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HomeMy WebLinkAbout1201_Burke_KirkseyDrive_MSWLF_Fall2019GW_FID1393612_20200304ENR USE ONLY: ❑Paper Report ❑Electronic Data - Email CD data loaded: Yes / No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc ). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D., P.G. Phone: (336) 323-0092 E-mail: vburbach@jlabellapc.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Burke Co. Kirksey Dr. Landfill Kirksey Drive November 4-5, 2019 12-01 Morganton, NC .0500 January 23, 2020 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., P.G. Technical Consultant (336) 323-0092 a Code) Telephone Number 2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Affix NC Licensed/ Professional Geologist Seal a J � SEAL 1349 = ,���"'•:;v MESS LaBeRa Powered by oartnershio. March 04, 2020 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Via Email: jaclynne.drummond@ncdenr.gov RE: November 2019 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2192621 Dear Ms. Drummond: Please find the attached November 2019 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the November 2019 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form and the laboratory EDD's. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide them upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates rzo�t-lr--� Van Burbach, Ph.D., P.G. Sr. Technical Consultant Enclosure Cc: Miles Champion - Burke County 2211 W. Meadowview Road #sos I Greensboro, NC 27407 1 p (336) 323-0092 www.labetlapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 28680 L ii 1i;a r. is R' 1* �j Submitted by: LaBella Associates (Joyce Engineering) 2211 West Meadowview Rd. Suite 101 Greensboro, NC 27407 (336) 323-00g2 NC License No. C-0782 LaBeRa Powered by partnership. NOVEMBER 2019 SEMIANNUAL WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 MARCH 2O20 PROJECT NO. 2192621 November 2019 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information................................................................................................................ 1 1.2 Site Geology........................................................................................................................ 1 1.3 Regulatory Status............................................................................................................... 2 2.0 FACILITY MONITORING PROGRAM...................................................................................2 2.1 Groundwater Monitoring Program.................................................................................... 2 2.2 Surface Water Monitoring Program.................................................................................. 2 3.0 NOVEMBER 2019 SEMIANNUAL SAMPLING EVENT.......................................................3 3.1 Field Work...........................................................................................................................3 3.2 Laboratory Analysis and Quality Control........................................................................... 4 4.0 HYDROGEOLOGY..............................................................................................................4 5.0 DATA ANALYSIS................................................................................................................6 5.1 Analytical Results and Comparison to Standards............................................................ 6 5.1.1 Groundwater............................................................................................................6 5.1.2 Surface Water..........................................................................................................6 7.0 REFERENCES....................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 i November 2019 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 November 2019 Groundwater Elevations Table 2 November 2019 Estimated Hydraulic Gradients and Velocities Table 3 November 2019 Detections of Constituents Table 4 November 2019 Exceedances of Standards Table 5 November 2019 Field Parameters Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 ii 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (graywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 1 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane. Well MW-1 was damaged and has not been able to be sampled. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points (SMP-1, SMP-2, and SMP-3) comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as water supply IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents plus 1,4-dioxane. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 2 Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 NOVEMBER 2019 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On November 4-5, 2019, personnel from LaBella visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for replacement. Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the November 2019 monitoring event can be found in Tabie 1. Monitoring wells were purged using either disposable bailers, or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field data logs are included in Appendix 1. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a and field sampling logs for the resampling event are provided in Appendix 1. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the November 2019 monitoring event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity and recorded in the site log book. Immediately Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 3 after sample collection, the samples were placed on ice in a laboratory -provided cooler. Analytical reports, chains -of -custody, and field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The November 2019 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory on November 6, 2019, in good condition, properly preserved, at proper temperature, and within analysis hold times. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by LaBella personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only, and both were analyzed for 1,4-dioxane. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); • Detections above the 15A NCAC 2L Groundwater Standards (NC2L), NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC 2B Surface Water Standards (NC2B), or NC Protective Values (NCPV); and • Detections that are above historical levels. Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. 4.0 HYDROGEOLOGY The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 4 Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in November 2019, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the November 2019 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.053 to 0.061, with an average of approximately 0.068. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: Where; V = Ki/ne V = average linear velocity, K = hydraulic conductivity, i = horizontal hydraulic gradient and ne = effective porosity. The mean of hydraulic conductivities from slug -tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of ne = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 319 to 526 feet/year, with an average flow velocity of approximately 404 feet/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplifying assumptions of a homogeneous and isotropic aquifer, which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 5 5,0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the November 2019 monitoring event are listed in Table 3. Results with quantified concentrations above their respective NC 2L or IMAC are presented in Table 4. Field parameter data from the November 2019 event are summarized in Table 5. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2), and historical groundwater field parameters can be found in Appendix 2 (Table A2-3). During the November 2019 monitoring event, the constituents detected at quantified concentrations above the MRL in the groundwater samples included: barium (all monitoring wells; cobalt (MW-2, MW-3S); chromium (MW-4); lead (MW-2); nickel (MW-2, MW-3D); thallium (MW-5); vanadium (MW-2, MW-4); zinc (MW-4); acetone (MW-2); benzene (MW-2, MW-3S, MW-3D); chlorobenzene (MW-2, MW-3S, MW-3D); ethylbenzene (MW-2); tetrachloroethene (MW-3D, MW-4); toluene (MW-2); trichloroethene (MW-3D), xylenes (MW-2, MW-3S), 1,1-dichloroethene (MW-3D, MW-4); 1,2-dichlorobenzene (MW-2); 1,4-dichlorobenzene (MW-2, MW-3S, MW-3D); 2-butanone (MW-2); 4-methyl-2-pentanone (MW-2); 1,4-dioxane (MW-2, MW-3S, MW-3D, MW-4); and cis-1,2-dichloroethene (MW-3D, MW-4). The constituents detected at quantified concentrations in exceedance of their respective NC 2L or IMAC standard during the November 2019 sampling event include: barium (MW-2); cobalt (MW-2, MW-3S); vanadium (MW-2, MW-4); benzene (MW-2, MW-3S, MW-3D), tetrachloroethene (MW-3D, MW-4), trichloroethene (MW-3D); 1,4-dichlorobenzene (MW-2, MW-3S); and 1,4-dioxane (MW-2, MW-3S, MW-3D). In general, these detections are consistent with historical data for the site with the exception of vanadium in monitoring wells MW-2 and MW-4. A resampling event for these constituents took place on January 23, 2020, the results of which confirmed the vanadium exceedance in MW-2, but refuted the exceedance in MW-4 (see Tables 3 and 4). 5.1.2 Surface Water Inorganic and organic constituents detected in the surface water during the November 2019 monitoring event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A24), and historical surface water field parameters can be found in Appendix 2 (Table A2-5). The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC 213 Standards or NC In -stream Target Values for class WS-IV waters during this sampling event. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 6 6.0 CONCLUSION The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for November 2019. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates November 2019 Semiannual Water Quality Monitoring Report March 2020 7 TABLES Table 1 Table 2 Table 3 Table 4 Table 5 November 2019 Groundwater Elevations November 2019 Estimated Hydraulic Gradients and Velocities November 2019 Detections of Constituents November 2019 Exceedances of Standards November 2019 Field Parameters TABLE 1: November 2019 Groundwater Elevations Location TOC Elevation (Ft-AMSL) Depth to Groundwater (Ft-BTOC) Lithology Well Depth (Ft-BTOC) Groundwater Elevation (Ft-AMSL) MW-1 1119.82 29.86 Saprolite 35.65 1089.96 MW-2 1077.23 26.30 Saprolite 45.70 1050.93 MW-3S 1022.76 6.35 Bedrock 26.69 1016.41 MW-3D 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 22.72 Saprolite 29.50 1032.27 MW-5 1137.43 35.92 Saprolite 49.80 1101.51 MW-6S 1065.00 10.10 Bedrock 25.00 1054.90 MW-6D 1065.00 11.91 Saprolite 60.00 1053.09 Notes: TOC = Top of casing Ft-BTOC = Feet below TOC Ft-AMSL = Feet above mean sea level Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 TABLE 2: November 2019 Hydraulic Gradients and Velocities Water Levels Measured: November 4, 2019 GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (feet) FLOW DIRECTION GROUNDWATER ELEVATION (feet) HORIZONTAL GRADIENT i HYDRAULIC CONDUCTIVITY K (feet/day) EFFECTIVE POROSITY n LINEAR VELOCITY V (feet/year) 1100 11 910 NW 0.0879 3.28E+00 0.20 526 1020 1100 12 1,312 NE 0.0534 3.28E+00 0.20 319 1030 1100 1 g 1,144 N 0.0612 3.28E+00 0.20 366 1030 AVERAGE: 0.0675 AVERAGE: 404 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V= Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: Detections of Constituents SAMPLE ID PARAMETER RESULT UNITS METHOD MDL MRL Standard Source DATE Barium 1370 pg/L EPA 6010D 1 5 700 NC21- Cobalt 119 pg/L EPA 6010D 1.1 5 1 IMAC Copper 3.3 J pg/L EPA 6010D 2.1 5 1,000 NC21- Lead 5.2 pg/L EPA 6010D 1.6 5 15 NC21- Nickel 16.8 pg/L EPA 6010D 0.9 5 100 NC21- Vanadium 5.3 pg/L EPA 6010D 1.3 5 0.3 IMAC 1,1-Dichloroethane 0.57 J pg/L EPA 8260D 0.27 1 6 NC2L 1,2-Dichlorobenzene 2.2 pg/L EPA 8260D 0.29 1 20 NC2L 1,4-Dichlorobenzene 38.6 pg/L EPA 8260D 0.26 1 6 NC21- 2-Butanone (MEK) 14.8 pg/L EPA 8260D 3.3 5 4,000 NC2L 11/5/2019 MW-2 4-Methyl-2-pentanone (MIBK) 11.2 pg/L EPA 8260D 4.5 5 40 IMAC Acetone 105 pg/L EPA 8260D 6.2 25 6,000 NC21- Benzene 8.3 pg/L EPA 8260D 0.15 1 1 NC21- Chlorobenzene 22.5 pg/L EPA 8260D 0.23 1 50 NC21- cis-1,2-Dichloroethene 0.33 J pg/L EPA 8260D 0.29 1 70 NC2L Ethylbenzene 12.1 pg/L EPA 8260D 0.26 1 600 NC21- Toluene 1.1 pg/L EPA 8260D 0.24 1 600 NC2L Xylene (Total) 22.3 pg/L EPA 8260D 0.63 1 500 NC21- 1,4-Dioxane (p-Dioxane) 236 pg/L EPA 8260D Mod. 5.8 10 3 NC21- Vanadium (Resample) 5.1 pg/L EPA 6010D 1.3 5 0.3 IMAC 1/23/2019 Barium 219 pg/L EPA 6010D 1 5 700 NC21- Nickel 28.7 pg/L EPA 6010D 0.9 5 100 NC21- Thallium 0.061 J pg/L I EPA 6020B 0.06 0.1 0.2 IMAC 1,1-Dichloroethane 4.7 pg/L EPA 8260D 0.27 1 6 NC2L 1,2-Dichloropropane 0.87 J pg/L EPA 8260D 0.19 1 0.6 NC2L 1,4-Dichlorobenzene 4.2 pg/L EPA 8260D 0.26 1 6 NC2L MW-3D Benzene 1.3 pg/L EPA 8260D 0.15 1 1 NC2L 11/5/2019 Chlorobenzene 7.5 pg/L EPA 8260D 0.23 1 50 NC21- cis-1,2-Dichloroethene 14.6 pg/L EPA 8260D 0.29 1 70 NC21- Tetrachloroethene 6.5 pg/L EPA 8260D 0.16 1 0.7 NC21- Trichloroethene 4.8 pg/L EPA 8260D 0.22 1 3 NC2L 1,4-Dioxane (p-Dioxane) 269 pg/L EPA 8260D Mod. 5.8 10 3 NC21- Barium 448 pg/L EPA 6010D 1 5 700 NC21- Cobalt 12.3 pg/L EPA 6010D 1.1 5 1 IMAC Lead 2.0 J pg/L EPA 6010D 1.6 5 15 NC21- Nickel 3.3 J pg/L EPA 6010D 0.9 5 100 NC21- Vanadium 1.8 J pg/L EPA 6010D 1.3 5 0.3 IMAC 1,1-Dichloroethane 0.43 J pg/L EPA 8260D 0.27 1 6 NC2L MW-3S 1,2-Dichlorobenzene 0.6 J pg/L EPA 8260D 0.29 1 20 NC21- 11/5/2019 1,4-Dichlorobenzene 10.7 pg/L EPA 8260D 0.26 1 6 NC21- Benzene 3.4 pg/L EPA 8260D 0.15 1 1 NC21- Chlorobenzene 32.7 pg/L EPA 8260D 0.23 1 50 NC21- Xylene (Total) 14.3 pg/L EPA 8260D 0.63 1 500 NC21- 1,4-Dioxane (p-Dioxane) 36.4 pg/L EPA 8260D Mod. 1.2 2 3 NC21- Barium 130 pg/L EPA 6010D 1 5 700 NC21- Chromium 5.9 pg/L EPA 6010D 1 5 10 NC21- Cobalt 1.6 J pg/L EPA 6010D 1.1 5 1 IMAC Copper 4.6 J pg/L EPA 6010D 2.1 5 1,000 NC21- Nickel 2.4 J pg/L EPA 6010D 0.9 5 100 NC21- Vanadium 10.0 pg/L EPA 6010D 1.3 5 0.3 IMAC Zinc 15.4 pg/L EPA 6010D 3.9 10 1,000 NC21- 11/4/2019 MW-4 Thallium 0.06 J pg/L EPA 6020B 0.06 0.1 0.2 IMAC 1,1-Dichloroethane 1.5 pg/L EPA 8260D 0.27 1 6 NC21- 1,4-Dichlorobenzene 0.48 J pg/L EPA 8260D 0.26 1 6 NC21- cis-1,2-Dichloroethene 8.0 pg/L EPA 8260D 0.29 1 70 NC21- Tetrachloroethene 1.8 pg/L EPA 8260D 0.16 1 0.7 NC21- Trichloroethene 0.72 J pg/L EPA 8260D 0.22 1 3 NC21- 1,4-Dioxane (p-Dioxane) 2.7 pg/L EPA 8260D Mod. 1.2 2 3 NC2L Vanadium (Resample) 2.3 J pg/L EPA 6010D 1.3 5 0.3 IMAC 1/23/2019 Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 1 of 2 LaBella Associates TABLE 3: Detections of Constituents SAMPLE ID PARAMETER RESULT UNITS METHOD MOIL MRL Standard Source Barium 46.5 pg/L EPA 6010D 1 5 700 NC21- Beryllium 0.23 J pg/L EPA 6010D 0.2 1 4 IMAC Chromium 1.8 J pg/L EPA 6010D 1 5 10 NC21- Cobalt 1.3 J pg/L EPA 6010D 1.1 5 1 IMAC MW-5 Nickel 1.0 J pg/L EPA 6010D 0.9 5 100 NC21- 11/4/2019 Vanadium 3.8 J pg/L EPA 6010D 1.3 5 0.3 IMAC Zinc 7.5 J pg/L EPA 6010D 3.9 10 1,000 NC21- Thallium 0.16 pg/L EPA 6020B 0.06 0.1 0.2 IMAC Barium 17.0 pg/L EPA 6010D 1 5 700 NC21- 11/4/2019 MW-6D Zinc 7.0 J pg/L EPA 6010D 3.9 10 1,000 NC21- Barium 35.6 pg/L EPA 6010D 1 5 700 NC21- MW-6S Chlorobenzene 0.28 J pg/L EPA 8260D 0.23 1 50 NC21- 11/4/2019 Barium 34.5 pg/L EPA 6010D 1 5 1,000 NC2B SW-1 Vanadium 1.4 J pg/L EPA 6010D 1.3 5 NE 11/5/2019 Hardness, Total 28300 pg/L EPA 6010D 131 662 100,000 NC213 Barium 35.9 pg/L EPA 6010D 1 5 1,000 NC213 Beryllium 0.24 J pg/L EPA 6010D 0.2 1 6.5 NC213 11/5/2019 SW-2 Vanadium 1.5 J pg/L EPA 6010D 1.3 5 NE Hardness, Total 29100 pg/L EPA 6010D 131 662 100,000 NC2B Barium 34.8 pg/L EPA 6010D 1 5 1,000 NC213 SW-3 Vanadium 1.5 J pg/L EPA 6010D 1.3 5 NE 11/5/2019 Hardness, Total 28500 pg/L EPA 6010D 131 662 100,000 NC2B Notes: ug/L= micrograms per liter. MDL = Method Detection Limit NC21- = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) MRL = Method Reporting Limit NC213 = NC Surface Water Standard from15A NCAC 2B J = Estimated concentration below the MRL (Note that NC2B for some metals is hardness -dependant.) B = Blank-qualilfied data due to detections in equipment, trip, or method blanks. ISTV = NC In -Stream Target Values Bold = quantified detections above the Standard NE = Not established Burke Co. - Kirksey Dr. Landfill Permit # 12-01 Page 2 of 2 LaBella Associates TABLE 4: Exceedances of Standards SAMPLE ID PARAMETER RESULT UNITS METHOD MDL MRL Standard Source DATE MW-2 Barium 1370 pg/L EPA 6010D 1 5 700 NC21- 11/5/2019 Cobalt 119 pg/L EPA 6010D 1.1 5 1 IMAC Vanadium 5.3 pg/L EPA 6010D 1.3 5 0.3 IMAC 1,4-Dichlorobenzene 38.6 pg/L EPA 8260D 0.26 1 6 NC21- Benzene 8.3 pg/L EPA 8260D 0.15 1 1 NC21- 1,4-Dioxane (p-Dioxane) 236 pg/L EPA 8260D Mod. 5.8 10 3 NC2L Vanadium (Resample) 5.1 pg/L EPA 6010D 1.3 5 0.3 IMAC 1/23/2019 MW-3D Benzene 1.3 pg/L EPA 8260D 0.15 1 1 NC2L 11/5/2019 Tetrachloroethene 6.5 pg/L EPA 8260D 0.16 1 0.7 NC2L Trichloroethene 4.8 pg/L EPA 8260D 0.22 1 3 NC21- 1,4-Dioxane (p-Dioxane) 269 pg/L EPA 8260D Mod. 5.8 10 3 NC2L MW-3S Cobalt 12.3 pg/L EPA 6010D 1.1 5 1 IMAC 11/5/2019 1,4-Dichlorobenzene 10.7 pg/L EPA 8260D 0.26 1 6 NC2L Benzene 3.4 pg/L EPA 8260D 0.15 1 1 NC21- 1,4-Dioxane (p-Dioxane) 36.4 pg/L EPA 8260D Mod. 1.2 2 3 NC2L MW-4 Vanadium 10.0 pg/L EPA 6010D 1.3 5 0.3 IMAC 11/4/2019 Tetrachloroethene 1.8 pg/L EPA 8260D 0.16 1 0.7 NC21- Vanadium (Resample) 2.3 J pg/L EPA 6010D 1.3 5 0.3 IMAC 1/23/2019 Notes: pg/L= micrograms per liter. MDL = Method Detection Limit NC21- = NC Groundwater Standard frme 15A NCAC 2L.0202 IMAC = NC Interim Maximum Allowable Concentration (IMAC) MRL = Method Reporting Limit J = Estimated concentration below the MRL B = Blank-qualilfied data due to detections in equipment, trip, or method blanks. Burke Co. - Kirksey Dr. Landfill Permit # 12-01 LaBella Associates TABLE 5: November 2019 Field Parameters GW Upgradient Groundwater Downgradient Surface Water Parameter Units Collect Date MW-1 MW-2 MW-3S MW-3D I MW-4 MW-5 MW-6S MW-6D SW-1 SW-2 SW-3 Well Depth Ft. -- 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 -- -- -- pH S.U. 11/4/2019 -- 5.64 5.94 6.15 5.43 5.49 5.28 5.54 6.60 6.78 6.63 Temperature °C 11/4/2019 -- 15.1 13 16.4 14.7 15.3 16.4 16.4 10.07 10.6 10.7 Conductivity pS/cm 11/4/2019 -- 2225 831 853 92.1 18.3 59.3 90 78 92.4 80.9 Dissolved Oxygen mg/L 11/4/2019 -- 1.63 1.85 4.39 3.99 4.36 3.55 2.89 7.23 6.56 7.27 Oxidation Reduction Potential my 11/4/2019 -- 33.3 85.4 180.3 199 146.4 208.3 -81.6 147.6 43.4 99.9 Turbidity NTU 11/4/2019 -- 4.79 9 3.01 35.17 41.13 8.49 30.39 11.64 10.4 9.99 Static Water Level Ft. 11/4/2019 29.86 29.40 6.35 0.00 22.72 35.92 10.10 11.91 -- -- -- pH S.U. 1/23/2020 -- 4.64 -- -- 5.75 -- -- -- -- -- -- Temperature °C 1/23/2020 -- 15.8 -- -- 14.7 -- -- -- -- -- -- Conductivity pS/cm 1/23/2020 -- 2540 -- -- 87.1 -- -- -- -- -- -- Dissolved Oxygen mg/L 1/23/2020 -- 1.38 -- -- 3.25 -- -- -- -- -- -- Oxidation Reduction Potential my 1/23/2020 -- 35.3 -- -- 179.8 -- -- -- -- -- -- Turbidity NTU 1/23/2020 -- 6.48 -- -- 8.03 -- -- -- -- -- -- Static Water Level I Ft. 1 1/23/2020 1 26.53 -- -- 20.49 -- -- -- -- -- -- Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microSemens per centimeter my = millivolts NTU = Nephelometric Turbidity Units Ft = feet Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map a6 ,ram_ -` ' `�- -,, .•r .� " �� �' � .. ti i n `160 900 ate_- f ._" •;t � - APPROXIMATE LOCATION OF PROPERTY LINE SCALE ' 2001) 0� s yO— �_.+• .. s Cam. i ► -l'1380 40 0,:3LaBella ISSUED FOR: GROUNDWATER MONITORING REPORT Powered by partnership. DRAWING NAME: SITE LOCATION MAP DRAWN BY: RWH DATE: 02/27/19 PROJECT NO.: 2192621 2211 WEST MEADOWVIEW ROAD GREENSBORO, N.C.27407 PHONE: (336) 323-0092 PROJECT NAME: DRAWING NUMBER: KIRKSEY DRIVE LANDFILL Figure 1 labellapc.com © 2020 LaBella Associates BURKE COUNTY, NORTH CAROLINA N:\DWgs\Drawings—Current\BURKE\GW EVENT MAPS\, SITE LOCA-104 MAP KIRKSEY DRIVE 2020.dwg DRAWING Drawing 1 Groundwater Potentiometric Surface Map LaBella Powered by partnership. 9731-F SOUTHERN PINE BLVD CHARLOTTE, NC 28273 PHONE: 817-2037 (704) labellapc.com F T / SMP-1 LIMITS OF WASTIf+T-YP j — \ ---��--------- LIMITS OF WASTE //I %'r M 2 T T 50.93 \ 10164 SMP-Z SMP-3 O {NW-3D / I \ \ 1 _02� / / © 2019 LaBella Associates100y s 40 j 1040� 0� / / O ` \ 14 1030 KIRKSEY DRIVE LANDFILL \ �...�\}` BURKE COUNTY, NORTH CAROLINA 270/ 1050 ^ / 1p60 / Mw-ss 1054.90 MW3.0 089 2. \ �`---- — — 090� �— —_ 10?0 1 - MW 5 / 7p8 GRAPHIC SCALE \ ` � ;-00/j 1101.51 JJ 0 \ �150 300 -11500- 00 —J (FE&l NOTES LEGEND 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. N0: DATE: DESCRIPTION Revisions 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD 2• GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. PROJECT NUMBER: 2181871 (� EXISTING 20' TOPOGRAPHIC CONTOUR APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS WERE MEASURED ON NOVEMBER 4, 2019. DRAWN BY: RH RENEWED BY: VB ISSUED FOR: GROUNDWATER REPORT GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION OHO — — — — — DATE: oz/zo/zozo ABOVE MEAN SEA LEVEL (AMSL)] BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, COMPLIANCE WELL LOCATION AND TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. - MW-5 DRAWING NAME: IDENTIFICATION WITH STATIC WATER — — PROPERTY LINE ELEV LEVEL ELEVATION (FEET AMSL) GROUNDWATER FLOW PATHWAY USED TO FLOW PATH LENGTH PERMIT N0.12-01 CALCULATE HYDRAULIC GRADIENT O SW-2 SURFACE MONITORING POINT LOCATION GROUNDWATER POTENTIOMETRIC AND IDENTIFICATION LF Q SURFACE MAP SEGMENT USED FOR GRADIENT CALCULATION ONOVEMBER 4, 2019 1 1,3 Z2 12 LF DRAWING NUMBER'. i3 1,144 LF 1 APPENDICES Appendix 1 Field Logs and Laboratory Analytical Reports Appendix 2 Historical Data APPENDIX 1 Field Logs and Laboratory Analytical Reports DATE: La BeRa ,P GROUND WATER SAMPLING LOG Project Name: _Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: Sampler(sr): D. Knagge/ A. Martin Well Location: A4P 0� �2' S��P af- 4uanu U Well Diameter: 2 inches Initial Depth to Water (DTW): "A feet Depth to Bottom (DTB): L1P5 feet Water Column Thickness (WCT): feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = MD gallons For 4" Well: WCT X 0.653 = gallons For THREE Well Volumes: WV X 3 = gallons Actual Amount Purged/Bailed: .—gallons Purged with: Sampled witt Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials ® JOV5 t(o.�3 545 f'6'Iq 2,L1 i(00ol 15. 0 DL '--5 �aIA Ivb,S ':�"V5 24LAc6 3,a,S GO-\ 15.2$ JD C b 1,u- �(,05 6,'isl a3(oa i-A-P-2 iAq, l t(o, 6(o 'DK Ck c q I(.,s P,- g,g- 5•LA 3Q�`5 C6,5 V__ Date of sample: lck of Before Sampling Qguo v5' .I Pl,A Comments (weather conditions, odor, color, silt, etc.): Signature: 4Date:" 15 1 1 1 QA/QC Sign Off: Date: LaBelLa DATE: '� �I I�l Pw eiexiby r GROUNDWATER SAMPLING LOG Project Name: _Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: ftA)-- � Sampler(s): D. Knagge/ A. Martin Well Location: l avyf\ � 6e Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: For 4" Well: For THREE Well Volumes: Actual Amount Pui Purged with: WCT X 0.163 WCT X 0.653 WVX3 !ailed: an. Uwnvar P, � - , Neav, PN �4-3-D 2 inches Co o -75c> feet feet a ' feet [DTB-DTW] _a gallons _ gallons gallons agallons Other: Sampled with: ((Bailer -,,� Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 1 �� oa . " " b5 tb--�d 3 Date of sample: L� Before Sampling 5 oP,IA qN 1 �9G (�s 175� i� r D Comments (weather conditions, odor, color, silt, etc.): Signature: A Date: r f P-AI C1 QA/QC Sign Off: Date: l ��( DATE: �, `�I19 LaBetLa GROUND WATER SAMPLING LOG Project Name: Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: r(1vJ -Sampler(s): D. Knagge/ A. Martin Well Location: D©w,\ b re �, Q n r\ a, .ar.v �A • mw -3 S Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt 2 inches 0 � o feet feet feet [DTB-DTW] gallons gallons gallons 3 -gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials tG- 5 (a. 0-- <)(lae-a --3. 3 aot Date of sample: Before Sampling 1 o - Comments (weather conditions, odor, color, silt, etc.): era► >CVveN —t r V-\ 1 �-F• �� g - AY Ness &k wk-\� i FSignature: Date: QA/QC Sign Off: Date: DATE: `1 LaBetLa J .. GROUND WATER SAMPLING LOG Project Name: Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: maj. Sampler(s): D. Knagge/ A. Martin Well Location: �uS� 1ii4�ti 4n_ S� - 0 � �,arf k heck( t� �r- Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witt Depth to Water before Sampling: M, JA feet 2 Jnches 9Q ova feet aok oCD� 0 feet feet [DTB-DTW] _ e gallons gallons gallons gallons Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials o NOL � .�- t�r�q ��t. r a. �- 2 �� �'P' J', OW 8 '1, q 0 q 1. 0 �a_f'06 e 3. ;4�7D VR VA 1/4-2 JOt 6 1 ;,00 2qO,41 T AA AAA Date of sample: i�� Before Sampling ��- � ` y 'la ?Jdq� �jc 0- Comments (weather conditions, odor, color, silt, etc.): Signature::1 I ���w2Date: M1 i I /1 � DATE: `I LaBelLa GROUND WATER SAMPLING LOG Project Name: Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: M vJ -L Sampler(s)): D. Knagge/ A. Martin Well Location: Po"U'- 0� avmgr� � cnr �nq �p`t el k)� r•o�r�� Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: For THREE Well Volumes: Actual Amount Pui Purged with: WCT X 0.163 WCT X 0.653 WVX3 lailed: 2 inches 6 'off feet a 2�® feet l'3 • �i� feet [DTB-DTW] 2 3 gallons gallons =—gallons (a, gallons Sampled with: .(Bailer) Pump Other: Depth to Water before Sampling: 1 feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials . 6 1201 k 0' 6 p l+• 13 t5�• 1 � -. Date of sample: o� Before Sampling v7k V5 '� �Jd °1 zj� `� .3�_r ��,��°� �� • i;l Comments (weather conditions, odor, color, silt, etc.): tl�. Signature:�_ i l il�. X�Lk) • - DATE: JL (. T LaBelLa - GROUND WATER SAMPLING LOG Project Name: Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: f'v,A1 Sampler(s): D. Knagge/ A. Martin Well Location: Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witl' r- 2 inches Inn feet 'ova ® feet A -A feet [DTB-DTW] .2_gallons Depth to Water before Sampling: j k .1©i feet gallons gallons gallons Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP Turb. (ntu) Initials ■/�m�,�yay N\ �a1 W. 0 �� `� ��,�- � � ices 1-7, LD �► °"(\ V o �c' 0� `� �'�53 i y':� PS, 7 -2 V�3 4 .c5 rz., 2lei ZZA z 5 A(�A Date of sample: 6 vq Before Sampling 12 `(A zdz `8- (Acl � Comments (weather conditions, odor, color, silt, etc.): Signature: 0ez5— Date:7 QA/QC Sign Off: Date: [ DATE: L l La BelLa ,id by.partner5i GROUND WATER SAMPLING LOG Project Name: _Burke Co. - Kirksey Drive Project No. /Task No.: 2192621.00/02 Well ID: MA-0 - (,oV Sampler(s): D. Knagge/ A. Martin Well Location: Dcly, +Volt' Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): M r��M 2 inches 1 low I feet (ff®$ 0 feet q%. dq feet [DTB-DTW] Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 = o gallons For 4" Well: WCT X 0.653 =-gallons For THREE Well Volumes: WV X 3 = 2 -7? gallons Actual Ammint PiircFarl/RaiIsnH- -Z 3°5 csalInn c Purged with: Sampled witl Depth to Water before Sampling: 1�-Sok feet Gallons Time Temp (°C) pH Cond. (US/CM) Dis.02 mg/L ORP my Turb. (ntu) Initials 0 CQr5Q 15 t 5. a a, -"k I D bCra ��Gald i � rt.5� tDo.2 2- ito -G35:2 �m�� 4 JIs, ,C> 5.01 .9 k.°ko -�5_?> Date of sample: L klkhq Before Sampling tf,cA qm '2a$q R). Comments (weather conditions, odor, color, silt, etc.): Loe;�e:'( " (A0 5 t- sty V\y Signature: Date: QA/QC Sign Off: Date: l DATE: [Vol La Betta SURFACE WATER MONITORING LOG Project Name: Burke Co.- Kirksey Drive Project/Task No.: 2192621.00/02 Surface Point ID: ff�>� Sampler(s): A. Martin/ D. Knagge Location: Ckp �k.QNt,n 4 T rA e_ Qr i tam; ZA Field Parameters: Time of Sampling: pH: Q Temperature: Q4—+ (a C) Conductivity: zS ;,® (US/cm) Turbidity: \ • log (ntu) Dissolved Oxygen �'�_J� (mg/L) Oxidation -Reduction Potential q,-'. U (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): Summary/Sketch of Sampling Location / I / 5W , Signature: Date: l LI 6�) n QA/QC Sign Off: L VV0 Date: La Betty DATE: P.1-,, SURFACE WATER MONITORING LOG Project Name: Burke Co.- Kirksey Drive Project/Task No.: 2192621.00/02 Surface Point I13:43W _a Sampler(s1s): A. Martin/ D. Knagge Location: � ��c+ 4Q oy, Qu(rry R N - �A k-f Field Parametei�� Time of Sampling: pH: U . IS Temperature: (o (°C) Conductivity: (US/CM) Turbidity: t0 (ntu) Dissolved Oxygen CO -S(o (mg/L) Oxidation -Reduction Potential q3..L- (mv) Comments/Sample Descript. n (weather conditions, odor, color, silt, etc.): Signature: Date: V 4A l9 QA/QC Sign Off:. Date: 1(41P� DATE: C LaBetta IIVC SURFACE WATER MONITORING LOG Project Name: Burke Co.- Kirksey Drive Project/Task No.: 2192621.00/02 Surface Point ID: "F9kk -*�iJ ,� Sampler(s): A. Martin/ D. Knagge Location: DOVAII k-C4, o4r,� qe_ oa, lwrfu U. i ti ear ��✓� � �� Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Turbidity: Dissolved Oxygen Oxidation -Reduction Potential © -,Q (US/cm) q.qn (ntu) 1. --i.. (mg/L) qQ.'j (mv) Comments/Sample Description (weather conditions, odor, color, silt, etc.): lQ -P.��� f / (2 5 t`S L�v1v1 td Summary/Sketch of Sampling Location Date: l l) N Ln Date: L/ Wf 9 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 18, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Ashley Martin, Labella Associates Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Lab ID Sample ID Matrix Date Collected Date Received 92452518001 1201-MW2 Water 11/05/19 09:06 11/06/19 10:10 92452518002 1201-MW3S Water 11/05/19 07:30 11/06/19 10:10 92452518003 1201-MW3D Water 11/05/1911:15 11/06/19 10:10 92452518004 1201-MW4 Water 11/04/1917:30 11/06/19 10:10 92452518005 1201-MW5 Water 11/04/1917:17 11/06/19 10:10 92452518006 1201-MW6S Water 11/04/1917:00 11/06/19 10:10 92452518007 1201-MW6D Water 11/04/1917:10 11/06/19 10:10 92452518008 1201-SW1 Water 11/05/19 08:50 11/06/19 10:10 92452518009 1201-SW2 Water 11/05/19 08:15 11/06/19 10:10 92452518010 1201-SW3 Water 11/05/19 08:08 11/06/19 10:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co.-Kirksey Dr Closed LF 92452518 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92452518001 1201-MW2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518002 1201-MW3S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518003 1201-MW3D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518004 1201-MW4 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518005 1201-MW5 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518006 1201-MW6S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518007 1201-MW6D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518008 1201-SW1 EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518009 1201-SW2 EPA 601OD SH1 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452518010 1201-SW3 EPA 601OD SH1 15 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co.-Kirksey Dr Closed LF 92452518 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92452518001 1201-MW2 EPA 6010D Barium 1370 ug/L 5.0 11/15/1913:57 EPA 6010D Cobalt 119 ug/L 5.0 11/15/1913:57 EPA 6010D Copper 3.3J ug/L 5.0 11/15/1913:57 EPA 6010D Lead 5.2 ug/L 5.0 11/15/1913:57 EPA 6010D Nickel 16.8 ug/L 5.0 11/15/1913:57 EPA 6010D Vanadium 5.3 ug/L 5.0 11/15/1913:57 EPA 8260D Acetone 105 ug/L 25.0 11/15/19 05:31 EPA 8260D Benzene 8.3 ug/L 1.0 11/15/19 05:31 EPA 8260D 2-Butanone (MEK) 14.8 ug/L 5.0 11/15/19 05:31 EPA 8260D Chlorobenzene 22.5 ug/L 1.0 11/15/19 05:31 EPA 8260D 1,2-Dichlorobenzene 2.2 ug/L 1.0 11/15/19 05:31 EPA 8260D 1,4-Dichlorobenzene 38.6 ug/L 1.0 11/15/19 05:31 EPA 8260D 1,1-Dichloroethane 0.57J ug/L 1.0 11/15/19 05:31 EPA 8260D cis-1,2-Dichloroethene 0.33J ug/L 1.0 11/15/19 05:31 EPA 8260D Ethylbenzene 12.1 ug/L 1.0 11/15/19 05:31 EPA 8260D 4-Methyl-2-pentanone (MIBK) 11.2 ug/L 5.0 11/15/19 05:31 EPA 8260D Toluene 1.1 ug/L 1.0 11/15/19 05:31 EPA 8260D Xylene (Total) 22.3 ug/L 1.0 11/15/19 05:31 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 236 ug/L 10.0 11/10/19 00:55 92452518002 1201-MW3S EPA 6010D Barium 448 ug/L 5.0 11/15/1914:00 EPA 6010D Cobalt 12.3 ug/L 5.0 11/15/1914:00 EPA 6010D Lead 2.OJ ug/L 5.0 11/15/1914:00 EPA 6010D Nickel 3.3J ug/L 5.0 11/15/1914:00 EPA 6010D Vanadium 1.8J ug/L 5.0 11/15/1914:00 EPA 8260D Benzene 3.4 ug/L 1.0 11/15/19 05:50 EPA 8260D Chlorobenzene 32.7 ug/L 1.0 11/15/19 05:50 EPA 8260D 1,2-Dichlorobenzene 0.60J ug/L 1.0 11/15/19 05:50 EPA 8260D 1,4-Dichlorobenzene 10.7 ug/L 1.0 11/15/19 05:50 EPA 8260D 1,1-Dichloroethane 0.43J ug/L 1.0 11/15/19 05:50 EPA 8260D Xylene (Total) 14.3 ug/L 1.0 11/15/19 05:50 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 36.4 ug/L 2.0 11/09/19 22:57 92452518003 1201-MW3D EPA 6010D Barium 219 ug/L 5.0 11/15/1914:03 EPA 6010D Nickel 28.7 ug/L 5.0 11/15/1914:03 EPA6020B Thallium 0.061J ug/L 0.10 11/09/1902:38 EPA 8260D Benzene 1.3 ug/L 1.0 11/15/19 06:08 EPA 8260D Chlorobenzene 7.5 ug/L 1.0 11/15/19 06:08 EPA 8260D 1,4-Dichlorobenzene 4.2 ug/L 1.0 11/15/19 06:08 EPA 8260D 1,1-Dichloroethane 4.7 ug/L 1.0 11/15/19 06:08 EPA 8260D cis-1,2-Dichloroethene 14.6 ug/L 1.0 11/15/19 06:08 EPA 8260D 1,2-Dichloropropane 0.87J ug/L 1.0 11/15/19 06:08 EPA 8260D Tetrachloroethene 6.5 ug/L 1.0 11/15/19 06:08 EPA 8260D Trichloroethene 4.8 ug/L 1.0 11/15/19 06:08 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 269 ug/L 10.0 11/10/19 01:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co.-Kirksey Dr Closed LF 92452518 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92452518004 1201-MW4 EPA 6010D Barium 130 ug/L 5.0 11/15/1914:18 EPA 6010D Chromium 5.9 ug/L 5.0 11/15/1914:18 EPA 6010D Cobalt 1.6J ug/L 5.0 11/15/1914:18 EPA 6010D Copper 4.6J ug/L 5.0 11/15/1914:18 EPA 6010D Nickel 2AJ ug/L 5.0 11/15/1914:18 EPA 6010D Vanadium 10 ug/L 5.0 11/15/1914:18 EPA 6010D Zinc 15.4 ug/L 10.0 11/15/1914:18 EPA 6020B Thallium 0.060J ug/L 0.10 11/09/19 02:46 EPA 8260D 1,4-Dichlorobenzene 0.48J ug/L 1.0 11/15/19 02:45 EPA 8260D 1,1-Dichloroethane 1.5 ug/L 1.0 11/15/19 02:45 EPA 8260D cis-1,2-Dichloroethene 8.0 ug/L 1.0 11/15/19 02:45 EPA 8260D Tetrachloroethene 1.8 ug/L 1.0 11/15/19 02:45 EPA 8260D Trichloroethene 0.72J ug/L 1.0 11/15/19 02:45 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 2.7 ug/L 2.0 11/09/19 23:17 92452518005 1201-MW5 EPA 6010D Barium 46.5 ug/L 5.0 11/15/1914:21 EPA 6010D Beryllium 0.23J ug/L 1.0 11/15/1914:21 EPA 6010D Chromium 1.8J ug/L 5.0 11/15/1914:21 EPA 6010D Cobalt 1.3J ug/L 5.0 11/15/1914:21 EPA 6010D Nickel 1.0J ug/L 5.0 11/15/1914:21 EPA 6010D Vanadium 3.8J ug/L 5.0 11/15/1914:21 EPA 6010D Zinc 7.5J ug/L 10.0 11/15/1914:21 EPA 6020B Thallium 0.16 ug/L 0.10 11/09/19 02:54 92452518006 1201-MW6S EPA 6010D Barium 35.6 ug/L 5.0 11/15/19 22:28 EPA 8260D Chlorobenzene 0.28J ug/L 1.0 11/15/19 03:22 92452518007 1201-MW6D EPA 6010D Barium 17.0 ug/L 5.0 11/15/19 22:40 EPA 6010D Zinc 7.OJ ug/L 10.0 11/15/19 22:40 92452518008 1201-SW1 EPA 6010D Barium 34.5 ug/L 5.0 11/15/19 22:43 EPA 6010D Hardness, Total(SM 2340B) 28300 ug/L 662 11/15/19 22:43 EPA 6010D Vanadium 1 AJ ug/L 5.0 11/15/19 22:43 92452518009 1201-SW2 EPA 6010D Barium 35.9 ug/L 5.0 11/15/19 22:46 EPA 6010D Beryllium 0.24J ug/L 1.0 11/15/19 22:46 EPA 6010D Hardness, Total(SM 2340B) 29100 ug/L 662 11/15/19 22:46 EPA 6010D Vanadium 1.51 ug/L 5.0 11/15/19 22:46 92452518010 1201-SW3 EPA 6010D Barium 34.8 ug/L 5.0 11/15/19 22:56 EPA 6010D Hardness, Total(SM 2340B) 28500 ug/L 662 11/15/19 22:56 EPA 6010D Vanadium 1.51 ug/L 5.0 11/15/19 22:56 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW2 Lab ID: 92452518001 Collected: 11/05/19 09:06 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 13:57 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 13:57 7440-38-2 1370 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 13:57 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 13:57 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 13:57 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 13:57 7440-47-3 119 ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 13:57 7440-48-4 3.3J ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 13:57 7440-50-8 5.2 ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 13:57 7439-92-1 16.8 ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 13:57 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 13:57 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 13:57 7440-22-4 5.3 ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 13:57 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 13:57 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:22 7440-28-0 Analytical Method: EPA 8260D 105 ug/L 25.0 6.2 1 11/15/19 05:31 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 05:31 107-13-1 8.3 ug/L 1.0 0.15 1 11/15/19 05:31 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 05:31 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 05:31 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 05:31 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 05:31 74-83-9 IK 14.8 ug/L 5.0 3.3 1 11/15/19 05:31 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 05:31 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 05:31 56-23-5 22.5 ug/L 1.0 0.23 1 11/15/19 05:31 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 05:31 75-00-3 IK,v1 ND ug/L 5.0 2.3 1 11/15/19 05:31 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 05:31 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 05:31 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 05:31 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 05:31 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 05:31 74-95-3 2.2 ug/L 1.0 0.29 1 11/15/19 05:31 95-50-1 38.6 ug/L 1.0 0.26 1 11/15/19 05:31 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 05:31 110-57-6 L1 0.57J ug/L 1.0 0.27 1 11/15/19 05:31 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 05:31 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 05:31 75-35-4 0.33J ug/L 1.0 0.29 1 11/15/19 05:31 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 05:31 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 05:31 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW2 Lab ID: 92452518001 Collected: 11/05/19 09:06 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 ND ug/L 1.0 12.1 ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 11.2 ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 1.1 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 22.3 ug/L 1.0 95 % 70-130 109 % 70-130 101 % 70-130 Analytical Method: EPA 8260D Mod. 236 ug/L 10.0 106 % 50-150 105 % 50-150 0.30 1 11/15/19 05:31 10061-01-5 0.31 1 11/15/19 05:31 10061-02-6 0.26 1 11/15/19 05:31 100-41-4 0.57 1 11/15/19 05:31 591-78-6 12.5 1 11/15/19 05:31 74-88-4 3.7 1 11/15/19 05:31 75-09-2 4.5 1 11/15/19 05:31 108-10-1 0.27 1 11/15/19 05:31 100-42-5 0.34 1 11/15/19 05:31 630-20-6 0.22 1 11/15/19 05:31 79-34-5 0.16 1 11/15/19 05:31 127-18-4 0.24 1 11/15/19 05:31 108-88-3 0.18 1 11/15/19 05:31 71-55-6 0.24 1 11/15/19 05:31 79-00-5 0.22 1 11/15/19 05:31 79-01-6 0.31 1 11/15/19 05:31 75-69-4 0.35 1 11/15/19 05:31 96-18-4 1.4 1 11/15/19 05:31 108-05-4 0.24 1 11/15/19 05:31 75-01-4 0.63 1 11/15/19 05:31 1330-20-7 1 11/15/19 05:31 460-00-4 1 11/15/19 05:31 17060-07-0 1 11/15/19 05:31 2037-26-5 5.8 5 5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/10/19 00:55 123-91-1 11/10/19 00:55 17060-07-0 11/10/19 00:55 2037-26-5 Page 9 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW3S Lab ID: 92452518002 Collected: 11/05/19 07:30 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 14:00 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:00 7440-38-2 448 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:00 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 14:00 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 14:00 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:00 7440-47-3 12.3 ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 14:00 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 14:00 7440-50-8 2.OJ ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 14:00 7439-92-1 3.3J ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 14:00 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:00 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 14:00 7440-22-4 1.81 ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 14:00 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 14:00 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:30 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 05:50 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 05:50 107-13-1 3.4 ug/L 1.0 0.15 1 11/15/19 05:50 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 05:50 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 05:50 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 05:50 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 05:50 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 05:50 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 05:50 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 05:50 56-23-5 32.7 ug/L 1.0 0.23 1 11/15/19 05:50 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 05:50 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 05:50 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 05:50 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 05:50 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 05:50 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 05:50 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 05:50 74-95-3 0.60J ug/L 1.0 0.29 1 11/15/19 05:50 95-50-1 10.7 ug/L 1.0 0.26 1 11/15/19 05:50 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 05:50 110-57-6 0.43J ug/L 1.0 0.27 1 11/15/19 05:50 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 05:50 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 05:50 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 05:50 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 05:50 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 05:50 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 10 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW3S Lab ID: 92452518002 Collected: 11/05/19 07:30 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 05:50 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 05:50 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 05:50 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 05:50 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 05:50 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 05:50 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 05:50 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 05:50 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 05:50 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 05:50 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 05:50 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 05:50 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 05:50 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 05:50 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 05:50 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 05:50 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 05:50 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 05:50 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 05:50 75-01-4 14.3 ug/L 1.0 0.63 1 11/15/19 05:50 1330-20-7 94 % 70-130 1 11/15/19 05:50 460-00-4 109 % 70-130 1 11/15/19 05:50 17060-07-0 99 % 70-130 1 11/15/19 05:50 2037-26-5 Analytical Method: EPA 8260D Mod. 36.4 ug/L 2.0 1.2 1 11/09/19 22:57 123-91-1 104 % 50-150 1 11/09/19 22:57 17060-07-0 102 % 50-150 1 11/09/19 22:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW3D Lab ID: 92452518003 Collected: 11/05/19 11:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 14:03 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:03 7440-38-2 219 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:03 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 14:03 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 14:03 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:03 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 14:03 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 14:03 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 14:03 7439-92-1 28.7 ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 14:03 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:03 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 14:03 7440-22-4 ND ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 14:03 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 14:03 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.061J ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:38 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 06:08 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 06:08 107-13-1 1.3 ug/L 1.0 0.15 1 11/15/19 06:08 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 06:08 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 06:08 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 06:08 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 06:08 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 06:08 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 06:08 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 06:08 56-23-5 7.5 ug/L 1.0 0.23 1 11/15/19 06:08 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 06:08 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 06:08 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 06:08 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 06:08 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 06:08 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 06:08 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 06:08 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 06:08 95-50-1 4.2 ug/L 1.0 0.26 1 11/15/19 06:08 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 06:08 110-57-6 4.7 ug/L 1.0 0.27 1 11/15/19 06:08 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 06:08 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 06:08 75-35-4 14.6 ug/L 1.0 0.29 1 11/15/19 06:08 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 06:08 156-60-5 0.87J ug/L 1.0 0.19 1 11/15/19 06:08 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 12 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW3D Lab ID: 92452518003 Collected: 11/05/19 11:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 5.0 ND ug/L 20.0 ND ug/L 5.0 ND ug/L 5.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 6.5 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 4.8 ug/L 1.0 ND ug/L 1.0 ND ug/L 1.0 ND ug/L 2.0 ND ug/L 1.0 ND ug/L 1.0 94 % 70-130 107 % 70-130 100 % 70-130 Analytical Method: EPA 8260D Mod. 269 ug/L 10.0 100 % 50-150 108 % 50-150 0.30 1 11/15/19 06:08 10061-01-5 0.31 1 11/15/19 06:08 10061-02-6 0.26 1 11/15/19 06:08 100-41-4 0.57 1 11/15/19 06:08 591-78-6 12.5 1 11/15/19 06:08 74-88-4 3.7 1 11/15/19 06:08 75-09-2 4.5 1 11/15/19 06:08 108-10-1 0.27 1 11/15/19 06:08 100-42-5 0.34 1 11/15/19 06:08 630-20-6 0.22 1 11/15/19 06:08 79-34-5 0.16 1 11/15/19 06:08 127-18-4 0.24 1 11/15/19 06:08 108-88-3 0.18 1 11/15/19 06:08 71-55-6 0.24 1 11/15/19 06:08 79-00-5 0.22 1 11/15/19 06:08 79-01-6 0.31 1 11/15/19 06:08 75-69-4 0.35 1 11/15/19 06:08 96-18-4 1.4 1 11/15/19 06:08 108-05-4 0.24 1 11/15/19 06:08 75-01-4 0.63 1 11/15/19 06:08 1330-20-7 1 11/15/19 06:08 460-00-4 1 11/15/19 06:08 17060-07-0 1 11/15/19 06:08 2037-26-5 5.8 5 5 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 11/10/19 01:15 123-91-1 11/10/19 01:15 17060-07-0 11/10/19 01:15 2037-26-5 Page 13 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW4 Lab ID: 92452518004 Collected: 11/04/19 17:30 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 14:18 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:18 7440-38-2 130 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:18 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 14:18 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 14:18 7440-43-9 5.9 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:18 7440-47-3 1.6J ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 14:18 7440-48-4 4.6J ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 14:18 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 14:18 7439-92-1 2.4J ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 14:18 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:18 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 14:18 7440-22-4 10 ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 14:18 7440-62-2 15.4 ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 14:18 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.060J ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:46 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 02:45 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 02:45 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 02:45 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 02:45 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 02:45 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 02:45 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 02:45 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 02:45 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 02:45 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 02:45 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 02:45 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 02:45 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 02:45 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 02:45 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 02:45 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 02:45 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 02:45 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 02:45 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 02:45 95-50-1 0.48J ug/L 1.0 0.26 1 11/15/19 02:45 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 02:45 110-57-6 1.5 ug/L 1.0 0.27 1 11/15/19 02:45 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 02:45 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 02:45 75-35-4 8.0 ug/L 1.0 0.29 1 11/15/19 02:45 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 02:45 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 02:45 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 14 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW4 Lab ID: 92452518004 Collected: 11/04/19 17:30 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 02:45 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 02:45 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 02:45 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 02:45 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 02:45 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 02:45 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 02:45 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 02:45 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 02:45 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 02:45 79-34-5 1.8 ug/L 1.0 0.16 1 11/15/19 02:45 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 02:45 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 02:45 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 02:45 79-00-5 0.72J ug/L 1.0 0.22 1 11/15/19 02:45 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 02:45 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 02:45 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 02:45 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 02:45 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 02:45 1330-20-7 93 % 70-130 1 11/15/19 02:45 460-00-4 105 % 70-130 1 11/15/19 02:45 17060-07-0 99 % 70-130 1 11/15/19 02:45 2037-26-5 Analytical Method: EPA 8260D Mod. 2.7 ug/L 2.0 1.2 1 11/09/19 23:17 123-91-1 99 % 50-150 1 11/09/19 23:17 17060-07-0 110 % 50-150 1 11/09/19 23:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW5 Lab ID: 92452518005 Collected: 11/04/19 17:17 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 14:21 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:21 7440-38-2 46.5 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:21 7440-39-3 0.23J ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 14:21 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 14:21 7440-43-9 1.81 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 14:21 7440-47-3 1.3J ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 14:21 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 14:21 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 14:21 7439-92-1 1.0J ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 14:21 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 14:21 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 14:21 7440-22-4 3.8J ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 14:21 7440-62-2 7.5J ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 14:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.16 ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 03:04 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 03:04 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 03:04 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 03:04 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 03:04 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 03:04 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 03:04 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 03:04 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 03:04 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 03:04 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 03:04 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 03:04 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 03:04 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 03:04 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 03:04 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 03:04 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 03:04 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 03:04 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 03:04 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 03:04 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 03:04 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 03:04 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 03:04 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 03:04 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 03:04 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 03:04 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 03:04 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 16 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW5 Lab ID: 92452518005 Collected: 11/04/19 17:17 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 03:04 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 03:04 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 03:04 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 03:04 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 03:04 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 03:04 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 03:04 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 03:04 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 03:04 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 03:04 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 03:04 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 03:04 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 03:04 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 03:04 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 03:04 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 03:04 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 03:04 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 03:04 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 03:04 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 03:04 1330-20-7 94 % 70-130 1 11/15/19 03:04 460-00-4 108 % 70-130 1 11/15/19 03:04 17060-07-0 99 % 70-130 1 11/15/19 03:04 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/09/19 23:36 123-91-1 95 % 50-150 1 11/09/19 23:36 17060-07-0 107 % 50-150 1 11/09/19 23:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW6S Lab ID: 92452518006 Collected: 11/04/19 17:00 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 22:28 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:28 7440-38-2 35.6 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:28 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 22:28 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 22:28 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:28 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 22:28 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 22:28 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 22:28 7439-92-1 ND ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 22:28 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:28 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 22:28 7440-22-4 ND ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 22:28 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 22:28 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 02:58 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 03:22 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 03:22 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 03:22 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 03:22 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 03:22 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 03:22 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 03:22 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 03:22 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 03:22 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 03:22 56-23-5 0.28J ug/L 1.0 0.23 1 11/15/19 03:22 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 03:22 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 03:22 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 03:22 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 03:22 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 03:22 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 03:22 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 03:22 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 03:22 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 03:22 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 03:22 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 03:22 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 03:22 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 03:22 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 03:22 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 03:22 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 03:22 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 18 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW6S Lab ID: 92452518006 Collected: 11/04/19 17:00 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 03:22 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 03:22 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 03:22 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 03:22 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 03:22 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 03:22 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 03:22 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 03:22 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 03:22 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 03:22 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 03:22 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 03:22 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 03:22 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 03:22 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 03:22 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 03:22 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 03:22 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 03:22 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 03:22 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 03:22 1330-20-7 93 % 70-130 1 11/15/19 03:22 460-00-4 107 % 70-130 1 11/15/19 03:22 17060-07-0 100 % 70-130 1 11/15/19 03:22 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/10/1916:48 123-91-1 96 % 50-150 1 11/10/1916:48 17060-07-0 104 % 50-150 1 11/10/1916:48 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW6D Lab ID: 92452518007 Collected: 11/04/19 17:10 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:27 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 22:40 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:40 7440-38-2 17.0 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:40 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 22:40 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 22:40 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:40 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 22:40 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 22:40 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 22:40 7439-92-1 ND ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 22:40 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:40 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 22:40 7440-22-4 ND ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 22:40 7440-62-2 7.OJ ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 22:40 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 03:11 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 03:40 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 03:40 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 03:40 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 03:40 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 03:40 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 03:40 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 03:40 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 03:40 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 03:40 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 03:40 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 03:40 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 03:40 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 03:40 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 03:40 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 03:40 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 03:40 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 03:40 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 03:40 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 03:40 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 03:40 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 03:40 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 03:40 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 03:40 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 03:40 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 03:40 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 03:40 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 03:40 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 20 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-MW6D Lab ID: 92452518007 Collected: 11/04/19 17:10 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 03:40 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 03:40 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 03:40 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 03:40 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 03:40 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 03:40 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 03:40 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 03:40 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 03:40 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 03:40 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 03:40 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 03:40 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 03:40 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 03:40 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 03:40 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 03:40 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 03:40 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 03:40 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 03:40 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 03:40 1330-20-7 94 % 70-130 1 11/15/19 03:40 460-00-4 110 % 70-130 1 11/15/19 03:40 17060-07-0 101 % 70-130 1 11/15/19 03:40 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/10/1917:08 123-91-1 96 % 50-150 1 11/10/1917:08 17060-07-0 109 % 50-150 1 11/10/1917:08 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW1 Lab ID: 92452518008 Collected: 11/05/19 08:50 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Date: 11/18/2019 06:27 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 22:43 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:43 7440-38-2 34.5 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:43 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 22:43 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 22:43 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:43 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 22:43 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 22:43 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 22:43 7439-92-1 ND ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 22:43 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:43 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 22:43 7440-22-4 28300 ug/L 662 131 1 11/12/19 01:24 11/15/19 22:43 1.4J ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 22:43 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 22:43 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 03:15 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 06:27 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 06:27 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 06:27 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 06:27 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 06:27 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 06:27 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 06:27 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 06:27 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 06:27 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 06:27 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 06:27 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 06:27 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 06:27 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 06:27 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 06:27 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 06:27 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 06:27 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 06:27 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 06:27 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 06:27 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 06:27 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 06:27 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 06:27 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 06:27 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 06:27 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 06:27 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 22 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW1 Lab ID: 92452518008 Collected: 11/05/19 08:50 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.19 1 11/15/19 06:27 78-87-5 ND ug/L 1.0 0.30 1 11/15/19 06:27 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 06:27 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 06:27 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 06:27 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 06:27 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 06:27 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 06:27 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 06:27 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 06:27 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 06:27 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 06:27 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 06:27 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 06:27 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 06:27 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 06:27 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 06:27 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 06:27 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 06:27 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 06:27 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 06:27 1330-20-7 93 % 70-130 1 11/15/19 06:27 460-00-4 110 % 70-130 1 11/15/19 06:27 17060-07-0 100 % 70-130 1 11/15/19 06:27 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/10/1917:28 123-91-1 94 % 50-150 1 11/10/1917:28 17060-07-0 107 % 50-150 1 11/10/1917:28 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW2 Lab ID: 92452518009 Collected: 11/05/19 08:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Date: 11/18/2019 06:27 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 22:46 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:46 7440-38-2 35.9 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:46 7440-39-3 0.24J ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 22:46 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 22:46 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:46 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 22:46 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 22:46 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 22:46 7439-92-1 ND ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 22:46 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:46 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 22:46 7440-22-4 29100 ug/L 662 131 1 11/12/19 01:24 11/15/19 22:46 1.5J ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 22:46 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 22:46 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 03:19 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 06:45 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 06:45 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 06:45 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 06:45 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 06:45 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 06:45 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 06:45 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 06:45 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 06:45 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 06:45 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 06:45 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 06:45 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 06:45 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 06:45 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 06:45 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 06:45 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 06:45 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 06:45 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 06:45 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 06:45 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 06:45 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 06:45 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 06:45 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 06:45 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 06:45 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 06:45 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 24 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW2 Lab ID: 92452518009 Collected: 11/05/19 08:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.19 1 11/15/19 06:45 78-87-5 ND ug/L 1.0 0.30 1 11/15/19 06:45 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 06:45 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 06:45 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 06:45 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 06:45 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 06:45 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 06:45 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 06:45 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 06:45 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 06:45 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 06:45 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 06:45 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 06:45 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 06:45 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 06:45 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 06:45 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 06:45 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 06:45 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 06:45 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 06:45 1330-20-7 94 % 70-130 1 11/15/19 06:45 460-00-4 108 % 70-130 1 11/15/19 06:45 17060-07-0 101 % 70-130 1 11/15/19 06:45 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/10/1917:47 123-91-1 96 % 50-150 1 11/10/1917:47 17060-07-0 104 % 50-150 1 11/10/1917:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW3 Lab ID: 92452518010 Collected: 11/05/19 08:08 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene Date: 11/18/2019 06:27 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.0 1 11/12/19 01:24 11/15/19 22:56 7440-36-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:56 7440-38-2 34.8 ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:56 7440-39-3 ND ug/L 1.0 0.20 1 11/12/19 01:24 11/15/19 22:56 7440-41-7 ND ug/L 1.0 0.40 1 11/12/19 01:24 11/15/19 22:56 7440-43-9 ND ug/L 5.0 1.0 1 11/12/19 01:24 11/15/19 22:56 7440-47-3 ND ug/L 5.0 1.1 1 11/12/19 01:24 11/15/19 22:56 7440-48-4 ND ug/L 5.0 2.1 1 11/12/19 01:24 11/15/19 22:56 7440-50-8 ND ug/L 5.0 1.6 1 11/12/19 01:24 11/15/19 22:56 7439-92-1 ND ug/L 5.0 0.90 1 11/12/19 01:24 11/15/19 22:56 7440-02-0 ND ug/L 10.0 4.7 1 11/12/19 01:24 11/15/19 22:56 7782-49-2 ND ug/L 5.0 2.5 1 11/12/19 01:24 11/15/19 22:56 7440-22-4 28500 ug/L 662 131 1 11/12/19 01:24 11/15/19 22:56 1.5J ug/L 5.0 1.3 1 11/12/19 01:24 11/15/19 22:56 7440-62-2 ND ug/L 10.0 3.9 1 11/12/19 01:24 11/15/19 22:56 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 03:23 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 07:04 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 07:04 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 07:04 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 07:04 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 07:04 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 07:04 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 07:04 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 07:04 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 07:04 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 07:04 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 07:04 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 07:04 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 07:04 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 07:04 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 07:04 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 07:04 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 07:04 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 07:04 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 07:04 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 07:04 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 07:04 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 07:04 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 07:04 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 07:04 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 07:04 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 07:04 156-60-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. IK IK,v1 L1 Page 26 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 Sample: 1201-SW3 Lab ID: 92452518010 Collected: 11/05/19 08:08 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:27 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.19 1 11/15/19 07:04 78-87-5 ND ug/L 1.0 0.30 1 11/15/19 07:04 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 07:04 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 07:04 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 07:04 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 07:04 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 07:04 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 07:04 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 07:04 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 07:04 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 07:04 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 07:04 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 07:04 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 07:04 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 07:04 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 07:04 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 07:04 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 07:04 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 07:04 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 07:04 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 07:04 1330-20-7 92 % 70-130 1 11/15/19 07:04 460-00-4 107 % 70-130 1 11/15/19 07:04 17060-07-0 101 % 70-130 1 11/15/19 07:04 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/10/1918:07 123-91-1 86 % 50-150 1 11/10/1918:07 17060-07-0 108 % 50-150 1 11/10/1918:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 508902 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005 METHOD BLANK: 2731583 Matrix: Water Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005 Blank Reporting Parameter Units Result Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 11/15/1913:23 Arsenic ug/L ND 10.0 4.7 11/15/1913:23 Barium ug/L ND 5.0 1.0 11/15/1913:23 Beryllium ug/L ND 1.0 0.20 11/15/1913:23 Cadmium ug/L ND 1.0 0.40 11/15/1913:23 Chromium ug/L ND 5.0 1.0 11/15/1913:23 Cobalt ug/L ND 5.0 1.1 11/15/1913:23 Copper ug/L ND 5.0 2.1 11/15/1913:23 Lead ug/L ND 5.0 1.6 11/15/1913:23 Nickel ug/L ND 5.0 0.90 11/15/1913:23 Selenium ug/L ND 10.0 4.7 11/15/1913:23 Silver ug/L ND 5.0 2.5 11/15/1913:23 Vanadium ug/L ND 5.0 1.3 11/15/1913:23 Zinc ug/L ND 10.0 3.9 11/15/1913:23 LABORATORY CONTROL SAMPLE: Parameter 2731584 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 509 102 80-120 Arsenic ug/L 500 495 99 80-120 Barium ug/L 500 515 103 80-120 Beryllium ug/L 500 508 102 80-120 Cadmium ug/L 500 507 101 80-120 Chromium ug/L 500 497 99 80-120 Cobalt ug/L 500 504 101 80-120 Copper ug/L 500 512 102 80-120 Lead ug/L 500 496 99 80-120 Nickel ug/L 500 498 100 80-120 Selenium ug/L 500 498 100 80-120 Silver ug/L 250 251 100 80-120 Vanadium ug/L 500 508 102 80-120 Zinc ug/L 500 486 97 80-120 l•r_�r:�►�y�l:��:�tr_�r:�►�y�r��.m���y�r��K�Nf:�. �K�Nfiy Qualifiers Qualifiers MS MSD 92452494001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 534 529 106 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Burke Co.-Kirksey Dr Closed LF 92452518 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2731585 2731586 MS MSD 92452494001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 515 518 103 104 75-125 1 20 Barium ug/L 38.6 500 500 552 560 103 104 75-125 1 20 Beryllium ug/L ND 500 500 514 518 103 103 75-125 1 20 Cadmium ug/L ND 500 500 522 521 104 104 75-125 0 20 Chromium ug/L ND 500 500 502 500 100 99 75-125 0 20 Cobalt ug/L ND 500 500 496 497 99 99 75-125 0 20 Copper ug/L 42.2 500 500 567 568 105 105 75-125 0 20 Lead ug/L ND 500 500 492 494 98 98 75-125 0 20 Nickel ug/L ND 500 500 493 494 98 98 75-125 0 20 Selenium ug/L ND 500 500 530 531 106 106 75-125 0 20 Silver ug/L ND 250 250 265 265 106 106 75-125 0 20 Vanadium ug/L ND 500 500 518 517 103 103 75-125 0 20 Zinc ug/L 135 500 500 621 628 97 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 508903 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92452518006, 92452518007, 92452518008, 92452518009, 92452518010 METHOD BLANK: 2731587 Matrix: Water Associated Lab Samples: 92452518006, 92452518007, 92452518008, 92452518009, 92452518010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.0 11/15/19 22:21 Arsenic ug/L ND 10.0 4.7 11/15/19 22:21 Barium ug/L ND 5.0 1.0 11/15/19 22:21 Beryllium ug/L ND 1.0 0.20 11/15/19 22:21 Cadmium ug/L ND 1.0 0.40 11/15/19 22:21 Chromium ug/L ND 5.0 1.0 11/15/19 22:21 Cobalt ug/L ND 5.0 1.1 11/15/19 22:21 Copper ug/L ND 5.0 2.1 11/15/19 22:21 Hardness, Total(SM 2340B) ug/L ND 662 131 11/15/19 22:21 Lead ug/L ND 5.0 1.6 11/15/19 22:21 Nickel ug/L ND 5.0 0.90 11/15/19 22:21 Selenium ug/L ND 10.0 4.7 11/15/19 22:21 Silver ug/L ND 5.0 2.5 11/15/19 22:21 Vanadium ug/L ND 5.0 1.3 11/15/19 22:21 Zinc ug/L ND 10.0 3.9 11/15/19 22:21 LABORATORY CONTROL SAMPLE: 2731588 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 471 94 80-120 Arsenic ug/L 500 460 92 80-120 Barium ug/L 500 498 100 80-120 Beryllium ug/L 500 506 101 80-120 Cadmium ug/L 500 482 96 80-120 Chromium ug/L 500 490 98 80-120 Cobalt ug/L 500 477 95 80-120 Copper ug/L 500 488 98 80-120 Hardness, Total(SM 2340B) ug/L 33100 32700 99 80-120 Lead ug/L 500 474 95 80-120 Nickel ug/L 500 477 95 80-120 Selenium ug/L 500 469 94 80-120 Silver ug/L 250 245 98 80-120 Vanadium ug/L 500 488 98 80-120 Zinc ug/L 500 467 93 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2731589 2731590 MS MSD 92452518006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 497 479 99 96 75-125 4 20 Arsenic ug/L ND 500 500 479 458 96 92 75-125 4 20 Barium ug/L 35.6 500 500 543 534 102 100 75-125 2 20 Beryllium ug/L ND 500 500 516 504 103 101 75-125 2 20 Cadmium ug/L ND 500 500 498 483 100 97 75-125 3 20 Chromium ug/L ND 500 500 506 490 101 98 75-125 3 20 Cobalt ug/L ND 500 500 485 467 97 93 75-125 4 20 Copper ug/L ND 500 500 498 480 99 96 75-125 3 20 Hardness, Total(SM 2340B) ug/L 19000 33100 33100 53700 52900 105 103 75-125 1 Lead ug/L ND 500 500 480 464 96 93 75-125 3 20 Nickel ug/L ND 500 500 486 470 97 94 75-125 3 20 Selenium ug/L ND 500 500 505 495 101 99 75-125 2 20 Silver ug/L ND 250 250 260 253 104 101 75-125 3 20 Vanadium ug/L ND 500 500 499 480 100 96 75-125 4 20 Zinc ug/L ND 500 500 483 465 96 93 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 508408 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005, 92452518006, 92452518007, 92452518008,92452518009,92452518010 METHOD BLANK: 2729091 Matrix: Water Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005, 92452518006, 92452518007, 92452518008,92452518009,92452518010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 11/08/1915:54 LABORATORY CONTROL SAMPLE: 2729092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.1 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2729093 2729094 MS MSD 92452442014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.1 10.1 100 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 509649 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005, 92452518006, 92452518007, 92452518008,92452518009,92452518010 METHOD BLANK: 2735246 Matrix: Water Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005, 92452518006, 92452518007, 92452518008,92452518009,92452518010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 11/15/19 00:55 1,1,1-Trichloroethane ug/L ND 1.0 0.18 11/15/19 00:55 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/15/19 00:55 1,1,2-Trichloroethane ug/L ND 1.0 0.24 11/15/19 00:55 1,1-Dichloroethane ug/L ND 1.0 0.27 11/15/19 00:55 1,1-Dichloroethene ug/L ND 1.0 0.24 11/15/19 00:55 1,2,3-Trichloropropane ug/L ND 1.0 0.35 11/15/19 00:55 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 11/15/19 00:55 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 11/15/19 00:55 1,2-Dichlorobenzene ug/L ND 1.0 0.29 11/15/19 00:55 1,2-Dichloroethane ug/L ND 1.0 0.34 11/15/19 00:55 1,2-Dichloropropane ug/L ND 1.0 0.19 11/15/19 00:55 1,4-Dichlorobenzene ug/L ND 1.0 0.26 11/15/19 00:55 2-Butanone (MEK) ug/L ND 5.0 3.3 11/15/19 00:55 2-Hexanone ug/L ND 5.0 0.57 11/15/19 00:55 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 11/15/19 00:55 Acetone ug/L ND 25.0 6.2 11/15/19 00:55 Acrylonitrile ug/L ND 10.0 0.90 11/15/19 00:55 Benzene ug/L ND 1.0 0.15 11/15/19 00:55 Bromochloromethane ug/L ND 1.0 0.34 11/15/19 00:55 Bromodichloromethane ug/L ND 1.0 0.26 11/15/19 00:55 Bromoform ug/L ND 1.0 0.62 11/15/19 00:55 Bromomethane ug/L ND 2.0 0.62 11/15/19 00:55 Carbon disulfide ug/L ND 2.0 0.40 11/15/19 00:55 Carbon tetrachloride ug/L ND 1.0 0.22 11/15/19 00:55 Chlorobenzene ug/L ND 1.0 0.23 11/15/19 00:55 Chloroethane ug/L ND 1.0 0.49 11/15/19 00:55 Chloroform ug/L ND 5.0 2.3 11/15/19 00:55 Chloromethane ug/L ND 1.0 0.39 11/15/19 00:55 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 11/15/19 00:55 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 11/15/19 00:55 Dibromochloromethane ug/L ND 1.0 0.41 11/15/19 00:55 Dibromomethane ug/L ND 1.0 0.46 11/15/19 00:55 Ethylbenzene ug/L ND 1.0 0.26 11/15/19 00:55 lodomethane ug/L ND 20.0 12.5 11/15/19 00:55 Methylene Chloride ug/L ND 5.0 3.7 11/15/19 00:55 Styrene ug/L ND 1.0 0.27 11/15/19 00:55 Tetrachloroethene ug/L ND 1.0 0.16 11/15/19 00:55 Toluene ug/L ND 1.0 0.24 11/15/19 00:55 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 11/15/19 00:55 L IK,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 METHOD BLANK: 2735246 Matrix: Water Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005, 92452518006, 92452518007, 92452518008,92452518009,92452518010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 11/15/19 00:55 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 11/15/19 00:55 Trichloroethene ug/L ND 1.0 0.22 11/15/19 00:55 Trichlorofluoromethane ug/L ND 1.0 0.31 11/15/19 00:55 Vinyl acetate ug/L ND 2.0 1.4 11/15/19 00:55 Vinyl chloride ug/L ND 1.0 0.24 11/15/19 00:55 Xylene (Total) ug/L ND 1.0 0.63 11/15/19 00:55 1,2-Dichloroethane-d4 (S) % 106 70-130 11/15/19 00:55 4-Bromofluorobenzene (S) % 93 70-130 11/15/19 00:55 Toluene-d8 (S) % 99 70-130 11/15/19 00:55 LABORATORY CONTROL SAMPLE: 2735247 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.5 103 70-130 1,1,1-Trichloroethane ug/L 50 53.7 107 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.2 104 70-130 1,1,2-Trichloroethane ug/L 50 54.4 109 70-130 1,1-Dichloroethane ug/L 50 52.9 106 70-130 1,1-Dichloroethene ug/L 50 53.6 107 70-130 1,2,3-Trichloropropane ug/L 50 54.6 109 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.5 107 70-130 1,2-Dibromoethane (EDB) ug/L 50 53.9 108 70-130 1,2-Dichlorobenzene ug/L 50 52.3 105 70-130 1,2-Dichloroethane ug/L 50 49.7 99 70-130 1,2-Dichloropropane ug/L 50 54.1 108 70-130 1,4-Dichlorobenzene ug/L 50 52.4 105 70-130 2-Butanone (MEK) ug/L 100 105 105 64-135 2-Hexanone ug/L 100 109 109 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 106 106 70-130 Acetone ug/L 100 124 124 61-157 Acrylonitrile ug/L 250 257 103 61-143 Benzene ug/L 50 52.1 104 70-130 Bromochloromethane ug/L 50 53.3 107 70-130 Bromodichloromethane ug/L 50 54.1 108 70-130 Bromoform ug/L 50 53.6 107 70-130 Bromomethane ug/L 50 57.9 116 38-130 IK Carbon disulfide ug/L 50 55.1 110 68-130 Carbon tetrachloride ug/L 50 53.0 106 70-130 Chlorobenzene ug/L 50 51.1 102 70-130 Chloroethane ug/L 50 36.5 73 37-142 IK,v1 Chloroform ug/L 50 54.4 109 70-130 Chloromethane ug/L 50 46.5 93 48-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 LABORATORY CONTROL SAMPLE: Parameter 2735247 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 51.9 104 70-130 cis-1,3-Dichloropropene ug/L 50 56.6 113 70-130 Dibromochloromethane ug/L 50 51.7 103 70-130 Dibromomethane ug/L 50 51.8 104 70-130 Ethylbenzene ug/L 50 51.9 104 70-130 lodomethane ug/L 100 99.7 100 40-130 Methylene Chloride ug/L 50 49.8 100 67-132 Styrene ug/L 50 54.2 108 70-130 Tetrachloroethene ug/L 50 50.4 101 69-130 Toluene ug/L 50 51.9 104 70-130 trans-1,2-Dichloroethene ug/L 50 54.6 109 70-130 trans- 1,3-Dichloropropene ug/L 50 56.2 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 111 222 35-189 L1 Trichloroethene ug/L 50 51.7 103 70-130 Trichlorofluoromethane ug/L 50 52.5 105 63-130 Vinyl acetate ug/L 100 115 115 55-143 Vinyl chloride ug/L 50 54.9 110 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 103 70-130 MATRIX SPIKE SAMPLE: Parameter 2735249 Units 92452862004 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.7 109 73-134 1,1,1-Trichloroethane ug/L ND 20 22.1 110 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.5 102 70-136 1,1,2-Trichloroethane ug/L ND 20 19.7 99 70-135 1,1-Dichloroethane ug/L ND 20 22.2 111 70-139 1,1-Dichloroethene ug/L ND 20 22.5 112 70-154 1,2,3-Trichloropropane ug/L ND 20 21.5 107 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 22.2 111 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.5 108 70-137 1,2-Dichlorobenzene ug/L ND 20 21.3 107 70-133 1,2-Dichloroethane ug/L ND 20 19.0 95 70-137 1,2-Dichloropropane ug/L ND 20 20.3 101 70-140 1,4-Dichlorobenzene ug/L ND 20 21.4 107 70-133 2-Butanone (MEK) ug/L ND 40 41.8 101 60-139 2-Hexanone ug/L ND 40 41.3 103 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 38.0 95 65-135 Acetone ug/L 11 AJ 40 45.5 85 60-148 Acrylonitrile ug/L ND 100 100 100 64-147 Benzene ug/L ND 20 20.6 103 70-151 Bromochloromethane ug/L ND 20 21.7 109 70-141 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 MATRIX SPIKE SAMPLE: 2735249 92452862004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromodichloromethane ug/L ND 20 20.0 100 70-138 Bromoform ug/L ND 20 21.1 106 63-130 Bromomethane ug/L ND 20 27.9 140 15-152 IK,v3 Carbon disulfide ug/L ND 20 23.5 117 69-149 Carbon tetrachloride ug/L ND 20 22.9 115 70-143 Chlorobenzene ug/L ND 20 20.9 105 70-138 Chloroethane ug/L ND 20 19.8 99 52-163 Chloroform ug/L ND 20 21.5 107 70-139 Chloromethane ug/L ND 20 20.0 100 41-139 cis-1,2-Dichloroethene ug/L 0.98J 20 22.8 109 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.6 103 70-137 Dibromochloromethane ug/L ND 20 21.4 107 70-134 Dibromomethane ug/L ND 20 19.7 98 70-138 Ethylbenzene ug/L ND 20 21.6 108 66-153 Iodomethane ug/L ND 40 43.6 109 20-1381K,v1 Methylene Chloride ug/L ND 20 20.7 103 42-159 Styrene ug/L ND 20 21.8 109 70-135 Tetrachloroethene ug/L ND 20 22.0 110 59-143 Toluene ug/L ND 20 19.5 98 59-148 trans-1,2-Dichloroethene ug/L ND 20 21.9 109 70-146 trans- 1,3-Dichloropropene ug/L ND 20 20.2 101 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 22.8 114 47-135 Trichloroethene ug/L ND 20 20.5 103 70-147 Trichlorofluoromethane ug/L ND 20 20.9 105 70-148 Vinyl acetate ug/L ND 40 40.1 100 49-151 Vinyl chloride ug/L ND 20 23.8 119 70-156 Xylene (Total) ug/L ND 60 65.2 109 63-158 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 96 70-130 SAMPLE DUPLICATE: 2735248 92452518010 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 SAMPLE DUPLICATE: 2735248 Parameter Units 92452518010 Result 1,2-Dichloropropane ug/L ND 1,4-Dichlorobenzene ug/L ND 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 107 4-Bromofluorobenzene (S) % 92 Toluene-d8 (S) % 101 Dup Result RPD Max RPD Qualifiers ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 IK ND 30 ND 30 ND 30 ND 30 IK,v1 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 109 94 98 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 508650 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005 METHOD BLANK: 2730482 Matrix: Water Associated Lab Samples: 92452518001, 92452518002, 92452518003, 92452518004, 92452518005 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 11/09/19 17:03 1,2-Dichloroethane-d4 (S) % 91 50-150 11/09/19 17:03 Toluene-d8 (S) % 102 50-150 11/09/19 17:03 LABORATORY CONTROL SAMPLE: 2730483 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.5 97 70-130 1,2-Dichloroethane-d4 (S) % 93 50-150 Toluene-d8(S) % 102 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2730484 2730485 MS MSD 92452518005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 20.2 19.0 99 93 50-150 6 30 1,2-Dichloroethane-d4 (S) % 104 99 50-150 30 Toluene-d8 (S) % 108 106 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 QC Batch: 508679 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92452518006, 92452518007, 92452518008, 92452518009, 92452518010 METHOD BLANK: 2730564 Matrix: Water Associated Lab Samples: 92452518006, 92452518007, 92452518008, 92452518009, 92452518010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 11/10/19 16:08 1,2-Dichloroethane-d4 (S) % 96 50-150 11/10/19 16:08 Toluene-d8 (S) % 106 50-150 11/10/19 16:08 LABORATORY CONTROL SAMPLE: 2730565 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.3 96 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 104 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2730566 2730567 MS MSD 92452936006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.2 18.8 94 92 50-150 2 30 1,2-Dichloroethane-d4 (S) % 99 104 50-150 30 Toluene-d8 (S) % 109 108 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co.-Kirksey Dr Closed LF Pace Project No.: 92452518 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:27 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 44 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Burke Co.-Kirksey Dr Closed LF 92452518 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92452518001 1201-MW2 EPA 3010A 508902 EPA 6010D 508914 92452518002 1201-MW3S EPA 3010A 508902 EPA 6010D 508914 92452518003 1201-MW3D EPA 3010A 508902 EPA 6010D 508914 92452518004 1201-MW4 EPA 3010A 508902 EPA 6010D 508914 92452518005 1201-MW5 EPA 3010A 508902 EPA 6010D 508914 92452518006 1201-MW6S EPA 3010A 508903 EPA 6010D 508915 92452518007 1201-MW6D EPA 3010A 508903 EPA 6010D 508915 92452518008 1201-SW1 EPA 3010A 508903 EPA6010D 508915 92452518009 1201-SW2 EPA 3010A 508903 EPA 6010D 508915 92452518010 1201-SW3 EPA 3010A 508903 EPA 6010D 508915 92452518001 1201-MW2 EPA 3010A 508408 EPA 6020B 508443 92452518002 1201-MW3S EPA 3010A 508408 EPA 6020B 508443 92452518003 1201-MW3D EPA 3010A 508408 EPA 6020B 508443 92452518004 1201-MW4 EPA 3010A 508408 EPA 6020B 508443 92452518005 1201-MW5 EPA 3010A 508408 EPA 6020B 508443 92452518006 1201-MW6S EPA 3010A 508408 EPA 6020B 508443 92452518007 1201-MW6D EPA 3010A 508408 EPA 6020B 508443 92452518008 1201-SW1 EPA 3010A 508408 EPA 6020B 508443 92452518009 1201-SW2 EPA 3010A 508408 EPA 6020B 508443 92452518010 1201-SW3 EPA 3010A 508408 EPA 6020B 508443 92452518001 1201-MW2 EPA 8260D 509649 92452518002 1201-MW3S EPA 8260D 509649 92452518003 1201-MW3D EPA 8260D 509649 92452518004 1201-MW4 EPA 8260D 509649 92452518005 1201-MW5 EPA 8260D 509649 92452518006 1201-MW6S EPA 8260D 509649 92452518007 1201-MW6D EPA 8260D 509649 92452518008 1201-SW1 EPA 8260D 509649 92452518009 1201-SW2 EPA 8260D 509649 92452518010 1201-SW3 EPA 8260D 509649 92452518001 1201-MW2 EPA 8260D Mod. 508650 92452518002 1201-MW3S EPA 8260D Mod. 508650 92452518003 1201-MW3D EPA 8260D Mod. 508650 92452518004 1201-MW4 EPA 8260D Mod. 508650 92452518005 1201-MW5 EPA 8260D Mod. 508650 92452518006 1201-MW6S EPA 8260D Mod. 508679 92452518007 1201-MW6D EPA 8260D Mod. 508679 92452518008 1201-SW1 EPA 8260D Mod. 508679 92452518009 1201-SW2 EPA 8260D Mod. 508679 92452518010 1201-SW3 EPA 8260D Mod. 508679 Date: 11/18/2019 06:27 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 44 Document Name: Document Revised: February 7, 2018 mple Condition Upon Receipt(SCUR) Sample Page 1 of 2 Document No.: Issuing Authority: J ,,PaceAnalWal F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville K Eden[] Greenwood ❑ Huntersville ❑ italeigh❑ Mechanicsville❑ Sample, .. Client Name: WQ# : 92452518 Upon Receipt Project #: e Courier: XFed Ex❑UPS_ ❑uses r ❑Client II Ill III I II I I II II I III ❑ Commercial ❑Pace ❑Other: 82452518 Custody Seal Present? ❑Yes JMNo seals Intact? ❑Yes P�]No Date/Initials Person Examining Contents: 17A Packing Material: ❑Bubble Wrap Wtubble Bags []None ❑ Other Biological Tissue Frozen? ❑Yes ❑No ,JN/A Thermometer: %��_' Type of Ice: [Wet ❑Blue []NoneMIR Gun lD: �- 11 Cooler Temp (°C):/ j , , Correction Factor: Add/Subtract (°C) Temp should be above freezing to VC Cooler Temp Corrected (°C): r ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Sail (;0 N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, ❑Yes X]No including Hawaii and Puerto IUCO) r LJYes ivo Com meets/Di scre pan cy: Chain of Custody Present? Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? MYes ❑No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? [-]Yes J@No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes ZINo ❑N/A 4. Sufficient Volume? Correct Containers Used? -Pace Containers Used? MYEs JXYes jS@Yes .[]No ❑No [:]No ❑N/A ❑N/A ❑N/A 5. 6. Containers Intact? ®Yes ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ®N/A S. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: kes ❑No El N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes ZNo El N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? [-]Yes ❑Yes PJNa RNo ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY CLIENT NOTIFICATION/RESOLUTION Person contacted: Project Manager SCURF Review: WV; Project Manager SRF Review: Date/Time: Lot ID of split containers: Date: Date: Field Data Required? ❑Yes ❑NO Page 42 of 44 += Document Name: Document Revised: February 7, 2018 -PkeblalytlCal Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/5015 (water) {HOC, LLHg **Bottom half of box is to list number of bottle Project # Wp# : 92452518 PM: NMG Due Date: 11/20/19 CLIENT: 92-Joyce Eng E W _ u ._- Z w a C U m a E to a d m z i m n C a ..' E o N 6 a m } v a. C V m a J E a N M m _ Q > v a' fl. d `m +� r4 tL m —_ v a Q N m a E In rN-I V' a m 'y v a m U @ a J E P N m M m n f0 '� a u o a E :n N a 0. m `" A a 2 d Z m a E to N a co 2 ° m Q) d L o f �" a ¢ TJ 2 d Q C1 £ Q a _ �. O .�[ l7 4 v q V = y a E Q m - r-I S r1 C') Q U z m °' m [7. C y .{1 E ¢ E N 7 M 17 Q N v O N a1 it Q = r{ to t-S l7 Q v r n O ry E ¢ O N A M O G u Z U a z E ¢ J E a N l7 Q M 0 4 ¢ Z V 2 ¢ O > a Q 5 01 0 ❑ z -" �`' n VNl m Z Q O > Q F 6t i7 > ¢ Z Q � 4 0 > E o C 7 T Q > ¢ z 0 m 4 O > E o of = M 0 0 Y to m O tit y a N �9 } l0 Y a O 7 S CL a ° } X Q > Z +�-. t9 a E to vN-I � U1 a h z @ d v v iri J E O N N c u a T Z u m a J E O N M a. ra 7 v `:L C M E ¢ E o C C7 ¢ N C O c U7 E O l7 en > Z y d C E a 0 am W d 1 2 3 4 5 6 7 N\\4 I 8 \M\\ 9 NN 6� 10 11 12 i pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent tothe North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 43 of 44 / . raceMalytica! CHAIN -OF -CUSTODY / Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page: 1 Of 1 Company: LaBella Associates Report TO: Van Burbach Attention: Lecia Jones Address: 2211 West Meadowview Rd Copy To Gretta Eller Company Name: LaBella Associates Greensboro, NC 27407 Address, 1604 Ownby Lane, Richmond. VA 2322 Regulatory Agency Finail To vburbach labella C.com Purchase Order No. Pace Quote Reference: Phone, 336 323-0092 JFax Client Project ID', Burke Co. - Kirksey Drive Closed LF Pace Project Manager: Nicole Gasiorowski State I Location Requested Due Date/TAT, 10 Da Default Container Order Number: Pace Profile #: 2327-5 North Carolina Requamsted An lyzis Filtered Y!N � m a � � MATRIX CODE ° COLLECTED = Preservatives } Dnnkmg Water Dw U O Wa1e1 Wr W-I.Water VVw _ S U rip Proaud P SAMPLE ID SWS.Ild 5L '�° � on W Z } O'i oL One Character per box. Wm� WP w w START END a D m i N p m `o Air AR (A-2.0-91, -i Other OT O 0 a ¢ W 4, Sample Ids must be unique Tisx.e Ts X w p c O 03 a u.l w M LL n — O t Q S 4 ~ DATE TIME DATE TIME _= s z z O z Z 2 1201-MW2 WT G X X X I I 1 001 3 1201-MW3S WT G X X X Ot 4 1201-MW3D WT G ���5 �. _ X X X 5 1201-MW4 WT G jIj' X X X `r Ss 0V & 1201-Mw5 w7 G I tN X X x 7 1201-Mw6S WT G bt/r� j� X X X nolo 8 1201-MW6D V 7 G tt X X X 1201-SW1 WT G r!'r`J>✓!�f `�- �. X X X 10 1201-SW2 WT G I Y5),q I X X X 11t 1, WT G Ife' • X X X12 ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS i� SAMPLER NAME AND SIGNATURE n RI'T Naj(nne of AMPLE `o o mz w r 51 NAT E o DATE Signed: 2 u} o E z l` G r leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 November 18, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on November 06, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Ashley Martin, Labella Associates Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Pace Analytical Services Charlotte 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Lab ID Sample ID Matrix Date Collected Date Received 92452484001 92452484002 Field Blank Trip Blank Water Water 11/05/19 14:15 11/05/19 14:15 11/06/19 10:10 11/06/19 10:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co Blanks EB & Kirksey 92452484 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92452484001 Field Blank EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C 92452484002 Trip Blank EPA 8260D GAW 50 PASI-C EPA 8260D Mod. LMB 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Sample: Field Blank Lab ID: 92452484001 Collected: 11/05/19 14:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 11/18/2019 06:26 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 11/09/19 00:08 11/13/19 19:04 7440-36-0 ND ug/L 10.0 5.0 1 11/09/19 00:08 11/13/19 19:04 7440-38-2 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-39-3 ND ug/L 1.0 0.50 1 11/09/19 00:08 11/13/19 19:04 7440-41-7 ND ug/L 1.0 0.50 1 11/09/19 00:08 11/13/19 19:04 7440-43-9 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-47-3 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-48-4 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-50-8 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7439-92-1 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-02-0 ND ug/L 10.0 5.0 1 11/09/19 00:08 11/13/19 19:04 7782-49-2 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-22-4 ND ug/L 5.0 2.5 1 11/09/19 00:08 11/13/19 19:04 7440-62-2 ND ug/L 10.0 5.0 1 11/09/19 00:08 11/13/19 19:04 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 11/08/19 09:55 11/09/19 01:17 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 02:08 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 02:08 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 02:08 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 02:08 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 02:08 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 02:08 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 02:08 74-83-9 IK ND ug/L 5.0 3.3 1 11/15/19 02:08 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 02:08 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 02:08 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 02:08 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 02:08 75-00-3 IK,v1 ND ug/L 5.0 2.3 1 11/15/19 02:08 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 02:08 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 02:08 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 02:08 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 02:08 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 02:08 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 02:08 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 02:08 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 02:08 110-57-6 L1 ND ug/L 1.0 0.27 1 11/15/19 02:08 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 02:08 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 02:08 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 02:08 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 02:08 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 02:08 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Sample: Field Blank Lab ID: 92452484001 Collected: 11/05/19 14:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 11/18/2019 06:26 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 11/15/19 02:08 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 02:08 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 02:08 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 02:08 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 02:08 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 02:08 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 02:08 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 02:08 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 02:08 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 02:08 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 02:08 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 02:08 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 02:08 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 02:08 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 02:08 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 02:08 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 02:08 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 02:08 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 02:08 75-01-4 ND ug/L 1.0 0.63 1 11/15/19 02:08 1330-20-7 93 % 70-130 1 11/15/19 02:08 460-00-4 108 % 70-130 1 11/15/19 02:08 17060-07-0 100 % 70-130 1 11/15/19 02:08 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 11/09/1917:42 123-91-1 93 % 50-150 1 11/09/1917:42 17060-07-0 104 % 50-150 1 11/09/1917:42 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Sample: Trip Blank Lab ID: 92452484002 Collected: 11/05/19 14:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Date: 11/18/2019 06:26 PM Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 11/15/19 02:27 67-64-1 ND ug/L 10.0 0.90 1 11/15/19 02:27 107-13-1 ND ug/L 1.0 0.15 1 11/15/19 02:27 71-43-2 ND ug/L 1.0 0.34 1 11/15/19 02:27 74-97-5 ND ug/L 1.0 0.26 1 11/15/19 02:27 75-27-4 ND ug/L 1.0 0.62 1 11/15/19 02:27 75-25-2 ND ug/L 2.0 0.62 1 11/15/19 02:27 74-83-9 ND ug/L 5.0 3.3 1 11/15/19 02:27 78-93-3 ND ug/L 2.0 0.40 1 11/15/19 02:27 75-15-0 ND ug/L 1.0 0.22 1 11/15/19 02:27 56-23-5 ND ug/L 1.0 0.23 1 11/15/19 02:27 108-90-7 ND ug/L 1.0 0.49 1 11/15/19 02:27 75-00-3 ND ug/L 5.0 2.3 1 11/15/19 02:27 67-66-3 ND ug/L 1.0 0.39 1 11/15/19 02:27 74-87-3 ND ug/L 5.0 0.26 1 11/15/19 02:27 96-12-8 ND ug/L 1.0 0.41 1 11/15/19 02:27 124-48-1 ND ug/L 1.0 0.26 1 11/15/19 02:27 106-93-4 ND ug/L 1.0 0.46 1 11/15/19 02:27 74-95-3 ND ug/L 1.0 0.29 1 11/15/19 02:27 95-50-1 ND ug/L 1.0 0.26 1 11/15/19 02:27 106-46-7 ND ug/L 1.0 0.54 1 11/15/19 02:27 110-57-6 ND ug/L 1.0 0.27 1 11/15/19 02:27 75-34-3 ND ug/L 1.0 0.34 1 11/15/19 02:27 107-06-2 ND ug/L 1.0 0.24 1 11/15/19 02:27 75-35-4 ND ug/L 1.0 0.29 1 11/15/19 02:27 156-59-2 ND ug/L 1.0 0.25 1 11/15/19 02:27 156-60-5 ND ug/L 1.0 0.19 1 11/15/19 02:27 78-87-5 ND ug/L 1.0 0.30 1 11/15/19 02:27 10061-01-5 ND ug/L 1.0 0.31 1 11/15/19 02:27 10061-02-6 ND ug/L 1.0 0.26 1 11/15/19 02:27 100-41-4 ND ug/L 5.0 0.57 1 11/15/19 02:27 591-78-6 ND ug/L 20.0 12.5 1 11/15/19 02:27 74-88-4 ND ug/L 5.0 3.7 1 11/15/19 02:27 75-09-2 ND ug/L 5.0 4.5 1 11/15/19 02:27 108-10-1 ND ug/L 1.0 0.27 1 11/15/19 02:27 100-42-5 ND ug/L 1.0 0.34 1 11/15/19 02:27 630-20-6 ND ug/L 1.0 0.22 1 11/15/19 02:27 79-34-5 ND ug/L 1.0 0.16 1 11/15/19 02:27 127-18-4 ND ug/L 1.0 0.24 1 11/15/19 02:27 108-88-3 ND ug/L 1.0 0.18 1 11/15/19 02:27 71-55-6 ND ug/L 1.0 0.24 1 11/15/19 02:27 79-00-5 ND ug/L 1.0 0.22 1 11/15/19 02:27 79-01-6 ND ug/L 1.0 0.31 1 11/15/19 02:27 75-69-4 ND ug/L 1.0 0.35 1 11/15/19 02:27 96-18-4 ND ug/L 2.0 1.4 1 11/15/19 02:27 108-05-4 ND ug/L 1.0 0.24 1 11/15/19 02:27 75-01-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 115 IK,v1 L1 Page 7 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Sample: Trip Blank Lab ID: 92452484002 Collected: 11/05/19 14:15 Received: 11/06/19 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D Xylene (Total) ND ug/L 1.0 0.63 1 11/15/19 02:27 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 94 % 70-130 1 11/15/19 02:27 460-00-4 1,2-Dichloroethane-d4 (S) 106 % 70-130 1 11/15/19 02:27 17060-07-0 Toluene-d8 (S) 100 % 70-130 1 11/15/19 02:27 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 11/09/19 18:02 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 94 % 50-150 1 11/09/19 18:02 17060-07-0 Toluene-d8 (S) 104 % 50-150 1 11/09/19 18:02 2037-26-5 Date: 11/18/2019 06:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 QC Batch: 508588 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92452484001 METHOD BLANK: 2730312 Associated Lab Samples: 92452484001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.0 11/14/1917:49 Arsenic ug/L ND 10.0 4.7 11/14/1917:49 Barium ug/L ND 5.0 1.0 11/14/1917:49 Beryllium ug/L ND 1.0 0.20 11/14/1917:49 Cadmium ug/L ND 1.0 0.40 11/14/1917:49 Chromium ug/L ND 5.0 1.0 11/14/1917:49 Cobalt ug/L ND 5.0 1.1 11/14/1917:49 Copper ug/L ND 5.0 2.1 11/14/1917:49 Lead ug/L 1.91 5.0 1.6 11 /14/19 17:49 Nickel ug/L ND 5.0 0.90 11/14/1917:49 Selenium ug/L ND 10.0 4.7 11/14/1917:49 Silver ug/L ND 5.0 2.5 11/14/1917:49 Vanadium ug/L ND 5.0 1.3 11/14/1917:49 Zinc ug/L ND 10.0 3.9 11/14/1917:49 LABORATORY CONTROL SAMPLE: Parameter 2730313 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 467 93 80-120 Arsenic ug/L 500 468 94 80-120 Barium ug/L 500 472 94 80-120 Beryllium ug/L 500 472 94 80-120 Cadmium ug/L 500 467 93 80-120 Chromium ug/L 500 469 94 80-120 Cobalt ug/L 500 463 93 80-120 Copper ug/L 500 471 94 80-120 Lead ug/L 500 465 93 80-120 Nickel ug/L 500 463 93 80-120 Selenium ug/L 500 458 92 80-120 Silver ug/L 250 235 94 80-120 Vanadium ug/L 500 470 94 80-120 Zinc ug/L 500 466 93 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2730314 2730315 MS MSD 92452099007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 509 510 101 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Burke Co Blanks EB & Kirksey 92452484 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2730314 2730315 MS MSD 92452099007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 492 494 98 99 75-125 0 20 Barium ug/L 26.8 500 500 521 518 99 98 75-125 1 20 Beryllium ug/L ND 500 500 507 500 101 100 75-125 1 20 Cadmium ug/L ND 500 500 477 476 95 95 75-125 0 20 Chromium ug/L ND 500 500 494 491 99 98 75-125 1 20 Cobalt ug/L ND 500 500 480 480 96 96 75-125 0 20 Copper ug/L ND 500 500 495 491 99 98 75-125 1 20 Lead ug/L ND 500 500 480 480 96 96 75-125 0 20 Nickel ug/L ND 500 500 487 483 97 97 75-125 1 20 Selenium ug/L ND 500 500 513 506 103 101 75-125 1 20 Silver ug/L ND 250 250 253 252 101 101 75-125 0 20 Vanadium ug/L ND 500 500 496 494 99 98 75-125 0 20 Zinc ug/L ND 500 500 493 489 98 98 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 QC Batch: 508408 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92452484001 METHOD BLANK: 2729091 Matrix: Water Associated Lab Samples: 92452484001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 11/08/1915:54 LABORATORY CONTROL SAMPLE: 2729092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.1 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2729093 2729094 MS MSD 92452442014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.1 10.1 100 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 QC Batch: 509649 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92452484001, 92452484002 METHOD BLANK: 2735246 Associated Lab Samples: 92452484001, 92452484002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 11/15/19 00:55 1,1,1-Trichloroethane ug/L ND 1.0 0.18 11/15/19 00:55 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 11/15/19 00:55 1,1,2-Trichloroethane ug/L ND 1.0 0.24 11/15/19 00:55 1,1-Dichloroethane ug/L ND 1.0 0.27 11/15/19 00:55 1,1-Dichloroethene ug/L ND 1.0 0.24 11/15/19 00:55 1,2,3-Trichloropropane ug/L ND 1.0 0.35 11/15/19 00:55 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 11/15/19 00:55 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 11/15/19 00:55 1,2-Dichlorobenzene ug/L ND 1.0 0.29 11/15/19 00:55 1,2-Dichloroethane ug/L ND 1.0 0.34 11/15/19 00:55 1,2-Dichloropropane ug/L ND 1.0 0.19 11/15/19 00:55 1,4-Dichlorobenzene ug/L ND 1.0 0.26 11/15/19 00:55 2-Butanone (MEK) ug/L ND 5.0 3.3 11/15/19 00:55 2-Hexanone ug/L ND 5.0 0.57 11/15/19 00:55 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 11/15/19 00:55 Acetone ug/L ND 25.0 6.2 11/15/19 00:55 Acrylonitrile ug/L ND 10.0 0.90 11/15/19 00:55 Benzene ug/L ND 1.0 0.15 11/15/19 00:55 Bromochloromethane ug/L ND 1.0 0.34 11/15/19 00:55 Bromodichloromethane ug/L ND 1.0 0.26 11/15/19 00:55 Bromoform ug/L ND 1.0 0.62 11/15/19 00:55 Bromomethane ug/L ND 2.0 0.62 11/15/19 00:55 Carbon disulfide ug/L ND 2.0 0.40 11/15/19 00:55 Carbon tetrachloride ug/L ND 1.0 0.22 11/15/19 00:55 Chlorobenzene ug/L ND 1.0 0.23 11/15/19 00:55 Chloroethane ug/L ND 1.0 0.49 11/15/19 00:55 Chloroform ug/L ND 5.0 2.3 11/15/19 00:55 Chloromethane ug/L ND 1.0 0.39 11/15/19 00:55 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 11/15/19 00:55 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 11/15/19 00:55 Dibromochloromethane ug/L ND 1.0 0.41 11/15/19 00:55 Dibromomethane ug/L ND 1.0 0.46 11/15/19 00:55 Ethylbenzene ug/L ND 1.0 0.26 11/15/19 00:55 lodomethane ug/L ND 20.0 12.5 11/15/19 00:55 Methylene Chloride ug/L ND 5.0 3.7 11/15/19 00:55 Styrene ug/L ND 1.0 0.27 11/15/19 00:55 Tetrachloroethene ug/L ND 1.0 0.16 11/15/19 00:55 Toluene ug/L ND 1.0 0.24 11/15/19 00:55 trans-1,2-Dichloroethene ug/L ND 1.0 0.25 11/15/19 00:55 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 11/15/19 00:55 Qualifiers IK IK,v1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 METHOD BLANK: 2735246 Associated Lab Samples: 92452484001, 92452484002 Parameter Units trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LABORATORY CONTROL SAMPLE: 2735247 Parameter QUALITY CONTROL DATA Matrix: Water Blank Result Reporting Limit ND 1.0 ND 1.0 ND 1.0 ND 2.0 ND 1.0 ND 1.0 106 70-130 93 70-130 99 70-130 MDL Analyzed 0.54 11/15/19 00:55 0.22 11/15/19 00:55 0.31 11/15/19 00:55 1.4 11/15/19 00:55 0.24 11/15/19 00:55 0.63 11/15/19 00:55 11/15/19 00:55 11/15/19 00:55 11/15/19 00:55 Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.5 103 70-130 1,1,1-Trichloroethane ug/L 50 53.7 107 70-130 1,1,2,2-Tetrachloroethane ug/L 50 52.2 104 70-130 1,1,2-Trichloroethane ug/L 50 54.4 109 70-130 1,1-Dichloroethane ug/L 50 52.9 106 70-130 1,1-Dichloroethene ug/L 50 53.6 107 70-130 1,2,3-Trichloropropane ug/L 50 54.6 109 70-130 1,2-Dibromo-3-chloropropane ug/L 50 53.5 107 70-130 1,2-Dibromoethane (EDB) ug/L 50 53.9 108 70-130 1,2-Dichlorobenzene ug/L 50 52.3 105 70-130 1,2-Dichloroethane ug/L 50 49.7 99 70-130 1,2-Dichloropropane ug/L 50 54.1 108 70-130 1,4-Dichlorobenzene ug/L 50 52.4 105 70-130 2-Butanone (MEK) ug/L 100 105 105 64-135 2-Hexanone ug/L 100 109 109 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 106 106 70-130 Acetone ug/L 100 124 124 61-157 Acrylonitrile ug/L 250 257 103 61-143 Benzene ug/L 50 52.1 104 70-130 Bromochloromethane ug/L 50 53.3 107 70-130 Bromodichloromethane ug/L 50 54.1 108 70-130 Bromoform ug/L 50 53.6 107 70-130 Bromomethane ug/L 50 57.9 116 38-130lK Carbon disulfide ug/L 50 55.1 110 68-130 Carbon tetrachloride ug/L 50 53.0 106 70-130 Chlorobenzene ug/L 50 51.1 102 70-130 Chloroethane ug/L 50 36.5 73 37-142 IK,v1 Chloroform ug/L 50 54.4 109 70-130 Chloromethane ug/L 50 46.5 93 48-130 cis-1,2-Dichloroethene ug/L 50 51.9 104 70-130 cis-1,3-Dichloropropene ug/L 50 56.6 113 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 LABORATORY CONTROL SAMPLE: 2735247 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Dibromochloromethane ug/L 50 51.7 103 70-130 Dibromomethane ug/L 50 51.8 104 70-130 Ethylbenzene ug/L 50 51.9 104 70-130 lodomethane ug/L 100 99.7 100 40-130 Methylene Chloride ug/L 50 49.8 100 67-132 Styrene ug/L 50 54.2 108 70-130 Tetrachloroethene ug/L 50 50.4 101 69-130 Toluene ug/L 50 51.9 104 70-130 trans-1,2-Dichloroethene ug/L 50 54.6 109 70-130 trans- 1,3-Dichloropropene ug/L 50 56.2 112 70-130 trans-1,4-Dichloro-2-butene ug/L 50 111 222 35-189 L1 Trichloroethene ug/L 50 51.7 103 70-130 Trichlorofluoromethane ug/L 50 52.5 105 63-130 Vinyl acetate ug/L 100 115 115 55-143 Vinyl chloride ug/L 50 54.9 110 70-131 Xylene (Total) ug/L 150 158 105 70-130 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 103 70-130 MATRIX SPIKE SAMPLE: 2735249 92452862004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 20 21.7 109 73-134 1,1,1-Trichloroethane ug/L ND 20 22.1 110 82-143 1,1,2,2-Tetrachloroethane ug/L ND 20 20.5 102 70-136 1,1,2-Trichloroethane ug/L ND 20 19.7 99 70-135 1,1-Dichloroethane ug/L ND 20 22.2 111 70-139 1,1-Dichloroethene ug/L ND 20 22.5 112 70-154 1,2,3-Trichloropropane ug/L ND 20 21.5 107 71-137 1,2-Dibromo-3-chloropropane ug/L ND 20 22.2 111 65-134 1,2-Dibromoethane (EDB) ug/L ND 20 21.5 108 70-137 1,2-Dichlorobenzene ug/L ND 20 21.3 107 70-133 1,2-Dichloroethane ug/L ND 20 19.0 95 70-137 1,2-Dichloropropane ug/L ND 20 20.3 101 70-140 1,4-Dichlorobenzene ug/L ND 20 21.4 107 70-133 2-Butanone (MEK) ug/L ND 40 41.8 101 60-139 2-Hexanone ug/L ND 40 41.3 103 65-138 4-Methyl-2-pentanone (MIBK) ug/L ND 40 38.0 95 65-135 Acetone ug/L 11 AJ 40 45.5 85 60-148 Acrylonitrile ug/L ND 100 100 100 64-147 Benzene ug/L ND 20 20.6 103 70-151 Bromochloromethane ug/L ND 20 21.7 109 70-141 Bromodichloromethane ug/L ND 20 20.0 100 70-138 Bromoform ug/L ND 20 21.1 106 63-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 MATRIX SPIKE SAMPLE: 2735249 92452862004 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromomethane ug/L ND 20 27.9 140 15-152 IK,v3 Carbon disulfide ug/L ND 20 23.5 117 69-149 Carbon tetrachloride ug/L ND 20 22.9 115 70-143 Chlorobenzene ug/L ND 20 20.9 105 70-138 Chloroethane ug/L ND 20 19.8 99 52-163 Chloroform ug/L ND 20 21.5 107 70-139 Chloromethane ug/L ND 20 20.0 100 41-139 cis-1,2-Dichloroethene ug/L 0.98J 20 22.8 109 70-141 cis-1,3-Dichloropropene ug/L ND 20 20.6 103 70-137 Dibromochloromethane ug/L ND 20 21.4 107 70-134 Dibromomethane ug/L ND 20 19.7 98 70-138 Ethylbenzene ug/L ND 20 21.6 108 66-153 Iodomethane ug/L ND 40 43.6 109 20-1381K,v1 Methylene Chloride ug/L ND 20 20.7 103 42-159 Styrene ug/L ND 20 21.8 109 70-135 Tetrachloroethene ug/L ND 20 22.0 110 59-143 Toluene ug/L ND 20 19.5 98 59-148 trans-1,2-Dichloroethene ug/L ND 20 21.9 109 70-146 trans- 1,3-Dichloropropene ug/L ND 20 20.2 101 70-135 trans-1,4-Dichloro-2-butene ug/L ND 20 22.8 114 47-135 Trichloroethene ug/L ND 20 20.5 103 70-147 Trichlorofluoromethane ug/L ND 20 20.9 105 70-148 Vinyl acetate ug/L ND 40 40.1 100 49-151 Vinyl chloride ug/L ND 20 23.8 119 70-156 Xylene (Total) ug/L ND 60 65.2 109 63-158 1,2-Dichloroethane-d4 (S) % 99 70-130 4-Bromofluorobenzene (S) % 100 70-130 Toluene-d8 (S) % 96 70-130 SAMPLE DUPLICATE: 2735248 92452518010 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND ND 30 1,1,1-Trichloroethane ug/L ND ND 30 1,1,2,2-Tetrachloroethane ug/L ND ND 30 1,1,2-Trichloroethane ug/L ND ND 30 1,1-Dichloroethane ug/L ND ND 30 1,1-Dichloroethene ug/L ND ND 30 1,2,3-Trichloropropane ug/L ND ND 30 1,2-Dibromo-3-chloropropane ug/L ND ND 30 1,2-Dibromoethane (EDB) ug/L ND ND 30 1,2-Dichlorobenzene ug/L ND ND 30 1,2-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 1,4-Dichlorobenzene ug/L ND ND 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 SAMPLE DUPLICATE: 2735248 Parameter Units 92452518010 Result 2-Butanone (MEK) ug/L ND 2-Hexanone ug/L ND 4-Methyl-2-pentanone (MIBK) ug/L ND Acetone ug/L ND Acrylonitrile ug/L ND Benzene ug/L ND Bromochloromethane ug/L ND Bromodichloromethane ug/L ND Bromoform ug/L ND Bromomethane ug/L ND Carbon disulfide ug/L ND Carbon tetrachloride ug/L ND Chlorobenzene ug/L ND Chloroethane ug/L ND Chloroform ug/L ND Chloromethane ug/L ND cis-1,2-Dichloroethene ug/L ND cis-1,3-Dichloropropene ug/L ND Dibromochloromethane ug/L ND Dibromomethane ug/L ND Ethylbenzene ug/L ND lodomethane ug/L ND Methylene Chloride ug/L ND Styrene ug/L ND Tetrachloroethene ug/L ND Toluene ug/L ND trans-1,2-Dichloroethene ug/L ND trans- 1,3-Dichloropropene ug/L ND trans-1,4-Dichloro-2-butene ug/L ND Trichloroethene ug/L ND Trichlorofluoromethane ug/L ND Vinyl acetate ug/L ND Vinyl chloride ug/L ND Xylene (Total) ug/L ND 1,2-Dichloroethane-d4 (S) % 107 4-Bromofluorobenzene (S) % 92 Toluene-d8 (S) % 101 Dup Result RPD Max RPD Qualifiers ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 IK ND 30 ND 30 ND 30 ND 30 IK,v1 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 ND 30 109 94 98 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 QC Batch: 508649 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92452484001, 92452484002 METHOD BLANK: 2730478 Matrix: Water Associated Lab Samples: 92452484001, 92452484002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 11/09/19 16:43 1,2-Dichloroethane-d4 (S) % 90 50-150 11/09/19 16:43 Toluene-d8 (S) % 101 50-150 11/09/19 16:43 LABORATORY CONTROL SAMPLE: 2730479 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.1 96 70-130 1,2-Dichloroethane-d4 (S) % 94 50-150 Toluene-d8(S) % 101 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2730480 2730481 MS MSD 92452508006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 12.3 20 20 31.0 28.2 93 79 50-150 9 30 1,2-Dichloroethane-d4 (S) % 101 92 50-150 30 Toluene-d8 (S) % 108 107 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the associated samples may have low bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /18/2019 06:26 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 22 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co Blanks EB & Kirksey Pace Project No.: 92452484 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92452484001 Field Blank EPA 3010A 508588 EPA6010D 508608 92452484001 Field Blank EPA 3010A 508408 EPA6020B 508443 92452484001 Field Blank EPA 8260D 509649 92452484002 Trip Blank EPA 8260D 509649 92452484001 Field Blank EPA 8260D Mod. 508649 92452484002 Trip Blank EPA 8260D Mod. 508649 Date: 11/18/2019 06:26 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 22 r Document Name: Document Revised: February 7, 2018 �� Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: /-!'aceAnalytical F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ® Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑ SampleCondition Client Name: W®# :92452484 Upon Receipt Project k II f I i Ll/� �� I'f'G sSOL icr Ir c Courier: Fed Ex ❑UPS ❑u5P5 [:]Clientfl� ❑ Commercial Pace ❑Other: 92452484 Custody Seal Present? []Yes 3]No Seals Intact? ❑Yes [MNo Packing Material: ❑Bubb€e Wrap Bubble Bags ❑None ❑ Other Thermometer: jOIR Gun ID: 0�' f Type of Ice: �JWet ❑61ue Cooler Temp (°C); J, A Y Correction Factor: Add/Subtract (°C) 11 Cooler Temp Corrected (C): USDA Regulated Soil (4 N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Date/Initials Person Examining Contents: Biological Tissue Frozen? ❑Yes [:]No UN/A ❑None Temp should be above freezing to 6°C []Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source (internationally, ❑Yes ®No including Hawaii and Puerto ItiCo}r uYes ivo Comments/Discrepancy: Chain of Custody Present? ' Yes []No ❑N/A 1. Samples Arrived within Hold Time? WYes ❑No ❑N/A 2. Short Hold Time Analysis (02 hr.)? ❑Yes ;CNo ❑N/A 3. Rush Turn Around Time Requested? ❑Yes XNo ❑N/A 4. Sufficient Volume? Yes ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? MY., XYes []No ❑No []N/A ❑N/A 6. Containers Intact? JKyes ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No �flN/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix: Ayes ❑No ❑N/A 4. Headspace in VOA Vials (>5-6mm)? ❑Yes No El N/A 10. Trip Blank Present? Trip Blank Custody Seals Present? [Yes Yes ❑No [—]No ❑N/A ❑N/A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted; Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Field Data Required? ❑Yes [—]No Date; I(4 Lg I y Date: It 11 Le IA9, Page 20 of 22 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCl1R) Page 1 of Z Document No.: Issuing Authority: aceAnal�trcal F-CAR-CS-033-Rev.06 Pace Carolinas 4ua#ity Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water} DOC, LLHg **Bottom half of box is to list number of bottle Project #f WQ# : 92452484 PM: NMG Due Date: 11/20/19 CLIENT: 92—Joyce Eng E v Z L v a a J n N-1 7 a a ca Z 7 y d r 7 u J N 7 m a m Z ] m v a u u d J 3 N n. m _ a ca m d 6 , a m _ = a O = u a a a m v a n1 O z J M a m o z ai m W Q N u J a a m n o. r O Z u v a m N `; m a v W n c E QQ �4 1.7 Q v O. u 2 E *i l7 Q < 4 c ¢ En o M l7 Q V V 0 ry S E vEMEEJEE.7mEE l7 ¢ a z L Q M [7 Q 7 z E Q E o m l7` Q 2 U x O o Cn C7 0 z M m 0C 7 C7 > Q Z a C a a a00 i7 > Q v 0 m 0 l7 0 z Y m o vy + x LA n 0 > a Z ,� 2 a > : M > z w m rL °J .-i a H n I Q z a = J N N a F m 0 p ^� S z w J o M a ra -o N 2 yJ a E ¢a E 0 CM(7 W Q z c J E 0 ti > z v a QJE 0 M l7 0 1 I V N 2 3 4 S 6 7 8 9 10 11 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot # Nate: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 21 of 22 �aceAnalytical CHAIN -OF -CUSTODY I Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section 8 Section C Required Client Information: Required Project Information: Invoice Information: Page : t Of 1 Company LaBella Associates Report To: Van Burbach Attention Lecia Jones Address 2211 West Meadowview Rd copy To: Gretta Eller company Name: LaBella Associates Greensboro, NC 27407 Address: 1604 Ownby Lane, Richmond, VA 2322 Regulatory Agency Email To. vburbach labella C.Com Purchase Order No. Pace Quote Reference, Phone: 336 323-0092 JFax Client Project ID Burke Co.Blanks ES & Kirksey Pace Project Manager- Nicole Gasjorowski State! Location Requested Due Date/TAT. 10 Da Default Container Order Number: Pace Profile M 2327-5 North Carolina Requested An lysis Filtered Y!N D � Z MATRIX CODE O COLLECTED z Preservatives } D—kmg Wetm Dw V 9 Water WT W�sta wefpr WVJ u a C~7 � P'... P SAMPLE ID S..VSnkd SL _ m START END 0 m m F m 'm m 0 Z m oa of One Character per box. Wrp� wP w w 4 Z °° 7 0 (A-Z. D-9 . -i Mr RR Orner oT O F F F Q Z m Zm CS w T, b m L # Sample Ids must be unique T-- T5 V x m O m .r (7 cLLJ eri o. _U X a a U m a�o-o�a¢<o 0 0 0 0 c C a n o �lb�y 4� DATE TIMEFDITE TIME �� y u __= z O i z 04 1 Field Blank V T G ms X X X 11 O t 2 Trip Blank VJT G X X 00 3 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQUISHED BY! AFFILIATION DATE TIME ACCEPTED BY! AFFILIATIO1N/ PATE SAMPLE CONDITIONS �vrcq jlhCty V g ftr. --nio G pTime G SAMPLER NAME AND SIGNATURE m o C o m Z c INjName of SAMPL k m } o o z_ 5 1 U E o,�AIMPL DATE Si ne . UJ L LaBella 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Sampled By: ' r- J fir,^ �Q2 Telephone: (336) 323-0092 Facsimile: (336) 323093 Date: WELL I.D.: Weather: CU(a 3 Project Name: Location: Project No.: WELL SAMPLING INFORMATION �11 Well Diameter: Depth of Well: Measuring Point: Pump Type:6�- FTF.1.>) PARAMF.TF.R MF.AIRURF.MF.NT Static Water Level: Length of Well Screen: Depth to Top of Pump: Tubing Type: cZ+ .. to .. -70 Gallon, Dissolved 02 i Redox Alkalinity i orai a _y -urgeo Purge Time Purge Time End: Start: 1 3 ! Q OBSERVATIONS Notes: Final Static Water Level: " ` 5 q Project Name: -&k �� N 141 Y LaBella Location: 4—Y46-a znw JI Project No.: 2 t 2 2211W. Meadowview Rd Suite 101 Greensboro, NC 27407 Sampled By: y)a % accaw 2n_ �Q2 Telephone: (336) 323-0092 Facsimile: (336) 323-0093 Date: WELL I.D.: _ VI U]— y Weather: LIDU, WELL SAMPLING INFORMATION Well Diameter: 2 N' Depth of Well: Measuring Point: �i7C Pump Type: Q cCm VW..T.D PARAMT.TIM MR..ACiTRIWA4F.NT Static Water Level: go. qq -4 _ Length of Well Screen: Depth to Top of Pump: 2 + Tubing Type: TbUbk 6 d Pump Rate allons Purged Mw Conductivity (MS/CM) Tu�' (NTU) Dissolv—edO, Jmg/L) Alkalinity Comments — rya=�&�= al, r�� '«■ cam - ���� 1 UCdl ✓- 17 Purge Time Start: OBSERVATIONS Notes: %-mwme t-grgeu Purge Time End: f2 V Final Static Water Level: 1*160 l��u /Zozc� 20- -72 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 February 03, 2020 Mr. Van Burbach Joyce Engineering -NC 2211 W. Meadowview Road Suite 101 Greensboro, NC 27407 RE: Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on January 24, 2020. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Mr. Daniel Girdner, Joyce Engineering -Greensboro Ashley Martin, Labella Associates Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Pace Analytical Services Asheville 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Lab ID Sample ID Matrix Date Collected Date Received 92462201001 1201-MW-2 Water 01/23/2013:40 01/24/2010:10 92462201002 1201-MW-4 Water 01/23/2012:30 01/24/2010:10 92462201003 Field Blank Water 01/23/20 13:55 01/24/20 10:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co.-Kirksey Drive Closed 92462201 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92462201001 1201-MW-2 EPA 6010D RDT 1 PASI-A 92462201002 1201-MW-4 EPA 6010D SH1 1 PASI-A 92462201003 Field Blank EPA 6010D SH1 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co.-Kirksey Drive Closed 92462201 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92462201001 1201-MW-2 EPA 601 OD Vanadium 5.1 ug/L 5.0 01 /29/20 22:18 92462201002 1201-MW-4 EPA 601OD Vanadium 2.3J ug/L 5.0 02/01/2013:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Sample: 1201-MW-2 Lab ID: 92462201001 Collected: 01/23/20 13:40 Received: 01/24/20 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Vanadium 5.1 ug/L 5.0 1.3 1 01/28/20 01:02 01/29/20 22:18 7440-62-2 Date: 02/03/2020 10:17 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Sample: 1201-MW-4 Lab ID: 92462201002 Collected: 01/23/20 12:30 Received: 01/24/20 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Vanadium 2.3J ug/L 5.0 1.3 1 01/30/20 01:11 02/01/20 13:31 7440-62-2 Date: 02/03/2020 10:17 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Sample: Field Blank Lab ID: 92462201003 Collected: 01/23/20 13:55 Received: 01/24/20 10:10 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Vanadium ND ug/L 5.0 1.3 1 01/30/20 01:11 02/01/20 13:34 7440-62-2 Date: 02/03/2020 10:17 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 QC Batch: 521690 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92462201001 METHOD BLANK: 2790879 Matrix: Water Associated Lab Samples: 92462201001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vanadium ug/L ND 5.0 1.3 01/29/20 21:30 LABORATORY CONTROL SAMPLE: 2790880 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vanadium ug/L 500 490 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2790881 2790882 MS MSD 92461861003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vanadium ug/L 2.7J 500 500 511 510 102 101 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/03/2020 10:17 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 QC Batch: 522192 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92462201002, 92462201003 METHOD BLANK: 2793084 Matrix: Water Associated Lab Samples: 92462201002, 92462201003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Vanadium ug/L ND 5.0 1.3 02/01/2013:07 LABORATORY CONTROL SAMPLE: 2793085 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Vanadium ug/L 500 502 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2793086 2793087 MS MSD 92461746003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Vanadium ug/L 49.5 500 500 574 578 105 106 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/03/2020 10:17 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/03/2020 10:17 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 15 leAnalyiical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co.-Kirksey Drive Closed Pace Project No.: 92462201 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92462201001 1201-MW-2 EPA 3010A 521690 EPA 6010D 521703 92462201002 1201-MW-4 EPA 3010A 522192 EPA 6010D 522212 92462201003 Field Blank EPA 3010A 522192 EPA6010D 522212 Date: 02/03/2020 10:17 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 15 Document Name: Sample Condition Upon Recell Document No.: F-CAR-CS-033-Rev.06 Document Ite+nseo: reoruary r, cusa Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[] Greenwood ❑ Huntersviile �l Raleigh❑ Mechanicsville[] Sample Condition Client Name: WO# . 92462201 Upon Receipt Project I I Laurier: ❑Fed Ex ❑UPS ❑U5P5 ❑Client ❑ Commercial ❑Pace ❑Other: 92462201 Custody Seal Present? [-]Yes ❑go Seals intact? ❑Yes ❑No Date/Initials Person Examining Contents: - Packing Material: ❑Bubble Wrap ❑Bubble Bags QNone ❑ Other Biological Tissue Frozen? ❑Yes ❑1'% []N/A92TO58Thermometer:. Type of Ice: []Wet ❑glue ❑None [iA Gun ID: Cooler Temp ('C): Correction Factor: Add/Subtract (*Cl 0.0°C Temp should be above freezing to VC Cooler Temp Corrected ('C): , ❑samples out of temp criteria. Samples an ice, cooling process hasbegun USDA Regulated Soll ([a N/A, water sample) Did samples origin4te in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, five f-1 Irtcludine Hawaii and Puerto Ricci? ❑Yes ❑No Comments/Olscrepancy: Chain of Custody Present? E e`s ❑No ❑N/A 1. Arrived within Hold lime) 17Z PC QNn 2. —Samples Short Hold TlmeAnalysis 1<72 hr.)? ❑Yes ONo ❑N/A 3. Rush Turn Around Time Requested? []Yes []No ❑N/A 4. Sufficient Volume? QYes ❑No []N/A 5. Correct Containers Used? -Pace Containers Used? M� QYes ❑No []No ❑N/A []N/A 6. Containers Intact? ©Yes [:)No ❑N/A 7. Dissolved analysis: samples Field Filtered? Dyes ❑No [-]N/A a. Sample Labels Match CDC? -IncludesDate/Time/ID/Analysis Matrix: DYes ❑No ❑N/A 9. Headspace in VOA Vials (>5-6mm)7 ❑Yes E]No [—]NIA 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes []Yes BNo ❑No ❑NIA UNIA 11, COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Field Data Required? []Yes []NO Person contacted: Date/Time: Project Manager SCURF Review: Date:--94- If/2L " 12 L Project Manager SRF Review: Date: Page 13 of 15 Document Name: Document Revised: February 7, 2018 aceAaalytical Sample Condition Upon RecelptiSCURi Page 1 of 2 Document No.: Issuing Authority: F-CAR-Cs-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS "Bottom half of box is to list number of bottle Project$1 Wp# : 924622Q1 PM: NMG Due Date: 02/04/20 CLIENT: 92-Joyce Eng u y z z 2 _ Z a ro a a z 2 Z < z ry m 20 m a i' . a Z m v v j w v = a T Z q ? rc d z O Z Z oN, n r QJ a m o i W ° O LA a m O ag _a ]v a c O 2 ? O N Z Zv 5 u ` N ry C a u u Z n u rviL O.n 5M m !V? y o m 7vE U m a a b n V m = ry a R a E .a E n E E ¢ F E ¢ o r^v a O 7 q O a O 7 Cr O D a C6 L u! a ^ m a E a c E a J E E E n J E J E 1 E 1 E v a « q o ¢ °= E m E ) E E E y 9 E. E 1 aE J E E A R '> ry > 'J �yN` N nNLr' N V 1=s .y ,y '+ •1 N M wyy, ri N WI If G� q 41 a Q1 d1 !af_[V-� a N N N en a m a co d m a m 0. m s � s m d m 3 U' a 11' a t7 a t7 a l7 a l7 a lR o l7 a l7 7 t7 n O a i > d vs a 1n 0. m l9 a tT > C7 a 1 - 2 - 3 ,j 4 i 5 q7N 6 7 $ i i 9 \\N 11 12� pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon ret:':pt Date preservation adjusted Time preservation adjusted Amount of PreservAive added Lot 9 Note: Whenever there is a discrepancy artecting Nortn carouna compnance sampces, a copy ar u1n -i i vc3ent 1V u1e 1•sJiu1 . e v e --in ,11-6a 1— = 1,- Out of hold, incorrect preservative, out of temp, Incorrect containers. ---- -- Page 14 of 15 ceAnalyfical CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C Required Client Information: Required Project Information: Invoice Information: Page: 1 Of 1 Company LaBella Associates Report To: Van Burbach Attention: Lecia Jones Address: 2211 West Meadowview Rd Copy To: Gretta Eller Company Name La Bella Associates Greensboro, NC 27407 Address: 1604 Ownby Lane, Richmond, VA 2322t Regulatory Agency Email To, vburbach labella c.com Purchase Order No. Pace Quote Reference Phone: 336 323-0092 JFa. Client Project 1D' Burke CO. - Kirksey Drive Closed LF Pace Project Manager. Nicole Gasiorowski State I Location Requested Due DalefrAT: 10 Da Default Container Order Number. Pace Profile #: 2186-12 North Carolina Requested Analysis Filtered YIN 4 z tnaTaix coop 0 0, COLLECTED z Preservatives � @-king Wet,: OW L V WateS WT Wes1e W. WW u v U P,2a P SAMPLE ID snluseim sL 0.1 PL m START END v n m Z } One Character per box. W.P. WP LLl a O (AZ 0-9 7. -1 rnt AR w. or a $ � z 2 a t Sample ids must be unique Tm— T$ ,¢ o v m w O O— v' z ' c Q a ^� 0L F a u DATE TIME DATE TIME a z i r z o L 1 0 f 1 1201-MW2 WT G J/�' r �� ; �� iv i i X 2 1201-MW4 VVT G •; -.'>-� � _?i...' �)a3 22 1-[ �,, /� X /y U/ 3 Field Blank WT G - I h'i�?r �j i �- X 4 5 6 7 8 9 10 11 12 ADDITIONAL COMMENTS RELINQtASHEDBY AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS SAMPLER NAME AND SIGNATURE c Ts m -' 0 L' INT{N;tmfC. ofSAIMPLER:Z _ } o E z r:SIGNATLREof,SAM LER- I// DATE Signed: APPENDIX 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Background Downgradient Location MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 102 2.7 6 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 27-May-08 1085.56 1049.57 1014.24 1022.76 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 01-Jun-09 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 4-Nov-19 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1054.90 1053.09 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 damaged approx. June 2017 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6s MW-6D Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 ug/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA6010D 3.9 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA6010D 3.9 5.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA6010D 3.0 5.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC2L = 50 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC21- = 10 ug/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL P16 MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC21- = 2,000 pg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC21L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 INS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1040 388 167 82 J 28 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 --- 1470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 --- 1240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 --- 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 --- 1160 507 205 82 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 --- 1040 454 181 82.6 37.5 43.7 12.2 ND 5-Nov-19 EPA 6010D 2.5 5 --- 1370 448 219 130 46.5 35.6 17.0 --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 ug/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.2 1.0 --- ND ND ND ND 0.23 J ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 1.75 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC21- = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND INS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- 2 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 0.4 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC21- = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 2.5 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.0 5.0 --- ND ND ND 5.9 1.8 J ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI Ni NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 ug/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 ug/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 NS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA6010 2.5 10.0 - 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA6010 2.5 10.0 - 114 11.0 ND ND ND ND ND ND 14-May-18 EPA6010 2.5 10.0 - 102 20.2 ND ND ND 4.2 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 107 14.4 ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.1 5.0 - 119 12.3 ND 1.6 J 1.3 J ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC21- = 1,000 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND INS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 8.3 5.8 3.2 J ND 3.1 J ND ND ND 5-Nov-19 EPA 6010D 2.1 5.0 --- 3.3 J ND ND 4.6 J ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC21- = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6O1OD 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 --- 4.9 J 3.2 J ND ND ND ND ND ND 5-Nov-19 EPA 6O1OD 1.6 5.0 --- 5.2 2.0 J ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC21- = 100 Ng/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND INS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 --- 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 --- 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 --- 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 14.5 4.4 J 25.7 3.0 J ND ND ND ND 5-Nov-19 EPA 6010D 0.9 5.0 --- 16.8 3.3 J 28.7 2.4 J 1.0 J ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC2L = 50 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC21- = 20 ug/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 4.7 10.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC2L = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 ug/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 ug/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND (4.81 J ND ND 4.0 (ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA6020B 0.0 5.5 - ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA6020B 0.03 0.1 - ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA6020 0.50 5.5 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA6020B 0.06 0.1 - ND ND ND ND ND ND ND ND 6-May-19 EPA6020B 0.06 0.1 - ND ND ND ND 0.087 J ND ND ND 5-Nov-19 EPA6020B 0.06 0.1 - ND ND 0.061 J 0.060 J 0.16 ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND INS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13.0 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 --- 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 --- 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 --- 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND 3.0 J ND 6.0 ND ND ND ND Resample > 8-Feb-19 EPA 6010D 2.5 5.0 --- - --- --- ND - - 6-May-19 EPA 6010D 2.5 5.0 --- 4.1 J ND ND ND ND ND ND ND 5-Nov-19 EPA 6010D 1.3 5.0 --- 5.3 1.8 J ND 10.0 3.8 J ND ND --- Resample > 23-Jan-20 EPA 6010D 1.3 5.0 --- 5.1 --- --- 2.3 J - --- --- --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC2L = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC21- = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND 5.9 J ND ND 7.5 J ND 7.6 J ND 5-Nov-19 EPA 6010D 3.9 10.0 --- ND ND ND 15.4 7.5 J ND 7.0 J --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC21- = 700 pWL (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC21- = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 --- ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 --- 484 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 10.0 25 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 8.2 25 --- 299 M3 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 6.2 25 --- 105 ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC2L = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 INS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 --- 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 --- 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 --- 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 --- 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA8260D 0.20 1.0 --- 10.4 4.6 1.7 ND ND ND ND ND 5-Nov-19 EPA8260D 0.15 1.0 --- 8.3 3.4 1.3 ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC21- = 700 ug/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND NS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 1.2 2 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.8 10 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.4 2 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 --- 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 --- 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 --- 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 8260E 0.23 1.0 --- 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 --- 26.6 36.4 8.7 ND ND ND ND ND 5-Nov-19 EPA 8260D 0.23 1.0 --- 22.5 32.7 7.5 ND ND 0.28 J ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 2,800 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC2L = 3,000 Ng/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J INS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 --- ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 --- ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.54 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.52 1.0 --- ND 1.8 0.56 J ND ND ND ND ND 5-Nov-19 EPA8260D 0.49 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21- = 70 ug/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.14 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 --- ND ND ND ND ND 0.67 J ND ND 5-Nov-19 EPA8260D 2.30 5.0 --- ND ND ND ND ND ND ND --- Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21- = 2.6 Ng/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 ug/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 --- 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.11 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.38 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.39 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC2L = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J INS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 --- 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 --- 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 --- 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 --- 2.4 0.88 J ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 --- 2.2 0.6 J ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC2L = 1.4 pg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 INS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 --- 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 --- 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 --- 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 --- 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 --- 47.3 14.6 4.8 ND ND ND ND ND 5-Nov-19 EPA8260D 0.26 1.0 --- 38.6 10.7 4.2 0.48 J ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J INS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 --- 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 --- 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 --- ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 --- 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA8260D 0.41 1.0 --- 0.68 J ND 6.1 ND ND ND ND ND 5-Nov-19 EPA8260D 0.27 1.0 --- 0.57 J 0.43 J 4.7 1.5 ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC21- = 0.4 Ng/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.24 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.67 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.34 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC2L = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 21 350 pg/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.56 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.72 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 PA 8260B Moc 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND 6-May-19 PA 8260D Moc 5.8 10 --- 218 57.0 128 2.4 ND ND ND ND 5-Nov-19 PA 8260D Moc 1.2 2 3 236 36.4 269 2.7 ND ND ND --- NC 21 = 3 pg/L cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J INS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 --- 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 --- 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 --- ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 --- 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA 8260D 0.66 1.0 --- ND ND 18.7 1.2 ND ND ND ND 5-Nov-19 EPA 8260D 0.29 1.0 --- 0.33 J ND 14.6 J 8 ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC2L = 100 Ng/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J INS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.49 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.46 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.25 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC2L = 0.51 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC21- = 0.6 pg/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 --- ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 --- ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 --- ND ND 1.1 ND ND ND ND ND 5-Nov-19 EPA8260D 0.19 1.0 --- ND ND 0.87 J ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC2L = 550 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC21- = 600 Ng/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 INS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 --- 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 --- 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 --- 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 --- 24.1 ND ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.26 1.0 --- 12.1 ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 ug/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 --- 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.46 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA826OD 0.89 5.0 --- 8 ND ND ND ND ND ND ND 5-Nov-19 EPA826OD 0.57 5.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Fr— Analyte Collection Date Method D RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61) Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND INS ND 7.4 J ND ND ND NULL = NE Ng/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.32 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 826OD 3.10 10.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 12.50 20.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 ug/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.97 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 --- ND ND 0.63 J ND ND ND ND ND 5-Nov-19 EPA8260D 3.70 5.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC21- = 4,200 pg/L (10/23/07) 28-Nov-07 NR 100 18.0 JD ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC21- = 4,000 ug/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA826O 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA826O 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA826O 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA826O 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA826O 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA826O 0.96 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA826O 0.96 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA826O 0.96 100 --- 268 ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.96 5 --- ND ND ND ND ND ND ND ND 6-May-19 EPA826OD 3.20 5 --- 448 E3' ND ND ND ND ND ND ND 5-Nov-19 EPA826OD 3.30 5 --- 14.8 ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MM MW-4 MW-5 MW-6S MW-6D Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 --- 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.33 5 --- 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA826OD 0.86 5 --- 311 E3, ND ND ND ND ND ND ND 5-Nov-19 EPA 826OD 4.50 5 --- 11.2 ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND INS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 --- ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 --- ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 --- ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 --- ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA8260D 0.78 1.0 --- ND ND 11.1 ND ND ND ND ND 5-Nov-19 EPA8260D 0.16 1.0 --- ND ND 6.5 1.8 ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC21- = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 INS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND --- 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 --- 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 --- 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 --- 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.26 1.0 --- 0.9 J ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.31 1.0 --- 4.8 ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 --- 1.1 ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND INS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 --- ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 --- ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 --- ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 --- ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA8260D 0.34 1.0 --- ND ND 5.9 ND ND ND ND ND 5-Nov-19 EPA8260D 0.22 1.0 --- ND ND 4.8 0.72 J ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC2L = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC21- = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND INS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 --- ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 --- ND ND 1.2 ND ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 --- ND ND 1.4 ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 --- ND ND ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC2L = 530 Ng/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC2L = 500 Ng/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 INS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 --- 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 --- 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 --- 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.66 1.0 --- 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA8260D 1.50 2.0 --- 55.8 17.7 ND ND ND ND ND ND 5-Nov-19 EPA 8260D 0.63 1.0 --- 22.3 14.3 ND ND ND ND ND --- Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND INS ND ND ND ND ND GWPS = 0.6 pg/L (10/23/07) 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.58 2.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.29 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.59 1.0 --- ND ND ND ND ND ND ND ND 5-Nov-19 EPA8260D 0.24 1.0 --- ND ND ND ND ND ND ND --- Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. INS = Not sampled. NE = Not established. NR = Not reported. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the DENR-SWS for constituents with no listed NC2L standard.. Bold values are greater than the NC2L Groundwater Standards or GWPS. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 41 Labella Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Well Depth [ft] 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25c) 11-Jun-13 233.1 1168.0 847 -- 56.9 14.2 62.8 74.1 [MS/cm] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 -- 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 2185.0 920 875 99 25 97 114 14-May-18 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample--> 8-Feb-19 -- -- -- 55.9 -- -- -- 6-May-19 1923 916 792 59.6 23.3 50.6 85.6 Resample--> 23-Jul-19 -- -- 1454 -- -- -- -- 4-Nov-19 -- 2225 831 853 92.1 18.3 59.3 90 pH 11-Jun-13 5.9 6.1 6.36 -- 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 -- 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample--> 8-Feb-19 -- -- -- 5.64 -- -- -- 6-May-19 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample--> 23-Jul-19 -- -- 6.00 -- -- -- -- 4-Nov-19 -- 5.64 5.94 6.15 5.43 5.49 5.28 5.54 Temperature 11-Jun-13 17.0 17.4 15.2 -- 15.9 16.4 14 15.4 [ ° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 2 0-0 ct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample--> 8-Feb-19 -- -- -- 15.2 -- -- -- 6-May-19 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample--> 23-Jul-19 -- -- 17.3 -- -- -- -- 4-Nov-19 15.1 13 16.4 14.7 15.3 16.4 16.4 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 1 of 2 TABLE A2-3: Historical Groundwater Field Parameters Dissolved Oxygen [mg/L] 6-May-19 23-Jul-19 4-Nov-19 0.92 -- 1.63 3.59 -- 1.85 1.09 0.91 4.39 5.18 -- 3.99 5.73 -- 4.36 5.44 -- 3.55 2.13 -- 2.89 Oxidation Reduction Potential 6-May-19 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 -- -- 210.5 -- -- -- -- 4-Nov-19 -- 33.3 85.4 180.3 199 146.4 208.3 -81.6 Turbidity 11-Jun-13 27.4 4.50 3.65 -- 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 -- 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample--> 8-Feb-19 -- -- -- 7.96 -- -- -- 6-May-19 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample--> 23-Jul-19 -- -- 3.12 -- -- -- -- 4-Nov-19 4.79 9 3.01 35.17 41.15 8.49 30.39 Notes: °C= degrees Centigrade S.U.= Standard Units pS = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet mg/L = milligrams per liter my = millivolts Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 2 of 2 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 28-Jun-95 NR 5 ND ND 10.0 NA 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC2B = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND 6-May-19 5.0 10.0 ND ND 5.2 J ND 5-Nov-19 5.0 10.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.5 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.2 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.8 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.3 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.7 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 2.5 100 38.1 J 38.0 J 301 2.5 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 2.5 5 33.1 32.0 267 ND 6-May-19 2.5 5 26.4 26.2 239 ND 5-Nov-19 2.5 5 34.5 35.9 34.8 -- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 1.0 1.0 ND ND ND ND 21-Oct-14 1.0 1.0 ND ND ND ND 19-May-15 0.5 1.0 ND ND Dry NA 7-Dec-15 0.5 1.0 ND ND ND ND 2-May-16 0.5 1.0 ND ND ND ND 12-Dec-16 0.5 1.0 ND ND NS ND 26-Jun-17 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 0.5 1.0 ND ND ND ND 4-Dec-18 0.5 1.0 ND ND ND ND 6-May-19 0.5 1.0 ND ND ND ND 5-Nov-19 0.5 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.0 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 5.0 10.0 ND ND 6.3 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.3 J ND 2-May-16 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 2.8 J ND 6-May-19 2.5 5.0 ND ND 4.4 J ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC2B = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 6.0 J ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND 9.6 J INS ND 26-Jun-17 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 3.6 J ND 6-May-19 2.5 5.0 ND ND 4.2 J ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 5.0 10.0 ND ND 6.4 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.0 J ND 2-May-16 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 4.1 J ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 N D N D 4.6 B 2.2 J NC2B = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 5.0 50.0 ND ND 10.4 J ND 19-May-15 2.5 50.0 ND ND Dry NA 7-Dec-15 2.5 50.0 ND ND 5.1 J ND 2-May-16 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 2.5 50.0 ND ND INS ND 26-Jun-17 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 2.5 50.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 5.9 ND 6-May-19 2.5 5.0 ND ND 6.3 ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC2B = 5 pg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND ND ND 21-Oct-14 10.0 10.0 ND ND ND ND 19-May-15 5.0 10.0 ND ND Dry NA 7-Dec-15 5.0 10.0 ND ND ND ND 2-May-16 5.0 10.0 ND ND ND ND 12-Dec-16 5.0 10.0 ND ND INS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND 6-May-19 5.0 10.0 ND ND ND ND 5-Nov-19 5.0 10.0 ND ND ND --- Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC2B = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND INS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND 5-Nov-19 2.5 5.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 0.1 0.1 ND ND 0.077 J --- 6-May-19 0.1 0.1 ND ND 0.11 ND 5-Nov-19 0.1 0.1 ND ND ND --- Vanadium 19-Nov-03 NR 40.0 62 56 60 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC2B = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8.0 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 5.0 25.0 ND ND ND ND 21-Oct-14 5.0 25.0 ND ND ND ND 19-May-15 2.5 25.0 ND ND Dry NA 7-Dec-15 2.5 25.0 ND ND ND ND 2-May-16 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 2.5 25.0 ND ND NS ND 26-Jun-17 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 2.5 25.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND 5-Nov-19 1.3 5.0 1.4 J 1.5 J 1.5 J --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13.0 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND 10.3 ND 21-Oct-14 10.0 10.0 ND ND 18.0 ND 19-May-15 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND 7.4 J ND 6-May-19 5.0 10.0 ND ND ND ND 5-Nov-19 5.0 10.0 ND ND ND --- Beryllium 5-Nov-19 0.2 1.0 ND 0.24 J ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 10.0 100 ND ND 17.6 J ND 21-Oct-14 10.0 100 ND ND ND ND 19-May-15 10.0 100 ND ND Dry NA 7-Dec-15 10.0 100 ND ND ND ND 2-May-16 10.0 100 ND ND ND ND 12-Dec-16 10.0 100 ND ND NS ND 26-Jun-17 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 10.0 100 ND ND ND ND 4-Dec-18 10.0 25 ND ND ND ND 6-May-19 8.2 25 ND ND ND ND 5-Nov-19 6.2 25 ND ND ND --- Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 pg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 0.25 1.0 ND ND ND ND 21-Oct-14 0.25 1.0 ND ND ND ND 19-May-15 0.25 1.0 ND ND Dry NA 7-Dec-15 0.25 1.0 ND ND ND ND 2-May-16 0.25 1.0 ND ND ND ND 12-Dec-16 0.25 1.0 ND ND NS ND 26-Jun-17 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 0.25 1.0 ND ND ND ND 4-Dec-18 0.25 1.0 ND ND ND ND 6-May-19 0.20 1.0 ND ND ND ND 5-Nov-19 0.15 1.0 ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 0.29 10.0 ND ND 0.41 J ND 19-May-15 0.29 10.0 ND ND Dry NA 7-Dec-15 0.29 10.0 ND ND ND ND 2-May-16 0.29 10.0 ND ND ND ND 12-Dec-16 0.29 10.0 ND ND NS ND 26-Jun-17 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 0.29 10.0 ND ND ND ND 4-Dec-18 0.29 2.0 ND ND ND ND 6-May-19 0.95 2.0 ND ND 1.5 J ND 5-Nov-19 0.62 2.0 ND ND ND --- Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 0.23 3.0 ND ND ND ND 21-Oct-14 0.23 3.0 ND ND ND ND 19-May-15 0.23 3.0 ND ND Dry NA 7-Dec-15 0.23 3.0 ND ND ND ND 2-May-16 0.23 3.0 ND ND ND ND 12-Dec-16 0.23 3.0 ND ND NS ND 26-Jun-17 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 0.23 3.0 ND ND ND ND 4-Dec-18 0.23 1.0 ND ND ND ND 6-May-19 0.53 1.0 ND ND ND ND 5-Nov-19 0.23 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 0.11 1.0 ND ND ND ND 21-Oct-14 0.11 1.0 ND ND 0.19 J ND 19-May-15 0.11 1.0 ND ND Dry NA 7-Dec-15 0.11 1.0 ND ND ND ND 2-May-16 0.11 1.0 ND ND ND ND 12-Dec-16 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 0.11 1.0 ND ND ND ND 4-Dec-18 0.11 1.0 ND ND ND ND 6-May-19 0.38 1.0 ND ND ND ND 5-Nov-19 0.39 1.0 ND ND ND --- 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 0.30 5.0 ND ND ND ND 21-Oct-14 0.30 5.0 ND ND ND ND 19-May-15 0.30 5.0 ND ND Dry NA 7-Dec-15 0.30 5.0 ND ND ND ND 2-May-16 0.30 5.0 ND ND ND ND 12-Dec-16 0.30 5.0 ND ND NS ND 26-Jun-17 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 0.30 5.0 ND ND ND ND 4-Dec-18 0.30 1.0 ND ND ND ND 6-May-19 0.49 1.0 ND ND ND ND 5-Nov-19 0.29 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 0.33 1.0 ND ND ND ND 21-Oct-14 0.33 1.0 ND ND ND ND 19-May-15 0.33 1.0 ND ND Dry NA 7-Dec-15 0.33 1.0 ND ND ND ND 2-May-16 0.33 1.0 ND ND ND ND 12-Dec-16 0.33 1.0 ND ND NS ND 26-Jun-17 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 0.33 1.0 ND ND ND ND 4-Dec-18 0.33 1.0 ND ND ND ND 6-May-19 0.58 1.0 ND ND ND ND 5-Nov-19 0.26 1.0 ND ND ND --- 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NC2B = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 0.32 5.0 ND ND ND ND 21-Oct-14 0.32 5.0 ND ND ND ND 19-May-15 0.32 5.0 ND ND Dry NA 7-Dec-15 0.32 5.0 ND ND ND ND 2-May-16 0.32 5.0 ND ND ND ND 12-Dec-16 0.32 5.0 ND ND NS ND 26-Jun-17 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 0.32 5.0 ND ND ND ND 4-Dec-18 0.32 1.0 ND ND ND ND 6-May-19 0.41 1.0 ND ND ND ND 5-Nov-19 0.27 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 0.19 5.0 ND ND ND ND 21-Oct-14 0.19 5.0 ND ND ND ND 19-May-15 0.19 5.0 ND ND Dry NA 7-Dec-15 0.19 5.0 ND ND ND ND 2-May-16 0.19 5.0 ND ND ND ND 12-Dec-16 0.19 5.0 ND ND NS ND 26-Jun-17 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 0.19 5.0 ND ND ND ND 4-Dec-18 0.19 1.0 ND ND ND ND 6-May-19 0.66 1.0 ND ND ND ND 5-Nov-19 0.29 1.0 ND ND ND --- 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 0.27 1.0 ND ND ND ND 21-Oct-14 0.27 1.0 ND ND ND ND 19-May-15 0.27 1.0 ND ND Dry NA 7-Dec-15 0.27 1.0 ND ND ND ND 2-May-16 0.27 1.0 ND ND ND ND 12-Dec-16 0.27 1.0 ND ND NS ND 26-Jun-17 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 0.27 1.0 ND ND ND ND 4-Dec-18 0.27 1.0 ND ND ND ND 6-May-19 0.60 1.0 ND ND ND ND 5-Nov-19 0.19 1.0 ND ND ND --- 1,4-Dioxane (p-Dioxane) 4-Dec-18 1.90 2.0 ND ND 10.5 ND 6-May-19 1.20 2.0 ND ND 7.6 ND 5-Nov-19 1.20 2.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 0.46 1.0 ND ND ND ND 21-Oct-14 0.46 1.0 ND ND ND ND 19-May-15 0.46 1.0 ND ND Dry NA 7-Dec-15 0.46 1.0 ND ND ND ND 2-May-16 0.46 1.0 ND ND ND ND 12-Dec-16 0.46 1.0 ND ND NS ND 26-Jun-17 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 0.46 1.0 ND ND ND ND 4-Dec-18 0.46 1.0 ND ND ND ND 6-May-19 0.78 1.0 ND ND ND ND 5-Nov-19 0.16 1.0 ND ND ND --- Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 0.47 1.0 ND ND ND ND 21-Oct-14 0.47 1.0 ND ND ND ND 19-May-15 0.47 1.0 ND ND Dry NA 7-Dec-15 0.47 1.0 ND ND ND ND 2-May-16 0.47 1.0 ND ND ND ND 12-Dec-16 0.47 1.0 ND ND NS ND 26-Jun-17 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 0.47 1.0 ND ND ND ND 4-Dec-18 0.47 1.0 ND ND ND ND 6-May-19 0.34 1.0 ND ND ND ND 5-Nov-19 0.22 1.0 ND ND ND --- Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND INS INS ND NC213 = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 0.62 1.0 ND ND ND ND 21-Oct-14 0.62 1.0 ND ND ND ND 19-May-15 0.62 1.0 ND ND Dry NA 7-Dec-15 0.62 1.0 ND ND ND ND 2-May-16 0.62 1.0 ND ND ND ND 12-Dec-16 0.62 1.0 ND ND INS ND 26-Jun-17 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 0.62 1.0 ND ND ND ND 4-Dec-18 0.62 1.0 ND ND ND ND 6-May-19 0.60 1.0 ND ND ND ND 5-Nov-19 0.24 1.0 ND ND ND --- Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. NS = Not sampled. NE = Not established. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). Dry = Surface water point was considered to be dry and no sample collected. NC213 = 15A NCAC 2B Surface Water Standards. Bold values are greater than the NC2B. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 18 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25c) 11-Jun-13 54.4 63.2 655 [MS/CM] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 4-Nov-19 78 92.4 80.9 pH 11-Jun-13 7.8 8.25 7.81 [S.U.] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 6.60 6.98 7.92 4-Nov-19 6.60 6.78 6.63 Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 1 of 2 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-Oct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 4-Nov-19 10.07 10.6 10.7 Dissolved Oxygen 6-May-19 5.89 6.14 5.93 (mg1L) 4-Nov-19 7.23 6.56 7.27 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 (mV) 4-Nov-19 147.6 43.4 99.9 Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-May-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 4-Nov-19 11.6 10.4 10.0 Notes: °C= degrees Centigrade S.U.= Standard Units my = millivolts pS/cm = microSemens per centimeter NTU = Nephelometric Turbidity Units mg/L - milligrams per liter Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 Page 2 of 2