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HomeMy WebLinkAbout8103_8105_Rutherford_CDLF_Permit_GWAReport_FID1389606_20200112REPORT OF GROUNDWATER
ASSESSMENT
JANUARY 2020
RUTHERFORD COUNTY LANDFILL
RUTHERFORDTON, NORTH CAROLINA
C&D Landfill — Phase 2 Expansion
Permit No. 8103-CDLF-2002
Prepared For:
Rutherford County Solid Waste Dept.
Rutherfordton, North Carolina
BLE Project Number J20-13675-04
February 7, 2020
x
_ SEAL
1043
111(410%
BLE North Carolina Business Licenses C-284 & C-1538
IM 13UNNELL
LAMMONS
ENGINEERING
6004 Ponders Court I Greenville, 5C 29615
864.288.1265 A 864.286.4330 a info@ble[orp.rom
BLECORMOM
91JNNELL
� CANNONS
ENGINEERING
February 7, 2020
Solid Waste Section
Division of Waste Management
NCDEQ-ARO
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Attention: Ms. Jaclynne Drummond, Hydrogeologist
Subject: Report of Groundwater Assessment — January 2020
Background for the Phase 2 C&D Expansion Area
Rutherford County Landfill, Permit #8103-CDLF-2002
Rutherford County, North Carolina
BLE Project No. J20-13675-04
Dear Ms. Drummond:
Bunnell-Lammons Engineering, Inc. (BLE) is pleased to submit this report to the North Carolina Division of
Waste Management (NCDWM) Solid Waste Section (SWS) for the Phase 2 construction and demolition
(C&D) landfill expansion area on behalf of Rutherford County, Odom Engineering, PLLC (Odom), and
McGill Associates (McGill). The report addresses the groundwater assessment activities required by the SWS
in support of the permit application (in progress) for the Phase 2 C&D landfill expansion.
Sincerely,
BUNNELL LAMMONs ENGINEERING INC.
acl
Andrew W 1evqyder P
Chief H
Registe
CC:
ydrogeologist �,•■' ERR
red, NC No. 1475■�+``�p�'� GE �SrJ9
ter
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►,1«sal
Mr. James Kilgo - Rutherford County
Mr. Pete Dickerson, P.E. - Odom
Mr. Mark Cathey, P.E. - McGill
*tvl -'
Mark S. Preddy, P.G.
Chief Hydrogeologist 11 f 1 f 1
Registered, NC No ' r�
SEAL
1043
IV —' ww�
/111NtiI
6004 Ponders Court, Greenville, SC 29615 (,864.288.1265 a 864.288.4430 Wg info@hleMrp.com
BLECORP.COM
1s 1m 1i
Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
TABLE OF CONTENTS
1.0
PROJECT INFORMATION........................................................................................................1
2.0
SCOPE OF SERVICES PERFORMED......................................................................................2
3.0
RESULTS.......................................................................................................................................
3
3.1
Groundwater Levels and Flow Direction.........................................................................................
3
3.2
Laboratory Analyses........................................................................................................................
3
4.0
CONCLUSIONS AND RECOMMENDATIONS
....................................................................... 4
4.1
Groundwater Levels and Flow Direction.........................................................................................
4
4.2
Laboratory Analyses........................................................................................................................
4
5.0
QUALIFICATIONS OF REPORT..............................................................................................
5
6.0
CLOSING.......................................................................................................................................5
Tables
Table 1 Groundwater Elevations and Well Data
Table 2 Background Sampling Matrix — Water Quality
Table 3 Metals List — Background Sampling
Table 4 Volatile Organic Compounds (VOC) Data (January 2020)
Table 5 Alkalinity, Chloride, Sulfate, Total Dissolved Solids, & Field Parameters (January 2020)
Table 6 Total & Dissolved Metals Data (January 2020)
Figures
Figure 1 Groundwater Elevation Contour Map — January 21, 2020
Appendices
Appendix A Field Sampling Logs
Appendix B Laboratory Analytical Data
Appendix C Figure 2 and Tables from the May 2018 Semi -Annual Sampling Report by Scarlett
Geophysical Consulting P.C.
Appendix D Figure 2 and Tables from the October 2018 Semi -Annual Sampling Report by Scarlett
Geophysical Consulting P.C.
Appendix E Figure 2 and Tables from the May 2019 Semi -Annual Sampling Report by Scarlett
Geophysical Consulting P.C.
iofi
1s 1m 1i
Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
1.0 PROJECT INFORMATION
The project information below was obtained from multiple in -person and telephone meetings and emails
between BLE, McGill, Odom, Rutherford County, and the SWS.
The subject landfill site is located in Rutherford County, North Carolina, between the cities of
Rutherfordton and Spindale with a physical address of 656 Laurel Hill Dr, Rutherfordton, North Carolina.
Rutherford County owns and operates a closed Subtitle D municipal solid waste (MSW) landfill and an
active C&D landfill consisting of one waste unit designated Phase 1. The county plans to expand the C&D
landfill in an area designated Phase 2 which is approximately 17 acres and construct one new approximate
5.5-acre C&D waste unit in the expansion area.
Rutherford County has retained McGill as design and permitting engineer for the project. Rutherford County
has also retained BLE (as a subconsultant to McGill) to provide design hydrogeologic services, geotechnical
engineering, monitoring plan services, and construction quality control services for the project. Work on the
project has begun. McGill has defined the limits of the expansion area and developed a conceptual design
plan. BLE has performed six (6) borings and installed five (5) piezometers in the expansion area as part of
the design hydrogeologic report (DHR).
Several discussions with the SWS occurred after the DHR work started. The SWS expressed concern about
development of a new waste unit in the expansion area due to an ongoing assessment of corrective measures
(performed by others) for the existing C&D and MSW waste units. As a result, the SWS informed Rutherford
County, McGill, and BLE that they will require a background assessment of the groundwater quality in the
expansion area as a condition of the permitting process for Phase 2.
BLE prepared a work plan to perform the required sampling, analysis, data evaluation, and reporting for the
background assessment and submitted the document to the SWS on January 16, 2020 (FID 1387733). The
SWS approved the plan on January 17, 2020 (FID 1387736).
The SWS approved plan included two sampling events to be conducted 30 days apart. This report documents
the results and findings of the first sampling event conducted on January 21-22, 2020.
1 of 5
1s 1M 1i
Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
2.0 SCOPE OF SERVICES PERFORMED
BLE personnel collected water levels from selected wells on January 21, 2020. The water level data is shown
on Table 1. A groundwater elevation map was prepared from the data (Figure 1).
BLE personnel conducted groundwater sampling of the eight (8) wells identified on the Tables 2 and 3. The
wells were purged and sampled within 24 hours of purging. We attempted to purge three (3) well volumes.
Less than three well volumes were purged for low yield wells. Efforts were made to reduce sample turbidity
during sampling to reduce the potential for false -positive metals results. Sampling logs were prepared for
each well sampled (Appendix A).
BLE submitted the groundwater samples to a North Carolina certified laboratory (Pace Analytical Services,
Inc. — Columbia [dba Shealy Environmental]) for analysis via laboratory courier. The laboratory performed
the analyses indicted on the matrix (Tables 2 and 3). Field parameters were measured in the field by BLE
during sampling and reported on the field sampling logs. The laboratory analysis reports are included in
Appendix B.
2 of 5
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Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
3.0 RESULTS
3.1 Groundwater Levels and Flow Direction
BLE prepared a groundwater elevation contour map for January 21, 2020 to illustrate groundwater flow
direction at the site (Figure 1). The data indicates that the groundwater flow direction in January 2020 is
consistent with that observed in November 2019 (shown in the work plan) and is primarily southwesterly
through the Phase 2 expansion area.
3.2 Laboratory Analyses
The laboratory and field analysis data has been summarized on Tables 4, 5, and 6. Table 4 summarizes the
volatile organic compound (VOC) results. Table 5 summarizes the inorganic and field parameter analyses.
Table 6 summarizes the total and dissolved metals analysis. The North Carolina Groundwater Quality
Standards (NC2L) promulgated in the North Carolina Rules for Environmental Management - Groundwater
Classification and Standards, [Rules] T15A NCAC 02L .0202 are included on the tables. The NC2L
groundwater standards (aka Maximum Contaminant Level [MCLs]) are utilized for regulatory compliance.
The North Carolina Interim Maximum Allowable Concentrations (IMACs) are also included on the summary
tables and are provided for reference only.
The VOC data on Table 4 indicates that no concentrations of Appendix II VOCs (except carbon disulfide in
B-42), tetrahydrofuran, or 1,4-dioxane were detected in the groundwater samples. The concentration of
carbon disulfide detected in B-42 (1.0 µg/L) does not exceed the NC2L standard of 700 µg/L.
The data on Table 5 indicates that none of the inorganic parameters analyzed in the laboratory exceed their
NC2L standards, if established. The data indicates that the pH field parameter was outside the range of NC2L
standard limits of 6.5 to 8.5 in LFG-6 (6.48) and B-41 (6.20).
The total and dissolved metals data on Table 6 indicates that concentrations of two (2) metals exceed their
NC2L standards. These metals included iron and manganese. Laboratory analyses detected concentrations of
total iron in LFG-7 (350 µg/L) and B-42 (1,300 µg/L). These detected concentrations of total iron exceed the
applicable NC2L standard of 300 µg/L. Laboratory analyses detected concentrations of total and/or dissolved
manganese in B-40D (150 µg/L, for both total and dissolved), B-42 (58 µg/L, total), and B-44 (total 310 µg/L
and dissolved 320 µg/L). These detected concentrations of manganese exceed the applicable NC2L standard
of 50 µg/L.
3 of 5
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Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
4.0 CONCLUSIONS AND RECOMMENDATIONS
4.1 Groundwater Levels and Flow Direction
The groundwater flow direction through the Phase 2 expansion area (Figure 1) appears similar to that
observed by BLE in 2019 and is also similar to that observed in the historical semi-annual groundwater
monitoring reports prepared by Scarlett Geophysical Consulting, P.C. (SGC). Copies of the groundwater
contour maps and summary tables from the SGC semi-annual reports for May 2018 (Appendix C), October
2018 (Appendix D), and May 2019 (Appendix E) are included for reference. These documents were sourced
from facility records. These data include water levels for each event on the Summary of Monitoring Well
Data (Table 1) and the Groundwater Contour Map (Figure 2) of each resource. We conclude that the water
levels and groundwater flow direction in January 2020 are fundamentally compliant with those shown in the
work plan and are acceptable for execution of the plan without changes.
4.2 Laboratory Analyses
We conclude that the laboratory and field analysis data collected during the January 2020 event do not provide
evidence that the groundwater in the Phase 2 area has been impacted by a contaminant release. The findings
for each parameter are discussed below.
The carbon disulfide detected in B-42 (1.0 µg/L) does not exceed the NC2L standard of 700 µg/L (Table 5)
and is detected at the level of quantitation (LOQ) of 1.0 µg/L for the laboratory analytical method. Therefore,
it is possible that the result is a false positive. Additionally, it is noted that concentrations of carbon disulfide
are routinely detected as naturally occurring compounds in groundwater sourced from the degradation of
organic materials. We conclude that the groundwater in the Phase 2 expansion area has not been impacted by
a VOC release.
The pH field parameter was outside the range of NC2L standard limits of 6.5 to 8.5 in LFG-6 (6.48) and B-41
(6.20) [Table 5]. However, these pH values are typical for the pH values observed in groundwater in the
region. For example, the pH values observed during the last three reported semi-annual sampling events and
documented on the Ground and Surface Water Sampling Field Data (Table 2) in Appendices C through D
indicate that the pH values in the groundwater monitoring wells range from 4.59 to 9.47. We conclude that the
out of range pH values observed in LFG-6 and B-41 in January 2020 are indicative of naturally occurring
groundwater chemistry. None of the other field or laboratory parameter results summarized on Table 5 provide
evidence of a contaminant release.
The metals iron and manganese exceed their NC2L standards at various sampling locations in the Phase 2
expansion area (Table 6). It's noted that the SWS's primary concern for potential contaminant impacts in the
Phase 2 area was related to the disposal (and subsequent remediation by removal) of alum sludge. We
understand that concentrations of aluminum have been detected in groundwater monitoring MW-14 and MW-
15 which have been suspected of being sourced from the sludge. It's noted that the SWS has not established a
groundwater standard for aluminum (Table 6).
Summary tables of metals detected in groundwater are included in the historical semi-annual groundwater
monitoring reports prepared by SGC. Those metals data include Tables 3, 5, 6, 11, 12, & 17 from May 2018
(Appendix C), Tables 3, 5, 6, 7, 12, & 17 from October 2018 (Appendix D), and Tables 3, 5, 6, 11, 12, & 17
from May 2019 (Appendix E).
4 of 5
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Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020
Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04
These historical data indicate that concentrations of metals have been detected in the facility groundwater
monitoring network which are similar to that observed in the Phase 2 expansion area. Specifically, the
concentrations of iron and manganese observed in the Phase 2 area appear to be in the range of the
concentrations observed in the facility monitoring network where no release of metals has been documented.
Additionally, the concentrations of aluminum observed in the Phase 2 area are much lower than those
observed in MW-14 and MW-15 in May 2018 (Appendix C). We conclude that the data from the January
2020 groundwater sampling event do not indicate that there has been a release of metals in the Phase 2
expansion area.
We recommend that groundwater sampling and analysis continue per the SWS approved work plan. The next
event is scheduled for approximately February 24, 2020.
5.0 QUALIFICATIONS OF REPORT
The activities and evaluative approaches used in this assessment are consistent with those normally employed
in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been
based on our understanding of the site and project information and the data obtained in our exploration.
This report has been prepared on behalf of and exclusively for the use of Rutherford County, North Carolina.
This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other
party (excluding the SWS) without BLE's prior written consent.
6.0 CLOSING
We appreciate the opportunity to be of service to Rutherford County. Please contact us at (864) 288-1265 if
you have any questions or comments.
5of5
Tables
Table 1
Groundwater Elevations and Well Data
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
Wen
Well
Location
Northing
(feet)
Easting
(feet)
Lat. North
(dd)
Long. West
(dd)
Top Casing
Elevation
Gad. Surface
Elevation
Depth to GW
(feet - btoc)
Groundwater
Elevation
Screen
Depth (bgs)
Screen
Elevation
Well Total Well
Monitors Depth (bgs)
Top of Rock Top of
Depth (bgs) Rock Elev.
MW-1
Outside
596,114.73
1,120,714.40
35.35204161
-81.94932162
1,007.76
1,006.05
51.31
956.45
35.5 - 45.5
970.5 - 960.5
Soil/PWR
45.5
45.5
960.5
MW-2
Outside
596,355.31
1,119,904.89
35.35263626
-81.95205930
994.86
994.47
37.56
957.30
50.0 - 60.0
944.5 - 934.5
Soil
60.0
NE
NE
MW-3
Outside
DNA
DNA
DNA
DNA
860.28
859.62
NM
NM
37.0 - 47.0
822.6 - 812.6
Soil
47.0
NE
NE
MW4
Outside
DNA
DNA
DNA
DNA
851.03
849.72
NM
NM
40.0 - 50.0
809.7 - 799.7
Soil
50.0
NE
NE
MW-5
Outside
DNA
DNA
DNA
DNA
DNA
DNA
NM
NM
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
MW-6
Outside
DNA
DNA
DNA
DNA
834.90
833.43
NM
NM
22.5 - 37.5
810.9 - 795.9
Soil/PWR
37.5
38.0
795.4
MW-7
Outside
DNA
DNA
DNA
DNA
892.70
890.51
NM
NM
39.0 - 54.0
851.5 - 836.5
PWR/BR
54.0
30.0
860.5
MW-8
Outside
DNA
DNA
DNA
DNA
860.31
857.86
NM
NM
29.5 - 44.5
828.4 813.4
Soil
44.5
NE
NE
MW-9
Outside
DNA
DNA
DNA
DNA
867.25
864.97
NM
NM
22.5 - 37.5
842.5 - 827.5
Soil
37.5
NE
NE
MW-10A
Outside
DNA
DNA
DNA
DNA
837.23
834.73
NM
NM
91.0 - 101.0
743.7 - 733.7
BR
101.0
39.0
795.7
MW-10B
Outside
DNA
DNA
DNA
DNA
836.15
834.50
NM
NM
32.0 - 37.0
802.5 - 797.5
Soil/PWR
37.0
39.0
795.5
MW-10C
Outside
DNA
DNA
DNA
DNA
836.19
834.50
NM
NM
11.0 - 16.0
823.5 - 818.5
Soil
16.0
39.0
795.5
MW-lOD
Outside
DNA
DNA
DNA
DNA
837.23
834.73
NM
NM
56.0 - 66.0
778.7 768.7
BR
66.0
39.0
795.7
MW-11A
Outside
DNA
DNA
DNA
DNA
817.18
815.39
NM
NM
35.0 - 45.0
780.4 - 770.4
PWR/BR
45.0
36.0
779.4
MW-11B
Outside
DNA
DNA
DNA
DNA
817.72
816.32
NM
NM
10.0 - 20.0
806.3 796.3
Soil
20.0
36.0
780.3
MW-12 (B-22)
Outside
DNA
DNA
DNA
DNA
886.68
884.33
NM
NM
35.5 - 45.5
848.8 - 838.8
Soil/PWR
45.5
45.5
838.8
MW-13 (B-6)
Outside
594,988.71
1,120,032.88
35.34889347
-81.95149400
962.47
960.35
77.90
884.57
73.0 - 88.0
887.3 - 872.3
BR
88.0
65.0
895.3
MW-14
Outside
595,446.06
1,118,985.16
35.35006391
-81.95505174
868.94
866.54
20.74
848.20
17.4 - 32.4
849.1 - 834.1
DNA
32.4
DNA
DNA
MW-15 (B-29)
Outside
595,672.95
1,118,986.20
35.35068714
-81.95507090
889.13
887.52
27.61
861.52
28.0 - 38.0
859.5 - 849.5
BR
38.0
26.0
861.5
LFG-6(B-13)
Inside
595,955.90
1,119,501.27
35.35150632
-81.95337249
941.81
939.68
17.55
924.26
21.0 - 31.0
918.7 - 908.7
BR
31.0
1.0
938.7
LFG-7 (B-17)
Inside
596,091.76
1,119,401.05
35.35187127
-81.95372202
963.14
960.89
35.87
927.27
40.0 - 50.0
920.9 - 910.9
BR
50.0
34.0
926.9
LFG-8 (B-12S)
Outside
596,098.89
1,120,135.92
35.35195090
-81.95125927
972.53
970.56
18.10
954.43
23.0 - 33.0
947.6 - 937.6
Soil
33.0
NE
NE
LFG-8A(B-12D)
Outside
596,099.74
1,120,129.76
35.35195271
-81.95128000
972.23
971.12
26.20
946.03
94.0 - 104.0
877.1 - 867.1
BR
104.0
74.0
897.1
LFG-9
Outside
596,979.03
1,120,087.63
35.35436417
-81.95150888
992.20
988.32
DRY
DRY
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
LFG-10
Outside
596,108.37
1,120,128.56
35.35197633
-81.95128489
975.07
971.36
DRY
DRY
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
LFG-II
Outside
596,417.18
1,119,314.26
35.35275789
-81.95404542
980.37
977.53
DRY
DRY
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
PZ-A
Outside
DNA
DNA
DNA
DNA
DNA
DNA
NM
NM
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
PZ-B
Outside
DNA
DNA
DNA
DNA
DNA
DNA
NM
NM
DNA - DNA
DNA - DNA
DNA
DNA
DNA
DNA
B-1
Outside
DNA
DNA
DNA
DNA
1,049.56
1,047.38
NM
NM
68.0 - 78.0
979.4 - 969.4
BR
78.0
42.0
1,005.4
B-2
Outside
DNA
DNA
DNA
DNA
1,007.84
1,005.62
NM
NM
55.0 - 65.0
950.6 - 940.6
PWR
65.0
NE
NE
B-3
Outside
DNA
DNA
DNA
DNA
964.99
961.74
NM
NM
58.0 - 68.0
903.7 - 893.7
PWR
68.5
68.5
893.2
B-4
Outside
DNA
DNA
DNA
DNA
989.58
987.89
NM
NM
65.0 - 75.0
922.9 - 912.9
PWR
75.0
NE
NE
B-5S
Outside
595,535.35
1,120,260.97
35.35041341
-81.95078391
928.29
926.87
13.36
914.93
18.0 - 28.0
908.9 - 898.9
Soil
28.0
NE
NE
B-51)
Outside
595,537.71
1,120,255.16
35.35041939
-81.95080362
929.48
927.07
13.37
916.11
41.0 - 51.0
886.1 876.1
BR
51.0
34.0
893.1
B-7
Outside
DNA
DNA
DNA
DNA
929.94
927.41
NM
NM
57.0 - 67.0
870.4 - 860.4
PWR/BR
65.0
65.0
862.4
B-8
Outside
DNA
DNA
DNA
DNA
918.95
916.46
NM
NM
58.0 - 68.0
858.5 - 848.5
Soil
74.0
74.0
842.5
B-9S
Outside
DNA
DNA
DNA
DNA
862.07
860.05
NM
NM
20.0 - 30.0
840.1 - 830.1
Soil
43.6
43.6
816.5
B-913
Outside
DNA
DNA
DNA
DNA
862.12
860.18
NM
NM
61.0 - 71.0
799.2 789.2
BR
72.0
43.5
816.7
B-10
Outside
596,444.04
1,120,317.76
35.35291367
-81.95068409
1,021.02
1,018.72
56.00
965.02
70.0 - 80.0
948.7 - 938.7
BR
80.0
48.5
970.2
B-11
Outside
DNA
DNA
DNA
DNA
1,016.01
1,015.07
NM
NM
50.0 - 60.0
965.1 955.1
PWR
60.0
NE
NE
B-14
Outside
DNA
DNA
DNA
DNA
972.50
971.17
NM
NM
21.0 - 100.0
950.2 - 871.2
Open BR
100.0
21.0
950.2
B-15
Outside
DNA
DNA
DNA
DNA
899.84
897.55
NM
NM
24.0 - 34.0
873.6 - 863.6
BR
34.0
11.0
886.6
B-16S
Outside
595,956.62
1,118,692.59
35.35144218
-81.95608345
857.04
854.96
11.58
845.46
18.0 - 28.0
837.0 - 827.0
Soil
28.0
28.0
827.0
B-16D
Outside
595,950.84
1,118,692.17
35.35142627
-81.95608429
856.95
854.97
11.31
845.64
42.0 - 52.0
813.0 - 803.0
BR
52.0
34.0
821.0
B-19
Outside
596,711.81
1,119,761.02
35.35360358
-81.95257715
962.02
959.99
17.20
944.82
48.0 - 58.0
912.0 - 902.0
Soil
65.0
65.0
895.0
B-20
Outside
596,020.52
1,119,045.38
35.35164654
81.95490720
899.56
897.60
25.28
874.28
23.0 - 33.0
874.6 - 864.6
Soil/PWR/BR
33.0
27.0
870.6
B-21
Outside
DNA
DNA
DNA
DNA
932.22
930.04
NM
NM
40.0 - 50.0
890.0 - 880.0
BR
50.0
5.0
925.0
B-23
Outside
595,969.15
1,120,391.19
35.35161542
-81.95039060
1,001.66
999.37
51.90
949.76
61.0 - 71.0
938.4 - 928.4
Soil/PWR
73.6
73.6
925.8
B-24
Outside
DNA
DNA
DNA
DNA
1,047.64
1,045.54
NM
NM
61.0 - 71.0
984.5 - 974.5
BR
71.0
40.5
1,005.0
B-25
Outside
DNA
DNA
DNA
DNA
954.41
951.46
NM
NM
40.0 - 50.0
911.5 - 901.5
Soil/PWR
50.0
50.0
901.5
B-26S
Outside
597,214.05
1,119,896.59
35.35499400
-81.95217277
949.55
947.63
12.43
937.12
25.0 - 35.0
922.6 - 912.6
Soil
35.0
NE
NE
B-26D
Outside
597,207.53
1,119,892.86
35.35497579
-81.95218462
949.85
947.52
12.51
937.34
76.0 - 86.0
871.5 - 861.5
BR
86.0
54.0
893.5
B-27
Outside
DNA
DNA
DNA
DNA
929.27
927.96
NM
NM
5.0 - 7.0
923.0 - 921.0
Soil
7.0
NE
NE
B-28
Outside
DNA
DNA
DNA
DNA
858.16
857.31
NM
NM
2.0 - 4.0
855.3 - 853.3
Soil
4.0
NE
NE
B-29
Outside
DNA
DNA
DNA
DNA
889.54
887.58
NM
NM
28.0 - 38.0
859.6 - 849.6
BR
40.0
26.0
861.6
B-30S
Outside
DNA
DNA
DNA
DNA
896.62
894.78
NM
NM
13.0 - 23.0
881.8 - 871.8
Soil
23.0
NE
NE
B-30D
Outside
DNA
DNA
DNA
DNA
896.54
894.69
NM
NM
30.0 - 40.0
864.7 - 854.7
BR
72.0
24.0
870.7
B-31
Outside
596,878.95
1,120,001.94
35.35408229
-81.95178619
1,002.65
1,000.80
48.91
953.74
61.0 - 71.0
939.8 - 929.8
PWR
72.0
72.0
928.8
B-32
Outside
DNA
DNA
DNA
DNA
978.51
975.98
NM
NM
63.0 - 73.0
913.0 - 903.0
BR
73.0
53.6
922.4
B-33
Inside
DNA
DNA
DNA
DNA
924.80
923.48
NM
NM
14.0 - 24.0
909.5 - 899.5
Soil/PWR
24.0
24.0
899.5
B-34
Outside
DNA
DNA
DNA
DNA
929.79
928.61
NM
NM
57.0 - 67.0
871.6 - 861.6
BR
67.0
40.0
888.6
B-35
Outside
596,673.92
1,119,491.24
35.35347748
-81.95347777
958.54
957.29
33.65
924.89
50.0 - 60.0
907.3 - 897.3
PWR
60.0
60.0
897.3
B-36
Inside
5D84A.29
,1N.63
35.35121025
895248148
4.75
3
0 09
20
20
15.5
929.7
Outside
N
DNA
DNA
91
8.33
NM
1
4
4B-37 0
SIR.
13.0
835.8
B-38
Outside
DNA
DNA
DNA
DNA
847.24
845.20
NM
NM
4.5 6.5
1 840.7 838.7
Soil
6.5
NE
NE
Piezometers B40S/40D through B-44 installed by BLE
B-00S
Inside
595,833.87
1,119,297.50
35.35115453
-81.95404340
915.44
912.40
26.80
888.64
35.8 - 45.8
876.6 - 866.6
BR
46.0
26.0
886.4
B-40D
Inside
595,840.93
1,119,293.66
35.35117361
-81.95405700
915.65
912.92
28.41
887.24
65.8 - 75.8
847.1 - 837.1
BR
76.0
26.0
886.9
B-41
Inside
595,739.81
1,119,415.19
35.35090584
-81.95363951
917.94
914.81
21.87
896.07
24.8 - 34.8
890.0 - 880.0
BR
35.0
22.0
892.8
B-42
Inside
596,039.12
1,119,652.32
35.35174724
-81.95287446
948.78
945.47
13.36
935.42
33.8 - 43.8
911.7 - 901.7
BR
44.0
18.5
927.0
B-44
Inside
595,922.12 1,119,897.37
35.35144591
-81.95204131
955.13
952.21
21.02
934.11
28.8 - 38.8
923.4 913.4
PWR 39.0
39.0 913.2
Notes:
All survey data in RED provided by McGill Associates, all units in feet.
All values shown to the nearest 0.1-ft have been rounded.
All wells installed by Others unless noted otherwise.
Inside = Within or near the boundary of the Phase 2 area
Outside = Outside the boundary of the Phase 2 area
Water levels in BLUE measured on 1/21/2020 by BLE
NM = Not measured
bgs = below ground surface
btoc = below top of casing
Soil =
Soil
PWR
= Partially Weathered Rock
BR =
Bedrock
DNA
= Data Not Available
NE =
Assumed Not Encountered
Well Sampled January 22, 2020
Prepared by: AWA
Table 1 GWM Jan2020 of Tables RCLF Baekgro ind Jm202O.xlsx Checked by: DPO
Table 2
Background Sampling Matrix -- Water Quality
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
2 Events
Station ID
App II VOCs
EPA 8260D
Tetrahydrofuran
EPA 8260D
1,4-Dioxane
EPA 8260D SIM
Total Metals*
Methods 6020B &
7470A
Dissolved Metals*
Methods 6020B &
7470A
Alkalinity
SM 2320B
Chloride
9056A
Sulfate
9056A
Total Dissolved
Solids
SM 2540C-2011
pH
Field
Sp. Cond.
Field
Temp.
Field
B-13 (LFG-6)
X
X
X
X
X
X
X
X
X
X
X
X
B-17 (LFG-7)
X
X
X
X
X
X
X
X
X
X
X
X
B-36
X
X
X
X
X
X
X
X
X
X
X
X
B40S
X
X
X
X
X
X
X
X
X
X
X
X
B-40D
X
X
X
X
X
X
X
X
X
X
X
X
B-41
X
X
X
X
X
X
X
X
X
X
X
X
B-42
X
X
X
X
X
X
X
X
X
X
X
X
B-44
X
X
X
X
X
X
X
X
X
X
X
X
Notes:
* See Table 3 for list of metals
Prepared by: AWA
Checked by: MSP
T2 Sampling Matrix of Tables RCLF Background Jm2020.xlsx
Table 3
Metals List - Background Sampling
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
Metals
Total Aluminum (Al)
Total Lead (Ph)
Dissolved Aluminum (Al)
Dissolved Lead (Pb)
Total Antimony (Sb)
Total Manganese (Mn)
Dissolved Antimony (Sb)
Dissolved Manganese (Mn)
Total Arsenic (As)
Total Mercury (Hg)
Dissolved Arsenic (As)
Dissolved Mercury (Hg)
Total Barium (Ba)
Total Nickel (Ni)
Dissolved Barium (Ba)
Total Beryllium (Be)
Dissolved Beryllium (Be)
Dissolved Nickel (Ni)
Total Selenium (Se)
Dissolved Selenium (Se)
Total Cadmium (Cd)
Total Silver (Ag)
Dissolved Cadmium (Cd)
Dissolved Silver (Ag)
Total Chromium (Cr)
Total Thallium (Tl)
Dissolved Chromium (Cr)
Dissolved Thallium (Tl)
Total Cobalt (Co)
Total Vanadium (V)
Dissolved Cobalt (Co)
Dissolved Vanadium (V)
Total Copper (Cu)
Total Zinc (Zn)
Dissolved Copper (Cu)
Dissolved Zinc (Zn)
Total Iron (Fe)
Dissolved Iron (Fe)
Notes•
Dissolved metals will be laboratory filtered.
Prepared by: AWA
Checked by: MSP
T3 Metals List of Tables RCLF Background Jan202O.xlsx
Table 4
Volatile Organic Compounds (VOC) Data (January 2020)
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
Sampled
by BLE on January 22, 2020 (Shealy Project VA23042)
COMPOUND
UNITS
LOQ
DL
MCL
LFG-6 (B-13)
LFG-7 (B-17)
B-36
B-40S
B-40D
B-41
B-42
B-44
Carbon Disulfide
µg/1
1.0
0.40
700
<0.40
<0.40
<0.40
<0.40
<0.40
<0.40
1.0
<0.40
All Other Appendix II VOCs
µg/1
V
V
V
ND
ND
ND
ND
ND
ND
ND
ND
Tetrahydrofuran
µg/1
5.0
1.0
NE
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
<1.0
1,4-Dioxane
µg/1
1 3.0
1 1.0
3.0
1 <1.0
<1.0
I <1.0
<1.0
I <1.0
I <1.0
I <1.0
I <1.0
Notes:
LOQ = Level of Quantitation
DL = Detection Limit
MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable
to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013
Table 4 VOCs (Jan202O) of Tables RCLF Background Jan202O.xlsx
ND = Not Detected
NE = Not Established; North Carolina has not established a MCL
V = Variable
Samples collected by BLE on January 22, 2020
Analysis by EPA Method 8260D and 8260D (SIM)
Prepared by: AWA
Checked by: IAI
Table 5
Alkalinity, Chloride, Sulfate, Total Dissolved Solids, & Field Parameters (January 2020)
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
Sampled by BLE
on January 22, 2020 (Shealy Project VA23042)
CLASS -- COMPOUND
Method
UNITS
LOQ
DL
MCL
LFG-6 (B-13)
LFG-7 (B-17)
B-36
B-40S
B-40D
B-41
B-42
B-44
Alkalinity
SM 2320B
mg/L
20
20
NE
<20
<20
<20
30
87
30
84
24
Chloride
9056A
mg/L
1.0
0.20
250
2.1
1.9
3.7
3.0
2.3
3.3
8.3
2.5
Sulfate
9056A
mg/L
1.0
0.20
250
<0.20
<0.20
<0.20
5.8
4.9
13
16
<0.20
Total Dissolved Solids
SM 2540C-2011
mg/L
25
25
500
31
47
25
66
130
76
160
50
pH
Field
SU
NA
NA
6.5 to 8.5
6.48
7.61
7.07
7.53
7.44
6.20
7.71
6.93
Specific Conductivity
Field
µmhos/cm
NA
NA
NE
68.32
113.2
40.31
135.9
206.7
144.5
266.4
100.8
Temperature
Field
°C
NA
NA
NE
15.9
14.9
15.3
14.8
14.5
14.2
14.5
15.3
Notes:
MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable
to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013
Yellow shaded cells indicate exceedance of MCL.
LOQ = Level of Quantitation
DL = Detection Limit
NA = Not Applicable
NE = Not Established; North Carolina has not established a MCL
Table 5 Inorgan (Jan202O) of Tables RCLF Background Jan202O.xlsx
Prepared by: AWA
Checked by: IAI
Table 6
Total & Dissolved Metals Data (January 2020)
Phase 2 C&D Expansion Area
Rutherford County Landfill
Rutherfordton, North Carolina
Permit No. 8103-CDLF-2002
BLE Project No. J20-13675-04
Sampled by BLE on January 22, 2020 (Shealy Project VA23042)
TEST
UNITS
LOQ
DL
MCL
LFG-6 (B-13)
LFG-7 (B-17)
B-36
B-40S
B-40D
B-41
B-42
B-44
Total Aluminum (Al)
µg/1
40
10
NE
41
350
40
80
96
25 J
2,600
110
Dissolved Aluminum (Al)
µg/l
40
10
NE
<10
63
Ili
<10
<10
<10
290
<10
Total Antimony (Sb)
µg/l
2.0
0.50
1(i)
<0.50
<0.50
<0.50
<0.50
<0.50
<0.50
0.81 J
<0.50
Dissolved Antimony (Sb)
µg/1
2.0
0.50
1(i)
I <0.50
<0.50
<0.50
<0.50
<0.50
<0.50
1.8 J
0.5 J
Total Arsenic (As)
µg/1
2.0
1.3
10
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
1.7 J
<1.3
Dissolved Arsenic (As)
µg/1
2.0
1.3
10
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
1.4 J
<1.3
Total Barium (Ba)
µg/1
5.0
1.3
700
11
5.0
25
42
12
54
43
50
Dissolved Barium (Ba)
µg/1
5.0
1.3
700
11
2.3 J
25
41
11
53
22
48
Total Beryllium (Be)
µg/1
0.40
0.15
4(i)
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
Dissolved Beryllium (Be)
µg/l
0.40
0.15
4(i)
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
Total Cadmium (Cd)
µg/l
0.50
0.13
2
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
Dissolved Cadmium (Cd)
µg/l
0.50
0.13
2
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
<0.13
Total Chromium (Cr)
µg/l
5.0
1.3
10
<1.3
1.6 J
<1.3
<1.3
<1.3
<1.3
2.1 J
<1.3
Dissolved Chromium (Cr)
µg/l
5.0
1.3
10
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
Total Cobalt (Co)
µg/1
5.0
1.3
1(i)
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
3.1 J
Dissolved Cobalt (Co)
µg/1
5.0
1.3
1(i)
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
2.8 J
Total Copper (Cu)
µg/1
5.0
1.3
1,000
1 <1.3
2.0 J
<1.3
<1.3
<1.3
<1.3
1.7 J
<1.3
Dissolved Copper (Cu)
µg/1
5.0
1.3
1,000
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
Total Iron (Fe)
µg/1
50
13
300
43 J
350
65
98
120
48 J
1,300
170
Dissolved Iron (Fe)
µg/l
50
13
300
14 J
14 J
<13
16 J
56
26 J
160
<13
Total Lead (Pb)
µg/1
1.0
0.25
15
<0.25
0.88 J
<0.25
<0.25
<0.25
1.1
1.7
<0.25
Dissolved Lead (Pb)
µg/l
1.0
0.25
15
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
Total Manganese (Mn)
µg/l
5.0
1.3
50
2.1 J
6.8
6.1
48
150
46
58
310
Dissolved Manganese (Mn)
µg/1
5.0
1.3
50
<1.3
<1.3
5.6
46
150
45
45
320
Total Mercury (Hg)
µg/1
0.20
0.091
1
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
Dissolved Mercury (Hg)
µg/1
0.20
0.091
1
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
<0.091
Total Nickel (Ni)
µg/1
5.0
1.3
100
1 <1.3
<1.3
<1.3
<1.3
<1.3
<1.3
2.3 J
<1.3
Dissolved Nickel (Ni)
µg/1
5.0
1.3
100
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
Total Selenium (Se)
µg/1
5.0
1.3
20
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
Dissolved Selenium (Se)
µg/l
5.0
1.3
20
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
<1.3
Total Silver (Ag)
µg/1
1.0
0.25
20
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
Dissolved Silver (Ag)
µg/l
1.0
0.25
20
1 <0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
<0.25
Total Thallium (Tl)
µg/l
0.50
0.15
0.2(i)
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
Dissolved Thallium (Tl)
µg/1
0.50
0.15
0.2(i)
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
<0.15
Total Vanadium (V)
µg/1
5.0
2.5
0.3(i)
<2.5
<2.5
<2.5
<2.5
<2.5
<2.5
6.3
<2.5
Dissolved Vanadium (V)
µg/1
1 5.0
1 2.5
1 0.3(i)
<2.5
<2.5
<2.5
<2.5
<2.5
<2.5
4.2 J
<2.5
Total Zinc (Zn)
µg/1
1 10
2.5
1,000
1 2.5 J
6.5 J
<2.5
1 <2.5
<2.5
<2.5
4.2 J
<2.5
Dissolved Zinc (Zn)
µg/1
1 10
2.5
1,000
1 <2.5
3.3 J
<2.5
1 <2.5
<2.5
<2.5
<2.5
<2.5
Notes:
MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable
to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013
Yellow shaded cells indicate exceedance of MCL.
Refer to the laboratory data sheets for detected concentrations which are J values (estimated values above DL but below LOQ).
(i) = Interim Maximum Allowable Concentrations (IMACs) April 6, 2018 - Non Regulatory (Reference Only)
LOQ = Level of Quantitation
DL = Detection Limit
NE = Not Established; North Carolina has not established a MCL
Analysis by EPA Methods 6020B & 7470A
Prepared by: AWA
Checked by: IAFTJD
Table 6 Metals (Jan202O) of Tables RCLF Background Jan202O.xlsx
Figures
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TOWN OF RUTHERFORDTON
WASTEWATER TREATMENT
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APPROVED: AWA
DATE: 02-06-20
CAD FILE: RUTHERFORDLF-04WTM
JOB NO: J20-13675-04
?I, umpm;'E'lll
EXISTING ANIMAL
SHELTER FACILITY 771,
-0-
APPROXIMATE FACILITY LIMITS
��i��- �����%����A ��������
PHASEy�2 -C&D EXPANSION
%LFG-7 (B-1
/ 991.21
hLFG -6 iB-13Y
\
6 - 44
1
� o
_FG-8A* B=121
111i�1
F3-8 (B-12S
isBUNNELL
� t,aMa Ns
im i EF16ilEERIHU
6004 Ponders Court, Greenville, SC 29515
PFrone: (664126B-1265 Fm (064) 289-4430
MONITORING LOCATION LEGEND
♦
LFG-9
LANDFILL GAS MONITORING WELL, SURVEYED BY MCGILL ASSOCIATES, 12/17/19
0
LFG-5
LANDFILL GAS MONITORING WELL, APPROXIMATE LOCATION
0
MW-8
GROUNDWATER MONITORING WELL, APPROXIMATE LOCATION
MW-1
GROUNDWATER MONITORING WELL, SURVEYED BY MCGILL ASSOCIATES, 12/17/19
®
B-18
BORING, APPROXIMATE LOCATION
+
B-43
BORING, SURVEYED BY MCGILL ASSOCIATES, 12/17/19
'
lqW-1
SURFACE WATER SAMPLING LOCATION, APPROXIMATE
•
B-41
PIEZOMETER, SURVEYED BY MCGILL ASSOCIATES, 12/17/19
O
B-15
PIEZOMETER LOCATION, APPROXIMATE
LFG-8A*
IGNORED FOR CONTOURING PURPOSES. WELL REPRESENTS UNIQUE
HYDROGEOLOGIC CONDITIONS
INDUSTRIAL PARK ROAD , o-
TOPOGRAPHIC &GEOLOGIC LEGEND
EXISTING 2' CONTOUR - LIDAR/ALS/MCGILL
EXISTING 10' CONTOUR - LIDAR/ALS/MCGILL
900 POTENTIOMETRIC SURFACE CONTOUR LINE (CI = 10')
956.32 WATER ELEVATIONS IN BLUE COLLECTED BY BLE ON JANUARY 21, 2020
f — — — — — GROUNDWATER FLOW DIRECTION
SW-4
NOTE:
APPROXIMATE LANDFILL GAS AND GROUNDWATER MONITORING WELLS,
APPROXIMATE BORINGS, AND APPROXIMATE SURFACE WATER SAMPLING
LOCATIONS ALL PROVIDED BY ODOM ENGINEERING
GENERAL MAP REFERENCE
1.1
Iv
LAUREL HILL DRIVE
200 100 0 200 400
APPROXIMATE SCALE IN FEET
11111f1jIt,"
~ � t
T
LO
f+rf1fift1110%
GROUNDWATER ELEVATION CONTOUR MAP (JANUARY 21, 2020)
RUTHERFORD COUNTY LANDFILL
RUTHERFORDTON, NORTH CAROLINA
FIGURE NO.
1
APPENDIX A
FIELD SAMPLING LOGS
it L IMM
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
941.81
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
2.13
Well ID #:
LFG-6 (B-13)
Land Surface Elevation (ft msl):
939.68
Downgradient:
Screened Interval (ft bgs):
21.0 - 31.0
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
Yes
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
33.13
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
20.21
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
12.92
Well Yield (subjective):
Low
1 Casing Volume in gallons (CV) = LWC x 0.17 =
2.20
Sample Date and Time:
Sampled at 1220 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
6.59
Remarks: Dry at 3.0 gallons of water removed.
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
3.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 3.0
Sample
Time (military)
1246
1249
1220
pH (S.U.)
6.47
6.51
6.48
Sp. Cond. (umhos/cm)
66.52
67.91
68.32
Water Temp. (°C)
16.0
1 16.3
1
1
1
1 15.9
Turbidity (NTU)
70.8
53.9
44.6
COMMENTS/OBSERVATIONS:
it Im
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
963.14
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
2.25
Well ID #:
LFG-7 (B-17)
Land Surface Elevation (ft msl):
960.89
Downgradient:
Screened Interval (ft bgs):
40.0 - 50.0
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
Yes
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
52.25
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
35.38
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
16.87
Well Yield (subjective):
Low
1 Casing Volume in gallons (CV) = LWC x 0.17 =
2.87
Sample Date and Time:
Sampled at 1120 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
8.60
Remarks: Dry at 6.5 gallons of water removed.
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
6.5 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 3.0 6.0
Sample
Time (military)
1127
1129
1132
1120
pH (S.U.)
7.58
7.66
7.73
7.61
Sp. Cond. (umhos/cm)
70.87
109.6
110.15
113.2
Water Temp. (°C)
15.7
1 15.6
1 15.4
1
1
1 14.9
Turbidity (NTU)
78.1
38.1
27.9
18.6
COMMENTS/OBSERVATIONS:
it L IMM
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
948.12
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
2.97
Well ID #:
B-36
Land Surface Elevation (ft msl):
945.15
Downgradient:
Screened Interval (ft bgs):
22.0 - 32.0
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
34.97
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
18.01
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
16.96
Well Yield (subjective):
Low
1 Casing Volume in gallons (CV) = LWC x 0.17 =
2.88
Sample Date and Time:
Sampled at 1203 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
8.65
Remarks:
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
10.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 3.5 7.0
10.0
Sample
Time (military)
1218
1223
1224
1228
1203
pH (S.U.)
7.21
6.02
6.41
6.06
7.07
Sp. Cond. (umhos/cm)
41.42
41.76
40.85
40.60
40.31
Water Temp. (°C)
15.9
1 15.2
1 15.2
1 15.9
1
1 15.3
Turbidity (NTU)
349
74.9
28.8
20.6
19.7
COMMENTS/OBSERVATIONS:
It Im
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
915.44
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
3.04
Well ID #:
B-40S
Land Surface Elevation (ft msl):
912.40
Downgradient:
Screened Interval (ft bgs):
35.8 - 45.8
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
48.84
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
32.51
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
16.33
Well Yield (subjective):
Low
1 Casing Volume in gallons (CV) = LWC x 0.17 =
2.78
Sample Date and Time:
Sampled at 845 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
8.33
Remarks: Dry at 8.5 gallons of water removed
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
8.5 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 4.0 8.0
Sample
Time (military)
937
940
944
845
pH (S.U.)
7.47
7.33
6.66
7.53
Sp. Cond. (umhos/cm)
379.6
123.1
120.4
135.9
Water Temp. (°C)
12.2
1 15.2
1 15.1
1
1
1 14.8
Turbidity (NTU)
>2,000
300
2.43
3.58
COMMENTS/OBSERVATIONS:
it L IMM
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
915.65
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
2.73
Well ID #:
B-40D
Land Surface Elevation (ft msl):
912.92
Downgradient:
Screened Interval (ft bgs):
65.8 - 75.8
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
78.53
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
33.70
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
44.83
Well Yield (subjective):
Low
1 Casing Volume in gallons (CV) = LWC x 0.17 =
7.62
Sample Date and Time:
Sampled at 835 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
22.86
Remarks: Dry at 9.0 gallons of water removed
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
9.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 8.5
Sample
Time (military)
910
915
835
pH (S.U.)
7.33
7.25
7.44
Sp. Cond. (umhos/cm)
384.2
188.5
206.7
Water Temp. (°C)
14.9
1 14.8
1
1
1
1 14.5
Turbidity (NTU)
>2,000
488
35.2
COMMENTS/OBSERVATIONS:
it L IMM
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
917.94
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
3.13
Well ID #:
B-41
Land Surface Elevation (ft msl):
914.81
Downgradient:
Screened Interval (ft bgs):
24.8 - 34.8
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
37.93
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
25.26
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
16.26
Well Yield (subjective):
Intemediate
1 Casing Volume in gallons (CV) = LWC x 0.17 =
2.76
Sample Date and Time:
Sampled at 910 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
8.28
Remarks:
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
9.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 3.0 6.0
9.0
Sample
Time (military)
1008
1014
1021
1028
910
pH (S.U.)
6.23
6.30
6.27
6.21
6.20
Sp. Cond. (umhos/cm)
176.2
143.2
134.7
135.2
144.5
Water Temp. (°C)
14.5
1 14.5
1 14.7
1 14.7
1
1 14.2
Turbidity (NTU)
945
164
65.8
26.9
20.8
COMMENTS/OBSERVATIONS:
it L IMM
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
948.78
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
3.31
Well ID #:
B-42
Land Surface Elevation (ft msl):
945.47
Downgradient:
Screened Interval (ft bgs):
33.8 - 43.8
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
47.11
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
15.70
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
31.41
Well Yield (subjective):
Interemediate
1 Casing Volume in gallons (CV) = LWC x 0.17 =
5.34
Sample Date and Time:
Sampled at 925 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
16.02
Remarks: Dry at 12.5 gallons of water removed.
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
12.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 6.0 12.0
Sample
Time (military)
1046
1053
1059
925
pH (S.U.)
6.71
6.83
7.86
7.71
Sp. Cond. (umhos/cm)
252.1
269.8
271.8
266.4
Water Temp. (°C)
14.6
1 14.8
1 14.8
1
1
1 14.5
Turbidity (NTU)
>2,000
>2,000
359
44.9
COMMENTS/OBSERVATIONS:
it im
BUNNELL-LAMMONS ENGINEERING, INC.
FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING
Page 1 of 1
Date:
Jan. 21, 2020
Casing Diameter:
2 inches
Field Personnel:
IAI
Casing Material:
PVC
Site Name:
RCLF
Measuring Point Elevation (ft msl):
955.13
BLE Job #:
J20-13675-04
Height of Riser (ft above land surface):
2.92
Well ID #:
B-44
Land Surface Elevation (ft msl):
952.21
Downgradient:
Screened Interval (ft bgs):
28.8 - 38.8
Upgradient:
Dedicated Pump or Bailer:
No
Weather Conditions:
Sunny
Steel Guard Pipe Around Casing:
No
Air Temperature:
25 OF
Locking Cap:
Yes
Total Well Depth in feet btoc (TWD) =
41.72
Protective Post/Abutment:
No
Depth to Groundwater in feet btoc (DGW) =
22.03
Well Integrity Satisfactory:
Yes
Length of Water Column (LWC) = TWD - DGW =
19.69
Well Yield (subjective):
Intermediate
1 Casing Volume in gallons (CV) = LWC x 0.17 =
3.35
Sample Date and Time:
Sampled at 1150 on 1/22/2020
Standard Evacuation Volume (3 casing volumes) =
10.04
Remarks:
Method of Well Evacuation: Submersible Pump
Method of Sample Collection:
Disp. Bailer
Total Volume of Water Removed (gallons):
12.0 gallons
Volume Purged (gallons)
FIELD ANALYSIS
Initial 4.0 8.0
12.0
Sample
Time (military)
1151
1154
1158
1204
1150
pH (S.U.)
7.18
7.18
7.10
6.81
6.93
Sp. Cond. (umhos/cm)
102.7
102.2
90.36
87.51
100.8
Water Temp. (°C)
14
1 14.7
1 15.1
1 14.4
1
1 15.3
Turbidity (NTU)
>2,000
>2,000
349
152
80.7
COMMENTS/OBSERVATIONS:
APPENDIX B
LABORATORY ANALYTICAL DATA
SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
County of Rutherford
289 N. Main Street
Rutherfordton, NC 28139
Attention: James Kilgo
Project Name: Rutherford County Landfill
Project Number: 13675-04
Lot Number:VA23042
Date Completed:02/07/2020
Revision Date: 02/06/2020
NO N � � J N N �
02/10/2020 9:56 AM
Approved and released by:
Lab Director - Greenville: Lucas Odom
PCCRFp 4
AM
AC CF ED I T E D
qe
11900 eLAa
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 1 of 91
SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
County of Rutherford
Lot Number: VA23042
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality
Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any
exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or
discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the
cover page.
Report Revision
Per client request, sample -001 was re -analyzed for total metals. The sample was reanalyzed in duplicate
to confirm the re -analysis. The second run has been reported. No other data has changed.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 2 of 91
SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
County of Rutherford
Lot Number: VA23042
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
LFG-6
Aqueous
01/22/20201220
01/23/2020
002
LFG-7
Aqueous
01/22/20201120
01/23/2020
003
B-36
Aqueous
01/22/20201203
01/23/2020
004
B-40S
Aqueous
01/22/2020 0845
01/23/2020
005
B-40D
Aqueous
01/22/2020 0835
01/23/2020
006
B-41
Aqueous
01/22/2020 0910
01/23/2020
007
B-42
Aqueous
01/22/2020 0925
01/23/2020
008
B-44
Aqueous
01/22/20201150
01/23/2020
009
TB
Aqueous
01/22/2020
01/23/2020
(9 samples)
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 3 of 91
SHEALY ENVIRONMENTAL SERVICES, INC.
Detection Summary
County of Rutherford
Lot Number: VA23042
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
001
LFG-6
Aqueous
Chloride
9056A
2.1
mg/L
7
001
LFG-6
Aqueous
TDS
SM 2540C-
31
mg/L
7
001
LFG-6
Aqueous
Dissolved Barium
6020B
11
ug/L
10
001
LFG-6
Aqueous
Dissolved Iron
6020B
14
J
ug/L
10
001
LFG-6
Aqueous
Aluminum
6020B
41
ug/L
10
001
LFG-6
Aqueous
Barium
6020B
11
ug/L
10
001
LFG-6
Aqueous
Iron
6020B
43
J
ug/L
10
001
LFG-6
Aqueous
Manganese
6020B
2.1
J
ug/L
10
001
LFG-6
Aqueous
Zinc
6020B
2.5
J
ug/L
11
002
LFG-7
Aqueous
Chloride
9056A
1.9
mg/L
12
002
LFG-7
Aqueous
TDS
SM 2540C-
47
mg/L
12
002
LFG-7
Aqueous
Dissolved Aluminum
6020B
63
ug/L
14
002
LFG-7
Aqueous
Dissolved Barium
6020B
2.3
J
ug/L
15
002
LFG-7
Aqueous
Dissolved Iron
6020B
14
J
ug/L
15
002
LFG-7
Aqueous
Dissolved Zinc
6020B
3.3
J
ug/L
15
002
LFG-7
Aqueous
Aluminum
6020B
350
ug/L
15
002
LFG-7
Aqueous
Barium
6020B
5.0
ug/L
15
002
LFG-7
Aqueous
Chromium
6020B
1.6
J
ug/L
15
002
LFG-7
Aqueous
Copper
6020B
2.0
J
ug/L
15
002
LFG-7
Aqueous
Iron
6020B
350
ug/L
15
002
LFG-7
Aqueous
Lead
6020B
0.88
J
ug/L
15
002
LFG-7
Aqueous
Manganese
6020B
6.8
ug/L
15
002
LFG-7
Aqueous
Zinc
6020B
6.5
J
ug/L
16
003
B-36
Aqueous
Chloride
9056A
3.7
mg/L
17
003
B-36
Aqueous
TDS
SM 2540C-
25
mg/L
17
003
B-36
Aqueous
Dissolved Aluminum
6020B
11
J
ug/L
19
003
B-36
Aqueous
Dissolved Barium
6020B
25
ug/L
20
003
B-36
Aqueous
Dissolved Manganese
6020B
5.6
ug/L
20
003
B-36
Aqueous
Aluminum
6020B
40
ug/L
20
003
B-36
Aqueous
Barium
6020B
25
ug/L
20
003
B-36
Aqueous
Iron
6020B
65
ug/L
20
003
B-36
Aqueous
Manganese
6020B
6.1
ug/L
20
004
B-40S
Aqueous
Alkalinity
SM 2320B-
30
mg/L
22
004
B-40S
Aqueous
Chloride
9056A
3.0
mg/L
22
004
B-40S
Aqueous
Sulfate
9056A
5.8
mg/L
22
004
B-40S
Aqueous
TDS
SM 2540C-
66
mg/L
22
004
B-40S
Aqueous
Dissolved Barium
6020B
41
ug/L
25
004
B-40S
Aqueous
Dissolved Iron
6020B
16
J
ug/L
25
004
B-40S
Aqueous
Dissolved Manganese
6020B
46
ug/L
25
004
B-40S
Aqueous
Aluminum
6020B
80
ug/L
25
004
B-40S
Aqueous
Barium
6020B
42
ug/L
25
004
B-40S
Aqueous
Iron
6020B
98
ug/L
25
004
B-40S
Aqueous
Manganese
6020B
48
ug/L
25
005
B-40D
Aqueous
Alkalinity
SM 232013-
87
mg/L
27
005
B-40D
Aqueous
Chloride
9056A
2.3
mg/L
27
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 4 of 91
Detection Summary (Continued)
Lot Number: VA23042
Sample Sample ID Matrix Parameter Method Result Q Units Page
005
B-40D
Aqueous
Sulfate
9056A
4.9
005
B-40D
Aqueous
TDS
SM 2540C-
130
005
B-40D
Aqueous
Dissolved Barium
6020B
11
005
B-40D
Aqueous
Dissolved Iron
6020B
56
005
B-40D
Aqueous
Dissolved Manganese
6020B
150
005
B-40D
Aqueous
Aluminum
6020B
96
005
B-40D
Aqueous
Barium
6020B
12
005
B-40D
Aqueous
Iron
6020B
120
005
B-40D
Aqueous
Manganese
6020B
150
006
B-41
Aqueous
Alkalinity
SM 232013-
30
006
B-41
Aqueous
Chloride
9056A
3.3
006
B-41
Aqueous
Sulfate
9056A
13
006
B-41
Aqueous
TDS
SM 2540C-
76
006
B-41
Aqueous
Dissolved Barium
6020B
53
006
B-41
Aqueous
Dissolved Iron
6020B
26
006
B-41
Aqueous
Dissolved Manganese
6020B
45
006
B-41
Aqueous
Aluminum
6020B
25
006
B-41
Aqueous
Barium
6020B
54
006
B-41
Aqueous
Iron
6020B
48
006
B-41
Aqueous
Lead
6020B
1.1
006
B-41
Aqueous
Manganese
6020B
46
007
B-42
Aqueous
Alkalinity
SM 2320B-
84
007
B-42
Aqueous
Chloride
9056A
8.3
007
B-42
Aqueous
Sulfate
9056A
16
007
B-42
Aqueous
TDS
SM 2540C-
160
007
B-42
Aqueous
Carbon disulfide
8260D
1.0
007
B-42
Aqueous
Dissolved Aluminum
6020B
290
007
B-42
Aqueous
Dissolved Antimony
6020B
1.8
007
B-42
Aqueous
Dissolved Arsenic
6020B
1.4
007
B-42
Aqueous
Dissolved Barium
6020B
22
007
B-42
Aqueous
Dissolved Iron
6020B
160
007
B-42
Aqueous
Dissolved Manganese
6020B
45
007
B-42
Aqueous
Dissolved Vanadium
6020B
4.2
007
B-42
Aqueous
Aluminum
6020B
2600
007
B-42
Aqueous
Antimony
6020B
0.81
007
B-42
Aqueous
Arsenic
6020B
1.7
007
B-42
Aqueous
Barium
6020B
43
007
B-42
Aqueous
Chromium
6020B
2.1
007
B-42
Aqueous
Copper
6020B
1.7
007
B-42
Aqueous
Iron
6020B
1300
007
B-42
Aqueous
Lead
6020B
1.7
007
B-42
Aqueous
Manganese
6020B
58
007
B-42
Aqueous
Nickel
6020B
2.3
007
B-42
Aqueous
Vanadium
6020B
6.3
007
B-42
Aqueous
Zinc
6020B
4.2
008
B-44
Aqueous
Alkalinity
SM 232013-
24
008
B-44
Aqueous
Chloride
9056A
2.5
008
B-44
Aqueous
TDS
SM 2540C-
50
J
J
J
mg/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
27
27
30
30
30
30
30
30
30
32
32
32
32
35
35
35
35
35
35
35
35
37
37
37
37
37
39
39
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
41
42
42
42
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 5 of 91
Detection Summary (Continued)
Lot Number: VA23042
Sample Sample ID
Matrix
Parameter
Method
Result
Q
Units
Page
008
B-44
Aqueous
Dissolved Antimony
6020B
0.50
J
ug/L
44
008
B-44
Aqueous
Dissolved Barium
6020B
48
ug/L
45
008
B-44
Aqueous
Dissolved Cobalt
6020B
2.8
J
ug/L
45
008
B-44
Aqueous
Dissolved Manganese
6020B
320
ug/L
45
008
B-44
Aqueous
Aluminum
6020B
110
ug/L
45
008
B-44
Aqueous
Barium
6020B
50
ug/L
45
008
B-44
Aqueous
Cobalt
6020B
3.1
J
ug/L
45
008
B-44
Aqueous
Iron
6020B
170
ug/L
45
008
B-44
Aqueous
Manganese
6020B
310
ug/L
45
(102 detections)
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 6 of 91
Client: County of Rutherford Laboratory ID:VA23042-001
Description: LFG-6 Matrix: Aqueous
Date Sampled:01/22/2020 1220
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1711 KFE
43147
1
(Chloride) 9056A
1 01/29/2020 2346 HKL
43548
1
(Sulfate) 9056A
1 01/29/2020 2346 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
ND
20
20
mg/L
1
Chloride
9056A
2.1
1.0
0.20
mg/L
1
Sulfate
9056A
ND
1.0
0.20
mg/L
1
TDS
SM 2540C-
31
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 1927 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
93 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0135 JTH
42874
2 5030B
8260D
1 01/27/2020 2205 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 7 of 91
Client: County of Rutherford Laboratory ID:VA23042-001
Description: LFG-6 Matrix: Aqueous
Date Sampled:01/22/2020 1220
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0135 JTH 42874
2 5030B 8260D 1 01/27/2020 2205 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 8 of 91
Client: County of Rutherford Laboratory ID:VA23042-001
Description: LFG-6 Matrix: Aqueous
Date Sampled:01/22/2020 1220
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0135 JTH
42874
2 5030B
8260D
1 01/27/2020 2205 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
106 70-130 103 70-130
1,2-Dichloroethane-d4
102 70-130 102 70-130
Toluene-d8
104 70-130 105 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1128 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1131 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1534 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B ND
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 9 of 91
Client: County of Rutherford Laboratory ID:VA23042-001
Description: LFG-6 Matrix: Aqueous
Date Sampled:01/22/2020 1220
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1534 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
11
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
14 J
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
ND
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
2 3005A
6020B
1 02/07/2020 1420 BPK
02/06/2020 1710 44149
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
41
40
10
ug/L
2
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
2
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
2
Barium
7440-39-3 6020B
11
5.0
1.3
ug/L
2
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
2
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
2
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
2
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
2
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
2
Iron
7439-89-6 6020B
43 J
50
13
ug/L
2
Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
2
Manganese
7439-96-5 6020B
2.1 J
5.0
1.3
ug/L
2
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
2
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
2
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
2
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
2
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
2
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 10 of 91
Client: County of Rutherford Laboratory ID:VA23042-001
Description: LFG-6 Matrix: Aqueous
Date Sampled:01/22/2020 1220
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
2 3005A 6020B 1 02/07/2020 1420 BPK 02/06/2020 1710 44149
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 2
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 11 of 91
Client: County of Rutherford Laboratory ID:VA23042-002
Description: LFG-7 Matrix: Aqueous
Date Sampled:01/22/2020 1120
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1726 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0004 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0004 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
ND
20
20
mg/L
1
Chloride
9056A
1.9
1.0
0.20
mg/L
1
Sulfate
9056A
ND
1.0
0.20
mg/L
1
TDS
SM 2540C-
47
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 1952 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
94 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0159 JTH
42874
2 5030B
8260D
1 01/27/2020 2228 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 12 of 91
Client: County of Rutherford Laboratory ID:VA23042-002
Description: LFG-7 Matrix: Aqueous
Date Sampled:01/22/2020 1120
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0159 JTH 42874
2 5030B 8260D 1 01/27/2020 2228 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 13 of 91
Client: County of Rutherford Laboratory ID:VA23042-002
Description: LFG-7 Matrix: Aqueous
Date Sampled:01/22/2020 1120
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0159 JTH
42874
2 5030B
8260D
1 01/27/2020 2228 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
101 70-130 104 70-130
1,2-Dichloroethane-d4
98 70-130 105 70-130
Toluene-d8
100 70-130 107 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1133 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1141 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1546 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B 63
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 14 of 91
Client: County of Rutherford Laboratory ID:VA23042-002
Description: LFG-7 Matrix: Aqueous
Date Sampled:01/22/2020 1120
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1546 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
2.3 J
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
14 J
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
ND
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
3.3 J
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1551 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
350
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
5.0
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
1.6 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
2.0 J
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
350
50
13
ug/L
1
Lead
7439-92-1 6020B
0.88 J
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
6.8
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 15 of 91
Client: County of Rutherford Laboratory ID:VA23042-002
Description: LFG-7 Matrix: Aqueous
Date Sampled:01/22/2020 1120
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1551 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B 6.5 J 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 16 of 91
Client: County of Rutherford Laboratory ID:VA23042-003
Description: B-36 Matrix: Aqueous
Date Sampled:01/22/2020 1203
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1731 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0101 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0101 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
ND
20
20
mg/L
1
Chloride
9056A
3.7
1.0
0.20
mg/L
1
Sulfate
9056A
ND
1.0
0.20
mg/L
1
TDS
SM 2540C-
25
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2016 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
93 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0223 JTH
42874
2 5030B
8260D
1 01/27/2020 2252 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 17 of 91
Client: County of Rutherford Laboratory ID:VA23042-003
Description: B-36 Matrix: Aqueous
Date Sampled:01/22/2020 1203
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0223 JTH 42874
2 5030B 8260D 1 01/27/2020 2252 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 18 of 91
Client: County of Rutherford Laboratory ID:VA23042-003
Description: B-36 Matrix: Aqueous
Date Sampled:01/22/2020 1203
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0223 JTH
42874
2 5030B
8260D
1 01/27/2020 2252 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
103 70-130 102 70-130
1,2-Dichloroethane-d4
101 70-130 101 70-130
Toluene-d8
103 70-130 104 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1143 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1151 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1557 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B 11 J
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 19 of 91
Client: County of Rutherford Laboratory ID:VA23042-003
Description: B-36 Matrix: Aqueous
Date Sampled:01/22/2020 1203
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1557 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
25
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
ND
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
5.6
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1603 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
40
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
25
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
65
50
13
ug/L
1
Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
6.1
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 20 of 91
Client: County of Rutherford Laboratory ID:VA23042-003
Description: B-36 Matrix: Aqueous
Date Sampled:01/22/2020 1203
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1603 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 21 of 91
Client: County of Rutherford Laboratory ID:VA23042-004
Description: B-40S Matrix: Aqueous
Date Sampled:01/22/2020 0845
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1737 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0120 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0120 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
30
20
20
mg/L
1
Chloride
9056A
3.0
1.0
0.20
mg/L
1
Sulfate
9056A
5.8
1.0
0.20
mg/L
1
TDS
SM 2540C-
66
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2040 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
95 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0247 JTH
42874
2 5030B
8260D
1 01/27/2020 2316 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 22 of 91
Client: County of Rutherford Laboratory ID:VA23042-004
Description: B-40S Matrix: Aqueous
Date Sampled:01/22/2020 0845
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0247 JTH 42874
2 5030B 8260D 1 01/27/2020 2316 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 23 of 91
Client: County of Rutherford Laboratory ID:VA23042-004
Description: B-40S Matrix: Aqueous
Date Sampled:01/22/2020 0845
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0247 JTH
42874
2 5030B
8260D
1 01/27/2020 2316 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
102 70-130 104 70-130
1,2-Dichloroethane-d4
100 70-130 102 70-130
Toluene-d8
102 70-130 105 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1153 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1156 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1609 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B ND
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 24 of 91
Client: County of Rutherford Laboratory ID:VA23042-004
Description: B-40S Matrix: Aqueous
Date Sampled:01/22/2020 0845
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1609 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
41
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
16 J
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
46
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1615 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
80
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
42
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
98
50
13
ug/L
1
Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
48
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 25 of 91
Client: County of Rutherford Laboratory ID:VA23042-004
Description: B-40S Matrix: Aqueous
Date Sampled:01/22/2020 0845
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1615 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 26 of 91
Client: County of Rutherford Laboratory ID:VA23042-005
Description: B-40D Matrix: Aqueous
Date Sampled:01/22/2020 0835
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1745 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0139 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0139 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
87
20
20
mg/L
1
Chloride
9056A
2.3
1.0
0.20
mg/L
1
Sulfate
9056A
4.9
1.0
0.20
mg/L
1
TDS
SM 2540C-
130
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2105 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
94 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0312 JTH
42874
2 5030B
8260D
1 01/27/2020 2340 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 27 of 91
Client: County of Rutherford Laboratory ID:VA23042-005
Description: B-40D Matrix: Aqueous
Date Sampled:01/22/2020 0835
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0312 JTH 42874
2 5030B 8260D 1 01/27/2020 2340 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 28 of 91
Client: County of Rutherford Laboratory ID:VA23042-005
Description: B-40D Matrix: Aqueous
Date Sampled:01/22/2020 0835
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0312 JTH
42874
2 5030B
8260D
1 01/27/2020 2340 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
103 70-130 102 70-130
1,2-Dichloroethane-d4
100 70-130 103 70-130
Toluene-d8
103 70-130 104 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1158 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1201 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1621 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B ND
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 29 of 91
Client: County of Rutherford Laboratory ID:VA23042-005
Description: B-40D Matrix: Aqueous
Date Sampled:01/22/2020 0835
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1621 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
11
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
56
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
150
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1627 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
96
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
12
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
120
50
13
ug/L
1
Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
150
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 30 of 91
Client: County of Rutherford Laboratory ID:VA23042-005
Description: B-40D Matrix: Aqueous
Date Sampled:01/22/2020 0835
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1627 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 31 of 91
Client: County of Rutherford Laboratory ID:VA23042-006
Description: B-41 Matrix: Aqueous
Date Sampled:01/22/2020 0910
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1752 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0158 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0158 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
30
20
20
mg/L
1
Chloride
9056A
3.3
1.0
0.20
mg/L
1
Sulfate
9056A
13
1.0
0.20
mg/L
1
TDS
SM 2540C-
76
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2129 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
84 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0336 JTH
42874
2 5030B
8260D
1 01/28/2020 0004 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 32 of 91
Client: County of Rutherford Laboratory ID:VA23042-006
Description: B-41 Matrix: Aqueous
Date Sampled:01/22/2020 0910
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0336 JTH 42874
2 5030B 8260D 1 01/28/2020 0004 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 33 of 91
Client: County of Rutherford Laboratory ID:VA23042-006
Description: B-41 Matrix: Aqueous
Date Sampled:01/22/2020 0910
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0336 JTH
42874
2 5030B
8260D
1 01/28/2020 0004 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
104 70-130 103 70-130
1,2-Dichloroethane-d4
100 70-130 101 70-130
Toluene-d8
102 70-130 104 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1203 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1211 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1644 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B ND
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B ND
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 34 of 91
Client: County of Rutherford Laboratory ID:VA23042-006
Description: B-41 Matrix: Aqueous
Date Sampled:01/22/2020 0910
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1644 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
53
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
26 J
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
45
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1650 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
25 J
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
54
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
48 J
50
13
ug/L
1
Lead
7439-92-1 6020B
1.1
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
46
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 35 of 91
Client: County of Rutherford Laboratory ID:VA23042-006
Description: B-41 Matrix: Aqueous
Date Sampled:01/22/2020 0910
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1650 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 36 of 91
Client: County of Rutherford Laboratory ID:VA23042-007
Description: B-42 Matrix: Aqueous
Date Sampled:01/22/2020 0925
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1811 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0217 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0217 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
84
20
20
mg/L
1
Chloride
9056A
8.3
1.0
0.20
mg/L
1
Sulfate
9056A
16
1.0
0.20
mg/L
1
TDS
SM 2540C-
160
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2153 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
96 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0400 JTH
42874
2 5030B
8260D
1 01/28/2020 0027 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
1.0
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 37 of 91
Client: County of Rutherford Laboratory ID:VA23042-007
Description: B-42 Matrix: Aqueous
Date Sampled:01/22/2020 0925
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0400 JTH 42874
2 5030B 8260D 1 01/28/2020 0027 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 38 of 91
Client: County of Rutherford Laboratory ID:VA23042-007
Description: B-42 Matrix: Aqueous
Date Sampled:01/22/2020 0925
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0400 JTH
42874
2 5030B
8260D
1 01/28/2020 0027 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
104 70-130 104 70-130
1,2-Dichloroethane-d4
100 70-130 102 70-130
Toluene-d8
103 70-130 105 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1214 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1216 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1656 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B 290
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B 1.8 J
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 39 of 91
Client: County of Rutherford Laboratory ID:VA23042-007
Description: B-42 Matrix: Aqueous
Date Sampled:01/22/2020 0925
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1656 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
1.4 J
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
22
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
160
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
45
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
4.2 J
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1702 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
2600
40
10
ug/L
1
Antimony
7440-36-0 6020B
0.81 J
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
1.7 J
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
43
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
2.1 J
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
ND
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
1.7 J
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
1300
50
13
ug/L
1
Lead
7439-92-1 6020B
1.7
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
58
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
2.3 J
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
6.3
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 40 of 91
Client: County of Rutherford Laboratory ID:VA23042-007
Description: B-42 Matrix: Aqueous
Date Sampled:01/22/2020 0925
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1702 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 41 of 91
Client: County of Rutherford Laboratory ID:VA23042-008
Description: B-44 Matrix: Aqueous
Date Sampled:01/22/2020 1150
Date Received: 01/23/2020
Inorganic non-metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 01/28/2020 1816 KFE
43147
1
(Chloride) 9056A
1 01/30/2020 0314 HKL
43548
1
(Sulfate) 9056A
1 01/30/2020 0314 HKL
43547
1
(TDS) SM 2540C-2011
1 01/23/2020 2354 MOM
42779
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
24
20
20
mg/L
1
Chloride
9056A
2.5
1.0
0.20
mg/L
1
Sulfate
9056A
ND
1.0
0.20
mg/L
1
TDS
SM 2540C-
50
25
25
mg/L
1
Volatile Organic Compounds by
GC/MS (SIM)
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D (SIM)
1 01/23/2020 2218 STM
42777
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
1,4-Dioxane
123-91-1 8260D (SIM)
ND
3.0
1.0
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
1,2-Dichloroethane-d4
94 40-170
Volatile Organic Compounds
by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0424 JTH
42874
2 5030B
8260D
1 01/28/2020 0051 JTH
43038
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Acetone
67-64-1 8260D
ND
20
5.0
ug/L
1
Acetonitrile
75-05-8 8260D
ND
50
15
ug/L
1
Acrolein
107-02-8 8260D
ND
20
4.0
ug/L
1
Acrylonitrile
107-13-1 8260D
ND
20
0.80
ug/L
1
Benzene
71-43-2 8260D
ND
1.0
0.40
ug/L
1
Bromochloromethane
74-97-5 8260D
ND
1.0
0.40
ug/L
1
Bromodichloromethane
75-27-4 8260D
ND
1.0
0.40
ug/L
1
Bromoform
75-25-2 8260D
ND
1.0
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9 8260D
ND
2.0
0.40
ug/L
1
2-Butanone (MEK)
78-93-3 8260D
ND
10
2.0
ug/L
1
Carbon disulfide
75-15-0 8260D
ND
1.0
0.40
ug/L
1
Carbon tetrachloride
56-23-5 8260D
ND
1.0
0.40
ug/L
1
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8 8260D
ND
5.0
1.0
ug/L
1
Chlorobenzene
108-90-7 8260D
ND
1.0
0.40
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 42 of 91
Client: County of Rutherford Laboratory ID:VA23042-008
Description: B-44 Matrix: Aqueous
Date Sampled:01/22/2020 1150
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/25/2020 0424 JTH 42874
2 5030B 8260D 1 01/28/2020 0051 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1, 1 -Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 43 of 91
Client: County of Rutherford Laboratory ID:VA23042-008
Description: B-44 Matrix: Aqueous
Date Sampled:01/22/2020 1150
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 5030B
8260D
1 01/25/2020 0424 JTH
42874
2 5030B
8260D
1 01/28/2020 0051 JTH
43038
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Toluene
108-88-3 8260D ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6 8260D ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5 8260D ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6 8260D ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4 8260D ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4 8260D ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4 8260D ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4 8260D ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7 8260D ND
1.0
0.40
ug/L
1
Run 1 Acceptance Run 2 Acceptance
Surrogate
Q % Recovery
Limits Q % Recovery Limits
Bromofluorobenzene
106 70-130 103 70-130
1,2-Dichloroethane-d4
103 70-130 102 70-130
Toluene-d8
105 70-130 105 70-130
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1219 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
CVAA
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1
7470A
1 01/28/2020 1221 KSH2 01/27/2020 1455
42828
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Mercury
7439-97-6 7470A ND 0.00020
0.000091
mg/L
1
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1731 BNW 01/24/2020 1024
42803
CAS Analytical
Parameter
Number Method Result Q
LOQ
DL
Units
Run
Dissolved Aluminum
7429-90-5 6020B ND
40
10
ug/L
1
Dissolved Antimony
7440-36-0 6020B 0.50 J
2.0
0.50
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range DL =
Detection
Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 % J = Estimated
result < LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 44 of 91
Client: County of Rutherford Laboratory ID:VA23042-008
Description: B-44 Matrix: Aqueous
Date Sampled:01/22/2020 1150
Date Received:01/23/2020
ICP-MS
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1731 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Dissolved Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Dissolved Barium
7440-39-3 6020B
48
5.0
1.3
ug/L
1
Dissolved Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Dissolved Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Dissolved Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Dissolved Cobalt
7440-48-4 6020B
2.8 J
5.0
1.3
ug/L
1
Dissolved Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Dissolved Iron
7439-89-6 6020B
ND
50
13
ug/L
1
Dissolved Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Dissolved Manganese
7439-96-5 6020B
320
5.0
1.3
ug/L
1
Dissolved Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Dissolved Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Dissolved Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Dissolved Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Dissolved Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
Dissolved Zinc
7440-66-6 6020B
ND
10
2.5
ug/L
1
ICP-MS Metals
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 3005A
6020B
1 01/27/2020 1737 BNW
01/24/2020 1024 42803
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Aluminum
7429-90-5 6020B
110
40
10
ug/L
1
Antimony
7440-36-0 6020B
ND
2.0
0.50
ug/L
1
Arsenic
7440-38-2 6020B
ND
2.0
1.3
ug/L
1
Barium
7440-39-3 6020B
50
5.0
1.3
ug/L
1
Beryllium
7440-41-7 6020B
ND
0.40
0.15
ug/L
1
Cadmium
7440-43-9 6020B
ND
0.50
0.13
ug/L
1
Chromium
7440-47-3 6020B
ND
5.0
1.3
ug/L
1
Cobalt
7440-48-4 6020B
3.1 J
5.0
1.3
ug/L
1
Copper
7440-50-8 6020B
ND
5.0
1.3
ug/L
1
Iron
7439-89-6 6020B
170
50
13
ug/L
1
Lead
7439-92-1 6020B
ND
1.0
0.25
ug/L
1
Manganese
7439-96-5 6020B
310
5.0
1.3
ug/L
1
Nickel
7440-02-0 6020B
ND
5.0
1.3
ug/L
1
Selenium
7782-49-2 6020B
ND
5.0
1.3
ug/L
1
Silver
7440-22-4 6020B
ND
1.0
0.25
ug/L
1
Thallium
7440-28-0 6020B
ND
0.50
0.15
ug/L
1
Vanadium
7440-62-2 6020B
ND
5.0
2.5
ug/L
1
LOQ = Limit of Quantitation
B = Detected in the method blank
E = Quantitation of compound exceeded the calibration range
DL = Detection Limit
NO = Not detected at or above the DL
N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time
W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 45 of 91
Client: County of Rutherford Laboratory ID:VA23042-008
Description: B-44 Matrix: Aqueous
Date Sampled:01/22/2020 1150
Date Received:01/23/2020
ICP-MS Metals
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 01/27/2020 1737 BNW 01/24/2020 1024 42803
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 46 of 91
Client: County of Rutherford Laboratory ID:VA23042-009
Description: TB Matrix: Aqueous
Date Sampled:01/22/2020
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/24/2020 2311 JTH 42874
2 5030B 8260D 1 01/28/2020 0114 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Acetone
67-64-1
8260D
ND
20
5.0
ug/L
Acetonitrile
75-05-8
8260D
ND
50
15
ug/L
Acrolein
107-02-8
8260D
ND
20
4.0
ug/L
Acrylonitrile
107-13-1
8260D
ND
20
0.80
ug/L
Benzene
71-43-2
8260D
ND
1.0
0.40
ug/L
Bromochloromethane
74-97-5
8260D
ND
1.0
0.40
ug/L
Bromodichloromethane
75-27-4
8260D
ND
1.0
0.40
ug/L
Bromoform
75-25-2
8260D
ND
1.0
0.40
ug/L
Bromomethane (Methyl bromide)
74-83-9
8260D
ND
2.0
0.40
ug/L
2-Butanone (MEK)
78-93-3
8260D
ND
10
2.0
ug/L
Carbon disulfide
75-15-0
8260D
ND
1.0
0.40
ug/L
Carbon tetrachloride
56-23-5
8260D
ND
1.0
0.40
ug/L
2-Chloro-1,3-Butadiene (Chloroprene)
126-99-8
8260D
ND
5.0
1.0
ug/L
Chlorobenzene
108-90-7
8260D
ND
1.0
0.40
ug/L
Chloroethane
75-00-3
8260D
ND
2.0
0.40
ug/L
Chloroform
67-66-3
8260D
ND
1.0
0.40
ug/L
Chloromethane (Methyl chloride)
74-87-3
8260D
ND
1.0
0.50
ug/L
3-Chloropropene (Allyl chloride)
107-05-1
8260D
ND
5.0
1.0
ug/L
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
ND
1.0
0.40
ug/L
Dibromochloromethane
124-48-1
8260D
ND
1.0
0.40
ug/L
1,2-Dibromoethane (EDB)
106-93-4
8260D
ND
1.0
0.40
ug/L
Dibromomethane (Methylene bromide)
74-95-3
8260D
ND
1.0
0.40
ug/L
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
ND
2.0
0.50
ug/L
1,2-Dichlorobenzene
95-50-1
8260D
ND
1.0
0.40
ug/L
1,3-Dichlorobenzene
541-73-1
8260D
ND
1.0
0.40
ug/L
1,4-Dichlorobenzene
106-46-7
8260D
ND
1.0
0.40
ug/L
Dichlorodifluoromethane
75-71-8
8260D
ND
2.0
0.60
ug/L
1,1-Dichloroethane
75-34-3
8260D
ND
1.0
0.40
ug/L
1,2-Dichloroethane
107-06-2
8260D
ND
1.0
0.40
ug/L
1,1-Dichloroethene
75-35-4
8260D
ND
1.0
0.40
ug/L
cis- 1,2-Dichloroethene
156-59-2
8260D
ND
1.0
0.40
ug/L
trans- 1,2-Dichloroethene
156-60-5
8260D
ND
1.0
0.40
ug/L
1,2-Dichloropropane
78-87-5
8260D
ND
1.0
0.40
ug/L
1,3-Dichloropropane
142-28-9
8260D
ND
1.0
0.40
ug/L
2,2-Dichloropropane
594-20-7
8260D
ND
1.0
0.40
ug/L
1,1-Dichloropropene
563-58-6
8260D
ND
2.0
0.40
ug/L
cis- 1,3-Dichloropropene
10061-01-5
8260D
ND
1.0
0.40
ug/L
trans- 1,3-Dichloropropene
10061-02-6
8260D
ND
1.0
0.40
ug/L
Ethyl methacrylate
97-63-2
8260D
ND
5.0
0.40
ug/L
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 47 of 91
Client: County of Rutherford Laboratory ID:VA23042-009
Description: TB Matrix: Aqueous
Date Sampled:01/22/2020
Date Received:01/23/2020
Volatile Organic Compounds by GC/MS
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 01/24/2020 2311 JTH 42874
2 5030B 8260D 1 01/28/2020 0114 JTH 43038
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethylbenzene
100-41-4
8260D
ND
1.0
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
ND
10
2.0
ug/L
1
Isobutyl alcohol
78-83-1
8260D
ND
50
12
ug/L
1
Methacrylonitrile
126-98-7
8260D
ND
5.0
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
ND
5.0
0.40
ug/L
1
Methyl methacrylate
80-62-6
8260D
ND
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
ND
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
ND
1.0
0.40
ug/L
1
Propionitrile (Ethyl cyanide)
107-12-0
8260D
ND
20
4.0
ug/L
1
Styrene
100-42-5
8260D
ND
1.0
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
ND
1.0
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
ND
1.0
0.40
ug/L
1
Tetrahydrofuran
109-99-9
8260D
ND
5.0
1.0
ug/L
1
Toluene
108-88-3
8260D
ND
1.0
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
ND
1.0
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
ND
1.0
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
ND
1.0
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
ND
1.0
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
ND
1.0
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
ND
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
ND
1.0
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
ND
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2
Acceptance
Surrogate
Q % Recovery Limits
Q % Recovery
Limits
Bromofluorobenzene
102 70-130
103
70-130
1,2-Dichloroethane-d4
98 70-130
102
70-130
Toluene-d8
102 70-130
105
70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 48 of 91
QC Summary
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 49 of 91
Inorganic non-metals - MB
Sample ID: VQ42779-001 Matrix: Aqueous
Batch: 42779
Analytical Method: SM 2540C-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
TDS ND 1 25 25 mg/L 01/23/2020 2354
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 50 of 91
Inorganic non-metals - LCS
Sample ID: VQ42779-002 Matrix: Aqueous
Batch: 42779
Analytical Method: SM 2540C-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
TDS 1500 1500 1 100 90-110 01/23/2020 2354
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 51 of 91
Inorganic non-metals - MB
Sample ID: VQ43147-001 Matrix: Aqueous
Batch: 43147
Analytical Method: SM 2320B-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Alkalinity ND 1 20 20 mg/L 01/28/20201640
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
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Page 52 of 91
Inorganic non-metals - LCS
Sample ID: VQ43147-002 Matrix: Aqueous
Batch: 43147
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 94 1 94 90-110 01/28/20201657
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
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Page 53 of 91
Inorganic non-metals - Duplicate
Sample ID: VA23042-001 DU Matrix: Aqueous
Batch: 43147
Analytical Method: SM 2320B-2011
Sample
Amount Result % RPD
Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date
Alkalinity ND ND 1 0.00 20 01/28/20201719
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 54 of 91
Inorganic non-metals - MB
Sample ID: VQ43547-001 Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate ND 1 1.0 0.20 mg/L 01/29/2020 2308
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 55 of 91
Inorganic non-metals - LCS
Sample ID: VQ43547-002 Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 19 1 96 80-120 01/29/2020 2327
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 56 of 91
Inorganic non-metals - MS
Sample ID: VA23042-002MS Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate ND 20 19 1 97 80-120 01/30/2020 0023
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 57 of 91
Inorganic non-metals - MSD
Sample ID: VA23042-002MD Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfate ND 20 19 1 95 2.6 80-120 20 01/30/2020 0042
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 58 of 91
Inorganic non-metals - MS
Sample ID: VA23042-008MS Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate ND 20 19 1 95 80-120 01/30/2020 0332
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 59 of 91
Inorganic non-metals - MSD
Sample ID: VA23042-008MD Matrix: Aqueous
Batch: 43547
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfate ND 20 18 1 92 3.8 80-120 20 01/30/2020 0351
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 60 of 91
Inorganic non-metals - MB
Sample ID: VQ43548-001 Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride ND 1 1.0 0.20 mg/L 01/29/2020 2308
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 61 of 91
Inorganic non-metals - LCS
Sample ID: VQ43548-002 Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 24 1 119 80-120 01/29/2020 2327
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 62 of 91
Inorganic non-metals - MS
Sample ID: VA23042-002MS Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 1.9 20 22 1 101 80-120 01/30/2020 0023
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 63 of 91
Inorganic non-metals - MSD
Sample ID: VA23042-002MD Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Chloride 1.9 20 21 1 98 2.8 80-120 20 01/30/2020 0042
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 64 of 91
Inorganic non-metals - MS
Sample ID: VA23042-008MS Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 2.5 20 22 1 98 80-120 01/30/2020 0332
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 65 of 91
Inorganic non-metals - MSD
Sample ID: VA23042-008MD Matrix: Aqueous
Batch: 43548
Analytical Method: 9056A
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Chloride 2.5 20 22 1 95 2.8 80-120 20 01/30/2020 0351
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 66 of 91
Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: VQ42777-001 Matrix: Aqueous
Batch:42777 Prep Method: 5030E
Analytical Method: 8260D (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane ND 1 3.0 1.0 ug/L 01/23/20201844
Acceptance
Surrogate Q % Rec Limit
1,2-Dichloroethane-d4 96 40-170
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 67 of 91
Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: VQ42777-002
Matrix: Aqueous
Batch:42777
Prep Method: 5030E
Analytical Method: 8260D (SIM)
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
1,4-Dioxane
50
48
1 96 70-130 01/23/20201708
Surrogate
Q % Rec
Acceptance
Limit
1,2-Dichloroethane-d4 99 40-170
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 68 of 91
Volatile Organic Compounds by GC/MS - MB
Sample ID: VQ42874-001 Matrix: Aqueous
Batch:42874 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
ND
1
20
5.0
ug/L
01/24/2020 2202
Acetonitrile
ND
1
50
15
ug/L
01/24/2020 2202
Acrolein
ND
1
20
4.0
ug/L
01/24/2020 2202
Acrylonitrile
ND
1
20
0.80
ug/L
01/24/2020 2202
Benzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Bromochloromethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Bromodichloromethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Bromoform
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Bromomethane (Methyl bromide)
ND
1
2.0
0.40
ug/L
01/24/2020 2202
2-Butanone (MEK)
ND
1
10
2.0
ug/L
01/24/2020 2202
Carbon disulfide
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Carbon tetrachloride
ND
1
1.0
0.40
ug/L
01/24/2020 2202
2-Chloro-1,3-Butadiene (Chloroprene)
ND
1
5.0
1.0
ug/L
01/24/2020 2202
Chlorobenzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Chloroethane
ND
1
2.0
0.40
ug/L
01/24/2020 2202
Chloroform
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Chloromethane (Methyl chloride)
ND
1
1.0
0.50
ug/L
01/24/2020 2202
3-Chloropropene (Allyl chloride)
ND
1
5.0
1.0
ug/L
01/24/2020 2202
1,2-Dibromo-3-chloropropane (DBCP)
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Dibromochloromethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,2-Dibromoethane (EDB)
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Dibromomethane (Methylene bromide)
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,2-Dichlorobenzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,3-Dichlorobenzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,4-Dichlorobenzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Dichlorodifluoromethane
ND
1
2.0
0.60
ug/L
01/24/2020 2202
1,1-Dichloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,2-Dichloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,1-Dichloroethene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
cis- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
trans- 1,2-Dichloroethene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,2-Dichloropropane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,3-Dichloropropane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
2,2-Dichloropropane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,1-Dichloropropene
ND
1
2.0
0.40
ug/L
01/24/2020 2202
cis- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
trans- 1,3-Dichloropropene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Ethyl methacrylate
ND
1
5.0
0.40
ug/L
01/24/2020 2202
Ethylbenzene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
2-Hexanone
ND
1
10
2.0
ug/L
01/24/2020 2202
Isobutyl alcohol
ND
1
50
12
ug/L
01/24/2020 2202
Methacrylonitrile
ND
1
5.0
2.0
ug/L
01/24/2020 2202
Methyl iodide (lodomethane)
ND
1
5.0
0.40
ug/L
01/24/2020 2202
Methyl methacrylate
ND
1
5.0
0.40
ug/L
01/24/2020 2202
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 69 of 91
Volatile Organic Compounds by GC/MS - MB
Sample ID: VQ42874-001 Matrix: Aqueous
Batch:42874 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
4-Methyl-2-pentanone
ND
1
10
2.0
ug/L
01/24/2020 2202
Methylene chloride
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Propionitrile (Ethyl cyanide)
ND
1
20
4.0
ug/L
01/24/2020 2202
Styrene
ND
1
1.0
0.41
ug/L
01/24/2020 2202
1,1,1,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,1,2,2-Tetrachloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Tetrachloroethene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Tetrahydrofuran
ND
1
5.0
1.0
ug/L
01/24/2020 2202
Toluene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,1,1-Trichloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,1,2-Trichloroethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Trichloroethene
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Trichlorofluoromethane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
1,2,3-Trichloropropane
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Vinyl acetate
ND
1
5.0
1.2
ug/L
01/24/2020 2202
Vinyl chloride
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Xylenes (total)
ND
1
1.0
0.40
ug/L
01/24/2020 2202
Surrogate Q % Rec Acceptance
Limit
Bromofluorobenzene 107 70-130
1,2-Dichloroethane-d4 104 70-130
Toluene-d8 106 70-130
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 70 of 91
Volatile Organic Compounds by GC/MS - LCS
Sample ID: VQ42874-002 Matrix: Aqueous
Batch:42874 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
97
1
97
60-140
01/24/2020 2033
Acetonitrile
500
450
1
90
60-140
01/24/2020 2033
Acrolein
500
590
1
119
60-140
01/24/2020 2033
Acrylonitrile
100
100
1
101
70-130
01/24/2020 2033
Benzene
50
49
1
97
70-130
01/24/2020 2033
Bromochloromethane
50
46
1
92
70-130
01/24/2020 2033
Bromodichloromethane
50
46
1
92
70-130
01/24/2020 2033
Bromoform
50
44
1
89
70-130
01/24/2020 2033
Bromomethane (Methyl bromide)
50
45
1
91
70-130
01/24/2020 2033
2-Butanone (MEK)
100
110
1
105
70-130
01/24/2020 2033
Carbon disulfide
50
40
1
80
70-130
01/24/2020 2033
Carbon tetrachloride
50
43
1
86
70-130
01/24/2020 2033
2-Chloro-1,3-Butadiene (Chloroprene)
50
48
1
96
70-130
01/24/2020 2033
Chlorobenzene
50
47
1
94
70-130
01/24/2020 2033
Chloroethane
50
49
1
97
70-130
01/24/2020 2033
Chloroform
50
47
1
94
70-130
01/24/2020 2033
Chloromethane (Methyl chloride)
50
51
1
101
60-140
01/24/2020 2033
3-Chloropropene (Allyl chloride)
50
49
1
98
70-130
01/24/2020 2033
1,2-Dibromo-3-chloropropane (DBCP)
50
46
1
93
70-130
01/24/2020 2033
Dibromochloromethane
50
45
1
90
70-130
01/24/2020 2033
1,2-Dibromoethane (EDB)
50
47
1
94
70-130
01/24/2020 2033
Dibromomethane (Methylene bromide)
50
46
1
92
70-130
01/24/2020 2033
1,2-Dichlorobenzene
50
49
1
97
70-130
01/24/2020 2033
1,3-Dichlorobenzene
50
48
1
95
70-130
01/24/2020 2033
1,4-Dichlorobenzene
50
47
1
94
70-130
01/24/2020 2033
Dichlorodifluoromethane
50
50
1
101
60-140
01/24/2020 2033
1,1-Dichloroethane
50
49
1
97
70-130
01/24/2020 2033
1,2-Dichloroethane
50
46
1
92
70-130
01/24/2020 2033
1,1-Dichloroethene
50
43
1
87
70-130
01/24/2020 2033
cis- 1,2-Dichloroethene
50
48
1
97
70-130
01/24/2020 2033
trans- 1,2-Dichloroethene
50
48
1
96
70-130
01/24/2020 2033
1,2-Dichloropropane
50
50
1
100
70-130
01/24/2020 2033
1,3-Dichloropropane
50
47
1
94
70-130
01/24/2020 2033
2,2-Dichloropropane
50
41
1
82
70-130
01/24/2020 2033
1,1-Dichloropropene
50
48
1
95
70-130
01/24/2020 2033
cis- 1,3-Dichloropropene
50
49
1
98
70-130
01/24/2020 2033
trans- 1,3-Dichloropropene
50
46
1
92
70-130
01/24/2020 2033
Ethyl methacrylate
50
51
1
102
70-130
01/24/2020 2033
Ethylbenzene
50
49
1
97
70-130
01/24/2020 2033
2-Hexanone
100
100
1
101
70-130
01/24/2020 2033
Isobutyl alcohol
500
490
1
98
60-140
01/24/2020 2033
Methacrylonitrile
250
250
1
101
70-130
01/24/2020 2033
Methyl iodide (lodomethane)
50
42
1
84
70-130
01/24/2020 2033
Methyl methacrylate
50
49
1
99
70-130
01/24/2020 2033
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 71 of 91
Volatile Organic Compounds by GC/MS - LCS
Sample ID: VQ42874-002 Matrix: Aqueous
Batch:42874 Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
4-Methyl-2-pentanone
100
100
1
103
70-130
01/24/2020 2033
Methylene chloride
50
44
1
88
70-130
01/24/2020 2033
Propionitrile (Ethyl cyanide)
500
520
1
105
70-130
01/24/2020 2033
Styrene
50
50
1
100
70-130
01/24/2020 2033
1,1,1,2-Tetrachloroethane
50
47
1
94
70-130
01/24/2020 2033
1,1,2,2-Tetrachloroethane
50
50
1
100
70-130
01/24/2020 2033
Tetrachloroethene
50
45
1
90
70-130
01/24/2020 2033
Tetrahydrofuran
50
46
1
92
70-130
01/24/2020 2033
Toluene
50
47
1
94
70-130
01/24/2020 2033
1,1,1-Trichloroethane
50
44
1
88
70-130
01/24/2020 2033
1,1,2-Trichloroethane
50
47
1
93
70-130
01/24/2020 2033
Trichloroethene
50
47
1
94
70-130
01/24/2020 2033
Trichlorofluoromethane
50
46
1
92
70-130
01/24/2020 2033
1,2,3-Trichloropropane
50
47
1
94
70-130
01/24/2020 2033
Vinyl acetate
50
51
1
103
60-140
01/24/2020 2033
Vinyl chloride
50
51
1
102
70-130
01/24/2020 2033
Xylenes (total)
100
96
1
96
70-130
01/24/2020 2033
Surrogate Q % Rec Acceptance
Limit
Bromofluorobenzene 92 70-130
1,2-Dichloroethane-d4 92 70-130
Toluene-d8 94 70-130
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 72 of 91
Volatile Organic Compounds by GC/MS - MB
Sample ID: VQ43038-001 Matrix: Aqueous
Batch:43038 Prep Method: 5030E
Analytical Method: 8260D
Parameter Result Q Dil LOQ DL Units Analysis Date
trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 01/27/2020 2124
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 103 70-130
1,2-Dichloroethane-d4 102 70-130
Toluene-d8 104 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 73 of 91
Volatile Organic Compounds by GC/MS - LCS
Sample ID: VQ43038-002
Matrix: Aqueous
Batch:43038
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
trans- 1,4-Dichloro-2-butene
50
50
1 100 70-130 01/27/2020 2002
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 96 70-130
Toluene-d8 98 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 74 of 91
ICP-MS - MB
Sample ID: VQ42803-001 Matrix: Aqueous
Batch:42803 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 01/24/2020 1024
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Dissolved Aluminum
ND
1
40
10
ug/L
01/27/2020 1238
Dissolved Antimony
ND
1
2.0
0.50
ug/L
01/27/2020 1238
Dissolved Arsenic
ND
1
2.0
1.3
ug/L
01/27/2020 1238
Dissolved Barium
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Beryllium
ND
1
0.40
0.15
ug/L
01/27/2020 1238
Dissolved Cadmium
ND
1
0.50
0.13
ug/L
01/27/2020 1238
Dissolved Chromium
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Cobalt
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Copper
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Iron
ND
1
50
13
ug/L
01/27/2020 1238
Dissolved Lead
ND
1
1.0
0.25
ug/L
01/27/2020 1238
Dissolved Manganese
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Nickel
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Selenium
ND
1
5.0
1.3
ug/L
01/27/2020 1238
Dissolved Silver
ND
1
1.0
0.25
ug/L
01/27/2020 1238
Dissolved Thallium
ND
1
0.50
0.15
ug/L
01/27/2020 1238
Dissolved Vanadium
ND
1
5.0
2.5
ug/L
01/27/2020 1238
Dissolved Zinc
ND
1
10
2.5
ug/L
01/27/2020 1238
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 75 of 91
ICP-MS - LCS
Sample ID: VQ42803-002
Matrix: Aqueous
Batch:42803
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 01/24/2020 1024
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Dissolved Aluminum
100
97
1 97
80-120
01/27/2020 1244
Dissolved Antimony
100
97
1 97
80-120
01/27/2020 1244
Dissolved Arsenic
100
100
1 102
80-120
01/27/2020 1244
Dissolved Barium
100
99
1 99
80-120
01/27/2020 1244
Dissolved Beryllium
100
96
1 96
80-120
01/27/2020 1244
Dissolved Cadmium
100
96
1 96
80-120
01/27/2020 1244
Dissolved Chromium
100
94
1 94
80-120
01/27/2020 1244
Dissolved Cobalt
100
94
1 94
80-120
01/27/2020 1244
Dissolved Copper
100
94
1 94
80-120
01/27/2020 1244
Dissolved Iron
1000
980
1 98
80-120
01/27/2020 1244
Dissolved Lead
100
98
1 98
80-120
01/27/2020 1244
Dissolved Manganese
100
99
1 99
80-120
01/27/2020 1244
Dissolved Nickel
100
97
1 97
80-120
01/27/2020 1244
Dissolved Selenium
100
98
1 98
80-120
01/27/2020 1244
Dissolved Silver
100
99
1 99
80-120
01/27/2020 1244
Dissolved Thallium
100
98
1 98
80-120
01/27/2020 1244
Dissolved Vanadium
100
93
1 93
80-120
01/27/2020 1244
Dissolved Zinc
100
96
1 96
80-120
01/27/2020 1244
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 76 of 91
ICP-MS Metals - MB
Sample ID: VQ42803-001 Matrix: Aqueous
Batch:42803 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 01/24/2020 1024
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Aluminum
ND
1
40
10
ug/L
01/27/20201238
Antimony
ND
1
2.0
0.50
ug/L
01/27/20201238
Arsenic
ND
1
2.0
1.3
ug/L
01/27/20201238
Barium
ND
1
5.0
1.3
ug/L
01/27/20201238
Beryllium
ND
1
0.40
0.15
ug/L
01/27/20201238
Cadmium
ND
1
0.50
0.13
ug/L
01/27/20201238
Chromium
ND
1
5.0
1.3
ug/L
01/27/20201238
Cobalt
ND
1
5.0
1.3
ug/L
01/27/20201238
Copper
ND
1
5.0
1.3
ug/L
01/27/20201238
Iron
ND
1
50
13
ug/L
01/27/20201238
Lead
ND
1
1.0
0.25
ug/L
01/27/20201238
Manganese
ND
1
5.0
1.3
ug/L
01/27/20201238
Nickel
ND
1
5.0
1.3
ug/L
01/27/20201238
Selenium
ND
1
5.0
1.3
ug/L
01/27/20201238
Silver
ND
1
1.0
0.25
ug/L
01/27/20201238
Thallium
ND
1
0.50
0.15
ug/L
01/27/20201238
Vanadium
ND
1
5.0
2.5
ug/L
01/27/20201238
Zinc
ND
1
10
2.5
ug/L
01/27/20201238
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 77 of 91
ICP-MS Metals - LCS
Sample ID: VQ42803-002
Matrix: Aqueous
Batch:42803
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 01/24/2020 1024
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Aluminum
100
97
1 97
80-120
01/27/20201244
Antimony
100
97
1 97
80-120
01/27/20201244
Arsenic
100
100
1 102
80-120
01/27/20201244
Barium
100
99
1 99
80-120
01/27/20201244
Beryllium
100
96
1 96
80-120
01/27/20201244
Cadmium
100
96
1 96
80-120
01/27/20201244
Chromium
100
94
1 94
80-120
01/27/20201244
Cobalt
100
94
1 94
80-120
01/27/20201244
Copper
100
94
1 94
80-120
01/27/20201244
Iron
1000
980
1 98
80-120
01/27/20201244
Lead
100
98
1 98
80-120
01/27/20201244
Manganese
100
99
1 99
80-120
01/27/20201244
Nickel
100
97
1 97
80-120
01/27/20201244
Selenium
100
98
1 98
80-120
01/27/20201244
Silver
100
99
1 99
80-120
01/27/20201244
Thallium
100
98
1 98
80-120
01/27/20201244
Vanadium
100
93
1 93
80-120
01/27/20201244
Zinc
100
96
1 96
80-120
01/27/20201244
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 78 of 91
ICP-MS Metals - MS
Sample ID: VA23042-007MS
Matrix: Aqueous
Batch:42803
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 01/24/2020 1024
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Aluminum
2600
100
7000
N 1
4380
70-130
01/27/20201708
Antimony
0.81
100
94
1
93
70-130
01/27/20201708
Arsenic
1.7
100
100
1
98
70-130
01/27/20201708
Barium
43
100
150
1
105
70-130
01/27/20201708
Beryllium
ND
100
97
1
97
70-130
01/27/20201708
Cadmium
ND
100
97
1
97
70-130
01/27/20201708
Chromium
2.1
100
95
1
93
70-130
01/27/20201708
Cobalt
ND
100
92
1
92
70-130
01/27/20201708
Copper
1.7
100
94
1
92
70-130
01/27/20201708
Iron
1300
1000
3100
N 1
181
70-130
01/27/20201708
Lead
1.7
100
96
1
94
70-130
01/27/20201708
Manganese
58
100
160
1
99
70-130
01/27/20201708
Nickel
2.3
100
95
1
93
70-130
01/27/20201708
Selenium
ND
100
96
1
96
70-130
01/27/20201708
Silver
ND
100
96
1
96
70-130
01/27/20201708
Thallium
ND
100
95
1
95
70-130
01/27/20201708
Vanadium
6.3
100
98
1
92
70-130
01/27/20201708
Zinc
4.2
100
100
1
97
70-130
01/27/20201708
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 79 of 91
ICP-MS Metals - MSD
Sample ID: VA23042-007MD
Matrix: Aqueous
Batch:42803
Prep Method:
3005A
Analytical Method: 6020B
Prep Date: 01/24/2020 1024
Sample
Spike
Amount
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec % RPD
Limit
Limit
Analysis Date
Aluminum
2600
100
7600
N 1
4960
8.0
70-130
20
01/27/20201713
Antimony
0.81
100
95
1
94
1.1
70-130
20
01/27/20201713
Arsenic
1.7
100
100
1
103
4.3
70-130
20
01/27/20201713
Barium
43
100
150
1
109
2.3
70-130
20
01/27/20201713
Beryllium
ND
100
99
1
99
1.7
70-130
20
01/27/20201713
Cadmium
ND
100
98
1
98
1.3
70-130
20
01/27/20201713
Chromium
2.1
100
95
1
93
0.38
70-130
20
01/27/20201713
Cobalt
ND
100
94
1
94
2.0
70-130
20
01/27/20201713
Copper
1.7
100
96
1
95
2.6
70-130
20
01/27/20201713
Iron
1300
1000
3300
N 1
196
4.7
70-130
20
01/27/20201713
Lead
1.7
100
97
1
96
1.4
70-130
20
01 /27/2020 1713
Manganese
58
100
160
1
103
2.0
70-130
20
01/27/20201713
Nickel
2.3
100
97
1
95
2.4
70-130
20
01/27/20201713
Selenium
ND
100
98
1
98
1.6
70-130
20
01/27/20201713
Silver
ND
100
97
1
97
1.3
70-130
20
01/27/20201713
Thallium
ND
100
95
1
95
0.41
70-130
20
01/27/20201713
Vanadium
6.3
100
99
1
93
1.4
70-130
20
01/27/20201713
Zinc
4.2
100
100
1
98
0.99
70-130
20
01/27/20201713
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 80 of 91
ICP-MS Metals - MB
Sample ID: VQ44149-001 Matrix: Aqueous
Batch:44149 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 02/06/2020 1710
Parameter
Result Q
Dil
LOQ
DL
Units
Analysis Date
Aluminum
ND
1
40
10
ug/L
02/07/20201343
Antimony
ND
1
2.0
0.50
ug/L
02/07/20201343
Arsenic
ND
1
2.0
1.3
ug/L
02/07/20201343
Barium
ND
1
5.0
1.3
ug/L
02/07/20201343
Beryllium
ND
1
0.40
0.15
ug/L
02/07/20201343
Cadmium
ND
1
0.50
0.13
ug/L
02/07/20201343
Chromium
ND
1
5.0
1.3
ug/L
02/07/20201343
Cobalt
ND
1
5.0
1.3
ug/L
02/07/20201343
Copper
ND
1
5.0
1.3
ug/L
02/07/20201343
Iron
ND
1
50
13
ug/L
02/07/20201343
Lead
ND
1
1.0
0.25
ug/L
02/07/20201343
Manganese
ND
1
5.0
1.3
ug/L
02/07/20201343
Nickel
ND
1
5.0
1.3
ug/L
02/07/20201343
Selenium
ND
1
5.0
1.3
ug/L
02/07/20201343
Silver
ND
1
1.0
0.25
ug/L
02/07/20201343
Thallium
ND
1
0.50
0.15
ug/L
02/07/20201343
Vanadium
ND
1
5.0
2.5
ug/L
02/07/20201343
Zinc
ND
1
10
2.5
ug/L
02/07/20201343
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 81 of 91
ICP-MS Metals - LCS
Sample ID: VQ44149-002
Matrix: Aqueous
Batch:44149
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 02/06/2020 1710
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Aluminum
100
100
1 100
80-120
02/07/20201350
Antimony
100
97
1 97
80-120
02/07/20201350
Arsenic
100
100
1 102
80-120
02/07/20201350
Barium
100
97
1 97
80-120
02/07/20201350
Beryllium
100
100
1 102
80-120
02/07/20201350
Cadmium
100
100
1 100
80-120
02/07/20201350
Chromium
100
93
1 93
80-120
02/07/20201350
Cobalt
100
96
1 96
80-120
02/07/20201350
Copper
100
98
1 98
80-120
02/07/20201350
Iron
1000
930
1 93
80-120
02/07/20201350
Lead
100
100
1 103
80-120
02/07/20201350
Manganese
100
95
1 95
80-120
02/07/20201350
Nickel
100
97
1 97
80-120
02/07/20201350
Selenium
100
98
1 98
80-120
02/07/20201350
Silver
100
100
1 102
80-120
02/07/20201350
Thallium
100
100
1 101
80-120
02/07/20201350
Vanadium
100
96
1 96
80-120
02/07/20201350
Zinc
100
100
1 103
80-120
02/07/20201350
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 82 of 91
CVAA -MB
Sample ID: VQ42828-001 Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury ND 1 0.00020 0.000091 mg/L 01/28/20201115
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 83 of 91
CVAA - LCS
Sample ID: VQ42828-002 Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0020 0.0021 1 106 80-120 01/28/20201118
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 84 of 91
CVAA - MS
Sample ID: VA23042-003MS Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury ND 0.0020 0.0021 1 103 85-115 01/28/20201146
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 85 of 91
CVAA - MSD
Sample ID: VA23042-003MD Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Mercury ND 0.0020 0.0021 1 103 0.20 85-115 20 01/28/20201148
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 86 of 91
CVAA -MB
Sample ID: VQ42828-001 Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Parameter Result Q Dil LOQ DL Units Analysis Date
Dissolved Mercury ND 1 0.00020 0.000091 mg/L 01/28/2020 1115
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 87 of 91
CVAA - LCS
Sample ID: VQ42828-002 Matrix: Aqueous
Batch:42828 Prep Method:
Analytical Method: 7470A Prep Date: 01/27/2020 1455
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Dissolved Mercury 0.0020 0.0021 1 106 80-120 01/28/2020 1118
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
ND = Not detected at or above the DL
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 88 of 91
Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 89 of 91
SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 90 of 91
SHEALY ENVIRONMENTAL SERVICES, INC.
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No
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14. Were alI samples nOXived within YL Lhe hoId%o.9 timc or 49 hours, whiehr,,c,•cwM fi,,0
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com
Page 91 of 91
APPENDIX C
FIGURE 2 AND TABLES
FROM THE MAY 2018
SEMI-ANNUAL SAMPLING REPORT
BY SCARLETT GEOPHYSICAL CONSULTING
P.C.
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. • ��`� \a �,• t� l� ��!!♦`/'+�Y�i�11.111+f..fd'�. +'�'�'t � � f ♦`' .�� r � .,,,,
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. ""'`. i ,,. '..»r"'""'�+....... '`tb ` + J / T t . •t r t Y I.tft. a • � \ r ` i ' / �."'r" .
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� s. t i � � � �� J',I+ff"di►•.,,'tYlrr��; a•r�fi:+ / +b �% � + .p'�
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op
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LEGEND:
.� i r v` �' r,a �. MON�'MRING WELL,
FROMltrflt+L�'a r1 '► f nc \,. f j 1 ; % '' ''�y \ ` t
7 � ttf ! Ji /' � • A � If �, � � t ! � 1. � `i f � � �� � 4~` � � �
SURFACE WATER SAMPLE LOCATION A.
DAVED GARRETT & ASSOCIATES
GROUNDWATER Mid ITORiNG i ,+ t_.%;' �..-- w...... p ..,,; `�.� Y GROUNDWATER CONTOUR
GROUNDWATER 924
WITH PHASE I CDLF AMENDMENTS \,,•I♦.,r. _..`�,
�"• ,� /ir' / �..-�. ` . -. � f 1 �. •___'' ✓'1 ?�. �, •, GRUUT`tDWArtER FLOW DIRECnON
..�. , f• ,� NNA -�.
SHEET 20., DRAWING NO. "i �----•-- t-.��.� `-`..,�' �.- � �`-
�. �BU AIR L=
,.+''^`� ) •�7 �... r ~ � r` ..-"`' * 'ire1 200"
TABLE 1
SUMMARY OF MONITORING WELL DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
Well
No.
Elevation (ft)
Depth
of
Well
(ft)
Static Water Levels3
Sep 19-Sep 22, 2016
May 3-9, 2017
Oct 2-5, 2017
May 10-17, 2018
Land
Surface
Top of
Casing'
Top of
Screen
Bottom of
Screen
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
8103-MW-2
995.43
995.51
945.43
935.43
60.0
41.82
953.69
46.25
949.26
47.27
948.24
46.89
948.62
8103-MW-3
859.62
860.28
822.62
812.62
47.0
34.35
825.93
33.89
826.39
1 34.61
825.67
32.09
828.19
8103-MW-4
849.72
851.03
809.72
799.72
50.0
36.22
814.81
36.06
814.97
36.48
814.55
31.91
819.12
8103-MW-6
833.43
834.90
810.93
795.93
37.5
31.14
803.76
31.88
803.02
32.33
802.57
31.36
803.54
8103-MW-7
890.51
892.70
851.51
836.51
54.0
36.57
856.13
37.82
854.88
37.33
855.37
34.93
857.77
8103-MW-8
857.86
860.31
828.36
813.36
44.5
42.54
817.77
43.49
816.82
44.26
816.05
39.89
820.42
8103-MW-9
864.97
867.25
842.47
827.47
37.5
33.44
833.81
34.00
833.25
35.65
831.60
34.02
833.23
8103-MW-10A
834.73
837.23
743.73
733.73
101.0
6.135
831.10'
4.505
832.73'
5.665
831.57'
6.475
830.76'
8103-MW-10B
834.50
836.15
802.50
797.50
37.0
9.93
826.22
8.92
827.23
10.01
826.14
9.11
827.04
8103-MW-10C
834.50
836.19
823.50
818.50
16.0
9.72
826.47
8.65
827.54
9.78
826.41
8.88
827.31
8103-MW-10D
834.73
837.23
778.73
768.73
66.0
10.99
826.24
9.88
827.35
11.16
826.07
9.96
827.27
8103-MW-11A
815.39
817.18
780.39
770.39
45.0
9.26
807.92
8.62
808.56
9.22
807.96
8.26
808.92
8103-MW-11B
816.32
817.72
806.32
796.32
20.0
10.44
807.28
9.65
808.07
10.31
807.41
9.45
808.27
8103-MW-12
884.33
886.68
849.33
834.33
50.0
46.26
840.42
33.10
853.58
38.90
847.78
32.27
854.41
8103-MW-13
960.80
962.90
887.80
872.80
88.0
77.75
885.15
82.05
880.85
82.50
880.40
81.21
881.69
8103-MW-14
867.08
869.48
849.68
834.68
32.4
23.54
845.94
23.51
845.97
24.80
844.68
20.67
848.81
8103-MW-15
887.58
889.54
1 839.58
849.58
1 38.0
35.04
854.50
31.41
858.13
35.38
854.16
29.10
860.44
Notes
Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC,
December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering
and Geology, Raleigh, NC, 2002 and 1999, respectively
2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C.
3 Water levels taken from top of casing
4 Depth of well measured from land surface
5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day)
RuthCent_0518.xis
TABLE 2
GROUND AND SURFACE WATER SAMPLING FIELD DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17. 2018
Parameter
Sample Location
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10A
8103-MW-10B
Temperature
16.86°C
16.2°C
15.64°C
20.26°C
16.4°C
18.01°C
15.83°C
NS
15.9°C
Conductivity
100 pmhos/cm
956 pmhos/cm
726 pmhos/cm
2080 pmhos/cm
950 pmhos/cm
622 pmhos/cm
35.0 pmhos/cm
NS
97.4 pmhos/cm
pH
8.84
6.56
5.85
6.44
6.65
6.06
5.47
NS
6.38
ORP
83 mV
NA
25 mV
-54 mV
NA
124 mV
157 mV
NS
NA
DO
4.52 mg/I
NA
0.00 mg/I
1.44 mg/I
NA
2.00 mg/I
3.68 mg/I
NS
NA
Turbidity
78.1 NTU
NA
15.4 NTU
10.7 NTU
NA
1.5 NTU
2.3 NTU
NS
NA
Parameter
Sample Location
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
Temperature
15.2°C
15.30°C
15.13°C
14.6°C
17.9°C
17.7°C
17.1 °C
16.4°C
17.6°C
Conductivity
101.9 pmhos/cm
336 pmhos/cm
855 pmhos/cm
186.5 mhos/cm
823 pmhos/cm
190.5 pmhos/cm
210.0 pmhos/cm
220.0 pmhos/cm
102.9 pmhos/cm
pH
6.37
5.95
5.60
5.96
6.63
5.75
5.92
5.97
7.26
ORP
NA
61 mV
-74 mV
NA
NA
NA
NA
NA
NA
DO
NA
0.00 mg/I
0.00 mg/I
NA
NA
NA
NA
NA
NA
Turbidity
NA
0.1 NTU
5.4 NTU
NA
NA
NA
NA
NA
NA
Parameter
Sample Location
8103-SW-3
8103-SW-4
8103-SW-5A
Temperature
20.3°C
18.7°C
17.7°C
Conductivity
65.6 pmhos/cm
53.4 pmhos/cm
63.1 pmhos/cm
pH
7.37
7.29
6.93
ORP
NA
NA
NA
DO
NA
NA
NA
Turbidity
NA
NA
NA
NS - Not sampled
NA - Not analyzed
RuthCent_0518.x1s
TABLE 3
GROUNDWATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 C
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Well Number
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
ANTIMONY
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
6.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
10.0
BARIUM
31.8 J
161.0
178.0
379.0
148.0
206.0
49.7 J
46.8 J
700.0
100
BERYLLIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
4.0
1.0
CADMIUM
BQL
0.36 J
0.7 J
0.5 J
0.2 J
BQL
BQL
BQL
2.0
1.0
CHROMIUM
22.2
3.0 J
4.6 J
3.6 J
18.7
1.7 J
2.7 J
2.7 J
10.0
10.0
COBALT
BQL
0.7 J
1.2 J
`62:5
5.3 J'
BQL
BQL
BQL
1.0
10.0
COPPER
8.2 J
7.0 J
15.8
9.2 J
10.6
5.1 J
3.9 J
4.5 J
1,000.0
10.0
LEAD
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
15.0
10.0
NICKEL
1.5 J
1.1 J
1.3 J
19.0 J
8.6 J
0.8 J
BQL
BQL
100.0
50.0
SELENIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
10.0
SILVER
BQL
3.8 J
1.6 J
2.6 J
1.8 J
BQL
1.7 J
BQL
20.0
10.0
THALLIUM
BQL
BQL
BQL
184
BQL
BQL
BQL
BQL
0.28
5.5
VANADIUM
5.3J =
1.8J=
15.4J =
2.2J
124.4J
1.0J
BQL
0.81 =
0.3
25.0
ZINC
248.0
248.0
69.1
170.0
301.0
143.0
156.0
191.0
1,000.0
10.0
Parameter
Well Number
15A NCAC 2L
Standard for Class
GAGroundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
ANTIMONY
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
6.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
10.0
BARIUM
767.0
189.0
166.0
415.0
178.0
159.0
1,130.0
680.0
700.0
100
BERYLLIUM
1.9
BQL
BQL
2.0 J
BQL
BQL
3.2
2.1
4.0
1.0
CADMIUM
BQL
BQL
BQL
BQL
0.3 J
BQL
BQL
BQL
2.0
1.0
CHROMIUM
65.1
BQL
0.9 J
-46.4
2.1 J
1.8 J
156.0 „ -
53.9
10.0
10.0
COBALT
36.5 ,.
27.8 ,
11.5
,20J
6.8 J.
3.04
.34.6.
29.4
1.0
10.0
COPPER
47.4
5.2 J
4.6 J
27.0
10.0
6.1 J
71.9
63.9
1,000.0
10.0
LEAD
18.3
BQL
BQL
15.1
BQL
BQL
16.3
30.4
15.0
10.0
NICKEL
39.6 J
4.4 J
4.0 J
28.8
1.8 J
3.2 J
33.5 J
30.6 J
100.0
50.0
SELENIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
10.0
SILVER
BQL
1.4 J
3.6 J
BQL
1.8 J
BQL
BQL
BQL
20.0
10.0
THALLIUM
BQL
BQL
4.6 J
BQL
7.8
BQL
BQL
BQL
0.28
5.5
VANADIUM
1 129.0
1 BQL
1 1.2 J
1 89.3
3.4 J
2.4 J
146.0
108.0
0.3
25.0
ZINC
1 305.0
1 230.0
1 26.0
1 227.0
1 284.0
1 263.0
1 302.0
1 272.0
1 1,000.0
1
10.0
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
J - Estimated results. Present but below SWSL
NS - Not Sampled
* - Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCent_0518.xis
TABLE 4
GROUNDWATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
Solid Waste
Section Limit
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GA Groundwater
Standard
(SWSL)
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
5.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
1.0
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
0.18
3.0
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
1.0
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
0.91
BQL
BQL
BQL
BQL
1.51
BQL
BQL
BQL
BQL
BQL
BQL
6.0
5.0
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2J
BQL
BQL
BQL
BQL
BQL
BQL
7.0
5.0
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
1.0
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
I BQL
BQL
BQL
BQL
BQL
BQL
I BQL
BQL
I BQL
BQL
0.04
13.0
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.02
1.0
1,2-DICHLOROBENZENE
BQL
BQL
BQL
0.51
BQL
BQL
BQL
BQL
BQL
BQL
0.11
BQL
BQL
BQL
BQL
BQL
20.0
5.0
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
0.11
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
1.0
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
25:3
BQL
BQL
0.1 J
BQL
BQL
BQL
BQL
BQL
BQL
0.6
1.0
1,4-DICHLOROBENZENE
BQL
BQL
1.4
7.9
BQL
0.11
BQL
BQL
BQL
22
3.1
BQL
BQL
BQL
BQL
BQL
6.0
1.0
2-BUTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4,000.0
100.0
2-HEXANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
40.0
50.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
560.0
100.0
ACETONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
7.1J
BQL
BQL
6000.0
100.0
ACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
'
200.0
BENZENE
BQL
BQL
BQL
1.4
BQL
BQL
BQL
BQL
BQL
1.2
0.2 J
BQL
0.2 J
0.6 J
BQL
BQL
1.0
1.0
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
0.6
3.0
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
1.0
BROMOFORM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
3.0
BROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
10.0
CARBON DISULFIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
700.0
100.0
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
1.0
CHLOROBENZENE
BQL
BQL
1.3J
453
0.2J
SOL
BQL
I BQL
BQL
2.0J
5.5
BQL
BQL
0.11
BQL
BQL
50.0
3.0
CHLOROETHANE
BQL
BQL
0.2 J
BQL
BQL
BQL
BQL
BQL
BQL
0.4 J
0.5 J
BQL
BQL
0.61
BQL
BQL
3,000.0
10.0
CHLOROFORM
BQL
BQL
BQL
BQL
BQL
BQL
0.3J
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
5.0
CHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3.0
1.0
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2 J
BQL
10.1
0.11
BQL
BQL
0.6 J
0.3 J
BQL
70.0
5.0
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
1.0
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.41
3.0
DIBROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
10.0
ETHYLBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
1.0
METHYL IODIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
5.0
1.0
STYRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
1.0
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.2
BQL
BQL
BQL
BQL
BQL
BQL
0.7
1.0
TOLUENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
1.0
TOTAL XYLENES
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.51
BQL
BQL
500.0
5.0
TRANS-I,2-DICHLOROETIENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
5.0
TRANS-I,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
1.0
TRANS-I,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
TRICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
12
BQL
BQL
BQL
BQL
BQL
BQL
3.0
1.0
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2J
BQL
2,000.0
1.0
VINYL ACETATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
88.0
50.0
VINYL CHLORIDE
BQL
BQL
SOL
0.4 J
SOL
BQL
BQL
BQL
BQL
0.3 J
0.4 J
BQL
BQL
0.2 J
BQL
BQL
0.03
1.0
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
J - Estimated result. Present but below SWSL
B - Lab blank contamination
NS - Not Sampled
Standard not established
• Shaded -11' cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• For constituents that are not naturally occurring and have no established standards, the SW SLs are the Standards
RuthCent_0518.As
TABLE 5
GROUNDWATER SAMPLING RESULTS
APPENDIX II TRIGGERED CONSTITUENTS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
SW-846
Method
Well Number
15A NCAC 2L
Standard for Class
GAGroundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
1,3-Dichlorobenzene
8260
BQL
0.6 J
BQL
BQL
BQL
BQL
BQL
BQL
0.2 J
BQL
200.0
5.0
1,3-Dichloropropane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
1.0
Dichlorodifluoromethane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1,000.0
5.0
4,4'- DDD
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
*
0.1
4,4'- DDT
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
*
0.1
alpha-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.006
0.05
beta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
0.05
delta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
0.05
Endrin
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.0
0.1
gamma-BHC (Lindane)
1 8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.03
*
0.05
Mercury
1 7470
0.72
0.11 J
0.05 J
0.06 J
0.05 J
0.02 J
0.06 J
0.09 J
0.03 J
0.06 J
1.0
0.2
Notes:
All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
J - Estimated result. Present but below SWSL
• * - Standard not established
Shaded, cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
NA - Not analyzed
RuthCent_0518.xis
TABLE 6
GROUNDWATER SAMPLING RESULTS
APPENDIX II INORGANIC CONSTITUENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Laboratory
Method
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
ANTIMONY
SW 846 6010
BQL
BQL
BQL
BQL
BQL
1.0
6.0
ARSENIC
SW 846 6010
BQL
BQL
BQL
BQL
BQL
10.0
10.0
BARIUM
SW 846 6010
178.0
379.0
148.0
206.0
49.7 J
700.0
100.0
BERYLLIUM
SW 846 6010
BQL
BQL
BQL
BQL
BQL
4.0
1.0
CADMIUM
SW 846 6010
0.7 J
0.5 J
0.2 J
BQL
BQL
2.0
1.0
CHROMIUM
SW 846 6010
4.6 J
3.6 J
18.7
1.7 J
2.7 J
10.0
10.0
COBALT
SW 846 6010
1.2 J
62.5
5.3 J
BQL
BQL
1.0
10.0
COPPER
SW 846 6010
15.8
9.2 J
10.6
5.1 J
3.9 J
1,000.0
10.0
CYANIDE
EPA 335.2
BQL
BQL
BQL
BQL
BQL
70.0
10.0
LEAD
SW 846 6010
4.3 J
BQL
BQL
BQL
BQL
15.0
10.0
MERCURY
SW 846 7470
0.72
0.11 J
0.05 J
0.06 J
0.05 J
1.0
0.2
NICKEL
SW 846 6010
1.3 J
19.0 J
8.6 J
0.8 J
BQL
100.0
50.0
SELENIUM
SW 846 6010
BQL
6.8 J
BQL
BQL
BQL
20.0
10.0
SILVER
SW 846 6010
1.6 J
2.6 J
1.8 J
BQL
1.7 J
20.0
10.0
SULFIDE
EPA 376.1
BQL
BQL
BQL
BQL
BQL
1,000.0
THALLIUM
SW 846 6010
BQL
18.4
BQL
BQL
BQL
0.28
5.5
TIN
SW 846 6010
BQL
BQL
BQL
BQL
BQL
2,000.0
100.0
VANADIUM
SW 846 6010
15.4 J
2.2 J
24.4 J
1.0 J
BQL
0.3
25.0
ZINC
SW 846 6010
69.1
BQL
301.0
143.0
156.0
1,000.0
10.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed the 2L or Groundwater Protection Standards
• INS - Not Sampled
RuthCent_0518.xis
TABLE 7
GROUNDWATER SAMPLING RESULTS
APPENDIX II VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17. 2018
Parameters
Sample Locations
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
1.0
5.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
200.0
*
1.0
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
0.2
0.18
3.0
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
0.6
1.0
1,1-DICHLOROETHANE
BQL
BQL
0.9 J
BQL
BQL
6.0
5.0
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
7.0
*
5.0
1,1-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
5.0
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
0.005
*
1.0
1,2,4-TRICHLOROBENZENE'
BQL
BQL
BQL
BQL
BQL
70.0
70.0
10
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
0.04
*
13.0
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
BQL
0.02
1.0
1,2-DICHLOROBENZENE
BQL
0.5 J
BQL
BQL
BQL
20.0
*
5.0
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
0.1 J
0.4
1.0
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
25.3
0.6
*
1.0
1,3-DICHLOROBENZENE
BQL
0.6 J
BQL
BQL
BQL
200.0
5.0
1,3-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
*
1.0
1,4-DICHLOROBENZENE
1.4
7.9 .
BQL
0.1 J
BQL
6.0
1.0
2,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
*
15.0
2-BUTANONE
BQL
BQL
BQL
BQL
BQL
4,000.0
100.0
2-HEXANONE
BQL
BQL
BQL
BQL
BQL
40.0
50.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
BQL
560.0
100.0
ACETONE
BQL
BQL
BQL
BQL
BQL
6,000.0
*
100.0
ACETONITRILE
BQL
BQL
BQL
BQL
BQL
42.0
55.0
ACROLEIN
BQL
BQL
BQL
BQL
BQL
*
4.0
53.0
ACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
200.0
ALLYL CHLORIDE 3-chloro ro ene
BQL
BQL
BQL
BQL
BQL
*
10.0
BENZENE
BQL
1.4 '
BQL
BQL
BQL
1.0
1.0
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
0.6
3.0
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
0.6
1.0
BROMOFORM
BQL
BQL
BQL
BQL
BQL
4.0
*
3.0
BROMOMETHANE
BQL
BQL
BQL
BQL
BQL
10.0
10.0
CARBON DISULFIDE
BQL
BQL
BQL
BQL
BQL
700.0
*
100.0
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
BQL
0.3
1.0
CHLOROBENZENE
1.3 J
45.3
0.2 J
BQL
BQL
50.0
*
3.0
CHLOROETHANE
0.2 J
BQL
BQL
BQL
BQL
3,000.0
*
10.0
CHLOROFORM
BQL
BQL
BQL
BQL
0.3 J
70.0
*
5.0
CHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
3.0
1.0
CHLOROPRENE
BQL
BQL
BQL
BQL
BOIL
*
*
20.0
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
70.0
5.0
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
0.4
*
1.0
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
0.4
0.41
3.0
DIBROMOMETHANE
BQL
BQL
BQL
BQL
BQL
70.0
10.0
DICHLORODIFLOUROMETHANE
BQL
BQL
BQL
BQL
BQL
1,000.0
5.0
ETHYL BENZENE
BQL
BQL
BQL
BQL
BQL
600.0
*
1.0
ETHYL METHACRYLATE
BQL
BQL
BQL
BQL
BQL
10.0
ISOBUTYL ALCOHOL
BQL
BQL
BQL
BQL
BQL
*
100.0
METHACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
100.0
METHYL IODIDE
BQL
BQL
BQL
BQL
BQL
*
10.0
METHYL METHACRYLATE
BQL
BQL
BQL
BQL
BQL
25.0
30.0
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
BQL
5.0
*
1.0
PROPIONITRILE
BQL
BQL
BQL
BQL
BQL
150.0
STYRENE
BQL
BQL
BQL
BQL
BQL
70.0
*
1.0
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
BQL
0.7
1.0
TOLUENE
BQL
BQL
BQL
BQL
BQL
600.0
*
1.0
TOTAL XYLENES
BQL
BQL
BQL
BQL
BQL
500.0
*
5.0
TRANS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
100.0
*
5.0
TRANS-I,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
0.4
1.0
TRANS-1,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
BQL
*
100.0
TRICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
3.0
1.0
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
BQL
2,000.0
*
1.0
VINYL ACETATE
BQL
BQL
BQL
BQL
BQL
88.0
50.0
VINYL CHLORIDE
BQL
0.4 J
BQL
BQL
BQL
0.03
*
1.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below reporting limit.
• * - Standard not established
• Shaded cells ' denote concentrations that equal or exceed 21 or Groundwater Protection Standards
• For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
• ' Analyzed by SW-846 Method 8270
• NS - Not Sampled
RuthCent_0518.xls
TABLE 8
GROUNDWATER SAMPLING RESULTS
APPENDIX II SEMI -VOLATILE CONSTITUENTS BY SW-846 METHOD 8270
CENTRAL SANITARY LANDFILL (# 81-03), RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
0,0,0-TRIETHYL PHOSPHOROTHIOATE
BQL
BQL
BQL
BQL
BQL
10.0
0,0-DIETHYL o-2-PYROZINYL
BQL
BQL
BQL
BQL
BQL
20.0
1,2,4,5-TETRACHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
2.0
10.0
1,2,4-TRICHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
70.0
70.0
10.0
1,4-NAPHTHOQUINONE
BQL
BQL
BQL
BQL
BQL
*
10.0
1-NAPHTHYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
2,3,4,6-TETRACHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
200.0
10.0
2,4,5-TRICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
*
63.0
10.0
2,4,6-TRICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
*
4.0
10.0
2,4-DICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
0.98
10.0
2,4-DIMETHYLPHENOL
BQL
BQL
BQL
BQL
BQL
100.0
10.0
2,4-DINITROPHENOL
BQL
BQL
BQL
BQL
BQL
*
50.0
2,4-DINITROTOLUENE
BQL
BQL
BQL
BQL
BQL
*
0.1
10.0
2,6-DICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
10.0
2,6-DINITROTOLUENE
BQL
BQL
BQL
BQL
BQL
10.0
2-ACETYLAMINOFLUORENE
BQL
BQL
BQL
BQL
BQL
20.0
2-CHLORONAPHTHALENE
BQL
BQL
BQL
BQL
BQL
10.0
2-CHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
0.4
10.0
2-METHYLNAPHTHALENE
BQL
BQL
BQL
BQL
BQL
30.0
10.0
2-METHYLPHENOL (O-CRESOL)
BQL
BQL
BQL
BQL
BQL
400.0
10.0
2-NAPHTHYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
2-NITROANILINE
BQL
BQL
BQL
BQL
BQL
50.0
2-NITROPHENOL
BQL
BQL
BQL
BQL
BQL
10.0
3 & 4-METHYLPHENOL M & P-CRESOL
BQL
BQL
BQL
BQL
BQL
400/40
10.0
3,3'-DICHLOROBENZIDINE
BQL
BQL
BQL
BQL
BQL
20.0
3,3'-DIMETHYLBENZIDINE
BQL
BQL
BQL
BQL
BQL
10.0
3-METHYLCHOLANTHRENE
BQL
BQL
BQL
BQL
BQL
10.0
3-NITROANILINE
BQL
BQL
BQL
BQL
BQL
50.0
4,6-DINITRO-o-CREOSOL
BQL
BQL
BQL
BQL
BQL
50.0
4-AMINOBIPHENYL
BQL
BQL
BQL
BQL
BQL
*
20.0
4-BROMOPHENYL PHENYL ETHER
BQL
BQL
BQL
BQL
BQL
10.0
4-CHLORO-3-METHYLPHENOL
BQL
BQL
BQL
BQL
BQL
*
20.0
4-CHLOROANILINE
BQL
BQL
BQL
BQL
BQL
*
20.0
4-CHLOROPHENYL PHENYL ETHER
BQL
BQL
BQL
BQL
BQL
*
"
10.0
4-NITROANILINE
BQL
BQL
BQL
BQL
BQL
*
20.0
4-NITROPHENOL
BQL
BQL
BQL
BQL
BQL
*
50.0
5-NITRO-0-TOLUIDINE
BQL
BQL
BQL
BQL
BQL
10.0
7,12-DIMETHYLBENZAANTHRACENE
BQL
BQL
BQL
BQL
BQL
10.0
ACENAPHTHENE
BQL
3.4 J
BQL
BQL
BQL
80.0
10.0
ACENAPHTHYLENE
BQL
BQL
BQL
BQL
BQL
200.0
10.0
ACETOPHENONE
BQL
BQL
BQL
BQL
BQL
700.0
10.0
ANTHRACENE
BQL
BQL
BQL
BQL
BQL
2,000.0
10.0
BENZO A ANTHRACENE
BQL
BQL
BQL
BQL
BQL
0.05
10.0
BENZO A PYRENE
BQL
BQL
BQL
BQL
BQL
0.005
10.0
BENZO B FLUORANTHENE
BQL
BQL
BQL
BQL
BQL
0.05
10.0
BENZO G,H,I PERYLENE
BQL
BQL
BQL
BQL
BQL
200.0
10.0
BENZO K FLUORANTHENE
BQL
BQL
BQL
BQL
BQL
0.5
10.0
BENZYL ALCOHOL
BQL
BQL
BQL
BQL
BQL
*
700.0
20.0
BIS(2-CHLORO-1-METHYLETHYL)ETHERZ
BQL
BQL
BQL
BQL
BQL
10.0
BIS 2-CHLOROETHOXY METHANE
BQL
BQL
BQL
BQL
BQL
10.0
BIS 2-CHLOROETHYL ETHER
BQL
BQL
BQL
BQL
BQL
0.031
10.0
BIS 2-ETHYLHEXYL PHTHALATE
BQL
BQL
BQL
BQL
1.8 J
3.0
*
15.0
BUTYL BENZYL PHTHALATE'
BQL
BQL
BQL
BQL
BQL
1,000.0
10.0
CHLOROBENZILATE
BQL
BQL
BQL
BQL
BQL
10.0
CHRYSENE
BQL
BQL
BQL
BQL
BQL
5.0
10.0
DIALLATE (TOTAL)
BQL
BQL
BQL
BQL
BQL
10.0
RuthCent_0518.xls
TABLE 8 (CONT.)
Parameter
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
DIBENZ A,H ANTHRACENE
BQL
BQL
BQL
BQL
BQL
0.005
10.0
DIBENZOFURAN
BQL
BQL
BQL
BQL
BQL
28.0
10.0
DIETHYL PHTHALATE
BQL
BQL
BQL
BQL
BQL
6,000.0
6,000.0
DIMETHYL PHTHALATE
BQL
BQL
BQL
BQL
BQL
10.0
DI-N-BUTYLPHTHALATE
BQL
BQL
BQL
BQL
BQL
700.0
10.0
DI-N-OCTYLPHTHALATE
BQL
BQL
BQL
BQL
BQL
100.0
10.0
DIPHENYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
ETHYL METHANESULFONATE
BQL
BQL
BQL
BQL
BQL
20.0
FLUORANTHENE
BQL
BQL
BQL
BQL
BQL
300.0
10.0
FLUORENE
BQL
BQL
BQL
BQL
BQL
300.0
10.0
HEXACHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
0.02
10.0
HEXACHLOROBUTADIENE
BQL
BQL
BQL
BQL
BQL
0.4
0.44
10.0
HEXACHLOROCYCLOPENTADIENE
BQL
BQL
BQL
BQL
BQL
50.0
10.0
HEXACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
2.5
10.0
HEXACHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
10.0
INDENO 1,2,3-CD PYRENE
BQL
BQL
BQL
BQL
BQL
0.05
10.0
ISODRIN
BQL
BQL
BQL
BQL
BQL
20.0
ISOPHORONE
BQL
BQL
BQL
BQL
BQL
40.0
10.0
ISOSAFROLE
BQL
BQL
BQL
BQL
BQL
10.0
m-DINITROBENZENE4
BQL
BQL
BQL
BQL
BQL
20.0
METHAPYRILENE
BQL
BQL
BQL
BQL
BQL
100.0
METHYL METHANESULFONATE
BQL
BQL
BQL
BQL
BQL
10.0
N-NITROSODIETHYLAMINE
BQL
BQL
BQL
BQL
BQL
20.0
N-NITROSODIMETHYLAMINE
BQL
BQL
BQL
BQL
BQL
0.0007
10.0
N-NITROSODI-N-BUTYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
N-NITROSODI-N-PROPYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
N-NITROSODIPHENYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
N-NITROSOMETHYLETHYLAMINE
BQL
BQL
BQL
BQL
BQL
10.0
N-NITROSOPIPERIDINE
BQL
BQL
BQL
BQL
BQL
20.0
N-NITROSOPYRROLI DINE
BQL
BQL
BQL
BQL
BQL
10.0
NAPHTHALENE
BQL
BQL
BQL
BQL
BQL
6.0
10.0
NITROBENZENE
BQL
BQL
BQL
BQL
BQL
10.0
O-TOLUIDINE
BQL
BQL
BQL
BQL
BQL
10.0
P-DIMETHYLAMINOAZOBENZENE
BQL
BQL
BQL
BQL
BQL
10.0
PENTACHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
10.0
PENTACHLORONITROBENZENE
BQL
BQL
BQL
BQL
BQL
20.0
PHENACETIN
BQL
BQL
BQL
BQL
BQL
20.0
PHENANTHRENE
BQL
BQL
BQL
BQL
BQL
200.0
10.0
PHENOL
BQL
BQL
BQL
BQL
BQL
30.0
10.0
p-PHENYLENEDIAMINES
BQL
BQL
BQL
BQL
BQL
10.0
PRONAMIDE
BQL
BQL
BQL
BQL
BQL
10.0
PYRENE
BQL
BQL
BQL
BQL
BQL
200.0
10.0
SAFROLE
BQL
BQL
BQL
BQL
BQL
10.0
sym-TRINITROBENZENE
BQL
BQL
BQL
BQL
BQL
10.0
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
J - Estimated result. Present but below SWSL
* - Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
- 4,6-Dinitro-o-creosole = 4,6-Dinitro-2-methylphenol = 2-Methyl-4,6-dinitrophenol
2 - Bis (2-chloro-l-methylethyl) ether = 2,2-Oxybis(1-chloropropane) = Bis (2-chloroisopropyl) ether
a - Butyl benzyl phthalate = Benzylbutylphthalate
4 - m-Dinitrobenzene = 1,3 Dinitrobenzene
e - p-Phenylenediamine = 1,4 Phenylenediamine
e - sym-Trinitrobenzene = 1,3,5-Trinitrobenzene
NS - Not Sampled
RuthCent_0518.x1s
TABLE 9
GROUNDWATER SAMPLING RESULTS
APPENDIX II ORGANOPHOSPHORUS PESTICIDES BY SW-846 METHOD 8270
APPENDIX II HERBICIDES BY SW-846 METHODS 8151A and 8270D
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
PARAMETER
WELL NUMBER
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9
PESTICIDES
0,0,0-TRIETHYL PHOSPHOROTHIOATE
BQL
BQL
BQL
BQL
BQL
10.0
DIMETHOATE
BQL
BQL
BQL
BQL
BQL
20.0
DISULFOTON
BQL
BQL
BQL
BQL
BQL
0.3
10.0
FAMPHUR
BQL
BQL
BQL
BQL
BQL
20.0
KEPONE
BQL
BQL
BQL
BQL
BQL
20.0
METHYL PARATHION
BQL
BQL
BQL
BQL
BQL
10.0
PARATHION
BQL
BQL
BQL
BQL
BQL
10.0
PHORATE
BQL
BQL
BQL
BQL
BQL
1.0
10.0
THIONAZIN
BQL
BQL
BQL
BQL
BQL
20.0
2,4,5-T
BQL
BQL
BQL
BQL
BQL
2.0
2,4,5-TP (SILVEX)
BQL
BQL
BQL
BQL
BQL
50.0
2,4-D
BQL
BQL
BQL
BQL
BQL
70.0
2.0
DINOSEB
BQL
BQL
BQL
BQL
BQL
7.0
1.0
PENTACHLOROPHENOL
I BQL
I BQL
I BQL
I BQL
I BQL
1 0.3
1
25.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• Shaded " cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
• 1 - Thionazin = 0,0-Diethyl o-2-pyrozinyl
RuthCent_0518.xls
TABLE 10
GROUNDWATER SAMPLING RESULTS
APPENDIX II PESTICIDES/PCBS BY SW-846 METHOD 8081/8082
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
PARAMETER
WELL NUMBER
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
4,4'-DDD
BQL
BQL
BQL
BQL
BQL
0.1
0.1
4,4'-DDE
BQL
BQL
BQL
BQL
BQL
0.1
4,4'-DDT
BQL
BQL
BQL
BQL
BQL
0.1
0.1
ALDRIN
BQL
BQL
BQL
BQL
BQL
0.002
0.05
ALPHA-BHC
BQL
BQL
BQL
BQL
BQL
0.006
0.05
AROCLOR 1016
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1221
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1232
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1242
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1248
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1254
BQL
BQL
BQL
BQL
BQL
0.09
2.0
AROCLOR 1260
BQL
BQL
BQL
BQL
BQL
0.09
2.0
BETA-BHC
BQL
BQL
BQL
BQL
BQL
0.019
0.05
CHLORDANE TOTAL
BQL
BQL
BQL
BQL
BQL
0.1
0.5
DELTA-BHC
BQL
BQL
BQL
BQL
BQL
0.019
0.05
DIELDRIN
BQL
BQL
BQL
BQL
BQL
0.002
0.075
ENDOSULFANI
BQL
BQL
BQL
BQL
BQL
40.0
0.1
ENDOSULFAN II
BQL
BQL
BQL
BQL
BQL
42.0
0.1
ENDOSULFAN SULFATE
BQL
BQL
BQL
BQL
BQL
40.0
0.1
ENDRIN
BQL
BQL
BQL
BQL
BQL
2.0
0.1
ENDRIN ALDEHYDE
BQL
BQL
BQL
BQL
BQL
2.0
0.1
GAMMA-BHC LINDANE
BQL
BQL
BQL
BQL
BQL
0.03
0.05
HEPTACHLOR
BQL
BQL
BQL
BQL
BQL
0.008
0.05
HEPTACHLOR EPDXIDE
BQL
BQL
BQL
BQL
BQL
0.004
0.075
METHOXYCHLOR
BQL
BQL
BQL
BQL
BQL
40.0
1.0
TOXAPHENE
BQL
BQL
BQL
BQL
BQL
0.03
1.5
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
• INS - Not Sampled
RuthCent_0518.xls
TABLE 11
GROUNDWATER SAMPLING RESULTS
MONITORED NATURAL ATTENUATION PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
Solid Waste
Section Limit
(SWSL)
8103-MW-2
8103-MW-4
8103-MW-6
8103-MW-8
8103-MW-9
8103-MW-10D
8103-MW-11A
ACETIC ACID
AM23G
BQL
BQL
BQL
120 u /L
BQL
BQL
BQL
ALKALINITY
SM 2320B
52,000 ug/L
359,000 ug/L
471,000 ug/L
79,400 ug/L
28,400 ug/L
161,000 ug/L
367,000 ug/L
BOD
SM 5210B
BQL
BQL
BQL
2,910 ug/L
BQL
BQL
BQL
BUTYRIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
CARBON DIOXIDE
SM 4500 CO2 C
20,200 u /L
173,000 u /L
248,000 u /L
61,600 u /L
62,500 u /L
130,000 u /L
290,000 u /L
CHLORIDE
SM 4500 Cl C
2,620 ug/L
18,400 ug/L
336,000 u /L
115,000 ug/L
4,720 ug/L
10,500 ug/L
42,000 ug/L
250,000.0
COD
EPA 410.4
BQL
BQL
74,000 u /L
BQL
BQL
BQL
20,000 u /L
ETHANE
AM20GAX
BQL
BQL
0.75 ug/L
BQL
BQL
BQL
0.15 ug/L
ETHENE
AM20GAX
BQL
BQL
0.59 u /L
BQL
BQL
BQL
0.15 u /L
HEXANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
HYDROGEN
AM20GAX
3.4 nM
N/A
3.3 nM
3.2 nM
3.2 nM
2.6 Nm
2.1 u /L
i-HEXANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
i-PENTANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
IRON
EPA 200.7
3,190 u /L
2,010 u /L
4,370 u /L
188 ug/L (J)
68.5 ug/L (J)
866 u /L
4,010 u /L
300.0
*
300.0
LACTIC ACID & HIBA
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHANE
AM20GAX
BQL
5.3 ug/L
75 ug/L
BQL
BQL
410 ug/L
200 ug/L
NITRATE -NITROGEN
SM 4500 NO3 E
67 u /L
80 u /L
65 u /L J
6,370 u /L J
BQL
BQL
BQL
10,000.0
*
10,000.0
PENTANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PROPIONOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PYRUVIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SULFATE
SM 4500 SO4 E
BQL
BQL
BQL
16,600 u /L J
BQL
BQL
BQL
250,000.0
*
250,000.0
SULFIDE
EPA 376.1
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
*
1,000.0
TOTAL ORGANIC CARBON
SM 5310C
BQL
3,240 ug/L
28,100 ug/L
3,590 ug/L
BQL
BQL
6,320 ug/L
Notes:
• ug/L - micrograms per Liter (ppb)
• nM - nano Moles
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• * - Standard not established
• NS - Not sampled
• Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• Analyzed approximately 2 hours out of hold time
Ruth Cent_0518.As
TABLE 12
GROUNDWATER AND SURFACE WATER SAMPLING RESULTS
C & D PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
15A NCAC 2B
Standard for Class
B,C Surface Water
Solid Waste
Section Limit
(SWSL)
8103-MW-2
8103-MW-3
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5A
ALKALINITY
SM 2320B
52,000
340,000
359,000
82,200
40,600
14,100
35,900
17,000
11,300
15,100
ALUMINUM
SW 846 6010C
1,580.0
308.0
867.0
423.0
47,300.0
50,000.0
2,400.0
500.0
767.0
788.0
3,500
CHLORIDE
SM 4500 Cl C
2,620.0
52,500.0
15,200.0
4,720.0
8,920.0
8,920.0
6,820.0
3,670.0
4,720.0
3,150.0
250,000.0
*
230,000
IRON
EPA200.7
3,190:0
`1,070:0
-3,960.-0
`2,580.0
43,700.0 '
43,100:0 "
-3,240.0
773.0
1,070.0
1,020.0
300.0
1,000
300.0
MANGANESE
SW 846 6010
34.7 J
262.0
5,3MID
779.0
`1,640.0
1,480.0
128.0
29.7 J
32.7 J
27.6 J
50.0
50.0
MERCURY
SW 846 7470
0.06 J
0.04 J
0.02 J
0.07 J
0.14 J
0.03 J
0.05 J
0.01 J
-0.16 J
0.04 J
1.0
0.012
0.200
SULFATE
SM 4500 SO4 E
BQL
41,400 J
14,800 J
BQL
44,700 J
61,500 J
10,300 J
BQL
BQL
BQL
250,000.0
250,000.0
TDS
SM 2540 C
72,000
552,000
508,000
121,000
162,000
156,000
73,000
40,000
55,000
55,000
500,000.0
TETRAHYDROFURAN
SW 846 8260B
BQL
1.6
1.9
BQL
1.1
BQL
BQL
BQL
BQL
BQL
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
J - Estimated result. Present but below SWSL
* - Standard/Limit not established
NS - Not sampled
I'l - Action Level
Shaded cells denote concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels
RuthCent_0518.xis
TABLE 13
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
0
r. r. ..
r r r: rrr
r• r rrr
�aaaa��a��aaaaaaaa
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichl..propane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• ' - Appendix I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list
• 4 - Aluminum added to C&D constituent list
RuthCent_0518.xis
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
04/11/2001
09/12-13/2001
04/03/2002
06/27/2002
10/02/2002
04/02-03/2003
09/03/2003
04/06/2004
10/27/2004
04/05/2005
09/08/2005
04/04-05/2006
10/26-27/2006
5/22-23/2007
10/23-26/2007
05/06-08/2008
09/22-25/2008
8103-MW-2
I
I
I
I
I
I
I
I
I
I
I
1
I, MINA
I, MNA, C&D
I, MNA, C&D
8103-MW-3
I
I
I
I
I
I
I
I
I
I
I
I
I
1
1, C&D
1, C&D
8103-MW-4
I'll
1, 11 t
I'll
I, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MINA
1, 11(t), MNA
8103-MW-6
I'll
1, 11 t
I'll
I, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MINA
1, 11(t), MNA
8103-MW-7
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
8103-MW-8
I'll
I, II t
I'll
I, II t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MNA
I, 11(t), MNA
8103-MW-9
I'll
I, II t
I'll
I, II t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
I, 11, MNA
1, 11(t), MNA
8103-MW-10A
8103-MW-10B
I,IIt)
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-10C
I,IIt)
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-10D
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
1,IIt,MNA
1,IIt,MNA
I,11t,MNA
8103-MW-11A
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I, lilt), MNA
I, lilt), MNA
I,11t,MNA
8103-MW-11B
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-12
I
I
I
I
I
I
I
I
I
I
I
1
I, C&D
I, C&D
8103-MW-13
I
I
I
I
I
I
I
I
I
I
I
1
I, C&D
I, C&D
8103-MW-14
I, C&D
I, C&D
8103-MW-15
1, C&D
1, C&D
I - denotes well was sampled for Appendix I constituents on this date
II - denotes well was sampled for Appendix II constituents on this date
II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
MNA - denotes well was sampled for Monitored Natural Attenuation constituents
C&D - denotes well was sampled for Construction and Demolition constituents
• ' - Appendix I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list
4 - Aluminum added to C&D constituent list
RuthCent_0518.xis
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
05/18-05/21, 2009
10/07-10/09, 2009
05/17-05/20, 2010
09/20-09/23, 2010
04/25-05/02, 2011
09/27-09/30, 2011
04/30-05/03, 2012
09/25-10/03, 2012
04/15-18/2013
09/23-09/28, 2013
04/28-05/01, 2014
09/29-10/04, 2014
04/27-05/02, 2015
09/28-10/07, 2015
04/26-05/05, 2016
8103-MW-2
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D°
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&Ds
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
8103-MW-3
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-4
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-6
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-7
1,11
I, II t
1,11
I, II t
1,11
I, II(t)s, MNA
8103-MW-8
1 I, II, MNA
I, 11(t), MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
1 I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-9
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)z, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-10A
8103-MW-10B
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(t)s
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10C
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(t)s
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10D
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t)s, MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
8103-MW-11A
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t)s, MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
8103-MW-11 Bi
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(tp
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-12
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-13
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-14
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-15
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• 1 - Appendix I volatiles only
• 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• 4 - Aluminum added to C&D constituent list
5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list
6 - Tetrahydrofuran added to C&D constituent list
RuthCent_0518.xls
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
Well
09/19-09/22, 2016
05/03-05/09, 2017
10/02-10/05, 2017
05/10-05/17, 2018
8103-MW-2
I, MNA, C&D
I, MINA, C&D
I, MNA, C&D
I, MINA, C&D
8103-MW-3
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-4
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
8103-MW-6
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
8103-MW-7
I, II t
1,11
I, II t
1,11
8103-MW-8
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
8103-MW-9
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
8103-MW-10A
8103-MW-10B
I, II t
I, II t
I, II t
I, II t
8103-MW-10C
I, II t
I, II t
I, II t
I, II t
8103-MW-10D
I, 11(t), MINA
I, 11(t), MNA
I, 11(t), MINA
I, 11(t), MNA
8103-MW-11A
I, 11(t), MNA
I, 11(t), MINA
I, 11(t), MNA
I, 11(t), MINA
t
I, II t
I, II t
I, It
83-MW-11B
-MW-1
I, C&D
I, C&D
I, C&D
I, C&D
-MW-13 3
I, C&D
I, C&D
I, C&D
I, C&D3-MW-13
4
I, C&D
I, C&D
I, C&D
I, C&D
.JO
I, C&D
I, C&D
I, C&D
I, C&D
• I - denotes well was sampled for Appendix I constituents on this date
• 11 - denotes well was sampled for Appendix 11 constituents on this date
• 11(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• ' -Appendix I volaliles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• " - Aluminum added to C&D constituent list
• s - 1,3-dichlorobenzene added to Appendix II triggered constituent list
• s - Tetrahydrofuran added to C&D constituent list
RuthCent_0518.xls
TABLE14
GROUNDWATER FLOW RATES
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Hydraulic
Conductivity
Effective
Velocity
Velocity
Well No.
(cm/sec)
Gradient
Porosity
(cm/sec)
(ft/yr)
8103-MW-2
1.3 x 10-5
0.087
.20
5.63 x 10-6
5.83
8103-MW-4
3.7 x 10-6
0.044
.20
8.16 x 10-7
0.84
8103-MW-6
2.4 x 10-5
0.109
.20
1.30 x 10-5
13.48
8103-MW-7
2.9 x 10-6
0.168
.201
2.43 x 10-6
2.52
8103-MW-8
1.6 x 10-4
0.029
.20
2.32 x 10-5
24.01
8103-MW-9
2.1 x 10-5
0.023
.20
2.42 x 10-6
2.50
The above results were obtained by using the relation:
V = Ki
Where K = hydraulic conductivity
i = gradient
n = effective porosity
V = velocity
Porosity value may not reflect true nature of fractured bedrock.
8103-MW-7 is screened in rock.
RuthCent_0518.xls
TABLE15
SURFACE WATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
Solid Waste
Section Limit
(SWSL)
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5A
ANTIMONY
BQL
BQL
BQL
BQL
6.0
ARSENIC
BQL
BQL
BQL
BQL
50.0
10.0
BARIUM
62.5 J
30.4 J
38.5 J
33.9 J
100.0
BERYLLIUM
BQL
BQL
BQL
BQL
6.5
1.0
CADMIUM
BQL
BQL
BQL
BQL
2.0
1.0
CHROMIUM
6.0 J
5.0 J
2.1 J
1.7 J
50.0
10.0
COBALT
1.7 J
BQL
BQL
BQL
10.0
COPPER
8.6 J
5.5 J
6.0 J
4.3 J
7.0111
10.0
LEAD
BQL
BQL
BQL
BQL
25.0
10.0
NICKEL
1.1 J
BQL
19.6 J
BQL
88.0
50.0
SELENIUM
BQL
BQL
BQL
BQL
5.0
10.0
SILVER
4.0 J
BQL
BQL
2.7 J
0.06"]
10.0
THALLIUM
BQL
BQL
BQL
BQL
5.5
VANADIUM
9.4 J
2.2 J
3.4 J
3.4 J
25.0
ZINC
1 230.0
1 319.0
1 258.0
1 146.0
1 50.0
10.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• ['] - Action Level
• NS - Not sampled. Dry location.
RuthCent_0518.x1s
TABLE 16
SURFACE WATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameters
Sample Location
15A NCAC 2B/EPA
Standards for Class
B,C Surface Water
Solid Waste
Section Limit
(SWSL)
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
5.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
2,500.0
1.0
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
3.0
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
1.0
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
20,000.0
5.0
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
5,400.0
5.0
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
1.0
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
13.0
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
1.0
1,2-DICHLOROBENZENE
BQL
BQL
BQL
BQL
470.0
5.0
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
1.0
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
1.0
1,4-DICHLOROBENZENE
BQL
BQL
BQL
BQL
100.0
1.0
2-BUTANONE
BQL
BQL
BQL
BQL
160,000.0
100.0
2-HEXANONE
BQL
BQL
BQL
BQL
50.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
26,000.0
100.0
ACETONE
BQL
BQL
BQL
BQL
2,000.0
100.0
ACRYLONITRILE
BQL
BQL
BQL
BQL
55.0
BENZENE
BQL
BQL
BQL
BQL
1.0
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
3.0
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
1.0
BROMOFORM
BQL
BQL
BQL
BQL
3.0
BROMOMETHANE
BQL
BQL
BQL
BQL
10.0
CARBON DISULFIDE
BQL
BQL
BQL
BQL
100.0
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
1.0
CHLOROBENZENE
BQL
BQL
BQL
BQL
140.0
3.0
CHLOROETHANE
BQL
BQL
BQL
BQL
10.0
CHLOROFORM
BQL
BQL
BQL
BQL
5.0
CHLOROMETHANE
BQL
BQL
BQL
BQL
1.0
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
5.0
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
12.0
1.0
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
3.0
DIBROMOMETHANE
BQL
BQL
BQL
BQL
10.0
ETHYLBENZENE
BQL
BQL
BQL
BQL
97.0
1.0
IODOMETHANE
BQL
BQL
BQL
BQL
10.0
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
1.0
STYRENE
BQL
BQL
BQL
BQL
1.0
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
1.0
TOLUENE
BQL
BQL
BQL
BQL
11.0
1.0
TOTAL XYLENES
BQL
BQL
BQL
BQL
670.0
5.0
TRANS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
5.0
TRANS- 1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
12.0
1.0
TRANS- 1,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
100.0
TRICHLOROETHENE
BQL
BQL
BQL
BQL
1.0
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
1.0
VINYL ACETATE
BQL
BQL
BQL
BQL
50.0
VINYL CHLORIDE
BQL
BQL
BQL
BQL
1.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• J - Estimated result. Present but below SWSL
• ' - Standard not established
• Shadedcellscells denote concentrations that equal or exceed 2B Standards
RutfFGQecnVitg xlss that are not naturally occurring and have no established standards, the SWSLs are the Standards
TABLE 17
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
Solid Waste
Section Limit
8103-MW-2
8103-MW-3
8103-MW4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGroundwater
Standard
(SWSL)
ALUMINUM
47,300.0
50,000.0
3,500.0
'
BARIUM
- 767.0 -
1-1130.0
700.0
'
100.0
CHLORIDE
336,000.0,
250,000.0
CHROMIUM
22.2
18.7
65.1
46A
56.0
53.9
10.0
'
10.0
COBALT
1.2 J
62.5
5:3 J
36.5
27.8
11.5
20.7
6.8 J
3.'0 J
38.6
29.4
'
1.0
10.0
IRON
• 3190.0
1,070.0
2,010,0
•4,370.0 _
= 866.0
4,010.0.
3,960.0 -
_ 2,580.0•
43,70&.0
43,100.0 =
300.0
'
300.0
LEAD
18.3
15.1
16.3
30A
15.0
'
10.0
MANGANESE
262.0
5,370.0
779.0
1640.0
1,480.0
50.0
'
50.0
TDS
' 552,000.0
508,000.0
500,000.0
THALLIUM
18.4
4.6 J
7.8
'
0.28
5.5
VANADIUM
5.3J
1.8J
15AJ
2.2J
24AJ
1.01
0.8J
129.0
1.2J
89.3
3.4J
2.4J
146.0
108.0
'
0.3
25.0
1,2-DICHLOROPROPANE
25:3
0.6
'
1.0
1,4-DICHLOROBENZENE
7.9
6.0
'
1.0
BENZENE
1.4
1.2
1.0
'
1.0
TETRACHLOROETHENE
1.2
0.7
'
1.0
VINYL CHLORIDE
- 0.4J
0.3,J
0A J -
0.2 J
0.03
'
1.0
Notes:
• All results in parts per billion (ppb)
• J - Estimated result. Present but below SWSL
• ' - Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards
RuthCeM_0519As
TABLE18
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 10-17, 2018
Parameter
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
Solid Waste
Section Limit
(SWSL)
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
COPPER
8.6 J
7.0111
10.0
IRON
3,240.0
1000.0111
300.0
MERCURY
0.05 J
0.16 J
0.04 J
0.012
0.200
SILVER
4.0 J
2.7 J
0.06111
10.0
ZINC
230.0
319.0
258.0
146.0
50.0111
10.0
Notes:
• All results in parts per billion (ppb)
• J - Estimated result. Present but below SWSL
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• I'] - Action Level
• NS - Not sampled. Dry location
RuthCent_0518.xls
APPENDIX D
FIGURE 2 AND TABLES
FROM THE OCTOBER 2018
SEMI-ANNUAL SAMPLING REPORT
BY SCARLETT GEOPHYSICAL CONSULTING
P.C.
�, r ,.�
i7 D- ` " _`"'_wwr, - yr-'''r • 4 ``,,..'- it•p ., .. M7 • >r iul
//
XPAR�OL U U 0
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APO0Elf W F00 PR1N E PANSfO�l- RUTHERFORD COUNTY, NORTH CAROLINA
fall it/, x.�-...._.� �P 0 S > C RDS C A TY) ,
„.: »•,.
TOWN OF RUTHERFORDTON •' r , SCARL.ETT GEOPHYSIC4L CONSULTING, PC
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x WASTEWATER TREATMENT ,t l• � �
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'AMA FACILITY i >< --""'�`J-, J Qj GROUNDWATER CONTOUR MAP'
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7 , 3 A RES
yt� ., 1 � +1� � .•.r....-�4 r � � b � Y l� t y r::t7 -
4p1� / e•a --- '.,.. LEGEND:°'�..�„ ias i ....�..•r..r�....,..
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r r 1 f rJ ! J MUI�ITORING WELL
FROM: �I i � , l 1 E �.,� � � (, ,� J °' : �-p / � T � . 1 i t rf �, ,---~-� • •, �. �. ``�• N �..\,
R SAMPLE LOCATION
1� /�% Jf � .. � gta. � i � � ! .''/�� � { -�•�,.,� �`''`�—` � 1 � � t y , SURFACE. WATER .�►.
DAViD► GA.RRETT & ASSOCIATES
�J 'ONOURGROUNDWATER MONITORING PLAN GROUNDWATER ATER C
WITH PHASE I CDLF AMENDMENTS GROUNDWATER rREcTIorr
,r J , ._ .... ) ``� ...w. f E-- `� , ,..: r• \ �. t.0w 03
SHEET 20, DRAWING NO. MIP1
_TR BUYARt�,EAST
\ `
"'� zoo'
NINO
TABLE 1
SUMMARY OF MONITORING WELL DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
Well
No.
Elevation (ft)
Depth
of
Well
(ft)
Static Water Levels3
May 3-9, 2017
Oct 2-5, 2017
May 10-17, 2018
Oct 1-8, 2018
Land
Surface
Top of
Casing'
Top of
Screen
Bottom of
Screen
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
8103-MW-2
995.43
995.51
945.43
935.43
60.0
46.25
949.26
47.27
948.24
46.89
948.62
46.20
949.31
8103-MW-3
859.62
860.28
822.62
812.62
47.0
33.89
826.39
34.61
825.67
32.09
828.19
33.23
827.05
8103-MW-4
849.72
851.03
809.72
799.72
50.0
36.06
814.97
36.48
814.55
31.91
819.12
34.82
816.21
8103-MW-6
833.43
834.90
810.93
795.93
37.5
31.88
803.02
32.33
802.57
31.36
803.54
31.12
803.78
8103-MW-7
890.51
892.70
851.51
836.51
54.0
37.82
854.88
37.33
855.37
34.93
857.77
35.88
856.82
8103-MW-8
857.86
860.31
828.36
813.36
44.5
43.49
816.82
44.26
816.05
39.89
820.42
42.56
817.75
8103-MW-9
864.97
867.25
842.47
827.47
37.5
34.00
833.25
35.65
831.60
34.02
833.23
34.64
832.61
8103-MW-10A
834.73
837.23
743.73
733.73
101.0
4.505
832.735
5.665
831.57'
6.475
830.76'
6.725
830.515
8103-MW-10B
834.50
836.15
802.50
797.50
37.0
8.92
827.23
10.01
826.14
9.11
827.04
9.51
826.64
8103-MW-10C
834.50
836.19
823.50
818.50
16.0
8.65
827.54
9.78
826.41
8.88
827.31
9.29
826.90
8103-MW-10D
834.73
837.23
778.73
768.73
66.0
9.88
827.35
11.16
826.07
9.96
827.27
9.44
827.79
8103-MW-11A
815.39
817.18
780.39
770.39
45.0
8.62
808.56
9.22
807.96
8.26
808.92
8.55
808.63
8103-MW-11 B
816.32
817.72
806.32
796.32
20.0
9.65
808.07
10.31
807.41
9.45
808.27
9.42
808.30
8103-MW-12
884.33
886.68
849.33
834.33
50.0
33.10
853.58
38.90
847.78
32.27
854.41
38.10
848.58
8103-MW-13
960.80
962.90
887.80
872.80
88.0
82.05
880.85
82.50
880.40
81.21
881.69
80.26
882.64
8103-MW-14
867.08
869.48
849.68
834.68
32.4
23.51
845.97
24.80
844.68
20.67
848.81
27.18
842.30
8103-MW-15
887.58
889.54
839.58
849.58
38.0
31.41
858.13
35.38
854.16
29.10
860.44
32.40
857.14
Notes:
1 Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC,
December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering
and Geology, Raleigh, NC, 2002 and 1999, respectively
2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C.
3 Water levels taken from top of casing
4 Depth of well measured from land surface
5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day)
RuthCent_1018
TABLE 2
GROUND AND SURFACE WATER SAMPLING FIELD DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Sample Location
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10A
8103-MW-10B
Temperature
15.08°C
17.4°C
13.69°C
15.41°C
16.7°C
14.39°C
13.79°C
NS
16.6°C
Conductivity
93.0 pmhos/cm
934 pmhos/cm
580 pmhos/cm
1960 pmhos/cm
953 pmhos/cm
393 pmhos/cm
41.0 pmhos/cm
NS
102.3 pmhos/cm
pH
7.24
6.38
5.88
5.90
6.70
5.33
4.59
NS
6.17
ORP
235 mV
NA
186 mV
6 mV
NA
310 mV
307 mV
NS
NA
DO
6.54 mg/I
NA
0.72 mg/I
1.69 mg/I
NA
5.48 mg/I
6.43 mg/I
NS
NA
Turbidity
18.4 NTU
NA
0.0 NTU
0.0 NTU
NA
0.0 NTU
0.0 NTU
NS
NA
Parameter
Sample Location
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
Temperature
17.1°C
13.06°C
13.42°C
17.2°C
17.7°C
17.6°C
17.4°C
16.2°C
20.5°C
Conductivity
100.0 pmhos/cm
286 pmhos/cm
715 pmhos/cm
167.E pmhos/cm
563 pmhos/cm
191.3 pmhos/cm
206 pmhos/cm
233 pmhos/cm
101.6 pmhos/cm
pH
6.40
5.30
5.56
5.86
6.41
5.70
5.71
5.87
7.13
ORP
NA
133 mV
53 mV
NA
NA
NA
NA
NA
NA
DO
NA
0.54 mg/I
0.40 mg/I
NA
NA
NA
NA
NA
NA
Turbidity
NA
0.0 NTU
0.0 NTU
NA
NA
NA
NA
NA
NA
Parameter
Sample Location
8103-SW-3
8103-SW-4
8103-SW-5
Temperature
21.0°C
20.9°C
20.4°C
Conductivity
80.6 pmhos/cm
58.3 pmhos/cm
76.7 pmhos/cm
pH
7.32
7.16
6.71
ORP
NA
NA
NA
DO
NA
NA
NA
Turbidity
NA
NA
NA
NS - Not sampled
NA - Not analyzed
RuthCent_1018
TABLE 3
GROUNDWATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Well Number
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
ANTIMONY
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
1.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
BARIUM
21.7
167.0
154.0
382.0
132.0
163.0
59.1
357.0
700.0
BERYLLIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.88
4.0
CADMIUM
BQL
0.4
0.4
0.5
0.4
0.3
BQL
BQL
2.0
CHROMIUM
2.2
1.8
2.3
7.0
4.8
2.8
2.9
26.3
10.0
COBALT
BQL
1.2
1.3 =
44.5
1.9 : -
BQL
BQL
17.4
1.0
COPPER
BQL
1.3
3.9
BQL
5.2
BQL
BQL
23.0
1000.0
LEAD
BQL
BQL
2.6
BQL
BQL
BQL
BQL
10.5
15.0
NICKEL
BQL
1.5
1.8
19.7
3.3
1.3
1.2
20.3
100.0
SELENIUM
BQL
BQL
BQL
6.78
BQL
BQL
BQL
BQL
20.0
SILVER
4.7
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
THALLIUM
BQL
BQL
BQL
34.3
BQL
BQL
BQL
BQL
0.28
VANADIUM
2.1
2.3
8.6
BQL
5.9
1.5
BQL
53.8
*
0.3
ZINC
12.4
9.0
26.1
55.6
29.7
47.4
17.8
66.5
1000.0
Parameter
Well Number
15A NCAC 2L
Standard for Class
GAGroundwater
NC Groundwater
Protection
Standard
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
ANTIMONY
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
1.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
BARIUM
209.0
191.0
183.0
492.0
140.0
171.0
83.4
104.0
700.0
BERYLLIUM
0.59
BQL
BQL
3.6
BQL
BQL
BQL
BQL
4.0
CADMIUM
BQL
0.32
0.3
BQL
0.3
0.4
BQL
0.3
2.0
CHROMIUM
23.5
1.9
3.8
67.2
6.8
2.7
1.6
3.9
10.0
COBALT
10.7
27.1
12.5
28.4
4.3
4.7
BQL
BQL
1.0
COPPER
13.0
10.3
BQL
30.9
8.8
14.5
BQL
BQL
1000.0
LEAD
6.6
BQL
BQL
23.1
2.4
3.9
BQL
BQL
15.0
NICKEL
11.3
12.1
4.6
40.8
3.8
12.4
0.7
0.8
100.0
SELENIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
SILVER
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
THALLIUM
BQL
• 4.4
14.2
BQL
3.4
•2.7
BQL
BQL
0.28
VANADIUM
42.&
BQL
0.9
136.0
9.5
2.9
2.4
2.7
0.3
ZINC
57.2
25.0
6.6
127.0
22.0
21.6
9.3
10.2
1000.0
Notes:
All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
NS - Not Sampled
• * - Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCent_1018
TABLE 4
GROUNDWATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MWA
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGroundwater
Standard
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
200.0
'
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
0.18
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
0.6
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
0.6
BQL
BQL
BQL
BQL
1.3
BQL
BQL
BQL
BQL
BQL
BQL
6.0
`
1,1-DICHLOROETHENE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
7.0
'
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
"
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
0.04
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.02
"
1,2-DICHLOROBENZENE
BQL
BQL
BQL
0.6
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
20.0
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
"
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BOIL
BQL
BOIL
20.3
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
0.6
1,4-DICHLOROBENZENE
BQL
BQL
0.7
6.9
BQL
BQL
BQL
BQL
BQL
2.0
2.6
BQL
BQL
BQL
BQL
BQL
6.0
"
1,4-DIOXANE
2.3
'22.9'
2.2
108.0'
.5.3"
7.0
BQL
2.5
BQL
2.2
10.8'
2.7
4:8
BOIL
2.5
BQL
3.0
2-BUTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4,000.0
`
2-HEXANONE
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
40.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
560.0
ACETONE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BQL
6,000.0
'
ACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
`
BENZENE
BQL
BQL
BQL
12
BQL
BQL
BQL
BOIL
BQL
1.0
0.2
BQL
BQL
0.6
BQL
BQL
1.0
'
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
BROMODICHLOROMETHANE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BQL
0.6
'
BROMOFORM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
"
BROMOMETHANE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BQL
1 10.0
CARBON DISULFIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
700.0
"
CARBON TETRACHLORIDE
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BOIL
BQL
BQL
0.3
CHLOROBENZENE
BQL
BQL
0.6
36.5
BQL
BQL
BQL
BQL
BQL
1.8
5.4
BQL
BQL
BQL
BQL
BQL
50.0
"
CHLOROETHANE
BQL
BQL
0.61
BQL
BQL
BQL
BQL
BQL
BQL
0.6
0.4
BQL
BQL
0.8
BQL
BQL
3,000.0
'
CHLOROFORM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
`
CHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3.0
'
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
9.5
BQL
BQL
BQL
0.5
0.3
BQL
70.0
"
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.41
DIBROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
ETHYLBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
"
METHYL IODIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
5.0
"
STYRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.3
BQL
BQL
BQL
BQL
BQL
BQL
0.7
"
TOLUENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
TOTAL XYLENES
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.5
BQL
BQL
500.0
`
TRANS-I,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
'
TRANS-I,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.2
TRANS-I,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
TRICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.1
BQL
BQL
BQL
BQL
BQL
BQL
3.0
`
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
0.3J
2,000.0
'
VINYL ACETATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
88.0
VINYLCHLORIDE
BQL
BQL
BQL
0.4
BQL
BQL
BQL
BQL
BQL
0.4
0.7
BQL
BQL
0.2
BQL
BQL
0.03
'
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
B - Lab blank contamination
NS - Not Sampled
`- Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCeM_1018
TABLE 5
GROUNDWATER SAMPLING RESULTS
APPENDIX II TRIGGERED CONSTITUENTS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
SW-846
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
Parameter
Method
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
GAGroundwater
Standard
1,3-Dichlorobenzene
8260
BQL
0.5
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
1,3-Dichloro ro ane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Dichlorodifluorom ethane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1,000.0
4,4'- DDD
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
4,4'- DDT
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
al ha-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.006
beta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
delta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
Endrin
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.0
gamma-BHC Lindane
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.03
Mercury
7470
0.09
0.05
BQL
BQL
0.03
0.01
BQL
0.05
BQL
0.08
1.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• * - Standard not established
Shaded" . ' ° cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• NA -Not analyzed
• NS - Not Sampled
RuthCent_1018
TABLE 6
GROUNDWATER SAMPLING RESULTS
MONITORED NATURAL ATTENUATION PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
8103-MW-2
8103-MW-4
8103-MW-6
8103-MW-8
8103-MW-9
8103-MW-10D
8103-MW-11A
ACETIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
ALKALINITY
SM 2320B
52,100 u /L
346,000 u /L
621,000 u /L
75,300 u /L
22,300 u /L
143,000 u /L
378,000 u /L
BOD
SM 5210B
BQL
BQL
2,190 u /L
BQL
BQL
BQL
BQL
BUTYRIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
CARBON DIOXIDE
SM 4500 CO2 C
2,640 u /L
202,000 u /L
316,000 u /L
106,000 u /L
79,200 u /L
150,000 u /L
304,000 u /L
CHLORIDE
SM 4500 Cl C
2,940 u /L
13,200 u /L
284,000 ug/L
71,900 u /L
5,870 u /L
10,800 u /L
41,100 u /L
250,000.0
COD
EPA 410.4
BQL
7,000 u /L
84,000 u /L
6,000 u /L
BQL
5,000 u /L
21,000 u /L
ETHANE
AM20GAX
BQL
BQL
0.70 u /L
BQL
BQL
BQL
0.19 u /L
ETHENE
AM20GAX
BQL
BQL
0.45 u /L
BQL
BQL
BQL
0.20 u /L
HEXANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
<MRL
BQL
HYDROGEN
AM20GAX
48 nM
16 Nm
24 nM
22 nM
24 nM
24 nM
48 Nm
i-HEXANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
i-PENTANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
IRON
EPA 200.7
1,060 ug/L
1,190 ug/L
3,790 ug/L
223 u /L
33.1 u /L
734 ug/L
3890 ug/L
300.0
LACTIC ACID & HIBA
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHANE
AM20GAX
BQL
3.0 u /L
120 u /L
BQL
3.5 u /L
3.5 u /L
320 u /L
NITRATE -NITROGEN
SM 4500 NO3 E
60.0 u /L
BQL
BQL
6,020 u /L
BQL
BQL
BQL
10,000.0
PENTANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PROPIONOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PYRUVIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SULFATE
SM 4500 SO4 E
BQL
BQL
11,000 u /L
12,700 u /L
BQL
BQL
10,700 u /L
250,000.0
SULFIDE
EPA 376.1
BQL
BQL
BQL
BQL
BQL
BQL
BQL
TOTAL ORGANIC CARBON
SM 5310
BQL
2,380 ug/L
27,700 ug/L
2,580 ug/L
BQL
BQL
6,100 ug/L
Notes:
• ug/L - micrograms per Liter (ppb)
• nM - nano Moles
• BQL - Below Method Detection Limit
• * - Standard not established
• ** - Analysed past hold time
• NS - Not sampled
RuthCent_1018
TABLE 7
GROUNDWATER AND SURFACE WATER SAMPLING RESULTS
C & D PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
15A NCAC 213
Standard for Class
B,C Surface Water
8103-MW-2
8103-MW-3
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
ALKALINITY
SM 2320B
52,100
342,000
253,000
74,400
41,800
24,200
27,000
24,200
14,000
21,400
ALUMINUM
SW8466010C
468.0
314.0
2,400.0
599.0
504.0
1,060.0
278.0
55.4
254.0
158.0
3,500.0
CHLORIDE
SM 4500 Cl C
2,940
458,400
9,780
6,360
5,870
9,780
7,340
5,870
5,380
6,360
250,000.0
230,000111
IRON
EPA200.7
1,060.0
1,060.0
4,500.0
2,570.0
637.0,
1,020.0
426.0
297.0
496.0
991.0
300.0
1 1,000111
MANGANESE
SW 846 6010
12.0
275.0_
1,620.0
1,060.0
29.3
60.3
76.4
41.2
21.7
35.6
50.0
MERCURY
SW 846 7470
0.03
BQL
0.02
0.12
BQL
BQL
0.04
BQL
0.05
BQL
1.0
0.012
SULFATE
SM 4500 SO4 E
BQL
42,700
BQL
BQL
24,600
36,600
BQL
BQL
BQL
BQL
250,000.0
TDS
SM 2540 C
78,000
572,000
323,000
125,000
139,000
185,000
79,000
60,000
57,000
66,000
TETRAHYDROFURAN
SW 8468260B
BQL
BQL
BQL
BQL
1.9
BQL
BQL
BQL
BQL
BQL
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
* - Standard/Limit not established
NS - Not sampled
Ill - Action Level
Shaded cells denote concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels
NA - Not analyzed due to insufficient sample volume. See note.
RuthCent_1018
TABLE 8
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
����
r r ••
r: r: ••
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r. r. ..
����
r r r: rrr
r• r rrr
�aaaa��a��aaaaaaaa
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix 11 triggered constituents
(113-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodiFluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• I - Appendix I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix 11 triggered constituent list
• a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• ° - Aluminum added to C&D constituent list
• s - 1,3-dichlorobenzene added to Appendix 11 triggered constituent list
• 6 - Tetrahydrofuran added to C&D constituent list
• 7 - 1,4-Dioxane added to all sample locations
RuthCent_1018
TABLE 8 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
04/11/2001
09/12-13/2001
04/03/2002
06/27/2002
10/02/2002
04/02-03/2003
09/03/2003
04/06/2004
10/27/2004
04/05/2005
09/08/2005
04/04-05/2006
10/26-27/2006
5/22-2312007
10/23-26/2007
05/06-08/2008
09/22-25/2008
8103-MW-2
I
I
I
I
I
I
I
I
I
I
I
1
I, MNA
I, MNA, C&D
I, MNA, C&D
8103-MW-3
I
I
I
I
I
I
I
I
I
I
I
I
I
1
I, C&D
I, C&D
8103-MW-4
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1,IIt,MNA
1,11,MNA
1,IIt,MNA
8103-MW-6
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
I, 11(t)
I'll
I, 11(t), MNA
1, 11, MNA
I, 11(t), MNA
8103-MW-7
I'll
1, 11(t)
I'll
I, 11(t)
I'll
I, 11(t)
I'll
I, 11(t)
I'll
1, 11(t)
I'll
I, 11(t)
I'll
I, 11(t)
I'll
I, 11(t)
8103-MW-8
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
8103-MW-9
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
1, 11(t)
I'll
I, 11(t), MNA
1,11,MNA
I, 11(t), MNA
8103-MW-10A
8103-MW-10B
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
8103-MW-10C
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
8103-MW-10D
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
8103-MW-11A
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
11(t)
1, 11(t)
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
8103-MW-11B
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
-1,
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
1, 11(t)
8103-MW-12
I
I
I
I
I
I
I
I
I
I
I
1
1, C&D
1, C&D
8103-MW-13
1
1
1
1
1
1
1
1
1
1
1
1
1, C&D
1, C&D
8103-MW-14
1, C&D
1, C&D
8103-MW-15
1, C&D
1, C&D
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• 11(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• - Appendix I volatiles only
• z - Mercury and endrin aldehyde added to Appendix I I triggered constituent list
• 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• ° - Aluminum added to C&D constituent list
• s - 1,3-dichlorobenzene added to Appendix 11 triggered constituent list
• 6 - Tetrahydrofuran added to C&D constituent list
• 7 - 1,4-Dioxane added to all sample locations
RuthCent_1018
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
TABLE 8 (cont.)
Well
05/18-05/21, 2009
10/07-10/09, 2009
05/17-05/20, 2010
09/20-09/23, 2010
04125-05102, 2011
09/27-09/30, 2011
04130-05103, 2011
09/25-10/03, 2012
04115-04118,2013
09/23-09/28, 2013
04128-0511, 2014
09/29-10/04, 2014
04/27-05102, 2015
09/28-10107, 2015
04/26-05/05, 2016
09119-09/22, 2016,
8103-MW-2
I MNA C&D
1, MINA C&D
I MNA C&D
I, MNA, C&D4
I, MNA, C&D
I, MINA, C&D
I, MNA, C&D
I, MINA, C&D
I, MNA, C&D
I, MINA, C&D
I, MINA, C&Ds
I, MINA, C&D
I, MNA, C&D
I, MNA, C&D
I, MINA, C&D
I, MNA, C&D
8103-MW-3
I, C&D
1, C&D
I, C&D
I, C&D4
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-4
I, II, MNA
1, lilt), MNA
I, II, MNA
I, II t MNA
I, II, MNA
I, II(t)s, MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MINA
I, II, MNA
I, II(t), MINA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
8103-MW-6
I, II, MNA
1, lilt), MNA
I, II, MNA
I, lilt), MNA
I, II, MNA
I, II(t)s, MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MINA
I, II, MNA
I, II(t), MINA
I, II, MINA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
8103-MW-7
III
I, II t
I, II
I, II t
III
I, II(t)s
I'll
I, II(t)
I'll
I, II(U
I'll
I, II(t)
I'll
I, II(t)
I'll
I, II(t)
8103-MW-8
I, II, MNA
1, lilt), MNA
I, lilt), MNA
I, II, MNA
I, II(t)s, MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MNA
I, II, MINA
I, II(t), MNA
8103-MW-9
I, II, MNA
1. lilt), MNA
I, II, MNA
I, lilt), MNA
I, II, MNA
I, II(t)s, MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MINA
I, II, MNA
I, lilt), MINA
I, II, MINA
I, II(t), MNA
I, II, MINA
I, II(t), MNA
8103-MW-10A
8103-MW-10B
1, II t
I, II t
I, II t
I II t
II t
I, II(t)s
I, II(t)
I, II(U
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10C
1, II t
I, II t
II t
I II t
II t
I, II(t)s
I, II(t)
I, II(U
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10D
I, II t, MNA
1, lilt), MNA
I, II t MNA
I, lilt), MNA
I, II t MNA
I, II(t)s, MINA
I, II(t), MNA
I, lilt), MINA
I, II(t), MNA
I, lilt), MINA
I, II(t), MINA
I, lilt), MINA
I, lilt), MINA
I, II(t), MNA
I, II(t), MINA
I, II(t), MNA
8103-MW-11A
I, II t, MNA
1, lilt), MNA
I, II t MNA
I, lilt), MNA
I, II t MNA
I, II(t)s, MINA
I, II(t), MNA
I, lilt), MINA
I, II(t), MNA
I, lilt), MINA
I, II(t), MINA
I, lilt), MINA
I, lilt), MINA
I, II(t), MNA
I, II(t), MINA
I, II(t), MNA
8103-MW-11B
1, II t
I, II t
II t
I II t
II t
I, II(t)s
I, II(t)
I, II(U
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-12
I, C&D
1, C&D
I, C&D
I, C&D4
I, C&D
I, C&D
I, C&D
1 I, C&D
1 I, C&D
1 I, C&D
I, C&Ds
I, C&D
1 I, C&D
I, C&D
I, C&D
1 I, C&D
8103-MW-13
I, C&D
1, C&D
I, C&D
I, C&D4
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-14
I, C&D
1, C&D
I, C&D
I, C&D4
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-15
I, C&D
1 I, C&D
1 I, C&D
1 I, C&D4
1 I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• ' -Appendix
I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• 4 - Aluminum added to C&D constituent list
• 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list
• 6 - Tetrahydrofuran added to C&D constituent list
• 7 - 1,4-Dioxane added to all sample locations
RuthCent_1018
TABLE 8 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
05/03-05/09, 2017
10/02-10/05, 2017
05/10-05/17, 2018
10/01-10/08, 2018
8103-MW-2
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D7
8103-MW-3
I, C&D
I, C&D
I, C&D
I, C&D7
8103-MW-4
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
8103-MW-6
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
8103-MW-7
1,11
I, II t
1,11
I, II(t)
8103-MW-8
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
8103-MW-9
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
8103-MW-10A
8103-MW-10B
I, II t
I, II t
I, II t
I, II(t)
8103-MW-10C
I, II t
I, II t
I, II t
I, II(t)
8103-MW-10D
I, 11(t), MNA
I, 11(t), MINA
I, 11(t), MINA
I, II(t), MNA7
8103-MW-11A
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t), MNA7
8103-MW-11B
I, II t
I, II t
I, II t
I, II(t)
8103-MW-12
I, C&D
I, C&D
I, C&D
I, C&D7
8103-MW-13
I, C&D
I, C&D
I, C&D
I, C&D7
8103-MW-14
I, C&D
I, C&D
I, C&D
I, C&D7
8103-MW-15
I, C&D
I, C&D
I, C&D
I, C&D7
I - denotes well was sampled for Appendix I constituents on this date
II - denotes well was sampled for Appendix II constituents on this date
II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
MNA - denotes well was sampled for Monitored Natural Attenuation constituents
C&D - denotes well was sampled for Construction and Demolition constituents
' -Appendix I volaliles only
3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
° -Aluminum added to C&D constituent list
5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list
6 - Tetrahydrofuran added to C&D constituent list
- 1,4-Dioxane added to all sample locations
RuthCent_1018
TABLE 9
GROUNDWATER FLOW RATES
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Hydraulic
Conductivity
Effective
Velocity
Velocity
Well No.
(cm/sec)
Gradient
Porosity
(cm/sec)
(ft/yr)
8103-MW-2
1.3 x 10-50.089
.20
5.77 x 10
5.97
8103-MW-4
3.7 x 10-6
0.032
.20
5.95 x 10-7
0.62
8103-MW-6
2.4 x 10-5
0.100
.20
1.20 x 10-5
13.15
8103-MW-7
2.9 x 10-6
0.095
.201
1.38 x 10-6
1.42
8103-MW-8
1.6 x 10-4
0.021
.20
1.66 x 10-5
17.23
8103-MW-9
I 2.1 x 10-
0.022
.20
1 2.33 x 1 O'l
2.42
The above results were obtained by using the relation:
V = Ki
n
Where K = hydraulic conductivity
i = gradient
n = effective porosity
V = velocity
Porosity value may not reflect true nature of fractured bedrock.
8103-MW-7 is screened in rock.
RuthCent_1018
TABLE10
SURFACE WATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
ANTIMONY
BQL
BQL
BQL
BQL
ARSENIC
BQL
BQL
BQL
BQL
50.0
BARIUM
47.5
31.3
35.4
40.5
BERYLLIUM
BQL
BQL
BQL
BQL
6.5
CADMIUM
BQL
0.2
BQL
BQL
2.0
CHROMIUM
1.2
1.0
1.3
2.9
50.0
COBALT
2.4 J
BQL
BQL
BQL
COPPER
BQL
BQL
BQL
39.0
7.0[1]
LEAD
BQL
BQL
BQL
BQL
25.0
NICKEL
BQL
BQL
BQL
26.1
88.0
SELENIUM
BQL
BQL
BQL
BQL
5.0
SILVER
BQL
BQL
BQL
BQL
0.06[1]
THALLIUM
BQL
BQL
BQL
BQL
VANADIUM
1 1.4
0.7
2.1
1.2
ZINC
1 5.4
8.1
9.4
10.0
50.0[1]
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• * - Standard not established
Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• [11 - Action Level
RuthCent_1018
TABLE 11
SURFACE WATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameters
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
1,1,1,2-TETRACHLOROETHANE
BOL
BOL
BOL
BOL
1,1,1-TRICHLOROETHANE
BOL
BOL
BOL
BOL
1,1,2,2-TETRACHLOROETHANE
BOL
BOL
BOL
BOL
1,1,2-TRICHLOROETHANE
BOL
BOL
BOL
BOL
1,1-DICHLOROETHANE
BOL
BOL
BOL
BOL
1,1-DICHLOROETHENE
BOL
BOL
BOL
BOL
1,2,3-TRICHLOROPROPANE
BOL
BOL
BOL
BOL
1,2-DIBROMO-3-CHLOROPROPANE
BOL
BOL
BOL
BOL
1,2-DIBROMOETHANE
BOL
BOL
BOL
BOL
1,2-DICHLOROBENZENE
BOL
BOL
BOL
BOL
1,2-DICHLOROETHANE
BOL
BOL
BOL
BOL
1,2-DICHLOROPROPANE
BOL
BOL
BOL
BOL
1,4-DICHLOROBENZENE
BOL
BOL
BOL
BOL
1,4-DIOXANE
2.7
BOL
BOL
2.4
2-BUTANONE
BOL
BOL
BOL
BOL
2-HEXANONE
BOL
BOL
BOL
BOL
4-METHYL-2-PENTANONE
BOL
BOL
BOL
BOL
ACETONE
BOL
BOL
BOL
BOL
ACRYLONITRILE
BOL
BOL
BOL
BOL
BENZENE
BOL
BOL
BOL
BOL
BROMOCHLOROMETHANE
BOL
BOL
BOL
BOL
BROMODICHLOROMETHANE
BOL
BOL
BOL
BOL
BROMOFORM
BOL
BOL
BOL
BOL
BROMOMETHANE
BOL
BOL
BOL
BOL
CARBON DISULFIDE
BOL
BOL
BOL
BOL
CARBON TETRACHLORIDE
BOL
BOL
BOL
BOL
CHLOROBENZENE
BOL
BOL
BOL
BOL
CHLOROETHANE
BOL
BOL
BOL
BOL
CHLOROFORM
BOL
BOL
BOL
BOL
CHLOROMETHANE
BOL
BOL
BOL
BOL
CIS-1,2-DICHLOROETHENE
BOL
BOL
BOL
BOL
CIS-1,3-DICHLOROPROPENE
BOL
BOL
BOL
BOL
DIBROMOCHLOROMETHANE
BOL
BOL
BOL
BOL
DIBROMOMETHANE
BOL
BOL
BOL
BOL
ETHYLBENZENE
BOL
BOL
BOL
BOL
IODOMETHANE
BOL
BOL
BOL
BOL
METHYLENE CHLORIDE
BOL
BOL
BOL
BOL
STYRENE
BOL
BOL
BOL
BOL
TETRACHLOROETHENE
BOL
BOL
BOL
BOL
TOLUENE
BOL
BOL
BOL
BOL
11.0
TOTAL XYLENES
BOL
BOL
BOL
BOL
TRANS-1,2-DICHLOROETHENE
BOL
BOL
BOL
BOL
TRANS-1,3-DICHLOROPROPENE
BOL
BOL
BOL
BOL
TRANS-1,4-DICHLORO-2-BUTENE
BOL
BOL
BOL
BOL
TRICHLOROETHENE
BOL
BOL
BOL
BOL
TRICHLOROFLUOROMETHANE
BOL
BOL
BOL
BOL
VINYL ACETATE
BOL
BOL
BOL
BOL
VINYL CHLORIDE
BOL
BOL
BOL
BOIL
Notes:
• All results in parts per billion (ppb)
• BOL - Below Method Detection Limit
• ` - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards
RuthCent_1018
TABLE 12
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MWA
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-IOC
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGroundwater
Standard
1,2-DICHLOROPROPANE
20.3
0.6
'
1,4-DICHLOROBENZENE
6.9
6.0
'
1,4-DIOXANE
22.9
108.0
5.3
7.0
10.8
4.8
3.0
'
BENZENE
1.2
1.0
1.0
'
CHLORIDE
'284;000.0
250,000.0
'
CHROMIUM
26.3•
23.5
• 67.2
10.0
'
COBALT
1.2„
1.3
44.5
.1.9„
17A„
, 10.7
- 27.1
12.5.
, 28.4 -
4.3
4.7 ,
1.0
IRON
1,060.0
1,060.0
11190.0
3,790.0
734.0
3,890.0
4,500.0
2,570.0
637.0
1,020.0
300.0
'
LEAD
23.7
15.0
'
MANGANESE
275.0
1,620.0
1,060.0
66.3
50.0
'
TETRACHLOROETHENE
1.3
0.7
'
THALLIUM
-. 34.3
4.4 -
.14.2,
3A ,
-2.7 „
0.28
VANADIUM
2.1
2.3
8.6
5.9
1.�
53.8
42;8
0.9
1360
9.5
2.9
24
2j
0.3
VINYLCHLORIDE
10.4
0.4
1 0.7
0.2
1
0.03
'
Notes:
• All results in parts per billion (ppb)
• ' - Standard not established
Shaded ., I cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• NS - Not Sampled
RuthCeM_1018
TABLE13
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
OCTOBER 1-8, 2018
Parameter
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
MERCURY
0.04
0.05
0.012
COPPER
39.0
7.01 11
Notes:
• All results in parts per billion (ppb)
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• �11- Action Level
• NS - Not sampled. Dry location
RuthCent_1018
APPENDIX E
FIGURE 2 AND TABLES
FROM THE MAY 2019
SEMI-ANNUAL SAMPLING REPORT
BY SCARLETT GEOPHYSICAL CONSULTING
P.C.
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ti>a f i O L
�'
�' ''° ----- ri, d ` I ' -- CENTRAL SANITARY LANDFILL
P OX. E W FOO IN� E PAN IOAI-
��'? ,� �--" >." R.UTHERFORD COUNTY NORTH aCAROLIN
4 _... _._� ,,..� O S > , OQ�C C Y RDS C ATY}
slat
TOWN OF RUTNERFORDTON i %
I x x°?.
SlT1tE�PI�ICAV5l�T11"PC
WASTEWATER TREATMENT ,x, _ - .
FACILITY -ter •iY , -' �"' ki " '� » '`' GROUNDWATER CONTOUR MAP'
` ART
10 .Ya .-.....__ 0 q,'ti®� EOM" MAY 7-15, 2019
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D V �r f -''' ! _ '� `r i °t \_ / �° ;'`— ., • s SURFACE WATER SAMPLE LOCATIaA3 ,11,
A ID GARRETT & ASSOCIATES,loll,
GROUNDWATER MONITORING P'� , � ,��,;,�/ ;� � � ,,- � .-- ,, `�� � � GROUNDWATER CONTOUR 920
WITH PHASE I CDLF AMENDMENTS :\``'-�,;;% ` � -� �----�,� � ��.% , � 1'' � � � � GROUNDWATER Flow DIRECTION-�
'`
S��SHEET 20, DRAWING NO. .r ;� � 0 20o. a�oo. goo,
<kAS T � z ~ goo'
TABLE 1
SUMMARY OF MONITORING WELL DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
Well
No.
Elevation (ft)
Depth
of
Well
(ft)
Static Water Levels3
Oct 2-5, 2017
May 10-17, 2018
Oct 1-8, 2018
May 7-15,
2019
Land
Surface
Top of
Casing'
Top of
Screen
Bottom of
Screen
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
Depth
(ft)
Elevation
(ft)
8103-MW-2
995.43
995.51
945.43
935.43
60.0
47.27
948.24
46.89
948.62
46.20
949.31
32.05
963.46
8103-MW-3
859.62
860.28
822.62
812.62
47.0
34.61
825.67
32.09
828.19
1 33.23
827.05
30.17
830.11
8103-MW-4
849.72
851.03
809.72
799.72
50.0
36.48
814.55
31.91
819.12
34.82
816.21
28.49
822.54
8103-MW-6
833.43
834.90
810.93
795.93
37.5
32.33
802.57
31.36
803.54
31.12
803.78
26.57
808.33
8103-MW-7
890.51
892.70
851.51
836.51
54.0
37.33
855.37
34.93
857.77
35.88
856.82
33.20
859.50
8103-MW-8
857.86
860.31
828.36
813.36
44.5
44.26
816.05
39.89
820.42
42.56
817.75
35.98
824.33
8103-MW-9
864.97
867.25
842.47
827.47
37.5
35.65
831.60
34.02
833.23
34.64
832.61
29.04
838.21
8103-MW-10A
834.73
837.23
743.73
733.73
101.0
5.665
831.575
6.475
830.765
6.725
830.515
5.745
831.495
8103-MW-10B
834.50
836.15
802.50
797.50
37.0
10.01
826.14
9.11
827.04
9.51
826.64
7.86
828.29
8103-MW-10C
834.50
836.19
823.50
818.50
16.0
9.78
826.41
8.88
827.31
9.29
826.90
7.82
828.37
8103-MW-10D
834.73
837.23
778.73
768.73
66.0
11.16
826.07
9.96
827.27
9.44
827.79
8.34
828.89
8103-MW-11A
815.39
817.18
780.39
770.39
45.0
9.22
807.96
8.26
808.92
8.55
808.63
7.40
809.78
8103-MW-11B
816.32
817.72
806.32
796.32
20.0
10.31
807.41
9.45
808.27
9.42
808.30
8.85
808.87
8103-MW-12
884.33
886.68
849.33
834.33
50.0
38.90
847.78
32.27
854.41
38.10
848.58
34.55
852.13
8103-MW-13
960.80
962.90
887.80
872.80
88.0
82.50
880.40
81.21
881.69
80.26
882.64
70.04
892.86
8103-MW-14
867.08
869.48
849.68
834.68
32.4
24.80
844.68
20.67
848.81
27.18
842.30
18.53
850.95
8103-MW-15
887.58
889.54
1 839.58
849.58
1 38.0
35.38
854.16
29.10
860.44
32.40
857.14
27.18
862.36
Notes
Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC,
December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering
and Geology, Raleigh, NC, 2002 and 1999, respectively
2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C.
3 Water levels taken from top of casing
4 Depth of well measured from land surface
5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day)
RuthCent_0519
TABLE 2
GROUND AND SURFACE WATER SAMPLING FIELD DATA
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15. 2019
Parameter
Sample Location
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10A
8103-MW-10B
Temperature
17.09°C
17.7°C
15.76°C
17.85°C
15.6°C
18.22°C
16.11°C
NS
16.7°C
Conductivity
82.0 pmhos/cm
941 pmhos/cm
387 pmhos/cm
1210 pmhos/cm
1016 pmhos/cm
185 pmhos/cm
28.0 pmhos/cm
NS
112.0 pmhos/cm
pH
9.47
6.44
6.74
7.48
6.73
6.61
6.31
NS
6.16
ORP
96 mV
NA
194 mV
-88 mV
NA
234 mV
233 mV
NS
NA
DO
1.49 mg/I
NA
0.00 mg/I
0.00 mg/I
NA
1.59 mg/I
0.52 mg/I
NS
NA
Turbidity
31.9 NTU
NA
3.3 NTU
0.0 NTU
NA
7.0 NTU
0.0 NTU
NS
NA
Parameter
Sample Location
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
Temperature
14.8°C
16.80°C
15.33°C
14.2°C
16.7°C
16.9°C
16.0°C
14.7°C
15.9°C
Conductivity
90.8 pmhos/cm
267 pmhos/cm
805 pmhos/cm
314 mhos/cm
720 pmhos/cm
206 pmhos/cm
191.6 pmhos/cm
185.8 pmhos/cm
120.6 pmhos/cm
pH
5.95
7.09
6.38
6.05
6.55
5.75
5.85
6.11
7.00
ORP
NA
39 mV
9 mV
NA
NA
NA
NA
NA
NA
DO
NA
0.00 mg/I
0.00 mg/I
NA
NA
NA
NA
NA
NA
Turbidity
NA
0.0 NTU
2.1 NTU
NA
NA
NA
NA
NA
NA
Parameter
Sample Location
8103-SW-3
8103-SW-4
8103-SW-5A
Temperature
18.6°C
15.4°C
15.8°C
Conductivity
70.9 pmhos/cm
48.6 pmhos/cm
72.3 pmhos/cm
pH
7.16
7.14
6.85
ORP
NA
NA
NA
DO
NA
NA
NA
Turbidity
NA
NA
NA
NS - Not sampled
NA - Not analyzed
RuthCent_0519
TABLE 3
GROUNDWATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 C
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
Well Number
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
ANTIMONY
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
BARIUM
19.30
180.00
101.00
227.00
130.00
111.00
61.70
265.00
700.0
BERYLLIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.46
4.0
CADMIUM
BQL
0.36
0.47
0.43
0.62
0.25
BQL
0.38
2.0
CHROMIUM
0.92
1.24
1.36
4.28
2.95
4.22
2.10
28.00
10.0
COBALT
BQL
1.32
BQL
j 30.70
2.98
BQL
BQL
15.60
*
1.0
COPPER
4.48
4.45
6.55
5.66
12.60
4.24
BQL
20.80
1,000.0
LEAD
BQL
BQL
2.82
BQL
BQL
BQL
BQL
10.40
15.0
NICKEL
BQL
1.33
0.77
7.53
4.76
0.87
BQL
14.90
100.0
SELENIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
SILVER
1.76
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
THALLIUM
BQL
BQL
BQL
30.10
2.70
BQL
BQL
BQL
0.28
VANADIUM
0.46
2.01
4.98
1.35
3.43
3.54
BQL
49.20
0.3
ZINC
13.80
11.00
21.40
19.20
26.90
29.10
13.50
129.00
1,000.0
Parameter
Well Number
15A NCAC 2L
Standard for Class
GAGroundwater
NC Groundwater
Protection
Standard
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
ANTIMONY
1.91.
BQL
BQL
BQL
BQL
2.76
BQL
BQL
*
1.0
ARSENIC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
BARIUM
306.00
201.00
210.00
344.00
163.00
213.00
103.00
120.00
700.0
BERYLLIUM
0.30
BQL
BQL
1.32
BQL
BQL
BQL
BQL
4.0
CADMIUM
BQL
0.22
0.39
0.28
0.68
0.32
BQL
0.45
2.0
CHROMIUM
15.00
0.94
4.90
26.00
5.15
2.33
1.83
3.62
10.0
COBALT
15.50
27.50
16.90
13.00
7.57
6.46
1.30
2.16
1.0
COPPER
11.60
3.89
6.01
16.10
15.90
11.30
5.75
6.62
1,000.0
LEAD
6.37
BQL
BQL
11.80
2.64
5.91
BQL
3.52
15.0
NICKEL
9.92
4.17
6.31
17.20
3.14
5.14
1.02
1.36
100.0
*
SELENIUM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
SILVER
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
THALLIUM
BQL
4.63
21.80
BQL
18.60
8.81
BQL
BQL
*
0.28
VANADIUM
30.20
BQL
2.23
52.20
5.94
1.94
4:86
6.74
*
0.3
ZINC
70.40
9.60
15.30
76.80
22.20
23.40
15.30
17.80
1,000.0
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
• NS - Not Sampled
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCent_0519
TABLE 4
GROUNDWATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GA Groundwater
Standard
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
'
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
0.18
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
1.60
BQL
BQL
BQL
BQL
1.6
BQL
BQL
BQL
BQL
BQL
BQL
6.0
'
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
BQL
BQL
BQL
BQL
BQL
BQL
7.0
'
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
'
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
I BQL
BQL
BQL
0.04
'
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.02
'
1,2-DICHLOROBENZENE
BQL
BQL
BQL
0.6
BQL
BQL
BQL
BQL
BQL
0.2
0.3
BQL
BQL
BQL
BQL
BQL
20.0
'
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
'
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
14)7
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
'
1,4-DICHLOROBENZENE
BQL
BQL
0.4
0.8
BQL
BQL
BQL
BQL
BQL
2.1
4.8
0.6
BQL
BQL
BQL
BQL
6.0
'
1,4-DIOXANE
BQL
3.5
BQL
17.3
BQL
BQL
BQL
4.2
BQL
BQL
BOIL
4.5
BQL
BQL
BQL
BQL
3.0
'
2-BUTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4,000.0
'
2-HEXANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
40.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
560.0
ACETONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
6000.0
'
ACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
BENZENE
BQL
BQL
BQL
1.0
0.3
BQL
BQL
BQL
BQL
1.1
0.4
BQL
BQL
'1.3
BQL
BQL
1.0
'
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
'
BROMOFORM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
'
BROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
10.0
CARBON DISULFIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
700.0
'
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
'
CHLOROBENZENE
BQL
BQL
BQL
35.40
0.30
BQL
BQL
BQL
BQL
2.0
9.4
0.7
0.2
BQL
BQL
BQL
50.0
'
CHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
BQL
BQL
1.1
BQL
BQL
3,000.0
'
CHLOROFORM
BQL
BQL
BQL
BQL
BQL
BQL
0.2
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
'
CHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3.0
'
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.5
BQL
12.3
0.2
BQL
BQL
0.8
0.5
BQL
70.0
'
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
'
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.41
DIBROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
ETHYLBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
..0
'
METHYL IODIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
5.0
'
STYRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
'
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.8
BQL
BQL
BQL
BQL
BQL
BQL
0.7
'
TOLUENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
'
TOTAL XYLENES
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.7
BQL
BQL
500.0
'
TRANS-I,2-DICHLOROETIENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
'
TRANS-I,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
'
TRANS-I,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
'
TRICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.70
BQL
BQL
BQL
QL
BQL
BQL
BQL
BQL
BQLBQL
BQL
BQL
BQL
B
BQL
BQL
BQL
BQLTRICHLOROFLUOROMETHANE
BQL
,3.0
2000.0
ACETATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
QVINYL
BL
BQL
BQL
BQL
BQL+
BOIL
B
88''
.0
CHLORIDE
BQL
BQL
BOIL
BOIL
QL
BQL
0.03VINYL
'
All results in parts per billion(ppb)
BQL - Below Method Detection Limit
B - Lab blank contamination
NS - Not Sampled
Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCent_0519
TABLE 5
GROUNDWATER SAMPLING RESULTS
APPENDIX II TRIGGERED CONSTITUENTS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
SW-846
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
Parameter
Method
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
GAGroundwater
Standard
1,3-Dichlorobenzene
8260
BQL
7.0
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
1,3-Dichloro ro ane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Dichlorodifluoromethane
8260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1,000.0
4,4'- DDD
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
4,4'- DDT
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
al ha-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.006
beta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
delta-BHC
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
Endrin
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.0
amma-BHC Lindane
8081
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.03
Mercury
1 7470
0.11
0.12
BQL
0.07
0.02
0.05
0.01
0.01
0.05
0.03
1.0
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
* - Standard not established
Shaded, cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
NA - Not analyzed
RuthCent_0519
TABLE 6
GROUNDWATER SAMPLING RESULTS
APPENDIX II INORGANIC CONSTITUENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2018
Parameter
Laboratory
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
Method
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GA Groundwater
Standard
ANTIMONY
SW 846 6010
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.76
BQL
BQL
1.0
ARSENIC
SW 846 6010
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
BARIUM
SW 846 6010
19.30
180.00
101.00
227.00
130.00
111.00
61.70
163.00
213.00
103.00
120.00
700.0
BERYLLIUM
SW 846 6010
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
CADMIUM
SW 846 6010
BQL
0.36
0.47
0.43
0.62
0.25
BQL
0.68
0.32
BQL
0.45
2.0
CHROMIUM
SW 846 6010
0.92
1.24
1.36
4.28
2.95
4.22
2.10
5.15
2.33
1.83
3.62
10.0
COBALT
SW 846 6010
BQL
1.32
BQL
36.70
2.98
BQL
BQL
7.57
8.40
1.30
2.10
1.0
COPPER
SW 8466010
4.48
4.45
6.55
5.66
12.60
4.24
BQL
15.90
11.30
5.75
6.62
1,000.0
CYANIDE
EPA 335.2
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
LEAD
SW 846 6010
BQL
BQL
2.82
BQL
BQL
BQL
BQL
2.64
5.91
BQL
3.52
15.0
MERCURY
SW 846 7470
BQL
0.07
0.11
0.12
BQL
0.07
0.02
0.02
0.02
BQL
0.12
1.0
NICKEL
SW 846 6010
BQL
1.33
0.77
7.53
4.76
0.87
BQL
3.14
5.14
1.02
1.36
100.0
SELENIUM
SW 8466010
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
SILVER
SW 846 6010
1.76
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
SULFIDE
EPA376.1
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
THALLIUM
SW 846 6010
BQL
BQL
BQL
30.10
2.70
BQL
BQL
.18.60
8.81
BQL
BQL
0.28
TIN
SW 846 6010
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2,000.0
VANADIUM
SW 846 6010
0.46
2.01
4.98
1.35
3.43
3.54
BQL
5.84
1.94
4.86
6.74
*
0.3
ZINC
SW 846 6010
13.60
11.00
21.40
19.20
26.90
29.10
13.50
22.20
23.40
15.30
17.80
1,000.0
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
* - Standard not established
Shaded cells denote concentrations that equal or exceed the 2L or Groundwater Protection Standards
NS - Not Sampled
NA - Not Analyzed
RuthCent_0519
TABLE 7
GROUNDWATER SAMPLING RESULTS
APPENDIX II VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameters
Sample Locations
15A NCAC 2L
Standard for Class
NC Groundwater
Protection Standard
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9 8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGroundwater
1,1,12-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
1.0
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
1,1,22-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.2
0.18
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
0.6
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
1.6
BQL
BQL
BQL
BQL
BQL
BQL
6.0
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
7.0
1,1-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
123-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
1,2,4-TRICHLOROBENZENE'
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
70.0
12-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.04
12-DIBROMOETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.02
12-DICHLOROBENZENE
BQL
BQL
BQL
0.6
BQL
BQL
BQL
BQL
BQL
BQL
BQL
20.0
12-DICHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
12-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
14.7
BQL
BQL
BQL
BOL
0.6
13-DICHLOROBENZENE
BQL
BQL
BQL
7.0
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
200.0
13-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
*
14-DICHLOROBENZENE
BQL
BQL
04
6.8
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
6.0
22-DICHLOROPROPANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
2-BUTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
4000.0
2-HEXANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOIL
40'"
.0
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
560.0
ACETONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
6000.0
ACETONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
42.0
ACROLEIN
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
4.0
ACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
ALLYL CHLORIDE 3-chloo ro ene
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BENZENE
BQL
BQL
BQL
1.0
0.3
BQL
BQL
BQL
1.3
BQL
BQL
1.0
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.6
BROMOFORM
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
BROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
10.0
DISULFIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQLCARBON
BQL
BQL
BQL
700.0
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
CHLOROBENZENE
BQL
BQL
BQL
35.4
0.3
BQL
BQL
0.2
BQL
BQL
BQL
50.0
CHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
11
BQL
BQL
000.0
BQL
BQL
BQL
BQL
BQL
BQL
0.2
BQL
BQL
BQL
BQL
70.0CHLOROFORM
CHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3.0
"
CHLOROPRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
CIS-I2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.8
0.5
BQL
70.0
CIS-I3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.41
DIBROMOMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
70.0
DICHLORODIFLOUROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.8
BQL
BQL
1000.0
ETHYLBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
ETHYL METHACRYLATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
ISOBUTYL ALCOHOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHACRYLONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHYL IODIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHYL METHACRYLATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
25.0
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQLki
PROPIONITRILE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQLSTYRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQLTETRACHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
TOLUENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
600.0
"
TOTALXYLENES
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.7
BQL
BQL
500.0
"
TRANS-I2-DICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
"
TRANS-I3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
TRANS-I4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
TRICHLOROETHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3.0
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2000.0
VINYL ACETATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
88.0
VINYL CHLORIDE
BQL
BQL
BQL
1.1
BQL
BQL
BQL
BQL
0.3
BQL
BQL
0.03
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• 'Analyzed by SW-846 Method 8270
• NS - Not Sampled
RuthCent_0519
TABLE 8
GROUNDWATER SAMPLING RESULTS
APPENDIX II SEMI -VOLATILE CONSTITUENTS BY SW-846 METHOD 8270
CENTRAL SANITARY LANDFILL (# 81-03), RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
15A NCAC 2L
Standard for Claw
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MW4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGroundwater
Standard
000-TRIETHYL PHOSPHOROTHIOATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
00-DIETHYL o-2-PYROZINYL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1245-TETRACHLOROSENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.0
124-TRICHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
70.0
70.0
14-NAPHTHOQUINONE
BQL
SOL
BQL
BQL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
1-NAPHTHYLAMINE
BQL
SOL
BQL
BQL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
2346-TETRACHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
245-TRICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
63.0
246-TRICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4.0
24-DICHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
8
0.9`'"""""""
24-DIMETHYLPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
100.0
24-DINITROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
24-DINITROTOLUENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
26-DICHLOROPHENOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
26-DINITROTOLUENE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
2-ACETYLAMINOFLUORENE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
2-CHLORONAPHTHALENE
BQL
SOL
BQL
BQL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
BQL
BQL
BQL
BQL2-CHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
2METHYLNAPHTHALENE
--
BQL
BOIL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
30.0
2METHYLPHENOL O-CRESOL
BQL
BOIL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4000
2NAPHTHYLAMINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2-NITROANILINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2-NITROPHENOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
3 & 4-METHYLPHENOL M &P-CRESOL
BQL
SOL
BQL
2.1
BQL
BQL
BQL
BQL
2.9
BQL
BQL
400/40
33'-DICHLOROBENZIDINE
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL33'-DIMETHYLBENZIDINE
BQL
SOL
BQL
BQL
BQL
SOL
SOL
BQL
BQL
3-METHYLCHOLANTHRENE
BQL
SOL
BQL
BQL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
3-NITROANILINE
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4,6-DINITRO-o-CREOSOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4-AMINOBIPHENYL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4-BROMOPHENYL PHENYL ETHER
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4-CHLORO-3-METHYLPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4-CHLOROANILINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
4-CHLOROPHENYL PHENYL ETHER
BQL
BQL
BQL
BQL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
4-NITROANILINE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
4-NITROPHENOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
5-NITRO-0-TOLUIDINE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BBQL
712-DIMETHYLBENZAANTHRACENE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
SOL
ACENAPHTHENE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQLL
850.0.0
ACENAPHTHYLENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
ACETOPHENONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
700
ANTHRACENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2000.0
BENZO A NTHRACENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.05
BENZO A PYRENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
BENZO B FLUORANTHENE
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
SOL
BQL
BQL
0.05
BENZO G HIPERYLENE
BQL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
200.0
BENZO KFLUORANTHENE
BQL
BQL
BQL
BQL
BOIL
SOL
BQL
SOL
SOL
BQL
SOL0.5
BENZYL ALCOHOL
BQL
SOL
BQL
BQL
BOIL
SOL
BQL
SOL
SOL
BQL
BQL
700.00
BIS(2-CHLORO-I-METHYLETHYL)ETHER
BQL
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
SOL
BQL
BQL
BIS2-CHLOROETHOX METHANE
BQL
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
SOL
BQL
BQL
BIS2-CHLOROETHYLETHER
BQL
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
SOL
BQL
BQL
0.031
BIS2-ETHYLHEXYLPHTHALATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQL3.0
L
BUYSENZYL PHTHALATE
BQL
BQL
BQL
BQL
BOIL
BQL
BQL
BQL
SOL
BQL
BQL
1,000.0
CHLOROBENZILATE
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
SOL
BQL
CHRYSENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
BQQL
DIALLATE TOTAL
BQL
BQL
BQL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
I BQL
RuthCent_0519
TABLE 8(CONT.)
Parameter
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GAGmundwater
Standard
DIBENZ AH NTHRACENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.005
DIBENZOFURAN
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
28.0
DIETHYL PHTHALATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
6000.0
DIMETHYL PHTHALATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
DI-N-BUTYLPHTHALATE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
700.0
DI-N-OCTYLPHTHALATE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
100.0
DIPHENYLAMINE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
ETHYL METHANESULFONATE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
FLUORANTHENE
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
300.0
FLUORENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
300.0
HEXACHLOROSENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.02
HEXACHLOROBUTADIENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.4
0.44
HEXACHLOROCYCLOPENTADIENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
50.0
HEXACHLOROETHANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.5
HEXACHLOROPROPENE
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
INDENO 123-CD PYRENE
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
0,05
"
ISODRIN
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
"
ISOPHORONE
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
BQL
BQL
40.0
ISOSAFROLE
SOL
BQL
SOL
BQL
SOL
BQLTBO
BQL
BQL
BQL
BQL
m-DINITROSENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHAPYRILENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHYL METHANESULFONATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N-NITROSODIETHYLAMINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
N-NITROSODIMETHYLAMINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.0007
N-NITROSODI-N-BUTYLAMINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
N-NITROSODI-N-PROPYLAMINE
BQL
BQL
BQL
BQL
SOL
BQL
BQL
SOL
BQL
BQL
"
N-NITROSODIPHENYLAMINE
SOL
BQL
SOL
BQL
SOL
BQL
BQL
SOL
BQL
BQL
"
N-NITROSOMETHYLETHYLAMINE
SOL
BQL
SOL
BQL
SOL
BQL
BQL
SOL
BQL
BQL
"
N-NITROSOPIPERIDINE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
"
N-NITROSOPYRROLIDINE
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
BQL
BQL
"
NAPHTHALENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
7.1.
BQL
BQL
6.0
NITROBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
O-TOLUIDINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
"
P-DIMETHYLAMINOAZOBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PENTACHLOROBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PENTACHLORONITROBENZENE
BQL
BQL
BQL
BQL
BQL
BQL
SOL
BQL
SOL
BQL
BQL
PHENACETIN
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
SOL
BQL
BQL
PHENANTHRENE
SOL
BQL
BQL
BQL
BQL
BQL
eQL
BQL
BQL
BQL
BQL
2W.0
PHENOL
BQL
BQL
BQL
BQL
BQL
BQL
eQL
BQL
BQL
BQL
BQL
30.0
p-PHENYLENEDIAMINE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PRONAMIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PYRENE
BQL
I BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
200.0
SAFROLE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
sym-TRINITROBENZENE
BQL
I BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
'-Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
•'-4,6-Dinitroo-creosole=4,6-Dinitro-2-methylphenol=2-Methy1-4,6-din-phenol
- Bis (2-chbro-1-methylethyl) ether = 2,2-Oxybis(1-chloropropane) = Bis (2-chloroisopropyp ether
3 - Butyl ben" phthalate = Benzylbutylphthalate
m-Dinitrobenzene = 1,3 Dinitrobenzene
s - p-Phenylenediamine = 1,4 Phenylenediamine
s - sym-Tdnkmbenzene = 1,3,5-Trinitrobenzene
NS - Not Sampled
RuthCent_0519
TABLE 9
GROUNDWATER SAMPLING RESULTS
APPENDIX II ORGANOPHOSPHORUS PESTICIDES BY SW-846 METHOD 8270
APPENDIX II HERBICIDES BY SW-846 METHODS 8151A and 8270D
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
15A NCAC 2L NC Groundwater
PARAMETER WELL NUMBER Standard for Class Protection
8103-MW-2 I 8103-MW-3 I 8103-MW-4 I 8103-MW-6 I 8103-MW-7 I 8103-MW-8 I 8103-MW-9 I 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard
PESTICIDES
0,0,0-TRIETHYL PHOSPHOROTHIOATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
DIMETHOATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
DISULFOTON
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
FAMPHUR
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
KEPONE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
METHYL PARATHION
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PARATHION
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PHORATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
1.0
THIONAZIN
BQL
BQL
BQL
BQL
I BQL
BQL
I BQL
BQL
I BQL
BQL
I BQL
HERBICIDES
2,4,5-T
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2,4,5-TP SILVEX
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
50.0
2,4-D
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
70.0
DINOSEB
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
TO
PENTACHLOROPHENOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.3
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• " Shaded ' - cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• ' - Thionazin = 0,0-Diethyl o-2-pyrozinyl
RuthCent_0519
TABLE 10
GROUNDWATER SAMPLING RESULTS
APPENDIX II PESTICIDES/PCBS BY SW-846 METHOD 8081/8082
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
PARAMETER
WELL NUMBER
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MW-4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GA Groundwater
Standard
4,4'-DDD
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
4,4'-DDE
BOL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
4,4'-DDT
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
ALDRIN
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
0.002
ALPHA-BHC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
0.006
AROCLOR 1016
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.09
AROCLOR 1221
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.09
AROCLOR 1232
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.09
AROCLOR 1242
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
0.09
AROCLOR 1248
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.09
AROCLOR 1254
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.09
AROCLOR 1260
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
0.09
BETA-BHC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
CHLORDANE TOTAL
BQL
BQL
BQL
BQL
BOL
BQL
BQL
BQL
BQL
BQL
BQL
0.1
DELTA-BHC
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.019
DIELDRIN
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.002
ENDOSULFANI
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
40.0
ENDOSULFAN II
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
42.0
ENDOSULFAN SULFATE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
*
40.0
ENDRIN
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
BQL
BOL
2.0
ENDRIN ALDEHYDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
2.0
GAMMA-BHC LINDANE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BOL
0.03
HEPTACHLOR
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.008
HEPTACHLOR EPDXIDE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.004
METHOXYCHLOR
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
40.0
TOXAPHENE
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
0.03
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• * - Standard not established
• Shaded Cells' ' ' denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• NS - Not Sampled
RuthCent_0519
TABLE 11
GROUNDWATER SAMPLING RESULTS
MONITORED NATURAL ATTENUATION PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
8103-MW-2
8103-MW-4
8103-MW-6
8103-MW-8
8103-MW-9
8103-MW-10D
8103-MW-11A
ACETIC ACID
AM23G
BQL
BQL
1,900 u /L
BQL
BQL
BQL
BQL
ALKALINITY
SM 2320B
44,200 ug/L
220,000 ug/L
486,000 ug/L
21,600 ug/L
13,500 ug/L
131,000 ug/L
421,000 ug/L
BOD
SM 5210B
BQL
BQL
4,230 u /L
BQL
BQL
BQL
BQL
BUTYRIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
CARBON DIOXIDE
SM 4500 CO2 C
1,760 u /L
156,000 u /L
380,000 u /L
58,100 u /L
71,300 u /L
110,000 u /L
347,000 u /L
CHLORIDE
SM 4500 Cl C
5,700 ug/L
7,600 ug/L
137,000 ug/L
48,900 ug/L
7,120 ug/L
12,800 ug/L
40,800 ug/L
250,000.0
COD
EPA 410.4
5,000 u /L
BQL
45,000 u /L
BQL
BQL
BQL
12,000 u /L
ETHANE
AM20GAX
BQL
BQL
0.26 ug/L
BQL
BQL
BQL
0.28 ug/L
ETHENE
AM20GAX
BQL
BQL
0.28 u /L
BQL
BQL
BQL
0.20 u /L
'
HEXANOIC ACID
AM23Gk73
L
BQL
BQL
BQL
BQL
BQL
BQL
HYDROGEN
AM20GAXnM
42.0 nM
43.0 nM
45.0 nM
43.0 nM
46.0 nM
25.0 u /L
i-HEXANOIC ACID
AM23GL
BQL
BQL
BQL
BQL
BQL
BQL
i-PENTANOIC ACID
AM23GL
BQL
BQL
BQL
BQL
BQL
BQL
IRON
EPA 200.7
/L
912 u /L
9,690u /L
1,010 u /L
66.0 ug/L
796 u /L
4,890 u /L
300.0
LACTIC ACID & HIBA
AM23G
L
BQL
BQL
BQL
BQL
BQL
BQL
METHANE
AM20GAX
BQL
0.91 ug/L
1,400 ug/L
BQL
BQL
580 ug/L
670 ug/L
NITRATE -NITROGEN
SM 4500 NO3 E
165 u /L
60 u /L
BQL
975 ug/L
170 ug/L
BQL
BQL
10,000.0
PENTANOIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
PROPIONOIC ACID
AM23G
BQL
BQL
640 ug/L
BQL
BQL
BQL
BQL
PYRUVIC ACID
AM23G
BQL
BQL
BQL
BQL
BQL
BQL
BQL
SULFATE
SM 4500 SO4 E
BQL
BQL
13,500 ug/L
BQL
BQL
BQL
BQL
250,000.0
SULFIDE
EPA 376.1
BQL
BQL
BQL
BQL
BQL
BQL
BQL
TOTAL ORGANIC CARBON
SM 5310C
BQL
1,410 ug/L
15,000 ug/L
1,240 ug/L
BQL
1,070 ug/L
5,680 ug/L
Notes:
• ug/L - micrograms per Liter (ppb)
• nM - nano Moles
• BQL - Below Method Detection Limit
• * - Standard not established
• NS - Not sampled
• Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
• - Analyzed approximately 2 hours out of hold time
RuthCent_0519
TABLE 12
GROUNDWATER AND SURFACE WATER SAMPLING RESULTS
C & D PARAMETERS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
Laboratory
Method
Sample Location
15A NCAC 2L
Standard for Class
GA Groundwater
NC Groundwater
Protection
Standard
15A NCAC 2B
Standard for Class
B,C Surface Water
8103-MW-2
8103-MW-3
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5A
ALKALINITY
SM 2320B
44,200
298,000
304,000
72,900
37,700
22,100
30,400
16,600
7,820
14,300
ALUMINUM
SW 846 6010C
325.0
305.0
1,240.0
475.0
1,630.0
3,760.0
761.0
191.0
528.0
666.0
3,500
CHLORIDE
SM 4500 Cl C
5,700.0
47,000.0
13,300.0
7,600.0
9,500.0
10,900.0
8,550.0
5,700.0
5,700.0
5,700.0
250,000.0
230,000"'
IRON
EPA 200.7
730.0
1,060.0
6,620.0
3,670.0
2,050.0
2,690.0
900.00
449.0
511.00
718.00
300.0
1,000'
MANGANESE
SW 846 6010
11.9
306.0
4,850.0
2,220.0
87.5
133.0
123.0
39.8
16.7
25.1
50.0
MERCURY
SW 846 7470
BQL
0.07
0.02
0.02
BQL
0.12
0.04
0.06
0.08
0.03
1.0
0.012
SULFATE
SM 4500 SO4 E
BQL
43,100
10,300
BQL
83,100
69,500
10,400
BQL
BQL
BQL
250,000.0
TDS
SM 2540 C
131,000
540,000
403000.00
150,000
124,000
135,000
77,000
68,000
42,000
63,000
500,000.0
TETRAHYDROFURAN
SW 8468260B
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
BQL
Notes:
All results in parts per billion (ppb)
BQL - Below Method Detection Limit
* - Standard/Limit not established
NS - Not sampled
I'] - Action Level
Shaded cells denote, concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels
RuthCent_0519
TABLE 13
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
0
r. r. ..
r r r: rrr
r• r rrr
�aaaa��a��aaaaaaaa
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichl..propane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• ' - Appendix I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list
• 4 - Aluminum added to C&D constituent list
RuthCent_0519
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
04/11/2001
09/12-13/2001
04/03/2002
06/27/2002
10/02/2002
04/02-03/2003
09/03/2003
04/06/2004
10/27/2004
04/05/2005
09/08/2005
04/04-05/2006
10/26-27/2006
5/22-23/2007
10/23-26/2007
05/06-08/2008
09/22-25/2008
8103-MW-2
I
I
I
I
I
I
I
I
I
I
I
1
I, MINA
I, MNA, C&D
I, MNA, C&D
8103-MW-3
I
I
I
I
I
I
I
I
I
I
I
I
I
1
1, C&D
1, C&D
8103-MW-4
I'll
1, 11 t
I'll
I, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MINA
1, 11(t), MNA
8103-MW-6
I'll
1, 11 t
I'll
I, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MINA
1, 11(t), MNA
8103-MW-7
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
I'll
I,IIt
8103-MW-8
I'll
I, II t
I'll
I, II t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
1, 11, MNA
I, 11(t), MNA
8103-MW-9
I'll
I, II t
I'll
I, II t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11 t
I'll
1, 11(t), MNA
I, 11, MNA
1, 11(t), MNA
8103-MW-10A
8103-MW-10B
I,IIt)
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-10C
I,IIt)
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-10D
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
1,IIt,MNA
1,IIt,MNA
1,111,MNA
8103-MW-11A
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I, lilt), MNA
I, lilt), MNA
I,11t,MNA
8103-MW-11B
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
I,IIt
8103-MW-12
I
I
I
I
I
I
I
I
I
I
I
1
I, C&D
I, C&D
8103-MW-13
I
I
I
I
I
I
I
I
I
I
I
1
I, C&D
I, C&D
8103-MW-14
I, C&D
I, C&D
8103-MW-15
1, C&D
1, C&D
I - denotes well was sampled for Appendix I constituents on this date
II - denotes well was sampled for Appendix II constituents on this date
II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
MNA - denotes well was sampled for Monitored Natural Attenuation constituents
C&D - denotes well was sampled for Construction and Demolition constituents
• ' - Appendix I volatiles only
• 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list
4 - Aluminum added to C&D constituent list
RuthCent_0519
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY. NORTH CAROLINA
Well
05/18-05/21, 2009
10/07-10/09, 2009
05/17-05/20, 2010
09/20-09/23, 2010
04/25-05/02, 2011
09/27-09/30, 2011
04/30-05/03, 2012
09/25-10/03, 2012
04/15-18/2013
09/23-09/28, 2013
04/28-05/01, 2014
09/29-10/04, 2014
04/27-05/02, 2015
09/28-10/07, 2015
04/26-05/05, 2016
8103-MW-2
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D°
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&Ds
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
I, MNA, C&D
8103-MW-3
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-4
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-6
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-7
1,11
I, II t
1,11
I, II t
1,11
I, II(t)s, MNA
8103-MW-8
1 I, II, MNA
I, 11(t), MNA
I, 11(t), MNA
I, II, MNA
I, II(t)s, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
1 I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-9
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t)z, MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
I, II(t), MNA
I, II, MNA
8103-MW-10A
8103-MW-10B
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(t)s
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10C
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(t)s
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-10D
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t)s, MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
8103-MW-11A
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t)s, MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
I, II(t), MNA
8103-MW-11 Bi
I, II t
I, II t
I, II t
I, II t
I, II t
I, II(tp
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
I, II(t)
8103-MW-12
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-13
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-14
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
8103-MW-15
I, C&D
I, C&D
I, C&D
I, C&D°
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D
I, C&Ds
I, C&D
I, C&D
I, C&D
I, C&D
• I - denotes well was sampled for Appendix I constituents on this date
• II - denotes well was sampled for Appendix II constituents on this date
• II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
• MNA - denotes well was sampled for Monitored Natural Attenuation constituents
• C&D - denotes well was sampled for Construction and Demolition constituents
• 1 - Appendix I volatiles only
• 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
• 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
• 4 - Aluminum added to C&D constituent list
5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list
6 - Tetrahydrofuran added to C&D constituent list
RuthCent_0519
TABLE 13 (cont.)
SUMMARY OF SAMPLING EVENTS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
Well
09/19-09/22, 2016
05/03-05/09, 2017
10/02-10/05, 2017
05/10-05/17, 2018
10/01-10/08, 2018
05/07-05/15, 2019
8103-MW-2
I, MINA, C&D
I, MINA, C&D
I, MINA, C&D
I, MINA, C&D
I, MNA, C&D7
I, II, MINA, C&D
8103-MW-3
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D'
I, II, C&D
8103-MW-4
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA'
I, II, MNA
8103-MW-6
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
I, II, MNA
8103-MW-7
I, II t
1,11
I, II t
1,11
I, II(t)
1,11
8103-MW-8
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA7
I, II, MNA
8103-MW-9
I, 11(t), MNA
I, II, MNA
I, 11(t), MNA
I, II, MNA
I, II(t), MNA'
I, II, MNA
8103-MW-10A
8103-MW-10B
I, II t
I, II t
I, II t
I, II t
I, II(t)
I, II(t)
8103-MW-10C
I, II t
I, II t
I, II t
I, II t
I, II(t)
I, II(t)
8103-MW-10D
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, 11(t), MNA
I, II(t), MNA'
I, II(t), MNA
8103-MW-11A
I, 11(t), MNA
I, 11(t), MINA
I, 11(t), MNA
I, 11(t), MINA
I, II(t), MNA7
I, II(t), MINA
8103-MW-11B
I, II t
I, II t
I, II t
I, II t
I, II(t)
I, II(t)
8103-MW-12
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D7
I, II, C&D
8103-MW-13
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D7
I, II, C&D
8103-MW-14
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D7
I, II, C&D
8103-MW-15
I, C&D
I, C&D
I, C&D
I, C&D
I, C&D7
I, II, C&D
I - denotes well was sampled for Appendix I constituents on this date
II - denotes well was sampled for Appendix II constituents on this date
II(t) - denotes well was sampled for Appendix II triggered constituents
(1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane,
endrin, and gamma-BHC) on this date
MINA - denotes well was sampled for Monitored Natural Attenuation constituents
C&D - denotes well was sampled for Construction and Demolition constituents
' -Appendix I volatiles only
3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list
a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list
"-Aluminum added to C&D constituent list
5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list
6 - Tetrahydrofuran added to C&D constituent list
- 1,4-Dioxane added to all sample locations
RuthCent_0519
TABLE14
GROUNDWATER FLOW RATES
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Hydraulic
Conductivity
Effective
Velocity
Velocity
Well No.
(cm/sec)
Gradient
Porosity
(cm/sec)
(ft/yr)
8103-MW-2
1.3 x 10-5
0.067
.20
4.36 x 10-6
4.52
8103-MW-4
3.7 x 10-6
0.056
.20
1.04 x 10-6
1.08
8103-MW-6
2.4 x 10-5
0.114
.20
1.37 x 10-5
14.12
8103-MW-7
2.9 x 10-6
0.196
.201
2.84 x 10-6
2.94
8103-MW-8
1.6 x 10-4
0.041
.20
3.28 x 10-5
33.97
8103-MW-9
1 2.1 x 10-5
0.038
.20
4.02 x 10-6
4.16
The above results were obtained by using the relation:
V = Ki
Where K = hydraulic conductivity
i = gradient
n = effective porosity
V = velocity
Porosity value may not reflect true nature of fractured bedrock.
8103-MW-7 is screened in rock.
RuthCent_0519
TABLE15
SURFACE WATER SAMPLING RESULTS
APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
Sample Location
15A NCAC 213
Standard for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5A
ANTIMONY
BQL
BQL
BQL
BQL
ARSENIC
BQL
BQL
BQL
BQL
50.0
BARIUM
52.40
35.20
34.60
43.10
BERYLLIUM
BQL
BQL
BQL
BQL
6.5
CADMIUM
BQL
BQL
BQL
0.25
2.0
CHROMIUM
1.34
BQL
0.96
1.24
50.0
COBALT
BQL
BQL
BQL
BQL
COPPER
3.16
3.58
3.77
2.86
7.0111
LEAD
BQL
BQL
BQL
BQL
25.0
NICKEL
BQL
BQL
0.94
BQL
88.0
SELENIUM
BQL
BQL
BQL
BQL
5.0
SILVER
BQL
BQL
BQL
BQL
0.06�11
THALLIUM
BQL
BQL
BQL
BQL
VANADIUM
2.59
0.86
1.48
2.28
ZINC
11.20
14.30
14.20
16.60
50.0
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• [1] - Action Level
• NS - Not sampled. Dry location.
RuthCent_0519
TABLE 16
SURFACE WATER SAMPLING RESULTS
APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameters
Sample Location
15A NCAC 2B/EPA
Standards for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
1,1,1,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
1,1,1-TRICHLOROETHANE
BQL
BQL
BQL
BQL
2,500.0
1,1,2,2-TETRACHLOROETHANE
BQL
BQL
BQL
BQL
1,1,2-TRICHLOROETHANE
BQL
BQL
BQL
BQL
1,1-DICHLOROETHANE
BQL
BQL
BQL
BQL
20,000.0
1,1-DICHLOROETHENE
BQL
BQL
BQL
BQL
5,400.0
1,2,3-TRICHLOROPROPANE
BQL
BQL
BQL
BQL
1,2-DIBROMO-3-CHLOROPROPANE
BQL
BQL
BQL
BQL
1,2-DIBROMOETHANE
BQL
BQL
BQL
BQL
1,2-DICHLOROBENZENE
BQL
BQL
BQL
BQL
470.0
1,2-DICHLOROETHANE
BQL
BQL
BQL
BQL
1,2-DICHLOROPROPANE
BQL
BQL
BQL
BQL
1,4-DICHLOROBENZENE
BQL
BQL
BQL
BQL
100.0
1,4-DIOXANE
BQL
BQL
BQL
BQL
2-BUTANONE
BQL
BQL
BQL
BQL
160,000.0
2-HEXANONE
BQL
BQL
BQL
BQL
4-METHYL-2-PENTANONE
BQL
BQL
BQL
BQL
26,000.0
ACETONE
BQL
BQL
BQL
BQL
2,000.0
ACRYLONITRILE
BQL
BQL
BQL
BQL
BENZENE
BQL
BQL
BQL
BQL
BROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
BROMODICHLOROMETHANE
BQL
BQL
BQL
BQL
BROMOFORM
BQL
BQL
BQL
BQL
BROMOMETHANE
BQL
BQL
BQL
BQL
CARBON DISULFIDE
BQL
BQL
BQL
BQL
CARBON TETRACHLORIDE
BQL
BQL
BQL
BQL
CHLOROBENZENE
BQL
BQL
BQL
BQL
140.0
CHLOROETHANE
BQL
BQL
BQL
BQL
CHLOROFORM
BQL
BQL
BQL
BQL
CHLOROMETHANE
BQL
BQL
BQL
BQL
CIS-1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
CIS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
12.0
DIBROMOCHLOROMETHANE
BQL
BQL
BQL
BQL
DIBROMOMETHANE
BQL
BQL
BQL
BQL
ETHYLBENZENE
BQL
BQL
BQL
BQL
97.0
IODOMETHANE
BQL
BQL
BQL
BQL
METHYLENE CHLORIDE
BQL
BQL
BQL
BQL
STYRENE
BQL
BQL
BQL
BQL
TETRACHLOROETHENE
BQL
BQL
BQL
BQL
TOLUENE
BQL
BQL
BQL
BQL
11.0
TOTALXYLENES
BQL
BQL
BQL
BQL
670.0
TRANS- 1,2-DICHLOROETHENE
BQL
BQL
BQL
BQL
TRANS-1,3-DICHLOROPROPENE
BQL
BQL
BQL
BQL
12.0
TRANS-1,4-DICHLORO-2-BUTENE
BQL
BQL
BQL
BQL
TRICHLOROETHENE
BQL
BQL
BQL
BQL
TRICHLOROFLUOROMETHANE
BQL
BQL
BQL
BQL
VINYL ACETATE
BQL
BQL
BQL
BQL
VINYL CHLORIDE
BQL
BQL
BQL
BQL
Notes:
• All results in parts per billion (ppb)
• BQL - Below Method Detection Limit
• ' - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards
RuthCent_0519
TABLE 17
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS
CENTRAL SANITARY LANDFILL (# 81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameters
Well Number
15A NCAC 2L
Standard for Class
NC Groundwater
Protection
8103-MW-2
8103-MW-3
8103-MW4
8103-MW-6
8103-MW-7
8103-MW-8
8103-MW-9
8103-MW-10B
8103-MW-10C
8103-MW-10D
8103-MW-11A
8103-MW-11B
8103-MW-12
8103-MW-13
8103-MW-14
8103-MW-15
GA Groundwater
Standard
ALUMINUM
1,760.0
3,500.0
ANTIMONY
,7.91„
2.76
1.0
CHROMIUM
28.0
15.0
26.0
10.0
`
COBALT
1.32
1.2 J
30.7
2.98
15.6
15.55
27.5
16.9
13.0
7.57
8.4
1.3
2.1
1.0
IRON
- 730.0
1,060.0
912.0
•9,690.0 =
1010.0 -
.796.0
4,890.0-
6,620.0 -
_ 3,670.0•
2y050A
2,690.0
300.0
`
MANGANESE
306.0
4,850.0
2,220.0
87.5
133.0
50.0
`
TDS
540,000.0
1
1
1
500,000.0
`
THALLIUM
30.1 °
2.7
° 4.63
21.80 °
18.'6
- 8.81 a
0.28
VANADIUM
0.46
.. ..
2.01
4.98 ..
1.35
..
3.43.
3.54
e ..
49.20. ..
30.20
..
2.23
..
.. 52.20
5."
..
.. 1.94
4.86.
6.74
.. ..
0.3
1,2-DICHLOROPROPANE
14.7
0.6
`
1,4-DICHLOROBENZENE
6.8
6.0
`
1,4-DIOXANE
3.5
17.3
4.2
.4.5,
3.0
`
BENZENE
1.0
1.1
1.3
1.0
`
NAPHTHALENE
7.1
6.0
`
TETRACHLOROETHENE
0.8
0.7
`
VINYL CHLORIDE
1.1
0.7
0.8
0.3
0.03
`
Notes:
• All results in parts per billion (ppb)
• ' - Standard not established
Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards
RuthCeM_0519
TABLE 18
NOTIFICATION TABLE
CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS
CENTRAL SANITARY LANDFILL (#81-03)
RUTHERFORD COUNTY, NORTH CAROLINA
MAY 7-15, 2019
Parameter
Sample Location
15A NCAC 2B
Standard for Class
B,C Surface Water
8103-SW-2
8103-SW-3
8103-SW-4
8103-SW-5
MERCURY
0.04
0.06
0.08
0.03
0.012
Notes:
• All results in parts per billion (ppb)
• * - Standard not established
• Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels
• �11 - Action Level
• NS - Not sampled. Dry location
RuthCent_0519