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HomeMy WebLinkAbout21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1_2 Via Email March 20, 2020 NCDEQ – Division of Waste Management Brownfields Program 1646 Mail Service Center Raleigh, NC 27699-1646 Attn: Ms. Joselyn Harriger, PG Re: Request for Occupancy – Building 2 and Carriage Houses B, C, & D – Revision 1 Radiator Specialty Tract E Broadstone Bryant Park Apartment Complex Charlotte, Mecklenburg County, North Carolina Brownfields Project No. 21032-17-060 H&H Project No. ALI-002 Dear Joselyn: 1.0 Introduction On behalf of Broadstone Bryant Park Alliance (BBPA), LLC, Hart & Hickman, PC (H&H) has prepared this Revision 1 letter report summarizing vapor intrusion mitigation system (VIMS) inspection, pre-occupancy testing, and sampling activities conducted at Building 2 and Carriage Houses B, C, & D, located on the Radiator Specialty – Tract E Brownfields property (Site). The Site is part of the North Carolina Department of Environmental Quality (DEQ) Brownfields Program (Brownfields Project No. 21032-17-060) and is located in Charlotte, Mecklenburg County, North Carolina. The Site is being redeveloped with a residential apartment complex that includes a clubhouse building (Clubhouse), three (3) carriage houses (Carriage Houses B, C, & D), and four (4) apartment buildings (Buildings 1 through 4) that are collectively known as the Broadstone Bryant Park Apartment (Bryant Park) complex. The VIMS installation at Buildings 1, 3, & 4, and the Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 2 2 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx Clubhouse were reported in Request for Occupancy reports previously submitted to DEQ. Building 4 and the Clubhouse received DEQ approval for occupancy on October 25, 2019, and Buildings 1 and 3 received DEQ approval for occupancy on January 13, 2020. Building 2 is an apartment building consisting of a total of five floors with multiple residential tenant spaces on each floor. The ground floor of Building 2 is split into two levels, Building 2 Basement and Building 2 Floor 1. Carriage Houses B, C, & D are townhome-style dwellings with a total of two floors each. Carriage House A, which was proposed in the original site plans, was removed from the proposed plans and will not be constructed. The general construction of foundations for each of these buildings consist of a concrete slab with load-bearing thickened concrete footers located between units or below load-bearing walls. The split ground floor levels in Building 2 are separated by concrete retaining walls. The approximate area of each of the ground floor levels for the buildings are listed in the table below. Ground Floor Level Approximate Area (square feet) Building 2 Basement 5,800 Building 2 Floor 1 15,000 Carriage House B Floor 1 1,350 Carriage House C Floor 1 1,350 Carriage House D Floor 1 1,100 In accordance with the Vapor Intrusion Mitigation System Design Report (VIMS Design Report), prepared by Engineering & Land Planning Associates, Inc. (E&LP), dated April 19, 2018, and approved by DEQ on May 17, 2018, H&H conducted above-slab VIMS inspections, pre- occupancy testing, and sub-slab analytical sampling of Building 2 and Carriage Houses B, C, & D. In addition, the sub-grade VIMS components, including a gravel base layer, Land Science Vapor Vent™, and Land Science Geo-Seal® vapor barrier were installed by a Geo-seal® certified installer/applicator, Contaminant Control Inc. (CCI), and was inspected by a Geo-Seal® certified Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 3 3 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx inspector from Intertek PSI (PSI). It should be noted that the sub-grade VIMS inspections for Carriage House D were conducted by a Geo-Seal®-certified inspector from H&H. The VIMS in Building 2 and Carriage Houses consist of passive vapor extraction systems with sub-slab vapor venting coupled with the Land Science Geo-Seal™ vapor barrier. The Geo-Seal® vapor barrier is located below the concrete slab of each ground floor level and, when applicable in Building 2, along the vertical sections of the concrete retaining walls located between the ground floor split levels. The Geo-Seal® vapor barrier includes 3 layers. The first layer consists of Geo- Seal™ BASE, followed by Geo-Seal™ CORE (30-dry mils), and finished with Geo-Seal™ BOND, for a total vapor barrier thickness of approximately 53 mils. Note, the installed thickness of the Geo-Seal CORE layer may vary slightly due to the spray applied installation method and weather conditions. In addition, Geo-Seal Vapor VentTM is installed within a sub-slab gravel layer to capture vapors migrating through the sub-slab annular space. The Vapor Vent™ is connected to 4-inch poly-vinyl chloride (PVC) riser vapor conveyance piping. Following installation of sub- slab portions of the VIMS and concrete slab, the 4-inch PVC vapor conveyance piping was run through walls of the buildings and terminated two feet above the roofline. Empire Model TV04G passive turbine ventilator wind driven fans were installed on the conveyance piping above the roofline. Following construction of the VIMS, H&H collected sub-slab vapor samples from solid 1-inch PVC permanent monitoring points which are screened in the gravel layer beneath the Geo-Seal™ vapor barrier of the buildings. A total of six sub-slab vapor samples were collected from Building 2, a total of two sub-slab samples were collected from Carriage House C (including a duplicate sample), and one sub-slab vapor sample was collected from each of Carriage Houses B and D. To further evaluate the detected VOCs, H&H input the concentrations of the compounds detected in each sub-slab vapor sample into the DEQ Risk Calculator (December 2019 Version). Calculations were run for residential use scenarios for the soil gas to indoor air exposure pathway to calculate cumulative potential carcinogenic and non-carcinogenic risks for the sub-slab vapor Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 4 4 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx samples. The risk calculations from the analytical data of the sub-slab samples indicated that Building 2 and Carriage Houses sub-slab vapor concentrations are within acceptable risk levels. The methods and results of sub-slab sampling are further discussed in Section 2.3. Based on the results of the inspection, testing, and sampling activities, H&H requests that the DEQ Brownfields Program acknowledge compliance of Land Use Restriction (LUR) 5 of the Notice of Brownfields Property and grant occupancy for Building 2 and Carriage Houses B, C, & D. The Site Layout Map is provided as Figure 1 and the VIMP Master Summary is included as Table 1. Representative photos of the VIMS installation are included as Appendix A. A summary of the VIMS installation inspection, pre-occupancy testing, and sampling activities is provided in the following sections. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 5 5 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx 2.0 VIMS Inspections, Testing, and Sampling During construction activities, the sub-slab portions of the VIMS were installed by CCI, a Geo- Seal® certified installer, and inspected by PSI, a Geo-Seal® certified inspector. In addition to the inspections performed by PSI, H&H conducted separate inspections of select sub-slab components and inspections of above-grade components of the VIMS. As indicated in Sections 1 and 2.1, both the sub-slab portions and above-grade components for Carriage House D were each conducted by a Geo-Seal®-certified inspector from H&H. In addition, H&H performed pre-occupancy testing and analytical sampling activities. The inspections, pre-occupancy testing, and sampling activities are summarized below in the following sections. 2.1 VIMS Inspections Between March 2019 and December 2019 (Building 2), between November 2019 and December 2019 (Carriage Houses B and C), and between August 2019 and December 2019 (Carriage House D), the VIMS were inspected at the following various stages during the construction process, including after completion of the Vapor Vent™ sub-slab vapor collection system and gravel layout, after placement of the Geo-Seal® vapor barrier and prior to the concrete pour, after installation of above-grade riser piping, and after installation of the Empire Model TV04G passive turbine ventilator fans. Each of the sub-slab VIMS components were inspected by PSI, while the above grade VIMS components were inspected by H&H, with the exception of Carriage House D, for which a Geo- Seal®-certified inspector from H&H performed the inspections. Following inspections of sub- slab portions of the VIMS, coupons of the Geo-SealTM BASE and CORE layers were collected and measured with calipers. Building sections with coupons which measured less than 48 mils were resprayed with Geo-SealTM CORE until they were visually observed to be at a thickness greater than the vapor barrier sections surrounding the area where the initial coupon was collected. Due to the destructive nature of collecting coupon samples, additional coupons were not collected Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 6 6 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx in re-sprayed areas. A letter clarifying this procedure from PSI is included in Appendix B. In addition, a description of vapor barrier thickness verification is presented in the daily inspection reports provided in Appendix B. Once vapor barrier thickness was approved by PSI, of H&H for Carriage House D, a smoke test was conducted by CCI to test that the Geo-Seal® vapor barrier was properly installed. PSI was present during smoke testing of the sub-slab portions of the VIMS for Building 2 and Carriage Houses B and C, and approved the results of the smoke test (as noted in the smoke test section of the daily inspection reports in Appendix B). H&H was present for the smoke test at Carriage House D and approved the results. In select areas, minor repairs to the Geo- Seal® vapor barrier were made based on the results of the smoke test. Note, in the PSI inspection documents, Carriage House B is referred to as Carriage House 1, and Carriage House C is referred to as Carriage House 2. Note that during H&H’s inspections of the VIMS, H&H conducted one follow-up inspection of Building 2 due to the following: 1) During an inspection of the riser piping conducted on July 29, 2019, H&H noted that several riser pipes were not completely plumbed from the ground floor through the roof and that several riser pipes were not labeled. Mr. Andrew Besu of H&H conducted a follow up inspection of Building 2 on October 29, 2019 and confirmed that all riser pipes were properly installed and labeled. Follow-up inspections of Carriage Houses B, C, & D were not necessary. After the inspection activities, PSI’s approval of the smoke testing results, Vapor Vent™ installation, and Geo-Seal® vapor barrier installation, H&H concluded that the VIMS within Building 2 and the Carriage Houses have been properly installed by the contractor in accordance with the DEQ-approved VIMS Design Report. The VIMS layout as-built drawings developed by PSI depicting the locations of the final Vapor Vent™ layout, riser pipes, and monitoring point locations are included as Appendix B. The inspection forms and field logs from H&H and PSI are included in Appendix C. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 7 7 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx 2.2 Pilot Influence Testing H&H conducted “pilot” influence testing on several occasions to the vent network installed below the concrete slabs of Building 2 and Carriage Houses to verify that adequate communication was present between the sub-slab annular space and the VIMS. The vacuum influence test in Building 2 (Basement and Floor 1) were performed on May 23, 2019. The vacuum influence tests for Carriage House B was performed on August 30, 2019, and the tests at Carriage Houses C and D were performed on October 28, 2019. During influence testing, H&H utilized temporary vapor extraction fans which were attached to the vertical riser piping. The fans use during the influence testing included RadonAway RP-145 and AMG Legend radon fans, along with a shop-vac style fan. Prior to turning the fans on, vacuum measurements were collected at each monitoring point to establish baseline conditions. After baseline conditions were recorded, the fans were activated. A Dwyer series 475 Mark III Digital manometer (capable of measuring to 0.001 inches of water column [in-WC] or 0.25 Pascals [Pa]) was then connected to each pressure measuring port via Teflon tubing to record differential pressures. H&H collected vacuum measurements at each of the monitoring points in Building 2 and Carriage Houses over varied time intervals. Results of the influence testing for Building 2 and Carriage Houses are summarized on Table 1. The results indicate that differential pressures measured at every monitoring point using various vacuum levels at the fan were above the minimum depressurization reading (4 Pa) deemed acceptable by DEQ Brownfields to demonstrate that adequate communication is present between sub-slab annular space and the riser pipes. VIMS Pilot Test field logs summarizing vacuum and flow measurements at each vapor extraction point location and differential pressure measurements at each observation point are included in Appendix C. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 8 8 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx 2.3 Sub-Slab Vapor Sampling Procedure After completion of the VIMS components including installation of the turbine ventilator fans, H&H collected six sub-slab vapor samples from below the ground floor levels of Building 2 on January 8 and January 17, 2020. H&H collected one sub-slab vapor sample from below the ground floor levels of Carriage Houses B and C on December 30, 2019, and one sample from below the ground floor level of Carriage House D on December 11, 2019. The locations of the samples collected from each of the ground floor levels is included in the table below. Ground Floor Level Sub-Slab Vapor Sample Locations Building 2 Basement MP-1/ DUP-1, MP-2 Building 2 Floor 1 MP-3, MP-4, MP-5, MP-6 Carriage House B Floor 1 CGH-B-SS-MP-1 Carriage House C Floor 1 CGH-C-SS-MP-1/Dup-20191230 Carriage House D Floor 1 CGH-D-SS-MP-1 Duplicate samples were also collected from the Building 2 Basement MP-1 parent sample, and from the Carriage House C Floor 1 MP-1 parent sample, for quality assurance / quality control (QA/QC) purposes. The vacuum monitoring points were sampled by emplacing a temporary expandable plug with sample port onto the monitoring point to create an air-tight seal, and using recommended procedures presented in the DEQ Division of Waste Management (DWM) Vapor Intrusion (VI) Guidance. Prior to sample collection for the samples, H&H conducted a leak test at the vacuum measuring point by placing a shroud around the point, sampling train, and Summa canister, saturating the air within the shroud with helium gas, then purging soil gas from the sampling point with a GilAir vacuum pump into a Tedlar® bag. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 9 9 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx A helium gas detector was used to measure helium concentrations in the shroud and bag. The leak test was considered successful if the helium concentration measured in the soil gas purged from the sampling point was less than 10% of the concentration measured in the shroud. Successful completion of this leak check ensured that short-circuiting at the sample point and fittings did not occur and that the data collected accurately represented soil gas concentrations. Additionally, in accordance with the DEQ-approved VIMS Design Report, an Indoor Air Building Survey form was completed for Building 2 and the Carriage Houses, even though only sub-slab vapor samples were collected. The Sub-Slab Soil Gas Field Forms and the Indoor Air Building Survey Forms are included in Appendix C. Following a successful leak check, the sub-slab vapor samples were collected into batch-certified 1-liter stainless steel Summa canisters connected to an airflow regulator preset by the laboratory to collect vapor over a 10-minute period at an approximate flow rate of 0.1 liters per minute (L/min). During the sample collection, vacuum inside the summa canisters was recorded prior to and following the 10-minute sampling period to ensure adequate sample volume was collected. The samples were submitted for analysis of select volatile organic compounds (VOCs) by EPA Method TO-15 to Con-Test Analytical Laboratory (Con-Test), a nationally accredited laboratory. The select VOCs included compounds that were detected in Site groundwater or soil gas during previous assessment activities as documented in the Brownfields Assessment Report Revision 1 prepared by H&H and dated March 2, 2018. A tabular summary of the post VIMS construction sub-slab soil gas analytical results is presented in Table 1. The laboratory analytical reports with chain of custody records are provided as Appendix D. The laboratory analytical results were compared to the DEQ DWM Residential Sub- Slab and Exterior Soil Gas Screening Levels (SGSLs) dated February 2018. To further evaluate the detected VOCs, H&H input the concentrations of the compounds detected in each sub-slab vapor sample into the DEQ Risk Calculator (December 2019 Version). A summary of the calculated Lifetime Incremental Cancer Risks (LICRs) and Hazard Index (HI) Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 10 10 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx values are provided in Table 1 and copies of the risk calculator summary pages are provided in Appendix E. Note, as a conservative measure, the higher of the detected concentration for each constituent in the parent and duplicate samples from Building 2 (MP-1/DUP-1) and from Carriage House C (CGH-C-SS-MP-1/Dup20191230) were used in the risk calculator. 2.4 Sub-Slab Vapor Sampling Results The results of analysis indicate that several VOCs were detected above laboratory method detection limits (MDLs) at low concentrations in the samples from each of the monitoring points. However, no compounds were detected at concentrations above Residential SGSLs in any of the samples. Building 2 The risk calculators indicated the calculated residential LICRs for the samples collected from the ground floor levels of Building 2 ranged from 8.6 x 10-9 to 1 x 10-6, which are notably below the acceptable risk level of 1 x 10-4. The calculated residential HI for the samples collected from Building 2 ranged from 0.0019 to 0.23, which are below the acceptable threshold level of 1. Therefore, the VOC vapor concentrations detected below the footprint of Building 2 do not appear to pose an unacceptable risk to future residential occupants of the building. Carriage House B The risk calculators indicated the calculated residential LICR for the sample collected from the ground floor level of Carriage House B was 1.3 x 10-9, which is notably below the acceptable risk level of 1 x 10-4. The calculated residential HI for the sample collected from Carriage House B is 0.00092, which is notably below the acceptable threshold level of 1. Therefore, the VOC vapor concentrations detected below the footprint of Carriage House B do not appear to pose an unacceptable risk to future residential occupants of the building. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 11 11 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx Carriage House C The risk calculators indicated the calculated residential LICR for the samples collected from the ground floor level of Carriage House C to be 1.1 x 10-6, which is notably below the acceptable risk level of 1 x 10-4. The calculated residential HI for the sample collected from Carriage House C is 0.13, which is notably below the acceptable threshold level of 1. Therefore, the VOC vapor concentrations detected below the footprint of Carriage House C do not appear to pose an unacceptable risk to future residential occupants of the building. Carriage House D The risk calculators indicated the calculated residential LICR for the sample collected from the ground floor level of Carriage House D to be 0.0, indicating no constituents which pose carcinogenic risk were detected above laboratory detection limits. The calculated residential HI for the sample collected from Carriage House D is 0.0021, which is notably below the acceptable threshold level of 1. Therefore, the VOC vapor concentrations detected below the footprint of Carriage House D do not appear to pose an unacceptable risk to future residential occupants of the building. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 12 12 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx 3.0 Summary and Recommendations Based on the results of our recent VIMS inspections, testing, and sampling activities, H&H certifies that the VIMS associated with Building 2 and Carriage Houses B, C, & D at the Broadstone Bryant Park site has been properly installed per the approved VIMP and there is adequate communication between the sub-slab annular space and the VIMS. In addition, based upon the sub-slab vapor sampling results, the VOC vapor concentrations detected in the sub-slab do not appear to pose an unacceptable risk to future occupants of these buildings. Therefore, H&H requests that the DEQ Brownfields Program acknowledge compliance of LUR 5 of the Notice of Brownfields Property and grant occupancy for Building 2 and Carriage Houses B, C, & D. In accordance with the approved VIMP, post-occupancy sub-slab vapor samples will be collected from each of the monitoring points of the ground floor levels (listed in Section 2.3) in Building 2 and the Carriage Houses on an annual basis for a period of two years following building completion. After the two-year period, the environmental consultant for the BBPA or current property owner, and DEQ, will reassess the need to continue collecting sub-slab vapor samples. A construction completion report will be submitted under separate cover following the completion of all buildings discussed in the approved Vapor Intrusion Mitigation System Design Report. Note, per the approved VIMP, an operational & maintenance (O&M) plan will also be developed for the operator of the VIMS to ensure proper functionality of the system post-construction. The O&M Plan will include instructions for semi-annual post-occupancy inspections. Inspection logs of semi-annual inspections will be submitted annually with the Land Use Restriction Update Form for the Site. The O&M plan will be developed and submitted to DEQ with the construction completion report. Ms. Joselyn Harriger, PG March 20, 2020 – Revision 1 Page 13 13 S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Carriage House B-D & Building 2\21032_Radiator Specialty_Building 2 and CH B-D - Request for Occupancy_032020_Revision 1.docx If you have any questions or require additional information, please do not hesitate to contact us at 704-586-0007. Sincerely, Hart & Hickman, PC Andrew Besu Trinh DeSa, PE Assistant Project Geologist Senior Project Engineer Brett Lawrence, PG Project Geologist #C1269 – Engineering #C245 - Geology Attachments: Table 1 – Vapor Intrusion Mitigation Plan Master Summary Figure 1 – Site Layout Map Appendix A – Photographic Logs Appendix B – Building 2 and Carriage Houses VIMS As-Built Drawings Appendix C – VIMS Inspection Forms and Field Logs Appendix D – Analytical Laboratory Reports Appendix E – Sub-Slab and Soil Gas Risk Calculator Summary Pages Table 1Vapor Intrusion Mitigation Plan Master SummaryRadiator Specialty Brownfields SiteBrownfields Project No. 21032-17-060Broadstone Bryant Park AllianceH&H Project: ALI.002Date of Most Recent Update - 02/20/20BuildingCarriage House BCarriage House DFloorBasementFloor 1 Floor 1VIMS Construction Inspection & Completion*Sub-grade Vapor VentYesYes Yes*Vapor Barrier - GeosealYesYes Yes**Above-Grade Riser Piping & LabelsYesYes Yes**Ventilator FansYesYes YesPilot Test Pilot Test Pass Date 05/23/198/30/2019 10/28/2019Vacuum Range at Monitoring Point (Pascals)176-1771,754-2,498 344-396Sub-Slab Sampling Results Sample ID MP-2 MP-3 MP-4 MP-5 MP-6 MP-7 MP-8 MP-2 MP-3 MP-4 MP-5 MP-6 MP-1 MP-2 MP-3 MP-1 MP-2 MP-3 MP-4 MP-5SS-CLUBHOUSE-MP-2SS-Clubhouse-MP-2(2)CGH-B-SS-MP-1CGH-C-SS-MP-1DUP-20191230CGH-D-SS-MP-1Sample Date 10/7/2019 10/7/2019 10/10/2019 10/7/2019 10/7/2019 10/7/2019 10/7/2019 1/8/2020 1/8/2020 1/8/2020 1/8/2020 1/8/2020 9/13/2019 9/13/2019 9/13/2019 8/21/2019 7/19/2019 7/19/2019 7/19/2019 7/19/2019 05/07/19 05/07/19 05/07/19 09/30/19 12/30/2019 12/30/2019 12/30/2019 12/11/2019VOCs by TO-15 (µg/m3)µg/m3Acetone 17 J 20<6.643 100 110 19 37 110 16 J 15 J 21 29 48 70 17 J 60 71 57 35 230 18,000 400 78 430 440 1,100 3,000 38 400 370 50 220,000Benzene<0.260.36 J<0.260.56 J<0.2617 0.37 J 0.60 J 0.41 J<0.026 <0.026<0.26<0.26 <0.26 <0.26 <0.260.88<0.26 <0.26 <0.26 <0.26 <2.6 <0.660.45 J<0.26 <0.26 <0.667.0<0.26 <0.260.65<0.261202-Butanone (MEK)<1.13.9 J<1.15.1 J 78<1.14.4 J 9.0 J 12 J 2.3 2.6 J 34 5.5 J 7.2 J 4.9 J 4.0 J 6.0 J 520 210 12 J 180 1,800 110 35 19 J 24 5,400 6,500 36 770 700 8.1 J 35,000tert-Butyl Alcohol (TBA) 1.3 J 1.5 J 1.3 J 2.8 5.0 4.0<0.93 <0.93 <0.93 <0.93 <0.93<0.937.6 1.3 J<0.931.0 J 1.4 J<0.93 <0.93 <0.93 <0.93 <9.3 <2.3 <0.93 <0.93 <0.93 <2.32.9<0.931.2 J<0.93 <0.93NSn-Butylbenzene<0.72 <0.72 <0.72 <0.72 <0.7238<0.720.99 J 1.3 J<0.72 <0.72<0.72<0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <0.72 <7.2 <1.8 <0.72 <0.72 <0.72 <1.8 <0.72 <0.7221 20<0.72NSsec-Butylbenzene<0.86 <0.86 <0.86 <0.86 <0.8627<0.86 <0.86 <0.86 <0.86 <0.86<0.86<0.86 <0.86 <0.86 <0.86 <0.86 <0.86 <0.86 <0.86 <0.86 <8.6 <2.1 <0.86 <0.86 <0.86 <2.18.2<0.8613 13<0.86NStert-Butylbenzene<0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <0.94<0.94<0.94 <0.942.3 J<0.94 <0.94 <0.94 <0.94 <0.94 <0.94 <9.4 <2.4 <0.94 <0.94 <0.94 <2.4 <0.94 <0.94 <0.94 <0.94 <0.94NSCarbon Disulfide<0.43 <0.43 <0.43 <0.430.71 J<0.43 <0.43 <0.43 <0.43 <0.43 <0.43<0.43<0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.430.75 J<4.32.0 J<0.43 <0.43 <0.43 <1.1 <0.43 <0.434.6 J 4.6 J<0.434,900Chloroform<0.361.6 4.1<0.360.84 J<0.364.4<0.360.88 J<0.36 <0.36<0.36<0.36 <0.36 <0.36 <0.36 <0.360.61 J 2.3<0.36 <0.36 <3.65.8 3.9<0.360.82 J 3.4<0.36 <0.361.6 1.2<0.3641Chloromethane<0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28 <0.28<0.28<0.28 <0.281.2<0.28 <0.28 <0.28 <0.28 <0.281.6<2.8 <0.70 <0.28 <0.28 <0.28 <0.70 <0.28 <0.28 <0.28 <0.28 <0.28630Cyclohexane<0.49 <0.49 <0.49 <0.49 <0.4952<0.49 <0.49 <0.49 <0.49 <0.49<0.49<0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <0.49 <4.9 <1.2 <0.49 <0.49 <0.49 <1.229<0.498.7 7.9<0.4942,0001,2-Dichlorobenzene<0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.582.4 2.6<0.58<0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <0.58 <5.8 <1.4 <0.58 <0.58 <0.58 <1.4 <0.58 <0.58 <0.58 <0.58 <0.581,4001,3-Dichlorobenzene<0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62<0.62<0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <6.2 <1.6 <0.62 <0.62 <0.62 <1.6 <0.62 <0.62 <0.62 <0.62 <0.62NSDichlorodifluoromethane (Freon 12)<0.43 <0.43 <0.433.1 2.4<0.43 <0.43 <0.433.1<0.43 <0.431.8 1.9 1.7 2.0 2.1 2.5<0.43 <0.43 <0.431.6<4.3 <1.1 <0.43 <0.43 <0.43 <1.1 <0.43 <0.43 <0.43 <0.432.5 7001,1-Dichloroethane<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25<0.25<0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <2.5 <0.62 <0.25 <0.25 <0.25 <0.62 <0.25 <0.25 <0.25 <0.25 <0.255801,1-Dichloroethylene<0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43<0.43<0.43 <0.43 <0.43 <0.43 <0.32 <0.32 <0.32 <0.32 <0.32 <3.2 <0.80 <0.32 <0.32 <0.32 <0.80 <0.32 <0.43 <0.43 <0.43 <0.431,400cis-1,2-Dichloroethylene<0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32 <0.32<0.32<0.32 <0.32 <0.321.9<0.32 <0.32 <0.32 <0.32 <0.32 <3.2 <0.81 <0.32 <0.32 <0.32 <0.81 <0.32 <0.32 <0.32 <0.32 <0.32NSEthanol 84 78 41 18 7.9 J 18 16 16 42 7.6 J<6.769 230 130 150 340 90 25 23<6.726<6717 J 20 12 J 10 J 27 J 13 J 550 18<6.718 NSEthyl Acetate<0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <0.54<0.542.6<0.542.1<0.54 <0.54 <0.54 <0.54 <0.54 <0.54 <5.4 <1.3 <0.54 <0.54 <0.54 <1.3 <0.54 <0.54 <0.54 <0.54 <0.54490Ethylbenzene<0.50 <0.50 <0.501.6<0.50150 0.50 J 2.3 2.3 4.8 4.9 2.5 0.99<0.501.0 2.3 0.97<0.50 <0.50 <0.501.3<5.0 <1.30.54 J<0.50 <0.50 <1.360<0.5023 21<0.503704-Ethyltoluene<0.60 <0.60 <0.60 <0.60 <0.60410<0.607.8 8.6<0.60 <0.60<0.60<0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.60 <0.602.4<6.0 <1.5 <0.60 <0.60 <0.60 <1.5110<0.6034 32<0.60NSHeptane<0.48 <0.48 <0.48 <0.48 <0.48110<0.481.1 2.4<0.48 <0.48<0.48<0.48 <0.48 <0.48 <0.481.0<0.48 <0.48 <0.481.3<4.8 <1.2 <0.48 <0.48 <0.48 <1.246<0.4819 17<0.482,800Hexane<1.2 <1.2 <1.2 <1.2 <1.251<1.2 <1.2 <1.2 <1.2 <1.2<1.2<1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <1.2 <12 <3.1 <1.2 <1.2 <1.2 <3.125 J<1.25.3 J 6.4 J<1.24,9002-Hexanone (MBK)<0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48 <0.48<0.49<0.49 <0.49 <0.49 <0.49 <0.48 <0.48 <0.48 <0.49 <0.49 <4.9 <1.2 <0.49 <0.49 <0.49 <1.2 <0.48 <0.48 <0.48 <0.48 <0.48210Isopropanol<0.90 <0.90 <0.902.2 J<0.90 <0.90 <0.90 <0.90 <0.90 <0.90 <0.90<0.902.3 J 1.5 J 5.3 J 3.3 J 2.1 J<0.60 <0.60 <0.608.7 J 180 J<1.57.2 J<0.60 <0.60 <1.5 <0.60 <0.90 <0.90 <0.902.2 J 1,400Isopropylbenzene (Cumene)<0.79 <0.79 <0.79 <0.79 <0.7927<0.79 <0.79 <0.79 <0.79 <0.79<0.79<0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <0.79 <7.9 <2.0 <0.79 <0.79 <0.79 <2.08.8<0.797.2 7.1<0.792,800p-Isopropyltoluene (p-Cymene)<0.75 <0.752.0 J<0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75<0.75<0.75 <0.752.3 J<0.752.4 J 1.4 J 2.2 J<0.75 <0.75 <7.5 <1.9 <0.75 <0.75 <0.75 <1.94.7<0.757.4<0.75 <0.75NSMethyl tert-Butyl Ether (MTBE)<0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36<0.36<0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <0.36 <3.6 <0.90 <0.36 <0.36 <0.36 <0.90 <0.36 <0.36 <0.36 <0.36 <0.363,600Methylene Chloride<0.84 <0.84 <0.84 <0.841.8 J<0.84 <0.84 <0.840.92 J 1.2 J 1.3 J<0.84<0.84 <0.840.97 J 0.88 J<0.84 <0.84 <0.84 <0.841.5 J<8.4 <2.13.2 J<0.84 <0.84 <2.1 <0.844.4 J<0.841.4 J<0.844,2004-Methyl-2-pentanone (MIBK)<0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43<0.43<0.43 <0.43 <0.43 <0.43 <0.39 <0.39 <0.39 <0.39 <0.39 <3.9 <0.99 <0.39 <0.39 <0.39 <0.99 <0.39 <0.43 <0.43 <0.43 <0.4321,000Naphthalene<0.80 <0.80 <0.801.5<0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80<0.80<0.80 <0.80 <0.80 <0.80 <0.801.3<0.802.5 3.2<8.0 <2.01.6 1.1 1.2<2.0 <0.80 <0.80 <0.80 <0.80 <0.8021Propene<0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64 <0.64<0.64<0.64 <0.64 <0.64 <0.64 <0.34 <0.34 <0.34 <0.34 <0.34 <3.4 <0.85 <0.34 <0.34 <0.34 <0.85 <0.34 <0.64 <0.64 <0.64 <0.64NSPropylbenzene<0.87 <0.87 <0.87 <0.87 <0.8762<0.87 <0.87 <0.87 <0.87 <0.87<0.87<0.87 <0.87 <0.87 <0.87 <0.87 <0.87 <0.87 <0.87 <0.87 <8.7 <2.2 <0.87 <0.87 <0.87 <2.2 <0.87 <0.8719 18<0.877,000Tetrachloroethylene<0.751.1 J 0.79 J<0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75 <0.75<0.75<0.753.1<0.7539 2.7 1.9 1.3 J<0.752.7<7.5 <1.9 <0.752.6 2.9<1.9 <0.75 <0.753.9 3.4<0.75280Tetrahydrofuran<0.59 <0.59 <0.592.1 360 210 92 15 250<0.59 <0.5912 14 95 3.2<0.592.4 260 130 210 37019,0001,400 57 990 990 1,400 4,900 32 1,800 1,600 69 14,000Toluene 6.1 3.1 19 220 11 260 4.5 7.6 4.9<0.39 <0.39<0.393.0 2.0 4.0 3.8 45 1.6 2.0 2.0 1,100 7.1 J 2.4 140 4.8 4.4 3 86 1.2 10 10<0.3935,000Trichloroethylene<0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43 <0.43<0.43<0.43 <0.43 <0.4314<0.43 <0.43 <0.43 <0.43 <0.43 <4.3 <1.1 <0.43 <0.43 <0.43 <1.1 <0.43 <0.43 <0.43 <0.43 <0.4314Trichlorofluoromethane (Freon 11) 1.4 J 1.7 J 1.8 J 1.6 J 1.2 J 1.6 J 1.7 J 1.4 J 1.6 J 2.4 J 2.4 J 1.6 J 1.3 J 1.3 J 1.2 J 1.9 J 1.1 J 2.5 J 1.4 J 1.0 J 0.85 J<6.5 <1.61.1 J 1.5 J 1.6 J<1.61.9 J 1.7 J 2.2 J 1.9 J 1.6 J NS1,2,4-Trimethylbenzene<0.63 <0.630.71 J 10<0.63370 0.87 J 8.6 9.9<0.63 <0.63<0.63<0.63 <0.63 <0.63 <0.63 <0.631.8<0.63 <0.6313<6.3 <1.6 <0.63 <0.63 <0.63 <1.696<0.6399 89<0.634201,3,5-Trimethylbenzene<0.62 <0.62 <0.621.9<0.62110<0.622.5<0.62 <0.62 <0.62<0.62<0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.62 <0.623.6<6.2 <1.5 <0.62 <0.62 <0.62 <1.5 <0.62 <0.6237 34<0.624202,2,4-Trimethylpentane 1.7 J<0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80<0.80<0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <0.80 <8.0 <2.0 <0.80 <0.80 <0.80 <2.012<0.807.7 7.0<0.80NSm&p-Xylene<1.00 <1.00 <1.002.9<1.00430 1.3 J 6.9 6.6 20 21 9.1 3.4 2.6 3.5 8.7 3.2 1.3 J<1.00 <1.004.4<10.0 <2.51.5 J<1.0 <1.0 <2.5160<1.0057 52<1.00700o-Xylene<0.54 <0.54 <0.541.3<0.54200 0.61 J 3.6 3.3 5.5 5.6 1.9<0.54 <0.540.94 2.0 1.6<0.54 <0.54 <0.542.8<5.4 <1.40.99<0.54 <0.54 <1.480<0.5437 34<0.54700Risk-Assessment - Soil Gas to Indoor AirCarcinogenic Risk (Resident)1.0 x 10-66.3 x 10-72.1 x 10-75.4 x 10-61.1 x 10-61.1 x 10-73.1 x 10-76.7 x 10-82.6 x 10-88.6 x 10-92.7 x 10-81.0 x 10-61.1 x 10-76.3 x 10-75.7 x 10-79.1 x 10-71.2 x 10-60.0 x 10-01.4 x 10-61.6 x 10-68.4 x 10-72.2 x 10-61.3 x 10-90.0 x 10-0Hazard Index (Resident)2.2 x 10-32.4 x 10-26.8 x 10-34.5 x 10-14.0 x 10-39.4 x 10-31.3 x 10-24.1 x 10-33.2 x 10-35.1 x 10-34.1 x 10-32.3 x 10-15.7 x 10-32.2 x 10-24.8 x 10-32.7 x 10-25.8 x 10-23.3 x 10-12.3 x 10-22.1 x 10-25.3 x 10-32.2 x 10-19.2 x 10-42.1 x 10-3Occupancy Granted by DEQPending PendingNotes:1) North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Residential Sub-Slab and Exterior Soil Gas Screening Levels (SGSLs) (February 2018)2) SS-Clubhouse-MP-2 sample from 9/30/19 was collected from the re-installed monitoring point location.* = Inspected by Intertek PSI, a Geo-Seal® certified inspector** = Inspected by Hart & HickmanCompounds detected in at least one sample are shown.Bold concentration indicates an exceedance in the applied standard.µg/m3 = micrograms per cubic meter; NS = Not Specified;'-- = not applicableJ = detected concentration is above the laboratory method detection limit, but below the laboratory calibrated reporting limit. Therefore, the reported concentration is an estimated value.Risk assessment for sample SS-CLUBHOUSE-MP-1/DUP-1 calculated using the higher of the two concentrations for the parent and duplicate sample.Pending YesFloor 1Carriage House C372-412 10/28/20191.1 x 10-61.3 x 10-1Clubhouse7-16103/25/19YesYesYesYesFloor 1YesYesYes9-1505/23/19209-42005/23/1924-152111-16704/11/1912/12/189-57Yes YesBuilding 1Basement Floor 1 Floor 2YesYesYesYesYesYesYesYesYesYesYesYesYesBuilding 3 Building 4Floor 1YesYesYesFloor 1Residential SGSLYes05/23/1902/06/1939-11292-13002/06/19YesYesYes2.9 x 10-2 1/13/202010/25/201910/7/2019MP-1 / DUP-14.3 x 10-71.7 x 10-31/13/2020SS-CLUBHOUSE-MP-1/DUP-110/25/20196.5 x 10-71/17/2020MP-1 / DUP1.3 x 10-78.3 x 10-3PendingBuilding 2Floor 1YesYesYesYesYesYesBasement\\HARTHICKMAN.LOCAL\Shares\MasterFiles\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\20191021 - Bryant Park - VIMP Summary Table 20200217Table 1 Hart & Hickman, PC UP UP DN BUILDING 1 BASEMENT BUILDING 1 FLOOR 1 BUILDING 2 FLOOR 1 BUILDING 3 BASEMENT BUILDING 3 FLOOR 1 BUILDING 4 FLOOR 1 CLUBHOUSE FLOOR 1 BLDG 1 BLDG 2 BLDG 3 BLDG 4 BUILDING 1 FLOOR 2 BUILDING 2 BASEMENT CARRIAGE HOUSE C CARRIAGE HOUSE B CLUBHOUSE CARRIAGE HOUSE D OPEN AIR MAIL KIOSK REVISION NO. 1 JOB NO. ALI-002 DATE: 03-20-20 FIGURE NO. 1 SITE LAYOUT MAP LEGEND SITE PROPERTY BOUNDARY PARCEL BOUNDARY 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology RADIATOR SPECIALTY TRACT E BROADSTONE BRYANT PARK APARTMENT COMPLEX BROWNFIELDS PROJECT NO. 21032-17-060 CHARLOTTE, NORTH CAROLINA WILKINSON BOULEVA R D ISOM S T R E E T SUTTLE AVENUENOTES: 1.VAPOR INTRUSION MITIGATION SYSTEM (VIMS) INSTALLED WITHIN BUILDINGS 1, 2, 3, & 4, AND CARRIAGE HOUSES B, C, & D. 2.VIMS NOT INSTALLED AT OPEN AIR MAIL KIOSK. 3.CARRIAGE HOUSE A WAS REPLACED BY THE MAIL KIOSK AND THUS WAS NOT CONSTRUCTED. 4.AFTER CONSTRUCTION, THE APARTMENT COMPLEX WILL BE REFERRED TO AS THE BRYANT APARTMENTS.S:\AAA-Master Projects\Alliance Residential Company (ALI)\ALI-002 Bryant Park Brownfields Assist\VMS Install\Occupancy Request\Clubhouse\Site Map R1.dwg, 3/20/2020 6:25:34 PM, DWG To PDF.pc3 Appendix A Photographic Logs Photograph 2: General view of Vapor Vent™ during installation at Building 2.ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 1: General view of Geo-Seal installation on the outside retaining wall of Building 2. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 4: General view of the completed vapor barrier system at Building 2 before concrete was poured.ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 3: General view of the penetration seals prior to the application of the Geo-Seal. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 5: Representative view of the labeled risers located throughout Building 2. Photograph 6: Representative view of the sub-slab sampling conducted at Building 2. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 8: General view of Vapor Vent™ during installation at Carriage House C.ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 7: General view of Vapor VentTM duringinstallation at Carriage House B. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 10:General view of Geo-Seal® installation at Carriage House B. ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 9: General view of Vapor VentTM duringinstallation at Carriage House D. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 12:General view of Geo-Seal® installation at Carriage House D. ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 11:General view of Geo-Seal® installation at Carriage House C. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 14: General set-up of sub slab sampling at Carriage Houses B-D.ALI-0022923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 13: Example of smoke testing at failed penetrations. Penetrations and seams were sealed after the smoke test. RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Photograph 16: Representative view of riser piping and labeling for Carriage Houses B-D. 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203704.586.0007(p) 704.586.0373(f) Photograph 15: Representative view of vacuum measuring from monitoring point for influence testing in Carriage Houses B-D.ALI-002RADIATOR SPECIALTY TRACT EBROADSTONE BRYANT PARKCHARLOTTE, NORTH CAROLINA Building 2-Basement View Spray apple to wall between Basement and Floor 1. Building 2 -Basement View of Spray apply and Grey cover on wall between Basement and Floor 1. Building 2 -Basement View of finished all after gray sheeting applied Building 2 -Basement View geo-vent being installed. Building 2 -Basement View of geo-vent without crossovers installed. Building 2 -Basement View of geo-vent cross overs and base layer installed. Building 2 -Basement View of base layer with floor penetrations. Building 2 -Basement View of base layer and core layer installed. Building 2 -Basement View of top layer being installed. Building 2-Floor 1 View of installing Geo-Vent in Sub-base. Building 2 –Floor 1 View of Geo-Vent thicken slab crossovers installed. Building 2 –Floor 1 View of Base layer being installed around floor penetrations and thicken slab crossovers. Building 2 –Floor 1 View of base layer being installed. Building 2 –Floor 1 View of a MP being installed. Building 2 –Floor 1 View of re-installing Geo-Vent line to the vertical riser. Carriage Houses 1 & 2 View of Geo-vent being installed with thicken slab crossovers. Carriage Houses 1 & 2 View of Geo-vent being install, and Riser Pipe. Also base layer being installed on slab. Carriage Houses 1 & 2 Another view of Riser pipe being install with Geo-vent. Carriage Houses 1 & 2 View of base layer installed on building slab prior to spraying core layer. Carriage Houses 1 & 2 View while core layer is being applied to base layer. Carriage Houses 1 & 2 View prior to starting smoke testing of slab. Carriage Houses 1 & 2 View applying core layer in areas that failed smoke testing. Carriage Houses 1 & 2 View of pad after smoke testing and with the third layer (white sheeing) applied. Carriage Houses 1 & 2 View of area patched after repairs to the water line. Carriage Houses 1 & 2 View of slab after core layer applied and View of Geo-vent riser. Appendix B Building 2 and Carriage Houses B, C, & D VIMS As-Built Drawings UPD.S.STAIR B MECH. UNIT A1_ADA SHEET A4.20 UNIT A1 SHEET A4.02 UNIT B2_M2 SHEET A4.08C01C01 C06 C09 C01 ELEV STORAGE RISER RECYCLING ELEC STG. K STG. K STG. K STG. K STG. K STG. K C06 C06 C06 C06 UNIT S1 SHEET A4.01 PH DN D.S.D.S.D.S.D.S.D.S.MECH UNIT A2 SHEET A4.03 UNIT A4 SHEET A4.05 STAIR B STAIR A ELEC STORAGE UNIT B2_M2 SHEET A4.08 UNIT B3_M3 SHEET A4.09 UNIT A1 SHEET A4.02 UNIT A1 SHEET A4.02 UNIT C1_ADASHEET A4.22 UNIT S1 SHEET A4.01 UNIT S1 SHEET A4.01 UNIT S1 SHEET A4.01 UNIT S1 SHEET A4.01 UNIT A1 SHEET A4.02 UNIT A1 SHEET A4.02 UNIT A1 SHEET A4.02 UNIT A1 SHEET A4.02 UNIT A1_ADA SHEET A4.20 UNIT B2_M2 SHEET A4.08 C01 C06 C05 C06 C06 C07 C06 UNIT B2_M3 SHEET A4.08 UNIT B1 SHEET A4.07 MECH UNIT A1 SHEET A4.02 ELEC ELEV LOBBY GATE / TYP VAPOR INTRUSION MITIGATION SYSTEMAS-BUILT PLAN BUILDING 2BUILDING 2 BASEMENT BUILDING 2 FLOOR 1 Environmental ServicesTotal Quality. Assured.BRYANT PARK APARTMENTSWILKINSON BOULEVARDCHARLOTTE, NORTH CAROLINA45021 West W.T. Harris Blvd.Charlotte, North Carolina 28269(704) 598-2234 (704) 598-2236 fax)DQ )DQ2 )DQ3 )DQ4 )DQ5 )DQ6 = INDICATES RETAINING WALL COVERED WITH VAPOR BARRIER BUILDING 2 FLOOR 1 BUILDING 2 FLOOR 1 = INDICATES RETAINING WALL COVERED WITH VAPOR BARRIER GEO-SEAL NOT INSTALLED IN AREA OUTSIDE OF BUILDING EXTERIOR WALLS GEO-SEAL NOT INSTALLED IN AREA OUTSIDE OF BUILDING EXTERIOR WALLS 5PER DEQ COMMENTSTCD3/18/20AS-BUILTS REFLECT CHANGES MADE DURING CONSTRUCTION. UP DN T.P.D.S.D.S. POOL & POOL BARRIER SYSTEM UNDER SEPARATE PERMIT SUBMITTAL ID5 WORK RM ASST PM OFFICE RESTROOM PM OFFICE LEASING ENTRY SELF SERVICEPACKAGERISER RM LOBBY LOUNGE GAME ROOM FITNESS POOL EQP/STOR. ELEVATOR MEP LOBBY POOL BARRIER C14 ID4 ID2 ID4 ID4 ID6 ID4 ID3 ID6 ID6 ID11 ID3 ID3 C01 ID1 ID2 ID2 ID1 ID3 ID9 ID9 UP UP CL E 1X 3 GARAGE GARAGE GARAGE GARAGE 1 1 B C06 C11U01B 12' - 5 1/2"12' - 5 1/2" 55' - 1" A-2.11 2 A8.22 12' - 5 1/2"12' - 5 1/2" C11 C11 C11 UP 1XW6Q F 1XW6QF 2XW6B S 2X W6B S W6QF 1X W6QF E 2XW6B S C06 E D 27' - 7"16' - 6"1/4":12" SLOPE1/4":12" SLOPE1/4":12" SLOPE1/4":12" SLOPE23' - 1 1/2"2' - 0"1/4":12" SLOPE2' - 0"23' - 7"2' - 0"1/4":12" SLOPE1/4":12" SLOPE4' - 6 3/4"W4B 2XW6B S 2XW6B S 2' - 4 3/4" 12' - 0"12' - 0"12' - 0"4' - 4" GARAGE GARAGE 1 GARAGE 2XW6B S 2XW6B S 1XW6QF B U36E C11 1 A8.25 C11 U01A C11 S11 U01A VAPOR INTRUSION MITIGATION SYSTEMCLUB HOUSE / AS BUILTCARRIAGE HOUSES AS BUILTCLUB HOUSE FLOOR 1 CARRIAGE HOUSE 1 LEVEL 1 CARRIAGE HOUSE B & C LAYOUT CARRIAGE HOUSE 2 LEVEL CARRIAGE HOUSE D LAYOUT Environmental ServicesTotal Quality. Assured.BRYANT PARK APARTMENTSWILKINSON BOULEVARDCHARLOTTE, NORTH CAROLINA75021 West W.T. Harris Blvd.Charlotte, North Carolina 28269(704) 598-2234 (704) 598-2236 fax= INDICATES RETAINING WALL COVERED WITH VAPOR BARRIER )DQ )DQ2 )DQ )DQ AS-BUILTS REFLECT CHANGES MADE DURING CONSTRUCTION. GEO-SEAL NOT INSTALLED IN OPEN AIR POOL AREA 6PER DEQ COMMENTSTCD03/18/20 G1 VAPORVENT/GEOSEAL MODIFIED PROFILE NTS G2 VAPORVENT INTERLOCKING DETAIL NTS G3 VAPORVENT THROUGH THICKENED SLAB DETAIL NTS F1 SUB-SLAB MONITORING POINT DETAIL NTS T1 VAPOR BARRIER WALL TERMINATION NTS T2 VAPOR BARRIER WALL TERMINATION NTS T3 VAPOR BARRIER PILE CAP TERMINATION NTS T4 VAPOR BARRIER OVERLAP DETAIL NTS P1 VAPOR BARRIER PENETRATIONS DETAIL NTS P2 VAPORVENT PENETRATING SLAB DETAIL NTS S1 SUCTION FAN DETAIL (FUTURE IF NECESSARY) NTS S2 PASSIVE VENT DETAIL NTS ” ” ” ” Environmental ServicesTotal Quality. Assured.VAPOR INTRUSION MITIGATION SYSTEMDETAILSBRYANT PARK APARTMENTSWILKINSON BOULEVARDCHARLOTTE, NORTH CAROLINA85021 West W.T. Harris Blvd.Charlotte, North Carolina 28269(704) 598-2234 (704) 598-2236 fax10 Environmental ServicesTotal Quality. Assured.VAPOR INTRUSION MITIGATION SYSTEMDETAILSBRYANT PARK APARTMENTSWILKINSON BOULEVARDCHARLOTTE, NORTH CAROLINA95021 West W.T. Harris Blvd.Charlotte, North Carolina 28269(704) 598-2234 (704) 598-2236 faxNTSE1ELEVATOR PIT/PLANTER DETAIL NTSW1LOWER TO UPPER LEVEL WALL DETAIL Appendix C VIMS Inspection Forms and Field Logs PSI Project No: 04571227 January 10, 2020 www.intertek.com/building Professional Service Industries, Inc. 5021-A West WT Harris Blvd Charlotte, NC 28269 Phone: (704) 598-2234 Fax: (704) 598-2236 Mr. Myles Helms Project Manager Alliance Residential Company 200 Providence Road, Suite 250 Charlotte, NC 28207 Re: Vapor Barrier Inspection Broadstone Bryant Park Apartments Northwest Quadrant of Wilkinson Blvd and Suttle Avenue Charlotte, Mecklenburg County, North Carolina PSI Project Number: 04571227-1 Dear Mr. Helms: Professional Service Industries, Inc (PSI) an Intertek company is submitting this letter, as you requested, for clarification regarding the inspections PSI conducted during the installation of the sub-slab depressurization system for the above referenced project. PSI conducted the field inspections and documented the inspections on daily field logs. As part of the inspection PSI collected coupon samples of the vapor barrier system. These coupon samples were used to verify the thickness of the vapor barrier in various location on each of the building slabs. When the thickness of the coupon sample was not to the design specifications PSI had the vapor barrier installer respray the areas. Since the coupon sampling is destructive to the vapor barrier additional coupon samples were not collected after the respraying the areas that failed the original thickness testing. Please call with any questions you may have, or if you require any additional information about this matter. Respectfully Submitted, Professional Services Industries, Inc Bryan M. Lucas Department Manager/Principal Consultant Inspection Log - Above Grade Components Vapor Intrusion Mitigation System Radiator Specialty Tract E Brownfields Project #21032-17-060 Broadstone Bryant Park Alliance H&H Project: ALI.002 Slab ID: Building 2 Date: 7/29/19 Inspector: ACB Yes Needs Work Comments / Repairs / Modifications x Risers 1-3 not plumbed to roof; Riser 4 not located. x Date: 12/17/19 Inspector: SMS Yes Needs Work x x x General Notes : Above-grade Piping Proper installation of vertical mitigation piping: Proper mitigation pipe labels: Correct fan type: Follow-Up Inspection Notes: 10/29/19 (if required) All Risers located and plumbed to roof with proper mitigation labels. Follow-Up Inspection Notes: (if required) Fan operational: Ventilator Fans Proper installation of fan: Inspection Log ‐ Above Grade Components Vapor Intrusion Mitigation System Radiator Specialty Tract E Brownfields Project #21032‐17‐060 Broadstone Bryant Park Alliance H&H Project: ALI.002 Slab ID: Carriage House B (PSI Carriage House 1) Date: 11/6/19 Inspector:              NMP                             Yes Needs  Work Comments / Repairs / Modifications x x Date: 12/17/19 Inspector:         SMS                              Yes Needs  Work x x x x General Notes : Follow‐Up Inspection Notes: (if required) Fan operational: Ventilator Fans Proper installation of fan: Proper labeling of ventilator fan/piping above roof line Above‐grade Piping Proper installation of vertical mitigation piping: Proper mitigation pipe labels: Correct fan type: Follow‐Up Inspection Notes: (if required) Inspection Log ‐ Above Grade Components Vapor Intrusion Mitigation System Radiator Specialty Tract E Brownfields Project #21032‐17‐060 Broadstone Bryant Park Alliance H&H Project: ALI.002 Slab ID: Carriage House C (PSI Carriage House 2) Date: 11/6/19 Inspector:              NMP                             Yes Needs  Work Comments / Repairs / Modifications x x Date: 12/17/19 Inspector:         SMS                              Yes Needs  Work x x x x General Notes : Follow‐Up Inspection Notes: (if required) Fan operational: Ventilator Fans Proper installation of fan: Proper labeling of ventilator fan/piping above roof line Above‐grade Piping Proper installation of vertical mitigation piping: Proper mitigation pipe labels: Correct fan type: Follow‐Up Inspection Notes: (if required) Inspection Log Vapor Intrusion Mitigation System Radiator Specialty Tract E Brownfields Project #21032-17-060 Broadstone Bryant Park Alliance H&H Project: ALI.002 Slab ID: Carriage House D Date: 8/28/19 Inspector: ACB Yes Needs Work Comments / Repairs / Modifications x x x x Date: 8/30/19 Inspector: NMP Yes Needs Work Comments / Repairs / Modifications x x x x Smoke test observed and approved by NMP Date:11/6/19 Inspector: NMP Yes Needs Work Comments / Repairs / Modifications x x Date: 12/11/19 Inspector: SMS/AMB Yes Needs Work x x x x General Notes : Coupon Sample collected on 8/30/19: N=1.42mm S=1.27mm Minimum thickness of 53 mil (1.35MM) NW=1.27mm SE=1.38mm Had CCI re-spray area around coupon sample W=1.31mm E=1.29mm SW=1.29mm NE=1.31mm Proper mitigation pipe labels Follow-Up Inspection Notes: (if required) Follow-Up Inspection Notes: (if required) Above-grade Piping Proper installation of vertical mitigation piping: Follow-Up Inspection Notes: (if required) Proper labels at fan location: Ventilator Fans Proper installation of fan: Fan operational: Above-grade Piping Proper installation of vertical mitigation piping: Proper placement of piping through footings: Correct fan type: Follow-Up Inspection Notes: (if required) Proper gravel depth and type Installation of filter socks and end caps Vapor Barrier Proper seals around edges, concrete: Proper seals around penetrations and vertical riser(s) Good condition of Geo-Seal Smoke Test of Geo-Seal Initials________________________ Sub-Slab VIMS Pilot Test Site Address:__________________________________________________________________________ Date: ___________ Test Start Time:___________ Weather:_______________________________ Sub-Slab Test # _______ Location:_______________________________________________________ Time Fan#  Suction Point Vacuum (“WC)  Fan#Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Observation Point Baseline Pressure Pressure “WC Pressure “WC Pressure “WC Pressure “WC Pressure “WC OP # OP # OP # OP # OP # Comments____________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ JML/MRU 2140 Suttle Avenue - Bryant Park 5/23/19 13:05 Sunny, 80s Building 2 Basement -0.010 -1.601 -0.840 0.000 -1.688 -1.050 Fan #1: Shop Vac at 13:10, AMG Legend at 13:55 Fan #2: AMG Legend 13:10 13:55 -8.10 -1.95 -2.10 -1.05 1 2 MP-1 MP-2 Initials________________________ Sub-Slab VIMS Pilot Test Site Address:__________________________________________________________________________ Date: ___________ Test Start Time:___________ Weather:_______________________________ Sub-Slab Test # _______ Location:_______________________________________________________ Time Fan#  Suction Point Vacuum (“WC)  Fan#Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Observation Point Baseline Pressure Pressure “WC Pressure “WC Pressure “WC Pressure “WC Pressure “WC OP # OP # OP # OP # OP # Comments____________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ JML/MRU 2140 Suttle Avenue - Bryant Park 5/23/19 16:50 Sunny, 80s Building 2 Floor 1 0.010 -0.087 -0.131 0.000 -0.178 -0.203 0.000 -0.104 -0.096 0.000 -0.609 -0.605 Fan #3: AMG Legend Fan #4: Shop Vac Fan #5: Radon Away RP145 Fan #6: AMG Legend 17:00 17:15 -1.17 -1.34 -6.22 -6.25 -0.87 -0.90 -2.07 -2.08 3 4 5 6 MP-3 MP-4 MP-5 MP-6 Initials________________________ Sub-Slab VIMS Pilot Test Site Address:__________________________________________________________________________ Date: ___________ Test Start Time:___________ Weather:_______________________________ Sub-Slab Test # _______ Location:_______________________________________________________ Time Fan#  Suction Point Vacuum (“WC)  Fan#Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Observation Point Baseline Pressure Pressure “WC Pressure “WC Pressure “WC Pressure “WC Pressure “WC OP # OP # OP # OP # OP # Comments____________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ MW 2140 Suttle Avenue - Bryant Park 8/30/19 09:00 Sunny, 75 Carriage House B -0.002 -2.69 -7.05 -10.04 Fan #1: Shop Vac 10:00 10:10 10:20 -4.06 -11.20 -18.401 MP-1 Initials________________________ Sub-Slab VIMS Pilot Test Site Address:__________________________________________________________________________ Date: ___________ Test Start Time:___________ Weather:_______________________________ Sub-Slab Test # _______ Location:_______________________________________________________ Time Fan#  Suction Point Vacuum (“WC)  Fan#Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Observation Point Baseline Pressure Pressure “WC Pressure “WC Pressure “WC Pressure “WC Pressure “WC OP # OP # OP # OP # OP # Comments____________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ ACB 2140 Suttle Avenue - Bryant Park 10/28/19 14:35 Clear, 80s 1 Carriage House C 0.000 -1.495 -1.611 -1.655 Fan #1: Shop Vac 14:45 14:55 15:05 -1.895 -2.053 -2.0991 MP-1 Initials________________________ Sub-Slab VIMS Pilot Test Site Address:__________________________________________________________________________ Date: ___________ Test Start Time:___________ Weather:_______________________________ Sub-Slab Test # _______ Location:_______________________________________________________ Time Fan#  Suction Point Vacuum (“WC)  Fan#Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Fan# Suction Point Vacuum (“WC) Observation Point Baseline Pressure Pressure “WC Pressure “WC Pressure “WC Pressure “WC Pressure “WC OP # OP # OP # OP # OP # Comments____________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ _____________________________________________________________________________________ ACB 2140 Suttle Avenue - Bryant Park 10/28/19 15:50 Clear, 80s 1 Carriage House D 0.000 -1.381 -1.501 -1.592 Fan #1: Shop Vac 16:00 16:10 16:20 -1.583 -1.619 -1.7131 MP-1 Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCALI-0021/17/2048.048.0Clear, sunny, 48.0 F, 8 mph SSWBld-2-SS-MP-12106 Air Pump4172DUP-01/17/202020904172SSSSPerm.Perm.ConcretConcret12:451/17/2012:45Air Pump10.010.014.114.10.00.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCALI-0021/8/2057.052.045.045.0Clear, Sunny, 45.0-57.0 F, 12 mph SEBld-2-SS-MP-22232Air Pump4324Bld-2-SS-MP-321094332Bld-2-SS-MP-423494323Bld-2-SS-MP-521274319SSSSSSSSPerm.Perm.Perm.Perm.ConcretConcretConcretConcret13:001/8/2012:151/8/2011:451/8/2011:15Air Pump Air Pump Air Pump10.010.010.010.012.614.913.612.70.00.00.00.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCALI-0021/8/2045.0Clear, Sunny, 45.0 F, 12 mph SEBld-2-SS-MP-62240Air Pump4333SS Perm.Concret10:1510.013.50.0ppmNatasha Pacifico%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Sub-Slab / Soil Gas Vapor QA/QC Field FormProject No.:____________________Depth of ScreenDate & TimeAmbient Temp.Purge Method Purge VolHelium Conc.ShroudHelium Conc.PurgeLeak Test PassedYes / No SS, SGperm., temp.concrete, wood, asphalt, grass, soil, gravel etc.thicknessinches(if appl.)ft bgsmm/dd/yy 24-hour clockoFsyringe, peristaltic, etc.Liters %% or ppm(indicate units below)Yes / No(see note)S:C:R:S:C:R:S:C:R:S:C:R:S= sample; C/R = canister/regulator; SS = sub-slab; SG = soil gas; perm = permanent; temp = temporarySampler(s): ___________________________________________________________Weather: ___________________________________________________________Notes: ____________________________________________________________________________________________________________________________________________________________________________________________________________________________________________Helium Leak TestCanister / RegulatorShut-in Test PassedGround SurfaceID NumbersSample / Canister / RegulatorTypeVapor Monitoring Point ConstructionGeneral Field Sketch of Sample Locations Note: Leak Test Requirements Per NC DEQ DWM Vapor Intrusion Guidance, leak test passes if helium concentration in purge air is less than 10% of helium concentration in shroud. S:\BBB Master Templates\Forms - Soil Gas\Sub-slab & Soil Gas QA_QC Field FormSub-Slab / Soil Gas Sampling Vapor QA/QC Field FormHart & Hickman, PCALI-00212/11/1945.065.065.067.0Partly Cloudy 45.0 F; Mostly Cloudy 65-67 FCGH-D-SS-MP-12099Air Pump4342CGH-C-SS-MP-120924315DUP-12/30/201921154315CGH-B-SS-MP-121254341SSSSSSSSPerm.Perm.Perm.Perm.ConcretConcretConcretConcret10:4512/30/1910:3012/30/1910:3012/30/1911:45 Air Pump Air Pump Air Pump10.010.010.010.020.119.519.514.10.00.00.00.0ppmAndrew Besu, Shannon Switch%ppm%ppm%ppm%YesNoYesNoYesNoYesNoYesNoYesNoYesNoYesNo Appendix D Analytical Laboratory Reports 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 December 18, 2019 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Charlotte, NC Client Job Number: Project Number: ALI-002 Laboratory Work Order Number: 19L0488 Enclosed are results of analyses for samples received by the laboratory on December 11, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 12/18/2019Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu ALI-002 19L0488 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Charlotte, NC ALI-002 CGH-D-SS-MP-1 19L0488-01 Sub Slab EPA TO-15 Page 2 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. Analyte & Samples(s) Qualified: Propene B248626-BS1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: Methylene Chloride 19L0488-01[CGH-D-SS-MP-1], B248626-BLK1, B248626-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: Methylene Chloride 19L0488-01[CGH-D-SS-MP-1], B248626-BLK1, B248626-BS1, S043895-CCV1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: Propene S043895-CCV1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/11/2019 Work Order: 19L0488Sample Description/Location: Field Sample #: CGH-D-SS-MP-1 Sample ID: 19L0488-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -3.7 Sampled: 12/11/2019 10:45 Canister ID: 2099 Flow Controller ID: Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 21 8.0 12/17/19 16:40 BRF504192.8 6.6 Benzene ND 0.20 12/17/19 16:40 BRFND40.640.082 0.26 2-Butanone (MEK)2.7 8.0 12/17/19 16:40 BRFJ8.1 4240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 12/17/19 16:40 BRFND42.50.31 0.93 n-Butylbenzene ND 0.58 12/17/19 16:40 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 12/17/19 16:40 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 12/17/19 16:40 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 12/17/19 16:40 BRFND46.20.14 0.43 Chloroform ND 0.20 12/17/19 16:40 BRFND40.980.074 0.36 Chloromethane ND 0.40 12/17/19 16:40 BRFND40.830.14 0.28 Cyclohexane ND 0.20 12/17/19 16:40 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 12/17/19 16:40 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 12/17/19 16:40 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.51 0.20 12/17/19 16:40 BRF2.5 40.990.087 0.43 1,1-Dichloroethane ND 0.20 12/17/19 16:40 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 12/17/19 16:40 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 12/17/19 16:40 BRFND40.790.082 0.32 Ethanol 9.6 8.0 12/17/19 16:40 BRF184153.6 6.7 Ethyl Acetate ND 0.20 12/17/19 16:40 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 12/17/19 16:40 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 12/17/19 16:40 BRFND40.980.12 0.60 Heptane ND 0.20 12/17/19 16:40 BRFND40.820.12 0.48 Hexane ND 8.0 12/17/19 16:40 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 12/17/19 16:40 BRFND40.820.12 0.48 Isopropanol 0.91 8.0 12/17/19 16:40 BRFJ2.2 4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 12/17/19 16:40 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 12/17/19 16:40 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 12/17/19 16:40 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 12/17/19 16:40 BRFV-05, L-03 ND 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 12/17/19 16:40 BRFND40.820.10 0.43 Naphthalene ND 0.20 12/17/19 16:40 BRFND41.00.15 0.80 Propene ND 8.0 12/17/19 16:40 BRFND4140.37 0.64 Propylbenzene ND 0.51 12/17/19 16:40 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 12/17/19 16:40 BRFND41.40.11 0.75 Tetrahydrofuran 23 0.20 12/17/19 16:40 BRF6940.590.20 0.59 Toluene ND 0.20 12/17/19 16:40 BRFND40.750.10 0.39 Trichloroethylene ND 0.20 12/17/19 16:40 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.28 0.80 12/17/19 16:40 BRFJ1.6 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 12/17/19 16:40 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 12/17/19 16:40 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 12/17/19 16:40 BRFND42.50.17 0.80 m&p-Xylene ND 0.40 12/17/19 16:40 BRFND41.70.23 1.00 o-Xylene ND 0.20 12/17/19 16:40 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits Page 4 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/11/2019 Work Order: 19L0488Sample Description/Location: Field Sample #: CGH-D-SS-MP-1 Sample ID: 19L0488-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -3.7 Sampled: 12/11/2019 10:45 Canister ID: 2099 Flow Controller ID: Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)107 12/17/19 16:4070-130 4-Bromofluorobenzene (2)94.4 12/17/19 16:4070-130 Page 5 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 19L0488-01 [CGH-D-SS-MP-1]B248626 1.5 1 N/A 1000 200 75 12/17/19 Page 6 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B248626 - TO-15 Prep Blank (B248626-BLK1)Prepared & Analyzed: 12/17/19 0.80NDAcetone 0.020NDBenzene 0.80ND2-Butanone (MEK) 0.082NDtert-Butyl Alcohol (TBA) 0.058NDn-Butylbenzene 0.046NDsec-Butylbenzene 0.046NDtert-Butylbenzene 0.20NDCarbon Disulfide 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.80NDEthanol 0.020NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.051NDIsopropylbenzene (Cumene) 0.046NDp-Isopropyltoluene (p-Cymene) 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20 L-03, V-05NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020NDNaphthalene 0.80NDPropene 0.051NDPropylbenzene 0.020NDTetrachloroethylene 0.020NDTetrahydrofuran 0.020NDToluene 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.054ND2,2,4-Trimethylpentane 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1088.62 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)95.97.67 Page 7 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B248626 - TO-15 Prep LCS (B248626-BS1)Prepared & Analyzed: 12/17/19 5.00 70-13079.13.96Acetone 5.00 70-13097.04.85Benzene 5.00 70-13088.54.422-Butanone (MEK) 2.06 50-15074.81.54tert-Butyl Alcohol (TBA) 1.14 70-13085.50.975n-Butylbenzene 1.14 70-13079.00.901sec-Butylbenzene 1.14 50-15068.40.780tert-Butylbenzene 5.00 70-13077.43.87Carbon Disulfide 5.00 70-13096.64.83Chloroform 5.00 70-1301165.79Chloromethane 5.00 70-13091.24.56Cyclohexane 5.00 70-1301095.431,2-Dichlorobenzene 5.00 70-1301095.431,3-Dichlorobenzene 5.00 70-1301145.72Dichlorodifluoromethane (Freon 12) 5.00 70-13096.04.801,1-Dichloroethane 5.00 70-13074.13.701,1-Dichloroethylene 5.00 70-13090.84.54cis-1,2-Dichloroethylene 5.00 70-1301145.69Ethanol 5.00 70-13074.93.74Ethyl Acetate 5.00 70-13092.84.64Ethylbenzene 5.00 70-13094.54.734-Ethyltoluene 5.00 70-13090.34.51Heptane 5.00 70-13085.64.28Hexane 5.00 70-13094.84.742-Hexanone (MBK) 5.00 70-13073.33.66Isopropanol 1.27 70-13077.20.981Isopropylbenzene (Cumene) 1.14 70-13080.10.913p-Isopropyltoluene (p-Cymene) 5.00 70-13085.24.26Methyl tert-Butyl Ether (MTBE) 5.00 V-05, L-0370-13066.03.30Methylene Chloride * 5.00 70-13096.54.824-Methyl-2-pentanone (MIBK) 5.00 70-1301005.00Naphthalene 5.00 L-0170-1301366.78Propene * 1.27 50-15075.80.963Propylbenzene 5.00 70-1301025.12Tetrachloroethylene 5.00 70-13085.14.25Tetrahydrofuran 5.00 70-13092.14.60Toluene 5.00 70-13094.14.71Trichloroethylene 5.00 70-13098.24.91Trichlorofluoromethane (Freon 11) 5.00 70-13095.14.751,2,4-Trimethylbenzene 5.00 70-13096.24.811,3,5-Trimethylbenzene 1.34 70-13074.30.9952,2,4-Trimethylpentane 10.0 70-13096.09.60m&p-Xylene 5.00 70-13093.64.68o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1108.83 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)98.07.84 Page 8 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank /laboratory control sample recovery outside of control limits. Data validation is not affected since all results are "not detected" for all samples in this batch for this compound and bias is on the high side. L-01 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-05 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-20 Page 9 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 10 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) NY,ME,NHtert-Butyl Alcohol (TBA) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NJ,NY,ME,NHIsopropylbenzene (Cumene) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH,VA2,2,4-Trimethylpentane AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 11 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2019 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 12 of 15 Page 13 of 15 Page 14 of 15 Page 15 of 15 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 January 7, 2020 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Charlotte, NC Client Job Number: Project Number: ALI-002 Laboratory Work Order Number: 20A0025 Enclosed are results of analyses for samples received by the laboratory on December 30, 2019. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 1/7/2020Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu ALI-002 20A0025 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Charlotte, NC ALI-002 CGH-B-SS-MP-1 20A0025-01 Sub Slab EPA TO-15 CGH-C-SS-MP-1 20A0025-02 Sub Slab EPA TO-15 DUP-20191230 20A0025-03 Sub Slab EPA TO-15 Page 2 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Reported result is estimated. Value reported over verified calibration range. Analyte & Samples(s) Qualified: Ethanol B249530-DUP1 Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: 2,2,4-Trimethylpentane, Isopropylbenzene (Cumene) 20A0025-01[CGH-B-SS-MP-1], 20A0025-02[CGH-C-SS-MP-1], 20A0025-03[DUP-20191230], B249530-BLK1, B249530-BS1, B249530-DUP1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. Analyte & Samples(s) Qualified: Naphthalene 20A0025-01[CGH-B-SS-MP-1], 20A0025-02[CGH-C-SS-MP-1], 20A0025-03[DUP-20191230], B249530-BLK1, B249530-BS1, B249530-DUP1, S044408-CCV1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: CGH-B-SS-MP-1 Sample ID: 20A0025-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 12/30/2019 12:11 Canister ID: 2125 Flow Controller ID: 4341 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 16 8.0 1/6/20 18:36 BRF384192.8 6.6 Benzene ND 0.20 1/6/20 18:36 BRFND40.640.082 0.26 2-Butanone (MEK)12 8.0 1/6/20 18:36 BRF364240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 1/6/20 18:36 BRFND42.50.31 0.93 n-Butylbenzene ND 0.58 1/6/20 18:36 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/6/20 18:36 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/6/20 18:36 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/6/20 18:36 BRFND46.20.14 0.43 Chloroform ND 0.20 1/6/20 18:36 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/6/20 18:36 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/6/20 18:36 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/6/20 18:36 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/6/20 18:36 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)ND 0.20 1/6/20 18:36 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/6/20 18:36 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/6/20 18:36 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/6/20 18:36 BRFND40.790.082 0.32 Ethanol 290 40 1/6/20 19:01 BRF55020751834 Ethyl Acetate ND 0.20 1/6/20 18:36 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 1/6/20 18:36 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 1/6/20 18:36 BRFND40.980.12 0.60 Heptane ND 0.20 1/6/20 18:36 BRFND40.820.12 0.48 Hexane ND 8.0 1/6/20 18:36 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/6/20 18:36 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/6/20 18:36 BRFND4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/6/20 18:36 BRFL-03 ND 42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/6/20 18:36 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/6/20 18:36 BRFND40.720.10 0.36 Methylene Chloride 1.3 2.0 1/6/20 18:36 BRFJ4.4 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/6/20 18:36 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/6/20 18:36 BRFV-05 ND 41.00.15 0.80 Propene ND 8.0 1/6/20 18:36 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/6/20 18:36 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/6/20 18:36 BRFND41.40.11 0.75 Tetrahydrofuran 11 0.20 1/6/20 18:36 BRF3240.590.20 0.59 Toluene 0.32 0.20 1/6/20 18:36 BRF1.2 40.750.10 0.39 Trichloroethylene ND 0.20 1/6/20 18:36 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.30 0.80 1/6/20 18:36 BRFJ1.7 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/6/20 18:36 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/6/20 18:36 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/6/20 18:36 BRFL-03 ND 42.50.17 0.80 m&p-Xylene ND 0.40 1/6/20 18:36 BRFND41.70.23 1.00 o-Xylene ND 0.20 1/6/20 18:36 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits Page 4 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: CGH-B-SS-MP-1 Sample ID: 20A0025-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 12/30/2019 12:11 Canister ID: 2125 Flow Controller ID: 4341 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)109 1/6/20 19:0170-130 4-Bromofluorobenzene (1)110 1/6/20 18:3670-130 4-Bromofluorobenzene (2)98.6 1/6/20 18:3670-130 Page 5 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: CGH-C-SS-MP-1 Sample ID: 20A0025-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 12/30/2019 10:55 Canister ID: 2092 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 170 8.0 1/6/20 20:16 BRF4004192.8 6.6 Benzene ND 0.20 1/6/20 20:16 BRFND40.640.082 0.26 2-Butanone (MEK)260 40 1/6/20 20:41 BRF770201201.9 5.5 tert-Butyl Alcohol (TBA)0.40 0.82 1/6/20 20:16 BRFJ1.2 42.50.31 0.93 n-Butylbenzene 3.9 0.58 1/6/20 20:16 BRF2143.20.13 0.72 sec-Butylbenzene 2.4 0.46 1/6/20 20:16 BRF1342.50.16 0.86 tert-Butylbenzene ND 0.46 1/6/20 20:16 BRFND42.50.17 0.94 Carbon Disulfide 1.5 2.0 1/6/20 20:16 BRFJ4.6 46.20.14 0.43 Chloroform 0.33 0.20 1/6/20 20:16 BRF1.6 40.980.074 0.36 Chloromethane ND 0.40 1/6/20 20:16 BRFND40.830.14 0.28 Cyclohexane 2.5 0.20 1/6/20 20:16 BRF8.7 40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/6/20 20:16 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/6/20 20:16 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)ND 0.20 1/6/20 20:16 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/6/20 20:16 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/6/20 20:16 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/6/20 20:16 BRFND40.790.082 0.32 Ethanol 9.4 8.0 1/6/20 20:16 BRF184153.6 6.7 Ethyl Acetate ND 0.20 1/6/20 20:16 BRFND40.720.15 0.54 Ethylbenzene 5.3 0.20 1/6/20 20:16 BRF2340.870.12 0.50 4-Ethyltoluene 6.9 0.20 1/6/20 20:16 BRF3440.980.12 0.60 Heptane 4.7 0.20 1/6/20 20:16 BRF1940.820.12 0.48 Hexane 1.5 8.0 1/6/20 20:16 BRFJ5.3 4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/6/20 20:16 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/6/20 20:16 BRFND4200.37 0.90 Isopropylbenzene (Cumene)1.5 0.51 1/6/20 20:16 BRFL-03 7.2 42.50.16 0.79 p-Isopropyltoluene (p-Cymene)1.4 0.46 1/6/20 20:16 BRF7.4 42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/6/20 20:16 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 1/6/20 20:16 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/6/20 20:16 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/6/20 20:16 BRFV-05 ND 41.00.15 0.80 Propene ND 8.0 1/6/20 20:16 BRFND4140.37 0.64 Propylbenzene 3.8 0.51 1/6/20 20:16 BRF1942.50.18 0.87 Tetrachloroethylene 0.57 0.20 1/6/20 20:16 BRF3.9 41.40.11 0.75 Tetrahydrofuran 610 1.0 1/6/20 20:41 BRF1800202.90.99 2.9 Toluene 2.7 0.20 1/6/20 20:16 BRF1040.750.10 0.39 Trichloroethylene ND 0.20 1/6/20 20:16 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.39 0.80 1/6/20 20:16 BRFJ2.2 44.50.15 0.85 1,2,4-Trimethylbenzene 20 0.20 1/6/20 20:16 BRF9940.980.13 0.63 1,3,5-Trimethylbenzene 7.4 0.20 1/6/20 20:16 BRF3740.980.13 0.62 2,2,4-Trimethylpentane 1.7 0.54 1/6/20 20:16 BRFL-03 7.7 42.50.17 0.80 m&p-Xylene 13 0.40 1/6/20 20:16 BRF5741.70.23 1.00 o-Xylene 8.6 0.20 1/6/20 20:16 BRF3740.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)110 1/6/20 20:1670-130 Page 6 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: CGH-C-SS-MP-1 Sample ID: 20A0025-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.1 Sampled: 12/30/2019 10:55 Canister ID: 2092 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)110 1/6/20 20:4170-130 4-Bromofluorobenzene (2)88.8 1/6/20 20:1670-130 Page 7 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: DUP-20191230 Sample ID: 20A0025-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 12/30/2019 00:00 Canister ID: 2115 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 160 8.0 1/6/20 21:05 BRF3704192.8 6.6 Benzene 0.20 0.20 1/6/20 21:05 BRF0.65 40.640.082 0.26 2-Butanone (MEK)240 40 1/6/20 21:30 BRF700201201.9 5.5 tert-Butyl Alcohol (TBA)ND 0.82 1/6/20 21:05 BRFND42.50.31 0.93 n-Butylbenzene 3.6 0.58 1/6/20 21:05 BRF2043.20.13 0.72 sec-Butylbenzene 2.4 0.46 1/6/20 21:05 BRF1342.50.16 0.86 tert-Butylbenzene ND 0.46 1/6/20 21:05 BRFND42.50.17 0.94 Carbon Disulfide 1.5 2.0 1/6/20 21:05 BRFJ4.6 46.20.14 0.43 Chloroform 0.25 0.20 1/6/20 21:05 BRF1.2 40.980.074 0.36 Chloromethane ND 0.40 1/6/20 21:05 BRFND40.830.14 0.28 Cyclohexane 2.3 0.20 1/6/20 21:05 BRF7.9 40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/6/20 21:05 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/6/20 21:05 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)ND 0.20 1/6/20 21:05 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/6/20 21:05 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/6/20 21:05 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/6/20 21:05 BRFND40.790.082 0.32 Ethanol ND 8.0 1/6/20 21:05 BRFND4153.6 6.7 Ethyl Acetate ND 0.20 1/6/20 21:05 BRFND40.720.15 0.54 Ethylbenzene 4.7 0.20 1/6/20 21:05 BRF2140.870.12 0.50 4-Ethyltoluene 6.5 0.20 1/6/20 21:05 BRF3240.980.12 0.60 Heptane 4.1 0.20 1/6/20 21:05 BRF1740.820.12 0.48 Hexane 1.8 8.0 1/6/20 21:05 BRFJ6.4 4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/6/20 21:05 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/6/20 21:05 BRFND4200.37 0.90 Isopropylbenzene (Cumene)1.4 0.51 1/6/20 21:05 BRFL-03 7.1 42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/6/20 21:05 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/6/20 21:05 BRFND40.720.10 0.36 Methylene Chloride 0.39 2.0 1/6/20 21:05 BRFJ1.4 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/6/20 21:05 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/6/20 21:05 BRFV-05 ND 41.00.15 0.80 Propene ND 8.0 1/6/20 21:05 BRFND4140.37 0.64 Propylbenzene 3.6 0.51 1/6/20 21:05 BRF1842.50.18 0.87 Tetrachloroethylene 0.50 0.20 1/6/20 21:05 BRF3.4 41.40.11 0.75 Tetrahydrofuran 550 1.0 1/6/20 21:30 BRF1600202.90.99 2.9 Toluene 2.7 0.20 1/6/20 21:05 BRF1040.750.10 0.39 Trichloroethylene ND 0.20 1/6/20 21:05 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.34 0.80 1/6/20 21:05 BRFJ1.9 44.50.15 0.85 1,2,4-Trimethylbenzene 18 0.20 1/6/20 21:05 BRF8940.980.13 0.63 1,3,5-Trimethylbenzene 6.8 0.20 1/6/20 21:05 BRF3440.980.13 0.62 2,2,4-Trimethylpentane 1.5 0.54 1/6/20 21:05 BRFL-03 7.0 42.50.17 0.80 m&p-Xylene 12 0.40 1/6/20 21:05 BRF5241.70.23 1.00 o-Xylene 7.9 0.20 1/6/20 21:05 BRF3440.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)109 1/6/20 21:3070-130 Page 8 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 12/30/2019 Work Order: 20A0025Sample Description/Location: Field Sample #: DUP-20191230 Sample ID: 20A0025-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 12/30/2019 00:00 Canister ID: 2115 Flow Controller ID: 4315 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)110 1/6/20 21:0570-130 4-Bromofluorobenzene (2)93.5 1/6/20 21:0570-130 Page 9 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 20A0025-01 [CGH-B-SS-MP-1]B249530 1.5 1 N/A 1000 200 75 01/06/20 20A0025-01RE1 [CGH-B-SS-MP-1]B249530 1.5 1 N/A 1000 200 15 01/06/20 20A0025-02 [CGH-C-SS-MP-1]B249530 1.5 1 N/A 1000 200 75 01/06/20 20A0025-02RE1 [CGH-C-SS-MP-1]B249530 1.5 1 N/A 1000 200 15 01/06/20 20A0025-03 [DUP-20191230]B249530 1.5 1 N/A 1000 200 75 01/06/20 20A0025-03RE1 [DUP-20191230]B249530 1.5 1 N/A 1000 200 15 01/06/20 Page 10 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B249530 - TO-15 Prep Blank (B249530-BLK1)Prepared & Analyzed: 01/06/20 0.80 J0.30Acetone 0.020NDBenzene 0.80ND2-Butanone (MEK) 0.082NDtert-Butyl Alcohol (TBA) 0.058NDn-Butylbenzene 0.046NDsec-Butylbenzene 0.046NDtert-Butylbenzene 0.20NDCarbon Disulfide 0.020NDChloroform 0.040NDChloromethane 0.020NDCyclohexane 0.020ND1,2-Dichlorobenzene 0.020ND1,3-Dichlorobenzene 0.020NDDichlorodifluoromethane (Freon 12) 0.020ND1,1-Dichloroethane 0.020ND1,1-Dichloroethylene 0.020NDcis-1,2-Dichloroethylene 0.80 J0.49Ethanol 0.020NDEthyl Acetate 0.020NDEthylbenzene 0.020ND4-Ethyltoluene 0.020NDHeptane 0.80NDHexane 0.020ND2-Hexanone (MBK) 0.80NDIsopropanol 0.051 L-03NDIsopropylbenzene (Cumene) 0.046NDp-Isopropyltoluene (p-Cymene) 0.020NDMethyl tert-Butyl Ether (MTBE) 0.20NDMethylene Chloride 0.020ND4-Methyl-2-pentanone (MIBK) 0.020 V-05NDNaphthalene 0.80NDPropene 0.051NDPropylbenzene 0.020NDTetrachloroethylene 0.020NDTetrahydrofuran 0.020NDToluene 0.020NDTrichloroethylene 0.080NDTrichlorofluoromethane (Freon 11) 0.020ND1,2,4-Trimethylbenzene 0.020ND1,3,5-Trimethylbenzene 0.054 L-03ND2,2,4-Trimethylpentane 0.040NDm&p-Xylene 0.020NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1098.74 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)99.37.94 Page 11 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B249530 - TO-15 Prep LCS (B249530-BS1)Prepared & Analyzed: 01/06/20 5.00 70-13087.14.35Acetone 5.00 70-13092.04.60Benzene 5.00 70-13089.84.492-Butanone (MEK) 2.06 50-15079.51.64tert-Butyl Alcohol (TBA) 1.14 70-13074.90.854n-Butylbenzene 1.14 70-13070.50.804sec-Butylbenzene 1.14 50-15061.10.696tert-Butylbenzene 5.00 70-13087.94.40Carbon Disulfide 5.00 70-13091.74.59Chloroform 5.00 70-1301125.60Chloromethane 5.00 70-13086.84.34Cyclohexane 5.00 70-1301065.291,2-Dichlorobenzene 5.00 70-1301216.061,3-Dichlorobenzene 5.00 70-1301065.28Dichlorodifluoromethane (Freon 12) 5.00 70-13091.94.601,1-Dichloroethane 5.00 70-13083.84.191,1-Dichloroethylene 5.00 70-13090.44.52cis-1,2-Dichloroethylene 5.00 70-1301115.54Ethanol 5.00 70-13074.23.71Ethyl Acetate 5.00 70-13091.04.55Ethylbenzene 5.00 70-1301055.264-Ethyltoluene 5.00 70-13086.94.34Heptane 5.00 70-13088.84.44Hexane 5.00 70-13092.84.642-Hexanone (MBK) 5.00 70-13077.73.88Isopropanol 1.27 L-0370-13068.10.865Isopropylbenzene (Cumene)* 1.14 70-13072.00.821p-Isopropyltoluene (p-Cymene) 5.00 70-13083.44.17Methyl tert-Butyl Ether (MTBE) 5.00 70-13073.53.68Methylene Chloride 5.00 70-13092.64.634-Methyl-2-pentanone (MIBK) 5.00 V-0570-1301015.03Naphthalene 5.00 70-1301286.41Propene 1.27 50-15066.90.850Propylbenzene 5.00 70-1301005.00Tetrachloroethylene 5.00 70-13089.04.45Tetrahydrofuran 5.00 70-13091.04.55Toluene 5.00 70-13088.54.42Trichloroethylene 5.00 70-13093.84.69Trichlorofluoromethane (Freon 11) 5.00 70-13095.44.771,2,4-Trimethylbenzene 5.00 70-13095.54.781,3,5-Trimethylbenzene 1.34 L-0370-13069.00.9242,2,4-Trimethylpentane * 10.0 70-13092.49.24m&p-Xylene 5.00 70-13090.44.52o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1139.07 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)96.07.68 Page 12 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B249530 - TO-15 Prep Duplicate (B249530-DUP1)Prepared & Analyzed: 01/06/20 Source: 20A0025-01 8.0 16 251.6516Acetone1937 0.20 ND 25NDBenzene0.64ND 8.0 12 252.11122-Butanone (MEK)2435 0.82 ND 25NDtert-Butyl Alcohol (TBA)2.5ND 0.58 ND 25NDn-Butylbenzene 3.2ND 0.46 ND 25NDsec-Butylbenzene 2.5ND 0.46 ND 25NDtert-Butylbenzene 2.5ND 2.0 ND 25NDCarbon Disulfide 6.2ND 0.20 ND 25NDChloroform0.98ND 0.40 ND 25NDChloromethane0.83ND 0.20 ND 25NDCyclohexane0.69ND 0.20 ND 25ND1,2-Dichlorobenzene 1.2ND 0.20 ND 25ND1,3-Dichlorobenzene 1.2ND 0.20 ND 25NDDichlorodifluoromethane (Freon 12)0.99ND 0.20 ND 25ND1,1-Dichloroethane 0.81ND 0.20 ND 25ND1,1-Dichloroethylene 0.79ND 0.20 ND 25NDcis-1,2-Dichloroethylene 0.79ND 8.0 320 25 E1.73320Ethanol15610 0.20 ND 25NDEthyl Acetate 0.72ND 0.20 ND 25NDEthylbenzene0.87ND 0.20 ND 25ND4-Ethyltoluene 0.98ND 0.20 ND 25NDHeptane0.82ND 8.0 ND 25NDHexane28ND 0.20 ND 25ND2-Hexanone (MBK)0.82ND 8.0 ND 25NDIsopropanol20ND 0.51 ND 25 L-03NDIsopropylbenzene (Cumene)2.5ND 0.46 ND 25NDp-Isopropyltoluene (p-Cymene)2.5ND 0.20 ND 25NDMethyl tert-Butyl Ether (MTBE)0.72ND 2.0 1.3 25 J3.501.2Methylene Chloride 6.94.3 0.20 ND 25ND4-Methyl-2-pentanone (MIBK)0.82ND 0.20 ND 25 V-05NDNaphthalene1.0ND 8.0 ND 25NDPropene14ND 0.51 ND 25NDPropylbenzene2.5ND 0.20 ND 25NDTetrachloroethylene1.4ND 0.20 11 250.29511Tetrahydrofuran0.5932 0.20 0.32 258.380.35Toluene 0.751.3 0.20 ND 25NDTrichloroethylene1.1ND 0.80 0.30 25 J0.000.30Trichlorofluoromethane (Freon 11)4.51.7 0.20 ND 25ND1,2,4-Trimethylbenzene 0.98ND 0.20 ND 25ND1,3,5-Trimethylbenzene 0.98ND 0.54 ND 25 L-03ND2,2,4-Trimethylpentane 2.5ND 0.40 ND 25NDm&p-Xylene 1.7ND 0.20 ND 25NDo-Xylene 0.87ND 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1118.87 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)98.27.86 Page 13 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Reported result is estimated. Value reported over verified calibration range.E Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Continuing calibration verification (CCV) did not meet method specifications and was biased on the low side for this compound. V-05 Page 14 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 15 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) NY,ME,NHtert-Butyl Alcohol (TBA) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NJ,NY,ME,NHIsopropylbenzene (Cumene) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH,VA2,2,4-Trimethylpentane AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 16 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 17 of 20 Page 18 of 20 Page 19 of 20 Page 20 of 20 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 January 16, 2020 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Charlotte, NC Client Job Number: Project Number: ALI-002 Laboratory Work Order Number: 20A0524 Enclosed are results of analyses for samples received by the laboratory on January 9, 2020. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 1/16/2020Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu ALI-002 20A0524 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Charlotte, NC ALI-002 Bld-2-SS-MP-2 20A0524-01 Sub Slab EPA TO-15 Bld-2-SS-MP-3 20A0524-02 Sub Slab EPA TO-15 Bld-2-SS-MP-4 20A0524-03 Sub Slab EPA TO-15 Bld-2-SS-MP-5 20A0524-04 Sub Slab EPA TO-15 Bld-2-SS-MP-6 20A0524-05 Sub Slab EPA TO-15 Page 2 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: tert-Butyl Alcohol (TBA) 20A0524-01[Bld-2-SS-MP-2], 20A0524-02[Bld-2-SS-MP-3], 20A0524-03[Bld-2-SS-MP-4], 20A0524-04[Bld-2-SS-MP-5], 20A0524-05[Bld-2-SS-MP-6], B250197-BLK1, B250197-BS1, S044668-CCV1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Tod E. Kopyscinski Laboratory Director Page 3 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-2 Sample ID: 20A0524-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 1/8/2020 13:19 Canister ID: 2232 Flow Controller ID: 4324 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 9.0 8.0 1/15/20 19:32 BRF214192.8 6.6 Benzene ND 0.20 1/15/20 19:32 BRFND40.640.082 0.26 2-Butanone (MEK)12 8.0 1/15/20 19:32 BRF344240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 1/15/20 19:32 BRFV-34 ND 42.50.31 0.93 n-Butylbenzene ND 0.58 1/15/20 19:32 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/15/20 19:32 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/15/20 19:32 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/15/20 19:32 BRFND46.20.14 0.43 Chloroform ND 0.20 1/15/20 19:32 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/15/20 19:32 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/15/20 19:32 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/15/20 19:32 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/15/20 19:32 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.36 0.20 1/15/20 19:32 BRF1.8 40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/15/20 19:32 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/15/20 19:32 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/15/20 19:32 BRFND40.790.082 0.32 Ethanol 37 8.0 1/15/20 19:32 BRF694153.6 6.7 Ethyl Acetate ND 0.20 1/15/20 19:32 BRFND40.720.15 0.54 Ethylbenzene 0.57 0.20 1/15/20 19:32 BRF2.5 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/15/20 19:32 BRFND40.980.12 0.60 Heptane ND 0.20 1/15/20 19:32 BRFND40.820.12 0.48 Hexane ND 8.0 1/15/20 19:32 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/15/20 19:32 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/15/20 19:32 BRFND4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/15/20 19:32 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/15/20 19:32 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/15/20 19:32 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 1/15/20 19:32 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/15/20 19:32 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/15/20 19:32 BRFND41.00.15 0.80 Propene ND 8.0 1/15/20 19:32 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/15/20 19:32 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/15/20 19:32 BRFND41.40.11 0.75 Tetrahydrofuran 4.1 0.20 1/15/20 19:32 BRF1240.590.20 0.59 Toluene ND 0.20 1/15/20 19:32 BRFND40.750.10 0.39 Trichloroethylene ND 0.20 1/15/20 19:32 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.28 0.80 1/15/20 19:32 BRFJ1.6 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/15/20 19:32 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/15/20 19:32 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/15/20 19:32 BRFND42.50.17 0.80 m&p-Xylene 2.1 0.40 1/15/20 19:32 BRF9.1 41.70.23 1.00 o-Xylene 0.45 0.20 1/15/20 19:32 BRF1.9 40.870.12 0.54 Surrogates % Recovery % REC Limits Page 4 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-2 Sample ID: 20A0524-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -27 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 1/8/2020 13:19 Canister ID: 2232 Flow Controller ID: 4324 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)110 1/15/20 19:3270-130 4-Bromofluorobenzene (2)115 1/15/20 19:3270-130 Page 5 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-3 Sample ID: 20A0524-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.4 Sampled: 1/8/2020 12:41 Canister ID: 2109 Flow Controller ID: 4332 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 12 8.0 1/15/20 20:12 BRF294192.8 6.6 Benzene ND 0.20 1/15/20 20:12 BRFND40.640.082 0.26 2-Butanone (MEK)1.9 8.0 1/15/20 20:12 BRFJ5.5 4240.37 1.1 tert-Butyl Alcohol (TBA)2.5 0.82 1/15/20 20:12 BRFV-34 7.6 42.50.31 0.93 n-Butylbenzene ND 0.58 1/15/20 20:12 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/15/20 20:12 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/15/20 20:12 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/15/20 20:12 BRFND46.20.14 0.43 Chloroform ND 0.20 1/15/20 20:12 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/15/20 20:12 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/15/20 20:12 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/15/20 20:12 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/15/20 20:12 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.38 0.20 1/15/20 20:12 BRF1.9 40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/15/20 20:12 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/15/20 20:12 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/15/20 20:12 BRFND40.790.082 0.32 Ethanol 120 8.0 1/15/20 20:12 BRF2304153.6 6.7 Ethyl Acetate 0.73 0.20 1/15/20 20:12 BRF2.6 40.720.15 0.54 Ethylbenzene 0.23 0.20 1/15/20 20:12 BRF0.99 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/15/20 20:12 BRFND40.980.12 0.60 Heptane ND 0.20 1/15/20 20:12 BRFND40.820.12 0.48 Hexane ND 8.0 1/15/20 20:12 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/15/20 20:12 BRFND40.820.12 0.48 Isopropanol 0.94 8.0 1/15/20 20:12 BRFJ2.3 4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/15/20 20:12 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/15/20 20:12 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/15/20 20:12 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 1/15/20 20:12 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/15/20 20:12 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/15/20 20:12 BRFND41.00.15 0.80 Propene ND 8.0 1/15/20 20:12 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/15/20 20:12 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/15/20 20:12 BRFND41.40.11 0.75 Tetrahydrofuran 4.9 0.20 1/15/20 20:12 BRF1440.590.20 0.59 Toluene 0.80 0.20 1/15/20 20:12 BRF3.0 40.750.10 0.39 Trichloroethylene ND 0.20 1/15/20 20:12 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.23 0.80 1/15/20 20:12 BRFJ1.3 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/15/20 20:12 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/15/20 20:12 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/15/20 20:12 BRFND42.50.17 0.80 m&p-Xylene 0.79 0.40 1/15/20 20:12 BRF3.4 41.70.23 1.00 o-Xylene ND 0.20 1/15/20 20:12 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)109 1/15/20 20:1270-130 Page 6 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-3 Sample ID: 20A0524-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.4 Sampled: 1/8/2020 12:41 Canister ID: 2109 Flow Controller ID: 4332 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (2)116 1/15/20 20:1270-130 Page 7 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-4 Sample ID: 20A0524-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -3.8 Sampled: 1/8/2020 12:05 Canister ID: 2349 Flow Controller ID: 4323 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 20 8.0 1/15/20 20:52 BRF484192.8 6.6 Benzene ND 0.20 1/15/20 20:52 BRFND40.640.082 0.26 2-Butanone (MEK)2.4 8.0 1/15/20 20:52 BRFJ7.2 4240.37 1.1 tert-Butyl Alcohol (TBA)0.44 0.82 1/15/20 20:52 BRFV-34, J 1.3 42.50.31 0.93 n-Butylbenzene ND 0.58 1/15/20 20:52 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/15/20 20:52 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/15/20 20:52 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/15/20 20:52 BRFND46.20.14 0.43 Chloroform ND 0.20 1/15/20 20:52 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/15/20 20:52 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/15/20 20:52 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/15/20 20:52 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/15/20 20:52 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.34 0.20 1/15/20 20:52 BRF1.7 40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/15/20 20:52 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/15/20 20:52 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/15/20 20:52 BRFND40.790.082 0.32 Ethanol 71 8.0 1/15/20 20:52 BRF1304153.6 6.7 Ethyl Acetate ND 0.20 1/15/20 20:52 BRFND40.720.15 0.54 Ethylbenzene ND 0.20 1/15/20 20:52 BRFND40.870.12 0.50 4-Ethyltoluene ND 0.20 1/15/20 20:52 BRFND40.980.12 0.60 Heptane ND 0.20 1/15/20 20:52 BRFND40.820.12 0.48 Hexane ND 8.0 1/15/20 20:52 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/15/20 20:52 BRFND40.820.12 0.48 Isopropanol 0.62 8.0 1/15/20 20:52 BRFJ1.5 4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/15/20 20:52 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/15/20 20:52 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/15/20 20:52 BRFND40.720.10 0.36 Methylene Chloride ND 2.0 1/15/20 20:52 BRFND46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/15/20 20:52 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/15/20 20:52 BRFND41.00.15 0.80 Propene ND 8.0 1/15/20 20:52 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/15/20 20:52 BRFND42.50.18 0.87 Tetrachloroethylene 0.45 0.20 1/15/20 20:52 BRF3.1 41.40.11 0.75 Tetrahydrofuran 32 0.20 1/15/20 20:52 BRF9540.590.20 0.59 Toluene 0.52 0.20 1/15/20 20:52 BRF2.0 40.750.10 0.39 Trichloroethylene ND 0.20 1/15/20 20:52 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.24 0.80 1/15/20 20:52 BRFJ1.3 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/15/20 20:52 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/15/20 20:52 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/15/20 20:52 BRFND42.50.17 0.80 m&p-Xylene 0.61 0.40 1/15/20 20:52 BRF2.6 41.70.23 1.00 o-Xylene ND 0.20 1/15/20 20:52 BRFND40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)108 1/15/20 20:5270-130 Page 8 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-4 Sample ID: 20A0524-03 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -30 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -3.8 Sampled: 1/8/2020 12:05 Canister ID: 2349 Flow Controller ID: 4323 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (2)114 1/15/20 20:5270-130 Page 9 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-5 Sample ID: 20A0524-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -4.9 Sampled: 1/8/2020 11:31 Canister ID: 2127 Flow Controller ID: 4319 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 29 8.0 1/15/20 21:33 BRF704192.8 6.6 Benzene ND 0.20 1/15/20 21:33 BRFND40.640.082 0.26 2-Butanone (MEK)1.6 8.0 1/15/20 21:33 BRFJ4.9 4240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 1/15/20 21:33 BRFV-34 ND 42.50.31 0.93 n-Butylbenzene ND 0.58 1/15/20 21:33 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/15/20 21:33 BRFND42.50.16 0.86 tert-Butylbenzene 0.42 0.46 1/15/20 21:33 BRFJ2.3 42.50.17 0.94 Carbon Disulfide ND 2.0 1/15/20 21:33 BRFND46.20.14 0.43 Chloroform ND 0.20 1/15/20 21:33 BRFND40.980.074 0.36 Chloromethane 0.56 0.40 1/15/20 21:33 BRF1.2 40.830.14 0.28 Cyclohexane ND 0.20 1/15/20 21:33 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/15/20 21:33 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/15/20 21:33 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.40 0.20 1/15/20 21:33 BRF2.0 40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/15/20 21:33 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/15/20 21:33 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/15/20 21:33 BRFND40.790.082 0.32 Ethanol 78 8.0 1/15/20 21:33 BRF1504153.6 6.7 Ethyl Acetate 0.60 0.20 1/15/20 21:33 BRF2.1 40.720.15 0.54 Ethylbenzene 0.23 0.20 1/15/20 21:33 BRF1.0 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/15/20 21:33 BRFND40.980.12 0.60 Heptane ND 0.20 1/15/20 21:33 BRFND40.820.12 0.48 Hexane ND 8.0 1/15/20 21:33 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/15/20 21:33 BRFND40.820.12 0.48 Isopropanol 2.1 8.0 1/15/20 21:33 BRFJ5.3 4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/15/20 21:33 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)0.42 0.46 1/15/20 21:33 BRFJ2.3 42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/15/20 21:33 BRFND40.720.10 0.36 Methylene Chloride 0.28 2.0 1/15/20 21:33 BRFJ0.97 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/15/20 21:33 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/15/20 21:33 BRFND41.00.15 0.80 Propene ND 8.0 1/15/20 21:33 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/15/20 21:33 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/15/20 21:33 BRFND41.40.11 0.75 Tetrahydrofuran 1.1 0.20 1/15/20 21:33 BRF3.2 40.590.20 0.59 Toluene 1.1 0.20 1/15/20 21:33 BRF4.0 40.750.10 0.39 Trichloroethylene ND 0.20 1/15/20 21:33 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.22 0.80 1/15/20 21:33 BRFJ1.2 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/15/20 21:33 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/15/20 21:33 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/15/20 21:33 BRFND42.50.17 0.80 m&p-Xylene 0.81 0.40 1/15/20 21:33 BRF3.5 41.70.23 1.00 o-Xylene 0.22 0.20 1/15/20 21:33 BRF0.94 40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)108 1/15/20 21:3370-130 Page 10 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-5 Sample ID: 20A0524-04 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -4.9 Sampled: 1/8/2020 11:31 Canister ID: 2127 Flow Controller ID: 4319 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (2)116 1/15/20 21:3370-130 Page 11 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-6 Sample ID: 20A0524-05 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6 Sampled: 1/8/2020 10:31 Canister ID: 2240 Flow Controller ID: 4333 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 7.1 8.0 1/15/20 22:13 BRFJ174192.8 6.6 Benzene ND 0.20 1/15/20 22:13 BRFND40.640.082 0.26 2-Butanone (MEK)1.4 8.0 1/15/20 22:13 BRFJ4.0 4240.37 1.1 tert-Butyl Alcohol (TBA)0.33 0.82 1/15/20 22:13 BRFV-34, J 1.0 42.50.31 0.93 n-Butylbenzene ND 0.58 1/15/20 22:13 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/15/20 22:13 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/15/20 22:13 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/15/20 22:13 BRFND46.20.14 0.43 Chloroform ND 0.20 1/15/20 22:13 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/15/20 22:13 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/15/20 22:13 BRFND40.690.14 0.49 1,2-Dichlorobenzene ND 0.20 1/15/20 22:13 BRFND41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/15/20 22:13 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)0.43 0.20 1/15/20 22:13 BRF2.1 40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/15/20 22:13 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/15/20 22:13 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene 0.49 0.20 1/15/20 22:13 BRF1.9 40.790.082 0.32 Ethanol 180 8.0 1/15/20 22:13 BRF3404153.6 6.7 Ethyl Acetate ND 0.20 1/15/20 22:13 BRFND40.720.15 0.54 Ethylbenzene 0.53 0.20 1/15/20 22:13 BRF2.3 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/15/20 22:13 BRFND40.980.12 0.60 Heptane ND 0.20 1/15/20 22:13 BRFND40.820.12 0.48 Hexane ND 8.0 1/15/20 22:13 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/15/20 22:13 BRFND40.820.12 0.48 Isopropanol 1.3 8.0 1/15/20 22:13 BRFJ3.3 4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/15/20 22:13 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/15/20 22:13 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/15/20 22:13 BRFND40.720.10 0.36 Methylene Chloride 0.25 2.0 1/15/20 22:13 BRFJ0.88 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/15/20 22:13 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/15/20 22:13 BRFND41.00.15 0.80 Propene ND 8.0 1/15/20 22:13 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/15/20 22:13 BRFND42.50.18 0.87 Tetrachloroethylene 5.7 0.20 1/15/20 22:13 BRF3941.40.11 0.75 Tetrahydrofuran ND 0.20 1/15/20 22:13 BRFND40.590.20 0.59 Toluene 1.0 0.20 1/15/20 22:13 BRF3.8 40.750.10 0.39 Trichloroethylene 2.5 0.20 1/15/20 22:13 BRF1441.10.081 0.43 Trichlorofluoromethane (Freon 11)0.34 0.80 1/15/20 22:13 BRFJ1.9 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/15/20 22:13 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/15/20 22:13 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/15/20 22:13 BRFND42.50.17 0.80 m&p-Xylene 2.0 0.40 1/15/20 22:13 BRF8.7 41.70.23 1.00 o-Xylene 0.47 0.20 1/15/20 22:13 BRF2.0 40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)108 1/15/20 22:1370-130 Page 12 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/9/2020 Work Order: 20A0524Sample Description/Location: Field Sample #: Bld-2-SS-MP-6 Sample ID: 20A0524-05 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -28 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6 Sampled: 1/8/2020 10:31 Canister ID: 2240 Flow Controller ID: 4333 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (2)115 1/15/20 22:1370-130 Page 13 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 20A0524-01 [Bld-2-SS-MP-2]B250197 1.5 1 N/A 1000 400 150 01/15/20 20A0524-02 [Bld-2-SS-MP-3]B250197 1.5 1 N/A 1000 400 150 01/15/20 20A0524-03 [Bld-2-SS-MP-4]B250197 1.5 1 N/A 1000 400 150 01/15/20 20A0524-04 [Bld-2-SS-MP-5]B250197 1.5 1 N/A 1000 400 150 01/15/20 20A0524-05 [Bld-2-SS-MP-6]B250197 1.5 1 N/A 1000 400 150 01/15/20 Page 14 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B250197 - TO-15 Prep Blank (B250197-BLK1)Prepared & Analyzed: 01/15/20 1.4NDAcetone 0.035NDBenzene 1.4ND2-Butanone (MEK) 0.14 V-34NDtert-Butyl Alcohol (TBA) 0.10NDn-Butylbenzene 0.080NDsec-Butylbenzene 0.080NDtert-Butylbenzene 0.35NDCarbon Disulfide 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.089NDIsopropylbenzene (Cumene) 0.080NDp-Isopropyltoluene (p-Cymene) 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35NDMethylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.089NDPropylbenzene 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.094ND2,2,4-Trimethylpentane 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1068.49 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)1139.01 Page 15 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B250197 - TO-15 Prep LCS (B250197-BS1)Prepared & Analyzed: 01/15/20 5.00 70-1301075.35Acetone 5.00 70-13075.23.76Benzene 5.00 70-13093.14.652-Butanone (MEK) 2.06 V-3450-15080.81.66tert-Butyl Alcohol (TBA) 1.14 70-13092.61.06n-Butylbenzene 1.14 70-13094.41.08sec-Butylbenzene 1.14 50-15096.81.10tert-Butylbenzene 5.00 70-13089.04.45Carbon Disulfide 5.00 70-13087.04.35Chloroform 5.00 70-13080.64.03Chloromethane 5.00 70-13071.13.55Cyclohexane 5.00 70-13096.34.821,2-Dichlorobenzene 5.00 70-13098.04.901,3-Dichlorobenzene 5.00 70-13094.54.72Dichlorodifluoromethane (Freon 12) 5.00 70-13084.64.231,1-Dichloroethane 5.00 70-13083.64.181,1-Dichloroethylene 5.00 70-13081.14.06cis-1,2-Dichloroethylene 5.00 70-13098.44.92Ethanol 5.00 70-13079.23.96Ethyl Acetate 5.00 70-13078.93.94Ethylbenzene 5.00 70-13086.04.304-Ethyltoluene 5.00 70-13073.53.67Heptane 5.00 70-1301055.27Hexane 5.00 70-13086.94.352-Hexanone (MBK) 5.00 70-13086.74.33Isopropanol 1.27 70-13091.21.16Isopropylbenzene (Cumene) 1.14 70-13095.01.08p-Isopropyltoluene (p-Cymene) 5.00 70-13079.73.99Methyl tert-Butyl Ether (MTBE) 5.00 70-13090.94.54Methylene Chloride 5.00 70-13082.74.144-Methyl-2-pentanone (MIBK) 5.00 70-13083.44.17Naphthalene 5.00 70-13092.14.60Propene 1.27 50-15089.71.14Propylbenzene 5.00 70-13094.54.72Tetrachloroethylene 5.00 70-13092.74.64Tetrahydrofuran 5.00 70-13080.84.04Toluene 5.00 70-13079.83.99Trichloroethylene 5.00 70-13099.74.98Trichlorofluoromethane (Freon 11) 5.00 70-13086.24.311,2,4-Trimethylbenzene 5.00 70-13086.64.331,3,5-Trimethylbenzene 1.34 70-13070.30.9422,2,4-Trimethylpentane 10.0 70-13081.68.16m&p-Xylene 5.00 70-13081.24.06o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1108.78 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)1128.96 Page 16 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. V-34 ANALYST Rebecca FaustRLF Kerry K. McGeeKKM Brittany R. FiskBRF Page 17 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) NY,ME,NHtert-Butyl Alcohol (TBA) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NJ,NY,ME,NHIsopropylbenzene (Cumene) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH,VA2,2,4-Trimethylpentane AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 18 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 19 of 22 Page 20 of 22 Page 21 of 22 Page 22 of 22 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 January 24, 2020 Andrew Besu Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 Project Location: Charlotte, NC Client Job Number: Project Number: ALI-002 Laboratory Work Order Number: 20A0921 Enclosed are results of analyses for samples received by the laboratory on January 17, 2020. If you have any questions concerning this report, please feel free to contact me. Sincerely, Kerry K. McGee Project Manager QA Officer Katherine Allen Laboratory Manager Daren Damboragian Page 1 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL SUMMARY 1/24/2020Hart & Hickman - Charlotte, NC 2923 South Tryon Street, Suite 100 Charlotte, NC 28203 ATTN: Andrew Besu ALI-002 20A0921 The results of analyses performed on the following samples submitted to the CON-TEST Analytical Laboratory are found in this report. PROJECT LOCATION: PURCHASE ORDER NUMBER: PROJECT NUMBER: REPORT DATE: WORK ORDER NUMBER: FIELD SAMPLE #LAB ID:MATRIX TESTSAMPLE DESCRIPTION SUB LAB Charlotte, NC ALI-002 Bld-2-SS-MP-1 20A0921-01 Sub Slab EPA TO-15 DUP-01/17/2020 20A0921-02 Sub Slab EPA TO-15 Page 2 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CASE NARRATIVE SUMMARY All reported results are within defined laboratory quality control objectives unless listed below or otherwise qualified in this report. EPA TO-15 Qualifications: Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. Analyte & Samples(s) Qualified: 2,2,4-Trimethylpentane 20A0921-01[Bld-2-SS-MP-1], 20A0921-02[DUP-01/17/2020], B250771-BLK1, B250771-BS1 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. Analyte & Samples(s) Qualified: tert-Butylbenzene S044918-CCV1 Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. Analyte & Samples(s) Qualified: tert-Butyl Alcohol (TBA) 20A0921-01[Bld-2-SS-MP-1], 20A0921-02[DUP-01/17/2020], B250771-BLK1, B250771-BS1, S044918-CCV1 The results of analyses reported only relate to samples submitted to the Con-Test Analytical Laboratory for testing. I certify that the analyses listed above, unless specifically listed as subcontracted, if any, were performed under my direction according to the approved methodologies listed in this document, and that based upon my inquiry of those individuals immediately responsible for obtaining the information, the material contained in this report is, to the best of my knowledge and belief, accurate and complete. Lisa A. Worthington Technical Representative Page 3 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/17/2020 Work Order: 20A0921Sample Description/Location: Field Sample #: Bld-2-SS-MP-1 Sample ID: 20A0921-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.0 Sampled: 1/17/2020 13:11 Canister ID: 2106 Flow Controller ID: 4172 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.8 8.0 1/23/20 23:52 BRFJ164192.8 6.6 Benzene ND 0.20 1/23/20 23:52 BRFND40.640.082 0.26 2-Butanone (MEK)0.76 8.0 1/23/20 23:52 BRFJ2.3 4240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 1/23/20 23:52 BRFV-34 ND 42.50.31 0.93 n-Butylbenzene ND 0.58 1/23/20 23:52 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/23/20 23:52 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/23/20 23:52 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/23/20 23:52 BRFND46.20.14 0.43 Chloroform ND 0.20 1/23/20 23:52 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/23/20 23:52 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/23/20 23:52 BRFND40.690.14 0.49 1,2-Dichlorobenzene 0.40 0.20 1/23/20 23:52 BRF2.4 41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/23/20 23:52 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)ND 0.20 1/23/20 23:52 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/23/20 23:52 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/23/20 23:52 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/23/20 23:52 BRFND40.790.082 0.32 Ethanol 4.0 8.0 1/23/20 23:52 BRFJ7.6 4153.6 6.7 Ethyl Acetate ND 0.20 1/23/20 23:52 BRFND40.720.15 0.54 Ethylbenzene 1.1 0.20 1/23/20 23:52 BRF4.8 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/23/20 23:52 BRFND40.980.12 0.60 Heptane ND 0.20 1/23/20 23:52 BRFND40.820.12 0.48 Hexane ND 8.0 1/23/20 23:52 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/23/20 23:52 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/23/20 23:52 BRFND4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/23/20 23:52 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/23/20 23:52 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/23/20 23:52 BRFND40.720.10 0.36 Methylene Chloride 0.34 2.0 1/23/20 23:52 BRFJ1.2 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/23/20 23:52 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/23/20 23:52 BRFND41.00.15 0.80 Propene ND 8.0 1/23/20 23:52 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/23/20 23:52 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/23/20 23:52 BRFND41.40.11 0.75 Tetrahydrofuran ND 0.20 1/23/20 23:52 BRFND40.590.20 0.59 Toluene ND 0.20 1/23/20 23:52 BRFND40.750.10 0.39 Trichloroethylene ND 0.20 1/23/20 23:52 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.43 0.80 1/23/20 23:52 BRFJ2.4 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/23/20 23:52 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/23/20 23:52 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/23/20 23:52 BRFL-03 ND 42.50.17 0.80 m&p-Xylene 4.6 0.40 1/23/20 23:52 BRF2041.70.23 1.00 o-Xylene 1.3 0.20 1/23/20 23:52 BRF5.5 40.870.12 0.54 Surrogates % Recovery % REC Limits Page 4 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/17/2020 Work Order: 20A0921Sample Description/Location: Field Sample #: Bld-2-SS-MP-1 Sample ID: 20A0921-01 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -6.0 Sampled: 1/17/2020 13:11 Canister ID: 2106 Flow Controller ID: 4172 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)112 1/23/20 23:5270-130 4-Bromofluorobenzene (2)129 1/23/20 23:5270-130 Page 5 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/17/2020 Work Order: 20A0921Sample Description/Location: Field Sample #: DUP-01/17/2020 Sample ID: 20A0921-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 1/17/2020 00:00 Canister ID: 2090 Flow Controller ID: 4172 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Acetone 6.5 8.0 1/24/20 0:32 BRFJ154192.8 6.6 Benzene ND 0.20 1/24/20 0:32 BRFND40.640.082 0.26 2-Butanone (MEK)0.89 8.0 1/24/20 0:32 BRFJ2.6 4240.37 1.1 tert-Butyl Alcohol (TBA)ND 0.82 1/24/20 0:32 BRFV-34 ND 42.50.31 0.93 n-Butylbenzene ND 0.58 1/24/20 0:32 BRFND43.20.13 0.72 sec-Butylbenzene ND 0.46 1/24/20 0:32 BRFND42.50.16 0.86 tert-Butylbenzene ND 0.46 1/24/20 0:32 BRFND42.50.17 0.94 Carbon Disulfide ND 2.0 1/24/20 0:32 BRFND46.20.14 0.43 Chloroform ND 0.20 1/24/20 0:32 BRFND40.980.074 0.36 Chloromethane ND 0.40 1/24/20 0:32 BRFND40.830.14 0.28 Cyclohexane ND 0.20 1/24/20 0:32 BRFND40.690.14 0.49 1,2-Dichlorobenzene 0.44 0.20 1/24/20 0:32 BRF2.6 41.20.096 0.58 1,3-Dichlorobenzene ND 0.20 1/24/20 0:32 BRFND41.20.10 0.62 Dichlorodifluoromethane (Freon 12)ND 0.20 1/24/20 0:32 BRFND40.990.087 0.43 1,1-Dichloroethane ND 0.20 1/24/20 0:32 BRFND40.810.061 0.25 1,1-Dichloroethylene ND 0.20 1/24/20 0:32 BRFND40.790.11 0.43 cis-1,2-Dichloroethylene ND 0.20 1/24/20 0:32 BRFND40.790.082 0.32 Ethanol ND 8.0 1/24/20 0:32 BRFND4153.6 6.7 Ethyl Acetate ND 0.20 1/24/20 0:32 BRFND40.720.15 0.54 Ethylbenzene 1.1 0.20 1/24/20 0:32 BRF4.9 40.870.12 0.50 4-Ethyltoluene ND 0.20 1/24/20 0:32 BRFND40.980.12 0.60 Heptane ND 0.20 1/24/20 0:32 BRFND40.820.12 0.48 Hexane ND 8.0 1/24/20 0:32 BRFND4280.35 1.2 2-Hexanone (MBK)ND 0.20 1/24/20 0:32 BRFND40.820.12 0.48 Isopropanol ND 8.0 1/24/20 0:32 BRFND4200.37 0.90 Isopropylbenzene (Cumene)ND 0.51 1/24/20 0:32 BRFND42.50.16 0.79 p-Isopropyltoluene (p-Cymene)ND 0.46 1/24/20 0:32 BRFND42.50.14 0.75 Methyl tert-Butyl Ether (MTBE)ND 0.20 1/24/20 0:32 BRFND40.720.10 0.36 Methylene Chloride 0.39 2.0 1/24/20 0:32 BRFJ1.3 46.90.24 0.84 4-Methyl-2-pentanone (MIBK)ND 0.20 1/24/20 0:32 BRFND40.820.10 0.43 Naphthalene ND 0.20 1/24/20 0:32 BRFND41.00.15 0.80 Propene ND 8.0 1/24/20 0:32 BRFND4140.37 0.64 Propylbenzene ND 0.51 1/24/20 0:32 BRFND42.50.18 0.87 Tetrachloroethylene ND 0.20 1/24/20 0:32 BRFND41.40.11 0.75 Tetrahydrofuran ND 0.20 1/24/20 0:32 BRFND40.590.20 0.59 Toluene ND 0.20 1/24/20 0:32 BRFND40.750.10 0.39 Trichloroethylene ND 0.20 1/24/20 0:32 BRFND41.10.081 0.43 Trichlorofluoromethane (Freon 11)0.42 0.80 1/24/20 0:32 BRFJ2.4 44.50.15 0.85 1,2,4-Trimethylbenzene ND 0.20 1/24/20 0:32 BRFND40.980.13 0.63 1,3,5-Trimethylbenzene ND 0.20 1/24/20 0:32 BRFND40.980.13 0.62 2,2,4-Trimethylpentane ND 0.54 1/24/20 0:32 BRFL-03 ND 42.50.17 0.80 m&p-Xylene 4.7 0.40 1/24/20 0:32 BRF2141.70.23 1.00 o-Xylene 1.3 0.20 1/24/20 0:32 BRF5.6 40.870.12 0.54 Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (1)112 1/24/20 0:3270-130 Page 6 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYTICAL RESULTS Project Location: Charlotte, NC Date Received: 1/17/2020 Work Order: 20A0921Sample Description/Location: Field Sample #: DUP-01/17/2020 Sample ID: 20A0921-02 Sample Matrix: Sub Slab Initial Vacuum(in Hg): -29 Final Vacuum(in Hg): -5 Receipt Vacuum(in Hg): -5.9 Sampled: 1/17/2020 00:00 Canister ID: 2090 Flow Controller ID: 4172 Sub Description/Location: Canister Size: 1 liter Flow Controller Type: Fixed-Orifice Flow Controller Calibration RPD Pre and Post-Sampling: Sample Type: 10 min RLResults AnalystAnalyzedDilutionFlag/QualRLResultsAnalyte Date/Time EPA TO-15 ppbv ug/m3 MDL MDL Surrogates % Recovery % REC Limits 4-Bromofluorobenzene (2)129 1/24/20 0:3270-130 Page 7 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Sample Extraction Data Prep Method: TO-15 Prep-EPA TO-15 Lab Number [Field ID]Batch Date Pressure Dilution Pre Dilution Pre-Dil Initial mL Pre-Dil Final mL Default Injection mL Actual Injection mL 20A0921-01 [Bld-2-SS-MP-1]B250771 1.5 1 N/A 1000 400 150 01/23/20 20A0921-02 [DUP-01/17/2020]B250771 1.5 1 N/A 1000 400 150 01/23/20 Page 8 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B250771 - TO-15 Prep Blank (B250771-BLK1)Prepared & Analyzed: 01/23/20 1.4NDAcetone 0.035NDBenzene 1.4ND2-Butanone (MEK) 0.14 V-34NDtert-Butyl Alcohol (TBA) 0.10NDn-Butylbenzene 0.080NDsec-Butylbenzene 0.080NDtert-Butylbenzene 0.35NDCarbon Disulfide 0.035NDChloroform 0.070NDChloromethane 0.035NDCyclohexane 0.035ND1,2-Dichlorobenzene 0.035ND1,3-Dichlorobenzene 0.035NDDichlorodifluoromethane (Freon 12) 0.035ND1,1-Dichloroethane 0.035ND1,1-Dichloroethylene 0.035NDcis-1,2-Dichloroethylene 1.4NDEthanol 0.035NDEthyl Acetate 0.035NDEthylbenzene 0.035ND4-Ethyltoluene 0.035NDHeptane 1.4NDHexane 0.035ND2-Hexanone (MBK) 1.4NDIsopropanol 0.089NDIsopropylbenzene (Cumene) 0.080NDp-Isopropyltoluene (p-Cymene) 0.035NDMethyl tert-Butyl Ether (MTBE) 0.35 J0.053Methylene Chloride 0.035ND4-Methyl-2-pentanone (MIBK) 0.035NDNaphthalene 1.4NDPropene 0.089NDPropylbenzene 0.035NDTetrachloroethylene 0.035NDTetrahydrofuran 0.035NDToluene 0.035NDTrichloroethylene 0.14NDTrichlorofluoromethane (Freon 11) 0.035ND1,2,4-Trimethylbenzene 0.035ND1,3,5-Trimethylbenzene 0.094 L-03ND2,2,4-Trimethylpentane 0.070NDm&p-Xylene 0.035NDo-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1068.47 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)1219.69 Page 9 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ug/m3 Spike Level Result Source %REC %REC Limits RPD RPD Limit Flag/Qual Analyte Air Toxics by EPA Compendium Methods - Quality Control QUALITY CONTROL RL ppbv Results RL Results ppbv Batch B250771 - TO-15 Prep LCS (B250771-BS1)Prepared & Analyzed: 01/23/20 5.00 70-1301286.42Acetone 5.00 70-13075.53.77Benzene 5.00 70-1301025.082-Butanone (MEK) 2.06 V-3450-15077.61.60tert-Butyl Alcohol (TBA) 1.14 70-13095.81.09n-Butylbenzene 1.14 70-13099.41.13sec-Butylbenzene 1.14 50-1501041.19tert-Butylbenzene 5.00 70-13097.34.86Carbon Disulfide 5.00 70-13096.34.81Chloroform 5.00 70-13089.54.47Chloromethane 5.00 70-13072.33.61Cyclohexane 5.00 70-1301045.201,2-Dichlorobenzene 5.00 70-1301055.261,3-Dichlorobenzene 5.00 70-1301095.44Dichlorodifluoromethane (Freon 12) 5.00 70-13091.74.591,1-Dichloroethane 5.00 70-13091.34.561,1-Dichloroethylene 5.00 70-13088.04.40cis-1,2-Dichloroethylene 5.00 70-1301145.70Ethanol 5.00 70-13089.64.48Ethyl Acetate 5.00 70-13080.84.04Ethylbenzene 5.00 70-13091.44.574-Ethyltoluene 5.00 70-13071.43.57Heptane 5.00 70-1301125.59Hexane 5.00 70-13084.74.242-Hexanone (MBK) 5.00 70-1301035.15Isopropanol 1.27 70-13098.31.25Isopropylbenzene (Cumene) 1.14 70-1301011.15p-Isopropyltoluene (p-Cymene) 5.00 70-13091.74.58Methyl tert-Butyl Ether (MTBE) 5.00 70-13095.74.78Methylene Chloride 5.00 70-13081.04.054-Methyl-2-pentanone (MIBK) 5.00 70-13090.94.55Naphthalene 5.00 70-13095.84.79Propene 1.27 50-15097.71.24Propylbenzene 5.00 70-1301015.06Tetrachloroethylene 5.00 70-1301045.19Tetrahydrofuran 5.00 70-13081.74.09Toluene 5.00 70-13081.34.06Trichloroethylene 5.00 70-1301216.06Trichlorofluoromethane (Freon 11) 5.00 70-13092.04.601,2,4-Trimethylbenzene 5.00 70-13092.34.611,3,5-Trimethylbenzene 1.34 L-0370-13066.20.8872,2,4-Trimethylpentane * 10.0 70-13083.68.36m&p-Xylene 5.00 70-13082.84.14o-Xylene 8.00 70-130Surrogate: 4-Bromofluorobenzene (1)1118.86 8.00 70-130Surrogate: 4-Bromofluorobenzene (2)1249.92 Page 10 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 Note: Blank Subtraction is not performed unless otherwise noted *QC result is outside of established limits. Wide recovery limits established for difficult compound. Wide RPD limits established for difficult compound. #Data exceeded client recommended or regulatory level RL Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference LCS Laboratory Control Sample Laboratory Control SampleLCS Dup Duplicate Laboratory Control Sample MS Matrix Spike Sample MS Dup Duplicate Matrix Spike Sample REC Recovery QC Quality Control ppbv Parts per billion volume EPA United States Environmental Protection Agency Percent Recovery% REC ND Not Detected Percent recoveries and relative percent differences (RPDs) are determined by the software using values in the calculation which have not been rounded. Not ApplicableN/A DL Detection Limit Not CalculatedNC LFB/LCS Lab Fortified Blank/Lab Control Sample ORP Oxidation-Reduction Potential Not dry weight correctedwet Percent weight% wt KilogramKg Gramg Milligrammg Microgramg Nanogramng LiterL MillilitermL Microliter L Cubic Meterm3 Extractable Petroleum HydrocarbonsEPH Volatile Petroleum HydrocarbonsVPH Air Petroleum HydrocarbonsAPH Flame Ionization DetectorFID Photo Ionization DetectorPID FLAG/QUALIFIER SUMMARY Detected but below the Reporting Limit (lowest calibration standard); therefore, result is an estimated concentration (CLP J-Flag). J Laboratory fortified blank/laboratory control sample recovery is outside of control limits. Reported value for this compound is likely to be biased on the low side. L-03 Continuing calibration verification (CCV) did not meet method specifications and was biased on the high side. Data validation is not affected since sample result was "not detected" for this compound. V-20 Initial calibration verification (ICV) did not meet method specifications and was biased on the low side for this compound. Reported result is estimated. V-34 Page 11 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 ANALYST Raisa A. PetraitisRAP PDF Management StationSTATION Kerry K. McGeeKKM Brittany R. FiskBRF Page 12 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 CertificationsAnalyte CERTIFICATIONS Certified Analyses included in this Report EPA TO-15 in Air AIHA,NY,ME,NHAcetone AIHA,FL,NJ,NY,ME,NH,VABenzene AIHA,FL,NJ,NY,ME,NH,VA2-Butanone (MEK) NY,ME,NHtert-Butyl Alcohol (TBA) AIHA,NJ,NY,ME,NH,VACarbon Disulfide AIHA,FL,NJ,NY,ME,NH,VAChloroform AIHA,FL,NJ,NY,ME,NH,VAChloromethane AIHA,NJ,NY,ME,NH,VACyclohexane AIHA,FL,NJ,NY,ME,NH,VA1,2-Dichlorobenzene AIHA,NJ,NY,ME,NH1,3-Dichlorobenzene AIHA,NY,ME,NHDichlorodifluoromethane (Freon 12) AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethane AIHA,FL,NJ,NY,ME,NH,VA1,1-Dichloroethylene AIHA,FL,NY,ME,NH,VAcis-1,2-Dichloroethylene AIHAEthanol AIHAEthyl Acetate AIHA,FL,NJ,NY,ME,NH,VAEthylbenzene AIHA,NJ4-Ethyltoluene AIHA,NJ,NY,ME,NH,VAHeptane AIHA,FL,NJ,NY,ME,NH,VAHexane AIHA2-Hexanone (MBK) AIHA,NY,ME,NHIsopropanol AIHA,NJ,NY,ME,NHIsopropylbenzene (Cumene) AIHA,FL,NJ,NY,ME,NH,VAMethyl tert-Butyl Ether (MTBE) AIHA,FL,NJ,NY,ME,NH,VAMethylene Chloride AIHA,FL,NJ,NY,ME,NH4-Methyl-2-pentanone (MIBK) NY,ME,NHNaphthalene AIHAPropene AIHA,FL,NJ,NY,ME,NH,VATetrachloroethylene AIHATetrahydrofuran AIHA,FL,NJ,NY,ME,NH,VAToluene AIHA,FL,NJ,NY,ME,NH,VATrichloroethylene AIHA,NY,ME,NHTrichlorofluoromethane (Freon 11) AIHA,NJ,NY,ME,NH1,2,4-Trimethylbenzene AIHA,NJ,NY,ME,NH1,3,5-Trimethylbenzene AIHA,NJ,NY,ME,NH,VA2,2,4-Trimethylpentane AIHA,FL,NJ,NY,ME,NH,VAm&p-Xylene AIHA,FL,NJ,NY,ME,NH,VAo-Xylene Page 13 of 17 39 Spruce Street * East Longmeadow, MA 01028 * FAX 413/525-6405 * TEL. 413/525-2332 The CON-TEST Environmental Laboratory operates under the following certifications and accreditations: Code Description Number Expires 100033AIHA-LAP, LLC - ISO17025:2017AIHA 03/1/2022 M-MA100Massachusetts DEPMA 06/30/2020 PH-0567Connecticut Department of Publilc HealthCT 09/30/2021 10899 NELAPNew York State Department of HealthNY 04/1/2020 2516 NELAPNew Hampshire Environmental LabNH-S 02/5/2020 LAO00112Rhode Island Department of HealthRI 12/30/2020 652North Carolina Div. of Water QualityNC 12/31/2020 MA007 NELAPNew Jersey DEPNJ 06/30/2020 E871027 NELAPFlorida Department of HealthFL 06/30/2020 LL015036Vermont Department of Health Lead LaboratoryVT 07/30/2020 2011028State of MaineME 06/9/2021 460217Commonwealth of VirginiaVA 12/14/2020 2557 NELAPNew Hampshire Environmental LabNH-P 09/6/2020 VT-255716Vermont Department of Health Drinking WaterVT-DW 06/12/2020 25703North Carolina Department of HealthNC-DW 07/31/2020 68-05812Commonwealth of Pennsylvania DEPPA 06/30/2020 Page 14 of 17 Page 15 of 17 Page 16 of 17 Page 17 of 17 Appendix E Sub-Slab and Soil Gas Risk Calculator Summary Pages Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-MP-1 / DUP-1/17/2020 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table 2/19/2020 Prepared By:Natasha Pacifico Hart & Hickman, PC Wes Barfield North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual) 1.0E-06 Target Cancer Risk (cumulative) 1.0E-04 Target Hazard Index (individual) 2.0E-01 Target Hazard Index (cumulative) 1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg) 15 Exposure Duration (ED) (yr) 6 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day) 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d) 0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 20 Exposure Frequency (EF) (d/yr) 350 Exposure Time (ET) (hr) 24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Exposure Duration (ED) (yr) 25 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day) 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d) 0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day) 1 Lifetime (LT) (years)70 Body Weight (BW) (kg) 80 Working Weeks (EW) (wk/yr) 50 Exposure Duration (ED) (yr) 1 Exposure Frequency (EF) (d/yr) 250 Exposure Time (ET) (hr) 8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day) 330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr) 365 NA 365 Body Weight (BW) (kg) 15 NA 15 Exposure Duration 0-2 (ED) (yr) 2 NA 2 Exposure Duration 2-6 (ED) (yr) 4 NA 4 Exposure Frequency (EF) (d/yr) 195 NA 195 Exposure Time (ET) (hr) 2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day) 200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr) 0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day) 100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr) 0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)22 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: December 2019Basis: November 2019 EPA RSL TableSite ID: 2103217060Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020Description of Exposure Point Concentration Selection:Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Notes: CAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion16 67-64-1 Acetoneug/m32.695-50-1Dichlorobenzene, 1,2-ug/m34.9100-41-4Ethylbenzeneug/m32.678-93-3Methyl Ethyl Ketone (2-Butanone)ug/m31.375-09-2Methylene Chlorideug/m32.475-69-4Trichlorofluoromethaneug/m321108-38-3Xylene, m-ug/m35.695-47-6Xylene, o-ug/m3Input Form 2DSoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 16 0.48 - 6.5E+03 1.5E-05 95-50-1 Dichlorobenzene, 1,2- 2.6 0.078 - 4.2E+01 3.7E-04 100-41-4 Ethylbenzene 4.9 0.147 1.1E+00 2.1E+02 1.3E-07 1.4E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.6 0.078 - 1.0E+03 1.5E-0575-09-2 Methylene Chloride 1.3 0.039 1.0E+02 1.3E+02 3.8E-10 6.2E-0575-69-4 Trichlorofluoromethane 2.4 0.072 - - 108-38-3 Xylene, m- 21 0.63 - 2.1E+01 6.0E-03 95-47-6 Xylene, o- 5.6 0.168 - 2.1E+01 1.6E-03 Cumulative: 1.3E-07 8.3E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-MP-1 / DUP-1/17/2020 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.3E-07 8.3E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-SS-MP-2 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table Prepared By:Shannon Switch Hart & Hickman, PC North Carolina DEQ Risk Calculator Wes Barfield 2/19/2020 Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-2 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-SS-MP-2 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-SS-MP-2 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-2 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 21 67-64-1 Acetone ug/m3 1.8 75-71-8 Dichlorodifluoromethane ug/m3 2.5 100-41-4 Ethylbenzene ug/m3 12 109-99-9 ~Tetrahydrofuran ug/m3 34 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.6 75-69-4 Trichlorofluoromethane ug/m3 9.1 108-38-3 Xylene, m-ug/m3 1.9 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-2 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 21 0.63 -6.5E+03 1.9E-05 75-71-8 Dichlorodifluoromethane 1.8 0.054 -2.1E+01 5.2E-04 100-41-4 Ethylbenzene 2.5 0.075 1.1E+00 2.1E+02 6.7E-08 7.2E-05 109-99-9 ~Tetrahydrofuran 12 0.36 -4.2E+02 1.7E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)34 1.02 -1.0E+03 2.0E-04 75-69-4 Trichlorofluoromethane 1.6 0.048 -- 108-38-3 Xylene, m-9.1 0.273 -2.1E+01 2.6E-03 95-47-6 Xylene, o-1.9 0.057 -2.1E+01 5.5E-04 Cumulative:6.7E-08 4.1E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-2 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 6.7E-08 4.1E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-SS-MP-3 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table Prepared By:Shannon Switch Hart & Hickman, PC North Carolina DEQ Risk Calculator Wes Barfield 2/19/2020 Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-3 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-SS-MP-3 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-SS-MP-3 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-3 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 29 67-64-1 Acetone ug/m3 1.9 75-71-8 Dichlorodifluoromethane ug/m3 2.6 141-78-6 Ethyl Acetate ug/m3 0.99 100-41-4 Ethylbenzene ug/m3 14 109-99-9 ~Tetrahydrofuran ug/m3 2.3 67-63-0 Isopropanol ug/m3 5.5 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 3 108-88-3 Toluene ug/m3 1.3 75-69-4 Trichlorofluoromethane ug/m3 3.4 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-3 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 29 0.87 -6.5E+03 2.7E-05 75-71-8 Dichlorodifluoromethane 1.9 0.057 -2.1E+01 5.5E-04 141-78-6 Ethyl Acetate 2.6 0.078 -1.5E+01 1.1E-03 100-41-4 Ethylbenzene 0.99 0.0297 1.1E+00 2.1E+02 2.6E-08 2.8E-05 109-99-9 ~Tetrahydrofuran 14 0.42 -4.2E+02 2.0E-04 67-63-0 Isopropanol 2.3 0.069 -4.2E+01 3.3E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)5.5 0.165 -1.0E+03 3.2E-05 108-88-3 Toluene 3 0.09 -1.0E+03 1.7E-05 75-69-4 Trichlorofluoromethane 1.3 0.039 -- 108-38-3 Xylene, m-3.4 0.102 -2.1E+01 9.8E-04 Cumulative:2.6E-08 3.2E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-3 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.6E-08 3.2E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-SS-MP-4 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table Prepared By:Shannon Switch Hart & Hickman, PC North Carolina DEQ Risk Calculator 2/19/2020 Wes Barfield Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-4 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-SS-MP-4 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-SS-MP-4 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-4 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 48 67-64-1 Acetone ug/m3 1.7 75-71-8 Dichlorodifluoromethane ug/m3 95 109-99-9 ~Tetrahydrofuran ug/m3 1.5 67-63-0 Isopropanol ug/m3 7.2 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 3.1 127-18-4 Tetrachloroethylene ug/m3 2 108-88-3 Toluene ug/m3 1.3 75-69-4 Trichlorofluoromethane ug/m3 2.6 108-38-3 Xylene, m-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-4 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 48 1.44 -6.5E+03 4.5E-05 75-71-8 Dichlorodifluoromethane 1.7 0.051 -2.1E+01 4.9E-04 109-99-9 ~Tetrahydrofuran 95 2.85 -4.2E+02 1.4E-03 67-63-0 Isopropanol 1.5 0.045 -4.2E+01 2.2E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)7.2 0.216 -1.0E+03 4.1E-05 127-18-4 Tetrachloroethylene 3.1 0.093 1.1E+01 8.3E+00 8.6E-09 2.2E-03 108-88-3 Toluene 2 0.06 -1.0E+03 1.2E-05 75-69-4 Trichlorofluoromethane 1.3 0.039 -- 108-38-3 Xylene, m-2.6 0.078 -2.1E+01 7.5E-04 Cumulative:8.6E-09 5.1E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-4 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 8.6E-09 5.1E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-SS-MP-5 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table Prepared By: Wes Barfield Hart & Hickman, PC North Carolina DEQ Risk Calculator 2/19/2020 Shannon Switch Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-5 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-SS-MP-5 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-SS-MP-5 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-5 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 70 67-64-1 Acetone ug/m3 2.3 98-06-6 Butylbenzene, tert-ug/m3 1.2 74-87-3 Chloromethane ug/m3 2 75-71-8 Dichlorodifluoromethane ug/m3 2.1 141-78-6 Ethyl Acetate ug/m3 1 100-41-4 Ethylbenzene ug/m3 3.2 109-99-9 ~Tetrahydrofuran ug/m3 5.3 67-63-0 Isopropanol ug/m3 4.9 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.97 75-09-2 Methylene Chloride ug/m3 4 108-88-3 Toluene ug/m3 1.2 75-69-4 Trichlorofluoromethane ug/m3 3.5 108-38-3 Xylene, m-ug/m3 0.94 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-5 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 70 2.1 -6.5E+03 6.5E-05 98-06-6 Butylbenzene, tert-2.3 0.069 -- 74-87-3 Chloromethane 1.2 0.036 -1.9E+01 3.8E-04 75-71-8 Dichlorodifluoromethane 2 0.06 -2.1E+01 5.8E-04 141-78-6 Ethyl Acetate 2.1 0.063 -1.5E+01 8.6E-04 100-41-4 Ethylbenzene 1 0.03 1.1E+00 2.1E+02 2.7E-08 2.9E-05 109-99-9 ~Tetrahydrofuran 3.2 0.096 -4.2E+02 4.6E-05 67-63-0 Isopropanol 5.3 0.159 -4.2E+01 7.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)4.9 0.147 -1.0E+03 2.8E-05 75-09-2 Methylene Chloride 0.97 0.0291 1.0E+02 1.3E+02 2.9E-10 4.7E-05 108-88-3 Toluene 4 0.12 -1.0E+03 2.3E-05 75-69-4 Trichlorofluoromethane 1.2 0.036 -- 108-38-3 Xylene, m-3.5 0.105 -2.1E+01 1.0E-03 95-47-6 Xylene, o-0.94 0.0282 -2.1E+01 2.7E-04 Cumulative:2.7E-08 4.1E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-5 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 2.7E-08 4.1E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: Bld-2-SS-MP-6 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table Prepared By:Shannon Switch Hart & Hickman, PC North Carolina DEQ Risk Calculator 2-19-2020 Wes Barfield Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-6 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: Bld-2-SS-MP-6 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: Bld-2-SS-MP-6 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-6 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 17 67-64-1 Acetone ug/m3 2.1 75-71-8 Dichlorodifluoromethane ug/m3 1.9 156-59-2 Dichloroethylene, 1,2-cis-ug/m3 2.3 100-41-4 Ethylbenzene ug/m3 3.3 67-63-0 Isopropanol ug/m3 4 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 0.88 75-09-2 Methylene Chloride ug/m3 39 127-18-4 Tetrachloroethylene ug/m3 3.8 108-88-3 Toluene ug/m3 14 79-01-6 Trichloroethylene ug/m3 1.9 75-69-4 Trichlorofluoromethane ug/m3 8.7 108-38-3 Xylene, m-ug/m3 2 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-6 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non-Carcinogenic Hazard Quotient 67-64-1 Acetone 17 0.51 -6.5E+03 1.6E-05 75-71-8 Dichlorodifluoromethane 2.1 0.063 -2.1E+01 6.0E-04 156-59-2 Dichloroethylene, 1,2-cis-1.9 0.057 -- 100-41-4 Ethylbenzene 2.3 0.069 1.1E+00 2.1E+02 6.1E-08 6.6E-05 67-63-0 Isopropanol 3.3 0.099 -4.2E+01 4.7E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)4 0.12 -1.0E+03 2.3E-05 75-09-2 Methylene Chloride 0.88 0.0264 1.0E+02 1.3E+02 2.6E-10 4.2E-05 127-18-4 Tetrachloroethylene 39 1.17 1.1E+01 8.3E+00 1.1E-07 2.8E-02 108-88-3 Toluene 3.8 0.114 -1.0E+03 2.2E-05 79-01-6 Trichloroethylene 14 0.42 4.8E-01 4.2E-01 8.8E-07 2.0E-0175-69-4 Trichlorofluoromethane 1.9 0.057 -- 108-38-3 Xylene, m-8.7 0.261 -2.1E+01 2.5E-03 95-47-6 Xylene, o-2 0.06 -2.1E+01 5.8E-04 Cumulative:1.0E-06 2.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: Bld-2-SS-MP-6 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.0E-06 2.3E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 2/19/2020 Prepared By:Natasha Pacifico Hart & Hickman, PC Wes Barfield CGH-B-SS-MP-1 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-B-SS-MP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 1 70 80 330 1 250 8 3527 0.3 50 100 19652 2.5 0.71 1 20 350 24 6032 0.07 0.54 1 70 80 2373 0.2 200 6365 0.78 Input Form 1B Exposure Unit ID: CGH-B-SS-MP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: CGH-B-SS-MP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-B-SS-MP-1 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 38 67-64-1 Acetone ug/m3 32 109-99-9 ~Tetrahydrofuran ug/m3 36 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 4.4 75-09-2 Methylene Chloride ug/m3 1.2 108-88-3 Toluene ug/m3 1.7 75-69-4 Trichlorofluoromethane ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-B-SS-MP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 38 1.14 -6.5E+03 3.5E-05 109-99-9 ~Tetrahydrofuran 32 0.96 -4.2E+02 4.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)36 1.08 -1.0E+03 2.1E-04 75-09-2 Methylene Chloride 4.4 0.132 1.0E+02 1.3E+02 1.3E-09 2.1E-04 108-88-3 Toluene 1.2 0.036 -1.0E+03 6.9E-06 75-69-4 Trichlorofluoromethane 1.7 0.051 -- Cumulative:1.3E-09 9.2E-04 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-B-SS-MP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.3E-09 9.2E-04 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: CGH-C-SS-MP-1 / DUP-12/30/2019 North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table 3/19/2020 Prepared By:Andrew Besu Hart & Hickman, PC Trinh DeSa, PE North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-C-SS-MP-1 / DUP-12/30/2019 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Complete Exposure Pathways Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-C-SS-MP-1 / DUP-12/30/2019 Note: Risk output will only be calculated for complete exposure pathways. Receptor Pathway Check box if pathway complete Soil Groundwater Use Soil Groundwater Use Construction Worker Soil Soil Surface Water Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Groundwater to Indoor Air Soil Gas to Indoor Air Indoor Air Source Soil Source Groundwater Source Soil Source Groundwater Resident Non-Residential Worker CONTAMINANT MIGRATION PATHWAYS Groundwater Surface Water Input Form 1A VAPOR INTRUSION PATHWAYS DIRECT CONTACT SOIL AND WATER PATHWAYS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-C-SS-MP-1 / DUP-12/30/2019 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 400 67-64-1 Acetone ug/m3 0.65 71-43-2 Benzene ug/m3 21 104-51-8 Butylbenzene, n-ug/m3 13 135-98-8 Butylbenzene, sec-ug/m3 4.6 75-15-0 Carbon Disulfide ug/m3 1.6 67-66-3 Chloroform ug/m3 7.2 98-82-8 Cumene ug/m3 8.7 110-82-7 Cyclohexane ug/m3 23 100-41-4 Ethylbenzene ug/m3 1800 109-99-9 ~Tetrahydrofuran ug/m3 19 142-82-5 Heptane, N-ug/m3 6.4 110-54-3 Hexane, N-ug/m3 770 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.4 75-09-2 Methylene Chloride ug/m3 19 103-65-1 Propyl benzene ug/m3 3.9 127-18-4 Tetrachloroethylene ug/m3 10 108-88-3 Toluene ug/m3 2.2 75-69-4 Trichlorofluoromethane ug/m3 99 95-63-6 Trimethylbenzene, 1,2,4-ug/m3 37 108-67-8 Trimethylbenzene, 1,3,5-ug/m3 7.7 25167-70-8 Trimethylpentene, 2,4,4-ug/m3 57 108-38-3 Xylene, m-ug/m3 37 95-47-6 Xylene, o-ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-C-SS-MP-1 / DUP-12/30/2019 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 1.1E-06 1.3E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-C-SS-MP-1 / DUP-12/30/2019 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 400 12 -6.5E+03 3.7E-04 71-43-2 Benzene 0.65 0.0195 3.6E-01 6.3E+00 5.4E-08 6.2E-04 104-51-8 Butylbenzene, n-21 0.63 -- 135-98-8 Butylbenzene, sec-13 0.39 -- 75-15-0 Carbon Disulfide 4.6 0.138 -1.5E+02 1.9E-04 67-66-3 Chloroform 1.6 0.048 1.2E-01 2.0E+01 3.9E-07 4.7E-04 98-82-8 Cumene 7.2 0.216 -8.3E+01 5.2E-04 110-82-7 Cyclohexane 8.7 0.261 -1.3E+03 4.2E-05 100-41-4 Ethylbenzene 23 0.69 1.1E+00 2.1E+02 6.1E-07 6.6E-04 109-99-9 ~Tetrahydrofuran 1800 54 -4.2E+02 2.6E-02 142-82-5 Heptane, N-19 0.57 -8.3E+01 1.4E-03 110-54-3 Hexane, N-6.4 0.192 -1.5E+02 2.6E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)770 23.1 -1.0E+03 4.4E-03 75-09-2 Methylene Chloride 1.4 0.042 1.0E+02 1.3E+02 4.1E-10 6.7E-05 103-65-1 Propyl benzene 19 0.57 -2.1E+02 5.5E-04 127-18-4 Tetrachloroethylene 3.9 0.117 1.1E+01 8.3E+00 1.1E-08 2.8E-03 108-88-3 Toluene 10 0.3 -1.0E+03 5.8E-05 75-69-4 Trichlorofluoromethane 2.2 0.066 -- 95-63-6 Trimethylbenzene, 1,2,4-99 2.97 -1.3E+01 4.7E-02 108-67-8 Trimethylbenzene, 1,3,5-37 1.11 -1.3E+01 1.8E-02 25167-70-8 Trimethylpentene, 2,4,4-7.7 0.231 -- 108-38-3 Xylene, m-57 1.71 -2.1E+01 1.6E-02 95-47-6 Xylene, o-37 1.11 -2.1E+01 1.1E-02 Cumulative:1.1E-06 1.3E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID:CGH-D-SS-MP-1 Submittal Date: Reviewed By: North Carolina Department of Environmental Quality Risk Calculator Radiator Specialty Tract E Charlotte, NC Brownfields 2103217060 December 2019 November 2019 EPA RSL Table 2/19/2020 Prepared By:Natasha Pacifico Hart & Hickman, PC Wes Barfield North Carolina DEQ Risk Calculator Table of Contents Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-D-SS-MP-1 Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Soil Exposure Point Concentration Table Input Form 2B Groundwater Exposure Point Concentration Table Input Form 2C Surface Water Exposure Point Concentration Table Input Form 2D Soil Gas Exposure Point Concentration Table Input Form 2E Indoor Air Exposure Point Concentration Table Output Form 1A Risk for Individual Pathways Output Form 1B Sitewide Risk Output Form 2A Resident Soil Output Form 2B Resident Groundwater Use Output Form 2C Non-Residential Worker Soil Output Form 2D Non-Residential Worker Groundwater Use Output Form 2E Construction Worker Soil Output Form 2F Recreator/Trespasser Soil Output Form 2G Recreator/Trespasser Surface Water Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil to Groundwater - Forward Mode Output Form 4B Groundwater to Groundwater - Forward Mode Output Form 4C Soil to Surface Water - Forward Mode Output Form 4D Groundwater to Surface Water - Forward Mode Output Form 4E Soil to Groundwater - Backward Mode Output Form 4F Groundwater to Groundwater - Backward Mode Output Form 4G Soil to Surface Water - Backward Mode Output Form 4H Groundwater to Surface Water - Backward Mode Output Section 4 - Contaminant Migration to Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Direct Contact Soil and Groundwater Calculators North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Target Cancer Risk (individual)1.0E-06 Target Cancer Risk (cumulative)1.0E-04 Target Hazard Index (individual)2.0E-01 Target Hazard Index (cumulative)1.0E+00 Lifetime (LT) (years)70 Body Weight (BW) (kg)15 Exposure Duration (ED) (yr)6 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 Soil Adherence Factor (AF) (mg/cm2)0.2 Soil Ingestion Rate (IRS) (mg/day)200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 Water Ingestion Rate (IRW) (L/d)0.78 Water Exposure Time (ETevent) (hr/event)0.54 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)20 Exposure Frequency (EF) (d/yr)350 Exposure Time (ET) (hr)24 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 Soil Adherence Factor (AF) (mg/cm2)0.07 Soil Ingestion Rate (IRS) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)2.5 Water Exposure Time (ETevent) (hr/event)0.71 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Exposure Duration (ED) (yr)25 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.12 Soil Ingestion Rate (IR) (mg/day)100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 Water Ingestion Rate (IRW) (L/d)0.83 Water Exposure Time (ETevent) (hr/event)0.67 Water Event Frequency (EV) (events/day)1 Lifetime (LT) (years)70 Body Weight (BW) (kg)80 Working Weeks (EW) (wk/yr)50 Exposure Duration (ED) (yr)1 Exposure Frequency (EF) (d/yr)250 Exposure Time (ET) (hr)8 Skin Surface Area - Soil Exposure (SAs) (cm2)3527 Soil Adherence Factor (AF) (mg/cm2)0.3 Soil Ingestion Rate (IR) (mg/day)330 Non-Residential Worker Construction Worker 70 80 25 250 8 3527 0.12 100 19652 0.83 0.67 Input Form 1B Exposure Unit ID: CGH-D-SS-MP-1 Residential Child General Residential Adult Default Value 1.0E-06 1.0E-04 2.0E-01 1.0E+00 70 15 6 350 24 2373 0.2 200 6365 0.78 0.54 1 70 80 20 350 24 6032 0.07 100 19652 2.5 0.71 1 1 70 80 330 1 250 8 3527 0.3 50 North Carolina DEQ Risk Calculator Exposure Factors and Target Risks Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Parameter Site Specific Value Justification Input Form 1B Exposure Unit ID: CGH-D-SS-MP-1 Default Value Recreator Trespasser Lifetime (LT) (years)70 NA 70 Averaging Time (AT) (days/yr)365 NA 365 Body Weight (BW) (kg)15 NA 15 Exposure Duration 0-2 (ED) (yr)2 NA 2 Exposure Duration 2-6 (ED) (yr)4 NA 4 Exposure Frequency (EF) (d/yr)195 NA 195 Exposure Time (ET) (hr)2 NA 2 Skin Surface Area - Soil Exposure (SAs) (cm2)2373 NA 2373 Soil Adherence Factor (AF) (mg/cm2)0.2 NA 0.2 Soil Ingestion Rate (IRS) (mg/day)200 NA 200 Skin Surface Area - Water Exposure (SAw) (cm2)6365 NA 6365 Water Ingestion Rate (IRW) (L/hr)0.124 NA 0.124 Water Exposure Time (ETevent) (hr/event)2 NA 2 Water Event Frequency (EV) (events/day)1 NA 1 Recreator Trespasser Lifetime (LT) (years)70 70 70 Body Weight (BW) (kg)80 45 80 Exposure Duration 6-16 (ED) (yr)10 10 10 Exposure Duration 16-26 (ED) (yr)10 0 10 Exposure Frequency (EF) (d/yr)195 90 195 Exposure Time (ET) (hr)2 2 2 Skin Surface Area - Soil Exposure (SAs) (cm2)6032 6032 6032 Soil Adherence Factor (AF) (mg/cm2)0.07 0.2 0.07 Soil Ingestion Rate (IRS) (mg/day)100 200 100 Skin Surface Area - Water Exposure (SAw) (cm2)19652 19652 19652 Water Ingestion Rate (IRW) (L/hr)0.0985 0.071 0.0985 Water Exposure Time (ETevent) (hr/event)2 2 2 Water Event Frequency (EV) (events/day)1 1 1 User Defined Child User Defined Adult North Carolina DEQ Risk Calculator Exposure Point Concentrations Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-D-SS-MP-1 Description of Exposure Point Concentration Selection: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. Exposure Point Concentration (ug/m3) Notes:CAS Number Chemical Minimum Concentration (Qualifier) Maximum Concentration (Qualifier) Units Location of Maximum Concentration Detection Frequency Range of Detection Limits Concentration Used for Screening Background Value Screening Toxicity Value (Screening Level) (n/c) Potential ARAR/TBC Value Potential ARAR/TBC Source COPC Flag (Y/N) Rationale for Selection or Deletion 50 67-64-1 Acetone ug/m3 2.5 75-71-8 Dichlorodifluoromethane ug/m3 69 109-99-9 ~Tetrahydrofuran ug/m3 2.2 67-63-0 Isopropanol ug/m3 8.1 78-93-3 Methyl Ethyl Ketone (2-Butanone)ug/m3 1.6 75-69-4 Trichlorofluoromethane ug/m3 Input Form 2D Soil Gas Exposure Point Concentration Table North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-D-SS-MP-1 CAS #Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 50 1.5 -6.5E+03 4.6E-05 75-71-8 Dichlorodifluoromethane 2.5 0.075 -2.1E+01 7.2E-04 109-99-9 ~Tetrahydrofuran 69 2.07 -4.2E+02 9.9E-04 67-63-0 Isopropanol 2.2 0.066 -4.2E+01 3.2E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone)8.1 0.243 -1.0E+03 4.7E-05 75-69-4 Trichlorofluoromethane 1.6 0.048 -- Cumulative:0.0E+00 2.1E-03 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator Risk for Individual Pathways Output Form 1A Version Date: December 2019 Basis: November 2019 EPA RSL Table Site ID: 2103217060 Exposure Unit ID: CGH-D-SS-MP-1 Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil NC NC NC Groundwater Use*NC NC NC Soil NC NC NC Groundwater Use*NC NC NC Construction Worker Soil NC NC NC Soil NC NC NC Surface Water*NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 0.0E+00 2.1E-03 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air NC NC NC Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NC 3. NM = Not Modeled 4. NC = Pathway not complete DIRECT CONTACT SOIL AND WATER CALCULATORS Resident Non-Residential Worker Recreator/Trespasser 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Surface Water Exceedence of 2B at Receptor? Exceedence of 2B at Receptor? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target Receptor Concentrations Exceeded? Groundwater Exceedence of 2L at Receptor? Exceedence of 2L at Receptor? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator