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HomeMy WebLinkAboutMO-4269_13403_CA_MRP_20200131_Monitoring Report*.
IELD
ENGINEERING, INC.
MONITORING REPORT
CAROLINA FAST MART #4 PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, CABARRUS COUNTY, NORTH CAROLINA, 28025
FACILITY ID #0-002137
GROUNDWATER INCIDENT NO. 13403
UST
Owner/Operator:
Carolina Oil
Company
P.O. Box 5010
Concord, NC
28207
Contact:
Mr. Robbie
Barbour
(704)782-3196
barbour@CTE.net
SHIELD PROJECT NO. 1120116
Consultant:
Property Owner:
Property
Analytical Laboratory:
Occupant
Shield Engineering, Inc.
Carolina Oil
BP
Pace Analytical Services, LLC
4301 Taggart Creek Road
Company
Fueling
9800 Kincey Ave. Suite 100
Charlotte, North Carolina 28208
P.O. Box 5010
Station
Hantersville, NC 28078
Concord, NC
State Certification 4 5342
28207
Contact:
Contact:
Contact:
Contact:
Kevin P. Stachura
(704)394-6913
kstachura@shl'eidc,ngincer-ing.com
Site Risk Classification: High Risk
Land Use Category: Commercial
Description of Geographical Data Point:
Middle of Site Canopy
Release Discovered: November 1997
Potential Release Source(s): Former UST System
Release Cause: [unknown
Kevin P. Stachura
Project Manager
Mr. Robbie Unknown Amanda Payne
Barbour (704)875-9092
(704) 782-3196 Amanda.payne@pacelabs.com
barbour@CTE.net
Site Latitude: 35.370603 N
Site Longitude: 80.665629 W
Location Method: Google EarthTM
Quantity Released: Unknown
January 31, 2020
CAt3p�
�,p�;reSSl pH
:a SEAL —
David A. 81� .
Senior PrinciN D A. S`
Registcred, NC 0140
4301 Taggart Creek Road
Charlotte NC ?8208
www.shieldenginee4ng.com
Telephane 704 394.69 F3
Fax 704 394 6968
Carolina Fast Mart #4 Pit Stop
Caharrus County, North Carolina
GWI#; 13403
Executive Summary
Monitoring Report
January 31, 2020
Page i
The Carolina Fast Mart #4 Pit Stop site is considered a High Risk site assigned groundwater incident
#201 l7 and is located in Cabarrus County, North Carolina. The site currently operates as a BP
petroleum filling station and convenience store. The site does not have an active remedial system
and is monitored via groundwater sampling events that are conducted semi-annually in June and
December, Mobile Multi -Phase Extraction (MMPE) events have been conducted historically prior
to sampling events. The following information pertains to the findings of the December 2019
sampling event(s):
• Free product was not present at the site during this monitoring period and has never been
present in any of the site wells.
• Dissolved phase petroleum constituent compounds were detected in concentrations
above the 15A NCAC 2L Groundwater Standards (2L Standards) in monitoring wells
MW-10B, MW-13, and MW-16.
• The contaminant plume appears to be relatively stable. Constituent concentrations have
overall decreased since the initial September 2013 sampling event.
• The concentration of benzene increased above the 2L Standard in MW-13 since the
previous routine sampling event.
• Diisopropyl ether (IPE) at the site has decreased below 2L Standards.
■ Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to
approximately 1,800 grams in December, 2019.
• Due to no power at the well, WSW-1 was not sampled during the December 2019
sampling event. Also, the owner was not at home during the sampling event.
■ Previous active remediation at the site consisted of soil excavation at the time of the UST
removal. Soil delineation sampling was conducted in association with Comprehensive
Site Assessment (CSA) addendum activities in September 2013. Based on information
presented in the CSA Addendum, soil contamination in the form of benzene only was
found near one former sidewall of the large UST excavation above the Soil -to -
Groundwater (STG) maximum soil contaminant concentration levels (MSCCs) but not
above the Residential MSCCs. No soil contamination was found near the former diesel
UST area above the STG or Residential MSCCS. All four samples collected from
around the smaller UST excavation area exceeded the STG MSCCs for gasoline related
constituents of concern (COCs) but none of these samples exceeded the Residential
MSCCs.
r'-HniH�iiNr: i�
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
GWI#: 13403
Monitoring Report
January 31, 2020
Page ii
• Shield's project director discussed the site with the current NCDEQ incident manager on
November h, 2019 as follow up to the NCDEQ NO RR letter dated September 24, 2019.
It was determined that two more sampling rounds, after the July 2019 sampling event,
with similar sampling results to the July 2019 results were needed before the site could
be closed with a Notice of Residual Petroleum (NDRP) deed restriction.
Based on the December 2019 sampling results, only one more round of sampling with
similar results should be required before the site can be closed with a Notice of Residual
Petroleum (NORP) deed restriction.
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
G W I#: 13403
TABLE OF CONTENTS
Monitoring Report
January 31, 2020
Page iii
Page No.
1.0 SITE HISTORY AND CHARACTERIZATION........................................................I
2.o PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT
INFORMATION..............................................................................................................5
3.0 FREE PRODUCT REMOVAL......................................................................I..............8
4.0 MONITORED NATURAL ATTENUATION..,..........................................................8
5.0 CONCLUSIONS AND RECOMMENDATIONS......................... . ........................... to
6.0 STATEMENTS & CERTIFICATION......................................................................11
7.0 LIMITATIONS.............................................................................................................12
LIST OF FIGURES
Figure 1: Site Location Map
Figure 2: Site Map
Figure 3: 1,500 Foot Radius Map
Figure 4: Groundwater Elevation Contour Map (12/12/2019)
Figure 5: Benzene Isoconcentration Map
Figure 5: MTBE Isoconcentration Map
Figure 7: Naphthalene Isoconcentration Map
LIST OF TABLES
Table 1: Water Supply Well and Receptor Information
Table 2: Summary of Well Construction and Groundwater Elevation Data
Table 3: Summary of Analytical Results — Groundwater Samples
Table 4: Summary of Historical Analytical Results — Groundwater Samples
APPENDICES
Appendix A: Geologic Logs for Borings - Not Applicable or Not Available (NA)
Appendix B: Copies of any NORR, NOV, etc. related to submittal of Site Closure Report (NA)
Appendix C: Field Parameters
Appendix D: Remedial System Performance Tables and Graphs (NA)
Appendix E: Constituent Concentration vs TimelHydrograph(s)
Appendix F: Compilation of Costs for Performance of Remedial Plan (NA)
Appendix G: Chronology of Remediation Activities (NA)
Appendix H: Proposed Remediation Schedule and Cleanup Progress Milestones (NA)
Appendix 1: Laboratory Analytical Results
*SHIEW
Ni:�NI'. RINK, ING
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
GWI#: 13403
Appendix J: Groundwater Calculations
Monitoring Report
January 31, 2020
Page iv
H. Wrojects12012U 120116-01 Carolina Fast Marl Pit SloplReporisWR January 202119Moniroring Reporl2020-01,doc
Carolina Fast Mart #4 Pit Stop
Cabarms County, North Carolina
G WI#: 13403
1.0 SITE HISTORY AND CHARACTERIZATION
1.1 Historical Information on Release
Monitoring Report
January 3I, 2020
Page I
According to the August 2002 Pre -CAP Monitoring Report prepared by Engineering
Tectonics, P.A. (ETPA), three 10,000 gallon gasoline underground storage tanks (USTs),
and one 8,000 gallon diesel UST were removed in November 1997. Upon the removal of the
USTs, soil contamination was detected and associated with the UST system. The exact
source of the release is unknown and can be one or a combination of the USTs, the piping,
and/or the dispensers. Carolina Oil Company was the owner and/or operator of the USTs.
The site was historically classified as an Intermediate Risk site by the North Carolina
Department of Environmental Quality (NCDEQ). Ongoing semi-annual monitoring and
reporting was being conducted by others during this time.
A Notice of Regulatory Requirements (NORR) dated May 3, 2012 indicated that the Pit Stop
BP site, of Intermediate Risk, was determined by the NCDEQ to be of sufficiently high
priority to allow funding by the State Trust Fund Program, Pursuant to the NORR and a
Notice of Violation (NOV) dated July 26, 2012, a Natural Attenuation Monitoring Report
(NAMR) was submitted by Shield Engineering, Inc. (Shield) to the NCDEQ on December
20, 2012. The December 2012 NAMR found that dissolved phase petroleum constituent
concentrations exceeded the NCDEQ Gross Contaminant Levels (GCLs) in monitoring well
MW-10B.
Additional soil sampling was performed in September 2013 in order to further delineate soil
contamination and was presented in a Comprehensive Site Assessment (CSA) Addendum. It
was noted that no soil contamination was found to be above the Residential Maximum Soil
Contaminant Concentration levels (MSCCs).
Based on groundwater results from the April 2014 sampling event, methyl tertiary butyl
ether (MTBE) and diisopropyl ether (IPE) were detected in water supply well WSW-1.
MTBE was detected at 29.9 micrograms per liter (ug/L) which was above the 15A NCAC 2L
Groundwater Standards (2L Standards) of 20 ug/L. Since MTBE was detected above the 2L
Standards and according to an NORR dated May 16, 2014, the Pit Stop BP site was
reclassified as High Risk. There are other petroleum fueling stations at this traffic
intersection so we are uncertain of the true source of the MTBE in WSW- 1. Since MTBE
has historically been detected above the 2L Standards and WSW-1 could not be sampled
during the July 2019 sampling event the Pit Stop BP site remains classified as High Risk,
according NORR dated September 24, 2019.
No Corrective Action Plan was ever conducted or implemented for this site. Semi-annual
Mobile Multi -Phase Extraction (MMPE) events along with routine sampling and reporting
are ongoing.
No non -LISTS are believed to have added to the site contamination.
Carolina Fast Mart #4 Pit Stop
Caharrus County, North Carolina
G WI#: 13403
1.2 Site Characteristics
Monitoring Report
ianuary 31, 2020
Page 2
The site is located at 3690 Concord Parkway South in Concord, North Carolina (See Figures
l & 2). The property currently operates as a BP petroleum filling station and convenience
store. The surrounding properties are residential, commercial, or agricultural in use.
Groundeover at the site is comprised ofasphalt/concrete paved surfaces and landscaped areas
of grass. A one-story convenience store building along with a canopy is also located on the
site. Geology and hydrogeology information can be seen in Section 2.5
1.3 Existing Area Receptors:
Refer to the following figure for information and locations of property owners/occupants and
area receptors.
Refer to Table: Table I
Refer to Figures): Figure 3
Pursuant to NCDEQ requirements in 2012, a Site Reconnaissance and Receptor Survey
(receptor survey) was conducted by Shield by walking and/or driving publicly accessible
roads within a 1,500-foot radius of the site. During the survey, Shield personnel observed
supply wells and/or water meters from the streets and interviewed available occupants.
Figure 3 depicts the subject site and all properties within 1,500 feet of the site. Refer to
Table l for specific information. Locations of addresses are approximate, based on
perceived locations, using a topographic map, a tax map, and observations in the field,
There may be other supply wells or water teeters that were not readily visible at the time of
our survey,
Based on the 2012 receptor survey, seven water supply wells were observed within 1,500
feet of the source area. According to the property owner of WSW-1, located approximately
430 feet from the source area, the water supply well is used for irrigation and washing
vehicles and they are connected to municipal water for other water uses. The property owner
of WSW-2 approximately 530 feet from the source stated that they did not use the water
supply well. No one was home at WSW-3, WSW-4, and WSW-5 at the time of the supply
well survey. WSW-3 is approximately 740 feet from the site. WSW-4 is approximately 840
feet from the site. WSW-5 is approximately 940 feet from the site. The property owner at
WSW-6 located approximately 890 feet from the site stated that they did not use the well.
WSW-7 is approximately 1,290 feet from the site and is located on undeveloped land. Water
supply well survey letters were left at residences of WSW-4, WSW-5, and mailed to the
residences at WSW-3 and WSW-7. The survey letters from the residents of WSW-4 and
WSW-5 stated that they did not use the wells. The survey letter from the residents of WSW-
3 stated they use the well for washing vehicles. No information was returned by the
residents of WSW-7. All other parcels shown on Figure 3 are either connected to municipal
water or are undeveloped.
*MIS.
Carolina Fast Mart 44 Pit Stop
Cabarrus County, North Carolina
G W I#: 13403
Monitoring Report
January 31, 2020
Page 3
A receptor survey update was performed by Shield personnel on July 2, 2019 in order to
review the status ofknown receptors and present information on new receptors, if applicable.
Based on this receptor survey update, nine water supply wells were observed within 1,500
feet of the source area. No well was observed at 15 Pitts School Road NW. No well was
observed in the formerly shown location of WSW-2, however, a potential water supply well
was observed on this property. The WSW-2 property is currently vacant and the well is
approximately 270 feet from the source, A water supply well, WSW-8, is used for irrigation
and is located at 3200 Concord Parkway S. A water supply well, WSW-9, is used for
domestic purposes, such as drinking water, irrigation etc., is located at 172 Pitts School Road
SW. In addition, request for water supply well information surveys were sent to all known
properties were water supply wells have been observed. Only four surveys were returned at
the time of this report. The returned surveys are included in Appendix K.
There is an unnamed intermittent drainage feature approximately 50 feet west of the site that
ultimately flows into Rocky River and another unnamed intermittent drainage feature
approximately 900 feet west of the site that flows into Coddle Creek.
Because of the receptor information and previous groundwater contaminant level(s) being
detected in supply we]1 WSW -I, the site remains ranked by the NCDEQ as a "High Risk"
site according to NCDEQ NORR letter dated September 14, 2019. There are other
petroleum fueling stations at this traffic -intersection so we are uncertain of the true source of
the MTBE in WSW-1 .
e Proximity of Plume to Nearest Receptor(s):
There is an unnamed intermittent drainage feature approximately 50 feet west of the site that
ultimately flows into Rocky River.
The closest active water supply well (WSW-1) is located approximately 430 feet west
southwest from the source area of release. WSW-1 was used for washing cars; the residents
have municipal water for other water uses. Sometime after the .tune, 2018 sampling event, a
pipe in WSW-1 broke, the party(ies) who live at the property disconnected the electricity to
the well, and the well is not being used. This was confirmed in July, 20I9 by Shield's field
services manager. Previous interviews with the owner(s) of the well were not successful in
getting them to abandon their well and connect their car washing station to municipal water.
We previously advised the property owners of concern relative to drinking water from this
well, although the levels of MTBE and IPE are now below the 2L Standards. There are other
petroleum fueling stations at this traffic intersection so we have always been uncertain of the
true source of the MTBE and IPE in WSW-L
*8ff19LD
Carolina Fast Mart #4 Pit Stop
Cabamas County, North Carolina
G W l#: 13403
1..4 Implementation of Remedial Plan:
Monitoring Report
January 31, 2020
Page 4
Corrective Action Plan activities have not been conducted at this site. Based on information
presented in the CSA Addendum, soil contamination in the form of benzene only was found
near one former sidewall ofthe large UST excavation above the Soil -to -Groundwater (STG)
MSCCs but not above the Residential MSCCs. No sail contamination was found near the
former diesel UST area above the STG or Residential MSCCS. All four samples collected
from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related
constituents of concern (COCs) but none ofthese samples exceeded the Residential MSCCs.
MMPE events are currently being conducted semi-annually utilizing monitoring wells MW-
10B and MW-16 in July and January. MMPE events have been conducted in March 2014,
April 2015, January 2016, October 2016, .Tune 2017, November 2017, July 2018, and
January 2019.
;tWIEL�D
Nn�N.
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
GWl#: 13403
Monitoring Report
January 31, 2020
Page 5
2.4 PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT
INFORMATION
2.1 Groundwater Elevation and Flow Directions
• No free product is present at the site.
• Current groundwater flow is predominantly toward the northwest. The current
groundwater elevation data are included in the following table(s) and figure(s):
Refer to Table(s): Table 1
Refer to Figure(s): Figure 4
2.2 Free Product
Free Product Detected during this Reporting Period?: No
2.4 Discussion of Groundwater Monitorine Event
Monitoring well construction information can be seen in Table 2.
2.4.1 Site Monitoring Requirements:
Site Location Map: See Figure 1
Site Map: See Figure 2
Site Monitoring Requirements
Based on CAP and/or NORR(t)
Sample Point
Total Quantity of Existing Sample
Required by NCDEQ to be
Type
Points and Their Identification
Monitored and Sampled per
NORR and/or TA 13403-I6
Monitoring
9
8
Wells
(MW-2, MW-6, MW-10B, MW-13,
(MW-2, MW-6, MW-10B, MW-13,
throw h MW-17, and TW-2)
throu h MW-17
Water Supply
I
1
Wells
(WSW-])
(WSW-1)
NOTES:
(1) Site monitoring require►nents are in accordance with the April 23, 2019 Notice of Regulatory Requirements.
*SHIES
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
GWI#: 13403
2.4.2 Groundwater Analytical Methods:
• Sampled Points and Analytical Methods:
Monitoring Report
January 31, 2020
Page 6
The following monitoring and supply wells were sampled on December 12, 2019. Field parameters
were also collected at the time of sampling, Refer to Appendix C for the Field Parameter Log.
Sampled Points and Analytical Methods
for this Reporting Period
Based on CAP and Pre -Approval Task Authorization Sampling Requirements
Type
Points Sampled during this
Analytical Method(s)
Reporting Period
Monitoring Wells
(8) Wells
EPA Method 6200E
(MW-2, MW-6, MW-IOB, MW-13,
throw h MW-17
Surface Water
No surface water sampling has ever
No analysis for this reporting period.
been required for this site,
Water Supply
(01) Water Supply Well
• EPA Method 6200B
Wells
(WSW -I)
I.) No power at well. Property owner not present during this routine sampling event.
■ Laboratory Used: Pace Analytical Services, LLC
■ Date(s) of Sampling Event(s): December 12, 2019
2.5 Summarization of Current and Historical Assessment Information
Current Groundwater Analytical Data:
Refer to the following table(s) and Appendix for current groundwater analytical data.
Refer to Table(s): Table 2
Rcffer to Appendix: Appendix E & Appendix I
a Historical Groundwater Analytical Data:
Refer to the following table and appendix for historical groundwater analytical data.
Refer to Table: Table 3
Refer to Appendix: Appendix E
• Surface water and soil are not required to be sampled.
Carolina Fast Mart 44 Pit Stop
Cabarrus County, North Carolina
G WI#: 13403
2.5 Site and Region Geolog3, and Hydropaeology
Monitoring Report
.January 31, 2020
Page 7
The project site is located in the Charlotte Belt Litho -Tectonic Province of the Piedmont
Physiographic Province. The Piedmont Province is approximately 20,000 square miles located
in the State of North Carolina and lies between the Coastal Plain to the east and the Blue Ridge
Province to the west_ The topography is characterized as a plateau with ridges and valleys
formed as a result of stream erosion. Elevations within the Piedmont Province vary from
approximately 400 feet above sea level in the east to approximately 1,800 feet above sea level
near the foot of the Blue Ridge Province to the west. The soil overburden in the Piedmont
Plateau consists of predominately fine grained sediments transitioning into saprolites. The
residual saprolites are predominately underlain by northeast/southwest trending metamorphic
and igneous rocks.
Based on soil classifications (Unified Soil Classification system), the soil lithology at the site
generally consists of silty sands, sands, clays, sandy clays, clayey silts, and sandy silts.
According to the Geologic Map ofNorth Carolina (1985), the site soils should be underlain by
Gabbro of the Concord Plutonic Suite.
Hydrogeological investigations were; to be performed during the CSA by others. Shield does
not have information pertaining to the CSA. CSA addendum activities were performed by
Shield in September and October 2013, however, no bydrogeological investigation was
performed as a part of those activities.
2.7 Evaluation of Site Assessment Information
Groundwater— The following Groundwater Summary and referenced figures are based on the
December 12, 2019 routine sampling event:
* Dissolved phase petroleum constituent compounds were detected in concentrations
above the 2L Standards in monitoring wells MW-1 OB, MW-13, and MWA 6.
* The two largest contaminant plumes are benzene and MTBE.
■ The benzene plume greater than the 2L Standards is approximately 113 feet in length and
approximately 44 feet in width. The areal extent of the benzene plume is approximately
3,951 square feet.
■ The MTBE plume greater than the 2L Standards is approximately 43 feet in length and
30 feet in width. The areal extent of the MTBE plume is approximately 987 square feet.
Refer to Figures: Figures 5 through 7
S�fi� ,LD
Carolina Fast Mart #4 Pit Stop
Cabarrus County, North Carolina
GWI#: I3403
• Predictive Rate of Contaminant Transport:
The contaminant plume(s) on site appear to be fairly stable.
Monitoring Report
January 31, 2020
Page 8
MTBE was detected at a concentration of 1 micrograms per liter (ug11) in supply well
WSW-1 during the June 26, 2018 sampling event. There was no power to well during
the December 12, 2019 sampling event and the well was not sampled. There are other
petroleum fueling stations at this traffic intersection so we are uncertain of the true
source of the MTBE in WSW-1. Refer to the following Tables and Figures:
Refer to Tables: Tables 3 and 4
Refer to Figures: Figures 5 through 7
• Soil
• Based on information presented in the CSA Addendum dated December 3, 2013, soil
contamination in the form of benzene only was found near one former sidewall of the
large LIST excavation above the STG MSCCs but not above the Residential MSCCs. No
soil contamination was found near the former diesel UST area above the STG or
Residential MSCCS. All four samples collected from around the smaller UST
excavation area exceeded the STG MSCCs for gasoline related CRCs but none of these
samples exceeded the Residential MSCCs.
• Soil monitoring was not required by the NCDEQ during this reporting period. Historical
soil information has been provided in previous reports.
i 'I��l�-�i�IL F�Y�-�uI�]'L•�7J
• Free product has not been historically encountered nor remediated at this site. Free
product was also not encountered during this reporting period.
4.0 MONITORED NATURAL ATTENUATION
• Refer to Section 2.3.1 Site Monitoring Requirements and Section 2.3.2 Groundwater
Analytical Methods for information pertaining to the established monitoring plan.
■ For Historical Groundwater Analytical Data, refer to Section 2.4 and Table 4.
• The current contaminant mass, as calculated from the December 12, 2019 routine
sampling event areal plume area (combination of benzene and MTBE plumes) is
approximately 1,783 grams and 3,951 square feet, respectively.
• Dissolved phase petroleum constituent compounds were detected in concentrations
above 2L Standards in MW-10B, MW-13, and MW-16.
Carolina Fast Mart #4 Pit Stop Monitoring Report
Cabarrus County, North Carolina January 31, 2020
GWI#: I3403 Page 9
■ Due to no power at the well, WSW-1 was not sampled during the December 2019
sampling event. The owner was not at home during the sampling event.
• No CAP was ever completed, so no progress milestones or schedule were ever
established.
• The concentration of benzene increased above the 2L Standard in MW-13 since the
previous routine sampling event.
■ Diisopropyl ether (IPE) at the site has decreased below 2L Standards.
• Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to
approximately 1,800 grams in December, 2019
Refer to Tcable(s):
Refer to Figures):
Refer to Appendix.
Tables 3 and 4
Figures 5 through 7
Appendix E
*SHIELD
Carolina Fast Mart tW Pit Stop
Cal}anus County, North Carolina
GWI##: 13403
5.0 CONCLUSIONS AND RECOMMENDATIONS
5.1 Interpretations of Submitted Data:
Monitoring Report
January 31, 2020
Page 10
■ The site is a High Risk site because of supply well W SW- I being located within 500 feet
of the site. WSW-1 has also been historically impacted with MTBE. There are other
petroleum fiteling stations at this traffic intersection so we are uncertain of the true
source of the MTBE in WSW-1. Due to the no power at the well, WSW-1 was not
sampled during the December 2019 sampling event. The owner was not at home during
the routine sampling event.
• Dissolved phase petroleum constituent compounds were detected in concentrations
above 2L Standards in MW-10B, MW-13, and MW-16.
• The current contaminant mass, as calculated from the December 12, 2019 routine
sampling event and areal plume area (combination of benzene and MTBE plumes) is
approximately 1,783 grams and 3,951 square feet, respectively. This contaminant mass
is an decrease from the July 2019 sampling event which was approximately 3,368 rams.
• The concentration of benzene increased above the 2L Standard in MW-13 since the
previous routine sampling event.
• Diisopropyl ether (1PE) at the site has decreased below 2L Standards.
• Contaminant Mass has decreased from approximately 3,400 grams in July 2019 to
approximately 1,800 grams in December, 2019.
• Due to power at the well, WSW- i was not sampled during the July 2019 sampling event.
The owner was not at home during the routine sampling event.
5.2 Recommendations
• Shield recommends the continuance of semi-annuai sampling of the site monitoring
wells and water supply well WSW-1.
• Shield's project director discussed the site with the current NCDEQ incident manager on
November 6, 2019 as follow up to the NCDEQ NORR letter dated September 24, 2019.
It was determined that two more sampling rounds, after the July 2019 sampling event,
with similar sampling results to the July 2019 results were needed before the site could
be closed with a Notice of Residual Petroleum (NORP) deed restriction.
■ Based on the December 2019 sampling results, only one more round of sampling with
similar results should be required before the site can be closed with a Notice of Residual
Petroleum (NORP) deed restriction.
1*
SI�LD
Carolina Fast Mart 44 Pit Stop
Cabarrvs County, North Carolina
GWI#: 13403
6.0 STATEMENTS & CERTIFICATION
Monitoring Report
January 31, 2020
Page 11
i
Enter the date the monitoring report was due. 01_ 131/20. Will this report be subin itted
YES
ItO
after the established due date?
2
Was any required information from the standardized template missing from this
E..
NO
report?
IF the answer to question #1 or# 2 is "YES", please provide additional information in
this cell to explain what was missing and why.
1) The sections and discussions pertaining to the historical contaminant mass and
projected milestones have been omitted since these were never calculated to our
knowledge. CAP activities were never conducted at this site.
3
If applicable, will any of the proposed attenuation milestones under the schedule
YES
NO
approved in the Corrective Action Plan not be met? (within a reasonable margin of error)
IF the answer to question #3 is "NO", skip to the certification Under #6 below.
IF the answer to question #3 is "YES", please generally describe in this cell the
possible reason(s) and outline proposed remedies. (This should be described in more
detail in the report text above_)
*The CSA report (if ever completed) is currently not available to Shield. No
milestones were previously established to our knowledge. CAP activities were never
conducted at this site.
4
Does any known or suspected source zone soil contamination or free product remain
YES
NO
outside of the assessed area that could be inhibiting natural attenuation?
5
Has there been an unexpected increase in contaminant mass sufficient to suggest a
YES
NO
potential new release from a separate unsite or offsite source?
IF the answer to either question #4 or #5 is "YES", generally describe in this cell any
actions recommended to further assess or clean up this known or suspected source.
(This should be described in more detail in the report text above.)
G
Certification:
1, David A. Stoner, a Professional Geologist for Shield Engineering, Inc., do certify that
the information contained in this report is correct and accurate to the best of my
knowledge.
CAROZI.f',
4 tiq
�Sssio4;
1
(Affix S*) u'hd Fina
Shield Engi(,47 All� .j§)tcensed to practice geology and engineering in North Carolina.
li,ber
The certi ficationr of the company or corporation is C-170(Geology) and F-0856
(Engineering).
1*SfIELD
Carolina Fast Mart 44 Pit Stop
Cabarrus County, North Carolina
GWT#: 13403
7.0 LIMITATIONS
Monitoring Report
,January 31, 2020
Page 12
Shield has performed environmental services at the subject site on behalf of Carolina Oil Company.
Shield has performed this scope of work as an independent contractor/consultant using reasonable
care and skill in accordance and consistent with customary industry standards of engineering,
geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of
care that can be applied to measure Shield's performance of the work. No other warranty, expressed
or implied is made or intended by Shield.
The report has been prepared for the exclusive use by Carolina Oil Company. All recommendations,
findings, and conclusions, made by Shield have been made to the best of Shield's knowledge,
opinion and belief, based upon information obtained during this scope of work, and is limited by the
scope nature and type of services as agreed upon between Carolina Oil Company and Shield.
Conclusions are provided with the understanding that Shield is presenting information and not
rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the
responsibility of Carolina Oil Company under advice of its counsel to notify the appropriate federal,
state, or Local public agencies as required by law; or otherwise to disclose in a timely manner, any
information that may be necessary to prevent damage to human health, safety, or the environment.
Compliance with recommendations provided as part of this report in no way assures compliance
with federal, state and/or local laws, regulations, and/or requirements. Analytical data has been
obtained from Pace Analytical Services, LLC. This information, to the extent that it was relied on to
generate this report, is assumed to be correct and complete. The work performed in conjunction with
this report and the data developed are intended as a description of available information at the dates
and specific locations given. Shield is not responsible for inspecting, examining, or reporting
findings or recommendations with respect to any conditions that were knowingly or unknowingly
withheld, concealed, hidden, or in any way not disclosed or observable at the time of this scope of
work,
*891,ELD
FIGURES
0.
TABLES
Table 1: Water Supply Well and Receptor Information
Carolina Fast Mart #4 Pit Stop
Concord NC
Alread-v
kererenced Supply
Namt
Property Address
Phone Number I
connected to
Supply Well on
Well use
Date
Depth of
Depth of
Diameter of
Screened
Willing to connect
Dialance from
source area of
Wcn No.
City or County
property'
lnstalled
Weli
Casing
Well
Interval
10 city water?
water?
release
Previously Irrigation &
WSW 1
Kenneth & Donna
213 Perry Street, Concord NC
704-634-3664
Yes
Yes
Washing Vehicles,
L'nk
Unk
link
Link
Unk
Not in 2017
590 feet
Blackwelder
'2019 broken pipe& no
electricity to well.
Fossibte Well
WSW-2
DCF Properties, LLC
6u Pitts School Road NW, Concord VC
N .A
Yes
House
Vacant Property Not
Use y
NIA
'.VIA
NIA
NIA
NIA
h!A
350 feet
Observed
in
WSW-3
Charles Strickland
80 Pitts School RoadNW, Concord NC
\.'A
Yes
Yes
Washing Vehicles
Unk
Link
Unk
Unk
Unk
Unk
1,050 feet
WSW-4
Scan, LLC
R4, RS Pitts School Road NW. Concord NC
ti .t
Yes
Yes
'101 in Use
Unk
Unk
Unk
Unk
Unk
link
1.090 fart
WSW-5
Mark & Melia Gordon
99 Pirts Sc heal Road NW, Concord NC
?�'A
Yes
Yes
Not in Use
Mid'40-59s
Unk
lank
tank
1'r-k
Unk
i,390 feet
Charles& Margaret
WSW-6
Mauney
91 Pitts School Road NW. Concord NC
7115-701-D'35
Yrs
Yes
Not in Use
1900
30'-40'
Unk
lank
Lrtk
U10,
l,00 feet
WSW-7
DCCF Properties, LLC
12 Csrpeorcr Coun NW, Concord, IBC
.•
NiA
Well House
Vacant Properly- Not
Unk
link
Unk
Unk
Unk
Link
4,750 feet
Observed
in Us¢
WSW-R
Leonard &. Lutie Dover
3600 Concord Parkway S. Concord NC
NIA
Yes
Yes
Irrigation
112713009
279
46'
6,25"
Unk
Unk
5R5 feel
WSW-9
Robert Morris
172 Pius School Road 5W, Concord
N'A
No
Yes
All Domestic Uses
Lank
F
Unk
Lank
Unk
Unk
1,300 feet
NA - NO a,wlahie Dr not am.J -cab Ic
link = Pnkiwwn
d vito+rnntno FKoleirwN r S pwo w.rsarwy reer4+a Page 1 011
Table 2; Summary of Well Construction and Groundwater Elevation Data
Carolina mast Mart 44 Pit Stop
Concord, Cabarrus County
NCDEQ GW14: 13403
Wc111D
Date
Installed
Top or
Casing
Elevation
(feet)
Well
Diameter
(inches)
As -built
Depth
(feet)
Screened
Interval
(feet)
Field Measurements
Field Calculations
Gauging
Date
Total
Depth
(feet)
Depth to
Free
Product
(feet)
Depth to
Static
Water
(feet)
Diff. Between
As -built and
Measured
Total Depth
(reef)
Measured
Water
Column in
Well
(feel)
Groundwater
Elevation
(feet)
MW-2
NA
100.00
2
NA
09/07/01
NA
ND
10.1
NM
NM
89,90
06/27/02
NA
ND
I0.85
NM
NM
89.15
10/31/12
26,85
Nil
11.24
NM
15.61
88.76
04101114
26,85
Nil
6.60
NM
20.25
93,40
IQiZV14
26,85
ND
9,50
NM
17.35
90,50
06/08/15
26,85
ND
8,55
NM
19.30
9IA5
02/17J16
26.85
ND
6.43
NM
29A2
93.57
11130)16
26.85
N❑
11.20
NM
15.65
88,80
07/19/17
26.85
ND
9,80
NM
18.05
91.20
12/13/17
26.95
ND
9.90
NM
16,95
90.10
06126/18
26.85
N❑
8.81
NM
18.04
91.19
01/03/19
26.85
N❑
5.82
NM
Fi.03
94.18
07/02/19
26.95
ND
7.77
NM
19.08
92,23
12/12119
26.85
ND
8.43
NM
19.47
91.57
MW-6
NA
94.77
_
NA
09/07/01
NA
Nil
5.3
NM
N1v1
! 9.47
06)27102
NA
Ni}
0,41
NM
NM
98.36
10)31112
8.84
NI)
6.26
NM
2,59
98.31
04/111/14
8.84
ND
3.36
NM
5AS
91.41
10121a,l
8,R4
ND
5.16
NM
3,68
89.61
06/08/15
8.84
Nil
4.20
NM
4,64
90.57
02/17/16
8.84
ND
2.93
NM
5.91
91.84
11/30/16
8.84
ND
5.84
NM
3,00
8893
07/19/17
9.84
ND
4.28
NM
4 56
9949
12/13/17
R.84
ND
4.81
NM
4.03
89.96
06/26/18
8.84
ND
4 37
NM
4,47
90.40
01/03/19
8.84
NO
7.87
NM
6,02
9195
07M2119
8.84
NO
3.86
NM
498
9091
12I12119
8.84
NO
3.76
NM
5.08
9101
"OW-108
NA
92
NA
091117101
NA
ND
9.93
NM
NM
89.89
06127/02
NA
ND
9.25
NM
NM
89.57
19/31/12
20.20
N❑
9.57
NM
10.63
99.15
04/01/14
20.20
NV
5J2
NM
14.98
9.3.60
10/21/14
2020.
ND
8.05
NM
12.15
90.77
06/08/15
20.20
ND
7.02
NM
13.18
91.80
02117114
20.20
NT)
5.17
NM
15,03
93,65
11/30/16
20.20
ND
91A
NM
10.56
89.18
07/19/17
10.20
ND
715
NM
13,05
91.67
12/13/17
20.20
ND
849
NM
11.71
90.33
06/26/18
20.20
ND
7.98
NM
12 22
90.84
a1103119
20.21)
ND
4,45
NM
15 75
94.37
07/02119
20.20 1
ND
6.27
NM
11.93
9255
12112(19
20.20
ND
6R)
NM
13.51
921.}
tf 11HY+00WOPr Iip411d snrurrrry41 WO Gnr+rzNw+ran midi uanc.0 rrmm h mrer tM" mn ARIA G.AWOPN IN If ONO IN1 I Not? Page 1 of 3
Table 2: Summary of Well Construction and Groundwater Elevation Data
Carolina Fast Mart #4 Pit Stop
Concord. Ca6arrus County
NCDEQ GWI#. B403
Well ID
Dale
insiailed
Top of
Casing
Elevation
(feet)
Well
Diameter
(inches)
As -built
Depth
(feet)
Screened
Interval
(feet)
Field Measurements
Field Calculations
Ganging
Dale
Total
Depth
(feet)
Depth to
Free
Yroducl
(feet)
Depth to
Static
Water
f feet}
Diff. 1letweeu
As -built and
Measured
Total Depth
(feet)
Measured
Water
Column in
Well
(feet)
Groundwater
Elevation
(feet)
MW-13
NA
99.3
2
NA
09107/01
NA
ND
9.3
NM
NM
90,02
06127/02
NA
ND
10.29
NM
NM
89.04
10/31/12
15.20
ND
10.48
NM
4.72
89.84
041111/14
i5.20
ND
5.19
NM
10.01
94.13
10/21/14
15.20
ND
9.36
NM
5.84
89.96
06/08/15
15.20
ND
7A9
NM
7.71
91.83
02117/16
15.20
ND
5.36
NM
9.84
93,96
11/30/16
15.20
N❑
10.54
NM
4.66
88,7,6
01/19/17
15.20
ND
7.71
NM
7.49
91.61
12/13/17
15,20
N❑
9.11
NM
6.09
90,21
06/26/18
15,20
ND
7,73
NM
7.47
91,59
01/03/19
15.20
NU
4.34
NM
10,86
94,98
07/02/19
15.20
ND
6.17
NM
9.03
93-15
12112A9
15.20
ND
7.01
NM
2.19
92.31
htW-14
NA
9:t '4
_
J A
09MV01
NA
ND
4.74
NM
NM
88.50
06127102
NA
ND
5.8f,
NM
NM
87.38
10/31/12
19.21
ND
5.02
NM
14.19
88.22
04/01/14
19.21
ND
2.76
NM
16A5
90.48
10/21/14
19.21
ND
1.42
NM
17.79
91M
06/08/15
19.21
ND
L 68
NM
16.53
90.56
02/17/16
19.21
ND
1 91
NM
17,30
91.33
11130116
19.21
N❑
4 52
NM
14,69
88.72
07119/17
19.21
ND
2.64
NM
16.57
90.60
12113/17
19.21
ND
3,71
NM
15,50
89.53
06126119
1921
ND
353
NM
15.68
89.71
01/03/19
19.21
NA
0.80
NM
19,41
92A4
07/02/19
19.21
ND
2.31
NM
16.90
90.93
12/12/19
19.21
ND
2.38
NM
16.83
9(06
MW-15
09/04/13
98.0
20
091041t3
20.25
ND
8.62
-0,25
I1.63
90 31
04/01/14
20.25
NO
4.83
-015
15,42
94.10
10/21/14
20,25
ND
8.25
425
12,00
90.68
06108115
20.25
ND
6,91
-0.25
13.34
92.02
02/17)16
2025.
N❑
4A
-0.25
15.45
94.13
11/30/16
20.25
ND
9,67
-0.25
10.63
89.31
07/19/17
20.23
ND
7.02
-0.25
13.23
91.91
12/13/17
20.25
Nil
8.48
-0.25
11.77
90.45
06/26/13
20.25
ND
8.03
-0.25
12.22
90.90
01103/19
20.25
ND
4.2
-0.25
1fr.05
94.73
07/02/19
2015
N❑
5,62
425
14.63
93.31
12/12/19
20.25
ND
5.98
-0.25
14.27
92.95
0 � kFft)e d3%PYI A T raoIIf, & mwery or woo Cnnvl-r- and RA- +cHoi,m,r w tjov pm. learn• r,„ a,, 0 AIr Um VNF toy. Page 2 of 3
Table 2: Summary of Well Construction and Groundwater Elevation Data
Carolina Fast Mart #4 Pit stop
Concord, Caharrus County
NCDEQ GW1#: 13403
Well I
Date
Installed
Top of
Casing
Elevation
(feet)
Well
Diameter
(inches)
As -built
Depth
(feet)
Screened
Interval
(feet)
Field Measurements
Field Calculations
Gauging
Date
Total
Depth
(feet)
Depth to
Free
product
(reel)
Depth its
Static
Dater
(feet)
Dif. . Between
M-hoilt and
Measured
Total Depth
(feet)
Measured
Water
Column in
Well
(feet)
Groundwater
Elevation
(feet)
MW-16
09/04113
98.36
2
20
09104A3
19,96
NO
SA5
0,04
11'81
9011
04/01/14
19,96
ND
5.31
0,04
14,65
9105
10/21/14
R96
ND
7,95
0.04
12.11
90.31
06/011/15
19,96
N❑
6,72
0.04
13,24
91.64
02/17/16
19.96
NI}
5,21
0-04
14.75
93.15
Iii30116
19.96
ND
9,25
0.04
10,71
99.11
(17119117
19.96
ND
632
0,04
13.24
9 1. 64
12/13/17
19.96
ND
7.84
0,04
12.12
90.52
06/26/18
19.96
ND
Tal
0.04
12,95
91.35
01/03/19
19.96
N❑
4.54
A 0.04
15.42
93,82
07/02/19
19.96
ND
6,02
0.04
13.94
92.34
12)12/19
19.96
ND
6.31
0.04
13.63
92.03
MW-17
09/04/13
9?",OI
HM4113
19.94
NO
6.0
0.06
13.94
92,00
0410t114
19.94
ND
4.94
0.06
15.00
93,06
1G121114
19.94
ND
842
0.06
11.52
S9.58
061U8115
19,94
ND
3.84
0.06
16.10
94.16
02/17/16
19.94
ND
4,74
U6
15.20
93,26
11130/16
19.94
ND
9.37
0.06
10,57
89.63
07/19/17
0,94
ND
7.04
0-06
1190
90,96
12/13/11
19,94
ND
7.99
0.06
11.95
90,01
06/26/18
19,94
ND
7.12
0.06
12,82
90,88
01/03/19
19,94
ND
4A5
0.06
I5.79
93.95
07/02/19
19,94
ND
6.93
0.06
13,91
91.97
12/12/19
19,94
ND
6.91
0.06
13.03
91,09
TW-2
NA
99.18
,.
NA
09/07/01
NA
ND
9.5
NM
NM
89.68
OW27102
NA
ND
8.57
NM
Non
90.61
10/31/12
Sim.
N❑
7.96
NM
43.10
91.22
04/01/14
51.06
ND
5.63
NM
45.43
9335
101211$4
51,06
ND
7.94
NM
43.12
91.24
Of"8115
51.06
ND
4.08
NM
46.99
95.10
02/17/16
51.06
ND
5,43
NM
45.63
9175
11/30/16
51.06
ND
9.74
NM
4132
89,44
07/19/17
5106
ND
718
NM
43.SS
92.00
12113117
51.06
ND
8,62
NM
42.44
90.56
(16126118
51.06
N❑
8.41
NM
42.65
90.77
01/03/19
51.06
ND
5.66
NM
45.40
93.52
07/02/19
51.06
ND
6.34
NM
44.72
92.84
{doles:
4, Uevations are relative to a Innporary hcuehmark set with un assm ried datum
of f AVO feel; e]ara reported in feet
2, NA Nai AY6101e
3. NI?=NoiNice ted
4, 2WIind 2002 dolt horn NCDFQ files tnrnsmud 6y previous coos ultHtrl
rvwecret�o+arem, er s.� �,. Y a w. [rx+rr xIa„ r,.nr tn.rmrcxr treoµulw+nr E�vn++ i, r1.r, C,.rnw n Inar Alai @r smt Page 3 of 3
Table 3. Summary of Analytical Results - Groundwater Samples
Carolina Fast Mart #4 Pit Stop
Concord, Cabarrus County, NC
NCDEQ7 GWI # 13403
Analyfical Method—
EPA Method 62005/602
v
v
�+
!a
v
v
e
=
c
^•+
c41
m
s
e
v
e
u
n
v
v
a
v
u
!0
c
F
y
:;IE
a
s
a
n
e
a
°
zi
9
ay
u
a
m
-
L
N
M'7
Location
Date Sampled
unlL
ug1L,
uglL
uglL
t,g1L
ugll,
uglL
ug1L
o,,1L
uglL
ugrL
uglL
ueIL
2L•Standards'
1
600
Min
Soo
70
70
20
70
6
70
70
400
4110
GCL'
5,0oo
260,000
84.500
85,500
6,900
8,500
20.000
70,000
6,000
25,000
301000
28,500
25,000
MW-2
12/12/2019
dD
ND
ND
ND
tip
ND
35
N0
ND
N❑
ND
ND
WW-6
12/12/2019
ND
NO
NO
ND
ND
ND
i 1
ND
ND
ND
ND
ND
ND
MW-10$
12/12/2019
1,630
20.3
240
138,E
22.4
ND
130
37.7
276
36.3
75
222
55.8
MW-13
12/12/2019
1I3
0.77 1
0.61
1.8
0.52
0.97
ND
ND
ND
1.8
2.9
ND
ND
MW-14
i211212019
QED
YD
ND
ND
ND
ND
1.9
1.8
ND
ND
ND
NI]
ND
MW-15
12/12/2019
N❑
ND
ND
N❑
ND
ND
2.2
8.7
ND
ND
ND
ND
ND
MW-16
1202/2019
1,450
12.8
1.,
ND
ND
ND
98.2
27
49
ND
5.9
ND
ND
MW-17
12/1212019
0.8
ND
ND
ND
ND
0.54
6.5
49.4
ND
ND
ND
ND
ND
WSWA
1 Z11212019
NS - No power to well; Owner not at home.
Trip Sia}}k
12A212019
ND
ND
ND
ND
ND I ND
1 ND
I VD
I ND
L tiD
I ND
ND
ND
;N'r u t"%
l A4icrngramsper firer
2. NCt7F.Q - North Carolina Adttrinistra6ve Cade Title 15A Subchapter ?L Class GA Gro u ndwater Standards
3. NCDEQ Gross Con tarninanl Levels (or groundwater
Hold data was detected at or above 2L Standards
ND - Nnl detected
1V4= Not Analyzed
NS - Nni Sampled
Italic -iced was delecred at orabove the 1YCDEQ Grass Candminoni Levels
other detected analyzes moy be seen in the attached laboratory analytical report.
H:1Projectsi201211120116-01 Carolina Fast Mart Pit StoplReportsWR January 202MTable 3 Surnmary of Analytical Results -Carolina Fast Mart Pit Stop Page 1
Table 4: Summary of historical Analytical Results - Groundwater Samples
Carolina Fast Mart W Pit Stop
Concord, Caber s County, NC
NCOBQ G►J 0 13.403
Analtlical ylatRod—�
LPA 17nhod 61008
y-
C
-
Lx 6..
t5alr Sam plyd
u;JL'
v;rL
u«iL
-JL
uL1L
uJL
Ur)L
uZeL
u%?L
UWL
1LSIandards'
1
600
660
500
10
70
5
70
70
400
GCL'
5.6o0
24F0.1100
$4.500
Y5,500
20,000
701000
6400
25'Wo
34,000
21.mfp
MW-1
6r3717.002
NO
ND
tip
N❑
ND
ND
NA
NA
NA
NA
I041112017
ND
NO
ND
\D
2.3
ND
Ni4
7#D
ND
NO
919f303
NS
NS
SIS
Ns
NS
NS
ti5
NS
NS
NS
411IR0E4
NP
KD
NO
NO
I.]
ND
ND
N'O
KO
ND
IM02014
t0
tiD
N'D
ND
3.5
tiD
NO
tiD
\D
XD
(1l112015
N❑
NO
La
NA
i 7
No
ND
ND
ND
ND
±i 17f1016
ND
ND
ND
NO
13
ND
ti➢
NO
NO
NO
I113011016
NO
N!)
ND
ND
1.1
ND
ND
NO
NO
ND
7119+20t7
N';1
ti5
NO
N❑
1 _2
ND
N'O
WD
ND
ND
t 111311017
ND
N;7
N❑
N❑
14
ND
ND
ND
ND
ND
6l1R701%
tiD
NO
NO
ND
13
NO
ND
ND
NO
NO
1IRVII9
ND
::O
N7
ND
1.2
4.4
ND
NO
Nb
tiD
71Ii1019
ND
ND
t^7
ND
7
51 2
ND
ND
ND
tiD
1211312015
ND
N❑
N1?
ND
3.F
35A
S'P
ND
ND
tiD
MW4
D
ND
•.D
NrD
ND
N:%
tiA
NA
�kA
101,3112012
ND
ND
ND
O
1 R
ND
N❑
%D
Uri
-.
1)1411013
N$
ti5
NS
Y$
NS
NS
NS
NS
N5
..
41112014
No
\D
N7
NO
? 5
ND
ND
tiD
Nb
KD
10+21 flo 14
Nl]
\D
i':i
N❑
36
yp
NO
Np
ND
�J
4191203
ND
tiff
ND
ND
26.9
0.54
ND
NO
S:O
IND
.171201A
ND
ND
ND
ND
192
0.74
NO
ND
N17
NO
11+1011016
%D
N?
ND
ND
19
ND
ND
ND
ND
ND
71191301^
ND
tiD
ND
N❑
5
ND
ND
ND
N❑
N❑
[21E312017
tiD
ND
NO
tip
4 d
ND
ND
ND
ND
ND
472fsr20ln
tiO
•=7
N❑
I tiD
NO
NO
ND
NO
ND
11}l1019
tiD
ND
YD
.,D
1
ND
ND
ND
ND
ND
7/1/1019
NO
ND
ND
NO
1.5
M1D
ND
ND
`:D
%O
E2112n(II9
ND
N❑
ND
NO
t I
ND
NO
tiD
`O
ND
„�..+.�..1a1,m,1.1.e.. �.w.,,,,., r...-+�ww+1r r�.•.r w.r. :•x Page I off
Table 4: Summary of Historical Analytical Results - Groundwater Samples
Carolina Pso Merl 44 pit Srap
Concord, Cabs rru6 County, NC
,NCDEQ CW 1 p 13403
.{gy15Air21 NltFJMd-
EPA titernod 62009
r
t
pEp
S
c
Localfnn
lis�eSampled
u;yL'
u,JL
vy+L
+.,:r,
ur/t-
o".+L
uVL
uWL
tl)L
arJL
2L Sla ndards'
1
600
no
509
20
10
6
70
70
494
rct'
SA00
260.000
NV;00
94c00
7%Dol)
701000
5,000
25,000
361000
16,500
h1%5'-108
1,200
N66
3300
R80
1,2o0
NA
NA
NA
NA
10/31/2012
17.44V
-
9R7
706$
-1.720
N34
632
0 0
151
207
914r2913
N�
1JS
1S
NS
%S
h5
NS
NS
Nc
NS
41112014
3.6111
I>Z=.
___
All
563
149
134
23
52-�
-715
10/2112014
WO
28
-•
R96
1,110
290
376
465
117
362
6lNi2a15
Cli9
335
549
1,401
637
249
415
W13
117
545
2,17R91F
1.970Cl;
..
703
230
791.5
150
Z3.fi
512
434
11 e3N2915
11040
�9 4
1 Qr.
457 7
156
56 1
15R
196
51 1
244
7119R017
3.530
924
240
519
419
134
258
2S.6
N❑
303
IVB1 017
1.120
314
165
5.15
145
70.6
25N
:2.4
ME)
370
6RE12plA
7,2E11 I
5i1'
SAC
501
Mir
414
465
432
NO
499
711512011
994
1S3
ofI
9027
171t
02 t
82'fi
%'D
NA
NA
1/3/2019
t4R
: 4
_ . -
33.9
11
K
59.5
124
NJ)
1-D
113012019
1,790
5a 9
.,
959
]66
80.5
in
17.9
ND
ND
7+2+2019
3A00
'43
If.i
1945
555
TO
173
17.6
31.1
131
M11120i9
1.630
2.-' J
'4,
1355
130
511
27CO
3,13
75
___ij
.MW-13
f;;2712002
710
M'4
13
130
NO
NA
NA
WA
NA
10131R011
19.5
:
1 2
1.9
3.2
tip
2 4
19
3,4
\E1
ur;r2n12
X5
N5
ti3
4S
NS
ti5
NS
NS
NS
J'IMP4
17.6
'I •::`
_ •,
6
NO
MU
ND
1.7
3.4
ND
10+2112014
53
•.
?31
I I
ND
ND
43
ND
ND
FrR .n15
ND
NO
tip
ND
ND
ND
ND
NO
'ND
247l1010
D
ti6
ND
ND
T4D
N❑
117
0.89
t❑
] 11311120t6
NO
Y'1
•TJ
tip
❑ 63
ND
ti❑
051
ND
N❑
7.'19i2057
135
!
MD
2i1
ND
ND
ND
24
2,9
NI)
rLi31i017
]5.5
_ .
1
5.p5
tip
N❑
_
? 6
4.]
N❑
6.+16: 201#
19.1
9"
39�
NO
N❑
1D
3'
5.2
N❑
I!]12019
1❑
ND
Ni
TID
ND
ND
ND
N❑
ND
N❑
'MM119
':D
hD
ND
ND
1. 11
NO
ND
ND
NO
ND
12+12R019
l 3
77
61
1 in
ND
N'O
ND
1.1
:9
\❑
Page 2 of C'
Table 4. Summary of Historical Analytical Results - Groundwater Samples
Carolina Fast Mart #4 Pit Stop
Conmrd, Ca13ar s Canly, NC
:tiCD -Q Gwl 4 13403
Anal) ljcyl Melhod—s
EPA %lahad 67006
u
K
m
_
LZ
tg
-
F
Laralion
Da1r Sampled
9SIL'
a?L
ogR
-
u14
u`1L
uC/L
ug�L.
uyL
uZfL
2L 51andxrds'
I
6011
600
S00
20
70
6
70
70
400
CCL'
5.0co
260.0"
RJ S00
><SSO0
201 011
70.000
5,00a
251509
30.000
23500
IIIW-14
6.•:7r7001
ND
ti7
NO
N❑
LAW
NU
NA
NA
NA
NA
10+312a12
.N'D
%D
N➢
ND
87.6
5.8
ND
\D
NO
NQ
9F12013
NS
N'S
NS
NS
NS
NS
NS
tis
tis
N$
41I1)2014
N❑
N❑
55
25
ND
NO
NO
N➢
i02112014
ND
ND
N❑
tiD
9.6
7.P
tiD
ND
ND
NO
6r82U15
NO
tiD
NO
ND
+➢
41
NO
ND
ND
ND
V17:2016
tiD
ND
ND
N❑
38
d.;
1D
NO
ND
ND
11/3072016
NO
N❑
ND
ND
ISR
ND
ND
ND
ND
VI-M017
ND
N❑
N'Q
ND
•d 3
ND
ND
ND
NO
12/132017
NO
N❑
\❑
ND
134
17
NO
ND
ND
ND
6r16r1018
tiD
NO
ND
ND
15.3
0.8
NO
NTT
NO
N❑
1132019
NO
ND
NO
NQ
3.9
3.9
N➢
ND
ND
::D
7f2a(119
ND
NG
ND
4D
9?
48
No
ND
N❑
ti❑
12;1ir101y
U0
N❑
ND
19
18
NO
h'➢
ND
ti❑
MW-15
914MI13
ti'.D
ND
ND
13
086
No
14.0
2.9
41112a14
No
ND
ND
ND
1a.1
7.3
ND
18
0.5fi
�.^.
102112014
tiD
NO
ND
5.9
4.5
ND
1 S
54
,yO
61R2013
ND
w:l
ND
ND
79
3 _
tiD
2•'172A(e
ND
ih')
NO
N'Q
1,1.45
t
ND
0.0
ND
ND
1113a7olA
N:]
N3
ND
1❑
ND
14D
ND
711911017
ND
H➢
NO
vD
5
28
!:D
ND
NO
Np
12113120t7
ND
vD
XD
N13
0.66
NO
._
NO
tip
X➢
626r7.o18
ND
Na
SO
N➢
a.R
33
MD
ND
ND
N5
113i_019
ND
ND
tiD
NO
} ]
I.i
ND
ND
ND
ND
71L+a0i9
ND
h"l
VD
__
1 2
N'D
ND
N❑
N❑
II112r_059
ND
'i:l
ND
ND
_ _
fl 7
NO
ND
N➢
N❑
�r �NNtM 1teMerrer rwl.irr grwu�r•mn�p.A.++. pY.h•. Fir u-n rr ;. -: Fagg 3 of 6
Table 4. Summary of Historical Analytical Results - Groundwater Samples
Camlina Fast Man 04 Pit Stop
Can card, Ca ha rrtts County, NC
NCO EIQ GW14134O3
J r.all rical Mmhud-
EPA Mashed 61008
v
L
W
?
S
-
-
-
L
�
-
I.eeatlan
❑ale Sun Pkd
ugIL'
u;;1L
vWL
drJL
u;1L
uglL
vVL
%IV[.
vyL
00-
2L$1-da rds`
1
600
660
560
30
70
6
70
10
400
C.Cx!
N.000
260,000
A440O
16:00
IWO
70.000
6.000
25.000
36.000
20.500
h1W-11
9141Z013
,f I V.
59 d
40?
1'_7 R
244
116
693
70,2
151
1 M
41 r I'M 14
963
891
1❑
dfi
90A
115
96.1
11.
357
21
10121l2014
3.740
54
3?3
(2 5
71.6
43 5
726
76.2
181
14
"ai)15
1,W0
313
132
53.1
220
73
569
562
734
27I
2IM21116
1,360
17
I?:
596
109
135
92.2
193
391
404
11/3012016
302
57
5=h
116
51.2
174
1 331
17.6
24.3
107
713911P17
416
4 a
F0,5
°3k
123
21-1
231
13,7
]7
• .
12/1212017
129
g3
-
49
75.7
2.6
34
_
sr-MU1k
1,126
16.7
1112
20.3
2"
6S
lil4
N❑
772.SR41R
All
r.€1
_ ..
ND
39.2
114
19'0
Na
NA
NA
VIM19
50
5?
P.
NU
.15.7
104
12.3
23
_ •
NM
U3011019
516
9
GR +
•t
27.6
67
15.6
6.1
ND
NO
7a7 2019
1.100
14 5
M4
31.1
166
64,3
51.3
96
15.9
5 5
i Nt2R0 19
11450
12Q
3,7
t4U
98.2
27
49
1D
5.9
N❑
MIN. II
914r20i3
4.1
ND
ND
ND
3?
9.5$
ND
NO
ND
'••D
41112014
4.R
.'D
ND
ND
3
ND
NO
ND
ND
ND
1012112014
D
ND
ND
MU
16.1
031
ND
ND
.`:D
tia
61a129 t5
5.7
'tiD
NO
tiD
47
NO
ND
ND
NO
ND
2117I10111
13
%Q
NO
VO
? 1
0.01
NO
NO
tin
�l�]
1130r3016
faU
ND
WVP
ND
A_
L.81
NO
ND
ND
1+G
711912017
.1 Ir9
Na
NO
NO
19
0E7
N'O
XD
ND
i]L1
M13+2017
%D
Na
NO
NO
0.93
NO
KO
ND
ND
NY
61_6Y201R
5S
t7
ND
NO
32
0
ND
ND
ND
ND
V312019
A
ND
N❑
NO
27
12
NO
NO
NO
ND
7M 019
Io,S
ND
NO
ND
27.2
167
t'D
ND
ND
N,D
t2+t111059
0 R
!+a
ND
ND
S.5
;4,4
NO
N❑
NO
ti❑
.•u+.w.N7vra++en+t r.. abm� 0 - gym..» r,F• -- - �a= 4nr 3
Table 4. Summary of Historical Analytical Results - Groundwater Samples
Carolina Fast :Hart 04 Fil Stop
Conch rd. Ca barrus Chu n ty, NC
NCA£Q GWI4 13403
A-h4ieal nlvhod—
EPA h1el hod 62006
F
_
a
Lcc,dan
pale Sarnpled
urL'
w1L
unrL
r;IL
uZeL
s1,1L
rWL
WJL
•CR
nw`L
UAI—dirdsl
1
600
600
500
20
79
9
70
70
400
CCL'
51001}
260.000
N4,500
%S,59p
IWO
70mo
UN
25,000
30.000
29,5oo
TW-2
F2712002
W
ti❑
ND
NO
ti❑
1D
VA
NA
NA
NA
1"IP013
'41)
tiD
ND
ND
057
ND
NO
ND
ND
SD
9142013
ti'S
NS
N:
NS
N5
NS
NS
NS
YS
\S
4wlaiJ
ND
tiD
ND
ND
ND
NO
ND
No
tiD
%D
I0.7112014
tiD
tip
ND
>D
ti0
NO
?l0
ND
NO
6MI2015
N➢
ti❑
V:)
Np
ND
NO
NO
ND
No
\D
D,oaa;e
ND
ND
NO
741)
\D
NO
No
NO
NO
I i130r2016
ND
ND
%,D
N7
ND
No
10
NO
N➢
NO
7r19f2017
N➢
Hp
tiD
NH
NO
NO
tip
NO
RD
N1]
17J1312017
N➢
NO
ND
ND
No
ND
ND
ND
ND
%1)
Vllap14
N➢
NO
ND
tip
NO
No
ND
RD
ND
ND
1132019
ND
MD
NO
ND
ND
NO
ND
N[l
N➢
�D
712/2019
N❑
NO
N➢
W
ND
T90
Np
iJ1'1
ND
tl]
12112121149
N01 sawkd Ots period
n'Sw-I
41?12014
ND
N❑
ND
ND
299
0.17
NO
NO
ND
NII
Ica Itic I
ND
NA
NO
ND
27.9
0..."
No
No
NL+
ND
E+a2015
Nrl
ND
ND
ND
49
P57
NO
N➢
::D
No
211112016
NO
N.
ND
ND
103
R55
ND
N❑
ND
tiD
111301I010
ND
N❑
ND
N'D
7
ND
ND
N❑
;dD
D
711912017
ND
N❑
NE)
NO
1.1
ND
N➢
tiD
%ID
\D
12113R017
NO
tiD
ND
ND
.,
ND
NO
tiD
\D
ti7
W26FI019
140
ti❑
HD
ND
I
140
ND
\❑
AD
�D
1 r311.pt9
KS - No power en „dl; 1.lw.ler SU4n there 113 fail In wall 0ipmi Ihai Will "c d *o be repaired
112/2919
NS No pawn++. —if; 0w — g. h.rac.
1:+1 b'_, 01 v
VS - No power to '. d1; 0 caner not er home
. — -i 'F!mw# � 4aw,•�twwrlr�ar cyu ra7,5 r.r f.
Table 4-. Summary of Historical Analytical Results - Groundwater Samples
Carolina Fast Mart A Pit Slap
Concord, CAarrus Counfv, NC
NCDEQ GW1 0 13403
.ana17 [ical SlnrheA--+
EP,i Method 62008
At
r
d5
i
c
n
L.caflo..
Da[e2irmpkii
u grrL
u;1L
eL
wL
uy1L
uWL
ryyL
-WL
MVL
2L Spa ad. rd,'
l
600
600
Soo
20
70
6
70
70
400
CCL"
5.000
260,000
RC 500
NS.500
20,000
70.006
6.000
251000
30,000
ZE500
Trip 84A
11+3012016
tiD
r1D
%D
ND
ND
N❑
tiil
ND
ND
I1D
7 f19f2017
ND
N❑
NE,
tiD
Np
ND
Nf7
NC]
ND
N❑
12111+2017
N❑
N❑
\❑
ND
N❑
ND
ND
ND
ND
KI)
6126+201R
NJ
N❑
tip
ti❑
ND
YD
ND
ND
ND
ND
1,3aQ19
Mp
N❑
ND
NO
MD
ND
NTJ
ND
Np
NO
7Rf2019
ND
N❑
.ND
HD
ND
'ND
:.D
ND
ND
tiD
17r11,+2019
fit❑
ND
ND
r4D
ND
ND
\D
N"t"
f 44rr•rr4rmwx prr fffrr
7 NCOFQ - Nnffje r irnrlffrry .44rx00-ork1w Cage TINT I$A.VjM-A ,ee, 24 Ud sr GA G.rufrrrlHwlof• Sfo+o-ldr.l.
3 ,V('RO•Q Groan CnNMN,mv t.e.nlx.I.rpn7+fodwryrrr-
f,:r1►1� hd6M!/fMMW00ofriior.Oct.
7:11..I"o femn4
MA - Nut darafy-Ml
N9 • Nor Fu+rryded
2003 dam lim. NC DEQ files presenlcd 6y prrrroar mMWJ ani
Other detected analNn can he saan in the analytical data
.�M.A..m..w:n�rr.-�n••.....,.�..-.�r...,.:...,..�..�.��.- - Payefiofn
APPENDIX A
(Omitted)
(Omitted
APPENDIX C
Carolina Fast Mart #4 - Pit Stop 6P
Calibration and Field Measurment Log
Field Meter YSI Pro Pius Serial ## 15A103266
Calibration
Standard
Pre -Calibration
Read
Calibration
Read
pH 7
7
7.02
7.01
pH 4
4
4.01
4.00
pH 10
10
10.40
10.01
Spec Cond (us/cm)
1413
1452
1453
❑RP (mVolts)
200
199.9
200.1
Field Measuremnt Log
ID
D❑ (mg/L)
pH
Spec Cond
(us/cm)
Temp (GQ
❑RP (mV)
MW-2
0.93
6.54
577.4
17.9
-13.5
MW-6
1.75
6.56
616.0
16.2
24.9
MW-108
0.7
6.53
556
20.3
-100.2
MW-13
3.23
6-54
412.9
19.1
-12.6
MW-14
2.35
6.13
728
16.5
70.3
MW-15
1.01
6.47
541
20.4
-46.0
MW-16
0.66
6.48
721
19.5
-138.3
MW-17
1.02
6.51
704
18.1
-14.9
APPENDIX D
(Omitted)
WSW-1 -439 FROM CAROLINA X 11
FAST MART #4
n
1
1
r C
�r
�r
�E MW-14
c
EXXON STATION 1�
r
l �
r
I r a r r
rl al 1
1 �r
}1 e
y � 1
fj r
1
7,W.6
X3
1
r LIGH POLE_{
1�j1MW]7
LEGEND
4
TYPE q MONITORING WELL
O TW
TYPE III MONITORING WELL
FORMER MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
3KTW
TYPE III MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
WELL CASING DAMAGED - ABANDONED
UST
UNDERGROUND STORAGE TANK
FORMER UST LOCATION
WATER LINE
—urs—c►s—
GAS LINE
c --r
ELECTRIC POWER
OVERHEAD ELECTRIC POWER
DRAINAGE FEATURE
-�-
PROPERTY BOUNDARY
—R-O-W -- - —
RIGHT-OF-WAY
0
LIGHT POLE
*1 12
' NOTES:
MW-13 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A.
UST DATED 07-02.
PIT 2. ALL LOCATIONS ARE APPROXIMATE.
4
mw-10
r
' f �{� 1�W.,DB
+ 1 s DJe�C (oTw 2
rl '
v-�- v— v v— v v— v— v— v ---- v v— v v— M— v ,-._ v— v ---- w ---- w— v
' omw-15
MW-8
`---------R-O-W--------- ---------- --------------- -
U.S. HIGHWAY 29
GRAPHIC SCALE
0 10 20 30 L4
SCALE, 1 in. + 40 n.
�Q I T4GC�T CR�K
IELD
SH
2a70agOM1C7
%-3at4gu
""'"
ENGINEERING, INC.
"°"" """" ° °"
SITE MAP
CAROLINA FAST MART #4 PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, NORTH CAROLINA
iHI6 9 1120116
DATE : 01/15/2020 DRAWN BY: KPS
5CALE : AS SHOWN FIGURE: 2
LEGEND
0 SITE SOURCE
N 55013440760000 PARCEL IDENTIFICATION NUMBER
WATER SUPPLY WELL - USED FOR
NON -POTABLE PURPOSES
WATER SUPPLY WELL - WELL USE
UNCERTAIN
�- WATER SUPPLY WELL - NOT IN USE
CONNECTED TO MUNICIPAL WATER
WATER SUPPLY WELL - WELL LIKELY
NOT IN USE (VACANT LAND)
-__ _ _ _ _ _ INTERMITTENT DRAINAGE FEATURE
fWSw•3 t,
t
1
S WSW- wsw-a
t
\, wsw- �` 1
wsw-2 55093466140000 0If
r-
�rgeSIT 55093492310000 i• 1
J
—�- - /55093328410WO 5"3377 1
NOTES:
�.' ► 1. REFERENCE CABARRUS COUNTY GIS.
+ 'Q�, ► 2. ALL LOCATIONS ARE APPROXIMATE.
� _ � ���� 55043355230000
1 �
►►
� 1 -
- �l 1
GRAPHIC SCALE
`��- --- - ��Q. - V 16a 2w 307
WSIV•9 SCALE: 1 In. - 300 Ft.
`— L14aH1,6TTC, NC 78N!
wsW-7SHIELD
�� ENGINEERING, INC.
oa, E► 1, 500' RADIUS MAP
CAROLI NA FAST MART #4 PIT STOP
3690 CONCORD PARKWAY SOUTH!
CONCORD, NORTH CAROLINA
_ 5111EL0 9 1120f (6,Of
l DATE: 07/26/2019 DRAWN BY, MTS
SCALE : AS SHOWN FIGURE : 3
WSW-1 -439 FROM CAROLINA
FAST MART #4
M
1
EXXON STATION
0
w
X 11
PUMP
ISLAND
CANOPY
_e MW-14
(90.861
�e
91
1
r '
I I►
1
11 �I 3
� fffl ►
5
--------------
Awl, ►
94.z�� Q \
' %%� HT POLE r
MW-17 I
CA�}L�iAt 'TW-1 I I
FAST MA 'L (NM)
yPIT STOP 'IA / / �(92 92,31) UST
4� 0 ►� ~ `1. PIT
4
-
1 MW-16
+ m192.03)
1 ' �MW 1013 k
_-9._ 1�-z- 1
,r 9x.0 "� (NMI." �
LV -I v Y '80 Y V
l *MW-15
1 (92.95) MW-8
----------R-O-W--------------_--_--------------------
U.S. HIGHWAY 29
LEGEND
0 TYPE 11 MONITORING WELL
O TW TYPE III MONITORING WELL
FORMER MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
TW
TYPE III MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
WELL CASING DAMAGED - ABANDONED
UST
UNDERGROUND STORAGE TANK
FORMER LIST LOCATION
—Y --Y WATER LINE
--rat— GAS LINE
t —[ ELECTRIC POWER
DRAINAGE FEATURE
PROPERTY BOUNDARY
--R-O-W — - - — RIGHT-OF-WAY
LIGHT POLE
(ft)
FEET
(92.23)
GROUNDWATER ELEVATION (ft)
[92-841
GROUNDWATER ELEVATION (ft) NOT
USED IN CONTOURING
-- — — GROUNDWATER POTENTIOMETRIC
CONTOUR LINE
ESTIMATED GROUNDWATER FLOW
DIRECTION
(NM) NOT MEASURED
NOTES:
1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P,A.
DATED 07-02.
2. ALL LOCATIONS ARE APPROXIMATE.
3. DEPTHS TO GROUNDWATER MEASURED ON D70Z/2D19.
4. CONTOUR INTERVAL AS SHOWN,
GRAPHIC SCAU
a fo �
SCALE; 1 W • 40 ft.
SHIELD
zezoeaono
w�esa''Tc
ENGfNEER1NG, INC.
GROUNDWATER
CAROLINA FAST MART #4 PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, NORTH CAROLINA
5HIELD 1 1120116
DATE : 1/15/2020 1 DRAWN BY : KPS
SCALE : AS SHOWN i FIGURE : 4
WSW-1 -430' FRONT CAROLINA 11
(ND) FAST MART #4
r
1
n
1
r C
�f
_e MW-14
— e __(ND)
r
EXXON STATION ' f`
r1
3
0
N
Y
+' AW-6 5
1 ,sND,_---
�� 3
LIGHT POLE
i 7
a i ' e
10 r -CbRDLINA
1 r f i } ✓FAST MART
J f PIT STOP / r *'MW-13
MW.2 "(11.3)
INDI
C' gr
r ll� -16
+ I (1,450) 1
I(1630
10 - 1Tw2/
INS]
V� V V- V V V V ---- Y --- V V- v -
' �MW 15
(ND) ig� MW-8
—R-O-W-------- —__—
U.S. HIGHWAY 29
12
1
1
3K 1
1
UST
PIT
4
LEGEND
4
TYPE II MON(FORING WELL
O TW
TYPE III MONITORING WELL
3K
FORMER MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
)K7W
TYPE III MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
WELL CASING DAMAGED - ABANDONED
UST
UNDERGROUND STORAGE TANK
FORMER UST LOCATION
— v — v WATER LINE
—cRs-FAI- GAS LINE
—c —c ELECTRIC POWER
----�- OVERHEAD ELECTRIC POWER
---- PROPERTY BOUNDARY
—R•O-W — - - — RIGHT-OF-WAY
0
LIGHT POLE
(ug/L)
MICROGRAMS PER LITER
(3,400)
BENZENE CONCENTRATION (ug/L)
INS]
BENZENE CONCENTRATION (ug/L) NOT
USED IN CONTOURING
— — — — — BENZENE tSOCONCENTRATION LINE (ug/L)
(ND) NOT DETECTED AT OR ABOVE
LABORATORY DETECTION LIMITS
INS) NOT SAMPLED
NOTES.
J
1. REFERENCE 51TE PLAN BY ENGINEERING TECTONICS, P.A.
DATED 07-02.
'
2. ALL LOCATIONS ARE APPROXIMATE.
!
3. GROUNDWATER SAMPLES COLLECTED ON 1711717019.
4. CONTOUR INTERVAL AS SHOWN.
V t-V --V --+-V -v -V -V -V -V TV V
GRAPHIC 51ALE
© 7Q 20 30 49
5C.ALE; 1 in. - 40 fL
SHIELD �M� �� n�a�A,
ENGINEERING, INC.
BENZENE
CAROLINA FAST MART PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, NORTH CAROLINA
SHIELD d 1120116
DATE : 1/15/2020 DRAWL BY: KPS
SCALE : AS SHOWN FIGURE: 5
WSW-1 -430' FROM CAROLINA X 11
111 FAST MART #4
r
1
w CCANOPY
c
�r
_x MW-14
EXXON STATION !'
r
N MW-6 a 5
' ?K 3
POLE_ {Z MW-17
}1 ,►
4
a' +' CAROLINA TW-I.
+ FAST MART
' PIT STOP I * MW-13
MW-z
►f 1 f5.81
s r^ 20
' �J� -MW 16
► � '1��148.2I
W 10
? 10
1 +
U.S. HIGHWAY 2. 9 V
U.S. HIGHWAY 29
X 1
LEGEND
®
TYPE 11 MONITORING WELL
TA+
TYPE III MONITORING WELL
FORMER MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
3KTW
TYPE III MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
WELL CASING DAMAGED - ABANDONED
UST
UNDERGROUND STORAGE TANK
FORMER UST LOCATION
v — v
WATER LINE
—ra—ram---
GAS LINE
c —x
ELECTRIC POWER
DRAINAGE FEATURE
-� -
PROPERTY BOUNDARY
— - R-O-W - - —
RIGHT-OF-WAY
0
LIGHT POLE
(ug/L)
MICROGRAMS PER LITER
MTBE
METHYL-TERT-BUTYL ETHER
(130)
MTBE CONCENTRATION (ug/Ly
[NSI
MTBE CONCENTRATION (ug/L) NOT USED
IN CONTOURING
-- — — — — —
MTBE 15000NCENTRATION LINE (ug/L)
(ND)
NOT DETECTED AT OR ABOVE
LABORATORY DETECTION LIMITS
(Ns)
NOT SAMPLED
NOTES-
1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A.
+1 DATED 07.02.
2. ALL LOCATIONS ARE APPROXIMATE.
3. GROUNDWATER SAMPLES COLLECTED ON 12/12/2019.
4. CONTOUR INTERVAL AS SHOWN.
V V -V V ---V
�y5
M2 1 MW-8
---- R-O-W---_—__—__—_----------------------- --
GRAPHIC SCALE
0 TO 20 30 48
SCALE: } in.. a 40 it.
GP MRiLOT If.. NC 29288
SHIELD{,ui inun7er UeCK eivi:
ipa� ]w Gv
�na.i0voaiu
ENGINEERING, INC.
MTBE
ISOCONCENTRATION MAP
CAROLINA FAST MART PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, NORTH CAROLINA
SHIELD a 1120116
DATE :
1 / 15/2020
DRAWN BY: KPS
SCALE w
AS SHOWN
FIGURE : 6
WSW-1 -439 FROM CAROLINA oil
INDI FAST MART #4
M`
1
1
L
MW-14 I&
�r fi(NDj i
r_
EXXON STATION ' j
1 ~
or
r
I1 s '
� f ►
r
,'�► rr1
I f
' f 1
v�1
l'
j 3
1 1 Q
1 +
I r
'r r
It ,+
N h1W-6 0 5
��f1vDj ._^_-------
r
►
J X 3
POLEW
'
17
rr
(ND)
CAROLINA TW-1
r
FAST MART
'
r
PIT STOP I
MN) 3
MW-2,
J� r
iND)
1
'
MW-16
1441.
'
t
`L (AMw 06
6)
'
J
I
1O -2
r INS)
r
v!�—v v-
1
U.S. HIGHWAY 29
fig-W-15V Y �V �^Y Y �-Y -Y
M
(ND) �k MW-S
---R-O-W-----------------
v ---v —+-v —v —v —V —v —v —v —V
LEGEND
0
TYPE 11 MONITORING WELL
O TW
TYPE III MONITORING WELL
FORMER MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
TW
TYPE III MONITORING WELL PAVED OVER
OR UNABLE TO BE LOCATED
WELL CASING DAMAGED - ABANDONED
UST
UNDERGROUND STORAGE TANK
FORMER UST LOCATION
—v —v
WATER LINE
--w ras--
GAS LINE
^r —e
ELECTRIC POWER
DRAINAGE FEATURE
----
PROPERTY BOUNDARY
— -R-O-W - - ---
RIGHT-OF-WAY
0
LIGHT POLE
(uglt)
MICROGRAMS PER LITER
(276)
NAPHTHALENE CONCENTRATION (ug/L)
[NS]
NAPHTHALENE CONCENTRATION (uglL)
NOT USED IN CONTOURING
— — — — — —
NAPHTHALENE ISOCONCENTRATION LINE
(uglL)
INDj
NOT DETECTED AT OR ABOVE
LABORATORY DETECTION LIMITS
(NS)
NOT SAMPLED
NOTES:
1. REFERENCE SITE PLAN
BY ENGINEERING TECTONICS, P.A.
DATED 07-02.
2. ALL LOCATIONS ARE
APPROXIMATE.
3. GROUNDWATER SAMPLES COLLECTED ON 1211212019.
4. CONTOUR INTERVAL
AS SHOWN.
GRAPHIC SCALE
0 10 20 30 40
SCALE! 1 in. - 413 ft,
SHIELD cMtAGGART CREEK eou ac 2a2oe�ona
ENGINEERING, INC. ^., '" °` ° ^•^ "`"
NAPHTHALENE
ISOCONCENTRATION MAP
CAROLINA FAST MART PIT STOP
3690 CONCORD PARKWAY SOUTH
CONCORD, NORTH CAROLINA
SHIELD If 1120116
DATE:
1 / 15 /2020 DRAWN BY: KP5
I
SCALE :
AS SHOWN FIGURE: 7
APPENDIX E
Constituent Concentrations vs Time/Hydrograph: MW-1013
Carolina Fast Mart #4 - Pit Stop
m
18,000
16,000
0 12,000
m
c
10,000
0
LJ
c
� 8,000
C
6
v 6,000
95
94
93
C
42 O —
m
--$--Benzene
(Total Xylenes
—*-- MTS E
N
91
--o*—Diisopropyl ether
3
o
Naphthalene
l7
--*—Groundwater Elenat}on
90
4,000 —
8S
2,000
4/19/2DD1 1/14/2004 10j10/2006 7/6/2009 4/1/2012 12/27/2014 9/22/2017 6/18/2020 3/15/2023
Date
5,000
J
mad
4,000
e
0
c
3,000
v
e
Z, 2,000
0
U
1,000
0
1/1/2013
Constituent Concentrations vs Time: MW-16
Carolina Fast Mart #4 - Pit Stop
5/16/2014 9/28/2015 2/9/2017 6/24/2018 11/6/2019
Date
95
94
93
90
89
88
3/20/2021
--*--Benzene
--O— MTBE
--�-Naphthalene
--t—Groundwater Elevation
12.0
10.0
8.D
2.0
0.0 -
4/1/2012
Constituent Concentration vs Time/Hydrograph: MW-17
Carolina Fast Mart #4 - Pit Stop
8/14/2013 12/27/2014 5/10/2016
Date
9122/2017 2/4/2019
180.0
160.0
140.0
120.0 .,
100.0
7
v
80.0 w
p1
+Benzene
3
60.0
--MTBE
°
—r[—Diisopropyl ether
40.0 "
+Groundwater Elevation
20.0
0.0
-20.0
6/18/2020
APPENDIX F
(Omitted)
APPENDIX G
(Omitted)
APPENDIX H
(Omitted)
APPENDIX I
ace*alylical
www.paceiab6.cern
December 24, 2919
Kevin Stachura
Shield Engineering, Inc.
4301 Taggart Creek Road
Charlotte, NC 28298
RE: Projects Pit Stop BP
Pace Project No.: 92457416
Dear Kevin Stachura;
Pace Analytical Services, LLC
9800 Kinc" Ave. S,lite ian
Huntersville, NC 28079
(704)875-9092
Enclosed are the analytical results for sample{s) received by the laboratory on December 13, 2919.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Amanda Payne
amanda-payne@PaGelabs.com
paeelabs.com
�794)875-9092
Project Manager
Enclosures
A ex
REPORT OF LABORATORY ANALYSIS
This Fepork Shall not be FepfoduGed, except,r1 Full.
withouI the wrllien cpnsent ❑F Pace Analy6raI services_ LLC
Page 1 of 36
ace Analytical
www.paselsLs.com
fr
I
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
(704)875-9092
CERTIFICATIONS
Project: Pit Slop BP
Pace Project No.. 92457416
Pace Analytical Se►yIces Charlotte
9800 Kincey Ave. Ste 100, Hunters vil le. NC 28078
South Carolina Certification At: 99006001
Louisia n a1N E LAP Certification 4 LA170028
FloridalNELAP Certification * E87627
North Carall na Drinking Water Certification M 37706
Kentucky UST Certification* a4
North Caroll na Field Services Certification * 5342
Virginia(VELAP Certification #: 460221
North Carolina Wastewater Certification #: 12
REPORT OF LABORATORY ANALYSIS
This report shall not be reprrsduced. except In full,
without the written consent of PaceAnal yUcA Services, LLC. Page 2 of 36
ciceAI1r3vlcal
+�+ www,paCnlaES.Com
i
SAMPLE ANALYTE COUNT
Pace Analytical Services, LLC
9800 KinceyAve Suite i00
Huntersv0le, NC 28078
(704)875-9092
Project'
Pace Project No.
Pit Stop SP
92457416
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92457416001
MW-2
SM 62006
CL
63
PASI-C
92457416002
MW6
SM 6200B
CL
63
PASI-C
92457416003
MW-108
SM 6200B
CL
63
PASI-C
92457416004
MW-13
SM 6200B
CL
63
PASI-C
92457416005
MW-14
SM 626013
CL
63
PASI-C
92457416006
MW 15
SM 6200B
CL
63
PASI-C
92457416007
MW-16
SM 6200E
CL
63
PASI-C
92457416008
MWA 7
SM 6200E
CL
63
PAS!-C
92457416009
TRIP BLANK
SM 62008
CL
63
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be fepf(>dur-ed, except in Full,
Without the written consent of Pace Analytical Services, LLC Page 3 of 36
Pace Analytical Services, LLC
w
ical 99t7U KinceyAve Suite 1I]D
HuRiersville, NC 20078
113c,
www.peoeleEe.enm
t711d]B75-9092
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Project No.. 92457416
Sample: MW-2 Lab ID; 92457416001 Collected; 12/12/19 13:50 Received: 12113A9 14:26 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual
6200B MSV Analytical Method: SM 6200B
Benzene
NO
uglL
0,50
1
1212011918.46
71-43-2
Bromobenzene
ND
ug1L
0.50
1
12/2011918-46
108-86-1
Bromochloromethane
ND
uglL
0.50
1
12/2011918:46
74-97-5
Bromadichloromethane
;ND
uglL
0.50
1
12120/1918:46
75-27.4
Bromoform
ND
ug1L
0.50
I
1212011916:46
75-25-2
Bromomethane
ND
ug/L
5.0
1
12/20/19 18:46
74-83-9
n-Butylbenzene
NO
uglL
0,50
1
12/2011918:46
104-51-8
sec-Butylbenzene
ND
uglL
0.50
1
1212011918:46
135-98-8
ter!-Butylbenzene
NO
uglL
0.50
1
12/2011918.-46
98-06-6
Carbon tetrachloride
NO
uglL
0.50
1
12/20/19 18:46
56-23-5
Chlorobenzene
ND
uglL
0.50
1
1212011918:45
108-90-7
Chicroethane
NO
ug1L
1.0
I
1212011918:46
75-00-3
Chloroform
NO
uglL
0.50
1
1212011916:46
67-66-3
Chlaromethane
ND
ugIL
1.0
1
1212W1918:46
74-87-3
2-Chlorotoluene
N❑
uglL
0.50
1
1212011918,46
95-49-5
4-Chlorotoluene
NO
uglL
0.50
1
12/20119 18:46
1 D6-43-4
12-Dibromo-3-chlorapropane
ND
uglL
1.0
1
12/20/19 18:46
96-12-8
Dlbromochloromethane
ND
ug1L
0.50
1
12/20/19 18:46
124-48-1
1,2-Dibromoethane (EDB)
NO
ug1L
0.50
1
12/20/19 18:46
106-93-4
Dibromomethane
NO
uglL
0.50
1
1212011918A6
74-95-3
1,2-Dichlorobenzene
ND
uglL
0,50
1
1212011918:46
95-50-1
13-❑ichiorobenzene
NO
ug1L
0.50
1
12/2011918:46
541-73-1
1 A-Dichlorobenzene
NO
ug1L
0.50
1
12/20/19 18:46
106-46-7
❑ichlorodlfluoromethane
NO
uglL
0.50
1
12120/1918:46
75-71-8
1,1-Dichloroelhane
NO
uglL
0.50
1
12120/1918-46
75-34-3
1,2-Dichloroethane
NO
uglL
0,50
1
1212011918:48
107-06-2
1,1-1)ichloroethene
NO
uglL
0.50
1
1212011918:46
75-35-4
cis -1,2-Dichloroethene
ND
ug1L
0,50
1
12i2011918A6
156-59-2
trans-1,2-Dichloroethene
NO
ug1L
0.50
1
1212011918A6
165-60-5
1,2-Dichlorapropane
NO
U91L
0.50
1
1212011918A6
78-87-5
1,3-Dlchloropropane
ND
ug1L
0 50
1
12/20/19 18.45
142-28-9
2,2-Dichloropropane
ND
uglL
0.50
1
1212011918-46
594-20-7
1,1-Dichloropropene
NO
ug1L
0.50
1
12120/1918:46
563-58-6
cis-1,3-Dichlompropene
ND
uglL
0 50
1
12/20/19 18:46
10061-01-5
trans-1,3-01chlompropene
ND
ug1L
0.50
1
12/2011918-46
10061-02-6
Diisopropyl ether
35.0
uglL
0,50
1
12/20/19 18:46
108-20.3
Ethylbenzene
NO
uglL
0.50
1
1212011918:46
100.41-4
Hexachloio-1,3-butadlene
NO
u91L
2,0
1
12120/1918:46
87-68-3
Isopropylbenzene (Cumene)
NO
uglL
0.50
1
12120119 18:46
98-82-8
Methylene Chloride
ND
uglL
2.0
1
121M0119 18-46
75-09-2
Methyl-tert-butyl ether
5.8
uglL
0.50
1
12/20119 16:46
1634-04-4
Naphthalene
NO
uglL
2.0
1
12/20/19 18 46
91-20-3
n-Propylbenzene
ND
ug1L
0 50
1
12/20/19 18:48
103-65-1
Styrene
NO
uglL
0.50
1
12/20119 18-46
1 D0-42-5
1,1,1,2-Tetrachloroethane
NO
uglL
0.50
1
1212011918:46
630-20-6
1,1,2,2- Tel rachlaroethane
ND
u91L
0.50
1
1212011918:46
79-34-5
Tetrachlorcethene
ND
uglL
0.50
1
1212011918:46
127-18-4
REPORT OF LABORATORY ANALYSIS
Thi& report shall not be reproduced, except In full,
Date: 12/24/2019 10:41 AM .Without the Wntten Chn Sent or Pace Analytical Services. 1- LC Page 4 of 36
aceAnalXical
www.pawleh�.cvm
ANALYTICAL RESULTS
Pace Analytical Senllte2s, LLC
9800 KinceyAve . Suite 100
Huntersvilla, NC 28078
[704]875-9092
Project: • Pit Stop BP
Pace Project No.: 92457416
Sample: MW-2 Lab lD: 92457416001 Collected: 12/12/19 13:50 Received: 12/13/19 14:28 Matrix: Water
Parameters
Results
units
62000 MSV
Analytical Method: SM 6200B
Toluene
ND
uglL
1,2,3-Trichlorobenzene
NO
uglL
1,2,4-Trichlorobenzene
NO
uglL
1,1,1-Trlchlomethane
NO
uglL
1,1,2-Trichlome'thane
NO
uglL
Trichloroethene
No
uglL
Trichlorofiuoromelhane
N❑
uglL
1,2,3-Tdchloropropane
NO
uglL
1,2,4-Trimethylbenzene
NO
uglL
1,3,5-Trirnethylbenzene,
N❑
ug1L
Vinyl chloride
NO
uglL
m&p-Xylene
NO
uglL
o-Xylene
NO
ugll-
Sumogafes
4,2-❑1chloroethane-d4 (S)
91
%
4-Bromofluorobenzene (S)
96
%
Toluene-d8 (S)
102
%
❑ate: 12/24/2019 10:41 AM
Report Limit DF Prepared Analyzed CAS No. Qua]
0.50
1
12/20119 18:46
108-88-3
2.0
1
12120/1918:46
87-61-6
2.0
t
1212011918:46
120-82-1
0.50
1
1212011918;46
71-55-6
0.50
1
12MI1918:46
79-00-5
0.50
1
12/2011918:46
79-01-6
1 0
1
1212011918:46
75-69-4
0.50
1
1D20/1918:46
96-18-4
0.50
1
12/2011918,46
95-63-6
0,50
1
12120M 9 15:46
108-67-8
1.0
1
12120/1918:46
75-01-4
1.0
1
12/20/19 18:46
179601-23-1
0,50
1
12/2011918:46
95-47-6
70-130
1
12/20/19 18:46
17060-07-0
70-130
1
1V2011918:46
460-00-4
70-130
1
1212011918AB
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report s}tali not tie reproduced, except in full,
without the written can sent of Pace Analytical Services, LLC
Page 5 of 36
11!;a'ceAnalAcal
f � www.pesele5e.tom
I
ANALYTICAL RESULTS
Pace Analytical Services, LLG
9800 Klncey Ave. Suite 100
Huntersviile, NC 28078
(704)875-9092
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW6 Lab IR: 92457416002 Collecled: 12/1211913:05 Received: 121i3119 14:28 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed
CAS No. Qual
6200E MSV
Analytical Method_
SM 0200B
Benzene
NO
uglL
0.50
1
12120/1917:15
71-43-2
Bromobenzene
NO
ug)L
0,50
1
1212011917:16
108-86-1
Bromochioromethane
ND
uglL
0.50
1
12120/1917:16
74-97-5
Bromodichloromethane
NO
uglL
0.50
1
1212011917:16
75-27A
Bromoform
ND
uglL
0.50
1
1212011917:16
75-25-2
Bromomethane
NO
uglL
5.0
1
1212011917:16
74-83-9
n-Butylbenzene
NO
uglL
0,50
1
1212011917:16
104-51-0
sec-Butylbenzene
NO
uglL
0,50
1
1212011917'16
135-98-8
tent-Butylbenzene
ND
uglL
0.50
i
1212011917:16
98-06-6
Carbon tetrachloride
NO
ug1L
0.50
1
12/20/19 17:16
56-23-5
Chlorobenzene
ND
uglL
0,50
1
1212011917:16
108-90-7
Chloroethane
NO
uglL
1.0
1
12/20/19 17:16
75-00-3
Chtoroform
ND
uglL
0,50
1
1212011917:16
67-86.3
ChIaTomethane
ND
uglL
1.0
1
1212011917'16
74-87-3
2-Chlorotoluene
ND
ug1L
0.50
1
12/2011917:16
95-49-8
4-Chloratoluene
NO
uglL
0,50
1
1212011917:16
106-43-4
1,2-Dibromo-3-chloropropane
NO
uglL
1.0
T
12/2011917:16
96-12-8
Dibromochloromethane
ND
uglL
0.50
1
12/20/1917-16
124-48-1
1,2-Dibrornoethane (EDB)
NO
uglL
0.50
1
12120/1917:16
106-93-4
Dibromomethane
NO
UgIL
0.50
1
12120/1917:16
74.95.3
1,2-DiWorobenzene
NO
uglL
0.50
1
1212OJ1917A6
95-50-1
1,3-Dichlorobenzene
ND
uglL
0,50
1
12120119IT16
541-73.1
1,4-Dichiorobenzene
NO
uglL
0.50
1
121201191716
106-46.7
Dichlorodifluoromethane
NO
uglL
0 50
1
12120J19 17:16
75-71-a
1,1-Dichloreethane
NO
ug1L
0.50
1
12120J1917:16
75-34-3
1,2-❑ichloroethano
N❑
uglL
0,50
1
1212011917:16
107-06-2
1,1-Dichloroethene
ND
uglL
0.50
1
1212011917.16
75-35-4
cis-1,2-Dichloroethene
N❑
u91L
0.50
1
1212011917A6
156-59-2
trans- 1, 2- D ichloroe thene
ND
ug1L
0.50
1
1212011917:16
156-60-5
1,2-Dichioropropane
ND
uglL
0.50
1
1212011917-16
7a-87-5
1,3-Oichioropropane
NO
uglL
0.50
1
12/20/19 VAG
142-28-9
2,2-Dichioropropane
NO
uglL
050
1
12120119 17:16
594-20-7
1,1-Dichleropropene
NO
ug&
0.50
1
12/20/1917:16
563-58-6
cis- 1,3-Dlchlaropropene
ND
uglL
0.50
1
'I212011917:16
10061-01-5
trans -1,3-Dichioropropena
NE]
ug&
0.50
1
1212011917:16
1D061-02-6
Diisopropyl ether
NO
uglL
0,50
1
12/20/1917:16
108-20-3
Ethylbenzene
ND
uglL
050
1
12/20/19 17:16
100A1-4
Hexachloro-1,3-butadiene
ND
uglL
2.0
1
1212011917:16
87-68-3
Isopropylbenzene ICumenej
NO
uglL
0,50
1
12/20/19 17:16
98-82-8
Methylene Chloride
NO
uglL
2.0
1
12/20/19 17.16
75-09-2
Methyl-tert-butyl ether
1A
uglL
0.50
1
12/20/19 17:16
1634-04-4
Naphthalene
N❑
uglL
2 0
1
12120/19 17:16
91-20 3
n-Propylbenzene
NO
uglL
0.S0
1
1212011917:16
103-65-1
Styrene
ND
uglL
050
1
12/20/19 17A6
100-42-5
1,1,1.2-Tetrachlorcethane
ND
ug1L
0.50
1
12120/1917:16
630-20-6
1.1.2,2-TetrachI=ethane
NO
uglL
0.50
1
1212011917'16
79-34-5
Tetrachloroethene
NO
uglL
050
1
12/20/19 17:16
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced, except in lull,
Date: 12/24/2019 10:41 AM withouI the wniten consent or Pace Analytical Services, LLG Page 6 of 36
aceAnalXical"'
www.pocdsbmam
ANALYTICAL. RESULTS
Pace Analytical Services, LLC
9800 Kin cey Ave. Suite 100
Hunteraville, NC 28078
(?04)575-9092
Protect: Pit Slop 0P
Pace Project No., 92457416
Sample: NW-6 Lab ID: 92457416002 Collected: 12/12119 13:05 Received: 12/13119 14:28 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual
62008 MSV Analytical Method: SM 62008
Toluene
NO
uglL
0.50
1
12120/1917:16
108-88-3
1,2,3-Trichlorobenzene
ND
uglL
2.0
1
12/20/1917:16
87-61-6
1,2,4-Trichlorobenzene
ND
uglL
2,0
1
1212011917:16
120-82-1
1.1,1-Trichloroethene
NO
uglL
0.50
1
1212011517:16
71-55-6
1,1,2-Trichlornethane
NO
uglL
0-50
1
1212011917'16
79-00-5
Trichloroethene
NO
uglL
U0
1
1212011917:16
79-01-6
TrlchioroRuoramethane
NO
uglL
1.0
1
1212011917:16
75-69-4
1,2,3-Trichloropropane
NO
ug1L
0.50
1
12120/1917:16
96-18-4
1,2,4-Trimelhylbenzene
NO
uglL
0.50
1
12120119 17: 16
95-63-6
1,3,5-Trlmethylbenzene
ND
ug1L
0.50
1
1212011917:16
1OM7-8
Vinyl chlorlde
NO
uglL
1.0
1
12/20/19 17:16
75-01-4
m&p-Xylene
NO
uglL
1.0
1
1212011917*16
179501.23-1
o-Xylene
NO
uglL
0.50
1
12120/1917:16
95.47-6
Surrogates
1,2-Dichlaroethane-d4 (S)
94
%
70.130
1
12/20/19 17:16
17060-07-0
4-Brornoliuorobenzene lSj
95
`S6
70-130
1
12/20/19 17:16
460-00-4
Toluene-d8 (3)
101
4
70-130
1
12120/19 17:16
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not pe reproduced, exeepr m full.
Date- 12/24/2019 10 41 AM without the written consent of Pace An alyticaI Services, LLC Page 7 of 36
a
aceAnalytical
w+►w.peceleEl.eem
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 1{inrey Ave Suge 700
Huntarsvdfe, NG 2808
(704)875-9092
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW-10B Lab ID: 92457416D03 Collected: 12/12/19 14:20 Received: 12/13119 14:28 Matrix: Water
Parameters
Results
Units
Report Limit
OF
Prepared Analyzed
CAS Na. Quai
62009 MSV
Analytical Method:
SM 6200B
Benzene
1630
uglL
5.0
10
12/2211912:04
71-43-2
Bromobenzene
NO
ug1L
5.0
10
12/22/1912:04
108-86-1
Bromochioromethane
NO
ug)L
5.0
10
12/2211912:04
74-97-5
Bromodichloromethane
NO
ug/L
5.0
10
12/22/1912'04.
75-27-4
Bramotorm
NO
uglL
5.0
10
12/22/1912:04
75-25-2
Bromornethane
ND
ug[L
%0
10
1212211912:04
74-83-9
n-Butylbenzene
22.4
uglL
S'D
10
12/2211912:04
104-51-8
sec-Butylbenzene
ND
u91L
5.0
10
1212211912.04
135-98-8
tert-Butylbenzene
ND
ug1L
5.0
10
12/22/1912:04
98-05-6
Carbon tetrachloride
N❑
uglL
5.0
10
12/22/19 12:04
56-23-5
Chlorobenzene
NO
uglL
&0
10
12/22/1912:44
108-90-7
Chlorcethane
ND
uglL
10.0
10
12122/1912:04
75-00-3
Chloroform
NO
ug1L
5.0
10
12/2211912:04
67-66-3
Chloromethane
NO
uglL
10.0
10
12122/1912:04
74-87-3
2-Chlorotoluene
NO
uglL
5.0
10
12122/1912:04
95-49-8
4-Chlorotoluene
NO
ug1L
5.0
10
12/2211912:04
106-43-4
12-Dibrome-3-chloropropane
NO
ug1L
10.0
10
1212211912:04
96-12-8
Dibromochloromethane
NO
uglL
5.0
10
1212211912:04
124-48.1
1,2-Dibromoelhane (EDS)
NO
ug/L
5.0
14
12122/19 12'04
105-93-4
DibromomeMane
ND
uglL
5.0
10
1212211912:04
74-95-3
1,2-Dichlorobenzene
NO
uglL
5.0
10
121220912:04
95-50-1
1,3-Dichioroherizene
ND
uglL
50
10
12/22119 12:04
541-73-1
IA-Dichlorobenzene
NO
ug1L
&0
10
12/22/1912:04
106-46-7
Dichlorodinuoromethane
ND
ug1L
5.0
10
1212211912.04
75-71-8
1.1-Dichloroethane
NO
uglL
5.0
10
12122/1912:04
75-34.3
1,2-Dichloroethane
NO
ug)L
5.0
10
1212211912:04
107-06-2
1,1-Dichloroethene
ND
uglL
5.0
10
1212211912:04
75-35-4
cis-1,2-Dichlosoethene
NO
u91L
5.0
10
1212211912.04
156-59-2
trans-12-Dichloroethene
NO
uglL
5.0
10
1212211912:04
156-60-5
1,2-Dichloropropane
N❑
uglL
5.0
10
1212211912-04
78-87-5
1,3-Dichlorapropane
ND
uglL
5.0
10
12/22/19 12:04
142-28-9
2,2-❑ichloropropane
NO
uglL
5.0
10
1212211912:04
594-20-7
1,1-Dichloropropene
NO
ug1L
5.0
10
1212211912:04
553-58-6
Cis-1,3-Dichloropropene
NO
uglL
5.0
10
1212211912'04
10061-01-5
trans-1,3-Dichloropropene
ND
uglL
5.0
10
1212211912,04
10061-02.6
Diisopropyl ether
37.7
uglL
5.0
10
/2/22119 12:04
408-20-3
Ethylbenzene
240
uglL
5.0
10
1212211912:04
100-41-4
Hexachlora-1,3-butadiene
ND
ug1L
20,0
10
1212211912:04
87-68-3
Isopropylbenzene (Cumene)
36.3
uglL
5.0
10
12122119 12.04
98-82-8
Methylene Chloride
NO
ugli.
20.0
10
t2122119 12:04
75-09-2
Melhyi-tert-butyl ether
130
u91L
5,0
10
12/22/19 12:04
1634-04-4
Naphthalene
276
uglL
20,0
10
12/22/1912:04
91-20-3
n-Propylbenzene
75.0
ug1L
5.0
10
12/220912'04
103-65-1
Styrene
ND
uglL
5.0
10
1212211912:04
100-42-5
1,1,12-Tetrachtorcethane
ND
uglL
5.0
10
1212211912:04
630-20-6
1,1,2,2-TetracNor oethane
ND
uglL
5 0
10
12122J19 12:04
79-34-5
Tetrachloroethene
ND
ug1L
5 0
10
12/22/19 12:04
127-18-4
REPORT OF LABORATORY ANALYSIS
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Date. 12/24/2019 10.41 AM without the written consent of Pace Analytical Services. LLC Page 8 of 36
_ aceAnalylical
www limatlabs,cam
ANALYTICAL RESULTS
Project: Pit Stop SP
Pace Project No. 92457416
Pace Analytical Services. LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 25073
[7o4ya75-9092
Sample: MW-10B
Lab ID: 92457416003 Collected: 12/12/19 14:20
Received: 12/13/19 14:28 Matrix: Water
Parameters
Results
Units
Report Limit
DF
Prepared Analyzed
CAS Na Qual
62000 MSV
Analytical Method: SM 6200B
Toluene
20.3
uglL
5.0
10
1212211912:04
108-88-3
1,2,3-Trichlorobenzene
ND
ug/L
20.0
10
1212211912.04
87-61-6
1,2,4-Trichlorobenzene
ND
ug/L
20.0
10
12/2211912;04
120-82-1
1,1,1-Trichloroelhane
ND
ug/L
5.0
10
12)2211912:04
71-55-6
1,1,2-Trichloroethane
ND
uglL
5.0
10
12/22/19 12:04
79-00-5
Trichloroethene
NO
u91L
5.0
11)
121221191204
79-01-6
Trichloranuoromethane
ND
ug/L
10.0
10
1212211912;04
75-69-4
1,2,3-Trichioropropane
Nil
ug1L
5.0
10
12J2211912:04
96-18-4
1,2,4-Trimethylbenzene
222
ug/L
5.0
10
12/22/1912-04
95-63-6
1,3,5-Trimethylbenzene
55.8
ug/L
5.0
10
12/2211912:04
108-67-8
Vinyl chloride
N❑
uglL
10.0
10
12/22/19 12:04
75-01-4
rn&p-xylene
128
uWL
10.0
10
12/22/1912:04
179601-23-1
o-xylene
1016
ugJL
5111
10
12/2211912:04
95-47-6
Surrogates
1,2-1)ichloroethane-d4 (S)
98
%
70-130
10
12122/19 12.04
17060-07-0
4-11ramofluorobenzene (S)
97
°%
70-130
10
12/22/19 12:04
460-00-4
Toluene-d8 (5)
98
%
70-130
10
12122119 12:04
2037-26-5
Date-, 12/24/2019 10:41 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC
Page 9 of 36
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ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Klncey Ave. Suite 100
Huntersville, NG 28078
i7a4j875-9092
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW-13 Lab 1t7: 92457416004 Collected: 12/12/19 13:35 Received: 12113/19 14:28 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Quaf
62009 MSV Analytical Method: SM 6200B
Benzene
11.3
ug/L
0.50
1
'1212011917:34 71-43-2
Bromobenzene
ND
uglL
0.50
1
1212011917:34
708-86-1
Bromochloramethane
NO
ug1L
0.50
1
1212011917:34
74-97-5
Bromodichlornmelhane
ND
ug/L
0.50
1
i212011917-34
75-27-4
$romoform
ND
ug1L
0.50
1
12/2011917:34
75.25-2
Bromomethane
NO
ug/L
5.0
1
1212011917:34
7"3-9
rr-Butylbenzene
0.52
uglL
0,50
1
12/2011917:34
104-51-8
sec-Butyfbenzene
0.97
uglL
0.50
1
12/2011917:34
135-98-8
tert-Bulylbenzene
ND
ug/L
0.50
1
1212011917:34
98-06-6
Carbon tetrachloride
NO
uglL
0.50
1
12120M9 17:34
56-23-5
Chlorobenzene
ND
uglL
050
1
12/20/19 17:34
108-90-7
Ghloroethane
NO
uglL
1.0
1
12/2011917:34
75-00-3
Chloroform
NO
uglL
0.50
1
1212011917:34
67-66-3
Chloromethane
NO
uglL
1.0
1
1212011917:34
74-87-3
2-Chiarotoluene
ND
ug/L
0.50
1
12120M917'34
95-49-8
4-Chlorotoluene
NO
uglL
0.50
1
1212011917:34
106-43A
12-Dibromo-3-chloropropane
ND
ugll-
1.0
1
12/20/1917:34
96-12-8
Dibromoehioromethane
ND
ug)L
0.60
1
12/20/19 1714
124-46-1
1,2-Dibromoethane (EDS)
N❑
ug/L
0.50
1
12/21/19 17:34
106-93.4
Dibromomethane
NO
ug1L
0.50
1
12/2011917:34
74.95-3
1,2-Dichlorobenzene
ND
uglL
0.50
1
1212011917:34
95-50-1
1,3-Dichlorobenzene
NO
uglL
0.50
1
12120M917:34
541-73-1
1,4-Dichlorobenzene
ND
uglL
050
1
12/20/19 17:34
106-46-7
Dichlorodifluorornethane
ND
ug/L
0.50
1
1212011917:34
75-71-8
11-❑ichloroethane
NO
uglL
0.50
1
1212011917.34
75-34-3
12-Dichloreelhane
NO
uglL
0.50
1
12/20/1917.34
107-06-2
11-❑ichloroethene
ND
ug/L
0.50
1
12/2011917:34
75-35-4
cis- 1,2-Dlchloroethene
NO
ug1L
0.50
t
12120/1917:34
156-59-2
trans- l,2-Dichlaroe thene
NO
uglL
0.50
1
12120/1917.34
156.60-5
1,2-Dichforopropane
NO
uglL
0.50
1
12/20/1917'34
78-87-5
1,3-Dichlaroprepane
ND
ug/L
0 50
1
12/20/19 17:34
142-28-9
2,2-1)ichloropropane
ND
uglL
050
1
12120/19 17.34
594-20-7
1,1-Dichloropropene
ND
ugll-
0.50
1
12/2011917:34
563-58-6
cis-1,3-D1chloropropene
N❑
uglL
0,50
1
12120M917.34
10061-01-5
trans-1,3-Dichloropropene
ND
uglL
0-50
1
1212011917-34
10061-02-6
Diisopropyl ether
ND
ugll-
0,50
1
12/20/19 17,34
108-20-3
Ethylbenzene
0.61
u91L
0,50
1
12/2011917:34
100-41-4
Hexach[aro•1,3-butadiene
ND
uglL
2.0
1
1212011917'34
87-68-3
Isopropylbenzene (Cumene)
1.8
uglL
0.50
1
12/20/19 17:34
98-82-8
Methylene Chloride
NO
uglL
2.0
1
12/20/19 17:34
75-09.2
Methyl-tert-butyl ether
ND
uglL
050
1
12120ilg 17:34
1634-04-4
Naphthalene
ND
ugll-
2.0
1
12120/1917:34
91-2D-3
n-Propylbenzene
2.9
uglL
0,50
1
1212011917:34
103-65.1
Styrene
NO
uglL
0.50
1
121201i917:34
100-42-5
1, 1. 1, 2-Teir achloroethane
ND
uglL
0.50
1
1212011917,34
630-20-6
1,1,2,2-Tetrachlaroethane
ND
uglL
0.50
1
1212011917734
79-34-5
Tatrachloroethene
NO
ug/L
0.50
1
121201191734
127-18.4
REPORT OF LABORATORY ANALYSIS
This report shall nor be reproduced, except in full,
Date, 12/24/2019 10:41 AM without the written con sent or Pace Analytical Services, LLC
Page 10 of 36
Pace Analytical Services, LLC
6 9600 Kincey Ave. Suite 100
acaAnalylical Huntersnille, NC 28070
www.pacslabs.vem (704A75-9092
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW-13
Parameters
Lab lD: 92457416004 Collected; 12112M9 13.35
Results Units Report Limit DF
Received: 12/13JI9 14:28 Matrix: Water
Prepared Analyzed CAS No. Qual
6200B MSV
Analytical Method: SM 6200B
Toluene
0,77
uglL
0.54
1
1212011917:34
108-88-3
1,2,3-Trichic robe nzene
ND
uglL
2.0
1
1212011917,34
87-61-6
1,24-Trichiorobenzene
ND
uglL
2.0
1
12120/1917:34
120-82-1
1,1,1-Trichtorcethane
N❑
uglL
0,50
1
12/2011917:34
71-55-6
1,1,2-Trichloroothane
ND
ug1L
0.50
1
12/20/1917:34
79-00-5
Trichloroethene
N❑
uglL
0.50
1
1212011917:34
79-01-6
Tdchloroftuoromethane
ND
ug1L
1.0
1
1212fl11917:34
75-69-4
1,2,3-Trichlorapropane
ND
ug/L
0.50
1
12120/1917:34
9&18-4
1,2,4-Trimethylbenzene
ND
ug1L
0.50
1
12/2011917:34
95-63-6
1,3,5-Trimethylbenzene
ND
ug/L
0.60
1
12/2011917:34
1Oa-67-8
Vinyl chloride
N❑
ugIL
1.0
1
12/20119 17:34
75-01-4
m&p-Xyiene
1.8
uglL
1.0
1
1212011917'34
179601-23-1
o-Xylene
N❑
uglL
0.50
1
12)2011917'34
95.47-6
surrogates
1,2-01chloroethane-d4 (S)
94
%
70-130
1
12120/19 17'34
17a6O-07-0
4-13romolluorobenzene tS)
95
0/0
70-130
1
12/20/19 17:34
460-00-4
Toluene-d8 (S)
99
%
70-130
1
12/20/19 17:34
2037-26-5
Date: 1212412019 10:41 AM
REPORT OF LABORATORY ANALYSIS
This report shall nal be reproduced, except in full,
withouttlie written consent of Pace Analytical Services, L L C
Page 11 of 36
aceAnalytical"
wwrv.per:slahy.ram
�I
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave Suile 100
Hunlersville, NC 28078
(704)875-9092
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW-14 Lab ID: 92457416005 Collected: 12112/19 12:50 Received: 12/13/19 14:28 Matriw Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qua]
62006 MSV Analytical Method: SM 62006
Benzene
NO
uglL
0.50
1
1212011917:52
71-43-2
Bromobenzene
ND
uglL
0.50
1
1212011917'52
108-86.1
ftmoMoromelhane
NO
uglL
0.50
1
1212011917:52
74-97-5
eramodichioremelhane
NO
uglL
0.50
1
12120/1917:52
75-27-4
Bromoform
NO
ug1L
0.50
1
12120M917:52
75-25-2
Bromamethane
NO
uglL
5.0
1
12/2011917:52
74-83-9
n-Bulylbenzene
NO
uglL
0.50
1
12120/1917:52
104-51-8
seo_Butylbenzene
NO
ug1L
0-50
1
1212011917:52
135-98-8
tert•Butylbenzene
NO
uglL
0.50
1
1212011917'52
98.06-6
Carbon tetrachloride
NO
ug1L
0.50
1
12120M9 17:52
56-23-5
Chlorobenzene
NO
ug1L
Mo
1
12/2011917:52
108-90.7
Chloroethane
NO
ug1L
110
1
12/20119 17:52
75-OD-3
Chloroform
NO
uglL
0.50
1
12/2011917:52
67-65-3
Chloromelhane
NO
uglL
1.0
1
1212011917:52
74-87-3
2-Chiorololuene
NO
uglL
0,50
1
1212011917:52
95-49-B
4-ChlorololUene
NO
uglL
0.50
1
12/20/1917:52
106-43-4
1,2-Dibromo-3-chloroprapane
NO
ug1L
1.0
1
1212011917:52
96-12-a
Dibromochloromethane
NO
ug1L
0,50
T
1212011917.52
124-48-1
1,2-Dibromoelhane (EDB)
ND
uglL
0.50
1
12/20/19 17:52
106-93-4
Dibromomethane
NO
uglL
0.50
1
1212011917:52
74-95-3
1,2-Dichlorobenzene
NO
uglL
0.50
1
1212011917:52
95-50-1
1,3-Dichlorobenzene
NO
uglL
0.50
1
1212011917-52
541-73-1
1,4-Dichlorobenrene
ND
ug)L
0.50
1
12/201191T.52
106.46-7
DichlorodMuoromethane
N❑
uglL
0.50
1
1212011917.52
75-71-8
1,1-Dichloroethane
NO
ug1L
0.50
1
1212011917.52
75-34-3
1,2-Dichloroethane
NO
uglL
0.50
1
1212011917:52
107-06-2
1,1-Dichloroethene
NO
uglL
0.50
1
12120M917:52
75-35-4
cis-1,2-Dichloroethene
NO
ug1L
0,50
1
12120/1917:52
156-59-2
Ira ns-1,2-Dichloroethene
NO
uglL
0.50
1
1212011917:62
156-60-5
1,2-Dichloropropane
N❑
ug1L
0,50
1
12120/1917:52
78-87-5
1,3-Dichloropropane
NO
uglL
0.50
1
12/20/19 i752
142-28-9
2,2-Dichloropropane
NO
ug1L
0,50
1
12/20/19 17 52
594-20-7
1,1-Dichlaropropane
ND
ug1L
0.50
1
1212011917'52
563-5a-6
cis-1,3-Dichloropropene
ND
ug1L
0,50
1
121201191T52
10061-01-5
trans -1,3-D]chi aropropene
ND
uglL
0.50
1
12/2011917:52
10061-02-6
Diisopropyl ether
1.8
uglL
0-50
1
12/20/19 17:52
108-2D-3
Ethylbenzene
NO
uglL
050
t
12120M9 17;52
10041-4
Hex achloro-1,3-butadiene
NO
uglL
2.0
1
1212011917;52
87-68-3
Isopropy(benzene {Cumene)
NO
ug)L
0.50
1
12/20/19 17:52
98-82-8
Methylene Chloride
Nf]
uglL
2-0
1
12/20/19 17:52
75-09-2
Methyl -led -butyl ether
1.9
ug1L
0.50
1
12/20/19 17:52
1634-04-4
Naphthalene
NO
ug1L
20
1
12120119 17'52
91-20-3
n-Propyibenzene
NO
ug1L
0.50
1
121201191T52
103-65-1
Styrene
ND
uglL
0.50
1
12120/1917:52
100-42-5
1,1,1.2-Tetrachlomelhane
NO
uglL
0,50
1
12/20/19 17:52
630-20-6
1,1,2,2-Tetrachloroethane
ND
u91L
0.50
1
1212011917:52
79-34-5
Tetrachioroethene
N❑
uglL
0.50
1
1212011917:52
127-18-4
REPORT OF LABORATORY ANALYSIS
This report shall no[ he reproduced, except qn lull,
Date, 12/24/2019 10:41 AM without the written cnnsent or Pace Analytical Servines, LLC Page 12 of 36
aceAnalyticalo
www.psedrabasotn
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincey Ave, Suite 100
Huntersvilie, NG 28078
(704)875-9092
Project' Pil Stop BP
Pace Project No.: 92457416
Sample: MW-14 Lab ID: 92457416005 Collected: 12112119 12:50 Received' 12/13/19 14:28 matrix: Water
Parameters Results Units Report Limit ❑F Prepared Analyzed CAS No- oual
6200B MSV
Toluene
1,2,3-Trichlorobenzene
1,2,4-Trichiorobenzene
1,1,1-Trlchloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1, 3, 5- Tri m e thyl be nze ne
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-Dichlvroelhane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Date- 12/24/2019 10.41 AM
Analytical Method: SM 62009
ND
uglL
0.50
1
12/20/1917:52
108-88-3
N❑
ugll-
2.o
1
12120/1917,52
87-61-6
ND
ug1L
2,0
1
1212011917:52
120-82-1
ND
uglL
0,50
1
-1212011917:52
71-55-6
ND
uglL
0.50
1
1212011917:52
79-00-5
NO
uglL
0,50
1
12MI1917:52
79-01-6
ND
uglL
1.0
1
12/20/1917:52
75-69-4
NO
ug1L
D.50
'1
12/20/1917:52
96-18-4
ND
uglL
050
1
12/20119 17:52
95-63-6
ND
uglL
0,50
1
1212011917:52
108-67-8
N❑
uglL
1,0
1
1212011917,52
75-01-4
ND
uglL
1.0
1
12/20/1917:52
179601-23-1
ND
ug)L
0.50
1
12/20/1917:52
95-47-6
93
%
70-130
1
12/20/1917:52
17060-07-0
95
%
70-130
1
1212011917:52
460-00-4
98
0/0
70-130
1
1212011917'52
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report snali not be reproauced, except,n fuil,
without the written consent or Pace Analytical Services,. LLC
Page 13 of 36
m
_ aceAnalyiical
www.)teeelepa.cam
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Project No.: 92457416
Pace Analytical Services, LLC
9800 Kincey Ave Sulle 100
Huntersville, NC 28078
(104)875-9092
Sample: MW-15 Lab ID: 92457416006 Collected: 12/12/19 14:50 Received. 12113119 14'28 Matrix: Waier
Parameters Results Units Report Limit OF Prepared Analyzed CAS No.
6200B M5V Analytical Method: SM 6200B
Benzene
NO
ug1L
0.50
1
1212011918:10
71-43-2
Bromobenzene
NO
uglL
0.50
1
12/20/1918'10
108-88-1
Broma0lornmetharle
ND
ug/L
0.50
1
12120/1918,10
74-97-5
Bromedichloramethane
NO
uglL
0 50
1
12120/19 1810
75-27-4
Bromoform
NO
uglL
0.50
1
1212011918:10
75-25-2
Bromomethane
NO
u91L
5,0
1
12120/19 18: 10
74-83-9
n-Butyibenzene
ND
ug1L
0,50
1
12/201191&10
1D4-51-8
sec-Butyibenzene
ND
ug1L
0,50
1
1212011918:10
135-98-8
tert-Sutylbenzene
N❑
ug1L
0.50
1
1212011918'10
98-06-6
Carbon tetrachloride
NO
uglL
0.50
1
12/20119 18:10
56-23-5
Chlorobenzene
NO
ug1L
0.50
1
1212011918:10
108-90-7
Chloroelhane
ND
uglL
1.0
1
12120/19 1 a:10
75-00-3
Chloroform
ND
ug1L
0,50
1
1212011918-10
67-6e-3
Chloromethane
NO
ug/L
1.0
1
121201191810
74-87-3
2-Chlorotoluene
ND
uglL
0.50
1
1212011918:10
95-49-8
4-Chlorotoluene
ND
ug/L
0,50
1
12/2011918:10
106-43-4
12-Dibromo-3-rhlaropropane
NO
ug/L
1.0
1
1212011918:10
96-12-8
Dibromochtoromethane
NO
ug1L
0,50
1
1212011918:10
124-48-1
1,2-Dibromoethane {E08)
NO
ug1L
0.50
1
12/20/19 18:10
106-93-4
Dibromomethane
NO
ug/L
0.50
1
121200918:10
74-95-3
12-Dichlorobenzene
NO
uglL
0,50
1
12/20/19 18:10
95-50.1
1,3-Dichlorobenzene
NO
ug/L
0.50
1
1212011918:10
541-73-1
1,4-Dichlorobenzene
NO
ug&
0.50
1
1212011918:10
106-46-7
DichlorodlTluoromethane
NO
uglL
0.50
1
12/20/19 18:111
75-71.8
1,1-Dichloroethane
NO
uglL
0.50
1
121201191B'10
75-34-3
1,2-Dichloroethane
NO
uqA-
0 50
1
12/20/19 18:10
107-06-2
1,1-Dichloroethene
NO
uglL
0,50
1
1212011918:10
75-35A
ris-1,2-Dichioraethene
ND
uglL
0,50
1
12120M918-10
156-59-2
trans-1,2-Dichloraethene
ND
ug1L
0.50
1
12/2011918-10
156-60-5
1,2-Dichioropropane
NO
uglL
0.50
1
12/20/1918:10
78.87-5
1,3-Dichloropropane
ND
uglL
0.50
1
1212011918-10
142-28-9
2,2-Dichloropropane
ND
ug1L
050
1
12/20/19 18-10
594-20-7
1,1-Dichloropropene
ND
ug1L
0.50
1
1212011918'10
563-58-6
cis-1,3-Dichloropropene
ND
uglL
0,50
1
121201191BA0
10061-01-5
trans-1,3-Dichloroprope ne
ND
uglL
0.50
1
12120/191BA0
10061-02-5
Diisopropyl elher
8.7
uglL
0.50
1
12/20/19 18-10
108-20-3
Ethylbenzene
NO
uglL
0.50
1
12/20/1918A0
100-41-4
Hexachloro-1,3-butadlene
NO
uglL
2.0
1
12/20/1918:10
87-68-3
Isapropylbenzene (Gumene)
NO
uglL
060
1
12/20/19 18:10
98-82-8
Melhyiene Chloride
NO
uglL
2.0
1
12/20/19 18-10
75-09-2
Methyl-iert-butyl ether
2.2
ug/L
0-50
1
12120/19 18'10
1634-04-4
Naphthalene
ND
ug1L
20
1
121201191B:10
91-20-3
n-Propylbenzene
ND
ug1L
0.50
t
1212011918.10
103-65-1
Styrene
NO
ug/L
0.50
t
1212011918-10
100.42.5
1.1,1.2-Tetrachloroethane
NO
ug1L
0.50
1
1212011918 :14
630 20-6
1,1,2,2- Tetra chloroethane
ND
uglL
0.50
1
12/2011918:10
79-34-5
Teirachlorcethene
ND
uglL
0.50
1
1212011918:10
127-18-4
REPORT OF LABORATORY ANALYSIS
Qual
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Date: 12/24/2019 10:41 AM without the written consent of Pace Analytical 3ervrces, L L C Page 14 of 36
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ANALYTICAL RESULTS
Pace Analytical Services. LLC
!M0 Kin ceyAve- Suite 100
Huntersville, NC 28079
(704)a75-9092
Project: Pit Stop BP
Pare Project Na.� 92457416
Sample: MW-15 Lab ID: 92457416006 Collected: 12/12/19 14:50 Received: 12/13/19 14,28 Matrix_ Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual
62008 MSV
Toluene
1,2,3•Trichlorobenzene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethape
1,1,2-Trichioroethane
Thchloroethene
Trichlorofl u o rometh a n e
1, 2, 3-Trichlorop ropa ne
1,2,4-Trimethylbenzene
1,3,5-TrimethyIbenzene
Vinyl chloride
m&p Xylene
o-Xylene
Surrogates
1,2-Dichlo►oethane-d4 (S)
4-Bromofluarobenzene (S)
Toluene-d8 (S)
Oate 1 D2412019 10:41 AM
Analytical Nlethod: SM 6200B
ND
eglL
0.50
1
1212011918'10
108-88-3
ND
ug1L
20
1
12/20/19 1 & 10
87-61-6
NO
ug1L
2.0
1
1212011918:10
120-82-1
ND
ug1L
0.50
1
12120/191810
71-55-6
NO
uglL
0.50
1
12120/19181-10
79-00-5
ND
uglL
0.50
1
12120/1918:10
79-01-6
Nil
uglL
1.0
1
1212011918:10
75-69-4
ND
uglL
0.50
1
1212011918:10
96-18-4
ND
u911-
0.50
1
1212011918:10
95-63-6
N❑
tiglL
0.50
1
1212011918:10
10M7-8
ND
uglL
1.0
1
12/2011918:10
75-01-4
ND
ug/L
1.0
1
12/20/19 18; 10
179601-23-1
NO
ug1L
0.50
1
1212011918:10
95-47-6
91
%
70-130
1
12/20/1918:10
17060-07-0
96
1/0
70.130
1
12/2011918:10
460-00-4
101
%
70-130
1
1212011918:10
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
without the written consent of Pace Analytical Services, LLC
Page 15 of 36
aceAnalytrcal"
www.pacilat3.com
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Analytical Services, LLC
9800 Kin cey Ave. Suite 100
Huntersville, NC 28078
(704)875 9092
Pace Project No.: 924574/6
Sample: MW-16 Lab It): 92457416007 Collected: 12/12119 14,05 Received: 12/13/19 14:26 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No, Qual
6200B MSV Analytical Method: SM 6200B
Benzene
1450
uglL
5.0
}0
1212011919:21
71-43-2
Bromobenzene
NO
ug/L
50
10
12/20/19 19.21
108-86-1
Bromochloromethane
NO
ug/L
5.0
10
12/20/1919-21
74.97-5
Bromodichloro methane
NO
uglL
5.0
10
12120/1919:21
75-27-4
Bromolorm
ND
ug/L
5.0
10
12120f1919:21
75.25-2
Bromomethane
NO
ug&
50.0
10
12/2011919'21
74-83-9
n•Sutylbenzene
NO
uglL
5.0
10
12/2011919,21
104-51-8
sec-Butylbenzene
ND
uglL
5,0
10
12120M919:21
135-98-8
tert-Butylbenzene
N❑
uglL
5.0
10
12120M919:21
98-08-6
Carbon letrachloride
NO
uglL
5.0
10
12/20/19 19:21
56-23-5
Chlorobenzene
ND
uglL
5.0
10
1212t711919:21
108-90-7
Chloroethane
NO
uglL
10.0
10
12120/1919:21
75-00-3
Chloroform
NO
ug1L
5.0
ID
12120/1919:21
67-66-3
Chloromethane
N❑
uglL
10.0
10
12/2011919'21
74-87-3
2-Chlorotoluene
NO
ug1L
5.0
10
1212011919,21
95-49-8
4-Chloratoluene
NO
ug1L
5.0
10
1212011919:21
106-43-4
112-❑ibromo-3-chioropropane
ND
ug/L
10.0
10
12120/1919:21
96-12-8
Dibromochloromethane
ND
uglL
5,0
10
1212011919:21
124-48-1
1,2-Dibrvrnoethane (EOB)
NO
uglL
5.0
10
12/20/19 19:21
106-93-4
Dibfomomethane
NO
uglL
5.0
10
1212011919:21
74-95-3
1,2-Oichlorobenzene
NO
uglL
5.0
10
1212011919:21
95-50-1
1,3-Dichlorobenzene
NO
ug1L
5.0
10
1212011919:21
541-73-1
IA-Diehlorobenzene
NO
uglL
5.0
10
1212011919'21
106-46-7
❑ichlorodifluoramethane
NO
uglL
5.0
10
121201191921
75-71-8
1,1-Dichloroethane
NO
uglL
5.0
10
121201191921
75-34-3
1,2-01chiaroethane
NO
u91L
50
10
12/20/19 19.21
107-06-2
1,1•❑ichloroethene
ND
uglL
5.0
10
12/2011919:21
75-35-4
cis-1,2-Oichloroethene
NO
ug1L
5.0
10
1212011919:21
156-59-2
trans-1,2-Qichloroethene
ND
ug1L
5.0
10
12120)1919:21
156-60-5
1,2-Dichloropropane
ND
uglL
5.0
10
12J2011919:21
78.87-5
1,3-Dichlaropropane
ND
uglL
50
10
12/20/19 19 21
142-28-9
2,2-0ichloropropane
ND
uglL
5.0
10
12/2011919:21
594-20-7
1,1-Dichloropropene
ND
uglL
5.0
10
12/2011919:21
563-58-6
60,3-Dichlaropropene
NO
uglL
5.0
10
12/2011919:21
10061-01-5
trans-1.3-Dichloropropene
NO
uglL
5.0
10
12/20/19 19,21
10061-02-6
❑iisopropyl ether
27.0
uglL
50
10
12/20/19 19,21
108-20-3
Ethylbenzene
13.7
ug1L
5.0
10
1212011919:21
100-41-4
Hexachloro-1.3-butadiene
NO
ug1L
20.0
10
12/20/1919:21
87-68-3
Isopropylbenzene (Cumene)
NO
uglL
5,0
10
12/20/19 1921
98-82-8
Methylene Chloride
ND
ug&
20.0
10
12/20119 19:21
75-09-2
Methyl-lert-butyl ether
98.2
ug/L
5.0
10
12/20119 19:21
1634-04-4
Naphthalene
49.0
uglL
20.0
10
1212011919.21
91-20-3
n•Propylbenzene
5.9
uglL
5.0
10
12120119 19 �21
103-65-1
Styrene
NO
ug1L
5.0
10
1212011919:21
100-42-5
1, 1, 1, 2 -Tetra ch loroethane
ND
ug1L
5.0
10
1212011919:21
630-20-6
1,1,2,2- Tetra chloroethane
N❑
ug/L
5.0
W
1212011919'21
79-34-5
Tetrachloroethene
ND
uglL
5.0
10
1212011919:21
127-1B-4
REPORT OF LABORATORY ANALYSIS
This report sheli not be reproduced, except in full,
Dale? 12/24/2019 10:41 AM without the wriuen consent of Pace Analytical Services, LLC Page 16 of 36
aceAnaljdcal
*rww.pved�6a.wrp
ANALYTICAL RESULTS
Pace Analytical Services, LLC
9800 Kincay Ave. Suite 100
Huntersville, NC 28078
(704)87s-9092
Project: Pit Stop BP
Pace Project No.; 92457416
Sample: MW-16 Lab ID, 92457416007 Collected, 12/12/19 14,05 Received: 12113/19 14:28 Matrix; Water
Parameters Results Units Report Urnit DF Prepared Analyzed CAS No, Qual
6200E MSV
Toluene
1,2,3-Trichlarobenzene
1,2,4-Trichlorobenzene
1, 1, 1 -Trichloroeth ane
1, 1. 2-Trichloroethane
Trichloroethene
Trichl orofiuorometh a n e
1,2,3-TrichlDropropane
1,2 A -Trim athylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
rn&p-Xylene
o-Xylene
Surrogates
1,2-Dichloroethane-d4_(S)
4-Bromoliuorobenzene (S)
Toluene-d8 (S)
Date: 12/24/2019 10:41 AM
Analytica! Method: SM 6200B
12.8
ug/L
5,0
10
1212011919:21
108-88-3
ND
ug/L
20.0
10
12/20/19 19 21
87-61-6
ND
ug/L
20,0
10
12120A91921
120-82-1
ND
ug/L
5.0
10
1212011919:21
71-55-6
ND
ug/L
5.0
10
12/201191921
79-00-5
ND
ug/L
5.0
10
12/20/1919:21
79-01-6
N❑
ug/L
10.0
10
12/2411919.21
75-69-4
ND
ug/L
5.0
10
12/20/1919:21
96-18-4
ND
uglL
5.0
10
12/2011919:21
95-63-6
ND
ug1L
&0
10
1212011919:21
10"7-8
ND
ug)L
10.0
10
12/2011919.21
75-0-4
N❑
ug/L
10.0
10
12/2011919:21
179601-23.1
ND
ug/L
&0
10
1212D11919:21
95-47-6
95
%
70-130
10
1212011919'21
17060-07-0
96
°%
70-130
10
1212011919*21
460-00-4
100
%
70-130
10
1212011919'21
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not ❑e reproduced, excepi in full.
without the written consent or Pace Analytical Services, L L C
Page 17 of 36
aceAnalyical
www,pacolabn.com
ANALYTICAL RESULTS
Pace Analytical Services, LLC
HOD KinceyAve. Suite 100
Nuntersville, NC 28078
(704)575-9092
Project: Pit Stop BP
Pace Project No.: 92457416
Sample: MW-17 Lair ID; 92457416008 Collected: 12112/19 13.20 Received: 12113/19 14:28 Matrix: Water
Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qua]
6200B MSV Analytical Method: SM 6200B
Benzene
0.80
ug)L
0,50
1
1212011919:03
71-43-2
Bromobenzene
NO
ug&
0.50
1
12120119 19! 03
108-86-1
Bromochloromethane
NO
uglL
0.50
1
1212011919:03
74-97,5
13romodichloromethane
ND
ug)L
0.50
1
1212011919:03
75-27-4
Bromoform
ND
ug1L
0.50
1
1212011919:03
75-25-2
Bromomethane
ND
uglL
5.0
1
12/2011919:03
74-83-9
n-Butytbenzene
ND
uglL
0.50
1
12/2011919:03
104-51-8
seo_Butylbenzene
0.54
uglL
0.50
1
12120/1919:03
135-98-8
tort-Butylbenzene
NO
uglL
0.50
1
12/2011919:03
98-06•6
Carbon tetrachloride
NO
uglL
0.50
i
12/20/19 19:03
56-23-5
Chiorobenzene
NO
uglL
0.50
1
12/20/19 19:03
108-90-7
Chloroethane
NO
ug1L
1.0
1
12/2011919:03
75-00-3
Chloroform
NO
uglL
0.50
1
1212011919:03
67-66-3
Chloromethane
NQ
uglL
1.0
1
12120MO %03
74-87-3
2-Chlorotoluene
ND
ugll-
0.50
1
12/20/1919:03
95-49.8
4-Chiorotoluene
ND
ug1L
U0
1
12120M919:03
106-43-4
1,2-Di1bramo-3-chloropropane
NO
uglL
1,0
1
12120/1919:03
96-12-8
Dibromochloromethane
✓+SD
uglL
0.50
1
1212011919:03
124-48-1
1,2-Dibromoethane [EDB)
NO
ug1L
0,50
1
12/20/19 19:03
106-93-4
Dlbromomelhane
NO
uglL
0.50
1
1212011919:03
74-95-3
1,2-Dichiorobenzene
ND
ug1L
0,50
1
12120/1919:03
96-50-1
1,3-Dlchlorobenzene
NO
ug1L
0,50
1
12/20/1919:03
541-73-1
1,4-Dlchlcrobenzene
ND
uglL
0.50
1
12120/1919:03
1 u6-46-7
Dichlorodl5uoromethane
NO
uglL
0.50
1
12/2011919:03
75-71.8
1,1-Oichloroethane
NO
uglL
0.50
1
12/2011919A3
75-34.3
1,2-Dichlornethane
N❑
ugll-
0,50
1
1212011919-03
107.06-2
1,1-Dichlaroethene
ND
ug1L
0.50
1
12120119 19: 03
75-35-4
cis-1,2-Dichtoroethene
ND
uglL
0.50
1
1212011919.03
156-59-2
trans-1,2-Dichloroethene
NO
uglL
0.50
1
12/2011919:03
156-60-5
1,2-Dichloropropane
NO
u91L
0.50
1
12120/1919:03
78-87-5
1,3-Dichloropropane
ND
uglL
0,50
1
12/20/1919,03
142-28-9
2,2-Dichloropropane
NO
uglL
0.50
1
12/20/1919:03
594-20-7
1,11-0(chloropropane
NO
uglL
0.50
1
1212011919A3
563-58-6
cis-1,3-Dichlaropropene
NO
uglL
0.50
1
1212011919:03
10061.01-5
trans-1,3-Dichloropropene
N❑
ug)L
GM
1
1212011919:03
10061-02-6
❑iisopropyl ether
49.4
uglL
0.50
1
12/20/19 19,03
108-20-3
Ethylbenzene
NO
uglL
0.50
t
1212DI1919.03
100-41-4
Nexachloro-1,3-butadiene
NO
uglL
2.0
1
1212011919-03
87-68-3
isopropylbenzene (Cumene)
NO
ug1L
0.50
1
12/20119 19,03
98-82-8
Methylene Chloride
NO
ug1L
2.0
1
12/20/19 19,03
75-09-2
Methyl-tert-butyl ether
6.5
ug1L
0,50
1
12/20/19 19:03
1634-04-4
Naphthalene
NO
uglL
2-0
1
12/20/19 19-03
91.20-3
n-Propylbenzene
NO
uglL
0.50
1
1212011919:03
103-65-1
Styrene
NO
uglL
0.50
1
12/20/1919:03
100-42-5
1.1,1,2-Tetrachicmethane
NO
uglL
0.50
1
1212011919:03
630-20-6
1,1,2,2-Tetrachtoroe thane
NO
uglL
0.50
1
1212011919:03
79-34-5
TetracMareethene
NO
uglL
0.50
1
1212D1919:03
127-18-4
REPORT OF LABORATORY ANALYSIS
M1
M1
This report shall not be reproduced, except in full,
bate: 12/24/2019 10.41 AM without the written consent of Pace Analytical 5ermes, LLC Page 18 of 36
aceAnalytical
www.Paeelaha.c m
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Project No.. 92457416
Pace Analytical Services, LLC
9800 Kincey Ave. SWe 100
Huntersville, NC 28078
(704)876-9092
Sample: MW 17 LatiIt7: 92457416008 Collected: 12/12/19 13:20 Received. 12/13/19 14:28 Matrix: Water
Parameters Results Units Report Umlt ❑F Prepared Analyzed CAS No, Qual
6200B MSV
Toluene
12,3-Tric4lorobenezene
12A-Trlchlorobenzene
1,1,1-Thchtoroethano
1, 1,2-T6chloroetha ne
Trichioroethene
Trichiarofluorom etha ne
1,2,3-Trichloropropane
1,2,4-Trimethylbenzene
1,3,5-Trimethylbenzene
Vinyl chloride
m&p-Xylene
o-Xylene
Surrogates
1,2-D!chi oroethane-d4 (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
Rate: 12/24/2019 10:41 AM
Analytical Method: 5M 6200B
N ❑
ug1L
NO
ug1L
NO
uglL
NO
ug1L
NO
ug1L
ND
ug/L
NO
ug1L
NO
ug)L
NO
ug1L
NO
uglL
NO
uglL
NO
ug1L
ND
uglL
95 °%
97 %
96 "%
0.50
1
12/20/19 19:03
108.88-3
2.0
1
12/2011919:03
87-61-6
2.a
1
12/20/1919'03
120.82-1
0,50
1
1212011919:03
71-55-6
0,50
1
1212011919:03
79-00-5
0.50
1
12120/1919:03
79-01-6
1.0
1
12/20/19 1 9:03
75-69-4
0.50
1
1212011919:03
96-18-4
0.50
t
1212011919.03
95-63-6
0,50
1
12/20/19 19:03
108-67-8
1'0
1
1212011919=03
75-01-4
1.0
1
12/20/19 19:03
179601-23-1
0.50
1
1212011919:03
95-47-6
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in foil.
without tha written consent of Pace Analytical Services, LLC.
12120M 9 19:03 17060-07-0
12120M919:03 460-00-4
12120/1919703 2037-26-5
Page 19 of 36
aceAnalytical
www.pacilabi.com
ANALYTICAL RESULTS
Project: Pit Stop BP
Pace Project No.: 92457416
Pace Analytical Smlaes, LLC
9800 Kin ceyAve. Sups 100
Huntersville. NC 28078
(104)975.9092
Sample: TRIP BLANK Lab 1D: 92457416009 Collected: 12/12/19 00:00 Received: 1211311914.28 Matrix: Water
Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qua)
6200E VISV Analytical Method: SM 5200B
Benzene
NO
uglL
0.50
1
12/2011915:29
71-43-2
Bromobenzene
NO
uglL
0.50
1
1212011915:29
10"6.1
Brorrochloromethane
NO
ug1L
0.50
1
1212011915:29
74-97-5
Bromodichloromethane
NO
uglL
0,50
1
1212011915:29
75-27-4
Bromotorm
NO
uglL
0,50
1
12/2011915:29
75-25-2
Bromometbane
NO
u911-
5.0
1
1212011915:29
74-B3-9
n-Butylbenzene
NO
ug1L
0150
1
1212011915:29
104-51-8
sec-Butylbenzene
NO
uglL
0.50
1
1212011915:29
135-98-8
tert-Butylbenzene
NO
uglL
0.50
1
12/2011915-29
98-06.6
Carbon tetrachloride
NO
uglL
0,50
1
12/20/19 15:29
56.20.5
Chlorobenzene
NO
uglL
0.50
11
1212011915:29
108-90-7
Chloroethane
NO
uglL
1,0
1
12/20/1915:29
75-00-3
Chforotorfn .
NO
uglL
0.50
1
12/20119 15.29
67-66-3
Chloromethane
NO
uglL
1.0
1
12120/1915:29
74-87-3
2-Chlorotoluene
NO
uglL
0.50
1
12/2011915:29
95-49-8
4-Chlorotoluene
NO
uglL
0.50
1
12/2011915.29
106-43-4
1,2-Dibromo-3-chloropropane
NO
uglL
1.0
1
1212011915:29
96-12-8
Dibromochloromethane
ND
uglL
0.50
1
1212011915:29
124-48-1
1,2-Dlbromoethane (FOB)
NO
uglL
0,50
1
12/20/19 15:29
106-93-4
❑ibromamethane
NO
ug/L
0.50
1
12/7011915:29
74-95-3
1,2-Dichloroberizene
NO
uglL
0.50
1
1212011915.29
95.50-1
15-❑ichlarobenzene
NO
uglL
0.50
1
1212011915,29
541-73-1
14-Dichlarobenzene
ND
ug1L
0.50
1
12/2011915:29
106-46-7
Dichlorodifluoromethane
ND
uglL
0.50
1
1212DM915-29
75-71-8
1,1-Dichloroethane
NO
uglL
0,50
1
12/20/1915.29
75-34-3
1,2-Dichloroethane
NO
uglL
0.50
1
12120/1915:29
107-06-2
1,1-Dichloroethene
ND
uglL
0.50
1
12120/1915:29
75-35.4
cis-1,2-Dichlaroethene
NO
uglL
0.50
1
1212011915:29
156-59-2
trans-1 ,2-Dichioroethene
NO
uglL
0.50
1
12/20119 15:29
165-60-5
1,2-Dichloropropane
ND
uglL
0.50
1
1212011915:29
78.87-5
1,3-0ichloropropane
ND
uglL
0,50
1
1212011915-29
142-28.9
2,2-Dichloropropane
NO
uglL
0.50
1
12/20/1915:29
594-20-7
1,1-Dichloropropene
NO
uglL
0,50
1
12/20/1915:29
563-58-6
cis -1,3-0ichIaropropene
ND
uglL
0.50
1
12120/1915:29
10061-01.5
tran s-1.3-Dichlotopropene
N❑
uglL
0-50
1
1212011915,29
10061-02-6
❑iisopropyl ether
NO
uglL
0 50
1
12/20/19 15.29
108-20-3
Ethylbenzene
NO
ug1L
0.50
1
1212011915:29
1OD-41-4
Hexachloro-1,3-butadiene
ND
uglL
2,0
1
12/2011915.29
87-68-3
Isopropylbenzene (Cumene)
NO
uglL
0,50
1
12/20/19 15.29
98-82-8
Methylene Chloride
NO
ug11-
2.0
1
12120/19 15,29
75-09-2
Methyl -ten -butyl ether
NO
uglL
❑.50
1
1212009 15:29
1634-04-4
Naphthalene
ND
uglL
2 0
1
12/20/19 15.29
91-20.3
n-P(opylbenzene
NO
uglL
0 50
1
12/20/19 15:29
103-65-1
Styrene
NO
uglL
0.50
1
12/20119 1 5:29
100-42-5
1,1,1.2-TetrachIoroethane
ND
uglL
0 50
1
1212009 15:29
630-20-6
1,1,2,2-TelrachloroeIhane
ND
uglL
0.50
1
12/2011915,29
79-34-5
Tetrachloraelhene
ND
uglL
0.50
1
1212011915:29
127-18-4
REPORT OF LABORATORY ANALYSIS
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Date: 12/24/2019 10741 AM without the written consent of Pace Analyticai Services. LLC Page 20 at 36
aceftylical
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ANALYTICAL RESULTS
Project: Pit Slop BP
Pace Project No.: 92457416
Pace Analytical Services, LLC
960d kinceyAve. Suite 100
Huntersville, NC 28078
(704)875-9092
Sample: TRIP BLANK Lab Ito: 92457416009 Collected: 12112119 00.00 Received: 12/13/19 14:28 Matrix: Water
Parameters Results Emits Report Limit OF Prepared Analyzed CAS No. Qual
62006 MSV
Toluene
12,3-Trichlorobenzene
1, 2,4- Tric hlar obenzene
1,1,1 •Trichloroethane
1, 1, 2-Trichloroethane
Trichloroethene
Trichlorofl uoromethane
1,2,3-Trichloropropa ne
1, 2,4-Tdmelhylb enzene
1,3,5-Trimethyibenzene
Vinyl chloride
m&p-Xylene
o-Xyiene
Surrogates
1,2-Dlchioroethane-d4 (S)
4-13romofluorobenzene (S)
Toluene-d8 (S)
Dale: 12/24/2019 10:41 AM
Analytical Method: SIN 6200E
NO
ug/L
NO
ug/L
NO
ug/L
NO
ug/L
ND
uglL
NO
ug/L
NO
uglL
ND
uglL
ND
ug/L
NO
uglL
NO
ug/L
ND
ug/L
NO
ug/L
94 %
95 %
101 %
0.50
1
12/20/19 15:29
108.88-3
20
1
1212011915-29
87-61.6
2.0
1
12/20119 15!29
120.82-1
0.50
1
1212011915:29
71-55-6
0.50
1
1212011915:29
79-00-5
0.50
1
12120/19 15:29
79-01-6
1.0
1
1212011915:29
75-69-4
0,50
1
1212011915:29
96-18-4
0.50
1
12/2011915:29
95-63-6
0,50
1
12/20/19 15:29
108-67-8
1.0
1
12120119 15:29
75-01-4
1.0
1
12/20/19 15:29
179601-23-1
0,50
1
12/20/1915:29
9547-6
70-130 1
70-130 1
70-130 1
REPORT OF LABORATORY ANALYSIS
This rmpan shall not be reproduced, except in Full,
wilhout the written consent of Pace Analytical Services, LLC
-i 2120119 15-29 17060-07-0
12120119151-29 460-00-4
12/2011915:29 2037-26-5
Page 21 of 36
ay
aceAnal0cal
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[QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No.. 92457416
Pace Analytical Services, LLG
9800 KinceyAve. Sidle 100
Huntersville, NC 2B07b
(704)875.9092
QC Batch: 516087 Analysis Method: SM 62008
QC Batch Method: SM 62009 Analysis Descriptiom 6200B MSV
Associated Lad Samples: 92457416001, 92457416002, 92457416004, 92457416005, 92457416006, 92457416007, 92457416008,
92457416009
METHOD BLANK: 2765261 Matrix: Water
Associated Lab Samples: 92457416001, 92457416002. 92457416004, 92457416005, 92457416006, 92457416007, 92457416003.
92457416009
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
1, 1, 1, 2-Tetrachloroeth ane
ug1L
NO
0.50
12/20/19 15:11
1, 1, 1 -Trichl oroethan a
uglL
ND
0.50
1212011915:11
1,1,2,2-Tetrachlaroethane
ug1L
ND
0.50
1212011915:11
1.1,2-Trichtoroethane
ug1L
NO
0.50
12/2011915,11
1,1-DichIornethane
uglL
ND
0.50
1212011915:11
11-Dichlaroethene
uglL
NO
0.50
12120M915:11
1,1-Dichloropropene
uglL
ND
0.50
121210915:11
1,2,3-Trichiorobenzene
ug1L
ND
2,0
12120/1915:11
1,2,3-Trichloropropane
uglL
ND
0.50
12120/1915:11
1,2,4-Trichlorobenzene
uglL
NO
2.0
12120/1915:11
1,2,4-Trimethylbenzene
ug1L
ND
0.50
1212011915:11
1,2-Dibromo-3-chloropropane
uglL
NO
1.0
12J2011915:11
1,2-Dibromoethane (EDB)
uglL
NO
0,50
12/20/19 15:11
1,2-Dichlorobenzene
ug1L
NO
0.50
12/20/19 15.11
12-Dichloroethane
uglL
NO
(1.50
12/20/19 15:11
1,2-Dichloropropane
uglL
NO
0,50
121201191511
1.3,5-Trimethylbenzene
uglL
NO
0,50
1212011915:11
1,3-Dichlorobenzene
uglL
NO
0.50
1212011915:11
1,3-Dichloropropane
uglL
ND
0.50
1212011915:11
1,4-Dichlorobenzene
ug)L
NO
0.50
1212011915:11
2,2-Dichloropropane
uglL
ND
0.50
1212011915:11
2-Chlorotoluene
uglL
ND
0,50
12/20/1915:11
4-Chlorotoiuene
uglL
NO
0,50
12/2011915:11
Benzene
uglL
N❑
0.50
1212011915:11
Bromobenzene
ug1L
ND
0.50
12/20/1915,11
Bromachloromethane
ug&
NO
050
12/20/19 15 11
Bromodichloromethane
uglL
NO
0,50
1212011915.11
Bramniorm
uglL
NO
0.50
12/2011915:11
Bromomethane
uglL
NO
5.0
12120/1915:11
Carbon tetrachloride
uglL
ND
0,50
12/20/19 15:11
CWorobenzene
uglL
NO
0.50
1212011915.11
Chloroethane
ug1L
NO
1.0
12/20/19 15.11
Chloroform
ug1L
NO
0 50
12/20/19 15:11
Chiaromethane
uglL
ND
1.0
12W2011915:11
cis-1,2-Dichloroethene
ug)L
ND
0,50
1212011915'11
cis-1,3-Dichlorepropen e
uglL
ND
0,50
12/20/19 15A 1
D ibromochl o rom ethane
uglL
N❑
0.50
1212011915711
Dibromomethane
uglL
ND
0.50
12120119 15: 11
Dichlorodifluoromethane
uglL
NO
050
1212011915'11
❑iisopropyl ether
ug1L
ND
0.50
12120/19 15:11
Rosuhs presented on this page are in the unils indicated by the "trnI10 column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 12/24/2019 10:41 AM without the written eonsenI of Pace Analytical Services, LLC Page 22 of 36
_ . aceAnal yical
www.pacelrbs.cora
QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Projecl No.: 92457416
Pace Analytical Services, LLC
9800 Kin coy Ave Suite 1no
Huntersville, NC 28078
(704)875-9092
METHOD BLANK: 2765261 Matrix. Water
Associated Lab Samples: 92457416001, 92457416002, 92457416004, 92457416005, 92457416006, 92457416007, 92457416008,
92457416009
Blank
Reporting
Parameter
Units
Result
Limit
Analyzed Qualifiers
Ethylbenzene
ug1L
ND
0.5U
1212011915:11
Hexachloro-1,3-butadiene
uglL
ND
2.0
12120/1915:11
lsopropylbenzene (Cumene)
ug/L.
ND
0.50
12120/19 15:11
m&p-Xylene
ug/L
ND
1.0
12/20119 15.11
Methyl-tert-butyl ether
uglL
NO
0.60
12/20/19 15:11
Methylene Chloride
ug/L
NO
2.0
12/20/19 15:11
n-Butylbenzene
4L
NO
0.50
1212011915:11
n-Propylbenzene
uglL
N❑
0.50
121201191511
Naphthalene
ug1L
ND
2.0
12/20/1915:11
o-Xylene
uglL
NO
0,50
1212011915:11
sec-Butylbenzene
ug1L
NO
0.50
12/20/1915:11
Styrene
ug/L
ND
0,50
12/2011915:11
tert-Butylbenzene
ug1L
N❑
050
12/20/19 15:11
Tetrachioroethene
ug/L
ND
0 50
12/20/19 15:11
Toluene
ug1L
ND
0,50
1212011915:11
trans- 1,2-Dichloroethene
ug1L
ND
050
12/20/19 15:11
trans-1,3-Dlchloropropene
ug/L
ND
0,50
1212011915:11
Trichloroethene
uglL
ND
0.50
12120/1915.11
Trichlorofluoromethane
ug1L
NO
1.0
1212W1915:11
Vinyl chloride
ug1L
ND
1.0
12/20119 15:11
1,2-Dichloroethane-d4 (S)
°%
93
70-130
12/20/19 15.11
4-Bromofluorobenzene (S)
%
97
70-130
12/20/19 15:11
Toluene-d8 (S)
%
101
70-130
12/20/19 15:11
LABORATORY CONTROL SAMPLE' 2765262
Parameter
Spike LCS LCS
Units Conc. Result A Rec
% Rec
Limits Qualifiers
1.1.1,2-Tetrachloroethane
ug1L
50
52.3
105
60-140
1.1.1-Trichloroethane
ug1L
50
50.6
1D1
60-140
1,1,2,2-Tetrachloroethane
uglL
50
50.2
100
60-140
1,1,2-Trichloroethane
ug1L
50
50.8
102
60-140
1,1-Dichloroethane
uglL
50
49.4
99
50-140
1,1-Dichloroethene
uglL
50
47.9
96
BO-140
1,1-Dichloropropene
uglL
50
53.7
107
60-140
1,2,3-Trichlorobenzene
ug/L
50
56.6
113
60-14D
1,2,3-Trichloropropane
uglL
50
49.6
99
60-140
1,2A-Trichlorohenzene
ug/L
50
55.6
111
60-140
1,2,4-Trimethylbenzene
ug/L
50
52.5
105
6D-140
1,2-Dibromo-3-chtoropropane
ug)L
50
54.4
109
60-140
1,2-Dibromoethane (EDB)
ug/L
50
53.2
106
6D-140
1,2-Dichlorobenzene
ug1L
50
54.2
108
60-140
1,2-Dichloraethane
uglL
So
45.4
91
60-140
1,2-❑ichloropropane
uglL
50
51.5
103
60-140
Resuils presented on this page are In the units Indicated by the "Units" col until except where an alternate unit is presen led to the right of the re skill,
REPORT OF LABORATORY ANALYSIS
This report shall not he reproduced. except in full,
Date: 12/2412019 10:41 AM without the written consent a Pace Analytical Services, LLC Page 23 of 36
aceAnalXical
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QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No.. 92457416
LABORATORY CONTROL SAMPLE:
Parameter
2765262
Units
Spike
Conc.
LCS
Result
LCS
°% Rec
% Rec
Limits
1,3,5-Trimethylbenzene
ug&
50
52.4
105
60-140
1,3-Dichlorobenzene
uglL
50
52.9
106
60-140
1,3•Dichloropropane
ug1L
50
53,1
106
60-140
1,4•Dichlorobenzene
uglL
50
53.6
107
60-140
2,2-Dichloropropane
uglL
50
58.0
116
60.140
2-Chlorotoluene
uglL
50
51.3
103
60-140
4-Chlorotoluene
uglL
50
53.1
106
50-140
Benzene
uglL
50
51.7
103
60-140
Bromobenzene
ug&
50
54.0
108
60-140
Sromochlorornethane
ug1L
50
50.1
100
60-140
Bromodichloramethane
uglL
50
51.2
102
60-140
Bromoform
uglL
50
54.2
108
60-140
Bromomethane
uglL
50
52.5
105
60-140
Carbon tetrachloride
uglL
50
52.8
106
60-140
Chlerobenzene
ug1L
50
51 A
103
60-140
Chlorcethane
uglL
50
53,3
107
60-140
Chloroform
ugIL
50
48.6
97
60.140
Chloromethane
uglL
50
40,5
81
60-140
cis-1,2-Dichloraethene
uglL
50
48.3
97
60.140
cis-1,3-Dichlorepropene
uglL
50
52,9
105
W-140
Dibromochloromethane
uglL
50
55,2
110
60-140
Dibromamethane
uglt-
50
51.7
103
60-140
❑Ichloradllluoromethane
uglL
50
46.4
93
60-140
Dlisopropyl ether
uglL
50
48.2
99
60-140
Ethylbenzene
uglL
50
51.2
102
60-140
Flexachloro-1,3-butadiene
uglL
50
53.2
106
60-140
Isopropylbenzene (Cumene)
u911-
50
52.2
104
60-140
m&p-Xylene
uglL
100
104
104
60-140
Methyl-tert-butyl ether
uglL
50
52.6
105
60-140
Methylene Chloride
uglL
50
45.2
90
60-140
n-Butylbenzene
uglL
50
53.5
107
60-140
n-Propyibenzene
uglL
50
50.7
101
M140
Naphthalene
U91L
50
56.6
113
60.140
o-Xylene
uglL
50
51.9
104
60.140
sec-Butylbenzene
uglL
50
51.9
104
60-140
Styrene
uglL
50
54.6
109
60-140
teri-Butylbenzene
uglL
50
44.5
89
60.140
Tetrachloroethene
uglL
50
51.5
103
60-140
Toluene
uglL
50
49.5
99
60-140
trans-1,2-Dichloreethene
u911-
50
49.2
98
60-140
trans -1,3-Dichloropropene
uglL
50
52.4
105
60-140
Trichloroethene
uglL
50
51.7
103
60-140
Trichlorofluoromettlane
uglL
50
46.8
94
60-140
Vinyl chloride
ugli-
50
50.1
100
60-140
1,2-Dichloroethane-d4 (S)
%
94
70-130
4-Bromofluorobenzene (5)
°%
98
70-130
Toluene-d8 (S)
%
98
70-130
Pace Analytical Services, LLC
s800 Kinsey Ave. Suite 100
Hu rite rsville, NC 28078
t7fl4j875-9092
Qualifiers
Results presented on this page are in the units indicated py the "Units" Lolumn except where an alternate unit Is presented to the nght of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in cull,
Date: 12124/201910.-41 AM without We written consent or Pace Analytical Services, LLC Page 24 of 36
aceAnalyticai
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DUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No.: 92457416
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2765263 2765264
Pace Analytical Services, LLC
9000 Kincey Ave Suite 100
Huntersvilte, NC 29078
t704j675-9092
MS MSO
92457416008 Spike Spike MS MSD NIS MSD % Rec
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual
1, 1. 1, 2-Tetrachloroethane
uglL
NO
20
20
23.4
23.9
117
120
60-140
1,1,1-Trichloroethane
uglL
ND
20
20
21.8
23.0
109
115
60-140
1,1,2,2-Tetra chi oroethane
uglt.
ND
20
20
2Z3
22.3
112
112
60-140
1,1,2-Trichloroethane
uglL
NO
20
20
22.1
23A
110
115
60-140
1,1-Dichloroethane
ug/L
NO
20
20
21.5
21.6
108
108
60-140
1,1-Dichioroethene
ug1
N❑
20
20
21.5
21.3
108
106
60-140
II J-Dichloropropene
uglL
ND
20
20
22.8
22.5
114
112
60-140
1,2,3-Trichlorobenzene
uglL
ND
20
20
25.3
23.9
127
120
60-140
1,2,3-Trichloropropane
uglL
ND
20
20
22.2
22.1
ill
111
60-140
1,2,4-Trichlorobenzene
uglL
N❑
20
20
23.5
24.0
118
120
60-140
1,2,4-Trimethylbenzene
ug1L
ND
20
20
23.1
23.3
115
117
60-140
1,2-Dibromo-3-chloropropane
uglL
ND
20
20
22.9
23.3
115
116
60-140
12-Dibromoethane (EDB)
uglL
ND
20
20
233
23.2
116
116
60-140
1,2-Dichiorobenzene
uglL
NO
20
20
22.9
23.4
115
117
60-140
1,2-Dichioroethane
uglL
ND
20
20
19A
19.9
97
100
60-140
1,2-Dichloropropane
uglL
NO
20
20
22.5
23.5
113
1i8
M140
1,3,5-Trimethylbenzene
uglL
ND
20
20
22.6
23.0
113
115
60-140
1,3-Dichlorobenzene
ugIL
NO
20
20
22.4
22.8
112
114
60-140
1,3-Dichloropropane
uglL
ND
20
20
22.9
23.3
114
117
60-140
1,4-Dichlorobenzene
Ug1L
NO
20
20
22.9
233
115
117
60-140
2,2-❑ichloropropane
ug1L
N❑
20
20
225
23.3
113
116
60-140
2-Chlorotaluene
uglL
NO
20
20
22-2
22.5
ill
113
60-140
4-Chlorotoluene
ug1L
NO
20
20
221
22.9
ill
115
60-140
Benzene
ug1L
0.80
20
20
23.3
24.5
113
118
60-140
Bromobenzene
uglL
ND
20
20
23.7
23.5
119
117
60-140
Bromochioramethane
u91L
NO
20
20
221
22.1
111
110
60-140
Bromodichloromethane
uglL
ND
20
20
23.1
236
115
118
60-140
Bromoform
uglL
NO
20
20
22.9
23.3
114
116
60-140
Bromameihane
uglL
NO
20
20
23.3
23.5
117
118
60-140
Carbon tetrachloride
q1
NO
20
20
23.2
241
116
121
60-140
Chlorobenzene
uglL
NO
20
20
23.3
23.2
117
116
60-140
Chloroethane
uglL
NO
20
20
28.6
28.4
143
142
60-140
Chloroform
uglL
NO
20
20
22.2
222
111
111
60-140
Chloromethane
ug1L
NO
20
20
13.0
14A
65
71
60.140
cis-1,2-Dichloroethene
uglL
ND
20
20
21.3
21.5
107
108
60-140
cts-1,3-Dichloropropene
uglL
ND
20
20
22.4
23.3
112
117
60.140
Dibromachioromethene
uglL
ND
20
20
23.8
23.9
119
119
60-140
Dibromomelhane
ug1L
ND
20
20
22.3
23.7
ill
118
60-140
Dichlorodifluoromethane
ug)L
ND
20
20
18.2
17Z
91
88
60-140
Diisopfopyl ether
ug/L
49.4
20
20
73.2
72.8
119
117
60-140
Ethylbenxene
uglL
NO
20
20
22.8
22.9
114
115
60-140
Hexachloro-1,3•butadiene
uglL
N0
20
20
22.3
22.2
112
111
60-140
lsopropylbenzene {Cumene}
uglL
NO
20
20
234
23.6
117
118
80.140
m&p-Xylene
uglL
NO
40
40
45.7
46.6
114
116
60-140
Methyl-tert-butyl ether
uglL
6.5
20
20
29.1
29.3
113
114
60-140
Methylene Chloride
uglL
NO
20
20
207
205
104
103
60-140
Results presentrd on this page are in
the units Indicaled by the "UnIts"
column excaptwhare an attemate unit is presented to therlght of She result.
REPORT OF LABORATORY ANALYSIS
4
0
1
1
s
0
2
1
1
0
2
3
4
2
2
2
2
3
1
4
5
}
a
2
2
1
4
0
1 M1
0
8
1
This report shall not be reproduced, except in Full.
Date: 12/24/2019 10A l AM without the wri lien consent or Pace Ana Iysical Services, LLC Page 26 of 36
_ IeAnapical r
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QUALITY CONTROL DATA
Pace Analytical Services, LLC
9B0G Kincay Ave Suite l00
Huntersville. NC 2807a
(794)876-9092
Project Pit Stop BP
Pace Projecl No.- 92457416
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2765263
2765264
MS
MSD
92457416GO8
Spike
Spike
MS
MSD
MS
MSO
% Rec
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD Quat
n-Butylbenzene
ug/L
ND
20
20
22.0
22.3
110
111
613-140
1
n-Propylbenzene
ug1L
ND
20
20
22.0
22.6
110
113
611-140
3
Naphthalene
ug1L
NO
20
20
29.5
24.9
148
125
W140
17 M1
o-Xylene
ug&
NO
20
20
22.7
23.2
114
116
60-140
2
sec -Butyl benzene
ugfL
0.54
20
20
23.3
23,3
114
114
60-140
0
Styrene
ug1L
N❑
20
20
23.5
23.8
117
119
60-140
1
teft-Butylbenzene
ug1L
ND
20
20
20.1
20.6
101
103
60-140
2
Tetra ch loroethene
ug1L
ND
20
20
21.9
22.5
110
113
60-140
3
Toluene
ug1L
ND
20
20
21.9
23.0
109
115
60-140
5
trans- 1,2-Dichloreethene
ug1L
NO
20
20
21.4
21.5
107
108
60-140
1
trans- 1,3-0ichloropropene
ug?L
ND
20
20
21.5
22.7
108
113
60-140
5
Trichloroethene
ug/L
NO
20
20
22.3
22.7
112
113
60-140
2
Trichlorafluoramethane
ugJL
N❑
20
20
21.4
21.2
107
106
60-140
1
Vinyl chloride
uglL
ND
20
20
21 A
20.8
109
104
60-140
5
1,2-Dichloroethane-d4 (S)
%
94
94
70-130
4-Bromofluorobenzene (S)
%
98
99
70-130
Toluene -dB (S)
%
98
99
70-130
Results presented on this page are in the units indicated by the "ilniIn" column exceptwhere an alternate unit Is presented to She rWht of the result.
REPORT OF LABORATORY ANALYSIS
This iepori shall not be reproduces, except in full.
Date: 12/24/2019 10:41 AM without the written consent at Pace Analytical Services, LLC
Page 26 of 36
ieAnalydcal"
www.paeelatxam
QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No.: 92457416
qC Batch- 516241 Analysis Method: SM 6200B
QC Batch Method: SM 6200B Analysis Descriptlon: 620GB MSV
Associated Lab Samples: 92457416003
METHOD BLANK: 2766036
Associated Lab Samples: 92457416003
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
Analyzed
1.1,1,2-Tetrachloroethane
u91L
ND
0.50
1212211911.46
1,1,1-Trichloroethane
ugfL
NO
0.50
1212211911:46
1,1,2,2-Tetrachloroethane
ug1L
ND
a50
12/2211911;46
1,1,2-Trichloroethane
ug1L
ND
0.50
1212211911:46
1,1-Oichloroethane
uglL
NO
0.50
12/2211911A6
1,1-Dichloroethene
ug1L
ND
0.50
1212211911:46
1,1-Dichioropropene
ug1L
NO
0.50
1212211911:46
1,2,3-Trichlorobenzene
ug1L
NO
2.0
1212211911:46
1,2,3-Trich(oropropane
uglL
NO
0.50
12122M911A6
1,2,4•Trichlorobenzene
uglL
ND
2.0
12122M911:46
1,2,4-Trimethylbenzene
ug1L
NO
0.50
12/22/1911:46
11,2-Dibroma-3-chloropropene
ug)L
NO
1.0
12/22/19 11:46
1,2-Dibromoethane {EDBj
ugfL
NO
0,501
12/22/19 11:46
1,2-❑ichlorobenzene
ug1L
NO
0,50
12/22/19 11:46
1,2-Dichlorcethane
ug1L
NO
0.50
12122/1911:46
1,2 Dichlarapropane
uglL
NO
0,60
12/22/19 11:46
1,3,5-Trimethyfbenzene
ug1L
NO
0.50
1212211911:46
1,3-Dichicrobenzene
uglL
NO
0,50
1212211911:46
1,3-Dichioropropane
uglL
NO
0.50
1212211911:46
IA-❑ichlorobenzene
ugfL
ND
0.50
12/2211911:46
2,2-Dichloropropane
uglL
ND
0.50
1212211911:46
2-Chlarotoiuene
uglL
NO
0.50
1212211911:46
4-Chlorotoluene
uglL
NO
0.50
12122/1911:46
Benzene
ug1L
NO
0 50
12/22/19 11:46
Bromobenzene
uglL
NO
050
12/22/19 11:46
Bromochloromethane
uglL
NO
0.50
12/2211911.46
Bromodichloromethane
ugfL
ND
0.50
1212211911-46
Bromoform !
uglL
NO
0.50
12122/1911:46
Bromomefhane
ug1L
NO
5.0
1212211911:46
Carbon tetrachloride
ug1L
NO
0.50
12/22/19 11 AG
Chlorobenzene
uglL
NO
0.50
12/22/1911:46
Chloroethane
uglL
N❑
1.0
1212211911:46
Chloroform
ug1L
NO
0.50
12/2211911:46
Chloromethane
uglL
NO
1.0
12/22/19 11:46
cis-1,2-Dichloroethene
ug1L
NO
0.50
12/22/19 11'46
cis-1,3-Dichloropropene
ug1L
NO
0.50
1212211911:46
D€bromochioromethane
uglL
NO
0,50
121220911A6
Dibromomethane
uglL
NO
0.50
1212211911:46
Dichlorodifluaromethane
uglL
NO
0,50
12/2211911A6
❑ilsopropyl ether
uglL
NO
0.50
12122M9 W46
Ethylbenzene
uglL
NO
0.50
12122M911,46
Qualifiers
Pace Analyticai Services, LLC
9BOO Kinsey Ave Suite 10U
Huntersville, NC 28078
(704)875-9092
Results presented an this page are in the units indicated by the "Units" call nn except where an aftvmate unit is presenteq to the right ar the result.
REPORT OF LABORATORY ANALYSIS
This report shall nat be reproduced, except in full,
Date: 12/2412019 10:41 AM withoutthe written consent of Pace Ans5yfical Services, LLC Page 27 oT 36
Iac
e Anavical
(�www.pactstabs,com
QUALITY CONTROL DATA
Project: Pill Stop BP
Pace Project No.: 92457416
METHOD BLANK: 2766036
Associated Lab Samples: 92457416003
Parameter
Units
Matrix:
Blank
Resull
Water
Reporting
Limit
Analyzed
Hexachlorc-11,3-butadiene
uglL
ND
2.0
12/22/19 11746
tsopropy ibenzene (Cumene)
ug1L
NO
0.50
12122119 11:46
m&p-Xylene
ug1L
NO
1.0
12122/19 11:46
Methyl-tert-butyl ether
uglL
ND
0.50
12/22/19 11:46
Methylene Chloride
ugIL
ND
2.0
12/2211.9 11:46
n-Butylbenzene
uglL
NO
0,50
1212211911:46
n-Propylbenzene
uglL
ND
0.50
12122119 11 A6
Naphthalene
uglL
NO
2.0
12/2211911,46
o-Xyfene
ug1L
NO
0.50
1212211911:46
sec-Butylbenzene
ug1L
NO
0.50
12/2211911:46
Styrene
uglL
NO
0.50
12/2211911.46
ter[-Butylbenzene
ug1L
NO
0.50
1212211911,46
Tetra chloroethene
ug1L
ND
0.50
1712211911;46
Toluene
ug1L
NO
0.50
12122J1 9 11:46
trans- 1, 2- Dichloroe the ne
uglL
NO
0.50
12122/1911:46
trans- l,3-Dichloropropene
uglL
NO
0.50
1212211911:46
Trichlorcethene
ug1L
NO
0.50
12R2119 11 A6
Trichloroiluoromethane
ug1L
ND
1.0
1212211911:46
Vinyl chloride
ug1L
ND
1.0
12122/19 11:46
1,2-Dichlofoethane-d4 (S)
%
90
70-130
12122M9 11:46
4-Bromofluorobenzene (S)
%
96
70-130
12/22/19 11:46
Toluene -dB (S)
%
102
70.130
12122/19 11:46
LABORATORY CONTROL SAMPLE: 2766037
Qualifiers
Pace Analytical Services, LLC
9800 Kincey Ave Suite 100
huntersville, NC 28078
(704)875-9092
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits ❑ualifters
1,1,1,2-Tetrachloroethane
uglL
50
55A
111
60-140
1,1,1-Trlchloroethane
ug1L
50
54.0
108
60-140
1.1,2,2-Tetrachloroethane
ug1L
50
52.0
104
60-140
1,1,2-Trlchloroethane
uglL
50
51.5
103
60-140
1,1-Dichtoroethane
ug1L
50
51Z
102
60.140
1,1-Dichlorcethane
uglL
50
50.4
101
60-140
11-01chloropropene
uglL
50
56.6
113
60-140
1,2,3-Trichlorobenzene
uglL
5o
62.5
125
60-140
1,2,3-Trichloropropane
uglL
50
52,2
104
60040
12,4-Trichlorobanzene
ug1L
50
51.0
122
60.140
1,2,4-TOmethyl benzene
ug1L
50
57.2
114
60-140
1.2-Dibromo-3-chlaropropane
ug1L
50
57.2
114
60-140
1,2-Dibromoethane (EDB)
uglL
50
55.7
111
60-140
1.2-Oichlorobenxene
uglL
54
57.7
115
60-140
1,2-Dichloroethane
uglL
50
47.9
96
60-140
1,2-Dichloropropane
uglL
50
52.6
105
60-140
1,3,5-Trimethylbenzene
ug)L
50
56.3
113
60-140
1,3-Dichiorobenzene
uglL
50
56.7
113
60-140
Results presented on this page are In the units Indicated by the "Units" column except where nn attemale unrl is presented to the right or the mull.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date, 12/24/2019 10:41 AM without the written consent of Pace Analytical Services, LLC. Page 28 c136
aceAnalytical
www.paeel+tEs.00rn
QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No, 92457416
LABORATORY CONTROL SAMPLE: 2766037
Pace Analytical Servltas, LLC
9800 Kincey Ave Suite 100
Huntersville, NC 28078
(704)875-9092
Parameter
Units
Spike
Conc.
LCS
Result
LCS
% Roo
% Rec
Limits Qualifiers
1,3-Dichloropropane
uglL
50
55.8
112
60-140
1,4-Dichlorobenzene
uglL
50
57.8
116
60.140
2,2-Dichloropropane
ug1L
50
62.8
126
60-140
2-Chtorotoluene
Ug1L
50
55.0
110
60-140
4-Chlorotoluene
uglL
50
56.4
113
60-140
Benzene
ug/L
50
52.7
105
60-140
Bromobenzene
uglL
50
57.5
115
60-140
Bromochloromettlane
uglL
50
5Z3
105
60.140
Bromodichloromethane
ug&
50
53.6
107
60-140
Bromoform
uglL
50
57A
114
60-140
Brumomethane
uglL
50
53.2
106
60-140
Carbon tetrachloride
uglL
50
56.1
112
60-140
Chlorobenzene
uglL
50
54.5
109
60.140
Chloroelhane
uglL
50
58.6
117
60-140
Chloroform
uglL
50
50.6
101
60-140
Chloromethane
uglL
50
41.2
82
60-140
cis-1,2-Dichloreethene
ugiL
50
50.1
100
60-140
cis-1,3-Dlch1aropropene
ug1L
50
55,7
11l
60-140
Dibromochloromethane
ug/L
50
58.2
116
60-140
Dibromomethane
uglL
50
55.6
111
60-140
❑ichlerodifluorornethanc
uglL
50
48.1
96
60.140
Diisopropyl ether
ug1L
50
51.2
102
60.140
Etrlylbenzene
uglL
50
53.8
108
60.140
Hexachloro-1,3-butadiene
ugll-
50
57.5
115
60-140
Isopropylberizene (Cumene)
uglL
50
56.1
112
60.140
m&p-Xylene
ug/L
100
109
109
60-140
Methyl-tert-butyl ether
uglL
50
54.8
110
60-140
Methylene Chloride
uglL
5D
46.8
94
6D•14D
n-Butylt}enzene
uglL
50
58A
117
60.140
n-Propylbenzene
uglL
50
54.9
110
60-140
Naphthalene
uglL
50
62 0
124
60-140
c-Xylene
uglL
50
55.0
110
50-140
sea-Butylbenzene
uglL
50
58.3
113
60-140
Styrene
uglL
50
5&0
116
60-140
tert-Butylbenzene
uglL
50
47,6
95
60-140
Tetrachloroethene
uglL
50
55.3
111
60-140
Toluene
ug1L
50
51.5
103
60-140
trans-12-Dichtoroethene
uglL
50
51.0
102
60-140
trans-1,3-Dichloropropene
uglL
50
55.0
110
60-140
Trichloroethene
uglL
50
53.5
107
60-140
Trichlorafiuoromethane
uglL
50
49.9
100
60-140
Vinyl chloride
uglL
50
51.8
104
60-140
1,2-Dichloroethane-0 (S)
%
92
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
97
70-130
Results presented an this page are to the units indicated by the "Units" cotumrf except where an alternate unit is presented to thst right of the result
REPORT OF LABORATORY ANALYSIS
This report shall not be reprodured, e#cepl in full,
bate' 12/24/2019 10,41 AM without the written consent of Pace Analytical Services, LLC Page 29 of 36
aceArialyticai
www.pecdahe.eorn
QUALITY CONTROL DATA
Project; Pit Stop BP
Pace Project No.; 92457416
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2766035 2766039
Parameter
92457416003
Units Result
MS
Spike
Conc.
MSD
Spike
Cone.
MS
Result
1,1,1.2-Tetrachloraelhane
ug1L
ND
200
200
220
1.1,1-T6chioroethane
uglL
Nib
200
200
219
1.1,2,2- Tel rachloroethane
ug1L
ND
200
200
210
1,1,2-Trichloroethane
uglL
NO
200
200
214
1.1-Dichloroathane
uglL
N❑
200
200
216
1,1-Dichloroethene
ug1L
ND
200
200
216
1,1-Dichlorapropene
uglL
ND
200
200
238
12,3-Trichlorobenzene
uglL
ND
200
200
207
1,2,3-Trichloropropane
ug&
ND
200
200
219
1,2,4-Trichlorobenzene
uglL
N❑
200
200
208
1,2,4-Trimethylbenzene
ug1
222
200
200
439
1,2-❑ibromo-3-chloropropane
ug1L
N❑
200
200
216
1,2-Dibromoethane {EDB)
u911-
NO
200
2D0
218
12-Dichlorobenzene
uglL
ND
200
200
221
1,2-Dichloroethane
uglL
ND
200
200
201
1,2-Dichloropropane
uglL
ND
200
200
222
1,3,5-Trimelhylbenzene
ug1
55.8
200
200
280
1,3-Dichlorobenzene
uglL
ND
200
200
218
1,3- Diehl oropropane
uglL
NO
200
200
222
1,4-D(chlorobenzene
ug&
NO
200
200
219
2,2-Dichloropropane
uglL
ND
200
200
221
2-Chlorotoluene
uglL
ND
200
200
229
4-Chlorotoluene
uglL
ND
200
200
223
Benzene
uglL
1630
200
200
1820
Bromobenzene
ug1L
ND
200
200
228
Bromochloromethane
ug/L
ND
200
200
213
Bromodichloromelhane
uglL
ND
200
200
218
Bromoform
u91L
ND
200
200
221
Bromomethane
ug)L
NO
200
200
150
Carboy+ tetrachloride
uglL
NO
200
200
234
Chiorobenzene
uglL
ND
200
200
223
Chloroethane
uglL
ND
200
200
277
Chloroform
uglL
NO
200
200
223
Chloromethane
uglL
ND
200
200
146
cis-1,2-Dlchloroethene
uglL
NO
200
200
209
cis -1,3-Di chi oropropene
uglL
ND
200
200
221
Dibromochloromethane
uglL
NO
200
200
224
Dibromomethane
uglL
ND
200
200
227
Dichloradifluorornelhane
uglL
N❑
200
200
182
Diisopropyl ether
uglL
37.7
200
200
235
Ethylbenzene
uglL
240
200
200
457
Hexachlora-1,3-butadiene
uglL
ND
200
200
206
Isopropylbenzene (Cumene)
uglL
36.3
200
200
263
m&p-Xylene
uglL
128
400
400
572
Methyl-tert-butyl ether
uglL
130
200
200
346
Methylene Chloride
uglL
ND
200
200
202
Pace Analytical Services, LLC
9800 Kinsey Ave Suite Ian
Huntersville. NC 28076
(7o4)s7h-9o92
MSD
Result
MS
1A Rec
MSD
% Rec
% Rec
Limits
RPL1 Qual
211
110
105
60-140
4
214
109
107
60-140
2
201
105
100
60-140
5
210
107
105
60-140
2
209
108
104
60-140
3
207
108
103
60-140
4
228
119
114
60-140
4
222
101
109
60-140
7
198
109
99
60.140
10
217
104
109
60-140
4
437
109
107
60-140
1
216
108
108
60-140
0
208
109
104
60-140
4
215
111
108
60-140
3
186
100
93
60-140
8
219
111
1 D9
60-140
2
272
112
105
60-140
3
214
109
107
60-140
2
211
111
106
60-140
5
217
109
109
50-140
1
213
111
106
60-140
4
218
114
109
60-140
5
218
111
109
60-140
2
1860
95
113
60-140
2
218
114
109
60.140
5
206
106
103
60-140
3
216
109
108
60-140
1
208
111
104
60-140
6
192
75
96
60-140
24
225
117
112
60-140
4
213
111
106
60-140
5
280
139
740
60-140
1
211
112
105
60-140
6
145
73
73
60-140
1
201
104
100
60-140
4
216
111
106
60-140
2
214
112
107
60-140
5
218
113
109
60-140
4
169
91
85
M140
7
230
99
96
60-140
2
452
108
106
60-140
1
211
103
105
60-140
2
255
113
109
60-140
3
556
11i
107
60-140
3
331
108
100
60-140
5
197
101
98
60-140
2
Results presented on thls page are In the units Indicated by the "units" column except where an alternate unh Is presented to the fight of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full.
Date' 12/24/2019 10-41 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 36
leAi�aryticar
wwlN.parelaGe.renl
QUALITY CONTROL DATA
Project: Pit Stop BP
Pace Project No.: 92457416
Para Analytical Services, LLC
9800 Kineey Ave Suite 100
Huntersvllle, NC 20078
(704)87"092
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2766036
MS
92457416003 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
2766039
MS
Result
MSD
Result
MS
% Rec
MSD
%n Rec
% Rec
Limits
RPD
n-Butylbenzene
ugll-
22.4
200
200
233
235
105
106
60-140
1
n-Propylbenzene
ugll-
75,0
200
200
289
286
107
105
60-140
1
Naphthalene
uglL
276
200
200
497
536
ill
130
60-140
8
o-Xylene
uglL
10.6
200
200
233
223
111
106
60-140
4
see-Butyibenzene
ug&
NO
200
200
229
224
115
112
60-140
2
Styrene
ug)L
ND
200
200
229
223
114
111
60-140
3
tert-Butylbenzene
uglL
Nil
200
200
193
188
97
94
60-140
3
Tetrachloroethene
ug1L
NO
200
200
225
216
112
108
60-140
4
Toluene
uglL
20.3
200
200
236
232
108
106
60-140
1
trans- 1,2-Dichloroethene
ugll-
ND
200
200
217
208
109
104
60-140
4
trans- 1,3-Dichleropropene
uglL
ND
200
200
204
203
102
101
60-140
1
Trichloroethene
uglL
ND
200
200
230
221
115
110
60-140
4
Trichloroiiummethane
uglL
IUD
200
200
217
206
108
103
60-140
5
Vinyl chloride
uglL
ND
200
200
214
208
107
104
60-140
3
1,2-Dichloroethene-d4 (S)
%
96
98
70-130
4-Brflmotluorobenzene (S)
%
98
98
70-130
Toluene-d6 (S)
%
97
99
70-130
Results presented on Ihis page are In the units Indicated by the "Units" column except where an alternate unit Is presented to the right or the resuiL
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date' 12/24/2019 10:41 AM without the written consent of Pace Analytical Servlaes, LLC
r■'lren
Page 31 of 36
aceAna!}ical,.
www.pecalaba.com
QUALIFIERS
Project: Pit Stop BP
Pace Project No.: 92457416
DEFINITIONS
OF - Dilution Factor, if reported, represents the factor appi led to the reported data due to dilution of the sample aliquot.
NO - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection IImlt and below the adjusted reporting limit
MOIL - Adjusted Method Detection Limit.
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC ZB078
(704)B75-9092
POL - Practical Ouantitation Limit.
RL - Reporting limit - The lowest concentration value Ihat meets project requirements For quantilative data with known precision and
bias far a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270 The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPO values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Nol Calculable.
SG - Silica Gel - Clean -Lip
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chioroethylvinyi ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapler 4 for the analysis of AcrolelIt and Acrylonitrlle by EPA
Method 8260.
N-Nttrosodiphenytamine decomposes and cannot be separated from Dip henylamine rising Method 8270. The result reported for
each analyte is a combined concentration,
Pace Analytical is TN accredited. Contact your pace PM far the current list of accredited anal ytes,
TN - The NELAC Institute.
LABORATORIES
PASI-C Pace AnaiylicaI Services - Charlotte
ANALYTE QUALIFIERS
M 1 Matrix spike recovery exceeded 4C limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in Full,
Date- 12/2412019 10:41 AM wlthout the written consent of Pace Analy4icol SarVioes, LLC Page 32 of 36
_ - aceAnalXical
' www,pacaleha.sorn
r
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Pit Stop BP
Pace Project No_ 92457416
Lab I❑ Sample ID QC Batch Method QC Hatch
92457416001
MW-2
SM
6200B
516087
92457416002
MW-6
SM
6200B
516087
92457416003
MW-10B
SM
6200B
516241
92467416004
MW-13
SM
6200B
516087
92457416005
MW-14
SM
6200B
516087
92457416006
MW-15
SM
62008
516087
9245741600T
MW-16
SM
62003
516087
92457416008
MW-17
SM
6200B
516087
92457416009
TRIP BLANK
SM
6200B
516057
Date: 12124/2019 10:41 AM
REPORT OF LABORATORY ANALYSES
This reporl shall not 6e repmducecr, except in full,
without the wrinan consent ❑1 Pace AnalytcaJ Services, LLC
Pace Analytical Services, LLC
9800 Kincey Ave Suite 1fl0
Huntersville. NC 26078
(704)575-B092
Analytical Method
Analytical
Batch
Page 33 of 36
Document Name:
Document Revised: February 7, 2013
Sample Corsditlon U on Recei t(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
a�eAnaVkal
F-CAR•CS-033-Rev.06
Pace Carolinas Qual Ity Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑
Sample Condition Cllent Name:
upon Roceipt h� ` A Project #:
Courler: [3FpdEx ❑ups ❑uSPs ❑Cllent
❑ Commercial ace ❑Other:
Custody seal Present? ❑Yes Seals Intact? Oyes No
Packing Material: ❑Bubble Wrap Bubble Bags []None ❑ Other
Thermometer:
❑IR can ID: 22TO5$ Fype of foe: Wet ❑BIue
Confer Temp ('C): _, Correction Factor: Add/subtract ('CI O.O°C
Cooler Temp Corrected2NIIA,
USDARegulatedSoli ( wafer sample)
Did samples originate In a quarantine zone within the united State;: CA, NY, or SC {check ma psi?
[]Yes ❑No
WO#:92457416
I� � lit lli 1 I li �11� 11 ll�
92457416
Dot dllnithibRenon rssaminIngCcntenw Z'« a JL
BlolagicalTissu_e�roien7
❑None
Des ONO N/A
Temp should be above freezing to VC
❑samples out of temp oriterla.5ampies an ice, coaling process
has begun
Did samplesoriglnate Nam afareign source 11 nte mational IV,
Includint Hawaii and PuertoRicoj? ❑Yes ❑Nu
Camments/Otscrepancy.
Chaln of Custody Present?
VeA
FINo
NIA
1.
Samples Arrlved within Hold Time?
Yes
[]Nq,
ONJA
2-
5 ho rt He Id Time An al is 102 hr. ?
clyes
N A
3,
Rush Turn Ara und Time Reg nested?
13yes
K.
i]rr1A
4.
Sufficient Volume?
No
NIA
5.
Correct Containers Used?
-Pace Containers Used?
es
Y
ONO
ONO
❑N/A
N/A
6.
Cnntafners Intact?
CIND
N
7.
Dissolved analysis-. Sample-; Field Rfteredi
s
ON.
IA
a.
Sample Labels Match COC?
-includes Date/Time/ID/Analysis Matrix-
Mej
V V ►
QNo
ONJA
9-
Headspace in VCA Vials (>5-Gmm)?
es
No
NIA
10.
Trip Blank Presents
Trip Blank Custody5ealsPre5ent?
Yes
es
❑No
IYo
❑NIA
NIA
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENF NOTIFICATION/RESOLUTION
Field Date Required? []Yes ❑No
Person contacted: Datejiime:
Project Manager SCURF Review: Date:
Project Manager SRF Review: I l Date: ?
's q .34 of 36
Document Name:
Document Revised: February 7, 2018
e�CL'�P.ri11CrZ�'
Sample CondHlen upon RecelptlSCUR)
Page 1 of 2
Document No.:
issuing Authority:
F-CAR-CS-033-Rev.05
Pace Carolinas Quality Office
•Check mark top half of box if pH and/or dechlorinatIon Is Project 9
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DROJ8015 (water) DOC, LLHg
*"Bottom half of box is to list number of bottle
Wo#:92457416—
PM: RP Due Date: 12/24/19
CLIENT: 92-shield
SR
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PH Adjustment Log for Preserved Samples
Sample to
Type or Preservativa
pH upon receipt
Date preservation adjusted
nmi.. presonration
adltrsted
Amount of Preservative
added
Lot It
Note: whenever there is a discrepancy affecting North Carolina compifante samples, a copy of trds Farm will de sent to the North Carolina DFlJNR Certlficatlon Office 0 U.
Qut of hold, incorrect presrrvotive, out of temp, incorrect containers.
--Page 35 of 36
°11%vvf CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately
Scr:ion A Section R Section C
Regvtred Cflrnt Information: Required Project irlfonnation: Invoice tntarmalion: page. Of
Cu - pang shrele; ReParr TG Kawn Srachura Attention Nevr Starhura
Aadre5s 43L'1 Taggal Creek Faad C9py YC CoelpEny Name Sr+refd
Crtar;onl . NC 2.E20H
Aaaress 4W1 Ta gart Creek Rd Cnaricne NC 2s206
RetluiatoryActency
Emad kslachura ahielden ine F .earn
Purchase Order
Pace 0.0le
NCDEO • UST
Prlone t7D4139--fi$13 Fsx t7pgl39q-6%8
Project Name Prt Slop BA
Pace Prolee hM1anSgpr Payne. Amanda
Sate ILocatlon
Fteq�esled Due Cale Standard
PrgeG A 1120116
Pace Prattle a
NC
Requested
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"DATE
r
SAMPLER NAME AND SIGNATURE
PRINT Name of SAMPLER_
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DATE Si ned:
V o
APPENDIX J
Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contamination Calculations
NCGWI #13404
Date of Sampling
Mass of GroundwaterContaminatian (rn..)
mg,,,=Volume (v) x Concentration (C)
V(L)=
C (VOCs in ug/L)=
mgw(ug)=
mgw(g)=
V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n)
A(ft')=
D (ft)=
n=
V (ft)=
V(l)=
Notes:
- Area (A) = Approximate area of the combined benzene and MTBE plumes
-Concentration is based on Total VOCs for each specific sampling event
-Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water
level in ail site monitoring wells during sampling event (7.5 ft)
-Porosity (n) = Total Porosity (Using a total porosity of 0.46*)
1 ft = 28.3168 L
-mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = liter; ug/L =
micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n
=Porosity; ft = feet
*Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W.
(1994). Applied Hydrogelogy (3rd ed.). New York, NY: Macmillan College Publishing Company.
inc.]
7/19/2017
1,102,953.52
6,542.25
7,215,797,655.75
7,215.80
11,290.00
7.50
0.46
38,950.50
1,102,953.52
12/13/2017
540,730.53
3,055.00
1,651,931,780.15
1,651.93
5,535.00
7.50
0.46
19,095.75
540,73053
Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contamination Calculations
NCGWI #13404
Mass of Groundwater Contamination (mgw)
mgw Volume (v) x Concentration (C)
V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n)
Notes:
- Area (A) = Approximate area of the combined benzene and MTBE plumes
-Concentration is based on Total VOCs for each specific sampling event
Date of Sampling 6/26/2018 1/3/2019
V(L)=
561,734.52
483,580.15
C (VQCs in ug/L)=
11,319.00
1,110.00
mgw(ug)=
6,358,273,031.88
536,773,968.72
mgw(g)=
6,358.27
536,77
A(ftz)=
5,750.00
4,950.00
D (ft)=
7.50
7.50
n=
0.46
0.46
V (ftl)=
19,837.50
17,077.50
VIL)=
561,734.52
493,580.15
-Depth (D)=Terminal depth of monitoring well (MW-10B) screen (M20 ft)- average static water
level in all site monitoring wells during sampling event (7.5 ft)
-Porosity (n) =Total Porosity (Using a total porosity of 0.46*}
1 ft3 = 28.3168 L
-mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L =
micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n
=Porosity; ft = feet
*Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W.
(1994). Applied Hydrogeiogy (3rd ed.). New York, NY: Macmillan College Publishing Company,
Inc.1
Carolina Fast Mart 44 - Fit Stop - Mass of Groundwater Contamination Calculations
NCGWI 413404
Date of Sampling
Mass of Groundwater Contamination (mgw)
mr,=Volume (v) x Concentration (C)
V(L)=
C (VUCs in ug/L)=
mgw(ug)=
mgw(g)=
V=Contaminant Area (A) x Depth of Plurne (0) x Porosity (n)
A(ft')=
D (ft)=
n=
V (ft 3)=
V(L)=
Notes:
- Area (A) = Approximate area of the combined benzene and MTBE plumes
-Concentration is teased on Total VOCs for each specific sampling event
-Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water
level in all site monitoring wells during sampling event (7.5 ft)
-Porosity (n) = Total Porosity (Using a total porosity of 0.46*j
1ft3=28.3169L
-mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L =
micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n
=Porosity; ft = feet
*Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W.
(1994). Applied Hydrogelogy (3rd ed.). New York, NY- Macmillan College Publishing Company,
Inc.]
7/2/2019
483,580.15
6,965.00
3,368,135,758.68
3,368.14
4,950.00
7.50
0.46
17,077.50
483,590.15
12/12/2019
385,984.88
4,619.31
1,782,983,838.94
1,782.98
3,951.00
7.50
0.46
13,630.95
385,984.98