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HomeMy WebLinkAbout1304_CharlotteMotorSpeedwayV_MSWLF_Oct2019GW_FID1387787_20200121Data - Yes) No) Doc/Evr TNL: utivn Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6), Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NO 2L groundwater standards or NC 28 surface water standards. The notification must include a preliminary anaiysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed expiosive gas levels- This includes any structures on or nearby the facility (NCAC 138 -1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWv1, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Hanle of entity submitting data (laboratory, consultant, facility owner): Jett Environmental Consulting, PLLC Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address: Name' sTEve tE E-mail. STEVE. JETTOJETTENVIRO.roM Phone L313; 61;f,a654 NO Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (,0500 or ,1600) October 20-24, 2006) BFI Waste Systems of North 5105 Morehead Road, October 14-17, 2019 & Speedway, Landfill V America. Inc. - Charlotte Motor Concord, NC 28027 13-04 1600 N ovember 6. 2019 Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Q Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells Corrective action data (specify) Leachate monitoring data Surface water monitoring data ❑ Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water Mon itonng points, dates, analytical values, NO 2L groundwater standard, NC 28 surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct - Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steve Jett n owner (314) 4864,654 Facility Signature rifle (Area Code) Telephone Number I L -1<j [ 7.--L o Affix NC Licensedl Professional Geologist Seal ❑ate Jett Environmental Consulting, PLLC,1002 Morgan Meadow Drive, Wentzville, Mo 63385 Facility Representative Address NO FIE Firm License Number (if applicable effective May 1, 2009) Revised 612009 Groundwater Statistical Analysis Report Second Semi -Annual 2019 Sampling Event Charlotte Motor Speedway, Landfill V Concord, North Carolina Permit No. 13-04 January 2020 Prepared by: JETT ENVIRONMENTAL CONSULTING 1002 Morgan Meadow Drive 314-496-4654 Wentzville, MO 63385 www.jettenviro.com TABLE OF CONTENTS 1.0 INTRODUCTION.............................................................................1 2.0 SITE BACKGROUND AND MONITORING NETWORK................1 3.0 SITE HYDROGEOLOGY................................................................1 4.0 DATA EVALUATION......................................................................2 5.0 STATISTICAL PROCEDURES.......................................................2 5.1 Inter -Well Prediction Intervals....................................................2 5.2 Intra-Well Confidence Intervals..................................................3 5.3 Statistical Results Summary.......................................................4 6.0 ASSESSMENT MONITORING STATUS........................................4 7.0 WATER QUALITY ASSESSMENT ACTIVITIES ............................7 Table 1 Wells Analyzed Table 2 Organic Detections Table 3A Comparisons to GWPSs (Inorganics) Table 313 Comparisons to GWPSs (Organics) Table 4 Surface Water Data Compared to NC 213 Standards Table 5 Inter -Well Prediction Limit Exceedances Table 6 Water Quality Assessment Well Data Compared to GWPSs APPENDICES Appendix A Potentiometric Surface Map Appendix B Statistical Evaluations Appendix C Laboratory Analytical Reports & Field Information Forms Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 1 1.0 INTRODUCTION On behalf of BFI Waste Systems of North America, Inc. -Charlotte Motor Speedway, Landfill V, Jett Environmental Consulting statistically evaluated the Second Semi -Annual 2019 water quality monitoring data. Groundwater, surface water, and leachate sampling was completed by Pace Analytical Services, LLC (Pace) on October 14-17 and November 6, 2019. Analytical testing was performed by Pace. The statistical analysis software package utilized, Sanitasll' follows a documented decision logic that incorporates the following guidance document: USEPA "Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance" (March 2009). 2.0 SITE BACKGROUND AND MONITORING NETWORK Jett Environmental Consulting statistically evaluated parameters from the Second Semi -Annual 2019 event against background data using inter -well prediction interval analysis. Prediction intervals are considered a powerful tool for groundwater statistical analysis, when feasible, due to their inherent low false negative and false positive rates utilizing confirmatory resampling, if necessary. Statistical comparisons of data to the Groundwater Protection Standards (GWPSs) were performed utilizing intra-well confidence limits. Background for the inter -well prediction limits was defined as all samples taken from each upgradient well. The parameters subject to statistical evaluation during detection monitoring are noted in NCDEQ Section .1633 as constituents listed in Appendix I of 40 CFR Part 258 "Constituents for Detection Monitoring". Due to previous detections, the Appendix II constituent mercury is also sampled semi-annually at each well along with the Appendix I constituents. In addition, in a May 29, 2018 memorandum, NCDEQ requested groundwater and surface water samples collected at landfills after July 1, 2018 be analyzed for 1,4-dioxane. The facility monitored 1,4-dioxane during the Second Semi -Annual 2018 and First Semi -Annual 2019 events even though it is not specified in the rules or approved monitoring plan. Per an August 8, 2019 DEQ letter, approval was granted to monitor 1,4-dioxane on alternating events (i.e. first semi-annual 2020, second semi-annual 2021, first semi-annual 2022, etc.). Therefore, 1,4-dioxane was not sampled for the groundwater wells or surface water points during the Second Semi -Annual 2019 event. Table 1 lists the groundwater monitoring wells for the site. Each of the wells was sampled during the Second Semi -Annual 2019 event. In correspondence dated October 13, 2015 (DIN 25121), NCDEQ approved a request to sample MW-17, MW-17A, and MW-24 annually. Wells MW-17, MW-17A, and MW- 24 were sampled during the first semi-annual 2019 event. The next scheduled annual sampling event for wells MW-17, MW-17A, and MW-24 is during the First Semi -Annual 2020 event. In addition to groundwater monitoring, the site has a surface water monitoring network consisting of one upstream surface water sampling point (SW-1) and one downstream point (SW-2). These points are sampled semi-annually for the 40 CFR Part 258 Appendix I list in conjunction with the groundwater monitoring wells. Both surface water monitoring points were sampled during the Second Semi -Annual 2019 event. A leachate sample is also routinely collected for analysis in accordance with the facility's permit. The leachate sample was analyzed for the 40 CFR Part 258 Appendix I list, biochemical oxygen demand, chemical oxygen demand, nitrate as N, phosphorous, and sulfate. 3.0 SITE HYDROGEOLOGY Previous site investigations indicate that groundwater is present in either the saprolite, Piedmont weathered rock, or bedrock depending on location. Data suggests hydraulic connection between these units, which form the uppermost aquifer. Generally, data indicate that the groundwater flow is principally within the saprolite and Piedmont weathered rock, in the direction of the Rocky River. Locally, the vertical component Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 2 of the groundwater flow may be slightly downward in topographic high areas and slightly upward in topographic low areas. In general, the configuration of the groundwater surface is similar to the topography of the site. Appendix A provides a potentiometric surface map for the site utilizing groundwater level data from the Second Semi -Annual 2019 event. Groundwater flow direction for the Second Semi -Annual 2019 event was to the southwest, consistent with past events. Groundwater flow rate for the Second Semi -Annual 2019 event was estimated to range from 22 feet/year to 135 feet/year, consistent with past events. Flow rate calculations are available in Appendix A. A well construction summary table is provided in Appendix A. 4.0 DATA EVALUATION The analytical results for the Second Semi -Annual 2019 event for the groundwater samples are summarized on Tables 2, 3A, and 3B. Table 2 provides a summary of organic compounds detected at or above a laboratory practical quantitation limit (PQL) in groundwater samples. Of the nineteen quantifiable VOC detections, ten volatile organic compounds (VOCs) were above a GWPS: 1,2-dichloroethane at MW- 33 and MW-34; 1,4-dichlorobenzene at MW-25; benzene at MW-31, MW-32R, MW-33, and MW-34; and vinyl chloride at MW-31, MW-32R, and MW-33. The detected VOCs are consistent with past events. As shown on Table 3A, four Appendix I inorganic constituents (barium at MW-18A, MW-2013; cobalt at MW- 2B, MW-18A, MW-21, MW-22, MW-22A, MW-26, and MW-32R; lead at MW-32R; and nickel at MW-22A) were detected above a PQL and a Groundwater Protection Standard (GWPS) during the Second Semi - Annual 2019 sampling event. Results are generally consistent with past events. As shown on Table 4, during the Second Semi -Annual 2019 event, one NC 2B Surface Water Standard was exceeded in the surface water samples: zinc at SW-1. SW-1 is located upgradient to the facility, therefore the Second Semi -Annual 2019 concentration of zinc at SW-1 (121 ug/L) is not attributable to the landfill. The constituents detected in the leachate sample collected during the Second Semi -Annual 2019 event are typical for Ieachate at this facility. Appendix C contains a copy of the groundwater, surface water and Ieachate laboratory analytical reports and field information forms for the Second Semi -Annual 2019 event. 5.0 STATISTICAL PROCEDURES The SanitaSTI program was utilized to compile and statistically evaluate the data for the Second Semi - Annual 2019 sampling event. Summary tables for the inter -well prediction interval analysis are available in Appendix B. Statistical analyses (i.e. inter -well prediction limits) were performed to establish background concentrations and determine if the NC GWPS/NC 2L value -to -value exceedances for barium at MW-18A, MW-2013; cobalt at MW-213, MW-18A, MW-21, MW-22, MW-22A, MW-26, and MW-32R; lead at MW-32R; and nickel at MW-22A exhibited statistically significant increases above background. 5.1 Inter -Well Prediction Intervals The prediction interval is a statistical method used to compare a single observation to a group of observations. The prediction interval is calculated to include observations from the same population with a specified confidence. In groundwater monitoring, a prediction interval approach may be used to make comparisons between background and compliance data. The interval is developed to contain all future observations, within a certain probability. For the Charlotte Motor Speedway V site, inter -well prediction intervals have been developed based on a 99% confidence that future observations will fall within the range. If any future observation exceeds the prediction interval, this is considered statistically significant evidence that the observation is not representative of the background group. Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 3 During parametric prediction interval analysis, the mean and the standard deviation are calculated for the raw or transformed background data. The number of comparison observations, K, is defined to be included in the interval. If less than 15% of the background observations are nondetects, the nondetects are replaced with one half of the reporting limit prior to performing the analysis. If more than 15% but less than 50% of the background data are below the reporting limit, the data's sample mean and standard deviation are adjusted according to the Kaplan -Meier method. However, when the background data are not transformed - normal or contain greater than 50% observations below the reporting limit, SanitasT' automatically constructs a nonparametric prediction interval. During nonparametric analysis, the highest value from the background data is used to set the upper limit of the prediction interval. For the Second Semi -Annual 2019 event, barium at MW-18A, MW-20B; cobalt at MW-2B, MW-18A, MW- 21, MW-22, MW-22A, MW-26, and MW-32R; lead at MW-32R; and nickel at MW-22A statistically exceeded background and were above NC GWPS/NC 2L standards in a value -to -value comparison. Table 5 provides a summary of the prediction limit exceedances. The prediction limit exceedances are generally consistent with past events. Included in Appendix B are time series plots for each of the inorganic parameters statistically analyzed for this reporting period and plots of the Second Semi -Annual 2019 organic detections at or above PQLs. 5.2 Intra-Well Confidence Intervals Per NCDEQ Regulation .1634(H), Groundwater Protection Standards (GWPSs) are equal to the National Primary Drinking Water Standard -Maximum Contaminant Level (MCL) or North Carolina 15A NCAC 2L Water Quality Standard, whichever is lower. Tables 3A and 3B provide comparisons of the Second Semi -Annual 2019 results to the GWPSs. In order to determine if the groundwater concentrations exhibit a statistical exceedance of the GWPS, a statistical comparison was made to the GWPSs. The following text outlines the procedures that were used to statistically compare concentrations to GWPSs. Per the U.S. Environmental Protection Agency document (dated March 2009), titled Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, a Confidence Interval is constructed from sample data and is designed to contain the mean concentration of a well analyte in groundwater monitoring, with a designated level of confidence. A confidence interval generally is used when samples are being compared to a GWPS, which is typically the MCL or alternate concentration limit (i.e. 2L Standard or NC GWPS). A lower confidence interval analysis was used to statistically compare to GWPSs. The method constructs a normal confidence interval on the mean concentration of a constituent incorporating, at a minimum, the four most recent measurements. The lower confidence interval on the mean was compared to the GWPS to determine whether the mean concentration exceeded its GWPS. If the lower confidence interval on the mean exceeds the GWPS then there is statistically significant evidence that the mean concentration of that constituent exceeds the GWPS. The distribution of the data is evaluated by applying the Shapiro -Wilk or Shapiro -Francis test for normality to the raw data or, when applicable, transformed data. If less than 15 percent of the observations are non - detects, the non -detects will be replaced with one half the reporting limit prior to performing the normality test and constructing the confidence limit. Per .1634(g)(5), if background (statistical limit based on upgradient well data) is higher than the NC 2L Standard, then background may be utilized as the GWPS. Background for organics is considered the non - detect level (equivalent to the PQL). The following is a summary of background data that was utilized as the GWPS: Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 4 ➢ The PQL (1.0 ug/L) for 1,2-dichloroethane, tetrachloroethene, and vinyl chloride is higher than the 2L Standard (0.4 ug/L, 0.7 ug/L, and 0.03 ug/L, respectively); therefore, the PQL (1.0 ug/L) was utilized as the GWPS for 1,2-dichloroethane, tetrachloroethene, and vinyl chloride. ➢ Background for total antimony (6 ug/L) is higher than the NC 2L Standard (1 ug/L), therefore 6 ug/L was utilized as the GWPS as outlined in .1634(g)(5). ➢ Background for total chromium (98 ug/L) is higher than the NC 2L Standard (10 ug/L), therefore 98 ug/L was utilized as the GWPS as outlined in .1634(g)(5). ➢ Background for total cobalt (12 ug/L) is higher than the NC 2L Standard (1 ug/L), therefore 12 ug/L was utilized as the GWPS as outlined in .1634(g)(5). ➢ Background for total thallium (5.5 ug/L) is higher than the NC 2L Standard (0.28 ug/L), therefore 5.5 ug/L was utilized as the GWPS as outlined in .1634(g)(5). ➢ Background for total vanadium (33 ug/L) is higher than the NC 2L Standard (0.3 ug/L), therefore 33 ug/L was utilized as the GWPS as outlined in .1634(g)(5). Inorganic and organic concentrations detected above PQLs and GWPSs (See Tables 3A and 3B) were statistically compared to their respective GWPSs utilizing intra-well confidence limits. As provided in Appendix B, two inorganics statistically exceeded a GWPS for the Second Semi -Annual 2019 event: cobalt at MW-22A and nickel at MW-22A. Four VOCs statistically exceeded a GWPS for the Second Semi -Annual 2019 event: benzene at MW-32R, MW-33, and MW-34; and vinyl chloride at MW-33. Wells MW-22A, MW-32R, MW-33, and MW-34 are already in the Assessment Monitoring Program 5.3 Statistical Results Summary Assessment Monitorina Inorganic and organic concentrations detected above PQLs and GWPSs were statistically compared to their respective GWPSs utilizing intra-well confidence limits. Two inorganics statistically exceeded a GWPS for the Second Semi -Annual 2019 event: cobalt at MW-22A and nickel at MW-22A. Four VOCs statistically exceeded a GWPS for the Second Semi -Annual 2019 event: benzene at MW-32R, MW-33, and MW-34; and vinyl chloride at MW-33, which was consistent with recent events. 6.0 ASSESSMENT MONITORING STATUS In accordance with Assessment Monitoring requirements set forth in the NCDEQ Regulations for Municipal Solid Waste Landfills Section .1634: (e) If the concentrations of all Appendix II constituents are shown to be at or below the approved ground- water protection standards, for two consecutive sampling events, the owner or operator shall report this information to the Division, and the Division shall give approval to the owner or operator to return to detection monitoring. (f) If one or more Appendix II constituents are detected above the approved ground -water protection standards in any sampling event, the owner or operator, shall within 14 days of this finding, submit a report to the Division, place a notice in the operating record, and notify local government officials. The owner or operator. (1) shall: (A) Characterize the nature and extent of the release by installing additional monitoring wells, as necessary; (B) Install at least one additional monitoring well at the facility boundary in the direction of contaminant migration and sample this well in accordance with Paragraph (d)(2) of this Rule; (C) Notify all persons who own land or reside on land that directly overlies any part of the plume of contamination if contaminants have migrated off -site; and (D) Within 90 days, initiate an assessment of corrective measures as required under Rule .1635 of this Section; or (2) may demonstrate that a source other than a MSWLF unit caused the exceedance of the ground -water protection standards, or the exceedance resulted from error in sampling, analysis, or natural variation in Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 5 ground -water quality. A report documenting this demonstration shall be approved by the Division. If required by G.S. 89C or G.S. 89E, a professional engineer or licensed geologist shall prepare these documents. [Note: The North Carolina Board of Examiners for Engineers and Surveyors and the Board of Licensing of Geologist has determined, via letters dated July 16, 2010 and November 30, 2010 respectively, that preparation of documents pursuant to this Paragraph constitutes practicing engineering or geology under G. S. 89C and G. S. 89E.] A copy of the approved report shall also be placed in the operating record. If a successful demonstration is made, the owner or operator may discontinue assessment monitoring, and may return to detection monitoring when approval is given by the Division. Until a successful demonstration is made, the owner or operator shall comply with Paragraph (0(1) of this Rule including initiating an assessment of corrective measures. During the Second Semi -Annual 2019 event, no Appendix II constituents (not also on the Appendix I list) were detected above GWPSs (see Tables 3A and 3113). Two inorganics statistically exceeded a GWPS for the Second Semi -Annual 2019 event: cobalt at MW-22A and nickel at MW-22A. Four VOCs statistically exceeded a GWPS for the Second Semi -Annual 2019 event: benzene at MW-32R, MW-33, and MW-34; and vinyl chloride at MW-33, which was consistent with recent events. The following groundwater monitoring wells are in assessment monitoring due to past exceedances: MW-17, MW-17A, MW-18A, MW-19, MW-19A, MW-20B, MW-22, MW-22A, MW-25, MW-26, MW-32R, MW-33, and MW-34. Wells with GWPS statistical exceedances during the Second Semi -Annual 2019 event (MW-22A, MW-32R, MW-33, and MW-34) are already in the assessment monitoring program. The following items are noted with regards to the Second Semi -Annual 2019 GWPS statistical exceedances: • It has been previously concluded that the VOC migration in the MW-32R, MW-33, and MW-34 portion of the site is due to landfill gas migration. The facility has implemented several phases of improvements to the gas collection system in recent years to address gas migration and improve groundwater conditions. Monitoring wells MW-32R, MW-33, and MW-34 will continue in Assessment Monitoring. Cobalt at MW-22A statistically exceeded the respective GWPS. Cobalt is naturally occurring at the site, evident by the historical cobalt detections in various wells across this site, and as typically found within soils of the Upper Piedmont Region of North Carolina (per a USGS Scientific Investigations Report 2013-5072 titled, "Naturally Occurring Contaminants in the Piedmont and Blue Ridge Crystalline -Rock Aquifers and Piedmont Early Mesozoic Basin Siliciclastic-Rock Aquifers, Eastern United States, 1994-2008"). In addition, wells downgradient of MW-22A (i.e., MW-10 and MW-10A) have not had confirmed, quantifiable detections above the PQL for cobalt. The site does not recommend additional corrective measures other than the upgrades that have been implemented to the landfill Gas Collection and Control System (GCCS) described below. The GCCS improvements and future upgrades to be implemented as needed should further enhance the removal of landfill gas and improve groundwater quality. In correspondence dated October 23, 2014 (DIN 22116), NCDEQ approved a site request to sample the full suite of Appendix II constituents every three years. The most recent full set of Appendix II sampling event occurred during the First Semi -Annual 2017 event. Therefore, the next Appendix II event will occur during the first semi-annual 2020 event for the assessment wells. Previously, dichlorodifluoromethane, mercury, and tin were the only Appendix II (non -Appendix 1) constituents confirmed detected above an PQL. However, during the First Semi -Annual 2019 event, dichlorodifluoromethane and tin had not been confirmed detected since October 2011. Therefore, only mercury will continue to be sampled semi-annually at each well along with the Appendix I constituents. Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 6 Landfill Gas Collection and Control System (GCCS) The following landfill gas system information was provided by SCS Engineers. The GCCS has been operational at the Landfill since 1996. As areas of the Landfill reached 5 years old or 2 years old and at final grade, the GCCS was expanded in general accordance with the NSPS GCCS Design Plan. The GCCS includes over 220 vertical extraction wells, 1 horizontal collector, and is connected to over 30 leachate cleanouts. The facility includes the following major control system components: • A 3,000 scfm candlestick flare, • A 6,000 scfm enclosed flare, • A 12,000 scfm blower system, and • 3 LFG-fired turbines. The turbines are part of a landfill gas -to -energy (LFGTE) facility at the site. The LFGTE facility is owned and operated by Fortistar. The LFGTE facility began generating electricity in early 2000 with power being sold to the City of Concord. Construction on the 2019 GCCS Expansion began on April 19, 2019, and was completed on July 31, 2019. Construction and installation was performed by B&M Excavating Co., LLC, and its drilling subcontractor Recovery Drilling Services. SCS provided construction quality assurance (CQA) services to verify that construction activities were completed in general accordance with the Construction Drawings. The project consisted of the construction and installation of the following: • Nine replacement vertical LFG extraction wells: EW-38E, EW-58E, EW-70D, • EW-120B, EW-121 B, EW-126A, EW-184A, EW-200A, and EXP-3C; 925 feet in total depth. • Three new vertical LFG extraction wells: EW-543, EW-544, and EW-545; 130 feet in total depth. • Two new de -watering wells: DW-1 and DW-2; 59 feet in total depth. • 6-inch diameter HDPE SDR-17 LFG lateral pipe. • 6-inch diameter HDPE SDR-17 gravity liquids drain pipe. • 6-inch diameter HDPE SDR-17 perforated pipe for horizontal LFG collector. • 4-inch/6-inch diameter HDPE SDR-11/17 dual containment forcemain pipe. • 4-inch diameter HDPE SDR-11 forcemain pipe. • 2-inch diameter HDPE SDR-9 airline pipe. • Two 6-inch diameter HDPE isolation valves for gravity liquids drain pipe. • One 4-inch diameter HDPE isolation valve for forcemain pipe. • Seven 2-inch diameter isolation/blowoff valves. • Seven 6-inch wye cleanouts for gravity liquids drain pipe. • Four 6-inch wye cleanout for horizontal collector pipe. • Seven 4-inch wye cleanouts for forcemain pipe. • Six 1-inch Plast-O-Matic combo air release/de-gassing valves. • Four'/2-inch Plast-O-Matic de -gassing valves. • One 6-ft diameter HDPE electric pump station. • Twenty-six PumpOne pneumatic pumps for select existing, replacement, new, and de -watering wells. Additionally, in the southwest corner of the site outside the waste disposal area, four soil probes were drilled to assess the presence of LFG near monitoring wells MW-17, MW-17A, MW-31, MW-32R, MW-33, and MW-34. This was proactively and voluntarily completed primarily to address VOC detections in groundwater and the presence of landfill gas measured in the headspace at these wells that is concluded to be causing the detections. Drilling and construction were performed by A.E. Drilling Services. In October 2018, the four probes were connected to the active landfill gas collection and control system (GCCS) by B&M Excavating Co., LLC and a vacuum applied. The "Soil Gas Extraction Wells and Migration Assessment Report" dated March 11, 2019 by SCS Engineers provided the results of the study and the following recommendations: Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 7 • Continue to actively extract gas from these four probes and monitor on a monthly basis. • Investigate potential causes of landfill gas migration from the landfill. • Install additional soil gas extraction wells in this area. • Maximize landfill gas removal from existing extraction wells in this area. • Evaluate additional methods for landfill gas extraction within the waste mass in the area. Because of the improvements stated above, the efficiency of the GCCS has improved. 2018 and 2019 upgrades to the GCCS should further enhance the removal of landfill gas and continued improvement in groundwater quality. The soil probe investigation was a proactive, voluntary investigation and the site will continue to monitor these probes on a voluntary basis. 7.0 WATER QUALITY ASSESSMENT ACTIVITIES Past Water Qualitv Assessment Activities In a letter dated January 28, 2010 from NCDEQ to the site, a Water Quality Assessment Plan was requested. The requirements for, or the contents of a Water Quality Assessment Plan (WQAP) are not referenced in NC Solid Waste Regulations or Guidance Documents, therefore the facility met with NCDEQ on March 9, 2010 in order to discuss potential items to include in the requested WQAP. Site representatives discussed with NCDEQ the planned items to be included in the WQAP. Subsequently, the site submitted a WQAP on March 19, 2010 of the proposed activities to address the constituents detected above the North Carolina 15A NCAC 2L Water Quality Standards at the site. In correspondence dated April 8, 2010, NCDEQ approved the Water Quality Assessment Plan. The proposed field activities associated with the WQAP were conducted in May 2010. A Water Quality Assessment Report summarizing the data collected during the Water Quality Assessment activities was submitted under separate cover on August 2, 2010. The August 2, 2010 Water Quality Assessment Report provided a summary of actions completed to date and proposed actions in order to address the source and extent of the VOC detections in groundwater monitoring wells at the site. The first phase of the field work occurred in conjunction with the First Semi - Annual 2010 event (May 2010) and consisted of (1) a sewer line examination, (2) headspace methane monitoring in groundwater monitoring wells of concern, and (3) a geochemical evaluation of groundwater and leachate. The results and summary of the first phase activities were submitted within the August 2, 2010 Water Quality Assessment Report. Results of the first phase indicated that (a) no apparent impacts were identified in the vicinity of the sewer line, (b) no significant concentrations of methane are currently present in the headspace of the groundwater monitoring wells of concern, and (c) the geochemical comparisons of MW-19A to leachate indicate possible mixing of groundwater and leachate. However the lack of heavy metals and the presence of downward trending VOCs in groundwater indicate that landfill gas likely was the source of impact at some stage. The improving groundwater conditions indicate that the source has likely been mitigated by the upgrades to the GCCS over the last few years. The February 28, 2011 Water Quality Assessment Report provided an updated summary of the data collected during the Water Quality Assessment activities in the Second Semi -Annual 2010 event (second phase). Installation and monitoring of wells downgradient of the wells of concern would allow the delineation of the horizontal and vertical extent of VOCs. The second phase of the field work occurred in October and November 2010 (in conjunction with the Second Semi -Annual 2010 event) and consisted of (4) installing new wells MW-18R, MW-18AR, MW-19R, and MW-19AR, and (5) sampling the new wells for the Appendix I list of constituents. Results of the second phase indicated that (d) lack of impact at well MW-18AR, which defines the extent of horizontal and vertical area of impact in the MW-18A area, and (e) impacts below the 2L Standards have not been horizontally or vertically defined in the MW-1 9R/MW-1 9AR portion of the site. Groundwater Statistical Analysis Report Charlotte Motor Speedway, Landfill V, North Carolina 8 Latest Water Quality Assessment Activities In correspondence dated September 12, 2013 (DIN 19706), NCDEQ approved a site request to monitor wells MW-18R and MW-18AR on an annual basis due to lack of confirmed exceedances since installation in 2010. Therefore, wells MW-18R and MW-18AR are sampled during the first semi-annual event of each year. Table 6 summarizes the results of the Second Semi -Annual 2019 event at water quality assessment (extent) wells. The Second Semi -Annual 2019 event sampling results exhibited concentrations above the GWPS for cobalt at MW-19R. These results are generally consistent with historical data (since installation in 2010). Review of data for MW-19R indicated that cobalt has been previously above GWPSs in adjacent/upgradient wells MW-19A and/or MW-19. No organic GWPSs have been statistically exceeded at MW-19 or MW-19A since the Second Semi -Annual 2009 event, likely due to the enhancements to the GCCS in combination with natural attenuations. It is recommended that MW-19R and MW-19AR continue to be monitored on a semi-annual basis. TABLES TABLE 1 WELLS ANALYZED SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V UPGRADIENT WELLS DOWNGRADIENT WELLS MW-11, MW-14, MW-1A, MW-1 B, MW-2A, MW-213, MW-10, MW-10A, MW-12, MW-14B, MW-15 MW-16, MW-17, MW-17A, MW-18A, MW-19, MW-19A, MW-20AR, MW-20B, MW-21, MW-22, MW-22A, MW-24, MW-25, MW-26, MW-27, MW-28, MW-29R, MW-30R, MW-31, MW-32R, MW-33, MW-34 Wells MW-17, MW-17A, and MW-24 are sampled annually during the first semi-annual events each year. Wells MW-18R, MW-18AR, MW-19R, and MW-19AR are Water Quality Assessment Wells and addressed separately in Section 7.0 of the Report. Wells MW-18R and MW-18AR are sampled annually during the first semi-annual events each year, while MW-19R and MW-19AR are sampled semi-annually. TABLE 2 ORGANIC DETECTIONS SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Monitoring Point Parameter National Primary Drinking Water Standard-MCL (ug/L) 15A NCAC 2L Water Quality Standard (uglL) Results (ug/L) MDL (ug/L) PQL (ug/L) MW-18A 1,4-Dichlorobenzene 75 6 2.5 0.58 1 MW-19 1,4-Dichlorobenzene 75 6 2.6 0.58 1 MW-19A 1,4-Dichlorobenzene 75 6 2.2 0.58 1 MW-20B 1,4-Dichlorobenzene 75 6 3.4 0.58 1 MW-25 1,4-Dichlorobenzene 75 6 13.3 0.58 1 Chlorobenzene 100 50 12.4 0.53 3 MW-31 Benzene 5 1 1.4 0.20 1 Vinyl chloride 2 0.03 2.1 0.60 1 MW-32R Benzene 5 1 6.7 0.20 1 Vinyl chloride 2 0.03 2.1 0.60 1 MW-33 1,2-Dichloroethane 5 0.4 1.5 0.67 1 Benzene 5 1 3.7 0.20 1 Trichloroethene 5 3 1.2 0.34 1 Vinyl chloride 2 0.03 2.5 0.60 1 1,2-Dichloroethane 5 0.4 4.1 0.67 1 1,4-Dichlorobenzene 75 6 2.7 0.58 1 MW-34 Benzene 5 1 5.6 0.20 1 cis- 1,2-Dichloroethene 70 70 12.5 0.66 5 Trichloroethene 5 3 1.2 0.34 1 Detections listed are for concentrations reported at or above the laboratory Practical Quantitation Limit (PQL) 2L Standards updated by NCDEQ on 10/10/18. Value exceed the applicable 2L Standard. TABLE3A COMPARISONS TO GWPSs (INORGANICS) SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Constituent u /L MDL PQL MCL NC 2L Std NC IMAC Final GWPS MW-1A MW-1 B MW-2A MW-213 MW-10 MW-10A MW-11 MW-12 MW-14 MW-14B MW-15 MW-16 MW-17 MW-17A MW-18A MW-19 Antimony Total 0.27 6 6 NE 1 6** <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 <6 NS NS <6 <6 Arsenic Total 0.35 10 10 10 NE 10 0.46 JB <10 <10 <10 1.2 JB 1.4 JB 1.2 JB 1.5 JB <10 0.57 JB 1.4 JB 1.6 JB NS NS 1.5 JB <10 Barium Total 0.49 100 2,000 700 NE 700 136 6.3 J 182 58.7 J 35.4 J 28.9 J 32.4 J 18.6 J 9.0 J 6.6 J 37.3 J 59.5 J NS NS 718 372 Beryllium Total 0.074 1 4 NE 4 4 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS <1 <1 Cadmium Total 0.11 1 5 2 NE 2 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS 0.49 J <1 Chromium Total 0.39 10 100 10 NE 98** 4.8 JB 0.52 JB 0.72 JB 0.81 JB 2.5 JB 1.9 JB 4.0 JB 9.5 J 1.3 JB 0.5 JB 1.8 JB 6.2 JB NS NS 5 JB <10 Cobalt Total 0.3 10 NE NE 1 12** 7.7 J 1.7 J 0.47 J 13.3 0.56 J <10 1.1 J 0.73 J 0.5 J <10 <10 10.8 NS NS 18.6 2.2 J Copper Total 0.19 10 1,300 1,000 NE 1,000 6.6 J 1.9 J 1.1 J 0.46 J 0.39 J 0.5 J 1.3 J 0.46 J 2.6 J 0.91 J 1.9 J 4.3 J NS NS 11 1.1 J Lead Total 0.046 10 15 15 NE 15 0.66 J 0.054 J <10 <10 0.064 J <10 <10 <10 <10 <10 <10 2.3 J NS NS 0.11 J <10 Mercury Total 0.14 0.2 2 1 NE 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NS NS <0.2 <0.2 Nickel Total 0.31 50 NE 100 NE 100 8.8 J 25.5 J 9.9 J 19.9 J 2.1 J 1.3 J 3.1 J 12.9 J 23.5 J 1.4 J 4.5 J 6.7 J NS NS 12.1 J 75.4 Selenium Total 1.3 10 50 20 NE 20 <10 <10 <10 <10 <10 <10 <10 <10 <10 1.3 J <10 <10 NS NS <10 <10 Silver Total 0.28 10 NE 20 NE 20 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 NS NS <10 <10 Thallium Total 0.052 5.5 2 NE 0.28 5.5** <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 NS NS <5.5 <5.5 Vanadium Total 0.71 25 NE NE 0.3 33** 3.4 JB 2.0 JB 3.7 JB <25 4.2 JB 5.6 JB 6.8 JB 8.2 JB 5.2 JB 5.8 JB 11 JB 17.9 J NS NS <25 <25 Zinc Total 1.5 10 NE 1,000 NE 1,000 12.1 B 9.0 JB 6.0 JB 5.8 JB 8.5 JB 9.9 JB 6.8 JB 15.2 B 10.5 B 7.4 JB 6.5 JB 22.1 B NS NS 42.6 B 5.9 JB Field Dissolved Oxygen u /L NE NE NE NE NE NE 1.74 1.84 6.73 7.90 1.71 1.07 6.30 7.71 6.81 8.01 5.34 7.85 NS NS 5.89 6.81 Field pH (SU) NE NE NE NE NE NE 6.47 6.43 6.09 6.10 5.33 6.12 6.46 6.34 6.43 6.61 6.62 6.56 NS NS 5.94 6.29 Field Specific Conductance (umhos/cm) NE NE NE NE NE NE 973 711 1189 988 116 229 564 433 663 654 444 680 NS NS 1845 1197 Field Temperature (°C) NE NE NE NE NE NE 18.2 16.6 19.5 17.5 16.4 17.4 20.4 17.8 19.4 17.3 22.7 17.6 NS NS 21.2 19.0 Field Turbidity (NTU) NE NE NE NE NE NE 7.16 3.27 2.01 2.74 6.70 2.17 3.41 2.30 0.72 0.79 0.95 5.10 NS NS 1.60 1.45 Constituent (ug/L) MDL PQL MCL NC 2L Std NC IMAC Final GWPS MW-19A MW-20AR MW-20B MW-21 MW-22 MW-22A MW-24 MW-25 MW-26 MW-27 MW-28 MW-29R MW-30R MW-31 MW-32R MW-33 MW-34 Antimony Total 0.27 6 6 NE 1 6** <6 <6 0.3 J 0.32 J <6 <6 NS <6 <6 <6 <6 <6 <6 0.43 J <6 <6 <6 Arsenic Total 0.35 10 10 10 NE 10 0.46 J <10 <10 0.59 J <10 <10 NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Barium Total 0.49 100 2,000 700 NE 700 215 317 936 79.5 J 343 65.2 J NS 112 148 54.9 J 83.1 J 37.4 J 111 157 141 119 198 Beryllium Total 0.074 1 4 NE 4 4 <1 <1 <1 0.15 J <1 <1 NS <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 Cadmium Total 0.11 1 5 2 NE 2 <1 <1 1.3 0.13 J <1 1.7 NS 0.21 J <1 <1 <1 <1 <1 <1 <1 0.28 J <1 Chromium Total 0.39 10 100 10 NE 98** <10 <10 1.0 J 14.5 6.1 J 1.2 J NS 0.87 J 4.5 J 4.9 J 13.5 2.8 J 2.8 J <10 8.5 J 1.5 J 3.5 J Cobalt Total 0.3 10 NE NE 1 12"* 9.3 J 2.4 J 7.8 J 833 189 21 NS 5.7 J 19.7 1.0 J <10 0.75 J 0.76 J 9.8 J 23.3 6.8 J 1.3 J Copper Total 0.19 10 1,300 1,000 NE 1,000 0.98 J 0.96 J 5.9 J 92.8 6.3 J 6.2 J NS 0.48 J 0.92 J 13.5 0.39 J 3.9 J 2.2 J 0.47 J 11.2 11.5 19.7 Lead Total 0.046 10 15 15 NE 15 0.049 J <10 1.4 J 2.2 J 0.14 J <10 NS <10 <10 0.47 J 0.054 J 0.05 J 0.092 J 0.32 J 27.3 0.5 J 0.23 J Mercury Total 0.14 0.2 2 1 NE 1 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 NS <0.2 0.45 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 <0.2 Nickel Total 0.31 50 NE 100 NE 100 30.3 J 38.7 J 41.6 J 57 22.9 J 123 NS 23.6 J 15.1 J 6.8 J 22 J 4.3 J 14.8 J 9.9 J 44.1 J 3.1 J 5.1 J Selenium Total 1.3 10 50 20 NE 20 <10 <10 <10 <10 <10 <10 NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Silver Total 0.28 10 NE 20 NE 20 <10 <10 <10 <10 <10 <10 NS <10 <10 <10 <10 <10 <10 <10 <10 <10 <10 Thallium Total 0.052 5.5 2 NE 0.28 5.5** 0.06 J <5.5 0.054 J <5.5 <5.5 <5.5 NS <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 <5.5 Vanadium Total 0.71 25 NE NE 0.3 33** <25 <25 <25 18.1 J <25 <25 NS 1.0 J 3.7 J 5.2 J <25 2.8 J 5.1 J <25 2.8 J 1.1 J 1.1 J Zinc Total 1.5 10 NE 1,000 NE 1,000 76.9 19.7 B 47.4 42.5 B 8.4 JB 13.1 B NS 7.5 JB 6.1 JB 15 B 5.7 JB 6.1 JB 23.9 B 10.3 B 7.5 JB 13.8 B 17.1 B Field Dissolved Oxygen (ug/L) NE NE NE NE NE NE 6.66 1.22 1.42 3.29 5.43 6.20 NS 5.13 6.18 2.14 1.80 1.44 1.59 1.47 1.98 1.41 1.67 Field pH (SU) NE NE NE NE NE NE 6.97 6.08 5.94 5.98 6.55 6.32 NS 6.16 6.35 6.42 6.33 6.03 5.57 5.61 6.00 5.32 5.27 Field Specific Conductance (umhos/cm) NE NE NE NE NE NE 1049 841 1124 345 2208 2066 NS 1324 881 252 549 309 272 471 599 326 322 Field Temperature (°C) NE NE NE NE NE NE 19.1 17.7 17.9 17.7 21.4 20.6 NS 23.2 20.6 19.1 21.2 17.2 15.7 16.3 18.3 17.0 16.6 Field Turbidity (NTU) NE NE NE NE NE NE 1.51 3.92 0.13 39.00 4.01 1.16 NS 1.32 5.41 15.00 1.40 5.50 2.68 1.13 2.47 4.29 5.84 J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. B: Denotes parameter also detected in the associated equipment blank, field blank, trip blank, or laboratory method blank. Final GWPS is the lowest of the MCL, NC 2L Standard, and NC Interim Maximum Allowable Concentration (IMAC) values. **: Denotes background limit or PQL used if higher than NC 2L Standard and NC IMAC. Denotes a concentration at or above a PQL is also above the Final GWPS: NS: Denotes not required to be sampled this event. Wells MW-17, MW-17A, and MW-24 are sampled annually during the first semi-annual events each year. TABLE3B COMPARISONS TO GWPSs (ORGANICS) SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Constituent (ug/L) MDL PQL MCL NC 2L Std NC IMAC Final GWPS MW-1A MW-1B MW-2A MW-2B MW-10 MW-10A MW-11 MW-12 MW-14 MW-14B MW-15 MW-16 MW-17 MW-17A MW-18A MW-19 MW-19A 1,1-Dichloroethane 0.41 5 NE 6 NE 6 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 NS NS <5 <5 <5 1,2-Dichloroethane 0.67 1 5 0.4 NE 1** <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS <1 <1 <1 1,2-Dichloro ro ane 0.6 1 5 0.6 NE 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS <1 <1 <1 1,4-Dichlorobenzene 0.58 1 75 6 NE 6 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS 2.5 2.6 2.2 2-Butanone MEK 3.2 1 100 NE 4000 NE 4000 <100 <100 I <100 <100 <100 I <100 <100 <100 I <100 <100 <100 I <100 NS NS <100 <100 <100 Acetone 8.2 100 NE 6000 NE 1 6000 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 NS NS I <100 <100 <100 Benzene 0.2 1 5 1 NE 1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS 0.83 J <1 <1 Carbon Disulfide 0.79 100 NE 700 NE 700 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 <100 NS NS <100 <100 <100 Chlorobenzene 0.53 3 100 50 NE 50 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 <3 NS NS 1.6 J 1.5 J 1.0 J cis- 1,2-Dichloroethene 0.66 5 70 70 NE 70 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 <5 NS NS <5 <5 <5 Methylene Chloride 0.5 1 1 5 1 5 NE 5 <1 <1 I <1 <1 <1 <1 <1 <1 I <1 <1 <1 I <1 NS NS <1 <1 <1 Tetrachloroethene 1 5 0.7 NE 1** <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS <1 <1 <1 trans-1,2-Dichloroethene 5 100 100 NE 100 <5Trichloroethene LOA 1 5 3 NE 3Vin I Chloride 1 2 0.03 NE 1** <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 <1 NS NS <1 <1 <1 Constituent (ug/L) MDL PQL MCL NC 2L Std NC IMAC Final GWPS MW-20AR MW-20B MW-21 MW-22 MW-22A MW-24 MW-25 MW-26 MW-27 MW-28 MW-29R MW-30R MW-31 MW-32R MW-33 MW-34 1,1-Dichloroethane 0.41 5 NE 6 NE 6 <5 2.1 J <5 <5 <5 NS <5 <5 <5 <5 <5 <5 <5 <5 1.2 J 1.3 J 1,2-Dichloroethane 0.67 1 5 0.4 NE 1** <1 <1 <1 <1 <1 NS <1 <1 <1 <1 <1 <1 <1 <1 1.5 4.1 1,2-Dichloro ro ane 0.6 1 5 0.6 NE 1 <1 <1 <1 <1 <1 NS <1 <1 <1 <1 <1 <1 <1 <1 <1 0.89 J 1,4-Dichlorobenzene 0.58 1 75 6 NE 6 <1 3.4 <1 <1 0.76 J NS 13.3 0.78 J <1 <1 <1 <1 <1 <1 <1 2.7 2-Butanone MEK 3.2 1 100 NE 4000 NE 4000 <100 <100 I <100 <100 <100 I NS <100 <100 I <100 <100 <100 I <100 <100 19.7 J <100 <100 Acetone 8.2 100 NE 6000 NE 6000 <100 <100 <100 <100 <100 NS <100 <100 <100 <100 <100 <100 I <100 <100 <100 I <100 Benzene 0.2 1 5 1 NE 1 <1 <1 <1 <1 <1 NS 0.34 J 0.27 J <1 <1 <1 <1 1.4 6.7 3.7 5.6 Carbon Disulfide 0.79 100 NE 700 NE 700 <100 <100 <100 <100 <100 NS <100 <100 <100 <100 <100 <100 <100 1.4 J <100 <100 Chlorobenzene 0.53 3 100 50 NE 50 <3 1.5 J <3 <3 <3 NS 12.4 0.68 J <3 <3 <3 <3 <3 <3 <3 0.97 J cis- 1,2-Dichloroethene 0.66 5 70 70 NE 70 <5 2.9 J <5 <5 <5 NS 0.91 J <5 <5 <5 <5 <5 <5 4.0 J 3.2 J 12.5 Methylene Chloride 0.5 1 5 5 NE 5 <1 I <1 <1 <1 <1 NS <1 <1 I <1 <1 <1 <1 <1 <1 0.69 J <1 Tetrachloroethene 0.78 1 5 0.7 NE 1** <1 <1 <1 <1 <1 NS <1 <1 <1 <1 <1 <1 <1 <1 <1 0.97 J trans-1,2-Dichloroethene 0.46 5 100 100 NE 100 <5 <5 <5 <5 <5 NS <5 <5 <5 <5 <5 <5 <5 <5 0.68 J 0.88 J Trichloroethene 0.34 1 5 3 NE 3 <1 <1 <1 <1 <1 NS <1 <1 <1 <1 <1 <1 <1 0.61 J 1.2 1.2 Vinyl Chloride 0.6 1 1 2 0.03 1 NE 1** <1 <1 <1 <1 <1 NS <1 <1 <1 <1 I <1 <1 2.1 1 2.1 2.5 0.99 J J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Final GWPS is the lowest of the MCL, NC 2L Standard, and NC Interim Maximum Allowable Concentration (IMAC) values. *: Denotes background limit or PQL used if higher than NC 2L Standard and NC IMAC. Denotes a concentration at or above a PQL is also above the Final GWPS: Only the VOCs reported above an MDL this event are summarized on the table. NS: Denotes not required to be sampled this event. Wells MW-17, MW-17A, and MW-24 are sampled annually during the first semi-annual events each year. TABLE 4 SURFACE WATER DATA COMPARED TO NC 2B STANDARDS SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Constituent Units NC 2B Standard MDL PQL SW-1 SW-2 Antimony Total u /L NE 0.27 6 0.33 J 0.55 J Arsenic Total u /L 10 0.35 10 1.7 JB 1.4 JB Barium Total u /L 1,000 0.49 100 44.5 J 25.1 J Beryllium Total u /L 6.5 0.074 1 0.084 J <1 Cadmium Total u /L 2 0.11 1 <1 <1 Chromium Total u /L 20 0.39 10 2.0 J 0.63 J Cobalt Total u /L NE 0.3 10 1.7 J 0.54 J Copper Total u /L 3 0.19 10 6.7 J 3.1 J Lead Total u /L 25 0.046 10 1.0 J 0.17 J Mercury Total u /L 0.012 0.14 0.2 <0.2 <0.2 Nickel Total u /L 8.3 0.31 50 1.6 J 1.9 J Selenium Total u /L 5 1.3 10 <10 <10 Silver Total u /L 0.06 0.28 10 <10 <10 Thallium Total u /L NE 0.052 5.5 <5.5 <5.5 Vanadium Total u /L NE 0.71 25 12.2 J 8.4 J Zinc Total u /L 50 1.5 10 121 8.7 JB Field Dissolved Oxygen u /L NE n/a n/a 9.18 6.20 Field pH SU NE n/a n/a 8.01 6.11 Field Specific Conductance umhos/cm NE n/a n/a 213 158 Field Temperature °C NE n/a n/a 14.4 13.5 Field Turbidity NTU NE n/a n/a 18.00 4.75 8: Denotes parameter also detected in the associated field blank, trip blank, or laboratory method blank. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. For NC 2B Standard, lowest value utilized from the classifications from the 2B Table published May 15, 2013. Denotes a concentration at or above a PQL is also above the NC 2B Standard No VOCs were detected in the Surface Water Samples TABLE 5 INTER -WELL PREDICTION LIMIT EXCEEDANCES SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Well Parameter (Total Metals MDL PQL MCL NC 2L NC IMAC Final GWPS Results Prediction Limit MW-2B Cobalt 0.30 10 NE NE 1 12** 13.3 12 MW-18A Barium 0.49 100 2,000 700 NE 700 718 380 Cobalt 0.30 10 NE NE 1 12** 18.6 12 MW-20B Barium 0.49 100 2,000 700 NE 700 936 380 MW-21 Cobalt 0.30 10 NE NE 1 12** 833 12 MW-22 Cobalt 0.30 10 NE NE 1 12** 189 12 MW-22A Cobalt 0.30 10 NE NE 1 12** 21 12 Nickel 0.31 50 NE 100 NE 100 123 43 MW-26 Cobalt 0.30 10 NE NE 1 12** 19.7 12 MW-32R Cobalt 1 0.30 1 10 NE NE 1 12** 23.3 12 Lead 1 0.046 1 10 15 15 NE 15 27.3 15 All units are in ug/L Final GWPS is the lowest of the MCL, NC 2L Standard, and NC Interim Maximum Allowable Concentration (IMAC) values. **: Denotes background limit or PQL used if higher than MCL, NC 2L, and NC IMAC. TABLE 6 WATER QUALITY ASSESSMENT WELL DATA COMPARED TO GWPSs SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Constituent (ug/L) MDL PQL MCL NC 2L Std NC GWPS Final GWPS MW-18AR MW-18R MW-19AR MW-19R Antimony Total 0.27 6 6 NE 1 6** NS NS 0.53 J <6 Arsenic Total 0.35 10 10 10 NE 10 NS NS 0.4 J <10 Barium Total 0.49 100 2,000 700 NE 700 NS NS 189 450 Beryllium Total 0.074 1 4 NE 4 4 NS NS <1 <1 Cadmium Total 0.11 1 5 2 NE 2 NS NS 0.52 J 0.36 J Chromium Total 0.39 10 100 10 NE 98** NS NS 7.8 J 0.7 J Cobalt Total 0.3 10 NE NE 1 12** NS NS 12 14.3 Copper Total 0.19 10 1,300 1,000 NE 1,000 NS NS 7.9 J 5.8 J Cyanide Total 10 10 200 70 NE 70 NS NS NS NS Lead Total 0.046 10 15 15 NE 15 NS NS 0.2 J 0.072 J Mercury Total 0.14 0.2 2 1 NE 1 NS NS <0.2 <0.2 Nickel Total 0.31 50 NE 100 NE 100 NS NS 26 J 20.3 J Selenium Total 1.3 10 50 20 NE 20 NS NS <10 <10 Silver Total 0.28 10 NE 20 NE 20 NS NS 0.93 J <10 Sulfide 1000 1000 NE NE NE NE NS NS NS NS Thallium Total 0.052 5.5 2 NE 0.28 5.5** NS NS <5.5 <5.5 Tin Total 7 20 NE NE 2,000 2,000 NS NS NS NS Vanadium Total 0.71 25 NE NE 0.3 19** NS NS <25 <25 Zinc Total 1.5 10 NE 1,000 NE 1,000 NS NS 21.2 B 12.4 B Field Dissolved Oxygen (ug/L) NE NE NE NE NE NE NS NS 6.51 7.73 Field pH SU NE NE NE NE NE NE NS NS 6.43 6.17 Field Specific Conductance (umhos/cm) NE NE NE NE NE NE NS NS 1692 1457 Field Temperature °C NE NE NE NE NE NE NS NS 20 17.7 Field Turbidity (NTU) NE NE NE NE NE NE NS NS 3.41 2.89 Constituent (ug/L) MDL PQL MCL NC 2L Std NC GWPS Final GWPS MW-18AR MW-18R MW-19AR MW-19R 1,1-Dichloroethane 0.41 5 NE 6 NE 6 NS NS <5 <5 1,2-Dichloroethane 0.67 1 5 0.4 NE 1** NS NS <1 <1 1,2-Dichloro ro ane 0.6 1 5 0.6 NE 1 NS NS <1 <1 1,4-Dichlorobenzene 0.58 1 75 6 NE 6 NS NS 2.9 2.5 2-Butanone MEK 3.2 100 NE 4000 NE 4000 NS NS <100 <100 Acetone 8.2 100 NE 6000 NE 6000 NS NS 9.5 J <100 Benzene 0.2 1 5 1 NE 1 NS NS <1 <1 Carbon Disulfide 0.79 100 NE 700 NE 700 NS NS <100 <100 Chlorobenzene 0.53 3 100 50 NE 50 NS NS 0.99 J 0.89 J cis- 1,2-Dichloroethene 0.66 5 70 70 NE 70 NS NS <5 <5 Methylene Chloride 0.5 1 5 5 NE 5 NS NS <1 <1 Tetrachloroethene 0.78 1 5 0.7 NE 1** NS NS <1 <1 trans-1,2-Dichloroethene 0.46 5 100 100 NE 100 NS NS <5 <5 Trichloroethene 0.34 1 5 3 NE 3 NS NS <1 <1 Vinyl Chloride 0.6 1 2 0.03 NE 1** NS NS <1 <1 8: Denotes parameter also detected in the associated equipment blank, field blank, trip blank, or laboratory method blank. J: Denotes Sample result above the MDL but below the PQL; estimated value; value may not be accurate. Final GWPS is the lowest of the MCL, NC 2L Standard, and NC Interim Maximum Allowable Concentration (IMAC) values. **: Denotes background limit or PQL used if higher than NC 2L Standard and NC IMAC. Denotes a concentration at or above a PQL is also above the Final GWPS: NS: Denotes not required to be sampled this event. Wells MW-18R and MW-18AR are sampled annually during the first semi-annual events each year. APPENDICES APPENDIX A POTENTIOMETRIC SURFACE MAP Q SW-1 9 / I I o ` \MW-10 555.60 MW-\ 555.82 �5\ 2 LEGEND SMW-22 Shallow Monitoring Well Location MW-22A Deep Monitoring Well Location 579.03 Groundwater Elevation (fmsl) — 0 _ 565 — Potentiometric Surface Contour (fmsl) J 581 95 ` \ \ =0.023 Groundwater Flow Directiond 581.95 / h J &SW-1 Surface Water Sampling Location (Approx) Landfill Cell Boundary — — Expansion Areas I I Denotes Assessment Monitoring \ Program Well I \ 1 \\ .. Denotes Water Quality Assessment (Extent) Well I r MW-1A CLOSED — water levels collected by Pace Analytical services, LLC on 569:33 MW-11 569.32 MW-1B CELL 1A — O I October 14, 2019. I 628.77 Photography provided Cooper Aerial surveys Co., date of 11 t� Photograa phy is January 27, 2013. I �? ✓ _ o�lF1 I , I I \ CLOSED \� CELL 113 \\\ EXISTIN 0 250 500 1000 CEL\ ® / PHAL 2 0 MW-2A �� MW-14 \ 570.41 \ , � � 618.94 Scale in Feet Graphic Scale: 1 inch = 500 feet MW-213 \ 0p23 i� IM 413 570.23� \\ , EXIST61�0 \ < I��o. CELL 2s PHASE 1 G MW-25* \ i MW-22A \ � 579.12 , \ MW-22 I \ i \ 579.03 1 / \ 1 sus I EXI ING i 1 CEL B s� PHAS 1 MW-21 S , MW-15 566.97 AI/ o^� S609.84 si, 1\ i� \� E STI ✓ 1 ASE 1 J MW-20B ✓7 576.87 In l \ S9s \ V � MW-20AR \ 7 V 574.48 1 \ 1 \ n \ 1 �/ \S ISTING ELL 2D HA 2 1 -16 PHASE 1 �� 590 45 \ I MW-19* jl 55845 560.271 I 1 MW-19A* 1 1I 560.I30 \ MW-19AR** f EXISTING \ 557.56 MW-19R** / CELL 2F ,\ 577.96* HASE 2 \ / MW-17* MW-17A* v / 556.39 557.09 � A\ �1� �• 564.11 I \ W-2 MW-18R** EXIST 3\ 569.91 MW-18AR** 559.88 MW-34* CELL 2 \ 556.37� J 547.61 \ PHASE \ 1 MW-33 . 547.64 i EXI NG \ CEL H v PHA2 \ a; r \ �� �MW-32R* I 564.45 I 1 „ — lvlW-28F 560.9393 d, \ MW\\` 566.97 / 1 1 EXISTING i CELL 21 / PHASE 3 i o MW-30R 1 559.311 �• / i� ___ �MW-29R` D — — — 557.75 , (r e ( n �! ETT Figure 1 1002 Morgan Meadow46i 4 Second Semi -Annual 2019 Potentiometric Surface Map Wentzville, MO 63385 EN�VIRONMENTIAL www.jettenviro.com Charlotte Motor Speedway Landfill V, Harrisburg, North Carolina Groundwater Elevation Summary Table Charlotte Motor Speedway, Landfill V Well Top of PVC Casing Elevation (fmsl)' Depth to 2 Water (ft) Groundwater Elevation (fmsl) Shallow Wells MW-1A 579.45 10.13 569.32 MW-2A 579.92 9.51 570.41 MW-10 578.10 22.50 555.60 MW-11 638.82 10.05 628.77 MW-12 596.69 14.74 581.95 MW-14 629.56 10.62 618.94 MW-15 620.60 10.76 609.84 MW-16 606.53 16.08 590.45 MW-17 569.88 13.49 556.39 MW-18A 581.81 17.70 564.11 MW-18R 580.02 20.14 559.88 MW-19 588.58 28.31 560.27 MW-19R 582.53 23.27 559.26 MW-20AR 585.28 10.80 574.48 MW-21 581.99 15.02 566.97 MW-22 586.21 7.18 579.03 MW-24 576.00 17.55 558.45 MW-25 589.07 8.12 580.95 MW-26 594.86 16.90 577.96 MW-27 581.32 11.41 569.91 MW-28 574.45 13.52 560.93 MW-29R 565.61 7.86 557.75 MW-30R 587.84 28.53 559.31 MW-31 592.26 25.29 566.97 MW-32R 587.80 23.35 564.45 MW-33 575.70 28.06 547.64 MW-34 577.71 30.10 547.61 Deep Wells MW-1 B 580.74 11.41 569.33 MW-213 579.92 9.69 570.23 MW-10A 578.67 22.85 555.82 MW-14B 629.82 10.72 619.10 MW-17A 570.12 13.03 557.09 MW-18AR 579.93 23.56 556.37 MW-19A 588.07 27.77 560.30 MW-19AR 582.83 25.27 557.56 MW-20B 583.57 6.70 576.87 MW-22A 586.13 7.01 579.12 Note 1: Top of PVC Casing Elevations from the December 1, 2000 Correspondence from S&ME, Inc. to the site regarding the October 2000 groundwater flow data. Top of PVC Casing Elevations for wells MW-16, MW-26 through MW-34 from survey information provided by Earnhardt Grading in correspondence dated June 19, 2008. Top of PVC Casing Elevations for wells MW-18R, MW-18AR, MW-19R, MW-19AR, MW-29R, MW-30R, and MW-32R from survey information provided by David Garrett & Associates in correspondence dated December 6, 2010. Note 2: Depth to water collected by Pace Analytical Services, LLC on October 14, 2019 Groundwater Flow Velocity Calculations Charlotte Motor Speedway, Landfill V Second Semi -Annual 2019 Event Velocitv Ranae For wells in Saprolite V = [(k)(i)]/(n) V = [(1 x 10-3 cm/sec)(0.021)]/0.16 V = 1.31 x 10-4 cm/sec V = 0.37 ft/day V = 135 ft/year For wells in PWR V = [(k)(i)]/(n) V = [(2 x 10-4 cm/sec)(0.021)]/0.20 V = 2.1 x 10-1 cm/sec V = 0.060 ft/day V = 22 ft/year For wells in Bedrock V = [(k)(i)]/(n) V = [(7 x 10-5 cm/sec)(0.021)]/0.07 V = 2.1 x 10-1 cm/sec V = 0.060 ft/day V = 22 ft/year Hydraulic conductivities (k) are from the geometric mean of the hydraulic conductivity for each unit monitored at the site. Hydraulic conductivities provided in "Groundwater Certification Document, CMS Landfill V" by S&ME, Inc. dated October 4, 1994. Effective porosities (n) are from the geometric mean of the effective porosities for each unit monitored at the site. Effective porosities provided in "Groundwater Certification Document, CMS Landfill W by S&ME, Inc. dated October 4, 1994. Conversion factor. ft/day = 2,835 x cm/sec. Gradient (i) is from the average gradient at site using the potentiometric surface map across the northern portion of the site and the southern portion of the site. Gradient (i) = Change in Groundwater Elevation along Flow Path inortn: = 50 ft / 2,210 ft = 0.023 isourn: = 50 ft / 2,662 ft = 0.019 Average gradient across the site is (0.023 + 0.019) / 2 = 0.021 WELL CONSTRUCTION SUMMARY SECOND SEMI-ANNUAL 2019 EVENT CHARLOTTE MOTOR SPEEDWAY, LANDFILL V Phase Well Northing Easting Ground Surface Elevation Top of Casing Elevation Casing Stickup Total Depth Elevation of Bottom of Boring Depth to Partially Weathered Rock Elevation of Partially Weathered Rock Depth to Rock Elevation of Rock Depth to Top of Screen Top of Screen Elevation Depth to Bottom of Screen Bottom of Screen Elevation Screen Thickness Litho. Unit Hydro. Unit Comments ft. Mel ft. msl ft. ft. b s ft. msl ft. b s ft. msl ft. b s ft. msl ft. b s ft. msl ft. b s ft. msl ft. 1 MW-1A 589012.548 1502604.566 576.45 579.45 3 17 559.45 NA NA NA NA 6.5 569.95 16.5 559.95 10 "Gneiss" Soil Likely Diorite 1 MW-1B 589012.548 1502604.566 578.24 580.74 2.5 32 546.24 24 554.24 29 549.24 25.5 552.74 31.5 546.74 5 "Gneiss" Bedrock Likely Diorite 1 MW-2A 587925.997 1502545.587 577.67 579.92 2.25 17 560.67 NA NA NA NA 4.5 573.17 16.5 561.17 2.5 Diorite*** Soil 1 MW-2B 587912.904 1502534.016 576.92 579.92 3 37 539.92 26 550.92 30 546.92 26 550.92 36 540.92 10 Diorite*** Bedrock 5 MW-10 587262.857 1501693.493 575.90 578.10 2.2 25 550.90 NA NA NA NA 9.5 566.40 24.5 551.40 15 Diorite*** Soil 5 MW-10A* 587262.857 1501693.493 576.17 578.67 2.5 43 533.17 NA NA 32.5 543.67 32.5 543.67 42.5 533.67 10 Diorite*** Bedrock 1 MINA 1 588977.331 1504541.502 636.62 638.82 2.2 22 614.62 NA NA NA NA 6.5 630.12 21.5 615.12 15 Diorite*** Soil 1 MW-12 589652.175 1502979.749 594.49 596.69 2.2 26 568.49 NA NA NA NA 10 584.49 25 569.49 15 Diorite*** Soil 1 MW-14 587899.549 1504980.859 627.54 629.56 2.02 15 612.54 1 626.54 12.8 614.74 5 622.54 15 612.54 10 Diorite*** PWR 1 MW-14B 587850.011 1505064.753 627.56 629.82 2.26 50 577.56 1 626.56 12.8 614.76 40 587.56 50 577.56 10 Diorite*** Bedrock 1 MW-15* 586871.0366 1505415.301 618.10 620.60 2.5 9.5 608.60 NA NA 9.5 608.60 4 614.10 9 609.10 5 Diorite*** Soil 2 MW-16**** 585653.703 1505654.468 604.03 606.53 2.5 27 577.03 23.5 580.53 NA NA 12 592.03 27 577.03 15 Diorite Soil/PWR 4 MW-17* 584792.54 1504230.802 566.88 569.88 3 25 541.88 NA NA 25 541.88 15 551.88 25 541.88 10 Syenite Soil/PWR Assumed rock depth 4 MW-17A* 584792.54 1504230.802 567.12 570.12 3 40 527.12 NA NA 25 527.12 30 537.12 40 527.12 10 Syenite Bedrock Assumed rock depth 1 MW-18A* 584658.688 1503258.693 579.31 581.81 2.5 26 553.31 NA NA 26 553.31 11 568.31 26 553.31 15 Syenite*** PWR Assumed rock depth 1 MW-19* 585155.848 1503186.087 586.08 588.58 2.5 53 533.08 NA NA 53 533.08 25 561.08 40 546.08 15 Diorite*** PWR Assumed rock depth 1 MW-19A* 585155.848 1503186.087 586.17 588.07 1.9 71 515.17 NA NA 53 533.17 61 525.17 71 515.17 10 Diorite*** Bedrock Assumed rock depth 1 MW-20AR 586092.717 1503211.489 582.78 585.28 2.5 19.7 563.08 NA NA 9 573.78 8.3 574.48 18.3 564.48 10 Diorite*** Soil 1 MW-20B 586092.717 1503211.489 581.43 583.57 2.14 60 521.43 NA NA 11 570.43 45 536.43 60 521.43 15 Diorite*** Soil 1 MW-21 586674.371 1502868.591 579.43 581.99 2.56 20 559.43 7 572.43 20 559.43 10 569.43 20 559.43 10 Diorite*** PWR 1 MW-22 587314.247 1502996.856 583.71 586.21 2.5 13 570.71 NA NA 13 570.71 2.5 581.21 12.5 571.21 10 Diorite Soil 1 MW-22A c 587314.247 1502996.856 583.53 586.13 2.6 26 557.53 NA NA 15.5 568.03 21 562.53 26 557.53 5 Diorite Bedrock 4 MW-24* 585310.927 1504239.235 574.50 576.00 1.5 30 544.50 NA NA 30 544.50 20 554.50 30 544.50 10 Syenite Soil/PWR Assumed rock depth 1 MW-25 587428.551 1502970.342 589.00 589.00 0 20.8 568.20 7 582.00 20.8 568.20 10.8 578.20 20.8 568.20 10 Diorite*** PWR 2 MW-26**** 585074.598 1505960.33 592.36 594.86 2.5 20 572.36 NA NA NA NA 5 587.36 20 572.36 15 Diorite Soil/PWR 2 MW-27**** 584646.73 1506060.422 578.82 581.32 2.5 12.5 566.32 NA NA NA NA 2.5 576.32 12.5 566.32 10 Diorite Soil 2 MW-28**** 583886.994 1506289.934 571.95 574.45 2.5 23 548.95 9 562.95 NA NA 8 563.95 20 551.95 12 Diorite Soil/PWR 3 MW-29R 583153.3 1506273.4 563.27 565.61 2.34 22.7 540.57 11 552.27 NA NA 5 558.28 20 543.27 15 Diorite Soil/PWR Assumed Diorite 3 MW-30R 583359.1 1504850.7 585.77 587.84 2.07 33.2 552.57 24.1 561.67 NA NA 1 18 567.77 33 552.77 15 Diorite Soil/PWR Assumed Diorite 2 MW-31**** 583669.983 1504988.978 589.76 592.26 2.5 30 559.76 12.5 577.26 NA NA 15 574.76 30 559.76 15 Diorite PWR 3 MW-32R 583967 1504900.4 585.36 587.80 2.44 28.5 556.86 13 572.36 NA NA 13.5 571.86 28.5 556.86 15 Diorite PWR Assumed Diorite 2 MW-33**** 584254.832 1504461.194 573.20 575.70 2.5 30.5 542.70 19.5 553.70 NA NA 15.5 557.70 30.5 542.70 15 Diorite Soil/PWR 2 MW-34**** 584444.191 1504280.597 575.21 577.71 2.5 30 545.21 16.5 558.71 NA NA 15 560.21 30 545.21 15 Syenite Soil/PWR Nature -Extent MW-18AR 584566.7 1503436.6 577.61 579.93 2.32 42.2 535.41 23 554.61 23.7 553.91 32.3 545.31 42.2 535.41 10 Diorite Bedrock Nature -Extent MW-18R 584568.2 1503441.5 577.60 580.02 2.42 24 553.60 23 552.60 NA NA 9 568.60 24 553.60 15 Diorite Soil/PWR Nature -Extent MW-19AR 585080.3 1503080.9 580.09 582.82 2.73 52.7 527.39 NA NA 36.4 543.69 41 539.09 51 529.09 10 Diorite Bedrock Nature -Extent MW-19R 585077.1 1503087.8 580.17 582.53 2.36 1 35 1 545.17 NA I NA NA NA 20 560.17 35 545.17 10 Diorite I Soil/PWR Notes: msl - mean sea level bgs - below ground surface NA - not applicable `No logs can be located; Depths and screen interval from well tags or tables; lithology based on field observations. **Screen intervals estimated based on conventional practice at the time of the earlier investigation and nearby boring records. Lithology assumed from soil description and/or field observation ****Ground elevation determined by subtracting 2.5 feet from surveyed well head data Boring numbers followed by "c" were cored. All information from this table is from Table 1 of the "Design Hydrogeologic Report, CMS Landfill V - Phase 3"prepared by David Garrett and Associates, dated May 2009 and approved by NCDENR on July 15, 2009, with the exception of wells MW-29R, MW-30R, MW-32R, MW-18AR, MW-18R, MW-19AR, and MW-19R from which the information was derived from the "Record of Monitoring Well Installations" dated January 13, 2011 by David Garrett 8 Associates. APPENDIX B STATISTICAL EVALUATIONS INTER -WELL PREDICTION LIMITS Prediction Limit Charlotte Motor Speedway Client: RSI Data: CMS Printed 11/22/2019, 7:18 AM Constituent Well Upper Lim. Lower Lim. Date Observ. S11c, Ba N Ba Mean Std. Dev. %NDs ND Ad. Barium Total (mg/L) MW-20B 0.38 nla 10/15/2019 0.936 Yes 209 n/a n/a 17.7 nla Barium Total (mg/L) MW-18A 0.38 nla 10/15/2019 0.718 Yes 209 n/a n/a 17.7 n/a Cobalt Total (ug/L) MW-213 12 nla 10/14/2019 13.3 Yes 196 n/a nla 62.24 nla Cobalt Total (ug/L) MW-21 12 n/a 10/17/2019 833 Yes 196 n/a nla 62.24 n/a Cobalt Total (ug/L) MW-22 12 nla 10/15/2019 189 Yes 196 n/a nla 62.24 n/a Cobalt Total (ug/L) MW-22A 12 nla 10/15/2019 21 Yes 196 n/a n/a 62.24 n/a Cobalt Total (ug/L) MW-18A 12 n/a 10/15/2019 18.6 Yes 196 n/a n/a 62.24 n/a Cobalt Total (ug/L) MW-26 12 n/a 10/17/2019 19.7 Yes 196 n/a n/a 62.24 n/a Cobalt Total (ug/L) MW-32R 12 n/a 10/15/2019 23.3 Yes 196 n/a n/a 62.24 n/a Lead Total (ug/L) MW-32R 15 n/a 10/15/2019 27.3 Yes 209 n/a n/a 89.47 n/a Nickel Total (ug/L) MW-22A 43 n/a 10/15/2019 123 Yes 201 n/a n/a 36.82 n/a Transform Aloha Method n/a 0.00004917 NP Inter (normality) 1 of 2 n/a 0.00004917 NP Inter (normality) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00005145 NP Inter (NDs) 1 of 2 n/a 0.00004917 NP Inter (NDs) 1 of 2 n/a 0.00004917 NP Inter (normality) 1 of 2 Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-20B, MW-18A 1 0.6 E 0.2 0 1 /23/96 Prediction Limit Interwell Non -parametric • 1 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B Limit = 0.38 Non -parametric test used in lieu of parametric prediction limit because the Chi Squared normality test showed the data to be non -normal at the 0.01 alpha level. Limit is highest of 209 background values. 17.7% NDs. Annual per - constituent alpha = 0.0007864. Individual comparison alpha = 0.00004917 (1 of 2). Comparing 2 points to limit. Assumes 6 future values. Outlier test was not run because sample size exceeded table. Constituent: Barium Total Analysis Run 11/22/2019 7:17 AM Charlotte Motor Speedway Client: RSI View: Interwell Prediction Limits Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-2B, MW-21, MW-22, MW-22A, MW-18A. MW-26. MW-32R Prediction Limit Interwell Non -parametric 2000 ♦ MW-2B 1600 ■ MW-21 • MW-22 1200 ♦ MW-22A 800 400 • MW-26 0 ■ MW-32R 11 /17/93 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 Limit = 12 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 196 background values. 62.24% NDs. Annual per -constituent alpha = 0.0008229. Individual comparison alpha = 0.00005145 (1 of 2). Comparing 7 points to limit. Assumes 1 future value. Outlier test was not run because sample size exceeded table. Constituent: Cobalt Total Analysis Run 11/22/2019 7:17 AM View: Interwell Prediction Limits Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Exceeds Limit: MW-32R Prediction Limit Interwell Non -parametric 40 32 24 16 8 0 11/15/10 8/27/12 6/9/14 3/21 /16 1 /1 /18 10/15/19 ■ MW-32R Limit = 15 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 209 background values. 89.47% NDs. Annual per -constituent alpha = 0.0007864. Individual comparison alpha = 0.00004917 (1 of 2). Assumes 7 future values. Outlier test was not run because sample size exceeded table. Constituent: Lead Total Analysis Run 11/22/2019 7:17 AM View: Interwell Prediction Limits Charlotte Motor Speedway Client: RSI Data: CMS 11/15/10 8/27/12 6/9/14 3/21 /16 1 /1 /18 10/15/19 ■ MW-32R Limit = 15 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 209 background values. 89.47% NDs. Annual per -constituent alpha = 0.0007864. Individual comparison alpha = 0.00004917 (1 of 2). Assumes 7 future values. Outlier test was not run because sample size exceeded table. Constituent: Lead Total Analysis Run 11/22/2019 7:17 AM View: Interwell Prediction Limits Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Exceeds Limit: MW-22A 200 160 120 M M Prediction Limit Interwell Non -parametric 0 I Tom^ i i i 1 /22/96 10/20/00 7/19/05 4/18/10 1 /15/15 10/15/19 ♦ MW-22A Limit = 43 Non -parametric test used in lieu of parametric prediction limit because the Chi Squared normality test showed the data to be non -normal at the 0.01 alpha level. Limit is highest of 201 background values. 36.82% NDs. Annual per - constituent alpha = 0.0007864. Individual comparison alpha = 0.00004917 (1 of 2). Assumes 7 future values. Outlier test was not run because sample size exceeded table. Constituent: Nickel Total Analysis Run 11/22/2019 7:17 AM Charlotte Motor Speedway Client: RSI View: Interwell Prediction Limits Data: CMS INTRA-WELL CONFIDENCE LIMITS Confidence Interval Charlotte Motor Speedway Client: RSI Data: CMS Printed 11/22/2019, 7:34 AM Constituent Well Upper Lim. Lower Lim. Compliance Sic. N %NDs Transform Alpha Method Barium Total (mg/L) MW-20B 1.037 -0.5257 0.7 No 4 0 x^6 0.01 Param. Barium Total (mg/L) MW-18A 0.8185 0.5375 0.7 No 4 0 No 0.01 Param. Cobalt Total (ug/L) MW-2B 15.57 8.845 12 No 4 25 In(x) 0.01 Param. Cobalt Total (ug/L) MW-21 2381 -615.2 12 No 4 0 No 0.01 Param. Cobalt Total (ug/L) MW-22 806.7 2.264 12 No 4 0 In(x) 0.01 Param. Cobalt Total (ug/L) MW-22A 24.54 20.1 12 Yes 4 0 In(x) 0.01 Param. Cobalt Total (ug/L) MW-18A 41.05 5.126 12 No 4 0 In(x) 0.01 Param. Cobalt Total (ug/L) MW-26 27.13 2.939 12 No 4 25 In(x) 0.01 Param. Cobalt Total (ug/L) MW-32R 147.3 10.49 12 No 4 0 In(x) 0.01 Param. Lead Total (ug/L) MW-32R 33.29 -20 15 No 4 0 x12 0.01 Param. Nickel Total (ug/L) MW-22A 130 115.1 100 Yes 4 0 x^6 0.01 Param. Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance Limit is not exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 2 1.4 0.2 J 0) E -0.4 -1 INN '>'& 9+'0Oe sr j�9 Constituent: Barium Total Analysis Run 11/22/2019 7:32 AM View: Confidence Intervals Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded.* Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 4000 91111I111 2000 1000 J 0 S[IIIII] ---limit = 12 Constituent: Cobalt Total Analysis Run 11/22/2019 7:32 AM View: Confidence Intervals Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance Limit is not exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 50 32 14 -4 J -22 -40 Limit = 15 Constituent: Lead Total Analysis Run 11/22/2019 7:32 AM View: Confidence Intervals Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance limit is exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 300 240 120 J 60 111 Constituent: Nickel Total Analysis Run 11/22/2019 7:32 AM View: Confidence Intervals Charlotte Motor Speedway Client: RSI Data: CMS Constituent 12-Dichloroethane (ug/L) 12-Dichloroethane (ug/L) 14-Dichlorobenzene(ug/L) Benzene(ug/L) Benzene (ug/L) Benzene (ug/L) Benzene (ug/L) Vinyl chloride (ug/L) Vinyl chloride (ug/L) Vinyl chloride (ug/L) Confidence Interval Charlotte Motor Speedway Client: RSI Data: CMS Printed 11/22/2019, 7:43 AM Well Upper Lim. Lower Lim. Compliance Sic. N %NDs Transform Alpha Method MW-33 1.699 0.5952 1 No 4 50 In(x) 0.01 Param. MW-34 4.765 -2.243 1 No 4 25 xA2 0.01 Param. MW-25 14.32 -8.597 6 No 4 0 xA6 0.01 Param. MW-31 1.4 1 1 No 4 75 No 0.0625 NP (normality) MW-33 4.615 3.325 1 Yes 4 0 In(x) 0.01 Param. MW-34 12.17 4.329 1 Yes 4 0 In(x) 0.01 Param. MW-32R 8.219 3.182 1 Yes 4 0 In(x) 0.01 Param. MW-31 2.1 1 1 No 4 50 No 0.0625 NP (normality) MW-33 6.823 1.748 1 Yes 4 0 In(x) 0.01 Param. MW-32R 4.455 -3.616 1 No 4 0 xA6 0.01 Param. Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance Limit is not exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 6 4 2 0 J -2 -4 El Limit = 1 Constituent: 12-Dichloroethane Analysis Run 11/22/2019 7:42 AM View: Confidence Intervals - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric Confidence Interval Compliance Limit is not exceeded. Per -well alpha = 0.01. Normality Test: Shapiro Wilk, alpha based on n. 30 22 14 91 J -2 F01 Constituent: 14-Dichlorobenzene Analysis Run 11/22/2019 7:42 AM View: Confidence Intervals - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric and Non -Parametric (NP) Confidence Interval Compliance limit is exceeded.* Per -well alpha = 0.01 except as noted. Normality Test: Shapiro Wilk, alpha based on n. 30 24 In 12 J 6 Id n x 4pO • 06, Constituent: Benzene Analysis Run 11/22/2019 7:42 AM View: Confidence Intervals - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Parametric and Non -Parametric (NP) Confidence Interval Compliance limit is exceeded.* Per -well alpha = 0.01 except as noted. Normality Test: Shapiro Wilk, alpha based on n. 10 [:l 2 -2 J -6 F01 sri�/U, �d/LJ �S Constituent: Vinyl chloride Analysis Run 11/22/2019 7:42 AM View: Confidence Intervals - Organics Charlotte Motor Speedway Client: RSI Data: CMS TIME SERIES PLOTS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 7 12 6 0 11 /17/93 Time Series 1 /22/99 3/29/04 6/4/09 8/10/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Antimony Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 7 20 10 Time Series aooio600�i�i�io6aio � i�o�a�i►. a' MW-11 MW-14 ♦ MW-14B MW-15 0 8/26/92 1 /29/98 7/4/03 12/7/08 5/12/14 10/16/19 Constituent: Arsenic Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.5 0.4 0.3 J E 0.2 0.1 w 0 1 /29/92 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Barium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 8-17 6 J 4 2-4 ^i�ooiaoa , A AAAAM` I 0 11 /17/93 1 /22/99 3/29/04 6/4/09 8/10/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Beryllium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.01 0.008 0.006 J 0.004 0.002 z 014 1 /29/92 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Cadmium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.1 0.08 0.06 J E 0.04 c 0.02 0 1 /29/92 Time Series 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Chromium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 7 8 4 0 3/23/95 Time Series 2/19/00 1 /18/05 12/17/09 11 /16/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Cobalt Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.4 0.32 0.24 J E 0.16 0.08 i 0 1 /29/92 Time Series 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Copper Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 0) 7 8 4 0 1 /29/92 Time Series 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Lead Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 7 20 10 0 11 /17/93 Time Series 1 /22/99 3/29/04 6/4/09 8/10/14 10/16/19 MW-11 MW-14 ♦ MW-14B IF MW-15 Constituent: Nickel Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 50 40 30 J 7 20 10 0 8/26/92 Time Series 1 /29/98 7/4/03 12/7/08 5/12/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Selenium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.03 0.024 0.018 J E 0.012 0.006 0 8/26/92 Time Series 1 /29/98 7/4/03 12/7/08 5/12/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Silver Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 C 1711 6 J 4 — 2 0 11 /17/93 1 /22/99 3/29/04 6/4/09 8/10/14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Thallium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 i J 7 16 8 Time Series a lI t e � MW-11 MW-14 ♦ MW-14B MW-15 0 11 /17/93 1 /22/99 3/29/04 6/4/09 8/10/14 10/16/19 Constituent: Vanadium Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.7 0.56 0.42 J E 0.28 0.14 i 0 1 /29/92 Time Series 8/14/97 2/28/03 9/14/08 3/31 /14 10/16/19 MW-11 MW-14 ♦ MW-14B MW-15 Constituent: Zinc Total Analysis Run 11/22/2019 7:47 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 30 24 18 J 7 12 6 Al 11 /17/93 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A ♦ MW-25 Constituent: Antimony Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 J 7 20 10 0 8/26/92 1 /29/98 7/5/03 12/7/08 5/13/14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A MW-25 Constituent: Arsenic Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J E 0.8 0.4 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A ♦ MW-25 Constituent: Barium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 8 6 J 7 4 2 0 11 /17/93 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A MW-25 Constituent: Beryllium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A MW-25 Constituent: Cadmium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.3 0.24 0.18 J E 0.12 0.06 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A ♦ MW-25 Constituent: Chromium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2000 1600 1200 J 7 800 400 11 /17/93 Time Series - 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A ♦ MW-25 Constituent: Cobalt Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.7 0.56 0.42 J E 0.28 0.14 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A MW-25 Constituent: Copper Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 110 88 66 J 7 44 22 0 4- 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 Constituent: Lead Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS MW-10 MW-10A MW-12 MW-1A MW-1 B MW-2A MW-2B M W-21 MW-22 MW-22A MW-25 Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 7 80 40 0 ! 11 /17/93 Time Series 0 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 MW-10 MW-10A MW-12 MW-1A MW-1 B MW-2A MW-2B M W-21 MW-22 MW-22A MW-25 Constituent: Nickel Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 J 7 20 10 0 8/26/92 1 /29/98 7/5/03 12/7/08 5/13/14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A MW-25 Constituent: Selenium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.03 0.024 0.018 J E 0.012 0.006 0 4- 8/26/92 Time Series 1 /29/98 7/5/03 12/7/08 5/13/14 10/17/19 MW-10 MW-10A MW-12 MW-1A MW-1 B MW-2A MW-2B M W-21 MW-22 MW-22A MW-25 Constituent: Silver Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 0) Z3 8 4 0 ! 11 /17/93 Time Series 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 MW-10 MW-10A MW-12 MW-1A MW-1 B MW-2A MW-2B M W-21 MW-22 MW-22A MW-25 Constituent: Thallium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 80 64 48 J 7 32 16 0 11 /17/93 Time Series 1 /23/99 3/30/04 6/5/09 8/11 /14 10/17/19 MW-10 MW-10A MW-12 MW-1A MW-1 B MW-2A MW-2B M W-21 MW-22 MW-22A MW-25 Constituent: Vanadium Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.4 0.32 0.24 J E 0.16 0.08 1 /29/92 Time Series 8/14/97 3/1 /03 9/14/08 4/1 /14 10/17/19 ♦ MW-10 ■ MW-10A ♦ MW-12 ♦ MW-1A ■ MW-1 B • MW-2A ♦ MW-2B ■ MW-21 • MW-22 ♦ MW-22A ♦ MW-25 Constituent: Zinc Total Analysis Run 11/22/2019 7:48 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J a� 12 6 0 4- 1 /23/96 Time Series 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Antimony Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS SanitasTM v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 10 8 6 J 4 2 0 1 /23/96 Time Series MY i 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 MW-20B IL MW-20AR MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R T- Constituent: Arsenic Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J a� E 0.8 0.4 Time Series I ► .A �I I�' 1 � � % 1. 1� I► �l►�j1 �1 ��Ir► ��� 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR MW-19R Constituent: Barium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 Time Series 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Beryllium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.01 0.008 0.006 J a E 0.004 0.002 Time Series T7 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Cadmium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.2 0.16 0.12 J a� E 0.08 0.04 Time Series 0 P -�-, 1 /23/96 10/21/00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Chromium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 80 64 48 J a� 32 16 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Cobalt Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.3 - 0.24 - 0.18 - J a� E 0.12 - 0.06 - 0 1 /23/96 Time Series r� r. 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Copper Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS SanitasTM v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 10 8 6 J 4 2 0 1 /23/96 10/21 /00 7/20/05 Time Series 4/18/10 1 /15/15 10/15/19 MW-20B MW-20AR MW-19 MW-19A MW-18AR MW-19AR MW-19R Constituent: Lead Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J a 80 40 Time Series iL r 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Nickel Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J a� 12 i Time Series I ' I1 ` 0 1 /23/96 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR I ♦ MW-19R 10/21/00 7/20/05 4/18/10 1/15/15 10/15/19 Constituent: Selenium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.2 0.16 0.12 J a� E 0.08 0.04 Time Series 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A ■ MW-18AR • MW-19AR ♦ MW-19R Constituent: Silver Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 10 8 6 J 4 2 0 1 /23/96 Time Series I 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-20AR ♦ MW-19 ♦ MW-19A MW-18AR MW-19AR MW-19R Constituent: Thallium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 80 64 48 J a� 32 16 0 1 /23/96 10/21 /00 7/20/05 Time Series 4/18/10 1 /15/15 10/15/19 MW-20B MW-20AR MW-19 MW-19A MW-18AR MW-19AR MW-19R Constituent: Vanadium Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 40 32 24 J E 16 8 0 4- 1 /23/96 Time Series 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 Constituent: Zinc Total Analysis Run 11/22/2019 7:50 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS MW-20B MW-20AR MW-19 MW-19A MW-18AR MW-19AR MW-19R Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 30 24 18 J 7 12 6 0 ! 11 /19/97 Time Series 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 MW-17 MW-17A MW-24 MW-31 MW-33 M W-34 MW-30R MW-32R Constituent: Antimony Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 J 0) Z3 8 4 [el ■ 11 /19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Arsenic Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 2 1.6 1.2 J E 0.8 0.4 0 11 /19/97 Time Series 4/7/02 8/24/06 1/10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Barium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 7 2 1 0 11 /19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Beryllium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.005 0.004 0.003 J E 0.002 0.001 0 I I I - -V q,--IV - I 11 /19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Cadmium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.7 0.56 0.42 J E 0.28 0.14 11 /19/97 Time Series 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Chromium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 90 72 54 J 7 36 18 0 ! 11 /19/97 Time Series 4/7/02 8/24/06 1/10/11 5/29/15 10/16/19 MW-17 MW-17A MW-24 MW-31 MW-33 M W-34 MW-30R MW-32R Constituent: Cobalt Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.2 0.16 0.12 J E 0.08 0.04 [lam ! ! , ` _ITS= _ _ -off I T 3 11 /19/97 4/7/02 8/24/06 1/10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Copper Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 7 80 40 0 11 /19/97 Time Series 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 Constituent: Lead Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS MW-17 MW-17A MW-24 MW-31 MW-33 M W-34 MW-30R MW-32R Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 300 240 180 J 7 120 60 Kelm Ir��I�It��r1�1�17�L�J \���7j _ I 11/19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Nickel Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 30 24 18 J 7 12 6 [el ■ 11 /19/97 4/7/02 8/24/06 1/10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Selenium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 0.01 0.008 0.006 J E 0.004 0.002 11 /19/97 Time Series 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Silver Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 J 7 8 4 Kelm� � r - : �r ■ 11 /19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Thallium Total Analysis Run 11/22/2019 7:51 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 200 160 120 J 0) Z3 80 40 0 11 /19/97 Time Series 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 MW-17 MW-17A MW-24 MW-31 MW-33 M W-34 MW-30R MW-32R Constituent: Vanadium Total Analysis Run 11/22/2019 7:52 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 1 0.8 0.6 J E 0.4 0.2 0 11 /19/97 4/7/02 8/24/06 1 /10/11 5/29/15 10/16/19 ♦ MW-17 ■ MW-17A • MW-24 • MW-31 ♦ MW-33 ♦ MW-34 ♦ MW-30R ■ MW-32R Constituent: Zinc Total Analysis Run 11/22/2019 7:52 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 20 16 12 J 7 8 4 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 I AL 1 Ii 1- AL 1 1 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Antimony Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 J 7 20 10 �u 0 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Arsenic Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.8 0.64 0.48 J 0) E 0.32 0.16 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 1 1 1 1 1 1 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Barium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 3 2.4 1.8 J 0) Z3 1.2 0.6 0 O Time Series ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Beryllium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.0011 0.00088 0.00066 J 0) E 0.00044 0.00022 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 I 1 i 1 1 1 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Cadmium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.4 0.32 0.24 J 0) E 0.16 0.08 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 r MW-29R 0 and ZS N ` 1 rr�+r�.y y`,`.�Fa' i -- !/ �Y� 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Chromium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 200 160 120 J 0) 7 80 40 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 T": - s armor. ate. i .C:l L� !d l� : �[l rd � 1 Z T�r�l'��Y�fT�^Tr^'-4TrY—� �T 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Cobalt Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.5 0.4 0.3 J >_ 0.2 0.1 0 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Copper Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 J 7 20 10 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 I T =V r — 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Lead Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 600 480 360 J 7 240 120 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 r MW-29R 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Nickel Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 50 40 30 J 0) Z3 20 10 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 I I - r-W M- T • I 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Selenium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.02 0.016 0.012 J E 0.008 0.004 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 ♦ MW-29R 0 1 1 L_= i 1 1 1 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Silver Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 10 8 6 J 4 2 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 r MW-29R 0 I • F• ■ i i I ■1 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Thallium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 400 320 240 J 7 160 80 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 r MW-29R *a. � r — — : r v ram_ —tea - •,L�— :W• 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Vanadium Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 0.3 0.24 0.18 J 0) E 0.12 0.06 0 ■ MW-16 • MW-26 ♦ MW-27 ♦ MW-28 r MW-29R 6/11 /07 11 /29/09 5/19/12 11 /7/14 4/27/17 10/17/19 Constituent: Zinc Total Analysis Run 11/22/2019 7:53 AM View: Time Series Graphs Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. Time Series 5 4 3 J 0) 2 FIR 1 0 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-19 ♦ MW-19A ♦ MW-25 • MW-31 ♦ MW-33 ♦ MW-34 ■ MW-32R Constituent: 12-Dichloroethane Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. J 20 16 12 8 4 0 1 /23/96 10/21 /00 7/20/05 Time Series 4/18/10 1 /15/15 10/15/19 am MW-20B MW-19 MW-19A MW-25 MW-31 MW-33 MW-34 MW-32R Constituent: 14-Dichlorobenzene Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 10 8 6 J a� 4 2 0 4- 1 /23/96 Time Series 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B MW-19 MW-19A MW-25 MW-31 MW-33 MW-34 MW-32R Constituent: Benzene Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 0) Z3 8 4 0 4- 1 /23/96 Time Series 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B MW-19 MW-19A MW-25 MW-31 MW-33 MW-34 MW-32R Constituent: Chlorobenzene Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 20 16 12 J 0) Z3 8 4 0 Time Series 1 1 /23/96 10/21 /00 7/20/05 4/18/10 1 /15/15 10/15/19 • MW-20B ♦ MW-19 ♦ MW-19A ♦ MW-25 • MW-31 ♦ MW-33 ♦ MW-34 ■ MW-32R Constituent: cis- 12-Dichloroethylene Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organ Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. 5 4 3 J 2 1 0 1 /23/96 10/21 /00 7/20/05 Time Series 4/18/10 1 /15/15 10/15/19 • MW-20B MW-19 MW-19A MW-25 MW-31 MW-33 MW-34 MW-32R Constituent: Trichloroethylene Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS Sanitas" v.9.6.23 Software licensed to Jett Environmental Consulting. UG Hollow symbols indicate censored values. J Z3 10 8 rX 4 2 0 1 /23/96 10/21 /00 7/20/05 Time Series 4/18/10 1 /15/15 10/15/19 • MW-20B MW-19 MW-19A MW-25 MW-31 MW-33 MW-34 MW-32R Constituent: Vinyl chloride Analysis Run 11/22/2019 8:06 AM View: Time Series Graphs - Organics Charlotte Motor Speedway Client: RSI Data: CMS APPENDIX C LABORATORY ANALYTICAL REPORTS FIELD INFORMATION FORMS lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 November 23, 2019 Environmental Manager BFI Waste Systems of North America. LLC 5105 Moreland Road Concord, NC 28027 RE: Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on October 17, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Maiya Parks for Betsy McDaniel betsy.mcdaniel@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Database Manager REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 CERTIFICATIONS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Pace Analytical Services Atlanta 110 Technology Parkway Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification #: E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 Virginia Certification #: 460204 Georgia DW Microbiology Certification #: 812 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Matrix Date Collected Date Received 2624501001 1304-MW-1A Water 10/17/1911:39 10/17/19 17:15 2624501002 1304-MW-1 B Water 10/17/19 11:54 10/17/19 17:15 2624501003 1304-MW-2A Water 10/14/1914:37 10/17/19 17:15 2624501004 1304-MW-2B Water 10/14/1915:28 10/17/19 17:15 2624501005 1304-MW-10 Water 10/16/19 08:05 10/17/19 17:15 2624501006 1304-MW-10A Water 10/16/19 09:13 10/17/19 17:15 2624501007 1304-MW-11 Water 10/14/1912:44 10/17/19 17:15 2624501008 1304-MW-12 Water 10/14/1913:22 10/17/19 17:15 2624501009 1304-MW-14 Water 10/16/19 09:26 10/17/19 17:15 2624501010 1304-MW-14B Water 10/16/19 08:49 10/17/19 17:15 2624501011 1304-MW-15 Water 10/16/1910:13 10/17/19 17:15 2624501012 1304-MW-16 Water 10/16/1911:05 10/17/19 17:15 2624501013 1304-MW-18A Water 10/15/1915:14 10/17/19 17:15 2624501014 1304-MW-19 Water 10/15/1910:41 10/17/19 17:15 2624501015 1304-MW-19A Water 10/15/1912:24 10/17/19 17:15 2624501016 1304-MW-19AR Water 10/15/1914:03 10/17/19 17:15 2624501017 1304-MW-19R Water 10/15/1914:24 10/17/19 17:15 2624501018 1304-MW-20AR Water 10/15/1912:23 10/17/19 17:15 2624501019 1304-MW-20B Water 10/15/1914:55 10/17/19 17:15 2624501020 1304-MW-21 Water 10/16/1914:29 10/17/19 17:15 2624501021 1304-MW-21 Water 10/17/19 08:09 10/17/19 17:15 2624501022 1304-MW-22 Water 10/15/19 08:32 10/17/19 17:15 2624501023 1304-MW-22A Water 10/15/19 09:22 10/17/19 17:15 2624501024 1304-MW-25 Water 10/15/19 08:02 10/17/19 17:15 2624501025 1304-MW-26 Water 10/17/1911:10 10/17/19 17:15 2624501026 1304-MW-27 Water 10/16/1911:54 10/17/19 17:15 2624501027 1304-MW-27 Water 10/17/19 07:57 10/17/19 17:15 2624501028 1304-MW-28 Water 10/15/1916:10 10/17/19 17:15 2624501029 1304-MW-29R Water 10/15/19 08:10 10/17/19 17:15 2624501030 1304-MW-30R Water 10/16/1915:24 10/17/19 17:15 2624501031 1304-MW-31 Water 10/15/19 08:48 10/17/19 17:15 2624501032 1304-MW-32R Water 10/15/19 09:38 10/17/19 17:15 2624501033 1304-MW-33 Water 10/15/1910:44 10/17/19 17:15 2624501034 1304-MW-34 Water 10/15/1911:11 10/17/19 17:15 2624501035 DUPLICATE Water 10/15/19 00:00 10/17/19 17:15 2624501036 Equipment Blank Water 10/17/19 17:05 10/17/19 17:15 2624501037 Field Blank Water 10/15/19 09:42 10/17/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Matrix Date Collected Date Received 2624501038 Trip Blank Water 10/14/19 00:00 10/17/19 17:15 2624501039 SW-1 Water 10/17/1910:13 10/17/19 17:15 2624501040 SW-2 Water 10/17/19 07:25 10/17/19 17:15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Method Analysts Analytes Reported 2624501001 1304-MW-1A EPA6020B CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501002 1304-MW-1 B EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501003 1304-MW-2A EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501004 1304-MW-2B EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501005 1304-MW-10 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501006 1304-MW-10A EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501007 1304-MW-11 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501008 1304-MW-12 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501009 1304-MW-14 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501010 1304-MW-14B EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501011 1304-MW-15 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501012 1304-MW-16 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501013 1304-MW-18A EPA 6020E CSW 15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Method Analysts Analytes Reported EPA 7470A DRB 1 EPA 8260D RAC 51 2624501014 1304-MW-19 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501015 1304-MW-19A EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501016 1304-MW-19AR EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501017 1304-MW-19R EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501018 1304-MW-20AR EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501019 1304-MW-20B EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501020 1304-MW-21 EPA 8260D RAC 51 2624501021 1304-MW-21 EPA 6020E CSW 15 EPA 7470A DRB 1 2624501022 1304-MW-22 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501023 1304-MW-22A EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501024 1304-MW-25 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501025 1304-MW-26 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501026 1304-MW-27 EPA 8260D RAC 51 2624501027 1304-MW-27 EPA 6020E CSW 15 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Method Analysts Analytes Reported EPA 7470A DRB 1 2624501028 1304-MW-28 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501029 1304-MW-29R EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501030 1304-MW-30R EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501031 1304-MW-31 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501032 1304-MW-32R EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D JG 51 2624501033 1304-MW-33 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D JG 51 2624501034 1304-MW-34 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D JG 51 2624501035 DUPLICATE EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D JG 51 2624501036 Equipment Blank EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501037 Field Blank EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D JG 51 2624501038 Trip Blank EPA 8260D RAC 51 2624501039 SW-1 EPA 6020E CSW 15 EPA 7470A DRB 1 EPA 8260D RAC 51 2624501040 SW-2 EPA 6020E CSW 15 EPA 7470A DRB 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID Method EPA 8260D REPORT OF LABORATORY ANALYSIS Analytes Analysts Reported RAC 51 This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-1A Lab ID: 2624501001 Collected: 10/17/19 11:39 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/17/19 11:39 Field pH 6.47 Std. Units 1 10/17/19 11:39 Field Temperature 18.2 deg C 1 10/17/19 11:39 Field Specific 973 umhos/c 1 10/17/19 11:39 Conductance m Field Turbidity 7.16 NTU 1 10/17/19 11:39 Oxygen, Dissolved 1.74 mg/L 1 10/17/19 11:39 7782-44-7 N2 Depth to Water 01.13 feet 1 10/17/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 22:37 7440-36-0 Arsenic 0.46J ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 22:37 7440-38-2 B Barium 136 ug/L 100 0.49 1 10/31/19 21:45 11/01/19 22:37 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 22:37 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 22:37 7440-43-9 Chromium 4.8J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 22:37 7440-47-3 B Cobalt 7.7J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 22:37 7440-48-4 Copper 6.6J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 22:37 7440-50-8 Lead 0.66J ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 22:37 7439-92-1 Nickel 8.8J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 22:37 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 22:37 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 22:37 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 22:37 7440-28-0 Vanadium 3.4J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 22:37 7440-62-2 B Zinc 12.1 ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 22:37 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:05 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/31/19 19:47 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/31/19 19:47 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/31/19 19:47 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/31/19 19:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/31/19 19:47 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/31/19 19:47 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/31/19 19:47 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/31/19 19:47 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/31/19 19:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/31/19 19:47 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/31/19 19:47 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/31/19 19:47 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/31/19 19:47 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/31/19 19:47 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/31/19 19:47 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-1A Lab ID: 2624501001 Collected: 10/17/19 11:39 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/31/1919:47 124-48-1 ND ug/L 2.0 0.28 1 10/31/1919:47 106-93-4 ND ug/L 10.0 0.62 1 10/31/1919:47 74-95-3 ND ug/L 5.0 0.49 1 10/31/1919:47 95-50-1 ND ug/L 1.0 0.58 1 10/31/1919:47 106-46-7 ND ug/L 100 1.6 1 10/31/1919:47 110-57-6 ND ug/L 5.0 0.41 1 10/31/1919:47 75-34-3 ND ug/L 1.0 0.67 1 10/31/1919:47 107-06-2 ND ug/L 5.0 0.72 1 10/31/1919:47 75-35-4 ND ug/L 5.0 0.66 1 10/31/1919:47 156-59-2 ND ug/L 5.0 0.46 1 10/31/1919:47 156-60-5 ND ug/L 1.0 0.60 1 10/31/1919:47 78-87-5 ND ug/L 1.0 0.22 1 10/31/1919:47 10061-01-5 ND ug/L 1.0 0.30 1 10/31/1919:47 10061-02-6 ND ug/L 1.0 0.45 1 10/31/1919:47 100-41-4 ND ug/L 50.0 0.89 1 10/31/1919:47 591-78-6 ND ug/L 10.0 3.1 1 10/31/1919:47 74-88-4 ND ug/L 1.0 0.50 1 10/31/1919:47 75-09-2 ND ug/L 100 0.86 1 10/31/1919:47 108-10-1 ND ug/L 1.0 0.50 1 10/31/1919:47 100-42-5 ND ug/L 5.0 0.32 1 10/31/1919:47 630-20-6 ND ug/L 3.0 0.53 1 10/31/1919:47 79-34-5 ND ug/L 1.0 0.78 1 10/31/1919:47 127-18-4 ND ug/L 1.0 0.31 1 10/31/1919:47 108-88-3 ND ug/L 1.0 0.38 1 10/31 /19 19:47 71-55-6 ND ug/L 1.0 0.59 1 10/31/1919:47 79-00-5 ND ug/L 1.0 0.34 1 10/31 /19 19:47 79-01-6 ND ug/L 1.0 0.51 1 10/31/1919:47 75-69-4 ND ug/L 1.0 0.46 1 10/31/1919:47 96-18-4 ND ug/L 50.0 0.42 1 10/31/1919:47 108-05-4 ND ug/L 1.0 0.60 1 10/31 /19 19:47 75-01-4 ND ug/L 5.0 1.5 1 10/31/1919:47 1330-20-7 109 %. 81-119 1 10/31/1919:47 17060-07-0 104 %. 82-114 1 10/31/1919:47 1868-53-7 106 %. 82-120 1 10/31 /19 19:47 460-00-4 106 %. 82-109 1 10/31 /19 19:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-1B Lab ID: 2624501002 Collected: 10/17/19 11:54 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/17/19 11:54 Field pH 6.43 Std. Units 1 10/17/19 11:54 Field Temperature 16.6 deg C 1 10/17/19 11:54 Field Specific 711 umhos/c 1 10/17/19 11:54 Conductance m Field Turbidity 3.27 NTU 1 10/17/19 11:54 Oxygen, Dissolved 1.84 mg/L 1 10/17/19 11:54 7782-44-7 N2 Depth to Water 11.41 feet 1 10/17/19 11:54 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:11 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:11 7440-38-2 Barium 6.3J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:11 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:11 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:11 7440-43-9 Chromium 0.52J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:11 7440-47-3 B Cobalt 1.7J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:11 7440-48-4 Copper 1.9J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:11 7440-50-8 Lead 0.054J ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:11 7439-92-1 Nickel 25.5J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:11 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:11 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:11 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:11 7440-28-0 Vanadium 2.OJ ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:11 7440-62-2 B Zinc 9.OJ ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:11 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:15 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/31/19 20:12 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/31/19 20:12 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/31/19 20:12 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/31/19 20:12 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/31/19 20:12 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/31/19 20:12 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/31/19 20:12 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/31/19 20:12 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/31/19 20:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/31/19 20:12 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/31/19 20:12 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/31/19 20:12 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/31/19 20:12 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/31/19 20:12 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/31/19 20:12 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-1B Lab ID: 2624501002 Collected: 10/17/19 11:54 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/31/19 20:12 124-48-1 ND ug/L 2.0 0.28 1 10/31/19 20:12 106-93-4 ND ug/L 10.0 0.62 1 10/31/19 20:12 74-95-3 ND ug/L 5.0 0.49 1 10/31/19 20:12 95-50-1 ND ug/L 1.0 0.58 1 10/31/19 20:12 106-46-7 ND ug/L 100 1.6 1 10/31/19 20:12 110-57-6 ND ug/L 5.0 0.41 1 10/31/19 20:12 75-34-3 ND ug/L 1.0 0.67 1 10/31/19 20:12 107-06-2 ND ug/L 5.0 0.72 1 10/31/19 20:12 75-35-4 ND ug/L 5.0 0.66 1 10/31/19 20:12 156-59-2 ND ug/L 5.0 0.46 1 10/31/19 20:12 156-60-5 ND ug/L 1.0 0.60 1 10/31/19 20:12 78-87-5 ND ug/L 1.0 0.22 1 10/31/19 20:12 10061-01-5 ND ug/L 1.0 0.30 1 10/31/19 20:12 10061-02-6 ND ug/L 1.0 0.45 1 10/31/19 20:12 100-41-4 ND ug/L 50.0 0.89 1 10/31/19 20:12 591-78-6 ND ug/L 10.0 3.1 1 10/31/19 20:12 74-88-4 ND ug/L 1.0 0.50 1 10/31/19 20:12 75-09-2 ND ug/L 100 0.86 1 10/31/19 20:12 108-10-1 ND ug/L 1.0 0.50 1 10/31/19 20:12 100-42-5 ND ug/L 5.0 0.32 1 10/31/19 20:12 630-20-6 ND ug/L 3.0 0.53 1 10/31/19 20:12 79-34-5 ND ug/L 1.0 0.78 1 10/31/19 20:12 127-18-4 ND ug/L 1.0 0.31 1 10/31/19 20:12 108-88-3 ND ug/L 1.0 0.38 1 10/31/19 20:12 71-55-6 ND ug/L 1.0 0.59 1 10/31/19 20:12 79-00-5 ND ug/L 1.0 0.34 1 10/31/19 20:12 79-01-6 ND ug/L 1.0 0.51 1 10/31/19 20:12 75-69-4 ND ug/L 1.0 0.46 1 10/31/19 20:12 96-18-4 ND ug/L 50.0 0.42 1 10/31/19 20:12 108-05-4 ND ug/L 1.0 0.60 1 10/31/19 20:12 75-01-4 ND ug/L 5.0 1.5 1 10/31/19 20:12 1330-20-7 110 %. 81-119 1 10/31/19 20:12 17060-07-0 104 %. 82-114 1 10/31/19 20:12 1868-53-7 106 %. 82-120 1 10/31/19 20:12 460-00-4 105 %. 82-109 1 10/31/19 20:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-2A Lab ID: 2624501003 Collected: 10/14/19 14:37 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/14/19 14:37 Field pH 6.09 Std. Units 1 10/14/19 14:37 Field Temperature 19.5 deg C 1 10/14/19 14:37 Field Specific 1189 umhos/c 1 10/14/19 14:37 Conductance m Field Turbidity 2.01 NTU 1 10/14/19 14:37 Oxygen, Dissolved 6.73 mg/L 1 10/14/19 14:37 7782-44-7 N2 Depth to Water 9.44 feet 1 10/14/19 14:37 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:17 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:17 7440-38-2 Barium 182 ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:17 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:17 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:17 7440-43-9 Chromium 0.72J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:17 7440-47-3 B Cobalt 0.47J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:17 7440-48-4 Copper 1.1J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:17 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:17 7439-92-1 Nickel 9.9J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:17 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:17 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:17 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:17 7440-28-0 Vanadium 3.7J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:17 7440-62-2 B Zinc 6.OJ ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:17 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:17 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 15:15 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 15:15 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 15:15 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 15:15 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 15:15 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 15:15 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 15:15 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 15:15 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 15:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 15:15 56-23-5 M1 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 15:15 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 15:15 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 15:15 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 15:15 74-87-3 R1 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 15:15 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-2A Lab ID: 2624501003 Collected: 10/14/19 14:37 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1915:15 124-48-1 ND ug/L 2.0 0.28 1 10/26/1915:15 106-93-4 ND ug/L 10.0 0.62 1 10/26/1915:15 74-95-3 ND ug/L 5.0 0.49 1 10/26/1915:15 95-50-1 ND ug/L 1.0 0.58 1 10/26/1915:15 106-46-7 ND ug/L 100 1.6 1 10/26/1915:15 110-57-6 ND ug/L 5.0 0.41 1 10/26/1915:15 75-34-3 ND ug/L 1.0 0.67 1 10/26/1915:15 107-06-2 ND ug/L 5.0 0.72 1 10/26/1915:15 75-35-4 ND ug/L 5.0 0.66 1 10/26/1915:15 156-59-2 ND ug/L 5.0 0.46 1 10/26/1915:15 156-60-5 ND ug/L 1.0 0.60 1 10/26/1915:15 78-87-5 ND ug/L 1.0 0.22 1 10/26/1915:15 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1915:15 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1915:15 100-41-4 ND ug/L 50.0 0.89 1 10/26/1915:15 591-78-6 ND ug/L 10.0 3.1 1 10/26/1915:15 74-88-4 ND ug/L 1.0 0.50 1 10/26/1915:15 75-09-2 ND ug/L 100 0.86 1 10/26/1915:15 108-10-1 ND ug/L 1.0 0.50 1 10/26/1915:15 100-42-5 ND ug/L 5.0 0.32 1 10/26/1915:15 630-20-6 ND ug/L 3.0 0.53 1 10/26/1915:15 79-34-5 ND ug/L 1.0 0.78 1 10/26/1915:15 127-18-4 ND ug/L 1.0 0.31 1 10/26/1915:15 108-88-3 ND ug/L 1.0 0.38 1 10/26/1915:15 71-55-6 ND ug/L 1.0 0.59 1 10/26/1915:15 79-00-5 ND ug/L 1.0 0.34 1 10/26/1915:15 79-01-6 ND ug/L 1.0 0.51 1 10/26/1915:15 75-69-4 ND ug/L 1.0 0.46 1 10/26/1915:15 96-18-4 ND ug/L 50.0 0.42 1 10/26/1915:15 108-05-4 ND ug/L 1.0 0.60 1 10/26/1915:15 75-01-4 ND ug/L 5.0 1.5 1 10/26/1915:15 1330-20-7 108 %. 81-119 1 10/26/1915:15 17060-07-0 104 %. 82-114 1 10/26/1915:15 1868-53-7 106 %. 82-120 1 10/26/1915:15 460-00-4 108 %. 82-109 1 10/26/1915:15 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 1:41 R1 Page 14 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-2B Lab ID: 2624501004 Collected: 10/14/19 15:28 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/14/19 15:28 Field pH 6.10 Std. Units 1 10/14/19 15:28 Field Temperature 17.5 deg C 1 10/14/19 15:28 Field Specific 988 umhos/c 1 10/14/19 15:28 Conductance m Field Turbidity 2.74 NTU 1 10/14/19 15:28 Oxygen, Dissolved 7.90 mg/L 1 10/14/19 15:28 7782-44-7 N2 Depth to Water 9.74 feet 1 10/14/19 15:28 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:23 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:23 7440-38-2 Barium 58.7J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:23 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:23 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:23 7440-43-9 Chromium 0.81J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:23 7440-47-3 B Cobalt 13.3 ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:23 7440-48-4 Copper 0.46J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:23 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:23 7439-92-1 Nickel 19.9J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:23 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:23 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:23 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:23 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:23 7440-62-2 Zinc 5.8J ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:23 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:20 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 15:41 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 15:41 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 15:41 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 15:41 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 15:41 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 15:41 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 15:41 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 15:41 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 15:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 15:41 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 15:41 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 15:41 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 15:41 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 15:41 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 15:41 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-2B Lab ID: 2624501004 Collected: 10/14/19 15:28 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1915:41 124-48-1 ND ug/L 2.0 0.28 1 10/26/1915:41 106-93-4 ND ug/L 10.0 0.62 1 10/26/1915:41 74-95-3 ND ug/L 5.0 0.49 1 10/26/1915:41 95-50-1 ND ug/L 1.0 0.58 1 10/26/1915:41 106-46-7 ND ug/L 100 1.6 1 10/26/1915:41 110-57-6 ND ug/L 5.0 0.41 1 10/26/1915:41 75-34-3 ND ug/L 1.0 0.67 1 10/26/1915:41 107-06-2 ND ug/L 5.0 0.72 1 10/26/1915:41 75-35-4 ND ug/L 5.0 0.66 1 10/26/1915:41 156-59-2 ND ug/L 5.0 0.46 1 10/26/1915:41 156-60-5 ND ug/L 1.0 0.60 1 10/26/1915:41 78-87-5 ND ug/L 1.0 0.22 1 10/26/1915:41 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1915:41 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1915:41 100-41-4 ND ug/L 50.0 0.89 1 10/26/1915:41 591-78-6 ND ug/L 10.0 3.1 1 10/26/1915:41 74-88-4 ND ug/L 1.0 0.50 1 10/26/1915:41 75-09-2 ND ug/L 100 0.86 1 10/26/1915:41 108-10-1 ND ug/L 1.0 0.50 1 10/26/1915:41 100-42-5 ND ug/L 5.0 0.32 1 10/26/1915:41 630-20-6 ND ug/L 3.0 0.53 1 10/26/1915:41 79-34-5 ND ug/L 1.0 0.78 1 10/26/1915:41 127-18-4 ND ug/L 1.0 0.31 1 10/26/1915:41 108-88-3 ND ug/L 1.0 0.38 1 10/26/1915:41 71-55-6 ND ug/L 1.0 0.59 1 10/26/1915:41 79-00-5 ND ug/L 1.0 0.34 1 10/26/1915:41 79-01-6 ND ug/L 1.0 0.51 1 10/26/1915:41 75-69-4 ND ug/L 1.0 0.46 1 10/26/1915:41 96-18-4 ND ug/L 50.0 0.42 1 10/26/1915:41 108-05-4 ND ug/L 1.0 0.60 1 10/26/1915:41 75-01-4 ND ug/L 5.0 1.5 1 10/26/1915:41 1330-20-7 108 %. 81-119 1 10/26/1915:41 17060-07-0 107 %. 82-114 1 10/26/1915:41 1868-53-7 107 %. 82-120 1 10/26/1915:41 460-00-4 107 %. 82-109 1 10/26/1915:41 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-10 Lab ID: 2624501005 Collected: 10/16/19 08:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/16/19 08:05 Field pH 5.33 Std. Units 1 10/16/19 08:05 Field Temperature 16.4 deg C 1 10/16/19 08:05 Field Specific 116 umhos/c 1 10/16/19 08:05 Conductance m Field Turbidity 6.70 NTU 1 10/16/19 08:05 Oxygen, Dissolved 1.71 mg/L 1 10/16/19 08:05 7782-44-7 N2 Depth to Water 22.50 feet 1 10/16/19 08:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:29 7440-36-0 Arsenic 1.2J ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:29 7440-38-2 B Barium 35.4J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:29 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:29 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:29 7440-43-9 Chromium 2.5J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:29 7440-47-3 B Cobalt 0.56J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:29 7440-48-4 Copper 0.39J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:29 7440-50-8 Lead 0.064J ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:29 7439-92-1 Nickel 2.1J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:29 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:29 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:29 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:29 7440-28-0 Vanadium 4.2J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:29 7440-62-2 B Zinc 8.5J ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:29 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:27 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 11:29 67-64-1 R1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 11:29 107-13-1 R1 Benzene ND ug/L 1.0 0.20 1 10/30/19 11:29 71-43-2 R1 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 11:29 74-97-5 R1 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 11:29 75-27-4 R1 Bromoform ND ug/L 3.0 0.55 1 10/30/19 11:29 75-25-2 R1 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 11:29 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 11:29 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 11:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 11:29 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 11:29 108-90-7 R1 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 11:29 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 11:29 67-66-3 R1 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 11:29 74-87-3 R1 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 11:29 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-10 Lab ID: 2624501005 Collected: 10/16/19 08:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1911:29 124-48-1 R1 ND ug/L 2.0 0.28 1 10/30/1911:29 106-93-4 R1 ND ug/L 10.0 0.62 1 10/30/1911:29 74-95-3 R1 ND ug/L 5.0 0.49 1 10/30/1911:29 95-50-1 R1 ND ug/L 1.0 0.58 1 10/30/1911:29 106-46-7 R1 ND ug/L 100 1.6 1 10/30/1911:29 110-57-6 R1 ND ug/L 5.0 0.41 1 10/30/1911:29 75-34-3 ND ug/L 1.0 0.67 1 10/30/1911:29 107-06-2 R1 ND ug/L 5.0 0.72 1 10/30/1911:29 75-35-4 ND ug/L 5.0 0.66 1 10/30/1911:29 156-59-2 ND ug/L 5.0 0.46 1 10/30/1911:29 156-60-5 ND ug/L 1.0 0.60 1 10/30/1911:29 78-87-5 R1 ND ug/L 1.0 0.22 1 10/30/1911:29 10061-01-5 R1 ND ug/L 1.0 0.30 1 10/30/1911:29 10061-02-6 R1 ND ug/L 1.0 0.45 1 10/30/1911:29 100-41-4 R1 ND ug/L 50.0 0.89 1 10/30/1911:29 591-78-6 ND ug/L 10.0 3.1 1 10/30/1911:29 74-88-4 ND ug/L 1.0 0.50 1 10/30/1911:29 75-09-2 ND ug/L 100 0.86 1 10/30/1911:29 108-10-1 R1 ND ug/L 1.0 0.50 1 10/30/1911:29 100-42-5 ND ug/L 5.0 0.32 1 10/30/1911:29 630-20-6 R1 ND ug/L 3.0 0.53 1 10/30/1911:29 79-34-5 R1 ND ug/L 1.0 0.78 1 10/30/1911:29 127-18-4 R1 ND ug/L 1.0 0.31 1 10/30/1911:29 108-88-3 R1 ND ug/L 1.0 0.38 1 10/30/1911:29 71-55-6 ND ug/L 1.0 0.59 1 10/30/1911:29 79-00-5 R1 ND ug/L 1.0 0.34 1 10/30/1911:29 79-01-6 ND ug/L 1.0 0.51 1 10/30/1911:29 75-69-4 M1 ND ug/L 1.0 0.46 1 10/30/1911:29 96-18-4 R1 ND ug/L 50.0 0.42 1 10/30/1911:29 108-05-4 ND ug/L 1.0 0.60 1 10/30/1911:29 75-01-4 ND ug/L 5.0 1.5 1 10/30/1911:29 1330-20-7 RS 106 %. 81-119 1 10/30/1911:29 17060-07-0 102 %. 82-114 1 10/30/1911:29 1868-53-7 107 %. 82-120 1 10/30/1911:29 460-00-4 106 %. 82-109 1 10/30/1911:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-10A Lab ID: 2624501006 Collected: 10/16/19 09:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/16/19 09:13 Field pH 6.12 Std. Units 1 10/16/19 09:13 Field Temperature 17.4 deg C 1 10/16/19 09:13 Field Specific 229 umhos/c 1 10/16/19 09:13 Conductance m Field Turbidity 2.17 NTU 1 10/16/19 09:13 Oxygen, Dissolved 1.07 mg/L 1 10/16/19 09:13 7782-44-7 N2 Depth to Water 22.85 feet 1 10/16/19 09:13 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:34 7440-36-0 Arsenic 1.4J ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:34 7440-38-2 B Barium 28.9J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:34 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:34 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:34 7440-43-9 Chromium 1.9J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:34 7440-47-3 B Cobalt ND ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:34 7440-48-4 Copper 0.50J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:34 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:34 7439-92-1 Nickel 1.3J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:34 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:34 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:34 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:34 7440-28-0 Vanadium 5.6J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:34 7440-62-2 B Zinc 9.9J ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:34 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:29 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 11:55 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 11:55 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 11:55 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 11:55 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 11:55 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 11:55 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 11:55 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 11:55 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 11:55 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 11:55 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 11:55 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 11:55 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 11:55 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 11:55 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 11:55 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-10A Lab ID: 2624501006 Collected: 10/16/19 09:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1911:55 124-48-1 ND ug/L 2.0 0.28 1 10/30/1911:55 106-93-4 ND ug/L 10.0 0.62 1 10/30/1911:55 74-95-3 ND ug/L 5.0 0.49 1 10/30/1911:55 95-50-1 ND ug/L 1.0 0.58 1 10/30/1911:55 106-46-7 ND ug/L 100 1.6 1 10/30/1911:55 110-57-6 ND ug/L 5.0 0.41 1 10/30/1911:55 75-34-3 ND ug/L 1.0 0.67 1 10/30/1911:55 107-06-2 ND ug/L 5.0 0.72 1 10/30/1911:55 75-35-4 ND ug/L 5.0 0.66 1 10/30/1911:55 156-59-2 ND ug/L 5.0 0.46 1 10/30/1911:55 156-60-5 ND ug/L 1.0 0.60 1 10/30/1911:55 78-87-5 ND ug/L 1.0 0.22 1 10/30/1911:55 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1911:55 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1911:55 100-41-4 ND ug/L 50.0 0.89 1 10/30/1911:55 591-78-6 ND ug/L 10.0 3.1 1 10/30/1911:55 74-88-4 ND ug/L 1.0 0.50 1 10/30/1911:55 75-09-2 ND ug/L 100 0.86 1 10/30/1911:55 108-10-1 ND ug/L 1.0 0.50 1 10/30/1911:55 100-42-5 ND ug/L 5.0 0.32 1 10/30/1911:55 630-20-6 ND ug/L 3.0 0.53 1 10/30/1911:55 79-34-5 ND ug/L 1.0 0.78 1 10/30/1911:55 127-18-4 ND ug/L 1.0 0.31 1 10/30/1911:55 108-88-3 ND ug/L 1.0 0.38 1 10/30/1911:55 71-55-6 ND ug/L 1.0 0.59 1 10/30/1911:55 79-00-5 ND ug/L 1.0 0.34 1 10/30/1911:55 79-01-6 ND ug/L 1.0 0.51 1 10/30/1911:55 75-69-4 ND ug/L 1.0 0.46 1 10/30/1911:55 96-18-4 ND ug/L 50.0 0.42 1 10/30/1911:55 108-05-4 ND ug/L 1.0 0.60 1 10/30/1911:55 75-01-4 ND ug/L 5.0 1.5 1 10/30/1911:55 1330-20-7 105 %. 81-119 1 10/30/1911:55 17060-07-0 99 %. 82-114 1 10/30/1911:55 1868-53-7 105 %. 82-120 1 10/30/1911:55 460-00-4 106 %. 82-109 1 10/30/1911:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-11 Lab ID: 2624501007 Collected: 10/14/19 12:44 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/14/19 12:44 Field pH 6.46 Std. Units 1 10/14/19 12:44 Field Temperature 20.4 deg C 1 10/14/19 12:44 Field Specific 564 umhos/c 1 10/14/19 12:44 Conductance m Field Turbidity 3.41 NTU 1 10/14/19 12:44 Oxygen, Dissolved 6.30 mg/L 1 10/14/19 12:44 7782-44-7 N2 Depth to Water 10.05 feet 1 10/14/19 12:44 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:40 7440-36-0 Arsenic 1.2J ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:40 7440-38-2 B Barium 32.4J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:40 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:40 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:40 7440-43-9 Chromium 4.OJ ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:40 7440-47-3 B Cobalt 1.1J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:40 7440-48-4 Copper 1.3J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:40 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:40 7439-92-1 Nickel 3.1J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:40 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:40 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:40 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:40 7440-28-0 Vanadium 6.8J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:40 7440-62-2 B Zinc 6.8J ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:40 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:32 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 16:06 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 16:06 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 16:06 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 16:06 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 16:06 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 16:06 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 16:06 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 16:06 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 16:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 16:06 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 16:06 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 16:06 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 16:06 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 16:06 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 16:06 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-11 Lab ID: 2624501007 Collected: 10/14/19 12:44 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1916:06 124-48-1 ND ug/L 2.0 0.28 1 10/26/1916:06 106-93-4 ND ug/L 10.0 0.62 1 10/26/1916:06 74-95-3 ND ug/L 5.0 0.49 1 10/26/1916:06 95-50-1 ND ug/L 1.0 0.58 1 10/26/1916:06 106-46-7 ND ug/L 100 1.6 1 10/26/1916:06 110-57-6 ND ug/L 5.0 0.41 1 10/26/1916:06 75-34-3 ND ug/L 1.0 0.67 1 10/26/1916:06 107-06-2 ND ug/L 5.0 0.72 1 10/26/1916:06 75-35-4 ND ug/L 5.0 0.66 1 10/26/1916:06 156-59-2 ND ug/L 5.0 0.46 1 10/26/1916:06 156-60-5 ND ug/L 1.0 0.60 1 10/26/1916:06 78-87-5 ND ug/L 1.0 0.22 1 10/26/1916:06 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1916:06 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1916:06 100-41-4 ND ug/L 50.0 0.89 1 10/26/1916:06 591-78-6 ND ug/L 10.0 3.1 1 10/26/1916:06 74-88-4 ND ug/L 1.0 0.50 1 10/26/1916:06 75-09-2 ND ug/L 100 0.86 1 10/26/1916:06 108-10-1 ND ug/L 1.0 0.50 1 10/26/1916:06 100-42-5 ND ug/L 5.0 0.32 1 10/26/1916:06 630-20-6 ND ug/L 3.0 0.53 1 10/26/1916:06 79-34-5 ND ug/L 1.0 0.78 1 10/26/1916:06 127-18-4 ND ug/L 1.0 0.31 1 10/26/1916:06 108-88-3 ND ug/L 1.0 0.38 1 10/26/1916:06 71-55-6 ND ug/L 1.0 0.59 1 10/26/1916:06 79-00-5 ND ug/L 1.0 0.34 1 10/26/1916:06 79-01-6 ND ug/L 1.0 0.51 1 10/26/1916:06 75-69-4 ND ug/L 1.0 0.46 1 10/26/1916:06 96-18-4 ND ug/L 50.0 0.42 1 10/26/1916:06 108-05-4 ND ug/L 1.0 0.60 1 10/26/1916:06 75-01-4 ND ug/L 5.0 1.5 1 10/26/1916:06 1330-20-7 108 %. 81-119 1 10/26/1916:06 17060-07-0 106 %. 82-114 1 10/26/1916:06 1868-53-7 108 %. 82-120 1 10/26/1916:06 460-00-4 108 %. 82-109 1 10/26/1916:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 22 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-12 Lab ID: 2624501008 Collected: 10/14/19 13:22 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/14/19 13:22 Field pH 6.34 Std. Units 1 10/14/19 13:22 Field Temperature 17.8 deg C 1 10/14/19 13:22 Field Specific 433 umhos/c 1 10/14/19 13:22 Conductance m Field Turbidity 2.30 NTU 1 10/14/19 13:22 Oxygen, Dissolved 7.71 mg/L 1 10/14/19 13:22 7782-44-7 N2 Depth to Water 14.73 feet 1 10/14/19 13:22 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/01/19 23:46 7440-36-0 Arsenic 1.5J ug/L 10.0 0.35 1 10/31/19 21:45 11/01/19 23:46 7440-38-2 B Barium 18.6J ug/L 100 0.49 1 10/31/19 21:45 11/01/19 23:46 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/01/19 23:46 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/01/19 23:46 7440-43-9 Chromium 9.5J ug/L 10.0 0.39 1 10/31/19 21:45 11/01/19 23:46 7440-47-3 Cobalt 0.73J ug/L 10.0 0.30 1 10/31/19 21:45 11/01/19 23:46 7440-48-4 Copper 0.46J ug/L 10.0 0.19 1 10/31/19 21:45 11/01/19 23:46 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/01/19 23:46 7439-92-1 Nickel 12.9J ug/L 50.0 0.31 1 10/31/19 21:45 11/01/19 23:46 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/01/19 23:46 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/01/19 23:46 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/01/19 23:46 7440-28-0 Vanadium 8.2J ug/L 25.0 0.71 1 10/31/19 21:45 11/01/19 23:46 7440-62-2 B Zinc 15.2 ug/L 10.0 1.5 1 10/31/19 21:45 11/01/19 23:46 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:34 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 16:31 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 16:31 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 16:31 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 16:31 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 16:31 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 16:31 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 16:31 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 16:31 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 16:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 16:31 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 16:31 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 16:31 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 16:31 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 16:31 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 16:31 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-12 Lab ID: 2624501008 Collected: 10/14/19 13:22 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1916:31 124-48-1 ND ug/L 2.0 0.28 1 10/26/1916:31 106-93-4 ND ug/L 10.0 0.62 1 10/26/1916:31 74-95-3 ND ug/L 5.0 0.49 1 10/26/1916:31 95-50-1 ND ug/L 1.0 0.58 1 10/26/1916:31 106-46-7 ND ug/L 100 1.6 1 10/26/1916:31 110-57-6 ND ug/L 5.0 0.41 1 10/26/1916:31 75-34-3 ND ug/L 1.0 0.67 1 10/26/1916:31 107-06-2 ND ug/L 5.0 0.72 1 10/26/1916:31 75-35-4 ND ug/L 5.0 0.66 1 10/26/1916:31 156-59-2 ND ug/L 5.0 0.46 1 10/26/1916:31 156-60-5 ND ug/L 1.0 0.60 1 10/26/1916:31 78-87-5 ND ug/L 1.0 0.22 1 10/26/1916:31 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1916:31 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1916:31 100-41-4 ND ug/L 50.0 0.89 1 10/26/1916:31 591-78-6 ND ug/L 10.0 3.1 1 10/26/1916:31 74-88-4 ND ug/L 1.0 0.50 1 10/26/1916:31 75-09-2 ND ug/L 100 0.86 1 10/26/1916:31 108-10-1 ND ug/L 1.0 0.50 1 10/26/1916:31 100-42-5 ND ug/L 5.0 0.32 1 10/26/1916:31 630-20-6 ND ug/L 3.0 0.53 1 10/26/1916:31 79-34-5 ND ug/L 1.0 0.78 1 10/26/1916:31 127-18-4 ND ug/L 1.0 0.31 1 10/26/1916:31 108-88-3 ND ug/L 1.0 0.38 1 10/26/1916:31 71-55-6 ND ug/L 1.0 0.59 1 10/26/1916:31 79-00-5 ND ug/L 1.0 0.34 1 10/26/1916:31 79-01-6 ND ug/L 1.0 0.51 1 10/26/1916:31 75-69-4 ND ug/L 1.0 0.46 1 10/26/1916:31 96-18-4 ND ug/L 50.0 0.42 1 10/26/1916:31 108-05-4 ND ug/L 1.0 0.60 1 10/26/1916:31 75-01-4 ND ug/L 5.0 1.5 1 10/26/1916:31 1330-20-7 106 %. 81-119 1 10/26/1916:31 17060-07-0 105 %. 82-114 1 10/26/1916:31 1868-53-7 107 %. 82-120 1 10/26/1916:31 460-00-4 107 %. 82-109 1 10/26/1916:31 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-14 Lab ID: 2624501009 Collected: 10/16/19 09:26 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/16/19 09:26 Field pH 6.43 Std. Units 1 10/16/19 09:26 Field Temperature 19.4 deg C 1 10/16/19 09:26 Field Specific 663 umhos/c 1 10/16/19 09:26 Conductance m Field Turbidity 0.72 NTU 1 10/16/19 09:26 Oxygen, Dissolved 6.81 mg/L 1 10/16/19 09:26 7782-44-7 N2 Depth to Water 10.62 feet 1 10/16/19 09:26 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/02/19 00:03 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:45 11/02/19 00:03 7440-38-2 Barium 9.OJ ug/L 100 0.49 1 10/31/19 21:45 11/02/19 00:03 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/02/19 00:03 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/02/19 00:03 7440-43-9 Chromium 1.3J ug/L 10.0 0.39 1 10/31/19 21:45 11/02/19 00:03 7440-47-3 B Cobalt 0.50J ug/L 10.0 0.30 1 10/31/19 21:45 11/02/19 00:03 7440-48-4 Copper 2.6J ug/L 10.0 0.19 1 10/31/19 21:45 11/02/19 00:03 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/02/19 00:03 7439-92-1 Nickel 23.5J ug/L 50.0 0.31 1 10/31/19 21:45 11/02/19 00:03 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/02/19 00:03 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/02/19 00:03 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/02/19 00:03 7440-28-0 Vanadium 5.2J ug/L 25.0 0.71 1 10/31/19 21:45 11/02/19 00:03 7440-62-2 B Zinc 10.5 ug/L 10.0 1.5 1 10/31/19 21:45 11/02/19 00:03 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:36 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 12:20 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 12:20 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 12:20 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 12:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 12:20 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 12:20 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 12:20 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 12:20 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 12:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 12:20 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 12:20 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 12:20 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 12:20 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 12:20 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 12:20 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-14 Lab ID: 2624501009 Collected: 10/16/19 09:26 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1912:20 124-48-1 ND ug/L 2.0 0.28 1 10/30/1912:20 106-93-4 ND ug/L 10.0 0.62 1 10/30/1912:20 74-95-3 ND ug/L 5.0 0.49 1 10/30/1912:20 95-50-1 ND ug/L 1.0 0.58 1 10/30/1912:20 106-46-7 ND ug/L 100 1.6 1 10/30/1912:20 110-57-6 ND ug/L 5.0 0.41 1 10/30/1912:20 75-34-3 ND ug/L 1.0 0.67 1 10/30/1912:20 107-06-2 ND ug/L 5.0 0.72 1 10/30/1912:20 75-35-4 ND ug/L 5.0 0.66 1 10/30/1912:20 156-59-2 ND ug/L 5.0 0.46 1 10/30/1912:20 156-60-5 ND ug/L 1.0 0.60 1 10/30/1912:20 78-87-5 ND ug/L 1.0 0.22 1 10/30/1912:20 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1912:20 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1912:20 100-41-4 ND ug/L 50.0 0.89 1 10/30/1912:20 591-78-6 ND ug/L 10.0 3.1 1 10/30/1912:20 74-88-4 ND ug/L 1.0 0.50 1 10/30/1912:20 75-09-2 ND ug/L 100 0.86 1 10/30/1912:20 108-10-1 ND ug/L 1.0 0.50 1 10/30/1912:20 100-42-5 ND ug/L 5.0 0.32 1 10/30/1912:20 630-20-6 ND ug/L 3.0 0.53 1 10/30/1912:20 79-34-5 ND ug/L 1.0 0.78 1 10/30/1912:20 127-18-4 ND ug/L 1.0 0.31 1 10/30/1912:20 108-88-3 ND ug/L 1.0 0.38 1 10/30/1912:20 71-55-6 ND ug/L 1.0 0.59 1 10/30/1912:20 79-00-5 ND ug/L 1.0 0.34 1 10/30/1912:20 79-01-6 ND ug/L 1.0 0.51 1 10/30/1912:20 75-69-4 ND ug/L 1.0 0.46 1 10/30/1912:20 96-18-4 ND ug/L 50.0 0.42 1 10/30/1912:20 108-05-4 ND ug/L 1.0 0.60 1 10/30/1912:20 75-01-4 ND ug/L 5.0 1.5 1 10/30/1912:20 1330-20-7 102 %. 81-119 1 10/30/1912:20 17060-07-0 101 %. 82-114 1 10/30/1912:20 1868-53-7 106 %. 82-120 1 10/30/1912:20 460-00-4 107 %. 82-109 1 10/30/1912:20 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 26 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-14B Lab ID: 2624501010 Collected: 10/16/19 08:49 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/16/19 08:49 Field pH 6.61 Std. Units 1 10/16/19 08:49 Field Temperature 17.3 deg C 1 10/16/19 08:49 Field Specific 654 umhos/c 1 10/16/19 08:49 Conductance m Field Turbidity 0.79 NTU 1 10/16/19 08:49 Oxygen, Dissolved 8.01 mg/L 1 10/16/19 08:49 7782-44-7 N2 Depth to Water 10.72 feet 1 10/16/19 08:49 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/02/19 00:09 7440-36-0 Arsenic 0.57J ug/L 10.0 0.35 1 10/31/19 21:45 11/02/19 00:09 7440-38-2 B Barium 6.6J ug/L 100 0.49 1 10/31/19 21:45 11/02/19 00:09 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/02/19 00:09 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/02/19 00:09 7440-43-9 Chromium 0.50J ug/L 10.0 0.39 1 10/31/19 21:45 11/02/19 00:09 7440-47-3 B Cobalt ND ug/L 10.0 0.30 1 10/31/19 21:45 11/02/19 00:09 7440-48-4 Copper 0.91J ug/L 10.0 0.19 1 10/31/19 21:45 11/02/19 00:09 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/02/19 00:09 7439-92-1 Nickel 1.4J ug/L 50.0 0.31 1 10/31/19 21:45 11/02/19 00:09 7440-02-0 Selenium 1.3J ug/L 10.0 1.3 1 10/31/19 21:45 11/02/19 00:09 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/02/19 00:09 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/02/19 00:09 7440-28-0 Vanadium 5.8J ug/L 25.0 0.71 1 10/31/19 21:45 11/02/19 00:09 7440-62-2 B Zinc 7.4J ug/L 10.0 1.5 1 10/31/19 21:45 11/02/19 00:09 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:39 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 12:45 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 12:45 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 12:45 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 12:45 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 12:45 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 12:45 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 12:45 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 12:45 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 12:45 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 12:45 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 12:45 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 12:45 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 12:45 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 12:45 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 12:45 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-14B Lab ID: 2624501010 Collected: 10/16/19 08:49 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1912:45 124-48-1 ND ug/L 2.0 0.28 1 10/30/1912:45 106-93-4 ND ug/L 10.0 0.62 1 10/30/1912:45 74-95-3 ND ug/L 5.0 0.49 1 10/30/1912:45 95-50-1 ND ug/L 1.0 0.58 1 10/30/1912:45 106-46-7 ND ug/L 100 1.6 1 10/30/1912:45 110-57-6 ND ug/L 5.0 0.41 1 10/30/1912:45 75-34-3 ND ug/L 1.0 0.67 1 10/30/1912:45 107-06-2 ND ug/L 5.0 0.72 1 10/30/1912:45 75-35-4 ND ug/L 5.0 0.66 1 10/30/1912:45 156-59-2 ND ug/L 5.0 0.46 1 10/30/1912:45 156-60-5 ND ug/L 1.0 0.60 1 10/30/1912:45 78-87-5 ND ug/L 1.0 0.22 1 10/30/1912:45 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1912:45 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1912:45 100-41-4 ND ug/L 50.0 0.89 1 10/30/1912:45 591-78-6 ND ug/L 10.0 3.1 1 10/30/1912:45 74-88-4 ND ug/L 1.0 0.50 1 10/30/1912:45 75-09-2 ND ug/L 100 0.86 1 10/30/1912:45 108-10-1 ND ug/L 1.0 0.50 1 10/30/1912:45 100-42-5 ND ug/L 5.0 0.32 1 10/30/1912:45 630-20-6 ND ug/L 3.0 0.53 1 10/30/1912:45 79-34-5 ND ug/L 1.0 0.78 1 10/30/1912:45 127-18-4 ND ug/L 1.0 0.31 1 10/30/1912:45 108-88-3 ND ug/L 1.0 0.38 1 10/30/1912:45 71-55-6 ND ug/L 1.0 0.59 1 10/30/1912:45 79-00-5 ND ug/L 1.0 0.34 1 10/30/1912:45 79-01-6 ND ug/L 1.0 0.51 1 10/30/1912:45 75-69-4 ND ug/L 1.0 0.46 1 10/30/1912:45 96-18-4 ND ug/L 50.0 0.42 1 10/30/1912:45 108-05-4 ND ug/L 1.0 0.60 1 10/30/1912:45 75-01-4 ND ug/L 5.0 1.5 1 10/30/1912:45 1330-20-7 104 %. 81-119 1 10/30/1912:45 17060-07-0 100 %. 82-114 1 10/30/1912:45 1868-53-7 106 %. 82-120 1 10/30/1912:45 460-00-4 106 %. 82-109 1 10/30/1912:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-15 Lab ID: 2624501011 Collected: 10/16/19 10:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/16/19 10:13 Field pH 6.62 Std. Units 1 10/16/19 10:13 Field Temperature 22.7 deg C 1 10/16/19 10:13 Field Specific 444 umhos/c 1 10/16/19 10:13 Conductance m Field Turbidity 0.95 NTU 1 10/16/19 10:13 Oxygen, Dissolved 5.34 mg/L 1 10/16/19 10:13 7782-44-7 N2 Depth to Water 10.76 feet 1 10/16/19 10:13 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/02/19 00:14 7440-36-0 Arsenic 1.4J ug/L 10.0 0.35 1 10/31/19 21:45 11/02/19 00:14 7440-38-2 B Barium 37.3J ug/L 100 0.49 1 10/31/19 21:45 11/02/19 00:14 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/02/19 00:14 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/02/19 00:14 7440-43-9 Chromium 1.8J ug/L 10.0 0.39 1 10/31/19 21:45 11/02/19 00:14 7440-47-3 B Cobalt ND ug/L 10.0 0.30 1 10/31/19 21:45 11/02/19 00:14 7440-48-4 Copper 1.9J ug/L 10.0 0.19 1 10/31/19 21:45 11/02/19 00:14 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:45 11/02/19 00:14 7439-92-1 Nickel 4.5J ug/L 50.0 0.31 1 10/31/19 21:45 11/02/19 00:14 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/02/19 00:14 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/02/19 00:14 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/02/19 00:14 7440-28-0 Vanadium 11.0J ug/L 25.0 0.71 1 10/31/19 21:45 11/02/19 00:14 7440-62-2 B Zinc 6.5J ug/L 10.0 1.5 1 10/31/19 21:45 11/02/19 00:14 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:41 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 13:11 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 13:11 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 13:11 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 13:11 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 13:11 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 13:11 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 13:11 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 13:11 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 13:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 13:11 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 13:11 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 13:11 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 13:11 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 13:11 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 13:11 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-15 Lab ID: 2624501011 Collected: 10/16/19 10:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1913:11 124-48-1 ND ug/L 2.0 0.28 1 10/30/1913:11 106-93-4 ND ug/L 10.0 0.62 1 10/30/1913:11 74-95-3 ND ug/L 5.0 0.49 1 10/30/1913:11 95-50-1 ND ug/L 1.0 0.58 1 10/30/1913:11 106-46-7 ND ug/L 100 1.6 1 10/30/1913:11 110-57-6 ND ug/L 5.0 0.41 1 10/30/1913:11 75-34-3 ND ug/L 1.0 0.67 1 10/30/1913:11 107-06-2 ND ug/L 5.0 0.72 1 10/30/1913:11 75-35-4 ND ug/L 5.0 0.66 1 10/30/1913:11 156-59-2 ND ug/L 5.0 0.46 1 10/30/1913:11 156-60-5 ND ug/L 1.0 0.60 1 10/30/1913:11 78-87-5 ND ug/L 1.0 0.22 1 10/30/1913:11 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1913:11 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1913:11 100-41-4 ND ug/L 50.0 0.89 1 10/30/1913:11 591-78-6 ND ug/L 10.0 3.1 1 10/30/1913:11 74-88-4 ND ug/L 1.0 0.50 1 10/30/1913:11 75-09-2 ND ug/L 100 0.86 1 10/30/1913:11 108-10-1 ND ug/L 1.0 0.50 1 10/30/1913:11 100-42-5 ND ug/L 5.0 0.32 1 10/30/1913:11 630-20-6 ND ug/L 3.0 0.53 1 10/30/1913:11 79-34-5 ND ug/L 1.0 0.78 1 10/30/1913:11 127-18-4 ND ug/L 1.0 0.31 1 10/30/1913:11 108-88-3 ND ug/L 1.0 0.38 1 10/30/1913:11 71-55-6 ND ug/L 1.0 0.59 1 10/30/1913:11 79-00-5 ND ug/L 1.0 0.34 1 10/30/1913:11 79-01-6 ND ug/L 1.0 0.51 1 10/30/1913:11 75-69-4 ND ug/L 1.0 0.46 1 10/30/1913:11 96-18-4 ND ug/L 50.0 0.42 1 10/30/1913:11 108-05-4 ND ug/L 1.0 0.60 1 10/30/1913:11 75-01-4 ND ug/L 5.0 1.5 1 10/30/1913:11 1330-20-7 106 %. 81-119 1 10/30/1913:11 17060-07-0 101 %. 82-114 1 10/30/1913:11 1868-53-7 106 %. 82-120 1 10/30/1913:11 460-00-4 104 %. 82-109 1 10/30/1913:11 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 30 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-16 Lab ID: 2624501012 Collected: 10/16/19 11:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/16/19 11:05 Field pH 6.56 Std. Units 1 10/16/19 11:05 Field Temperature 17.6 deg C 1 10/16/19 11:05 Field Specific 680 umhos/c 1 10/16/19 11:05 Conductance m Field Turbidity 5.10 NTU 1 10/16/19 11:05 Oxygen, Dissolved 7.85 mg/L 1 10/16/19 11:05 7782-44-7 N2 Depth to Water 16.08 feet 1 10/16/19 11:05 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:45 11/02/19 00:20 7440-36-0 Arsenic 1.6J ug/L 10.0 0.35 1 10/31/19 21:45 11/02/19 00:20 7440-38-2 B Barium 59.5J ug/L 100 0.49 1 10/31/19 21:45 11/02/19 00:20 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:45 11/02/19 00:20 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:45 11/02/19 00:20 7440-43-9 Chromium 6.2J ug/L 10.0 0.39 1 10/31/19 21:45 11/02/19 00:20 7440-47-3 B Cobalt 10.8 ug/L 10.0 0.30 1 10/31/19 21:45 11/02/19 00:20 7440-48-4 Copper 4.3J ug/L 10.0 0.19 1 10/31/19 21:45 11/02/19 00:20 7440-50-8 Lead 2.3J ug/L 10.0 0.046 1 10/31/19 21:45 11/02/19 00:20 7439-92-1 Nickel 6.7J ug/L 50.0 0.31 1 10/31/19 21:45 11/02/19 00:20 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:45 11/02/19 00:20 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:45 11/02/19 00:20 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:45 11/02/19 00:20 7440-28-0 Vanadium 17.9J ug/L 25.0 0.71 1 10/31/19 21:45 11/02/19 00:20 7440-62-2 Zinc 22.1 ug/L 10.0 1.5 1 10/31/19 21:45 11/02/19 00:20 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:43 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 13:36 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 13:36 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 13:36 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 13:36 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 13:36 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 13:36 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 13:36 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 13:36 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 13:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 13:36 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 13:36 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 13:36 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 13:36 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 13:36 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 13:36 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-16 Lab ID: 2624501012 Collected: 10/16/19 11:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1913:36 124-48-1 ND ug/L 2.0 0.28 1 10/30/1913:36 106-93-4 ND ug/L 10.0 0.62 1 10/30/1913:36 74-95-3 ND ug/L 5.0 0.49 1 10/30/1913:36 95-50-1 ND ug/L 1.0 0.58 1 10/30/1913:36 106-46-7 ND ug/L 100 1.6 1 10/30/1913:36 110-57-6 ND ug/L 5.0 0.41 1 10/30/1913:36 75-34-3 ND ug/L 1.0 0.67 1 10/30/1913:36 107-06-2 ND ug/L 5.0 0.72 1 10/30/1913:36 75-35-4 ND ug/L 5.0 0.66 1 10/30/1913:36 156-59-2 ND ug/L 5.0 0.46 1 10/30/1913:36 156-60-5 ND ug/L 1.0 0.60 1 10/30/1913:36 78-87-5 ND ug/L 1.0 0.22 1 10/30/1913:36 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1913:36 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1913:36 100-41-4 ND ug/L 50.0 0.89 1 10/30/1913:36 591-78-6 ND ug/L 10.0 3.1 1 10/30/1913:36 74-88-4 ND ug/L 1.0 0.50 1 10/30/1913:36 75-09-2 ND ug/L 100 0.86 1 10/30/1913:36 108-10-1 ND ug/L 1.0 0.50 1 10/30/1913:36 100-42-5 ND ug/L 5.0 0.32 1 10/30/1913:36 630-20-6 ND ug/L 3.0 0.53 1 10/30/1913:36 79-34-5 ND ug/L 1.0 0.78 1 10/30/1913:36 127-18-4 ND ug/L 1.0 0.31 1 10/30/1913:36 108-88-3 ND ug/L 1.0 0.38 1 10/30/1913:36 71-55-6 ND ug/L 1.0 0.59 1 10/30/1913:36 79-00-5 ND ug/L 1.0 0.34 1 10/30/1913:36 79-01-6 ND ug/L 1.0 0.51 1 10/30/1913:36 75-69-4 ND ug/L 1.0 0.46 1 10/30/1913:36 96-18-4 ND ug/L 50.0 0.42 1 10/30/1913:36 108-05-4 ND ug/L 1.0 0.60 1 10/30/1913:36 75-01-4 ND ug/L 5.0 1.5 1 10/30/1913:36 1330-20-7 104 %. 81-119 1 10/30/1913:36 17060-07-0 100 %. 82-114 1 10/30/1913:36 1868-53-7 105 %. 82-120 1 10/30/1913:36 460-00-4 105 %. 82-109 1 10/30/1913:36 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-18A Lab ID: 2624501013 Collected: 10/15/19 15:14 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: James 1 10/15/19 15:14 5.94 Std. Units 1 10/15/19 15:14 21.2 deg C 1 10/15/19 15:14 1845 umhos/c 1 10/15/19 15:14 m 1.60 NTU 1 10/15/19 15:14 5.89 mg/L 1 10/15/19 15:14 7782-44-7 17.70 feet 1 10/15/19 15:14 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:45 11/02/19 00:26 7440-36-0 1.5J ug/L 10.0 0.35 1 10/31/19 21:45 11/02/19 00:26 7440-38-2 718 ug/L 100 0.49 1 10/31/19 21:45 11/02/19 00:26 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:45 11/02/19 00:26 7440-41-7 0.49J ug/L 1.0 0.11 1 10/31/19 21:45 11/02/19 00:26 7440-43-9 5.OJ ug/L 10.0 0.39 1 10/31/19 21:45 11/02/19 00:26 7440-47-3 18.6 ug/L 10.0 0.30 1 10/31/19 21:45 11/02/19 00:26 7440-48-4 11.0 ug/L 10.0 0.19 1 10/31/19 21:45 11/02/19 00:26 7440-50-8 0.11J ug/L 10.0 0.046 1 10/31/19 21:45 11/02/19 00:26 7439-92-1 12.1J ug/L 50.0 0.31 1 10/31/19 21:45 11/02/19 00:26 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:45 11/02/19 00:26 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:45 11/02/19 00:26 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:45 11/02/19 00:26 7440-28-0 ND ug/L 25.0 0.71 1 10/31/19 21:45 11/02/19 00:26 7440-62-2 42.6 ug/L 10.0 1.5 1 10/31/19 21:45 11/02/19 00:26 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N 0.83 N N N N N N N 1.6 N N N ND D ug/L 100 D ug/L 200 J ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 100 D ug/L 100 D ug/L 1.0 J ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 ug/L 2.0 0.14 1 11/05/1912:43 11/05/1917:46 7439-97-6 8.2 1 10/26/19 16:57 67-64-1 2.5 1 10/26/19 16:57 107-13-1 0.20 1 10/26/19 16:57 71-43-2 0.50 1 10/26/19 16:57 74-97-5 0.36 1 10/26/19 16:57 75-27-4 0.55 1 10/26/19 16:57 75-25-2 0.95 1 10/26/19 16:57 74-83-9 3.2 1 10/26/19 16:57 78-93-3 0.79 1 10/26/19 16:57 75-15-0 0.42 1 10/26/19 16:57 56-23-5 0.53 1 10/26/19 16:57 108-90-7 0.52 1 10/26/19 16:57 75-00-3 0.58 1 10/26/19 16:57 67-66-3 0.38 1 10/26/19 16:57 74-87-3 0.55 1 10/26/19 16:57 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B B B Page 33 of 157 0.14 1 11/05/1912:43 11/05/1917:46 7439-97-6 8.2 1 10/26/19 16:57 67-64-1 2.5 1 10/26/19 16:57 107-13-1 0.20 1 10/26/19 16:57 71-43-2 0.50 1 10/26/19 16:57 74-97-5 0.36 1 10/26/19 16:57 75-27-4 0.55 1 10/26/19 16:57 75-25-2 0.95 1 10/26/19 16:57 74-83-9 3.2 1 10/26/19 16:57 78-93-3 0.79 1 10/26/19 16:57 75-15-0 0.42 1 10/26/19 16:57 56-23-5 0.53 1 10/26/19 16:57 108-90-7 0.52 1 10/26/19 16:57 75-00-3 0.58 1 10/26/19 16:57 67-66-3 0.38 1 10/26/19 16:57 74-87-3 0.55 1 10/26/19 16:57 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B B B Page 33 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B B B Page 33 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-18A Lab ID: 2624501013 Collected: 10/15/19 15:14 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1916:57 124-48-1 ND ug/L 2.0 0.28 1 10/26/1916:57 106-93-4 ND ug/L 10.0 0.62 1 10/26/1916:57 74-95-3 ND ug/L 5.0 0.49 1 10/26/1916:57 95-50-1 2.5 ug/L 1.0 0.58 1 10/26/1916:57 106-46-7 ND ug/L 100 1.6 1 10/26/1916:57 110-57-6 ND ug/L 5.0 0.41 1 10/26/1916:57 75-34-3 ND ug/L 1.0 0.67 1 10/26/1916:57 107-06-2 ND ug/L 5.0 0.72 1 10/26/1916:57 75-35-4 ND ug/L 5.0 0.66 1 10/26/1916:57 156-59-2 ND ug/L 5.0 0.46 1 10/26/1916:57 156-60-5 ND ug/L 1.0 0.60 1 10/26/1916:57 78-87-5 ND ug/L 1.0 0.22 1 10/26/1916:57 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1916:57 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1916:57 100-41-4 ND ug/L 50.0 0.89 1 10/26/1916:57 591-78-6 ND ug/L 10.0 3.1 1 10/26/1916:57 74-88-4 ND ug/L 1.0 0.50 1 10/26/1916:57 75-09-2 ND ug/L 100 0.86 1 10/26/1916:57 108-10-1 ND ug/L 1.0 0.50 1 10/26/1916:57 100-42-5 ND ug/L 5.0 0.32 1 10/26/1916:57 630-20-6 ND ug/L 3.0 0.53 1 10/26/1916:57 79-34-5 ND ug/L 1.0 0.78 1 10/26/1916:57 127-18-4 ND ug/L 1.0 0.31 1 10/26/1916:57 108-88-3 ND ug/L 1.0 0.38 1 10/26/1916:57 71-55-6 ND ug/L 1.0 0.59 1 10/26/1916:57 79-00-5 ND ug/L 1.0 0.34 1 10/26/1916:57 79-01-6 ND ug/L 1.0 0.51 1 10/26/1916:57 75-69-4 ND ug/L 1.0 0.46 1 10/26/1916:57 96-18-4 ND ug/L 50.0 0.42 1 10/26/1916:57 108-05-4 ND ug/L 1.0 0.60 1 10/26/1916:57 75-01-4 ND ug/L 5.0 1.5 1 10/26/1916:57 1330-20-7 107 %. 81-119 1 10/26/1916:57 17060-07-0 108 %. 82-114 1 10/26/1916:57 1868-53-7 109 %. 82-120 1 10/26/1916:57 460-00-4 108 %. 82-109 1 10/26/1916:57 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 34 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19 Lab ID: 2624501014 Collected: 10/15/19 10:41 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/15/19 10:41 Field pH 6.29 Std. Units 1 10/15/19 10:41 Field Temperature 19.0 deg C 1 10/15/19 10:41 Field Specific 1197 umhos/c 1 10/15/19 10:41 Conductance m Field Turbidity 1.45 NTU 1 10/15/19 10:41 Oxygen, Dissolved 6.81 mg/L 1 10/15/19 10:41 7782-44-7 N2 Depth to Water 28.31 feet 1 10/15/19 10:41 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 19:27 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 19:27 7440-38-2 Barium 372 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 19:27 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 19:27 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 19:27 7440-43-9 Chromium ND ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 19:27 7440-47-3 Cobalt 2.2J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 19:27 7440-48-4 Copper 1.1J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 19:27 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 19:27 7439-92-1 Nickel 75.4 ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 19:27 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 19:27 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 19:27 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 19:27 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 19:27 7440-62-2 Zinc 5.9J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 19:27 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:48 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 17:22 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 17:22 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 17:22 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 17:22 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 17:22 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 17:22 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 17:22 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 17:22 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 17:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 17:22 56-23-5 Chlorobenzene 1.5J ug/L 3.0 0.53 1 10/26/19 17:22 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 17:22 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 17:22 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 17:22 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 17:22 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19 Lab ID: 2624501014 Collected: 10/15/19 10:41 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1917:22 124-48-1 ND ug/L 2.0 0.28 1 10/26/1917:22 106-93-4 ND ug/L 10.0 0.62 1 10/26/1917:22 74-95-3 ND ug/L 5.0 0.49 1 10/26/1917:22 95-50-1 2.6 ug/L 1.0 0.58 1 10/26/1917:22 106-46-7 ND ug/L 100 1.6 1 10/26/1917:22 110-57-6 ND ug/L 5.0 0.41 1 10/26/1917:22 75-34-3 ND ug/L 1.0 0.67 1 10/26/1917:22 107-06-2 ND ug/L 5.0 0.72 1 10/26/1917:22 75-35-4 ND ug/L 5.0 0.66 1 10/26/1917:22 156-59-2 ND ug/L 5.0 0.46 1 10/26/1917:22 156-60-5 ND ug/L 1.0 0.60 1 10/26/1917:22 78-87-5 ND ug/L 1.0 0.22 1 10/26/1917:22 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1917:22 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1917:22 100-41-4 ND ug/L 50.0 0.89 1 10/26/1917:22 591-78-6 ND ug/L 10.0 3.1 1 10/26/1917:22 74-88-4 ND ug/L 1.0 0.50 1 10/26/1917:22 75-09-2 ND ug/L 100 0.86 1 10/26/1917:22 108-10-1 ND ug/L 1.0 0.50 1 10/26/1917:22 100-42-5 ND ug/L 5.0 0.32 1 10/26/1917:22 630-20-6 ND ug/L 3.0 0.53 1 10/26/1917:22 79-34-5 ND ug/L 1.0 0.78 1 10/26/1917:22 127-18-4 ND ug/L 1.0 0.31 1 10/26/1917:22 108-88-3 ND ug/L 1.0 0.38 1 10/26/1917:22 71-55-6 ND ug/L 1.0 0.59 1 10/26/1917:22 79-00-5 ND ug/L 1.0 0.34 1 10/26/1917:22 79-01-6 ND ug/L 1.0 0.51 1 10/26/1917:22 75-69-4 ND ug/L 1.0 0.46 1 10/26/1917:22 96-18-4 ND ug/L 50.0 0.42 1 10/26/1917:22 108-05-4 ND ug/L 1.0 0.60 1 10/26/1917:22 75-01-4 ND ug/L 5.0 1.5 1 10/26/1917:22 1330-20-7 110 %. 81-119 1 10/26/1917:22 17060-07-0 105 %. 82-114 1 10/26/1917:22 1868-53-7 109 %. 82-120 1 10/26/1917:22 460-00-4 106 %. 82-109 1 10/26/1917:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19A Lab ID: 2624501015 Collected: 10/15/19 12:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/15/19 12:24 Field pH 6.97 Std. Units 1 10/15/19 12:24 Field Temperature 19.1 deg C 1 10/15/19 12:24 Field Specific 1049 umhos/c 1 10/15/19 12:24 Conductance m Field Turbidity 1.51 NTU 1 10/15/19 12:24 Oxygen, Dissolved 6.66 mg/L 1 10/15/19 12:24 7782-44-7 N2 Depth to Water 27.71 feet 1 10/15/19 12:24 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 19:50 7440-36-0 Arsenic 0.46J ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 19:50 7440-38-2 Barium 215 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 19:50 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 19:50 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 19:50 7440-43-9 Chromium ND ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 19:50 7440-47-3 Cobalt 9.3J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 19:50 7440-48-4 Copper 0.98J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 19:50 7440-50-8 Lead 0.049J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 19:50 7439-92-1 Nickel 30.3J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 19:50 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 19:50 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 19:50 7440-22-4 Thallium 0.060J ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 19:50 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 19:50 7440-62-2 Zinc 76.9 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 19:50 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1917:55 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 17:47 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 17:47 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 17:47 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 17:47 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 17:47 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 17:47 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 17:47 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 17:47 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 17:47 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 17:47 56-23-5 Chlorobenzene 1.OJ ug/L 3.0 0.53 1 10/26/19 17:47 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 17:47 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 17:47 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 17:47 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 17:47 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19A Lab ID: 2624501015 Collected: 10/15/19 12:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1917:47 124-48-1 ND ug/L 2.0 0.28 1 10/26/1917:47 106-93-4 ND ug/L 10.0 0.62 1 10/26/1917:47 74-95-3 ND ug/L 5.0 0.49 1 10/26/1917:47 95-50-1 2.2 ug/L 1.0 0.58 1 10/26/1917:47 106-46-7 ND ug/L 100 1.6 1 10/26/1917:47 110-57-6 ND ug/L 5.0 0.41 1 10/26/1917:47 75-34-3 ND ug/L 1.0 0.67 1 10/26/1917:47 107-06-2 ND ug/L 5.0 0.72 1 10/26/1917:47 75-35-4 ND ug/L 5.0 0.66 1 10/26/1917:47 156-59-2 ND ug/L 5.0 0.46 1 10/26/1917:47 156-60-5 ND ug/L 1.0 0.60 1 10/26/1917:47 78-87-5 ND ug/L 1.0 0.22 1 10/26/1917:47 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1917:47 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1917:47 100-41-4 ND ug/L 50.0 0.89 1 10/26/1917:47 591-78-6 ND ug/L 10.0 3.1 1 10/26/1917:47 74-88-4 ND ug/L 1.0 0.50 1 10/26/1917:47 75-09-2 ND ug/L 100 0.86 1 10/26/1917:47 108-10-1 ND ug/L 1.0 0.50 1 10/26/1917:47 100-42-5 ND ug/L 5.0 0.32 1 10/26/1917:47 630-20-6 ND ug/L 3.0 0.53 1 10/26/1917:47 79-34-5 ND ug/L 1.0 0.78 1 10/26/1917:47 127-18-4 ND ug/L 1.0 0.31 1 10/26/1917:47 108-88-3 ND ug/L 1.0 0.38 1 10/26/1917:47 71-55-6 ND ug/L 1.0 0.59 1 10/26/1917:47 79-00-5 ND ug/L 1.0 0.34 1 10/26/1917:47 79-01-6 ND ug/L 1.0 0.51 1 10/26/1917:47 75-69-4 ND ug/L 1.0 0.46 1 10/26/1917:47 96-18-4 ND ug/L 50.0 0.42 1 10/26/1917:47 108-05-4 ND ug/L 1.0 0.60 1 10/26/1917:47 75-01-4 ND ug/L 5.0 1.5 1 10/26/1917:47 1330-20-7 105 %. 81-119 1 10/26/1917:47 17060-07-0 104 %. 82-114 1 10/26/1917:47 1868-53-7 107 %. 82-120 1 10/26/1917:47 460-00-4 108 %. 82-109 1 10/26/1917:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19AR Lab ID: 2624501016 Collected: 10/15/19 14:03 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: James 1 10/15/19 14:03 6.43 Std. Units 1 10/15/19 14:03 20.0 deg C 1 10/15/19 14:03 1692 umhos/c 1 10/15/19 14:03 m 3.41 NTU 1 10/15/19 14:03 6.51 mg/L 1 10/15/19 14:03 7782-44-7 25.27 feet 1 10/15/19 14:03 Analytical Method: EPA 6020B Preparation Method: EPA 3005A 0.53J ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 19:55 7440-36-0 0.40J ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 19:55 7440-38-2 189 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 19:55 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 19:55 7440-41-7 0.52J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 19:55 7440-43-9 7.8J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 19:55 7440-47-3 12.0 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 19:55 7440-48-4 7.9J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 19:55 7440-50-8 0.20J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 19:55 7439-92-1 26.OJ ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 19:55 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 19:55 7782-49-2 0.93J ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 19:55 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 19:55 7440-28-0 ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 19:55 7440-62-2 21.2 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 19:55 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D 9.5 N N N N N N N N N 0.99 N N N ND J ug/L 100 D ug/L 200 D ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 100 D ug/L 100 D ug/L 1.0 J ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 ug/L 2.0 0.14 1 11/05/1912:43 11/05/1917:58 7439-97-6 8.2 1 10/26/19 18:13 67-64-1 2.5 1 10/26/19 18:13 107-13-1 0.20 1 10/26/19 18:13 71-43-2 0.50 1 10/26/19 18:13 74-97-5 0.36 1 10/26/19 18:13 75-27-4 0.55 1 10/26/19 18:13 75-25-2 0.95 1 10/26/19 18:13 74-83-9 3.2 1 10/26/19 18:13 78-93-3 0.79 1 10/26/19 18:13 75-15-0 0.42 1 10/26/19 18:13 56-23-5 0.53 1 10/26/19 18:13 108-90-7 0.52 1 10/26/19 18:13 75-00-3 0.58 1 10/26/19 18:13 67-66-3 0.38 1 10/26/19 18:13 74-87-3 0.55 1 10/26/19 18:13 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 39 of 157 0.14 1 11/05/1912:43 11/05/1917:58 7439-97-6 8.2 1 10/26/19 18:13 67-64-1 2.5 1 10/26/19 18:13 107-13-1 0.20 1 10/26/19 18:13 71-43-2 0.50 1 10/26/19 18:13 74-97-5 0.36 1 10/26/19 18:13 75-27-4 0.55 1 10/26/19 18:13 75-25-2 0.95 1 10/26/19 18:13 74-83-9 3.2 1 10/26/19 18:13 78-93-3 0.79 1 10/26/19 18:13 75-15-0 0.42 1 10/26/19 18:13 56-23-5 0.53 1 10/26/19 18:13 108-90-7 0.52 1 10/26/19 18:13 75-00-3 0.58 1 10/26/19 18:13 67-66-3 0.38 1 10/26/19 18:13 74-87-3 0.55 1 10/26/19 18:13 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 39 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 39 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19AR Lab ID: 2624501016 Collected: 10/15/19 14:03 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1918:13 124-48-1 ND ug/L 2.0 0.28 1 10/26/1918:13 106-93-4 ND ug/L 10.0 0.62 1 10/26/1918:13 74-95-3 ND ug/L 5.0 0.49 1 10/26/1918:13 95-50-1 2.9 ug/L 1.0 0.58 1 10/26/1918:13 106-46-7 ND ug/L 100 1.6 1 10/26/1918:13 110-57-6 ND ug/L 5.0 0.41 1 10/26/1918:13 75-34-3 ND ug/L 1.0 0.67 1 10/26/1918:13 107-06-2 ND ug/L 5.0 0.72 1 10/26/1918:13 75-35-4 ND ug/L 5.0 0.66 1 10/26/1918:13 156-59-2 ND ug/L 5.0 0.46 1 10/26/1918:13 156-60-5 ND ug/L 1.0 0.60 1 10/26/1918:13 78-87-5 ND ug/L 1.0 0.22 1 10/26/1918:13 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1918:13 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1918:13 100-41-4 ND ug/L 50.0 0.89 1 10/26/1918:13 591-78-6 ND ug/L 10.0 3.1 1 10/26/1918:13 74-88-4 ND ug/L 1.0 0.50 1 10/26/1918:13 75-09-2 ND ug/L 100 0.86 1 10/26/1918:13 108-10-1 ND ug/L 1.0 0.50 1 10/26/1918:13 100-42-5 ND ug/L 5.0 0.32 1 10/26/1918:13 630-20-6 ND ug/L 3.0 0.53 1 10/26/1918:13 79-34-5 ND ug/L 1.0 0.78 1 10/26/1918:13 127-18-4 ND ug/L 1.0 0.31 1 10/26/1918:13 108-88-3 ND ug/L 1.0 0.38 1 10/26/1918:13 71-55-6 ND ug/L 1.0 0.59 1 10/26/1918:13 79-00-5 ND ug/L 1.0 0.34 1 10/26/1918:13 79-01-6 ND ug/L 1.0 0.51 1 10/26/1918:13 75-69-4 ND ug/L 1.0 0.46 1 10/26/1918:13 96-18-4 ND ug/L 50.0 0.42 1 10/26/1918:13 108-05-4 ND ug/L 1.0 0.60 1 10/26/1918:13 75-01-4 ND ug/L 5.0 1.5 1 10/26/1918:13 1330-20-7 106 %. 81-119 1 10/26/1918:13 17060-07-0 106 %. 82-114 1 10/26/1918:13 1868-53-7 107 %. 82-120 1 10/26/1918:13 460-00-4 107 %. 82-109 1 10/26/1918:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19R Lab ID: 2624501017 Collected: 10/15/19 14:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: James 1 10/15/19 14:24 6.17 Std. Units 1 10/15/19 14:24 17.7 deg C 1 10/15/19 14:24 1457 umhos/c 1 10/15/19 14:24 m 2.89 NTU 1 10/15/19 14:24 7.73 mg/L 1 10/15/19 14:24 7782-44-7 23.27 feet 1 10/15/19 14:24 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:01 7440-36-0 ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:01 7440-38-2 450 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:01 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:01 7440-41-7 0.36J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:01 7440-43-9 0.70J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:01 7440-47-3 14.3 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:01 7440-48-4 5.8J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:01 7440-50-8 0.072J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:01 7439-92-1 20.3J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:01 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:01 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:01 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:01 7440-28-0 ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:01 7440-62-2 12.4 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:01 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N N N N N N N N N 0.89 N N N ND D ug/L 100 D ug/L 200 D ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 100 D ug/L 100 D ug/L 1.0 J ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 ug/L 2.0 0.14 1 11/05/1912:43 11/05/1918:00 7439-97-6 8.2 1 10/26/19 18:38 67-64-1 2.5 1 10/26/19 18:38 107-13-1 0.20 1 10/26/19 18:38 71-43-2 0.50 1 10/26/19 18:38 74-97-5 0.36 1 10/26/19 18:38 75-27-4 0.55 1 10/26/19 18:38 75-25-2 0.95 1 10/26/19 18:38 74-83-9 3.2 1 10/26/19 18:38 78-93-3 0.79 1 10/26/19 18:38 75-15-0 0.42 1 10/26/19 18:38 56-23-5 0.53 1 10/26/19 18:38 108-90-7 0.52 1 10/26/19 18:38 75-00-3 0.58 1 10/26/19 18:38 67-66-3 0.38 1 10/26/19 18:38 74-87-3 0.55 1 10/26/19 18:38 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 41 of 157 0.14 1 11/05/1912:43 11/05/1918:00 7439-97-6 8.2 1 10/26/19 18:38 67-64-1 2.5 1 10/26/19 18:38 107-13-1 0.20 1 10/26/19 18:38 71-43-2 0.50 1 10/26/19 18:38 74-97-5 0.36 1 10/26/19 18:38 75-27-4 0.55 1 10/26/19 18:38 75-25-2 0.95 1 10/26/19 18:38 74-83-9 3.2 1 10/26/19 18:38 78-93-3 0.79 1 10/26/19 18:38 75-15-0 0.42 1 10/26/19 18:38 56-23-5 0.53 1 10/26/19 18:38 108-90-7 0.52 1 10/26/19 18:38 75-00-3 0.58 1 10/26/19 18:38 67-66-3 0.38 1 10/26/19 18:38 74-87-3 0.55 1 10/26/19 18:38 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 41 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 41 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-19R Lab ID: 2624501017 Collected: 10/15/19 14:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1918:38 124-48-1 ND ug/L 2.0 0.28 1 10/26/1918:38 106-93-4 ND ug/L 10.0 0.62 1 10/26/1918:38 74-95-3 ND ug/L 5.0 0.49 1 10/26/1918:38 95-50-1 2.5 ug/L 1.0 0.58 1 10/26/1918:38 106-46-7 ND ug/L 100 1.6 1 10/26/1918:38 110-57-6 ND ug/L 5.0 0.41 1 10/26/1918:38 75-34-3 ND ug/L 1.0 0.67 1 10/26/1918:38 107-06-2 ND ug/L 5.0 0.72 1 10/26/1918:38 75-35-4 ND ug/L 5.0 0.66 1 10/26/1918:38 156-59-2 ND ug/L 5.0 0.46 1 10/26/1918:38 156-60-5 ND ug/L 1.0 0.60 1 10/26/1918:38 78-87-5 ND ug/L 1.0 0.22 1 10/26/1918:38 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1918:38 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1918:38 100-41-4 ND ug/L 50.0 0.89 1 10/26/1918:38 591-78-6 ND ug/L 10.0 3.1 1 10/26/1918:38 74-88-4 ND ug/L 1.0 0.50 1 10/26/1918:38 75-09-2 ND ug/L 100 0.86 1 10/26/1918:38 108-10-1 ND ug/L 1.0 0.50 1 10/26/1918:38 100-42-5 ND ug/L 5.0 0.32 1 10/26/1918:38 630-20-6 ND ug/L 3.0 0.53 1 10/26/1918:38 79-34-5 ND ug/L 1.0 0.78 1 10/26/1918:38 127-18-4 ND ug/L 1.0 0.31 1 10/26/1918:38 108-88-3 ND ug/L 1.0 0.38 1 10/26/1918:38 71-55-6 ND ug/L 1.0 0.59 1 10/26/1918:38 79-00-5 ND ug/L 1.0 0.34 1 10/26/1918:38 79-01-6 ND ug/L 1.0 0.51 1 10/26/1918:38 75-69-4 ND ug/L 1.0 0.46 1 10/26/1918:38 96-18-4 ND ug/L 50.0 0.42 1 10/26/1918:38 108-05-4 ND ug/L 1.0 0.60 1 10/26/1918:38 75-01-4 ND ug/L 5.0 1.5 1 10/26/1918:38 1330-20-7 109 %. 81-119 1 10/26/1918:38 17060-07-0 104 %. 82-114 1 10/26/1918:38 1868-53-7 108 %. 82-120 1 10/26/1918:38 460-00-4 107 %. 82-109 1 10/26/1918:38 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-20AR Lab ID: 2624501018 Collected: 10/15/19 12:23 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 12:23 Field pH 6.08 Std. Units 1 10/15/19 12:23 Field Temperature 17.7 deg C 1 10/15/19 12:23 Field Specific 841 umhos/c 1 10/15/19 12:23 Conductance m Field Turbidity 3.92 NTU 1 10/15/19 12:23 Oxygen, Dissolved 1.22 mg/L 1 10/15/19 12:23 7782-44-7 N2 Depth to Water 10.80 feet 1 10/15/19 12:23 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:07 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:07 7440-38-2 Barium 317 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:07 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:07 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:07 7440-43-9 Chromium ND ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:07 7440-47-3 Cobalt 2.4J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:07 7440-48-4 Copper 0.96J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:07 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:07 7439-92-1 Nickel 38.7J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:07 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:07 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:07 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:07 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:07 7440-62-2 Zinc 19.7 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:07 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1918:02 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 19:03 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 19:03 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 19:03 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 19:03 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 19:03 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 19:03 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 19:03 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 19:03 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 19:03 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 19:03 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 19:03 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 19:03 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 19:03 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 19:03 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 19:03 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-20AR Lab ID: 2624501018 Collected: 10/15/19 12:23 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1919:03 124-48-1 ND ug/L 2.0 0.28 1 10/26/1919:03 106-93-4 ND ug/L 10.0 0.62 1 10/26/1919:03 74-95-3 ND ug/L 5.0 0.49 1 10/26/1919:03 95-50-1 ND ug/L 1.0 0.58 1 10/26/1919:03 106-46-7 ND ug/L 100 1.6 1 10/26/1919:03 110-57-6 ND ug/L 5.0 0.41 1 10/26/1919:03 75-34-3 ND ug/L 1.0 0.67 1 10/26/1919:03 107-06-2 ND ug/L 5.0 0.72 1 10/26/1919:03 75-35-4 ND ug/L 5.0 0.66 1 10/26/1919:03 156-59-2 ND ug/L 5.0 0.46 1 10/26/1919:03 156-60-5 ND ug/L 1.0 0.60 1 10/26/1919:03 78-87-5 ND ug/L 1.0 0.22 1 10/26/1919:03 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1919:03 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1919:03 100-41-4 ND ug/L 50.0 0.89 1 10/26/1919:03 591-78-6 ND ug/L 10.0 3.1 1 10/26/1919:03 74-88-4 ND ug/L 1.0 0.50 1 10/26/1919:03 75-09-2 ND ug/L 100 0.86 1 10/26/1919:03 108-10-1 ND ug/L 1.0 0.50 1 10/26/1919:03 100-42-5 ND ug/L 5.0 0.32 1 10/26/1919:03 630-20-6 ND ug/L 3.0 0.53 1 10/26/1919:03 79-34-5 ND ug/L 1.0 0.78 1 10/26/1919:03 127-18-4 ND ug/L 1.0 0.31 1 10/26/1919:03 108-88-3 ND ug/L 1.0 0.38 1 10/26/1919:03 71-55-6 ND ug/L 1.0 0.59 1 10/26/1919:03 79-00-5 ND ug/L 1.0 0.34 1 10/26/1919:03 79-01-6 ND ug/L 1.0 0.51 1 10/26/1919:03 75-69-4 ND ug/L 1.0 0.46 1 10/26/1919:03 96-18-4 ND ug/L 50.0 0.42 1 10/26/1919:03 108-05-4 ND ug/L 1.0 0.60 1 10/26/1919:03 75-01-4 ND ug/L 5.0 1.5 1 10/26/1919:03 1330-20-7 108 %. 81-119 1 10/26/1919:03 17060-07-0 104 %. 82-114 1 10/26/1919:03 1868-53-7 108 %. 82-120 1 10/26/1919:03 460-00-4 108 %. 82-109 1 10/26/1919:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 44 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-20B Lab ID: 2624501019 Collected: 10/15/19 14:55 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 14:55 Field pH 5.94 Std. Units 1 10/15/19 14:55 Field Temperature 17.9 deg C 1 10/15/19 14:55 Field Specific 1124 umhos/c 1 10/15/19 14:55 Conductance m Field Turbidity 0.13 NTU 1 10/15/19 14:55 Oxygen, Dissolved 1.42 mg/L 1 10/15/19 14:55 7782-44-7 N2 Depth to Water 6.70 feet 1 10/15/19 14:55 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony 0.30J ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:24 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:24 7440-38-2 Barium 936 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:24 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:24 7440-41-7 Cadmium 1.3 ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:24 7440-43-9 Chromium 1.OJ ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:24 7440-47-3 Cobalt 7.8J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:24 7440-48-4 Copper 5.9J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:24 7440-50-8 Lead 1.4J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:24 7439-92-1 Nickel 41.6J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:24 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:24 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:24 7440-22-4 Thallium 0.054J ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:24 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:24 7440-62-2 Zinc 47.4 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:24 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1918:12 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 19:29 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 19:29 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 19:29 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 19:29 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 19:29 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 19:29 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 19:29 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 19:29 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 19:29 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 19:29 56-23-5 Chlorobenzene 1.5J ug/L 3.0 0.53 1 10/26/19 19:29 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 19:29 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 19:29 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 19:29 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 19:29 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-20B Lab ID: 2624501019 Collected: 10/15/19 14:55 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1919:29 124-48-1 ND ug/L 2.0 0.28 1 10/26/1919:29 106-93-4 ND ug/L 10.0 0.62 1 10/26/1919:29 74-95-3 ND ug/L 5.0 0.49 1 10/26/1919:29 95-50-1 3.4 ug/L 1.0 0.58 1 10/26/1919:29 106-46-7 ND ug/L 100 1.6 1 10/26/1919:29 110-57-6 2.1J ug/L 5.0 0.41 1 10/26/1919:29 75-34-3 ND ug/L 1.0 0.67 1 10/26/1919:29 107-06-2 ND ug/L 5.0 0.72 1 10/26/1919:29 75-35-4 2.9J ug/L 5.0 0.66 1 10/26/1919:29 156-59-2 ND ug/L 5.0 0.46 1 10/26/1919:29 156-60-5 ND ug/L 1.0 0.60 1 10/26/1919:29 78-87-5 ND ug/L 1.0 0.22 1 10/26/1919:29 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1919:29 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1919:29 100-41-4 ND ug/L 50.0 0.89 1 10/26/1919:29 591-78-6 ND ug/L 10.0 3.1 1 10/26/1919:29 74-88-4 ND ug/L 1.0 0.50 1 10/26/1919:29 75-09-2 ND ug/L 100 0.86 1 10/26/1919:29 108-10-1 ND ug/L 1.0 0.50 1 10/26/1919:29 100-42-5 ND ug/L 5.0 0.32 1 10/26/1919:29 630-20-6 ND ug/L 3.0 0.53 1 10/26/1919:29 79-34-5 ND ug/L 1.0 0.78 1 10/26/1919:29 127-18-4 ND ug/L 1.0 0.31 1 10/26/1919:29 108-88-3 ND ug/L 1.0 0.38 1 10/26/1919:29 71-55-6 ND ug/L 1.0 0.59 1 10/26/1919:29 79-00-5 ND ug/L 1.0 0.34 1 10/26/1919:29 79-01-6 ND ug/L 1.0 0.51 1 10/26/1919:29 75-69-4 ND ug/L 1.0 0.46 1 10/26/1919:29 96-18-4 ND ug/L 50.0 0.42 1 10/26/1919:29 108-05-4 ND ug/L 1.0 0.60 1 10/26/1919:29 75-01-4 ND ug/L 5.0 1.5 1 10/26/1919:29 1330-20-7 107 %. 81-119 1 10/26/1919:29 17060-07-0 106 %. 82-114 1 10/26/1919:29 1868-53-7 109 %. 82-120 1 10/26/1919:29 460-00-4 107 %. 82-109 1 10/26/1919:29 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-21 Lab ID: 2624501020 Collected: 10/16/19 14:29 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/16/19 14:29 Field pH 5.98 Std. Units 1 10/16/19 14:29 Field Temperature 17.7 deg C 1 10/16/19 14:29 Field Specific 345 umhos/c 1 10/16/19 14:29 Conductance m Field Turbidity 39 NTU 1 10/16/19 14:29 Oxygen, Dissolved 3.29 mg/L 1 10/16/19 14:29 7782-44-7 N2 Depth to Water 15.02 feet 1 10/16/19 14:29 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 14:01 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 14:01 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 14:01 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 14:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 14:01 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 14:01 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 14:01 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 14:01 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 14:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 14:01 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 14:01 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 14:01 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 14:01 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 14:01 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 14:01 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/30/19 14:01 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 10/30/19 14:01 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 10/30/19 14:01 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 10/30/19 14:01 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 10/30/19 14:01 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 10/30/19 14:01 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.41 1 10/30/19 14:01 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.67 1 10/30/19 14:01 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.72 1 10/30/19 14:01 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.66 1 10/30/19 14:01 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.46 1 10/30/19 14:01 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.60 1 10/30/19 14:01 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.22 1 10/30/19 14:01 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.30 1 10/30/19 14:01 10061-02-6 Ethylbenzene ND ug/L 1.0 0.45 1 10/30/19 14:01 100-41-4 2-Hexanone ND ug/L 50.0 0.89 1 10/30/19 14:01 591-78-6 lodomethane ND ug/L 10.0 3.1 1 10/30/19 14:01 74-88-4 Methylene Chloride ND ug/L 1.0 0.50 1 10/30/19 14:01 75-09-2 4-Methyl-2-pentanone ND ug/L 100 0.86 1 10/30/19 14:01 108-10-1 (MIBK) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-21 Lab ID: 2624501020 Collected: 10/16/19 14:29 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Styrene ND ug/L 1.0 0.50 1 10/30/19 14:01 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.32 1 10/30/19 14:01 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.53 1 10/30/19 14:01 79-34-5 Tetrachloroethene ND ug/L 1.0 0.78 1 10/30/19 14:01 127-18-4 Toluene ND ug/L 1.0 0.31 1 10/30/19 14:01 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 10/30/19 14:01 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 10/30/19 14:01 79-00-5 Trichloroethene ND ug/L 1.0 0.34 1 10/30/19 14:01 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.51 1 10/30/19 14:01 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 10/30/19 14:01 96-18-4 Vinyl acetate ND ug/L 50.0 0.42 1 10/30/19 14:01 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 10/30/19 14:01 75-01-4 Xylene (Total) ND ug/L 5.0 1.5 1 10/30/19 14:01 1330-20-7 Surrogates 1,2-Dichloroethane-d4 (S) 105 %. 81-119 1 10/30/19 14:01 17060-07-0 Dibromofluoromethane (S) 101 %. 82-114 1 10/30/19 14:01 1868-53-7 4-Bromofluorobenzene (S) 107 %. 82-120 1 10/30/19 14:01 460-00-4 Toluene-d8 (S) 106 %. 82-109 1 10/30/19 14:01 2037-26-5 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-21 Lab ID: 2624501021 Collected: 10/17/19 08:09 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By James 1 10/17/19 08:09 Field Turbidity 18 NTU 1 10/17/19 08:09 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony 0.32J ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:30 7440-36-0 Arsenic 0.59J ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:30 7440-38-2 Barium 79.5J ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:30 7440-39-3 Beryllium 0.15J ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:30 7440-41-7 Cadmium 0.13J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:30 7440-43-9 Chromium 14.5 ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:30 7440-47-3 Cobalt 833 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:30 7440-48-4 Copper 92.8 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:30 7440-50-8 Lead 2.2J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:30 7439-92-1 Nickel 57.0 ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:30 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:30 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:30 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:30 7440-28-0 Vanadium 18AJ ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:30 7440-62-2 Zinc 42.5 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:30 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1912:43 11/05/1918:18 7439-97-6 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 49 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-22 Lab ID: 2624501022 Collected: 10/15/19 08:32 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/15/19 08:32 Field pH 6.55 Std. Units 1 10/15/19 08:32 Field Temperature 21.4 deg C 1 10/15/19 08:32 Field Specific 2208 umhos/c 1 10/15/19 08:32 Conductance m Field Turbidity 4.01 NTU 1 10/15/19 08:32 Oxygen, Dissolved 5.43 mg/L 1 10/15/19 08:32 7782-44-7 N2 Depth to Water 7.18 feet 1 10/15/19 08:32 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:36 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:36 7440-38-2 Barium 343 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:36 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:36 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:36 7440-43-9 Chromium 6.1J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:36 7440-47-3 Cobalt 189 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:36 7440-48-4 Copper 6.3J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:36 7440-50-8 Lead 0.14J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:36 7439-92-1 Nickel 22.9J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:36 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:36 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:36 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:36 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:36 7440-62-2 Zinc 8.4J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:36 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:26 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 19:54 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 19:54 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 19:54 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 19:54 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 19:54 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 19:54 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 19:54 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 19:54 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 19:54 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 19:54 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 19:54 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 19:54 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 19:54 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 19:54 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 19:54 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-22 Lab ID: 2624501022 Collected: 10/15/19 08:32 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1919:54 124-48-1 ND ug/L 2.0 0.28 1 10/26/1919:54 106-93-4 ND ug/L 10.0 0.62 1 10/26/1919:54 74-95-3 ND ug/L 5.0 0.49 1 10/26/1919:54 95-50-1 ND ug/L 1.0 0.58 1 10/26/1919:54 106-46-7 ND ug/L 100 1.6 1 10/26/1919:54 110-57-6 ND ug/L 5.0 0.41 1 10/26/1919:54 75-34-3 ND ug/L 1.0 0.67 1 10/26/1919:54 107-06-2 ND ug/L 5.0 0.72 1 10/26/1919:54 75-35-4 ND ug/L 5.0 0.66 1 10/26/1919:54 156-59-2 ND ug/L 5.0 0.46 1 10/26/1919:54 156-60-5 ND ug/L 1.0 0.60 1 10/26/1919:54 78-87-5 ND ug/L 1.0 0.22 1 10/26/1919:54 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1919:54 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1919:54 100-41-4 ND ug/L 50.0 0.89 1 10/26/1919:54 591-78-6 ND ug/L 10.0 3.1 1 10/26/1919:54 74-88-4 ND ug/L 1.0 0.50 1 10/26/1919:54 75-09-2 ND ug/L 100 0.86 1 10/26/1919:54 108-10-1 ND ug/L 1.0 0.50 1 10/26/1919:54 100-42-5 ND ug/L 5.0 0.32 1 10/26/1919:54 630-20-6 ND ug/L 3.0 0.53 1 10/26/1919:54 79-34-5 ND ug/L 1.0 0.78 1 10/26/1919:54 127-18-4 ND ug/L 1.0 0.31 1 10/26/1919:54 108-88-3 ND ug/L 1.0 0.38 1 10/26/1919:54 71-55-6 ND ug/L 1.0 0.59 1 10/26/1919:54 79-00-5 ND ug/L 1.0 0.34 1 10/26/1919:54 79-01-6 ND ug/L 1.0 0.51 1 10/26/1919:54 75-69-4 ND ug/L 1.0 0.46 1 10/26/1919:54 96-18-4 ND ug/L 50.0 0.42 1 10/26/1919:54 108-05-4 ND ug/L 1.0 0.60 1 10/26/1919:54 75-01-4 ND ug/L 5.0 1.5 1 10/26/1919:54 1330-20-7 107 %. 81-119 1 10/26/1919:54 17060-07-0 104 %. 82-114 1 10/26/1919:54 1868-53-7 108 %. 82-120 1 10/26/1919:54 460-00-4 108 %. 82-109 1 10/26/1919:54 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-22A Lab ID: 2624501023 Collected: 10/15/19 09:22 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/15/19 09:22 Field pH 6.32 Std. Units 1 10/15/19 09:22 Field Temperature 20.6 deg C 1 10/15/19 09:22 Field Specific 2066 umhos/c 1 10/15/19 09:22 Conductance m Field Turbidity 1.16 NTU 1 10/15/19 09:22 Oxygen, Dissolved 6.20 mg/L 1 10/15/19 09:22 7782-44-7 N2 Depth to Water 7.01 feet 1 10/15/19 09:22 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:41 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:41 7440-38-2 Barium 65.2J ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:41 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:41 7440-41-7 Cadmium 1.7 ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:41 7440-43-9 Chromium 1.2J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:41 7440-47-3 Cobalt 21.0 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:41 7440-48-4 Copper 6.2J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:41 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:41 7439-92-1 Nickel 123 ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:41 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:41 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:41 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:41 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:41 7440-62-2 Zinc 13.1 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:41 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:36 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 20:20 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 20:20 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 20:20 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 20:20 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 20:20 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 20:20 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 20:20 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 20:20 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 20:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 20:20 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 20:20 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 20:20 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 20:20 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 20:20 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 20:20 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-22A Lab ID: 2624501023 Collected: 10/15/19 09:22 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/19 20:20 124-48-1 ND ug/L 2.0 0.28 1 10/26/19 20:20 106-93-4 ND ug/L 10.0 0.62 1 10/26/19 20:20 74-95-3 ND ug/L 5.0 0.49 1 10/26/19 20:20 95-50-1 0.76J ug/L 1.0 0.58 1 10/26/19 20:20 106-46-7 ND ug/L 100 1.6 1 10/26/19 20:20 110-57-6 ND ug/L 5.0 0.41 1 10/26/19 20:20 75-34-3 ND ug/L 1.0 0.67 1 10/26/19 20:20 107-06-2 ND ug/L 5.0 0.72 1 10/26/19 20:20 75-35-4 ND ug/L 5.0 0.66 1 10/26/19 20:20 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 20:20 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 20:20 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 20:20 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 20:20 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 20:20 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 20:20 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 20:20 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 20:20 75-09-2 ND ug/L 100 0.86 1 10/26/19 20:20 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 20:20 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 20:20 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 20:20 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 20:20 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 20:20 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 20:20 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 20:20 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 20:20 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 20:20 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 20:20 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 20:20 108-05-4 ND ug/L 1.0 0.60 1 10/26/19 20:20 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 20:20 1330-20-7 108 %. 81-119 1 10/26/19 20:20 17060-07-0 108 %. 82-114 1 10/26/19 20:20 1868-53-7 106 %. 82-120 1 10/26/19 20:20 460-00-4 106 %. 82-109 1 10/26/19 20:20 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 53 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-25 Lab ID: 2624501024 Collected: 10/15/19 08:02 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: James 1 10/15/19 08:02 6.16 Std. Units 1 10/15/19 08:02 23.2 deg C 1 10/15/19 08:02 1324 umhos/c 1 10/15/19 08:02 m 1.32 NTU 1 10/15/19 08:02 5.13 mg/L 1 10/15/19 08:02 7782-44-7 8.12 feet 1 10/15/19 08:02 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:47 7440-36-0 ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:47 7440-38-2 112 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:47 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:47 7440-41-7 0.21J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:47 7440-43-9 0.87J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:47 7440-47-3 5.7J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:47 7440-48-4 0.48J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:47 7440-50-8 ND ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:47 7439-92-1 23.6J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:47 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:47 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:47 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:47 7440-28-0 1.OJ ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:47 7440-62-2 7.5J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:47 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N 0.34 N N N N N N N 12. N N N ND D ug/L 100 D ug/L 200 J ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 100 D ug/L 100 D ug/L 1.0 4 ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 ug/L 2.0 0.14 1 11/05/1913:10 11/05/1919:38 7439-97-6 8.2 1 10/26/19 20:45 67-64-1 2.5 1 10/26/19 20:45 107-13-1 0.20 1 10/26/19 20:45 71-43-2 0.50 1 10/26/19 20:45 74-97-5 0.36 1 10/26/19 20:45 75-27-4 0.55 1 10/26/19 20:45 75-25-2 0.95 1 10/26/19 20:45 74-83-9 3.2 1 10/26/19 20:45 78-93-3 0.79 1 10/26/19 20:45 75-15-0 0.42 1 10/26/19 20:45 56-23-5 0.53 1 10/26/19 20:45 108-90-7 0.52 1 10/26/19 20:45 75-00-3 0.58 1 10/26/19 20:45 67-66-3 0.38 1 10/26/19 20:45 74-87-3 0.55 1 10/26/19 20:45 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 54 of 157 0.14 1 11/05/1913:10 11/05/1919:38 7439-97-6 8.2 1 10/26/19 20:45 67-64-1 2.5 1 10/26/19 20:45 107-13-1 0.20 1 10/26/19 20:45 71-43-2 0.50 1 10/26/19 20:45 74-97-5 0.36 1 10/26/19 20:45 75-27-4 0.55 1 10/26/19 20:45 75-25-2 0.95 1 10/26/19 20:45 74-83-9 3.2 1 10/26/19 20:45 78-93-3 0.79 1 10/26/19 20:45 75-15-0 0.42 1 10/26/19 20:45 56-23-5 0.53 1 10/26/19 20:45 108-90-7 0.52 1 10/26/19 20:45 75-00-3 0.58 1 10/26/19 20:45 67-66-3 0.38 1 10/26/19 20:45 74-87-3 0.55 1 10/26/19 20:45 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 54 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 54 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-25 Lab ID: 2624501024 Collected: 10/15/19 08:02 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/19 20:45 124-48-1 ND ug/L 2.0 0.28 1 10/26/19 20:45 106-93-4 ND ug/L 10.0 0.62 1 10/26/19 20:45 74-95-3 ND ug/L 5.0 0.49 1 10/26/19 20:45 95-50-1 13.3 ug/L 1.0 0.58 1 10/26/19 20:45 106-46-7 ND ug/L 100 1.6 1 10/26/19 20:45 110-57-6 ND ug/L 5.0 0.41 1 10/26/19 20:45 75-34-3 ND ug/L 1.0 0.67 1 10/26/19 20:45 107-06-2 ND ug/L 5.0 0.72 1 10/26/19 20:45 75-35-4 0.91J ug/L 5.0 0.66 1 10/26/19 20:45 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 20:45 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 20:45 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 20:45 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 20:45 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 20:45 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 20:45 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 20:45 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 20:45 75-09-2 ND ug/L 100 0.86 1 10/26/19 20:45 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 20:45 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 20:45 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 20:45 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 20:45 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 20:45 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 20:45 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 20:45 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 20:45 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 20:45 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 20:45 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 20:45 108-05-4 ND ug/L 1.0 0.60 1 10/26/19 20:45 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 20:45 1330-20-7 109 %. 81-119 1 10/26/19 20:45 17060-07-0 105 %. 82-114 1 10/26/19 20:45 1868-53-7 108 %. 82-120 1 10/26/19 20:45 460-00-4 108 %. 82-109 1 10/26/19 20:45 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 55 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-26 Lab ID: 2624501025 Collected: 10/17/19 11:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/17/19 11:10 Field pH 6.35 Std. Units 1 10/17/19 11:10 Field Temperature 20.6 deg C 1 10/17/19 11:10 Field Specific 881 umhos/c 1 10/17/19 11:10 Conductance m Field Turbidity 5.41 NTU 1 10/17/19 11:10 Oxygen, Dissolved 6.18 mg/L 1 10/17/19 11:10 7782-44-7 N2 Depth to Water 16.90 feet 1 10/17/19 11:10 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:53 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:53 7440-38-2 Barium 148 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:53 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:53 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:53 7440-43-9 Chromium 4.5J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:53 7440-47-3 Cobalt 19.7 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:53 7440-48-4 Copper 0.92J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:53 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:53 7439-92-1 Nickel 15.1J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:53 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:53 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:53 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:53 7440-28-0 Vanadium 3.7J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:53 7440-62-2 Zinc 6.1J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:53 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury 0.45 ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:40 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/31/19 20:37 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/31/19 20:37 107-13-1 Benzene 0.27J ug/L 1.0 0.20 1 10/31/19 20:37 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/31/19 20:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/31/19 20:37 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/31/19 20:37 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/31/19 20:37 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/31/19 20:37 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/31/19 20:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/31/19 20:37 56-23-5 Chlorobenzene 0.68J ug/L 3.0 0.53 1 10/31/19 20:37 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/31/19 20:37 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/31/19 20:37 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/31/19 20:37 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/31/19 20:37 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-26 Lab ID: 2624501025 Collected: 10/17/19 11:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/31/19 20:37 124-48-1 ND ug/L 2.0 0.28 1 10/31/19 20:37 106-93-4 ND ug/L 10.0 0.62 1 10/31/19 20:37 74-95-3 ND ug/L 5.0 0.49 1 10/31/19 20:37 95-50-1 0.78J ug/L 1.0 0.58 1 10/31/19 20:37 106-46-7 ND ug/L 100 1.6 1 10/31/19 20:37 110-57-6 ND ug/L 5.0 0.41 1 10/31/19 20:37 75-34-3 ND ug/L 1.0 0.67 1 10/31/19 20:37 107-06-2 ND ug/L 5.0 0.72 1 10/31/19 20:37 75-35-4 ND ug/L 5.0 0.66 1 10/31/19 20:37 156-59-2 ND ug/L 5.0 0.46 1 10/31/19 20:37 156-60-5 ND ug/L 1.0 0.60 1 10/31/19 20:37 78-87-5 ND ug/L 1.0 0.22 1 10/31/19 20:37 10061-01-5 ND ug/L 1.0 0.30 1 10/31/19 20:37 10061-02-6 ND ug/L 1.0 0.45 1 10/31/19 20:37 100-41-4 ND ug/L 50.0 0.89 1 10/31/19 20:37 591-78-6 ND ug/L 10.0 3.1 1 10/31/19 20:37 74-88-4 ND ug/L 1.0 0.50 1 10/31/19 20:37 75-09-2 ND ug/L 100 0.86 1 10/31/19 20:37 108-10-1 ND ug/L 1.0 0.50 1 10/31/19 20:37 100-42-5 ND ug/L 5.0 0.32 1 10/31/19 20:37 630-20-6 ND ug/L 3.0 0.53 1 10/31/19 20:37 79-34-5 ND ug/L 1.0 0.78 1 10/31/19 20:37 127-18-4 ND ug/L 1.0 0.31 1 10/31/19 20:37 108-88-3 ND ug/L 1.0 0.38 1 10/31/19 20:37 71-55-6 ND ug/L 1.0 0.59 1 10/31/19 20:37 79-00-5 ND ug/L 1.0 0.34 1 10/31/19 20:37 79-01-6 ND ug/L 1.0 0.51 1 10/31/19 20:37 75-69-4 ND ug/L 1.0 0.46 1 10/31/19 20:37 96-18-4 ND ug/L 50.0 0.42 1 10/31/19 20:37 108-05-4 ND ug/L 1.0 0.60 1 10/31/19 20:37 75-01-4 ND ug/L 5.0 1.5 1 10/31/19 20:37 1330-20-7 107 %. 81-119 1 10/31/19 20:37 17060-07-0 100 %. 82-114 1 10/31/19 20:37 1868-53-7 106 %. 82-120 1 10/31/19 20:37 460-00-4 104 %. 82-109 1 10/31/19 20:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 57 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-27 Lab ID: 2624501026 Collected: 10/16/19 11:54 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By WF 1 10/17/19 07:57 Field pH 6.42 Std. Units 1 10/17/19 07:57 Field Temperature 19.1 deg C 1 10/17/19 07:57 Field Specific 252 umhos/c 1 10/17/19 07:57 Conductance m Field Turbidity 15 NTU 1 10/17/19 07:57 Oxygen, Dissolved 2.14 mg/L 1 10/17/19 07:57 7782-44-7 N2 Depth to Water 11.41 feet 1 10/17/19 07:57 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 14:26 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 14:26 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 14:26 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 14:26 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 14:26 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 14:26 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 14:26 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 14:26 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 14:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 14:26 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 14:26 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 14:26 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 14:26 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 14:26 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 14:26 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/30/19 14:26 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 10/30/19 14:26 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 10/30/19 14:26 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 10/30/19 14:26 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 10/30/19 14:26 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 10/30/19 14:26 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.41 1 10/30/19 14:26 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.67 1 10/30/19 14:26 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.72 1 10/30/19 14:26 75-35-4 cis-1,2-Dichloroethene ND ug/L 5.0 0.66 1 10/30/19 14:26 156-59-2 trans-1,2-Dichloroethene ND ug/L 5.0 0.46 1 10/30/19 14:26 156-60-5 1,2-Dichloropropane ND ug/L 1.0 0.60 1 10/30/19 14:26 78-87-5 cis-1,3-Dichloropropene ND ug/L 1.0 0.22 1 10/30/19 14:26 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.30 1 10/30/19 14:26 10061-02-6 Ethylbenzene ND ug/L 1.0 0.45 1 10/30/19 14:26 100-41-4 2-Hexanone ND ug/L 50.0 0.89 1 10/30/19 14:26 591-78-6 lodomethane ND ug/L 10.0 3.1 1 10/30/19 14:26 74-88-4 Methylene Chloride ND ug/L 1.0 0.50 1 10/30/19 14:26 75-09-2 4-Methyl-2-pentanone ND ug/L 100 0.86 1 10/30/19 14:26 108-10-1 (MIBK) REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-27 Lab ID: 2624501026 Collected: 10/16/19 11:54 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Styrene ND ug/L 1.0 0.50 1 10/30/19 14:26 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 5.0 0.32 1 10/30/19 14:26 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 3.0 0.53 1 10/30/19 14:26 79-34-5 Tetrachloroethene ND ug/L 1.0 0.78 1 10/30/19 14:26 127-18-4 Toluene ND ug/L 1.0 0.31 1 10/30/19 14:26 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 10/30/19 14:26 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 10/30/19 14:26 79-00-5 Trichloroethene ND ug/L 1.0 0.34 1 10/30/19 14:26 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.51 1 10/30/19 14:26 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 10/30/19 14:26 96-18-4 Vinyl acetate ND ug/L 50.0 0.42 1 10/30/19 14:26 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 10/30/19 14:26 75-01-4 Xylene (Total) ND ug/L 5.0 1.5 1 10/30/19 14:26 1330-20-7 Surrogates 1,2-Dichloroethane-d4 (S) 104 %. 81-119 1 10/30/19 14:26 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 10/30/19 14:26 1868-53-7 4-Bromofluorobenzene (S) 106 %. 82-120 1 10/30/19 14:26 460-00-4 Toluene-d8 (S) 106 %. 82-109 1 10/30/19 14:26 2037-26-5 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 59 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-27 Lab ID: 2624501027 Collected: 10/17/19 07:57 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Collected By WF 1 10/17/19 07:57 Field Turbidity 9.37 NTU 1 10/17/19 07:57 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 20:58 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 20:58 7440-38-2 Barium 54.9J ug/L 100 0.49 1 10/31/19 21:41 11/01/19 20:58 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 20:58 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 20:58 7440-43-9 Chromium 4.9J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 20:58 7440-47-3 Cobalt 1.OJ ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 20:58 7440-48-4 Copper 13.5 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 20:58 7440-50-8 Lead 0.47J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 20:58 7439-92-1 Nickel 6.8J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 20:58 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 20:58 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 20:58 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 20:58 7440-28-0 Vanadium 5.2J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 20:58 7440-62-2 Zinc 15.0 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 20:58 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:48 7439-97-6 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-28 Lab ID: 2624501028 Collected: 10/15/19 16:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 16:10 Field pH 6.33 Std. Units 1 10/15/19 16:10 Field Temperature 21.2 deg C 1 10/15/19 16:10 Field Specific 549 umhos/c 1 10/15/19 16:10 Conductance m Field Turbidity 1.40 NTU 1 10/15/19 16:10 Oxygen, Dissolved 1.80 mg/L 1 10/15/19 16:10 7782-44-7 N2 Depth to Water 13.52 feet 1 10/15/19 16:10 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:04 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:04 7440-38-2 Barium 83.1J ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:04 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:04 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:04 7440-43-9 Chromium 13.5 ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:04 7440-47-3 Cobalt ND ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:04 7440-48-4 Copper 0.39J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:04 7440-50-8 Lead 0.054J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:04 7439-92-1 Nickel 22.OJ ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:04 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:04 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:04 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:04 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:04 7440-62-2 Zinc 5.7J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:04 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:50 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 21:10 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 21:10 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 21:10 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 21:10 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 21:10 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 21:10 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 21:10 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 21:10 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 21:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 21:10 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 21:10 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 21:10 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 21:10 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 21:10 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 21:10 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-28 Lab ID: 2624501028 Collected: 10/15/19 16:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/19 21:10 124-48-1 ND ug/L 2.0 0.28 1 10/26/19 21:10 106-93-4 ND ug/L 10.0 0.62 1 10/26/19 21:10 74-95-3 ND ug/L 5.0 0.49 1 10/26/19 21:10 95-50-1 ND ug/L 1.0 0.58 1 10/26/19 21:10 106-46-7 ND ug/L 100 1.6 1 10/26/19 21:10 110-57-6 ND ug/L 5.0 0.41 1 10/26/19 21:10 75-34-3 ND ug/L 1.0 0.67 1 10/26/19 21:10 107-06-2 ND ug/L 5.0 0.72 1 10/26/19 21:10 75-35-4 ND ug/L 5.0 0.66 1 10/26/19 21:10 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 21:10 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 21:10 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 21:10 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 21:10 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 21:10 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 21:10 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 21:10 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 21:10 75-09-2 ND ug/L 100 0.86 1 10/26/19 21:10 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 21:10 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 21:10 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 21:10 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 21:10 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 21:10 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 21:10 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 21:10 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 21:10 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 21:10 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 21:10 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 21:10 108-05-4 ND ug/L 1.0 0.60 1 10/26/19 21:10 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 21:10 1330-20-7 113 %. 81-119 1 10/26/19 21:10 17060-07-0 106 %. 82-114 1 10/26/19 21:10 1868-53-7 104 %. 82-120 1 10/26/19 21:10 460-00-4 105 %. 82-109 1 10/26/19 21:10 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 62 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-29R Lab ID: 2624501029 Collected: 10/15/19 08:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 08:10 Field pH 6.03 Std. Units 1 10/15/19 08:10 Field Temperature 17.2 deg C 1 10/15/19 08:10 Field Specific 309 umhos/c 1 10/15/19 08:10 Conductance m Field Turbidity 5.50 NTU 1 10/15/19 08:10 Oxygen, Dissolved 1.44 mg/L 1 10/15/19 08:10 7782-44-7 N2 Depth to Water 7.86 feet 1 10/15/19 08:10 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:10 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:10 7440-38-2 Barium 37.4J ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:10 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:10 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:10 7440-43-9 Chromium 2.8J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:10 7440-47-3 Cobalt 0.75J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:10 7440-48-4 Copper 3.9J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:10 7440-50-8 Lead 0.050J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:10 7439-92-1 Nickel 4.3J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:10 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:10 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:10 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:10 7440-28-0 Vanadium 2.8J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:10 7440-62-2 Zinc 6.1J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:10 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:52 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 21:35 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 21:35 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 21:35 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 21:35 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 21:35 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 21:35 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 21:35 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 21:35 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 21:35 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 21:35 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 21:35 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 21:35 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 21:35 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 21:35 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 21:35 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-29R Lab ID: 2624501029 Collected: 10/15/19 08:10 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/19 21:35 124-48-1 ND ug/L 2.0 0.28 1 10/26/19 21:35 106-93-4 ND ug/L 10.0 0.62 1 10/26/19 21:35 74-95-3 ND ug/L 5.0 0.49 1 10/26/19 21:35 95-50-1 ND ug/L 1.0 0.58 1 10/26/19 21:35 106-46-7 ND ug/L 100 1.6 1 10/26/19 21:35 110-57-6 ND ug/L 5.0 0.41 1 10/26/19 21:35 75-34-3 ND ug/L 1.0 0.67 1 10/26/19 21:35 107-06-2 ND ug/L 5.0 0.72 1 10/26/19 21:35 75-35-4 ND ug/L 5.0 0.66 1 10/26/19 21:35 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 21:35 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 21:35 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 21:35 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 21:35 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 21:35 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 21:35 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 21:35 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 21:35 75-09-2 ND ug/L 100 0.86 1 10/26/19 21:35 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 21:35 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 21:35 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 21:35 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 21:35 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 21:35 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 21:35 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 21:35 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 21:35 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 21:35 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 21:35 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 21:35 108-05-4 ND ug/L 1.0 0.60 1 10/26/19 21:35 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 21:35 1330-20-7 111 %. 81-119 1 10/26/19 21:35 17060-07-0 105 %. 82-114 1 10/26/19 21:35 1868-53-7 107 %. 82-120 1 10/26/19 21:35 460-00-4 107 %. 82-109 1 10/26/19 21:35 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 64 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-30R Lab ID: 2624501030 Collected: 10/16/19 15:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/16/19 15:24 Field pH 5.57 Std. Units 1 10/16/19 15:24 Field Temperature 15.7 deg C 1 10/16/19 15:24 Field Specific 272 umhos/c 1 10/16/19 15:24 Conductance m Field Turbidity 2.68 NTU 1 10/16/19 15:24 Oxygen, Dissolved 1.59 mg/L 1 10/16/19 15:24 7782-44-7 N2 Depth to Water 28.53 feet 1 10/16/19 15:24 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:16 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:16 7440-38-2 Barium 111 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:16 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:16 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:16 7440-43-9 Chromium 2.8J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:16 7440-47-3 Cobalt 0.76J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:16 7440-48-4 Copper 2.2J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:16 7440-50-8 Lead 0.092J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:16 7439-92-1 Nickel 14.8J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:16 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:16 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:16 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:16 7440-28-0 Vanadium 5.1J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:16 7440-62-2 Zinc 23.9 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:16 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:55 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/30/19 14:51 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/30/19 14:51 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/30/19 14:51 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/30/19 14:51 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/30/19 14:51 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/30/19 14:51 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/30/19 14:51 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/30/19 14:51 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/30/19 14:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/30/19 14:51 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/30/19 14:51 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/30/19 14:51 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/30/19 14:51 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/30/19 14:51 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/30/19 14:51 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-30R Lab ID: 2624501030 Collected: 10/16/19 15:24 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/30/1914:51 124-48-1 ND ug/L 2.0 0.28 1 10/30/1914:51 106-93-4 ND ug/L 10.0 0.62 1 10/30/1914:51 74-95-3 ND ug/L 5.0 0.49 1 10/30/1914:51 95-50-1 ND ug/L 1.0 0.58 1 10/30/1914:51 106-46-7 ND ug/L 100 1.6 1 10/30/1914:51 110-57-6 ND ug/L 5.0 0.41 1 10/30/1914:51 75-34-3 ND ug/L 1.0 0.67 1 10/30/1914:51 107-06-2 ND ug/L 5.0 0.72 1 10/30/1914:51 75-35-4 ND ug/L 5.0 0.66 1 10/30/1914:51 156-59-2 ND ug/L 5.0 0.46 1 10/30/1914:51 156-60-5 ND ug/L 1.0 0.60 1 10/30/1914:51 78-87-5 ND ug/L 1.0 0.22 1 10/30/1914:51 10061-01-5 ND ug/L 1.0 0.30 1 10/30/1914:51 10061-02-6 ND ug/L 1.0 0.45 1 10/30/1914:51 100-41-4 ND ug/L 50.0 0.89 1 10/30/1914:51 591-78-6 ND ug/L 10.0 3.1 1 10/30/1914:51 74-88-4 ND ug/L 1.0 0.50 1 10/30/1914:51 75-09-2 ND ug/L 100 0.86 1 10/30/1914:51 108-10-1 ND ug/L 1.0 0.50 1 10/30/1914:51 100-42-5 ND ug/L 5.0 0.32 1 10/30/1914:51 630-20-6 ND ug/L 3.0 0.53 1 10/30/1914:51 79-34-5 ND ug/L 1.0 0.78 1 10/30/1914:51 127-18-4 ND ug/L 1.0 0.31 1 10/30/1914:51 108-88-3 ND ug/L 1.0 0.38 1 10/30/1914:51 71-55-6 ND ug/L 1.0 0.59 1 10/30/1914:51 79-00-5 ND ug/L 1.0 0.34 1 10/30/1914:51 79-01-6 ND ug/L 1.0 0.51 1 10/30/1914:51 75-69-4 ND ug/L 1.0 0.46 1 10/30/1914:51 96-18-4 ND ug/L 50.0 0.42 1 10/30/1914:51 108-05-4 ND ug/L 1.0 0.60 1 10/30/1914:51 75-01-4 ND ug/L 5.0 1.5 1 10/30/1914:51 1330-20-7 105 %. 81-119 1 10/30/1914:51 17060-07-0 100 %. 82-114 1 10/30/1914:51 1868-53-7 106 %. 82-120 1 10/30/1914:51 460-00-4 107 %. 82-109 1 10/30/1914:51 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-31 Lab ID: 2624501031 Collected: 10/15/19 08:48 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 08:48 Field pH 5.61 Std. Units 1 10/15/19 08:48 Field Temperature 16.3 deg C 1 10/15/19 08:48 Field Specific 471 umhos/c 1 10/15/19 08:48 Conductance m Field Turbidity 1.13 NTU 1 10/15/19 08:48 Oxygen, Dissolved 1.47 mg/L 1 10/15/19 08:48 7782-44-7 N2 Depth to Water 25.29 feet 1 10/15/19 08:48 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony 0.43J ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:33 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:33 7440-38-2 Barium 157 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:33 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:33 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:33 7440-43-9 Chromium ND ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:33 7440-47-3 Cobalt 9.8J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:33 7440-48-4 Copper 0.47J ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:33 7440-50-8 Lead 0.32J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:33 7439-92-1 Nickel 9.9J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:33 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:33 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:33 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:33 7440-28-0 Vanadium ND ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:33 7440-62-2 Zinc 10.3 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:33 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/1913:10 11/05/1919:57 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 22:01 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 22:01 107-13-1 Benzene 1.4 ug/L 1.0 0.20 1 10/26/19 22:01 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 22:01 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 22:01 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 22:01 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 22:01 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 22:01 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 22:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 22:01 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 22:01 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 22:01 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 22:01 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 22:01 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 22:01 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-31 Lab ID: 2624501031 Collected: 10/15/19 08:48 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/19 22:01 124-48-1 ND ug/L 2.0 0.28 1 10/26/19 22:01 106-93-4 ND ug/L 10.0 0.62 1 10/26/19 22:01 74-95-3 ND ug/L 5.0 0.49 1 10/26/19 22:01 95-50-1 ND ug/L 1.0 0.58 1 10/26/19 22:01 106-46-7 ND ug/L 100 1.6 1 10/26/19 22:01 110-57-6 ND ug/L 5.0 0.41 1 10/26/19 22:01 75-34-3 ND ug/L 1.0 0.67 1 10/26/19 22:01 107-06-2 ND ug/L 5.0 0.72 1 10/26/19 22:01 75-35-4 ND ug/L 5.0 0.66 1 10/26/19 22:01 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 22:01 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 22:01 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 22:01 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 22:01 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 22:01 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 22:01 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 22:01 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 22:01 75-09-2 ND ug/L 100 0.86 1 10/26/19 22:01 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 22:01 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 22:01 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 22:01 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 22:01 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 22:01 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 22:01 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 22:01 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 22:01 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 22:01 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 22:01 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 22:01 108-05-4 2.1 ug/L 1.0 0.60 1 10/26/19 22:01 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 22:01 1330-20-7 110 %. 81-119 1 10/26/19 22:01 17060-07-0 105 %. 82-114 1 10/26/19 22:01 1868-53-7 106 %. 82-120 1 10/26/19 22:01 460-00-4 106 %. 82-109 1 10/26/19 22:01 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 68 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-32R Lab ID: 2624501032 Collected: 10/15/19 09:38 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: WF 1 10/15/19 09:38 6.00 Std. Units 1 10/15/19 09:38 18.3 deg C 1 10/15/19 09:38 599 umhos/c 1 10/15/19 09:38 m 2.47 NTU 1 10/15/19 09:38 1.98 mg/L 1 10/15/19 09:38 7782-44-7 23.35 feet 1 10/15/19 09:38 Analytical Method: EPA 6020B Preparation Method: EPA 3005A N N 14 N N 8.5 23. 11. 27. 44.1 N N N 2.8 7.5 D ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:39 7440-36-0 D ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:39 7440-38-2 1 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:39 7440-39-3 D ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:39 7440-41-7 D ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:39 7440-43-9 J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:39 7440-47-3 3 ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:39 7440-48-4 2 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:39 7440-50-8 3 ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:39 7439-92-1 J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:39 7440-02-0 D ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:39 7782-49-2 D ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:39 7440-22-4 D ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:39 7440-28-0 J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:39 7440-62-2 J ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:39 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N 6. N N N N 19.7 1.4 N N N N N N D ug/L 100 D ug/L 200 7 ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 J ug/L 100 J ug/L 100 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 D ug/L 2.0 0.14 1 11/05/1913:10 11/05/1919:59 7439-97-6 8.2 1 10/26/19 18:07 67-64-1 2.5 1 10/26/19 18:07 107-13-1 0.20 1 10/26/19 18:07 71-43-2 0.50 1 10/26/19 18:07 74-97-5 0.36 1 10/26/19 18:07 75-27-4 0.55 1 10/26/19 18:07 75-25-2 0.95 1 10/26/19 18:07 74-83-9 3.2 1 10/26/19 18:07 78-93-3 0.79 1 10/26/19 18:07 75-15-0 0.42 1 10/26/19 18:07 56-23-5 0.53 1 10/26/19 18:07 108-90-7 0.52 1 10/26/19 18:07 75-00-3 0.58 1 10/26/19 18:07 67-66-3 0.38 1 10/26/19 18:07 74-87-3 0.55 1 10/26/19 18:07 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 69 of 157 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N 6. N N N N 19.7 1.4 N N N N N N D ug/L 100 D ug/L 200 7 ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 J ug/L 100 J ug/L 100 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 D ug/L 2.0 0.14 1 11/05/1913:10 11/05/1919:59 7439-97-6 8.2 1 10/26/19 18:07 67-64-1 2.5 1 10/26/19 18:07 107-13-1 0.20 1 10/26/19 18:07 71-43-2 0.50 1 10/26/19 18:07 74-97-5 0.36 1 10/26/19 18:07 75-27-4 0.55 1 10/26/19 18:07 75-25-2 0.95 1 10/26/19 18:07 74-83-9 3.2 1 10/26/19 18:07 78-93-3 0.79 1 10/26/19 18:07 75-15-0 0.42 1 10/26/19 18:07 56-23-5 0.53 1 10/26/19 18:07 108-90-7 0.52 1 10/26/19 18:07 75-00-3 0.58 1 10/26/19 18:07 67-66-3 0.38 1 10/26/19 18:07 74-87-3 0.55 1 10/26/19 18:07 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 69 of 157 0.14 1 11/05/1913:10 11/05/1919:59 7439-97-6 8.2 1 10/26/19 18:07 67-64-1 2.5 1 10/26/19 18:07 107-13-1 0.20 1 10/26/19 18:07 71-43-2 0.50 1 10/26/19 18:07 74-97-5 0.36 1 10/26/19 18:07 75-27-4 0.55 1 10/26/19 18:07 75-25-2 0.95 1 10/26/19 18:07 74-83-9 3.2 1 10/26/19 18:07 78-93-3 0.79 1 10/26/19 18:07 75-15-0 0.42 1 10/26/19 18:07 56-23-5 0.53 1 10/26/19 18:07 108-90-7 0.52 1 10/26/19 18:07 75-00-3 0.58 1 10/26/19 18:07 67-66-3 0.38 1 10/26/19 18:07 74-87-3 0.55 1 10/26/19 18:07 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 69 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 B Page 69 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-32R Lab ID: 2624501032 Collected: 10/15/19 09:38 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1918:07 124-48-1 ND ug/L 2.0 0.28 1 10/26/1918:07 106-93-4 ND ug/L 10.0 0.62 1 10/26/1918:07 74-95-3 ND ug/L 5.0 0.49 1 10/26/1918:07 95-50-1 ND ug/L 1.0 0.58 1 10/26/1918:07 106-46-7 ND ug/L 100 1.6 1 10/26/1918:07 110-57-6 ND ug/L 5.0 0.41 1 10/26/1918:07 75-34-3 ND ug/L 1.0 0.67 1 10/26/1918:07 107-06-2 ND ug/L 5.0 0.72 1 10/26/1918:07 75-35-4 4.OJ ug/L 5.0 0.66 1 10/26/1918:07 156-59-2 ND ug/L 5.0 0.46 1 10/26/1918:07 156-60-5 ND ug/L 1.0 0.60 1 10/26/1918:07 78-87-5 ND ug/L 1.0 0.22 1 10/26/1918:07 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1918:07 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1918:07 100-41-4 ND ug/L 50.0 0.89 1 10/26/1918:07 591-78-6 ND ug/L 10.0 3.1 1 10/26/1918:07 74-88-4 ND ug/L 1.0 0.50 1 10/26/1918:07 75-09-2 ND ug/L 100 0.86 1 10/26/1918:07 108-10-1 ND ug/L 1.0 0.50 1 10/26/1918:07 100-42-5 ND ug/L 5.0 0.32 1 10/26/1918:07 630-20-6 ND ug/L 3.0 0.53 1 10/26/1918:07 79-34-5 ND ug/L 1.0 0.78 1 10/26/1918:07 127-18-4 ND ug/L 1.0 0.31 1 10/26/1918:07 108-88-3 ND ug/L 1.0 0.38 1 10/26/1918:07 71-55-6 ND ug/L 1.0 0.59 1 10/26/1918:07 79-00-5 0.61J ug/L 1.0 0.34 1 10/26/1918:07 79-01-6 ND ug/L 1.0 0.51 1 10/26/1918:07 75-69-4 ND ug/L 1.0 0.46 1 10/26/1918:07 96-18-4 ND ug/L 50.0 0.42 1 10/26/1918:07 108-05-4 2.1 ug/L 1.0 0.60 1 10/26/1918:07 75-01-4 ND ug/L 5.0 1.5 1 10/26/1918:07 1330-20-7 103 %. 81-119 1 10/26/1918:07 17060-07-0 100 %. 82-114 1 10/26/1918:07 1868-53-7 97 %. 82-120 1 10/26/1918:07 460-00-4 100 %. 82-109 1 10/26/1918:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-33 Lab ID: 2624501033 Collected: 10/15/19 10:44 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By WF 1 10/15/19 10:44 Field pH 5.32 Std. Units 1 10/15/19 10:44 Field Temperature 17.0 deg C 1 10/15/19 10:44 Field Specific 326 umhos/c 1 10/15/19 10:44 Conductance m Field Turbidity 4.29 NTU 1 10/15/19 10:44 Oxygen, Dissolved 1.41 mg/L 1 10/15/19 10:44 7782-44-7 N2 Depth to Water 28.06 feet 1 10/15/19 10:44 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:44 7440-36-0 Arsenic ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:44 7440-38-2 Barium 119 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:44 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:44 7440-41-7 Cadmium 0.28J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:44 7440-43-9 Chromium 1.5J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:44 7440-47-3 Cobalt 6.8J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:44 7440-48-4 Copper 11.5 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:44 7440-50-8 Lead 0.50J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:44 7439-92-1 Nickel 3.1J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:44 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:44 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:44 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:44 7440-28-0 Vanadium 1.1J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:44 7440-62-2 Zinc 13.8 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:44 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:02 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 18:37 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 18:37 107-13-1 Benzene 3.7 ug/L 1.0 0.20 1 10/26/19 18:37 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 18:37 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 18:37 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 18:37 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 18:37 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 18:37 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 18:37 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 18:37 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 18:37 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 18:37 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 18:37 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 18:37 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 18:37 96-12-8 chloropropane REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-33 Lab ID: 2624501033 Collected: 10/15/19 10:44 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1918:37 124-48-1 ND ug/L 2.0 0.28 1 10/26/1918:37 106-93-4 ND ug/L 10.0 0.62 1 10/26/1918:37 74-95-3 ND ug/L 5.0 0.49 1 10/26/1918:37 95-50-1 ND ug/L 1.0 0.58 1 10/26/1918:37 106-46-7 ND ug/L 100 1.6 1 10/26/1918:37 110-57-6 1.2J ug/L 5.0 0.41 1 10/26/1918:37 75-34-3 1.5 ug/L 1.0 0.67 1 10/26/1918:37 107-06-2 ND ug/L 5.0 0.72 1 10/26/1918:37 75-35-4 3.2J ug/L 5.0 0.66 1 10/26/1918:37 156-59-2 0.68J ug/L 5.0 0.46 1 10/26/1918:37 156-60-5 ND ug/L 1.0 0.60 1 10/26/1918:37 78-87-5 ND ug/L 1.0 0.22 1 10/26/1918:37 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1918:37 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1918:37 100-41-4 ND ug/L 50.0 0.89 1 10/26/1918:37 591-78-6 ND ug/L 10.0 3.1 1 10/26/1918:37 74-88-4 0.69J ug/L 1.0 0.50 1 10/26/1918:37 75-09-2 ND ug/L 100 0.86 1 10/26/1918:37 108-10-1 ND ug/L 1.0 0.50 1 10/26/1918:37 100-42-5 ND ug/L 5.0 0.32 1 10/26/1918:37 630-20-6 ND ug/L 3.0 0.53 1 10/26/1918:37 79-34-5 ND ug/L 1.0 0.78 1 10/26/1918:37 127-18-4 ND ug/L 1.0 0.31 1 10/26/1918:37 108-88-3 ND ug/L 1.0 0.38 1 10/26/1918:37 71-55-6 ND ug/L 1.0 0.59 1 10/26/1918:37 79-00-5 1.2 ug/L 1.0 0.34 1 10/26/1918:37 79-01-6 ND ug/L 1.0 0.51 1 10/26/1918:37 75-69-4 ND ug/L 1.0 0.46 1 10/26/1918:37 96-18-4 ND ug/L 50.0 0.42 1 10/26/1918:37 108-05-4 2.5 ug/L 1.0 0.60 1 10/26/1918:37 75-01-4 ND ug/L 5.0 1.5 1 10/26/1918:37 1330-20-7 102 %. 81-119 1 10/26/1918:37 17060-07-0 98 %. 82-114 1 10/26/1918:37 1868-53-7 98 %. 82-120 1 10/26/1918:37 460-00-4 101 %. 82-109 1 10/26/1918:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-34 Lab ID: 2624501034 Collected: 10/15/19 11:11 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Collected By Field pH Field Temperature Field Specific Conductance Field Turbidity Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Date: 11/23/2019 08:19 PM Analytical Method: WF 1 10/15/19 11:11 5.27 Std. Units 1 10/15/19 11:11 16.6 deg C 1 10/15/19 11:11 322 umhos/c 1 10/15/19 11:11 m 5.84 NTU 1 10/15/19 11:11 1.67 mg/L 1 10/15/19 11:11 7782-44-7 N2 30.10 feet 1 10/15/19 11:11 Analytical Method: EPA 6020B Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:50 7440-36-0 ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:50 7440-38-2 198 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:50 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:50 7440-41-7 ND ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:50 7440-43-9 3.5J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:50 7440-47-3 1.3J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:50 7440-48-4 19.7 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:50 7440-50-8 0.23J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:50 7439-92-1 5.1 J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:50 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:50 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:50 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:50 7440-28-0 1.1J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:50 7440-62-2 17.1 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:50 7440-66-6 B Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 Analytical Method: EPA 8260D N N 5. N N N N N N N 0.97 N N N N D ug/L 100 D ug/L 200 6 ug/L 1.0 D ug/L 3.0 D ug/L 1.0 D ug/L 3.0 D ug/L 10.0 D ug/L 100 D ug/L 100 D ug/L 1.0 J ug/L 3.0 D ug/L 10.0 D ug/L 5.0 D ug/L 1.0 D ug/L 2.0 0.14 1 11/05/19 13:10 11/05/19 20:04 7439-97-6 8.2 1 10/26/19 19:07 67-64-1 2.5 1 10/26/19 19:07 107-13-1 0.20 1 10/26/19 19:07 71-43-2 0.50 1 10/26/19 19:07 74-97-5 0.36 1 10/26/19 19:07 75-27-4 0.55 1 10/26/19 19:07 75-25-2 0.95 1 10/26/19 19:07 74-83-9 3.2 1 10/26/19 19:07 78-93-3 0.79 1 10/26/19 19:07 75-15-0 0.42 1 10/26/19 19:07 56-23-5 0.53 1 10/26/19 19:07 108-90-7 0.52 1 10/26/19 19:07 75-00-3 0.58 1 10/26/19 19:07 67-66-3 0.38 1 10/26/19 19:07 74-87-3 0.55 1 10/26/19 19:07 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 157 0.14 1 11/05/19 13:10 11/05/19 20:04 7439-97-6 8.2 1 10/26/19 19:07 67-64-1 2.5 1 10/26/19 19:07 107-13-1 0.20 1 10/26/19 19:07 71-43-2 0.50 1 10/26/19 19:07 74-97-5 0.36 1 10/26/19 19:07 75-27-4 0.55 1 10/26/19 19:07 75-25-2 0.95 1 10/26/19 19:07 74-83-9 3.2 1 10/26/19 19:07 78-93-3 0.79 1 10/26/19 19:07 75-15-0 0.42 1 10/26/19 19:07 56-23-5 0.53 1 10/26/19 19:07 108-90-7 0.52 1 10/26/19 19:07 75-00-3 0.58 1 10/26/19 19:07 67-66-3 0.38 1 10/26/19 19:07 74-87-3 0.55 1 10/26/19 19:07 96-12-8 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 157 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: 1304-MW-34 Lab ID: 2624501034 Collected: 10/15/19 11:11 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 3.0 0.31 1 10/26/1919:07 124-48-1 ND ug/L 2.0 0.28 1 10/26/1919:07 106-93-4 ND ug/L 10.0 0.62 1 10/26/1919:07 74-95-3 ND ug/L 5.0 0.49 1 10/26/1919:07 95-50-1 2.7 ug/L 1.0 0.58 1 10/26/1919:07 106-46-7 ND ug/L 100 1.6 1 10/26/1919:07 110-57-6 1.3J ug/L 5.0 0.41 1 10/26/1919:07 75-34-3 4.1 ug/L 1.0 0.67 1 10/26/1919:07 107-06-2 ND ug/L 5.0 0.72 1 10/26/1919:07 75-35-4 12.5 ug/L 5.0 0.66 1 10/26/1919:07 156-59-2 0.88J ug/L 5.0 0.46 1 10/26/1919:07 156-60-5 0.89J ug/L 1.0 0.60 1 10/26/1919:07 78-87-5 ND ug/L 1.0 0.22 1 10/26/1919:07 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1919:07 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1919:07 100-41-4 ND ug/L 50.0 0.89 1 10/26/1919:07 591-78-6 ND ug/L 10.0 3.1 1 10/26/1919:07 74-88-4 ND ug/L 1.0 0.50 1 10/26/1919:07 75-09-2 ND ug/L 100 0.86 1 10/26/1919:07 108-10-1 ND ug/L 1.0 0.50 1 10/26/1919:07 100-42-5 ND ug/L 5.0 0.32 1 10/26/1919:07 630-20-6 ND ug/L 3.0 0.53 1 10/26/1919:07 79-34-5 0.97J ug/L 1.0 0.78 1 10/26/1919:07 127-18-4 ND ug/L 1.0 0.31 1 10/26/1919:07 108-88-3 ND ug/L 1.0 0.38 1 10/26/1919:07 71-55-6 ND ug/L 1.0 0.59 1 10/26/1919:07 79-00-5 1.2 ug/L 1.0 0.34 1 10/26/1919:07 79-01-6 ND ug/L 1.0 0.51 1 10/26/1919:07 75-69-4 ND ug/L 1.0 0.46 1 10/26/1919:07 96-18-4 ND ug/L 50.0 0.42 1 10/26/1919:07 108-05-4 0.99J ug/L 1.0 0.60 1 10/26/1919:07 75-01-4 ND ug/L 5.0 1.5 1 10/26/1919:07 1330-20-7 105 %. 81-119 1 10/26/1919:07 17060-07-0 99 %. 82-114 1 10/26/1919:07 1868-53-7 100 %. 82-120 1 10/26/1919:07 460-00-4 100 %. 82-109 1 10/26/1919:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 74 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: DUPLICATE Lab ID: 2624501035 Collected: 10/15/19 00:00 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1.1-Dichloroethene Date: 11/23/2019 08:19 PM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:41 11/01/19 21:56 7440-36-0 ND ug/L 10.0 0.35 1 10/31/19 21:41 11/01/19 21:56 7440-38-2 195 ug/L 100 0.49 1 10/31/19 21:41 11/01/19 21:56 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:41 11/01/19 21:56 7440-41-7 0.14J ug/L 1.0 0.11 1 10/31/19 21:41 11/01/19 21:56 7440-43-9 2.9J ug/L 10.0 0.39 1 10/31/19 21:41 11/01/19 21:56 7440-47-3 1.5J ug/L 10.0 0.30 1 10/31/19 21:41 11/01/19 21:56 7440-48-4 17.2 ug/L 10.0 0.19 1 10/31/19 21:41 11/01/19 21:56 7440-50-8 0.33J ug/L 10.0 0.046 1 10/31/19 21:41 11/01/19 21:56 7439-92-1 3.8J ug/L 50.0 0.31 1 10/31/19 21:41 11/01/19 21:56 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:41 11/01/19 21:56 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:41 11/01/19 21:56 7440-22-4 ND ug/L 5.5 0.052 1 10/31/19 21:41 11/01/19 21:56 7440-28-0 1.4J ug/L 25.0 0.71 1 10/31/19 21:41 11/01/19 21:56 7440-62-2 18.8 ug/L 10.0 1.5 1 10/31/19 21:41 11/01/19 21:56 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.15J ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:07 7439-97-6 Analytical Method: EPA 8260D ND ug/L 100 8.2 1 10/26/1919:37 67-64-1 ND ug/L 200 2.5 1 10/26/1919:37 107-13-1 4.8 ug/L 1.0 0.20 1 10/26/1919:37 71-43-2 ND ug/L 3.0 0.50 1 10/26/1919:37 74-97-5 ND ug/L 1.0 0.36 1 10/26/1919:37 75-27-4 ND ug/L 3.0 0.55 1 10/26/1919:37 75-25-2 ND ug/L 10.0 0.95 1 10/26/1919:37 74-83-9 ND ug/L 100 3.2 1 10/26/1919:37 78-93-3 ND ug/L 100 0.79 1 10/26/1919:37 75-15-0 ND ug/L 1.0 0.42 1 10/26/1919:37 56-23-5 0.89J ug/L 3.0 0.53 1 10/26/1919:37 108-90-7 ND ug/L 10.0 0.52 1 10/26/1919:37 75-00-3 ND ug/L 5.0 0.58 1 10/26/1919:37 67-66-3 ND ug/L 1.0 0.38 1 10/26/1919:37 74-87-3 ND ug/L 2.0 0.55 1 10/26/1919:37 96-12-8 ND ug/L 3.0 0.31 1 10/26/1919:37 124-48-1 ND ug/L 2.0 0.28 1 10/26/1919:37 106-93-4 ND ug/L 10.0 0.62 1 10/26/1919:37 74-95-3 ND ug/L 5.0 0.49 1 10/26/1919:37 95-50-1 2.6 ug/L 1.0 0.58 1 10/26/1919:37 106-46-7 ND ug/L 100 1.6 1 10/26/1919:37 110-57-6 1.3J ug/L 5.0 0.41 1 10/26/1919:37 75-34-3 4.0 ug/L 1.0 0.67 1 10/26/1919:37 107-06-2 ND ug/L 5.0 0.72 1 10/26/1919:37 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 75 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: DUPLICATE Lab ID: 2624501035 Collected: 10/15/19 00:00 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D 11.8 ug/L 5.0 0.66 1 10/26/1919:37 156-59-2 0.91J ug/L 5.0 0.46 1 10/26/1919:37 156-60-5 0.95J ug/L 1.0 0.60 1 10/26/1919:37 78-87-5 ND ug/L 1.0 0.22 1 10/26/1919:37 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1919:37 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1919:37 100-41-4 ND ug/L 50.0 0.89 1 10/26/1919:37 591-78-6 ND ug/L 10.0 3.1 1 10/26/1919:37 74-88-4 ND ug/L 1.0 0.50 1 10/26/1919:37 75-09-2 ND ug/L 100 0.86 1 10/26/1919:37 108-10-1 ND ug/L 1.0 0.50 1 10/26/1919:37 100-42-5 ND ug/L 5.0 0.32 1 10/26/1919:37 630-20-6 ND ug/L 3.0 0.53 1 10/26/1919:37 79-34-5 1.0 ug/L 1.0 0.78 1 10/26/1919:37 127-18-4 ND ug/L 1.0 0.31 1 10/26/1919:37 108-88-3 ND ug/L 1.0 0.38 1 10/26/1919:37 71-55-6 ND ug/L 1.0 0.59 1 10/26/1919:37 79-00-5 1.1 ug/L 1.0 0.34 1 10/26/1919:37 79-01-6 ND ug/L 1.0 0.51 1 10/26/1919:37 75-69-4 ND ug/L 1.0 0.46 1 10/26/1919:37 96-18-4 ND ug/L 50.0 0.42 1 10/26/1919:37 108-05-4 0.93J ug/L 1.0 0.60 1 10/26/1919:37 75-01-4 ND ug/L 5.0 1.5 1 10/26/1919:37 1330-20-7 104 %. 81-119 1 10/26/1919:37 17060-07-0 97 %. 82-114 1 10/26/1919:37 1868-53-7 100 %. 82-120 1 10/26/1919:37 460-00-4 100 %. 82-109 1 10/26/1919:37 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Equipment Blank Lab ID: 2624501036 Collected: 10/17/19 17:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1.1-Dichloroethene Date: 11/23/2019 08:19 PM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 6.0 0.27 1 10/31/19 21:48 11/01/19 19:11 7440-36-0 0.77J ug/L 10.0 0.35 1 10/31/19 21:48 11/01/19 19:11 7440-38-2 B ND ug/L 100 0.49 1 10/31/19 21:48 11/01/19 19:11 7440-39-3 ND ug/L 1.0 0.074 1 10/31/19 21:48 11/01/19 19:11 7440-41-7 ND ug/L 1.0 0.11 1 10/31/19 21:48 11/01/19 19:11 7440-43-9 ND ug/L 10.0 0.39 1 10/31/19 21:48 11/01/19 19:11 7440-47-3 ND ug/L 10.0 0.30 1 10/31/19 21:48 11/01/19 19:11 7440-48-4 0.79J ug/L 10.0 0.19 1 10/31/19 21:48 11/01/19 19:11 7440-50-8 0.058J ug/L 10.0 0.046 1 10/31/19 21:48 11/01/19 19:11 7439-92-1 ND ug/L 50.0 0.31 1 10/31/19 21:48 11/01/19 19:11 7440-02-0 ND ug/L 10.0 1.3 1 10/31/19 21:48 11/01/19 19:11 7782-49-2 ND ug/L 10.0 0.28 1 10/31/19 21:48 11/01/19 19:11 7440-22-4 0.075J ug/L 5.5 0.052 1 10/31/19 21:48 11/01/19 19:11 7440-28-0 0.78J ug/L 25.0 0.71 1 10/31/19 21:48 11/01/19 19:11 7440-62-2 6.OJ ug/L 10.0 1.5 1 10/31/19 21:48 11/01/19 19:11 7440-66-6 B Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:09 7439-97-6 Analytical Method: EPA 8260D ND ug/L 100 8.2 1 10/31/19 21:03 67-64-1 ND ug/L 200 2.5 1 10/31/19 21:03 107-13-1 ND ug/L 1.0 0.20 1 10/31/19 21:03 71-43-2 ND ug/L 3.0 0.50 1 10/31/19 21:03 74-97-5 ND ug/L 1.0 0.36 1 10/31/19 21:03 75-27-4 ND ug/L 3.0 0.55 1 10/31/19 21:03 75-25-2 ND ug/L 10.0 0.95 1 10/31/19 21:03 74-83-9 ND ug/L 100 3.2 1 10/31/19 21:03 78-93-3 ND ug/L 100 0.79 1 10/31/19 21:03 75-15-0 ND ug/L 1.0 0.42 1 10/31/19 21:03 56-23-5 ND ug/L 3.0 0.53 1 10/31/19 21:03 108-90-7 ND ug/L 10.0 0.52 1 10/31/19 21:03 75-00-3 ND ug/L 5.0 0.58 1 10/31/19 21:03 67-66-3 ND ug/L 1.0 0.38 1 10/31/19 21:03 74-87-3 ND ug/L 2.0 0.55 1 10/31/19 21:03 96-12-8 ND ug/L 3.0 0.31 1 10/31/19 21:03 124-48-1 ND ug/L 2.0 0.28 1 10/31/19 21:03 106-93-4 ND ug/L 10.0 0.62 1 10/31/19 21:03 74-95-3 ND ug/L 5.0 0.49 1 10/31/19 21:03 95-50-1 ND ug/L 1.0 0.58 1 10/31/19 21:03 106-46-7 ND ug/L 100 1.6 1 10/31/19 21:03 110-57-6 ND ug/L 5.0 0.41 1 10/31/19 21:03 75-34-3 ND ug/L 1.0 0.67 1 10/31/19 21:03 107-06-2 ND ug/L 5.0 0.72 1 10/31/19 21:03 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 77 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Equipment Blank Lab ID: 2624501036 Collected: 10/17/19 17:05 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 5.0 0.66 1 10/31/19 21:03 156-59-2 ND ug/L 5.0 0.46 1 10/31/19 21:03 156-60-5 ND ug/L 1.0 0.60 1 10/31/19 21:03 78-87-5 ND ug/L 1.0 0.22 1 10/31/19 21:03 10061-01-5 ND ug/L 1.0 0.30 1 10/31/19 21:03 10061-02-6 ND ug/L 1.0 0.45 1 10/31/19 21:03 100-41-4 ND ug/L 50.0 0.89 1 10/31/19 21:03 591-78-6 ND ug/L 10.0 3.1 1 10/31/19 21:03 74-88-4 ND ug/L 1.0 0.50 1 10/31/19 21:03 75-09-2 ND ug/L 100 0.86 1 10/31/19 21:03 108-10-1 ND ug/L 1.0 0.50 1 10/31/19 21:03 100-42-5 ND ug/L 5.0 0.32 1 10/31/19 21:03 630-20-6 ND ug/L 3.0 0.53 1 10/31/19 21:03 79-34-5 ND ug/L 1.0 0.78 1 10/31/19 21:03 127-18-4 ND ug/L 1.0 0.31 1 10/31/19 21:03 108-88-3 ND ug/L 1.0 0.38 1 10/31/19 21:03 71-55-6 ND ug/L 1.0 0.59 1 10/31/19 21:03 79-00-5 ND ug/L 1.0 0.34 1 10/31/19 21:03 79-01-6 ND ug/L 1.0 0.51 1 10/31/19 21:03 75-69-4 ND ug/L 1.0 0.46 1 10/31/19 21:03 96-18-4 ND ug/L 50.0 0.42 1 10/31/19 21:03 108-05-4 ND ug/L 1.0 0.60 1 10/31/19 21:03 75-01-4 ND ug/L 5.0 1.5 1 10/31/19 21:03 1330-20-7 105 %. 81-119 1 10/31/19 21:03 17060-07-0 102 %. 82-114 1 10/31/19 21:03 1868-53-7 107 %. 82-120 1 10/31/19 21:03 460-00-4 105 %. 82-109 1 10/31/19 21:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 78 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Field Blank Lab ID: 2624501037 Collected: 10/15/19 09:42 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 6.0 0.27 1 10/31/19 21:48 11/01/19 19:17 7440-36-0 Arsenic 0.59J ug/L 10.0 0.35 1 10/31/19 21:48 11/01/19 19:17 7440-38-2 B Barium ND ug/L 100 0.49 1 10/31/19 21:48 11/01/19 19:17 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:48 11/01/19 19:17 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:48 11/01/19 19:17 7440-43-9 Chromium ND ug/L 10.0 0.39 1 10/31/19 21:48 11/01/19 19:17 7440-47-3 Cobalt ND ug/L 10.0 0.30 1 10/31/19 21:48 11/01/19 19:17 7440-48-4 Copper 0.70J ug/L 10.0 0.19 1 10/31/19 21:48 11/01/19 19:17 7440-50-8 Lead ND ug/L 10.0 0.046 1 10/31/19 21:48 11/01/19 19:17 7439-92-1 Nickel ND ug/L 50.0 0.31 1 10/31/19 21:48 11/01/19 19:17 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:48 11/01/19 19:17 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:48 11/01/19 19:17 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:48 11/01/19 19:17 7440-28-0 Vanadium 0.74J ug/L 25.0 0.71 1 10/31/19 21:48 11/01/19 19:17 7440-62-2 Zinc 5.5J ug/L 10.0 1.5 1 10/31/19 21:48 11/01/19 19:17 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:16 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/26/19 20:07 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/26/19 20:07 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/26/19 20:07 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/26/19 20:07 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/26/19 20:07 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/26/19 20:07 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/26/19 20:07 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/26/19 20:07 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/26/19 20:07 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/26/19 20:07 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/26/19 20:07 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/26/19 20:07 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/26/19 20:07 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/26/19 20:07 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/26/19 20:07 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/26/19 20:07 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 10/26/19 20:07 106-93-4 Dibromomethane ND ug/L 10.0 0.62 1 10/26/19 20:07 74-95-3 1,2-Dichlorobenzene ND ug/L 5.0 0.49 1 10/26/19 20:07 95-50-1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 10/26/19 20:07 106-46-7 trans-1,4-Dichloro-2- ND ug/L 100 1.6 1 10/26/19 20:07 110-57-6 butene 1,1-Dichloroethane ND ug/L 5.0 0.41 1 10/26/19 20:07 75-34-3 1,2-Dichloroethane ND ug/L 1.0 0.67 1 10/26/19 20:07 107-06-2 1,1-Dichloroethene ND ug/L 5.0 0.72 1 10/26/19 20:07 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 79 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Field Blank Lab ID: 2624501037 Collected: 10/15/19 09:42 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-M ethyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 5.0 0.66 1 10/26/19 20:07 156-59-2 ND ug/L 5.0 0.46 1 10/26/19 20:07 156-60-5 ND ug/L 1.0 0.60 1 10/26/19 20:07 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 20:07 10061-01-5 ND ug/L 1.0 0.30 1 10/26/19 20:07 10061-02-6 ND ug/L 1.0 0.45 1 10/26/19 20:07 100-41-4 ND ug/L 50.0 0.89 1 10/26/19 20:07 591-78-6 ND ug/L 10.0 3.1 1 10/26/19 20:07 74-88-4 ND ug/L 1.0 0.50 1 10/26/19 20:07 75-09-2 ND ug/L 100 0.86 1 10/26/19 20:07 108-10-1 ND ug/L 1.0 0.50 1 10/26/19 20:07 100-42-5 ND ug/L 5.0 0.32 1 10/26/19 20:07 630-20-6 ND ug/L 3.0 0.53 1 10/26/19 20:07 79-34-5 ND ug/L 1.0 0.78 1 10/26/19 20:07 127-18-4 ND ug/L 1.0 0.31 1 10/26/19 20:07 108-88-3 ND ug/L 1.0 0.38 1 10/26/19 20:07 71-55-6 ND ug/L 1.0 0.59 1 10/26/19 20:07 79-00-5 ND ug/L 1.0 0.34 1 10/26/19 20:07 79-01-6 ND ug/L 1.0 0.51 1 10/26/19 20:07 75-69-4 ND ug/L 1.0 0.46 1 10/26/19 20:07 96-18-4 ND ug/L 50.0 0.42 1 10/26/19 20:07 108-05-4 ND ug/L 1.0 0.60 1 10/26/19 20:07 75-01-4 ND ug/L 5.0 1.5 1 10/26/19 20:07 1330-20-7 104 %. 81-119 1 10/26/19 20:07 17060-07-0 97 %. 82-114 1 10/26/19 20:07 1868-53-7 99 %. 82-120 1 10/26/19 20:07 460-00-4 101 %. 82-109 1 10/26/19 20:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 80 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Trip Blank Lab ID: 2624501038 Collected: 10/14/19 00:00 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 100 8.2 1 10/26/1914:50 67-64-1 ND ug/L 200 2.5 1 10/26/1914:50 107-13-1 ND ug/L 1.0 0.20 1 10/26/1914:50 71-43-2 ND ug/L 3.0 0.50 1 10/26/1914:50 74-97-5 ND ug/L 1.0 0.36 1 10/26/1914:50 75-27-4 ND ug/L 3.0 0.55 1 10/26/1914:50 75-25-2 ND ug/L 10.0 0.95 1 10/26/1914:50 74-83-9 ND ug/L 100 3.2 1 10/26/1914:50 78-93-3 ND ug/L 100 0.79 1 10/26/1914:50 75-15-0 ND ug/L 1.0 0.42 1 10/26/1914:50 56-23-5 ND ug/L 3.0 0.53 1 10/26/1914:50 108-90-7 ND ug/L 10.0 0.52 1 10/26/1914:50 75-00-3 ND ug/L 5.0 0.58 1 10/26/1914:50 67-66-3 ND ug/L 1.0 0.38 1 10/26/1914:50 74-87-3 ND ug/L 2.0 0.55 1 10/26/1914:50 96-12-8 ND ug/L 3.0 0.31 1 10/26/1914:50 124-48-1 ND ug/L 2.0 0.28 1 10/26/1914:50 106-93-4 ND ug/L 10.0 0.62 1 10/26/1914:50 74-95-3 ND ug/L 5.0 0.49 1 10/26/1914:50 95-50-1 ND ug/L 1.0 0.58 1 10/26/1914:50 106-46-7 ND ug/L 100 1.6 1 10/26/1914:50 110-57-6 ND ug/L 5.0 0.41 1 10/26/1914:50 75-34-3 ND ug/L 1.0 0.67 1 10/26/1914:50 107-06-2 ND ug/L 5.0 0.72 1 10/26/1914:50 75-35-4 ND ug/L 5.0 0.66 1 10/26/1914:50 156-59-2 ND ug/L 5.0 0.46 1 10/26/1914:50 156-60-5 ND ug/L 1.0 0.60 1 10/26/1914:50 78-87-5 ND ug/L 1.0 0.22 1 10/26/19 14:50 10061-01-5 ND ug/L 1.0 0.30 1 10/26/1914:50 10061-02-6 ND ug/L 1.0 0.45 1 10/26/1914:50 100-41-4 ND ug/L 50.0 0.89 1 10/26/1914:50 591-78-6 ND ug/L 10.0 3.1 1 10/26/1914:50 74-88-4 ND ug/L 1.0 0.50 1 10/26/1914:50 75-09-2 ND ug/L 100 0.86 1 10/26/1914:50 108-10-1 ND ug/L 1.0 0.50 1 10/26/1914:50 100-42-5 ND ug/L 5.0 0.32 1 10/26/1914:50 630-20-6 ND ug/L 3.0 0.53 1 10/26/1914:50 79-34-5 ND ug/L 1.0 0.78 1 10/26/1914:50 127-18-4 ND ug/L 1.0 0.31 1 10/26/1914:50 108-88-3 ND ug/L 1.0 0.38 1 10/26/1914:50 71-55-6 ND ug/L 1.0 0.59 1 10/26/1914:50 79-00-5 ND ug/L 1.0 0.34 1 10/26/1914:50 79-01-6 ND ug/L 1.0 0.51 1 10/26/1914:50 75-69-4 ND ug/L 1.0 0.46 1 10/26/1914:50 96-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 81 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: Trip Blank Lab ID: 2624501038 Collected: 10/14/19 00:00 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Vinyl acetate ND ug/L 50.0 0.42 1 10/26/19 14:50 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 10/26/19 14:50 75-01-4 Xylene (Total) ND ug/L 5.0 1.5 1 10/26/19 14:50 1330-20-7 Surrogates 1,2-Dichloroethane-d4 (S) 106 %. 81-119 1 10/26/19 14:50 17060-07-0 Dibromofluoromethane (S) 105 %. 82-114 1 10/26/19 14:50 1868-53-7 4-Bromofluorobenzene (S) 105 %. 82-120 1 10/26/19 14:50 460-00-4 Toluene-d8 (S) 107 %. 82-109 1 10/26/19 14:50 2037-26-5 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: SW-1 Lab ID: 2624501039 Collected: 10/17/19 10:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/17/19 10:13 Field pH 8.01 Std. Units 1 10/17/19 10:13 Field Temperature 14.4 deg C 1 10/17/19 10:13 Field Specific 213 umhos/c 1 10/17/19 10:13 Conductance m Field Turbidity 18 NTU 1 10/17/19 10:13 Oxygen, Dissolved 9.18 mg/L 1 10/17/19 10:13 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony 0.33J ug/L 6.0 0.27 1 10/31/19 21:48 11/01/19 19:22 7440-36-0 Arsenic 1.7J ug/L 10.0 0.35 1 10/31/19 21:48 11/01/19 19:22 7440-38-2 B Barium 44.5J ug/L 100 0.49 1 10/31/19 21:48 11/01/19 19:22 7440-39-3 Beryllium 0.084J ug/L 1.0 0.074 1 10/31/19 21:48 11/01/19 19:22 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:48 11/01/19 19:22 7440-43-9 Chromium 2.OJ ug/L 10.0 0.39 1 10/31/19 21:48 11/01/19 19:22 7440-47-3 Cobalt 1.7J ug/L 10.0 0.30 1 10/31/19 21:48 11/01/19 19:22 7440-48-4 Copper 6.7J ug/L 10.0 0.19 1 10/31/19 21:48 11/01/19 19:22 7440-50-8 Lead 1.OJ ug/L 10.0 0.046 1 10/31/19 21:48 11/01/19 19:22 7439-92-1 Nickel 1.6J ug/L 50.0 0.31 1 10/31/19 21:48 11/01/19 19:22 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:48 11/01/19 19:22 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:48 11/01/19 19:22 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:48 11/01/19 19:22 7440-28-0 Vanadium 12.2J ug/L 25.0 0.71 1 10/31/19 21:48 11/01/19 19:22 7440-62-2 Zinc 121 ug/L 10.0 1.5 1 10/31/19 21:48 11/01/19 19:22 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:18 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/31/19 21:28 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/31/19 21:28 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/31/19 21:28 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/31/19 21:28 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/31/19 21:28 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/31/19 21:28 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/31/19 21:28 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/31/19 21:28 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/31/19 21:28 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/31/19 21:28 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/31/19 21:28 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/31/19 21:28 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/31/19 21:28 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/31/19 21:28 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/31/19 21:28 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/31/19 21:28 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: SW-1 Lab ID: 2624501039 Collected: 10/17/19 10:13 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 2.0 0.28 1 10/31/19 21:28 106-93-4 ND ug/L 10.0 0.62 1 10/31/19 21:28 74-95-3 ND ug/L 5.0 0.49 1 10/31/19 21:28 95-50-1 ND ug/L 1.0 0.58 1 10/31/19 21:28 106-46-7 ND ug/L 100 1.6 1 10/31/19 21:28 110-57-6 ND ug/L 5.0 0.41 1 10/31/19 21:28 75-34-3 ND ug/L 1.0 0.67 1 10/31/19 21:28 107-06-2 ND ug/L 5.0 0.72 1 10/31/19 21:28 75-35-4 ND ug/L 5.0 0.66 1 10/31/19 21:28 156-59-2 ND ug/L 5.0 0.46 1 10/31/19 21:28 156-60-5 ND ug/L 1.0 0.60 1 10/31/19 21:28 78-87-5 ND ug/L 1.0 0.22 1 10/31/19 21:28 10061-01-5 ND ug/L 1.0 0.30 1 10/31/19 21:28 10061-02-6 ND ug/L 1.0 0.45 1 10/31/19 21:28 100-41-4 ND ug/L 50.0 0.89 1 10/31/19 21:28 591-78-6 ND ug/L 10.0 3.1 1 10/31/19 21:28 74-88-4 ND ug/L 1.0 0.50 1 10/31/19 21:28 75-09-2 ND ug/L 100 0.86 1 10/31/19 21:28 108-10-1 ND ug/L 1.0 0.50 1 10/31/19 21:28 100-42-5 ND ug/L 5.0 0.32 1 10/31/19 21:28 630-20-6 ND ug/L 3.0 0.53 1 10/31/19 21:28 79-34-5 ND ug/L 1.0 0.78 1 10/31/19 21:28 127-18-4 ND ug/L 1.0 0.31 1 10/31/19 21:28 108-88-3 ND ug/L 1.0 0.38 1 10/31/19 21:28 71-55-6 ND ug/L 1.0 0.59 1 10/31/19 21:28 79-00-5 ND ug/L 1.0 0.34 1 10/31/19 21:28 79-01-6 ND ug/L 1.0 0.51 1 10/31/19 21:28 75-69-4 ND ug/L 1.0 0.46 1 10/31/19 21:28 96-18-4 ND ug/L 50.0 0.42 1 10/31/19 21:28 108-05-4 ND ug/L 1.0 0.60 1 10/31/19 21:28 75-01-4 ND ug/L 5.0 1.5 1 10/31/19 21:28 1330-20-7 107 %. 81-119 1 10/31/19 21:28 17060-07-0 102 %. 82-114 1 10/31/19 21:28 1868-53-7 108 %. 82-120 1 10/31/19 21:28 460-00-4 104 %. 82-109 1 10/31/19 21:28 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 84 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: SW-2 Lab ID: 2624501040 Collected: 10/17/19 07:25 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Collected By James 1 10/17/19 07:25 Field pH 6.11 Std. Units 1 10/17/19 07:25 Field Temperature 13.5 deg C 1 10/17/19 07:25 Field Specific 158 umhos/c 1 10/17/19 07:25 Conductance m Field Turbidity 4.75 NTU 1 10/17/19 07:25 Oxygen, Dissolved 6.20 mg/L 1 10/17/19 07:25 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020B Preparation Method: EPA 3005A Antimony 0.55J ug/L 6.0 0.27 1 10/31/19 21:48 11/01/19 19:45 7440-36-0 Arsenic 1.4J ug/L 10.0 0.35 1 10/31/19 21:48 11/01/19 19:45 7440-38-2 B Barium 25.1J ug/L 100 0.49 1 10/31/19 21:48 11/01/19 19:45 7440-39-3 Beryllium ND ug/L 1.0 0.074 1 10/31/19 21:48 11/01/19 19:45 7440-41-7 Cadmium ND ug/L 1.0 0.11 1 10/31/19 21:48 11/01/19 19:45 7440-43-9 Chromium 0.63J ug/L 10.0 0.39 1 10/31/19 21:48 11/01/19 19:45 7440-47-3 Cobalt 0.54J ug/L 10.0 0.30 1 10/31/19 21:48 11/01/19 19:45 7440-48-4 Copper 3.1J ug/L 10.0 0.19 1 10/31/19 21:48 11/01/19 19:45 7440-50-8 Lead 0.17J ug/L 10.0 0.046 1 10/31/19 21:48 11/01/19 19:45 7439-92-1 Nickel 1.9J ug/L 50.0 0.31 1 10/31/19 21:48 11/01/19 19:45 7440-02-0 Selenium ND ug/L 10.0 1.3 1 10/31/19 21:48 11/01/19 19:45 7782-49-2 Silver ND ug/L 10.0 0.28 1 10/31/19 21:48 11/01/19 19:45 7440-22-4 Thallium ND ug/L 5.5 0.052 1 10/31/19 21:48 11/01/19 19:45 7440-28-0 Vanadium 8.4J ug/L 25.0 0.71 1 10/31/19 21:48 11/01/19 19:45 7440-62-2 Zinc 8.7J ug/L 10.0 1.5 1 10/31/19 21:48 11/01/19 19:45 7440-66-6 B 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 0.14 1 11/05/19 13:10 11/05/19 20:21 7439-97-6 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 100 8.2 1 10/31/19 21:53 67-64-1 Acrylonitrile ND ug/L 200 2.5 1 10/31/19 21:53 107-13-1 Benzene ND ug/L 1.0 0.20 1 10/31/19 21:53 71-43-2 Bromochloromethane ND ug/L 3.0 0.50 1 10/31/19 21:53 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 10/31/19 21:53 75-27-4 Bromoform ND ug/L 3.0 0.55 1 10/31/19 21:53 75-25-2 Bromomethane ND ug/L 10.0 0.95 1 10/31/19 21:53 74-83-9 2-Butanone (MEK) ND ug/L 100 3.2 1 10/31/19 21:53 78-93-3 Carbon disulfide ND ug/L 100 0.79 1 10/31/19 21:53 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 10/31/19 21:53 56-23-5 Chlorobenzene ND ug/L 3.0 0.53 1 10/31/19 21:53 108-90-7 Chloroethane ND ug/L 10.0 0.52 1 10/31/19 21:53 75-00-3 Chloroform ND ug/L 5.0 0.58 1 10/31/19 21:53 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 10/31/19 21:53 74-87-3 1,2-Dibromo-3- ND ug/L 2.0 0.55 1 10/31/19 21:53 96-12-8 chloropropane Dibromochloromethane ND ug/L 3.0 0.31 1 10/31/19 21:53 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 85 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Sample: SW-2 Lab ID: 2624501040 Collected: 10/17/19 07:25 Received: 10/17/19 17:15 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 11/23/2019 08:19 PM Analytical Method: EPA 8260D ND ug/L 2.0 0.28 1 10/31/19 21:53 106-93-4 ND ug/L 10.0 0.62 1 10/31/19 21:53 74-95-3 ND ug/L 5.0 0.49 1 10/31/19 21:53 95-50-1 ND ug/L 1.0 0.58 1 10/31/19 21:53 106-46-7 ND ug/L 100 1.6 1 10/31/19 21:53 110-57-6 ND ug/L 5.0 0.41 1 10/31/19 21:53 75-34-3 ND ug/L 1.0 0.67 1 10/31/19 21:53 107-06-2 ND ug/L 5.0 0.72 1 10/31/19 21:53 75-35-4 ND ug/L 5.0 0.66 1 10/31/19 21:53 156-59-2 ND ug/L 5.0 0.46 1 10/31/19 21:53 156-60-5 ND ug/L 1.0 0.60 1 10/31/19 21:53 78-87-5 ND ug/L 1.0 0.22 1 10/31/19 21:53 10061-01-5 ND ug/L 1.0 0.30 1 10/31/19 21:53 10061-02-6 ND ug/L 1.0 0.45 1 10/31/19 21:53 100-41-4 ND ug/L 50.0 0.89 1 10/31/19 21:53 591-78-6 ND ug/L 10.0 3.1 1 10/31/19 21:53 74-88-4 ND ug/L 1.0 0.50 1 10/31/19 21:53 75-09-2 ND ug/L 100 0.86 1 10/31/19 21:53 108-10-1 ND ug/L 1.0 0.50 1 10/31/19 21:53 100-42-5 ND ug/L 5.0 0.32 1 10/31/19 21:53 630-20-6 ND ug/L 3.0 0.53 1 10/31/19 21:53 79-34-5 ND ug/L 1.0 0.78 1 10/31/19 21:53 127-18-4 ND ug/L 1.0 0.31 1 10/31/19 21:53 108-88-3 ND ug/L 1.0 0.38 1 10/31/19 21:53 71-55-6 ND ug/L 1.0 0.59 1 10/31/19 21:53 79-00-5 ND ug/L 1.0 0.34 1 10/31/19 21:53 79-01-6 ND ug/L 1.0 0.51 1 10/31/19 21:53 75-69-4 ND ug/L 1.0 0.46 1 10/31/19 21:53 96-18-4 ND ug/L 50.0 0.42 1 10/31/19 21:53 108-05-4 ND ug/L 1.0 0.60 1 10/31/19 21:53 75-01-4 ND ug/L 5.0 1.5 1 10/31/19 21:53 1330-20-7 108 %. 81-119 1 10/31/19 21:53 17060-07-0 102 %. 82-114 1 10/31/19 21:53 1868-53-7 105 %. 82-120 1 10/31/19 21:53 460-00-4 107 %. 82-109 1 10/31/19 21:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 86 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 38205 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2624501001, 2624501002, 2624501003, 2624501004, 2624501005, 2624501006, 2624501007, 2624501008, 2624501009,2624501010,2624501011,2624501012,2624501013,2624501014,2624501015,2624501016, 2624501017, 2624501018, 2624501019, 2624501021 METHOD BLANK: 173487 Matrix: Water Associated Lab Samples: 2624501001, 2624501002, 2624501003, 2624501004, 2624501005, 2624501006, 2624501007, 2624501008, 2624501009,2624501010,2624501011,2624501012,2624501013,2624501014,2624501015,2624501016, 2624501017, 2624501018, 2624501019, 2624501021 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.14 11/05/1917:01 LABORATORY CONTROL SAMPLE: 173488 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 99 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 173489 173490 MS MSD 2624501001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.3 2.3 92 90 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 87 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 38216 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2624501022, 2624501023, 2624501024, 2624501025, 2624501027, 2624501028, 2624501029, 2624501030, 2624501031, 2624501032, 2624501033, 2624501034, 2624501035, 2624501036, 2624501037, 2624501039, 2624501040 METHOD BLANK: 173543 Matrix: Water Associated Lab Samples: 2624501022, 2624501023, 2624501024, 2624501025, 2624501027, 2624501028, 2624501029, 2624501030, 2624501031, 2624501032, 2624501033, 2624501034, 2624501035, 2624501036, 2624501037, 2624501039, 2624501040 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.14 11/05/1919:22 LABORATORY CONTROL SAMPLE: 173544 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.5 101 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 173545 173546 MS MSD 2624501022 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.1 2.2 83 86 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37963 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2624501001, 2624501002, 2624501003, 2624501004, 2624501005, 2624501006, 2624501007, 2624501008, 2624501009,2624501010,2624501011,2624501012,2624501013 METHOD BLANK: 172512 Matrix: Water Associated Lab Samples: 2624501001, 2624501002, 2624501003, 2624501004, 2624501005, 2624501006, 2624501007, 2624501008, 2624501009,2624501010,2624501011,2624501012,2624501013 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.27 11/01/19 21:46 Arsenic ug/L 0.62J 10.0 0.35 11/01/19 21:46 Barium ug/L ND 100 0.49 11/01/19 21:46 Beryllium ug/L ND 1.0 0.074 11/01/19 21:46 Cadmium ug/L ND 1.0 0.11 11/01/19 21:46 Chromium ug/L 0.85J 10.0 0.39 11/01/19 21:46 Cobalt ug/L ND 10.0 0.30 11/01/19 21:46 Copper ug/L ND 10.0 0.19 11/01/19 21:46 Lead ug/L ND 10.0 0.046 11/01/19 21:46 Nickel ug/L ND 50.0 0.31 11/01/19 21:46 Selenium ug/L ND 10.0 1.3 11/01/19 21:46 Silver ug/L ND 10.0 0.28 11/01/19 21:46 Thallium ug/L ND 5.5 0.052 11/01/19 21:46 Vanadium ug/L 1AJ 25.0 0.71 11/01/19 21:46 Zinc ug/L 5.3J 10.0 1.5 11/01/19 21:46 LABORATORY CONTROL SAMPLE: Parameter 172513 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 100 110 110 80-120 Arsenic ug/L 100 99.8 100 80-120 Barium ug/L 100 104 104 80-120 Beryllium ug/L 100 102 102 80-120 Cadmium ug/L 100 102 102 80-120 Chromium ug/L 100 99.7 100 80-120 Cobalt ug/L 100 98.6 99 80-120 Copper ug/L 100 102 102 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 101 101 80-120 Selenium ug/L 100 97.1 97 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 100 100 80-120 Vanadium ug/L 100 99.9 100 80-120 Zinc ug/L 100 107 107 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 89 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: CMS V Landfill -Revised Report 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 172514 172515 MS MSD 2624501001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 104 108 104 108 75-125 4 20 Arsenic ug/L 0.46J 100 100 98.7 107 98 106 75-125 8 20 Barium ug/L 136 100 100 227 236 91 100 75-125 4 20 Beryllium ug/L ND 100 100 83.9 93.5 84 93 75-125 11 20 Cadmium ug/L ND 100 100 97.7 103 98 103 75-125 5 20 Chromium ug/L 4.8J 100 100 102 106 97 101 75-125 4 20 Cobalt ug/L 7.7J 100 100 101 107 93 99 75-125 6 20 Copper ug/L 6.6J 100 100 103 106 97 100 75-125 3 20 Lead ug/L 0.66J 100 100 93.2 97.0 93 96 75-125 4 20 Nickel ug/L 8.8J 100 100 103 108 94 99 75-125 4 20 Selenium ug/L ND 100 100 98.8 102 98 101 75-125 3 20 Silver ug/L ND 100 100 97.0 101 97 101 75-125 4 20 Thallium ug/L ND 100 100 93.3 95.9 93 96 75-125 3 20 Vanadium ug/L 3AJ 100 100 102 107 99 104 75-125 5 20 Zinc ug/L 12.1 100 100 107 115 95 103 75-125 7 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37964 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2624501014,2624501015,2624501016,2624501017,2624501018,2624501019,2624501021,2624501022, 2624501023, 2624501024, 2624501025, 2624501027, 2624501028, 2624501029, 2624501030, 2624501031, 2624501032,2624501033,2624501034,2624501035 METHOD BLANK: 172516 Associated Lab Samples: Parameter Matrix: Water 2624501014,2624501015,2624501016,2624501017,2624501018,2624501019,2624501021,2624501022, 2624501023, 2624501024, 2624501025, 2624501027, 2624501028, 2624501029, 2624501030, 2624501031, 2624501032,2624501033,2624501034,2624501035 Blank Reporting Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.27 11/01/1919:15 Arsenic ug/L ND 10.0 0.35 11/01/1919:15 Barium ug/L ND 100 0.49 11/01/1919:15 Beryllium ug/L ND 1.0 0.074 11/01/1919:15 Cadmium ug/L ND 1.0 0.11 11/01/1919:15 Chromium ug/L ND 10.0 0.39 11/01/1919:15 Cobalt ug/L ND 10.0 0.30 11/01/1919:15 Copper ug/L ND 10.0 0.19 11/01/1919:15 Lead ug/L ND 10.0 0.046 11/01/1919:15 Nickel ug/L ND 50.0 0.31 11/01/1919:15 Selenium ug/L ND 10.0 1.3 11/01/1919:15 Silver ug/L ND 10.0 0.28 11/01/1919:15 Thallium ug/L ND 5.5 0.052 11/01/1919:15 Vanadium ug/L ND 25.0 0.71 11/01/1919:15 Zinc ug/L 4.6J 10.0 1.5 11/01/1919:15 LABORATORY CONTROL SAMPLE: 172517 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 105 105 80-120 Arsenic ug/L 100 102 102 80-120 Barium ug/L 100 101 101 80-120 Beryllium ug/L 100 95.7 96 80-120 Cadmium ug/L 100 103 103 80-120 Chromium ug/L 100 99.4 99 80-120 Cobalt ug/L 100 99.6 100 80-120 Copper ug/L 100 101 101 80-120 Lead ug/L 100 102 102 80-120 Nickel ug/L 100 101 101 80-120 Selenium ug/L 100 98.2 98 80-120 Silver ug/L 100 99.8 100 80-120 Thallium ug/L 100 100 100 80-120 Vanadium ug/L 100 98.9 99 80-120 Zinc ug/L 100 105 105 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: CMS V Landfill -Revised Report 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 172518 172519 MS MSD 2624501014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 105 106 105 106 75-125 1 20 Arsenic ug/L ND 100 100 96.1 95.8 96 96 75-125 0 20 Barium ug/L 372 100 100 473 471 102 100 75-125 0 20 Beryllium ug/L ND 100 100 94.8 96.2 95 96 75-125 1 20 Cadmium ug/L ND 100 100 97.2 99.6 97 100 75-125 2 20 Chromium ug/L ND 100 100 101 102 100 102 75-125 1 20 Cobalt ug/L 2.2J 100 100 100 99.2 98 97 75-125 1 20 Copper ug/L 1.11 100 100 98.6 96.7 98 96 75-125 2 20 Lead ug/L ND 100 100 94.1 95.9 94 96 75-125 2 20 Nickel ug/L 75.4 100 100 175 167 99 92 75-125 4 20 Selenium ug/L ND 100 100 91.2 94.6 91 95 75-125 4 20 Silver ug/L ND 100 100 96.5 97.8 96 98 75-125 1 20 Thallium ug/L ND 100 100 95.1 94.9 95 95 75-125 0 20 Vanadium ug/L ND 100 100 104 102 104 102 75-125 1 20 Zinc ug/L 5.9J 100 100 104 103 98 97 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37965 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2624501036, 2624501037, 2624501039, 2624501040 METHOD BLANK: 172520 Matrix: Water Associated Lab Samples: 2624501036, 2624501037, 2624501039, 2624501040 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.27 11/01/1918:57 Arsenic ug/L 0.67J 10.0 0.35 11/01/1918:57 Barium ug/L ND 100 0.49 11/01/1918:57 Beryllium ug/L ND 1.0 0.074 11/01/1918:57 Cadmium ug/L ND 1.0 0.11 11/01/1918:57 Chromium ug/L ND 10.0 0.39 11/01/1918:57 Cobalt ug/L ND 10.0 0.30 11/01/1918:57 Copper ug/L ND 10.0 0.19 11/01/1918:57 Lead ug/L ND 10.0 0.046 11/01/1918:57 Nickel ug/L ND 50.0 0.31 11/01/1918:57 Selenium ug/L ND 10.0 1.3 11/01/1918:57 Silver ug/L ND 10.0 0.28 11/01/1918:57 Thallium ug/L ND 5.5 0.052 11/01/1918:57 Vanadium ug/L ND 25.0 0.71 11/01/1918:57 Zinc ug/L 4.9J 10.0 1.5 11/01/1918:57 LABORATORY CONTROL SAMPLE: 172521 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 110 110 80-120 Arsenic ug/L 100 100 100 80-120 Barium ug/L 100 107 107 80-120 Beryllium ug/L 100 109 109 80-120 Cadmium ug/L 100 102 102 80-120 Chromium ug/L 100 106 106 80-120 Cobalt ug/L 100 102 102 80-120 Copper ug/L 100 106 106 80-120 Lead ug/L 100 103 103 80-120 Nickel ug/L 100 104 104 80-120 Selenium ug/L 100 97.6 98 80-120 Silver ug/L 100 105 105 80-120 Thallium ug/L 100 103 103 80-120 Vanadium ug/L 100 106 106 80-120 Zinc ug/L 100 109 109 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: CMS V Landfill -Revised Report 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 172522 172523 MS MSD 2624501039 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L 0.33J 100 100 108 104 108 104 75-125 4 20 Arsenic ug/L 1.7J 100 100 101 102 99 100 75-125 1 20 Barium ug/L 44.5J 100 100 152 147 108 103 75-125 3 20 Beryllium ug/L 0.084J 100 100 109 109 109 109 75-125 0 20 Cadmium ug/L ND 100 100 101 98.9 101 99 75-125 2 20 Chromium ug/L 2.OJ 100 100 103 102 102 100 75-125 1 20 Cobalt ug/L 1.7J 100 100 100 98.1 98 96 75-125 2 20 Copper ug/L 6.7J 100 100 108 107 101 101 75-125 1 20 Lead ug/L 1.01 100 100 104 102 103 101 75-125 2 20 Nickel ug/L 1.6J 100 100 102 99.4 101 98 75-125 3 20 Selenium ug/L ND 100 100 95.7 97.7 95 97 75-125 2 20 Silver ug/L ND 100 100 103 100 103 100 75-125 3 20 Thallium ug/L ND 100 100 103 102 103 102 75-125 1 20 Vanadium ug/L 12.2J 100 100 114 115 102 103 75-125 1 20 Zinc ug/L 121 100 100 219 220 99 99 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37605 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2624501003, 2624501004, 2624501007, 2624501008, 2624501013, 2624501014, 2624501015, 2624501016, 2624501017, 2624501018, 2624501019, 2624501022, 2624501023, 2624501024, 2624501028, 2624501029, 2624501031,2624501038 METHOD BLANK: 170783 Matrix: Water Associated Lab Samples: 2624501003, 2624501004, 2624501007, 2624501008, 2624501013, 2624501014, 2624501015, 2624501016, 2624501017, 2624501018, 2624501019, 2624501022, 2624501023, 2624501024, 2624501028, 2624501029, 2624501031,2624501038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 10/26/19 13:08 1,1,1-Trichloroethane ug/L ND 1.0 0.38 10/26/19 13:08 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 10/26/19 13:08 1,1,2-Trichloroethane ug/L ND 1.0 0.59 10/26/19 13:08 1,1-Dichloroethane ug/L ND 5.0 0.41 10/26/19 13:08 1,1-Dichloroethene ug/L ND 5.0 0.72 10/26/19 13:08 1,2,3-Trichloropropane ug/L ND 1.0 0.46 10/26/19 13:08 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 10/26/19 13:08 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 10/26/19 13:08 1,2-Dichlorobenzene ug/L ND 5.0 0.49 10/26/19 13:08 1,2-Dichloroethane ug/L ND 1.0 0.67 10/26/19 13:08 1,2-Dichloropropane ug/L ND 1.0 0.60 10/26/19 13:08 1,4-Dichlorobenzene ug/L ND 1.0 0.58 10/26/19 13:08 2-Butanone (MEK) ug/L ND 100 3.2 10/26/19 13:08 2-Hexanone ug/L ND 50.0 0.89 10/26/19 13:08 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 10/26/19 13:08 Acetone ug/L ND 100 8.2 10/26/19 13:08 Acrylonitrile ug/L ND 200 2.5 10/26/19 13:08 Benzene ug/L ND 1.0 0.20 10/26/19 13:08 Bromochloromethane ug/L ND 3.0 0.50 10/26/19 13:08 Bromodichloromethane ug/L ND 1.0 0.36 10/26/19 13:08 Bromoform ug/L ND 3.0 0.55 10/26/19 13:08 Bromomethane ug/L ND 10.0 0.95 10/26/19 13:08 Carbon disulfide ug/L ND 100 0.79 10/26/19 13:08 Carbon tetrachloride ug/L ND 1.0 0.42 10/26/19 13:08 Chlorobenzene ug/L ND 3.0 0.53 10/26/19 13:08 Chloroethane ug/L ND 10.0 0.52 10/26/19 13:08 Chloroform ug/L ND 5.0 0.58 10/26/19 13:08 Chloromethane ug/L ND 1.0 0.38 10/26/19 13:08 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 10/26/19 13:08 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 10/26/19 13:08 Dibromochloromethane ug/L ND 3.0 0.31 10/26/19 13:08 Dibromomethane ug/L ND 10.0 0.62 10/26/19 13:08 Ethylbenzene ug/L ND 1.0 0.45 10/26/19 13:08 lodomethane ug/L ND 10.0 3.1 10/26/19 13:08 Methylene Chloride ug/L ND 1.0 0.50 10/26/19 13:08 Styrene ug/L ND 1.0 0.50 10/26/19 13:08 Tetrachloroethene ug/L ND 1.0 0.78 10/26/19 13:08 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 METHOD BLANK: 170783 Matrix: Water Associated Lab Samples: 2624501003, 2624501004, 2624501007, 2624501008, 2624501013, 2624501014, 2624501015, 2624501016, 2624501017, 2624501018, 2624501019, 2624501022, 2624501023, 2624501024, 2624501028, 2624501029, 2624501031.2624501038 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Toluene ug/L ND 1.0 0.31 10/26/19 13:08 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 10/26/19 13:08 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 10/26/19 13:08 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 10/26/19 13:08 Trichloroethene ug/L ND 1.0 0.34 10/26/19 13:08 Trichlorofluoromethane ug/L ND 1.0 0.51 10/26/19 13:08 Vinyl acetate ug/L ND 50.0 0.42 10/26/19 13:08 Vinyl chloride ug/L ND 1.0 0.60 10/26/19 13:08 Xylene (Total) ug/L ND 5.0 1.5 10/26/19 13:08 1,2-Dichloroethane-d4 (S) %. 108 81-119 10/26/19 13:08 4-Bromofluorobenzene (S) %. 107 82-120 10/26/19 13:08 Dibromofluoromethane (S) %. 104 82-114 10/26/19 13:08 Toluene-d8 (S) %. 107 82-109 10/26/19 13:08 LABORATORY CONTROL SAMPLE: 170784 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.7 103 68-137 1,1,1-Trichloroethane ug/L 50 51.0 102 72-134 1,1,2,2-Tetrachloroethane ug/L 50 55.3 111 51-158 1,1,2-Trichloroethane ug/L 50 58.7 117 78-131 1,1-Dichloroethane ug/L 50 57.9 116 69-151 1,1-Dichloroethene ug/L 50 61.5 123 64-158 1,2,3-Trichloropropane ug/L 50 51.5 103 78-133 1,2-Dibromo-3-chloropropane ug/L 50 50.2 100 58-124 1,2-Dibromoethane (EDB) ug/L 50 53.8 108 71-134 1,2-Dichlorobenzene ug/L 50 57.7 115 70-135 1,2-Dichloroethane ug/L 50 52.9 106 72-129 1,2-Dichloropropane ug/L 50 58.9 118 64-135 1,4-Dichlorobenzene ug/L 50 57.3 115 70-131 2-Butanone (MEK) ug/L 100 102 102 52-143 2-Hexanone ug/L 100 84.7 85 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 99.11 99 71-129 Acetone ug/L 100 84.7J 85 48-224 Acrylonitrile ug/L 200 222 111 66-154 Benzene ug/L 50 53.9 108 68-132 Bromochloromethane ug/L 50 53.3 107 73-133 Bromodichloromethane ug/L 50 50.6 101 67-121 Bromoform ug/L 50 51.8 104 57-125 Bromomethane ug/L 50 62.7 125 35-156 Carbon disulfide ug/L 100 103 103 47-141 Carbon tetrachloride ug/L 50 52.3 105 66-122 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 LABORATORY CONTROL SAMPLE: Parameter 170784 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Chlorobenzene ug/L 50 53.2 106 71-126 Chloroethane ug/L 50 47.3 95 43-143 Chloroform ug/L 50 56.2 112 71-136 Chloromethane ug/L 50 49.4 99 47-123 cis-1,2-Dichloroethene ug/L 50 56.8 114 74-131 cis-1,3-Dichloropropene ug/L 50 54.1 108 78-120 Dibromochloromethane ug/L 50 51.3 103 65-115 Dibromomethane ug/L 50 55.2 110 79-129 Ethylbenzene ug/L 50 55.2 110 68-129 lodomethane ug/L 100 90.2 90 49-154 Methylene Chloride ug/L 50 53.5 107 61-147 Styrene ug/L 50 60.7 121 77-128 Tetrachloroethene ug/L 50 46.9 94 51-139 Toluene ug/L 50 55.4 111 60-133 trans-1,2-Dichloroethene ug/L 50 59.4 119 69-144 trans- 1,3-Dichloropropene ug/L 50 52.7 105 74-128 trans-1,4-Dichloro-2-butene ug/L 100 97.2J 97 61-139 Trichloroethene ug/L 50 46.6 93 73-126 Trichlorofluoromethane ug/L 50 50.0 100 55-132 Vinyl acetate ug/L 50 53.6 107 52-141 Vinyl chloride ug/L 50 46.1 92 50-133 Xylene (Total) ug/L 150 171 114 78-132 1,2-Dichloroethane-d4 (S) %. 106 81-119 4-Bromofluorobenzene (S) %. 109 82-120 Dibromofluoromethane (S) %. 109 82-114 Toluene-d8 (S) %. 108 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 170785 MS 2624501003 Spike Parameter Units Result Conc. MSD Spike Conc. 170786 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 54.8 59.2 110 118 68-137 8 11 1,1,1-Trichloroethane ug/L ND 50 50 62.7 69.4 125 139 66-142 10 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 57.5 58.4 115 117 39-171 2 13 1,1,2-Trichloroethane ug/L ND 50 50 59.6 63.7 119 127 73-136 7 12 1,1-Dichloroethane ug/L ND 50 50 63.2 66.6 126 133 66-155 5 15 1,1-Dichloroethene ug/L ND 50 50 71.0 78.2 142 156 33-181 10 34 1,2,3-Trichloropropane ug/L ND 50 50 49.1 51.5 98 103 78-133 5 14 1,2-Dibromo-3- ug/L ND 50 50 50.8 53.5 102 107 58-124 5 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 57.1 58.2 114 116 71-134 2 12 1,2-Dichlorobenzene ug/L ND 50 50 58.0 60.2 116 120 69-135 4 10 1,2-Dichloroethane ug/L ND 50 50 56.0 62.9 112 126 36-159 12 10 R1 1,2-Dichloropropane ug/L ND 50 50 61.4 64.5 123 129 68-132 5 11 1,4-Dichlorobenzene ug/L ND 50 50 56.8 59.8 114 120 49-153 5 9 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 170785 170786 Parameter Units 2-Butanone (MEK) ug/L 2-Hexanone ug/L 4-Methyl-2-pentanone ug/L (MIBK) Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L Methylene Chloride ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L trans-1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. MS MSD 2624501003 Spike Spike MS MSD Result Conc. Conc. Result Result ND 100 100 114 117 ND 100 100 94.4 94.6 ND 100 100 104 106 ND 100 100 80.1J 88.9J ND 200 200 214 229 ND 50 50 58.9 63.5 ND 50 50 53.7 59.4 ND 50 50 54.6 57.6 ND 50 50 48.8 54.0 ND 50 50 57.4 63.9 ND 100 100 103 113 ND 50 50 65.5 71.2 ND 50 50 57.4 59.9 ND 50 50 51.0 59.0 ND 50 50 62.1 66.5 ND 50 50 53.7 60.2 ND 50 50 60.6 64.4 ND 50 50 54.4 56.7 ND 50 50 51.5 55.7 ND 50 50 58.0 60.2 ND 50 50 59.8 63.5 ND 100 100 80.1 110 ND 50 50 50.3 56.3 ND 50 50 62.8 66.7 ND 50 50 53.8 55.5 ND 50 50 61.7 63.7 ND 50 50 59.3 63.6 ND 50 50 51.4 54.1 ND 100 100 89.7J 92.6J ND 50 50 50.6 54.2 ND 50 50 69.4 79.2 ND 50 50 45.9J 49.8J ND 50 50 51.8 60.5 ND 150 150 183 194 MS % Rec 114 94 104 80 107 118 107 109 98 115 103 131 115 102 124 107 121 109 103 116 120 80 101 126 108 123 119 103 90 101 139 92 104 122 108 112 109 108 MSD % Rec % Rec Limits 117 10-189 95 40-135 106 30-177 89 44-223 114 13-189 127 66-139 119 73-133 115 57-120 108 48-128 128 10-187 113 47-141 142 58-127 120 63-137 118 52-146 133 74-137 120 41-127 129 71-138 113 32-145 111 52-116 120 79-129 127 31-174 110 49-154 113 61-146 133 77-128 111 36-155 127 52-146 127 61-152 108 37-146 93 61-139 108 61-141 158 51-141 100 52-141 121 22-156 130 78-132 112 81-119 110 82-120 114 82-114 107 82-109 Max RPD RPD Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. 3 23 0 18 2 10 10 14 7 12 8 10 10 13 5 13 10 13 11 32 10 322 8 14 M1 4 10 15 16 7 9 11 10 R1 6 16 4 12 8 13 4 14 6 10 31 30 R1 11 15 6 14 M1 3 14 3 11 7 14 5 12 3 12 7 12 13 13 M1 8 14 15 26 6 7 Page 98 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37608 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2624501032, 2624501033, 2624501034, 2624501035, 2624501037 METHOD BLANK: 170792 Matrix: Water Associated Lab Samples: 2624501032, 2624501033, 2624501034, 2624501035, 2624501037 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 10/26/19 17:38 1,1,1-Trichloroethane ug/L ND 1.0 0.38 10/26/19 17:38 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 10/26/19 17:38 1,1,2-Trichloroethane ug/L ND 1.0 0.59 10/26/19 17:38 1,1-Dichloroethane ug/L ND 5.0 0.41 10/26/19 17:38 1,1-Dichloroethene ug/L ND 5.0 0.72 10/26/19 17:38 1,2,3-Trichloropropane ug/L ND 1.0 0.46 10/26/19 17:38 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 10/26/19 17:38 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 10/26/19 17:38 1,2-Dichlorobenzene ug/L ND 5.0 0.49 10/26/19 17:38 1,2-Dichloroethane ug/L ND 1.0 0.67 10/26/19 17:38 1,2-Dichloropropane ug/L ND 1.0 0.60 10/26/19 17:38 1,4-Dichlorobenzene ug/L ND 1.0 0.58 10/26/19 17:38 2-Butanone (MEK) ug/L ND 100 3.2 10/26/19 17:38 2-Hexanone ug/L ND 50.0 0.89 10/26/19 17:38 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 10/26/19 17:38 Acetone ug/L ND 100 8.2 10/26/19 17:38 Acrylonitrile ug/L ND 200 2.5 10/26/19 17:38 Benzene ug/L ND 1.0 0.20 10/26/19 17:38 Bromochloromethane ug/L ND 3.0 0.50 10/26/19 17:38 Bromodichloromethane ug/L ND 1.0 0.36 10/26/19 17:38 Bromoform ug/L ND 3.0 0.55 10/26/19 17:38 Bromomethane ug/L ND 10.0 0.95 10/26/19 17:38 Carbon disulfide ug/L ND 100 0.79 10/26/19 17:38 Carbon tetrachloride ug/L ND 1.0 0.42 10/26/19 17:38 Chlorobenzene ug/L ND 3.0 0.53 10/26/19 17:38 Chloroethane ug/L ND 10.0 0.52 10/26/19 17:38 Chloroform ug/L ND 5.0 0.58 10/26/19 17:38 Chloromethane ug/L ND 1.0 0.38 10/26/19 17:38 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 10/26/19 17:38 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 10/26/19 17:38 Dibromochloromethane ug/L ND 3.0 0.31 10/26/19 17:38 Dibromomethane ug/L ND 10.0 0.62 10/26/19 17:38 Ethylbenzene ug/L ND 1.0 0.45 10/26/19 17:38 lodomethane ug/L ND 10.0 3.1 10/26/19 17:38 Methylene Chloride ug/L ND 1.0 0.50 10/26/19 17:38 Styrene ug/L ND 1.0 0.50 10/26/19 17:38 Tetrachloroethene ug/L ND 1.0 0.78 10/26/19 17:38 Toluene ug/L ND 1.0 0.31 10/26/19 17:38 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 10/26/19 17:38 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 10/26/19 17:38 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 METHOD BLANK: 170792 Associated Lab Samples: Parameter Matrix: Water 2624501032, 2624501033, 2624501034, 2624501035, 2624501037 Blank Reporting Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 10/26/19 17:38 Trichloroethene ug/L ND 1.0 0.34 10/26/19 17:38 Trichlorofluoromethane ug/L ND 1.0 0.51 10/26/19 17:38 Vinyl acetate ug/L ND 50.0 0.42 10/26/19 17:38 Vinyl chloride ug/L ND 1.0 0.60 10/26/19 17:38 Xylene (Total) ug/L ND 5.0 1.5 10/26/19 17:38 1,2-Dichloroethane-d4 (S) %. 103 81-119 10/26/19 17:38 4-Bromofluorobenzene (S) %. 98 82-120 10/26/19 17:38 Dibromofluoromethane (S) %. 96 82-114 10/26/19 17:38 Toluene-d8 (S) %. 100 82-109 10/26/19 17:38 LABORATORY CONTROL SAMPLE: Parameter 170793 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 47.4 95 68-137 1,1,1-Trichloroethane ug/L 50 50.1 100 72-134 1,1,2,2-Tetrachloroethane ug/L 50 48.3 97 51-158 1,1,2-Trichloroethane ug/L 50 51.6 103 78-131 1,1-Dichloroethane ug/L 50 48.9 98 69-151 1,1-Dichloroethene ug/L 50 49.7 99 64-158 1,2,3-Trichloropropane ug/L 50 48.5 97 78-133 1,2-Dibromo-3-chloropropane ug/L 50 42.6 85 58-124 1,2-Dibromoethane (EDB) ug/L 50 55.2 110 71-134 1,2-Dichlorobenzene ug/L 50 52.6 105 70-135 1,2-Dichloroethane ug/L 50 49.8 100 72-129 1,2-Dichloropropane ug/L 50 50.8 102 64-135 1,4-Dichlorobenzene ug/L 50 48.9 98 70-131 2-Butanone (MEK) ug/L 100 126 126 52-143 2-Hexanone ug/L 100 117 117 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 107 107 71-129 Acetone ug/L 100 124 124 48-224 Acrylonitrile ug/L 200 179J 89 66-154 Benzene ug/L 50 49.7 99 68-132 Bromochloromethane ug/L 50 54.3 109 73-133 Bromodichloromethane ug/L 50 46.1 92 67-121 Bromoform ug/L 50 39.9 80 57-125 Bromomethane ug/L 50 51.8 104 35-156 Carbon disulfide ug/L 100 92.9J 93 47-141 Carbon tetrachloride ug/L 50 51.4 103 66-122 Chlorobenzene ug/L 50 49.5 99 71-126 Chloroethane ug/L 50 49.3 99 43-143 Chloroform ug/L 50 50.0 100 71-136 Chloromethane ug/L 50 44.5 89 47-123 cis-1,2-Dichloroethene ug/L 50 49.4 99 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 LABORATORY CONTROL SAMPLE: Parameter 170793 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 47.1 94 78-120 Dibromochloromethane ug/L 50 44.0 88 65-115 Dibromomethane ug/L 50 52.5 105 79-129 Ethylbenzene ug/L 50 49.5 99 68-129 lodomethane ug/L 100 105 105 49-154 Methylene Chloride ug/L 50 50.2 100 61-147 Styrene ug/L 50 52.5 105 77-128 Tetrachloroethene ug/L 50 52.0 104 51-139 Toluene ug/L 50 50.2 100 60-133 trans-1,2-Dichloroethene ug/L 50 49.6 99 69-144 trans- 1,3-Dichloropropene ug/L 50 44.9 90 74-128 trans-1,4-Dichloro-2-butene ug/L 100 88.2J 88 61-139 Trichloroethene ug/L 50 50.3 101 73-126 Trichlorofluoromethane ug/L 50 50.2 100 55-132 Vinyl acetate ug/L 50 48AJ 97 52-141 Vinyl chloride ug/L 50 46.4 93 50-133 Xylene (Total) ug/L 150 151 101 78-132 1,2-Dichloroethane-d4 (S) %. 103 81-119 4-Bromofluorobenzene (S) %. 98 82-120 Dibromofluoromethane (S) %. 106 82-114 Toluene-d8 (S) %. 101 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 170794 MS 2624501032 Spike Parameter Units Result Conc. MSD Spike Conc. 170795 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 51.1 52.2 102 104 68-137 2 11 1,1,1-Trichloroethane ug/L ND 50 50 56.2 56.6 112 113 66-142 1 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 56.3 57.0 113 114 39-171 1 13 1,1,2-Trichloroethane ug/L ND 50 50 58.2 58.9 116 118 73-136 1 12 1,1-Dichloroethane ug/L ND 50 50 56.3 57.5 112 115 66-155 2 15 1,1-Dichloroethene ug/L ND 50 50 60.4 59.0 121 118 33-181 2 34 1,2,3-Trichloropropane ug/L ND 50 50 52.3 55.8 105 112 78-133 7 14 1,2-Dibromo-3- ug/L ND 50 50 49.0 51.7 98 103 58-124 5 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 61.1 63.2 122 126 71-134 3 12 1,2-Dichlorobenzene ug/L ND 50 50 57.9 60.9 115 121 69-135 5 10 1,2-Dichloroethane ug/L ND 50 50 56.4 55.9 113 112 36-159 1 10 1,2-Dichloropropane ug/L ND 50 50 56.5 57.5 113 115 68-132 2 11 1,4-Dichlorobenzene ug/L ND 50 50 54.5 56.4 108 112 49-153 4 9 2-Butanone (MEK) ug/L 19.7J 100 100 135 135 115 115 10-189 0 23 2-Hexanone ug/L ND 100 100 113 115 113 115 40-135 2 18 4-Methyl-2-pentanone ug/L ND 100 100 115 116 115 116 30-177 1 10 (MIBK) Acetone ug/L ND 100 100 82.OJ 82.5J 81 82 44-223 1 14 Acrylonitrile ug/L ND 200 200 208 222 104 111 13-189 7 12 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 170794 MS 2624501032 Spike Parameter Units Result Conc. MSD Spike Conc. 170795 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L 6.7 50 50 60.8 61.5 108 110 66-139 1 10 Bromochloromethane ug/L ND 50 50 58.6 56.2 117 112 73-133 4 13 Bromodichloromethane ug/L ND 50 50 49.6 50.8 99 102 57-120 2 13 Bromoform ug/L ND 50 50 43.9 44.8 88 90 48-128 2 13 Bromomethane ug/L ND 50 50 51.2 53.8 102 108 10-187 5 32 Carbon disulfide ug/L 1 AJ 100 100 102 106 101 104 47-141 3 322 Carbon tetrachloride ug/L ND 50 50 58.1 58.3 116 117 58-127 0 14 Chlorobenzene ug/L ND 50 50 53.2 54.2 106 108 63-137 2 10 Chloroethane ug/L ND 50 50 53.4 54.0 106 107 52-146 1 16 Chloroform ug/L ND 50 50 54.9 55.0 110 110 74-137 0 9 Chloromethane ug/L ND 50 50 54.0 54.5 108 109 41-127 1 10 cis-1,2-Dichloroethene ug/L 4.OJ 50 50 58.5 59.6 109 111 71-138 2 16 cis-1,3-Dichloropropene ug/L ND 50 50 52.3 53.2 105 106 32-145 2 12 Dibromochloromethane ug/L ND 50 50 47.5 48.5 95 97 52-116 2 13 Dibromomethane ug/L ND 50 50 61.2 61.4 122 123 79-129 0 14 Ethylbenzene ug/L ND 50 50 54.2 55.2 108 110 31-174 2 10 lodomethane ug/L ND 100 100 118 122 118 122 49-154 3 30 Methylene Chloride ug/L ND 50 50 57.0 58.0 114 116 61-146 2 15 Styrene ug/L ND 50 50 58.6 57.5 117 115 77-128 2 14 Tetrachloroethene ug/L ND 50 50 55.7 55.2 111 110 36-155 1 14 Toluene ug/L ND 50 50 55.3 55.3 110 110 52-146 0 11 trans-1,2-Dichloroethene ug/L ND 50 50 56.8 58.1 113 115 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 48.7 49.8 97 100 37-146 2 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 91.2J 92.8J 91 93 61-139 2 12 Trichloroethene ug/L 0.61J 50 50 50.4 51.7 100 102 61-141 3 12 Trichlorofluoromethane ug/L ND 50 50 57.9 58.4 116 117 51-141 1 13 Vinyl acetate ug/L ND 50 50 55.7 55.2 111 110 52-141 1 14 Vinyl chloride ug/L 2.1 50 50 51.1 52.7 98 101 22-156 3 26 Xylene (Total) ug/L ND 150 150 168 170 112 114 78-132 1 7 1,2-Dichloroethane-d4 (S) %. 104 102 81-119 4-Bromofluorobenzene (S) %. 98 98 82-120 Dibromofluoromethane (S) %. 105 104 82-114 Toluene-d8 (S) %. 100 101 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37803 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2624501005, 2624501006, 2624501009, 2624501010, 2624501011, 2624501012, 2624501020, 2624501026, 2624501030 METHOD BLANK: 171584 Matrix: Water Associated Lab Samples: 2624501005, 2624501006, 2624501009, 2624501010, 2624501011, 2624501012, 2624501020, 2624501026, 2624501030 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 10/30/19 09:36 1,1,1-Trichloroethane ug/L ND 1.0 0.38 10/30/19 09:36 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 10/30/19 09:36 1,1,2-Trichloroethane ug/L ND 1.0 0.59 10/30/19 09:36 1,1-Dichloroethane ug/L ND 5.0 0.41 10/30/19 09:36 1,1-Dichloroethene ug/L ND 5.0 0.72 10/30/19 09:36 1,2,3-Trichloropropane ug/L ND 1.0 0.46 10/30/19 09:36 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 10/30/19 09:36 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 10/30/19 09:36 1,2-Dichlorobenzene ug/L ND 5.0 0.49 10/30/19 09:36 1,2-Dichloroethane ug/L ND 1.0 0.67 10/30/19 09:36 1,2-Dichloropropane ug/L ND 1.0 0.60 10/30/19 09:36 1,4-Dichlorobenzene ug/L ND 1.0 0.58 10/30/19 09:36 2-Butanone (MEK) ug/L ND 100 3.2 10/30/19 09:36 2-Hexanone ug/L ND 50.0 0.89 10/30/19 09:36 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 10/30/19 09:36 Acetone ug/L ND 100 8.2 10/30/19 09:36 Acrylonitrile ug/L ND 200 2.5 10/30/19 09:36 Benzene ug/L ND 1.0 0.20 10/30/19 09:36 Bromochloromethane ug/L ND 3.0 0.50 10/30/19 09:36 Bromodichloromethane ug/L ND 1.0 0.36 10/30/19 09:36 Bromoform ug/L ND 3.0 0.55 10/30/19 09:36 Bromomethane ug/L ND 10.0 0.95 10/30/19 09:36 Carbon disulfide ug/L ND 100 0.79 10/30/19 09:36 Carbon tetrachloride ug/L ND 1.0 0.42 10/30/19 09:36 Chlorobenzene ug/L ND 3.0 0.53 10/30/19 09:36 Chloroethane ug/L ND 10.0 0.52 10/30/19 09:36 Chloroform ug/L ND 5.0 0.58 10/30/19 09:36 Chloromethane ug/L ND 1.0 0.38 10/30/19 09:36 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 10/30/19 09:36 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 10/30/19 09:36 Dibromochloromethane ug/L ND 3.0 0.31 10/30/19 09:36 Dibromomethane ug/L ND 10.0 0.62 10/30/19 09:36 Ethylbenzene ug/L ND 1.0 0.45 10/30/19 09:36 lodomethane ug/L 3.2J 10.0 3.1 10/30/19 09:36 Methylene Chloride ug/L ND 1.0 0.50 10/30/19 09:36 Styrene ug/L ND 1.0 0.50 10/30/19 09:36 Tetrachloroethene ug/L ND 1.0 0.78 10/30/19 09:36 Toluene ug/L ND 1.0 0.31 10/30/19 09:36 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 10/30/19 09:36 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 METHOD BLANK: 171584 Matrix: Water Associated Lab Samples: 2624501005, 2624501006, 2624501009, 2624501010, 2624501011, 2624501012, 2624501020, 2624501026, 2624501030 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 10/30/19 09:36 trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 10/30/19 09:36 Trichloroethene ug/L ND 1.0 0.34 10/30/19 09:36 Trichlorofluoromethane ug/L ND 1.0 0.51 10/30/19 09:36 Vinyl acetate ug/L ND 50.0 0.42 10/30/19 09:36 Vinyl chloride ug/L ND 1.0 0.60 10/30/19 09:36 Xylene (Total) ug/L ND 5.0 1.5 10/30/19 09:36 1,2-Dichloroethane-d4 (S) %. 104 81-119 10/30/19 09:36 4-Bromofluorobenzene (S) %. 105 82-120 10/30/19 09:36 Dibromofluoromethane (S) %. 105 82-114 10/30/19 09:36 Toluene-d8 (S) %. 106 82-109 10/30/19 09:36 LABORATORY CONTROL SAMPLE: 171585 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 500 45.7 9 68-137 1,1,1-Trichloroethane ug/L 500 47.1 9 72-134 1,1,2,2-Tetrachloroethane ug/L 500 52.7 11 51-158 1,1,2-Trichloroethane ug/L 500 50.4 10 78-131 1,1-Dichloroethane ug/L 500 50.8 10 69-151 1,1-Dichloroethene ug/L 500 52.4 10 64-158 1,2,3-Trichloropropane ug/L 500 45.8 9 78-133 1,2-Dibromo-3-chloropropane ug/L 500 43.0 9 58-124 1,2-Dibromoethane (EDB) ug/L 500 48.0 10 71-134 1,2-Dichlorobenzene ug/L 500 50.6 10 70-135 1,2-Dichloroethane ug/L 500 45.8 9 72-129 1,2-Dichloropropane ug/L 500 51.6 10 64-135 1,4-Dichlorobenzene ug/L 500 50.2 10 70-131 2-Butanone (MEK) ug/L 1000 87.8J 9 52-143 2-Hexanone ug/L 1000 77.6 8 61-136 4-Methyl-2-pentanone (MIBK) ug/L 1000 90.3J 9 71-129 Acetone ug/L 1000 89.6J 9 48-224 Acrylonitrile ug/L 2000 204 10 66-154 Benzene ug/L 500 47.5 9 68-132 Bromochloromethane ug/L 500 48.5 10 73-133 Bromodichloromethane ug/L 500 46.6 9 67-121 Bromoform ug/L 500 44.1 9 57-125 Bromomethane ug/L 500 40.0 8 35-156 Carbon disulfide ug/L 1000 103 10 47-141 Carbon tetrachloride ug/L 500 47.3 9 66-122 Chlorobenzene ug/L 500 47.2 9 71-126 Chloroethane ug/L 500 51.1 10 43-143 Chloroform ug/L 500 47.4 9 71-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 LABORATORY CONTROL SAMPLE: 171585 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloromethane ug/L 500 49.2 10 47-123 cis-1,2-Dichloroethene ug/L 500 49.9 10 74-131 cis-1,3-Dichloropropene ug/L 500 48.1 10 78-120 Dibromochloromethane ug/L 500 45.5 9 65-115 Dibromomethane ug/L 500 49.5 10 79-129 Ethylbenzene ug/L 500 47.8 10 68-129 lodomethane ug/L 1000 99.0 10 49-154 Methylene Chloride ug/L 500 46.4 9 61-147 Styrene ug/L 500 53.2 11 77-128 Tetrachloroethene ug/L 500 47.3 9 51-139 Toluene ug/L 500 48.5 10 60-133 trans-1,2-Dichloroethene ug/L 500 52.1 10 69-144 trans- 1,3-Dichloropropene ug/L 500 46.6 9 74-128 trans-1,4-Dichloro-2-butene ug/L 1000 91.2J 9 61-139 Trichloroethene ug/L 500 44.2 9 73-126 Trichlorofluoromethane ug/L 500 49.9 10 55-132 Vinyl acetate ug/L 500 51.5 10 52-141 Vinyl chloride ug/L 500 46.8 9 50-133 Xylene (Total) ug/L 1500 150 10 78-132 1,2-Dichloroethane-d4 (S) %. 101 81-119 4-Bromofluorobenzene (S) %. 112 82-120 Dibromofluoromethane (S) %. 108 82-114 Toluene-d8 (S) %. 107 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 171586 171587 MS MSD 2624501005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 500 500 49.2 43.8 10 9 68-137 12 11 R1 1,1,1-Trichloroethane ug/L ND 500 500 55.0 50.3 11 10 66-142 9 11 1,1,2,2-Tetrachloroethane ug/L ND 500 500 59.7 50.6 12 10 39-171 16 13 R1 1,1,2-Trichloroethane ug/L ND 500 500 56.0 47.8 11 10 73-136 16 12 R1 1,1-Dichloroethane ug/L ND 500 500 56.5 50.6 11 10 66-155 11 15 1,1-Dichloroethene ug/L ND 500 500 65.9 59.2 13 12 33-181 11 34 1,2,3-Trichloropropane ug/L ND 500 500 49.2 41.1 10 8 78-133 18 14 R1 1,2-Dibromo-3- ug/L ND 500 500 47.5 41.1 10 8 58-124 15 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 500 500 52.7 46.0 11 9 71-134 14 12 R1 1,2-Dichlorobenzene ug/L ND 500 500 53.3 46.4 11 9 69-135 14 10 R1 1,2-Dichloroethane ug/L ND 500 500 50.5 44.7 10 9 36-159 12 10 R1 1,2-Dichloropropane ug/L ND 500 500 55.5 47.9 11 10 68-132 15 11 R1 1,4-Dichlorobenzene ug/L ND 500 500 53.2 46.7 11 9 49-153 13 9 R1 2-Butanone (MEK) ug/L ND 1000 1000 119 101 12 10 10-189 16 23 2-Hexanone ug/L ND 1000 1000 92.8 78.1 9 8 40-135 17 18 4-Methyl-2-pentanone ug/L ND 1000 1000 106 88.3J 11 9 30-177 18 10 R1 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 171586 171587 MS MSD 2624501005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 1000 1000 90AJ 76.2J 9 8 44-223 17 14 R1 Acrylonitrile ug/L ND 2000 2000 230 198J 12 10 13-189 15 12 R1 Benzene ug/L ND 500 500 53.8 47.2 11 9 66-139 13 10 R1 Bromochloromethane ug/L ND 500 500 53.0 45.1 11 9 73-133 16 13 R1 Bromodichloromethane ug/L ND 500 500 49.0 42.6 10 9 57-120 14 13 R1 Bromoform ug/L ND 500 500 44.8 38.0 9 8 48-128 17 13 R1 Bromomethane ug/L ND 500 500 38.6 36.3 8 7 10-187 6 32 Carbon disulfide ug/L ND 1000 1000 115 102 11 10 47-141 12 322 Carbon tetrachloride ug/L ND 500 500 58.8 52.7 12 11 58-127 11 14 Chlorobenzene ug/L ND 500 500 51.9 45.0 10 9 63-137 14 10 R1 Chloroethane ug/L ND 500 500 56.3 52.0 11 10 52-146 8 16 Chloroform ug/L ND 500 500 53.2 46.5 11 9 74-137 13 9 R1 Chloromethane ug/L ND 500 500 59.0 50.7 12 10 41-127 15 10 R1 cis-1,2-Dichloroethene ug/L ND 500 500 55.9 49.4 11 10 71-138 12 16 cis-1,3-Dichloropropene ug/L ND 500 500 50.7 43.5 10 9 32-145 15 12 R1 Dibromochloromethane ug/L ND 500 500 47.3 40.7 9 8 52-116 15 13 R1 Dibromomethane ug/L ND 500 500 54.2 44.9 11 9 79-129 19 14 R1 Ethylbenzene ug/L ND 500 500 54.3 47.5 11 10 31-174 13 10 R1 lodomethane ug/L ND 1000 1000 92.4 105 9 10 49-154 12 30 Methylene Chloride ug/L ND 500 500 50.1 45.0 10 9 61-146 11 15 Styrene ug/L ND 500 500 58.4 50.7 12 10 77-128 14 14 Tetrachloroethene ug/L ND 500 500 57.9 47.5 12 10 36-155 20 14 R1 Toluene ug/L ND 500 500 54.9 46.5 11 9 52-146 16 11 R1 trans-1,2-Dichloroethene ug/L ND 500 500 58.7 51.6 12 10 61-152 13 14 trans-1,3-Dichloropropene ug/L ND 500 500 47.2 41.3 9 8 37-146 13 12 R1 trans-1,4-Dichloro-2-butene ug/L ND 1000 1000 91AJ 75AJ 9 8 61-139 19 12 R1 Trichloroethene ug/L ND 500 500 50.4 44.6 10 9 61-141 12 12 Trichlorofluoromethane ug/L ND 500 500 71.6 65.0 14 13 51-141 10 13 M1 Vinyl acetate ug/L ND 500 500 52.9 48.3J 11 10 52-141 9 14 Vinyl chloride ug/L ND 500 500 59.2 51.5 12 10 22-156 14 26 Xylene (Total) ug/L ND 1500 1500 167 146 11 10 78-132 13 7 RS 1,2-Dichloroethane-d4 (S) %. 105 106 81-119 4-Bromofluorobenzene (S) %. 110 110 82-120 Dibromofluoromethane (S) %. 108 108 82-114 Toluene-d8 (S) %. 107 106 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 QC Batch: 37951 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2624501001, 2624501002, 2624501025, 2624501036, 2624501039, 2624501040 METHOD BLANK: 172451 Matrix: Water Associated Lab Samples: 2624501001, 2624501002, 2624501025, 2624501036, 2624501039, 2624501040 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 5.0 0.32 10/31/19 18:06 1,1,1-Trichloroethane ug/L ND 1.0 0.38 10/31/19 18:06 1,1,2,2-Tetrachloroethane ug/L ND 3.0 0.53 10/31/19 18:06 1,1,2-Trichloroethane ug/L ND 1.0 0.59 10/31/19 18:06 1,1-Dichloroethane ug/L ND 5.0 0.41 10/31/19 18:06 1,1-Dichloroethene ug/L ND 5.0 0.72 10/31/19 18:06 1,2,3-Trichloropropane ug/L ND 1.0 0.46 10/31/19 18:06 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 10/31/19 18:06 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 10/31/19 18:06 1,2-Dichlorobenzene ug/L ND 5.0 0.49 10/31/19 18:06 1,2-Dichloroethane ug/L ND 1.0 0.67 10/31/19 18:06 1,2-Dichloropropane ug/L ND 1.0 0.60 10/31/19 18:06 1,4-Dichlorobenzene ug/L ND 1.0 0.58 10/31/19 18:06 2-Butanone (MEK) ug/L ND 100 3.2 10/31/19 18:06 2-Hexanone ug/L ND 50.0 0.89 10/31/19 18:06 4-Methyl-2-pentanone (MIBK) ug/L ND 100 0.86 10/31/19 18:06 Acetone ug/L ND 100 8.2 10/31/19 18:06 Acrylonitrile ug/L ND 200 2.5 10/31/19 18:06 Benzene ug/L ND 1.0 0.20 10/31/19 18:06 Bromochloromethane ug/L ND 3.0 0.50 10/31/19 18:06 Bromodichloromethane ug/L ND 1.0 0.36 10/31/19 18:06 Bromoform ug/L ND 3.0 0.55 10/31/19 18:06 Bromomethane ug/L ND 10.0 0.95 10/31/19 18:06 Carbon disulfide ug/L ND 100 0.79 10/31/19 18:06 Carbon tetrachloride ug/L ND 1.0 0.42 10/31/19 18:06 Chlorobenzene ug/L ND 3.0 0.53 10/31/19 18:06 Chloroethane ug/L ND 10.0 0.52 10/31/19 18:06 Chloroform ug/L ND 5.0 0.58 10/31/19 18:06 Chloromethane ug/L ND 1.0 0.38 10/31/19 18:06 cis-1,2-Dichloroethene ug/L ND 5.0 0.66 10/31/19 18:06 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 10/31/19 18:06 Dibromochloromethane ug/L ND 3.0 0.31 10/31/19 18:06 Dibromomethane ug/L ND 10.0 0.62 10/31/19 18:06 Ethylbenzene ug/L ND 1.0 0.45 10/31/19 18:06 lodomethane ug/L ND 10.0 3.1 10/31/19 18:06 Methylene Chloride ug/L ND 1.0 0.50 10/31/19 18:06 Styrene ug/L ND 1.0 0.50 10/31/19 18:06 Tetrachloroethene ug/L ND 1.0 0.78 10/31/19 18:06 Toluene ug/L ND 1.0 0.31 10/31/19 18:06 trans-1,2-Dichloroethene ug/L ND 5.0 0.46 10/31/19 18:06 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 10/31/19 18:06 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 157 lV11.1 Analytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 METHOD BLANK: 172451 Associated Lab Samples: Parameter Matrix: Water 2624501001, 2624501002, 2624501025, 2624501036, 2624501039, 2624501040 Blank Reporting Units Result Limit MDL Analyzed trans-1,4-Dichloro-2-butene ug/L ND 100 1.6 10/31/19 18:06 Trichloroethene ug/L ND 1.0 0.34 10/31/19 18:06 Trichlorofluoromethane ug/L ND 1.0 0.51 10/31/19 18:06 Vinyl acetate ug/L ND 50.0 0.42 10/31/19 18:06 Vinyl chloride ug/L ND 1.0 0.60 10/31/19 18:06 Xylene (Total) ug/L ND 5.0 1.5 10/31/19 18:06 1,2-Dichloroethane-d4 (S) %. 108 81-119 10/31/19 18:06 4-Bromofluorobenzene (S) %. 105 82-120 10/31/19 18:06 Dibromofluoromethane (S) %. 105 82-114 10/31/19 18:06 Toluene-d8 (S) %. 104 82-109 10/31/19 18:06 LABORATORY CONTROL SAMPLE: Parameter 172452 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 44.2 88 68-137 1,1,1-Trichloroethane ug/L 50 44.3 89 72-134 1,1,2,2-Tetrachloroethane ug/L 50 51.2 102 51-158 1,1,2-Trichloroethane ug/L 50 47.5 95 78-131 1,1-Dichloroethane ug/L 50 48.4 97 69-151 1,1-Dichloroethene ug/L 50 45.8 92 64-158 1,2,3-Trichloropropane ug/L 50 42.1 84 78-133 1,2-Dibromo-3-chloropropane ug/L 50 40.0 80 58-124 1,2-Dibromoethane (EDB) ug/L 50 47.0 94 71-134 1,2-Dichlorobenzene ug/L 50 47.4 95 70-135 1,2-Dichloroethane ug/L 50 45.2 90 72-129 1,2-Dichloropropane ug/L 50 49.1 98 64-135 1,4-Dichlorobenzene ug/L 50 47.8 96 70-131 2-Butanone (MEK) ug/L 100 102 102 52-143 2-Hexanone ug/L 100 79.3 79 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 87.5J 87 71-129 Acetone ug/L 100 81.2J 81 48-224 Acrylonitrile ug/L 200 1901 95 66-154 Benzene ug/L 50 44.7 89 68-132 Bromochloromethane ug/L 50 49.2 98 73-133 Bromodichloromethane ug/L 50 43.2 86 67-121 Bromoform ug/L 50 39.7 79 57-125 Bromomethane ug/L 50 34.7 69 35-156 Carbon disulfide ug/L 100 84.2J 84 47-141 Carbon tetrachloride ug/L 50 42.8 86 66-122 Chlorobenzene ug/L 50 46.4 93 71-126 Chloroethane ug/L 50 45.8 92 43-143 Chloroform ug/L 50 47.4 95 71-136 Chloromethane ug/L 50 44.9 90 47-123 cis-1,2-Dichloroethene ug/L 50 49.4 99 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 157 Pace Analytical Services, LLC 110 Technology Parkway lCtaac, Analytrcal ePeachtree Corners, GA 30092 www.pacelabs.com (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 LABORATORY CONTROL SAMPLE: Parameter 172452 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 44.8 90 78-120 Dibromochloromethane ug/L 50 42.8 86 65-115 Dibromomethane ug/L 50 47.2 94 79-129 Ethylbenzene ug/L 50 45.4 91 68-129 lodomethane ug/L 100 90.8 91 49-154 Methylene Chloride ug/L 50 43.1 86 61-147 Styrene ug/L 50 51.5 103 77-128 Tetrachloroethene ug/L 50 43.3 87 51-139 Toluene ug/L 50 45.6 91 60-133 trans-1,2-Dichloroethene ug/L 50 46.0 92 69-144 trans- 1,3-Dichloropropene ug/L 50 40.7 81 74-128 trans-1,4-Dichloro-2-butene ug/L 100 82.5J 82 61-139 Trichloroethene ug/L 50 41.5 83 73-126 Trichlorofluoromethane ug/L 50 48.2 96 55-132 Vinyl acetate ug/L 50 51.8 104 52-141 Vinyl chloride ug/L 50 40.2 80 50-133 Xylene (Total) ug/L 150 143 95 78-132 1,2-Dichloroethane-d4 (S) %. 108 81-119 4-Bromofluorobenzene (S) %. 111 82-120 Dibromofluoromethane (S) %. 111 82-114 Toluene-d8 (S) %. 108 82-109 MATRIX SPIKE SAMPLE: Parameter 172453 Units 2624501001 Result Spike Conc. MS Result MS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 50 50.9 102 68-137 1,1,1-Trichloroethane ug/L ND 50 58.3 117 66-142 1,1,2,2-Tetrachloroethane ug/L ND 50 57.7 115 39-171 1,1,2-Trichloroethane ug/L ND 50 57.0 114 73-136 1,1-Dichloroethane ug/L ND 50 58.2 116 66-155 1,1-Dichloroethene ug/L ND 50 64.4 129 33-181 1,2,3-Trichloropropane ug/L ND 50 45.5 91 78-133 1,2-Dibromo-3-chloropropane ug/L ND 50 45.4 91 58-124 1,2-Dibromoethane (EDB) ug/L ND 50 53.0 106 71-134 1,2-Dichlorobenzene ug/L ND 50 54.6 109 69-135 1,2-Dichloroethane ug/L ND 50 52.2 104 36-159 1,2-Dichloropropane ug/L ND 50 57.4 115 68-132 1,4-Dichlorobenzene ug/L ND 50 53.3 107 49-153 2-Butanone (MEK) ug/L ND 100 128 128 10-189 2-Hexanone ug/L ND 100 95.5 95 40-135 4-Methyl-2-pentanone (MIBK) ug/L ND 100 104 104 30-177 Acetone ug/L ND 100 87.3J 87 44-223 Acrylonitrile ug/L ND 200 209 105 13-189 Benzene ug/L ND 50 55.0 110 66-139 Bromochloromethane ug/L ND 50 57.0 114 73-133 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 MATRIX SPIKE SAMPLE: 172453 2624501001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Bromodichloromethane ug/L ND 50 51.5 103 57-120 Bromoform ug/L ND 50 45.4 91 48-128 Bromomethane ug/L ND 50 39.6 79 10-187 Carbon disulfide ug/L ND 100 111 111 47-141 Carbon tetrachloride ug/L ND 50 62.6 125 58-127 Chlorobenzene ug/L ND 50 53.4 107 63-137 Chloroethane ug/L ND 50 57.6 115 52-146 Chloroform ug/L ND 50 55.8 112 74-137 Chloromethane ug/L ND 50 54.1 108 41-127 cis-1,2-Dichloroethene ug/L ND 50 58.4 117 71-138 cis-1,3-Dichloropropene ug/L ND 50 51.4 103 32-145 Dibromochloromethane ug/L ND 50 49.1 98 52-116 Dibromomethane ug/L ND 50 53.8 108 79-129 Ethylbenzene ug/L ND 50 55.9 112 31-174 lodomethane ug/L ND 100 118 118 49-154 Methylene Chloride ug/L ND 50 49.3 99 61-146 Styrene ug/L ND 50 59.4 119 77-128 Tetrachloroethene ug/L ND 50 55.8 112 36-155 Toluene ug/L ND 50 56.1 112 52-146 trans-1,2-Dichloroethene ug/L ND 50 55.8 112 61-152 trans- 1,3-Dichloropropene ug/L ND 50 47.5 95 37-146 trans-1,4-Dichloro-2-butene ug/L ND 100 89.2J 89 61-139 Trichloroethene ug/L ND 50 51.9 104 61-141 Trichlorofluoromethane ug/L ND 50 73.2 146 51-141 M1 Vinyl acetate ug/L ND 50 52.2 104 52-141 Vinyl chloride ug/L ND 50 54.6 109 22-156 Xylene (Total) ug/L ND 150 173 116 78-132 1,2-Dichloroethane-d4 (S) %. 106 81-119 4-Bromofluorobenzene (S) %. 108 82-120 Dibromofluoromethane (S) %. 110 82-114 Toluene-d8 (S) %. 106 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 157 Pace Analytical Services, LLC 110 Technology Parkway lCtaac, Analytrcal ePeachtree Corners, GA 30092 www.pacelabs.com (770)734-4200 QUALIFIERS Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 111 of 157 laceAnalytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID QC Batch Method QC Batch Analytical Method Analytical Batch 2624501001 1304-MW-1A 37195 2624501002 1304-MW-1B 37195 2624501003 1304-MW-2A 37195 2624501004 1304-MW-2B 37195 2624501005 1304-MW-10 37195 2624501006 1304-MW-10A 37195 2624501007 1304-MW-11 37195 2624501008 1304-MW-12 37195 2624501009 1304-MW-14 37195 2624501010 1304-MW-14B 37195 2624501011 1304-MW-15 37195 2624501012 1304-MW-16 37195 2624501013 1304-MW-18A 37195 2624501014 1304-MW-19 37195 2624501015 1304-MW-19A 37195 2624501016 1304-MW-19AR 37195 2624501017 1304-MW-19R 37195 2624501018 1304-MW-20AR 37195 2624501019 1304-MW-20B 37195 2624501020 1304-MW-21 37195 2624501021 1304-MW-21 37195 2624501022 1304-MW-22 37195 2624501023 1304-MW-22A 37195 2624501024 1304-MW-25 37195 2624501025 1304-MW-26 37195 2624501026 1304-MW-27 37195 2624501027 1304-MW-27 37195 2624501028 1304-MW-28 37195 2624501029 1304-MW-29R 37195 2624501030 1304-MW-30R 37195 2624501031 1304-MW-31 37195 2624501032 1304-MW-32R 37195 2624501033 1304-MW-33 37195 2624501034 1304-MW-34 37195 2624501039 SW-1 37195 2624501040 SW-2 37195 2624501001 1304-MW-1A EPA 3005A 37963 EPA 6020B 38008 2624501002 1304-MW-1B EPA 3005A 37963 EPA 6020B 38008 2624501003 1304-MW-2A EPA 3005A 37963 EPA 6020B 38008 2624501004 1304-MW-2B EPA 3005A 37963 EPA 6020B 38008 2624501005 1304-MW-10 EPA 3005A 37963 EPA 6020B 38008 2624501006 1304-MW-10A EPA 3005A 37963 EPA 6020B 38008 2624501007 1304-MW-11 EPA 3005A 37963 EPA 6020B 38008 2624501008 1304-MW-12 EPA 3005A 37963 EPA 6020B 38008 2624501009 1304-MW-14 EPA 3005A 37963 EPA 6020B 38008 2624501010 1304-MW-14B EPA 3005A 37963 EPA 6020B 38008 2624501011 1304-MW-15 EPA 3005A 37963 EPA 6020B 38008 2624501012 1304-MW-16 EPA 3005A 37963 EPA 6020B 38008 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2624501013 1304-MW-18A EPA 3005A 37963 EPA 6020B 38008 2624501014 1304-MW-19 EPA 3005A 37964 EPA 6020B 38009 2624501015 1304-MW-19A EPA 3005A 37964 EPA 6020B 38009 2624501016 1304-MW-19AR EPA 3005A 37964 EPA 6020B 38009 2624501017 1304-MW-19R EPA 3005A 37964 EPA 6020B 38009 2624501018 1304-MW-20AR EPA 3005A 37964 EPA 6020B 38009 2624501019 1304-MW-20B EPA 3005A 37964 EPA 6020B 38009 2624501021 1304-MW-21 EPA 3005A 37964 EPA 6020B 38009 2624501022 1304-MW-22 EPA 3005A 37964 EPA 6020B 38009 2624501023 1304-MW-22A EPA 3005A 37964 EPA 6020B 38009 2624501024 1304-MW-25 EPA 3005A 37964 EPA 6020B 38009 2624501025 1304-MW-26 EPA 3005A 37964 EPA 6020B 38009 2624501027 1304-MW-27 EPA 3005A 37964 EPA 6020B 38009 2624501028 1304-MW-28 EPA 3005A 37964 EPA 6020B 38009 2624501029 1304-MW-29R EPA 3005A 37964 EPA 6020B 38009 2624501030 1304-MW-30R EPA 3005A 37964 EPA 6020B 38009 2624501031 1304-MW-31 EPA 3005A 37964 EPA 6020B 38009 2624501032 1304-MW-32R EPA 3005A 37964 EPA 6020B 38009 2624501033 1304-MW-33 EPA 3005A 37964 EPA 6020B 38009 2624501034 1304-MW-34 EPA 3005A 37964 EPA 6020B 38009 2624501035 DUPLICATE EPA 3005A 37964 EPA 6020B 38009 2624501036 Equipment Blank EPA 3005A 37965 EPA 6020B 38010 2624501037 Field Blank EPA 3005A 37965 EPA 6020B 38010 2624501039 SW-1 EPA 3005A 37965 EPA 6020B 38010 2624501040 SW-2 EPA 3005A 37965 EPA 6020B 38010 2624501001 1304-MW-IA EPA 7470A 38205 EPA 7470A 38248 2624501002 1304-MW-1 B EPA 7470A 38205 EPA 7470A 38248 2624501003 1304-MW-2A EPA 7470A 38205 EPA 7470A 38248 2624501004 1304-MW-2B EPA 7470A 38205 EPA 7470A 38248 2624501005 1304-MW-10 EPA 7470A 38205 EPA 7470A 38248 2624501006 1304-MW-10A EPA 7470A 38205 EPA 7470A 38248 2624501007 1304-MW-11 EPA 7470A 38205 EPA 7470A 38248 2624501008 1304-MW-12 EPA 7470A 38205 EPA 7470A 38248 2624501009 1304-MW-14 EPA 7470A 38205 EPA 7470A 38248 2624501010 1304-MW-14B EPA 7470A 38205 EPA 7470A 38248 2624501011 1304-MW-15 EPA 7470A 38205 EPA 7470A 38248 2624501012 1304-MW-16 EPA 7470A 38205 EPA 7470A 38248 2624501013 1304-MW-18A EPA 7470A 38205 EPA 7470A 38248 2624501014 1304-MW-19 EPA 7470A 38205 EPA 7470A 38248 2624501015 1304-MW-19A EPA 7470A 38205 EPA 7470A 38248 2624501016 1304-MW-19AR EPA 7470A 38205 EPA 7470A 38248 2624501017 1304-MW-19R EPA 7470A 38205 EPA 7470A 38248 2624501018 1304-MW-20AR EPA 7470A 38205 EPA 7470A 38248 2624501019 1304-MW-20B EPA 7470A 38205 EPA 7470A 38248 2624501021 1304-MW-21 EPA 7470A 38205 EPA 7470A 38248 2624501022 1304-MW-22 EPA 7470A 38216 EPA 7470A 38262 2624501023 1304-MW-22A EPA 7470A 38216 EPA 7470A 38262 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 157 laceAnalytical www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2624501024 1304-MW-25 EPA 7470A 38216 EPA 7470A 38262 2624501025 1304-MW-26 EPA 7470A 38216 EPA 7470A 38262 2624501027 1304-MW-27 EPA 7470A 38216 EPA 7470A 38262 2624501028 1304-MW-28 EPA 7470A 38216 EPA 7470A 38262 2624501029 1304-MW-29R EPA 7470A 38216 EPA 7470A 38262 2624501030 1304-MW-30R EPA 7470A 38216 EPA 7470A 38262 2624501031 1304-MW-31 EPA 7470A 38216 EPA 7470A 38262 2624501032 1304-MW-32R EPA 7470A 38216 EPA 7470A 38262 2624501033 1304-MW-33 EPA 7470A 38216 EPA 7470A 38262 2624501034 1304-MW-34 EPA 7470A 38216 EPA 7470A 38262 2624501035 DUPLICATE EPA 7470A 38216 EPA 7470A 38262 2624501036 Equipment Blank EPA 7470A 38216 EPA 7470A 38262 2624501037 Field Blank EPA 7470A 38216 EPA 7470A 38262 2624501039 SW-1 EPA 7470A 38216 EPA 7470A 38262 2624501040 SW-2 EPA 7470A 38216 EPA 7470A 38262 2624501001 1304-MW-1A EPA 8260D 37951 2624501002 1304-MW-1B EPA 8260D 37951 2624501003 1304-MW-2A EPA 8260D 37605 2624501004 1304-MW-2B EPA 8260D 37605 2624501005 1304-MW-10 EPA 8260D 37803 2624501006 1304-MW-10A EPA 8260D 37803 2624501007 1304-MW-11 EPA 8260D 37605 2624501008 1304-MW-12 EPA 8260D 37605 2624501009 1304-MW-14 EPA 8260D 37803 2624501010 1304-MW-14B EPA 8260D 37803 2624501011 1304-MW-15 EPA 8260D 37803 2624501012 1304-MW-16 EPA 8260D 37803 2624501013 1304-MW-18A EPA 8260D 37605 2624501014 1304-MW-19 EPA 8260D 37605 2624501015 1304-MW-19A EPA 8260D 37605 2624501016 1304-MW-19AR EPA 8260D 37605 2624501017 1304-MW-19R EPA 8260D 37605 2624501018 1304-MW-20AR EPA 8260D 37605 2624501019 1304-MW-20B EPA 8260D 37605 2624501020 1304-MW-21 EPA 8260D 37803 2624501022 1304-MW-22 EPA 8260D 37605 2624501023 1304-MW-22A EPA 8260D 37605 2624501024 1304-MW-25 EPA 8260D 37605 2624501025 1304-MW-26 EPA 8260D 37951 2624501026 1304-MW-27 EPA 8260D 37803 2624501028 1304-MW-28 EPA 8260D 37605 2624501029 1304-MW-29R EPA 8260D 37605 2624501030 1304-MW-30R EPA 8260D 37803 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /23/2019 08:19 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CMS V Landfill -Revised Report Pace Project No.: 2624501 Lab ID Sample ID QC Batch Method QC Batch 2624501031 1304-MW-31 EPA 8260D 37605 2624501032 1304-MW-32R EPA 8260D 37608 2624501033 1304-MW-33 EPA 8260D 37608 2624501034 1304-MW-34 EPA 8260D 37608 2624501035 DUPLICATE EPA 8260D 37608 2624501036 Equipment Blank EPA 8260D 37951 2624501037 Field Blank EPA 8260D 37608 2624501038 Trip Blank EPA 8260D 37605 2624501039 SW-1 EPA 8260D 37951 2624501040 SW-2 EPA 8260D 37951 Date: 11/23/2019 08:19 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 115 of 157 U z m m� a a (WA) OUPOlUO IGnplsea -ramlctl; •o®000ev©ove© . ti ~ �• �s Q o z W ui W U 'a o d r .,, �00 CND ,�► t� cn r__ A N a ..�. .Q .i Q i n i •� '• (dwoo.. BYHO.0) 3dA131dws S .,i J J aT �T �T S s ; F s UPI of ■GPM P9en ...) 3Q03 XIll1VW tt ee t rr rr d tt a.c u oS�aino3°d O� = 3 �o33d838�� }�"1 a d O Lt 0 1 n .-M _j J o �, r1 S M Q 9 l 3> 7 z Z 2 3 Q mra 7 J! # W311 Eu -nil it uopo 3 Ln f .- = (NIA seldwe O N1A r [ :- _ f A00 ^ A peiea isn C-A', U (N/A Z a (MIA) auuolyO lenplsoll uo peAleos m [ - 0 of 'Ma 9 f n Ll b '!'^ ='_ a s uo) 00 QSnj dwel OS Hd tt. L d x �( ti Y n = to ' BH+ slelapy X Qi T !� w C. 09Z9 tq DOA X m IWO E > £OZSZeN in HOeN {{ M e%► CA c m H IOH sal L c h Z m b � VOSZH _ a o m E m O v a a u peASaswduN a Q U cmi Q d d a Sa3NIV1NO3 d0 o S .T S �' g ,�' '� M •"' S .� ! y. l' = NOI1031103IV043131dMS u�i u�j a a r �r�j O o p Z :24.� E Lu Lu U W O r- 2 C Z ,i 3 `_:n :5 H _ p i r S a )p 6 �' ` M M N r F l%5 p ' e r c�. T m r CD m U (dW00�O BtlaOaO) 3dA131dW'dS �J i.7 c?t CT cYtt Jtt tt tt C 3 S s U. m (405 s,p„ pgeA ouc) 3o03 xla1NW �l CL O E 9 F o m 2 if o tt33'I�k c�i�53aL'i0��0.FL .S r) / q$g o3: ap Q� m I acr �$ d C,4 0 qa o=m� Au o ?X V nor •E 7 O N c�) m�m v � C (0 ¢ u z EQ $ #W311 • = ge D - a 'a w 0 � ci ci a (WA) euuoly0 lenp!sey s uo) 00 qm1 dwe10S Hd iL is X t BH. sle=eyl +C !C o9Z9 AQ 00A �• .0 11 x �! n m ieu10 lousyieyr i, ¢OZSZeN HOeN m g� I OH l n m d aZi ur N CONH -- r 0_ m vOSZH ��ooeov000voo 0 w L) U w O U � F ~ D y _ G m (MOO-O eVED-9) 3dAl3ldViVS (7 U o m (yal of copoa Alen LYI) 3000 XRllVA a io p to g F o W Z' OU O$at�ii0$�O� 7 O T di fA D a U a R & L 3 4 rC o yy L � 3 m y m n U Z E C O F - C O m a 0¢ chi w a y LLj _ q O Q T 00 5- = L V' rrL aA as p O 0 f7 O Ci 0 Ll cL t-i w J^ mom= N N, M J li u o E Q tla a 1 1 , } N o (A ` L C L pp p # W3il (WA) puiul seldweS --TN—/7,k lelao0 peleeS Apoisn0 (WA) Sol uo poNeoey 0 u! dW31 M z (N/A) auuol4O lenpisoa m — m � s C d dC Q E G U ✓t y V L O in E E m v s uo) 00 Qjnl durel OS Hd ,l x rn BH+ stelaµ) c > m 09ZB A9 OOA W, N n m ��*-wl euy a Jokao F- •cc $ Zj E loumaow $ > £OZSZeN C U co io HOeN H IOH cn C4�1 U ii 0 £ONH Q J z DOSZH 0 o N ul u « n p d y peniasajduN O Vl G Q U Q a a a Skl3NIV1NOO:i d" �- LL N0110311001V dW31 3ldWVS O U I?i w c QL U ul _ M o rw- L o U ,L- W o c� r O 0 > a rn a 0 � " v (dW00a'J BVU0.0) 3dA131dWVS —IT tt �tt tt tt tt tt tt tt tt S 5 S $ S o a o (Ygl W rapm peen ggr) 3000 XRLLVW S $ S S m m I°- o 0 a T z ii $ o c°� aino odor n 3 3a33�8�8`s� � � � Z 0 LL 3 cD 5 yg W .4) .J $ + $ a u o E J ! 1 o �x mCL n 0 w i (i:%A rz a O Np a S m O a) i ro U z _ m 8 m #W311ff �_- W. m L) ¢ ci a=� Q L u0 p& OLP r 3 a Sample Condition Upon Receipt " areAnaCal Client Name: %Al Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial L`fPace Other �Dt ip }pe, Tracking #: ;i�Enim���,tl+rtr Custody Seal on Cooler/Box Present: yes ❑ no Seals intact: yes Packing Material: Bubble Wrap E39ubble Bags ❑ None ❑ Other Thermometer Used Type of Ice: Wet Blue None ❑ Samples on ice, cooling process has begu Cooler Temperature Biological Tissue is Frozen: Yes No Date and Initial? examinin r g Temp should be above freezing to 6°C Comments: conten , r Chain of Custody Present: Di it 'C]No ❑NIA 1. Chain of Custody Filled Out: I�JYes ❑No ❑N/A 2, Chain of Custody Relinquished: Yes ❑No ❑N/A 3. Sampler Name & Signature on COC: El r� ❑No ❑N/A 4. Samples Arrived within Hold Time: L Y es ❑No ❑N/A 5. Short Hold Time Analysis (<72hr): Oyes DKo ❑N/A 6. Rush Turn Around Time Requested: ❑Yes ❑ o ❑N/A 7. Sufficient Volume: Rle-'s' ON ❑N/A 8. Correct Containers Used: -Pace Containers Used: 'yes El No es ❑No ❑NIA ❑NIA g. Containers Intact: ❑ es ❑No ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ❑No Ofq A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: O er❑No El N/A 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. exceptions O iforrn, TOC, O&G, WI-DRO (water) es No �yE�L'INo es ❑No ❑NIA ❑NIA 13. Initial when completed Lot # of added preservative Samples checked for dechlodnation: ❑Yes ❑No t/A 14. Headspace in VOA Vials ( >6mm): ❑❑Y/es� o ❑N/A 15. Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # if purchased): 12 Yes No ZYes []No ❑N/A ❑N/A 16. Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Time: Field Data Required? Y I N Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Page 120 of 57 F-ALLC003rev.3, 11September20 aceAnalyticala October 29, 2019 BPI Wal f'P SWP�orth rarolina Mr. Mike Gurley 5105-A Morehead Road, Concord, North Carolina 28027 RE: Charlotte Motor Speedway V Landfill Report 2624501 Mr. Gurley: Pace Anatyttcst Services, Inc. 110 Technology Parkway Peachtree Cancers, GA 30092 Phone: 770.734 4200 Fax: 770.734 4201 www.pagoiabs.com Pace Analytical completed the semi-annual groundwater and surface water at the referenced site on October 17, 2019. Our representatives performed groundwater monitoring in accordance with the most recently approved U.S. E.P.A. Region 4 Operating Procedures. Presented herein is a description of our work. The following wells were purged and sampled using a dedicated Grundfos pump and Teflon -lined tubing: MW-1A,113, 2A, 213,10,10A,11,12,14,1413,15,16,18A,19,19A, 19AR,19R, 20AR, 2013, 21, 22, 22A, 25, 26, 27, 28, 29R, 30R, 31, 32R, 33, and 34. Surface water points sampled: SW-1 and 2. Water levels and bottom of casing depths were measured to the nearest hundredth of a foot prior to purging the wells. Indicator parameters were measured on site for pH, specific conductance, temperature, dissolved oxygen, and turbidity. All indicator parameter were also measured on surface waters. The meters were calibrated in the field according to the manufacturers' specifications and checked periodically. The water level indicator and instrument probes were decontaminated in the field using a modified version of the EPA Appendix B. All pumps/tubing were decontaminated prior to being brought on site. The samples were collected in A certified -clean bottles as soon as three well volumes had been removed and field parameters stabilized. The bottles were labeled in the field at the time of sampling. The members of the sampling team initialed the labels before placing them on the bottles. New gloves were donned prior to collecting samples. Page 121 of 157 aceAnalytical° Pace Analytical Services, Inc. 110 Technology Parkway Peachtree Corners, GA 30092 Phone: 770734.42070 Fax: 770.734.4201 www.pacei8bs.com Samples for Appendix I Metals were collected in 2S0 mL wide -mouth HDFE bottles pre -preserved by the supplier with HNO3. Samples for Appendix I VOC's were collected in three 40 mL vials pre -preserved by the supplier with HCI. Once the bottles were filled they were placed in an ice chest filled with ice to maintain four degrees centigrade. Attached are the results from this sampling event and table listing the water levels recorded. Respe fully submitted, Ao�t_ Jonathan Scott Field Services Manager Page 122 of 157 r O L � o N r a V a a w to a O Z G •C. W E a 0� r_ J r0+ o N O �Y m L O E m a�v)0 E c z 0 v0CLUS 1toNcc CD LO 0r F3- O N N N N QLLCq r t0 chi p co Q ~r`nC6cDrCMi` r r r r Q N to CD n w — N cm N N � N N N O N r CM n N n N 0 w N N O m N CC%4 N N N O Q CA r Q CD Q C r N CA r r p N N 3 ................ . N CC) N nn0VOntc) CD CO CA eM O CO Q O r O V.- O V.- CD r M r CM r I� r M N dmr— � v , 00 Q O N N - Q Q m N Q p r N } 7 7 m m 78 CL (a Page 123 of 157 7 r r o CC y a° r y ^v OG H w � a O Uzi o � � a C C � 4C) Q. C a� 2 � w4. 0 oo y O O %" Q C V U V A ii3v� �5 r' GQ T y v Cl) O O O Q V H ct c (A cj>> AR c- n u:3 .�N� 5 4 G3' i o Cr qrr M ity S 9 r to .� ce o rCA <� u 1 cp I tr o m L _ =L ado 10 z E F > � N cm R a 0 Page 124 of 157 30 C 54 a ri p v r W _ O � a� to �V 0 W O !' V G C a [ v� 3 3 .i Il II � O n fX-i > > O of QCi UC II uv> o n�3�Cre II II o o •� O O > y.r 01 p p --3U > > C °3 C� o3UU 3 N u C z .00 ,S 0�v330 A _ C, tr ICE _c r Cli F O a � z O ua C/! 0 W O J W7 G� Page 125 of 157 �b AG w AC w M `U0 w O o a O C O � U N V c. [ ] a� as w •� a a w 0 4.., O*�O � 6Q � O C b "d UUrm3� � r ry J 11 V „ u M 'j O X X 3 U u U � o .. U M G C 1 Q`3 3 � +,• 42 C a y E y =--rx S O d r a o o 2 c 0, �C30"°3 VOf , � 'y -0 C� =F+ =cu 0 2 :UU > v �tj3r-r-W A > tl- l,n 0 Z E U � .-. O V .. O v low LJ� 0 MI Page 126 of 157 CI= r I glu I C;. ro Q Ir zO w 0 td A Page 127 of 157 C � v tx aG O O � b � z �U 0 y 6� 1 0 a w. 4., •c p D 0 M �,. U U ��✓ a � 4 b�i law �'.. Y+ tR x w o II 33 .. •�i f�UV°>o CA A j a o o > .-. L4 0 > > .� s U U A U v V N U y n w3 N A3Hgs�i l L ',� ; g E� aP R (-� > 3 03 Fy A Cal U C 6 Page 128 of 157 Buz o>0 ° a W 3 .. a. o «. a. r� v Q C� � r .G V w UUCP] O N o a� 0 C �� e�!�;���1 [A ° A�.v: o a . I w N N 0- z 0 W �a 01 z Q o c Page 129 of 157 O ° a a' ,o 0 0 N � U O � e `>> U E 3 W .2 .o O o aIIJ ❑ S r-� cn GOt U U�3� Y ci r M `rl a.� k X U �' II UU a R` .r > > c 40. °3U uq ter, c 'O r. C .� e� ro o� �3UU; E O w�cam' o33c o ��xUj�•/��Ar� �U r 4 r. +� I••1 5 i.r N d i/] ✓ i�} S A� Page 130 of 157 w 9 CIC ---; o •° — . o 1-1'a H w.2 N.� U U A 3 A=, I� DO 19 0 m a z O Ce m F W O G Page 131 of 157 4 W 3 GG oG w w d' ^o � a 0 c � � o U •� 0. ❑ G O a� ❑ A O O e� U U � � O 3 N y � II II ��� -ALA I� V C r4 �33 II r V_ U o i� Q O •R v U M � ' r � o �3U» 03 r o E 4 4., 2 UU, E � r r M t'b Zr- o� v ^` x O � E U � .. o U0 v K o (~ z E a ° H � 3 CL V) Page 132 of 157 ti w o� oG •-i' w cQ i C d 0 U A C A 'g o 0 Ob �o�= U U M CA � r > r 3 C,6 II II x x 1~, cC fs, > > O V) U II r� e uu > C tx � �3•� C a,'o t `� • C � � G Q�r tCr. y �3 0 V > u > tan z Q ISI 0 v � �,�,� 3U rA w3 A3r �q,!r ° J i zoo ro � O a r+ kr rrch�� 00 9 QV � N A V1 4 � 41 O 0 � 3 cl CA v e, a 3 Page 133 of 157 A Page 134 of 157 0. it i. Y' U z a>CL(33 C O � ,0 •� O N O > ai A O O O 1Q cd` M s .d V Za tn M o OG II U U 11 U o `/ v _ -0 > 0Li =3 °„ °3 C) �, c m t} o U 10 u uc'u .2 a �°o C33oE o �= ��. 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W C W ,a 0 o ° ') a; A uua3 w r o 1 ti • � s: + y 40 Q � M rc� i Y N x * N * O 0 10 0 N z a _ � F�3x�3hAc� PO O mall Page 148 of 157 �d "r A o 1+ L; Uz > O Sir O � a G y N *0 u y 0A 0 G 1p 4 ram ' V' O 0�n �n O a � r , N u' Ay Q y y II Tn d it ,� o 0 GC K x II 3 3 II a • 2 V) o r ®` O cR AMA II^II 0 a 0 y � ��� ` w d N 0 pU M .1 * * V, � ' � 5 c � a c � c � �• W O p C cn C O ) v p.Slv L .9 5 a ct oq o3QU °'� O z o�C33o a3Nr�Ntrv�� Page 149 of 157 ■ Vs. - iD Vl Vf 4�r Gr� O r y aN w 6. U C .0 U w O �+1 w s� ' II II �%�Ok� II tl. O c� f�4 6 5. II 3UU o Oil U M C a N O O O > 4' C Li °3u °3 w ~°Av3UUW * O GGG N * V� O Q w rz 10 N zV W 0 r v U co >3x�31: 0 `o �I Page 150 of 157 J 0 0 u ❑ 0 o N �' C►- 1 �MMkp V 10 '%n --- : O II II cM ','f' - In N 0 0 � k k � Ip Ell II Uo�� cr U V u 3A3 o 0 .p (� M r 0 0 x w o o > c3 O» 83 v _ Y v .s 5 UQ�3VUwa �a a>� y "U O 72 . cr 3 c. v� E� A C7 16 a ate+ I O Page 151 of 157 I { f _ r4- d M %p 4, y ��rtWp '0 -40~ N�+ qrf a N N cn r r. d' �Nrl: O .Jr e,�AP N 9 N O �(�1PS rN r fl �D * N � O X O_ Page 152 of 157 CI= 3 z o > G , a C O CA b 41 o o A U Ulm ;8 2 3 LAO .01 oS F � d Q � V p Page 153 of 157 o N O 0 lip M rIL v Ik- z 0 4 W w V O y � C a� a� a� U a o � '� iii CJ C C u r yE {.� ❑ U M iii O > > C id oU, tz 5 94„ .. O U V v w3 A3Hr��N��H H>3x�3 H 04 A Page 154 of 157 Page 155 of 157 as b ¢zzz zz b, r � 4 U o o Q U U 0 4 *� CIS zz U �� AG U 44z x 0 U v � •r "G � S o r7 VJ � 4 0 v o Lj Page 156 of 157 1+ zz zzz a O � o �U o o Q U U 0 Kn N _ zz ry � � 0 0 N Np � � � �t w x�3V 3 N 8 (n 0 04 M r o b }+ o E `L x z U �� !►� I U�w3 30�-x�3�LLLLo G 'r5 Page 157 of 157 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 November 26, 2019 Environmental Manager BFI Waste Systems of North America. LLC 5105 Moreland Road Concord, NC 28027 RE: Project: CMS Untreated Leachate Pace Project No.: 2625377 Dear Environmental Manager: Enclosed are the analytical results for sample(s) received by the laboratory on November 07, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Maiya Parks maiya.parks@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Database Manager REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 CERTIFICATIONS Project: CMS Untreated Leachate Pace Project No.: 2625377 Pace Analytical Services Atlanta 110 Technology Parkway Peachtree Corners, GA 30092 North Carolina Certification #: 381 Florida DOH Certification #: E87315 South Carolina Certification #: 98011001 Georgia DW Inorganics Certification #: 812 Virginia Certification #: 460204 Georgia DW Microbiology Certification #: 812 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: CMS Untreated Leachate Pace Project No.: 2625377 Lab ID Sample ID Matrix Date Collected Date Received 2625377001 Untreated Leachate Water 11/06/19 11:56 11/07/19 15:00 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: CMS Untreated Leachate Pace Project No.: 2625377 Lab ID Sample ID Method Analysts Analytes Reported 2625377001 Untreated Leachate EPA6020B CSW 15 EPA 7470A DRB 1 EPA 8260D LIH 51 EPA410.4 ANB 1 SM 4500-P JAD 1 SM 4500-P JAD 1 SM 5210B KN 1 EPA 9056A MWB 1 EPA 9056A MWB 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS Untreated Leachate Pace Project No.: 2625377 Sample: Untreated Leachate Lab ID: 2625377001 Collected: 11/06/19 11:56 Received: 11/07/19 15:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3- chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene Date: 11/26/2019 10:54 PM Analytical Method: 7.74 Std. Units 1 14.7 deg C 1 5499 umhos/c 1 m Analytical Method: EPA 6020B Preparation Method: EPA 3005A 11 /06/19 12:56 11 /06/19 12:56 11 /06/19 12:56 186 ug/L 6.0 0.27 1 11/15/1915:46 11/19/1919:52 7440-36-0 493 ug/L 10.0 0.35 1 11/15/1915:46 11/19/1919:52 7440-38-2 700J ug/L 1000 4.9 10 11/15/19 15:46 11/21/19 00:11 7440-39-3 ND ug/L 1.0 0.074 1 11/15/1915:46 11/19/1919:52 7440-41-7 ND ug/L 1.0 0.11 1 11/15/1915:46 11/19/1919:52 7440-43-9 82.7 ug/L 10.0 0.39 1 11/15/1915:46 11/19/1919:52 7440-47-3 40.3 ug/L 10.0 0.30 1 11/15/1915:46 11/19/1919:52 7440-48-4 16.7 ug/L 10.0 0.19 1 11/15/1915:46 11/19/1919:52 7440-50-8 B 4.4J ug/L 10.0 0.046 1 11/15/1915:46 11/19/1919:52 7439-92-1 207 ug/L 50.0 0.31 1 11/15/1915:46 11/19/1919:52 7440-02-0 2.3J ug/L 10.0 1.3 1 11/15/1915:46 11/19/1919:52 7782-49-2 ND ug/L 10.0 0.28 1 11/15/1915:46 11/19/1919:52 7440-22-4 ND ug/L 5.5 0.052 1 11/15/1915:46 11/19/1919:52 7440-28-0 24.5J ug/L 25.0 0.71 1 11/15/1915:46 11/19/1919:52 7440-62-2 110 ug/L 10.0 1.5 1 11/15/1915:46 11/19/1919:52 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 0.14 1 11/12/1913:45 11/13/1913:12 7439-97-6 Analytical Method: EPA 8260D 105J ug/L 250 82.0 10 11/16/19 03:13 67-64-1 ND ug/L 500 25.0 10 11/16/19 03:13 107-13-1 ND ug/L 10.0 2.0 10 11/16/19 03:13 71-43-2 ND ug/L 10.0 5.0 10 11/16/19 03:13 74-97-5 v1 ND ug/L 10.0 3.6 10 11/16/19 03:13 75-27-4 ND ug/L 10.0 5.5 10 11/16/19 03:13 75-25-2 84.4 ug/L 20.0 9.5 10 11/16/19 03:13 74-83-9 ND ug/L 50.0 32.0 10 11/16/19 03:13 78-93-3 ND ug/L 100 7.9 10 11/16/19 03:13 75-15-0 ND ug/L 10.0 4.2 10 11/16/19 03:13 56-23-5 ND ug/L 10.0 5.3 10 11/16/19 03:13 108-90-7 ND ug/L 10.0 5.2 10 11/16/19 03:13 75-00-3 ND ug/L 10.0 5.8 10 11/16/19 03:13 67-66-3 21.2 ug/L 10.0 3.8 10 11/16/19 03:13 74-87-3 ND ug/L 20.0 5.5 10 11/16/19 03:13 96-12-8 ND ug/L 10.0 3.1 10 11/16/19 03:13 124-48-1 ND ug/L 20.0 2.8 10 11/16/19 03:13 106-93-4 ND ug/L 10.0 6.2 10 11/16/19 03:13 74-95-3 ND ug/L 10.0 4.9 10 11/16/19 03:13 95-50-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS Untreated Leachate Pace Project No.: 2625377 Sample: Untreated Leachate Lab ID: 2625377001 Collected: 11/06/19 11:56 Received: 11/07/19 15:00 Matrix: Water Report Reg. Parameters Results Units Limit MDL Limit DF Prepared Analyzed CAS No. Qual 8260D MSV 1,4-Dichlorobenzene trans-1,4-Dichloro-2- butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropene cis-1,3-Dichloropropene trans- 1,3-Dichloropropene Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pe n to n o n e (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 410.4 COD Chemical Oxygen Demand 450OPE Total Phosphorus Phosphorus 450OPE Ortho Phosphorus Orthophosphate as P Date: 11/26/2019 10:54 PM Analytical Method: EPA 8260D ND ug/L 10.0 5.8 10 11/16/19 03:13 106-46-7 ND ug/L 50.0 16.0 10 11/16/19 03:13 110-57-6 ND ug/L 10.0 4.1 10 11/16/19 03:13 75-34-3 ND ug/L 10.0 6.7 10 11/16/19 03:13 107-06-2 ND ug/L 10.0 7.2 10 11/16/19 03:13 75-35-4 ND ug/L 10.0 6.6 10 11/16/19 03:13 156-59-2 ND ug/L 10.0 4.6 10 11/16/19 03:13 156-60-5 ND ug/L 10.0 6.0 10 11/16/19 03:13 78-87-5 ND ug/L 10.0 2.2 10 11/16/19 03:13 10061-01-5 ND ug/L 10.0 3.0 10 11/16/19 03:13 10061-02-6 ND ug/L 10.0 4.5 10 11/16/19 03:13 100-41-4 ND ug/L 50.0 8.9 10 11/16/19 03:13 591-78-6 ND ug/L 100 31.0 10 11/16/19 03:13 74-88-4 ND ug/L 10.0 5.0 10 11/16/19 03:13 75-09-2 ND ug/L 50.0 8.6 10 11/16/19 03:13 108-10-1 ND ug/L 10.0 5.0 10 11/16/19 03:13 100-42-5 ND ug/L 10.0 3.2 10 11/16/19 03:13 630-20-6 ND ug/L 10.0 5.3 10 11/16/19 03:13 79-34-5 ND ug/L 10.0 7.8 10 11/16/19 03:13 127-18-4 ND ug/L 10.0 3.1 10 11/16/19 03:13 108-88-3 ND ug/L 10.0 3.8 10 11/16/19 03:13 71-55-6 ND ug/L 10.0 5.9 10 11/16/19 03:13 79-00-5 ND ug/L 10.0 3.4 10 11/16/19 03:13 79-01-6 ND ug/L 10.0 5.1 10 11/16/19 03:13 75-69-4 ND ug/L 10.0 4.6 10 11/16/19 03:13 96-18-4 ND ug/L 20.0 4.2 10 11/16/19 03:13 108-05-4 ND ug/L 10.0 6.0 10 11/16/19 03:13 75-01-4 ND ug/L 20.0 14.6 10 11/16/19 03:13 1330-20-7 106 %. 81-119 10 11/16/19 03:13 17060-07-0 104 %. 82-114 10 11/16/19 03:13 1868-53-7 101 %. 82-120 10 11/16/19 03:13 460-00-4 106 %. 82-109 10 11/16/19 03:13 2037-26-5 Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 1250000 ug/L 50000 50000 1 11/15/19 09:35 11/15/19 13:37 Analytical Method: SM 4500-P Preparation Method: SM 4500-P 424 ug/L 200 200 1 11/14/1912:30 11/14/1919:39 7723-14-0 Analytical Method: SM 4500-P ND ug/L 200 200 10 11/08/1911:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. v1 v1 Page 6 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: CMS Untreated Leachate Pace Project No.: 2625377 Sample: Untreated Leachate Parameters Lab ID: 2625377001 Collected: Report Results Units Limit MDL 11/06/19 11:56 Received: 11/07/19 15:00 Matrix: Water Reg. Limit DF Prepared Analyzed CAS No. Qual 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 67800 ug/L 46800 46800 30 11/08/19 11:53 11/13/19 14:36 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 15800 ug/L 50.0 5.0 1 11/09/19 14:19 14797-55-8 H1 9056 IC Anions Analytical Method: EPA 9056A Sulfate ND ug/L 5000 17.0 1 11/09/1914:19 14808-79-8 Date: 11/26/2019 10:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38630 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2625377001 METHOD BLANK: 175574 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.14 11/13/1912:07 LABORATORY CONTROL SAMPLE: 175575 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.7 107 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 175576 175577 MS MSD 2625466002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.8 2.7 112 109 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38953 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2625377001 METHOD BLANK: 176938 Associated Lab Samples: 2625377001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers Antimony ug/L ND 6.0 0.27 11/19/1917:57 Arsenic ug/L ND 10.0 0.35 11/19/1917:57 Barium ug/L ND 100 0.49 11/19/1917:57 Beryllium ug/L ND 1.0 0.074 11/19/1917:57 Cadmium ug/L ND 1.0 0.11 11/19/1917:57 Chromium ug/L ND 10.0 0.39 11/19/1917:57 Cobalt ug/L ND 10.0 0.30 11/19/1917:57 Copper ug/L 4.7J 10.0 0.19 11/19/1917:57 Lead ug/L ND 10.0 0.046 11/19/1917:57 Nickel ug/L ND 50.0 0.31 11/19/1917:57 Selenium ug/L ND 10.0 1.3 11/19/1917:57 Silver ug/L ND 10.0 0.28 11/19/1917:57 Thallium ug/L ND 5.5 0.052 11/19/1917:57 Vanadium ug/L ND 25.0 0.71 11/19/1917:57 Zinc ug/L 5.9J 10.0 1.5 11/19/1917:57 LABORATORY CONTROL SAMPLE: 176939 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 98.0 98 80-120 Arsenic ug/L 100 96.5 96 80-120 Barium ug/L 100 94.9J 95 80-120 Beryllium ug/L 100 99.1 99 80-120 Cadmium ug/L 100 97.9 98 80-120 Chromium ug/L 100 101 101 80-120 Cobalt ug/L 100 100 100 80-120 Copper ug/L 100 99.4 99 80-120 Lead ug/L 100 98.3 98 80-120 Nickel ug/L 100 98.1 98 80-120 Selenium ug/L 100 95.5 96 80-120 Silver ug/L 100 99.6 100 80-120 Thallium ug/L 100 98.3 98 80-120 Vanadium ug/L 100 99.4 99 80-120 Zinc ug/L 100 104 104 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: CMS Untreated Leachate 2625377 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 176940 176941 MS MSD 2625428058 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 78.3 82.5 78 82 75-125 5 20 Arsenic ug/L ND 100 100 99.5 99.2 97 97 75-125 0 20 Barium ug/L 0.11 mg/L 100 100 269 287 160 178 75-125 6 20 M1 Beryllium ug/L ND 100 100 86.5 88.2 85 86 75-125 2 20 Cadmium ug/L ND 100 100 101 104 101 103 75-125 2 20 Chromium ug/L ND 100 100 112 115 106 109 75-125 3 20 Cobalt ug/L ND 100 100 105 106 101 103 75-125 2 20 Copper ug/L ND 100 100 107 109 100 103 75-125 3 20 Lead ug/L 0.0066 100 100 105 106 98 100 75-125 2 20 mg/L Nickel ug/L ND 100 100 104 107 100 103 75-125 3 20 Selenium ug/L ND 100 100 95.0 97.5 94 96 75-125 3 20 Silver ug/L ND 100 100 101 103 101 102 75-125 2 20 Thallium ug/L ND 100 100 99.1 101 99 101 75-125 2 20 Vanadium ug/L 0.016 100 100 122 125 106 109 75-125 2 20 mg/L Zinc ug/L 0.021 100 100 126 131 105 110 75-125 4 20 mg/L Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38927 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2625377001 METHOD BLANK: 176743 Associated Lab Samples: 2625377001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.32 11/15/19 10:48 1,1,1-Trichloroethane ug/L ND 1.0 0.38 11/15/19 10:48 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 11/15/19 10:48 1,1,2-Trichloroethane ug/L ND 1.0 0.59 11/15/19 10:48 1,1-Dichloroethane ug/L ND 1.0 0.41 11/15/19 10:48 1,1-Dichloroethene ug/L ND 1.0 0.72 11/15/19 10:48 1,2,3-Trichloropropane ug/L ND 1.0 0.46 11/15/19 10:48 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 11/15/19 10:48 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 11/15/19 10:48 1,2-Dichlorobenzene ug/L ND 1.0 0.49 11/15/19 10:48 1,2-Dichloroethane ug/L ND 1.0 0.67 11/15/19 10:48 1,2-Dichloropropane ug/L ND 1.0 0.60 11/15/19 10:48 1,4-Dichlorobenzene ug/L ND 1.0 0.58 11/15/19 10:48 2-Butanone (MEK) ug/L ND 5.0 3.2 11/15/19 10:48 2-Hexanone ug/L ND 5.0 0.89 11/15/19 10:48 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.86 11/15/19 10:48 Acetone ug/L ND 25.0 8.2 11/15/19 10:48 Acrylonitrile ug/L ND 50.0 2.5 11/15/19 10:48 Benzene ug/L ND 1.0 0.20 11/15/19 10:48 Bromochloromethane ug/L ND 1.0 0.50 11/15/19 10:48 Bromodichloromethane ug/L ND 1.0 0.36 11/15/19 10:48 Bromoform ug/L ND 1.0 0.55 11/15/19 10:48 Bromomethane ug/L ND 2.0 0.95 11/15/19 10:48 Carbon disulfide ug/L ND 10.0 0.79 11/15/19 10:48 Carbon tetrachloride ug/L ND 1.0 0.42 11/15/19 10:48 Chlorobenzene ug/L ND 1.0 0.53 11/15/19 10:48 Chloroethane ug/L ND 1.0 0.52 11/15/19 10:48 Chloroform ug/L ND 1.0 0.58 11/15/19 10:48 Chloromethane ug/L ND 1.0 0.38 11/15/19 10:48 cis-1,2-Dichloroethene ug/L ND 1.0 0.66 11/15/19 10:48 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 11/15/19 10:48 Dibromochloromethane ug/L ND 1.0 0.31 11/15/19 10:48 Dibromomethane ug/L ND 1.0 0.62 11/15/19 10:48 Ethylbenzene ug/L ND 1.0 0.45 11/15/19 10:48 lodomethane ug/L ND 10.0 3.1 11/15/19 10:48 Methylene Chloride ug/L ND 1.0 0.50 11/15/19 10:48 Styrene ug/L ND 1.0 0.50 11/15/19 10:48 Tetrachloroethene ug/L ND 1.0 0.78 11/15/19 10:48 Toluene ug/L ND 1.0 0.31 11/15/19 10:48 trans-1,2-Dichloroethene ug/L ND 1.0 0.46 11/15/19 10:48 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 11/15/19 10:48 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 METHOD BLANK: 176743 Associated Lab Samples: 2625377001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL trans-1,4-Dichloro-2-butene ug/L ND 5.0 Trichloroethene ug/L ND 1.0 Trichlorofluoromethane ug/L ND 1.0 Vinyl acetate ug/L ND 2.0 Vinyl chloride ug/L ND 1.0 Xylene (Total) ug/L ND 2.0 1,2-Dichloroethane-d4 (S) %. 105 81-119 4-Bromofluorobenzene (S) %. 104 82-120 Dibromofluoromethane (S) %. 103 82-114 Toluene-d8 (S) %. 107 82-109 Analyzed 1.6 11/15/19 10:48 0.34 11/15/19 10:48 0.51 11/15/19 10:48 0.42 11/15/19 10:48 0.60 11/15/19 10:48 1.5 11/15/19 10:48 11/15/19 10:48 11/15/19 10:48 11/15/19 10:48 11/15/19 10:48 LABORATORY CONTROL SAMPLE: Parameter 176744 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 49.8 100 68-137 1,1,1-Trichloroethane ug/L 50 50.6 101 72-134 1,1,2,2-Tetrachloroethane ug/L 50 59.1 118 51-158 1,1,2-Trichloroethane ug/L 50 56.9 114 78-131 1,1-Dichloroethane ug/L 50 58.3 117 69-151 1,1-Dichloroethene ug/L 50 60.0 120 64-158 1,2,3-Trichloropropane ug/L 50 48.7 97 78-133 1,2-Dibromo-3-chloropropane ug/L 50 55.7 111 58-124 1,2-Dibromoethane (EDB) ug/L 50 53.4 107 71-134 1,2-Dichlorobenzene ug/L 50 56.5 113 70-135 1,2-Dichloroethane ug/L 50 51.1 102 72-129 1,2-Dichloropropane ug/L 50 52.2 104 64-135 1,4-Dichlorobenzene ug/L 50 56.3 113 70-131 2-Butanone (MEK) ug/L 100 119 119 52-143 2-Hexanone ug/L 100 81.9 82 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 93.6 94 71-129 Acetone ug/L 100 121 121 48-224 Acrylonitrile ug/L 200 205 102 66-154 Benzene ug/L 50 52.9 106 68-132 Bromochloromethane ug/L 50 57.4 115 73-133 Bromodichloromethane ug/L 50 50.1 100 67-121 Bromoform ug/L 50 49.7 99 57-125 Bromomethane ug/L 50 38.5 77 35-156 Carbon disulfide ug/L 100 93.0 93 47-141 Carbon tetrachloride ug/L 50 52.3 105 66-122 Chlorobenzene ug/L 50 52.3 105 71-126 Chloroethane ug/L 50 47.9 96 43-143 Chloroform ug/L 50 54.1 108 71-136 Chloromethane ug/L 50 48.7 97 47-123 cis-1,2-Dichloroethene ug/L 50 55.7 111 74-131 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 LABORATORY CONTROL SAMPLE: Parameter 176744 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 52.2 104 78-120 Dibromochloromethane ug/L 50 49.6 99 65-115 Dibromomethane ug/L 50 52.8 106 79-129 Ethylbenzene ug/L 50 53.5 107 68-129 lodomethane ug/L 100 100 100 49-154 Methylene Chloride ug/L 50 52.5 105 61-147 Styrene ug/L 50 60.1 120 77-128 Tetrachloroethene ug/L 50 55.4 111 51-139 Toluene ug/L 50 53.3 107 60-133 trans-1,2-Dichloroethene ug/L 50 57.1 114 69-144 trans- 1,3-Dichloropropene ug/L 50 48.6 97 74-128 trans-1,4-Dichloro-2-butene ug/L 100 90.0 90 61-139 Trichloroethene ug/L 50 51.4 103 73-126 Trichlorofluoromethane ug/L 50 49.1 98 55-132 Vinyl acetate ug/L 50 46.8 94 52-141 Vinyl chloride ug/L 50 51.7 103 50-133 Xylene (Total) ug/L 150 169 113 78-132 1,2-Dichloroethane-d4 (S) %. 104 81-119 4-Bromofluorobenzene (S) %. 109 82-120 Dibromofluoromethane (S) %. 108 82-114 Toluene-d8 (S) %. 106 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 176745 MS 2625249006 Spike Parameter Units Result Conc. MSD Spike Conc. 176746 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 0.5 0.5 58.8 57.1 11800 11400 68-137 3 11 M1 1,1,1-Trichloroethane ug/L ND 0.5 0.5 68.6 66.9 13700 13400 66-142 3 11 M1 1,1,2,2-Tetrachloroethane ug/L ND 0.5 0.5 66.0 66.0 13200 13200 39-171 0 13 M1 1,1,2-Trichloroethane ug/L ND 0.5 0.5 72.1 68.5 14400 13700 73-136 5 12 M1 1,1-Dichloroethane ug/L ND 0.5 0.5 76.6 72.3 15300 14500 66-155 6 15 M1 1,1-Dichloroethene ug/L ND 0.5 0.5 87.2 87.3 17400 17500 33-181 0 34 M1 1,2,3-Trichloropropane ug/L ND 0.5 0.5 51.3 49.9 10300 9980 78-133 3 14 M1 1,2-Dibromo-3- ug/L ND 0.5 0.5 57.5 58.6 11500 11700 58-124 2 15 M1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 0.5 0.5 65.9 63.6 13200 12700 71-134 4 12 M1 1,2-Dichlorobenzene ug/L ND 0.5 0.5 62.2 62.0 12400 12400 69-135 0 10 M1 1,2-Dichloroethane ug/L ND 0.5 0.5 65.0 62.9 13000 12600 36-159 3 10 M1 1,2-Dichloropropane ug/L ND 0.5 0.5 66.5 63.2 13300 12600 68-132 5 11 M1 1,4-Dichlorobenzene ug/L ND 0.5 0.5 60.6 60.8 12100 12200 49-153 0 9 M1 2-Butanone (MEK) ug/L ND 1 1 110 114 11000 11400 10-189 3 23 M1 2-Hexanone ug/L ND 1 1 90.8 89.4 9080 8940 40-135 2 18 M1 4-Methyl-2-pentanone ug/L ND 1 1 103 103 10300 10300 30-177 1 10 M1 (MIBK) Acetone ug/L ND 1 1 93.4 95.8 9340 9580 44-223 3 14 M1 Acrylonitrile ug/L ND 2 2 242 247 12100 12400 13-189 2 12 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 176745 MS 2625249006 Spike Parameter Units Result Conc. MSD Spike Conc. 176746 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L ND 0.5 0.5 69.3 66.3 13900 13300 66-139 4 10 M1 Bromochloromethane ug/L ND 0.5 0.5 73.0 68.6 14600 13700 73-133 6 13 M1 Bromodichloromethane ug/L ND 0.5 0.5 63.5 61.0 12700 12200 57-120 4 13 M1 Bromoform ug/L ND 0.5 0.5 54.2 53.0 10800 10600 48-128 2 13 M1 Bromomethane ug/L ND 0.5 0.5 37.6 42.3 7520 8450 10-187 12 32 M1 Carbon disulfide ug/L ND 1 1 126 125 12600 12500 47-141 1 322 M1 Carbon tetrachloride ug/L ND 0.5 0.5 76.3 73.8 15300 14800 58-127 3 14 M1 Chlorobenzene ug/L ND 0.5 0.5 65.8 61.6 13200 12300 63-137 7 10 M1 Chloroethane ug/L ND 0.5 0.5 60.5 57.7 12100 11500 52-146 5 16 M1 Chloroform ug/L ND 0.5 0.5 72.1 68.0 14400 13600 74-137 6 9 M1 Chloromethane ug/L ND 0.5 0.5 61.1 56.8 12200 11400 41-127 7 10 M1 cis-1,2-Dichloroethene ug/L ND 0.5 0.5 71.3 69.2 14300 13800 71-138 3 16 M1 cis-1,3-Dichloropropene ug/L ND 0.5 0.5 61.5 59.3 12300 11900 32-145 4 12 M1 Dibromochloromethane ug/L ND 0.5 0.5 58.8 56.5 11800 11300 52-116 4 13 M1 Dibromomethane ug/L ND 0.5 0.5 67.6 64.6 13500 12900 79-129 5 14 M1 Ethylbenzene ug/L ND 0.5 0.5 66.5 64.0 13300 12800 31-174 4 10 M1 lodomethane ug/L ND 1 1 130 129 13000 12900 49-154 0 30 M1 Methylene Chloride ug/L ND 0.5 0.5 68.0 67.3 13600 13500 61-146 1 15 M1 Styrene ug/L ND 0.5 0.5 71.2 67.5 14200 13500 77-128 5 14 M1 Tetrachloroethene ug/L ND 0.5 0.5 70.6 67.6 14100 13500 36-155 4 14 M1 Toluene ug/L ND 0.5 0.5 69.2 65.5 13800 13100 52-146 5 11 M1 trans-1,2-Dichloroethene ug/L ND 0.5 0.5 75.0 71.6 15000 14300 61-152 5 14 M1 trans-1,3-Dichloropropene ug/L ND 0.5 0.5 56.6 55.5 11300 11100 37-146 2 12 M1 trans-1,4-Dichloro-2-butene ug/L ND 1 1 89.1 88.7 8910 8870 61-139 0 12 M1 Trichloroethene ug/L ND 0.5 0.5 68.2 64.0 13600 12800 61-141 6 12 M1 Trichlorofluoromethane ug/L ND 0.5 0.5 73.3 72.4 14700 14500 51-141 1 13 M1 Vinyl acetate ug/L ND 0.5 0.5 42.9 43.2 8580 8650 52-141 1 14 M1 Vinyl chloride ug/L ND 0.5 0.5 67.2 63.8 13400 12800 22-156 5 26 M1 Xylene (Total) ug/L ND 1.5 1.5 206 196 13700 13100 78-132 5 7 MS 1,2-Dichloroethane-d4 (S) %. 105 105 81-119 4-Bromofluorobenzene (S) %. 102 106 82-120 Dibromofluoromethane (S) %. 108 111 82-114 Toluene-d8 (S) %. 107 107 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38920 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2625377001 METHOD BLANK: 176686 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 50000 50000 11/15/19 13:32 LABORATORY CONTROL SAMPLE: 176687 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 193000 97 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 176688 176689 MS MSD 2625508001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 311 mg/L 200000 200000 499000 494000 94 92 90-110 1 10 MATRIX SPIKE SAMPLE: 176690 2625428063 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 96.6 mg/L 200000 276000 89 90-110 M1 SAMPLE DUPLICATE: 176691 2625499002 Dup Max Parameter Units Result Result RPD RPD Qualifiers Chemical Oxygen Demand ug/L 65.0 mg/L 67100 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38838 Analysis Method: SM 4500-P QC Batch Method: SM 4500-P Analysis Description: 450OPE Total Phosphorus Associated Lab Samples: 2625377001 METHOD BLANK: 176330 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus ug/L ND 20.0 20.0 11/14/1919:35 LABORATORY CONTROL SAMPLE: 176331 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus ug/L 100 90.8 91 89-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 176332 176333 MS MSD 2625377001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 424 1000 1000 1200 1160 77 74 73-117 3 19 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38487 Analysis Method: SM 4500-P QC Batch Method: SM 4500-P Analysis Description: 450OPE Ortho Phosphorus Associated Lab Samples: 2625377001 METHOD BLANK: 174596 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Orthophosphate as P ug/L ND 20.0 20.0 11/08/19 11:37 LABORATORY CONTROL SAMPLE: 174597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Orthophosphate as P ug/L 500 441 88 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 174598 174599 MS MSD 2625315002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Orthophosphate as P ug/L ND 500 500 445 444 87 87 80-120 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38519 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2625377001 METHOD BLANK: 174831 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 11/13/19 14:23 1A LABORATORY CONTROL SAMPLE: 174833 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 184000 93 85-115 1A SAMPLE DUPLICATE: 174913 2625393001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 165 mg/L 167000 1 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38528 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2625377001 METHOD BLANK: 174899 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrate as N ug/L 12.OJ 50.0 5.0 11/09/19 06:34 LABORATORY CONTROL SAMPLE: 174900 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 10300 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 174901 174902 MS MSD 2625370001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L ND 10000 10000 10400 10400 104 104 90-110 0 15 H1 MATRIX SPIKE SAMPLE: 174903 2625370002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 0.10 mg/L 10000 10000 99 90-110 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: CMS Untreated Leachate Pace Project No.: 2625377 QC Batch: 38527 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2625377001 METHOD BLANK: 174891 Matrix: Water Associated Lab Samples: 2625377001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L 61.OJ 5000 17.0 11/09/19 06:34 LABORATORY CONTROL SAMPLE: 174892 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 10000 9850 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 174893 174894 MS MSD 2625370001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L ND 10000 10000 11900 11900 98 98 90-110 0 15 MATRIX SPIKE SAMPLE: 174895 2625370002 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Sulfate ug/L ND 10000 ND 0 90-110 M1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 27 Pace Analytical Services, LLC 110 Technology Parkway lCtaac, Analytrcal ePeachtree Corners, GA 30092 www.pacelabs.com (770)734-4200 QUALIFIERS Project: CMS Untreated Leachate Pace Project No.: 2625377 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. BATCH QUALIFIERS Batch: 38771 The calculated SCF was below the desired range of 0.6 tp 1.0 mg/L. All other indicators. including the LCS, were within acceptance criteria ANALYTE QUALIFIERS 1A The calculated SCF was below the desired range of 0.6 tp 1.0 mg/L. All other indicators. including the LCS, were within acceptance criteria B Analyte was detected in the associated method blank. H1 Analysis conducted outside the EPA method holding time. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 11 /26/2019 10:54 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 27 lceAnalyircal www.pacelabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: CMS Untreated Leachate Pace Project No.: 2625377 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 2625377001 Untreated Leachate 38875 2625377001 Untreated Leachate EPA 3005A 38953 EPA 6020B 2625377001 Untreated Leachate EPA 7470A 38630 EPA 7470A 2625377001 Untreated Leachate EPA 8260D 38927 2625377001 Untreated Leachate EPA 410.4 38920 EPA 410.4 2625377001 Untreated Leachate SM 4500-P 38838 SM 4500-P 2625377001 Untreated Leachate SM 4500-P 38487 2625377001 Untreated Leachate SM 5210B 38519 SM 5210B 2625377001 Untreated Leachate EPA 9056A 38528 2625377001 Untreated Leachate EPA 9056A 38527 Date: 11/26/2019 10:54 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Batch 38996 38698 38925 38849 38771 Page 22 of 27 A to ITEM 0 ?! w e m a •4 m o, 3 C � E �v • m v m se ; �` MATRIX CODE (—,AM codes to Ism SAMPLE TYPE (G-GRAB C•COMP) 3 rh Np 0 G m SL $ m z o m TEMP AT COLLECTION PSAMPLE 0 m a Of CONTAINERS UnMmwved .0 10 I H2SO4 IF ; _ MN03 HCI 12 NaOH Na2S203 � Methanol 3 � i DOW Analyses Test YM x VOC sm �i x Iaelab Z x SOD. NO3, SO4 OMro phosphate x COD Phosphms 1 x PH SC, Tamp ip i TEMP in C Reedua! Chlorine (YlN) Raosivad on 100 (YIN) Sealed C00w Y!N Samples Intact (Y/NI R J 0 p� o p �ssa • r 1 1 ~_ N s� Page 23 of 27 INFORMATION SHEET SCHEDULE: April, Oct CLIENT NAME: BFI Waste Systems of North America, LLC CLIENT ADDRESS: 5105-A Morehead Rd. Concord NC CLIENT PHONE: 704-400-6557 CLIENT CONTACT: Mr. Mike Gurley PROJECT NAME: UNTREATED LEACHATE WW MONITORING EQUIPMENT NEEDED: NOTES: ICE, pH METER, Grab Jar Get with Tony Reiss if you need help pulling sample. Check in at the Administration Building SAMPLERS)/DATE(S): Page 1 of 2 Page 24 of 27 i r m � m r 3 O 0 Z W O m ro °° o �c o Q 2 m O O m _a In Og� fAO� a ro as ME n H � 'D n r n tOr�m 0 m' 00 Page 25 of 27 Sampl LZ -Conditionaa wog . 2625377J0 9Zwd An cal Client Name: PM: BM Due Date: 11/25/19 CLIENT: Renublie—NC Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial ❑ Pace Othe Tracking #: Custody Seal on CoolerlBox Present: ❑ yes ❑ na Seals Intact: ❑ yes Packing Material: ❑ Bubble Wrap ❑Bubble Bags ❑ Nonf El Other n SamrAm nn icA Molina aracess has begun Cooler Temperature U- Biological Tissue Is Frozen: Yes No Date and Initials of person examining contents: Temp should be above freezing to B°C Comments: Chain of Custody Present: ONO ❑NIA 1. Chain of Custody Filled Out: ZYA ONO ❑NIA 2. Chain of Cus Relin uished: Y ❑No ❑NIA 3, Sampler Name & Signature on COC: DOW. ONO ❑NIA 4. Samples Arrived within Hold Time: Y ONO ❑NIA 5. Short !gold Time Analysis <72hr : es ONI.V ❑NIA 6. Rush Turn Around Time Requested:— ❑Y o ❑NIA 7. Sufficient Volume: Yes ON. ❑wA 8. ` Correct Containers Used: Z11❑No ❑NIA g. -Pace Containers Used: No ❑NIA Containers Intact: Yss ON, ONIX 10. Filtered volume received for Dissolved tests 0 YO ❑Nc N/A 11. Sample Labels match COC: � ❑No ❑NIA 12. -Includes date/time/IEWAnal is Matrix: All containers needing preservation have been checked. Y ON a ❑NIA 13. All containers needing preservation are found to be in I�Yes ❑Nc ONIA Compliance with EPA recommendation Initial when Lot # of added exceptions: VOA, cofdonm, TOC, 0&G, WI-DRO (water) Yes ONO completed preservative Samples checked for dechlorination: ❑Yes ❑No N/A 14, Heads ace in VOA Vials >6mm): ❑Yes a 4, ZA 15. Trip Blank Present: ❑Yes ❑No 16, Z/A Trip Blank Custody Seals Present ❑Yes ❑No Ab Pace Trip Blank Lot # if purchased): Client Notification! Resolution: Field Data Required? Y I N Person Contacted: Datell-ime: Comments/ Resolution: 3000 W28 Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) F-ALLCO03rev.3, 11Seplember2006 ti Q ¢ zz zzz C C O O •Y U ° W Q% cd co a.. ° 4. o C U o o N N� E as ¢ Q zz Y AO 03 c •� �w Y c o Ca co 0. 0 ) Y n w 3 3oF°- 0 7 � S r (•�' v' N a _ o 0 E w � E co CL d. cd O F= a cn 3 d 0, cc a Y Ll Page 27 of 27