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8603_Surry_Elkin_MSWLF_CDLF_Nov2019GW_20200327
�ENRUSE oNLY4 ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring' Data Submittal Information: Name of entity submitting data (laboratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting: Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl E-mail: jpfohl@mesco.com Facility name: Surry County Closed C&D and Closed MSW Landfill -Elkin Phone: (919)772-5393 Address: Landfill Road off Joe Mill Lane (SR 1121j Elkin, NC 28621 Environmental Status: (Check all thatapply) Initial/Background Monitoring � Detection Monitoring of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitoring data Notification attached? NC Landfill Rule: Facility Permit # (.0500 or .1600) 86-03 .1600 QX Assessment Monitoring Methane -gas monitoring data Corrective action data (specify) Other(specify) Actual sampling dates (e.g., October 20-24, 2006) 26-27. 2019 Corrective Action No. No groundwater or surface water standards were exceeded. X Yes, a nocation of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete nocation of any sampling values meeting or exceeding groundwater standards or explosive gas levelsI and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Facility Name (Print) P.O. Box 97, Garner, NC 27529 Facility Representative Address C-0281 Senior Project Manager Title NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 (919) 772-5393 (Area Code) Telephone Number Semi -Annual Water Quality Monitoring Report November 2019 Prepared for Surry County Closed CDLF and Closed Unlined Landfill Elkin, North Carolina Permit No. 86-02 Prepared by Municipal Engineering Services Company, P.A. P.O. BOX 97 Garner, North Carolina MESCO Project Number: G19031.0 Steven R. Gandy, Ph.D, P.E. Senior Project Manager sgandy(kmesco.com Jonathan Pfohl Environmental Specialist jpfohl&mesco.com AQ`��MUNICIPAL ENGINEERING SERVICES COMPANY, P.A. 66 SNIPWASH DRIVE, GARNER, NC 27529 - PHONE! 919.772.5393 P.O. Box 349, BOONE, NC 213607 - PHONE; SZB-262-1767 �� LICENSE NUMBER: C-13261 Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report for an event performed at the Surry County closed construction and demolition (C&D) and closed unlined municipal solid waste landfill (MSWLF) located in Elkin NC (SWS Permit No. 86-03) on November 26-27, 2019. The site is located at the end of Landfill Road off Joe Mill Lane (SR 1121), Elkin, Surry County, North Carolina. The site location topographic map is depicted as Sheet 1. NCDEQ Solid Waste Rule NCDEQ Solid Waste Rules 15ANCAC13B.1630 through .1637 require that Surry County provide this monitoring report to the SWS on a semi-annual basis. In general accordance with 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater characterization and a brief discussion of the findings. Detection tables, a potentiometric map, field parameters and the laboratory analytical reports with quality assurance/quality control data and chains -of -custody (COC) are also included in this report. Laboratory analytical results indicate that volatile organic compound(s) (VOC) were found above their respective North Carolina Groundwater Standard in groundwater samples collected from MW-2, MW-3 and MW-3A. One or two total recoverable metals were also detected above its respective groundwater Standard in samples collected from MW-3A, MW-6, MW-7S and MW-7D. Background Prior to operating as a C&D landfill the site operated as an unlined sanitary MSWLF that consisted of two units. The first area was closed prior to October 1991 with a 24 inch final soil cover. The second area was closed with a cohesive cap of 18 inches of soil with a minimum permeability of less than 1 x 10-5 cm/sec, and 18 inches of erosive layer prior to December 31, 1998 in accordance with the Transition Plan. C&D was placed on top of the cohesive capped MSW unit until 2008. The transfer station that operated at the landfill closed around June 2010 and the site has remained vacant since. Water quality at this facility has been monitored at least semi. -annually since 1989 with historical data available since 1994. The landfill has been in assessment monitoring since 1997 in response to detections of VOCs. The SWS approved a modification to the assessment monitoring program on October 15, 2014 (DIN:21983) which entails a subset of wells to be sampled for Appendix II parameters once every three years which was last performed during the December 2017 event. Sampling Locations The groundwater monitoring network includes 12 locations; nine downgradient monitoring wells (MW-2, MW-3, MW-3A, MW-4, MW-5, MW-6, MW-7S, MW-7D and MW-8), a background monitoring well (MW-1) and two downstream surface water points (SW-1, SW-2). All locations were sampled during this event. Water monitoring locations are depicted on Sheet 2. A summary detailing the construction of the water monitoring wells is presented on Table 1. Semi -Annual Water Quality Monitoring Report -November 2019 Surry County Closed CDLF and Closed Unlined Landfill Page 1 Sampling Procedures Sampling was conducted utilizing portable methodologies outlined in the NCDENR SWS guidance document Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling revised April 2008. The function and integrity of all monitoring locations were visually evaluated as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Bailing or submersible pumping was utilized to purge the wells a minimum of three times the volume of standing water in the well or until dry. Surface water samples were dipped from the surface of Snow Creek at previously designated locations. Stabilized field parameters were recorded during purging. Samples were then placed into laboratory -prepared, pre -preserved containers. Samples were kept on ice and transported to a NC -certified laboratory under proper chain of custody (C- O-C) protocol within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters recorded during purging included pH, specific conductance, temperature and turbidity. A summary of the field parameter data is presented in Table 3 and field data sheets are in Appendix A. In general field parameter results remain consistent with previously reported events. Laboratory Results Pace Analytical Laboratories (PACE) (NC Cert. #12 & 40) performed the laboratory analysis. Pace reported that their procedures conformed to the most current, applicable TNI/NELAC standards and the their Quality Assurance Manual, where applicable, unless otherwise noted in the body of the laboratory report. Groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4-dioxane. A sampling and analysis table summarizing the locations, targeted constituents and methods is presented as Table 4. Laboratory results and C-O-Cs are presented in Appendix B. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as with a "J" which indicates an estimated concentration. "J-qualified" concentrations are considered non - quantifiable and discretion should be made prior to making decisions based on a value that the laboratory considers an estimate. Table 5 summarizes constituents detected in groundwater samples compared to Interim Maximum Allowable Concentrations (IMAC) and North Carolina Groundwater Standards (2L) which have been adopted by the NC SWS as groundwater compliance Standards. Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal Primary "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared to the North Carolina Surface Water Standards (2B), NC Protective Values, EPA Nationally Recommended Water Quality Criteria and the MCL. Semi -Annual Water Quality Monitoring Report -November 2019 Surry County Closed CDLF and Closed Unlined Landfill Page 2 Groundwater Samples Above Standards Metals One or two total recoverable metals were detected above its RL and respective NC 2L/IMAC Standard in samples collected from four wells (MW-3A, MW-6, MW-7S and MW-7D) as summarized below. Metals Detected in Groundwater Samples Above RL and 2L/IMAC Standards Cadmium Cobalt 2L/IMAC 2 1 MW-3A 3.8 39 MW-6 25 MW-7S 6.6 MW-7D 5.1 concentrations in ugn, VOCs One to three VOCs were detected above its RL and respective NC 2L Standard in samples collected from MW-2, MW-3 and MW-3A as summarized below. VOCs Detected in Groundwater Samples Above RL and 2L Standards Benzene I 1,4-Dichlorobenzene 1,4-Dioxane Vinyl Chloride 2L Standard 1 6 3 0.03 MW-2 2.4 8.8 180 MW-3 1.8 MW-3A 1.1 concentrations to ugn, Surface Water Samples Above Standards No parameters were detected in either surface water sample in concentrations exceeding their 2B Standard. Groundwater Characterization A single -day potentiometric map constructed from groundwater levels collected during this event is presented as Sheet 2. Groundwater flow rates and directions were calculated and are included in Table 7. Groundwater flows generally southwest, towards the Snow Creek discharge feature. Groundwater average linear velocity rates calculated from modified Darcy's equation indicate flow rates ranged from approximately 8 ft/yr (MW-5) to 730 ft/yr (MW-6). Findings The metal detections are believed to originate from erosion of natural deposits rather than anthropogenic. Groundwater samples collected from MW-2, MW-3 and MW-3A contained one or more VOC(s) in concentrations above 2L Standards. VOC concentrations remain within their respective historically identified range. Semi -Annual Water Quality Monitoring Report -November 2019 Surry County Closed CDLF and Closed Unlined Landfill Page 3 Constituents above NC 2B Standards continue to be absent in the surface water samples (SW-1 and SW- 2) collected from the main Snow Creek discharge feature which also serves as the southern downgradient property boundary. The reduction in VOC concentrations over time and distance from the landfill and the prevalence of biodegradation byproducts indicate natural attenuation is occurring and groundwater quality is expected to continue to improve. Closing Semi-annual water quality monitoring is planned to continue in Spring of 2020. Semi -Annual Water Quality Monitoring Report -November 2019 Surry County Closed CDLF and Closed Unlined Landfill Page 4 Sheets Topographic Map with Site Location Surry County Closed MSW/C&D Landfill - Elkin ige KIM ON a K �- �C APPROXIMATE' o o WASTE % fond rl'ER4% L FOOTPRINT -�� � 1, t� ==� - \ ✓��~-�i� �t �' .I ' it i" '� /))� �`� ,�(j ��_�... `•�, it I ;i ROAD CLASSIFICATION QUADRANGLE LEGEND Primary highway, Light -duty road, hard or hard Surface... _-.. improved surface........__ --- _ Secondary highway, �� hard surface... Unimproved road.. --------- 1" — 2000Interstate Route rj U. 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TOPOGRAPHIC CONTOURS FROM NC ONEMAP (11-2013) 2. WELL LOCATIONS PLOTTED WITH ELEVATIONS EXTRAPOLATED FROM AERIAL PHOTOGPAHY INSPECTION 3. PARCEL BOUNDARY FROM NC ONEMAP (10/2018) TOPOGRAPHIC CONTOURS WATER FEATURES PROPERTY LINE APPROXIMATE WASTE BOUNDARY • WATER MONITORING WELL SURFACE WATER MONITORING POINT POTENTIOMETRIC GROUNDWATER CONTOUR GWE:GR000NDWATER ELEVATION * : ELEVATION NOT USED IN CONTOURING Ce NilII0IMEI[�"IsE,I ma 200 0 100 200 400 800 ( IN FEET ) SHEET 2 ■ A M L9 Q M r, zCL ul N L� N W � 0� � �0 N cb W w Z00 N Za Z O W o r 00 L9a 0) = a N 1�1 z � N in . O U w W N U 0m 00 2 L3- Z NZI U J WZW z ul Q � Z Q W 0 Z U W � wm p J U N M X o m EL In Lr) 0 a LU m CL Q � U N 1 O W u- W � C'1 O Q Q O W W CD CL Z � DATE: 9125119 DRWN. BY. J. PFOHL CHKD. BY: S. GANDY PROJECT NUMBER G19031.0 DRAWING NO. I SHEET NO. Tables Table 1 Groundwater Monitoring Well Construction Table November 26, 2019 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of Casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 11/28/89 4 80 70 10 Soil 1042 1041 984 52.75 36.29711 -80.77236 MW-2 11/08/89 4 79 69 10 Soil 948 947 890 57.28 36.29572 -80.77620 MW-3 11/28/89 4 63 53 10 Soil 932 931 881 50.42 36.29362 -80.77646 MW-3A 09/16/94 2 40 24 16 Fractured Rock 927 924 894 31.83 36.29457 -80.77675 MW-4 09/15/94 2 29 13 16 Fractured Rock 933 929 920 11.91 36.29379 -80.77528 MW-5 09/15/94 2 31 16 15 Fractured Rock 949 845 936 11.62 36.29450 -80.77456 MW-6 09/15/94 2 66 51 15 Fractured Rock 1005 1002 955 46.92 36.29780 -80.77270 MW-7S 06/05/01 2 24 9 15 Fractured Rock 901 889 890 11.18 36.29407 -80.77730 MW-7D 06/05/01 2 90 80 10 Fractured Rock 901 889 895 3.07 36.29407 -80.77730 MW-8 1 06/04/01 1 2 1 67 52 15 Fractured Rock 1015 1013 971 1 40.21 1 36.29739 -80.77246 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Slurry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 2 Field Observations of Monitoring Locations November 26-27, 2019 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears to be Effective Comments MW-1 Yes Yes No Yes Yes Yes 4" Diameter. MW-2 Yes Yes Yes Yes Yes Yes 4" Diameter. MW-3 Yes Yes Yes Yes Yes Yes 4" Diameter. MW-3A Yes Yes Yes Yes Yes MW-4 Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes MW-6 Yes Yes Yes Yes Yes Yes Removed bailer that was dropped in well on 6/19/19. MW-7S Yes Yes Yes Yes Yes Yes MW-71) Yes Yes Yes Yes Yes Yes pH elevated likely grout intrusion MW-8 Yes Yes Yes Yes Yes Yes SW-1 Yes - - - - SW-2 Yes - - Any unusual field conditions, observations, or events: Facility no longer in operation or occupied since transfer station closed in — June 2010. Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 3 Field Parameter Data Summary November 26, 2019 Depth to Water Water Elevation* TOC Elevation* Temp. pH Specific Conductance Hardness Turbidity of Metals Sample Parameter ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm mg/L NTU MW-1 52.75 989 1042.00 15.0 6.87 127.3 -- 1.12 MW-2 57.28 891 948.00 15.1 6.95 1370 -- 14.8 MW-3 50.42 882 932.00 14.5 6.25 329 -- 2.00 MW-3A 31.83 895 926.50 14.6 6.68 727 -- 4.29 MW-4 11.91 921 932.50 14.1 7.10 66 -- 1.68 MW-5 11.62 937 948.50 14.8 6.73 123 -- 0.70 MW-6 46.92 958 1004.50 14.0 6.42 335 -- 7.30 MW-7S 11.18 890 901.01 15.8 6.51 420 -- 1.78 MW-7D 3.07 898 900.95 13.6 8.19 312 -- 1.92 MW-8 40.21 975 1014.87 14.0 6.27 229 -- 4.05 Minimum 3.07 882 900.95 13.6 6.25 66 -- 0.70 Average 31.72 923 955.08 14.6 6.80 404 -- 3.96 Maximum 57.28 989 1042.00 15.8 8.19 1370 -- 14.8 SW-1 - - - 18.2 8.55 106 80 9.16 SW-2 - - - 18.3 8.43 119 80 7.04 Minimum - - - 18.2 8.43 106 80 7.04 Average - - - - 18.3 8.49 113 80 8.1 Maximum - - 18.3 8.55 119 80 9.16 NOTES: * = Elevation extrapolated from photo inspected LIDAR released in 2007 by NCDOT (Not Surveyed). btoc = below top of casing amsl = above mean sea level Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 4 Sampling and Analysis Summary November 27, 2019 App. I Other Field Parameters ro v X _ U U 0 0M C a O> H H 2 U a H 0 0 � 0 ~ 0 0 co 0 00 0 0 0 00 Qi L ai L a) L ya% Qd a- IL a% ++ ai ai ai J (6 J J N LL LL LL LL LL MW-1 x x x x x x x MW-2 x x x x x x x MW-3 x x x x x x x MW-3A x x x x x x x MW-4 x x x x x x x MW-5 x x x x x x x MW-6 x x x x x x x MW-7S x x x x x x x MW-7D x x x x x x x MW-8 x x x x x x x SW-1 x x x x x x x x SW-2 x x x x x x x x App I = List from current 40 UFR 258 Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 5 Groundwater Sample Detections November 27, 2019 Parameter Name MDL RL 2L Standard MCL MW-1 MW-2 MW-3 MW-3A MW-4 MW-5 MW-6 MW-7D MW-7S MW-8 IMAC Value* U D D D D D D D D D Metals Tar eted 40CFR 258 Appendix I Arsenic, total 4.7 10 10 10 9 J Barium, total 5.0 5 700 2000 30 J 301 74.2 J 455 22.1 J 20.2 J 89 J 10.4 J 61.2 J 42 J Beryllium, total 0.2 1 4* 4 0.31 J Cadmium, total 0.53 1 2 5 1 1.2 0.98 J 3.8 (N) 0.48 J 1.3 5.1 (N) 6.6 (N) 1.7 Chromium, total 1.0 5 10 100 1.1 J 2.5 J Cobalt, total 1.1 5 1* NE 4.9 J 5 J 39 (N) 25 (N) 2.3 J Copper, total 2.1 5 1000 1300 2.9 J 2.2 J 3.3 J 3 J Lead, total 1.6 5 15 15 2.5 J 2.8 J 1.7 J 2.6 J 1.7 J 2.1 J 1.9 J 1.7 J Nickel, total 0.9 5 100 NE 2.6 J 41.8 J 51.1 1.7 J 1.8 J 4.8 J 1.4 J 6.4 J Vanadium, total 1.3 5 0.3* NE 1.4 J 1.8 J 1.6 J Zinc, total 3.9 10 1000 NE 7.1 J 9.8 J 12.2 8 J 3.9 J 4.1 J VOCs Tar eted 40CFR 258 Appendix I & 1 4-Dioxane 1,1-Dichloroethane 0.27 1 6 NE 0.5 J 0.68 J 0.47 J 1,2-Dichlorobenzene 0.29 1 20 NE 5.2 3.5 J 1.7 J 0.55 J 1,2-Dichloroethane 0.34 1 0.4 5 0.55 J 1,2-Dichloropropane 0.19 1 0.6 5 0.75 J 1,4-Dichlorobenzene 0.26 1 6 75 8.8 (L) 2.5 11.6 (L) 2.9 0.79 J 1,4-Dioxane 56.2 150 3 NE 180 (L) Benzene 0.15 1 1 5 2.4 (L) 1.8 (L) 0.86 J 0.71 J 0.46 J Chlorobenzene 0.23 1 50 100 6 0.46 J 4.8 6.1 0.29 J Chloroethane 0.49 1 3000 NE 0.68 J cis-1,2-Dichloroethene 0.29 1 70 70 0.32 J 8.3 11.5 2.6 J 3.2 J 2.6 J Toluene 0.24 1 600 1000 0.59 J Trichloroethene 0.22 1 3 5 0.89 J Vin I chloride 0.24 1 0.03 2 1.1 L Notes: Units ug/L unless shown otherwise, Blank cells means not detected above MDL, NE means not established. Bold Above RL and Established 2L/IMAC U= Well Upgradient, D = Well Downgradient MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." 2L Standard and IMAC Values recognized by the NC SWS as regulatory groundater Standards. 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 IMAC = Interim Maximum Allowable Concentration MCL = Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualifled". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas Wor leachate as suspected transport mechanism. A deflnitive source of the detections was not determined as part of this report. Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 6 Surface Water Sample Detections November 27, 2019 Parameter Name MDL RL NC 2B STD EPA z NRWQC NC PV3 MCL° SW-1 SW-2 Downstream Downstream Tarneted 40CFR 258 Armendix I & 1 4-Dioxane Barium, total 0.03 1 NE NE 200,000 2000 18 J 17.5 J Beryllium, total 0.03 5 65 NE NE 4 0.22 J Cadmium, total 0.03 10 2.26 NE NE 5 0.53 J Lead, total 0.02 1 50.61 NE NE 15 1.9 J Hardness m /L Hardness (mg/L) 20 1 NE I NE I NE I NE NE 80 80 TurbidityNTU TurbidityNTU 0.01 NE 50 NE NE NE 9.16 7.04 Notes: Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Not Established J = "J-qualified" by lab and defined as estimated concentration above the adusted method detection limit and below the adusted reporting limit. Bold Above Applicable Established 2B Std. MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit defined by Pace laboratory as "The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix." Receiving surface waters is Snow Creek (12-62-15) Class C ' NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes. Beryllium 2B Standard All Waters Freshwaters Class C "Acute". Sample tested as total recoverable but 2B Std. based on dissolved portion. 2B Standard for cadmium is determined via a calculation (below) for acute that is dependent upon hardness. Cadmium 2B Standard calculation:WER*[{1.136672-[In hardness](0.041838))*e^{0.9151[In hardness]-3.1485)] 2B Standard for lead is determined via a calculation (below) for acute that is dependent upon hardness. Lead 2B Standard calculation:WER*[{1.46203-[In hardness](0.145712))*e^{1.273[In hardness]-1.460)] Turbidity 2B Standard All Waters Freshwaters Class C Streams 'EPA NRWQC = EPA Nationally Recommended Water Quality Criteria for Aquatic Life & Human Health. Nationally Recommended Water Quality Criteria for which NC does not have a Water Quality Standard for one or more uses 3 NC PV= NC Protective Value. These criteria may be based on limited toxicological information and are offered as guidelines only. Contact DWR staff for further information. NC PV for barium from fresh and salt water All waters (Class C & SC) for fish consumption. ° MCL= Maximum Contaminant Level. Federal "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Table 7 Hydrologic Properties at Monitoring Locations November 26, 2019 Monitoring Hydraulic Well Conductivity (cm/second) Effective Porosity (%) Hydraulic Gradient (feet/feet) Groundwater Average Linear Velocity Rate (feet/year) Flow Depth to Direction Groundwater (ft btoc) Groundwater Potentiometric Elevation* (ft amsl) Screened Interval Lithology MW-1 9.90E-05 5 0.240 492 N52W 52.75 989 Clay MW-2 2.00E-05 5 na na na 57.28 891** Clay MW-3 5.00E-05 5 na na na 50.42 882** Clay Minimum 2.00E-05 5 0.240 492 - 50.42 880 - Average 5.63E-05 5 0.240 492 - 53.48 917 - Maximum 9.90E-05 5 0.240 492 - 57.28 983 - MW-3A 2.50E-05 5 0.130 67 S64W 31.83 895 Fractured Rock MW-4 4.20E-04 5 0.011 95 N66W 11.91 921 Fractured Rock MW-5 2.70E-04 5 0.002 8 N81 W 11.62 937 Fractured Rock MW-6 1.20E-04 5 0.294 730 N16W 46.92 958 Fractured Rock MW-7S 2.30E-04 5 0.051 240 S37W 11.18 890 Fractured Rock MW-71D na na na na na 3.07 898** Fractured Rock MW-8 2.40E-05 5 0.346 172 N32W 40.21 975 Fractured Rock Minimum 2.40E-05 5 0.002 8 - 3.07 889 - Average 1.82E-04 5 0.139 219 - 22.39 922 - Maximum 4.20E-04 5 0.346 730 - 46.92 970 - NOTE: Effective porosity data obtained from GAI Consultants' January 1995 Groundwater Sampling Report. Hydraulic conductivity values from MW-7S and MW-8 derived from slug tests performed by Joyce Engineering on July 25, 2001. Values for MW-1 through MW-6 obtained from GAI consultants' January 1995 Groundwater Sampling Report. Hydrologic gradient calculated from groundwater elevations recorded November 26, 2019. Wells screened in both the upper bedrock & unconfined aquifer utilized for flow directions/gradients. = Datum used to determine elevation extrapolated from photo inspected LIDAR released 2007 by NCDOT (Not Surveyed). * = Denotes wells with depressed potentiometric head. Therefore, flow directions and rates not calculable. Average Linear Velocity Rate (Q) is defined by modified Darcy's equation: where K. ch2 K = hydraulic conductivity ne = effective porosity dh = head difference dl = horizontal distance Surry County Closed C&D and Closed MSWLF, Elkin Page 1 of 1 Appendix A Field Sampling Parameter Data Sheet(s) Field Sampling Data Sheet SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Ury VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained I�r �rSonlcdpni .;.;. LngtncarinF Appendix B Laboratory Analysis Reports Chains of Custody lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 December 10, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on November 27, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ft*OL-' Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Steven R. Gandy, Municipal Engineering Services Co. Maddie German, Municipal Engineering Services REPORT OF LABORATORY ANALYSIS r e This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Lab ID Sample ID Matrix Date Collected Date Received 92455490001 MW-1 Water 11/27/1911:19 11/27/19 14:00 92455490002 MW-2 Water 11/27/19 08:37 11/27/19 14:00 92455490003 MW-3 Water 11/27/1910:03 11/27/19 14:00 92455490004 MW-3A Water 11/27/19 08:46 11/27/19 14:00 92455490005 MW-4 Water 11/27/1910:41 11/27/19 14:00 92455490006 MW-5 Water 11/27/1910:56 11/27/19 14:00 92455490007 MW-6 Water 11/27/1911:31 11/27/19 14:00 92455490008 MW-7S Water 11/27/19 09:11 11/27/19 14:00 92455490009 MW-7D Water 11/27/19 09:19 11/27/19 14:00 92455490010 MW-8 Water 11/27/1911:24 11/27/19 14:00 92455490011 SW-1 Water 11/27/19 09:36 11/27/19 14:00 92455490012 SW-2 Water 11/27/19 09:48 11/27/19 14:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Closed LF-Elkin 92455490 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92455490001 MW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490002 MW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490003 MW-3 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490004 MW-3A EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490005 MW-4 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490006 MW-5 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490007 MW-6 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490008 MW-7S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490009 MW-7D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490010 MW-8 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490011 SW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92455490012 SW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-1 Lab ID: 92455490001 Collected: 11/27/19 11:19 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:35 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:35 7440-38-2 30.0 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:35 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:35 7440-41-7 1.0 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:35 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:35 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:35 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:35 7440-50-8 2.5J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:35 7439-92-1 ND ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:35 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:35 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:35 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:35 7440-62-2 7.1J ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:35 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/28/19 02:23 12/03/19 17:32 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 02:06 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 02:06 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 02:06 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 02:06 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 02:06 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 02:06 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 02:06 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 02:06 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 02:06 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 02:06 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 02:06 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 02:06 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 02:06 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 02:06 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 02:06 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 02:06 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 02:06 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 02:06 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 02:06 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 02:06 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 02:06 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 02:06 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 02:06 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 02:06 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 02:06 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 02:06 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 02:06 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-1 Lab ID: 92455490001 Collected: 11/27/19 11:19 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 02:06 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 02:06 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 02:06 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 02:06 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 02:06 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 02:06 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 02:06 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 02:06 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 02:06 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 02:06 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 02:06 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 02:06 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 02:06 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 02:06 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 02:06 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 02:06 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 02:06 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 02:06 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 02:06 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 02:06 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 02:06 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 12/10/19 02:06 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/10/19 02:06 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 02:06 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-2 Lab ID: 92455490002 Collected: 11/27/19 08:37 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:38 7440-36-0 9.01 ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:38 7440-38-2 301 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:38 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:38 7440-41-7 1.2 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:38 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:38 7440-47-3 4.9J ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:38 7440-48-4 2.9J ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:38 7440-50-8 2.8J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:38 7439-92-1 2.6J ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:38 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:38 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:38 7440-22-4 1.4J ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:38 7440-62-2 9.8J ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:38 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/28/19 02:23 12/03/19 17:36 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 02:24 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 02:24 107-13-1 2.4 ug/L 1.0 0.15 1 12/10/19 02:24 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 02:24 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 02:24 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 02:24 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 02:24 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 02:24 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 02:24 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 02:24 56-23-5 6.0 ug/L 1.0 0.23 1 12/10/19 02:24 108-90-7 0.68J ug/L 1.0 0.49 1 12/10/19 02:24 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 02:24 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 02:24 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 02:24 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 02:24 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 02:24 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 02:24 74-95-3 5.2 ug/L 1.0 0.29 1 12/10/19 02:24 95-50-1 8.8 ug/L 1.0 0.26 1 12/10/19 02:24 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 02:24 110-57-6 0.50J ug/L 1.0 0.27 1 12/10/19 02:24 75-34-3 0.55J ug/L 1.0 0.34 1 12/10/19 02:24 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 02:24 75-35-4 0.32J ug/L 1.0 0.29 1 12/10/19 02:24 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 02:24 156-60-5 0.75J ug/L 1.0 0.19 1 12/10/19 02:24 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-2 Lab ID: 92455490002 Collected: 11/27/19 08:37 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 02:24 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 02:24 10061-02-6 1,4-Dioxane (p-Dioxane) 180 ug/L 150 56.2 1 12/10/19 02:24 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 02:24 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 02:24 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 02:24 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 02:24 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 02:24 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 02:24 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 02:24 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 02:24 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 02:24 127-18-4 Toluene 0.59J ug/L 1.0 0.24 1 12/10/19 02:24 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 02:24 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 02:24 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 02:24 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 02:24 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 02:24 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 02:24 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 02:24 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 02:24 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/10/19 02:24 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/10/19 02:24 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 12/10/19 02:24 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-3 Lab ID: 92455490003 Collected: 11/27/19 10:03 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:41 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:41 7440-38-2 74.2 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:41 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:41 7440-41-7 0.981 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:41 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:41 7440-47-3 5.OJ ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:41 7440-48-4 2.2J ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:41 7440-50-8 1.7J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:41 7439-92-1 41.8 ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:41 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:41 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:41 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:41 7440-62-2 12.2 ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:41 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/28/19 02:23 12/03/19 17:44 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 02:41 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 02:41 107-13-1 1.8 ug/L 1.0 0.15 1 12/10/19 02:41 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 02:41 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 02:41 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 02:41 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 02:41 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 02:41 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 02:41 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 02:41 56-23-5 0.46J ug/L 1.0 0.23 1 12/10/19 02:41 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 02:41 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 02:41 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 02:41 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 02:41 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 02:41 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 02:41 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 02:41 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 02:41 95-50-1 2.5 ug/L 1.0 0.26 1 12/10/19 02:41 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 02:41 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 02:41 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 02:41 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 02:41 75-35-4 8.3 ug/L 1.0 0.29 1 12/10/19 02:41 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 02:41 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 02:41 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-3 Lab ID: 92455490003 Collected: 11/27/19 10:03 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 02:41 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 02:41 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 02:41 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 02:41 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 02:41 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 02:41 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 02:41 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 02:41 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 02:41 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 02:41 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 02:41 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 02:41 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 02:41 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 02:41 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 02:41 79-00-5 Trichloroethene 0.891 ug/L 1.0 0.22 1 12/10/19 02:41 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 02:41 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 02:41 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 02:41 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 02:41 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 02:41 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 12/10/19 02:41 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/10/19 02:41 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 02:41 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-3A Lab ID: 92455490004 Collected: 11/27/19 08:46 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:45 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:45 7440-38-2 455 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:45 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:45 7440-41-7 3.8 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:45 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:45 7440-47-3 39.0 ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:45 7440-48-4 3.3J ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:45 7440-50-8 2.6J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:45 7439-92-1 51.1 ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:45 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:45 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:45 7440-22-4 1.81 ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:45 7440-62-2 8.01 ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:45 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 04:04 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 02:58 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 02:58 107-13-1 0.86J ug/L 1.0 0.15 1 12/10/19 02:58 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 02:58 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 02:58 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 02:58 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 02:58 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 02:58 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 02:58 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 02:58 56-23-5 4.8 ug/L 1.0 0.23 1 12/10/19 02:58 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 02:58 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 02:58 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 02:58 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 02:58 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 02:58 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 02:58 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 02:58 74-95-3 3.5 ug/L 1.0 0.29 1 12/10/19 02:58 95-50-1 11.6 ug/L 1.0 0.26 1 12/10/19 02:58 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 02:58 110-57-6 0.68J ug/L 1.0 0.27 1 12/10/19 02:58 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 02:58 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 02:58 75-35-4 11.5 ug/L 1.0 0.29 1 12/10/19 02:58 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 02:58 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 02:58 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-3A Lab ID: 92455490004 Collected: 11/27/19 08:46 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 02:58 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 02:58 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 02:58 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 02:58 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 02:58 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 02:58 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 02:58 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 02:58 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 02:58 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 02:58 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 02:58 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 02:58 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 02:58 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 02:58 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 02:58 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 02:58 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 02:58 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 02:58 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 02:58 108-05-4 Vinyl chloride 1.1 ug/L 1.0 0.24 1 12/10/19 02:58 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 02:58 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 12/10/19 02:58 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 12/10/19 02:58 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 02:58 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-4 Lab ID: 92455490005 Collected: 11/27/19 10:41 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:48 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:48 7440-38-2 22.1 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:48 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:48 7440-41-7 ND ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:48 7440-43-9 1.1J ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:48 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:48 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:48 7440-50-8 1.7J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:48 7439-92-1 ND ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:48 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:48 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:48 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:48 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:48 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 04:35 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 03:15 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 03:15 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 03:15 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 03:15 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 03:15 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 03:15 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 03:15 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 03:15 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 03:15 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 03:15 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 03:15 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 03:15 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 03:15 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 03:15 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 03:15 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 03:15 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 03:15 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 03:15 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 03:15 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 03:15 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 03:15 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 03:15 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 03:15 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 03:15 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 03:15 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 03:15 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 03:15 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-4 Lab ID: 92455490005 Collected: 11/27/19 10:41 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 03:15 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 03:15 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 03:15 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 03:15 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 03:15 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 03:15 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 03:15 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 03:15 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 03:15 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 03:15 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 03:15 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 03:15 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 03:15 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 03:15 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 03:15 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 03:15 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 03:15 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 03:15 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 03:15 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 03:15 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 03:15 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/10/19 03:15 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/10/19 03:15 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 03:15 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-5 Lab ID: 92455490006 Collected: 11/27/19 10:56 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:51 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:51 7440-38-2 20.2 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:51 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:51 7440-41-7 0.48J ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:51 7440-43-9 2.5J ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:51 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:51 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:51 7440-50-8 ND ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:51 7439-92-1 1.7J ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:51 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:51 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:51 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:51 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:51 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 04:39 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 03:33 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 03:33 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 03:33 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 03:33 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 03:33 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 03:33 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 03:33 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 03:33 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 03:33 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 03:33 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 03:33 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 03:33 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 03:33 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 03:33 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 03:33 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 03:33 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 03:33 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 03:33 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 03:33 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 03:33 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 03:33 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 03:33 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 03:33 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 03:33 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 03:33 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 03:33 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 03:33 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-5 Lab ID: 92455490006 Collected: 11/27/19 10:56 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 03:33 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 03:33 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 03:33 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 03:33 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 03:33 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 03:33 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 03:33 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 03:33 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 03:33 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 03:33 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 03:33 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 03:33 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 03:33 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 03:33 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 03:33 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 03:33 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 03:33 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 03:33 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 03:33 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 03:33 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 03:33 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 102 % 70-130 1 12/10/19 03:33 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/10/19 03:33 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 03:33 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-6 Lab ID: 92455490007 Collected: 11/27/19 11:31 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:54 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:54 7440-38-2 89.0 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:54 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:54 7440-41-7 1.3 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:54 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:54 7440-47-3 25.0 ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:54 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:54 7440-50-8 2.1J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:54 7439-92-1 1.81 ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:54 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:54 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:54 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:54 7440-62-2 3.9J ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:54 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 04:51 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 03:50 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 03:50 107-13-1 0.71J ug/L 1.0 0.15 1 12/10/19 03:50 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 03:50 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 03:50 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 03:50 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 03:50 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 03:50 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 03:50 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 03:50 56-23-5 6.1 ug/L 1.0 0.23 1 12/10/19 03:50 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 03:50 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 03:50 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 03:50 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 03:50 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 03:50 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 03:50 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 03:50 74-95-3 1.7 ug/L 1.0 0.29 1 12/10/19 03:50 95-50-1 2.9 ug/L 1.0 0.26 1 12/10/19 03:50 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 03:50 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 03:50 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 03:50 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 03:50 75-35-4 2.6 ug/L 1.0 0.29 1 12/10/19 03:50 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 03:50 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 03:50 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-6 Lab ID: 92455490007 Collected: 11/27/19 11:31 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 03:50 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 03:50 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 03:50 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 03:50 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 03:50 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 03:50 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 03:50 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 03:50 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 03:50 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 03:50 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 03:50 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 03:50 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 03:50 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 03:50 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 03:50 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 03:50 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 03:50 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 03:50 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 03:50 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 03:50 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 03:50 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 12/10/19 03:50 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/10/19 03:50 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 12/10/19 03:50 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-7S Lab ID: 92455490008 Collected: 11/27/19 09:11 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 03:57 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:57 7440-38-2 61.2 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:57 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 03:57 7440-41-7 6.6 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 03:57 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 03:57 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 03:57 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 03:57 7440-50-8 ND ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 03:57 7439-92-1 1.4J ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 03:57 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 03:57 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 03:57 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 03:57 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 03:57 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 04:59 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 04:07 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 04:07 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 04:07 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 04:07 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 04:07 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 04:07 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 04:07 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 04:07 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 04:07 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 04:07 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 04:07 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 04:07 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 04:07 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 04:07 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 04:07 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 04:07 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 04:07 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 04:07 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 04:07 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 04:07 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 04:07 110-57-6 0.47J ug/L 1.0 0.27 1 12/10/19 04:07 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 04:07 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 04:07 75-35-4 3.2 ug/L 1.0 0.29 1 12/10/19 04:07 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 04:07 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 04:07 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-7S Lab ID: 92455490008 Collected: 11/27/19 09:11 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 04:07 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 04:07 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 04:07 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 04:07 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 04:07 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 04:07 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 04:07 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 04:07 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 04:07 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 04:07 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 04:07 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 04:07 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 04:07 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 04:07 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 04:07 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 04:07 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 04:07 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 04:07 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 04:07 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 04:07 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 04:07 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 12/10/19 04:07 460-00-4 1,2-Dichloroethane-d4 (S) 98 % 70-130 1 12/10/19 04:07 17060-07-0 Toluene-d8 (S) 97 % 70-130 1 12/10/19 04:07 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-7D Lab ID: 92455490009 Collected: 11/27/19 09:19 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 04:00 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:00 7440-38-2 10.4 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:00 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 04:00 7440-41-7 5.1 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 04:00 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:00 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 04:00 7440-48-4 3.OJ ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 04:00 7440-50-8 1.91 ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 04:00 7439-92-1 4.8J ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 04:00 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:00 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 04:00 7440-22-4 1.6J ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 04:00 7440-62-2 4.1J ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 04:00 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 05:02 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 04:24 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 04:24 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 04:24 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 04:24 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 04:24 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 04:24 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 04:24 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 04:24 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 04:24 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 04:24 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 04:24 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 04:24 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 04:24 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 04:24 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 04:24 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 04:24 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 04:24 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 04:24 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 04:24 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 04:24 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 04:24 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 04:24 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 04:24 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 04:24 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 04:24 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 04:24 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 04:24 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-7D Lab ID: 92455490009 Collected: 11/27/19 09:19 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 04:24 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 04:24 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 04:24 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 04:24 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 04:24 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 04:24 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 04:24 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 04:24 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 04:24 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 04:24 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 04:24 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 04:24 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 04:24 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 04:24 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 04:24 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 04:24 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 04:24 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 04:24 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 04:24 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 04:24 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 04:24 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 12/10/19 04:24 460-00-4 1,2-Dichloroethane-d4 (S) 97 % 70-130 1 12/10/19 04:24 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 12/10/19 04:24 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-8 Lab ID: 92455490010 Collected: 11/27/19 11:24 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 04:04 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:04 7440-38-2 42.0 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:04 7440-39-3 0.31J ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 04:04 7440-41-7 1.7 ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 04:04 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:04 7440-47-3 2.3J ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 04:04 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 04:04 7440-50-8 1.7J ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 04:04 7439-92-1 6.4 ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 04:04 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:04 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 04:04 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 04:04 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 04:04 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 05:06 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 04:42 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 04:42 107-13-1 0.46J ug/L 1.0 0.15 1 12/10/19 04:42 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 04:42 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 04:42 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 04:42 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 04:42 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 04:42 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 04:42 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 04:42 56-23-5 0.29J ug/L 1.0 0.23 1 12/10/19 04:42 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 04:42 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 04:42 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 04:42 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 04:42 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 04:42 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 04:42 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 04:42 74-95-3 0.55J ug/L 1.0 0.29 1 12/10/19 04:42 95-50-1 0.79J ug/L 1.0 0.26 1 12/10/19 04:42 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 04:42 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 04:42 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 04:42 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 04:42 75-35-4 2.6 ug/L 1.0 0.29 1 12/10/19 04:42 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 04:42 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 04:42 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: MW-8 Lab ID: 92455490010 Collected: 11/27/19 11:24 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 04:42 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 04:42 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 04:42 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 04:42 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 04:42 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 04:42 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 04:42 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 04:42 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 04:42 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 04:42 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 04:42 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 04:42 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 04:42 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 04:42 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 04:42 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 04:42 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 04:42 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 04:42 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 04:42 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 04:42 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 04:42 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 12/10/19 04:42 460-00-4 1,2-Dichloroethane-d4 (S) 100 % 70-130 1 12/10/19 04:42 17060-07-0 Toluene-d8 (S) 99 % 70-130 1 12/10/19 04:42 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: SW-1 Lab ID: 92455490011 Collected: 11/27/19 09:36 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 04:19 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:19 7440-38-2 18.0 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:19 7440-39-3 0.22J ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 04:19 7440-41-7 ND ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 04:19 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:19 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 04:19 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 04:19 7440-50-8 1.91 ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 04:19 7439-92-1 ND ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 04:19 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:19 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 04:19 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 04:19 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 04:19 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 05:10 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 04:59 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 04:59 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 04:59 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 04:59 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 04:59 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 04:59 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 04:59 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 04:59 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 04:59 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 04:59 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 04:59 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 04:59 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 04:59 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 04:59 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 04:59 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 04:59 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 04:59 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 04:59 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 04:59 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 04:59 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 04:59 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 04:59 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 04:59 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 04:59 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 04:59 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 04:59 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 04:59 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: SW-1 Lab ID: 92455490011 Collected: 11/27/19 09:36 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 04:59 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 04:59 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 04:59 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 04:59 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 04:59 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 04:59 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 04:59 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 04:59 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 04:59 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 04:59 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 04:59 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 04:59 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 04:59 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 04:59 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 04:59 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 04:59 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 04:59 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 04:59 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 04:59 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 04:59 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 04:59 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 105 % 70-130 1 12/10/19 04:59 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 12/10/19 04:59 17060-07-0 Toluene-d8 (S) 98 % 70-130 1 12/10/19 04:59 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: SW-2 Lab ID: 92455490012 Collected: 11/27/19 09:48 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 12/10/2019 04:50 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/28/19 01:34 12/03/19 04:22 7440-36-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:22 7440-38-2 17.5 ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:22 7440-39-3 ND ug/L 1.0 0.20 1 11/28/19 01:34 12/03/19 04:22 7440-41-7 0.53J ug/L 1.0 0.40 1 11/28/19 01:34 12/03/19 04:22 7440-43-9 ND ug/L 5.0 1.0 1 11/28/19 01:34 12/03/19 04:22 7440-47-3 ND ug/L 5.0 1.1 1 11/28/19 01:34 12/03/19 04:22 7440-48-4 ND ug/L 5.0 2.1 1 11/28/19 01:34 12/03/19 04:22 7440-50-8 ND ug/L 5.0 1.6 1 11/28/19 01:34 12/03/19 04:22 7439-92-1 ND ug/L 5.0 0.90 1 11/28/19 01:34 12/03/19 04:22 7440-02-0 ND ug/L 10.0 4.7 1 11/28/19 01:34 12/03/19 04:22 7782-49-2 ND ug/L 5.0 2.5 1 11/28/19 01:34 12/03/19 04:22 7440-22-4 ND ug/L 5.0 1.3 1 11/28/19 01:34 12/03/19 04:22 7440-62-2 ND ug/L 10.0 3.9 1 11/28/19 01:34 12/03/19 04:22 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 12/03/19 00:42 12/04/19 05:14 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 12/10/19 05:34 67-64-1 ND ug/L 10.0 0.90 1 12/10/19 05:34 107-13-1 ND ug/L 1.0 0.15 1 12/10/19 05:34 71-43-2 ND ug/L 1.0 0.34 1 12/10/19 05:34 74-97-5 ND ug/L 1.0 0.26 1 12/10/19 05:34 75-27-4 ND ug/L 1.0 0.62 1 12/10/19 05:34 75-25-2 ND ug/L 2.0 0.62 1 12/10/19 05:34 74-83-9 ND ug/L 5.0 3.3 1 12/10/19 05:34 78-93-3 ND ug/L 2.0 0.40 1 12/10/19 05:34 75-15-0 ND ug/L 1.0 0.22 1 12/10/19 05:34 56-23-5 ND ug/L 1.0 0.23 1 12/10/19 05:34 108-90-7 ND ug/L 1.0 0.49 1 12/10/19 05:34 75-00-3 ND ug/L 5.0 2.3 1 12/10/19 05:34 67-66-3 ND ug/L 1.0 0.39 1 12/10/19 05:34 74-87-3 ND ug/L 5.0 0.26 1 12/10/19 05:34 96-12-8 ND ug/L 1.0 0.41 1 12/10/19 05:34 124-48-1 ND ug/L 1.0 0.26 1 12/10/19 05:34 106-93-4 ND ug/L 1.0 0.46 1 12/10/19 05:34 74-95-3 ND ug/L 1.0 0.29 1 12/10/19 05:34 95-50-1 ND ug/L 1.0 0.26 1 12/10/19 05:34 106-46-7 ND ug/L 1.0 0.54 1 12/10/19 05:34 110-57-6 ND ug/L 1.0 0.27 1 12/10/19 05:34 75-34-3 ND ug/L 1.0 0.34 1 12/10/19 05:34 107-06-2 ND ug/L 1.0 0.24 1 12/10/19 05:34 75-35-4 ND ug/L 1.0 0.29 1 12/10/19 05:34 156-59-2 ND ug/L 1.0 0.25 1 12/10/19 05:34 156-60-5 ND ug/L 1.0 0.19 1 12/10/19 05:34 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Sample: SW-2 Lab ID: 92455490012 Collected: 11/27/19 09:48 Received: 11/27/19 14:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 12/10/19 05:34 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 12/10/19 05:34 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 12/10/19 05:34 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 12/10/19 05:34 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 12/10/19 05:34 591-78-6 lodomethane ND ug/L 20.0 12.5 1 12/10/19 05:34 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 12/10/19 05:34 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 12/10/19 05:34 108-10-1 Styrene ND ug/L 1.0 0.27 1 12/10/19 05:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 12/10/19 05:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 12/10/19 05:34 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 12/10/19 05:34 127-18-4 Toluene ND ug/L 1.0 0.24 1 12/10/19 05:34 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 12/10/19 05:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 12/10/19 05:34 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 12/10/19 05:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 12/10/19 05:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 12/10/19 05:34 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 12/10/19 05:34 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 12/10/19 05:34 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 12/10/19 05:34 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 104 % 70-130 1 12/10/19 05:34 460-00-4 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 12/10/19 05:34 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 12/10/19 05:34 2037-26-5 Date: 12/10/2019 04:50 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 QC Batch: 512234 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92455490001, 92455490002, 92455490003, 92455490004, 92455490005, 92455490006, 92455490007, 92455490008,92455490009,92455490010,92455490011,92455490012 METHOD BLANK: 2746960 Matrix: Water Associated Lab Samples: 92455490001, 92455490002, 92455490003, 92455490004, 92455490005, 92455490006, 92455490007, 92455490008,92455490009,92455490010,92455490011,92455490012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 12/03/19 02:41 Arsenic ug/L ND 10.0 4.7 12/03/19 02:41 Barium ug/L ND 5.0 1.0 12/03/19 02:41 Beryllium ug/L ND 1.0 0.20 12/03/19 02:41 Cadmium ug/L ND 1.0 0.40 12/03/19 02:41 Chromium ug/L ND 5.0 1.0 12/03/19 02:41 Cobalt ug/L ND 5.0 1.1 12/03/19 02:41 Copper ug/L ND 5.0 2.1 12/03/19 02:41 Lead ug/L ND 5.0 1.6 12/04/19 00:13 Nickel ug/L ND 5.0 0.90 12/03/19 02:41 Selenium ug/L ND 10.0 4.7 12/03/19 02:41 Silver ug/L ND 5.0 2.5 12/03/19 02:41 Vanadium ug/L ND 5.0 1.3 12/03/19 02:41 Zinc ug/L ND 10.0 3.9 12/03/19 02:41 LABORATORY CONTROL SAMPLE: Parameter 2746961 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 454 91 80-120 Arsenic ug/L 500 450 90 80-120 Barium ug/L 500 459 92 80-120 Beryllium ug/L 500 445 89 80-120 Cadmium ug/L 500 449 90 80-120 Chromium ug/L 500 447 89 80-120 Cobalt ug/L 500 450 90 80-120 Copper ug/L 500 450 90 80-120 Lead ug/L 500 449 90 80-120 Nickel ug/L 500 443 89 80-120 Selenium ug/L 500 445 89 80-120 Silver ug/L 250 226 90 80-120 Vanadium ug/L 500 450 90 80-120 Zinc ug/L 500 445 89 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Closed LF-Elkin 92455490 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2746962 2746963 MS MSD 92455507006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 484 466 97 93 75-125 4 20 Arsenic ug/L ND 500 500 489 478 98 96 75-125 2 20 Barium ug/L 72.6 500 500 552 536 96 93 75-125 3 20 Beryllium ug/L ND 500 500 467 454 93 91 75-125 3 20 Cadmium ug/L ND 500 500 478 465 96 93 75-125 3 20 Chromium ug/L ND 500 500 469 463 94 93 75-125 1 20 Cobalt ug/L ND 500 500 472 460 94 92 75-125 3 20 Copper ug/L ND 500 500 476 467 95 93 75-125 2 20 Lead ug/L 2.6J 500 500 471 459 94 91 75-125 3 20 Nickel ug/L 1.81 500 500 465 453 93 90 75-125 3 20 Selenium ug/L ND 500 500 518 502 103 100 75-125 3 20 Silver ug/L ND 250 250 240 235 96 94 75-125 2 20 Vanadium ug/L ND 500 500 479 466 96 93 75-125 3 20 Zinc ug/L ND 500 500 480 466 95 93 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 QC Batch: 512230 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92455490001, 92455490002, 92455490003 METHOD BLANK: 2746944 Matrix: Water Associated Lab Samples: 92455490001, 92455490002, 92455490003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/03/1915:16 LABORATORY CONTROL SAMPLE: 2746945 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.7 97 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2746946 2746947 MS MSD 92455507005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.9 9.8 99 98 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 QC Batch: 512475 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92455490004, 92455490005, 92455490006, 92455490007, 92455490008, 92455490009, 92455490010, 92455490011,92455490012 METHOD BLANK: 2747937 Matrix: Water Associated Lab Samples: 92455490004, 92455490005, 92455490006, 92455490007, 92455490008, 92455490009, 92455490010, 92455490011,92455490012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 12/04/19 03:29 LABORATORY CONTROL SAMPLE: 2747938 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2747939 2747940 MS MSD 92455490004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 11.0 10.4 110 104 75-125 5 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 QC Batch: 513749 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92455490001, 92455490002, 92455490003, 92455490004, 92455490005, 92455490006, 92455490007, 92455490008,92455490009,92455490010,92455490011,92455490012 METHOD BLANK: 2753980 Matrix: Water Associated Lab Samples: 92455490001, 92455490002, 92455490003, 92455490004, 92455490005, 92455490006, 92455490007, 92455490008,92455490009,92455490010,92455490011,92455490012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 12/10/19 01:49 1,1,1-Trichloroethane ug/L ND 1.0 0.18 12/10/19 01:49 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 12/10/19 01:49 1,1,2-Trichloroethane ug/L ND 1.0 0.24 12/10/19 01:49 1,1-Dichloroethane ug/L ND 1.0 0.27 12/10/19 01:49 1,1-Dichloroethene ug/L ND 1.0 0.24 12/10/19 01:49 1,2,3-Trichloropropane ug/L ND 1.0 0.35 12/10/19 01:49 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 12/10/19 01:49 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 12/10/19 01:49 1,2-Dichlorobenzene ug/L ND 1.0 0.29 12/10/19 01:49 1,2-Dichloroethane ug/L ND 1.0 0.34 12/10/19 01:49 1,2-Dichloropropane ug/L ND 1.0 0.19 12/10/19 01:49 1,4-Dichlorobenzene ug/L ND 1.0 0.26 12/10/19 01:49 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 12/10/19 01:49 2-Butanone (MEK) ug/L ND 5.0 3.3 12/10/19 01:49 2-Hexanone ug/L ND 5.0 0.57 12/10/19 01:49 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 12/10/19 01:49 Acetone ug/L ND 25.0 6.2 12/10/19 01:49 Acrylonitrile ug/L ND 10.0 0.90 12/10/19 01:49 Benzene ug/L ND 1.0 0.15 12/10/19 01:49 Bromochloromethane ug/L ND 1.0 0.34 12/10/19 01:49 Bromodichloromethane ug/L ND 1.0 0.26 12/10/19 01:49 Bromoform ug/L ND 1.0 0.62 12/10/19 01:49 Bromomethane ug/L ND 2.0 0.62 12/10/19 01:49 Carbon disulfide ug/L ND 2.0 0.40 12/10/19 01:49 Carbon tetrachloride ug/L ND 1.0 0.22 12/10/19 01:49 Chlorobenzene ug/L ND 1.0 0.23 12/10/19 01:49 Chloroethane ug/L ND 1.0 0.49 12/10/19 01:49 Chloroform ug/L ND 5.0 2.3 12/10/19 01:49 Chloromethane ug/L ND 1.0 0.39 12/10/19 01:49 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 12/10/19 01:49 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 12/10/19 01:49 Dibromochloromethane ug/L ND 1.0 0.41 12/10/19 01:49 Dibromomethane ug/L ND 1.0 0.46 12/10/19 01:49 Ethylbenzene ug/L ND 1.0 0.26 12/10/19 01:49 lodomethane ug/L ND 20.0 12.5 12/10/19 01:49 Methylene Chloride ug/L ND 5.0 3.7 12/10/19 01:49 Styrene ug/L ND 1.0 0.27 12/10/19 01:49 Tetrachloroethene ug/L ND 1.0 0.16 12/10/19 01:49 Toluene ug/L ND 1.0 0.24 12/10/19 01:49 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 METHOD BLANK: 2753980 Matrix: Water Associated Lab Samples: 92455490001, 92455490002, 92455490003, 92455490004, 92455490005, 92455490006, 92455490007, 92455490008,92455490009,92455490010,92455490011,92455490012 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 12/10/19 01:49 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 12/10/19 01:49 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 12/10/19 01:49 Trichloroethene ug/L ND 1.0 0.22 12/10/19 01:49 Trichlorofluoromethane ug/L ND 1.0 0.31 12/10/19 01:49 Vinyl acetate ug/L ND 2.0 1.4 12/10/19 01:49 Vinyl chloride ug/L ND 1.0 0.24 12/10/19 01:49 Xylene (Total) ug/L ND 1.0 0.63 12/10/19 01:49 1,2-Dichloroethane-d4 (S) % 96 70-130 12/10/19 01:49 4-Bromofluorobenzene (S) % 102 70-130 12/10/19 01:49 Toluene-d8 (S) % 99 70-130 12/10/19 01:49 LABORATORY CONTROL SAMPLE: 2753981 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 48.6 97 70-130 1,1,1-Trichloroethane ug/L 50 46.1 92 70-130 1,1,2,2-Tetrachloroethane ug/L 50 49.2 98 70-130 1,1,2-Trichloroethane ug/L 50 49.4 99 70-130 1,1-Dichloroethane ug/L 50 46.6 93 70-130 1,1-Dichloroethene ug/L 50 45.8 92 70-130 1,2,3-Trichloropropane ug/L 50 49.5 99 70-130 1,2-Dibromo-3-chloropropane ug/L 50 49.3 99 70-130 1,2-Dibromoethane (EDB) ug/L 50 48.0 96 70-130 1,2-Dichlorobenzene ug/L 50 49.7 99 70-130 1,2-Dichloroethane ug/L 50 46.8 94 70-130 1,2-Dichloropropane ug/L 50 48.3 97 70-130 1,4-Dichlorobenzene ug/L 50 49.5 99 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1000 100 59-169 2-Butanone (MEK) ug/L 100 94.9 95 64-135 2-Hexanone ug/L 100 92.4 92 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 93.5 93 70-130 Acetone ug/L 100 96.5 97 61-157 Acrylonitrile ug/L 250 229 92 61-143 Benzene ug/L 50 47.8 96 70-130 Bromochloromethane ug/L 50 46.9 94 70-130 Bromodichloromethane ug/L 50 46.3 93 70-130 Bromoform ug/L 50 47.7 95 70-130 Bromomethane ug/L 50 54.3 109 38-130 Carbon disulfide ug/L 50 48.5 97 68-130 Carbon tetrachloride ug/L 50 45.5 91 70-130 Chlorobenzene ug/L 50 49.0 98 70-130 Chloroethane ug/L 50 41.5 83 37-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 LABORATORY CONTROL SAMPLE: 2753981 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloroform ug/L 50 48.5 97 70-130 Chloromethane ug/L 50 36.8 74 48-130 cis-1,2-Dichloroethene ug/L 50 46.8 94 70-130 cis-1,3-Dichloropropene ug/L 50 50.2 100 70-130 Dibromochloromethane ug/L 50 46.9 94 70-130 Dibromomethane ug/L 50 48.8 98 70-130 Ethylbenzene ug/L 50 49.1 98 70-130 lodomethane ug/L 100 96.2 96 40-130 Methylene Chloride ug/L 50 44.4 89 67-132 Styrene ug/L 50 48.4 97 70-130 Tetrachloroethene ug/L 50 44.2 88 69-130 Toluene ug/L 50 48.3 97 70-130 trans-1,2-Dichloroethene ug/L 50 46.7 93 70-130 trans- 1,3-Dichloropropene ug/L 50 49.4 99 70-130 trans-1,4-Dichloro-2-butene ug/L 50 56.6 113 35-189 Trichloroethene ug/L 50 47.5 95 70-130 Trichlorofluoromethane ug/L 50 44.7 89 63-130 Vinyl acetate ug/L 100 100 100 55-143 Vinyl chloride ug/L 50 45.7 91 70-131 Xylene (Total) ug/L 150 144 96 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 MATRIX SPIKE SAMPLE: 2753983 92455490012 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.9 110 73-134 1,1,1-Trichloroethane ug/L ND 20 21.7 109 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 21.7 108 70-136 1,1,2-Trichloroethane ug/L ND 20 22.2 111 70-135 1,1-Dichloroethane ug/L ND 20 21.7 108 70-139 1,1-Dichloroethene ug/L ND 20 21.5 108 70-154 1,2,3-Trichloropropane ug/L ND 20 22.1 111 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 20.3 101 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.9 109 70-137 1,2-Dichlorobenzene ug/L ND 20 22.2 111 70-133 1,2-Dichloroethane ug/L ND 20 21.1 105 70-137 1,2-Dichloropropene ug/L ND 20 21.5 108 70-140 1,4-Dichlorobenzene ug/L ND 20 22.5 113 70-133 1,4-Dioxane (p-Dioxane) ug/L ND 400 405 101 53-168 2-Butanone (MEK) ug/L ND 40 38.7 97 60-139 2-Hexanone ug/L ND 40 37.1 93 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 37.7 94 65-135 Acetone ug/L ND 40 38.7 97 60-148 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 MATRIX SPIKE SAMPLE: Parameter 2753983 Units 92455490012 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers Acrylonitrile ug/L ND 100 96.3 96 64-147 Benzene ug/L ND 20 22.6 113 70-151 Bromochloromethane ug/L ND 20 21.4 107 70-141 Bromodichloromethane ug/L ND 20 20.7 104 70-138 Bromoform ug/L ND 20 19.7 98 63-130 Bromomethane ug/L ND 20 27.1 135 15-152 Carbon disulfide ug/L ND 20 22.9 114 69-149 Carbon tetrachloride ug/L ND 20 21.7 108 70-143 Chlorobenzene ug/L ND 20 22.4 112 70-138 Chloroethane ug/L ND 20 20.3 101 52-163 Chloroform ug/L ND 20 23.1 116 70-139 Chloromethane ug/L ND 20 16.6 83 41-139 cis-1,2-Dichloroethene ug/L ND 20 21.8 109 70-141 cis-1,3-Dichloropropene ug/L ND 20 22.8 114 70-137 Dibromochloromethane ug/L ND 20 20.2 101 70-134 Dibromomethane ug/L ND 20 22.0 110 70-138 Ethylbenzene ug/L ND 20 23.2 116 66-153 lodomethane ug/L ND 40 41.2 103 20-138 Methylene Chloride ug/L ND 20 20.3 101 42-159 Styrene ug/L ND 20 21.8 109 70-135 Tetrachloroethene ug/L ND 20 20.7 103 59-143 Toluene ug/L ND 20 22.2 111 59-148 trans-1,2-Dichloroethene ug/L ND 20 22.0 110 70-146 trans- 1,3-Dichloropropene ug/L ND 20 21.9 110 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 20.5 103 47-135 Trichloroethene ug/L ND 20 22.9 114 70-147 Trichlorofluoromethane ug/L ND 20 22.1 111 70-148 Vinyl acetate ug/L ND 40 41.3 103 49-151 Vinyl chloride ug/L ND 20 20.9 104 70-156 Xylene (Total) ug/L ND 60 67.9 113 63-158 1,2-Dichloroethane-d4 (S) % 95 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 98 70-130 SAMPLE DUPLICATE: 2753982 92455490011 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 42 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Closed LF-Elkin Pace Project No.: 92455490 SAMPLE DUPLICATE: 2753982 Parameter Units 92455490011 Result Dup Result RPD Max RPD 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 1,4-Dioxane (p-Dioxane) ug/L ND ND 30 2-Butanone (MEK) ug/L ND ND 30 2-Hexanone ug/L ND ND 30 4-Methyl-2-pentanone (MIBK) ug/L ND ND 30 Acetone ug/L ND ND 30 Acrylonitrile ug/L ND ND 30 Benzene ug/L ND ND 30 Bromochloromethane ug/L ND ND 30 Bromodichloromethane ug/L ND ND 30 Bromoform ug/L ND ND 30 Bromomethane ug/L ND ND 30 Carbon disulfide ug/L ND ND 30 Carbon tetrachloride ug/L ND ND 30 Chlorobenzene ug/L ND ND 30 Chloroethane ug/L ND ND 30 Chloroform ug/L ND ND 30 Chloromethane ug/L ND ND 30 cis-1,2-Dichloroethene ug/L ND ND 30 cis-1,3-Dichloropropene ug/L ND ND 30 Dibromochloromethane ug/L ND ND 30 Dibromomethane ug/L ND ND 30 Ethylbenzene ug/L ND ND 30 lodomethane ug/L ND ND 30 Methylene Chloride ug/L ND ND 30 Styrene ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 Toluene ug/L ND ND 30 trans-1,2-Dichloroethene ug/L ND ND 30 trans- 1,3-Dichloropropene ug/L ND ND 30 trans-1,4-Dichloro-2-butene ug/L ND ND 30 Trichloroethene ug/L ND ND 30 Trichlorofluoromethane ug/L ND ND 30 Vinyl acetate ug/L ND ND 30 Vinyl chloride ug/L ND ND 30 Xylene (Total) ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 99 99 4-Bromofluorobenzene (S) % 105 104 Toluene-d8 (S) % 98 97 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Closed LF-Elkin Pace Project No.: 92455490 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 42 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Closed LF-Elkin Pace Project No.: 92455490 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92455490001 MW-1 EPA 3010A 512234 EPA 6010D 512239 92455490002 MW-2 EPA 3010A 512234 EPA 6010D 512239 92455490003 MW-3 EPA 3010A 512234 EPA 6010D 512239 92455490004 MW-3A EPA 3010A 512234 EPA 6010D 512239 92455490005 MW-4 EPA 3010A 512234 EPA 6010D 512239 92455490006 MW-5 EPA 3010A 512234 EPA 6010D 512239 92455490007 MW-6 EPA 3010A 512234 EPA 6010D 512239 92455490008 MW-7S EPA 3010A 512234 EPA 6010D 512239 92455490009 MW-7D EPA 3010A 512234 EPA 6010D 512239 92455490010 MW-8 EPA 3010A 512234 EPA 6010D 512239 92455490011 SW-1 EPA 3010A 512234 EPA 6010D 512239 92455490012 SW-2 EPA 3010A 512234 EPA 6010D 512239 92455490001 MW-1 EPA 3010A 512230 EPA 6020B 512244 92455490002 MW-2 EPA 3010A 512230 EPA 6020B 512244 92455490003 MW-3 EPA 3010A 512230 EPA 6020B 512244 92455490004 MW-3A EPA 3010A 512475 EPA 6020B 512494 92455490005 MW-4 EPA 3010A 512475 EPA 6020B 512494 92455490006 MW-5 EPA 3010A 512475 EPA 6020B 512494 92455490007 MW-6 EPA 3010A 512475 EPA 6020B 512494 92455490008 MW-7S EPA 3010A 512475 EPA 6020B 512494 92455490009 MW-7D EPA 3010A 512475 EPA 6020B 512494 92455490010 MW-8 EPA 3010A 512475 EPA 6020B 512494 92455490011 SW-1 EPA 3010A 512475 EPA 6020B 512494 92455490012 SW-2 EPA 3010A 512475 EPA 6020B 512494 92455490001 MW-1 EPA 8260D 513749 92455490002 MW-2 EPA 8260D 513749 92455490003 MW-3 EPA 8260D 513749 92455490004 MW-3A EPA 8260D 513749 92455490005 MW-4 EPA 8260D 513749 92455490006 MW-5 EPA 8260D 513749 92455490007 MW-6 EPA 8260D 513749 92455490008 MW-7S EPA 8260D 513749 92455490009 MW-7D EPA 8260D 513749 92455490010 MW-8 EPA 8260D 513749 92455490011 SW-1 EPA 8260D 513749 92455490012 SW-2 EPA 8260D 513749 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/10/2019 04:50 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 42 Document Name: Document Revised: February 7, 2018 m aCL'ARc3�ytlCa� Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quaky Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh[] Mechanicsville[] Sample Condition Client Name: 1 L (q Courier: ❑Fed Ex [—]UPS ❑USPS ,ent ❑ commercial ❑Pace ' ❑Other. Custody Seal Present? ❑Yes 2 Seals Intact? Oyes Packing Material: ❑Bubble Wrap Zgubble Bags ❑None ❑ Other Thermometer: IR Gun ID: 92TO5$ Type of Ice: et ❑Blue Cooler Temp (°C): Correction Factor: Add/Subtract VC) O.0°C Cooler Temp Corrected (°Cl:_ USDA Regulated Sall ( "NIA, water sample) Did samples origipW in a quarantine zone within the United States: CA, NY, or 5C (check maps)? r1Ves o WO#:92455490 1111111111111111111111 92435490 Date/Initials Person Examining Content- )/ T 277fF Biological ssue Frozen? Elvesto ❑N/A ❑Nacre Temp should be abave freezing to VC ❑5amples out of temp criteria. Samples an ice, cooling process has begun Did samples originate from a foreign source (internationally, In r6 idina Hawaii —4 0.—m 01-17 FIV- F-1rvn Comm ents/Disere pane . Chain of Custody Present? es ❑Na El N/A 1. Samples Arrived within Hold Time? J2 es [:IN. ❑N/A 2. Short Hold InmeAnalysls (<72 hr.)? []Yes No N/A 3. Rush Turn Around Time Requested? Des Na ❑N/A 4. Sufficient volume? es []No []N/A S. Correct Containers Used? Pace Containers Used? ElYes es ❑No ❑No ❑N/A []NIA 6. Containers Intact? ❑Yes o ❑NIA 7. Dissolved analysis: Samples Field Filtered? [:)Ye []No N/A B. Sample Labels IiMatch COC7 -Includes Date/Time/ID/Analysis Matrix: es i ❑No (]N/A 9. Headspace in VOA Vials {>5-6mm)? ❑Yes ErNG _ N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Yes o No ❑NIA N/A 11. DISCREPANCY / 0 JQ17 11,, n~~ Lot iD of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Oate/11-ime: Project Manager SCURF Review: Project Manager SRF Review: Field Data Requlred? []Yes []No Date: _ i 1 J0�I —1 /C- Date: 4 �a1 mi(. 07 Page 40 of 42 Document Name. Document Revised: February 7, 2018 �AwnaWical` Sample Condition Upon Recelpt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination Is verified and within the acceptance range for preservation samples. Exceptions- VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project # Wp# : 9245549® PM: AMB Due Date: 12/13/19 CLIENT: 92-Municipal V Z V V Z Q V — ? Z 2 Z .- 2 a Z N _ Z a ro m d V Z Z 2 = v n 2 v x = _ Q z 4 Q Z v ? Q. a z z a ? c O y av m v c m a y z O07 ¢ o c O OO z cc n fJ _ N E Z Q O C 7 C = Z .fl C U N = Q vl N a > q Z Z) U M N C V ro rY�'o .Y io a .o p q Q q a y EE aa n a a 2 E Q Q ry O O O0 6 n v °. q a , >Ln > G �n q E E E m E E E E v r a E M E 9 E E E E E - = E E �+ o E N v0 n n v�, N ry r r v tp o 0 0 o V o V1 a a N e-1 -e'1 _- N ti N n �r er —y - N ri N 7 tt E 1�l r i rl M rl M M z T 0 III CI Q �jj N Q a 01 a� 7 a M a N n .-/ a Q a M a V a -r Q. W 0 U 0 W 0 10 W O Vr i�1 o m com m m m ca [aa a ¢ a a a o > > o > v°i cca > f z J 3 I � 7 I B y I S f t0 y / -I N\�N- I pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon retelpt Date preservation adjusted Time preservation adjusted Amount of Prese• ative added Lot tl Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DFHNR Certification Office (i.e. but of hold, incorrect preservative, out of temp, incorrect containers. 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