19 1.000 --- U --- U --- u 40, Bromoform 0.20 3.000 --- U --- U --- V 41. 1,1,2,2-Tetrachloroethane 0,03 0,200 --- U 0.19 a --- U 42. 1,2,3-Trichloropropane 0.09 0.200 --- V --- U --- U 43, 1,4-Dichlorobenzens 0.39 1,000 --- U --- U --- U 44, 1,2-Dichlorobenzene 0.32 5.000 --- V --- U --- U 45. 1,2-Dibromo-3-Chloropropane 0,07 0.200 --• V --- U --- V 46, Aorylonitrile 2,72 200,000 --- V --- U --- U 47. trans-1,4-Dichloro-2-Butane 0,42 100,000 --- U --- U --- u g v Estimated value between the MOL and MRL, V a Below ALL Quantltation Limits. Page: 3 Environment 1, �d Drinking Water IDI 37715 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 ENE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 Page: 4 DURHAM, NC 27703 DATE REPORTED: 02/07/20 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 82601) R4(18) PARAMETERS, ug/l Date NDL Analysed MRL 12/10/19 NW-3D 12/19/19 HW-3A 12/18/19 Trip Blank 48, Acrolein 1.97 4,000 --- U --- U --- u 49, Allyl Chloride 0,20 10,000 --- U --- v --- u 50, Chloroprene 0,21 20,000 --- U --- u --- u 51, 1,3-Dichlorobenaene 0.41 5,000 --- V --- u --- v 52. Dlchlorodifluoromethane 0.51 5.D00 --- u --- U •-- u 53. 1,3-Dichloropropane 0,28 1.000 --- u --- U --- U 54. 2,2-Dichloropropane 0,17 15,000 --- u --- U --- u 55. 1,1-Dichloropropane 0,22 56000 --- U --- U --- u 56, Ethyl Mathacrylate 0.16 10.000 --- u --- V --- u 57, Hexachlorabutadiene 0.10 0.200 --- u --- u --- U 58. Isobutyl Alcohol 12,80 100,000 --- u --- u --- u 59, Methacrylonitrils 1,93 100,000 --- U --- u --- u 60. Methyl Mathacrylate 0,25 30,000 --- u --- u --- u 61, Naphthalene 0,47 6.000 --- U --- u --- V 62. Propionitrile 3,26 150.000 --- u --- U --- V 63. 1,2,4-Trichlorobenaene 0,50 10.00D --- u --- u --- u 64, Acetonitrlle 36,29 55.000 --- u --- u --- V 65, Tetrahydrofuran 0.39 1.000 --- U 20,50 --- u 66, IADioxane 2,71 3.000 --- U 257.00 --- v S EeCSmdted value between the MDL and MRL, v e Below ALL Quantit ration Limits. \� \ � \ ( \ \/ � \ T «ems sy«LECI }perature A._m_m EA8 tt / f § ) / 3 � � ■ � § OD App •, ° A AAMEAs 7 g \ � z L aw ` m � \ \ \ \ � � \ � 9 o, D c 1 cn 9 T N Z W > O A n Q . D y C m � 7��7yn n7 3 CD rn c r pw v O O O S O O G 3 TOTAL CHLORINE, mg1l L L C7 m m 0 OR ug/I AT COLLECTION ON TEMPERATURE,°C O < x ATCOLLECTION m o H o Q gOFCONTAINERS m z 0 8260D App. II 2 \ ? 8260D App. II 3 -? 8260D App. II 4 Z .. 0 «; 8151A Landfill Y .. ... ... ... ... ... lA Du 0 815 licate p ➢ ORP ro mm' \ m ... .... _. .. ... ... w m O m � Cl w o v < o w � 0 o V` m w m w � C S 0 PARAMETERS TESTS n n v � D 2 1�j f=il � n as m N N O O � C7 m D D Z C0J z i� N _ = z m m n m O z v� z O x z m cci� p m z y my m m m 0 z n n m m IZC 0 3 m Z m. T G) m m 0 m N Z �] CO Z m m -%D_+ D Z n p V m + w z o n m z O ➢ z O Ul _ G D a om C ➢ O `` z m m O27 o O 0 m = Environment 1, Inco GREENVILLE, N.C. 2fOUO CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS 6003 A JP 12/11/19 12/17/19 - 12/18/19 02/21/20 PARAMETERS, ug/1 hIDL MRL Concentration 1, Chloromethane 0,77 3,00 -- U 2. Vinyl Chloride 0,12 0.20 --- U 3. Bromomethane 0.67 10.00 - D 4. Chloroethane 0,48 10.00 -- U Be Trichlorofluoromethane 0,24 1,00 - U 6. 1,1-Dichloroethene 0.17 5.00 --- U 7. Acetone 9.06 100.00 -- U 8, Iodomethane 0.26 10,00 -- U 9. Carbon Disulfide 0.23 100.00 - U 10, Methylene Chloride 0,64 1,00 --- U 11. trans-1,2-Dichloroethene 0,23 5,00 --- U 12. 1,1-Dichloroethane 0,20 5.00 --- U 13. Vinyl Acetate 0920 50.00 --- U 14. cis-1,2-Dichloroethene 0.25 5,00 --- U 15. 2-Butanone 2.21 100,00 -- U 16. Bromochloromethane 0.27 3.00 -- U 17. Chloroform 0,25 5.00 - U 18. 1,1,1-Trichloroethane 0.19 1.00 --- U 19, Carbon Tetrachloride 0.04 1 0.20 -- U 20, Benzene 0,24 1.00 - U 21. 1,2-Dichloroethane 0,02 0,20 --- U 22. Trichloroethene 0.23 1.00 - - U 23. 1,2-Dichloropropane 0,04 0,20 --- U 24. Bromodichloromethane 0,04 0.20 - U 25, cis-1,3-Dichloropropene 0.06 0,20 --- U 26. 4-methyl-2-Pentanone 1.19 100.00 --- U 27, Toluene 0,23 1.00 - U 28. trans-1,3-Diohloropropene 0.04 0.20 --- U 29. 1,1,2-Trichloroethane 0,03 0.20 --- U 30. Tetrachloroethene 0.10 0.20 - U 31. 2-Hexanone 1.57 40,00 - U 32, Dibromochloromethane 0.03 0,20 - U 33. 1,2-Dibromoethans 0.03 0.20 --- U 34. Chlorobenzene 0.30 3.00 - U 35. 1,1,1,2-Tetrachloroethane 0.22 1.00 --- U 36. Ethylbenzene 0,21 1,00 --- U 37, Xylenes 0,68 5.00 --- U 38. Dibromomethane 0,28 10.00 -- U 39, Styrene 0,19 1.00 --- U 40. Bromoform 0.20 3,00 - U 41. 1,1,2,2-Tetrachloroethane 0,03 0,20 --- U 42. 1,2,3-Trichloropropane 0,09 0,20 --- U 43. 1,4-Dichlorobenzene 0.39 1.00 --- U 44. 1,2-Dichlorobenzene 0.32 5.00 --- U 45. 1,2-Dibromo-3-Chloropropane 0.07 0.20 --- U 46. Acrylonitrile 2,72 200.00 --- U 47, trans-1,4-Dichloro-2-Butene 0.42 100.00 1 --- U 48, Acrolein 1,97 4.00 - U 49. Allyl Chloride 0:20 10.00 --- U 50. Chloroprene 0.21 20,00 --- U Environment 11 GREENVILLCI N.C. 41DUO CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: i REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS (continued) 6003 A JP 12/11/19 12/17/19 - 12/18/19 02/07/20 PARAMETERS, ug/1 MOL MRL Concentration 51. 1,3-Dichlorobenzene 0.41 5.00 --- U 52. Dichlorodifluoromethane 0.51 5.00 --- U 53. 1,3-Dichloropropane 0.28 1.00 --- U 54, 2,2-Dichloropropane 0,17 15.00 --- U 55. 1,1-Dichloropropane 0.22 5,00 --- U 56, Ethyl Methacrylate 0,16 10.00 --- U 57. Hexachlorobutadiene 0.10 0,20 --- U 58, Isobutyl Alcohol 12,80 100,00 --- U 59. Methacrylonitrile 1.93 100,00 --- U 60, Methyl Methacrylate 0,25 30,00 --- U 61, Naphthalene 0.47 6.00 --- U 62, Propionitrile 3,26 150:00 --- U 63. 1,2,4-Trichlorobenzene 0.50 50.00 --- U 64, Acetonitrile 36,29 55,00 - U 65, Tetrahydrofuran 0.39 1900 --- U 66. 114-Dioxane 2.71 3,00 --- U Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 ENE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE ANALYZED: 12/20/19 - 12/21/19 DATE REPORTED: 02/21/20 REVIEWED BY: zz VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS PARAMETERS, ug/1 hIDL MRL Concentration 1. Chloromethane 0,77 3,00 --- U 2. Vinyl Chloride 0.12 0.20 --- U 3. Bromomethane 0,67 10.00 --- U ----------------------- 4. Chloroethene 0.48 10.00 --- U S. Trichlorofluoromethane 0,24 1.00 --- U 6, 1,1-Dichloroethene 0,17 5.00 --- U 7. Acetone 9.06 100.00 --- U S. Iodomethane 0,26 10,00 --- U 9, Carbon Disulfide 0,23 100,00 --- U 10, Methylene Chloride 0,64 1.00 --- U 11. trans-1,2-Dichloroethene 0.23 5.00 --- U 12. 1,1-Dichloroethene 0.20 5,00 --- U 13. Vinyl Acetate 0,20 50..00 --- U 14. cis-1,2-Dichloroethene 0.25 5,00 --- U 15, 2-Butanone 2,21 100.00 --- U 16. Bromochloromethane 0.27 3,00 --- U 17. Chloroform 0.25 5.00 --- U 18, 1,1,1-Trichloroethane 0,19 1.00 --- U 19. Carbon Tetrachloride 0.04 0,20 --- U 20. Benzene 0,24 1.00 --- U 21, 1,2-Dichloroethane 0.02 0,20 --- U 22, Trichloroethene 0.23 1,00 -- U 23, 1,2-Dichloropropane 0,04 0,20 --- U 24. Bromodichloromethane 0.04 0.20 --- U 25. cia-1,3-Dichloropropane 0,06 0.20 --- U 26. 4-methyl-2-Pentanone 1.19 100.00 --- U 27, Toluene 0,23 1,00 --- U 28. tran9-1,3-Dichloropropane 0.04 0,20 --- U 29. 1,1,2-Trichloroethane 0.03 0,20 --- U 30. Tetrachloroethene 0.10 0.20 --- U 31. 2-Hexanone 1.57 40.00 --- U 32, Dibromochloromethane 0.03 0,20 - U 33, 1,2-Dihromoethane 0,03 0,20 --- U 34. Chlorobenzene 0.30 3.00 --- U 35. 1,1,1,2-Tetraohloroethane 0..22 1.00 --- U 36. Ethylbenzene 0.21 1.00 --- U 37, Xylenes 0.68 5.00 --- U 36, Dibromomethane 0,28 10,00 --- U 39, Styrene 0.19 1.00 --- U 40, Bromoform 0,20 3.00 - U 41. 1,1,2,2-Tetrachloroethene 0.03 0.20 --- U 42. 1,2,3-Trichloropropane 0.09 0,20 --- U 43, 1,4-Dichlorobenzene 0,39 1.D0 --- U 44. 1,2-Dichlorobenzene 0.32 5.00 --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0.20 --- U 46. Acrylonitrile 2.72 200.00 --- U 4-Dichloro-2-Butene 0.42 U47 Arle 1.97.al, 4.00 --- U 49. 020 10,00 U n 50Chloropree 0.21 20,00 --- U Environment 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) A4EC POSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: ANALYST; DATE COLLECTED: DATE ANALYZED: DATE REPORTED: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS (continued) PHONE (252) 756-6208 FAX (252) 756-0633 6003 A JP 12/11/19 12/20/19 - 12/21/19 02/07/20 pARAMETER9, ug/1 AIDL MRL Concentration 51, 1,3-Dichlorobenzene 0,41 5.00 --- U 52. Dichlorodifluoromethane 0,51 5.00 --- U 53, 1,3-Dichloropropane 0.28 1,00 --- U 54, 2,2-Dichloropropane 0,17 15,00 --- U 55. 1,1-Dichloropropane 0.22 5,00 --- U 56. Ethyl Methacrylate 0,16 10,00 --- U 57. Hexachlorobutadiene 0,10 0.20 --- U 58. Isobutyl Alcohol 12.80 100,00 --- U 59. Methacrylonitrile 1.93 100.00 --- U 60. Methyl Methacrylate 0,25 30.00 --- U 61. Naphthalene 0,47 6.00 --- U 62, Propionitrile 3.26 150.00 --- U 63. 1,2,4-Trichlorobenzene 0.50 50.00 --- U 64. Acetonitrile 36,29 55.00 --- U 65, Tetrahydrofuran 0.39 1.00 --- U 66, 1,4-Dioxane 2,71 3.00 --- U Environment 1, Inco 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHUR3T (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: e� CLIENT ID: 6003 A ANALYST: JP DATE COLLECTED: 12/11/19 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 VOLATILE ORGANICS EPA METHOD 8260D R4 (18) SURROGATE RECOVERY RESULTS Sample Name Limits ($ recovery) 1,2-DCA-d4 ($ recovery) Toluene-d8 ($ recovery) 4-BFB ($ recovery) Continuing Calibration std. Method Blank 70-130 70-130 100 102 100 102 101 101 MW-1S 70-130 105 101 101 MW-2S 70-130 106 102 102 MW-2D 70-130 105 100 101 MW-3S 70-130 106 101 102 MW-3D 70-130 106 102 102 MW-3A 70-130 106 101 103 Txip blank 6003 MW-13 M.S. 70-130 70-130 101 99.1 102 98.4 101 98.2 6003 MW-IS M.S.D. 70-130 99,4 98.6 99.8 Environment 1, Incorporated GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: L % oe �. CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) SURROGATE RECOVERY RESULTS PHONE (252) 756-u2vu FAX (252) 756-0633 6003 A JP 12/11/19 12/20/19 - 12/21/19 02/21/20 Sample Name Limite (8 recovery) 1,2-DCA-d4 (8 recovery) Toluene-d8 (& recovery) 4-HFB (B recovery) Continuing Calibration std. 70-130 98.3 99.1 100 Method Blank 70-130 106 101 MW-ID 70-130 105 105 101 6003 SW-4 M.S. 70-130 106 107 102 6003 SW-4 M.S,D. 70-130 96.9 99.8 101 Environment 1, 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 A AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/11/19 DURHAM, NC 27703 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS Sample Spiked: (6003) Mw-lS Spike Amount Ug/l Sample Result Ug/1 Spikes Result Ug/l Spike Recovery (70-130%) Spike Dup. Result Ug/l Spike Dup. Recovery (70-130%) MS/MSD RPD (20&) 1,1-Dichloroethene 2060 --- U 21.33 107 21,60 108 1.3 Benzene 20.0 -- U 22,04 110 22,68 113 2.9 Trichloroethene 20.0 -- U 22.02 110 22.84 114 3.7 Toluene 20.0 -- U 21.47 107 22.48 112 4.6 Chlorobenzene 20..0 - U 20.83 104 21,76 109 4.4 LAEORATORY CONTROL SAMPLE RE 3ULTS Sample Compound; Spike Amount Ug/l Spike Result Ug/1 Spike Recovery (70-130%) 1,1-Dichloroethene 20,00 20.83 104 Benzene 20.00 20,49 102 Trichloroethene 20,00 20.83 104 Toluene 20,00 21.02 105 Chlorobenzene 20.00 2FO,44 102 Environment 1(Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C 6D LANDFILL) CLIENT ID: AMEC FOSTER WHEELER ENVIRONMENT 6 INFRASTRUCTURE ANALYST: 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: DURHAM, NC 27703 DATE ANALYZED: DATE REPORTED: REVIEWED BY: 4 VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS FAX k2j 756-0633 6003 A JP 12/11/19 12/20/19 - 12/21/19 02/21/20 Sample Spiked: (6003) SW-4 Spike Amount Ug/1 Sample Result Ug/1 Spike Result Ug/1 Spike Recovery (70-130%) Spike Dup. Result Ug/1 Spike Dup. Recovery (70-130%) MS/MSD RPD (20%) 1,1-Dichloroethene 20.0 - U 20.25 101 23,32 117 14.1 Benzene 20.0 -- U 19.07 95.4 22,48 112 16.4 Trichloroethene 20.0 -- U 18,74 93.7 22,67 113 19.0 Toluene 20.0 -- U 18.90 94.5 22.50 113 17.4 Chlorobenzene 20.0 - U 18.66 93.3 22.01 110 16.5 LABORATORY CONTROL SAMPLE RESULTS Sample Compound: Spike Amourtt Ug/l Spike Result Ug/1 Spike Re00veiy (70-13094) 1,1-Dichloroethene 20.00 19.63 98.2 Benzene 20.00 19,93 99.7 Trichloroethene 20,00 20.40 102 Toluene 20.00 20.27 101 Chlorobenzene 20.00 19.94 99.7 Environment 1, Incorporated 114 CAKMONT GREENVILLE, N.C. 27858 FAX (252) 756-0633 ID#: 6003 B JUDSON WHITEHURST (C&D LANDFILL) AMEC POSTER WHEELER ENVIRONMENT19 0 & INFRASTRUCTURE DATE COLLECTED: 2/ 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED 2/21//20 DURHAM INC 27703 REVIEWED BY: MW-9A MW-1D MW-11 MW-13 MW-12B Analysis Method Date Analyst Code PARAMETERS MDL MAL PH (field m eu a ant), Unite 7.1 6.6 6.7 6,4 6.7 12/12/19 BY 4500HB-11 Nitrate Nitrogen as N, mg/l 0.009 0.04 --- V --- U --- V loll - U 12/13/19 AKB 353*2 R2-9 Alkalinity (to BE 9.5), mg CaCO3/1 1.0 1.0 198 1D90 828 U 19D U 1580 U 12/18/19 SSJ 4500CNS111 Cyanide, ug/l 5.0 5.0 --- V --- U Sulfate, mg/3 5.0 5.0 107 45.2 197 124 5.4 11/16/19 88J 9500804281 Antimony, ug/l 0,03 1.0 0.05J 0.18 J 0,36 J 0111 J 0,31 J 02/03/20 NAB EPA200.8 Arsenic, ug/1 0,08 5.0 --- U 5.5 4.6J - V 29 02/19/20 NAB EPA200.8 0.32 300 62 267 131 77 589 01/17/20 LFJ HPA200.7 . Barium, ug/1 - --- U 01/03/2D NAB BPA20068 Beryllium, ug/l 0,02 140 --- U 0,02 J 0,04 J - - O Cadmium, ug/1 0,04 1.0 --- U 0.05 J --- U --- U - U 02/19/20 NAB SPA200,8 0,02 1.0 0051 J 2,6 2.4 0.49a 303 02/03/20 NAB EPA200.0 Cobalt, u9/1 Total Chromium, ug/l 0o12 Soo --- u 21 --- U - 44 01/07/20 NAB SPA200.8 V copper, u9/3 1,47 10.0 2 J 5 J 2 J --- U 3 J 01/17/20 LPJ BPA200.7 327 24410 577 1710 01/31/20 NAB 3111E-11 Iran, ug/1 12.08 50.0 3528 Manganese, ug/1 0.31 10.0 250 150 418 25 570 02/03/20 LPJ 8PA200,7 Lead, ug/1 0,03 5.0 0.06 J 0.05 J 0.05 J 0.16 J V 0 12/26/19 HIM 245,1R3-9 Mercury, ug/1 D.05 0,20 --- V D.05 J --- U 01/09/20 HIM 245.1 R3-9 Mercury, ug/1 0.05 0.20 -- U --- U Nickel, ug/l 0.03 10.0 5.2 J 18.0 14*6 8.2J 14.7 02/03/20 NAB HPA200.8 0.05 10.0 0*62 J 714J 3.5J 1.4a 16 02/04/20 NAB SPA200.8 selenium, ug/1 -- U 02/03/20 NAB UPA200.8 Silveri ug/1 0.22 5.0 --- V U U Thallium, USA 042 1.0 0,06 J 0.05 J 0,02 J 0,04 J -- U 02/04/20 NAB SPA200.8 Tin, ug/l 0405 100*0 0.16 J --- U 0.19 J --1U 0.460 J 02/03/20 NAB EPA20OPS 02/03/20 LPJ EPA200.7 Vanadium, ug/l 0.20 1.0 1 11 3 zinc, ug/l 1.10 10.0 8 J 6 J 1.4J 7 J - 8 J 02/03/20 LPJ SPA200.7 sulfide, ug/1 100 1000 -- U 849 J --- U 592 J -- U 12/16/19 LPJ 4500S2D-11 Conductivity (at 250), uMhes/cm 1.0 1.0 653 2526 1743 609 3956 11/12/19 PJC 1530B-11 Dissolved Oxygen, mg/l 0.1 0.1 0.99 2*24 0.29 0*40 1.06 12/12/19 PJC 450000-11 Tempe rnture, °C 14 14 11 17 14 12/12/19 BP 2550E-10 Static Water Level, feat 5*96 3,82 3,62 9,75 5,26 12/12/19 BY 23*17 22,73 23,84 20,68 22,93 12/12/19 BP Well Depth, feet +55 +119 +87 +49 +123 12/12/19 HP 1580E-11 OAP, m" Turbidity (Field), NTU 140 1.0 7424 7,82 7,55 6,88 1.74 32 /12/19 HP 1130B-11 J 8etlmated value between the MDL and MRL, U e Below ALL Quantlt atlon Limlte. Environment 1, Incorporated GREENVILLE, N.C. 27858 t9aat&water IDi 10 PHONE (252) 756-6206 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 H AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/18/19 DATE ANALYZED: 01/04/20 REVIEWED BY: DATE REPORTED: 02/21/20 PESTICIDES AND PCB'S F.Da MR.TUnn An RlA R2t071 PARAMSTERB, u911 HDL MRL MH-9A MW-10 MN-31 Mw-13 MN-12e 1, Aldrin 0,029 00050 --- U --- U --- U --- U --- u 2. Alpha-BHC 0,032 01050 --- U --• U --- V --- U --- V 3. Beta -HNC 0,031 0,050 --- U --- U --- U --- U M. U 0,030 00050 --- U --- U --- U --- U --- U 4, Delta-BHC 5. Gamma-BHC (Llndane) 0.032 01050 --- U --- U --- U --- U --- U 6, Chlordane 04320 0,500 +-- U --- U --- U --- U --- V 7, 4,4-DDD 0.051 0,300 --- U --- V --- U --- V --- U 8, 404-DDB 0,049 0.100 --- U --- U --- U --- U --- U 9. 4,4-DDT 0.052 0.300 --- ❑ --- U --- U --- U --- V 10, Dieldrin 0,042 0.075 --- U --- V --- U --- U --- U 11, Endoeulfan I 0.056 0.100 --- U --- V --- U --- U --- U 12. Endoeulfan II 0,046 0.100 --- U --- U -•. U --- U -'- U 13. Endoeulfan Sulfate 0,072 0.100 --- V --- V --- U --- V --- U 14, Sndrin 0.053 0.100 --- U '-- U --- U ... U -- U 15, Endrin Aldehyde 0.06E 0.100 --- U --- U --- U --- U --- U 16, Heptachlor 0,039 0.050 --- U --- U --- V --- U --- U 17. Heptachlor Spoxlde 0,042 0.075 --- U --- U --- U --- U --- U 18, Methoxychlor 0,530 1.000 --- U --- U --- U --- U --- U 19, Pob's (AroclOre) 0.500 2.000 --- V --- U --- V --- U --- U 20, Toxaphene 01690 1,500 --- U •-- V --- U --- U --- U NOTE: EPA METHOD 8081B R2 (07): Final Continuing Calibration verification exceeded control limit for Heptachlor. This analyte was not detected in samples. Data not impacted. S = Estimated Value between the MDL and MRL, U Below ALL Quantitatlon Limits, Environment 1, Incorporated GREENVILLE, N.C. 41000 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT IA: 6003 H AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: HIC 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/19/19 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II n uvmvnn 91 S1 A R1 l9 A) Date Analyzed Ol/02/20 01/03/20 02/03/20 01/03/20 Ol/03/20 MW-9A MW-ID MW-11 MW-13 Mw-12e PARAMETERS, ug/1 MDL MRL 1, 2,4-D 0.36 2.011 --- V --- U --- U --- U --- U 2, Dinoeab 0.54 1.000 --- U --- U --- U V V 3, 2,415-TP 0,42 2,000 --- U --- V --- V --- U --- U 4. 2,4,5-T 0.49 2,000 ___ D _-- U __. U ___ U ___ U J eetlmatad value between Cha MDL and MRL, U Below ALL Vuantitation Llm lte, Environment 1, Incorporated I I4 OAKMONT DRIVE GREENVILLE, N.C. 27858 wastewater IDi 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/21/20 REVIEWED BY: SEMI -VOLATILE ORGANICS PDA MPTRf373 M27nR RfifiBl Page: 1 PARAMETERS, ug/1 Date MDL Analyzed MRL 01/23/20 MW-9A 01/23/20 MW-10 12/28/19 NW-11 12/28/19 MW-13 12/2B/19 MW-12e 1. Acenaphthene 2.66 10,000 --- u --- U --- U --- U --- u 2. Acenaphthylene 2,60 10,000 --- U --- u --- U --- ❑ --- U 3, Anthracena 2.97 30.000 --- V --- U --- V U u 4. Benzo[alantrhacene 4,16 10.000 --- U --- u --- V --- u •-- u 5. Benzo[b)fluotanthene 3,32 10,000 --- V --- u --- U --- u --- U 6, Benzo[k)fluoranthene 4,23 10,000 --- U --- V --- U --- U -•- u 7. Benzo[9,h,1)perylene 2,61 10.000 --- u --- u --- u --- u --- u B. eenzo [al pyzene 3,27 10.000 --- U --- u --- U U --- V 9, 4-Bromophenyl Phenyl Ether 2,63 10.000 -•- V •-- U --- V --- V •-- u 10, Butyl Benzyl Phthalate 5.78 10,000 --- V --- u --- V --- u --- U 11, Bie(2-Chloroethoxy) Methane 3,14 10,000 --- u --- U --- u --- U --- U 12. Bie(2-Chloroethyl) Ether 2,59 10,000 --- U --- u --- u --- u --- u 13, Bis(2-Chloro-l-msthylethyl) Ether 2.58 10,000 --- u --- V --- U --- u --- u 14. 2-Chloronaphthalene 2,17 10,000 --- u --- V --- u --- u --- V l5. 4-Chlorophenyl Phenyl Ether 2,42 10,000 --- V --- U --- u --- V --- U 16. Chryeane 9.04 30.000 ___ U ___ u ___ u ___ V ___ u 17, Dibenzo[a,h)anthracene 2,78 10,000 --- V --- U --- u --- u --- V 18. Di-N-Butyl Phthalate 3,09 10,000 --- U --- V --- u --- u --- U 19. DSmethyl Phthalate 3,78 10.000 --- u --- V --- u --- U --- U 20. Diethyl Phthalate 3,92 10,000 --- U --- u --- u --- U --- V 21, 2,4-Dinitrotoluens 3,95 10,000 --- u --- V --- V --- u •-- V 22. 2,6-Dinitrotoluene 3,08 10.000 --- u --- u --- U --- V --- U 23, Di-N-Dotyl Phthalate 2.B1 10,000 --- U --- V --- U --- u --- U 24. Hie-(2-Ethylhexyl) Phthalate 9.97 15,000 --- U --- U --- V --- V -•- u 25, rluoranthene 3,92 10,000 -•- V --- U --- V --- ❑ --- u 26, Pluorene 2.95 10,000 --- V --- U --- u --- U --- u 27. Hexachlorobenzene 2,61 10,000 --- U --- U --- U --- V --- u 28. Haxachlorocyclopentadiene 4.16 10,000 --- u --- V --- V --- u --- V 29. Indsno[1,2,3-Cd]pyrene 2,91 10.000 --- u --- u --- u --- u --- U 30, Isophorone 3,74 10,000 --- U --- u --- u --- u --- u 31. Nitrobenzene 2,85 10.000 --- u --- u --- U --- V --- u 32. N-Nitroeodlmethylamine 4,25 10.OD0 --- u --- U --- U --- 0 --- V 33. N-Nitrosodiphenylamine 3.95 10,000 --- U --- U --- V --- U --- u 34. N-Nitrosodl-N-Propylamine 4.06 10,000 --- U --- u --- U --- U --- u 35, Phenanthrene 3.24 10.000 --- u •-- U --- u --- u --- V 36, Pyrene 3,63 10,000 --- V --- U --- U --- U •-- u 37. 4-Chloro-3-Methylphenol 3,79 20,000 --- U --- U --- U --- U --- u 38. 2-Chlorophenol 2.75 10,000 --- U --- U --- u --- u --- U 39, 0-Cresol 3,68 10.000 --- U --- u --- V --- u --- U 40, P-Cresol 4,12 10.000 --- u --- u --- U --- U --- u 41. 2,4-Diahlorophen0l 5.19 10,000 --- U --- V --- U --- u --- V 42. 2,6-➢iahlorophenol 4.89 10,000 --- u --- U --- U --- V --- u 43. 2,4-Dimethylphenol 3,21 10,000 --- V --- U --- a --- U --- U 44. 4,6-Dinitro-2-Methylphenol 4.77 50.000 --- U --- V --- u --- u --- U 45. 2,4-Dlnitrophenol 4.37 50.000 --- U --- V --- u --- V --- V 46, Ethyl Methaneeulfonate 5,26 20,000 --- u --- V --- u --- u •-- u 47, Methyl Methaneeulfonate 4.92 10.000 --- u --- V --- U •-- u --- U J Estimated value between the MDL and MRL, U Below ALL Quantltatlon Llmita. Environment 1, I [4 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: ANALYST: DATE COLLECTED: DATE EXTRACTED: RATE REPORTED: SEMI -VOLATILE ORGANICS FAX (252) 758-0833 6003 B JAP 12/12/19 Page: 2 12/16/19 02/21/20 PARANETERB, ug/l Date ML Analyzed MRL 01/23/20 MW-9A 01/23/20 NW-10 12/28/19 MW-11 12/28/19 NW-13 12/28 /19 MN-129 48. 2-Nitrophenol 3,64 10.000 --- U --- U --- U --- u --- U 49, 4-Nitrophenol 3,17 50.000 --- U --- U --- U --- U --- U 50. Pentachlorophenol 5,33 25.000 --- u --- U --- U --- U --- U 51, Phenol 1.86 10.000 --- U --- U --- u --- U •-- U 52. 2,3,4,6•Tetrachlorophenol 3,12 10,000 --- u --- U --- U •-- U --- U 53, 2,4,5-Trichlorophenol 4,17 10,000 --- U --- U --- U --- u --- u 54. 2,4,6-Trichlorophenol 3,84 10,000 --- U --- V --- U --- V --- U 55. Aoetophenone 2.89 10,000 --- U --- V --- U --- V --- V 56. 2-Acetylaminofluorene 3.98 20.000 --- U --- U --- U --- U --- u 57, 4-Aminabiphenyl 4,12 20.000 --- U --• U --- U --- U --- u 58, Banzyl Alcohol 4,47 20,000 --- U --- u --- U --- V --- 59. 4-Chloroanlline 3,36 20.000 --- U --- V --- U --- U --- V 60, Chlorobenzilate 5,12 10,000 --- u --- V --- U --- U --- u 61. Di 2.98 30.000 --- V --- V --- U U U 62. Bllate Dibenzofuran 4,28 10,000 --- u --- U --- U --- u --- U 63. 3,31-Dichlorobenzidine 4,22 20,000 --- u •-- U --- u --- V --- u 64, Dimethoate 3,98 20,000 --- U --- U M. U --- U --- V 65. P-Dimethylaminoazobenzene 2,89 10.000 --- U --- V --- U --- U --- V 66. 7,12-Dlmethylbenz[a]anthracene 5.26 10,000 --- U --- U --- U --- U --- u 67. 3,3-Dimethylbenaldlne 3,21 10.000 --- V --- U --- u --- U --- U 68, 1,3-Dinitrobenzene 2,99 20.000 --- V --- U --- U --- V --- V 69. Diphenylamine 5,10 10.000 --- U --- U •-- U --- U --- D 70. Diaulfoton 4.28 10.000 --- U --- D --- U --- U --- D 71, Famphur 3.98 20,000 --- U --- V --- V --- U --- U 72, Rexachloropropene 4,31 10,000 --- U --- U --- U --- U --- u 73. Ieoeafrole 2.88 10,000 --- U --- u --- U --- U --- u 74. Kepone 2,79 20.000 --- U --- u --- U --- V --- V 75, Methapyrilene 3,54 1009000 --- V --- U --- U --- V --- U 76. 3-Methyloholanthrene 4,21 MOOD --- U --- U --- U --- V --- U 77. 2-Methylnaphthalene 3,79 10,000 --- U --- V --- u --- V --- U 78, Methyl Parathion 4.32 10,000 --- U --- U --- U --- U --- u 79. m-Creeol 3.81 10,000 --- V --- U --- U --- U --- U 80, 1,4-11aphthoqulnone 4.00 10.000 --- U --- U --- U '-- V --- V el. 1-NaBAthylamine 5.61 10.000 --- u --• V --- U U --- u 82, 2-Naphthylamine 4,62 10.000 --- U --- V --- V --- U •-- U 83. 2-Nitroanlllne 3161 50,000 --- U --- U --- U --- V --- V 84, 3-Nitroaniline 4.81 50,000 --- V --- U --- U --- U --- u 85. 4-Nitrcaniline 4,22 20.000 --- U --- U --- V --- U --- U 86. 5-Nitro-O-Toluldlne 4.01 10.000 --- U --- u --- U --• V --- V 3.63 10,000 --- V --- U --- V --- U --- U 87, 88. N-Nitroeodi-n-butylamine N-Nitroeodlethylamine 3,93 20.000 --- U --- V --- V --- U --- u 89. N-Nltroeomethylethylamine 3.83 10,000 --- U --- V --- U --- U --- U 90, N-Nitroeopiperidlna 5.19 20,000 --- U --- U --- U --• U --- U 91, N-Nitroaopyrrolidfne 2,89 10,000 --- V --- U --- U --- V --- V 92, Parathion 3,12 10,000 --- V --- U --- U --- V --- U 93, Pentachlorobenzene 3,92 10.000 --- u --- U --- U --- V --- V 94. Pentachloronitrobenzene 3.71 20,000 --- U --- U --- V --- u --- u T Estimated Value between the MDL and MRL, V Below ALL Quantlt at ion Limits, Environment 1, Inco GREENVILLEI N.C. 27858 =b, PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR9 STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE EXTRACTED: 12/16/19 DATE REPORTED: 02/21/20 REVIEWED BY: SEMI -VOLATILE ORGANICS Diva aewmwnn A77nw R6 (1R) Page: 3 PARAMETERS, ug/l Date MDL Analyzed MEL 01/23/20 MW-9A 01/23/20 MW-10 12/28/19 Mw-ll 12/28/19 MW-13 12/2S/19 MW-12e 95, Phenaaetin 4,41 20,000 --• U --- U --- U •-- U --- U 96, 1,4-Banzenediamine 2.99 10,000 --- U --- U --- U --- U --- U 3,86 10,000 --- U --- U --- U --- U --• U 97, Phorate 98, Pronemide 3,69 10.000 ___ U ___ U ___ U ___ U ___ U 4.12 10.000 --- U --- U --- U --- U --- U 99, SaFrale 100. 1,2,4,5-Tatraohlorobenzene 5,01 10,000 --- U --- U --- U --- u --- U 101, Thionazin 4.62 20,000 --- U --- U --- U --- D --- U 102, 0-Toluidine 4,11 10,000 --- U --- U --- U --- U --- U 103, 1,3,5-Trinitrobenzene 3.98 104000 --- U --- U --- U --- U --- U 104. 0,0,0-Triethyl Phoephorothioate 3.61 10.000 --- U --- U --- U --- u "'" U 105. Hexachloroethane 1,49 10.000 --- U --- U --- U --- U --- U 306, Ieodrin 3.11 20,000 --- U --- U --- U --- U --- U J = Setimatad value between tha MDL and MRL, U Below ALL Quantltetlon Limlte. Environment 1f Incor GREENVILLE, N.C. 27858 Wastaweter IDt PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II 7Gmn od 17 al Page: 1 PARAMETERS, a9/1 MDL MRL MW-9A MW-10 MW-ll MW-13 MW-1Re 1, 2. 3, 4, 5, 6, 7, 9. 9, 10, 11, 12. 13, 14, 15, 16, 17, 18, 19. 20, 21. 22. 23. 24. 25. 26, 27. 28. 29, 30, 31. 32, 33. 34. 35. 36, 37, 38. 39, 40, 41, 42. 43, 44. 45. 46, 47. 48. Chloromethane Vinyl Chloride Bromomethane Chloroathane Trlchlorofluoromethane 1,1-Dichloroethena Acetone iodomethane Carbon Disulfide Methylene Chloride trans-112-Dichloroethene 1,1-Dichloroethans Vinyl Acetate Cie-1,2-Dichloroethene 2-Butanone Bromochloromethane Chloroform 1,1,1-Trichloroethane Carbon Tetrachloride Benzene 1,2-Dichloroethane Trichloroethane 1,2•Dichloropropane Bromodichloromethane Cie-1,3-Diahloropropene 4-Methyl-2-Pentanona Toluene Crane-1,3-Dichloropropene 1,1,2-Trichloroethane Tetrachloroathene 2-Eexanone Dibromochloromethane 1,2-Dibromoethane Chlorobenaene 1,1,1,2-Tetrachloraethane Ethylbenzene Xylenes Dibromomethane Styrene Bromoform 1,1,2,2-Tetrachloroethane 1,2,3-Trichloropropane 1,4-Dichlorobenzene 1,2•Dichlorobenzene 1,2-Dibromo-3-Chloropropane Acrylonitrile trans-1,4-Diohloro-2-Butane Acrolein 0.77 0.12 0,67 0,49 0,24 0.17 9.06 0.26 0,23 0,64 0,23 0,20 0.20 0.25 2,21 0,27 0,25 0.19 0,04 0.24 0,02 0,23 0.04 0.04 0.06 1,19 0,23 0.04 0.03 0.30 1,57 0,03 0,03 0,30 0.22 0.21 0.68 0.28 0.19 0.20 0,03 0.09 0,39 0,32 0,07 2.72 0,42 1.97 3.000 0,200 10,000 10,000 1.000 5.000 100,000 10,000 100.000 1.000 5.000 5.000 50,000 5,000 100,000 3,000 5.000 1,000 0,200 1.000 0,200 1,000 0,200 0.200 0,200 100,000 1.000 0.200 0,200 0,200 50,000 0.200 B.2BJ 3,000 1.000 1.000 5.000 10.000 1,000 3,000 0,200 0,200 1.000 5.000 0,200 200.000 100,000 9.000 --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- v --- U --- V --- U --- U --- U --- U --- U --- U --- U --• U --- U --- U --- U ___ U --- U --• U --- U --- U --- U --- U --- U --- U --- U --- U --- U --- V --- 0.33 --- --- --- --- --- --- --- M. --- •-- --- --- --- --- --- --- '-- 1.28 0.21 --- 0.08 --- --• --- 0,37 --- --- --- --- --- --- --- --- ___ --- --- --- -"" --- -'" --- --- --- --- --- ___ U U U U U U U U U U U U U U U U U U U J U U U J U U U U U U U u U U U U U U U U U U U U V --- 0,57 --- --- --- --- 12,30 --- --" --- --- --- --- 0.52 --- --- --- --- _-- 2,56 0.27 --- 0.15 --- --- --- 0,26 --- --- --- --- --- --- --- -"" ___ --- --- --- --" 0,04 --- --- --- --- --- --- ___ U U U U U J U U U U U U J U U U V U U J U U U J v U U V U v v U U U U U V J U U U U U U U --- U --- v --- U --- U --- U --- U --- U --- U '"" U --- U --- U --- U --- V --- V --- U --- U --- U --- U --- U --- U --- U - U --- U --- u --- U --- v --- U --- U --- U --- U --- U --- V --- U --- U --- U ___ U --• v --- U --- U -•- U --- U - U --- U --- V --- v --- U ___ U --- 1,25 --- --- --- --- 12,70 --- - --- --- --- --- 0.34 --- -•- --- -•- --- 2.12 0,15 0.08 --- --- --- 0.50 •-- --- --- --- --- --- --- - --- --- 0,07 0.50 --- _._ U U U U U J U U U U U u J v U U U U J U J U U U J U U U U U U U U U u J u J U U J Eetimatad value between the MDL and MAL, U Below ALL quantit ation Limits. Environment 1, Incorporated GREENVILLEI N.C. 27858 Wa ate Water ID, 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 7703 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II RPA METHOD 8260D R4(18) Page: 2 PARAMETERS, ug/1 MDL MEL MW-9A MW-10 MW-11 MW-13 Mw-laa 49. Allyl Chloride 0.20 10.000 --- u --- U --- U --- U --- U 50. Chloroprene 0.21 20.000 --- V --- U --- V --- u --- U 51. 1,3-Diohlorobenzene 0.41 5.000 --- U --- U --- U --- U --- u 52. Dichlorodl[luoromethane 0.51 5.000 --- U --- U --- V --- V --- U 53, 10-Dichloropropane 0.2E 1.000 --- U --- U --- U --- U --- U 54. 2,2-Dichloropropane 0.17 15.000 --- U --- V --- u --- U --- U 55, 1,1-Dichloropropane 0.22 5.000 --- U -•- U --- V --- U --- U 56, Ethyl Methacrylate 0.16 10.000 --- U --- U --- V --- U -'- V 57. Eexachlorobutadiena 0.10 0.200 --- U --- U --- U --- V --- U 58, Ieobutyl Alcohol 12.80 100,000 --- V --- V --- V --- U --- U 59, Methaczylonitrila 1.93 100.000 --- U --- U --- U U --- U 60. Nethyl Methacrylate 0.25 30.000 --- U --- U --- U --- V --- U 61, Naphthalene 0.47 6.ODO --- u 0.60 J --- V --- V 1.56 J 62, Proplonitrile 3.26 150,000 --- U --- U --- V --- U --- U 63, 1.2,4-Trichlorebenzene 0.50 10.000 --- U --- U --- U --- V --- V 64, Acatonitrlle 36*29 55.000 --- U --- U --- U --- V --- U 0.39 1.000 --- U 31.20 43.80 --- V 40.10 65, TetrahydroLuran 66. 1p4-Dioxane 2.71 3.000 --- u 10.5D 25.20 --• V 27.40 J Eetlmatad value between the NDL and NRL� U eeloW ALL Uuantitation Llmite. Environment 1, Incorporated 114 OAKMONT DRIVE rnvrv� GREENVILLE, N.C. 27858 FAX CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT TD: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR., STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/18/19 / DATE REPORTED: 02/21/20 REVIEWED BY: /(A LANDFILL APPENDIX II mvh momTmnD 9260D R4(18) PARAMETBRS, U9/l MDL MRL Trip Blank 14 00000- Chloromethane 0,77 3.000 --- V 2, Vinyl Chloride 0,12 0,200 --- U 3, Bromomethane 0,67 10,000 --- U 4, Chloroethane 0,48 10,000 --- V 5. Trichlorofluoromethane 0,24 1.000 --- U 64 1,1-Dichloroethene 0.17 5,000 --- U 7, Acetone 9.O6 1004000 --- V 8. Iodomethans 0426 10.000 --- U 9, Carbon DSaulfSde 0.23 100,000 •-- U 10, Methylene Chloride 0.64 1,000 --- U 11. trans-1,2-Dichloroethene 0,23 5.000 --- U 12. 1,1-Dichloroethane 0,20 5.000 --- V 13, Vinyl Acetate 0,20 50,000 --- U 14, Cie-1,2-Dichloroethene 0,25 5.000 --- V 15, 2-BUtanone 2.21 300,000 --- D 16, Bromochloromethane 0,27 3,000 --- U 17. Chloroform 0.25 5.000 --- V 18, 1,1,1-Trichloroethans 0,19 14000 --- V 19. Carbon Tetrachloride 0,04 04200 --- V 20, Benzene 0.24 1.000 --- V 21. 1,2-Dichloroethane 0,02 0,200 --- U 22, Trichloroethens 0,23 1.000 --- U 23, 1,2-Dichloropropane 0.04 0,200 --- U 24, Bromodichloromethane 0.04 0.200 --- U 25. Cie-1,3-Dichloropropene 0.06 0,200 --- U 26. 4-Methyl-2-Pentanons 1.19 100,000 --- V 27, Toluene 0,23 11000 --- U 28. trans-1,3-Dichloropropene 0.04 0,200 --- U 29. 1,1,2-Trichloroethane 0403 0,200 --- U 30, Tetrachloroethene 0.10 0.200 --- U 31. 2-ReXanone 1.57 50,000 --- U 32, Dibromochloromethane 0,03 0,200 --- D 33. 1,2-➢ibromoethane 0.03 0,200 --- U 34, Chlorobanzene 0,30 34000 --- U 35, 1,1,1,2-Tetrachloroethane o,22 1,000 --- U 36, Bthylbenzens 0,21 1,000 -•- U 37, Xylenes 0.68 5.000 --- U 38, Vlbromomethane 0,26 10,000 --- U 39, Styrene 0.19 11000 --- U 40, Bromoform 0,20 3.000 --- U 41, 1,1,2,2-Tetrachloroethane 0.03 0.200 --- V 42, 1,2,3-Trichloropropane 0.09 0.200 --- V 43. 1,4-Dichlorobanzene 0,39 1,000 -•- U 44, 1,2-Dichlorobanzene 0,32 56000 --- U 45, 1,2-Dibromo-3-Chloropropane 0,07 0,200 --- U 46. Acrylonitrile 2.72 200,000 --- U 47, trans-1,4-Dichloro-2-Butene 0,42 100,000 --- U 484 Acrolein 1,97 4.000 --- U 756-0633 Page: 3 3 8atimated value between the MDL and Matte V Below ALL DUantitatlon Limits. Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 wastewater ID, 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, 27703 DATE ANALYZED: 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PARAMETBRB, u9/1 MDL MAL Trip Blank 49. A11yl Chloride 0,20 10.000 --- U 50, Chloroprene 0.21 20.000 --- U 51. 1,3-Diohlorobenaene 0.41 5.000 --- U 52, DSchlorodiPluoromethane 0.51 5,000 --- U 53. 1,3-Dichloropropane 0.28 1.000 --- V 54, 2,2-DSchlaropropane 0,17 15,000 -•- U 55, 1,1-Dichloropropene 0.22 5,000 --- U 56, Ethyl Methacrylate 0.16 10.000 --- U 57. Hexachlorobutadiene 0.10 0.200 --- V 58. Ieobutyl Alcohol 12.B0 100,000 --- U 59, Methacrylonitrile 1,93 1004000 --- U 60, Methyl Methacrylate 0,25 30.000 --- V 61, Naphthalene 0.47 6,000 --- U 62, Propionitrile 3.26 150.000 --- V 63, 1,2,4-Trichlorobenaane 0.50 30.000 --- U 64, Acetonitrile 36.29 55,000 --- U 65, Tetrahydro8uran 0,39 1.000 --- U 66. 1,4-Dloxane 2,71 3,000 --- U Page: 4 S Eetlmated value between the MDL and MRL, U Below ALL puantitdtion Llmite. Z l0 W V Ol Ln mm FFFh (7 S 4; z z z v < owYo HrygOry hlz '� ry o Z x O C m ry o n '`'V-C- [[z�+1] G�77 y V m 0 0 m ],� < < o z wLi' to cw-i o v �rto �n � yy�d n 0D — n s Jn �. -f -.P N rn -ni C" ate. :rLo -LNe' Y m m x TOTAL CHLORINE, mg/1 l7 m m OR ug/I AT COLLECTION m < < < [ z TEMPERATURE,°C C r l _ ATCOLLECTION m o N N o a a a 4 OF CONTAINERS tr t'..; ` *: Field 'v ... .... ,.. pH Nitrate 9 ro ... ..: ... ... :.. Alkalinity ro .., _.. .. ,,. 777 Cyanide IF I ... ... .... .. > Sulfate 9 ro .:. ..:. .. .... ... Metals ro m m m w ' Sulfide .:.%F ,. .. ... .. p Conductivity 9 ro , DO y ro ... ... za . .... .. Temperature % ro .: ...'^; .... Field Parameter EPA 8270E Z ... .. ... ... .... 8270E Dup. 1 a ... .... ... .... .:. EPA 8081B 9 _ „_ 8081E Duplicaterb 9 G� 8260D App. II PARAMETERS/TESTS m po = _ = MIA_ w v M z p Ca n (� z m rn v' n m :;K r. m _F x x z x o p m m 1 o D y O o D m m m o rc r-ir o p m z T c) ?� m o 'm z Z{ > O n O z iv x z w m } D m D 1] O C) Ox Z D z O Chi p f4 m D O mm ~D F (IFV m P z D z f F mo 0 p n z O 31 N v m n m m 0 ti 0 0 L1] d ? 7 7 m tz m m2'2' n w to n O r iu00 PZ z m 4OOz `D e. O z C- o � W o v 7j z C Ij z v iIT 0 o'Jo is1 z JnH� v o 5"nUL < < < O O O IJ R0 w w coryryy� Z t w " I L) fib GJ xr�y �D o r_ R� y C - - -D-{{I„ay O m ml P m w m 6 } TOTAL CHLORINE, mg/I d OR ug/I AT COLLECTION m m m 2 C — TEMPERATURE,°C < m 0 0 0 ATCOLLECTION M 0 o n oo flOFCONTAINERS z 8260D App. 112 8260D App. II 3 O . 8260D App. II 4 '.4: 8151A Landfill ^ " ?:ssa>' 8151A Duplicate o o ORP 9 ro 1 m .. ,.. .. .. ... mm "V O M b PARAMETERS TESTS = o = x c D m m =IM o c? m D y m m umi -�„ A m Q z c> v� z O m D rr z C U> O C7 O Z D D m O D rn n� � m w m m s a z in N m m o O P o z T G) T m o C r-ir �� Li C) NN Z } 1 Om D D Cl Z N = Z ➢ T �D � z m o o m n m M F z z yIM m o O N iEnvironment 1, Inco �2 (@d l l4 OAKMONT DRIVE GREENVILLE, N.C. 27858 ENE ((252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 B AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS PARAMETERS, ug/1 MOL MRL Concentration 1, Chloromethane 0,77 3,00 -- U 2, Vinyl Chloride 0.12 0.20 --- U 3, BiamOmethane 0.67 10,00 --- U 4, Chloroethane 0,48 10.00 --- U 5, Triohlorofluoromethane 0.24 1..00 --- U 6. 1,1-Dichloroethene 0,17 5.00 --- U 7, Acetone 9.06 100.00 --- U 8, Iodomethane 0.26 10,00 --- U 9. Carbon Disulfide 0.23 100,00 --- U 10, Methylene Chloride 0.64 1.00 --- U 11. trans-1,2-Dichloroethene 0.23 5.00 --- U 12. 1,1-Dichloroethane 0.20 5.00 --- U 13. Vinyl Acetate 0,20 50.00 --- U 14. cis-1,2-Dichloroethene 0.25 5.00 --- U 15, 2-Hutanone 2,21 100,00 - U 16, Bromochloromethans 0.27 3,00 --- U 17. Chloroform 0,25 5,00 -- U 18, 1,1,1-Tsichloroethane 0.19 1.00 --- U 19. Carbon Tetrachloride 0.04 0,20 --- U 20, Benzene 0,24 1.00 --- U 21, 1,2-Dichloroethene 0.02 0,20 --- U 22, Trichloroethene 0,23 1.00 -- U 23. 1,2-Dichloropropane 0,04 0,20 --- U 24, Bromodichloromethane 0,04 0,20 -- U 25. cis-1,3-Dichloropropane 0,06 0.20 --- U 26, 4-methyl-2-Pentanone 1,19 500.00 --- U 27, Toluene 0,23 1.00 -- U 28, trans-1,3-Dichloropropene 0,04 0,20 --- U 29. 1,1,2-Trichloroethane 0,03 0,20 --- U 30, Tetrachloroethene 0,10 0.20 - - U 31, 2-Hexanone 1.57 40,00 - U 32, Dibromoohloromethane 0,03 0.20 -- U 33, 112-Dibromoethane 0.03 0.20 --- U 34, Chlorobenzene 0,30 3.00 --- U 35. 1,1-,1,2-Tatrachloroethane 0,22 1.00 --- U 36, Ethylbenzene 0,21 1.00 --- U 37, Xylenes 0,68 5,00 --- U 38, Dibromomethane 0.28 10,00 -- U 39, Styrene 0.19 1.00 --- U 40, Bromoform 0.20 3,00 -- U 41, 1,1,2,2-Tatrachloroethane 0,03 0,20 --- U 42. 1,2,3-Trichloropropane 0.09 0.20 --- U 43. 1,4-Dichlorobenzene 0.39 1.00 --- U 44. 1,2-Dichlorobenzene 0,32 5.00 --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0,20 --- U 46, Acrylonitrile 2,72 200,00 --- U 47. trans-1,4-Dichloro-2-Hutene 0,42 100.00 --- U 48, Acrolein 1,97 4.00 --- U 49, Allyl Chloride 0.20 10.00 --- U 50, Chloroprene 0,21 20.00 --- U Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED; DURHAM, NC 27703 DATE ANALYZED: DATE REPORTED: REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS (continued) PHONE (252) 756-6208 FAX (252) 75&0633 6003 B JP 12/12/19 12/17/19 - 12/18/19 02/07/20 PARAMETERS, 11g/1 MDL MRL Concentration 51. 1,3-Dichlorobenzene 0.41 5,00 --- U 52, Dichlorodifluoromethane 0.51 5.00 - U 53. 1,3-Dichloropropane 0,28 1.00 --- U 54, 2,2-Dichloropropane 0,17 15,00 --- U 55. 1,1-Dichloropropane 0,22 5,00 --- U 56, Ethyl Methacrylate 0.16 10.00 --- U 57, Hexachlorobutadiene 0.10 0,20 - U 58, Isobutyl Alcohol 12,80 100.00 --- U 59, Methacrylonitrile 1.93 100,00 --- U 60, Methyl Methacrylate 0,25 30,00 --- U 61. Naphthalene 0.47 6.00 --- U 62, Propionitrile 3.26 150.00 --- U 63. 1,2,4-Trichlorobenzene 0,50 10.00 --- U 64, Acetonitrile 36,29 55.00 - U 65. Tetrahydrofuran 0.39 1.00 --- U 66. 1,4-Dioxene 2.71 3,00 --- U Environment 1, �to GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) SURROGATE RECOVERY RESULTS Sample Name LiIDite (6 recovery) 1,2-DCA-d4 (8 recovery) Toluene -de (& recovery) 9-BFB recovery) Continuing Calibration std. 70-130 100 100 101 Method Blank 70-130 102 102 101 MW-9A 70-130 103 99.9 102 MR-10 70-130 105 101 103 MW-11 70-130 104 102 100 MW-13 70-130 103 100 101 MW-12S 70-130 104 102 104 Trip blank 70-130 104 101 100 6003 MW-lS M.S. 70-130 99.1 98.4 98.2 6003 MW-IS M.S.D. 70-130 99.4 98.6 99.8 Environment 1, Inco aNd 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 FAX (252) 756-0633 CLIENT; JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 8 AMC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/17/19 - 12/18/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS Sample Spiked: (6003) MW-1S Spike Amount Ug/1 Sample Result Ug/l Spike Result U9/1 Spike Recovery (70-130%) Spike Dup. Result Ug/1 Spike Dup. Recovery (70-1308) MS/M3D RPD (20%) 1,1-Dichloroethene 20.0 - U 21.33 107 21.60 108 1.3 Benzene 2040 - U 22.04 110 22.68 113 2.9 Trichloroethene 20.0 - U 22.02 110 22.84 114 3.7 Toluene 20.0 - U 21,47 107 22.48 112 4.6 Chlorobenzene 20.0 1 U 20.83 1,04 21.76 1 109 444 LABORATORY CONTROL SAMPLE RESULTS Sample Compound: Spike Amount Ug/1 Spike Result Ug/l Spike Recovery (70-130%) 1,1-Dichloroethene 20.00 20.83 104 Benzene 20.00 20.49 102 Trichloroethene 20.00 20.83 104 Toluene 20.00 21.02 105 Chlorobenzene 20,00 20.44 102 Environment 1, Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 ID#: 6003 C ti. PHONE (252) ,: FAX (252) 7W0633 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 12/12/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED : 02/20/20 DURHAM ,NC 27703 REVIEWED BY: SW-1 SW-2 SW-3 Bw-4 Analysis Method PARAMETERS MDL MRL Date Analyst Code PH (field measurement), Unite 6.9 6.6 6.0 6.8 12/12/19 BF 4500HB-11 Antimony, ug/l 0,03 1.0 0,40 J 0,05 J 0.09 J 0.04 J 02/03/20 NAB 8PA200.0 Arsenic, ug/1 0.08 5.0 30 --- U 2.3J --- U 02/19/20 NAB EPA200.0 Barium, ug/1 0,04 10.0 1725 155 02/12/20 LFJ EPA200.7 Barium, ug/l 0.04 10.0 48.4 60.0 02/03/20 NAB EPA200.B Beryllium, ug/1 0,02 1.0 1 --- U 0.28 J 0,06 J 02/03/20 NAB BPA200.8 Cadmium, ug/1 0.04 1.0 2 --- U 0.12 J --- U 02/19/20 NAB EPA200.8 Cobalt, ug/1 0,02 1.0 0.9 0.26 J 2.0 0,44 J 02/03/20 NAB EPA200.8 Total Chromium, ug/1 0.12 5.0 18 --- U --- D --- V 02/03/20 NAB 8PA200.8 Copper, ug/1 0.04 10.0 41 6.1J 8.4 J 4.99 02/04/20 NAB EPA200,8 Lead, ug/1 0,03 5.0 46 0.30 J 7.2 0,64 J 02/04/20 NAB BPA200.0 Nickel, ug/l 0603 10.0 13.7 1.2J 2.9J Ito 02/03/20 NAB EPA200t8 Selenium, ug/l 0.05 10.0 5.4J 0,54 J 0.99 J 0.26 J 02/04/20 NAB HPA200.0 Silver, ug/1 0,22 5.0 --- U --- U --- U --- U 02/03/20 NAB EPA200.0 Thallium, ug/1 0.02 1.0 0.46 J --- V 0.11 J 0,02 J 02/04/20 NAB BPA200.8 Vanadium, ug/1 0,20 1.0 84 0.9J 11 2 02/12/20 LPJ 8PA200.7 zinc, ug/1 0,17 10.0 202 4.2 J 31 3.0 J 02/04/20 NAB EPA200.8 Conductivity (at 250), uMhoe/cm 1.0 1.0 943 184 385 156 12/12/19 PJC 2510D-11 Temperature, °C 30 5 7 10 12/12/19 BF 2550B-1D Turbidity (Field), NTU 1.0 1.0 335 440 22.8 14.1 12/12/19 8P 2130E-11 J 8etimated value between the MDL end MRL, U Below ALL Quentitatlon Limits. Environment 1, Incorporated I1 OAKMONT DRIVE GREENVILLE, N.C. 27858 Wastewater IDi 10 PHONE (252) 756-6208 FAX (252) 756-0633 CLIENT: JUDSON WHITEHURST %U% LANDFILL) CLIENT ID: 6003 C AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 7703 DATE ANALYZED: 12/20/19 DATE REPORTED: 02/20/20 REVIEWED BY: VOLATILE ORGANICS APA METHOD 8260D R4(18) PARAMETERS, ug/l MDL MRL Sw-1 SW-2 Bw-3 SW-4 1, Chloromethane 0,77 3.000 --- U --- U --- U --- U 2. Vinyl Chloride 0,12 0.200 --- U --- V --- U --- U 3. Bromomethane 0,67 10.000 --- U --- V --- U --- V 4, Chloroethene 0.98 30.000 --- V --- U --- U --- U 5. Trichlorofluoromethane 0.24 1.000 --- U --- D --- U --- U 6. 1.1-Dichloroathene 0,17 5.000 --- U --- V --- U •-- V 7, Acetone 9,06 100,000 --- U --- V --- V --- U B. Iodomethane 0.26 10,000 --- U --- V --- V --- U 9, Carbon Dleulfide 0,23 100,000 --- U --- U --- U --- U 10, Methylene Chloride 0,64 1.000 --- U --- U --- V --- V 11. trans-1,2-Dlchloroethene 0,23 5.000 --- U --- U --- U --- U 12, 1,1-Dichloroathane 0,20 5.000 --- U --- U --- U --- U 13, Vinyl Acetate 0,20 500000 --- U --- U --- V --- U 14, Cis-1.1-Dichloroathane 0,25 5.000 ___ U ___ g ___ U __. U 15. 2-Butsnone 2.21 100,000 --- V --- U --- U --- U 16, Bromochloromethane 0,27 3,000 --- U --- U --- V --- U 17, Chloroform 0.25 5,000 --- U --- V --- U --- V 10. 1,1,1-Trlchloroethane 0.19 1.000 --- U --- U --- U --- V 19, Carbon Tetrachloride 0,04 0,200 --- U --• V --- U --- U 20, Benzene 0,24 1.000 --- U --- V --- V --- V 21. 1,2-Dichloroathane 0,02 0,200 --- U --- U --- V •-- U 22, Trichloroethene 0,23 1.000 --- U --- U --- U --- U 23. 1.2-Dichloropropane 0,04 0,200 --- V --- U --- U --- U 24, Bromodichloromethane 0,04 0,200 --- U --- U --- U --- U 25. Cis-1,3-Dichloropropane 0.06 0.200 •-- U --- U --- U --- U 26. 4-Methyl-2-Pentanons 1.19 100,000 --- V --- U --- U --- U 27. Toluene 0,23 1.000 1,13 --- V --- U --- V 29, trans-1,3-Dichloropropane 0,04 0.200 --- u --- u --- U --- u 29, 1,1,2-Trlchloroethane 0,03 0,200 --- V --- U --- U --- U 30. Tetrachloroethene 0010 0,200 --- U --- U --- U --- V 31. 2-Bexanone 1.57 40,000 --- U --- U •-- U --- u 32, Dibromochloromethane 0.03 0,200 --- U --- V --- U --- V 33. 1.2-Dibromoethans 0,03 0,200 --- V --- U --- V --- V 34. Chlorobenzene 0.30 3,000 --- U --- U --- V --- U 354 1,1,1,2-Tetrachloroethane 0,22 1.000 --- U --- U --- U --- U 36. Ethylbenzene 0.21 11000 --- V --- U --- U --- U 37, Aylenes 0.68 5.000 --- V --- V --- 0 --- U 38, Dlbromomethane 0.28 30.000 --- V --- U --- V --- U 39, Styrene 0.19 1.000 --- V --- V --- U --- U 40. Bromoform 0,20 3.000 --- U --- V --- U --- V 41, 1,1,2,2-Tetrachloroethane 0.03 0.200 --- V --- V --- U --- V 42, 1,2,3-Trlchlozopropane 0.09 0,200 --- U --- U --- U --- U 43, 1,4-Dlchlorobanzene 0,39 1.000 --- U --- U --- U -'- U 44, 1,2-Dichlorobanzene 0,32 5,000 --- U --- U --- V --- U 45, 1,2-Dibromo-3-Chloropropane 0,07 d.200 --- u -•- U --- U --- U 46. Acrylonitrile 2.72 200,000 --- U --- U --- V --- U 47, trans-1,9-Dichloro-2-Butene 0.42 100,000 --- U --- U --- U --- U 4B. Tetrahydrofuran 0,39 1.000 4,22 0,93 il --- U --- U Pages 1 J Estimated value between the MDL and MRL, V Below ALL Ovantitation Limits. Environment 1, Incorporated 114 OAKMONT DRIVE PHONE GREENVILLE, N.C. 27858 FAX CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 C AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/20/19 DATE REPORTED: 02/20/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4(18) PARAMETERS, Ug/1 MDL MRL aw-1 sw-a sw-3 sw-a 49, 1,9-Dioxane 2,71 3.000 4,14 --- U --- U --- U 756-0633 Page: 2 .T = Eetlmated value between the MDL end MRL, D = Below ALL Quantitatlon Limi te. Z i0 R77� �, m M m Q Q j w C) o C C C m 6 Zn z Oyy�J (i 'Tl V� Unn H O J Al L ti 0 N V, 0 o G G M Mo M C) z w C \ m a m TOTAL CHLORINE, mg/I C7 OR ug/I AT COLLECTION m m m 7, TEMPER < < 0 x AT COLLECTION AT m z < `^ "' YOFCONTAINERS m z Field a ro ,... ... .. ... pH Metals ro ,.. ,,. .. ._, Conductivity 9 ro Temperature ro N EPA 8260D A C 0 0 .... _,. .... :.. %3 Dup. I 8260 p M M M 8260 Dup. 2 G� r °!'': ,.. ... ... 8260 Dup. 3 0 0 8260 Dup. 4 A Q m , z Field Parameter ro .��.' lP PARAMETERS/TESTS D ti v s = o = x 0 z L LiD CJ n ➢ z M m z N _ = z m r m r F� zo oz m o M n S IT �� 0 1.m z m m m M 0 z r w '� m 0 v 0 ti m 0 c� w z D c� D z ni 0 z D m Z m m > Fn 31 z 0 0 0 z D -1 O I 0 n a a c O a" 7 <➢ p D r < n m n x z Environment 1, Incorno Ed GREENVILLE, N.C. 27858 FAX 12521156-0633 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 C AMEC FOSTER WHEELER ENVIRONMENT 6 INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 12/12/19 DURHAM, NC 27703 DATE ANALYZED: 12/20/19 - 12/21/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS PARAMETERS, ug/1 MDL MRL Conaentsation 1. Chloromethane 0,77 3,00 -- U 2. Vinyl Chloride 0,12 0,20 --- U 3. Bxomomethane 0.67 10,00 --- U 4. Chloroethane 0,48 10.00 - U 5. Trichlorofluoromethane 0.24 1.00 --- U 6, 1,1-Dichloroethene 0,17 5,00 --- U 7. Acetone 9,06 100.00 -- U 8, Iodomethans 0.26 10.00 -- U 9. Carbon Disulfide 0.23 100.00 - U 10. Methylene Chloride 0,64 1.00 --- U 11, trane-1,2-Dichloroethene 0,23 5.00 --- U 12, 1,1-Dichloroethane 0.20 5.00 --- U 13. Vinyl Acetate 0.20 50,00 --- U 14. cis-1,2-Dichloroethene 0,25 5,00 --- U 15. 2-Butanone 2.21 100.00 -- U 16, Bromochloromethane 0.27 3.00 - U 17. Chloroform 0.25 5.00 -- U 18, 1,1,1-Trichloroethane 0.19 1.00 --- U 19. Carbon Tetrachloride 0,04 0,20 -- U 20, Benzene 0,24 1.00 -- U 21. 1,2-Dichloroethane 0,02 0,20 --- U 22, Trichloroethane 0,23 1.00 - U 23, 1,2-Dichloropropane 0.04 0.20 --- U 24, Bromodichloromethane 0,04 0.20 - U 25. cis-1,3-Dichloropropane 0.06 0,20 --- U 26. 4-methyl-2-Pentanone 1.19 100,00 --- U 27. Toluene 0.23 1.00 -- U 28. trans-1,3-Dichloropropene 0,04 0,20 --- U 29. 1,1,2-Trichloroethane 0,03 0,20 --- U 30. Tetrachloroethane 0.10 0.20 - U 31, 2-Hexanone 1.57 40.00 --- U 32, Dibromochloromethane 0.03 0.20 - U 33, 112-Dibromoethane 0,03 0,20 --- U 34, Chlorobenzene 0.30 3.00 - U 35, 1,1,1,2-Tetrachloroethane 0,22 1.00 --- U 36, Ethylbenzene 0.21 1.00 --- U 37. Xylenes 0.68 5,00 --- U 38. Dibromomethane 0,28 10,00 - U 39, Styrene 0.19 1.00 --- U 40, Bromoform 0,20 3,00 - U 41. 1,1,2,2-Tetrachloroethane 0.03 0.20 --- U 42. 1,2,3-Trichloropropane 0.09 0,20 --- U 43, 1,4-Dichlorobenzene 0,39 1.00 --- U 44, 1,2-Diohlorobenzene 0.32 5.00 --- U 45, 1,2-Dibromo-3-Chloropropane 0.07 0.20 --- U 46. Aorylonitrile 2.72 200.00 --- U 97. trans-1,4-Dichloro-2-Butene 0.42 100.00 --- U 48, Tetrahydrofuran 0.39 1.00 --- U 49. 1,4-Dioxane 2,71 3,00 --- U Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) SURROGATE RECOVERY RESULTS PHONE (252) 756-6208 FAX (252) 756-0633 6003 C JP 12/12/19 12/20/19 - 12/21/19 02/21/20 Sample Name Limite (� recovery) 1,2-DCA-d4 ( recovery) Toluene-d8 (% recovery) 4-HFB recovery) Continuing Calibration std. 70-130 98.3 9901 100 Method Blank 70-130 106 103 101 SW-1 70-130 104 104 101 SW-2 70-130 105 104 102 SW-3 70-130 107 107 104 SW-4 70-130 105 105 102 6003 SW-4 M.S. 70-130 106 107 102 6003 SW-4 M.S.D. 70-130 96.9 99,8 SOS Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: REVIEWED BY: 4dI& VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS PHONE (252) 756-6208 FAX (252) 756-0633 6003 C JP 12/12/19 12/20/19 - 12/21/19 02/21/20 Sample Spiked: (6003) SW-4 Spike Amount Ug/1 sample Result Ug/l Spike Result Ug/1 Spike Recovery (70-130%) spike Dup. Result Ug/l Spike Dup. Recovery (70-130%) MS/MSD RPD (20%) 1,1-Dichloroethene 20.0 - U 20.25 101 23.32 117 14,1 Benzene 20.0 - U 19,07 95.4 22.48 112 16.4 Trichloroethene 20.0 - U 18,74 93,7 22.67 113 1910 Toluene 20,0 -- U 18,90 94.5 22.50 113 17.4 Chlorobenzene 20.0 - U 18.66 93.3 22,01 110 16.5 LABORATORY CONTROL SAMPLE RESULTS Sample Compound: Spike Amount Ug/1 Spike Result Ug/l spike Recovery (70-130%) 1,1-Dichloroethene 20.00 19,63 98.2 Benzene 20,00 19,93 99.7 Trichloroethene 20.00 20,40 102 Toluene 20,00 20,27 101 Chlorobenzene 20,00 19,94. 99.7 Environment 1, GREENVILLE, NI 27858 JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM INC 27703 PARAMETERS MDL PH (Eielfl m sure ant), snits Nitrate Nitrogen ae N, m9/1 0.009 Alkalinity (Co pH 4. 5), mg CaCO3/1 1.0 Cyanide, ug/l 5.0 Sulfate, mg/l 5,0 Antimony, ug/l 0,03 Antimony, ug/l 0,03 ArBenior ug/1 0,08 Barium, ug/l 0,32 Barium, ug/l 0.32 Barium, ug/1 0,32 Barium, ug/l 0,32 Beryllium, ug/1 0.02 Beryllium, ug/1 0,02 Cadmium, ug/l 0,04 Cobalt, ug/l 0,02 Cobalt, ug/l 0,02 Total Chromium, ug/1 0,12 Total Chromium, ug/l 0,12 Copper, ug/1 1,47 Coppers USA 1,47 Iron, ug/l 12,08 Iron, ug/l 12.08 Manganese, ug/l 0.31 Manganese, ug/l 0,31 Lead, ug/l 0.D3 Lead, ug/l 0.03 Mercury, ug/l 0005 Nickel, ug/l 0.03 Nickel, ug/1 0,03 Selenium, ug/l 0.05 selenium, ug/l 0.05 silver, ug/1 0.22 Silver, ug/l 0,22 Thallium, ug/1 - 0.02 Thallium, ug/1 0,02 Tin, ug/1 0.05 Tin, ug/1 045 Vanadium, ug/l 0,20 Vanadium, ug/l 0,20 Zino, ug/1 1.10 Zinc, ug/l 1.30 -W2a'taweter TD% TO PHONE (252) 756-6208 FAX (252) 756-0633 ID#: 6003 D DATE COLLECTED: 12/16/19 DATE REPORTED : 02/21/20 REVIEWED BY: MW-15 MW-16 MW-17 MW-14S MW-14D Analysis Method MRL Date Analyst Code 5.8 611 5.7 615 7.6 12/16/19 BB/NA 4500HB-11 0.04 --- U --- U --- U --- U 0.25 12/17/19 BLD 353.2 R2-9 1.0 130 240 51 1140 205 12/23/19 GNB 2320B-11 5.0 --- U --- U --- U --- U --- U 12/18/19 SHJ 4500CNB-Il 5.0 133 59.3 268 135 --- U 12/19/19 SBJ 45008042E1 160 0406 J 0,18 J 02/03/20 NAB HPA200.8 1.0 Owls J 0.06 J o,22 J 02/19/20 NAB EPA200.8 5$0 0.10 J 3.9J --- U 0.58 J -•- U 02/19/20 NAB RPA200.8 30.0 255 D1/17/20 LPJ EPA200.7 30 w0 394 02/12/20 LFJ BPA200,7 10.0 49.2 02/11/20 LFJ BPA200.8 10.0 332 9 J 02/03/20 LFJ EPA200.7 1.0 0,12J 0.0E J 02/03/20 NAB EPA200.0 140 0.05 J 0,04 J --- U 02/11/20 LFJ EPA200.0 1,0 --- U --- U --- U --- U 0,06 J 02/19/20 NAB BPA200.8 1.0 0,71J L,8 02/03/20 NAB EPA200.8 1.0 0.9 J 0,8 J 0.14 J 02/12/20 LFJ 9PA200.7 5.0 --- U 11117 02/03/20 NAB EPA200,8 5,0 5 1.2J --- U 02/12/20 LFJ EPA200.7 10.0 --- V 2 J 01/17/20 LFJ HPA200.7 10,0 2.0 J 5.0J 2 J 02/11/20 LPJ HPA200.8 5040 21100 14240 01/31/20 NAB 3111E-11 50.0 51400 1700 221 02/07/20 NAB 311IS-11 10.0 107 1664 02/03/20 LFJ EPA200.7 10.0 340 116 3 J 02/12/20 LFJ EPA200.7 5.0 0,32 J 0,22 J 02/04/20 NAB BPA200.8 5.0 0.08.T 0.12 J 0,06 J D2/11/20 LFJ BPA200.8 0.20 --- U --- U --- U --- U --- U 01/09/20 MTM 245.1 R3-9 10.0 3,Oa 14,2 02/03/20 NAB EPA200.8 10.0 2.8J 2,6 J 2.5J 02/11/20 LFJ EPA200.8 3040 4.1J 2.7 J 02/04/20 NAB SPA200.8 10.0 3,4J 0.65 J 0,31 J 02/11/20 LFJ 9PA200.8 5.0 --- U --- U 02/03/20 NAB EPA200.8 5.o --- U --- V --- U 02/11/20 LFJ BPA200.8 110 01101 0,31 J 02/04/20 NAB BPA200.8 1.D 0.09 J 0.06 J 0,02 J 02/11/20 LFJ EPA200PO 100.0 0.10 J 0.16 J 02/03/20 HAD SPA200.8 100.0 --- U --- U 0,20 J 02/21/20 NAB SPA200.8 1.0 35 4 02/03/20 LFJ EPA200.7 1.0 11.2 3.3 O,SJ 02/12/20 NAB BPA200,8 30.0 13 3 J 02/03/20 LFJ HPA200.7 10.0 2.4 J 1.811 9 J 02/11/20 LFJ EPA200.8 T = Estimated value between the M➢L and MAL, U � Below ALL Quantitation Limits. Environment 1, 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 ID#: 6003 D swat ar Ini 18 PHONE (252) 756-6208 FAX (252) 756-0633 JUDSON WHZTEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE DATE COLLECTED: 12/16/19 4021 STIRRUP CREEK DR. STE 100 DATE REPORTED 02/21/20 DURHAM ,NC 27703 REVIEWED BY; MW-15 MW-16 W. 17 Mw-148 MW-14D Analysis Method PARAMBTBRS MDL MRL Date Analyst Code Sulfide, ug/1 100 1000 --- u --- ❑ 226 J --- U --- U 12/19/19 LFJ 450OS2D-11 Conductivity (at 25c), uMhos/om 1.0 1.0 669 1155 555 2008 521 12/16/19 SB/NK 25108-11 Oxygen, mg/l 0.1 0.1 0,78 1.26 0.95 0181 0,53 12/16/19 SB/NK 450000-11 Dissolved 17 16 18 20 12/16/19 8B/NK 2550E-10 Temperature, °C 19 6,33 5.90 7.15 5,51 6,10 12/16/19 SB/NK Static Water Level, feat 41,92 12/16/19 SB/NX Well Depth, feet 22. 14 22,73 22.25 23,12 +54 +97 +112 +93 +66 12/16/19 SR/NK 25BOB-11 ORP, my 1.0 110 4,63 7979 6.60 8,24 2,07 12/16/19 SB/NK 2130E-11 Turbidity (Field), NTU J Setlmated Value between the MDL end MRL, U ealow ALL quantltation Limits. Environment 1, Incor GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: PESTICIDES AND PCB'3 RPA MRTmon 8081E R2(07) CLIENT ID: ANALYST: DATE COLLECTED: DATE EXTRACTED: DATE ANALYZED: DATE REPORTED: wastewater IDi 10 PHONE (252) 756-6208 FAX (252) 756-0633 6003 D HIC 12/16/19 12/18/19 O1/04/20 02/21/20 PARAMETERS, ug/l MDL MRL MW-15 MW-16 MW-17 HW-149 MW-14D 1, Aldrin 0,029 0.050 --- U --- U --- U --- U --- V 2, Alpha-BHC 0,032 0,050 --- U --- u --- U --- V --- U 3, Beta-BHC 0,D31 0.050 --- U --- U --- U --- U --- U 4, Delta-BHC 0.030 0.050 --- U --- U --- U --- V --- U 5. gamma-BHC (Lindane) 0.032 0.050 --- V --- V --- U --- V --- U 6, Chlordane 0.320 0.500 --- V --- U --- U --- U --- V 7. 9,4-DDD 0.051 0.300 --- U --- V --- U --- U --- U 9, 414-DDE 0.049 0.100 --- U --- V --- U --- V --- V 9, 4,4-DDT 0.052 0.100 --- U --- V --- U --- U --- U 10, Dleldrin 0,042 0.075 --- U --- u --- U --- V --- V 11, Endoeulfan I 0.056 0.100 --- U --- V --- U --- U --- V 12, Endoaulfan II 0.D46 0.100 --- U --- U --- U --- U --- U 33. Endoeulfan Sulfate 0,072 0.100 --- U --- V •-- U --- U '-- U 14, Sndrin 0.053 0.100 --- U --- U --- U --- U --- V 15. Sndrin Aldehyde 0.069 0.100 --- V --- U --- U --- U --- U 16, Heptachlor 0.039 0.050 --- V --- U --- U --- U --- U 17, Haptachlor Spoxide 0.042 0.075 --- U --- V --- U --- U --- U 19, Methoxychlor 0.530 1,000 --- U --- U --- U --- U --- U 19, Pob's (Aroclore) 0.500 2,000 --- U --- U --- U --- U --- V 20. Toxaphene 0.690 1.500 --- U --- U --- U --- U --- U NOTE: EPA METHOD SOS1B R2 (07): Initial and Final Continuing Calibration verification exceeded control limit for Heptachlor. Final Continuing Calibration verification exceeded control limit for 4,4-DDT. These analytes were not detected in samples. Data not impacted. g BeEimated value between the MDL and MRL, U Below ALL Quentitatlon Limits. Environment 1, Incorporated 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: UUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 2 703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8151A R1(96) CLIENT ID: ANALYST: DATE COLLECTED: DATE EXTRACTED: DATE ANALYZED: DATE REPORTED: PHONE (252) 756-6208 FAX (252) 756-0633 6003 D HIC 12/16/19 12/19/19 01/30/20 02/21/20 MW-15 m-16 Mw-17 Mw-34a MW-19D PARAMHTERS, ug/1 MDL MRL 1, 214-D 0,36 2,000 --- U --- U --- U --- U --- U 2, Dlnoeeb 0,54 1.000 --- U --- U --- U --- U --- U 3. 2,4,5-TF 0,42 2,000 --- U --- U --- U --- U --- U 4, 2,4,5-T 0.97 2.000 --- U --- U --- U -- U U J = estimated vela¢ between the MDL and MRL, U e Below ALL Quantitatlon Limit¢. Environment 1, Inco 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR- STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: J6, PHONE (252) 756-6208 FAX (252) 756-0633 6003 D ANALYST: JAP DATE COLLECTED: 12/16/19 Page: 1 DATE REPORTED: 02/21/20 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) PARAMETERS. ug/l Date Extracted Date Analyzed MDL MRL 12/16/19 01/23/20 Mw-15 12/23/19 12/28/19 MW-16 12/23/19 12/28/19 NW-17 12/13/10 12/28/19 MW-148 12/23/19 12/2B/19 MW-14D 1. Acenaphthene 2,66 10,000 --- u --- U 3,24 J --- U --- U 2, Acenaphthylene 2,60 104000 --- U --- U --- U --- U --- U 3, Anthracene 2,97 10,000 --- U --- U --- U --- V --- V 4, Benzo[alantrhacene 4,16 10,000 --- U --- V --- U --- U --- U 5, Benzo[blfluoranthens 3,32 10,000 --- u --- U --- u --- U --- U 6, Benzo[klflucranthene 4,23 10,000 --- V --- U --- u --- U --- U 7, Benzo[g,h,ilperylene 2461 10,000 --- U --- U --- V --- U --- U 8, Benzo[alpyrene 3.27 10.000 --- U •-- U --- U --- U --- U 9. 4-Bromophenyl Phenyl Ether 2,63 10,000 --- U --- U --- V --- U --- U 10, Butyl Benzyl Phthalate 5,78 104000 --- U --- U --- U --- U --- U 11, Ble(2-Chloroethoxy) Methane 3,14 104000 --- U W. U --- U --- 0 --- V 12, Bia(2-Chloroethyl) Ether 2,58 104000 --- U --- U --- U --- V --- U 13. BSs(2-Chloro-l-methylethyl) Ether 2,58 10,000 --- U --• U --- V --- V --- U lfl. 2-Chloronaphthalene 2.17 10.000 --- U ___ V ___ V •__ ❑ ___ V 15, 4-Chlorophenyl Phenyl Ether 2.42 10.000 --- u --- U --- U --- V --- U 16, Chrysene 4,04 10,000 --- U W. U --• U --- U --- U 17, Dibenzo[a,hlanthracene 2,78 104000 --- U --- U --- V --- V --- V 18. Di-N-Butyl Phthalate 3,09 10,000 --- U --- u --- V --- U --- U 19. Dlmethyl Phthalate 3478 10,000 --- U --- U --- u --- U M. U 20. methyl Phthalate 3.92 10.000 --- U --- V --- U -•- U --- U 21. 2,4-Dinitrotoluens 3,95 104000 --- V --- U --- V --- U --- U 22. 2,6-Dinitratoluene 3.80 10.000 --- V --- U --- U --- U --- U 23, Di-N-Octyl Phthalate 2,81 10.000 --- U --- U --- V --- V --- V 24. Bis-(2-Sthylhexyl) Phthalate 9497 15,D00 --- U --- U --- U --- u --- U 25, Pluoranthene 3,92 10.000 --- U --- u --- V --- V --- U 26. Pluo rene 2.95 10.000 --- U --- V --- U U --- U 27, Rexachlorobenzene 2.61 10,000 --- U --- U --- V --- V --- U 18, 8exachlorocyolopent adiene 4.16 106000 --- U --- O --- V u ___ V 29, Indeno[1,2,3-Cd)pyrene 2,91 10.000 --- u --- U --- U --- U --- U 30. Ieophorone 3.74 10.000 --- V --- V --- V U U 31, Nitrobenzene 2,85 10,000 --- U --- U •-- V --- U --- U 32, N-Nitroeodimethylamine 4.25 10,000 --- V --- U --- V --- U --• V 33, N-Nitrosodiphenylamine 3.95 10,000 --- U --- V --- V --- V --- U 34, N-NStrosodl-N-Propylamine 4,06 104000 --- V --- U --- u --- U --- U 35, Phenanthrens 344 10,000 --- U --- U -•- U --- V --- U 36. Pyrene 3.63 30.000 --- V --- U --- U V u 37, 4"Chloro-3-Methylphenol 3,79 20,000 --- V --- V --- U --- V --- 38. 2-Chlorophenol 2,75 10,000 --- V --- U --- V --- U --- V 39. O-Cresol 3,68 10,000 --- U --- U --- U --- U --- U 40, P-Cresol 4,12 10,000 --- V --- V --- U --- U --- V 41, 2,4-Dichlorophenol 5.19 10,000 --- U --- U --- U --- U --- V 42. 2,6-Dichlorophenol 4,89 10,000 --- V --- U --- U --- U --- U 43, 2,4-Dimethylphenol 3,21 10,000 --- U --- U --- O --- U --- U 44, 4,6-Dlnitro-2-Methylphenol 4977 50,000 --- U --- U --- U --- U --- u 45. 2,4-Dinitrophenol 4,37 50,000 --- V --- U --- U --- U --- U 46, Ethyl Methanesulfonate 5.26 20,000 "-- U --- U --- U --- U --- u J Estimated value between the MDL and NRL, U Below ALL Quentitatlon Limits, Environment 1, Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) A14EC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 7703 REVIEWED BY: SEMI -VOLATILE ORGANICS RPA METHOD 8270E R6(18) CLIENT ID: IDi PHONE (252) 756-6208 FAX (252) 756-0633 6003 D ANALYST: JAP DATE COLLECTED: 12/16/19 Page: 2 DATE REPORTED: 02/21/20 PARAMRTRRS, U9/1 Date Rxtracted Date Analyzed MDL NRL 12/16/19 01/23/20 MW-15 12/23/19 12/28/19 NW-16 12/23/19 12/28/19 NW-17 12/23/19 12/28/19 MW-14B 12/23/19 12/20/19 MN-14D 97, Methyl MethaneeulEonate 4.92 10.000 --- U --- U --- u --- V --- U 98, 2-NitroBhenol 3.64 10.000 --- U --- U --- u --- V --- U 99. 4-NitroBhenol 3417 50.000 --- V --- u --- u --- U --- u 50. Pantachlozophenol 5.33 25.000 --- U --- U --- U --- V --- U 51, Phenol 1.86 10,000 --- U --- U --- V --- V --- U 52. 2,3,4,6-Tatzaohlorophenol 3.12 10.000 --- U --- U --- u --- u W. u 53, 2,4,5-Trichlorophanol 4,17 10.000 --- U --- U --- U --- V --- U 54, 2,9,6-Trichlorophanol 3,84 10.000 •-- V --- U --- U --- U ^-- U 55, Acetophenone 2,59 10,000 --- V --- U --- U ... V --- V 56. 2-Acetylaminofluorene 3,98 20,000 --- u --- U -•- U --- U --- V 57. 4-Aminobiphe¢yl 4.12 20.000 --- U --- U --- U --- U --- U 58. Denzyl Alcohol 4,47 20,000 --- U --- U --- u --- U --- V 59, 9-ChlozoanilSne 3.36 20,000 --- U --- u --- U --- V W. u 60. Chlorobenzilate 5.12 10.000 --- U --- U --- V U --- U 61. Di allete 2.98 10.000 --- U --- U --- U u ___ U 62, Dibenzofuran 4,28 10,000 --- U --- V --- V --- U --- U 63. 3,31-DSchlerobenzidine 4.22 20,000 --- U --- U --- u •-- U --- U 64. Dimetho ate 3.98 20.000 --- V --- U --- U u U 65, P-Dimethylaminoazobenzene 2,89 10.000 -"- V --- U --- U --- U --- U 66. 7,12-Dimethylbenz[alanthracene 5,26 10.000 --- U --- U --- U --- U --- U 67. 3,3-Dimethylben zldina 3.21 30.000 --- U --- U --- U --- U --- U 68. 1,3-DSnitrobenzena 2,89 20.000 --- V --- U --- U --- U --- U 69, Diphenylamine 5.10 10,000 --- U --- V --- U --- U --- U 70. Disulfoton 9.28 10,000 ... U ... U --• U --- u --- u 71, Famphur 3.98 20,000 --- U --- U --" u "' U --- V 72. Hexachloropropene 4.31 10.000 --- V ___ u ___ U "". U __" U 73, Ieoeaf tole 1.88 10.000 --- U --- U ___ U •_• U "." U 74, Kepone 2,78 20.000 --- U --- V --- U --- V --• U 75. Methapyzlle ne 3,54 100.000 --- D --- V --- U --- U ... V 76, 3-Methyleholenthsene 4,21 10.000 --" D -"- D -"" U --- u --- U 77, 2-Methylnaphthalene 3.79 10.000 --- U --- V --- U --- V --- U 78, Methyl Parathion 4,32 10,000 --- V --- U --- U --- V •-- U 79. m-Cresol 3.81 30.000 --- U -^- U --- U --- U --- U 80. 1,4-Naphthoquinone 4,00 10,000 --- U --- u --- V --- U --- U 81. 1-Naphthylamine 5.61 10.000 _._ U ___ U ___ U. ___ U ___ u 82. 2-Naphthylamine 4.62 10.000 --- U --- V --- U --- U --- U 83, 2-Nltroaniline 3.61 50,000 --- U --- U --- V --- U --- U 04, 3-Nitroaniline 4,91 50.000 --- U --- U --- V --- U --- U 85. 4-NStzoaniline 4.22 20,000 --- U --- V --- U --- V --- U 86. 5-Nitro-O-Toluidine 4.01 10,000 --- U --- U ... V --- U --- U 87. N-Nitroeodi-n-butylamine 3,63 10,000 --- U ^-- U •-• U --- U --- U 88. N-Nit roeo diethy lamina 3.83 20.000 --- U --- U --- V --- V --- U 89. N-Nitroecmethylethylamine 3.03 10.000 --- U --- U --- U --- u --- U 90, N-NitrosoplparSdine 5.19 20.000 --- U --- V --- U -- u U 91. N-Nitrosopyrrolidine 2.89 10,000 --- V --- V --- U --- U --- V 92, Parathion 3.12 30.000 --- u --- U --- u --- D --- u J KBtimated value between the MDL and MRL, U Below ALL UaantitatlOR Limits, Environment 1, InCO 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: wastewater Tpi 10 PHONE (252) 756-6208 FAX (252) 756-0633 6003 D ANALYST: JAP DATE COLLECTED: 12/16/19 Page: 3 DATE REPORTED: 02/21/20 SEMI -VOLATILE ORGANICS EPA METHOD 8270E R6(18) Date Extrdrtetl Date Analyzed PARAMETERS, ug/1 MDL MRL 12/16/19 01/23/20 MW-15 12/23/19 12/26/19 MW-16 12/23/19 12/20/19 MW-17 32/23/19 12/20/19 NW-148 12/23/19 12/20/19 MW-14D 93, Pentachlorobenzene 3.92 10,000 --- D --- u --- V --- V --- u 94, Pentachloronitrobenzene 3.71 20.D9H --- u --- a --- u --- u --- u 95, Phenaoetin 4941 20,000 --- a --- u --- v --- u --- u 96. 1,4-Henzenediamine 2,99 10,000 --- U --- u --- U --- u --- u 97. Phorate 3,86 10.000 --- U --- u --- u --- u --- U 98. Pronamide 3.69 10.000 --- u --- u --- u --- u --- u 99, Sa[role 4,12 10,000 --- U --- V --- u --- u --- U 100. 1,2,4,5-Tetrachlorobenzene 5.01 10,000 --- u --- a --- U --- u --- u 101, Thionazin 4.62 20.000 --- V --- u --- v --- u --- u 102, 0-Toluidine 4,11 10,000 --- u --- U --- u --- u --- u 103. 1,3,5-Trinitrobenzene 3.95 10.000 --- u --- U --- V --- v --- u 104. 0,0,0-Triethyl Phoephorothioate 3.61 10,000 --- u --- u --- u --- u --- u 105, Hexachloroethane 1.49 10,000 --- U --- u --- u --- u --- V 106, Ieodrin 3,11 20.000 --- U --- V --- u --- U --- u J = 8etimated value between the MHL and MAL, U = Helow ALL Quantitation LSm1ta. Environment 1, Inco 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHQRST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27103 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) CLIENT ID: PHONE (252) 756-6208 FAX (252) 756-0633 6003 D ANALYST: JAP DATE COLLECTED: 12/16/19 Page: 1 DATE REPORTED: 02/21/20 PARAMETERS, ug/1 Date HDL Analyzes MRL 12/20/19 MW-15 12/20/19 MW-16 12/21/19 MW-17 la/21/19 MW-14S la/al/19 MW-14D 1. Chloromethane 0,77 34000 --- U -•- U --- U --- U --- U 2. Vinyl Chloride 0,12 0,200 --- V ... U --- U 2.53 --- U 3. Bromomethane 0.67 10,000. --- U --- U --- U --- U --- V 4, Chloroathane 0.48 10,000 --- U --- U --- V --- U ... U 5, Trichlorofluoromethane 0,24 1.000 --- U --- U --- U --- U --- U 6. 101-Dichloroethene 0417 5.000 --- U --- U --- U --- U --- U 7, Acetone 9.06 100,000 --- U --- U --- U --- U --- U 8, Iodomethane 0,26 10.000 --- V --- U --- U --- U --- U 9, Carbon Disulfide 0,23 100,000 --- U --- U --- U --- U --- U 10, Methylene Chloride 0.64 1.000 --- U --- U --- U --- U --- U 11. trans-1,2-Dichloroethena 0,23 5.000 --- U --- U --- U --• U --- U 12. 1,1-Dichloroethane O.aO 5.000 --- U --- U --- U U U 13. Vinyl Acetate 0.20 50.000 --- U --- V --- U --- U --- V 14, Cie-1,2-Dichloroethena 0,25 5,000 --- U --- U --- U 0.46 J --- U 15. 2-Butanons 2,21 100,000 --- U --- U --- V •-- U --- U 16, Bromochloromethans 0,27 3,000 --- U --- U --- U --- V --- U 17, Chloroform 0.25 5.000 ___ U .__ U ___ U ___ U ___ U 18. 1,1,1-Trichloroethans 0.19 1.000 --- U --- U --- U --- U --- U 19, Carbon Tetrachloride 0.04 0,200 --- U --- U --- U --- V --- U 20. Benzene 0,24 1.000 --- U --- U --- U 1,47 --- U 21, 1,2•Dichloroethane D.02 04200 •-- U --- U --- U 0911 J --- U 22, Trichloroethene 0,23 1.000 --- V --- U --- U --- V --- U 23. 1,2-Dichloropropane 0.04 0,200 --- U --- V --- U 0.05 J --- U 24. Bromodichloromethane 0,04 0.200 --- U --- V --- U --- U --- U 25. Cie-1,3-D ichloropropene 0.06 0.200 --- U --- U --- U --- U --- U 26. 4-Methyl-2-Pent anone 1,19 1000000 --- U --- V --- U U --- U 27, Toluene 0.23 1.000 --- U •-- U --- U --- U --- U 28. Crane-1,3-➢Sohla ropropene 0.04 0.200 --- U --- V --- U U --- U 29, l,l,a-Trichlo roethane 0,03 0.200 ___ ❑ -__ U __. U __. U .__ U 30, Tetrachloroethens 0.10 0,200 --- U --- V --- U --- U --- U 31. 2-Heranone 1.57 50,000 --- V --- U --- U --- U --- U 324 Dibromochloromethane 0.03 0,200 --- V --- U --- U --- U --- V 33. 1,2-Dibromoethane 0.03 0.200 --- V --- U --- V U ___ U 34, Chlorobenzene 0.30 3,000 --- U --- U --- U --- U --- U 35, 1,1,1,2-Tetrachloroethans 0,22 1.000 --- U --- U --- U --- U --- U 36, Ethylbenzens 0,21 1.000 --- U --- V -•- U --- U --- U 37, %ylenes 0.68 5.000 --- U --- U --- U --- U --- U 38. Dibromomethene 0,28 10,000 W. U --- U --- U --- V --- U 39. Styrene 0.19 1.000 --- U --- U --- U --- V --- U 40. Bromoform 0.20 3.000 --- U --- U --- U --- U --- U 41, 1,1,2,2-Tatrachloroethans 0,03 0.200 --- U --- U --- U --- U --- V 42, 1,2,3-Trichloropropane 0,09 0.200 --- U --- V --- U --- U --- U 43, 1,4-Dlchlorobsnzene 0,39 1.000 --- U --- U --- U --- U --- U 44, 1,2-Dichlorobenzene 0,32 5.000 --- U -•- V --- U --- V --- U 45, 1,2-Dibromo-3-Chloropropsna 0,07 0,200 --- U --- U --- U --- U --- U 46, Acrylonitrile 2.72 200.000 --- U --- V --- U --- U --- V 47. trans-1,4-Dichlero-2-Butens D.42 100.000 --- U --- V --- V '-- V -'- U J = Estimated value between the MDL and MRL, U = Below ALL Uuantitatlon Limits, Environment 1, Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) CLIENT ID: PHONE (252) 756-6208 FAX (252) 756-0633 6003 D ANALYST: JAP DATE COLLECTED: 12/16/19 Page: 2 DATE REPORTED: 02/21/20 PARAMETERS, ug/1 Date MDL Analyzed MRL 12/20/19 MW715 12/20/19 MW-16 12/21/19 MW-17 12/21/19 MW-14S 12/21/19 MW-14D 98, Acroleln 1.97 4.000 --- U --- U --- u •-- V --- U 49, Allyl Chloride 0,20 10.000 --- U --- U --- u --- V --- u 50. Chloroprene 0,21 20,000 --- U --- U --- U --- u --- u 51, 1,3-Dlchlorobenzene 0,41 5.000 --- U --- D --- U --- V --- U 52. DSchlorodl Eluoromethane 0.51 5.000 --- U --- U --- U D U 53. 1,3-Dichloropropane D.2E 1.000 --- U --- U --- U --- V --- U 54, 2,2-Dichloropropane 0,17 15.000 --- U --- U --- U --- U --- U 55, 1,1-Dichloropropene 0.22 5.000 --- V --- U --- U --- U --- U 56. Ethyl Nethacrylate 0.16 30.000 --- u --- U --- u --- U --- U 57, Hexachlorobutadiene 0.10 0.200 --- V --- u --- U --- U --- U 58, Ieobutyl Alcohol 12.80 100,000 --- U --- u --- U --- U --- u 59, Methacrylonitrlle 1.93 100.000 --- u --- U --- u --- U --- V 60, Methyl Methacrylate 0,25 30,000 --- U --- U --- U --- V --- V 61, Naphthalene 0,47 6.000 --- U --- U --- u --- U --- U 62. Propionitrile 3.26 150,000 --- U --- U --- V --- u --- U 63. 1,2,4-Trichlorobenzene 0,50 10.000 --- U --- U --- V --- U --- V 64. Acatonitrile 36,29 55.000 --- U --- U --- u --- V --- u 65. TetrahydroEuran 0,39 1.OD0 --- U --- U --- V 10.50 --- U 66. 1,4-Dioxane 2,71 3.000 3,69 --- U --- V 3.71 --- u J = Retimated value between the MDL and MRL, U = Below ALL Quentl tfltion Limlte. Environment 1, Incor GREENVILLE, N.C. 27858 FAX CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/16/19 DURHAM, NC ? 703 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PARAMETERS, ug/l Date MDL Analyses MRL la/a0/19 Trip Blank 1, Chloromethane 0,77 34000 --- U 2. Vinyl Chloride 0,12 0.200 --- V 3. eromomethane 0.67 10,000 --- U 4, Chloroethane 0,48 10.000 --- D 5, Trichlorofluoromethane 0,24 1.000 --- V 6, 1,1-Dichloroethene 0.17 5,000 --- V 7. Acetone 9.06 100,000 --- D 8, Iodomethane 0,26 10,000 --- D 9, Carbon Disulfide 0,23 100,000 --- U 10, Methylene Chloride 0,64 1.000 --- V 11, Crane-1,2-Dichloroethene 0,23 5.000 --- U 12, 1,1-Dichloroethane 0.20 5,000 --- D 13, Vinyl Acetate 0,20 50.000 --- U 14, Cie-1,2-Dichloroethene 0,25 5.000 --- U 15. 2-Butanone 2,21 100,000 --- U 16, Bromochloromethane 0,27 3,000 --- V 17, Chloroform 0,25 5,000 --- ➢ 18, 1,1,1-Trichloroethane 0.19 1,000 --- D 19, Carbon Tetrachloride 0.04 0.200 --- V 20, Benzene 0,24 1.000 --- V 21, 1,2-Dichloroethane 0,02 0.200 --- U 22, Trichloroethens 0,23 1.000 --- U 23. 1,2-Dichloropropane 0.04 0.200 --- V 24. Bromodichloromethane 0,04 0,200 --- V 25, Cis-1,3-Dichloropropene 0.06 0,200 --- V 26. 4-Methyl-2-Pentanone 1.19 100,000 --- V 27, Toluene 0,23 1.000 W. U 26, trans-1,3-➢Schloropropene 0,04 0,200 •-- U 29, 1,1,2-Trichloroethane 0,03 0,200 --- V 30, Tetrachloroethens 0.10 0,200 --- U 31. 2-Rexanone 1.57 50,000 --- U 32. Dibromochloromethane 0.03 0,200 --- V $3. 1,2-Dibromoothane 0,03 0,200 --- V 34, Chlorobenzene 0.30 3.000 --- V 35, 1,1,1,2-Tetrachloroethane 0,22 1.000 --- V 36, Ethylbenzene 0,21 1.000 --- V 37, Xylenes 0068 54000 --- U 38, DSbromomethane 0,28 10,000 --- V 39, Styrene 0.19 1.000 --- V 40, Bromoform 0,20 3.000 --- V 41, 1,1,2,2-Tetrachloroethane 0,03 0,200 --- U 42, 1,2,3-Trichloropropane 0,09 0.200 •-- U 43, 1,4-Dichlorobenzene 0,39 1,000 --- U 44. 1,2-Dichlorobenzene 0,32 54000 --- V 459 1,2-Dibromo-3-Chloropropane 0,07 0,200 --- U 46, Acrylonitrlle 2,72 200. 000 --- V 47. Crane-1,4-Dichloro-2-Butene 0,42 100,000 --- V 756-0633 Page: 3 J Estimated value between the MDL and MRL, V Below ALL Vuantitation Llml L'a. Environment 1I Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 FAX CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST$ SAP 4021 STIRRUP CREEK DR. STE 100 DATE COLLECTED: 12/16/19 DURHAM, NC 27703 DATE REPORTED: 02/21/20 REVIEWED BY: LANDFILL APPENDIX II EPA METHOD 8260D R4(18) PARAMETBRS, ug/l Date NDL Analysed MAL 32/20/19 Trip Blank 48, Acrolein 1,97 4,000 --- U 49, Allyl Chloride 0.20 10,000 --- u 50, Chloroprene 0,21 20,000 --- U 51, 1,3-Dichlorobenaene 0,41 5.000 --- ➢ 52, DSahlorodifluoromethane 0.51 5.000 --- U 53, 1,3-Dichloropropane 0.28 1.000 --- u 54, 2,2-Dichloropropane 0.17 15,000 --- u 55, 1,1-Dichloropropane 0.22 5.000 --- U 56, Bthyl Methacrylate 0.16 10,000 --- U 57, Bexachlorobutadiene 0.10 0,200 --- U 58, Ieobutyl Alcohol 12.80 1004000 --- u 59, Methacrylonitrlle 1,93 100.000 --- u 60, Methyl Methacrylate 0,25 30,000 --- u 61, Naphthalene 0,47 6.000 --- u 62, Proplonitrile 3,26 150,000 --- U 63, 1,2,4-Trichlorobenzene 0.50 10,000 --- U 64, Aaetonitrlla 36.29 55,000 --- u 65, Tetrahydroiuran 0,39 1.000 --- u 66, 1,4-Diaxane 2,71 3,000 --- u 756-0633 Page: 4 S = Setima[ed value between the NDL find MRL, U e BelOW ALL Ouflntitatlon LlmlEe, r D Cn m M 0 0 C5L d o M � 04 cn7yAp C" 9 ` y w on z z o�z mo< O m F O o A FyGyI ;'� � o m m M zCif �Gy in in in z w u�yn'1 9 C >e � � � � P` lC Q' G �' r➢y. � CZ7 � o N � 0 D o ➢ o D � m m m J J C'r m z M M M TOTAL CHLORINE, mg/I C7 m m OR ug/1 AT COLLECTION 71 m z TEMPERATURE,°C 0 0 O < '� m 0 < O J ATCOLLECTION m o y O w + a Oe #OF CONTAINERS m Z GS Field pH 9 ro .-? :.. ... ... Nitrate % ro "ti :.. .:. .:. ... ?Y'€ Alkalinity a ro ... .,. .. .< Cyanide d ro � Sulfateffl Metals 9 ro zz a .. o. m m m .... ... :.. Suede hf ro .. .... Conductivity 9 'b DO Temperature a 'd Field Parameter _. 8260 Dup. 2 EPA 8270E ,. 8270E Dup. I Y EPA 8081B Y SOS1B Duplicate Y Gi , PARAMETERSfTESTS m D 2 'i ro z D C) z Cmi z cn ? z o D z z z m m m c O rt�] T T m o M1`r V' O .� D L) 2 DG IV V< z D ➢ O Z m -�i T Z ram- O wZ ➢ o M O = C) z D D W M —r- M D z O n Ci cn p O r D Z m � m z O z 0 n o = 0 P N Z AC W V CSI m rm vi f] pIs: D w o�z _ O D< O A v o In o •� fn o b TC� o Z N ''� o ] d Z W d G5 L7 47 O a a r H D y Oz m m G m O U� t Uj m m P TOTAL CHLORINE, mg/IULUL O 0 m 0 OR ug/I AT COLLECTION N z )J TEMPERATURE, 0 m 0 o < x 0 G. J z r O m { AT COLLECTION m y in in ti o m #OF CONTAINERS m 'z I.,k 8260D App. II ::. ... ._ .... ... 8260D App. II2 G� ,., .__ r. 8260D App. II 3 r 4� _. ., s� 8260D App. II 4 Gi o 8151A Landfill G] 8151A Duplicate ORP Y 'V ,. .... :,. :: ,.. O r Q PARAMETERSfrESTS v m0 m m o o L Li u c? m n c) z z U x Z m m x m U w c> = z m F e o a m m � mac] V m o U' 0 T m 0 � p 3 n a c> 0 czi cT-i < z o a o m oz n D v n m OW O C rm- O M z m v'mi 3 z D n y m z � o x N n x Environment 1, Incor 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT 6 INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: oe VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS FAX CLIENT ID: 6003 D ANALYST: JP DATE COLLECTED: 12/16/19 DATE ANALYZED: 12/20/19 - 12/21/19 DATE REPORTED: 02/21/20 PARAMETERS, ug/1 MDL MRL Concentration 1, Chloromethane 0.77 3,00 --- U 2. Vinyl Chloride 0,12 0,20 --- U 3, Bromomethane 0,67 10.00 --- U 4, Chloroethane 0,48 10,00 --- U 5, Trichlorofluoromethane 0,24 1.00 --- U 6. 1,1-Dichloroethene 0.17 5,00 --- U 7. Acetone 9.06 100.00 --- U 8, Iodomethane 0.26 10,00 --- U 9. Carbon Disulfide 0,23 100,00 --- U 10. Methylene Chloride 0.64 1.00 --- U 11. trans-1,2-Dichloroethene 0,23 5.00 --- U 12, 1,1-Dichloroethane 0,20 5.00 --- U 13, Vinyl Acetate 0,20 50,00 --- U 14. cis-1,2-Dichloroethene 0.25 5,00 --- U 15, 2-Butanone 2.21 100,00 --- U 16. Bromochloromethane 0.27 3.00 --- U 17, Chloroform 0.25 5.00 --- U 18. 1,1,1-Trichloroethane 0.19 1400 --- U 19, Carbon Tetrachloride 0.04 0.20 --- U 20, Benzene 0,24 1,00 -- U 21, 1,2-Dichloroethane 0,02 0,20 --- U 22. Trichloroethene 0,23 1.00 --- U 23, 1,2-Dichloropropane 0,04 0,20 --- U 24. Bromodichloromethane 0,04 0,20 --- U 25. cis-1,3-Dichloropropene 0.06 0,20 --- U 26. 4-methyl-2-Pentanone 1,19 100.00 --- U 27. Toluene 0.23 1.00 --- U 28. trans-1,3-Dichloropropene 0,04 0,20 --- U 29. 1,1,2-Trichloroethane 0,03 0.20 --- U 30, Tetrachloroethene 0.10 0.20 --- U 31. 2-Hexanone 1,57 40,00 --- U 32. Dibromochloromethane 0.03 0.20 --- U 33, 1,2-Dibromoethane 0,03 0.20 --- U 34. Chlorobenzene 0,30 3,00 --- U 35, 1,1,1,2-Tetxachloroethane 0,22 1.00 --- U 36. Ethylbenzene 0.21 1.00 --- U 37. Xylenes 0.68 5.00 --- U 38. Dibromomethane 0,28 10.00 --- U 39, Styrene 0,19 1.00 --- U 40. Bromoform 0,20 3.00 --- U 41, 1,1,2,2-Tetrachloroethane 0.03 0.20 --- U 42. 1,2,3-Trichloropropane 0.09 0.20 --- U 43. 1,4-Dichlorobenzene 0,39 1.00 --- U 44. 1,2-Dichlorobenzene 0.32 5.00 --- U 45. 1,2-Dibromo-3-Chloropropane 0,07 0.20 --- U 46. Acrylonitrile 2,72 1 200,00 --- U 47. trans-1,4-Dichloro-2-Butene 0.42 100.00 --- U 48. Acrolein 1.97 4,00 --- U 49, Allyl Chloride 0,20 10.00 --- U 50. Chloroprene 0,21 20.00 --- U 756-0633 Environment 1, I 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR. STE 100 DURHAM, NC 27703 REVIEWED BY: CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) METHOD BLANK RESULTS (continued) PHONE (252) 756-6208 FAX (252) 756-0633 6003 D JP 12/16/19 12/20/19 - 12/21/19 02/07/20 PARAMETERS, ug/1 MDL MRL Concentration 51, 1,3-Dichlorobenzene 0.41 5.00 --- U 52. ➢ichlorodifluoromethane 0,51 5.00 --- U 53. 1,3-Dichloropropane 0.28 1.00 --- U 54. 2,2-Dichloropropane 0,17 15.00 --- U 55. 1,1-Dichloropropane 0.22 5.00 --- U 56, Ethyl Methacrylate 0.16 10,00 --- U 57, Hexachlorobutadiene 0.10 0.20 --- U 58, Isobutyl Alcohol 12,80 500.00 --- U 59, Methacrylonitrile 1.93 100.00 --- U 60. Methyl Methacrylate 0,25 30.00 --- U 61, Naphthalene 0.47 6.00 --- U 62. Propionitrile 3.26 150.00 --- U 63: 1,2,4-Trichlorobenzene 0.50 10,00 --- U 64, Acetonitrile 36,29 55.00 --- U 65. Tetrahydrofuran 0,39 1,00 --- U 66. 1,4-Dioxane 2,71 3.00 --- U Environment 1, Inco 114 OAKMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) AMEC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE 4021 STIRRUP CREEK DR, STE 100 DURHAM, NC 27703 REVIEWED BY: 2�/ CLIENT ID: ANALYST: DATE COLLECTED: DATE ANALYZED: DATE REPORTED: VOLATILE ORGANICS EPA METHOD 82601) R4 (18) SURROGATE RECOVERY RESULTS ENE (252) 756-6208 FAX (252) 756-0633 6003 D JP 12/16/19 12/20/19 - 12/21/19 02/21/20 Sample Name Limita (8 recovery) 1,2-DCA-d9 (% recovery) Toluene-d8 recovery) 4-HFH (& recovery) Continuing Calibration atd. Method Blank 70-130 70-130 9B.3 106 99.1 103 100 101 MW-15 70-130 106 105 102 MW-16 70-130 107 106 103 MW-17 70-130 106 105 102 MW-14S 70-130 105 105 102 MR-14D 70-130 106 107 102 Trip Blank 6003 3W-4 M.9. 70-130 70-130 103 106 103 107 SOS 102 6003 SW-4 M.9.D. 70-130 96.9 99.8 101 Environment 1, 1 I4 OAMMONT DRIVE GREENVILLE, N.C. 27858 CLIENT: JUDSON WHITEHURST (C&D LANDFILL) CLIENT ID: 6003 D AMC FOSTER WHEELER ENVIRONMENT & INFRASTRUCTURE ANALYST: JP 4021 STIRRUP CREEK DR, STE 100 DATE COLLECTED: 12/16/19 DURHAM, NC 27703 DATE ANALYZED: 12/20/19 - 12/21/19 DATE REPORTED: 02/21/20 REVIEWED BY: VOLATILE ORGANICS EPA METHOD 8260D R4 (18) MATRIX SPIKE/MATRIX SPIKE DUPLICATE RESULTS Sample Spiked: Spike Sample Spike spike Spike Dup. Spike Dup. MS/MSD (6003) Amount Result Result Recovery Result Recovery RPD SW-4 [7g/1 Ug/l Ug/1 (70-130%) Ug/l (70-130%) (20%) 1,1-Dichloroethene 20.0 --- U 20.25 101 23.32 117 14.1 Benzene 20.0 - U 19.07 95.4 22,48 112 16.4 Trichloroethene 20.0 - U 1s.74 93.7 22.67 113 19.0 Toluene 20.0 - U 16, 90 94.5 22.50 113 17.4 Chlorobenzene 20.0 - U 18.66 93.3 22,01 110 16.5 LABORATORY CONTROL SAMPLE RESULTS sample Compound: Spike Amount Ug/1 Spike Reavlt Ug/l Spike Recovery (70-130$) 1,1-Dichloroethene 20.00 19,63 98.2 Benzene 20.00 19.93 99.7 Trichloroethene 20.00 20.40 102 Toluene 20.00 20.27 101 Chlorobenzene 20.00 19.94 99.7 ENVIRONMENT 1, INC. WELL SAIv�LING Ff�LD LOG Chant 'T, . a 4 W, .kc1Iw^5 ID# [,063 SampieDate 1 11 1i)1 Total Hours AA,r-3 site. Contact t 9 5� ' I S"1' y 14 Analpstts) 'I; A PL / 11 R L¢ealio¢ sfatic Water Lcpel Well Deptk Feet Feet of Water Feet Gals in Well Gals Purged pH 1 pH Z pH 3 Temp. 'C C¢¢d. ¢NBras 1 C¢¢d. ra1JR¢s Z Co¢¢IL ¢IvIluas 3 Collrr-[ Time Twbidity, NTQ i1,35 � :� � o 1. ) • G.�3U b,h3F�•ti !v5'O 113 6.J i JE, yi7U`1 �i�,� 200% � �7� 7_b9"1 yoo �, �7`iU 2�19 o�,a � � ,� SI 2 , 8 0 2 61 � •<'1g3 (,•EF q.-50 .`Sbcl )f 398H 362b 3977 - /-,.o37 D�q. �A NVIRONMMENT I, INC. W0371, =: WELL SAA�LING FIELD TAG Client Sf. : ho h. L 14 Wrt. 1i 0 0 3 Sample Date Tot2l HDUM Site Contact knatypt(g) it/ K Location Bfafic Wafer Level Wei Deptb Feet Feetd Water Fmt Gaigm Wci CYah Purged pH 1 pH 2 pH 3 Temp. °C Coed. UlaUS 1 Cond. Uh5DS 2 Coand. uMbos 3 Coiect T®c Turbidity, NT0 AAul1+ ivi vi w 612 „ 'J 7 ,r)I 6,"I.D )Ao VA? b:S 1, a �1 3 I,u D.`> i:5 lice) 0blbb 6.6 �;l 11001 bl 6•17(6,7 l,`1'1 rl,o3 b',b 5 o Iy lu 15 goo IIkQ "0� 14f)S 11 �411 l0'j6 906 11 I b-loll 2o'7i I) �o ,70. cjf IULI� �.911 MI6, 2 S.U? 06 w a I & tvlrv. G,D 31:46 1 os i5 21 . U NA ENVIMONMENT L INC. �qq-3 ►.�. : V _W Client H .r i II3# L�Uo3P Total Hours Site Contact W n. —t sf-), AT 4 Sample Date 1 Z /j �i q Analpst(s) hk Loeafio¢ Sta.(ic Watrr Leeel wav Depth Feet Fed Water Fmt Gales in Wdl Crels Purged Pg 1 PH 2 PH 3 TAP• °C C¢¢d. ¢h2b¢s C¢¢d. uMh¢s Cooed. uMIuos Co6ect T®� Twbidity� 1vTQ 5,q6 0.,l\6 9, �aviol65b.6 ., 11 m3 lo.y3 1.3 •U I (, 93635 b.y (,:,59 .ya 1u.(a �,7 6.'1 �•i 14 11 It/ 77 a4 3 173� 3g26 5gz3 S. 79J 3�q6 by i723;29) 3956 bra 13UcA 132a 7,�h 1 414 6- ENVMONII +ANT 1, INC. UAL`( LAB main WELL sAYAPLING FIELD LAG Client m# 1-l) �3 sample Date Total Sows site Contact tlJ 'i S1- Y,li f Analyst(s) Location Rktie Water Lave Well Depth Feet Feet of Water Feet Gales in Wet Gals Purged pH 1 pH 2 pH 3 Temp. 'C Cond, UNDus 1 Com uMbos 2 Coond. uMbns 3 Co6ect Time Turbidity, NPQ M -AA LAI ILj,90 6,10 7,15 3y,8 �(,,g�. 5,9 L,� 6l0 3�0 3,o '3.� 7,�67,6�7�bZD 5A, .$).,�i 6,07 16,E 5.� 007 19 16 ��3 Zvo�l 67Z N9 5`�� Z�iZ 666 jhj ���j 5Z( 2008 669 1155 5� iz�7 Izv3 �)5 (155 ( 0 �, Z�I .6 .61� Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Appendix B wood. Historical Analytical Data and Groundwater Elevations Appendix B MW-11) Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 2 VIC 1 1,000 15 1 20 2,000 0.3 "11000 2001-May NS NS NS NS iv. ivy NS NS N� NS NS NS ivy ivy 2001-Nov ND ND ND ND ND 83 ND ND ND NS ND ND ND ND NS 48 53 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov ND ND ND ND ND 22 ND ND ND NS ND ND ND ND NS ND ND 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 1 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 16 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May 0.2J 0.3J 11J 0.06U 0.11 0.3J 0.11 0.4 0.04U NS 0.91 0.3J 0.04U ND NS 0.07U 1 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2013-May Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.57J 0.49J 71.1J 0.02U 0.85J 0.24J 0.22J 4.8J 0.27J NS 3.4J 0.24J 0.01U 0.03J NS 0.88J 16 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.3 J 0.07 U 74.6 J 0.07 U 0.60 J 0.13 J 0.38 J 4.1 J 0.29 J 0.07 U 4.4 J 0.51 U 0.20 U 0.08 U 0.52 J 2.2 J 11 2017-Dec 0.26J 4.9J 115 0.07J 0.55J 2.1J 0.57J 3.1J 2.1J 0.07U 4.4J 0.63J 0.24J 0.08U 0.911 4.1J 51 2018-Jun 0.08 J 2.6 J 35.6 0.05 U 0.27 J 0.15 U 0.22 J 1.5 J 0.53 J 0.07 U 2 J 0.33 J 0.06 J 0.05 U 0.11 1.4 6.5 J 2018-Dec 0.111 2.5J 35.5 0.05U 0.111 1.4J 0.27J 1.6J 11 0.05U 1.6J 0.3J 0.091 0.05U 0.17J 2 14 2019-Jun 9 1.5 J 28.1 0.05 U 0.02 U 0.15 U 0.07 J 11 0.03 U 0.12 J 0.72 J 0.29 J 0.05 U 0.05 U 0.05 U 0.03 U 3.8 J 2019-Dec 0.03 U 0.08 U 25 0.38 J 0.04 U 1.3 J 0.76 J 1.47 U 0.03 U 0.06 J 5 J 0.05 U 0.52 J 0.02 U 0.05 U 0.7 J 7 J 1 of 53 Appendix B MW-1D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. . 14m, . GWPS 1 70 NE 0.03 NE-- 2001-May ND ND ND NS ND NS NS 11.12 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May ND ND ND NS ND NS NS 11.98 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May Damaged Damaged Damaged NS Damaged NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May Damaged Damaged Damaged NS Damaged NS NS Damaged 2006-Nov NS NS NS NS NS NS NS NM 2007-May ND ND ND NS ND NS NS 12.52 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May ND ND ND NS ND NS NS 12.24 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS Damaged 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS Damaged 2013-May NS NS NS NS NS NS NS Damaged 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.33 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 1000 0.63U 14.4 NS 13.01 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 117 NS Damaged 2018-Jun 0.24 U 0.21 U 0.25 U 100 0.63 U 30.5 NS Damaged 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 42.70 2.71 U 13.34 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 43.30 2.71 U 12.50 2019-Dec 0.24 U 0.02 U 0.25 U 422 J 0.12 U 122.00 2.71 U 12.28 2 of 53 Appendix B MW-1S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium ND Total Chromium CobaltCopper ND ND ND NS ND ND ND ND ND ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND 15 ND ND ND NS ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U 0.42 U 0.42 U 0.2 U 2007-Nov 0.05U 0.47U 62.4J 0.6J 0.7J 0.3J 1.51 1.7 1.3 NS 3.3J 1.91 0.04U 0.04U 1.5J 1.51 7.9J 2008-May 0.44U 0.5J 27.5J 1 0.6J 0.2J 0.8J 1.5 1.6 NS 5.2J 1.91 0.2J 0.11 0.8J 0.81 4.5J 2008-Nov 0.11 1.11 62.5J 0.7J 0.3J 0.5J 0.91 1.3 2.8 NS 4J 1.6J 0.04U 0.04U 2.6J 2.6J 5.1J 2009-May 0.11 1.8J 26J 2.6 2.3 0.10U 1.2J 0.7 3.7 NS 2.1J 5.2J 0.04U 0.03U 3.5J 3.5J 9.4J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 2.1J 77.4J 0.2J 0.2J 0.10U 2.5J 0.91 0.8J NS 1.7J 5.2J 0.11 0.11 11 11 2.2J 2010-May 0.22U 0.7J 23.5J 0.5J 0.2J 0.5J 0.7J 0.7J 3.0J NS 3.2J 1.01 0.11 0.05U 3.8J 3.8J 2.2J 2010-Nov 0.22U 1.91 56.6J 0.3J 0.2J 0.5J 0.8J 0.5J 2.0J NS 3.9J 1.8J 0.03U 0.05U 3.3J 3.3J 5.6J 2011-May 0.191 0.36J 36J 0.16J 0.111 0.44J 0.41J 1.11 0.6J NS 1.2J 0.46J 0.02U 0.02U 1.2J 1.2J 2.6J 2011-Nov 0.14U 1.11 58.7J 0.26J 0.37J 0.66J 0.48J 0.89J 1.7J NS 1.4J 1.2J 0.02U 0.02U 2.5J 2.5J 3.2J 2012-May 0.12J 0.88J 68.3J 0.191 0.03U 0.911 0.38J 0.87J 1.11 NS 2.6J 1.7J 0.1U 0.35J 1.7J 1.7J 1.4J 2012-Nov 0.14J 0.74J 37.1J 0.18J 0.16J 0.45J 0.31J 1.01 1.11 0.02U 2.6J 1.2J 0.1U 0.07U 1.2J 1.2J 4.7J 2013-May 0.07J 0.02J 73.9J 0.04J 0.15J 0.50J 0.20J 0.96J 0.14J 0.04J 1.8J 1.6J 0.03U 0.04J 1.01 1.01 0.76J 2014-May 0.19 J 0.05 U 20.3 J 0.03 U 0.111 0.45 J 0.13 J 1.0 J 0.111 0.01 U 1.3 J 0.06 U 0.03 U 0.02 U 0.16 J 0.16 J 0.88 J 2014-Nov 16 0.86J 64.5J 0.04U 0.12J 1.6J 0.33J 0.94J 0.18J 0.06U 2.6J 3.0J 0.04U 0.13U 0.96J 0.96J 1.2J 2015-May 0.26J 2.2J 19.91 0.03J 0.13J 0.17J 0.44J 0.60J 0.34J 0.05U 1.6J 0.35J 0.01U 0.02U 1.01 1.01 3.3J 2015-Nov 0.95J 1.01 21.4J 0.04U 0.08J 0.12U 0.30J 1.6J 0.26J 0.05U 2.9J 0.23J 0.01U 0.02U 2.3J 2.3J 1.7J 2016-May 0.56J 2.7J 24.6J 0.07J 0.12J 0.52J 0.20J 3.0J 1.8J 0.04U 2.0J 0.54U 0.06U 0.05U 4.0J 4.0J 3.4J 2016-Nov 0.45J 1.91 49.4J 0.05J 0.13J 0.53J 0.31J 1.8J 0.69J 0.04U 3.8J 1.6J 0.06U 0.05U 2.0J 2.0J 1.8J 2017-May 0.66J 0.31J 31.4J 0.07U 0.11 0.17J 0.24U 3.0J 0.56J NS 2.4J 0.51U 0.20U 0.08U 2.8J 2.8J 1.8J 2017-Dec 0.37J 0.42J 25J 0.07U 0.08U 0.111 0.24U 1.7J 0.191 0.07U 2.7J 0.71J 0.20U 0.08U 1.11 1.11 4.3J 2018-Jun 0.41J 1.5J 33.7 0.05J 0.05J 0.15U 0.2J 1.3J 0.48J 0.07U 2J 0.56J 0.05U 0.05U 1.2 1.2 1.11 2018-Dec 0.52 J 0.96 J 38.5 0.05 U 0.14 J 0.77 J 0.27 J 1.9 J 0.28 J 0.05 U 3.1 J 1.9 J 0.05 U 0.05 U 1.8 1.8 8.1 J 2019-Jun 0.67J 0.68J 31.3 0.05U 0.07J 0.18J 0.37J 3.1J 0.6J 0.06J 2.4J 0.7J 0.05U 0.14J 0.05U 1.5 2.3J 2019-Dec 1 0.03 U 1 0.08 U 1 43 1 0.42 J 1 0.04 U 1 3 J 1 0.32 U 1 1.47 U 1 0.03 U 0.05 U 7.9 J 0.05 U 0.51 U 0.02 U 0.05 U 5 13 3 of 53 Appendix B MW-1S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May ND ND ND NS ND NS NS 12 2001-Nov ND ND ND NS ND NS NS 10.83 2002-May ND ND ND NS ND NS NS 13.06 2002-Nov ND ND ND NS ND NS NS 12.35 2003-May ND ND ND NS ND NS NS 13.08 2003-Nov ND ND ND NS ND NS NS 13.57 2004-May ND ND ND NS ND NS NS 12.42 2004-Nov ND ND ND NS ND NS NS 12.01 2005-May ND ND ND NS ND NS NS 12.63 2005-Nov ND ND ND NS ND NS NS 13.5 2006-May ND ND ND NS ND NS NS 12.45 2006-Nov ND ND ND NS ND NS NS 13.71 2007-May ND ND ND NS ND NS NS 13.64 2007-Jun ND ND ND NS ND NS NS 2007-Nov ND ND ND NS ND NS NS 11.03 2008-May ND ND ND NS ND NS NS 11.05 2008-Nov ND ND 1.0 J NS ND NS NS 11.77 2009-May ND ND ND NS ND NS NS 10.31 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 13.74 2010-May ND ND ND NS ND NS NS 11.87 2010-Nov 0.6 J ND ND NS ND NS NS 12.71 2011-May 0.3 J ND ND NS ND ND NS 11.97 2011-Nov NL ND ND NS ND ND NS 12.71 2012-May ND ND ND NS ND 1.8 NS 12.04 2012-Nov ND ND ND 100 U ND ND NS 12.71 2013-May ND ND ND 100 U ND ND NS 12.55 2014-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.31 2014-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.17 2015-May 0.24 U 0.27 U 0.25 U 104 J 0.63 U 0.39 U NS 14.21 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 15.71 2016-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 14.48 2016-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.31 2017-May 0.24U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.34 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.35 2018-Jun 0.24 U 0.21 U 0.25 U 147 J 0.63 U 0.39 U NS 13.81 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 5.33 14.17 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.62 J 2.71 U 12.80 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 4.39 12.73 4 of 53 Appendix B MW-21) Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 10 1 1,000 15 1 20 2,000 2001-May ND ND ND ND ND 29 ND ND AU JJ ND ND ND ND ND ND ND 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2003-May ND ND ND ND ND 24 ND ND ND NS ND ND ND ND ND ND ND 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2006-May ND ND ND ND ND it ND ND ND NS ND ND ND ND ND ND ND 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2007-May 0.05 U 0.47 U NS 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U ND 0.42 U 19 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2008-May 0.44U 0.4J 16J 0.06U 0.35J 0.3J 0.11 0.7 0.2 NS 1.4J 0.2J 0.04U 0.04U ND 0.07U 2.2 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2009-May 0.06 J 1.2 J 1.8 J 0.06 U 3.6 1.7 J 0.4 J 5.5 0.7 NS 1.7 J 0.12 U 0.04 U 0.03 U ND 2.6 J 14 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2011-Nov 0.14 U 0.48 J 2.0 J 0.02 U 0.09 J 0.04 U 0.03 U 0.15 J 0.06 J NS 0.3 J 0.38 J 0.02 U 0.02 U ND 2.0 J 1.11 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2012-Nov 0.11 0.35J 1.8J 0.07U 0.03J 0.18U 0.04J 0.76J 0.07J 0.07J 1.11 0.55J 0.1U 0.07U 0.1U 1.51 1.8J 2013-May 0.04J 0.86J 16.5J 0.03J 0.39J 0.7J 0.26J 2.0J 0.33J 0.04J 1.6J 0.06J 0.03U 0.02U 0.24J 1.3J 5.4J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2015-May 0.21J 0.39J 6.1J 0.02U 0.23J 0.31J 0.04J 1.5J 0.05J NS 1.5J 0.71J 0.01U 0.04J ND 1.91 3.5J 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS ND NS NS 2017-May 0.08 J 0.07 U 15.1 J 0.07 U 0.23 J 0.63 J 0.24 U 1.4 J 0.27 J 0.07 U 1.3 J 0.51 U 0.20 U 0.08 U 0.14 J 2.0 J 5.4 J 2017-Dec 0.06 U 0.79 J 16.7 J 0.07 U 0.08 U 0.57 J 0.24 U 0.55 J 0.24 J 0.07 U 1.2 J 0.51 U 0.20 U 0.08 U 0.13 U 0.98 J 2.7 J 2018-Jun 0.04J 1.3J 19.8 0.11 0.091 2J 0.51J 1.11 0.98J 0.07U 2J 0.31J 0.05U 0.111 0.05U 2.7 5.7J 2018-Dec 0.03 U 0.91 J 15.6 0.05 U 0.02 U 0.35 J 0.12 J 0.35 J 0.03 U 0.05 U 1.11 0.19 J 0.05 U 0.05 U 0.05 U 0.03 U 1.8 J 2019-Jun 0.03 J 0.06 J 15.2 0.05 U 0.02 U 0.09 J 0.15 U 0.61 J 0.03 U 0.07 J 1.11 0.15 U 0.06 J 0.11 0.05 U 0.03 U 4.7 J 2019-Dec 0.03 U 0.08 U 13 0.32 U 0.04 U 4 J 1 1.47 U 0.03 U 0.06 J 5 J 0.05 U 1.3 J 0.02 U 0.05 U 0.39 J 8 J 5 of 53 Appendix B MW-2D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. . . GWPS 1 0.4 70 NE 0.03 NE 2001-May ND ND ND NS ND NS NS 9.11 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May ND ND ND NS ND NS NS 9.74 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May ND ND ND NS ND NS NS 9.47 2005-Nov NS NS NS NS NS NS NS NM 2006-May ND ND ND NS ND NS NS 9.45 2006-Nov NS NS NS NS NS NS NS NM 2007-May ND ND ND NS ND NS NS 9.85 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May ND ND ND NS ND NS NS 9.52 2008-Nov NS NS NS NS NS NS NS NM 2009-May ND ND ND NS ND NS NS 8.99 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov ND ND ND NS ND NS NS 9.47 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND 100 U ND ND NS 9.65 2013-May ND ND ND 100 U ND ND NS 9.42 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.59 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 9.94 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 9.80 2018-Jun 0.24 U 0.21 U 0.25 U 161 J 0.63 U 0.39 U NS 9.99 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 10.08 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 0.51 J 2.71 U 9.25 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 9.13 6 of 53 Appendix B MW-2S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium �mmw15 ND Total Chromium CobaltCopper ND ND 29 NS ND q'w0.2 ND ND ND NS ND ND ND 2001-Nov ND ND ND ND ND ND ND ND 27 NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND 85 ND ND ND NS ND ND ND ND NS 124 99 2002-Nov ND ND ND ND ND 69 19 ND ND NS ND ND ND ND NS 98 57 2003-May ND ND ND ND ND ND 16 ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND 22 NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND 42 ND ND 20 NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND 33 11 ND ND NS ND ND ND ND NS 44 ND 2005-May ND ND ND ND ND 33 ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND 15 13 ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05U 0.47U 0.04U 0.08U 0.06U 0.24U 0.41U 0.2U 0.07U 0.04U 0.66U 0.35U 0.52U 0.07U NS 0.42U 0.2U 2007-Nov 0.4J 4.2J 96.9J 0.06U 0.3J 0.5J 9.3J 2 0.3 NS 3.6J 2.3J 0.04U 0.2J NS 0.91 3.3J 2008-May 0.44U 1.3J 51.8J 0.11 0.11 0.6J 1.3J 1 0.5 NS 2.1J 1.2J 0.11 0.11 NS 0.07U 1.91 2008-Nov 0.11 5.6J 165 0.06U 0.11 1.7J 10 1.2 0.4 NS 6J 4.8J 0.04U 0.11 NS 1.3J 2.4J 2009-May 0.11 2.2J 6.9J 0.06U 0.04U 0.7J 5.8J 1.9 0.5 NS 1.8J 2.5J 0.04U 0.03U NS 1.8J 5J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.11 0.8J 15.4J 0.91 0.4J 0.10U 0.4J 1.2J 3.9J NS 3.1J 1.91 0.2J 0.03U NS 3.5J 3J 2010-May 0.7J 1.7J 47.5J 0.11 0.8J 0.7J 1.11 0.91 1.11 NS 1.7J 3.5J 0.03U 0.05U NS 2.1J 5.8J 2010-Nov 0.22U 5.6J 149 0.11 0.6J 0.6J 3.3J 1.11 0.5J NS 6.2J 0.32U 0.03U 0.11 NS 0.6J 3.5J 2011-May 0.14U 3.1J 101 0.11 0.29J 0.62J 3.7J 1.5J 0.92J NS 3.1J 0.20U 0.02U 0.11 NS 0.94J 3.1J 2011-Nov 0.14 U 0.9 J 34.3 J 0.07 J 0.17 J 0.29 J 1.11 0.49 J 0.68 J NS 1.2 J 1.3 J 0.02 U 0.07 J NS 0.75 J 2.0 J 2012-May 0.12J 6.1J 166 0.17J 0.25J 1.7J 7.0J 1.3J 1.3J NS 4.4J 13 0.1U 0.22J NS 2.0J 2.0J 2012-Nov 0.28J 91 152 0.091 0.18J 1.91 8.6J 1.3J 0.64J NS 6.6J 15 0.1U 0.101 NS 1.7J 4.6J 2013-May 0.091 5.3J 80.2J 0.101 0.29J 0.57J 2.0J 1.6J 0.55J NS 4.6J 14 0.03U 0.07J NS 0.62J 2.4J 2014-May 0.02 U 0.12 J 33.0 J 0.06 J 0.14 J 0.81 J 1.0 J 0/8 U 0.19 J NS 1.6 J 0.38 J 0.03 U 0.07 J NS 0.07 U 1.11 2014-Nov 0.16J 7J 273 0.111 0.44J 3.5J 5.6J 2.0J 83 NS 5.9J 0.16U 0.04U 0.13U NS 2.3J 3.2J 2015-May 0.03 J 0.15 J 34.3 J 0.08 J 0.13 J 0.14 J 0.29 J 0.36 J 0.27 J NS 0.57 J 0.22 U 0.01 U 0.06 J NS 0.59 J 0.37 J 2015-Nov 0.15J 1.2J 34.6J 0.07J 0.26J 1.2J 0.39J 2.7J 2.6J NS 1.3J 0.26J 0.01U 0.07J NS 2.8J 3.2J 2016-May 0.05 U 0.66 U 89.5 J 0.08 J 0.10 J 0.70 J 0.49 J 1.2 J 0.32 J NS 2.0 J 1.3 J 0.06 U 0.07 J NS 0.36 U 2.5 J 2016-Nov 0.07J 1.2J 55.2J 0.04U 0.101 0.37J 1.7J 0.34J 0.13J NS 2.6J 2.6J 0.06U 0.101 NS 0.39J 1.61U 2017-May 0.08 J 1.2 J 39.9 J 0.07U 0.13J 0.82 J 1.11 1.3 J 0.37 J 0.07 U 2.5 J 1.3 J 0.20 U 0.08U 0.13U 2.4 J 3.4 J 2017-Dec 0.17J 8.0J 281 0.18J 0.17J 7.6J 4.1J 2.7J 1.8J 0.07U 6.0J 0.5U 0.20U 0.08U 0.13U 5.3J 4.0J 2018-Jun 0.07 J 2 J 62.6 0.06 J 0.06 J 0.43 J 1.1 1.3 J 0.48 J 0.07 U 3.3 J 2.1 J 0.05 U 0.05 U 0.05 U 0.83 J 5.2 J 2018-Dec 0.16 J 4.1 J 135 0.05 U 0.111 3 J 1.4 1.5 J 0.41 J 0.05 U 3.9 J 4.6 J 0.05 U 0.08 J 0.05 U 1.2 2.3 J 2019-Jun 0.09 J 5.3 94.7 0.05 J 0.06 J 1.3 2 J 0.56 J 0.04 J 0.08 J 3.9 J 1.7 J 0.05 U 0.05 U 0.05 U 0.6 J 2.3 J 2019-Dec 0.03 U 16 331 0.32 U 0.04 U 5.7 3.4 7.8 J 0.03 U 0.05 U 0.32 U 14 0.51 U 0.02 U 0.05 U 4 3.5 J 7 of 53 Appendix B MW-2S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May ND ND ND NS ND NS NS 10.54 2001-Nov ND ND ND NS ND NS NS 9.7 2002-May ND ND ND NS ND NS NS 10.91 2002-Nov ND ND ND NS ND NS NS 9.95 2003-May ND ND ND NS ND NS NS 11.24 2003-Nov ND ND ND NS ND NS NS 11.06 2004-May ND ND ND NS ND NS NS 10.70 2004-Nov ND ND ND NS ND NS NS 10.18 2005-May ND ND ND NS ND NS NS 10.89 2005-Nov ND ND ND NS ND NS NS 11.55 2006-May ND ND ND NS ND NS NS 10.57 2006-Nov ND ND ND NS ND NS NS 11.29 2007-May ND ND ND NS ND NS NS 11.14 2007-Jun ND ND ND NS ND NS NS 2007-Nov ND ND ND NS ND NS NS 9.56 2008-May ND ND ND NS ND NS NS 10.93 2008-Nov ND ND ND NS ND NS NS 10.32 2009-May ND ND ND NS ND NS NS 9.14 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 11.65 2010-May ND ND ND NS ND NS NS 10.83 2010-Nov ND ND ND NS ND NS NS 11.43 2011-May ND ND ND NS ND 0.7 NS 10.56 2011-Nov ND ND ND NS ND NS 11.88 2012-May ND ND ND NS ND 2.4 NS 10.43 2012-Nov 0.6 J ND ND NS ND 8.5 NS 10.50 2013-May ND ND ND NS ND 1.8 NS 10.71 2014-May 0.24 U 0.27 U 0.27 U NS 0.63 U 1 NS 11.43 2014-Nov 0.60 J 0.27 U 0.27 U NS 0.63 U 17.7 NS 10.33 2015-May 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 12.14 2015-Nov 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.84 2016-May 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.73 2016-Nov 0.24 U 0.27 U 0.27 U NS 0.63 U 0.39 U NS 11.94 2017-May 0.24 U 0.27 U 0.27 U 100 U 0.63 U 1 NS 11.43 2017-Dec 0.24 U 0.21 U 0.21 U 100 U 0.63 U 13.1 NS 10.44 2018-Jun 0.24 U 0.21 U 0.21 U 100 U 0.63 U 1.1 NIA 11.62 2018-Dec 0.24 U 0.02 U 0.02 U 100 U 0.12 U 4.85 6.20 11.08 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 3.94 11.90 10.69 2019-Dec 0.44 J 0.02 U 0.25 U 100 U 0.12 U 27.90 129.00 10.09 8 of 53 Appendix B MW-31) Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina 99L- I I L m N=. GWPS 1 10 4 2 10 1 1,000 15 1 20 2,000 2001-May NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov 0.05U 0.6J 4.6J 0.06U 0.5J 0.24U 0.41U 1.3 0.1 NS 1.6J 0.14U 0.04U 0.04U NS 0.7J 3.6J 2008-May 0.1 J 7.3 J 394 0.06 U 0.11 1.5 J 13 1.3 0.1 NS 7.4 J 0.14 U 0.11 0.04 U NS 1.11 2.6 J 2008-Nov 0.05U 0.2J 5J 0.06U 0.04U 0.11U 0.11 1.3 0.1 NS 0.6J 0.3J 0.04U 0.04U NS 0.11 3.3J 2009-May 0.06J 0.5J 5.3J 0.06U 0.11 0.10U 0.11 0.7 0.04U NS 0.4J 0.3J 0.04U 0.03U NS 1.01 5.9J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov 0.14 U 0.36 J 7.6 J 0.02 U 0.24 J 0.15 J 0.05 J 0.52 J 0.08 J NS 0.71 J 0.20 U 0.02 U 0.02 U NS 0.4 J 1.7 J 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov 0.17 J 0.33 J 7.0 J 0.07 U 0.03 U 0.18 U 0.03 J 1.3 J 0.08 U 0.03 J 0.88J 0.52 J 0.1 U 0.07 U 0.17 J 0.1 U 2.5 J 2013-May 0.03J 0.51J 7.8J 0.03U 0.48J 0.38J 0.08J 1.6J 0.13J 0.05J 0.901 0.23J 0.03U 0.18J NS 0.93J 5.0J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.05 J 0.26 J 10.8 J 0.02 U 0.18 J 0.40 J 0.05J 0.92 J 0.07 J NS 0.68 J 0.22 U 0.01 U 0.03 J NS 0.26 J 3.3 J 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.06 U 0.40 J 11.8 J 0.07 U 0.40 J 0.58 J 0.24 U 1.6 J 0.16 J 0.07 U 0.83 J 0.51 U 0.20 U 0.08 U 0.28 J 1.6 J 5.2 J 2017-Dec 0.06 U 0.41 J 11.11 0.07 U 0.08 U 0.08 U 0.24 U 0.86 J 0.111 0.07 U 0.68 J 0.74 J 0.20 U 0.08 U 0.13 U 0.35 J 2.1 J 2018-Jun 0.07J 0.68J 11.4 0.06J 0.2J 4.6J 0.26J 1.8J 0.6J 0.07U 1.5J 0.3J 0.05U 0.05U 1.2J 3 6.8J 2018-Dec 0.04 J 0.12 J 10.1 0.05 U 0.02 U 0.15 U 0.08 J 0.54 J 0.03 U 0.05 U 11 0.6 J 0.05 U 0.05 U 0.05 U 0.03 U 1.8 J 2019-Jun 0.04 J 0.27 J 9.2 J 0.05 U 0.02 U 0.03 J 0.15 U 0.73 J 0.03 U 0.06 J 0.55 J 0.66 J 0.05 U 0.05 U 0.05 U 0.03 U 2.1 J 2019-Dec 0.03 U 1 0.08 U 8 J 0.32 U 0.04 U 1.05 U 1 1.47 U 0.03 U 0.05 U 2 J 0.05 U 1 J 0.02 U 0.05 U 0.2 U 5 J 9 of 53 Appendix B MW-3D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov ND ND ND NS ND NS NS 9.06 2008-May ND ND ND NS ND NS NS 10.31 2008-Nov ND ND ND NS ND NS NS 9.83 2009-May ND ND ND NS ND NS NS 8.41 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS ND NS NM 2011-Nov ND ND ND NS ND NS NS 10.18 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND 100 U ND ND NS 10.47 2013-May ND ND ND 100 U ND ND NS 10.30 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.01 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS 100 U NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24U 0.27 U 0.25 U 1000 0.63 U 0.39 U NS 10.71 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 10.60 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.48 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 10.88 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.52 J 2.71 U 10.18 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 9.93 10 of 53 Appendix B MW-3S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS Antimony Arsenic Barium NS Beryllium NS Cadmium NS Total Chromium CobaltCopper NS NS NS NS NS NS NS NS NS NS NS NS 2001-May NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov 0.11 6.7J 357 0.06U 0.7J 1.2J 9.4J 1.8 0.1 NS 5.9J 5.6J 0.04U 0.04U NS 1.7J 8J 2008-May 0.44 U 0.4 J 4 J 0.06 U 1 0.2 J 0.11 0.8 0.04 U NS 0.5 J 0.3 J 0.04 U 0.04 U NS 0.07 U 1.6 J 2008-Nov 0.1 J 8.4 J 447 0.06 U 0.04 U 1.4 J 17 1.3 0.1 NS 7.1 J 9.8 J 0.11 0.04 U NS 1.5 J 3.3 J 2009-May 0.06 J 7.0 J 460 0.06 U 0.11 1.6 J 12.6 1.4 0.04 U NS 5.4 J 8.2 J 0.04 U 0.03 U NS 2.7 J 5.9 J 2009-Aug 2.95 U 6.4 J 701 B 0.44 U 0.16 J 8.8 JB 10.6 3.64 J 6.79 U 0.024 U 3.47 J 17 8.22 JB 0.198 U 12.9 JB 0.586 U 1.29 U 2010-Jan 0.06 J 6.8 J 492 0.06 U 0.04 U 11 5.7 J 1.9 J 0.11 0.03 U 5.8 J 0.12 U 0.2 J 0.03 U 0.08 U 2.3 J 1.3 J 2010-May 0.22U 9.2J 527 0.02U 0.3J 2J 18 1.11 0.11 0.08U 10.8J 11 0.11 0.05U 1.5J 2J 2.3J 2010-Nov 0.22 U 0.04 U 254 0.11 0.11 1.7 J 37 1.11 0.11 0.08 U 12.1 J 0.32 U 0.03 U 0.05 U 0.5 J 2.6 J 3.4 J 2011-May 0.14 U 3.8 J 242 0.02 U 0.07 J 0.76 J 14 1.3 J 0.16 J 0.05 U 3.3 J 3.5 J 0.02 U 0.02 U 0.23 J 1.4 J 3.6 J 2011-Nov 0.14U 4.9J 484 0.02U 0.12J 1.7J 6.8J 1.5J 0.42J 0.05U 4.3J 6.6J 0.04J 0.24J 0.26J 3J 2.7J 2012-May 0.27J 4.2J 342 0.07U 0.04J 1.01 2.6J 0.911 0.22J 0.091 3.6J 3.8J 0.1U 0.07U 0.15J 1.4J 0.72J 2012-Nov 0.16J 5.7J 425 0.07U 0.05J 1.5J 15 1.6J 0.31J 0.02J 5.8J 0.3J 0.1U 0.07U 0.13J 1.8J 7.6J 2013-May 0.02 U 3.7 J 288 0.09 J 0.111 0.50 J 2.2 J 0.77 J 0.03 J 0.03 J 3.5 J 5.4 J 0.03 U 0.02 U 0.24 J 1.9 J 1.2 J 2014-May 0.02 U 3.8 J 343 0.03 U 0.19 J 1.8 J 5.91 1.11 0.16 J 0.01 U 3.1 J 2.9 J 0.03 U 0.02 U 0.06 U 1.3 J 2.6 J 2014-Nov 0.14J 91 675 0.04U 0.17J 5.1J 2.6J 1.5J 0.13U 0.06U 5.7J 0.16U 0.04U 0.13U 0.96J 2.5J 2.4J 2015-May 0.06J 6.1J 412 0.04J 0.03J 2.6J 0.89J 0.56J 0.16J 0.05U 2.3J 9.4J 0.01U 0.02U 0.13J 2.2J 0.94J 2015-Nov 0.16J 11 625 0.04J 0.04J 7.3J 2.7J 2.3J 0.091 0.05U 5.7J 0.79J 0.01U 0.02U 0.14J 3.2J 1.7J 2016-May 0.101 10 648 0.06J 0.05U 9.8J 3.1J 2.2J 0.24J 0.04J 4.5J 2J 0.06U 0.05U 0.11J 3.4J 3.8J 2016-Nov 0.19 J 7 945 0.14 J 0.05 U 18 3.0 J 1.7 J 0.19 J 4.93 8.5 J 0.62 U 0.06 U 0.05 U 0.06 U 3.3 J 2.5 J 2017-May 0.15J 11 515 0.08J 0.08U 13 2.5J 2.0J 0.30J 0.07U 4.7J 0.51U 0.20U 0.08U 0.22J 5.3J 2.6J 2017-Dec 0.19 J 14 709 0.08 J 0.08 U 17 3.9 J 2.7 J 0.46 J 0.07 U 6.4 J 0.51 U 0.20 U 0.08 U 0.23 J 5.2 J 4.2 J 2018-Jun 0.21 J 25 879 0.07 J 0.02 U 24 4.7 2.6 J 0.13 J 0.07 U 7.9 J 0.15 U 0.05 U 0.05 U 0.05 U 5.8 1.11 2018-Dec 0.28 J 27 689 0.05 U 0.111 32 3 1.5 J 0.03 J 0.05 U 8.1 J NS 0.05 U 0.05 U 0.05 U 7.2 3.6 J 2019-Jun 0.17 J 1 20 502 1 0.06 J 1 0.02 U 1 2.9 1 24 2.2 J 0.03 U 0.13 J 5.6 J 14 0.05 U 0.05 U 0.05 U 5.9 2.8 J 2019-Dec 0.03 U 1 22 1 650 1 0.32 U 1 0.04 U 1 25 1 6 4 J 0.03 U 0.05 U 5 J 27 0.51 U 0.02 U 0.05 U 5 3 J 11 of 53 Appendix B MW-3S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .1,4-Dioxane NS NS NS NS NS Groundwater Elevation NS 2001-Nov NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov 1 0.4 J 0.2 J NS 0.4 NS NS 10.28 2008-May 1.1 0.4 J 0.2 J NS ND NS NS 11.02 2008-Nov 2.1 0.7 J 1.3 J NS 0.5 NS NS 10.56 2009-May 1.5 0.5 J 0.2 J NS ND NS NS 9.77 2009-Aug 1.3 ND 0.67 J 134 J ND NS NS 9.58 2010-Jan ND 0.4 0.3 J 100 U ND NS NS 11.42 2010-May 3.1 0.5 0.5 J 100 U ND NS NS 10.70 2010-Nov 2.1 0.3 J 0.3 J 1380 ND NS NS 11.14 2011-May 1 ND 0.3 J 544 J ND 2.5 NS 10.71 2011-Nov 1.1 ND ND 2795 ND 6.7 NS 11.29 2012-May 1 ND ND 137 J ND 4.4 NS 10.53 2012-Nov 1.2 ND ND 644 J ND 4.6 NS 10.68 2013-May ND 1 ND 272 J ND 5.6 NS 10.90 2014-May 1.1 0.27 U 0.25 U 467 J 0.63 U 6.5 NS 11.55 2014-Nov 2.1 0.27 U 0.25 U 100 U 2 15.6 NS 10.38 2015-May 1.5 0.27 U 0.25 U 100 U 0.63 U 16.9 NS 12.21 2015-Nov 1.7 0.27 U 0.25 U 100 U 0.63 U 20.9 NS 12.08 2016-May 1.3 0.27 U 0.25 U 100 U 0.63 U 14.4 NS 12.11 2016-Nov 1.2 0.30 J 0.25 U 100 U 0.63 U 10.6 NS 11.99 2017-May 2.8 0.27 U 0.25 U 1000 0.63 U 19.1 NS 11.86 2017-Dec 1.7 0.21 U 0.25 U 100 U 0.63 U 23.5 NS 11.74 2018-Jun 1.2 0.21 U 0.25 U 100 U 2.7 28.8 NS 12.12 2018-Dec 1.3 0.24 0.25 U 100 U 1.82 35.30 184.00 11.52 2019-Jun 0.89 J 0.11 J 0.25 U 100 U 0.12 U 26.60 176.00 11.12 2019-Dec 1.81 0.02 U 0.25 U 100 U 0.12 U 23.10 326.00 10.28 12 of 53 Appendix B MW-3A Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1�4= 2 2,000 2001-May NS NS NS NS NS NS LN_ Lv-) LJJ NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 125 B 0.44 U 0.18 J 3.36 JB 19.9 2.35 J 6.79 U 0.024 U 2.36 U 4.14 J 7.15 JB 0.198 U 5.34 JB 0.586 U 1.29 U 2010-Jan 0.06J 2.6J 84.2J 0.11 0.2J 0.10U 15 1.3J 0.2J 0.09 2.6J 2.7J 0.11 0.11 0.08U 2.1J 3.1J 2010-May 0.22 U 1.01 42.7 J 0.02 U 0.11 0.11 3.8 J 4.0 J 0.01 U 0.08 U 1.5 J 1.01 0.03 U 0.05 U 3.9 J 0.81 2.9 J 2010-Nov 0.22U 5.4J 100 0.11 0.11 0.3J 17 0.5J 0.2J 0.08U 6.4J 8.8J 0.03U 0.05U 0.6J 1.6J 4.1J 2011-May 0.14U 0.93J 36J 0.02U 0.11 0.3J 7.7J 1.11 0.15J 0.05J 1.6J 1.11 0.02U 0.02U 0.32J 0.69J 3.2J 2011-Nov 0.14 U 2.2 J 70.7 J 0.02 U 0.36 J 0.67 J 15 0.88 J 0.17 J 0.05 J 3.6 J 2.3 J 0.02 U 0.14 J 0.47 J 0.88 J 4.7 J 2012-May 0.101 2.8J 86.6J 0.07U 0.08J 1.5J 25 0.85J 0.25J 0.04J 4.8J 4.3J 0.1U 0.101 0.24J 2.0J 5.7J 2012-Nov 0.50 J 5.5 J 120 0.07 U 0.34 J 2.3 J 28 1.4 J 0.35 J 0.05 J 8.8 J 11 0.1 U 0.13 J 0.28 J 1.6 J 8.4 J 2013-May 0.07 J 2.4 J 62.5 J 0.03 U 0.07 J 1.01 18 1.01 0.04 J 0.03 J 5.0 J 4.9 J 0.03 U 0.08 J 0.20 J 0.39 J 3.8 J 2014-May 0.03 J 0.05 U 28.6 J 0.03 U 0.15 J 0.29 J 0.28 J 0.54 J 0.06 J 0.01 U 1.5 J 0.06 U 0.03 U 0.06 J 0.06 J 0.07 U 1.4 J 2014-Nov 0.12U 4.5J 123 0.04U 0.12J 2.8J 15 0.74J 0.13U 0.06U 6.7J 7.2J 0.04U 0.13U 0.05U 0.14J 3.0J 2015-May 0.02 U 0.14 U 17.9 J 0.02 U 0.011 0.12 U 0.12 J 0.12 J 0.06 J 0.05 U 0.43 J 0.53 U 0.01 U 0.02 U 0.06 U 0.46 J 0.27 J 2015-Nov 0.24J 8J 145 0.04J 0.15J 5.1J 11 1.3J 0.28J 0.05U 9.7J 0.22U 0.03J 0.16J 0.35J 1.51 6.9J 2016-May 0.05U 1.5J 78.9J 0.05J 0.07J 1.01 7.6J 1.3J 0.34J 0.04U 2.6J 1.11 0.06U 0.05U 0.06U 1.51 3.7J 2016-Nov 0.111 6.8J 198 0.08J 0.08J 4.1J 6.2J 1.11 0.26J 0.04U 5.5J 9.7J 0.06U 0.05U 0.06U 1.91 2.6 J 2017-May 0.191 11 191 0.091 0.08U 8.7J 8.6J 1.5J 0.42J 0.07U 6.2J 0.51U 0.20U 0.08U 0.21J 4.3J 3.7J 2017-Dec 0.2 J 13 253 0.07 J 0.09 J 10 9.5 J 2.2 J 0.78 J 0.07 U 7.4 J 0.5 U 0.20 U 0.08 U 0.24 J 4.1 J 8.2 J 2018-Jun 0.06J 4.4J 56.1 0.12J 0.06J 2.5J 2.1 1.11 0.911 0.07U 1.8J 2.5J 0.05U 0.05U 0.05U 4 3.2J 2018-Dec 0.2 J 21 312 0.05 U 0.04 J 13 8.3 1.2 J 0.04 J 0.05 U 7.1 J NS 0.05 U 0.05 U 0.05 U 3.1 3.1 J 2019-Jun 0.14 J 11 238 0.06 J 0.02 U 6 9.3 11 0.03 U 0.05 U 4.9 J 4 J 0.05 U 0.05 U 0.05 U 2.5 3.1 J 2019-Dec 0.03 U 20 299 0.32 U 0.04 U 15 7 2 J 0.03 U 0.05 U 5 J 19 0.51 U 0.02 U 0.05 U 4 3 J 13 of 53 Appendix B MW-3A Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 7.78 2010-Jan ND ND ND 100 U ND NS NS 11.12 2010-May ND ND ND 100 U ND NS NS 10.36 2010-Nov 0.9 J ND ND 100 U ND NS NS 10.61 2011-May ND ND 100 U ND ND NS 10.39 2011-Nov 0.6 J ND ND 100 U ND 3.3 NS 10.83 2012-May 0.60 J ND ND 100 U ND 5.1 NS 10.31 2012-Nov 0.70 J ND ND 100 U ND 3.8 NS 10.50 2013-May 0.30 J ND ND 100 U ND 2.4 NS 10.42 2014-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U U.sy U NS 11.13 2014-Nov 0.50 J 0.27 U 0.25 U 100 U 0.63 U 5.7 NS 10.03 2015-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 11.73 2015-Nov 1.7 0.27 U 0.25 U 100 U 0.63 U 8.6 NS 11.66 2016-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 1.3 NS 11.81 2016-Nov 0.80 J 0.27 U 0.25 U 100 U 0.63 U 6.1 NS 11.53 2017-May 2 0.27 U 0.25 U 100U 0.63U 12.7 NS 11.43 2017-Dec 2.7 0.21 U 0.25 U 100 U 0.63 U 19.1 NS 11.17 2018-Jun 0.5 J 0.21 U 0.25 U 100 U 0.63 U 4.5 'r, 12.35 2018-Dec 1.69 0.13 J 0.25 U 100 U 1.09 24.40 87.00 11.19 2019-Jun 1 0.13 J 0.25 U 100 U 0.12 U 8.44 66.90 10.73 2019-Dec 1.49 0.02 U 0.25 U 100 U 0.12 U 20.50 257.00 10.28 14of53 Appendix B MW-4 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium ND Total Chromium CobaltCopper ND ND 15 ND NS ND ND ND 0.2 ND NS ND ND ND 2001-Nov ND ND ND ND ND 29 ND ND 11 NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND 42 ND ND 13 NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND 13 ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND 2 ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND 12 ND ND 25 NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND 25 ND ND 19 NS ND ND ND ND NS 45 ND 2005-May ND ND ND ND ND 30 ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND ND ND 14 NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 100 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05 U 1.3 J 207 0.8 J 0.5 J 2.7 J 1.0 J 2.3 7.2 NS 2.7 J 0.14 U 0.04 U 0.04 U NS 6.9 J 16 2008-May 0.11 1.01 203 0.4J 0.2J 1.2J 1.01 0.7 4.8 NS 2.3J 0.91 0.11 0.11 NS 3.4J 7.8J 2008-Nov 0.11 0.3J 196 0.2J 0.3J 1.01 0.4J 0.9 3.4 NS 1.7J 0.14U 0.04U 0.04U NS 3.1J 5.3J 2009-May 0.7J 2.8J 266 0.91 0.91 2.1J 1.3J 1.8 11 NS 1.2J 0.5J 0.11 0.03U NS 10.01 12 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 2.8J 165 1 0.3J 2.8J 0.91 1.8J 14 NS 2.1J 0.2J 0.11 0.11 NS 11.4J 16 2010-May 0.22U 2.6J 202 0.8J 1.2 2.1J 0.91 1.4J 6.3J NS 2.0J 1.11 0.11 0.11 NS 8.3J 8.5J 2010-Nov 0.22U 2.3J 141 0.7J 0.5J 3.1J 1.11 1.3J 6.4J NS 2.1J 0.7J 0.03U 0.11 NS 9.4J 8.1J 2011-May 0.14U 1.6J 174 0.57J 0.35J 3J 0.58J 1.91 4.8J NS 1.4J 0.73J 0.02U 0.03J NS 7.5J 6.1J 2011-Nov 0.14U 1.91 183 0.65J 0.43J 3.7J 0.76J 1.11 7.3J NS 1.8J 0.61J 0.02U 0.05J NS 8.5J 9.4J 2012-May 0.15J 2.9J 278 0.50J 0.16J 5.7J 0.63J 1.8J 7.6J NS 1.7J 1.6J 0.1U 0.07U NS 7.2J 4.7J 2012-Nov 0.14J 0.91 151 0.47J 0.22J 3.6J 0.38J 0.88J 3.1J NS 1.8J 1.2J 0.1U 0.07U NS 5.8J 6.7J 2013-May 0.02 U 0.83 J 108 0.03 U 0.09 J 2.2 J 0.35 J 0.61 J 0.29 J NS 1.8 J 1.11 0.03 U 0.02 U NS 3.3 J 1.6 J 2014-May 0.02 U 0.05 U 80.2 J 0.23 J 0.08 J 1.9 J 0.30 J 0.31 J 0.74 J NS 0.87 J 0.06 U 0.03 U 0.02 U NS 3.2 J 1.8 J 2014-Nov 0.78J 0.66J 7.3J 0.04U 0.04U 0.14U 0.13J 5.5J 0.31J NS 1.5J 2.6J 0.06J 0.13U NS 0.44J 50 2015-May 0.23J 1.7J 151 0.55J 0.33J 3.0J 0.80J 0.911 3.8J NS 2.0J 1.4J 0.02J 0.05J NS 6.3J 8.3J 2015-Nov 0.191 3.6J 109 0.30J 0.21J 3.3J 1.3J 1.01 2.0J NS 2.5J 1.8J 0.02J 0.05J NS 5.3J 5.9J 2016-May 0.05 U 2.1 J 68.1 J 0.18 J 0.08 J 1.9 J 0.38 J 0.50 J 0.87 J NS 1.3 J 0.76 J 0.06 U 0.05 U NS 3.4 J 3.4 J 2016-Nov 0.05 U 0.91 J 123 0.15 J 0.09 J 2.0 J 0.33 J 0.36 J 0.45 J NS 2.4 J 1.7 J 0.06 U 0.05 U NS 2.7 J 1.8 J 2017-May 0.06U 0.75 J 149 0.17 J 0.09 J 2.0 J 0.36 J 0.53 J 1.7 J NS 2.1 J 1.0 J 0.20 U 0.08 U NA 5.9 J 3.3 J 2017-Dec 0.06J 0.74J 68.7J 0.31J 0.111 3.2J 0.51J 0.92J 1.91 0.07U 1.5J 0.59J 0.20U 0.08U 0.13U 4.6J 5.6J 2018-Jun 0.07 J 1.1 J 93.2 0.26 J 0.09 J 2.4 J 0.46 J 11 1.8 J 0.07 U 1.7 J 0.79 J 0.05 U 0.06 J 0.05 U 5.1 3.3 J 2018-Dec 0.08 J 0.48 J 52.5 0.11 0.14 J 4.4 J 0.22 J 0.65 J 0.28 J 0.05 U 1.5 J 0.74 J 0.05 U 0.05 U 0.24 J 5 4 J 2019-Jun 0.06J 1.5J 167 0.13J 0.07J 0.57J 3.8J 0.39J 0.05J 0.11 1.91 1.11 0.07J 0.16J 0.05U 2.7 3.5J 2019-Dec 0.03 U 0.08 U 72 0.36 J 0.04 U 3 J 0.82 J 1.47 U 0.03 U 0.05 U 3 J 2.2 J 11 0.02 U 0.05 U 3 11 15 of 53 Appendix B MW-4 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May ND ND ND NS ND NS NS 11.48 2001-Nov ND ND ND NS ND NS NS 10.95 2002-May ND ND ND NS ND NS NS 11.80 2002-Nov ND ND ND NS ND NS NS 11.66 2003-May ND ND ND NS ND NS NS 11.82 2003-Nov ND ND ND NS ND NS NS 11.96 2004-May ND ND ND NS ND NS NS 11.62 2004-Nov ND ND ND NS ND NS NS 11.46 2005-May ND ND ND NS ND NS NS 11.69 2005-Nov ND ND ND NS ND NS NS 12.02 2006-May ND ND ND NS ND NS NS 11.68 2006-Nov ND ND ND NS ND NS NS 11.99 2007-May ND ND ND NS ND NS NS 11.92 2007-Jun ND ND ND NS ND NS NS 2007-Nov ND ND ND NS ND NS NS 10.74 2008-May ND ND ND NS ND NS NS 11.84 2008-Nov ND ND ND NS ND NS NS 11.62 2009-May ND ND ND NS ND NS NS 10.03 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 12.19 2010-May ND ND ND NS ND NS NS 11.62 2010-Nov ND ND ND NS ND NS NS 11.61 2011-May ND ND ND NS ND ND NS 11.49 2011-Nov ND ND ND NS ND ND NS 11.92 2012-May ND ND ND NS ND 1.4 NS 11.49 2012-Nov ND ND ND NS ND ND NS 11.80 2013-May ND ND ND NS ND ND NS 11.85 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.86 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.70 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.1 NS 12.03 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.59 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.26 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 11.87 2017-May 0.24U 0.27 U 0.25 U NS 0.63U 0.5 NS 11.86 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.12 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.87 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 9.70 2019-Jun 0.3 J 0.02 J 0.25 U 100 U 0.12 U 2.44 2.71 U 11.62 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 8.64 16 of 53 Appendix B MW-5 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 20 0.2 2,000 2001-May NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND ND 21 ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND ND 12 ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND 29 ND ND NS ND ND ND ND NS ND ND 2006-May ND 5.3 ND ND ND ND 17 ND ND NS ND ND ND ND NS ND ND 2006-Nov ND 5 J ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05U 5.3J 115 0.11 0.6J 0.4J 2.3J 1.6 0.4 NS 9.11 2.3J 0.04U 0.04U NS 1.6J 5.9J 2008-May 0.51 5.0J 101 0.11 0.11 1.2J 1.7J 0.9 0.4 NS 4.3J 2.5J 0.11 0.11 NS 1.2J 4.1J 2008-Nov 0.11 2.1J 48.3J 0.11 0.04U 1.11 0.5J 3.3 0.6 NS 3.4J 1.2J 0.11 0.04U NS 1.8J 3.9J 2009-May 0.2J 1.3J 117 0.5J 0.3J 0.7J 1.2J 2.6 0.2 NS 2.5J 1.5J 0.04U 0.03U NS 1.6J 3.3J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.5 5.8J 83.8J 1 0.6J 2.7J 1.6J 1.6J 1.5J NS 4.8J 5.0J 0.11 0.11 NS 5.1J 4.8J 2010-May 0.22U 3.9J 92.1J 0.5J 0.3J 2.3J 2.8J 1.11 0.7J NS 7.1J 7.3J 0.11 0.05U NS 2.3J 4.3J 2010-Nov 0.6J 0.04U 129 1 2 11 7.8J 3.9J 3.9J NS 16.8J 0.32U 0.11 0.51 NS 3.2J 14 2011-May 0.4J 6.4J 80.5J 0.92J 0.64J 6.2J 1.51 4.4J 3.0J NS 5.5J 4.9J 0.02U 0.07J NS 4.3J 7.4J 2011-Nov 0.55J 3.3J 150 0.24J 0.69J 9.5J 1.6J 7.1J 2.1J NS 6.9J 5.9J 0.02U 0.16J NS 2.4J 7.7J 2012-May 0.36J 6.8J 122 0.50J 0.22J 6.1J 1.7J 3.4J 3.5J NS 4.7J 5.0J 0.1U 0.07U NS 5.6J 6.6J 2012-Nov 0.5J 1.91 117 0.13J 0.12J 5.2J 1.11 4.2J 1.4J NS 5.4J 4.3J 0.1U 0.07U NS 2.0J 5.8J 2013-May 0.34J 2.4J 115 0.23J 0.20J 4.8J 1.6J 4.8J 1.5J NS 5.6J 4.4J 0.03U 0.07J NS 3.5J 6.1J 2014-May 0.34J 0.28J 67.9J 0.03U 0.05J 3.1J 0.34J 4.0J 0.51J NS 2.2J 0.06U 0.03U 0.02J NS 1.11 2.0J 2014-Nov Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged Damaged NS Damaged Damaged Damaged Damaged NS Damaged Damaged 2015-May 0.52 J 11 130 0.02 U 0.62 J 9.3 J 2.6 J 3.5 J 3.9 J NS 6.4 J 0.53 U 0.02 J 0.07 J NS 5.5 J 15 2015-Nov 1.4J 3.5J 233 0.08J 0.38J 9.8J 1.51 4.9J 0.65J NS 10.11 10 0.03J 0.091 NS 1.2J 6.6J 2016-May Dry Dry Dry Dry Dry Dry Dry Dry Dry NS Dry Dry Dry Dry NS Dry Dry 2016-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry NS Dry Dry Dry Dry NS Dry Dry 2017-May 0.44J 5.1J 187 0.46J 0.88J 13 2.9J 5.5J 7.8J NS 8.7J 3.6J 0.20U 0.111 NA 17.2J 27 2017-Dec 0.69 J 2.1 J 76.1 J 0.07 U 0.08 U 6.7 J 0.99 J 3.6 J 0.3 J 0.07 U 4.4 J 3.8 J 0.20 U 0.08 U 0.13 U 3.0 J 2.7 J 2018-Jun 0.18J 5J 82.5 0.13J 0.12J 4.9J 1.1 1.6J 1.11 0.07U 3.6J 2.2J 0.05U 0.05U 0.05U 4.6 4.5J 2018-Dec 0.18 J 4.1 J 140 0.05 U 0.08 J 3.3 J 1.2 0.87 J 0.16 J 0.05 U 3.9 J 4.4 J 0.05 U 0.05 U 0.55 J 1.3 3.5 J 2019-Jun 0.26 J 7 280 0.09 J 0.14 J 4 7.5 1.11 0.03 U 0.11 7.9 J 3.8 J 0.05 U 0.13 J 0.05 U 2.8 4.7 J 2019-Dec 1 0.03 U 1 3.2 J 119 0.02 U 0.04 U 11 2 2 J 0.03 U 0.05 J 10 5.8 J 1 J 0.02 U 0.05 U 5 11 17 of 53 Appendix B MW-5 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS Ninn 2002-Nov ND ND ND NS ND NS NS 10.92 2003-May ND ND ND NS ND NS NS 11.72 2003-Nov ND ND ND NS ND NS NS 11.52 2004-May ND ND ND NS ND NS NS 11.29 2004-Nov ND ND ND NS ND NS NS 10.78 2005-May ND ND ND NS ND NS NS 11.29 2005-Nov ND ND ND NS ND NS NS 11.80 2006-May ND ND ND NS ND NS NS 11.10 2006-Nov ND ND ND NS ND NS NS 11.58 2007-May ND ND ND NS ND NS NS 11.59 2007-Jun ND ND ND NS ND NS NS 2007-Nov ND ND ND NS ND NS NS 10.47 2008-May ND ND ND NS ND NS NS 11.30 2008-Nov ND ND ND NS ND NS NS 10.90 2009-May ND ND ND NS ND NS NS 10.14 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 12.04 2010-May ND ND ND NS ND NS NS 11.33 2010-Nov ND ND ND NS ND NS NS 11.70 2011-May ND ND ND NS ND 0.9 J NS 11.19 2011-Nov ND ND ND NS ND ND NS 11.64 2012-May ND ND ND NS ND 1.7 NS 11.10 2012-Nov ND ND ND NS ND ND NS 11.32 2013-May ND ND ND NS ND ND NS 11.45 2014-May 0.24 U 0.27 U 0.25U NS 0.63 U 0.39 U NS 11.60 2014-Nov Damaged Damaged Damaged NS Damaged Damaged NS amagea 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.08 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 13.47 2016-May Dry Dry Dry NS Dry Dry NS Dry 2016-Nov Dry Dry Dry NS Dry Dry NS Dry 2017-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.5 NS 12.66 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.95 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 1.3 'r, 12.45 2018-Dec 0.24 U 0.02 U 0.25 U 390 J 0.12 U 2.27 16.40 12.30 2019-Jun 0.24 U 0.07 J 0.25 U 100 U 0.12 U 6.80 74.20 11.90 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 2.48 31.70 11.20 18 of 53 Appendix B MW-6 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony ND Arsenic 10 ND Barium ND Beryllium ND Cadmium ND Total Chromium CobaltCopper ND ND ND NS ND ND ND ND NS ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND ND 11 ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND 11 52 ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND 15 23 ND ND NS ND ND ND ND NS ND ND 2004-Nov ND 14 ND ND ND 22 ND ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND 20 15 ND ND NS ND ND ND ND NS ND ND 2005-Nov ND 22 ND ND ND 11 ND ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND 11 ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND 12 ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 112 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.2 J 16 233 0.9 J 0.6 J 13 6.3 J 6.7 5.9 NS 9.11 7.9 J 0.04 U 0.2 J NS 17 J 20 2008-May 0.2J 5.3J 65J 0.11 0.4J 3.1J 1.7J 2.1 0.5 NS 3.2J 1.7J 0.11 0.2J NS 4.6J 3.0J 2008-Nov 0.2J 11 161 0.11 0.4J 4.7J 4.4J 2.8 0.4 NS 6.1J 5.3J 0.04U 0.11 NS 4.2J 3.6J 2009-May 0.11 2.9J 56.1 0.11 0.91 2.5J 1.11 2.3 0.3 NS 1.01 0.5J 0.04U 0.03U NS 7.5J 2.5J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 6.4J 137 0.11 0.3J 0.8J 0.6J 1.11 0.5J NS 1.11 2.0J 0.11 0.03U NS 11.6J 3.9J 2010-May 0.22U 6.1J 215 0.11 2.2 4.2J 5.4J 2.4J 0.2J NS 7.5J 7.5J 0.03U 0.05U NS 5.8J 3.3J 2010-Nov 0.22U 4.8J 155 0.11 0.6J 2J 0.7J 1.5J 0.3J NS 5.7J 7.2J 0.11 0.11 NS 4.4J 4.5J 2011-May 0.14U 2.2J 124 0.02U 0.43J 2.4J 1.4J 1.6J 0.18J NS 2J 1.3J 0.02U 0.9J NS 3.9J 1.8J 2011-Nov 0.14U 2.4J 157 0.06J 0.29J 2.7J 1.11 1.7J 0.24J NS 2.7J 1.6J 0.02U 0.08J NS 3.3J 3.3J 2012-May 0.17J 2.2J 128 0.07U 0.27J 2.5J 1.3J 2.2J 0.39J NS 2.9J 1.5J 0.1U 0.101 NS 3.0J 0.911 2012-Nov 0.07J 2.4J 53.4J 0.091 0.12J 1.8J 0.55J 1.2J 0.55J NS 1.4J 0.64J 0.1U 0.07U NS 4.7J 4.9J 2013-May 0.07J 2.4J 209 0.16J 0.31J 3.2J 3.0J 1.8J 0.05J NS 4.3J 2.7J 0.03U 0.101 NS 1.51 0.911 2014-May 0.02 U 0.05 U 110 0.05 J 0.31 J 0.38 J 0.22 J 0.52 J 0.04 J NS 0.71 J 0.06 U 0.03 U 0.02 U NS 0.34 J 0.84 J 2014-Nov 0.18J 3.4J 246 0.04U 0.20J 2.6J 2.8J 0.61J 0.13U NS 3.1J 1.7J 0.04U 0.13U NS 1.2J 0.54J 2015-May 0.08J 1.3J 271 0.15J 0.48J 0.86J 0.911 0.84J 0.091 NS 1.7J 0.46J 0.01U 0.101 NS 1.11 2.5J 2015-Nov 0.24J 3.6J 131 0.05J 0.45J 1.3J 1.11 1.91 0.191 NS 2.3J 0.81J 0.011 0.06J NS 4.1J 6.2J 2016-May 0.12J 5.2J 561 0.07J 0.48J 4.0J 4.5J 2.5J 0.14J NS 5.5J 3.2J 0.06U 0.18J NS 4.9J 3.2J 2016-Nov 0.08 J 13 336 0.13 J 0.18 J 4.8 J 2.5 J 1.01 0.66 J NS 3.6 J 6.3 J 0.06 U 0.05 U NS 5.6 J 1.9 J 2017-May 0.06U 6.4J 98.1J 0.18J 0.25J 3.4J 1.4J 1.5J 2.2J NS 1.8J 0.52J 0.20U 0.08U NA 17.9J 6.1J 2017-Dec 0.11 J 10 633 0.07 U 0.08 U 7.7 J 2.9 J 1.6 J 0.35 J 0.07 U 4.9 J 0.5 U 0.20 U 0.08 U 0.14 J 7.5 J 2.8 J 2018-Jun 0.08 J 1.2 J 348 0.05 U 0.15 J 1.3 J 1.6 1.4 J 0.07 J 0.07 U 3.6 J 2.5 J 0.05 U 0.11 0.05 U 1.2 0.11 U 2018-Dec 0.19 J 5.7 470 0.05 U 0.17 J 4.3 J 2.9 1.3 J 0.03 U 0.06 J 6.3 J 3.7 J 0.05 U 0.05 U 0.05 U 2 2.3 J 2019-Jun 0.15 J 11 776 0.07 J 0.13 J 3.5 7.1 0.98 J 0.03 U 0.16 J 6.2 J 4 J 0.05 U 0.05 U 0.05 U 6.2 2.2 J 2019-Dec 1 0.03 U 1 10 1 535 1 0.02 U 0.04 U 12 4 1.47 U 0.03 U 0.05 J 7 J 10 0.6 J 0.02 U 0.05 U 7 4 J 19 of 53 Appendix B MW-6 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 70 NE -- 2001-May ND ND ND NS ND NS NS 10.19 2001-Nov ND ND ND NS ND NS NS 9.57 2002-May ND ND ND NS ND NS NS 10.3 2002-Nov ND ND ND NS ND NS NS 9.73 2003-May ND ND ND NS ND NS NS 10.57 2003-Nov ND ND ND NS ND NS NS 10.75 2004-May ND ND ND NS ND NS NS 10.48 2004-Nov ND ND ND NS ND NS NS 10.16 2005-May ND ND ND NS ND NS NS 10.66 2005-Nov ND ND ND NS ND NS NS 11.03 2006-May ND ND ND NS ND NS NS 10.4 2006-Nov ND ND ND NS ND NS NS 10.95 2007-May ND ND ND NS ND NS NS 10.85 2007-Jun ND ND ND NS ND NS NS 2007-Nov 0.2 J ND ND NS ND NS NS 9.65 2008-May ND ND ND NS ND NS NS 10.58 2008-Nov ND ND ND NS ND NS NS 10.19 2009-May ND ND ND NS ND NS NS 9.35 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 11.07 2010-May ND ND ND NS ND NS NS 10.64 2010-Nov ND ND ND NS ND NS NS 10.88 2011-May ND ND ND NS ND 2.3 NS 10.40 2011-Nov ND ND ND NS ND 1.9 NS 10.61 2012-May ND ND ND NS ND 2.7 NS 10.3 2012-Nov ND ND ND NS ND ND NS 10.49 2013-May ND ND ND NS ND 4.4 NS 10.44 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.13 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 3.4 NS 10.68 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.9 NS 11.58 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.8 0.39 U NS 11.49 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 8.2 NS 11.50 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 5.6 NS 11.71 2017-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.5 NS 11.28 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 12.3 NS 10.88 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 5.6 'r, 11.38 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.18 J 6.88 13.50 10.98 2019-Jun 0.24 U 0.02 J 0.25 U 100 U 0.12 U 14.40 40.10 10.61 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 14.70 25.30 10.30 20 of 53 Appendix B MW-7 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony ND Arsenic ND Barium ND Beryllium ND Cadmium ND Total Chromium CobaltCopper ND ND ND NS ND ND ND 0.2 ND NS ND ND ND 2001-Nov ND ND ND ND ND 15 ND ND ND NS ND ND ND ND NS ND ND 2002-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND ND ND ND ND ND 17 ND ND NS ND ND ND ND NS ND ND 2003-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-May ND 6.4 J ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2004-Nov ND 3.6 ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND 40 ND ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 144 0.08 U 0.06 U 0.24 U 12 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05 U 6.4 J 136 0.11 0.4 J 1.3 J 17 2.7 0.3 NS 7.5 J 6.0 J 0.04 U 0.04 U NS 2.5 J 3.4 J 2008-May 0.2J 3.6J 31J 0.11 0.04U 1.11 2.6J 2 0.7 NS 2.0J 1.7J 0.04U 0.11 NS 3.1J 3.4J 2008-Nov 0.11 3.3J 103 0.11 0.04U 1.11 2.8J 3 0.3 NS 4.6J 5.9J 0.11 0.11 NS 1.3J 3.0J 2009-May 0.06J 1.01 31J 0.11 0.8J 0.5J 2.3J 1.6 0.1 NS 0.91 0.8J 0.04U 0.03U NS 1.8J 2.8J 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.06J 0.5J 29.1J 0.06U 0.2J 0.10U 1.11 2.4J 0.11 NS 0.6J 0.2J 0.3J 0.03U NS 0.8J 1.5J 2010-May 0.22U 4.5J 266 0.11 2 2.5J 9.01 2.9J 0.11 NS 10.4J 9.8J 0.03U 0.5J NS 1.3J 3.8J 2010-Nov 0.22U 0.91 34.3J 0.11 0.4J 0.4J 0.8J 0.8J 0.2J NS 1.7J 1.11 0.11 0.05U NS 1.11 4.3J 2011-May 0.14U 1.5J 174 0.02U 0.4J 1.2J 4.2J 1.5J 0.12J NS 2.3J 3J 0.02U 0.24J NS 0.75J 2.4J 2011-Nov 0.14U 0.81J 67.4J 0.06J 0.38J 0.92J 1.2J 0.93J 0.29J NS 1.5J 1.11 0.02U 0.08J NS 1.2J 1.8J 2012-May 0.16J 2.3J 294 0.07U 0.12J 2.0J 3.6J 1.91 0.33J NS 4.3J 4.3J 0.1U 0.26J NS 1.3J 0.66J 2012-Nov 0.15J 0.72J 100 0.07U 0.16J 1.5J 1.3J 1.91 0.20J NS 2.5J 1.91 0.1U 0.29J NS 0.52J 4.6J 2013-May 0.02 U 5.0 J 560 0.03 U 0.14 J 7.4 J 9.2 J 1.9 J 0.08 J NS 5.5 J 9.9 J 0.03 U 0.20 J NS 1.3 J 1.01 2014-May 0.12J 2.1J 291 0.04J 0.29J 6.1J 5.2J 1.7J 0.14J NS 3.5J 3.4J 0.03U 0.26J NS 1.3J 1.91 2014-Nov 0.22 J 4.1 J 398 0.04 U 0.26 J 11 5.01 4.8 J 0.22 J NS 6.0 J 0.44 U 0.04 U 0.13 U NS 1.3 J 1.4 J 2015-May 0.22J 5J 819 0.06J 0.44J 18 18 1.6J 0.25J NS 6.8J 0.53U 0.02J 0.101 NS 2.9J 2.5J 2015-Nov 0.27J 2.9J 294 0.05J 0.35J 9.91 4.1J 5.6J 0.35J NS 5.4J 9.6J 0.01U 0.04J NS 1.91 6.1J 2016-May 0.13J 5.6J 751 0.07J 0.15J 18 16 1.91 0.27J NS 6.3J 9.91 0.06U 0.091 NS 3.0J 2.3J 2016-Nov 0.12J 5.1J 411 0.101 0.30J 8.8J 3.3J 4.1J 0.24J NS 10.4J 0.62U 0.06U 0.05U NS 1.6J 2.7J 2017-May 0.08 J 4.0 J 367 0.07 J 0.11 8.9 J 8.3 J 1.2 J 0.44 J NS 4.2 J 5.0 J 0.20 U 0.08 U NA 4.3 J 2.8 J 2017-Dec 0.12 J 0.47 U 312 0.07 U 0.09 J 8.2 J 3.5 J 4.6 J 0.24 J 0.07 U 5.1 J 0.5 U 0.20 U 0.08 J 0.13 U 1.11 1.11 2018-Jun 0.06 J 1.9 J 132 0.05 U 0.06 J 2.7 J 2.4 0.65 J 0.14 J 0.07 U 2 J 2.7 J 0.05 U 0.06 J 0.05 U 1.3 0.19 J 2018-Dec 0.17 J 15 566 0.07 J 0.16 J 12 12 1.2 J 0.2 J 0.05 U 6.3 J NS 0.05 U 0.05 U 0.05 U 2.4 3.4 J 2019-Jun 0.1 J 9 524 0.06 J 0.02 U 8 14 2 J 0.03 U 0.05 J 4.9 J 5.6 J 0.06 J 0.05 U 0.05 U 2.9 5.6 J 2019-Dec 0.03 U 2.8 J 234 0.02 U 0.04 U 15 4 7 J 0.03 U 0.05 J 8 J 9.2 J 0.22 U 0.02 U 0.05 U 0.86 J 5 J 21 of 53 Appendix B MW-7 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 0.4 70 NE -- 2001-May ND ND ND NS ND NS NS 10.74 2001-Nov ND ND ND NS ND NS NS 10.08 2002-May ND ND ND NS ND NS NS 10.89 2002-Nov ND ND ND NS ND NS NS 10.33 2003-May ND ND ND NS ND NS NS 10.92 2003-Nov ND ND ND NS ND NS NS 11.24 2004-May ND ND ND NS ND NS NS 10.90 2004-Nov ND ND ND NS ND NS NS 10.61 2005-May ND ND ND NS ND NS NS 11.10 2005-Nov ND ND ND NS ND NS NS 11.42 2006-May ND ND ND NS ND NS NS 10.89 2006-Nov ND ND ND NS ND NS NS 11.41 2007-May ND ND ND NS ND NS NS 11.40 2007-Jun ND ND ND NS ND NS NS 2007-Nov 0.3 J ND ND NS ND NS NS 9.98 2008-May ND ND ND NS ND NS NS 11.00 2008-Nov ND ND ND NS ND NS NS 10.72 2009-May ND ND ND NS ND NS NS 9.51 2009-Aug NS NS NS NS NS NS NS 2010-Jan ND ND ND NS ND NS NS 11.60 2010-May ND ND ND NS ND NS NS 11.06 2010-Nov ND ND ND NS ND NS NS 11.24 2011-May ND ND ND NS ND 4.5 NS 10.85 2011-Nov ND ND ND NS ND NS 11.14 2012-May ND ND ND NS ND 6.4 NS 10.79 2012-Nov ND ND ND NS ND 1.2 NS 10.79 2013-May ND 0.40 J ND NS ND 20.9 NS 11.08 2014-May 0.30 J 0.27 U 0.25 U NS 0.63 U 10.8 NS 10.70 2014-Nov 0.30 J 0.27 U 0.25 U NS 0.63 U 7.1 NS 11.75 2015-May 0.60 J 0.27 U 0.25 U NS 0.63 U 34.7 NS 11.89 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 1.6 NS 12.02 2016-May 0.40 J 0.27 U 0.25 U NS 0.63 U 29.7 NS 11.98 2016-Nov 0.40 J 0.27 U 0.25 U NS 0.63 U 16.3 NS 11.95 2017-May 0.24U 0.27 U 0.25 U NS 0.63 U 12.8 NS 11.48 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 3 NS 11.69 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 6.3 NIA 11.65 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 1.25 32 18.2 11.45 2019-Jun 0.31 J 0.02 J 0.25 U 100 U 0.12 U 27 17 10.65 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 2.47 8.51 10.89 22 of 53 Appendix B MW-8 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina Date Sampled GWPS 2001-May Antimony NS Arsenic NS Barium NS Beryllium NS Cadmium NS Total Chromium CobaltCopper NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2003-May ND 13 ND ND ND ND ND ND 2.8J NS ND ND ND ND NS 115 134 2003-Nov ND ND ND ND ND 122 ND ND ND NS ND ND ND ND NS ND ND 2004-May ND ND ND ND ND 10 ND ND ND NS ND ND ND ND NS ND ND 2004-Nov ND ND ND ND ND 25 ND ND ND NS ND ND ND ND NS ND ND 2005-May ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2005-Nov ND ND ND ND ND ND ND ND ND NS ND ND ND ND NS ND ND 2006-May ND ND ND ND 1 ND ND ND ND NS ND ND ND ND NS ND ND 2006-Nov ND ND ND ND ND ND 43 ND ND NS ND ND ND ND NS ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.24 U 38 0.2 U 0.07 U 0.04 U 0.66 U 0.35 U 0.52 U 0.07 U NS 0.42 U 0.2 U 2007-Nov 0.05U 0.47U 214 0.11 0.3J 1.01 0.41U 1.6 0.3 NS 5.3J 4.7J 0.04U 0.04U NS 1.4J 5.1J 2008-May 0.11 4.5J 127 0.11 0.11 1.11 19 0.9 0.2 NS 7.8J 5.9J 0.04U 0.04U NS 1.01 2.7J 2008-Nov 0.05 U 2.7 J 121 0.06 U 0.11 0.4 J 12 0.8 0.2 NS 4.7 J 3.5 J 0.04 U 0.04 U NS 0.8 J 1.7 J 2009-May 0.06J 1.6J 113 0.06U 0.2J 0.11 8.4J 0.6 0.1 NS 3.3J 2.2J 0.04U 0.03U NS 1.3J 3.2J 2009-Aug 2.95 U 4.9 U 127 B 0.44 U 0.3 J 4.76 JB 12.3 2.31 J 6.79 U 0.024 U 3.91 J 4.59 J 7.77 JB 0.198 U 5.12 JB 0.586 U 1.29 U 2010-Jan 0.06J 4.0J 169 0.11 0.2J 0.10U 10 0.7J 0.4J 0.03U 5.1J 3.0J 0.3J 0.03U 0.08U 0.91 3.1J 2010-May 0.22U 7.5J 140 0.4J 0.2J 0.8J 21 1.11 0.4J 0.08U 9.2J 4.4J 0.11 0.11 0.4J 1.6J 6.3J 2010-Nov 0.22U 4.0J 164 0.2J 0.3J 0.8J 24 0.8J 0.4J 0.08U 9.11 4.7J 0.11 0.05U 0.5J 1.91 5.4J 2011-May 0.14U 3.2J 124 0.06J 0.06J 0.84J 31 1.3J 0.13J 0.08J 5.2J 3.0J 0.02U 0.02U 0.95J 0.76J 5.4J 2011-Nov 0.14U 2.7J 184 0.24J 0.13J 2.1J 17 0.69J 1.2J 0.05U 5.4J 1.91 0.02U 0.02U 0.24J 4.1J 5.3J 2012-May 0.13J 5.8J 142 0.13J 0.06J 1.7J 31 1.11 0.20J 0.04J 7.2J 4.5J 0.1U 0.07U 0.10U 1.3J 3.2J 2012-Nov 0.16J 8.0J 133 0.091 0.04J 3.0J 27 1.4J 0.191 0.02U 8.6J 6.9J 0.1U 0.07U 0.92J 1.2J 5.5J 2013-May 0.14J 6.2J 144 0.03U 0.13J 2.2J 24 1.3J 0.06J 0.03J 9.3J 6.8J 0.03U 0.06J 0.08J 1.3J 2.9J 2014-May 0.07J 5.8J 157 0.12J 0.39J 3.8J 22 2.0J 0.191 0.01U 7.8J 4.9J 0.03U 0.03J 0.06U 1.01 3.4J 2014-Nov 0.20 J 10 189 0.04 J 0.08 J 5.8 J 12 1.2 J 0.13 U 0.06 U 8.4 J 0.16 U 0.04 U 0.13 U 0.22 J 1.11 2.8 J 2015-May 0.11 J 4.3 J 202 0.26 J 0.101 2.9 J 14 0.66 J 0.39 J 0.05 U 4.4 J 4.3 J 0.01 U 0.06 J 0.06 J 0.94 J 1.5 J 2015-Nov 0.32J 2.1J 131 0.02U 0.12J 1.3J 4.0J 0.71J 0.16J 0.05U 2.5J 1.7J 0.02J 0.18J 0.20J 1.2J 1.3J 2016-May 0.12 J 11 325 0.06 J 0.05 U 8.7 J it 1.7 J 0.20 J 0.04 J 6.4 J 8.6 J 0.06 U 0.05 U 0.09 J 1.8 J 1.9 J 2016-Nov 0.24 J 21 285 0.24 J 0.20 J 9.3 J 9.8 J 1.8 J 0.69 J 0.04 U 10.4 J 0.62 U 0.06 U 0.05 U 0.06 U 3.0 J 3.5 J 2017-May 0.191 16 340 0.18J 0.111 12 8.0J 1.8J 0.22J 0.07U 8.3J 0.51U 0.20U 0.08U 0.20J 3.7J 2.9J 2017-Dec 0.26 J 15 323 0.07 U 0.08 U 17 3.3 J 2.0 J 0.14 J 0.07 U 8.0 J 0.5 U 0.20 U 0.08 U 0.13 U 2.7 J 1.9 J 2018-Jun 0.09 J 5.5 328 0.09 J 0.06 J 3.9 J 3.2 11 0.26 J 0.07 U 3.1 J 4.5 J 0.05 U 0.05 U 0.05 U 1.7 1.5 J 2018-Dec 0.22 J 15 358 0.06 J 0.08 J 15 3.4 1.11 0.04 J 0.05 U 7.4 J NS 0.05 U 0.05 U 0.05 U 1.6 3 J 2019-Jun 0.24 J 19 608 0.08 J 0.02 U 3.8 21 2 J 0.03 U 0.08 J 7.1 J 8.4 J 0.05 U 0.05 U 0.05 U 3.1 2.9 J 2019-Dec 1 0.03 U 1 28 1 475 1 0.02 U 1 0.04 U 1 23 4.1 5 J 0.03 U 0.05 U 13.4 17 0.22 U 0.02 U 0.05 U 5 5 J 23 of 53 Appendix B MW-8 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS 2001-May NS . NS .1,4-Dioxane NS NS NS NS NS Groundwater Elevation NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov ND ND ND NS ND NS NS 11.03 2003-May ND ND ND NS ND NS NS 11.85 2003-Nov ND ND ND NS ND NS NS 11.63 2004-May ND ND ND NS ND NS NS 11.60 2004-Nov ND ND ND NS ND NS NS 10.92 2005-May ND ND ND NS ND NS NS 11.42 2005-Nov ND ND ND NS ND NS NS 11.81 2006-May ND ND ND NS ND NS NS 11.21 2006-Nov ND ND ND NS ND NS NS 11.56 2007-May ND ND ND NS ND NS NS 11.63 2007-Jun ND ND ND NS ND NS NS NM 2007-Nov 0.7 J ND 0.2 J NS ND NS NS 10.63 2008-May 0.5 J ND 0.2 J NS ND NS NS 11.35 2008-Nov 0.5 J ND 0.2 J NS ND NS NS 10.76 2009-May 0.3 J ND ND NS ND NS NS 10.07 2009-Aug 1.9 ND 0.07 J ND ND NS NS 10.29 2010-Jan ND ND ND 100 U ND NS NS 11.70 2010-May ND ND ND 100 U ND NS NS 12.74 2010-Nov ND ND ND 100 U ND NS NS 11.62 2011-May 0.40 J ND 0.4 J 100 U ND ND NS 11.25 2011-Nov 0.40 J ND ND 100 U ND 3.9 NS 11.76 2012-May 1.1 ND ND 100 U ND 5.2 NS 11.36 2012-Nov 1.6 ND ND 100 U ND 5.5 NS 11.49 2013-May ND 1.2 ND 100 U ND 5.4 NS 11.58 2014-May 1.9 0.27 U 0.25 U 100 U 0.63 U 10.2 NS 12.27 2014-Nov 0.80 J 0.27 U 0.25 U 100 U 1.4 7.7 NS 11.21 2015-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 4.9 NS 12.80 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 2.6 NS 12.74 2016-May 0.90 J 0.27 U 0.25 U 100 U 0.63 U 8.1 NS 12.62 2016-Nov 1.5 0.27 U 0.25 U 100 U 0.63 U 11.7 NS 12.78 2017-May 1.2 0.27 U 0.25 U 100 U 0.63 U 15 NS 12.63 2017-Dec 0.6 J 0.21 U 0.25 U 100 U 0.63 U 22.2 NS 12.46 2018-Jun 0.3 J 0.21 U 0.25 U 100 U 0.63 U 10.5 NS 16.36 2018-Dec 0.48 J 0.02 U 0.25 U 100 U 1.48 21.20 49.30 12.22 2019-Jun 1.17 0.06 J 0.25 U 100 U 0.12 U 28.10 94.70 11.71 2019-Dec 1.13 0.02 U 0.25 U 100 U 0.12 U 32.90 218.00 11.36 24 of 53 Appendix B MW-9A Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 20 2,000 2001-May NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 112 B 0.44 U 0.16 J 3 JB 1.72 U 2.13 J 6.79 U NS 2.36 U 6.61 J 7.15 JB 0.198 U NS 0.586 U 1.66 JB 2010-Jan 0.4J 1.3J 55.4J 0.2J 0.11 2.7J 0.7J 1.3J 1.8J NS 2.5J 0.12U 0.11 0.03U NS 4.9J 7.5J 2010-May 0.22 U 0.3 J 29.4 J 0.02 U 0.2 J 0.3 J 0.2 J 0.11 0.11 NS 2.0 J 0.32 U 0.03 U 0.05 U NS 0.6 J 1.5 J 2010-Nov 0.22 U 0.6 J 32.9 J 0.02 U 0.11 0.03 U 0.2 J 0.03 U 0.01 U NS 1.8 J 0.32 U 0.03 U 0.05 U NS 0.9 J 2.6 J 2011-May 0.14 U 0.60 J 50.7 J 0.02 U 0.05 J 0.17 J 0.09 J 0.29 J 0.16 J NS 0.77 J 0.20 U 0.02 U 0.02 U NS 1.2 J 3.2 J 2011-Nov 0.14 U 0.50 J 43.6 J 0.02 U 0.08 J 0.23 J 0.111 0.05 J 0.16 J NS 0.78 J 0.20 U 0.02 U 0.08 J NS 1.3 J 2.3 J 2012-May 0.03 J 0.50 J 48.9 J 0.07 U 0.14 J 0.18 U 0.06 J 0.111 0.08 U NS 0.23 J 0.17 U 0.1 U 0.07 U NS 0.96 J 0.66 J 2012-Nov 0.06J 0.17J 36.5J 0.07U 0.04J 0.18U 0.08J 0.50J 0.12J NS 1.3J 0.21J 0.1U 0.07U NS 0.25J 4.4J 2013-May 0.04J 0.15J 39.5J 0.03U 0.64J 0.13J 0.04J 0.35J 0.12J NS 0.98J 0.08J 0.03U 0.02U NS 0.07J 3.7J 2014-May 0.02 U 0.05 U 29.3 J 0.03 U 1 0.04 U 0.05 J 0.67 J 0.07 J NS 1.3 J 0.06 U 0.03 U 0.02 U NS 0.07 U 3.4 J 2014-Nov 0.12U 0.14U 32.1J 0.04U 0.31J 0.14U 0.12U 0.51J 0.13U NS 1.2J 0.44U 0.04U 0.13U NS 0.48J 1.3J 2015-May 0.02 U 0.14 U 25.8 J 0.02 U 0.10 J 0.18 J 0.06 J 0.23 J 0.03 U NS 0.87 J 0.22 U 0.01 U 0.02 U NS 0.22 U 2.0 J 2015-Nov 0.20 J 0.14 U 54.3 J 0.02 U 0.18 J 0.12 U 0.10 J 0.46 J 0.16 J NS 1.9 J 0.22 U 0.01 U 0.02 U NS 0.911 4.8 J 2016-May 0.05 U 0.66 U 51.0 J 0.04 U 0.12 J 0.08 J 0.07 J 0.43 J 0.19 J NS 1.2 J 0.54 U 0.06 U 0.05 U NS 0.36 U 3.1 J 2016-Nov 0.05 U 0.66 U 45.3 J 0.04 U 0.13 J 0.06 U 0.113 J 0.16 J 0.06 J NS 1.8 J 0.62 U 0.06 U 0.05 U NS 0.36 U 1.9 J 2017-May 0.06U 0.21 J 39.0 J 0.07 U 0.08 U 0.08 U 0.24 U 0.22 J 0.08 U 0.07 U 1.5 J 0.51 U 0.20 U 0.08 U 0.13 U 0.24 U 2.5 J 2017-Dec 0.1 J 0.36 J 68.4 J 0.07 U 0.09 J 0.36 J 0.29 J 0.68 J 0.35 J 0.07 U 2.1 J 0.5 U 0.20 U 0.08 U 0.13 U 1.5 J 3.7 J 2018-Jun 0.04 J 0.64 J 56.8 0.05 U 0.04 J 0.15 U 0.27 J 0.35 J 0.19 J 0.07 U 1.8 J 0.38 J 0.05 U 0.05 U 0.05 U 1.2 1.6 J 2018-Dec 0.1 J 0.03 J 48.8 0.05 U 0.02 J 0.15 U 0.12 J 0.38 J 0.03 U 0.05 J 2.1 J 0.15 U 0.05 U 0.05 U 0.05 U 0.03 U 3.3 J 2019-Jun 0.03 U 0.42 U 47.7 0.05 U 0.02 U 0.111 0.15 U 0.84 J 0.03 U 0.05 U 1.7 J 0.35 J 0.05 U 0.05 U 0.05 U 0.54 J 4.2 J 2019-Dec 0.05 J 0.08 U 62 0.02 U 0.04 U 0.12 U 0.51 J 2 J 0.06 J 0.05 U 5.2 J 0.62 J 0.22 U 0.06 J 0.16 J 1 8 J 25 of 53 Appendix B MW-9A Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS 1 A 70 NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 12.86 2010-Jan ND ND ND NS ND NS NS 14.94 2010-May ND ND ND NS ND NS NS 13.76 2010-Nov ND ND ND NS ND NS NS 14.50 2011-May ND ND ND NS ND ND NS 13.57 2011-Nov ND ND ND NS ND ND NS 14.46 2012-May ND ND ND NS ND ND NS 13.67 2012-Nov ND ND ND NS ND ND NS 14.60 2013-May ND ND ND NS ND ND NS 13.99 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.97 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.39 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.47 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 15.46 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.58 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.47 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 14.28 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 15.11 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.38 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 15.76 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.67 J 2.71 U 14.04 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 14.62 26 of 53 Appendix B MW-10 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1�4= 2,000 2001-May NS NS NS NS NS NS LN_ Lv-) LJJ NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 76.1 B 0.44 U 0.17J 3 JB 1.72 U 2.34J 6.79 U 0.024 U 2.36 U ND 6.95JB 0.198 U 5.36 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.5J 113 0.2J 0.04U 0.91 0.3J 1.01 1.4J NS 0.8J 0.2J 0.11 0.03U NS 4.5J 2.6J 2010-May 0.22U 0.5J 129 0.11 1 0.6J 0.2J 0.6J 2.0J NS 1.5J 0.6J 0.03U 0.05U NS 3.2J 4.0J 2010-Nov 0.22 U 1.1 J 63.2 J 0.11 0.11 0.11 0.3 J 0.03 U 1.11 NS 4.1 J 0.32 U 0.03 U 0.05 U NS 1.91 2.1 J 2011-May 0.14U 0.52J 89.2J 0.29J 0.8J 0.83J 2.2J 1.7J 1.2J NS 1.11 1.11 0.02U 0.05J NS 3.1J 3.5J 2011-Nov 0.14U 2.5J 43.6J 0.16J 0.08J 0.86J 0.26J 0.18J 1.91 NS 1.3J 0.62J 0.02U 0.05J NS 9.2J 1.7J 2012-May 0.04 J 1.1 J 87.5 J 0.09 J 0.05 J 0.50 J 0.45 J 0.37 J 0.74 J NS 2.3 J 0.93 J 0.1 U 0.07 U NS 5.9 J 0.48 U 2012-Nov 0.09 J 1.5 J 132 0.08 J 0.08 J 0.80 J 0.86 J 0.64 J 0.43 J NS 1.6 J 2.1 J 0.1 U 0.07 U NS 4.1 J 3.1 J 2013-May 0.04J 0.74J 169 0.08J 0.06J 1.11 0.33J 0.68J 0.23J NS 1.5J 1.7J 0.03U 0.02U NS 4.6J 2.1J 2014-May 0.02 U 0.05 U 58.9 J 0.04 J 0.17 J 0.83 J 0.44 J 0.38 J 0.10 J NS 1.0 J 0.06 U 0.03 U 0.02 U NS 2.9 J 1.3 J 2014-Nov 0.24J 0.84J 100 0.04J 0.21J 1.11 0.49J 0.76J 0.13U NS 1.8J 1.8J 0.04U 0.13U NS 4.4J 1.4J 2015-May 0.02 U 0.73 J 63.2 J 0.04 J 0.08 J 1.4 J 0.31 J 0.27 J 0.05 J NS 1.20 J 1.10 J 0.01 U 0.02 U NS 4.90 J 1.10 J 2015-Nov 0.17J 1.2J 119 0.05J 0.62J 1.7J 0.38J 0.75J 0.111 NS 1.7J 2.5J 0.01U 0.02U NS 5.3J 2.8J 2016-May 0.27J 10 344 0.05J 0.13J 9.2J 0.92J 0.97J 0.12J NS 4.1J 4.6J 0.06U 0.05U NS 8.7J 2.1J 2016-Nov 0.21 J 7 J 260 0.10 J 0.09 J 11 1.0 J 0.70 J 0.06 U NS 6.7 J 9.4 U 0.06 U 0.05 U NS 8.5 J 1.61 U 2017-May 0.31 J 8 J 200 0.07 U 0.17 J 12 0.87 J 0.70 J 0.08 U 0.07 U 6.3 J 5.1 J 0.20 U 0.08 U 0.13 U 8.5 J 1.9 J 2017-Dec 0.15J 2.6J 184 0.07U 0.15J 4.7J 0.56J 0.95J 0.76J 0.07U 3.4J 3.1J 0.20U 0.08U 0.13U 9.11 3.8J 2018-Jun 0.12J 2.2J 161 0.06J 0.04J 4.1J 0.42J 0.69J 0.18J 0.07U 3.3J 4.3J 0.05U 0.05U 0.05U 8 0.32J 2018-Dec 0.03 U 9 368 0.05 J 0.14 J 14 1.8 0.96 J 0.03 J 0.05 U 12.1 7.9 J 0.05 U 0.05 U 0.05 U 8.1 1.5 J 2019-Jun 0.21J 9 321 0.12J 0.111 1.9 19 0.8J 0.03U 0.05U 9.3J 4.1J 0.05U 0.18J 0.05U 9.5 2.7J 2019-Dec 0.18 J 5.5 267 0.02 J 0.05 J 21 2.6 5 J 0.05 J 0.05 J 18.0 7.4 J 0.22 U 0.05 J 0.05 U 11 6 J 27 of 53 Appendix B MW-10 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina ■ .• c �. GWPS A A 7n NE nnq mr-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 9.35 2010-Jan ND ND ND NS ND NS NS 13.61 2010-May ND ND ND NS ND NS NS 12.50 2010-Nov ND ND ND NS ND NS NS 12.78 2011-May ND ND ND NS ND ND NS 12.33 2011-Nov ND ND ND NS ND ND NS 12.69 2012-May ND ND ND NS ND ND NS 12.21 2012-Nov ND ND ND NS ND ND NS 12.68 2013-May ND ND ND NS ND ND NS 12.28 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.68 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.59 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 13.20 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 14.05 2016-May 0.50 J 0.27 U 0.5 J NS 1.9 14.3 NS 13.42 2016-Nov 0.60 J 0.27 U 0.4 J NS 1.7 8.8 NS 13.42 2017-May 0.40 J 0.27 U 0.25 U 4790 1.1 6.4 NS 13.36 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.9 J 0.39 U NS 13.05 2018-Jun 0.24 U 0.21 U 0.4 J 1182 2 3.4 NIA 13.37 2018-Dec 1.57 0.34 0.31 J 328 J 2.2 25.42 5.40 13.72 2019-Jun 2.26 0.4 0.35 J 849 J 1.77 29.00 10.70 12.82 2019-Dec 1.28 0.21 0.25 1, 849 J 0.33 31.20 10.50 12.79 28 of 53 Appendix B MW-11 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 20 0.2 2,000 2001-May NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 39.8 B 0.44 U 0.3J 3.09 JB 1.72 U 2.44J 6.79 U 0.024 U 2.75J 4.22J 6.92JB 0.198 U 6.02 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.17U 23.4J 0.3J 0.2J 0.10U 0.5J 0.8J 0.2J NS 2.2J 0.12U 0.04U 0.03U NS 1.3J 2.9J 2010-May 0.7J 0.04U 14.2J 0.11 0.11 0.3J 0.3J 0.2J 0.2J NS 1.8J 0.32U 0.11 0.05U NS 1.01 2.0J 2010-Nov 0.22 U 0.6 J 31.4 J 0.2 J 0.2 J 0.11 0.3 J 0.03 U 0.2 J NS 1.6 J 0.32 U 0.03 U 0.05 U NS 0.6 J 3.2 J 2011-May 0.14U 0.10U 19.2J 0.31J 0.17J 0.23J 0.26J 0.67J 0.11 NS 1.2J 0.20U 0.02U 0.02U NS 0.54J 2.1J 2011-Nov 0.14U 0.23J 17.3J 0.101 0.13J 0.04J 0.20J 0.091 0.12J NS 1.2J 0.20U 0.02U 0.12J NS 0.551 1.91 2012-May 0.06 J 0.41 J 23.9 J 0.08 J 0.22 J 0.18 U 0.22 J 0.50 J 0.09 J NS 3.4 J 0.72 J 0.1 U 0.07 U NS 0.78 J 1.7 J 2012-Nov 0.08J 0.82J 19.3J 0.29J 0.64J 0.25J 0.53J 0.70J 0.49J NS 2.3J 1.11 0.1U 0.07U NS 0.44J 6.4J 2013-May 0.05J 0.58J 19.8J 1 0.97J 0.78J 0.73J 1.4J 0.53J NS 2.4J 1.11 0.03J 0.14J NS 0.35J 3.8J 2014-May 0.02 U 0.05 U 18.3 J 0.03 U 0.25 J 0.20 J 0.19 J 0.37 J 0.04 J NS 2.7 J 0.06 U 0.03 U 0.02 U NS 0.07 U 1.3 J 2014-Nov 0.24J 0.17J 19.7J 0.24J 0.58J 0.34J 0.66J 0.96J 0.13U NS 4.5J 0.44U 0.04J 0.13U NS 0.34J 3.1J 2015-May 0.02U 0.46J 24.4J 0.18J 0.33J 1.11 0.43J 0.901 0.101 NS 3.20J 1.40J 0.01U 0.30J NS 0.22U 3.0J 2015-Nov 0.12J 0.24J 21.3J 0.06J 0.45J 0.65J 0.52J 1.11 0.091 NS 4.1J 0.911 0.01U 0.03J NS 0.54J 4.5J 2016-May 0.05 U 0.66 U 23.6 J 0.05 J 0.16 J 0.85 J 0.30 J 0.51 J 0.07 J NS 3.6 J 0.77 J 0.06 U 0.05 U NS 0.36 U 1.9 J 2016-Nov 0.05 U 1.3 J 31.3 J 0.12 J 0.50 J 0.43 J 0.70 J 0.35 J 0.24 J NS 5.2 J 1.4 J 0.06 U 0.05 U NS 0.59 J 2.4 J 2017-May 0.07 J 0.44 J 20.3 J 0.07U 0.15 J 0.08 U 0.28 J 3.5 J 0.08 U 0.07 U 9.3 J 0.74 J 0.20 U 0.08 U 0.13 U 0.24 U 2.5 J 2017-Dec 0.07 J 2.2 J 42.4 J 0.09 J 0.08 U 0.8 J 0.73 J 0.66 J 0.111 0.07 U 4.8 J 1.8 J 0.20 U 0.08 U 0.13 U 1.5 J 3.2 J 2018-Jun 0.11 3.6J 78.3 0.11 0.08J 1.3J 1.4J 0.46J 0.13J 0.07U 5.3J 2J 0.05U 0.06J 0.05U 2.7 2.2J 2018-Dec 0.06 J 3.2 J 55 0.05 U 0.1 J 0.56 J 1 0.3 J 0.04 J 0.05 U 5.7 J 1.1 J 0.05 U 0.05 U 0.05 U 1.5 1.3 J 2019-Jun 0.03 J 5.5 72.2 0.22 J 0.12 J 0.9 J 0.77 J 0.31 J 0.03 U 0.05 U 3.8 J 1.2 J 0.05 U 0.05 U 0.05 U 3.2 6 J 2019-Dec 0.36 J 4.6 J 131 0.04 J 0.04 U 0.12 U 2.4 2 J 0.05 J 0.05 U 14.6 3.5 J 0.22 U 0.02 J 0.19 J 3 1.4 J 29 of 53 Appendix B MW-11 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina GWPS 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 8.49 2010-Jan ND ND ND NS ND NS NS 11.52 2010-May ND ND ND NS ND NS NS 11.02 2010-Nov ND ND ND NS ND NS NS 8.35 2011-May ND ND ND NS ND ND NS 10.26 2011-Nov ND ND ND NS ND ND NS 11.24 2012-May ND ND ND NS ND 18.4 NS 10.33 2012-Nov ND ND ND NS ND 6.2 NS 10.94 2013-May ND ND ND NS ND ND NS 10.32 2014-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.82 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 2.7 NS 11.15 2015-May 0.24 U 0.27 U 0.3 J NS 0.63 U 6.1 NS 11.23 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 2.5 NS 12.06 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1.5 NS 11.47 2016-Nov 0.24 U 0.27 U 0.3 J NS 0.63 U 0.39 U NS 11.29 2017-May 0.24U 0.27 U 0.25 U 100U 0.63U 0.9 NS 11.76 2017-Dec 1 0.21 U 0.6 J 100 U 0.63 U 17 NS 11.89 2018-Jun 0.9 J 0.21 U 0.5 J 100 U 0.63 U 16 NS 11.62 2018-Dec 0.48 J 0.08 J 0.25 U 100 U 0.12 U 8.02 8.15 11.69 2019-Jun 1.89 0.18 J 0.25 U 100 U 0.69 17.30 9.21 9.95 2019-Dec 2.56 0.27 0.52 J 100 U 0.57 43.80 25.20 10.87 30 of 53 Appendix B MW-12S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1�4= 2,000 2001-May NS NS NS NS NS NS LN_ Lv-) LJJ NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 56.6 B 0.44 U 0.158 U 2.48 JB 1.72 U 1.86J 6.79 U 0.024 U 2.43J 2.78 U 6.87JB 0.198 U 4 JB 0.586 U 1.29 U 2010-Jan 0.06J 0.17U 98.5J 0.06U 0.2J 0.10U 0.2J 0.7J 0.4J NS 0.91 0.2J 0.11 0.03U NS 2.4J 2.8J 2010-May 0.22U 0.4J 39.2J 0.11 0.2J 0.6J 0.2J 0.3J 1.11 NS 0.91 0.32U 0.03U 0.05U NS 3.7J 1.11 2010-Nov 0.8J 5.3J 177 0.11 0.11 1.7J 0.8J 1.11 1.91 NS 4.1J 1.3J 0.11 0.05U NS 4.4J 3.1J 2011-May 0.47J 5.9J 346 0.02U 0.11 2.6J 1.51 1.5J 0.83J NS 6.8J 1.7J 0.02U 0.08J NS 2.9J 3.5J 2011-Nov 0.51 J 11 467 0.02 U 0.06 J 14 0.84 J 0.53 J 0.64 J NS 7.6 J 2.5 J 0.02 U 0.04 J NS 4.8 J 1.8 J 2012-May 0.24 J 24 291 0.07 U 0.05 J 6.5 J 0.72 J 0.87 J 0.90 J NS 5.6 J 3.7 J 0.1 U 0.07 U NS 6.9 J 0.48 U 2012-Nov 0.3J 15 504 0.07U 0.13J 16 1.11 0.911 0.65J NS 7.3J 4.1J 0.1U 0.07U NS 6.4J 4.1J 2013-May 0.18 J 19 342 0.03 J 0.68 J 19 0.88 J 1.5 J 0.07 J NS 4.8 J 5.7 J 0.03 U 0.02 U NS 7.8 J 1.9 J 2014-May 0.10 J 11 368 0.03 U 0.09 J 9.0 J 0.82 J 0.63 J 0.02 U 0.01 U 5.9 J 1.3 J 0.03 U 0.02 U 0.06 U 4.1 J 2.0 J 2014-Nov 0.34J 36 515 0.04U 0.26J 21 1.11 1.2J 0.13U 0.06U 6.7J 0.44U 0.04U 0.13U 0.18J 11.01 1.91 2015-May 0.70 J 15 292 0.02 U 0.09 J 8.9 J 0.81 J 0.35 J 0.03 U 0.05 U 4.90 J 3.40 J 0.01 U 0.02 U 0.12 J 5.10 J 13 2015-Nov 0.14J 2.8J 69.2J 0.04J 1 2.7J 0.30J 1.5J 0.191 0.05U 2.3J 0.911 0.03J 0.07J 0.35J 3.2J 6.0J 2016-May 0.26 J 38 550 0.04 U 0.14 J 27 1.7 J 1.6 J 0.07 J 0.04 J 6.6 J 6.7 J 0.06 U 0.05 U 0.33 J 16.5 J 2.0 J 2016-Nov 0.28 J 42 654 0.10 J 0.15 J 28 2.0 J 1.5 J 0.06 J 0.04 U 8.9 J 0.62 U 0.06 U 0.05 U 0.06 U 16.4 J 2.0 J 2017-May 0.29 J 52 507 0.07 U 0.08 U 28 1.8 J 1.11 0.08 U 0.07 U 7.6 J 9.9 J 0.20 U 0.08 U 0.13 U 17.9 J 1.5 J 2017-Dec 0.25 J 41 541 0.07 U 0.15 J 31 2.0 J 2.4 J 0.24 J 0.07 U 6.9 J 0.5 U 0.20 U 0.08 U 0.24 J 21.3 J 5.5 J 2018-Jun 0.18 J 37 466 0.07 J 0.13 J 26 1.9 0.76 J 0.6 J 0.07 U 5.6 J 0.53 U 0.05 U 0.05 U 0.05 U 16 2 J 2018-Dec 0.17 J 22 398 0.05 U 0.02 U 24 1.6 1.11 0.03 U 0.05 U 6.6 J 8.1 J 0.05 U 0.05 U 0.05 U 17.5 1.2 J 2019-Jun 2.9 54 759 0.08 J 0.02 U 3.2 55 2.5 J 0.03 U 0.05 U 9.11 11 0.05 U 0.07 J 0.05 U 40 4.4 J 2019-Dec j 0.31 J j 29 589 0.02 U 0.04 U 44 3.3 3 J 0.03 U 0.05 U 14.7 16 0.22 U 0.02 U 0.60 J 40 8 J 31 of 53 Appendix B MW-12S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. GWPS . .1,4-Dioxane Groundwater Elevation 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 8.45 2010-Jan ND ND ND ND NS NS 11.71 2010-May ND ND ND NS ND NS NS 12.03 2010-Nov ND ND ND NS ND NS NS 11.25 2011-May ND 0.6 J 0.6 J NS ND ND NS 11.00 2011-Nov 0.30 J 0.4 J 1.2 J NS ND 4.2 NS 11.51 2012-May 1.2 1.1 8.5 NS 0.8 2.5 NS 11.06 2012-Nov 0.70 J ND 4.1 J NS 1.9 10.9 NS 10.70 2013-May 1.1 ND 5.9 J NS 3 3.3 NS 10.50 2014-May 0.4 J 0.27 U 0.7 J 230 J 1.1 5.5 NS 10.93 2014-Nov 1.1 0.27 U 1.7 J 100 U 3.4 10 NS 10.58 2015-May 0.50 J 0.27 U 0.5 J 100 U 1.7 7.1 NS 11.32 2015-Nov 0.24 U 0.27 U 0.25 U 100 U 0.63 U 1.8 NS 11.98 2016-May 1.4 0.27 U 0.8 J 346 J 3.7 46.2 NS 11.64 2016-Nov 1.9 0.27 U 1.6 J 240 J 4.3 49 NS 11.38 2017-May 1.7 0.27 U 0.25 U 537J 4.3 36.4 NS 11.58 2017-Dec 2 0.21 U 1.4 J 100 U 3.7 58.4 NS 12.04 2018-Jun 1.4 0.21 U 0.6 J 298 J 2.9 32.7 NS 11.58 2018-Dec 1.48 0.13 J 0.34 J 115 J 2.21 38.75 8.82 12.03 2019-Jun 2.52 0.19 J 0.4 J 100 U 3.33 64.90 32.80 11.46 2019-Dec 2.12 0.15 J 0.34 J 100 U 1.25 40.10 27.40 10.92 32 of 53 Appendix B MW-13 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 OIL NEL2 2,000 2001-May NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 411 JB 0.44 U 0.16 J 1.77 JB 1.72 U 1.33 J 6.79 U NS 2.44 J 2.78 U 6.91 JB 0.198 U NS 0.586 U 4.63 JB 2010-Jan 0.06J 2.4J 82.8J 0.3J 0.2J 0.7J 1.3J 1.2J 3.2J NS 1.6J 0.5J 0.11 0.03U NS 4.9J 8.5J 2010-May 0.22U 1.4J 86.7J 0.3J 0.4J 0.8J 0.91 0.5J 1.81 NS 1.7J 0.32U 0.03U 0.05U NS 2.4J 7.5J 2010-Nov 0.22U 1.81 106 0.3J 0.2J 0.91 1.01 0.8J 3.1J NS 2.2J 0.8J 0.03U 0.05U NS 3.6J 8.5J 2011-May 0.14U 0.29J 92.3J 0.12J 0.16J 0.51J 1.2J 2.1J 0.8J NS 2.1J 0.38J 0.02U 0.04J NS 1.01 32 2011-Nov 0.14U 0.52J 67.8J 0.14J 0.13J 0.57J 0.60J 0.82J 0.93J NS 1.3J 0.78J 0.02U 0.07J NS 1.4J 3.2J 2012-May 0.101 0.62J 74.2J 0.12J 0.18J 0.61J 1.51 0.77J 1.01 NS 3.4J 0.64J 0.1U 0.07U NS 2.2J 8.1J 2012-Nov 0.101 0.76J 76.6J 0.13J 0.12J 0.68J 0.46J 1.01 1.5J NS 1.7J 1.01 0.1U 0.07U NS 3.0J 3.3J 2013-May 0.03J 0.34J 69.7J 0.12J 0.21J 0.59J 0.47J 0.63J 0.93J NS 0.84J 0.83J 0.03U 0.02U NS 2.0J 3.5J 2014-May 0.02 U 0.05 U 52.4 J 0.04 J 1 0.46 J 0.32 J 1.0 J 0.40 J NS 1.2 J 0.06 U 0.03 U 0.02 U NS 1.4 J 2.4 J 2014-Nov 0.12U 0.37J 69.9J 0.08J 0.18J 0.35J 0.47J 0.40J 0.52J NS 1.11 0.62J 0.04U 0.13U NS 1.3J 4.6J 2015-May 0.02 U 0.41 J 57.1 J 0.02 U 0.10 J 0.63 J 0.28 J 0.60 J 0.111 NS 1.40 J 0.59 J 0.01 U 0.03 J NS 1.20 J 1.30 J 2015-Nov 0.16J 0.26J 57.7J 0.03J 1 0.42J 0.35J 2.0J 1.01 NS 2.5J 0.63J 0.01U 0.06J NS 5.8J 3.6J 2016-May 0.12J 0.66U 46.2J 0.06J 0.23J 0.81J 0.26J 1.3J 2.1J NS 1.4J 0.73J 0.06U 0.07J NS 10.5J 4.5J 2016-Nov 0.11 J 0.85 J 53.1 J 0.04 U 0.05 J 0.26 J 0.94 J 0.50 J 0.08 J NS 3.4 J 1.11 0.06 U 0.05 U NS 1.5 J 1.61 U 2017-May 0.16J 1.3J 36.3J 0.07U 0.08U 0.15J 0.50J 0.69J 0.17J 0.07U 1.8J 0.77J 0.20U 0.08J 0.13U 0.911 1.91 2017-Dec 0.13J 1.5J 56.3J 0.07U 0.08U 0.4J 0.37J 0.7J 1.11 0.07U 2.3J 0.77J 0.20U 0.08U 0.13U 6.6J 2.3J 2018-Jun 0.13 J 5 38.7 0.06 J 0.04 J 0.15 U 0.85 J 0.89 J 2.8 J 0.07 U 2.1 J 1.2 J 0.05 U 0.05 U 0.05 U 15 1.6 J 2018-Dec 0.13 J 1.1 J 47.5 0.05 U 0.06 J 0.31 J 0.54 J 0.38 J 0.16 J 0.05 U 3.9 J 0.85 J 0.05 U 0.05 U 0.05 U 1.3 0.911 2019-Jun 0.1 J 2.3 J 45.8 0.06 J 0.05 J 0.75 J 0.3 J 0.56 J 0.111 0.05 U 2.2 J 0.73 J 0.05 U 0.12 J 0.05 U 1.5 4.7 J 2019-Dec 0.11 J 0.08 U 77 0.02 U 0.04 U 0.12 U 0.49 J 1.47 U 0.16 J 0.05 U 8.2 J 1.4 J 0.22 U 0.04 J 0.05 U 1 7 J 33 of 53 Appendix B MW-13 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS 1 A 70 NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND ND ND NS NS 9.35 2010-Jan ND ND ND NS ND NS NS 12.45 2010-May ND ND ND NS ND NS NS 11.22 2010-Nov ND ND ND NS ND NS NS 12.44 2011-May ND ND ND NS ND ND NS 12.01 2011-Nov ND ND ND NS ND ND NS 12.10 2012-May ND ND ND NS ND ND NS 11.86 2012-Nov ND ND ND NS ND ND NS 11.51 2013-May ND ND ND NS ND ND NS 10.77 2014-May ND 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.29 2014-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 10.57 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 11.69 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.24 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.33 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.17 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.35 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.69 2018-Jun 0.24 U 0.21 U 0.25 U 158 J 0.63 U 0.39 U NS 13.03 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.12 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 1.47 2.71 U 12.21 2019-Dec 0.24 U 0.02 U 0.25 U 592 J 0.12 U 0.39 U 2.71 U 10.94 34 of 53 Appendix B MW-14D Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 Nk 2,000 2001-May NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 13.9 JB 0.44 U 0.4 J 4.24 JB 1.72 U 1.29 U 6.79 U NS 2.36 U 2.78 U 6.77 JB 0.198 U NS 0.586 U 1.29 U 2010-Jan 0.11 0.2J 13.1J 0.06U 1 1.8J 0.2J 2.4J 1.2J NS 2.14J 0.12U 1.11 0.03U NS 1.4J 21 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov 0.14 U 0.32 J 9.9 J 0.02 U 0.43 J 0.04 U 0.08 J 0.66 J 0.17 J NS 1.4 J 0.20 U 0.02 U 0.02 U NS 0.3 J 3.2 J 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov 0.91 0.24J 11.2J 0.07U 0.43J 0.4J 0.101 1.2J 0.22J NS 1.7J 0.23J 0.1U 0.07U NS 0.41J 6.1J 2013-May 0.4 J 0.08 J 10.2 J 0.03 U 2 0.27 J 0.04 J 0.84 J 0.07 J NS 0.96 J 0.27 J 0.03 U 0.02 U NS 0.07 U 4.2 J 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May 0.06 J 0.23 J 10.7 J 0.02 U 0.50 J 0.12 U 0.05 J 1.3 J 0.05 J NS 1.1 J 0.22 U 0.01 U 0.02 U NS 0.22 U 11 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.09 J 0.07 U 9.90 J 0.07 U 0.25 J 0.08U 0.24 U 1.2 J 0.08U 0.07 U 1.7 J 0.51 U 0.20 U 0.08 U 0.13 U 1.4 J 8.4 J 2017-Dec 0.08 J 0.58 J 10.9 J 0.07 U 0.19 J 0.08 J 0.24 U 0.6 J 0.18 J 0.07 U 3.0 J 0.51 U 0.20 U 0.08 U 0.21 J 0.59 J 7.4 J 2018-Jun 0.03 U 0.24 J 10.2 0.05 U 0.22 J 0.15 U 0.09 J 0.77 J 0.12 J 0.07 U 0.99 J 0.36 J 0.05 U 0.05 U 0.05 U 0.05 J 4.7 J 2018-Dec 0.04 J 0.03 U 8.5 J 0.05 U 0.06 J 0.15 U 0.07 J 0.41 J 0.03 U 0.05 U 1.4 J 0.15 U 0.05 U 0.05 U 0.05 U 0.03 U 2 J 2019-Jun 0.04 J 0.18 J 10.1 0.05 U 0.05 J 0.05 J 0.15 U 0.94 J 0.03 U 0.05 U 1.8 J 0.35 J 0.05 U 0.05 U 0.05 U 0.03 U 9.7 J 2019-Dec 0.22 J 0.08 U 9 J 0.02 U 0.06 J 0.12 U 0.14 J 2 J 0.06 J 0.05 U 2.5 J 0.31 J 0.22 U 0.02 J 0.2 J 0.51 9 J 35 of 53 Appendix B MW-14D Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 10.50 2010-Jan ND ND ND NS ND NS NS 9.49 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov ND ND ND NS ND ND NS 11.71 2012-May NS NS NS NS NS NS NS NM 2012-Nov ND ND ND NS ND ND NS 11.86 2013-May ND ND ND NS ND ND NS 11.44 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.43 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS ^'"j 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 12.05 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 11.84 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.15 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 12.21 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 11.30 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 11.35 36 of 53 Appendix B MW-14S Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 1 1,000 15 1 2 2OIL,000 2001-May NS NS NS NS NS NS LN_ NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug 2.95 U 4.9 U 111 0.44 U 0.23 J 2.8 JB 1.72 U 1.34 J 6.79 U NS 2.36 U 2.78 U 7.2 JB 0.198 U NS 0.586 U 1.48 JB 2010-Jan 0.2J 1.3J 100 0.6J 0.2J 2.6J 0.4J 2.4J 21 NS 1.01 0.4J 0.11 0.03U NS 35 4.7J 2010-May 0.22U 0.04U 107 0.11 0.11 0.5J 0.2J 0.11 1.5J NS 1.11 0.32U 0.03U 0.05U NS 3.3J 1.2J 2010-Nov 0.22U 1.6J 177 0.2J 0.3J 0.5J 0.3J 0.11 2.2J NS 1.91 0.32U 0.03U 0.05U NS 8.5J 2.6J 2011-May 0.14U 1.5J 127 0.2J 0.12J 0.48J 0.18J 0.81J 4.4J NS 0.86J 0.44J 0.02U 0.04J NS 11.81 2.6J 2011-Nov 0.14 U 1.7 J 223 0.29 J 0.29 J 1.3 J 0.42 J 0.59 J 3.2 J NS 2 J 0.33 J 0.02 U 0.05 J NS 8.4 J 4.7 J 2012-May 0.34J 4.0J 105 2 0.18J 2.0J 3.4J 1.91 11 NS 5.2J 1.4J 0.1U 0.07U NS 31 6.2J 2012-Nov 0.14J 3.7J 74.7J 0.39J 0.36J 1.2J 1.6J 0.57J 7.9J NS 1.91 0.94J 0.1U 0.07U NS 22.7J 4.6J 2013-May 0.15J 5.0J 69.4J 0.48J 0.18J 5.8J 2.4J 1.8J 0.75J NS 4.4J 5.5J 0.03U 0.30J NS 8.2J 5.6J 2014-May 0.17J 0.30J 90.91 0.03U 2 2.1J 0.24J 1.8J 0.42J NS 1.6J 0.06U 0.03U 0.13J NS 1.4J 2.6J 2014-Nov 0.21J 6.9J 207 0.08J 0.26J 14 1.8J 1.11 1.4J NS 6.9J 0.16U 0.04U 0.15J NS 4.3J 5.7J 2015-May 0.18 J 1.2 J 54.3 J 0.04 J 0.86 J 0.82 J 0.79 J 0.55 J 0.56 J NS 1.60 J 0.28 J 0.01 U 0.02 J NS 1.60 J 16 2015-Nov 0.12J 2.4J 93.8J 0.48J 0.66J 8.4J 1.6J 3.6J 13 NS 4.1J 0.22U 0.02J 0.13J NS 27 35 2016-May 0.12J 0.84J 52.1J 0.13J 0.44J 3.0J 0.61J 1.8J 2.7J NS 2.5J 0.54U 0.06U 0.07J NS 5.7J 12 2016-Nov 0.08J 2.1J 73.1J 0.06J 0.29J 1.2J 1.3J 0.62J 1.01 NS 3.0J 0.69J 0.06U 0.05U NS 2.6J 6.8J 2017-May 0.14 J 0.90 J 75.0 J 0.101 0.61J 2.1 J 0.74 J 1.4 J 2.1 J 0.07 U 2.6 J 0.51 U 0.20 U 0.08 U NA 5.9 J 13 2017-Dec 0.111 2.6J 92.0J 0.32J 0.44J 9.11 1.6J 3.8J 8.6J 0.07U 4.5J 0.57J 0.20U 0.12J 0.24J 20.1J 21 2018-Jun 0.03 U 2.4 J 65 0.05 U 0.11 0.84 J 0.59 J 0.56 J 0.69 J 0.07 U 1.5 J 11 0.05 U 0.06 J 0.05 U 2.1 5 J 2018-Dec 0.06 J 0.59 J 49.3 0.05 U 0.07 J 0.48 J 0.36 J 0.52 J 0.73 J 0.05 J 1.8 J 0.15 U 0.05 U 0.05 U 0.05 U 2.3 4.6 J 2019-Jun 0.06 J 2.2 J 98.9 0.07 J 0.05 J 0.69 J 2 J 0.92 J 0.72 J 0.05 U 4 J 1.11 0.05 U 0.05 J 0.05 U 4.2 6.2 J 2019-Dec 0.18 J 1 0.58 J 332 0.02 J 0.04 U 1.11 1.8 =2 J 0.22 J 0.05 U 14.2 2.7 J 0.22 U 0.31 J 0.16 J 4 3 J 37 of 53 Appendix B MW-14S Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS 1 A70 NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug ND ND ND NS ND NS NS 11.90 2010-Jan ND ND ND NS ND NS NS 12.51 2010-May ND ND ND NS ND NS NS 11.41 2010-Nov ND ND ND NS ND NS NS 12.59 2011-May ND ND ND NS ND ND NS 12.03 2011-Nov ND ND ND NS ND 0.9 NS 12.03 2012-May ND ND ND NS ND 14 NS 11.99 2012-Nov ND ND ND NS ND 0.7 NS 11.49 2013-May 0.40 J ND 1.4 J NS ND 7.4 NS 11.00 2014-May 0.27 U 0.3 J NS 0.63 U 0.8 NS 11.49 2014-Nov 0.50 J 0.27 U 1.6 J NS 0.63 U 17.3 NS 10.84 2015-May 0.24 U 0.27 U 0.25 U NS 0.63 U 1 NS 11.86 2015-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.70 2016-May 0.24 U 0.27 U 0.25 U NS 0.63 U 0.39 U NS 12.65 2016-Nov 0.24 U 0.27 U 0.25 U NS 0.63 U 0.6 NS 12.09 2017-May 0.24U 0.27 U 0.25 U 100U 0.63U 0.39U NS 12.50 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.60 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 12.80 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.36 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.13 J 0.81 J 2.71 U 12.60 2019-Dec 1.47 0.11 J 0.46 J 100 U 2.53 10.50 3.71 11.09 38 of 53 Appendix B MW-15 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 4 2 10 1 1,000 15 1 2,000 2001-May NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.101 6.4 J 88.7 J 0.42 J 0.20 J 2.9J 0.32 1.4 J 10 0.07 U 1.11 1.8 J 0.20 U 0.08U 0.13U 71 4.9 J 2017-Dec 0.08J 2.8J 134 0.33J 0.12J 2.9J 0.36J 0.6J 5.6J 0.07U 0.94J 1.8J 0.20U 0.08U 0.13U 34 5.8J 2018-Jun 0.04J 3J 99.5 0.27J 0.17J 2.6J 0.33J 1.11 6.8J 0.07U 11 0.96J 0.05U 0.07J 0.05U 21.2 2.4J 2018-Dec 0.05 J 1.4 J 95.2 0.05 J 0.08 J 0.15 U 0.15 J 0.44 J 0.11 0.05 U 2.1 J 0.15 U 0.05 U 0.05 U 0.05 U 3.5 0.87 J 2019-Jun 0.04 J 1.6 J 109 0.111 0.07 J 0.26 J 0.46 J 0.4 J 0.03 U 0.05 U 1.3 J 0.51 J 0.05 U 0.05 U 0.05 U 5.7 5.1 J 2019-Dec 0.06 J 1 0.10 J 255 0.12 J 0.04 U 0.12 U 0.71 J 1.47 U 0.32 J 0.05 U 3 J 4.1 J 0.22 U 0.10 J 0.10 J 15 13 39 of 53 Appendix B MW-15 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS 1 A 70 NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.54 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.06 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 14.37 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 14.47 2019-Jun 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 13.28 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 3.69 13.34 40 of 53 Appendix B MW-16 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina GWPS 1 10 A 1 1,000 15 JL 1 20 2,000 .3 1,000 2001-May ivy NS NS NS NS NS NS NS ivy NS NS NS NS NS 2001-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS N' NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS N' N� NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS N' N� NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS N' N� NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS N' N� NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS N'- NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS N� NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS N� NS NS NS NS NS NS NS NS NS NS 2010-Jan NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS W NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May Nc- NS NS NS NS NS NS NS Nc- NS NS NS NS NS NS Nc- Nc- 2017-Dec 0.14J 3.2J 251 0.16J 0.21J 6.9J 0.86J 2.6J 3.11 0.07U 1.7J 3.01 0.20U 0.131 0.18J 12.0J 6.9J 2018-Jun 0.04J 2.4J 196 0.07J 0.131 2.5J 0.55J 1.2J 0.8J 0.07U 0.97J 2.7J 0.05U 0.11 0.43J 8.8 5.4J 2018-Dec 0.05J 3.2J 67.7 0.091 0.15J 1.51 0.531 0.25J 0.12J 0.05U 1.51 2.1J 0.05U 0.05U 9.1 0.84J 2019-Jun 0.46J 5 418 0.16J 0.131 0.94J 2.9J 1.4J 0.71J 0.05U 7J 4.3J 0.05U 0.091 0.05U 11.9 5J 2019-Dec 0.18 J 3.9 J 394 0.05 J 5 0.9 J 2.0 J 0.08 J 0.05 U 2.8 J 3.4 J 0.22 U 0.09 J 0.05 U 11.2 2.4 J 41 of 53 Appendix B MW-16 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan NS NS NS NS NS NS NS NM 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May NS NS NS NS NS NS NS NM 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS NM 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS NM 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U NM 2019-Jun 0.24 U 0.04 J 0.25 U 100 U 0.12 U 0.59 J 2.71 U NM 2019-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U NM 42 of 53 Appendix B MW-17 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina ... GWPS 1 10 1 1,000 15 1 2,000 2001-May NS NS NS NS NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.3J 3.6J 51.5J 1 2 3.3J 1.2J 4.8J 5.3J NS 5.2J 2.8J 0.2J 0.03U NS 15.7J 15 2010-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2011-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2012-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2013-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2014-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2015-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2016-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2017-May 0.06U 0.41J 136 0.13J 0.14J 1.5J 0.33J 0.35J 0.34J 0.07U 3.0J 0.51U 0.20U 0.08U 0.13U 4.5J 3.2J 2017-Dec 0.091 2.4J 84.2J 0.31J 0.08U 2.4J 0.28J 0.77J 1.7J 0.07U 2.2J 1.2J 0.20U 0.08U 0.22J 7.1J 5.0J 2018-Jun 0.04 J 0.54 J 89.1 0.16 J 0.111 2.9 J 0.33 J 0.88 J 0.97 J 0.07 U 2.4 J 0.89 J 0.05 U 0.05 U 0.57 J 5.2 8.6 J 2018-Dec 0.04 J 0.03 U 256 0.05 J 0.04 J 0.94 J 0.32 J 0.12 J 0.06 J 0.05 U 5.2 J 0.15 U 0.05 U 0.05 U 0.05 U 1.2 1.5 J 2019-Jun 0.03 U 1.1 J 39 0.05 U 0.04 J 0.2 J 0.18 J 0.17 J 0.03 U 0.05 U 1.4 J 0.68 J 0.05 U 0.06 J 0.05 U 2.9 3 J 2019-Dec 0.06 J 0.08 U 49.2 0.04 J 0.04 U 1.2 J 0.8 J 5.0 J 0.12 J 0.05 U 2.6 J 0.65 J 0.22 U 0.06 J 0.05 U 3.3 1.8 J 43 of 53 Appendix B MW-17 Selected VOCs and other Analytes Historical Analytical Data and Groundwater Elevations C&D Landfill, Pitt County, North Carolina .. -. W'. - .- . GWPS NE 0.03 NE-- 2001-May NS NS NS NS NS NS NS NM 2001-Nov NS NS NS NS NS NS NS NM 2002-May NS NS NS NS NS NS NS NM 2002-Nov NS NS NS NS NS NS NS NM 2003-May NS NS NS NS NS NS NS NM 2003-Nov NS NS NS NS NS NS NS NM 2004-May NS NS NS NS NS NS NS NM 2004-Nov NS NS NS NS NS NS NS NM 2005-May NS NS NS NS NS NS NS NM 2005-Nov NS NS NS NS NS NS NS NM 2006-May NS NS NS NS NS NS NS NM 2006-Nov NS NS NS NS NS NS NS NM 2007-May NS NS NS NS NS NS NS NM 2007-Jun NS NS NS NS NS NS NS NM 2007-Nov NS NS NS NS NS NS NS NM 2008-May NS NS NS NS NS NS NS NM 2008-Nov NS NS NS NS NS NS NS NM 2009-May NS NS NS NS NS NS NS NM 2009-Aug NS NS NS NS NS NS NS NM 2010-Jan ND ND ND NS ND NS NS 14.19 2010-May NS NS NS NS NS NS NS NM 2010-Nov NS NS NS NS NS NS NS NM 2011-May NS NS NS NS NS NS NS NM 2011-Nov NS NS NS NS NS NS NS NM 2012-May NS NS NS NS NS NS NS NM 2012-Nov NS NS NS NS NS NS NS NM 2013-May NS NS NS NS NS NS NS NM 2014-May NS NS NS NS NS NS NS NM 2014-Nov NS NS NS NS NS NS NS NM 2015-May NS NS NS NS NS NS NS NM 2015-Nov NS NS NS NS NS NS NS NM 2016-May NS NS NS NS NS NS NS NM 2016-Nov NS NS NS NS NS NS NS NM 2017-May 0.24 U 0.27 U 0.25 U 100 U 0.63 U 0.39 U NS 13.52 2017-Dec 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 13.72 2018-Jun 0.24 U 0.21 U 0.25 U 100 U 0.63 U 0.39 U NS 13.44 2018-Dec 0.24 U 0.02 U 0.25 U 100 U 0.12 U 0.39 U 2.71 U 14.59 2019-Jun 0.24 U 0.02 U 0.25 U 100 0 0.12 U 0.5 J 2.71 U 12.44 2019-Dec 0.24 U 0.02 U 0.25 U 226 J 0.12 U 0.39 U 2.71 U 13.59 44 of 53 Appendix B SW-1 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 2001-May rAntimony ND Arsenic ND Barium 21,000 ND Beryllium ND Cadmium ND Chromium CobaltTotal ND ... ND ND dk ND ND ND ND E ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND 4 ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND 14 ND ND ND ND ND ND 2005-Nov ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND 3 ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 5 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 26 2007-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2008-May 0.2 J 11 174 0.7 J 0.4 J 8.0 J 1.2 J 5.5 25 3.5 J 1.3 J 0.11 0.2 J 40 43 2008-Nov Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2009-May 0.1 J 6.3 J 181 0.6 J 0.7 J 5.1 J 1.01 4.9 23 1.9 J 0.8 J 0.11 0.03 U 30 21 2009-Aug NS NS NS NS NS NS NS 2.7 J NS NS NS NS NS NS NS 2010-Jan 0.11 3.9J 89.2J 0.2J 1.9 2.1J 0.6J 0.4J 8.0J 1.3J 0.12U 0.2J 0.11 18.9J 15 2010-May 0.22U 0.91 33.3J 0.11 0.2J 0.4J 0.3J 0.3J 0.91 0.4J 0.32U 0.03U 0.05U 2.0J 2.3J 2010-Nov 0.22U 2J 49.8J 0.11 0.11 0.5J 0.4J 1.7J 11 0.7J 0.32U 0.03U 0.05U 3.1J 5.6J 2011-May 0.14U 3.1J 70.8J 0.12J 0.22J 1.8J 0.84J 0.17J 4.3J 1.3J 0.3J 0.02U 0.05J 6.8J 9.6J 2011-Nov 0.14 U 2.0 J 48.7 J 0.02 U 0.02 J 0.74 J 0.50 J 2.3 J 0.95 J 0.88 J 0.20 J 0.02 U 0.02 U 2.2 J 1.9 J 2012-May 0.13J 4.7J 78.8J 0.191 0.17J 2.6J 0.89J 2.1J 7.0J 3.8J 0.41J 0.1U 0.07U 9.5J 6.4J 2012-Nov 0.02 U 0.93 J 38.0 J 0.07 U 0.07 J 0.54 J 0.42 J 1.3 J 0.45 J 0.46 J 0.17 J 0.1 U 0.07 U 1.5 J 4.8 J 2013-May 0.14J 1.2J 50.2J 0.12J 0.08J 2.4J 0.73J 2.4J 1.6J 0.97J 0.39J 0.03U 0.05J 3.1J 4.1J 2014-May 0.02 U 0.67 J 94.3 J 0.16 J 0.22 J 1.9 J 0.38 J 0.46 J 5.2 J 0.98 J 0.06 U 0.03 U 0.02 J 6.0 J 9.9 J 2014-Nov 0.12 U 0.78 J 86.6 J 0.04 U 0.05 J 0.98 J 0.41 J 0.80 J 0.30 J 1.2 J 0.16 U 0.04 U 0.13 U 0.30 J 3.7 J 2015-May 0.65 J 0.82 J 57.6 J 0.06 J 0.07 J 1.2 J 0.33 J 0.66 J 0.69 J 0.67 J 0.22 U 0.01 U 0.03 J 1.11 2.9 J 2015-Nov 0.101 0.71 J 55.8 J 0.02 U 0.04 J 0.86 J 0.26 J 0.68 J 0.38 J 0.80 J 0.46 J 0.01 U 0.02 U 1.3 J 4.7 J 2016-May 0.05 U 0.92 J 56.3 J 0.04 U 0.05 U 1.6 J 0.27 J 0.48 J 0.82 J 0.92 J 0.54 U 0.06 U 0.05 U 1.6 J 3.6 J 2016-Nov 0.05 U 1.2 J 50.0 J 0.05 J 0.05 U 0.95 J 0.34 J 0.45 J 0.32 J 0.72 J 0.54 U 0.06 U 0.05 U 0.57 J 2.4 J 2017-May 0.06 U 1.8 J 128 0.07 U 0.08 U 1.3 J 0.35 J 0.45 J 0.28 J 1.4 J 0.95 J 0.20 U 0.08 U 0.74 J 0.76 J 2017-Dec Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Jun Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Dec 0.17 J 1.6 J 108 0.31 J 0.15 J 6.1 0.79 J 3.1 9.6 2.1 1.4 0.05 0.08 8.4 22 2019-Jun 0.05 J 1.5 J 76.7 0.2 J 0.05 J 0.56 J 5.1 2.2 J 3.9 J 1.8 J 0.87 J 0.05 U 0.05 U 9.4 13 2019-Dec 1 0.4 J 1 30 1 1,725 1 1 1 2 1 18 1 8.9 1 41 1 46 13.7 1 5.4 J 1 0.22 U 1 0.46 J 1 84 202 45 of 53 Appendix B SW-1 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 7 2001-May ND ND ND ND NS NS 2001-Nov ND ND ND ND NS NS 2002-May ND ND ND ND NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov Dry Dry Dry Dry NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND ND ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS NS NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.7 NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec Dry Dry Dry Dry Dry NS 2018-Jun Dry Dry Dry Dry Dry NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24 U 0.02 U 0.25 U 0.12 U 0.73 J 2.71 U 2019-Dec 0.24 U 0.02 U 0.25 U 0.12 U 4.22 4.14 46 of 53 Appendix B SW-2 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 2001-May rAntimony ND Arsenic ND Barium 21,000 ND Beryllium ND Cadmium Chromium CobaltTotal ND ... s.Is ND ND ND ND ND ND E ND ND ND ND 2001-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 2 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 0.06 U 0.24 U 0.41 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 0.2 U 2007-Nov 0.05 U 2.0 J 126 0.06 U 0.11 1.5 J 0.8 J 1.9 1.6 2.9 J 2.2 J 0.04 U 0.04 U 2.0 J 24 2008-May 0.44U 1.11 71.2J 0.11 0.11 1.11 0.8J 0.8 0.7 1.4J 0.91 0.04U 0.04U 1.4J 7.8J 2008-Nov 0.6J 5.3J 268 0.4J 0.3J 5.0J 1.91 5.6 14 4.2J 3.0J 0.11 0.11 9.2J 96 2009-May 0.06 J 1.4 J 61.6 J 0.06 U 0.04 U 0.5 J 0.4 J 1.5 0.5 0.2 J 0.12 U 0.11 0.03 U 2.3 J 4.8 J 2009-Aug NS NS NS NS NS NS NS 0.8 J NS NS NS NS NS NS NS 2010-Jan 0.11 0.3J 71.3J 0.06U 1.2 0.7J 0.3J 0.4J 0.3J 0.91 0.12U 0.11 0.11 0.8J 8.1J 2010-May 0.22U 1.3J 79.4J 0.11 0.11 0.91 0.6J 0.11 0.5J 1.2J 0.7J 0.11 0.05U 1.5J 5.3J 2010-Nov 0.22U 1.11 59.1J 0.11 0.11 0.5J 0.5J 0.94J 0.11 1.6J 0.6J 0.03U 0.05U 1.11 6.8J 2011-May 0.2 J 0.82 J 71.6 J 0.06 J 0.111 0.58 J 1.5 J 0.46 J 0.5 J 1.8 J 0.22 J 0.02 U 0.02 U 0.86 J 12 2011-Nov 0.14 U 2.5 J 69.4 J 0.06 J 0.02 J 1.2 J 0.75 J 1.2 J 0.79 J 0.99 J 0.29 J 0.02 U 0.02 U 3.4 J 8.2 J 2012-May 0.09 J 2.0 J 84.8 J 0.07 U 0.03 U 1.4 J 0.79 J 0.36 J 2.1 J 2.9 J 0.57 J 0.1 U 0.07 U 2.5 J 18 2012-Nov 0.02 U 0.68 J 49.1 J 0.07 U 0.03 J 0.545 J 0.31 J 1.4 J 0.43 J 0.46 J 0.30 J 0.1 U 0.07 U 0.83 J 6.5 J 2013-May 0.04J 0.81J 64.6J 0.07J 0.05J 1.6J 0.52J 0.46J 1.2J 0.65J 0.38J 0.03U 0.02U 1.5J 5.2J 2014-May 0.02 U 1.4 J 72.9 J 0.04 J 0.05 U 0.95 J 0.88 J 0.37 J 0.39 J 0.89 J 0.06 U 0.03 U 0.02 U 0.48 J 2.3 J 2014-Nov 0.12U 0.47J 57.7J 0.04U 0.04J 0.81J 0.34J 0.62J 0.21J 1.4J 0.16U 0.04U 0.13U 0.06U 2.0J 2015-May 0.18J 0.56J 59.7J 0.05J 0.02J 1.11 0.32J 0.87J 0.53J 0.70J 0.29J 0.01U 0.02J 0.94J 3.0J 2015-Nov 0.09 J 0.55 J 44.7 J 0.03 J 0.04 J 0.43 J 0.20 J 0.52 J 0.46 J 0.74 J 0.22 U 0.01 U 0.02 U 0.84 J 4.8 J 2016-May 0.09 J 0.89 J 51.8 J 0.04 U 0.05 U 0.80 J 0.28 J 0.34 J 0.62 J 0.86 J 0.54 U 0.06 U 0.06 J 0.70 J 2.4 J 2016-Nov 0.05 U 0.96 J 65.8 J 0.04 U 0.05 U 1.0 J 0.32 J 0.56 J 0.40 J 1.0 J 0.76 J 0.06 U 0.05 U 0.54 J 2.9 J 2017-May 0.06 U 1.5 J 77.5 J 0.07 U 0.08 U 0.46 J 0.35 J 0.56 J 0.42 J 1.2 J 0.89 J 0.20 U 0.08 U 0.71 J 1.8 J 2017-Dec 0.06 U 0.54 J 54.4 J 0.07 U 0.08 U 0.64 J 0.24 J 0.43 J 0.33 J 0.6 J 0.86 J 0.20U 0.08 U 1.3 J 2.1 J 2018-Jun 0.07 J 1.3 J 58.3 0.05 J 0.02 U 0.15 U 0.3 J 0.58 J 0.81 J 0.73 J 0.6 J 0.05 U 0.05 U 1.4 1.6 J 2018-Dec 0.04 J 0.68 J 53.8 0.05 U 0.02 U 0.53 J 0.19 J 0.26 J 0.21 J 0.65 J 0.15 U 0.05 U 0.05 U 0.111 1.7 J 2019-Jun 0.05 J 0.95 J 78.2 0.08 J 0.02 J 0.33 J 0.74 J 0.62 J 0.63 J 0.88 J 0.45 J 0.05 U 0.05 U 0.92 J 5 J 2019-Dec 0.05 J 0.08 U 48.4 0.02 U 0.04 U 0.12 U 0.26 J 6.1 J 0.30 J 1.2 J 0.54 J 0.22 U 0.02 U 0.9 J 4.2 J 47 of 53 Appendix B SW-2 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 7 2001-May ND ND ND ND NS NS 2001-Nov ND ND ND ND NS NS 2002-May ND ND ND ND NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov ND ND ND ND NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND ND ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS ND NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.9 NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 1.2 NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 1.1 2.71U 2019-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.93 J 2.71 U 48 of 53 Appendix B SW-3 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 2001-May rntimony NS Arsenic NS Barium 21,000 NS Beryllium NS Cadmium NS Chromium CobaltTotal NS ... NS NS NS NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2003-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2004-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2005-Nov ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-May ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND 2006-Nov ND ND ND ND 1 ND ND ND ND ND ND ND ND ND ND 2007-May 0.05 U 0.47 U 0.04 U 0.08 U 1 0.24 U 0.41 U 0.2 U 0.07 U 0.66 U 0.35 U 0.52 U 0.07 U ND 15 2007-Nov 0.05 U 0.5 J 571 0.11 0.2 J 0.24 U 0.7 J 1.6 0.2 0.7 J 0.14 U 0.04 U 0.04 U 0.7 J 71 2008-May 0.44U 0.11 63J 0.11 0.11 0.4J 1.01 0.6 0.3 0.8J 0.2J 0.11 0.04U 0.8J 19 2008-Nov 0.11 0.91 75.1J 0.11 0.04U 0.3J 5.1J 1.1 0.9 1.3J 0.3J 0.11 ND 1.2J 36 2009-May 0.06 J 0.8 J 78.7 J 0.11 0.04 U 0.5 J 1.3 J 0.4 0.2 0.4 J 0.12 U 0.04 U 0.03 U 1.9 J 18 2009-Aug NS NS NS NS NS NS NS 0.8 J NS NS NS NS NS NS NS 2010-Jan 0.6J 0.17U 76.1J 0.2J 0.3J 0.4J 1.2J 0.3J 0.6J 0.8J 0.12U 0.2J 0.11 0.91 14 2010-May 0.22U 0.4J 69.2J 0.11 0.11 0.4J 0.6J 0.11 0.6J 0.8J 0.32U 0.03U 0.05U 1.4J 11 2010-Nov 0.22U 0.6J 75.5J 0.11 0.11 0.2J 1.01 1.11 0.5J 0.8J 0.32U 0.03U 0.05U 0.91 17 2011-May 0.14 U 1.1 J 77.8 J 0.02 U 0.29 J 0.99 J 0.42 J 0.30 J 0.28 J 1.11 0.64 J 0.04 J 0.02 U 0.93 J 5.8 J 2011-Nov 0.14U 0.991 73.3J 0.091 0.14J 0.63J 1.3J 0.34J 1.11 0.76J 0.21J 0.02U 0.12J 1.11 16 2012-May 0.05 J 1.0 J 60.8 J 0.07 U 0.03 U 0.38 J 0.76 J 0.58 J 0.46 J 5.0 J 0.17 U 0.1 U 0.07 U 1.0 J 6.0 J 2012-Nov 0.02 U 0.50 J 74.1 J 0.07 U 0.04 J 0.18 J 0.89 J 1.11 0.111 0.78 J 0.26 J 0.1 U 0.07 U 0.67 J 8.2 J 2013-May 0.03J 0.35J 30.3J 0.111 0.08J 1.6J 0.48J 0.40J 3.0J 0.47J 0191 0.03U 0.06J 3.4J 6.8J 2014-May 0.02 U 0.26 J 37.9 J 0.04 J 0.05 U 0.51 J 0.31 J 0.41 J 1.2 J 0.45 U 0.06 U 0.03 U 0.02 U 1.2 J 2.7 J 2014-Nov 0.46J 0.33J 46.6J 0.08J 0.04J 0.14U 0.75J 0.72J 0.78J 0.53J 0.16U 0.04U 0.13U 1.3J 5.7J 2015-May 0.06J 0.71J 54.2J 0.111 0.03J 1.2J 0.48J 0.72J 2.5J 0.60J 0.22U 0.01U 0.03J 2.5J 6.4J 2015-Nov 0.06J 0.52J 63.2J 0.13J 0.07J 0.85J 0.74J 0.64J 11 0.88J 0.22U 0.01U 0.04J 1.7J 9.4J 2016-May 0.05 U 0.88 J 75.1 J 0.10 J 0.05 U 1.11 0.72 J 0.39 J 1.0 J 0.75 J 0.54 U 0.06 U 0.05 U 1.7 J 5.2 J 2016-Nov 0.06 J 0.72 J 99.11 0.09 J 0.05 U 0.61 J 0.47 J 0.57 J 0.42 J 0.64 J 0.54 U 0.06 U 0.05 J 1.0 J 5.0 J 2017-May 0.06U 1.1 J 65.7 J 0.07U 0.08U 0.08U 0.36 J 0.57 J 0.56 J 1.11 ND 0.20 U 0.08U 0.95 J 2.6 J 2017-Dec 0.06 U 0.49 J 79.0 J 0.07U 0.08U 0.4 J 0.51 J 0.47 J 0.41 J 0.67 J 0.51 U 0.20U 0.08 U 1.3 J 4.6 J 2018-Jun 0.05 J 1.7 J 117 0.09 J 0.03 J 1.2 J 0.65 J 0.66 J 1.11 1.11 0.56 J 0.05 U 0.05 U 1.8 5.2 J 2018-Dec 0.05 J 0.44 J 77.5 0.05 J 0.02 J 0.37 J 0.32 J 0.46 J 0.32 J 0.79 J 0.15 U 0.05 U 0.05 U 0.57 J 3.6 J 2019-Jun 0.07J 1.91 121 0.12J 0.03J 0.67J 1.7J 0.96J 2.5J 1.6J 0.65J 0.05U 0.05U 2.4 8.2J 2019-Dec 1 0.09 J 1 2.3 J 1 155 1 0.28 J 1 0.12 J 1 0.12 U 1 2.0 1 8.4 J 1 7.2 2.9 J 0.99 J 0.22 U 0.11 J 11 31 49 of 53 Appendix B SW-3 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina 775-5-1-M Standard 720 110,000 80 NS NS NS NS NS 2001-Nov NS NS NS NS NS NS 2002-May NS NS NS NS NS NS 2002-Nov ND ND ND ND NS NS 2003-May ND ND ND ND NS NS 2003-Nov ND ND ND ND NS NS 2004-May ND ND ND ND NS NS 2004-Nov ND ND ND ND NS NS 2005-May ND ND ND ND NS NS 2005-Nov ND ND ND ND NS NS 2006-May ND ND ND ND NS NS 2006-Nov ND ND ND ND NS NS 2007-May ND ND ND ND NS NS 2007-Jun ND ND ND ND NS NS 2007-Nov ND ND ND ND NS NS 2008-May ND ND ND ND NS NS 2008-Nov ND ND 1.6 J ND NS NS 2009-May ND ND ND ND NS NS 2009-Aug NS NS NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND 0.6 NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May ND ND ND ND ND NS 2014-May ND 0.27 U 0.25 U 0.63 U 0.39 U NS 2014-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 1.14 2.71U 2019-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 50 of 53 Appendix B SW-4 Metals Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 640 10 21,000 4 7 25 5 0.06 0.47 m1mL NE 2001-May ivy NS NS NS NS -_ LN_ NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-May NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2009-Aug NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS 2010-Jan 0.2J 0.2J 70.9J 0.11 0.11 0.3J 0.2J 0.5J 0.3J 0.6J 0.12U 0.11 0.03U 0.6J 8.8J 2010-May 0.22U 0.6J 82.1J 0.11 0.11 0.91 0.5J 0.3J 1.6J 0.81 0.32U 0.03U 0.05U 3.0J 3.0J 2010-Nov 0.22U 0.5J 94.2J 0.11 0.2J 0.3J 0.7J 1.5J 0.2J 0.81 0.32U 0.03U 0.05U 0.91 3.9J 2011-May 0.29J 1.3J 137 0.57J 0.14J 3.1J 1.6J 0.02U 5.7J 1.5J 0.33J 0.02U 0.091 7.2J 9.4J 2011-Nov 0.14 U 0.51 J 81.2 J 0.10 J 0.05 J 0.46 J 0.86 J 0.42 J 0.29 J 0.55 J 0.20 U 0.02 U 0.09 J 0.88 J 2.4 J 2012-May 0.04J 0.92J 74.3J 0.15J 0.03U 1.001 0.72J 1.2J 1.3J 6.1J 0.17U 0.1U 0.07U 3.0J 0.70J 2012-Nov 0.02U 0.82J 70.6J 0.12J 0.07J 1.11 1.7J Dry 1.3J 1.11 0.17U 0.1U 0.07U 2.3J 11 2013-May Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2014-May Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2014-Nov Dry Dry Dry Dry Dry Dry Dry 0.60 J Dry Dry Dry Dry Dry Dry Dry 2015-May 0.04J 0.80J 78.3J 0.04J 0.03J 0.95J 0.34J 0.74J 0.84J 0.74J 0.22U 0.01U 0.04J 1.11 5.2J 2015-Nov 0.86 J 0.39 J 74.0 J 0.09 J 0.08 J 0.53 J 0.26 J 0.60 J 0.68 J 0.75 J 0.22 U 0.03 J 0.07 J 1.5 J 9.8 J 2016-May 0.05 U 0.66 U 76.1 J 0.04 U 0.05 U 0.71 J 0.18 J Dry 0.60 J 0.78 J 0.54 U 0.06 U 0.05 U 0.53 J 6.3 J 2016-Nov Dry Dry Dry Dry Dry Dry Dry 1.6 J Dry Dry Dry Dry Dry Dry Dry 2017-May 0.06U 1.2 J 83.3 J 0.07 U 0.08U 3.1 J 0.47 J 1.6 J 4.3 J 1.4 J ND 0.20 U 0.10 J 5.6 J 8.1 J 2017-Dec 0.07 J 0.14 J 83.0 J 0.07 U 0.08 U 0.08 J 0.24 U 0.68 J 0.24 J 0.94 J 0.51 U 0.20 U 0.08 U 1.11 10 2018-Jun Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry Dry 2018-Dec 0.04J 0.16J 74.1 0.111 0.04J 0.6J 0.62J 0.43J 0.38J 0.75J 0.15U 0.05U 0.07J 0.7J 4.5J 2019-Jun 0.08J 1.11 71.5 0.12J 0.02U 0.36J 0.72J 1.11 1.11 0.81J 0.38J 0.05U 0.05U 3.1 4.8J 2019-Dec 0.04 J 0.08 U 60.0 0.06 J 0.04 U 0.12 U 0.44 J 4.8 J 0.64 J 1.0 J 0.26 J 0.22 U 0.02 J 2 3.0 J 51 of 53 Appendix B SW-4 Selected VOCs Historical Analytical Data C&D Landfill, Pitt County, North Carolina SW Standard 7 2001-May NS NS NS NS NS NS 2001-Nov NS NS NS NS NS NS 2002-May NS NS NS NS NS NS 2002-Nov NS NS NS NS NS NS 2003-May NS NS NS NS NS NS 2003-Nov NS NS NS NS NS NS 2004-May NS NS NS NS NS NS 2004-Nov NS NS NS NS NS NS 2005-May NS NS NS NS NS NS 2005-Nov NS NS NS NS NS NS 2006-May NS NS NS NS NS NS 2006-Nov NS NS NS NS NS NS 2007-May NS NS NS NS NS NS 2007-Jun NS NS NS NS NS NS 2007-Nov NS NS NS NS NS NS 2008-May NS NS NS NS NS NS 2008-Nov NS NS NS NS NS NS 2009-May NS NS NS NS NS NS 2009-Aug NS ND NS NS NS NS 2010-Jan ND ND ND ND NS NS 2010-May ND ND ND ND NS NS 2010-Nov ND ND ND ND NS NS 2011-May ND ND ND ND ND NS 2011-Nov ND ND ND ND ND NS 2012-May ND ND ND ND ND NS 2012-Nov ND ND ND ND ND NS 2013-May Dry Dry Dry Dry Dry NS 2014-May Dry Dry Dry Dry Dry NS 2014-Nov Dry Dry Dry Dry Dry NS 2015-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2015-Nov 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-May 0.24 U 0.27 U 0.25 U 0.63 U 0.39 U NS 2016-Nov Dry Dry Dry Dry Dry NS 2017-May 0.24U 0.27 U 0.25 U 0.63U 0.39U NS 2017-Dec 0.24U 0.21 U 0.25 U 0.63 U 0.39 U NS 2018-Jun Dry Dry Dry Dry Dry NS 2018-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 2019-Jun 0.24U 0.02U 0.25U 0.12U 0.4J 2.71U 2019-Dec 0.24 U 0.02 U 0.25 U 0.12 U 0.39 U 2.71 U 52 of 53 Water Quality Monitoring Report December 2019 Semiannual Sampling Event Wood Project No. 6468-19-9035 Attachment C Mann -Kendall Trend Analyses wood. TOOLKIT for • - Analysis Evaluation Date: 22-Mar-20 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Benzene Conducted By: DH Concentration Units: N /L Sampling Point ID: MW-31S I MW-3A I MW-8 I MW-10 I MW-11 MW-12S 1 1-Nov-15 1.7 1.7 0.24 0.24 2 1-Ma -16 1.3 0.24 0.9 0.5 1.4 3 1-Nov-16 1.2 0.8 1.5 0.6 1.9 4 1-May-17 2.8 2 1.2 0.4 1.7 5 1-Dec-17 1.7 2.7 0.6 0.24 1 2 6 1-Jun-18 1.2 0.5 0.3 0.24 0.9 1.4 7 1-Dec-18 1.3 1.69 0.48 1.57 0.48 1.48 8 1-Jun-19 0.89 1 1.17 2.26 1.89 2.52 9 1-Dec-19 1.81 1.49 1.13 1.28 2.56 2.12 10 11 12 13 14 15 16 17 18 19 20 Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: ' Concentration Trend: Stable No Trend No Trend No Trend No Trend Increasing 10 --4- M W-3S ^` --41-- M W-3A J \ MW-8 _ M W-10 v _ MW-11 O1 MW-12S L d V _ O U 0.1 07115 01116 08116 03117 09117 04118 10118 05119 12119 06120 Sampling Date Notes: 1. At least four independent sampling events per well are required for calculating the trend. Methodology is valid for 4 to 40 samples. 2. Confidence in Trend = Confidence (in percent) that constituent concentration is increasing (S>0) or decreasing (S<0): >95% = Increasing or Decreasing; >_ 90% = Probably Increasing or Probably Decreasing; < 90% and S>0 = No Trend; < 90%, S<_0, and COV >_ 1 = No Trend; < 90% and COV < 1 = Stable. 3. Methodology based on "MAROS: A Decision Support System for Optimizing Monitoring Plans", J.J. Aziz, M. Ling, H.S. Rifai, C.J. Newell, and J.R. Gonzales, Ground Water, 41(3):355-367, 2003. 4 MDL value used for ND concentrations. DISCLAIMER: The GSI Mann -Kendall Toolkit is available "as is". Considerable care has been exercised in preparing this software product; however, no party, including without limitation GSI Environmental Inc., makes any representation or warranty regarding the accuracy, correctness, or completeness of the information contained herein, and no such party shall be liable for any direct, indirect, consequential, incidental or other damages resulting from the use of this product or the information contained herein. Information in this publication is subject to change without notice. GSI Environmental Inc., disclaims any responsibility or obligation to update the information contained herein. GSI Environmental Inc., www.gsi-net.com TOOLKIT for • • Analysis Evaluation Date: 22-Mar-20 Job ID: 6480199035 Facility Name: C&D Landfill Constituent: Vinyl Chloride Conducted By: DH Concentration Units: N IL VINYL CHLORIDE CONCENTRATION (N9Coefficient of Variation: Mann -Kendall Statistic (S): Confidence Factor: Concentration Trend: l�end / U)