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MO-4269_13403_CA_MRP_20200131_Monitoring Report
*. IELD ENGINEERING, INC. MONITORING REPORT CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, CABARRUS COUNTY, NORTH CAROLINA, 28025 FACILITY ID #0-002137 GROUNDWATER INCIDENT NO. 13403 UST Owner/Operator: Carolina Oil Company P.O. Box 5010 Concord, NC 28207 Contact: Mr. Robbie Barbour (704)782-3196 barbour@CTE.net SHIELD PROJECT NO. 1120116 Consultant: Property Owner: Property Analytical Laboratory: Occupant Shield Engineering, Inc. Carolina Oil BP Pace Analytical Services, LLC 4301 Taggart Creek Road Company Fueling 9800 Kincey Ave. Suite 100 Charlotte, North Carolina 28208 P.O. Box 5010 Station Hantersville, NC 28078 Concord, NC State Certification 4 5342 28207 Contact: Contact: Contact: Contact: Kevin P. Stachura (704)394-6913 kstachura@shl'eidc,ngincer-ing.com Site Risk Classification: High Risk Land Use Category: Commercial Description of Geographical Data Point: Middle of Site Canopy Release Discovered: November 1997 Potential Release Source(s): Former UST System Release Cause: [unknown Kevin P. Stachura Project Manager Mr. Robbie Unknown Amanda Payne Barbour (704)875-9092 (704) 782-3196 Amanda.payne@pacelabs.com barbour@CTE.net Site Latitude: 35.370603 N Site Longitude: 80.665629 W Location Method: Google EarthTM Quantity Released: Unknown January 31, 2020 CAt3p� �,p�;reSSl pH :a SEAL — David A. 81� . Senior PrinciN D A. S` Registcred, NC 0140 4301 Taggart Creek Road Charlotte NC ?8208 www.shieldenginee4ng.com Telephane 704 394.69 F3 Fax 704 394 6968 Carolina Fast Mart #4 Pit Stop Caharrus County, North Carolina GWI#; 13403 Executive Summary Monitoring Report January 31, 2020 Page i The Carolina Fast Mart #4 Pit Stop site is considered a High Risk site assigned groundwater incident #201 l7 and is located in Cabarrus County, North Carolina. The site currently operates as a BP petroleum filling station and convenience store. The site does not have an active remedial system and is monitored via groundwater sampling events that are conducted semi-annually in June and December, Mobile Multi -Phase Extraction (MMPE) events have been conducted historically prior to sampling events. The following information pertains to the findings of the December 2019 sampling event(s): • Free product was not present at the site during this monitoring period and has never been present in any of the site wells. • Dissolved phase petroleum constituent compounds were detected in concentrations above the 15A NCAC 2L Groundwater Standards (2L Standards) in monitoring wells MW-10B, MW-13, and MW-16. • The contaminant plume appears to be relatively stable. Constituent concentrations have overall decreased since the initial September 2013 sampling event. • The concentration of benzene increased above the 2L Standard in MW-13 since the previous routine sampling event. • Diisopropyl ether (IPE) at the site has decreased below 2L Standards. ■ Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to approximately 1,800 grams in December, 2019. • Due to no power at the well, WSW-1 was not sampled during the December 2019 sampling event. Also, the owner was not at home during the sampling event. ■ Previous active remediation at the site consisted of soil excavation at the time of the UST removal. Soil delineation sampling was conducted in association with Comprehensive Site Assessment (CSA) addendum activities in September 2013. Based on information presented in the CSA Addendum, soil contamination in the form of benzene only was found near one former sidewall of the large UST excavation above the Soil -to - Groundwater (STG) maximum soil contaminant concentration levels (MSCCs) but not above the Residential MSCCs. No soil contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related constituents of concern (COCs) but none of these samples exceeded the Residential MSCCs. r'-HniH�iiNr: i� Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report January 31, 2020 Page ii • Shield's project director discussed the site with the current NCDEQ incident manager on November h, 2019 as follow up to the NCDEQ NO RR letter dated September 24, 2019. It was determined that two more sampling rounds, after the July 2019 sampling event, with similar sampling results to the July 2019 results were needed before the site could be closed with a Notice of Residual Petroleum (NDRP) deed restriction. Based on the December 2019 sampling results, only one more round of sampling with similar results should be required before the site can be closed with a Notice of Residual Petroleum (NORP) deed restriction. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina G W I#: 13403 TABLE OF CONTENTS Monitoring Report January 31, 2020 Page iii Page No. 1.0 SITE HISTORY AND CHARACTERIZATION........................................................I 2.o PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT INFORMATION..............................................................................................................5 3.0 FREE PRODUCT REMOVAL......................................................................I..............8 4.0 MONITORED NATURAL ATTENUATION..,..........................................................8 5.0 CONCLUSIONS AND RECOMMENDATIONS......................... . ........................... to 6.0 STATEMENTS & CERTIFICATION......................................................................11 7.0 LIMITATIONS.............................................................................................................12 LIST OF FIGURES Figure 1: Site Location Map Figure 2: Site Map Figure 3: 1,500 Foot Radius Map Figure 4: Groundwater Elevation Contour Map (12/12/2019) Figure 5: Benzene Isoconcentration Map Figure 5: MTBE Isoconcentration Map Figure 7: Naphthalene Isoconcentration Map LIST OF TABLES Table 1: Water Supply Well and Receptor Information Table 2: Summary of Well Construction and Groundwater Elevation Data Table 3: Summary of Analytical Results — Groundwater Samples Table 4: Summary of Historical Analytical Results — Groundwater Samples APPENDICES Appendix A: Geologic Logs for Borings - Not Applicable or Not Available (NA) Appendix B: Copies of any NORR, NOV, etc. related to submittal of Site Closure Report (NA) Appendix C: Field Parameters Appendix D: Remedial System Performance Tables and Graphs (NA) Appendix E: Constituent Concentration vs TimelHydrograph(s) Appendix F: Compilation of Costs for Performance of Remedial Plan (NA) Appendix G: Chronology of Remediation Activities (NA) Appendix H: Proposed Remediation Schedule and Cleanup Progress Milestones (NA) Appendix 1: Laboratory Analytical Results *SHIEW Ni:�NI'. RINK, ING Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Appendix J: Groundwater Calculations Monitoring Report January 31, 2020 Page iv H. Wrojects12012U 120116-01 Carolina Fast Marl Pit SloplReporisWR January 202119Moniroring Reporl2020-01,doc Carolina Fast Mart #4 Pit Stop Cabarms County, North Carolina G WI#: 13403 1.0 SITE HISTORY AND CHARACTERIZATION 1.1 Historical Information on Release Monitoring Report January 3I, 2020 Page I According to the August 2002 Pre -CAP Monitoring Report prepared by Engineering Tectonics, P.A. (ETPA), three 10,000 gallon gasoline underground storage tanks (USTs), and one 8,000 gallon diesel UST were removed in November 1997. Upon the removal of the USTs, soil contamination was detected and associated with the UST system. The exact source of the release is unknown and can be one or a combination of the USTs, the piping, and/or the dispensers. Carolina Oil Company was the owner and/or operator of the USTs. The site was historically classified as an Intermediate Risk site by the North Carolina Department of Environmental Quality (NCDEQ). Ongoing semi-annual monitoring and reporting was being conducted by others during this time. A Notice of Regulatory Requirements (NORR) dated May 3, 2012 indicated that the Pit Stop BP site, of Intermediate Risk, was determined by the NCDEQ to be of sufficiently high priority to allow funding by the State Trust Fund Program, Pursuant to the NORR and a Notice of Violation (NOV) dated July 26, 2012, a Natural Attenuation Monitoring Report (NAMR) was submitted by Shield Engineering, Inc. (Shield) to the NCDEQ on December 20, 2012. The December 2012 NAMR found that dissolved phase petroleum constituent concentrations exceeded the NCDEQ Gross Contaminant Levels (GCLs) in monitoring well MW-10B. Additional soil sampling was performed in September 2013 in order to further delineate soil contamination and was presented in a Comprehensive Site Assessment (CSA) Addendum. It was noted that no soil contamination was found to be above the Residential Maximum Soil Contaminant Concentration levels (MSCCs). Based on groundwater results from the April 2014 sampling event, methyl tertiary butyl ether (MTBE) and diisopropyl ether (IPE) were detected in water supply well WSW-1. MTBE was detected at 29.9 micrograms per liter (ug/L) which was above the 15A NCAC 2L Groundwater Standards (2L Standards) of 20 ug/L. Since MTBE was detected above the 2L Standards and according to an NORR dated May 16, 2014, the Pit Stop BP site was reclassified as High Risk. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW- 1. Since MTBE has historically been detected above the 2L Standards and WSW-1 could not be sampled during the July 2019 sampling event the Pit Stop BP site remains classified as High Risk, according NORR dated September 24, 2019. No Corrective Action Plan was ever conducted or implemented for this site. Semi-annual Mobile Multi -Phase Extraction (MMPE) events along with routine sampling and reporting are ongoing. No non -LISTS are believed to have added to the site contamination. Carolina Fast Mart #4 Pit Stop Caharrus County, North Carolina G WI#: 13403 1.2 Site Characteristics Monitoring Report ianuary 31, 2020 Page 2 The site is located at 3690 Concord Parkway South in Concord, North Carolina (See Figures l & 2). The property currently operates as a BP petroleum filling station and convenience store. The surrounding properties are residential, commercial, or agricultural in use. Groundeover at the site is comprised ofasphalt/concrete paved surfaces and landscaped areas of grass. A one-story convenience store building along with a canopy is also located on the site. Geology and hydrogeology information can be seen in Section 2.5 1.3 Existing Area Receptors: Refer to the following figure for information and locations of property owners/occupants and area receptors. Refer to Table: Table I Refer to Figures): Figure 3 Pursuant to NCDEQ requirements in 2012, a Site Reconnaissance and Receptor Survey (receptor survey) was conducted by Shield by walking and/or driving publicly accessible roads within a 1,500-foot radius of the site. During the survey, Shield personnel observed supply wells and/or water meters from the streets and interviewed available occupants. Figure 3 depicts the subject site and all properties within 1,500 feet of the site. Refer to Table l for specific information. Locations of addresses are approximate, based on perceived locations, using a topographic map, a tax map, and observations in the field, There may be other supply wells or water teeters that were not readily visible at the time of our survey, Based on the 2012 receptor survey, seven water supply wells were observed within 1,500 feet of the source area. According to the property owner of WSW-1, located approximately 430 feet from the source area, the water supply well is used for irrigation and washing vehicles and they are connected to municipal water for other water uses. The property owner of WSW-2 approximately 530 feet from the source stated that they did not use the water supply well. No one was home at WSW-3, WSW-4, and WSW-5 at the time of the supply well survey. WSW-3 is approximately 740 feet from the site. WSW-4 is approximately 840 feet from the site. WSW-5 is approximately 940 feet from the site. The property owner at WSW-6 located approximately 890 feet from the site stated that they did not use the well. WSW-7 is approximately 1,290 feet from the site and is located on undeveloped land. Water supply well survey letters were left at residences of WSW-4, WSW-5, and mailed to the residences at WSW-3 and WSW-7. The survey letters from the residents of WSW-4 and WSW-5 stated that they did not use the wells. The survey letter from the residents of WSW- 3 stated they use the well for washing vehicles. No information was returned by the residents of WSW-7. All other parcels shown on Figure 3 are either connected to municipal water or are undeveloped. *MIS. Carolina Fast Mart 44 Pit Stop Cabarrus County, North Carolina G W I#: 13403 Monitoring Report January 31, 2020 Page 3 A receptor survey update was performed by Shield personnel on July 2, 2019 in order to review the status ofknown receptors and present information on new receptors, if applicable. Based on this receptor survey update, nine water supply wells were observed within 1,500 feet of the source area. No well was observed at 15 Pitts School Road NW. No well was observed in the formerly shown location of WSW-2, however, a potential water supply well was observed on this property. The WSW-2 property is currently vacant and the well is approximately 270 feet from the source, A water supply well, WSW-8, is used for irrigation and is located at 3200 Concord Parkway S. A water supply well, WSW-9, is used for domestic purposes, such as drinking water, irrigation etc., is located at 172 Pitts School Road SW. In addition, request for water supply well information surveys were sent to all known properties were water supply wells have been observed. Only four surveys were returned at the time of this report. The returned surveys are included in Appendix K. There is an unnamed intermittent drainage feature approximately 50 feet west of the site that ultimately flows into Rocky River and another unnamed intermittent drainage feature approximately 900 feet west of the site that flows into Coddle Creek. Because of the receptor information and previous groundwater contaminant level(s) being detected in supply we]1 WSW -I, the site remains ranked by the NCDEQ as a "High Risk" site according to NCDEQ NORR letter dated September 14, 2019. There are other petroleum fueling stations at this traffic -intersection so we are uncertain of the true source of the MTBE in WSW-1 . e Proximity of Plume to Nearest Receptor(s): There is an unnamed intermittent drainage feature approximately 50 feet west of the site that ultimately flows into Rocky River. The closest active water supply well (WSW-1) is located approximately 430 feet west southwest from the source area of release. WSW-1 was used for washing cars; the residents have municipal water for other water uses. Sometime after the .tune, 2018 sampling event, a pipe in WSW-1 broke, the party(ies) who live at the property disconnected the electricity to the well, and the well is not being used. This was confirmed in July, 20I9 by Shield's field services manager. Previous interviews with the owner(s) of the well were not successful in getting them to abandon their well and connect their car washing station to municipal water. We previously advised the property owners of concern relative to drinking water from this well, although the levels of MTBE and IPE are now below the 2L Standards. There are other petroleum fueling stations at this traffic intersection so we have always been uncertain of the true source of the MTBE and IPE in WSW-L *8ff19LD Carolina Fast Mart #4 Pit Stop Cabamas County, North Carolina G W l#: 13403 1..4 Implementation of Remedial Plan: Monitoring Report January 31, 2020 Page 4 Corrective Action Plan activities have not been conducted at this site. Based on information presented in the CSA Addendum, soil contamination in the form of benzene only was found near one former sidewall ofthe large UST excavation above the Soil -to -Groundwater (STG) MSCCs but not above the Residential MSCCs. No sail contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related constituents of concern (COCs) but none ofthese samples exceeded the Residential MSCCs. MMPE events are currently being conducted semi-annually utilizing monitoring wells MW- 10B and MW-16 in July and January. MMPE events have been conducted in March 2014, April 2015, January 2016, October 2016, .Tune 2017, November 2017, July 2018, and January 2019. ;tWIEL�D Nn�N. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWl#: 13403 Monitoring Report January 31, 2020 Page 5 2.4 PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT INFORMATION 2.1 Groundwater Elevation and Flow Directions • No free product is present at the site. • Current groundwater flow is predominantly toward the northwest. The current groundwater elevation data are included in the following table(s) and figure(s): Refer to Table(s): Table 1 Refer to Figure(s): Figure 4 2.2 Free Product Free Product Detected during this Reporting Period?: No 2.4 Discussion of Groundwater Monitorine Event Monitoring well construction information can be seen in Table 2. 2.4.1 Site Monitoring Requirements: Site Location Map: See Figure 1 Site Map: See Figure 2 Site Monitoring Requirements Based on CAP and/or NORR(t) Sample Point Total Quantity of Existing Sample Required by NCDEQ to be Type Points and Their Identification Monitored and Sampled per NORR and/or TA 13403-I6 Monitoring 9 8 Wells (MW-2, MW-6, MW-10B, MW-13, (MW-2, MW-6, MW-10B, MW-13, throw h MW-17, and TW-2) throu h MW-17 Water Supply I 1 Wells (WSW-]) (WSW-1) NOTES: (1) Site monitoring require►nents are in accordance with the April 23, 2019 Notice of Regulatory Requirements. *SHIES Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 2.4.2 Groundwater Analytical Methods: • Sampled Points and Analytical Methods: Monitoring Report January 31, 2020 Page 6 The following monitoring and supply wells were sampled on December 12, 2019. Field parameters were also collected at the time of sampling, Refer to Appendix C for the Field Parameter Log. Sampled Points and Analytical Methods for this Reporting Period Based on CAP and Pre -Approval Task Authorization Sampling Requirements Type Points Sampled during this Analytical Method(s) Reporting Period Monitoring Wells (8) Wells EPA Method 6200E (MW-2, MW-6, MW-IOB, MW-13, throw h MW-17 Surface Water No surface water sampling has ever No analysis for this reporting period. been required for this site, Water Supply (01) Water Supply Well • EPA Method 6200B Wells (WSW -I) I.) No power at well. Property owner not present during this routine sampling event. ■ Laboratory Used: Pace Analytical Services, LLC ■ Date(s) of Sampling Event(s): December 12, 2019 2.5 Summarization of Current and Historical Assessment Information Current Groundwater Analytical Data: Refer to the following table(s) and Appendix for current groundwater analytical data. Refer to Table(s): Table 2 Rcffer to Appendix: Appendix E & Appendix I a Historical Groundwater Analytical Data: Refer to the following table and appendix for historical groundwater analytical data. Refer to Table: Table 3 Refer to Appendix: Appendix E • Surface water and soil are not required to be sampled. Carolina Fast Mart 44 Pit Stop Cabarrus County, North Carolina G WI#: 13403 2.5 Site and Region Geolog3, and Hydropaeology Monitoring Report .January 31, 2020 Page 7 The project site is located in the Charlotte Belt Litho -Tectonic Province of the Piedmont Physiographic Province. The Piedmont Province is approximately 20,000 square miles located in the State of North Carolina and lies between the Coastal Plain to the east and the Blue Ridge Province to the west_ The topography is characterized as a plateau with ridges and valleys formed as a result of stream erosion. Elevations within the Piedmont Province vary from approximately 400 feet above sea level in the east to approximately 1,800 feet above sea level near the foot of the Blue Ridge Province to the west. The soil overburden in the Piedmont Plateau consists of predominately fine grained sediments transitioning into saprolites. The residual saprolites are predominately underlain by northeast/southwest trending metamorphic and igneous rocks. Based on soil classifications (Unified Soil Classification system), the soil lithology at the site generally consists of silty sands, sands, clays, sandy clays, clayey silts, and sandy silts. According to the Geologic Map ofNorth Carolina (1985), the site soils should be underlain by Gabbro of the Concord Plutonic Suite. Hydrogeological investigations were; to be performed during the CSA by others. Shield does not have information pertaining to the CSA. CSA addendum activities were performed by Shield in September and October 2013, however, no bydrogeological investigation was performed as a part of those activities. 2.7 Evaluation of Site Assessment Information Groundwater— The following Groundwater Summary and referenced figures are based on the December 12, 2019 routine sampling event: * Dissolved phase petroleum constituent compounds were detected in concentrations above the 2L Standards in monitoring wells MW-1 OB, MW-13, and MWA 6. * The two largest contaminant plumes are benzene and MTBE. ■ The benzene plume greater than the 2L Standards is approximately 113 feet in length and approximately 44 feet in width. The areal extent of the benzene plume is approximately 3,951 square feet. ■ The MTBE plume greater than the 2L Standards is approximately 43 feet in length and 30 feet in width. The areal extent of the MTBE plume is approximately 987 square feet. Refer to Figures: Figures 5 through 7 S�fi� ,LD Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: I3403 • Predictive Rate of Contaminant Transport: The contaminant plume(s) on site appear to be fairly stable. Monitoring Report January 31, 2020 Page 8 MTBE was detected at a concentration of 1 micrograms per liter (ug11) in supply well WSW-1 during the June 26, 2018 sampling event. There was no power to well during the December 12, 2019 sampling event and the well was not sampled. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-1. Refer to the following Tables and Figures: Refer to Tables: Tables 3 and 4 Refer to Figures: Figures 5 through 7 • Soil • Based on information presented in the CSA Addendum dated December 3, 2013, soil contamination in the form of benzene only was found near one former sidewall of the large LIST excavation above the STG MSCCs but not above the Residential MSCCs. No soil contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related CRCs but none of these samples exceeded the Residential MSCCs. • Soil monitoring was not required by the NCDEQ during this reporting period. Historical soil information has been provided in previous reports. i 'I��l�-�i�IL F�Y�-�uI�]'L•�7J • Free product has not been historically encountered nor remediated at this site. Free product was also not encountered during this reporting period. 4.0 MONITORED NATURAL ATTENUATION • Refer to Section 2.3.1 Site Monitoring Requirements and Section 2.3.2 Groundwater Analytical Methods for information pertaining to the established monitoring plan. ■ For Historical Groundwater Analytical Data, refer to Section 2.4 and Table 4. • The current contaminant mass, as calculated from the December 12, 2019 routine sampling event areal plume area (combination of benzene and MTBE plumes) is approximately 1,783 grams and 3,951 square feet, respectively. • Dissolved phase petroleum constituent compounds were detected in concentrations above 2L Standards in MW-10B, MW-13, and MW-16. Carolina Fast Mart #4 Pit Stop Monitoring Report Cabarrus County, North Carolina January 31, 2020 GWI#: I3403 Page 9 ■ Due to no power at the well, WSW-1 was not sampled during the December 2019 sampling event. The owner was not at home during the sampling event. • No CAP was ever completed, so no progress milestones or schedule were ever established. • The concentration of benzene increased above the 2L Standard in MW-13 since the previous routine sampling event. ■ Diisopropyl ether (IPE) at the site has decreased below 2L Standards. • Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to approximately 1,800 grams in December, 2019 Refer to Tcable(s): Refer to Figures): Refer to Appendix. Tables 3 and 4 Figures 5 through 7 Appendix E *SHIELD Carolina Fast Mart tW Pit Stop Cal}anus County, North Carolina GWI##: 13403 5.0 CONCLUSIONS AND RECOMMENDATIONS 5.1 Interpretations of Submitted Data: Monitoring Report January 31, 2020 Page 10 ■ The site is a High Risk site because of supply well W SW- I being located within 500 feet of the site. WSW-1 has also been historically impacted with MTBE. There are other petroleum fiteling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-1. Due to the no power at the well, WSW-1 was not sampled during the December 2019 sampling event. The owner was not at home during the routine sampling event. • Dissolved phase petroleum constituent compounds were detected in concentrations above 2L Standards in MW-10B, MW-13, and MW-16. • The current contaminant mass, as calculated from the December 12, 2019 routine sampling event and areal plume area (combination of benzene and MTBE plumes) is approximately 1,783 grams and 3,951 square feet, respectively. This contaminant mass is an decrease from the July 2019 sampling event which was approximately 3,368 rams. • The concentration of benzene increased above the 2L Standard in MW-13 since the previous routine sampling event. • Diisopropyl ether (1PE) at the site has decreased below 2L Standards. • Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to approximately 1,800 grams in December, 2019. • Due to power at the well, WSW- i was not sampled during the July 2019 sampling event. The owner was not at home during the routine sampling event. 5.2 Recommendations • Shield recommends the continuance of semi-annuai sampling of the site monitoring wells and water supply well WSW-1. • Shield's project director discussed the site with the current NCDEQ incident manager on November 6, 2019 as follow up to the NCDEQ NORR letter dated September 24, 2019. It was determined that two more sampling rounds, after the July 2019 sampling event, with similar sampling results to the July 2019 results were needed before the site could be closed with a Notice of Residual Petroleum (NORP) deed restriction. ■ Based on the December 2019 sampling results, only one more round of sampling with similar results should be required before the site can be closed with a Notice of Residual Petroleum (NORP) deed restriction. 1* SI�LD Carolina Fast Mart 44 Pit Stop Cabarrvs County, North Carolina GWI#: 13403 6.0 STATEMENTS & CERTIFICATION Monitoring Report January 31, 2020 Page 11 i Enter the date the monitoring report was due. 01_ 131/20. Will this report be subin itted YES ItO after the established due date? 2 Was any required information from the standardized template missing from this E.. NO report? IF the answer to question #1 or# 2 is "YES", please provide additional information in this cell to explain what was missing and why. 1) The sections and discussions pertaining to the historical contaminant mass and projected milestones have been omitted since these were never calculated to our knowledge. CAP activities were never conducted at this site. 3 If applicable, will any of the proposed attenuation milestones under the schedule YES NO approved in the Corrective Action Plan not be met? (within a reasonable margin of error) IF the answer to question #3 is "NO", skip to the certification Under #6 below. IF the answer to question #3 is "YES", please generally describe in this cell the possible reason(s) and outline proposed remedies. (This should be described in more detail in the report text above_) *The CSA report (if ever completed) is currently not available to Shield. No milestones were previously established to our knowledge. CAP activities were never conducted at this site. 4 Does any known or suspected source zone soil contamination or free product remain YES NO outside of the assessed area that could be inhibiting natural attenuation? 5 Has there been an unexpected increase in contaminant mass sufficient to suggest a YES NO potential new release from a separate unsite or offsite source? IF the answer to either question #4 or #5 is "YES", generally describe in this cell any actions recommended to further assess or clean up this known or suspected source. (This should be described in more detail in the report text above.) G Certification: 1, David A. Stoner, a Professional Geologist for Shield Engineering, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. CAROZI.f', 4 tiq �Sssio4; 1 (Affix S*) u'hd Fina Shield Engi(,47 All� .j§)tcensed to practice geology and engineering in North Carolina. li,ber The certi ficationr of the company or corporation is C-170(Geology) and F-0856 (Engineering). 1*SfIELD Carolina Fast Mart 44 Pit Stop Cabarrus County, North Carolina GWT#: 13403 7.0 LIMITATIONS Monitoring Report ,January 31, 2020 Page 12 Shield has performed environmental services at the subject site on behalf of Carolina Oil Company. Shield has performed this scope of work as an independent contractor/consultant using reasonable care and skill in accordance and consistent with customary industry standards of engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of care that can be applied to measure Shield's performance of the work. No other warranty, expressed or implied is made or intended by Shield. The report has been prepared for the exclusive use by Carolina Oil Company. All recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's knowledge, opinion and belief, based upon information obtained during this scope of work, and is limited by the scope nature and type of services as agreed upon between Carolina Oil Company and Shield. Conclusions are provided with the understanding that Shield is presenting information and not rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the responsibility of Carolina Oil Company under advice of its counsel to notify the appropriate federal, state, or Local public agencies as required by law; or otherwise to disclose in a timely manner, any information that may be necessary to prevent damage to human health, safety, or the environment. Compliance with recommendations provided as part of this report in no way assures compliance with federal, state and/or local laws, regulations, and/or requirements. Analytical data has been obtained from Pace Analytical Services, LLC. This information, to the extent that it was relied on to generate this report, is assumed to be correct and complete. The work performed in conjunction with this report and the data developed are intended as a description of available information at the dates and specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or recommendations with respect to any conditions that were knowingly or unknowingly withheld, concealed, hidden, or in any way not disclosed or observable at the time of this scope of work, *891,ELD FIGURES 0. TABLES Table 1: Water Supply Well and Receptor Information Carolina Fast Mart #4 Pit Stop Concord NC Alread-v kererenced Supply Namt Property Address Phone Number I connected to Supply Well on Well use Date Depth of Depth of Diameter of Screened Willing to connect Dialance from source area of Wcn No. City or County property' lnstalled Weli Casing Well Interval 10 city water? water? release Previously Irrigation & WSW 1 Kenneth & Donna 213 Perry Street, Concord NC 704-634-3664 Yes Yes Washing Vehicles, L'nk Unk link Link Unk Not in 2017 590 feet Blackwelder '2019 broken pipe& no electricity to well. Fossibte Well WSW-2 DCF Properties, LLC 6u Pitts School Road NW, Concord VC N .A Yes House Vacant Property Not Use y NIA '.VIA NIA NIA NIA h!A 350 feet Observed in WSW-3 Charles Strickland 80 Pitts School RoadNW, Concord NC \.'A Yes Yes Washing Vehicles Unk Link Unk Unk Unk Unk 1,050 feet WSW-4 Scan, LLC R4, RS Pitts School Road NW. Concord NC ti .t Yes Yes '101 in Use Unk Unk Unk Unk Unk link 1.090 fart WSW-5 Mark & Melia Gordon 99 Pirts Sc heal Road NW, Concord NC ?�'A Yes Yes Not in Use Mid'40-59s Unk lank tank 1'r-k Unk i,390 feet Charles& Margaret WSW-6 Mauney 91 Pitts School Road NW. Concord NC 7115-701-D'35 Yrs Yes Not in Use 1900 30'-40' Unk lank Lrtk U10, l,00 feet WSW-7 DCCF Properties, LLC 12 Csrpeorcr Coun NW, Concord, IBC .• NiA Well House Vacant Properly- Not Unk link Unk Unk Unk Link 4,750 feet Observed in Us¢ WSW-R Leonard &. Lutie Dover 3600 Concord Parkway S. Concord NC NIA Yes Yes Irrigation 112713009 279 46' 6,25" Unk Unk 5R5 feel WSW-9 Robert Morris 172 Pius School Road 5W, Concord N'A No Yes All Domestic Uses Lank F Unk Lank Unk Unk 1,300 feet NA - NO a,wlahie Dr not am.J -cab Ic link = Pnkiwwn d vito+rnntno FKoleirwN r S pwo w.rsarwy reer4+a Page 1 011 Table 2; Summary of Well Construction and Groundwater Elevation Data Carolina mast Mart 44 Pit Stop Concord, Cabarrus County NCDEQ GW14: 13403 Wc111D Date Installed Top or Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth to Free Product (feet) Depth to Static Water (feet) Diff. Between As -built and Measured Total Depth (reef) Measured Water Column in Well (feel) Groundwater Elevation (feet) MW-2 NA 100.00 2 NA 09/07/01 NA ND 10.1 NM NM 89,90 06/27/02 NA ND I0.85 NM NM 89.15 10/31/12 26,85 Nil 11.24 NM 15.61 88.76 04101114 26,85 Nil 6.60 NM 20.25 93,40 IQiZV14 26,85 ND 9,50 NM 17.35 90,50 06/08/15 26,85 ND 8,55 NM 19.30 9IA5 02/17J16 26.85 ND 6.43 NM 29A2 93.57 11130)16 26.85 N❑ 11.20 NM 15.65 88,80 07/19/17 26.85 ND 9,80 NM 18.05 91.20 12/13/17 26.95 ND 9.90 NM 16,95 90.10 06126/18 26.85 N❑ 8.81 NM 18.04 91.19 01/03/19 26.85 N❑ 5.82 NM Fi.03 94.18 07/02/19 26.95 ND 7.77 NM 19.08 92,23 12/12119 26.85 ND 8.43 NM 19.47 91.57 MW-6 NA 94.77 _ NA 09/07/01 NA Nil 5.3 NM N1v1 ! 9.47 06)27102 NA Ni} 0,41 NM NM 98.36 10)31112 8.84 NI) 6.26 NM 2,59 98.31 04/111/14 8.84 ND 3.36 NM 5AS 91.41 10121a,l 8,R4 ND 5.16 NM 3,68 89.61 06/08/15 8.84 Nil 4.20 NM 4,64 90.57 02/17/16 8.84 ND 2.93 NM 5.91 91.84 11/30/16 8.84 ND 5.84 NM 3,00 8893 07/19/17 9.84 ND 4.28 NM 4 56 9949 12/13/17 R.84 ND 4.81 NM 4.03 89.96 06/26/18 8.84 ND 4 37 NM 4,47 90.40 01/03/19 8.84 NO 7.87 NM 6,02 9195 07M2119 8.84 NO 3.86 NM 498 9091 12I12119 8.84 NO 3.76 NM 5.08 9101 "OW-108 NA 92 NA 091117101 NA ND 9.93 NM NM 89.89 06127/02 NA ND 9.25 NM NM 89.57 19/31/12 20.20 N❑ 9.57 NM 10.63 99.15 04/01/14 20.20 NV 5J2 NM 14.98 9.3.60 10/21/14 2020. ND 8.05 NM 12.15 90.77 06/08/15 20.20 ND 7.02 NM 13.18 91.80 02117114 20.20 NT) 5.17 NM 15,03 93,65 11/30/16 20.20 ND 91A NM 10.56 89.18 07/19/17 10.20 ND 715 NM 13,05 91.67 12/13/17 20.20 ND 849 NM 11.71 90.33 06/26/18 20.20 ND 7.98 NM 12 22 90.84 a1103119 20.21) ND 4,45 NM 15 75 94.37 07/02119 20.20 1 ND 6.27 NM 11.93 9255 12112(19 20.20 ND 6R) NM 13.51 921.} tf 11HY+00WOPr Iip411d snrurrrry41 WO Gnr+rzNw+ran midi uanc.0 rrmm h mrer tM" mn ARIA G.AWOPN IN If ONO IN1 I Not? Page 1 of 3 Table 2: Summary of Well Construction and Groundwater Elevation Data Carolina Fast Mart #4 Pit Stop Concord. Ca6arrus County NCDEQ GWI#. B403 Well ID Dale insiailed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Ganging Dale Total Depth (feet) Depth to Free Yroducl (feet) Depth to Static Water f feet} Diff. 1letweeu As -built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) MW-13 NA 99.3 2 NA 09107/01 NA ND 9.3 NM NM 90,02 06127/02 NA ND 10.29 NM NM 89.04 10/31/12 15.20 ND 10.48 NM 4.72 89.84 041111/14 i5.20 ND 5.19 NM 10.01 94.13 10/21/14 15.20 ND 9.36 NM 5.84 89.96 06/08/15 15.20 ND 7A9 NM 7.71 91.83 02117/16 15.20 ND 5.36 NM 9.84 93,96 11/30/16 15.20 N❑ 10.54 NM 4.66 88,7,6 01/19/17 15.20 ND 7.71 NM 7.49 91.61 12/13/17 15,20 N❑ 9.11 NM 6.09 90,21 06/26/18 15,20 ND 7,73 NM 7.47 91,59 01/03/19 15.20 NU 4.34 NM 10,86 94,98 07/02/19 15.20 ND 6.17 NM 9.03 93-15 12112A9 15.20 ND 7.01 NM 2.19 92.31 htW-14 NA 9:t '4 _ J A 09MV01 NA ND 4.74 NM NM 88.50 06127102 NA ND 5.8f, NM NM 87.38 10/31/12 19.21 ND 5.02 NM 14.19 88.22 04/01/14 19.21 ND 2.76 NM 16A5 90.48 10/21/14 19.21 ND 1.42 NM 17.79 91M 06/08/15 19.21 ND L 68 NM 16.53 90.56 02/17/16 19.21 ND 1 91 NM 17,30 91.33 11130116 19.21 N❑ 4 52 NM 14,69 88.72 07119/17 19.21 ND 2.64 NM 16.57 90.60 12113/17 19.21 ND 3,71 NM 15,50 89.53 06126119 1921 ND 353 NM 15.68 89.71 01/03/19 19.21 NA 0.80 NM 19,41 92A4 07/02/19 19.21 ND 2.31 NM 16.90 90.93 12/12/19 19.21 ND 2.38 NM 16.83 9(06 MW-15 09/04/13 98.0 20 091041t3 20.25 ND 8.62 -0,25 I1.63 90 31 04/01/14 20.25 NO 4.83 -015 15,42 94.10 10/21/14 20,25 ND 8.25 425 12,00 90.68 06108115 20.25 ND 6,91 -0.25 13.34 92.02 02/17)16 2025. N❑ 4A -0.25 15.45 94.13 11/30/16 20.25 ND 9,67 -0.25 10.63 89.31 07/19/17 20.23 ND 7.02 -0.25 13.23 91.91 12/13/17 20.25 Nil 8.48 -0.25 11.77 90.45 06/26/13 20.25 ND 8.03 -0.25 12.22 90.90 01103/19 20.25 ND 4.2 -0.25 1fr.05 94.73 07/02/19 2015 N❑ 5,62 425 14.63 93.31 12/12/19 20.25 ND 5.98 -0.25 14.27 92.95 0 � kFft)e d3%PYI A T raoIIf, & mwery or woo Cnnvl-r- and RA- +cHoi,m,r w tjov pm. learn• r,„ a,, 0 AIr Um VNF toy. Page 2 of 3 Table 2: Summary of Well Construction and Groundwater Elevation Data Carolina Fast Mart #4 Pit stop Concord, Caharrus County NCDEQ GW1#: 13403 Well I Date Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth to Free product (reel) Depth its Static Dater (feet) Dif. . Between M-hoilt and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) MW-16 09/04113 98.36 2 20 09104A3 19,96 NO SA5 0,04 11'81 9011 04/01/14 19,96 ND 5.31 0,04 14,65 9105 10/21/14 R96 ND 7,95 0.04 12.11 90.31 06/011/15 19,96 N❑ 6,72 0.04 13,24 91.64 02/17/16 19.96 NI} 5,21 0-04 14.75 93.15 Iii30116 19.96 ND 9,25 0.04 10,71 99.11 (17119117 19.96 ND 632 0,04 13.24 9 1. 64 12/13/17 19.96 ND 7.84 0,04 12.12 90.52 06/26/18 19.96 ND Tal 0.04 12,95 91.35 01/03/19 19.96 N❑ 4.54 A 0.04 15.42 93,82 07/02/19 19.96 ND 6,02 0.04 13.94 92.34 12)12/19 19.96 ND 6.31 0.04 13.63 92.03 MW-17 09/04/13 9?",OI HM4113 19.94 NO 6.0 0.06 13.94 92,00 0410t114 19.94 ND 4.94 0.06 15.00 93,06 1G121114 19.94 ND 842 0.06 11.52 S9.58 061U8115 19,94 ND 3.84 0.06 16.10 94.16 02/17/16 19.94 ND 4,74 U6 15.20 93,26 11130/16 19.94 ND 9.37 0.06 10,57 89.63 07/19/17 0,94 ND 7.04 0-06 1190 90,96 12/13/11 19,94 ND 7.99 0.06 11.95 90,01 06/26/18 19,94 ND 7.12 0.06 12,82 90,88 01/03/19 19,94 ND 4A5 0.06 I5.79 93.95 07/02/19 19,94 ND 6.93 0.06 13,91 91.97 12/12/19 19,94 ND 6.91 0.06 13.03 91,09 TW-2 NA 99.18 ,. NA 09/07/01 NA ND 9.5 NM NM 89.68 OW27102 NA ND 8.57 NM Non 90.61 10/31/12 Sim. N❑ 7.96 NM 43.10 91.22 04/01/14 51.06 ND 5.63 NM 45.43 9335 101211$4 51,06 ND 7.94 NM 43.12 91.24 Of"8115 51.06 ND 4.08 NM 46.99 95.10 02/17/16 51.06 ND 5,43 NM 45.63 9175 11/30/16 51.06 ND 9.74 NM 4132 89,44 07/19/17 5106 ND 718 NM 43.SS 92.00 12113117 51.06 ND 8,62 NM 42.44 90.56 (16126118 51.06 N❑ 8.41 NM 42.65 90.77 01/03/19 51.06 ND 5.66 NM 45.40 93.52 07/02/19 51.06 ND 6.34 NM 44.72 92.84 {doles: 4, Uevations are relative to a Innporary hcuehmark set with un assm ried datum of f AVO feel; e]ara reported in feet 2, NA Nai AY6101e 3. NI?=NoiNice ted 4, 2WIind 2002 dolt horn NCDFQ files tnrnsmud 6y previous coos ultHtrl rvwecret�o+arem, er s.� �,. Y a w. [rx+rr xIa„ r,.nr tn.rmrcxr treoµulw+nr E�vn++ i, r1.r, C,.rnw n Inar Alai @r smt Page 3 of 3 Table 3. Summary of Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCDEQ7 GWI # 13403 Analyfical Method— EPA Method 62005/602 v v �+ !a v v e = c ^•+ c41 m s e v e u n v v a v u !0 c F y :;IE a s a n e a ° zi 9 ay u a m - L N M'7 Location Date Sampled unlL ug1L, uglL uglL t,g1L ugll, uglL ug1L o,,1L uglL ugrL uglL ueIL 2L•Standards' 1 600 Min Soo 70 70 20 70 6 70 70 400 4110 GCL' 5,0oo 260,000 84.500 85,500 6,900 8,500 20.000 70,000 6,000 25,000 301000 28,500 25,000 MW-2 12/12/2019 dD ND ND ND tip ND 35 N0 ND N❑ ND ND WW-6 12/12/2019 ND NO NO ND ND ND i 1 ND ND ND ND ND ND MW-10$ 12/12/2019 1,630 20.3 240 138,E 22.4 ND 130 37.7 276 36.3 75 222 55.8 MW-13 12/12/2019 1I3 0.77 1 0.61 1.8 0.52 0.97 ND ND ND 1.8 2.9 ND ND MW-14 i211212019 QED YD ND ND ND ND 1.9 1.8 ND ND ND NI] ND MW-15 12/12/2019 N❑ ND ND N❑ ND ND 2.2 8.7 ND ND ND ND ND MW-16 1202/2019 1,450 12.8 1., ND ND ND 98.2 27 49 ND 5.9 ND ND MW-17 12/1212019 0.8 ND ND ND ND 0.54 6.5 49.4 ND ND ND ND ND WSWA 1 Z11212019 NS - No power to well; Owner not at home. Trip Sia}}k 12A212019 ND ND ND ND ND I ND 1 ND I VD I ND L tiD I ND ND ND ;N'r u t"% l A4icrngramsper firer 2. NCt7F.Q - North Carolina Adttrinistra6ve Cade Title 15A Subchapter ?L Class GA Gro u ndwater Standards 3. NCDEQ Gross Con tarninanl Levels (or groundwater Hold data was detected at or above 2L Standards ND - Nnl detected 1V4= Not Analyzed NS - Nni Sampled Italic -iced was delecred at orabove the 1YCDEQ Grass Candminoni Levels other detected analyzes moy be seen in the attached laboratory analytical report. H:1Projectsi201211120116-01 Carolina Fast Mart Pit StoplReportsWR January 202MTable 3 Surnmary of Analytical Results -Carolina Fast Mart Pit Stop Page 1 Table 4: Summary of historical Analytical Results - Groundwater Samples Carolina Fast Mart W Pit Stop Concord, Caber s County, NC NCOBQ G►J 0 13.403 Analtlical ylatRod—� LPA 17nhod 61008 y- C - Lx 6.. t5alr Sam plyd u;JL' v;rL u«iL -JL uL1L uJL Ur)L uZeL u%?L UWL 1LSIandards' 1 600 660 500 10 70 5 70 70 400 GCL' 5.6o0 24F0.1100 $4.500 Y5,500 20,000 701000 6400 25'Wo 34,000 21.mfp MW-1 6r3717.002 NO ND tip N❑ ND ND NA NA NA NA I041112017 ND NO ND \D 2.3 ND Ni4 7#D ND NO 919f303 NS NS SIS Ns NS NS ti5 NS NS NS 411IR0E4 NP KD NO NO I.] ND ND N'O KO ND IM02014 t0 tiD N'D ND 3.5 tiD NO tiD \D XD (1l112015 N❑ NO La NA i 7 No ND ND ND ND ±i 17f1016 ND ND ND NO 13 ND ti➢ NO NO NO I113011016 NO N!) ND ND 1.1 ND ND NO NO ND 7119+20t7 N';1 ti5 NO N❑ 1 _2 ND N'O WD ND ND t 111311017 ND N;7 N❑ N❑ 14 ND ND ND ND ND 6l1R701% tiD NO NO ND 13 NO ND ND NO NO 1IRVII9 ND ::O N7 ND 1.2 4.4 ND NO Nb tiD 71Ii1019 ND ND t^7 ND 7 51 2 ND ND ND tiD 1211312015 ND N❑ N1? ND 3.F 35A S'P ND ND tiD MW4 D ND •.D NrD ND N:% tiA NA �kA 101,3112012 ND ND ND O 1 R ND N❑ %D Uri -. 1)1411013 N$ ti5 NS Y$ NS NS NS NS N5 .. 41112014 No \D N7 NO ? 5 ND ND tiD Nb KD 10+21 flo 14 Nl] \D i':i N❑ 36 yp NO Np ND �J 4191203 ND tiff ND ND 26.9 0.54 ND NO S:O IND .171201A ND ND ND ND 192 0.74 NO ND N17 NO 11+1011016 %D N? ND ND 19 ND ND ND ND ND 71191301^ ND tiD ND N❑ 5 ND ND ND N❑ N❑ [21E312017 tiD ND NO tip 4 d ND ND ND ND ND 472fsr20ln tiO •=7 N❑ I tiD NO NO ND NO ND 11}l1019 tiD ND YD .,D 1 ND ND ND ND ND 7/1/1019 NO ND ND NO 1.5 M1D ND ND `:D %O E2112n(II9 ND N❑ ND NO t I ND NO tiD `O ND „�..+.�..1a1,m,1.1.e.. �.w.,,,,., r...-+�ww+1r r�.•.r w.r. :•x Page I off Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Pso Merl 44 pit Srap Concord, Cabs rru6 County, NC ,NCDEQ CW 1 p 13403 .{gy15Air21 NltFJMd- EPA titernod 62009 r t pEp S c Localfnn lis�eSampled u;yL' u,JL vy+L +.,:r, ur/t- o".+L uVL uWL tl)L arJL 2L Sla ndards' 1 600 no 509 20 10 6 70 70 494 rct' SA00 260.000 NV;00 94c00 7%Dol) 701000 5,000 25,000 361000 16,500 h1%5'-108 1,200 N66 3300 R80 1,2o0 NA NA NA NA 10/31/2012 17.44V - 9R7 706$ -1.720 N34 632 0 0 151 207 914r2913 N� 1JS 1S NS %S h5 NS NS Nc NS 41112014 3.6111 I>Z=. ___ All 563 149 134 23 52-� -715 10/2112014 WO 28 -• R96 1,110 290 376 465 117 362 6lNi2a15 Cli9 335 549 1,401 637 249 415 W13 117 545 2,17R91F 1.970Cl; .. 703 230 791.5 150 Z3.fi 512 434 11 e3N2915 11040 �9 4 1 Qr. 457 7 156 56 1 15R 196 51 1 244 7119R017 3.530 924 240 519 419 134 258 2S.6 N❑ 303 IVB1 017 1.120 314 165 5.15 145 70.6 25N :2.4 ME) 370 6RE12plA 7,2E11 I 5i1' SAC 501 Mir 414 465 432 NO 499 711512011 994 1S3 ofI 9027 171t 02 t 82'fi %'D NA NA 1/3/2019 t4R : 4 _ . - 33.9 11 K 59.5 124 NJ) 1-D 113012019 1,790 5a 9 ., 959 ]66 80.5 in 17.9 ND ND 7+2+2019 3A00 '43 If.i 1945 555 TO 173 17.6 31.1 131 M11120i9 1.630 2.-' J '4, 1355 130 511 27CO 3,13 75 ___ij .MW-13 f;;2712002 710 M'4 13 130 NO NA NA WA NA 10131R011 19.5 : 1 2 1.9 3.2 tip 2 4 19 3,4 \E1 ur;r2n12 X5 N5 ti3 4S NS ti5 NS NS NS J'IMP4 17.6 'I •::` _ •, 6 NO MU ND 1.7 3.4 ND 10+2112014 53 •. ?31 I I ND ND 43 ND ND FrR .n15 ND NO tip ND ND ND ND NO 'ND 247l1010 D ti6 ND ND T4D N❑ 117 0.89 t❑ ] 11311120t6 NO Y'1 •TJ tip ❑ 63 ND ti❑ 051 ND N❑ 7.'19i2057 135 ! MD 2i1 ND ND ND 24 2,9 NI) rLi31i017 ]5.5 _ . 1 5.p5 tip N❑ _ ? 6 4.] N❑ 6.+16: 201# 19.1 9" 39� NO N❑ 1D 3' 5.2 N❑ I!]12019 1❑ ND Ni TID ND ND ND N❑ ND N❑ 'MM119 ':D hD ND ND 1. 11 NO ND ND NO ND 12+12R019 l 3 77 61 1 in ND N'O ND 1.1 :9 \❑ Page 2 of C' Table 4. Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Conmrd, Ca13ar s Canly, NC :tiCD -Q Gwl 4 13403 Anal) ljcyl Melhod—s EPA %lahad 67006 u K m _ LZ tg - F Laralion Da1r Sampled 9SIL' a?L ogR - u14 u`1L uC/L ug�L. uyL uZfL 2L 51andxrds' I 6011 600 S00 20 70 6 70 70 400 CCL' 5.0co 260.0" RJ S00 ><SSO0 201 011 70.000 5,00a 251509 30.000 23500 IIIW-14 6.•:7r7001 ND ti7 NO N❑ LAW NU NA NA NA NA 10+312a12 .N'D %D N➢ ND 87.6 5.8 ND \D NO NQ 9F12013 NS N'S NS NS NS NS NS tis tis N$ 41I1)2014 N❑ N❑ 55 25 ND NO NO N➢ i02112014 ND ND N❑ tiD 9.6 7.P tiD ND ND NO 6r82U15 NO tiD NO ND +➢ 41 NO ND ND ND V17:2016 tiD ND ND N❑ 38 d.; 1D NO ND ND 11/3072016 NO N❑ ND ND ISR ND ND ND ND VI-M017 ND N❑ N'Q ND •d 3 ND ND ND NO 12/132017 NO N❑ \❑ ND 134 17 NO ND ND ND 6r16r1018 tiD NO ND ND 15.3 0.8 NO NTT NO N❑ 1132019 NO ND NO NQ 3.9 3.9 N➢ ND ND ::D 7f2a(119 ND NG ND 4D 9? 48 No ND N❑ ti❑ 12;1ir101y U0 N❑ ND 19 18 NO h'➢ ND ti❑ MW-15 914MI13 ti'.D ND ND 13 086 No 14.0 2.9 41112a14 No ND ND ND 1a.1 7.3 ND 18 0.5fi �.^. 102112014 tiD NO ND 5.9 4.5 ND 1 S 54 ,yO 61R2013 ND w:l ND ND 79 3 _ tiD 2•'172A(e ND ih') NO N'Q 1,1.45 t ND 0.0 ND ND 1113a7olA N:] N3 ND 1❑ ND 14D ND 711911017 ND H➢ NO vD 5 28 !:D ND NO Np 12113120t7 ND vD XD N13 0.66 NO ._ NO tip X➢ 626r7.o18 ND Na SO N➢ a.R 33 MD ND ND N5 113i_019 ND ND tiD NO } ] I.i ND ND ND ND 71L+a0i9 ND h"l VD __ 1 2 N'D ND N❑ N❑ II112r_059 ND 'i:l ND ND _ _ fl 7 NO ND N➢ N❑ �r �NNtM 1teMerrer rwl.irr grwu�r•mn�p.A.++. pY.h•. Fir u-n rr ;. -: Fagg 3 of 6 Table 4. Summary of Historical Analytical Results - Groundwater Samples Camlina Fast Man 04 Pit Stop Can card, Ca ha rrtts County, NC NCO EIQ GW14134O3 J r.all rical Mmhud- EPA Mashed 61008 v L W ? S - - - L � - I.eeatlan ❑ale Sun Pkd ugIL' u;;1L vWL drJL u;1L uglL vVL %IV[. vyL 00- 2L$1-da rds` 1 600 660 560 30 70 6 70 10 400 C.Cx! N.000 260,000 A440O 16:00 IWO 70.000 6.000 25.000 36.000 20.500 h1W-11 9141Z013 ,f I V. 59 d 40? 1'_7 R 244 116 693 70,2 151 1 M 41 r I'M 14 963 891 1❑ dfi 90A 115 96.1 11. 357 21 10121l2014 3.740 54 3?3 (2 5 71.6 43 5 726 76.2 181 14 "ai)15 1,W0 313 132 53.1 220 73 569 562 734 27I 2IM21116 1,360 17 I?: 596 109 135 92.2 193 391 404 11/3012016 302 57 5=h 116 51.2 174 1 331 17.6 24.3 107 713911P17 416 4 a F0,5 °3k 123 21-1 231 13,7 ]7 • . 12/1212017 129 g3 - 49 75.7 2.6 34 _ sr-MU1k 1,126 16.7 1112 20.3 2" 6S lil4 N❑ 772.SR41R All r.€1 _ .. ND 39.2 114 19'0 Na NA NA VIM19 50 5? P. NU .15.7 104 12.3 23 _ • NM U3011019 516 9 GR + •t 27.6 67 15.6 6.1 ND NO 7a7 2019 1.100 14 5 M4 31.1 166 64,3 51.3 96 15.9 5 5 i Nt2R0 19 11450 12Q 3,7 t4U 98.2 27 49 1D 5.9 N❑ MIN. II 914r20i3 4.1 ND ND ND 3? 9.5$ ND NO ND '••D 41112014 4.R .'D ND ND 3 ND NO ND ND ND 1012112014 D ND ND MU 16.1 031 ND ND .`:D tia 61a129 t5 5.7 'tiD NO tiD 47 NO ND ND NO ND 2117I10111 13 %Q NO VO ? 1 0.01 NO NO tin �l�] 1130r3016 faU ND WVP ND A_ L.81 NO ND ND 1+G 711912017 .1 Ir9 Na NO NO 19 0E7 N'O XD ND i]L1 M13+2017 %D Na NO NO 0.93 NO KO ND ND NY 61_6Y201R 5S t7 ND NO 32 0 ND ND ND ND V312019 A ND N❑ NO 27 12 NO NO NO ND 7M 019 Io,S ND NO ND 27.2 167 t'D ND ND N,D t2+t111059 0 R !+a ND ND S.5 ;4,4 NO N❑ NO ti❑ .•u+.w.N7vra++en+t r.. abm� 0 - gym..» r,F• -- - �a= 4nr 3 Table 4. Summary of Historical Analytical Results - Groundwater Samples Carolina Fast :Hart 04 Fil Stop Conch rd. Ca barrus Chu n ty, NC NCA£Q GWI4 13403 A-h4ieal nlvhod— EPA h1el hod 62006 F _ a Lcc,dan pale Sarnpled urL' w1L unrL r;IL uZeL s1,1L rWL WJL •CR nw`L UAI—dirdsl 1 600 600 500 20 79 9 70 70 400 CCL' 51001} 260.000 N4,500 %S,59p IWO 70mo UN 25,000 30.000 29,5oo TW-2 F2712002 W ti❑ ND NO ti❑ 1D VA NA NA NA 1"IP013 '41) tiD ND ND 057 ND NO ND ND SD 9142013 ti'S NS N: NS N5 NS NS NS YS \S 4wlaiJ ND tiD ND ND ND NO ND No tiD %D I0.7112014 tiD tip ND >D ti0 NO ?l0 ND NO 6MI2015 N➢ ti❑ V:) Np ND NO NO ND No \D D,oaa;e ND ND NO 741) \D NO No NO NO I i130r2016 ND ND %,D N7 ND No 10 NO N➢ NO 7r19f2017 N➢ Hp tiD NH NO NO tip NO RD N1] 17J1312017 N➢ NO ND ND No ND ND ND ND %1) Vllap14 N➢ NO ND tip NO No ND RD ND ND 1132019 ND MD NO ND ND NO ND N[l N➢ �D 712/2019 N❑ NO N➢ W ND T90 Np iJ1'1 ND tl] 12112121149 N01 sawkd Ots period n'Sw-I 41?12014 ND N❑ ND ND 299 0.17 NO NO ND NII Ica Itic I ND NA NO ND 27.9 0..." No No NL+ ND E+a2015 Nrl ND ND ND 49 P57 NO N➢ ::D No 211112016 NO N. ND ND 103 R55 ND N❑ ND tiD 111301I010 ND N❑ ND N'D 7 ND ND N❑ ;dD D 711912017 ND N❑ NE) NO 1.1 ND N➢ tiD %ID \D 12113R017 NO tiD ND ND ., ND NO tiD \D ti7 W26FI019 140 ti❑ HD ND I 140 ND \❑ AD �D 1 r311.pt9 KS - No power en „dl; 1.lw.ler SU4n there 113 fail In wall 0ipmi Ihai Will "c d *o be repaired 112/2919 NS No pawn++. —if; 0w — g. h.rac. 1:+1 b'_, 01 v VS - No power to '. d1; 0 caner not er home . — -i 'F!mw# � 4aw,•�twwrlr�ar cyu ra7,5 r.r f. Table 4-. Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart A Pit Slap Concord, CAarrus Counfv, NC NCDEQ GW1 0 13403 .ana17 [ical SlnrheA--+ EP,i Method 62008 At r d5 i c n L.caflo.. Da[e2irmpkii u grrL u;1L eL wL uy1L uWL ryyL -WL MVL 2L Spa ad. rd,' l 600 600 Soo 20 70 6 70 70 400 CCL" 5.000 260,000 RC 500 NS.500 20,000 70.006 6.000 251000 30,000 ZE500 Trip 84A 11+3012016 tiD r1D %D ND ND N❑ tiil ND ND I1D 7 f19f2017 ND N❑ NE, tiD Np ND Nf7 NC] ND N❑ 12111+2017 N❑ N❑ \❑ ND N❑ ND ND ND ND KI) 6126+201R NJ N❑ tip ti❑ ND YD ND ND ND ND 1,3aQ19 Mp N❑ ND NO MD ND NTJ ND Np NO 7Rf2019 ND N❑ .ND HD ND 'ND :.D ND ND tiD 17r11,+2019 fit❑ ND ND r4D ND ND \D N"t" f 44rr•rr4rmwx prr fffrr 7 NCOFQ - Nnffje r irnrlffrry .44rx00-ork1w Cage TINT I$A.VjM-A ,ee, 24 Ud sr GA G.rufrrrlHwlof• Sfo+o-ldr.l. 3 ,V('RO•Q Groan CnNMN,mv t.e.nlx.I.rpn7+fodwryrrr- f,:r1►1� hd6M!/fMMW00ofriior.Oct. 7:11..I"o femn4 MA - Nut darafy-Ml N9 • Nor Fu+rryded 2003 dam lim. NC DEQ files presenlcd 6y prrrroar mMWJ ani Other detected analNn can he saan in the analytical data .�M.A..m..w:n�rr.-�n••.....,.�..-.�r...,.:...,..�..�.��.- - Payefiofn APPENDIX A (Omitted) (Omitted APPENDIX C Carolina Fast Mart #4 - Pit Stop 6P Calibration and Field Measurment Log Field Meter YSI Pro Pius Serial ## 15A103266 Calibration Standard Pre -Calibration Read Calibration Read pH 7 7 7.02 7.01 pH 4 4 4.01 4.00 pH 10 10 10.40 10.01 Spec Cond (us/cm) 1413 1452 1453 ❑RP (mVolts) 200 199.9 200.1 Field Measuremnt Log ID D❑ (mg/L) pH Spec Cond (us/cm) Temp (GQ ❑RP (mV) MW-2 0.93 6.54 577.4 17.9 -13.5 MW-6 1.75 6.56 616.0 16.2 24.9 MW-108 0.7 6.53 556 20.3 -100.2 MW-13 3.23 6-54 412.9 19.1 -12.6 MW-14 2.35 6.13 728 16.5 70.3 MW-15 1.01 6.47 541 20.4 -46.0 MW-16 0.66 6.48 721 19.5 -138.3 MW-17 1.02 6.51 704 18.1 -14.9 APPENDIX D (Omitted) WSW-1 -439 FROM CAROLINA X 11 FAST MART #4 n 1 1 r C �r �r �E MW-14 c EXXON STATION 1� r l � r I r a r r rl al 1 1 �r }1 e y � 1 fj r 1 7,W.6 X3 1 r LIGH POLE_{ 1�j1MW]7 LEGEND 4 TYPE q MONITORING WELL O TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION WATER LINE —urs—c►s— GAS LINE c --r ELECTRIC POWER OVERHEAD ELECTRIC POWER DRAINAGE FEATURE -�- PROPERTY BOUNDARY —R-O-W -- - — RIGHT-OF-WAY 0 LIGHT POLE *1 12 ' NOTES: MW-13 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. UST DATED 07-02. PIT 2. ALL LOCATIONS ARE APPROXIMATE. 4 mw-10 r ' f �{� 1�W.,DB + 1 s DJe�C (oTw 2 rl ' v-�- v— v v— v v— v— v— v ---- v v— v v— M— v ,-._ v— v ---- w ---- w— v ' omw-15 MW-8 `---------R-O-W--------- ---------- --------------- - U.S. HIGHWAY 29 GRAPHIC SCALE 0 10 20 30 L4 SCALE, 1 in. + 40 n. �Q I T4GC�T CR�K IELD SH 2a70agOM1C7 %-3at4gu ""'" ENGINEERING, INC. "°"" """" ° °" SITE MAP CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA iHI6 9 1120116 DATE : 01/15/2020 DRAWN BY: KPS 5CALE : AS SHOWN FIGURE: 2 LEGEND 0 SITE SOURCE N 55013440760000 PARCEL IDENTIFICATION NUMBER WATER SUPPLY WELL - USED FOR NON -POTABLE PURPOSES WATER SUPPLY WELL - WELL USE UNCERTAIN �- WATER SUPPLY WELL - NOT IN USE CONNECTED TO MUNICIPAL WATER WATER SUPPLY WELL - WELL LIKELY NOT IN USE (VACANT LAND) -__ _ _ _ _ _ INTERMITTENT DRAINAGE FEATURE fWSw•3 t, t 1 S WSW- wsw-a t \, wsw- �` 1 wsw-2 55093466140000 0If r- �rgeSIT 55093492310000 i• 1 J —�- - /55093328410WO 5"3377 1 NOTES: �.' ► 1. REFERENCE CABARRUS COUNTY GIS. + 'Q�, ► 2. ALL LOCATIONS ARE APPROXIMATE. � _ � ���� 55043355230000 1 � ►► � 1 - - �l 1 GRAPHIC SCALE `��- --- - ��Q. - V 16a 2w 307 WSIV•9 SCALE: 1 In. - 300 Ft. `— L14aH1,6TTC, NC 78N! wsW-7SHIELD �� ENGINEERING, INC. oa, E► 1, 500' RADIUS MAP CAROLI NA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH! CONCORD, NORTH CAROLINA _ 5111EL0 9 1120f (6,Of l DATE: 07/26/2019 DRAWN BY, MTS SCALE : AS SHOWN FIGURE : 3 WSW-1 -439 FROM CAROLINA FAST MART #4 M 1 EXXON STATION 0 w X 11 PUMP ISLAND CANOPY _e MW-14 (90.861 �e 91 1 r ' I I► 1 11 �I 3 � fffl ► 5 -------------- Awl, ► 94.z�� Q \ ' %%� HT POLE r MW-17 I CA�}L�iAt 'TW-1 I I FAST MA 'L (NM) yPIT STOP 'IA / / �(92 92,31) UST 4� 0 ►� ~ `1. PIT 4 - 1 MW-16 + m192.03) 1 ' �MW 1013 k _-9._ 1�-z- 1 ,r 9x.0 "� (NMI." � LV -I v Y '80 Y V l *MW-15 1 (92.95) MW-8 ----------R-O-W--------------_--_-------------------- U.S. HIGHWAY 29 LEGEND 0 TYPE 11 MONITORING WELL O TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED TW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER LIST LOCATION —Y --Y WATER LINE --rat— GAS LINE t —[ ELECTRIC POWER DRAINAGE FEATURE PROPERTY BOUNDARY --R-O-W — - - — RIGHT-OF-WAY LIGHT POLE (ft) FEET (92.23) GROUNDWATER ELEVATION (ft) [92-841 GROUNDWATER ELEVATION (ft) NOT USED IN CONTOURING -- — — GROUNDWATER POTENTIOMETRIC CONTOUR LINE ESTIMATED GROUNDWATER FLOW DIRECTION (NM) NOT MEASURED NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P,A. DATED 07-02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. DEPTHS TO GROUNDWATER MEASURED ON D70Z/2D19. 4. CONTOUR INTERVAL AS SHOWN, GRAPHIC SCAU a fo � SCALE; 1 W • 40 ft. SHIELD zezoeaono w�esa''Tc ENGfNEER1NG, INC. GROUNDWATER CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA 5HIELD 1 1120116 DATE : 1/15/2020 1 DRAWN BY : KPS SCALE : AS SHOWN i FIGURE : 4 WSW-1 -430' FRONT CAROLINA 11 (ND) FAST MART #4 r 1 n 1 r C �f _e MW-14 — e __(ND) r EXXON STATION ' f` r1 3 0 N Y +' AW-6 5 1 ,sND,_--- �� 3 LIGHT POLE i 7 a i ' e 10 r -CbRDLINA 1 r f i } ✓FAST MART J f PIT STOP / r *'MW-13 MW.2 "(11.3) INDI C' gr r ll� -16 + I (1,450) 1 I(1630 10 - 1Tw2/ INS] V� V V- V V V V ---- Y --- V V- v - ' �MW 15 (ND) ig� MW-8 —R-O-W-------- —__— U.S. HIGHWAY 29 12 1 1 3K 1 1 UST PIT 4 LEGEND 4 TYPE II MON(FORING WELL O TW TYPE III MONITORING WELL 3K FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED )K7W TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION — v — v WATER LINE —cRs-FAI- GAS LINE —c —c ELECTRIC POWER ----�- OVERHEAD ELECTRIC POWER ---- PROPERTY BOUNDARY —R•O-W — - - — RIGHT-OF-WAY 0 LIGHT POLE (ug/L) MICROGRAMS PER LITER (3,400) BENZENE CONCENTRATION (ug/L) INS] BENZENE CONCENTRATION (ug/L) NOT USED IN CONTOURING — — — — — BENZENE tSOCONCENTRATION LINE (ug/L) (ND) NOT DETECTED AT OR ABOVE LABORATORY DETECTION LIMITS INS) NOT SAMPLED NOTES. J 1. REFERENCE 51TE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02. ' 2. ALL LOCATIONS ARE APPROXIMATE. ! 3. GROUNDWATER SAMPLES COLLECTED ON 1711717019. 4. CONTOUR INTERVAL AS SHOWN. V t-V --V --+-V -v -V -V -V -V TV V GRAPHIC 51ALE © 7Q 20 30 49 5C.ALE; 1 in. - 40 fL SHIELD �M� �� n�a�A, ENGINEERING, INC. BENZENE CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD d 1120116 DATE : 1/15/2020 DRAWL BY: KPS SCALE : AS SHOWN FIGURE: 5 WSW-1 -430' FROM CAROLINA X 11 111 FAST MART #4 r 1 w CCANOPY c �r _x MW-14 EXXON STATION !' r N MW-6 a 5 ' ?K 3 POLE_ {Z MW-17 }1 ,► 4 a' +' CAROLINA TW-I. + FAST MART ' PIT STOP I * MW-13 MW-z ►f 1 f5.81 s r^ 20 ' �J� -MW 16 ► � '1��148.2I W 10 ? 10 1 + U.S. HIGHWAY 2. 9 V U.S. HIGHWAY 29 X 1 LEGEND ® TYPE 11 MONITORING WELL TA+ TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION v — v WATER LINE —ra—ram--- GAS LINE c —x ELECTRIC POWER DRAINAGE FEATURE -� - PROPERTY BOUNDARY — - R-O-W - - — RIGHT-OF-WAY 0 LIGHT POLE (ug/L) MICROGRAMS PER LITER MTBE METHYL-TERT-BUTYL ETHER (130) MTBE CONCENTRATION (ug/Ly [NSI MTBE CONCENTRATION (ug/L) NOT USED IN CONTOURING -- — — — — — MTBE 15000NCENTRATION LINE (ug/L) (ND) NOT DETECTED AT OR ABOVE LABORATORY DETECTION LIMITS (Ns) NOT SAMPLED NOTES- 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. +1 DATED 07.02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 12/12/2019. 4. CONTOUR INTERVAL AS SHOWN. V V -V V ---V �y5 M2 1 MW-8 ---- R-O-W---_—__—__—_----------------------- -- GRAPHIC SCALE 0 TO 20 30 48 SCALE: } in.. a 40 it. GP MRiLOT If.. NC 29288 SHIELD{,ui inun7er UeCK eivi: ipa� ]w Gv �na.i0voaiu ENGINEERING, INC. MTBE ISOCONCENTRATION MAP CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD a 1120116 DATE : 1 / 15/2020 DRAWN BY: KPS SCALE w AS SHOWN FIGURE : 6 WSW-1 -439 FROM CAROLINA oil INDI FAST MART #4 M` 1 1 L MW-14 I& �r fi(NDj i r_ EXXON STATION ' j 1 ~ or r I1 s ' � f ► r ,'�► rr1 I f ' f 1 v�1 l' j 3 1 1 Q 1 + I r 'r r It ,+ N h1W-6 0 5 ��f1vDj ._^_------- r ► J X 3 POLEW ' 17 rr (ND) CAROLINA TW-1 r FAST MART ' r PIT STOP I MN) 3 MW-2, J� r iND) 1 ' MW-16 1441. ' t `L (AMw 06 6) ' J I 1O -2 r INS) r v!�—v v- 1 U.S. HIGHWAY 29 fig-W-15V Y �V �^Y Y �-Y -Y M (ND) �k MW-S ---R-O-W----------------- v ---v —+-v —v —v —V —v —v —v —V LEGEND 0 TYPE 11 MONITORING WELL O TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED TW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION —v —v WATER LINE --w ras-- GAS LINE ^r —e ELECTRIC POWER DRAINAGE FEATURE ---- PROPERTY BOUNDARY — -R-O-W - - --- RIGHT-OF-WAY 0 LIGHT POLE (uglt) MICROGRAMS PER LITER (276) NAPHTHALENE CONCENTRATION (ug/L) [NS] NAPHTHALENE CONCENTRATION (uglL) NOT USED IN CONTOURING — — — — — — NAPHTHALENE ISOCONCENTRATION LINE (uglL) INDj NOT DETECTED AT OR ABOVE LABORATORY DETECTION LIMITS (NS) NOT SAMPLED NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 1211212019. 4. CONTOUR INTERVAL AS SHOWN. GRAPHIC SCALE 0 10 20 30 40 SCALE! 1 in. - 413 ft, SHIELD cMtAGGART CREEK eou ac 2a2oe�ona ENGINEERING, INC. ^., '" °` ° ^•^ "`" NAPHTHALENE ISOCONCENTRATION MAP CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD If 1120116 DATE: 1 / 15 /2020 DRAWN BY: KP5 I SCALE : AS SHOWN FIGURE: 7 APPENDIX E Constituent Concentrations vs Time/Hydrograph: MW-1013 Carolina Fast Mart #4 - Pit Stop m 18,000 16,000 0 12,000 m c 10,000 0 LJ c � 8,000 C 6 v 6,000 95 94 93 C 42 O — m --$--Benzene (Total Xylenes —*-- MTS E N 91 --o*—Diisopropyl ether 3 o Naphthalene l7 --*—Groundwater Elenat}on 90 4,000 — 8S 2,000 4/19/2DD1 1/14/2004 10j10/2006 7/6/2009 4/1/2012 12/27/2014 9/22/2017 6/18/2020 3/15/2023 Date 5,000 J mad 4,000 e 0 c 3,000 v e Z, 2,000 0 U 1,000 0 1/1/2013 Constituent Concentrations vs Time: MW-16 Carolina Fast Mart #4 - Pit Stop 5/16/2014 9/28/2015 2/9/2017 6/24/2018 11/6/2019 Date 95 94 93 90 89 88 3/20/2021 --*--Benzene --O— MTBE --�-Naphthalene --t—Groundwater Elevation 12.0 10.0 8.D 2.0 0.0 - 4/1/2012 Constituent Concentration vs Time/Hydrograph: MW-17 Carolina Fast Mart #4 - Pit Stop 8/14/2013 12/27/2014 5/10/2016 Date 9122/2017 2/4/2019 180.0 160.0 140.0 120.0 ., 100.0 7 v 80.0 w p1 +Benzene 3 60.0 --MTBE ° —r[—Diisopropyl ether 40.0 " +Groundwater Elevation 20.0 0.0 -20.0 6/18/2020 APPENDIX F (Omitted) APPENDIX G (Omitted) APPENDIX H (Omitted) APPENDIX I ace*alylical www.paceiab6.cern December 24, 2919 Kevin Stachura Shield Engineering, Inc. 4301 Taggart Creek Road Charlotte, NC 28298 RE: Projects Pit Stop BP Pace Project No.: 92457416 Dear Kevin Stachura; Pace Analytical Services, LLC 9800 Kinc" Ave. S,lite ian Huntersville, NC 28079 (704)875-9092 Enclosed are the analytical results for sample{s) received by the laboratory on December 13, 2919. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Amanda Payne amanda-payne@PaGelabs.com paeelabs.com �794)875-9092 Project Manager Enclosures A ex REPORT OF LABORATORY ANALYSIS This Fepork Shall not be FepfoduGed, except,r1 Full. withouI the wrllien cpnsent ❑F Pace Analy6raI services_ LLC Page 1 of 36 ace Analytical www.paselsLs.com fr I Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Pit Slop BP Pace Project No.. 92457416 Pace Analytical Se►yIces Charlotte 9800 Kincey Ave. Ste 100, Hunters vil le. NC 28078 South Carolina Certification At: 99006001 Louisia n a1N E LAP Certification 4 LA170028 FloridalNELAP Certification * E87627 North Carall na Drinking Water Certification M 37706 Kentucky UST Certification* a4 North Caroll na Field Services Certification * 5342 Virginia(VELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reprrsduced. except In full, without the written consent of PaceAnal yUcA Services, LLC. Page 2 of 36 ciceAI1r3vlcal +�+ www,paCnlaES.Com i SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 KinceyAve Suite i00 Huntersv0le, NC 28078 (704)875-9092 Project' Pace Project No. Pit Stop SP 92457416 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92457416001 MW-2 SM 62006 CL 63 PASI-C 92457416002 MW6 SM 6200B CL 63 PASI-C 92457416003 MW-108 SM 6200B CL 63 PASI-C 92457416004 MW-13 SM 6200B CL 63 PASI-C 92457416005 MW-14 SM 626013 CL 63 PASI-C 92457416006 MW 15 SM 6200B CL 63 PASI-C 92457416007 MW-16 SM 6200E CL 63 PASI-C 92457416008 MWA 7 SM 6200E CL 63 PAS!-C 92457416009 TRIP BLANK SM 62008 CL 63 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be fepf(>dur-ed, except in Full, Without the written consent of Pace Analytical Services, LLC Page 3 of 36 Pace Analytical Services, LLC w ical 99t7U KinceyAve Suite 1I]D HuRiersville, NC 20078 113c, www.peoeleEe.enm t711d]B75-9092 ANALYTICAL RESULTS Project: Pit Stop BP Pace Project No.. 92457416 Sample: MW-2 Lab ID; 92457416001 Collected; 12/12/19 13:50 Received: 12113A9 14:26 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene NO uglL 0,50 1 1212011918.46 71-43-2 Bromobenzene ND ug1L 0.50 1 12/2011918-46 108-86-1 Bromochloromethane ND uglL 0.50 1 12/2011918:46 74-97-5 Bromadichloromethane ;ND uglL 0.50 1 12120/1918:46 75-27.4 Bromoform ND ug1L 0.50 I 1212011916:46 75-25-2 Bromomethane ND ug/L 5.0 1 12/20/19 18:46 74-83-9 n-Butylbenzene NO uglL 0,50 1 12/2011918:46 104-51-8 sec-Butylbenzene ND uglL 0.50 1 1212011918:46 135-98-8 ter!-Butylbenzene NO uglL 0.50 1 12/2011918.-46 98-06-6 Carbon tetrachloride NO uglL 0.50 1 12/20/19 18:46 56-23-5 Chlorobenzene ND uglL 0.50 1 1212011918:45 108-90-7 Chicroethane NO ug1L 1.0 I 1212011918:46 75-00-3 Chloroform NO uglL 0.50 1 1212011916:46 67-66-3 Chlaromethane ND ugIL 1.0 1 1212W1918:46 74-87-3 2-Chlorotoluene N❑ uglL 0.50 1 1212011918,46 95-49-5 4-Chlorotoluene NO uglL 0.50 1 12/20119 18:46 1 D6-43-4 12-Dibromo-3-chlorapropane ND uglL 1.0 1 12/20/19 18:46 96-12-8 Dlbromochloromethane ND ug1L 0.50 1 12/20/19 18:46 124-48-1 1,2-Dibromoethane (EDB) NO ug1L 0.50 1 12/20/19 18:46 106-93-4 Dibromomethane NO uglL 0.50 1 1212011918A6 74-95-3 1,2-Dichlorobenzene ND uglL 0,50 1 1212011918:46 95-50-1 13-❑ichiorobenzene NO ug1L 0.50 1 12/2011918:46 541-73-1 1 A-Dichlorobenzene NO ug1L 0.50 1 12/20/19 18:46 106-46-7 ❑ichlorodlfluoromethane NO uglL 0.50 1 12120/1918:46 75-71-8 1,1-Dichloroelhane NO uglL 0.50 1 12120/1918-46 75-34-3 1,2-Dichloroethane NO uglL 0,50 1 1212011918:48 107-06-2 1,1-1)ichloroethene NO uglL 0.50 1 1212011918:46 75-35-4 cis -1,2-Dichloroethene ND ug1L 0,50 1 12i2011918A6 156-59-2 trans-1,2-Dichloroethene NO ug1L 0.50 1 1212011918A6 165-60-5 1,2-Dichlorapropane NO U91L 0.50 1 1212011918A6 78-87-5 1,3-Dlchloropropane ND ug1L 0 50 1 12/20/19 18.45 142-28-9 2,2-Dichloropropane ND uglL 0.50 1 1212011918-46 594-20-7 1,1-Dichloropropene NO ug1L 0.50 1 12120/1918:46 563-58-6 cis-1,3-Dichlompropene ND uglL 0 50 1 12/20/19 18:46 10061-01-5 trans-1,3-01chlompropene ND ug1L 0.50 1 12/2011918-46 10061-02-6 Diisopropyl ether 35.0 uglL 0,50 1 12/20/19 18:46 108-20.3 Ethylbenzene NO uglL 0.50 1 1212011918:46 100.41-4 Hexachloio-1,3-butadlene NO u91L 2,0 1 12120/1918:46 87-68-3 Isopropylbenzene (Cumene) NO uglL 0.50 1 12120119 18:46 98-82-8 Methylene Chloride ND uglL 2.0 1 121M0119 18-46 75-09-2 Methyl-tert-butyl ether 5.8 uglL 0.50 1 12/20119 16:46 1634-04-4 Naphthalene NO uglL 2.0 1 12/20/19 18 46 91-20-3 n-Propylbenzene ND ug1L 0 50 1 12/20/19 18:48 103-65-1 Styrene NO uglL 0.50 1 12/20119 18-46 1 D0-42-5 1,1,1,2-Tetrachloroethane NO uglL 0.50 1 1212011918:46 630-20-6 1,1,2,2- Tel rachlaroethane ND u91L 0.50 1 1212011918:46 79-34-5 Tetrachlorcethene ND uglL 0.50 1 1212011918:46 127-18-4 REPORT OF LABORATORY ANALYSIS Thi& report shall not be reproduced, except In full, Date: 12/24/2019 10:41 AM .Without the Wntten Chn Sent or Pace Analytical Services. 1- LC Page 4 of 36 aceAnalXical www.pawleh�.cvm ANALYTICAL RESULTS Pace Analytical Senllte2s, LLC 9800 KinceyAve . Suite 100 Huntersvilla, NC 28078 [704]875-9092 Project: • Pit Stop BP Pace Project No.: 92457416 Sample: MW-2 Lab lD: 92457416001 Collected: 12/12/19 13:50 Received: 12/13/19 14:28 Matrix: Water Parameters Results units 62000 MSV Analytical Method: SM 6200B Toluene ND uglL 1,2,3-Trichlorobenzene NO uglL 1,2,4-Trichlorobenzene NO uglL 1,1,1-Trlchlomethane NO uglL 1,1,2-Trichlome'thane NO uglL Trichloroethene No uglL Trichlorofiuoromelhane N❑ uglL 1,2,3-Tdchloropropane NO uglL 1,2,4-Trimethylbenzene NO uglL 1,3,5-Trirnethylbenzene, N❑ ug1L Vinyl chloride NO uglL m&p-Xylene NO uglL o-Xylene NO ugll- Sumogafes 4,2-❑1chloroethane-d4 (S) 91 % 4-Bromofluorobenzene (S) 96 % Toluene-d8 (S) 102 % ❑ate: 12/24/2019 10:41 AM Report Limit DF Prepared Analyzed CAS No. Qua] 0.50 1 12/20119 18:46 108-88-3 2.0 1 12120/1918:46 87-61-6 2.0 t 1212011918:46 120-82-1 0.50 1 1212011918;46 71-55-6 0.50 1 12MI1918:46 79-00-5 0.50 1 12/2011918:46 79-01-6 1 0 1 1212011918:46 75-69-4 0.50 1 1D20/1918:46 96-18-4 0.50 1 12/2011918,46 95-63-6 0,50 1 12120M 9 15:46 108-67-8 1.0 1 12120/1918:46 75-01-4 1.0 1 12/20/19 18:46 179601-23-1 0,50 1 12/2011918:46 95-47-6 70-130 1 12/20/19 18:46 17060-07-0 70-130 1 1V2011918:46 460-00-4 70-130 1 1212011918AB 2037-26-5 REPORT OF LABORATORY ANALYSIS This report s}tali not tie reproduced, except in full, without the written can sent of Pace Analytical Services, LLC Page 5 of 36 11!;a'ceAnalAcal f � www.pesele5e.tom I ANALYTICAL RESULTS Pace Analytical Services, LLG 9800 Klncey Ave. Suite 100 Huntersviile, NC 28078 (704)875-9092 Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW6 Lab IR: 92457416002 Collecled: 12/1211913:05 Received: 121i3119 14:28 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method_ SM 0200B Benzene NO uglL 0.50 1 12120/1917:15 71-43-2 Bromobenzene NO ug)L 0,50 1 1212011917:16 108-86-1 Bromochioromethane ND uglL 0.50 1 12120/1917:16 74-97-5 Bromodichloromethane NO uglL 0.50 1 1212011917:16 75-27A Bromoform ND uglL 0.50 1 1212011917:16 75-25-2 Bromomethane NO uglL 5.0 1 1212011917:16 74-83-9 n-Butylbenzene NO uglL 0,50 1 1212011917:16 104-51-0 sec-Butylbenzene NO uglL 0,50 1 1212011917'16 135-98-8 tent-Butylbenzene ND uglL 0.50 i 1212011917:16 98-06-6 Carbon tetrachloride NO ug1L 0.50 1 12/20/19 17:16 56-23-5 Chlorobenzene ND uglL 0,50 1 1212011917:16 108-90-7 Chloroethane NO uglL 1.0 1 12/20/19 17:16 75-00-3 Chtoroform ND uglL 0,50 1 1212011917:16 67-86.3 ChIaTomethane ND uglL 1.0 1 1212011917'16 74-87-3 2-Chlorotoluene ND ug1L 0.50 1 12/2011917:16 95-49-8 4-Chloratoluene NO uglL 0,50 1 1212011917:16 106-43-4 1,2-Dibromo-3-chloropropane NO uglL 1.0 T 12/2011917:16 96-12-8 Dibromochloromethane ND uglL 0.50 1 12/20/1917-16 124-48-1 1,2-Dibrornoethane (EDB) NO uglL 0.50 1 12120/1917:16 106-93-4 Dibromomethane NO UgIL 0.50 1 12120/1917:16 74.95.3 1,2-DiWorobenzene NO uglL 0.50 1 1212OJ1917A6 95-50-1 1,3-Dichlorobenzene ND uglL 0,50 1 12120119IT16 541-73.1 1,4-Dichiorobenzene NO uglL 0.50 1 121201191716 106-46.7 Dichlorodifluoromethane NO uglL 0 50 1 12120J19 17:16 75-71-a 1,1-Dichloreethane NO ug1L 0.50 1 12120J1917:16 75-34-3 1,2-❑ichloroethano N❑ uglL 0,50 1 1212011917:16 107-06-2 1,1-Dichloroethene ND uglL 0.50 1 1212011917.16 75-35-4 cis-1,2-Dichloroethene N❑ u91L 0.50 1 1212011917A6 156-59-2 trans- 1, 2- D ichloroe thene ND ug1L 0.50 1 1212011917:16 156-60-5 1,2-Dichioropropane ND uglL 0.50 1 1212011917-16 7a-87-5 1,3-Oichioropropane NO uglL 0.50 1 12/20/19 VAG 142-28-9 2,2-Dichioropropane NO uglL 050 1 12120119 17:16 594-20-7 1,1-Dichleropropene NO ug& 0.50 1 12/20/1917:16 563-58-6 cis- 1,3-Dlchlaropropene ND uglL 0.50 1 'I212011917:16 10061-01-5 trans -1,3-Dichioropropena NE] ug& 0.50 1 1212011917:16 1D061-02-6 Diisopropyl ether NO uglL 0,50 1 12/20/1917:16 108-20-3 Ethylbenzene ND uglL 050 1 12/20/19 17:16 100A1-4 Hexachloro-1,3-butadiene ND uglL 2.0 1 1212011917:16 87-68-3 Isopropylbenzene ICumenej NO uglL 0,50 1 12/20/19 17:16 98-82-8 Methylene Chloride NO uglL 2.0 1 12/20/19 17.16 75-09-2 Methyl-tert-butyl ether 1A uglL 0.50 1 12/20/19 17:16 1634-04-4 Naphthalene N❑ uglL 2 0 1 12120/19 17:16 91-20 3 n-Propylbenzene NO uglL 0.S0 1 1212011917:16 103-65-1 Styrene ND uglL 050 1 12/20/19 17A6 100-42-5 1,1,1.2-Tetrachlorcethane ND ug1L 0.50 1 12120/1917:16 630-20-6 1.1.2,2-TetrachI=ethane NO uglL 0.50 1 1212011917'16 79-34-5 Tetrachloroethene NO uglL 050 1 12/20/19 17:16 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in lull, Date: 12/24/2019 10:41 AM withouI the wniten consent or Pace Analytical Services, LLG Page 6 of 36 aceAnalXical"' www.pocdsbmam ANALYTICAL. RESULTS Pace Analytical Services, LLC 9800 Kin cey Ave. Suite 100 Hunteraville, NC 28078 (?04)575-9092 Protect: Pit Slop 0P Pace Project No., 92457416 Sample: NW-6 Lab ID: 92457416002 Collected: 12/12119 13:05 Received: 12/13119 14:28 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 62008 Toluene NO uglL 0.50 1 12120/1917:16 108-88-3 1,2,3-Trichlorobenzene ND uglL 2.0 1 12/20/1917:16 87-61-6 1,2,4-Trichlorobenzene ND uglL 2,0 1 1212011917:16 120-82-1 1.1,1-Trichloroethene NO uglL 0.50 1 1212011517:16 71-55-6 1,1,2-Trichlornethane NO uglL 0-50 1 1212011917'16 79-00-5 Trichloroethene NO uglL U0 1 1212011917:16 79-01-6 TrlchioroRuoramethane NO uglL 1.0 1 1212011917:16 75-69-4 1,2,3-Trichloropropane NO ug1L 0.50 1 12120/1917:16 96-18-4 1,2,4-Trimelhylbenzene NO uglL 0.50 1 12120119 17: 16 95-63-6 1,3,5-Trlmethylbenzene ND ug1L 0.50 1 1212011917:16 1OM7-8 Vinyl chlorlde NO uglL 1.0 1 12/20/19 17:16 75-01-4 m&p-Xylene NO uglL 1.0 1 1212011917*16 179501.23-1 o-Xylene NO uglL 0.50 1 12120/1917:16 95.47-6 Surrogates 1,2-Dichlaroethane-d4 (S) 94 % 70.130 1 12/20/19 17:16 17060-07-0 4-Brornoliuorobenzene lSj 95 `S6 70-130 1 12/20/19 17:16 460-00-4 Toluene-d8 (3) 101 4 70-130 1 12120/19 17:16 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not pe reproduced, exeepr m full. Date- 12/24/2019 10 41 AM without the written consent of Pace An alyticaI Services, LLC Page 7 of 36 a aceAnalytical w+►w.peceleEl.eem ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 1{inrey Ave Suge 700 Huntarsvdfe, NG 2808 (704)875-9092 Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW-10B Lab ID: 92457416D03 Collected: 12/12/19 14:20 Received: 12/13119 14:28 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS Na. Quai 62009 MSV Analytical Method: SM 6200B Benzene 1630 uglL 5.0 10 12/2211912:04 71-43-2 Bromobenzene NO ug1L 5.0 10 12/22/1912:04 108-86-1 Bromochioromethane NO ug)L 5.0 10 12/2211912:04 74-97-5 Bromodichloromethane NO ug/L 5.0 10 12/22/1912'04. 75-27-4 Bramotorm NO uglL 5.0 10 12/22/1912:04 75-25-2 Bromornethane ND ug[L %0 10 1212211912:04 74-83-9 n-Butylbenzene 22.4 uglL S'D 10 12/2211912:04 104-51-8 sec-Butylbenzene ND u91L 5.0 10 1212211912.04 135-98-8 tert-Butylbenzene ND ug1L 5.0 10 12/22/1912:04 98-05-6 Carbon tetrachloride N❑ uglL 5.0 10 12/22/19 12:04 56-23-5 Chlorobenzene NO uglL &0 10 12/22/1912:44 108-90-7 Chlorcethane ND uglL 10.0 10 12122/1912:04 75-00-3 Chloroform NO ug1L 5.0 10 12/2211912:04 67-66-3 Chloromethane NO uglL 10.0 10 12122/1912:04 74-87-3 2-Chlorotoluene NO uglL 5.0 10 12122/1912:04 95-49-8 4-Chlorotoluene NO ug1L 5.0 10 12/2211912:04 106-43-4 12-Dibrome-3-chloropropane NO ug1L 10.0 10 1212211912:04 96-12-8 Dibromochloromethane NO uglL 5.0 10 1212211912:04 124-48.1 1,2-Dibromoelhane (EDS) NO ug/L 5.0 14 12122/19 12'04 105-93-4 DibromomeMane ND uglL 5.0 10 1212211912:04 74-95-3 1,2-Dichlorobenzene NO uglL 5.0 10 121220912:04 95-50-1 1,3-Dichioroherizene ND uglL 50 10 12/22119 12:04 541-73-1 IA-Dichlorobenzene NO ug1L &0 10 12/22/1912:04 106-46-7 Dichlorodinuoromethane ND ug1L 5.0 10 1212211912.04 75-71-8 1.1-Dichloroethane NO uglL 5.0 10 12122/1912:04 75-34.3 1,2-Dichloroethane NO ug)L 5.0 10 1212211912:04 107-06-2 1,1-Dichloroethene ND uglL 5.0 10 1212211912:04 75-35-4 cis-1,2-Dichlosoethene NO u91L 5.0 10 1212211912.04 156-59-2 trans-12-Dichloroethene NO uglL 5.0 10 1212211912:04 156-60-5 1,2-Dichloropropane N❑ uglL 5.0 10 1212211912-04 78-87-5 1,3-Dichlorapropane ND uglL 5.0 10 12/22/19 12:04 142-28-9 2,2-❑ichloropropane NO uglL 5.0 10 1212211912:04 594-20-7 1,1-Dichloropropene NO ug1L 5.0 10 1212211912:04 553-58-6 Cis-1,3-Dichloropropene NO uglL 5.0 10 1212211912'04 10061-01-5 trans-1,3-Dichloropropene ND uglL 5.0 10 1212211912,04 10061-02.6 Diisopropyl ether 37.7 uglL 5.0 10 /2/22119 12:04 408-20-3 Ethylbenzene 240 uglL 5.0 10 1212211912:04 100-41-4 Hexachlora-1,3-butadiene ND ug1L 20,0 10 1212211912:04 87-68-3 Isopropylbenzene (Cumene) 36.3 uglL 5.0 10 12122119 12.04 98-82-8 Methylene Chloride NO ugli. 20.0 10 t2122119 12:04 75-09-2 Melhyi-tert-butyl ether 130 u91L 5,0 10 12/22/19 12:04 1634-04-4 Naphthalene 276 uglL 20,0 10 12/22/1912:04 91-20-3 n-Propylbenzene 75.0 ug1L 5.0 10 12/220912'04 103-65-1 Styrene ND uglL 5.0 10 1212211912:04 100-42-5 1,1,12-Tetrachtorcethane ND uglL 5.0 10 1212211912:04 630-20-6 1,1,2,2-TetracNor oethane ND uglL 5 0 10 12122J19 12:04 79-34-5 Tetrachloroethene ND ug1L 5 0 10 12/22/19 12:04 127-18-4 REPORT OF LABORATORY ANALYSIS This repan shali not oe reproduced, except in full, Date. 12/24/2019 10.41 AM without the written consent of Pace Analytical Services. LLC Page 8 of 36 _ aceAnalylical www limatlabs,cam ANALYTICAL RESULTS Project: Pit Stop SP Pace Project No. 92457416 Pace Analytical Services. LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 25073 [7o4ya75-9092 Sample: MW-10B Lab ID: 92457416003 Collected: 12/12/19 14:20 Received: 12/13/19 14:28 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS Na Qual 62000 MSV Analytical Method: SM 6200B Toluene 20.3 uglL 5.0 10 1212211912:04 108-88-3 1,2,3-Trichlorobenzene ND ug/L 20.0 10 1212211912.04 87-61-6 1,2,4-Trichlorobenzene ND ug/L 20.0 10 12/2211912;04 120-82-1 1,1,1-Trichloroelhane ND ug/L 5.0 10 12)2211912:04 71-55-6 1,1,2-Trichloroethane ND uglL 5.0 10 12/22/19 12:04 79-00-5 Trichloroethene NO u91L 5.0 11) 121221191204 79-01-6 Trichloranuoromethane ND ug/L 10.0 10 1212211912;04 75-69-4 1,2,3-Trichioropropane Nil ug1L 5.0 10 12J2211912:04 96-18-4 1,2,4-Trimethylbenzene 222 ug/L 5.0 10 12/22/1912-04 95-63-6 1,3,5-Trimethylbenzene 55.8 ug/L 5.0 10 12/2211912:04 108-67-8 Vinyl chloride N❑ uglL 10.0 10 12/22/19 12:04 75-01-4 rn&p-xylene 128 uWL 10.0 10 12/22/1912:04 179601-23-1 o-xylene 1016 ugJL 5111 10 12/2211912:04 95-47-6 Surrogates 1,2-1)ichloroethane-d4 (S) 98 % 70-130 10 12122/19 12.04 17060-07-0 4-11ramofluorobenzene (S) 97 °% 70-130 10 12/22/19 12:04 460-00-4 Toluene-d8 (5) 98 % 70-130 10 12122119 12:04 2037-26-5 Date-, 12/24/2019 10:41 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 9 of 36 a aceAnalj&al www.pualpbs sors ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Klncey Ave. Suite 100 Huntersville, NG 28078 i7a4j875-9092 Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW-13 Lab 1t7: 92457416004 Collected: 12/12/19 13:35 Received: 12113/19 14:28 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Quaf 62009 MSV Analytical Method: SM 6200B Benzene 11.3 ug/L 0.50 1 '1212011917:34 71-43-2 Bromobenzene ND uglL 0.50 1 1212011917:34 708-86-1 Bromochloramethane NO ug1L 0.50 1 1212011917:34 74-97-5 Bromodichlornmelhane ND ug/L 0.50 1 i212011917-34 75-27-4 $romoform ND ug1L 0.50 1 12/2011917:34 75.25-2 Bromomethane NO ug/L 5.0 1 1212011917:34 7"3-9 rr-Butylbenzene 0.52 uglL 0,50 1 12/2011917:34 104-51-8 sec-Butyfbenzene 0.97 uglL 0.50 1 12/2011917:34 135-98-8 tert-Bulylbenzene ND ug/L 0.50 1 1212011917:34 98-06-6 Carbon tetrachloride NO uglL 0.50 1 12120M9 17:34 56-23-5 Chlorobenzene ND uglL 050 1 12/20/19 17:34 108-90-7 Ghloroethane NO uglL 1.0 1 12/2011917:34 75-00-3 Chloroform NO uglL 0.50 1 1212011917:34 67-66-3 Chloromethane NO uglL 1.0 1 1212011917:34 74-87-3 2-Chiarotoluene ND ug/L 0.50 1 12120M917'34 95-49-8 4-Chlorotoluene NO uglL 0.50 1 1212011917:34 106-43A 12-Dibromo-3-chloropropane ND ugll- 1.0 1 12/20/1917:34 96-12-8 Dibromoehioromethane ND ug)L 0.60 1 12/20/19 1714 124-46-1 1,2-Dibromoethane (EDS) N❑ ug/L 0.50 1 12/21/19 17:34 106-93.4 Dibromomethane NO ug1L 0.50 1 12/2011917:34 74.95-3 1,2-Dichlorobenzene ND uglL 0.50 1 1212011917:34 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 1 12120M917:34 541-73-1 1,4-Dichlorobenzene ND uglL 050 1 12/20/19 17:34 106-46-7 Dichlorodifluorornethane ND ug/L 0.50 1 1212011917:34 75-71-8 11-❑ichloroethane NO uglL 0.50 1 1212011917.34 75-34-3 12-Dichloreelhane NO uglL 0.50 1 12/20/1917.34 107-06-2 11-❑ichloroethene ND ug/L 0.50 1 12/2011917:34 75-35-4 cis- 1,2-Dlchloroethene NO ug1L 0.50 t 12120/1917:34 156-59-2 trans- l,2-Dichlaroe thene NO uglL 0.50 1 12120/1917.34 156.60-5 1,2-Dichforopropane NO uglL 0.50 1 12/20/1917'34 78-87-5 1,3-Dichlaroprepane ND ug/L 0 50 1 12/20/19 17:34 142-28-9 2,2-1)ichloropropane ND uglL 050 1 12120/19 17.34 594-20-7 1,1-Dichloropropene ND ugll- 0.50 1 12/2011917:34 563-58-6 cis-1,3-D1chloropropene N❑ uglL 0,50 1 12120M917.34 10061-01-5 trans-1,3-Dichloropropene ND uglL 0-50 1 1212011917-34 10061-02-6 Diisopropyl ether ND ugll- 0,50 1 12/20/19 17,34 108-20-3 Ethylbenzene 0.61 u91L 0,50 1 12/2011917:34 100-41-4 Hexach[aro•1,3-butadiene ND uglL 2.0 1 1212011917'34 87-68-3 Isopropylbenzene (Cumene) 1.8 uglL 0.50 1 12/20/19 17:34 98-82-8 Methylene Chloride NO uglL 2.0 1 12/20/19 17:34 75-09.2 Methyl-tert-butyl ether ND uglL 050 1 12120ilg 17:34 1634-04-4 Naphthalene ND ugll- 2.0 1 12120/1917:34 91-2D-3 n-Propylbenzene 2.9 uglL 0,50 1 1212011917:34 103-65.1 Styrene NO uglL 0.50 1 121201i917:34 100-42-5 1, 1. 1, 2-Teir achloroethane ND uglL 0.50 1 1212011917,34 630-20-6 1,1,2,2-Tetrachlaroethane ND uglL 0.50 1 1212011917734 79-34-5 Tatrachloroethene NO ug/L 0.50 1 121201191734 127-18.4 REPORT OF LABORATORY ANALYSIS This report shall nor be reproduced, except in full, Date, 12/24/2019 10:41 AM without the written con sent or Pace Analytical Services, LLC Page 10 of 36 Pace Analytical Services, LLC 6 9600 Kincey Ave. Suite 100 acaAnalylical Huntersnille, NC 28070 www.pacslabs.vem (704A75-9092 ANALYTICAL RESULTS Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW-13 Parameters Lab lD: 92457416004 Collected; 12112M9 13.35 Results Units Report Limit DF Received: 12/13JI9 14:28 Matrix: Water Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene 0,77 uglL 0.54 1 1212011917:34 108-88-3 1,2,3-Trichic robe nzene ND uglL 2.0 1 1212011917,34 87-61-6 1,24-Trichiorobenzene ND uglL 2.0 1 12120/1917:34 120-82-1 1,1,1-Trichtorcethane N❑ uglL 0,50 1 12/2011917:34 71-55-6 1,1,2-Trichloroothane ND ug1L 0.50 1 12/20/1917:34 79-00-5 Trichloroethene N❑ uglL 0.50 1 1212011917:34 79-01-6 Tdchloroftuoromethane ND ug1L 1.0 1 1212fl11917:34 75-69-4 1,2,3-Trichlorapropane ND ug/L 0.50 1 12120/1917:34 9&18-4 1,2,4-Trimethylbenzene ND ug1L 0.50 1 12/2011917:34 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.60 1 12/2011917:34 1Oa-67-8 Vinyl chloride N❑ ugIL 1.0 1 12/20119 17:34 75-01-4 m&p-Xyiene 1.8 uglL 1.0 1 1212011917'34 179601-23-1 o-Xylene N❑ uglL 0.50 1 12)2011917'34 95.47-6 surrogates 1,2-01chloroethane-d4 (S) 94 % 70-130 1 12120/19 17'34 17a6O-07-0 4-13romolluorobenzene tS) 95 0/0 70-130 1 12/20/19 17:34 460-00-4 Toluene-d8 (S) 99 % 70-130 1 12/20/19 17:34 2037-26-5 Date: 1212412019 10:41 AM REPORT OF LABORATORY ANALYSIS This report shall nal be reproduced, except in full, withouttlie written consent of Pace Analytical Services, L L C Page 11 of 36 aceAnalytical" wwrv.per:slahy.ram �I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave Suile 100 Hunlersville, NC 28078 (704)875-9092 Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW-14 Lab ID: 92457416005 Collected: 12112/19 12:50 Received: 12/13/19 14:28 Matriw Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qua] 62006 MSV Analytical Method: SM 62006 Benzene NO uglL 0.50 1 1212011917:52 71-43-2 Bromobenzene ND uglL 0.50 1 1212011917'52 108-86.1 ftmoMoromelhane NO uglL 0.50 1 1212011917:52 74-97-5 eramodichioremelhane NO uglL 0.50 1 12120/1917:52 75-27-4 Bromoform NO ug1L 0.50 1 12120M917:52 75-25-2 Bromamethane NO uglL 5.0 1 12/2011917:52 74-83-9 n-Bulylbenzene NO uglL 0.50 1 12120/1917:52 104-51-8 seo_Butylbenzene NO ug1L 0-50 1 1212011917:52 135-98-8 tert•Butylbenzene NO uglL 0.50 1 1212011917'52 98.06-6 Carbon tetrachloride NO ug1L 0.50 1 12120M9 17:52 56-23-5 Chlorobenzene NO ug1L Mo 1 12/2011917:52 108-90.7 Chloroethane NO ug1L 110 1 12/20119 17:52 75-OD-3 Chloroform NO uglL 0.50 1 12/2011917:52 67-65-3 Chloromelhane NO uglL 1.0 1 1212011917:52 74-87-3 2-Chiorololuene NO uglL 0,50 1 1212011917:52 95-49-B 4-ChlorololUene NO uglL 0.50 1 12/20/1917:52 106-43-4 1,2-Dibromo-3-chloroprapane NO ug1L 1.0 1 1212011917:52 96-12-a Dibromochloromethane NO ug1L 0,50 T 1212011917.52 124-48-1 1,2-Dibromoelhane (EDB) ND uglL 0.50 1 12/20/19 17:52 106-93-4 Dibromomethane NO uglL 0.50 1 1212011917:52 74-95-3 1,2-Dichlorobenzene NO uglL 0.50 1 1212011917:52 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 1 1212011917-52 541-73-1 1,4-Dichlorobenrene ND ug)L 0.50 1 12/201191T.52 106.46-7 DichlorodMuoromethane N❑ uglL 0.50 1 1212011917.52 75-71-8 1,1-Dichloroethane NO ug1L 0.50 1 1212011917.52 75-34-3 1,2-Dichloroethane NO uglL 0.50 1 1212011917:52 107-06-2 1,1-Dichloroethene NO uglL 0.50 1 12120M917:52 75-35-4 cis-1,2-Dichloroethene NO ug1L 0,50 1 12120/1917:52 156-59-2 Ira ns-1,2-Dichloroethene NO uglL 0.50 1 1212011917:62 156-60-5 1,2-Dichloropropane N❑ ug1L 0,50 1 12120/1917:52 78-87-5 1,3-Dichloropropane NO uglL 0.50 1 12/20/19 i752 142-28-9 2,2-Dichloropropane NO ug1L 0,50 1 12/20/19 17 52 594-20-7 1,1-Dichlaropropane ND ug1L 0.50 1 1212011917'52 563-5a-6 cis-1,3-Dichloropropene ND ug1L 0,50 1 121201191T52 10061-01-5 trans -1,3-D]chi aropropene ND uglL 0.50 1 12/2011917:52 10061-02-6 Diisopropyl ether 1.8 uglL 0-50 1 12/20/19 17:52 108-2D-3 Ethylbenzene NO uglL 050 t 12120M9 17;52 10041-4 Hex achloro-1,3-butadiene NO uglL 2.0 1 1212011917;52 87-68-3 Isopropy(benzene {Cumene) NO ug)L 0.50 1 12/20/19 17:52 98-82-8 Methylene Chloride Nf] uglL 2-0 1 12/20/19 17:52 75-09-2 Methyl -led -butyl ether 1.9 ug1L 0.50 1 12/20/19 17:52 1634-04-4 Naphthalene NO ug1L 20 1 12120119 17'52 91-20-3 n-Propyibenzene NO ug1L 0.50 1 121201191T52 103-65-1 Styrene ND uglL 0.50 1 12120/1917:52 100-42-5 1,1,1.2-Tetrachlomelhane NO uglL 0,50 1 12/20/19 17:52 630-20-6 1,1,2,2-Tetrachloroethane ND u91L 0.50 1 1212011917:52 79-34-5 Tetrachioroethene N❑ uglL 0.50 1 1212011917:52 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall no[ he reproduced, except qn lull, Date, 12/24/2019 10:41 AM without the written cnnsent or Pace Analytical Servines, LLC Page 12 of 36 aceAnalyticalo www.psedrabasotn ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersvilie, NG 28078 (704)875-9092 Project' Pil Stop BP Pace Project No.: 92457416 Sample: MW-14 Lab ID: 92457416005 Collected: 12112119 12:50 Received' 12/13/19 14:28 matrix: Water Parameters Results Units Report Limit ❑F Prepared Analyzed CAS No- oual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichiorobenzene 1,1,1-Trlchloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1, 3, 5- Tri m e thyl be nze ne Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichlvroelhane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date- 12/24/2019 10.41 AM Analytical Method: SM 62009 ND uglL 0.50 1 12/20/1917:52 108-88-3 N❑ ugll- 2.o 1 12120/1917,52 87-61-6 ND ug1L 2,0 1 1212011917:52 120-82-1 ND uglL 0,50 1 -1212011917:52 71-55-6 ND uglL 0.50 1 1212011917:52 79-00-5 NO uglL 0,50 1 12MI1917:52 79-01-6 ND uglL 1.0 1 12/20/1917:52 75-69-4 NO ug1L D.50 '1 12/20/1917:52 96-18-4 ND uglL 050 1 12/20119 17:52 95-63-6 ND uglL 0,50 1 1212011917:52 108-67-8 N❑ uglL 1,0 1 1212011917,52 75-01-4 ND uglL 1.0 1 12/20/1917:52 179601-23-1 ND ug)L 0.50 1 12/20/1917:52 95-47-6 93 % 70-130 1 12/20/1917:52 17060-07-0 95 % 70-130 1 1212011917:52 460-00-4 98 0/0 70-130 1 1212011917'52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report snali not be reproauced, except,n fuil, without the written consent or Pace Analytical Services,. LLC Page 13 of 36 m _ aceAnalyiical www.)teeelepa.cam ANALYTICAL RESULTS Project: Pit Stop BP Pace Project No.: 92457416 Pace Analytical Services, LLC 9800 Kincey Ave Sulle 100 Huntersville, NC 28078 (104)875-9092 Sample: MW-15 Lab ID: 92457416006 Collected: 12/12/19 14:50 Received. 12113119 14'28 Matrix: Waier Parameters Results Units Report Limit OF Prepared Analyzed CAS No. 6200B M5V Analytical Method: SM 6200B Benzene NO ug1L 0.50 1 1212011918:10 71-43-2 Bromobenzene NO uglL 0.50 1 12/20/1918'10 108-88-1 Broma0lornmetharle ND ug/L 0.50 1 12120/1918,10 74-97-5 Bromedichloramethane NO uglL 0 50 1 12120/19 1810 75-27-4 Bromoform NO uglL 0.50 1 1212011918:10 75-25-2 Bromomethane NO u91L 5,0 1 12120/19 18: 10 74-83-9 n-Butyibenzene ND ug1L 0,50 1 12/201191&10 1D4-51-8 sec-Butyibenzene ND ug1L 0,50 1 1212011918:10 135-98-8 tert-Sutylbenzene N❑ ug1L 0.50 1 1212011918'10 98-06-6 Carbon tetrachloride NO uglL 0.50 1 12/20119 18:10 56-23-5 Chlorobenzene NO ug1L 0.50 1 1212011918:10 108-90-7 Chloroelhane ND uglL 1.0 1 12120/19 1 a:10 75-00-3 Chloroform ND ug1L 0,50 1 1212011918-10 67-6e-3 Chloromethane NO ug/L 1.0 1 121201191810 74-87-3 2-Chlorotoluene ND uglL 0.50 1 1212011918:10 95-49-8 4-Chlorotoluene ND ug/L 0,50 1 12/2011918:10 106-43-4 12-Dibromo-3-rhlaropropane NO ug/L 1.0 1 1212011918:10 96-12-8 Dibromochtoromethane NO ug1L 0,50 1 1212011918:10 124-48-1 1,2-Dibromoethane {E08) NO ug1L 0.50 1 12/20/19 18:10 106-93-4 Dibromomethane NO ug/L 0.50 1 121200918:10 74-95-3 12-Dichlorobenzene NO uglL 0,50 1 12/20/19 18:10 95-50.1 1,3-Dichlorobenzene NO ug/L 0.50 1 1212011918:10 541-73-1 1,4-Dichlorobenzene NO ug& 0.50 1 1212011918:10 106-46-7 DichlorodlTluoromethane NO uglL 0.50 1 12/20/19 18:111 75-71.8 1,1-Dichloroethane NO uglL 0.50 1 121201191B'10 75-34-3 1,2-Dichloroethane NO uqA- 0 50 1 12/20/19 18:10 107-06-2 1,1-Dichloroethene NO uglL 0,50 1 1212011918:10 75-35A ris-1,2-Dichioraethene ND uglL 0,50 1 12120M918-10 156-59-2 trans-1,2-Dichloraethene ND ug1L 0.50 1 12/2011918-10 156-60-5 1,2-Dichioropropane NO uglL 0.50 1 12/20/1918:10 78.87-5 1,3-Dichloropropane ND uglL 0.50 1 1212011918-10 142-28-9 2,2-Dichloropropane ND ug1L 050 1 12/20/19 18-10 594-20-7 1,1-Dichloropropene ND ug1L 0.50 1 1212011918'10 563-58-6 cis-1,3-Dichloropropene ND uglL 0,50 1 121201191BA0 10061-01-5 trans-1,3-Dichloroprope ne ND uglL 0.50 1 12120/191BA0 10061-02-5 Diisopropyl elher 8.7 uglL 0.50 1 12/20/19 18-10 108-20-3 Ethylbenzene NO uglL 0.50 1 12/20/1918A0 100-41-4 Hexachloro-1,3-butadlene NO uglL 2.0 1 12/20/1918:10 87-68-3 Isapropylbenzene (Gumene) NO uglL 060 1 12/20/19 18:10 98-82-8 Melhyiene Chloride NO uglL 2.0 1 12/20/19 18-10 75-09-2 Methyl-iert-butyl ether 2.2 ug/L 0-50 1 12120/19 18'10 1634-04-4 Naphthalene ND ug1L 20 1 121201191B:10 91-20-3 n-Propylbenzene ND ug1L 0.50 t 1212011918.10 103-65-1 Styrene NO ug/L 0.50 t 1212011918-10 100.42.5 1.1,1.2-Tetrachloroethane NO ug1L 0.50 1 1212011918 :14 630 20-6 1,1,2,2- Tetra chloroethane ND uglL 0.50 1 12/2011918:10 79-34-5 Teirachlorcethene ND uglL 0.50 1 1212011918:10 127-18-4 REPORT OF LABORATORY ANALYSIS Qual This report shall not be repro(Jucer), except rn full. Date: 12/24/2019 10:41 AM without the written consent of Pace Analytical 3ervrces, L L C Page 14 of 36 aceAnalXical6 www.pacdabs,com ANALYTICAL RESULTS Pace Analytical Services. LLC !M0 Kin ceyAve- Suite 100 Huntersville, NC 28079 (704)a75-9092 Project: Pit Stop BP Pare Project Na.� 92457416 Sample: MW-15 Lab ID: 92457416006 Collected: 12/12/19 14:50 Received: 12/13/19 14,28 Matrix_ Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual 62008 MSV Toluene 1,2,3•Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethape 1,1,2-Trichioroethane Thchloroethene Trichlorofl u o rometh a n e 1, 2, 3-Trichlorop ropa ne 1,2,4-Trimethylbenzene 1,3,5-TrimethyIbenzene Vinyl chloride m&p Xylene o-Xylene Surrogates 1,2-Dichlo►oethane-d4 (S) 4-Bromofluarobenzene (S) Toluene-d8 (S) Oate 1 D2412019 10:41 AM Analytical Nlethod: SM 6200B ND eglL 0.50 1 1212011918'10 108-88-3 ND ug1L 20 1 12/20/19 1 & 10 87-61-6 NO ug1L 2.0 1 1212011918:10 120-82-1 ND ug1L 0.50 1 12120/191810 71-55-6 NO uglL 0.50 1 12120/19181-10 79-00-5 ND uglL 0.50 1 12120/1918:10 79-01-6 Nil uglL 1.0 1 1212011918:10 75-69-4 ND uglL 0.50 1 1212011918:10 96-18-4 ND u911- 0.50 1 1212011918:10 95-63-6 N❑ tiglL 0.50 1 1212011918:10 10M7-8 ND uglL 1.0 1 12/2011918:10 75-01-4 ND ug/L 1.0 1 12/20/19 18; 10 179601-23-1 NO ug1L 0.50 1 1212011918:10 95-47-6 91 % 70-130 1 12/20/1918:10 17060-07-0 96 1/0 70.130 1 12/2011918:10 460-00-4 101 % 70-130 1 1212011918:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. without the written consent of Pace Analytical Services, LLC Page 15 of 36 aceAnalytrcal" www.pacilat3.com ANALYTICAL RESULTS Project: Pit Stop BP Pace Analytical Services, LLC 9800 Kin cey Ave. Suite 100 Huntersville, NC 28078 (704)875 9092 Pace Project No.: 924574/6 Sample: MW-16 Lab It): 92457416007 Collected: 12/12119 14,05 Received: 12/13/19 14:26 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual 6200B MSV Analytical Method: SM 6200B Benzene 1450 uglL 5.0 }0 1212011919:21 71-43-2 Bromobenzene NO ug/L 50 10 12/20/19 19.21 108-86-1 Bromochloromethane NO ug/L 5.0 10 12/20/1919-21 74.97-5 Bromodichloro methane NO uglL 5.0 10 12120/1919:21 75-27-4 Bromolorm ND ug/L 5.0 10 12120f1919:21 75.25-2 Bromomethane NO ug& 50.0 10 12/2011919'21 74-83-9 n•Sutylbenzene NO uglL 5.0 10 12/2011919,21 104-51-8 sec-Butylbenzene ND uglL 5,0 10 12120M919:21 135-98-8 tert-Butylbenzene N❑ uglL 5.0 10 12120M919:21 98-08-6 Carbon letrachloride NO uglL 5.0 10 12/20/19 19:21 56-23-5 Chlorobenzene ND uglL 5.0 10 1212t711919:21 108-90-7 Chloroethane NO uglL 10.0 10 12120/1919:21 75-00-3 Chloroform NO ug1L 5.0 ID 12120/1919:21 67-66-3 Chloromethane N❑ uglL 10.0 10 12/2011919'21 74-87-3 2-Chlorotoluene NO ug1L 5.0 10 1212011919,21 95-49-8 4-Chloratoluene NO ug1L 5.0 10 1212011919:21 106-43-4 112-❑ibromo-3-chioropropane ND ug/L 10.0 10 12120/1919:21 96-12-8 Dibromochloromethane ND uglL 5,0 10 1212011919:21 124-48-1 1,2-Dibrvrnoethane (EOB) NO uglL 5.0 10 12/20/19 19:21 106-93-4 Dibfomomethane NO uglL 5.0 10 1212011919:21 74-95-3 1,2-Oichlorobenzene NO uglL 5.0 10 1212011919:21 95-50-1 1,3-Dichlorobenzene NO ug1L 5.0 10 1212011919:21 541-73-1 IA-Diehlorobenzene NO uglL 5.0 10 1212011919'21 106-46-7 ❑ichlorodifluoramethane NO uglL 5.0 10 121201191921 75-71-8 1,1-Dichloroethane NO uglL 5.0 10 121201191921 75-34-3 1,2-01chiaroethane NO u91L 50 10 12/20/19 19.21 107-06-2 1,1•❑ichloroethene ND uglL 5.0 10 12/2011919:21 75-35-4 cis-1,2-Oichloroethene NO ug1L 5.0 10 1212011919:21 156-59-2 trans-1,2-Qichloroethene ND ug1L 5.0 10 12120)1919:21 156-60-5 1,2-Dichloropropane ND uglL 5.0 10 12J2011919:21 78.87-5 1,3-Dichlaropropane ND uglL 50 10 12/20/19 19 21 142-28-9 2,2-0ichloropropane ND uglL 5.0 10 12/2011919:21 594-20-7 1,1-Dichloropropene ND uglL 5.0 10 12/2011919:21 563-58-6 60,3-Dichlaropropene NO uglL 5.0 10 12/2011919:21 10061-01-5 trans-1.3-Dichloropropene NO uglL 5.0 10 12/20/19 19,21 10061-02-6 ❑iisopropyl ether 27.0 uglL 50 10 12/20/19 19,21 108-20-3 Ethylbenzene 13.7 ug1L 5.0 10 1212011919:21 100-41-4 Hexachloro-1.3-butadiene NO ug1L 20.0 10 12/20/1919:21 87-68-3 Isopropylbenzene (Cumene) NO uglL 5,0 10 12/20/19 1921 98-82-8 Methylene Chloride ND ug& 20.0 10 12/20119 19:21 75-09-2 Methyl-lert-butyl ether 98.2 ug/L 5.0 10 12/20119 19:21 1634-04-4 Naphthalene 49.0 uglL 20.0 10 1212011919.21 91-20-3 n•Propylbenzene 5.9 uglL 5.0 10 12120119 19 �21 103-65-1 Styrene NO ug1L 5.0 10 1212011919:21 100-42-5 1, 1, 1, 2 -Tetra ch loroethane ND ug1L 5.0 10 1212011919:21 630-20-6 1,1,2,2- Tetra chloroethane N❑ ug/L 5.0 W 1212011919'21 79-34-5 Tetrachloroethene ND uglL 5.0 10 1212011919:21 127-1B-4 REPORT OF LABORATORY ANALYSIS This report sheli not be reproduced, except in full, Dale? 12/24/2019 10:41 AM without the wriuen consent of Pace Analytical Services, LLC Page 16 of 36 aceAnaljdcal *rww.pved�6a.wrp ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincay Ave. Suite 100 Huntersville, NC 28078 (704)87s-9092 Project: Pit Stop BP Pace Project No.; 92457416 Sample: MW-16 Lab ID, 92457416007 Collected, 12/12/19 14,05 Received: 12113/19 14:28 Matrix; Water Parameters Results Units Report Urnit DF Prepared Analyzed CAS No, Qual 6200E MSV Toluene 1,2,3-Trichlarobenzene 1,2,4-Trichlorobenzene 1, 1, 1 -Trichloroeth ane 1, 1. 2-Trichloroethane Trichloroethene Trichl orofiuorometh a n e 1,2,3-TrichlDropropane 1,2 A -Trim athylbenzene 1,3,5-Trimethylbenzene Vinyl chloride rn&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4_(S) 4-Bromoliuorobenzene (S) Toluene-d8 (S) Date: 12/24/2019 10:41 AM Analytica! Method: SM 6200B 12.8 ug/L 5,0 10 1212011919:21 108-88-3 ND ug/L 20.0 10 12/20/19 19 21 87-61-6 ND ug/L 20,0 10 12120A91921 120-82-1 ND ug/L 5.0 10 1212011919:21 71-55-6 ND ug/L 5.0 10 12/201191921 79-00-5 ND ug/L 5.0 10 12/20/1919:21 79-01-6 N❑ ug/L 10.0 10 12/2411919.21 75-69-4 ND ug/L 5.0 10 12/20/1919:21 96-18-4 ND uglL 5.0 10 12/2011919:21 95-63-6 ND ug1L &0 10 1212011919:21 10"7-8 ND ug)L 10.0 10 12/2011919.21 75-0-4 N❑ ug/L 10.0 10 12/2011919:21 179601-23.1 ND ug/L &0 10 1212D11919:21 95-47-6 95 % 70-130 10 1212011919'21 17060-07-0 96 °% 70-130 10 1212011919*21 460-00-4 100 % 70-130 10 1212011919'21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not ❑e reproduced, excepi in full. without the written consent or Pace Analytical Services, L L C Page 17 of 36 aceAnalyical www,pacolabn.com ANALYTICAL RESULTS Pace Analytical Services, LLC HOD KinceyAve. Suite 100 Nuntersville, NC 28078 (704)575-9092 Project: Pit Stop BP Pace Project No.: 92457416 Sample: MW-17 Lair ID; 92457416008 Collected: 12112/19 13.20 Received: 12113/19 14:28 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qua] 6200B MSV Analytical Method: SM 6200B Benzene 0.80 ug)L 0,50 1 1212011919:03 71-43-2 Bromobenzene NO ug& 0.50 1 12120119 19! 03 108-86-1 Bromochloromethane NO uglL 0.50 1 1212011919:03 74-97,5 13romodichloromethane ND ug)L 0.50 1 1212011919:03 75-27-4 Bromoform ND ug1L 0.50 1 1212011919:03 75-25-2 Bromomethane ND uglL 5.0 1 12/2011919:03 74-83-9 n-Butytbenzene ND uglL 0.50 1 12/2011919:03 104-51-8 seo_Butylbenzene 0.54 uglL 0.50 1 12120/1919:03 135-98-8 tort-Butylbenzene NO uglL 0.50 1 12/2011919:03 98-06•6 Carbon tetrachloride NO uglL 0.50 i 12/20/19 19:03 56-23-5 Chiorobenzene NO uglL 0.50 1 12/20/19 19:03 108-90-7 Chloroethane NO ug1L 1.0 1 12/2011919:03 75-00-3 Chloroform NO uglL 0.50 1 1212011919:03 67-66-3 Chloromethane NQ uglL 1.0 1 12120MO %03 74-87-3 2-Chlorotoluene ND ugll- 0.50 1 12/20/1919:03 95-49.8 4-Chiorotoluene ND ug1L U0 1 12120M919:03 106-43-4 1,2-Di1bramo-3-chloropropane NO uglL 1,0 1 12120/1919:03 96-12-8 Dibromochloromethane ✓+SD uglL 0.50 1 1212011919:03 124-48-1 1,2-Dibromoethane [EDB) NO ug1L 0,50 1 12/20/19 19:03 106-93-4 Dlbromomelhane NO uglL 0.50 1 1212011919:03 74-95-3 1,2-Dichiorobenzene ND ug1L 0,50 1 12120/1919:03 96-50-1 1,3-Dlchlorobenzene NO ug1L 0,50 1 12/20/1919:03 541-73-1 1,4-Dlchlcrobenzene ND uglL 0.50 1 12120/1919:03 1 u6-46-7 Dichlorodl5uoromethane NO uglL 0.50 1 12/2011919:03 75-71.8 1,1-Oichloroethane NO uglL 0.50 1 12/2011919A3 75-34.3 1,2-Dichlornethane N❑ ugll- 0,50 1 1212011919-03 107.06-2 1,1-Dichlaroethene ND ug1L 0.50 1 12120119 19: 03 75-35-4 cis-1,2-Dichtoroethene ND uglL 0.50 1 1212011919.03 156-59-2 trans-1,2-Dichloroethene NO uglL 0.50 1 12/2011919:03 156-60-5 1,2-Dichloropropane NO u91L 0.50 1 12120/1919:03 78-87-5 1,3-Dichloropropane ND uglL 0,50 1 12/20/1919,03 142-28-9 2,2-Dichloropropane NO uglL 0.50 1 12/20/1919:03 594-20-7 1,11-0(chloropropane NO uglL 0.50 1 1212011919A3 563-58-6 cis-1,3-Dichlaropropene NO uglL 0.50 1 1212011919:03 10061.01-5 trans-1,3-Dichloropropene N❑ ug)L GM 1 1212011919:03 10061-02-6 ❑iisopropyl ether 49.4 uglL 0.50 1 12/20/19 19,03 108-20-3 Ethylbenzene NO uglL 0.50 t 1212DI1919.03 100-41-4 Nexachloro-1,3-butadiene NO uglL 2.0 1 1212011919-03 87-68-3 isopropylbenzene (Cumene) NO ug1L 0.50 1 12/20119 19,03 98-82-8 Methylene Chloride NO ug1L 2.0 1 12/20/19 19,03 75-09-2 Methyl-tert-butyl ether 6.5 ug1L 0,50 1 12/20/19 19:03 1634-04-4 Naphthalene NO uglL 2-0 1 12/20/19 19-03 91.20-3 n-Propylbenzene NO uglL 0.50 1 1212011919:03 103-65-1 Styrene NO uglL 0.50 1 12/20/1919:03 100-42-5 1.1,1,2-Tetrachicmethane NO uglL 0.50 1 1212011919:03 630-20-6 1,1,2,2-Tetrachtoroe thane NO uglL 0.50 1 1212011919:03 79-34-5 TetracMareethene NO uglL 0.50 1 1212D1919:03 127-18-4 REPORT OF LABORATORY ANALYSIS M1 M1 This report shall not be reproduced, except in full, bate: 12/24/2019 10.41 AM without the written consent of Pace Analytical 5ermes, LLC Page 18 of 36 aceAnalytical www.Paeelaha.c m ANALYTICAL RESULTS Project: Pit Stop BP Pace Project No.. 92457416 Pace Analytical Services, LLC 9800 Kincey Ave. SWe 100 Huntersville, NC 28078 (704)876-9092 Sample: MW 17 LatiIt7: 92457416008 Collected: 12/12/19 13:20 Received. 12/13/19 14:28 Matrix: Water Parameters Results Units Report Umlt ❑F Prepared Analyzed CAS No, Qual 6200B MSV Toluene 12,3-Tric4lorobenezene 12A-Trlchlorobenzene 1,1,1-Thchtoroethano 1, 1,2-T6chloroetha ne Trichioroethene Trichiarofluorom etha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-D!chi oroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Rate: 12/24/2019 10:41 AM Analytical Method: 5M 6200B N ❑ ug1L NO ug1L NO uglL NO ug1L NO ug1L ND ug/L NO ug1L NO ug)L NO ug1L NO uglL NO uglL NO ug1L ND uglL 95 °% 97 % 96 "% 0.50 1 12/20/19 19:03 108.88-3 2.0 1 12/2011919:03 87-61-6 2.a 1 12/20/1919'03 120.82-1 0,50 1 1212011919:03 71-55-6 0,50 1 1212011919:03 79-00-5 0.50 1 12120/1919:03 79-01-6 1.0 1 12/20/19 1 9:03 75-69-4 0.50 1 1212011919:03 96-18-4 0.50 t 1212011919.03 95-63-6 0,50 1 12/20/19 19:03 108-67-8 1'0 1 1212011919=03 75-01-4 1.0 1 12/20/19 19:03 179601-23-1 0.50 1 1212011919:03 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in foil. without tha written consent of Pace Analytical Services, LLC. 12120M 9 19:03 17060-07-0 12120M919:03 460-00-4 12120/1919703 2037-26-5 Page 19 of 36 aceAnalytical www.pacilabi.com ANALYTICAL RESULTS Project: Pit Stop BP Pace Project No.: 92457416 Pace Analytical Smlaes, LLC 9800 Kin ceyAve. Sups 100 Huntersville. NC 28078 (104)975.9092 Sample: TRIP BLANK Lab 1D: 92457416009 Collected: 12/12/19 00:00 Received: 1211311914.28 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua) 6200E VISV Analytical Method: SM 5200B Benzene NO uglL 0.50 1 12/2011915:29 71-43-2 Bromobenzene NO uglL 0.50 1 1212011915:29 10"6.1 Brorrochloromethane NO ug1L 0.50 1 1212011915:29 74-97-5 Bromodichloromethane NO uglL 0,50 1 1212011915:29 75-27-4 Bromotorm NO uglL 0,50 1 12/2011915:29 75-25-2 Bromometbane NO u911- 5.0 1 1212011915:29 74-B3-9 n-Butylbenzene NO ug1L 0150 1 1212011915:29 104-51-8 sec-Butylbenzene NO uglL 0.50 1 1212011915:29 135-98-8 tert-Butylbenzene NO uglL 0.50 1 12/2011915-29 98-06.6 Carbon tetrachloride NO uglL 0,50 1 12/20/19 15:29 56.20.5 Chlorobenzene NO uglL 0.50 11 1212011915:29 108-90-7 Chloroethane NO uglL 1,0 1 12/20/1915:29 75-00-3 Chforotorfn . NO uglL 0.50 1 12/20119 15.29 67-66-3 Chloromethane NO uglL 1.0 1 12120/1915:29 74-87-3 2-Chlorotoluene NO uglL 0.50 1 12/2011915:29 95-49-8 4-Chlorotoluene NO uglL 0.50 1 12/2011915.29 106-43-4 1,2-Dibromo-3-chloropropane NO uglL 1.0 1 1212011915:29 96-12-8 Dibromochloromethane ND uglL 0.50 1 1212011915:29 124-48-1 1,2-Dlbromoethane (FOB) NO uglL 0,50 1 12/20/19 15:29 106-93-4 ❑ibromamethane NO ug/L 0.50 1 12/7011915:29 74-95-3 1,2-Dichloroberizene NO uglL 0.50 1 1212011915.29 95.50-1 15-❑ichlarobenzene NO uglL 0.50 1 1212011915,29 541-73-1 14-Dichlarobenzene ND ug1L 0.50 1 12/2011915:29 106-46-7 Dichlorodifluoromethane ND uglL 0.50 1 1212DM915-29 75-71-8 1,1-Dichloroethane NO uglL 0,50 1 12/20/1915.29 75-34-3 1,2-Dichloroethane NO uglL 0.50 1 12120/1915:29 107-06-2 1,1-Dichloroethene ND uglL 0.50 1 12120/1915:29 75-35.4 cis-1,2-Dichlaroethene NO uglL 0.50 1 1212011915:29 156-59-2 trans-1 ,2-Dichioroethene NO uglL 0.50 1 12/20119 15:29 165-60-5 1,2-Dichloropropane ND uglL 0.50 1 1212011915:29 78.87-5 1,3-0ichloropropane ND uglL 0,50 1 1212011915-29 142-28.9 2,2-Dichloropropane NO uglL 0.50 1 12/20/1915:29 594-20-7 1,1-Dichloropropene NO uglL 0,50 1 12/20/1915:29 563-58-6 cis -1,3-0ichIaropropene ND uglL 0.50 1 12120/1915:29 10061-01.5 tran s-1.3-Dichlotopropene N❑ uglL 0-50 1 1212011915,29 10061-02-6 ❑iisopropyl ether NO uglL 0 50 1 12/20/19 15.29 108-20-3 Ethylbenzene NO ug1L 0.50 1 1212011915:29 1OD-41-4 Hexachloro-1,3-butadiene ND uglL 2,0 1 12/2011915.29 87-68-3 Isopropylbenzene (Cumene) NO uglL 0,50 1 12/20/19 15.29 98-82-8 Methylene Chloride NO ug11- 2.0 1 12120/19 15,29 75-09-2 Methyl -ten -butyl ether NO uglL ❑.50 1 1212009 15:29 1634-04-4 Naphthalene ND uglL 2 0 1 12/20/19 15.29 91-20.3 n-P(opylbenzene NO uglL 0 50 1 12/20/19 15:29 103-65-1 Styrene NO uglL 0.50 1 12/20119 1 5:29 100-42-5 1,1,1.2-TetrachIoroethane ND uglL 0 50 1 1212009 15:29 630-20-6 1,1,2,2-TelrachloroeIhane ND uglL 0.50 1 12/2011915,29 79-34-5 Tetrachloraelhene ND uglL 0.50 1 1212011915:29 127-18-4 REPORT OF LABORATORY ANALYSIS This rep on shall not" reprod uceu, except in full. Date: 12/24/2019 10741 AM without the written consent of Pace Analyticai Services. LLC Page 20 at 36 aceftylical www'PaWabs.rans ANALYTICAL RESULTS Project: Pit Slop BP Pace Project No.: 92457416 Pace Analytical Services, LLC 960d kinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: TRIP BLANK Lab Ito: 92457416009 Collected: 12112119 00.00 Received: 12/13/19 14:28 Matrix: Water Parameters Results Emits Report Limit OF Prepared Analyzed CAS No. Qual 62006 MSV Toluene 12,3-Trichlorobenzene 1, 2,4- Tric hlar obenzene 1,1,1 •Trichloroethane 1, 1, 2-Trichloroethane Trichloroethene Trichlorofl uoromethane 1,2,3-Trichloropropa ne 1, 2,4-Tdmelhylb enzene 1,3,5-Trimethyibenzene Vinyl chloride m&p-Xylene o-Xyiene Surrogates 1,2-Dlchioroethane-d4 (S) 4-13romofluorobenzene (S) Toluene-d8 (S) Dale: 12/24/2019 10:41 AM Analytical Method: SIN 6200E NO ug/L NO ug/L NO ug/L NO ug/L ND uglL NO ug/L NO uglL ND uglL ND ug/L NO uglL NO ug/L ND ug/L NO ug/L 94 % 95 % 101 % 0.50 1 12/20/19 15:29 108.88-3 20 1 1212011915-29 87-61.6 2.0 1 12/20119 15!29 120.82-1 0.50 1 1212011915:29 71-55-6 0.50 1 1212011915:29 79-00-5 0.50 1 12120/19 15:29 79-01-6 1.0 1 1212011915:29 75-69-4 0,50 1 1212011915:29 96-18-4 0.50 1 12/2011915:29 95-63-6 0,50 1 12/20/19 15:29 108-67-8 1.0 1 12120119 15:29 75-01-4 1.0 1 12/20/19 15:29 179601-23-1 0,50 1 12/20/1915:29 9547-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This rmpan shall not be reproduced, except in Full, wilhout the written consent of Pace Analytical Services, LLC -i 2120119 15-29 17060-07-0 12120119151-29 460-00-4 12/2011915:29 2037-26-5 Page 21 of 36 ay aceAnal0cal wwr.pacellbs.eom [QUALITY CONTROL DATA Project: Pit Stop BP Pace Project No.. 92457416 Pace Analytical Services, LLG 9800 KinceyAve. Sidle 100 Huntersville, NC 2B07b (704)875.9092 QC Batch: 516087 Analysis Method: SM 62008 QC Batch Method: SM 62009 Analysis Descriptiom 6200B MSV Associated Lad Samples: 92457416001, 92457416002, 92457416004, 92457416005, 92457416006, 92457416007, 92457416008, 92457416009 METHOD BLANK: 2765261 Matrix: Water Associated Lab Samples: 92457416001, 92457416002. 92457416004, 92457416005, 92457416006, 92457416007, 92457416003. 92457416009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1, 1, 1, 2-Tetrachloroeth ane ug1L NO 0.50 12/20/19 15:11 1, 1, 1 -Trichl oroethan a uglL ND 0.50 1212011915:11 1,1,2,2-Tetrachlaroethane ug1L ND 0.50 1212011915:11 1.1,2-Trichtoroethane ug1L NO 0.50 12/2011915,11 1,1-DichIornethane uglL ND 0.50 1212011915:11 11-Dichlaroethene uglL NO 0.50 12120M915:11 1,1-Dichloropropene uglL ND 0.50 121210915:11 1,2,3-Trichiorobenzene ug1L ND 2,0 12120/1915:11 1,2,3-Trichloropropane uglL ND 0.50 12120/1915:11 1,2,4-Trichlorobenzene uglL NO 2.0 12120/1915:11 1,2,4-Trimethylbenzene ug1L ND 0.50 1212011915:11 1,2-Dibromo-3-chloropropane uglL NO 1.0 12J2011915:11 1,2-Dibromoethane (EDB) uglL NO 0,50 12/20/19 15:11 1,2-Dichlorobenzene ug1L NO 0.50 12/20/19 15.11 12-Dichloroethane uglL NO (1.50 12/20/19 15:11 1,2-Dichloropropane uglL NO 0,50 121201191511 1.3,5-Trimethylbenzene uglL NO 0,50 1212011915:11 1,3-Dichlorobenzene uglL NO 0.50 1212011915:11 1,3-Dichloropropane uglL ND 0.50 1212011915:11 1,4-Dichlorobenzene ug)L NO 0.50 1212011915:11 2,2-Dichloropropane uglL ND 0.50 1212011915:11 2-Chlorotoluene uglL ND 0,50 12/20/1915:11 4-Chlorotoiuene uglL NO 0,50 12/2011915:11 Benzene uglL N❑ 0.50 1212011915:11 Bromobenzene ug1L ND 0.50 12/20/1915,11 Bromachloromethane ug& NO 050 12/20/19 15 11 Bromodichloromethane uglL NO 0,50 1212011915.11 Bramniorm uglL NO 0.50 12/2011915:11 Bromomethane uglL NO 5.0 12120/1915:11 Carbon tetrachloride uglL ND 0,50 12/20/19 15:11 CWorobenzene uglL NO 0.50 1212011915.11 Chloroethane ug1L NO 1.0 12/20/19 15.11 Chloroform ug1L NO 0 50 12/20/19 15:11 Chiaromethane uglL ND 1.0 12W2011915:11 cis-1,2-Dichloroethene ug)L ND 0,50 1212011915'11 cis-1,3-Dichlorepropen e uglL ND 0,50 12/20/19 15A 1 D ibromochl o rom ethane uglL N❑ 0.50 1212011915711 Dibromomethane uglL ND 0.50 12120119 15: 11 Dichlorodifluoromethane uglL NO 050 1212011915'11 ❑iisopropyl ether ug1L ND 0.50 12120/19 15:11 Rosuhs presented on this page are in the unils indicated by the "trnI10 column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 12/24/2019 10:41 AM without the written eonsenI of Pace Analytical Services, LLC Page 22 of 36 _ . aceAnal yical www.pacelrbs.cora QUALITY CONTROL DATA Project: Pit Stop BP Pace Projecl No.: 92457416 Pace Analytical Services, LLC 9800 Kin coy Ave Suite 1no Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 2765261 Matrix. Water Associated Lab Samples: 92457416001, 92457416002, 92457416004, 92457416005, 92457416006, 92457416007, 92457416008, 92457416009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene ug1L ND 0.5U 1212011915:11 Hexachloro-1,3-butadiene uglL ND 2.0 12120/1915:11 lsopropylbenzene (Cumene) ug/L. ND 0.50 12120/19 15:11 m&p-Xylene ug/L ND 1.0 12/20119 15.11 Methyl-tert-butyl ether uglL NO 0.60 12/20/19 15:11 Methylene Chloride ug/L NO 2.0 12/20/19 15:11 n-Butylbenzene 4L NO 0.50 1212011915:11 n-Propylbenzene uglL N❑ 0.50 121201191511 Naphthalene ug1L ND 2.0 12/20/1915:11 o-Xylene uglL NO 0,50 1212011915:11 sec-Butylbenzene ug1L NO 0.50 12/20/1915:11 Styrene ug/L ND 0,50 12/2011915:11 tert-Butylbenzene ug1L N❑ 050 12/20/19 15:11 Tetrachioroethene ug/L ND 0 50 12/20/19 15:11 Toluene ug1L ND 0,50 1212011915:11 trans- 1,2-Dichloroethene ug1L ND 050 12/20/19 15:11 trans-1,3-Dlchloropropene ug/L ND 0,50 1212011915:11 Trichloroethene uglL ND 0.50 12120/1915.11 Trichlorofluoromethane ug1L NO 1.0 1212W1915:11 Vinyl chloride ug1L ND 1.0 12/20119 15:11 1,2-Dichloroethane-d4 (S) °% 93 70-130 12/20/19 15.11 4-Bromofluorobenzene (S) % 97 70-130 12/20/19 15:11 Toluene-d8 (S) % 101 70-130 12/20/19 15:11 LABORATORY CONTROL SAMPLE' 2765262 Parameter Spike LCS LCS Units Conc. Result A Rec % Rec Limits Qualifiers 1.1.1,2-Tetrachloroethane ug1L 50 52.3 105 60-140 1.1.1-Trichloroethane ug1L 50 50.6 1D1 60-140 1,1,2,2-Tetrachloroethane uglL 50 50.2 100 60-140 1,1,2-Trichloroethane ug1L 50 50.8 102 60-140 1,1-Dichloroethane uglL 50 49.4 99 50-140 1,1-Dichloroethene uglL 50 47.9 96 BO-140 1,1-Dichloropropene uglL 50 53.7 107 60-140 1,2,3-Trichlorobenzene ug/L 50 56.6 113 60-14D 1,2,3-Trichloropropane uglL 50 49.6 99 60-140 1,2A-Trichlorohenzene ug/L 50 55.6 111 60-140 1,2,4-Trimethylbenzene ug/L 50 52.5 105 6D-140 1,2-Dibromo-3-chtoropropane ug)L 50 54.4 109 60-140 1,2-Dibromoethane (EDB) ug/L 50 53.2 106 6D-140 1,2-Dichlorobenzene ug1L 50 54.2 108 60-140 1,2-Dichloraethane uglL So 45.4 91 60-140 1,2-❑ichloropropane uglL 50 51.5 103 60-140 Resuils presented on this page are In the units Indicated by the "Units" col until except where an alternate unit is presen led to the right of the re skill, REPORT OF LABORATORY ANALYSIS This report shall not he reproduced. except in full, Date: 12/2412019 10:41 AM without the written consent a Pace Analytical Services, LLC Page 23 of 36 aceAnalXical Www,p&E818115.COhV QUALITY CONTROL DATA Project: Pit Stop BP Pace Project No.. 92457416 LABORATORY CONTROL SAMPLE: Parameter 2765262 Units Spike Conc. LCS Result LCS °% Rec % Rec Limits 1,3,5-Trimethylbenzene ug& 50 52.4 105 60-140 1,3-Dichlorobenzene uglL 50 52.9 106 60-140 1,3•Dichloropropane ug1L 50 53,1 106 60-140 1,4•Dichlorobenzene uglL 50 53.6 107 60-140 2,2-Dichloropropane uglL 50 58.0 116 60.140 2-Chlorotoluene uglL 50 51.3 103 60-140 4-Chlorotoluene uglL 50 53.1 106 50-140 Benzene uglL 50 51.7 103 60-140 Bromobenzene ug& 50 54.0 108 60-140 Sromochlorornethane ug1L 50 50.1 100 60-140 Bromodichloramethane uglL 50 51.2 102 60-140 Bromoform uglL 50 54.2 108 60-140 Bromomethane uglL 50 52.5 105 60-140 Carbon tetrachloride uglL 50 52.8 106 60-140 Chlerobenzene ug1L 50 51 A 103 60-140 Chlorcethane uglL 50 53,3 107 60-140 Chloroform ugIL 50 48.6 97 60.140 Chloromethane uglL 50 40,5 81 60-140 cis-1,2-Dichloraethene uglL 50 48.3 97 60.140 cis-1,3-Dichlorepropene uglL 50 52,9 105 W-140 Dibromochloromethane uglL 50 55,2 110 60-140 Dibromamethane uglt- 50 51.7 103 60-140 ❑Ichloradllluoromethane uglL 50 46.4 93 60-140 Dlisopropyl ether uglL 50 48.2 99 60-140 Ethylbenzene uglL 50 51.2 102 60-140 Flexachloro-1,3-butadiene uglL 50 53.2 106 60-140 Isopropylbenzene (Cumene) u911- 50 52.2 104 60-140 m&p-Xylene uglL 100 104 104 60-140 Methyl-tert-butyl ether uglL 50 52.6 105 60-140 Methylene Chloride uglL 50 45.2 90 60-140 n-Butylbenzene uglL 50 53.5 107 60-140 n-Propyibenzene uglL 50 50.7 101 M140 Naphthalene U91L 50 56.6 113 60.140 o-Xylene uglL 50 51.9 104 60.140 sec-Butylbenzene uglL 50 51.9 104 60-140 Styrene uglL 50 54.6 109 60-140 teri-Butylbenzene uglL 50 44.5 89 60.140 Tetrachloroethene uglL 50 51.5 103 60-140 Toluene uglL 50 49.5 99 60-140 trans-1,2-Dichloreethene u911- 50 49.2 98 60-140 trans -1,3-Dichloropropene uglL 50 52.4 105 60-140 Trichloroethene uglL 50 51.7 103 60-140 Trichlorofluoromettlane uglL 50 46.8 94 60-140 Vinyl chloride ugli- 50 50.1 100 60-140 1,2-Dichloroethane-d4 (S) % 94 70-130 4-Bromofluorobenzene (5) °% 98 70-130 Toluene-d8 (S) % 98 70-130 Pace Analytical Services, LLC s800 Kinsey Ave. Suite 100 Hu rite rsville, NC 28078 t7fl4j875-9092 Qualifiers Results presented on this page are in the units indicated py the "Units" Lolumn except where an alternate unit Is presented to the nght of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in cull, Date: 12124/201910.-41 AM without We written consent or Pace Analytical Services, LLC Page 24 of 36 aceAnalyticai www.>tri�elAtiasam DUALITY CONTROL DATA Project: Pit Stop BP Pace Project No.: 92457416 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2765263 2765264 Pace Analytical Services, LLC 9000 Kincey Ave Suite 100 Huntersvilte, NC 29078 t704j675-9092 MS MSO 92457416008 Spike Spike MS MSD NIS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1, 1. 1, 2-Tetrachloroethane uglL NO 20 20 23.4 23.9 117 120 60-140 1,1,1-Trichloroethane uglL ND 20 20 21.8 23.0 109 115 60-140 1,1,2,2-Tetra chi oroethane uglt. ND 20 20 2Z3 22.3 112 112 60-140 1,1,2-Trichloroethane uglL NO 20 20 22.1 23A 110 115 60-140 1,1-Dichloroethane ug/L NO 20 20 21.5 21.6 108 108 60-140 1,1-Dichioroethene ug1 N❑ 20 20 21.5 21.3 108 106 60-140 II J-Dichloropropene uglL ND 20 20 22.8 22.5 114 112 60-140 1,2,3-Trichlorobenzene uglL ND 20 20 25.3 23.9 127 120 60-140 1,2,3-Trichloropropane uglL ND 20 20 22.2 22.1 ill 111 60-140 1,2,4-Trichlorobenzene uglL N❑ 20 20 23.5 24.0 118 120 60-140 1,2,4-Trimethylbenzene ug1L ND 20 20 23.1 23.3 115 117 60-140 1,2-Dibromo-3-chloropropane uglL ND 20 20 22.9 23.3 115 116 60-140 12-Dibromoethane (EDB) uglL ND 20 20 233 23.2 116 116 60-140 1,2-Dichiorobenzene uglL NO 20 20 22.9 23.4 115 117 60-140 1,2-Dichioroethane uglL ND 20 20 19A 19.9 97 100 60-140 1,2-Dichloropropane uglL NO 20 20 22.5 23.5 113 1i8 M140 1,3,5-Trimethylbenzene uglL ND 20 20 22.6 23.0 113 115 60-140 1,3-Dichlorobenzene ugIL NO 20 20 22.4 22.8 112 114 60-140 1,3-Dichloropropane uglL ND 20 20 22.9 23.3 114 117 60-140 1,4-Dichlorobenzene Ug1L NO 20 20 22.9 233 115 117 60-140 2,2-❑ichloropropane ug1L N❑ 20 20 225 23.3 113 116 60-140 2-Chlorotaluene uglL NO 20 20 22-2 22.5 ill 113 60-140 4-Chlorotoluene ug1L NO 20 20 221 22.9 ill 115 60-140 Benzene ug1L 0.80 20 20 23.3 24.5 113 118 60-140 Bromobenzene uglL ND 20 20 23.7 23.5 119 117 60-140 Bromochioramethane u91L NO 20 20 221 22.1 111 110 60-140 Bromodichloromethane uglL ND 20 20 23.1 236 115 118 60-140 Bromoform uglL NO 20 20 22.9 23.3 114 116 60-140 Bromameihane uglL NO 20 20 23.3 23.5 117 118 60-140 Carbon tetrachloride q1 NO 20 20 23.2 241 116 121 60-140 Chlorobenzene uglL NO 20 20 23.3 23.2 117 116 60-140 Chloroethane uglL NO 20 20 28.6 28.4 143 142 60-140 Chloroform uglL NO 20 20 22.2 222 111 111 60-140 Chloromethane ug1L NO 20 20 13.0 14A 65 71 60.140 cis-1,2-Dichloroethene uglL ND 20 20 21.3 21.5 107 108 60-140 cts-1,3-Dichloropropene uglL ND 20 20 22.4 23.3 112 117 60.140 Dibromachioromethene uglL ND 20 20 23.8 23.9 119 119 60-140 Dibromomelhane ug1L ND 20 20 22.3 23.7 ill 118 60-140 Dichlorodifluoromethane ug)L ND 20 20 18.2 17Z 91 88 60-140 Diisopfopyl ether ug/L 49.4 20 20 73.2 72.8 119 117 60-140 Ethylbenxene uglL NO 20 20 22.8 22.9 114 115 60-140 Hexachloro-1,3•butadiene uglL N0 20 20 22.3 22.2 112 111 60-140 lsopropylbenzene {Cumene} uglL NO 20 20 234 23.6 117 118 80.140 m&p-Xylene uglL NO 40 40 45.7 46.6 114 116 60-140 Methyl-tert-butyl ether uglL 6.5 20 20 29.1 29.3 113 114 60-140 Methylene Chloride uglL NO 20 20 207 205 104 103 60-140 Results presentrd on this page are in the units Indicaled by the "UnIts" column excaptwhare an attemate unit is presented to therlght of She result. REPORT OF LABORATORY ANALYSIS 4 0 1 1 s 0 2 1 1 0 2 3 4 2 2 2 2 3 1 4 5 } a 2 2 1 4 0 1 M1 0 8 1 This report shall not be reproduced, except in Full. Date: 12/24/2019 10A l AM without the wri lien consent or Pace Ana Iysical Services, LLC Page 26 of 36 _ IeAnapical r www pecaiabe.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9B0G Kincay Ave Suite l00 Huntersville. NC 2807a (794)876-9092 Project Pit Stop BP Pace Projecl No.- 92457416 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2765263 2765264 MS MSD 92457416GO8 Spike Spike MS MSD MS MSO % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Quat n-Butylbenzene ug/L ND 20 20 22.0 22.3 110 111 613-140 1 n-Propylbenzene ug1L ND 20 20 22.0 22.6 110 113 611-140 3 Naphthalene ug1L NO 20 20 29.5 24.9 148 125 W140 17 M1 o-Xylene ug& NO 20 20 22.7 23.2 114 116 60-140 2 sec -Butyl benzene ugfL 0.54 20 20 23.3 23,3 114 114 60-140 0 Styrene ug1L N❑ 20 20 23.5 23.8 117 119 60-140 1 teft-Butylbenzene ug1L ND 20 20 20.1 20.6 101 103 60-140 2 Tetra ch loroethene ug1L ND 20 20 21.9 22.5 110 113 60-140 3 Toluene ug1L ND 20 20 21.9 23.0 109 115 60-140 5 trans- 1,2-Dichloreethene ug1L NO 20 20 21.4 21.5 107 108 60-140 1 trans- 1,3-0ichloropropene ug?L ND 20 20 21.5 22.7 108 113 60-140 5 Trichloroethene ug/L NO 20 20 22.3 22.7 112 113 60-140 2 Trichlorafluoramethane ugJL N❑ 20 20 21.4 21.2 107 106 60-140 1 Vinyl chloride uglL ND 20 20 21 A 20.8 109 104 60-140 5 1,2-Dichloroethane-d4 (S) % 94 94 70-130 4-Bromofluorobenzene (S) % 98 99 70-130 Toluene -dB (S) % 98 99 70-130 Results presented on this page are in the units indicated by the "ilniIn" column exceptwhere an alternate unit Is presented to She rWht of the result. REPORT OF LABORATORY ANALYSIS This iepori shall not be reproduces, except in full. Date: 12/24/2019 10:41 AM without the written consent at Pace Analytical Services, LLC Page 26 of 36 ieAnalydcal" www.paeelatxam QUALITY CONTROL DATA Project: Pit Stop BP Pace Project No.: 92457416 qC Batch- 516241 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Descriptlon: 620GB MSV Associated Lab Samples: 92457416003 METHOD BLANK: 2766036 Associated Lab Samples: 92457416003 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1.1,1,2-Tetrachloroethane u91L ND 0.50 1212211911.46 1,1,1-Trichloroethane ugfL NO 0.50 1212211911:46 1,1,2,2-Tetrachloroethane ug1L ND a50 12/2211911;46 1,1,2-Trichloroethane ug1L ND 0.50 1212211911:46 1,1-Oichloroethane uglL NO 0.50 12/2211911A6 1,1-Dichloroethene ug1L ND 0.50 1212211911:46 1,1-Dichioropropene ug1L NO 0.50 1212211911:46 1,2,3-Trichlorobenzene ug1L NO 2.0 1212211911:46 1,2,3-Trich(oropropane uglL NO 0.50 12122M911A6 1,2,4•Trichlorobenzene uglL ND 2.0 12122M911:46 1,2,4-Trimethylbenzene ug1L NO 0.50 12/22/1911:46 11,2-Dibroma-3-chloropropene ug)L NO 1.0 12/22/19 11:46 1,2-Dibromoethane {EDBj ugfL NO 0,501 12/22/19 11:46 1,2-❑ichlorobenzene ug1L NO 0,50 12/22/19 11:46 1,2-Dichlorcethane ug1L NO 0.50 12122/1911:46 1,2 Dichlarapropane uglL NO 0,60 12/22/19 11:46 1,3,5-Trimethyfbenzene ug1L NO 0.50 1212211911:46 1,3-Dichicrobenzene uglL NO 0,50 1212211911:46 1,3-Dichioropropane uglL NO 0.50 1212211911:46 IA-❑ichlorobenzene ugfL ND 0.50 12/2211911:46 2,2-Dichloropropane uglL ND 0.50 1212211911:46 2-Chlarotoiuene uglL NO 0.50 1212211911:46 4-Chlorotoluene uglL NO 0.50 12122/1911:46 Benzene ug1L NO 0 50 12/22/19 11:46 Bromobenzene uglL NO 050 12/22/19 11:46 Bromochloromethane uglL NO 0.50 12/2211911.46 Bromodichloromethane ugfL ND 0.50 1212211911-46 Bromoform ! uglL NO 0.50 12122/1911:46 Bromomefhane ug1L NO 5.0 1212211911:46 Carbon tetrachloride ug1L NO 0.50 12/22/19 11 AG Chlorobenzene uglL NO 0.50 12/22/1911:46 Chloroethane uglL N❑ 1.0 1212211911:46 Chloroform ug1L NO 0.50 12/2211911:46 Chloromethane uglL NO 1.0 12/22/19 11:46 cis-1,2-Dichloroethene ug1L NO 0.50 12/22/19 11'46 cis-1,3-Dichloropropene ug1L NO 0.50 1212211911:46 D€bromochioromethane uglL NO 0,50 121220911A6 Dibromomethane uglL NO 0.50 1212211911:46 Dichlorodifluaromethane uglL NO 0,50 12/2211911A6 ❑ilsopropyl ether uglL NO 0.50 12122M9 W46 Ethylbenzene uglL NO 0.50 12122M911,46 Qualifiers Pace Analyticai Services, LLC 9BOO Kinsey Ave Suite 10U Huntersville, NC 28078 (704)875-9092 Results presented an this page are in the units indicated by the "Units" call nn except where an aftvmate unit is presenteq to the right ar the result. REPORT OF LABORATORY ANALYSIS This report shall nat be reproduced, except in full, Date: 12/2412019 10:41 AM withoutthe written consent of Pace Ans5yfical Services, LLC Page 27 oT 36 Iac e Anavical (�www.pactstabs,com QUALITY CONTROL DATA Project: Pill Stop BP Pace Project No.: 92457416 METHOD BLANK: 2766036 Associated Lab Samples: 92457416003 Parameter Units Matrix: Blank Resull Water Reporting Limit Analyzed Hexachlorc-11,3-butadiene uglL ND 2.0 12/22/19 11746 tsopropy ibenzene (Cumene) ug1L NO 0.50 12122119 11:46 m&p-Xylene ug1L NO 1.0 12122/19 11:46 Methyl-tert-butyl ether uglL ND 0.50 12/22/19 11:46 Methylene Chloride ugIL ND 2.0 12/2211.9 11:46 n-Butylbenzene uglL NO 0,50 1212211911:46 n-Propylbenzene uglL ND 0.50 12122119 11 A6 Naphthalene uglL NO 2.0 12/2211911,46 o-Xyfene ug1L NO 0.50 1212211911:46 sec-Butylbenzene ug1L NO 0.50 12/2211911:46 Styrene uglL NO 0.50 12/2211911.46 ter[-Butylbenzene ug1L NO 0.50 1212211911,46 Tetra chloroethene ug1L ND 0.50 1712211911;46 Toluene ug1L NO 0.50 12122J1 9 11:46 trans- 1, 2- Dichloroe the ne uglL NO 0.50 12122/1911:46 trans- l,3-Dichloropropene uglL NO 0.50 1212211911:46 Trichlorcethene ug1L NO 0.50 12R2119 11 A6 Trichloroiluoromethane ug1L ND 1.0 1212211911:46 Vinyl chloride ug1L ND 1.0 12122/19 11:46 1,2-Dichlofoethane-d4 (S) % 90 70-130 12122M9 11:46 4-Bromofluorobenzene (S) % 96 70-130 12/22/19 11:46 Toluene -dB (S) % 102 70.130 12122/19 11:46 LABORATORY CONTROL SAMPLE: 2766037 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 huntersville, NC 28078 (704)875-9092 Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits ❑ualifters 1,1,1,2-Tetrachloroethane uglL 50 55A 111 60-140 1,1,1-Trlchloroethane ug1L 50 54.0 108 60-140 1.1,2,2-Tetrachloroethane ug1L 50 52.0 104 60-140 1,1,2-Trlchloroethane uglL 50 51.5 103 60-140 1,1-Dichtoroethane ug1L 50 51Z 102 60.140 1,1-Dichlorcethane uglL 50 50.4 101 60-140 11-01chloropropene uglL 50 56.6 113 60-140 1,2,3-Trichlorobenzene uglL 5o 62.5 125 60-140 1,2,3-Trichloropropane uglL 50 52,2 104 60040 12,4-Trichlorobanzene ug1L 50 51.0 122 60.140 1,2,4-TOmethyl benzene ug1L 50 57.2 114 60-140 1.2-Dibromo-3-chlaropropane ug1L 50 57.2 114 60-140 1,2-Dibromoethane (EDB) uglL 50 55.7 111 60-140 1.2-Oichlorobenxene uglL 54 57.7 115 60-140 1,2-Dichloroethane uglL 50 47.9 96 60-140 1,2-Dichloropropane uglL 50 52.6 105 60-140 1,3,5-Trimethylbenzene ug)L 50 56.3 113 60-140 1,3-Dichiorobenzene uglL 50 56.7 113 60-140 Results presented on this page are In the units Indicated by the "Units" column except where nn attemale unrl is presented to the right or the mull. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date, 12/24/2019 10:41 AM without the written consent of Pace Analytical Services, LLC. Page 28 c136 aceAnalytical www.paeel+tEs.00rn QUALITY CONTROL DATA Project: Pit Stop BP Pace Project No, 92457416 LABORATORY CONTROL SAMPLE: 2766037 Pace Analytical Servltas, LLC 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Parameter Units Spike Conc. LCS Result LCS % Roo % Rec Limits Qualifiers 1,3-Dichloropropane uglL 50 55.8 112 60-140 1,4-Dichlorobenzene uglL 50 57.8 116 60.140 2,2-Dichloropropane ug1L 50 62.8 126 60-140 2-Chtorotoluene Ug1L 50 55.0 110 60-140 4-Chlorotoluene uglL 50 56.4 113 60-140 Benzene ug/L 50 52.7 105 60-140 Bromobenzene uglL 50 57.5 115 60-140 Bromochloromettlane uglL 50 5Z3 105 60.140 Bromodichloromethane ug& 50 53.6 107 60-140 Bromoform uglL 50 57A 114 60-140 Brumomethane uglL 50 53.2 106 60-140 Carbon tetrachloride uglL 50 56.1 112 60-140 Chlorobenzene uglL 50 54.5 109 60.140 Chloroelhane uglL 50 58.6 117 60-140 Chloroform uglL 50 50.6 101 60-140 Chloromethane uglL 50 41.2 82 60-140 cis-1,2-Dichloreethene ugiL 50 50.1 100 60-140 cis-1,3-Dlch1aropropene ug1L 50 55,7 11l 60-140 Dibromochloromethane ug/L 50 58.2 116 60-140 Dibromomethane uglL 50 55.6 111 60-140 ❑ichlerodifluorornethanc uglL 50 48.1 96 60.140 Diisopropyl ether ug1L 50 51.2 102 60.140 Etrlylbenzene uglL 50 53.8 108 60.140 Hexachloro-1,3-butadiene ugll- 50 57.5 115 60-140 Isopropylberizene (Cumene) uglL 50 56.1 112 60.140 m&p-Xylene ug/L 100 109 109 60-140 Methyl-tert-butyl ether uglL 50 54.8 110 60-140 Methylene Chloride uglL 5D 46.8 94 6D•14D n-Butylt}enzene uglL 50 58A 117 60.140 n-Propylbenzene uglL 50 54.9 110 60-140 Naphthalene uglL 50 62 0 124 60-140 c-Xylene uglL 50 55.0 110 50-140 sea-Butylbenzene uglL 50 58.3 113 60-140 Styrene uglL 50 5&0 116 60-140 tert-Butylbenzene uglL 50 47,6 95 60-140 Tetrachloroethene uglL 50 55.3 111 60-140 Toluene ug1L 50 51.5 103 60-140 trans-12-Dichtoroethene uglL 50 51.0 102 60-140 trans-1,3-Dichloropropene uglL 50 55.0 110 60-140 Trichloroethene uglL 50 53.5 107 60-140 Trichlorafiuoromethane uglL 50 49.9 100 60-140 Vinyl chloride uglL 50 51.8 104 60-140 1,2-Dichloroethane-0 (S) % 92 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 Results presented an this page are to the units indicated by the "Units" cotumrf except where an alternate unit is presented to thst right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reprodured, e#cepl in full, bate' 12/24/2019 10,41 AM without the written consent of Pace Analytical Services, LLC Page 29 of 36 aceArialyticai www.pecdahe.eorn QUALITY CONTROL DATA Project; Pit Stop BP Pace Project No.; 92457416 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2766035 2766039 Parameter 92457416003 Units Result MS Spike Conc. MSD Spike Cone. MS Result 1,1,1.2-Tetrachloraelhane ug1L ND 200 200 220 1.1,1-T6chioroethane uglL Nib 200 200 219 1.1,2,2- Tel rachloroethane ug1L ND 200 200 210 1,1,2-Trichloroethane uglL NO 200 200 214 1.1-Dichloroathane uglL N❑ 200 200 216 1,1-Dichloroethene ug1L ND 200 200 216 1,1-Dichlorapropene uglL ND 200 200 238 12,3-Trichlorobenzene uglL ND 200 200 207 1,2,3-Trichloropropane ug& ND 200 200 219 1,2,4-Trichlorobenzene uglL N❑ 200 200 208 1,2,4-Trimethylbenzene ug1 222 200 200 439 1,2-❑ibromo-3-chloropropane ug1L N❑ 200 200 216 1,2-Dibromoethane {EDB) u911- NO 200 2D0 218 12-Dichlorobenzene uglL ND 200 200 221 1,2-Dichloroethane uglL ND 200 200 201 1,2-Dichloropropane uglL ND 200 200 222 1,3,5-Trimelhylbenzene ug1 55.8 200 200 280 1,3-Dichlorobenzene uglL ND 200 200 218 1,3- Diehl oropropane uglL NO 200 200 222 1,4-D(chlorobenzene ug& NO 200 200 219 2,2-Dichloropropane uglL ND 200 200 221 2-Chlorotoluene uglL ND 200 200 229 4-Chlorotoluene uglL ND 200 200 223 Benzene uglL 1630 200 200 1820 Bromobenzene ug1L ND 200 200 228 Bromochloromethane ug/L ND 200 200 213 Bromodichloromelhane uglL ND 200 200 218 Bromoform u91L ND 200 200 221 Bromomethane ug)L NO 200 200 150 Carboy+ tetrachloride uglL NO 200 200 234 Chiorobenzene uglL ND 200 200 223 Chloroethane uglL ND 200 200 277 Chloroform uglL NO 200 200 223 Chloromethane uglL ND 200 200 146 cis-1,2-Dlchloroethene uglL NO 200 200 209 cis -1,3-Di chi oropropene uglL ND 200 200 221 Dibromochloromethane uglL NO 200 200 224 Dibromomethane uglL ND 200 200 227 Dichloradifluorornelhane uglL N❑ 200 200 182 Diisopropyl ether uglL 37.7 200 200 235 Ethylbenzene uglL 240 200 200 457 Hexachlora-1,3-butadiene uglL ND 200 200 206 Isopropylbenzene (Cumene) uglL 36.3 200 200 263 m&p-Xylene uglL 128 400 400 572 Methyl-tert-butyl ether uglL 130 200 200 346 Methylene Chloride uglL ND 200 200 202 Pace Analytical Services, LLC 9800 Kinsey Ave Suite Ian Huntersville. NC 28076 (7o4)s7h-9o92 MSD Result MS 1A Rec MSD % Rec % Rec Limits RPL1 Qual 211 110 105 60-140 4 214 109 107 60-140 2 201 105 100 60-140 5 210 107 105 60-140 2 209 108 104 60-140 3 207 108 103 60-140 4 228 119 114 60-140 4 222 101 109 60-140 7 198 109 99 60.140 10 217 104 109 60-140 4 437 109 107 60-140 1 216 108 108 60-140 0 208 109 104 60-140 4 215 111 108 60-140 3 186 100 93 60-140 8 219 111 1 D9 60-140 2 272 112 105 60-140 3 214 109 107 60-140 2 211 111 106 60-140 5 217 109 109 50-140 1 213 111 106 60-140 4 218 114 109 60-140 5 218 111 109 60-140 2 1860 95 113 60-140 2 218 114 109 60.140 5 206 106 103 60-140 3 216 109 108 60-140 1 208 111 104 60-140 6 192 75 96 60-140 24 225 117 112 60-140 4 213 111 106 60-140 5 280 139 740 60-140 1 211 112 105 60-140 6 145 73 73 60-140 1 201 104 100 60-140 4 216 111 106 60-140 2 214 112 107 60-140 5 218 113 109 60-140 4 169 91 85 M140 7 230 99 96 60-140 2 452 108 106 60-140 1 211 103 105 60-140 2 255 113 109 60-140 3 556 11i 107 60-140 3 331 108 100 60-140 5 197 101 98 60-140 2 Results presented on thls page are In the units Indicated by the "units" column except where an alternate unh Is presented to the fight of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date' 12/24/2019 10-41 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 36 leAi�aryticar wwlN.parelaGe.renl QUALITY CONTROL DATA Project: Pit Stop BP Pace Project No.: 92457416 Para Analytical Services, LLC 9800 Kineey Ave Suite 100 Huntersvllle, NC 20078 (704)87"092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2766036 MS 92457416003 Spike Parameter Units Result Conc. MSD Spike Conc. 2766039 MS Result MSD Result MS % Rec MSD %n Rec % Rec Limits RPD n-Butylbenzene ugll- 22.4 200 200 233 235 105 106 60-140 1 n-Propylbenzene ugll- 75,0 200 200 289 286 107 105 60-140 1 Naphthalene uglL 276 200 200 497 536 ill 130 60-140 8 o-Xylene uglL 10.6 200 200 233 223 111 106 60-140 4 see-Butyibenzene ug& NO 200 200 229 224 115 112 60-140 2 Styrene ug)L ND 200 200 229 223 114 111 60-140 3 tert-Butylbenzene uglL Nil 200 200 193 188 97 94 60-140 3 Tetrachloroethene ug1L NO 200 200 225 216 112 108 60-140 4 Toluene uglL 20.3 200 200 236 232 108 106 60-140 1 trans- 1,2-Dichloroethene ugll- ND 200 200 217 208 109 104 60-140 4 trans- 1,3-Dichleropropene uglL ND 200 200 204 203 102 101 60-140 1 Trichloroethene uglL ND 200 200 230 221 115 110 60-140 4 Trichloroiiummethane uglL IUD 200 200 217 206 108 103 60-140 5 Vinyl chloride uglL ND 200 200 214 208 107 104 60-140 3 1,2-Dichloroethene-d4 (S) % 96 98 70-130 4-Brflmotluorobenzene (S) % 98 98 70-130 Toluene-d6 (S) % 97 99 70-130 Results presented on Ihis page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right or the resuiL REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date' 12/24/2019 10:41 AM without the written consent of Pace Analytical Servlaes, LLC r■'lren Page 31 of 36 aceAna!}ical,. www.pecalaba.com QUALIFIERS Project: Pit Stop BP Pace Project No.: 92457416 DEFINITIONS OF - Dilution Factor, if reported, represents the factor appi led to the reported data due to dilution of the sample aliquot. NO - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection IImlt and below the adjusted reporting limit MOIL - Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC ZB078 (704)B75-9092 POL - Practical Ouantitation Limit. RL - Reporting limit - The lowest concentration value Ihat meets project requirements For quantilative data with known precision and bias far a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Nol Calculable. SG - Silica Gel - Clean -Lip U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chioroethylvinyi ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapler 4 for the analysis of AcrolelIt and Acrylonitrlle by EPA Method 8260. N-Nttrosodiphenytamine decomposes and cannot be separated from Dip henylamine rising Method 8270. The result reported for each analyte is a combined concentration, Pace Analytical is TN accredited. Contact your pace PM far the current list of accredited anal ytes, TN - The NELAC Institute. LABORATORIES PASI-C Pace AnaiylicaI Services - Charlotte ANALYTE QUALIFIERS M 1 Matrix spike recovery exceeded 4C limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date- 12/2412019 10:41 AM wlthout the written consent of Pace Analy4icol SarVioes, LLC Page 32 of 36 _ - aceAnalXical ' www,pacaleha.sorn r QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pit Stop BP Pace Project No_ 92457416 Lab I❑ Sample ID QC Batch Method QC Hatch 92457416001 MW-2 SM 6200B 516087 92457416002 MW-6 SM 6200B 516087 92457416003 MW-10B SM 6200B 516241 92467416004 MW-13 SM 6200B 516087 92457416005 MW-14 SM 6200B 516087 92457416006 MW-15 SM 62008 516087 9245741600T MW-16 SM 62003 516087 92457416008 MW-17 SM 6200B 516087 92457416009 TRIP BLANK SM 6200B 516057 Date: 12124/2019 10:41 AM REPORT OF LABORATORY ANALYSES This reporl shall not 6e repmducecr, except in full, without the wrinan consent ❑1 Pace AnalytcaJ Services, LLC Pace Analytical Services, LLC 9800 Kincey Ave Suite 1fl0 Huntersville. NC 26078 (704)575-B092 Analytical Method Analytical Batch Page 33 of 36 Document Name: Document Revised: February 7, 2013 Sample Corsditlon U on Recei t(SCUR) Page 1 of 2 Document No.: Issuing Authority: a�eAnaVkal F-CAR•CS-033-Rev.06 Pace Carolinas Qual Ity Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑ Sample Condition Cllent Name: upon Roceipt h� ` A Project #: Courler: [3FpdEx ❑ups ❑uSPs ❑Cllent ❑ Commercial ace ❑Other: Custody seal Present? ❑Yes Seals Intact? Oyes No Packing Material: ❑Bubble Wrap Bubble Bags []None ❑ Other Thermometer: ❑IR can ID: 22TO5$ Fype of foe: Wet ❑BIue Confer Temp ('C): _, Correction Factor: Add/subtract ('CI O.O°C Cooler Temp Corrected2NIIA, USDARegulatedSoli ( wafer sample) Did samples originate In a quarantine zone within the united State;: CA, NY, or SC {check ma psi? []Yes ❑No WO#:92457416 I� � lit lli 1 I li �11� 11 ll� 92457416 Dot dllnithibRenon rssaminIngCcntenw Z'« a JL BlolagicalTissu_e�roien7 ❑None Des ONO N/A Temp should be above freezing to VC ❑samples out of temp oriterla.5ampies an ice, coaling process has begun Did samplesoriglnate Nam afareign source 11 nte mational IV, Includint Hawaii and PuertoRicoj? ❑Yes ❑Nu Camments/Otscrepancy. Chaln of Custody Present? VeA FINo NIA 1. Samples Arrlved within Hold Time? Yes []Nq, ONJA 2- 5 ho rt He Id Time An al is 102 hr. ? clyes N A 3, Rush Turn Ara und Time Reg nested? 13yes K. i]rr1A 4. Sufficient Volume? No NIA 5. Correct Containers Used? -Pace Containers Used? es Y ONO ONO ❑N/A N/A 6. Cnntafners Intact? CIND N 7. Dissolved analysis-. Sample-; Field Rfteredi s ON. IA a. Sample Labels Match COC? -includes Date/Time/ID/Analysis Matrix- Mej V V ► QNo ONJA 9- Headspace in VCA Vials (>5-Gmm)? es No NIA 10. Trip Blank Presents Trip Blank Custody5ealsPre5ent? Yes es ❑No IYo ❑NIA NIA 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of split containers: CLIENF NOTIFICATION/RESOLUTION Field Date Required? []Yes ❑No Person contacted: Datejiime: Project Manager SCURF Review: Date: Project Manager SRF Review: I l Date: ? 's q .34 of 36 Document Name: Document Revised: February 7, 2018 e�CL'�P.ri11CrZ�' Sample CondHlen upon RecelptlSCUR) Page 1 of 2 Document No.: issuing Authority: F-CAR-CS-033-Rev.05 Pace Carolinas Quality Office •Check mark top half of box if pH and/or dechlorinatIon Is Project 9 verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DROJ8015 (water) DOC, LLHg *"Bottom half of box is to list number of bottle Wo#:92457416— PM: RP Due Date: 12/24/19 CLIENT: 92-shield SR _ m a. E & m E E a m E a ffi q m _ V E X ar E x 4 m .n � N a m _ E a m a v u C Z a .'.f <7 .L C L7 d 2 of 5 l7 Q ❑ `m Vl L7 ¢ r`� s E M l7 a 2 r� Q Z O E ❑ Dry z p 7 2 7 E i Lo 7 4O X O ch �ry G ❑ 7 _ a 9 ` 7 a � N E v� ,c t M E N �i A � S x E m 6 co E p N E � G Q E I7 1 N 3 n —�— — - S 1 N\\�'l 7 _ 8 9 Ll I 1p -.N\\ 11 12 PH Adjustment Log for Preserved Samples Sample to Type or Preservativa pH upon receipt Date preservation adjusted nmi.. presonration adltrsted Amount of Preservative added Lot It Note: whenever there is a discrepancy affecting North Carolina compifante samples, a copy of trds Farm will de sent to the North Carolina DFlJNR Certlficatlon Office 0 U. Qut of hold, incorrect presrrvotive, out of temp, incorrect containers. --Page 35 of 36 °11%vvf CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately Scr:ion A Section R Section C Regvtred Cflrnt Information: Required Project irlfonnation: Invoice tntarmalion: page. Of Cu - pang shrele; ReParr TG Kawn Srachura Attention Nevr Starhura Aadre5s 43L'1 Taggal Creek Faad C9py YC CoelpEny Name Sr+refd Crtar;onl . NC 2.E20H Aaaress 4W1 Ta gart Creek Rd Cnaricne NC 2s206 RetluiatoryActency Emad kslachura ahielden ine F .earn Purchase Order Pace 0.0le NCDEO • UST Prlone t7D4139--fi$13 Fsx t7pgl39q-6%8 Project Name Prt Slop BA Pace Prolee hM1anSgpr Payne. Amanda Sate ILocatlon Fteq�esled Due Cale Standard PrgeG A 1120116 Pace Prattle a NC Requested AnfW sis Filtered Arty _ a 2 —MM WDE — v COLLECTED Preservatives Y omumg wow tri+ i7 war m E w atoe�n a SAMPLE !❑ wa a START raD Eix ° m } ¢ c One ChgraClpr Per AoX W" vrP z p # >7 Y F $ m O [] Sampin Ida must he unique ? w S x ry. TDATEnME c ti d m fl — O 5 C a 'a 4 z jj V� DATE TIME • = i 1 MW-? WT G 15�77 -0 4 � 2 Mw-a wT G 171,0J 4 e x 3 Mw.1os WT G ��..]Q q 4 % 4 Mw-13 wT G l31' 5 a 4 5 MW-14 YJT G �rf'r]Q 4 4 A 6 Mw-15 wT G 111 517 4 q x 14 7 mw-is WT G -35 4 X. 8 MW-17 WT G x 9 4— 1 Tr10 8lw* WT G 1 2 2 x CIO, 11 12 ADonxxALcommergs RPLUXMI dSI) 8y lAFFA1ATION PATE Trma ACCEPTED 9Y I AFnLIATION nw sIWPLE CCMM NS "DATE r SAMPLER NAME AND SIGNATURE PRINT Name of SAMPLER_ M m ? e o z m z SIGNATURE of SAMPLER' DATE Si ned: V o APPENDIX J Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contamination Calculations NCGWI #13404 Date of Sampling Mass of GroundwaterContaminatian (rn..) mg,,,=Volume (v) x Concentration (C) V(L)= C (VOCs in ug/L)= mgw(ug)= mgw(g)= V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n) A(ft')= D (ft)= n= V (ft)= V(l)= Notes: - Area (A) = Approximate area of the combined benzene and MTBE plumes -Concentration is based on Total VOCs for each specific sampling event -Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water level in ail site monitoring wells during sampling event (7.5 ft) -Porosity (n) = Total Porosity (Using a total porosity of 0.46*) 1 ft = 28.3168 L -mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = liter; ug/L = micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n =Porosity; ft = feet *Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W. (1994). Applied Hydrogelogy (3rd ed.). New York, NY: Macmillan College Publishing Company. inc.] 7/19/2017 1,102,953.52 6,542.25 7,215,797,655.75 7,215.80 11,290.00 7.50 0.46 38,950.50 1,102,953.52 12/13/2017 540,730.53 3,055.00 1,651,931,780.15 1,651.93 5,535.00 7.50 0.46 19,095.75 540,73053 Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contamination Calculations NCGWI #13404 Mass of Groundwater Contamination (mgw) mgw Volume (v) x Concentration (C) V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n) Notes: - Area (A) = Approximate area of the combined benzene and MTBE plumes -Concentration is based on Total VOCs for each specific sampling event Date of Sampling 6/26/2018 1/3/2019 V(L)= 561,734.52 483,580.15 C (VQCs in ug/L)= 11,319.00 1,110.00 mgw(ug)= 6,358,273,031.88 536,773,968.72 mgw(g)= 6,358.27 536,77 A(ftz)= 5,750.00 4,950.00 D (ft)= 7.50 7.50 n= 0.46 0.46 V (ftl)= 19,837.50 17,077.50 VIL)= 561,734.52 493,580.15 -Depth (D)=Terminal depth of monitoring well (MW-10B) screen (M20 ft)- average static water level in all site monitoring wells during sampling event (7.5 ft) -Porosity (n) =Total Porosity (Using a total porosity of 0.46*} 1 ft3 = 28.3168 L -mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L = micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n =Porosity; ft = feet *Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W. (1994). Applied Hydrogeiogy (3rd ed.). New York, NY: Macmillan College Publishing Company, Inc.1 Carolina Fast Mart 44 - Fit Stop - Mass of Groundwater Contamination Calculations NCGWI 413404 Date of Sampling Mass of Groundwater Contamination (mgw) mr,=Volume (v) x Concentration (C) V(L)= C (VUCs in ug/L)= mgw(ug)= mgw(g)= V=Contaminant Area (A) x Depth of Plurne (0) x Porosity (n) A(ft')= D (ft)= n= V (ft 3)= V(L)= Notes: - Area (A) = Approximate area of the combined benzene and MTBE plumes -Concentration is teased on Total VOCs for each specific sampling event -Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water level in all site monitoring wells during sampling event (7.5 ft) -Porosity (n) = Total Porosity (Using a total porosity of 0.46*j 1ft3=28.3169L -mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L = micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n =Porosity; ft = feet *Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W. (1994). Applied Hydrogelogy (3rd ed.). New York, NY- Macmillan College Publishing Company, Inc.] 7/2/2019 483,580.15 6,965.00 3,368,135,758.68 3,368.14 4,950.00 7.50 0.46 17,077.50 483,590.15 12/12/2019 385,984.88 4,619.31 1,782,983,838.94 1,782.98 3,951.00 7.50 0.46 13,630.95 385,984.98