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HomeMy WebLinkAbout4501_Henderson_MSWLF_CDLF_GW_FID1387782_20200117dENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #. NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Golder Associates NC, Inc. on behalf of Henderson County Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: David Y. Reedy II Phone: 336-852-4903 E-mail: dreedy@golder.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Henderson County Closed Landfill 191 Transfer Station Drive 45-01 .1600/.0500 September 18 - 19, 2019 Hendersonville, NC 28791 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑X Leachate monitoring data ❑ Surface water monitoring data Methane gas monitoring data Corrective action data (specify) MNA Monito Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. David Y. Reedy II, PG Senior Hydrogeologist 336-852-4903 Facility R tive Name (Print) Title / - /_) - Zv a-0 Signature Date Golder Associates NC, Inc., 5B Oak Branch Drive, Greensboro, NC 27407 Facility Representative Address C-2862 NIC PE Firm License Number (if applicable effective May 1, 2009) Po-4 R»nna (Area Code) Te lone Number,,.,., Affix NC Seal GOLDER REPORT Second Semi -Annual 2019 Water Quality and Corrective Action Monitoring Report 2019 Closed Henderson County Landfill, Permit No. 45-01 Submitted to: Henderson County Solid Waste Division 191 Transfer Station Drive Stoney Mountain Drive Hendersonville, North Carolina 28791 Submitted by: Golder Associates NC, Inc. 5B Oak Branch Drive, Greensboro, North Carolina, USA 27407 +1 336 852-4903 19128179.101 January 17, 2020 January 17, 2020 Distribution List iKIPMM11IIII Jaclynne Drummond, Hydrogeologist, Department of Environmental Quality, Division of Waste Management — Solid Waste Section, 2090 US Highway 70, Swannanoa, NC 28778. 828-296-4706. jaclynne.drummond@ncdenr.gov Marcus Jones, PE, Director of Engineering, Henderson County, 1 Historic Courthouse Square, Suite 6, Hendersonville, NC 28792. 828-694-6560. majones@hendersoncountync.org (electronic copy) Greg Wiggins, Manager, Solid Waste Department, 191 Transfer Station Drive, Hendersonville, NC 28791. 828-694-7982 gwiggins@hendersoncountync.org ,> GOLDER January 17, 2020 19128179.101 Executive Summary On behalf of Henderson County, Golder Associates NC, Inc. (Golder) is submitting this Water Quality Monitoring Report, which documents the results of the compliance monitoring and corrective action monitoring results from the September 18 - 19, 2019, groundwater and surface water sampling and analysis event. At the closed MSW facility, no NC Appendix I inorganic constituents were detected at quantifiable concentrations that exceed the applicable groundwater standards in samples from downgradient wells during the September 2019 event. Cobalt and thallium were detected at estimated concentrations above their respective NC 2L Interim Maximum Allowable Concentrations (IMACs) in the samples from MW-7, MW-8, and AMW-1 S. Per 15A NCAC 02L .0202 (b)(1), "where the standard (i.e., the NC 2L Standard) for a substance is less than the practical quantitation limit (PQL), the detection of that substance at or above the PQL constitutes a violation of the standard." The groundwater standard for cobalt is 1 micrograms per liter (ug/L) and the PQL for cobalt is 10 ug/L. The groundwater standard for thallium is 0.2 ug/L and the PQL for thallium is 2 ug/L. As presented, during the 2019 second semi-annual water quality monitoring event, the cobalt and thallium concentrations mentioned above were reported below the PQL and are considered estimated. There are currently insufficient background data from upgradient well MW-5 with turbidity measurement less than 10 Nephelometric Turbidity Units (NTUs) to establish background concentrations utilizing statistical methods. After approximately one year of routine semi-annual monitoring, a sufficient number of background data should be acquired and will be utilized to further evaluate this concentration. A desktop study of the prevalence of cobalt and thallium in soil and sediment in the general proximity of the Henderson County MSW Landfill shows that cobalt and thallium occur naturally in stream sediment and is likely to occur in subsurface soil at the Henderson County MSW Landfill at concentrations that would account for the concentrations of these constituents in groundwater. At the closed MSW facility, two NC Appendix I VOCs (benzene and 1,4-dichlorobenzene) were detected at quantifiable concentrations that exceeded the respective NC 2L Standards in the samples from one or more downgradient monitoring wells at the MSW landfill during the September 2019 event. Constituent 1,4-dioxane was detected at quantifiable concentrations above the NC 2L Standard in samples from one or more downgradient monitoring wells at the MSW landfill during the September 2019 event. 1,4-dioxane was analyzed per the May 29, 2018, memorandum from the NC Department of Environmental Quality (DEQ). At the closed C&D facility, one inorganic constituent (cobalt) was reported at a concentration that exceeds the PQL and groundwater protection standard in the samples from MW-11. The concentration of cobalt in the sample from MW-11 was determined to exceed the statistically calculated background concentration during this event. The concentration of cobalt from the sample from MW-11 is more than two times higher than recent concentrations and is considered suspect. The concentration will be confirmed during the first semi- annual monitoring event of 2020. The indicator parameter iron was reported at quantifiable concentrations above the NC 2L Standard in samples from downgradient monitoring wells MW-11 and MW-13. The indicator parameter manganese was reported at concentrations above the NC 2L Standard in samples from downgradient monitoring wells MW-11, MW-12, and MW-13. The concentration of iron in the sample from MW-13 was determined to be below the statistically calculated background concentration during this event, and therefore; no further action is recommended. The concentration of iron in the sample from MW-11 was determined to be above the statistically calculated background concentration during this event. Iron was reported at a concentration nearly two times higher than recent events and is considered suspect. The concentration will be confirmed during the first semi-annual monitoring event of 2020. ,> GOLDER January 17, 2020 19128179.101 There are currently insufficient background data from upgradient well MW-10 with turbidity measurements less than 10 NTUs to establish background concentrations utilizing statistical methods for manganese. Within approximately one year of routine semi-annual monitoring, a sufficient number of background data should be acquired to further evaluate these concentrations. The USGS National Geochemical Survey Database indicates that concentrations of cobalt, iron, and manganese in stream sediment samples within 25 miles of the facility could account for the concentrations detected in groundwater samples from the C&D monitoring wells. At the C&D facility, one NC Appendix I VOC, vinyl chloride, was detected at quantifiable concentrations above the NC 2L Standard in samples from downgradient wells MW-12 and MW-13 during the September 2019 event. Constituent 1,4-dioxane was detected at a quantifiable concentration above the NC 2L Standard in the sample from MW-12. On September 28, 2010, the County submitted an Alternate Source Demonstration (ASD) to NC DEQ in response to VOC concentrations detected in samples from the closed C&D landfill downgradient monitoring wells. Based on the data and evaluations from the ASD, it was apparent that leachate from the C&D disposal unit is not the likely source of the VOC concentrations. Additionally, the data suggest that the source of the VOCs in samples from the monitoring wells is most likely landfill gas. No NC Appendix I constituents were detected at concentrations above applicable surface water standards in the samples from surface water monitoring points during the September 2019 event. Constituent 1,4-dioxane was detected at quantifiable concentrations above the applicable surface water standard in the samples from BR-1, BR-2 and SW-1 and at estimated concentrations above the applicable surface water standard in the sample from BR-3. Based on these results, the County will continue the implementation of groundwater corrective action at the MSW landfill for the unconsolidated aquifer in accordance with the approved Corrective Action Plan. Also based on the results, the County will continue monitoring the C&D landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.0545. The next compliance monitoring event for this facility is scheduled for March 2020. ,> GOLDER January 17, 2020 19128179.101 Table of Contents 1.0 INTRODUCTION.........................................................................................................................................1 1.1 Site Description and Background......................................................................................................1 1.2 Compliance Monitoring History.........................................................................................................1 1.2.1 Closed MSW Landfill.....................................................................................................................1 1.2.2 Closed C&D Landfill......................................................................................................................2 1.3 Hydrogeologic Setting.......................................................................................................................3 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION .........................................................4 2.1 Visual Inspection Program................................................................................................................4 2.2 Well Network and Groundwater Elevation Measurements...............................................................4 2.2.1 Closed MSW Landfill 2.2.2 Closed C&D Landfill 2.2.3 Groundwater Elevation Measurements .4 4 .4 2.3 September 2019 Groundwater and Surface Water Monitoring Event..............................................5 2.4 Laboratory Analysis Program............................................................................................................5 2.4.1 Closed MSW Landfill Compliance Monitoring...............................................................................5 2.4.2 Closed C&D Landfill Compliance Monitoring................................................................................6 2.4.3 Closed MSW Landfill Corrective Action Monitoring......................................................................6 3.0 LABORATORY AND FIELD QA/QC..........................................................................................................6 4.0 DATA EVALUATION..................................................................................................................................6 4.1 North Carolina Groundwater and Surface Water Quality Standard Comparisons for the Closed MSWLandfill.....................................................................................................................................6 4.2 North Carolina Groundwater Standard Comparisons for the Closed C&D Landfill ..........................7 5.0 CORRECTIVE ACTION PERFORMANCE MONITORING........................................................................8 5.1 Monitored Natural Attenuation..........................................................................................................8 5.1.1 Monitored Natural Attenuation Sampling Results.........................................................................8 5.1.2 Monitored Natural Attenuation Sampling Evaluation....................................................................9 6.0 CONCLUSIONS........................................................................................................................................10 7.0 REFERENCES..........................................................................................................................................10 GOLDER iv January 17, 2020 TABLES Table 1 Summary of Historical Static Water Level Data Table 2 Summary of Estimated Horizontal Flow Velocities Table 3 Summary of Well Construction Information Table 4 Summary of Detected Constituents in MSW Monitoring Wells Table 5 Summary of Field Parameters for MSW Monitoring Wells Table 6 Summary of Detected Constituents in Surface Water Monitoring Points Table 7 Summary of Field Parameters for Surface Water Monitoring Points Table 8 Summary of Detected Constituents in C&D Monitoring Wells Table 9 Summary of Field Parameters for C&D Monitoring Wells Table 10 Summary of Geochemical Indicators Table 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points FIGURES Figure 1 Groundwater Surface Contour Map, September 19, 2019 APPENDICES 19128179.101 Appendix A Groundwater and Surface Water Sampling Logs Appendix B September 2019 Groundwater and Surface Water Certificate -of -Analysis, Chain -of -Custody Forms and Laboratory Data Review Appendix C USGS National Geochemical Survey Database Summary Appendix D Statistical Evaluation Worksheets & Summary Table Appendix E EPA Natural Attenuation Screening Protocol Forms and BIOCHLOR Monitored Natural Attenuation Analysis for September 2019 Sampling Event 4 GOLDER v January 17, 2020 19128179.101 1.0 INTRODUCTION This report summarizes the monitoring results from the September 18 - 19, 2019, groundwater and surface water sampling and analysis event at the closed Henderson County Landfill in Henderson County, North Carolina in accordance with Title 15A of the North Carolina Administrative Code (NCAC) Subchapter 1313.1632 and NCAC Subchapter 1313.0544. The Henderson County Landfill, which consists of a closed municipal solid waste (MSW) and a closed construction and demolition (C&D) landfill, is maintained by the County under Permit No. 45-01 issued by the NC Department of Environment Quality (DEQ, formerly Department of Environment and Natural Resources). 1.1 Site Description and Background The location of the facility is shown on the inlay on Figure 1. As presented, the closed Henderson County Landfill is located approximately three miles northwest of the city of Hendersonville, off Stoney Mountain Road. The County maintains an approximately 120-acre landfill facility that consists of a closed, unlined C&D over MSW facility; a closed, unlined C&D facility; a closed, unlined facility formerly operated by the Tennessee Valley Authority (TVA); an active transfer station, and a customer convenience center. A white goods area, a yard waste disposal area, and a beneficial reuse area are also present on the property. Unpermitted waste was discovered along the eastern portion of the southern property boundary in 2011, during the construction of a road to the customer convenience center. The waste, which appears to consist of mainly C&D material, extends off -site to an adjacent parcel. The MSW facility is subject to Assessment Monitoring in accordance with .1634 of the Solid Waste Management Rules (SWMR) and the Transition Plan for the facility. The C&D facility is subject to water quality monitoring in accordance with the January 1, 2007, revision to the C&D Rules (.0544 of the SWMR) and is currently in Assessment Monitoring. Water quality monitoring is also required for the TVA landfill. The facility has been in operation since the 1940s, beginning with the TVA landfill. In January 1998, the MSW facility ceased accepting MSW waste and began placing C&D waste over the MSW waste. After closure of the C&D-over-MSW area, a new C&D landfill began operation on the southeastern portion of the facility property. The C&D-over-MSW area was capped with a modified clay cap. The County ceased accepting waste at the stand-alone C&D landfill on June 30, 2008 and completed closure activities on June 30, 2009. The landfill is bounded to the north and east by residential and undeveloped wooded properties, to the south by Stoney Mountain Road and residential and wooded properties, and to the west by a tributary of Mill Pond Creek, a NC Department of Transportation maintenance yard, and a Henderson County School bus maintenance facility. Topographic relief at the landfill ranges from approximately 2170 to 2590 feet above mean sea level. Surface drainage from the facility is predominantly to the southwest toward several streams along the western and southern portions of the property. These features drain into Mill Pond Creek located southwest of the landfill. 1.2 Compliance Monitoring History The following sections summarize the compliance monitoring histories of the closed MSW landfill, the closed C&D landfill, and the closed TVA landfill. 1.2.1 Closed MSW Landfill Henderson County monitors water quality at the closed MSW landfill by sampling one upgradient background monitoring well (MW-5), and three downgradient monitoring wells (MW-6, MW-7, and MW-8) semi-annually. Samples from the wells have historically been analyzed for the NC Appendix II list for the first semi-annual event and the NC Appendix I list plus mercury during the second semi-annual event. Two assessment monitoring wells (AMW-1 S and AMW-1 D) have also been monitored semi-annually since April 2002. Samples ,> GOLDER January 17, 2020 19128179.101 from the assessment wells have historically been analyzed for the NC Appendix I list plus mercury during each semi-annual event. Based on the documented volatile organic compound (VOC) exceedances of applicable groundwater standards, the County submitted an Additional Groundwater Assessment Proposed Work Plan to NC DEQ on September 26, 2008. NC DEQ approved the Work Plan on April 17, 2008, and the County submitted the Assessment Report on June 3, 2008. As part of the Assessment Report, assessment monitoring wells AMW-2S and AMW-2D were installed to further delineate the VOC plume. As part of this submittal, Camp Dresser & McKee (CDM) recommended that AMW-2S and AMW-2D continue to be sampled semi-annually. On September 17, 2009, representatives of the County and Golder met with NC DEQ and submitted a Groundwater Assessment Work Plan to NC DEQ to address continued assessment activities at the MSW and C&D facilities. During the meeting, it was verbally agreed that TVA well MW-9 would no longer be sampled and would remain for water level collection, and wells AMW-1 S, AMW-1 D, AMW-2S, and AMW-2D would be sampled for NC Appendix I constituents plus mercury. Follow-up emails were received on September 18, 2009, regarding approval to discontinue monitoring MW-9, and on February 2, 2010, regarding approval of reduced analytical parameters for the four assessment monitoring wells. In a letter to the County dated May 12, 2011, NC DEQ requested that MW-9 be sampled on an annual basis for NC Appendix I constituents to monitor the closed TVA landfill; currently the well is sampled during each of the first semi-annual compliance events. In July 2012, Henderson County submitted a Nature and Extent Study (NES) to the NC DEQ with the purpose of delineating the vertical and horizontal extent of those constituents identified in the groundwater samples at concentrations that exceed their respective groundwater standards. The NC DEQ granted approval of the NES on October 18, 2012. The October 18, 2012, approval letter of the NES requires the County to initiate an Assessment of Corrective Measures (ACM) per the NCAC 15A NCAC 13B.1635 of the NC Solid Waste Management Rules. An ACM was submitted to the NC DEQ on April 15, 2013. The ACM was approved by NC DEQ on May 22, 2013, and the County held a public hearing to discuss the ACM and potential remedies for the site on August 15, 2013. A Corrective Action Plan (CAP) was submitted to the NC DEQ on June 24, 2015, and was approved on July 13, 2015. As specified in the CAP, monitored natural attenuation (MNA) was implemented as the corrective action along with a super aerated water (SAW) pilot test in the southwestern portion of the facility. A Corrective Action Evaluation Report (CAER) for the SAW pilot test was submitted to the NC DEQ on October 25, 2019. The CAER proposed that methylene chloride be removed as a constituent of concern (COC) and that SAW injections cease unless VOCs are detected above the NC 2L Standard in samples from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. The CAER was approved by the NC DEQ on November 5, 2019. Four downstream surface water monitoring points, BR-1, BR-2, BR-3, and SW-1, have been monitored semi-annually for NC Appendix I parameters. 1.2.2 Closed C&D Landfill The County monitors water quality at the C&D facility by sampling one upgradient monitoring well (MW-10), and three downgradient monitoring wells (MW-11, MW-12, and MW-13) semi-annually. Samples from the wells have been analyzed for the NC Appendix I list plus mercury and indicator parameters. On September 28, 2010, the County submitted an Alternate Source Demonstration (ASD) to NC DEQ in response to VOC concentrations detected in samples from the closed C&D landfill downgradient monitoring wells. Based on the data and evaluations from the ASD, it was apparent that leachate from the C&D disposal unit is not the likely source of the VOC concentrations. Additionally, the data suggest that the source of the VOCs in samples from the monitoring wells is most likely landfill gas. On May 12, 2011, NC DEQ issued a letter to the County ,> GOLDER January 17, 2020 19128179.101 to initiate an Assessment Monitoring Program at the C&D facility. The County submitted an Assessment Monitoring Work Plan to NC DEQ on September 21, 2011 and sampled the C&D landfill monitoring wells for the NC Appendix II list of constituents during the September 2011. Prior to the September 2012 compliance monitoring event, NC DEQ allowed the County to sample the C&D wells for the NC Appendix I list of constituents plus 2,4-D after conducting two baseline NC Appendix II sampling events. 1.3 Hydrogeologic Setting Geologically, the facility is located within the Chauga Belt of the Blue Ridge Physiographic Province of NC (NCGS, 1985 and 2004). The Chauga Belt is comprised of Cambrian intrusive metamorphic rocks of monzonitic to granodioritic origin. The Chauga Belt is considered a low-grade metamorphic part of the Inner Piedmont Belt and is bordered to the west by the Brevard thrust fault zone. The facility is underlain primarily by the Henderson Gneiss which is a medium -gray, biotite granite augen composed of microcline, oligoclase, quartz, biotite, and minor amounts of muscovite, epidote, and titanite (Butler and Secor, 1991). The topography of the area is characterized by rolling, rounded hills with broad valleys and moderately steep ravines typically containing streams. The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of partially weathered, fractured, metamorphic intrusive rock. Topographic relief at the site ranges from an elevation of approximately 2590 feet above mean sea level (AMSL) along the eastern property boundary and slopes downward to the southwest to an approximate elevation of 2170 feet AMSL along the western property boundary. As a result of the varying topographic relief at the site, groundwater occurs at depths of ranging from approximately 6 to 55 feet below grade. Depth -to -water measurements obtained during the September 2019 monitoring event are summarized in Table 1 and were used to prepare a groundwater surface contour map presented as an overlay on Figure 1. As presented, the groundwater flow in the uppermost aquifer beneath the site is generally toward the southwest toward a tributary of Mill Pond Creek, which is located along the western property boundary of the site. The groundwater contour map and interpreted flow directions are generally consistent with previously submitted groundwater contour maps and flow directions. Based on the September 2019 groundwater surface contour map, the average hydraulic gradient in the shallow aquifer underlying the MSW landfill was calculated to be approximately 0.09 foot/foot (Table 2). The hydraulic gradient underlying the C&D landfill was calculated to be approximately 0.27 foot/foot (Table 2). A hydraulic conductivity of 1.26E-04 centimeters/second is used based on an average of previous hydraulic conductivities calculated for specific wells (CDM, October 2008). An estimated effective porosity of 0.15 was used for the shallow aquifer to represent a range from saprolite to fractured rock (CDM, December 2008). Using the above values, the estimated rate of groundwater flow for the uppermost aquifer beneath the facility was calculated using the following modified Darcy equation: Vgw = Ki/ne where Vgw = average linear velocity (feet/year), K = hydraulic conductivity (feet/year), i = horizontal hydraulic gradient, and ne = effective porosity. The average estimated linear groundwater flow velocity under the MSW landfill is approximately 74 feet/year, which is generally consistent with previous estimates (Table 2). The average estimated linear groundwater flow velocity under the C&D landfill is approximately 232 feet/year (Table 2). The range of groundwater flow is expected to vary depending on the hydrogeologic unit in which it occurs. However, the linear velocity equation above makes the simplified assumptions of a homogeneous and isotropic aquifer. Therefore, this > GOLDER January 17, 2020 19128179.101 equation represents a likely average value for the uppermost aquifer and does not account for heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. 2.0 FIELD PROGRAM, MONITORING RESULTS, AND DISCUSSION Field activities conducted for the September 2019 sampling events are discussed in the following sections. 2.1 Visual Inspection Program In order to detect a potential release at the earliest possible time, the visual inspection program is used by sampling personnel at the closed Henderson County Landfill. This program includes physical indicators such as potential water table mounding beneath the waste management unit, physical examination of any stresses in biological communities, visible signs of Ieachate migration (i.e., leachate seeps), unexplained changes in soil characteristics, and any other change to the environment due to the waste management unit. During the compliance monitoring event, no physical indicators of a potential release were observed in the vicinity of the waste management area. 2.2 Well Network and Groundwater Elevation Measurements The following sections summarize the water quality networks and groundwater elevation measurements for the closed MSW landfill, the closed C&D landfill, and the closed TVA landfill. 2.2.1 Closed MSW Landfill The network of groundwater monitoring wells at the closed Henderson County MSW landfill consists of one upgradient monitoring well (MW-5) and three downgradient monitoring wells (MW-6, MW-7, and MW-8). Four assessment monitoring wells (AMW-1 S, AMW-1 D, AMW-2S, and AMW-2D) are also monitored during each semi-annual monitoring event. Four surface water monitoring points (BR-1, BR-2, BR-3, and SW-1) are monitored semi-annually. Monitoring well and surface water point locations are shown on Figure 1. Compliance wells MW-5, MW-6, MW-7, and MW-8; assessment wells AMW-1 S and AMW-2S; and corrective action monitoring well Old MW-2 are also sampled semi-annually as part of the MNA corrective action. Monitoring wells MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 are screened in the shallow, unconfined aquifer. Monitoring wells AMW-1 D and AMW-2D are screened in fractured bedrock. Available groundwater monitoring well construction information is summarized in Table 3. TVA Well MW-9 is sampled annually (first semi-annual event) to monitor groundwater downgradient of the closed TVA landfill. The well is screened in the shallow, unconfined aquifer. 2.2.2 Closed C&D Landfill The network of groundwater monitoring wells at the closed C&D landfill consists of one upgradient monitoring well (MW-10), and three downgradient monitoring wells (MW-11, MW-12, and MW-13). Downgradient monitoring wells MW-10, MW-11, and MW-12 are screened in the shallow, unconfined aquifer. Monitoring well MW-13 is screened in fractured bedrock. The four wells are screened to target the preferential flow path for groundwater underlying the closed C&D waste disposal areas. 2.2.3 Groundwater Elevation Measurements Depth -to -water measurements were recorded to the nearest 0.01 foot prior to initiating groundwater purging and sampling activities. A summary of the current and available historical water level elevations is presented in Table 1. As presented, the data indicate that the hydraulic head level in the uppermost aquifer beneath the facility is fairly consistent, with temporal variation from the long-term average ranging from approximately 2 to 12 feet (plus or minus). As expected, the range in fluctuation is greatest in the upgradient wells MW-5 and MW-10, as > GOLDER January 17, 2020 19128179.101 these wells are located in groundwater recharge areas. The range of fluctuation in downgradient compliance wells, which are located closer to groundwater discharge areas, is less, presumably due to the stabilizing effect of the hydraulic discharge boundary. 2.3 September 2019 Groundwater and Surface Water Monitoring Event Personnel from Golder visited the facility on September 18-19, 2019, to purge and sample the 12 monitoring wells (Old MW-2, MW-5, MW-6, MW-7, MW-8, MW-10, MW-12, MW-13, AMW-1S, AMW-1D, AMW-2S, and AMW-2D) at the closed MSW and C&D landfills and to sample four surface water monitoring points (BR-1, BR-2, BR-3, and SW-1). All monitoring wells were purged and sampled using dedicated bladder pumps and low flow techniques. Measurements of pH, specific conductivity, turbidity, dissolved oxygen, temperature, and oxidation reduction potential were recorded after each system volume collected during the purge with field -calibrated instruments to monitor for stabilization of water quality. The purge rate was matched to the yield of the monitoring well, as determined by continuously monitoring the depth to water, up to a maximum purge rate of 400 milliliters per minute. Purging was continued until stabilization was indicated by the field parameters. The groundwater samples were collected directly from the bladder pump discharge line in the labelled, laboratory -supplied, pre -preserved sample containers after purging was completed. Each sample container was labelled with the sample identification number, sampling personnel, date and time of sample collection, project name and number, and requested chemical analyses. The surface water samples were collected by lowering the sample containers into the stream flow with the opening facing away from the current flow, taking care to prevent the overflow of the sample containers and to minimize sample -induced turbidity. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded during the collection of the surface water samples. After collection, the samples were placed in a cooler on ice, under chain -of -custody control. Copies of the sampling logs are presented in Appendix A. Included in each log is a description of the sampling equipment, sampling location, sampling method, field observations, and water quality measurements. 2.4 Laboratory Analysis Program The September 2019 groundwater and surface water samples were shipped to Environmental Conservation Laboratories, Inc. (ENCO) of Cary, NC under chain -of -custody control. The samples were received at the laboratory September 20, 2019, in good condition and properly preserved. Additional groundwater samples were shipped to Pace Analytical Energy Services, LLC (Pace) of Pittsburgh, Pennsylvania under chain -of -custody control. The samples were received at the laboratory on September 19, 2019, in good condition and properly preserved. Groundwater samples from MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S, and Old MW-2 were analyzed for ferrous iron and hydrogen by Pace. 2.4.1 Closed MSW Landfill Compliance Monitoring Groundwater samples from the compliance MSW wells and the assessment wells were analyzed for the NC Appendix I list of constituents plus mercury. Surface water samples BR-1, BR-2, BR-3, and SW-1, were analyzed for the NC Appendix I list of constituents. Samples were also analyzed for 1,4-dioxane per the May 29, 2018, NC DEQ memorandum. ,> GOLDER January 17, 2020 19128179.101 2.4.2 Closed C&D Landfill Compliance Monitoring Groundwater samples from the closed C&D facility were analyzed for the NC Appendix I list of constituents, 2,4-D, tetrahydrofuran, and indicator parameters specified in Title 15A NCAC 1313.0566. Samples were also analyzed for 1,4-dioxane per the May 29, 2018, NC DEQ memorandum. 2.4.3 Closed MSW Landfill Corrective Action Monitoring Groundwater samples from the MNA evaluation wells MW-5, MW-6, MW-7, MW-8, AMW-1S, AMW-2S, and Old MW-2 were analyzed for MNA parameters, which include nitrate, nitrite, ferrous iron, sulfate, sulfide, alkalinity, chloride, methane, ethane, ethene, carbon dioxide, biochemical oxygen demand, chemical oxygen demand, total organic carbon, and hydrogen. The sample from Old MW-2 was also analyzed for the constituents -of -concern (COCs) from the CAP, which include benzene; 1,4-dichlorobenzene; 1,1-dichloroethane; tetrachloroethene; trichloroethene; and vinyl chloride. 3.0 LABORATORY AND FIELD QA/QC A field blank was collected by Golder personnel as part of the September 2019 groundwater and surface water sampling event. In addition to the field blank, laboratory -prepared trip blanks accompanied the volatile sample containers for the September 2019 sampling event to and from the laboratory. ENCO analyzed the field blank for the NC Appendix I list of parameters plus mercury, iron; manganese; 1,4-dioxane, and tetrahydrofuran. The trip blanks were analyzed for NC Appendix I and/or tetrahydrofuran. Reviews of the laboratory data were performed by Golder (Appendix B). Based on Golder's review of the laboratory data, estimated concentrations of barium, copper, iron, and manganese were detected in the field blank. The following detections are considered blank -qualified: barium in the samples from MW-10, MW-13, AMW-1 D, AMW-2S, and AMW-1 D and copper in the samples from MW-5, MW-6, AMW-1 S, AMW-1 D, BR-3, and SW-1. 4.0 DATA EVALUATION The results of the data evaluations are presented in the following sections. North Carolina Groundwater and Surface Water Quality Standard Comparisons for the Closed MSW Landfill As presented in Table 4, no NC Appendix I inorganic constituents were detected at quantifiable concentrations that exceed the applicable groundwater standards in samples from downgradient wells during the September 2019 event. Cobalt and vanadium were detected at estimated concentrations above their respective NC 2L Interim Maximum Allowable Concentrations (IMACs) in the samples from MW-7, MW-8, and AMW-1 S. Per 15A NCAC 02L .0202 (b)(1), "where the standard (i.e., the NC 2L Standard) for a substance is less than the practical quantitation limit (PQL), the detection of that substance at or above the PQL constitutes a violation of the standard." The groundwater standard for cobalt is 1 micrograms per liter (ug/L) and the PQL for cobalt is 10 ug/L. The groundwater standard for thallium is 0.2 ug/L and the PQL for thallium is 2 ug/L. As presented, during the 2019 second semi-annual water quality monitoring event, the cobalt and thallium concentrations mentioned above were reported below the PQL and are considered estimated. There are currently insufficient background data from upgradient well MW-5 with turbidity measurement less than 10 Nephelometric Turbidity Units (NTUs) to establish background concentrations utilizing statistical methods. In one year of routine semi-annual monitoring, a sufficient number of background data should be acquired and will be utilized to further evaluate this concentration. A desktop study of the prevalence of barium, cadmium, cobalt, and thallium in soil and sediment in the general proximity of the Henderson County MSW Landfill shows that cobalt, and thallium occur naturally in stream sediment and is likely to occur in ,> GOLDER January 17, 2020 19128179.101 subsurface soil at the Henderson County MSW Landfill at concentrations that would account for the concentrations of these constituents in groundwater (Appendix C). As presented on Table 4, two NC Appendix I VOCs (benzene and 1,4-dichlorobenzene) were detected at quantifiable concentrations that exceeded the respective NC 2L Standards in the sample from downgradient monitoring well MW-6 at the MSW landfill during the September 2019 event. 1,4-dichlorobenzene was also detected at a quantifiable concentration above NC 2L in monitoring well MW-7. The constituent 1,4-dioxane was detected at quantifiable concentrations above the NC 2L Standard in samples from MW-6, MW-7, and AMW-1 D. This constituent was analyzed per the May 29, 2018, NC DEQ memorandum for all permitted landfills; this constituent is not required by regulation or the facility permit. The concentrations of 1,4-dioxane can be affected by seasonality and currently with limited data, will continue to be evaluated. 1,4-Dioxane was analyzed per the May 29, 2018, memorandum from the NC Department of Environmental Quality (DEQ). As presented in Table 6, no NC Appendix I constituents were detected at concentrations above applicable surface water standards in the samples from surface water monitoring points during the September 2019 event. Constituent 1,4-dioxane was detected at a quantifiable concentration above the applicable surface water standard in the samples from BR-1, BR-2, and SW-1 and was detected at an estimated concentration above the applicable surface water standard in the sample from BR-3. 1,4-dioxane was analyzed per the May 29, 2018, NC DEQ memorandum; this constituent is not required by regulation or the facility permit. 4.2 North Carolina Groundwater Standard Comparisons for the Closed C&D Landfill As presented in Table 8, one NC Appendix I inorganic constituent was reported in samples collected from monitoring wells at quantifiable concentrations that exceeded applicable groundwater standards at the C&D landfill during the September 2019 event. Cobalt was reported at concentrations above the IMAC, in the sample from downgradient well MW-11. The concentration of cobalt in the sample from MW-11 was statistically evaluated to determine if the reported concentration exceeded the facility background concentration. The statistical worksheets are presented as Appendix D. The concentration of cobalt in the sample from MW-11 was determined to exceed the statistically calculated background concentration during this event. The concentration of cobalt from the sample from MW-11 is more than two times higher than recent concentrations and is considered suspect. The concentration will be confirmed during the first semi- annual monitoring event of 2020. The indicator parameter iron was reported at quantifiable concentrations above the NC 2L Standard in samples from downgradient monitoring wells MW-11 and MW-13. The indicator parameter manganese was reported at concentrations above the NC 2L Standard in samples from downgradient monitoring wells MW-11, MW-12, and MW-13. The concentrations of iron in the samples from MW-11 and MW-13 were statistically evaluated to determine if the reported concentrations exceeded the facility background concentration. The statistical worksheets are presented as Appendix D. The concentration of iron in the sample from MW-13 was determined to be below the statistically calculated background concentration during this event; therefore, no further action is recommended. The concentration of iron in the sample from MW-11 was determined to be above the statistically calculated background concentration during this event. Much like the cobalt concentration, iron was reported at a concentration nearly two times higher than recent events and is considered suspect. The concentration will be confirmed during the first semi-annual monitoring event of 2020. There are currently insufficient background data from upgradient well MW-10 with turbidity measurements less than 10 NTUs to establish background concentrations utilizing statistical methods for manganese. Within ,> GOLDER January 17, 2020 19128179.101 approximately one year of routine semi-annual monitoring, a sufficient number of background data should be acquired to further evaluate these concentrations. The USGS National Geochemical Survey Database indicates that concentrations of cobalt, iron, and manganese in stream sediment samples with 25 miles of the facility could contribute to the concentrations detected in groundwater samples from the C&D monitoring wells (Appendix C). While a direct comparison between sediment sample concentrations and groundwater concentrations cannot be made, these data show that these constituents occur naturally in local stream sediment. As presented in Table 8, one NC Appendix I VOC, vinyl chloride, was detected at quantifiable concentrations above the NC 2L Standard in samples from downgradient wells MW-12 and MW-13 during the September 2019 event at the C&D landfill. Constituent 1,4-dioxane was detected at a quantifiable concentration above the NC 2L Standard in the sample from MW-12. Samples were analyzed for 1,4-dioxane per the May 29, 2018, NC DEQ memorandum; this constituent is not required by regulation or the facility permit. The concentrations of 1,4-dioxane can be affected by seasonality and currently with limited data, will continue to be evaluated. On September 28, 2010, the County submitted an ASD to NC DEQ in response to VOC concentrations detected in samples from the closed C&D landfill downgradient monitoring wells. Based on the data and evaluations from the ASD, it was apparent that leachate from the C&D disposal unit is not the likely source of the VOC concentrations. Additionally, the data suggest that the source of the VOCs in samples from the monitoring wells is most likely landfill gas. 5.0 CORRECTIVE ACTION PERFORMANCE MONITORING A Corrective Action Performance Monitoring Plan (CAPMP) was approved as part of the CAP by the NC DEQ on July 13, 2015. Per the CAPMP, MNA background sampling began during the September 2015 semi-annual water quality event and the ninth MNA background event was performed during the September 2019 semi-annual water quality event. A request to modify the MNA parameter list was submitted to the NC DEQ on July 26, 2017 and was approved on September 19, 2017. The modified MNA list consists of sampling alkalinity, carbon dioxide, chloride, ethane, ethene, methane, hydrogen, ferrous iron, nitrate, and sulfate, semi-annually and sampling biological oxygen demand (BOD), chemical oxygen demand (COD), nitrite, sulfide, total organic carbon (TOC), and volatile fatty acids (VFAs), semi-annually every three years and were sampled during the September 2019 event. A CAER for MNA will be submitted to the NC DEQ after five years of MNA sampling results have been collected, which will be after the first semi-annual monitoring event of 2020. A CAER for the SAW pilot test was submitted to the NC DEQ on October 25, 2019. The CAER proposed that methylene chloride be removed as a constituent of concern (COC) and that SAW injections cease unless VOCs are detected above the NC 2L Standard in samples from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. The CAER was approved by the NC DEQ on November 5, 2019. 5.1 Monitored Natural Attenuation The fifth MNA monitoring event with the modified parameter list was performed during the September 2019 event. The MNA sampling results and evaluation are described below. 5.1.1 Monitored Natural Attenuation Sampling Results The ninth MNA background sampling event was performed during the September 2019 event. Per the CAPMP, monitoring well Old MW-2 was sampled in addition to the MSW compliance monitoring wells. The samples from MW-5, MW-6, MW-7, MW-8, AMW-1 S, AMW-2S and Old MW 2 were analyzed for modified ,> GOLDER January 17, 2020 19128179.101 MNA parameter list above. A summary of the MNA parameters is included as Table 10 and the certificates -of - analyses are included in Appendix B. The sample from Old MW-2 was also analyzed for the COCs from the CAP, which include benzene; 1,4-dichlorobenzene; 1,1-dichloroethene; tetrachloroethene; trichloroethene; and vinyl chloride. These constituents were analyzed in the other wells as part of the NC Appendix I list of constituents for the routine semi-annual water quality monitoring. A summary of the COCs is included as Table 11 and the certificates -of - analyses are included in Appendix B. Benzene and 1,4-dichlorobenzene were detected at quantifiable concentrations that exceeded their respective NC 2L Standards in the sample from downgradient monitoring well MW-6 during the September 2019 event. 1,4-dichlorobenzene was detected at quantifiable concentrations that exceeded their respective NC 2L Standards in the sample from downgradient monitoring well MW-7 during the September 2019 event No other COCs were detected at concentrations above the NC 2L Standards during the September 2019 event. 5.1.2 Monitored Natural Attenuation Sampling Evaluation Monitoring wells MW-7, MW-6, MW-8, and Old MW-2 were selected for a performance evaluation of MNA processes to adhere to the NC DEQ guidance document titled MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities. These wells have been selected because they are located in the area identified for corrective action by MNA in the June 2015 CAP. The September 2019 analytical data for these wells were evaluated using the Environmental Protection Agency (EPA)'s natural attenuation screening protocol (1999). Based on the EPA's screening protocol, monitoring well MW-7, MW-8, and Old MW-2 received scores of 18, 17, and 19, respectively, indicating adequate evidence for anaerobic biodegradation of chlorinated organics (EPA, 1999). Monitoring well MW-6 received a score of 22, which indicates there is strong evidence for anaerobic biodegradation of chlorinated organics. The natural attenuation screening protocol forms are included in Appendix E. Based on the results of the screening protocol, there is evidence that natural attenuation is occurring at the site; therefore, modelling was performed on the September 2019 data to simulate remediation by natural attenuation using a screening model called BIOCHLOR (EPA, 2000). Monitoring wells MW-7, MW-6, MW-8, and Old MW-2 were used in the model. Modelling parameters for advection, dispersion, and modelled area were the same as previous models performed for the site, done as part of an MNA evaluation in the NES. A 59-year simulation period was selected for the model, representing the time at which waste was first placed in the landfill (the original source). The September 2019 results represent current conditions at the facility and therefore, the model was calibrated to the current sample results by adjusting the biotransformation data within a prescribed range specified by literature values within the BIOCHLOR program. Once the model was calibrated a forecasted model was created by changing the simulation period to 100 years to assess the size of the contaminant plume in the future. BIOCHLOR generates plots that compare concentrations of tetrachloroethene, trichloroethene, dichloroethene, vinyl chloride, and ethene over time with no degradation to concentrations where sequential 1st order decay is occurring. The plots are provided in Appendix E. The centerline plots can be used to forecast the contaminant plume size over time. Because tetrachloroethene and trichloroethene were not detected in samples from downgradient monitoring wells MW-7, MW-6, MW-8, and Old MW-2 during the September 2019 monitoring event, the BIOCHLOR model could not be calibrated; however, the absence of tetrachloroethene and trichloroethene in these downgradient samples could be considered evidence of biodegradation. Dichloroethene, Vinyl chloride, and Ethene were not detected in samples from these wells during the September 2019 event. The results from these plots indicate that natural attenuation is occurring at the site and that as long as conditions at the site ,> GOLDER January 17, 2020 19128179.101 continue to be strongly anaerobic, biodegradation will likely continue. According to the current data, it is likely that the plume size has stabilized, as indicated by the BIOCHLOR model. 5.2 Super Aerated Water Pilot Test Sampling Results SAW pilot test injections occurred quarterly between May 2016 and March 2019. SAW injections have ceased unless VOCs are detected above the NC 2L Standard in samples from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. As presented in Table 11, no COCs were detected at concentrations above NC 2L Standards during the September 2019 event. Benzene was detected at an estimated concentration below the NC 2L Standard in the sample from AMW-1 D and 1,4-dichlorobenzene was detected at a quantifiable concentration below the NC 2L Standard in the sample from AMW-1 D. A summary of the alkalinity results is included in Table 10 and a summary of the COC results is included as Table 11. The certificates -of -analyses for each event are included in Appendix B. CONCLUSIONS Due to the presence of VOCs above applicable groundwater standards, Henderson County will continue to monitor the uppermost aquifer beneath the MSW landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.1634. MNA monitoring events have been performed as outlined in the approved CAP and a CAER will be prepared after the first semi-annual water quality monitoring event of 2020. SAW pilot test injections are no longer required unless VOCs are detected above the NC 2L Standards in samples from groundwater monitoring wells screened in the partially weathered rock / fractured bedrock aquifer. Benzene in samples from MW-6 and MW-7 and 1,4-dichlorobenzene in the sample from MW-7 were the only NC Appendix I VOCs detected at quantifiable concentrations above groundwater standards in samples from MSW downgradient wells during the September 2019 event. An ASD was submitted to NC DEQ on September 28, 2010, to address the source of the VOCs in samples from the closed C&D landfill wells. Based on the data and evaluations from the ASD, it is apparent that leachate from the C&D unit is not the likely source of the VOC concentrations that have been detected in the C&D landfill downgradient monitoring wells. Additionally, the data suggest that the source of the VOCs detected in these monitoring wells is most likely landfill gas. However, a letter from NC DEQ dated May 12, 2011, instructed the County to initiate an Assessment Monitoring Program for the C&D facility. Vinyl chloride in the samples from MW-12 and MW-13 was the only NC Appendix I VOC that was detected at quantifiable concentrations above groundwater standards in samples from C&D downgradient monitoring wells during the September 2019 event. Based on the results summarized herein, the County will continue the implementation of groundwater corrective action at the MSW landfill in accordance with the approved CAP. The County will also continue monitoring the C&D landfill in accordance with the requirements of the Assessment Monitoring Program as outlined in Title 15A NCAC 13B.0545. The next compliance monitoring event for this facility is tentatively scheduled for March 2020. 7.0 REFERENCES Butler, J.R., and D.T. Secor, Jr., 1991. The Central Piedmont (Chapter 4) in J.W. Horton, Jr. and V.A. Zullo, eds., The Geology of the Carolinas (Carolina Geological Society Fiftieth Anniversary Volume): The University of Tennessee Press, pp. 2, 4, 24, 36, 44-45. Camp Dresser & McKee, December 2008. October 2008 Semi -Annual Sampling Report, Stoney Mountain Road Sanitary Landfill. > GOLDER 10 January 17, 2020 19128179.101 Camp Dresser & McKee, June 3, 2008. Henderson County Closed Stoney Mountain Road Sanitary Landfill Additional Groundwater Assessment. Camp Dresser & McKee, May 9, 2008. April 2008 Semi -Annual Sampling Report, Stoney Mountain Road Sanitary Landfill. Camp Dresser & McKee, September 26, 2008. Henderson County Additional Groundwater Assessment Proposed Workplan. Golder Associates NC, Inc., September 17, 2009. Groundwater Assessment Work Plan; Closed Henderson County Landfill, Permit No. 45-01; Henderson County, North Carolina. Golder Associates NC, Inc., September 28, 2010. Alternate Source Demonstration: Anomalous Detections of Volatile Organic Compounds; Henderson County Closed Construction and Demolition Landfill, Permit No. 45-01. North Carolina Geologic Survey, 1985. Geologic Map of North Carolina North Carolina Geologic Survey, 2004. Modified from 1991 Generalized Geologic Map (digital representation) ,> GOLDER 11 January 17, 2020 19128179.101 Signature Page Golder Associates NC, Inc. David "Dusty" Y. Reedy Il, PG Rachel P. Kirkman, PG Senior Hydrogeologist Associate and Senior Consultant Engineering Lic. No. C-2862/Geology Lic. No. C-399 Golder Associates NC, Inc. is a licensed user of the Golder trademark, and an associated operating entity. Golder and the G logo are trademarks of Golder Associates Corporation. gAprojecWhenderson county\19128179\phase 101 -2nd sa wqm 2019\200 deliver2bles\252 final issued\19128179.101-001-r-rev0-2nd sa_wgmr_2019.docx GOLDER 12 Tables January 2020 19128179 TABLE 1 Summary of Historical Static Water Level Data Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 MSW Landfill Compliance Monitoring Wells MSW Landfill Assessment Monitoring Wells MSW Non -Compliance Wells MW-5 MW-6 MW-7 MW-8 AMWAS AMWAD AMW-2S AMW-21D MW-1(Old) MW-1 MW-2(Old) MW-2 IW-1 TOC Elevation 2389.82 2204.24 2210.66 2235.87 2193.09 2190.77 2177.66 2177.58 2206.42 2205.76 2182.77 2182.07 2189.48 (ft AMSL) Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 10/04/06 2334.31 55.51 2191.02 13.22 2191.61 19.05 2209.54 26.33 2179.83 13.26 2176.67 14.10 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 03/21/07 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- 10/02/07 2331.55 58.27 2188.19 16.05 2189.95 20.71 2207.85 28.02 2176.63 16.46 2174.07 16.70 -- -- -- -- -- -- -- -- -- -- -- -- -- -- 04/03/08 2326.17 63.65 2190.65 13.59 2190.63 20.03 2209.61 26.26 2180.41 12.68 2177.04 13.73 -- -- - -- -- -- -- -- -- -- -- -- -- -- 10/29/08 2322.17 67.65 2186.73 17.51 2188.87 21.79 2206.91 28.96 2175.87 17.22 2173.56 17.21 2168.25 9.41 2170.93 6.65 -- -- -- -- -- -- -- -- -- -- 03/24/09 2319.25 70.57 2188.30 15.94 2189.28 21.38 2208.43 27.44 2178.99 14.10 2176.04 14.73 2169.29 8.37 2172.05 5.53 -- -- -- -- -- -- - -- -- -- 09/21-24109 2326.37 63.45 2194.99 9.25 2190.56 20.10 2209.46 26.41 2180.79 12.30 2177.56 13.21 2170.17 7.49 2174.88 2.70 2200.47 5.95 2200.58 5.18 2174.92 7.85 2174.14 7.93 - -- 03/22-23/10 2342.62 47.20 <2185.22 >19.02 2193.88 16.78 2208.53 27.34 2182.71 10.38 2178.32 12.45 2170.28 7.38 2173.33 4.25 2200.91 5.51 2201.11 4.65 2175.02 7.75 2164.27 17.8 - - 09/21-22110 2338.34 51.48 2189.98 14.26 2191.49 19.17 2210.62 25.25 2177.74 15.35 2173.85 16.92 2171.40 6.26 2170.92 6.66 2199.72 6.70 2199.58 6.18 2163.77 19.00 2171.73 10.34 - - 03/15-16/11 2333.36 56.46 2194.83 9.41 2191.45 19.21 2211.13 24.74 2181.44 11.65 2176.77 14.00 2169.72 7.94 2171.74 5.84 2200.61 5.81 2200.72 5.04 2174.81 7.96 2173.04 9.03 - -- 09/20-21111 2331.91 57.91 2189.10 15.14 2190.61 20.05 2209.78 26.09 2177.42 15.67 2173.77 17.00 2168.40 9.26 2170.86 6.72 2199.74 6.68 2199.44 6.32 2173.97 8.8 2171.72 10.35 - -- 03/20-22/12 2330.51 59.31 2189.49 14.75 2191.15 19.51 2210.25 25.62 2178.99 14.10 2175.58 15.19 2169.04 8.62 2171.08 6.50 2200.24 6.18 2200.13 5.63 2174.36 8.41 2172.34 9.73 - -- 09/19-20112 2328.67 61.15 2189.64 14.60 2190.07 20.59 2209.24 26.63 2177.89 15.20 2175.53 15.24 2169.33 8.33 2172.33 5.25 -- -- -- -- -- -- - -- -- -- 03/20/13 2330.45 59.37 2189.68 14.56 2190.54 20.12 2210.79 25.08 2179.83 13.26 2176.77 14.00 2169.69 7.97 2173.50 4.08 2200.44 5.98 2200.45 5.31 2174.59 8.18 2172.83 9.24 - - 09/18/13 2342.55 47.27 2190.92 13.32 2191.97 18.69 2212.33 23.54 2179.38 13.71 2176.39 14.38 2168.98 8.68 2174.27 3.31 2198.04 8.38 2198.73 7.03 2174.20 8.57 2172.58 9.49 - - 03/26/14 2339.89 49.93 2190.53 13.71 2191.50 19.16 2211.92 23.95 2180.00 13.09 2176.92 13.85 2169.51 8.15 2174.24 3.34 2200.43 5.99 2200.54 5.22 2174.54 8.23 2172.73 9.34 - -- 09/18/14 2336.72 53.10 2189.19 15.05 2190.44 20.22 2210.90 24.97 2178.02 15.07 2175.28 15.49 2168.67 8.99 2173.02 4.56 2200.33 6.09 2199.73 6.03 2174.10 8.67 2171.82 10.25 - - 03/17/15 2332.78 57.04 2189.98 14.26 2190.34 20.32 2210.90 24.97 2179.80 13.29 2176.77 14.00 2169.61 8.05 2173.51 4.07 2200.96 5.46 2200.62 5.14 2174.61 8.16 2172.62 9.45 - - 09/23/15 2328.66 61.16 2187.28 16.96 2188.93 21.73 2209.22 26.65 2175.97 17.12 2173.51 17.26 2167.94 9.72 2171.46 6.12 2198.30 8.12 2198.24 7.52 2173.77 9.00 2170.45 11.62 - -- 03/15/16 2342.54 47.28 2191.02 13.22 2192.41 18.25 2213.36 22.51 2180.40 12.69 2177.45 13.32 2169.78 7.88 2174.97 2.61 2200.41 6.01 2199.98 5.78 2174.75 8.02 2173.27 8.80 2180.06 9.42 09/21/16 2335.83 53.99 2187.40 16.84 2189.75 20.91 2210.08 25.79 2177.10 15.99 2174.46 16.31 2168.30 9.36 2172.46 5.12 2200.08 6.34 2198.89 6.87 2172.84 9.93 - - 2176.86 12.62 03/22/17 2326.49 63.33 <2187.09 >17.15 2188.48 22.18 2208.65 27.22 2177.07 16.02 2174.75 16.02 2168.97 8.69 2171.56 6.02 2200.22 6.20 2199.15 6.61 2174.15 8.62 2171.10 10.97 2177.19 12.29 09/20/17 2329.64 60.18 <2186.84 >17.40 2189.65 21.01 2210.24 25.63 2178.54 14.55 2175.63 15.14 2169.10 8.56 2173.05 4.53 2200.71 5.71 2199.40 6.36 2174.00 8.77 2171.78 10.29 2178.19 11.29 03/21/18 2336.18 53.64 2199.99 4.25 2190.89 19.77 2211.44 24.43 2179.69 13.40 2176.73 14.04 2169.65 8.01 2173.82 3.76 2201.21 5.21 2199.77 5.99 2174.32 8.45 2172.47 9.60 2179.40 10.08 09/24/18 2342.89 46.93 2189.73 14.51 2191.11 19.55 2212.25 23.62 2178.95 14.14 2176.03 14.74 2168.94 8.72 2173.73 3.85 2200.92 5.50 2199.52 6.24 2174.01 8.76 2172.05 10.02 2178.72 10.76 03/25/19 2349.70 40.12 2198.35 5.89 2193.91 16.75 2215.21 20.66 2181.26 11.83 2178.01 12.76 2170.40 7.26 2175.74 1.84 2201.90 4.52 2200.21 5.55 2174.42 8.35 2173.52 8.55 2180.90 8.58 09/18/19 2341.54 48.28 2190.00 14.24 2191.30 19.36 2211.82 24.05 2178.09 15.00 2175.29 15.48 2168.52 9.14 2173.37 4.21 2200.61 5.81 2199.24 6.52 2173.87 8.90 2171.69 10.38 2178.02 11.46 MEAN 2333.89 55.93 2190.74 13.50 2190.80 19.86 2210.40 25.47 2178.95 14.14 2175.88 14.90 2169.30 8.36 2172.91 4.67 2200.31 6.11 2199.80 5.96 2173.75 9.02 2171.90 10.17 2178.67 10.81 MAXIMUM 2349.70 70.57 2199.99 17.51 2193.91 22.18 2215.21 28.96 2182.71 17.22 2178.32 17.26 2171.40 9.72 2175.74 6.72 2201.90 8.38 2201.11 7.52 2175.02 19.00 2174.14 17.80 2180.90 12.62 MINIMUM 2319.25 40.12 2186.73 4.25 2188.48 16.75 2206.91 20.66 2175.87 10.38 2173.51 12.45 2167.94 6.26 2170.86 1.84 2198.04 4.52 1 2198.24 1 4.65 2163.77 7.75 2164.27 7.93 2176.86 8.58 TVA Landfill Monitoring C&D Landfill Compliance Monitoring Wells Well MW-10 MWA1 MW-12 MW-13 MW3 TOC Elevation 2404.55 2307.72 2300.09 2296.33 2259.59 (ft AMSL) Elevation DTW Elevation DTW Elevation DTW Elevation DTW Elevation DTW Date (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) (ft AMSL) (ft) 10/04/06 -- -- -- -- -- -- -- -- 2244.64 15.37 03/21/07 2371.42 33.13 2266.46 30.55 2250.25 49.84 2252.90 47.34 -- -- 10/02/07 -- -- -- -- -- -- -- -- 2244.08 15.93 04/03/08 -- -- -- -- -- -- -- -- 2244.03 15.98 10/29/08 2364.42 40.13 2258.56 38.45 2246.56 53.53 2245.91 54.33 2242.52 17.49 03/24/09 2363.04 41.51 2256.50 40.51 2244.43 55.66 2244.51 55.73 2242.21 17.80 09/21-24109 2367.33 37.22 2258.97 38.04 2245.20 54.89 2245.56 54.68 2243.29 16.72 03122-23/10 2376.31 28.24 2258.18 38.83 2250.60 49.49 2253.17 47.07 2236.04 23.97 09/21-22110 2369.83 34.72 2267.16 29.85 2250.78 49.31 2253.84 46.4 2245.16 14.85 03115-16/11 2367.12 37.43 2263.36 33.65 2248.90 51.19 2251.00 49.24 2245.10 14.91 09/20-21111 2368.37 36.18 2260.95 46.77 2249.18 50.91 2250.57 45.76 2244.95 14.64 03120-22/12 2367.47 37.08 2260.61 47.11 2248.24 51.85 2249.98 46.35 2244.54 15.05 09/19-20112 2367.05 37.50 2260.07 47.65 2247.39 52.70 2249.08 47.25 -- -- 03/20/13 2367.57 36.98 2259.14 48.58 2247.66 52.43 2249.30 47.03 2244.43 15.16 09/18/13 2375.12 29.43 2265.42 42.30 2252.34 47.75 2255.88 40.45 2249.63 9.96 03/26/14 2372.14 32.41 2266.61 41.11 2253.04 47.05 2255.79 40.54 2247.08 12.51 09/18/14 2369.87 34.68 2265.38 42.34 2251.59 48.50 2254.33 42.00 -- -- 03/17/15 2367.64 36.91 2262.72 45.00 2249.97 50.12 2251.60 44.73 2245.25 14.34 09/23/15 2366.71 37.84 2259.50 48.22 2248.16 51.93 2249.76 46.57 2243.30 16.29 03/15/16 2374.71 29.84 2263.81 43.91 2253.18 46.91 2255.44 40.89 2247.00 12.59 09/21/16 2369.18 35.37 2263.94 43.78 2251.74 48.35 2253.68 42.65 2245.61 13.98 03/22/17 <2366.76 >37.79 2258.35 49.37 2247.61 52.48 2248.70 47.63 2243.07 16.52 09/20/17 2366.74 37.81 2257.41 50.31 2247.42 52.67 2249.08 47.25 2242.77 16.82 03/21/18 2368.44 36.11 2261.40 46.32 2249.49 50.60 2250.84 45.49 2244.53 15.06 09/25/18 2373.46 31.09 2265.79 41.93 2253.50 46.59 2256.04 40.29 2246.54 13.05 03/25/19 2379.31 25.24 2270.94 36.78 2259.00 41.09 2261.36 34.97 2250.01 9.58 09/18/19 2371.95 32.60 2273.88 33.84 2256.36 43.73 2257.79 38.54 2248.34 11.25 MEAN 2369.79 34.76 2262.71 41.88 2250.11 49.98 2251.92 45.55 2244.76 14.99 MAXIMUM 2379.31 41.51 2273.88 50.31 2259.00 55.66 2261.36 55.73 2250.01 23.97 MINIMUM 2363.04 25.24 2256.50 29.85 2244.43 41.09 2244.51 34.97 2236.04 9.58 Notes: DTW = depth to water ft = feet ft AMSL = feet above mean sea level. TOC = top of casing -- = no data available Historical data prior to March 2009 provided by Henderson County and CDM. The stick-ups on monitoring wells MW-9, MW-11, and MW-13 were modified prior to the September 2011 event and the TOC elevations for those wells were resurveyed. (, GOLDER 1 of 1 January 2020 TABLE 2 Summary of Estimated Horizontal Flow Velocities Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 19128179 September 2019 Gradient Calculation Gradient Segment Gradient Segment Horizontal Gradient Effective Hydraulic Velocity Segment Flow Direction Length Elevations (i feet) Porosity Conductivity (V9W, feet/year) (feet) (feet) (ne) (K, cm/sec) i SW 1416 ------ ---2320--------- 2200 0.0847 0.15 1.26E-04 73.82 i2 SSW 1631 _________2340 2200 0.0858 0.15 1.26E-04 74.78 i3 WSW 376 --------- 2360--------- 2260 0.2660 0.15 1.26E-04 231.68 Notes: Horizontal velocities based on the modified Darcy equation V9W = Ki/ne, Value for K is collected from the average of measured hydraulic conductivities from the December 2008 CDM Report. Value for ne is an estimated effective porosity used in previous CDM reports. .,> GOLDER 1 of 1 January2020 TABLE 3 Summary of Well Construction Information Henderson County Closed MSW and C&D Landfills, Permit No. 45-01 19128179 Well Identification Construction Date Coordinates Ground Surface Elevation ft AMSL TOC Elevation ft AMSL Well Depth ft Well Diameter in Screened Interval ft BGS Screened Interval ft AMSL Geology of Screened Interval Well Status Northing Easting MW-5 10/21/1994 603077.23 958574.87 2386.79 2389.82 73.03 2 48.03 - 73.03 2341.79 - 2316.79 Sa rolite MSW Compliance Background Well MW-6 10/20/1994 602152.02 956919.71 2202.39 2205.39 23.00 2 8.00 - 23.00 2197.39 - 2182.39 Sa rolite MSW Compliance Well MW-7 10/17/1994 601949.28 957146.97 2207.77 2210.66 27.89 2 12.89 - 27.89 2197.77 - 2182.77 Sa rolite MSW Compliance Well MW-8 10/18/1994 601765.86 957772.78 1 2232.97 2235.87 34.90 2 1 19.90 - 34.90 2215.97 - 2200.97 Sa rolite MSW Compliance Well MW-9 10/18/1994 601664.26 958474.38 2256.95 2260.01 28.06 2 13.06 - 28.06 2246.95 - 2231.95 Sa rolite TVA Monitoring Well AMW-1 S 10/15/2001 602112.51 956718.62 2190.20 2193.09 31.72 2 15 - 30 2175.20 - 2160.20 Sa rolite MSW Assessment Well AMW-1 D 10/15/2001 602096.10 956704.70 2188.37 2190.77 62.65 2 50 - 60 2138.37 - 2128.37 PWR / Upper Fractured Rock MSW Assessment Well AMW-2S 4/2/2008 602098.59 956540.99 2168.25 2177.66 22.00 2 7.00 - 22.00 2161.25 - 2146.25 Sa rolite MSW Assessment Well AMW-2D 4/2/2008 602116.88 956553.69 2170.93 2177.58 80.00 2 70.00 - 80.00 2100.93 - 2090.93 Fractured Rock MSW Assessment Well MW-10 NA 601790.07 959077.23 2402.63 2404.55 45.0 2 35 - 45 2367.63 - 2357.63 Sa rolite / PWR C&D Compliance Background Well MW-11 NA 601946.06 958655.82 NA 2297.01 48.17 2 NA-48.17 NA NA C&D Compliance Well MW-12 NA 601683.36 958608.18 2297.97 2300.09 60.0 2 50 - 60 2244.97 - 2234.97 Sa rolite / PWR C&D Compliance Well MW-13 NA 601511.47 958653.36 NA 2300.24 92.0 2 77 - 92 2221.16 - 2206.16 Bedrock C&D Compliance Well MW-1 OLD NA 601264.43 957865.19 NA 2206.40 20.7 BTOC 2 NA NA Sa rolite Non -Compliance Well MW-1 NA 601286.04 957837.08 NA 2206.80 70.2 BTOC 2 NA NA PWR Non -Compliance Well MW-2 OLD NA 601446.34 957142.17 NA 2182.10 20.6 BTOC 2 NA NA Sa rolite / PWR Corrective Action Well MW-2 NA 601438.21 957125.15 NA 2182.80 67.6 BTOC 2 NA NA PWR / Upper Fractured Rock Corrective Action Well IW-1 3/9/2016 602096.76 1 956729.44 2189.96 2189.48 65.0 2 45 - 65 2144.96 - 2124.96 Bedrock MSW Injection Well Notes: ft = feet in = inches AMSL = above mean sea level BGS = below ground surface BTOC = below top of casing Well construction information provided by Henderson County & CDM NA = Data is not available or not applicable PWR = Partially Weathered Rock Northings and eastings were taken from Drawing 1 and should be considered approximate. GOLDER 1of1 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW-5 MW-6 MW-7 MW-8 AMW-,S AMW-1D AMW-2S AMW-213 MW-9 Antimony ug/L 12/05/94 - -- 6 ND ND ND ND -- -- -- - ND -- IMAC = 1 ug/L ug/L 02/14/95 -- -- 6 ND ND ND ND -- -- -- -- ND -- EPA MCL=6 ug/L ug/L 04/03/95 -- -- 6 ND ND ND ND -- -- -- - ND -- ug/L 101 0/95 -- -- 6 ND ND ND ND - -- -- -- ND -- ug/L 04/08/96 -- -- 6 ND ND ND ND -- -- -- - ND -- ug/L 10/24/96 -- -- 6 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 -- -- 6 ND -- ND ND - -- -- - ND -- ug/L 10/29/99 -- -- 6 ND ND 3 ND - -- -- - ND -- ug/L 05/14/98 -- -- 6 ND ND ND ND - -- -- - ND -- ug/L 10/1,/98 -- -- 6 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 -- -- 6 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 -- -- 6 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 6 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 -- -- 6 ND ND ND ND - -- - -- ND -- ug/L 05/15/0, -- -- 6 ND ND ND ND - -- - -- ND -- ug/L 10,16/0, -- -- 6 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 6 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 6 ND ND ND ND ND ND - -- ND -- ug/L 10/04/O6 -- -- 6 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 6 ND ND ND ND ND ND - -- 0.91 J ND ug/L 10/02/07 - -- 6 ND ND ND ND ND ND - -- ND ND 04/03/08 - -- 6 ND ND ND ND ND ND ND ND ND ND %ug/L L 10/29/08 - -- 6 ND ND ND ND ND ND ND ND ND ND ug/L 03/24/09 0.68 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.073 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/22/10 0.22 2.00 6 ND Dry ND 0.441 J ND ND ND ND -- ND ug/L 09/231 0 0.22 2.00 6 ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.22 2.00 6 0.226 J ND 0.286 J ND 0.460 J 0.382 J ND 0.365 J -- ND ug/L 09/21/11 0.22 2.00 6 ND 0.478 J 0.408 J 0.287 J ND ND ND ND - ND ug/L 03/21/12 0.22 2.00 6 0.320 J ND ND 0.906 J ND 0.236 J ND ND ND ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND ND ND ND ND - ND ug/L 03/20/13 0.22 2.00 6 ND ND ND 0.621 J ND ND ND ND ND ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND ND ND ND ND - ND ug/L 03/27/14 0.22 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.22 2.00 6 0.319 J 0.275 J 0.874 J ND ND ND ND ND - ND ug/L 03/18/15 0.22 2.00 6 ND ND ND 0.661 J ND ND ND ND ND ND ug/L 09/23/15 0.22 2.00 6 ND ND 2.64 J ND ND ND ND ND - 0.331 J ug/L 03/17/16 0.22 2.00 6 0.861 J 0.517 J ND ND ND 0.333 J ND ND ND ND ug/L 09/21/16 0.22 2.00 6 ND ND 0.308 J ND ND ND ND ND - ND ug/L 03/21/17 0.22 2.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/17 0.37 2.00 6 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 1.85 5.00 6 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.85 5.00 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 0.74 2.00 - ND ND ND ND ND ND ND ND ND ND 09/18/19 0.74 2.00 ND ND ND ND ND ND ND ND ND IArsenic L 12/05/94 -- -- 10 ND ND ND ND -- -- -- -- ND -- NC 2L = 10 ug/L ug/L 02/14/95 -- -- 10 ND ND ND ND -- -- -- -- ND -- EPA MCL = 10 ug/L ug/L 04/03/95 - -- 10 ND ND ND ND -- -- -- -- ND -- ug/L 101 0/95 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 04/08/96 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 - -- 10 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 - -- 10 ND -- ND ND - -- -- -- ND -- ug/L 10/29/97 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 05/14/98 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 04/20/00 - -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 - -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 10 ND ND ND ND 10.1 ND - -- ND -- ug/L 04/09/03 - -- 10 ND ND ND ND ND 11.1 - -- ND -- ug/L 10/20/03 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 - -- 10 ND 14.7 ND 21.3 ND ND - -- ND -- ug/L 05/25/05 - -- 10 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 - -- 10 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 - -- 10 ND 0.84 J 0.94 J 0.46 J 1.13 J ND - -- ND ND ug/L 10/02/07 - -- 10 ND ND ND ND ND ND - -- ND ND ug/L 04/03/0B - -- 10 2.07 J 2.45 J 3.04 J 5.07 J ND ND 3.64 J 10.5 ND ND ug/L 10/29/08 - -- 10 ND 13.9 7.18 J ND ND 5.98 J 5.38 J 2.96 J ND ND ug/L 03/24/09 2.8 10.0 10 ND ND ND 3.1 J ND ND ND ND ND ND ug/L 09/22/09 2.8 10.0 10 ND 5.40 B 7.18 B ND ND ND ND ND - 2.90 J ug/L 03/22/10 2.8 10.0 10 ND Dry ND ND ND ND ND ND - ND ug/L 09/23/10 2.8 10.0 10 ND 5.27 J ND 4.58 J ND ND ND ND - ND ug/L 03/16/11 2.8 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 09/21/11 2.8 10.0 10 ND ND 5.48 J 6.93 J ND ND 4.29 J 3.03 J - ND ug/L 03/21/12 2.8 10.0 10 3.80 J ND ND ND ND ND ND 4.00 J ND ND ug/L 09/20/12 2.8 10.0 10 ND ND ND ND ND ND ND ND -- 3.27 J ug/L 03/20/13 2.6 10.0 10 ND ND ND ND ND ND ND 3.04 J ND ND ug/L 09/18/13 5.4 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/27/14 5.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/1814 5.4 10.0 10 ND ND ND ND 5.51 J ND ND ND - ND ug/L 03/18/15 5.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 5.4 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 5.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 6.8 10.0 10 ND 14.1 ND 8.11 J ND ND ND ND - ND ug/L 03/21/17 6.8 10.0 10 ND 8.43 B 10.6 B 11.7 B ND ND 14.4 B ND ND 9.82 J ug/L 09/20/17 6.8 10.0 10 ND ND ND ND ND ND ND ND - ND 03/21/18 6.8 10.0 10 ND ND ND ND ND ND ND ND ND ND %ug/L L 09/23/18 7.6 10.0 -- ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 7.6 10.0 -- ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 7.6 10.0 ND ND ND ND ND ND ND ND ND Barium ug/L 12/05/94 -- -- 100 134 237 378 528 -- -- -- -- 207 -- NC 2L = 700 ug/L ug/L 02/14/95 -- -- 100 ND 416 439 601 -- -- -- -- 205 -- EPA MCL=2000 ug/L ug/L 04/03/95 -- -- 100 174 493 35 7816 -- -- -- -- 197 -- ug/L 10/30/95 - -- 100 348 539 230 835 -- -- -- -- 358 -- ug/L 04/08/96 -- -- 100 199 3329 264 790 -- -- -- -- 140 -- ug/L 10/24/96 -- -- 100 300 -- 338 925 -- -- -- -- 285 -- ug/L 04/15/97 -- -- 100 180 -- 300 810 -- -- -- -- 360 -- ug/L 10/29/97 -- -- 100 200 700 500 700 -- -- -- -- 100 -- ug/L 05/14/98 -- -- 100 ND ND ND 628 -- -- -- -- ND -- ug/L 10/11/98 -- -- 100 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 -- -- 100 ND ND ND 552 - -- -- -- ND -- ug/L 10/29/99 -- -- 100 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 100 ND ND ND ND 258 -- - -- ND -- ug/L 11/07/00 -- -- 100 ND ND ND ND - -- - -- ND -- ug/L 05/,5/0, -- -- 100 ND ND ND 604 - -- - -- ND -- ug/L 10/16/01 -- -- 1Do ND 178 116 298 - ND - -- ND -- ug/L 04/24/02 -- -- 100 ND ND ND 642 ND ND - -- ND -- ug/L 10/01/02 -- -- 100 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 100 ND ND ND 522 ND ND - -- ND -- ug/L 10/20/03 -- -- 100 ND ND ND 720 ND ND - -- ND -- ug/L 03/24/04 -- -- 100 ND ND ND 829 ND ND - -- ND -- ug/L 10/27/04 -- -- 100 ND 530 ND 866 ND ND - -- ND -- ug/L 05/25/05 -- -- 100 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 100 ND ND ND 982 ND ND - -- ND -- ug/L 04/25/06 - -- 100 ND 687 ND 822 ND ND - -- ND -- ug/L 10/04/06 - -- 100 ND 562 ND 920 ND ND - -- ND ND ug/L 03/21/07 - -- 100 47.5 J 136 294 992 306 27.2 J - -- 49.9 J ND ug/L 10/02/07 - -- 100 135 904 198 695 563 37.4 B - -- 54.3 B 16.1 J ug/L 04/03/08 - -- 100 87.8 J 86.8 J 144 714 476 20.3 B 44.3 B 39.4 B 65.9 J 10.1 J ug/L 10/29/08 - -- 100 69.9 J 795 227 429 930 2082 24.9 J 19.4 J 62.1 J ND ug/L 03/24/09 4.2 10.0 100 26.2 J 54.5 J 203 517 221 19.0 J 15.4 J ND 56.7 J ND ug/L 09/22/09 1.0 10.0 100 31.5 J 48.9 J 259 916 323 11.7 J 19.1 J 5.46 J - ND ug/L 03/22/10 1.0 10.0 100 28.2 J Dry 268 693 79.9 J 23.1 J 9.57 J 4.16 B - 1.54 J ug/L 09/23/10 1.0 10.0 100 34.3 J 335 302 1130 86.5 J 13.1 J 7.69 J 1.79 J - ND ug/L 03/16/11 1.0 10.0 100 71.3 J 39.4 J 417 414 216 8.14 J 85.4 J 2.71 J - ND ug/L 09/21/11 1.0 10.0 100 40.2 J 482 453 1370 214 12.2 J 14.0 J 2.07 J - ND ug/L 03/21/12 1.0 10.0 100 60.8 J 315 481 1070 412 14.5 J 7.28 J 164 J 180 ND ug/L 09/20/12 1.0 10.0 100 28.9 J 58.9 J 464 454 390 12.2 J 12.9 J 2.15 J - ND ug/L 03/20/13 1.0 10.0 100 51.9 J 33.4 J 518 957 342 10.4 J 8.94 J 1.74 B 192 1.34 J ug/L 09/18/13 1.0 10.0 100 57.7 J 218 590 787 400 11.3 J 26.6 J 2.75 B - 1.08 J ug/L 03/27/14 1.0 10.0 100 42.5 J 43.3 J 514 988 239 21.5 J 10.4 J 2.58 J 217 ND ug/L 09/18/14 1.0 10.0 100 31.2 J 482 453 1050 306 16.5 J 5.60 B 2.15 B - 1.96 J ug/L 03/18/15 1.0 10.0 100 42.3 J 27.4 J 535 710 538 11.0 J 11.7 J 2.26 J 226 ND ug/L 09/23/15 1.0 10.0 100 27.0 J 692 521 741 686 17.5 B 7.64 B 3.32 B - 4.08 J ug/L 03/17/16 1.0 ,0.0 100 50.7 J 131 618 530 388 8.55 J 7.16 J 2.96 J 118 ND ug/L 013/21116 1.0 10.0 100 3099 J 838 628 699 338 8.38 J 8.46 J 3.92 J - ND ug/L 03/21/17 1.0 10.0 100 16.6 J 576 554 581 412 7.31 J 8.01 J 2.87 J 105 ND ug/L 09/20/17 1.0 10.0 100 25.1 J 122 562 569 324 7.76 J 6.36 J 3.07 J - ND ug/L 03/21/18 1.0 10.0 100 51.5 J 54.5 J 566 575 491 8.61 J 7.04 J 3.23 J 122 ND ug/L 09/23/18 1.1 10.0 -- 36.0 159 518 5435 338 15.3 5.36 J 2.60 J -- ND ug/L 03/26/19 1.1 10.0 -- 41.2 36 617 728 384 39.2 4.10 J 2.66 J 123 ND (dissolved) ug/L 03/26/19 1.1 10.0 -- -- -- - 654 -- -- - -- - ND u /L 09/18/19 1.1 10.0 27.9 563 556 669 284 17.2 B 4.03 B 2.87 B 3.97 J 4 GOLDER of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-6 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Beryllium ug/L 12/05/94 -- -- 1 ND ND 3 7 -- -- -- -- ND -- IMAC=4 ug/L ug/L 02/14/95 - -- 1 ND ND 4 5 -- -- -- -- ND -- EPA MCL =4 ug/L ug/L 04/03/95 -- -- 1 ND 2 3 9 -- -- -- -- ND -- ug/L 10/30/95 - -- 1 ND ND ND 5 -- -- -- -- ND -- ug/L 04/08/96 -- -- 1 ND ND ND 4 -- -- -- -- ND -- ug/L 10/24/96 -- -- 1 ND -- ND 4 - -- -- -- ND -- ug/L 04/15/97 -- -- 1 ND -- ND 8 - -- -- -- ND -- ug/L 10/29/97 - -- 1 ND 3 3 14 - -- -- -- 1 -- ug/L 05/14/98 -- -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/1,/98 -- -- 1 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 -- -- 1 ND ND ND 2.4 - -- - -- ND -- ug/L 10/29/99 -- -- 1 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 1 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 -- -- 1 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 -- -- 1 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 -- -- 1 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 1 4.2 ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 1 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 1 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 1 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 1 ND ND ND ND ND ND - -- ND -- ug/L 04/25,06 -- -- 1 ND ND ND ND ND ND -- -- ND -- ug/L 10/04/O6 -- -- 1 ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 -- -- 1 ND ND ND 1.06 J 5.1 J ND -- -- ND ND ug/L 10/02/07 - -- 1 ND ND ND ND ND ND -- -- 22.8 B 6.01 ug/L 04/03/08 -- -- 1 1.07 2.8 6.28 ND 5.41 3.2 ND 2.33 1.54 ND ug/L 10/29/08 -- -- 1 4.60 5.96 2.23 10.2 10.7 5.45 10.7 2.23 11.2 ND ug/L 03/24/09 0.08 1.00 1 0.35 J 0.20 J 0.82 J 3.02 1.30 ND 0.18 J ND 0.35 J ND ug/L 09/22/09 0.10 1.00 1 0.438 J 0.299 J 0.771 J 1.26 0.438 J ND 0.470 J ND -- ND ug/L 03/22/10 0.10 1.00 1 ND Dry 0.635 J ND 0.631 J ND ND 0.247 J -- ND ug/L 09/23/10 0.10 1.00 1 0.198 J ND 0.570 J ND 0.492 J ND ND ND -- ND ug/L 03/16/11 0.10 1.00 1 0.208 J ND 0.422 J ND 1.06 ND 1.80 ND - ND ug/L 09/21/11 0.10 1.00 1 ND 0.183 J 0.707 J 1.13 1.37 ND 0.138 J ND - ND ug/L 03/21/12 0.10 1.00 1 0.222 J ND 0.260 J 0.189 J 1.96 ND ND ND 1.37 ND ug/L 09/20/12 0.10 1.00 1 ND ND 0.298 J 0.443 J 1.68 ND ND ND - ND ug/L 03/20/13 0.10 1.00 1 ND ND 0.258 J 0.327 J 0.420 J ND ND ND 1.68 ND ug/L 09/18/13 0.10 1.00 1 ND ND 0.105 J ND 0.484 J ND 0.331 J ND - ND ug/L 03/27/14 0.10 1.00 1 ND ND 0.199 J ND 0.556 J ND ND ND 2.19 ND ug/L 09/18/14 0.10 1.00 1 0.106 J ND 0.295 J ND 1.07 ND ND ND - ND ug/L 03/18/15 0.10 1.00 1 0.125 J ND 0.514 J 0.344 J 0.992 J ND ND ND 1.54 ND ug/L 09/23/15 0.10 1.00 1 ND ND 0.352 J 0.114 J 0.611 J ND ND ND - ND ug/L 03/17/16 0.10 1.00 1 0.134 J ND 0.130 J ND 1.04 ND ND ND 1.75 ND ug/L 09/21/16 0.10 1.00 1 0.146 J ND 0.277 J ND 1.08 ND ND ND - ND ug/L 03/21/17 0.10 1.00 1 ND ND 0.356 J 0.199 J 0.610 J ND ND ND 1.06 ND ug/L 09/20/17 0.10 1.00 1 ND ND ND ND 0.988 J ND ND ND - ND ug/L 03/21/18 0.10 1.00 1 ND ND 0.273 J ND 1.61 ND ND ND 2.66 ND ug/L 09/23/18 0.16 1.00 -- 0.262 J ND 0.293 J ND 1.32 ND ND ND - ND ug/L 03/26/19 0.16 1.00 -- 0.178 J ND 0.2692 J 0.279 J 1.96 ND ND ND 2.02 ND u /L 09/18/19 0.16 1.00 ND ND ND ND 1.66 ND ND ND ND Cadmium ug/L 12/05/94 - -- 1 ND ND 22 ND - -- -- -- ND -- NC2L=2 ug/L ug/L 02/14/95 - -- 1 ND ND 3 ND - -- -- -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 - -- 1 ND ND 1 ND - -- -- -- ND -- ug/L 10/30/95 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 04/08/96 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/24/96 - -- 1 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 - -- 1 ND -- ND ND - -- -- -- ND -- ug/L 101 9/97 - -- 1 ND 9 ND ND - -- -- -- ND -- ug/L 05/14/98 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 - -- 1 ND 5.6 ND ND - -- -- -- ND -- ug/L 10/29/99 - -- 1 ND 1.2 ND ND - -- -- -- ND -- ug/L 04/20/00 - -- 1 ND 2.3 1.7 ND ND -- - -- ND -- ug/L 11/07/00 - -- 1 ND 15 ND ND - -- - -- ND -- ug/L 05/15/01 -- -- 1 ND 3.2 ND ND - -- - -- ND -- ug/L 10/16/01 -- -- 1 ND 2 - ND - ND - -- ND -- ug/L 04/24/02 -- -- 1 ND 2 ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 1 ND 2 ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 1 ND 1.35 ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 1 ND 3.34 ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- 1 ND 11.8 ND ND ND ND -- -- ND -- ug/L 10/27/04 - -- 1 ND 1.31 1.28 1.08 1 ND -- -- ND -- ug/L 05/25/05 -- -- 1 ND 1.9 1.02 -- ND ND -- -- ND -- ug/L 10/04/05 -- -- 1 ND ND 1.39 ND 2.57 ND -- -- ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 -- -- 1 ND 1.73 J 1.27 ND ND ND -- -- ND ND ug/L 03/21/07 -- -- 1 1.57 J 0.65 J 2.35 J 2.08 J 2.5 J 1.38 J -- -- 1.4 J ND ug/L 10/02/07 - -- 1 ND ND 1.63 0.4 J ND ND -- -- ND ND ug/L 04/03/08 - -- 1 ND 0.2 J 0.9 J 0.47 J 0.29 J ND ND ND ND ND ug/L 10/29/08 - -- 1 ND 3.09 0.43 J 0.2 J ND ND ND ND ND ND ug/L 03/24/09 0.09 1.00 1 ND 0.22 J 0.18 J 1.06 0.61 J ND ND ND ND ND ug/L 09/22/09 0.36 1.00 1 0.667 J ND 0.659 J 0.627 J ND ND 1.24 ND -- ND ug/L 03/22/10 0.36 1.00 1 ND Dry ND ND ND ND ND ND -- ND ug/L 09/231 0 0.36 1.00 1 ND ND 0.493 J 0.618 J 0.416 J ND ND ND -- ND ug/L 03/1 11 0.36 1.00 1 ND 0.517 J ND ND 1.07 ND ND ND -- ND ug/L 09/21/11 0.36 1.00 1 ND ND 0.666 J 0.441 J 0.841 J ND ND ND - ND ug/L 03/21/12 0.36 1.00 1 ND ND 0.673 J ND 2.13 ND ND ND ND ND ug/L 09/20/12 0.36 1.00 1 ND ND 0.655 J ND 2.87 ND ND ND - ND ug/L 03/20/13 0.36 1.00 1 ND ND 3.30 ND 1.20 ND ND ND ND ND ug/L 09/18/13 0.36 1.00 1 ND ND 0.785 J ND 0.669 J ND ND ND - ND ug/L 03/27/14 0.36 1.00 1 ND ND 0.455 J ND 1.24 ND ND ND 0.453 J ND ug/L 09/18/14 0.36 1.00 1 ND ND 0.858 J ND 2.41 ND ND ND - ND ug/L 03/18/15 0.36 1.00 1 ND ND 2.18 ND 1.63 ND ND ND ND ND ug/L 09/23/15 0.36 1.00 1 ND ND 0.627 J ND 1.05 ND ND ND - ND ug/L 03/17/16 0.36 1.00 1 ND ND 0.456 J ND 2.00 ND ND ND ND ND ug/L 09/21/16 0.36 1.00 1 ND ND 0.3660 J ND 1.67 ND ND ND - ND ug/L 03/21/17 0.36 1.00 1 ND ND 1.27 B ND 2.28 B ND ND ND ND 0.591 J ug/L 09/20/17 0.36 1.00 1 ND ND 0.572 J ND 1.76 ND ND ND - ND ug/L 03/21/18 0.36 1.00 1 ND ND 0.618 J ND 3.00 ND ND ND 0.360 J ND (vedficaton event) ug/L 06/15/18 0.36 1.00 1 -- -- - -- 3.44 -- -- -- - ND (dissolved) ug/L 06/15/18 0.36 1.00 1 -- -- - -- 3.14 -- -- -- - ND ug/L 09/23/18 0.36 1.00 - ND ND ND ND 1.97 ND ND ND - ND ug/L 03/26/19 0.36 1.00 - ND ND ND ND 2.72 ND ND ND ND ND 09/18/19 0.36 1.00 ND ND 0.387 J ND 1.97 ND ND ND ND ZChromium L 12/05/94 - -- 10 ND ND 56 ND - -- -- -- ND -- NC 2L = 10 ug/L ug/L 02/14/95 - -- 10 ND ND ND ND - -- -- -- ND -- EPA MCL = 100 ug/L ug/L 04/03/95 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/30/95 - -- 10 11 ND ND ND - -- -- -- ND -- ug/L 04/08/96 - -- 10 5 ND ND ND - -- -- -- ND -- ug/L 10/24/96 - -- 10 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 - -- 10 3 -- ND 2 - -- -- -- 2 -- ug/L 10/29/97 - -- 10 3 8 2 2 - -- -- -- 1 -- ug/L 05/14/98 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 -- -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 -- -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 -- -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 10 ND ND ND ND ND ND -- -- ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 10 ND 20.1 ND -- ND ND - -- ND -- ug/L 10/04/0 -- -- 10 ND 14.9 ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 10 ND 11.4 ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 10 ND 11.3 ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 10 3.33 J 3.81 J 6.01 J 4.12 J 2.7 J 1.29 J - -- 1.44 J ND ug/L 10/02/07 - -- 10 9.55 B 9.44 B 7.31 B 4.47 B 5.99 B 12.3 B - -- 3.67 B 367 J ug/L 04/03/08 10 6.54 B 493 ... B 4.18 B 4.42 B 41 B 3.31 B 4.18 B 130 2.45 B 194 J ugL 10/29/08 10 7.45 J 355 8.07 J 6.10 J 8.55 11.3 5.24 . J 137 4.63 J ND ug/L 03/2409 07 100 10 ND 1.0 J 1.6 J 4.0 J 1.2 J ND ND 1.5 J ND ND ugL 09/22 1.0 10.0 10 1.36 J ND 1.99 J 3.28 J 1.14 J ND 1.61 J 1.51 J ND/0 ug/L 03/22/10 0 .0 00 10.0 10 ND D ND ND ND ND ND ND ND ugL 09/23/10 10 ND ND 15 J 4.38 J ND ND ND ND ND ug/L 03/16/11 . 10 10.0 10 2.55 J 132 J 2.90 J 3.29 J 1.60 J ND 3.34 J ND ND ugL 09/21/11 1.0 10.0 10 ND 6.75 J 5.20 J 12.4 ND ND ND ND - ND ug/L 03/21/12 1.0 10.0 10 2.15 J 3.60 J 2.25 J 4.57 J 3.36 J ND ND ND ND ND ug/L 09/20/12 1.0 10.0 10 ND ND 1.31 J 2.42 J 2.29 J ND ND ND - ND ug/L 03/20/13 1.4 10.0 10 2.48 J ND ND ND ND ND ND ND ND ND ug/L 09/181 3 1.4 10.0 10 ND 4.80 J 5.25 J 3.23 J ND ND ND ND - ND ug/L 03/27/14 1.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/1 81 4 1.4 10.0 10 ND 5.15 J 1.95 J 2.65 J 1.68 J ND ND ND -- ND ug/L 03/18/15 1.4 10.0 10 ND ND 7.41 J 2.76 J 2.45 J ND ND ND ND ND ug/L 09/23/15 1.4 10.0 10 ND 2.61 J 2.70 J 2.87 J 3.81 J ND ND ND - ND ug/L 03/17/16 1.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.4 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/21/17 1.4 10.0 10 ND ND ND ND ND ND 2.18 J ND 1A7 J ND ug/L 09/20/17 1.4 10.0 10 ND ND ND 1.51 J ND ND ND ND - ND ug/L 03/21/18 1.4 10.0 10 ND ND ND ND 1.79 J ND ND ND ND ND ug/L 09/23/18 1.4 10.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 1.4 10.0 - ND ND 1.54 J ND ND 2.04 J ND ND ND ND u /L 09/18/19 1.4 10.0 ND ND ND ND ND ND ND ND ND 4 GOLDER 2 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SINS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-8 AMW-1S AMW-ID AMW-2S AMW-2D MW-9 Cobalt ug/L 12/05/94 -- -- 10 ND 41 ND ND -- -- -- -- ND -- IMAC = 1 ug/L ug/L 02/14/95 -- -- 10 ND 48 ND ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/03/95 -- -- 10 ND 38 ND ND -- -- -- -- ND -- ug/L 10/30/95 -- -- 10 ND 34 ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- 10 ND 32 ND ND -- -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 -- -- 10 2 -- 19 2 - -- -- -- 3 -- ug/L 10/29/97 -- -- 10 ND 19 7 ND - -- -- -- ND -- ug/L 05/14/98 -- -- 10 ND 53.4 17.3 ND - -- -- -- ND -- ug/L 10/11/98 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 -- -- 10 ND 52.3 11.5 ND - -- - -- ND -- ug/L 10/29/99 -- -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- - 10 ND ND 12.5 ND 14.3 -- - -- ND -- ug/L 11/07/00 -- - 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 -- - 10 ND 14 ND ND - -- - -- ND -- ug/L 10/16/01 -- -- 1 0 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 10 ND 17.9 ND ND 16.1 ND - -- ND -- ug/L 10/01/02 -- -- 10 ND 11.4 ND ND 11.7 ND - -- ND -- ug/L 04/09/03 -- -- 10 ND 13.1 ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 10 ND 32.1 ND ND ND ND - -- ND -- ug/L 03/24/04 - -- 10 ND 94.9 16 ND ND ND - -- ND -- ug/L 10/27/04 - -- 10 ND 120 18.5 ND ND ND - -- ND -- ug/L 05/25/05 - -- 10 ND 35.5 16.8 -- 13.4 ND - -- ND -- ug/L 10/04/05 - -- 10 ND 23.5 16.2 ND 16.1 ND - -- ND -- ug/L 04/25/O6 - -- 10 ND 18.8 13.9 ND 16.1 ND - -- ND -- ug/L 10/04/O6 - -- 10 ND 15.4 13.4 ND 18.9 ND - -- ND ND ug/L 03/21/07 - -- 10 1.13 J 11.3 12.6 1.5 J 16.2 ND - -- ND ND ug/L 10/02/07 - -- 10 ND ND ND ND ND ND - -- ND ND ug/L 04/03/08 - -- 10 ND 12.4 ND ND 15.1 ND 12.5 ND ND ND ug/L 10/29/08 - -- 10 3.55 J 35.9 5.16 J 3.74 J 24.8 ND 3.91 J ND ND ND ug/L 03/24/09 0.6 10.0 10 0.6 J 3.1 J ND 5.8 J 10.7 ND 4.0 J ND ND ND ug/L 09/22/09 1.1 10.0 10 ND 4.81 J ND 2.50 J 10.8 ND ND ND - ND ug/L 03/22/10 1.1 10.0 10 ND Dry ND 6.33 J 3.47 J ND ND ND - ND ug/L 09/23/10 1.1 10.0 10 ND 2.13 J ND 9.21 J 3.42 J ND ND ND - ND ug/L 03/1 6/1 1 1.1 10.0 10 ND ND ND 2.87 J 8.51 J ND 1.26 J ND - ND ug/L 09/21/11 1.1 10.0 10 ND 3.73 J ND 7.48 J 9.15 J ND ND ND - ND ug/L 03/21/12 1.1 10.0 10 ND 3.48 J ND 3.74 J 18.4 ND ND ND ND ND ug/L 09/20/12 1.1 10.0 10 ND ND ND 3.20 J 16.0 ND 1.33 J ND - ND ug/L 03/20/13 1.1 10.0 10 1.32 J ND ND 3.67 J 5.62 J ND ND ND ND ND ug/L 09/18/13 1.1 10.0 10 ND 43.8 18.7 2.44 J 4.83 J ND 2.33 J ND - ND ug/L 03/27/14 1.1 10.0 10 ND 1.91 J ND 3.03 J 5.44 J ND 2.24 J ND 1.81 J ND ug/L 09/18/14 1.1 10.0 10 ND 5.56 J ND 5.11 J 9.65 J ND 1.23 J ND - ND ug/L 03/18/15 1.1 10.0 10 ND ND 2.87 J 5.00 J 7.67 J ND 1.78 J ND 1.67 J ND ug/L 09/23/15 1.1 10.0 10 ND 1.34 J ND 2.89 J 7.86 J ND ND ND - ND ug/L 03/17/16 1.1 10.0 10 ND 3.66 J 6.51 J 6.75 J 7.42 J ND ND ND 3.13 J ND ug/L 09/21/16 1.1 10.0 10 ND 1.75 J 4.61 J 9.16 J 7.40 J ND ND ND - ND ug/L 03/21/17 1.1 10.0 10 ND 1.66 J ND 2.62 J 7.47 J ND ND ND ND ND ug/L 09/20/17 1.1 10.0 10 ND ND ND 10.4 6.94 J ND ND ND - ND (verification event) ug/L 12/19/17 1.1 10.0 10 -- -- - 10.3 -- -- -- -- - ND (dissolved) ug/L 12/19/17 1.1 10.0 10 -- -- - 10.5 -- -- -- -- - ND ug/L 03/21/18 1.1 10.0 10 ND 2.32 J ND 9.96 J 9.52 J ND ND ND 2.10 J ND ug/L 09/23/18 1.4 10.0 - ND ND 5.08 J 3.68 J 7.03 J ND ND ND - ND ug/L 03/26/19 1.4 10.0 - ND ND 8.52 J 17.06 7.36 J ND ND ND 2.32 J ND (dissolved) ug/L 03/26/19 1.4 10.0 - -- -- -- 17.6 -- -- -- -- -- ND 09/18/19 1.4 10.0 ND ND 4.89 J 7.39 J 6.08 J ND ND ND ND ZCopper L 12/05/94 - -- 10 ND ND 19 ND -- -- -- -- ND -- NC 2L = 1000 ug/L ug/L 02/14/95 - -- 10 10 ND ND ND - -- - -- 16 -- EPA MCL = 1300 ug/L" ug/L 04/03/95 - -- 10 ND ND 13 12 - -- - -- 14 -- ug/L 10/30/95 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 - -- 10 13 -- ND ND - -- - -- 10 -- ug/L 04/15/97 - -- 10 20 -- ND ND - -- - -- ND -- ug/L 10/29/97 - -- 10 20 ND ND ND - -- - -- ND -- ug/L 05/14/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 0 /04/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 -- -- 10 ND ND ND ND -- -- - -- ND -- ug/L 04/20/00 - -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 0115/01 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 - -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 041 9/03 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 015/05 - -- 10 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 - -- 10 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 - -- 10 12.4 12.8 4.23 J 5.28 J 5.41 J 5.15 J - -- 9.92 J ND ug/L 10/02/07 - -- 10 33.9 16.7 B 6.61 B 7.24 B 9.14 B 6.91 B - -- 5.94 B 6.41 J ug/L 04/03/08 - -- 10 23.4 23.9 4.54 B 6.53 B 5.54 B 5.75 B 5.89 B 10.6 B 4.58 B 4.46 J ug/L 10/29/O8 - -- 10 16.5 145 7.91 J 8.17 J 8.61 9.49 6.93 J 7.82 J 6.28 J ND ug/L 03/24/09 0.81 10.0 10 2.32 J 4.96 J ND ND ND ND ND ND ND ND ug/L 09/22/09 1.6 10.0 10 5.15 J 6.17 J ND ND ND ND ND ND -- ND ug/L 03/22/10 1.6 10.0 10 1.84 J Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 1.6 10.0 10 1.77 J ND ND 9.93 J ND ND ND ND -- ND ug/L 03/16/11 1.6 10.0 10 9.85 J 6.75 J ND 2.99 J 1.73 J 1.66 J 4.98 J ND -- ND ug/L 09/21/11 1.6 10.0 10 4.10 J 12.8 ND 14.2 ND ND ND ND -- ND ug/L 03/21/12 1.6 10.0 10 8.77 J ND ND 2.96 J ND ND ND ND ND ND ug/L 09/20/12 1.6 10.0 10 1.77 J 3.29 J ND 2.54 J ND ND ND ND - ND ug/L 03/20/13 1.6 10.0 10 9.21 J 5.01 J 1.84 J 2.57 J ND 1.99 J ND ND ND ND ug/L 09/1 8/1 3 1.6 10.0 10 5.69 J 9.55 J ND ND ND ND 1.99 J ND -- ND ug/L 03/2714 1.6 10.0 10 ND 2.51 J ND 2.75 J ND ND ND ND ND ND ug/L 09/11/14 1.6 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 1.6 10.0 10 2.54 B ND ND ND ND ND ND ND 2.90 B 1.74 J ug/L 09/23/15 1.6 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/17/16 1.6 10.0 10 ND ND ND ND ND ND ND ND ND 2.01 J ug/L 09/21/16 1.6 10.0 10 1.65 B ND ND 4.19 B 1.94 B 2.20 B 1.73 B 1.95 B - 3.37 J ug/L 03/21/17 1.6 10.0 10 ND ND ND ND ND ND ND ND ND 1.97 J ug/L 09/20/17 1.6 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 1.6 10.0 10 1.72 B ND ND ND ND ND ND ND ND 1.87 J ug/L 09/23/18 1.6 10.0 -- ND ND ND ND 1.98 J ND ND ND -- ND ug/L 03/236 9 1.6 10.0 - ND 2.42 J ND ND ND 2.66 J ND ND ND ND u /L 09/18/19 1.6 10.0 1,78 B 1.81 B ND ND 1.65 B 2.21 B ND ND 5.73 J Lead ug/L 12/05/94 - -- 10 ND 7 27 7 - -- - -- ND -- NC 2L = 15 ug/L ug/L 02/14/95 - -- 10 ND 10 5 ND - -- - -- ND -- EPA MCL = 15 ug/0 ug/L 04/03/95 - -- 10 ND 12 ND ND - -- - -- ND -- ug/L 10/30/95 - -- 10 7 19 ND ND - -- - -- ND -- ug/L 04/08/96 - -- 10 ND 6 ND ND - -- - -- ND -- ug/L 10/24/96 - -- 10 8 -- 7 ND - -- - -- 13 -- ug/L 04/15/97 - -- 10 13 -- ND 12 - -- - -- 12 -- ug/L 10/29/97 - -- 10 9 36 5 11 - -- - -- ND -- ug/L 05/14/98 - -- 10 ND 14.4 ND ND - -- - -- ND -- ug/L 10/11/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 0104/99 - -- 10 ND 11.9 ND ND - -- - -- ND -- ug/L 10/29/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 - -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 10 24 ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 10 ND 61.3 ND 17.4 ND ND - -- ND -- ug/L 05/25/05 - -- 10 ND 11.9 ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 10 ND 12.7 ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 10 ND 6.56 J 3.69 J ND 3.14 J ND - -- 1.9 J ND ug/L 10/02/07 -- -- 10 69.2 J 7.18 J 1.39 B 0.9 B 0.80 B 0.56 S - -- 0.57 B 0.49 J ug/L 04/03/08 -- -- 10 75.8 J 16.4 ND 8 J fi.43 J 3.78 J 6 6 J 12.5 6.253 J ND ug/L 10/29/08 - -- 10 75.9 J 84.7 7.72 J 6.83 J 9.41 9.08 8.50 J 6.93 J 4.54 J ND ug/L 03/24/09 1.6 10.0 10 3.3 J 5.6 J 1.6 J 6.2 J 2.5 J 1.6 J 3.1 J ND ND ND ug/L 09/22/09 1.9 10.0 10 3.52 J 2.55 J ND 3.17 J 2.50 J ND 3.96 J 1.95 J - ND ug/L 03/221 0 1.9 10.0 10 ND Dry ND 2.20 J ND ND ND ND - ND ug/L 09/23/10 1.9 10.0 10 ND ND ND 12.2 ND ND ND ND -- ND ug/L 03/16/11 1.9 10.0 10 4.92 J ND ND 3.40 J ND ND 25.6 2.69 J -- ND ug/L 09/21/11 1.9 10.0 10 ND 15.5 3.27 J 18.5 2.57 J ND ND ND -- ND ug/L 03/21/12 1.9 10.0 10 4.38 J ND ND ND ND ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 2.53 B 3.10 B 4.18 B 5.91 B 4.90 B 4.40 B 4.82 B 3.00 B - 2.70 J ug/L 03/20/13 1.9 10.0 10 ND ND 3.46 J ND ND ND ND ND ND ND ug/L 09/1 8/1 3 2.1 10.0 10 ND 17.4 ND ND ND ND 6.58 J ND - ND ug/L 03/27/14 2.1 10.0 10 ND 2.2fi J ND 2.33 J ND ND ND ND ND ND ug/L 09/18/14 2.1 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 2.1 10.0 10 ND ND 3.32 J ND ND ND ND ND ND ND ug/L 09/23/15 2.1 10.0 10 ND ND ND ND 3.10 J ND 3.15 J ND - ND ug/L 03/1716 2.1 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 3.1 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 3.1 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/17 3.1 10.0 10 ND 3.45 J ND ND 3.75 J ND ND 3.40 J -- ND ug/L 03/21/18 3.1 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/16 3.1 10.0 - ND ND ND ND ND ND ND ND - 8.83 J ug/L 03/26/19 3.1 10.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 3.1 10.0 ND ND ND ND ND ND ND ND ND GOLDER 3 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MWS MW-6 MW-7 Ml AMW-1S AMW-1D AMW-2S AMW-213 MW-9 Mercury ug/L 10/30/95 -- -- 0.2 0.5 ND 0.9 0.9 -- -- -- - 0.8 -- NC 21 = 1 ug/L ug/L 10/24/96 - -- 0.2 0.7 -- ND ND -- -- -- -- ND -- EPA MCL = 2 ug/L ug/L 10/29/97 - -- 0.2 ND ND 1.9 0.6 - -- -- - ND -- ug/L 05/14/98 - -- 0.2 ND ND 2 0.2 - -- -- - ND -- ug/L 10/11/98 - -- 0.2 ND ND ND 0.2 - -- -- - ND -- ug/L 06/04/99 - -- 0.2 ND ND 0.5 ND - -- -- -- ND -- ug/L 10/29/99 - -- 0.2 ND ND 0.4 ND - -- -- - ND -- ug/L 041 0/00 - -- 0.2 ND ND 1.0 ND ND -- -- -- ND -- ug/L 11/07/00 - -- 0.2 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 0.2 ND ND 0.4 ND - -- - -- ND -- ug/L 10/16/01 - -- 0.2 ND ND 0.3 0.3 - ND - -- 0.3 -- ug/L 041 4/02 - -- 0.2 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 0.2 ND ND 0.3 ND ND ND - -- ND -- ug/L 04/09/03 - -- 0.2 ND ND 0.3 ND ND ND - -- 0.3 -- ug/L 10/20/03 - -- 0.2 ND ND 0.45 ND ND ND - -- ND -- ug/L 0314/04 - -- 0.2 ND ND 0.73 0.258 ND ND -- -- ND -- ug/L 10/27/04 - -- 0.2 ND ND 0.91 ND ND ND -- -- ND -- ug/L 05/25/05 - -- 0.2 ND ND 0.72 -- ND ND -- -- ND -- ug/L 10/04/05 - -- 0.2 ND ND ND ND ND ND -- -- ND -- ug/L 04/25/O6 - -- 0.2 ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 - -- 0.2 ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 - -- 0.2 ND ND 0.134 J 0.242 J ND ND -- -- ND ND ug/L 10/02/07 - -- 0.2 ND ND ND 0.709 ND ND -- -- ND ND ug/L 04/03/08 - -- 0.2 ND ND ND 0.489 ND ND ND ND ND ND ug/L 10/29/08 - -- 0.2 ND 0.145 J ND 0.503 ND ND ND ND ND ND ug/L 03/24/09 0.11 0.200 0.2 ND ND ND 1.33 ND ND ND ND 0.14 J ND ug/L 09/22/09 0.054 0.200 0.2 ND ND 0.0926 J 0.419 -- -- -- -- - ND ug/L 03/22/10 0.054 0.200 0.2 ND Dry ND ND ND ND ND ND - ND ug/L 09/23/10 0.17 0.200 0.2 ND ND ND 0.371 ND ND ND ND - ND (dissolved) ug/L 09/23/10 0.17 0.200 0.2 -- -- - ND -- -- -- -- - -- ug/L 03/16/11 0.17 0.200 0.2 ND ND ND ND ND ND 0.178 J ND - ND ug/L 09/21/11 0.17 0.200 0.2 ND ND ND 0.683 ND ND 0.225 ND -- ND ug/L 03/21/12 0.17 0.200 0.2 ND ND ND ND ND ND ND ND -- ND ug/L 09/20/12 0.17 0.200 0.2 ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.17 0.200 0.2 ND ND ND ND ND ND ND ND -- ND ug/L 09/18/13 0.17 0.200 0.2 ND ND ND ND ND ND 0.302 ND -- ND ug/L 03/27/14 0.17 0.200 0.2 ND ND ND ND ND ND 0.308 ND -- ND ug/L 09/18/14 0.17 0.200 0.2 ND ND ND ND ND ND 1.53 ND -- ND ug/L 03/18/15 0.17 0.200 0.2 ND ND ND ND ND ND 1.49 ND -- ND ug/L 09/23/15 0.17 0.200 0.2 ND ND ND ND ND ND 0.226 ND -- ND ug/L 03/17/16 0.17 0.200 0.2 ND ND ND ND ND ND 0.527 ND -- ND ug/L 09/21/16 0.17 0.200 0.2 ND ND ND ND ND ND 0.810 ND -- ND ug/L 03/21/17 0.17 0.200 0.2 ND ND ND ND ND ND 0.213 ND -- ND ug/L 09/20/17 0.0990 0.200 0.2 ND ND ND ND ND ND 0.474 ND -- ND ug/L 03/21/18 0.15 0.200 0.2 ND ND ND ND ND ND 1.12 ND -- ND (verification event) ug/L 06/15/18 0.15 0.200 0.2 -- -- - -- - -- 0.517 -- -- ND (dissolved) ug/L 06/15/18 0.15 0.200 0.2 -- -- - -- - -- ND -- -- ND ug/L 09/23/18 0.15 0.200 -- ND ND ND ND ND ND 0.313 ND -- ND ug/L 03/26/19 0.15 0,200 -- ND ND ND ND ND ND 0.379 ND 0.164 J ND u /L 09/18/19 0.15 0.200 ND ND ND ND ND ND 0.487 ND ND Nickel ug/L 12/05/94 - -- 50 ND ND ND ND -- -- - -- ND NC 21 100 ug/L ug/L 02/14/95 - -- 50 ND ND ND ND - -- - -- ND -- EPA MCL = No Standard ug/L 04/03/95 - -- 50 ND ND ND ND -- -- - -- ND -- ug/L 10/30/95 - -- 50 ND ND ND ND -- -- - -- ND -- ug/L 04/08/96 - -- 50 ND ND ND ND -- -- - -- ND -- ug/L 10/24/96 - -- 50 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 - -- 50 ND -- ND ND - -- - -- ND -- ug/L 10/29/97 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 05/14/98 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 -- -- 50 ND ND ND ND -- -- - -- ND -- ug/L 04/20/00 -- -- 50 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 50 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 - -- 50 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 - -- 50 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 - -- 50 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 - -- 50 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 - -- 50 ND 1.61 J ND ND ND ND - -- ND ND ug/L 10/02/07 - -- 50 2.75 B 9.04 J 0.67 B 0.9 B 4.65 J 8.72 J - -- 0.24 B 0.8 J ug/L 04/03/OB - -- 50 ND ND ND ND ND ND 5.89 J 7.09 J ND ND ug/L 10/29/08 - -- 50 ND 47.3 J ND ND 8.13 J 7.57 J 6.40 J 4.99 J ND ND ug/L 03/24/09 0.6 10.0 50 ND 3.9 J ND 2.8 J 2.5 J 0.9 J 2.2 J ND ND ND ug/L 09/22/09 1.8 10.0 50 ND 3.77 J ND ND 2.54 J 2.04 J ND ND - ND ug/L 03/22/10 1.8 10.0 50 ND Dry ND ND ND ND ND ND - ND ug/L 09/231 0 1.8 10.0 50 ND ND ND ND ND ND ND ND - ND ug/L 03/1 11 1.8 10.0 50 ND 2.28 J ND ND ND ND ND ND - ND ug/L 09/21/11 1.8 10.0 50 ND 4.59 J ND ND 2.04 J ND ND ND - ND ug/L 03/21/12 1.8 10.0 50 ND 3.62 J ND ND 3.14 J ND ND ND ND ND ug/L 09/20/12 1.8 10.0 50 ND ND ND ND 2.62 J ND ND ND - ND ug/L 03/20/13 1.8 10.0 50 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 1.8 10.0 50 ND 8.99 J 4.74 J ND ND ND ND ND - ND ug/L 03/27/14 1.8 10.0 50 ND 1.80 J ND ND ND ND ND ND ND ND ug/L 09/18/14 1.8 10.0 50 ND 6.47 J ND ND ND ND ND ND - ND ug/L 03/18/15 1.8 10.0 50 ND ND 2.55 J ND 2.22 J ND ND ND ND ND ug/L 09/23/15 1.8 10.0 50 ND 6.60 B ND 3.03 B 2.84 B ND ND ND -- 2.22 J ug/L 03/17/16 1.8 10.0 50 ND 4.55 J ND ND ND ND ND ND ND ND ug/L 09/21/16 2.2 10.0 50 ND 2.93 J ND 4.55 J 2.21 J 2.87 J ND ND - ND ug/L 03/21/17 2.2 10.0 50 4.77 B 3.44 B 2.65 B 3.16 B 4.33 B 2.57 B 2.24 B 2.32 B 1.76 B 2.69 J ug/L 09/20/17 2.2 10.0 50 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 2.2 10.0 50 ND 3.42 J ND ND ND ND ND ND ND ND ug/L 09/23/18 2.2 10.0 - ND ND ND 2.61 B 2.36 B ND ND ND - 10.1 ug/L 03/26/19 2.2 10.0 - ND 57.1 2.98 J ND 3.79 J ND ND ND ND ND u /L 09/18/19 2.2 10.0 ND 4.32 J ND ND ND ND ND ND ND Selenium ug/L 12/05/94 - -- 10 ND ND ND ND - -- - -- ND -- NC 21 = 20 ug/L ug/L 02/14/95 - -- 10 ND ND ND ND - -- - -- ND -- EPA MCL = 50 ug/L ug/L 04/03/95 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/30/95 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 - -- 10 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 - -- 10 ND -- ND ND - -- - -- ND -- ug/L 10/29/97 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/14/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 10 ND 61.1 ND ND - -- - -- ND -- ug/L 10/29/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 10 ND 24.7 ND ND - -- - -- ND -- ug/L 10/16/01 - -- 10 ND ND ND ND - 20.6 - -- ND -- ug/L 04/24/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 1011/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 10 ND 25.3 ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 10 ND 26.6 ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 10 ND 23.4 ND ND ND ND - -- ND ND ug/L 03/21/07 - -- 10 9.46 J 23.4 10.7 J ND ND ND - -- ND ND ug/L 10/02/07 - -- 10 ND 7.49 J ND 11.1 ND ND - -- 8.68 J ND ug/L 04/03/08 - -- 10 ND 10.7 ND ND 10.9 ND 9.54 J 7.51 J ND ND ug/L 10/29/08 - -- 10 ND 37.5 ND ND 1.94 ND ND ND ND ND ug/L 03/24/09 3.4 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/109 2.7 10.0 10 6.68 B ND 8.38 B 4.55 B ND 7.33 B 4.11 B 5.98 B - 6.41 J ug/L 03/22/10 0.83 1.00 10 ND Dry ND ND 0.962 J ND ND ND - ND ug/L 09/2310 5.2 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/1 11 2.7 10.0 10 ND ND ND ND 5.08 B ND ND ND - 3.32 J ug/L 0.1111 2.7 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/21/12 2.7 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 2.7 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 4.5 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/108 3 5.0 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/27/14 5.0 10.0 10 ND ND ND ND ND ND ND ND 5.67 (ND) J ND ug/L 09/1814 5.0 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 5.0 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 5.0 10.0 10 ND ND ND ND ND ND ND ND -- ND 03/17/16 5.0 10.0 10 ND ND ND ND ND ND ND ND ND ND %ug/L L 09/21/16 6.2 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 6.2 10.0 10 ND ND ND ND ND ND ND ND ND 14.1 J ug/L 09/20/17 6.2 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 6.2 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 6.2 10.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 6.2 10.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 6.2 10.0 ND ND ND ND ND ND ND ND ND GOLDER 4 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring ConstituentlParameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-213 MW-9 Silver ug/L 12/05/94 -- -- 10 ND ND ND ND -- -- -- - ND -- NC2L=20 ug/L ug/L 02/14/95 -- -- 10 ND ND ND ND -- -- -- -- 11 -- EPA MCL = 100 ug/L ug/L 04/03/95 -- -- 10 ND ND ND ND -- -- -- - ND -- ug/L 101 0/95 -- -- 10 ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 -- -- 10 ND ND ND ND - -- -- - ND -- ug/L 10/24/96 -- -- 10 ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 -- -- 10 0.9 -- 0.9 0.7 - -- -- - 0.3 -- ug/L 10/29/97 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 -- -- 10 ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 04/20/00 -- -- 10 ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 05/15/0, -- -- 10 ND 11.3 ND ND - -- - -- ND -- ug/L 10,16/0, -- -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 10 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 10 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 10 ND 0.64 J 3.42 J 0.5 J 1.14 J 0.46 J - -- 3.18 J ND ug/L 10/02/07 -- -- 10 ND 1.82 J 0.91 J ND 0.86 J ND - -- ND ND ug/L 04/03/08 -- -- 10 ND 0.97 J 2.04 J ND 0.94 J ND 1.48 J ND ND ND ug/L 10/29/08 -- -- 10 4.74 J 6.91 J 5.23 J 5.00 J 6.32 J 5.19 J 4.91 J 4.33 J 5.24 J ND ug/L 03/24/09 1.0 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 1.9 10.0 10 ND ND ND ND 2.24 J ND ND ND -- ND ug/L 03/22/10 1.9 10.0 10 ND Dry ND 3.34 J ND ND ND ND -- ND ug/L 09/23/10 1.9 10.0 10 ND 2.52 J ND 3.05 J ND ND ND ND -- ND ug/L 03/i6/11 1.9 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 1.9 10.0 10 ND 3.73 J ND 2.33 J ND ND ND ND - ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND ND ND ND ND - ND ug/L 03/20/13 1.9 10.0 10 ND ND 7.00 B 3.58 B 3.31 B ND 2.17 B ND ND 2.11 J ug/L 09/18/13 1.9 10.0 10 ND 2.92 J 4.35 J 2.07 J ND ND ND ND - ND ug/L 03/27/14 1.9 10.0 10 ND ND 1.98 J ND ND ND ND ND ND ND ug/L 09/18/14 1.9 10.0 10 ND ND ND ND ND ND ND ND -- ND ug/L 03/18/15 1.9 10.0 10 ND ND 4.00 J ND 2.05 J ND ND ND ND ND ug/L 09/23/15 1.9 10.0 10 ND 6.68 B 1.97 B 3.26 B ND ND ND ND - 4.69 J ug/L 03/17/16 1.9 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.9 10.0 10 ND ND ND 9.23 J ND ND ND ND - ND ug/L 0.'/17 1.9 10.0 10 ND ND 1.06 B 0.849 B ND 1.23 B ND ND 1.04 B 0.823 J ug/L 09/20/17 1.9 10.0 10 ND ND ND 2826 J ND ND ND ND - ND ug/L 03/21/18 1.9 10.0 10 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.9 10.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 1.9 10.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 1.9 10.0 ND ND ND ND ND ND ND ND ND Thallium ug/L 12/05/94 - -- 5.5 ND ND ND ND - -- - -- ND -- IMAC = 0.2 ug/L ug/L 02/14/95 - -- 5.5 ND ND ND ND - -- - -- ND -- EPA MCL = 2 ug/L ug/L 04/03/95 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 101 0/95 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 - -- 5.5 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 - -- 5.5 ND -- ND ND - -- - -- ND -- ug/L 101 9/97 - -- 5.5 1 1 1 1 - -- - -- 2 -- ug/L 05/14/98 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 5.5 13.7 ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 5.5 ND ND ND ND - -- - -- ND -- ug/L 06/21/01 - -- 5.5 ND -- ND ND - -- - -- ND -- ug/L 10/16/01 - -- 5.5 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 5.5 ND 22.4 ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 5.5 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 5.5 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 5.5 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 - -- 5.5 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 - -- 5.5 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 - -- 5.5 ND 77.1 22 -- ND ND - -- ND -- ug/L 10/04/0 - -- 5.5 ND 58.5 54.6 17.8 ND ND - -- ND -- ug/L 04/25/06 - -- 5.5 ND 81.3 24.2 ND ND ND -- -- ND -- ug/L 10/04/06 - -- 5.5 ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 - -- 5.5 ND ND 24 ND ND ND -- -- ND ND ug/L 10/02/07 - -- 5.5 ND ND ND ND ND ND -- -- ND ND ug/L 04/03/08 - -- 5.5 ND ND ND ND ND ND -- -- ND ND ug/L 10/29/08 - -- 5.5 ND 8.90 ND 6.97 9.61 ND -- -- ND ND ug/L 03/24/09 0.036 1.00 5.5 0.051 B 0.090 B 0.080 B 0.242 B 0,280 B ND ND ND ND 0.092 J ug/L 09/22/09 0.11 1.00 5.5 ND ND ND 0.404 J 0.212 J ND ND ND -- ND ug/L 03/2210 0.11 1.00 5.5 ND Dry 0.118 J 0.620 J 0.169 J ND ND ND -- ND ug/L 09/23/10 0.11 1.00 5.5 ND ND 0.124 J 1.18 J ND ND ND ND -- ND ug/L 03/16/11 0.11 1.00 5.5 ND ND 0.518 J 1.12 J 0.274 J 0.491 J 0.514 J ND -- ND ug/L 09/21/11 0.11 1.00 5.5 ND ND ND 1.53 J ND ND ND ND - ND ug/L 03/21/12 0.11 1.00 5.5 ND ND 0.119 J 1.31 J 0.418 J ND ND ND ND ND ug/L 09/20/12 0.11 1.00 5.5 ND 0.144 J 0.155 J 1.09 J 0.512 J ND ND ND - ND ug/L 03/20/13 0.11 1.00 5.5 0.117 J ND 0.413 J 0.659 J 0.487 J ND ND ND ND ND ug/L 09/18/13 0.11 1.00 5.5 ND 0.127 B 0.604 B 0.609 B 0.459 B ND ND ND - 0.142 J u 03/27/14 0 1. 5.5 ND 0.13 J 0171 J 0.637 J 0.340 J ND ND ND ND ND 09/1814 0.11 5.5 ND ND 0.4 J 0.815 J 0.6 J ND NDug ND ND ug/L 03/18/15 0.11 1.0 . ND ND ND u 09/23/15 .11 0 55 ND ND 0225 J 09 0.5gL 50 J ND ND ND ND ug/L 03/1716 0 .00 10 55 ND ND 0.377 J 0.400 J 0.552 J ND ND ND ND ND ugL 09/21/1 1.00 55 ND ND 0.427 J 0.553 J 0.69 J ND ND ND - ND 21/1 0.11 1.00 55 0.153 J 0175 J 0 J 1.25 J 0.021 J 0.30 J 0.364 J 09J 0.189 J ND L 7 09/20/17 .11 1.0 5.5 0.386 J 0.28 J 0.369 .446 J 6 J .828 0.945 J .3929 J 0.409 0.20 J 32J - ND u 03/211 0.55 5.005 5 ND J 1.08 Jg/L ND ND ND ND ND ugL 09/23/18 0.55 5.00 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 0.22 2.00 - ND ND 0.565 J 0.344 J 0.547 J ND ND ND ND ND u /L 09/18/19 0.22 2.00 ND ND 0.376 J 0.485 J 0.322 J ND ND ND ND Tin ug/L 10/30/95 - -- - ND ND ND ND - -- - -- ND -- IMAC = 2000 ug/L ug/L 10/24/96 - -- - ND -- ND ND - -- - -- ND -- EPA MCL = No Standard ug/L 10/29/97 - -- - ND -- ND ND - -- - -- ND -- ug/L 03/24/09 1.1 10.0 100 ND ND 1.4 J 5.4 J 1.3 J 2.0 J 1.5 J ND ND ND ug/L 03/22/10 2.1 10.0 100 ND Dry ND 2.38 J - -- - -- -- ND ug/L 03/16/11 2.1 10.0 100 2.50 J 3.17 J 5.65 J 7.24 J - -- - -- -- ND ug/L 03/21/12 2.1 10.0 100 ND 3.86 J 3.42 J 4.51 J - -- - -- -- ND ug/L 03/20/13 2.1 10.0 100 ND 3.86 J 3.79 J 6.88 J - -- - -- -- ND ug/L 03/27/14 2.1 10.0 100 ND ND ND ND - -- - -- -- ND ug/L 03/1 8/1 5 2.1 10.0 100 ND ND ND ND - -- - -- -- ND ug/L 03/17/16 2.1 10.0 100 ND ND ND ND - -- - -- -- ND ug/L 03/21/17 2.1 10.0 100 ND 9.06 J 7.24 J 8.42 J - -- - -- -- ND ug/L 03/21/18 2.1 10.0 100 ND ND ND ND - -- - -- -- ND u /L 03/26/19 2.9 10.0 ND ND ND ND ND Vanadium ug/L 12/05/94 - -- 25 ND ND ND ND - -- - -- ND -- IMAC = 0.3 ug/L ug/L 02/14/95 - -- 25 ND ND ND ND - -- - -- ND -- EPAMCL=No Standard ug/L 04/03/95 - -- 25 ND ND ND ND - -- - -- ND -- ug/L 10/30/95 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 -- -- 25 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 -- -- 25 13 -- ND 5 - -- - -- 6 -- ug/L 10/29/97 - -- 25 ND ND ND ND - -- - -- ND -- ug/L 05/14/98 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 -- -- 25 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 25 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 -- -- 25 ND ND ND ND -- -- - -- ND -- ug/L 05/15/01 -- -- 25 ND ND ND ND -- -- - -- ND -- ug/L 10/i6/01 -- -- 25 ND ND ND ND -- ND - -- ND -- ug/L 04/24/02 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 25 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 25 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 25 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 25 3.81 J 4.21 J ND 1.31 J ND ND - -- ND ND ug/L 10/02/07 -- -- 25 17.1 J 12.9 J 5.6 J ND ND ND - -- ND ND ug/L 04/03/08 -- -- 25 9.73 J 10.7 J ND ND ND ND ND 5.13 J ND ND ug/L 10/29/08 - -- 25 4.88 J 68.9 10.3 J 0.52 J 1.37 J 3.74 J 0.86 J ND ND ND ug/L 03/24/09 0.7 10.0 25 2.2 J 3.2 J 1.7 J 9.0 J ND ND 3.0 J 0.9 J 0.7 J ND ug/L 09/22/09 1.4 10.0 25 3.31 J 1.97 J ND 5.45 J ND ND 6.35 J 1.52 J - ND ug/L 03/22/0 1.4 10.0 25 1.75 J Dry ND 1.76 J ND ND 1.78 J 1.42 J - ND ug/L 09/23/10 1.4 10.0 25 ND ND ND 14.7 J ND ND 4.79 J ND - ND ug/L 03/16/11 1.4 10.0 25 4.98 J 2.77 J ND ND ND ND 15.3 J ND - ND ug/L 01/21/11 1.4 10.0 25 2.21 J 8.14 J 2.88 J 17.3 J ND ND 11.1 J ND - ND ug/L 03/21/12 1.4 10.0 25 4.72 J ND ND ND ND ND 1.70 J ND ND ND ug/L 09/20/12 1.4 10.0 25 1.79 J 1.77 J ND 4.28 J ND ND 3.65 J ND - ND ug/L 03/20/13 1.4 10.0 25 5.60 J 2.36 J ND 2.47 J ND ND ND ND ND ND ug/L 09/18/13 1.4 10.0 25 2.71 J 12.4 J ND ND ND ND 9.96 J ND - ND ug/L 03/27/14 1A 10.0 25 ND 1.93 J ND ND ND ND 5.88 J ND ND ND ug/L 09/18/14 1.4 10.0 25 ND ND ND ND ND ND 4.57 J ND - ND ug/L 03/18/15 1.4 10.0 25 ND ND ND ND ND ND 7.02 J ND 1.53 J ND ug/L 09/23/15 1.4 10.0 25 1.51 J 1.43 J ND ND ND ND 1.69 J 1.45 J - ND ug/L 03/17/16 1.4 10.0 25 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 1.4 10.0 25 ND ND ND 3.10 J ND ND 2.05 J ND - ND ug/L 03/21/17 1.4 10.0 25 19.9 J 1.96 B ND 2.51 B 0.807 B ND 0.903 B 1.05 B ND 0.589 J ug/L 09/20/17 1.4 10.0 25 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 1.4 10.0 25 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 1.4 10.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 1.4 10.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 1.4 10.0 ND ND ND ND ND ND ND ND ND 4 GOLDER 5 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Zinc ug/L 12/05/94 -- -- 10 21 ND 33 20 -- -- -- -- 82 -- NC 2L = 1000 ug/L ug/L 02/14/95 -- -- 10 33 44 29 69 -- -- -- -- 113 -- EPA MCL = 5000 ug/L' ug/L 04/03/95 -- -- 10 29 48 26 29 - -- -- -- 20 -- ug/L 10/30/95 -- -- 10 25 30 ND ND - -- -- -- 23 -- ug/L 04/08/96 -- -- 10 44 63 22 67 - -- -- -- 36 -- ug/L 10/24/96 -- -- 10 37 -- 22 18 - -- -- -- 39 -- ug/L 04/15/97 -- -- 10 50 -- 50 30 - -- -- -- 40 -- ug/L 10/29/97 -- -- 10 ND 340 ND ND - -- -- -- ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 -- -- 10 ND ND ND ND -- -- -- -- ND -- ug/L 06/04/99 -- -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 -- -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 10 ND ND ND ND 20.6 -- - -- ND -- ug/L 11/07/00 -- -- 10 ND ND ND ND - -- - -- ND -- 05/15/0, -- -- 10 ND ND ND ND - -- - -- ND -- Iug/L L 10,16/0, -- -- 10 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/05 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 -- -- 10 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 -- -- 10 15.6 J 124 6.92 J 10.1 J 12.1 J 3.82 J - -- 7.14 J ND ug/L 10/02/07 -- -- 10 44 49.1 12.6 J 5.43 J 6.23 J ND - -- 4.53 J ND ug/L 04/03/08 -- -- 10 31.9 46 5.82 J 10.4 4.83 J 4.06 J 14.1 27.7 5.53 J ND ug/L 10/29/08 -- -- 10 20.1 380 29.0 6.90 J 5.37 J ND 5.37 J ND 6.63 J ND ug/L 03/24/09 3.4 10.0 10 10.7 B 56.3 9.3 B 38.3 4.1 B 3.4 B 7.7 B ND 4.1 B 3.4 J ug/L 09/22/09 3.8 10.0 10 13.8 12.3 4.56 J 12.8 7.02 J 5.92 J 18.0 8.77 J -- ND ug/L 03/22/10 3.8 10.0 10 9.18 J Dry 8.52 J 36.7 15.6 7.21 J 11.2 7.25 J -- ND ug/L 09/23/10 3.8 10.0 10 ND ND 5.357 J 168 4.30 J 5.86 J ND ND -- ND ug/L 03/16/11 3.8 10.0 10 17.6 36.7 7.03 J 611 4.64 J 17.5 44.8 4.77 J - ND ug/L 09/21/11 3.8 10.0 10 9.32 J 44.1 9.85 J 430 4.44 J 11.7 14.2 4.57 J -- ND ug/L 03/21/12 3.8 10.0 10 14.9 28.8 ND 48.3 ND 6.06 J ND ND ND ND ug/L 09/20/12 3.8 10.0 10 5.18 J 6.60 J ND 173 6.69 J 5.19 J 4.68 J 3.87 J -- ND ug/L 03/20/13 3.8 10.0 10 21.3 12.5 6.76 J 60.1 9.19 J 6.32 J ND 5.00 J 12.0 ND ug/L 09/18/13 3.8 10.0 10 12.0 45.7 5.04 J 40.5 4.40 J ND 27.3 ND -- ND ug/L 03/27/14 3.8 10.0 10 ND 11.3 ND 79.6 4.19 J 4.92 J 8.80 J ND ND ND ug/L 09/18/14 3.8 10.0 10 ND 8.37 J ND 16.8 ND 22.7 ND ND - ND ug/L 03/18/15 3.8 10.0 10 5.35 J 7.19 J 9.75 J 21.7 4.58 J 6.15 J 6.87 J ND 12.2 ND ug/L 09/23/15 3.8 10.0 10 ND ND ND 28.6 ND 5.535 J ND ND - ND ug/L 03/17/16 3.8 10.0 10 ND 32.2 ND 117 5.20 J ND ND ND ND ND ug/L 09/21/16 4.4 10.0 10 ND ND ND 28.5 ND ND ND ND - ND ug/L 03/21/17 4.4 10.0 10 ND ND ND 80.3 ND ND ND ND ND ND ug/L 09/20/17 4.4 10.0 10 ND ND 5.35 J 76.5 ND ND ND ND -- ND ug/L 03/21/18 4.4 10.0 10 4.40 J 17.7 ND 169 ND ND ND ND ND ND ug/L 09/23/18 4.4 10.0 - ND ND ND 131 B ND ND ND ND - 64.2 ug/L 03/26/19 4.4 10.0 - 7.04 J 319 ND 109 ND 4.83 J ND ND ND ND 09/18/19 4.4 10.0 ND 5.24 J 4.52 J 24.0 5.23 J 7.42 J ND ND ND 0Acetone - -- - -- ND -- NC2L=6000 ug/L ug/L 02/14/95 100 100 100 ND ND ND ND - -- - -- ND -- EPAMCL=No Standard ug/L 04/03/95 100 100 100 ND ND ND ND - -- - -- ND -- ug/L 10/30/95 100 100 100 ND 50 ND ND - -- - -- ND -- ug/L 04/08/96 100 100 100 ND 98 ND ND - -- - -- ND -- ug/L 10/24/96 - -- 100 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 - -- 100 ND -- ND ND - -- - -- ND -- ug/L 1019/97 - -- 100 ND 95 ND ND - -- - -- ND -- ug/L 05/14/98 - -- 100 ND 330 ND ND - -- - -- ND -- ug/L 11/11/98 - -- 100 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 100 ND 780 ND ND - -- - -- ND -- ug/L 10/29/99 - -- 100 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 100 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 100 ND 190 ND ND - -- - -- ND -- ug/L 05/15/01 - -- 100 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 100 100 100 ND ND ND ND - ND - -- ND -- ug/L 04/25/02 100 100 100 ND 190 ND ND ND ND - -- ND -- ug/L 10/01/02 100 100 100 ND 280 ND ND ND ND - -- ND -- ug/L 04/09/03 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 10/21/03 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 03/25/04 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 100 100 100 ND ND ND -- ND ND - -- ND -- ug/L 10106/0 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 04/26/06 100 100 100 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 100 100 100 ND ND ND ND ND ND - -- ND ND ug/L 03/22/07 100 100 100 ND ND 4.34 J ND ND ND - -- ND ND ug/L 10/02/07 100 100 100 ND 9.81 B ND ND 1.76 B ND - -- ND 5.5 J ug/L 04/03/08 100 100 100 ND 10.1 J ND ND ND ND ND ND ND ND ug/L 10/30/08 100 100 100 ND 13.8 J ND ND 7.95 J ND ND ND ND ND ug/L 03/24/09 1.5 5.0 100 ND 280 ND ND ND ND ND ND ND ND ug/L 09/22/09 1.5 5.0 100 ND 9.0 J 13 J ND ND ND ND ND -- ND ug/L 03/22/10 1.5 5.0 100 ND Dry 55 J ND ND ND ND ND -- ND ug/L 09/23/10 1.5 5.0 100 ND 8.7 J ND ND ND ND ND ND -- ND ug/L 03/16/11 1.2 5.0 100 ND 16 J ND ND ND ND ND ND -- ND ug/L 09/21/11 1.2 5.0 100 ND 310 ND ND ND ND ND ND - ND ug/L 03/21/12 1.2 5.0 100 ND 2700 3.6 J 13 J ND ND ND ND ND ND ug/L 09/20/12 1.2 5.0 100 ND ND ND 5.4 B ND ND ND ND - 7.0 J ug/L 03/20/13 1.2 5.0 100 ND 21 J ND ND ND ND ND ND ND ND ug/L 09/18/13 1.2 5.0 100 ND 34 J ND ND ND ND ND ND - ND ug/L 03/27/14 1.2 5.0 100 ND 77 B ND 6.2 B ND ND ND ND ND 19 J ug/L 09/1814 1.2 5.0 100 ND 24 J ND ND ND ND ND ND - ND ug/L 03/18/15 1.2 5.0 100 ND 29 J ND ND ND ND ND ND ND ND ug/L 09/23/15 1.2 5.0 1Do ND ND ND 4.9 J ND ND ND ND -- ND ug/L 03/17/16 1.2 5.0 100 ND ND ND ND ND ND ND 4.5 J ND ND ug/L 09/21/16 10 20 100 ND ND ND ND ND ND ND ND - ND ug/L 03/21/17 10 20 100 ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 10 20 100 -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 10 20 100 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/18 10 20 100 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 10 20 -- ND ND ND ND ND ND ND ND -- ND ug/L 03/26/19 10 20 -- ND ND 20 B ND ND ND ND ND ND 12 J u /L 09/18/19 10 20 ND ND ND ND ND ND ND ND ND Benzene ug/L 12/05/94 5 5 5 ND 11 ND ND - -- - -- ND -- NC2L=1 ug/L ug/L 02/14/95 5 5 5 ND 11 ND ND - -- - -- ND -- EPA MCL = 5 ug/L ug/L 04/03/95 5 5 5 ND 8 ND ND - -- - -- ND -- ug/L 10/30/95 5 5 5 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 5 5 5 ND 9 3.9 ND - -- - -- ND -- ug/L 10/24/96 5 5 5 ND -- 5 ND - -- - -- ND -- ug/L 04/15/97 5 5 5 ND -- 6.9 ND - -- - -- ND -- ug/L 10/29/97 -- -- 5 ND 5 6 ND - -- - -- ND -- ug/L 05/14/98 -- -- 5 ND B 6 ND - -- - -- ND -- ug/L 10/11/98 -- -- 5 ND ND 7 ND - -- - -- ND -- ug/L 06/04/99 -- -- 5 ND B 6 ND - -- - -- ND -- ug/L 10/29/99 -- -- 5 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 -- -- 5 ND ND ND ND ND -- -- -- ND -- ug/L 11/07/00 -- -- 5 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 -- -- 5 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 -- -- 5 ND ND ND ND -- ND - -- ND -- ug/L 04/24/02 -- -- 5 ND 6 ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 5 ND 7 ND ND ND ND - -- ND -- ug/L 03/24/04 5 5 5 ND 6 ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND 7.19 ND ND ND ND - -- ND -- ug/L 05/25/05 5 5 5 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 5 5 5 ND 7.61 ND ND ND ND - -- ND -- ug/L 04/25/06 5 5 5 ND 6.23 ND ND ND ND - -- ND -- ug/L 10/04/O6 5 5 5 ND 6.8 ND ND ND ND - -- ND ND ug/L 03/21/07 5 5 5 ND 1.36 2.46 3.55 0.44 J 1.52 - -- ND ND ug/L 10/02/07 5 5 5 ND 5.47 1.70 4.99 1.68 1.55 - -- ND ND ug/L 04/03/08 5 5 5 ND 0.37 J 1.57 5.82 0.98 J 1.48 1.28 ND ND ND ug/L 10/29/0 5 5 5 ND 3.08 1.51 6.23 2.13 1.49 1.25 ND ND ND ug/L 03/24/08 0.20 1.0 1 ND ND ND 0.64 J ND ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND ND 1.4 4.2 0.44 J 1.3 1.2 ND -- ND ug/L 03/22/10 0.050 1.0 1 ND Dry 1.4 ND ND 1.1 0.75 J ND -- ND ug/L 09/23/10 0.20 1.0 1 ND 0.98 J ND ND ND ND ND ND -- ND ug/L 03/16/11 0.fi8 1.0 1 ND ND 1.6 ND ND 1.2 0.96 J ND -- ND ug/L 09/21/1, 0.68 1.0 1 ND 4.6 1.4 0.85 J ND 1.2 0.82 J ND -- ND ug/L 03/21/12 0.15 1.0 1 ND ND 1.1 0.65 J 0.73 J 0.95 J 0.82 J ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND 0.94 J ND ND ND ND ND -- ND ug/L 03/20/113 0.15 1.0 1 ND ND 1.5 3.0 ND 1.2 1.2 ND ND ND ug/L 09/18/13 0.15 1.0 1 ND 2.9 1.7 0.89 J 0.56 J 1.1 0.86 J ND - ND ug/L 03/27/14 0.15 1.0 1 ND ND 1.6 ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND 4.6 1.1 ND ND 1.1 0.58 J ND - ND ug/L 03/18/15 0.15 1.0 1 ND ND 1.3 ND ND 1.2 0.60 J ND ND ND ug/L 09/23/15 0.15 1.0 1 ND 3.7 1.3 ND 1.1 0.83 J 0.66 J ND - ND ug/L 03/17/16 0.15 1.0 1 ND 1.2 2.4 ND ND 1.2 0.45 J ND ND ND ug/L 09/21/16 0.15 1.0 1 ND 3.5 1.6 ND ND 1.1 0.41 J ND - ND ug/L 03/21/17 0.15 1.0 1 ND 2.6 1.8 ND ND 0.97 J 0.64 J ND - ND (re -sample) ug/L 05/03/17 0.15 1.0 1 -- -- - -- -- -- -- -- ND ND ug/L 09/20/17 0.15 1.0 1 ND ND 1.6 ND ND ND ND ND - ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.15 1.0 - ND ND ND ND ND 0.71 J ND ND - ND ug/L 03/26/19 0.15 1.0 - ND ND 2.5 ND ND 0.47 J ND ND ND ND u /L 09/18/19 0.15 1.0 ND 4.3 ND ND ND 0.68 J ND ND ND 4 GOLDER 6 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW-5 MW-6 MW-7 MW-8 AMW-,S AMW-1D AMW-2S AMW-213 MW-9 Chloroben- ug/L 12/05/94 5 5 5 ND ND ND ND -- -- -- - ND -- NC 2L = 50 ug/L ug/L 02/14/95 5 5 5 ND ND ND ND -- -- -- -- ND -- EPA MCL = 100 ug/L ug/L 04/03/95 5 5 5 ND ND ND ND -- -- -- - ND -- ug/L 101 0/95 5 5 5 ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 5 5 5 ND ND ND ND - -- -- - ND -- ug/L 10/24/96 - -- 5 ND -- ND ND -- -- -- -- ND -- ug/L 04/15/97 - -- 5 ND -- ND ND - -- -- - ND -- ug/L 10/29/97 - -- 5 ND 7 3 ND - -- -- -- ND -- ug/L 05/14/98 - -- 5 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 -- -- 5 ND 8 ND ND -- -- -- -- ND -- ug/L 06/04/99 - -- 5 ND 7 ND ND - -- -- -- ND -- ug/L 10/29/99 - -- 5 ND ND ND ND - -- -- -- ND -- ug/L 04/20/00 - -- 5 ND ND ND ND 8 -- -- -- ND -- ug/L 11/07/00 - -- 5 ND 7 ND ND - -- -- -- ND -- 05/15/0, - -- 5 ND 6 ND ND - -- - -- ND -- Iug/L L 10,16/0, - -- 5 ND 7 ND ND - ND - -- ND -- ug/L 04/24/02 - -- 5 ND 6 ND ND 7 ND - -- ND -- ug/L 10/01/02 - -- 5 ND 8 ND ND ND ND - -- ND -- ug/L 04/09/03 -- -- 5 ND ND ND ND 6 ND - -- ND -- ug/L 10/20/03 5 5 5 ND 10 ND ND ND ND - -- ND -- ug/L 03/24/04 5 5 5 ND 1, ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND 13 5 ND ND ND - -- ND -- ug/L 05/25/05 5 5 5 ND ND 6 -- 6.12 ND - -- ND -- ug/L 10/04/05 5 5 5 ND 13.4 6 ND ND ND - -- ND -- ug/L 04/25/06 5 5 5 ND 10.8 6.02 ND 9.62 ND - -- ND -- ug/L 10/04/06 5 5 5 ND 9 6 ND 16.2 ND - -- ND ND ug/L 03/21/07 5 5 5 ND 1.34 589 0.59 J 2.83 4.62 - -- ND ND ug/L 10/02/07 5 5 5 ND 6.16 195 0.83 J ND 5.13 - -- ND ND ug/L 04/03/08 5 5 5 ND 0.30 J 5.72 1.14 J 11.3 5.01 4.50 ND ND ND ug/L 10/29/08 5 5 5 ND 8.02 5.41 1.11 J 23.8 5.09 1.86 J ND ND ND ug/L 03/24/09 0.27 1.0 3 ND ND 4.6 ND 0.46 J 3.8 2.0 J ND ND ND ug/L 09/22/09 0.27 1.0 3 ND ND 5.7 0.75 J 4.9 4.9 1.0 J ND -- ND ug/L 03/22/10 0.069 1.0 3 ND Dry 6.4 ND ND 4.6 0.97 J ND -- ND ug/L 09/23/10 0.27 1.0 3 ND 7.5 6.3 ND ND 4.2 0.55 J ND -- ND ug/L 03/16/11 0.74 1.0 3 ND ND 7.3 ND ND 4.5 1.2 J ND -- ND ug/L 09/21/11 0.74 1.0 3 ND 8.1 8.4 ND 1.4 J 4.6 1.2 J ND - ND ug/L 03/21/12 0.17 1.0 3 ND ND 8.5 ND 5.5 3.6 1.7 J ND ND ND ug/L 09/20/12 0.17 1.0 3 ND ND 7.8 ND 1.7 J 1.8 J ND ND - ND ug/L 03/20/13 0.17 1.0 3 ND ND 10 1.0 J 1.2 J 5.2 2.4 J ND ND ND ug/L 09/18/13 0.17 1.0 3 ND 4.8 8.0 0.43 J 4.1 5.2 1.8 J ND - ND ug/L 03/27/14 0.17 1.0 3 ND ND 10 ND ND 4.9 1.2 J ND ND ND ug/L 09/18/14 0.17 1.0 3 ND 8.0 10 ND ND 5.6 0.88 J ND -- ND ug/L 03/18/15 0.17 1.0 3 ND ND 10 ND 1.4 J 6.4 2.2 J ND ND ND ug/L 09/23/15 0.17 1.0 3 ND 11 9.4 ND 4.2 5.2 1.5 J ND - ND ug/L 03/17/16 0.17 1.0 3 ND 1.3 J 9.0 ND ND 6.6 0.86 J ND ND ND ug/L 09/21/16 0.17 1.0 3 ND 11 8.6 ND ND 6.3 0.97 J ND - ND ug/L 03/21/17 0.17 1.0 3 ND 8.5 12 ND 0.92 J 5.4 1.6 J ND - ND (re -sample) ug/L 05/03/17 0.17 1.0 3 -- -- - -- - -- - -- ND ND ug/L 09/20/17 0.17 1.0 3 ND ND 11 ND ND 4.3 1.6 J ND - ND ug/L 03/21/18 0.17 1.0 3 ND ND 9.9 ND ND 5.3 1.1 J ND ND ND ug/L 09/23/18 0.17 1.0 - ND 1.1 9.5 ND ND 4.9 ND ND -- ND ug/L 03/26/19 0.17 1.0 - ND ND 10 ND ND 3.6 0.57 J ND ND ND 09/18/19 0.17 1.0 ND 8.4 8.3 ND ND 4.9 0.49 J ND ND Z1,2-Dichlorobenzene L 12/05/94 0.27 5 5 ND ND ND ND - -- - -- ND -- NC 2L = 20 ug/L ug/L 02/14/95 5 5 5 ND ND ND ND - -- - -- ND -- EPA MCL = 600 ug/L ug/L 04/03/95 5 5 5 ND ND ND ND - -- - -- ND -- ug/L 10/30/95 5 5 5 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 5 5 5 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 5 5 5 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 5 5 5 ND -- ND ND - -- - -- ND -- ug/L 10/29/97 - -- 5 ND 1 ND ND - -- - -- ND -- ug/L 05/14/98 - -- 5 ND ND 14 ND - -- - -- ND -- ug/L 10/11/98 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 0614/99 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 10/29/99 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 5 ND ND ND ND ND -- - -- ND -- ug/L 1 1/07/00 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 0 /15/01 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 10/i6/01 - -- 5 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 5 ND 7 ND 6 ND ND - -- ND -- ug/L 03/24/04 - -- 5 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND 6 ND ND ND ND - -- ND -- ug/L 0 /25/05 5 5 5 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 5 5 5 ND 12 ND ND ND ND - -- ND -- ug/L 04/25/006 5 5 5 ND 10 ND ND ND ND - -- ND -- ug/L 10/04/06 5 5 5 ND 10 ND ND ND ND - -- ND ND ug/L 03/21/07 5 5 5 ND 0.39 J ND 0.97 J ND 0.62 J - -- ND ND ug/L 10/02/07 5 5 5 ND 2.52 J 0.56 J 0.94 J 0.44 J 0.67 J - -- ND ND ug/L 04/03/08 5 5 5 ND ND 0.46 J 1.35 J 0.23 J 0.65 J 0.27 J ND ND ND ug/L 10/29/O8 5 5 5 ND 1.98 J 0.45 J 1.12 J 0.52 J 0.63 J 0.29 J ND ND ND ug/L 03/24/09 0.27 1.0 5 ND ND ND 0.44 J ND 0.53 J ND ND ND ND ug/L 09/22/09 0.27 1.0 5 ND ND ND 0.66 J ND 0.46 J ND ND -- ND ug/L 03/22/10 0.052 1.0 5 ND Dry 0.49 J ND ND 0.64 J ND ND -- ND ug/L 09/23/10 0.27 1.0 5 ND 3.6 J 0.52 J ND ND 0.64 J ND ND -- ND ug/L 03/16/11 0.11 1.0 5 ND ND ND ND ND 0.71 J ND ND -- ND ug/L 09/21/11 0.1, 1.0 5 ND 5.8 0.58 J ND ND 0.65 J ND ND -- ND ug/L 03/21/12 0.19 1.0 5 ND ND 0.56 J ND ND 0.625 J ND ND ND ND ug/L 09/20/12 0.19 1.0 5 ND ND 0.50 J 0.52 J ND 0.51 J ND ND -- ND ug/L 03/20/13 0.19 1.0 5 ND ND 0.76 J 1.3 J ND 0.90 J ND ND ND ND ug/L 09/18/13 0.19 1.0 5 ND 1.3 J 0.83 J ND ND 0.65 J ND ND -- ND ug/L 03/27/14 0.19 1.0 5 ND ND 0.76 J ND ND 0.55 J ND ND ND ND ug/L 09/18/14 0.19 1.0 5 ND 2.9 J 0.81 J ND ND 0.69 J ND ND - ND ug/L 03/18/15 0.19 1.0 5 ND ND 0.77 J ND ND 0.71 J ND ND ND ND ug/L 09/23/15 0.19 1.0 5 ND 2.9 J 0.76 J ND ND 0.57 J ND ND - ND ug/L 03/17/16 0.19 1.0 5 ND ND 0.78 J ND ND 0.77 J ND ND ND ND ug/L 09/21/16 0.19 1.0 5 ND 3.1 J 0.72 J ND ND 0.69 J ND ND -- ND ug/L 03/21/17 0.19 1.0 5 ND 1.5 J 0.87 J ND ND 0.579 J ND ND -- ND (re -sample) ug/L 05/03/17 0.19 1.0 5 -- -- -- -- -- -- -- -- ND ND ug/L 09/20/17 0.19 1.0 5 ND ND 0.84 J ND ND 0.47 J ND ND - ND ug/L 03/21/18 0.19 1.0 5 ND ND 0.76 J ND ND 0.48 J ND ND ND ND ug/L 09/23/18 0.19 1.0 - ND 0.87 J 0.94 J ND ND 0.48 J ND ND - ND ug/L 03/26/19 0.19 1.0 -- ND ND 0.81 J ND ND ND ND ND ND ND u /L 09/18/19 0.19 1.0 ND 3.2 0.64 J ND ND 0.46 J ND ND ND 1,4-Dichlorobenwne ug/L 12/05/94 5 5 5 ND ND ND ND - -- - -- ND -- NC 2L = 6 ug/L ug/L 02/14/95 5 5 5 ND -- ND ND - -- - -- ND -- EPA MCL = 75 ug/L ug/L 04/03/95 5 5 5 ND 11 ND ND - -- - -- ND -- ug/L 10/30/95 5 5 5 ND 10 5 ND - -- - -- ND -- ug/L 04/08/96 - -- 5 ND -- 9 ND - -- - -- ND -- ug/L 10/24/96 - -- 5 ND -- 8 ND - -- - -- ND -- ug/L 04/15/97 -- -- 5 ND -- 24 ND - -- - -- ND -- ug/L 10/29/97 -- -- 5 ND 9 10 ND - -- - -- ND -- ug/L 05/14/98 -- -- 5 ND 18 22 ND - -- - -- ND -- ug/L 10/11/98 -- -- 5 ND 18 ND ND - -- - -- ND -- ug/L O6/04/99 -- -- 5 ND 18 10 ND - -- - -- ND -- ug/L 10/29/99 -- -- 5 ND ND 7 ND - -- - -- ND -- ug/L 04/20/00 -- -- 5 ND 5 16 ND ND -- - -- ND -- ug/L 11/07/00 -- -- 5 ND ND 8 ND - -- - -- ND -- ug/L 05/15/01 -- -- 5 ND 14 6 ND - -- - -- ND -- ug/L 10/16/01 -- -- 5 ND 12 7 ND - ND - -- ND -- ug/L 04/24/02 -- -- 5 ND 18 8 ND ND ND - -- ND -- ug/L 10/01/02 -- -- 5 ND 14 9 ND ND ND - -- ND -- ug/L 04/09/03 5 5 5 ND ND 12 ND ND ND - -- ND -- ug/L 10/20/03 5 5 5 ND 23 13 ND ND ND - -- ND -- ug/L 03/24/04 5 5 5 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND 20 19 ND ND ND - -- ND -- ug/L 05/25/05 5 5 5 ND ND 17.8 -- ND ND - -- ND -- ug/L 10/04/05 5 5 5 ND 25.4 17 ND ND ND - -- ND -- ug/L 04/25/06 5 5 5 ND 24.3 1% ND ND ND - -- ND -- ug/L 10/04/O6 5 5 5 ND 18.5 14.6 ND ND ND - -- ND ND ug/L 03/21/07 5 5 5 ND 1.67 J 17.1 2.79 J 1.37 2.86 J - -- ND ND ug/L 10/02/07 5 5 5 ND 18.7 12.0 3.64 J 3.24 J 2.89 J - -- ND ND ug/L 04/03/08 5 5 5 ND 0.38 J 8.37 4.50 J 1.57 J 2.77 J 2.11 J ND ND ND ug/L 10/29/08 5 5 5 ND 23.9 7.81 4.44 J 4.11 J 2.96 J 1.66 J ND ND ND ug/L 03/24/09 0.38 1.0 1 ND ND 6.4 1.3 0.57 J 2.6 1.4 ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND 6.8 2.4 1.4 2.1 1.0 ND -- ND ug/L 03/22/10 0.10 1.0 1 ND Dry 9.8 ND ND 3.2 1.2 ND -- ND ug/L 09/23/10 0.38 1.0 1 ND 15 8.8 ND ND 3.4 0.91 J ND -- ND ug/L 03/1611 1 0.79 1.0 1 ND ND 10 ND ND 3.2 1.3 ND -- ND ug/L 09/21/11 0.79 1.0 1 ND 14 12 ND 0.93 J 4.2 1.2 ND - ND ug/L 03/21/12 0.19 1.0 1 ND 5.4 J 12 0.49 J 2.9 3.7 1.4 ND ND ND ug/L 09/20/12 0.19 1.0 1 ND 0.77 J 11 1.0 2.0 3.8 1.2 ND - ND ug/L 03/20/13 0.19 1.0 1 ND ND 14 3.8 ND 5.0 2.2 ND ND ND ug/L 09/18/13 0.19 1.0 1 ND 6.0 13 1.2 0.73 J 4.1 1.4 ND - ND ug/L 03/27/14 0.19 1.0 1 ND ND 18 ND ND 3.1 0.73 J ND ND ND ug/L 09/18/14 0.19 1.0 1 ND 13 15 ND ND 4.3 0.86 J ND - ND ug/L 03/18/15 0.19 1.0 1 ND ND 74 ND 0.46 J 4.0 1.4 ND ND ND ug/L 09/23/15 0.19 1.0 1 ND 21 13 ND 0.85 J 3.6 1.3 ND - ND ug/L 03/17/16 0.19 1.0 , ND 1.2 16 ND ND 4.2 0.90 J ND ND ND ug/L 09/21/16 0.19 1.0 1 ND 28 14 ND ND 4.2 0.87 J ND - ND ug/L 03/21/17 0.19 1.0 1 ND 24 18 ND 0.44 J 4.1 1A ND - ND (re -sample) ug/L 05/03/17 0.19 1.0 1 -- -- -- -- - -- - -- ND ND ug/L 09/20/17 0.19 1.0 1 ND 2.9 16 ND ND 3.8 1.2 ND - ND ug/L 03/21/18 0.19 1.0 1 ND ND 14 ND ND 3.4 1.1 ND ND ND ug/L 09/23/16 0.19 1.0 - ND 5.4 16 ND ND 3.4 1.1 ND - ND ug/L 03/26/19 0.19 1.0 - ND ND 17 ND ND 2.3 0.59 J ND ND ND u /L 09/18/19 0.19 1.0 ND 14 12 ND ND 2.8 ND ND ND 4 GOLDER 7 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 1,1-Dichloroethane ug/L 12/05/94 5 5 5 ND ND ND ND -- -- -- - ND -- NC 2L = 6 ug/L ug/L 02/14/95 5 5 5 ND ND 9 ND -- -- -- - ND -- EPA MCL = No Standard ug/L 04/03/95 5 5 5 ND -- 7 ND -- -- -- - - -- ug/L 10/30/95 5 5 5 ND ND 10 ND -- -- -- - ND -- ug/L 04/08/96 - -- 5 ND ND 6 ND - -- -- - ND -- ug/L 10/24/96 - -- 5 ND -- 8 ND - -- -- - ND -- ug/L 04/15/97 - -- 5 ND -- ND ND - -- -- - ND -- ug/L 10/29/97 - -- 5 ND 1 7 ND - -- -- - 1 -- ug/L 05/14/98 - -- 5 ND ND ND ND - -- -- - ND -- ug/L 10/11/98 - -- 5 ND ND 6 ND - -- -- -- ND -- ug/L 06/04/99 - -- 5 ND ND 5 6 - -- - -- ND -- ug/L 1019/99 - -- 5 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 5 ND ND ND 5 ND -- - -- ND -- ug/L 11/07/00 - -- 5 ND ND ND 6 - -- - -- ND -- ug/L 05/15/01 - -- 5 ND ND ND 14 - -- - -- ND -- ug/L 10/16/01 - -- 5 ND ND ND 11 - ND - -- ND -- ug/L 04/24/02 - -- 5 ND ND ND 25 ND ND - -- ND -- ug/L 10/01/02 - -- 5 ND ND ND 17 ND ND - -- ND -- ug/L 04/09/03 - -- 5 ND ND ND 24 ND ND - -- ND -- ug/L 10/20/03 5 5 5 ND ND ND 18 ND ND - -- ND -- ug/L 03/24/04 5 5 5 ND ND ND 10 ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND ND ND 13 ND ND - -- ND -- ug/L 05/25/05 5 5 5 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 5 5 5 ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 5 5 5 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 5 5 5 ND ND ND 6 ND ND - -- ND ND ug/L 03/21/07 5 5 5 ND ND 1.69 7.8 ND 1.31 - -- ND ND ug/L 10/02/07 5 5 5 ND 0.45 J 1.66 J 9.7 0.1 J 1.27 J - -- ND ND ug/L 04/03/08 5 5 5 ND ND 1.72 J 13.1 ND 1.36 J 0.98 J ND ND ND ug/L 10/29/08 5 5 5 ND 0.40 J 1.32 J 13.5 ND 1.36 J 1.33 J ND 0.11 J ND ug/L 03/24/09 0.33 1.0 5 ND ND 0.83 J 3.6 J ND 1.2 J 1.1 J ND ND ND ug/L 09/22/09 0.33 1.0 5 ND ND 0.75 J 6.9 ND 1.0 J 1.3 J ND - ND ug/L 03/22/10 0.050 1.0 5 ND Dry 0.64 J ND ND 0.76 J 0.90 J ND - ND ug/L 09/231 0 0.33 1.0 5 ND ND 0.64 J ND ND 0.87 J 0.84 J ND - ND ug/L 03/i 6/11 0.080 1.0 5 ND ND 0.56 J ND ND 0.91 J 1.0 J ND - ND ug/L 09/21/11 0.080 1.0 5 ND ND 0.74 J 1.7 J ND 1.1 J 1.4 J ND - ND ug/L 03/21/12 0.13 1.0 5 ND ND 0.63 J 0.94 J ND 0.74 J 1.1 J ND ND ND ug/L 09/20/12 0.13 1.0 5 ND ND 0.49 J 295 J ND 1.0 J 1.3 J ND - ND ug/L 03/20/13 0.13 1.0 5 ND ND 0.71 J 8.9 ND 1.2 J 1.6 J ND ND ND ug/L 09/18/13 0.13 1.0 5 ND ND ND 1.7 J ND 0.71 J 1.0 J ND - ND ug/L 03/27/14 0.13 1.0 5 ND ND ND ND ND 0.72 J 0.92 J ND ND ND ug/L 09/18/14 0.13 1.0 5 ND ND 0.43 J ND ND 0.54 J 0.96 J ND - ND ug/L 03/18/15 0.13 1.0 5 ND ND 0.47 J ND ND 0.76 J 0.77 J ND ND ND ug/L 09/23/115 0.13 1.0 5 ND ND ND ND ND 0.62 J 1.1 J ND - ND ug/L 03/17/16 0.13 1.0 5 ND ND ND ND ND 0.54 J 0.99 J 0.45 J ND ND ug/L 09/2116 0.13 1.0 5 ND ND ND ND ND 0.51 J 0.94 J ND -- ND ug/L 03/21/17 0.13 1.0 5 ND ND ND ND ND 0.58 J 1.1 J ND - ND (re -sample) ug/L 05/03/17 0.13 1.0 5 -- -- - -- - -- - -- ND ND ug/L 09/20/17 0.13 1.0 5 ND ND ND ND ND ND 0.87 J ND - ND ug/L 03/21/18 0.13 1.0 5 ND ND ND ND ND ND 0.74 J ND ND ND ug/L 09/23/16 0.13 1.0 - ND ND ND ND ND ND 0.89 J 0.53 J - ND ug/L 03/2611: 0.13 1.0 - ND ND ND ND ND ND 0.65 J ND ND ND ug/L 09/18/19 0.13 1.0 -- ND ND ND ND ND ND 0.58 J ND -- ND ug/L 09/18/19 0.21 1.0 -- ND ND ND ND ND ND ND ND -- ND u /L 09/18/19 0.21 1.0 ND ND ND ND ND ND ND ND ND cis-1,2-Dichloroethane ug/L 12/05/94 5 5 5 ND -- 24 11 - -- - -- ND -- NC 2L = 70 ug/L ug/L 02/14/95 5 5 5 ND 9 ND 8 - -- - -- ND -- EPA MCL = 70 ug/L ug/L 04/03/95 5 5 5 ND 7 17 ND - -- - -- ND -- ug/L 10/30/95 5 5 5 ND 10 25 10 - -- - -- ND -- ug/L 04/08/96 5 5 5 ND 7 17 7 - -- - -- ND -- ug/L 10/24/96 - -- 5 ND -- 21 ND - -- - -- ND -- ug/L 04/15/97 - -- 5 ND -- 14 15 - -- - -- ND -- ug/L 10/29/97 -- -- 5 ND 4 20 3 -- -- -- -- 6 -- ug/L 05/14/98 -- -- 5 ND ND 14 ND -- -- -- -- ND -- ug/L 10/11/98 - -- 5 ND ND 21 ND - -- - -- ND -- ug/L 06/04/99 - -- 5 ND 6 17 ND - -- - -- 12 -- ug/L 10/29/99 - -- 5 ND ND 17 ND - -- - -- 26 -- ug/L 04/20/00 - -- 5 ND ND 13 ND ND -- - -- 16 -- ug/L 11/07/00 - -- 5 ND ND 15 ND - -- - -- 12 -- ug/L 05/15/01 - -- 5 ND ND 14 7 - -- - -- 8 -- ug/L 10/i6/01 - -- 5 ND ND 13 ND - ND - -- 10 -- ug/L 04/24/02 - -- 5 ND ND 15 11 ND ND - -- 6 -- ug/L 10/01/02 -- -- 5 ND ND 12 7 ND ND - -- ND -- ug/L 04/09/03 - -- 5 ND ND 11 18 ND ND - -- ND -- ug/L 10/20/03 - -- 5 ND ND 11 22 ND ND - -- ND -- ug/L 03/24/04 5 5 5 ND ND 10 13 ND ND - -- ND -- ug/L 10/27/04 5 5 5 ND ND 10.5 26.2 ND ND - -- ND -- ug/L 05/25/05 5 5 5 ND ND 10.6 -- ND ND - -- ND -- ug/L 10/04/05 5 5 5 ND ND 12.1 12.8 ND ND - -- ND -- ug/L 04/25/O6 5 5 5 ND ND 12.8 12.3 ND ND - -- ND -- ug/L 10/04/06 5 5 5 ND ND 14.2 15.7 ND ND - -- ND ND ug/L 03/21/07 5 5 5 ND 0.4. J 12..7 22.1 ND 2..3 -. ND ND ug/L 10/02/07 5 5 5 ND 1.1 J 124 J 239 J 071 J 2.14 J ND ND ug/L 04/03/08 5 5 5 ND 005 J 12.2 30.6 0.35 J 22 J 1.85 J ND ND ND ug/L 10/29/O8 5 5 5 ND 02 J 98 28.9 0.27 J 2.27 J 2.36 J ND 0.24 J ND ugL 03/24/ 0 1.0 5 ND ND 4.9 J 7.4 ND 1.7 J 1.7 J ND ND ND 09/22/ 0.3 36 5 ND ND 61 19 ND 20 Jug/L 25 J ND ND u 03/22/10 0.gL 075 1.0 5 ND D 70 0.66 J ND 20 J 21 J ND -- ND u/ g 10 036 .72 1.0 5 ND ND 52 ND ND 1.7 J 1.2 J ND ND ugL 03/16/11 1.0 5 ND ND 6.4 0.89 J ND 26 J 20 J ND - ND ug/L 09/21/11 0.72 1.0 5 ND ND 5.6 2.9 J ND 1.7 J 1.3 J ND - ND ug/L 03/21/12 0.15 1.0 5 ND ND 5.2 2.6 J ND 1.5 J 1.6 J ND ND ND ug/L 09/20/12 0.15 1.0 5 ND ND 4.4 J 4.1 J ND 1.4 J 1.2 J ND - ND ug/L 03/20/13 0.15 1.0 5 ND ND 5.6 13 ND 1.9 J 1.8 J ND ND ND ug/L 09/18/13 0.15 1.0 5 ND 0.53 J 5.3 4.1 J ND 1.4 J 1.5 J ND - ND ug/L 03/27/14 0.15 1.0 5 ND ND 4.5 J ND ND 1.2 J 1.2 J ND ND ND ug/L 09/18/14 0.15 1.0 5 ND ND 5.0 ND ND 1.4 J 0.88 J ND - ND ug/L 03/18/15 0.15 1.0 5 ND ND 5.3 0.63 J ND 1.2 J 1.2 J ND ND ND ug/L 09/23/15 0.15 1.0 5 ND ND 3.8 J ND ND 1.2 J 1.1 J ND - ND ug/L 03/17/16 0.15 1.0 5 ND ND 3.6 J ND ND 1.2 J 0.95 J ND ND ND ug/L 09/21/16 0.15 1.0 5 ND ND 3.4 J ND ND 1.0 J 0.89 J ND - ND ug/L 03/21/17 0.15 1.0 5 ND ND 3.7 J ND ND 0.90 J 1.0 J ND - ND (re -sample) ug/L 05/03/17 0.15 1.0 5 -- -- - -- - -- -- -- ND ND ug/L 09/20/17 0.15 1.0 5 ND ND 3.5 J ND ND 0.65 J 0.91 J ND -- ND ug/L 03/21/18 0.15 1.0 5 ND ND 2.7 J ND ND 0.68 J 0.76 J ND ND ND ug/L 09/23/18 0.15 1.0 - ND ND 2.6 ND ND 0.56 J 0.91 J ND - ND ug/L 03/26/19 0.15 1.0 - ND ND 2.1 ND ND 0.51 J 0.61 J ND ND ND 09/18/19 0.15 1.0 ND ND ND ND ND 0.50 J 0.40 J ND ND IEthylben.ne L 12/05/94 5 5 1 ND 11 ND ND - -- - -- ND -- NC2L=600 ug/L ug/L 02/14/95 5 5 1 ND 14 ND ND - -- - -- ND -- EPA MCL =700 ug/L ug/L 04/03/95 5 5 1 ND 8 ND ND - -- - -- ND -- ug/L 10/30/95 5 5 1 ND 10 ND ND - -- - -- ND -- ug/L 04/08/96 5 5 1 ND 9 ND ND - -- - -- ND -- ug/L 10/24/96 5 5 1 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 5 5 1 ND -- ND ND - -- - -- ND -- ug/L 10/29/97 5 5 1 ND 3 ND 2 - -- - -- ND -- ug/L 05/14/98 5 5 1 ND 8 ND ND - -- - -- ND -- ug/L 10/11/98 5 5 1 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 5 5 1 ND 11 ND ND - -- - -- ND -- ug/L 10/29/99 5 5 1 ND ND ND ND - -- - -- ND -- ug/L 0%0/00 5 5 1 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 5 5 1 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 5 5 1 ND ND ND ND - -- - -- ND -- ug/L 10/16/01 5 5 1 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 5 5 1 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 5 5 1 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 5 5 1 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 5 5 1 ND ND ND ND ND ND -- -- ND -- ug/L 03/24/04 5 5 1 ND 9 ND ND ND ND -- -- ND -- ug/L 10/27/04 5 5 1 ND 22.4 ND ND ND ND -- -- ND -- ug/L 05/25/05 5 5 1 ND ND ND -- ND ND -- -- ND -- ug/L 10/04/05 5 5 1 ND 28 ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 1 ND 12.4 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 1 ND 15.7 ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 1 ND 0.96 J ND 1.04 ND ND -- -- ND ND ug/L 10/02/07 5 5 1 ND 3.46 ND 1.24 J ND ND -- -- ND ND ug/L 04/03/08 5 5 1 ND ND ND 1.37 J ND ND ND ND ND ND ug/L 10/29/08 5 5 1 ND 0.22 J ND 1.62 ND ND ND ND ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND ND ND 0.95 J ND ND ND ND - ND ug/L 03/22/10 0.10 1.0 1 ND Dry ND ND ND ND ND ND - ND ug/L 09/23/10 0.20 1.0 1 ND 2.1 ND ND ND ND ND ND - ND ug/L 03/16/11 0.62 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 09/21/11 0:62 1.0 1 ND 2.3 ND ND ND ND ND ND - ND ug/L 03/21/12 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 0.13 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/20/13 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 0.13 1.0 1 ND 0.79 J ND ND ND ND ND ND - ND ug/L 03/27/14 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.13 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.13 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/17/16 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.13 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.13 1.0 1 ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.13 1.0 1 -- -- - -- -- -- -- -- ND ND ug/L 09/20/17 0.13 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 0.13 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/16 0.13 1.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 0.13 1.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 0.13 1.0 ND 0.51 J ND ND ND ND ND ND ND 4 GOLDER 8 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-8 AMW-1S AMW-1D AMW-2S AMW-2D MW-9 Methylene chloride ug/L 12/05/94 10 10 10 ND ND ND 7 -- -- -- -- ND -- NC2L=5ug/L ug/L 10/30/95 10 10 10 ND ND 10 ND -- -- -- -- ND -- EPA MCL = No Standard ug/L 04/08/96 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/24/96 - -- 10 ND -- 9 ND - -- -- -- ND -- ug/L 10/29/97 - -- 10 ND ND ND ND - -- -- -- 1 -- ug/L 0114/98 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 - -- 10 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 10 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 10 ND ND ND ND - -- - -- ND -- ug/L 05/15/01 - -- 10 ND ND ND 52 - -- - -- ND -- ug/L 10/16/01 - -- 10 ND ND ND 38 - ND - -- ND -- ug/L 04/24/02 - -- 10 ND ND ND 87 ND ND - -- ND -- ug/L 10/01/02 - -- 10 ND ND ND 44 ND ND - -- ND -- ug/L 04/09/03 10 10 10 ND ND ND 54 ND ND - -- ND -- ug/L 10/20/03 10 10 10 ND ND ND 27 ND ND - -- ND -- ug/L 03/24/04 10 10 10 ND ND ND 30 ND ND - -- ND -- ug/L 10/27/04 10 10 10 ND ND ND 42.1 ND ND - -- ND -- ug/L 05/25/05 10 10 10 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 10 10 10 ND ND ND 13A ND ND - -- ND -- ug/L 04/25/06 10 10 10 ND ND ND 13.9 ND ND - -- ND -- ug/L 10/04/O6 10 10 10 ND ND ND 15.1 ND ND - -- ND ND ug/L 03/21/07 10 10 10 ND ND 0.35 J 23.3 ND 0.24 J - -- ND ND ug/L 10/02/07 10 10 10 ND 0.57 B ND 22.0 ND ND - -- ND 0.41 J ug/L 04/03/08 10 10 10 ND ND 0.34 B 34.2 ND ND ND 3.10 J ND 0.42 J ug/L 10/29/0 10 10 10 ND ND 0.27 J 33.7 ND 0.42 J 0.92 J ND 0.75 J ND ug/L 03/24/09 0.53 2.0 1 ND ND ND 11 ND ND ND ND ND ND 09/22/09 0.53 1.0 1 ND ND ND 21 ND ND ND ND - ND It. ug/L 03/22/10 0.070 1.0 1 ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.53 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.14 1.0 1 ND ND ND ND ND ND ND ND -- ND Iug/t. 09/21/1, 0.14 1.0 1 ND ND ND 3.4 ND ND ND ND -- ND L 0.1112 0.23 1.0 1 ND ND ND 1.8 ND ND ND ND ND ND ug/L 09/20/12 0.23 1.0 1 ND ND ND 2A ND ND ND ND -- ND ug/L 03/20/13 0.23 1.0 1 ND ND ND 11 ND ND ND ND ND ND ug/L 09/18/13 0.23 1.0 1 ND ND ND 1.0 ND ND ND ND - ND ug/L 03/27/114 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.23 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.23 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/17/16 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.23 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.23 1.0 1 ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.23 1.0 1 -- -- - -- -- -- -- -- ND ND ug/L 09/20/17 0.23 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 0.23 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.23 1.0 - ND ND ND ND ND ND ND ND - 0.43 J ug/L 03/26/19 0.23 1.0 - ND ND ND ND ND ND ND ND ND ND 09/18/19 0.23 1.0 ND ND ND ND ND ND ND ND ND I1,1,1-Td'hlomethane L 12/05/94 5 5 1 ND ND - ND -- -- -- -- -- NC 2L = 200 ug/L ug/L 02/14/95 5 5 1 ND ND - ND -- -- -- -- -- -- EPA MCL=200 ug/L ug/L 04/03/95 5 5 1 ND ND - ND -- -- -- -- - -- ug/L 10/30/95 - -- 1 ND ND - ND -- -- -- -- - -- ug/L 04/08/96 - -- 1 ND ND - ND -- -- -- -- - -- ug/L 10/24/96 - -- 1 ND -- - ND -- -- -- -- - -- ug/L 04/15/97 - -- 1 ND -- - ND - -- -- -- - -- ug/L 10/29/97 - -- 1 ND ND - ND -- -- -- -- -- -- ug/L 05/14/98 - -- 1 ND ND - ND -- -- -- -- - -- ug/L 10/11/98 - -- 1 ND ND -- ND -- -- -- -- -- -- ug/L 06/04/99 - -- 1 ND ND -- ND -- -- -- -- - -- ug/L 101 9/99 - -- 1 ND ND - ND -- -- -- -- -- -- ug/L 04/20/00 - -- 1 ND ND - ND - -- -- -- -- -- ug/L 11/07/00 - -- 1 ND ND - ND - -- -- -- -- -- ug/L 02/27/01 ug/L 05/15/01 - -- 1 ND ND - 6 - -- -- -- -- -- ug/L 10/16/01 - -- 1 ND ND - 6 - -- - -- -- -- ug/L 04/24/02 - -- 1 ND ND - 9 - -- - -- -- -- ug/L 10/01/02 - -- 1 ND ND - 5 - -- - -- -- -- ug/L 04/09/03 - -- 1 ND ND - ND - -- - -- -- -- ug/L 10/20/03 5 5 1 ND ND - ND - -- - -- -- -- ug/L 03/24/04 5 5 1 ND ND - ND - -- -- -- -- -- ug/L 10/27/04 5 5 1 ND ND - ND - -- -- -- -- -- ug/L 05125/0 5 5 1 ND ND - -- - -- -- -- ND -- ug/L 10/04/05 5 5 1 ND ND ND ND ND ND -- -- ND -- ug/L 04/25/06 5 5 1 ND ND ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 1 ND ND ND ND ND ND -- -- ND ND ug/L 03/21/07 5 5 1 ND ND ND ND ND ND -- -- ND ND ug/L 10/02/07 5 5 1 ND ND ND 0.18 J ND ND -- -- ND ND ug/L 04/03/08 5 5 1 ND ND ND 0.23 J ND ND ND ND ND ND ug/L 10/29/0 5 5 1 ND ND ND 0.13 J ND ND ND ND ND ND ug/L 03/24/09 0.7 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/22/09 0.27 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/22/10 0.15 1.0 1 ND Dry ND ND ND ND ND ND -- ND ug/L 09/23/10 0.27 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/16/11 0.65 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 09/21/11 0.65 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/12 0.12 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/20/12 0.12 -- 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/20/13 0.12 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/13 0.12 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/27/14 0.12 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.12 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 0.12 -- 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.12 -- 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/17/16 0.12 -- 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.12 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L 03/21/17 0.12 -- 1 ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.12 1.0 1 -- -- - -- - -- - -- ND ND ug/L 09/20/17 0.12 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 0.12 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/18 0.12 -- - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 0.12 1.0 - ND ND ND ND ND ND ND ND ND ND 09/18/19 0.12 1.0 ND ND ND ND ND ND ND ND ND Trichloroethene IL L 12/05/94 5 5 1 ND ND ND ND - -- - -- ND -- NC2L=3 ug/L ug/L 02/14/95 5 5 1 ND ND ND ND - -- - -- ND -- EPA MCL=5ug/L ug/L 04/03/95 5 5 1 ND ND ND ND - -- - -- ND -- ug/L 10/30/95 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 04/08/96 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 10/24/96 - -- 1 ND -- ND ND - -- - -- ND -- ug/L 04/15/97 - -- 1 ND -- ND ND - -- - -- ND -- ug/L 10/29/97 - -- 1 ND ND 2 ND - -- - -- 2 -- ug/L 05/14/98 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 10/11/98 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- 1 ND ND ND ND -- -- - -- ND -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- -- - -- ND -- ug/L 04/20/00 - -- 1 ND ND ND 8 ND -- - -- ND -- ug/L 11/07/00 - -- 1 ND ND ND ND -- -- - -- ND -- ug/L OS/15/01 - -- 1 ND ND ND 14 -- -- - -- ND -- ug/L 10/i6/01 - -- 1 ND ND ND B -- -- - -- ND -- ug/L 04/24/02 - -- 1 ND ND ND 20 ND -- - -- ND -- ug/L 10/01/02 5 5 1 ND ND ND 13 ND -- - -- ND -- ug/L 04/09/03 5 5 1 ND ND ND 27 ND -- - -- ND -- ug/L 10/20/03 5 5 1 ND ND ND 26 ND -- - -- ND -- 03/24/04 5 5 1 ND ND ND 13 ND -- - -- ND -- Iug/t. L 10/27/04 5 5 1 ND ND ND 17.5 ND -- - -- ND -- ug/L 05/25/05 5 5 1 ND ND ND -- ND -- - -- ND -- ug/L 10/04/05 5 5 1 ND ND ND 5 ND ND - -- ND -- ug/L 04/25/06 5 5 1 ND ND ND ND ND ND - -- ND -- ug/L 10/04/06 5 5 1 ND ND ND 7 ND ND - -- ND ND ug/L 03/21/07 5 5 1 ND ND 0.48 J 12 ND 0.31 J - -- ND ND ug/L 10/02/07 5 5 1 ND ND 0.41 J 15.5 ND 0.3 J - -- ND ND ug/L 04/03/08 5 5 1 ND ND 0.47 J 18.1 ND 0.28 J 0.30 J ND ND ND ug/L 10/29/08 5 5 1 ND ND 0.32 J 18.2 ND 0.33 J 0.45 J ND 0.16 J ND ug/L 03/24/09 0.38 1.0 1 ND ND ND 3.1 ND ND ND ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND ND 9.5 ND ND ND ND - ND ug/L 03/22/10 0.13 1.0 1 ND Dry ND ND ND ND 0.44 J ND - ND ug/L 09/23/10 0.38 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/16/11 0.72 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 09/21/11 0.72 1.0 1 ND ND ND 1.1 ND ND ND ND - ND Iug/t. 03/21/12 0.15 1.0 1 ND ND ND 0.70 J ND ND ND ND ND ND L 09/20/12 0.15 1.0 1 ND ND ND 1.6 ND ND ND ND - ND ug/L 03/20/13 0.15 1.0 1 ND ND ND 3.9 ND ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND 1.3 ND ND ND ND - ND ug/L 03/27/14 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/115 0.15 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/17/16 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/16 0.15 1.0 1 ND ND ND ND ND ND ND ND -- ND ug/L tt."17 0.15 1.0 1 ND ND ND ND ND ND ND ND -- ND (re -sample) ug/L 05/03/17 0.15 1.0 1 -- -- - -- -- -- -- -- ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ND ND ND - ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/1 0.15 1.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/2611: 0.15 1.0 - ND ND ND ND ND ND ND ND ND ND u /L 09/18/19 0.15 1.0 ND ND ND ND ND ND ND ND ND GOLDER 9 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-8 AMW-iS AMW-iD AMW-2S AMW-2D MW-9 Vinyl chloride ug/L 12/05/94 10 10 1 ND ND ND ND -- -- -- -- ND -- NC 2L = 0.03 ug/L ug/L 02/14/95 10 10 1 ND ND ND ND -- -- -- -- ND -- EPA MCL =2 ug/L ug/L 04/03/95 10 10 1 ND ND ND ND -- -- -- -- ND -- ug/L 10,30/95 - -- 1 ND ND ND ND -- -- -- -- ND -- ug/L 04/08/96 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/24/96 - -- 1 ND -- ND ND - -- -- -- ND -- ug/L 04/15/97 - -- 1 ND -- ND ND - -- -- -- ND -- ug/L 10/29/97 - -- 1 ND 2 5 2 - -- -- -- 1 -- ug/L 05/14/98 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/11/98 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 06/04/99 - -- 1 ND ND ND ND - -- -- -- ND -- ug/L 10/29/99 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- 1 ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- 1 ND ND ND ND - -- - -- ND -- ug/L 05/15/0, - -- 1 ND ND ND ND - -- - -- ND -- ug/L 10,16/0, - -- 1 ND ND ND ND - ND - -- ND -- ug/L 04/24/02 - -- 1 ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- 1 ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- 1 ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- 1 ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 10 10 1 ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 10 10 1 ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 10 10 1 ND ND ND -- ND ND - -- ND -- ug/L 10/04/05 10 10 1 ND ND ND ND ND ND - -- ND -- ug/L 04/25/O6 10 10 1 ND ND ND ND ND ND - -- ND -- ug/L 10/04/O6 10 10 1 ND ND ND ND ND ND - -- ND ND ug/L 03/21/07 10 10 1 ND 0.43 J 2.35 ND ND 0.94 J - -- ND ND ug/L 10/02/07 10 10 1 ND 1.03 J 2.66 J 0.31 J ND 0.89 J - -- ND ND ug/L 04/03/08 10 10 1 ND ND 2.94 J ND ND 0.98 J 0.59 J ND ND ND ug/L 10/29/08 10 10 1 ND 0.25 J 2.36 0.49 J ND 0.82 J 0.57 J ND ND ND ug/L 03/24/09 0.30 1.0 1 ND ND 1.5 ND ND 0.60 J 0.53 J ND ND ND ug/L 09/22/09 0.30 1.0 1 ND ND 1.4 ND ND 0.67 J ND ND -- ND ug/L 03/22/10 0.083 1.0 1 ND Dry 1.2 ND ND 0.60 J ND ND -- ND ug/L 09/23/10 0.30 1.0 1 ND ND 1.2 ND ND ND ND ND -- ND ug/L 03/16/11 0.60 1.0 1 ND ND 1.3 ND ND ND ND ND -- ND ug/L 09/21/11 0:60 1.0 1 ND ND 1.5 ND ND 0.76 J ND ND -- ND ug/L 03/21/12 0.32 1.0 1 ND ND 0.88 J ND ND ND 0.55 J ND ND ND ug/L 09/20/12 0.32 1.0 1 ND ND ND ND ND 0.57 J 0.61 J ND -- ND ug/L 03/20/13 0.32 1.0 1 ND ND 1.0 0.77 J ND o.50 J 0.49 J ND ND ND ug/L 09/18/13 0.32 1.0 1 ND ND 0.81 J ND ND 0.48 J 0.48 J ND -- ND ug/L 03/27/14 0.32 1.0 1 ND ND 1.1 ND ND 0.84 J ND ND ND ND ug/L 09/18/14 0.32 1.0 1 ND ND 1.1 ND ND 0.54 J ND ND -- ND ug/L 03/18/15 0.32 1.0 1 ND ND 0.88 J ND ND 0.46 J ND ND ND ND ug/L 09/23/15 0.32 1.0 1 ND ND 0.96 J ND ND ND ND ND -- ND ug/L 03/17/16 0.32 1.0 1 ND ND 0.93 J ND ND 0.46 J ND ND ND ND ug/L 09/21/16 0.32 1.0 1 ND ND 0.74 J ND ND ND ND ND - ND ug/L 03/21/17 0.32 1.0 1 ND ND 0.92 J ND ND ND ND ND - ND (re -sample) ug/L 05/03/17 0.32 1.0 1 -- -- - -- -- -- -- -- ND ND ug/L 09/20/17 0.32 1.0 1 ND ND 0.73 J ND ND ND ND ND - ND ug/L 03/201 8 0.32 1.0 1 ND ND 0.51 J ND ND ND ND ND ND ND ug/L 09/23/18 0.32 1.0 - ND ND ND ND ND ND ND ND - ND ug/L 03/26/19 0.32 1.0 - ND ND 0.51 J ND ND ND ND ND ND ND u /L 09/18/19 0.32 1.0 ND ND ND ND ND ND ND ND ND 1,4-Di. re ug/L 09/23/18 1.2 -- - ND 11 18 ND ND 0.56 J 3.5 1.6 J - ND NC 2L=3 ug/L ug/L 03/26/19 1.2 2.0 - ND 2A 17 ND ND 7.2 2.1 ND ND ND u /L 09/18/19 1.2 2.0 ND 35 13 1.9 J ND 8.5 2.6 2.2 ND Diethylphthalate Zi- 12/OS/94 5 5 - -- -- -- -- - -- - -- -- NC 2L = 6000 ug/L ug/L 02/14/95 5 5 - -- -- -- -- - -- - -- -- -- EPA MCL = No Standard ug/L 04/03/95 5 5 -- -- -- -- -- - -- - -- -- -- ug/L 10/30/95 5 5 -- -- -- -- -- -- -- -- -- -- -- 06/06/96 -- -_ __ -- -- __ -- -- -- -- -- %ug/L !- 10/24/96 __ __ __ __ __ __ __ __ ug/L 04/15/97 -- -_ __ -- -- -- -- -- ug/L 10/295/97 -- -- -- ND ND ND ND -- -- -- -- ND -- ug/L 05/14/98 -- -- -- ND ND ND ND -- -- - -- ND -- ug/L 10/11/98 - -- - ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- - ND ND ND ND - -- - -- ND -- ug/L 101 9/99 - -- -- ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 02/27/01 - -- -- -- -- - -- - ug/L 0 /15/01 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 10/16/01 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 04/24/02 - -- - ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- - ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- - ND 19 ND ND ND ND - -- ND -- ug/L 03/24/04 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 -- ND 35.9 ND ND ND ND - -- ND -- ug/L 0 /25/05 5 5 -- ND 140 ND ND ND ND - -- ND -- ug/L 10/04/05 5 5 -- ND 548 ND ND ND ND - -- ND -- ug/L 04/25/006 5 5 -- ND 101 ND ND ND ND -- -- ND -- ug/L 10/04/06 5 5 -- ND 86.6 ND ND ND ND - -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 10/02/07 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 04/03/08 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 10/30/08 - -- -- ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 1.3 10 10 ND ND ND ND ND ND 1.5 J ND ND ND ug/L 09/22/09 - -- - -- -- -- -- - -- - ug/L 03/22/10 0.61 10 10 ND Dry ND ND - -- - -- -- ND ug/L 09/23/10 - -- - -- -- -- -- - -- - ug/L 03/1fi/11 2.1 10 6000 ND ND ND ND - -- - -- -- ND ug/L 09/21,111 - 10 - -- -- -- -- - -- - -- -- -- ug/L 03/21/12 2.1 10 6000 ND 3.1 B ND ND - -- - -- -- ND ug/L 09/20/12 _ ug/L 03/20/13 2.1 10 10 ND ND ND ND - -- - -- -- ND ug/L 09/18/13 2.1 10 10 -- -- -- -- - -- - -- -- -- ug/L 03/27/14 2.1 10 10 ND ND ND ND - -- - -- -- ND ug/L 09/18/14 2.1 10 10 -- -- -- -- - -- - -- -- -- ug/L 03/18/15 2.1 10 10 ND ND ND ND - -- - -- -- ND ug/L 09/23/15 2.1 10 10 -- -- - -- - -- - -- -- -- ug/L 03/17/16 2.1 10 10 ND ND ND ND - -- - -- -- ND ug/L 03/21/17 2.1 -- 10 ND ND ND ND - -- - -- -- ND ug/L 03/21/18 2.1 10 10 ND ND ND ND - -- - -- -- ND u /L 03/26/19 2.4 10 ND ND 27 ND ND Di-n-octylphthalate ug/L 10/29/97 - -- ND ND ND ND - -- - -- ND -- NC2L=100 ug/L ug/L 05/14/98 - -- -- ND ND ND ND - -- - -- ND -- EPA MCL = No Standard ug/L 10/11/98 - -- -- ND ND ND ND - -- - -- ND -- ug/L 06/04/99 - -- -- ND ND ND ND - -- - -- ND -- ug/L 10/29/99 - -- -- ND ND ND ND - -- - -- ND -- ug/L 04/20/00 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 11/07/00 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 05/15/01 - -- -- ND ND ND ND ND -- - -- ND -- ug/L 10/16/01 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 04/24/02 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 10/01/02 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 04/09/03 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 10/20/03 - -- - ND ND ND ND ND ND - -- ND -- ug/L 03/24/04 - -- -- ND ND ND ND ND ND - -- ND -- ug/L 10/27/04 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 05/25/05 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 10/04/05 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 04/25/06 5 5 - ND ND ND ND ND ND - -- ND -- ug/L 10/04/0 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 03/21/07 5 5 -- ND ND ND ND ND ND - -- ND -- ug/L 10/02/07 5 5 - ND ND ND ND ND ND -- -- ND -- 04/03/08 5 5 - ND ND ND ND ND ND -- -- ND -- %ug/L !- 10/30/08 5 -- - ND ND ND ND ND ND ND ND ND -- ug/L 03/24/09 2.0 10 10 ND ND ND ND ND ND ND ND ND ND ug/L 03/22/0 1.4 10 10 ND Dry ND ND - -- -- -- -- ND ug/L 03/16/11 3.1 10 10 ND ND ND ND - -- -- -- -- ND ug/L 03/21/12 3.1 10 10 ND 6.6 J ND ND - -- -- -- -- ND ug/L 03/20/13 3.1 10 10 ND ND ND ND - -- -- -- -- ND ug/L 03/27/14 3.1 10 10 ND ND ND ND - -- -- -- -- ND ug/L 03/18/15 3.1 10 10 ND ND ND ND - -- -- -- -- ND ug/L 03/17/16 3.1 -- 10 ND ND ND ND - -- -- -- -- ND ug/L 03/21/17 3.1 -- 10 ND ND ND ND - -- -- -- -- ND ug/L 03/21/18 3.1 10 10 ND ND ND ND - -- -- -- -- ND ug/L 03/26/19 3.1 10 ND ND ND ND ND GOLDER 10 of 11 January 2020 TABLE 4 Summary of Detected Constituents In MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 SWS Upgradient Detected Monitoring Constituent/Parameter Units Date MDL PQL Reporting Compliance Well Downgradient Compliance Wells Assessment Wells NA Well Blanks Limit MW5 MW-6 MW-7 MW-8 AMW-,S AMW-1D AMW-2S AMW-2D MW-9 3 &4-methylphenol ug/L 12/05/94 5 5 -- -- -- - -- -- -- -- - - -- NC 2L Standard = 400/40 ug/L ug/L 02/14/95 5 5 -- -- -- - -- -- -- -- -- -- -- EPA MCL = No Standard ug/L 04/03/95 5 5 -- -- -- - -- -- -- -- - -- -- ug/L 10/30/95 5 5 -- -- -- - -- -- -- -- -- -- -- ug/L 04/08/96 5 5 ug/L 05/29/96 -- -- -- -- -- -- -- __ ug/L O6/06/96 __ __ __ .. __ __ -- .. ug/L 10/24/96 __ __ __ _ __ __ ug/L 04/15/97 __ __ .. .. .. __ -- ug/L 10/29/97 -- -- -- NO 140 NO NO - -- -- -- NO -- ug/L 05/14/98 -- -- -- NO 160 NO NO - -- -- -- NO -- ug/L 10/11/98 -- -- -- NO NO NO NO - -- -- -- NO -- ug/L O6104/99 -- -- -- NO 260 NO NO - -- - -- NO -- ug/L 10/29/99 -- -- -- NO NO NO NO - -- - -- NO -- ug/L 04/20/00 -- -- -- NO 57 NO NO NO -- - -- NO -- ug/L 11/07/00 -- -- - NO NO NO NO NO -- - -- NO -- ug/L 02/27/01 -- -- - -- -- -- -- ug/L 05/15/01 -- -- - NO NO ND ND NO -- - -- NO -- ug/L 10/i6/01 -- -- - NO ND ND ND NO NO - -- NO -- ug/L 04/24/02 -- -- -- NO NO NO NO ND NO - -- ND -- ug/L 10/01/02 -- -- -- NO NO NO NO NO NO - -- NO -- ug/L 04/09/03 -- -- -- NO NO NO NO NO NO - -- NO -- ug/L 10/20/03 -- -- -- NO 27 NO NO NO NO - -- NO -- ug/L 03/24/04 -- -- -- NO 1930 NO NO NO NO - -- NO -- ug/L 10/27/04 5 5 -- NO 2880 NO NO NO NO - -- NO -- ug/L 05/25/05 5 5 - NO 398 NO NO NO NO - -- NO -- ug/L 10/04/05 5 5 -- NO 109 NO NO NO NO - -- NO -- ug/L 04/25/06 5 5 -- NO 25.4 NO NO NO NO - -- NO -- ug/L 10/04/06 5 5 -- NO 16.4 NO NO ND NO - -- NO -- ug/L 03/21/07 5 5 -- NO NO NO NO NO NO - -- NO -- ug/L 10/02/07 5 5 -- NO NO NO NO NO NO - -- NO -- ug/L 04/03/08 5 5 - NO NO NO NO NO NO - -- NO -- ug/L 10/30/08 5 -- - NO 4.26 J NO NO NO NO NO NO NO -- ug/L 03/24/09 1.9 20 10 NO NO NO NO NO NO NO NO NO NO ug/L 09/22/09 - -- - -- -- -- -- -- ug/L 03/22/10 1.8 10 10 NO Dry NO NO -- -- -- -- -- NO ug/L 09/23/10 - -- - -- -- -- -- -- ug/L 03/16/11 1.6 10 10 NO NO NO NO -- -- - -- -- ND ug/L 09/21/11 1.6 10 10 -- -- -- -- -- -- - -- -- -- ug/L 03/21/12 1.6 10 10 NO NO NO NO -- -- - -- -- ND ug/L 09/20/12 1.6 -- 10 -- -- -- -- -- -- -- -- -- -- ug/L 03/20/13 1.6 10 10 NO NO NO NO -- -- -- -- -- ND ug/L 09/18/13 1.6 __ 10 ug/L 03/27/14 1.6 10 10 NO NO ND NO -- -- - -- -- ND ug/L 09/18/14 1.6 -- 10 -- -- - -- - -- - -- -- -- ug/L 03/18/15 10 NO NO NO NO - -- - -- -- ND ug/L 09/23/15 1.6 -- 10 -- -- - -- - -- - -- -- -- ug/L 03/17/16 1.6 -- 10 NO NO NO NO - -- - -- -- ND ug/L 03/21/17 1.6 -- 10 NO NO NO NO - -- - -- -- NO ug/L 0.1/18 1.6 10 10 NO NO NO NO - -- - -- -- ND u /L 03/26/19 2.1 10 NO NO 2.6 J NO NO 2,4-D ug/L 10/30/95 - -- - NO NO NO NO - -- - -- NO -- NC 2L = 70 ug/L ug/L 10/24/96 - -- - NO -- NO NO - -- - -- NO -- EPA MCL = 70 ug/L ug/L 10/29/97 - -- -- NO ND NO NO - -- - -- NO -- ug/L 05/14/98 - -- -- NO NO NO NO - -- - -- NO -- ug/L 10/11/98 - -- -- NO NO NO NO - -- - -- NO -- ug/L O6/04/99 - -- -- NO NO NO NO - -- - -- NO -- ug/L 10/29/99 - -- -- NO ND NO NO - -- - -- NO -- ug/L 04/20/00 - -- -- NO NO NO NO NO -- - -- NO -- ug/L 11/07/00 - -- -- NO ND ND NO NO -- - -- NO -- ug/L 0S/15/01 - -- -- NO NO NO NO NO -- - -- NO -- ug/L 10/16/01 - -- -- NO NO NO NO NO NO - -- NO -- ug/L 04/24/02 - -- - NO NO NO NO NO NO - -- NO -- ug/L 10/01/02 - -- - NO NO ND NO ND NO - -- NO -- ug/L 04/09/03 - -- -- NO NO NO NO NO NO - -- ND -- ug/L 10/20/03 - -- -- NO ND NO NO NO NO - -- NO -- ug/L 03/24/04 - -- -- NO NO ND NO NO NO - -- NO -- ug/L 10/27/04 - -- - NO ND NO NO NO NO - -- NO -- ug/L 05/25/05 - -- -- NO NO NO NO NO NO - -- NO -- ug/L 10/04/05 - -- -- NO NO NO NO NO NO - -- NO -- ug/L 04/25/06 - -- -- NO NO NO NO NO NO - -- NO -- ug/L 10/04/06 - -- -- NO NO NO NO NO NO - -- NO -- ug/L 0311/07 - -- - NO NO NO NO NO NO - -- NO -- ug/L 10/02/07 - -- - NO NO NO NO NO NO - -- NO -- ug/L 04/03/08 - -- - NO NO ND NO NO NO - -- NO -- ug/L 10/30/08 - -- - NO ND ND NO NO NO NO NO NO -- ug/L 03/24/09 0.091 0.50 2 NO NO NO NO NO NO NO NO NO NO ug/L 03/22/10 0.091 0.50 2 NO Dry ND NO -- -- - -- -- NO ug/L 03/16/11 0.15 0.50 2 NO NO NO NO -- -- - -- -- NO ug/L 03/21/12 0.16 0.50 2 NO ND ND NO -- -- - -- -- NO ug/L 03/20/13 0.16 0.50 2 NO NO 0.75 J NO -- -- - -- -- NO ug/L 03/27/14 0.27 0.50 2 NO NO ND NO -- -- - -- -- ND ug/L 03/1 8/1 5 0.27 -- 2 NO NO NO NO -- -- - -- -- NO ug/L 03/17/16 0.27 -- 2 NO NO NO NO -- -- - -- -- ND ug/L 03/21/17 0.27 -- 2 NO NO NO NO -- -- - -- -- NO ug/L 03/21/18 0.27 0.50 2 NO NONO NO -- -- - -- -- ND u /L 03/26/19 0.27 0.50 ND ND ND ND NO Notes: ug/L= micrograms par liter mg/L = milligrams per liter ND- Not detected at the stated reporting limit J = estimated concentration B = Blank -qualified result --= no data available MDL = laboratory method detection limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL orlab-specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2019 event: Antimony and Thallium in MW-5, MW-6, MW-7, MW-8, MW-9, AMW-1S, AMWAD, AMW-2S, and AMW-2D (2x). 4 GOLDER 11 of 11 January 2020 TABLES Summary of Field Parameters for MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Upgradient Downgradlent Compliance Wells Assessment Wells TVA Well Detected Monitoring Parameter Units Date Compliance Well MW-5 MW-6 MW-7 MW-8 AMW-IS AMWAD AMW-2S AMW-2D MW-9 pH (field) S.U. 10/04/06 5.81 6.06 5.54 5.90 6.17 6.15 -- -- 5.35 S.U. 10102J07 5.60 5.88 5.28 5.23 5.81 5.90 -- -- 5.37 S.U. 04/03/08 5.76 6.05 5.30 5.63 6.00 5.95 6.24 7.35 4.93 S.U. 03/24/09 6.94 6.43 6.42 6.64 6.21 6.82 7.11 7.56 6.31 S.U. 09/22/09 5.58 5.32 5.60 5.72 5.87 5.91 5.92 6.27 -- S.U. 03/22/10 5.58 Dry 5.44 6.01 6.07 5.62 5.98 6.40 -- S.U. 09/23/10 5.48 6.00 5.67 6.04 5.27 5.79 5.85 6.26 -- S.U. 03/16/11 5.53 5.91 5.74 6.15 5.29 5.93 6.08 6.42 -- S.U. 09/21/11 5.65 6.01 5.92 5.88 5.11 5.88 6.38 6.44 -- S.U. 03/21/12 5.92 5.67 5.79 5.61 4.76 5.79 6.01 6.26 4.86 S.U. 09/20/12 5.94 6.81 7.20 5.39 6.20 6.62 7.38 7.69 -- S.U. 03/20/13 5.60 6.11 6.02 6.21 5.84 6.06 5.95 6.31 4.85 S.U. 09/18/13 5.79 6.02 6.19 6.25 6.30 6.16 6.17 6.56 -- S.U. 03/27/14 5.29 6.24 5.46 5.94 6.33 6.31 5.87 7.35 4.42 S.U. 09/18/14 6.49 6.63 6.50 6.14 6.15 6.49 7.40 6.77 -- S.U. 03/18/15 5.71 6.25 5.93 6.17 6.36 6.20 6.21 6.23 4.97 S.U. 09/23/15 5.63 6.19 5.95 5.96 6.03 6.09 5.94 6.39 -- S.U. 03/15/16 5.15 5.43 5.58 6.08 5.48 5.94 5.73 5.83 4.64 S.U. 09/21/16 4.74 6.21 6.10 6.12 5.67 6.19 6.28 6.53 -- S.U. 03/21/17 5.20 6.03 5.73 5.95 5.55 5.88 5.67 5.97 4.72 (re -sample) S.U. 05/03/17 - -- -- -- -- - 3.97 S.U. 09/20/17 5.78 5.58 5.96 6.17 5.37 6.02 6.00 6.33 -- (verification event) S.U. 12/19/17 - -- -- 6.36 -- -- -- -- -- S.U. 03/21/18 5.63 5.90 6.05 6.84 5.94 6.53 6.52 6.65 4.78 (verification event) S.U. 06/15/18 - -- -- -- 5.11 -- 5.91 -- -- S.U. 09/24/18 5.60 5.8 5.95 6.32 5.6 7.71 6.03 5.71 -- S.U. 03/25/19 5.63 5.98 6.01 6.04 5.28 6.18 6.06 6.13 4.93 S.U. 09/18/19 4.77 6.03 5.79 6.35 4.80 5.90 6.23 6.32 Specific Conductivity (field) uS/cm 10/04/06 90 953 319 530 531 395 -- -- 56 US/Cm 10/02/07 115 451 189 319 715 597 -- -- 85 uS/cm 04/03/08 98 250 197 552 597 585 243 140 59 us/cm 03/24/09 110 150 330 730 200 650 610 130 120 uS/cm 09/22/09 101 125 340 661 441 675 277 111 -- us/cm 03/22/10 148 Dry 339 884 89 560 248 109 -- us/cm 09/23/10 181 1262 451 999 93 603 219 124 us/cm 03/16/11 166 92 431 529 140 589 259 119 -- us/cm 09/21/11 146 1228 494 989 94 563 282 114 -- us/cm 03/21/12 124 992 455 845 188 504 251 93 127 us/cm 09/20/12 116 257 468 488 209 513 251 111 -- us/cm 03/20/13 90 147 510 863 211 479 238 82 113 us/cm 09/18/13 171 965 995 1022 598 646 314 136 -- us/cm 03/27/14 171 391 770 1047 254 694 290 176 195 uS/cm 09/18/14 180 1797 649 605 200 749 347 114 -- us/cm 03/18/15 191 157 716 805 548 700 310 143 160 uS/cm 09/23/15 128 1876 562 911 558 634 262 120 -- us/cm 03/15/16 228 389 790 967 264 764 219 152 154 us/cm 09/21/16 180 1640 659 1140 192 703 200 144 -- us/cm 03/21/17 100 1342 601 960 273 597 240 143 109 (re -sample) uS/cm 05/03/17 - -- -- -- -- - 139 us/cm 09/20/17 122 360 580 1141 144 644 235 153 -- (verification event) uS/cm 12/19/17 - -- -- 1028 -- -- -- -- -- us/cm 03/21/18 207 242 582 1124 299 668 246 162 179 (verification event) uS/cm 06/15/18 - -- -- -- 265 -- 245 -- -- us/cm 09/24/18 176 540 737 1047 239 670 224 193 -- US/cm 03/25/19 270 237 806 728 268 499 215 174 205 us/cm 09/18/19 168 1393 670 1126 160 646 202 178 Temperature (field) Celsius 10/04/06 13.8 16.6 18.0 15.7 15.4 14.7 -- -- 13.7 Celsius 10/02/07 14.1 17.4 17.9 16.0 15.1 14.8 -- -- 13.6 Celsius 04/03/08 13.2 12.1 16.5 15.5 13.0 12.4 13.01 15.30 13.1 Celsius 03/24/09 12.6 14.9 18.5 17.3 17.6 16.8 13.6 11.9 13.7 Celsius 09/22/09 16.7 19.95 19.91 22.78 17.31 16.68 17.22 17.47 -- Celsius 03/22/10 13.17 Dry 14.97 11.76 10.08 10.97 9.33 7.41 -- Celsius 09/23/10 14.92 19.69 18.65 18.77 16.25 15.78 17.11 18.35 -- Celsius 03/16/11 12.61 9.68 15.64 15.08 11.96 11.95 10.02 9.24 -- Celsius 09/21/11 14.32 17.37 17.38 16.06 16.29 15.85 17.06 17.34 -- Celsius 03/21/12 15.20 14.46 16.53 17.08 15.47 15.45 13.25 12.95 14.46 Celsius 09/20/12 14.11 17.35 17.30 15.92 16.86 17.05 16.76 18.16 -- Celsius 03/20/13 12.82 13.84 16.78 16.17 12.68 13.26 10.12 9.10 11.54 Celsius 09/18/13 14.3 16.7 16.6 16.2 15.9 14.6 14.6 14.0 -- Celsius 03/27/14 12.7 13.4 15.4 15.3 13.4 13.4 11.0 10.9 11.3 Celsius 09/18/14 14.5 18.6 17.7 16.8 17.2 17.4 18.6 19.2 -- Celsius 03/18/15 14.2 12.7 16.2 16.5 14.8 14.7 10.9 13.8 13.5 Celsius 09/23/15 15.0 16.5 17.6 17.1 16.5 16.2 14.7 15.5 -- Celsius 03/15/16 15.3 15.8 15.9 17.3 16.2 16.5 15.0 15.1 14.5 Celsius 09/21/16 15.0 17.9 17.7 17.8 16.9 17.0 16.3 15.4 -- Celsius 03/21/17 16.1 14.0 16.5 15.6 15.0 14.9 13.0 13.5 14.4 (re -sample) Celsius 05/03/17 - -- -- -- -- - 15.5 Celsius 09/20/17 15.24 21.61 18.02 18.02 18.25 17.38 16.46 16.98 -- (verification event) Celsius 12/19/17 - -- -- 17.44 -- -- -- -- -- Celsius 03/21/18 11.90 11.7 15.6 15.09 14.01 13.89 11.51 11.61 13.40 (verification event) Celsius 06/15/18 - -- -- -- 16.8 -- 16.7 -- -- Celsius 09/24/18 16.16 18.47 17.71 18.27 17.81 16.57 15.8 15.96 -- Celsius 03/25/19 14.0 13.1 16.3 16.0 13.6 14.4 11.9 12.0 12.3 Celsius 09/18/19 15.5 18.1 17.4 17.7 17.1 16.5 15.3 15.8 a COLDER 1of2 January 2020 TABLES Summary of Field Parameters for MSW Monitoring Wells Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Upgmdient Downgradlent Compliance Wells Assessment Wells TVA Well Detected Monitoring Parameter Units Date Compliance Well MW5 MW-6 MW-7 MW-8 AMW-IS AMW-1D AMW-2S AMW-2D MW-9 Turbidity (field) NTU 03/24/09 59.0 60.5 29.1 83.9 18.8 4.37 41.1 17.2 9.04 NTU 09/22/09 39.1 11.6 23.7 97.6 20.2 6.68 91.0 46.0 -- NTU 03/22/10 73.8 Dry 17.0 33.8 19.0 9.68 24.8 18.4 -- NTU 09/23/10 48.4 11.0 24.3 51.1 12.8 4.35 34.2 6.63 -- NTU 03/16/11 51.7 38.9 5.93 30.8 12.4 0.77 14.2 5.17 -- NTU 09/21/11 40.1 140 64.9 280 10.3 2.18 64.9 3.41 -- NTU 03/21/12 88.2 54.9 8.27 15.5 6.71 4.33 6.57 4.51 24.9 NTU 09/20/12 257 30.2 82.8 90.0 85.1 16.7 163 6.46 -- NTU 03/20/13 107 93.6 71.4 89.5 5.15 1.74 5.25 1.08 4.20 NTU 09/18/13 66.1 >1000 27.2 60.7 72.4 19.3 192 25.3 -- NTU 03/27/14 2.18 47.4 1.67 99.4 1.66 1.48 36.5 2.02 2.83 NTU 09/18/14 0.75 65.4 0.58 1.80 1.41 0.55 4.41 0.63 -- NTU 03/18/15 71.3 28.5 61.2 23.1 31.8 2.43 43.2 3.15 12.1 NTU 09/23/15 21.8 3.77 21.9 3.72 26.3 0.34 9.15 8.69 -- NTU 03/15/16 3.21 8.53 1.77 25.4 26.5 0.46 17.8 1.78 1.65 NTU 09/21/16 8.72 5.92 1.97 24.5 11.3 1.93 18.6 1.60 -- NTU 03/21/17 11.1 2.29 0.64 20.3 7.68 0.78 12.5 1.27 (re -sample) NTU 05/03/17 - -- -- -- -- -- -- -- 1.40 NTU 09/20/17 6.77 4.17 0.17 8.13 2.89 0.26 1.49 1.50 -- (verification event) NTU 12/19/17 - -- -- 5.54 -- -- -- -- -- NTU 03/21/18 9.70 2.88 0.36 8.76 7.56 1.07 5.51 2.69 1.27 (verification event) NTU O6/15/18 - -- -- -- 3.76 -- 1.83 -- -- NTU 09/24/18 8.32 8.73 0.53 5.10 4.64 0.94 1.67 0.60 -- NTU 03/25/19 2.92 2.95 4.78 5.68 4.16 5.46 1.21 0.61 0.62 NTU 09/18/19 8.45 3.40 2.84 8.00 0.02 1.95 1.21 1.43 Oxidation Reduction Potential (field) mV 09/22/09 178.9 -30.3 76.2 132.5 20.5 39.0 30.4 88.8 -- mV 09/23/15 148.0 -26.1 90.7 103.1 18.8 42.9 69.5 36.2 -- mV 03/15/16 253.3 -32.9 52.4 -16.8 129.1 87.1 125.3 150.8 270.0 mV 09/21/16 318.0 -43.2 43.1 -26.6 121.7 77.8 60.9 56.0 -- mV 03/21/17 262.8 -38.6 378 75.9 133 -80.4 118.6 150.3 -59.0 (re -sample) mV 05/03/17 - -- -- -- -- - 464.2 mV 09/20/17 89.0 6.8 103.2 16.5 215.4 185.5 128.1 153.3 -- (verification event) mV 12/19/17 - -- -- -6.2 -- -- -- -- -- mV 03/21/18 359.3 73.9 337.5 -19.5 115.6 69.5 70.4 66.4 364.1 (verification event) mV O6/15/18 - -- -- -- 248.5 -- 362.1 -- -- mV 09/24/18 124.6 -55.2 55.6 5.2 67.4 -152.6 3.3 -16.8 -- mV 03/25/19 195.5 12.2 31.5 60.0 214.4 99.7 176.5 137.1 360.5 mV 09/18/19 192.4 -54.8 51.2 -35.5 150.0 54.2 93.9 80.2 Dissolved Oxygen (field) mg/L 09/22/09 7.85 1.49 1.18 1.31 1.66 1.21 1.03 3.11 -- mg/L 09/23/15 7.30 1.70 1.08 0.78 4.80 0.33 0.64 4.21 -- mg/L 03/15/16 8.78 0.14 0.46 0.12 0.35 0.35 0.11 1.27 0.55 mg/L 09/21/16 7.41 0.39 1.59 1.09 2.45 1.17 0.80 2.36 -- mg/L 03/21/17 9.45 0.98 0.30 1.39 0.40 0.48 1.41 2.78 0.92 (re -sample) mg/L 05/03/17 - -- -- -- -- -- -- -- 2.78 mg/L 09/20/17 2.21 1.39 0.72 1.07 4.48 1.26 0.39 1.15 -- (verification event) mg/L 12/19/17 - -- -- 1.51 -- -- -- -- -- mg/L 03/21/18 6.59 0.27 0.49 1.04 0.15 1.28 0.25 1.04 1.44 (verification event) mg/L 06 15 18 - -- -- -- 2.01 -- 0.93 -- -- mg/L 09/24/18 7.37 0.15 0.18 0.59 3.3 1.49 2.25 2.61 -- mg/L 03/25/19 8.16 0.11 0.20 0.08 2.42 1.66 0.43 2.00 1.96 mg/L 1 09/18/19 1 7.28 1 3.66 1.47 0.71 1.00 0.45 1.44 1.83 Notes: NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter S.U. = Standard Units mg/L = milligrams per liter mV = Millivolts - = no data available 1) Historical data prior to March 2009 provided by Henderson County and CDM. a COLDER 2of2 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Antimony ug/L 12/05/94 30 30 6 ND ND ND ND -- Human Health = 640 ug/L ug/L 02/14/95 30 30 6 ND ND -- ND -- ug/L 04/03/95 30 30 6 ND ND ND ND -- ug/L 10/30/95 30 30 6 ND ND ND ND -- ug/L 04/08/96 30 30 6 -- -- -- ND -- ug/L 10/24/96 30 30 6 ND ND ND ND -- ug/L 04/15/97 30 30 6 ND ND ND 5 -- ug/L 10/29/97 30 30 6 18 ND ND ND -- ug/L 05/14/98 -- -- 6 ND ND ND ND -- ug/L 11/11/98 -- -- 6 ND ND ND ND -- ug/L O6/04/99 -- -- 6 ND -- ND ND -- ug/L 10/29/99 -- -- 6 ND -- ND ND -- ug/L 04/20/00 -- -- 6 ND -- ND ND -- ug/L 11/07/00 -- -- 6 -- -- ND ND -- ug/L 10/16/01 30 30 6 ND -- ND ND -- ug/L 04/24/02 30 30 6 ND -- ND ND -- ug/L 10/01/02 30 30 6 ND -- ND ND -- ug/L 04/09/03 30 30 6 ND -- ND ND -- ug/L 10/20/03 30 30 6 ND ND ND ND -- ug/L 03/24/04 30 30 6 ND ND ND ND -- ug/L 10/27/04 30 30 6 ND ND ND ND -- ug/L 05/25/05 30 30 6 ND ND ND ND -- ug/L 10/04/05 30 30 6 ND ND ND ND -- ug/L 04/25/06 30 30 6 ND ND ND ND -- ug/L 10/04/06 30 30 6 ND ND ND ND ND ug/L 03/21/07 6.00 6.00 6 ND ND ND ND ND ug/L 10/02/07 0.05 6.00 6 ND ND ND ND ND ug/L 04/03/08 0.68 2.00 6 ND ND ND ND ND ug/L 10/29/08 0.68 2.00 6 ND -- ND ND ND ug/L 03/24/09 0.68 2.00 6 ND ND ND ND ND ug/L 09/22/09 0.073 2.00 6 ND ND ND ND ND ug/L 03/22/10 0.22 2.00 6 ND ND 0.521 J ND ND ug/L 09/23/10 0.22 2.00 6 ND ND ND ND ND ug/L 03/16/11 0.22 2.00 6 ND ND ND ND ND ug/L 09/21/11 0.22 2.00 6 ND ND ND ND ND ug/L 03/21/12 0.22 2.00 6 ND ND ND ND ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND ND ug/L 03/20/13 0.22 2.00 6 ND ND ND ND ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND ND ug/L 03/27/14 0.22 2.00 6 ND ND ND ND ND ug/L 09/18/14 0.22 2.00 6 ND ND ND ND ND ug/L 03/18/15 0.22 2.00 6 ND 0.681 J 0.230 J ND ND ug/L 09/23/15 0.22 2.00 6 ND ND ND ND 0.331 J ug/L 03/15/16 0.22 2.00 6 ND 0.334 J ND ND ND ug/L 09/20/16 0.22 2.00 6 ND ND ND ND ND ug/L 03/21/17 0.22 2.00 6 ND ND ND ND ND ug/L 09/20/17 0.37 2.00 6 -- ND ND ND ND (re -sample) ug/L 10/02/17 0.37 2.00 6 ND -- -- -- ND ug/L 03/21/18 0.37 5.00 6 ND ND ND ND ND ug/L 09/25/18 1.85 5.00 -- ND ND ND ND ND ug/L 03/26/19 0.74 2.00 -- ND ND ND ND ND u /L 09/18/19 0.74 2.00 ND ND ND ND ND Arsenic ug/L 12/05/94 10.0 10.0 10 ND ND ND ND -- SW Standard ug/L 02/14/95 10.0 10.0 10 ND ND -- ND -- Acute: 340 ug/L ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- Chronic: 150ug/L ug/L 10/30/95 10.0 10.0 10 ND 12 ND ND -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- ug/L 04/15/97 -- -- 10 ND ND ND ND -- ug/L 10/29/97 -- -- 10 19 ND ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 10.0 10.0 10 ND -- ND ND -- ug/L 10/20/03 10.0 10.0 10 ND ND ND ND -- ug/L 03/24/04 10.0 10.0 10 ND ND ND ND -- ug/L 10/27/04 10.0 10.0 10 ND ND 11.7 ND -- ug/L 05/25/05 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/05 10.0 10.0 10 ND ND ND ND -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND ND ug/L 03/21/07 10.0 10.0 10 ND ND 0.56 J 1.57 J ND ug/L 10/02/07 10.0 10.0 10 ND ND ND ND ND ug/L 04/03/08 10.0 10.0 10 ND ND 4.8 J 2.52 J ND ug/L 10/29/08 10.0 10.0 10 2.5 J -- 4.65 J 4.14 J ND ug/L 03/24/09 2.8 10.0 10 ND ND ND ND ND J ug/L 09/22/09 2.8 10.0 10 4.69 B 2.94 B 3.11 B ND 2.90 ug/L 03/22/10 2.8 10.0 10 ND ND ND ND ND ug/L 09/23/10 2.8 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.8 10.0 10 ND ND ND ND ND ug/L 09/21/11 2.8 10.0 10 ND ND 4.96 J ND ND ug/L 03/21/12 2.8 10.0 10 ND 4.18 J ND ND ND J ug/L 09/20/12 2.8 10.0 10 ND ND ND ND 3.27 ug/L 03/20/13 2.8 10.0 10 ND ND ND ND ND ug/L 09/18/13 5.4 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.4 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.4 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.4 10.0 10 ND ND ND ND ND ug/L 09/20/16 6.8 10.0 10 ND ND ND ND ND ug/L 03/21/17 6.8 10.0 10 ND 9.55 B ND ND 9.82 J ug/L 09/20/17 6.8 10.0 10 -- ND ND ND ND (re -sample) ug/L 10/02/17 6.8 10.0 10 ND -- -- -- ND ug/L 03/21/18 6.8 10.0 10 ND 7.70 J ND ND ND ug/L 09/25/18 7.6 10.0 -- ND ND ND ND ND ug/L 03/26/19 7.6 10.0 -- ND ND ND ND ND u /L 09/18/19 7.6 10.0 ND ND ND ND ND GOLDER 1of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Barium ug/L 12/05/94 500 500 100 ND ND ND ND -- Human Health = 200000 ug/L ug/L 02/14/95 500 500 100 131 ND -- ND -- ug/L 04/03/95 500 500 100 ND ND ND ND -- ug/L 10/30/95 500 500 100 ND ND ND ND -- ug/L 04/08/96 500 500 100 -- -- -- ND -- ug/L 10/24/96 -- -- 100 ND ND ND ND -- ug/L 04/15/97 -- -- 100 130 220 ND ND -- ug/L 10/29/97 -- -- 100 400 ND ND ND -- ug/L 05/14/98 -- -- 100 ND ND ND ND -- ug/L 11/11/98 -- -- 100 ND ND ND ND -- ug/L O6/04199 -- -- 100 ND -- ND ND -- ug/L 10/29/99 -- -- 100 ND -- ND ND -- ug/L 04/20/00 -- -- 100 ND -- ND ND -- ug/L 11/07/00 -- -- 100 -- -- ND ND -- ug/L 10/16/01 -- -- 100 ND -- 111 ND -- ug/L 04/24/02 -- -- 100 ND -- ND ND -- ug/L 10/01/02 -- -- 100 ND -- ND ND -- ug/L 04/09/03 500 500 100 ND -- ND ND -- ug/L 10/20/03 500 500 100 ND ND ND ND -- ug/L 03/24/04 500 500 100 ND ND ND ND -- ug/L 10/27/04 500 500 100 ND ND ND ND -- ug/L 05/25/05 500 500 100 ND ND ND ND -- ug/L 10/04/05 500 500 100 ND 4310 ND ND -- ug/L 04/25/06 500 500 100 ND ND ND ND -- ug/L 10/04/06 500 500 100 ND ND ND ND ND J ug/L 03/21/07 500 500 100 22.7 J 193 342 36.3 J ND J ug/L 10/02/07 500 500 100 77.5 B 266 697 42.2 B 16.1 ug/L 04/03/08 500 500 100 64.6 J 171 504 47.9 B 10.1 ug/L 10/29/08 500 500 100 78.6 B -- 732 B 65.1 B ND ug/L 03/24/09 4.2 10.0 100 73.2 J 273 575 42.1 J ND J ug/L 09/22/09 1.0 10.0 100 75.6 J 130 253 64.8 J ND ug/L 03/22/10 1.0 10.0 100 62.7 J 144 83.3 J 58.1 J 1.54 ug/L 09/23/10 1.0 10.0 100 45.6 J 163 361 26.1 J ND ug/L 03/16/11 1.0 10.0 100 89.8 J 265 199 63.2 J ND ug/L 09/21/11 1.0 10.0 100 65.3 J 200 253 52.5 J ND ug/L 03/21/12 1.0 10.0 100 46.2 J 240 323 38.0 J ND J ug/L 09/20/12 1.0 10.0 100 70.1 J 219 439 43.4 J ND J ug/L 03/20/13 1.0 10.0 100 41.8 J 171 194 42.0 J 1.34 ug/L 09/18/13 1.0 10.0 100 49.8 J 220 162 35.1 J 1.08 J ug/L 03/27/14 1.0 10.0 100 53.9 J 168 183 47.2 J ND ug/L 09/18/14 1.0 10.0 100 25.0 J 128 185 30.2 J 1.96 J ug/L 03/18/15 1.0 10.0 100 49.7 J 251 169 41.0 J ND ug/L 09/23/15 1.0 10.0 100 69.6 J 120 186 19.0 B 4.08 ug/L 03/15/16 1.0 10.0 100 51.1 J 182 128 44.8 J ND ug/L 09/20/16 1.0 10.0 100 17.6 J 131 177 24.7 J ND ug/L 03/21/17 1.0 10.0 100 32.8 J 219 223 25.9 J ND ug/L 09/20/17 1.0 10.0 100 -- 363 150 35.5 J ND (re -sample) ug/L 10/02/17 1.0 10.0 100 32.7 J -- -- -- ND ug/L 03/21/18 1.0 10.0 100 35.0 J 195 116 41.9 J ND ug/L 09/25/18 1.1 10.0 -- 34.1 185 115 31.2 ND ug/L 03/26/19 1.1 10.0 -- 47.9 171 72.6 44.4 ND u /L 09/18/19 1.1 10.0 38.1 168 103 29.6 3.97 J Beryllium ug/L 12/05/94 2.00 2.00 1 ND ND ND ND -- SW Standard ug/L 02/14/95 2.00 2.00 1 ND ND -- ND -- Acute = 65 ug/L ug/L 04/03/95 2.00 2.00 1 ND ND ND ND -- Chronic = 6.5 ug/L ug/L 10/30/95 2.00 2.00 1 ND ND ND ND -- ug/L 04/08/96 2.00 2.00 1 -- -- -- ND -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- ug/L 10/29/97 -- -- 1 9 ND ND ND -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- ug/L O6/04/99 -- -- 1 ND -- ND ND -- ug/L 10/29/99 -- -- 1 ND -- ND ND -- ug/L 04/20/00 -- -- 1 ND -- ND ND -- ug/L 11/07/00 -- -- 1 -- -- ND ND -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 2.00 2.00 1 ND ND ND ND -- ug/L 10/04/05 2.00 2.00 1 ND 4.07 ND ND -- ug/L 04/25/06 2.00 2.00 1 ND ND ND ND -- ug/L 10/04/06 2.00 2.00 1 ND ND ND ND ND ug/L 03/21/07 2.00 2.00 1 ND ND ND ND ND ug/L 10/02/07 2.00 2.00 1 1.97 B 2.28 B 3.9 B 1.97 B 6.01 ug/L 04/03/08 2.00 2.00 1 1.93 5.01 2.80 2.73 ND ug/L 10/29/08 2.00 2.00 1 6.46 B -- 10.2 B 7.9 B ND ug/L 03/24/09 0.08 1.00 1 ND ND 1.01 ND ND ug/L 09/22/09 0.10 1.00 1 ND ND 0.656 J ND ND ug/L 03/22/10 0.10 1.00 1 ND ND 0.318 J ND ND ug/L 09/23/10 0.10 1.00 1 ND ND 0.820 J ND ND ug/L 03/16/11 0.10 1.00 1 ND ND 0.543 J ND ND ug/L 09/21/11 0.10 1.00 1 ND ND 0.362 J ND ND ug/L 03/21/12 0.10 1.00 1 ND ND 0.736 J ND ND ug/L 09/20/12 0.10 1.00 1 ND ND 0.694 J ND ND ug/L 03/20/13 0.10 1.00 1 ND ND 0.227 J ND ND ug/L 09/18/13 0.10 1.00 1 ND ND ND ND ND ug/L 03/27/14 0.10 1.00 1 ND ND 0.222 J ND ND ug/L 09/18/14 0.10 1.00 1 ND ND ND ND ND ug/L 03/18/15 0.10 1.00 1 ND ND 0.163 J ND ND ug/L 09/23/15 0.10 1.00 1 ND ND ND ND ND ug/L 03/15/16 0.10 1.00 1 ND ND ND ND ND ug/L 09/20/16 0.10 1.00 1 ND ND ND ND ND ug/L 03/21/17 0.10 1.00 1 ND ND ND ND ND ug/L 09/20/17 0.13 1.00 1 -- ND ND ND ND (re -sample) ug/L 10/02/17 0.13 1.00 1 0.173 B -- -- -- 0.233 J ug/L 03/21/18 0.13 1.00 1 ND ND 0.174 J ND ND ug/L 09/25/18 0.16 1.00 -- ND ND ND ND ND ug/L 03/26/19 0.16 1.00 -- ND ND 0.191 J ND ND u /L 09/18/19 0.16 1.00 ND ND ND ND ND GOLDER 2of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45M Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Cadmium ug/L 12/05/94 1.00 1.00 1 ND ND ND ND -- SW Standard ug/L 02/14/95 1.00 1.00 1 ND ND -- ND -- Fresh Water Acute : 4.53 ug/L (BR-1), 8.12 ug/L (BR-2), 2.45 ug/L (BR-3), 5.66 ug/L (SW-1) ug/L 04/03/95 1.00 1.00 1 ND ND ND ND -- Fresh Water Chronic = 0.66 ug/L (BR-1), 1.09 ug/L (BR-2), 0.39 ug/L (BR-3), 0.79 ug/L (SW-1) ug/L 10/30/95 1.00 1.00 1 ND ND ND ND -- ug/L 04/08/96 1.00 1.00 1 -- -- -- ND -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- ug/L 10/29/97 -- -- 1 11 ND ND ND -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- ug/L O6/04/99 -- -- 1 ND -- ND ND -- ug/L 10/29/99 -- -- 1 ND -- ND ND -- ug/L 04/20/00 -- -- 1 1.5 -- 1.7 1.2 -- ug/L 11/07/00 -- -- 1 -- -- ND ND -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- ug/L 04/24/02 -- -- 1 1.5 -- 1.2 1.5 -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 1.00 1.00 1 ND ND ND ND -- ug/L 10/27/04 1.00 1.00 1 ND ND ND ND -- ug/L 05/25/05 1.00 1.00 1 ND ND ND ND -- ug/L 10/04/05 1.00 1.00 1 ND 111 ND ND -- ug/L 04/25/06 1.00 1.00 1 ND ND 1.15 1.03 -- ug/L 10/04/06 1.00 1.00 1 ND ND ND ND ND ug/L 03/21/07 1.00 1.00 1 1.42 J 2.71 J 1.36 J 0.51 J ND ug/L 10/02/07 1.00 1.00 1 ND ND 1.31 ND ND ug/L 04/03/08 1.00 1.00 1 ND ND 1.10 ND ND ug/L 10/29/08 1.00 1.00 1 ND -- 1.83 ND ND ug/L 03/24/09 0.09 1.00 1 ND ND 1.12 ND ND ug/L 09/22/09 0.36 1.00 1 ND ND 0.716 J ND ND ug/L 03/22/10 0.36 1.00 1 ND ND ND ND ND ug/L 09/23/10 0.36 1.00 1 ND ND 0.487 J ND ND ug/L 03/16/11 0.36 1.00 1 ND ND ND ND ND ug/L 09/21/11 0.36 1.00 1 ND ND ND ND ND ug/L 03/21/12 0.36 1.00 1 ND ND 0.468 J ND ND ug/L 09/20/12 0.36 1.00 1 ND ND 0.691 J ND ND ug/L 03/20/13 0.36 1.00 1 ND ND ND ND ND ug/L 09/18/13 0.36 1.00 1 ND ND ND ND ND ug/L 03/27/14 0.36 1.00 1 ND ND ND ND ND ug/L 09/18/14 0.36 1.00 1 ND ND ND ND ND ug/L 03/18/15 0.36 1.00 1 ND ND ND ND ND ug/L 09/23/15 0.36 1.00 1 ND ND ND ND ND ug/L 03/15/16 0.36 1.00 1 ND ND ND ND ND ug/L 09/20/16 0.36 1.00 1 ND ND ND ND ND ug/L 03/21/17 0.36 1.00 1 ND ND ND ND 0.591 J ug/L 09/20/17 0.36 1.00 1 -- ND ND ND ND (re -sample) ug/L 10/02/17 0.36 1.00 1 ND -- -- -- ND ug/L 03/21/18 0.36 1.00 1 ND ND ND ND ND ug/L 09/25/18 0.36 1.00 -- ND ND ND ND ND ug/L 43550.00 0.36 1.00 -- ND ND ND ND ND u /L 09/18/19 0.36 1.00 ND ND ND ND ND Chromium ug/L 12/05/94 10.0 10.0 10 ND ND ND ND -- SW Standard ug/L 02/14/95 10.0 10.0 10 ND ND -- ND -- Fresh Water Acute : 2.81 ug/L (BR-1), 5.05 ug/L (BR-2), 1.52 ug/L (BR-3), 3.52 ug/L (SW-1) ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- Fresh Water Chronic: 913.87 ug/L (BR-1), 1585.87 ug/L (BR-2), 513.13 ug/L (BR-3), 1127.07 ug/L (SW-1) ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- ug/L 10/24/96 10.0 10.0 10 ND ND ND ND -- ug/L 04/15/97 -- -- 10 ND ND ND ND -- ug/L 10/29/97 -- -- 10 10 1 ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L O6/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 10.0 10.0 10 ND ND ND ND -- J ug/L 10/04/05 10.0 10.0 10 ND ND ND ND -- J ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND ND ug/L 03/21/07 10.0 10.0 10 1.44 J 3.02 J 2.38 J 2.86 J ND ug/L 10/02/07 10.0 10.0 10 5.39 B 5.08 B 4.58 B 4.07 B 3.67 ug/L 04/03/08 10.0 10.0 10 5.05 B 4.06 B 4.06 B 3.31 B 2.94 ug/L 10/29/08 10.0 10.0 10 6.96 B -- 6.34 B 6.10 B ND ug/L 03/24/09 0.7 10.0 10 2.0 J 3.4 J 1.9 J 1.4 J ND ug/L 09/22/09 1.0 10.0 10 ND 1.83 J ND ND ND ug/L 03/22/10 1.0 10.0 10 ND ND ND ND ND ug/L 09/23/10 1.0 10.0 10 ND ND ND ND ND ug/L 03/16/11 1.0 10.0 10 2.21 J 3.97 J 2.42 J 1.64 J ND ug/L 09/21/11 1.0 10.0 10 1.29 J 3.44 J 1.78 J 1.06 J ND ug/L 03/21/12 1.0 10.0 10 1.39 J 2.21 J 2.19 J 1.10 J ND ug/L 09/20/12 1.0 10.0 10 ND 1.93 J 1.38 J ND ND ug/L 03/20/13 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/13 1.4 10.0 10 ND 1.92 J ND ND ND ug/L 03/27/14 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 10 ND 2.23 J ND ND ND ug/L 09/23/15 1.4 10.0 10 2.11 J ND ND ND ND ug/L 03/15/16 1.4 10.0 10 ND ND ND ND ND ug/L 09/20/16 1.4 10.0 10 ND ND ND ND ND ug/L 03/21/17 1.4 10.0 10 ND ND ND 2.62 J ND ug/L 09/20/17 1.4 10.0 10 -- 1.88 J ND ND ND (re -sample) ug/L 10/02/17 1.4 10.0 10 ND -- -- -- ND ug/L 03/21/18 1.4 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/26/19 1.4 10.0 -- ND ND ND ND ND u /L 09/18/19 1.4 10.0 ND ND ND ND ND GOLDER 3of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Cobalt ug/L 12/05/94 10.0 10.0 10 ND ND ND ND No SW Standard ug/L 02/14/95 10.0 10.0 10 11 ND -- ND -- ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- ug/L 04/15/97 -- -- 10 4 1 ND ND -- ug/L 10/29/97 -- -- 10 -- -- -- -- -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L O6/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- 10.7 ND -- ug/L 10/01/02 -- -- 10 ND -- 10.7 ND -- ug/L 04/09/03 10.0 10.0 10 ND -- ND ND -- ug/L 10/20/03 10.0 10.0 10 ND ND ND ND -- ug/L 03/24/04 10.0 10.0 10 ND ND ND ND -- ug/L 10/27/04 10.0 10.0 10 ND ND ND ND -- ug/L 05/25/05 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/05 10.0 10.0 10 ND ND ND ND -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND ND ug/L 03/21/07 10.0 10.0 10 2.52 J 3.56 J 4.76 J ND ND ug/L 10/02/07 10.0 10.0 10 ND ND ND ND ND ug/L 04/03/08 10.0 10.0 10 ND 5.32 J 3.66 J ND ND ug/L 10/29/08 10.0 10.0 10 7.54 J -- 7.90 J ND ND ug/L 03/24/09 0.6 10.0 10 3.9 J 4.8 J 4.8 J 1.0 J ND ug/L 09/22/09 1.1 10.0 10 1.21 J 5.16 J 1.90 J ND ND ug/L 03/22/10 1.1 10.0 10 3.17 J 6.20 J 1.39 J 2.71 J ND ug/L 09/23/10 1.1 10.0 10 2.38 J 5.61 J 3.38 J ND ND ug/L 03/16/11 1.1 10.0 10 1.94 J 5.87 J 1.82 J 1.85 J ND ug/L 09/21/11 1.1 10.0 10 3.22 J 9.89 J 3.13 J 2.29 J ND ug/L 03/21/12 1.1 10.0 10 2.44 J 8.93 J 2.84 J 1.71 J ND ug/L 09/20/12 1.1 10.0 10 2.52 J 8.43 J 3.31 J 1.12 J ND ug/L 03/20/13 1.1 10.0 10 1.77 J 3.49 J 2.03 J ND ND ug/L 09/18/13 1.1 10.0 10 3.01 J 3.55 J 1.19 J 1.19 J ND ug/L 03/27/14 1.1 10.0 10 3.47 J 4.19 J 2.75 J 2.45 J ND ug/L 09/18/14 1.1 10.0 10 ND 1.96 J 1.58 J ND ND ug/L 03/18/15 1.1 10.0 10 2.58 J 5.51 J 2.75 J 1.62 J ND ug/L 09/23/15 1.1 10.0 10 6.17 J ND ND ND ND ug/L 03/15/16 1.1 10.0 10 2.67 J 3.70 J 2.22 J 1.70 J ND ug/L 09/20/16 1.1 10.0 10 ND 1.29 J 1.84 J ND ND ug/L 03/21/17 1.1 10.0 10 ND 3.58 J 3.18 J ND ND ug/L 09/20/17 1.1 10.0 10 -- 8.77 J 1.50 J ND ND (re -sample) ug/L 10/02/17 1.1 10.0 10 ND -- -- -- ND ug/L 03/21/18 1.1 10.0 10 1.68 J 4.02 J 2.30 J ND ND ug/L 09/25/18 1.4 10.0 -- ND 2.52 J ND ND ND ug/L 03/26/19 1.4 10.0 -- 2.97 J 3.60 J ND 1.83 J ND u /L 09/18/19 1.4 10.0 ND 1.55 J 1.45 J ND ND Copper ug/L 12/05/94 200 200 10 ND ND ND ND -- SW Standards ug/L 02/14/95 200 200 10 ND ND -- ND -- Fresh Water Acute = 118.85 ug/L (BR-1), 206.29 ug/L (BR-2), 66.75 ug/L (BR-3), 146.61 ug/L (SW-1) ug/L 04/03/95 200 200 10 ND ND ND ND -- Fresh Water Chronic = 23.14 ug/L (BR-1), 43.63 ug/L (BR-2), 11.91 ug/L (BR-3), 29.46 ug/L (SW-1) ug/L 10/30/95 200 200 10 ND ND ND ND -- ug/L 04/08/96 200 200 10 -- -- -- ND -- ug/L 10/24/96 200 200 10 ND ND ND ND -- ug/L 04/15/97 200 200 10 ND ND ND ND -- ug/L 10/29/97 200 200 10 ND -- ND ND -- ug/L 05/14/98 200 200 10 ND ND ND ND -- ug/L 11/11/98 200 200 10 ND ND ND ND -- ug/L O6/04/99 -- - 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- J ug/L 10/27/04 -- -- 10 ND ND ND ND -- J ug/L 05/25/05 200 200 10 ND ND ND ND -- ug/L 10/04/05 200 200 10 ND ND ND ND -- ug/L 04/25/06 200 200 10 ND ND ND ND -- ug/L 10/04/06 200 200 10 ND ND ND ND ND ug/L 03/21/07 200 200 10 4.32 J 4.93 J 3.97 J 4.23 J ND ug/L 10/02/07 200 200 10 5.94 B 6.24 B 5.64 B 6.01 B 6.41 ug/L 04/03/08 200 200 10 4.96 B 4.27 B 4.53 B 5.38 B 4.46 ug/L 10/29/08 200 200 10 6.95 B -- 5.85 B 10.3 B ND ug/L 03/24/09 0.81 10.0 10 ND ND ND ND ND ug/L 09/22/09 1.6 10.0 10 ND ND ND ND ND ug/L 03/22/10 1.6 10.0 10 ND ND ND ND ND ug/L 09/23/10 1.6 10.0 10 ND ND 2.15 J ND ND ug/L 03/16/11 1.6 10.0 10 9.17 J ND 4.73 J 2.13 J ND ug/L 09/21/11 1.6 10.0 10 ND 3.90 J 2.35 J ND ND J ug/L 03/21/12 1.6 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.6 10.0 10 ND ND ND ND ND J ug/L 03/20/13 1.6 10.0 10 ND ND 1.60 J ND ND ug/L 09/18/13 1.6 10.0 10 5.72 J ND ND ND ND ug/L 03/27/14 1.6 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.6 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.6 10.0 10 ND ND ND ND 1.74 ug/L 09/23/15 1.6 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.6 10.0 10 ND ND ND ND 2.01 ug/L 09/20/16 1.6 10.0 10 1.61 B ND 2.27 B ND 3.37 J ug/L 03/21/17 1.6 10.0 10 ND ND ND ND 1.97 J ug/L 09/20/17 1.6 10.0 10 -- ND ND ND ND (re -sample) ug/L 10/02/17 1.6 10.0 10 2.89 B -- -- -- 2.75 J ug/L 03/21/18 1.6 10.0 10 ND ND ND ND 1.87 J ug/L 09/25/18 1.6 10.0 -- ND ND ND ND ND ug/L 03/26/19 1.6 10.0 -- ND ND ND ND ND u /L 09/18/19 1.6 10.0 ND ND 2.45 B 2.23 BI 5.73 J GOLDER 4of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Lead ug/L 12/05/94 10.0 10.0 10 ND 38 8 7 -- SW Standards* ug/L 02/14/95 10.0 10.0 10 ND 5 -- 7 -- Fresh Water Acute = 14.66 ug/L (BR-1), 26.06 ug/L (BR-2), 8.03 ug/L (BR-3), 18.25 ug/L (SW-1) ug/L 04/03/95 10.0 10.0 10 ND ND ND ND -- Fresh Water Chronic = 120.26 ug/L (BR-1), 244.05 ug/L (BR-2), 56.17 ug/L (BR-3), 157.85 ug/L (SW-1) ug/L 10/30/95 10.0 10.0 10 ND ND ND ND -- ug/L 04/08/96 10.0 10.0 10 -- -- -- ND -- ug/L 10/24/96 10.0 10.0 10 ND 110 ND ND -- ug/L 04/15/97 10.0 10.0 10 ND ND ND ND -- ug/L 10/29/97 -- -- 10 28 ND ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 18.5 -- ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- J ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND 11.6 ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/04/05 10.0 10.0 10 ND 242 ND ND -- ug/L 04/25/06 10.0 10.0 10 ND ND ND ND -- ug/L 10/04/06 10.0 10.0 10 ND ND ND ND ND ug/L 03/21/07 10.0 10.0 10 ND 1.56 J ND ND ND ug/L 10/02/07 10.0 10.0 10 0.49 B 0.65 B 0.46 B 0.49 B 0.49 ug/L 04/03/08 10.0 10.0 10 5.13 J 7.36 J ND ND ND ug/L 10/29/08 10.0 10.0 10 6.36 B -- 7.18 B 10.1 B ND J ug/L 03/24/09 1.6 10.0 10 2.8 J 3.9 J 3.8 J 2.1 J ND ug/L 09/22/09 1.9 10.0 10 ND 2.33 J ND ND ND ug/L 03/22/10 1.9 10.0 10 ND ND ND ND ND ug/L 09/23/10 1.9 10.0 10 ND ND ND ND ND ug/L 03/16/11 1.9 10.0 10 4.31 J 2.33 J 3.29 J ND ND ug/L 09/21/11 1.9 10.0 10 ND 8.03 J 2.33 J ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 3.64 B ND 2.28 B 3.19 B 2.70 ug/L 03/20/13 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/13 2.1 10.0 10 ND ND ND ND ND ug/L 03/27/14 2.1 10.0 10 ND ND ND ND ND ug/L 09/18/14 2.1 10.0 10 ND ND ND ND ND ug/L 03/18/15 2.1 10.0 10 ND ND ND ND ND ug/L 09/23/15 2.1 10.0 10 ND ND ND ND ND ug/L 03/15/16 2.1 10.0 10 ND ND ND ND ND ug/L 09/20/16 3.1 10.0 10 ND ND ND ND ND ug/L 03/21/17 3.1 10.0 10 ND ND ND ND ND ug/L 09/20/17 3.1 10.0 10 -- 5.42 J ND 3.29 J ND (re -sample) ug/L 10/02/17 3.1 10.0 10 ND -- -- -- ND ug/L 03/21/18 3.1 10.0 10 ND ND ND ND ND ug/L 09/25/18 3.1 10.0 -- ND ND ND ND 8.83 J ug/L 03/26/19 3.1 10.0 -- ND ND ND ND ND u /L 09/18/19 3.1 1 10.0 ND ND ND ND ND Nickel ug/L 12/05/94 50 50 50 ND ND ND ND -- SW Standards ug/L 02/14/95 50 50 50 ND ND -- ND -- Fresh Water Acute = 4.69 ug/L (BR-1), 9.51 ug/L (BR-2), 2.19 ug/L (BR-3), 6.15 ug/L (SW-1) ug/L 04/03/95 50 50 50 ND ND ND ND -- Fresh Water Chronic = 762.64 ug/L (BR-1), 1348.02 ug/L (BR-2), 420.24 ug/L (BR-3), 947.30 ug/L (SW-1) ug/L 10/30/95 50 50 50 ND ND ND ND -- ug/L 04/08/96 -- -- 50 -- -- -- ND -- ug/L 10/24/96 -- -- 50 ND ND ND ND -- ug/L 04/15/97 -- -- 50 ND ND ND ND -- ug/L 10/29/97 -- -- 50 ND -- ND ND -- ug/L 05/14/98 -- -- 50 ND ND ND ND -- ug/L 11/11/98 -- -- 50 ND ND ND ND -- ug/L O6/04/99 -- -- 50 ND -- ND ND -- ug/L 10/29/99 -- -- 50 ND -- ND ND -- ug/L 04/20/00 -- -- 50 ND -- ND ND -- ug/L 11/07/00 -- -- 50 -- -- ND ND -- ug/L 10/16/01 -- -- 50 ND -- ND ND -- ug/L 04/24/02 -- -- 50 ND -- ND ND -- ug/L 10/01/02 -- -- 50 ND -- ND ND -- J ug/L 04/09/03 -- -- 50 ND -- ND ND -- ug/L 10/20/03 50 50 50 ND ND ND ND -- ug/L 03/24/04 50 50 50 ND ND ND ND -- ug/L 10/27/04 50 50 50 ND ND ND ND -- ug/L 05/25/05 50 50 50 ND ND ND ND -- ug/L 10/04/05 50 50 50 ND ND ND ND -- ug/L 04/25/06 50 50 50 ND ND ND ND -- ug/L 10/04/06 50 50 50 ND ND ND ND ND ug/L 03/21/07 50 50 50 0.61 J ND 5.04 J ND ND ug/L 10/02/07 50 50 50 2.25 B 3.79 B 7.68 J 1.67 B 0.8 ug/L 04/03/08 50 50 50 ND ND ND ND ND ug/L 10/29/08 50 50 50 ND -- 8.09 J ND ND ug/L 03/24/09 0.6 10.0 50 2.0 J 2.5 J 4.2 J 1.0 J ND ug/L 09/22/09 1.8 10.0 50 2.17 J 3.90 J 2.65 J ND ND ug/L 03/22/10 1.8 10.0 50 ND 3.21 J ND ND ND ug/L 09/23/10 1.8 10.0 50 ND 2.24 J ND ND ND J ug/L 03/16/11 1.8 10.0 50 2.92 J ND 2.04 J ND ND ug/L 09/21/11 1.8 10.0 50 ND 2.97 J 2.71 J ND ND ug/L 03/21/12 1.8 10.0 50 ND 2.31 J 2.51 J ND ND ug/L 09/20/12 1.8 10.0 50 ND 1.82 J 2.80 J ND ND ug/L 03/20/13 1.8 10.0 50 ND ND 2.04 J ND ND ug/L 09/18/13 1.8 10.0 50 ND 2.51 J ND ND ND ug/L 03/27/14 1.8 10.0 50 ND 2.16 J 2.23 J ND ND ug/L 09/18/14 1.8 10.0 50 ND ND ND ND ND ug/L 03/18/15 1.8 10.0 50 ND 2.24 J 1.99 J ND ND ug/L 09/23/15 1.8 10.0 50 17.8 J ND ND ND 2.22 ug/L 03/15/16 1.8 10.0 50 ND ND ND ND ND ug/L 09/20/16 2.2 10.0 50 ND ND ND ND ND ug/L 03/21/17 2.2 10.0 50 ND 3.30 B ND 2.13 B 2.69 J ug/L 09/20/17 2.2 10.0 50 -- ND ND ND ND (re -sample) ug/L 10/02/17 2.2 10.0 50 2.32 B -- -- -- 2.66 J ug/L 03/21/18 2.2 10.0 50 ND ND ND ND ND ug/L 09/25/18 2.2 10.0 -- ND 2.95 B ND ND 10.1 ug/L 03/26/19 2.2 10.0 -- ND ND 2.21 J ND ND u /L 09/18/19 2.2 10.0 ND ND ND ND ND GOLDER 5 of 11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Selenium ug/L 12/05/94 20 20 10 ND ND ND ND -- SW Standards ug/L 02/14/95 20 20 10 ND ND -- ND -- Acute = 5 ug/L ug/L 04/03/95 20 20 10 ND ND ND ND -- Chronic = 5 ug/L ug/L 10/30/95 20 20 10 ND ND ND ND -- ug/L 04/08/96 -- -- 10 -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- ug/L 04/15/97 -- -- 10 18 ND ND 8 -- ug/L 10/29/97 -- -- 10 26 -- ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- 10 ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- J ug/L 10/27/04 20 20 10 ND ND ND ND -- ug/L 05/25/05 20 20 10 ND ND ND ND -- ug/L 10/04/05 20 20 10 ND ND ND ND -- J ug/L 04/25/06 20 20 10 ND ND ND ND -- ug/L 10/04/06 20 20 10 ND ND ND ND ND ug/L 03/21/07 20 20 10 ND ND ND ND ND ug/L 10/02/07 20 20 10 10.4 8.22 J ND 9.83 J ND ug/L 04/03/08 20 20 10 ND 7.73 J 7.75 J 8.67 J ND ug/L 10/29/08 20 20 10 ND -- ND ND ND ug/L 03/24/09 3.4 10.0 10 ND ND ND ND ND ug/L 09/22/09 2.7 10.0 10 3.17 B ND ND 6.01 B 6.41 ug/L 03/22/10 0.83 1.00 10 ND 2.75 J ND ND ND ug/L 09/23/10 5.2 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.7 10.0 10 ND ND ND 3.09 B 3.32 ug/L 09/21/11 2.7 10.0 10 ND ND ND ND ND ug/L 03/21/12 2.7 10.0 10 ND ND ND ND ND ug/L 09/20/12 2.7 10.0 10 ND ND ND ND ND ug/L 03/20/13 4.5 10.0 10 ND ND ND ND ND ug/L 09/18/13 5.0 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.0 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.0 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.0 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.0 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.0 10.0 10 ND ND ND ND ND ug/L 09/20/16 6.2 10.0 10 ND ND ND ND ND ug/L 03/21/17 6.2 10.0 10 ND ND ND ND 14.1 J ug/L 09/20/17 6.2 10.0 10 -- ND ND ND ND (re -sample) ug/L 10/02/17 6.2 10.0 10 ND -- -- -- ND ug/L 03/21/18 6.2 10.0 10 ND ND ND ND ND ug/L 09/25/18 6.2 10.0 -- ND ND ND ND ND ug/L 03/26/19 6.2 10.0 -- ND ND ND ND ND u /L 09/18/19 6.2 10.0 ND ND ND ND ND Silver ug/L 12/05/94 1.9 10.0 10 ND ND ND ND -- SW Standards ug/L 02/14/95 -- -- 10 ND ND -- ND -- Fresh Water Acute = 84.71 ug/L (BR-1), 149.72 ug/L (BR-2), 46.68 ug/L (BR-3), 105.22 ug/L (SW-1) ug/L 04/03/95 -- -- 10 ND ND ND ND -- Fresh Water Chronic = 8.67 ug/L (BR-1), 27.61 ug/L (BR-2), 2.58 ug/L (BR-3), 13.48 ug/L ( SW-1) ug/L 10/30/95 -- -- 10 ND ND ND ND -- ug/L 04/08/96 -- -- 10 -- -- -- ND -- ug/L 10/24/96 -- -- 10 ND ND ND ND -- ug/L 04/15/97 -- -- 10 ND 0.2 ND 0.3 -- ug/L 10/29/97 -- -- 10 2 -- ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND ND ND -- ug/L 06/04/99 -- -- 10 ND -- ND ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- ND ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- ND ND -- ug/L 04/24/02 -- -- 10 ND -- ND ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 ND -- ND ND -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/04/05 -- -- 10 ND ND ND ND -- ug/L 04/25/06 -- -- 10 ND ND ND ND -- ug/L 10/04/06 -- -- 10 ND ND ND ND ND ug/L 03/21/07 -- -- 10 1.32 J 1.01 J 0.97 J 0.99 J ND ug/L 10/02/07 -- -- 10 ND 1.55 J 1.25 J ND ND ug/L 04/03/08 -- -- 10 1.03 J 1.41 J 1.64 J 1.25 J ND ug/L 10/29/08 -- -- 10 6.03 B -- 5.77 B 5.32 B ND ug/L 03/24/09 1.0 10.0 10 1.3 J 2.5 J 2.4 J 1.3 J ND ug/L 09/22/09 1.9 10.0 10 ND 2.23 J ND ND ND ug/L 03/22/10 1.9 10.0 10 ND 2.89 J ND ND ND ug/L 09/23/10 1.9 10.0 10 ND ND ND ND ND ug/L 03/16/11 1.9 10.0 10 ND 2.81 J ND ND ND ug/L 09/21/11 1.9 10.0 10 ND ND ND ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND ND ug/L 03/20/13 1.9 10.0 10 1.94 B 2.72 B ND ND 2.11 J ug/L 09/18/13 1.9 10.0 10 ND ND ND ND ND ug/L 03/27/14 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.9 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.9 10.0 10 ND 2.16 J ND ND ND ug/L 09/23/15 1.9 10.0 10 2.18 B 1.93 B 2.33 B ND 4.69 ug/L 03/15/16 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/16 1.9 10.0 10 ND ND ND ND ND ug/L 03/21/17 1.9 10.0 10 ND ND ND ND 0.823 J ug/L 09/20/17 1.9 10.0 10 -- ND ND ND ND (re -sample) ug/L 10/02/17 1.9 10.0 10 ND -- -- -- ND ug/L 03/21/18 1.9 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.9 10.0 -- ND ND ND ND ND ug/L 03/26/19 1.9 10.0 -- ND ND ND ND ND u /L 09/18/19 1.9 10.0 ND ND ND ND ND GOLDER 6 of 11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Thallium ug/L 12/05/94 200 200 5.5 ND ND ND ND No SW Standard ug/L 02/14/95 200 200 5.5 ND ND -- ND -- ug/L 04/03/95 200 200 5.5 ND ND ND ND -- ug/L 10/30/95 200 200 5.5 ND ND ND ND -- ug/L 04/08/96 -- -- 5.5 -- -- -- ND -- ug/L 10/24/96 -- -- 5.5 ND ND ND ND -- ug/L 04/15/97 -- -- 5.5 ND ND ND ND -- ug/L 10/29/97 -- -- 5.5 206 1 2 1 -- ug/L 05/14/98 -- -- 5.5 ND ND ND ND -- ug/L 11/11/98 -- -- 5.5 ND ND ND ND -- ug/L O6/04/99 -- -- 5.5 ND -- ND ND -- ug/L 10/29/99 -- -- 5.5 ND -- ND ND -- ug/L 04/20/00 -- -- 5.5 ND -- ND ND -- ug/L 11/07/00 -- -- 5.5 -- -- ND ND -- ug/L 10/16/01 -- -- 5.5 ND -- ND ND -- ug/L 04/24/02 -- -- 5.5 ND -- ND ND -- ug/L 10/01/02 -- -- 5.5 ND -- ND ND -- J ug/L 04/09/03 -- -- 5.5 ND -- ND ND -- ug/L 10/20/03 -- -- 5.5 ND ND ND ND -- ug/L 03/24/04 -- -- 5.5 ND ND ND ND -- ug/L 10/27/04 200 200 5.5 ND ND ND ND -- ug/L 05/25/05 200 200 5.5 ND ND ND ND -- ug/L 10/04/05 200 200 5.5 ND ND ND ND -- ug/L 04/25/06 200 200 5.5 ND ND ND ND -- ug/L 10/04/06 200 200 5.5 ND ND ND ND ND ug/L 03/21/07 200 200 5.5 ND ND ND ND ND J ug/L 10/02/07 200 200 5.5 ND ND ND ND ND ug/L 04/03/08 200 200 5.5 ND ND ND ND ND ug/L 10/29/08 200 200 5.5 7.25 -- ND ND ND ug/L 03/24/09 0.036 1.00 5.5 ND ND ND ND 0.092 ug/L 09/22/09 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/22/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/23/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/16/11 0.11 1.00 5.5 0.465 J 0.415 J 0.192 J 0.675 J ND ug/L 09/21/11 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/21/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/20/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/20/13 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/13 0.11 1.00 5.5 ND ND ND ND 0.142 ug/L 03/27/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/18/15 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/23/15 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/15/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/20/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/21/17 0.11 1.00 5.5 0.183 J 0.185 J ND 0.321 J ND ug/L 09/20/17 0.11 1.00 5.5 -- 0.258 J 0.129 J 0.397 J ND (re -sample) ug/L 10/02/17 0.11 1.00 5.5 0.540 B -- -- -- 0.233 J ug/L 03/21/18 0.11 5.00 5.5 ND ND ND ND ND ug/L 09/25/18 0.55 5.00 -- ND ND ND ND ND ug/L 03/26/19 0.22 2.00 -- ND ND ND ND ND u /L 09/18/19 0.22 2.00 ND ND ND ND ND Vanadium ug/L 12/05/94 40 40 25 ND ND ND ND No SW Standard ug/L 02/14/95 40 40 25 ND ND -- ND -- ug/L 04/03/95 40 40 25 ND ND ND ND -- ug/L 10/30/95 40 40 25 ND ND ND ND -- ug/L 04/08/96 40 40 25 -- -- -- ND -- ug/L 10/24/96 -- -- 25 ND ND ND ND -- ug/L 04/15/97 -- -- 25 ND ND ND ND -- ug/L 10/29/97 -- -- 25 ND ND ND ND -- ug/L 05/14/98 -- -- 25 ND ND ND ND -- ug/L 11/11/98 -- -- 25 ND ND ND ND -- ug/L O6/04/99 -- -- 25 ND -- ND ND -- ug/L 10/29/99 -- -- 25 ND -- ND ND -- ug/L 04/20/00 -- -- 25 ND -- ND ND -- ug/L 11/07/00 -- -- 25 -- -- ND ND -- ug/L 10/16/01 -- -- 25 ND -- ND ND -- ug/L 04/24/02 -- -- 25 ND -- ND ND -- ug/L 10/01/02 -- -- 25 ND -- ND ND -- ug/L 04/09/03 -- -- 25 ND -- ND ND -- ug/L 10/20/03 -- -- 25 ND ND ND ND -- ug/L 03/24/04 40 40 25 ND ND ND ND -- ug/L 10/27/04 40 40 25 ND ND ND ND -- ug/L 05/25/05 40 40 25 ND ND ND ND -- ug/L 10/04/05 40 40 25 ND 60.5 ND ND -- ug/L 04/25/06 40 40 25 ND ND ND ND -- ug/L 10/04/06 40 40 25 ND ND ND ND ND J ug/L 03/21/07 40 40 25 ND ND ND ND ND ug/L 10/02/07 40 40 25 ND ND ND ND ND ug/L 04/03/08 40 40 25 ND 4.61 J ND ND ND ug/L 10/29/08 40 40 25 ND -- 2.04 J 2.59 J ND ug/L 03/24/09 0.7 10.0 25 ND ND ND ND ND ug/L 09/22/09 1.4 10.0 25 ND ND ND ND ND ug/L 03/22/10 1.4 10.0 25 ND ND ND ND ND ug/L 09/23/10 1.4 10.0 25 ND ND ND ND ND ug/L 03/16/11 1.4 10.0 25 4.70 J ND ND ND ND ug/L 09/21/11 1.4 10.0 25 ND 8.61 J ND ND ND ug/L 03/21/12 1.4 10.0 25 ND ND ND ND ND ug/L 09/20/12 1.4 10.0 25 ND ND ND ND ND ug/L 03/20/13 1.4 10.0 25 ND ND ND ND ND ug/L 09/18/13 1.4 10.0 25 ND ND ND ND 0.142 ug/L 03/27/14 1.4 10.0 25 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 25 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 25 ND ND ND ND ND ug/L 09/23/15 1.4 10.0 25 ND ND ND ND ND ug/L 03/15/16 1.4 10.0 25 ND ND ND ND ND ug/L 09/20/16 1.4 10.0 25 ND ND ND ND ND ug/L 03/21/17 1.4 10.0 25 ND 0.563 B ND 0.737 B 0.589 J ug/L 09/20/17 1.4 10.0 25 -- ND ND ND ND (re -sample) ug/L 10/02/17 1.4 10.0 25 ND -- -- -- ND ug/L 03/21/18 1.4 10.0 25 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/26/19 1.4 10.0 -- ND ND ND ND ND u /L 09/18/19 1.4 10.0 ND ND ND ND ND GOLDER 7of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Zinc ug/L 12/05/94 50 50 10 16 27 26 40 -- SW Standards ug/L 02/14/95 50 50 10 30 300 -- 71 -- Fresh Water Acute = 191.0 ug/L (BR-1), 337.90 ug/L (BR-2), 105.15 ug/L (BR-3), 237.33 ug/L (SW-1) ug/L 04/03/95 50 50 10 10 ND 21 51 -- Fresh Water Chronic = 192.56 ug/L (BR-1), 340.67 ug/L (BR-2), 106.01 ug/L (BR-3), 239.27 ug/L (SW-1) ug/L 10/30/95 50 50 10 ND 11 31 ND -- ug/L 04/08/96 50 50 10 -- -- -- 40 -- ug/L 10/24/96 -- -- 10 28 ND 16 13 -- ug/L 04/15/97 -- -- 10 20 20 40 30 -- ug/L 10/29/97 -- -- 10 20 ND ND ND -- ug/L 05/14/98 -- -- 10 ND ND ND ND -- ug/L 11/11/98 -- -- 10 ND ND 144 ND -- ug/L 06/04/99 -- -- 10 ND -- 118 ND -- ug/L 10/29/99 -- -- 10 ND -- ND ND -- ug/L 04/20/00 -- -- 10 ND -- 394 ND -- ug/L 11/07/00 -- -- 10 -- -- ND ND -- ug/L 10/16/01 -- -- 10 ND -- 26 ND -- J ug/L 04/24/02 -- -- 10 ND -- 132 ND -- ug/L 10/01/02 -- -- 10 ND -- ND ND -- ug/L 04/09/03 -- -- 10 82.7 -- ND 63 -- ug/L 10/20/03 -- -- 10 ND ND ND ND -- ug/L 03/24/04 -- -- 10 ND ND ND ND -- ug/L 10/27/04 -- -- 10 ND ND ND ND -- ug/L 05/25/05 -- -- 10 ND ND ND ND -- ug/L 10/04/05 50 50 10 ND 487 ND ND -- ug/L 04/25/06 50 50 10 ND ND 107 ND -- ug/L 10/04/06 50 50 10 ND ND ND ND ND ug/L 03/21/07 50 50 10 6.76 J 9.01 J 37 8.63 J ND ug/L 10/02/07 50 50 10 5.22 J 15.3 J 24.4 24 ND ug/L 04/03/08 50 50 10 6.29 J 5.45 J 52.5 10.6 ND ug/L 10/29/08 50 50 10 9.19 J -- 37.6 29.4 ND ug/L 03/24/09 3.4 10.0 10 5.5 B 5.6 B 35.6 3.6 B 3.4 ug/L 09/22/09 3.8 10.0 10 9.11 J 8.90 J 71.4 11.3 ND ug/L 03/22/10 3.8 10.0 10 11.4 6.16 J 24.9 9.02 J ND ug/L 09/23/10 3.8 10.0 10 ND 4.03 J 46.1 18.8 ND J ug/L 03/16/11 3.8 10.0 10 30.6 5.84 J 53.8 8.11 J ND ug/L 09/21/11 3.8 10.0 10 6.85 J 22.1 69.0 ND ND ug/L 03/21/12 3.8 10.0 10 ND ND 22.7 ND ND ug/L 09/20/12 3.8 10.0 10 ND 5.00 J 19.4 ND ND ug/L 03/20/13 3.8 10.0 10 ND 6.72 J 35.9 ND ND ug/L 09/18/13 3.8 10.0 10 9.22 J 4.03 J 12.5 ND ND ug/L 03/27/14 3.8 10.0 10 ND 4.30 J 25.9 ND ND ug/L 09/18/14 3.8 10.0 10 ND 5.11 J 9.98 J ND ND ug/L 03/18/15 3.8 10.0 10 ND 4.48 J 34.2 3.83 J ND ug/L 09/23/15 3.8 10.0 10 ND ND 7.06 J ND ND ug/L 03/15/16 3.8 10.0 10 ND ND 25.1 ND ND ug/L 09/20/16 4.4 10.0 10 ND ND 7.32 J ND ND ug/L 03/21/17 4.4 10.0 10 ND ND 33.2 ND ND ug/L 09/20/17 4.4 10.0 10 -- 30.3 15.4 ND ND (re -sample) ug/L 10/02/17 4.4 10.0 10 ND -- -- -- ND ug/L 03/21/18 4.4 10.0 10 ND 5.64 J 32.2 ND ND ug/L 09/25/18 4.4 10.0 -- ND 4.90 B 20.5 B ND 64.2 ug/L 03/26/19 4.4 10.0 -- 5.40 J 5.09 J 21.5 ND ND u /L 09/18/19 4.4 10.0 4.89 J 4.93 J 15.8 4.64 J ND Acetone ug/L 12/05/94 100 100 100 ND ND ND ND -- SW Standard =2.0 mg/L ug/L 02/14/95 100 100 100 ND ND ND ND -- Human Health =1100 mg/L ug/L 04/03/95 100 100 100 ND ND ND ND -- ug/L 10/30/95 100 100 100 ND ND ND ND -- ug/L 04/08/96 100 100 100 -- ND ND ND -- ug/L 05/29/96 100 100 100 -- ND ND ND -- ug/L O6/06196 100 100 100 -- ND ND ND -- ug/L 10/24/96 -- -- 100 ND ND ND ND -- ug/L 04/15/97 -- -- 100 ND ND ND ND -- ug/L 10/29/97 -- -- 100 ND ND ND ND -- ug/L 05/14/98 -- -- 100 ND ND ND ND -- J ug/L 11/11/98 -- -- 100 ND ND ND ND -- ug/L O6/04/99 -- -- 100 ND ND ND ND -- ug/L 10/29/99 -- -- 100 ND ND ND ND -- ug/L 04/20/00 -- -- 100 ND ND ND ND -- ug/L 11/07/00 -- -- 100 ND ND ND ND -- ug/L 10/16/01 -- -- 100 ND -- ND ND -- ug/L 04/24/02 -- -- 100 ND -- ND ND -- ug/L 10/01/02 -- -- 100 ND -- ND ND -- ug/L 04/09/03 100 100 100 ND -- ND ND -- ug/L 10/20/03 100 100 100 ND ND ND ND -- ug/L 03/24/04 100 100 100 ND ND ND ND -- J ug/L 10/27/04 100 100 100 ND ND ND ND -- ug/L 05/25/05 100 100 100 ND ND ND ND -- ug/L 10/04/05 100 100 100 ND ND ND ND -- J ug/L 04/25/06 100 100 100 ND ND ND ND -- ug/L 10/04/06 100 100 100 ND ND ND ND ND ug/L 03/21/07 100 100 100 ND ND ND ND ND ug/L 10/02/07 100 100 100 3.51 B 1.73 B ND ND 5.5 ug/L 04/03/08 100 100 100 ND ND ND ND ND ug/L 10/29/08 100 100 100 ND -- ND ND ND ug/L 03/24/09 1.5 5.0 100 ND ND ND ND ND ug/L 09/22/09 1.5 5.0 100 ND ND ND ND ND ug/L 03/22/10 1.5 5.0 100 2.3 J ND ND 2.5 J ND ug/L O6/03/10 1.5 5.0 100 -- -- -- -- ND ug/L 09/23/10 1.5 5.0 100 ND ND ND ND ND ug/L 03/16/11 1.2 5.0 100 ND 4.2 J 3.0 J ND ND ug/L 09/21/11 1.2 5.0 100 ND 7.0 J ND ND ND ug/L 03/21/12 1.2 5.0 100 ND ND ND ND ND ug/L 09/20/12 1.2 5.0 100 ND 7.4 B ND ND 7.0 ug/L 03/20/13 1.2 5.0 100 ND ND ND ND ND ug/L 09/18/13 1.2 5.0 100 ND ND ND ND ND ug/L 03/27/14 1.2 5.0 100 ND ND 5.5 B 4.7 B 19 ug/L 09/18/14 1.2 5.0 100 ND ND ND ND ND ug/L 03/18/15 1.2 5.0 100 ND ND ND ND ND ug/L 09/23/15 1.2 5.0 100 ND ND ND ND ND ug/L 03/15/16 1.2 5.0 100 ND ND ND ND ND ug/L 09/20/16 10 20 100 ND ND ND ND ND ug/L 03/21/17 10 20 100 ND ND ND ND ND ug/L 09/20/17 10 20 100 ND 13 J ND ND ND ug/L 03/21/18 10 20 100 ND ND ND ND ND ug/L 09/25/18 10 20 -- ND ND ND ND ND ug/L 03/26/19 10 20 -- ND ND ND ND 12 J u /L 09/18/19 10 20 ND ND ND ND ND GOLDER 8of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Benzene ug/L 12/05/94 0.2 1 1 ND ND ND ND -- SW Standard ug/L 02/14/95 -- -- 1 ND ND ND ND -- Human Health = 51 ug/L ug/L 04/03/95 -- -- 1 ND ND ND ND -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- ug/L 04/08/96 -- -- 1 -- ND ND ND -- ug/L 05/29/96 -- -- 1 -- ND ND ND -- ug/L O6/06/96 -- -- 1 -- ND ND ND -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- ug/L 10/29/97 -- -- 1 ND ND ND ND -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- ug/L O6/04/99 -- -- 1 ND ND ND ND -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- ug/L 04/20/00 -- -- 1 ND ND ND ND -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- J ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/04/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/04/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 ND 0.86 J ND ND ND ug/L 10/02/07 -- -- 1 0.16 J 0.76 J ND ND ND ug/L 04/03/08 -- -- 1 ND 0.39 J ND ND ND ug/L 10/29/08 -- -- 1 0.12 J -- ND ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND ND ND ND ND ug/L 03/22/10 0.050 1.0 1 ND ND ND ND ND ug/L 06/03/10 0.050 1.0 1 -- -- -- -- ND ug/L 09/23/10 0.20 1.0 1 ND ND ND ND ND ug/L 03/16/11 0.68 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.68 1.0 1 ND ND ND ND ND ug/L 03/21/12 0.15 1.0 1 ND 0.46 J ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND ND 1.75 ug/L 03/27/14 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.15 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.15 1.0 1 ND ND ND ND ND ug/L 09/20/16 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.15 1.0 1 ND ND ND ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.15 1.0 -- ND ND ND ND ND ug/L 03/26/19 0.15 1.0 -- ND ND ND ND ND u /L 09/18/19 0.15 1.0 ND ND ND ND ND Chlorobenzene ug/L 12/05/94 0.27 1 3 ND ND ND ND -- SW Standard = 140 ug/L ug/L 02/14/95 -- -- 3 ND ND ND ND -- Human Health = 1.6 mg/L ug/L 04/03/95 -- -- 3 ND ND ND ND -- ug/L 10/30/95 -- -- 3 ND ND ND ND -- ug/L 04/08/96 -- -- 3 -- ND ND ND -- ug/L 05/29/96 -- -- 3 -- ND ND ND -- ug/L O6/06/96 -- -- 3 -- ND ND ND -- ug/L 10/24/96 -- -- 3 ND ND ND ND -- ug/L 04/15/97 -- -- 3 ND ND ND ND -- ug/L 10/29/97 -- -- 3 ND ND ND ND -- ug/L 05/14/98 -- -- 3 ND ND ND ND -- ug/L 11/11/98 -- -- 3 ND ND ND ND -- ug/L O6/04/99 -- -- 3 ND ND ND ND -- ug/L 10/29/99 -- -- 3 ND ND ND ND -- ug/L 04/20/00 -- -- 3 ND ND ND ND -- ug/L 11/07/00 -- -- 3 ND ND ND ND -- ug/L 10/16/01 -- -- 3 ND -- ND ND -- ug/L 04/24/02 -- -- 3 ND -- ND ND -- ug/L 10/01/02 -- -- 3 ND -- ND ND -- ug/L 04/09/03 -- -- 3 ND -- ND ND -- ug/L 10/20/03 -- -- 3 ND ND ND ND -- ug/L 03/24/04 -- -- 3 ND ND ND ND -- ug/L 10/27/04 -- -- 3 ND ND ND ND -- ug/L 05/25/05 -- -- 3 ND ND ND ND -- ug/L 10/04/05 -- -- 3 ND ND ND ND -- ug/L 04/25/06 -- -- 3 ND ND ND ND -- ug/L 10/04/06 -- -- 3 ND ND ND ND ND ug/L 03/21/07 -- -- 3 ND 1.69 ND ND ND ug/L 10/02/07 -- -- 3 0.86 J 2.2 J ND ND ND ug/L 04/03/08 -- -- 3 0.43 J 1.22 J ND ND ND ug/L 10/29/08 -- -- 3 0.86 J -- ND ND ND ug/L 03/24/09 0.27 1.0 3 0.53 J 0.72 J ND ND ND ug/L 09/22/09 0.27 1.0 3 ND 1.0 J ND ND ND ug/L 03/22/10 0.069 1.0 3 ND 0.77 J ND ND ND ug/L O6/03/10 0.069 1.0 3 -- -- -- -- ND ug/L 09/23/10 0.27 1.0 3 0.42 J 0.79 J ND ND ND ug/L 03/16/11 0.74 1.0 3 ND 1.1 J ND ND ND ug/L 09/21/11 0.74 1.0 3 ND ND ND ND ND ug/L 03/21/12 0.17 1.0 3 ND 2.2 J ND ND ND ug/L 09/20/12 0.17 1.0 3 ND ND ND ND ND ug/L 03/20/13 0.17 1.0 3 ND 0.46 J ND ND ND ug/L 09/18/13 0.17 1.0 3 ND 0.55 J ND ND ND ug/L 03/27/14 0.17 1.0 3 ND ND ND ND ND ug/L 09/18/14 0.17 1.0 3 ND ND ND ND ND ug/L 03/18/15 0.17 1.0 3 ND 0.70 J ND ND ND ug/L 09/23/15 0.17 1.0 3 1.3 J ND ND ND ND ug/L 03/15/16 0.17 1.0 3 ND ND ND ND ND ug/L 09/20/16 0.17 1.0 3 ND ND ND ND ND ug/L 03/21/17 0.17 1.0 3 ND ND ND ND ND ug/L 09/20/17 0.17 1.0 3 ND ND ND ND ND ug/L 03/21/18 0.17 1.0 3 ND ND ND ND ND ug/L 09/25/18 0.17 1.0 -- ND 0.44 J ND ND ND ug/L 03/26/19 0.17 1.0 -- ND 0.69 J ND ND ND u /L 09/18/19 0.17 1.0 ND ND ND ND ND GOLDER 9of11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks 1,2-Dichlorobenzene ug/L 12/05/94 0.27 1 5 ND ND ND ND No SW Standard ug/L 02/14/95 -- -- 5 ND ND ND ND -- ug/L 04/03/95 -- -- 5 ND ND ND ND -- ug/L 10/30/95 -- -- 5 ND ND ND ND -- ug/L 04/08/96 -- -- 5 -- ND ND ND -- ug/L 05/29/96 -- -- 5 -- ND ND ND -- ug/L O6/06/96 -- -- 5 -- ND ND ND -- ug/L 10/24/96 -- -- 5 ND ND ND ND -- ug/L 04/15/97 -- -- 5 ND ND ND ND -- ug/L 10/29/97 -- -- 5 ND ND ND ND -- ug/L 05/14/98 -- -- 5 ND ND ND ND -- ug/L 11/11/98 -- -- 5 ND ND ND ND -- ug/L 06/04/99 -- -- 5 ND ND ND ND -- ug/L 10/29/99 -- -- 5 ND ND ND ND -- ug/L 04/20/00 -- -- 5 ND ND ND ND -- ug/L 11/07/00 -- -- 5 ND ND ND ND -- ug/L 10/16/01 -- -- 5 ND -- ND ND -- ug/L 04/24/02 -- -- 5 ND -- ND ND -- ug/L 10/01/02 -- -- 5 ND -- ND ND -- ug/L 04/09/03 -- -- 5 ND -- ND ND -- ug/L 10/20/03 -- -- 5 ND ND ND ND -- ug/L 03/24/04 -- -- 5 ND ND ND ND -- ug/L 10/27/04 -- -- 5 ND ND ND ND -- ug/L 05/25/05 -- -- 5 ND ND ND ND -- ug/L 10/04/05 -- -- 5 ND ND ND ND -- ug/L 04/25/06 -- -- 5 ND ND ND ND -- ug/L 10/04/06 -- -- 5 ND ND ND ND ND ug/L 03/21/07 -- -- 5 ND ND ND ND ND ug/L 10/02/07 -- -- 5 0.27 J 0.23 J ND ND ND ug/L 04/03/08 -- -- 5 0.12 J ND ND ND ND ug/L 10/29/08 -- -- 5 0.28 J -- ND ND ND ug/L 03/24/09 0.27 1.0 5 ND 0.49 J ND ND ND ug/L 09/22/09 0.27 1.0 5 ND ND ND ND ND ug/L 03/22/10 0.052 1.0 5 ND ND ND ND ND ug/L 06/03/10 0.052 1.0 5 -- -- -- -- ND ug/L 09/23/10 0.27 1.0 5 ND ND ND ND ND ug/L 03/16/11 0.11 1.0 5 ND 0.79 J ND ND ND ug/L 09/21/11 0.11 1.0 5 ND ND ND ND ND ug/L 03/21/12 0.19 1.0 5 ND 0.51 J ND ND ND ug/L 09/20/12 0.19 1.0 5 ND 0.59 J ND ND ND ug/L 03/20/13 0.19 1.0 5 ND ND ND ND ND ug/L 09/18/13 0.19 1.0 5 ND 0.48 J ND ND ND ug/L 03/27/14 0.19 1.0 5 ND ND ND ND ND ug/L 09/18/14 0.19 1.0 5 ND ND ND ND ND ug/L 03/18/15 0.19 1.0 5 ND 0.60 J ND ND ND ug/L 09/23/15 0.19 1.0 5 ND ND ND ND ND ug/L 03/15/16 0.19 1.0 5 ND ND ND ND ND ug/L 09/20/16 0.19 1.0 5 ND ND ND ND ND ug/L 03/21/17 0.19 1.0 5 ND ND ND ND ND ug/L 09/20/17 0.19 1.0 5 ND 0.50 J ND ND ND ug/L 03/21/18 0.19 1.0 5 ND ND ND ND ND ug/L 09/25/18 0.19 1.0 -- ND ND ND ND ND ug/L 03/26/19 0.19 1.0 -- ND ND ND ND ND u /L 09/18/19 0.19 1.0 ND 0.29 J ND ND ND 1,4-Dichlorobenzene ug/L 12/05/94 0.2 1 1 ND ND ND -- No SW Standard ug/L 02/14/95 -- -- 1 ND ND ND -- -- ug/L 04/03/95 -- -- 1 ND ND ND -- -- ug/L 10/30/95 -- -- 1 ND ND ND ND -- ug/L 04/08/96 -- -- 1 -- ND ND -- -- ug/L 05/29/96 -- -- 1 -- ND ND -- -- ug/L O6/06/96 -- -- 1 -- ND ND -- -- ug/L 10/24/96 -- -- 1 ND ND ND ND -- ug/L 04/15/97 -- -- 1 ND ND ND ND -- ug/L 10/29/97 -- -- 1 ND ND ND ND -- ug/L 05/14/98 -- -- 1 ND ND ND ND -- ug/L 11/11/98 -- -- 1 ND ND ND ND -- ug/L 06/04/99 -- -- 1 ND ND ND ND -- ug/L 10/29/99 -- -- 1 ND ND ND ND -- ug/L 04/20/00 -- -- 1 ND ND ND ND -- ug/L 11/07/00 -- -- 1 ND ND ND ND -- ug/L 10/16/01 -- -- 1 ND -- ND ND -- ug/L 04/24/02 -- -- 1 ND -- ND ND -- ug/L 10/01/02 -- -- 1 ND -- ND ND -- ug/L 04/09/03 -- -- 1 ND -- ND ND -- ug/L 10/20/03 -- -- 1 ND ND ND ND -- ug/L 03/24/04 -- -- 1 ND ND ND ND -- ug/L 10/27/04 -- -- 1 ND ND ND ND -- ug/L 05/25/05 -- -- 1 ND ND ND ND -- ug/L 10/04/05 -- -- 1 ND ND ND ND -- ug/L 04/25/06 -- -- 1 ND ND ND ND -- ug/L 10/04/06 -- -- 1 ND ND ND ND ND ug/L 03/21/07 -- -- 1 0.19 J 2.26 0.37 J ND ND ug/L 10/02/07 -- -- 1 0.87 J 3.57 ND ND ND ug/L 04/03/08 -- -- 1 0.39 J 1.55 J ND ND ND ug/L 10/29/08 -- -- 1 1.01 J -- ND ND ND ug/L 03/24/09 0.38 1.0 1 0.59 J 2.4 ND ND ND ug/L 09/22/09 0.38 1.0 1 ND 1.6 ND ND ND ug/L 03/22/10 0.10 1.0 1 ND 1.4 ND ND ND ug/L O6/03/10 0.10 1.0 1 -- -- -- -- ND ug/L 09/23/10 0.38 1.0 1 ND 3.0 ND ND ND ug/L 03/16/11 0.79 1.0 1 ND 2.8 ND ND ND ug/L 09/21/11 0.79 1.0 1 ND ND ND ND ND ug/L 03/21/12 0.19 1.0 1 ND 4.5 ND ND ND ug/L 09/20/12 0.19 1.0 1 0.40 J 5.9 ND ND ND ug/L 03/20/13 0.19 1.0 1 ND 1.4 ND ND ND ug/L 09/18/13 0.19 1.0 1 ND 1.7 ND ND ND ug/L 03/27/14 0.19 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.19 1.0 1 ND 0.55 J ND ND ND ug/L 03/18/15 0.19 1.0 1 ND 2.2 ND ND ND ug/L 09/23/15 0.19 1.0 1 0.87 J ND ND ND ND ug/L 03/15/16 0.19 1.0 1 ND 0.93 J ND ND ND ug/L 09/20/16 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.19 1.0 1 ND ND ND ND ND ug/L 09/20/17 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.19 1.0 1 ND 1.3 ND ND ND ug/L 09/25/18 0.19 1.0 -- ND ND ND ND ND ug/L 03/26/19 0.19 1.0 -- ND 1.4 ND ND ND u /L 09/18/19 0.19 1.0 ND ND ND ND ND GOLDER 10 of 11 January2020 TABLE 6 19128179 Summary of Detected Constituents in Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit BR-1 BR-2 BR-3 SW-1 Blanks Methylene chloride ug/L 12/05/94 0.24 2 1 NO ND ND NO -- SW Standard ug/L 02/14/95 -- -- 1 NO ND ND NO -- Human Health = 590 ug/L ug/L 04/03/95 -- -- 1 NO ND ND NO -- ug/L 10/30/95 -- -- 1 NO ND ND NO -- ug/L 04/08/96 -- -- 1 -- ND ND NO -- ug/L 05/29/96 -- -- 1 -- ND ND NO -- ug/L 06/06/96 -- -- 1 -- ND ND NO -- ug/L 10/24/96 -- -- 1 ND ND ND NO -- ug/L 04/15/97 -- -- 1 ND ND ND NO -- ug/L 10/29/97 -- -- 1 NO ND ND NO -- ug/L 05/14/98 -- -- 1 NO ND NO NO -- ug/L 11/11/98 -- -- 1 NO NO NO NO -- ug/L 06/04/99 -- -- 1 NO NO NO NO -- ug/L 10/29/99 -- -- 1 NO NO ND NO -- ug/L 04/20/00 -- -- 1 NO ND ND NO -- ug/L 11/07/00 -- -- 1 NO ND ND NO -- ug/L 10/16/01 -- -- 1 NO -- ND NO -- ug/L 04/24/02 -- -- 1 NO -- ND NO -- ug/L 10/01/02 -- -- 1 NO -- ND NO -- ug/L 04/09/03 -- -- 1 NO -- ND NO -- ug/L 10/20/03 -- -- 1 NO ND ND NO -- ug/L 03/24/04 -- -- 1 NO NO ND NO -- ug/L 10/27/04 -- -- 1 NO NO ND NO -- ug/L 05/25/05 -- -- 1 NO NO ND NO -- ug/L 10/04/05 -- -- 1 NO NO NO NO -- ug/L 04/25/06 -- -- 1 NO NO NO NO -- ug/L 10/04/06 -- -- 1 NO NO NO NO NO ug/L 03/21/07 -- -- 1 NO ND ND NO NO ug/L 10/02/07 -- -- 1 NO ND ND NO 0.41 ug/L 04/03/08 -- -- 1 NO ND ND NO 0.42 ug/L 10/29/08 0.44 5 1 NO -- ND 0.19 J NO ug/L 03/24/09 0.53 2.0 1 ND NO ND NO NO ug/L 09/22/09 0.53 1.0 1 NO ND ND NO NO ug/L 03/22/10 0.070 1.0 1 NO NO NO NO NO ug/L 06/03/10 0.070 1.0 1 -- -- -- -- NO ug/L 09/23/10 0.53 1.0 1 NO ND NO NO NO ug/L 03/16/11 0.14 1.0 1 NO ND NO NO NO ug/L 09/21/11 0.14 1.0 1 NO ND NO NO NO ug/L 03/21/12 0.23 1.0 1 NO ND NO NO NO ug/L 09/20/12 0.23 -- 1 NO ND NO NO NO ug/L 03/20/13 0.23 1.0 1 NO ND NO NO NO ug/L 09/18/13 0.23 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.23 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.23 1.0 1 ND ND NO ND ND ug/L 03/18/15 0.23 -- 1 ND ND ND ND ND ug/L 09/23/15 0.23 -- 1 ND ND ND ND ND ug/L 03/15/16 0.23 -- 1 ND ND ND ND ND ug/L 09/20/16 0.23 1.0 1 NO ND ND NO NO ug/L 03/21/17 0.23 -- 1 NO ND ND NO NO ug/L 09/20/17 0.23 1.0 1 NO NO NO NO NO ug/L 03/21/18 0.23 1.0 1 NO ND ND NO NO ug/L 09/25/18 0.23 -- -- NO ND ND NO 0.43 J ug/L 03/26/19 0.23 1.0 -- NO ND ND ND NO u /L 09/18/19 0.23 1.0 NO ND ND ND NO 1,4-Dioxane ug/L 09/25/18 1.2 2.0 -- 1.4 J 7.2 1.3 J 1.7 J NO SW Standard = 0.35 ug/L ug/L 03/26/19 1.2 2.0 -- ND 7.7 1.2 J 1.2 J NO u /L 09/18/19 1.2 2.0 2.1 8.0 1.8 J 2.8 NO Notes: mg/L = milligrams per liter ug/L = micrograms per liter ND = Not detected at the stated reporting limit uS/cm = microsiemens per centimeter J = Estimated concentration B = Blank -qualified result -- = no data available dry = there was no discernible flow and a sample was not collected. SW Standard = Surface Water Standard based on Freshwater Aquatic Life Classification unless otherwise noted 1) Surface Water Standards based on Fresh Water Aquatic Life Classification Blanks = field, trip and method blanks Bold = concentrations above the chronic SW Standards or Human Health Standards have been bolded Highlighted= concentrations above the acute SW Standards have been highlighted SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 (N) = Narrative Standard (AL) = Action Level Standard 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2019 event: antimony and thallium in BRA, BR-2, BR-3, and SW-1 (2x). = Acute and Chronic surface water standards for Cadmium, Chromium, Copper, Lead, Nickel, Silver, and Zinc are based on hardness concentrations at each monitoring location. Hardness was 178 mg/L at BR-1, 349 mg/L at BR-2, 230 mg/L at SW-1 during the March 2018 event and at the June 2018 event BR-3 had a hardness of 88 mg/L. GOLDER 11of11 January 2020 TABLE 7 Summary of Field Parameters for Surface Water Monitoring Points Henderson County Closed Landfill, Permit No. 45-01 Detected Monitoring Constituent/Parameter Units Date BRA BR-2 BR-3 SW-1 pH (field) S.U. 10/05/06 5.90 6.62 6.74 6.80 S.U. 10/02/07 6.35 6.37 6.25 7.20 S.U. 04/01/08 6.61 6.41 6.35 7.32 S.U. 03/24/09 7.48 7.83 7.50 7.84 S.U. 09/22/09 6.94 6.81 7.06 7.01 S.U. 03/22/10 6.29 6.32 6.34 6.75 S.U. 09/23/10 7.27 7.17 6.55 7.44 S.U. 03/16/11 7.16 6.42 6.48 6.65 S.U. 09/21/11 6.95 7.51 6.65 7.41 S.U. 03/21/12 6.62 6.67 6.32 6.93 S.U. 09/20/12 7.18 5.24 7.69 7.75 S.U. 03/20/13 6.61 7.06 6.45 6.89 S.U. 09/18/13 7.23 7.17 6.83 7.18 S.U. 03/26/14 6.84 7.17 6.58 7.32 S.U. 09/18/14 7.57 6.54 6.85 6.31 S.U. 03/18/15 6.86 7.16 6.88 7.52 S.U. 09/23/15 6.71 7.06 7.13 6.49 S.U. 03/15/16 6.61 6.65 6.54 6.73 S.U. 09/20/16 6.76 6.02 6.64 5.41 S.U. 03/21/17 7.40 6.60 6.86 6.17 S.U. 09/20/17 6.55 7.15 6.89 7.55 (re -sample) S.U. 10/02/17 7.55 -- -- -- S.U. 03/21/18 8.13 8.01 7.37 7.90 S.U. 09/25/18 7.26 7.09 6.62 7.05 S.U. 03/25/19 7.21 7.20 6.93 7.26 S.U. 09/18/19 7.06 7.21 7.06 7.37 Specific Conductivity (field) US/cm 10/05/06 530 765 1512 184 US/cm 10/02/07 498 1029 3037 321 US/cm 04/01/08 400 932 2355 400 US/cm 03/24/09 620 810 3230 360 US/cm 09/22/09 388 845 1328 338 US/cm 03/22/10 343 783 403 317 US/cm 09/23/10 506 1217 2605 343 US/cm 03/16/11 357 715 2341 354 US/cm 09/21/11 484 863 2149 326 US/cm 03/21/12 347 1025 2466 250 US/cm 09/20/12 418 1017 3162 269 US/cm 03/20/13 171 456 1567 177 US/cm 09/18/13 356 738 1782 307 US/cm 03/26/14 339 685 2688 342 US/cm 09/18/14 401 691 2212 345 US/cm 03/18/15 323 366 2766 297 US/cm 09/23/15 505 561 2455 278 US/cm 03/15/16 316 666 1587 326 US/cm 09/20/16 264 542 1990 265 US/cm 03/21/17 423 700 6161 308 US/cm 09/20/17 386 785 1966 349 (re -sample) uS/cm 10/02/17 365 -- -- -- US/cm 03/21/18 284 669 1869 292 US/cm 09/25/18 351 697 3302 311 US/cm 03/25/19 282 619 1346 334 US/cm 09/18/19 397 708 1863 376 Temperature (field) Celsius 10/05/06 15.7 16.0 15.9 17.0 Celsius 10/02/07 13.6 14.9 15.30 14.9 Celsius 04/01/08 15.9 10.7 10.7 15.9 Celsius 03/24/09 13.4 14.8 8.2 14.4 Celsius 09/22/09 20.5 18.6 19.5 19.2 Celsius 03/22/10 6.8 8.1 7.7 7.8 Celsius 09/23/10 20.1 18.1 19.6 19.4 Celsius 03/16/11 8.1 11.2 11.3 7.1 Celsius 09/21/11 16.7 20.1 18.1 16.6 Celsius 03/21/12 13.4 17.0 17.7 14.4 Celsius 09/20/12 15.7 17.8 16.1 16.3 Celsius 03/20/13 2.4 10.3 7.8 7.7 Celsius 09/18/13 16.0 17.7 17.3 16.9 Celsius 03/26/14 10.6 6.9 10.7 3.9 Celsius 09/18/14 17.8 17.3 17.9 16.6 Celsius 03/18/15 12.7 13.0 14.0 9.0 Celsius 09/23/15 18.3 19.1 19.1 18.1 Celsius 03/15/16 8.5 10.0 16.3 8.9 Celsius 09/20/16 22.4 20.7 20.3 20.5 Celsius 03/21/17 15.0 17.0 15.5 16.5 Celsius 09/20/17 18.31 20.42 18.08 19.28 (re -sample) Celsius 10/02/17 14.5 -- -- -- Celsius 03/21/18 9.00 10.47 9.35 9.03 Celsius 09/25/18 19.42 19.62 18.83 18.62 Celsius 03/25/19 8.3 11.7 8.0 8.3 Celsius 09/18/19 18.7 19.0 18.4 18.2 19128179 G GOLDER 1of2 January 2020 Detected Monitoring Co nstitue nt/Parameter Units Date BRA BR-2 BR-3 SW-t Turbidity (field) NTU 03/24/09 34.2 12.7 3.02 6.58 NTU 09/22/09 69.3 29.7 24.9 9.06 NTU 03/22/10 29.6 12.6 10 23 NTU 09/23/10 54.2 6.72 11.3 3.51 NTU 03/16/11 74.6 8.59 23.6 20.7 NTU 09/21/11 66.4 215 42.8 35.9 NTU 03/21/12 27.7 97.4 17.0 11.4 NTU 09/20/12 67.0 30.2 12.5 67.0 NTU 03/20/13 40.7 19.1 10.1 9.60 NTU 09/18/13 23.4 24.9 14.3 16.9 NTU 03/26/14 24.9 6.90 14.7 9.87 NTU 09/18/14 2.32 4.95 1.46 2.84 NTU 03/18/15 10.40 6.35 3.19 11.10 NTU 09/23/15 20.2 1.05 0.90 1.01 NTU 03/15/16 17.9 10.5 5.01 4.75 NTU 09/20/16 5.73 2.78 2.03 3.71 NTU 03/21/17 3.93 6.39 3.85 3.27 NTU 09/20/17 4.16 22.7 1.20 2.05 (re -sample) NTU 10/02/17 -- -- -- -- NTU 03/21/18 10.5 5.54 2.80 8.76 NTU 09/25/18 9.67 4.23 7.48 2.66 NTU 03/25/19 26.2 17.2 14.1 13.7 NTU 09/18/19 19.3 4.84 2.44 3.77 Oxidation Reduction Potential (field) my 09/22/09 -27.9 -51.1 -35.1 26.6 my 03/22/10 -9.7 -45.7 47.1 -29.0 my 09/23/10 -27.2 -134.9 -2.0 30.2 my 03/16/11 15.1 31.4 1.3 -1.6 my 09/21/11 -34.1 -25.4 -18.9 -41.0 my 03/21/12 15.4 -51.4 11.0 7.71 my 09/20/12 -180.3 1.0 -136.6 -129.5 my 03/20/13 1.5 -42.3 9.7 -1.7 my 09/18/13 14.2 -31.0 60.7 90.6 my 03/26/14 -105.6 -120.6 -80.5 -75.0 my 09/18/14 86.8 66.5 45.0 179.9 my 03/18/15 26.8 -40.9 7.0 76.0 my 09/23/15 -13.3 118.2 74.5 155.9 my 03/15/16 7.3 -0.5 -2.3 37.3 my 09/20/16 170.1 190.8 171.0 213.8 my 03/21/17 -- -- -1.5 200.6 my 09/20/17 3.00 -8.1 28.1 (re -sample) my 10/02/17 -- -- -- -- mv 03/21/18 -29.4 -51.4 -4.4 -6.8 my 09/25/18 -52.5 -89.4 4.6 42.9 my 03/25/19 -45.2 -13.2 3.2 -14.8 my 09/18/19 -21.1 2.4 -5.4 51.1 Dissolved Oxygen (field) mg/L 09/22/09 4.00 4.20 4.33 5.02 mg/L 03/22/10 10.99 9.49 9.03 10.47 mg/L 09/23/10 6.87 24.0 6.36 6.28 mg/L 03/16/11 14.68 13.44 8.76 10.47 mg/L 09/21/11 7.42 6.32 6.90 8.74 mg/L 03/21/12 8.37 6.04 7.23 13.9 mg/L 09/20/12 5.53 12.35 6.67 7.13 mg/L 09/18/13 8.19 5.36 6.09 5.86 mg/L 03/26/14 10.75 8.64 9.54 9.33 mg/L 09/18/14 6.17 5.45 6.38 6.12 mg/L 03/18/15 11.15 9.01 8.17 10.03 mg/L 09/23/15 4.77 4.18 5.09 4.93 mg/L 03/15/16 8.39 5.82 8.33 6.95 mg/L 09/20/16 7.91 4.18 6.84 6.32 mg/L 03/21/17 -- -- 7.50 7.45 mg/L 09/20/17 6.37 6.75 5.87 (re -sample) mg/L 10/02/17 -- -- -- -- mg/L 03/21/18 6.98 7.94 7.56 7.31 mg/L 09/25/18 6.67 4.00 7.43 5.71 mg/L 03/25/19 10.42 5.87 9.43 9.84 mg/L 09/18/19 5.27 3.17 7.43 5.39 Notes: mg/L = milligrams per liter S.U. = Standard Units NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter my = Millivolts -- = no data available dry = there was no discernible flow and a sample was not collected. 1) Historical data prior to March 2009 provided by Henderson County and CDM. 19128179 G GOLDER 2of2 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Antimony ug/L 03/24/09 0.68 2.00 6 ND ND ND ND ND IMAC = 1 ug/L ug/L 09/22/09 0.073 2.00 6 ND ND 0.098 J ND ND EPA MCL = 6 ug/L ug/L 03/24/10 0.22 2.00 6 ND ND ND ND ND ug/L 09/22/10 0.22 2.00 6 ND ND ND ND ND ug/L 03/16/11 0.22 2.00 6 ND ND 0.248 J 0.360 J ND ug/L 09/21/11 0.22 2.00 6 0.255 J -- ND 0.609 J ND ug/L 03/21/12 0.22 2.00 6 0.365 J 0.965 J ND ND ND ug/L 09/20/12 0.22 2.00 6 ND ND ND ND ND ug/L 03/20/13 0.22 2.00 6 ND 0.323 J ND ND ND ug/L 09/18/13 0.22 2.00 6 ND ND ND ND ND ug/L 03/27/14 0.22 2.00 6 ND 0.870 J ND ND ND ug/L 09/18/14 0.22 2.00 6 0.335 J 0.893 J ND ND ND ug/L 03/18/15 0.22 2.00 6 0.653 J 0.742 J ND ND ND ug/L 09/23/15 0.22 2.00 6 ND ND ND ND 0.331 J ug/L 03/15/16 0.22 2.00 6 0.908 J ND ND ND ND ug/L 09/21/16 0.22 2.00 6 ND 0.282 J ND ND ND ug/L 03/23/17 0.22 2.00 6 Dry ND ND ND ND ug/L 09/20/17 0.22 2.00 6 ND ND ND ND ND ug/L 03/21/18 0.22 5.00 6 ND ND ND ND ND ug/L 09/25/18 1.85 5.00 -- ND ND ND ND ND ug/L 03/25/19 0.74 2.00 ND ND ND ND ND ug/L 09/19/19 0.74 2.00 -- ND ND ND ND ND Arsenic ug/L 06/21/01 -- -- 10 ND ND ND ND NC 2L = 10 ug/L ug/L 04/24/02 10 ND ND ND ND EPA MCL = 10 ug/L ug/L 10/01/02 10 ND ND ND ND ug/L 04/10/03 10 ND ND ND ND ug/L 10/20/03 10 ND ND ND ND ug/L 03/24/04 10 ND ND ND ND ug/L 10/27/04 10 ND ND ND ND ug/L 05/25/05 10 ND ND ND ND ug/L 10/05/05 10 ND ND ND ND ug/L 04/25/06 10 ND ND ND ND ug/L 10/05/06 10 ND ND ND ND ND ug/L 03/21/07 10 ND ND ND ND ND ug/L 10/02/07 10 2.79 J ND ND 4.85 J ND ug/L 04/01/08 -- 10 10.1 3.01 J 6.29 J 9.48 J ND ug/L 10/29/08 10 ND ND ND ND ND ug/L 03/24/09 2.8 10.0 10 ND ND ND ND ND ug/L 09/22/09 2.8 10.0 10 ND 3.81 J 3.64 J ND ND ug/L 03/24/10 2.8 10.0 10 ND ND ND ND ND ug/L 09/22/10 2.8 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.8 10.0 10 ND ND ND ND ND ug/L 09/21/11 2.8 10.0 10 ND ND ND ND ug/L 03/21/12 2.8 10.0 10 ND ND ND ND ND ug/L 09/20/12 2.8 10.0 10 ND ND ND ND 3.27 J ug/L 03/20/13 2.8 10.0 10 ND ND 3.23 J ND ND ug/L 09/18/13 5.4 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.4 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.4 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.4 10.0 10 ND ND ND ND ND ug/L 09/21/16 5.4 10.0 10 ND ND ND ND ND ug/L 03/23/17 5.4 10.0 10 Dry ND ND ND ND ug/L 09/20/17 5.4 10.0 10 ND ND ND ND ND ug/L 03/21/18 5.4 10.0 10 ND ND ND ND ND ug/L 09/25/18 7.6 10.0 -- ND ND ND ND ND ug/L 03/25/19 7.6 10.0 ND ND ND ND ND ug/L 09/19/19 7.6 10.0 -- ND ND ND ND ND Barium ug/L 06/21/01 -- -- 100 ND ND ND ND NC 2L = 700 ug/L ug/L 04/24/02 100 278 ND 306 ND EPA MCL = 2000 ug/L ug/L 10/01/02 100 ND ND ND ND ug/L 04/10/03 100 ND ND ND ND ug/L 10/20/03 100 ND ND ND ND ug/L 03/24/04 100 ND ND ND ND ug/L 10/27/04 100 ND ND ND ND ug/L 05/25/05 100 ND ND ND ND ug/L 10/05/05 100 ND ND ND ND ug/L 04/25/06 100 ND ND ND ND ug/L 10/05/06 100 ND ND ND ND ND ug/L 03/21/07 100 19.5 J 25.0 J 19.7 J 20.0 J ND ug/L 10/02/07 100 12.0 J 24.7 J 15.6 J 28.2 J ND ug/L 04/01/08 100 49.5 J 63.1 J 27.6 J 153 ND ug/L 10/29/08 100 5.81 J 150 26.1 J 68.7 J ND ug/L 03/24/09 4.2 10.0 100 15.8 J 61.2 J 25.9 J 19.8 J ND ug/L 09/22/09 1.0 10.0 100 5.04 J 75.9 J 26.0 J 14.9 J ND ug/L 03/24/10 1.0 10.0 100 2.75 B 33.7 J 14.3 J 12.1 J 1.54 J ug/L 09/22/10 1.0 10.0 100 26.1 J 23.0 J 9.25 J 12.5 J ND ug/L 03/16/11 1.0 10.0 100 59.1 J 32.5 J 18.0 J 12.6 J ND ug/L 09/21/11 1.0 10.0 100 2.53 J -- 13.7 J 12.2 J ND ug/L 03/21/12 1.0 10.0 100 1.99 J 46.7 J 16.8 J 11.9 J ND ug/L 09/20/12 1.0 10.0 100 2.07 J 72.8 J 13.7 J 12.4 J ND ug/L 03/20/13 1.0 10.0 100 1.42 B 48.2 J 12.8 J 20.7 J 1.34 J ug/L 09/18/13 1.0 10.0 100 429 59.6 J 16.7 J 24.2 J 1.08 J ug/L 03/27/14 1.0 10.0 100 1.87 J 107 11.5 J 13.6 J ND ug/L 09/18/14 1.0 10.0 100 6.05 B 78.8 J 10.7 J 14.4 J 1.96 J ug/L 03/18/15 1.0 10.0 100 8.07 J 155 22.4 J 14.5 J ND ug/L 09/23/15 1.0 10.0 100 4.41 B 113 16.7 B 13.9 B 4.08 J ug/L 03/15/16 1.0 10.0 100 4.45 J 112 15.4 J 13.1 J ND ug/L 09/21/16 1.0 10.0 100 2.53 J 168 19.6 J 29.6 J ND ug/L 03/23/17 1.0 10.0 100 Dry 151 19.9 J 14.0 J ND ug/L 09/20/17 1.0 10.0 100 4.75 J 144 19.9 J 15.7 J ND ug/L 03/21/18 1.0 10.0 100 3.40 J 100 16.3 J 13.8 J ND ug/L 09/25/18 1.1 10.0 -- 2.75 J 86.4 15.5 12.6 ND ug/L 03/25/19 1.1 10.0 2.04 J 124 21.7 13.1 ND u /L 09/19/19 1.1 10.0 2.47 B 121 30.1 14.2 B 3.97 J ;;,j� GOLDER 1of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Beryllium ug/L 03/24/09 0.08 1.00 1 0.32 J 1.19 0.46 J 0.09 J ND IMAC = 4 ug/L ug/L 09/22/09 0.10 1.00 1 0.190 B 1.02 0.682 J 0.117 B 0.113 EPA MCL = 4 ug/L ug/L 03/24/10 0.10 1.00 1 0.178 J 1.46 0.130 J ND ND ug/L 09/22/10 0.10 1.00 1 ND 0.882 J 0.120 J ND ND ug/L 03/16/11 0.10 1.00 1 0.753 J 0.941 J 0.117 J ND ND ug/L 09/21/11 0.10 1.00 1 ND -- ND ND ND ug/L 03/21/12 0.10 1.00 1 ND 0.869 J 0.118 J ND ND ug/L 09/20/12 0.10 1.00 1 ND 1.04 ND ND ND ug/L 03/20/13 0.10 1.00 1 ND 0.785 J 0.102 J ND ND ug/L 09/18/13 0.10 1.00 1 5.56 1.12 0.193 J ND ND ug/L 03/27/14 0.10 1.00 1 0.139 J 1.55 0.132 J ND ND ug/L 09/18/14 0.10 1.00 1 0.112 J 0.968 J ND ND ND ug/L 03/18/15 0.10 1.00 1 0.143 J 1.37 0.135 J ND ND ug/L 09/23/15 0.10 1.00 1 ND 0.451 J ND ND ND ug/L 03/15/16 0.10 1.00 1 0.115 J 0.951 J ND ND ND ug/L 09/21/16 0.10 1.00 1 ND 0.676 J ND ND ND ug/L 03/23/17 0.10 1.00 1 Dry 0.458 J ND ND ND ug/L 09/20/17 0.10 1.00 1 ND 0.644 J ND ND ND ug/L 03/21/18 0.13 1.00 1 0.211 J 0.426 J ND ND ND ug/L 09/25/18 0.16 1.00 -- 0.224 J 0.480 J 0.221 J ND ND ug/L 03/25/19 0.16 1.00 0.220 J 0.462 J ND ND ND ug/L 09/19/19 0.16 1.00 -- ND 0.501 J ND ND ND Cadmium ug/L 06/21/01 -- -- 1 ND ND ND ND NC 2L = 2 ug/L ug/L 04/24/02 1 ND ND ND ND EPA MCL = 5 ug/L ug/L 10/01/02 1 ND ND ND ND ug/L 04/10/03 1 ND ND ND ND ug/L 10/20/03 1 ND ND ND ND ug/L 03/24/04 1 ND ND ND ND ug/L 10/27/04 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND ND ND ug/L 04/25/06 -- 1 ND ND ND ND -- ug/L 10/05/06 -- 1 ND ND ND ND ND ug/L 03/21/07 -- 1 0.750 J 1.31 J 2.31 J 2.15 J ND ug/L 10/02/07 1 ND ND 2.90 J ND ND ug/L 04/01/08 1 ND ND ND 0.53 J ND ug/L 10/29/08 1 ND 0.35 J ND ND ND ug/L 03/24/09 0.09 1.00 1 ND 0.27 J 0.14 J ND ND ug/L 09/22/09 0.36 1.00 1 ND 1.15 0.461 J 1.00 ND ug/L 03/24/10 0.36 1.00 1 ND ND ND ND ND ug/L 09/22/10 0.36 1.00 1 ND ND ND ND ND ug/L 03/16/11 0.36 1.00 1 ND ND ND ND ND ug/L 09/21/11 0.36 1.00 1 ND 0.402 J ND ND ug/L 03/21/12 0.36 1.00 1 ND ND 0.774 J ND ND ug/L 09/20/12 0.36 1.00 1 ND ND ND ND ND ug/L 03/20/13 0.36 1.00 1 ND ND ND ND ND ug/L 09/18/13 0.36 1.00 1 ND ND ND ND ND ug/L 03/27/14 0.36 1.00 1 ND 1.05 ND ND ND ug/L 09/18/14 0.36 1.00 1 ND ND ND ND ND ug/L 03/18/15 0.36 1.00 1 ND ND ND ND ND ug/L 09/23/15 0.36 1.00 1 ND ND ND ND ND ug/L 03/15/16 0.36 1.00 1 ND ND ND ND ND ug/L 09/21/16 0.36 1.00 1 ND ND ND ND ND ug/L 03/23/17 0.36 1.00 1 Dry 0.573 B ND ND 0.508 J ug/L 09/20/17 0.36 1.00 1 ND ND ND ND ND ug/L 03/21/18 0.36 1.00 1 ND ND ND ND ND ug/L 09/25/18 0.36 1.00 -- ND ND ND ND ND ug/L 03/25/19 0.36 1.00 ND ND ND ND ND ug/L 09/19/19 0.36 1.00 -- ND ND ND ND ND Chromium ug/L 06/21/01 -- -- 10 ND ND ND 23.8 NC 2L = 10 ug/L ug/L 04/24/02 10 ND ND ND ND EPA MCL = 100 ug/L ug/L 10/01/02 10 ND ND ND ND ug/L 04/10/03 10 ND ND ND ND ug/L 10/20/03 10 ND ND ND 13.5 ug/L 03/24/04 10 ND ND ND 12.8 ug/L 10/27/04 10 ND ND ND ND ug/L 05/25/05 10 ND ND ND ND ug/L 10/05/05 10 ND ND ND ND ug/L 04/25/06 10 ND ND ND ND ug/L 10/05/06 10 ND ND ND ND ND ug/L 03/21/07 10 3.41 J 3.26 J 3.55 J 2.97 J ND ug/L 10/02/07 10 2.28 J 1.17 J 2.08 J 3.80 J ND ug/L 04/01/08 10 5.80 J 3.56 J 3.07 J 103 ND ug/L 10/29/08 10 ND ND 1.77 J 19.0 ND ug/L 03/24/09 0.7 10.0 10 1.0 J ND 1.2 J 3.0 J ND ug/L 09/22/09 1.0 10.0 10 ND ND ND ND ND ug/L 03/24/10 1.0 10.0 10 ND ND ND ND ND ug/L 09/22/10 1.0 10.0 10 1.18 J ND ND ND ND ug/L 03/16/11 1.0 10.0 10 5.18 J ND ND ND ND ug/L 09/21/11 1.0 10.0 10 ND ND ND ND ug/L 03/21/12 1.0 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.0 10.0 10 ND 1.80 J ND ND ND ug/L 03/20/13 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/13 1.4 10.0 10 12.6 ND ND 1.57 J ND ug/L 03/27/14 1.4 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 10 ND ND ND ND ND ug/L 09/23/15 1.4 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.4 10.0 10 ND ND ND ND ND ug/L 09/21/16 1.4 10.0 10 ND ND ND ND ND ug/L 03/23/17 1.4 10.0 10 Dry ND ND 4.79 J ND ug/L 09/20/17 1.4 10.0 10 ND ND ND ND ND ug/L 03/21/18 1.4 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.4 10.0 ND ND ND ND ND u /L 09/19/19 1.4 10.0 ND ND ND ND ND ;;,j� GOLDER 2of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Cobalt ug/L 03/24/09 0.6 10.0 10 0.8 J ND 1.10 J ND ND IMAC = 1 ug/L ug/L 09/22/09 1.1 10.0 10 ND ND 1.28 J ND ND EPA MCL = No Standard ug/L 03/24/10 1.1 10.0 10 ND 4.30 J ND ND ND ug/L 09/22/10 1.1 10.0 10 2.10 J 2.89 J 1.87 J ND ND ug/L 03/16/11 1.1 10.0 10 3.28 J 2.05 J ND ND ND ug/L 09/21/11 1.1 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.1 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.1 10.0 10 ND 1.37 J 1.55 J 1.11 J ND ug/L 03/20/13 1.1 10.0 10 ND 1.54 J ND 2.35 J ND ug/L 09/18/13 1.1 10.0 10 15.3 1.56 J ND ND ND ug/L 03/27/14 1.1 10.0 10 ND 6.98 J ND ND ND ug/L 09/18/14 1.1 10.0 10 ND 7.44 J ND ND ND ug/L 03/18/15 1.1 10.0 10 ND 1.29 J ND ND ND ug/L 09/23/15 1.1 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.1 10.0 10 ND 2.74 J ND ND ND ug/L 09/21/16 1.1 10.0 10 ND 4.39 J ND ND ND ug/L 03/23/17 1.1 10.0 10 Dry ND ND ND ND ug/L 09/20/17 1.1 10.0 10 ND 2.27 J ND 1.28 J ND ug/L 03/21/18 1.1 10.0 10 ND 2.93 J ND 1.32 J ND ug/L 09/25/18 1.4 10.0 -- ND 5.09 J ND ND ND ug/L 03/25/19 1.4 10.0 ND 3.18 J ND 1.93 J ND ug/L 09/19/19 1.4 10.0 -- ND 13.0 ND ND ND Copper ug/L 03/24/09 0.81 10.0 10 3.42 J ND ND ND ND NC 2L =1000 ug/L ug/L 09/22/09 1.6 10.0 10 ND ND ND 1.82 J ND EPA MCL = 1300 ug/L ug/L 03/24/10 1.6 10.0 10 ND 2.76 J ND ND ND ug/L 09/22/10 1.6 10.0 10 3.49 J ND ND ND ND ug/L 03/16/11 1.6 10.0 10 15.9 2.55 J 3.09 J 4.85 J ND ug/L 09/21/11 1.6 10.0 10 ND -- ND 1.80 J ND ug/L 03/21/12 1.6 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.6 10.0 10 ND ND ND ND ND ug/L 03/20/13 1.6 10.0 10 ND ND 1.97 J ND ND ug/L 09/18/13 1.6 10.0 10 31.1 ND ND ND ND ug/L 03/27/14 1.6 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.6 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.6 10.0 10 ND 4.30 B 1.95 B ND 1.74 J ug/L 09/23/15 1.6 10.0 10 ND ND ND ND ND ug/L 03/15/16 1.6 10.0 10 ND ND ND ND 2.01 J ug/L 09/21/16 1.6 10.0 10 3.22 B 2.80 B 5.34 B 2.15 B 3.37 J ug/L 03/23/17 1.6 10.0 10 Dry ND ND ND 1.97 J ug/L 09/20/17 1.6 10.0 10 3.20 B 4.13 B 2.70 B 2.55 B 2.35 J ug/L 03/21/18 1.6 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.6 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.6 10.0 ND 4.17 J ND ND ND ug/L 09/19/19 1.6 10.0 -- ND ND ND ND 5.73 J Lead ug/L 06/21/01 -- -- 10 14.2 ND ND 10.4 -- NC 2L = 15 ug/L ug/L 04/24/02 10 ND ND ND ND EPA MCL = 15 ug/L ug/L 10/01/02 10 ND ND ND ND ug/L 04/10/03 10 ND ND ND ND ug/L 10/20/03 10 ND ND ND ND ug/L 03/24/04 10 ND ND ND ND ug/L 10/27/04 10 ND ND ND ND ug/L 05/25/05 10 10.3 ND ND ND ug/L 10/05/05 10 ND ND ND ND ug/L 04/25/06 10 ND ND ND ND ug/L 10/05/06 -- 10 ND ND ND ND ND ug/L 03/21/07 -- 10 3.32 J 3.57 J 2.12 J ND ND ug/L 10/02/07 -- 10 ND ND ND ND ND ug/L 04/01/08 -- 10 13.1 9.16 J ND 25.1 ND ug/L 10/29/08 10 6.51 J ND 8.35 J 9.00 J ND ug/L 03/24/09 1.6 10.0 10 4.4 J 3.7 J 3.1 J 3.9 J ND ug/L 09/22/09 1.9 10.0 10 2.40 J ND 3.84 J ND ND ug/L 03/24/10 1.9 10.0 10 ND ND 2.18 J ND ND ug/L 09/22/10 1.9 10.0 10 2.56 J ND ND ND ND ug/L 03/16/11 1.9 10.0 10 12.8 2.55 J ND 2.29 J ND ug/L 09/21/11 1.9 10.0 10 ND -- ND ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND 2.70 J ug/L 03/20/13 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/13 2.1 10.0 10 37.6 ND ND ND ND ug/L 03/27/14 2.1 10.0 10 ND ND ND ND ND ug/L 09/18/14 2.1 10.0 10 ND ND ND ND ND ug/L 03/18/15 2.1 10.0 10 ND ND ND ND ND ug/L 09/23/15 2.1 10.0 10 ND ND ND ND ND ug/L 03/15/16 2.1 10.0 10 ND ND ND ND ND ug/L 09/21/16 2.1 10.0 10 ND ND ND ND ND ug/L 03/23/17 2.1 10.0 10 Dry ND ND ND ND ug/L 09/20/17 3.1 10.0 10 ND ND ND ND ND ug/L 03/21/18 3.1 10.0 10 ND 6.99 J ND ND ND ug/L 09/25/18 3.1 10.0 -- ND ND ND ND 8.83 ug/L 03/25/19 3.1 10.0 ND ND ND ND ND u /L 09/19/19 3.1 10.0 ND ND ND ND ND ;;,j� GOLDER 3of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Mercury ug/L 06/21/01 0.2 ND ND ND ND NC 2L = 1 ug/L ug/L 04/24/02 0.2 ND ND ND ND EPA MCL = 2 ug/L ug/L 10/01/02 0.2 ND ND ND ND ug/L 04/10/03 0.2 ND ND ND ND ug/L 10/20/03 0.2 ND ND ND ND ug/L 03/24/04 0.2 ND ND ND ND ug/L 10/27/04 0.2 ND ND ND ND ug/L 05/25/05 0.2 ND ND ND ND ug/L 10/05/05 0.2 ND ND ND ND ug/L 04/25/06 0.2 ND ND ND ND ug/L 10/05/06 0.2 ND ND ND ND ND ug/L 03/21/07 0.2 ND ND 0.093 J ND ND ug/L 10/02/07 0.2 ND ND 0.136 J ND ND ug/L 04/01/08 -- 0.2 ND ND 0.096 J ND ND ug/L 10/29/08 0.2 ND ND 0.198 J ND ND ug/L 03/24/09 0.11 0.20 0.2 ND ND 0.54 ND ND ug/L 09/22/09 0.054 0.200 0.2 ND ND 0.172 J ND ND ug/L 03/24/10 0.054 0.200 0.2 ND 0.0586 J 0.144 J ND ND ug/L 09/22/10 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/16/11 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/21/11 0.17 0.200 0.2 ND -- ND ND ND ug/L 03/21/12 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/20/12 0.17 0.200 0.2 ND ND 0.253 ND ND ug/L 03/20/13 0.17 0.200 0.2 ND ND 0.199 J ND ND ug/L 09/18/13 0.17 0.200 0.2 ND ND ND 0.246 ND ug/L 03/27/14 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/18/14 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/18/15 0.17 0.200 0.2 ND ND 0.227 ND ND ug/L 09/23/15 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/15/16 0.17 0.200 0.2 ND ND ND 0.275 ND ug/L 09/21/16 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/23/17 0.17 0.200 0.2 Dry ND ND ND ND ug/L 09/20/17 0.17 0.200 0.2 ND ND ND ND ND ug/L 03/21/18 0.17 0.200 0.2 ND ND ND ND ND ug/L 09/25/18 0.15 0.200 -- ND ND ND ND ND ug/L 03/25/19 0.15 0.200 ND ND ND ND ND ug/L 09/19/19 0.15 0.200 -- ND ND ND ND ND Nickel ug/L 03/24/09 0.6 10.0 50 0.7 J ND 1.1 J 1.0 J ND NC 2L = 100 ug/L ug/L 09/22/09 1.8 50.0 50 ND ND ND 1.88 J ND EPA MCL = No Standard ug/L 03/24/10 1.8 10.0 50 ND ND ND ND ND ug/L 09/22/10 1.8 10.0 50 ND ND ND ND ND ug/L 03/16/11 1.8 10.0 50 3.91 J ND ND ND ND ug/L 09/21/11 1.8 10.0 50 ND ND ND ND ug/L 03/21/12 1.8 10.0 50 ND ND ND ND ND ug/L 09/20/12 1.8 10.0 50 ND 3.07 J ND ND ND ug/L 03/20/13 1.8 10.0 50 ND ND ND ND ND ug/L 09/18/13 1.8 10.0 50 7.11 J ND ND ND ND ug/L 03/27/14 1.8 10.0 50 ND ND ND ND ND ug/L 09/18/14 1.8 10.0 50 ND ND ND ND ND ug/L 03/18/15 1.8 10.0 50 ND 14.3 J ND ND ND ug/L 09/23/15 1.8 10.0 50 ND 4.08 B ND ND 2.22 J ug/L 03/15/16 1.8 10.0 50 ND ND ND ND ND ug/L 09/21/16 1.8 10.0 50 ND ND ND 2.29 J ND ug/L 03/23/17 1.8 10.0 50 Dry 5.08 B 2.26 B 2.24 B 2.63 J ug/L 09/20/17 1.8 10.0 50 ND 3.23 J ND ND ND ug/L 03/21/18 1.8 10.0 50 ND ND ND ND ND ug/L 09/25/18 2.2 10.0 -- ND ND ND ND 10.1 ug/L 03/25/19 2.2 10.0 ND ND ND ND ND ug/L 09/19/19 2.2 10.0 -- ND ND ND ND ND Selenium ug/L 06/21/01 -- -- 10 ND ND ND ND NC 2L = 20 ug/L ug/L 04/24/02 -- 10 ND ND ND ND EPA MCL = 50 ug/L ug/L 10/01/02 10 ND ND ND ND ug/L 04/10/03 10 ND ND ND ND ug/L 10/20/03 10 ND ND ND ND ug/L 03/24/04 10 ND ND ND ND ug/L 10/27/04 10 ND ND ND ND ug/L 05/25/05 10 ND ND ND ND ug/L 10/05/05 10 ND ND ND ND ug/L 04/25/06 10 ND ND ND ND ug/L 10/05/06 10 ND ND ND ND ND ug/L 03/21/07 10 ND ND ND 10.2 J ND ug/L 10/02/07 10 ND ND ND ND ND ug/L 04/01/08 10 ND ND ND 19.2 ND ug/L 10/29/08 10 ND ND ND ND ND ug/L 03/24/09 3.4 10.0 10 ND ND ND ND ND ug/L 09/22/09 2.7 10.0 10 ND ND ND ND ND ug/L 03/24/10 0.83 1.00 10 ND ND ND ND ND ug/L 09/22/10 2.7 10.0 10 ND ND ND ND ND ug/L 03/16/11 2.7 10.0 10 ND ND ND ND 3.32 J ug/L 09/21/11 0.83 1.00 10 ND ND ND ND ug/L 03/21/12 2.7 10.0 10 ND ND ND ND ND ug/L 09/20/12 2.7 10.0 10 ND ND ND ND ND ug/L 03/20/13 4.5 10.0 10 ND ND ND ND ND ug/L 09/18/13 5.0 10.0 10 ND ND ND ND ND ug/L 03/27/14 5.0 10.0 10 ND ND ND ND ND ug/L 09/18/14 5.0 10.0 10 ND ND ND ND ND ug/L 03/18/15 5.0 10.0 10 ND ND ND ND ND ug/L 09/23/15 5.0 10.0 10 ND ND ND ND ND ug/L 03/15/16 5.0 10.0 10 ND ND ND ND ND ug/L 09/21/16 5.0 10.0 10 ND ND ND ND ND ug/L 03/23/17 5.0 10.0 10 Dry ND ND ND 14.1 J ug/L 09/20/17 5.0 10.0 10 ND ND ND ND ND ug/L 03/21/18 5.0 10.0 10 ND ND ND ND ND ug/L 09/25/18 6.2 10.0 -- ND ND ND ND ND ug/L 03/25/19 6.2 10.0 ND ND ND ND ND ug/L 09/19/19 6.2 10.0 ND ND ND ND ND u /L 09/19/19 1.82 2.0 ND ND ND ND ND ;;,j� GOLDER 4of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Silver ug/L 06/21/01 10 ND ND ND ND NC 2L = 20 ug/L ug/L 04/24/02 10 ND ND ND ND EPA MCL = 100 ug/L ug/L 10/01/02 10 ND ND ND ND ug/L 04/10/03 10 ND ND ND ND ug/L 10/20/03 10 ND ND ND ND ug/L 03/24/04 10 ND ND ND ND ug/L 10/27/04 10 ND ND ND ND ug/L 05/25/05 10 ND ND ND ND ug/L 10/05/05 10 ND ND ND ND ug/L 04/25/06 10 ND ND ND ND ug/L 10/05/06 10 ND ND ND ND ND ug/L 03/21/07 10 3.49 J 3.41 J 3.04 J 2.96 J ND ug/L 10/02/07 10 ND ND ND ND ND ug/L 04/01/08 -- 10 4.12 J 4.48 J 4.07 J 3.65 J ND ug/L 10/29/08 10 1.57 B 1.80 B 1.40 B 1.52 B -- ug/L 03/24/09 1.0 10.0 10 ND 1.2 J ND ND ND ug/L 09/22/09 1.9 10.0 10 ND ND ND ND ND ug/L 03/24/10 1.9 10.0 10 ND ND ND ND ND ug/L 09/22/10 1.9 10.0 10 ND ND ND ND ND ug/L 03/16/11 1.9 10.0 10 ND ND ND ND ND ug/L 09/21/11 1.9 10.0 10 ND ND ND ND ug/L 03/21/12 1.9 10.0 10 ND ND ND ND ND ug/L 09/20/12 1.9 10.0 10 ND ND ND ND ND ug/L 03/20/13 1.9 10.0 10 ND ND ND ND 2.11 J ug/L 09/18/13 1.9 10.0 10 ND ND ND ND ND ug/L 03/27/14 1.9 10.0 10 ND ND ND ND ND ug/L 09/18/14 1.9 10.0 10 ND ND ND ND ND ug/L 03/18/15 1.9 10.0 10 ND ND ND ND ND ug/L 09/23/15 1.9 10.0 10 ND ND ND ND 4.69 J ug/L 03/15/16 1.9 10.0 10 ND ND ND ND ND ug/L 09/21/16 1.9 10.0 10 ND ND ND ND ND ug/L 03/23/17 1.9 10.0 10 Dry 1.63 B 0.902 B ND 0.823 J ug/L 09/20/17 1.9 10.0 10 ND ND ND ND ND ug/L 03/21/18 1.9 10.0 10 ND ND ND ND ND ug/L 09/25/18 1.9 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.9 10.0 ND ND ND ND ND ug/L 09/19/19 1.9 10.0 -- ND ND ND ND ND Thallium ug/L 03/24/09 0.036 1.00 5.5 ND ND 0.061 B ND 0.092 J IMAC = 0.2 ug/L ug/L 09/22/09 0.11 1.00 5.5 ND ND ND ND ND EPA MCL = 2 ug/L ug/L 03/24/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/22/10 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/16/11 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/21/11 0.11 1.00 5.5 ND ND ND ND ug/L 03/21/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/20/12 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/20/13 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/13 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/27/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/18/14 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/18/15 0.11 1.00 5.5 0.251 J 0.202 J ND ND ND ug/L 09/23/15 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/15/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 09/21/16 0.11 1.00 5.5 ND ND ND ND ND ug/L 03/21/17 0.11 1.00 5.5 Dry 0.221 J 0.273 J 0.274 J ND ug/L 09/20/17 0.11 1.00 5.5 0.189 J 0.425 J 0.424 J 0.319 J ND ug/L 03/21/18 0.11 5.00 5.5 ND ND ND ND ND ug/L 09/25/18 0.55 5.00 -- ND ND ND ND ND ug/L 03/25/19 0.22 2.00 ND ND ND ND ND ug/L 09/19/19 0.22 2.00 -- ND ND ND ND ND Vanadium ug/L 03/24/09 0.7 10.0 25 4.9 J 1.0 J 6.5 J 3.3 J ND IMAC = 0.3 ug/L ug/L 09/22/09 1.4 10.0 25 2.01 J ND 6.20 J 2.01 J ND EPA MCL = No Standard ug/L 03/24/10 1.4 10.0 25 ND 2.62 J 1.57 J ND ND ug/L 09/22/10 1.4 10.0 25 7.06 J ND ND 1.64 J ND ug/L 03/16/11 1.4 10.0 25 19.5 J 1.76 J 3.03 J ND ND ug/L 09/21/11 1.4 10.0 25 ND -- 2.32 J ND ND ug/L 03/21/12 1.4 10.0 25 ND 2.19 J 3.02 J 1.52 J ND ug/L 09/20/12 1.4 10.0 25 ND 2.85 J ND ND ND ug/L 03/20/13 1.4 10.0 25 ND 2.34 J ND 1.91 J ND ug/L 09/18/13 1.4 10.0 25 75.0 1.86 J 1.72 J 3.22 J ND ug/L 03/27/14 1.4 10.0 25 ND ND ND ND ND ug/L 09/18/14 1.4 10.0 25 ND ND ND ND ND ug/L 03/18/15 1.4 10.0 25 1.62 J 2.39 J 1.87 J ND ND ug/L 09/23/15 1.4 10.0 25 2.11 J ND 1.83 J 1.53 J ND ug/L 03/15/16 1.4 10.0 25 ND ND ND ND ND ug/L 09/21/16 1.4 10.0 25 ND ND ND ND ND ug/L 03/21/17 1.4 10.0 25 Dry 2.15 B ND ND 0.589 J ug/L 09/20/17 1.4 10.0 25 ND 1.65 J ND ND ND ug/L 03/21/18 1.4 10.0 25 ND ND ND ND ND ug/L 09/25/18 1.4 10.0 -- ND ND ND ND ND ug/L 03/25/19 1.4 10.0 ND ND ND ND ND ug/L 09/19/19 1.4 10.0 -- ND ND ND ND ND Zinc ug/L 03/24/09 3.4 10.0 10 8.0 B 9.0 B 17.9 7.2 B 3.4 NC 2L = 1000 ug/L ug/L 09/22/09 3.8 10.0 10 ND 32.4 17.3 12.0 ND EPA MCL = 5000 ug/L" ug/L 03/24/10 3.8 10.0 10 13.2 20.0 21.5 12.2 ND ug/L 09/22/10 3.8 10.0 10 14.8 7.45 J 6.78 J 10.5 ND ug/L 03/16/11 3.8 10.0 10 43.2 4.05 J 12.5 26.0 ND ug/L 09/21/11 3.8 10.0 10 ND -- 12.0 12.5 ND ug/L 03/21/12 3.8 10.0 10 ND 92.0 6.44 J ND ND ug/L 09/20/12 3.8 10.0 10 ND 22.2 ND ND ND ug/L 03/20/13 3.8 10.0 10 9.34 J 11.2 11.9 8.08 J ND ug/L 09/18/13 3.8 10.0 10 152 15.6 9.51 J 7.43 J ND ug/L 03/27/14 3.8 10.0 10 ND 13.7 ND 7.05 J ND ug/L 09/18/14 3.8 10.0 10 4.00 J 15.5 ND 5.45 J ND ug/L 03/18/15 3.8 10.0 10 ND 265 9.40 J 5.27 J ND ug/L 09/23/15 3.8 10.0 10 ND 3.93 J ND ND ND ug/L 03/15/16 3.8 10.0 10 ND 8.92 J ND ND ND ug/L 09/21/16 3.8 10.0 10 ND ND ND ND ND ug/L 03/21/17 3.8 10.0 10 Dry 16.6 ND ND ND ug/L 09/20/17 3.8 10.0 10 ND 56.0 ND ND ND ug/L 03/21/18 3.8 10.0 10 ND 36.4 ND ND ND ug/L 09/25/18 4.4 10.0 -- ND 10.7 B ND ND 64.2 ug/L 03/25/19 4.4 10.0 ND ND ND ND ND u /L 09/19/19 4.4 10.0 ND 5.76 J 5.08 J ND ND GOLDER 5of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit Iron ug/L 03/24/09 31.0 50.0 300 2750 1400 4810 1670 ND NC 2L = 300 ug/L ug/L 09/22/09 22.0 50.0 300 684 1390 4450 735 ND EPA MCL = 300 ug/L ug/L 03/24/10 22.0 50.0 300 151 J 2050 830 564 27.6 ug/L 09/22/10 22.0 50.0 300 4690 630 841 658 ND ug/L 03/16/11 22.0 50.0 300 14200 1770 1600 462 ND ug/L 09/21/11 22.0 50.0 300 153 J -- 269 J 457 ND ug/L 03/21/12 22.0 50.0 300 81.3 B 4460 1260 245 J 44.0 J ug/L 09/20/12 22.0 50.0 300 36.2 J 4040 133 J 91.7 J ND ug/L 03/20/13 22.0 50.0 300 22.2 J 4530 594 2040 ND ug/L 09/18/13 22.0 50.0 300 52700 5170 1270 1770 ND ug/L 03/27/14 22.0 50.0 300 41.0 J 6590 126 J 35.9 J ND ug/L 09/18/14 22.0 50.0 300 425 6200 37.0 J 454 ND ug/L 03/18/15 22.0 50.0 300 659 5720 880 214 J ND ug/L 09/23/15 22.0 50.0 300 302 979 632 323 ND ug/L 03/15/16 22.0 50.0 300 192 J 2860 82.5 J 157 J ND ug/L 09/21/16 22.0 50.0 300 ND 6720 38.0 J 299 J ND ug/L 03/21/17 22.0 50.0 300 Dry 1250 51.1 B 676 29.4 J ug/L 09/20/17 22.0 50.0 300 334 4730 59.3 J 778 ND ug/L 03/21/18 22.0 50.0 300 ND 3880 150 J 895 ND ug/L 09/25/18 22.0 50.0 -- 30.4 J 9610 63.8 705 ND ug/L 03/25/19 22.0 50.0 39.2 J 6580 104 1360 ND ug/L 09/19/19 22.0 50.0 -- ND 17100 154 1160 26.9 J Manganese ug/L 03/24/09 1.1 10.0 50 60.9 165 155 59.1 ND NC 2L = 50 ug/L ug/L 09/22/09 1.1 10.0 50 18.1 J 186 163 34.9 J 1.99 EPA MCL = 50 ug/L ug/L 03/24/10 1.1 10.0 50 4.51 B 1780 142 111 2.13 ug/L 09/22/10 1.1 10.0 50 121 923 743 58.4 3.27 J ug/L 03/16/11 1.1 10.0 50 356 349 389 116 3.57 J ug/L 09/21/11 1.1 10.0 50 8.27 J -- 239 66.2 ND ug/L 03/21/12 1.1 10.0 50 3.45 B 164 295 88.3 2.02 J ug/L 09/20/12 1.1 10.0 50 1.43 J 256 163 74.2 ND ug/L 03/20/13 1.1 10.0 50 2.22 B 262 285 286 7.96 J ug/L 09/18/13 1.1 10.0 50 1530 390 214 84.9 1.75 J ug/L 03/27/14 1.1 10.0 50 2.05 B 1690 285 64.7 3.64 J ug/L 09/18/14 1.1 10.0 50 16.9 J 1950 176 64.7 ND ug/L 03/18/15 1.1 10.0 50 24.4 J 593 124 74.0 ND ug/L 09/23/15 1.1 10.0 50 8.10 J 823 128 85.6 ND ug/L 03/15/16 1.1 10.0 50 5.96 J 1250 123 96.0 ND ug/L 09/21/16 1.1 10.0 50 1.78 J 2330 148 103 ND ug/L 03/21/17 1.1 10.0 50 Dry 1520 172 138 ND ug/L 09/20/17 1.1 10.0 50 9.55 J 2420 194 172 ND ug/L 03/21/18 1.1 10.0 50 2.29 J 2300 199 199 ND ug/L 09/25/18 1.5 10.0 -- 1.58 J 4010 130 153 ND ug/L 03/25/19 1.5 10.0 2.05 J 5200 199 285 ND ug/L 09/19/19 1.5 10.0 -- ND 5950 407 247 1.59 J Acetone ug/L 03/24/09 1.5 5.0 100 ND ND 3.8 J ND ND NC 2L = 6000 ug/L ug/L 09/22/09 1.5 5.0 100 ND ND ND ND ND EPA MCL = No Standard ug/L 03/24/10 1.5 5.0 100 ND 19 J 13 J ND ND ug/L 09/22/10 1.5 5.0 100 ND 4.5 J 2.7 J ND ND ug/L 03/16/11 1.2 5.0 100 ND 92 J 17 J ND ND ug/L 09/21/11 1.2 5.0 100 ND -- 18 J ND ND ug/L 03/21/12 1.2 5.0 100 ND 7.5 J 30 J ND ND ug/L 09/20/12 1.2 5.0 100 ND 4.3 B 9.9 B ND 7.0 J ug/L 03/20/13 1.2 5.0 100 ND ND 6.8 J ND ND ug/L 09/18/13 1.2 5.0 100 ND ND ND ND ND ug/L 03/27/14 1.2 5.0 100 ND 18 B ND ND 19 J ug/L 09/18/14 1.2 5.0 100 ND 4.9 J ND ND ND ug/L 03/18/15 1.2 5.0 100 ND 160 ND ND ND ug/L 09/23/15 1.2 5.0 100 ND ND ND ND ND ug/L 03/15/16 1.2 5.0 100 ND ND ND ND ND ug/L 09/21/16 1.2 5.0 100 ND 11 J ND ND ND ug/L 03/21/17 1.2 5.0 100 Dry 11 J ND ND ND ug/L 09/20/17 1.2 20 100 ND 39 J ND ND ND ug/L 03/21/18 1.2 20 100 ND ND ND ND ND ug/L 09/25/18 10 20 -- ND ND ND ND ND ug/L 03/25/19 10 20 ND 11 J ND ND ND ug/L 09/19/19 10 20 -- ND ND ND ND ND Benzene ug/L 06/21/01 5.0 5.0 1 ND ND ND ND NC 2L = 1 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND EPA MCL = 5 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND ug/L 04/10/03 5.0 5.0 1 ND ND ND ND ug/L 10/20/03 5.0 5.0 1 ND ND ND ND ug/L 03/24/04 5.0 5.0 1 ND ND ND ND ug/L 10/27/04 5.0 5.0 1 ND ND ND ND ug/L 05/25/05 5.0 5.0 1 ND ND ND ND ug/L 10/05/05 5.0 5.0 1 ND ND ND ND ug/L 04/25/06 -- -- 1 ND ND ND ND ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 1 ND ND ND ND ND ug/L 10/02/07 1 ND ND 0.15 J ND ND ug/L 04/01/08 1 ND ND 0.28 J ND ND ug/L 10/29/08 -- 1 ND ND 0.28 J ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND 0.50 J ND ND ND ug/L 03/24/10 0.050 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.20 1.0 1 ND ND ND ND ND ug/L 03/16/11 0.68 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.68 1.0 1 ND ND ND ND ug/L 03/21/12 0.15 1.0 1 ND ND ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND 0.47 J ND ND ug/L 03/27/14 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.15 1.0 1 ND 0.76 J 0.47 J ND ND ug/L 03/15/16 0.15 1.0 1 ND 0.72 J ND ND ND ug/L 09/21/16 0.15 1.0 1 ND 0.92 J ND ND ND ug/L 03/21/17 0.15 1.0 1 Dry 0.75 J ND ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.15 1.0 -- ND 0.74 J ND ND ND ug/L 03/25/19 0.15 1.0 ND 0.59 J 0.66 J ND ND ug/L 09/19/19 0.15 1.0 ND ND ND ND ND GOLDER 6of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit 1,4-Dichlorobenzene ug/L 06/21/01 0.27 5.0 1 ND ND ND ND NC 2L = 6 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND EPA MCL = 75 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND ug/L 04/10/03 5.0 5.0 1 ND ND ND ND ug/L 10/20/03 5.0 5.0 1 ND ND ND ND ug/L 03/24/04 5.0 5.0 1 ND ND ND ND ug/L 10/27/04 5.0 5.0 1 ND ND ND ND ug/L 05/25/05 5.0 5.0 1 ND ND ND ND ug/L 10/05/05 5.0 5.0 1 ND ND ND ND ug/L 04/25/06 -- -- 1 ND ND ND ND ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 -- 1 ND ND 0.21 J ND ND ug/L 10/02/07 -- 1 ND ND 0.23 J 0.23 J ND ug/L 04/01/08 -- 1 ND ND 0.26 J ND ND ug/L 10/29/08 1 ND ND 0.23 J ND ND ug/L 03/24/09 0.38 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND ND ND ND ug/L 03/24/10 0.10 1.0 1 ND 0.46 J ND 0.45 J ND ug/L 09/22/10 0.38 1.0 1 ND ND ND 0.57 J ND ug/L 03/16/11 0.79 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.79 1.0 1 ND ND ND ND ug/L 03/21/12 0.19 1.0 1 ND ND ND 0.64 J ND ug/L 09/20/12 0.19 1.0 1 ND ND ND 0.51 J ND ug/L 03/20/13 0.19 1.0 1 ND ND ND 0.41 J ND ug/L 09/18/13 0.19 1.0 1 ND ND ND 0.55 J ND ug/L 03/27/14 0.19 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.19 1.0 1 ND ND ND 0.52 J ND ug/L 03/18/15 0.19 1.0 1 ND ND ND 0.55 J ND ug/L 09/23/15 0.19 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.19 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.19 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.19 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.19 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.19 1.0 -- ND 1.0 ND ND ND ug/L 03/25/19 0.19 1.0 ND ND ND ND ND ug/L 09/19/19 0.19 1.0 -- ND ND ND ND ND 1,1-Dichloroethane ug/L 06/21/01 5.0 5.0 5 ND ND ND ND NC 2L = 6 ug/L ug/L 04/24/02 5.0 5.0 5 ND ND ND ND EPA MCL = No Standard ug/L 10/01/02 5.0 5.0 5 ND ND ND ND ug/L 04/10/03 5.0 5.0 5 ND ND ND ND ug/L 10/20/03 -- -- 5 ND ND ND ND ug/L 03/24/04 5 ND ND ND ND ug/L 10/27/04 5 ND ND ND ND ug/L 05/25/05 5 ND ND ND ND ug/L 10/05/05 5 ND ND ND ND ug/L 04/25/06 5 ND ND ND ND ug/L 10/05/06 5 ND ND ND ND ND ug/L 03/21/07 5 ND ND 0.71 J ND ND ug/L 10/02/07 -- 5 ND ND 0.79 J 0.09 J ND ug/L 04/01/08 -- 5 ND ND 0.99 J 0.12 J ND ug/L 10/29/08 -- 5 ND ND 1.01 J 0.15 J ND ug/L 03/24/09 0.33 1.0 5 ND ND 0.82 J ND ND ug/L 09/22/09 0.33 1.0 5 ND ND 0.70 J ND ND ug/L 03/24/10 0.050 1.0 5 ND ND 0.47 J ND ND ug/L 09/22/10 0.33 1.0 5 ND ND ND ND ND ug/L 03/16/11 0.080 1.0 5 ND ND 0.40 J ND ND ug/L 09/21/11 0.080 1.0 5 ND 0.51 J ND ND ug/L 03/21/12 0.13 1.0 5 ND ND ND ND ND ug/L 09/20/12 0.13 1.0 5 ND ND ND ND ND ug/L 03/20/13 0.13 1.0 5 ND ND ND 0.46 J ND ug/L 09/18/13 0.13 1.0 5 ND ND ND ND ND ug/L 03/27/14 0.13 1.0 5 ND ND ND ND ND ug/L 09/18/14 0.13 1.0 5 ND ND ND ND ND ug/L 03/18/15 0.13 1.0 5 ND ND ND ND ND ug/L 09/23/15 0.13 1.0 5 ND ND ND ND ND ug/L 03/15/16 0.13 1.0 5 ND ND ND ND ND ug/L 09/21/16 0.13 1.0 5 ND ND ND ND ND ug/L 03/21/17 0.13 1.0 5 Dry ND ND ND ND ug/L 09/20/17 0.13 1.0 5 ND ND ND ND ND ug/L 03/21/18 0.13 1.0 5 ND ND ND ND ND ug/L 09/25/18 0.13 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.13 1.0 ND ND ND ND ND ug/L 09/19/19 0.13 1.0 -- ND ND ND ND ND 1,1-Dichloroethene ug/L 03/24/09 0.24 1.0 5 ND ND ND ND ND NC 2L = 350 ug/L ug/L 09/22/09 0.24 1.0 5 ND ND ND ND ND EPA MCL = 7 ug/L ug/L 03/24/10 0.15 1.0 5 ND ND ND ND ND ug/L 09/22/10 0.24 1.0 5 ND ND ND ND ND ug/L 03/16/11 0.60 1.0 5 ND ND 3.3 J ND ND ug/L 09/21/11 0.60 1.0 5 ND ND ND ND ug/L 03/21/12 0.21 1.0 5 ND ND ND ND ND ug/L 09/20/12 0.21 1.0 5 ND ND ND ND ND ug/L 03/20/13 0.21 1.0 5 ND ND ND 3.1 J ND ug/L 09/18/13 0.21 1.0 5 ND ND ND ND ND ug/L 03/27/14 0.21 1.0 5 ND ND ND ND ND ug/L 09/18/14 0.21 1.0 5 ND ND ND ND ND ug/L 03/18/15 0.21 1.0 5 ND ND 1.7 J 2.4 J ND ug/L 09/23/15 0.21 1.0 5 ND ND ND ND ND ug/L 03/15/16 0.21 1.0 5 ND ND 1.0 J ND ND ug/L 09/21/16 0.21 1.0 5 ND ND ND ND ND ug/L 03/21/17 0.21 1.0 5 Dry ND ND ND ND ug/L 09/20/17 0.21 1.0 5 ND ND ND ND ND ug/L 03/21/18 0.21 1.0 5 ND ND ND ND ND ug/L 09/25/18 0.21 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.21 1.0 ND ND ND ND ND u /L 09/19/19 0.21 1.0 ND ND ND ND ND ;;,j� GOLDER 7of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Constituent/Parameter Limit cis-1,2-Dichloroethene ug/L 06/21/01 5.0 5.0 5 ND ND ND ND NC 2L = 70 ug/L ug/L 04/24/02 5.0 5.0 5 ND ND ND ND EPA MCL = 70 ug/L ug/L 10/01/02 5.0 5.0 5 ND ND ND ND ug/L 04/10/03 5.0 5.0 5 ND 6 ND ND ug/L 10/20/03 5.0 5.0 5 ND ND ND ND ug/L 03/24/04 -- -- 5 ND ND ND ND ug/L 10/27/04 5 ND ND ND ND ug/L 05/25/05 5 ND ND ND ND ug/L 10/05/05 5 ND ND ND ND ug/L 04/25/06 5 ND ND ND ND ug/L 10/05/06 5 ND ND ND ND ND ug/L 03/21/07 -- 5 ND ND 0.20 J ND ND ug/L 10/02/07 -- 5 ND ND 0.27 J 0.21 J ND ug/L 04/01/08 -- 5 ND ND 0.39 J 0.30 J ND ug/L 10/29/08 5 ND 0.11 J 0.44 J 0.35 J ND ug/L 03/24/09 0.36 1.0 5 ND ND ND ND ND ug/L 09/22/09 0.36 1.0 5 ND 5.7 ND ND ND ug/L 03/24/10 0.075 1.0 5 ND 5.3 ND 0.84 J ND ug/L 09/22/10 0.36 1.0 5 ND ND ND 0.78 J ND ug/L 03/16/11 0.72 1.0 5 ND ND 0.76 J 1.3 J ND ug/L 09/21/11 0.72 1.0 5 ND -- ND 1.1 J ND ug/L 03/21/12 0.15 1.0 5 ND 0.46 J 0.73 J 1.3 J ND ug/L 09/20/12 0.15 -- 5 ND ND 0.60 J 1.4 J ND ug/L 03/20/13 0.15 1.0 5 ND 0.94 J 0.86 J 1.6 J ND ug/L 09/18/13 0.15 1.0 5 ND 1.8 J 1.1 J 1.7 J ND ug/L 03/27/14 0.15 1.0 5 ND 1.2 J 0.64 J 2.3 J ND ug/L 09/18/14 0.15 1.0 5 ND ND 0.90 J 3.0 J ND ug/L 03/18/15 0.15 1.0 5 ND 0.53 J 1.6 J 2.5 J ND ug/L 09/23/15 0.15 1.0 5 ND ND 1.2 J 3.0 J ND ug/L 03/15/16 0.15 1.0 5 ND 2.4 J 1.3 J 3.6 J ND ug/L 09/21/16 0.15 1.0 5 ND 2.4 J 1.6 J 3.6 J ND ug/L 03/21/17 0.15 1.0 5 Dry 1.6 J 1.9 J 3.7 J ND ug/L 09/20/17 0.15 1.0 5 ND 1.7 J 1.4 J 3.4 J ND ug/L 03/21/18 0.15 1.0 5 ND 2.9 J 1.2 J 2.7 J ND ug/L 09/25/18 0.15 1.0 -- ND 6.7 0.76 J 2.1 ND ug/L 03/25/19 0.15 1.0 ND 4.8 1.6 3.1 ND ug/L 09/19/19 0.15 1.0 -- ND 1.3 1.7 3.0 ND Chloromethane ug/L 03/24/09 0.34 1.0 1 ND ND ND ND ND NC 2L = 3 ug/L ug/L 09/22/09 0.34 1.0 1 ND ND ND ND ND EPA MCL = No Standard ug/L 03/24/10 0.050 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.34 1.0 1 0.51 J 0.47 J 1.1 ND ND ug/L 03/16/11 0.55 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.55 1.0 1 ND ND ND ND ug/L 03/21/12 0.13 1.0 1 ND ND ND ND ND ug/L 09/20/12 0.13 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.13 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.13 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.13 1.0 1 ND ND ND ND ND ug/L 09/18/14 0.13 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.13 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.13 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.13 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.13 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.13 1.0 1 Dry ND 2.4 ND ND ug/L 09/20/17 0.13 1.0 1 ND ND 5.1 ND ND ug/L 03/21/18 0.13 1.0 1 ND ND 8.3 ND ND ug/L 09/25/18 0.13 1.0 -- ND ND 1.7 ND ND ug/L 03/25/19 0.13 1.0 ND ND ND ND ND ug/L 09/19/19 0.13 1.0 -- ND ND ND ND ND Methylene chloride ug/L 06/21/01 10.0 10.0 1 ND ND ND ND NC 2L = 5 ug/L ug/L 04/24/02 10.0 10.0 1 ND ND ND ND EPA MCL = 5 ug/L ug/L 10/01/02 10.0 10.0 1 ND ND ND ND ug/L 04/10/03 10.0 10.0 1 ND ND ND ND ug/L 10/20/03 -- -- 1 ND ND ND ND ug/L 03/24/04 1 ND ND ND ND ug/L 10/27/04 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND ND ND ug/L 04/25/06 1 ND ND ND ND -- ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 1 0.20 B ND 2.08 B 0.38 B 0.39 ug/L 10/02/07 -- 1 ND ND 1.42 B ND 0.61 ug/L 04/01/08 1 ND 0.52 B 2.83 J 0.48 B 0.54 ug/L 10/29/08 1 ND ND 2.58 0.52 J ND ug/L 03/24/09 0.53 2.0 1 ND ND 0.53 J ND ND ug/L 09/22/09 0.53 1.0 1 ND ND 1.2 ND ND ug/L 03/24/10 0.070 1.0 1 ND ND 0.92 J ND ND ug/L 09/22/10 0.53 1.0 1 ND ND 0.70 J ND ND ug/L 03/16/11 0.14 1.0 1 ND ND 1.6 0.52 J ND ug/L 09/21/11 0.14 1.0 1 ND 1.0 ND ND ug/L 03/21/12 0.23 1.0 1 ND ND 0.87 J 0.62 J ND ug/L 09/20/12 0.23 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.23 1.0 1 ND ND 1.3 ND ND ug/L 09/18/13 0.23 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.23 1.0 1 ND ND 0.59 J 0.59 J ND ug/L 09/18/14 0.23 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.23 1.0 1 ND ND ND ND ND ug/L 09/23/15 0.23 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.23 1.0 1 ND ND 0.62 J 0.59 J ND ug/L 09/21/16 0.23 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.23 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.23 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.23 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.23 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.23 1.0 ND ND ND 0.49 J ND u /L 09/19/19 0.23 1.0 ND ND ND ND ND ;;,j� GOLDER 8of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Tetrachloroethene ug/L 06/21/01 5.0 5.0 1 ND ND ND ND NC 2L = 0.7 ug/L ug/L 04/24/02 5.0 5.0 1 ND ND ND ND EPA MCL = 5 ug/L ug/L 10/01/02 5.0 5.0 1 ND ND ND ND ug/L 04/10/03 5.0 5.0 1 ND ND ND ND ug/L 10/20/03 5.0 5.0 1 ND ND ND ND ug/L 03/24/04 -- -- 1 ND ND ND ND ug/L 10/27/04 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND ND ND ug/L 04/25/06 1 ND ND ND ND ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 -- 1 ND ND 0.76 J ND ND ug/L 10/02/07 1 ND ND 1.05 J 0.27 J ND ug/L 04/01/08 1 ND 0.12 J 1.22 J 0.32 J ND ug/L 10/29/08 1 ND 0.36 J 1.21 0.33 J ND ug/L 03/24/09 0.36 1.0 1 ND 0.49 J 1.3 ND ND ug/L 09/22/09 0.36 1.0 1 ND 2.9 1.1 ND ND ug/L 03/24/10 0.099 1.0 1 ND 3.4 1.6 0.56 J ND ug/L 09/22/10 0.36 1.0 1 ND ND 1.7 ND ND ug/L 03/16/11 0.73 1.0 1 ND ND 1.4 ND ND ug/L 09/21/11 0.73 1.0 1 ND ND 0.75 J ND ug/L 03/21/12 0.17 1.0 1 ND ND 0.74 J 0.49 J ND ug/L 09/20/12 0.17 1.0 1 ND ND 0.73 J ND ND ug/L 03/20/13 0.17 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.17 1.0 1 ND 0.46 J 0.40 J ND ND ug/L 03/27/14 0.17 1.0 1 ND ND 1.2 0.5 J ND (Verification Event) ug/L 05/28/14 0.17 1.0 1 ND ND -- ND ug/L 09/18/14 0.17 1.0 1 ND ND 0.91 J 0.45 J ND ug/L 03/18/15 0.17 1.0 1 ND ND 0.46 J ND ND ug/L 09/23/15 0.17 1.0 1 ND ND 0.46 J ND ND ug/L 03/15/16 0.17 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.17 1.0 1 ND ND 0.42 J ND ND ug/L 03/21/17 0.17 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.17 1.0 1 ND ND ND 0.46 J ND ug/L 03/21/18 0.17 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.17 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.17 1.0 ND ND ND ND ND ug/L 09/19/19 0.17 1.0 -- ND ND ND ND ND Trichloroethene ug/L 06/21/01 5 5 1 ND ND ND ND NC 2L = 3 ug/L ug/L 04/24/02 5 5 1 ND ND ND ND EPA MCL = 5 ug/L ug/L 10/01/02 5 5 1 ND ND ND ND ug/L 04/10/03 -- -- 1 ND ND ND ND ug/L 10/20/03 1 ND ND ND ND ug/L 03/24/04 1 ND ND ND ND ug/L 10/27/04 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND ND ND ug/L 04/25/06 1 ND ND ND ND ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 1 ND ND 0.24 J ND ND ug/L 10/02/07 -- 1 ND ND 0.27 J 0.18 J ND ug/L 04/01/08 -- 1 ND ND 0.51 J 0.19 J ND ug/L 10/29/08 -- 1 ND ND 0.52 J 1.13 ND ug/L 03/24/09 0.38 1.0 1 ND ND 0.44 J ND ND ug/L 09/22/09 0.38 1.0 1 ND 0.64 J ND ND ND ug/L 03/24/10 0.13 1.0 1 ND 0.90 J 0.52 J ND ND ug/L 09/22/10 0.38 1.0 1 ND ND ND ND ND ug/L 03/16/11 0.72 1.0 1 ND ND ND ND ND ug/L 09/21/11 0.72 1.0 1 ND 0.82 J ND ND ug/L 03/21/12 0.15 1.0 1 ND ND 0.46 J 0.41 J ND ug/L 09/20/12 0.15 1.0 1 ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND ND ND ug/L 03/27/14 0.15 1.0 1 ND ND 0.41 J ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND 0.41 J ND ug/L 09/23/15 0.15 1.0 1 ND ND ND ND ND ug/L 03/15/16 0.15 1.0 1 ND ND ND ND ND ug/L 09/21/16 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/17 0.15 1.0 1 Dry ND ND ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.15 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.15 1.0 ND ND ND ND ND u /L 09/19/19 0.15 1.0 ND ND ND ND ND ;;,j� GOLDER 9of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Trichlorofluoromethane ug/L 06/21/01 5 5 1 ND ND ND ND NC 2L = 2000 ug/L ug/L 04/24/02 5 5 1 ND ND ND ND EPA MCL = No Standard ug/L 10/01/02 5 5 1 ND ND ND ND ug/L 04/10/03 5 5 1 ND ND ND ND ug/L 10/20/03 5 5 1 ND ND ND ND ug/L 03/24/04 5 5 1 ND ND ND ND ug/L 10/27/04 -- -- 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND 8.07 ND ug/L 04/25/06 1 ND ND ND 23.1 ug/L 10/05/06 1 ND ND 13.8 ND ND ug/L 03/21/07 1 ND ND 11.3 ND ND ug/L 10/02/07 1 ND ND 9.90 0.26 J ND ug/L 04/01/08 -- 1 ND ND 8.03 3.88 ND ug/L 10/29/08 1 ND ND 6.83 2.71 ND ug/L 03/24/09 0.28 1.0 1 ND ND 4.3 1.5 ND ug/L 09/22/09 0.28 1.0 1 ND ND 2.0 ND ND ug/L 03/24/10 0.15 1.0 1 ND ND 2.6 1.0 ND ug/L 09/22/10 0.28 1.0 1 ND ND 2.0 0.87 J ND ug/L 03/16/11 0.66 1.0 1 ND ND 1.4 2.5 ND ug/L 09/21/11 0.66 1.0 1 ND 0.82 J 1.7 ND ug/L 03/21/12 0.24 1.0 1 ND ND 0.51 J ND ND ug/L 09/20/12 0.24 1.0 1 ND ND 0.80 J 0.76 J ND ug/L 03/20/13 0.24 1.0 1 ND ND ND 1.1 ND ug/L 09/18/13 0.24 1.0 1 ND ND ND 1.3 ND ug/L 03/27/14 0.24 1.0 1 ND ND ND 3.9 ND ug/L 09/18/14 0.24 1.0 1 ND ND ND 1.6 ND ug/L 03/18/15 0.24 1.0 1 ND ND ND 1.5 ND ug/L 09/23/15 0.24 1.0 1 ND ND ND 0.77 J ND ug/L 03/15/16 0.24 1.0 1 ND ND ND 0.72 J ND ug/L 09/21/16 0.24 1.0 1 ND ND ND 0.82 J ND ug/L 03/21/17 0.24 1.0 1 Dry ND ND 0.52 J ND ug/L 09/20/17 0.24 1.0 1 ND ND ND 0.46 J ND ug/L 03/21/18 0.24 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.24 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.24 1.0 ND ND ND ND ND ug/L 09/19/19 0.24 1.0 -- ND ND ND ND ND Vinyl Chloride ug/L 06/21/01 10 10 1 ND ND ND ND NC 2L = 0.03 ug/L ug/L 04/24/02 10 10 1 ND ND ND ND EPA MCL = 2 ug/L ug/L 10/01/02 10 10 1 ND ND ND ND ug/L 04/10/03 -- -- 1 ND ND ND ND ug/L 10/20/03 1 ND ND ND ND ug/L 03/24/04 1 ND ND ND ND ug/L 10/27/04 1 ND ND ND ND ug/L 05/25/05 1 ND ND ND ND ug/L 10/05/05 1 ND ND ND ND ug/L 04/25/06 1 ND ND ND ND ug/L 10/05/06 1 ND ND ND ND ND ug/L 03/21/07 1 ND ND ND ND ND ug/L 10/02/07 -- 1 ND ND ND ND ND ug/L 04/01/08 -- 1 ND ND ND ND ND ug/L 10/29/08 -- 1 ND ND 0.56 J ND ND ug/L 03/24/09 0.30 1.0 1 ND ND ND ND ND ug/L 09/22/09 0.30 1.0 1 ND 0.55 J ND ND ND ug/L 03/24/10 0.083 1.0 1 ND ND ND ND ND ug/L 09/22/10 0.30 1.0 1 ND ND 0.42 J ND ND ug/L 03/16/11 0.60 1.0 1 ND ND ND 0.64 J ND ug/L 09/21/11 0.60 1.0 1 ND ND ND ND ug/L 03/21/12 0.32 1.0 1 ND ND 0.45 J ND ND ug/L 09/20/12 0.32 1.0 1 ND ND 0.57 J 0.56 J ND ug/L 03/20/13 0.32 1.0 1 ND 0.51 J 0.70 J 0.51 J ND ug/L 09/18/13 0.32 1.0 1 ND 0.83 J 0.79 J 0.72 J ND ug/L 03/27/14 0.32 1.0 1 ND 1.5 1.3 2.5 ND (Verification Event) ug/L 05/28/14 0.32 1.0 1 ND 0.72 J ND 1.8 ND ug/L 09/18/14 0.32 1.0 1 ND 0.97 J 0.92 J 2.0 ND ug/L 03/18/15 0.32 1.0 1 ND 0.85 J 0.86 J 2.5 ND ug/L 09/23/15 0.32 1.0 1 ND 0.78 J 1.2 2.6 ND ug/L 03/15/16 0.32 1.0 1 ND 1.3 0.98 J 2.2 ND ug/L 09/21/16 0.32 1.0 1 ND 1.5 1.3 2.5 ND ug/L 03/21/17 0.32 1.0 1 Dry 0.86 J 1.5 2.6 ND ug/L 09/20/17 0.32 1.0 1 ND 0.70 J 1.2 1.5 ND ug/L 03/21/18 0.32 1.0 1 ND ND ND ND ND ug/L 09/25/18 0.32 1.0 -- ND ND ND ND ND ug/L 03/25/19 0.32 1.0 -- ND 0.57 J 1.5 1.8 ND u /L 09/19/19 0.32 1.0 ND ND 1.3 1.9 ND ;;,j� GOLDER 10of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SwS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Xylenes (Total) ug/L 06/21/01 5 5 5 ND ND ND ND NC 2L = 500 ug/L ug/L 04/24/02 5 5 5 ND ND ND ND EPA MCL = 10000 ug/L ug/L 10/01/02 5 5 5 ND ND ND ND ug/L 04/10/03 5 5 5 ND ND ND ND ug/L 10/20/03 5 5 5 ND ND ND ND ug/L 03/24/04 -- -- 5 ND ND ND ND ug/L 10/27/04 5 ND ND ND ND ug/L 05/25/05 5 ND ND ND ND ug/L 10/05/05 5 ND ND ND ND ug/L 04/25/06 5 ND ND ND ND ug/L 10/05/06 5 ND ND ND ND ND ug/L 03/21/07 5 ND ND 0.17 J ND ND ug/L 10/02/07 5 ND ND 0.17 J ND ND ug/L 04/01/08 -- 5 ND ND 0.28 J ND ND ug/L 10/29/08 5 ND ND 0.25 J ND ND ug/L 03/24/09 0.40 1.0 5 ND ND ND ND ND ug/L 09/22/09 0.40 1.0 5 ND 0.72 J ND ND ND ug/L 03/24/10 0.22 1.0 5 ND 0.62 J ND ND ND ug/L 09/22/10 0.40 1.0 5 ND ND ND ND ND ug/L 03/16/11 2.1 3.0 5 ND ND ND ND ND ug/L 09/21/11 2.1 3.0 5 ND ND ND ND ug/L 03/21/12 0.45 3.0 5 ND ND ND ND ND ug/L 09/20/12 0.45 3.0 5 ND ND ND ND ND ug/L 03/20/13 0.45 3.0 5 ND ND ND ND ND ug/L 09/18/13 0.45 3.0 5 ND ND ND ND ND ug/L 03/27/14 0.45 3.0 5 ND ND ND ND ND ug/L 09/18/14 0.45 3.0 5 ND ND ND ND ND ug/L 03/18/15 0.45 3.0 5 ND ND ND ND ND ug/L 09/23/15 0.45 3.0 5 ND ND ND ND ND ug/L 03/15/16 0.45 3.0 5 ND ND ND ND ND ug/L 09/21/16 0.45 3.0 5 ND ND ND ND ND ug/L 03/21/17 0.45 3.0 5 Dry ND ND ND ND ug/L 09/20/17 0.45 3.0 5 ND ND ND ND ND ug/L 03/21/18 0.45 3.0 5 ND ND ND ND ND ug/L 09/25/18 0.45 3.0 -- ND ND ND ND ND ug/L 03/25/19 0.45 3.0 -- ND ND ND ND ND ug/L 09/19/19 0.45 3.0 ND ND ND ND ND 1,4-Dioxane ug/L 09/25/18 1.2 2.0 ND ND 3.3 1.9 J ND NC 2L = 3 ug/L ug/L 03/25/19 1.2 2.0 -- ND ND 8.7 1.9 J ND ug/L 09/19/19 1.2 2.0 ND ND 10 2.3 ND Tetrahydrofuran ug/L 03/16/11 0.80 1.0 ND ND 74 7.6 ND NC 2L = No Standard ug/L 09/21/11 0.80 1.0 ND 39 8.2 ND EPA MCL = No Standard ug/L 03/21/12 0.80 1.0 ND ND 28 17 ND ug/L 09/20/12 0.80 1.0 ND ND 22 9.1 ND ug/L 03/20/13 0.80 1.0 ND ND 34 B 9.0 B 21 ug/L 09/18/13 0.80 1.0 ND 11 13 3.6 ND ug/L 03/27/14 0.80 1.0 ND 200 ND 8.0 ND ug/L 09/18/14 0.80 1.0 ND 21 ND 9.5 ND ug/L 03/18/15 0.80 1.0 ND 9.8 6.3 6.8 ND ug/L 09/23/15 0.80 1.0 ND 99 6.4 10 ND ug/L 03/15/16 0.80 1.0 ND 50 4.9 14 ND ug/L 09/21/16 0.80 1.0 ND ND 13 14 ND ug/L 03/21/17 0.80 1.0 Dry 48 14 9.4 ND ug/L 09/20/17 0.80 1.0 ND 9.9 4.8 5.7 ND ug/L 09/25/18 0.53 1.0 ND ND ND ND ND ug/L 09/25/18 0.53 1.0 ND ND ND ND ND ug/L 03/25/19 0.53 1.0 ND ND 12 ND ND ug/L 09/19/19 0.53 1.0 ND ND 32 2.1 ND ug/L 03/21/18 0.80 1.0 -- ND ND ND 5.8 ND 2,4-D ug/L 03/21/12 0.16 0.50 2 ND ND ND 0.80 J ND NC 2L = 70 ug/L ug/L 09/20/12 0.16 0.50 2 ND ND ND ND ND EPA MCL = 70 ug/L ug/L 03/20/13 0.16 0.50 2 ND ND ND 1.1 J ND ug/L 09/18/13 0.16 0.50 2 ND ND ND 1.3 J ND ug/L 03/27/14 0.27 0.50 2 ND ND ND 1.0 J ND ug/L 09/18/14 0.27 0.50 2 ND ND ND 0.85 J ND ug/L 03/18/15 0.27 0.50 2 ND ND ND 0.82 J ND ug/L 09/23/15 0.27 0.50 2 ND ND ND 0.54 J ND ug/L 03/15/16 0.27 0.50 2 ND ND ND ND ND ug/L 09/21/16 0.27 0.50 2 ND ND ND ND ND ug/L 03/21/17 0.27 0.50 2 Dry ND ND ND ND ug/L 09/20/17 0.27 0.50 2 ND ND ND ND ND ug/L 03/21/18 0.27 0.50 2 ND ND ND ND ND ug/L 09/25/18 0.27 0.50 -- ND ND ND ND ND ug/L 03/25/19 0.27 0.50 ND ND ND 1.0 ND ug/L 09/19/19 0.27 0.50 ND ND ND ND ND Chloride mg/L 03/24/09 1.9 5.0 ND 8.8 4.1 J ND ND NC 2L = 250 mg/L mg/L 09/22/09 0.018 5.0 3.1 J 8.1 8.7 3.6 J ND EPA MCL = 250 mg/L mg/L 03/24/10 1.2 5.0 ND 1.7 J 7.3 2.5 J ND mg/L 09/22/10 0.018 5.0 3 J 4.7 J 4.8 J 5.1 ND mg/L 03/16/11 0.047 5.0 3 J ND J 8.6 4.8 J ND mg/L 09/21/11 0.047 5.0 2.6 B -- 17 4.4 B 1.5 J mg/L 03/21/12 0.43 5.0 2.3 B 4.2 B 18 4.6 B 1.2 J mg/L 09/20/12 0.43 5.0 2.6 B 6.3 B 16 6.3 B 1.5 mg/L 03/20/13 0.43 5.0 2.6 B 6.6 B 14 7.3 B 1.5 mg/L 09/18/13 2.2 5.0 2.4 J 5.0 13 5.9 ND mg/L 03/27/14 2.2 5.0 2.4 J 23 3.7 J 5.2 ND mg/L 09/18/14 2.2 5.0 2.6 J 8.9 3.1 J 5.4 ND mg/L 03/18/15 2.2 5.0 2.3 J 60 19 5.6 ND mg/L 09/23/15 2.2 5.0 2.6 J 20 15 5.8 ND mg/L 03/15/16 2.2 5.0 ND 14 10 5.1 ND mg/L 09/21/16 2.2 5.0 ND 32 18 5.5 ND mg/L 03/21/17 2.2 5.0 Dry 45 27 6.0 ND mg/L 09/20/17 2.2 5.0 ND 110 19 6.7 ND mg/L 03/21/18 2.2 5.0 ND 13 27 7.0 ND mg/L 09/25/18 2.2 5.0 ND 9.3 15.0 7.0 ND mg/L 03/25/19 2.2 5.0 ND 14 41 7.7 ND mg/L 09/19/19 2.2 5 ND 12 47 7.7 ND ;;,j� GOLDER 11of12 January 2020 TABLE 8 19128179 Summary of Detected Constituents in C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Henderson County, North Carolina Detected Monitoring SWS Upgradient Well Downgradient Wells Constituent/Parameter Units Date MDL PQL Reporting Blanks MW-10 MW-11 MW-12 MW-13 Limit Total Dissolved Solids mg/L 03/24/09 10 10 86 310 190 140 ND NC 2L = 500 mg/L mg/L 09/22/09 10 10 66 280 160 130 ND EPA MCL = 500 mg/L mg/L 03/24/10 10 10 22 110 170 140 ND mg/L 09/22/10 10 10 40 110 160 190 ND mg/L 03/16/11 10 10 46 ND 160 120 ND mg/L 09/21/11 10 10 16 200 140 ND mg/L 03/21/12 10 10 18 190 190 140 ND mg/L 09/20/12 10 10 200 170 120 110 ND mg/L 03/20/13 10 10 46 270 260 260 ND mg/L 09/18/13 10 10 ND 110 180 180 ND mg/L 03/27/14 10 10 ND 300 110 170 ND mg/L 09/18/14 10 10 ND 180 98 180 ND mg/L 03/18/15 10 10 38 330 210 150 ND mg/L 09/23/15 10 10 ND 400 190 160 ND mg/L 03/15/16 10 10 ND 360 190 170 ND mg/L 09/21/16 10 10 ND 720 150 120 ND mg/L 03/21/17 10 10 Dry 970 320 200 ND mg/L 09/20/17 10 50 ND 1000 270 210 ND mg/L 03/21/18 10 50 ND 540 210 170 ND mg/L 09/25/18 50 50 ND 390 160 140 ND mg/L 03/25/19 50 50 ND 750 390 200 ND m /L 09/19/19 50 50 ND 570 510 240 ND Sulfate as SO4 mg/L 03/24/09 0.078 5.0 250 1.5 J 150 J 18 J 3.0 J ND NC 2L = 250 mg/L mg/L 09/22/09 0.078 5.0 250 1.7 J 100 J 17 J 3.9 J ND EPA MCL = 250 mg/L mg/L 03/24/10 0.12 5.0 250 ND 5.3 J 16 J 2.1 J ND mg/L 09/22/10 0.12 5.0 250 ND 4.8 J 5.4 J 4.9 J ND mg/L 03/16/11 0.02 5.0 250 1.9 J ND J 7.3 J 3.9 J ND mg/L 09/21/11 0.02 5.0 250 1.7 B 14 J 4.2 B 1.7 J mg/L 03/21/12 0.04 5.0 250 1.5 J 46 J 18 J 6.3 J ND mg/L 09/20/12 0.04 5.0 250 1.9 J 66 J 18 J 9.9 J ND mg/L 03/20/13 0.04 5.0 250 1.6 J 32 J 16 J 12 J ND mg/L 09/18/13 0.04 5.0 250 1.60 B 18.0 J 14.0 J 15.0 J 1.50 J mg/L 03/27/14 2.9 5.0 250 ND 83.0 J ND 14.0 J ND mg/L 09/18/14 2.9 5.0 250 ND 49 J ND 16 J ND mg/L 03/18/15 2.9 5.0 250 ND 78 J 25 J 17 J ND mg/L 09/23/15 2.9 5.0 250 ND 73 J 22 J 19 J ND mg/L 03/15/16 2.9 5.0 250 ND 98 J 14 J 17 J ND mg/L 09/21/16 2.9 5.0 250 ND 250 18 J 18 J ND mg/L 03/21/17 2.9 5.0 250 Dry 310 31 J 20 J ND mg/L 09/20/17 2.9 5.0 250 ND 460 27 J 24 J ND mg/L 03/21/18 2.9 5.0 250 ND 160 J 14 J 23 J ND mg/L 09/25/18 2.9 5.0 ND 96 16 20 ND mg/L 03/25/19 2.9 5.0 ND 190 46 19 ND m /L 09/19/19 2.9 5.0 ND 140 54 18 ND Total Alkalinity mg/L 03/24/09 8.3 15 17 18 80 65 ND NC 2L = No Standard mg/L 09/22/09 8.3 15 12 J 41 76 68 ND EPA MCL = No Standard mg/L 03/24/10 8.0 15 9.6 J 57 76 75 ND mg/L 09/22/10 8 15 ND 46 86 100 ND mg/L 03/16/11 12 15 ND ND 94 96 ND mg/L 09/21/11 12 15 ND 90 90 ND mg/L 03/21/12 12 15 14 J 51 87 100 ND mg/L 09/20/12 12 15 19 53 86 100 ND mg/L 03/20/13 12 15 15 69 96 110 ND mg/L 09/18/13 14 15 ND 77.0 110 110 ND mg/L 03/27/14 14 15 ND 84.0 94.0 110 ND mg/L 09/18/14 14 15 ND 96 83 110 ND mg/L 03/18/15 14 15 14 J 120 130 120 ND mg/L 09/23/15 14 15 16 260 140 120 ND mg/L 03/15/16 14 15 19 160 130 120 ND mg/L 09/21/16 14 15 ND 350 150 120 ND mg/L 03/21/17 14 15 Dry 370 170 120 ND mg/L 09/20/17 14 75 ND 330 170 120 ND mg/L 03/21/18 14 15 ND 240 140 110 ND mg/L 09/25/18 14 15 ND 230 160 120 ND mg/L 03/25/19 14 15 ND 370 190 130 ND m /L 09/19/19 14 15 ND 300 280 140 ND Notes: ug/L = micrograms per liter mg/L = milligrams per liter ND = Not detected at the stated reporting limit J = The March 2019 event, J flags are estimated values between the MDL and PQL. Prior to the November B = Blank -qualified result = no data available #= EPA Action Level = EPA Secondary MCL MDL = laboratory method detection limit PQL = practical quantitation limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007, ending in July 2018 EPA MCL = US Environmental Protection Agency Maximum Contaminant Level NC 2L = North Carolina 2L Groundwater Standard IMAC = Interim Maximum Allowable Concentration (under NC 2L Rules) 1) Historical data prior to March 2009 provided by Henderson County and CDM. 2) The following dilutions were noted for the September 2019 event: antimony and thallium in MW-10, MW-11, MW-12, and MW-13 (2x); MW-11 sulfate (4x) and Alkalinity (2x), MW-12 Alkalinity (2x). ;;,j� GOLDER 12of12 January 2020 TABLE 9 Summary of Field Parameters for C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Detected Monitoring Units Date Upgradient Well Downgradient Wells MW-10 MW-11 MW-12 MW-13 Constituent/Parameter pH (field) S.U. 03/21/07 5.23 5.29 5.52 5.78 S.U. 03/24/09 6.78 6.22 6.46 6.84 S.U. 09/22/09 7.37 5.41 5.59 5.90 S.U. 03/24/10 7.47 5.64 5.90 6.61 S.U. 09/22/10 5.80 5.27 5.39 5.81 S.U. 03/16/11 5.58 5.48 5.52 5.65 S.U. 09/21/11 5.92 -- 5.38 5.87 S.U. 03/21/12 6.75 5.18 5.47 5.89 S.U. 09/20/12 6.34 5.72 5.07 6.16 S.U. 03/20/13 5.86 5.37 5.63 5.73 S.U. 09/18/13 5.83 5.40 5.76 6.06 S.U. 03/26/14 4.65 5.42 4.94 6.03 (Verification Event) S.U. 05/28/14 -- 5.46 5.96 6.12 S.U. 09/18/14 7.11 5.30 5.75 6.66 S.U. 03/18/15 6.31 5.27 5.70 5.73 S.U. 09/24/15 5.73 5.72 5.67 5.68 S.U. 03/15/16 4.86 5.58 5.45 5.48 S.U. 09/21/16 6.04 6.56 5.99 5.77 S.U. 03/21/17 Dry 5.87 5.55 5.41 S.U. 09/20/17 5.45 5.88 5.83 5.75 S.U. 03/21/18 5.69 6.12 5.92 5.85 S.U. 09/25/18 5.56 5.89 5.76 5.67 S.U. 03/25/19 5.51 6.10 5.93 5.76 S.U. 09/19/19 4.46 5.97 5.90 5.72 Specific Conductivity (field) PS/cm 03/21/07 35 73 135 87 PS/cm 03/24/09 50 450 150 230 PS/cm 09/22/09 58 404 240 156 PS/cm 03/24/10 42 170 249 191 PS/cm 09/22/10 37 144 230 316 PS/cm 03/16/11 46 138 256 220 PS/cm 09/21/11 44 -- 272 207 PS/cm 03/21/12 22 188 292 219 PS/cm 09/20/12 44 262 218 215 PS/cm 03/20/13 36 213 252 215 PS/cm 09/18/13 39 227 309 283 PS/cm 03/18/14 40 1034 367 277 PS/cm 03/26/14 54 493 227 310 (Verification Event) pS/cm 05/28/14 -- 430 211 307 PS/cm 09/18/14 63 407 221 318 PS/cm 09/24/15 36 691 318 259 PS/cm 03/15/16 42 749 324 295 PS/cm 09/21/16 32 1040 342 272 PS/cm 03/21/17 Dry 1167 405 264 PS/cm 09/20/17 88 1449 400 301 PS/cm 03/21/18 47 777 409 301 PS/cm 09/25/18 37 748 389 310 PS/cm 03/25/19 31 1148 614 320 PS/cm 09/19/19 31 845 784 348 Temperature (field) Celsius 03/21/07 14.1 15.5 13.5 13.1 Celsius 03/24/09 16.0 14.7 14.1 15.8 Celsius 09/22/09 15.68 15.92 14.99 14.90 Celsius 03/24/10 13.36 14.12 13.13 12.31 Celsius 09/22/10 15.22 15.42 14.36 14.61 Celsius 03/16/11 12.28 13.51 12.90 12.73 Celsius 09/21/11 13.97 -- 15.20 14.38 Celsius 03/21/12 14.35 17.52 15.18 16.65 Celsius 09/20/12 14.15 17.47 14.45 13.97 Celsius 03/20/13 9.27 13.86 12.44 13.00 Celsius 09/18/13 13.8 18.9 14.6 14.3 Celsius 03/26/14 11.5 14.8 13.8 13.5 (Verification Event) Celsius 05/28/14 -- 16.9 18.6 17.2 Celsius 09/18/14 13.9 21.9 14.9 14.5 Celsius 03/18/15 14.2 14.2 14.4 13.6 Celsius 09/24/15 15.04 16.58 15.18 15.62 Celsius 03/15/16 15.3 15.5 14.4 14.9 Celsius 09/21/16 16.1 17.1 17.0 15.3 Celsius 03/21/17 Dry 15.4 14.5 14.5 Celsius 09/20/17 22.2 22.1 18.0 19.4 Celsius 03/21/18 9.9 13.4 13.4 12.4 Celsius 09/25/18 16.4 19.9 16.7 16.9 Celsius 03/25/19 13.6 15.8 13.8 12.9 Celsius 09/19/19 14.4 17.8 15.7 15.4 19128179 GOLDER 1of2 January 2020 19128179 TABLE 9 Summary of Field Parameters for C&D Monitoring Wells Henderson County Closed C&D Landfill, Permit No. 45-01 Detected Monitoring Upgradient Well Downgradient Wells Constituent/Parameter Units Date MW-10 MW-11 MW-12 MW-13 Turbidity (field) NTU 03/24/09 76.2 13.8 149 108 NTU 09/22/09 20.1 20.4 61.3 37.3 NTU 03/24/10 6.36 16.6 51.1 19.7 NTU 09/22/10 8.46 5.45 10.3 24.2 NTU 03/16/11 21.6 12.1 36.1 17.6 NTU 09/21/11 14.6 -- 27.6 26.4 NTU 03/21/12 45.0 45.8 13.5 27.5 NTU 09/20/12 42.3 35.0 32.4 25.2 NTU 03/20/13 4.86 11.9 12.2 20.4 NTU 09/18/13 >1000 26.5 47.1 81.5 NTU 03/26/14 4.60 15.5 1.93 2.55 (Verification Event) NTU 05/28/14 -- 13.0 44.6 121 NTU 09/18/14 1.78 8.31 1.01 16.0 NTU 03/18/15 14.20 46.90 43.2 11.7 NTU 09/24/15 17.6 3.7 19.7 17.2 NTU 03/15/16 7.53 2.91 1.44 0.38 NTU 09/21/16 1.70 2.09 2.12 2.17 NTU 03/21/17 Dry 4.36 1.54 0.87 NTU 09/20/17 8.49 7.09 0.38 0.25 NTU 03/21/18 0.71 6.34 1.41 0.96 NTU 09/25/18 1.89 5.64 3.74 1.36 NTU 03/25/19 1.48 2.28 1.16 0.44 NTU 09/19/19 0.39 0.00 2.16 1.62 Oxidation Reduction Potential (field) mV 9/18/2013 -- 49.2 -- -- mV 03/27/14 -146 mV 09/18/14 70.6 mV 03/18/15 107 -- -- mV 09/24/15 95.8 72.0 99.3 91.0 mV 03/15/16 247 115 200 66.1 mV 03/21/17 Dry -80.4 -204 -73.0 mV 09/20/17 123 7.70 111 -65.5 mV 03/21/18 308 57.5 288 110 mV 09/25/18 206 -102 94 -42 mV 03/25/19 420 -42 384 130 mV 09/19/19 167 -58 37 -91 Dissolved Oxygen (field) mg/L 09/18/13 -- 0.33 -- -- mg/L 03/27/14 0.24 mg/L 09/18/14 0.55 mg/L 03/18/15 0.44 -- -- mg/L 09/24/15 7.31 0.40 1.48 1.20 mg/L 03/15/16 6.47 0.08 0.42 0.16 mg/L 09/21/16 8.22 0.33 1.38 1.10 mg/L 03/21/17 Dry 0.60 0.63 0.54 mg/L 09/20/17 7.42 3.06 0.50 0.42 mg/L 03/21/18 4.53 0.36 0.40 0.39 mg/L 09/25/18 6.03 0.09 0.79 0.55 mg/L 03/25/19 7.80 0.13 0.80 0.29 mg/L 09/19/19 8.42 0.21 1.28 0.55 Notes: NTU = Nephelometric Turbidity Units uS/cm = microsiemens per centimeter S.U. = Standard Units -- = no data available 1) Historical data prior to March 2009 provided by Henderson County and CDM. GOLDER 2of2 January 2020 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring SWS Background Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-1D AMW-2D MW-2 BR-3 Sulfide mg/L 0.031 0.1 09/24/09 1 ND 0.28 J ND ND 0.48 J -- ND mg/L 0.031 0.1 03/23/10 1 -- -- 0.043 J ND mg/L 0.01 0.1 09/24/15 1 ND 0.12 J NO ND NO ND ND -- ND mg/L 0.01 0.1 03/15/16 1 ND 0.30 J ND ND 0.360 J ND ND ND mg/L 0.01 0.1 09/21/16 1 ND ND NO ND NO ND ND ND mg/L 0.01 0.1 03/21/17 1 ND 0.098 J ND ND NO ND NO ND mg/L 0.01 0.1 09/20/17 1 -- -- -- -- -- -- -- -- -- -- -- mg/L 0.01 0.1 03/21/18 1 ND 0.69 J ND ND ND mg/L 0.01 0.1 09/18/19 -- ND ND NO ND NO ND ND ND Chloride mg/L 0.018 5 09/24/09 1 5.3 3.0 J 22 32 7.8 -- ND mg/L 1.2 5 03/23/10 1 -- -- -- mg/L 2.2 5 09/24/15 1 4.3 J 0.18 J 39 5.8 4.3 J 14 16 -- ND mg/L 2.2 5 03/15/16 1 5.4 57 99 32 18 11 15 ND mg/L 2.2 5 09/21/16 1 6.1 190 67 19 23 12 19 ND mg/L 2.2 5 03/21/17 1 5.2 180 49 42 8.8 14 20 ND mg/L 2.2 5 09/20/17 1 5.8 4.7 J 53 30 14 14 21 ND mg/L 2.2 5 03/21/18 -- 8.5 3.2 J 57 57 62 14 21 ND mg/L 2.2 5 09/24/18 4.4 54 95 24 44 14 22 ND mg/L 2.2 5 03/25/19 7.0 12 100 33 58 13 24 ND mg/L 2.2 5 09/18/19 -- 5.3 190 J 76 33 16 13 25 ND Nitrate as N mg/L 0.0056 0.1 09/24/09 10 3.9 J ND NO 0.055 J -- -- 0.017 J mg/L 0.021 0.1 03/23/10 10 -- -- -- -- -- ND mg/L 0.025 0.1 09/24/15 10 3.0 J 0.062 J ND 0.096 J 0.29 J ND 0.110 J NO mg/L 0.025 0.1 03/15/16 10 10 0.064 J ND ND 1.3 J ND ND ND mg/L 0.025 0.1 09/21/16 10 6.2 J 0.11 J ND 0.069 J 0.5 J ND 1.3 J NO mg/L 0.025 0.1 03/21/17 10 1.0 J 0.19 J ND 0.18 J 1.3 J ND 0.15 J ND mg/L 0.025 0.1 09/20/17 10 2.7 J 0.069 J ND 0.12 J 0.7 J ND 0.66 J NO mg/L 0.025 0.1 03/21/18 10 6.1 J 0.11 J ND 0.16 J 0.76 J ND 0.092 J ND mg/L 0.025 0.1 09/24/18 -- 2.9 0.16 0.083 J 0.16 0.29 0.051 J 2.0 ND mg/L 0.025 0.1 03/25/19 1.0 ND ND 0.074 J 0.34 ND 0.067 J ND mg/L 0.025 0.1 09/18/19 -- 0.95 0.14 0.056 J 0.20 0.31 0.070 J 0.86 ND Nitrite as N mg/L 0.0056 0.1 09/24/09 1 0.0095 B 0.011 B 0.0062 B 0.013 B -- -- 0.0095 B -- 0.0086 J mg/L 0.0056 0.1 03/23/10 1 -- -- -- mg/L 0.017 0.1 09/24/15 1 ND ND ND ND ND ND ND -- ND mg/L 0.017 0.1 03/15/16 1 ND ND ND ND NO ND ND ND mg/L 0.017 0.1 03/21/17 1 ND ND ND ND ND NO ND ND mg/L 0.017 0.1 09/20/17 1 ND ND NO ND NO ND ND ND mg/L 0.017 0.1 03/21/18 1 ND ND ND ND ND NO ND ND mg/L 0.017 0.1 09/24/18 -- ND ND NO ND NO ND ND ND mg/L 0.017 0.1 03/25/19 ND 0.045 J 0.033 J ND ND NO 0.028 J ND mg/L 0.017 0.1 09/18/19 -- ND ND NO ND NO ND 0.045 J ND Sulfate mg/L 0.078 5 09/24/09 250 3.2 J 7.3 J 4.8 J 6.3 J 2.6 J -- ND mg/L 0.12 5 03/23/10 250 -- -- -- mg/L 0.07 5 09/24/15 250 21 J ND 2.7 J 18 J 9.1 J 0.62 J 1.8 J -- ND mg/L 2.9 5 03/15/16 250 27 J 8.2 J 3.3 J 10 J 14 J ND 4.2 J NO mg/L 2.9 5 09/21/16 250 27 J ND 3.5 J 8 J 17 J ND 3.8 J ND mg/L 2.9 5 03/21/17 250 12 J ND 3.3 J 13 J 26 J ND 3.8 J NO mg/L 2.9 5 09/20/17 250 18 J ND ND 13 J 22 J ND 3.1 J NO mg/L 2.9 5 03/21/18 250 36 J 5.0 J NO 6.9 J 8.9 J ND 3.0 J NO mg/L 2.9 5 09/24/18 -- 38 ND ND 6.5 11 ND 3.4 J ND mg/L 2.9 5 03/25/19 83 3.7 J NO 13 8.8 ND 3.3 J NO mg/L 2.9 5 09/18/19 40 ND ND 13 24 ND 3.7 J ND Biochemical Oxygen Demand mg/L 10 10 09/24/15 ND 3.9 NO ND NO ND ND ND mg/L 2 2 03/15/16 ND 4.3 NO ND ND ND ND ND mg/L 2 2 09/21/16 ND 4.6 NO ND NO ND NO ND mg/L 2 2 03/21/17 ND 6.4 ND ND NO ND ND ND mg/L 2 2 09/18/19 ND 6.2 ND 2.0 ND ND 2.1 ND Chemical Oxygen Demand mg/L 10 10 09/24/15 15 140 28 130 38 19 25 ND mg/L 10 10 03/15/16 10 39 48 95 22 ND ND ND mg/L 10 10 09/21/16 ND 110 37 93 18 12 14 ND mg/L 10 10 03/21/17 ND 110 26 110 45 20 22 ND mg/L 10 10 09/18/19 11 1 130 32 68 ND ND 83 ND ..,> GOL❑ER 1 of 5 January 2020 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring SWS Background Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-1D AMW-2D MW-2 BR-3 Total Alkalinity mg/L 8.3 15 09/24/09 ND 21 160 200 150 -- ND mg/L 8.0 15 03/23/10 -- -- -- -- -- -- -- 150 NO mg/L 14 15 09/24/15 30 670 220 400 250 120 120 -- -- -- -- -- ND mg/L 14 15 03/15/16 17 190 300 460 72 94 81 260 300 59 88 180 NO mg/L 14 15 06/29/16 -- -- 100 310 -- -- 82 mg/L 14 15 09/21/16 15 530 270 550 38 98 120 25 310 53 78 NO mg/L 14 15 12/19/16 -- -- 44 260 -- 73 mg/L 14 15 03/21/17 19 470 250 350 83 110 140 55 240 58 85 NO mg/L 14 15 06/21/17 -- -- 79 290 -- 83 ND mg/L 14 15 09/20/17 ND 130 230 510 29 97 140 23 260 59 -- 86 NO mg/L 14 15 12/19/17 -- 25 280 61 190 85 ND mg/L 14 15 03/21/18 ND 91 230 520 18 100 130 42 270 59 -- 75 NO mg/L 14 15 06/15/18 -- 27 270 70 200 82 ND mg/L 14 15 09/24/18 ND 170 280 510 30 100 130 22 240 60 -- 86 NO mg/L 14 15 12/20/18 -- 74 260 67 180 ND mg/L 14 15 03/25/19 ND 79 230 320 NO 81 130 65 190 59 -- 84 NO m /L 14 15 09/18/19 16 170 270 480 ND 78 160 -- -- -- -- ND Total Organic Carbon mg/L 0.34 1 09/24/09 0.64 J 10 3.4 18 -- 32 -- NO mg/L 0.34 1 03/23/10 -- -- mg/L 0.34 1 09/24/15 0.47 J 33 3.0 39 6.1 1.70 6.5 -- NO mg/L 0.34 1 03/15/16 0.600 J 7.0 10 28 1.9 0.870 J 2.0 ND mg/L 0.34 1 09/21/16 88 J 24 5.4 26 1.6 1.3 2.7 NO mg/L 0.34 1 03/21/17 0.35 J 21 2.9 34 2.4 1.5 2.7 ND mg/L 0.34 1 09/18/19 6.4 130 45 80 23 11 46 NO Ethane mg/L 0.0004 0.002 09/24/09 ND ND ND ND -- -- ND ND mg/L 0.0004 0.002 03/23/10 NO NO mg/L 0.00047 0.002 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.00047 0.002 03/15/16 ND ND NO ND NO NO NO NO mg/L 0.0013 0.002 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.0013 0.002 03/21/17 ND ND NO ND NO ND NO NO mg/L 0.0013 0.002 09/20/17 ND ND ND ND ND ND ND ND mg/L 0.0013 0.002 03/21/18 ND ND NO ND NO ND NO NO mg/L 0.0013 0.002 09/24/18 ND ND ND ND ND ND ND ND mg/L 0.0013 0.002 03/25/19 ND ND NO ND NO ND NO NO m /L 0.0013 0.002 09/18/19 ND ND ND ND ND ND ND ND Ethane mg/L 0.0004 0.002 09/24/09 ND ND NO ND NO NO mg/L 0.0004 0.002 03/23/10 -- -- -- -- -- -- -- --ND-- ND mg/L 0.00062 0.003 09/24/15 ND ND NO ND NO NO NO NO mg/L 0.00062 0.003 03/15/16 ND ND ND ND ND ND ND ND mg/L 0.0015 0.003 09/21/16 ND ND NO ND NO NO NO NO mg/L 0.0015 0.003 03/21/17 ND ND ND ND ND ND ND ND mg/L 0.0015 0.003 09/20/17 ND ND NO ND NO ND NO NO mg/L 0.0015 0.003 03/21/18 ND ND ND ND ND ND ND ND mg/L 0.0015 0.003 09/24/18 ND ND NO ND NO NO NO NO mg/L 0.0015 0.003 03/25/19 ND ND ND ND ND ND ND ND mg/L 0.0015 0.003 09/18/19 ND ND NO NO NO NO NO NO Methane mg/L 0.0002 0.001 09/24/09 0.002 0.640 0.654 1.45 3.91 -- ND mg/L 0.0002 0.001 03/23/10 -- -- -- -- -- -- -- 0.232 NO mg/L 0.00044 0.001 09/24/15 ND 4.14 0.078 0.165 0.563 0.16 0.003 -- ND mg/L 0.00044 0.001 03/15/16 0.000516 J 8.5 0.418 0.150 0.0700 0.0910 0.021 NO mg/L 0.00044 0.001 09/21/16 ND 3.71 0.0819 0.17 0.0167 0.093 0.253 ND mg/L 0.00044 0.001 03/21/17 ND 2.1 0.128 0.136 0.122 0.246 0.061 NO mg/L 0.00044 0.001 09/20/17 0.000995 J 2.28 0.126 0.0737 0.057 0.143 0.0457 ND mg/L 0.00044 0.001 03/21/18 0.025 2.83 0.0843 0.190 0.0152 0.117 0.0392 NO mg/L 0.00045 0.001 09/24/18 0.028 3.16 0.1990 0.118 0.0240 0.168 0.0540 ND mg/L 0.00045 0.001 03/25/19 0.002 2.82 0.282 0.190 0.00156 ND 0.139 NO m /L 0.00045 0.001 09/18/19 0.00156 1.40 0.136 0.231 0.00526 0.0565 0.0539 ND Carbon dioxide mg/L 0.780 2.50 09/24/09 60.7 105 689 641 -- -- 181 -- NO mg/L 0.780 2.50 03/23/10 -- -- -- -- -- -- -- -- -- --181-- ND mg/L 0.210 2.50 09/24/15 92.3 927 649 861 487 293 469 -- NO mg/L 0.210 2.50 03/15/16 117 841 795 790 249 220 338 ND mg/L 0.66 2.50 09/21/16 74 731 542 699 111 155 413 NO mg/L 0.66 2.50 03/21/17 50.5 376 603 949 260 213 184 ND mg/L 0.66 2.50 09/20/17 67.4 176 643 793 179 186 323 NO mg/L 0.66 2.50 03/21/18 88.9 257 646 706 147 205 212 ND mg/L 1.62 5.25 09/24/18 90.8 523 558 521 166 200 300 NO mg/L 0.77 2.50 03/25/19 165 321 480 583 171 180 290 ND mg/L 0.77 2.50 09/18/19 74.1 482 517 465 209 170 1110 NO .,,> GOL❑ER 2of5 January 2020 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 SWS Background Detected Monitoring Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 pH (field) S.U. 09/24/09 5.58 5.32 5.60 5.72 5.93 5.91 6.27 -- 7.06 S.U. 03/23/10 5.58 Dry 5.44 6.01 -- -- -- -- -- 5.87 -- S.U. 09/24/15 5.63 6.19 5.95 5.96 6.03 5.94 5.71 -- 6.09 6.39 -- 7.13 S.U. 03/15/16 5.15 5.43 5.98 6.08 5.48 5.73 5.35 5.77 5.94 5.83 6.03 6.54 S.U. 06/29/16 -- -- -- -- -- -- -- 6.12 5.84 5.86 5.86 6.40 S.U. 09/21/16 4.74 6.21 6.10 6.12 5.67 6.28 5.68 6.21 6.19 6.53 -- 6.64 S.U. 12/19/16 -- 6.28 -- -- -- -- -- 7.60 6.07 6.22 5.97 5.91 S.U. 03/21/17 5.20 6.03 5.73 5.95 5.55 5.67 5.97 9.70 5.88 5.97 -- 6.86 S.U. 06/21/17 -- 5.64 -- -- -- -- -- 9.10 5.91 5.92 5.95 6.09 S.U. 09/20/17 5.78 5.58 5.96 6.17 5.37 6.00 5.43 6.81 6.02 6.33 -- 6.89 S.U. 12/19/17 -- 5.99 -- -- -- -- -- 6.83 6,07 5.94 6.17 6.23 S.U. 03/21/18 5.63 5.90 6.05 6.84 5.94 6.52 6.34 8.73 6.53 6.65 -- 7.37 S.U. 06/15/18 -- -- -- -- -- -- -- 6.71 6.06 6.12 6.12 6.59 S.U. 09/25/18 5.60 5.80 5.95 6.32 5.60 6.03 5.99 8.42 7.74 5.71 -- 6.62 S.U. 12/20/18 -- -- -- -- -- -- -- 9.96 6.06 6.12 6.18 7.74 S.U. 03/25/19 5.63 5.98 6.01 6.04 5.28 6.06 6.17 10.35 6.18 6.13 -- 6.93 ND S.U. 09/18/19 4.77 6.03 5.79 6.35 4.8 6.23 5.94 -- 5.9 6.32 7.06 Specific Conductivity (field) us/cm 09/24/09 101 125 340 661 -- -- 374 675 111 -- 1328 us/cm 03/23/10 148 Dry 339 884 -- -- -- -- -- 289 -- us/cm 09/24/15 128 1876 562 911 558 262 307 -- 634 120 -- 2455 us/cm 03/15/16 228 389 790 967 264 219 236 692 764 152 366 1587 us/cm 06/29/16 -- -- -- -- -- -- -- 77 740 151 367 2090 us/cm 09/21/16 180 1640 659 1140 192 200 306 78 703 144 -- 1990 us/cm 12/19/16 -- 1352 -- -- -- -- -- 118 606 133 306 6445 us/cm 03/21/17 100 1342 601 960 273 240 331 150 597 143 -- 6161 us/cm 06/21/17 -- 658 -- -- -- -- -- 203 670 154 384 2343 us/cm 09/20/17 122 360 580 1141 144 235 422 81 644 153 -- 1966 us/cm 12/19/17 -- 542 -- -- -- -- -- 79 595 139 351 1707 us/cm 03/21/18 207 242 582 1124 299 246 336 129 668 162 -- 1869 us/cm 06/15/18 -- -- -- -- -- -- -- 97 619 179 407 1677 us/cm 09/25/18 176 540 737 1047 239 224 355 89 670 193 -- 3302 - 181 615 199 408 4026 us/cm 03/25/19 270 237 806 728 268 215 346 164 499 174 -- 1346 ND US/cm 09/18/19 168.2 139.3 670 1126 160 202 402 -- 646 178 1863 Temperature (field) Celsius 09/24/09 16.7 20.0 19.9 22.8 -- -- 21.1 16.7 17.5 -- 19.5 Celsius 03/23/10 13.2 Dry 15.0 11.8 -- -- -- -- -- 15.6 -- Celsius 09/24/15 15.0 16.5 17.6 17.1 16.5 14.7 15.7 -- 16.2 15.5 -- 19.1 Celsius 03/15/16 15.3 15.8 15.9 17.3 16.2 15.0 13.9 17.1 16.5 15.1 16.1 16.3 Celsius 06/29/16 -- -- -- -- -- -- -- 18.4 17.9 16.9 17.3 19.0 Celsius 09/21/16 15.0 17.9 17.7 17.8 16.9 16.3 21.6 18.2 17.0 15.4 -- 20.3 Celsius 12/19/16 -- 13.8 -- -- -- -- -- 14.4 14.2 12.9 13.5 8.1 Celcius 03/21/17 16.1 14.0 16.5 15.6 15.0 13.0 14.3 15.5 14.9 13.5 -- 15.5 Celcius 06/21/17 -- 18.1 -- -- -- -- -- 18.9 17.3 15.6 16.4 17.9 Celcius 09/20/17 15.24 21.61 18.02 18.02 18.25 16.46 17.97 19.5 17.4 17.0 -- 18.1 Celsius 12/19/17 -- 16.81 -- -- -- -- -- 15.8 15.7 13.7 15.6 10.8 Celsius 03/21/18 11.9 11.7 15.60 15.09 14.01 11.51 12.70 13.1 13.9 11.6 -- 9.35 Celcius 06/15/18 -- -- -- -- -- -- -- 18.3 18.5 16.4 18.2 18.4 Celcius 09/25/18 16.16 18.47 17.71 18.27 17.81 15.84 17.30 16.86 16.57 15.96 -- 18.83 Celcius 12/20/18 -- -- -- -- -- -- -- 13.4 13.6 12.4 12.1 6.4 Celsius 03/25/19 14.0 13.1 16.3 16.0 13.6 11.9 12.8 14.1 14.4 12.0 -- 8.0 ND Celsius 09/18/19 15.5 18.1 17.4 17.7 17.1 15.3 17.0 -- 16.5 15.8 18.4 Turbidity (field) NTU 09/24/09 39.1 11.6 23.7 97.6 -- -- 75.8 6.68 46 -- 24.9 NTU 03/23/10 73.8 Dry 17.0 33.8 -- -- -- -- -- 43.2 -- NTU 09/24/15 21.8 3.77 21.9 3.72 26.3 9.15 6.82 -- 0.34 8.69 -- 0.90 NTU 03/15/16 3.21 8.53 1.77 25.4 26.5 17.8 1.43 91.2 0.46 1.78 22.6 5.01 NTU 06/29/16 -- -- -- -- -- -- -- 25.3 0.73 0.99 19.0 4.25 NTU 09/21/16 8.72 5.92 1.97 24.5 11.3 18.6 2.91 12.1 1.93 1.60 -- 2.03 NTU 12/19/16 12.6 -- -- -- -- -- 9.82 0.24 0.87 11.2 1.37 NTU 03/21/17 11.1 2.29 0.64 20.3 7.68 12.5 2.17 9.18 0.78 1.27 -- 3.85 NTU 06/21/17 -- 9.60 -- -- -- -- -- 4.30 0.62 1.57 25.0 1.93 NTU 09/20/17 6.77 4.17 0.17 8.13 2.89 1.49 5.02 1.96 0.26 1.50 -- -8.10 NTU 12/19/17 -- 2.78 -- -- -- -- -- 1.63 1.02 0.59 15.4 1.79 NTU 03/21/18 9.7 2.88 0.36 8.76 7.56 5.51 2.03 4.02 1.07 2.69 -- 2.80 NTU -- -- 5 -- -- -- -- -- -- -- - 1.37 0.72 1.27 13.3 8.36 NTU 09/25/18 8.32 8.73 0.53 5.10 4.64 1.67 9.28 1.28 0.94 0.60 -- 7.48 NTU 12/20/18 -- -- -- -- -- -- -- 2.46 4.63 0.79 16.8 228 NTU 03/25/19 2.92 2.95 4.78 5.68 4.16 1.21 1.79 8.77 5.46 0.61 -- 14.1 ND NTU 09/18/19 8.5 3.4 2.84 8 0.02 1.21 1.78 -- 1.95 1.43 2.44 G GOLDER 3of5 January 2020 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring SWS Background Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IW-1 AMW-1D AMW-2D MW-2 BR-3 Oxidation Reduction Potential (field) my 09/22/09 179 -30.3 101 133 -132 39.0 88.8 -- -35.1 my 03/23/10 -- -- -- -- -- -- -- -- -- 31.1 -- mv 09/24/15 148 -26.1 90.7 103 18.8 69.5 61.2 -- 42.9 36.2 -- 74.5 my 03/15/16 253 -32.9 52.4 -16.8 129 125 180 117 87.1 151 35.2 -2.3 my 06/29/16 -- -- -- -- -- -- -- 55.9 138 157 49.7 33.1 my 09/21/16 318 -43.2 43.1 -26.6 121.7 60.9 103 41.9 77.8 56.0 -- 171 my 12/19/16 -- -47.1 -- -- -- -- -- -21.4 121 154 52.3 94.9 my 03/21/17 262.8 -38.6 378.0 75.9 133.0 5.67 125.8 -71.2 -80.4 150.3 -- -1.50 my 06/21/17 -- -32.0 -- -- -- -- -- -1.9 115.8 118.3 67.8 49.0 my 09/20/17 89.0 6.8 103.2 16.5 215.4 128.1 132.3 -74.6 185.5 153.3 -- -- mv 12/19/17 -- 16.6 -- -- -- -- -- -3.7 44.3 60.1 24.0 74.7 my 03/21/18 359.3 75.9 337.5 -19.50 115.6 70.40 312.4 23.6 69.5 66.4 -- -4.4 my 06/15/18 -- -- -- -- -- -- -- 131 280 322 60.1 352 my 09/25/18 125 -55.2 55.6 5.2 67.4 3.3 93.5 -92.7 -153 -16.8 -- 4.6 my 12/20/18 -- -- -- -- -- -- -- -50.3 81.4 142.3 -28.1 115.0 my 03/25/19 195.5 12.2 31.5 60.0 214.4 176.5 308.0 264.7 99.7 137.1 -- 3.2 ND my 09/18/19 192 -54.8 51.2 -33.5 150 93.9 47.0 -- 54.2 80.2 -5.4 Dissolved Oxygen (field) mg/L 09/22/09 7.85 1.49 1.18 1.31 -- -- 1.07 1.21 3.11 -- 4.33 mg/L 03/23/10 -- -- mg/L 09/24/15 7.30 1.70 1.08 0.78 4.80 0.64 0.81 -- 0.33 4.21 -- 5.09 mg/L 03/15/16 8.78 0.14 0.46 0.12 0.35 0.11 3.64 3.85 0.35 1.27 0.24 8.33 mg/L 06/29/16 -- -- -- -- -- -- -- 0.77 1.01 1.77 2.44 5.63 mg/L 09/21/16 7.41 0.39 1.59 1.09 2.45 0.80 3.26 0.39 1.17 2.36 -- 6.84 mg/L 12/19/16 -- 1.85 -- -- -- -- -- 1.07 1.18 3.11 1.52 8.74 mg/L 03/21/17 9.45 0.98 0.30 1.39 0.40 1.41 3.89 2.41 0.48 2.78 -- 7.50 mg/L 06/21/17 -- 0.27 -- -- -- -- -- 0.33 1.01 1.28 1.38 6.00 mg/L 09/20/17 2.21 1.39 0.72 1.07 4.48 0.39 2.41 0.40 1.26 1.15 -- -- mg/L 12/19/17 -- 0.92 -- -- -- -- -- 0.27 0.34 1.96 0.57 7.86 mg/L 03/21/18 6.59 0.27 0.49 1.04 0.15 0.25 3.75 0.81 1.28 1.04 -- 7.56 mg/L 06/15/18 -- -- -- -- -- -- -- 0.25 0.35 1.61 0.29 6.71 mg/L 09/25/18 7.37 0.15 0.18 0.59 3.30 2.25 3.40 2.72 1.49 2.61 -- 7.43 mg/L 12/20/18 -- -- -- -- -- -- -- 1.60 3.42 1.73 2.83 10.72 mg/L 03/25/19 8.16 0.11 0.20 0.08 2.42 0.43 4.53 2.67 1.66 2.00 -- 9.43 ND mg/L 09/18/19 7.28 3.66 1.47 0.71 1 1.44 1.81 -- 0.45 1.83 7.43 iso-Hexanoic Acid mg/L 0.51 0.50 09/24/09 ND ND ND ND -- -- ND -- -- -- ND mg/L 0.41 1.0 03/23/10 ND ND mg/L 0.44 0.50 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/15/16 ND ND 0.990 ND ND 0.610 ND ND mg/L 0.44 0.50 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.44 0.50 03/21/17 ND 1.80 ND ND ND ND ND ND m /L 0.44 0.50 09/18/19 ND ND ND ND ND ND ND ND iso-Pentanoic Acid mg/L 0.13 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.13 0.50 03/23/10 -- -- -- -- -- -- -- --ND-- ND mg/L 0.18 0.50 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/15/16 ND ND ND ND ND ND ND ND mg/L 0.18 0.50 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.18 0.50 03/21/17 ND ND ND ND ND ND ND ND mg/L 0.18 0.50 09/18/19 ND ND ND ND ND ND ND ND Pentanoic Acid mg/L 0.18 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.18 0.50 03/23/10 ND ND mg/L 0.11 0.20 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.11 0.20 03/15/16 ND ND ND ND ND ND ND ND mg/L 0.11 0.20 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.11 0.20 03/21/17 ND ND ND ND ND ND ND ND m /L 0.14 0.20 09/18/19 ND ND ND ND ND ND ND ND Hexanoic Acid mg/L 0.32 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.32 1.0 03/23/10 -- -- -- -- -- -- -- --ND-- ND mg/L 0.26 0.50 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/15/16 ND ND ND ND ND ND ND ND mg/L 0.26 0.50 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.26 0.50 03/21/17 ND ND ND ND ND ND ND ND mg/L 0.26 0.50 09/18/19 ND ND ND ND ND ND ND ND Pyruvic Acid mg/L 0.020 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.020 0.50 03/23/10 ND ND mg/L 0.012 0.070 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.012 0.070 03/15/16 ND ND ND ND 0.013 J 0.012 J ND ND mg/L 0.012 0.070 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.012 0.070 03/21/17 ND ND ND ND ND ND ND ND m /L 0.021 0.070 09/18/19 ND ND ND ND ND ND ND ND ..,> GOL❑ER 4of5 January 2020 TABLE 10 Summary of Geochemical Indicators Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring SWS Background Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Units MDL PQL Date Reporting Well Blanks Constituent/Parameter Limit MW-5 MW-6 MW-7 MW-8 AMW-1S AMW-2S Old MW-2 IWA AMWAD AMW-2D MW-2 BR-3 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) mg/L 0.088 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.088 0.50 03/23/10 NO NO mg/L 0.095 0.14 09/24/15 ND ND ND ND ND ND ND ND mg/L 0.095 0.14 03/15/16 ND 5.7 9.9 ND 0.59 0.56 ND NO mg/L 0.095 0.14 09/21/16 ND ND ND ND ND ND ND ND mg/L 0.095 0.14 03/21/17 ND ND ND ND ND ND NO NO m /L 0.13 0.14 09/18/19 ND 23 3.8 ND ND ND ND ND Acetic Acid mg/L 0.071 0.50 09/24/09 0.43 J ND 0.39 J ND ND NO mg/L 0.071 0.50 03/23/10 -- -- -- -- -- -- -- --ND-- ND mg/L 0.16 0.20 09/24/15 ND 18 ND ND ND ND NO NO mg/L 0.16 0.20 03/15/16 ND ND 7.2 ND 0.38 ND ND ND mg/L 0.16 0.20 09/21/16 ND 18 3.4 ND ND ND NO NO mg/L 0.16 0.20 03/21/17 ND 15 ND ND 0.33 0.49 ND ND mg/L 0.18 0.20 09/18/19 ND 18 1.4 ND ND ND NO NO Propionic Acid mg/L 0.054 0.50 09/24/09 ND ND ND ND ND ND mg/L 0.054 0.50 03/23/10 NO NO mg/L 0.065 0.10 09/24/15 ND 14.0 ND ND 2.40 ND ND ND mg/L 0.065 0.10 03/15/16 ND 2.30 3.50 ND 0.42 0.14 0.11 NO mg/L 0.065 0.10 09/21/16 ND 12.0 1.50 ND ND ND ND ND mg/L 0.065 0.10 03/21/17 ND 8.40 ND ND 0.12 ND ND NO m /L 0.065 0.10 09/18/19 ND ND ND ND ND ND ND ND Butyric Acid mg/L 0.16 0.50 09/24/09 ND ND ND ND ND NO mg/L 0.16 0.50 03/23/10 -- -- -- -- -- -- -- --ND-- ND mg/L 0.089 0.10 09/24/15 ND ND ND ND ND ND NO NO mg/L 0.089 0.10 03/15/16 ND ND ND ND ND ND ND ND mg/L 0.089 0.10 09/21/16 ND ND ND ND NO ND NO NO mg/L 0.089 0.10 03/21/17 ND ND ND ND ND ND ND ND mg/L 0.089 0.10 09/18/19 ND ND NO ND ND ND NO NO Hydrogen nM 0.60 09/24/09 1.3 1.9 1.3 1.4 1.3 nM 0.60 03/23/10 17 nM 0.088 0.60 09/24/15 21 21 25 2.6 27 4.5 21 nM 0.088 0.60 03/15/16 3.1 3.2 2.7 4.2 3.4 3.4 3.2 nM 0.075 0.60 09/21/16 2.5 2.6 2.4 2.8 2.4 2.9 2.4 nM 0.075 0.60 03/21/17 2.3 2.5 2.4 2.2 2.9 2.4 2.8 nM 0.16 0.60 09/20/17 2.6 3.2 2.5 2.6 2.5 2.7 3.1 nM 0.16 0.60 03/21/18 2.2 1.7 2.2 1.6 1.9 1.6 1.8 NO nM 0.65 1.00 09/24/18 2.7 2.1 2.8 3.1 2.4 3.1 2.7 ND nM 0.75 1.00 03/25/19 ND 1.6 3.1 15 2.4 1.5 1.3 nM 0.75 1.00 09/18/19 24 120 64 84 98 170 110 Ferrous Iron (field) mg/L 09/24/09 ND 0.8 2.3 ND 2.9 mg/L 03/23/10 1.5 mg/L 09/24/15 ND 3.5 ND ND 3.6 ND 1.0 mg/L 03/15/16 ND 2.6 ND 4.2 1.0 ND ND (lab) mg/L 0.046 0.5 09/21/16 ND 44 5.3 16 0.79 ND 0.94 mg/L 09/21/16 ND ND ND ND ND ND ND ND (lab) mg/L 0.046 0.5 03/21/17 ND 45 0.65 ND 0.87 ND ND (lab) mg/L 0.031 0.5 09/20/17 ND 11 ND 12 0.65 ND ND (lab) mg/L 0.031 0.5 03/21/18 ND 11 1 17 ND ND NO NO (lab) mg/L 0.040 0.5 09/24/18 ND 22 9.8 12 1.1 ND ND ND (lab) mg/L 0.120 0.5 03/25/19 ND 17 19 13 ND ND ND (lab) mg/L 0.120 0.5 09/18/19 ND 49 11 26 NO ND 1.5 Notes: ug/L = micrograms per liter mg/L = milligrams per liter ND = Not detected at the stated reporting limit J = estimated concentration between the MDL and PQL. B = Blank -qualified result = no data available MDL = laboratory method detection limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 1) Historical data prior to March 2009 provided by Henderson County and CDM. hydrogen (4x), AMW-1S carbon dioxide (2.1x) and hydrogen (4x), AMW-2S carbon dioxide (2.1x) and hydrogen (20x), Old MW-2 carbon dioxide (100 and ferrous iron (8x). ..,> GOL❑ER 5 of 5 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-'IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 Benzene ug/L 12/05/94 5.0 5.0 5 ND 11 ND ND ND NC 2L = 1 ug/L ug/L 02/14/95 5.0 5.0 5 ND 11 ND ND ND EPA MCL = 5 ug/L ug/L 04/03/95 5.0 5.0 5 ND 8 ND ND ND ug/L 10/30/95 5.0 5.0 5 ND ND ND ND ND ug/L 04/08/96 5.0 5.0 5 ND 9 3.9 ND ND ug/L 10/24/96 5.0 5.0 5 ND -- 5 ND ND ug/L 04/15/97 5.0 5.0 5 ND -- 6.9 ND ND ug/L 10/29/97 -- -- 5 ND 5 6 ND ND ug/L 05/14/98 5 ND 8 6 ND ND ug/L 10/11/98 5 ND ND 7 ND ND ug/L 06/04/99 5 ND 8 6 ND ND ug/L 10/29/99 5 ND ND ND ND ND ug/L 04/20/00 5 ND ND ND ND ND ND ug/L 11/07/00 5 ND ND ND ND ND ug/L 02/27/01 5 ND ND ND ug/L 05/15/01 5 ND ND ND ND ND ug/L 10/16/01 5 ND ND ND ND ND ND ug/L 04/24/02 5 ND 6 ND ND ND ND ND ug/L 10/01/02 5 ND ND ND ND ND ND ND ug/L 04/09/03 5 ND ND ND ND ND ND ND ug/L 10/20/03 -- -- 5 ND 7 ND ND ND ND ND ug/L 03/24/04 5.0 5.0 5 ND 6 ND ND ND ND ND ug/L 10/27/04 5.0 5.0 5 ND 7.19 ND ND ND ND ND ug/L 05/25/05 5.0 5.0 5 ND ND ND ND ND ND ug/L 10/04/05 5.0 5.0 5 ND 7.61 ND ND ND ND ND ug/L 04/25/06 5.0 5.0 5 ND 6.23 ND ND ND ND ND ug/L 10/04/06 5.0 5.0 5 ND 6.8 ND ND ND ND ND ND ug/L 03/21/07 5.0 5.0 5 ND 1.36 2.48 3.55 0.44 1 1.52 ND ND ug/L 10/02/07 5.0 5.0 5 ND 5.47 1.70 4.99 1.68 1.55 ND ND ug/L 04/03/08 5.0 5.0 5 ND 0.37 1 1.57 5.82 0.98 1 1.28 0.880 1 1.48 ND ND ND ug/L 10/29/08 5.0 5.0 5 ND 3.08 1.51 6.23 2.13 1.25 -- 1.49 ND ND ND ug/L 03/24/09 0.20 1.0 1 ND ND ND 0.64 1 ND ND ND ND ND ND ug/L 09/22/09 0.20 1.0 1 ND ND 1.4 4.2 0.44 1 1.2 ND 1.3 ND -- ND ND ug/L 03/22/10 0.050 1.0 1 ND Dry 1.4 ND ND 0.75 1 1.1 ND 0.91 1 ND ND ug/L 09/23/10 0.20 1.0 1 ND 0.98 1 ND ND ND ND ND ND -- ND ND ug/L 03/16/11 0.68 1.0 1 ND ND 1.6 ND ND 0.96 1 1.2 ND ND ND ug/L 09/21/11 0.68 1.0 1 ND 4.6 1.4 0.85 1 ND 0.82 1 1.2 ND ND ND ug/L 03/21/12 0.15 1.0 1 ND ND 1.1 0.65 1 0.73 1 0.82 1 0.95 1 ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND 0.94 1 ND ND ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND 1.5 3.0 ND 1.2 1.2 ND ND ND ug/L 09/18/13 0.15 1.0 1 ND 2.9 1.7 0.89 1 0.56 1 0.86 1 1.1 ND ND ND ug/L 03/27/14 0.15 1.0 1 ND ND 1.6 ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND 4.6 1.1 ND ND 0.58 1 1.1 ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND 1.3 ND ND 0.60 1 1.2 ND ND ND ug/L 09/23/15 0.15 1.0 1 ND 3.7 1.3 ND 1.1 0.66 1 ND -- 0.83 1 ND -- ND ND ug/L 03/15/16 0.15 1.0 1 ND 1.2 2.4 ND ND 0.45 1 ND 0.91 1 1.2 ND 0.60 1 ND ND ug/L 06/29/16 0.15 1.0 1 -- -- ND 0.91 1 ND 0.46 1 ND ND ug/L 09/21/16 0.15 1.0 1 ND 3.5 1.8 ND ND 0.41 1 ND ND 1.1 ND -- ND ND ug/L 12/19/16 0.15 1.0 1 -- -- -- ND 0.68 1 ND 0.40 1 ND ND ug/L 03/21/17 0.15 1.0 1 ND 2.6 1.8 ND ND 0.64 1 ND ND 0.97 1 ND -- ND ND ug/L 06/21/17 0.15 1.0 1 -- ND 0.72 1 ND 0.53 1 ND ND ug/L 09/20/17 0.15 1.0 1 ND ND 1.6 ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.15 1.0 1 -- ND 0.80 1 ND 0.46 1 ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/15/18 0.15 1.0 1 ND 0.60 1 ND ND ND ND ug/L 09/24/18 0.15 1.0 -- ND ND ND ND ND ND ND ND 0.71 1 ND ND ND ug/L 12/20/18 0.15 1.0 -- ND 0.71 1 ND ND ND ND ug/L 03/26/19 0.15 1.0 ND ND 2.5 ND ND ND ND ND 0.47 1 ND ND ND ug/L 09/18/19 0.15 1.0 ND 4.3 ND ND ND ND ND 0.68 1 ND ND ND GOLDER 1 of 6 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-'IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 1,4-Dichlorobenzene ug/L 12/05/94 5.0 5.0 5 ND ND ND ND ND NC 2L = 6 ug/L ug/L 02/14/95 5.0 5.0 5 ND -- ND ND ND EPA MCL = 75 ug/L ug/L 04/03/95 5.0 5.0 5 ND 11 ND ND ND ug/L 10/30/95 5.0 5.0 5 ND 10 5 ND ND ug/L 04/08/96 -- -- 5 ND -- 9 ND ND ug/L 10/24/96 5 ND 8 ND ND ug/L 04/15/97 5 ND -- 24 ND ND ug/L 10/29/97 5 ND 9 10 ND ND ug/L 05/14/98 5 ND 18 22 ND ND ug/L 10/11/98 5 ND 18 ND ND ND ug/L 06/04/99 5 ND 18 10 ND ND ug/L 10/29/99 5 ND ND 7 ND ND ug/L 04/20/00 5 ND 5 18 ND ND ND ug/L 11/07/00 5 ND ND 8 ND ND ug/L 02/27/01 5 -- -- ND ND ND ug/L 05/15/01 5 ND 14 6 ND ND ug/L 10/16/01 5 ND 12 7 ND ND ND ug/L 04/24/02 5 ND 18 8 ND ND ND ND ug/L 10/01/02 -- -- 5 ND 14 9 ND ND ND ND ug/L 04/09/03 5.0 5.0 5 ND ND 12 ND ND ND ND ug/L 10/20/03 5.0 5.0 5 ND 23 13 ND ND ND ND ug/L 03/24/04 5.0 5.0 5 ND ND ND ND ND ND ND ug/L 10/27/04 5.0 5.0 5 ND 20 19 ND ND ND ND ug/L 05/25/05 5.0 5.0 5 ND ND 17.8 ND ND ND ug/L 10/04/05 5.0 5.0 5 ND 25.4 17 ND ND ND ND ug/L 04/25/06 5.0 5.0 5 ND 24.3 16.4 ND ND ND ND ug/L 10/04/06 5.0 5.0 5 ND 18.5 14.6 ND ND ND ND ND ug/L 03/21/07 5.0 5.0 5 ND 1.67 1 17.1 2.79 1 1.37 2.86 1 0.37 1 ND ug/L 10/02/07 5.0 5.0 5 ND 18.7 12.0 3.64 1 3.24 1 -- -- 2.99 1 ND ND ug/L 04/03/08 5.0 5.0 5 ND 0.38 1 8.37 4.50 1 1.57 1 2.11 1 1.04 1 2.77 1 ND ND ND ug/L 10/29/08 5.0 5.0 5 ND 23.9 7.81 4.44 1 4.11 1 1.66 1 -- 2.96 1 ND ND ND ug/L 03/24/09 0.38 1.0 1 ND ND 6.4 1.3 0.57 1 1.4 2.6 ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND 6.8 2.4 1.4 1.0 ND 2.1 ND -- ND ND ug/L 03/22/10 0.10 1.0 1 ND Dry 9.8 ND ND 1.2 3.2 ND 2.0 ND ND ug/L 09/23/10 0.38 1.0 1 ND 15 8.8 ND ND 0.91 1 3.4 ND -- ND ND ug/L 03/16/11 0.79 1.0 1 ND ND 10 ND ND 1.3 3.2 ND ND ND ug/L 09/21/11 0.79 1.0 1 ND 14 12 ND 0.93 1 1.2 4.2 ND ND ND ug/L 03/21/12 0.19 1.0 1 ND 5.4 1 12 0.49 1 2.9 1.4 3.7 ND ND ND ug/L 09/20/12 0.19 1.0 1 ND 0.77 1 11 1.0 2.0 1.2 3.8 ND ND ND ug/L 03/20/13 0.19 1.0 1 ND ND 14 3.8 ND 2.2 5.0 ND ND ND ug/L 09/18/13 0.19 1.0 1 ND 6.0 13 1.2 0.73 1 1.4 4.1 ND ND ND ug/L 03/27/14 0.19 1.0 1 ND ND 18 ND ND 0.73 1 3.1 ND ND ND ug/L 09/18/14 0.19 1.0 1 ND 13 15 ND ND 0.86 1 4.3 ND ND ND ug/L 03/18/15 0.19 1.0 1 ND ND 14 ND 0.46 1 1.4 4.0 ND ND ND ug/L 09/23/15 0.19 1.0 1 ND 21 13 ND 0.85 1 1.3 1.0 3.6 ND -- ND ND ug/L 03/15/16 0.19 1.0 1 ND 1.2 16 ND ND 0.90 1 ND 2.4 4.2 ND 3.5 ND ND ug/L 06/29/16 0.19 1.0 1 -- -- -- -- ND 4.2 ND 4.0 ND ND ug/L 09/21/16 0.19 1.0 1 ND 28 14 ND ND 0.87 1 0.6 1 ND 4.2 ND -- ND ND ug/L 12/19/16 0.19 1.0 1 -- -- -- -- -- ND 3.2 ND 4.1 ND ND ug/L 03/21/17 0.19 1.0 1 ND 24 18 ND 0.44 1.4 ND ND 4.1 ND -- ND ND ug/L 06/21/17 0.19 1.0 1 -- -- -- ND 2.8 ND ND ND ND ug/L 09/20/17 0.19 1.0 1 ND 2.9 16 ND ND 1.2 0.45 1 ND 3.8 ND -- ND ND ug/L 12/19/17 0.19 1.0 1 -- -- -- -- ND 3.5 ND 4.2 ND ND ug/L 03/21/18 0.19 1.0 1 ND ND 14 ND ND 1.1 ND ND 3.4 ND -- ND ND ug/L 06/15/18 0.19 1.0 1 -- -- ND 2.8 ND 4.2 ND ND ug/L 09/24/18 0.19 1.0 -- ND 5.4 16 ND ND 1.1 ND ND 3.4 ND -- ND ND ug/L 12/20/18 0.19 1.0 -- -- -- ND 2.9 ND 4.4 ND ND ug/L 03/26/19 0.19 1.0 ND ND 17 ND ND 0.59 1 ND ND 2.3 ND -- ND ND ug/L 09/18/19 0.19 1.0 ND 14 12 ND ND ND ND 2.8 ND ND ND GOLDER 2 of 6 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-'IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 1,1-Dichloroethane ug/L 12/05/94 5.0 5.0 5 ND ND ND ND ND NC 2L = 6 ug/L ug/L 02/14/95 5.0 5.0 5 ND ND 9 ND ND EPA MCL = No Standard ug/L 04/03/95 5.0 5.0 5 ND 7 ND ND ug/L 10/30/95 5.0 5.0 5 ND ND 10 ND ND ug/L 04/08/96 -- -- 5 ND ND 6 ND ND ug/L 10/24/96 5 ND 8 ND ND ug/L 04/15/97 5 ND -- ND ND ND ug/L 10/29/97 5 ND 1 7 ND ND ug/L 05/14/98 5 ND ND ND ND ND ug/L 10/11/98 5 ND ND 6 ND ND ug/L 06/04/99 5 ND ND 5 6 ND ug/L 10/29/99 5 ND ND ND ND ND ug/L 04/20/00 5 ND ND ND 5 ND ND ug/L 11/07/00 5 ND ND ND 6 -- ND ug/L 02/27/01 5 -- ND 7 ND ug/L 05/15/01 5 ND ND ND 14 -- ND ug/L 10/16/01 5 ND ND ND 11 ND ND ug/L 04/24/02 5 ND ND ND 25 ND ND ND ug/L 10/01/02 5 ND ND ND 17 ND ND ND ug/L 04/09/03 -- -- 5 ND ND ND 24 ND ND ND ug/L 10/20/03 5.0 5.0 5 ND ND ND 18 ND ND ND ug/L 03/24/04 5.0 5.0 5 ND ND ND 10 ND ND ND ug/L 10/27/04 5.0 5.0 5 ND ND ND 13 ND ND ND ug/L 05/25/05 5.0 5.0 5 ND ND ND -- ND ND ND ug/L 10/04/05 5.0 5.0 5 ND ND ND ND ND ND ND ug/L 04/25/06 5.0 5.0 5 ND ND ND ND ND ND ND ug/L 10/04/06 5.0 5.0 5 ND ND ND 6 ND ND ND ND ug/L 03/21/07 5.0 5.0 5 ND ND 1.69 7.8 ND 1.31 ND ND ug/L 10/02/07 5.0 5.0 5 ND 0.45 1 1.66 1 9.7 0.1 1 -- -- 1.27 1 ND ND ug/L 04/03/08 5.0 5.0 5 ND ND 1.72 1 13.1 ND 0.98 1 3.87 1 1.36 1 ND ND ND ug/L 10/29/08 5.0 5.0 5 ND 0.40 1 1.32 1 13.5 ND 1.33 1 -- 1.36 1 ND ND ND ug/L 03/24/09 0.33 1.0 5 ND ND 0.83 1 3.6 1 ND 1.1 1 1.2 1 ND ND ND ug/L 09/22/09 0.33 1.0 5 ND ND 0.75 1 8.9 ND 1.3 1 ND 1.0 1 ND -- ND ND ug/L 03/22/10 0.050 1.0 5 ND Dry 0.64 1 ND ND 0.90 1 0.76 1 ND 3.9 1 ND ND ug/L 09/23/10 0.33 1.0 5 ND ND 0.64 1 ND ND 0.84 1 0.87 1 ND -- ND ND ug/L 03/16/11 0.080 1.0 5 ND ND 0.56 1 ND ND 1.0 1 0.91 1 ND ND ND ug/L 09/21/11 0.080 1.0 5 ND ND 0.74 1 1.7 1 ND 1.4 1 1.1 1 ND ND ND ug/L 03/21/12 0.13 1.0 5 ND ND 0.63 1 0.94 1 ND 1.1 1 0.74 1 ND ND ND ug/L 09/20/12 0.13 1.0 5 ND ND 0.49 1 2.5 1 ND 1.3 1 1.0 1 ND ND ND ug/L 03/20/13 0.13 1.0 5 ND ND 0.71 1 6.9 ND 1.6 1 1.2 1 ND ND ND ug/L 09/18/13 0.13 1.0 5 ND ND ND 1.7 1 ND 1.0 1 0.71 1 ND ND ND ug/L 03/27/14 0.13 1.0 5 ND ND ND ND ND 0.92 1 0.72 1 ND ND ND ug/L 09/18/14 0.13 1.0 5 ND ND 0.43 1 ND ND 0.96 1 0.54 1 ND ND ND ug/L 03/18/15 0.13 1.0 5 ND ND 0.47 1 ND ND 0.77 1 0.76 1 ND ND ND ug/L 09/23/15 0.13 1.0 5 ND ND ND ND ND 1.1 1 2.2 1 0.62 1 ND -- ND ND ug/L 03/15/16 0.13 1.0 5 ND ND ND ND ND 0.99 1 2.0 1 0.55 1 0.54 1 0.45 1 4.0 1 ND ND ug/L 06/29/16 0.13 1.0 5 -- -- ND 0.44 1 ND 2.6 1 ND ND ug/L 09/21/16 0.13 1.0 5 ND ND ND ND ND 0.94 1 1.7 1 ND 0.51 1 ND -- ND ND ug/L 12/19/16 0.13 1.0 5 -- -- ND ND ND 3.2 1 ND ND ug/L 03/21/17 0.13 1.0 5 ND ND ND ND ND 1.1 1 1.6 1 ND 0.58 1 ND -- ND ND ug/L 06/21/17 0.13 1.0 5 -- -- 0.49 1 ND ND 3.3 1 ND ND ug/L 09/20/17 0.13 1.0 5 ND ND ND ND ND 0.87 1 1.8 1 ND ND ND -- ND ND ug/L 12/19/17 0.13 1.0 5 -- -- ND ND ND 2.3 1 ND ND ug/L 03/21/18 0.13 1.0 5 ND ND ND ND ND 0.74 1 0.92 1 ND ND ND -- ND ND ug/L 06/15/18 0.13 1.0 5 -- -- ND ND ND 2.5 1 ND ND ug/L 09/24/18 0.13 1.0 -- ND ND ND ND ND ND 1.0 ND ND ND -- ND ND ug/L 12/20/18 0.13 1.0 -- -- ND ND ND 2.6 ND ND ug/L 03/26/19 0.13 1.0 ND ND ND ND ND 0.65 1 1.0 ND ND ND -- ND ND ug/L 09/18/19 0.13 1.0 ND ND ND ND ND 0.58 1 1.0 ND ND ND ND GOLDER 3 of 6 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-'IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 Tetrachloroethene (PCE) ug/L 12/05/94 5.0 5.0 1 ND ND 6.6 9 ND NC 2L = 0.7 ug/L ug/L 02/14/95 5.0 5.0 1 ND ND 7 7 ND EPA MCL = 5 ug/L ug/L 04/03/95 5.0 5.0 1 ND ND 6.3 ND ND ug/L 10/30/95 5.0 5.0 1 ND ND ND ND ND ug/L 04/08/96 5.0 5.0 1 ND ND ND ND ND ug/L 10/24/96 -- -- 1 ND ND ND ND ug/L 04/15/97 1 ND ND 15 ND ug/L 10/29/97 1 ND ND 4 4 ND ug/L 05/14/98 1 ND ND ND 19 ND ug/L 10/11/98 1 ND ND ND 15 ND ug/L 06/04/99 1 ND ND ND 44 ND ug/L 10/29/99 1 ND ND ND 27 ND ug/L 04/20/00 1 ND ND ND 69 ND ND ug/L 11/07/00 1 ND ND ND 54 ND ug/L 02/27/01 1 -- ND ND ND ug/L 05/15/01 1 ND ND ND 110 ND ug/L 10/16/01 1 ND ND ND 44 ND ND ug/L 04/24/02 1 ND ND ND 170 ND ND ND ug/L 10/01/02 1 ND ND ND 110 ND ND ND ug/L 04/09/03 1 ND ND ND 120 ND ND ND ug/L 10/20/03 1 ND ND ND 61 ND ND ND ug/L 03/24/04 -- -- 1 ND ND ND 32 ND ND ND ug/L 10/27/04 5.0 5.0 1 ND ND ND 52 ND ND ND ug/L 05/25/05 5.0 5.0 1 ND ND ND -- ND ND ND ug/L 10/04/05 5.0 5.0 1 ND ND ND 16.2 ND ND ND ug/L 04/25/06 5.0 5.0 1 ND ND ND 10 ND ND ND ug/L 10/04/06 5.0 5.0 1 ND ND ND 21 ND ND ND ND ug/L 03/21/07 5.0 5.0 1 ND ND ND 28.8 ND ND ND ND ug/L 10/02/07 5.0 5.0 1 ND ND ND 42.1 ND -- ND ND ND ug/L 04/03/08 5.0 5.0 1 ND ND ND 47.9 ND ND 0.650 1 ND ND ND ND ug/L 10/29/08 5.0 5.0 1 ND ND ND 48.5 ND ND -- ND ND ND ND ug/L 03/24/09 0.36 1.0 1 ND ND ND 8.7 ND ND ND ND ND ND ug/L 09/22/09 0.36 1.0 1 ND ND ND 25 ND ND ND ND ND -- ND ND ug/L 03/22/10 0.099 1.0 1 ND Dry ND 0.80 J ND ND ND ND 1.4 ND ND ug/L 09/23/10 0.36 1.0 1 ND ND ND ND ND ND ND ND -- ND ND ug/L 03/16/11 0.73 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/11 0.73 1.0 1 ND ND ND 2.8 ND ND ND ND ND ND ug/L 03/21/12 0.17 1.0 1 ND ND ND 1.7 ND ND ND ND ND ND ug/L 09/20/12 0.17 1.0 1 ND ND ND 3.9 ND ND ND ND ND ND ug/L 03/20/13 0.17 1.0 1 ND ND ND 11 ND ND ND ND ND ND ug/L 09/18/13 0.17 1.0 1 ND ND ND 2.8 ND ND ND ND ND ND ug/L 03/27/14 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 03/18/15 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.17 1.0 1 ND ND ND ND ND ND ND ND ND -- ND ND ug/L 03/15/16 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND 0.44 1 ND ND ug/L 06/29/16 0.17 1.0 1 ND ND ND 0.85 J ND ND ug/L 09/21/16 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/16 0.17 1.0 1 ND ND ND 0.64 1 ND ND ug/L 03/21/17 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/21/17 0.17 1.0 1 ND ND ND 0.60 1 ND ND ug/L 09/20/17 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.17 1.0 1 ND ND ND 0.46 1 ND ND ug/L 03/21/18 0.17 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/15/18 0.17 1.0 1 ND ND ND ND ND ND ug/L 09/24/18 0.17 1.0 -- ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/20/18 0.17 1.0 ND ND ND 0.56 1 ND ND ug/L 03/26/19 0.17 1.0 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 09/18/19 0.17 1.0 ND ND ND ND ND ND ND ND ND ND ND GOLDER 4of6 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-'IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 Trichloroethene ug/L 12/05/94 5.0 5.0 1 ND ND ND ND ND NC 2L = 3 ug/L ug/L 02/14/95 5.0 5.0 1 ND ND ND ND ND EPA MCL = 5 ug/L ug/L 04/03/95 5.0 5.0 1 ND ND ND ND ND ug/L 10/30/95 -- -- 1 ND ND ND ND ND ug/L 04/08/96 1 ND ND ND ND ND ug/L 10/24/96 1 ND ND ND ND ug/L 04/15/97 1 ND ND ND ND ug/L 10/29/97 1 ND ND 2 ND ND ug/L 05/14/98 1 ND ND ND ND ND ug/L 10/11/98 1 ND ND ND ND ND ug/L 06/04/99 1 ND ND ND ND ND ug/L 10/29/99 1 ND ND ND ND ND ug/L 04/20/00 1 ND ND ND 6 ND ND ug/L 11/07/00 1 ND ND ND ND ND ug/L 02/27/01 1 -- ND ND ND ug/L 05/15/01 1 ND ND ND 14 ND ug/L 10/16/01 1 ND ND ND 8 ND ug/L 04/24/02 -- -- 1 ND ND ND 20 ND ND ug/L 10/01/02 5.0 5.0 1 ND ND ND 13 ND ND ug/L 04/09/03 5.0 5.0 1 ND ND ND 27 ND ND ug/L 10/20/03 5.0 5.0 1 ND ND ND 26 ND ND ug/L 03/24/04 5.0 5.0 1 ND ND ND 13 ND ND ug/L 10/27/04 5.0 5.0 1 ND ND ND 17.5 ND ND ug/L 05/25/05 5.0 5.0 1 ND ND ND -- ND ND ug/L 10/04/05 5.0 5.0 1 ND ND ND 5 ND ND ND ug/L 04/25/06 5.0 5.0 1 ND ND ND ND ND ND ND ug/L 10/04/06 5.0 5.0 1 ND ND ND 7 ND ND ND ND ug/L 03/21/07 5.0 5.0 1 ND ND 0.48 1 12 ND 0.31 1 ND ND ug/L 10/02/07 5.0 5.0 1 ND ND 0.41 1 15.5 ND -- -- 0.3 1 ND ND ug/L 04/03/08 5.0 5.0 1 ND ND 0.47 1 18.1 ND 0.30 1 0.850 1 0.28 1 ND ND ND ug/L 10/29/08 5.0 5.0 1 ND ND 0.32 1 18.2 ND 0.45 1 -- 0.33 1 ND ND ND ug/L 03/24/09 0.38 1.0 1 ND ND ND 3.1 ND ND ND ND ND ND ug/L 09/22/09 0.38 1.0 1 ND ND ND 9.5 ND ND ND ND ND -- ND ND ug/L 03/22/10 0.13 1.0 1 ND Dry ND ND ND 0.44 1 ND ND 1.6 ND ND ug/L 09/23/10 0.38 1.0 1 ND ND ND ND ND ND ND ND -- ND ND ug/L 03/16/11 0.72 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/21/11 0.72 1.0 1 ND ND ND 1.1 ND ND ND ND ND ND ug/L 03/21/12 0.15 1.0 1 ND ND ND 0.70 1 ND ND ND ND ND ND ug/L 09/20/12 0.15 1.0 1 ND ND ND 1.6 ND ND ND ND ND ND ug/L 03/20/13 0.15 1.0 1 ND ND ND 3.9 ND ND ND ND ND ND ug/L 09/18/13 0.15 1.0 1 ND ND ND 1.3 ND ND ND ND ND ND ug/L 03/27/14 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/18/14 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 03/18/15 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ug/L 09/23/15 0.15 1.0 1 ND ND ND ND ND ND ND ND ND -- ND ND ug/L 03/15/16 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND 0.83 1 ND ND ug/L 06/29/16 0.15 1.0 1 ND ND ND 0.71 1 ND ND ug/L 09/21/16 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/16 0.15 1.0 1 ND ND ND 0.80 1 ND ND ug/L 03/21/17 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 06/21/17 0.15 1.0 ND ND ND 0.70 1 ND ND ug/L 09/20/17 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/19/17 0.15 1.0 1 ND ND ND ND ND ND ug/L 03/21/18 0.15 1.0 1 ND ND ND ND ND ND ND ND ND ND ND ND ug/L 06/15/18 0.15 1.0 1 ND ND ND ND ND ND ug/L 09/24/18 0.15 1.0 -- ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 12/20/18 0.15 1.0 ND ND ND 0.49 1 ND ND ug/L 03/26/19 0.15 1.0 ND ND ND ND ND ND ND ND ND ND -- ND ND ug/L 09/18/19 0.15 1.0 ND ND ND ND ND ND ND ND ND ND ND GOLDER 5 of 6 November 2019 TABLE 11 Summary of Constituents of Concern in MSW Corrective Action Monitoring Points Henderson County Closed MSW Landfill, Permit No. 45-01 19128179 Detected Monitoring Constituent/Parameter Units Date MDL PQL SWS Reporting Limit Upgradient Compliance Well Monitored Natural Attenuation Monitoring Wells Pilot Test Monitoring Points Blanks MW-5 MW-6 MW-7 MW-8 AMW-IS AMW-2S Old MW-2 IW-1 AMWAD AMW-21D MW-2 BR-3 Vinyl chloride ug/L 12/05/94 10 10 1 ND ND ND ND ND NC 2L = 0.03 ug/L ug/L 02/14/95 10 10 1 ND ND ND ND ND EPA MCL = 2 ug/L ug/L 04/03/95 10 10 1 ND ND ND ND ND ug/L 10/30/95 1 ND ND ND ND ND ug/L 04/08/96 1 ND ND ND ND ND ug/L 10/24/96 1 ND ND ND ND ug/L 04/15/97 1 ND ND ND ND ug/L 10/29/97 1 ND 2 5 2 ND ug/L 05/14/98 1 ND ND ND ND ND ug/L 10/11/98 1 ND ND ND ND ND ug/L 06/04/99 1 ND ND ND ND ND ug/L 10/29/99 1 ND ND ND ND ND ug/L 04/20/00 1 ND ND ND ND ND ND ug/L 11/07/00 1 ND ND ND ND ND ug/L 02/27/01 1 ND ND ND ug/L 05/15/01 1 ND ND ND ND ND ug/L 10/16/01 1 ND ND ND ND ND ND ug/L 04/24/02 1 ND ND ND ND ND ND ND ug/L 10/01/02 1 ND ND ND NO ND ND ND ug/L 04/09/03 1 ND ND ND ND ND ND ND ug/L 10/20/03 1 ND ND ND ND ND ND ND ug/L 03/24/04 10 10 1 ND ND ND ND ND ND ND ug/L 10/27/04 10 10 1 ND ND ND ND ND ND ND ug/L 05/25/05 10 10 1 ND ND ND ND ND ND ug/L 10/04/05 10 10 1 ND ND ND ND ND ND ND ug/L 04/25/06 10 10 1 ND ND ND ND ND ND ND ug/L 10/04/06 10 10 1 ND ND ND ND ND ND ND ND ug/L 03/21/07 10 10 1 ND 0.43 J 2.35 ND ND 0.94 J ND ND ug/L 10/02/07 10 10 1 ND 1.03 J 2.68 J 0.31 J ND 0.89 J ND ND ug/L 04/03/08 10 10 1 ND ND 2.94 J ND 0.59 J 0.640 J 0.98 J ND ND ND ug/L 10/29/08 10 10 1 ND 0.25 J 2.36 0.49 J ND 0.57 J 0.82 J ND ND ND ug/L 03/24/09 0.30 1.0 1 ND ND 1.5 ND ND 0.53 J 0.60 J ND ND ND ug/L 09/22/09 0.30 1.0 1 ND ND 1.4 ND ND ND ND 0.67 J ND ND ND ug/L 03/22/10 0.083 1.0 1 ND Dry 1.2 ND ND ND 0.60 J ND 0.74 J ND ND ug/L 09/23/10 0.30 1.0 1 ND ND 1.2 ND ND ND ND ND ND ND ug/L 03/16/11 0.60 1.0 1 ND ND 1.3 ND ND ND ND ND ND ND ug/L 09/21/11 0.60 1.0 1 ND ND 1.5 ND ND ND 0.76 J ND ND ND ug/L 03/21/12 0.32 1.0 1 ND ND 0.88 J ND ND 0.55 J ND ND ND ND ug/L 09/20/12 0.32 1.0 1 ND ND ND ND ND 0.61 J 0.57 J ND ND ND ug/L 03/20/13 0.32 1.0 1 ND ND 1.0 0.77 J ND 0.49 J 0.50 J ND ND ND ug/L 09/18/13 0.32 1.0 1 ND ND 0.81 J ND ND 0.48 J 0.48 J ND ND ND ug/L 03/27/14 0.32 1.0 1 ND ND 1.1 ND ND ND 0.64 J ND ND ND ug/L 09/18/14 0.32 1.0 1 ND ND 1.1 ND ND ND 0.54 J ND ND ND ug/L 03/18/15 0.32 1.0 1 ND ND 0.88 J ND ND ND 0.46 J ND ND ND ug/L 09/23/15 0.32 1.0 1 ND ND 0.98 J ND ND ND ND ND ND ND ND ug/L 03/15/16 0.32 1.0 1 ND ND 0.93 J ND ND ND ND ND 0.46 J ND 0.56 J ND ND ug/L 06/29/16 0.32 1.0 1 ND ND ND ND ND ND ug/L 09/21/16 0.32 1.0 1 ND ND 0.74 J ND ND ND ND ND ND ND ND ND ug/L 12/19/16 0.32 1.0 1 ND ND ND ND ND ND ug/L 03/21/17 0.32 1.0 1 ND ND 0.92 J ND ND ND ND ND ND ND ND ND ug/L 06/21/17 0.32 1.0 1 ND ND ND ND ND ND ug/L 09/20/17 0.32 1.0 1 ND ND 0.73 J ND ND ND ND ND ND ND ND ND ug/L 12/19/17 0.32 1.0 1 ND ND ND ND ND ND ug/L 03/21/18 0.32 1.0 1 ND ND 0.51 J ND ND ND ND ND ND ND ND ND ug/L 06/15/18 0.32 1.0 1 ND ND ND ND ND ND ug/L 09/24/18 0.32 1.0 ND ND ND ND ND ND ND ND ND ND ND ND ug/L 12/20/18 0.32 1.0 ND ND ND ND ND ND ug/L 03/26/19 0.32 1.0 ND ND 0.51 J ND ND ND ND ND ND ND ND ND ug/L 09/18/19 0.32 1.0 ND ND ND ND ND ND ND ND ND ND ND Notes: J = Following the The November 2018 event, J flags are estimated values between the MDL and PQL. Prior to the November 2018 event, J flags are estimated values below the SWS Reporting limit. B = Blank -qualified result MDL = laboratory method detection limit PQL = practical quantitation limit Blanks = field, trip and method blanks Bold = concentrations above the NC 2L Groundwater Standards or Solid Waste Section Groundwater Protection Standards (SWS GPS) have been bolded Shaded = concentrations above the EPA Maximum Contaminant Level (MCL) has been shaded SWS Reporting Limit = NCPQL or lab -specific reporting limit prior to October 2007 and NCSWSL starting in October 2007 EPA MCL = US Environmental Protection Agency Maximum Contaminant Level NC 2L = North Carolina 2L Groundwater Standard GOLDER 6 of 6 Figures 3 B ri 0 Q rn co cm 00 0 ai m z a) cm M MI L Q a U g 3 0 Q E Y 0 g U a m CLIENT HENDERSON COUNTY CONSULTANT YYYY-M M-D D DESIGNED GO L D E R PREPARED REVIEWED 2019-10-15 NTT SIB DYR GOLDER ASSOCIATES NC, INC. APPROVED RPK LEGEND EXISTING 10 FT. CONTOUR EXISTING 2 FT. CONTOUR PROPERTY LINE LIMITS OF WASTE STREAM BUFFER TREELINE EXISTING ROAD X-X-X- FENCE GROUNDWATER SURFACE CONTOURS APPROXIMATE GROUNDWATER FLOW SEGMENT USED TO CALCULATE GRADIENT G1 MW-8 COMPLIANCE GROUNDWATER MONITORING WELL AND IDENTIFICATION O 2211.82 MW-1 NON COMPLIANCE GROUNDWATER MONITORING WELL AND IDENTIFICATION 2199.24 - MP-8 COMPLIANCE METHANE MONITORING WELL AND IDENTIFICATION MP-6 ASSESSMENT COMPLIANCE METHANE MONITORING WELL AND IDENTIFICATION ❑ BR-1 SURFACE WATER MONITORING POINT AND IDENTIFICATION O IW-1 INJECTION WELL AND IDENTIFICATION 2178.02 NM NOT MEASURED NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET 2. GROUNDWATER SURFACE CONTOUR INTERVAL = 20 FEET 3. GROUNDWATER ELEVATIONS MEASURED ON SEPTEMBER 18, 2019. 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. THEREFORE GROUNDWATER CONTOURS MAY NOT REFLECT ACTUAL CONDITIONS. 5. GROUNDWATER CONTOUR LINES SHOW THE WATER TABLE SHAPE AND ELEVATION. THESE CONTOURS ARE INFERRED LINES FOLLOWING THE GROUNDWATER SURFACE AT A CONSTANT ELEVATION ABOVE SEA LEVEL 6. COORDINATE SYSTEM IS N.C. STATE PLANE GRID. 7. TOPOGRAPHIC DIVIDING LINE DIVIDES THE BASE MAP TOPOGRAPHIC CONTOURS FROM LANDSAT TOPOGRAPHIC CONTOURS. LANDSAT TOPOGRAPHIC CONTOURS HAVE A 5-CONTOUR INTERVAL. 8. LOCATION OF COMPLIANCE METHANE MONITORING WELL MP-4 IS APPROXIMATE. REFERENCES 1. BASE MAP PROVIDED BY CAMP DRESSER & McKEE FROM PREVIOUS WATER QUALITY MONITORING REPORTS. 0 200 400 SCALE FEET PROJECT HENDERSON COUNTY CLOSED MSW AND C&D LANDFILL PERMIT # 45-01 TITLE GROUNDWATER SURFACE CONTOUR MAP SEPTEMBER 18, 2019 PROJECT NO. PHASE REV. FIGURE 19-128179 101 0 1 c c APPENDIX A Groundwater and Surface Water Sampling Logs CLOSED MSW LANDFILL September 2019 Compliance, MNA, and Post -Injection Monitoring Event hr ,,> GOLDER Project Name: Well ID: Well Diameter: Depth to Bottom: Pumping Rate: Well Location: DATE. `77 _ / f _/1 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: 19128179 w ' Sampler(s): T. Martinez 2 inches Initial Depth to Water: Ll. feet feet Water Column Thickness: Z Y. 7Y feet mUmin. System Volume: 13 Ll'00 mL Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) �M--cu-4/cm) Sp. Cond. �__(_M_9/L) • • • u .. r • '----- Comments (weather condition color, type of sample, purge -water management, etc.): 'Weather: ®verY66t d '7o` t' Begin purging @ C 8Ll Signature: QA/QC Sign Off: Date: '? `/,f - / q Date: I - Va -'LG �,�> GOLDER Project Name: Henderson County LF Well ID: M 1- 6 Well Diameter: 2 inches Depth to Bottom: I It, &A> feet Pumping Rate: 6 j mUmin. DATE: 9'1? `l c GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): T. Martinez Initial Depth to Water: , Z feet Water Column Thickness: 4, jeq feet System Volume: 9-2 mL Well Location: Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: 1 54 �- Rc,h Beqin nurginci (cD I0 Signature: QA/QC Sign Off: Date: Date: 1 - 12 -2-0 GOLDER Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: Well Location: DATE: 9-/?-/.7 GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: 19128179 w --7 Sampler(s): T. Martinez 2 inches Initial Depth to Water: a feet 2 ' ti feet Water Column Thickness: feet �C:y mUmin. System Volume: 1 Sy mL Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 NdpRh • • • , is • • _Jm • • M®IKUK mg rl`1� y M • Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: overc4S } (obr Signature: QA/QC Sign Off: Date.. -I q Date: l- /2 - 2_V GOLDER Project Name: HencJerson County LF Well ID: Well Diameter: 2 Inches Depth to Bottom: Qr feet Pumping Rate: 130 mUmin. Well Location: Equipment: YSI RFe-Plus urbidimeter, Water DATE: qC y I GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): E. Vasko Initial Depth to Water: Z i0 S feet Water Column Thickness: 6 7 feet System Volume: I 1 '�; mL level meter, dedicated bladder pump, MP15 +/- a 1 +/- 5% <1 n +/- 1 n% nr n 9 +i_ in rriAan Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: 0t,4Aras Begin purging Signature: �'a " _ Date: / — (F m QA/QC Sign Off: Date: 1- 12.-2,o ra GOLDER Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: Well Location: Henderson County LF An, I- - is 2 inches -2 `f. 5 feet 'LO Q mUmin. DATE: 9- / ? -/ 7 GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): T. Martinez Initial Depth to Water: (S . o 0 feet Water Column Thickness: 1_ � la feet System Volume: 11 -7 O mL Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +1- 10% or 0.2 +/- 10 (HPAl Dis • • Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: Over(ti St Begin purging @ \ D Signature: Date: QA/QC Sign Off: Date: y GOLDER Project Name: Henderson County LF Well ID: mow- I Q Well Diameter: 2 inches Depth to Bottom: 2.7 q feet Pumping Rate: Zg0 7Zya mUmin. Well Location: Equipment: DATE: 9— /� - GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): T. Martinez Initial Depth to Water: S, feet Water Column Thickness: 4}. feet System Volume: 1 Z 4 ? mL YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0,1 +/- 5% <10 +/- 10% or 02 +1- 10 liripnh Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: 0 6,1,.qy Beain Duraina (cD 14,? o Signature: QA/QC Sign Off: Date: Date: GOLDER Project Name: Henderson County LF Well ID: A Kvvi . 2 Well Diameter: 2 inches Depth to Bottom: Z 5 < 0 feet Pumping Rate: `LSO mUmin. Well Location: U� DATE: GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): E. Vasko Initial Depth to Water: 4- feet Water Column Thickness: G5, 4 Z feet System Volume: i (3 2-- mL Equipment: YSI PFe42ktk, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: O V &-cAS-i - Begin purging @ i2 $2 Signature: �"" �� Date: q— Cy- C q QA/QC Sign Off: Date: / - I Z - Z v GOLDER Project Name: Nkc,4 aq C.G. L Well ID: 0, w - Z b Well Diameter: 'L inches Depth to Bottom: Z. & Z feet Pumping Rate: 'Z0-0, mUmin. Well Location: DATE: q (r' f '( GROUNDWATER SAMPLING LOG Project No./Phaseo.: Sampler(s). C..V p Initial Depth to Water: 2 feet Water Column Thickness: feet System Volume: 1671 mL Equipment: ?S I SSG,, 4 U_ twe 14 r AP IS' +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) �MFr,�� 1� Dis • affl� Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: O�j t(-caS} Beqin puminq Cad (SSA Signature: -u/� (� Date: 4 — ( 0 1 l QA/QC Sign Off: Date: / - 12 - 2,,C GOLDER Project Name: Henderson County LF Well ID: 0 )w- z Well Diameter: 2 inches Depth to Bottom: feet Pumping Rate: U mUmin. Well Location: Equipment: DATE: q-i J (� GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): E. Vasko Initial Depth to Water: q bo feet Water Column Thickness: feet System Volume: (C)71 mL eter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: 0 \jkMa5* - Begin purging @ JC)S''l Signature: W J�� QA/QC Sign Off: Date: Date: !- / 2.2 0 ;� GOLDER DATE: SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: 19128179 Sample ID: l3P.-1 Sampler(s): N c LA-,& -T? Sampling Location: Equipment: YSl Pro Plus, Turbidimeter Time i pH S.U. p. Cond. US/cm Tu rb. ntu tei.S Dis.OZ _ m /L �•�� Temp. °C l't3 ORP my R Surface Water Sampling Location Sketch Comments (sample methodology, weather conditions, color, silt, etc.): Signature: Date: q-.1-8-_Tq QA/QC Sign Off: Date: (- !2- 2-6 DATE: �_( JC( ki G O L D E R SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: 19128179 Sample ID: F jz-2 Sampler(s): 17 U Sampling Location: Equipment: YSl Pro Plus, Turbidimeter Time )S35 pH S.U. 7 it Sp. Cond. US/cm % b$ 0 Tu rb. ntu �^p UT_ Dis. OZ mg/L 1-7 Temp. ORP my 2 /bus NO - Surface Water Sampling Location Sketch Comments (sample methodology, weather conditions, color, silt, etc.): GGa d r I0,,j Ousvcusf Signature: c V QA/QC Sign Off: Glw Date: Date: t , _ p DATE: (— I z —t SURFACE WATER SAMPLING LOG GOLDER Project Name: &*&5c L Cc Lli� Project No./Phase No.: 1 R (ZB P R/ Sample ID: (Z- 3 Sampler(s): F, Sampling Location: A1eXt -o /i yg'Lj--LS & _ � Equipment: � 5)SS 6. Park Z(BB Q Time to s pH S.U. o% Sp. Cond. US/cm Turb. NTU Z , Dis. OZ mg/L Temp. *C c , -3 Q( ORP mV `�— Surface Water Location Sketch ER- Comments (sample methodology, weather conditions, color, silt, etc.): Weather: 0IJe,('cn as-�- Signature:y 1%Date QA/QC Sign Off: Date 9-cam (q L-t2 - z. o 66e, GOLDER DATE: _ , (F-' SURFACE WATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: 19128179 Sample ID: S ( Sampler(s): Sampling Location: Equipment: YSI Pro Plus, Turbidimeter Surface Water Sampling Location Sketch Time ISO pH SM. ~7�3� Sp. Cond. us/cm 37 C Turb. ntu 47] Dis. OZ m /L S,3 rt Temp. oC l�tZ3 ORP my s(. Commen (sample methodology, weather conditions, color, silt, etc.): C�Ccd Hc'v" 0� c: ccrSd' Signature: Date: QA/QC Sign Off: Date: ) - I Z . t,v CLOSED C&D LANDFILL September 2019 Compliance Monitoring Event GOLDER Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: Well Location: Henderson County LF M Iv - I 2 inches 3`l.6 feet '2-oo mL/min DATE: 9 - / 9 '/ � GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): T. Martinez Initial Depth to Water: "' 2. feet Water Column Thickness: 6 q 5 feet System Volume: 12 7 © mL Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 5°/ <1 n +i- 1 nai nr n 9 +r_ 1 n (A—h • ' �L'R.�®�'a�����E'>�����®tea �� ► s !►lIIIIF��®�®�® Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: OV e r(4sl_ Beqin oumina 0 ©cry 10 Signature: QA/QC Sign Off: Date: C?- / C/ -1 / Date: / - /2 -Z,0 ,.� GOLDER Project Name: Well ID: _ Well Diameter: Depth to Bottom: Pumping Rate: Well Location: DATE. ?-/ 9' /? GROUNDWATER SAMPLING LOG Henderson County LF Project No./Phase No.: 19128179 M 1,-! ► Sampler(s): T. Martinez 2 inches Initial Depth to Water: feet �� ;70 feet Water Column Thickness: feet -2d0 mL/min. System Volume: >,4 4 �l O 7 mL Equipment: YSI Pro Plus, Turbidimeter, Water level meter, dedicated bladder pump, MP15 +/- 0.1 +/- 5% <10 +/- 101/ or 0 ? �Moffime?* ldmm�� NEW,=�® Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: oyeactsf n ourai Signature: QA/QC Sign Off: Date: Date: G- /2 -'La GOLDER DATE: C' g— I 1 GROUNDWATER SAMPLING LOG Project Name: Henderson County LF Project No./Phase No.: 19128179 Well ID: A W- / 2 Sampler(s): E. Vasko Well Diameter: 2 inches Initial Depth to Water: i3l A feet Depth to Bottom: 6c , 06 feet Water Column Thickness: _Z, 9 feet Pumping Rate: /c (3 mUmin. System Volume: mL Well Location: Equipment: YSI Turbidimeter, Water level meter, dedicated bladder pump, MP15 ss6 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) • Cond. ' ' • go Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: d Ve-�-c,5 -�-- Z Signature: U2G QA/QC Sign Off: ooe Date: 4 lq (-r Date: GOLDER Project Name: Henderson County LF Well ID: Well Diameter: 2 inches Depth to Bottom: feet Pumping Rate: mL/min. Well Location: DATE: I" ( q' I q GROUNDWATER SAMPLING LOG Project No./Phase No.: 19128179 Sampler(s): E. Vasko Initial Depth to Water: 3Y 2 feet Water Column Thickness: 2, z.2 feet System Volume: 121 Z mL Equipment: YS/ , Turbidimeter, Water level meter, dedicated bladder pump, MP15 S5S6 +/- 0.1 +/- 5% <10 +/- 10% or 0.2 +/- 10 (ideal) • � � �i����i� � ■�� � � is Comments (weather conditions, color, type of sample, purge -water management, etc.): Weather: dvy's-cG {— Begin purging @ 0 (, Signature: U �'`l� Date:'l �' l QA/QC Sign Off: Date: APPENDIX B September 2019 Groundwater and Surface Water Certificates -of - Analysis, Chain -of -Custody Forms and Laboratory Data Review CLOSED MSW LANDFILL September 2019 Compliance Monitoring Event ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Friday, October 4, 2019 Golder Associates, Inc. (GO007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 19128179.101, Project Name/Desc: Henderson Co. LF ENCO Workorder(s): CC13963 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, September 20, 2019. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, �"n'1 Meghan K Shea Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of rJ3 PROJECT NARRATIVE Date: 04 October 2019 Client: Golder Associates, Inc. (GO007) Project: Henderson Co. LF Lab ID: CC13963 Overview (� �Eo www.encolabs.com Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in the QC Remarks section below. Quality Control Samples Chloromethane bias low in associated QC but can be detected in the CRL. Since the analyte in 4501-MW5 (Background), 4501-MW6, 4501-MW7, 4501-AMW1S, 4501-AMW1D, 4501-AMW2S, 4501-AMW2D, 4501-BR1, 4501-BR2, 4501-BR3, 4501-SW1 and 4501-Field Blank was not detected, there is no impact on data quality. Iron and Manganese post -digestion spikes did not meet method requirements due to confirmed matrix effects. Precision between 8151 A 2,4 D duplicate matrix spikes of the same sample was outside acceptance limits. The QC batch was accepted based on acceptable LCS recoveries. The Iron and Manganese spike recoveries were outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recoveries. The method blank had a positive result for 1,4-Dioxane; however, the concentration in the method blank is less than 10% of the sample result for 4501-MW6. There is minimal impact to the data. The method blank contains 1,4-Dioxane at the concentration above the MDL and/or greater than one-half the MRL. The analyte was not detected in 4501-MW5 (Background) and 4501-AMW1S, there is no impact. The Vinyl acetate associated laboratory control sample exhibited high bias; since 4501-BR2, 4501-BR3 and 4501-SW1 are non -detect, there is no impact. The Vinyl acetate associated continuing calibration verification standard exhibited high bias; since 4501-MW5 (Background), 4501-MW6, 4501-MW7, 4501-AMW1S, 4501-AMW1D, 4501-AMW2S, 4501-AMW2D, 4501-BR1 and 4501-Field Blank were non -detect, there is no impact. Quality Control Remarks No Comments Other Comments All samples received under this work order arrived in acceptable conditions. The samples were not checked for residual chlorine, as it is not required. The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of the report. Released By: Environmental Conservation Laboratories, Inc. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 of 53 (� �Eo www.encolabs.com Meghan Shea Project Manager FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 of 53 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-MW5 (Background) Lab ID: CC13963-01 Sampled: 09/18/19 09:07 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:34 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 11:57 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 13:42 EPA 8260D EPA 503013_MS 10/02/19 10/01/19 11:34 10/01/19 21:29 EPA 8260D EPA 503013_MS 10/02/19 10/01/19 16:37 10/02/19 03:12 Client ID: 4501-MW6 Lab ID: CC13963-02 Sampled: 09/18/19 11:00 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:44 EPA 6020E EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:15 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 13:44 EPA 8260D EPA 503013_MS 10/02/19 10/01/19 11:34 10/01/19 22:00 EPA 8260D EPA 503013_MS 10/02/19 10/01/19 16:37 10/02/19 03:50 Client ID: 4501-MW7 Lab ID: CC13963-03 Sampled: 09/18/19 12:25 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:46 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:19 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 13:52 EPA 8260D EPA 503013_MS 10/02/19 10/01/19 11:34 10/01/19 22:32 Client ID: 4501-MW7 Lab ID: CC13963-03RE1 Sampled: 09/18/19 12:25 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 503013_MS 10/02/19 10/02/19 00:00 10/02/19 14:44 Client ID: 4501-MW8 (MS/MSD) Lab ID: CC13963-04 Sampled: 09/18/19 09:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:18 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 10:15 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 12:55 EPA 8260D EPA 503013_MS 10/02/19 09/27/19 15:58 09/27/19 21:14 Client ID: 4501-MW8 (MS/MSD) Lab ID: CC13963-04RE1 Sampled: 09/18/19 09:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 5030B_MS 10/02/19 10/02/19 00:00 10/02/19 15:21 Client ID: 4501-AMWlS Lab ID: CC13963-06 Sampled: 09/18/19 13:22 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:49 EPA 6020E EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:23 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 13:54 EPA 8260D EPA 503013_MS 10/02/19 09/27/19 15:56 09/28/19 11:33 EPA 8260D EPA 5030B_MIS 10/02/19 10/01/19 16:37 10/02/19 05:06 Client ID: 4501-AMWlD Lab ID: CC13963-07 Sampled: 09/18/19 14:35 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:51 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:28 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 13:57 EPA 8260D EPA 503013_MS 10/02/19 09/27/19 15:56 09/28/19 12:05 Client ID: 4501-AMWID Lab ID: CC13963-07RE1 Sampled: 09/18/19 14:35 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 5030B_MS 10/02/19 10/02/19 00:00 10/02/19 16:00 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 53 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-AMW2S Lab ID: CC13963-08 Sampled: 09/18/19 13:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:54 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:32 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 14:01 EPA 8260D EPA 503013_MS 10/02/19 09/27/19 15:56 09/28/19 12:36 Client ID: 4501-AMW2S Lab ID: CC13963-08RE1 Sampled: 09/18/19 13:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 5030B_MS 10/02/19 10/02/19 00:00 10/02/19 16:36 Client ID: 4501-AMW2D Lab ID: CC13963-09 Sampled: 09/18/19 14:35 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:57 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:34 09/25/19 12:36 EPA 7470A EPA 7470A 10/16/19 09/25/19 10:52 09/26/19 14:03 EPA 8260D EPA 503013_MS 10/02/19 09/27/19 15:56 09/28/19 13:07 Client ID: 4501-AMW2D Lab ID: CC13963-09RE1 Sampled: 09/18/19 14:35 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 503013_MS 10/02/19 10/02/19 00:00 10/02/19 17:15 Client ID: 4501-BR1 Lab ID: CC13963-10 Sampled: 09/18/19 15:10 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 13:59 EPA 6020E EPA 3005A 03/16/20 09/24/19 11:38 09/25/19 13:19 EPA 8260D EPA 5030B_MS 10/02/19 09/27/19 15:56 09/28/19 13:38 Client ID: 4501-BR1 Lab ID: CC13963-10RE1 Sampled: 09/18/19 15:10 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 8260D EPA 5030B_MS 10/02/19 10/02/19 00:00 10/02/19 17:53 Client ID: 4501-13112 Lab ID: CC13963-11 Sampled: 09/18/19 15:35 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 14:02 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:38 09/25/19 13:23 EPA 8260D EPA 503013_MS 10/02/19 09/30/19 09:55 09/30/19 15:02 EPA 8260D EPA 5030B_MS 10/02/19 10/02/19 00:00 10/02/19 12:22 Client ID: 4501-BR3 Lab ID: CC13963-12 Sampled: 09/18/19 14:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 14:04 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:38 09/25/19 13:28 EPA 8260D EPA 503013_MS 10/02/19 09/30/19 09:55 09/30/19 15:34 EPA 8260D EPA 503013_MS 10/02/19 10/02/19 00:00 10/02/19 12:55 Client ID: 4501-SW1 Lab ID: CC13963-13 Sampled: 09/18/19 15:05 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/16/20 09/24/19 11:14 09/25/19 14:07 EPA 6020B EPA 3005A 03/16/20 09/24/19 11:38 09/25/19 13:32 EPA 8260D EPA 5030B_MIS 10/02/19 09/30/19 09:55 09/30/19 16:05 EPA 8260D EPA 503013_MS 10/02/19 10/02/19 00:00 10/02/19 13:29 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) Of rJ3 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-Field Blank Lab ID: CC13963-14 Sampled: 09/19/19 11:00 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 03/17/20 09/24/19 11:14 09/25/19 14:17 EPA 6020B EPA 3005A 03/17/20 09/24/19 11:38 09/25/19 13:36 EPA 7470A EPA 7470A 10/17/19 09/25/19 10:52 09/26/19 14:05 EPA 8151A EPA 3510C 09/26/19 11/03/19 09/24/19 22:22 09/26/19 15:21 EPA 8260D EPA 5030B_MS 10/03/19 10/01/19 11:34 10/01/19 17:51 EPA 8260D EPA 5030B_MS 10/03/19 10/02/19 00:00 10/02/19 18:32 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of rJ3 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 4501-MW5 (Background) Lab ID: CC13963-01 Anala Results Flag MDL POLL Units Method Notes Barium - Total 27.9 1.10 10.0 ug/L EPA 6010D Copper - Total 1.78 1 1.60 10.0 ug/L EPA 6010D Client ID: 4501-MW6 Lab ID: CC13963-02 Anala Results Flag MDL POLL Units Method Notes 1,2-Dichlorobenzene 3.2 0.19 1.0 ug/L EPA 8260D 1,4-Dichlorobenzene 14 0.19 1.0 ug/L EPA 8260D 1,4-Dioxane 35 B 1.2 2.0 ug/L EPA 8260D QB-01 Barium - Total 563 1.10 10.0 ug/L EPA 6010D Benzene 4.3 0.15 1.0 ug/L EPA 8260D Chlorobenzene 8.4 0.17 1.0 ug/L EPA 8260D Copper - Total 1.81 1 1.60 10.0 ug/L EPA 6010D Ethylbenzene 0.51 1 0.13 1.0 ug/L EPA 8260D Nickel - Total 4.32 1 2.20 10.0 ug/L EPA 6010D Toluene 12 0.14 1.0 ug/L EPA 8260D Zinc - Total 5.24 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-MW7 Lab ID: CC13963-03 Anala Results Flag MDL POLL Units Method Notes 1,2-Dichlorobenzene 0.64 1 0.19 1.0 ug/L EPA 8260D 1,4-Dichlorobenzene 12 0.19 1.0 ug/L EPA 8260D Barium - Total 558 1.10 10.0 ug/L EPA 6010D Cadmium - Total 0.387 1 0.360 1.00 ug/L EPA 6010D Chlorobenzene 8.3 0.17 1.0 ug/L EPA 8260D Cobalt - Total 4.89 1 1.40 10.0 ug/L EPA 6010D Thallium - Total 0.376 1 0.220 2.00 ug/L EPA 6020B Zinc - Total 4.52 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-MW7 Lab ID: CC13963-03RE3 Anala Results Flag MDL POLL Units Method Notes 1.4-Dioxane 13 1.2 2.0 ua/L EPA 8260D I Client ID: 4501-MWS (MS/MSD) Lab ID: CC13963-04 Anala Results Flag MDL POLL Units Method Notes Barium - Total 669 1.10 10.0 ug/L EPA 6010D Cobalt - Total 7.39 1 1.40 10.0 ug/L EPA 6010D Thallium - Total 0.485 1 0.220 2.00 ug/L EPA 6020B Zinc - Total 24.0 4.40 10.0 ug/L EPA 6010D Client ID: 4501-MW8 (MS/MSD) Lab ID: CC13963-04RE3 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 1.9 1 1.2 2.0 ug/L EPA 8260D Client ID: 4501-AMWlS Lab ID: CC13963-06 Anala Results Flag MDL POLL Units Method Notes Barium - Total 284 1.10 10.0 ug/L EPA 6010D Beryllium - Total 1.66 0.160 1.00 ug/L EPA 6010D Cadmium - Total 1.97 0.360 1.00 ug/L EPA 6010D Cobalt - Total 6.08 1 1.40 10.0 ug/L EPA 6010D Copper - Total 1.65 1 1.60 10.0 ug/L EPA 6010D Thallium - Total 0.322 1 0.220 2.00 ug/L EPA 6020B Zinc - Total 5.23 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-AMWlD Lab ID: CC13963-07 Anala Results Flag MDL POLL Units Method Notes 1,2-Dichlorobenzene 0.46 1 0.19 1.0 ug/L EPA 8260D 1,4-Dichlorobenzene 2.8 0.19 1.0 ug/L EPA 8260D Barium - Total 17.2 1.10 10.0 ug/L EPA 6010D Benzene 0.68 1 0.15 1.0 ug/L EPA 8260D Chlorobenzene 4.9 0.17 1.0 ug/L EPA 8260D cis-1,2-Dichloroethene 0.50 1 0.15 1.0 ug/L EPA 8260D Copper - Total 2.21 1 1.60 10.0 ug/L EPA 6010D Zinc - Total 7.42 1 4.40 10.0 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 53 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 4501-AMWlD Lab ID: CC13963-07RE3 Anala 1,4-Dioxane Results 8.5 Flag MDL 1.2 POLL 2.0 Units ug/L Method EPA 8260D Notes Client ID: 4501-AMW2S Lab ID: CC13963-08 Anala 1,1-Dichloroethane Barium - Total Chlorobenzene cis-1,2-Dichloroethene Mercury - Total Results 0.58 4.03 0.49 0.40 0.487 Flag 1 1 1 1 MDL 0.13 1.10 0.17 0.15 0.150 POLL 1.0 10.0 1.0 1.0 0.200 Units ug/L ug/L ug/L ug/L ug/L Method EPA 8260D EPA 6010D EPA 8260D EPA 8260D EPA 7470A Notes Client ID: 4501-AMW2S Lab ID: CC13963-08RE3 Anala 1,4-Dioxane Results 2.6 Flag MDL 1.2 POLL 2.0 Units ug/L Method EPA 8260D Notes Client ID: 4501-AMW2D Lab ID: CC13963-09 Anala Barium - Total Results 2.87 Flag 1 MDL 1.10 POLL 10.0 Units ug/L Method EPA 6010D Notes Client ID: 4501-AMW2D Lab ID: CC13963-09RE3 Anala 1,4-Dioxane Results 2.2 Flag MDL 1.2 POLL 2.0 Units ug/L Method EPA 8260D Notes Client ID: 4501-BR1 Lab ID: CC13963-10 Anala Results Flag MDL POLL Units Method Notes Barium - Total 38.1 1.10 10.0 ug/L EPA 6010D Zinc - Total 4.89 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-BR1 Lab ID: CC13963-30RE1 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 2.1 1.2 2.0 ug/L EPA 8260D Client ID: 4501-BR2 Lab ID: CC13963-11 Anala Results Flag MDL POLL Units Method Notes 1,2-Dichlorobenzene 0.29 1 0.19 1.0 ug/L EPA 8260D 1,4-Dioxane 8.0 1.2 2.0 ug/L EPA 8260D Barium - Total 168 1.10 10.0 ug/L EPA 6010D Cobalt - Total 1.55 1 1.40 10.0 ug/L EPA 6010D Zinc - Total 4.93 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-BR3 Lab ID: CC13963-12 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 1.8 1 1.2 2.0 ug/L EPA 8260D Barium - Total 103 1.10 10.0 ug/L EPA 6010D Cobalt - Total 1.45 1 1.40 10.0 ug/L EPA 6010D Copper - Total 2.45 1 1.60 10.0 ug/L EPA 6010D Zinc - Total 15.8 4.40 10.0 ug/L EPA 6010D Client ID: 4501-SW3 Lab ID: CC13963-13 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 2.8 1.2 2.0 ug/L EPA 8260D Barium - Total 29.6 1.10 10.0 ug/L EPA 6010D Copper - Total 2.23 1 1.60 10.0 ug/L EPA 6010D Zinc - Total 4.64 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-Field Blank Lab ID: CC13963-14 Anala Results Flag MDL POLL Units Method Notes Barium - Total 3.97 1 1.10 10.0 ug/L EPA 6010D Copper - Total 5.73 1 1.60 10.0 ug/L EPA 6010D Iron - Total 26.9 1 22.0 50.0 ug/L EPA 6010D Manganese - Total 1.59 1 1.50 10.0 ug/L EPA 6010D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW5 (Background) Lab Sample ID:CC13963-01 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 09:07 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 21:29 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9301011 EPA 8260D 10/01/19 21:29 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9301011 EPA 8260D 10/01/19 21:29 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9301011 EPA 8260D 10/01/19 21:29 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9301011 EPA 8260D 10/01/19 21:29 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9301011 EPA 8260D 10/01/19 21:29 REF Benzene[71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9301011 EPA 8260D 10/01/19 21:29 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Chlorobenzene[108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 21:29 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 21:29 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Ethylbenzene[100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9301011 EPA 8260D 10/01/19 21:29 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Styrene[100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 21:29 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 21:29 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 21:29 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9301011 EPA 8260D 10/01/19 21:29 REF QV-01 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9301011 EPA 8260D 10/01/19 21:29 REF Xylenes (Total) [1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9301011 EPA 8260D 10/01/19 21:29 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW5 (Background) Lab Sample ID:CC13963-01 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 09:07 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 44 1 50.0 87 % 53-136 9J01011 EPA 8260D 10101119 21:29 REF Dibromofluoromethane 48 1 50.0 95 % 67-129 9J01011 EPA 8260D 10101119 21:29 REF Toluene-& 37 1 50.0 74 % 59-134 9J01011 EPA 8260D 10101119 21:29 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 13:42 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 11:57 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Barium [7440-39-3]^ 27.9 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:34 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:34 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Copper[7440-50-8]^ 1.78 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 11:57 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Zinc[7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:34 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1.2 U ug/L 1 1.2 2.0 9301056 EPA 8260D 10/02/19 03:12 mjh QB-02 Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.2 1 5.00 105 % 75-125 9701056 EPA 8260D 10102119 03:12 mjh FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW6 Lab Sample ID:CC13963-02 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 11:00 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,2-Dichlorobenzene [95-50-1]A 3.2 ug/L 1 0.19 1.0 9101011 EPA 8260D 10/01/19 22:00 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9301011 EPA 8260D 10/01/19 22:00 REF 1,4-Dichlorobenzene [106-46-7]A 14 ug/L 1 0.19 1.0 9101011 EPA 8260D 10/01/19 22:00 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9301011 EPA 8260D 10/01/19 22:00 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9301011 EPA 8260D 10/01/19 22:00 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9301011 EPA 8260D 10/01/19 22:00 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9301011 EPA 8260D 10/01/19 22:00 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9301011 EPA 8260D 10/01/19 22:00 REF Benzene [71-43-2]A 4.3 ug/L 1 0.15 1.0 9101011 EPA 8260D 10/01/19 22:00 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9301011 EPA 8260D 10/01/19 22:00 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Chlorobenzene [308-90-7]A 8.4 ug/L 1 0.17 1.0 9101011 EPA 8260D 10/01/19 22:00 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 22:00 REF cis-1,2-Dichloroethene [156-59-2]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:00 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Ethylbenzene [300-41-4]A 0.51 1 ug/L 1 0.13 1.0 9101011 EPA 8260D 10/01/19 22:00 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9301011 EPA 8260D 10/01/19 22:00 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Toluene [108-88-3]A 12 ug/L 1 0.14 1.0 9101011 EPA 8260D 10/01/19 22:00 REF trans- l,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:00 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:00 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9301011 EPA 8260D 10/01/19 22:00 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9301011 EPA 8260D 10/01/19 22:00 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9301011 EPA 8260D 10/01/19 22:00 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW6 Lab Sample ID:CC13963-02 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 11:00 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 45 1 50.0 89 % 53-136 9J01011 EPA 8260D 10101119 22:00 REF Dibromofluoromethane 45 1 50.0 91 % 67-129 9J01011 EPA 8260D 10101119 22:00 REF Toluene-& 38 1 50.0 76 % 59-134 9J01011 EPA 8260D 10101119 22:00 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 13:44 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:15 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Barium [7440-39-3]^ 563 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:44 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:44 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Copper[7440-50-8]^ 1.81 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Nickel[7440-02-O]^ 4.32 J ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:15 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Zinc [7440-66-6]^ 5.24 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:44 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 35 B ug/L 1 1.2 2.0 9301056 EPA 8260D 10/02/19 03:50 mjh QB-01 Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.0 1 5.00 100 % 75-125 9701056 EPA 8260D 10102119 03:50 mjh FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 12 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW7 Lab Sample ID:CC13963-03 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 12:25 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,2-Dichlorobenzene [95-50-1]A 0.64 J ug/L 1 0.19 1.0 9101011 EPA 8260D 10/01/19 22:32 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9301011 EPA 8260D 10/01/19 22:32 REF 1,4-Dichlorobenzene [106-46-7]A 12 ug/L 1 0.19 1.0 9101011 EPA 8260D 10/01/19 22:32 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9301011 EPA 8260D 10/01/19 22:32 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9301011 EPA 8260D 10/01/19 22:32 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9301011 EPA 8260D 10/01/19 22:32 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9301011 EPA 8260D 10/01/19 22:32 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9301011 EPA 8260D 10/01/19 22:32 REF Benzene[71-43-2]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9301011 EPA 8260D 10/01/19 22:32 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Chlorobenzene [108-90-7]A 8.3 ug/L 1 0.17 1.0 9101011 EPA 8260D 10/01/19 22:32 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 22:32 REF cis-1,2-Dichloroethene [156-59-2]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:32 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9301011 EPA 8260D 10/01/19 22:32 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 22:32 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 22:32 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:32 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9301011 EPA 8260D 10/01/19 22:32 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9301011 EPA 8260D 10/01/19 22:32 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9301011 EPA 8260D 10/01/19 22:32 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 13 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW7 Lab Sample ID:CC13963-03 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 12:25 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 44 1 50.0 88 % 53-136 9J01011 EPA 8260D 10101119 22:32 REF Dibromofluoromethane 47 1 50.0 95 % 67-129 9J01011 EPA 8260D 10101119 22:32 REF Toluene-& 37 1 50.0 74 % 59-134 9J01011 EPA 8260D 10101119 22:32 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 13:52 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:19 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Barium [7440-39-3]^ 558 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:46 ]DH Cadmium [7440-43-9]^ 0.387 J ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:46 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Cobalt[7440-48-4]^ 4.89 J ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Thallium [7440-28-0]^ 0.376 J ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:19 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Zinc [7440-66-6]^ 4.52 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:46 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 13 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 14:44 KKW Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.3 1 5.00 106 % 75-125 9702038 EPA 8260D 1010211914:44 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW8 (MS/MSD) Lab Sample ID:CC13963-04 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 09:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9I27032 EPA 8260D 09/27/19 21:14 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9I27032 EPA 8260D 09/27/19 21:14 REF Benzene[71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Chlorobenzene [108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Ethylbenzene [100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Styrene [100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9I27032 EPA 8260D 09/27/19 21:14 REF Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9I27032 EPA 8260D 09/27/19 21:14 REF Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I27032 EPA 8260D 09/27/19 21:14 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW8 (MS/MSD) Lab Sample ID:CC13963-04 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 09:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 50 1 50.0 100 % 53-136 9127032 EPA 8260D 09127119 21:14 REF Dibromofluoromethane 43 1 50.0 86 % 67-129 9127032 EPA 8260D 09127119 21:14 REF Toluene-& 40 1 50.0 79 % 59-134 9127032 EPA 8260D 09127119 21:14 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 12:55 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 10:15 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Barium [7440-39-3]^ 669 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:18 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:18 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Cobalt[7440-48-4]^ 7.39 J ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Thallium [7440-28-0]^ 0.485 J ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 10:15 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Zinc [7440-66-6]^ 24.0 ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:18 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1.9 J ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 15:21 KKW Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.5 1 5.00 109 % 75-125 9702038 EPA 8260D 1010211915:21 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMWlS Lab Sample ID:CC13963-06 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 13:22 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I27031 EPA 8260D 09/28/19 11:33 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I27031 EPA 8260D 09/28/19 11:33 REF Benzene[71-43-2]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Chlorobenzene[108-90-7]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF cis-1,2-Dichloroethene [156-59-2]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I27031 EPA 8260D 09/28/19 11:33 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I27031 EPA 8260D 09/28/19 11:33 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9I27031 EPA 8260D 09/28/19 11:33 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 17 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMWlS Lab Sample ID:CC13963-06 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 13:22 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 45 1 50.0 90 % 53-136 9127031 EPA 8260D 09128119 11:33 REF Dibromofluoromethane 47 1 50.0 93 % 67-129 9127031 EPA 8260D 09128119 11:33 REF Toluene-& 37 1 50.0 73 % 59-134 9127031 EPA 8260D 09128119 11:33 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 13:54 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:23 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Barium [7440-39-3]^ 284 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Beryllium [7440-41-7]^ 1.66 ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:49 ]DH Cadmium [7440-43-9]^ 1.97 ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:49 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Cobalt[7440-48-4]^ 6.08 J ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Copper[7440-50-8]^ 1.65 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Thallium [7440-28-0]^ 0.322 J ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:23 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Zinc [7440-66-6]^ 5.23 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:49 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1.2 U ug/L 1 1.2 2.0 9301056 EPA 8260D 10/02/19 05:06 mjh QB-02 Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.1 1 5.00 102 % 75-125 9701056 EPA 8260D 10102119 05:06 mjh FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 of 553 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMWlD Lab Sample ID:CC13963-07 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 14:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2-Dichlorobenzene [95-50-1]A 0.46 J ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 1,4-Dichlorobenzene [106-46-7]A 2.8 ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I27031 EPA 8260D 09/28/19 12:05 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I27031 EPA 8260D 09/28/19 12:05 REF Benzene [71-43-2]A 0.68 J ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Chlorobenzene [108-90-7]A 4.9 ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF cis-1,2-Dichloroethene [156-59-2]A 0.50 1 ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I27031 EPA 8260D 09/28/19 12:05 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I27031 EPA 8260D 09/28/19 12:05 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9I27031 EPA 8260D 09/28/19 12:05 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 19 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMWlD Lab Sample ID:CC13963-07 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 14:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 43 1 50.0 86 % 53-136 9127031 EPA 8260D 09128119 12:05 REF Dibromofluoromethane 47 1 50.0 93 % 67-129 9127031 EPA 8260D 0912811912:05 REF Toluene-& 37 1 50.0 75 % 59-134 9127031 EPA 8260D 0912811912:05 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 13:57 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:28 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Barium [7440-39-3]^ 17.2 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:51 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:51 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Copper[7440-50-8]^ 2.21 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:28 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Zinc [7440-66-6]^ 7.42 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:51 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 8.5 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 16:00 KKW Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.4 1 5.00 107 % 75-125 9702038 EPA 8260D 1010211916:00 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 20 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMW2S Lab Sample ID:CC13963-08 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 13:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,1-Dichloroethane [75-34-3]A 0.58 1 ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I27031 EPA 8260D 09/28/19 12:36 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I27031 EPA 8260D 09/28/19 12:36 REF Benzene[71-43-2]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Chlorobenzene [108-90-7]A 0.49 J ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF cis-1,2-Dichloroethene [156-59-2]A 0.40 J ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I27031 EPA 8260D 09/28/19 12:36 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I27031 EPA 8260D 09/28/19 12:36 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9I27031 EPA 8260D 09/28/19 12:36 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 21 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMW2S Lab Sample ID:CC13963-08 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 13:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 44 1 50.0 87 % 53-136 9127031 EPA 8260D 09128119 12:36 REF Dibromofluoromethane 47 1 50.0 94 % 67-129 9127031 EPA 8260D 09128119 12:36 REF Toluene-& 37 1 50.0 74 % 59-134 9127031 EPA 8260D 09128119 12:36 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]A 0.487 ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 14:01 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]A 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:32 RLF Arsenic[7440-38-2]A 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Barium [7440-39-3]A 4.03 J ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Beryllium [7440-41-7]A 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:54 ]DH Cadmium [7440-43-9]A 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:54 ]DH Chromium [7440-47-3]A 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Cobalt[7440-48-4]A 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Copper[7440-50-8]A 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Lead [7439-92-1]A 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Nickel[7440-02-0]A 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Selenium [7782-49-2]A 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Silver[7440-22-4]A 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Thallium [7440-28-0]A 0.220 U ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:32 RLF Vanadium [7440-62-2]A 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Zinc[7440-66-6]A 4.40 U ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:54 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte MAS Numberl 1,4-Dioxane [123-91-1]A Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 2.6 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 16:36 KKW Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.4 1 5.00 108 % 75-125 9702038 EPA 8260D 101021191636 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 22 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMW2D Lab Sample ID:CC13963-09 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 14:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I27031 EPA 8260D 09/28/19 13:07 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I27031 EPA 8260D 09/28/19 13:07 REF Benzene[71-43-2]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Chlorobenzene [108-90-7]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF cis-1,2-Dichloroethene [156-59-2]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I27031 EPA 8260D 09/28/19 13:07 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I27031 EPA 8260D 09/28/19 13:07 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9I27031 EPA 8260D 09/28/19 13:07 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 23 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMW2D Lab Sample ID:CC13963-09 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/18/19 14:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 43 1 50.0 86 % 53-136 9127031 EPA 8260D 09128119 13:07 REF Dibromofluoromethane 47 1 50.0 94 % 67-129 9127031 EPA 8260D 09128119 13:07 REF Toluene-& 37 1 50.0 74 % 59-134 9127031 EPA 8260D 09128119 13:07 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 14:03 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24026 EPA 6020E 09/25/19 12:36 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Barium [7440-39-3]^ 2.87 J ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:57 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:57 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24026 EPA 6020E 09/25/19 12:36 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Zinc[7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:57 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte MAS Numberl 1,4-Dioxane [123-91-1]^ Surrogates Toluene-& Results Flag Units DF MDL P L Batch Method Analyzed By Notes 2.2 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 17:15 KKW Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 5.4 1 5.00 108 % 75-125 9702038 EPA 8260D 1010211917:15 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 24 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR1 Lab Sample ID:CC13963-10 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:10 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9I27031 EPA 8260D 09/28/19 13:38 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9I27031 EPA 8260D 09/28/19 13:38 REF Benzene[71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Chlorobenzene [108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Ethylbenzene [100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Styrene [100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9I27031 EPA 8260D 09/28/19 13:38 REF QV-01 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9I27031 EPA 8260D 09/28/19 13:38 REF Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I27031 EPA 8260D 09/28/19 13:38 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 25 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR1 Lab Sample ID:CC13963-10 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:10 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 45 1 50.0 89 % 53-136 9127031 EPA 8260D 09128119 13:38 REF Dibromofluoromethane 47 1 50.0 94 % 67-129 9127031 EPA 8260D 0912811913:38 REF Toluene-& 37 1 50.0 75 % 59-134 9127031 EPA 8260D 091281191338 REF Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020E 09/25/19 13:19 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Barium [7440-39-3]^ 38.1 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 13:59 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 13:59 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020E 09/25/19 13:19 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Zinc [7440-66-6]^ 4.89 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 13:59 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]^ 2.1 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 17:53 KKW Surrogates Results DF Snike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-d8 5.0 1 5.00 100 % 75-125 9702038 EPA 8260D 1010211917:53 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 26 of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR2 Lab Sample ID:CC13963-11 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2-Dichlorobenzene [95-50-1]A 0.29 J ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 U ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I30019 EPA 8260D 09/30/19 15:02 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I30019 EPA 8260D 09/30/19 15:02 REF Benzene [71-43-2]A 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Chlorobenzene [108-90-7]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF cis-1,2-Dichloroethene [156-59-2]A 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Toluene [108-88-3]A 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I30019 EPA 8260D 09/30/19 15:02 REF QL-02 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I30019 EPA 8260D 09/30/19 15:02 REF Xylenes (Total) [1330-20-7]A 0.45 U ug/L 1 0.45 3.0 9I30019 EPA 8260D 09/30/19 15:02 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 27 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR2 Lab Sample ID:CC13963-11 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:35 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 44 1 50.0 87 % 53-136 9130019 EPA 8260D 09130119 15:02 REF Dibromofluoromethane 46 1 50.0 92 % 67-129 9130019 EPA 8260D 0913011915:02 REF Toluene-& 37 1 50.0 74 % 59-134 9130019 EPA 8260D 0913011915:02 REF Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020E 09/25/19 13:23 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Barium [7440-39-3]^ 168 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 14:02 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 14:02 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Cobalt[7440-48-4]^ 1.55 J ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020E 09/25/19 13:23 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Zinc [7440-66-6]^ 4.93 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 14:02 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]^ 8.0 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 12:22 KKW Surrogates Results DF Snike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-d8 5.1 1 5.00 101 % 75-125 9702038 EPA 8260D 10102119 12:22 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 28 of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR3 Lab Sample ID:CC13963-12 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 14:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9I30019 EPA 8260D 09/30/19 15:34 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9I30019 EPA 8260D 09/30/19 15:34 REF Benzene [71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Chlorobenzene [108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Ethylbenzene [100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Styrene [100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9I30019 EPA 8260D 09/30/19 15:34 REF QL-02 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9I30019 EPA 8260D 09/30/19 15:34 REF Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I30019 EPA 8260D 09/30/19 15:34 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 29 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-BR3 Lab Sample ID:CC13963-12 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 14:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 45 1 50.0 90 % 53-136 9130019 EPA 8260D 09130119 15:34 REF Dibromofluoromethane 46 1 50.0 92 % 67-129 9130019 EPA 8260D 0913011915:34 REF Toluene-& 37 1 50.0 74 % 59-134 9130019 EPA 8260D 091301191534 REF Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020E 09/25/19 13:28 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Barium [7440-39-3]^ 103 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 14:04 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 14:04 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Cobalt[7440-48-4]^ 1.45 J ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Copper[7440-50-8]^ 2.45 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020E 09/25/19 13:28 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Zinc [7440-66-6]^ 15.8 ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 14:04 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]^ 1.8 J ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 12:55 KKW Surrogates Results DF Snike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-d8 5.1 1 5.00 101 % 75-125 9702038 EPA 8260D 10102119 12:55 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 30 of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-SW1 Lab Sample ID:CC13963-13 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flan Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9I30019 EPA 8260D 09/30/19 16:05 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9I30019 EPA 8260D 09/30/19 16:05 REF Benzene [71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Chlorobenzene [108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Ethylbenzene [100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Styrene [100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9I30019 EPA 8260D 09/30/19 16:05 REF QL-02 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9I30019 EPA 8260D 09/30/19 16:05 REF Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I30019 EPA 8260D 09/30/19 16:05 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 31 Of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-SW1 Lab Sample ID:CC13963-13 Received: 09/20/19 13:55 Matrix: Surface Water Sampled:09/18/19 15:05 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed Notes 4-Bromofluorobenzene 45 1 50.0 90 % 53-136 9130019 EPA 8260D 09130119 16:05 REF Dibromofluoromethane 45 1 50.0 90 % 67-129 9130019 EPA 8260D 09130119 16:05 REF Toluene-& 36 1 50.0 73 % 59-134 9130019 EPA 8260D 09130119 16:05 REF Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020E 09/25/19 13:32 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Barium [7440-39-3]^ 29.6 ug/L 1 1.10 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 14:07 ]DH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 14:07 ]DH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Copper[7440-50-8]^ 2.23 J ug/L 1 1.60 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020E 09/25/19 13:32 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Zinc [7440-66-6]^ 4.64 J ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 14:07 ]DH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]^ 2.8 ug/L 1 1.2 2.0 9302038 EPA 8260D 10/02/19 13:29 KKW Surrogates Results DF Snike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-d8 5.7 1 5.00 114 % 75-125 9702038 EPA 8260D 1010211913:29 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 32 Of 53 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-Field Blank Lab Sample ID:CC13963-14 Received: 09/20/19 13:55 Matrix: Water Sampled:09/19/19 11:00 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 17:51 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9301011 EPA 8260D 10/01/19 17:51 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9301011 EPA 8260D 10/01/19 17:51 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9301011 EPA 8260D 10/01/19 17:51 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9301011 EPA 8260D 10/01/19 17:51 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9301011 EPA 8260D 10/01/19 17:51 REF Benzene[71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9301011 EPA 8260D 10/01/19 17:51 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Chlorobenzene[108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 17:51 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 17:51 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Ethylbenzene [100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9301011 EPA 8260D 10/01/19 17:51 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Styrene [100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Tetrahydrofuran [109-99-9]^ 0.53 U ug/L 1 0.53 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 17:51 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 17:51 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 17:51 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9301011 EPA 8260D 10/01/19 17:51 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9301011 EPA 8260D 10/01/19 17:51 REF QV-01 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9301011 EPA 8260D 10/01/19 17:51 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 33 of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-Field Blank Lab Sample ID:CC13963-14 Received: 09/20/19 13:55 Matrix: Water Sampled:09/19/19 11:00 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9301011 EPA 8260D 10/01/19 17:51 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 44 1 50.0 89 % 53-136 9701011 EPA 8260D 10101119 17:51 REF Dibromofluoromethane 47 1 50.0 94 % 67-129 9701011 EPA 8260D 1010111917:51 REF Toluene-d8 38 1 50.0 76 % 59-134 9701011 EPA 8260D 10101119 17:51 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25027 EPA 7470A 09/26/19 14:05 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020B 09/25/19 13:36 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Barium [7440-39-3]^ 3.97 J ug/L 1 1.10 10.0 9124024 EPA 6010D 09/25/19 14:17 JDH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24024 EPA 6010D 09/25/19 14:17 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24024 EPA 6010D 09/25/19 14:17 JDH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Copper[7440-50-8]^ 5.73 J ug/L 1 1.60 10.0 9124024 EPA 6010D 09/25/19 14:17 JDH Iron [7439-89-6]^ 26.9 J ug/L 1 22.0 50.0 9124024 EPA 6010D 09/25/19 14:17 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Manganese [7439-96-5]^ 1.59 J ug/L 1 1.50 10.0 9124024 EPA 6010D 09/25/19 14:17 JDH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020B 09/25/19 13:36 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Zinc[7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 9I24024 EPA 6010D 09/25/19 14:17 JDH Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes 1,4-Dioxane [123-91-1]^ 1.2 U ug/L 1 1.2 2.0 9JO2038 EPA 8260D 10/02/19 18:32 KKW Surrogates Results DF So/ke Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes Toluene-d8 5.0 1 5.00 99 % 75-125 9702038 EPA 8260D 10102119 1832 KKW FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 34 of 53 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-Field Blank Lab Sample ID:CC13963-14 Received: 09/20/19 13:55 Matrix: Water Sampled:09/19/19 11:00 Work Order: CC13963 Project: Henderson Co. LF Sampled By:Travis Martinez/ Erik Vaskc Chlorinated Herbicides by GC ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 2,4-D [94-75-7]A 0.27 U ug/L 1 0.27 0.50 9I24050 EPA 8151A 09/26/19 15:21 RGG Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed By Notes 2,4-DC4A 1.3 1 2.00 66 % 37-134 9124050 EPA 6151A 0912611915:21 RGG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 35 of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9127031 - EPA 50308 MS Blank (9I27031-BLK3) Prepared: 09/27/2019 15:56 Analyzed: 09/28/2019 04:48 Analvte Result Flaa POL Units 1, 1, 1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes 4-Bromofluorobenzene Dibromofluoromethane FINAL 43 ug/L 50.0 66 53-136 45 u9/L 50.0 90 67-129 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 36 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9127031 - EPA 50308 MS - Continued Blank (9I27031-BLKi) Continued Prepared: 09/27/2019 15:56 Analyzed: 09/28/2019 04:48 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Toluene-d8 37 u91L 50.0 74 59-134 LCS (9I27031-BSI) Prepared: 09/27/2019 15:56 Analyzed: 09/28/2019 02:44 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 85 75-133 Benzene 19 1.0 ug/L 20.0 97 80-134 Chlorobenzene 18 1.0 ug/L 20.0 91 80-120 Toluene 19 1.0 ug/L 20.0 93 71-120 Trichloroethene 18 1.0 ug/L 20.0 90 74-120 Matrix Spike (9I27031-MS1) Prepared: 09/27/2019 15:56 Analyzed: 09/28/2019 03:15 Source: CC16420-08 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 0.21 U 92 75-133 Benzene 20 1.0 ug/L 20.0 0.15 U 102 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 95 80-120 Toluene 19 1.0 ug/L 20.0 0.14 U 96 71-120 Trichloroethene 19 1.0 ug/L 20.0 0.15 U 97 74-120 Matrix Spike Dup (9I27031-MSD1) Prepared: 09/27/2019 15:56 Analyzed: 09/28/2019 03:46 Source: CC16420-08 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 0.21 U 86 75-133 6 20 Benzene 19 1.0 ug/L 20.0 0.15 U 94 80-134 7 17 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 89 80-120 6 16 Toluene 18 1.0 ug/L 20.0 0.14 U 89 71-120 8 17 Trichloroethene 18 1.0 ug/L 20.0 0.15 U 89 74-120 9 22 Batch 9I27032 - EPA 50308 MS Blank (9I27032-BLK3) Prepared: 09/27/2019 15:58 Analyzed: 09/27/2019 22:19 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1,1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 37 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9I27032 - EPA 50308 MS - Continued Blank (9I27032-BLKi) Continued Prepared: 09/27/2019 15:58 Analyzed: 09/27/2019 22:19 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L 4-Bromofluorobenzene 49 u9/L 50.0 98 53-136 Dlbromofluoromethane 42 u9/L 50.0 84 67-129 Toluene-c48 40 u9/L 50.0 80 59-134 LCS (9I27032-BS1) Prepared: 09/27/2019 15:58 Analyzed: 09/27/2019 19:04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 20 1.0 ug/L 20.0 101 75-133 Benzene 21 1.0 ug/L 20.0 106 80-134 Chlorobenzene 19 1.0 ug/L 20.0 96 80-120 Toluene 20 1.0 ug/L 20.0 100 71-120 Trichloroethene 19 1.0 ug/L 20.0 97 74-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 38 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9127032 - EPA 50308 MS - Continued Matrix Spike (9I27032-MSI) Prepared: 09/27/2019 15:58 Analyzed: 09/27/2019 19:36 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 0.21 U 97 75-133 Benzene 22 1.0 ug/L 20.0 0.15 U 109 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 97 80-120 Toluene 20 1.0 ug/L 20.0 0.14 U 99 71-120 Trichloroethene 19 1.0 ug/L 20.0 0.15 U 97 74-120 Matrix Spike Dup (9I27032-MSD1) Prepared: 09/27/2019 15:58 Analyzed: 09/27/2019 20:09 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 0.21 U 96 75-133 0.6 20 Benzene 21 1.0 ug/L 20.0 0.15 U 107 80-134 2 17 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 93 80-120 3 16 Toluene 20 1.0 ug/L 20.0 0.14 U 98 71-120 2 17 Trichloroethene 19 1.0 ug/L 20.0 0.15 U 94 74-120 3 22 Batch 9I30019 - EPA 50308 MS Blank (9I30019-BLK3) Prepared: 09/30/2019 09:55 Analyzed: 09/30/2019 13:29 Analvte Result Flaq POL Units 1, 1, 1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 39 Of 53 QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9130019 - EPA 50308 145 - Continued (� �Eo www.encolabs.com Blank (9I30019-BLKi) Continued Prepared: 09/30/2019 09:55 Analyzed: 09/30/2019 13:29 Analvte Result Flaq POL Units cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes 4-Bromofluorobenzene 45 u9/L 50.0 89 53-136 Dibromofluoromethane 45 u91L 50.0 89 67-129 Toluene-d8 37 u9/L 50.0 74 59-134 LCS (9I30019-BS1) Prepared: 09/30/2019 09:55 Analyzed: 09/30/2019 11:24 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 90 75-133 Benzene 20 1.0 ug/L 20.0 98 80-134 Chlorobenzene 18 1.0 ug/L 20.0 91 80-120 Toluene 18 1.0 ug/L 20.0 89 71-120 Trichloroethene 17 1.0 ug/L 20.0 84 74-120 Matrix Spike (9I30019-MS1) Prepared: 09/30/2019 09:55 Analyzed: 09/30/2019 11:55 Source: CC16420-07 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 0.21 U 91 75-133 Benzene 20 1.0 ug/L 20.0 0.15 U 102 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 93 80-120 Toluene 19 1.0 ug/L 20.0 0.14 U 93 71-120 Trichloroethene 18 1.0 ug/L 20.0 0.15 U 89 74-120 Matrix Spike Dup (9I30019-MSD1) Prepared: 09/30/2019 09:55 Analyzed: 09/30/2019 12:26 Source: CC16420-07 Spike Analvte Result Flaa POL Units Level 1,1-Dichloroethene 18 1.0 ug/L 20.0 Benzene 20 1.0 ug/L 20.0 Chlorobenzene 19 1.0 ug/L 20.0 Toluene 18 1.0 ug/L 20.0 Trichloroethene 18 1.0 ug/L 20.0 Source %REC Result %REC Limits 0.21 U 90 75-133 0.15 U 98 80-134 0.17 U 93 80-120 0.14 U 92 71-120 0.15 U 88 74-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. RPD RPD Limit Notes 0.6 20 3 17 0.1 16 1 17 0.8 22 Page 40 of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9101011 -EPA 5030B MS Blank (9301011-BLK3) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 15:45 Analvte Result Flaq POL Units 1, 1, 1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Tetrahydrofuran 0.53 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes 4-Bromofluorobenzene FINAL 44 ug/L 50.0 87 53-136 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 41 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9J01011 - EPA 5030E MS - Continued Blank (9101011-BLK3) Continued Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 15:45 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes D/bromofluoromethane 44 u91L 50.0 89 67-129 Toluene-& 37 u91L 50.0 74 59-134 LCS (9301011-BSI) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 13:40 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 95 75-133 Benzene 21 1.0 ug/L 20.0 106 80-134 Chlorobenzene 20 1.0 ug/L 20.0 98 80-120 Toluene 20 1.0 ug/L 20.0 98 71-120 Trichloroethene 18 1.0 ug/L 20.0 92 74-120 Matrix Spike (9303011-MS1) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 14:12 Source: CC16562-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 0.21 U 96 75-133 Benzene 21 1.0 ug/L 20.0 0.15 U 106 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 97 80-120 Toluene 19 1.0 ug/L 20.0 0.14 U 97 71-120 Trichloroethene 19 1.0 ug/L 20.0 0.15 U 94 74-120 Matrix Spike Dup (9103011-MSD1) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 14:43 Source: CC16562-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 0.21 U 85 75-133 12 20 Benzene 20 1.0 ug/L 20.0 0.15 U 98 80-134 8 17 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 92 80-120 5 16 Toluene 18 1.0 ug/L 20.0 0.14 U 91 71-120 6 17 Trichloroethene 17 1.0 ug/L 20.0 0.15 U 86 74-120 9 22 Metals by EPA 6000/7000 Series Methods - Quality Control Batch 9I25027 - EPA 7470A Blank (9I25027-BLK3) Prepared: 09/25/2019 10:52 Analyzed: 09/26/2019 12:49 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 0.150 U 0.200 ug/L LCS (9I25027-BS1) Prepared: 09/25/2019 10:52 Analyzed: 09/26/2019 12:53 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 5.14 0.200 ug/L 5.00 103 80-120 Matrix Spike (9I25027-MS1) Prepared: 09/25/2019 10:52 Analyzed: 09/26/2019 12:57 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Mercury 5.25 0.200 ug/L 5.00 0.150 U 105 75-125 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 42 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals by EPA 6000/7000 Series Methods - Quality Control Batch 9I25027 - EPA 7470A - Continued Matrix Spike Dup (9I25027-MSD3) Prepared: 09/25/2019 10:52 Analyzed: 09/26/2019 13:00 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Mercury 5.38 0.200 ug/L 5.00 0.150 U 108 75-125 2 25 Post Spike (9I25027-PSI) Prepared: 09/25/2019 10:52 Analyzed: 09/26/2019 13:07 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Mercury 5.96 0.200 ug/L 5.00 -0.0150 119 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24024 - EPA 3005A Blank (9I24024-BLK3) Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:14 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Iron 22.0 U 50.0 ug/L Lead 3.10 U 10.0 ug/L Manganese 1.50 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Selenium 6.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L LCS (9I24024-BSI) Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:21 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Arsenic 197 10.0 ug/L 200 99 80-120 Barium 198 10.0 ug/L 200 99 80-120 Beryllium 20.3 1.00 ug/L 20.0 102 80-120 Cadmium 20.3 1.00 ug/L 20.0 102 80-120 Chromium 200 10.0 ug/L 200 100 80-120 Cobalt 198 10.0 ug/L 200 99 80-120 Copper 197 10.0 ug/L 200 98 80-120 Iron 997 50.0 ug/L 1000 100 80-120 Lead 203 10.0 ug/L 200 102 80-120 Manganese 201 10.0 ug/L 200 101 80-120 Nickel 201 10.0 ug/L 200 101 80-120 Selenium 201 10.0 ug/L 200 101 80-120 Silver 205 10.0 ug/L 200 102 80-120 Vanadium 199 10.0 ug/L 200 100 80-120 Zinc 210 10.0 ug/L 200 105 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 43 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9124024 - EPA 3005A - Continued Matrix Spike (9I24024-MSI) Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:24 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 185 10.0 ug/L 200 7.60 U 93 75-125 Barium 854 10.0 ug/L 200 669 93 75-125 Beryllium 19.3 1.00 ug/L 20.0 0.160 U 97 75-125 Cadmium 19.0 1.00 ug/L 20.0 0.360 U 95 75-125 Chromium 193 10.0 ug/L 200 1.40 U 96 75-125 Cobalt 198 10.0 ug/L 200 7.39 95 75-125 Copper 196 10.0 ug/L 200 1.60 U 98 75-125 Iron 24800 50.0 ug/L 1000 23800 102 75-125 Lead 199 10.0 ug/L 200 3.10 U 100 75-125 Manganese 6650 10.0 ug/L 200 6430 109 75-125 Nickel 201 10.0 ug/L 200 2.20 U 100 75-125 Selenium 206 10.0 ug/L 200 6.20 U 103 75-125 Silver 197 10.0 ug/L 200 1.90 U 98 75-125 Vanadium 196 10.0 ug/L 200 1.40 U 98 75-125 Zinc 220 10.0 ug/L 200 24.0 98 75-125 Matrix Spike Dup (9I24024-MSD1) Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:26 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 187 10.0 ug/L 200 7.60 U 94 75-125 1 20 Barium 864 10.0 ug/L 200 669 97 75-125 1 20 Beryllium 19.7 1.00 ug/L 20.0 0.160 U 99 75-125 2 20 Cadmium 19.6 1.00 ug/L 20.0 0.360 U 98 75-125 3 20 Chromium 195 10.0 ug/L 200 1.40 U 98 75-125 1 20 Cobalt 205 10.0 ug/L 200 7.39 99 75-125 4 20 Copper 204 10.0 ug/L 200 1.60 U 102 75-125 4 20 Iron 25100 50.0 ug/L 1000 23800 131 75-125 1 20 QM-07 Lead 207 10.0 ug/L 200 3.10 U 103 75-125 4 20 Manganese 6720 10.0 ug/L 200 6430 140 75-125 0.9 20 QM-07 Nickel 195 10.0 ug/L 200 2.20 U 98 75-125 3 20 Selenium 208 10.0 ug/L 200 6.20 U 104 75-125 0.7 20 Silver 207 10.0 ug/L 200 1.90 U 103 75-125 5 20 Vanadium 200 10.0 ug/L 200 1.40 U 100 75-125 2 20 Zinc 230 10.0 ug/L 200 24.0 103 75-125 4 20 Post Spike (9I24024-PS1) Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:29 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 0.185 0.0100 mg/L 0.200 -0.0219 93 80-120 Barium 0.842 0.0100 mg/L 0.200 0.669 86 80-120 Beryllium 0.0195 0.00100 mg/L 0.0200 -0.000444 98 80-120 Cadmium 0.0196 0.00100 mg/L 0.0200 -0.000264 98 80-120 Chromium 0.197 0.0100 mg/L 0.200 0.000513 98 80-120 Cobalt 0.203 0.0100 mg/L 0.200 0.00739 98 80-120 Copper 0.201 0.0100 mg/L 0.200 0.000716 100 80-120 Iron 24.3 0.0500 mg/L 1.00 23.8 59 80-120 QM-08 Lead 0.203 0.0100 mg/L 0.200 -0.000496 102 80-120 Manganese 6.52 0.0100 mg/L 0.200 6.43 43 80-120 QM-08 Nickel 0.206 0.0100 mg/L 0.200 0.00184 102 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 44 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24024 - EPA 3005A - Continued Post Spike (9I24024-PS3) Continued Prepared: 09/24/2019 11:14 Analyzed: 09/25/2019 13:29 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Selenium 0.206 0.0100 mg/L 0.200-0.000792 103 80-120 Silver 0.205 0.0100 mg/L 0.200-0.000251 103 80-120 Vanadium 0.199 0.0100 mg/L 0.200-0.000609 100 80-120 Zinc 0.233 0.0100 mg/L 0.200 0.0240 104 80-120 Batch 9I24026 - EPA 3005A Blank (9I24026-BLK3) Prepared: 09/24/2019 11:34 Analyzed: 09/25/2019 10:10 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L LCS (9I24026-BS3) Prepared: 09/24/2019 11:34 Analyzed: 09/25/2019 10:27 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Antimony 20.3 1.00 ug/L 20.0 101 80-120 Thallium 20.2 1.00 ug/L 20.0 101 80-120 Matrix Spike (9I24026-MSI) Prepared: 09/24/2019 11:34 Analyzed: 09/25/2019 10:31 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 43.0 2.00 ug/L 40.0 0.740 U 107 75-125 Thallium 39.1 2.00 ug/L 40.0 0.485 97 75-125 Matrix Spike Dup (9I24026-MSD1) Prepared: 09/24/2019 11:34 Analyzed: 09/25/2019 10:36 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 42.5 2.00 ug/L 40.0 0.740 U 106 75-125 1 20 Thallium 39.3 2.00 ug/L 40.0 0.485 97 75-125 0.5 20 Post Spike (9I24026-PS1) Prepared: 09/24/2019 11:34 Analyzed: 09/25/2019 10:40 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Antimony 21.9 1.00 ug/L 20.0 0.0133 109 75-125 Thallium 20.1 1.00 ug/L 20.0 0.243 99 75-125 Batch 9I24028 - EPA 3005A Blank (9I24028-BLK1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:40 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L LCS (9I24028-BSI) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:49 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 45 Of rJ3 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9124028 - EPA 3005A - Continued LCS (9I24028-BS3) Continued Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:49 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Antimony 21.2 1.00 ug/L 20.0 106 80-120 Thallium 20.4 1.00 ug/L 20.0 102 80-120 Matrix Spike (9I24028-MSI) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:53 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 42.7 2.00 ug/L 40.0 0.740 U 107 75-125 Thallium 38.6 2.00 ug/L 40.0 0.220 U 97 75-125 Matrix Spike Dup (9I24028-MSD1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 13:06 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 43.6 2.00 ug/L 40.0 0.740 U 109 75-125 2 20 Thallium 39.9 2.00 ug/L 40.0 0.220 U 100 75-125 3 20 Post Spike (9I24028-PS1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 13:10 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Antimony 22.0 1.00 ug/L 20.0 -0.00236 110 75-125 Thallium 20.0 1.00 ug/L 20.0 0.00182 100 75-125 Volatile Organic Compounds by GCMS SIM Isotope Dilution - Quality Control Batch 9JO1056 - EPA 5030B MS Blank (9301056-BLK3) Prepared: 10/01/2019 16:37 Analyzed: 10/01/2019 22:48 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 3.5 2.0 ug/L Q13-01, QB-( Toluene-d8 5.4 ug/L 5.00 107 75-125 LCS (9701056-BS1) Prepared: 10/01/2019 16:37 Analyzed: 10/01/2019 20:55 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 25 B 2.0 ug/L 25.0 101 80-133 Toluene-d8 5.0 ug/L 5.00 100 75-125 Matrix Spike (9303056-MS1) Prepared: 10/01/2019 16:37 Analyzed: 10/01/2019 21:32 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 25 B 2.0 ug/L 25.0 1.4 96 80-133 Toluene-d8 5.2 ug/L 5.00 105 75-125 Matrix Spike Dup (9303056-MSD1) Prepared: 10/01/2019 16:37 Analyzed: 10/01/2019 22:11 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 27 B 2.0 ug/L 25.0 1.4 103 80-133 7 19 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 46 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS SIM Isotope Dilution - Quality Control Batch 9JO1056 - EPA 5030E MS - Continued Matrix Spike Dup (9103056-MSD3) Continued Prepared: 10/01/2019 16:37 Analyzed: 10/01/2019 22:11 Source: CC13963-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Toluene-d8 5.1 u9/L 5.00 103 75-125 Batch 9-702038 - EPA 5030B MS Blank (9302038-BLK3) Prepared: 10/02/2019 00:00 Analyzed: 10/02/2019 11:49 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 1.2 U 2.0 ug/L Toluene-d8 5.0 u91L 5.00 101 75-125 LCS (9302038-BSI) Prepared: 10/02/2019 00:00 Analyzed: 10/02/2019 10:05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 23 2.0 ug/L 25.0 93 80-133 Toluene-d8 5.0 u9/L 5.00 101 75-125 LCS Dup (9702038-BSD1) Prepared: 10/02/2019 00:00 Analyzed: 10/02/2019 10:39 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 25 2.0 ug/L 25.0 100 80-133 8 19 QM-10 Toluene-d8 4.8 u91L 5.00 97 75-125 QM-10 Chlorinated Herbicides by GC - Quality Control Batch 9124050 - EPA 3510C Blank (9I24050-BLK3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 07:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 0.27 U 0.50 ug/L 2,4-DC4A[2C] 1.2 u91L 2.00 61 37-134 LCS (9I24050-BSI) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.3 0.50 ug/L 2.00 66 20-134 2, 4-DCAA [2C] 1.6 u9/L 2.00 60 37-134 Matrix Spike (9I24050-MS1) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:28 Source: AC06687-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.6 0.50 ug/L 2.00 0.27 U 80 20-134 2,4-DC,4A [2C] 1.4 u91L 2.00 68 37-134 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 47 Of 53 (� �Eo www.encolabs.com QUALITY CONTROL DATA Chlorinated Herbicides by GC - Quality Control Batch 9I24050 - EPA 3510C - Continued Matrix Spike (9I24050-MS2) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 10:44 Source: AC06689-02 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.6 0.50 ug/L 2.00 0.27 U 78 20-134 2,4-DC.4A[2C] 1.7 ug/L 2.00 84 37-134 Matrix Spike (9I24050-MS3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 12:00 Source: AC06458-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 6.0 2.5 ug/L 10.0 1.4 U 60 20-134 2,4-DCAA [2C] 5.6 ug/L 10.0 56 37-134 Matrix Spike Dup (9I24050-MSD3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:54 Source: AC06687-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.2 0.50 ug/L 2.00 0.27 U 60 20-134 27 19 QM-11 2,4-DC.4A[2C] 1.4 ug/L 2.00 68 37-134 Matrix Spike Dup (9I24050-MSD2) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 11:09 Source: AC06689-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.3 0.50 ug/L 2.00 0.27 U 66 20-134 17 19 2, 4-DCAA [2C] 1.4 ug/L 2.00 70 37-134 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 48 Of 53 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QB-01 The method blank had a positive result for the analyte; however, the concentration in the method blank is less than 10% of the sample result. There is minimal impact to the data. QB-02 The method blank contains analyte at a concentration above the MDL and/or greater than one-half the MRL. The analyte was not detected in the sample. QL-02 The associated laboratory control sample exhibited high bias; since the result is ND, there is no impact. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-10 LCS/LCSD were analyzed in place of MS/MSD. QM-11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits. QV-01 The associated continuing calibration verification standard exhibited high bias; since the result is ND, there is no impact. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 49 Of 53 �j � � � a , : W (�]� �� ws y Z tp } W T �y n a a R yr m �' m m a 0 0 CD 00 0 0 0 0 0 a 0 cu r rA w 8 W W W �. A a v a �aw iV Ct 0 77 a. w as rn u+ „ �- � � Z � � y m a C) .+ �1 •-- CL p (0 A a m m V Cb ss ,S W �wq0 r❑� � z C C LP co �y O m N m CD d 0w m w 3 o 0 in N m [p 71 x °° C 2k �5- 0 z --j-4 N_ -4 ti v-4 v-4 N) v-4 v 0� 0 = N (n X =y m m � 8151A m —0 ° =w 8260D Appendix 1,8260D SI M ID j q� 30 a 82600 Appendix 1,8260D Extended Z 1 , -❑ N HIr W m 8260D Appendix 2,8280D .4 n 3 Emand9d,82BOD SIM ID z 0 r N Ag,As,Ba,Be,Cd,Co,Cr.Cu.Fe,Mn,Ni,Pb, S �{ a $ Sb,Se,Se.1,V.2n n n G Ag.As,Ba,Be,Cd,Co,Cr,Cu,Ni,Pb,Sb.Se• y ?C X X X X X X X X X X _c Se.T1,V,7n A m w m C] n X x x x x x X X Hg o uN a O C d C: C K W l vC� N iC ❑ ❑�v 3 3 3 co o w M cn _I Q -� = 0 m N w o CD W CD a Page 50 of 53 ram. D 3 3 3 "'3 i R .a p �n� N [JCID M [b a C 3 L 14 CTI C) w co 9) 77 ry m 0 m m 6 �_ { t► n $ ^ C v [� y m n ro C w N 0 v C. G7 3 v 2 n w x W C) o 0 o s 4 Atom r .15 � V Z N nmi o n C w m ❑ m o a a A o Z Q v'�o �r .� a � g ❑� c r �- , � Ao rA - m S � � a aa A ❑ o Q C �3 N� O 5- g� 1T z o g ] [p _ m 3 m m m N V 3 o V a "� CA D � Z a ❑ o o a [l7 m a ' In a ' m a m n nx o 8 W �' T � Z V r � x o y -4m rn n A o, ❑ ra N n O o x $15lA, I,Y-� a.,1� m � d v m o X 82600 Appendix 1.8260D SW ID a 3� L m ro 8260D Appendix 2,B260D Extended 7 � `°❑o❑ N 0 8260D Appendix A,8260D X m a n 0 N Emonded,82601D SIM I0 pA m n p o WOV/ 9 o {. —4 7] 2 9 Ag,As,Be,Be,Cd,Co,Cr,Cu,FB,Mn.Ni.Ph. H AL ❑ a x Ag,As,Ba,Be,Cd.Co,Cr,Cu,Ni,P6.Sh,Se, D m a Se.Ti.V,Zn m a m rn o H °� Hg xLl i N i I Q Q Q Z CD W G m cc o v v m A m m 3 a. m W m a 1 n m��m o wry _0 3 � o v 3 (L I� Q � m w ¢n 5a Page 51 of 53 . Sample Preservation Verification ENCO Cary ENCO Work Order: CC13963 Project: Henderson Co. LF Client: Golder Associates, Inc. {GO007} Project #: 19128179.101 Loggedin: 20-Sep-19 14:17 Logged By: John C King Preservation Check Performed By: Date/Time: q a:�O'P CC13963-01 Cant Type Pres (pH) Requirement pH Checked ! In Control pH Adjusted DatelTme Adjusted Reagent Used/Comments A 250rnLP+HNQ3 <2 _Y,j N 1 NA Y h N. I NA CC13963-02 Cant Type Pres (pH) Requirement pH Checked 1 n Control pH Adjusted Uatefrime Adjusted Reagent Used/Comments A 25omLP+HNO3 <2 Ot N I NA I Y I / NA CC13963-03 Cont Type Pres (pH) JpH Checked 1 pH Adjusted DateMme Reagent UsedlComments Requirement I in Control Adjusted A 250mLP+HNO3 <2 Yi! N I NA Y !iN 1 NA CC1'1963-11M Cont Type Pres (pH) pH Checked 1 pH Adjusted DaterFime Reagent Used/Comments Requirement In Control Adjusted A 250mLPtHNO3 2 Y! N 1 NA Y 1 �} ! NA B 250mLP+HNC3 <2 Y I N I NA Y =/N CC13963-06 Cant Type Pres (pH) Requirement JpH Checked 1 I In Control pH Adjusted DatelTme Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 N 1 NA Y 1 N; 1 NA CC13963-07 Cont Type Pres (pH) JpH Checked 1 pH Adjusted UateMme Reagent Used/Comments Requirement I In Control Adjusted A 250mLP+HNO3 <2 YI 1 N 1 NA Y I N I NA CC13963-08 Cont Type Pres (pH) pH Checked 1I pH Adjusted UatelTime Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y, I N! NA Y F N` I NA C C 13963-09 Cont Type Pres (pH) pH Checked I pH Adjusted Datefrime Reagent Used/Comments Requirement In Control Adjusted A 250mLP+HNO3 <2 Y I N I NA YIN I NA Page 52 of 53 C:IELMNT1Printlwko_PreservationCheck.rpt Page I of 2 Sample Preservation Verification ENCO Cary Work Order: CC13963 Client: Goider Associates, Inc. (00007) Project: Henderson Co. LF Project #: 19128179.101 Lagged im 20-Sep-19 14:17 Logged By: John C King( Preservation Check Performed By: DatelTime: `'{ -M CC13963-10 Cont Type Pres (PH) pH Checked 1 PH Adjusted DateMme Reagent UsedlComments Requirement In Control Adjusted A 25omLP+HNO3 <2 Y, I N I NA Y 1 ,N j NA CC13963-11 Cont Type Pres (pH) I pH Checked /I Requirement In Control pH Adjusted DateMme Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 I N! NA Y I fi�l 1 NA CC13963-12 Cont Type Pres (pH) JpH Checked/1 PH Adjusted DateMme Reagent Used/Comments Requirement In Control I Adlusted A 250mLP+HNO3 <2 Y, I N 1 NA I Y N I NA CC13963-13 Cant Type Pres (pH) Requirement pH Checked ! In Control PH Adjusted DateT ime Adjusted Reagent Used/Comments A 250mLP+HNO3 <2 Y Y N I NA Y I( Ni 1 NA CC13963-14 Cont Type Pres (pH} Requirement pH Checked 1 In Control pH Adjusted DateMme Adjusted Reagent Used/Comments B 25omLP+HNO3 <2 `Y I N I NA Y N; I NA Reacient Name I❑ 1 2 PH Strip ID. Rea ent Name ID 3 4 Reacient Name ID 5 6 C:\ELMNT\Print\wko—PreservationCheck.rpt Page 53 of 53 Page 2 of 2 WORK ORDER Printed: 10/3/2019 5:32:25PM CC13963 ENCO Cary Sample Receipt Conditions Client: Golder Associates, Inc. (G0007) Lab Project Mgr: Meghan K Shea Project: Henderson Co. LF Project Number: 19128179.101 PO #: Report To: Invoice To: Golder Associates, Inc. (G0007) Golder Associates, Inc. (G0007) Dusty Reedy Accounts Payable 5B Oak Branch Drive 5B Oak Branch Drive Greensboro, NC 27407 Greensboro, NC 27407 Phone: (336) 852-4903 Phone :(804) 358-7900 Fax: (336) 852-4904 Fax: 804-358-2900 Received By: Timothy J. Parker Date Received: 20-Sep-19 13:55 Logged In By: John C King Date Logged In: 20-Sep-19 14:17 Work Order Comments: C-1955 received at 1.4°C Containers Intact Y Custody Seals Intact Y Temperature Corrected Y Containers Properly Preserved Y Proper Containers Received Y All Samples in PreLog Received Y COC/Labels Agree Y Volatile Containers Preserved Y Volatile Containers Headspace Free Y Aqueous Samples Checked for Residual Cl N Received On Ice Y Default Cooler Containers Intact N Containers Properly Preserved N Proper Containers Received N All Samples in PreLog Received N COC/Labels Agree N Custody Seals Intact N Volatile Containers Preserved N Volatile Containers Headspace Free N Aqueous Samples Checked for Residual Cl N Received On Ice N Temoeratme Corrected N Page 1 of 1 GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 4 Project Name: Henderson County MSW Landfill Project Reference Number: 19128179 Sampling Event Date: September 18-19, 2019 Review Date: October 10, 2019 Report #: CC13963 Signature: i V4" >"a M)ZC C e A C_X Date: i" 17,ZOTO GOLDER Initials: DC QA/QC Sign Off: G!K��� Date: Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) _ NC Closed Facility List (.500 Rules) _ NC C & D List (New Rules) _ NC Appendix I X NC Appendix I + Mercury NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW DC COC was properly signed by all parties. DC Correct project name and number are on the form. DC Sample receipt condition at laboratory was acceptable. DC Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 4 2.0 SAMPLE HOLDING TIMES 4 GOLDER DC Holding times for extraction and/or analysis were met for each analytical Method (see below for reference). Review Criteria Method Anal tes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW DC Laboratory analyzed at least one internal blank for each method, where applicable. DC Laboratory blank is interference -free. Chloromethane bias low in associated QC but can be detected in the CRL. Since the analyte in 4501- MW5 (Background), 4501-MW6, 4501-MW7, 4501-AMW1S, 4501-AMW1D, 4501-AMW2S, 4501-AMW2D, 4501-BR1, 4501-BR2, 4501-BR3, 4501-SW1 and 4501-Field Blank was not detected, there is no impact on data quality. The method blank had a positive result for 1,4-Dioxane; however, the concentration in the method blank is less than 10% of the sample result for 4501-MW6. There is minimal impact to the data. The method blank contains 1,4-Dioxane at the concentration above the MDL and/or greater than one- half the MRL. The analyte was not detected in 4501-MW5 (Background) and 4501-AMW1S, there is no impact. The Vinyl acetate associated laboratory control sample exhibited high bias; since 4501-131112, 4501- BR3 and 4501-SW1 are non -detect, there is no impact. The Vinyl acetate associated continuing calibration verification standard exhibited high bias; since 4501-MW5 (Background), 4501-MW6, 4501-MW7, 4501-AMW1S, 4501-AMW1D, 4501-AMW2S, 4501- AMW2113, 4501-BR1 and 4501-Field Blank were non -detect, there is no impact. DC Surrogate recoveries are provided for each analytical method, where applicable. DC Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). DC MS/MSD/LCS data results are provided for each analytical method. DC MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). Iron and Manganese post -digestion spikes did not meet method requirements due to confirmed matrix effects. Precision between 8151A 2,4 D duplicate matrix spikes of the same sample was outside acceptance limits. The QC batch was accepted based on acceptable LCS recoveries. The Iron and Manganese spike recoveries were outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recoveries. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 3 of 4 4.0 ANALYTE LISTS/METHODS ,,,> GOLDER DC The proper number of constituents are present for each analyte list as identified above (including detects where applicable). DC Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING DC All analytical reporting associated with the event was performed by the contracted lab. DC Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been 'flagged' with a 'B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. • Barium in Field Blank @ 3.97 ug/L (J) o Add B-Flags to AMW1 D, AMW2S, AMW2D • Copper in Field Blank @ 5.73 ug/L (J) o Add B-Flags to MW5, MW6, AMW1S, AMW1D, BR3 and SW1 • Iron in Field Blank @ 26.9 ug/L (J) • Manganese in Field Blank @ 1.79 ug/L (J) DC It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 1 Ox resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. • Antimony and Thallium 2x in all points including the field blank DC The report provides the reporting limit for each constituent. DC The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. DC No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. NC 2L/SWS GWPS Exceedances Benzene (NC 2L = 1 ug/L) • MW-6 @ 4.3 ug/L Thallium (IMAC = 0.2 ug/L) • MW -7 0.376 ug/L (J) • MW-8 0.485 ug/L (J) • AMW- 1S 0.322 ug/L (J) Cobalt (NC 2L IMAC = 1 ug/L) • MW-7 @ 4.89 ug/L (J) • MW-8 @ 7.39 ug/L (J) • AMW-1S @ 6.08 ug/L (J) 1,4-Dichlorobenzene ( NC 2L = 6 ug/L) • MW-6 @14 ug/L • MW-7 @ 12 ug/L GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 4 of 4 1,4 Dioxane ( NC 2L = 3 ug/L SW Standard = 0.35 ug/L) • MW-6 @ 35 ug/L • MW-7 @ 13 ug/L • AMW-1 D @ 8.5 ug/L • BR-1 @ 2.1 ug/L • BR-2 @ 8.0 ug/L • BR-3 @ 1.8 ug/L (J) • SW-1 @ 2.8 ug/L Golder Associates DC No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). N/A Other report issues/Communications with laboratory/etc.: ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, January 13, 2020 Golder Associates, Inc. (GO007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 0839650618.103, Project Name/Desc: Henderson Co. LF MNA ENCO Workorder(s): CC13965 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Thursday, September 19, 2019. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, �"n'1 Meghan K Shea Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 27 PROJECT NARRATIVE Date: 13 January 2020 Client: Golder Associates, Inc. (G0007) Project: Henderson Co. LF MNA Lab ID: CC13965 Overview (� �Eo www.encolabs.com This report is an amendment to the original report dated 01 October 2019 for this work order. This report was revised, at the client's request, to report Chloride result for MW-6. This an estimated value as it is over the calibration curve and due to analyst oversight was not reanalyzed at a proper dilution. Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in the QC Remarks section below. Quality Control Samples The spike recoveries for Alkalinity, Chloride, Nitrate/Nitrite (NOX), Nitrite, Sulfate and Total Organic Carbon were outside acceptance limits for the MS and/or MSD. The QC batches were accepted based on acceptable LCS recoveries. The Total Organic Carbon continuing calibration blank had a positive result for the analyte ; however, the concentration in the continuing calibration blank is less than 10% of the of the 4501-MW7, 4501-MW8 and 4501-Old MW-2 results. There is minimal impact to the data. The iso-Pentanoic Acid associated continuing calibration verification standard exhibited high bias; since all the sample results were non -detect, there is no impact. Quality Control Remarks No Comments Other Comments All samples received under this work order arrived in acceptable conditions. The samples were not checked for residual chlorine, as it is not required. The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of the report. Released By: Environmental Conservation Laboratories, Inc. Meghan Shea Project Manager FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 of 27 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-MW5 (Background) Lab ID: CC13965-01 Sampled: 09/18/19 09:07 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 18:47 EPA 310.2 NO PREP 10/02/19 09/24/19 14:45 09/24/19 14:45 EPA 353.2 NO PREP 09/20/19 09:07 09/19/19 17:30 09/19/19 17:30 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 12:38 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 09:07 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/20/19 08:15 09/20/19 11:30 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 17:21 Client ID: 4501-MW5 (Background) Lab ID: CC13965-01RE1 Sampled: 09/18/19 09:07 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 353.2 NO PREP 10/16/19 09/23/19 09:06 09/23/19 14:08 SM 531OB-2011 Same 10/16/19 09/26/19 11:00 09/26/19 11:25 Client ID: 4501-MW6 Lab ID: CC13965-02 Sampled: 09/18/19 11:00 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 19:40 EPA 310.2 NO PREP 10/02/19 09/24/19 14:46 09/24/19 14:46 EPA 353.2 NO PREP 09/20/19 11:00 09/19/19 17:32 09/19/19 17:32 EPA 353.2 NO PREP 10/16/19 09/25/19 16:04 09/25/19 16:04 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 13:10 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 11:00 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/20/19 08:15 09/20/19 11:30 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 18:00 Client ID: 4501-MW6 Lab ID: CC33965-02RE1 Sampled: 09/18/19 11:00 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 16:27 SM 531OB-2011 Same 10/16/19 09/26/19 11:00 09/26/19 11:25 Client ID: 4501-MW7 Lab ID: CC13965-03 Sampled: 09/18/19 12:25 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 20:51 EPA 310.2 NO PREP 10/02/19 09/24/19 14:48 09/24/19 14:48 EPA 353.2 NO PREP 09/20/19 12:25 09/19/19 17:32 09/19/19 17:32 EPA 353.2 NO PREP 10/16/19 09/25/19 16:06 09/25/19 16:06 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 13:26 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 12:25 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/20/19 08:15 09/20/19 11:30 SM 531OB-2011 Same 10/16/19 09/25/19 11:00 09/25/19 14:01 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 18:38 Client ID: 4501-MW7 Lab ID: CC13965-03REi Sampled: 09/18/19 12:25 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 16:43 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 Of 27 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-MW8 Lab ID: CC13965-04 Sampled: 09/18/19 09:05 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 22:01 EPA 310.2 NO PREP 10/02/19 09/24/19 14:48 09/24/19 14:48 EPA 353.2 NO PREP 09/20/19 09:05 09/19/19 17:33 09/19/19 17:33 EPA 353.2 NO PREP 10/16/19 09/25/19 16:11 09/25/19 16:11 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 13:42 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 09:05 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/25/19 09:30 09/25/19 15:02 SM 531OB-2011 Same 10/16/19 09/25/19 11:00 09/25/19 14:01 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 19:17 Client ID: 4501-MW8 Lab ID: CC13965-04RE1 Sampled: 09/18/19 09:05 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 16:59 Client ID: 4501-AMWlS Lab ID: CC13965-05 Sampled: 09/18/19 13:22 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 22:19 EPA 310.2 NO PREP 10/02/19 09/24/19 14:49 09/24/19 14:49 EPA 353.2 NO PREP 09/20/19 13:22 09/19/19 17:36 09/19/19 17:36 EPA 353.2 NO PREP 10/16/19 09/25/19 16:13 09/25/19 16:13 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 13:58 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 13:22 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/25/19 09:30 09/25/19 15:02 SM 531OB-2011 Same 10/16/19 09/25/19 11:00 09/25/19 14:01 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 19:56 Client ID: 4501-AMWIS Lab ID: CC13965-05RE1 Sampled: 09/18/19 13:22 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 17:15 Client ID: 4501-AMW2S Lab ID: CC13965-06 Sampled: 09/18/19 13:05 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 22:37 EPA 310.2 NO PREP 10/02/19 09/24/19 14:50 09/24/19 14:50 EPA 353.2 NO PREP 09/20/19 13:05 09/19/19 17:37 09/19/19 17:37 EPA 353.2 NO PREP 10/16/19 09/25/19 16:15 09/25/19 16:15 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 14:14 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 13:05 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/25/19 09:30 09/25/19 15:02 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 20:34 Client ID: 4501-AMW2S Lab ID: CC13965-06REi Sampled: 09/18/19 13:05 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) SM 531OB-2011 Same 10/16/19 09/26/19 11:00 09/26/19 11:25 Client ID: 4501-AMW2S Lab ID: CC13965-06RE2 Sampled: 09/18/19 13:05 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 19:31 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 27 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-Old MW-2 Lab ID: CC13965-07 Sampled: 09/18/19 11:02 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/16/19 09/20/19 16:06 09/20/19 22:54 EPA 310.2 NO PREP 10/02/19 09/24/19 14:50 09/24/19 14:50 EPA 353.2 NO PREP 09/20/19 11:02 09/19/19 17:38 09/19/19 17:38 EPA 353.2 NO PREP 10/16/19 09/25/19 16:17 09/25/19 16:17 EPA 353.2 NO PREP 06/13/22 10/01/19 16:10 10/01/19 16:10 EPA 8260D EPA 5030B_MS 10/02/19 09/27/19 09:49 09/27/19 16:50 RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 14:30 SM 4500S2 D-2011 NO PREP 09/25/19 09/23/19 14:25 09/23/19 14:40 SM 5210 B-2011 NO PREP 09/20/19 11:02 09/19/19 11:31 09/19/19 11:31 SM 5220D-2011 Same 10/16/19 09/25/19 09:30 09/25/19 15:02 SM 531OB-2011 Same 10/16/19 09/25/19 11:00 09/25/19 14:01 Volatile Fatty Acids NO PREP 10/16/19 09/25/19 09:20 09/25/19 21:13 Client ID: 4501-Old MW-2 Lab ID: CC33965-07RE3 Sampled: 09/18/19 11:02 Received: 09/19/19 09:30 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) RSK-175 Same 10/02/19 09/23/19 10:15 09/23/19 17:47 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) Of 27 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 4501-MW5 (Background) Lab ID: CC13965-01 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 74100 770 2500 ug/L RSK-175 Chemical Oxygen Demand 11000 10000 10000 ug/L SM 5220D-2011 Chloride 5300 2200 5000 ug/L EPA 300.0 Methane 1.56 0.450 1.00 ug/L RSK-175 Nitrate as N 950 25 100 ug/L EPA 353.2 Sulfate as SO4 40000 2900 5000 ug/L EPA 300.0 Total Alkalinity as CaCO3 16000 14000 15000 ug/L EPA 310.2 Client ID: 4501-MW5 (Background) Lab ID: CC13965-01RE3 Anala Results Flag MDL POLL Units Method Notes Nitrate/Nitrite as N 950 41 100 ug/L EPA 353.2 Total Organic Carbon 6400 340 1000 ug/L SM 531OB-2011 Client ID: 4501-MW6 Lab ID: CC13965-02 Anala Results Flag MDL POLL Units Method Notes Acetic Acid 18000 180 200 ug/L Volatile Fatty Acids Biochemical Oxygen Demand 6200 2000 2000 ug/L SM 5210 B-2011 Chemical Oxygen Demand 130000 10000 10000 ug/L SM 5220D-2011 Chloride 190000 E 2200 5000 ug/L EPA 300.0 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 23000 130 140 ug/L Volatile Fatty Acids Nitrate as N 140 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 140 41 100 ug/L EPA 353.2 Total Alkalinity as CaCO3 170000 14000 15000 ug/L EPA 310.2 Client ID: 4501-MW6 Lab ID: CC13965-02RE3 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 482000 D 16200 52500 ug/L RSK-175 Methane 1400 D 9.45 21.0 ug/L RSK-175 Total Organic Carbon 130000 D 680 2000 ug/L SM 531OB-2011 Client ID: 4501-MW7 Lab ID: CC13965-03 Anala Results Flag MDL POLL Units Method Notes Acetic Acid 1400 180 200 ug/L Volatile Fatty Acids Chemical Oxygen Demand 32000 10000 10000 ug/L SM 5220D-2011 Chloride 76000 2200 5000 ug/L EPA 300.0 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 3800 130 140 ug/L Volatile Fatty Acids Methane 136 0.450 1.00 ug/L RSK-175 Nitrate as N 56 1 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 56 1 41 100 ug/L EPA 353.2 Total Alkalinity as CaCO3 270000 D 28000 30000 ug/L EPA 310.2 Total Organic Carbon 45000 340 1000 ua/L SM 531OB-2011 OB-06 I Client ID: 4501-MW7 Lab ID: CC13965-03RE3 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 517000 D 3850 12500 ug/L RSK-175 Client ID: 4501-MWS Lab ID: CC13965-04 Anala Results Flag MDL POLL Units Method Notes Biochemical Oxygen Demand 2000 2000 2000 ug/L SM 5210 B-2011 Chemical Oxygen Demand 68000 10000 10000 ug/L SM 5220D-2011 Chloride 33000 2200 5000 ug/L EPA 300.0 Nitrate as N 200 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 200 41 100 ug/L EPA 353.2 Sulfate as SO4 13000 2900 5000 ug/L EPA 300.0 Total Alkalinity as CaCO3 480000 D 70000 75000 ug/L EPA 310.2 Total Organic Carbon 80000 340 1000 ug/L SM 531OB-2011 QB-06 Client ID: 4501-MW8 Lab ID: CC13965-04RE3 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 465000 D 3850 12500 ug/L RSK-175 Methane 231 D 2.25 5.00 ug/L RSK-175 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 27 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 4501-AMWlS Lab ID: CC13965-05 Anala Results Flag MDL POLL Units Method Notes Chloride 16000 2200 5000 ug/L EPA 300.0 Methane 5.26 0.450 1.00 ug/L RSK-175 Nitrate as N 310 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 310 41 100 ug/L EPA 353.2 Sulfate as SO4 24000 2900 5000 ug/L EPA 300.0 Total Organic Carbon 23000 340 1000 ug/L SM 531OB-2011 QM-07 Client ID: 4501-AMWlS Lab ID: CC13965-05RE3 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 209000 D 1620 5250 ug/L RSK-175 Client ID: 4501-AMW2S Lab ID: CC13965-06 Anala Results Flag MDL POLL Units Method Notes Chloride 13000 2200 5000 ug/L EPA 300.0 Methane 56.5 0.450 1.00 ug/L RSK-175 Nitrate as N 70 1 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 70 1 41 100 ug/L EPA 353.2 Total Alkalinity as CaCO3 78000 14000 15000 ug/L EPA 310.2 Client ID: 4501-AMW2S Lab ID: CC13965-06RE1 Anala Results Flag MDL POLL Units Method Notes Total Organic Carbon 11000 340 1000 ug/L SM 531OB-2011 Client ID: 4501-AMW2S Lab ID: CC13965-06RE2 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 170000 D 1620 5250 ug/L RSK-175 Client ID: 4501-Old MW-2 Lab ID: CC13965-07 Anala Results Flag MDL POLL Units Method Notes IJ-Dichloroethane 1.0 0.13 1.0 ug/L EPA 8260D Biochemical Oxygen Demand 2100 2000 2000 ug/L SM 5210 B-2011 Chemical Oxygen Demand 83000 10000 10000 ug/L SM 5220D-2011 Chloride 25000 2200 5000 ug/L EPA 300.0 Methane 53.9 0.450 1.00 ug/L RSK-175 Nitrate as N 860 25 100 ug/L EPA 353.2 Nitrate/Nitrite as N 900 41 100 ug/L EPA 353.2 Nitrite as N 45 1 17 100 ug/L EPA 353.2 Sulfate as SO4 3700 1 2900 5000 ug/L EPA 300.0 Total Alkalinity as CaCO3 160000 14000 15000 ug/L EPA 310.2 Total Organic Carbon 46000 340 1000 ug/L SM 531OB-2011 QB-06 Client ID: 4501-Old MW-2 Lab ID: CC13965-07RE1 Anala Results Flag MDL POLL Units Method Notes Carbon dioxide 1110000 D 7700 25000 ug/L RSK-175 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW5 (Background) Lab Sample ID:CC13965-01 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 09:07 Work Order: CC13965 Project: Henderson Co. LF MINA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 2000 U ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand^ 11000 ug/L 1 10000 10000 9I20002 SM 5220D-2011 09/20/19 11:30 JOC Chloride [16887-00-6]^ 5300 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 18:47 PDK Nitrate as N [14797-55-8]^ 950 ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as N^ 950 ug/L 1 41 100 9I23007 EPA 353.2 09/23/19 14:08 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:30 NMN Sulfate as SO4 [14808-79-8]^ 40000 ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 18:47 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 >M 4500S2 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 16000 ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:45 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 130 U ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI [50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 17:21 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed By Notes Trimethylacetic acid 20000 1 20000 99 % 50-150 9125016 Volatile Fatty Acid-, 09/25/1917:21 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MOIL POLL Batch Method Analyzed —By Notes Total Organic Carbon^ 6400 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/26/19 11:25 JSS Dissolved Gases by GC Analyte ICAS Numberl Results Flag Units DF MOIL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 74100 ug/L 1 770 2500 9I20008 RSK-175 09/23/19 12:38 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 12:38 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 12:38 LTS Methane [74-82-8] 1.56 ug/L 1 0.450 1.00 9I20008 RSK-175 09/23/19 12:38 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW6 Lab Sample ID:CC13965-02 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 11:00 Work Order: CC13965 Project: Henderson Co. LF MNA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 6200 ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand 130000 ug/L 1 10000 10000 9I20002 SM 5220D-2011 09/20/19 11:30 JOC Chloride [16887-00-6]^ 190000 E ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 19:40 PDK Nitrate as N [14797-55-8]^ 140 ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as IN 140 ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:04 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9119009 EPA 353.2 09/19/19 17:32 NMN Sulfate as SO4 [14808-79-8]^ 2900 U ug/L 1 2900 5000 9120033 EPA 300.0 09/20/19 19:40 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9123022 >M 4500S2 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 170000 ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:46 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 18000 ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric 23000 ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Acid)[50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9125018 ✓olatile Fatty Acids 09/25/19 18:00 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes Trimethylacetic acid 21000 1 20000 103 % 50-150 9125016 Volatile Fatty Acid-, 09/25/1918:00 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 130000 D ug/L 2 680 2000 9I23042 SM 531OB-2011 09/26/19 11:25 JSS Dissolved Gases by GC Analyte ICAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 482000 D ug/L 21 16200 52500 9I20008 RSK-175 09/23/19 16:27 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9120008 RSK-175 09/23/19 13:10 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9120008 RSK-175 09/23/19 13:10 LTS Methane [74-82-8] 1400 D ug/L 21 9.45 21.0 9I20008 RSK-175 09/23/19 16:27 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW7 Lab Sample ID:CC13965-03 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 12:25 Work Order: CC13965 Project: Henderson Co. LF MINA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 2000 U ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand^ 32000 ug/L 1 10000 10000 9I20002 SM 5220D-2011 09/20/19 11:30 JOC Chloride [16887-00-6]^ 76000 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 20:51 PDK Nitrate as N [14797-55-8]^ 56 J ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as N^ 56 J ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:06 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:32 NMN Sulfate as SO4 [14808-79-8]^ 2900 U ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 20:51 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 >M 4500S2 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 270000 D ug/L 2 28000 30000 9I24018 EPA 310.2 09/24/19 14:48 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 1400 ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric 3800 ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Acid)[50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 18:38 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes Trimethylacetic acid 22000 1 20000 108 % 50-150 9125016 Volatile Fatty Acid-, 09/25/1918:38 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 45000 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/25/19 14:01 JSS QB-06 Dissolved Gases by GC Analyte ICAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 517000 D ug/L 5 3850 12500 9I20008 RSK-175 09/23/19 16:43 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 13:26 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 13:26 LTS Methane [74-82-8] 136 ug/L 1 0.450 1.00 9I20008 RSK-175 09/23/19 13:26 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW8 Lab Sample ID:CC13965-04 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 09:05 Work Order: CC13965 Project: Henderson Co. LF MNA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 2000 ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand^ 68000 ug/L 1 10000 10000 9I25010 SM 5220D-2011 09/25/19 15:02 JOC Chloride [16887-00-6]^ 33000 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 22:01 PDK Nitrate as N [14797-55-8]^ 200 ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as IN 200 ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:11 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:33 NMN Sulfate as SO4 [14808-79-8]^ 13000 ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 22:01 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 >M 4500S2 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 480000 D ug/L 5 70000 75000 9I24018 EPA 310.2 09/24/19 14:48 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 130 U ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI [50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 19:17 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed By Notes Trimethylacetic acid 16000 1 20000 92 % 50-150 9125016 Volatile Fatty Acid-, 09/25/1919:17 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 80000 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/25/19 14:01 JSS QB-06 Dissolved Gases by GC Analyte ICAS Numberl Results Flaa Units DF MDL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 465000 D ug/L 5 3850 12500 9I20008 RSK-175 09/23/19 16:59 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 13:42 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 13:42 LTS Methane [74-82-8] 231 D ug/L 5 2.25 5.00 9I20008 RSK-175 09/23/19 16:59 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMWlS Lab Sample ID:CC13965-05 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 13:22 Work Order: CC13965 Project: Henderson Co. LF MINA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 2000 U ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand' 10000 U ug/L 1 10000 10000 9I25010 SM 5220D-2011 09/25/19 15:02 JOC Chloride [16887-00-6]^ 16000 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 22:19 PDK Nitrate as N [14797-55-8]^ 310 ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as N^ 310 ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:13 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:36 NMN Sulfate as SO4 [14808-79-8]^ 24000 ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 22:19 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 >M 450052 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 14000 U ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:49 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 130 U ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI [50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 19:56 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed By Notes Trimethylacetic acid 20000 1 20000 100 % 50-150 9I25016 Volatile Fatty Acid-, 09/25/1919:56 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 23000 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/25/19 14:01 JSS QM-07 Dissolved Gases by GC Analyte ICAS Numberl Results Flag Units DF MOIL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 209000 D ug/L 2.1 1620 5250 9I20008 RSK-175 09/23/19 17:15 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 13:58 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 13:58 LTS Methane [74-82-8] 5.26 ug/L 1 0.450 1.00 9I20008 RSK-175 09/23/19 13:58 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 12 Of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-AMW2S Lab Sample ID:CC13965-06 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 13:05 Work Order: CC13965 Project: Henderson Co. LF MINA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed By Notes Biochemical Oxygen Demand^ 2000 U ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand' 10000 U ug/L 1 10000 10000 9I25010 SM 5220D-2011 09/25/19 15:02 JOC Chloride [16887-00-6]^ 13000 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 22:37 PDK Nitrate as N [14797-55-8]^ 70 J ug/L 1 25 100 9301037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as N^ 70 J ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:15 NMN Nitrite as N [14797-65-0]^ 17 U ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:37 NMN Sulfate as SO4 [14808-79-8]^ 2900 U ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 22:37 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 >M 450052 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 78000 ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:50 NMN Volatile Fatty Acids by HPLC Analyte ICAS Numberl Results Flag Units DF MOIL P L Batch Method Analyzed —By Notes Acetic Acid [64-19-7] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI Butyric Acid [107-92-6] 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI Hexanoic Acid [142-62-1] 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI iso-Hexanoic Acid [646-07-1] 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI iso-Pentanoic Acid [503-74-2] 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI QV-01 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 130 U ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI [50-21-5/594-61-6] Pentanoic Acid [109-52-4] 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI Propionic Acid [79-09-4] 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI Pyruvic Acid [127-17-3] 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 20:34 JFI Surrogates Results DF Spike Lv/ % Rec % Rec Limits Batch Method Ana/vzed By Notes Trimethylacetic acid 17000 1 20000 83 % 50-150 9I25016 Volatile Fatty Acid-, 091251192034 JFI Classical Chemistry Parameters ^ - ENCO Orlando certified analyte [NC 424] Analyte ICAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Total Organic Carbon^ 11000 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/26/19 11:25 JSS Dissolved Gases by GC Analyte ICAS Numberl Results Flag Units DF MOIL POLL Batch Method Analyzed —By Notes Carbon dioxide [124-38-9] 170000 D ug/L 2.1 1620 5250 9I20008 RSK-175 09/23/19 19:31 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 14:14 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 14:14 LTS Methane [74-82-8] 56.5 ug/L 1 0.450 1.00 9I20008 RSK-175 09/23/19 14:14 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 13 of 27 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-Old MW-2 Lab Sample ID:CC13965-07 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 11:02 Work Order: CC13965 Project: Henderson Co. LF MINA Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte ICAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,1-Dichloroethane [75-34-3]A 1.0 ug/L 1 0.13 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Benzene [71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9I27013 EPA 8260D 09/27/19 16:50 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 43 1 50.0 85 % 53-136 9127013 EPA 8260D 09127119 16:50 REF Dibromofluoromethane 44 1 50.0 88 % 67-129 9127013 EPA 8260D 09127119 16:50 REF Toluene-d8 37 1 50.0 74 % 59-134 9127013 EPA 8260D 09127119 16:50 REF Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte fCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Biochemical Oxygen Demand ^ 2100 ug/L 1 2000 2000 9I19010 SM 5210 B-2011 09/19/19 11:31 JOC Chemical Oxygen Demand^ 83000 ug/L 1 10000 10000 9I25010 SM 5220D-2011 09/25/19 15:02 JOC Chloride [16887-00-6]^ 25000 ug/L 1 2200 5000 9I20033 EPA 300.0 09/20/19 22:54 PDK Nitrate as N [14797-55-8]^ 860 ug/L 1 25 100 9101037 EPA 353.2 10/01/19 16:10 MKS Nitrate/Nitrite as N^ 900 ug/L 1 41 100 9I25039 EPA 353.2 09/25/19 16:17 NMN Nitrite as N [14797-65-0]^ 45 J ug/L 1 17 100 9I19009 EPA 353.2 09/19/19 17:38 NMN Sulfate as SO4 [14808-79-8]^ 3700 J ug/L 1 2900 5000 9I20033 EPA 300.0 09/20/19 22:54 PDK Sulfide [18496-25-8]^ 10 U ug/L 1 10 100 9I23022 iM 4500S2 D-2011 09/23/19 14:40 JOC Total Alkalinity as CaCO3 [471-34-1]^ 160000 ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:50 NMN Volatile Fatty Acids by HPLC Analyte fCAS Numberl Acetic Acid [64-19-7] Butyric Acid [107-92-6] Hexanoic Acid [142-62-1] iso-Hexanoic Acid [646-07-1] iso-Pentanoic Acid [503-74-2] Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) [50-21-5/594-61-6] Pentanoic Acid [109-52-4] Propionic Acid [79-09-4] Pyruvic Acid [127-17-3] Surrogates Trimethylacetic acid Results Flag Units DF MDL POLL Batch Method Analyzed By Notes 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 89 U ug/L 1 89 100 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 260 U ug/L 1 260 500 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 440 U ug/L 1 440 500 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 180 U ug/L 1 180 200 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI QV-01 130 U ug/L 1 130 140 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 140 U ug/L 1 140 200 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 65 U ug/L 1 65 100 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI 21 U ug/L 1 21 70 9I25018 ✓olatile Fatty Acids 09/25/19 21:13 JFI Results DF SSqike Lv/ % Rec % Rec Limits Batch Method Analyzed ffy Notes 19000 1 20000 97 % 50-150 9125018 Volatile Fatty Acid., 09125119 21:13 JFI FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 of 2% (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-01d MW-2 Lab Sample ID:CC13965-07 Received: 09/19/19 09:30 Matrix: Ground Water Sampled:09/18/19 11:02 Work Order: CC13965 Project: Henderson Co. LF MNA Sampled By:Travis Martinez/ Erik Vaskc Classical Chemistry Parameters A - ENCO Orlando Certified analyte [NC 424] Analyte rCAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes Total Organic CarbonA 46000 ug/L 1 340 1000 9I23042 SM 531OB-2011 09/25/19 14:01 ]SS QB-06 Dissolved Gases by GC Analyte rCAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes Carbon dioxide [124-38-9] 1110000 D ug/L 10 7700 25000 9I20008 RSK-175 09/23/19 17:47 LTS Ethane [74-84-0] 1.30 U ug/L 1 1.30 2.00 9I20008 RSK-175 09/23/19 14:30 LTS Ethene [74-85-1] 1.50 U ug/L 1 1.50 3.00 9I20008 RSK-175 09/23/19 14:30 LTS Methane [74-82-8] 53.9 ug/L 1 0.450 1.00 9I20008 RSK-175 09/23/19 14:30 LTS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 of 2% (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9I27013 - EPA 50308 MS Blank (9I27013-BLK3) Prepared: 09/27/2019 09:49 Analyzed: 09/27/2019 15:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L Benzene 0.15 U 1.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L 4-Bromofluorobenzene 43 u91L 50.0 87 53-136 Dibromofluoromethane 45 u9/L 50.0 89 67-129 Toluene-d8 36 u9/L 50.0 75 59-134 LCS (9I27013-BSI) Prepared: 09/27/2019 09:49 Analyzed: 09/27/2019 13:42 Spike Source %REC RPD Analvte Result Flaa P L Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 86 75-133 Benzene 19 1.0 ug/L 20.0 96 80-134 Chlorobenzene 18 1.0 ug/L 20.0 90 80-120 Toluene 18 1.0 ug/L 20.0 92 71-120 Trichloroethene 17 1.0 ug/L 20.0 86 74-120 4-Bromofluorobenzene 43 u9/L 50.0 67 53-136 Dibromofluoromethane 43 u91L 50.0 86 67-129 Toluene-d8 37 u91L 50.0 75 59-134 Matrix Spike (9I27013-MS1) Prepared: 09/27/2019 09:49 Analyzed: 09/27/2019 14:13 Source: CC16420-06 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 0.21 U 85 75-133 Benzene 19 1.0 ug/L 20.0 0.15 U 94 80-134 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 90 80-120 Toluene 17 1.0 ug/L 20.0 0.14 U 87 71-120 Trichloroethene 16 1.0 ug/L 20.0 0.15 U 82 74-120 4-Bromofluorobenzene 44 u91L 50.0 89 53-136 Dibromofluoromethane 44 u91L 50.0 88 67-129 Toluene-d8 37 u9/L 50.0 75 59-134 Matrix Spike Dup (9I27013-MSD1) Prepared: 09/27/2019 09:49 Analyzed: 09/27/2019 14:45 Source: CC16420-06 Spike Source %REC RPD Analvte Result Flaq P L Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 0.21 U 91 75-133 7 20 Benzene 21 1.0 ug/L 20.0 0.15 U 104 80-134 10 17 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 96 80-120 7 16 Toluene 19 1.0 ug/L 20.0 0.14 U 97 71-120 11 17 Trichloroethene 18 1.0 ug/L 20.0 0.15 U 91 74-120 10 22 4-Bromofluorobenzene 43 u9/L 50.0 66 53-136 Dibromofluoromethane 43 u9/L 50.0 87 67-129 Toluene-d8 38 u91L 50.0 76 59-134 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 Of 27 (� �Eo www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9I19OO9 - NO PREP Blank (9I19009-BLKI) Prepared: 09/19/2019 10:37 Analyzed: 09/19/2019 10:37 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 17 U 100 ug/L LCS (9I19009-BS1) Prepared: 09/19/2019 10:30 Analyzed: 09/19/2019 10:30 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 0.97 0.10 mg/L 1.00 97 90-110 Matrix Spike (9I19009-MS1) Prepared: 09/19/2019 10:39 Analyzed: 09/19/2019 10:39 Source: CC13966-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 860 100 ug/L 1000 17 U 86 90-110 QM-07 Matrix Spike (9I19009-MS2) Prepared: 09/19/2019 17:31 Analyzed: 09/19/2019 17:31 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 990 100 ug/L 1000 17 U 99 90-110 Matrix Spike Dup (9I19009-MSD1) Prepared: 09/19/2019 10:40 Analyzed: 09/19/2019 10:40 Source: CC13966-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Nitrite as N 880 100 ug/L 1000 17 U 88 90-110 2 10 QM-07 Batch 9I19O1O - NO PREP Blank (9I19010-BLK1) Prepared & Analyzed: 09/19/2019 11:31 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2000 U 2000 ug/L LCS (9I19010-BSI) Prepared & Analyzed: 09/19/2019 11:31 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 190000 2000 ug/L 198000 94 85-115 Duplicate (9I19010-DUP1) Prepared & Analyzed: 09/19/2019 11:31 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Biochemical Oxygen Demand 2000 U 2000 ug/L 2000 U 30 Batch 9I2OOO2 - Same Blank (9I20002-BLK1) Prepared: 09/20/2019 08:15 Analyzed: 09/20/2019 11:30 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10000 U 10000 ug/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 17 Of 27 (� �Eo www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9120002 - Same - Continued LCS (9I20002-BS3) Prepared: 09/20/2019 08:15 Analyzed: 09/20/2019 11:30 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 510000 10000 ug/L 500000 102 90-110 Matrix Spike (9I20002-MS3) Prepared: 09/20/2019 08:15 Analyzed: 09/20/2019 11:30 Source: CC13115-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 1400000 20000 ug/L 1000000 480000 97 90-110 Matrix Spike Dup (9I20002-MSD1) Prepared: 09/20/2019 08:15 Analyzed: 09/20/2019 11:30 Source: CC13115-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 1400000 20000 ug/L 1000000 480000 95 90-110 1 10 Batch 9120033 - NO PREP Blank (9I20033-BLK1) Prepared: 09/20/2019 16:06 Analyzed: 09/20/2019 18:12 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 2200 U 5000 ug/L Sulfate as SO4 2900 U 5000 ug/L LCS (9I20033-BS1) Prepared: 09/20/2019 16:06 Analyzed: 09/20/2019 18:29 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 51000 5000 ug/L 50000 103 90-110 Sulfate as SO4 50000 5000 ug/L 50000 100 90-110 Matrix Spike (9I20033-MS3) Prepared: 09/20/2019 16:06 Analyzed: 09/20/2019 19:05 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 24000 5000 ug/L 20000 5300 96 90-110 Sulfate as SO4 62000 5000 ug/L 20000 40000 108 90-110 Matrix Spike (9I20033-MS2) Prepared: 09/20/2019 16:06 Analyzed: 09/20/2019 19:58 Source: CC13965-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 210000 E 5000 ug/L 20000 190000 101 90-110 QM-07 Sulfate as SO4 19000 5000 ug/L 20000 2900 U 93 90-110 Matrix Spike Dup (9I20033-MSD1) Prepared: 09/20/2019 16:06 Analyzed: 09/20/2019 19:22 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 25000 5000 ug/L 20000 5300 99 90-110 2 10 Sulfate as SO4 63000 5000 ug/L 20000 40000 111 90-110 0.9 10 QM-07 Batch 9123007 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 Of 27 QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9I23007 - NO PREP - Continued (� �Eo www.encolabs.com Blank (9I23007-BLK3) Prepared: 09/23/2019 09:06 Analyzed: 09/23/2019 12:45 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 41 U 100 ug/L LCS (9I23007-BSI) Prepared: 09/23/2019 09:06 Analyzed: 09/23/2019 12:43 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 104 90-110 Matrix Spike (9I23007-MS1) Prepared: 09/23/2019 09:06 Analyzed: 09/23/2019 12:52 Source: CC09864-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 770 100 ug/L 521 200 110 90-110 Matrix Spike (9I23007-MS2) Prepared: 09/23/2019 09:06 Analyzed: 09/23/2019 14:06 Source: CC32707-02RE3 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 6000 500 ug/L 2500 3100 116 90-110 QM-07 Matrix Spike Dup (9I23007-MSD3) Prepared: 09/23/2019 09:06 Analyzed: 09/23/2019 12:54 111 Source: CC09864-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 750 100 ug/L 521 200 107 90-110 2 10 Batch 9I23022 - NO PREP Blank (9I23022-BLK1) Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Sulfide 10 U 100 ug/L LCS (9I23022-BS3) Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Sulfide 0.44 0.10 mg/L 0.401 109 80-120 Duplicate (9I23022-DUP3) Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Sulfide 10 U 100 ug/L 10 U 25 Matrix Spike (9I23022-MSI) Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Sulfide 430 100 ug/L 401 10 U 108 80-120 Matrix Spike Dup (9I23022-MSD1) Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. F Page 19 Of 27 (� �Eo www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9I23O22 - NO PREP - Continued Matrix Spike Dup (9I23022-MSD3) Continued Prepared: 09/23/2019 14:25 Analyzed: 09/23/2019 14:40 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes Sulfide 430 100 ug/L 401 10 U 107 80-120 0.5 25 Batch 9I24O1B - NO PREP Blank (9I24018-BLK3) Prepared: 09/24/2019 14:40 Analyzed: 09/24/2019 14:40 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 14000 U 15000 ug/L LCS (9I24O18-BS1) Prepared: 09/24/2019 14:40 Analyzed: 09/24/2019 14:40 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 100 15 mg/L 100 100 80-120 Matrix Spike (9I24O18-MSI) Prepared: 09/24/2019 14:42 Analyzed: 09/24/2019 14:42 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 350000 30000 ug/L 80000 300000 52 80-120 QM-07 Matrix Spike Dup (9I24018-MSD3) Prepared: 09/24/2019 14:42 Analyzed: 09/24/2019 14:42 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 350000 30000 ug/L 80000 300000 56 80-120 0.8 25 QM-07 Batch 9I25O1O - Same Blank (9I25010-BLK1) Prepared: 09/25/2019 09:30 Analyzed: 09/25/2019 15:02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 10000 U 10000 ug/L LCS (9I25O10-BS1) Prepared: 09/25/2019 09:30 Analyzed: 09/25/2019 15:02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 510000 10000 ug/L 500000 102 90-110 Matrix Spike (9I25O1O-MS3) Prepared: 09/25/2019 09:30 Analyzed: 09/25/2019 15:02 Source: CC12869-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 3.2E7 400000 ug/L 2.00E7 1.2E7 100 90-110 Matrix Spike Dup (9I25O1O-MSD1) Prepared: 09/25/2019 09:30 Analyzed: 09/25/2019 15:02 Source: CC12869-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chemical Oxygen Demand 3.2E7 400000 ug/L 2.00E7 1.2E7 98 90-110 0.8 10 Batch 9I25O39 - NO PREP FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 20 Of 27 (� �Eo www.encolabs.com QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9125039 - NO PREP - Continued Blank (9I25039-BLK3) Prepared: 09/25/2019 15:53 Analyzed: 09/25/2019 15:53 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 41 U 100 ug/L LCS (9I25039-BSI) Prepared: 09/25/2019 15:51 Analyzed: 09/25/2019 15:51 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 1.3 0.10 mg/L 1.25 103 90-110 Matrix Spike (9I25039-MSI) Prepared: 09/25/2019 15:57 Analyzed: 09/25/2019 15:57 Source: CC11206-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 2600 500 ug/L 2500 200 U 106 90-110 Matrix Spike (9I25039-MS2) Prepared: 09/25/2019 16:02 Analyzed: 09/25/2019 16:02 Source: CC13115-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 8500 500 ug/L 2500 5800 106 90-110 Matrix Spike Dup (9I25039-MSD3) Prepared: 09/25/2019 15:59 Analyzed: 09/25/2019 15:59 Source: CC11206-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Nitrate/Nitrite as N 2600 500 ug/L 2500 200 U 105 90-110 1 10 Volatile Fatty Acids by HPLC - Quality Control Batch 9125018 - NA Blank (9I25018-BLK3) Prepared: 09/25/2019 09:20 Analyzed: 09/25/2019 10:39 Analvte Result Flag POL Units Acetic Acid 180 U 200 ug/L Butyric Acid 89 U 100 ug/L Hexanoic Acid 260 U 500 ug/L iso-Hexanoic Acid 440 U 500 ug/L iso-Pentanoic Acid 180 U 200 ug/L Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 130 U 140 ug/L Pentanoic Acid 140 U 200 ug/L Propionic Acid 65 U 100 ug/L Pyruvic Acid 21 U 70 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Trimethylacetic acid 21000 ug/L 20000 103 50-150 LCS (9I25018-BS1) Prepared: 09/25/2019 09:20 Analyzed: 09/25/2019 11:17 Spike Source %REC Analvte Result Flag POL Units Level Result %REC Limits Acetic Acid 21000 200 ug/L 20000 105 60-123 Butyric Acid 15000 100 ug/L 20000 76 54-133 Hexanoic Acid 21000 500 ug/L 20000 106 62-146 iso-Hexanoic Acid 18000 500 ug/L 20000 91 36-168 iso-Pentanoic Acid 23000 200 ug/L 20000 114 59-138 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. RPD RPD Limit Notes Page 21 of 27 QUALITY CONTROL DATA Volatile Fatty Acids by HPLC - Quality Control Batch 9I25018 - NA - Continued (� �Eo www.encolabs.com LCS (9I25018-BS1) Continued Prepared: 09/25/2019 09:20 Analyzed: 09/25/2019 11:17 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 45000 140 ug/L 40000 111 73-131 Pentanoic Acid 17000 200 ug/L 20000 87 63-131 Propionic Acid 17000 100 ug/L 20000 83 74-121 Pyruvic Acid 20000 70 ug/L 20000 100 44-137 Trimethylacetic acid 20000 ug/L 20000 100 50-150 LCS Dup (9I25018-BSDI) Prepared: 09/25/2019 09:20 Analyzed: 09/25/2019 11:56 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Acetic Acid 20000 200 ug/L 20000 102 60-123 3 25 Butyric Acid 14000 100 ug/L 20000 69 54-133 10 25 Hexanoic Acid 21000 500 ug/L 20000 103 62-146 3 25 iso-Hexanoic Acid 18000 500 ug/L 20000 90 36-168 2 25 iso-Pentanoic Acid 22000 200 ug/L 20000 111 59-138 3 25 Lactic Acid/HIBA (2-Hydroxyisobutyric Acid) 44000 140 ug/L 40000 109 73-131 2 25 Pentanoic Acid 17000 200 ug/L 20000 84 63-131 4 25 Propionic Acid 16000 100 ug/L 20000 82 74-121 1 25 Pyruvic Acid 20000 70 ug/L 20000 101 44-137 0.5 25 Trimethylacetic acid 20000 ug/L 20000 101 50-150 Classical Chemistry Parameters - Quality Control Batch 9I23042 - NO PREP Blank (9I23042-BLK3) Prepared: 09/25/2019 11:00 Analyzed: 09/25/2019 14:01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Organic Carbon 340 U 1000 ug/L LCS (9I23042-BS1) Prepared: 09/25/2019 11:00 Analyzed: 09/25/2019 14:01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Organic Carbon 36000 1000 ug/L 40000 91 85-115 Matrix Spike (9I23042-MS1) Prepared: 09/25/2019 11:00 Analyzed: 09/25/2019 14:01 Source: CC13965-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Organic Carbon 51000 1000 ug/L 40000 23000 68 85-115 QM-07 Matrix Spike Dup (9I23042-MSD3) Prepared: 09/25/2019 11:00 Analyzed: 09/25/2019 14:01 Source: CC13965-05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Organic Carbon 51000 1000 ug/L 40000 23000 69 85-115 0.9 21 QM-07 Dissolved Gases by GC - Quality Control Batch 9I20008 - Same FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 22 Of 27 (� �Eo www.encolabs.com QUALITY CONTROL DATA Dissolved Gases by GC - Quality Control Batch 9I20008 - Same - Continued Blank (9I20008-BLK3) Prepared: 09/20/2019 10:07 Analyzed: 09/23/2019 11:18 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Carbon dioxide 770 U 2500 ug/L Ethane 1.30 U 2.00 ug/L Ethene 1.50 U 3.00 ug/L Methane 0.450 U 1.00 ug/L LCS (9I20008-BSI) Prepared: 09/20/2019 10:07 Analyzed: 09/23/2019 11:34 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Carbon dioxide 49700 2.50 mg/L 49900 100 80-120 Ethane 547 0.00200 mg/L 500 109 80-120 Ethene 541 0.00300 mg/L 500 108 80-120 Methane 510 0.00100 mg/L 500 102 80-120 LCS Dup (9I20008-BSD1) Prepared: 09/20/2019 10:07 Analyzed: 09/23/2019 11:50 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Carbon dioxide 50700 2.50 mg/L 49900 102 80-120 2 25 Ethane 565 0.00200 mg/L 500 113 80-120 3 25 Ethene 554 0.00300 mg/L 500 111 80-120 2 25 Methane 514 0.00100 mg/L 500 103 80-120 0.8 25 Duplicate (9I20008-DUP1) Prepared: 09/20/2019 10:07 Analyzed: 09/23/2019 12:54 Source: CC13965-01 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Carbon dioxide 71600 2500 ug/L 74100 3 25 Ethane 1.30 U 2.00 ug/L 1.30 U 25 Ethene 1.50 U 3.00 ug/L 1.50 U 25 Methane 1.93 1.00 ug/L 1.56 21 25 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 23 Of 27 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QB-06 The continuing calibration blank had a positive result for the analyte; however, the concentration in the continuing calibration blank is less than 10% of the sample result. There is minimal impact to the data. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QV-01 The associated continuing calibration verification standard exhibited high bias; since the result is ND, there is no impact. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 24 Of 27 2 Ir.11 C 0 [9 m a C.001 T N N _ ry C3 an c i ,n 3 ;.? ' ]h O 2 0 C> C> Q n Q i v�� CD Cr W 1 i ...i i J i (!J 1 i i 1 i r m = iV Q W V1 0 2 7 m r m Aft Nin maZ. - n rn . v CIDrr p�ry� �P V�i w� -- 2 0 ❑ Z r C� r _r n O 3 p�. �l a° Ts �y n� r % r�.} 1 �, �1 ❑ l- p m m R o N'o W = w W e o Z "1 �.1 fJ1 Vi 0 ❑ 5 Ow n 5 3 3 67 a En d C,m o r o 09 m fD� 0 y �] 7 A 0 m CO % .. Z e r m o< `mod r^ a �s 1 " x $ Z R, �8 u F > S ❑ cn h7 M1] iU IV C x 8260D m U) x x x x Alkalinity 310I.Chlodde 300.Nitrite as N 3512 0 2 x x x x x x x BOD SM5210B z � 1 x x x x x x x CAD SM52201) p z➢ 0 h x x x x x x x Fatty Acids w x x x x x x x 3 NOX 353.2 a w C7 0 x x x x x x x t RSK 175 + CO2 LP 0 � v x x x x x x x t�! Sulfate 300 x x x x x x x Sulfide SM4500-S D x x x x x x x TOC SM531 OB o � � mom i^► I ` • O lm co W `° I x a @fCD o Q C m NCr N D Cl N 0) Q ` Page 25 of 27 Sample Preservation Verification ENCO Cary Work Order: CC13965 Project: Henderson Co. LF MNA Client: Golder Associates, Inc. (00007) Project #: 0839650618.103 Logged In: 19-Sep-19 09:48 __ Logged By: John C King Preservation Check Performed By: i t, DatelTime: CC13965-01 Cont Type Pres (PH) PH Checked I pH Adjusted Datellime Reagent Used/Comments yP Requirement In Control Adjusted F 250mLP+H2SO4 <2 Y I N! NA Y CW1 NA G 250mLP+ZnAc+NaOH >9 Y I N I NA Y (N) 1 NA CC13965-02 Cont Type Pres (pH) pH Checked 1 pH Adjusted Datefiime Reagent Used/Comments Requirement In Control Adjusted F 250mLP+H2SO4 <2 `Y I N I NA Y l 1 NA G 250mLP+ZnAc+NaOH >9 Y I N I NA YIN I NA CC:13965-01 Cont Type Pres (PH) PH Checked/ PH Adjusted DateMme Reagent Used/Comments Requirement In Control Adjusted F 25GmLP+H2SO4 <2 1 N I NA Y I I NA G 250mLP+ZnAc+NaOH >9 I N I NA Y I b 1 NA Cont Type Pres (pH) PH Checked ! PH Adjusted DatelTime Reagent Used/Comments Requirement In Control Adjusted F 250mLP+H2SO4 E2 1^ 1 N! NA Y 1 1 NA G 250mLP+ZnAc+NaOH >S I N I NA Y! 1 NA CC13965-05 'Cont Type Pres (PH) PH Checked 1 pH Adjusted DateMme Reagent Used/Comments Requirement In Control Adjusted F 250mLP+H28O4 <2 ! N I NA YIN 1 NA G 250mLP+ZnAc+Naafi >9 I N I NA Y I 1 NA CC 13965-06 Cant yP Type Pres (PH) pH Checked I PH Adjusted DateMme Reagent UsedlComments Requirement In Control Adjusted F 250mLP+H2SO4 <2 I N I NA Y I`& NA G 250mLP+ZnAc+NaOH >9 I N I NA Y I I NA CCI39r;5-07 Cont Type Pres (pH) Requirement pH Checked 1 In Control PH Adjusted Daterrime Adjusted Reagent Used/Comments F 250mLP+H2SO4 <2 'Y ! N I NA Y I 1 NA G 250mLP+ZnAc+NaOH >9 I N I NA Y ITN/ NA Page 26 of 27 C:IELMNTIPrintlwko_PreservationCheck. rpt Sample Preservation Verification ENCo Cary Work Order: CC13965 Client: Golder Associates, Inc. (GO007) 0 Project: Henderson Co. LF MNA Project #: 0839650618.103 Logged In: 19-Sep-19 09:48 Logged By: John C King j Preservation Check Performed By: Datef ime: f "Iq l 00 Reagent Name ID 1 2 pH Strip ID: Reagent Name I❑ 3 4 Reacient Name ID 5 6 C:IE LM NT1P rintlwko_PreservationCheck, rpt Page 27 of 27 age 7 ❑ 2 WORK ORDER Printed: 10/1/2019 2:32:46PM CC13965 ENCO Cary Sample Receipt Conditions Client: Golder Associates, Inc. (G0007) Lab Project Mgr: Meghan K Shea Project: Henderson Co. LF MNA Project Number: 0839650618.103 PO #: Report To: Invoice To: Golder Associates, Inc. (G0007) Golder Associates, Inc. (G0007) Dusty Reedy Accounts Payable 5B Oak Branch Drive 5B Oak Branch Drive Greensboro, NC 27407 Greensboro, NC 27407 Phone: (336) 852-4903 Phone :(804) 358-7900 Fax: (336) 852-4904 Fax:804-358-2900 Received By: John C King Date Received: 19-Sep-19 09:30 Logged In By: John C King Date Logged In: 19-Sep-19 09:48 Work Order Comments: C-202 received at 2.4°C Containers Intact Y Containers Properly Preserved Y Proper Containers Received Y All Samples in PreLog Received Y COC/Labels Agree Y Custody Seals Intact Y Volatile Containers Preserved Y Volatile Containers Headspace Free Y Aqueous Samples Checked for Residual Cl N Received On Ice Y Temperature Corrected Y Default Cooler Containers Intact N Containers Properly Preserved N Proper Containers Received N All Samples in PreLog Received N COC/Labels Agree N Custody Seals Intact N Volatile Containers Preserved N Volatile Containers Headspace Free N Aqueous Samples Checked for Residual Cl N Received On Ice N Temperature Corrected N Reviewed By Date Page 1 of 1 GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Henderson County Landfill — MNA Parameters Project Reference Number.- 19128179.101 Sampling Event Date: September 18-19, 2019 Review Date: October 21, 2019 Report #: CC13965 Val I Signature: Va le4 Pa, D'c f re 1 C�( QA/QC Sign Off: Date: - ( 7 ` Z D Z6 Date: GOLDER Initials: DC Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) — NC Closed Facility List (.500 Rules) — NC C & D List (New Rules) — NC Appendix I — NC Appendix I + Detects — NC Appendix II NC Subtitle D Leachate List Other: MNA Parameters: Nitrate, Total Iron, Sulfate, Sulfide, Alkalinity, Chloride, TOC, Methane Ethane Ethene, BOD, COD, Carbon Dioxide, Volatile Fatty Acids, and COCs 1.0 CHAIN OF CUSTODY (COC) REVIEW DC COC was properly signed by all parties. DC Correct project name and number are on the form. ➢ Should be 19128179.101 —listed as 08396506018.102 DC Sample receipt condition at laboratory was acceptable. DC Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES 4 GOLDER DC Holding times for extraction and/or analysis were met for each analytical Method (see below for reference). Review Criteria Method Anal tes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW DC Laboratory analyzed at least one internal blank for each method, where applicable. DC Laboratory blank is interference -free. ➢ The Total Organic Carbon continuing calibration blank had a positive result for the analyte; however, the concentration in the continuing calibration blank is less than 10% of the of the 4501-MW7, 4501- MW8 and 4501-Old MW-2 results. There is minimal impact to the data. ➢ The iso-Pentanoic Acid associated continuing calibration verification standard exhibited high bias; since all the sample results were non -detect, there is no impact. DC Surrogate recoveries are provided for each analytical method, where applicable. DC Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). DC MS/MSD/LCS data results are provided for each analytical method. DC MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). ➢ The spike recovery of Alkalinity, Chloride, Nitrate/Nitrite (NOx), Nitrite, Total Organic Carbon and Sulfate were outside of control limits for the MS and/or MSD samples. The QC batch was approved based on acceptable LCS recovery of these analytes. 4.0 ANALYTE LISTS/METHODS DC The proper number of constituents are present for each analyte list as identified above (including detects where applicable). DC Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING DC All analytical reporting associated with the event was performed by the contracted lab. DC Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW G O L D E R Page 3 of 3 blanks are listed below by constituent. All laboratory method blanks, if any, have been 'flagged' with a 'B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. DC It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 10x resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. ➢ MW-6 • CO2 (21x) • Methane (21 x) ➢ MW-7 • Alkalinity (2x) • CO2 (5x) ➢ MW-8 • Alkalinity (5x) • CO2 (5x) • Methane (5x) ➢ AMW-1 S • CO2 (2.1x) ➢ AMW-2S • CO2 (2.1x) ➢ Old MW-2 • CO2 (10x) DC The report provides the reporting limit for each constituent. DC The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. DC No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. DC No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). DC Other report issues/Communications with laboratory/etc.: /� ace RnalX caJ October 7, 2019 David Reedy Golder Associates 5B Oak Branch Dr Greensboro, NC 27407 RE: HENDERSON / 0839650618 Pace Workorder. 31464 Dear David Reedy: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, September 19, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Ruth Welsh 10/07/2019 Ruth.Welsh@pacelabs.com Customer Service Representative Enclosures Report ID: 31464 - 1211815 As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 26 Page 1 of 25 Pace Analytical Energy Services LLC �}^Q �7 r + f 220 William Pitt Way ac A! alyfica7 Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 25 ace RnalX caJ SAMPLE SUMMARY Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 314640001 MW5 Water 9/18/2019 09:07 9/19/2019 11:15 314640002 MW6 Water 9/18/201911:00 9/19/2019 11:15 314640003 MW7 Water 9/18/201912:25 9/19/2019 11:15 314640004 MW8 Water 9/18/2019 09:05 9/19/2019 11:15 314640005 AMW1S Water 9/18/201913:22 9/19/2019 11:15 314640006 AMW2S Water 9/18/201913:05 9/19/2019 11:15 314640007 OLD MW2 Water 9/18/2019 11:02 9/19/2019 11:15 314640008 MW5 Bubble Strip 9/18/2019 09:07 9/19/2019 11:15 314640009 MW6 Bubble Strip 9/18/2019 11:00 9/19/2019 11:15 314640010 MW7 Bubble Strip 9/18/2019 12:25 9/19/2019 11:15 314640011 MW8 Bubble Strip 9/18/2019 09:05 9/19/2019 11:15 314640012 AMW1S Bubble Strip 9/18/2019 13:22 9/19/2019 11:15 314640013 AMW2S Bubble Strip 9/18/2019 13:05 9/19/2019 11:15 314640014 OLD MW2 Bubble Strip 9/18/2019 11:02 9/19/2019 11:15 Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 25 ace RnalX caJ PROJECT SUMMARY Workorder: 31464 HENDERSON / 0839650618 Workorder Comments Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The original analysis of the samples 31464 (0002, 0004) was conducted within the procedural holdtime of 48 hours from collection; method Dionex Tech Note 10 Mtd A. Subsequent dilutions of the samples were conducted outside the assigned holding time period. Analyte Ferrous Iron. The original analysis of samples 31464 (0009-0014) were conducted 09/28/2019, within the procedural holdtime of 14 days from collection; method AM20GAx. Subsequent dilutions and/or re -analysis of the samples were conducted outside the assigned holding time period. Because the bubble samples were collected using PAES procedure SM9, any affect to the vapor phase component concentrations due to the delay of the analysis is expected to be minimal. Batch Comments Batch: EACC/2912 - Cations by IC The percent recovery for the laboratory control sample (63409) was below laboratory control limits. Analytes Ferric Iron. Samples affected by this specific LCS shall be reanalyzed. Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 25 ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640001 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: MW5 Date Collected: 9/18/2019 09:07 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron <0.50 mg/I 0.50 0.12 1 9/19/2019 18:22 MD n Report ID: 31464 - 1211815 Page 5 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640002 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: MW6 Date Collected: 9/18/2019 11:00 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron 49 mg/I 2.5 0.60 5 9/20/2019 12:33 MD d,H1,n Report ID: 31464 - 1211815 Page 6 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640003 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: MW7 Date Collected: 9/18/2019 12:25 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron 11 mg/I 0.50 0.12 1 9/19/2019 20:08 MD n Report ID: 31464 - 1211815 Page 7 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640004 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: MW8 Date Collected: 9/18/2019 09:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron 26 mg/I 2.5 0.60 5 9/20/2019 12:59 MD d,H1,n Report ID: 31464 - 1211815 Page 8 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640005 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: AMW1S Date Collected: 9/18/2019 13:22 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron <0.50 mg/I 0.50 0.12 1 9/19/2019 21:00 MD n Report ID: 31464 - 1211815 Page 9 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640006 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: AMW2S Date Collected: 9/18/2019 13:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron <0.50 mg/I 0.50 0.12 1 9/19/2019 21:26 MD n Report ID: 31464 - 1211815 Page 10 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ I_1► /t1>A'I11111 li [Illf_T111111 0 *411%V Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640007 Date Received: 9/19/2019 11:15 Matrix: Water Sample ID: OLD MW2 Date Collected: 9/18/2019 11:02 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EAcceptors - PAES Analysis Desc: Dionex Tech Note 10 Analytical Method: Dionex Tech Note 10 Mtd A Mtd A Ferrous Iron 1.5 mg/I 0.50 0.12 1 9/19/2019 23:37 MD n Report ID: 31464 - 1211815 Page 11 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640008 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: MW5 Date Collected: 9/18/2019 09:07 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 24 nM 1.0 0.75 1 9/28/2019 05:29 TD n Report ID: 31464 - 1211815 Page 12 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640009 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: MW6 Date Collected: 9/18/2019 11:00 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 120 nM 8.0 6.0 8 10/3/201911:40 MM d,H1,n Report ID: 31464 - 1211815 Page 13 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640010 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: MW7 Date Collected: 9/18/2019 12:25 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 64 nM 2.0 1.5 2 10/3/201911:52 MM d,H1,n Report ID: 31464 - 1211815 Page 14 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640011 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: MW8 Date Collected: 9/18/2019 09:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 84 nM 4.0 3.0 4 10/3/201912:05 MM d,H1,n Report ID: 31464 - 1211815 Page 15 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640012 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: AMW1S Date Collected: 9/18/2019 13:22 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 98 nM 4.0 3.0 4 10/3/201912:24 MM d,H1,n Report ID: 31464 - 1211815 Page 16 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640013 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: AMW2S Date Collected: 9/18/2019 13:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 170 nM 20 15 20 10/3/201912:41 MM d,H1,n Report ID: 31464 - 1211815 Page 17 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ace RnalX caJ Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 314640014 Date Received: 9/19/2019 11:15 Matrix: Bubble Strip Sample ID: OLD MW2 Date Collected: 9/18/2019 11:02 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 110 nM 8.0 6.0 8 10/3/201912:54 MM d,H1,n Report ID: 31464 - 1211815 Page 18 of 25 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. /� ace RnalX caJ ANALYTICAL RESULTS QUALIFIERS Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. H1 The sample was prepared or the analysis was conducted outside the method specific holding time. d The analyte concentration was determined from a dilution. Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 19 of 25 ace RnalX caJ QUALITY CONTROL DATA Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EACC/2911 Analysis Method: Dionex Tech Note 10 Mtd A QC Batch Method: Dionex Tech Note 10 Mtd A Associated Lab Samples: 314640001, 314640003, 314640005, 314640006, 314640007 METHOD BLANK: 63354 Blank Reporting Parameter Units Result Limit Qualifiers EAcceptors Ferrous Iron mg/I <0.50 0.50 n LABORATORY CONTROL SAMPLE: 63355 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Ferrous Iron mg/I 10 9.6 96 90-110 n MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 63356 63357 Original: 314640001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EAcceptors Ferrous Iron mg/I 0 10 9.5 9.3 95 93 70-130 2.2 20 n Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 20 of 25 Pace Analytical Energy Services LLC 220 William Pitt Way aceRnalX caJ,n Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QUALITY CONTROL DATA Workorder: 31464 HENDERSON / 0839650618 QC Batch: EACC/2912 Analysis Method: Dionex Tech Note 10 Mtd A QC Batch Method: Dionex Tech Note 10 Mtd A Associated Lab Samples: 314640002, 314640004 METHOD BLANK: 63381 Blank Reporting Parameter Units Result Limit Qualifiers EAcceptors Ferrous Iron mg/I <0.50 0.50 n METHOD BLANK: 63408 Blank Reporting Parameter Units Result Limit Qualifiers EAcceptors Ferrous Iron mg/I <0.50 0.50 n LABORATORY CONTROL SAMPLE: 63382 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Ferrous Iron mg/I 10 10 100 90-110 n LABORATORY CONTROL SAMPLE: 63409 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Ferrous Iron mg/I 10 11 108 90-110 n MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 63383 63384 Original: 314740001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EAcceptors Ferrous Iron mg/I 0 10 9.6 9.8 96 98 70-130 2.1 20 n Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 21 of 25 ace RnalX caJ QUALITY CONTROL DATA Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7800 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 314640008 METHOD BLANK: 63466 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 63467 63468 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 26 26 107 107 80-120 0.035 20 n Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 22 of 25 ace RnalX caJ QUALITY CONTROL DATA Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7810 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 314640009, 314640010, 314640011, 314640012, 314640013, 314640014 METHOD BLANK: 63534 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM <1.0 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 63535 63536 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 25 26 105 105 80-120 0.48 20 n Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 23 of 25 /� ace RnalX caJ QUALITY CONTROL DATA QUALIFIERS Workorder: 31464 HENDERSON / 0839650618 QUALITY CONTROL PARAMETER QUALIFIERS H2 The sample was received or analysis was requested outside the method specific holding time. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 24 of 25 ace RnalX caJ QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 31464 HENDERSON / 0839650618 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 314640001 MW5 Dionex Tech Note 10 EACC/2911 Mtd A 314640003 MW7 Dionex Tech Note 10 EACC/2911 Mtd A 314640005 AMW1S Dionex Tech Note 10 EACC/2911 Mtd A 314640006 AMW2S Dionex Tech Note 10 EACC/2911 Mtd A 314640007 OLD MW2 Dionex Tech Note 10 EACC/2911 Mtd A 314640002 MW6 Dionex Tech Note 10 EACC/2912 Mtd A 314640004 MW8 Dionex Tech Note 10 EACC/2912 Mtd A 314640008 MW5 AM20GAX DISG/7800 314640009 MW6 AM20GAX DISG/7810 314640010 MW7 AM20GAX DISG/7810 314640011 MW8 AM20GAX DISG/7810 314640012 AMW1S AM20GAX DISG/7810 314640013 AMW2S AM20GAX DISG/7810 314640014 OLD MW2 AM20GAX DISG/7810 Report ID: 31464 - 1211815 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 25 of 25 m :10 rD 11 � . rD n n * O d �� N D O n O n y o 4 m -0 3 s �. n c n O rD -0 a °- o O o= ° rD rD rD S S S (D eM max, - .,� ` ro x n p o- o- -" V..- a a a 0- a s 3 6 @a 3 ao ° o < < it` �' ad a Sy < < < w 41 rD N o _. �°.•- rD f �D a O O O m � y ? Z 3 3 -0 3 V" o ° o rr m F rD 7:, �• rro aNa`Da n O rD F rD r -010 — S w 0 S T l! R, m < m o _ D N ° rD (D xr o p O w 3 Gl° D 2- O c T < rD rD (D_ C 0 0-�y Z] r... ; N m W 3 3 3 a n <° 0 "w & p n 3 O ° N D A z O ° �m ° 0 w r O G1 0 s ,"�' (-;.('< rmK. Vu< 3 C �% ( o rD° a a p o O 7 rD b C E ° o 3 42, n a .rD 4 . G fye �l = m w w < n �' ® a m rf z n n rD n 7� rD n 3 N 3 C C O rD m rD � ° ,. r� o n G o ,—, w a 3 �� u 3 - m °_A _ < < f o' °' p o m a m <° o o m -' 3 v D t �4 4 o C 0 o O - m m m 3 c • rD a p^ z� z m Z `r m a rD O a =o• a• = a ago' -- flID fl m Z - a .' a � �^- is o N 3 3D m w 2 1-`- y.e a `. .. 4 w �f. jJ 1 s , fit. �. 3 s m c' 0. 0 (D rD r. X,r n 5• n- o O D yy� a m - Lm D J p c v D. Z z Nv ° D rD V O C W 2 N . = N C O N rw.f O Xcc G OQ g` m O n * 0 n'1CD 3 m 3 D < �,a DOo �c rrr l O w � r O D Z ,m~. O m rn 4, O 00• r m D. x s Z m O rmi z crr ~' •^•�.. - rp' ti t-� t� V1 ro w 0 jJ En C C w m 0 w 0 0 0 t+ a yy m G xw H m w M o a G 0 0 0 G G- a 'y D- s y a o- v M (D C t7 M a H 3 N l7 M H rt H N N tY a FtmK7 mH-ro Y. ro MH rtHrtrt C H..rt Hrt p.H I HH-m Hm O O. a,=_ G m m. O O ID O a a m m m H- H. a N m tt N H.rt N '(D O w o ID � Z O rth7N wN HH-G w �P wHO. wm ro? mz aH.. �0HP.mrt0p H- (D (D n 3 w n C 3.w3 ti c+ (D > P' a m O c+ c+ W W a �km N ° H +ro (D c+ w H. a O L N rL m E, 3 ° ° ID m o om0H-oHowwNH 0 (D p m H rt rt rt ro H- 0, m m G N a G ro (D o m - M - O 1 O ° : ,-�. O O Dl n H rr 0 F'- w O. 5 + H H H- 3 C rD O ID H n O --. O S m -- ]r. m o w a mp o m: G m m 'U ro tr W H O O H N N rt 3 o- Z C z' O _ m 3 3 m a ° 3 N H ro H°❑ (D (D m m H H N m hi p 0 '�' n .o T < n .. CD .°-r (� C rp ❑ m H- ro H h1 H rt rt N rt O. H m m p. Z N v .. m0_ CL rD O. O < w i m p m tr' m N N p. X. c �' — N 3 = CD R- 3 rt m 0 fi a +H�- m m OOQ z z z z zx{�z`zzzz�z_kG' r _, ;a . D $ GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 3 Project Name: Henderson County Landfill Project Reference Number: 19128179.102 Sampling Event Date: September 18-19, 2019 Review Date: October 14, 2019 Report #: Golder 31464 Signature: (/� V 4r!/ 1 c(- Da cc QA/QC Sign Off: z),���[��A� Date: (-I 7-1G ZG Date: / - / 2 - t o GOLDER Initials: DC Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) NC Closed Facility List (.500 Rules) _ NC C & D List (New Rules) _ NC Appendix I _ NC Appendix I + Detects _ NC Appendix II NC Subtitle D Leachate List Other: Hydrogen & Ferrous Iron 1.0 CHAIN OF CUSTODY (COC) REVIEW DC COC was properly signed by all parties. DC Correct project name and number are on the form. • Project number is listed as 0839650618, should be 19128179.102 DC Sample receipt condition at laboratory was acceptable. DC Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 2 of 3 2.0 SAMPLE HOLDING TIMES .,� GOLDER DC Holding times for extraction and/or analysis were met for each analytical Method (see below for reference). • Hold times for Hydrogen samples were exceeded Review Criteria Method Anal tes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW DC Laboratory analyzed at least one internal blank for each method, where applicable. DC Laboratory blank is interference -free. n/a Surrogate recoveries are provided for each analytical method, where applicable. n/a Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). n/a MS/MSD/LCS data results are provided for each analytical method. n/a MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). 4.0 ANALYTE LISTS/METHODS DC The proper number of constituents are present for each analyte list as identified above (including detects where applicable). DC Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING DC All analytical reporting associated with the event was performed by the contracted lab. DC Trip, field, and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been `flagged' with a 'B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW �jo G Q L D E R Page 3 of 3 DC It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 1 Ox resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. *Ferrous Iron x5 @ MW-6, MW-8 • Hydrogen • x8 @ MW-6, Old MW-2 • x2 @ MW-7 • x4 @ MW-8, AMWAS • x20 @ AMW-2S DC The report provides the reporting limit for each constituent. DC The results were reported at or below their proper reporting limits (i.e., MDLs with SWSLs reported). Those that are not reported correctly are listed below (by constituent) with the proper reporting limit listed beside them. State if the reporting limit error is due to dilutions. n/a No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. n/a No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). n/a Other report issues/Communications with laboratory/etc.: CLOSED C&D LANDFILL September 2019 Compliance Monitoring Event ENCO Laboratones Accurate. Timely. Responsive. Innovative. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Tuesday, October 8, 2019 Golder Associates, Inc. (GO007) Attn: Dusty Reedy 5B Oak Branch Drive Greensboro, NC 27407 RE: Laboratory Results for Project Number: 0839650618.103, Project Name/Desc: Henderson Co. LF C&D ENCO Workorder(s): CC13964 Dear Dusty Reedy, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Friday, September 20, 2019. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, �"n'1 Meghan K Shea Project Manager Enclosure(s) FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 1 of 33 PROJECT NARRATIVE Date: 08 October 2019 Client: Golder Associates, Inc. (G0007) Project: Henderson Co. LF C&D Lab ID: CC13964 REV 1 Overview (� �Eo www.encolabs.com This report is an amendment to the original report dated 07 October 2019 for this work order. This report was revised, to report only 6010D Selenium. Environmental Conservation Laboratories, Inc. (ENCO) analyzed all submitted samples in accordance with the methods referenced in the laboratory report. Any particular difficulties encountered during sample handling by ENCO are discussed in the QC Remarks section below. Quality Control Samples Chloromethane bias low in associated QC but can be detected in the CRL. Since the analyte in all the samples in the work order was not detected, there is no impact on data quality. The Alkalinity spike recovery was outside acceptance limits for the MS and /or MSD. The QC batch was accepted based on acceptable LCS recovery. The Iron and Manganese spike recoveries were outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recoveries. The Sulfate spike recovery was outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recovery. Iron and Manganese post -digestion spike did not meet method requirements due to confirmed matrix effects. Precision between 2,4-D duplicate matrix spikes of the same sample was outside acceptance limits. The QC batch was accepted based on acceptable LCS recovery. The Vinyl acetate associated continuing calibration verification standard exhibited high bias; since all samples in the work order are non -detect, there is no impact. Quality Control Remarks No Comments Other Comments All samples received under this work order arrived in acceptable conditions. The samples were not checked for residual chlorine, as it is not required. The analytical data presented in this report are consistent with the methods as referenced in the analytical report. Any exceptions or deviations are noted in the QC remarks section of this narrative or in the Flags/Notes and Definitions section of the report. Released By: Environmental Conservation Laboratories, Inc. Meghan Shea Project Manager FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2 of 33 (� �Eo www.encolabs.com FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 3 of 33 (� �Eo www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: 4501-MW10 Lab ID: CC13964-01 Sampled: 09/19/19 09:36 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/17/19 09/24/19 14:46 09/24/19 19:23 EPA 310.2 NO PREP 10/03/19 09/24/19 14:43 09/24/19 14:43 EPA 6010D EPA 3005A 03/17/20 09/24/19 15:31 09/26/19 12:47 EPA 6020B EPA 3005A 03/17/20 09/24/19 11:38 09/25/19 13:40 EPA 7470A EPA 7470A 10/17/19 09/25/19 11:01 09/26/19 15:25 EPA 8151A Same 2 09/26/19 11/03/19 09/24/19 22:22 09/26/19 14:06 EPA 8260D EPA 503013_MS 10/03/19 10/01/19 11:34 10/01/19 23:03 EPA 8260D EPA 503013_MS 10/03/19 10/02/19 14:07 10/03/19 06:39 SM 254OC-2011 NO PREP 09/26/19 09/23/19 17:25 09/23/19 17:25 Client ID: 4501-MW11 (MS/MSD) Lab ID: CC13964-02 Sampled: 09/19/19 10:23 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/17/19 09/24/19 14:46 09/24/19 18:30 EPA 310.2 NO PREP 10/03/19 09/24/19 14:41 09/24/19 14:41 EPA 6010D EPA 3005A 03/17/20 09/24/19 15:31 09/26/19 11:28 EPA 6020B EPA 3005A 03/17/20 09/24/19 11:38 09/25/19 12:45 EPA 7470A EPA 7470A 10/17/19 09/25/19 11:01 09/26/19 15:08 EPA 8151A Same 2 09/26/19 11/03/19 09/24/19 22:22 09/26/19 11:35 EPA 8260D EPA 503013_MS 10/03/19 09/30/19 14:34 10/01/19 02:30 EPA 8260D EPA 503013_MS 10/03/19 10/02/19 14:07 10/03/19 02:48 SM 2540C-2011 NO PREP 09/26/19 09/23/19 17:25 09/23/19 17:25 Client ID: 4501-MW11 (MS/MSD) Lab ID: CC13964-02RE1 Sampled: 09/19/19 10:23 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/17/19 09/24/19 14:46 09/24/19 18:12 Client ID: 4501-MW12 Lab ID: CC13964-03 Sampled: 09/19/19 11:10 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/17/19 09/24/19 14:46 09/24/19 20:16 EPA 6010D EPA 3005A 03/17/20 09/24/19 15:31 09/26/19 11:58 EPA 6020E EPA 3005A 03/17/20 09/24/19 11:38 09/25/19 13:45 EPA 7470A EPA 7470A 10/17/19 09/25/19 11:01 09/26/19 15:28 EPA 8151A Same 2 09/26/19 11/03/19 09/24/19 22:22 09/26/19 14:31 EPA 8260D EPA 503013_MS 10/03/19 09/30/19 14:34 10/01/19 05:06 EPA 8260D EPA 503013_MS 10/03/19 10/02/19 14:07 10/03/19 07:18 SM 254OC-2011 NO PREP 09/26/19 09/23/19 17:25 09/23/19 17:25 Client ID: 4501-MW12 Lab ID: CC13964-03RE1 Sampled: 09/19/19 11:10 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 310.2 NO PREP 10/03/19 09/24/19 15:35 09/24/19 15:35 Client ID: 4501-MW13 Lab ID: CC13964-04 Sampled: 09/19/19 09:53 Received: 09/20/19 13:55 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 300.0 NO PREP 10/17/19 09/24/19 14:46 09/24/19 21:09 EPA 310.2 NO PREP 10/03/19 09/24/19 14:44 09/24/19 14:44 EPA 6010D EPA 3005A 03/17/20 09/24/19 15:43 09/26/19 14:02 EPA 6020B EPA 3005A 03/17/20 09/24/19 11:38 09/25/19 13:58 EPA 7470A EPA 7470A 10/17/19 09/25/19 11:01 09/26/19 15:30 EPA 8151A Same 2 09/26/19 11/03/19 09/24/19 22:22 09/26/19 14:56 EPA 8260D EPA 503013_MS 10/03/19 09/30/19 14:34 10/01/19 05:37 EPA 8260D EPA 5030B_MS 10/03/19 10/03/19 00:00 10/03/19 10:53 SM 2540C-2011 NO PREP 09/26/19 09/23/19 17:25 09/23/19 17:25 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 4 Of 33 (� �Eo www.encolabs.com SAMPLE DETECTION SUMMARY Client ID: 4501-MW10 Lab ID: CC13964-01 Anala Results Flag MDL POLL Units Method Notes Barium - Total 2.47 1 1.10 10.0 ug/L EPA 6010D Client ID: 4501-MWll (MS/MSD) Lab ID: CC13964-02 Anala Results Flag MDL POLL Units Method Notes Barium - Total 121 1.10 10.0 ug/L EPA 6010D Beryllium - Total 0.501 1 0.160 1.00 ug/L EPA 6010D cis-1,2-Dichloroethene 1.3 0.15 1.0 ug/L EPA 8260D Cobalt - Total 13.0 1.40 10.0 ug/L EPA 6010D Iron - Total 17100 22.0 50.0 ug/L EPA 6010D Manganese - Total 5950 1.50 10.0 ug/L EPA 6010D Sulfate as SO4 140000 12000 20000 ug/L EPA 300.0 Toluene 0.24 1 0.14 1.0 ug/L EPA 8260D Total Alkalinity as CaCC3 300000 28000 30000 ug/L EPA 310.2 Total Dissolved Solids 570000 50000 50000 ug/L SM 2540C-2011 Zinc - Total 5.76 1 4.40 10.0 ua/L EPA 6010D I Client ID: 4501-MWll (MS/MSD) Lab ID: CC13964-02RE3 Anala Results Flag MDL POLL Units Method Notes Chloride 12000 2200 5000 ug/L EPA 300.0 Client ID: 4501-MW12 Lab ID: CC13964-03 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 10 1.2 2.0 ug/L EPA 8260D Barium - Total 30.1 1.10 10.0 ug/L EPA 6010D Chloride 47000 2200 5000 ug/L EPA 300.0 cis-1,2-Dichloroethene 1.7 0.15 1.0 ug/L EPA 8260D Iron - Total 154 22.0 50.0 ug/L EPA 6010D Manganese - Total 407 1.50 10.0 ug/L EPA 6010D Sulfate as SO4 54000 2900 5000 ug/L EPA 300.0 Tetrahydrofuran 32 0.53 1.0 ug/L EPA 8260D Total Dissolved Solids 510000 50000 50000 ug/L SM 2540C-2011 Vinyl chloride 1.3 0.32 1.0 ug/L EPA 8260D Zinc - Total 5.08 1 4.40 10.0 ug/L EPA 6010D Client ID: 4501-MW12 Lab ID: CC13964-03RE3 Anala Results Flag MDL POLL Units Method Notes Total Alkalinity as CaCC3 280000 D 28000 30000 ug/L EPA 310.2 Client ID: 4501-MW13 Lab ID: CC13964-04 Anala Results Flag MDL POLL Units Method Notes 1,4-Dioxane 2.3 1.2 2.0 ug/L EPA 8260D Barium - Total 14.2 1.10 10.0 ug/L EPA 6010D Chloride 7700 2200 5000 ug/L EPA 300.0 cis-1,2-Dichloroethene 3.0 0.15 1.0 ug/L EPA 8260D Iron - Total 1160 22.0 50.0 ug/L EPA 6010D Manganese - Total 247 1.50 10.0 ug/L EPA 6010D Sulfate as SO4 18000 2900 5000 ug/L EPA 300.0 Tetrahydrofuran 2.1 0.53 1.0 ug/L EPA 8260D Total Alkalinity as CaCC3 140000 14000 15000 ug/L EPA 310.2 Total Dissolved Solids 240000 50000 50000 ug/L SM 2540C-2011 Vinyl chloride 1.9 0.32 1.0 ug/L EPA 8260D FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Pager) Of 33 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW10 Lab Sample ID:CC13964-01 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:36 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,1,1-Trichloroethane [71-55-6]^ 0.12 U ug/L 1 0.12 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,1,2,2-Tetrachloroethane [79-34-5]^ 0.28 U ug/L 1 0.28 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,1,2-Trichloroethane [79-00-5]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,1-Dichloroethane [75-34-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,1-Dichloroethene [75-35-4]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2,3-Trichloropropane [96-18-4]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2-Dibromo-3-chloropropane [96-12-8]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2-Dibromoethane [106-93-4]^ 0.66 U ug/L 1 0.66 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2-Dichlorobenzene [95-50-1]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2-Dichloroethane [107-06-2]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,2-Dichloropropane [78-87-5]^ 0.10 U ug/L 1 0.10 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 1,4-Dichlorobenzene [106-46-7]^ 0.19 U ug/L 1 0.19 1.0 9301011 EPA 8260D 10/01/19 23:03 REF 2-Butanone [78-93-3]^ 1.3 U ug/L 1 1.3 5.0 9301011 EPA 8260D 10/01/19 23:03 REF 2-Hexanone [591-78-6]^ 0.88 U ug/L 1 0.88 5.0 9301011 EPA 8260D 10/01/19 23:03 REF 4-Methyl-2-pentanone [108-10-1]^ 1.1 U ug/L 1 1.1 5.0 9301011 EPA 8260D 10/01/19 23:03 REF Acetone [67-64-1]^ 10 U ug/L 1 10 20 9301011 EPA 8260D 10/01/19 23:03 REF Acrylonitrile [107-13-1]^ 3.5 U ug/L 1 3.5 10 9301011 EPA 8260D 10/01/19 23:03 REF Benzene[71-43-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Bromochloromethane [74-97-5]^ 0.48 U ug/L 1 0.48 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Bromodichloromethane [75-27-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Bromoform [75-25-2]^ 0.22 U ug/L 1 0.22 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Bromomethane [74-83-9]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Carbon disulfide [75-15-0]^ 1.5 U ug/L 1 1.5 5.0 9301011 EPA 8260D 10/01/19 23:03 REF Carbon tetrachloride [56-23-5]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Chlorobenzene[108-90-7]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Chloroethane [75-00-3]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Chloroform [67-66-3]^ 0.18 U ug/L 1 0.18 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Chloromethane [74-87-3]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 23:03 REF cis-1,2-Dichloroethene [156-59-2]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 23:03 REF cis-1,3-Dichloropropene [10061-01-5]^ 0.20 U ug/L 1 0.20 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Dibromochloromethane [124-48-1]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Dibromomethane [74-95-3]^ 0.27 U ug/L 1 0.27 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Ethylbenzene[100-41-4]^ 0.13 U ug/L 1 0.13 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Iodomethane [74-88-4]^ 1.7 U ug/L 1 1.7 5.0 9301011 EPA 8260D 10/01/19 23:03 REF Methylene chloride [75-09-2]^ 0.23 U ug/L 1 0.23 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Styrene[100-42-5]^ 0.11 U ug/L 1 0.11 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Tetrachloroethene [127-18-4]^ 0.17 U ug/L 1 0.17 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Tetrahydrofuran [109-99-9]^ 0.53 U ug/L 1 0.53 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Toluene [108-88-3]^ 0.14 U ug/L 1 0.14 1.0 9301011 EPA 8260D 10/01/19 23:03 REF trans-1,2-Dichloroethene [156-60-5]^ 0.21 U ug/L 1 0.21 1.0 9301011 EPA 8260D 10/01/19 23:03 REF trans-1,3-Dichloropropene [10061-02-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 23:03 REF trans-1,4-Dichloro-2-butene [110-57-6]^ 0.70 U ug/L 1 0.70 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Trichloroethene [79-01-6]^ 0.15 U ug/L 1 0.15 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Trichlorofluoromethane [75-69-4]^ 0.24 U ug/L 1 0.24 1.0 9301011 EPA 8260D 10/01/19 23:03 REF Vinyl acetate [108-05-4]^ 0.95 U ug/L 1 0.95 5.0 9301011 EPA 8260D 10/01/19 23:03 REF QV-01 Vinyl chloride [75-01-4]^ 0.32 U ug/L 1 0.32 1.0 9301011 EPA 8260D 10/01/19 23:03 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 6 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW10 Lab Sample ID:CC13964-01 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:36 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9301011 EPA 8260D 10/01/19 23:03 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 43 1 50.0 86 % 53-136 9701011 EPA 8260D 10101119 23:03 REF Dlbromofluoromethane 46 1 50.0 92 % 67-129 9701011 EPA 8260D 10101119 23:03 REF Toluene-d8 38 1 50.0 75 % 59-134 9701011 EPA 8260D 10101119 23:03 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25030 EPA 7470A 09/26/19 15:25 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020B 09/25/19 13:40 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Barium [7440-39-3]^ 2.47 J ug/L 1 1.10 10.0 9124037 EPA 6010D 09/26/19 12:47 JDH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24037 EPA 6010D 09/26/19 12:47 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24037 EPA 6010D 09/26/19 12:47 JDH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Iron [7439-89-6]^ 22.0 U ug/L 1 22.0 50.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Manganese [7439-96-5]^ 1.50 U ug/L 1 1.50 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020B 09/25/19 13:40 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Zinc[7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 9I24037 EPA 6010D 09/26/19 12:47 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Chloride [16887-00-6]^ 2200 U ug/L 1 2200 5000 9I24034 EPA 300.0 09/24/19 19:23 PDK Sulfate as SO4 [14808-79-8]^ 2900 U ug/L 1 2900 5000 9I24034 EPA 300.0 09/24/19 19:23 PDK Total Alkalinity as CaCO3 [471-34-1]^ 14000 U ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:43 NMN Total Dissolved Solids^ 50000 U ug/L 1 50000 50000 9I23003 SM 2540C-2011 09/23/19 17:25 JOC FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 7 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW10 Lab Sample ID:CC13964-01 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:36 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando Certified analyte [NC 424] Analyte MAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]A 1.2 u ug/L 1 1.2 2.0 9302042 EPA 8260D 10/03/19 06:39 KKW Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-& 5.8 1 5.00 117 % 75-125 9702042 EPA 8260D 10103119 0629 KKW Chlorinated Herbicides by GC A - ENCO Orlando Certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes 2,4-D [94-75-7]A 0.27 u ug/L 1 0.27 0.50 9I24050 EPA 8151A 09/26/19 14:06 RGG Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes 2,4-DCAA 0.98 1 2.00 49 % 37-134 9124050 EPA 6151A 09126119 14:06 RGG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 8 Of 33 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW11 (MS/MSD) Lab Sample ID:CC13964-02 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 10:23 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 U ug/L 1 0.12 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 U ug/L 1 0.28 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 U ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,1-Dichloroethane [75-34-3]A 0.13 U ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,1-Dichloroethene [75-35-4]A 0.21 U ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 U ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 U ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2-Dibromoethane [106-93-4]A 0.66 U ug/L 1 0.66 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 U ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2-Dichloroethane [107-06-2]A 0.21 U ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,2-Dichloropropane [78-87-5]A 0.10 U ug/L 1 0.10 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 U ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF 2-Butanone [78-93-3]A 1.3 U ug/L 1 1.3 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF 2-Hexanone [591-78-6]A 0.88 U ug/L 1 0.88 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 U ug/L 1 1.1 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF Acetone [67-64-1]A 10 U ug/L 1 10 20 9I30034 EPA 8260D 10/01/19 02:30 REF Acrylonitrile [107-13-1]A 3.5 U ug/L 1 3.5 10 9I30034 EPA 8260D 10/01/19 02:30 REF Benzene[71-43-2]A 0.15 U ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Bromochloromethane [74-97-5]A 0.48 U ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Bromodichloromethane [75-27-4]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Bromoform [75-25-2]A 0.22 U ug/L 1 0.22 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Bromomethane [74-83-9]A 0.14 U ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Carbon disulfide [75-15-0]A 1.5 U ug/L 1 1.5 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF Carbon tetrachloride [56-23-5]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Chlorobenzene[108-90-7]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Chloroethane [75-00-3]A 0.23 U ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Chloroform [67-66-3]A 0.18 U ug/L 1 0.18 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Chloromethane [74-87-3]A 0.13 U ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF cis-1,2-Dichloroethene [156-59-2]A 1.3 ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 U ug/L 1 0.20 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Dibromochloromethane [124-48-1]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Dibromomethane [74-95-3]A 0.27 U ug/L 1 0.27 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Ethylbenzene [100-41-4]A 0.13 U ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Iodomethane [74-88-4]A 1.7 U ug/L 1 1.7 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF Methylene chloride [75-09-2]A 0.23 U ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Styrene [100-42-5]A 0.11 U ug/L 1 0.11 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Tetrachloroethene [127-18-4]A 0.17 U ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Tetrahydrofuran [109-99-9]A 0.53 U ug/L 1 0.53 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Toluene [108-88-3]A 0.24 J ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 U ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 U ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 U ug/L 1 0.70 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Trichloroethene [79-01-6]A 0.15 U ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Trichlorofluoromethane [75-69-4]A 0.24 U ug/L 1 0.24 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF Vinyl acetate [108-05-4]A 0.95 U ug/L 1 0.95 5.0 9I30034 EPA 8260D 10/01/19 02:30 REF QV-01 Vinyl chloride [75-01-4]A 0.32 U ug/L 1 0.32 1.0 9I30034 EPA 8260D 10/01/19 02:30 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 9 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MWll (MS/MSD) Lab Sample ID:CC13964-02 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 10:23 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I30034 EPA 8260D 10/01/19 02:30 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 45 1 50.0 91 % 53-136 9130034 EPA 8260D 10101119 02:30 REF Dlbromofluoromethane 45 1 50.0 90 % 67-129 9130034 EPA 8260D 10101119 02:30 REF Toluene-d8 37 1 50.0 73 % 59-134 9130034 EPA 8260D 10101119 0230 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25030 EPA 7470A 09/26/19 15:08 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020B 09/25/19 12:45 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Barium [7440-39-3]^ 121 ug/L 1 1.10 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Beryllium [7440-41-7]^ 0.501 J ug/L 1 0.160 1.00 9I24037 EPA 6010D 09/26/19 11:28 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24037 EPA 6010D 09/26/19 11:28 JDH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Cobalt[7440-48-4]^ 13.0 ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Iron [7439-89-6]^ 17100 ug/L 1 22.0 50.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Manganese [7439-96-5]^ 5950 ug/L 1 1.50 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020B 09/25/19 12:45 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Zinc[7440-66-6]^ 5.76 J ug/L 1 4.40 10.0 9I24037 EPA 6010D 09/26/19 11:28 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Chloride [16887-00-6]^ 12000 ug/L 1 2200 5000 9I24034 EPA 300.0 09/24/19 18:12 PDK Sulfate as SO4 [14808-79-8]^ 140000 ug/L 4 12000 20000 9I24034 EPA 300.0 09/24/19 18:30 PDK Total Alkalinity as CaCO3 [471-34-1]^ 300000 ug/L 2 28000 30000 9I24018 EPA 310.2 09/24/19 14:41 NMN Total Dissolved Solids^ 570000 ug/L 1 50000 50000 9I23003 SM 2540C-2011 09/23/19 17:25 JOC FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 10 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MWll (MS/MSD) Lab Sample ID:CC13964-02 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 10:23 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando Certified analyte [NC 424] Analyte MAS Numberl Results Flao Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]A 1.2 u ug/L 1 1.2 2.0 9302042 EPA 8260D 10/03/19 02:48 KKW Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-& 6.0 1 5.00 120 % 75-125 9702042 EPA 8260D 10103119 02:48 KKW Chlorinated Herbicides by GC A - ENCO Orlando Certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes 2,4-D [94-75-7]A 0.27 u ug/L 1 0.27 0.50 9I24050 EPA 8151A 09/26/19 11:35 RGG Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes 2,4-DCAA 0.93 1 2.00 46 % 37-134 9124050 EPA 6151A 0912611911:35 RGG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 11 of 33 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW12 Lab Sample ID:CC13964-03 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 11:10 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 u ug/L 1 0.12 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 u ug/L 1 0.28 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,1-Dichloroethane [75-34-3]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,1-Dichloroethene [75-35-4]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 u ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2-Dibromoethane [106-93-4]A 0.66 u ug/L 1 0.66 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 u ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2-Dichloroethane [107-06-2]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,2-Dichloropropane [78-87-5]A 0.10 u ug/L 1 0.10 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 u ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF 2-Butanone [78-93-3]A 1.3 u ug/L 1 1.3 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF 2-Hexanone [591-78-6]A 0.88 u ug/L 1 0.88 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 u ug/L 1 1.1 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF Acetone [67-64-1]A 10 u ug/L 1 10 20 9I30034 EPA 8260D 10/01/19 05:06 REF Acrylonitrile [107-13-1]A 3.5 u ug/L 1 3.5 10 9I30034 EPA 8260D 10/01/19 05:06 REF Benzene[71-43-2]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Bromochloromethane [74-97-5]A 0.48 u ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Bromodichloromethane [75-27-4]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Bromoform [75-25-2]A 0.22 u ug/L 1 0.22 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Bromomethane [74-83-9]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Carbon disulfide [75-15-0]A 1.5 u ug/L 1 1.5 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF Carbon tetrachloride [56-23-5]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Chlorobenzene[108-90-7]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Chloroethane [75-00-3]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Chloroform [67-66-3]A 0.18 u ug/L 1 0.18 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Chloromethane [74-87-3]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF cis-1,2-Dichloroethene [156-59-2]A 1.7 ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 u ug/L 1 0.20 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Dibromochloromethane [124-48-1]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Dibromomethane [74-95-3]A 0.27 u ug/L 1 0.27 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Ethylbenzene [100-41-4]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Iodomethane [74-88-4]A 1.7 u ug/L 1 1.7 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF Methylene chloride [75-09-2]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Styrene [100-42-5]A 0.11 u ug/L 1 0.11 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Tetrachloroethene [127-18-4]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Tetrahydrofuran [109-99-9]A 32 ug/L 1 0.53 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Toluene [108-88-3]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 u ug/L 1 0.70 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Trichloroethene [79-01-6]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Trichlorofluoromethane [75-69-4]A 0.24 u ug/L 1 0.24 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF Vinyl acetate [108-05-4]A 0.95 u ug/L 1 0.95 5.0 9I30034 EPA 8260D 10/01/19 05:06 REF QV-01 Vinyl chloride [75-01-4]A 1.3 ug/L 1 0.32 1.0 9I30034 EPA 8260D 10/01/19 05:06 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 12 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW12 Lab Sample ID:CC13964-03 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 11:10 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I30034 EPA 8260D 10/01/19 05:06 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 45 1 50.0 90 % 53-136 9130034 EPA 8260D 10101119 05:06 REF Dlbromofluoromethane 46 1 50.0 93 % 67-129 9130034 EPA 8260D 10101119 05:06 REF Toluene-d8 37 1 50.0 75 % 59-134 9130034 EPA 8260D 10101119 05:06 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25030 EPA 7470A 09/26/19 15:28 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020B 09/25/19 13:45 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Barium [7440-39-3]^ 30.1 ug/L 1 1.10 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24037 EPA 6010D 09/26/19 11:58 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24037 EPA 6010D 09/26/19 11:58 JDH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Iron [7439-89-6]^ 154 ug/L 1 22.0 50.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Manganese [7439-96-5]^ 407 ug/L 1 1.50 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020B 09/25/19 13:45 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Zinc[7440-66-6]^ 5.08 J ug/L 1 4.40 10.0 9I24037 EPA 6010D 09/26/19 11:58 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Chloride [16887-00-6]^ 47000 ug/L 1 2200 5000 9I24034 EPA 300.0 09/24/19 20:16 PDK Sulfate as SO4 [14808-79-8]^ 54000 ug/L 1 2900 5000 9I24034 EPA 300.0 09/24/19 20:16 PDK Total Alkalinity as CaCO3 [471-34-1]^ 280000 D ug/L 2 28000 30000 9I24018 EPA 310.2 09/24/19 15:35 NMN Total Dissolved Solids^ 510000 ug/L 1 50000 50000 9I23003 SM 2540C-2011 09/23/19 17:25 JOC FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 13 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW12 Lab Sample ID:CC13964-03 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 11:10 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando Certified analyte [NC 424] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]A 10 ug/L 1 1.2 2.0 9302042 EPA 8260D 10/03/19 07:18 KKW Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-& 5.7 1 5.00 114 % 75-125 9702042 EPA 8260D 10103119 07:18 KKW Chlorinated Herbicides by GC A - ENCO Orlando Certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes 2,4-D [94-75-7]A 0.27 u ug/L 1 0.27 0.50 9I24050 EPA 8151A 09/26/19 14:31 RGG Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes 2,4-DCAA 1.4 1 1.96 71 % 37-134 9124050 EPA 6151A 09126119 1431 RGG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 14 of 33 0Nk"q09 www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW13 Lab Sample ID:CC13964-04 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:53 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flao Units DF MDL Q Batch Method Analyzed By Notes 1,1,1,2-Tetrachloroethane [630-20-6]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,1,1-Trichloroethane [71-55-6]A 0.12 u ug/L 1 0.12 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,1,2,2-Tetrachloroethane [79-34-5]A 0.28 u ug/L 1 0.28 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,1,2-Trichloroethane [79-00-5]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,1-Dichloroethane [75-34-3]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,1-Dichloroethene [75-35-4]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2,3-Trichloropropane [96-18-4]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2-Dibromo-3-chloropropane [96-12-8]A 0.48 u ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2-Dibromoethane [106-93-4]A 0.66 u ug/L 1 0.66 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2-Dichlorobenzene [95-50-1]A 0.19 u ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2-Dichloroethane [107-06-2]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,2-Dichloropropane [78-87-5]A 0.10 u ug/L 1 0.10 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 1,4-Dichlorobenzene [106-46-7]A 0.19 u ug/L 1 0.19 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF 2-Butanone [78-93-3]A 1.3 u ug/L 1 1.3 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF 2-Hexanone [591-78-6]A 0.88 u ug/L 1 0.88 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF 4-Methyl-2-pentanone [108-10-1]A 1.1 u ug/L 1 1.1 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF Acetone [67-64-1]A 10 u ug/L 1 10 20 9I30034 EPA 8260D 10/01/19 05:37 REF Acrylonitrile [107-13-1]A 3.5 u ug/L 1 3.5 10 9I30034 EPA 8260D 10/01/19 05:37 REF Benzene[71-43-2]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Bromochloromethane [74-97-5]A 0.48 u ug/L 1 0.48 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Bromodichloromethane [75-27-4]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Bromoform [75-25-2]A 0.22 u ug/L 1 0.22 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Bromomethane [74-83-9]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Carbon disulfide [75-15-0]A 1.5 u ug/L 1 1.5 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF Carbon tetrachloride [56-23-5]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Chlorobenzene[108-90-7]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Chloroethane [75-00-3]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Chloroform [67-66-3]A 0.18 u ug/L 1 0.18 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Chloromethane [74-87-3]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF cis-1,2-Dichloroethene [156-59-2]A 3.0 ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF cis-1,3-Dichloropropene [10061-01-5]A 0.20 u ug/L 1 0.20 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Dibromochloromethane [124-48-1]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Dibromomethane [74-95-3]A 0.27 u ug/L 1 0.27 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Ethylbenzene [100-41-4]A 0.13 u ug/L 1 0.13 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Iodomethane [74-88-4]A 1.7 u ug/L 1 1.7 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF Methylene chloride [75-09-2]A 0.23 u ug/L 1 0.23 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Styrene [100-42-5]A 0.11 u ug/L 1 0.11 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Tetrachloroethene [127-18-4]A 0.17 u ug/L 1 0.17 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Tetrahydrofuran [109-99-9]A 2.1 ug/L 1 0.53 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Toluene [108-88-3]A 0.14 u ug/L 1 0.14 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF trans-1,2-Dichloroethene [156-60-5]A 0.21 u ug/L 1 0.21 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF trans-1,3-Dichloropropene [10061-02-6]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF trans-1,4-Dichloro-2-butene [110-57-6]A 0.70 u ug/L 1 0.70 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Trichloroethene [79-01-6]A 0.15 u ug/L 1 0.15 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Trichlorofluoromethane [75-69-4]A 0.24 u ug/L 1 0.24 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF Vinyl acetate [108-05-4]A 0.95 u ug/L 1 0.95 5.0 9I30034 EPA 8260D 10/01/19 05:37 REF QV-01 Vinyl chloride [75-01-4]A 1.9 ug/L 1 0.32 1.0 9I30034 EPA 8260D 10/01/19 05:37 REF FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 15 Of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW13 Lab Sample ID:CC13964-04 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:53 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes Xylenes(Total)[1330-20-7]^ 0.45 U ug/L 1 0.45 3.0 9I30034 EPA 8260D 10/01/19 05:37 REF Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes 4-Bromofluorobenzene 46 1 50.0 91 % 53-136 9130034 EPA 8260D 10101119 05:37 REF Dlbromofluoromethane 47 1 50.0 94 % 67-129 9130034 EPA 8260D 10101119 05:37 REF Toluene-d8 37 1 50.0 74 % 59-134 9130034 EPA 8260D 10101119 0537 REF Metals by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Mercury [7439-97-6]^ 0.150 U ug/L 1 0.150 0.200 9I25030 EPA 7470A 09/26/19 15:30 KAH Metals (total recoverable) by EPA 6000/7000 Series Methods ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed By Notes Antimony [7440-36-0]^ 0.740 U ug/L 2 0.740 2.00 9I24028 EPA 6020B 09/25/19 13:58 RLF Arsenic[7440-38-2]^ 7.60 U ug/L 1 7.60 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Barium [7440-39-3]^ 14.2 ug/L 1 1.10 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Beryllium [7440-41-7]^ 0.160 U ug/L 1 0.160 1.00 9I24040 EPA 6010D 09/26/19 14:02 JDH Cadmium [7440-43-9]^ 0.360 U ug/L 1 0.360 1.00 9I24040 EPA 6010D 09/26/19 14:02 JDH Chromium [7440-47-3]^ 1.40 U ug/L 1 1.40 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Cobalt[7440-48-4]^ 1.40 U ug/L 1 1.40 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Copper[7440-50-8]^ 1.60 U ug/L 1 1.60 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Iron [7439-89-6]^ 1160 ug/L 1 22.0 50.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Lead [7439-92-1]^ 3.10 U ug/L 1 3.10 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Manganese [7439-96-5]^ 247 ug/L 1 1.50 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Nickel[7440-02-0]^ 2.20 U ug/L 1 2.20 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Selenium [7782-49-2]^ 6.20 U ug/L 1 6.20 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Silver[7440-22-4]^ 1.90 U ug/L 1 1.90 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Thallium [7440-28-0]^ 0.220 U ug/L 2 0.220 2.00 9I24028 EPA 6020B 09/25/19 13:58 RLF Vanadium [7440-62-2]^ 1.40 U ug/L 1 1.40 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Zinc[7440-66-6]^ 4.40 U ug/L 1 4.40 10.0 9I24040 EPA 6010D 09/26/19 14:02 JDH Classical Chemistry Parameters ^ - ENCO Cary certified analyte [NC 591] Analvte rCAS Numberl Results Flag Units DF MDL POLL Batch Method Analyzed Ay Notes Chloride [16887-00-6]^ 7700 ug/L 1 2200 5000 9I24034 EPA 300.0 09/24/19 21:09 PDK Sulfate as SO4 [14808-79-8]^ 18000 ug/L 1 2900 5000 9I24034 EPA 300.0 09/24/19 21:09 PDK Total Alkalinity as CaCO3 [471-34-1]^ 140000 ug/L 1 14000 15000 9I24018 EPA 310.2 09/24/19 14:44 NMN Total Dissolved Solids^ 240000 ug/L 1 50000 50000 9I23003 SM 2540C-2011 09/23/19 17:25 JOC FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 16 of 33 (� �Eo www.encolabs.com ANALYTICAL RESULTS Description: 4501-MW13 Lab Sample ID:CC13964-04 Received: 09/20/19 13:55 Matrix: Ground Water Sampled:09/19/19 09:53 Work Order: CC13964 Project: Henderson Co. LF C&D Sampled By:Travis Martinez/ Erik Vaskc Volatile Organic Compounds by GCMS SIM Isotope Dilution ^ - ENCO Orlando Certified analyte [NC 424] Analyte MAS Numberl Results Flag Units DF MDL P L Batch Method Analyzed By Notes 1,4-Dioxane [123-91-1]A 2.3 ug/L 1 1.2 2.0 9303054 EPA 8260D 10/03/19 10:53 KKW Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed ffy Notes Toluene-& 4.9 1 5.00 98 % 75-125 9703054 EPA 6260D 1010311910:53 KKW Chlorinated Herbicides by GC A - ENCO Orlando Certified analyte [NC 424] Analyte rCAS Numberl Results Flag Units DF MDL PQL Batch Method Analyzed Ay Notes 2,4-D [94-75-7]A 0.27 u ug/L 1 0.27 0.50 9I24050 EPA 8151A 09/26/19 14:56 RGG Surrogates Results DF Soike Lv/ % Rec % Rec Limits Batch Method Ana/vzed " Notes 2,4-DCAA 1.6 1 2.00 78 % 37-134 9124050 EPA 6151A 09126119 14:56 RGG FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 17 of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9130034 - EPA 50308 MS Blank (9I30034-BLK3) Prepared: 09/30/2019 14:34 Analyzed: 10/01/2019 03:32 Analvte Result Flaa POL Units 1, 1, 1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Tetrahydrofuran 0.53 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes 4-Bromofluorobenzene FINAL 44 u9/L 50.0 69 53-136 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 18 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9I30034 - EPA 50308 MS - Continued Blank (9I30034-BLKi) Continued Prepared: 09/30/2019 14:34 Analyzed: 10/01/2019 03:32 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes D/bromofluoromethane 46 u91L 50.0 91 67-129 Toluene-& 37 u91L 50.0 75 59-134 LCS (9I30034-BS1) Prepared: 09/30/2019 14:34 Analyzed: 10/01/2019 00:25 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 91 75-133 Benzene 21 1.0 ug/L 20.0 103 80-134 Chlorobenzene 19 1.0 ug/L 20.0 95 80-120 Toluene 20 1.0 ug/L 20.0 98 71-120 Trichloroethene 19 1.0 ug/L 20.0 95 74-120 Matrix Spike (9I30034-MS1) Prepared: 09/30/2019 14:34 Analyzed: 10/01/2019 00:56 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 0.21 U 92 75-133 Benzene 20 1.0 ug/L 20.0 0.15 U 101 80-134 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 92 80-120 Toluene 19 1.0 ug/L 20.0 0.24 94 71-120 Trichloroethene 17 1.0 ug/L 20.0 0.15 U 87 74-120 Matrix Spike Dup (9I30034-MSD1) Prepared: 09/30/2019 14:34 Analyzed: 10/01/2019 01:27 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 18 1.0 ug/L 20.0 0.21 U 89 75-133 4 20 Benzene 20 1.0 ug/L 20.0 0.15 U 100 80-134 1 17 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 91 80-120 2 16 Toluene 18 1.0 ug/L 20.0 0.24 88 71-120 7 17 Trichloroethene 17 1.0 ug/L 20.0 0.15 U 84 74-120 3 22 Batch 9JO1011 - EPA 5030B MS Blank (9301011-BLK1) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 15:45 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1,1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 19 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9J01011 - EPA 5030E MS - Continued Blank (9101011-BLK3) Continued Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 15:45 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Tetrahydrofuran 0.53 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L 4-Bromofluorobenzene 44 u9/L 50.0 87 53-136 Dibromofluoromethane 44 u9/L 50.0 89 67-129 Toluene-d8 37 u91L 50.0 74 59-134 LCS (9303011-BS1) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 13:40 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 95 75-133 Benzene 21 1.0 ug/L 20.0 106 80-134 Chlorobenzene 20 1.0 ug/L 20.0 98 80-120 Toluene 20 1.0 ug/L 20.0 98 71-120 Trichloroethene 18 1.0 ug/L 20.0 92 74-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 2O Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS - Quality Control Batch 9JO1011 - EPA 5030E MS - Continued Matrix Spike (9703011-MS3) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 14:12 Source: CC16562-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 19 1.0 ug/L 20.0 0.21 U 96 75-133 Benzene 21 1.0 ug/L 20.0 0.15 U 106 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 97 80-120 Toluene 19 1.0 ug/L 20.0 0.14 U 97 71-120 Trichloroethene 19 1.0 ug/L 20.0 0.15 U 94 74-120 Matrix Spike Dup (9303011-MSD3) Prepared: 10/01/2019 11:34 Analyzed: 10/01/2019 14:43 Source: CC16562-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 17 1.0 ug/L 20.0 0.21 U 85 75-133 12 20 Benzene 20 1.0 ug/L 20.0 0.15 U 98 80-134 8 17 Chlorobenzene 18 1.0 ug/L 20.0 0.17 U 92 80-120 5 16 Toluene 18 1.0 ug/L 20.0 0.14 U 91 71-120 6 17 Trichloroethene 17 1.0 ug/L 20.0 0.15 U 86 74-120 9 22 Metals by EPA 6000/7000 Series Methods - Quality Control Batch 9125030 - EPA 7470A Blank (9I25030-BLK3) Prepared: 09/25/2019 11:01 Analyzed: 09/26/2019 15:03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 0.150 U 0.200 ug/L LCS (9I25030-BSI) Prepared: 09/25/2019 11:01 Analyzed: 09/26/2019 15:05 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 5.34 0.200 ug/L 5.00 107 80-120 Matrix Spike (9I25030-MS1) Prepared: 09/25/2019 11:01 Analyzed: 09/26/2019 15:11 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 4.85 0.200 ug/L 5.00 0.150 U 97 75-125 Matrix Spike Dup (9I25030-MSD3) Prepared: 09/25/2019 11:01 Analyzed: 09/26/2019 15:13 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Mercury 5.17 0.200 ug/L 5.00 0.150 U 103 75-125 6 25 Post Spike (9I25030-PSI) Prepared: 09/25/2019 11:01 Analyzed: 09/26/2019 15:20 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Mercury 5.08 0.200 ug/L 5.00 0.0160 101 75-125 Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I2402B - EPA 3005A FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 21 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24028 - EPA 3005A - Continued Blank (9I24028-BLK1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:40 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L LCS (9I24028-BS1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:49 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 21.2 1.00 ug/L 20.0 106 80-120 Thallium 20.4 1.00 ug/L 20.0 102 80-120 Matrix Spike (9I24028-MS3) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 12:53 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 42.7 2.00 ug/L 40.0 0.740 U 107 75-125 Thallium 38.6 2.00 ug/L 40.0 0.220 U 97 75-125 Matrix Spike Dup (9I24028-MSD1) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 13:06 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 43.6 2.00 ug/L 40.0 0.740 U 109 75-125 2 20 Thallium 39.9 2.00 ug/L 40.0 0.220 U 100 75-125 3 20 Post Spike (9I24028-PSI) Prepared: 09/24/2019 11:38 Analyzed: 09/25/2019 13:10 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Antimony 22.0 1.00 ug/L 20.0-0.00236 110 75-125 Thallium 20.0 1.00 ug/L 20.0 0.00182 100 75-125 Batch 9I24037 - EPA 3005A Blank (9I24037-BLK3) Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:23 Analvte Result Flaq POL Units Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Iron 22.0 U 50.0 ug/L Lead 3.10 U 10.0 ug/L Manganese 1.50 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Selenium 6.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L Spike Source %REC Level Result %REC Limits RPD RPD Limit Notes FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 22 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9124037 - EPA 3005A - Continued LCS (9I24037-BS3) Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:31 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 193 10.0 ug/L 200 96 80-120 Barium 195 10.0 ug/L 200 98 80-120 Beryllium 19.8 1.00 ug/L 20.0 99 80-120 Cadmium 19.5 1.00 ug/L 20.0 97 80-120 Chromium 195 10.0 ug/L 200 98 80-120 Cobalt 192 10.0 ug/L 200 96 80-120 Copper 191 10.0 ug/L 200 96 80-120 Iron 976 50.0 ug/L 1000 98 80-120 Lead 192 10.0 ug/L 200 96 80-120 Manganese 197 10.0 ug/L 200 99 80-120 Nickel 197 10.0 ug/L 200 99 80-120 Selenium 210 10.0 ug/L 200 105 80-120 Silver 202 10.0 ug/L 200 101 80-120 Vanadium 195 10.0 ug/L 200 97 80-120 Zinc 209 10.0 ug/L 200 104 80-120 Matrix Spike (9I24037-MSI) Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:46 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 164 10.0 ug/L 200 7.60 U 82 75-125 Barium 309 10.0 ug/L 200 121 94 75-125 Beryllium 18.8 1.00 ug/L 20.0 0.501 91 75-125 Cadmium 17.6 1.00 ug/L 20.0 0.360 U 88 75-125 Chromium 181 10.0 ug/L 200 1.40 U 91 75-125 Cobalt 192 10.0 ug/L 200 13.0 90 75-125 Copper 182 10.0 ug/L 200 1.60 U 91 75-125 Iron 17500 50.0 ug/L 1000 17100 41 75-125 QM-07 Lead 176 10.0 ug/L 200 3.10 U 88 75-125 Manganese 6120 10.0 ug/L 200 5950 83 75-125 Nickel 187 10.0 ug/L 200 2.20 U 94 75-125 Selenium 186 10.0 ug/L 200 6.20 U 93 75-125 Silver 185 10.0 ug/L 200 1.90 U 92 75-125 Vanadium 183 10.0 ug/L 200 1.40 U 92 75-125 Zinc 196 10.0 ug/L 200 5.76 95 75-125 Matrix Spike Dup (9I24037-MSD1) Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:48 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes Arsenic 157 10.0 ug/L 200 7.60 U 78 75-125 5 20 Barium 311 10.0 ug/L 200 121 95 75-125 0.8 20 Beryllium 19.1 1.00 ug/L 20.0 0.501 93 75-125 2 20 Cadmium 17.9 1.00 ug/L 20.0 0.360 U 89 75-125 2 20 Chromium 183 10.0 ug/L 200 1.40 U 91 75-125 0.8 20 Cobalt 195 10.0 ug/L 200 13.0 91 75-125 1 20 Copper 182 10.0 ug/L 200 1.60 U 91 75-125 0.05 20 Iron 17300 50.0 ug/L 1000 17100 18 75-125 1 20 QM-07 Lead 184 10.0 ug/L 200 3.10 U 92 75-125 5 20 Manganese 6020 10.0 ug/L 200 5950 36 75-125 2 20 QM-07 Nickel 192 10.0 ug/L 200 2.20 U 96 75-125 3 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 23 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24037 - EPA 3005A - Continued Matrix Spike Dup (9I24037-MSD3) Continued Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:48 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Selenium 182 10.0 ug/L 200 6.20 U 91 75-125 2 20 Silver 184 10.0 ug/L 200 1.90 U 92 75-125 0.1 20 Vanadium 186 10.0 ug/L 200 1.40 U 93 75-125 1 20 Zinc 197 10.0 ug/L 200 5.76 96 75-125 0.9 20 Post Spike (9I24037-PSI) Prepared: 09/24/2019 15:31 Analyzed: 09/26/2019 11:51 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Arsenic 0.187 0.0100 mg/L 0.200 -0.0193 94 80-120 Barium 0.324 0.0100 mg/L 0.200 0.121 101 80-120 Beryllium 0.0206 0.00100 mg/L 0.0200 0.000501 100 80-120 Cadmium 0.0193 0.00100 mg/L 0.0200 -0.000576 97 80-120 Chromium 0.196 0.0100 mg/L 0.200 2.36E-5 98 80-120 Cobalt 0.207 0.0100 mg/L 0.200 0.0130 97 80-120 Copper 0.195 0.0100 mg/L 0.200 0.000580 97 80-120 Iron 17.4 0.0500 mg/L 1.00 17.1 25 80-120 QM-08 Lead 0.195 0.0100 mg/L 0.200 -0.00154 97 80-120 Manganese 6.04 0.0100 mg/L 0.200 5.95 45 80-120 QM-08 Nickel 0.204 0.0100 mg/L 0.200 0.00206 101 80-120 Selenium 0.207 0.0100 mg/L 0.200 -0.0222 104 80-120 Silver 0.203 0.0100 mg/L 0.200 -0.000311 102 80-120 Vanadium 0.199 0.0100 mg/L 0.200 -0.000573 99 80-120 Zinc 0.210 0.0100 mg/L 0.200 0.00576 102 80-120 Batch 9I24040 - EPA 3005A Blank (9I24040-BLK3) Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 13:59 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Iron 22.0 U 50.0 ug/L Lead 3.10 U 10.0 ug/L Manganese 1.50 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Selenium 6.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L LCS (9I24040-BSI) Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:16 Spike Source %REC RPD Analvte Result Flaq PQL Units Level Result %REC Limits RPD Limit Notes Arsenic 200 10.0 ug/L 200 100 80-120 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 24 of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24040 - EPA 3005A - Continued LCS (9I24040-BS3) Continued Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:16 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Barium 200 10.0 ug/L 200 100 80-120 Beryllium 20.2 1.00 ug/L 20.0 101 80-120 Cadmium 20.2 1.00 ug/L 20.0 101 80-120 Chromium 200 10.0 ug/L 200 100 80-120 Cobalt 200 10.0 ug/L 200 100 80-120 Copper 197 10.0 ug/L 200 98 80-120 Iron 1000 50.0 ug/L 1000 100 80-120 Lead 198 10.0 ug/L 200 99 80-120 Manganese 202 10.0 ug/L 200 101 80-120 Nickel 200 10.0 ug/L 200 100 80-120 Selenium 206 10.0 ug/L 200 103 80-120 Silver 208 10.0 ug/L 200 104 80-120 Vanadium 199 10.0 ug/L 200 99 80-120 Zinc 216 10.0 ug/L 200 108 80-120 Matrix Spike (9I24040-MSI) Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:21 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 178 10.0 ug/L 200 7.60 U 89 75-125 Barium 199 10.0 ug/L 200 14.2 92 75-125 Beryllium 19.3 1.00 ug/L 20.0 0.160 U 96 75-125 Cadmium 18.6 1.00 ug/L 20.0 0.360 U 93 75-125 Chromium 186 10.0 ug/L 200 1.40 U 93 75-125 Cobalt 186 10.0 ug/L 200 1.40 U 93 75-125 Copper 183 10.0 ug/L 200 1.60 U 92 75-125 Iron 2040 50.0 ug/L 1000 1160 88 75-125 Lead 185 10.0 ug/L 200 3.10 U 93 75-125 Manganese 424 10.0 ug/L 200 247 89 75-125 Nickel 186 10.0 ug/L 200 2.20 U 93 75-125 Selenium 181 10.0 ug/L 200 6.20 U 91 75-125 Silver 192 10.0 ug/L 200 1.90 U 96 75-125 Vanadium 189 10.0 ug/L 200 1.40 U 94 75-125 Zinc 199 10.0 ug/L 200 4.40 U 100 75-125 Matrix Spike Dup (9I24040-MSD1) Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:24 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 185 10.0 ug/L 200 7.60 U 92 75-125 4 20 Barium 203 10.0 ug/L 200 14.2 95 75-125 2 20 Beryllium 19.7 1.00 ug/L 20.0 0.160 U 98 75-125 2 20 Cadmium 18.8 1.00 ug/L 20.0 0.360 U 94 75-125 1 20 Chromium 191 10.0 ug/L 200 1.40 U 95 75-125 3 20 Cobalt 188 10.0 ug/L 200 1.40 U 94 75-125 1 20 Copper 188 10.0 ug/L 200 1.60 U 94 75-125 3 20 Iron 2130 50.0 ug/L 1000 1160 97 75-125 4 20 Lead 186 10.0 ug/L 200 3.10 U 93 75-125 0.4 20 Manganese 444 10.0 ug/L 200 247 99 75-125 5 20 Nickel 189 10.0 ug/L 200 2.20 U 94 75-125 2 20 Selenium 182 10.0 ug/L 200 6.20 U 91 75-125 0.8 20 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 25 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I24040 - EPA 3005A - Continued Matrix Spike Dup (9I24040-MSD3) Continued Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:24 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Silver 195 10.0 ug/L 200 1.90 U 97 75-125 2 20 Vanadium 193 10.0 ug/L 200 1.40 U 97 75-125 2 20 Zinc 202 10.0 ug/L 200 4.40 U 101 75-125 2 20 Post Spike (9I24040-PS1) Prepared: 09/24/2019 15:43 Analyzed: 09/26/2019 14:26 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Arsenic 0.191 0.0100 mg/L 0.200 -0.0109 96 80-120 Barium 0.214 0.0100 mg/L 0.200 0.0142 100 80-120 Beryllium 0.0208 0.00100 mg/L 0.0200 -8.30E-5 104 80-120 Cadmium 0.0199 0.00100 mg/L 0.0200 0.000107 99 80-120 Chromium 0.200 0.0100 mg/L 0.200 0.000135 100 80-120 Cobalt 0.199 0.0100 mg/L 0.200 0.00107 99 80-120 Copper 0.198 0.0100 mg/L 0.200 0.000680 99 80-120 Iron 2.16 0.0500 mg/L 1.00 1.16 100 80-120 Lead 0.196 0.0100 mg/L 0.200 -0.00275 98 80-120 Manganese 0.449 0.0100 mg/L 0.200 0.247 101 80-120 Nickel 0.199 0.0100 mg/L 0.200 0.000557 99 80-120 Selenium 0.201 0.0100 mg/L 0.200 -0.00640 100 80-120 Silver 0.209 0.0100 mg/L 0.200 -0.000598 105 80-120 Vanadium 0.203 0.0100 mg/L 0.200 -0.000138 102 80-120 Zinc 0.213 0.0100 mg/L 0.200 0.00362 105 80-120 Classical Chemistry Parameters - Quality Control Batch 9I23003 - NO PREP Blank (9I23003-BLK1) Prepared & Analyzed: 09/23/2019 17:25 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 50000 U 50000 ug/L LCS (9I23003-BS3) Prepared & Analyzed: 09/23/2019 17:25 Spike Source %REC RPD Analvte Result Flaq Q Units Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 1000 50 mg/L 1000 100 80-120 Duplicate (9I23003-DUPi) Prepared & Analyzed: 09/23/2019 17:25 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Dissolved Solids 600000 50000 ug/L 570000 5 20 Batch 9I24018 - NO PREP Blank (9I24018-BLK1) Prepared: 09/24/2019 14:40 Analyzed: 09/24/2019 14:40 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 14000 U 15000 ug/L FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 26 Of 33 QUALITY CONTROL DATA Classical Chemistry Parameters - Quality Control Batch 9I24018 - NO PREP - Continued (� �Eo www.encolabs.com LCS (9I24018-BS1) Prepared: 09/24/2019 14:40 Analyzed: 09/24/2019 14:40 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 100 15 mg/L 100 100 80-120 Matrix Spike (9I24018-MS3) Prepared: 09/24/2019 14:42 Analyzed: 09/24/2019 14:42 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 350000 30000 ug/L 80000 300000 52 80-120 QM-07 Matrix Spike Dup (9I24018-MSD1) Prepared: 09/24/2019 14:42 Analyzed: 09/24/2019 14:42 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Total Alkalinity as CaCO3 350000 30000 ug/L 80000 300000 56 80-120 0.8 25 QM-07 Batch 9I24034 - NO PREP Blank (9I24034-BLK3) Prepared: 09/24/2019 14:17 Analyzed: 09/24/2019 17:36 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 2200 U 5000 ug/L Sulfate as SO4 2900 U 5000 ug/L LCS (9I24034-BS1) Prepared: 09/24/2019 14:17 Analyzed: 09/24/2019 17:54 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 50000 5000 ug/L 50000 100 90-110 Sulfate as SO4 49000 5000 ug/L 50000 97 90-110 Matrix Spike (9I24034-MS3) Prepared: 09/24/2019 14:17 Analyzed: 09/24/2019 18:47 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 84000 20000 ug/L 80000 9300 94 90-110 Sulfate as SO4 220000 20000 ug/L 80000 140000 109 90-110 Matrix Spike (9I24034-MS2) Prepared: 09/24/2019 14:17 Analyzed: 09/24/2019 19:40 Source: CC13964-01 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 20000 5000 ug/L 20000 2200 U 98 90-110 Sulfate as SO4 17000 5000 ug/L 20000 2900 U 87 90-110 QM-07 Matrix Spike Dup (9I24034-MSD1) Prepared: 09/24/2019 14:17 Analyzed: 09/24/2019 19:05 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag POL Units Level Result %REC Limits RPD Limit Notes Chloride 83000 20000 ug/L 80000 9300 93 90-110 1 10 Sulfate as SO4 220000 20000 ug/L 80000 140000 108 90-110 0.6 10 Volatile Organic Compounds by GCMS SIM Isotope Dilution - Quality Control Batch 9JO2042 - EPA 5030E MS FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 27 Of 33 0Nk"q09 www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS SIM Isotope Dilution - Quality Control Batch 9JO2042 - EPA 5030B MS - Continued Blank (9302042-BLKi) Prepared: 10/02/2019 14:07 Analyzed: 10/03/2019 01:32 Spike Source %REC RPD Analvte Result Flao POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 1.2 U 2.0 ug/L Toluene-& 5.4 u9/L 5.00 108 75-125 LCS (9302042-BS1) Prepared: 10/02/2019 14:07 Analyzed: 10/02/2019 23:02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limi RPD Limit Notes 1,4-Dioxane 24 2.0 ug/L 25.0 96 80-133 Toluene-& 5.3 u9/L 5.00 105 75-125 Matrix Spike (9302042-MS1) Prepared: 10/02/2019 14:07 Analyzed: 10/02/2019 23:39 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 24 2.0 uq/L 25.0 1.2 U 96 80-133 Toluene-& 5.4 u9/L 5.00 109 75-125 Matrix Spike Dup (9302042-MSD1) Prepared: 10/02/2019 14:07 Analyzed: 10/03/2019 00:17 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 25 2.0 ug/L 25.0 1.2 U 100 80-133 4 19 Toluene-d8 6.1 u9/L 5.00 123 75-125 Batch 9JO3054 - EPA 5030B MS Blank (9303054-BLK1) Prepared: 10/03/2019 00:00 Analyzed: 10/03/2019 10:22 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 1.2 U 2.0 ug/L Toluene-& 5.9 u9/L 5.00 117 75-125 LCS (9303054-BSI) Prepared: 10/03/2019 00:00 Analyzed: 10/03/2019 09:18 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 28 2.0 ug/L 25.0 113 80-133 Toluene-d8 5.8 u9/L 5.00 117 75-125 Matrix Spike (9303054-MS1) Prepared: 10/03/2019 00:00 Analyzed: 10/03/2019 19:14 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 25 2.0 ug/L 25.0 2.3 89 80-133 Toluene-& 4.9 u91L 5.00 98 75-125 Matrix Spike Dup (9303054-MSD1) Prepared: 10/03/2019 00:00 Analyzed: 10/03/2019 19:51 Source: CC13964-04 Spike Source %REC RPD Awe Result Flaa POL Units Level Result %REC Limits RPD Limit Notes 1,4-Dioxane 28 2.0 ug/L 25.0 2.3 SOS 80-133 11 19 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 28 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Volatile Organic Compounds by GCMS SIM Isotope Dilution - Quality Control Batch 9.703054 - EPA 5030E MS - Continued Matrix Spike Dup (9103054-MSD3) Continued Prepared: 10/03/2019 00:00 Analyzed: 10/03/2019 19:51 Source: CC13964-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes Toluene-d8 5.1 ug/L 5.00 102 75-125 Chlorinated Herbicides by GC - Quality Control Batch 9124050 - EPA 3510C Blank (9I24050-BLK3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 07:47 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 0.27 U 0.50 ug/L 2,4-DC4A 0.99 ug/L 2.00 50 37-134 LCS (9I24050-BS1) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:03 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.3 0.50 ug/L 2.00 66 20-134 2, 4-DCAA 1.4 u9/L 2.00 70 37-134 Matrix Spike (9I24050-MS1) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:28 Source: AC06687-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.6 0.50 ug/L 2.00 0.27 U 80 20-134 2,4-DC4A 1.4 ug/L 2.00 72 37-134 Matrix Spike (9I24050-MS2) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 10:44 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.6 0.50 ug/L 2.00 0.27 U 78 20-134 2, 4-DCAA 1.1 u9/L 2.00 54 37-134 Matrix Spike (9I24050-MS3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 12:00 Source: AC06458-01 Spike Source %REC RPD Analvte Result Flaa POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 6.0 2.5 ug/L 10.0 1.4 U 60 20-134 2,4-DC4A 6.0 ug/L 10.0 60 37-134 Matrix Spike Dup (9I24050-MSD3) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 09:54 Source: AC06687-04 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.2 0.50 ug/L 2.00 0.27 U 60 20-134 27 19 QM-11 2, 4-DCAA 1.4 ug/L 2.00 66 37-134 Matrix Spike Dup (9I24050-MSD2) Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 11:09 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flaq POL Units Level Result %REC Limits RPD Limit Notes 2,4-D 1.3 0.50 ug/L 2.00 0.27 U 66 20-134 17 19 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Pag@ Z9 Of 33 (� �Eo www.encolabs.com QUALITY CONTROL DATA Chlorinated Herbicides by GC - Quality Control Batch 9124050 - EPA 3510C - Continued Matrix Spike Dup (9I24050-MSD2) Continued Prepared: 09/24/2019 22:22 Analyzed: 09/26/2019 11:09 Source: CC13964-02 Spike Source %REC RPD Analvte Result Flag Q Units Level Result %REC Limits RPD Limit Notes 2,4-DC4A 1.3 ug/L 2.00 65 37-134 FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 30 Of 33 (� �Eo www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). QM-11 Precision between duplicate matrix spikes of the same sample was outside acceptance limits. QV-01 The associated continuing calibration verification standard exhibited high bias; since the result is ND, there is no impact. FINAL This report relates only to the sample as received by the laboratory, and may only be reproduced in full. I Page 31 of 33 E 3 � 3 /e/� Li 0 U w 0 U LL 0 a U LLJ 0 Li 0 m a J Z 0 a Z 0 U J I Z LLJ Z M0 I.L Z LU U m m q rn m M ' m z _0 m C.0 LL�I w� O a no- �Vyy U ca c a w L C1J W ! p 'C a� L.AE 0F= � Y E � ay � � j ( 1 � O ❑� 0 tr o a c v a 4 a c U pa � N — % N p m O N = m D m d � z m m (� o � Z c D En ooc alejInS o x x x x v J Z fH x x x X� N z E v syy OMMS 5C1L'40£ 8PwW4o'i'4 L£ 4.u!Iv)IId c x X X X ` N U m �+ UZ'A'LL'aS eS 4S iC ice` X 7< '6V a o o L) e E (]! W!S Q()9i9'PRPua)x3 X X X X. 009Z9' L qPueddy 04959 o 0 o a ro o d��8 Z xapuafddy x x x x �o C U G m E E- E L1J v r g� V 0 Q 0 �� Q Q LL N ` m 1 Q c w d (7 y }y, m o fo q z U w E ED c U C co o ,g c .� v `o m MJ r� �� ` �T m� U o BEM ,�, E7 � Cc ir c Q E a a [t m U) '1 �'- Ll y a+ EELO (nn U C m LO C 0N € O N r7 C m O CNLO �/} m m V Q /1 V Q w co C z 4Y et St a y mU n CO E JL-l Page 32 of 33 ci) ._ Sample Preservation Verification ENCO Cary 0 Work Order: CC13964 Project: Henderson Co. LF C&D Client: Golder Associates, Inc. (GO007) Project#: 0839650618.103 Logged In: 20-Sep-19 14:31 � � Lagged By: John C King� �D Preservation Check Performed By: Datefrime: f "t CC13964-01 Cont Type �., F"M Pres (pH) Requirement pl I Checked In Control pH Adjusted Date/Time Adjusted Used/Comments B 250mLP+HNO3 <2 Y/ N/ NA Y l N] NA CC13964-02 Cont Type Pres (pH) Requirement PH Checked/ In Control pH Adjusted Dateffime Adjusted Reagent Used/Comments D 250mLP+HNO3 <2 Y 1 N 1 NA Y F '. NA E 250mLP+HNO3 <2 Y N I NA YIN NA CC13964-03 Cont 'Type Pres (pH) Requirement PH Checked 1 In Control pH Adjusted Date/Time Adjusted Reagent Used/Comments B 250mLP+HNO3 <2 Y/ N 1 NA Y/ r N/ NA CC13964-04 Cont Type Pres (pH) JpH Checked ! PH Adjusted Date/Time Reagent Used]Comments Requirement In Control Adjusted B 250mLP+HNO3 <2 Y / N l NA I YIN :! NA Rea ent Name ID 1 2 Rea ent Name ID 3 4 Rea ent Name ID 5 6 pH Strip ID: PH Strips CSl07a1 C:IELM NTIPnnmko_PreservationCheck, rpt Page 33 of 33 Page 1 of 1 WORK ORDER Printed: 10/7/2019 5:34:56PM CC13964 ENCO Cary Sample Receipt Conditions Client: Golder Associates, Inc. (G0007) Lab Project Mgr: Meghan K Shea Project: Henderson Co. LF C&D Project Number: 0839650618.103 PO #: Report To: Invoice To: Golder Associates, Inc. (G0007) Golder Associates, Inc. (G0007) Dusty Reedy Accounts Payable 5B Oak Branch Drive 5B Oak Branch Drive Greensboro, NC 27407 Greensboro, NC 27407 Phone: (336) 852-4903 Phone :(804) 358-7900 Fax: (336) 852-4904 Fax:804-358-2900 Received By: Timothy J. Parker Date Received: 20-Sep-19 13:55 Logged In By: John C King Date Logged In: 20-Sep-19 14:31 Work Order Comments: C-120 received at 2.1°C Containers Intact Y Containers Properly Preserved Y Proper Containers Received Y All Samples in PreLog Received Y COC/Labels Agree Y Custody Seals Intact Y Volatile Containers Preserved Y Volatile Containers Headspace Free Y Aqueous Samples Checked for Residual Cl N Received On Ice Y Temperature Corrected Y Page 1 of 1 GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW Page 1 of 4 Project Name: Henderson County C&D Landfill Project Reference Number: 19128179 Sampling Event Date: September 18-19, 2019 Review Date: October 10, 2019 Report #: CC13964 Signature: qZ4 � Vj� f�f gofC� o QA/QC Sign Off: 100�,�r ,,> COLDER Date: ���7-2o2G Date: _ / a - 2ri Initials: DC Person(s) performing the review are to initial each item on this form as acknowledgement of data acceptance, or as acknowledgement of a review issue. In the case of the latter, a brief explanation should follow the applicable item. Golder Associates Inc. has reviewed the laboratory certificates of analysis, chain -of -custody form, and laboratory provided sample group quality assurance and quality control data for the above referenced sample group to identify potential bias or inaccuracy, in general accordance with the following United States Environmental Protection Agency documents: • Region III Modifications to Functional Guidelines for Organic Data Review Multi -Media, Multi - Concentration, September 1994; • Region III Modifications to the Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, April 1993; and • Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, July 1998. COMPLIANCE ANALYTE LIST(S) (check all that apply) _ NC Closed Facility List (.500 Rules) X NC C & D List (New Rules) _ NC Appendix I X NC Appendix I + 2,4-D _ NC Appendix II NC Subtitle D Leachate List Other: 1.0 CHAIN OF CUSTODY (COC) REVIEW DC COC was properly signed by all parties. DC Correct project name and number are on the form. • Listed as 0839-6506018.103, should be listed as 19128179.101 DC Sample receipt condition at laboratory was acceptable. DC Each sample and blank submitted for analysis appears in the report. GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW G Q L D E R Page 2 of 4 2.0 SAMPLE HOLDING TIMES DC Holding times for extraction and/or analysis were met for each analytical Method (see below for reference). Review Criteria Method Analytes Holding Time SW-846 Method 8260 and 8011 VOCs 14 days SW-846 Methods 8270, 8080, 8081, 8082, and 8151 SVOCs, PCBs, pesticides and herbicides 7 days for extraction, 40 days from extraction for analysis SW-846 Methods 6000 and 7000 Series Metals except mercury 6 months (no temperature requirements) SW-846 Method 7470 Mercury 28 days SW-846 Method 376.1 Sulfide 7 days SW-846 Method 9010 Cyanide 14 days EPA Method 300 Nitrate/Sulfate 48 hours/28 days EPA Method 405.1 BOD 48 hours EPA Method 410.4 COD 28 days EPA Method 365.4 Phosphorous 28 days 3.0 LABORATORY QUALITY CONTROL REVIEW DC Laboratory analyzed at least one internal blank for each method, where applicable. DC Laboratory blank is interference -free. Chloromethane bias low in associated QC but can be detected in the CRL. Since the analyte in all the samples in the work order was not detected, there is no impact on data quality. The Vinyl acetate associated continuing calibration verification standard exhibited high bias; since all samples in the work order are non -detect, there is no impact. DC Surrogate recoveries are provided for each analytical method, where applicable. DC Surrogate recoveries for each method are within the acceptable limits (i.e., at least 50% of the surrogates were within range). DC MS/MSD/LCS data results are provided for each analytical method. DC MS/MSD/LCS recoveries for each method are within the acceptable limits (i.e., at least 1 of the 3 were within range). The Alkalinity spike recovery was outside acceptance limits for the MS and /or MSD. The QC batch was accepted based on acceptable LCS recovery. The Iron and Manganese spike recoveries were outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recoveries. The Sulfate spike recovery was outside acceptance limits for the MS and/or MSD. The QC batch was accepted based on acceptable LCS recovery. Iron and Manganese post -digestion spike did not meet method requirements due to confirmed matrix effects. y Precision between 2,4-D duplicate matrix spikes of the same sample was outside acceptance limits. The QC batch was accepted based on acceptable LCS recovery. 4.0 ANALYTE LISTS/METHODS DC The proper number of constituents are present for each analyte list as identified above (including detects where applicable). GOLDER ASSOCIATES INC. QUALITY ASSURANCE & QUALITY CONTROL LABORATORY DATA REVIEW C O L D E R Page 3 of 4 DC Proper EPA SW-846 analytical methods were used for analysis. 5.0 DATA REPORTING DC All analytical reporting associated with the event was performed by the contracted lab. DC Trip, field and/or equipment, and laboratory blank results have all been reported. All detects for blanks are listed below by constituent. All laboratory method blanks, if any, have been `flagged' with a `B' where detected in other samples as appropriate and a laboratory narrative was provided. If the sample was flagged by the laboratory and is not within 5X of the concentration in the blank (or 10X for commonly detected laboratory contaminants -acetone, methylene chloride and phthalates), list below with explanation if flags should be removed. If flags need to be added for samples, also list below. DC It is clear from the laboratory report that samples have or have not been diluted during analysis, and if the samples have been diluted, the result is reported as a multiple of the dilution (e.g., a sample diluted 1 Ox resulting in an analytical detection of 1.0 should be reported as 10). Those that have been diluted are listed below with the dilution factor. ➢ Antimony and Thallium (2x) • MW-11 • MW-10 • MW-12 • MW-13 ➢ Sulfate as SO4 (4x) • MW-11 • MW-12 ➢ Total Alkalinity (2x) • MW-11 DC No organic constituents were reported above their respective SWSLs, and no inorganic or organic constituents were reported above their respective NC 2L Drinking Water Standards/GWPS in wells, or field/equipment/trip blanks, or above applicable surface water standards in surface water points. NC 2L/SWS GWPS Exceedances • 1,4-Dioxane (NC 2L = 3 ug/L) • MW-12 @ 10 ug/L • Vinyl Chloride (NC 2L = 0.03 ug/L) • MW-12 @ 1.3 • MW-13 @ 1.9 • Cobalt (NC 2L IMAC/SWS GWPS = 1 ug/L) • MW-11 @ 13 ug/L • Iron (NC 2L = 300 ug/L) • MW-11 @ 17100 ug/L • MW-13 @ 1160 ug/L . Manganese (NC 2L = 50 ug/L) • MW-11 @ 5950 ug/L • MW-12 @ 407 ug/L • MW-13 @ 247 ug/L . Total Dissolved Solids (NC 2L = 500 mg/L) 9 MW-11 @ 570 mg/L ASSOCIATES INC. GULLET C O L D E R QUALITY ASSURANCE &QUALITY CONTROL LABORATORY DATA REVIEW Page 4 of 4 . MW-12 @ 510 mg/L DC No inorganic and organic constituents were detected in a well or surface water point at quantified concentrations outside of their historical range (more than 5X previous concentrations or first-time detections). N/A Other report issues/Communications with laboratory/etc.: APPENDIX C USGS National Geochemical Survey Database Summary January 2020 APPENDIX C USGS National Geochemical Survey Database Summary Henderson County MSW C&D Landfill, Permit No. 45-01 Project No. 19128179 NURE Record ID Lab ID Collection Date Datum Latitude Longitude Medium Source Units Iron Thallium Cobalt Manganese 5287765 C-110024 06/03/76 NAD27 35.3919 -82.4395 Sediment Stream ppm 0.70 0.260 ND 168 5288276 C-110099 06/04/76 NAD27 35.2858 -82.2908 Sediment Stream ppm 1.70 0.290 4 363 5288402 C-110164 08/03/76 NAD27 35.2925 -82.6996 Sediment Stream ppm 2.50 0.550 4 457 5287509 C-110206 06/07/76 NAD27 35.6083 -82.4171 Sediment Stream ppm 4.20 0.580 11 813 5288425 C-110285 08/03/76 NAD27 35.2003 -82.8557 Sediment Stream ppm 1.50 0.360 4 390 5287782 C-110313 06/04/76 NAD27 35.3999 -82.6317 Sediment Stream ppm 4.90 0.710 6 1180 5287813 C-110459 06/07/76 NAD27 35.3505 -82.8203 Sediment Stream ppm 5.10 1.20 8 1620 5288593 C-142453 07/08/76 NAD27 35.0267 -82.6374 Sediment Stream ppm 1.51 0.330 5 506 5287493 C-143098 06/06/76 NAD27 35.4751 -82.6388 Sediment Stream ppm 2.37 0.645 9 472 5287791 C-143172 06/05/76 NAD27 35.4303 -82.6555 Sediment Stream ppm 3.50 1.014 8 1020 5287574 C-143236 06/09/76 NAD27 35.6346 -82.4159 Sediment Stream ppm 5.15 1.027 16 1490 5287825 C-143564 06/07/76 NAD27 35.4695 -82.8924 Sediment Stream ppm 3.79 0.721 11 1050 5288393 C-143759 08/03/76 NAD27 35.3832 -82.7216 Sediment Stream ppm 2.05 0.387 8 511 5287780 C-143901 06/04/76 NAD27 35.3899 -82.5668 Sediment Stream ppm 4.07 0.880 6 1140 5287534 C-143909 06/07/76 NAD27 35.5901 -82.6262 Sediment Stream ppm 3.42 0.934 12 986 5288412 C-144004 08/03/76 NAD27 35.2523 -82.8528 Sediment Stream ppm 2.66 0.547 7 361 5288288 C-210857 06/05/76 NAD27 35.5212 -82.1979 Sediment Stream ppm 2.71 0.451 9 424 5287506 C-210895 06/07/76 NAD27 35.641 -82.3088 Sediment Stream ppm 3.06 0.593 10 395 5287739 C-210903 06/03/76 NAD27 35.2585 -82.5017 Sediment Stream ppm 1.28 0.400 3 401 5287472 C-210906 06/05/76 NAD27 35.4504 -82.474 Sediment Stream ppm 1.64 0.376 4 395 Average 2.89 0.613 7 707 Notes: 1. NURE = National Uranium Resource Evaluation 2. ID = identification 3. ND = non -detect 4. Inorganic analysis performed by ICP40. 5. ppm = parts per million 6. Sample locations are within 25 miles of the Henderson County MSW Landfill 7. Source of data is the United States Geological Survey National Geochemical Survey Database. - V0L❑EP? 1of1 APPENDIX D Statistical Evaluation Worksheets & Summary Table January 2020 Summary of Statistical Analysis Henderson County Landfill, Permit No. 45-01 Hendersonville, North Carolina Project No. 1912879 September 2019 Detected Groundwater Standard Statistical Downgradient Constituent Analysis Monitoring Reporting Units Statistical Determination Monitoring Well Concentration Constituent NC 2L IMAC Interwell Closed C&D Landfill Downgradient Monitoring Wells and Concentrations Cobalt ug/L -- 1 MW-11 13.0 10.0 SSI ug/L 300 -- ..........................11.60.............. MMWW--1131 17100 4690 SSIIron ........................................................................................................ Not SSI Notes: 1. Statistical worksheets are provided as Appendix C. 2. ug/L = micrograms per liter 3. NC 2L = North Carolina 2L Groundwater Standard 4. IMAC = Interim Maximum Allowable Concentration (under NC 2L Rules) 5. SSI = statistically significant increase 6. ND = not detected above laboratory detection limit 7. -- = not available 8. North Carolina Appendix I Inorganic constituents detected above their respective Solid Waste Section Reporting Limit and Groundwater Standard in samples from downgradient monitoring wells were statistically evaluated. GOLDER 10f1 WQStat Plus" v.9.4.32 J 0) EPA 1989 Outlier Test MW-10 (bg) 10 8 6 4 2 0 3/24/10 n=12 No statistical outliers found. The distribution was not normalizable. Mean = 2.117 Std. dev. = 2.483 Critical Tn = 2.285 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.327 Critical = 0.859 2/15/12 1 /8/14 12/2/15 10/25/17 9/18/19 Constituent: Cobalt Analysis Run 1/14/2020 10:09 AM Facility: Henerson County C&D Landfill Data File: Henderson C&D Stats WQStat Plus" v.9.4.32 Hollow symbols indicate censored values. Exceeds Limit: MW-11 161111111 16 12 M 0 4- 3/24/09 Prediction Limit Interwell Non -parametric 4/29/11 6/3/13 7/9/15 8/13/17 9/18/19 ■ MW-11 MW-12 ♦ MW-13 Limit = 10 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 12 background values. 100% NDs. Report alpha = 0.2. Individual comparison alpha = 0.07168. Most recent point for each compliance well compared to limit. Insufficient data to test for seasonality; data will not be deseasonalized. Constituent: Cobalt Analysis Run 1/14/2020 10:10 AM Facility: Henerson County C&D Landfill Data File: Henderson C&D Stats WQStat Plus" v.9.4.32 5000 4000 3000 J 2000 1000 0 4- 3/24/10 EPA 1989 Outlier Test MW-10 (bg) n=11 No statistical outliers found. Mean = 615 Std. dev. = 1360 Critical Tn = 2.234 Normality test used: Shapiro Wilk@alpha = 0.05 Calculated = 0.8534 Critical = 0.85 (after natural log transforma- tion) The distribution was found to be log -normal. 2/15/12 1 /8/14 12/2/15 10/25/17 9/18/19 Constituent: Iron Analysis Run 1/14/2020 10:12 AM Facility: Henerson County C&D Landfill Data File: Henderson C&D Stats WQStat Plus" v.9.4.32 Hollow symbols indicate censored values. Exceeds Limit: MW-11 20000 16000 12000 8000 4000 3/24/09 Prediction Limit Interwell Non -parametric 4/29/11 6/3/13 7/9/15 8/13/17 9/18/19 ■ MW-11 MW-12 ♦ MW-13 Limit = 4690 Non -parametric test used in lieu of parametric prediction limit because censored data exceeded 50%. Limit is highest of 11 background values. 72.73% NDs. Report alpha = 0.2143. Individual comparison alpha = 0.07724. Most recent point for each compliance well compared to limit. Insufficient data to test for seasonality; data will not be deseasonalized. Constituent: Iron Analysis Run 1/14/2020 10:12 AM Facility: Henerson County C&D Landfill Data File: Henderson C&D Stats APPENDIX E EPA Natural Attenuation Screening Protocol Forms and BIOCHLOR Monitored Natural Attenuation Analysis for September 2019 Sampling Event Naturalenua ion Screening Protocol Interpretation Score Score: I S 5c roll to End of Table Inadequate evidence for anaerobic biodegradation' of cHorin#ed organics 0 to 5 Limited evidence for amembicbiodegadatiort of chlorinated organics 6 to 1 Q Tie bll*hg is t*e i" ti a US" A p nbml 11SEPA, 1gg8j. n e res r M or ti v scan g process iae io regr mtorq agi ncai ce. Adequate evidence for anaerobebiodegradation' of chlorinated organics 15 to 20 evi gra gancs Strongdence for anaerobic biode lotion' of chlorinated a 720 ' eorcwe decilomanoi Concentration in Points Analysis Most Contam. Zone Interpretation Yes No Awarded Oxygen' m.5 mg/L Tolerated, suppresses the reductive pathway at higher concentrations Q 0 >Emg/L Nottolerated; however,VC may be oxidized aerobically Q © 0 Nitrate' <1 mg/L At higher concentrations may compete with reductive pathway Q 2 Iron II' >1 mg/L Reductive pathway possible; VC may be oxidized under Fe(Ill)-re-ducin.q conditions D Q 3 Sulfate' 20 mgL At higher concentrations may compete with reductive pathway 0 Q 2 Sulfide* >1 mg/L Reductive pathway possible Q 0 Methane* a0.5 mg/L Ultimate reductive daughter product, VC Accumulates Q © n Oxidation Reduction Potential' (ORP) <60 ml)livolts (mV) Reductive pathway possible Q ig) A ¢-100mV Reductive pathway likely 0 0 0 PH' 5 ¢ pH <9 Optimal range for reductive pathway Q 0 TOC >20 mg/L Carbon and energy source, drives dechlorination; can be natural or anthro n enic 1) U 2 Temperature* >20'C At T >20'C biochemical process is accelerated O Q D Carbon Dioxide �,2x background Ultimate oxidative daughter product Q 1 Alkalinity �,2xbackground Results from interaction of carbondioxidewith aquifer minerals Q 1 Chloride' a2x background Daughter product of organic chlorine (K Q 2 Hydrogen a1 nM Reductive pathway possible, VC may accumulate Q Q 3 Volatile Fatty Acids >0.1 mg/L Intermediates resulting from biodegradation ofaromatic compounds. carbon and energy source Q Q 2 BTEX' >0.1 mg/L Carbonand energy source; drives dechlorination a © 0 PCE' Material released O Q 0 TCE' Daughter product of PCEa Q 0 DCE' Daughter product ofTCE. If cis is greater than 80% of total DCE it is likely a daughter product ofTCE``; 1 ,1-DCE can be a them. reaction product of TCA (D Q VC" Daughter product of DOE" Q (b 0 1,1,1- Trichloroethane' Material released d fl 0 DCA Daughter product ofT A under reducing conditions Q 0 Carbon Tetrachloride Material released Q fl 0 Chloroethane' Daughter product ofDCA, orVC under reducing conditions U U 0 Ethene/Ethane >0.01 mg/L Daughter product of VC/ethene Q 0 a0.1 mg/L Daughter product of VC/ethene U 0 Chloroform Daughter producf of Carbon Tetrachloride Q 0 Dichloromethane Daughter product of Chloroform { i ts q * requiredanalys . of Points awarded Orly if it canoe shown that the compound is a daughter product (i.e., mt a constituerl ofthe source NAPQ. DATE: 11 /18/19 Project #: 19128179 *> Prepared By: ESV G O L D E R I Reviewed By: DYR SCORE Reset Title: MW-7 MNA SCREENING September 2019 Baseline MNA Evaluation Henderson County Closed MSW Landfill, Permit No. 45-01 pendixl E-1 Natural Attenuation Screening Protocol Iriterpretzitlon Score Score: 22 Sei oll to End of Table Inadequate eoidence for anaerobic biodegradation` of cNonnated organics 0 to 5 Limited evidinoeioranaerobic biodegradation' ofchlorinatedorganics 6 to 14 ne Albullg VtAe1 from Ue USEPApU% VGEPA, 19981. Tie —n, of t1 V —h g p—ss lace to regl la[of ag1 wa— Adequate evidence for anaerobic biodegradation' ofohlorinatedorgan 15 to 20 Strong evidence for anaerobic biodegradation' of chlorinated orgarios >20 eOecWe Oecl bAlaN Concentration in ' Points Analy5la Most Contam. Zone IMerpretati0rl Yas NQ AMrdeO Oxygen- <0.5 mg/L Tolerated, suppresses the reductive pathway at higher concentrations 0 0 >5mg/L Nottolerated; however,VC may be oxidized aerobically 4�) 0 Nitrate' <1 mg/L At Higher concentrations may compete with reductive athwa 0 2 Iron II' Al mg/L Reductive pathway possible; VC may be oxidized under Fe(IIJ)-reducinq conditions p 0 3 Sulfate' 20 mg/L Ai higher concentrations may compete with reductive pathway 10 2 Sulfide' >1 mg/L Reductive pathway possible 0 t-} 0 Methane >0.5 mg1L Ultimate reductive daughter product, VC Accumulates J 3 Oxidation Reduction Potential*(ORP) c50 millivolts [mV] Reductive pathway possible O 1 5-107mV Reductive pathway likely 0 0 0 PH' 5 ¢ pH <9 Optimal rangefor reductive pathway (0 0 0 TOC >20 mg/L Carbon and energy source; drives dechlarination; can be natural or anthro o enic 0 2 Temperature' >20°C At T >20°C biochemical process is accelerated 0 fl 0 Carbon Dioxide >2x background Ultimate oxidative daughterprodud t9 0 1 Alkalinity >2x background Results from interaction of carbon dioxide with aquifer minerals O 0 1 Chloride' >2x background Daughter product of organic chlorine 49 0 2 Hydrogen y1 nM Reductive pathway possible, VC may accumulate U 0 3 Volatile Fatty Acids >0.1 mg/L Intermediates resulting from biodegradation of aromatic compounds; carbon and energy source 0 2 BTEX* >0.1 mg/L Carbon and energy source; drives dechlorination 0 fl 0 PCE* Material released 0 0 TCE* DaughterproductofPCEa (7 4) 0 DCE` Daughter productofTCE. If cis is greaterthan 801 oftotal DCE it is likely a daughter product ofTCE"; 1 ,1-DCE can be a them. reaction product of TCA 4 111 0 VC* Daughter productof DCEa d 0 O 1,1,1- Trichloroethane* Material released 0 g 0 DCA Daughter product of TCA under reducing conditions O 0 Carbon Tetrachloride Material released d 0 Chloroethane* Daughter productof DCA or VC under reducing conditions Q 0 Ethene/Ethane >0.01 mg/L Daughter product ofVClethene d 0 >0.1 mg/L DaughterproductofVClethene O © 0 Chloroform Daughter product of Carbon Tetrachloride 0 Q 0 Dichloromethane Daughter product of Chloroform 0 0 0 * required analysis. al Points awarded onlyif it canoe shown that the compound is a daughter product (i.e., not aconstituerd o£the source NAPL). DATE: 11 /18/19 Project #: 19128179 Prepared By: ESV G O L D E R I Reviewed By: DYR SCORE Reset Title: MW-6 MNA SCREENING September 2019 Baseline MNA Evaluation Henderson County Closed MSW Landfill, Permit No. 45-01 pendixl E-2 Natural Attenuation Interpretation Score TO INPUT Screening Inadequate evidence for anaerobic biodegradation* of chlorinated organics 0 to 5 Protocol Limited evidence for anaerobic biodegradation* of chlorinated organics Score: 17 6 to 14 The following is Taken Nora the usEPA pnotoco' (USEPA. 1998). The results of Nis scoring have no regulatory Adequate evidence for anaerobic biodegradation* of chlorinated organics 15 to 20 Strong evidence for anaerobic biodegradation* of chlorinated organics >20 process sigalnoanoe. Scroll to End of Table Concentration in eau eaeonlernation Points Analysis Most Contam. Zone Interpretation Yes NO Awarded Oxygen* <0.5 mg/L Tolerated, suppresses the reductive pathway at higher 0 concentrations > 5mg/L Not tolerated; however, VC may be oxidized aerobically 0 Nitrate* <1 mg/L At higher concentrations may compete with reductive O 0 2 pathway Iron II* >1 mg/L Reductive pathway possible; VC may be oxidized under 0 3 Fe(Ill)-reducing conditions Sulfate* <20 mg/L At higher concentrations may compete with reductive 0 2 pathway Sulfide* >1 mg/L Reductive pathway possible 0 Methane* >0.5 mg/L Ultimate reductive daughter product, VC Accumulates J 0 Oxidation <50 millivolts (mV) Reductive pathway possible 0 D 1 Reduction Potential* (ORP) <-100mV Reductive pathway likely 0 0 PH* 5 < PH < 9 Optimal range for reductive pathway 0 0 TOC >20 mg/L Carbon and energy source; drives dechlorination; can be O► 0 2 natural or anthropo enic Temperature* >20°C At T >20°C biochemical process is accelerated 0 0 0 Carbon Dioxide >2x background Ultimate oxidative daughter product 0 1 Alkalinity >2x background Results from interaction of carbon dioxide with aquifer 0 1 minerals Chloride* >2x background Daughter product of organic chlorine 00 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate 0 3 Volatile Fatty Acids >0.1 mg/L Intermediates resulting from biodegradation of aromatic 0 tom ounds; carbon and energy source BTEX* >0.1 mg/L Carbon and energy source; drives dechlorination 0 O 0 PCE* Material released 0 0 TCE* Daughter product of PCE ai 0 D 0 DCE* Daughter product of TCE. If cis is greater than 80% of total DCE it is likely a daughter p 0 product of TCEaf; 1,1-DCE can be a them. reaction product of TCA VC* Daughter product of DCE'/ 0 1,1,1- Material released 0 0 Trichloroethane* DCA Daughter product of TCA under reducing conditions 0 0 0 Carbon Material released 0 0 0 Tetrachloride Chloroethane* Daughter product of DCA or VC under reducing conditions 0 0 Ethene/Ethane >0.01 mg/L Daughter product of VC/ethene 0 0 0 >0.1 mg/L Daughter product of VC/ethene o 0 0 Chloroform Daughter product of Carbon Tetrachloride 0 0 Dichloromethane Daughter product of Chloroform 0 ® 0 * required analysis. al Points awarded only if it can be shmn that the compound is a daughter product TO INPUT SCORE Reset (i.e., not aconstituent of the source NAPL). ` DATE:11118/19 Title: MW-8 MNA SCREENING Project#: 19128178 Appendix September 2019 Baseline MNA Evaluation Prepared By: ESV Henderson County Closed MSW Landfill, E-3 G O L D E R Permit No. 45-01 Reviewed By: DYR Natural Attenuation Interpretation Score TO INPUT Screening Inadequate evidence for anaerobic biodegradation* of chlorinated organics 0 to 5 Limited evidence for anaerobic biodegradation* of chlorinated organics 6 to 14 Protocol Score: 19 Adequate evidence for anaerobic biodegradation* of chlorinated organics 15 to 20 The following ie taken from me USEPA protocol (USEPA, lgga). The results of this scoring process have no regulatory Strong evidence for anaerobic biodegradation* of chlorinated organics >20 significance. Scroll to End of Table ' reductive dechlorination Concentration in Points Analysis Most Contam. Zone Interpretation Y es NO Awarded Oxygen* <0.5 mg/L Tolerated, suppresses the reductive pathway at higher p 0 concentrations > 5mg/L Not tolerated; however, VC may be oxidized aerobically D 0 0 Nitrate* <1 mg/L At higher concentrations may compete with reductive D O 2 pathway Iron II* >1 mg/L Reductive pathway possible; VC may be oxidized under 0 O 3 Fe(Ill)-reducing conditions Sulfate* <20 mg/L At higher concentrations may compete with reductive D O 2 pathway Sulfide* >1 mg/L Reductive pathway possible O D 0 Methane* >0.5 mg/L Ultimate reductive daughter product, VC Accumulates 0 0 0 Oxidation <50 millivolts (mV) Reductive pathway possible O► L 1 Reduction Potential* (ORP) <-100mV Reductive pathway likely O 0 0 PH- 5 < pH < 9 Optimal range for reductive pathway Q O 0 TOC >20 mg/L Carbon and energy source; drives dechlorination; can be t7 0 2 natural or anthro o enic Temperature* >20°C At T >20°C biochemical process is accelerated O D 0 Carbon Dioxide >2x background Ultimate oxidative daughter product D 0 1 Alkalinity >2x background Results from interaction of carbon dioxide with aquifer D O 1 minerals Chloride* >2x background Daughter product of organic chlorine D O 2 Hydrogen >1 nM Reductive pathway possible, VC may accumulate D 0 3 Volatile Fatty Acids >0.1 mg/L Intermediates resulting from biodegradation of aromatic O ® 0 compounds; carbon and energy source BTEX* >0.1 mg/L Carbon and energy source; drives dechlorination O D 0 PCE* Material released O m 0 TCE* Daughter product of PCE ai 0 D 0 DCE* Daughter product of TCE. If cis is greater than 80% of total DCE it is likely a daughter O ® 0 product of TCE'/; 1, 1 -DCE can be a them. reaction product of TCA VC* Daughter product of DCE" O ® 0 1,1,1- Material released O D 0 Trichloroethane* DCA Daughter product of TCA under reducing conditions D O 2 Carbon Material released O D 0 Tetrachloride Chloroethane* Daughter product of DCA or VC under reducing conditions O O 0 Ethene/Ethane >0.01 mg/L Daughter product of VC/ethene O D 0 >0.1 mg/L Daughter product of VC/ethene O D 0 Chloroform Daughter product of Carbon Tetrachloride O 0 0 Dichloromethane Daughter product of Chloroform 0 D 0 * required analysis _ at Points awarded only if it can be shown that the compound is adaighter product TO INPUT SCORE Reset (i.e., not a constituent of the source NAPL). ' DATE:11/18/19 Title: OLD MW-2 MNA SCREENING Appendix Project#: 19128179 September 2019 Baseline MNA Evaluation E-4 Prepared By: ESV Henderson County Closed MSW Landfill, G I L D E R Permit No. 45-01 Reviewed By: DYR BIOCHLOR Natural Attenuation Decision Support System Version 2.2 Excel 2000 TYPE OF CHLORINATED SOLVENT: Ethenes Ethanes 1. ADVECTION Seepage Velocity, or Hydraulic Conductivity Hydraulic Gradient Effective Porosity----- 2. DISPERSION Alpha x' (Alpha y) ! (Alpha x)' (Alpha zLiha x , --- 3. ADSORPTION Retardation Factor, or Soil Bulk Density, rho FractionOrganicCarbon, foc Partition Coefficient PCE TCE DCE VC ETH Common R (u 4. BIOTRANSFORMATION Zone 1 PCE TCE TCE DCE DCE VC VC ETH Zone 2 PCE TCE TCE DCE DCE VC VC ETH Vs K i n (ft) Calc. 0R I5. GENERAL Q Simulation Timex -- Modeled Area Width, ftlyr) Modeled Area Length Zone 1 Length, cm/sec) (Zone 2 Length, futt) 1.7 (kg1L) 1 OEM (- Koc 426 (Ukg) 1.48 ( ) 130 (Ukg) 1.15 0125 (Ukg) 1.14 ( ) 30 (Ukg) 1.03 ( ) 302 (Ukg) 1.34 (-) sed in mod"* = 1.15 --_ -1st order Decay Coefficient' 1 r half-life (yrs) Yield 12.000 1.20 0.79 20.000 0.90 0.74 1.000 F 1.50 0.64 6.000 2.60 0.45 1 r half-life (yrs) 12.000 <- 1.20 1 20.000 0.90 HELP 1.000 1.50 6.000 2.60 Henderson County Data Input Instructions: Landfill 115 1. Enter value directly....or Run Name 'h or 2. Calculate by filling in gray 0.02 cells. Press Enter, then 59 (yr) ~ L � (To restore formulas, hit "Restore Formulas" button } 370 (ft) W Variable' : Data used directlyin model. 550 (ft) Test if 550 (ft) Biotransformation Natural Attenuation B transfo 0 (ft) Zone 2= L. Screening Protocol lis L - Zone 1 6. SOURCE DATA _ TYPE: Continuous Source Options Single Planar Source Thickness in Sat. Zone, F 55 (ft) Y1 Width, (ft) 370 ks, Conc. (mglL), C1 (1tyr) PCE .17 0 TCE .027 0 DCE .031 0 VC .005 0 ETH 0 0 7. FIELD DATA FOR COMPARISON PCE Conc. (mg(L) TCE Conc. (mg/L) DCE Conic. (mglL) VC Conc. (mg1L) ETH Conc. (mg/L) Distance from Source (ft) --Vertical Plane Source: Determine Source Well Location and Input Solvent Concentrations View of Plume Looking Down Observed Centerline Conic. at Monitoring Wells Date_ Data Collected2019-- 8. CHOOSE TYPE OF OUTPUT TO SEE: RUN CENTERLINE RUN ARRAY Help Restore RESET SEE OUTPUT Paste 1310CHLOR Natural Attenuation Decision Support System Version 2.2 Excel 2000 TYPE OF CHLORINATED SOLVENT: Ethenes I5. GENERAL Ethanes Q Simulation Time' Modeled Area Width' 1. ADVECTION Seepage Velocity' Vs 74.1 (MI-) Modeled Area Length* or Hydraulic Conductivity K f 1.3E-04 (cm/sec) Zone 1 Length' Zone 2 Length' Hydraulic Gradient i 0.0853 (ft/ft) Effective Porosityn0.15 2. DISPERSION Alpha x' 47.5 (ft) CaIC. (Alpha y) I (Alpha x)' 0.1 ( ) (AJEha zLlha x --- 5. E-02 _----------I 3. ADSORPTION Retardation Factor' R or Soil Bulk Density, rho FractionOrganicCarbon, foc Partition Coefficient PCE TCE DCE VC ETH Common R 4. BIOTRANSFORMATION Zone 1 PCE TCE TCE DCE DCE VC VC ETH Zone 2 PCE TCE TCE DCE DCE VC VC ETH Henderson County jData Input Instructions: M (yr) (ft) (ft) (ft) 0 (ft) Landfill Run Name �L W 1 Zone 2= L - Zone..1 6. SOURCE DATA _ TYPE: Continuous Source Options Single Planar 55 (ft) ks' (1tyr) 1.7 (kgtL) PCE .17 0 TCE 027 0 Koc DCE 031 0 426 (Ukg) 1.48 (-) VC 005 0 130 (Ukg) 1.15 (-) ETH 0 0 125 (Ukg) 1.14 30 (Ukg) 1.03 (-) 7. FIELD DATA FOR CONPARISON Source Thickness in Sat. Zone' Y1 Width' (ft) 370 Conc. (mg/L)' C1 302 (Ukg) 1.34 (-) PCE Conc. (mg/L) sed in model * = 1.15 _ TCE Conc. (mg1L) -1st order Decay Coefficient' ,DCE Conc. (mglL) x 0 r half-life (yrs) Yield JVC Conc. (mg1L) 12.000 1.20 0.79 JETH Conc. (mg/L) 20.000 0.90 0.74 IDistance from Source (ft) 115 1. Enter value directly .... or or 2. Calculate by filling in gray 0.02 cells. Press Enter, then G (To restore formulas, hit "Restore Formulas" button ) Variable' Data used directly in model. Test if Biotransformation is Occurrinq Natural Attenuation Screening Protocol --Vertical Plane Source: Determine Source Well Location and Input Solvent Concentrations View of Plume Looking Down Observed Centerline Conc. at Monitoring Wells 1.000 1.50 0.64 jDate Data Collected 1 2019 6 000 2.60 045 18. CHOOSE TYPE OF OUTPUT TO SEE: x 0 r half-life (yrs) 12.000 1.20 f7HELP RUN CENTERLINE RUN ARRAY 20 000 <' 0.90 Aj..Help Restore RESET E1.000 1.50 SEE OUTPUT Paste 6.000 2.60 P DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source ft Distance from Source (ft) PCE 0 55 110 ;7:(, 165 220 275 330 385 440 495 550 PCE 0 55 110 165 220 275 330 385 440 495 550 No Degradation 0.170 0.167 0.162 0.155 0.148 0.142 0.136 0.131 0.125 0.121 No Degradation 0.170 0.170 0.167 0.162 0.155 0,148 0.142 0.136 0.131 0.125 0.121 otransformation 0.1700 0.012 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Biotrensformalion 0.1700 0.012 0.00t 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Monitorinp Well Locations ft Monitorinp Well Locations ft 100 110 210 450 100 110 210 450 d Data from Site 0.000 0.000 0.000 0.0001 1 ata from Sitel 0.000 1 0.000 1 0.000 1 0.000 -No Degradati.NProdudion -Sequential 1st Order Decay n Field Data from Site -No Degradation/Production -Sequential 1st Omer Decay P Field Data from Site 0.16 ` See PCE 0.16 See PCE W 0.14 r See TCE 0:14 r See TCE E 0.12 550 550 l C 0.10 See DCE C 0.10 See DCE 'q 0.08 ` l 0.08 0.06 S� VC 0.06 r See VC 0.04 N 0.04 ? c 0.02 r See ETH 0.02 See ETH o U 0.00 0 100 200 300 400 500 600 l 0 U 0.00 0 100 200 300 400 500 600 Distance From Source (ft.) Distance From Source (ft.) Time: - - Time: 59.0 Years Return to 100.0 Years r Un otect Pr Return to Prepare Animation Unprotecl Sheet To All Input To Array Prepare Animation Log Linear Sheet In t Pu To All To Array Log ��Linear � ` DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source ft Distance from Source ft TCE 0 55 110 165 220 275 330 385 440 495 550 TCE 0 55 110 165 220 275 330 385 440 495 550 No Degradation 0.027 0.027 0.027 0.026 0.025 0.024 0.023 0.022 0.021 0.020 0.019 No De radatlon 0.027 0.027 0.027 0.026 0.025 0.024 0.023 0.022 0.021 0.020 0.019 Biotransformation 0.0270 0.009 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 B'otmnsformatlon 0.0270 0.009 0.001 0.000 0.000 0.000 0.000 0.000 0.000 0.000 0.000 Monitorin Well Locations ft Monitorin Well Locations ft 100 110 210 450 100 110 210 450 Field Data from Site 0.000 0.000 0.000 0.000 Field Data from Site 0.000 0.000 0.0001 0.000 No Degradation/Production -Sequential lst Omer Decay n Field Data from Site -No Degmdaticn/Production -Sequential lal Omer Decay C Field Data from Site 0.03 0.03 See PCE See PCE J 0.03 J 0.03 rn See TCE See TCE E 0.02 ` E 0.02 C 0 02 550 See DCE o 0.02 550 See DCE 0.01 N See VC 0.01 See VC u 0.01 100 200 300 400 500 600 v 0 01 1 0 200 300 400 500 600 t= See ETH See ETH rj 0.00 ` ' U 0.00 Distance From Source (ft.) Distance From Source (ft.) Time: -_ Time: 0 59.0 Years Return _ 100.0 Years � r Return to Prepare Animation Un tact pro Sheet to Input TO All TO Army Prepare Animation �>Linear UnProted Sheet To All Input To Array Log ��Linear Log ` � DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source ft Distance from Source ft DCE 0 55 110 165 220 275 330 385 440 495 550 DCE 0 55 110 165 220 275 330 385 440 495 550 No Degradation 0.031 0.031 0.030 0.029 0.028 0.027 0.026 0.024 0.023 0.023 0.022 No Degradation 0,031 0.031 0,030 0.029 0.028 0.027 0.026 0.024 0.023 0.023 0.022 B...risformation 0.0306 0.085 0.058 0.035 0.020 0.012 0.007 0.004 0.002 0.001 0.001 Blotransformation 0.0306 0.085 0.058 0.035 0.020 0.012 0.007 0.004 0.002 0.001 0.001 Monitorin Well Locations(ft),Monitorin Well Locations ft 100 110 210 450100 110 210 450 Field Data from Site 0.000 0.000 0.000 0.000 Field Data from Site 0.000 0.000 0.000 0.000 -No Degradation/Production -Sequential tat Order Decay 3 Field Data from Slte -No Degradation/Production -Sequ.ml.11 et Omer Decay tr Fieltl Data from Site 0.09 0.09 0.08 See PCE 0.08 See PCE J 0.07 See TCE J 07 See TCE 0.06 E 0.06 0 0.05 See DCE C p 0.05 See DCE 0. @04 ' 0.04 0.03 See VC 0.03 See VC u0.02 550 0 0.02 550 0.01 See ETH C 0.01 1 See ETH 0 U 0.00 100 200 300 600 U 0.00 100 200 300 600 Distance From Source (ft.) Distance From Source (ft.) _ Time: -. Time: Prepare Animation 59.0 Years r n rotect Up Sheet Return to Input To All To Array Prepare Animation f00.0 Years U nprotcct Log Linear Sheet Return to Input To All TO Array Log �-JLinear ` DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source (ft) Distance from Source ft VC 0 55 110 165 220 275 330 385 440 495 550 Vri 0 55 110 165 220 275 330 385 440 495 550 No De radatlon 0.005 0.005 0.005 0.005 0.005 0.004 0.004 0.004 0.004 0.004 0.004 No De radation 0.005 0.005 0.005 0.005 0.005 0.004 0.004 0.004 0.004 0.004 0.004 Blotmnsfonnation 0.0050 0.008 0.007 0.004 0.003 0.001 0.001 0.000 0.000 0.000 0.000 Biotransfonnation 0.0050 0.008 0.007 0.004 0.003 0.001 0.001 0.000 0.000 0.000 0.000 Monitorin Well Locations ft Monitorin Well Locations k 100 110 210 450 100 110 210 450 Fieltl Data from Site 0.000 0.000 0.000 0.000 Fieltl Data from Site 0.000 1 0.000 1 0.000 1 0.000 -No Degradation/Production -Sequenlial 1el Omer Decay D Field Data from Site -No Degradation/Production Sequential tat Omer Decay : Field Data from Site 0.01 0.01 1100 200 300 400 500 600 See PCE 1@0 200 300 400 500 600 See PCE 001 J 001 0.01 See TCE E 0.01 See TCE E 0.01 .E 0.01 O 0.01 ` See DCE l 0 0 01 See DCE 0.00 o.o0 d 0.00 55o See VC d 0.00 550 See VC C 0.00 See ETH C 0.00 See ETH U 0.00 ` V 0.00 Distance From Source (ft.) Distance From Source (ft.) Time: Time: e100.0 59.0 Years r r Return to Years r Return to Prepare Animation Unprotect To All To Array Prepare Animation Unprotect To All To Arra y Log Linear ` Sheet Input Log Linear ` Sheet Input DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg1L) at Z=0 DISSOLVED CHLORINATED SOLVENT CONCENTRATIONS ALONG PLUME CENTERLINE (mg/L) at Z=0 Distance from Source ft Distance from Source (ft) ETH 0 55 110 165 220 275 330 385 440 495 550 ETH 0 55 110 165 220 275 330 385 440 495 550 No Degradation o.000 o.000 o.000 0.000 0.000 0.00o o.000 0.000 0.000 0.00o o.000 No De radation 0.000 0.000 0.00o o.000 0.000 0.000 O.ODo 0.000 0.000 0.000 0.000 Blotransfonnation 0.0000 0.014 0.025 0.032 0.035 0.036 0.036 0.035 0.034 0.033 0.032 Biotransformation 0.0000 0A14 0.025 0.032 0.035 0.036 0.036 0.035 0.034 0.033 0.032 Monitorin Well Locations(ft),Monitorin Well Locations ft 100 110 210 450100 110 210 450 Field Data from Sitel 0.000 1 0.000 1 0.000 1 0.000 1 1 1 1 1 ta from Site 0.000 0.000 0.000 0.000 -No Degradation/Produdion -Sequential tat Omer Decay o Field Dala from Site -No Degradation/Production -Sequential let Omer Decay rl Field Data from Sit. 0.04 0'04 j 0.04 See PCE J 0.04 See PCE r rn 0.03 E See TCE at 0.03 See TCE 0.03 = 0.03 0 0.02 ` See DCE r o 0.02 ` See DCE s 0.02 0.02 y 0.01 See VC s 0.01 See VC 2 0.01 200 300 400 500 -600 See ETH C 0.01 100 200 300 400 500 0 See ETH fj 0.00 ` ' U 0.010 ` Distance From Source (ft.) Distance From Source (ft.) Time: _ Time: 11 59.0 Years r � Return to 100.0 Years r Return to r Prepare Animation Uprotact n Sheet 7o All Input TO Array Prepare Animation Unprotcct Input To All To Amay Log �>Linear ` Log C==Linear Shoat GOLDER golder.com