The URL can be used to link to this page

Home My WebLink AboutMO-3655_9362_CA_MRP_20200319_Semi-Annual Monitoring ReportMONITORING REPORT CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, CABARRUS COUNTY, NORTH CAROLINA GROUNDWATER INCIDENT NO.9362 Shield Project No. 1090032 Period: February -March 2020 Responsible Party: Security Oil Company, Inc. PO Box 5028 Concord, NC 28027 Contact: Dale Carpenter (704)786-7235 Site Risk Classification: High (165D) Land Use Category: Commercial/Residential Site Latitude: 35' 26' 26" North Site Longitude: 80' 43' 40" West j� Z__ Kevin P. Stachura Staff Geologist Consultant: Shield Engineering, Inc. 4301 Taggart Creek Road Charlotte, NC 28208 Contact: Kevin P. Stachura (704) 394-6913 Release Discovered: December 1994 Quantity Released: Unknown Property Owner: Prime Business LLC A NC 1534 Copperplate Road Charlotte, NC 28262 Contact: Shailesh Panara (980) 722-3751 Suspected Release Source(s): One 3,000-gallon gasoline UST Release Cause: Possible spillage/leak from UST March 19, 2020 Thomas Witner, L.G. Principal NC License #916 �r•'�tH CARp� SEAL. 916 HHIELD ENGINEERING. INC ••..qS W. W �.. TABLE OF CONTENTS N,iac No, 1.0 DISCUSSION OF SAMPLING ACTIVITIES... ........ -- ................................................ 1 2.0 CONCLUSIONS AND RECOMMENDATIONS...........................................................4 3.0 STATEMENTS AND CERTIFICATION ... ................................................ ........ .......—...5 4.0 LIMITATIONS .............. ............................................................ --- ................ ,.............. 6 Figure 1: Site Location Map Figure 2: Site Map Figure 3: 1,500' Radius Map Figure 4: Groundwater Elevation Contour Map Figure 5: Benzene Isoconcentration Map Figure 6: MTBE Isoconcentration Map Figure 7: Naphthalene Isoconcentration Map TABLES Table 1: Summary of Water Supply Well and Receptor Information Table 2: Summary of Well Construction and Historical Groundwater Elevation Data Table 3: Summary of Groundwater Analytical Results (February 04, 2020) Table 4: Summary of Historical Groundwater Analytical Results GRAPHS Graph(s): Concentration vs. Time/ Hydrograph APPENDICES Appendix A: Calibration and Field Measurement Log Appendix B: Laboratory Report — Groundwater Samples HAProjecls\2009\1090032-01 Carl's Country Store\Reports\MR 3-2020\MO-3655_9362_CA_MRP_20200331_Semi-Annual Monitoring Report.doc Carl's Country Store Concord, Cabarrus County, North Carolina GWI#: 9362 1.0 DISCUSSION OF SAMPLING ACTIVITIES 1.1 Site Location Refer to Figure(s): Figure 1 and Figure 2 1.2 Summary of Analytical Results and Free Product Thickness(s): 1.2.1 Date(s) of Sampling Event: February 4, 2020 1.2.2 Existing Area Receptors: Monitoring Report March 19, 2020 Page 1 During the April 2009 sampling event, Shield personnel were informed by the store attendant that water supply well WSW-1 had been abandoned. Also, during the February 2009 sampling event, supply wells WSW-3 and WSW-4 were reported by community residents as being interconnected and serving the Hillsdell Drive and Odell Circle community. A receptor survey update was performed by Shield personnel on March 14, 2019 in order to review the status of known receptors and present information on new receptors, if applicable. Water supply wells WSW-2, WSW-8, WSW-13 and WSW- 18 were not observed and appear to have been destroyed or abandoned due to parcel consolidation and redevelopment. Water supply well WSW-15 was abandoned as reported by the property owner. An additional receptor, WSW-24, was added as the property owner reported that there is a well in use on that property. Refer to the following Table and Figure for additional information and locations of area receptors within a 1,500-foot radius of the site. Refer to Table: Table 1 Refer to Figure: Figure 3 1.2.3 Groundwater Elevation Data: Historically, groundwater flows generally towards the west with a groundwater elevation high around monitoring well MW-6. Based on the groundwater elevations determined during the February 2020 sampling event, the groundwater flow direction is generally towards the west from monitoring well MW-6 with a slight convergence around MW-5. Groundwater elevation data from the February 4, 2020 sampling event is included in the following Table and Figure: Refer to Table: Table 2 Refer to Figure: Figure 4 Carl's Country Store Concord, Cabarrus County, North Carolina G WI#: 9362 1.2.4 Free Product: Free product detected during this reporting period?: No Free product plume size and location: Not Applicable (N/A) Free product recovered during this period: N/A 1.2.5 Field Measurements: Monitoring Report March 19, 2020 Page 2 Field measurement parameters were collected from each sampled monitoring well at the time of sample collection using a YSI Pro Plus meter. Parameters recorded include dissolved oxygen (DO), pH, specific conductivity (us/cm), temperature (T), and oxidation reduction potential [ORP (mVolts)]. Refer to Appendix: Appendix A Carl's Country Store Monitoring Report Concord, Cabarrus County, North Carolina March 19, 2020 GWI#; 9362 Page 3 1.2.5 Groundwater Analytical Results: • Sampled points and analytical methods: The following monitoring wells and other points were sampled during this reporting period. Sampled Points and Analytical Methods for this Reporting Period Based on CAP and/or NORR Related Pre -Approval Task Authorization Sampling_Reg uirements Type Points Sampled during this Reporting Analytical Method(s) Period 12* . EPA Method 6200B Monitoring Wells (MW-1, MW-2, MW-4 through MW-7, (including MTBE, IPE, & MW-9, MW-10, DMW-1, and DMW-3 EDB, 5 Oxygenates, Ethanol) through DMW-5) Water Supply Wells 1 • EPA Method 6200B (WSW-9) * Per the North Carolina Department of Environmental Quality (NCDEQ) pre -approval. • Laboratory Used: Pace Analytical Services, Inc., Huntersville, NC • Current groundwater analytical data: Refer to the following Table, Figures, and Appendix for current groundwater analytical data. Refer to Table: Table 3 Refer to Figure: Figure 5 through Figure 7 Refer to Appendix: Appendix B • Historical groundwater analytical data: Refer to the following Table and Graphs for historical groundwater analytical data. Refer to Table: Table 4 Refer to Graph(s): Concentration vs. Time/ Hydrograph Carl's Country Store Concord, Cabarrus County, North Carolina GWl#; 9362 Predictive Rate of Contaminant Transport: Monitoring Report March 19, 2020 Page 4 Refer to the 1993 Integrity Environmental Consultants Comprehensive Site Assessment and the Corrective Action Plan (CAP) dated October 19, 2012 completed by Shield Engineering, Inc. Contaminant transport is typically in the same direction as groundwater flow, but with a slower velocity. Refer to the following Tables and Figures: Refer to Table(s): Table 2, Table 3, and Table 4 Refer to Figure(s): Figure 4 through Figure 7 1.2.6 Other Field Data Collected: 0 No other field data was collected. 2.0 CONCLUSIONS AND RECOMMENDATIONS 2.1 Conclusions: Dissolved phase petroleum constituent compounds were detected in concentrations exceeding 2L Standards and/or Interim Maximum Allowable Concentrations (IMACs) in MW-2, MW-4, MW-5, MW-6, MW-10, DMW-1, DMW-3, DMW-4 and DMW-5 during this reporting period. Overall, constituent of concern (COC) concentrations in monitoring wells MW-2, MW-4, MW-5, MW-6, MW-10, DMW-1, DMW-3, and DMW-5 have generally increased since the previous sampling event in August 2019. COC concentrations have decreased in monitoring well DMW-4 since the previous sampling event in August 2019. In water supply well WSW-9, no COCs were reported above the laboratory detection limits. 2.2 Recommendations: Continue sampling of groundwater on a semi-annual basis in accordance with the December 5, 2013 Notice of Regulatory Requirements. The next semi-annual sampling event will be in August 2020. Carl's County Store Monitoring Report Concord, Cabarrus County, North Carolina March 19, 2020 G W UP; 9362 Page 5 3.0 STATEMENTS & CERTIFICATION Enter the date the monitoring report was due. 3/31/2020. Will this report be submitted YES after the established due date? 2 Was `—any information from the above template missing from this report? YES NO IF the answer to question #1 or# 2 is "YES", please provide additional information in this cell to explain what was missing and why. If applicable, will any of the proposed attenuation milestones under the schedule YE approved in the Corrective Action Plan not be met? (within a reasonable margin of error) IF the answer to question #3 is "NO", skip to the certification under #6 below. IF the answer to question 43 is "YES", please generally describe in this cell the possible reason(s) and outline proposed remedies. (This should be described in more detail in the report text above.) Does any known or suspected source zone soil contamination or free product remain YES NO outside of the assessed area that could be inhibiting natural attenuation? Has there been an unexpected increase in contaminant mass sufficient to suggest a YES NO potential new release from a separate onsite or offsite source? IF the answer to either question #4 or #5 is "YES", generally describe in this cell any actions recommended to further assess or clean up this known or suspected source. (This should be described in more detail in the report text above.) Certification: I,111olnax Wisner, a Professional Geologist for Shield Engineering, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. _;, , ;;d�� w � � a SC Al_ r 16 N (Affix Seal and Signature) Shield Engineering, Inc. is licensed to practice geology and engineering in North Carolina. The certification number of the company or corporation is C-170(Geology) and F-0856 (Engineering), Carl's Country Store Concord, Cabarrus County, North Carolina G Wl#; 9362 4.0 LIMITATIONS Monitoring Report March 19, 2020 Page 6 Shield has performed environmental services at the subject site on behalf of Security Oil Company, Inc. Shield has performed this scope of work as an independent contractor/consultant using reasonable- care and skill in accordance and consistent with customary industry standards of engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of care that can be applied to measure Shield's performance of the work. No other warranty, expressed or implied, is made or intended by Shield. The report has been prepared for the exclusive use by Security Oil Company, Inc. All recommendations, findings, and conclusions made by Shield have been made to the best of Shield's knowledge, opinion, and belief, based upon information obtained during this scope of work and is limited by the scope nature and type of services as agreed upon between Security Oil Company, Inc. and Shield. Conclusions are provided with the understanding that Shield is presenting information and not rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the responsibility of Security Oil Company, Inc., under advice of its counsel, to notify the appropriate federal, state, or local public agencies as required by law; or otherwise to disclose in a timely manner, any information that may be necessary to prevent damage to human health, safety, or the environment. Compliance with recommendations provided as part of this report in no way assures compliance with federal, state, and/or local laws, regulations, and/or requirements. Analytical data has been obtained from Pace Analytical Services. This information, to the extent that it was relied on to generate this report, is assumed to be correct and complete. The work performed in conjunction with this report and the data developed are intended as a description of available information at the dates and specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or recommendations with respect to any conditions that were knowingly or unknowingly withheld, concealed, hidden, or in any way not disclosed or observable at the time of this scope of work. FIGURES NGRAPHIC SCALE 0 taus 2,000 SCALE: I in..• 2,000 ft. I SOURCE: NATIONAL GEOGRAPHIC USGS TOPO, 7,5 MINUTE MAP SERIES, CABARRUS COUNTY, NORTH CAROLINA SHIELD ' lJ ? �R°� SITE LOCATION MAP CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SHIELD V040072 DATE : 06/11 /09 DRAWN BY: RBS SCALE : AS SHOWN FIGURE: 1 0 N M O O O� O rn O O u u w 0 a x N / \ / GRAVEL PARKING \ / GRAVEL PARKING LEGEND RIGHT OF WAY (R/W) ® TYPE II MONITORING WELL ® TYPE III MONITORING WELL SOIL BORING LOCATION ■ APPROXIMATE LOCATION OF SOIL BORING COMPLETED BY INTEGRITY ENVIRONMENTAL CONSULTANTS, P.C. (IEC) AS PRESENTED IN FIGURE 7 - CONTAMINATED SOIL LOCATION IN THE CORRECTIVE ACTION PLAN REPORT BY IEC DATED JUNE 1993. NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5-12. 2. ALL LOCATIONS ARE APPROXIMATE. 3. SB-8 - SB-12 WERE COMPLETED ON 3/7/11. SB-13 Ex SB-14 WERE COMPLETED ON 8/11 /12. SB-15 - SB-17 WERE COMPLETED ON 1 /4/12. 1 1 ®MW-9 1 1 1 IASPHALT �•,vfuSON HIGHWAY (N.C. HIGH WAY 73) 0 v rn r 0 0 0 v GRAPHIC SCALE 0 10 20 30 SCALE: 1 in. = 30 ft. LEGEND O SITE SOURCE N - WATER SUPPLY WELL X ABANDONED WATER SUPPLY WELL 4681593728 PROPERTY IDENTIFICATION NUMBER NOTES: 1. REFERENCE SEI PROFESSIONAL SERVICES, P.C. FIGURE AND CABARRUS COUNTY, NORTH CAROLINA GIS 2. ALL LOCATIONS ARE APPROXIMATE. GRAPHIC SCALE 0 100' 200, 300 SCALE: 1 in. = 300 ft. 0 N O O O� O OOP O O N H U W 1 O K d GRAVEL PARKING / ®(9.58) / so' � i ao' 1 / GRAVEL PARKING ASPHALT � r o sa 78' 74 + 76' ' ( (80.831 ®MA /(79.4�4 mW-1 ASPHALT r / Mw 76' $ 80' S Y.541' FORMERr7 �� ' (NM) SVE-1 1 UST PIT [NM] 1 CONCRETE � W-3 DMW- `'DM 4 I (NM) [79.081 [79.231 -- MW_) CURRENT (79.40) US PIT 86 ASPHALT DMW1� 79.50' �— ('79.471 ®DMW-3 [79.521 ® MW-10 (79.66) 0 30' R/W FROM 4- (APPROXIMATE) DAVIDSON HIGIJWAY 0 (N.C. HIGHWAY73) M 0 LEGEND LLJ RIGHT OF WAY (R/W) crl LLJ® TYPE II MONITORING WELL 0 GR10 5 of 30 wD ® TYPE III MONITORING WELL no SCALE: 1 in. = 30 ft. (ft) FEET 0 N (80.83) GROUNDWATER ELEVATION (ft) [79.521 GROUNDWATER ELEVATION (ft) NOT USED IN z CONTOURING D i301 TAGGART CREEK ROAD 0 — — — — GROUNDWATER ELEVATION (ft) CONTOUR LINE CHARLOrrF-NC sees �-- ESTIMATED GROUNDWATER FLOW DIRECTION SHIELDLi ',,, a wmv hmld-gm>emg � ENGINEERING, INC. b (NM) NOT MEASURED GROUNDWATER ELEVATION NOTES: CONTOUR MAP 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED _ 7-5-12. CARL'S COUNTRY STORE 2. ALL LOCATIONS ARE APPROXIMATE. 8952 DAVIDSON HIGHWAY 3. GROUNDWATER INFORMATION PRODUCED BY SHIELD PERSONNEL. CONCORD, NORTH CAROLINA 3. GROUNDWATER ELEVATION MEASURED ON 02/04/2020. SHIELD #1090032 a 4. GROUNDWATER LEVELS ASSUME REFERENCE TOP OF CASING ELEVATION DATE : 3/ 17/2020 DRAWN BY : KPS a AT MW-1 OF 100 FEET. r 5. GROUNDWATER CONTOUR INTERVALS AS SHOWN SCALE AS SHOWN FIGURE 4 0 M O O P O a O 0 G u u w 0 0 a / � 1 / GRAVEL PARKING \ ®MW-91- / (ND) I / l GRAVEL PARKING I 0 5�0 o- m I ASPHALT n e 1 " ®MW 6 M(5o.4)• (ND) J ` ` I MW-I ® MW-7 1 IND) ASPHALT � � +,. � Q �y \ 1 MW-8 + �1 INS) % SVVE-1 Iu(W�401 '+ FORMER 1 fCY �` �` / (ids) 1 ; WUST PIT V CONCRETES / MW 3 DM�S I'-DMW-4 + _ CURRENT ` \ _ MW UST PIT 11 y ASPHALT D NA`DMW. -- -�. [32.3] ®[,IIW-10 ff"71 30' R/W FROM rL (APPROXIMATE) DAVIDSON HIGHWAY (N C. J HIGHWAY 73) LEGEND RIGHT OF WAY (R/W) GRAPHIC SCALE ® TYPE II MONITORING WELL o 10 I_ 30 0 TYPE III MONITORING WELL SCALE: 1 in. = 30 ft. (ug/L) MICROGRAMS PER LITER (50.4) BENZENE CONCENTRATION (ug/L) [32.3) BENZENE CONCENTRATION (ug/L) NOT USED IN CONTOURING SHIELD 77- TAR13 CREEK Ri CHARLOrre. NC 2820 — — — — BENZENE ISOCONCENTRATION CONTOUR LINE (ug/L) � :w.Ms®,� rw•7e�eew iaY (ND) NOT DETECTED AT OR ABOVE THE METHOD DETECTION ENGINEERING, INC. LIMIT SPECIFIED IN THE LABORATORY REPORT. INS) NOT SAMPLED BENZENE ISOCONCENTRATION MAP NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5-12. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 02/04/2020. 4. CONTOUR INTERVALS AS SHOWN. 0 N M O 0 rn 0 0 0 w 0 a e GRAVEL PARKING \ ®MW-9I- / (2.3) 1 GRAVEL PARKING ASPHALT / —— 1 / 20 —100� I / 1500Zo =.{LSD®MW-/ 515 1 MW 1 (ND) MW-7 ® (0.2) I I R ASPHALT 5(NS♦' +r—__ .��j°R� MW S( ) L �MW'4 FORD I ��1a) USTPI �+ V / D I •5 �, ` CONCRETE MW (NS) [ Di DM DI4*4 1 1 h+IW-2 �URRENT �(1210[' ST PIT 1 ASPHALT [[14.1 1®91d+W 3 1 ®MW 10 30' R/W FROM ti (APPROXIMATE) DAVIDSON HIGHW J AY (N.C. HIGHWAY 73 O v LEGEND RIGHT OF WAY (R/W) GRAPHIC SCALE ® TYPE II MONITORING WELL o 10 20 30 ® TYPE III MONITORING WELL SCALE: 1 in. = 30 ft. (ug/L) MICROGRAMS PER LITER MTBE METHYL TERT-BUTYL ETHER (1,210) MTBE CONCENTRATION (ug/L) [14.11 MTBE CONCENTRATION (ug/L) NOT USED IN 4301 TAGGARTCREEK R CHARLOTTE, NC 2B20B SHIELD7,Z3.4 CONTOURING 1399 "'MTBE ISOCONCENTRATION CONTOUR LINE (ug/L) wlde B ..nny— ENGINEERING, INC. (ND) NOT DETECTED AT OR ABOVE THE METHOD DETECTION LIMIT SPECIFIED IN THE LABORATORY REPORT. MTBE ISOCONCENTRATION MAP (NS) NOT SAMPLED CARL'S COUNTRY STORE NOTES: 8952 DAVIDSON HIGHWAY 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED CONCORD, NORTH CAROLINA 7 5 12. SHIELD 1t1090032 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 02/04/2020. DATE : 3/17/2020 DRAWN BY : KPS 4. CONTOUR INTERVALS AS SHOWN. ri • i r _ • r rl 1�unl r1i 1 lmr _ i x 0 N / GRAVEL PARKING \ ®MW-91, / (NO) I GRAVEL PARKING ASPHALT 1 MW-6 ® (ND) \ \ \ 1 ®MW35 11 MW 1 (ND) ® MW-7 \ ASPHALT SVE-1 ` Q� \ MW 8 MW-4 INS) -Q (Ns) i (ND) ` \ ® + UOSTT elf \ / MW 3 DMW-5 f \ CONA-Th, INS) [ND] MW- CURRjg7 DMNDI4 (DMW 1 UST PIT\ \ � ' ASPHALT %NDj � DMW-3 �.. (ND] ® j - `��MW91 30' R/W FROM ti (APPROXIMATE) LEGEND RIGHT OF WAY (R/W) ® TYPE II MONITORING WELL ® TYPE III MONITORING WELL (ug/L) MICROGRAMS PER LITER (51.3) NAPHTHALENE CONCENTRATION (ug/L) [NDI NAPHTHALENE CONCENTRATION (ug/L) NOT USED IN CONTOURING — — — ^- NAPHTHALENE ISOCONCENTRATION CONTOUR LINE (ug/L) (NO) NOT DETECTED AT OR ABOVE THE METHOD DETECTION LIMIT SPECIFIED IN THE LABORATORY REPORT. INS) NOT SAMPLED NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5.12. 2. CONTOUR INTERVAL AS SHOWN. 3. ALL LOCATIONS ARE APPROXIMATE. 4. GROUNDWATER SAMPLES COLLECTED ON 02/04/2020. DAVIDgp N HIGHWAY (N.C, HIGHWAY 73) yv GRAPHIC SCALE 0 10 20 30 SCALE: 1 in. = 30 ft. x TABLES TABLE 1 - SUMMARY OF WATER SUPPLY WELL AND RECEPTOR INFORMATION Carl's Country Store 8952 Davidson Highway INC 73) Kannapolis, Cabarrus County, North Carolina Facility ID Number: 0-007470 Incident Number: 9362 Well Address and Parcel Phone Casing Well Screen Interval (feet Distance from Well # Well Owner and Address 7Well Well Use DepthDepth EWell source area of ID Number Number If bls) bls) release feet WSW 1 8952 Davidson Highway VSP Business, LLC Unknown Abandoned Unit Unk Unk Unk <250 Subject Propedyl 1534 Ciopperplate Road Charknlle. NC 28262 Former 1890 Odell School Abandoned - Parcel WSW-2 Road 4987-59-6415 Odell 73 investments LLC Unknown Consolidation and Unk Unk Unk Unk 450 1151 Biscayne Dr, Concord, NC 28027 Redevelopment Former 8845 Davidson Hi hwa 4987-59-8347 2082/8900 Odell School Road Waller D. Dennis Unknown Community Well - Serves 6 Unk Unk Unk Unk 650 682-50-3481 2062 Odell School Road Concord, NC 28027 Lots 2140 Odell School Road WJkam Andrew and Linda Mark 4682-50-2750 2140 Ode0.Sctwol Road Concani NC 28027 Unknown Drinking NA NA NA NA NA 2114 Odelr School' Road Dean D. Everhardt 2114 WSW-3 46B2-50-3524 Odell Sahoul Road Concood NC 28027 Unknown Drinking NA NA NA NA NA 2038 Odell School Road Tho nlls R. sad Sandra Snulb 4682-504281 2038 Odell Sc wd Road Concord NC 28027 Unknown Drinking NA NA NA NA NA 2010 Dealt School Road Nancy Brown Whipple 2010 Unknown Drinking NA NA NA NA NA 4682-50-5151 Odell School RoacLCarmpird, NC 28027 2uou Odell School Road Odell Lions Club Unknown Drinking NA NA NA NA NA 4682-50-8001 2000 Odell School Road Concord NC 28027 8730 Hillsdell Drive Todd G and Sharon Gibilisc , Unknown Community Well Serves 12 Unk Unk Unk Unk 620 4682-50-6273 B887 Hillsdell Drive Concord NC 28027 Known Lots 8935 Hillsdell Drive 4682 George P. Lawrence NA Drinking NA NA NA NA NA 50-9322 8835 Hillsdell Dr, Concord NC 28027 _ 8785 Hillsdell Drive Darlene H. Easley NA Drinking NA NA NA NA NA 4682-60-1472 8785 Hillsdell Drive Concord NO 28027 8736 Hillsdell Drive Nicholas R, and Sally S Pierce NA Drinking NA NA NA NA NA 4682-60-4522 8736 Hillsdell Drive Concord NC 28027 8711 Hillsdell Drive Robert K- and Dorothy J. Park NA Drinking NA NA NA NA NA 682-60-5546 8711 Hillsdell Drive Concord NC 28027 8691 Hillsdell Drive Steven A. and Megan S. Earnhardt 4682-60-6671 8691 Hillsdell Drive Concord NC 28027 NA Drinking NA NA NA NA NA WSW-0 8690 Hillsdell Drive Carl R. and Deborah P. Parker >1500; Served by 4682-60-5945 690 Hi8sde8. Drive Concord NC 28027 NA Drinking NA NA NA NA W W 4 8774 Hillsdell Drive Donald and Cynthia C, Belush 4682-60-1707 774 Hillsdell Drive Concord NC 28027 NA Drinking NA NA NA NA NA 2225 Odell Circle Joseph W. Fagan Jr. 4682-51-9093 2225 Odell Circle Citnuara NC 28027 NA Drinking NA NA NA NA NA 2161 Odell Circle Dennis W. Forester NA Drinking NA NA NA NA NA 4682-50-6836 2161 Odell Circle Concord,NC 28027 8824 Hillsdell Drive Franklin and Angela Holder NA Drinking NA NA NA NA NA 4682-50-9625. 8824 Hillsdell Drive Concord NC 28027 BB50 Hillsdell Drive Aaron and Ashley Carswell NA Drinking NA NA NA NA NA 4682-50-7559 8850 Hillsdell Drive Concord NC 28027 WSW-5 835 Hillsdell Drive 4682 George P. Lawrence Unknown Abandoned/No Longer Present Unk Unk Unk Unk 920 50-9322 8B35 Hi8sde8 Dr Concord NC 28027 WSW-6 8800 Johnston Street 4682 Robert L. and Sherry K. Harmon, Jr. 782-7791 Drinking Unk Unk Unk f0-1076 19BO Odell School Road Unk 920 WSW 7 8750 Davidson Highway Roger L. Fortney 7844255 Drinking Unk Unk Unk Unk 900 Q W— -3527 B750 Davidson Hwy. Concord. NC 2 7 Former 1810 Odell School Odell 73 investments LLC Abandoned - Parcel Unk 750 WSW-8 Road 4681-59-7099 1151 Biscayne Dr, Concord, NC 28027 Unknown Consolidation and Unk Unk Unk _ Redevelopment 9051 Davidson Highway Odell Volunteer Fire Department, Inc. Outside Use Only (Le, washing W5W-9 4681-49-8600/468lA9-9538 9051 Davidson Hwy, Concord, NC 28027 791-1780 vehicles)-2 properties 600 Unk 68 Unk 650 WSW-10 8703 Johnson Road Rodger D, Baucom 785-6072 Drinking 130 Unk Unk Unk >1000 4681-69-5804 6703 Johnson Street Concord, NC 28027 WSW 11 8741 Davidson Highway Mar-Meck Development Limited Partnership Unknown Drinking Unk Unk Unk Unk >1000 4681-69-1361 PO Box 5107 Concord NC 28027 8699 Davidson Highway Mar-Meck Development Limited Partnership WSW 12 4681-69-3383 PO Box 5107, Concord, NC 28028 Unknown Drinking Unk Unk Unk Unk >1000 Former 1760 Odell School Odell 73 investments LLC Aporoonod - Parent WSW-13 Road 4681-68-2624 1151 Biscayne Dr, Concord, NC 28027 Unknown Consolidation and Unk Unk Unk Unk >1000 Redevelopment WSW 14 9179 Davidson Highway 4681 Rocky River Crossing LLC Unknown Formerly Drinking - Well not Unk Unk Unk Unk >7000 49-0380 4350 Main SI STE 201, Harrisburg, NC 28075 observed; Vacant Land (2019) 9150 Davidson Highway 4681 Suslar/Lftlle LLC; Patrick Sustar WSW-15 49-3973 9172 Davidson Hwy. Concord. NC 28027 704-795-9005 Abandoned Unk Unit Unk Unk >1000 Sustar/Lillle LLC; Patrick Sustar Drinking, Cleaning, 8 Drinking WSW-16 9172 Davidson Highway W72 Davidson Hwy. Concord. NC 28027 704-795-9005 for Animals Onsite 230 Unk 76 Unk >1000 4682-30-9176 Sustar/Lillie LLC; Patrick Sustar Drinking, Cleaning, 8 Drinking WSW-16A 0172 Davidson. HwV. Concord NC 28027 704-795-9005 for Animals Onsiha 350 Unk 76 Unk >1000 WSW-17 2135 Odell School Road Harriet H, Shivadecker Unknown Drinking Unk Unk 0-290' 290'-300' 950 A682-40-6462 2135 Odell School Rd. Concord- NC 2B➢27 Former 9105 Davidson Cabarrus County Abandoned - Parcel WSW-1B Highway 4681-49-5378 PO Box 707 Concord NC 28026 Unknown Consolidation with Cabarrus Unk Unk Unk Unk 725 County School Property 2131 Davidson Highway 4682 David Yawn 796-3799 Drinking 100 Unk Unk Unk >1000 WSW 19 40-2979 2131 Odell School Road, Concord, NC 28027 2145 Odell School Road Jennie H Yawn Unknown Drinking Unk Unk Unk Unk >1000 4642-40-4776 1106 River dint Lu., Townsend. GA 31331 WSW-20 2339 Odell School Road 4682-41-7025 Cabarrusoo LLC 150 2nd Ave N STE 1600, St Petersburg, FL 33701 Unknown Drinking - Currently Not in Use (Property Vacant) Unk Unk Unk Unk >1000 WSW 21 Unk Unk Unk Unk >1000 21 B2Odell School Road Jennifer Clark 2182 WSW 22 4682-50-1997 Odell School Read Concord. NC 28027 Unknown Drinking Unk Unk Unk Unk >1000 WSW-23 8651 Johnston Street 4681 Joyce Wallllf Collins B651 Unknown Drinking Unk Unk Unk Unk >7000 59-0996 John a1w1 Sinim Concord- NC 78027 WSW-24 9180 Davidson Highway Susladl-itile LLC; Patrick Sustar 704-795-9005 Drinking Unk Unk Unk Unk >1000 4681-49-2903 9172 Davidson Hwy Cnnered. NC 28027 Notes: Unk - Information unknown Information contained in this Table observed by Shield personnel or reported by others TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Cabarrus County, North Carolina Incident Number: 9362 Well ID Dale Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) p Depth to Groundwater (feet) Diff Between As - built and Measured Total Depth (feel) Measured Water Column in Well (feet) Groundwater Elevation (feel) MW-1 5/15/2003' 10000 2 30 10-30 11/2199 NA 9.47 NA NA 9053 e123101 NA 8.13 NA NA 9167 2112102 NA 8.66 NA NA 9134 W25102 NA 10.63 NA NA 8937 5/19/03 NA 18.36 NA NA 8164 11/3/03 NA 16-97 NA NA 83,03 514104 NA 17.09 NA NA 82.91 11007 NA 21.86 NA NA 78.14 5f28108 NA 20.72 NA f4A 79.26 4/16109 29,83 1912 0,17 10.71 80.88 11/6/09 29.87 21.48 0.13 8.39 78,52 6/28/10 29.87 17.20 0.13 12.67 1 82.80 3l7/11 29.87 19,44 0.13 10.43 80.56 8/2112 29.87 1992. 0.13 995 1 80.08 2f2GI14 29.87 16.85 013 13.02 83,15 8/25114 29,87 16.81 0.13 13.06 83.19 2/9/15 29.87 18.46 0.13 11.41 81.54 8/17/15 29,87 13.25 0.13 16.62 86.75 2/22/16 29.87 013 12 12 82.25 8/30116 29.87 .1775 1943 0,13 10.44 8057 2/21117 29.87 21.29 0.13 8.58 78,71 619117 29,87 20.76 0.13 911 79,24 2120118 29,87 22.24 013 763 77 76 8/31/16 29,87 2236 0,13 7.51 7764 8/12/19 29.87 1855 0.13 11.32 81.45 214/20 29.87 19.43 0 13 10.44 8057 MW-2 5/15/2003' 98.39 2 30 10-30 11/2/99 NA 22 51 NA NA 7588 2/14101 NA 22.57 NA NA 75.82 8/23101 NA 21.16 NA NA 77 23 2/12102 NA 22,62 NA NA 75 77 9125102 NA 23.01 NA _NA _ 7538 5119103 NA 17.06 NA NA 8133 1113103 NA 1591 NA NA 82.48 5/4/04 NA 16.12 NA NA 8227 11/8/07 NA 20.46 NA NA 77.93 5/28108 NA 19.30 NA NA 7909 4/16M 30.04 18.25 -0,04 11,79 80,14 1116109 30.07 19.63 -0.07 10,44 78.76 6126110 3007 115.89 -0.07 14.18 82.50 3/7111 30,07 17.56 -0.07 12.51 80.83 8/2/12 30,07 18.43 -0.07 11.64 79,96 2/26/14 30.07 15.02 -0,07 15.05 83.37 8/25114 30.07 15.64 -0.07 14.43 82.75 2/9115 30.07 17.16 -0,07 12.91 81.23 8117115 30,07 1920 -0.07 10.87 79.19 2122116 30.07 16.84 -0.07 13-23 81.55 BM116 30.07 18.44 -0,07 11.63 79.95 2121117 30,07 2035. -0.07 9.72 78,04 8/9/17 30.07 19.98 -0.07 10.09 78.41 2/20/18 30.07 20.09 -0.07 9,98 7830 6/31/18 30.07 21.28 -0.07 579 77 11 2/19119 30.07 18.11 -0,07 11,96 80.28 8/12119 30.07 18,25 -0.07 1182 80,14 2/4120 30.07 18.99 -0.07 11 D8 7940 MW-3 51152003• 94.16 2 30 10-30 1112)99 NA 813 NA NA 8603 8/23l01 NA 7 12 NA NA 87 04 2112142 NA 757 NA NA 8659 9/25/02 NA 960 NA NA 84 56 5119/03 NA 13.09 NA NA 8107 11/3103 NA 12.00 NA NA 8216 514104 NA 12.23 NA NA 81.93 1118107 NA 1&58 NA NA 77.58 5128108 NA 15.47 NA NA 7869 4/16109 29.59 13.55 041 16.04 8061 11/6/09 29.65 15.88 0.35 13.77 78.28 6/28/10 29,65 12.11 0.35 17.54 82.05 317/11 29.65 13.89 035 15.76 80.27 812112 29,65 14-54 0.35 15.11 79-62 2126/14 29.65 11.29 0.35 18.36 82.87 8125114 29.65 11.89 0.35 17.76 8227 2/9115 29,65 13.32 0.35 16.33 60.84 8/17115 29.65 1521 0.35 14.44 7895 2/22/16 29.65 12.89 0.35 16.76 8127 NM Unable to Locate - E2/4/2020 NM Well has been paved over HAProjecls12009\1090032-01 Carl's Counlry Store\RepodswR 3-2020\Tuble 2 - Hisl GW Elev Page 1 of 4 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Cabarrus County, North Carolina Incident Number: 9362 Well ID Dale Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth P (feet) Screened Interval (feel) Field Measurements Field Calculations Gauging Date Total Depth P (feel) Depth to Groundwater (feet) Dlff Between As - built end Measured Total Depth (feel) Measured Water Column in Well (Feet) Groundwater Elevation (feel) MW-4 5/15/2003' 9806 2 30 10-30 11/2/99 NA 19.11 NA NA 78.95 10/15/01 NA 2195 NA NA 76,11, 10/30/01 NA 21.62 NA NA 76.44 5/19/03 NA 16.86 NA NA 81.20 11/3/03 NA 15.79 NA NA 82.27 5/4/04 NA 15-90 NA NA 82.16 11/8/07 NA 20A0 NA NA 77,66 5/28/08 NA 19.29 NA NA 78.77 4/16109 30,13 1741 -0.13 12.72 8065 11/6/09 30,20 19.72 -0.20 10.48 78.34 6/28/10 30.20 15.90 -0.20 14.30 82,16 3/7/11 30.20 17.78 -0.20 12.42 80.28 8/2112 30.20 18.42 -020 11.78 79,64 2/26114 3020 15AS -0.20 15.05 82.91 8125114 3020 15.62 -0-20 14,58 82.44 219115 3020 17.07 -020 13.13 80.99 8117/15 30-20 19-03 -0.20 11.17 79.03 2/22/16 3020 16.74 -0.20 13.46 8132 8/30/16 3020 18.22 -0.20 11,98 79.84 2/21/17 30.20 20.12 -0,20 10.08 7794 8/9117 3020 19.61 _ -0,20 10.59 76.45 2t20/18 3020 20.83 -020 9,37 77.23 8/31118 3020 19,90 -0,20 10.30 78.16 2/19/19 3020 17.77 -0.20 12.43 80,29 8/12/19 30.20 17.82 -0.20 12..38 80..24 2/4/20 30.20 18,52 -0.20 11.68 79.54 MW5 10/17/2001' 9874 2 30 10-30 1112/99 NA 21.39 NA NA 7798 8/23/01 NA 2038 NA NA 78.99 9/25/02 NA 21.93 NA NA 76.81 5I79103 NA 17.61 NA NA 81.13 1113/03 NA 16.48 NA NA 82.26 514/04 NA 16.69 NA NA 82.05 11/8/07 NA 21.16 NA NA 77.58 5/28/08 NA 20.03 NA NA 78.71 4/16109 29,81 1821 0.19 11,60 80.53 _ 11/6109 29.87 20.45 0.13 SA2 78.29 6128110 29.87 1.6.65 0,13 1322 82.09 317/11 29.87 18-56 0,13 11.31 80,18 812/12 29-87 1992 0,13 9,95 78.82 2/26/14 29.87 15-94 0.13 13.93 82.80 8/25/14 29.87 16A0 0.13 13..47 8234 2/9/15 29.87 17.82 0.13 1205. 80.92 8117/15 29.87 1938 0,13 10-09 78.96 2/22/1.6 29.87 17.47 0-13 12.40 81.27 8/30/16 29.87 18.95 0.13 10.92 79.79 _ 2721/17 29.87 2085. 0.13 902 77.89 6/9/17 29.87 20.39 0.13 9.48 78.35 2/20/18 29.87 2155 0.13 8.32 77.19 8/31/16 29.87 21.62 0.13 825 77.12 2119l19 29.87 18-44 0.13 11.43 8030 e/12/19 29.87 18.58 0.13 1131 80.18 2/4/20 29.87 1928 0.13 1059 79.46 H:\Projects\200911090092-01 Carl's Country Store\RepodswlR 3-20201Taple 2 - Hist GW Elev Page 2 01' 4 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Cabarrus County, North Carolina Incident Number: 9362 Well ID Dale Installed Top of Casing Elevation (feel) Well Diameter (inches) As -built Depth (feel) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total De Ih p (feet) Depth to Groundwater (feet) Diff. Between As - built and Measured Total Depth (feel) Measured Water Column in Well (feet) Groundwater Elevation (feel) MW-7 8/3/2004 8640 2 35 15-35 11/2/99 NA 8.98 NA NA 7742 2114/01 NA 9.76 NA NA 7664 8/23/01 NA 7,95 NA NA 78-45 2/12/02 NA 6.0 NA NA 77.87 9/25102 NA 10.44 NA NA 75.96 11/8/07 NA_ 20.71 NA NA 65-69 5/28/08 NA 20-26 NA _ NA 56,14 _ 11/6109 35.16 19.42 -0.16 15..74 66.98 6128/10 35.16 15,31 -0.16 19.85 71,09 3/7/11 35.16 17.34 -0-16 17,82 690G 8/2/12 35,16 17,53 -0.16 17.63 68.87 2/26/14 35.16 13.76 -0.16 21.40 72.64 8/25/14 35.16 15.24 -0.16 19.92 71.16 2/9115 35,16 15.35 -0.16 19,81 71-05 8/17/15 35.16 1764 -0.16 17.52 6876 2122116 35,16 13.85 -0.16 21.31 72.55 _8/30/16 35-16 16-39 -0.16 18,77 70-01 2121/17 35.16 16.71 -0.16 18.45 6969 8/9/17 35.16 16.26 -0.16 18.90 70,14 2/20118 _ 35.16 16.84 -0.16 18.32 69.56 8/31118 35.16 16.93 -0.16 1823 69.47 8/12/19 35.16 1538 -0,16 19-78 71.02 214120 35 16 14,13 -0.16 21.03 72.27 MW-8 Unknown Unknown '2 Unknown Unknown 2/12/02 NA 7.38 NA NA Unknown 9/25/02 NA 9.49 NA NA Unknown 2/26/14 1955 17.44 NA NA Unknown 8/25/14 1955 17,36 NA NA Unknown 2/9/15 1955 19.03 NA NA Unknown 8117/15 19.55 >19.95 NA NA Unknown 2/22/16 1.9.55 18.31 NA NA Unknown 8/30/16 19.55 19.54 NA NA Unknown 2/21/17 19-55 >19 55 NA NA Unknown 8/9/17 19-55 >19,55 NA NA Unknown 2/20/2018- 2/4/2020 1955 >19.55 NA NA Unknown MW-9 3/312011 98.16 2 26 8-28 317/11 27-80 18.38 0.20 9-42 79,78 8/2/12 27,80 18.86 0.20 6.94 79.30 2/26114 27.80 15.84 0-20 1 11,96 82.32 8125114 2780 16.06 0.20 11.74 82.10 219115 27.80 17.63 0.20 10.17 80.53 8117/15 27.80 19,39 0.20 8.41 78.77 2/22116 27.80 17.05 0.20 10,75 8111 8/30/816 27.80 18.51 0.20 9.29 7965 2/21/17 27,80 20.38 0.20 7.42 7778 8/9/17 27.80 19-69 020 8-11 78.47 2/20/18 27,80 21-07 0,20 6.73 77-09 8131/18 27-80 21.17 020 6-63 76.99 8112/19 27-80 17.85 020 9.95 80.31 2/4/20 27-80 18.58 020 9.22 79.58 MW-10 3/3/2011 99.52 2 28 8-28 3/7/11 27-76 18-47 0-24 9.29 8105 8/2/12 27.76 19-19 0.24 8.57 80.33 2/26/14 27.76 15.70 024 12.06 8382 8/25/14 2776 16-16 024 11.60 63.36 219115 27.76 17-74 024 10.02 61.78 8/17/15 27.76 19,91 024 7.85 79.61 2/22/16 27.76 17.49 024 10.27 82-03 8130/16 2776 19.31 0.24 845 B0.21 2/21/17 2776 21.15 0.24 6.61 78.37 8/9/17 2776 21.04 0.24 6.72 78.48 2/20/18 27.76 21.98 0.24 5.78 77,54 8/31/18 27.76 22.38 024 5-38 77.14 2/19/19 27.76 19,06 0.24 8.71 80.47 8/1209 27.76 19.15 0.24 8.61 60.37 214/20 27.76 19.86 0.24 7,90 7966 DMW-1 4/29/1993 9835 2 37 33-37 1112/99 NA 8.94 NA NA 89A1 2/23/01 NA 20.75 NA NA 77.60 10/18/01 NA 21.90 NA NA 76.45 10/30/01 NA 27.70 NA NA 76-65 5/19/03 NA 16.89 NA NA 81-46 11/3/03 NA 15-67 NA NA 82.68 5/4104 NA 16-74 NA NA 82,61 11/8/07 NA 20.25 NA NA _ 78,10 6128/08 NA 19,06 NA NA 79.29 4116/09 38.83 17.02 -183 21.81 81.33 11/6/09 38.90 t9.45 -1.90 19.45 78.90 6/28/10 38.90 15.61 -1.90 23,29 8234 317111 38.90 17-33 -1.90 21.57 81.02 812/12 38-90 18.16 -1.90 20.74 8019 2/26/14 38-90 _14.76 -1.90 24.14 8359 8/25/14 38.90 15-64 1.90 23.26 82.71 2/9/15 38.90 16.80 -1.90 22.10 81.55 HAProjecls\2009\1090032-01 Carl's Country Slore\ReporlsWlR 3-202\Table 2 - Hisl GW Elev Peg. 3 0l4 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Cabarrus County, North Carolina Incident Number: 9362 Well ID Dale Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feel) Screened Interval (feet) Field Measurements Field Calculations Gauging Dale Total Depth (feet) Depth to Groundwater (feel) Diff. Between As - built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) DMW-1 CONT 8117/15 38.90 18-88 -1.90 20.02 79.47 2/22/16 38.90 16.53 -1.90 22.37 81.82 6/30/16 38.90 18.22 -1.90 2068. 80.13 2121/17 38-90 2010 -1.90 18.80 78.25 8/9117 38.90 19.84 -1.90 1906. 78.51 2/20/18 38.90 2089. -1.90 18.01 _ 77.46 8/31/18 3890 21.24 -1.90 17.66 77.11 8112/19 3890 18.06 -1.90 20.84 80.29 2/4120 38.90 18.88 -190 20.02 79.47 DMW-2 Unknown 100.28 2 Unknown Unknown 112/99 NA 22.74 NA NA 77.54 DMW-3 3/3/2011 9849 2 5000 45-50 317111 49 57 1738 0.43 32.19 81 11 812/12 49.57 1839 0.43 31.18 80.10 2/26/14 4957 14.95 043 34.62 63.54 8/25/14 4957 15.52 043 3405 82-97 2/9115 4957 1703 043 3254 91.46 8/17115 49.57 19 12 043 30.45 79.37 2/22/16 4957 16-78 0.43 32,79 81.71 8/30/16 49.57 16,48 0.43 31.09 80.01 2/21117 4957 1 20 36 0.43 29.21 78.13 8/9/17 49.57 20.04 0.43 29.53 78.45 2/20/18 49.57 21.13 043 28.44 7736 8/31/18 49.57 2144 0.43 28.13 7705 2/19/19 49.57 18.16 0.43 31.41 80.33 8112/19 49.57 18.32 0.43 31.25 80.17 214/20 4957 18.97 0.43 30.60 79.52 DMW-4 8/15/2011 98A0 2 70 65-70 8/16/11 70.01 17.95 -0.01 52.06 80.45 8/2/12 70.01 18-60 -0.01 51.41 79.80 2/26/14 70.01 1514 -0.01 54.87 83.26 8/25/14 70.01 15.80 -0.01 54.21 82Z0 2/9/15 70.01 17-30 -0.01 52.71 81.10 8/17/15 70.01 19.33 -0.01 50.68 79.07 2/22/16 70.01 17.02 -0.01 _ 52.99 81,38 8/30/16 70.01 18.62 -0.01 51.39 79.78 2/21/17 7001 20.51 -0 01 49.50 77.89 619/17 7001 20.15 -0.01 49.86 78.25 2/20118 70.01 2127 -0.01 48.74 1 77.13 8/31/18 70.01 2L50 -0.01 48.51 7690 8/12/19 70.01 1846 -0.01 51.55 79.94 2/4/20 70-01 19.17 -0,01 50,84 7923 DMW-5 1/6/2012 9794 2 99 94-99 1110112 98.35 16.92 065 81.43 8102 2/20/12 98.35 1670 0.65 81.55 81 24 8/2112 98-35 17.96 0.65 80.39 79.98 2/26/14 9835 14.57 0.65 83.78 83.37 8/25/14 9835 1515 065 83.20 82.79 2/9115 98.35 16.76 0.65 81.59 8118 8117/15 98.35 18.74 0.65 79.61 7920 2/22116 98.35 16.43 0.65 81.92 81.51 8/30/16 98.35 18.08 0-65 80.27 79.86 2/21/17 98.35 19.89 0.65 78.46 7805 8/9/17 98.35 19.57 0.65 78.78 78.37 2/20/18 9835 20.71 0.65 77.64 77.23 8131/18 98.35 21.04 0.65 77.31 76.90 2119/19 98-35 17.79 0.65 80.56 8015 8/12/19 9835 1794 0.65 80.41 80.00 214/20 9835 1886 065 79.49 7908 SVE-1 6/1/2012 9 94 2 25 10-25 6f7/12 25,00 16.79 000 8.21 81115 719/12 2500 17.52 0-00 7 46 80.42 8/3/12 25.00 18.28 000 6 72 79.66 2/26/14 NM NM NM NM NM 8/25/14 NM NM NM NM NM Notes. Top of Casing elevation based on arbitrary datum of 100 feet = Replacement monitoring well NM= Not Measured NA = Data Not Available; data prior to 4/16/09 reported by others H IProlecls0009\1090032-01 Carrs Country SlorelReporlawR 3-2020\Tat)le 2 - Hiel OW Elev Page 4 of 4 TABLE 3 - SUMMARY OF GROUNDWATER ANALYTICAL RESULTS (February 4, 2020) Carl's Country Store 8652 Davidson Highway INC 73) Kannapolis, Cabarrus County, North Carolina Incident # 9362 EPA Method 6200 B Benzene Toluene Ethyl- benzene Total Xylene Ethanol n-Butyl- benzene terY- Butylbenzene sec -Butyl- benzene 1.2 Dicfiloroe Lfia� Diisopropy I Ether Isopropoyl benzene Methyl -tart- butyl -ether Naphthalene n�ropyl- benzene Trichloro ethene 1,2,4- TrimethyI benzene 1,3,5- Trimethyl- benzene tertJUnyl Alcohol tertaimyl Methyl Eller tart -Butyl Alcohol Sample Location Sample Date u u 71 u l u u l up" u /I u /I u /l u u u 11 u IL u u ll .211 ugA uwi MW-1 2/42020 NO NO NO ND ND NO NO ND NO NO NO NO ND ND NO NO ND NO NO NO MW-2 2/4/2020 5.4 I ND ND NO NO NO NO ND NO 330 ND 1210 ND NO NO NO NO 1880 NO 7360 MW-4 2/42020 1.6 ND ND ND NO NO NO NO ND 22 ND 118 ND NO NO NO NO NO NO 182 MW-5 2J412020 50.4 ND NO ND NO 2,9 ND NO ND NO 5 515 51.3 NO NO 27 ND 1100 126 26A MW-6 2/42020 NO NO NO NO NO NO NO NO ND 65 ND 1500 NO ND ND NO NO NO NO 773 MW-7 2/4/2020 NO NO ND NO NO NO NO ND ND ND NO 07 NO NO ND ND NO NO NO NO MW-9 2/4/2020 NO NO NO NO NO ND NO 051 NO ND NO 23 NO ND NO NO NO NO ND NO MW-10 2/42020 3.7 NO NO 075 NO ND 24 217 ND ND 117 ND 21.9 052 ND N0 ND NO NO ND DMW-1 2142020 ND ND NO ND NO ND ND ND 1.0 15 ND 141 ND ND ND ND ND NO NO NO DMW-3 2/4/2020 32.3 ND ND ND ND ND ND ND 11.0 139 ND 65.7 ND ND ND ND ND 238 NO 112 DMW4 2/4/2020 ND ND NO ND ND ND ND ND 1.6 ND ND ND ND ND ND ND ND ND NO NO DMW-5 2/42020 18.2 ND ND ND ND ND ND ND 15.3 176 ND ND ND ND ND ND ND 400 NO ND WSW-9 2/42024 NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO ND Trip Blank 2/4/2420 NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO NO 21 $tandardsflMAC 1 600 600 500 4,000 70 70 70 0.4 �] 70 70 20 6 70 3 400 400 40 128 10 GCL Standards %000 260,0W KSW 65,600 4,OW,0W 6,8W 15,0W B,SW 4W 70,0W 25,0W 1 20,OW 6,0W A= 3,04:11111 2111,54M 26= 40.WO 1n,0W 10,000 Notes ug/L = Micrograms per liter NA = Data Not Avaitable NR = Analysis Not Requested NO = Not detected at or above laboratory method report limit 21 Standard: NCDEQ-North Carolina Administrative Code Title 75A Subchapter2L Class GA Groundwater Standards IMAC= Interim Maximum Allowable Concentration GCL Standard: NCDEQ-North Carolina Administrative Code Title 15A Subchapter 2L Standard for Risk -Based Maximum Gross Contamination Levels for Groundwater NE = Not established BOLD Concentration in excess o£2L Standards or IMACs SHADED Concentration in excess of GCL Standards H Vrotects1200911090032-01 Cad's Country Store\Reports\MR 3-20201 Table 4; Summary of Historical Groundwater Analytical Results Carl's. Country Store 8952 Davidson Highway Concord, Cabarrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Project Number 1090032 Anal al Method ---> EPA 602 501/602 or 62005 EPA 5K1 or 6200B EPA200.7 or 6010 Analyle---••> Benzene Toluene Ethyl- benzene Total Xylenes Methyl -(art- bulyl ether (MTBE) lAlcohol Alcohol lert- Amylmethyl ether Alcohol lAccohol ether (IPE) ether 1,2- Dichloroelhane Naphthalene 1,2-Dibromo-ethane (EDB) Total Lead 1■ ■ 1 0 600 600 500 20 40 128 10 70 0 4 6 002 15 C>'Ci 5 = 280 OOD B-0 500 05 500 20.000 40 000 128 000 10.00 70 000 400 5.001) 50 15.000 Sample Locallon Dale Sampled (ug/1) (ug/1) (ug/1) (ug/1) (ug/1) (ug/1) (ug/1) (ug/1) (ug/1) (ug/0 (ug/1) (ug/0 (ug/p MW-1 01127193 NO No NO N5 ND_ NR NR NO NO NO NA N N 04/16/93 NO NO NO NO ND NR NR NR NO NR NA NR NA 06/11/93 NO ND NO NO 3 NR NR NR 2 NR NA NR NA 11/12/97 NO NO NO NO ND NR NR NR ND NR NA NR NA 05/19/03 <10 _ <5,0 <1-0 <1.0 <5.0 NR NR NR <5.0 NR NA <10 NA 11/03/03 <10 <50 <10 <10 <5-0 NR NR NR <50 NR NA <1-0 NA OW04/04 c1.0 <50 <1.0 <20 c1.0 NR NR NR <10 _ <05 NA- -10 NA 1fi08107 c10 c1.0 {1.0 c30 c1.8 NR NR NR <7.0 c1.0 NA NR NA Mama e1.0 <1.0 c1.0 e30 1;0 NR NR NR <1.0 0.0 NA NR NA 04/16109 ND N❑ NO ND NO NR I NR NR NO NR NA ND NA 11/06/09 ND ND I NO ND NO NR NR NR ND ND NO NR ND O6/28/10 NO NO NO ND NO NR NR NR NO ND ND NR ND 03/07/11 _ ND ND NO ND NO NR NR NR ND ND NO NR ND 08/02/12 NO NO NO ND_ NO NR NR NR ND ND ND ND ND 02125114 NO ND NO NO ND NR NR NR NO ND NO ND ND 0012504 NO ND NO. ND ND NR NR NR NO ND NO NQ NO 02i00N5 NO NO NO NO 140 NR NR NR NO ND ND NO ND 00/17/15 NO N❑ ND NO ND NR NR NR ND N D NO ND ND 02/22/16 NO ND NO ND NO NR NR NR ND ND ND ND ND 08/30/16 NO ND NO ND NO NR NR NR ND ND ND ND ND 02121117 ND ND NO ND ND NO ND NO NO ND ND ND ND 08t09117 ND Nit ND NO ND NR NR NR NO ND NQ ND NO 02120118 ND NO NO NO NO ND ND ND NO ND NO NR NA 08/31/18 NO NO NO ND ND NO ND NO NO ND ND NR NA 02/19119 NS - PER REQUEST FROM NCOED 08/12/19 NO ND NO ND NO NO NO NO ND NO NO NO NA 02/04/20 ND NO NO NO NO ND ND ND ND NO ND NO NA MW-2 01127/93 18 NO NO NO NR NR NR NO NR NA NR NA 04116193 3 NO ND NO _ ND NR Nft _ NR NO NR NA NR NA Q2111193 13 NO NO NO ND NR NR NR NO NR NA NR NA 11t03t03 E1,0c1.0 9:.1 NR NR NR �5.0 NR NA K1.0 NA. OW04109 11i .4 1 <1A • e <5.0 « f1 a.1.0 'In -2.0 <15 22 '!Aq NR NR NR Nn NR AIR e1.0 "n <0,5 <F n NA AIA <10 AIR NA 1 - 05/28IOB 6.2 1<50 <5.0 <15 024 NR NR NR 2.5 <50 NA NR NA 04/16/09 Np ND NO NO 499 NR NR NR NO NO ND NO NA 11/06/09 _ 5.1 ND NO NO 1,080 NR NR NR NO ND NO NR NO 06/28/10 NO NO ND NO 1270 NR NR NR ND NO ND NR NO 03t07t 11 ND ND NO NO 551 NR NR RR NO ND NO NR NO W07t12 NO NO NO ND 210 NR NR NR ND NO NO NO NO 02/26114 No N➢ ND ND 112 NR NR NR ND ND NO _ NO NO 08/25/14 R➢ NO ND NO 281 NR NR NR 3.3 ND NO NO NO 02/09/15 NO NO ND NO 204 NR NR NR 2 NO NO NO NO 08/17/15 NO NO NO NO 347 NR NR NR 52 ND NO NO NO 02/22/16 NO NO ND NO 261 NR NR NR 56 NO NO ND NO 08/30/16 NO ND NO NO 4195 NR NR NR 13.6 NO ND NO, ND W21117 M 50.1 371 250 463 1470 NO 3,560 16.1 ND ND ND ND 08d09t17 3.0 7A 23.6 154 5 856 NR NR NR 22.6 NO 13.0 D ND 02720/18 4.3 4.1 21 18.3 503 1,110 ND 8050 236 ND 13.6 NR NR DW1118 33 ❑ tm 3 52S 1640 ND 7690 283 NO ND NR NR 02/19/19 2.9 NO ND NO 710 1.470 NO 6,630 266 NO NO NR NR Q0112/19 NO NO NO NO 1,350 1.400 NO 7,980 34 6 NO NO NO NR 02/04/20 5-4 ND NO NO 1,210 1.680 NO 7,360 33 NO NO NO NR 01127793 NO ND ND ND ND NR NR NR ND NR NA NR NA 04/16/93 ND NO ND ND ND NR NR NR ND NR NA NR NA 08/11/93 Nb ND ND ND ND NR NR NR ND _ NR NA NR NA 11112l07 ND ND ND ND ND NR NR NR ND NR NA MR NA 0 919r0] �1.0 <5M <1 0 <10 32 NR NR NR <6 0 NR NA <1.0 NA 1IMW03 c10 <50 .10 <10 S4 1 NR NR NR t5-0 NR NA �10 NA 05/04/p4 <t.p <50 <1 p <1 0 130 N_R NR NR _ e5.0 s0.5 NA _ <7 0 NA 11100/W <10 <10 <10 <30 78.6 NR NR NR 11 <10 NA NR NA 05/28/08 110 <1 0 110 <3 0 96 NR NR NR 0 5 '10 NA NR NA 04/16/09 NO I NO I NO I NO 46 J NR I NR I NR I NO I NR NA NO NA NU 06/02112 NO I ND I NO I ND I ND I NR I NR I NR I ND NO NO NO NO 1026/14 ND ND NO ND NO NR NR NR NO NO. NO NO ND 08/25/14 NO NO NO NO 0.51 NR NR NR NO ND NO NO NO 02/09M5 NO ND ND Np ND NR NR NR NO NO NO NO ND 08/17/15 ND NO NO ND ND NR NR NR ND ND ND ND ND 02/22/16 NQ NO I NO NO _ NO NR NR NR ND NQ ND NO NO 08/30/16 NS-UNABLE TO LOCATE /21/2017- 214/2020 NS - WELL HAS BEEN PAVED OVER 01127193 NO ND RD ND ND NR NR NR ND NR NA NR NA 041%/93 5,0 NO NO ND 79 NR NR NR 11 NR NA NR _ NA OB/11/93 4,0 ND NO NO 265 NR NR NR 41 NR NA NR NA 04/05/94 ND ND ND ND 100 NR NR NR 12 NR NA NR NA W23184 2.0 ND ND ND 140 NR NR NR NO NR NA NR NA. 11122*4 TA 2.11 ND ND 38 NR NR NR 9.0 NR NA NR NA B313tg5 ND NO ND ND 90 R NR NR 11 NR NA NR NA 05/16195 7.0 _ ND ND ND 89 NR NR NR 7,0 NR NA NR NA p4/10197 NO NO NO ND 490 NR NR NR 52 NO NA NR NA 11/12/97 2.0 NO NO NO 320I NR NR NR 37 NR I NA NR NA 08/05/99 ND NO NO NO 350 1 NR NR NR NO NO NA NR NA 02128700 ND NO NO NO 1 530 1 NR NR NR NO NR NA NR NA r11P,.j.c 1200911090032-01 G.0 s Country St.,0Rep.d.%MR 3-20201Table 4 - Hislancal G,ouM-1., P.a. i 96 Table 4: Summary of Historical Groundwater Analytical Results Carl's Country Store 8952 Davidson Highway Concord, Cabarrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Pro .ect Number 1090032 Analytical Method --- > EPA 602 601/602 Or 62005 EPA 504 1 or 6200B EPA 200 7 or 601.0 AnalNe ---- � Benzene Toluene Ethyl- benzene Total Xylenes Methyl-ted- butyl ether (MTBE) tert-Amyl Alcohol (ert- Amylmelhyl ether lerl-Butyl Alcohol Diisopropyl ether(IPE) 1,2- Dichloroelhane Naphthalene 1.2-Di-ethane (EDB) Tolel Lead SlandardnMAC 10 GOD 600 500 20 40 120 10 70 0.4 6 Opt 15 G L _ 5 000 - 260 000 84,500 05. SQ0 2Q QQO 40,000 1 128,000 10 000 70 000 4 6 D0 fiD 15 000 Sample Dale Sam led (ugll) (ug/I) (ug/ILocation ) (ug/p (ugll) (ugll) (ugll) (ug/0 (ugll) u 1:(4Ol)-- (ug/I) (ug/I) (ug/I) A (Cunt) 138115= _ DRY 1p7wl ND NO NO ND ND NR NR NR NO NO NA NR NA 0El191c3 <1.0 �5.0 <1.0 s10 32 NR NR NR <5.0 NR NA _ <7.0 NA 11103/03 <10 <50 <10 c10 24 NR NR NR c9.0 NR NA <1.0 NA 05/04104 <10 <50 <10 <2.0 22 NR NR NR <1.0 40.5 NA -1.0 NA 11/06/07 <1 0 <1 0 <1 0 <3 0 a5 NR NR NR 23 <1.0 NA NR NA 05/28108 <70 <10 <10 <30 65 NR NR NR 1A <1.0 NA NR NA 0406mg NO NO NO ND 179 NR NR NR NO NR NA ND NA I 1006109 ND NO NO NO 346 NR NR NR ND NO NO _ NR NO 676CL8110 ND ND NO NO 454 NR NR NR IA NO NO NR NO 03/07/11 NO NO NO NO 947 NR NR NR 2_5 ND NO NR ND 08/02/12 NO _ N➢ NO ND 866 _ NR NR NR NO No NO ND ND 02/26)14 ND NO NO NO 158 NR NR NR 05 NO NO NO NO 08/25114 ND ND NO NO 2280 NR NR NR 5.7 NO ND NO NO 02/09/15 NO ND ND NO 2650 NR NR NR NO NO NO NO NO 08117/15 ND ND NO NO 6390 NR NR NR 12.4 NO NO NO NO 0207J16 1 ND ND ND NO 6670 NR NR NR NO NO NO NO NO 08130116 ND NO NO NO 329c NR NR NR 198 ND NO NO NO 07.121/17 NO NO NO NO 2360 NO NO 1360 20.3 NO NO NO NO OBY09117 5-1 NO - NO NO ND NR NR I_ 0.0 0.68 NQ ND 6-3 02/20/1B NO NO NO ND 713 ND ND _NR NO 6.7 NO NO NR NR 08MMS NO NO NO NO 412 ND NO 475 B.3 NO NO NR NR 02/19/19 NO NO NO NO 326 NO ND 336 3-9 NO NO NR NR 08/12/19 M NO NO ND 34 NO ND 65 1:9 ND NO NO NR 02/04/20 1.6 NO ND ND 156 NO ND 182 2.2 ND ND NO NR MW-5 04/16/93 1 ND NO NO NO NR NR NR NO NR NA NR NA 0511179t3 ND NO NI) No 4.0 MR NR NR NO MR HA NR NA 1116M <l0 45.0 <1.0 CI <50 NR NR NR <1.0 NR NA 41.O NA 0st" <l0 -5.0 410 -2.0 5.3 NR NR NR <1.0 <0.5 NA _<7..0 NA Ili=07 <1 0 _ <i.0 <1 0 <3 0 151 NR NR NR 9,9 410 NA NR NA Q5l2B/OB <10 <1.0 <1.0 <3.0 83.9 NR NR NR 6.7 <10 NA NR NA 04/16/09 38.7 NO NO 0 8 69,4 NR NR NR 12 5 NR NA NO NA 11/06/09 184 _ ND ND 43 9 7947 NR NR NR 12 3 ND 3.8 NR NO 06/28/10 194 140 ND 14.1 176 NR NR MR 14.1 ND 12 NR ND 03407111 477 NO ND 24 7 45S NR NR NR 18.4 NO 8.0 NR NO QWW12 163 NO NO NO 17" NR NR NR 122 NO NO NO ND QM(U14 5a6 NO 7-1 ND 5470 NR NR NR 162_ NO 36.4 ND NO 08125/14 2160 O 426 NO 7030 NR NR NR NO NO 161 ND NO 02/09/15 2020 NO 55 3 NO 6210 NR NR NR NO NO 290 NO NO 08/17/15 4470 NO 143 711 4070 NR NR NR NO NO 340 NO NO 02/22/16 2420 712 156 551.7 2740 NR NR NR NO NO 497 NO NO OBl30116 3600 174 466 672 2690 NR NR NR NO NO so NO ND OV2Ill 7 2970 371 365 317.2 2L140 3050 $66 414 NO NO 612 ND ND 11 3080 132 456 1437 1830 NR NR NR NO NO 463 NO NO c2120+t8 1640 NO 902 NO 1340 2280 440 NO ND NO 450 NR NR 08/31/18 1320 17 411 NO 1200 2320 409 135 NO NO 464 NR NR 02/19/19 213 NO 5.7 NO 1030 1470 234 118 ND NO 196 NR NR 08/12/19 101 NO 16 19 148 275 32.4 28.4 NO NO 34.6 NO NR 02/04/20 50A NO NO NO 515 lice 125 26.4 NO NO 511 NO NR MW-6 04116/93 ND NO NO _ NO NO _ NR NR NR NO NR NA NR NA 08/11/93 NO ND NO NO 6 NR NR NR 4 NR NA NR NA 04=44 NO NO NO NO ND NR NR NR ND NR NA NR NA O82344 NO NO NO NO NO NR NR MR NO NR NA NR NA 11122N4 _ NO NO ND N❑ ND NR NR NR NO NR NA NR NA 03/13/95 NO ND No Nb ND NR NR NR NO NR NA NR NA 05/16195 NO ND ND ND ND NR NR NR NO NR NA NR NA 11/03103 NS 05/04/04 NS 11/08/07 <10 <1.0 <10 <3.0 1.3 NR NR NR <10 <10 NA NR NA 05/26/08 <1 0 <7.0 j <1 0 1 <3 0 1 1 7 NR NR NR 0.0 1 c1.13 1 NR I NR NA 04116I09 NS 11/08I09 NO NO NO NO 6-0 NR NR NR NO N❑ NO NR 24.7 176728710 NO NO NO NA Q-71 NR NR NR NO ND NO NR 5.0 03707711 _ ND NO NO NO NO NR NR NR NO NR N❑ NR NA 08/02/12 NO NO NO ND NO NR NR NR NO ND ND ND ND 02/26I74 NO ND ND ND ND NR NR NR NO 0-82 ND ND NO 08/25/14 ND ND ND ND ND NR NR NR NO 0.89 ND ND ND 02/09/15 NO NO NO NO ND NR NR NR NO 0.8 ND ND ND 06r17A5 NO NO NO NO ND NR NR NR NO 0.72 ND ND ND 07122,16 NO NO NO NO ND NR NR NR NO 0.14 N❑ NO NO OBW16 _ NO NO I NO NO N❑ NR NR NR ND .74 ND NO NO 02121/17 NO ND ND ND ND NO ND NO ND 0,66 ND NO SO-2 O8/09/17 NO ND ND NO NO NR NR NR ND 0.65 ND NO E 02/20118 ND NO ND ND 27,4 ND ND NO ND ND NO NR NR 08/3108 ND ND ND NO 134 NO NO 52.8 1 2 ND NO NR NR wmaot9 NO ND NO NO 342 NO NO ill) 2 _ _ NO NO NR NR 091t2719 ND NO NO NO 68,3 NO NO 48'.7 ND NO NO ND NR 02/0412Q NO NO NO _ _ ND 150D ND ND 773 6.5 ND NO Nb NR H 1P,olecls1200911090032-01 C.,N Country SlorelRep.r.WR 3-20201Table 4 - Historical Groundwater Page 2 0( 6 Table 4: Summary of Historical Groundwater Analytical Results Carl's Country Store 8952 Davidson Highway Concord, Caborrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Project Number 1090032 ilylical Method --> EPA 602. 601/602 or 6200E EPA 504.1 or 6200E EPA 200 7 or E Analyle---•--> Benzene Toluene Ethyl- Total Methyl-lert- butyl ether tart -Amyl tart. Amylmelhyl larl•Butyl Diisapropyl 1,2- Naphthalene 1,2-Dibromo-elhane Total Lead benzene Xylenes (MTBE) Alcohol ether Alcohol ether (IPE) Dichloroethane (EDS) an r 1 0 600 600 500 20 40 128 10 70 0 4 11 0.02 15 GCL 5 000 280 000 84.500 85 500 20 ODO 40.0DD 128 ODD 10 MG 70 000 400 6 000 50 15 00 Dale (ugll) (ugll) (ug/I) (ugll) (ug/I) (ugll) (ug/1) (ugll) (ugll) (ug/1) (ug/1) (ug1) (ug/p apn e N-7 1 11/08107 1 <1.0 <10 <10 <3-0 1<LO NR NR NR <l0 <10 NA NR NA N M-11 08I12119 NO ND NO NO NO NO NO NO ND NO NO NO NR 02/04/20 _ ND NO I NO I NO 1 07 1 NO I NO I NO NO I NO I NO NO NR 02/26/14 DKY M 17 NS- DRY ]VEST FROM NCI NR NO NR NO NR ND NR NO NR NO NR NO NR NO NO NO NR ND NO ND ND ND WEST FROM NC NO NO NO ND NR ND NR NO NR N5 NR NO NR NO NR ND NR NO NO NO NR NO NO ND 2 NO ub/19/03 1 <10 1 <50 1 -1.p 1 <10 I <5.0 I NH I NR I NK 1 -5.0 1 NR I NA I <1 -0 1 NA 11I03103 1.6 <50 <10 <10 <5.0 NR NR NR 45.0 NR NA <10 NA 05104/04 12 <5 0 <1 0 <2 0 <1 0 NR NR NR <1 0 -0.5 NA -1.0 NA 1110 7 <10 <10 <10 <30 37 NR NR NR <1-0 <1-0 NA NR NA 05125" IA -1.0 <10 -3-.0 <_l0 NR NR NR <1.0 <1-0 NA NR NA 04/10100 121 No ND NO NO NR NR NR NO NR NA NO NA 11/06109 64.6 NO ND ND NO I NR NR NR 11 1.9 1 NO NR NO :7 IQ NO H Tro)ects1200e11090037-01 Cads Country tlore%RapcftWR 3-70701Table 4 - Kslor-1 G—d-ter Peg. 3 0l6 Table 4: Summary or Historical Groundwater Analytical Results Carl's Country Store 8952 Davidson Highway Concord, Cabarrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Pro-ect Number 1090032 Anal lical Method --- > EPA 602 601/602 or 6200E EPA 504A or 6200E EPA 2➢0 7 or 6010 Analyle------:= Benzene Toluene Ethyl- Ethyl- benzene Total Xylenes Melthbutyl other (MTBE) tart -Amyl Alcohol ylme Am tart- yl ether tart-Bulyl Alcohol Diisopropyl ether (WE) 1,2- Dichloroelhane Naphthalene 1�2-Dibromo-ethane (EDS) Total Lead _ _ SaindwOMAC 1.0 800 000 500 20 40 128 10 70 0.4 5 0 67 15 GC l- 5.000 260,000 84 500 85 500 20 D00 4000 128 000 10.000 70.()00 400 6 000 50 15 000 Sample Localion Dale sampled u /I (9) (ug/I) (ugll) (ug/I) (ugll) (ugll) (ug/I) (ugll) (ugll) (ugll) (ug/I) (ugll) (ugll) DMW-1 (Cont.) 02/21/17 NO NO NO NO NO NO NO NO NO NO NO ND ND 08/09/17 NO NO NO NO NO NR NR NR I NO NO NO NO NO 0211011E ND NDI NO I NO I ND ND ND NO ND NO NO NR NR 08131/18 ND ND NO ND NO ND ND I ND I ND NO NO NR NR 02119119 N&• PER REQUEST OF NCDEQ 08/12/19 ND ND _ I NO NO _ NO NO N❑ ND 0.08 DAS ND No NR 02/04/20 NO NO NO ND 141 NO ND NO I50 1 NO NO NR M -3 03@7111 59,5 NP ND NO NA N N 10 2.0 ND ND ND D8102r12 NO NO NO NO N❑ NR NR NR 0.9 NO NO N❑ ND 02/26/14 NO ND NO NO ND NR NR NR ND ND ND NO NO 213/25M4 NO NO NO NO NO NR NR NR ND NO NO NO NO Q2/09/15 NO NO NO NO NO NR NR NR NO NO NO NO NO 98/17/15 NO NO NO NO NO NR NR NR NO NO NO NO NO 02/22/16 _ NO NO NO NO NO NR NR NR NO NO NO NO NO 08/30116 14.0 NO NO NO NO NR NR NR 2.8 1-7 NO NO NO 0W1117 a$: NO ND ND N❑ NO ND NO 7.3 5.1 ND ND ND _ 08e091t7. 0.4 ND ND ND NO NR I NR NIZ 9.4 6.6 NO ND ND 021701i9 52,5 ND ND NO ND 123 ND NO 9.2 8-E RD NR NR Q8131 11 B 37.5 ND NO NO ND 141 ND 10.2 10.3 7A ND NR NR 02/19/19 42 RD NU NO ND 199 ND 13.0 116 1DA ND NR NR 09/12/19 61.4 NO ND ND 14.3 385 ND 53 2.2.3 17.3 ND ND NR 02/04/20 32.3 ND ND ND 65.7 238 ND 112 139 11.0 ND ND NR DMW-4 08/16/11 1560 NO NO 13 ND NR NR NR 31-3 43.E NO ND ND 08/02112 111 ND ND ND ND NR NR NR 8 3 13.1 ND ND ND 02126114 60.3 ND ND NO NO I NR NR RR a.4 14.2 ND NO ND M125114 RD NO NO No ND NR NR NR 57 9.6 ND NO ND 02*9116 372 ND NO NO ND NR NR NR 4 0.7 ND NO ND 08/17115 921 NO ND NO ND NR NR NR 4.6 & ND ND ND 02/22/16 23.7 NO ND ND ND NR NR NR 2.a 3 ND ND ND 08/30/16 7.2 ND ND ND ND NR NR NR 12 1.3 ND ND ND 02/21/17 82.2 ND ND ND NO NO ND NO 4.1 4.1 NO NO ND 118At9117 ND NO No NO 1350 NA NR NR 121 ND NO ND ND 0212W8 9.5 NO NO N❑ NR NO NO 0-72 1. ND NR NR 08/31/18 ND ND NO _ _NO ND ND ND Ntl NO ND ND NO NR #R 02/19/19 _- - NS-PERREQUEST FROM NCOEQ 08/12/19 NO NO ND NO NO ND ND ND ND 2..9 ND ND NR 02/04/20 N0 ND ND ND ND ND ND ND ND L6 _ ND ND NR DMW-5 DVIW12 - 197 ND NO NO ND NR NR NR 7,9 13.9 NO NO NO 02/20/12 194 2 5 NO NO NO NR NR NR T5 12,2 NO NO NA 06/02/12 _ 78.4 NO NO NO ND NR NR _ NR 7.2 11.4 NO NO ND 02/26114 27.2 NO NO NO ND NR NR NR 4 5.1 NO NO ND OEt25714 -2.1 NO ND NO RD NR NR NR 2.4 2.4 ND NO ND 021D91t5 21.5 NO NO NO NO NR NR NR 2.3 3,7 NO NO ND 08117115 52. ND NO NO - RD NR NR NR 1.5 2 NO NO NO 02/22/16 2 NO NO NO NO NR NR NR 22 2.4 NO NO NO 08/30/16 1.0 12 ND_ NO ND NR NR NR 6 5.9 ND ND ND 02/21/17 2.2 ND ND ND _ ND 128 ND ND 66 8..4 _ ND ND ND 08109117 075 17 _ ND ND ND NR NR NR 6.3 9.1 NO NO N 0ZQW"1E. 3.2 NO NO No ND n1i NO 15.1 11.5 13 NO NR NR D8131118 8.2 NO NA NO ND 275 NO 10.4 141 16.3 ND NR NR _ 02YI9019 17 ND ND NO ND 396 ND 19.3 14.8 13A NO NR NR 08/12/19 ND NO ND NO ND ND ND ND N❑ ND NO ND NR 02/04/20 18.2 ND ND ND ND 400 ND ND 17.6 15.3 ND ND NR WSW-T 04v"7 NO ND NO NO ND NR NR NR ND NO NA NR NA 11/12J97 NO ND NO NO ND NR NR NR N❑ NR NA NR NA 02/28/00 NO NO ND NO ND NR NR NR ND NR NA NR NA 02/23/01 ND ND ND ND ND NR NR NR NO ND NA NR NA 03/07/11 Wall Abandoned WSW-2- 05104/04 •10 �5.0 -10 <2.0 r10 NR NR NR -1.0 <0.50 NA .1.0 NA 05/26/08 c10 <1.0 -1.0 <30 <10 NR NR NR <10 <10 NA NR NA 04116/09 NO NO NO NO NO NR NR NR NO NO NO NO NR 06128/10 NO ND NO NO ND NR NR NR NO ND NO NR NO 0 NLI2 ND ND NO NO ND NR NR NR ND NO NO NR ND 02l261'14 NO ND NO RD ND NR NR NR ND ND NO NQ ND 08/25/14 NO N❑ ND NO ND NR NR NR NO ND NO ND ND 02/09/15 Nat Sampled- No Power to Woo 001T71T5 Not Slom od- No Poworto Wail WSW-2(Conl) 02/22/16 Net Sampled -Na PowDr to Weil 08/30116 _ Nei S6fl1 ad - No Power to Wee 02/21/17 Not Sampled - No Power la Wall 08/09/17 - - - NotSamplad- Walllibandoread WSW-3 04/16/09 NO NO NO NO NO NR NR _ NR NO NO NO NO NR "WO RD ND ND RD ND NR NR NR ND NO NO NR 20.5 01d0a112 ND ND NO ND NO NR NR NR ND ND ND NR 25.8 02/26/14 NO NO NO NO NO NR NR NR NO ND NO NO ND 08125/14 NO NO NO NO NO NR NR NR NO ND NO NO ND 02/09/15 NO NO NO NO NO NR NR NR ND NO NO ND NO 08117/15 NO NO NO NO NO NR NR NR NO ND ND NO NO 02/22116 Not San ad - Not Requiredby NCDEQ 08130/16 m Not SA led - No Pawlr to Well 02/21/17 NO NO NO ND NO NO ND ND ND I N❑ NO NO 52 09709r17 _ Not Sam lod - No P7r to Well H \Prolec1s\2009\1090D32-D1 CM, Country Store\RBp,,t AMR 3-202MTable 4 - Hislonc.l Groundwater Per 4.10 Table 4: Summary of Historical Groundwater Analytical Results Carl's Country Store 8952 Davidson Highway Concord, Cobarrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Pro'ect Number 1090032 Analytical Method --> _ _ EPA 602 601/602 or 6200E EPA 504-1 or 6200E EPA 200-7 or 6010 Analyle---•--> Benzene Toluene Ethyl- benzene Total Xylenes Methyl -tent- bulyl ether (MTBE) led -Amyl Alcohol lerl- Amylmethyl ether [art -Butyl Alcohol other (l pyl ether (IPE) 1 oe Dichloroelhane Naphthalene 1,2-Dib EDB)ethane (EDB) Total Lead Ian ar 1.0 600 600 500 20 40 120 10 70 0A 6 0.02 1S GCt 5,2W 78p 000 84 500 e6-500 20 OM 40 000 128 000 10 Qo 70,000 400 6.000 50 15=0 Sample Location Dale Sampled (ug/I) (ugll) (ug/1) (ugll) (ugll) (ug/1) (ug/l) (ugll) (ug/l) (ug/1) (ug/1) (ug/1) (ugll) WSW-4 05/04/04 <1,0 796 1 <10 <20 <1.0 NR NR NR <1.0 <0.50 NA <10 NA 05/28/08 <10 1 <10 1 10 <3,0 <1.0 NR NR NR <1.0 <10 NA NR NA 04116I09 ND I NO I NO NO ND NR NR NR NO NO ND ND NR _ 06/28/10 Not SaM led due to No Water Flaw 01112/12 - Not Saml 4ad duo IC NO Water Flow 42rW2 ND ND ND ND ND NR NR NR ND NO _ ND ND ND WI M14 ND ND ND ND NO NR NR NR ND ND NO NO ND OW25114 NO ND ND ND No NR NR NR NO NO NO NO ND 02/09/15 NO NO ND NO NO _ NR NR NR NO ND NO NO No 08/17/15 NO NO NO ND NO NR NR NR NO ND NO NO NO 02/22/16 Not Sam ad - Not Rs ulrad by NCDE4 01130f18 NI NO NO NO N0 f.1R NR _ NRMND ND NO D N 0272ir17 Mo ND NI] ND NO ND- NO NO NO No NO NO 08109/17 NO NO NO NO NO NR NR NFtNO NO NO NO ND - WSW-6 05A4 410 -50 <1.0 <7,O 41,0 NR NR NR .0.60 .14 MA 11YQ8107 <10 <10 <10 <3.0 <1-0 NR NR NR <10 NA NR NA 04/16/09 NO NO NO NO ND NR NR NRNO NO NO NO NR 06128/10 NO NO NO NO ND NR NR NIR NO NO NR NO OM14 NO Nil NO ND ND NR NR NR NO NO ND NO 09 Wt4 ND ND ND ND No NR NR NR NO NO NO NO 0d1 05 NO NO NO ND ND NR NR NH NO I NO I NO I NO 08/17/15 ND NO NO I ND I ND NR I NR I NR I NO I NO Np I NO I NO 02122/16 _ Not Sam lad - Net Re rnd b NC13 4 08/30/16 Rol Sam led • Not Ra iced bX NCDEQ 02/21/17 Nul Sam lad -N(nRaqWFadbVNCOE0 aawi 17 NO N.0 NO ND NO NR I NR NR NO NO ND ND ND WSW-7 05104004 <1.0 <fr0 <1,0 <20 r1.0 NR NR NR 0A <0.50 NA <10 NA 1 VOW7 <1.0 <1.0 <1_1) <3D <1-0 NR NR NR <1.0 st 0 NA NR NA 04116109 ND NO NO ND NO NR NR NR ND ND NO ND NR 06/28/10 ND NO NO ND NO NR NR NR ND ND ND NR ND Q2/26114 NO NO ND NO NO NR NR NR ND ND ND No a? 08/25/14 ND NO NO NO NO NR NR NR ND ND NO ND NO 02/09115 NO ND ND ND No NR NR NR ND NO NO ND ND O6 IMS ND _ NO ND ND ND NR NR 1 NR I N❑ I ND i ND ND ND 07/2 116 NIX Safi led - Not R ulred b NCOEC 08/30/tB Not Sam lad - Nol R uLrad byNCOEO 02/21/17 Not Sam led - Nol R wma by NCOEQ 08JO9117 NO NO NO ND NR NR MR NO XD NO ND ND WSW-8 05/04/04 <10 <50 <7.0 e2,1) <10 NR NR NR <1.0 < NA. 04 NA 05126/08 <10 -10 s1,0 <3-0 <10 NR NR NR <10 <1.Q NA. NR NA 0"111110 NO NO NO NO NO NR NR NR NO ND NO NR NO 0-1,11d _ NO ND NO NO NO NR NR NR NO ND NO _ NO _ ND _ 08125/14. NO NO ND NO NO NR NR NO ND NO NO ND Q2/09115 NO ND ND NO _ NO _NR NR NR NR NO ND NO NO ND 08/17/15 ND NO ND I NO NO I NR I NR NR I NO I NO No ND NO 02I22M6 Net Sampled . Neil R vulredb.NCDEO MUM Not Sampled - Not Reuued by NCOEO 07Y7.1117 "SPm led - NOI Rc u dbyNCOE0 WSW-9 0510d104 41.0 <5.0 41,9 <2.0 1-0 NR NR NR<1 - NA 05/281Qa <1.0 <1,Q <10 <30 c10 NR NR NR <10 <7.0 NA NR NA 06/28/10 NO NO ND NO NO NR NR NR NO NO NO NR ND 01/06/12 NO NO ND NO NO NR NR NR 14D NO No NR NO 02/26/14 3.3 NO NO NO ND NR NR NR ND ND NO _ NO NO 08125/14 PiD ND NO NO NO NR NR NR NO _ _ ND ND NO ND 0=9115 ND NO NO NO ND NR NR NR NO ND ND. ND NO 0611'7i15 NO ND NO NO ND NR NR NR NO ND NO I NO NO G2122116 Not Sam fed-NOIRo uiredh NCDEG 08/30/16 NO NO NO NO ND NR NR I NR RD NO NO NO ND 02/21/17 NO NO NO NO ND ND NO ND NO No NO NO NO 08109117 ND ND N4 NO NO NR NR NR NO ND NO NO NO 02/20/18 ND NO NO NO NO NO NO NO NO ND NO NR NR 08/31/18 NO NO NO NO _ NO ND NO ND ND NO NO NR NR 02/19/19 NO N❑ NO ND ND ND ND ND NO No ND NR NR OE112119 NO ND NO No ND ND ND NO =m NO t1D NO NO NR 02104/29 NO ND NO NO ND NO ND NO NO NO NO NO NR H 1Piolec1s12WM 1090032-01 Ca,rs Counby SIO,e1RepO %MR 3-2020\Table 4 - Hislpncal Gr nd ler Page 5 W 6 Table 4; Summary of Historical Groundwater Analytical Results Carl's Country Store 8952 Davidson Highway - Concord, Cabarrus County, North Carolina Facility ID Number 0-007470 Incident Number 9362 Shield Project Number 1090032 Analytical Method ---> EPA 602, 601/602 or 6200B EPA 506.1 w t}200B EPA 200] or 6010 Anal a �> N Benzene Toluene Ethyl- benzene Total Xylenes Methyl-lerl- butyl her (MTBE) tart -Amyl Alcohol lert- Ama h ethylether ether g0000 Diisopropyl (IPE) 1,2- Dichloroethane Naphthalene 1,2-Dibrvmo-ethane (EDB) Total Lead .. t0a 10 600 600 500 20 40 128 70 0.4 0 OA2 i5 GCL 5 _ 260,000 84 500 85 500 20 000 40.000 128,000 70 000 400 6 000 50 15 000 Sample Location Dale Sampled (ug/) (ugll) (ugl0 (uglq (ugll) (ugll) (ug/1) (ug/1) (ug/1) (ug11) (ug/I) (ugll) (ugll) WSW-17 05/04/04 -10 <50 <10 -20 -10 NR NR NR <10 <0.50 NA <10 NA 0512881E 0.0 -to 00 e3,0 11.0 NR NR NR <10 <10 NA NR NA 06125110 ND NO NO NO NA NR NR NR NO NO NO NR 14.6 02/26/14 NO NO NO NO NO NR NR NR NO NO NO NO NO 08125/14 NO NO ND NO NO NR NR NR NO NO ND No NO 02/09M5 _ NO NO ND ND NO NR NR NR NO NO No NO N13 08/17/15 ND NO ND NO I NO I NR NR NR NO ND NO NO ND 02/22/16 Noi Sam ad - Not Ra irod b NCOEQ 08/30/16 NotNo! ulrad 19 NCOEQ 02/21/17 Not Sum ad - N01 Re uirad NCOEQ 08/09117 ND ND NO ND ND NR NR NR NO NO NO ND ND vvsw-18 06/28/10 not sampled out to No wouir Flaw _ 02126114 Not Sam Ie0 due 10 No WolofFlow 08/25/14 - - Not urn !ed Unable l0 Locate 6210911E _ _ No! s¢m lad Unahla 1a L 1e 01V1711E No! aam ad- Unable tb Lor to 62127116 Not Sam lad - N01 R tared b NCDEQ 98C3011B Not Sam ad- Na sll Vialble on Proeqq 02/21/17 Not Sam - No Wall Vislbf0 on Pfopa TRIP BLANK W2E1to NO NO NO NO NO NR NR NR NO NO ND NR NR 01/06/t2 ND NO ND NO ND NR NR NR NO NO NO NR NR 02/26M4 ND NO ND ND ND NR NR NR ND NO ND NR NR 08/25/14 ND NO NO NO NO NR NR NR NO NO NO ND NR 02/09/15 NO NO NO ND NO NR NR NR NO NO NO ND NR 08117/15 NO NO NO NO ND NR NR NR ND NO ND NO _ NR 0212211Li NO NO NO NO NO NR NR NR NO NO NO NO NR oEf"30ri6 N❑ NO No ND NO NR NR NR NO NO NO NO NR 02/21/17 NO NO NO NO NO NO NO NO ND NO NO NO NR 08I09/17 _ ND NO NO ND ND NR NR. NR ND NO NO NO NR 00/31/18 ND ND NO ND NO NR NR NR NO NO NO NO NR 06/12119 NO NO NO ND ND ND NO ND ND NO NO NO NR 02/04/20 ND NO ND NO ND ND NO NO NO NO NO NO NR ug/I - micrograms per liter NU- Not detected at or above laboratory method report limit NS = Not Sampled NR = Analysis Not Requested NA = Data Not Available NE = Not established < = Less than the laboratory method report limit NCDEO - North Carolina Department of Environmental Quality (formerly North Carolina Department of Environment and Natural Resources) 2L Standard = NCDENR-North Carolina Administrative Code Title 15A Subchapler 2L Class GA Groundwater Standards IMAC= Interim Maximum Allowable Concentrations GCL = NCDENR-North Carolina Administrative Code Title 15A Subchapter 2L Standard for Risk -Based Maximum Gross Contamination Levels for Groundwater BOLD denotes concentrations above 15A NCAC 2L Standards or IMACs Data prior to 4/1612009 reported by others H 1P,ol.cls%21x1911090032 01 Ca„s Coynlry Sloi01R.pWr1s1MR 3-20201Table 4 - Hls.11 al Grodndw W, P.O. 6 0l 6 GRAPHS) Concentration vs. Time (MW-2) Carl's Country Store 1600 1400 1200 1000 7 C 800 C d c 600 V 400 200 C pad ��N5�- zP�6'I aPQ ,�O �h�,�, ,� ,��t,�NIIIII % J� Date 84.00 83.00 82.00 81.00 w m m 80.009 C O 'a+ 79.00 d LU 78.00 !a 3 77.00 O L_ 76.00 a 75.00 74.00 73.00 t Benzene --�i--p Toluene Ethyl -benzene f Total Xylenes -- Methyl-tert-butyl ether (MTBE) t Groundwater Elevation (feet) Concentration vs. Time (MW-4) Carl's Country Store 7000.0 5000.0 IM _ m 4000.0 o 3000.0 V 44/1/414 1000.0 0.0 as a ab oa p� oo pa ,�° �N �ti No Nt,` Na No NA Na Gy Gy G"` G*' G� G1G� p G� G� G� G� G� Gy G� 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 Date 84.00 82.00 80.00 _ O w d fl:111I1110 m eo a c 76.00 0 �mflf ♦ IFMIII) t-Benzene --a-- Methyl-tert-butyl ether (MTBE) - Groundwater Elevation (feet) Concentration vs. Time (MW-5) Carl's Country Store 7000 =J5000 Of 7 C O %4000 v3000 2000 1000 0 0 0A 0 0 00 O`L (:�5 O� O) O°i O� DO �O ?0�J\ �)`�c PQ� ��\ 4°� ��g+ PQ�,)`,Q PQS �J cp*,� Date 84.00 83.00 82.00 A ffeA: r m m 80.00 cc w+ !0 79.00 m W m 78.00 0 3 a c 77.00 'o 76.00 75.00 74.00 73.00 Benzene ---f— Toluene Ethyl -benzene t Total Xylenes Methyl-tert-butyl ether (MTBE) �— Groundwater Elevation (feet) 1600 1400 1200 ;1000 IM MI c O 0 600 400 200 Concentration vs. Time (MW-6) Carl's Country Store Date 85.00 84.00 83.00 82.00 m m 81.00 d 80.00 MU d 3 79.00 0 78.00 77.00 76.00 75.00 f 1,2-Dichloroethane —■— Methyl-tert-butyl ether (MTBE) --+— Groundwater Elevation (feet) Concentration vs. Time (MW-10) Carl's Country Store 120 100 M 40 20 P O Q P O Q' P O PQ P O W P O P P O Q' P O P Date 84.00 82.00 m C Q 8&00 � d W d M 78.00 c 7 O a 74.00 72.00 f Benzene --a— Naphthalene — Groundwater Elevation (feet) 80 70 60 20 10 0 Concentration vs. Time (DMW-3) Carl's Country Store � P SNc�' �o�' PP �m� e<0 -S Oyu * & lac Pao; �ac�' S§ �a,' ?9 �m� ee, Date mom 70.00 60.00 m c O 50.00 d w 40.00 `m as 3 v 30.00 O 20.00 10.00 1 10 Benzene t Groundwater Elevation (feet) 1,2-Dichloroethane m0 ECO H P vj c > 3 c O OU �+ H c � (DU v C O U 0 0 m W t m N O m 3 N O N 0I+I0 1 C2 I (;aa;) u014ena13 ja;eMpunojE) N co - OCOO LO 't M N O LO o L o Lo N N +- (-li6n) uol;ej;ueouoC) CSC '9'y 8z ba A`J S ad 0 A� �d 9`v/ °O A2" DO. AW, O AZ'9 a o y ba e., S o� G� o �G a^ APPENDIX A Carl's Country Store Calibration and Field Measurment Log Field Meter YSI Pro Plus Calibration Standard Pre -Calibration Read Calibration Read pH 7 7 7.01 7.00 p H 4 4 4.00 4.00 pH 10 10 9.98 10.00 Spec Cond (us/cm) 1413 1415 1413 ORP (mVolts) 200 202 200 Field Measuremnt Log ID DO pH Spec Cond (us/cm) Temp (IQ ORP (mV) M W-1 3.10 5.32 86.4 19.5 -51.2 MW-2 1.31 5.81 414 20.3 -122.1 M W-4 1.15 5.76 310.9 20.3 -91.6 MW-5 1.03 5.86 476.4 19.6 -133.5 M W-6 1.03 6.53 277.6 20.4 -74.2 M W-7 3.71 6.14 929 19.5 -80.6 M W-9 1.44 5.75 210.8 19.2 -86.8 MW-10 0.91 6.03 498.5 20.1 -140.8 DMW-1 1.63 6.86 549.9 19.8 -59.3 DMW-3 1.82 6.08 354.2 18.9 -62.5 DMW-4 3.89 6.33 365.8 20.2 -24.4 DMW-5 1.66 6.51 257.7 20.2 -82.2 WSW-9 4.46 6.34 112.5 16.2 3.9 APPENDIX B leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 March 02, 2020 Kevin Stachura Shield Engineering, Inc. 4301 Taggart Creek Road Charlotte, NC 28208 RE: Project: Carl's Country Store Pace Project No.: 92463689 Dear Kevin Stachura: Enclosed are the analytical results for sample(s) received by the laboratory on February 04, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This revision was issued on 3/2/20 to correctly report the requested analyte list for sample WSW-9. If you have any questions concerning this report, please feel free to contact me. Sincerely, ". f'o'k-9--.? Amanda Payne amanda.payne@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 48 lacmnalyfica(' www,pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Carl's Country Store Pace Project No.: 92463689 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Carl's Country Store 92463689 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92463689001 MW-1 SM 6200B CL 69 PASI-C 92463689002 MW-2 SM 6200B CL 69 PASI-C 92463689003 MW-4 SM 6200B CL 69 PASI-C 92463689004 MW-5 SM 6200B CL 69 PASI-C 92463689005 MW-6 SM 6200B CL 69 PASI-C 92463689006 MW-7 SM 6200B CL 69 PASI-C 92463689007 MW-9 SM 6200B CL 69 PASI-C 92463689008 MW-10 SM 6200B CL 69 PASI-C 92463689009 DMW-1 SM 6200B CL 69 PASI-C 92463689010 DMW-3 SM 6200B CL 69 PASI-C 92463689011 DMW-4 SM 6200B CL 69 PASI-C 92463689012 DMW-5 SM 6200B CL 69 PASI-C 92463689013 WSW-9 SM 6200B CL 63 PASI-C 92463689014 TRIP BLANK SM 6200B CL 69 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-1 Lab ID: 92463689001 Collected: 02/04/20 12:52 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 15:08 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 15:08 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 15:08 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 15:08 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 15:08 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 15:08 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 15:08 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 15:08 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 15:08 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 15:08 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 15:08 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 15:08 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 15:08 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 15:08 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 15:08 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 15:08 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 15:08 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 15:08 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:08 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:08 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 15:08 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 15:08 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 15:08 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 15:08 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:08 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:08 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:08 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 15:08 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 15:08 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 15:08 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 15:08 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:08 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:08 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:08 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 15:08 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:08 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 15:08 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:08 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:08 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 15:08 108-20-3 Ethanol ND ug/L 200 1 02/10/20 15:08 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 15:08 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 15:08 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 15:08 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 15:08 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 15:08 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 15:08 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-1 Lab ID: 92463689001 Collected: 02/04/20 12:52 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Naphthalene ND ug/L 2.0 1 02/10/20 15:08 91-20-3 n-Propylbenzene ND ug/L 0.50 1 02/10/20 15:08 103-65-1 Styrene ND ug/L 0.50 1 02/10/20 15:08 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 15:08 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 15:08 79-34-5 Tetrachloroethene ND ug/L 0.50 1 02/10/20 15:08 127-18-4 Toluene ND ug/L 0.50 1 02/10/20 15:08 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 02/10/20 15:08 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 02/10/20 15:08 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 02/10/20 15:08 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 02/10/20 15:08 79-00-5 Trichloroethene ND ug/L 0.50 1 02/10/20 15:08 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 02/10/20 15:08 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 02/10/20 15:08 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 02/10/20 15:08 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 02/10/20 15:08 108-67-8 Vinyl chloride ND ug/L 1.0 1 02/10/20 15:08 75-01-4 m&p-Xylene ND ug/L 1.0 1 02/10/20 15:08 179601-23-1 o-Xylene ND ug/L 0.50 1 02/10/20 15:08 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 % 70-130 1 02/10/20 15:08 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 02/10/20 15:08 460-00-4 Toluene-d8 (S) 104 % 70-130 1 02/10/20 15:08 2037-26-5 Date: 03/02/2020 12:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-2 Lab ID: 92463689002 Collected: 02/04/20 13:01 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol 1880 ug/L 1000 10 02/10/20 19:07 75-85-4 tert-Amylmethyl ether ND ug/L 100 10 02/10/20 19:07 994-05-8 Benzene 5.4 ug/L 5.0 10 02/10/20 19:07 71-43-2 Bromobenzene ND ug/L 5.0 10 02/10/20 19:07 108-86-1 Bromochloromethane ND ug/L 5.0 10 02/10/20 19:07 74-97-5 Bromodichloromethane ND ug/L 5.0 10 02/10/20 19:07 75-27-4 Bromoform ND ug/L 5.0 10 02/10/20 19:07 75-25-2 Bromomethane ND ug/L 50.0 10 02/10/20 19:07 74-83-9 M1 tert-Butyl Alcohol 7360 ug/L 200 10 02/10/20 19:07 75-65-0 M1 n-Butylbenzene ND ug/L 5.0 10 02/10/20 19:07 104-51-8 sec-Butylbenzene ND ug/L 5.0 10 02/10/20 19:07 135-98-8 tert-Butyl benzene ND ug/L 5.0 10 02/10/20 19:07 98-06-6 tert-Butyl Formate ND ug/L 200 10 02/10/20 19:07 762-75-4 L1,P5 Carbon tetrachloride ND ug/L 5.0 10 02/10/20 19:07 56-23-5 Chlorobenzene ND ug/L 5.0 10 02/10/20 19:07 108-90-7 Chloroethane ND ug/L 10.0 10 02/10/20 19:07 75-00-3 Chloroform ND ug/L 5.0 10 02/10/20 19:07 67-66-3 Chloromethane ND ug/L 10.0 10 02/10/20 19:07 74-87-3 2-Chlorotoluene ND ug/L 5.0 10 02/10/20 19:07 95-49-8 4-Chlorotoluene ND ug/L 5.0 10 02/10/20 19:07 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 10.0 10 02/10/20 19:07 96-12-8 Dibromochloromethane ND ug/L 5.0 10 02/10/20 19:07 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 10 02/10/20 19:07 106-93-4 Dibromomethane ND ug/L 5.0 10 02/10/20 19:07 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 10 02/10/20 19:07 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 10 02/10/20 19:07 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 10 02/10/20 19:07 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 10 02/10/20 19:07 75-71-8 1,1-Dichloroethane ND ug/L 5.0 10 02/10/20 19:07 75-34-3 1,2-Dichloroethane ND ug/L 5.0 10 02/10/20 19:07 107-06-2 1,1-Dichloroethene ND ug/L 5.0 10 02/10/20 19:07 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 10 02/10/20 19:07 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 10 02/10/20 19:07 156-60-5 1,2-Dichloropropane ND ug/L 5.0 10 02/10/20 19:07 78-87-5 1,3-Dichloropropane ND ug/L 5.0 10 02/10/20 19:07 142-28-9 2,2-Dichloropropane ND ug/L 5.0 10 02/10/20 19:07 594-20-7 1,1-Dichloropropene ND ug/L 5.0 10 02/10/20 19:07 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 10 02/10/20 19:07 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 5.0 10 02/10/20 19:07 10061-02-6 Diisopropyl ether 33.0 ug/L 5.0 10 02/10/20 19:07 108-20-3 Ethanol ND ug/L 2000 10 02/10/20 19:07 64-17-5 Ethylbenzene ND ug/L 5.0 10 02/10/20 19:07 100-41-4 Ethyl-tert-butyl ether ND ug/L 100 10 02/10/20 19:07 637-92-3 Hexachloro-1,3-butadiene ND ug/L 20.0 10 02/10/20 19:07 87-68-3 Isopropylbenzene (Cumene) ND ug/L 5.0 10 02/10/20 19:07 98-82-8 Methylene Chloride ND ug/L 20.0 10 02/10/20 19:07 75-09-2 Methyl-tert-butyl ether 1210 ug/L 5.0 10 02/10/20 19:07 1634-04-4 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-2 Lab ID: 92463689002 Collected: 02/04/20 13:01 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Naphthalene ND ug/L 20.0 10 02/10/20 19:07 91-20-3 n-Propylbenzene ND ug/L 5.0 10 02/10/20 19:07 103-65-1 Styrene ND ug/L 5.0 10 02/10/20 19:07 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 10 02/10/20 19:07 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 5.0 10 02/10/20 19:07 79-34-5 Tetrachloroethene ND ug/L 5.0 10 02/10/20 19:07 127-18-4 Toluene ND ug/L 5.0 10 02/10/20 19:07 108-88-3 1,2,3-Trichlorobenzene ND ug/L 20.0 10 02/10/20 19:07 87-61-6 1,2,4-Trichlorobenzene ND ug/L 20.0 10 02/10/20 19:07 120-82-1 1,1,1-Trichloroethane ND ug/L 5.0 10 02/10/20 19:07 71-55-6 1,1,2-Trichloroethane ND ug/L 5.0 10 02/10/20 19:07 79-00-5 Trichloroethene ND ug/L 5.0 10 02/10/20 19:07 79-01-6 Trichlorofluoromethane ND ug/L 10.0 10 02/10/20 19:07 75-69-4 1,2,3-Trichloropropane ND ug/L 5.0 10 02/10/20 19:07 96-18-4 1,2,4-Trimethylbenzene ND ug/L 5.0 10 02/10/20 19:07 95-63-6 1,3,5-Trimethylbenzene ND ug/L 5.0 10 02/10/20 19:07 108-67-8 Vinyl chloride ND ug/L 10.0 10 02/10/20 19:07 75-01-4 m&p-Xylene ND ug/L 10.0 10 02/10/20 19:07 179601-23-1 o-Xylene ND ug/L 5.0 10 02/10/20 19:07 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 97 % 70-130 10 02/10/20 19:07 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 10 02/10/20 19:07 460-00-4 Toluene-d8 (S) 102 % 70-130 10 02/10/20 19:07 2037-26-5 Date: 03/02/2020 12:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-4 Lab ID: 92463689003 Collected: 02/04/20 12:53 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 15:27 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 15:27 994-05-8 Benzene 1.6 ug/L 0.50 1 02/10/20 15:27 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 15:27 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 15:27 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 15:27 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 15:27 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 15:27 74-83-9 tert-Butyl Alcohol 182 ug/L 20.0 1 02/10/20 15:27 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 15:27 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 15:27 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 15:27 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 15:27 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 15:27 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 15:27 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 15:27 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 15:27 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 15:27 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:27 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:27 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 15:27 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 15:27 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 15:27 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 15:27 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:27 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:27 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:27 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 15:27 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 15:27 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 15:27 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 15:27 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:27 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:27 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:27 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 15:27 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:27 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 15:27 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:27 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:27 10061-02-6 Diisopropyl ether 2.2 ug/L 0.50 1 02/10/20 15:27 108-20-3 Ethanol ND ug/L 200 1 02/10/20 15:27 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 15:27 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 15:27 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 15:27 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 15:27 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 15:27 75-09-2 Methyl-tert-butyl ether 118 ug/L 0.50 1 02/10/20 15:27 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-4 Lab ID: 92463689003 Collected: 02/04/20 12:53 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Naphthalene ND ug/L 2.0 1 02/10/20 15:27 91-20-3 n-Propylbenzene ND ug/L 0.50 1 02/10/20 15:27 103-65-1 Styrene ND ug/L 0.50 1 02/10/20 15:27 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 15:27 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 15:27 79-34-5 Tetrachloroethene ND ug/L 0.50 1 02/10/20 15:27 127-18-4 Toluene ND ug/L 0.50 1 02/10/20 15:27 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 02/10/20 15:27 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 02/10/20 15:27 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 02/10/20 15:27 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 02/10/20 15:27 79-00-5 Trichloroethene ND ug/L 0.50 1 02/10/20 15:27 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 02/10/20 15:27 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 1 02/10/20 15:27 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 1 02/10/20 15:27 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 02/10/20 15:27 108-67-8 Vinyl chloride ND ug/L 1.0 1 02/10/20 15:27 75-01-4 m&p-Xylene ND ug/L 1.0 1 02/10/20 15:27 179601-23-1 o-Xylene ND ug/L 0.50 1 02/10/20 15:27 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 70-130 1 02/10/20 15:27 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 02/10/20 15:27 460-00-4 Toluene-d8 (S) 108 % 70-130 1 02/10/20 15:27 2037-26-5 Date: 03/02/2020 12:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-5 Lab ID: 92463689004 Collected: 02/04/20 13:11 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol 1100 ug/L 500 5 02/11/20 22:00 75-85-4 tert-Amylmethyl ether 125 ug/L 50.0 5 02/11/20 22:00 994-05-8 Benzene 50.4 ug/L 2.5 5 02/11/20 22:00 71-43-2 Bromobenzene ND ug/L 2.5 5 02/11/20 22:00 108-86-1 Bromochloromethane ND ug/L 2.5 5 02/11/20 22:00 74-97-5 Bromodichloromethane ND ug/L 2.5 5 02/11/20 22:00 75-27-4 Bromoform ND ug/L 2.5 5 02/11/20 22:00 75-25-2 Bromomethane ND ug/L 25.0 5 02/11/20 22:00 74-83-9 tert-Butyl Alcohol ND ug/L 100 5 02/11/20 22:00 75-65-0 n-Butylbenzene 2.9 ug/L 2.5 5 02/11/20 22:00 104-51-8 sec-Butylbenzene 3.9 ug/L 2.5 5 02/11/20 22:00 135-98-8 tert-Butyl benzene ND ug/L 2.5 5 02/11/20 22:00 98-06-6 tert-Butyl Formate ND ug/L 100 5 02/11/20 22:00 762-75-4 Carbon tetrachloride ND ug/L 2.5 5 02/11/20 22:00 56-23-5 Chlorobenzene ND ug/L 2.5 5 02/11/20 22:00 108-90-7 Chloroethane ND ug/L 5.0 5 02/11/20 22:00 75-00-3 Chloroform ND ug/L 2.5 5 02/11/20 22:00 67-66-3 Chloromethane ND ug/L 5.0 5 02/11/20 22:00 74-87-3 2-Chlorotoluene ND ug/L 2.5 5 02/11/20 22:00 95-49-8 4-Chlorotoluene ND ug/L 2.5 5 02/11/20 22:00 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 5 02/11/20 22:00 96-12-8 Dibromochloromethane ND ug/L 2.5 5 02/11/20 22:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.5 5 02/11/20 22:00 106-93-4 Dibromomethane ND ug/L 2.5 5 02/11/20 22:00 74-95-3 1,2-Dichlorobenzene ND ug/L 2.5 5 02/11/20 22:00 95-50-1 1,3-Dichlorobenzene ND ug/L 2.5 5 02/11/20 22:00 541-73-1 1,4-Dichlorobenzene ND ug/L 2.5 5 02/11/20 22:00 106-46-7 Dichlorodifluoromethane ND ug/L 2.5 5 02/11/20 22:00 75-71-8 1,1-Dichloroethane ND ug/L 2.5 5 02/11/20 22:00 75-34-3 1,2-Dichloroethane ND ug/L 2.5 5 02/11/20 22:00 107-06-2 1,1-Dichloroethene ND ug/L 2.5 5 02/11/20 22:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.5 5 02/11/20 22:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.5 5 02/11/20 22:00 156-60-5 1,2-Dichloropropane ND ug/L 2.5 5 02/11/20 22:00 78-87-5 1,3-Dichloropropane ND ug/L 2.5 5 02/11/20 22:00 142-28-9 2,2-Dichloropropane ND ug/L 2.5 5 02/11/20 22:00 594-20-7 1,1-Dichloropropene ND ug/L 2.5 5 02/11/20 22:00 563-58-6 cis-1,3-Dichloropropene ND ug/L 2.5 5 02/11/20 22:00 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 2.5 5 02/11/20 22:00 10061-02-6 Diisopropyl ether ND ug/L 2.5 5 02/11/20 22:00 108-20-3 Ethanol ND ug/L 1000 5 02/11/20 22:00 64-17-5 Ethylbenzene ND ug/L 2.5 5 02/11/20 22:00 100-41-4 Ethyl-tert-butyl ether ND ug/L 50.0 5 02/11/20 22:00 637-92-3 Hexachloro-1,3-butadiene ND ug/L 10.0 5 02/11/20 22:00 87-68-3 Isopropylbenzene (Cumene) 5.0 ug/L 2.5 5 02/11/20 22:00 98-82-8 Methylene Chloride 10.2 ug/L 10.0 5 02/11/20 22:00 75-09-2 C9 Methyl-tert-butyl ether 515 ug/L 2.5 5 02/11/20 22:00 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-5 Lab ID: 92463689004 Collected: 02/04/20 13:11 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B 51.3 ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 2.7 ug/L ND ug/L ND ug/L ND ug/L ND ug/L 96 % 101 % 101 % 10.0 5 02/11/20 22:00 91-20-3 2.5 5 02/11/20 22:00 103-65-1 2.5 5 02/11/20 22:00 100-42-5 2.5 5 02/11/20 22:00 630-20-6 2.5 5 02/11/20 22:00 79-34-5 2.5 5 02/11/20 22:00 127-18-4 2.5 5 02/11/20 22:00 108-88-3 10.0 5 02/11/20 22:00 87-61-6 10.0 5 02/11/20 22:00 120-82-1 2.5 5 02/11/20 22:00 71-55-6 2.5 5 02/11/20 22:00 79-00-5 2.5 5 02/11/20 22:00 79-01-6 5.0 5 02/11/20 22:00 75-69-4 2.5 5 02/11/20 22:00 96-18-4 2.5 5 02/11/20 22:00 95-63-6 2.5 5 02/11/20 22:00 108-67-8 5.0 5 02/11/20 22:00 75-01-4 5.0 5 02/11/20 22:00 179601-23-1 2.5 5 02/11/20 22:00 95-47-6 70-130 5 70-130 5 70-130 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/11/20 22:00 17060-07-0 02/11/20 22:00 460-00-4 02/11/20 22:00 2037-26-5 Page 11 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-6 Lab ID: 92463689005 Collected: 02/04/20 12:16 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 1000 10 02/11/20 22:18 75-85-4 tert-Amylmethyl ether ND ug/L 100 10 02/11/20 22:18 994-05-8 Benzene ND ug/L 5.0 10 02/11/20 22:18 71-43-2 Bromobenzene ND ug/L 5.0 10 02/11/20 22:18 108-86-1 Bromochloromethane ND ug/L 5.0 10 02/11/20 22:18 74-97-5 Bromodichloromethane ND ug/L 5.0 10 02/11/20 22:18 75-27-4 Bromoform ND ug/L 5.0 10 02/11/20 22:18 75-25-2 Bromomethane ND ug/L 50.0 10 02/11/20 22:18 74-83-9 tert-Butyl Alcohol 773 ug/L 200 10 02/11/20 22:18 75-65-0 n-Butylbenzene ND ug/L 5.0 10 02/11/20 22:18 104-51-8 sec-Butylbenzene ND ug/L 5.0 10 02/11/20 22:18 135-98-8 tert-Butyl benzene ND ug/L 5.0 10 02/11/20 22:18 98-06-6 tert-Butyl Formate ND ug/L 200 10 02/11/20 22:18 762-75-4 Carbon tetrachloride ND ug/L 5.0 10 02/11/20 22:18 56-23-5 Chlorobenzene ND ug/L 5.0 10 02/11/20 22:18 108-90-7 Chloroethane ND ug/L 10.0 10 02/11/20 22:18 75-00-3 Chloroform ND ug/L 5.0 10 02/11/20 22:18 67-66-3 Chloromethane ND ug/L 10.0 10 02/11/20 22:18 74-87-3 2-Chlorotoluene ND ug/L 5.0 10 02/11/20 22:18 95-49-8 4-Chlorotoluene ND ug/L 5.0 10 02/11/20 22:18 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 10.0 10 02/11/20 22:18 96-12-8 Dibromochloromethane ND ug/L 5.0 10 02/11/20 22:18 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 5.0 10 02/11/20 22:18 106-93-4 Dibromomethane ND ug/L 5.0 10 02/11/20 22:18 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 10 02/11/20 22:18 95-50-1 1,3-Dichlorobenzene ND ug/L 5.0 10 02/11/20 22:18 541-73-1 1,4-Dichlorobenzene ND ug/L 5.0 10 02/11/20 22:18 106-46-7 Dichlorodifluoromethane ND ug/L 5.0 10 02/11/20 22:18 75-71-8 1,1-Dichloroethane ND ug/L 5.0 10 02/11/20 22:18 75-34-3 1,2-Dichloroethane ND ug/L 5.0 10 02/11/20 22:18 107-06-2 1,1-Dichloroethene ND ug/L 5.0 10 02/11/20 22:18 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 10 02/11/20 22:18 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 10 02/11/20 22:18 156-60-5 1,2-Dichloropropane ND ug/L 5.0 10 02/11/20 22:18 78-87-5 1,3-Dichloropropane ND ug/L 5.0 10 02/11/20 22:18 142-28-9 2,2-Dichloropropane ND ug/L 5.0 10 02/11/20 22:18 594-20-7 1,1-Dichloropropene ND ug/L 5.0 10 02/11/20 22:18 563-58-6 cis-1,3-Dichloropropene ND ug/L 5.0 10 02/11/20 22:18 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 5.0 10 02/11/20 22:18 10061-02-6 Diisopropyl ether 6.5 ug/L 5.0 10 02/11/20 22:18 108-20-3 Ethanol ND ug/L 2000 10 02/11/20 22:18 64-17-5 Ethylbenzene ND ug/L 5.0 10 02/11/20 22:18 100-41-4 Ethyl-tert-butyl ether ND ug/L 100 10 02/11/20 22:18 637-92-3 Hexachloro-1,3-butadiene ND ug/L 20.0 10 02/11/20 22:18 87-68-3 Isopropylbenzene (Cumene) ND ug/L 5.0 10 02/11/20 22:18 98-82-8 Methylene Chloride ND ug/L 20.0 10 02/11/20 22:18 75-09-2 Methyl-tert-butyl ether 1500 ug/L 5.0 10 02/11/20 22:18 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-6 Lab ID: 92463689005 Collected: 02/04/20 12:16 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 % 102 % 105 % 20.0 10 02/11/20 22:18 91-20-3 5.0 10 02/11/20 22:18 103-65-1 5.0 10 02/11/20 22:18 100-42-5 5.0 10 02/11/20 22:18 630-20-6 5.0 10 02/11/20 22:18 79-34-5 5.0 10 02/11/20 22:18 127-18-4 5.0 10 02/11/20 22:18 108-88-3 20.0 10 02/11/20 22:18 87-61-6 20.0 10 02/11/20 22:18 120-82-1 5.0 10 02/11/20 22:18 71-55-6 5.0 10 02/11/20 22:18 79-00-5 5.0 10 02/11/20 22:18 79-01-6 10.0 10 02/11/20 22:18 75-69-4 5.0 10 02/11/20 22:18 96-18-4 5.0 10 02/11/20 22:18 95-63-6 5.0 10 02/11/20 22:18 108-67-8 10.0 10 02/11/20 22:18 75-01-4 10.0 10 02/11/20 22:18 179601-23-1 5.0 10 02/11/20 22:18 95-47-6 70-130 10 70-130 10 70-130 10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/11/20 22:18 17060-07-0 02/11/20 22:18 460-00-4 02/11/20 22:18 2037-26-5 Page 13 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-7 Lab ID: 92463689006 Collected: 02/04/20 12:30 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 15:45 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 15:45 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 15:45 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 15:45 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 15:45 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 15:45 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 15:45 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 15:45 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 15:45 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 15:45 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 15:45 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 15:45 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 15:45 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 15:45 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 15:45 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 15:45 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 15:45 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 15:45 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:45 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 15:45 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 15:45 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 15:45 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 15:45 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 15:45 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:45 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:45 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 15:45 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 15:45 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 15:45 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 15:45 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 15:45 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:45 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 15:45 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:45 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 15:45 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 15:45 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 15:45 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:45 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 15:45 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 15:45 108-20-3 Ethanol ND ug/L 200 1 02/10/20 15:45 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 15:45 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 15:45 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 15:45 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 15:45 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 15:45 75-09-2 Methyl-tert-butyl ether 0.70 ug/L 0.50 1 02/10/20 15:45 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-7 Lab ID: 92463689006 Collected: 02/04/20 12:30 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 103 % 101 % 104 % 2.0 1 02/10/20 15:45 91-20-3 0.50 1 02/10/20 15:45 103-65-1 0.50 1 02/10/20 15:45 100-42-5 0.50 1 02/10/20 15:45 630-20-6 0.50 1 02/10/20 15:45 79-34-5 0.50 1 02/10/20 15:45 127-18-4 0.50 1 02/10/20 15:45 108-88-3 2.0 1 02/10/20 15:45 87-61-6 2.0 1 02/10/20 15:45 120-82-1 0.50 1 02/10/20 15:45 71-55-6 0.50 1 02/10/20 15:45 79-00-5 0.50 1 02/10/20 15:45 79-01-6 1.0 1 02/10/20 15:45 75-69-4 0.50 1 02/10/20 15:45 96-18-4 0.50 1 02/10/20 15:45 95-63-6 0.50 1 02/10/20 15:45 108-67-8 1.0 1 02/10/20 15:45 75-01-4 1.0 1 02/10/20 15:45 179601-23-1 0.50 1 02/10/20 15:45 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 15:45 17060-07-0 02/10/20 15:45 460-00-4 02/10/20 15:45 2037-26-5 Page 15 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-9 Lab ID: 92463689007 Collected: 02/04/20 12:40 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 13:00 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 13:00 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 13:00 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 13:00 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 13:00 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 13:00 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 13:00 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 13:00 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 13:00 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 13:00 104-51-8 sec-Butylbenzene 0.51 ug/L 0.50 1 02/10/20 13:00 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 13:00 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 13:00 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 13:00 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 13:00 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 13:00 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 13:00 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 13:00 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 13:00 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 13:00 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 13:00 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 13:00 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 13:00 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 13:00 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 13:00 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 13:00 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 13:00 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 13:00 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 13:00 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 13:00 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 13:00 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 13:00 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 13:00 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 13:00 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 13:00 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 13:00 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 13:00 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 13:00 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 13:00 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 13:00 108-20-3 Ethanol ND ug/L 200 1 02/10/20 13:00 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 13:00 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 13:00 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 13:00 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 13:00 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 13:00 75-09-2 Methyl-tert-butyl ether 2.3 ug/L 0.50 1 02/10/20 13:00 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-9 Lab ID: 92463689007 Collected: 02/04/20 12:40 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 99 % 100 % 115 % 2.0 1 02/10/20 13:00 91-20-3 0.50 1 02/10/20 13:00 103-65-1 0.50 1 02/10/20 13:00 100-42-5 0.50 1 02/10/20 13:00 630-20-6 0.50 1 02/10/20 13:00 79-34-5 0.50 1 02/10/20 13:00 127-18-4 0.50 1 02/10/20 13:00 108-88-3 2.0 1 02/10/20 13:00 87-61-6 2.0 1 02/10/20 13:00 120-82-1 0.50 1 02/10/20 13:00 71-55-6 0.50 1 02/10/20 13:00 79-00-5 0.50 1 02/10/20 13:00 79-01-6 1.0 1 02/10/20 13:00 75-69-4 0.50 1 02/10/20 13:00 96-18-4 0.50 1 02/10/20 13:00 95-63-6 0.50 1 02/10/20 13:00 108-67-8 1.0 1 02/10/20 13:00 75-01-4 1.0 1 02/10/20 13:00 179601-23-1 0.50 1 02/10/20 13:00 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 13:00 17060-07-0 02/10/20 13:00 460-00-4 02/10/20 13:00 2037-26-5 Page 17 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-10 Lab ID: 92463689008 Collected: 02/04/20 13:02 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 17:53 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 17:53 994-05-8 Benzene 3.7 ug/L 0.50 1 02/10/20 17:53 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 17:53 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 17:53 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 17:53 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 17:53 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 17:53 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 17:53 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 17:53 104-51-8 sec-Butylbenzene 21.7 ug/L 0.50 1 02/10/20 17:53 135-98-8 tert-Butyl benzene 2.4 ug/L 0.50 1 02/10/20 17:53 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 17:53 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 17:53 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 17:53 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 17:53 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 17:53 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 17:53 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 17:53 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 17:53 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 17:53 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 17:53 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 17:53 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 17:53 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:53 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:53 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:53 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 17:53 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 17:53 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 17:53 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 17:53 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 17:53 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 17:53 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 17:53 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 17:53 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 17:53 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 17:53 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 17:53 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 17:53 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 17:53 108-20-3 Ethanol ND ug/L 200 1 02/10/20 17:53 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 17:53 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 17:53 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 17:53 87-68-3 Isopropylbenzene (Cumene) 11.7 ug/L 0.50 1 02/10/20 17:53 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 17:53 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 17:53 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: MW-10 Lab ID: 92463689008 Collected: 02/04/20 13:02 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B 21.9 ug/L 0.52 ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 0.75 ug/L 98 % 99 % 102 % 2.0 1 02/10/20 17:53 91-20-3 0.50 1 02/10/20 17:53 103-65-1 0.50 1 02/10/20 17:53 100-42-5 0.50 1 02/10/20 17:53 630-20-6 0.50 1 02/10/20 17:53 79-34-5 0.50 1 02/10/20 17:53 127-18-4 0.50 1 02/10/20 17:53 108-88-3 2.0 1 02/10/20 17:53 87-61-6 2.0 1 02/10/20 17:53 120-82-1 0.50 1 02/10/20 17:53 71-55-6 0.50 1 02/10/20 17:53 79-00-5 0.50 1 02/10/20 17:53 79-01-6 1.0 1 02/10/20 17:53 75-69-4 0.50 1 02/10/20 17:53 96-18-4 0.50 1 02/10/20 17:53 95-63-6 0.50 1 02/10/20 17:53 108-67-8 1.0 1 02/10/20 17:53 75-01-4 1.0 1 02/10/20 17:53 179601-23-1 0.50 1 02/10/20 17:53 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 17:53 17060-07-0 02/10/20 17:53 460-00-4 02/10/20 17:53 2037-26-5 Page 19 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-1 Lab ID: 92463689009 Collected: 02/04/20 12:15 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 16:03 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 16:03 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 16:03 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 16:03 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 16:03 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 16:03 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 16:03 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 16:03 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 16:03 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 16:03 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 16:03 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 16:03 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 16:03 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 16:03 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 16:03 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 16:03 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 16:03 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 16:03 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:03 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:03 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 16:03 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 16:03 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 16:03 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 16:03 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:03 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:03 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:03 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 16:03 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 16:03 75-34-3 1,2-Dichloroethane 1.0 ug/L 0.50 1 02/10/20 16:03 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 16:03 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:03 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:03 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:03 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 16:03 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:03 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 16:03 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:03 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:03 10061-02-6 Diisopropyl ether 1.5 ug/L 0.50 1 02/10/20 16:03 108-20-3 Ethanol ND ug/L 200 1 02/10/20 16:03 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 16:03 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 16:03 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 16:03 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 16:03 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 16:03 75-09-2 Methyl-tert-butyl ether 14.1 ug/L 0.50 1 02/10/20 16:03 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-1 Lab ID: 92463689009 Collected: 02/04/20 12:15 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 103 % 100 % 109 % 2.0 1 02/10/20 16:03 91-20-3 0.50 1 02/10/20 16:03 103-65-1 0.50 1 02/10/20 16:03 100-42-5 0.50 1 02/10/20 16:03 630-20-6 0.50 1 02/10/20 16:03 79-34-5 0.50 1 02/10/20 16:03 127-18-4 0.50 1 02/10/20 16:03 108-88-3 2.0 1 02/10/20 16:03 87-61-6 2.0 1 02/10/20 16:03 120-82-1 0.50 1 02/10/20 16:03 71-55-6 0.50 1 02/10/20 16:03 79-00-5 0.50 1 02/10/20 16:03 79-01-6 1.0 1 02/10/20 16:03 75-69-4 0.50 1 02/10/20 16:03 96-18-4 0.50 1 02/10/20 16:03 95-63-6 0.50 1 02/10/20 16:03 108-67-8 1.0 1 02/10/20 16:03 75-01-4 1.0 1 02/10/20 16:03 179601-23-1 0.50 1 02/10/20 16:03 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 16:03 17060-07-0 02/10/20 16:03 460-00-4 02/10/20 16:03 2037-26-5 Page 21 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-3 Lab ID: 92463689010 Collected: 02/04/20 12:25 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol 238 ug/L 100 1 02/10/20 17:35 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 17:35 994-05-8 Benzene 32.3 ug/L 0.50 1 02/10/20 17:35 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 17:35 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 17:35 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 17:35 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 17:35 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 17:35 74-83-9 tert-Butyl Alcohol 112 ug/L 20.0 1 02/10/20 17:35 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 17:35 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 17:35 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 17:35 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 17:35 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 17:35 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 17:35 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 17:35 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 17:35 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 17:35 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 17:35 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 17:35 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 17:35 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 17:35 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 17:35 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 17:35 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:35 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:35 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 17:35 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 17:35 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 17:35 75-34-3 1,2-Dichloroethane 11.0 ug/L 0.50 1 02/10/20 17:35 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 17:35 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 17:35 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 17:35 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 17:35 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 17:35 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 17:35 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 17:35 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 17:35 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 17:35 10061-02-6 Diisopropyl ether 13.9 ug/L 0.50 1 02/10/20 17:35 108-20-3 Ethanol ND ug/L 200 1 02/10/20 17:35 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 17:35 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 17:35 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 17:35 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 17:35 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 17:35 75-09-2 Methyl-tert-butyl ether 65.7 ug/L 0.50 1 02/10/20 17:35 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-3 Lab ID: 92463689010 Collected: 02/04/20 12:25 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 100 % 99 % 101 % 2.0 1 02/10/20 17:35 91-20-3 0.50 1 02/10/20 17:35 103-65-1 0.50 1 02/10/20 17:35 100-42-5 0.50 1 02/10/20 17:35 630-20-6 0.50 1 02/10/20 17:35 79-34-5 0.50 1 02/10/20 17:35 127-18-4 0.50 1 02/10/20 17:35 108-88-3 2.0 1 02/10/20 17:35 87-61-6 2.0 1 02/10/20 17:35 120-82-1 0.50 1 02/10/20 17:35 71-55-6 0.50 1 02/10/20 17:35 79-00-5 0.50 1 02/10/20 17:35 79-01-6 1.0 1 02/10/20 17:35 75-69-4 0.50 1 02/10/20 17:35 96-18-4 0.50 1 02/10/20 17:35 95-63-6 0.50 1 02/10/20 17:35 108-67-8 1.0 1 02/10/20 17:35 75-01-4 1.0 1 02/10/20 17:35 179601-23-1 0.50 1 02/10/20 17:35 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 17:35 17060-07-0 02/10/20 17:35 460-00-4 02/10/20 17:35 2037-26-5 Page 23 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-4 Lab ID: 92463689011 Collected: 02/04/20 12:35 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 16:22 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 16:22 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 16:22 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 16:22 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 16:22 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 16:22 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 16:22 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 16:22 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 16:22 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 16:22 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 16:22 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 16:22 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 16:22 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 16:22 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 16:22 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 16:22 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 16:22 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 16:22 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:22 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:22 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 16:22 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 16:22 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 16:22 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 16:22 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:22 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:22 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:22 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 16:22 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 16:22 75-34-3 1,2-Dichloroethane 1.6 ug/L 0.50 1 02/10/20 16:22 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 16:22 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:22 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:22 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:22 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 16:22 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:22 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 16:22 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:22 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:22 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 16:22 108-20-3 Ethanol ND ug/L 200 1 02/10/20 16:22 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 16:22 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 16:22 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 16:22 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 16:22 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 16:22 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 16:22 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-4 Lab ID: 92463689011 Collected: 02/04/20 12:35 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 % 98 % 103 % 2.0 1 02/10/20 16:22 91-20-3 0.50 1 02/10/20 16:22 103-65-1 0.50 1 02/10/20 16:22 100-42-5 0.50 1 02/10/20 16:22 630-20-6 0.50 1 02/10/20 16:22 79-34-5 0.50 1 02/10/20 16:22 127-18-4 0.50 1 02/10/20 16:22 108-88-3 2.0 1 02/10/20 16:22 87-61-6 2.0 1 02/10/20 16:22 120-82-1 0.50 1 02/10/20 16:22 71-55-6 0.50 1 02/10/20 16:22 79-00-5 0.50 1 02/10/20 16:22 79-01-6 1.0 1 02/10/20 16:22 75-69-4 0.50 1 02/10/20 16:22 96-18-4 0.50 1 02/10/20 16:22 95-63-6 0.50 1 02/10/20 16:22 108-67-8 1.0 1 02/10/20 16:22 75-01-4 1.0 1 02/10/20 16:22 179601-23-1 0.50 1 02/10/20 16:22 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 16:22 17060-07-0 02/10/20 16:22 460-00-4 02/10/20 16:22 2037-26-5 Page 25 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-5 Lab ID: 92463689012 Collected: 02/04/20 12:45 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol 400 ug/L 100 1 02/10/20 16:40 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 16:40 994-05-8 Benzene 18.2 ug/L 0.50 1 02/10/20 16:40 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 16:40 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 16:40 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 16:40 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 16:40 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 16:40 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 16:40 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 16:40 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 16:40 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 16:40 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 16:40 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 16:40 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 16:40 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 16:40 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 16:40 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 16:40 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:40 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 16:40 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 16:40 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 16:40 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 16:40 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 16:40 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:40 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:40 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 16:40 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 16:40 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 16:40 75-34-3 1,2-Dichloroethane 15.3 ug/L 0.50 1 02/10/20 16:40 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 16:40 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:40 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 16:40 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:40 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 16:40 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 16:40 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 16:40 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:40 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 16:40 10061-02-6 Diisopropyl ether 17.6 ug/L 0.50 1 02/10/20 16:40 108-20-3 Ethanol ND ug/L 200 1 02/10/20 16:40 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 16:40 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 16:40 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 16:40 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 16:40 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 16:40 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 16:40 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: DMW-5 Lab ID: 92463689012 Collected: 02/04/20 12:45 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 % 98 % 102 % 2.0 1 02/10/20 16:40 91-20-3 0.50 1 02/10/20 16:40 103-65-1 0.50 1 02/10/20 16:40 100-42-5 0.50 1 02/10/20 16:40 630-20-6 0.50 1 02/10/20 16:40 79-34-5 0.50 1 02/10/20 16:40 127-18-4 0.50 1 02/10/20 16:40 108-88-3 2.0 1 02/10/20 16:40 87-61-6 2.0 1 02/10/20 16:40 120-82-1 0.50 1 02/10/20 16:40 71-55-6 0.50 1 02/10/20 16:40 79-00-5 0.50 1 02/10/20 16:40 79-01-6 1.0 1 02/10/20 16:40 75-69-4 0.50 1 02/10/20 16:40 96-18-4 0.50 1 02/10/20 16:40 95-63-6 0.50 1 02/10/20 16:40 108-67-8 1.0 1 02/10/20 16:40 75-01-4 1.0 1 02/10/20 16:40 179601-23-1 0.50 1 02/10/20 16:40 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 16:40 17060-07-0 02/10/20 16:40 460-00-4 02/10/20 16:40 2037-26-5 Page 27 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: WSW-9 Lab ID: 92463689013 Collected: 02/04/20 13:35 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 02/10/20 14:32 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 14:32 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 14:32 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 14:32 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 14:32 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 14:32 74-83-9 n-Butylbenzene ND ug/L 0.50 1 02/10/20 14:32 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 14:32 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 14:32 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 14:32 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 14:32 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 14:32 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 14:32 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 14:32 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 14:32 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 14:32 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 14:32 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 14:32 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 14:32 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 14:32 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 14:32 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 14:32 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 14:32 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 14:32 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 14:32 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 14:32 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 14:32 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 14:32 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 14:32 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 14:32 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 14:32 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 14:32 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 14:32 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 14:32 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 14:32 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 14:32 108-20-3 Ethylbenzene ND ug/L 0.50 1 02/10/20 14:32 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 14:32 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 14:32 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 14:32 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 14:32 1634-04-4 Naphthalene ND ug/L 2.0 1 02/10/20 14:32 91-20-3 n-Propylbenzene ND ug/L 0.50 1 02/10/20 14:32 103-65-1 Styrene ND ug/L 0.50 1 02/10/20 14:32 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 14:32 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 02/10/20 14:32 79-34-5 Tetrachloroethene ND ug/L 0.50 1 02/10/20 14:32 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: WSW-9 Lab ID: 92463689013 Collected: 02/04/20 13:35 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 103 % 100 % 106 % 0.50 1 02/10/20 14:32 108-88-3 2.0 1 02/10/20 14:32 87-61-6 2.0 1 02/10/20 14:32 120-82-1 0.50 1 02/10/20 14:32 71-55-6 0.50 1 02/10/20 14:32 79-00-5 0.50 1 02/10/20 14:32 79-01-6 1.0 1 02/10/20 14:32 75-69-4 0.50 1 02/10/20 14:32 96-18-4 0.50 1 02/10/20 14:32 95-63-6 0.50 1 02/10/20 14:32 108-67-8 1.0 1 02/10/20 14:32 75-01-4 1.0 1 02/10/20 14:32 179601-23-1 0.50 1 02/10/20 14:32 95-47-6 70-130 1 02/10/20 14:32 17060-07-0 70-130 1 02/10/20 14:32 460-00-4 70-130 1 02/10/20 14:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: TRIP BLANK Lab ID: 92463689014 Collected: 02/04/20 00:00 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND ug/L 100 1 02/10/20 12:42 75-85-4 tert-Amylmethyl ether ND ug/L 10.0 1 02/10/20 12:42 994-05-8 Benzene ND ug/L 0.50 1 02/10/20 12:42 71-43-2 Bromobenzene ND ug/L 0.50 1 02/10/20 12:42 108-86-1 Bromochloromethane ND ug/L 0.50 1 02/10/20 12:42 74-97-5 Bromodichloromethane ND ug/L 0.50 1 02/10/20 12:42 75-27-4 Bromoform ND ug/L 0.50 1 02/10/20 12:42 75-25-2 Bromomethane ND ug/L 5.0 1 02/10/20 12:42 74-83-9 tert-Butyl Alcohol ND ug/L 20.0 1 02/10/20 12:42 75-65-0 n-Butylbenzene ND ug/L 0.50 1 02/10/20 12:42 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 02/10/20 12:42 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 02/10/20 12:42 98-06-6 tert-Butyl Formate ND ug/L 20.0 1 02/10/20 12:42 762-75-4 L1 Carbon tetrachloride ND ug/L 0.50 1 02/10/20 12:42 56-23-5 Chlorobenzene ND ug/L 0.50 1 02/10/20 12:42 108-90-7 Chloroethane ND ug/L 1.0 1 02/10/20 12:42 75-00-3 Chloroform ND ug/L 0.50 1 02/10/20 12:42 67-66-3 Chloromethane ND ug/L 1.0 1 02/10/20 12:42 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 02/10/20 12:42 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 02/10/20 12:42 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 02/10/20 12:42 96-12-8 Dibromochloromethane ND ug/L 0.50 1 02/10/20 12:42 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 02/10/20 12:42 106-93-4 Dibromomethane ND ug/L 0.50 1 02/10/20 12:42 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 02/10/20 12:42 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 02/10/20 12:42 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 02/10/20 12:42 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 02/10/20 12:42 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 02/10/20 12:42 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 02/10/20 12:42 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 02/10/20 12:42 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 12:42 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 02/10/20 12:42 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 02/10/20 12:42 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 02/10/20 12:42 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 02/10/20 12:42 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 02/10/20 12:42 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 12:42 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 02/10/20 12:42 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 02/10/20 12:42 108-20-3 Ethanol ND ug/L 200 1 02/10/20 12:42 64-17-5 Ethylbenzene ND ug/L 0.50 1 02/10/20 12:42 100-41-4 Ethyl-tert-butyl ether ND ug/L 10.0 1 02/10/20 12:42 637-92-3 Hexachloro-1,3-butadiene ND ug/L 2.0 1 02/10/20 12:42 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 02/10/20 12:42 98-82-8 Methylene Chloride ND ug/L 2.0 1 02/10/20 12:42 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 02/10/20 12:42 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92463689 Sample: TRIP BLANK Lab ID: 92463689014 Collected: 02/04/20 00:00 Received: 02/04/20 14:37 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 03/02/2020 12:49 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 % 100 % 103 % 2.0 1 02/10/20 12:42 91-20-3 0.50 1 02/10/20 12:42 103-65-1 0.50 1 02/10/20 12:42 100-42-5 0.50 1 02/10/20 12:42 630-20-6 0.50 1 02/10/20 12:42 79-34-5 0.50 1 02/10/20 12:42 127-18-4 0.50 1 02/10/20 12:42 108-88-3 2.0 1 02/10/20 12:42 87-61-6 2.0 1 02/10/20 12:42 120-82-1 0.50 1 02/10/20 12:42 71-55-6 0.50 1 02/10/20 12:42 79-00-5 0.50 1 02/10/20 12:42 79-01-6 1.0 1 02/10/20 12:42 75-69-4 0.50 1 02/10/20 12:42 96-18-4 0.50 1 02/10/20 12:42 95-63-6 0.50 1 02/10/20 12:42 108-67-8 1.0 1 02/10/20 12:42 75-01-4 1.0 1 02/10/20 12:42 179601-23-1 0.50 1 02/10/20 12:42 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 02/10/20 12:42 17060-07-0 02/10/20 12:42 460-00-4 02/10/20 12:42 2037-26-5 Page 31 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 QC Batch: 524223 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92463689001, 92463689002, 92463689003, 92463689006, 92463689007, 92463689008, 92463689009, 92463689010,92463689011,92463689012,92463689013,92463689014 METHOD BLANK: 2802348 Matrix: Water Associated Lab Samples: 92463689001, 92463689002, 92463689003, 92463689006, 92463689007, 92463689008, 92463689009, 92463689010,92463689011,92463689012,92463689013,92463689014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/10/20 12:24 1,1,1-Trichloroethane ug/L ND 0.50 02/10/20 12:24 1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/10/20 12:24 1,1,2-Trichloroethane ug/L ND 0.50 02/10/20 12:24 1,1-Dichloroethane ug/L ND 0.50 02/10/20 12:24 1,1-Dichloroethene ug/L ND 0.50 02/10/20 12:24 1,1-Dichloropropene ug/L ND 0.50 02/10/20 12:24 1,2,3-Trichlorobenzene ug/L ND 2.0 02/10/20 12:24 1,2,3-Trichloropropane ug/L ND 0.50 02/10/20 12:24 1,2,4-Trichlorobenzene ug/L ND 2.0 02/10/20 12:24 1,2,4-Trimethylbenzene ug/L ND 0.50 02/10/20 12:24 1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/10/20 12:24 1,2-Dibromoethane (EDB) ug/L ND 0.50 02/10/20 12:24 1,2-Dichlorobenzene ug/L ND 0.50 02/10/20 12:24 1,2-Dichloroethane ug/L ND 0.50 02/10/20 12:24 1,2-Dichloropropane ug/L ND 0.50 02/10/20 12:24 1,3,5-Trimethylbenzene ug/L ND 0.50 02/10/20 12:24 1,3-Dichlorobenzene ug/L ND 0.50 02/10/20 12:24 1,3-Dichloropropane ug/L ND 0.50 02/10/20 12:24 1,4-Dichlorobenzene ug/L ND 0.50 02/10/20 12:24 2,2-Dichloropropane ug/L ND 0.50 02/10/20 12:24 2-Chlorotoluene ug/L ND 0.50 02/10/20 12:24 4-Chlorotoluene ug/L ND 0.50 02/10/20 12:24 Benzene ug/L ND 0.50 02/10/20 12:24 Bromobenzene ug/L ND 0.50 02/10/20 12:24 Bromochloromethane ug/L ND 0.50 02/10/20 12:24 Bromodichloromethane ug/L ND 0.50 02/10/20 12:24 Bromoform ug/L ND 0.50 02/10/20 12:24 Bromomethane ug/L ND 5.0 02/10/20 12:24 Carbon tetrachloride ug/L ND 0.50 02/10/20 12:24 Chlorobenzene ug/L ND 0.50 02/10/20 12:24 Chloroethane ug/L ND 1.0 02/10/20 12:24 Chloroform ug/L ND 0.50 02/10/20 12:24 Chloromethane ug/L ND 1.0 02/10/20 12:24 cis-1,2-Dichloroethene ug/L ND 0.50 02/10/20 12:24 cis-1,3-Dichloropropene ug/L ND 0.50 02/10/20 12:24 Dibromochloromethane ug/L ND 0.50 02/10/20 12:24 Dibromomethane ug/L ND 0.50 02/10/20 12:24 Dichlorodifluoromethane ug/L ND 0.50 02/10/20 12:24 Diisopropyl ether ug/L ND 0.50 02/10/20 12:24 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 METHOD BLANK: 2802348 Matrix: Water Associated Lab Samples: 92463689001, 92463689002, 92463689003, 92463689006, 92463689007, 92463689008, 92463689009, 92463689010,92463689011,92463689012,92463689013,92463689014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethanol ug/L ND 200 02/10/20 12:24 Ethyl-tert-butyl ether ug/L ND 10.0 02/10/20 12:24 Ethylbenzene ug/L ND 0.50 02/10/20 12:24 Hexachloro-1,3-butadiene ug/L ND 2.0 02/10/20 12:24 Isopropylbenzene (Cumene) ug/L ND 0.50 02/10/20 12:24 m&p-Xylene ug/L ND 1.0 02/10/20 12:24 Methyl-tert-butyl ether ug/L ND 0.50 02/10/20 12:24 Methylene Chloride ug/L ND 2.0 02/10/20 12:24 n-Butylbenzene ug/L ND 0.50 02/10/20 12:24 n-Propylbenzene ug/L ND 0.50 02/10/20 12:24 Naphthalene ug/L ND 2.0 02/10/20 12:24 o-Xylene ug/L ND 0.50 02/10/20 12:24 sec-Butylbenzene ug/L ND 0.50 02/10/20 12:24 Styrene ug/L ND 0.50 02/10/20 12:24 tert-Amyl Alcohol ug/L ND 100 02/10/20 12:24 tert-Amylmethyl ether ug/L ND 10.0 02/10/20 12:24 tert-Butyl Alcohol ug/L ND 20.0 02/10/20 12:24 tert-Butyl Formate ug/L ND 20.0 02/10/20 12:24 tert-Butyl benzene ug/L ND 0.50 02/10/20 12:24 Tetrachloroethene ug/L ND 0.50 02/10/20 12:24 Toluene ug/L ND 0.50 02/10/20 12:24 trans-1,2-Dichloroethene ug/L ND 0.50 02/10/20 12:24 trans- 1,3-Dichloropropene ug/L ND 0.50 02/10/20 12:24 Trichloroethene ug/L ND 0.50 02/10/20 12:24 Trichlorofluoromethane ug/L ND 1.0 02/10/20 12:24 Vinyl chloride ug/L ND 1.0 02/10/20 12:24 1,2-Dichloroethane-d4 (S) % 100 70-130 02/10/20 12:24 4-Bromofluorobenzene (S) % 102 70-130 02/10/20 12:24 Toluene-d8 (S) % 107 70-130 02/10/20 12:24 LABORATORY CONTROL SAMPLE: 2802349 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 55.3 111 60-140 1,1,1-Trichloroethane ug/L 50 50.7 101 60-140 1,1,2,2-Tetrachloroethane ug/L 50 53.6 107 60-140 1,1,2-Trichloroethane ug/L 50 53.9 108 60-140 1,1-Dichloroethane ug/L 50 48.7 97 60-140 1,1-Dichloroethene ug/L 50 48.3 97 60-140 1,1-Dichloropropene ug/L 50 51.9 104 60-140 1,2,3-Trichlorobenzene ug/L 50 52.7 105 60-140 1,2,3-Trichloropropane ug/L 50 50.6 101 60-140 1,2,4-Trichlorobenzene ug/L 50 53.0 106 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 LABORATORY CONTROL SAMPLE: Parameter 2802349 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trimethylbenzene ug/L 50 51.6 103 60-140 1,2-Dibromo-3-chloropropane ug/L 50 58.0 116 60-140 1,2-Dibromoethane (EDB) ug/L 50 54.1 108 60-140 1,2-Dichlorobenzene ug/L 50 51.6 103 60-140 1,2-Dichloroethane ug/L 50 45.4 91 60-140 1,2-Dichloropropane ug/L 50 51.6 103 60-140 1,3,5-Trimethylbenzene ug/L 50 51.4 103 60-140 1,3-Dichlorobenzene ug/L 50 51.8 104 60-140 1,3-Dichloropropane ug/L 50 51.5 103 60-140 1,4-Dichlorobenzene ug/L 50 49.9 100 60-140 2,2-Dichloropropane ug/L 50 57.8 116 60-140 2-Chlorotoluene ug/L 50 50.1 100 60-140 4-Chlorotoluene ug/L 50 51.4 103 60-140 Benzene ug/L 50 50.9 102 60-140 Bromobenzene ug/L 50 51.7 103 60-140 Bromochloromethane ug/L 50 50.4 101 60-140 Bromodichloromethane ug/L 50 51.5 103 60-140 Bromoform ug/L 50 48.9 98 60-140 Bromomethane ug/L 50 57.6 115 60-140 Carbon tetrachloride ug/L 50 53.8 108 60-140 Chlorobenzene ug/L 50 50.7 101 60-140 Chloroethane ug/L 50 55.4 111 60-140 Chloroform ug/L 50 49.6 99 60-140 Chloromethane ug/L 50 33.3 67 60-140 cis-1,2-Dichloroethene ug/L 50 48.6 97 60-140 cis-1,3-Dichloropropene ug/L 50 56.3 113 60-140 Dibromochloromethane ug/L 50 56.3 113 60-140 Dibromomethane ug/L 50 52.6 105 60-140 Dichlorodifluoromethane ug/L 50 45.5 91 60-140 Diisopropyl ether ug/L 50 52.4 105 60-140 Ethanol ug/L 2000 1470 74 60-140 Ethyl-tert-butyl ether ug/L 100 97.6 98 60-140 Ethylbenzene ug/L 50 49.1 98 60-140 Hexachloro-1,3-butadiene ug/L 50 52.6 105 60-140 Isopropylbenzene (Cumene) ug/L 50 51.2 102 60-140 m&p-Xylene ug/L 100 98.5 98 60-140 Methyl-tert-butyl ether ug/L 50 52.5 105 60-140 Methylene Chloride ug/L 50 44.8 90 60-140 n-Butylbenzene ug/L 50 52.3 105 60-140 n-Propylbenzene ug/L 50 50.7 101 60-140 Naphthalene ug/L 50 53.7 107 60-140 o-Xylene ug/L 50 49.7 99 60-140 sec-Butylbenzene ug/L 50 50.8 102 60-140 Styrene ug/L 50 52.2 104 60-140 tert-Amyl Alcohol ug/L 1000 1090 109 60-140 tert-Amylmethyl ether ug/L 100 107 107 60-140 tert-Butyl Alcohol ug/L 500 463 93 60-140 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 LABORATORY CONTROL SAMPLE: 2802349 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers tert-Butyl Formate ug/L 400 687 172 60-140 L1 tert-Butyl benzene ug/L 50 40.8 82 60-140 Tetrachloroethene ug/L 50 50.4 101 60-140 Toluene ug/L 50 50.0 100 60-140 trans-1,2-Dichloroethene ug/L 50 48.5 97 60-140 trans- 1,3-Dichloropropene ug/L 50 50.5 101 60-140 Trichloroethene ug/L 50 49.9 100 60-140 Trichlorofluoromethane ug/L 50 46.1 92 60-140 Vinyl chloride ug/L 50 52.3 105 60-140 1,2-Dichloroethane-d4 (S) % 101 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8(S) % 101 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2802350 2802351 MS MSD 92463689002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 200 200 237 236 118 118 60-140 0 1,1,1-Trichloroethane ug/L ND 200 200 236 233 118 116 60-140 1 1,1,2,2-Tetrachloroethane ug/L ND 200 200 233 236 117 118 60-140 1 1,1,2-Trichloroethane ug/L ND 200 200 236 234 118 117 60-140 1 1,1-Dichloroethane ug/L ND 200 200 219 219 109 110 60-140 0 1,1-Dichloroethene ug/L ND 200 200 230 229 115 114 60-140 0 1,1-Dichloropropene ug/L ND 200 200 241 237 121 119 60-140 2 1,2,3-Trichlorobenzene ug/L ND 200 200 218 226 109 113 60-140 4 1,2,3-Trichloropropane ug/L ND 200 200 243 251 121 125 60-140 3 1,2,4-Trichlorobenzene ug/L ND 200 200 212 226 106 113 60-140 6 1,2,4-Trimethylbenzene ug/L ND 200 200 228 236 112 116 60-140 3 1,2-Dibromo-3-chloropropane ug/L ND 200 200 244 255 122 128 60-140 4 1,2-Dibromoethane (EDB) ug/L ND 200 200 229 228 114 114 60-140 0 1,2-Dichlorobenzene ug/L ND 200 200 225 235 113 117 60-140 4 1,2-Dichloroethane ug/L ND 200 200 207 205 103 102 60-140 1 1,2-Dichloropropane ug/L ND 200 200 226 229 113 115 60-140 1 1,3,5-Trimethylbenzene ug/L ND 200 200 227 236 114 118 60-140 4 1,3-Dichlorobenzene ug/L ND 200 200 230 239 115 119 60-140 4 1,3-Dichloropropane ug/L ND 200 200 222 220 111 110 60-140 1 1,4-Dichlorobenzene ug/L ND 200 200 218 226 109 113 60-140 4 2,2-Dichloropropane ug/L ND 200 200 191 188 96 94 60-140 2 2-Chlorotoluene ug/L ND 200 200 223 234 112 117 60-140 5 4-Chlorotoluene ug/L ND 200 200 227 238 114 119 60-140 5 Benzene ug/L 5.4 200 200 235 238 115 116 60-140 1 Bromobenzene ug/L ND 200 200 230 238 115 119 60-140 4 Bromochloromethane ug/L ND 200 200 237 232 119 116 60-140 2 Bromodichloromethane ug/L ND 200 200 224 225 112 112 60-140 0 Bromoform ug/L ND 200 200 198 202 99 101 60-140 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2802350 2802351 MS MSD 92463689002 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Bromomethane ug/L ND 200 200 107 123 53 61 60-140 14 M1 Carbon tetrachloride ug/L ND 200 200 242 249 121 124 60-140 3 Chlorobenzene ug/L ND 200 200 228 230 114 115 60-140 1 Chloroethane ug/L ND 200 200 233 244 116 122 60-140 5 Chloroform ug/L ND 200 200 229 227 114 113 60-140 1 Chloromethane ug/L ND 200 200 190 192 95 96 60-140 1 cis-1,2-Dichloroethene ug/L ND 200 200 223 219 111 110 60-140 2 cis-1,3-Dichloropropene ug/L ND 200 200 222 225 111 112 60-140 1 Dibromochloromethane ug/L ND 200 200 233 234 117 117 60-140 0 Dibromomethane ug/L ND 200 200 231 235 116 118 60-140 2 Dichlorodifluoromethane ug/L ND 200 200 228 233 114 116 60-140 2 Diisopropyl ether ug/L 33.0 200 200 261 257 114 112 60-140 2 Ethanol ug/L ND 8000 8000 8880 9160 111 114 60-140 3 Ethyl-tert-butyl ether ug/L ND 400 400 411 405 103 101 60-140 1 Ethylbenzene ug/L ND 200 200 224 227 112 114 60-140 1 Hexachloro-1,3-butadiene ug/L ND 200 200 224 229 112 114 60-140 2 Isopropylbenzene (Cumene) ug/L ND 200 200 235 238 117 119 60-140 1 m&p-Xylene ug/L ND 400 400 455 463 114 116 60-140 2 Methyl-tert-butyl ether ug/L 1210 200 200 1500 1450 143 116 60-140 4 M1 Methylene Chloride ug/L ND 200 200 211 215 106 108 60-140 2 n-Butylbenzene ug/L ND 200 200 222 233 111 117 60-140 5 n-Propylbenzene ug/L ND 200 200 224 236 112 118 60-140 5 Naphthalene ug/L ND 200 200 220 231 110 116 60-140 5 o-Xylene ug/L ND 200 200 225 228 113 114 60-140 1 sec-Butylbenzene ug/L ND 200 200 229 239 115 120 60-140 4 Styrene ug/L ND 200 200 229 235 114 117 60-140 3 tert-Amyl Alcohol ug/L 1880 4000 4000 7090 7230 130 134 60-140 2 tert-Amylmethyl ether ug/L ND 400 400 459 460 115 115 60-140 0 tert-Butyl Alcohol ug/L 7360 2000 2000 11200 11000 192 181 60-140 2 M1 tert-Butyl Formate ug/L ND 1600 1600 807 816 50 51 60-140 1 P5 tert-Butyl benzene ug/L ND 200 200 185 194 92 97 60-140 5 Tetrachloroethene ug/L ND 200 200 226 226 113 113 60-140 0 Toluene ug/L ND 200 200 229 234 113 115 60-140 2 trans-1,2-Dichloroethene ug/L ND 200 200 227 226 114 113 60-140 1 trans- 1,3-Dichloropropene ug/L ND 200 200 191 198 96 99 60-140 4 Trichloroethene ug/L ND 200 200 225 228 112 114 60-140 2 Trichlorofluoromethane ug/L ND 200 200 226 227 113 114 60-140 1 Vinyl chloride ug/L ND 200 200 244 251 122 126 60-140 3 1,2-Dichloroethane-d4 (S) % 101 99 70-130 4-Bromofluorobenzene (S) % 100 99 70-130 Toluene-d8(S) % 100 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 QC Batch: 524433 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92463689004, 92463689005 METHOD BLANK: 2803387 Associated Lab Samples: 92463689004, 92463689005 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 02/11/20 16:12 1,1,1-Trichloroethane ug/L ND 0.50 02/11/20 16:12 1,1,2,2-Tetrachloroethane ug/L ND 0.50 02/11/20 16:12 1,1,2-Trichloroethane ug/L ND 0.50 02/11/20 16:12 1,1-Dichloroethane ug/L ND 0.50 02/11/20 16:12 1,1-Dichloroethene ug/L ND 0.50 02/11/20 16:12 1,1-Dichloropropene ug/L ND 0.50 02/11/20 16:12 1,2,3-Trichlorobenzene ug/L ND 2.0 02/11/20 16:12 1,2,3-Trichloropropane ug/L ND 0.50 02/11/20 16:12 1,2,4-Trichlorobenzene ug/L ND 2.0 02/11/20 16:12 1,2,4-Trimethylbenzene ug/L ND 0.50 02/11/20 16:12 1,2-Dibromo-3-chloropropane ug/L ND 1.0 02/11/20 16:12 1,2-Dibromoethane (EDB) ug/L ND 0.50 02/11/20 16:12 1,2-Dichlorobenzene ug/L ND 0.50 02/11/20 16:12 1,2-Dichloroethane ug/L ND 0.50 02/11/20 16:12 1,2-Dichloropropane ug/L ND 0.50 02/11/20 16:12 1,3,5-Trimethylbenzene ug/L ND 0.50 02/11/20 16:12 1,3-Dichlorobenzene ug/L ND 0.50 02/11/20 16:12 1,3-Dichloropropane ug/L ND 0.50 02/11/20 16:12 1,4-Dichlorobenzene ug/L ND 0.50 02/11/20 16:12 2,2-Dichloropropane ug/L ND 0.50 02/11/20 16:12 2-Chlorotoluene ug/L ND 0.50 02/11/20 16:12 4-Chlorotoluene ug/L ND 0.50 02/11/20 16:12 Benzene ug/L ND 0.50 02/11/20 16:12 Bromobenzene ug/L ND 0.50 02/11/20 16:12 Bromochloromethane ug/L ND 0.50 02/11/20 16:12 Bromodichloromethane ug/L ND 0.50 02/11/20 16:12 Bromoform ug/L ND 0.50 02/11/20 16:12 Bromomethane ug/L ND 5.0 02/11/20 16:12 Carbon tetrachloride ug/L ND 0.50 02/11/20 16:12 Chlorobenzene ug/L ND 0.50 02/11/20 16:12 Chloroethane ug/L ND 1.0 02/11/20 16:12 Chloroform ug/L ND 0.50 02/11/20 16:12 Chloromethane ug/L ND 1.0 02/11/20 16:12 cis-1,2-Dichloroethene ug/L ND 0.50 02/11/20 16:12 cis-1,3-Dichloropropene ug/L ND 0.50 02/11/20 16:12 Dibromochloromethane ug/L ND 0.50 02/11/20 16:12 Dibromomethane ug/L ND 0.50 02/11/20 16:12 Dichlorodifluoromethane ug/L ND 0.50 02/11/20 16:12 Diisopropyl ether ug/L ND 0.50 02/11/20 16:12 Ethanol ug/L ND 200 02/11/20 16:12 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 METHOD BLANK: 2803387 Associated Lab Samples: 92463689004, 92463689005 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Ethyl-tert-butyl ether ug/L ND 10.0 02/11/20 16:12 Ethylbenzene ug/L ND 0.50 02/11/20 16:12 Hexachloro-1,3-butadiene ug/L ND 2.0 02/11/20 16:12 Isopropylbenzene (Cumene) ug/L ND 0.50 02/11/20 16:12 m&p-Xylene ug/L ND 1.0 02/11/20 16:12 Methyl-tert-butyl ether ug/L ND 0.50 02/11/20 16:12 Methylene Chloride ug/L ND 2.0 02/11/20 16:12 n-Butylbenzene ug/L ND 0.50 02/11/20 16:12 n-Propylbenzene ug/L ND 0.50 02/11/20 16:12 Naphthalene ug/L ND 2.0 02/11/20 16:12 o-Xylene ug/L ND 0.50 02/11/20 16:12 sec-Butylbenzene ug/L ND 0.50 02/11/20 16:12 Styrene ug/L ND 0.50 02/11/20 16:12 tert-Amyl Alcohol ug/L ND 100 02/11/20 16:12 tert-Amylmethyl ether ug/L ND 10.0 02/11/20 16:12 tert-Butyl Alcohol ug/L ND 20.0 02/11/20 16:12 tert-Butyl Formate ug/L ND 20.0 02/11/20 16:12 tert-Butyl benzene ug/L ND 0.50 02/11/20 16:12 Tetrachloroethene ug/L ND 0.50 02/11/20 16:12 Toluene ug/L ND 0.50 02/11/20 16:12 trans-1,2-Dichloroethene ug/L ND 0.50 02/11/20 16:12 trans- 1,3-Dichloropropene ug/L ND 0.50 02/11/20 16:12 Trichloroethene ug/L ND 0.50 02/11/20 16:12 Trichlorofluoromethane ug/L ND 1.0 02/11/20 16:12 Vinyl chloride ug/L ND 1.0 02/11/20 16:12 1,2-Dichloroethane-d4 (S) % 94 70-130 02/11/20 16:12 4-Bromofluorobenzene (S) % 100 70-130 02/11/20 16:12 Toluene-d8 (S) % 102 70-130 02/11/20 16:12 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2803388 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 54.2 108 60-140 1,1,1-Trichloroethane ug/L 50 51.2 102 60-140 1,1,2,2-Tetrachloroethane ug/L 50 53.2 106 60-140 1,1,2-Trichloroethane ug/L 50 54.9 110 60-140 1,1-Dichloroethane ug/L 50 49.2 98 60-140 1,1-Dichloroethene ug/L 50 50.5 101 60-140 1,1-Dichloropropene ug/L 50 53.1 106 60-140 1,2,3-Trichlorobenzene ug/L 50 53.0 106 60-140 1,2,3-Trichloropropane ug/L 50 47.9 96 60-140 1,2,4-Trichlorobenzene ug/L 50 53.1 106 60-140 1,2,4-Trimethylbenzene ug/L 50 51.5 103 60-140 1,2-Dibromo-3-chloropropane ug/L 50 59.0 118 60-140 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 LABORATORY CONTROL SAMPLE: Parameter 2803388 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dibromoethane (EDB) ug/L 50 51.9 104 60-140 1,2-Dichlorobenzene ug/L 50 51.9 104 60-140 1,2-Dichloroethane ug/L 50 46.8 94 60-140 1,2-Dichloropropane ug/L 50 52.2 104 60-140 1,3,5-Trimethylbenzene ug/L 50 51.5 103 60-140 1,3-Dichlorobenzene ug/L 50 52.5 105 60-140 1,3-Dichloropropane ug/L 50 49.9 100 60-140 1,4-Dichlorobenzene ug/L 50 50.3 101 60-140 2,2-Dichloropropane ug/L 50 48.2 96 60-140 2-Chlorotoluene ug/L 50 51.2 102 60-140 4-Chlorotoluene ug/L 50 51.6 103 60-140 Benzene ug/L 50 51.7 103 60-140 Bromobenzene ug/L 50 52.7 105 60-140 Bromochloromethane ug/L 50 51.2 102 60-140 Bromodichloromethane ug/L 50 52.5 105 60-140 Bromoform ug/L 50 46.8 94 60-140 Bromomethane ug/L 50 41.0 82 60-140 Carbon tetrachloride ug/L 50 55.3 111 60-140 Chlorobenzene ug/L 50 51.2 102 60-140 Chloroethane ug/L 50 40.0 80 60-140 Chloroform ug/L 50 50.7 101 60-140 Chloromethane ug/L 50 47.6 95 60-140 cis-1,2-Dichloroethene ug/L 50 49.8 100 60-140 cis-1,3-Dichloropropene ug/L 50 55.0 110 60-140 Dibromochloromethane ug/L 50 53.9 108 60-140 Dibromomethane ug/L 50 53.8 108 60-140 Dichlorodifluoromethane ug/L 50 53.6 107 60-140 Diisopropyl ether ug/L 50 51.7 103 60-140 Ethanol ug/L 2000 1990 99 60-140 Ethyl-tert-butyl ether ug/L 100 94.0 94 60-140 Ethylbenzene ug/L 50 49.6 99 60-140 Hexachloro-1,3-butadiene ug/L 50 52.5 105 60-140 Isopropylbenzene (Cumene) ug/L 50 52.1 104 60-140 m&p-Xylene ug/L 100 99.9 100 60-140 Methyl-tert-butyl ether ug/L 50 50.9 102 60-140 Methylene Chloride ug/L 50 47.1 94 60-140 n-Butylbenzene ug/L 50 52.3 105 60-140 n-Propylbenzene ug/L 50 51.3 103 60-140 Naphthalene ug/L 50 52.8 106 60-140 o-Xylene ug/L 50 50.2 100 60-140 sec-Butylbenzene ug/L 50 51.3 103 60-140 Styrene ug/L 50 52.7 105 60-140 tert-Amyl Alcohol ug/L 1000 1140 114 60-140 tert-Amylmethyl ether ug/L 100 105 105 60-140 tert-Butyl Alcohol ug/L 500 457 91 60-140 tert-Butyl Formate ug/L 400 333 83 60-140 tert-Butyl benzene ug/L 50 41.5 83 60-140 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 LABORATORY CONTROL SAMPLE: 2803388 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Tetrachloroethene ug/L 50 50.2 100 60-140 Toluene ug/L 50 51.4 103 60-140 trans-1,2-Dichloroethene ug/L 50 49.8 100 60-140 trans- 1,3-Dichloropropene ug/L 50 48.5 97 60-140 Trichloroethene ug/L 50 50.5 101 60-140 Trichlorofluoromethane ug/L 50 49.5 99 60-140 Vinyl chloride ug/L 50 56.4 113 60-140 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 102 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2803389 MS 92463988004 Spike Parameter Units Result Conc. MSD Spike Conc. 2803390 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 200 200 223 218 111 109 60-140 2 1,1,1-Trichloroethane ug/L ND 200 200 217 214 109 107 60-140 1 1,1,2,2-Tetrachloroethane ug/L ND 200 200 222 223 111 112 60-140 1 1,1,2-Trichloroethane ug/L ND 200 200 226 223 113 112 60-140 1 1,1-Dichloroethane ug/L ND 200 200 208 203 104 101 60-140 2 1,1-Dichloroethene ug/L ND 200 200 217 213 109 106 60-140 2 1,1-Dichloropropene ug/L ND 200 200 226 219 113 109 60-140 3 1,2,3-Trichlorobenzene ug/L ND 200 200 207 206 103 103 60-140 0 1,2,3-Trichloropropane ug/L ND 200 200 191 193 95 96 60-140 1 1,2,4-Trichlorobenzene ug/L ND 200 200 205 207 102 104 60-140 1 1,2,4-Trimethylbenzene ug/L 1370 200 200 1550 1610 92 121 60-140 4 1,2-Dibromo-3-chloropropane ug/L ND 200 200 229 237 115 119 60-140 3 1,2-Dibromoethane (EDB) ug/L ND 200 200 216 213 108 106 60-140 1 1,2-Dichlorobenzene ug/L ND 200 200 214 217 107 109 60-140 1 1,2-Dichloroethane ug/L ND 200 200 197 194 98 97 60-140 1 1,2-Dichloropropane ug/L ND 200 200 218 218 109 109 60-140 0 1,3,5-Trimethylbenzene ug/L 372 200 200 583 602 105 115 60-140 3 1,3-Dichlorobenzene ug/L ND 200 200 221 222 111 111 60-140 1 1,3-Dichloropropane ug/L ND 200 200 209 207 104 103 60-140 1 1,4-Dichlorobenzene ug/L ND 200 200 210 212 105 106 60-140 1 2,2-Dichloropropane ug/L ND 200 200 165 153 83 77 60-140 7 2-Chlorotoluene ug/L ND 200 200 352 359 176 179 60-140 2 M1 4-Chlorotoluene ug/L ND 200 200 218 217 109 108 60-140 0 Benzene ug/L ND 200 200 221 217 111 109 60-140 2 Bromobenzene ug/L ND 200 200 218 220 109 110 60-140 1 Bromochloromethane ug/L ND 200 200 230 220 115 110 60-140 5 Bromodichloromethane ug/L ND 200 200 213 211 107 105 60-140 1 Bromoform ug/L ND 200 200 180 179 90 90 60-140 0 Bromomethane ug/L ND 200 200 122 123 61 61 60-140 1 Carbon tetrachloride ug/L ND 200 200 231 226 115 113 60-140 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92463689 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2803389 2803390 MS MSD 92463988004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chlorobenzene ug/L ND 200 200 217 216 109 108 60-140 1 Chloroethane ug/L ND 200 200 221 215 110 107 60-140 3 Chloroform ug/L ND 200 200 216 211 108 106 60-140 2 Chloromethane ug/L ND 200 200 162 161 81 80 60-140 1 cis-1,2-Dichloroethene ug/L ND 200 200 209 205 104 103 60-140 2 cis-1,3-Dichloropropene ug/L ND 200 200 207 206 103 103 60-140 0 Dibromochloromethane ug/L ND 200 200 213 214 106 107 60-140 0 Dibromomethane ug/L ND 200 200 223 222 111 111 60-140 1 Dichlorodifluoromethane ug/L ND 200 200 205 199 102 100 60-140 3 Diisopropyl ether ug/L ND 200 200 215 211 108 105 60-140 2 Ethanol ug/L ND 8000 8000 8680 8700 108 109 60-140 0 Ethyl-tert-butyl ether ug/L ND 400 400 390 381 97 95 60-140 2 Ethylbenzene ug/L 351 200 200 561 568 105 108 60-140 1 Hexachloro-1,3-butadiene ug/L ND 200 200 202 205 101 103 60-140 2 Isopropylbenzene(Cumene) ug/L 32.4 200 200 254 255 111 112 60-140 1 m&p-Xylene ug/L 1310 400 400 1690 1740 96 107 60-140 3 Methyl-tert-butyl ether ug/L ND 200 200 210 207 105 104 60-140 1 Methylene Chloride ug/L ND 200 200 213 202 98 92 60-140 5 n-Butylbenzene ug/L ND 200 200 246 251 123 125 60-140 2 n-Propylbenzene ug/L 126 200 200 338 344 106 109 60-140 2 Naphthalene ug/L 281 200 200 509 517 114 118 60-140 2 o-Xylene ug/L 382 200 200 586 599 102 109 60-140 2 sec-Butylbenzene ug/L ND 200 200 225 231 113 115 60-140 2 Styrene ug/L ND 200 200 228 230 114 115 60-140 1 tert-Amyl Alcohol ug/L ND 4000 4000 4640 4750 116 119 60-140 2 tert-Amylmethyl ether ug/L ND 400 400 430 429 108 107 60-140 0 tert-Butyl Alcohol ug/L ND 2000 2000 2440 2410 122 121 60-140 1 tert-Butyl Formate ug/L ND 1600 1600 518 500 32 31 60-140 4 P5 tert-Butyl benzene ug/L ND 200 200 176 178 88 89 60-140 1 Tetrachloroethene ug/L ND 200 200 212 207 106 104 60-140 2 Toluene ug/L 726 200 200 932 950 103 112 60-140 2 trans-1,2-Dichloroethene ug/L ND 200 200 211 208 105 104 60-140 1 trans- 1,3-Dichloropropene ug/L ND 200 200 178 177 89 89 60-140 0 Trichloroethene ug/L ND 200 200 215 212 108 106 60-140 1 Trichlorofluoromethane ug/L ND 200 200 212 207 106 104 60-140 3 Vinyl chloride ug/L ND 200 200 233 228 117 114 60-140 2 1,2-Dichloroethane-d4 (S) % 98 97 70-130 4-Bromofluorobenzene (S) % 99 99 70-130 Toluene-d8(S) % 102 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Carl's Country Store Pace Project No.: 92463689 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS C9 Common Laboratory Contaminant. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. P5 The EPA or method required sample preservation degrades this compound, therefore acceptable recoveries may not be achieved in sample matrix spikes. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 03/02/2020 12:49 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 48 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Carl's Country Store Pace Project No.: 92463689 Lab ID Sample ID QC Batch Method QC Batch 92463689001 MW-1 SM 6200B 524223 92463689002 MW-2 SM 6200B 524223 92463689003 MW-4 SM 6200B 524223 92463689004 MW-5 SM 6200B 524433 92463689005 MW-6 SM 6200B 524433 92463689006 MW-7 SM 6200B 524223 92463689007 MW-9 SM 6200B 524223 92463689008 MW-10 SM 6200B 524223 92463689009 DMW-1 SM 6200E 524223 92463689010 DMW-3 SM 6200E 524223 92463689011 DMW-4 SM 6200B 524223 92463689012 DMW-5 SM 6200E 524223 92463689013 WSW-9 SM 6200E 524223 92463689014 TRIP BLANK SM 6200B 524223 Date: 03/02/2020 12:49 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 43 of 48 Document Name: Document Revised: February 7, 2018 aceAnah �lCal m l Sample Condition U on Receipt(SOUR) Page 1 of 2 Document No.: Issuing Authority: f F-CAR-CS-033-Rev.06 Pace Carolinas quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersville Ralelgh❑ Mechanicsville[] Sample Condition Client Narne; WO# : 9246368-a Upon Receipt Project q Courier: []Fed Ex ❑UPS CUSPS ❑Client II III II III I IIII III III ❑ Commercial QPace ❑Other; 02463689 Custody Seal Present? Oyes 'EINo Seals Intact? Des `EjNo �,r j /� Datelinitials Person Examining Contents: L Packing Material: []Bubble Wrap Bubble Bags ❑None ❑ Other Thermometer: �Tr1C� Type of Ice: . Wet [:]Blue �R Gun ID: 921058 Cooler Temp (°C): �� J Correction Factor: Add/Subtract (°C) O.00C Cooler Temp Corrected CC): USDA Regulated Soll [ N/A, water sample) Did samples on�r'Hate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Flyp% 71n BloiaglcaI Tissue Frozen? ❑Yes ❑No �i N/A ❑None r Temp should be above freezing to VC []Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, Includina Hawaii and Puerto Ricol? nYes .FTN. Comments/Discrepancy: Chain of Custody Present? JZYes No ❑N/A 1. Samples Arrived within Hold Time? L..s ❑Na N/A 2. Short Hold Time Analysis (c72 hr.)? Yes No N A 3. Rush Turn Around Time Requested? 0yes ITNo ❑N/A 4. Sufficient Volume? Yes QNo N/A 5. Correct Containers Used? -Pace Containers Used? ,oyes UYiS ❑No ONO ❑N/A N/A 6. Containers Intact? Y'es No ❑N/A 7. Dissolved analysis: Samples Field Filtered? []Yes ❑No -lN/A B. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: QVes ❑No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? Yes ZiNo 041A 10. Trip Blank Present? Trip Blank Custody Seals Present? [}Yes 0es []No ONo ❑N/A N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOT]KATiON/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: 1 / ►y1r �o Project Manager SRF Review: Field Data Required? (—]Yes ❑No Date: D' I J1ZZj Date: 2L110 W Page 44 of 48 i aceAnaVicalY Document Name: Sample Condition Upon Recelpt{SCUR) Document Revised: February 7, 2019 Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-433-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechiorination Is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8615 (water) DOC, LLHg "Bottom half of box is to list number of battle Project it Wo# : 924636819 PM: AP Due Date: 02/13/20 CLIENT: 92—Shield a r 2 a 2 m C a E ry a in Z i' a C O a E In a m Z w Z w C 7 a E O a m ` Z a v N n a f1 w 7 a m U N v 2 C to N i E N v a m N v x n m Z a E 2 v in O Z Q Z a J E N N i m N s1 ^ x O a J E N V a m a M .o �] a rr=. 4 Z v Z v G C E Q a tJ d a U E Q ° tS a y Z 9 2 N n Q J of N lR a v to _ c N E Q a`+ W l7 d N V a qq O N S ¢ J E M l7 d u U x z y L E Q ry � r a M l7 d ? O J E q m t7 d ¢ z rn ON v7 O J E 4� t7 7 <Z O J E M c7 ZEE cQ?► S 0 — E Ch [7 0 4 ? m , R N y Y d O > �-� x = ~M. ! it a X ° U' > a N J E N ul a t 6 C C N d% N o. 0 M -P.+ a N Z a E Q M 0. m ? 'O III 2 a 7 E E p O —I G c7 Q Q z y io C n J E O N Y y Q E O V e1 C9 c Z l,� 3 L1 5 6 f 7 N\\IdY i 9 N\N �+ 10 11 �� r12 pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot It Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy or tnfs form will oe sentio the Noah Carolina utnnn CertuicauvuT Unite %I.E. Out of hold, incorrect preservative, out oftemp, incorrect containers. Page 45 of 48 Document Name: Document Revised: February 7, 2018 Analytical Sample Condition Upon Recelpt{SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev,06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: UDA, Coliform, TOC, Oil and Grease, ORO/8015 (water) DOC, LLHg **Bottom half of box Is to list number of bottle Project # WQ# : 92463689 PM: AP Due Date: 02/13/20 CLIENT: 92-Shield XL E _ GI a2i C c 7 E Ln a anm a a�i a c > E 0 4 Cl a�i G c > e o a 0 _ Z C 2 d n C Y _ a Ca N V pp N 0. E e. W V p• M 0 z S E c 6 m Z '�" W +.+ Q Z J E 6n Ir 0. m A G Y S 0 E Ln a m N C -'0 N m i7 9 a 3 Z v 2 Q c a Q .v_ _ .tea l7 a y 4 a a _ rl t7 a a 7 .E? of M l7 a V a 0 N 4 ey l7 a N = N S a Q E a M l9 a 2 _ 2 E a 0 M M U' a 2 E p a• t7 o ¢ 2 0 N ¢ E M 0 7 Z E 4A W a q 0 E 41 0 o Q z " in CL d O 7 Z Y b > 9 1� � ¢ A J E Ln iA Q iA ' \ 2 E 0 4 N 4, 0 M 7 0 Z E 0 LA T a mI ae a ] E E 8 ri C] U a Q 2 m b a -E V1 E a N {� q a z m } N Z L C Q E o Q 41 C7 o t \NNL/ I 3 I N \J 4 N N\N N\d 5 6 7 N\\ VT9 to \\N N 11 1z NN \1 N\ pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservatian adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will beient to the North Carolina DEHNR Certification Office {i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 46 of 48 /0 . -.2cmnalyfia .-YAcruss cam Section A Required Client Information: Company, Shield Address. 4301 Taggart Creek Road Charlotte, NC 28208 EmaiF kstachura@shieldenginecring.com Phone: (7D4)280-4787 Fax Requested Due Date. - - Section B Required Project Information Report To Kevin Stachura Copy To: Purchase Order Project Name, Carl's Country Store Project #: CHAIN -OF -CUSTODY 1 Analytical Request Document 00 o The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. V N Section C m Invoice Information- Pd 0 : 1 �f 1 IL Pace Quote: Pace Project h Pace Profile #: State I Location NC MATR ix CODE m a 0 COLLECTED z Preservatives � D—W9 Mw DW 'p O Wales WT waste waxy ww _ m ¢ U J m o m w jn g SAMPLE ID Sn VSeIW 5L 0a a y oil oL `� START END One Character per box. W.P. 1MP w 0 C1 m o c a (A-Z 0.9 J _} A,, AR Sample Ids must be unique Or ie os 00 X y 11 M o m Om — c e 0 s y n w O O 2 N m C Q o C'm a Q DATE TIME DATE TIME a = 2 2 z Q to w ll Iz 3 � MJ OU -''�- 5 '.Z ADDITIONAL COMMENTS RELINQUISHED BY!AFFILIATION DATE TIME ACCEPTED I3Y I AFFILUI N. DATE SAMPLECONDRSONS jTIME PLER NAME AND SIGNATURE c 0 PRINT Name of SAMPLER: � m a m `m SIGNATURE of SAMPLER: DATE Si ned: `m' Z N m O Z m m z ll l rf r>Uo t g Z/ /� ! } - �, 5 2aceAr, lr*Car CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT- All relevant fields must be completed accurately. Section A Section B Section C Required Client Information: Required Project information: Ynvoice Information: FP—. , : Of Company Shreld R,rpu To Kevin Stachura AII.W.0'% Kevin, Stachura Address 4301 Taggart Creek Road Copy TO Company Narne Shield Cesar loll,- NC 28208 Address 4301 Taggart Creek Road Charlolle, NC Regulatory Agency Email kstachura Shielden ineerin -com Purchase 07deT 4 Pace Quote NCDEQ-UST Phone (704)3944i913 Fax Protec: Nawe Carl's Counlry Store Pace Protect Manager State ! Location Reuuesled Due Date Standard (10 pa I Project # Pace Profile A NC Requested Anal sis Filtered YIN a Z_ nnATR{x CODE COLLECTED Z Preservatives } 0rrnkm9W.I.,DW n S U 0 r wat.r wT Waste Wass wW g ¢ w O -- Sei{f5alm Sl SAMPLE ID r� H - s } Or Ou c� START END F 4 C.. Character per box. Wog wP a {zt m w (A-z, 9-9 1. ) a, AR Olne, 4T o F a a m +) c� Sample Ids must he unique Ts x +L o O -�` N I— `a O C f V Z U m m m Q O U - 1 y pATE TIME DATE TIME u= _ _ z Z i O a 13 14 — wT 15 vTT 16 wT 17 18 19 20 21 22 23 24 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY( AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE U GIL � a PRINT Namo of SAMPLER:., . m w } y } mAIL SIGNATURE of SAMPLER:; RATE Signed: y U 00 0 eo v a� N d Beverly, Trudy From: Beverly, Trudy Sent: Friday, March 20, 2020 7:05 AM To: Kevin Stachura Subject: RE: [External] Carl's Country Store - Incident #9362 No need to resend the paper copy or cd. I'll print a copy of the statements & certification page to add there and insert the page into the electronic copy. Thanks for letting me know, Trudy Trudy Beverly, L.G. Hydrogeologist, Division of Waste Management 4!ro5f North Carolina Department of Environmental Quality ' D,1EN4.we Q� UST Section, Mooresville Regional Office 704.235.2182 (Office) Trudy.B everlyL&ncdenr. gov Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Office Mailing Address: 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Branch's Underground Storage Tanks Website Address: https://deq.nc.gov/about/divisions/waste-manaaement/ust Branch's Above Ground Storage Tanks Website Address: hgps://deg.nc.gov/about/divisions/waste-management/ust/ast-prosram INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES: httns://deo.nc. eov/about/divisions/waste-management/waste-management-rules-data/waste-management-eis-mans File Review Procedures: https://deq.nc. gov/about/divisions/waste-management/ust/file-review-procedures#mooresville-regional-office ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche): hit 2s://deg.nc.gov/about/divisions/waste-management/laserfiche Document Submittal & UST File Names for Laserfiche Policies: https:Hfiles.nc. gov/ncdeg/Waste%20Management/D WM/UST/Corrective%2OAction/Electronic%2ODocument%2OSubmittal%2OMemo%2OUpdate.pdf htips:Hfiles.nc. gov/ncdeq/Waste%20Management/D WM/UST/Corrective%2OAction/UST%20file%20names%20for%2OLaserfiche.docx From: Kevin Stachura [mailto:KStachura@shieldengineering.com] Sent: Thursday, March 19, 2020 5:07 PM To: Beverly, Trudy <trudy.beverly@ncdenr.gov> Subject: [External] Carl's Country Store - Incident #9362 ��External email. Do not click links or open attachments unless you verify. Send all suspicious email as an attachment to report.spam@nc.gov Hi Trudy, I hope you are doing well. Attached is a copy of the Carl's Country Store monitoring report for the February 2020 sampling event. A physical copy and CD was also be mailed to you. However, I noticed after mailing the report that in copy given to be filed with the project that the Statements & Certification page was not stamped and signed. Attached is a stamped and signed certification page. Would you prefer I resend the full report and CD? If you have any questions, please feel free to contact me. Thank you, Kevin Stachura Staff Geologist SHIELD ENGINEERING, INC. 4301 Taggart Creek Road Charlotte, NC 28208 (704) 394-6913 -office (704) 280-0787 -cell kstachura@shieldengineering.com Shield Engineering is a common sense provider of Environmental, Engineering Design, Geotechnical Engineering and Risk Management Services. This message is intended only for the use of the addressee and may contain information that is PRIVILEGED and CONFIDENTIAL, and/or may contain ATTORNEY WORK PRODUCT. If you are not the intended recipient, you are hereby notified that any dissemination of this communication is strictly prohibited. If you have received this communication in error, please erase all copies of the message and its attachments and notify us immediately. Thank you.