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HomeMy WebLinkAbout8103_8105_Rutherford_CDLF_Permit_GWAReport_FID1389606_20200112REPORT OF GROUNDWATER ASSESSMENT JANUARY 2020 RUTHERFORD COUNTY LANDFILL RUTHERFORDTON, NORTH CAROLINA C&D Landfill — Phase 2 Expansion Permit No. 8103-CDLF-2002 Prepared For: Rutherford County Solid Waste Dept. Rutherfordton, North Carolina BLE Project Number J20-13675-04 February 7, 2020 x _ SEAL 1043 111(410% BLE North Carolina Business Licenses C-284 & C-1538 IM 13UNNELL LAMMONS ENGINEERING 6004 Ponders Court I Greenville, 5C 29615 864.288.1265 A 864.286.4330 a info@ble[orp.rom BLECORMOM 91JNNELL � CANNONS ENGINEERING February 7, 2020 Solid Waste Section Division of Waste Management NCDEQ-ARO 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Attention: Ms. Jaclynne Drummond, Hydrogeologist Subject: Report of Groundwater Assessment — January 2020 Background for the Phase 2 C&D Expansion Area Rutherford County Landfill, Permit #8103-CDLF-2002 Rutherford County, North Carolina BLE Project No. J20-13675-04 Dear Ms. Drummond: Bunnell-Lammons Engineering, Inc. (BLE) is pleased to submit this report to the North Carolina Division of Waste Management (NCDWM) Solid Waste Section (SWS) for the Phase 2 construction and demolition (C&D) landfill expansion area on behalf of Rutherford County, Odom Engineering, PLLC (Odom), and McGill Associates (McGill). The report addresses the groundwater assessment activities required by the SWS in support of the permit application (in progress) for the Phase 2 C&D landfill expansion. Sincerely, BUNNELL LAMMONs ENGINEERING INC. acl Andrew W 1evqyder P Chief H Registe CC: ydrogeologist �,•■' ERR red, NC No. 1475■�+``�p�'� GE �SrJ9 ter `bLoan '�..� W, A1� ► ►,1«sal Mr. James Kilgo - Rutherford County Mr. Pete Dickerson, P.E. - Odom Mr. Mark Cathey, P.E. - McGill *tvl -' Mark S. Preddy, P.G. Chief Hydrogeologist 11 f 1 f 1 Registered, NC No ' r� SEAL 1043 IV —' ww� /111NtiI 6004 Ponders Court, Greenville, SC 29615 (,864.288.1265 a 864.288.4430 Wg info@hleMrp.com BLECORP.COM 1s 1m 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 TABLE OF CONTENTS 1.0 PROJECT INFORMATION........................................................................................................1 2.0 SCOPE OF SERVICES PERFORMED......................................................................................2 3.0 RESULTS....................................................................................................................................... 3 3.1 Groundwater Levels and Flow Direction......................................................................................... 3 3.2 Laboratory Analyses........................................................................................................................ 3 4.0 CONCLUSIONS AND RECOMMENDATIONS ....................................................................... 4 4.1 Groundwater Levels and Flow Direction......................................................................................... 4 4.2 Laboratory Analyses........................................................................................................................ 4 5.0 QUALIFICATIONS OF REPORT.............................................................................................. 5 6.0 CLOSING.......................................................................................................................................5 Tables Table 1 Groundwater Elevations and Well Data Table 2 Background Sampling Matrix — Water Quality Table 3 Metals List — Background Sampling Table 4 Volatile Organic Compounds (VOC) Data (January 2020) Table 5 Alkalinity, Chloride, Sulfate, Total Dissolved Solids, & Field Parameters (January 2020) Table 6 Total & Dissolved Metals Data (January 2020) Figures Figure 1 Groundwater Elevation Contour Map — January 21, 2020 Appendices Appendix A Field Sampling Logs Appendix B Laboratory Analytical Data Appendix C Figure 2 and Tables from the May 2018 Semi -Annual Sampling Report by Scarlett Geophysical Consulting P.C. Appendix D Figure 2 and Tables from the October 2018 Semi -Annual Sampling Report by Scarlett Geophysical Consulting P.C. Appendix E Figure 2 and Tables from the May 2019 Semi -Annual Sampling Report by Scarlett Geophysical Consulting P.C. iofi 1s 1m 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 1.0 PROJECT INFORMATION The project information below was obtained from multiple in -person and telephone meetings and emails between BLE, McGill, Odom, Rutherford County, and the SWS. The subject landfill site is located in Rutherford County, North Carolina, between the cities of Rutherfordton and Spindale with a physical address of 656 Laurel Hill Dr, Rutherfordton, North Carolina. Rutherford County owns and operates a closed Subtitle D municipal solid waste (MSW) landfill and an active C&D landfill consisting of one waste unit designated Phase 1. The county plans to expand the C&D landfill in an area designated Phase 2 which is approximately 17 acres and construct one new approximate 5.5-acre C&D waste unit in the expansion area. Rutherford County has retained McGill as design and permitting engineer for the project. Rutherford County has also retained BLE (as a subconsultant to McGill) to provide design hydrogeologic services, geotechnical engineering, monitoring plan services, and construction quality control services for the project. Work on the project has begun. McGill has defined the limits of the expansion area and developed a conceptual design plan. BLE has performed six (6) borings and installed five (5) piezometers in the expansion area as part of the design hydrogeologic report (DHR). Several discussions with the SWS occurred after the DHR work started. The SWS expressed concern about development of a new waste unit in the expansion area due to an ongoing assessment of corrective measures (performed by others) for the existing C&D and MSW waste units. As a result, the SWS informed Rutherford County, McGill, and BLE that they will require a background assessment of the groundwater quality in the expansion area as a condition of the permitting process for Phase 2. BLE prepared a work plan to perform the required sampling, analysis, data evaluation, and reporting for the background assessment and submitted the document to the SWS on January 16, 2020 (FID 1387733). The SWS approved the plan on January 17, 2020 (FID 1387736). The SWS approved plan included two sampling events to be conducted 30 days apart. This report documents the results and findings of the first sampling event conducted on January 21-22, 2020. 1 of 5 1s 1M 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 2.0 SCOPE OF SERVICES PERFORMED BLE personnel collected water levels from selected wells on January 21, 2020. The water level data is shown on Table 1. A groundwater elevation map was prepared from the data (Figure 1). BLE personnel conducted groundwater sampling of the eight (8) wells identified on the Tables 2 and 3. The wells were purged and sampled within 24 hours of purging. We attempted to purge three (3) well volumes. Less than three well volumes were purged for low yield wells. Efforts were made to reduce sample turbidity during sampling to reduce the potential for false -positive metals results. Sampling logs were prepared for each well sampled (Appendix A). BLE submitted the groundwater samples to a North Carolina certified laboratory (Pace Analytical Services, Inc. — Columbia [dba Shealy Environmental]) for analysis via laboratory courier. The laboratory performed the analyses indicted on the matrix (Tables 2 and 3). Field parameters were measured in the field by BLE during sampling and reported on the field sampling logs. The laboratory analysis reports are included in Appendix B. 2 of 5 1s 1m 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 3.0 RESULTS 3.1 Groundwater Levels and Flow Direction BLE prepared a groundwater elevation contour map for January 21, 2020 to illustrate groundwater flow direction at the site (Figure 1). The data indicates that the groundwater flow direction in January 2020 is consistent with that observed in November 2019 (shown in the work plan) and is primarily southwesterly through the Phase 2 expansion area. 3.2 Laboratory Analyses The laboratory and field analysis data has been summarized on Tables 4, 5, and 6. Table 4 summarizes the volatile organic compound (VOC) results. Table 5 summarizes the inorganic and field parameter analyses. Table 6 summarizes the total and dissolved metals analysis. The North Carolina Groundwater Quality Standards (NC2L) promulgated in the North Carolina Rules for Environmental Management - Groundwater Classification and Standards, [Rules] T15A NCAC 02L .0202 are included on the tables. The NC2L groundwater standards (aka Maximum Contaminant Level [MCLs]) are utilized for regulatory compliance. The North Carolina Interim Maximum Allowable Concentrations (IMACs) are also included on the summary tables and are provided for reference only. The VOC data on Table 4 indicates that no concentrations of Appendix II VOCs (except carbon disulfide in B-42), tetrahydrofuran, or 1,4-dioxane were detected in the groundwater samples. The concentration of carbon disulfide detected in B-42 (1.0 µg/L) does not exceed the NC2L standard of 700 µg/L. The data on Table 5 indicates that none of the inorganic parameters analyzed in the laboratory exceed their NC2L standards, if established. The data indicates that the pH field parameter was outside the range of NC2L standard limits of 6.5 to 8.5 in LFG-6 (6.48) and B-41 (6.20). The total and dissolved metals data on Table 6 indicates that concentrations of two (2) metals exceed their NC2L standards. These metals included iron and manganese. Laboratory analyses detected concentrations of total iron in LFG-7 (350 µg/L) and B-42 (1,300 µg/L). These detected concentrations of total iron exceed the applicable NC2L standard of 300 µg/L. Laboratory analyses detected concentrations of total and/or dissolved manganese in B-40D (150 µg/L, for both total and dissolved), B-42 (58 µg/L, total), and B-44 (total 310 µg/L and dissolved 320 µg/L). These detected concentrations of manganese exceed the applicable NC2L standard of 50 µg/L. 3 of 5 1s 1m 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 4.0 CONCLUSIONS AND RECOMMENDATIONS 4.1 Groundwater Levels and Flow Direction The groundwater flow direction through the Phase 2 expansion area (Figure 1) appears similar to that observed by BLE in 2019 and is also similar to that observed in the historical semi-annual groundwater monitoring reports prepared by Scarlett Geophysical Consulting, P.C. (SGC). Copies of the groundwater contour maps and summary tables from the SGC semi-annual reports for May 2018 (Appendix C), October 2018 (Appendix D), and May 2019 (Appendix E) are included for reference. These documents were sourced from facility records. These data include water levels for each event on the Summary of Monitoring Well Data (Table 1) and the Groundwater Contour Map (Figure 2) of each resource. We conclude that the water levels and groundwater flow direction in January 2020 are fundamentally compliant with those shown in the work plan and are acceptable for execution of the plan without changes. 4.2 Laboratory Analyses We conclude that the laboratory and field analysis data collected during the January 2020 event do not provide evidence that the groundwater in the Phase 2 area has been impacted by a contaminant release. The findings for each parameter are discussed below. The carbon disulfide detected in B-42 (1.0 µg/L) does not exceed the NC2L standard of 700 µg/L (Table 5) and is detected at the level of quantitation (LOQ) of 1.0 µg/L for the laboratory analytical method. Therefore, it is possible that the result is a false positive. Additionally, it is noted that concentrations of carbon disulfide are routinely detected as naturally occurring compounds in groundwater sourced from the degradation of organic materials. We conclude that the groundwater in the Phase 2 expansion area has not been impacted by a VOC release. The pH field parameter was outside the range of NC2L standard limits of 6.5 to 8.5 in LFG-6 (6.48) and B-41 (6.20) [Table 5]. However, these pH values are typical for the pH values observed in groundwater in the region. For example, the pH values observed during the last three reported semi-annual sampling events and documented on the Ground and Surface Water Sampling Field Data (Table 2) in Appendices C through D indicate that the pH values in the groundwater monitoring wells range from 4.59 to 9.47. We conclude that the out of range pH values observed in LFG-6 and B-41 in January 2020 are indicative of naturally occurring groundwater chemistry. None of the other field or laboratory parameter results summarized on Table 5 provide evidence of a contaminant release. The metals iron and manganese exceed their NC2L standards at various sampling locations in the Phase 2 expansion area (Table 6). It's noted that the SWS's primary concern for potential contaminant impacts in the Phase 2 area was related to the disposal (and subsequent remediation by removal) of alum sludge. We understand that concentrations of aluminum have been detected in groundwater monitoring MW-14 and MW- 15 which have been suspected of being sourced from the sludge. It's noted that the SWS has not established a groundwater standard for aluminum (Table 6). Summary tables of metals detected in groundwater are included in the historical semi-annual groundwater monitoring reports prepared by SGC. Those metals data include Tables 3, 5, 6, 11, 12, & 17 from May 2018 (Appendix C), Tables 3, 5, 6, 7, 12, & 17 from October 2018 (Appendix D), and Tables 3, 5, 6, 11, 12, & 17 from May 2019 (Appendix E). 4 of 5 1s 1m 1i Report of Groundwater Assessment -- Phase 2 Expansion Area February 7, 2020 Rutherford County Landfill, North Carolina BLE Project No. J20-13675-04 These historical data indicate that concentrations of metals have been detected in the facility groundwater monitoring network which are similar to that observed in the Phase 2 expansion area. Specifically, the concentrations of iron and manganese observed in the Phase 2 area appear to be in the range of the concentrations observed in the facility monitoring network where no release of metals has been documented. Additionally, the concentrations of aluminum observed in the Phase 2 area are much lower than those observed in MW-14 and MW-15 in May 2018 (Appendix C). We conclude that the data from the January 2020 groundwater sampling event do not indicate that there has been a release of metals in the Phase 2 expansion area. We recommend that groundwater sampling and analysis continue per the SWS approved work plan. The next event is scheduled for approximately February 24, 2020. 5.0 QUALIFICATIONS OF REPORT The activities and evaluative approaches used in this assessment are consistent with those normally employed in hydrogeological and environmental assessments of this type. Our evaluation of site conditions has been based on our understanding of the site and project information and the data obtained in our exploration. This report has been prepared on behalf of and exclusively for the use of Rutherford County, North Carolina. This report and the findings contained herein shall not, in whole or in part, be used or relied upon by any other party (excluding the SWS) without BLE's prior written consent. 6.0 CLOSING We appreciate the opportunity to be of service to Rutherford County. Please contact us at (864) 288-1265 if you have any questions or comments. 5of5 Tables Table 1 Groundwater Elevations and Well Data Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 Wen Well Location Northing (feet) Easting (feet) Lat. North (dd) Long. West (dd) Top Casing Elevation Gad. Surface Elevation Depth to GW (feet - btoc) Groundwater Elevation Screen Depth (bgs) Screen Elevation Well Total Well Monitors Depth (bgs) Top of Rock Top of Depth (bgs) Rock Elev. MW-1 Outside 596,114.73 1,120,714.40 35.35204161 -81.94932162 1,007.76 1,006.05 51.31 956.45 35.5 - 45.5 970.5 - 960.5 Soil/PWR 45.5 45.5 960.5 MW-2 Outside 596,355.31 1,119,904.89 35.35263626 -81.95205930 994.86 994.47 37.56 957.30 50.0 - 60.0 944.5 - 934.5 Soil 60.0 NE NE MW-3 Outside DNA DNA DNA DNA 860.28 859.62 NM NM 37.0 - 47.0 822.6 - 812.6 Soil 47.0 NE NE MW4 Outside DNA DNA DNA DNA 851.03 849.72 NM NM 40.0 - 50.0 809.7 - 799.7 Soil 50.0 NE NE MW-5 Outside DNA DNA DNA DNA DNA DNA NM NM DNA - DNA DNA - DNA DNA DNA DNA DNA MW-6 Outside DNA DNA DNA DNA 834.90 833.43 NM NM 22.5 - 37.5 810.9 - 795.9 Soil/PWR 37.5 38.0 795.4 MW-7 Outside DNA DNA DNA DNA 892.70 890.51 NM NM 39.0 - 54.0 851.5 - 836.5 PWR/BR 54.0 30.0 860.5 MW-8 Outside DNA DNA DNA DNA 860.31 857.86 NM NM 29.5 - 44.5 828.4 813.4 Soil 44.5 NE NE MW-9 Outside DNA DNA DNA DNA 867.25 864.97 NM NM 22.5 - 37.5 842.5 - 827.5 Soil 37.5 NE NE MW-10A Outside DNA DNA DNA DNA 837.23 834.73 NM NM 91.0 - 101.0 743.7 - 733.7 BR 101.0 39.0 795.7 MW-10B Outside DNA DNA DNA DNA 836.15 834.50 NM NM 32.0 - 37.0 802.5 - 797.5 Soil/PWR 37.0 39.0 795.5 MW-10C Outside DNA DNA DNA DNA 836.19 834.50 NM NM 11.0 - 16.0 823.5 - 818.5 Soil 16.0 39.0 795.5 MW-lOD Outside DNA DNA DNA DNA 837.23 834.73 NM NM 56.0 - 66.0 778.7 768.7 BR 66.0 39.0 795.7 MW-11A Outside DNA DNA DNA DNA 817.18 815.39 NM NM 35.0 - 45.0 780.4 - 770.4 PWR/BR 45.0 36.0 779.4 MW-11B Outside DNA DNA DNA DNA 817.72 816.32 NM NM 10.0 - 20.0 806.3 796.3 Soil 20.0 36.0 780.3 MW-12 (B-22) Outside DNA DNA DNA DNA 886.68 884.33 NM NM 35.5 - 45.5 848.8 - 838.8 Soil/PWR 45.5 45.5 838.8 MW-13 (B-6) Outside 594,988.71 1,120,032.88 35.34889347 -81.95149400 962.47 960.35 77.90 884.57 73.0 - 88.0 887.3 - 872.3 BR 88.0 65.0 895.3 MW-14 Outside 595,446.06 1,118,985.16 35.35006391 -81.95505174 868.94 866.54 20.74 848.20 17.4 - 32.4 849.1 - 834.1 DNA 32.4 DNA DNA MW-15 (B-29) Outside 595,672.95 1,118,986.20 35.35068714 -81.95507090 889.13 887.52 27.61 861.52 28.0 - 38.0 859.5 - 849.5 BR 38.0 26.0 861.5 LFG-6(B-13) Inside 595,955.90 1,119,501.27 35.35150632 -81.95337249 941.81 939.68 17.55 924.26 21.0 - 31.0 918.7 - 908.7 BR 31.0 1.0 938.7 LFG-7 (B-17) Inside 596,091.76 1,119,401.05 35.35187127 -81.95372202 963.14 960.89 35.87 927.27 40.0 - 50.0 920.9 - 910.9 BR 50.0 34.0 926.9 LFG-8 (B-12S) Outside 596,098.89 1,120,135.92 35.35195090 -81.95125927 972.53 970.56 18.10 954.43 23.0 - 33.0 947.6 - 937.6 Soil 33.0 NE NE LFG-8A(B-12D) Outside 596,099.74 1,120,129.76 35.35195271 -81.95128000 972.23 971.12 26.20 946.03 94.0 - 104.0 877.1 - 867.1 BR 104.0 74.0 897.1 LFG-9 Outside 596,979.03 1,120,087.63 35.35436417 -81.95150888 992.20 988.32 DRY DRY DNA - DNA DNA - DNA DNA DNA DNA DNA LFG-10 Outside 596,108.37 1,120,128.56 35.35197633 -81.95128489 975.07 971.36 DRY DRY DNA - DNA DNA - DNA DNA DNA DNA DNA LFG-II Outside 596,417.18 1,119,314.26 35.35275789 -81.95404542 980.37 977.53 DRY DRY DNA - DNA DNA - DNA DNA DNA DNA DNA PZ-A Outside DNA DNA DNA DNA DNA DNA NM NM DNA - DNA DNA - DNA DNA DNA DNA DNA PZ-B Outside DNA DNA DNA DNA DNA DNA NM NM DNA - DNA DNA - DNA DNA DNA DNA DNA B-1 Outside DNA DNA DNA DNA 1,049.56 1,047.38 NM NM 68.0 - 78.0 979.4 - 969.4 BR 78.0 42.0 1,005.4 B-2 Outside DNA DNA DNA DNA 1,007.84 1,005.62 NM NM 55.0 - 65.0 950.6 - 940.6 PWR 65.0 NE NE B-3 Outside DNA DNA DNA DNA 964.99 961.74 NM NM 58.0 - 68.0 903.7 - 893.7 PWR 68.5 68.5 893.2 B-4 Outside DNA DNA DNA DNA 989.58 987.89 NM NM 65.0 - 75.0 922.9 - 912.9 PWR 75.0 NE NE B-5S Outside 595,535.35 1,120,260.97 35.35041341 -81.95078391 928.29 926.87 13.36 914.93 18.0 - 28.0 908.9 - 898.9 Soil 28.0 NE NE B-51) Outside 595,537.71 1,120,255.16 35.35041939 -81.95080362 929.48 927.07 13.37 916.11 41.0 - 51.0 886.1 876.1 BR 51.0 34.0 893.1 B-7 Outside DNA DNA DNA DNA 929.94 927.41 NM NM 57.0 - 67.0 870.4 - 860.4 PWR/BR 65.0 65.0 862.4 B-8 Outside DNA DNA DNA DNA 918.95 916.46 NM NM 58.0 - 68.0 858.5 - 848.5 Soil 74.0 74.0 842.5 B-9S Outside DNA DNA DNA DNA 862.07 860.05 NM NM 20.0 - 30.0 840.1 - 830.1 Soil 43.6 43.6 816.5 B-913 Outside DNA DNA DNA DNA 862.12 860.18 NM NM 61.0 - 71.0 799.2 789.2 BR 72.0 43.5 816.7 B-10 Outside 596,444.04 1,120,317.76 35.35291367 -81.95068409 1,021.02 1,018.72 56.00 965.02 70.0 - 80.0 948.7 - 938.7 BR 80.0 48.5 970.2 B-11 Outside DNA DNA DNA DNA 1,016.01 1,015.07 NM NM 50.0 - 60.0 965.1 955.1 PWR 60.0 NE NE B-14 Outside DNA DNA DNA DNA 972.50 971.17 NM NM 21.0 - 100.0 950.2 - 871.2 Open BR 100.0 21.0 950.2 B-15 Outside DNA DNA DNA DNA 899.84 897.55 NM NM 24.0 - 34.0 873.6 - 863.6 BR 34.0 11.0 886.6 B-16S Outside 595,956.62 1,118,692.59 35.35144218 -81.95608345 857.04 854.96 11.58 845.46 18.0 - 28.0 837.0 - 827.0 Soil 28.0 28.0 827.0 B-16D Outside 595,950.84 1,118,692.17 35.35142627 -81.95608429 856.95 854.97 11.31 845.64 42.0 - 52.0 813.0 - 803.0 BR 52.0 34.0 821.0 B-19 Outside 596,711.81 1,119,761.02 35.35360358 -81.95257715 962.02 959.99 17.20 944.82 48.0 - 58.0 912.0 - 902.0 Soil 65.0 65.0 895.0 B-20 Outside 596,020.52 1,119,045.38 35.35164654 81.95490720 899.56 897.60 25.28 874.28 23.0 - 33.0 874.6 - 864.6 Soil/PWR/BR 33.0 27.0 870.6 B-21 Outside DNA DNA DNA DNA 932.22 930.04 NM NM 40.0 - 50.0 890.0 - 880.0 BR 50.0 5.0 925.0 B-23 Outside 595,969.15 1,120,391.19 35.35161542 -81.95039060 1,001.66 999.37 51.90 949.76 61.0 - 71.0 938.4 - 928.4 Soil/PWR 73.6 73.6 925.8 B-24 Outside DNA DNA DNA DNA 1,047.64 1,045.54 NM NM 61.0 - 71.0 984.5 - 974.5 BR 71.0 40.5 1,005.0 B-25 Outside DNA DNA DNA DNA 954.41 951.46 NM NM 40.0 - 50.0 911.5 - 901.5 Soil/PWR 50.0 50.0 901.5 B-26S Outside 597,214.05 1,119,896.59 35.35499400 -81.95217277 949.55 947.63 12.43 937.12 25.0 - 35.0 922.6 - 912.6 Soil 35.0 NE NE B-26D Outside 597,207.53 1,119,892.86 35.35497579 -81.95218462 949.85 947.52 12.51 937.34 76.0 - 86.0 871.5 - 861.5 BR 86.0 54.0 893.5 B-27 Outside DNA DNA DNA DNA 929.27 927.96 NM NM 5.0 - 7.0 923.0 - 921.0 Soil 7.0 NE NE B-28 Outside DNA DNA DNA DNA 858.16 857.31 NM NM 2.0 - 4.0 855.3 - 853.3 Soil 4.0 NE NE B-29 Outside DNA DNA DNA DNA 889.54 887.58 NM NM 28.0 - 38.0 859.6 - 849.6 BR 40.0 26.0 861.6 B-30S Outside DNA DNA DNA DNA 896.62 894.78 NM NM 13.0 - 23.0 881.8 - 871.8 Soil 23.0 NE NE B-30D Outside DNA DNA DNA DNA 896.54 894.69 NM NM 30.0 - 40.0 864.7 - 854.7 BR 72.0 24.0 870.7 B-31 Outside 596,878.95 1,120,001.94 35.35408229 -81.95178619 1,002.65 1,000.80 48.91 953.74 61.0 - 71.0 939.8 - 929.8 PWR 72.0 72.0 928.8 B-32 Outside DNA DNA DNA DNA 978.51 975.98 NM NM 63.0 - 73.0 913.0 - 903.0 BR 73.0 53.6 922.4 B-33 Inside DNA DNA DNA DNA 924.80 923.48 NM NM 14.0 - 24.0 909.5 - 899.5 Soil/PWR 24.0 24.0 899.5 B-34 Outside DNA DNA DNA DNA 929.79 928.61 NM NM 57.0 - 67.0 871.6 - 861.6 BR 67.0 40.0 888.6 B-35 Outside 596,673.92 1,119,491.24 35.35347748 -81.95347777 958.54 957.29 33.65 924.89 50.0 - 60.0 907.3 - 897.3 PWR 60.0 60.0 897.3 B-36 Inside 5D84A.29 ,1N.63 35.35121025 895248148 4.75 3 0 09 20 20 15.5 929.7 Outside N DNA DNA 91 8.33 NM 1 4 4B-37 0 SIR. 13.0 835.8 B-38 Outside DNA DNA DNA DNA 847.24 845.20 NM NM 4.5 6.5 1 840.7 838.7 Soil 6.5 NE NE Piezometers B40S/40D through B-44 installed by BLE B-00S Inside 595,833.87 1,119,297.50 35.35115453 -81.95404340 915.44 912.40 26.80 888.64 35.8 - 45.8 876.6 - 866.6 BR 46.0 26.0 886.4 B-40D Inside 595,840.93 1,119,293.66 35.35117361 -81.95405700 915.65 912.92 28.41 887.24 65.8 - 75.8 847.1 - 837.1 BR 76.0 26.0 886.9 B-41 Inside 595,739.81 1,119,415.19 35.35090584 -81.95363951 917.94 914.81 21.87 896.07 24.8 - 34.8 890.0 - 880.0 BR 35.0 22.0 892.8 B-42 Inside 596,039.12 1,119,652.32 35.35174724 -81.95287446 948.78 945.47 13.36 935.42 33.8 - 43.8 911.7 - 901.7 BR 44.0 18.5 927.0 B-44 Inside 595,922.12 1,119,897.37 35.35144591 -81.95204131 955.13 952.21 21.02 934.11 28.8 - 38.8 923.4 913.4 PWR 39.0 39.0 913.2 Notes: All survey data in RED provided by McGill Associates, all units in feet. All values shown to the nearest 0.1-ft have been rounded. All wells installed by Others unless noted otherwise. Inside = Within or near the boundary of the Phase 2 area Outside = Outside the boundary of the Phase 2 area Water levels in BLUE measured on 1/21/2020 by BLE NM = Not measured bgs = below ground surface btoc = below top of casing Soil = Soil PWR = Partially Weathered Rock BR = Bedrock DNA = Data Not Available NE = Assumed Not Encountered Well Sampled January 22, 2020 Prepared by: AWA Table 1 GWM Jan2020 of Tables RCLF Baekgro ind Jm202O.xlsx Checked by: DPO Table 2 Background Sampling Matrix -- Water Quality Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 2 Events Station ID App II VOCs EPA 8260D Tetrahydrofuran EPA 8260D 1,4-Dioxane EPA 8260D SIM Total Metals* Methods 6020B & 7470A Dissolved Metals* Methods 6020B & 7470A Alkalinity SM 2320B Chloride 9056A Sulfate 9056A Total Dissolved Solids SM 2540C-2011 pH Field Sp. Cond. Field Temp. Field B-13 (LFG-6) X X X X X X X X X X X X B-17 (LFG-7) X X X X X X X X X X X X B-36 X X X X X X X X X X X X B40S X X X X X X X X X X X X B-40D X X X X X X X X X X X X B-41 X X X X X X X X X X X X B-42 X X X X X X X X X X X X B-44 X X X X X X X X X X X X Notes: * See Table 3 for list of metals Prepared by: AWA Checked by: MSP T2 Sampling Matrix of Tables RCLF Background Jm2020.xlsx Table 3 Metals List - Background Sampling Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 Metals Total Aluminum (Al) Total Lead (Ph) Dissolved Aluminum (Al) Dissolved Lead (Pb) Total Antimony (Sb) Total Manganese (Mn) Dissolved Antimony (Sb) Dissolved Manganese (Mn) Total Arsenic (As) Total Mercury (Hg) Dissolved Arsenic (As) Dissolved Mercury (Hg) Total Barium (Ba) Total Nickel (Ni) Dissolved Barium (Ba) Total Beryllium (Be) Dissolved Beryllium (Be) Dissolved Nickel (Ni) Total Selenium (Se) Dissolved Selenium (Se) Total Cadmium (Cd) Total Silver (Ag) Dissolved Cadmium (Cd) Dissolved Silver (Ag) Total Chromium (Cr) Total Thallium (Tl) Dissolved Chromium (Cr) Dissolved Thallium (Tl) Total Cobalt (Co) Total Vanadium (V) Dissolved Cobalt (Co) Dissolved Vanadium (V) Total Copper (Cu) Total Zinc (Zn) Dissolved Copper (Cu) Dissolved Zinc (Zn) Total Iron (Fe) Dissolved Iron (Fe) Notes• Dissolved metals will be laboratory filtered. Prepared by: AWA Checked by: MSP T3 Metals List of Tables RCLF Background Jan202O.xlsx Table 4 Volatile Organic Compounds (VOC) Data (January 2020) Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 Sampled by BLE on January 22, 2020 (Shealy Project VA23042) COMPOUND UNITS LOQ DL MCL LFG-6 (B-13) LFG-7 (B-17) B-36 B-40S B-40D B-41 B-42 B-44 Carbon Disulfide µg/1 1.0 0.40 700 <0.40 <0.40 <0.40 <0.40 <0.40 <0.40 1.0 <0.40 All Other Appendix II VOCs µg/1 V V V ND ND ND ND ND ND ND ND Tetrahydrofuran µg/1 5.0 1.0 NE <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 <1.0 1,4-Dioxane µg/1 1 3.0 1 1.0 3.0 1 <1.0 <1.0 I <1.0 <1.0 I <1.0 I <1.0 I <1.0 I <1.0 Notes: LOQ = Level of Quantitation DL = Detection Limit MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013 Table 4 VOCs (Jan202O) of Tables RCLF Background Jan202O.xlsx ND = Not Detected NE = Not Established; North Carolina has not established a MCL V = Variable Samples collected by BLE on January 22, 2020 Analysis by EPA Method 8260D and 8260D (SIM) Prepared by: AWA Checked by: IAI Table 5 Alkalinity, Chloride, Sulfate, Total Dissolved Solids, & Field Parameters (January 2020) Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 Sampled by BLE on January 22, 2020 (Shealy Project VA23042) CLASS -- COMPOUND Method UNITS LOQ DL MCL LFG-6 (B-13) LFG-7 (B-17) B-36 B-40S B-40D B-41 B-42 B-44 Alkalinity SM 2320B mg/L 20 20 NE <20 <20 <20 30 87 30 84 24 Chloride 9056A mg/L 1.0 0.20 250 2.1 1.9 3.7 3.0 2.3 3.3 8.3 2.5 Sulfate 9056A mg/L 1.0 0.20 250 <0.20 <0.20 <0.20 5.8 4.9 13 16 <0.20 Total Dissolved Solids SM 2540C-2011 mg/L 25 25 500 31 47 25 66 130 76 160 50 pH Field SU NA NA 6.5 to 8.5 6.48 7.61 7.07 7.53 7.44 6.20 7.71 6.93 Specific Conductivity Field µmhos/cm NA NA NE 68.32 113.2 40.31 135.9 206.7 144.5 266.4 100.8 Temperature Field °C NA NA NE 15.9 14.9 15.3 14.8 14.5 14.2 14.5 15.3 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013 Yellow shaded cells indicate exceedance of MCL. LOQ = Level of Quantitation DL = Detection Limit NA = Not Applicable NE = Not Established; North Carolina has not established a MCL Table 5 Inorgan (Jan202O) of Tables RCLF Background Jan202O.xlsx Prepared by: AWA Checked by: IAI Table 6 Total & Dissolved Metals Data (January 2020) Phase 2 C&D Expansion Area Rutherford County Landfill Rutherfordton, North Carolina Permit No. 8103-CDLF-2002 BLE Project No. J20-13675-04 Sampled by BLE on January 22, 2020 (Shealy Project VA23042) TEST UNITS LOQ DL MCL LFG-6 (B-13) LFG-7 (B-17) B-36 B-40S B-40D B-41 B-42 B-44 Total Aluminum (Al) µg/1 40 10 NE 41 350 40 80 96 25 J 2,600 110 Dissolved Aluminum (Al) µg/l 40 10 NE <10 63 Ili <10 <10 <10 290 <10 Total Antimony (Sb) µg/l 2.0 0.50 1(i) <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 0.81 J <0.50 Dissolved Antimony (Sb) µg/1 2.0 0.50 1(i) I <0.50 <0.50 <0.50 <0.50 <0.50 <0.50 1.8 J 0.5 J Total Arsenic (As) µg/1 2.0 1.3 10 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.7 J <1.3 Dissolved Arsenic (As) µg/1 2.0 1.3 10 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 1.4 J <1.3 Total Barium (Ba) µg/1 5.0 1.3 700 11 5.0 25 42 12 54 43 50 Dissolved Barium (Ba) µg/1 5.0 1.3 700 11 2.3 J 25 41 11 53 22 48 Total Beryllium (Be) µg/1 0.40 0.15 4(i) <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Dissolved Beryllium (Be) µg/l 0.40 0.15 4(i) <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Total Cadmium (Cd) µg/l 0.50 0.13 2 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 Dissolved Cadmium (Cd) µg/l 0.50 0.13 2 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 <0.13 Total Chromium (Cr) µg/l 5.0 1.3 10 <1.3 1.6 J <1.3 <1.3 <1.3 <1.3 2.1 J <1.3 Dissolved Chromium (Cr) µg/l 5.0 1.3 10 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Cobalt (Co) µg/1 5.0 1.3 1(i) <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 3.1 J Dissolved Cobalt (Co) µg/1 5.0 1.3 1(i) <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 2.8 J Total Copper (Cu) µg/1 5.0 1.3 1,000 1 <1.3 2.0 J <1.3 <1.3 <1.3 <1.3 1.7 J <1.3 Dissolved Copper (Cu) µg/1 5.0 1.3 1,000 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Iron (Fe) µg/1 50 13 300 43 J 350 65 98 120 48 J 1,300 170 Dissolved Iron (Fe) µg/l 50 13 300 14 J 14 J <13 16 J 56 26 J 160 <13 Total Lead (Pb) µg/1 1.0 0.25 15 <0.25 0.88 J <0.25 <0.25 <0.25 1.1 1.7 <0.25 Dissolved Lead (Pb) µg/l 1.0 0.25 15 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 Total Manganese (Mn) µg/l 5.0 1.3 50 2.1 J 6.8 6.1 48 150 46 58 310 Dissolved Manganese (Mn) µg/1 5.0 1.3 50 <1.3 <1.3 5.6 46 150 45 45 320 Total Mercury (Hg) µg/1 0.20 0.091 1 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 Dissolved Mercury (Hg) µg/1 0.20 0.091 1 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 <0.091 Total Nickel (Ni) µg/1 5.0 1.3 100 1 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 2.3 J <1.3 Dissolved Nickel (Ni) µg/1 5.0 1.3 100 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Selenium (Se) µg/1 5.0 1.3 20 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Dissolved Selenium (Se) µg/l 5.0 1.3 20 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 <1.3 Total Silver (Ag) µg/1 1.0 0.25 20 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 Dissolved Silver (Ag) µg/l 1.0 0.25 20 1 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 <0.25 Total Thallium (Tl) µg/l 0.50 0.15 0.2(i) <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Dissolved Thallium (Tl) µg/1 0.50 0.15 0.2(i) <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 <0.15 Total Vanadium (V) µg/1 5.0 2.5 0.3(i) <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 6.3 <2.5 Dissolved Vanadium (V) µg/1 1 5.0 1 2.5 1 0.3(i) <2.5 <2.5 <2.5 <2.5 <2.5 <2.5 4.2 J <2.5 Total Zinc (Zn) µg/1 1 10 2.5 1,000 1 2.5 J 6.5 J <2.5 1 <2.5 <2.5 <2.5 4.2 J <2.5 Dissolved Zinc (Zn) µg/1 1 10 2.5 1,000 1 <2.5 3.3 J <2.5 1 <2.5 <2.5 <2.5 <2.5 <2.5 Notes: MCL = Maximum Contaminant Level, as established in the NCDENR Classifications of Water Quality Standards Applicable to Groundwaters of North Carolina, Section 15A NCAC 2L.202. Effective April 1, 2013 Yellow shaded cells indicate exceedance of MCL. Refer to the laboratory data sheets for detected concentrations which are J values (estimated values above DL but below LOQ). (i) = Interim Maximum Allowable Concentrations (IMACs) April 6, 2018 - Non Regulatory (Reference Only) LOQ = Level of Quantitation DL = Detection Limit NE = Not Established; North Carolina has not established a MCL Analysis by EPA Methods 6020B & 7470A Prepared by: AWA Checked by: IAFTJD Table 6 Metals (Jan202O) of Tables RCLF Background Jan202O.xlsx Figures 0 I -o- K0 .'•J TOWN OF RUTHERFORDTON WASTEWATER TREATMENT FACILITY LFG-5 W-6 CLOSED MSW LANDFILL LFG-2 0 — B-6T a $4' EXISTING SCALEHOU SE �a 0 THUNDER ROAD MW-10 A,B LFG-1 4 MW-10 CD \ S Q -----ROW----- ROW ----- ROW ----- ROW— ----RO ---ROW ----- ROW— -- {} Ir o -O- ---- ----- ROW ----- ROW ----- ROW--- -----ROW— ---ROW -----ROW I EXISTING DUKE ENERGY EASEMENT I I I I I I I I I I I I 3 I I I I I � I I I � I I o I I I I I o f I I I DRAWN: KLW CHECKED: TJD APPROVED: AWA DATE: 02-06-20 CAD FILE: RUTHERFORDLF-04WTM JOB NO: J20-13675-04 ?I, umpm;'E'lll EXISTING ANIMAL SHELTER FACILITY 771, -0- APPROXIMATE FACILITY LIMITS ��i��- �����%����A �������� PHASEy�2 -C&D EXPANSION %LFG-7 (B-1 / 991.21 hLFG -6 iB-13Y \ 6 - 44 1 � o _FG-8A* B=121 111i�1 F3-8 (B-12S isBUNNELL � t,aMa Ns im i EF16ilEERIHU 6004 Ponders Court, Greenville, SC 29515 PFrone: (664126B-1265 Fm (064) 289-4430 MONITORING LOCATION LEGEND ♦ LFG-9 LANDFILL GAS MONITORING WELL, SURVEYED BY MCGILL ASSOCIATES, 12/17/19 0 LFG-5 LANDFILL GAS MONITORING WELL, APPROXIMATE LOCATION 0 MW-8 GROUNDWATER MONITORING WELL, APPROXIMATE LOCATION MW-1 GROUNDWATER MONITORING WELL, SURVEYED BY MCGILL ASSOCIATES, 12/17/19 ® B-18 BORING, APPROXIMATE LOCATION + B-43 BORING, SURVEYED BY MCGILL ASSOCIATES, 12/17/19 ' lqW-1 SURFACE WATER SAMPLING LOCATION, APPROXIMATE • B-41 PIEZOMETER, SURVEYED BY MCGILL ASSOCIATES, 12/17/19 O B-15 PIEZOMETER LOCATION, APPROXIMATE LFG-8A* IGNORED FOR CONTOURING PURPOSES. WELL REPRESENTS UNIQUE HYDROGEOLOGIC CONDITIONS INDUSTRIAL PARK ROAD , o- TOPOGRAPHIC &GEOLOGIC LEGEND EXISTING 2' CONTOUR - LIDAR/ALS/MCGILL EXISTING 10' CONTOUR - LIDAR/ALS/MCGILL 900 POTENTIOMETRIC SURFACE CONTOUR LINE (CI = 10') 956.32 WATER ELEVATIONS IN BLUE COLLECTED BY BLE ON JANUARY 21, 2020 f — — — — — GROUNDWATER FLOW DIRECTION SW-4 NOTE: APPROXIMATE LANDFILL GAS AND GROUNDWATER MONITORING WELLS, APPROXIMATE BORINGS, AND APPROXIMATE SURFACE WATER SAMPLING LOCATIONS ALL PROVIDED BY ODOM ENGINEERING GENERAL MAP REFERENCE 1.1 Iv LAUREL HILL DRIVE 200 100 0 200 400 APPROXIMATE SCALE IN FEET 11111f1jIt," ~ � t T LO f+rf1fift1110% GROUNDWATER ELEVATION CONTOUR MAP (JANUARY 21, 2020) RUTHERFORD COUNTY LANDFILL RUTHERFORDTON, NORTH CAROLINA FIGURE NO. 1 APPENDIX A FIELD SAMPLING LOGS it L IMM BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 941.81 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 2.13 Well ID #: LFG-6 (B-13) Land Surface Elevation (ft msl): 939.68 Downgradient: Screened Interval (ft bgs): 21.0 - 31.0 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: Yes Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 33.13 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 20.21 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 12.92 Well Yield (subjective): Low 1 Casing Volume in gallons (CV) = LWC x 0.17 = 2.20 Sample Date and Time: Sampled at 1220 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 6.59 Remarks: Dry at 3.0 gallons of water removed. Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 3.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 3.0 Sample Time (military) 1246 1249 1220 pH (S.U.) 6.47 6.51 6.48 Sp. Cond. (umhos/cm) 66.52 67.91 68.32 Water Temp. (°C) 16.0 1 16.3 1 1 1 1 15.9 Turbidity (NTU) 70.8 53.9 44.6 COMMENTS/OBSERVATIONS: it Im BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 963.14 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 2.25 Well ID #: LFG-7 (B-17) Land Surface Elevation (ft msl): 960.89 Downgradient: Screened Interval (ft bgs): 40.0 - 50.0 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: Yes Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 52.25 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 35.38 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 16.87 Well Yield (subjective): Low 1 Casing Volume in gallons (CV) = LWC x 0.17 = 2.87 Sample Date and Time: Sampled at 1120 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 8.60 Remarks: Dry at 6.5 gallons of water removed. Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 6.5 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 3.0 6.0 Sample Time (military) 1127 1129 1132 1120 pH (S.U.) 7.58 7.66 7.73 7.61 Sp. Cond. (umhos/cm) 70.87 109.6 110.15 113.2 Water Temp. (°C) 15.7 1 15.6 1 15.4 1 1 1 14.9 Turbidity (NTU) 78.1 38.1 27.9 18.6 COMMENTS/OBSERVATIONS: it L IMM BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 948.12 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 2.97 Well ID #: B-36 Land Surface Elevation (ft msl): 945.15 Downgradient: Screened Interval (ft bgs): 22.0 - 32.0 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 34.97 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 18.01 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 16.96 Well Yield (subjective): Low 1 Casing Volume in gallons (CV) = LWC x 0.17 = 2.88 Sample Date and Time: Sampled at 1203 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 8.65 Remarks: Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 10.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 3.5 7.0 10.0 Sample Time (military) 1218 1223 1224 1228 1203 pH (S.U.) 7.21 6.02 6.41 6.06 7.07 Sp. Cond. (umhos/cm) 41.42 41.76 40.85 40.60 40.31 Water Temp. (°C) 15.9 1 15.2 1 15.2 1 15.9 1 1 15.3 Turbidity (NTU) 349 74.9 28.8 20.6 19.7 COMMENTS/OBSERVATIONS: It Im BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 915.44 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 3.04 Well ID #: B-40S Land Surface Elevation (ft msl): 912.40 Downgradient: Screened Interval (ft bgs): 35.8 - 45.8 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 48.84 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 32.51 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 16.33 Well Yield (subjective): Low 1 Casing Volume in gallons (CV) = LWC x 0.17 = 2.78 Sample Date and Time: Sampled at 845 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 8.33 Remarks: Dry at 8.5 gallons of water removed Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 8.5 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 4.0 8.0 Sample Time (military) 937 940 944 845 pH (S.U.) 7.47 7.33 6.66 7.53 Sp. Cond. (umhos/cm) 379.6 123.1 120.4 135.9 Water Temp. (°C) 12.2 1 15.2 1 15.1 1 1 1 14.8 Turbidity (NTU) >2,000 300 2.43 3.58 COMMENTS/OBSERVATIONS: it L IMM BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 915.65 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 2.73 Well ID #: B-40D Land Surface Elevation (ft msl): 912.92 Downgradient: Screened Interval (ft bgs): 65.8 - 75.8 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 78.53 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 33.70 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 44.83 Well Yield (subjective): Low 1 Casing Volume in gallons (CV) = LWC x 0.17 = 7.62 Sample Date and Time: Sampled at 835 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 22.86 Remarks: Dry at 9.0 gallons of water removed Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 9.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 8.5 Sample Time (military) 910 915 835 pH (S.U.) 7.33 7.25 7.44 Sp. Cond. (umhos/cm) 384.2 188.5 206.7 Water Temp. (°C) 14.9 1 14.8 1 1 1 1 14.5 Turbidity (NTU) >2,000 488 35.2 COMMENTS/OBSERVATIONS: it L IMM BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 917.94 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 3.13 Well ID #: B-41 Land Surface Elevation (ft msl): 914.81 Downgradient: Screened Interval (ft bgs): 24.8 - 34.8 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 37.93 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 25.26 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 16.26 Well Yield (subjective): Intemediate 1 Casing Volume in gallons (CV) = LWC x 0.17 = 2.76 Sample Date and Time: Sampled at 910 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 8.28 Remarks: Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 9.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 3.0 6.0 9.0 Sample Time (military) 1008 1014 1021 1028 910 pH (S.U.) 6.23 6.30 6.27 6.21 6.20 Sp. Cond. (umhos/cm) 176.2 143.2 134.7 135.2 144.5 Water Temp. (°C) 14.5 1 14.5 1 14.7 1 14.7 1 1 14.2 Turbidity (NTU) 945 164 65.8 26.9 20.8 COMMENTS/OBSERVATIONS: it L IMM BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 948.78 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 3.31 Well ID #: B-42 Land Surface Elevation (ft msl): 945.47 Downgradient: Screened Interval (ft bgs): 33.8 - 43.8 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 47.11 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 15.70 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 31.41 Well Yield (subjective): Interemediate 1 Casing Volume in gallons (CV) = LWC x 0.17 = 5.34 Sample Date and Time: Sampled at 925 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 16.02 Remarks: Dry at 12.5 gallons of water removed. Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 12.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 6.0 12.0 Sample Time (military) 1046 1053 1059 925 pH (S.U.) 6.71 6.83 7.86 7.71 Sp. Cond. (umhos/cm) 252.1 269.8 271.8 266.4 Water Temp. (°C) 14.6 1 14.8 1 14.8 1 1 1 14.5 Turbidity (NTU) >2,000 >2,000 359 44.9 COMMENTS/OBSERVATIONS: it im BUNNELL-LAMMONS ENGINEERING, INC. FIELD DATA INFORMATION LOG FOR GROUNDWATER SAMPLING Page 1 of 1 Date: Jan. 21, 2020 Casing Diameter: 2 inches Field Personnel: IAI Casing Material: PVC Site Name: RCLF Measuring Point Elevation (ft msl): 955.13 BLE Job #: J20-13675-04 Height of Riser (ft above land surface): 2.92 Well ID #: B-44 Land Surface Elevation (ft msl): 952.21 Downgradient: Screened Interval (ft bgs): 28.8 - 38.8 Upgradient: Dedicated Pump or Bailer: No Weather Conditions: Sunny Steel Guard Pipe Around Casing: No Air Temperature: 25 OF Locking Cap: Yes Total Well Depth in feet btoc (TWD) = 41.72 Protective Post/Abutment: No Depth to Groundwater in feet btoc (DGW) = 22.03 Well Integrity Satisfactory: Yes Length of Water Column (LWC) = TWD - DGW = 19.69 Well Yield (subjective): Intermediate 1 Casing Volume in gallons (CV) = LWC x 0.17 = 3.35 Sample Date and Time: Sampled at 1150 on 1/22/2020 Standard Evacuation Volume (3 casing volumes) = 10.04 Remarks: Method of Well Evacuation: Submersible Pump Method of Sample Collection: Disp. Bailer Total Volume of Water Removed (gallons): 12.0 gallons Volume Purged (gallons) FIELD ANALYSIS Initial 4.0 8.0 12.0 Sample Time (military) 1151 1154 1158 1204 1150 pH (S.U.) 7.18 7.18 7.10 6.81 6.93 Sp. Cond. (umhos/cm) 102.7 102.2 90.36 87.51 100.8 Water Temp. (°C) 14 1 14.7 1 15.1 1 14.4 1 1 15.3 Turbidity (NTU) >2,000 >2,000 349 152 80.7 COMMENTS/OBSERVATIONS: APPENDIX B LABORATORY ANALYTICAL DATA SHEALY ENVIRONMENTAL SERVICES, INC. Report of Analysis County of Rutherford 289 N. Main Street Rutherfordton, NC 28139 Attention: James Kilgo Project Name: Rutherford County Landfill Project Number: 13675-04 Lot Number:VA23042 Date Completed:02/07/2020 Revision Date: 02/06/2020 NO N � � J N N � 02/10/2020 9:56 AM Approved and released by: Lab Director - Greenville: Lucas Odom PCCRFp 4 AM AC CF ED I T E D qe 11900 eLAa The electronic signature above is the equivalent of a handwritten signature. This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 1 of 91 SHEALY ENVIRONMENTAL SERVICES, INC. SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639 Case Narrative County of Rutherford Lot Number: VA23042 This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary following this Case Narrative. The sample receiving date is documented in the header information associated with each sample. All results listed in this report relate only to the samples that are contained within this report. Sample receipt, sample analysis, and data review have been performed in accordance with the most current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or discussed below. If you have any questions regarding this report please contact the Shealy Project Manager listed on the cover page. Report Revision Per client request, sample -001 was re -analyzed for total metals. The sample was reanalyzed in duplicate to confirm the re -analysis. The second run has been reported. No other data has changed. Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 2 of 91 SHEALY ENVIRONMENTAL SERVICES, INC. Sample Summary County of Rutherford Lot Number: VA23042 Sample Number Sample ID Matrix Date Sampled Date Received 001 LFG-6 Aqueous 01/22/20201220 01/23/2020 002 LFG-7 Aqueous 01/22/20201120 01/23/2020 003 B-36 Aqueous 01/22/20201203 01/23/2020 004 B-40S Aqueous 01/22/2020 0845 01/23/2020 005 B-40D Aqueous 01/22/2020 0835 01/23/2020 006 B-41 Aqueous 01/22/2020 0910 01/23/2020 007 B-42 Aqueous 01/22/2020 0925 01/23/2020 008 B-44 Aqueous 01/22/20201150 01/23/2020 009 TB Aqueous 01/22/2020 01/23/2020 (9 samples) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 3 of 91 SHEALY ENVIRONMENTAL SERVICES, INC. Detection Summary County of Rutherford Lot Number: VA23042 Sample Sample ID Matrix Parameter Method Result Q Units Page 001 LFG-6 Aqueous Chloride 9056A 2.1 mg/L 7 001 LFG-6 Aqueous TDS SM 2540C- 31 mg/L 7 001 LFG-6 Aqueous Dissolved Barium 6020B 11 ug/L 10 001 LFG-6 Aqueous Dissolved Iron 6020B 14 J ug/L 10 001 LFG-6 Aqueous Aluminum 6020B 41 ug/L 10 001 LFG-6 Aqueous Barium 6020B 11 ug/L 10 001 LFG-6 Aqueous Iron 6020B 43 J ug/L 10 001 LFG-6 Aqueous Manganese 6020B 2.1 J ug/L 10 001 LFG-6 Aqueous Zinc 6020B 2.5 J ug/L 11 002 LFG-7 Aqueous Chloride 9056A 1.9 mg/L 12 002 LFG-7 Aqueous TDS SM 2540C- 47 mg/L 12 002 LFG-7 Aqueous Dissolved Aluminum 6020B 63 ug/L 14 002 LFG-7 Aqueous Dissolved Barium 6020B 2.3 J ug/L 15 002 LFG-7 Aqueous Dissolved Iron 6020B 14 J ug/L 15 002 LFG-7 Aqueous Dissolved Zinc 6020B 3.3 J ug/L 15 002 LFG-7 Aqueous Aluminum 6020B 350 ug/L 15 002 LFG-7 Aqueous Barium 6020B 5.0 ug/L 15 002 LFG-7 Aqueous Chromium 6020B 1.6 J ug/L 15 002 LFG-7 Aqueous Copper 6020B 2.0 J ug/L 15 002 LFG-7 Aqueous Iron 6020B 350 ug/L 15 002 LFG-7 Aqueous Lead 6020B 0.88 J ug/L 15 002 LFG-7 Aqueous Manganese 6020B 6.8 ug/L 15 002 LFG-7 Aqueous Zinc 6020B 6.5 J ug/L 16 003 B-36 Aqueous Chloride 9056A 3.7 mg/L 17 003 B-36 Aqueous TDS SM 2540C- 25 mg/L 17 003 B-36 Aqueous Dissolved Aluminum 6020B 11 J ug/L 19 003 B-36 Aqueous Dissolved Barium 6020B 25 ug/L 20 003 B-36 Aqueous Dissolved Manganese 6020B 5.6 ug/L 20 003 B-36 Aqueous Aluminum 6020B 40 ug/L 20 003 B-36 Aqueous Barium 6020B 25 ug/L 20 003 B-36 Aqueous Iron 6020B 65 ug/L 20 003 B-36 Aqueous Manganese 6020B 6.1 ug/L 20 004 B-40S Aqueous Alkalinity SM 2320B- 30 mg/L 22 004 B-40S Aqueous Chloride 9056A 3.0 mg/L 22 004 B-40S Aqueous Sulfate 9056A 5.8 mg/L 22 004 B-40S Aqueous TDS SM 2540C- 66 mg/L 22 004 B-40S Aqueous Dissolved Barium 6020B 41 ug/L 25 004 B-40S Aqueous Dissolved Iron 6020B 16 J ug/L 25 004 B-40S Aqueous Dissolved Manganese 6020B 46 ug/L 25 004 B-40S Aqueous Aluminum 6020B 80 ug/L 25 004 B-40S Aqueous Barium 6020B 42 ug/L 25 004 B-40S Aqueous Iron 6020B 98 ug/L 25 004 B-40S Aqueous Manganese 6020B 48 ug/L 25 005 B-40D Aqueous Alkalinity SM 232013- 87 mg/L 27 005 B-40D Aqueous Chloride 9056A 2.3 mg/L 27 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 4 of 91 Detection Summary (Continued) Lot Number: VA23042 Sample Sample ID Matrix Parameter Method Result Q Units Page 005 B-40D Aqueous Sulfate 9056A 4.9 005 B-40D Aqueous TDS SM 2540C- 130 005 B-40D Aqueous Dissolved Barium 6020B 11 005 B-40D Aqueous Dissolved Iron 6020B 56 005 B-40D Aqueous Dissolved Manganese 6020B 150 005 B-40D Aqueous Aluminum 6020B 96 005 B-40D Aqueous Barium 6020B 12 005 B-40D Aqueous Iron 6020B 120 005 B-40D Aqueous Manganese 6020B 150 006 B-41 Aqueous Alkalinity SM 232013- 30 006 B-41 Aqueous Chloride 9056A 3.3 006 B-41 Aqueous Sulfate 9056A 13 006 B-41 Aqueous TDS SM 2540C- 76 006 B-41 Aqueous Dissolved Barium 6020B 53 006 B-41 Aqueous Dissolved Iron 6020B 26 006 B-41 Aqueous Dissolved Manganese 6020B 45 006 B-41 Aqueous Aluminum 6020B 25 006 B-41 Aqueous Barium 6020B 54 006 B-41 Aqueous Iron 6020B 48 006 B-41 Aqueous Lead 6020B 1.1 006 B-41 Aqueous Manganese 6020B 46 007 B-42 Aqueous Alkalinity SM 2320B- 84 007 B-42 Aqueous Chloride 9056A 8.3 007 B-42 Aqueous Sulfate 9056A 16 007 B-42 Aqueous TDS SM 2540C- 160 007 B-42 Aqueous Carbon disulfide 8260D 1.0 007 B-42 Aqueous Dissolved Aluminum 6020B 290 007 B-42 Aqueous Dissolved Antimony 6020B 1.8 007 B-42 Aqueous Dissolved Arsenic 6020B 1.4 007 B-42 Aqueous Dissolved Barium 6020B 22 007 B-42 Aqueous Dissolved Iron 6020B 160 007 B-42 Aqueous Dissolved Manganese 6020B 45 007 B-42 Aqueous Dissolved Vanadium 6020B 4.2 007 B-42 Aqueous Aluminum 6020B 2600 007 B-42 Aqueous Antimony 6020B 0.81 007 B-42 Aqueous Arsenic 6020B 1.7 007 B-42 Aqueous Barium 6020B 43 007 B-42 Aqueous Chromium 6020B 2.1 007 B-42 Aqueous Copper 6020B 1.7 007 B-42 Aqueous Iron 6020B 1300 007 B-42 Aqueous Lead 6020B 1.7 007 B-42 Aqueous Manganese 6020B 58 007 B-42 Aqueous Nickel 6020B 2.3 007 B-42 Aqueous Vanadium 6020B 6.3 007 B-42 Aqueous Zinc 6020B 4.2 008 B-44 Aqueous Alkalinity SM 232013- 24 008 B-44 Aqueous Chloride 9056A 2.5 008 B-44 Aqueous TDS SM 2540C- 50 J J J mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L mg/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L mg/L mg/L mg/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L mg/L mg/L mg/L 27 27 30 30 30 30 30 30 30 32 32 32 32 35 35 35 35 35 35 35 35 37 37 37 37 37 39 39 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 40 41 42 42 42 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 5 of 91 Detection Summary (Continued) Lot Number: VA23042 Sample Sample ID Matrix Parameter Method Result Q Units Page 008 B-44 Aqueous Dissolved Antimony 6020B 0.50 J ug/L 44 008 B-44 Aqueous Dissolved Barium 6020B 48 ug/L 45 008 B-44 Aqueous Dissolved Cobalt 6020B 2.8 J ug/L 45 008 B-44 Aqueous Dissolved Manganese 6020B 320 ug/L 45 008 B-44 Aqueous Aluminum 6020B 110 ug/L 45 008 B-44 Aqueous Barium 6020B 50 ug/L 45 008 B-44 Aqueous Cobalt 6020B 3.1 J ug/L 45 008 B-44 Aqueous Iron 6020B 170 ug/L 45 008 B-44 Aqueous Manganese 6020B 310 ug/L 45 (102 detections) Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 6 of 91 Client: County of Rutherford Laboratory ID:VA23042-001 Description: LFG-6 Matrix: Aqueous Date Sampled:01/22/2020 1220 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1711 KFE 43147 1 (Chloride) 9056A 1 01/29/2020 2346 HKL 43548 1 (Sulfate) 9056A 1 01/29/2020 2346 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- ND 20 20 mg/L 1 Chloride 9056A 2.1 1.0 0.20 mg/L 1 Sulfate 9056A ND 1.0 0.20 mg/L 1 TDS SM 2540C- 31 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 1927 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0135 JTH 42874 2 5030B 8260D 1 01/27/2020 2205 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 7 of 91 Client: County of Rutherford Laboratory ID:VA23042-001 Description: LFG-6 Matrix: Aqueous Date Sampled:01/22/2020 1220 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0135 JTH 42874 2 5030B 8260D 1 01/27/2020 2205 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 8 of 91 Client: County of Rutherford Laboratory ID:VA23042-001 Description: LFG-6 Matrix: Aqueous Date Sampled:01/22/2020 1220 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0135 JTH 42874 2 5030B 8260D 1 01/27/2020 2205 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 106 70-130 103 70-130 1,2-Dichloroethane-d4 102 70-130 102 70-130 Toluene-d8 104 70-130 105 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1128 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1131 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1534 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B ND 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 9 of 91 Client: County of Rutherford Laboratory ID:VA23042-001 Description: LFG-6 Matrix: Aqueous Date Sampled:01/22/2020 1220 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1534 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 11 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 14 J 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B ND 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3005A 6020B 1 02/07/2020 1420 BPK 02/06/2020 1710 44149 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 41 40 10 ug/L 2 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 2 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 2 Barium 7440-39-3 6020B 11 5.0 1.3 ug/L 2 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 2 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 2 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 2 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 2 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 2 Iron 7439-89-6 6020B 43 J 50 13 ug/L 2 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 2 Manganese 7439-96-5 6020B 2.1 J 5.0 1.3 ug/L 2 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 2 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 2 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 2 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 2 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 10 of 91 Client: County of Rutherford Laboratory ID:VA23042-001 Description: LFG-6 Matrix: Aqueous Date Sampled:01/22/2020 1220 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 2 3005A 6020B 1 02/07/2020 1420 BPK 02/06/2020 1710 44149 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B 2.5 J 10 2.5 ug/L 2 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 11 of 91 Client: County of Rutherford Laboratory ID:VA23042-002 Description: LFG-7 Matrix: Aqueous Date Sampled:01/22/2020 1120 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1726 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0004 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0004 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- ND 20 20 mg/L 1 Chloride 9056A 1.9 1.0 0.20 mg/L 1 Sulfate 9056A ND 1.0 0.20 mg/L 1 TDS SM 2540C- 47 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 1952 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0159 JTH 42874 2 5030B 8260D 1 01/27/2020 2228 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 12 of 91 Client: County of Rutherford Laboratory ID:VA23042-002 Description: LFG-7 Matrix: Aqueous Date Sampled:01/22/2020 1120 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0159 JTH 42874 2 5030B 8260D 1 01/27/2020 2228 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 13 of 91 Client: County of Rutherford Laboratory ID:VA23042-002 Description: LFG-7 Matrix: Aqueous Date Sampled:01/22/2020 1120 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0159 JTH 42874 2 5030B 8260D 1 01/27/2020 2228 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 101 70-130 104 70-130 1,2-Dichloroethane-d4 98 70-130 105 70-130 Toluene-d8 100 70-130 107 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1133 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1141 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1546 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B 63 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 14 of 91 Client: County of Rutherford Laboratory ID:VA23042-002 Description: LFG-7 Matrix: Aqueous Date Sampled:01/22/2020 1120 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1546 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 2.3 J 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 14 J 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B ND 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B 3.3 J 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1551 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 350 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 5.0 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 1.6 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 2.0 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 350 50 13 ug/L 1 Lead 7439-92-1 6020B 0.88 J 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 6.8 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 15 of 91 Client: County of Rutherford Laboratory ID:VA23042-002 Description: LFG-7 Matrix: Aqueous Date Sampled:01/22/2020 1120 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1551 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B 6.5 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 16 of 91 Client: County of Rutherford Laboratory ID:VA23042-003 Description: B-36 Matrix: Aqueous Date Sampled:01/22/2020 1203 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1731 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0101 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0101 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- ND 20 20 mg/L 1 Chloride 9056A 3.7 1.0 0.20 mg/L 1 Sulfate 9056A ND 1.0 0.20 mg/L 1 TDS SM 2540C- 25 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2016 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 93 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0223 JTH 42874 2 5030B 8260D 1 01/27/2020 2252 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 17 of 91 Client: County of Rutherford Laboratory ID:VA23042-003 Description: B-36 Matrix: Aqueous Date Sampled:01/22/2020 1203 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0223 JTH 42874 2 5030B 8260D 1 01/27/2020 2252 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 18 of 91 Client: County of Rutherford Laboratory ID:VA23042-003 Description: B-36 Matrix: Aqueous Date Sampled:01/22/2020 1203 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0223 JTH 42874 2 5030B 8260D 1 01/27/2020 2252 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 103 70-130 102 70-130 1,2-Dichloroethane-d4 101 70-130 101 70-130 Toluene-d8 103 70-130 104 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1143 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1151 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1557 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B 11 J 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 19 of 91 Client: County of Rutherford Laboratory ID:VA23042-003 Description: B-36 Matrix: Aqueous Date Sampled:01/22/2020 1203 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1557 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 25 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B ND 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 5.6 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1603 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 40 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 25 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 65 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 6.1 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 20 of 91 Client: County of Rutherford Laboratory ID:VA23042-003 Description: B-36 Matrix: Aqueous Date Sampled:01/22/2020 1203 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1603 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 21 of 91 Client: County of Rutherford Laboratory ID:VA23042-004 Description: B-40S Matrix: Aqueous Date Sampled:01/22/2020 0845 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1737 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0120 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0120 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- 30 20 20 mg/L 1 Chloride 9056A 3.0 1.0 0.20 mg/L 1 Sulfate 9056A 5.8 1.0 0.20 mg/L 1 TDS SM 2540C- 66 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2040 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 95 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0247 JTH 42874 2 5030B 8260D 1 01/27/2020 2316 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 22 of 91 Client: County of Rutherford Laboratory ID:VA23042-004 Description: B-40S Matrix: Aqueous Date Sampled:01/22/2020 0845 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0247 JTH 42874 2 5030B 8260D 1 01/27/2020 2316 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 23 of 91 Client: County of Rutherford Laboratory ID:VA23042-004 Description: B-40S Matrix: Aqueous Date Sampled:01/22/2020 0845 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0247 JTH 42874 2 5030B 8260D 1 01/27/2020 2316 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 102 70-130 104 70-130 1,2-Dichloroethane-d4 100 70-130 102 70-130 Toluene-d8 102 70-130 105 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1153 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1156 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1609 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B ND 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 24 of 91 Client: County of Rutherford Laboratory ID:VA23042-004 Description: B-40S Matrix: Aqueous Date Sampled:01/22/2020 0845 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1609 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 41 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 16 J 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 46 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1615 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 80 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 42 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 98 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 48 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 25 of 91 Client: County of Rutherford Laboratory ID:VA23042-004 Description: B-40S Matrix: Aqueous Date Sampled:01/22/2020 0845 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1615 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 26 of 91 Client: County of Rutherford Laboratory ID:VA23042-005 Description: B-40D Matrix: Aqueous Date Sampled:01/22/2020 0835 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1745 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0139 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0139 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- 87 20 20 mg/L 1 Chloride 9056A 2.3 1.0 0.20 mg/L 1 Sulfate 9056A 4.9 1.0 0.20 mg/L 1 TDS SM 2540C- 130 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2105 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0312 JTH 42874 2 5030B 8260D 1 01/27/2020 2340 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 27 of 91 Client: County of Rutherford Laboratory ID:VA23042-005 Description: B-40D Matrix: Aqueous Date Sampled:01/22/2020 0835 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0312 JTH 42874 2 5030B 8260D 1 01/27/2020 2340 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 28 of 91 Client: County of Rutherford Laboratory ID:VA23042-005 Description: B-40D Matrix: Aqueous Date Sampled:01/22/2020 0835 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0312 JTH 42874 2 5030B 8260D 1 01/27/2020 2340 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 103 70-130 102 70-130 1,2-Dichloroethane-d4 100 70-130 103 70-130 Toluene-d8 103 70-130 104 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1158 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1201 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1621 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B ND 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 29 of 91 Client: County of Rutherford Laboratory ID:VA23042-005 Description: B-40D Matrix: Aqueous Date Sampled:01/22/2020 0835 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1621 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 11 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 56 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 150 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1627 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 96 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 12 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 120 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 150 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 30 of 91 Client: County of Rutherford Laboratory ID:VA23042-005 Description: B-40D Matrix: Aqueous Date Sampled:01/22/2020 0835 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1627 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 31 of 91 Client: County of Rutherford Laboratory ID:VA23042-006 Description: B-41 Matrix: Aqueous Date Sampled:01/22/2020 0910 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1752 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0158 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0158 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- 30 20 20 mg/L 1 Chloride 9056A 3.3 1.0 0.20 mg/L 1 Sulfate 9056A 13 1.0 0.20 mg/L 1 TDS SM 2540C- 76 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2129 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 84 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0336 JTH 42874 2 5030B 8260D 1 01/28/2020 0004 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 32 of 91 Client: County of Rutherford Laboratory ID:VA23042-006 Description: B-41 Matrix: Aqueous Date Sampled:01/22/2020 0910 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0336 JTH 42874 2 5030B 8260D 1 01/28/2020 0004 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 33 of 91 Client: County of Rutherford Laboratory ID:VA23042-006 Description: B-41 Matrix: Aqueous Date Sampled:01/22/2020 0910 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0336 JTH 42874 2 5030B 8260D 1 01/28/2020 0004 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 104 70-130 103 70-130 1,2-Dichloroethane-d4 100 70-130 101 70-130 Toluene-d8 102 70-130 104 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1203 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1211 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1644 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B ND 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 34 of 91 Client: County of Rutherford Laboratory ID:VA23042-006 Description: B-41 Matrix: Aqueous Date Sampled:01/22/2020 0910 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1644 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 53 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 26 J 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 45 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1650 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 25 J 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 54 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 48 J 50 13 ug/L 1 Lead 7439-92-1 6020B 1.1 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 46 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 35 of 91 Client: County of Rutherford Laboratory ID:VA23042-006 Description: B-41 Matrix: Aqueous Date Sampled:01/22/2020 0910 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1650 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 36 of 91 Client: County of Rutherford Laboratory ID:VA23042-007 Description: B-42 Matrix: Aqueous Date Sampled:01/22/2020 0925 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1811 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0217 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0217 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- 84 20 20 mg/L 1 Chloride 9056A 8.3 1.0 0.20 mg/L 1 Sulfate 9056A 16 1.0 0.20 mg/L 1 TDS SM 2540C- 160 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2153 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 96 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0400 JTH 42874 2 5030B 8260D 1 01/28/2020 0027 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D 1.0 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 37 of 91 Client: County of Rutherford Laboratory ID:VA23042-007 Description: B-42 Matrix: Aqueous Date Sampled:01/22/2020 0925 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0400 JTH 42874 2 5030B 8260D 1 01/28/2020 0027 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 38 of 91 Client: County of Rutherford Laboratory ID:VA23042-007 Description: B-42 Matrix: Aqueous Date Sampled:01/22/2020 0925 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0400 JTH 42874 2 5030B 8260D 1 01/28/2020 0027 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 104 70-130 104 70-130 1,2-Dichloroethane-d4 100 70-130 102 70-130 Toluene-d8 103 70-130 105 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1214 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1216 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1656 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B 290 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B 1.8 J 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 39 of 91 Client: County of Rutherford Laboratory ID:VA23042-007 Description: B-42 Matrix: Aqueous Date Sampled:01/22/2020 0925 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1656 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B 1.4 J 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 22 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B 160 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 45 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B 4.2 J 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1702 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 2600 40 10 ug/L 1 Antimony 7440-36-0 6020B 0.81 J 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B 1.7 J 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 43 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B 2.1 J 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B ND 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B 1.7 J 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 1300 50 13 ug/L 1 Lead 7439-92-1 6020B 1.7 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 58 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B 2.3 J 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B 6.3 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 40 of 91 Client: County of Rutherford Laboratory ID:VA23042-007 Description: B-42 Matrix: Aqueous Date Sampled:01/22/2020 0925 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1702 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B 4.2 J 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 41 of 91 Client: County of Rutherford Laboratory ID:VA23042-008 Description: B-44 Matrix: Aqueous Date Sampled:01/22/2020 1150 Date Received: 01/23/2020 Inorganic non-metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 (Alkalinity) SM 2320B-2011 1 01/28/2020 1816 KFE 43147 1 (Chloride) 9056A 1 01/30/2020 0314 HKL 43548 1 (Sulfate) 9056A 1 01/30/2020 0314 HKL 43547 1 (TDS) SM 2540C-2011 1 01/23/2020 2354 MOM 42779 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Alkalinity SM 232013- 24 20 20 mg/L 1 Chloride 9056A 2.5 1.0 0.20 mg/L 1 Sulfate 9056A ND 1.0 0.20 mg/L 1 TDS SM 2540C- 50 25 25 mg/L 1 Volatile Organic Compounds by GC/MS (SIM) Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D (SIM) 1 01/23/2020 2218 STM 42777 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run 1,4-Dioxane 123-91-1 8260D (SIM) ND 3.0 1.0 ug/L 1 Run 1 Acceptance Surrogate Q % Recovery Limits 1,2-Dichloroethane-d4 94 40-170 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0424 JTH 42874 2 5030B 8260D 1 01/28/2020 0051 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L 1 Acetonitrile 75-05-8 8260D ND 50 15 ug/L 1 Acrolein 107-02-8 8260D ND 20 4.0 ug/L 1 Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L 1 Benzene 71-43-2 8260D ND 1.0 0.40 ug/L 1 Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L 1 Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L 1 Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L 1 Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 1 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L 1 Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L 1 Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 1 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L 1 Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 42 of 91 Client: County of Rutherford Laboratory ID:VA23042-008 Description: B-44 Matrix: Aqueous Date Sampled:01/22/2020 1150 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0424 JTH 42874 2 5030B 8260D 1 01/28/2020 0051 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1, 1 -Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 43 of 91 Client: County of Rutherford Laboratory ID:VA23042-008 Description: B-44 Matrix: Aqueous Date Sampled:01/22/2020 1150 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/25/2020 0424 JTH 42874 2 5030B 8260D 1 01/28/2020 0051 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 106 70-130 103 70-130 1,2-Dichloroethane-d4 103 70-130 102 70-130 Toluene-d8 105 70-130 105 70-130 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1219 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 CVAA Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 7470A 1 01/28/2020 1221 KSH2 01/27/2020 1455 42828 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Mercury 7439-97-6 7470A ND 0.00020 0.000091 mg/L 1 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1731 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Aluminum 7429-90-5 6020B ND 40 10 ug/L 1 Dissolved Antimony 7440-36-0 6020B 0.50 J 2.0 0.50 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 44 of 91 Client: County of Rutherford Laboratory ID:VA23042-008 Description: B-44 Matrix: Aqueous Date Sampled:01/22/2020 1150 Date Received:01/23/2020 ICP-MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1731 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Dissolved Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Dissolved Barium 7440-39-3 6020B 48 5.0 1.3 ug/L 1 Dissolved Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Dissolved Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Dissolved Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Dissolved Cobalt 7440-48-4 6020B 2.8 J 5.0 1.3 ug/L 1 Dissolved Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Dissolved Iron 7439-89-6 6020B ND 50 13 ug/L 1 Dissolved Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Dissolved Manganese 7439-96-5 6020B 320 5.0 1.3 ug/L 1 Dissolved Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Dissolved Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Dissolved Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Dissolved Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Dissolved Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 Dissolved Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1737 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Aluminum 7429-90-5 6020B 110 40 10 ug/L 1 Antimony 7440-36-0 6020B ND 2.0 0.50 ug/L 1 Arsenic 7440-38-2 6020B ND 2.0 1.3 ug/L 1 Barium 7440-39-3 6020B 50 5.0 1.3 ug/L 1 Beryllium 7440-41-7 6020B ND 0.40 0.15 ug/L 1 Cadmium 7440-43-9 6020B ND 0.50 0.13 ug/L 1 Chromium 7440-47-3 6020B ND 5.0 1.3 ug/L 1 Cobalt 7440-48-4 6020B 3.1 J 5.0 1.3 ug/L 1 Copper 7440-50-8 6020B ND 5.0 1.3 ug/L 1 Iron 7439-89-6 6020B 170 50 13 ug/L 1 Lead 7439-92-1 6020B ND 1.0 0.25 ug/L 1 Manganese 7439-96-5 6020B 310 5.0 1.3 ug/L 1 Nickel 7440-02-0 6020B ND 5.0 1.3 ug/L 1 Selenium 7782-49-2 6020B ND 5.0 1.3 ug/L 1 Silver 7440-22-4 6020B ND 1.0 0.25 ug/L 1 Thallium 7440-28-0 6020B ND 0.50 0.15 ug/L 1 Vanadium 7440-62-2 6020B ND 5.0 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 45 of 91 Client: County of Rutherford Laboratory ID:VA23042-008 Description: B-44 Matrix: Aqueous Date Sampled:01/22/2020 1150 Date Received:01/23/2020 ICP-MS Metals Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 3005A 6020B 1 01/27/2020 1737 BNW 01/24/2020 1024 42803 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Zinc 7440-66-6 6020B ND 10 2.5 ug/L 1 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 46 of 91 Client: County of Rutherford Laboratory ID:VA23042-009 Description: TB Matrix: Aqueous Date Sampled:01/22/2020 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/24/2020 2311 JTH 42874 2 5030B 8260D 1 01/28/2020 0114 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Acetone 67-64-1 8260D ND 20 5.0 ug/L Acetonitrile 75-05-8 8260D ND 50 15 ug/L Acrolein 107-02-8 8260D ND 20 4.0 ug/L Acrylonitrile 107-13-1 8260D ND 20 0.80 ug/L Benzene 71-43-2 8260D ND 1.0 0.40 ug/L Bromochloromethane 74-97-5 8260D ND 1.0 0.40 ug/L Bromodichloromethane 75-27-4 8260D ND 1.0 0.40 ug/L Bromoform 75-25-2 8260D ND 1.0 0.40 ug/L Bromomethane (Methyl bromide) 74-83-9 8260D ND 2.0 0.40 ug/L 2-Butanone (MEK) 78-93-3 8260D ND 10 2.0 ug/L Carbon disulfide 75-15-0 8260D ND 1.0 0.40 ug/L Carbon tetrachloride 56-23-5 8260D ND 1.0 0.40 ug/L 2-Chloro-1,3-Butadiene (Chloroprene) 126-99-8 8260D ND 5.0 1.0 ug/L Chlorobenzene 108-90-7 8260D ND 1.0 0.40 ug/L Chloroethane 75-00-3 8260D ND 2.0 0.40 ug/L Chloroform 67-66-3 8260D ND 1.0 0.40 ug/L Chloromethane (Methyl chloride) 74-87-3 8260D ND 1.0 0.50 ug/L 3-Chloropropene (Allyl chloride) 107-05-1 8260D ND 5.0 1.0 ug/L 1,2-Dibromo-3-chloropropane (DBCP) 96-12-8 8260D ND 1.0 0.40 ug/L Dibromochloromethane 124-48-1 8260D ND 1.0 0.40 ug/L 1,2-Dibromoethane (EDB) 106-93-4 8260D ND 1.0 0.40 ug/L Dibromomethane (Methylene bromide) 74-95-3 8260D ND 1.0 0.40 ug/L trans- 1,4-Dichloro-2-butene 110-57-6 8260D ND 2.0 0.50 ug/L 1,2-Dichlorobenzene 95-50-1 8260D ND 1.0 0.40 ug/L 1,3-Dichlorobenzene 541-73-1 8260D ND 1.0 0.40 ug/L 1,4-Dichlorobenzene 106-46-7 8260D ND 1.0 0.40 ug/L Dichlorodifluoromethane 75-71-8 8260D ND 2.0 0.60 ug/L 1,1-Dichloroethane 75-34-3 8260D ND 1.0 0.40 ug/L 1,2-Dichloroethane 107-06-2 8260D ND 1.0 0.40 ug/L 1,1-Dichloroethene 75-35-4 8260D ND 1.0 0.40 ug/L cis- 1,2-Dichloroethene 156-59-2 8260D ND 1.0 0.40 ug/L trans- 1,2-Dichloroethene 156-60-5 8260D ND 1.0 0.40 ug/L 1,2-Dichloropropane 78-87-5 8260D ND 1.0 0.40 ug/L 1,3-Dichloropropane 142-28-9 8260D ND 1.0 0.40 ug/L 2,2-Dichloropropane 594-20-7 8260D ND 1.0 0.40 ug/L 1,1-Dichloropropene 563-58-6 8260D ND 2.0 0.40 ug/L cis- 1,3-Dichloropropene 10061-01-5 8260D ND 1.0 0.40 ug/L trans- 1,3-Dichloropropene 10061-02-6 8260D ND 1.0 0.40 ug/L Ethyl methacrylate 97-63-2 8260D ND 5.0 0.40 ug/L LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 47 of 91 Client: County of Rutherford Laboratory ID:VA23042-009 Description: TB Matrix: Aqueous Date Sampled:01/22/2020 Date Received:01/23/2020 Volatile Organic Compounds by GC/MS Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch 1 5030B 8260D 1 01/24/2020 2311 JTH 42874 2 5030B 8260D 1 01/28/2020 0114 JTH 43038 CAS Analytical Parameter Number Method Result Q LOQ DL Units Run Ethylbenzene 100-41-4 8260D ND 1.0 0.40 ug/L 1 2-Hexanone 591-78-6 8260D ND 10 2.0 ug/L 1 Isobutyl alcohol 78-83-1 8260D ND 50 12 ug/L 1 Methacrylonitrile 126-98-7 8260D ND 5.0 2.0 ug/L 1 Methyl iodide (lodomethane) 74-88-4 8260D ND 5.0 0.40 ug/L 1 Methyl methacrylate 80-62-6 8260D ND 5.0 0.40 ug/L 1 4-Methyl-2-pentanone 108-10-1 8260D ND 10 2.0 ug/L 1 Methylene chloride 75-09-2 8260D ND 1.0 0.40 ug/L 1 Propionitrile (Ethyl cyanide) 107-12-0 8260D ND 20 4.0 ug/L 1 Styrene 100-42-5 8260D ND 1.0 0.41 ug/L 1 1,1,1,2-Tetrachloroethane 630-20-6 8260D ND 1.0 0.40 ug/L 1 1,1,2,2-Tetrachloroethane 79-34-5 8260D ND 1.0 0.40 ug/L 1 Tetrachloroethene 127-18-4 8260D ND 1.0 0.40 ug/L 1 Tetrahydrofuran 109-99-9 8260D ND 5.0 1.0 ug/L 1 Toluene 108-88-3 8260D ND 1.0 0.40 ug/L 1 1,1,1-Trichloroethane 71-55-6 8260D ND 1.0 0.40 ug/L 1 1,1,2-Trichloroethane 79-00-5 8260D ND 1.0 0.40 ug/L 1 Trichloroethene 79-01-6 8260D ND 1.0 0.40 ug/L 1 Trichlorofluoromethane 75-69-4 8260D ND 1.0 0.40 ug/L 1 1,2,3-Trichloropropane 96-18-4 8260D ND 1.0 0.40 ug/L 1 Vinyl acetate 108-05-4 8260D ND 5.0 1.2 ug/L 1 Vinyl chloride 75-01-4 8260D ND 1.0 0.40 ug/L 1 Xylenes (total) 1330-20-7 8260D ND 1.0 0.40 ug/L 1 Run 1 Acceptance Run 2 Acceptance Surrogate Q % Recovery Limits Q % Recovery Limits Bromofluorobenzene 102 70-130 103 70-130 1,2-Dichloroethane-d4 98 70-130 102 70-130 Toluene-d8 102 70-130 105 70-130 LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit NO = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL H = Out of holding time W = Reported on wet weight basis Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 48 of 91 QC Summary Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 49 of 91 Inorganic non-metals - MB Sample ID: VQ42779-001 Matrix: Aqueous Batch: 42779 Analytical Method: SM 2540C-2011 Parameter Result Q Dil LOQ DL Units Analysis Date TDS ND 1 25 25 mg/L 01/23/2020 2354 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 50 of 91 Inorganic non-metals - LCS Sample ID: VQ42779-002 Matrix: Aqueous Batch: 42779 Analytical Method: SM 2540C-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date TDS 1500 1500 1 100 90-110 01/23/2020 2354 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 51 of 91 Inorganic non-metals - MB Sample ID: VQ43147-001 Matrix: Aqueous Batch: 43147 Analytical Method: SM 2320B-2011 Parameter Result Q Dil LOQ DL Units Analysis Date Alkalinity ND 1 20 20 mg/L 01/28/20201640 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 52 of 91 Inorganic non-metals - LCS Sample ID: VQ43147-002 Matrix: Aqueous Batch: 43147 Analytical Method: SM 2320B-2011 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Alkalinity 100 94 1 94 90-110 01/28/20201657 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 53 of 91 Inorganic non-metals - Duplicate Sample ID: VA23042-001 DU Matrix: Aqueous Batch: 43147 Analytical Method: SM 2320B-2011 Sample Amount Result % RPD Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date Alkalinity ND ND 1 0.00 20 01/28/20201719 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 54 of 91 Inorganic non-metals - MB Sample ID: VQ43547-001 Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Sulfate ND 1 1.0 0.20 mg/L 01/29/2020 2308 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 55 of 91 Inorganic non-metals - LCS Sample ID: VQ43547-002 Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate 20 19 1 96 80-120 01/29/2020 2327 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 56 of 91 Inorganic non-metals - MS Sample ID: VA23042-002MS Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate ND 20 19 1 97 80-120 01/30/2020 0023 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 57 of 91 Inorganic non-metals - MSD Sample ID: VA23042-002MD Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate ND 20 19 1 95 2.6 80-120 20 01/30/2020 0042 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 58 of 91 Inorganic non-metals - MS Sample ID: VA23042-008MS Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Sulfate ND 20 19 1 95 80-120 01/30/2020 0332 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 59 of 91 Inorganic non-metals - MSD Sample ID: VA23042-008MD Matrix: Aqueous Batch: 43547 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Sulfate ND 20 18 1 92 3.8 80-120 20 01/30/2020 0351 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 60 of 91 Inorganic non-metals - MB Sample ID: VQ43548-001 Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Parameter Result Q Dil LOQ DL Units Analysis Date Chloride ND 1 1.0 0.20 mg/L 01/29/2020 2308 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 61 of 91 Inorganic non-metals - LCS Sample ID: VQ43548-002 Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 20 24 1 119 80-120 01/29/2020 2327 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 62 of 91 Inorganic non-metals - MS Sample ID: VA23042-002MS Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 1.9 20 22 1 101 80-120 01/30/2020 0023 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 63 of 91 Inorganic non-metals - MSD Sample ID: VA23042-002MD Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 1.9 20 21 1 98 2.8 80-120 20 01/30/2020 0042 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 64 of 91 Inorganic non-metals - MS Sample ID: VA23042-008MS Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Chloride 2.5 20 22 1 98 80-120 01/30/2020 0332 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 65 of 91 Inorganic non-metals - MSD Sample ID: VA23042-008MD Matrix: Aqueous Batch: 43548 Analytical Method: 9056A Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Chloride 2.5 20 22 1 95 2.8 80-120 20 01/30/2020 0351 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 66 of 91 Volatile Organic Compounds by GC/MS (SIM) - MB Sample ID: VQ42777-001 Matrix: Aqueous Batch:42777 Prep Method: 5030E Analytical Method: 8260D (SIM) Parameter Result Q Dil LOQ DL Units Analysis Date 1,4-Dioxane ND 1 3.0 1.0 ug/L 01/23/20201844 Acceptance Surrogate Q % Rec Limit 1,2-Dichloroethane-d4 96 40-170 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 67 of 91 Volatile Organic Compounds by GC/MS (SIM) - LCS Sample ID: VQ42777-002 Matrix: Aqueous Batch:42777 Prep Method: 5030E Analytical Method: 8260D (SIM) Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 1,4-Dioxane 50 48 1 96 70-130 01/23/20201708 Surrogate Q % Rec Acceptance Limit 1,2-Dichloroethane-d4 99 40-170 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 68 of 91 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ42874-001 Matrix: Aqueous Batch:42874 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date Acetone ND 1 20 5.0 ug/L 01/24/2020 2202 Acetonitrile ND 1 50 15 ug/L 01/24/2020 2202 Acrolein ND 1 20 4.0 ug/L 01/24/2020 2202 Acrylonitrile ND 1 20 0.80 ug/L 01/24/2020 2202 Benzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Bromochloromethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 Bromodichloromethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 Bromoform ND 1 1.0 0.40 ug/L 01/24/2020 2202 Bromomethane (Methyl bromide) ND 1 2.0 0.40 ug/L 01/24/2020 2202 2-Butanone (MEK) ND 1 10 2.0 ug/L 01/24/2020 2202 Carbon disulfide ND 1 1.0 0.40 ug/L 01/24/2020 2202 Carbon tetrachloride ND 1 1.0 0.40 ug/L 01/24/2020 2202 2-Chloro-1,3-Butadiene (Chloroprene) ND 1 5.0 1.0 ug/L 01/24/2020 2202 Chlorobenzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Chloroethane ND 1 2.0 0.40 ug/L 01/24/2020 2202 Chloroform ND 1 1.0 0.40 ug/L 01/24/2020 2202 Chloromethane (Methyl chloride) ND 1 1.0 0.50 ug/L 01/24/2020 2202 3-Chloropropene (Allyl chloride) ND 1 5.0 1.0 ug/L 01/24/2020 2202 1,2-Dibromo-3-chloropropane (DBCP) ND 1 1.0 0.40 ug/L 01/24/2020 2202 Dibromochloromethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,2-Dibromoethane (EDB) ND 1 1.0 0.40 ug/L 01/24/2020 2202 Dibromomethane (Methylene bromide) ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,2-Dichlorobenzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,3-Dichlorobenzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,4-Dichlorobenzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Dichlorodifluoromethane ND 1 2.0 0.60 ug/L 01/24/2020 2202 1,1-Dichloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,2-Dichloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,1-Dichloroethene ND 1 1.0 0.40 ug/L 01/24/2020 2202 cis- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 01/24/2020 2202 trans- 1,2-Dichloroethene ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,2-Dichloropropane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,3-Dichloropropane ND 1 1.0 0.40 ug/L 01/24/2020 2202 2,2-Dichloropropane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,1-Dichloropropene ND 1 2.0 0.40 ug/L 01/24/2020 2202 cis- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 01/24/2020 2202 trans- 1,3-Dichloropropene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Ethyl methacrylate ND 1 5.0 0.40 ug/L 01/24/2020 2202 Ethylbenzene ND 1 1.0 0.40 ug/L 01/24/2020 2202 2-Hexanone ND 1 10 2.0 ug/L 01/24/2020 2202 Isobutyl alcohol ND 1 50 12 ug/L 01/24/2020 2202 Methacrylonitrile ND 1 5.0 2.0 ug/L 01/24/2020 2202 Methyl iodide (lodomethane) ND 1 5.0 0.40 ug/L 01/24/2020 2202 Methyl methacrylate ND 1 5.0 0.40 ug/L 01/24/2020 2202 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 69 of 91 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ42874-001 Matrix: Aqueous Batch:42874 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date 4-Methyl-2-pentanone ND 1 10 2.0 ug/L 01/24/2020 2202 Methylene chloride ND 1 1.0 0.40 ug/L 01/24/2020 2202 Propionitrile (Ethyl cyanide) ND 1 20 4.0 ug/L 01/24/2020 2202 Styrene ND 1 1.0 0.41 ug/L 01/24/2020 2202 1,1,1,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,1,2,2-Tetrachloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 Tetrachloroethene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Tetrahydrofuran ND 1 5.0 1.0 ug/L 01/24/2020 2202 Toluene ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,1,1-Trichloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,1,2-Trichloroethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 Trichloroethene ND 1 1.0 0.40 ug/L 01/24/2020 2202 Trichlorofluoromethane ND 1 1.0 0.40 ug/L 01/24/2020 2202 1,2,3-Trichloropropane ND 1 1.0 0.40 ug/L 01/24/2020 2202 Vinyl acetate ND 1 5.0 1.2 ug/L 01/24/2020 2202 Vinyl chloride ND 1 1.0 0.40 ug/L 01/24/2020 2202 Xylenes (total) ND 1 1.0 0.40 ug/L 01/24/2020 2202 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 107 70-130 1,2-Dichloroethane-d4 104 70-130 Toluene-d8 106 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 70 of 91 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ42874-002 Matrix: Aqueous Batch:42874 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Acetone 100 97 1 97 60-140 01/24/2020 2033 Acetonitrile 500 450 1 90 60-140 01/24/2020 2033 Acrolein 500 590 1 119 60-140 01/24/2020 2033 Acrylonitrile 100 100 1 101 70-130 01/24/2020 2033 Benzene 50 49 1 97 70-130 01/24/2020 2033 Bromochloromethane 50 46 1 92 70-130 01/24/2020 2033 Bromodichloromethane 50 46 1 92 70-130 01/24/2020 2033 Bromoform 50 44 1 89 70-130 01/24/2020 2033 Bromomethane (Methyl bromide) 50 45 1 91 70-130 01/24/2020 2033 2-Butanone (MEK) 100 110 1 105 70-130 01/24/2020 2033 Carbon disulfide 50 40 1 80 70-130 01/24/2020 2033 Carbon tetrachloride 50 43 1 86 70-130 01/24/2020 2033 2-Chloro-1,3-Butadiene (Chloroprene) 50 48 1 96 70-130 01/24/2020 2033 Chlorobenzene 50 47 1 94 70-130 01/24/2020 2033 Chloroethane 50 49 1 97 70-130 01/24/2020 2033 Chloroform 50 47 1 94 70-130 01/24/2020 2033 Chloromethane (Methyl chloride) 50 51 1 101 60-140 01/24/2020 2033 3-Chloropropene (Allyl chloride) 50 49 1 98 70-130 01/24/2020 2033 1,2-Dibromo-3-chloropropane (DBCP) 50 46 1 93 70-130 01/24/2020 2033 Dibromochloromethane 50 45 1 90 70-130 01/24/2020 2033 1,2-Dibromoethane (EDB) 50 47 1 94 70-130 01/24/2020 2033 Dibromomethane (Methylene bromide) 50 46 1 92 70-130 01/24/2020 2033 1,2-Dichlorobenzene 50 49 1 97 70-130 01/24/2020 2033 1,3-Dichlorobenzene 50 48 1 95 70-130 01/24/2020 2033 1,4-Dichlorobenzene 50 47 1 94 70-130 01/24/2020 2033 Dichlorodifluoromethane 50 50 1 101 60-140 01/24/2020 2033 1,1-Dichloroethane 50 49 1 97 70-130 01/24/2020 2033 1,2-Dichloroethane 50 46 1 92 70-130 01/24/2020 2033 1,1-Dichloroethene 50 43 1 87 70-130 01/24/2020 2033 cis- 1,2-Dichloroethene 50 48 1 97 70-130 01/24/2020 2033 trans- 1,2-Dichloroethene 50 48 1 96 70-130 01/24/2020 2033 1,2-Dichloropropane 50 50 1 100 70-130 01/24/2020 2033 1,3-Dichloropropane 50 47 1 94 70-130 01/24/2020 2033 2,2-Dichloropropane 50 41 1 82 70-130 01/24/2020 2033 1,1-Dichloropropene 50 48 1 95 70-130 01/24/2020 2033 cis- 1,3-Dichloropropene 50 49 1 98 70-130 01/24/2020 2033 trans- 1,3-Dichloropropene 50 46 1 92 70-130 01/24/2020 2033 Ethyl methacrylate 50 51 1 102 70-130 01/24/2020 2033 Ethylbenzene 50 49 1 97 70-130 01/24/2020 2033 2-Hexanone 100 100 1 101 70-130 01/24/2020 2033 Isobutyl alcohol 500 490 1 98 60-140 01/24/2020 2033 Methacrylonitrile 250 250 1 101 70-130 01/24/2020 2033 Methyl iodide (lodomethane) 50 42 1 84 70-130 01/24/2020 2033 Methyl methacrylate 50 49 1 99 70-130 01/24/2020 2033 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 71 of 91 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ42874-002 Matrix: Aqueous Batch:42874 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date 4-Methyl-2-pentanone 100 100 1 103 70-130 01/24/2020 2033 Methylene chloride 50 44 1 88 70-130 01/24/2020 2033 Propionitrile (Ethyl cyanide) 500 520 1 105 70-130 01/24/2020 2033 Styrene 50 50 1 100 70-130 01/24/2020 2033 1,1,1,2-Tetrachloroethane 50 47 1 94 70-130 01/24/2020 2033 1,1,2,2-Tetrachloroethane 50 50 1 100 70-130 01/24/2020 2033 Tetrachloroethene 50 45 1 90 70-130 01/24/2020 2033 Tetrahydrofuran 50 46 1 92 70-130 01/24/2020 2033 Toluene 50 47 1 94 70-130 01/24/2020 2033 1,1,1-Trichloroethane 50 44 1 88 70-130 01/24/2020 2033 1,1,2-Trichloroethane 50 47 1 93 70-130 01/24/2020 2033 Trichloroethene 50 47 1 94 70-130 01/24/2020 2033 Trichlorofluoromethane 50 46 1 92 70-130 01/24/2020 2033 1,2,3-Trichloropropane 50 47 1 94 70-130 01/24/2020 2033 Vinyl acetate 50 51 1 103 60-140 01/24/2020 2033 Vinyl chloride 50 51 1 102 70-130 01/24/2020 2033 Xylenes (total) 100 96 1 96 70-130 01/24/2020 2033 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 92 70-130 1,2-Dichloroethane-d4 92 70-130 Toluene-d8 94 70-130 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 72 of 91 Volatile Organic Compounds by GC/MS - MB Sample ID: VQ43038-001 Matrix: Aqueous Batch:43038 Prep Method: 5030E Analytical Method: 8260D Parameter Result Q Dil LOQ DL Units Analysis Date trans- 1,4-Dichloro-2-butene ND 1 2.0 0.50 ug/L 01/27/2020 2124 Acceptance Surrogate Q % Rec Limit Bromofluorobenzene 103 70-130 1,2-Dichloroethane-d4 102 70-130 Toluene-d8 104 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 73 of 91 Volatile Organic Compounds by GC/MS - LCS Sample ID: VQ43038-002 Matrix: Aqueous Batch:43038 Prep Method: 5030E Analytical Method: 8260D Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date trans- 1,4-Dichloro-2-butene 50 50 1 100 70-130 01/27/2020 2002 Surrogate Q % Rec Acceptance Limit Bromofluorobenzene 93 70-130 1,2-Dichloroethane-d4 96 70-130 Toluene-d8 98 70-130 LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria LOD = Limit of Detection ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 74 of 91 ICP-MS - MB Sample ID: VQ42803-001 Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Parameter Result Q Dil LOQ DL Units Analysis Date Dissolved Aluminum ND 1 40 10 ug/L 01/27/2020 1238 Dissolved Antimony ND 1 2.0 0.50 ug/L 01/27/2020 1238 Dissolved Arsenic ND 1 2.0 1.3 ug/L 01/27/2020 1238 Dissolved Barium ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Beryllium ND 1 0.40 0.15 ug/L 01/27/2020 1238 Dissolved Cadmium ND 1 0.50 0.13 ug/L 01/27/2020 1238 Dissolved Chromium ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Cobalt ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Copper ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Iron ND 1 50 13 ug/L 01/27/2020 1238 Dissolved Lead ND 1 1.0 0.25 ug/L 01/27/2020 1238 Dissolved Manganese ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Nickel ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Selenium ND 1 5.0 1.3 ug/L 01/27/2020 1238 Dissolved Silver ND 1 1.0 0.25 ug/L 01/27/2020 1238 Dissolved Thallium ND 1 0.50 0.15 ug/L 01/27/2020 1238 Dissolved Vanadium ND 1 5.0 2.5 ug/L 01/27/2020 1238 Dissolved Zinc ND 1 10 2.5 ug/L 01/27/2020 1238 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 75 of 91 ICP-MS - LCS Sample ID: VQ42803-002 Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Dissolved Aluminum 100 97 1 97 80-120 01/27/2020 1244 Dissolved Antimony 100 97 1 97 80-120 01/27/2020 1244 Dissolved Arsenic 100 100 1 102 80-120 01/27/2020 1244 Dissolved Barium 100 99 1 99 80-120 01/27/2020 1244 Dissolved Beryllium 100 96 1 96 80-120 01/27/2020 1244 Dissolved Cadmium 100 96 1 96 80-120 01/27/2020 1244 Dissolved Chromium 100 94 1 94 80-120 01/27/2020 1244 Dissolved Cobalt 100 94 1 94 80-120 01/27/2020 1244 Dissolved Copper 100 94 1 94 80-120 01/27/2020 1244 Dissolved Iron 1000 980 1 98 80-120 01/27/2020 1244 Dissolved Lead 100 98 1 98 80-120 01/27/2020 1244 Dissolved Manganese 100 99 1 99 80-120 01/27/2020 1244 Dissolved Nickel 100 97 1 97 80-120 01/27/2020 1244 Dissolved Selenium 100 98 1 98 80-120 01/27/2020 1244 Dissolved Silver 100 99 1 99 80-120 01/27/2020 1244 Dissolved Thallium 100 98 1 98 80-120 01/27/2020 1244 Dissolved Vanadium 100 93 1 93 80-120 01/27/2020 1244 Dissolved Zinc 100 96 1 96 80-120 01/27/2020 1244 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 76 of 91 ICP-MS Metals - MB Sample ID: VQ42803-001 Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 40 10 ug/L 01/27/20201238 Antimony ND 1 2.0 0.50 ug/L 01/27/20201238 Arsenic ND 1 2.0 1.3 ug/L 01/27/20201238 Barium ND 1 5.0 1.3 ug/L 01/27/20201238 Beryllium ND 1 0.40 0.15 ug/L 01/27/20201238 Cadmium ND 1 0.50 0.13 ug/L 01/27/20201238 Chromium ND 1 5.0 1.3 ug/L 01/27/20201238 Cobalt ND 1 5.0 1.3 ug/L 01/27/20201238 Copper ND 1 5.0 1.3 ug/L 01/27/20201238 Iron ND 1 50 13 ug/L 01/27/20201238 Lead ND 1 1.0 0.25 ug/L 01/27/20201238 Manganese ND 1 5.0 1.3 ug/L 01/27/20201238 Nickel ND 1 5.0 1.3 ug/L 01/27/20201238 Selenium ND 1 5.0 1.3 ug/L 01/27/20201238 Silver ND 1 1.0 0.25 ug/L 01/27/20201238 Thallium ND 1 0.50 0.15 ug/L 01/27/20201238 Vanadium ND 1 5.0 2.5 ug/L 01/27/20201238 Zinc ND 1 10 2.5 ug/L 01/27/20201238 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 77 of 91 ICP-MS Metals - LCS Sample ID: VQ42803-002 Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum 100 97 1 97 80-120 01/27/20201244 Antimony 100 97 1 97 80-120 01/27/20201244 Arsenic 100 100 1 102 80-120 01/27/20201244 Barium 100 99 1 99 80-120 01/27/20201244 Beryllium 100 96 1 96 80-120 01/27/20201244 Cadmium 100 96 1 96 80-120 01/27/20201244 Chromium 100 94 1 94 80-120 01/27/20201244 Cobalt 100 94 1 94 80-120 01/27/20201244 Copper 100 94 1 94 80-120 01/27/20201244 Iron 1000 980 1 98 80-120 01/27/20201244 Lead 100 98 1 98 80-120 01/27/20201244 Manganese 100 99 1 99 80-120 01/27/20201244 Nickel 100 97 1 97 80-120 01/27/20201244 Selenium 100 98 1 98 80-120 01/27/20201244 Silver 100 99 1 99 80-120 01/27/20201244 Thallium 100 98 1 98 80-120 01/27/20201244 Vanadium 100 93 1 93 80-120 01/27/20201244 Zinc 100 96 1 96 80-120 01/27/20201244 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 78 of 91 ICP-MS Metals - MS Sample ID: VA23042-007MS Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Sample Spike Amount Amount Result % Rec Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum 2600 100 7000 N 1 4380 70-130 01/27/20201708 Antimony 0.81 100 94 1 93 70-130 01/27/20201708 Arsenic 1.7 100 100 1 98 70-130 01/27/20201708 Barium 43 100 150 1 105 70-130 01/27/20201708 Beryllium ND 100 97 1 97 70-130 01/27/20201708 Cadmium ND 100 97 1 97 70-130 01/27/20201708 Chromium 2.1 100 95 1 93 70-130 01/27/20201708 Cobalt ND 100 92 1 92 70-130 01/27/20201708 Copper 1.7 100 94 1 92 70-130 01/27/20201708 Iron 1300 1000 3100 N 1 181 70-130 01/27/20201708 Lead 1.7 100 96 1 94 70-130 01/27/20201708 Manganese 58 100 160 1 99 70-130 01/27/20201708 Nickel 2.3 100 95 1 93 70-130 01/27/20201708 Selenium ND 100 96 1 96 70-130 01/27/20201708 Silver ND 100 96 1 96 70-130 01/27/20201708 Thallium ND 100 95 1 95 70-130 01/27/20201708 Vanadium 6.3 100 98 1 92 70-130 01/27/20201708 Zinc 4.2 100 100 1 97 70-130 01/27/20201708 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 79 of 91 ICP-MS Metals - MSD Sample ID: VA23042-007MD Matrix: Aqueous Batch:42803 Prep Method: 3005A Analytical Method: 6020B Prep Date: 01/24/2020 1024 Sample Spike Amount Amount Result % Rec % RPD Parameter (ug/L) (ug/L) (ug/L) Q Dil % Rec % RPD Limit Limit Analysis Date Aluminum 2600 100 7600 N 1 4960 8.0 70-130 20 01/27/20201713 Antimony 0.81 100 95 1 94 1.1 70-130 20 01/27/20201713 Arsenic 1.7 100 100 1 103 4.3 70-130 20 01/27/20201713 Barium 43 100 150 1 109 2.3 70-130 20 01/27/20201713 Beryllium ND 100 99 1 99 1.7 70-130 20 01/27/20201713 Cadmium ND 100 98 1 98 1.3 70-130 20 01/27/20201713 Chromium 2.1 100 95 1 93 0.38 70-130 20 01/27/20201713 Cobalt ND 100 94 1 94 2.0 70-130 20 01/27/20201713 Copper 1.7 100 96 1 95 2.6 70-130 20 01/27/20201713 Iron 1300 1000 3300 N 1 196 4.7 70-130 20 01/27/20201713 Lead 1.7 100 97 1 96 1.4 70-130 20 01 /27/2020 1713 Manganese 58 100 160 1 103 2.0 70-130 20 01/27/20201713 Nickel 2.3 100 97 1 95 2.4 70-130 20 01/27/20201713 Selenium ND 100 98 1 98 1.6 70-130 20 01/27/20201713 Silver ND 100 97 1 97 1.3 70-130 20 01/27/20201713 Thallium ND 100 95 1 95 0.41 70-130 20 01/27/20201713 Vanadium 6.3 100 99 1 93 1.4 70-130 20 01/27/20201713 Zinc 4.2 100 100 1 98 0.99 70-130 20 01/27/20201713 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 80 of 91 ICP-MS Metals - MB Sample ID: VQ44149-001 Matrix: Aqueous Batch:44149 Prep Method: 3005A Analytical Method: 6020B Prep Date: 02/06/2020 1710 Parameter Result Q Dil LOQ DL Units Analysis Date Aluminum ND 1 40 10 ug/L 02/07/20201343 Antimony ND 1 2.0 0.50 ug/L 02/07/20201343 Arsenic ND 1 2.0 1.3 ug/L 02/07/20201343 Barium ND 1 5.0 1.3 ug/L 02/07/20201343 Beryllium ND 1 0.40 0.15 ug/L 02/07/20201343 Cadmium ND 1 0.50 0.13 ug/L 02/07/20201343 Chromium ND 1 5.0 1.3 ug/L 02/07/20201343 Cobalt ND 1 5.0 1.3 ug/L 02/07/20201343 Copper ND 1 5.0 1.3 ug/L 02/07/20201343 Iron ND 1 50 13 ug/L 02/07/20201343 Lead ND 1 1.0 0.25 ug/L 02/07/20201343 Manganese ND 1 5.0 1.3 ug/L 02/07/20201343 Nickel ND 1 5.0 1.3 ug/L 02/07/20201343 Selenium ND 1 5.0 1.3 ug/L 02/07/20201343 Silver ND 1 1.0 0.25 ug/L 02/07/20201343 Thallium ND 1 0.50 0.15 ug/L 02/07/20201343 Vanadium ND 1 5.0 2.5 ug/L 02/07/20201343 Zinc ND 1 10 2.5 ug/L 02/07/20201343 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 81 of 91 ICP-MS Metals - LCS Sample ID: VQ44149-002 Matrix: Aqueous Batch:44149 Prep Method: 3005A Analytical Method: 6020B Prep Date: 02/06/2020 1710 Spike Amount Result % Rec Parameter (ug/L) (ug/L) Q Dil % Rec Limit Analysis Date Aluminum 100 100 1 100 80-120 02/07/20201350 Antimony 100 97 1 97 80-120 02/07/20201350 Arsenic 100 100 1 102 80-120 02/07/20201350 Barium 100 97 1 97 80-120 02/07/20201350 Beryllium 100 100 1 102 80-120 02/07/20201350 Cadmium 100 100 1 100 80-120 02/07/20201350 Chromium 100 93 1 93 80-120 02/07/20201350 Cobalt 100 96 1 96 80-120 02/07/20201350 Copper 100 98 1 98 80-120 02/07/20201350 Iron 1000 930 1 93 80-120 02/07/20201350 Lead 100 100 1 103 80-120 02/07/20201350 Manganese 100 95 1 95 80-120 02/07/20201350 Nickel 100 97 1 97 80-120 02/07/20201350 Selenium 100 98 1 98 80-120 02/07/20201350 Silver 100 100 1 102 80-120 02/07/20201350 Thallium 100 100 1 101 80-120 02/07/20201350 Vanadium 100 96 1 96 80-120 02/07/20201350 Zinc 100 100 1 103 80-120 02/07/20201350 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 82 of 91 CVAA -MB Sample ID: VQ42828-001 Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Parameter Result Q Dil LOQ DL Units Analysis Date Mercury ND 1 0.00020 0.000091 mg/L 01/28/20201115 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 83 of 91 CVAA - LCS Sample ID: VQ42828-002 Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury 0.0020 0.0021 1 106 80-120 01/28/20201118 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 84 of 91 CVAA - MS Sample ID: VA23042-003MS Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Sample Spike Amount Amount Result % Rec Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Mercury ND 0.0020 0.0021 1 103 85-115 01/28/20201146 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 85 of 91 CVAA - MSD Sample ID: VA23042-003MD Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Sample Spike Amount Amount Result % Rec % RPD Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date Mercury ND 0.0020 0.0021 1 103 0.20 85-115 20 01/28/20201148 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 86 of 91 CVAA -MB Sample ID: VQ42828-001 Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Parameter Result Q Dil LOQ DL Units Analysis Date Dissolved Mercury ND 1 0.00020 0.000091 mg/L 01/28/2020 1115 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 87 of 91 CVAA - LCS Sample ID: VQ42828-002 Matrix: Aqueous Batch:42828 Prep Method: Analytical Method: 7470A Prep Date: 01/27/2020 1455 Spike Amount Result % Rec Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date Dissolved Mercury 0.0020 0.0021 1 106 80-120 01/28/2020 1118 LOQ = Limit of Quantitation DL = Detection Limit LOD = Limit of Detection P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria J = Estimated result < LOQ and > DL + = RPD is out of criteria ND = Not detected at or above the DL Note: Calculations are performed before rounding to avoid round -off errors in calculated results Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 88 of 91 Chain of Custody and Miscellaneous Documents Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 89 of 91 SHEALY ENVIRONMENTAL SERVICES, INC. CD z z Ik Y w �Z L Z I lul . 0� z� W J PE e o w r C 4 RIK � 1 iV$R �n ANa�hky ; ur �mc �2, 0 M Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 90 of 91 SHEALY ENVIRONMENTAL SERVICES, INC. Flh-ly BnvIkftm tibl Scr4pcc, lea Dacualen -ir'nbcrMGCQI*U]-J Ciicnra SLF. M14aos AL cc 2.9 1, %VCM PgEe t of 1 Sample Receipt Check]6t (SR.C) `f&ai+ L3AIMBIZL2ala Ooolef Ios acd hoyedatA- [ifiC r 01.2�1I2020 J_at A, - Vr923042 on the a MCA.; r=1 d 1Vy V. ti 2. If gLsWy SeIls ucm pnse1jr, were die intact =d unbmltL:1t? 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Yee ❑ 1�, aid &Lll coutLiinLr labs] infnruLatiulp ), date, tirft) ageec with tf e CDC? No 11. VVerc tmt to he perfom ed listed on the CCC? Yen El -No 12, Did al I &%upleS arrive in the proper cantitiuers tier cacti tesi 41ndiclr in good coltdi Lion funhrokcn. link e,n, elta-)? No Yes 0 Yesi 0 No I 0 I3- V'as ad-gmtc samp]n volme a -.-a ilable" 14. Were alI samples nOXived within YL Lhe hoId%o.9 timc or 49 hours, whiehr,,c,•cwM fi,,0 15, Were atty sampiesl r2ntailliM r;tissi ] =MB irc3C pus.) Sa1n lu Na[ lis;wd on Co c: 16- For VOA and ASK-175 5attlt}leN wl}re bullbles present"pea-ciTr" (l "or fimro in dinmeG Nh in arty 0f Lfte V<)A VjaLL*' NA 17, -W= all DR(1mmaL3ill utrimIt lcs receivrrl at a tEI vr < 2'i NA 11 1 151- & IX -ere atl cvawde Rem ley L,ec6ivcrl at a pH > 12 and r[u]ftde sam lcs rECnivorl at a pH? -_- - ❑'feAf ❑ N01 DATA -- m Q Yes O N o 10 — A 2 0. Wcrc Qlicni rcrnarksVrequ= (i.e. rcgLLe6Led dill.l.dWS, t4-ISiN D dcsi,gna6rm�. ,m. --`I I I oorreitl+j iran,9rTikCl fC0111 the COC into d4Sxr1u=Llt Wticu in IjMg? Ycs ON0121. Vas Lb ate numhcr iisied on [l1e raklLtaincrr 1qb 12 Tf tote # NA . Impk Jlt-eservatiox Uylu5t be cnmpicted for any samp]c(s) iur,)rr:eGtly prmmed o,- with headspaco.) arnplc, .&) NA P erk rccm%r dl inoon-Oc[1y Pro%nred mid lhcm a*sted aawrslmgly 1 salmpie rcC+aiviilg wiUi mI of circle ane. li'2SO4, IJNW, HCI, Na0h using SR,4 NA irne of prescnpa i�A NA _. 'If more fl1m one pry 8 iive is necidcd, pl Lase i10te in Lk cormxmts below. =Tle(s) NA werc rc -eived wide bubbles - 6 ruin in diamutcr. arnplvs(s) A]A were rccsived wttJ] TRC 0.5 tup,7, (If n19 is t+a) and aria ijuritod aCcurc[illgly itx sautple reGGraing 4vith 90diurn thiasulfatn (h'a,S,C,) �sitb Shealy IC}; -NA 'SR lxdr:3ade- iahe-13 applio3 by: JSH COMMMI Z EXCESS: TB par,; OU23j2020 Shealy Environmental Services, Inc. 106 Vantage Point Drive West Columbia, SC 29172 (803) 791-9700 Fax (803) 791-9111 www.shealylab.com Page 91 of 91 APPENDIX C FIGURE 2 AND TABLES FROM THE MAY 2018 SEMI-ANNUAL SAMPLING REPORT BY SCARLETT GEOPHYSICAL CONSULTING P.C. 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'`tb ` + J / T t . •t r t Y I.tft. a • � \ r ` i ' / �."'r" . i/I/ ` �i�'� i �� � .�../ .,r.t►.Y+ .1/"�iP',Y•'1'�V1161\ rl1( ,i;;: -v'� '� yes •� � �� � s. t i � � � �� J',I+ff"di►•.,,'tYlrr��; a•r�fi:+ / +b �% � + .p'� • l qt! J) l'4 .,,,,r-�!,.,"'•�..�� k � � f • � •+t "Y+Y�'iY1♦ �.,t r r wt i � ,(w V4 op � +I , tt � �� 1 r/ !�• � � � � t� � . i tii V~��w/ lrl� Ty/ f ���1���r vJ V Y�. LEGEND: .� i r v` �' r,a �. MON�'MRING WELL, FROMltrflt+L�'a r1 '► f nc \,. f j 1 ; % '' ''�y \ ` t 7 � ttf ! Ji /' � • A � If �, � � t ! � 1. � `i f � � �� � 4~` � � � SURFACE WATER SAMPLE LOCATION A. DAVED GARRETT & ASSOCIATES GROUNDWATER Mid ITORiNG i ,+ t_.%;' �..-- w...... p ..,,; `�.� Y GROUNDWATER CONTOUR GROUNDWATER 924 WITH PHASE I CDLF AMENDMENTS \,,•I♦.,r. _..`�, �"• ,� /ir' / �..-�. ` . -. � f 1 �. •___'' ✓'1 ?�. �, •, GRUUT`tDWArtER FLOW DIRECnON ..�. , f• ,� NNA -�. SHEET 20., DRAWING NO. "i �----•-- t-.��.� `-`..,�' �.- � �`- �. �BU AIR L= ,.+''^`� ) •�7 �... r ~ � r` ..-"`' * 'ire1 200" TABLE 1 SUMMARY OF MONITORING WELL DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA Well No. Elevation (ft) Depth of Well (ft) Static Water Levels3 Sep 19-Sep 22, 2016 May 3-9, 2017 Oct 2-5, 2017 May 10-17, 2018 Land Surface Top of Casing' Top of Screen Bottom of Screen Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) 8103-MW-2 995.43 995.51 945.43 935.43 60.0 41.82 953.69 46.25 949.26 47.27 948.24 46.89 948.62 8103-MW-3 859.62 860.28 822.62 812.62 47.0 34.35 825.93 33.89 826.39 1 34.61 825.67 32.09 828.19 8103-MW-4 849.72 851.03 809.72 799.72 50.0 36.22 814.81 36.06 814.97 36.48 814.55 31.91 819.12 8103-MW-6 833.43 834.90 810.93 795.93 37.5 31.14 803.76 31.88 803.02 32.33 802.57 31.36 803.54 8103-MW-7 890.51 892.70 851.51 836.51 54.0 36.57 856.13 37.82 854.88 37.33 855.37 34.93 857.77 8103-MW-8 857.86 860.31 828.36 813.36 44.5 42.54 817.77 43.49 816.82 44.26 816.05 39.89 820.42 8103-MW-9 864.97 867.25 842.47 827.47 37.5 33.44 833.81 34.00 833.25 35.65 831.60 34.02 833.23 8103-MW-10A 834.73 837.23 743.73 733.73 101.0 6.135 831.10' 4.505 832.73' 5.665 831.57' 6.475 830.76' 8103-MW-10B 834.50 836.15 802.50 797.50 37.0 9.93 826.22 8.92 827.23 10.01 826.14 9.11 827.04 8103-MW-10C 834.50 836.19 823.50 818.50 16.0 9.72 826.47 8.65 827.54 9.78 826.41 8.88 827.31 8103-MW-10D 834.73 837.23 778.73 768.73 66.0 10.99 826.24 9.88 827.35 11.16 826.07 9.96 827.27 8103-MW-11A 815.39 817.18 780.39 770.39 45.0 9.26 807.92 8.62 808.56 9.22 807.96 8.26 808.92 8103-MW-11B 816.32 817.72 806.32 796.32 20.0 10.44 807.28 9.65 808.07 10.31 807.41 9.45 808.27 8103-MW-12 884.33 886.68 849.33 834.33 50.0 46.26 840.42 33.10 853.58 38.90 847.78 32.27 854.41 8103-MW-13 960.80 962.90 887.80 872.80 88.0 77.75 885.15 82.05 880.85 82.50 880.40 81.21 881.69 8103-MW-14 867.08 869.48 849.68 834.68 32.4 23.54 845.94 23.51 845.97 24.80 844.68 20.67 848.81 8103-MW-15 887.58 889.54 1 839.58 849.58 1 38.0 35.04 854.50 31.41 858.13 35.38 854.16 29.10 860.44 Notes Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC, December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering and Geology, Raleigh, NC, 2002 and 1999, respectively 2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C. 3 Water levels taken from top of casing 4 Depth of well measured from land surface 5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day) RuthCent_0518.xis TABLE 2 GROUND AND SURFACE WATER SAMPLING FIELD DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17. 2018 Parameter Sample Location 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10A 8103-MW-10B Temperature 16.86°C 16.2°C 15.64°C 20.26°C 16.4°C 18.01°C 15.83°C NS 15.9°C Conductivity 100 pmhos/cm 956 pmhos/cm 726 pmhos/cm 2080 pmhos/cm 950 pmhos/cm 622 pmhos/cm 35.0 pmhos/cm NS 97.4 pmhos/cm pH 8.84 6.56 5.85 6.44 6.65 6.06 5.47 NS 6.38 ORP 83 mV NA 25 mV -54 mV NA 124 mV 157 mV NS NA DO 4.52 mg/I NA 0.00 mg/I 1.44 mg/I NA 2.00 mg/I 3.68 mg/I NS NA Turbidity 78.1 NTU NA 15.4 NTU 10.7 NTU NA 1.5 NTU 2.3 NTU NS NA Parameter Sample Location 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 Temperature 15.2°C 15.30°C 15.13°C 14.6°C 17.9°C 17.7°C 17.1 °C 16.4°C 17.6°C Conductivity 101.9 pmhos/cm 336 pmhos/cm 855 pmhos/cm 186.5 mhos/cm 823 pmhos/cm 190.5 pmhos/cm 210.0 pmhos/cm 220.0 pmhos/cm 102.9 pmhos/cm pH 6.37 5.95 5.60 5.96 6.63 5.75 5.92 5.97 7.26 ORP NA 61 mV -74 mV NA NA NA NA NA NA DO NA 0.00 mg/I 0.00 mg/I NA NA NA NA NA NA Turbidity NA 0.1 NTU 5.4 NTU NA NA NA NA NA NA Parameter Sample Location 8103-SW-3 8103-SW-4 8103-SW-5A Temperature 20.3°C 18.7°C 17.7°C Conductivity 65.6 pmhos/cm 53.4 pmhos/cm 63.1 pmhos/cm pH 7.37 7.29 6.93 ORP NA NA NA DO NA NA NA Turbidity NA NA NA NS - Not sampled NA - Not analyzed RuthCent_0518.x1s TABLE 3 GROUNDWATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 C CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Well Number 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B ANTIMONY BQL BQL BQL BQL BQL BQL BQL BQL 1.0 6.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 10.0 BARIUM 31.8 J 161.0 178.0 379.0 148.0 206.0 49.7 J 46.8 J 700.0 100 BERYLLIUM BQL BQL BQL BQL BQL BQL BQL BQL * 4.0 1.0 CADMIUM BQL 0.36 J 0.7 J 0.5 J 0.2 J BQL BQL BQL 2.0 1.0 CHROMIUM 22.2 3.0 J 4.6 J 3.6 J 18.7 1.7 J 2.7 J 2.7 J 10.0 10.0 COBALT BQL 0.7 J 1.2 J `62:5 5.3 J' BQL BQL BQL 1.0 10.0 COPPER 8.2 J 7.0 J 15.8 9.2 J 10.6 5.1 J 3.9 J 4.5 J 1,000.0 10.0 LEAD BQL BQL BQL BQL BQL BQL BQL BQL 15.0 10.0 NICKEL 1.5 J 1.1 J 1.3 J 19.0 J 8.6 J 0.8 J BQL BQL 100.0 50.0 SELENIUM BQL BQL BQL BQL BQL BQL BQL BQL 20.0 10.0 SILVER BQL 3.8 J 1.6 J 2.6 J 1.8 J BQL 1.7 J BQL 20.0 10.0 THALLIUM BQL BQL BQL 184 BQL BQL BQL BQL 0.28 5.5 VANADIUM 5.3J = 1.8J= 15.4J = 2.2J 124.4J 1.0J BQL 0.81 = 0.3 25.0 ZINC 248.0 248.0 69.1 170.0 301.0 143.0 156.0 191.0 1,000.0 10.0 Parameter Well Number 15A NCAC 2L Standard for Class GAGroundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 ANTIMONY BQL BQL BQL BQL BQL BQL BQL BQL 1.0 6.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 10.0 BARIUM 767.0 189.0 166.0 415.0 178.0 159.0 1,130.0 680.0 700.0 100 BERYLLIUM 1.9 BQL BQL 2.0 J BQL BQL 3.2 2.1 4.0 1.0 CADMIUM BQL BQL BQL BQL 0.3 J BQL BQL BQL 2.0 1.0 CHROMIUM 65.1 BQL 0.9 J -46.4 2.1 J 1.8 J 156.0 „ - 53.9 10.0 10.0 COBALT 36.5 ,. 27.8 , 11.5 ,20J 6.8 J. 3.04 .34.6. 29.4 1.0 10.0 COPPER 47.4 5.2 J 4.6 J 27.0 10.0 6.1 J 71.9 63.9 1,000.0 10.0 LEAD 18.3 BQL BQL 15.1 BQL BQL 16.3 30.4 15.0 10.0 NICKEL 39.6 J 4.4 J 4.0 J 28.8 1.8 J 3.2 J 33.5 J 30.6 J 100.0 50.0 SELENIUM BQL BQL BQL BQL BQL BQL BQL BQL 20.0 10.0 SILVER BQL 1.4 J 3.6 J BQL 1.8 J BQL BQL BQL 20.0 10.0 THALLIUM BQL BQL 4.6 J BQL 7.8 BQL BQL BQL 0.28 5.5 VANADIUM 1 129.0 1 BQL 1 1.2 J 1 89.3 3.4 J 2.4 J 146.0 108.0 0.3 25.0 ZINC 1 305.0 1 230.0 1 26.0 1 227.0 1 284.0 1 263.0 1 302.0 1 272.0 1 1,000.0 1 10.0 Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit J - Estimated results. Present but below SWSL NS - Not Sampled * - Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCent_0518.xis TABLE 4 GROUNDWATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection Solid Waste Section Limit 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GA Groundwater Standard (SWSL) 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL BQL BQL BQL BQL 1.0 5.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL BQL BQL BQL BQL 200.0 1.0 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL BQL BQL BQL BQL 0.2 0.18 3.0 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL BQL BQL BQL BQL 0.6 1.0 1,1-DICHLOROETHANE BQL BQL BQL BQL 0.91 BQL BQL BQL BQL 1.51 BQL BQL BQL BQL BQL BQL 6.0 5.0 1,1-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2J BQL BQL BQL BQL BQL BQL 7.0 5.0 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 1.0 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL BQL BQL I BQL BQL BQL BQL BQL BQL I BQL BQL I BQL BQL 0.04 13.0 1,2-DIBROMOETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 1.0 1,2-DICHLOROBENZENE BQL BQL BQL 0.51 BQL BQL BQL BQL BQL BQL 0.11 BQL BQL BQL BQL BQL 20.0 5.0 1,2-DICHLOROETHANE BQL BQL BQL BQL BQL BQL 0.11 BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 1.0 1,2-DICHLOROPROPANE BQL BQL BQL BQL BQL BQL 25:3 BQL BQL 0.1 J BQL BQL BQL BQL BQL BQL 0.6 1.0 1,4-DICHLOROBENZENE BQL BQL 1.4 7.9 BQL 0.11 BQL BQL BQL 22 3.1 BQL BQL BQL BQL BQL 6.0 1.0 2-BUTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4,000.0 100.0 2-HEXANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 40.0 50.0 4-METHYL-2-PENTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 560.0 100.0 ACETONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 7.1J BQL BQL 6000.0 100.0 ACRYLONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL ' 200.0 BENZENE BQL BQL BQL 1.4 BQL BQL BQL BQL BQL 1.2 0.2 J BQL 0.2 J 0.6 J BQL BQL 1.0 1.0 BROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' 0.6 3.0 BROMODICHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 1.0 BROMOFORM BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 3.0 BROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.0 10.0 CARBON DISULFIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 700.0 100.0 CARBON TETRACHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 1.0 CHLOROBENZENE BQL BQL 1.3J 453 0.2J SOL BQL I BQL BQL 2.0J 5.5 BQL BQL 0.11 BQL BQL 50.0 3.0 CHLOROETHANE BQL BQL 0.2 J BQL BQL BQL BQL BQL BQL 0.4 J 0.5 J BQL BQL 0.61 BQL BQL 3,000.0 10.0 CHLOROFORM BQL BQL BQL BQL BQL BQL 0.3J BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 5.0 CHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 1.0 CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL 0.2 J BQL 10.1 0.11 BQL BQL 0.6 J 0.3 J BQL 70.0 5.0 CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 1.0 DIBROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.41 3.0 DIBROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 10.0 ETHYLBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 1.0 METHYL IODIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.0 METHYLENE CHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 5.0 1.0 STYRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 1.0 TETRACHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.2 BQL BQL BQL BQL BQL BQL 0.7 1.0 TOLUENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 1.0 TOTAL XYLENES BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.51 BQL BQL 500.0 5.0 TRANS-I,2-DICHLOROETIENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 5.0 TRANS-I,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 1.0 TRANS-I,4-DICHLORO-2-BUTENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 TRICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 12 BQL BQL BQL BQL BQL BQL 3.0 1.0 TRICHLOROFLUOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2J BQL 2,000.0 1.0 VINYL ACETATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 88.0 50.0 VINYL CHLORIDE BQL BQL SOL 0.4 J SOL BQL BQL BQL BQL 0.3 J 0.4 J BQL BQL 0.2 J BQL BQL 0.03 1.0 All results in parts per billion (ppb) BQL - Below Method Detection Limit J - Estimated result. Present but below SWSL B - Lab blank contamination NS - Not Sampled Standard not established • Shaded -11' cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • For constituents that are not naturally occurring and have no established standards, the SW SLs are the Standards RuthCent_0518.As TABLE 5 GROUNDWATER SAMPLING RESULTS APPENDIX II TRIGGERED CONSTITUENTS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter SW-846 Method Well Number 15A NCAC 2L Standard for Class GAGroundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 1,3-Dichlorobenzene 8260 BQL 0.6 J BQL BQL BQL BQL BQL BQL 0.2 J BQL 200.0 5.0 1,3-Dichloropropane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 1.0 Dichlorodifluoromethane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1,000.0 5.0 4,4'- DDD 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 * 0.1 4,4'- DDT 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 * 0.1 alpha-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.006 0.05 beta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 0.05 delta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 0.05 Endrin 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.0 0.1 gamma-BHC (Lindane) 1 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.03 * 0.05 Mercury 1 7470 0.72 0.11 J 0.05 J 0.06 J 0.05 J 0.02 J 0.06 J 0.09 J 0.03 J 0.06 J 1.0 0.2 Notes: All results in parts per billion (ppb) • BQL - Below Method Detection Limit J - Estimated result. Present but below SWSL • * - Standard not established Shaded, cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards NA - Not analyzed RuthCent_0518.xis TABLE 6 GROUNDWATER SAMPLING RESULTS APPENDIX II INORGANIC CONSTITUENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Laboratory Method 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 ANTIMONY SW 846 6010 BQL BQL BQL BQL BQL 1.0 6.0 ARSENIC SW 846 6010 BQL BQL BQL BQL BQL 10.0 10.0 BARIUM SW 846 6010 178.0 379.0 148.0 206.0 49.7 J 700.0 100.0 BERYLLIUM SW 846 6010 BQL BQL BQL BQL BQL 4.0 1.0 CADMIUM SW 846 6010 0.7 J 0.5 J 0.2 J BQL BQL 2.0 1.0 CHROMIUM SW 846 6010 4.6 J 3.6 J 18.7 1.7 J 2.7 J 10.0 10.0 COBALT SW 846 6010 1.2 J 62.5 5.3 J BQL BQL 1.0 10.0 COPPER SW 846 6010 15.8 9.2 J 10.6 5.1 J 3.9 J 1,000.0 10.0 CYANIDE EPA 335.2 BQL BQL BQL BQL BQL 70.0 10.0 LEAD SW 846 6010 4.3 J BQL BQL BQL BQL 15.0 10.0 MERCURY SW 846 7470 0.72 0.11 J 0.05 J 0.06 J 0.05 J 1.0 0.2 NICKEL SW 846 6010 1.3 J 19.0 J 8.6 J 0.8 J BQL 100.0 50.0 SELENIUM SW 846 6010 BQL 6.8 J BQL BQL BQL 20.0 10.0 SILVER SW 846 6010 1.6 J 2.6 J 1.8 J BQL 1.7 J 20.0 10.0 SULFIDE EPA 376.1 BQL BQL BQL BQL BQL 1,000.0 THALLIUM SW 846 6010 BQL 18.4 BQL BQL BQL 0.28 5.5 TIN SW 846 6010 BQL BQL BQL BQL BQL 2,000.0 100.0 VANADIUM SW 846 6010 15.4 J 2.2 J 24.4 J 1.0 J BQL 0.3 25.0 ZINC SW 846 6010 69.1 BQL 301.0 143.0 156.0 1,000.0 10.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • * - Standard not established • Shaded cells denote concentrations that equal or exceed the 2L or Groundwater Protection Standards • INS - Not Sampled RuthCent_0518.xis TABLE 7 GROUNDWATER SAMPLING RESULTS APPENDIX II VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17. 2018 Parameters Sample Locations 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL 1.0 5.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL BQL 200.0 * 1.0 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL 0.2 0.18 3.0 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL BQL 0.6 1.0 1,1-DICHLOROETHANE BQL BQL 0.9 J BQL BQL 6.0 5.0 1,1-DICHLOROETHENE BQL BQL BQL BQL BQL 7.0 * 5.0 1,1-DICHLOROPROPENE BQL BQL BQL BQL BQL 5.0 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL BQL 0.005 * 1.0 1,2,4-TRICHLOROBENZENE' BQL BQL BQL BQL BQL 70.0 70.0 10 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL BQL 0.04 * 13.0 1,2-DIBROMOETHANE BQL BQL BQL BQL BQL 0.02 1.0 1,2-DICHLOROBENZENE BQL 0.5 J BQL BQL BQL 20.0 * 5.0 1,2-DICHLOROETHANE BQL BQL BQL BQL 0.1 J 0.4 1.0 1,2-DICHLOROPROPANE BQL BQL BQL BQL 25.3 0.6 * 1.0 1,3-DICHLOROBENZENE BQL 0.6 J BQL BQL BQL 200.0 5.0 1,3-DICHLOROPROPANE BQL BQL BQL BQL BQL * 1.0 1,4-DICHLOROBENZENE 1.4 7.9 . BQL 0.1 J BQL 6.0 1.0 2,2-DICHLOROPROPANE BQL BQL BQL BQL BQL * 15.0 2-BUTANONE BQL BQL BQL BQL BQL 4,000.0 100.0 2-HEXANONE BQL BQL BQL BQL BQL 40.0 50.0 4-METHYL-2-PENTANONE BQL BQL BQL BQL BQL 560.0 100.0 ACETONE BQL BQL BQL BQL BQL 6,000.0 * 100.0 ACETONITRILE BQL BQL BQL BQL BQL 42.0 55.0 ACROLEIN BQL BQL BQL BQL BQL * 4.0 53.0 ACRYLONITRILE BQL BQL BQL BQL BQL 200.0 ALLYL CHLORIDE 3-chloro ro ene BQL BQL BQL BQL BQL * 10.0 BENZENE BQL 1.4 ' BQL BQL BQL 1.0 1.0 BROMOCHLOROMETHANE BQL BQL BQL BQL BQL 0.6 3.0 BROMODICHLOROMETHANE BQL BQL BQL BQL BQL 0.6 1.0 BROMOFORM BQL BQL BQL BQL BQL 4.0 * 3.0 BROMOMETHANE BQL BQL BQL BQL BQL 10.0 10.0 CARBON DISULFIDE BQL BQL BQL BQL BQL 700.0 * 100.0 CARBON TETRACHLORIDE BQL BQL BQL BQL BQL 0.3 1.0 CHLOROBENZENE 1.3 J 45.3 0.2 J BQL BQL 50.0 * 3.0 CHLOROETHANE 0.2 J BQL BQL BQL BQL 3,000.0 * 10.0 CHLOROFORM BQL BQL BQL BQL 0.3 J 70.0 * 5.0 CHLOROMETHANE BQL BQL BQL BQL BQL 3.0 1.0 CHLOROPRENE BQL BQL BQL BQL BOIL * * 20.0 CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL BQL 70.0 5.0 CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL BQL 0.4 * 1.0 DIBROMOCHLOROMETHANE BQL BQL BQL BQL BQL 0.4 0.41 3.0 DIBROMOMETHANE BQL BQL BQL BQL BQL 70.0 10.0 DICHLORODIFLOUROMETHANE BQL BQL BQL BQL BQL 1,000.0 5.0 ETHYL BENZENE BQL BQL BQL BQL BQL 600.0 * 1.0 ETHYL METHACRYLATE BQL BQL BQL BQL BQL 10.0 ISOBUTYL ALCOHOL BQL BQL BQL BQL BQL * 100.0 METHACRYLONITRILE BQL BQL BQL BQL BQL 100.0 METHYL IODIDE BQL BQL BQL BQL BQL * 10.0 METHYL METHACRYLATE BQL BQL BQL BQL BQL 25.0 30.0 METHYLENE CHLORIDE BQL BQL BQL BQL BQL 5.0 * 1.0 PROPIONITRILE BQL BQL BQL BQL BQL 150.0 STYRENE BQL BQL BQL BQL BQL 70.0 * 1.0 TETRACHLOROETHENE BQL BQL BQL BQL BQL 0.7 1.0 TOLUENE BQL BQL BQL BQL BQL 600.0 * 1.0 TOTAL XYLENES BQL BQL BQL BQL BQL 500.0 * 5.0 TRANS-1,2-DICHLOROETHENE BQL BQL BQL BQL BQL 100.0 * 5.0 TRANS-I,3-DICHLOROPROPENE BQL BQL BQL BQL BQL 0.4 1.0 TRANS-1,4-DICHLORO-2-BUTENE BQL BQL BQL BQL BQL * 100.0 TRICHLOROETHENE BQL BQL BQL BQL BQL 3.0 1.0 TRICHLOROFLUOROMETHANE BQL BQL BQL BQL BQL 2,000.0 * 1.0 VINYL ACETATE BQL BQL BQL BQL BQL 88.0 50.0 VINYL CHLORIDE BQL 0.4 J BQL BQL BQL 0.03 * 1.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below reporting limit. • * - Standard not established • Shaded cells ' denote concentrations that equal or exceed 21 or Groundwater Protection Standards • For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards • ' Analyzed by SW-846 Method 8270 • NS - Not Sampled RuthCent_0518.xls TABLE 8 GROUNDWATER SAMPLING RESULTS APPENDIX II SEMI -VOLATILE CONSTITUENTS BY SW-846 METHOD 8270 CENTRAL SANITARY LANDFILL (# 81-03), RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 0,0,0-TRIETHYL PHOSPHOROTHIOATE BQL BQL BQL BQL BQL 10.0 0,0-DIETHYL o-2-PYROZINYL BQL BQL BQL BQL BQL 20.0 1,2,4,5-TETRACHLOROBENZENE BQL BQL BQL BQL BQL 2.0 10.0 1,2,4-TRICHLOROBENZENE BQL BQL BQL BQL BQL 70.0 70.0 10.0 1,4-NAPHTHOQUINONE BQL BQL BQL BQL BQL * 10.0 1-NAPHTHYLAMINE BQL BQL BQL BQL BQL 10.0 2,3,4,6-TETRACHLOROPHENOL BQL BQL BQL BQL BQL 200.0 10.0 2,4,5-TRICHLOROPHENOL BQL BQL BQL BQL BQL * 63.0 10.0 2,4,6-TRICHLOROPHENOL BQL BQL BQL BQL BQL * 4.0 10.0 2,4-DICHLOROPHENOL BQL BQL BQL BQL BQL 0.98 10.0 2,4-DIMETHYLPHENOL BQL BQL BQL BQL BQL 100.0 10.0 2,4-DINITROPHENOL BQL BQL BQL BQL BQL * 50.0 2,4-DINITROTOLUENE BQL BQL BQL BQL BQL * 0.1 10.0 2,6-DICHLOROPHENOL BQL BQL BQL BQL BQL 10.0 2,6-DINITROTOLUENE BQL BQL BQL BQL BQL 10.0 2-ACETYLAMINOFLUORENE BQL BQL BQL BQL BQL 20.0 2-CHLORONAPHTHALENE BQL BQL BQL BQL BQL 10.0 2-CHLOROPHENOL BQL BQL BQL BQL BQL 0.4 10.0 2-METHYLNAPHTHALENE BQL BQL BQL BQL BQL 30.0 10.0 2-METHYLPHENOL (O-CRESOL) BQL BQL BQL BQL BQL 400.0 10.0 2-NAPHTHYLAMINE BQL BQL BQL BQL BQL 10.0 2-NITROANILINE BQL BQL BQL BQL BQL 50.0 2-NITROPHENOL BQL BQL BQL BQL BQL 10.0 3 & 4-METHYLPHENOL M & P-CRESOL BQL BQL BQL BQL BQL 400/40 10.0 3,3'-DICHLOROBENZIDINE BQL BQL BQL BQL BQL 20.0 3,3'-DIMETHYLBENZIDINE BQL BQL BQL BQL BQL 10.0 3-METHYLCHOLANTHRENE BQL BQL BQL BQL BQL 10.0 3-NITROANILINE BQL BQL BQL BQL BQL 50.0 4,6-DINITRO-o-CREOSOL BQL BQL BQL BQL BQL 50.0 4-AMINOBIPHENYL BQL BQL BQL BQL BQL * 20.0 4-BROMOPHENYL PHENYL ETHER BQL BQL BQL BQL BQL 10.0 4-CHLORO-3-METHYLPHENOL BQL BQL BQL BQL BQL * 20.0 4-CHLOROANILINE BQL BQL BQL BQL BQL * 20.0 4-CHLOROPHENYL PHENYL ETHER BQL BQL BQL BQL BQL * " 10.0 4-NITROANILINE BQL BQL BQL BQL BQL * 20.0 4-NITROPHENOL BQL BQL BQL BQL BQL * 50.0 5-NITRO-0-TOLUIDINE BQL BQL BQL BQL BQL 10.0 7,12-DIMETHYLBENZAANTHRACENE BQL BQL BQL BQL BQL 10.0 ACENAPHTHENE BQL 3.4 J BQL BQL BQL 80.0 10.0 ACENAPHTHYLENE BQL BQL BQL BQL BQL 200.0 10.0 ACETOPHENONE BQL BQL BQL BQL BQL 700.0 10.0 ANTHRACENE BQL BQL BQL BQL BQL 2,000.0 10.0 BENZO A ANTHRACENE BQL BQL BQL BQL BQL 0.05 10.0 BENZO A PYRENE BQL BQL BQL BQL BQL 0.005 10.0 BENZO B FLUORANTHENE BQL BQL BQL BQL BQL 0.05 10.0 BENZO G,H,I PERYLENE BQL BQL BQL BQL BQL 200.0 10.0 BENZO K FLUORANTHENE BQL BQL BQL BQL BQL 0.5 10.0 BENZYL ALCOHOL BQL BQL BQL BQL BQL * 700.0 20.0 BIS(2-CHLORO-1-METHYLETHYL)ETHERZ BQL BQL BQL BQL BQL 10.0 BIS 2-CHLOROETHOXY METHANE BQL BQL BQL BQL BQL 10.0 BIS 2-CHLOROETHYL ETHER BQL BQL BQL BQL BQL 0.031 10.0 BIS 2-ETHYLHEXYL PHTHALATE BQL BQL BQL BQL 1.8 J 3.0 * 15.0 BUTYL BENZYL PHTHALATE' BQL BQL BQL BQL BQL 1,000.0 10.0 CHLOROBENZILATE BQL BQL BQL BQL BQL 10.0 CHRYSENE BQL BQL BQL BQL BQL 5.0 10.0 DIALLATE (TOTAL) BQL BQL BQL BQL BQL 10.0 RuthCent_0518.xls TABLE 8 (CONT.) Parameter 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 DIBENZ A,H ANTHRACENE BQL BQL BQL BQL BQL 0.005 10.0 DIBENZOFURAN BQL BQL BQL BQL BQL 28.0 10.0 DIETHYL PHTHALATE BQL BQL BQL BQL BQL 6,000.0 6,000.0 DIMETHYL PHTHALATE BQL BQL BQL BQL BQL 10.0 DI-N-BUTYLPHTHALATE BQL BQL BQL BQL BQL 700.0 10.0 DI-N-OCTYLPHTHALATE BQL BQL BQL BQL BQL 100.0 10.0 DIPHENYLAMINE BQL BQL BQL BQL BQL 10.0 ETHYL METHANESULFONATE BQL BQL BQL BQL BQL 20.0 FLUORANTHENE BQL BQL BQL BQL BQL 300.0 10.0 FLUORENE BQL BQL BQL BQL BQL 300.0 10.0 HEXACHLOROBENZENE BQL BQL BQL BQL BQL 0.02 10.0 HEXACHLOROBUTADIENE BQL BQL BQL BQL BQL 0.4 0.44 10.0 HEXACHLOROCYCLOPENTADIENE BQL BQL BQL BQL BQL 50.0 10.0 HEXACHLOROETHANE BQL BQL BQL BQL BQL 2.5 10.0 HEXACHLOROPROPENE BQL BQL BQL BQL BQL 10.0 INDENO 1,2,3-CD PYRENE BQL BQL BQL BQL BQL 0.05 10.0 ISODRIN BQL BQL BQL BQL BQL 20.0 ISOPHORONE BQL BQL BQL BQL BQL 40.0 10.0 ISOSAFROLE BQL BQL BQL BQL BQL 10.0 m-DINITROBENZENE4 BQL BQL BQL BQL BQL 20.0 METHAPYRILENE BQL BQL BQL BQL BQL 100.0 METHYL METHANESULFONATE BQL BQL BQL BQL BQL 10.0 N-NITROSODIETHYLAMINE BQL BQL BQL BQL BQL 20.0 N-NITROSODIMETHYLAMINE BQL BQL BQL BQL BQL 0.0007 10.0 N-NITROSODI-N-BUTYLAMINE BQL BQL BQL BQL BQL 10.0 N-NITROSODI-N-PROPYLAMINE BQL BQL BQL BQL BQL 10.0 N-NITROSODIPHENYLAMINE BQL BQL BQL BQL BQL 10.0 N-NITROSOMETHYLETHYLAMINE BQL BQL BQL BQL BQL 10.0 N-NITROSOPIPERIDINE BQL BQL BQL BQL BQL 20.0 N-NITROSOPYRROLI DINE BQL BQL BQL BQL BQL 10.0 NAPHTHALENE BQL BQL BQL BQL BQL 6.0 10.0 NITROBENZENE BQL BQL BQL BQL BQL 10.0 O-TOLUIDINE BQL BQL BQL BQL BQL 10.0 P-DIMETHYLAMINOAZOBENZENE BQL BQL BQL BQL BQL 10.0 PENTACHLOROBENZENE BQL BQL BQL BQL BQL 10.0 PENTACHLORONITROBENZENE BQL BQL BQL BQL BQL 20.0 PHENACETIN BQL BQL BQL BQL BQL 20.0 PHENANTHRENE BQL BQL BQL BQL BQL 200.0 10.0 PHENOL BQL BQL BQL BQL BQL 30.0 10.0 p-PHENYLENEDIAMINES BQL BQL BQL BQL BQL 10.0 PRONAMIDE BQL BQL BQL BQL BQL 10.0 PYRENE BQL BQL BQL BQL BQL 200.0 10.0 SAFROLE BQL BQL BQL BQL BQL 10.0 sym-TRINITROBENZENE BQL BQL BQL BQL BQL 10.0 Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit J - Estimated result. Present but below SWSL * - Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards - 4,6-Dinitro-o-creosole = 4,6-Dinitro-2-methylphenol = 2-Methyl-4,6-dinitrophenol 2 - Bis (2-chloro-l-methylethyl) ether = 2,2-Oxybis(1-chloropropane) = Bis (2-chloroisopropyl) ether a - Butyl benzyl phthalate = Benzylbutylphthalate 4 - m-Dinitrobenzene = 1,3 Dinitrobenzene e - p-Phenylenediamine = 1,4 Phenylenediamine e - sym-Trinitrobenzene = 1,3,5-Trinitrobenzene NS - Not Sampled RuthCent_0518.x1s TABLE 9 GROUNDWATER SAMPLING RESULTS APPENDIX II ORGANOPHOSPHORUS PESTICIDES BY SW-846 METHOD 8270 APPENDIX II HERBICIDES BY SW-846 METHODS 8151A and 8270D CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 PARAMETER WELL NUMBER 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 PESTICIDES 0,0,0-TRIETHYL PHOSPHOROTHIOATE BQL BQL BQL BQL BQL 10.0 DIMETHOATE BQL BQL BQL BQL BQL 20.0 DISULFOTON BQL BQL BQL BQL BQL 0.3 10.0 FAMPHUR BQL BQL BQL BQL BQL 20.0 KEPONE BQL BQL BQL BQL BQL 20.0 METHYL PARATHION BQL BQL BQL BQL BQL 10.0 PARATHION BQL BQL BQL BQL BQL 10.0 PHORATE BQL BQL BQL BQL BQL 1.0 10.0 THIONAZIN BQL BQL BQL BQL BQL 20.0 2,4,5-T BQL BQL BQL BQL BQL 2.0 2,4,5-TP (SILVEX) BQL BQL BQL BQL BQL 50.0 2,4-D BQL BQL BQL BQL BQL 70.0 2.0 DINOSEB BQL BQL BQL BQL BQL 7.0 1.0 PENTACHLOROPHENOL I BQL I BQL I BQL I BQL I BQL 1 0.3 1 25.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • Shaded " cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards • 1 - Thionazin = 0,0-Diethyl o-2-pyrozinyl RuthCent_0518.xls TABLE 10 GROUNDWATER SAMPLING RESULTS APPENDIX II PESTICIDES/PCBS BY SW-846 METHOD 8081/8082 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 PARAMETER WELL NUMBER 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 4,4'-DDD BQL BQL BQL BQL BQL 0.1 0.1 4,4'-DDE BQL BQL BQL BQL BQL 0.1 4,4'-DDT BQL BQL BQL BQL BQL 0.1 0.1 ALDRIN BQL BQL BQL BQL BQL 0.002 0.05 ALPHA-BHC BQL BQL BQL BQL BQL 0.006 0.05 AROCLOR 1016 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1221 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1232 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1242 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1248 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1254 BQL BQL BQL BQL BQL 0.09 2.0 AROCLOR 1260 BQL BQL BQL BQL BQL 0.09 2.0 BETA-BHC BQL BQL BQL BQL BQL 0.019 0.05 CHLORDANE TOTAL BQL BQL BQL BQL BQL 0.1 0.5 DELTA-BHC BQL BQL BQL BQL BQL 0.019 0.05 DIELDRIN BQL BQL BQL BQL BQL 0.002 0.075 ENDOSULFANI BQL BQL BQL BQL BQL 40.0 0.1 ENDOSULFAN II BQL BQL BQL BQL BQL 42.0 0.1 ENDOSULFAN SULFATE BQL BQL BQL BQL BQL 40.0 0.1 ENDRIN BQL BQL BQL BQL BQL 2.0 0.1 ENDRIN ALDEHYDE BQL BQL BQL BQL BQL 2.0 0.1 GAMMA-BHC LINDANE BQL BQL BQL BQL BQL 0.03 0.05 HEPTACHLOR BQL BQL BQL BQL BQL 0.008 0.05 HEPTACHLOR EPDXIDE BQL BQL BQL BQL BQL 0.004 0.075 METHOXYCHLOR BQL BQL BQL BQL BQL 40.0 1.0 TOXAPHENE BQL BQL BQL BQL BQL 0.03 1.5 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards • INS - Not Sampled RuthCent_0518.xls TABLE 11 GROUNDWATER SAMPLING RESULTS MONITORED NATURAL ATTENUATION PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard Solid Waste Section Limit (SWSL) 8103-MW-2 8103-MW-4 8103-MW-6 8103-MW-8 8103-MW-9 8103-MW-10D 8103-MW-11A ACETIC ACID AM23G BQL BQL BQL 120 u /L BQL BQL BQL ALKALINITY SM 2320B 52,000 ug/L 359,000 ug/L 471,000 ug/L 79,400 ug/L 28,400 ug/L 161,000 ug/L 367,000 ug/L BOD SM 5210B BQL BQL BQL 2,910 ug/L BQL BQL BQL BUTYRIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL CARBON DIOXIDE SM 4500 CO2 C 20,200 u /L 173,000 u /L 248,000 u /L 61,600 u /L 62,500 u /L 130,000 u /L 290,000 u /L CHLORIDE SM 4500 Cl C 2,620 ug/L 18,400 ug/L 336,000 u /L 115,000 ug/L 4,720 ug/L 10,500 ug/L 42,000 ug/L 250,000.0 COD EPA 410.4 BQL BQL 74,000 u /L BQL BQL BQL 20,000 u /L ETHANE AM20GAX BQL BQL 0.75 ug/L BQL BQL BQL 0.15 ug/L ETHENE AM20GAX BQL BQL 0.59 u /L BQL BQL BQL 0.15 u /L HEXANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL HYDROGEN AM20GAX 3.4 nM N/A 3.3 nM 3.2 nM 3.2 nM 2.6 Nm 2.1 u /L i-HEXANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL i-PENTANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL IRON EPA 200.7 3,190 u /L 2,010 u /L 4,370 u /L 188 ug/L (J) 68.5 ug/L (J) 866 u /L 4,010 u /L 300.0 * 300.0 LACTIC ACID & HIBA AM23G BQL BQL BQL BQL BQL BQL BQL METHANE AM20GAX BQL 5.3 ug/L 75 ug/L BQL BQL 410 ug/L 200 ug/L NITRATE -NITROGEN SM 4500 NO3 E 67 u /L 80 u /L 65 u /L J 6,370 u /L J BQL BQL BQL 10,000.0 * 10,000.0 PENTANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL PROPIONOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL PYRUVIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL SULFATE SM 4500 SO4 E BQL BQL BQL 16,600 u /L J BQL BQL BQL 250,000.0 * 250,000.0 SULFIDE EPA 376.1 BQL BQL BQL BQL BQL BQL BQL * * 1,000.0 TOTAL ORGANIC CARBON SM 5310C BQL 3,240 ug/L 28,100 ug/L 3,590 ug/L BQL BQL 6,320 ug/L Notes: • ug/L - micrograms per Liter (ppb) • nM - nano Moles • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • * - Standard not established • NS - Not sampled • Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • Analyzed approximately 2 hours out of hold time Ruth Cent_0518.As TABLE 12 GROUNDWATER AND SURFACE WATER SAMPLING RESULTS C & D PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 15A NCAC 2B Standard for Class B,C Surface Water Solid Waste Section Limit (SWSL) 8103-MW-2 8103-MW-3 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5A ALKALINITY SM 2320B 52,000 340,000 359,000 82,200 40,600 14,100 35,900 17,000 11,300 15,100 ALUMINUM SW 846 6010C 1,580.0 308.0 867.0 423.0 47,300.0 50,000.0 2,400.0 500.0 767.0 788.0 3,500 CHLORIDE SM 4500 Cl C 2,620.0 52,500.0 15,200.0 4,720.0 8,920.0 8,920.0 6,820.0 3,670.0 4,720.0 3,150.0 250,000.0 * 230,000 IRON EPA200.7 3,190:0 `1,070:0 -3,960.-0 `2,580.0 43,700.0 ' 43,100:0 " -3,240.0 773.0 1,070.0 1,020.0 300.0 1,000 300.0 MANGANESE SW 846 6010 34.7 J 262.0 5,3MID 779.0 `1,640.0 1,480.0 128.0 29.7 J 32.7 J 27.6 J 50.0 50.0 MERCURY SW 846 7470 0.06 J 0.04 J 0.02 J 0.07 J 0.14 J 0.03 J 0.05 J 0.01 J -0.16 J 0.04 J 1.0 0.012 0.200 SULFATE SM 4500 SO4 E BQL 41,400 J 14,800 J BQL 44,700 J 61,500 J 10,300 J BQL BQL BQL 250,000.0 250,000.0 TDS SM 2540 C 72,000 552,000 508,000 121,000 162,000 156,000 73,000 40,000 55,000 55,000 500,000.0 TETRAHYDROFURAN SW 846 8260B BQL 1.6 1.9 BQL 1.1 BQL BQL BQL BQL BQL Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit J - Estimated result. Present but below SWSL * - Standard/Limit not established NS - Not sampled I'l - Action Level Shaded cells denote concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels RuthCent_0518.xis TABLE 13 SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA 0 r. r. .. r r r: rrr r• r rrr �aaaa��a��aaaaaaaa • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichl..propane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • ' - Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list • 4 - Aluminum added to C&D constituent list RuthCent_0518.xis TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 04/11/2001 09/12-13/2001 04/03/2002 06/27/2002 10/02/2002 04/02-03/2003 09/03/2003 04/06/2004 10/27/2004 04/05/2005 09/08/2005 04/04-05/2006 10/26-27/2006 5/22-23/2007 10/23-26/2007 05/06-08/2008 09/22-25/2008 8103-MW-2 I I I I I I I I I I I 1 I, MINA I, MNA, C&D I, MNA, C&D 8103-MW-3 I I I I I I I I I I I I I 1 1, C&D 1, C&D 8103-MW-4 I'll 1, 11 t I'll I, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MINA 1, 11(t), MNA 8103-MW-6 I'll 1, 11 t I'll I, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MINA 1, 11(t), MNA 8103-MW-7 I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt 8103-MW-8 I'll I, II t I'll I, II t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MNA I, 11(t), MNA 8103-MW-9 I'll I, II t I'll I, II t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA I, 11, MNA 1, 11(t), MNA 8103-MW-10A 8103-MW-10B I,IIt) I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-10C I,IIt) I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-10D I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 1,IIt,MNA 1,IIt,MNA I,11t,MNA 8103-MW-11A I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I, lilt), MNA I, lilt), MNA I,11t,MNA 8103-MW-11B I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-12 I I I I I I I I I I I 1 I, C&D I, C&D 8103-MW-13 I I I I I I I I I I I 1 I, C&D I, C&D 8103-MW-14 I, C&D I, C&D 8103-MW-15 1, C&D 1, C&D I - denotes well was sampled for Appendix I constituents on this date II - denotes well was sampled for Appendix II constituents on this date II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date MNA - denotes well was sampled for Monitored Natural Attenuation constituents C&D - denotes well was sampled for Construction and Demolition constituents • ' - Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list 4 - Aluminum added to C&D constituent list RuthCent_0518.xis TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 05/18-05/21, 2009 10/07-10/09, 2009 05/17-05/20, 2010 09/20-09/23, 2010 04/25-05/02, 2011 09/27-09/30, 2011 04/30-05/03, 2012 09/25-10/03, 2012 04/15-18/2013 09/23-09/28, 2013 04/28-05/01, 2014 09/29-10/04, 2014 04/27-05/02, 2015 09/28-10/07, 2015 04/26-05/05, 2016 8103-MW-2 I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D° I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&Ds I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D 8103-MW-3 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-4 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-6 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-7 1,11 I, II t 1,11 I, II t 1,11 I, II(t)s, MNA 8103-MW-8 1 I, II, MNA I, 11(t), MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 1 I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-9 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)z, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-10A 8103-MW-10B I, II t I, II t I, II t I, II t I, II t I, II(t)s I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10C I, II t I, II t I, II t I, II t I, II t I, II(t)s I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10D I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t)s, MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA 8103-MW-11A I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t)s, MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA 8103-MW-11 Bi I, II t I, II t I, II t I, II t I, II t I, II(tp I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-12 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-13 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-14 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-15 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • 1 - Appendix I volatiles only • 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • 4 - Aluminum added to C&D constituent list 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list 6 - Tetrahydrofuran added to C&D constituent list RuthCent_0518.xls TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA Well 09/19-09/22, 2016 05/03-05/09, 2017 10/02-10/05, 2017 05/10-05/17, 2018 8103-MW-2 I, MNA, C&D I, MINA, C&D I, MNA, C&D I, MINA, C&D 8103-MW-3 I, C&D I, C&D I, C&D I, C&D 8103-MW-4 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA 8103-MW-6 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA 8103-MW-7 I, II t 1,11 I, II t 1,11 8103-MW-8 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA 8103-MW-9 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA 8103-MW-10A 8103-MW-10B I, II t I, II t I, II t I, II t 8103-MW-10C I, II t I, II t I, II t I, II t 8103-MW-10D I, 11(t), MINA I, 11(t), MNA I, 11(t), MINA I, 11(t), MNA 8103-MW-11A I, 11(t), MNA I, 11(t), MINA I, 11(t), MNA I, 11(t), MINA t I, II t I, II t I, It 83-MW-11B -MW-1 I, C&D I, C&D I, C&D I, C&D -MW-13 3 I, C&D I, C&D I, C&D I, C&D3-MW-13 4 I, C&D I, C&D I, C&D I, C&D .JO I, C&D I, C&D I, C&D I, C&D • I - denotes well was sampled for Appendix I constituents on this date • 11 - denotes well was sampled for Appendix 11 constituents on this date • 11(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • ' -Appendix I volaliles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • " - Aluminum added to C&D constituent list • s - 1,3-dichlorobenzene added to Appendix II triggered constituent list • s - Tetrahydrofuran added to C&D constituent list RuthCent_0518.xls TABLE14 GROUNDWATER FLOW RATES CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Hydraulic Conductivity Effective Velocity Velocity Well No. (cm/sec) Gradient Porosity (cm/sec) (ft/yr) 8103-MW-2 1.3 x 10-5 0.087 .20 5.63 x 10-6 5.83 8103-MW-4 3.7 x 10-6 0.044 .20 8.16 x 10-7 0.84 8103-MW-6 2.4 x 10-5 0.109 .20 1.30 x 10-5 13.48 8103-MW-7 2.9 x 10-6 0.168 .201 2.43 x 10-6 2.52 8103-MW-8 1.6 x 10-4 0.029 .20 2.32 x 10-5 24.01 8103-MW-9 2.1 x 10-5 0.023 .20 2.42 x 10-6 2.50 The above results were obtained by using the relation: V = Ki Where K = hydraulic conductivity i = gradient n = effective porosity V = velocity Porosity value may not reflect true nature of fractured bedrock. 8103-MW-7 is screened in rock. RuthCent_0518.xls TABLE15 SURFACE WATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Sample Location 15A NCAC 2B Standard for Class B,C Surface Water Solid Waste Section Limit (SWSL) 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5A ANTIMONY BQL BQL BQL BQL 6.0 ARSENIC BQL BQL BQL BQL 50.0 10.0 BARIUM 62.5 J 30.4 J 38.5 J 33.9 J 100.0 BERYLLIUM BQL BQL BQL BQL 6.5 1.0 CADMIUM BQL BQL BQL BQL 2.0 1.0 CHROMIUM 6.0 J 5.0 J 2.1 J 1.7 J 50.0 10.0 COBALT 1.7 J BQL BQL BQL 10.0 COPPER 8.6 J 5.5 J 6.0 J 4.3 J 7.0111 10.0 LEAD BQL BQL BQL BQL 25.0 10.0 NICKEL 1.1 J BQL 19.6 J BQL 88.0 50.0 SELENIUM BQL BQL BQL BQL 5.0 10.0 SILVER 4.0 J BQL BQL 2.7 J 0.06"] 10.0 THALLIUM BQL BQL BQL BQL 5.5 VANADIUM 9.4 J 2.2 J 3.4 J 3.4 J 25.0 ZINC 1 230.0 1 319.0 1 258.0 1 146.0 1 50.0 10.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • ['] - Action Level • NS - Not sampled. Dry location. RuthCent_0518.x1s TABLE 16 SURFACE WATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameters Sample Location 15A NCAC 2B/EPA Standards for Class B,C Surface Water Solid Waste Section Limit (SWSL) 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL 5.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL 2,500.0 1.0 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL 3.0 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL 1.0 1,1-DICHLOROETHANE BQL BQL BQL BQL 20,000.0 5.0 1,1-DICHLOROETHENE BQL BQL BQL BQL 5,400.0 5.0 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL 1.0 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL 13.0 1,2-DIBROMOETHANE BQL BQL BQL BQL 1.0 1,2-DICHLOROBENZENE BQL BQL BQL BQL 470.0 5.0 1,2-DICHLOROETHANE BQL BQL BQL BQL 1.0 1,2-DICHLOROPROPANE BQL BQL BQL BQL 1.0 1,4-DICHLOROBENZENE BQL BQL BQL BQL 100.0 1.0 2-BUTANONE BQL BQL BQL BQL 160,000.0 100.0 2-HEXANONE BQL BQL BQL BQL 50.0 4-METHYL-2-PENTANONE BQL BQL BQL BQL 26,000.0 100.0 ACETONE BQL BQL BQL BQL 2,000.0 100.0 ACRYLONITRILE BQL BQL BQL BQL 55.0 BENZENE BQL BQL BQL BQL 1.0 BROMOCHLOROMETHANE BQL BQL BQL BQL 3.0 BROMODICHLOROMETHANE BQL BQL BQL BQL 1.0 BROMOFORM BQL BQL BQL BQL 3.0 BROMOMETHANE BQL BQL BQL BQL 10.0 CARBON DISULFIDE BQL BQL BQL BQL 100.0 CARBON TETRACHLORIDE BQL BQL BQL BQL 1.0 CHLOROBENZENE BQL BQL BQL BQL 140.0 3.0 CHLOROETHANE BQL BQL BQL BQL 10.0 CHLOROFORM BQL BQL BQL BQL 5.0 CHLOROMETHANE BQL BQL BQL BQL 1.0 CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL 5.0 CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL 12.0 1.0 DIBROMOCHLOROMETHANE BQL BQL BQL BQL 3.0 DIBROMOMETHANE BQL BQL BQL BQL 10.0 ETHYLBENZENE BQL BQL BQL BQL 97.0 1.0 IODOMETHANE BQL BQL BQL BQL 10.0 METHYLENE CHLORIDE BQL BQL BQL BQL 1.0 STYRENE BQL BQL BQL BQL 1.0 TETRACHLOROETHENE BQL BQL BQL BQL 1.0 TOLUENE BQL BQL BQL BQL 11.0 1.0 TOTAL XYLENES BQL BQL BQL BQL 670.0 5.0 TRANS-1,2-DICHLOROETHENE BQL BQL BQL BQL 5.0 TRANS- 1,3-DICHLOROPROPENE BQL BQL BQL BQL 12.0 1.0 TRANS- 1,4-DICHLORO-2-BUTENE BQL BQL BQL BQL 100.0 TRICHLOROETHENE BQL BQL BQL BQL 1.0 TRICHLOROFLUOROMETHANE BQL BQL BQL BQL 1.0 VINYL ACETATE BQL BQL BQL BQL 50.0 VINYL CHLORIDE BQL BQL BQL BQL 1.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • J - Estimated result. Present but below SWSL • ' - Standard not established • Shadedcellscells denote concentrations that equal or exceed 2B Standards RutfFGQecnVitg xlss that are not naturally occurring and have no established standards, the SWSLs are the Standards TABLE 17 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection Solid Waste Section Limit 8103-MW-2 8103-MW-3 8103-MW4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard (SWSL) ALUMINUM 47,300.0 50,000.0 3,500.0 ' BARIUM - 767.0 - 1-1130.0 700.0 ' 100.0 CHLORIDE 336,000.0, 250,000.0 CHROMIUM 22.2 18.7 65.1 46A 56.0 53.9 10.0 ' 10.0 COBALT 1.2 J 62.5 5:3 J 36.5 27.8 11.5 20.7 6.8 J 3.'0 J 38.6 29.4 ' 1.0 10.0 IRON • 3190.0 1,070.0 2,010,0 •4,370.0 _ = 866.0 4,010.0. 3,960.0 - _ 2,580.0• 43,70&.0 43,100.0 = 300.0 ' 300.0 LEAD 18.3 15.1 16.3 30A 15.0 ' 10.0 MANGANESE 262.0 5,370.0 779.0 1640.0 1,480.0 50.0 ' 50.0 TDS ' 552,000.0 508,000.0 500,000.0 THALLIUM 18.4 4.6 J 7.8 ' 0.28 5.5 VANADIUM 5.3J 1.8J 15AJ 2.2J 24AJ 1.01 0.8J 129.0 1.2J 89.3 3.4J 2.4J 146.0 108.0 ' 0.3 25.0 1,2-DICHLOROPROPANE 25:3 0.6 ' 1.0 1,4-DICHLOROBENZENE 7.9 6.0 ' 1.0 BENZENE 1.4 1.2 1.0 ' 1.0 TETRACHLOROETHENE 1.2 0.7 ' 1.0 VINYL CHLORIDE - 0.4J 0.3,J 0A J - 0.2 J 0.03 ' 1.0 Notes: • All results in parts per billion (ppb) • J - Estimated result. Present but below SWSL • ' - Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • For constituents that are not naturally occurring and have no established standards, the SWSLs are the Standards RuthCeM_0519As TABLE18 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 10-17, 2018 Parameter Sample Location 15A NCAC 2B Standard for Class B,C Surface Water Solid Waste Section Limit (SWSL) 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 COPPER 8.6 J 7.0111 10.0 IRON 3,240.0 1000.0111 300.0 MERCURY 0.05 J 0.16 J 0.04 J 0.012 0.200 SILVER 4.0 J 2.7 J 0.06111 10.0 ZINC 230.0 319.0 258.0 146.0 50.0111 10.0 Notes: • All results in parts per billion (ppb) • J - Estimated result. Present but below SWSL • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • I'] - Action Level • NS - Not sampled. Dry location RuthCent_0518.xls APPENDIX D FIGURE 2 AND TABLES FROM THE OCTOBER 2018 SEMI-ANNUAL SAMPLING REPORT BY SCARLETT GEOPHYSICAL CONSULTING P.C. �, r ,.� i7 D- ` " _`"'_wwr, - yr-'''r • 4 ``,,..'- it•p ., .. M7 • >r iul // XPAR�OL U U 0 ,� , f -- -'"` `--. CENTRAL SANITARY LANDFILL, APO0Elf W F00 PR1N E PANSfO�l- RUTHERFORD COUNTY, NORTH CAROLINA fall it/, x.�-...._.� �P 0 S > C RDS C A TY) , „.: »•,. TOWN OF RUTHERFORDTON •' r , SCARL.ETT GEOPHYSIC4L CONSULTING, PC A. x WASTEWATER TREATMENT ,t l• � � *Sol V f L.. TER p.Napr .. y ,U•••r.r- 'AMA FACILITY i >< --""'�`J-, J Qj GROUNDWATER CONTOUR MAP' '' �- O .�'� �` a '' �- OCTOBER 1-8,2018 Figure 2, ro tAl. 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MIP1 _TR BUYARt�,EAST \ ` "'� zoo' NINO TABLE 1 SUMMARY OF MONITORING WELL DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA Well No. Elevation (ft) Depth of Well (ft) Static Water Levels3 May 3-9, 2017 Oct 2-5, 2017 May 10-17, 2018 Oct 1-8, 2018 Land Surface Top of Casing' Top of Screen Bottom of Screen Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) 8103-MW-2 995.43 995.51 945.43 935.43 60.0 46.25 949.26 47.27 948.24 46.89 948.62 46.20 949.31 8103-MW-3 859.62 860.28 822.62 812.62 47.0 33.89 826.39 34.61 825.67 32.09 828.19 33.23 827.05 8103-MW-4 849.72 851.03 809.72 799.72 50.0 36.06 814.97 36.48 814.55 31.91 819.12 34.82 816.21 8103-MW-6 833.43 834.90 810.93 795.93 37.5 31.88 803.02 32.33 802.57 31.36 803.54 31.12 803.78 8103-MW-7 890.51 892.70 851.51 836.51 54.0 37.82 854.88 37.33 855.37 34.93 857.77 35.88 856.82 8103-MW-8 857.86 860.31 828.36 813.36 44.5 43.49 816.82 44.26 816.05 39.89 820.42 42.56 817.75 8103-MW-9 864.97 867.25 842.47 827.47 37.5 34.00 833.25 35.65 831.60 34.02 833.23 34.64 832.61 8103-MW-10A 834.73 837.23 743.73 733.73 101.0 4.505 832.735 5.665 831.57' 6.475 830.76' 6.725 830.515 8103-MW-10B 834.50 836.15 802.50 797.50 37.0 8.92 827.23 10.01 826.14 9.11 827.04 9.51 826.64 8103-MW-10C 834.50 836.19 823.50 818.50 16.0 8.65 827.54 9.78 826.41 8.88 827.31 9.29 826.90 8103-MW-10D 834.73 837.23 778.73 768.73 66.0 9.88 827.35 11.16 826.07 9.96 827.27 9.44 827.79 8103-MW-11A 815.39 817.18 780.39 770.39 45.0 8.62 808.56 9.22 807.96 8.26 808.92 8.55 808.63 8103-MW-11 B 816.32 817.72 806.32 796.32 20.0 9.65 808.07 10.31 807.41 9.45 808.27 9.42 808.30 8103-MW-12 884.33 886.68 849.33 834.33 50.0 33.10 853.58 38.90 847.78 32.27 854.41 38.10 848.58 8103-MW-13 960.80 962.90 887.80 872.80 88.0 82.05 880.85 82.50 880.40 81.21 881.69 80.26 882.64 8103-MW-14 867.08 869.48 849.68 834.68 32.4 23.51 845.97 24.80 844.68 20.67 848.81 27.18 842.30 8103-MW-15 887.58 889.54 839.58 849.58 38.0 31.41 858.13 35.38 854.16 29.10 860.44 32.40 857.14 Notes: 1 Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC, December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering and Geology, Raleigh, NC, 2002 and 1999, respectively 2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C. 3 Water levels taken from top of casing 4 Depth of well measured from land surface 5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day) RuthCent_1018 TABLE 2 GROUND AND SURFACE WATER SAMPLING FIELD DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Sample Location 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10A 8103-MW-10B Temperature 15.08°C 17.4°C 13.69°C 15.41°C 16.7°C 14.39°C 13.79°C NS 16.6°C Conductivity 93.0 pmhos/cm 934 pmhos/cm 580 pmhos/cm 1960 pmhos/cm 953 pmhos/cm 393 pmhos/cm 41.0 pmhos/cm NS 102.3 pmhos/cm pH 7.24 6.38 5.88 5.90 6.70 5.33 4.59 NS 6.17 ORP 235 mV NA 186 mV 6 mV NA 310 mV 307 mV NS NA DO 6.54 mg/I NA 0.72 mg/I 1.69 mg/I NA 5.48 mg/I 6.43 mg/I NS NA Turbidity 18.4 NTU NA 0.0 NTU 0.0 NTU NA 0.0 NTU 0.0 NTU NS NA Parameter Sample Location 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 Temperature 17.1°C 13.06°C 13.42°C 17.2°C 17.7°C 17.6°C 17.4°C 16.2°C 20.5°C Conductivity 100.0 pmhos/cm 286 pmhos/cm 715 pmhos/cm 167.E pmhos/cm 563 pmhos/cm 191.3 pmhos/cm 206 pmhos/cm 233 pmhos/cm 101.6 pmhos/cm pH 6.40 5.30 5.56 5.86 6.41 5.70 5.71 5.87 7.13 ORP NA 133 mV 53 mV NA NA NA NA NA NA DO NA 0.54 mg/I 0.40 mg/I NA NA NA NA NA NA Turbidity NA 0.0 NTU 0.0 NTU NA NA NA NA NA NA Parameter Sample Location 8103-SW-3 8103-SW-4 8103-SW-5 Temperature 21.0°C 20.9°C 20.4°C Conductivity 80.6 pmhos/cm 58.3 pmhos/cm 76.7 pmhos/cm pH 7.32 7.16 6.71 ORP NA NA NA DO NA NA NA Turbidity NA NA NA NS - Not sampled NA - Not analyzed RuthCent_1018 TABLE 3 GROUNDWATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Well Number 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B ANTIMONY BQL BQL BQL BQL BQL BQL BQL BQL * 1.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 BARIUM 21.7 167.0 154.0 382.0 132.0 163.0 59.1 357.0 700.0 BERYLLIUM BQL BQL BQL BQL BQL BQL BQL 0.88 4.0 CADMIUM BQL 0.4 0.4 0.5 0.4 0.3 BQL BQL 2.0 CHROMIUM 2.2 1.8 2.3 7.0 4.8 2.8 2.9 26.3 10.0 COBALT BQL 1.2 1.3 = 44.5 1.9 : - BQL BQL 17.4 1.0 COPPER BQL 1.3 3.9 BQL 5.2 BQL BQL 23.0 1000.0 LEAD BQL BQL 2.6 BQL BQL BQL BQL 10.5 15.0 NICKEL BQL 1.5 1.8 19.7 3.3 1.3 1.2 20.3 100.0 SELENIUM BQL BQL BQL 6.78 BQL BQL BQL BQL 20.0 SILVER 4.7 BQL BQL BQL BQL BQL BQL BQL 20.0 THALLIUM BQL BQL BQL 34.3 BQL BQL BQL BQL 0.28 VANADIUM 2.1 2.3 8.6 BQL 5.9 1.5 BQL 53.8 * 0.3 ZINC 12.4 9.0 26.1 55.6 29.7 47.4 17.8 66.5 1000.0 Parameter Well Number 15A NCAC 2L Standard for Class GAGroundwater NC Groundwater Protection Standard 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 ANTIMONY BQL BQL BQL BQL BQL BQL BQL BQL * 1.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 BARIUM 209.0 191.0 183.0 492.0 140.0 171.0 83.4 104.0 700.0 BERYLLIUM 0.59 BQL BQL 3.6 BQL BQL BQL BQL 4.0 CADMIUM BQL 0.32 0.3 BQL 0.3 0.4 BQL 0.3 2.0 CHROMIUM 23.5 1.9 3.8 67.2 6.8 2.7 1.6 3.9 10.0 COBALT 10.7 27.1 12.5 28.4 4.3 4.7 BQL BQL 1.0 COPPER 13.0 10.3 BQL 30.9 8.8 14.5 BQL BQL 1000.0 LEAD 6.6 BQL BQL 23.1 2.4 3.9 BQL BQL 15.0 NICKEL 11.3 12.1 4.6 40.8 3.8 12.4 0.7 0.8 100.0 SELENIUM BQL BQL BQL BQL BQL BQL BQL BQL 20.0 SILVER BQL BQL BQL BQL BQL BQL BQL BQL 20.0 THALLIUM BQL • 4.4 14.2 BQL 3.4 •2.7 BQL BQL 0.28 VANADIUM 42.& BQL 0.9 136.0 9.5 2.9 2.4 2.7 0.3 ZINC 57.2 25.0 6.6 127.0 22.0 21.6 9.3 10.2 1000.0 Notes: All results in parts per billion (ppb) • BQL - Below Method Detection Limit NS - Not Sampled • * - Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCent_1018 TABLE 4 GROUNDWATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MWA 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 200.0 ' 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2 0.18 1,1,2-TRICHLOROETHANE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 0.6 1,1-DICHLOROETHANE BQL BQL BQL BQL 0.6 BQL BQL BQL BQL 1.3 BQL BQL BQL BQL BQL BQL 6.0 ` 1,1-DICHLOROETHENE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 7.0 ' 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 " 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 0.04 1,2-DIBROMOETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 " 1,2-DICHLOROBENZENE BQL BQL BQL 0.6 BQL BOIL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 20.0 1,2-DICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 " 1,2-DICHLOROPROPANE BQL BQL BQL BOIL BQL BOIL 20.3 BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 0.6 1,4-DICHLOROBENZENE BQL BQL 0.7 6.9 BQL BQL BQL BQL BQL 2.0 2.6 BQL BQL BQL BQL BQL 6.0 " 1,4-DIOXANE 2.3 '22.9' 2.2 108.0' .5.3" 7.0 BQL 2.5 BQL 2.2 10.8' 2.7 4:8 BOIL 2.5 BQL 3.0 2-BUTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4,000.0 ` 2-HEXANONE BQL BQL BQL BOIL BQL BOIL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 40.0 4-METHYL-2-PENTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 560.0 ACETONE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BQL BQL BOIL BQL BQL 6,000.0 ' ACRYLONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ` BENZENE BQL BQL BQL 12 BQL BQL BQL BOIL BQL 1.0 0.2 BQL BQL 0.6 BQL BQL 1.0 ' BROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BROMODICHLOROMETHANE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BOIL BQL BOIL BQL BQL 0.6 ' BROMOFORM BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 " BROMOMETHANE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BOIL BQL BOIL BQL BQL 1 10.0 CARBON DISULFIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 700.0 " CARBON TETRACHLORIDE BQL BQL BQL BOIL BQL BQL BQL BOIL BQL BOIL BQL BOIL BQL BOIL BQL BQL 0.3 CHLOROBENZENE BQL BQL 0.6 36.5 BQL BQL BQL BQL BQL 1.8 5.4 BQL BQL BQL BQL BQL 50.0 " CHLOROETHANE BQL BQL 0.61 BQL BQL BQL BQL BQL BQL 0.6 0.4 BQL BQL 0.8 BQL BQL 3,000.0 ' CHLOROFORM BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ` CHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 ' CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL 0.3 9.5 BQL BQL BQL 0.5 0.3 BQL 70.0 " CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 DIBROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.41 DIBROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ETHYLBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 " METHYL IODIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHYLENE CHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 5.0 " STYRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 TETRACHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.3 BQL BQL BQL BQL BQL BQL 0.7 " TOLUENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 TOTAL XYLENES BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.5 BQL BQL 500.0 ` TRANS-I,2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 ' TRANS-I,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.2 TRANS-I,4-DICHLORO-2-BUTENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' TRICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.1 BQL BQL BQL BQL BQL BQL 3.0 ` TRICHLOROFLUOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2 0.3J 2,000.0 ' VINYL ACETATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 88.0 VINYLCHLORIDE BQL BQL BQL 0.4 BQL BQL BQL BQL BQL 0.4 0.7 BQL BQL 0.2 BQL BQL 0.03 ' All results in parts per billion (ppb) BQL - Below Method Detection Limit B - Lab blank contamination NS - Not Sampled `- Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCeM_1018 TABLE 5 GROUNDWATER SAMPLING RESULTS APPENDIX II TRIGGERED CONSTITUENTS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 SW-846 Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection Parameter Method 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B GAGroundwater Standard 1,3-Dichlorobenzene 8260 BQL 0.5 BQL BQL BQL BQL BQL BQL BQL BQL 200.0 1,3-Dichloro ro ane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Dichlorodifluorom ethane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1,000.0 4,4'- DDD 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 4,4'- DDT 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 al ha-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.006 beta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 delta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 Endrin 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.0 gamma-BHC Lindane 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.03 Mercury 7470 0.09 0.05 BQL BQL 0.03 0.01 BQL 0.05 BQL 0.08 1.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • * - Standard not established Shaded" . ' ° cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • NA -Not analyzed • NS - Not Sampled RuthCent_1018 TABLE 6 GROUNDWATER SAMPLING RESULTS MONITORED NATURAL ATTENUATION PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 8103-MW-2 8103-MW-4 8103-MW-6 8103-MW-8 8103-MW-9 8103-MW-10D 8103-MW-11A ACETIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL ALKALINITY SM 2320B 52,100 u /L 346,000 u /L 621,000 u /L 75,300 u /L 22,300 u /L 143,000 u /L 378,000 u /L BOD SM 5210B BQL BQL 2,190 u /L BQL BQL BQL BQL BUTYRIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL CARBON DIOXIDE SM 4500 CO2 C 2,640 u /L 202,000 u /L 316,000 u /L 106,000 u /L 79,200 u /L 150,000 u /L 304,000 u /L CHLORIDE SM 4500 Cl C 2,940 u /L 13,200 u /L 284,000 ug/L 71,900 u /L 5,870 u /L 10,800 u /L 41,100 u /L 250,000.0 COD EPA 410.4 BQL 7,000 u /L 84,000 u /L 6,000 u /L BQL 5,000 u /L 21,000 u /L ETHANE AM20GAX BQL BQL 0.70 u /L BQL BQL BQL 0.19 u /L ETHENE AM20GAX BQL BQL 0.45 u /L BQL BQL BQL 0.20 u /L HEXANOIC ACID AM23G BQL BQL BQL BQL BQL <MRL BQL HYDROGEN AM20GAX 48 nM 16 Nm 24 nM 22 nM 24 nM 24 nM 48 Nm i-HEXANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL i-PENTANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL IRON EPA 200.7 1,060 ug/L 1,190 ug/L 3,790 ug/L 223 u /L 33.1 u /L 734 ug/L 3890 ug/L 300.0 LACTIC ACID & HIBA AM23G BQL BQL BQL BQL BQL BQL BQL METHANE AM20GAX BQL 3.0 u /L 120 u /L BQL 3.5 u /L 3.5 u /L 320 u /L NITRATE -NITROGEN SM 4500 NO3 E 60.0 u /L BQL BQL 6,020 u /L BQL BQL BQL 10,000.0 PENTANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL PROPIONOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL PYRUVIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL SULFATE SM 4500 SO4 E BQL BQL 11,000 u /L 12,700 u /L BQL BQL 10,700 u /L 250,000.0 SULFIDE EPA 376.1 BQL BQL BQL BQL BQL BQL BQL TOTAL ORGANIC CARBON SM 5310 BQL 2,380 ug/L 27,700 ug/L 2,580 ug/L BQL BQL 6,100 ug/L Notes: • ug/L - micrograms per Liter (ppb) • nM - nano Moles • BQL - Below Method Detection Limit • * - Standard not established • ** - Analysed past hold time • NS - Not sampled RuthCent_1018 TABLE 7 GROUNDWATER AND SURFACE WATER SAMPLING RESULTS C & D PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 15A NCAC 213 Standard for Class B,C Surface Water 8103-MW-2 8103-MW-3 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 ALKALINITY SM 2320B 52,100 342,000 253,000 74,400 41,800 24,200 27,000 24,200 14,000 21,400 ALUMINUM SW8466010C 468.0 314.0 2,400.0 599.0 504.0 1,060.0 278.0 55.4 254.0 158.0 3,500.0 CHLORIDE SM 4500 Cl C 2,940 458,400 9,780 6,360 5,870 9,780 7,340 5,870 5,380 6,360 250,000.0 230,000111 IRON EPA200.7 1,060.0 1,060.0 4,500.0 2,570.0 637.0, 1,020.0 426.0 297.0 496.0 991.0 300.0 1 1,000111 MANGANESE SW 846 6010 12.0 275.0_ 1,620.0 1,060.0 29.3 60.3 76.4 41.2 21.7 35.6 50.0 MERCURY SW 846 7470 0.03 BQL 0.02 0.12 BQL BQL 0.04 BQL 0.05 BQL 1.0 0.012 SULFATE SM 4500 SO4 E BQL 42,700 BQL BQL 24,600 36,600 BQL BQL BQL BQL 250,000.0 TDS SM 2540 C 78,000 572,000 323,000 125,000 139,000 185,000 79,000 60,000 57,000 66,000 TETRAHYDROFURAN SW 8468260B BQL BQL BQL BQL 1.9 BQL BQL BQL BQL BQL Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit * - Standard/Limit not established NS - Not sampled Ill - Action Level Shaded cells denote concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels NA - Not analyzed due to insufficient sample volume. See note. RuthCent_1018 TABLE 8 SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA ���� r r •• r: r: •• ����� r. r. .. ���� r r r: rrr r• r rrr �aaaa��a��aaaaaaaa • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix 11 triggered constituents (113-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodiFluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • I - Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix 11 triggered constituent list • a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • ° - Aluminum added to C&D constituent list • s - 1,3-dichlorobenzene added to Appendix 11 triggered constituent list • 6 - Tetrahydrofuran added to C&D constituent list • 7 - 1,4-Dioxane added to all sample locations RuthCent_1018 TABLE 8 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 04/11/2001 09/12-13/2001 04/03/2002 06/27/2002 10/02/2002 04/02-03/2003 09/03/2003 04/06/2004 10/27/2004 04/05/2005 09/08/2005 04/04-05/2006 10/26-27/2006 5/22-2312007 10/23-26/2007 05/06-08/2008 09/22-25/2008 8103-MW-2 I I I I I I I I I I I 1 I, MNA I, MNA, C&D I, MNA, C&D 8103-MW-3 I I I I I I I I I I I I I 1 I, C&D I, C&D 8103-MW-4 I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1,IIt,MNA 1,11,MNA 1,IIt,MNA 8103-MW-6 I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll I, 11(t) I'll I, 11(t), MNA 1, 11, MNA I, 11(t), MNA 8103-MW-7 I'll 1, 11(t) I'll I, 11(t) I'll I, 11(t) I'll I, 11(t) I'll 1, 11(t) I'll I, 11(t) I'll I, 11(t) I'll I, 11(t) 8103-MW-8 I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll I, 11(t), MNA I, II, MNA I, 11(t), MNA 8103-MW-9 I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll 1, 11(t) I'll I, 11(t), MNA 1,11,MNA I, 11(t), MNA 8103-MW-10A 8103-MW-10B 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 8103-MW-10C 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 8103-MW-10D 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA 8103-MW-11A 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 11(t) 1, 11(t) I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA 8103-MW-11B 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) -1, 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 1, 11(t) 8103-MW-12 I I I I I I I I I I I 1 1, C&D 1, C&D 8103-MW-13 1 1 1 1 1 1 1 1 1 1 1 1 1, C&D 1, C&D 8103-MW-14 1, C&D 1, C&D 8103-MW-15 1, C&D 1, C&D • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • 11(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • - Appendix I volatiles only • z - Mercury and endrin aldehyde added to Appendix I I triggered constituent list • 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • ° - Aluminum added to C&D constituent list • s - 1,3-dichlorobenzene added to Appendix 11 triggered constituent list • 6 - Tetrahydrofuran added to C&D constituent list • 7 - 1,4-Dioxane added to all sample locations RuthCent_1018 SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA TABLE 8 (cont.) Well 05/18-05/21, 2009 10/07-10/09, 2009 05/17-05/20, 2010 09/20-09/23, 2010 04125-05102, 2011 09/27-09/30, 2011 04130-05103, 2011 09/25-10/03, 2012 04115-04118,2013 09/23-09/28, 2013 04128-0511, 2014 09/29-10/04, 2014 04/27-05102, 2015 09/28-10107, 2015 04/26-05/05, 2016 09119-09/22, 2016, 8103-MW-2 I MNA C&D 1, MINA C&D I MNA C&D I, MNA, C&D4 I, MNA, C&D I, MINA, C&D I, MNA, C&D I, MINA, C&D I, MNA, C&D I, MINA, C&D I, MINA, C&Ds I, MINA, C&D I, MNA, C&D I, MNA, C&D I, MINA, C&D I, MNA, C&D 8103-MW-3 I, C&D 1, C&D I, C&D I, C&D4 I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D I, C&D 8103-MW-4 I, II, MNA 1, lilt), MNA I, II, MNA I, II t MNA I, II, MNA I, II(t)s, MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MINA I, II, MNA I, II(t), MINA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA 8103-MW-6 I, II, MNA 1, lilt), MNA I, II, MNA I, lilt), MNA I, II, MNA I, II(t)s, MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MINA I, II, MNA I, II(t), MINA I, II, MINA I, II(t), MNA I, II, MNA I, II(t), MNA 8103-MW-7 III I, II t I, II I, II t III I, II(t)s I'll I, II(t) I'll I, II(U I'll I, II(t) I'll I, II(t) I'll I, II(t) 8103-MW-8 I, II, MNA 1, lilt), MNA I, lilt), MNA I, II, MNA I, II(t)s, MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MNA I, II, MINA I, II(t), MNA 8103-MW-9 I, II, MNA 1. lilt), MNA I, II, MNA I, lilt), MNA I, II, MNA I, II(t)s, MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MINA I, II, MNA I, lilt), MINA I, II, MINA I, II(t), MNA I, II, MINA I, II(t), MNA 8103-MW-10A 8103-MW-10B 1, II t I, II t I, II t I II t II t I, II(t)s I, II(t) I, II(U I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10C 1, II t I, II t II t I II t II t I, II(t)s I, II(t) I, II(U I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10D I, II t, MNA 1, lilt), MNA I, II t MNA I, lilt), MNA I, II t MNA I, II(t)s, MINA I, II(t), MNA I, lilt), MINA I, II(t), MNA I, lilt), MINA I, II(t), MINA I, lilt), MINA I, lilt), MINA I, II(t), MNA I, II(t), MINA I, II(t), MNA 8103-MW-11A I, II t, MNA 1, lilt), MNA I, II t MNA I, lilt), MNA I, II t MNA I, II(t)s, MINA I, II(t), MNA I, lilt), MINA I, II(t), MNA I, lilt), MINA I, II(t), MINA I, lilt), MINA I, lilt), MINA I, II(t), MNA I, II(t), MINA I, II(t), MNA 8103-MW-11B 1, II t I, II t II t I II t II t I, II(t)s I, II(t) I, II(U I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-12 I, C&D 1, C&D I, C&D I, C&D4 I, C&D I, C&D I, C&D 1 I, C&D 1 I, C&D 1 I, C&D I, C&Ds I, C&D 1 I, C&D I, C&D I, C&D 1 I, C&D 8103-MW-13 I, C&D 1, C&D I, C&D I, C&D4 I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D I, C&D 8103-MW-14 I, C&D 1, C&D I, C&D I, C&D4 I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D I, C&D 8103-MW-15 I, C&D 1 I, C&D 1 I, C&D 1 I, C&D4 1 I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D I, C&D • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • ' -Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • 4 - Aluminum added to C&D constituent list • 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list • 6 - Tetrahydrofuran added to C&D constituent list • 7 - 1,4-Dioxane added to all sample locations RuthCent_1018 TABLE 8 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 05/03-05/09, 2017 10/02-10/05, 2017 05/10-05/17, 2018 10/01-10/08, 2018 8103-MW-2 I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D7 8103-MW-3 I, C&D I, C&D I, C&D I, C&D7 8103-MW-4 I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 8103-MW-6 I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 8103-MW-7 1,11 I, II t 1,11 I, II(t) 8103-MW-8 I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 8103-MW-9 I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 8103-MW-10A 8103-MW-10B I, II t I, II t I, II t I, II(t) 8103-MW-10C I, II t I, II t I, II t I, II(t) 8103-MW-10D I, 11(t), MNA I, 11(t), MINA I, 11(t), MINA I, II(t), MNA7 8103-MW-11A I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t), MNA7 8103-MW-11B I, II t I, II t I, II t I, II(t) 8103-MW-12 I, C&D I, C&D I, C&D I, C&D7 8103-MW-13 I, C&D I, C&D I, C&D I, C&D7 8103-MW-14 I, C&D I, C&D I, C&D I, C&D7 8103-MW-15 I, C&D I, C&D I, C&D I, C&D7 I - denotes well was sampled for Appendix I constituents on this date II - denotes well was sampled for Appendix II constituents on this date II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date MNA - denotes well was sampled for Monitored Natural Attenuation constituents C&D - denotes well was sampled for Construction and Demolition constituents ' -Appendix I volaliles only 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list ° -Aluminum added to C&D constituent list 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list 6 - Tetrahydrofuran added to C&D constituent list - 1,4-Dioxane added to all sample locations RuthCent_1018 TABLE 9 GROUNDWATER FLOW RATES CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Hydraulic Conductivity Effective Velocity Velocity Well No. (cm/sec) Gradient Porosity (cm/sec) (ft/yr) 8103-MW-2 1.3 x 10-50.089 .20 5.77 x 10 5.97 8103-MW-4 3.7 x 10-6 0.032 .20 5.95 x 10-7 0.62 8103-MW-6 2.4 x 10-5 0.100 .20 1.20 x 10-5 13.15 8103-MW-7 2.9 x 10-6 0.095 .201 1.38 x 10-6 1.42 8103-MW-8 1.6 x 10-4 0.021 .20 1.66 x 10-5 17.23 8103-MW-9 I 2.1 x 10- 0.022 .20 1 2.33 x 1 O'l 2.42 The above results were obtained by using the relation: V = Ki n Where K = hydraulic conductivity i = gradient n = effective porosity V = velocity Porosity value may not reflect true nature of fractured bedrock. 8103-MW-7 is screened in rock. RuthCent_1018 TABLE10 SURFACE WATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Sample Location 15A NCAC 2B Standard for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 ANTIMONY BQL BQL BQL BQL ARSENIC BQL BQL BQL BQL 50.0 BARIUM 47.5 31.3 35.4 40.5 BERYLLIUM BQL BQL BQL BQL 6.5 CADMIUM BQL 0.2 BQL BQL 2.0 CHROMIUM 1.2 1.0 1.3 2.9 50.0 COBALT 2.4 J BQL BQL BQL COPPER BQL BQL BQL 39.0 7.0[1] LEAD BQL BQL BQL BQL 25.0 NICKEL BQL BQL BQL 26.1 88.0 SELENIUM BQL BQL BQL BQL 5.0 SILVER BQL BQL BQL BQL 0.06[1] THALLIUM BQL BQL BQL BQL VANADIUM 1 1.4 0.7 2.1 1.2 ZINC 1 5.4 8.1 9.4 10.0 50.0[1] Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • * - Standard not established Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • [11 - Action Level RuthCent_1018 TABLE 11 SURFACE WATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameters Sample Location 15A NCAC 2B Standard for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 1,1,1,2-TETRACHLOROETHANE BOL BOL BOL BOL 1,1,1-TRICHLOROETHANE BOL BOL BOL BOL 1,1,2,2-TETRACHLOROETHANE BOL BOL BOL BOL 1,1,2-TRICHLOROETHANE BOL BOL BOL BOL 1,1-DICHLOROETHANE BOL BOL BOL BOL 1,1-DICHLOROETHENE BOL BOL BOL BOL 1,2,3-TRICHLOROPROPANE BOL BOL BOL BOL 1,2-DIBROMO-3-CHLOROPROPANE BOL BOL BOL BOL 1,2-DIBROMOETHANE BOL BOL BOL BOL 1,2-DICHLOROBENZENE BOL BOL BOL BOL 1,2-DICHLOROETHANE BOL BOL BOL BOL 1,2-DICHLOROPROPANE BOL BOL BOL BOL 1,4-DICHLOROBENZENE BOL BOL BOL BOL 1,4-DIOXANE 2.7 BOL BOL 2.4 2-BUTANONE BOL BOL BOL BOL 2-HEXANONE BOL BOL BOL BOL 4-METHYL-2-PENTANONE BOL BOL BOL BOL ACETONE BOL BOL BOL BOL ACRYLONITRILE BOL BOL BOL BOL BENZENE BOL BOL BOL BOL BROMOCHLOROMETHANE BOL BOL BOL BOL BROMODICHLOROMETHANE BOL BOL BOL BOL BROMOFORM BOL BOL BOL BOL BROMOMETHANE BOL BOL BOL BOL CARBON DISULFIDE BOL BOL BOL BOL CARBON TETRACHLORIDE BOL BOL BOL BOL CHLOROBENZENE BOL BOL BOL BOL CHLOROETHANE BOL BOL BOL BOL CHLOROFORM BOL BOL BOL BOL CHLOROMETHANE BOL BOL BOL BOL CIS-1,2-DICHLOROETHENE BOL BOL BOL BOL CIS-1,3-DICHLOROPROPENE BOL BOL BOL BOL DIBROMOCHLOROMETHANE BOL BOL BOL BOL DIBROMOMETHANE BOL BOL BOL BOL ETHYLBENZENE BOL BOL BOL BOL IODOMETHANE BOL BOL BOL BOL METHYLENE CHLORIDE BOL BOL BOL BOL STYRENE BOL BOL BOL BOL TETRACHLOROETHENE BOL BOL BOL BOL TOLUENE BOL BOL BOL BOL 11.0 TOTAL XYLENES BOL BOL BOL BOL TRANS-1,2-DICHLOROETHENE BOL BOL BOL BOL TRANS-1,3-DICHLOROPROPENE BOL BOL BOL BOL TRANS-1,4-DICHLORO-2-BUTENE BOL BOL BOL BOL TRICHLOROETHENE BOL BOL BOL BOL TRICHLOROFLUOROMETHANE BOL BOL BOL BOL VINYL ACETATE BOL BOL BOL BOL VINYL CHLORIDE BOL BOL BOL BOIL Notes: • All results in parts per billion (ppb) • BOL - Below Method Detection Limit • ` - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards RuthCent_1018 TABLE 12 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MWA 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-IOC 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard 1,2-DICHLOROPROPANE 20.3 0.6 ' 1,4-DICHLOROBENZENE 6.9 6.0 ' 1,4-DIOXANE 22.9 108.0 5.3 7.0 10.8 4.8 3.0 ' BENZENE 1.2 1.0 1.0 ' CHLORIDE '284;000.0 250,000.0 ' CHROMIUM 26.3• 23.5 • 67.2 10.0 ' COBALT 1.2„ 1.3 44.5 .1.9„ 17A„ , 10.7 - 27.1 12.5. , 28.4 - 4.3 4.7 , 1.0 IRON 1,060.0 1,060.0 11190.0 3,790.0 734.0 3,890.0 4,500.0 2,570.0 637.0 1,020.0 300.0 ' LEAD 23.7 15.0 ' MANGANESE 275.0 1,620.0 1,060.0 66.3 50.0 ' TETRACHLOROETHENE 1.3 0.7 ' THALLIUM -. 34.3 4.4 - .14.2, 3A , -2.7 „ 0.28 VANADIUM 2.1 2.3 8.6 5.9 1.� 53.8 42;8 0.9 1360 9.5 2.9 24 2j 0.3 VINYLCHLORIDE 10.4 0.4 1 0.7 0.2 1 0.03 ' Notes: • All results in parts per billion (ppb) • ' - Standard not established Shaded ., I cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • NS - Not Sampled RuthCeM_1018 TABLE13 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA OCTOBER 1-8, 2018 Parameter Sample Location 15A NCAC 2B Standard for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 MERCURY 0.04 0.05 0.012 COPPER 39.0 7.01 11 Notes: • All results in parts per billion (ppb) • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • �11- Action Level • NS - Not sampled. Dry location RuthCent_1018 APPENDIX E FIGURE 2 AND TABLES FROM THE MAY 2019 SEMI-ANNUAL SAMPLING REPORT BY SCARLETT GEOPHYSICAL CONSULTING P.C. l� x ��� #ea.s w � �J� i � �� � �,,�� `•--r' sic � ►.i � J fro ,,e S C PA�101 �2 ti>a f i O L �' �' ''° ----- ri, d ` I ' -- CENTRAL SANITARY LANDFILL P OX. E W FOO IN� E PAN IOAI- ��'? ,� �--" >." R.UTHERFORD COUNTY NORTH aCAROLIN 4 _... _._� ,,..� O S > , OQ�C C Y RDS C ATY} slat TOWN OF RUTNERFORDTON i % I x x°?. SlT1tE�PI�ICAV5l�T11"PC WASTEWATER TREATMENT ,x, _ - . FACILITY -ter •iY , -' �"' ki " '� » '`' GROUNDWATER CONTOUR MAP' ` ART 10 .Ya .-.....__ 0 q,'ti®� EOM" MAY 7-15, 2019 .,;......_ ........- �0 --^ .,. :r q, `�, FIGURE 2 al x !! 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C'•� / '� � � 1. , 1 x � / �'a.►"�6 � 1 '�, rtr!lllilt•�'pi,'. tt. r.sry� r � , � if a0 +� , i s1P1 9/ � It•ii � � +r'ir#i�p,i�i�''rtt ata..'r'� 1 r � '/ � ®$ � �� D Q �rf � � i x � f � !'rir' Js�l 9 t� ' r � //f//// jf/ `fj � �' � '1J � f• /� IN a,t f,•jr 9, ,� ,� 'RE ND I LI t i q \ L / Poo ia?• / /"� 1- !70 x� f r i r a ,f "\ l , t r-' -�• _ IV �. � MRING WELL ��• 1 �� ! � � / # � J � r �b� � 'rr �'�� p S q• i1'� �°{ .�' ". � f / � 4 � 1 i i �l� �rr/'�� �, !>� 1. � ��'=•,`�.,�...�.r,'� ` i ��A1 D V �r f -''' ! _ '� `r i °t \_ / �° ;'`— ., • s SURFACE WATER SAMPLE LOCATIaA3 ,11, A ID GARRETT & ASSOCIATES,loll, GROUNDWATER MONITORING P'� , � ,��,;,�/ ;� � � ,,- � .-- ,, `�� � � GROUNDWATER CONTOUR 920 WITH PHASE I CDLF AMENDMENTS :\``'-�,;;% ` � -� �----�,� � ��.% , � 1'' � � � � GROUNDWATER Flow DIRECTION-� '` S��SHEET 20, DRAWING NO. .r ;� � 0 20o. a�oo. goo, <kAS T � z ~ goo' TABLE 1 SUMMARY OF MONITORING WELL DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA Well No. Elevation (ft) Depth of Well (ft) Static Water Levels3 Oct 2-5, 2017 May 10-17, 2018 Oct 1-8, 2018 May 7-15, 2019 Land Surface Top of Casing' Top of Screen Bottom of Screen Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) Depth (ft) Elevation (ft) 8103-MW-2 995.43 995.51 945.43 935.43 60.0 47.27 948.24 46.89 948.62 46.20 949.31 32.05 963.46 8103-MW-3 859.62 860.28 822.62 812.62 47.0 34.61 825.67 32.09 828.19 1 33.23 827.05 30.17 830.11 8103-MW-4 849.72 851.03 809.72 799.72 50.0 36.48 814.55 31.91 819.12 34.82 816.21 28.49 822.54 8103-MW-6 833.43 834.90 810.93 795.93 37.5 32.33 802.57 31.36 803.54 31.12 803.78 26.57 808.33 8103-MW-7 890.51 892.70 851.51 836.51 54.0 37.33 855.37 34.93 857.77 35.88 856.82 33.20 859.50 8103-MW-8 857.86 860.31 828.36 813.36 44.5 44.26 816.05 39.89 820.42 42.56 817.75 35.98 824.33 8103-MW-9 864.97 867.25 842.47 827.47 37.5 35.65 831.60 34.02 833.23 34.64 832.61 29.04 838.21 8103-MW-10A 834.73 837.23 743.73 733.73 101.0 5.665 831.575 6.475 830.765 6.725 830.515 5.745 831.495 8103-MW-10B 834.50 836.15 802.50 797.50 37.0 10.01 826.14 9.11 827.04 9.51 826.64 7.86 828.29 8103-MW-10C 834.50 836.19 823.50 818.50 16.0 9.78 826.41 8.88 827.31 9.29 826.90 7.82 828.37 8103-MW-10D 834.73 837.23 778.73 768.73 66.0 11.16 826.07 9.96 827.27 9.44 827.79 8.34 828.89 8103-MW-11A 815.39 817.18 780.39 770.39 45.0 9.22 807.96 8.26 808.92 8.55 808.63 7.40 809.78 8103-MW-11B 816.32 817.72 806.32 796.32 20.0 10.31 807.41 9.45 808.27 9.42 808.30 8.85 808.87 8103-MW-12 884.33 886.68 849.33 834.33 50.0 38.90 847.78 32.27 854.41 38.10 848.58 34.55 852.13 8103-MW-13 960.80 962.90 887.80 872.80 88.0 82.50 880.40 81.21 881.69 80.26 882.64 70.04 892.86 8103-MW-14 867.08 869.48 849.68 834.68 32.4 24.80 844.68 20.67 848.81 27.18 842.30 18.53 850.95 8103-MW-15 887.58 889.54 1 839.58 849.58 1 38.0 35.38 854.16 29.10 860.44 32.40 857.14 27.18 862.36 Notes Elevations for 8103-MW-2 through 8103-MW-11 B determined by survey: Burnt Chimney Surveying, Forest City, NC, December 1998, elevations for 8103-MW-12 and 8103-MW-13 provided by David Garrett P.G., P.E., Engineering and Geology, Raleigh, NC, 2002 and 1999, respectively 2 Depth to groundwater measured by Scarlett Geophysical Consulting, P.C. 3 Water levels taken from top of casing 4 Depth of well measured from land surface 5 Does not represent static water level. Well has very slow recharge rate (less than 0.03 gallons per day) RuthCent_0519 TABLE 2 GROUND AND SURFACE WATER SAMPLING FIELD DATA CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15. 2019 Parameter Sample Location 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10A 8103-MW-10B Temperature 17.09°C 17.7°C 15.76°C 17.85°C 15.6°C 18.22°C 16.11°C NS 16.7°C Conductivity 82.0 pmhos/cm 941 pmhos/cm 387 pmhos/cm 1210 pmhos/cm 1016 pmhos/cm 185 pmhos/cm 28.0 pmhos/cm NS 112.0 pmhos/cm pH 9.47 6.44 6.74 7.48 6.73 6.61 6.31 NS 6.16 ORP 96 mV NA 194 mV -88 mV NA 234 mV 233 mV NS NA DO 1.49 mg/I NA 0.00 mg/I 0.00 mg/I NA 1.59 mg/I 0.52 mg/I NS NA Turbidity 31.9 NTU NA 3.3 NTU 0.0 NTU NA 7.0 NTU 0.0 NTU NS NA Parameter Sample Location 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 Temperature 14.8°C 16.80°C 15.33°C 14.2°C 16.7°C 16.9°C 16.0°C 14.7°C 15.9°C Conductivity 90.8 pmhos/cm 267 pmhos/cm 805 pmhos/cm 314 mhos/cm 720 pmhos/cm 206 pmhos/cm 191.6 pmhos/cm 185.8 pmhos/cm 120.6 pmhos/cm pH 5.95 7.09 6.38 6.05 6.55 5.75 5.85 6.11 7.00 ORP NA 39 mV 9 mV NA NA NA NA NA NA DO NA 0.00 mg/I 0.00 mg/I NA NA NA NA NA NA Turbidity NA 0.0 NTU 2.1 NTU NA NA NA NA NA NA Parameter Sample Location 8103-SW-3 8103-SW-4 8103-SW-5A Temperature 18.6°C 15.4°C 15.8°C Conductivity 70.9 pmhos/cm 48.6 pmhos/cm 72.3 pmhos/cm pH 7.16 7.14 6.85 ORP NA NA NA DO NA NA NA Turbidity NA NA NA NS - Not sampled NA - Not analyzed RuthCent_0519 TABLE 3 GROUNDWATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 C CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter Well Number 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B ANTIMONY BQL BQL BQL BQL BQL BQL BQL BQL 1.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 BARIUM 19.30 180.00 101.00 227.00 130.00 111.00 61.70 265.00 700.0 BERYLLIUM BQL BQL BQL BQL BQL BQL BQL 0.46 4.0 CADMIUM BQL 0.36 0.47 0.43 0.62 0.25 BQL 0.38 2.0 CHROMIUM 0.92 1.24 1.36 4.28 2.95 4.22 2.10 28.00 10.0 COBALT BQL 1.32 BQL j 30.70 2.98 BQL BQL 15.60 * 1.0 COPPER 4.48 4.45 6.55 5.66 12.60 4.24 BQL 20.80 1,000.0 LEAD BQL BQL 2.82 BQL BQL BQL BQL 10.40 15.0 NICKEL BQL 1.33 0.77 7.53 4.76 0.87 BQL 14.90 100.0 SELENIUM BQL BQL BQL BQL BQL BQL BQL BQL 20.0 SILVER 1.76 BQL BQL BQL BQL BQL BQL BQL 20.0 THALLIUM BQL BQL BQL 30.10 2.70 BQL BQL BQL 0.28 VANADIUM 0.46 2.01 4.98 1.35 3.43 3.54 BQL 49.20 0.3 ZINC 13.80 11.00 21.40 19.20 26.90 29.10 13.50 129.00 1,000.0 Parameter Well Number 15A NCAC 2L Standard for Class GAGroundwater NC Groundwater Protection Standard 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 ANTIMONY 1.91. BQL BQL BQL BQL 2.76 BQL BQL * 1.0 ARSENIC BQL BQL BQL BQL BQL BQL BQL BQL 10.0 BARIUM 306.00 201.00 210.00 344.00 163.00 213.00 103.00 120.00 700.0 BERYLLIUM 0.30 BQL BQL 1.32 BQL BQL BQL BQL 4.0 CADMIUM BQL 0.22 0.39 0.28 0.68 0.32 BQL 0.45 2.0 CHROMIUM 15.00 0.94 4.90 26.00 5.15 2.33 1.83 3.62 10.0 COBALT 15.50 27.50 16.90 13.00 7.57 6.46 1.30 2.16 1.0 COPPER 11.60 3.89 6.01 16.10 15.90 11.30 5.75 6.62 1,000.0 LEAD 6.37 BQL BQL 11.80 2.64 5.91 BQL 3.52 15.0 NICKEL 9.92 4.17 6.31 17.20 3.14 5.14 1.02 1.36 100.0 * SELENIUM BQL BQL BQL BQL BQL BQL BQL BQL 20.0 SILVER BQL BQL BQL BQL BQL BQL BQL BQL 20.0 THALLIUM BQL 4.63 21.80 BQL 18.60 8.81 BQL BQL * 0.28 VANADIUM 30.20 BQL 2.23 52.20 5.94 1.94 4:86 6.74 * 0.3 ZINC 70.40 9.60 15.30 76.80 22.20 23.40 15.30 17.80 1,000.0 Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit • NS - Not Sampled • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCent_0519 TABLE 4 GROUNDWATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GA Groundwater Standard 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 ' 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2 0.18 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 1,1-DICHLOROETHANE BQL BQL BQL BQL 1.60 BQL BQL BQL BQL 1.6 BQL BQL BQL BQL BQL BQL 6.0 ' 1,1-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2 BQL BQL BQL BQL BQL BQL 7.0 ' 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 ' 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL I BQL BQL BQL 0.04 ' 1,2-DIBROMOETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 ' 1,2-DICHLOROBENZENE BQL BQL BQL 0.6 BQL BQL BQL BQL BQL 0.2 0.3 BQL BQL BQL BQL BQL 20.0 ' 1,2-DICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 ' 1,2-DICHLOROPROPANE BQL BQL BQL BQL BQL BQL 14)7 BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 ' 1,4-DICHLOROBENZENE BQL BQL 0.4 0.8 BQL BQL BQL BQL BQL 2.1 4.8 0.6 BQL BQL BQL BQL 6.0 ' 1,4-DIOXANE BQL 3.5 BQL 17.3 BQL BQL BQL 4.2 BQL BQL BOIL 4.5 BQL BQL BQL BQL 3.0 ' 2-BUTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4,000.0 ' 2-HEXANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 40.0 4-METHYL-2-PENTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 560.0 ACETONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 6000.0 ' ACRYLONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' BENZENE BQL BQL BQL 1.0 0.3 BQL BQL BQL BQL 1.1 0.4 BQL BQL '1.3 BQL BQL 1.0 ' BROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BROMODICHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 ' BROMOFORM BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 ' BROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' 10.0 CARBON DISULFIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 700.0 ' CARBON TETRACHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 ' CHLOROBENZENE BQL BQL BQL 35.40 0.30 BQL BQL BQL BQL 2.0 9.4 0.7 0.2 BQL BQL BQL 50.0 ' CHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BQL BQL 1.1 BQL BQL 3,000.0 ' CHLOROFORM BQL BQL BQL BQL BQL BQL 0.2 BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ' CHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 ' CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL 0.5 BQL 12.3 0.2 BQL BQL 0.8 0.5 BQL 70.0 ' CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 ' DIBROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.41 DIBROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ETHYLBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ..0 ' METHYL IODIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' METHYLENE CHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 5.0 ' STYRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 ' TETRACHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.8 BQL BQL BQL BQL BQL BQL 0.7 ' TOLUENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 ' TOTAL XYLENES BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.7 BQL BQL 500.0 ' TRANS-I,2-DICHLOROETIENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 ' TRANS-I,3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 ' TRANS-I,4-DICHLORO-2-BUTENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ' TRICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.70 BQL BQL BQL QL BQL BQL BQL BQL BQLBQL BQL BQL BQL B BQL BQL BQL BQLTRICHLOROFLUOROMETHANE BQL ,3.0 2000.0 ACETATE BQL BQL BQL BQL BQL BQL BQL BQL BQL QVINYL BL BQL BQL BQL BQL+ BOIL B 88'' .0 CHLORIDE BQL BQL BOIL BOIL QL BQL 0.03VINYL ' All results in parts per billion(ppb) BQL - Below Method Detection Limit B - Lab blank contamination NS - Not Sampled Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCent_0519 TABLE 5 GROUNDWATER SAMPLING RESULTS APPENDIX II TRIGGERED CONSTITUENTS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 SW-846 Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection Parameter Method 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B GAGroundwater Standard 1,3-Dichlorobenzene 8260 BQL 7.0 BQL BQL BQL BQL BQL BQL BQL BQL 200.0 1,3-Dichloro ro ane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Dichlorodifluoromethane 8260 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1,000.0 4,4'- DDD 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 4,4'- DDT 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 al ha-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.006 beta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 delta-BHC 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 Endrin 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.0 amma-BHC Lindane 8081 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.03 Mercury 1 7470 0.11 0.12 BQL 0.07 0.02 0.05 0.01 0.01 0.05 0.03 1.0 Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit * - Standard not established Shaded, cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards NA - Not analyzed RuthCent_0519 TABLE 6 GROUNDWATER SAMPLING RESULTS APPENDIX II INORGANIC CONSTITUENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2018 Parameter Laboratory 15A NCAC 2L Standard for Class NC Groundwater Protection Method 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GA Groundwater Standard ANTIMONY SW 846 6010 BQL BQL BQL BQL BQL BQL BQL BQL 2.76 BQL BQL 1.0 ARSENIC SW 846 6010 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.0 BARIUM SW 846 6010 19.30 180.00 101.00 227.00 130.00 111.00 61.70 163.00 213.00 103.00 120.00 700.0 BERYLLIUM SW 846 6010 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 CADMIUM SW 846 6010 BQL 0.36 0.47 0.43 0.62 0.25 BQL 0.68 0.32 BQL 0.45 2.0 CHROMIUM SW 846 6010 0.92 1.24 1.36 4.28 2.95 4.22 2.10 5.15 2.33 1.83 3.62 10.0 COBALT SW 846 6010 BQL 1.32 BQL 36.70 2.98 BQL BQL 7.57 8.40 1.30 2.10 1.0 COPPER SW 8466010 4.48 4.45 6.55 5.66 12.60 4.24 BQL 15.90 11.30 5.75 6.62 1,000.0 CYANIDE EPA 335.2 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 LEAD SW 846 6010 BQL BQL 2.82 BQL BQL BQL BQL 2.64 5.91 BQL 3.52 15.0 MERCURY SW 846 7470 BQL 0.07 0.11 0.12 BQL 0.07 0.02 0.02 0.02 BQL 0.12 1.0 NICKEL SW 846 6010 BQL 1.33 0.77 7.53 4.76 0.87 BQL 3.14 5.14 1.02 1.36 100.0 SELENIUM SW 8466010 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 20.0 SILVER SW 846 6010 1.76 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 20.0 SULFIDE EPA376.1 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL THALLIUM SW 846 6010 BQL BQL BQL 30.10 2.70 BQL BQL .18.60 8.81 BQL BQL 0.28 TIN SW 846 6010 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2,000.0 VANADIUM SW 846 6010 0.46 2.01 4.98 1.35 3.43 3.54 BQL 5.84 1.94 4.86 6.74 * 0.3 ZINC SW 846 6010 13.60 11.00 21.40 19.20 26.90 29.10 13.50 22.20 23.40 15.30 17.80 1,000.0 Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit * - Standard not established Shaded cells denote concentrations that equal or exceed the 2L or Groundwater Protection Standards NS - Not Sampled NA - Not Analyzed RuthCent_0519 TABLE 7 GROUNDWATER SAMPLING RESULTS APPENDIX II VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameters Sample Locations 15A NCAC 2L Standard for Class NC Groundwater Protection Standard 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater 1,1,12-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 1.0 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 1,1,22-TETRACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.2 0.18 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 0.6 1,1-DICHLOROETHANE BQL BQL BQL BQL 1.6 BQL BQL BQL BQL BQL BQL 6.0 1,1-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 7.0 1,1-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 123-TRICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 1,2,4-TRICHLOROBENZENE' BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 70.0 12-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.04 12-DIBROMOETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 12-DICHLOROBENZENE BQL BQL BQL 0.6 BQL BQL BQL BQL BQL BQL BQL 20.0 12-DICHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 12-DICHLOROPROPANE BQL BQL BQL BQL BQL BQL 14.7 BQL BQL BQL BOL 0.6 13-DICHLOROBENZENE BQL BQL BQL 7.0 BQL BQL BQL BQL BQL BQL BOIL 200.0 13-DICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BOIL * 14-DICHLOROBENZENE BQL BQL 04 6.8 BQL BQL BQL BQL BQL BQL BOIL 6.0 22-DICHLOROPROPANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BOIL 2-BUTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BOIL 4000.0 2-HEXANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BOIL 40'" .0 4-METHYL-2-PENTANONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 560.0 ACETONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 6000.0 ACETONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 42.0 ACROLEIN BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 4.0 ACRYLONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ALLYL CHLORIDE 3-chloo ro ene BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BENZENE BQL BQL BQL 1.0 0.3 BQL BQL BQL 1.3 BQL BQL 1.0 BROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BROMODICHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.6 BROMOFORM BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 BROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 10.0 DISULFIDE BQL BQL BQL BQL BQL BQL BQL BQLCARBON BQL BQL BQL 700.0 CARBON TETRACHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 CHLOROBENZENE BQL BQL BQL 35.4 0.3 BQL BQL 0.2 BQL BQL BQL 50.0 CHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL 11 BQL BQL 000.0 BQL BQL BQL BQL BQL BQL 0.2 BQL BQL BQL BQL 70.0CHLOROFORM CHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 " CHLOROPRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL CIS-I2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL 0.8 0.5 BQL 70.0 CIS-I3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 DIBROMOCHLOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.41 DIBROMOMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 70.0 DICHLORODIFLOUROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL 4.8 BQL BQL 1000.0 ETHYLBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 ETHYL METHACRYLATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL ISOBUTYL ALCOHOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHACRYLONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHYL IODIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHYL METHACRYLATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 25.0 METHYLENE CHLORIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQLki PROPIONITRILE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQLSTYRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQLTETRACHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL TOLUENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 600.0 " TOTALXYLENES BQL BQL BQL BQL BQL BQL BQL BQL 0.7 BQL BQL 500.0 " TRANS-I2-DICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 " TRANS-I3-DICHLOROPROPENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 TRANS-I4-DICHLORO-2-BUTENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL TRICHLOROETHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 3.0 TRICHLOROFLUOROMETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2000.0 VINYL ACETATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 88.0 VINYL CHLORIDE BQL BQL BQL 1.1 BQL BQL BQL BQL 0.3 BQL BQL 0.03 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • 'Analyzed by SW-846 Method 8270 • NS - Not Sampled RuthCent_0519 TABLE 8 GROUNDWATER SAMPLING RESULTS APPENDIX II SEMI -VOLATILE CONSTITUENTS BY SW-846 METHOD 8270 CENTRAL SANITARY LANDFILL (# 81-03), RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter 15A NCAC 2L Standard for Claw NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MW4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard 000-TRIETHYL PHOSPHOROTHIOATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 00-DIETHYL o-2-PYROZINYL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1245-TETRACHLOROSENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.0 124-TRICHLOROBENZENE BQL BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL 70.0 70.0 14-NAPHTHOQUINONE BQL SOL BQL BQL BQL SOL BQL SOL BQL BQL BQL 1-NAPHTHYLAMINE BQL SOL BQL BQL BQL SOL BQL SOL SOL BQL BQL 2346-TETRACHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 245-TRICHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 63.0 246-TRICHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4.0 24-DICHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 8 0.9`'""""""" 24-DIMETHYLPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 100.0 24-DINITROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 24-DINITROTOLUENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 26-DICHLOROPHENOL BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 26-DINITROTOLUENE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 2-ACETYLAMINOFLUORENE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 2-CHLORONAPHTHALENE BQL SOL BQL BQL BQL SOL BQL SOL SOL BQL BQL BQL BQL BQL BQL2-CHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL 0.4 2METHYLNAPHTHALENE -- BQL BOIL BQL BQL BQL BQL BQL BQL BQL BQL BQL 30.0 2METHYLPHENOL O-CRESOL BQL BOIL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4000 2NAPHTHYLAMINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2-NITROANILINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2-NITROPHENOL BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL BQL 3 & 4-METHYLPHENOL M &P-CRESOL BQL SOL BQL 2.1 BQL BQL BQL BQL 2.9 BQL BQL 400/40 33'-DICHLOROBENZIDINE BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL BQL BQL BQL33'-DIMETHYLBENZIDINE BQL SOL BQL BQL BQL SOL SOL BQL BQL 3-METHYLCHOLANTHRENE BQL SOL BQL BQL BQL SOL BQL SOL SOL BQL BQL 3-NITROANILINE BQL SOL BQL BQL BQL BQL BQL BQL BQL BQL " 4,6-DINITRO-o-CREOSOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " 4-AMINOBIPHENYL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " 4-BROMOPHENYL PHENYL ETHER BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " 4-CHLORO-3-METHYLPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " 4-CHLOROANILINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " 4-CHLOROPHENYL PHENYL ETHER BQL BQL BQL BQL BQL SOL BQL SOL SOL BQL BQL 4-NITROANILINE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 4-NITROPHENOL BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 5-NITRO-0-TOLUIDINE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BBQL 712-DIMETHYLBENZAANTHRACENE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL SOL ACENAPHTHENE BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL BQLL 850.0.0 ACENAPHTHYLENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 ACETOPHENONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 700 ANTHRACENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2000.0 BENZO A NTHRACENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.05 BENZO A PYRENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 BENZO B FLUORANTHENE BQL SOL BQL SOL BQL SOL BQL SOL SOL BQL BQL 0.05 BENZO G HIPERYLENE BQL BQL SOL BQL SOL BQL SOL BQL BQL 200.0 BENZO KFLUORANTHENE BQL BQL BQL BQL BOIL SOL BQL SOL SOL BQL SOL0.5 BENZYL ALCOHOL BQL SOL BQL BQL BOIL SOL BQL SOL SOL BQL BQL 700.00 BIS(2-CHLORO-I-METHYLETHYL)ETHER BQL BQL BQL BQL BOIL BQL BQL BQL SOL BQL BQL BIS2-CHLOROETHOX METHANE BQL BQL BQL BQL BOIL BQL BQL BQL SOL BQL BQL BIS2-CHLOROETHYLETHER BQL BQL BQL BQL BOIL BQL BQL BQL SOL BQL BQL 0.031 BIS2-ETHYLHEXYLPHTHALATE BQL BQL BQL BQL BQL BQL BQL SOL BQL BQL3.0 L BUYSENZYL PHTHALATE BQL BQL BQL BQL BOIL BQL BQL BQL SOL BQL BQL 1,000.0 CHLOROBENZILATE BQL BQL BQL BQL SOL BQL BQL BQL SOL BQL CHRYSENE BQL BQL BQL BQL BQL BQL BQL SOL BQL BQQL DIALLATE TOTAL BQL BQL BQL BQL SOL BQL BQL BQL BQL BQL I BQL RuthCent_0519 TABLE 8(CONT.) Parameter 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGmundwater Standard DIBENZ AH NTHRACENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.005 DIBENZOFURAN BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 28.0 DIETHYL PHTHALATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 6000.0 DIMETHYL PHTHALATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL DI-N-BUTYLPHTHALATE SOL BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL 700.0 DI-N-OCTYLPHTHALATE SOL BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL 100.0 DIPHENYLAMINE SOL BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL ETHYL METHANESULFONATE SOL BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL FLUORANTHENE SOL BQL SOL BQL BQL BQL BQL BQL BQL BQL BQL 300.0 FLUORENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 300.0 HEXACHLOROSENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.02 HEXACHLOROBUTADIENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.4 0.44 HEXACHLOROCYCLOPENTADIENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 50.0 HEXACHLOROETHANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.5 HEXACHLOROPROPENE SOL BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL INDENO 123-CD PYRENE SOL BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL 0,05 " ISODRIN SOL BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL " ISOPHORONE SOL BQL SOL BQL SOL BQL BQL BQL BQL BQL BQL 40.0 ISOSAFROLE SOL BQL SOL BQL SOL BQLTBO BQL BQL BQL BQL m-DINITROSENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHAPYRILENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHYL METHANESULFONATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL N-NITROSODIETHYLAMINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL N-NITROSODIMETHYLAMINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.0007 N-NITROSODI-N-BUTYLAMINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " N-NITROSODI-N-PROPYLAMINE BQL BQL BQL BQL SOL BQL BQL SOL BQL BQL " N-NITROSODIPHENYLAMINE SOL BQL SOL BQL SOL BQL BQL SOL BQL BQL " N-NITROSOMETHYLETHYLAMINE SOL BQL SOL BQL SOL BQL BQL SOL BQL BQL " N-NITROSOPIPERIDINE SOL BQL SOL BQL SOL BQL SOL BQL SOL BQL BQL " N-NITROSOPYRROLIDINE SOL BQL SOL BQL SOL BQL SOL BQL BQL BQL BQL " NAPHTHALENE BQL BQL BQL BQL BQL BQL BQL BQL 7.1. BQL BQL 6.0 NITROBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " O-TOLUIDINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL " P-DIMETHYLAMINOAZOBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PENTACHLOROBENZENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PENTACHLORONITROBENZENE BQL BQL BQL BQL BQL BQL SOL BQL SOL BQL BQL PHENACETIN SOL BQL SOL BQL SOL BQL SOL BQL SOL BQL BQL PHENANTHRENE SOL BQL BQL BQL BQL BQL eQL BQL BQL BQL BQL 2W.0 PHENOL BQL BQL BQL BQL BQL BQL eQL BQL BQL BQL BQL 30.0 p-PHENYLENEDIAMINE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PRONAMIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PYRENE BQL I BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 200.0 SAFROLE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL sym-TRINITROBENZENE BQL I BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit '-Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards •'-4,6-Dinitroo-creosole=4,6-Dinitro-2-methylphenol=2-Methy1-4,6-din-phenol - Bis (2-chbro-1-methylethyl) ether = 2,2-Oxybis(1-chloropropane) = Bis (2-chloroisopropyp ether 3 - Butyl ben" phthalate = Benzylbutylphthalate m-Dinitrobenzene = 1,3 Dinitrobenzene s - p-Phenylenediamine = 1,4 Phenylenediamine s - sym-Tdnkmbenzene = 1,3,5-Trinitrobenzene NS - Not Sampled RuthCent_0519 TABLE 9 GROUNDWATER SAMPLING RESULTS APPENDIX II ORGANOPHOSPHORUS PESTICIDES BY SW-846 METHOD 8270 APPENDIX II HERBICIDES BY SW-846 METHODS 8151A and 8270D CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 15A NCAC 2L NC Groundwater PARAMETER WELL NUMBER Standard for Class Protection 8103-MW-2 I 8103-MW-3 I 8103-MW-4 I 8103-MW-6 I 8103-MW-7 I 8103-MW-8 I 8103-MW-9 I 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GAGroundwater Standard PESTICIDES 0,0,0-TRIETHYL PHOSPHOROTHIOATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL DIMETHOATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL DISULFOTON BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 FAMPHUR BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL KEPONE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL METHYL PARATHION BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PARATHION BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL PHORATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 1.0 THIONAZIN BQL BQL BQL BQL I BQL BQL I BQL BQL I BQL BQL I BQL HERBICIDES 2,4,5-T BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2,4,5-TP SILVEX BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 50.0 2,4-D BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 70.0 DINOSEB BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL TO PENTACHLOROPHENOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.3 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • " Shaded ' - cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • ' - Thionazin = 0,0-Diethyl o-2-pyrozinyl RuthCent_0519 TABLE 10 GROUNDWATER SAMPLING RESULTS APPENDIX II PESTICIDES/PCBS BY SW-846 METHOD 8081/8082 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 PARAMETER WELL NUMBER 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MW-4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GA Groundwater Standard 4,4'-DDD BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 4,4'-DDE BOL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 4,4'-DDT BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.1 ALDRIN BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 0.002 ALPHA-BHC BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 0.006 AROCLOR 1016 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.09 AROCLOR 1221 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.09 AROCLOR 1232 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.09 AROCLOR 1242 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 0.09 AROCLOR 1248 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.09 AROCLOR 1254 BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.09 AROCLOR 1260 BQL BQL BQL BQL BQL BQL BQL BQL BOL BQL BOL 0.09 BETA-BHC BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 CHLORDANE TOTAL BQL BQL BQL BQL BOL BQL BQL BQL BQL BQL BQL 0.1 DELTA-BHC BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.019 DIELDRIN BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.002 ENDOSULFANI BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 40.0 ENDOSULFAN II BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 42.0 ENDOSULFAN SULFATE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL * 40.0 ENDRIN BQL BQL BQL BQL BQL BQL BQL BQL BOL BQL BOL 2.0 ENDRIN ALDEHYDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 2.0 GAMMA-BHC LINDANE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BOL 0.03 HEPTACHLOR BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.008 HEPTACHLOR EPDXIDE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.004 METHOXYCHLOR BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 40.0 TOXAPHENE BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL 0.03 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • * - Standard not established • Shaded Cells' ' ' denote concentrations that equal or exceed 2L or Groundwater Protection Standards • NS - Not Sampled RuthCent_0519 TABLE 11 GROUNDWATER SAMPLING RESULTS MONITORED NATURAL ATTENUATION PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 8103-MW-2 8103-MW-4 8103-MW-6 8103-MW-8 8103-MW-9 8103-MW-10D 8103-MW-11A ACETIC ACID AM23G BQL BQL 1,900 u /L BQL BQL BQL BQL ALKALINITY SM 2320B 44,200 ug/L 220,000 ug/L 486,000 ug/L 21,600 ug/L 13,500 ug/L 131,000 ug/L 421,000 ug/L BOD SM 5210B BQL BQL 4,230 u /L BQL BQL BQL BQL BUTYRIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL CARBON DIOXIDE SM 4500 CO2 C 1,760 u /L 156,000 u /L 380,000 u /L 58,100 u /L 71,300 u /L 110,000 u /L 347,000 u /L CHLORIDE SM 4500 Cl C 5,700 ug/L 7,600 ug/L 137,000 ug/L 48,900 ug/L 7,120 ug/L 12,800 ug/L 40,800 ug/L 250,000.0 COD EPA 410.4 5,000 u /L BQL 45,000 u /L BQL BQL BQL 12,000 u /L ETHANE AM20GAX BQL BQL 0.26 ug/L BQL BQL BQL 0.28 ug/L ETHENE AM20GAX BQL BQL 0.28 u /L BQL BQL BQL 0.20 u /L ' HEXANOIC ACID AM23Gk73 L BQL BQL BQL BQL BQL BQL HYDROGEN AM20GAXnM 42.0 nM 43.0 nM 45.0 nM 43.0 nM 46.0 nM 25.0 u /L i-HEXANOIC ACID AM23GL BQL BQL BQL BQL BQL BQL i-PENTANOIC ACID AM23GL BQL BQL BQL BQL BQL BQL IRON EPA 200.7 /L 912 u /L 9,690u /L 1,010 u /L 66.0 ug/L 796 u /L 4,890 u /L 300.0 LACTIC ACID & HIBA AM23G L BQL BQL BQL BQL BQL BQL METHANE AM20GAX BQL 0.91 ug/L 1,400 ug/L BQL BQL 580 ug/L 670 ug/L NITRATE -NITROGEN SM 4500 NO3 E 165 u /L 60 u /L BQL 975 ug/L 170 ug/L BQL BQL 10,000.0 PENTANOIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL PROPIONOIC ACID AM23G BQL BQL 640 ug/L BQL BQL BQL BQL PYRUVIC ACID AM23G BQL BQL BQL BQL BQL BQL BQL SULFATE SM 4500 SO4 E BQL BQL 13,500 ug/L BQL BQL BQL BQL 250,000.0 SULFIDE EPA 376.1 BQL BQL BQL BQL BQL BQL BQL TOTAL ORGANIC CARBON SM 5310C BQL 1,410 ug/L 15,000 ug/L 1,240 ug/L BQL 1,070 ug/L 5,680 ug/L Notes: • ug/L - micrograms per Liter (ppb) • nM - nano Moles • BQL - Below Method Detection Limit • * - Standard not established • NS - Not sampled • Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards • - Analyzed approximately 2 hours out of hold time RuthCent_0519 TABLE 12 GROUNDWATER AND SURFACE WATER SAMPLING RESULTS C & D PARAMETERS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter Laboratory Method Sample Location 15A NCAC 2L Standard for Class GA Groundwater NC Groundwater Protection Standard 15A NCAC 2B Standard for Class B,C Surface Water 8103-MW-2 8103-MW-3 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5A ALKALINITY SM 2320B 44,200 298,000 304,000 72,900 37,700 22,100 30,400 16,600 7,820 14,300 ALUMINUM SW 846 6010C 325.0 305.0 1,240.0 475.0 1,630.0 3,760.0 761.0 191.0 528.0 666.0 3,500 CHLORIDE SM 4500 Cl C 5,700.0 47,000.0 13,300.0 7,600.0 9,500.0 10,900.0 8,550.0 5,700.0 5,700.0 5,700.0 250,000.0 230,000"' IRON EPA 200.7 730.0 1,060.0 6,620.0 3,670.0 2,050.0 2,690.0 900.00 449.0 511.00 718.00 300.0 1,000' MANGANESE SW 846 6010 11.9 306.0 4,850.0 2,220.0 87.5 133.0 123.0 39.8 16.7 25.1 50.0 MERCURY SW 846 7470 BQL 0.07 0.02 0.02 BQL 0.12 0.04 0.06 0.08 0.03 1.0 0.012 SULFATE SM 4500 SO4 E BQL 43,100 10,300 BQL 83,100 69,500 10,400 BQL BQL BQL 250,000.0 TDS SM 2540 C 131,000 540,000 403000.00 150,000 124,000 135,000 77,000 68,000 42,000 63,000 500,000.0 TETRAHYDROFURAN SW 8468260B BQL BQL BQL BQL BQL BQL BQL BQL BQL BQL Notes: All results in parts per billion (ppb) BQL - Below Method Detection Limit * - Standard/Limit not established NS - Not sampled I'] - Action Level Shaded cells denote, concentrations that equal or exceed 2B Standards, 2L Standards, Groundwater Protection Standards, or Action Levels RuthCent_0519 TABLE 13 SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA 0 r. r. .. r r r: rrr r• r rrr �aaaa��a��aaaaaaaa • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichl..propane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • ' - Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list • 4 - Aluminum added to C&D constituent list RuthCent_0519 TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 04/11/2001 09/12-13/2001 04/03/2002 06/27/2002 10/02/2002 04/02-03/2003 09/03/2003 04/06/2004 10/27/2004 04/05/2005 09/08/2005 04/04-05/2006 10/26-27/2006 5/22-23/2007 10/23-26/2007 05/06-08/2008 09/22-25/2008 8103-MW-2 I I I I I I I I I I I 1 I, MINA I, MNA, C&D I, MNA, C&D 8103-MW-3 I I I I I I I I I I I I I 1 1, C&D 1, C&D 8103-MW-4 I'll 1, 11 t I'll I, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MINA 1, 11(t), MNA 8103-MW-6 I'll 1, 11 t I'll I, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MINA 1, 11(t), MNA 8103-MW-7 I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt I'll I,IIt 8103-MW-8 I'll I, II t I'll I, II t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA 1, 11, MNA I, 11(t), MNA 8103-MW-9 I'll I, II t I'll I, II t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11 t I'll 1, 11(t), MNA I, 11, MNA 1, 11(t), MNA 8103-MW-10A 8103-MW-10B I,IIt) I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-10C I,IIt) I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-10D I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 1,IIt,MNA 1,IIt,MNA 1,111,MNA 8103-MW-11A I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I, lilt), MNA I, lilt), MNA I,11t,MNA 8103-MW-11B I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt I,IIt 8103-MW-12 I I I I I I I I I I I 1 I, C&D I, C&D 8103-MW-13 I I I I I I I I I I I 1 I, C&D I, C&D 8103-MW-14 I, C&D I, C&D 8103-MW-15 1, C&D 1, C&D I - denotes well was sampled for Appendix I constituents on this date II - denotes well was sampled for Appendix II constituents on this date II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date MNA - denotes well was sampled for Monitored Natural Attenuation constituents C&D - denotes well was sampled for Construction and Demolition constituents • ' - Appendix I volatiles only • 2 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • s - 4,4'-DDD and 4,4'-DDT added to Appendix 11 triggered constituent list 4 - Aluminum added to C&D constituent list RuthCent_0519 TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY. NORTH CAROLINA Well 05/18-05/21, 2009 10/07-10/09, 2009 05/17-05/20, 2010 09/20-09/23, 2010 04/25-05/02, 2011 09/27-09/30, 2011 04/30-05/03, 2012 09/25-10/03, 2012 04/15-18/2013 09/23-09/28, 2013 04/28-05/01, 2014 09/29-10/04, 2014 04/27-05/02, 2015 09/28-10/07, 2015 04/26-05/05, 2016 8103-MW-2 I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D° I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&Ds I, MNA, C&D I, MNA, C&D I, MNA, C&D I, MNA, C&D 8103-MW-3 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-4 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-6 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-7 1,11 I, II t 1,11 I, II t 1,11 I, II(t)s, MNA 8103-MW-8 1 I, II, MNA I, 11(t), MNA I, 11(t), MNA I, II, MNA I, II(t)s, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 1 I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-9 I, II, MNA I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t)z, MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA I, II(t), MNA I, II, MNA 8103-MW-10A 8103-MW-10B I, II t I, II t I, II t I, II t I, II t I, II(t)s I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10C I, II t I, II t I, II t I, II t I, II t I, II(t)s I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-10D I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t)s, MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA 8103-MW-11A I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t)s, MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA I, II(t), MNA 8103-MW-11 Bi I, II t I, II t I, II t I, II t I, II t I, II(tp I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) I, II(t) 8103-MW-12 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-13 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-14 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D 8103-MW-15 I, C&D I, C&D I, C&D I, C&D° I, C&D I, C&D I, C&D I, C&D I, C&D I, C&D I, C&Ds I, C&D I, C&D I, C&D I, C&D • I - denotes well was sampled for Appendix I constituents on this date • II - denotes well was sampled for Appendix II constituents on this date • II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date • MNA - denotes well was sampled for Monitored Natural Attenuation constituents • C&D - denotes well was sampled for Construction and Demolition constituents • 1 - Appendix I volatiles only • 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list • 3 - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list • 4 - Aluminum added to C&D constituent list 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list 6 - Tetrahydrofuran added to C&D constituent list RuthCent_0519 TABLE 13 (cont.) SUMMARY OF SAMPLING EVENTS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA Well 09/19-09/22, 2016 05/03-05/09, 2017 10/02-10/05, 2017 05/10-05/17, 2018 10/01-10/08, 2018 05/07-05/15, 2019 8103-MW-2 I, MINA, C&D I, MINA, C&D I, MINA, C&D I, MINA, C&D I, MNA, C&D7 I, II, MINA, C&D 8103-MW-3 I, C&D I, C&D I, C&D I, C&D I, C&D' I, II, C&D 8103-MW-4 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA' I, II, MNA 8103-MW-6 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 I, II, MNA 8103-MW-7 I, II t 1,11 I, II t 1,11 I, II(t) 1,11 8103-MW-8 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA7 I, II, MNA 8103-MW-9 I, 11(t), MNA I, II, MNA I, 11(t), MNA I, II, MNA I, II(t), MNA' I, II, MNA 8103-MW-10A 8103-MW-10B I, II t I, II t I, II t I, II t I, II(t) I, II(t) 8103-MW-10C I, II t I, II t I, II t I, II t I, II(t) I, II(t) 8103-MW-10D I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, 11(t), MNA I, II(t), MNA' I, II(t), MNA 8103-MW-11A I, 11(t), MNA I, 11(t), MINA I, 11(t), MNA I, 11(t), MINA I, II(t), MNA7 I, II(t), MINA 8103-MW-11B I, II t I, II t I, II t I, II t I, II(t) I, II(t) 8103-MW-12 I, C&D I, C&D I, C&D I, C&D I, C&D7 I, II, C&D 8103-MW-13 I, C&D I, C&D I, C&D I, C&D I, C&D7 I, II, C&D 8103-MW-14 I, C&D I, C&D I, C&D I, C&D I, C&D7 I, II, C&D 8103-MW-15 I, C&D I, C&D I, C&D I, C&D I, C&D7 I, II, C&D I - denotes well was sampled for Appendix I constituents on this date II - denotes well was sampled for Appendix II constituents on this date II(t) - denotes well was sampled for Appendix II triggered constituents (1,3-dichloropropane, alpha-BHC, beta-BHC, delta-BHC, dichlorodifluoromethane, endrin, and gamma-BHC) on this date MINA - denotes well was sampled for Monitored Natural Attenuation constituents C&D - denotes well was sampled for Construction and Demolition constituents ' -Appendix I volatiles only 3 - Mercury and endrin aldehyde added to Appendix II triggered constituent list a - 4,4'-DDD and 4,4'-DDT added to Appendix II triggered constituent list "-Aluminum added to C&D constituent list 5 - 1,3-dichlorobenzene added to Appendix II triggered constituent list 6 - Tetrahydrofuran added to C&D constituent list - 1,4-Dioxane added to all sample locations RuthCent_0519 TABLE14 GROUNDWATER FLOW RATES CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Hydraulic Conductivity Effective Velocity Velocity Well No. (cm/sec) Gradient Porosity (cm/sec) (ft/yr) 8103-MW-2 1.3 x 10-5 0.067 .20 4.36 x 10-6 4.52 8103-MW-4 3.7 x 10-6 0.056 .20 1.04 x 10-6 1.08 8103-MW-6 2.4 x 10-5 0.114 .20 1.37 x 10-5 14.12 8103-MW-7 2.9 x 10-6 0.196 .201 2.84 x 10-6 2.94 8103-MW-8 1.6 x 10-4 0.041 .20 3.28 x 10-5 33.97 8103-MW-9 1 2.1 x 10-5 0.038 .20 4.02 x 10-6 4.16 The above results were obtained by using the relation: V = Ki Where K = hydraulic conductivity i = gradient n = effective porosity V = velocity Porosity value may not reflect true nature of fractured bedrock. 8103-MW-7 is screened in rock. RuthCent_0519 TABLE15 SURFACE WATER SAMPLING RESULTS APPENDIX I INORGANIC CONSTITUENTS BY SW-846 METHOD 6010 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter Sample Location 15A NCAC 213 Standard for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5A ANTIMONY BQL BQL BQL BQL ARSENIC BQL BQL BQL BQL 50.0 BARIUM 52.40 35.20 34.60 43.10 BERYLLIUM BQL BQL BQL BQL 6.5 CADMIUM BQL BQL BQL 0.25 2.0 CHROMIUM 1.34 BQL 0.96 1.24 50.0 COBALT BQL BQL BQL BQL COPPER 3.16 3.58 3.77 2.86 7.0111 LEAD BQL BQL BQL BQL 25.0 NICKEL BQL BQL 0.94 BQL 88.0 SELENIUM BQL BQL BQL BQL 5.0 SILVER BQL BQL BQL BQL 0.06�11 THALLIUM BQL BQL BQL BQL VANADIUM 2.59 0.86 1.48 2.28 ZINC 11.20 14.30 14.20 16.60 50.0 Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • [1] - Action Level • NS - Not sampled. Dry location. RuthCent_0519 TABLE 16 SURFACE WATER SAMPLING RESULTS APPENDIX I VOLATILE ORGANIC CONSTITUENTS BY SW-846 METHOD 8260 CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameters Sample Location 15A NCAC 2B/EPA Standards for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 1,1,1,2-TETRACHLOROETHANE BQL BQL BQL BQL 1,1,1-TRICHLOROETHANE BQL BQL BQL BQL 2,500.0 1,1,2,2-TETRACHLOROETHANE BQL BQL BQL BQL 1,1,2-TRICHLOROETHANE BQL BQL BQL BQL 1,1-DICHLOROETHANE BQL BQL BQL BQL 20,000.0 1,1-DICHLOROETHENE BQL BQL BQL BQL 5,400.0 1,2,3-TRICHLOROPROPANE BQL BQL BQL BQL 1,2-DIBROMO-3-CHLOROPROPANE BQL BQL BQL BQL 1,2-DIBROMOETHANE BQL BQL BQL BQL 1,2-DICHLOROBENZENE BQL BQL BQL BQL 470.0 1,2-DICHLOROETHANE BQL BQL BQL BQL 1,2-DICHLOROPROPANE BQL BQL BQL BQL 1,4-DICHLOROBENZENE BQL BQL BQL BQL 100.0 1,4-DIOXANE BQL BQL BQL BQL 2-BUTANONE BQL BQL BQL BQL 160,000.0 2-HEXANONE BQL BQL BQL BQL 4-METHYL-2-PENTANONE BQL BQL BQL BQL 26,000.0 ACETONE BQL BQL BQL BQL 2,000.0 ACRYLONITRILE BQL BQL BQL BQL BENZENE BQL BQL BQL BQL BROMOCHLOROMETHANE BQL BQL BQL BQL BROMODICHLOROMETHANE BQL BQL BQL BQL BROMOFORM BQL BQL BQL BQL BROMOMETHANE BQL BQL BQL BQL CARBON DISULFIDE BQL BQL BQL BQL CARBON TETRACHLORIDE BQL BQL BQL BQL CHLOROBENZENE BQL BQL BQL BQL 140.0 CHLOROETHANE BQL BQL BQL BQL CHLOROFORM BQL BQL BQL BQL CHLOROMETHANE BQL BQL BQL BQL CIS-1,2-DICHLOROETHENE BQL BQL BQL BQL CIS-1,3-DICHLOROPROPENE BQL BQL BQL BQL 12.0 DIBROMOCHLOROMETHANE BQL BQL BQL BQL DIBROMOMETHANE BQL BQL BQL BQL ETHYLBENZENE BQL BQL BQL BQL 97.0 IODOMETHANE BQL BQL BQL BQL METHYLENE CHLORIDE BQL BQL BQL BQL STYRENE BQL BQL BQL BQL TETRACHLOROETHENE BQL BQL BQL BQL TOLUENE BQL BQL BQL BQL 11.0 TOTALXYLENES BQL BQL BQL BQL 670.0 TRANS- 1,2-DICHLOROETHENE BQL BQL BQL BQL TRANS-1,3-DICHLOROPROPENE BQL BQL BQL BQL 12.0 TRANS-1,4-DICHLORO-2-BUTENE BQL BQL BQL BQL TRICHLOROETHENE BQL BQL BQL BQL TRICHLOROFLUOROMETHANE BQL BQL BQL BQL VINYL ACETATE BQL BQL BQL BQL VINYL CHLORIDE BQL BQL BQL BQL Notes: • All results in parts per billion (ppb) • BQL - Below Method Detection Limit • ' - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards RuthCent_0519 TABLE 17 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE GROUNDWATER STANDARDS CENTRAL SANITARY LANDFILL (# 81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameters Well Number 15A NCAC 2L Standard for Class NC Groundwater Protection 8103-MW-2 8103-MW-3 8103-MW4 8103-MW-6 8103-MW-7 8103-MW-8 8103-MW-9 8103-MW-10B 8103-MW-10C 8103-MW-10D 8103-MW-11A 8103-MW-11B 8103-MW-12 8103-MW-13 8103-MW-14 8103-MW-15 GA Groundwater Standard ALUMINUM 1,760.0 3,500.0 ANTIMONY ,7.91„ 2.76 1.0 CHROMIUM 28.0 15.0 26.0 10.0 ` COBALT 1.32 1.2 J 30.7 2.98 15.6 15.55 27.5 16.9 13.0 7.57 8.4 1.3 2.1 1.0 IRON - 730.0 1,060.0 912.0 •9,690.0 = 1010.0 - .796.0 4,890.0- 6,620.0 - _ 3,670.0• 2y050A 2,690.0 300.0 ` MANGANESE 306.0 4,850.0 2,220.0 87.5 133.0 50.0 ` TDS 540,000.0 1 1 1 500,000.0 ` THALLIUM 30.1 ° 2.7 ° 4.63 21.80 ° 18.'6 - 8.81 a 0.28 VANADIUM 0.46 .. .. 2.01 4.98 .. 1.35 .. 3.43. 3.54 e .. 49.20. .. 30.20 .. 2.23 .. .. 52.20 5." .. .. 1.94 4.86. 6.74 .. .. 0.3 1,2-DICHLOROPROPANE 14.7 0.6 ` 1,4-DICHLOROBENZENE 6.8 6.0 ` 1,4-DIOXANE 3.5 17.3 4.2 .4.5, 3.0 ` BENZENE 1.0 1.1 1.3 1.0 ` NAPHTHALENE 7.1 6.0 ` TETRACHLOROETHENE 0.8 0.7 ` VINYL CHLORIDE 1.1 0.7 0.8 0.3 0.03 ` Notes: • All results in parts per billion (ppb) • ' - Standard not established Shaded cells denote concentrations that equal or exceed 2L or Groundwater Protection Standards RuthCeM_0519 TABLE 18 NOTIFICATION TABLE CONSTITUENTS DETECTED AT OR ABOVE SURFACE WATER STANDARDS CENTRAL SANITARY LANDFILL (#81-03) RUTHERFORD COUNTY, NORTH CAROLINA MAY 7-15, 2019 Parameter Sample Location 15A NCAC 2B Standard for Class B,C Surface Water 8103-SW-2 8103-SW-3 8103-SW-4 8103-SW-5 MERCURY 0.04 0.06 0.08 0.03 0.012 Notes: • All results in parts per billion (ppb) • * - Standard not established • Shaded cells denote concentrations that equal or exceed 2B Standards or Action Levels • �11 - Action Level • NS - Not sampled. Dry location RuthCent_0519