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HomeMy WebLinkAbout6301_Moore_MSWLF_CDLF_WQMP_FID1387272_20200106J GOLDER REPORT WATER QUALITY MONITORING PLAN - MOORE COUNTY LANDFILL, PERMIT NO. 63-01 Volume 2 - Moore County Design Hydrogeologic Report and Monitoring Plans Submitted to: Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 (828) 296-4706 Submitted by: Golder Associates NC, Inc. 5B Oak Branch Drive Greensboro, North Carolina, USF +1 336 852-4903 1895531 December 10, 2019 December 2019 Distribution List 1895531 Chao, Ming-Tai, PE, Environmental Engineer, NC DEQ, Division of Waste Management, Solid Waste Section, Permitting Branch, 1646 Mail Service Center, Raleigh, NC 27699-1646, ming.chao@ncdenr.gov Drummond, Jaclynne, Hydrogeologist, NC DEQ, Division of Waste Management, Solid Waste Section, 2090 US Highway 70, Swannanoa, NC 28778, jaclynne.drummond@ncdenr.gov Gould, Randy, PE, Director, Moore County, Department of Public Works, 5227 US Highway 15, Carthage, NC 28327-1927, rgould@moorecountync.gov Lambert, David Interim Solid Waste Director, Moore County, Department of Public Works, 5227 US Highway 15, Carthage, NC 28327-1927, awilkison@moorecountync.gov 4 GOLDER December 2019 1895531 Table of Contents 1.0 INTRODUCTION.............................................................................................................................................1 1.1 Site Description....................................................................................................................................1 1.2 Site Hydrogeology................................................................................................................................1 2.0 GROUNDWATER MONITORING SYSTEM...................................................................................................2 2.1 Groundwater Monitoring Well Network................................................................................................2 2.2 Groundwater Monitoring Well Construction.........................................................................................3 2.3 Groundwater Monitoring Well Development........................................................................................3 2.4 Maintenance and Recordkeeping........................................................................................................3 2.5 Monitoring Well Decommissioning.......................................................................................................4 3.0 GROUNDWATER MONITORING PROGRAM...............................................................................................4 3.1 Active C&D Landfill..............................................................................................................................4 3.1.1 Detection Monitoring.......................................................................................................................5 3.1.1.1 Sampling Frequency....................................................................................................................5 3.1.1.2 Establishment of Background Data.............................................................................................5 3.1.1.3 Evaluation of Background Data...................................................................................................5 3.1.2 Assessment Monitoring...................................................................................................................5 3.1.3 Evaluation and Reporting of Monitoring Data.................................................................................6 3.2 Closed MSW Landfill............................................................................................................................6 3.2.1 Corrective Action.............................................................................................................................7 3.2.1.1 Sampling Frequency....................................................................................................................7 3.2.1.2 Evaluation of Data........................................................................................................................7 3.2.2 Evaluation and Reporting of Monitoring Data.................................................................................7 4.0 GROUNDWATER SAMPLING METHODOLOGY.........................................................................................7 4.1 Sample Collection................................................................................................................................8 4.1.1 Static Water Elevations...................................................................................................................8 4.1.2 Well Evacuation..............................................................................................................................8 4.1.2.1 Low -Flow Procedures..................................................................................................................8 > GOLDER December2019 1895531 4.1.2.2 Standard Evacuation Procedures..............................................................................................10 4.1.2.3 Collection...................................................................................................................................10 4.1.2.4 Decontamination........................................................................................................................11 4.2 Sample Preservation and Handling...................................................................................................11 4.3 Chain -of -Custody Program................................................................................................................11 4.3.1 Sample Labels..............................................................................................................................11 4.3.2 Sample Seal..................................................................................................................................12 4.3.3 Field Logbook................................................................................................................................12 4.3.4 Chain -of -Custody Record.............................................................................................................12 4.4 Analytical Procedures........................................................................................................................13 4.5 Quality Assurance and Quality Control Program...............................................................................14 5.0 STATISTICAL METHODS............................................................................................................................14 6.0 SURFACE WATER MONITORING (RULE .0602).......................................................................................14 7.0 REFERENCES..............................................................................................................................................15 TABLES Table 1 Summary of Proposed Changes to the Groundwater Monitoring Network Table 2 Summary of Groundwater Monitoring Well Construction Information Table 3 Summary of Proposed Constituents and Analytical Methods Table 4 Proposed Water Quality Monitoring Schedule DRAWINGS Drawing WQMP-1 Proposed Water Quality Monitoring Plan APPENDIX A Boring Logs and Well Construction Records APPENDIX B Groundwater Protection Compliance Standards - Constituents List APPENDIX C Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling GOLDER December 2019 1895531 1.0 INTRODUCTION This Water Quality Monitoring Plan (WQMP) will serve as a guidance document for collecting and analyzing groundwater and surface water samples, evaluating the associated analytical results, and monitoring potential releases to the uppermost aquifer from the Moore County Landfills, North Carolina Solid Waste Permit (NC SWP) No. 63-01, located at 456 Turning Leaf Way near the town of Aberdeen in Moore County, NC. The NC SWP No. 63-01 includes two permitted waste units: an active Construction and Demolition (C&D) landfill and a closed Municipal Solid Waste (MSW) landfill. This WQMP complies with the NC Solid Waste Management Rules (NCSWMR) listed in the NC Administrative Code (NCAC) Subchapter 13B .0544 through .0545 as it relates to the active C&D landfill and NCAC 13B .0601 as it relates to the closed MSW landfill. This plan also addresses the requirements for surface water monitoring as specified in NCAC 13B .0602. The pertinent geologic and hydrogeologic characteristics of the site, as described in the Design Hydrogeologic Report submitted as part of the Permit Amendment associated with the later expansion of the proposed Cell 6 at the active C&D landfill and previous water quality monitoring reports prepared by Golder Associates NC, Inc. (Golder) are summarized below. 1.1 Site Description The Moore County Landfill (the "facility" or the "site") is located in southwestern Moore County with the jurisdiction of Pinehurst between the towns of Pinehurst and Aberdeen, as shown on inset of Drawing WQMP-1. The facility is bound to the west by Horse Creek and to the north and south by unnamed tributaries of Horse Creek. A power - line right-of-way transects the property and represents the eastern boundary of the closed municipal solid waste (MSW) landfill. Topographic surface elevations at the facility range from approximately 460 feet above mean sea level (AMSL) along the eastern portion of the closed MSW landfill to approximately 350 feet AMSL on the southwestern side of the facility. The site is surrounded predominately by wooded, agricultural, or rural residential properties. The Moore County Landfill comprises approximately 314 acres and contains an active C&D landfill unit, a closed unlined MSW landfill unit, and several land clearing and inert debris (LCID) landfill units. In conjunction with Moore County, Republic Services of NC, LLC operates a solid waste transfer station located on the southwestern portion of the property. The MSW landfill accepted waste from approximately 1968 to 1993 and was closed prior to October 1993, with final closure approved in December 1996; the County expressed their intent to comply with post -closure monitoring regulations in January 1997. The MSW area encompasses approximately 60 acres, 12 of which have a clay cap. The County began transferring MSW waste in 1993. The County temporarily stockpiled C&D waste from approximately 1993 to 1996, until the current C&D landfill was permitted and constructed (HDR, 2005). 1.2 Site Hydrogeology The Moore County Landfill is located in the inner Coastal Plain Physiographic Province of North Carolina. The geologic units of this region are relatively young, dating from the Cretaceous to the Tertiary period (NCGS, 1985). The site is underlain by sands, silts, and clays of the Middendorf Formation, which generally consists of intercalated, lenticular, thick -bedded, light-colored sands and clays (mudstones) with local concentrations of clay - cast conglomerates (NCGS, 1985 and Sohl and Owens, 1991). The uppermost groundwater beneath the facility is present in a shallow, unconfined aquifer comprised of sands mixed with thin clay seams and larger seams of fine sand. The uppermost aquifer at the site is approximately 55 4 GOLDER December2019 1895531 feet thick and underlain by a clay confining layer (HDR, 2005). Groundwater occurs at depths varying form approximately 5 to 38 feet below ground surface (bgs) across the entire site. Surface water and groundwater at the site generally flows to the west and southwest toward Horse Creek, which is located along the western property boundary. Limited surface water and groundwater flows to the north and south to unnamed tributaries of Horse Creek located along the northern and southern property boundaries. Historically, the average estimated linear groundwater flow velocity for the subsurface at the facility is around 300 feet/year. The range of groundwater flow is expected to vary depending on the topographic and hydrogeologic conditions. The modified Darcy equation used to calculate the linear flow velocity makes simplified assumptions of a homogenous and isotropic aquifer. Therefore, this estimate of linear groundwater flow velocity only represents a presumptive estimated value for the uppermost aquifer and does not account for the heterogeneous and/or anisotropic conditions that may be present in the uppermost aquifer at the facility. 2.0 GROUNDWATER MONITORING SYSTEM The following section presents the proposed monitoring well network for the active C&D landfill and the closed MSW landfill, along with the specifications associated with installing, developing, maintaining, and decommissioning facility groundwater monitoring wells. The proposed well locations are selected to yield groundwater samples representative of the sub -surface conditions in the uppermost aquifer underlying the facility, and to monitor potential releases from each landfill unit. Well placement, well construction methods, well development, well maintenance, and well decommissioning procedures are discussed in the following sections. 2.1 Groundwater Monitoring Well Network As presented, there are two groundwater monitoring well networks at the site — one network to monitor groundwater beneath the active C&D landfill and one to monitor groundwater beneath the closed MSW landfill. One background monitoring well, MW-5, provides background data for both groundwater monitoring networks. The proposed active C&D landfill groundwater monitoring network consists of eight downgradient monitoring wells (MW-4, MW-11SR, MW-11DR, MW-13S, MW-13D, MW-17S, MW-17D, and MW-18) and one additional upgradient monitoring well (MW-14) which monitors groundwater between the adjacent upgradient closed MSW landfill and the active C&D landfill. The proposed closed MSW landfill groundwater monitoring network consisted of eight downgradient monitoring wells (MW-1, MW-2, MW-3, MW-6, MW-7, MW-8, MW-9, and MW-15R). In addition, we are proposing to use two C&D monitoring wells (i.e., MW-4 and MW-11 SR) as "performance" or monitored natural attenuation (MNA) monitoring wells related to ongoing corrective action at the closed MSW landfill. A table summarizing the proposed changes to the monitoring well network has been included as Table 1. In addition, a table summarizing the well construction information for each monitoring well in the compliance network has been included as Table 2. Each monitoring well location is shown on the included Drawing WQMP-1 and the associated boring logs for each monitoring well can be found in Appendix A. One off -site homeowner well (PW-1 at Blake residence) has been monitored semi-annually since October 1996 in conjunction with routine groundwater monitoring events. Due to the upgradient location of the well, its current status (unused as house is unoccupied), and the amount of historical data which do not indicate any landfill impacts, we recommend annual rather than semi-annual monitoring at this location. 4 GOLDER December 2019 1895531 2.2 Groundwater Monitoring Well Construction Previous and future drilling and installation of monitoring wells at the facility has and will be performed in accordance with the specifications outlined in 15A NCAC 2C .0100. Additionally, Moore County will utilize the guidance document Draft North Carolina Water Quality Monitoring Guidance for Solid Waste Facilities; Solid Waste Section (SWS), Division of Waste Management (DWM); Department of Environmental, Health, and Natural Resources (NC DENR) — March 1995. During the future installation of monitoring wells, a geologist will oversee drilling activities and prepare boring and well construction logs documenting each new monitoring well. As required, following the installation of each new monitoring well a NC licensed surveyor will be procured to survey each new monitoring well to within ±0.1-inch on the horizontal plane and to within ±0.01-inch on the vertical plane in North Carolina State Plane North American Datum (NAD) 1983 feet. Following the installation of new groundwater monitoring wells, a boring log, well construction log, groundwater monitoring network map, well installation certification (i.e., GW-1 Form), and the survey data will be submitted in a report to the SWS within 30 days of the completion of field activities unless prior approval is obtained for an alternate submittal schedule. 2.3 Groundwater Monitoring Well Development Each newly constructed groundwater monitoring well will be developed to remove particulates present in the well due to construction activities and to interconnect the monitoring well with the aquifer. Development of new groundwater monitoring wells will be performed no sooner than 24 hours after well completion allowing time for the Portland cement/bentonite slurry to setup following construction. A surge block may be used as a means of assessing the integrity of the well screen and riser. If a pump is employed, the design of the pump will be such that any groundwater that has encounter the surface atmosphere is not allowed to drain back into the monitoring well. In general, each groundwater monitoring well will be developed until the water is sediment free (i.e., less than 10 NTUs) or is as sediment free as feasibly possible and the following field parameters: temperature, pH, and specific conductance (to be collected during development) have stabilized. Well development equipment (e.g., bailers, pumps, surge blocks, etc.) and any other equipment that contacts the inner monitoring well casing or groundwater shall be decontaminated via the use of Alconox and deionized or distilled water prior to on -site use, between consecutive on -site uses, and/or between consecutive monitoring well installations. Samples withdrawn from the facility's monitoring wells should be clay- and silt -free; therefore, existing wells may require re -development from time to time based upon observed turbidity levels during sampling activities. If re -development of an existing monitoring well is required, it will be performed in a manner similar to that used for a new well. 2.4 Maintenance and Recordkeeping The monitoring wells will be used and maintained in accordance with design specifications throughout the life of the monitoring program. Routine well maintenance will include inspection and correction/repair of, as necessary, identification labels, concrete aprons, locking caps and locks, and access to the wells. Should it be determined that background or compliance monitoring wells no longer provide samples representative of the quality of groundwater passing the relevant point of compliance, the SWS will be notified. The owner will re-evaluate the monitoring network, and provide recommendations to the SWS for modifying, rehabilitating, decommissioning, or installing replacement or additional monitoring wells, as appropriate. Laboratory analytical results will be submitted to the SWS semi-annually within 120 days of completion of the sampling event. Analytical data, calculations, and other relevant groundwater monitoring records will be kept 4 GOLDER December2019 1895531 throughout the active life of the facility and the post -closure care period, including notices and reports of any North Carolina (2L) Groundwater Protection Standard exceedances, resampling notifications, and re -sampling results. 2.5 Monitoring Well Decommissioning Piezometers and wells installed within the MSW waste footprint will be properly decommissioned in accordance with the procedures for permanent decommissioning, as described in 15A NCAC 2C Rule .0113(b). The piezometers and wells will be progressively decommissioned as necessary to complete landfill construction activities. The piezometers and wells that are within the proposed footprint will be overdrilled to remove well construction materials, and then grouted with a cement-bentonite grout. Other piezometers and wells that require decommissioning will be grouted in place without overdrilling with a cement-bentonite grout and removing surface features, such as concrete aprons, protective casings, and stick-ups. In each case, the bentonite content of the cement-bentonite grout shall be approximately 5%, and a tremie pipe will be used to ensure that grout is continuously placed from the bottom of the borehole/monitoring well upward. If a monitoring well becomes unusable during the monitoring period of the landfill, the well will be decommissioned in accordance with the procedures described above. Approval from the SWS will be obtained prior to decommissioning any monitoring well. For each monitoring well decommissioned, the following information will be provided to the SWS in a report sealed by a licensed geologist: the monitoring well name, a description of the procedure by which the monitoring well was decommissioned, the date when the monitoring well was considered to be taken out of service, and the date when the monitoring well was decommissioned. 3.v GROUNDWATER MONITORING PROGRAM The following sections describe the proposed groundwater monitoring program for the active C&D and the closed MSW landfill units owned and operated by Moore County under NC SWP# 63-01. 3.1 Active C&D Landfill Moore County met with NC DEQ on March 10, 2016 to discuss groundwater impacts at the site and the effectiveness of the previously implemented corrective actions at the facility. In this meeting and in a follow-up, correspondence sent from NC DEQ on March 14, 2016, the SWS requested that Moore County commence assessment monitoring at the C&D landfill or submit an alternate source demonstration (ASD) to demonstrate the impacts observed in the C&D landfill monitoring network were from a source other than the C&D landfill. On February 28, 2017, the County submitted an ASD for the Active C&D Landfill, identifying the upgradient closed unlined MSW landfill as the source of VOCs at downgradient C&D wells. In two letters dated September 28, 2017, the NC DEQ declined to issue a determination on the ASD for the Active C&D Landfill and requested Moore County implement landfill gas and groundwater corrective action at the closed MSW landfill, as well as commence assessment monitoring as detailed in 15A NCAC 13B .0545 at the active C&D landfill. The County submitted a response to these communications on October 26, 2017 and met with NC DEQ on November 30, 2017. Following this meeting, Moore County submitted a letter on December 6, 2017 confirming the County's intention to comply with the requests of NC DEQ and requesting an extension to comply. This request was approved by NC DEQ on December 11, 2017. The Moore County landfill is currently completing the background phase of assessment monitoring at the active C&D landfill in accordance with the Assessment Monitoring Work Plan (Golder, 2018) approved by NC DEQ in a correspondence dated January 23, 2018. 4 GOLDER December 2019 1895531 3.1.1 Detection Monitoring Should the active C&D landfill return to detection monitoring, groundwater samples for the active C&D landfill monitoring network (described in Section 2.1) will be analyzed semi-annually for the constituents listed in NC Appendix I plus mercury, chloride, manganese, sulfate, iron, specific conductance, pH, temperature, alkalinity, and total dissolved solids as defined in 15A NCAC 13B .0544(b)(1)(D), during the life of the facility and the post - closure care period. Refer to Appendix 8 of this report for a list of the required constituents, analytical methods, and applicable standards. 3.1.1.1 Sampling Frequency As presented, groundwater samples will be collected and analyzed for constituents outlined in Table 3 plus required field parameters, including but not limited to, pH, conductivity, and temperature per the schedule proposed on Table 4 (i.e., semiannually for the active C&D landfill). 3.1.1.2 Establishment of Background Data Prior to the construction of the proposed Cell 6, a minimum of four (4) independent groundwater samples will be collected from the recently installed groundwater monitoring wells associated with the proposed Cell 6 area. Samples collected from these wells will be analyzed for Appendix I constituents. The intent of background sampling is to collect data to more accurately reflect the natural fluctuations that may occur with these constituents. The data will be submitted to the SWS after completion of the fourth background sampling event. 3.1.1.3 Evaluation of Background Data The detection monitoring program for the C&D landfill unit, will include the comparison of the reported constituent concentrations from downgradient compliance monitoring wells and the groundwater protection standards [i.e., NC 2L Standards and Interim Maximum Allowable Concentrations (IMACs)]. If inorganic constituents are determined to be above the groundwater protection standards, the reported constituent concentrations from downgradient compliance monitoring wells will be statistically compared to the site -specific background values to determine if a release has occurred. If a constituent is detected above both its groundwater quality standard and its background value, the following procedures will be followed: 1) Within 30 days, submit an Assessment Monitoring Work Plan to the SWS for review. 2) Upon the SWS's approval of the Assessment Monitoring Work Plan, initiate assessment monitoring. The data may be evaluated within ninety (90) days following the exceedance, and wells may be resampled if appropriate, to determine if the concentration resulted from an error in sampling, analysis, statistical evaluation, or natural variation in groundwater quality; or a source other than the facility. If it can be demonstrated that one of these factors occurred, a report [an Alternate Source Demonstration (ASD)] certified by a licensed geologist will be submitted to the SWS within 90 days of identifying the suspect statistical increase. A copy of this report will be placed in the operating record. If the SWS approves the demonstration, the Detection Monitoring Program will be resumed with the required semi-annual sampling and analysis. If SWS does not accept the demonstration assessment monitoring will be initiated. 3.1.2 Assessment Monitoring Assessment monitoring is required for the C&D landfill unit whenever one or more Appendix I constituents are detected at concentrations that exceed the groundwater protection standards, and no source of error or naturally GOLDER December2019 1895531 occurring condition can be identified. If a false positive result cannot be demonstrated, an assessment monitoring program will be established, as described below. After triggering the assessment monitoring water quality monitoring will be performed in accordance with the approved Assessment Monitoring Work Plan, which will include at a minimum one sampling event where monitoring wells are sampled for Appendix II constituents. A minimum of one groundwater sample will be collected from each downgradient groundwater monitoring well and submitted for analysis during each assessment monitoring sampling event. However, the NCSWMR allow for petitions to the SWS for an appropriate subset of wells or a reduction in the Appendix II sampling list. If any Appendix II constituents are detected in groundwater from the downgradient wells, a minimum of four (4) independent samples will be collected from each background and downgradient groundwater monitoring well to establish background concentrations for the detected Appendix II constituents. After approval of the Assessment monitoring work plan and completion of an initial complete Appendix II sampling event, and on at least a semi-annual basis thereafter, the wells will be sampled and analyzed for the Appendix list plus any additional detected Appendix II constituents. An analytical results report of each sampling event will be submitted to the SWS and placed in the facility operational record. The SWS will determine whether groundwater protection standards must be established for the facility and may specify a more appropriate alternate sampling frequency for repeated sampling and analysis for the full set of Appendix II constituents. Groundwater monitoring will continue in one of two ways, based on the results of the assessment monitoring statistical analyses: 1) If the Appendix II constituents are at or less than background values using approved statistical procedures for two consecutive sampling events, the facility may resume detection monitoring with the approval of SWS. 2) If one or more Appendix II constituents are detected at statistically significant concentrations in excess of the approved groundwater protection standards, and no source of error can be identified, a notice will be placed in the operating record, and all appropriate local government officials will be notified. The facility will proceed to a characterization of the nature and extent of the release. If the facility proceeds to corrective action, an Assessment of Corrective Measures will be submitted to the SWS and a remedy will be selected. 3.1.3 Evaluation and Reporting of Monitoring Data Reports will be submitted electronically with analytical data provided in the required format, and be accompanied by the required Environmental Monitoring Form, which will be signed and sealed by a licensed geologist in the State of North Carolina. A copy of this form is also included in Appendix B. The reported constituent concentrations from downgradient compliance wells will be compared to background values, NC 2L Drinking Water Standards and the IMAC Standards, using a value -to -value comparison. Any exceedances of the NC 2L Drinking Water Standards and/or IMAC Standards will be identified in the semi-annual submittals to the SWS. 3.2 Closed MSW Landfill The closed MSW landfill located upgradient of the active C&D landfill is currently performing corrective action in accordance with the North Carolina Solid Waste .0500 Groundwater Corrective Action Application and associated Groundwater Corrective Action Milestone Schedule (Golder 2018) which was submitted to NC DEQ on January 4 GOLDER December2019 1895531 31, 2018. In accordance with the Groundwater Corrective Action Milestone Schedule, a methane cut-off trench was installed to the south of replacement monitoring well MW-15R in November 2018. In addition, the County has continued MNA monitoring at the closed landfill and plans to submit an assessment of this remedy prior to January 31, 2020 in accordance with the proposed schedule. 3.2.1 Corrective Action The County proposes to continue MNA monitoring at the closed landfill in accordance with Table 3. Should another remedy be deemed necessary MNA monitoring will continue as prescribed in Table 3 to evaluate the remedy until NC DEQ approves an alternate sampling plan or following two consecutive groundwater monitoring events in which there are no groundwater standard exceedances in groundwater samples at the site. 3.2.1.1 Sampling Frequency Based on proximity to the source and the existence of significant historical data and locations of the wells with respect to the waste unit, with other compliance monitoring wells in closer proximity to the waste unit, the County would like to propose to identify groundwater monitoring wells MW-1, MW-2, and MW-3 as assessment monitoring wells and monitor them on an annual basis. In addition, the County would also request that the private water supply well located on the Blake property be monitored annually as well as no impacts from the landfill have been noted in this well and its location is upgradient with respect to the waste unit; this well is at a residence that has been unoccupied for many years and the well does not appear to be in use The other groundwater monitoring wells identified on Table 1 associated with the closed MSW landfill shall be monitored semiannually in accordance with Table 3. As presented on Table 3 and as previously approved by NC DEQ in a letter dated April 18, 2008, volatile fatty acids (VFAs) and dissolved hydrogen will continue to be monitored every 51' year and incorporated into a Corrective Action Evaluation Report (the next report will follow the sampling performed in 2021; therefore, VFAs and hydrogen will be collected next in 2021). 3.2.1.2 Evaluation of Data The results from the semiannual and annual monitoring will continue to be evaluated via the use of direct comparison to the applicable groundwater standards, statistics, and/or analytical modelling (e.g., Biochlor) following the completion of each sampling event. 3.2.2 Evaluation and Reporting of Monitoring Data Reports will be submitted electronically with analytical data provided in the required format, and be accompanied by the required Environmental Monitoring Form, which will be signed and sealed by a licensed geologist in the State of North Carolina. A copy of this form is also included in Appendix B. The reported constituent concentrations from downgradient compliance wells will be compared to background values, NC 2L Drinking Water Standards and the IMAC Standards, using a value -to -value comparison. Any exceedances of the NC 2L Drinking Water Standards and/or IMAC Standards will be identified in the semi-annual submittals to the SWS. &+.V GROUNDWATER SAMPLING METHODOLOGY As presented, groundwater samples will be collected in accordance with NCSWMR 15A NCAC 13B .0544 or .0545, this Water Quality Monitoring Plan, and guidance provided in the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling (Appendix C). Procedures for well purging, sample withdrawal, decontamination methods, and chain -of -custody procedures are outlined below. Field parameter measurements 4 GOLDER December2019 1895531 will be submitted electronically to the SWS in a format consistent with the Electronic Data Deliverable (EDD) Template (last updated by NC DEQ in May 2018). 4.1 Sample Collection The procedures for collecting groundwater samples are presented below. The background well for the C&D and MSW landfill unit (MW-5) will be sampled first, followed by the background monitoring well for the C&D landfill unit (MW-14), and then the downgradient compliance monitoring wells. The downgradient groundwater monitoring wells will be sampled so that the most contaminated well, if one is identified from the previous sampling event, will be sampled last. 4.1.1 Static Water Elevations The static groundwater level shall be measured with an electronic water level indicator, to the nearest 0.01 foot, in each well prior to sampling. Static groundwater elevations will be calculated from groundwater depth measurements and top of casing elevations. A reference point will be marked on the top of casing of each well to ensure the same measuring point is used each time static groundwater levels are measured. If a monitoring well contains a dedicated pump, the depth to water shall be measured without removing the pump. Depth -to -bottom measurements should be taken from the well construction data and updated when pumps are removed for maintenance. 4.1.2 Well Evacuation Currently, groundwater is purged via the use of a peristaltic pump or a submersible portable bladder pump, if necessary due to limitations of a non -submersible pump. The preferred well evacuation and sampling procedure for the site is a low -flow purge (micro -purge) and sample methodology and procedure. Standard evacuation and sample methodology and procedures are also outlined below based on the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling (Appendix C), as an alternative. 4.1.2.1 Low -Flow Procedures Groundwater monitoring wells may be purged and sampled using the low -flow sampling method in accordance with the Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling (NCDENR, 2008). A summary of these procedures is presented below, and, as presented, a copy of the procedures is presented in Appendix C. Prior to sampling, a depth -to -water measurement shall be obtained using an electronic water level indicator capable of recording the depth to an accuracy of one -hundredth (0.01) of a foot. Next, a determination of whether or not the water table is located within the screened interval of the well shall be made. If the water table is not within the screened interval, the amount of drawdown that can be achieved before the screen is intersected will be calculated and the amount of drawdown should be minimized to prevent the screen from being exposed. If possible, the water level should not fall to within one (1) foot of the top of the well screen. If the water table is within the screened interval, total drawdown should not exceed one (1) foot, whenever possible, so as to minimize the amount of aeration and turbidity. Because the purging equipment is non -dedicated, the equipment (i.e., tubing or bladder pump and tubing) will be lowered into the well, taking care to minimize the disturbance to the water column. If conditions (i.e., water column height and well yield) allow, the pump or tubing will be placed in the uppermost portion of the water column (minimum of 18 inches of pump submergence is recommended when using a portable bladder pump). 4 GOLDER December2019 1895531 The minimum volume/time period for obtaining independent Water Quality Parameter Measurements (WQPM) will be determined. The minimum volume/time period is determined based on the stabilized flow rate and the amount of volume in the pump and the discharge tubing (alternatively, the volume of the flow cell can be used, provided it is greater than the volume of the pump and discharge tubing). If used, the volume of the bladder pump should be obtained from the manufacturer. Volume of the discharge tubing is as follows: 3/8-inch inside diameter tubing: 20 milliliters per foot 1/4-inch inside diameter tubing: 10 milliliters per foot 3/16-inch inside diameter tubing: 5 milliliters per foot Once the volume of the flow -cell or the pump and the discharge tubing has been calculated, the monitoring well purge can begin. The flow rate should be based on historical data for each specific monitoring well (if available) and should not exceed 500 milliliters per minute. After the flow cell is filled, an initial round of water quality parameters shall be recorded, and the flow rate adjusted until drawdown in the well stabilizes. Depth to water measurements should be measured periodically to maintain a stabilized water level. If the purge rate has been reduced to 100 milliliters or less and the head level in the well continues to decline, the required water samples should be collected following stabilization of the water quality monitoring parameters, based on the criteria presented below. If after the flow rate has been reduced to 100 milliliters or less and neither the head level nor the water quality parameters stabilize, a passive sample should be collected. Passive sampling is defined as sampling before water quality monitoring parameters have stabilized if the well yield is low enough that the monitoring well will purge dry at the lowest possible purge rate (generally 100 milliliters per minute or less). Golder proposes to use the following as water quality monitoring parameter stabilization criteria for this site once achieved for three consecutive measurements: pH (+/- 0.1 S.U.), conductance (+/- 5% of reading), temperature (+/- 0.2°C), and dissolved oxygen [+/- 10% of reading or 0.2 mg/L (whichever is greater)]. Oxidation reduction potential will be measured and ideally should also fall within +/- 10 mV of reading; however, this is not a required parameter. At a minimum, turbidity measurements should also be recorded at the beginning of purging and following the stabilization of the water quality monitoring parameters prior to sampling. The optimal turbidity range for micro -purging is 10 Nephelometric Turbidity Units (NTUs) or less. Turbidity measurements above 10 NTUs are generally indicative of an excessive purge rate or natural conditions related to excessive fines in the aquifer matrix. If stabilization does not occur following the removal of a purge volume equal to three well volumes, a passive sample will be collected. The direct -reading equipment used at each monitoring well will be calibrated in the field according to the manufacturer's specifications prior to each day's use and checked at a minimum at the end of each sampling day. Calibration information should be documented in the instrument's calibration logbook and the field book. Each well is to be sampled immediately following stabilization of the water quality monitoring parameters. The sampling flow rate must be maintained at a rate that is less than or equal to the purging rate. For volatile organic compounds, lower sampling rates (100 - 200 milliliters/minute) should be used. Final field parameter readings should be recorded prior to sampling. GOLDER December 2019 1895531 4.1.2.2 Standard Evacuation Procedures As presented low -flow is the preferred procedure for sampling groundwater at the site; however, if a situation arises in which a representative groundwater sample cannot be obtained using low -flow procedure, the monitoring well may be evacuated with peristaltic pump, a submersible pump, or a disposal bailer (if a situation prevents the use of a pump). If the pump is used to evacuate multiple wells, it and any other non -dedicated equipment will be decontaminated before use and between use at each well. When utilizing standard evacuation procedures on a low -yield well (one that yields less than 0.5 gallon per minute), the monitoring well will be purged so that water is removed from the bottom of the screened interval. Low -yield wells will be evacuated to dryness once. However, at no time will a well be evacuated to dryness if the recharge rate causes the formation water to vigorously cascade down the sides of the screen and cause an accelerated loss of volatiles. Upon recharging of the well and no longer than 24 hours from completing the purge, the first sample will be field-tested for pH, temperature, specific conductivity, and turbidity. Samples will then be collected and containerized in the order of the volatilization sensitivity of the target constituents. When utilizing standard evacuation procedures on a high -yield well (one that yields 0.5 gallon per minute or more), the monitoring well will be purged so that water is drawn down from above the screen in the uppermost part of the water column to ensure that fresh water from the formation will move upward in the screen. If a pump is used for purging, a high -yield well should be purged at less than 4 gallons per minute to prevent further well development. Standard evacuation procedure requires that a minimum of three casing volumes be evacuated from each well prior to sampling. An alternative purge shall be considered complete if the monitoring well goes dry before removing the calculated minimum purge volume. The well casing volume for a 2-inch well will be calculated using the following formula: Vc (gallons) = 0.163 x hwc where: Vc = volume of the casing (in cubic feet) = n x rz x hwc; r = radius of the casing (in feet) = 0.083; hwc = height of the water column (i.e., monitoring well depth minus the measured depth to water); Vc (gallons) = Vc (in cubic feet) x 7.48 (gallons per cubic feet). If disposable bailers are utilized for standard evacuation procedures, the bailers shall be equipped with a check valve and bottom -emptying device. The disposable bailer will be lowered gently into the monitoring well to minimize the possibility of degassing the water. When using standard evacuation procedures, precautions to minimize turbidity in the samples will be taken (e.g., collecting samples most likely to be influenced by turbidity such as metals first). As with low -flow sampling procedure, the direct -reading equipment used at each monitoring well will be calibrated in the field according to the manufacturer's specifications prior to each day's use. Calibration information will be documented in the instrument's calibration logbook and/or the field book. 4.1.2.3 Collection Unless otherwise specified, samples will be collected and containerized in the order described below: ■ Volatile Organic Compounds (SW- 846 Method 8260) �i GOLDER 10 December2019 1895531 Semi -Volatile Organic Compounds (SW- 846 Method 8270) Herbicides (SW-846 Method 8151) Pesticides (SW- 846 Method 8080) Polychlorinated Biphenyls (PCBs; SW-846 Method 8082) Cyanide and Sulfide Total Metals Field and General Chemistry Parameters (as applicable) Whenever possible, samples will be transferred directly from field sampling equipment into pre -preserved, laboratory -supplied containers. 4.1.2.4 Decontamination Non -dedicated field equipment that is used for purging or sample collection shall be cleaned with a phosphate - free detergent (e.g., AlconoxTM), and triple -rinsed with distilled water. Any disposable tubing used with non - dedicated pumps should be discarded after use at each well. Clean, chemical -resistant nitrile gloves will be worn by sampling personnel during monitoring well evacuation and sample collection. Measures will be taken to prevent surface soils, which could introduce contaminants into the monitoring well during sampling, from coming in contact with the purging and sampling equipment. 4.2 Sample Preservation and Handling Upon containerizing groundwater samples, the samples will be packed into pre -chilled, ice -filled coolers and either hand -delivered or shipped overnight by a commercial carrier to a NC certified laboratory for analysis. Sample preservation methods will be used to retard biological action and hydrolysis, as well as to reduce sorption effects. These methods will include chemical preservation, cooling/refrigeration at 4° C, and protection from light. 4.3 Chain -of -Custody Program The chain -of -custody program will allow for tracing sample possession and handling from the time of field collection through laboratory analysis. The chain -of -custody program includes sample labels, sample seal, field logbook, and chain -of -custody record. 4.3.1 Sample Labels Legible labels sufficiently durable to remain legible when wet will contain the following information: ■ Site and sample identification number ■ Monitoring well number or other location ■ Date and time of collection ■ Name (or initials) of collector — Parameters to be analyzed Preservative, if applicable 4 GOLDER 11 December 2019 1895531 Sample Seal The shipping container will be sealed to ensure that the samples have not been disturbed during transport to the laboratory. Sample seals should be labeled with instructions to notify the shipper if the seal is broken prior to receipt at the laboratory. 4.3.3 Field Logbook The field logbook will contain sheets documenting the following information: Identification of the well Well depth Field meter calibration information ■ Static water level depth and measurement technique ■ Purge volume (given in gallons) ■ Time well was purged ■ Date and time of collection ■ Well sampling sequence Types of sample containers used and sample identification numbers Preservative used ■ Field analysis data and methods ■ Field observations on sampling event ■ Name of collector(s) ■ Climatic conditions including air temperatures and precipitation 4.3.4 Chain -of -Custody Record The chain -of -custody record is required for tracing sample possession from time of collection to time of receipt at the laboratory. A chain -of -custody record will accompany each individual shipment. The record will contain the following information: Sample destination and transporter Sample identification numbers Signature of collector Date and time of collection Sample type Identification of well GOLDER 12 December2019 Number of sample containers in shipping container Parameters requested for analysis Signature of person(s) involved in the chain of possession Inclusive dates of possession Internal temperature of shipping container upon opening in laboratory (noted by the laboratory) 1895531 A copy of the completed chain -of -custody form shall accompany the shipment and will be returned to the shipper after the shipping container reaches its destination. The chain -of -custody record will also be used as the analysis request or work order. 4.4 Analytical Procedures A laboratory certified by the NC DEQ will be utilized for analysis of the groundwater and surface water samples. Analyses will be performed in accordance with US EPA SW-846 methods in accordance with the US EPA guidance document (USEPA, 1997). The monitoring parameters are listed in Table 3, along with the proposed analytical methods. Alternate SW 846 methods may be used if they have the same or lower reporting limit. The laboratory should report to the method detection levels (MDLs) and should report at or below established groundwater and surface water standards, where applicable. The laboratory certificates -of -analyses shall, at a minimum, include the following information: • Narrative: Must include a brief description of the sample group (number and type of samples, field and associated lab sample identification numbers, preparation and analytical methods used). The data reviewer shall also include a statement that all holding times and Quality Control (QC) criteria were met, samples were received intact and properly preserved, with a brief discussion of any deviations potentially affecting data usability. This includes, but is not limited to, test method deviation(s), holding time violations, out -of -control incidents occurring during the processing of QC or field samples and corrective actions taken, and repeated analyses and reasons for the re -analyses (including, for example, contamination, failing surrogate recoveries, matrix effects, or dilutions). The narrative shall be signed by the laboratory director or authorized laboratory representative, signifying that all statements are true to the best of the reviewer's knowledge, and that the data meet the data quality objectives as described in this plan (except as noted). One narrative is required for each sample group. • Original Chain -of- Custody Form. • Target Analyte List (TAL)/Target Compound List (TCL): The laboratory shall list all compounds for which the samples were analyzed. The TAL/TCL is typically included as part of the analytical reporting forms. • Dilution factors with a narrative of the sample results, including the reasons for the dilution (if any). • Blank Data: For organic analyses, the laboratory shall report the results of any method blanks, reagent blanks, trip blanks, field blanks, and any other blanks associated with the sample group. For inorganic analyses, the laboratory shall provide the results of any preparation or initial calibration blanks associated with the sample group. • QC Summary: The laboratory will provide summary forms detailing laboratory QC sample results, which include individual recoveries and relative percent differences (if appropriate) for the following Quality Assurance (QA)/QC criteria: surrogates, MS analyses, MSD analyses, LCS, and sample duplicate GOLDER 13 December2019 1895531 analyses. QC control limits shall also be reported; if any QC limits are exceeded, a flag or footnote shall be placed to indicate the affected samples. • Additional QA data and/or other pertinent data may be reported as requested by the owner/operator of the facility. 4.5 Quality Assurance and Quality Control Program A field blank may be collected and analyzed during each monitoring event to verify that the sample collection and handling process has not affected the quality of the samples. The field blank will be prepared in the field and exposed to the sampling environment. As with all other samples, the time of the blank exposure will be recorded so that the sampling sequence is documented. The field blank will be analyzed for the same list of constituents as the groundwater samples. The assessment of blank analysis results will be in general accordance with US EPA guidance documents (US EPA 1993 and 1994). No positive sample results will be relied upon unless the concentration of the compound in the sample exceeds ten (10) times the amount in any blank for common laboratory contaminants, or five (5) times the amount for other compounds. If necessary, re -sampling will be performed as necessary to confirm or refute suspect data; such re -sampling will occur within the individual compliance monitoring period. Concentrations of any contaminants found in the blanks will be used to qualify the groundwater data. Any compound detected in the sample, which was also detected in any associated blank, will be qualified "B" when the sample concentration is less than five times the blank concentration. For common laboratory contaminants, the results will be qualified "B" when the reported sample concentration is less than ten times the blank concentration. The "B" qualifier designates that the reported detection is considered to represent cross -contamination and that the reported constituent is not considered to be present in the sample at the reported concentration. 5.0 STATISTICAL METHODS Statistical analysis of groundwater monitoring data is not required by regulation for landfill compliance. However, it is allowed by regulation for the purposes of determining naturally occurring (i.e., background) concentrations of constituents. If utilized, statistical evaluation of groundwater monitoring data will be performed in compliance with industry standards including the US EPA's Unified Guidance Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities (March 2009), Interim Final Guidance (April 1989), and the Addendum to Interim Final Guidance (July 1992). 6.0 SURFACE WATER MONITORING (RULE .0602) In accordance with Rule .0602 of the NCSWMR, surface water monitoring locations have been established to monitor surface water quality at the facility. There are no proposed changes to the current surface water monitoring network associated with this permit amendment. Four surface water locations (SW 1 through SW-4) will be monitored at the facility. The locations of proposed monitoring locations are shown on Drawing WQMP-1. The upstream surface water monitoring point for both the MSW and C&D units (SW-2) which is located along Horse Creek. Currently, no downstream surface water monitoring location is accessible on the landfill property or via public access; therefore, several tributaries of Horse Creek are monitored instead. An additional upstream monitoring location (i.e., upstream of the active C&D landfill) is located along a tributary of Horse Creek near the southern property boundary and is known as SW-1. Downstream monitoring points SW-3 and SW-4 are downstream monitoring locations along unnamed tributaries to Horse Creek. Samples from SW-3 and SW-4 are 4 GOLDER 14 December2019 1895531 collected at the property boundary where the unnamed tributaries exit the site as they flow toward Horse Creek. Samples shall be collected at each of these locations only if flowing water is observed during the sampling event. As presented in Table 1, the surface water monitoring locations monitored include: SW-1 Upstream (Second Creek) MSW/C&D SW-2 Upstream (Second Creek) MSW/C&D SW-3 Downstream (Unnamed Tributary) MSW/C&D SW-4 Downstream (Unnamed Tributary) MSW/C&D These surface water monitoring points will be sampled semi-annually for analysis of Appendix I constituents, and pH, specific conductivity, and temperature. The results of the analysis of the surface water data will be submitted to the SWS at least semi-annually in conjunction with the groundwater data. Data will be compared to applicable NC surface water standards, and those comparisons will be included with each submittal. 7.0 REFERENCES HDR Engineering, Inc. of the Carolinas (HDR), Assessment of Corrective Measures Report, Moore County Landfill, NC SWP# 63-01, Submitted to NC DENR: July 29, 2005. North Carolina Department of Environmental Quality (NC DEQ), Solid Waste Section (SWS), Guidelines for Groundwater, Soil, and Surface Water Sampling, April 2008. North Carolina Geologic Survey (NCGS), Geologic Map of North Carolina, 1985. Sohl, Norman F. and Owens, James P., Cretaceous Stratigraphy of the Carolinas Coastal Plain, The Geology of the Carolinas, pages 191-220, 1991. 4 GOLDER 15 December 2019 Signature Page Sincerely, Golder Associates NC, Inc. Benj min S. Draper, PG, PMP Senior Project Geologist BSD/RPK/bsd: q& Rachel P. Kirkman, PG Associate and Senior Consultant Golder and the G logo are trademarks of Golder Associates Corporation g:\projects\moore county\_current engineering\2018 permit amendment (env)\monitoring plans%water quality monitoring plan\finaR63-01_20191210 wqm plan.docx 1895531 GOLDER 16 TABLES December 2019 Project No. 1895531 TABLE 1 Summary of Proposed Changes to the Groundwater Monitoring Network Permit Amendment (Lateral Expansion - Cell 6) - Design Hydrogeologic Report - Water Quality Monitoring Plan Moore County Landfill, NC SWP No. 63-01 Moore County, North Carolina Quality�Wcurrent Water liffl-c—Urrent Status IF Background :D Montoring Well 'EMSW Monitoring Well MW-1 Active X MNA Monitoring Well X MW-2 Active X X MW-3 Active X X MW-4 Active X X X MW-5 Active X X X X MW-6 Active X X MW-7 Active X X MW-8 Active X X MW-9 Active X X MW-11 S Inactive' M W-11 SR Active X X X MW-11 D Inactive' MW-11 DR Active X MW-13S Active X MW-13D Active X MW-14 Active X X MW-15 Inactive MW-15R Active X X MW-16S Active X X MW-16D Active X MW-17S Inactive MW-17D Inactive MW-18 Inactive SW-1 Active X X SW-2 Active X X SW-3 Active X X SW-4 Active X X PW-1 Active X MW-1 Active eMm X6 X6 MW-2 Active X6 X6 MW-3 Active X6 X6 MW-4 Active X X MW-5 Active X X X X MW-6 Active X X MW-7 Active X X MW-8 Active X X MW-9 Active X X MW-11S To Be Decommissioned MW-11 SR Active X X MW-11 D To Be Decommissioned MW-11 DR Active X MW-13S To Be Decommissioned 8 MW-13SR To Be Installed 8 X MW-13D To Be Decommissioned 8 MW-13DR To Be Installed 8 X MW-14 Active XS X MW-15 Inactive MW-15R Active X X MW-16S Decommissioned 3 MW-16D Decommissioned 3 MW-17S Active X MW-17D Active X M W-18 Active X SW-1 Active X X SW-2 Active X X SW-3 Active X X SW-4 Active X X PW-1 Active X' X - Denotes inclusion in column group = Denotes change from current monitoring network 1.) Monitoring wells MW-11 SID were replaced by MW-11 SRIDR on June 1, 2018 and May 31, 2018, respectively. The replacement of these monitoring wells was requested in the Assessment Monitoring Plan submitted by Golder on behalf of Moore County on January 5, 2018. The plan was subsequently approved by NC DEQ in a letter dated January 23, 2018. Monitoring wells MW- 11 S/D are currently monitored for water levels semi-annually. 2.) Monitoring well MW-15 was replaced by MW-15R on May 29, 2018. The replacement was also requested in the Assessment Monitoring Plan submitted on January 5, 2018 and subsequently approved by NC DEQ in a letter dated January 23, 2018. In accordance with the Landfill Gas Remedation Plan, submitted by Golder on behalf of Moore County on January 31, 2018 and subsequently approved by NC DEQ on February 14, 2018, former groundwater monitoring well MW-15 was converted to a methane probe which will be used to assess the effectiveness of the recently installed landfill gas trench system. 3.) Monitoring wells MW-17S, MW-17D, and MW-18 were installed as part of the current design hydrogeologic report. Moore County was granted permission to replace monitoring wells MW- 16S/D with MW-17S/D by NC DEQ on February 22, 2019 due to concerns of the potential to compromise the integrity of these wells from site borrowing activities. Monitoring wells MW-16S/D were last sampled during the April 2019 sampling event and decommissioned on May 17, 2019. 4.) As part of this WQMP, Moore County is requesting to decommission MW-11 S/D as these monitoring wells have been replaced. Existing monitoring well pair MW-11 S/D are located within the proposed waste boundary. There is some concern that these monitoring wells, due to their location in a low lying area could potentially be a pathway for contaminants to reach the water table. Moore County is requesting that MW-11S/D be decommissioned upon approval of this Water Quality Monitoring Plan. 5.) MW-14 is proposed a background well for the C&D landfill only. 6.) The County is proposing to monitor MW-1, MW-2, and MW-3 on a annual basis (during the fall of each year) as these wells are essentially nature and extent wells due to their location at the facility. The monitoring wells upgradient of these wells (i.e., closer the waste unit) will continue to be monitored on a semiannual basis. Continuous semiannual monitoring results are available for these wells dating back to April 2006; however, a few sample results are available which date to March 1990. 7.) The County is proposing to monitor PW-1 (the Blake well adjacent to the closed MSW landfill) on an annual basis as there is significant available historical data. The Blake well PW-1 has been sampled on a semiannual basis since October 1996. Currently, the house is not occupied on a continuous basis. 8.) The County is proposing to decommission monitoring wells MW-13SID and replace them with MW-13SRIDR due to their close proximity to waste, the potential for the monitoring wells to be a pathway to groundwater, and the County's desire to include this area in the current permit ammendment waste disposal area. G 0 L D E R 1of1 December 2019 Project No. 1895531 TABLE 2 Summary of Groundwater Monitoring Well Construction Information Permit Amendment (Lateral Expansion - Cell 6) - Design Hydrogeologic Report - Water Quality Monitoring Plan Moore County Landfill, NC SWP No. 63-01 Moore County, North Carolina Well Identification MW-1 Construction Date 06/05/87 Coordinates Northing 508605.64 Easting 1854636.41 Ground Surface Elevation (ft AMSL) 390.70 Measuring Point Elevation (ft AMSL) 392.87 Total Well D- (feet) 20 Well Depth AMSL) 370.70 (inches) 2 (ft bgs) On 6.97 - 17.07 (ft AMSL) 383.73 - 373.63 Sand A I Groundwater Monitoring Well Active MW-2 06/06/87 508508.07 1853819.73 373.39 375.50 20 353.39 2 7.52 - 17.77 365.87 - 355.62 Sand Groundwater Monitoring Well Active MW-3 06/06/87 508781.79 1852845.34 362.00 363.82 16.5 345.50 2 5.75 - 15.88 356.25 - 346.12 Sand and Silty Clay Groundwater Monitoring Well Active MW-4 06/06/87 509793.80 1853641.22 363.40 366.19 15 348.40 2 4.28 - 14.09 359.12 - 349.31 Sand and Silty Clay Groundwater Monitoring Well Active MW-5 06/06/87 510970.55 1853091.84 384.06 386.61 20 364.06 2 6.96 - 17.21 377.10 - 366.85 Sand and Clayey Sand Groundwater Monitoring Well Active MW-6 03/06/95 510385.96 1853881.79 403.50 405.86 20 383.50 2 5.00 - 20.00 398.50 - 383.50 Sand to Silty Sand Groundwater Monitoring Well Active MW-7 03/06/95 509783.24 1853820.43 399.20 402.01 20 379.20 2 4.00 - 19.00 395.20 - 380.20 Sand, Silt, Silty Sand, Clay Groundwater Monitoring Well Active MW-8 03/06/95 509384.99 1853844.10 395.20 397.85 20 375.20 2 5.00 - 20.00 390.20 - 375.20 Sand, Silt, Silty Sand, Clay Groundwater Monitoring Well Active MW-9 03/06/95 508964.80 1854268.28 403.70 406.06 30 373.70 2 15.00 - 30.00 388.70 - 373.70 Silty Sand Groundwater Monitoring Well Active MW-11S 09/16/96 510361.58 1852939.03 380.36 382.34 20 360.36 2 5.00 - 20.00 375.36 - 360.36 Sand to Silty Sand Groundwater Monitoring Well (Proposed Decommissionin MW-11 D 09/16/96 510342.65 1852938.03 380.03 383.05 40 340.03 2 30.00 - 40.00 350.03 - 340.03 Silty Sand Groundwater Monitoring Well (Proposed Decommissionin MW-11SR 06/01/18 510452.38 1852905.36 383.41 386.13 28 355.41 2 18.00 - 28.00 358.13 - 368.13 Clayey Sand Groundwater Monitoring Well Active MW-11DR 05/31/18 510453.00 1852911.56 383.41 386.36 44 339.41 2 34.00 - 44.00 342.36 - 332.36 Sand Groundwater Monitoring Well Active MW-13S 09/18/96 509580.75 1853131.47 386.35 388.88 20 366.35 2 5.00 - 20.00 381.35-366.35 Sand to Silty Sand Groundwater Monitoring Well (Proposed Replacement & Decommissionin MW-13D 09/18/96 509568.07 1853130.65 385.65 388.04 40 345.65 2 30.00 - 40.00 355.65 - 345.65 Sand to Silty Sand Groundwater Monitoring Well (Proposed Replacement & Decommissionin MW-14 09/16/96 510056.32 1853641.99 397.88 400.58 20 377.88 2 5.00 - 20.00 392.88 - 377.88 Sand to Silty Sand Groundwater Monitoring Well Active MW-15R 05/29/18 510589.03 1854391.51 428.81 431.48 47 381.81 2 37.00 - 47.00 384.48 - 374.48 Sand Groundwater Monitoring Well Active MW-16S 04/17/03 509789.42 1852386.76 384.00 386.00 24 360.00 2 14.00 - 24.00 370.00 - 360.00 Sand to Silty Sand Decommissioned MW-16D 04/17/03 509778.32 1852396.77 384.10 386.10 44 340.10 2 34.00 - 44.00 350.00-340.00 Clay Decommissioned MW-17S 06/04/18 509704.03 1852096.70 371.45 374.16 18.0 353.45 2 8.00 - 18.00 363.45 - 353.45 Sand Groundwater Monitoring Well Active MW-17D 06/01/18 509693.71 1852101.52 372.05 374.56 34.0 338.05 2 29.00 - 34.00 343.05 - 338.05 Clay/Sandy-Clay Groundwater Monitoring Well Active MW-18 06/04/18 509369.85 1852249.28 365.35 368.50 13 352.35 2 5.00 - 13.00 360.35 - 352.35 Gravel, Sand, Clay Groundwater Monitoring Well (Proposed) Notes: 1.) ft AMSL = feet above mean sea level 2.) ft BGS = feet below ground surface 3.) Well construction information for monitoring wells MW-1 through MW-16S/D collected from boring logs and well construction records from HDR Engineering, Inc. of the Carolinas July 2006 Water Quality Monitoring Plan. TOC and Ground Elevations are taken from the July 2005 Assessment of Corrective Measures Report and/or well records where available. GOLDER Page 1 of 1 December 2019 Project No. 1895531 TABLE 3 Summary of Proposed Constituents and Analytical Methods Permit Amendment (Lateral Expansion - Cell 6) - Design Hydrogeologic Report - Water Quality Monitoring Plan Moore County Landfill, NC SWP No. 63-01 Moore County, North Carolina Backgroygi� M4M Fw-4 MW-11SR MW-11DR C&D Monitoring MW-13SR Well MW-13DR Network MW-14 1W MW-17S MW-17D MW-18 -'-I MW-3 MSW Monitoring MW-6 Well Network MW-7 MW-8 MW-9 MW-15R Surface Water Monitoring Network SW-4 Private Well Parameters Methods y ����������aaaaaaaaaaaaa z -Nitrate/Nitrite a - rr . .. • Volatile Fatty AcidS2 Not Applicable 4 7 ' aaaaaaaaaaaaaaaaaaaaaaa E aaaaaaaaaaaaaaaaaaaaaaa a - .- . - - - - = aaaaaaaaaaaaaaaaaaaaaaa ... • . aaaaaaaaaaaaaaaaaaaaaaa a .-- - - - - aaaaaaaaaaaaaaaaaaaaaaa s aaaaaaaaaaaaaaaaaa����� 3 = X - Denotes inclusion in column group = Proposed to move these monitoring wells to annual monitoring (in the fall of each year) based on location from source and the existance of significant historical data. 1.) The only recent additional Appendix 11 constituent detected at the C&D monitoring network is Napthalene. Napthalene will continue to be monitored in select monitoring wells annually during the spring event within the C&D monitoring network in accordance with NCAC 13B .0545. 2.) Volatile fatty acids and dissolved hydrogen will continue to be monitored every 5 m year in accodance with a letter received from NC DEQ on April 18, 2008 and incorporated into a Corrective Action Evaluation Report (the next report will follow the sampling performed in 2021; therfore, VFAs and hydrogen will be collected next in 2021. 3.) VOCs = Volatile Organic Compounds 4.) No EPA method number currently exists for the analysis of volatile fatty acids. GOLDER 1of1 December 2019 Project No. 1895531 TABLE 4 Proposed Water Quality Monitoring Schedule Permit Amendment (Lateral Expansion - Cell 6) - Design Hydrogeologic Report - Water Quality Monitoring Plan Moore County Landfill, NC SWP No. 63-01 Moore County, North Carolina MW-5 Site Background X MW-4 Active C&D Landfill; Closed MSW Landfill X MW-11SR Active C&D Landfill; Closed MSW Landfill X MW-11DR Active C&D Landfill X MW-13SR Active C&D Landfill X MW-13DR Active C&D Landfill X MW-14 Active C&D Landfill X MW-17S Active C&D Landfill X MW-17D Active C&D Landfill X MW-18 Active C&D Landfill X MW-1 Closed MSW Landfill X MW-2 Closed MSW Landfill X MW-3 Closed MSW Landfill X MW-6 Closed MSW Landfill X MW-7 Closed MSW Landfill X MW-8 Closed MSW Landfill X MW-9 Closed MSW Landfill X MW-15R Closed MSW Landfill X SW-1 Active C&D Landfill; Closed MSW Landfill X SW-2 Active C&D Landfill; Closed MSW Landfill X SW-3 Active C&D Landfill; Closed MSW Landfill X SW-4 Active C&D Landfill; Closed MSW Landfill X PW-1 Closed MSW Landfill X X - Denotes inclusion in column group 1 of 1 DRAWINGS GROUND OBSCURED SEE ACCURACY NUTF 0.00 �.�..�. SITE LOCATION MAP NOT TO SCALE `�. ❑SW-3� f� u i� BLAKE RESIDENCE (PRIVATE WELL) `POND LEGEND — STREAM, POND, AND WETLAND LIMITS EXISTING 10 FT GROUND SURFACE CONTOUR EXISTING 2 FT GROUND SURFACE CONTOUR PROPERTY LINE APPROXIMATE LIMITS OF WASTE --— — — — — — — EXISTING ROAD OMW-3 MONITORING WELL AND IDENTIFICATION ❑SW-2 SURFACE WATER MONITORING POINT AND IDENTIFICATION BMW-13SR PROPOSED GROUNDWATER MONITORING WELL AND IDENTIFICATION I I NOTES 1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET \ J I 2. PROPERTY BOUNDARY SURVEY BY JAMES L. WRIGHT DATED NOVEMBER 1984. ITS LOCATION IS RELATIVE TO TOPOGRAPHY APPROXIMATE BY HDR ENGINEERING, INC. 3. EXISTING TOPOGRAPHY WITHIN ACTIVE AND PROPOSED LANDFILL PROVIDED BY MATTHEWS - LAND SURVEYING & MAPPING, PLLC DATED APRIL 17, 2015 AND JUNE 2018. 4. MONITORING WELLS MW-6 THROUGH MW-16 SURVEYED APRIL 1995, SEPTEMBER 1996, AND APRIL 2003 BY HDR ENGINEERING INC.I ED BUCKNER RLS APRIL 17, 2015. O I 5. MONITORING WELLS MW-17S/D, MW-18, MW-ti S/DR, MW-15R, PZ-1, PZ-2, AND PZ-3 WERE SURVEYED BY FLEMING ENGINEERING ON JULY 2, 2018. -J SCALEHOUSE i CLIENT MOORE COUNTY PUBLIC WORKS PO BOX 1927 CARTHAGE, NORTH CAROLINA CONSULTANT PE C-2862 YYYY-MM-DD 2019-09-24 PG C-399 PREPARED BSD G O L D E R DESIGN BSD REVIEW RPK COLDER ASSOCIATES NO, INC. APPROVED RPK 0 200 400 1. SCALE FEET o PROJECT o MOORE COUNTY LANDFILL (PERMIT#63-01) 456 TURNING LEAF WAY ABERDEEN, NORTH CAROLINA TITLE — WATER QUALITY MONITORING PLAN - PROJECT No. Rev. DRAWING 1895531 004 0 WQMP-1 APPENDIX A Boring Logs and Well Construction Records RECORD OF BOREHOLE MW-17S SHEET 1of 1 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 509,704.03 DEPTH W.L.: 11.79' PROJECT NUMBER: 1895531 DATE STARTED: 6/4/18 EASTING: 1,852,096.70 ELEVATION W.L.: 362.37 DRILLED DEPTH: 18.00 ft DATE COMPLETED: 6/4/18 GS ELEVATION: 371.45 DATE W.L.: 6/11/18 LOCATION: Aberdeen, INC TOC ELEVATION: 374.16 ft TIME W.L.: 1501 SOIL PROFILE SAMPLES Z U ELEV. z p PIEZOMETER PIEZOMETER w ❑ > DESCRIPTION = c� a p w w c> DIAGRAM and NOTES CONSTRUCTION DETAILS DEPTH W w ❑ a p (ft) 0 0 0.00 - 4.00 3P WELL CASING SAND, organics in upper 3", medium to fine, some clay, tan, moist, g pp y Interval: 0'-8' 370 loose Portland Material: Schedule 40 PVC SP Type I - 3 Diameter:2" Cement Joint Type: Threaded fed in WELL SCREEN 367.45 Interval: 8'-18' Material: Schedule 40 PVC 4.00 - 7.00 4.00 5 CLAY, lean clay with medium to fine sand, white and tan, stiff, 1/4" Bentonite- Diameter: 2 Slot Size:0.010" W-PLand W<PL CL Pellets End Cap: 365 FILTER PACK 364.45 Interval: 6'-18' Type: #2 Filter Sand 7.00 -10.00 7.00 SILTY SAND, some clay, medium to fine, tan, red, and orange, loose to compact, mosit FILTER PACK SEAL SM - Interval:4'-6' Type: 1/4" Bentonite Pellets 10-- 361.45 #2Filter_ ANNULUSSEAL 10.00 - 18.00 10.00 Sand Interval: 0'-4' SAND, some silt, medium to fine, some coarse, tan, grey, white, Type: Portland Type I and some purple, loose, wet Cement 360 WELL COMPLETION Pad: 3'x3'x6" Protective Casing: Steel 0.010" SP Slotted- DRILLING METHODS Screen Soil Drill: 4.25 inch HSA 15 355 353.45 Boring completed at 18.00 ft 20 350 25 345 30 340 35 335 40 LOG SCALE: 1 in = 5 ft GA INSPECTOR: W. Ballow DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: 9/3/19 G O L D E R RECORD OF BOREHOLE MW-17D SHEET 1of 1 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 509,693.71 DEPTH W.L.: 17.22' PROJECT NUMBER: 1895531 DATE STARTED: 6/1/18 EASTING: 1,852,101.52 ELEVATION W.L.: 357.34 DRILLED DEPTH: 34.00 ft DATE COMPLETED: 6/1/18 GS ELEVATION: 372.05 DATE W.L.: 6/11/2018 LOCATION: Aberdeen, NC TOC ELEVATION: 374.56 ft TIME W.L.: 1502 SOIL PROFILE SAMPLES Z U ELEV. O Z w O PIEZOMETER PIEZOMETER is v v a 0 W a BLOWS O DIAGRAM and NOTES CONSTRUCTION ❑ w DESCRIPTION O J per 6 in ; w DETAILS uJ D DEPTH C') 140 lb hammer ZZ 30 inch drop 0 0.00 - 0.30 SP 0.30 - N: WELL CASING SAND with organics 1 a 1-1-2-1 3 1.80 Interval: 0'-29' 0.30 - 2.00 SP cn 2.00 Material: Schedule 40 PVC SAND, medium to fine, tan, noncohesive, -. 370.05 =n Diameter: 2" 370 moist un °'g Joint Type: Threaded 2.00 2.00 - 3.50 SAND, medium to fine, tan, non -cohesive, SP - 368.55 2 2-1-4-6 5 2.00ee 2.00 M. 0 `i'. B° WELL SCREEN moist Interval:29'-34' CLS 368.05 w a Material: Schedule 40 PVC 3.50 - 4.00 q 00 SANDY CLAY, medium sand, tan, cohesive, °aS Diameter: 2 Slot Size: 0.010" 5 moist CLS 3 EL 3-5-7-11 12 2:00 ag 365.55 , e End Cap: 4.00 - 6.00 CLAY, lean claywith medium to fine sand 0 °BeO FILTER PACK CLS 365.55 zones, whtie and tan, stiff clay, compact 2.00_° Interval: 27'-34' 365 sand, moist SP 364.8 4 5-7-9-10 16 2.00 Type: #2 Filter Sand 6.00 - 6.50 SM 364.05 CLAY, lean clay with medium sand, tan, °°3° °g's FILTER PACK SEAL 8 00 cohesive, W-PL SC 39 °° use Interval: 25'-27' 5 a_ 4-4-4-4 8 2:00 - Type: 1/4" Bentonite Pellets 6.50 - 7.25 SAND, medium to fine, tan, non -cohesive, SC 005 10 compact, moist - 362.05 1 1 99 ANNULUS SEAL 7.25 - 8.00 10.00 peo paa Interval: 0'-25' SILTY SAND, medium to fine, red, SM 6 a_ 2-1-1-1 2 2'00 °°r es^ TCe: Port land Type I non -cohesive, compact, moist n 2.00 e ent 360 360.05 Portland ,z a WELL COMPLETION 8.00 - 9.00 CLAYEY SAND, medium to fine, orange, 12.00 non -cohesive, loose, moist SP 7 1-2-2-4 4 2.00 Type I Cement ee oo a as Pad: 3'x3'x6" Protective Casing: Steel 9.00 -10.00 co 2.00 CLAYEY SAND, medium to fine, orange, - 358.05 °^^^ DRILLING METHODS 14.00 non -cohesive, loose, wet Soil Drill: 4.25 inch HSA 10.00 - 12.00 15 SP 8 0_ 3-1-4-4 5 2.00 :i SILTY SAND, medium to fine, tan to grey, rn 2.00 non -cohesive, loose, moist 356.05 12.00 - 14.00 16.00 SAND, coarse to medium, purple to white, 2.00 355 non -cohesive, loose, wet SP 9 3-1-2-2 3 2.00 14.00 - 16.00 354.05 SAND, coarse to medium, tan with purple ae -22 � 18.0092 streaks, non -cohesive, loose, moist SP 353.05 a 2.00 10 n 2-3-4-30 7 2.00 16.00 - 18.00 19.00 SAND, coarse to medium, tan with purple streaks, non -cohesive, loose, moist CL 352.05 20 fig31.9 18.00 - 19.00 20.00 w ,N SAND, coarse to medium, tan with purple CL 11 (L 4-39-50 >50 2 00 streaks, non -cohesive, loose, moist 350.05 350 �„ 19.00 - 20.00 CLAY, fat clay with fine sand, grey to purple, 22.00 cohesive, dry, dense, W<PL CL 12 N 12-22-30-36 >50 2.00 r 20.00 - 22.00 CLAY, fat clay with fine sand, grey to purple, 348.05 kp 24.00 cohesive, dry, dense, W<PL moo 25 CL 0purple, 13 EL 5-12-20-23 32 2.00 22.00 - 24.00 CLAY, fat clay with fine sand, dark grey to 2.00 1/4" cohesive, dense, W<PL 346.05 Bentonite - 24.00 - 26.00 26.00 Pellets 345 CLAY, fat clay with medium sand, light grey, CL 14 d 6-11-19-19 30 2.00 cohesive, stiff, W-PL rn 2.00 344.05 26.00 - 28.00 28.00 CLAY, fat clay with coarse to medium sand, pink to grey, cohesive, stiff, W-PL 2.00 CLS 15 � 5-7-8-10 15 2.00 28.00 - 30.00 SANDY CLAY, medium sand, tan, cohesive, 342.05 #2 Filter 30 firm, W-PL _ Sand 30.00 30.00 - 32.00 2.00 SANDY CLAY, medium sand, tan, cohesive, CLS 16 (L 2-4-7-8 11 2.00 firm, W-PL 340.05 0.010" 340 Screen 32.00 - 34.00 32.00 SANDY CLAY, medium sand, tan, cohesive, 2.00 firm, W-PL CLS 17 3-4-8-8 12 2.00 338.05 34.00 - 36.00 34.00 CLAY, fat clay, grey, cohesive, stiff, W<PL 2.00 35 CL 18 N 12-15-20 27 2.00 336.05 Boring completed at 34.00 ft 36.00 335 40 LOG SCALE: 1 in = 5 ft GA INSPECTOR: D. Reedy DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: 9/3/19 G O L D E R RECORD OF BOREHOLE MW-18 SHEET 1of 1 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 509,369.85 DEPTH W.L.: 7.12' PROJECT NUMBER: 1895531 DATE STARTED: 6/4/18 EASTING: 1,852,249.28 ELEVATION W.L.: 361.38 DRILLED DEPTH: 13.00 ft DATE COMPLETED: 6/4/18 GS ELEVATION: 365.35 DATE W.L.: 6/11/2018 LOCATION: Aberdeen, NC TOC ELEVATION: 368.5 ft TIME W.L.: 1459 SOIL PROFILE SAMPLES Z U ELEV. O Z w O PIEZOMETER PIEZOMETER is v v a 0 W a BLOWS O DIAGRAM and NOTES CONSTRUCTION ❑ w DESCRIPTION O J per 6 in ; w DETAILS uJ D DEPTH CO 1401b hammer ZZ 30 inch drop O 365 0.00 - 2.00 SAND, fine to medium sand, dark brown to H 1 70 - Flortland gee Type I moo WELL CASING Interval: 0'-5' black from U-0.7', tan 0.7'-2', ve loose, d ry ry SP 1 a m 1-2-2-3 4 2.00 Cement Materal:Schedule 40PVC - 363.35 1/4„ Diameter: 2" Bentonite- Pellets Joint Type: Threaded 2.00 - 4.00 2.00 SAND, medium to coarse sand, -60 % 1.80 quartz, tan, light brown, some orange -brown SP 2 a. 2-3-2-5 5 2.00 WELL SCREEN in bottom, uniformly graded, loose, moist 361.35 Interval: 5'-13' Material: Schedule 40 PVC 4.00 - 6.00 4.00 5 SAND, some gravel from 5.5'-13% medium to SP 3 1-2-6-7 8 1.80 Diameter: 2 0.010" 360 coarse sand, brown, tan brown, EL 2.00 End CaSlot p: p: orange -brown, loose, wet 359.35 6.00 - 8.00 6.00 FILTER PACK SAND, trace clay, medium to coarse sand, a 2.00 Interval: T-13' -70% quartz sand, light brown, subangular SP 4 n 5-3-2-3 5 2.00 Type: #2 Filter Sand to subrounded, uniformly graded, loose, wet 357.35 #2 Filter _ Sand FILTER PACK SEAL 8.00 -10.00 d 8.00 GRAVELLY SAND, trace clay, medium to - 2.00 Interval: 1'-2' coarse sand, light brown from 8'-9', light SPG 5 1-1-2-6 3 2.00 Type: 1/4" Bentonite Pellets grey from 9'-10', very loose, wet 355.35 0.010" ANNULUS SEAL 10 355 Slotted - Screen Interval: 0'-1' 10.00 - 12.00 0 10.00 GRAVELLY SAND, some clay1 T-12' , - 2.00 Type: Portland Type I medium to coarse sand, light brown, light SPG � � 6 � 2-1-1/12" 2 2.00 Cement grey, some purple (clay), very loose, wet 353.35 WELL COMPLETION 12.00 - 13.00 12.00 SAND, some gravel, medium to coarse SP 352.35 1.90 Pad: 3'x3'x6" sand, -60 % quartz sand, suban ular to 9 7 a Cn 14-15-16-50 31 1.90 Protective Casing: Steel 13.00 subrounded, light brown, light grey, dense, CLS 351.35 wet DRILLING METHODS 14.00 Soil Drill: 4.25 inch HSA 13.00 - 14.00 15 SANDY CLAY, some silt, light grey mottled 350 orange and purple, hard, dry, W<PL Boring completed at 13.00 it 20 345 25 340 30 335 35 330 40 LOG SCALE: 1 in = 5 ft GA INSPECTOR: W. Ballow DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: 9/3/19 G O L D E R DEPTH FT. 8„0 14.0 15.,0 DESCRIPTION ELEV. PENETRATION -BLOWS PER FT. Loose Pink, Tan Slightly Silty Slightl Clayey Coarse SAND (SP) . 9 2 Very Loose ran, Pink Slightly Silty Coarse SAND (SP) 9 tztt ink, an Medium Sandy7LAY rn Boring Terminated at 15„0 BORING AND SAMPLING MEETS ASTM D-I586 CORE DRILLING MEETS ASTM D-21I3 PENETRATION IS THE NUMBER OF BLOWS OF 140 LB HAMMER. FALLING 30 IN.. REQUIRED TO DRIVE 14 IN I, D SAMPLER I FT. UNDISTURBED SAMPLE — WATER TABLE-24HR j50�% ROCK CORE RECOVERY -!--:—WATER TABLE -I HR. I•1m TEST BORING RECORD MW-4 BORING NO,. DATE DRILLED 6� 6—S7 ,SOB NO. 4112-87-146 SOIL & MATERIAL ENGINEERS, INC., Well Number:MGI-k __ • briiling Hetbod: Auger r Date Started:&-6-87 Drilling Fluids: Hone Date Finished: 6- - Static Water Level: Date: Geologist/Engineer: Hav s Observed By: Remarks' O.,D„ of Borehole: " ALL DEPTHS REFERENCED FROM GROUND SURFACE O.D. of Casing: " _ ''sill Length of Screen- " LOC+CABLE CAP T I - {1 Screen Opening Size:Q.OIO" PROTECTIVE C ELEVATION OF GROUNO SURFACE Portland {TYPE) 2" S chC (SIZE 9 TYPE) B ENTOMTE SAND 2" Sch 40 PVC (StZE 6 TYP IP DtSTA NLE 2.80 0.0 M TO TOP OF BENTOHITE H TO TOP OF GRAVEL, 2.5 H TO TOP OF SCREEN i TN TO BOTTOM OF SC CEN 14.09 l AL DEPTH 15.0 PROJECT SOILS MATERI AL ENGI NEERS, IN C. Moore County Landfill RAL,EI GH, NORTH CAROLINA Moore County, North Caroli I a SCALE", JOB NO: F I G .• NO'.. N.T.S. 4112-87-146 4 J Geologist Log: MW-1 G Project: Moore County Landfill Project No: 07372-2934 Client. Moore County Ground Elevation: 381.0 Location: Moore County Geologist: P. May r SUBSURFACE PROFILEM>E M Description[20 hear Strength Q Remarks o blows/ft 0 co!r 40 60 80 Cleared area used to store mulch, mulch was 0.0s , removed leaving clayey sand surface similar to I 1 1 1 3' - 5'. 2 (Note: data copied from MW-16D log) r —T _ 3 I t I t I SAND 3.0 I I 1 I i I I Light tan to orange clayey, fine to medium 4 1 1 1 I grained, grades to light tan 4 4.5, small 1 8 20" "' —1-- J— —I— — amount of mica throughout, some quartz, quar f E I I I I 5 moist. ! I t I 1 I 6 i 1 I I t I I i 7 I I t I Portland Type 1 8 -8.0 1 I I Cement 1 I r I White, light tan, and tan -orange, clay, fine to T -" 1 medium grained, higher clay associated with 9 I I I tan color, very moist 0 10', some quartz. 2 12 16" t t I 10 4 t I I T 11 I 1 I 1 3/8" Bentonite 1 I 1 I 12 I 1 t Chips 1 I i I 13 -13.0 l Light tan - white, fine to medium grained, ! 1 E I clayey, grades to tan - orange very clayey 14 sand to white, tan, and tan orange, sandy clay, 370 0 3 8 14" - t — 4 _ --I — striated, fine to medium quartz gravel, wet. 15 t I 1 f 1 I I I ifi i t I l t ! ► i I 17 I ! I I 1 1 1 �RDrilled By: Graham & Currie HDR Engineering, Inc. of the Carolinas Hole Size: 8" 128 S. Tryon Street Drill Method: HSA Suite 1400 Top of Casing:86.� Drill Date: 411 7/2003 Charlotte, NC 28202 Sheet: 1 of 2 Geologist Log: MW-16D Project. Moore County Landfill Project No: 07372-2934 Client: Moore County Ground Elevation:��• . Location: Moore County Geologist: P. May SUBSURFACE PROFILE SAMPLE Shear Strength ca Remarks r Description � a 3 u blows/it -- W Z H o Fn N 20 40 60 80 0f -3 -2 Ground Surface + + t t Cleared area used to store mulch, mulch was removed leaving clayey sand surface similar to r 1 3'-V. 2 "l + ! ! I -3.0 + + 1 t 3 SAND l I I ! Ught tan to orange clayey, fine to medium 1 8 20" i _ 1 _ �1_ —1 _ t t I I 4 grained, grades to light tan 0 4.5', small ! ! I + amount of mica throughout, some quartz, + + ! l 5 moist. I + + t I ► I t t— -}--i— 'I- 6 I { ! + E + I I 7 t I + t -8.0 -I-_-i--I--+-- 8 White, light tan, and tan•orange, clay, fine to t + 1 ! t medium grained, higher clay associated with 2 12 16" I I + I + ! l 9 tan color, very moist @ 101, some quartz. I t I I I _ 1- _I - Portland Type I 10 ! t t +- Cement + + + I i t l ii 1 1 f l I i I 1 l 12 + ! l I -13.0 I l t + 13 Light tan - white, fine to medium grained, + l 1 I 1 + + 1 clayey, grades to tan - orange very clayey 3 8 14" t _ -+ _ —1 14 sand to white, tan, and tan orange, sandy clay, F striated, fine to medium quartz gravel, wet. 4 i f I 1 15 I t I I -r_I--1--I—_ 16 I t i I 17M Drilled By: Graham & Currie HDR Engineering, Inc. of the Carolinas Hole Size: e" T128 S. Tryon Street Drill Method: HSA Suite 1400 Top of Casing: Charlotte, NC 28202 Sheet: t of 3 r Drill Date: 4/17/2003 Geologist Log: MW-1 SD Project.- Moore County Landfill Project No: 07372-2934 Client. Moore County Ground Elevation: Location: Moore County Geologist: P. May • SUBSURFACE PROFILE SAMPLE r Description � Shear Strength o Remarks a E > E 3 blows/ft ❑ Uj LEI Z 20 40 60 BO Tan, pink, coarse grained clayey, fine to E medium quartz gravel, lower 5" tight, clayey ! 1 1 I - 38 sand, mottled gray, tan, pink, and white, some mica and quartz throughout. 38.5 _ I _ f I - T " �- -I- - #2 Silica Send 39 Tan, pink, medium to coarse grained, 8" of 8 I ! I f I I 1 Pack mottled gray, tan, sandy clay, quartz and mica 8 ► I f 40 throughout. I 1 f f 41 I 1 r 1 1 ! f I i i f f '- 42 1 1 I I I E t— — I I-- — 43 I f f t 1 1 1 I I End of Borehole 44. � 1 I I 1 45 I t i r 1 I 1 I 46 f I I 1 _1_1--�--L- ! I 1 I 47 I E I 48 f 1 I 1 I I i I i 49 I E t I I f 1 I 1 50 I 1 I t 1 I I --4--4--4--a-- I l ! I 51 I t I I I I I 1 52 ! f I t 1 I I i -t-i--1--1 — 1 I 1 I 53 I ! f I 1 I I t 54 1 E f 1 I f 1 I 1 r i i 55 t I t 1 1 I I I 56 I I 1 I i ! f 1 I 1 f I 57-I— Drilled By: Graham & Currie HDR Engineering, Inc, of the Carolinas Hole Size: 8" i28 S. Tryon Street Drill Method: I-ISA Suite 1400 Top of Casing: �� Charlotte, NC 28202 Drill Date: 4/17/2003 Sheet: 3 of 3 RECORD OF BOREHOLE MW-11 DR SHEET 1 of 2 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 510,453.00 DEPTH W.L.: 15.94' PROJECT NUMBER: 1895531 DATE STARTED: 5/31/18 EASTING: 1,852,911.56 ELEVATION W.L.: 370.42 DRILLED DEPTH: 44.00 ft DATE COMPLETED: 5/31/18 GS ELEVATION: 383.41 DATE W.L.: 6/11/18 LOCATION: Aberdeen, NC TOC ELEVATION: 386.36 ft TIME W.L.: 1435 SOIL PROFILE SAMPLES Z V ELEV. z W a O a MONITORING WELL/ WELL c W" c �" rn x( w w BLOWS J v PIEZOMETER CONSTRUCTION o J DESCRIPTION as O Ja y per 6 in DIAGRAM and NOTES DETAILS uJ o DEPTH H h- < 140lb hammer Z 30 inch drop 0 0.00 - 0.30 Organic layer CL0 WELL CASING 1 (L 2-3-3-4 6 Interval: 0'-34' 0.50 1.80 0.30 - 0.50 SC v) 2.00 Material: Schedule 40 PVC CLAY with medium sand //, 381.41 Diameter: 2" ° 3 Joint Type: Threaded 0.50 - 2.00 2.00 SAND, medium sand, little clay, yellow, ~ 1.70 loose, dry SM 2 (L 2-1-1-6 2 2.00 te' {° WELL SCREEN 380 379.41 Mg m Interval: 34'-44' 2.00 - 4.00 SILTY SAND, medium sand, little fine sand, 2. Material: Schedule 40 PVC 4.00 silt, black, very loose, moist (FIIL) N. Wge ag Diameter: 2 Slot Size: 0.010" 4.00 - 6.00 5 SM 3 (L 2-4-6-8 10 2 00 SILTY SAND, medium sand, little fine sand, - 377.41 . ss rw End Cap: trace coarse sand, silt, black, very loose, FILTER PACK 6.00 moist (FIIL) 0.20 M. Interval: 32'-44' 6.00 - 8.00 FILL 4 7 4 4-6 8, 2.00 N Type: #2 Filter Sand FILL, brick debris 375.41 375 3e °°w =8 °° FILTER PACK SEAL 8.00 -10.00 8.00 - - - SAND FILL, medium, brick debris, black, 1.00 Ise Interval: 30'-32' loose, moist FILL11 5 (L 8-5-4-7 .'9 2.00 -9 Type: 1/4" Bentonite Pellets 10 373.41 ANNULUS SEAL 10.00 - 12.00 10.00 opeo paa Interval: 0'-30' FILL, brick debris 0.20 gr er Type: Portland Type I FILL 6 a 6-5-3-2 8 2.00 % ,a^ Cement 371.41°° >8° WELL COMPLETION 12.00 - 14.00 12.00 SANDY CLAY, fine to medium sand, light 1 00 Leo Pad: 3'x3'x6" grey, soft, W-PL CLS 7 2-2-2-3 4 2.00 >s Protective Casing: Steel 370 369.41 DRILLING METHODS 14.00 - 16.00 14.00 Portland Soil Drill: 4.25 inch HSA 15 SANDY CLAY, fine to medium sand, light 9 CLS 8 2-1/12"-5 1 1.20 Type I - _°< t5 Rock Drill: N/A grey, very soft, W-PL 2.00 Cement woe 3 67.41 16.00 - 18.00 16.00 SAND, medium sand, little to trace silt and 1.50 clay, yellow, saturated SP 9 a � 5-2-3-5 5 2.00 365.41 365 18.00 - 20.00 18.00 An 22 SAND, medium sand, little to trace silt and a 2.00 clay, yellow, saturated SP 10 m 4-5-6-5 11 2.00 Ea 22 20 363.41 308 20.00 - 22.00 20.00 SAND, medium sand, little to trace silt and 2.00 I _= clay, trace coarse sand and clay nodules, SP 11 a Cl) 1-1-3-5 4 2.00 vaee fea yellow, saturated 361.41 22.00 - 24.00 22.00 SAND, medium sand, little to trace silt, trace $' °g coarse sand, pink to brown to light SP 12 m 0-2-3-3 5 0 360 brown/tan, saturatedg41„ k oo ` 24.00 - 26.00 24.00 Roo SAND, medium sand, trace fine and coarse 2.00 25 sand, trace clay and silt, pink to white, SP 13 N 2-4-1-12 5 2.00 compact, saturated 35741 up 'g 26.00 - 28.00 26.00° SAND, medium sand, trace fine and coarse 2.00 sand, trace gravel, trace clay and silt, pink SP 14 m 2-6-9-16 15 2.00 xe, to white, compact, saturated 355.41 355 28.00 - 30.00 - 28.00 ooan >a SAND, medium sand, trace coarse and fine 2.00 ^g's sand, trace silt and clay, pink to light grey, SP 15 EL 2-4-7-15 11 2.00 white, compact, saturated 353.41 30 30.00 - 32.00 30.00 SAND, medium and coarse sand, trace silt 1.00 1/4" and clay, pinkish white to tan, very loose, SP 16 a m 1/12"-34 3 2.00 Bentonite- saturated 351.41 Pellets 32.00 - 34.00 32.00 SAND, medium and coarse sand, trace silt 2.00 and clay, pinkish white to tan, very loose, SP 17 EL2-3-9-10 12 2.00 350 saturated 349.41 34.00 - 36.00 34.00 SAND, medium and coarse sand, trace silt 2.00 35 and clay, trace fine gravel, pinkish white to SP 18 N 3-3-6-11 9 2.00 tan, very loose, saturated 347,41 #2 Filter_ 36.00 - 38.00 36.00 Sand SAND, medium and coarse sand, trace silt 2.00 and clay, trace fine gravel, pinkish white to SP 19 N 3-3-6-11 9 2.00 tan, very loose, saturated 345.41 345 38.00 - 40.00 38.00 SAND, medium sand, trace silt and clay, 2.00 white, loose, saturated SW 20 N 4-2 4-8 6 2.00 343.41 0.010" 40 Loq continued on next page LOG SCALE: 1 in = 5 ft GA INSPECTOR: W. Ballow DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: G O L D E R RECORD OF BOREHOLE MW-11DR SHEET 2of2 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 510,453.00 DEPTH W.L.: 15.94' PROJECT NUMBER: 1895531 DATE STARTED: 5/31/18 EASTING: 1,852,911.56 ELEVATION W.L.: 370.42 DRILLED DEPTH: 44.00 ft DATE COMPLETED: 5/31/18 GS ELEVATION: 383.41 DATE W.L.: 6/11/18 LOCATION: Aberdeen, NC TOC ELEVATION: 386.36 ft TIME W.L.: 1435 SOIL PROFILE SAMPLES Z V ELEV. z W a O a MONITORING WELL/ WELL c W" c �" rn x( w w BLOWS J v PIEZOMETER CONSTRUCTION o J DESCRIPTION as O Ja y per 6 in DIAGRAM and NOTES DETAILS uJ o H DEPTH h- < 140lb hammer Z 30 inch drop 40 40.00 - 42.00 40.00 ° e WELL CASING SAND, fine san, trace medium sand, clay, SW 21 4-2-3-8 5 1 00 Screen Interval: 0'-34' and silt, pink to white, loose, saturated (L 2.00 Material: Schedule 40 PVC 341.41 Diameter: 2" 42.00 - 43.00 42.00 Joint Type: Threaded SAND, fine san, trace medium sand, clay, SW ° 340.41 2.00 340 and siltP , ink to white, loose, saturated 22 0- v) 3-5-6-9 11 2.00 WELL SCREEN SW ° 339.91 43.00 - 43.50 CLS 339.41 Interval: 34' 44' SAND, medium sand, fine gravel, yellow, Material: Schedule 40 PVC compact, saturated Diameter: 2 45 Slot Size: 0.010" 43.50 - 44.00 SANDY CLAY End Cap: Boring completed at 44.00 ft FILTER PACK Interval: 32'-44' Type: #2 Filter Sand FILTER PACK SEAL 335 Interval: 30'-32' Type: 1/4" Bentonite Pellets 50 ANNULUS SEAL Interval: 0'-30' Type: Portland Type I Cement WELL COMPLETION Pad: 3'x3'x6" Protective Casing: Steel 330 DRILLING METHODS Soil Drill: 4.25 inch HSA 55 Rock Drill: N/A 325 60 320 65 315 70 310 75 305 80 LOG SCALE: 1 in = 5 ft GA INSPECTOR: W. Ballow DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: G O L D E R RECORD OF BOREHOLE MW-11 SR SHEET 1 of 1 PROJECT: Moore County DRILL RIG: Deidrich D-50 NORTHING: 510,452.38 DEPTH W.L.: 15.89' PROJECT NUMBER: 1895531 DATE STARTED: 6/1/18 EASTING: 1,852,905.36 ELEVATION W.L.: 370.24 DRILLED DEPTH: 28.00 ft DATE COMPLETED: 6/1/18 GS ELEVATION: 383.41 DATE W.L.: 6/11/2018 LOCATION: Aberdeen, NC TOC ELEVATION: 386.13 ft TIME W.L.: 1450 SOIL PROFILE SAMPLES Z V ELEV. z a O a MONITORING WELL/ WELL w >" rn =� w w v PIEZOMETER CONSTRUCTION o w DESCRIPTION a 0 Ja y w DIAGRAM and NOTES DETAILS w DEPTH (ft)an 0 0.00 - 0.30 Organic material CL WELL CASING 0.50 Interval: 0' 0.30 - 0.50 Material: Schedule 40 PVC CLAY SC Diameter: 2" ° 3 Joint Type: Threaded 0.50 - 3.00 SAND, medium tan 380.41 380 MgtB° WELL SCREEN 3.00 -12.00 3.00 SAND, black, fill, moist, non -cohesive, loose, moist Interval: 18'-28' Material: Schedule 40 PVC Diameter: 2 5 ooa^ a& Slot Size: 0.010" g° rw End Cap: FILTER PACK Portland Sao Inte rval:16'-28' Type I - Type: #2 Filter Sand SC Cement FILTER PACK SEAL 375 Interval:14'-16' Type: 1/4" Bentonite Pellets 10 ggR ANNULUS SEAL opeo paa Interval:0'-14' Se eS3 Type: Portland Type I a° Cement 371.41 )'°^ >f° WELL COMPLETION 12.00 - 13.00 12.00 Silly SAND, grey, non -cohesive, loose, moist SM 376.41 Pad: 3'x3'x6" 370 ,eo pa3 Protective Casing: Steel 13.00 - 14.00 -13,00 CLAY, fat clay with medium sand, grey, cohesive, moist, W-PL CH 369.49. DRILLING METHODS 14.00 -18.00 14.00 1/4 Soil Drill: 4.25 inch HSA 15 CLAY, lean clay with medium sand, red, cohesive, moist, W-PL Bentonite - Rock Drill: N/A Pellets CH 365.41 18.00 - 28.00 18.00 365 CLAYEY SAND, coarse, tan, non -cohesive, wet 20 #2 Filter _ Sand SC 360 25 0.0101, Slotted - Screen 355.41 Boring completed at 28.00-ft 355 30 350 35 345 40 LOG SCALE: 1 in = 5 ft GA INSPECTOR: D. Reedy DRILLING COMPANY: SAEDACCO CHECKED BY: Ben Draper, P.G. DRILLER: Stephan Smith DATE: G O L D E R DEPTH BELOW GROUND SURFACE 1.0 FT 3.0 FT 5.0 FT PROTECTIVE PIPE HEIGHT MONITORING WELL INSTALLATION DIAGRAM 382.34 FT 1.98 FT GROUT MIX: PORTLAND TYPE I CEMENT BENTONITE SEAL: 3/8-INCH SEN70NITE PELLETS IMPERVIOUS ZONE: 3.0 FT THICK PERMEABLE ZONE: 17.0 FT THICK MOORE COUNTY C&D LANDFILL PEIZOMETER NO.: MW-11S BORING NO.: B-115 JOB NO.: 07625-001-018 PREPARED BY: J. ISHAM CHECKED BY: DATE: _ 9/16/96 EL. 380.36 FT. TOP OF GROUND SURFACE PROTECTVE METALOASING 4-INCH SQUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE _ 40 _ ASTM DESIGNATION: ID: _-2 0-ilv_CL _ OD: _ COUPLINGS: __ ?HRADED FT PIPE IN 10_0 FT. LENGTHS PIPE--_L1)- I M. FT PIPE — LL5.O FT SCREEN _ M-5.O 1 _ t0.0 FT TOTAL: 21.98 ------ FT THICKNESS OF UPPER SEAL 2.0 FT LENGTH OF SCREEN 15.0 FT SAN D 17.0 FT FT 20.0 FT BOTTOM OF BORING REMARKS: ALL MEASUREMENTS TO THE NEAREST 0.1 FT. N=_2,999.7523 E=2,914.1607 FDR En&ew nQ Ia. PROJECT: MOORE COUNTY C&D LANDFILL PROJECT NO: 07625-001-018 LOCATION: HIGHWAY 5, ABERDEEN, NC BORING LOG NUMBER I DEPTH I SPT I T I WL I S1 BORING NUMBER: B-1 1 D PAGE: 1 of 1- DATE: 9/ 16/96 DESCRIPTION (USCS) I COMMENTS I 4' SS-1 17 SS v TAN, MEDIUM TO COARSE GRAINED, MEDIUM - DENSE CLAYEY SAND (SC), MOIST, SLIGHTLY 8' PLASTIC, MOTTLED MAROON AND BROWN. SS-2 6 SS TAN, YELLOW TO BROWN, COARSE TO VERY COARSE -GRAINED, LOOSE SAND (SM), WET, MOTTLED, IRON OXIDE STAINING. SS-3 1 6' 20 SS TAN, YELLOW, MAROON, WHITE, MEDIUM -DENSE, COARSE TO VERY COARSE -GRAINED SAND (SM), VERY WET, MOTTLED, IRON OXIDE STAINING. SS-4 21 SS SAME AS ABOVE (SM), MEDIUM TO COARSE - GRAINED, ALTERNATING LENSES OF MAROON, 24' WHITE, YELLOW AND TAN SAND WITH FINES, WET. SS-5 24 SS SAME AS ABOVE (SM), MINOR CLAY STRINGERS 28' (GRAY), WET SS-6 19 SS = WHITE TO TAN, COARSE -GRAINED, MEDIUM -DENSE I - SAND (SM), MOTTLED YELLOW, MAROON AND BROWN, WET, FINES MIXED _- AT SS-7 36' 17 SS NO SAMPLE OBTAINED DUE TO HEAVING SANDS. -� ORILLIIv - 24 H BOREHOLE COMPLETION: 40 FEET BELOW LAND SURFACE 51 - SCREEN SS - SP�IT5Po0N WATER DEPTH: 6.75 FEET BELOW LAND SURFACE DATE: 9/17/96 5� �NENUr . ti ST - SHELBY TUBE T -rfPE DRILLING METHOD: 4 1/4—INCH HOLLOW STEM AUGERS a WL - WATER LEVEL m LOGGED BY: J. ISHAM 0 Q �►� a DEPTH BELOW GROUND SURFACE 0 26.0 FT 28.0 FT 30.0 FT PROTECTIVE PIPE HEIGHT MONITORING WELL INSTALLATION DIAGRAM 383.05 FT 3.02 FT GROUT MIX: PORTLAND TYPE I CEMENT BENTONITE SEAL- 3/8-INCH BENTONITE PELLETS IMPERVIOUS ZONE: 28.0 FT THICK PERMEABLE ZONE: 12.0 FT THICK MOORE COUNTY C&D LANOFILL PEIZOMETER NO.: Mw-11D B0RING NO.: B-1 ID JOB NO.: 07625-001-018 PREPARED BY: J. 15HAM CHECKED BY: DATE: . _.-_. 9/16/96 EL. 380.03 FT. TOP OF GROUND SURFACE PROTECTIVEMEIAL CASING 4-INCH SOUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE __ 40__ ASTM DESIGNATION: -------- ID: _.�9 �iNCH _ OD: ---- COUPLINGS: THREADED FT PIPE IN _ 10.0 FT LENGTHS PIPE------.C1J=3_0Z --M FT PIPE _-_�3��? 0_ 0 ---- FT SCREEN �_10.0__-_-_ FT TOTAL: _43_02 __--__ Fi THICKNESS OF UPPER SEAL 2.0 FT LENGTH OF SCREEN 10.0 FT SAND 12.0 FT FT -- - - - - - - - 40.0 FT - - - - - - - - BOTTOM OF BORING REMARKS: ALL MEASUREMENTS TO THE NEAREST 0.1 FT. fDq N=3 01 1 .4497 E=2,914.0764 MDR Er4roerina kr- W 0 m ct 0 0 DEPTH PROTECTIVE BELOW PIPE HEIGHT - GROUND SURFACE O 1 3.0 FT I•�a" MONITORING WELL INSTALLATION DIAGRAM 388.88 FT 2.53 FT GROUT MIX: PORTLAND TYPE I CEMENT BENTONITE SEAL: 3/8-INCH BENTONITE PELLETS IMPERVIOUS ZONE: 3.0 FT THICK PERMEABLE ZONE: 17.0 FT THICK FT za.oFT �--- MOORE COUNTY C&D LANDFILL I PEIZOMETER NO.: MW-13S BORING NO: B-13S JOB NO: 07625-001-018 PREPARED BY: J. ISHAM _ CHECKED BY: DATE: 9/18/96 _ EL. 386.35 FT, TOP OF GROUND SURFACE PROTECTIVE METAL CASING _4-INCH SQUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE ASTM DESIGNATION: ....... ID:-2�0-1Ii2H _ OD: _ COUPLINGS: THR�Dj.Q___ FT PIPE IN __ D_a __ FT LENGTHS PIPE U _ FT PIPE _._fit Z 5N0 _ FT SCREEN _�5.0� �o_o _ FT TOTAL: __22_53 FT THICKNESS OF UPPER SEAL 2.0 FT LENGTH OF SCREEN 15.0 FT SAN D 17.0 FT -- — — — — — _ I [BOTTOM OF BORING R MARK : ALL MEASUREMENTS TO THE NEAREST 0.1 FT. N=2 218.1284 E=3 106.6545 HOR Enolee k-a rfC c_ J PROJECT: MOORE COUNTY C&D LANDFILL PROJECT NO: 07625-001--018 LOCATION: HIGHWAY 5, ABERDEEN, NC BORING NUMBER: B-13D PAGE: 1 Of 1 BORING LOG DATE: 9/18/96 NUMBER DEPTH SPT T WL SI DESCRIPTION (USCS) COMMENTS 4' TAN, MAROON, WHITE, YELLOW AND BROWN, SS-1 26 SS MEDIUM -DENSE, MEDIUM TO COARSE -GRAINED CLAYEY SAND (SC), MOTTLED, SLIGHTLY MOIST. YELLOW, BROWN AND TAN, MEDIUM -DENSE, 8 SS-2 22 SS ' MEDIUM TO COARSE -GRAINED SAND (SM) WITH FINES, MOTTLED MAROON, IRON OXIDE STAINING, WET YELLOW, TAN, WHITE AND MAROON, MEDIUM -DENSE, SS-3 1 6' 26 SS MEDIUM TO COARSE -GRAINED SAND (SM), FINES MIXED, WET NO SAMPLE RECOVERED DUE TO HEAVING SS-4 24 SS SANDS 2 4' 2 8' 3 2'- v AT 36' DRILLING -1-� 24 HR BOREHOLE COMPLETION: 40 FEET BELOW LAND SURFACE K Y: SI - SCREEN SS - SPUTSPDON TEST-N NU BER" WATER DEPTH: 9 9.3 FEET BELOW LAND SURFACE DATE: 9/19/96 ST - SHELBY TUBE T - TYPE wL - WATER LEVEL DRILLING METHOD: 4 1/4-INCH HOLLOW STEM AUGERS laq � � I LOG�tD BY. J ISHAM DEPTH BELOW GROUND SURFACE 2 6. 0 FT 28.0 FT 30.0 FT F7 an n MONITORING WELL INSTALLATION DIAGRAM PROTECTIVE PIPE HEIGHT 388.04 FT 2.39 FT GROUT MIX: PORTLANO TYPE I CEMENT BENTONITE SEAL: 3/8-INCH BENTONITE PELLETS IMPERVIOUS ZONE: 28.0 FT THICK PERMEABLE ZONE: 12.0 FT THICK MOORE COUNTY C&D LANDFILL PEIZOMETER NO.: Mw-13D BORING NO.: B-13D JOB NO.: 07625-001-018 PREPARED BY: J. ISHAM CHECKED BY: DATE: _. _ 18/96 EL, 385.65 FT. TOP OF GROUND SURFACE PROTECTIVE METAL CASING 4-INCH SQUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE __ 40__ ASTM DESIGNATION: ID: OD:— COUPLINGS: THRFA Q _ �FT PIPE IN _ �_0FT. LENGTHS PIPE — _-1��_39 Fl PIPE .--NL3-) i o.o _ FT SCREEN �1�_ 10.0 FT TOTAL: --- 42.39 -- --- F i i THICKNESS OF UPPER SEAL 2.0 IT LENGTH OF SCREEN 10.0 FT SAND 12.0 FT BOTTOM OF BORING NEAREST D.t FT. N=2 207.4862 REMARK,._ ALL MEASUREMENTS TO THE - - E=3,108.5434 HDR Ercheerin% k,c. due 20 „( DESCRIPTION ELEV. ,♦PENETRATION -BLOWS PER FT,'. 60 80 100 0 10 20 30 40 Medium Dense Tan Slightly Silty Coarse SAND with Gravel (SP) W 13 21 Loose to Medium Dense, Gray, Orange Slightly Silty Clayey Coarse SAND (Sp) 22 Boring Terminates at 20 ft. BORING AND SAMPLING MEETS ASTM D-1566 CORE DRILLING MEETS ASTM D-2113 PENETRATION IS THE NUMBER OF BLOWS OF 140 LB. HAMMER, FALLING 30 3N REQUIRED TO DRIVE 14 IN I D SAMPLER I FT 00 UNDISTURBED SAMPLE = WATER TABLE-24HR 150 % ROCK CORE RECOVERY WATER TABLE-IHR. M TEST BORING RECORD BORING NO, � L --» DATE DRILLED 6-�-87 JOB NO, 4112-87-146 SOIL & MATERIAL ENGINEERS, INC. - drilling Hechod: Well Number: MW= Auger Dace Started: Drilling Fluids: Done Date Finished- 6 ji me, B7 Static Water Level: Date: Geologist/Engineer:Hayes Observed By: Remarks: O,.D.. of Borehole: 6.5" ALL DEPTHS REFERENCED FROM GROUND SURFACE O j} of Casing-.--. 2.375' - �_ Length of Screen: 1 0 . 1 0 ! LOCKABLE CAP 0. 01 �!! Screen Opening Size: PROTECTME C ELEvxTiOm OF GROUND SURFACE E_ortland Cr TPEI 2" Sch 40 PVC {SIZE 6 TYPEi BENTONITE SAND 211 Sch 40 Pl {StZ E a TV? IP OISTANCE 2 • 3 3 0.0 . I H TO TOP OF SENTONITE 3.. 4..5' -K TO TOP OF GRAVEL rH TO TOP OF SCREEN 6.47 r r 'TH TO BOTTOM OF SCREEN 1La7_ 1 rAL DEPTH PROJECT SOIL& MATERIAL ENGINEERS, INC. Moore Co„ Landfill RALEI GH , NORTH CAROLINA Moore County, North Carola a S C ALE: NTS JOB NO;; 4112-87-146 FIG., NO:: DEPTH FT. 0 RE 13.0 20„( DESCRIPTION ELEV. OPENETRATION--BLOWS PER FT. n In 20 30 40 60 60 100 BORING AND SAMPLING MEETS ASTM D-1586 CORE DRILLING MEETS ASTM D-2113 PENETRATION IS THE NUMBER OF BLOWS OF 140 LB HAMMER. FALLING 301N REQUIRED TO DRIVE 14 IN I D SAMPLER i FT. UNDISTURBED SAMPLE WATER TABLE-24HR _= WATER TABLE-1 HR. ROCK CORE RECOVERY - 5.0 TEST BORING RECORD BORING NO KW-2 DATE DRILLEDl=L=8-7 — 4112-87-146 JOB NO. .--�- SOIL & MATERIAL. ENGINEERS, INC. Well Number:, Mw-2 ! 6rfiling. Hethod:Auger _- - Date Started: 6-6-87 _ Drilling Fluids:None n Date Finished: 6-k-EZ Static Water Level: Date: Geologist/Engineer: Haves Observed By: Remarks: ALL DEPTHS REFERENCED FROM GROUND SURFACE LOCKABLE PROTECTIVE C Et.,EVATFOH OF GROUND SURFACE Portland (TYPE) 211 i 40 PVC (SIZE S TYPE] B ENTOH[T£ SAND I 2" Sch 40 PV1 (SIZE % TTPt PROJECT Moore County Landfill Moore County, North Caroli O.,D,. of Borehole: tl O.,D., of Casing: :1C; T , Length of Screen: 30-751 _ Screen Opening Size: 0-nin" rP OISiAHCE 0.0 H TO TOP Of BENTOHITE 1 .35` H TO TOP OF GRAVEL 2.42 M TO TOP OF SCR££N 7.52r A DEPTH TO BOTTOM OF SCREEN 17.77, TOTAL DEPTH 20.0' SOIL 5 MATERIAL ENGINEERS, INC. SCALE:. N.T.s RALEIGH, NORTH CAROLINA JOB NO:4112-87-146 FIG. NO:. DEPTH DESCRIPTION ELEV. *PENETRATION --BLOWS PER FT. FT 0 10 20 30 40 60 80 100 14..0 16..` Medium Dense to Loose Tan Slightly Clayey Coarse SAND (SP) 11 4 i Hard Tan, Pink Medium Sandy Silty CLAY(CL) r Boring 'Terminated at 16..5 ft., BORING AND SAMPLING MEETS ASTM D-1586 CORE DRILLING MEETS ASTM D-2113 cn PENETRATION IS THE NUMBER OF BLOWS OF 140 LB HAMMER, FALLING 30 IN. REQUIRED TO DRIVE 1,4 IN.. I D SAMPLER I FT. UNDISTURBED SAMPLE = WATER TABLE-24HR �5C�°% ROCK CORE RECOVERY WATER TABLE-IHR, 5 TEST BORING RECORD BORING NO. MW-3 DATE DRILLED 4112-87-146 JOB NO. — SOIL & MATERIAL ENGINEERS, INC„ Well Nusber: - 0 $rikfing Method: Auger _ Date Started:-6-6-87 Drilling Fluids: None Date Finished:6-6-87 Static Water. Level: Date: Geologist/Engi.neer:.Rgyps — Observed By: Remarks: - 0,.D, of Borehole: 6•5" ALL DEPTHS REFERENCED FROM GROUND SURFACE 2.375" O.D. of Casing: Length of Screen- 10.13` LOCKABLE CAP Screen Opening Size: nin" _ PROTECTrVE C ELEvaTrON Of GROUND SURFACE Portland (TYPE) 2'1,o�) 40 PI (SIZE S TYPE) B EHroN1TE $AND 2" Sch 40 P (SIZE & TYP' IP DISTANCE 2.25 H TO TOP OF BENTOHITE i - 9 r 'H TO TOP OF GROVEL_ 3.0 r H TO TOP OF SCREEN 5.75 • 1 DEPTH TO BOTTOM OF SCREEN L5 . u — TOTAL OEvrm 16.5 PROJECT SOILS MATERIAL ENGINEERS, INC. SCALE:, N.T.S. Moore County Landfill RAL.EIGH, NORTH CAROLINA JOB NO" 4112-87-146 Moore County, North Caroli a FIG„ NO.. DEPTH FT DESCRIPTION ELM PENETRATION—BL01WS PER 7. n in 20 30 40 60 80 100 4 „0 WIP 14 19..0 20..0 Tan Brown 5jigntiy SAND (SW) 18 Medium Dense Pink Tan Slightly Silty Clayey Coarse SAND (SC) 9 Medium Dense Pink -Tan Slightly Silty Coarse SAND (SP) 12 Medium Dense Tan -Gray Silty, Clayey Coarse to Fine SAND (SC) 6 Medium Dense Tan -Pink Slightly Clayey Q Boring Terminated at 20..0 ft. *Coarse SAND (SP) BORING AND SAMPLING MEETS ASTM D-1586 CORE DRILLING MEETS ASTM 0- 2113 PENETRATION IS 7HE NUMBER OF BLOWS OF 140 LB HAMMER, FALLING 30 IN. REQUIRED TO DRIVE 14 IN I D SAMPLER I FT UNDISTURBED SAMPLE = WATER TABLE-24HR. I501% POCK CORE RECOVERY = WATER TABLE-] HR 9..5 TEST BORING RECORD mw-BORING NO. 6.�- 8 -- DATE DRILLED--- JOB NO, 411-145 SOIL & MATERIAL. ENGINEERS, INC„ • method'.-- Auger Well Number:_ W S - • dri ang Dace Started- 6 R7 Drilling Fluids: None Static tracer Level: Date: Date Finished: f,—R-87 Geologist/Engineer:_Hay.QG Observed By: Remarks: 0„D,, of Borehole: 6.511 ALL OEPTKS REFERENCED FROM GROUND SURFACE D. of Casing'. 2.37511 Length of Screen: J_OCKA8LE CAP I11 0OTt 1Screen Opening Size:.01 L PROTECTIVE C ELEVATION OF GROUND SURFACE Portland (T"ET 2i1 Sch 40 PVC (SIZE a TrpE] BENTO wTE SAND 2" Sch 40 F (SIZE IL TTI �P OISTANCE 2.91I m. 3„40' N To Top OF BENTONITE fN TO TOP OF GRAVEL 5.0� 6.96 TN TO TOP OF SCREEN PTN TO BOTTOu OF SCREEN 17 . 21, i TAL DEPTH 20.0 PROJECT SOILS MATERIAL ENGINEERS, INC Moore County Landfill RALEIGH, NORTH CAROLINA Moore County, North Caroli a S C ALE':. JOB NO:. FIG.. NO N.T.S. 411.2-87-146 f PROJECT: MOORE COUNTY LANDFILL PROJECT NO: 07625-001-018 LOCATION: JACKSON HAMLET 60RING NUM13ER: 8-6 PAGE: 1 of 1 BORING LOG DATE: 3/6/95 NUMBER DEPTH SPT T WL SI DESCRIPTION (USCS) COMMENTS UPPER 1', DENSE, BROWN, MED--GRAINED 4' SILTY SAND W/ 1 /4 —1 /Z' QTZ PEBBLES (SM), THEN 4 LIGHT GRAY, MASSIVE, SS-1 12,20.21 SS VERY FINE SILT (ML) OR CLAY (CL), THEN 3" DENSE, RED MED—GRAINED SILTY 8' SAND (SM), DRY. UPPER 3", LIGHT GRAY, MASSIVE, V. FINE SS- 9,12,17 SS SILT (ML) OR CLAY (CL), THEN V. FIRM, VARIGATED BROWN TO MAROON COARSE SILTY SAND W/SOME QTZ PEBBLES (SM), DRY SS-3 8,9,11 SS INTERBEDDED, FIRM, YELLOW —BROWN, FINE TO COARSE, SILTY SAND (SM), WET EOH @ 20' SS--4 8,10,12 SS VERY FIRM, VARIGATED YELLOW —BROWN, RED --BROWN, MAROON, COARSE TO VERY COARSE, W/SOME QTZ PEBBLES, SILTY T 24' CLEAN SAND (SM—SP), WET. 28' 32' 36' 40' BOREHOLE COMPLETION: 20' ILYL !N - SCREEN SS - SPUTSPOON WATER DEPTH: 13.9' BELOW GRADE DATE: 3/ 13/95 SPT - SOL PDNETRJ D M TEST-it'^M ST - SHELBY TUBE T - TYPE v& - WATER LEVEL DRILLING METHOD: HOLLOW STEM AUGERS lir"IR LOGGED BY: C. WELTY MONITORING WELL INSTALLATION DIAGRAM PROTECTIVE DEPTH PIPE HEIGHT FT BELOW GROUND SURFACE STICKUP FT i o 1 FT 3 FT 5 FT 2.3 FT GROUT MIX: LEAN PORTLAND/BENTONITE SLURRY -RENTQI.TE SEAL 1 BAG SENTONITE CHIPS. 50 LBS. IMPERVIOUS ZONE: 3 FT THICK PERMEABLE ZONE: 17 FT THICK PEiZOMETER NO..: WW-6 BORING NO..: B-6 JOB NO..: 07625-001--018 PREPARED 8Y: C- WELTM CHECKED By: C. LEE DATE:. 3/6/95. _ EL. 403.5 FT. TOP OF GROUND SURFACE PR TECTTVE METAL CASING LOCKING RISER PIPE: SCHEDULE ASTM DESIGNATION: --------- ID: __Z---- OD: --------- COUPLINGS: - T1jBl6Qfp_w FT PIPE IN _ 10 _ FT LENGTHS PIPE FT SCREEN _____.__ t 5 --------- FT TOTAL:--------22.3------- FT THICKNESS OF UPPER SEAL 2 FT LENGTH OF SCREEN 15 FT SAND 17 FT 20 FT }� 20 FT J BOTTOM OF BORING R MARK ALL MEASUREMENTS TO THE NEAREST 0.1 FT. HDR 6 vg. kr- MOORE COUNTY LANDFILL s PROJECT: MOORE COUNTY LANDFILL PROJECT NO: 07625-001-018 LOCATION: JACKSON HAMLET BORING NUMBER: B-7 PAGE: 1 of 1 BORING LOG DATE: 3/6/95 NUMBER DEPTH SPT T WL Sl DESCRIPTION (USCS) COMMENTS UPPER HALF OF SAMPLE IS FIRM, VARIGATED 4' MAROON, COARSE TO VERY COARSE, PEBBLY, SILTY SAND (SM). LOWER HALF IS VERY FIRM SS-1 10,10,11 SS BRIGHT YELLOW -BROWN, FINE-GRAINED SILTY SAND (SM), DRY.. 8 1 DENSE, VARIGATED LIGHT TAN, YELLOW -BROWN, MAROON, MEDIUM TO COARSE SILTY SAND WITH SOME. CLAY RIP -UP CLASTS (SM), DRY SS-2 13,17,21 SS UPPER QUARTER OF SAMPLE IS VERY FIRM, VARIGATED YELLOW -BROWN TO RED, MEDIUM SILTY SAND (SM). MIDDLE HALF IS VERY FIRM, 1 6' 10,12,12 SS LIGHT GRAY, YELLOW --BROWN TO LIMONITE -YELLOW, SS- 3 FINE CLAYEY SAND (SC) WITH A 1" -Z" SANDY CLAY LENS BOTTOM QUARTER IS YELLOW -BROWN TO GRAY- BROWN, MEDIUM TO COARSE SILTY SAND (SM), MOIST. EOH ® 20' SS-4 9,9,12 SS VERY RRM, VARIGATED LIMONITE -YELLOW, YELLOW -BROWN, RED, mMOON, MEDIUM TO VERY COARSE SILTY SAND (SDI) 2 4' WITI.1 A Z' GRAY VERY FINE SILT (ML) OR CLAY (CL) NDR BOTTOM, WET 28' 32' 36' 40' BOREHOLE COMPLETION: 20' K Y Si - SMEEN 55 - SPL[iSPooN SPT - WL PDORADON WATER DEPTH: 1 1 .9' BELOW GRADE DATE: 3/13/95 SHELBY TUBE - T - IYPE WL - WATER LML DR{LLING METHOD: HOLLOW STEM AUGERS LOGGED BY: C WELTY DEPTH BELOW GROUND SURFACE 0 FT 2 FT 4 FT of MONITORING WELL INSTALLATION DIAGRAM PROTECTIVE PIPE HEIGHT FT STICKUP FT GROLIT MIX: LEAN PORTLAND/BENTONTE SLURRY BENTQNITE AFC.' I 9AG SENTONRE CHPS. 50 LBS_ IMPERVIOUS ZONE: 2 FT THICK PERMEABLE ZONE: 17 FT THICK PEIZOMIETFR No.: IJW 7 BORING NO, : 8-7 ,108 No.,: 07625-001-018 PREPARED BY: C. WELTY CHECKED BY: C. LEE DATE: _ 3 fi 95 — EL 399.2 FT. TOP OF GROUND SURFACE PROTECTIVE METAL CASING LOCKING RISER PIPE: SCHEDULE ____ N ASTM DESIGNATION: ID: OD: COUPLINGS: TFIffb= PIPE IN 10 _ FT. LENGTHS ppE __1-10 CUT 4 _8!z 1 FT SCREEN 15 FT TOTAL: 21.8 FT THICKNESS OF UPPER SEAL 2 F LENGTH OF SCREEN 15 FT SMD 17 FT 19 FT _ Jf-1 20 FT _ _ BOTTOM OF BORING imREMARK5: ALL MEASUREMENTS TO THE NEAREST 0.1 FL• H R Etgkweer hg¢ >nc MOORE COUNTY LANDFILL PROJECT: MOORE COUNTY LANDFILL LOCATION: JACKSON HAMLET BORING LOG NUMBER DEPTH SPT T WL SI PROJECT: NO: 07625-001-018 BORING NUMBER: 8-8 PAGE: 1 of 1 DESCRIPTION (USCS) 4 FILL TO 6-1/2'. THEN VERY FIRM, YELLOW BROWN, VERY SILTY, MEDIUM TO COARSE SAND SS-1 7,9112 SS WITH GRANULES (SM), DRY 8' VERY DENSE, VARIGATED & INTEREEDDED, LIGHT GRAY, LIMONITE -YELLOW, RED, GRAY, SLIGHTLY SILTY, COARSS-2 13,21,33 SSWITH �}yp TVERY CH;CKSCLAYELL STRNOGERS, WIT (SR) VERY FIRM, YELLOW --BROWN TO RED, GRAY, SLIGHTLY SILTY, COARSE TO VERY COARSE SAND 55-3 1 1 6'-j 10,10,11 1 SS SS-4 �7SS 2 4' 28' 32' (SP) INTERBEDDED WITH I- TO 6" BEDS OF HARD, LIGHT REDDISH -GRAY, UASSINE FINE SILT (ML) OR CLAY (CL), WET EOH ® 20' FIRM, MAROON, WELL SORTED SILTY MEDIUM - GRAINED SAND (SM) WITH ONE C1/2' CLAY STRINGER, Y&F. 36' 40' BOREHOLE COMPLETION: 20' WATER DEPTH: 10 5' BELOW GRADE, DRILLING METHOD: HOLLOW STEM AUGERS LOGGED BY: C. WELTY DATE: .3/ 1 3/9 5 DATE: 3/7/95 COMMENTS K Y• si - SCREEN SS - SPUTSPOoN SPT - SOE PENEMATION TEST-N NUMBER ST -- SHELBY TUBE T -- TYPE wL - WATER LEVEL r m IE DEPTH BELOW GROUND >URFACE 0 5 FT I f MONITORING WELL INSTALLATION DIAGRAM PROTECTIVE PIPE HEIGHT STICKUP � FT 1 2.7 FT R�,T M X.. LEAN POM LAND/BENTONITE SLURRY NT N R I BAG BENTONfIE CHIPS, 50 LBS. IMPERVIOUS ZONE: 3 FT THICK PERMEABLE ZONE: 17 FT THICK PEIZOMETER KO.- 11W-8 BowNG NO. _ B-8 JOB NO.: 07625-001-018 PREPARED B1f: C. MiTy CHECKED BY: C. LEE DATE; 3/61.95 EL, 395.2 FT, TOP OF GROUND SURFACE PROT CTIVE METAL CASIN LOCKING RISER PIPE SCHEDULE — 19 ASTM DESIGNATION: ID: - OD: COUPLINGS: THREAD FT PIPE IN 10 FT LENGTHS PtPE I —10 (gt T O 7.71 - FT SCREEN 15 FT TOTAL: 22.7 THICKNESS OF UPPER SEAL 2 F7 I LENGTH OF SCREEN 15 FT SAND 17 FT 20 FT 20 _ _BOTTOM OF BORING gFM&EKS; ALL MEASUREMENTS TO THE NEAREST 0.1 FT. HM Engkm ewi'1 b'r— MOORE COUNTY LANDFILL PROJECT: MOORE COUNTY LANDFILL PROJECT NO: 07625-001-018 LOCATION: JACKSON HAMLET BORING NUMBER: B-9 PAGE: 1 of 1 BORING LOG DATE: 3/6/95 NUMBER DEPTH SPT T WL SI DESCRIPTION (USCS) COMMENTS 4' UPPER 1' IS FIRM, `FELLOW -BROWN SLIGHTLY SS-1 G,1O,17 SS SILTY COARSE SAND (SP), GETTING RED DIRECTLY ABOVE 2 -T GRAY SANDY CLAY (CL)_ LOWER PORTION 8 IS VERY qW, LIGHT TAN MEDIUM TO COARSE SILTY SAND (SM), DRY.. SS-2 8.10,15 SS VERY FIRMA, LIGHT TAN, FINE-GRAINED SILTY CLAYEY SAND (SC -Sty), LOTS OF KAOUNITE, DRY. 1 5 SS UPPER HALF OF SAMPLE 6 VERY FIRM, LIGHT TAN FINE SS-3 11.12,15 TO MEDIUM, VERY SILTY SAND (SM).. LOWER HALF IS VERY STIFF, UGiT GRAY, wSSNE, VERY CLEM, VERY FINE SILT (ML) OR 0-P1Jl X CLAY (CL), DRY. SS-4 15,18,23 SS DENSE, VARIGATED GRAY, TAN, BROWN, RED, COARSE SILTY SAND, WET.. 24' SS-5 13.14,19 SS DENSE, VARIGATED, BLOOD RED, BLUE --GRAY, DEEP TAN, RED -YELLOW, VERY COARSE TO COARSE, 2 8' POORLY SORTED SILTY SAND, WET EOH ® 30' 32' 36' 40' BOREHOLE COMPLETION: 30, sl - SCREEN 55 - SpuTspwN WATER DEPTH: 19 9' BELOW GRADE DATE: 3/13/95 sf - sm P'fNETR nm ST - s�Y � T - TYPE WL - WATER LEVM DRILLING METHOD: HOLLOW STEM AUGERS im LOGGED BY: C. WELTY w DEPTH BELOW ROUND ;URFACE 11 FT 13 FT 15 FT I MONITORING WELL INSTALLATION DIAGRAM PROTECTIVE PIPE HEIGHT FT STICKUP - FT 1 2.4 FT Sri MiX LEM PORnAND/BC9TONITE SLURRY DENTONITE 1 BAG BENTOMTE CHIPS, 50 LBS. IMPERVIOUS ZONE: 13 FT THICK PERMEABLE ZONE: 17 FT THICK PEIZOMEIEK NO..: MW-9 BORING NO..: 8-9 J013 NO„; 07625-001-018 PREPARED BY: C. WELTY CHECKED BY: C. LEE DAB; 3L6195 EL. 403.7 FT. TOP OF GROUND SURFACE P TECTN ME & Q&51NG I LOCKING RISER PIPE: SCHEDULE _ 40 ASTM DESIGNATION: ID: - OD: CW UNGS:._ RRE6Xp - FT PIPE IN w._ 1 o Fr. LENGTHS PIPE IN _ 1-1 o FT.. LENGTHS PIPE _ 1--10 (CiiT 0 7.4' FT ` SCREEN 15 FT TOTAL: 32.4 FT THICKNESS OF UPPER SEAL 2 F LENGTH OF SCREEN 15 FT .. yI SAND 17 FT 30 FT 30 BOTTOM OF BORING gg ALL MEASUREMENTS TO THE NEAREST 0.1 FT. m 8 OORE COUNTY LANDFILL HDR PROJECT: MOORE COUNTY C&D LANDFILL PROJECT NO: 07625-001-018 LOCATION: HIGHWAY 5, ABERDEEN, NC BORING NUMBER: B-14 PAGE: 1 of 1 BORING LOG DATE: 9/ 16/96 NUMBER DEPTH SPT T WL SI DESCRIPTION (USCS) COMMENTS 4' _ — WHITE AND TAN, MOTTLED, DENSE, FINE— GRAINED SAND (SW), WITH A TRACE OF CLAY, SLIGHTLY MOIST, IRON OXIDE VERY UNIFORM TEXTURE SS-1 46 SS 8' — STAINING. —_ _ WHITE TO TAN, MEDIUM —DENSE, FINE TO COARSE —GRAINED SAND (SM), MOTTLED WITH MAROON SAND LENSES, IRON OXIDE STAINING, SLIGHT CLAY CONTENT, VERY SS-2 11 SS _ — MOIST TO WET. DARK GRAY AND MAROON, MEDIUM —DENSE, SS-3 1 6' 19 SS = COARSE TO VERY COARSE SAND (SC), MIXED WITH DARK GRAY TO MAROON SANDY — CLAY LENSES, STIFF, FIRM, SL. PLASTICITY, = WET. T.D. = 20 FEET 2 4' 28' 32' AT —� DRILLING 36' �- 24 HR 40' BOREHOLE COMPLETION: 20 FEET BELOW LAND SURFACE Si - SCREEN SS - SPLITSPOON SPT - SOIL PENETRATIDN TEST-N NUMBER ST - SHELffY TUBE T - TYPE WL - WATER LEVEL WATER DEPTH: 12.78 FEET BELOW LAND SURFACE DATE: 9/18/96 DRILLING METHOD: 4 1/4-INCH HOLLOW STEM AUGERS LOGGED BY: J ISHAM J DEPTH BELOW GROUND SURFACE 0 1.0 FT 3.0 FT 5.0 FT PROTECTIVE PIPE HEIGHT MONITORING WELL INSTALLATION DIAGRAM 400.58 FT 2.70 FT LROUT_MIX: PORTLAND TYPE I CEMENT QENTONITE SEAL: 3/8-INCH SENTONITE PELLETS IMPERVIOUS ZONE: 3.0 Fr THICK PERMEABLE ZONE: 17.0 Fr THICK MOORE COUNTY C&D LANDFILL PEIZOMETER NO: Mw-14 BORING NO,: B-14 JOB NO: 07625-001-018 { PREPARED BY: J. 1SHAM CHECKED BY: DATE: _- 9/16/96 EL, 397.88 Fr. TOPOF GROUND SURFACE PROTECTIVE MFFAL CASING 4-INCH SQUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE aQ_v ASTM DESIGNATION: ID: _��0 CINCH _ OD: _______ - COUPLINGS: THREADfD—_ FT PIPE IN 10_0 FT LENGTH '. PIPE------� 2.7 F PIPE _ _LL�5.0 FT SCREEN _�Z S.OL��_ t4_4 FT � TOTAL: ___-- 22,70 __--_—. F THICKNESS OF UPPER SEAL 2.0 F LENGTH OF SCREEN 15.0 FT SAN D 17.0 FT FT 20.0 FT — — — — — — — BOTTOM OF BORING REMARKS: ALL MEASUREMENTS TO THE NEAREST 0.1 FT. fDq N=2,694.2171 E=3,615.2164 T PROJECT: MOORE COUNTY C&D LANDFILL PROJECT NO: 07625-001-018 LOCATION: HIGHWAY 5, ABERDEEN, NC BORING NUMBER: B-15 PAGE: 1 of 1 BORING LOG DATE: 9/19/96 NUMBER DEPTH SPT T WL SI DESCRIPTION (USCS) COMMENTS 4' TAN AND REDDISH -BROWN, MEDIUM -DENSE, SS-1 17 SS MEDIUM TO COARSE —GRAINED SLIGHTLY CLAYEY SAND (SC), NO PLASTICITY, STICKY, 8' MOIST, MOTTLED. WHITE, MEDIUM —DENSE, FINE—GRAINED SAND VERY UNIFORM SS-2 17 SS (SW), WITH MINOR FINES, MIXED WITH DENSE TEXTURE SANDY CLAY LENSES. SL. PLASTICITY, DRY, = HORIZONTAL COLOR BANDING, SAME AS ABOVE (SW), MEDIUM TO COARSE— GRAINED, PINK/MAROON MOTTLING, FINES MIXED, SLIGHTLY KAOLONITIC, V. MOIST, WHITE, MAROON, BROWN, RED —ORANGE, VERY UNIFORM TEXTURE SS-3 1 6' 19 SS SS-4 22 SS _ MEDIUM —DENSE, MEDIUM TO COARSE —GRAINED = CLAYEY SAND (SC), KAOLINITIC ZONES, WET. 24' _ — -------� WHITE AND PINK, MEDIUM —DENSE, MEDIUM TO SS-5 26 SS = COARSE —GRAINED SAND (SM) MIXED WITH 28' = GRAY/WHITE CLAY LAYERS (KAOLINITIC/STICKY), _ — — SLIGHTLY MOIST, HORIZONTAL MOTTLING SAME AS ABOVE (SM), MEDIUM TO COARSE— GRAINED, WET. LANDFILL GAS SS-6 ' 22 SS = ODOR SS-7 36` 18 SS T D = .35 FEET � AT — DRILLING 40' BOREHOLE COMPLETION: 35 FEET BELOW LAND SURFACE SI - SCREEN SS - SPUTSPOON SPT - SOIL' PENETRATION TEST-N NUMBER ST - SHELBY TUBE T - TYPE WL - WATER LEVEL WATER DEPTH: 30 FEET BELOW LAND SURFACE DATE: 9/19/96 DRILLING METHOD: 4 1/4-INCH HOLLOW STEM AUGERS Imi LOGGED BY: J ISHAM DEPTH PROTECTIVE BELOW PIPE HEIGHT GROUND SURFACE 16.0 FT 18.0 FT 1 20.0 FT MONITORING WELL INSTALLATION DIAGRAM 431.10 FT 1.79 FT GRQ„WT MIX: PORTLAND TYPE I CEMENT NT NITESEAL: 3/8—INCH BENTONME PELLETS IMPERVIOUS ZONE: 18.0 FT THICK PERMEABLE ZONE: 17.0 FT THICK MOORE COUNTY LANDFILL PEIZOMETER NO..: MW-15 BORING NO.: B-15 JOB NO.: 07625-001-018 PREPARED BY: J. rSHAM CHECKED BY: DATE: 9/ 19 /96 EL. 429.31 FT. TOP OF GROUND SURFACE PROTECTIVE METAL CASIN 4—INCH SQUARE BLACK STEEL WELL BOX WITH LOCKING COVER RISER PIPE: SCHEDULE ASTM DESIGNATION: ID: _�_0 CINCH OD COUPLINGS: __ THREADED __ FT PIPE IN __ 10_0 _ FT.. LENGTHS PIPE -___ .il),?_79 FT PIPE FT SCREEN _LZ 5�0`��10�0 FT TOTAL: -- 36.79 . �__-- FT THICKNESS OF UPPER SEAL 2-0 FT LENGTH OF SCREEN 15.0 FT SAND 17.0 FT FT 35.0 FT — — — — — -- — — BOTTOM OF BORING REMARKS: ALL MEASUREMENTS TO THE NEAREST 0.1 FT. N=3s234.5825 _ E=4 373.7788 Hari Ord), Ism, APPENDIX B Groundwater Protection Compliance Standards - Constituents List NC Solid Waste Section Environmental Monitoring List NC Solid Waste Section Environmental Monitoring Groundwater Protection Compliance Standards - Constituents List (updated October 15, 2018) All units are ug/L unless otherwise noted. NE = Not Established Groundwater Protection Standards) DEQ Calculated CAS RN 2 SWS ID' CHEMICAL NAME 2L 2L IMAC I MCL GWP Std Reference List` 67-64-1 3 Acetone 107-13-1 8 Acrylonitrile 6000 NE NE NE Appendix NE NE Appendix 1 NE NE 7440-36-0 13 Antimony NE 1 6 NE Appendix I 7440-38-2 14 Arsenic 10 NE 30 _ NE 1 Appendix 1 7440-39-3 15 Barium 700 NE 2000 NE Appendix I 71-43-2 16 Benzene Beryllium Bromochloromethane; Chlorobromethane Bromodichloromethane; Dibromochloromethane 1 NE 5 NE I AppendixI Appendix I Appendix I 7440-41-7 23 NE 4 4 NE 74-97-5 28 NE NE NE 0.6 75-27-4 29 0.6 NE 80 NE Appendix I 75-25-2 30 Bromoform; Tribromomethane 4 NE 80 NE Appendix 1 7440-43-9 34 Cadmium 35 Carbon disulfide 36 Carbon tetrachloride 39 Chlorobenzene 41 Chloroethane; Ethyl chloride 44 i Chloroform; Trichloromethane 2 NE 5 NE Appendix 1 75-15-0 700 NE NE NE I Appendix I 56-23-5 0.3 NE NE NE 5 NE Appendix 1 108-90-7 S0 3000 70 100 NE Appendix I 75-00-3 NE NE A nix I Appendix I 67-66-3 NE 80 NE 7440-47-3 51 Chromium 10 NE 100 € NE Appendix 1 A en ix I Appendix Appendix I Appendix I 1 7440-48-4 53 Cobalt NE 54 Copper 1000 66 Dibromochloromethane; Chlorodibromomethane 0.4 67 1,2-Dibromo-3-chloropropane; DBCP 0.04 T 68 1,2-Dibromoethane; Ethylene dibromide; EDB 0.02 69 o-Dichlorobenzene; 1,2-Dichlorobenzene 20 71 p-Dichlorobenzene; 1,4-Dichlorobenzene 6 1 I NE NE 7440-50-8 NE i 1300 NE 124-48-1 NE 80 NE 96-12-8 NE 0.2 NE 106-93-4 NE 0.05 600 NE 95-50-1 NE i NE _Appendix Appendix I Appendix 1 106-46-7 NE 75 NE 110-57-6 73 trans-1,4-Dichloro-2-butene 75 1,1-Dichloroethane; Ethyldidene chloride 76 1,2-Dichloroethane; Ethylene dichloride 77 1,1-Dichloroethylene; 1,1-Dichloroethene; NE NE NE NE Appendix 1 75-34-3 6 NE NE NE Appendix I 107-06-2 0.4 NE 5 NE Appendix I 75-35-4 350 NE 7 NE Appendixi Page 1 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) CAS RN z 156-59-2 SWS ID CHEMICAL CHEMICAL NAME Vinylidene chloride cis-1,2-Dichloroethylene; cis-1,2- 78 Dichloroethene 79 trans-1,2-Dichloroethylene;trans-1,2-Dichloroethene 82 1,2-Dichloropropane 86 cis-1,3-Dichloropropene DEQ Calculated 2L 21. [MAC MCL GWP Std Reference List` 70 NE 70 NE I ADDendix I 156-60-5 100 NE 100 NE ARRendix1 78_87-5 10061-01-5 0.6 NE 5 NE A nix I 0.4 NE NE NE ADDendix 1 10061-02-6 87 trans-1,3-Dichloropropene 0.4 NE NE NE ADDendix I 100-41-4 110 Ethylbenzene 600 NE 700 NE AROnclix1 591-78-6 124 2-Hexanone; Methyl butyl ketone NE 40 1 NE NE ARRCndix I 7439-92-1 131 Lead is NE 15 NE A en ix1 74-83-9 136 Methyl bromide; Bromomethane NE 10 NE NE &WSndix 1 74-87-3 137 Methyl chloride; Chloromethane 3 NE NE NE ADDendix 1 74-95-3 75-09-2 78-93-3 139 Methylene bromide; Dibromomethane NE 5 70 NE NE 5 NE NE Appendix I ADDendix 1 140 Methylene chloride; Dichloromethane 141 Methyl ethyl ketone; MEK; 2-Butanone 142 Methyl iodide; Iodomethane 147 4-Methyl-2-pentanone; Methyl isobutyl ketone 152Nickel 183 t Selenium 184 Silver 186 Styrene 190 1,1,1,2-Tetrachloroethane 191 1,1,2,2-Tetrachloroethane Tetrachloroethylene; Tetrachloroethene; 192 Perchloroethylene 4000 NE NE NE ADDendix I 74-88-4 NE NE NE NE Agpencliox 1 108-10-1 NE 100 NE NE Appendix I Appendix I Appendix I A nix 1 Appendix Appendix 1 ADoendix I - A2Rgn Ix ADDendix I 744D-02-0 100 NE NE NE 7782-49-2 20 NE 50 NE 7440-22-4 20 NE NE NE 100-42-5 70 NE 100 NE 630-20-6 79-34-5 127-18-4 NE 1 NE NE 0.2 NE NE NE 0.7 NE NE 0.2 1 5 NE 2 NE 1000 NE 200 NE 7440-28-0 108-88-3 71-55-6 194 Thallium 196 Toluene 200 1,1,1-Trichloroethane; Methylchloroform 201 Trichloroethylene; Trichloroethene 202 1,1,2-Trichloroethane 600 NE j ARRgndixI 200 NE Appendix 1 A nix I ADDendix 1 79-01-6 3 NE 5 NE 79-00-5 NE 1 2000 0.6 NE 5 NE NE 75-69-4 203 Trichlorofluoromethane; CFC-11 206 1,2,3-Trichloropropane 209 Vanadium 210 Vinyl acetate 211 Vinyl chloride; Chloroethene NE A en ix 1 Appendix I 96-18-4 1 0.00s NE NE NE 7440-62-2 NE 0.3 NE NE ARRen ix I 108-05-4 NE 88 NE I NE ADoendix I 75-01-4 0.03 NE 2 1 NE A nix I Page 2 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards 1 CAS RN Z 7440-66-6 1330-20-7 ! I DEQ Calculated SWS ID a CHEMICAL NAME 2L 2L IMAC MCL GWP Std Reference List` 213 Zinc 1000 NE NE NE _Appendix I 346 Xylene (total) 500 NE 10000 NE Appendix 83-32-9 208-96-8 1 Acenaphthene 2 Acenaphthylene 80 NE NE NE Appendix II Appendix II 200 NE NE NE 75-05-8 4 Acetonitrile; Methyl cyanide NE NE NE NE Appendix II 98-86-2 5 Acetophenone NE 700 NE NE Appendix II 53-96-3 6 2-Acetylaminofluorene; 2-AAF NE NE NE NE Appendix II 107-02-8 7 Acrolein NE 4 NE NE Appendix II 309-00-2 9 10 Aldrin Ally[ chloride NE 0.002 NE NE Appendix II 107-05-1 NE NE NE NE NE NE Appendix II 92-67-1 11 4-Aminobiphenyl 12 Anthracene 17 Benzo[a]anthracene; Benzanthracene 18 Benzo[b]fluoranthene 19 Benzo[k]fluoranthene 20 Benzo[ghi]perylene 21 Benzo[a]pyrene 22 Benzyl alcohol 24 alpha-BHC 25 beta-BHC NE NE Appendix II 120-12-7 2000 NE NE NE NE NE NE 700 0.006 0.02 NE NE NE NE Appendix II Appendix II Appendix II 56-55-3 0.05 0.05 0.5 200 0.005 205-99-2 NE NE 207-08-9 NE NE Appendix II 191-24-2 NE NE Appendix II 50-32-8 1 0.2 NE NE NE NE NE NE NE Appendix II Appendix II Appendix II Appendix II 100-51-6 NE 319-84-6 NE 319-85-7 NE NE 319-86-8 26 delta-BHC NE NE 0.019 Appendix II 58-89-9 27 31 gamma-BHC; Lindane 4-Bromophenyl phenyl ether 0.03 NE 0.2 NE Appendix II Appendix II 101-55-3 NE NE NE NE 85-68-7 32 i Butyl benzyl phthalate; Benzyl butyl phthalate 33 Di-n-butyl phthalate 38 p-Chloroaniline 40 Chlorobenzilate 42 Bis(2-chloroethoxy)methane 43 Bis(2-chloroethyl)ether; Dichloroethyl ether 45 p-Chloro-m-cresol; 4-Chloro-3-methylphenol Bis(2-chloro-l-methylethyl) ether; 2,2'- 46 Dichlorodiisopropyl ether; DCIP 47 2-Chloronaphthalene 1000 NE NE NE I Appendix II 84-74-2 106-47-8 510-15-6 700 NE NE NE Appendix II Appd NE NE NE NE NE NE NE NE Appendix II 111-91-1 NE NE NE NE Appendix II 111-44-4 NE NE NE 0.031 Appendix II Appendix II Appendix II 59-50-7 108-60-1 91-58-7 NE NE NE NE NE NE NE NE NE NE NE NE Appendix II Page 3 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards 1 CAS RN z DEQ calculated SWS ID' CHEMICAL NAME 2L 2L [MAC MCL GWP Std Reference List° 48 2-Chlorophenol 0.4 NE NE NE Appendix II 49 4-Chlorophenyl phenyl ether NE NE i NE NE Appendix II 95-57-8 7005-72-3 126-99-8 50 Chloroprene NE NE NE NE Appendix II 218-01-9 95-48-7 57-12-5 52 Chrysene o-Cresol; 2-Methylphenol 5 NE NE NE Appendix II Appendix II Appendix II Appendix 11 Appendix 11 56 NE 400 NE NE 58 Cyanide 70 NE 200 NE 94-75-7 59 60 2,4-D; 2,4-Dichlorophenoxyacetic acid 70 NE 70 NE 72-54-8 4,4'-DDD 0.2 NE NE NE 72-55-9 61 4,4'-DDE NE NE NE NE NE NE i Appendix II Appendix II 50-29-3 62 4,4'-DDT 0.1 NE 2303-16-4 63 Diallate NE NE NE NE ADDenc ix 11 53-70-3 132-64-9 541-73-1 91-94-1 75-71-8 64 65 Dibenz[a,h)anthracene Dibenzofuran m-Dichlorobenzene;1,3-Dichlorobenzene 3,3'-Dichlorobenzidine 0.005 NE NE NE NE Appendix II Appendix II Appendix II NE 28 NE 70 200 NE NE NE 72 NE 1000 NE NE NE NE NE NE ADpendix II Appendix II 74 Dichlorodifluoromethane; CFC 12 120-83-2 80 2,4-Dichlorophenol NE 0.98 NE NE Appendix II 87-65-0 81 2,6-Dichlorophenol NE NE NE NE Appendix 11 142-28-9 1 83 1,3-Dichloropropane; Trimethylene dichloride NE NE NE NE Appendix 11 594-20-7 84 2,2-Dichloropropane; Isopropylidene chloride 85 1,1-Dichloropropene 88 Dieldrin 89 O,O-Diethyl O-2-pyrazinyl phosphorothioate; Thionazin 90 Diethyl phthalate NE NE NE NE ADpendix II 563-58-6 NE NE NE i NE Appendix II Appendix 11 60-57-1 0.002 1 NE NE NE 297-97-2 NE NE NE NE ADpendix 11 84-66-2 6000 NE NE NE Appendix II 60-51-5 60-11-7 57-97-6 91 Dimethoate _ 92 I p-(Dimethylamino)azobenzene 93 7,12-Dimethylbenz[a)anthracene 94 3,3'-Dimethylbenzidine 95 2,4-Dimethylphenol; m-Xylenol 96 Dimethyl phthalate NE NE NE NE Appendix II NE NE NE NE Appendix 11 NE NE NE NE Appendix II 119-93-7 NE NE NE NE Appendix 11 ADpendix II 105-67-9 100 1 NE NE NE 131-11-3 NE NE NE NE ADpendix 11 99-65-0 97 m-Dinitrobenzene NE NE NE NE ADpendix II 534-52-1 98 4,6-Dinitro-o-cresol; 4,6-Dinitro-2-methylphenol NE NE I NE I NE ADpendix II Page 4 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards t CAS RN 2 SWS ID a CHEMICAL NAME DEQ Calculated 21. 211. IMAC MCL GWP Std Reference List ` NE NE NE NE Appendix II 51-28-5 99 2,4-Dinitrophenol 121-14-2 100 2,4-Dinitrotoluene NE 0.1 NE NE ADpendix II 606-20-2 101 2,6-Dinitrotoluene NE NE NE NE Appendix 11 88-85-7 102 Dinoseb; DNBP; 2-sec-Butyl-4,6-dinitrophenol Diphenylamine NE 7 1 7 NE Appendix II ADpendix 11 122-39-4 103 NE NE NE NE 298-04-4 104 Disulfoton 0.3 NE NE NE Appendix 11 959-98-8 105 Endosulfan 1 106 Endosulfan II 107 Endosulfan sulfate 40 NE NE NE Appendix 11 33213-65-9 NE NE NE 42 Appendix II Appendix II Appendix II 1031-07-8 NE 2 40 NE NE 2 E ENE 72-20-8 108 Endrin 7421-93-4 109 Endrin aldehyde 111 Bis(2-ethylhexyl) phthalate 112 Ethyl methacrylate 2 NE NE NE Appendix II 117-81-7 3 NE NE NE Appendix 11 Appendix II Appendix II 97-63-2 NE NE NE NE NE NE NE NE 62-50-0 113 Ethyl methanesulfonate NE NE NE 52-85-7 114 Famphur NE 300 NE NE Appendix 11 206-44-0 115 Fluoranthene 116 Fluorene 117 Heptachlor 118 Heptachlor epoxide NE NE Appendix 11 Appendix II Appendix 11 86-73-7 76-44-8 1024-57-3 300 NE NE 0.008 NE 0.4 NE 0.004 NE 1 0.2 NE Appendix 11 118-74-1 119 Hexachlorobenzene 0.02 NE 1 NE Appendix11 87-68-3 120 Hexachlorobutadiene Hexachlorocyclopentadiene Hexachloroethane 0.4 NE NE NE Appendix II Appendix 11 Appendix 11 Appendix II 77-47-4 121 NE NE NE NE 50 SO 67-72-1 122 NE NE NE NE 2.5 NE 1888-71-7 123 Hexachloropropene 193-39-5 125 Indeno(1,2,3-cd)pyrene 0.05 1 NE NE NE I Appendix II Appendix 11 78-83-1 126 Isobutyl alcohol 127 Isodrin 128 Isophorone NE NE NE NE 465-73-6 NE NE NE NE Appendix II 78-59-1 40 NE I NE NE Appendix II 120-58-1 129 Isosafrole NE NE NE NE Appendix II 143-50-0 130 Kepone NE NE NE NE Appendix 11 7439-97-6 132 Mercury 1 NE 2 NE App. II / C&D 126-98-7 133 Methacrylonitrile NE NEI NE NE ADpendix 11 Page 5 of 11 NC Solid Waste Section Environmental Monitoring List CAS RN z 91-80-5 72-43-5 56-49-5 80-62-6 66-27-3 91-57-6 298-00-0 91-20-3 130-15-4 134-32-7 91-59-8 99-09-2 88-74-4 100.01-6 98-95-3 99-55-8 88-75-5 100-02-7 55-18-5 62-75-9 924-16-3 86-30-6 SWS ID 3 CHEMICAL NAME 134 Methapyrilene 135 Methoxychlor 138 3-Methylcholanthrene 143 Methyl methacrylate 144 Methyl methanesulfonate 145 2-Methylnaphthalene 146 Methyl parathion; Parathion methyl 148 Naphthalene 149 1,4-Naphthoquinone 150 1-Naphthylamine 151�2-N'a'p-hthyla mine 153 m-Nitroaniline;3-Nitroaniline____ 154 o-Nitroaniline; 2-Nitroaniline 155 rp-Nitroaniline; 4-Nitroaniline 156 Nitrobenzene 157 5-Nitro-o-toluidine 158 o-Nitrophenoi; 2-Nitrophenol 159 1 p-Nitrophenol; 4-Nitrophenol 160 _N_-Nitrosodiethylamine i 161 i N-Nitrosodimethylamine 162 N-Nitro sodi-n-butylamine 163 N-Nitrosodiphenylamine N-Nitrosodipropylamine; N-Nitroso-N-dipropylamine; Di - Groundwater Protection Standards 1 211. 21. IMAC MCL NE NE NE DEQ Calculated GWP Std Reference List ° NE j Appendix II NE Appendix II NE Appendix II 40 NE NE NE NE NE NE 25 NE NE Appendix II I Appendix II NE NE NE NE 30 NE NE NE Appendix II NE NE NE NE Appendix II 6 NE NE NE Appendix II Appendix II Appendix II Appendix II Appendix II NE NE NE NE NE NE NE NE NE NE NE I NE NE NE NE NE NE NE NE NE NE Appendix II Appendix II Appendix II Appendix II Appendix II T Appendix II NE NE I NE NE NE NE NE NE NE NE NE NE I NE NE NE NE NE NE NE NE NE NE NE Appendix II 0.0007 NE NE NE Appendix II NE NE NE NE Appendix II Appendix If NE NE NE NE I 621-64-7 164 n-propyinitrosamine NE NE NE NE 10595-95-6 100-75-4 165 N-Nitrosomethylethalamine 166 N-Nitrosopiperidine 167 N-Nitrosopyrrolidine 168 Di-n-octyl phthalate 169 Parathion NE NE NE NE NE NE NE NE 930-55-2 117-84-0 56-38-2 I NE NE NE I NE 100 NE NE NE NE NE NE NE 1336-36-3 170 Polychlorinated biphenyls; PCBs 171 Pentachlorobenzene 172 Pentachloronitrobenzene 173 Pentachlorophenol NE 0.09 0.5 NE 608-93-5 NE NE NE NE 82-68-8 NE NE NE NE 87-86-5 0.3 NE 1 NE Page 6 of 11 NC Solid Waste Section Environmental Monitoring List CAS RN z I SWS ID' CHEMICAL NAME Groundwater 2L NE 200 NE Protection 21. IMAC NE NE NE Standards 1 MCL NE NE NE NE DEQ Calculated GWPStd NE NE NE NE Reference List Appendix II Appendix II Appendix II Appendix II 62-44-2 174 Phenacetin 85-01-8 106-50-3 175 Phenanthrene 176 177 p-Phenylenediamine Phenol 108-95-2 30 NE 298-02-2 178 Phorate 1 NE NE NE Appendix II 23950-58-5 179 Pronamide NE NE NE NE Appendix II 107-12-0 180 Propionitrile; Ethyl cyanide Pyrene NE NE NE NE NE NE Appendix II Appendix 11 Appendix 11 129-00-0 181 200 NE NE NE NE NE 94-59-7 182 Safrole 93-72-1 185 Silvex; 2,4,5-TP 50 NE NE NE Appendix 11 18496-25-8 187 Sulfide N I NE NE NE Appendix 11 93-76-5 95-94-3 188 2,4,5-T; 2,4,5-Trichlorophenoxyacetic acid 1,2,4,5-Tetrachlorobe nzene 2,3,4,6-Tetrachlorophenol Tin NE NE NE NE Appendix II 189 NE 2 NE NE Appendix 11 58-90-2 193 200 NE NE NE Appendix II ADoendix 11 7440-31-5 195 NE 2000 NE NE 95-53-4 197 o-Toluidine Toxaphene NE NE NE NE Appendix 11 Appendix II 8001-35-2 198 0.03 NE 3 NE 120-82-1 199 1,2,4-Trichlorobenzene 70 NE 70 NE Appendix 11 95-95-4 204 2,4,5-Trichlorophenol NE 63 NE NE Appendix 11 88-06-2 205 2,4,6-Trichlorophenol NE 4 NE NE Appendix 11 126-68-1 207 0,0,0-Triethyl phosphorothioate NE NE NE NE Appendix 11 99-35-4 208 sym-Trinitrobenzene NE NE NE NE Appendix 11 57-74-9 339 Chlordane 0.1 NE NE NE ADoendix II 106-44-5 344 p-Cresol; 4-Methylphenol 40 400 NE NE NE NE NE NE Appendix 11 Appendix II Appendix II Appendix 11 108-394 345 m-Cresol; 3-Methylphenol 386 Benzeneethanamine, alpha,alpha-dimethyl 122-09-8 NE .0002 ng/L NE NE 1 NE 0.03 NE NE 1746-01-6 1 440 2,3,7,8-TCDD; 2,3,7,8-Tetrachlorodibenzo- p-dioxin 123-91-1 I 422 I 1,4-dioxane 3 I NE I NE i NE ALL' SW301 301 Chloride 250000 NE NE NE C&D SW311 311 Total Dissolved Solids 500000 NE NE NE C&D 14808-79-8 315 Sulfate 250000 NE NE NE C&D/Leachate SW337 337 1 Alkalinity NE NE NE NE C&D Page 7 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards' CAS RN z SWS ID' CHEMICAL NAME 7439-89-6 340 Iron DEQ Calculated 2L 2L IMAC MCL GWP Std Reference List ` 300 NE NE NE C&D 50 NE NE NE _ C&D NE NE NE NE C&D 7439 96 5 342 Manganese 441 Tetrahydrofuran 109-99-9 SW316 316 piological Oxygen Demand 317 Chemical Oxygen Demand 419 No2/No3 (nitrate & nitrite reported together) 1 437 Orthophosphate Phosphorus NE NE NE NE NE NE NE Leachate Leachate SW317 NE SW419 NE NE 7.0 NE NE NE Leachate Leachate _ Leachate__ I Leachate SW437 NE NE NE SW321 SW32424 T321pH (lab) I SpecCond (lab) NE NE NE NE NE I NE NE 226-36-8 385 1,2,5,6-Dibenzacridine 394 1,2-Diphenylhydrazine 371 1-2-3-Trichlorobenzene 352 2-(2-4-dichlorophenoxy)propionic acid 350 2-4 DB NE NE NE NE NE NE NE NE NE NE Other Other Other 122-66-7 NE 87-61-6 NE NE NE 120-36-5 NE NE NE I Other Other 94-82-6 NE NE NE 130-75-8 358 2-Chloroethylvinyl ether NE 390 2-Picoline NE 388 4-nitroquinoline-l-oxide NE 416 Acetic Acid NE NE NE NE Other Other other Other 109-06-8 NE NE NE 56-57-5 NE NE NE 64-19-7 5000 NE NE 62-53-3 381 1 Aniline NE NE NE NE Other 140-57-8 382 Aramite NE NE NE NE Other 12674-11-2 401 Aroclor 1016 Aroclor1221 NE NE NE NE Other 11104-28-2 11141-16-5 402 NE NE NE NE NE NE NE NE Other Other 403 Aroclor 1232 53469-21-9 404 Aroclor 1242 NE NE NE NE Other 12672-29-6 11097-69-1 405 Aroclor 12_48 NE NE NE NE I NE NE NE NE I NE NE Other Other__ _ Other other Other other 406 407 383 1 Aroclor1254 i Aroclor 1260 Benzidine 11096-82-5 NE NE 92-87-5 NE NE NE I NE 7440-42-8 428 Boron 347 Bicarbonate (as CaCO3) 423 biphenyl ether 700 NE NE NE SW347 101-84-8 NE NE NE NE NE NE NE NE Other 108-86-1 360 Bromobenzene NE NE NE NE Other Page 8 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards 1 CAS RN Z SW418 7440-70-2 SWS ID' CHEMICAL NAME 418 Butyric Acid 375 Calcium DEQ Calculated 21. 2L IMAC MCL GWP Std Reference List 4 NE NE NE NE Other NE NE NE NE other NE NE NE NE Other NE NE NE NE Other SW413 413 Carbon Dioxide (CO2) SW348 12789-03-6 348 Carbonate (as CaCO3) Chlordane (constituents) 400 NE NE NE NE other 79-06-1 429 Acrylamide 0.008 NE NE NE Other 5103-71-9 379 Chlordane, alpha NE NE I NE NE Other 5103-74-2 378 Chlordane, beta NE NE NE NE 2 NE NE NE other Other 5566-34-7 399 Chlordane, gamma 75-99-0 355 Dalapon NE 200 200 NE Other SW318 318 Depth To Water (ft) NE NE NE NE Other 1918-00-9 353 Dicamba NE NE NE NE NE NE NE Other Other Other SW334 334 Ferrous Iron- Dissolved Groundwater Elevation (feet) NE NE SW427 427 NE NE NE NE NE NE SW319 319 Head (ft mean sea level) NE NE NE NE NE Other Other Other Other other 70-30.4 387 Hexachlorophene Hydrogen Sulfide Lactic Acid NE I NE NE SW338 SW415 SW329 338 415 NE NE NE NE NE NE 329 Landfill Gas NE NE NE SW374 374 m-&p-Cresol (combined) NE NE NE NE Other 92-52-4 SW359 421 1,1-biphenyl m-&p-Xylene (combined) Carbofuran 400 NE NE NE Other 359 NE NE NE NE Other Other Other 1563-66-2 430 40 10000 NE NE 40 NE NE NE 107-21-1 424 ethylene glycol 142-82-5 432 Heptane 400 NE NE NE Other 7439-95-4 376 Magnesium MCPA 1,1,2-Trichlorotrifluoroethane NE NE NE NE Other Other 94-74-6 351 NE NE NE NE 76-13-1 398 200000 NE NE NE Other 93-65-2 354 Mecopop, MCPP Methane- Dissolved Molybdenum NE NE NE NE Other SW333 7439-98-7 333 NE NE NE NE Other 397 i NE NE NE NE NE NE NE NE Other Other 108-38 3 409 1 m-Xylene Page 9 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards 1 DEQ CAS RN z SWS ID a CHEMICAL NAME SW426 426 N-nitrosodiphenylamine/diphenylamine SW439 439 N-Nitrosodiphenylamine/Diphenylamine 65-85-0 395 Benzoic Acid 211. 21. (MAC MCL GWP Std Reference List NE NE Other NE NE Other NE NE other NE NE NE NE 30000 1 NE 39638-32-9 384 Bis(2-chloroisopropyl) ether 0.03 NE NE NE Other 59-89-2 389 N-Nitrosomorpholine Coliform (total) NE NE NE NE Other other SW309 309 1 is NE NE 5 NE NE NE SW310 310 Color (color units) Other SW336 SW313 SW314 336 Oxygen Reduction Potential (mV) Foaming Agents NE NE NE NE Other Other Other 313 500 is NE NE NE NE NE NE 314 Gross Alpha 106-43-4 365 4-Chlorotoluene NE NE 24 25 NE NE NE NE Other other Other Other 99-87-6 108-20-3 98-82-8 368 _ p-Cymene 366 ( Isopropyl ether 367 Isopropylbenzene 70 NE NE NE 70 NE NE NE 76-01-7 380 Pentachloroethane NE NE NE NE other SW335 335 Manganese- Dissolved s0 NE NE NE Other 108-67-8 373 Mesiitylene (1-3-5-trimethylbenzene) 400 NE NE NE other 7440-09-7 377 Potassium NE NE NE NE Other 1634-04-4 369 Methyl-tert-butyl ether (MTBE) 20 NE NE NE Other 104-51-8 361 n-Butylbenzene 70 NE NE NE Other SW417 417 PropionicAcid NE NE NE NE Other 106-42-3 410 p-Xylene _ NE NE NE NE Other 103-65-1 370 1 n-Propylbenzene 70 NE NE NE other 95-49-8 364 o-Chlorotoluene 100 NE NE NE Other 110-86-1 391 414 1 Pyridine Pyruvic Acid NE NE NE 7 Other SW414 NE NE NE NE NE NE NE 20000 NE NE NE Other Other Other Other other Other Other 7440-23-5 322 Sodium SW323 323 SpecCond (field) 307 petroleum aliphatic carbon fraction class C19 - C36 305 petroleum aliphatic carbon fraction class CS - C8 306 petroleum aliphatic carbon fraction class C9 - C18 308 petroleum aromatics carbon fraction class C9 - C22 NE NE NE SW307 10000 NE NE SW305 400 NE NE NE SW306 700 NE NE SW308 200 NE NE NE Page 10 of 11 NC Solid Waste Section Environmental Monitoring List Groundwater Protection Standards) DEQ 2 Calculated CAS RN i SWS ID a CHEMICAL NAME 211. 2L IMAC MCL GWP Std SW320 320 pH (field) 7.0 NE NE NE 95-63-6 372 Pseudocumene (1-2-4-trimethylbenzene) 400 NE NE NE 3689-24-5 392 Sulfotep NE NE NE NE SW325 325 Temp (oC) NE NE NE NE 135-98-8 362 sec-Butylbenzene 70 NE NE NE SW328 328 Top Of Casing (ft mean sea level) NE I NE NE NE SW425 425 Total BHC 0.02 NE NE NE SW436 436 Total Fatty Acids NE NE NE NE E-10195 357 Total Organic Carbon NE NE NE NE 98-06-6 363 tert-Butylbenzene 70 NE NE NE SW396 396 Total Organic Halides NE NE NE NE SW343 343 Total Suspended Solids NE NE NE NE SW411 _� 411 Total Well Depth (ft) NE NE NE NE SW330 330 Turbidity NE i NE NE NE NOTE: GWPSs as listed are current as of October 15, 2018 and are subject to change. Refer to originating sources for any changes. Reference List 4 Other 1 Groundwater Protection Standard (GWPS) - For compliance purposes, the applicable GWPS is the lower of the listed standards. 2 CAS RN = Chemical Abstract Service Registry Number. For listed contituents with no CAS, the SWS ID is used. 3 SWS ID = Solid Waste Section ID. Unique ID assigned by the Section. 4 Constituents Reference Lists APPENDIX I - Constituents for Detection Monitoring per 40 CFR Part 258 (7.1-2017 Edition) APPENDIX II -List of Hazardous Inorganic & Organic Constituents per 40 CFR Part 258 (7-1-2017 Edition). Appendix ll list includes all Appendix I constituents. C&D - Additional monitored constituents required for Construction & Demolition landfills (CDLFs) LEACHATE - Monitored constituents for leachate sampling as specified in permit conditions. other - other constituents, field testing, field measurements, or miscellaneous data that may be required by the Section. 5 ALL -1,4-Dioxane sampling required for all MSW, C&D, & Industrial landfills (active and closed) per SWS Memo dated May 29, 2018. Other Other Other Other Other Other Other Other Other Other Other Other Other GW Protection Standards References 2L - NC groundwater water standards per 15A NCAC 02L .0202 2L IMAC (Interim Maximum Allowable Concentrations) - Interim NC groundwater standards per 15A NCAC 02L .0202 MCL (Maximum Contaminant Level) - National primary drinking water standards per Safe Drinking Water Act under 40 CFR Part 141 NC GWP Std (NC Groundwater Protected Standard) - Groundwater value calculated by NC DEQ for constituents with no established 2L standard. Values are calculated using criteria 1 & 2 of the NC Groundwater standards and do not consider taste, odor, MCLs, MCLG, and secondary drinking water standards. Weblink for 40 CFR Part 258 Page 11 of 11 APPENDIX C Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling STATE OF NORTH CAROLINA DEPARTMENT OF ENVIRONMENT AND NATURAL RESOURCES DIVISION OF WASTE MANAGEMENT SOLID WASTE SECTION General Sampling Procedures The following guidance is provided to insure a consistent sampling approach so that sample collection activities at solid waste management facilities provide reliable data. Sampling must begin with an evaluation of facility information, historical environmental data and site geologic and hydrogeologic conditions. General sampling procedures are described in this document. Planning Begin sampling activities with planning and coordination. The party contracting with the laboratory is responsible for effectively communicating reporting requirements and evaluating data reliability as it relates to specific monitoring activities. Sample Collection Contamination Prevention a.) Take special effort to prevent cross contamination or environmental contamination when collecting samples. 1. If possible, collect samples from the least contaminated sampling location (or background sampling location, if applicable) to the most contaminated sampling location. 2. Collect the ambient or background samples first, and store them in separate ice chests or separate shipping containers within the same ice chest (e.g. untreated plastic bags). 3. Collect samples in flowing water at designated locations from upstream to downstream. b.) Do not store or ship highly contaminated samples (concentrated wastes, free product, etc.) or samples suspect of containing high concentrations of contaminants in the same ice chest or shipping containers with other environmental samples. 1. Isolate these sample containers by sealing them in separate, untreated plastic bags immediately after collecting, preserving, labeling, etc. 2. Use a clean, untreated plastic bag to line the ice chest or shipping container. c.) All sampling equipment should be thoroughly decontaminated and transported in a manner that does not allow it to become contaminated. Arrangements should be made ahead of time to decontaminate any sampling or measuring equipment that will be reused when taking samples from more than one well. Field decontamination of Rev 4-08 sampling equipment will be necessary before sampling each well to minimize the risk of cross contamination. Decontamination procedures should be included in reports as necessary. Certified pre -cleaned sampling equipment and containers may be used. When collecting aqueous samples, rinse the sample collection equipment with a portion of the sample water before taking the actual sample. Sample containers do not need to be rinsed. In the case of petroleum hydrocarbons, oil and grease, or containers with pre -measured preservatives, the sample containers cannot be rinsed. d.) Place all fuel -powered equipment away from, and downwind of, any site activities (e.g., purging, sampling, decontamination). 1. If field conditions preclude such placement (i.e., the wind is from the upstream direction in a boat), place the fuel source(s) as far away as possible from the sampling activities and describe the conditions in the field notes. 2. Handle fuel (i.e., filling vehicles and equipment) prior to the sampling day. If such activities must be performed during sampling, the personnel must wear disposable gloves. 3. Dispense all fuels downwind. Dispose of gloves well away from the sampling activities. Filling Out Sample Labels Fill out label, adhere to vial and collect sample. Print legibly with indelible ink. At a minimum, the label or tag should identify the sample with the following information: 1. Sample location and/or well number 2. Sample identification number 3. Date and time of collection 4. Analysis required/requested 5. Sampler's initials 6. Preservative(s) used, if any [i.e., HCI, Na2S203, NO3, ice, etc.] 7. Any other pertinent information for sample identification Sample Collection Order Unless field conditions justify other sampling regimens, collect samples in the following order: 1. Volatile Organics and Volatile Inorganics 2. Extractable Organics, Petroleum Hydrocarbons, Aggregate Organics and Oil and Grease 3. Total Metals 4. Inorganic Nonmetallics, Physical and Aggregate Properties, and Biologicals 5. Microbiological NOTE: If the pump used to collect groundwater samples cannot be used to collect volatile or extractable organics then collect all other parameters and withdraw the pump and tubing. Then collect the volatile and extractable organics. Rev 4-08 Health and Safety Implement all local, state, and federal requirements relating to health and safety. Follow all local, state and federal requirements pertaining to the storage and disposal of any hazardous or investigation derived wastes. a.) The Solid Waste Section recommends wearing protective gloves when conducting all sampling activities. 1. Gloves serve to protect the sample collector from potential exposure to sample constituents, minimize accidental contamination of samples by the collector, and preserve accurate tare weights on preweighed sample containers. 2. Do not let gloves come into contact with the sample or with the interior or lip of the sample container. Use clean, new, unpowdered and disposable gloves. Various types of gloves may be used as long as the construction materials do not contaminate the sample or if internal safety protocols require greater protection. 3. Note that certain materials that may potentially be present in concentrated effluent can pass through certain glove types and be absorbed in the skin. Many vendor catalogs provide information about the permeability of different gloves and the circumstances under which the glove material might be applicable. The powder in powdered gloves can contribute significant contamination. Powdered gloves are not recommended unless it can be demonstrated that the powder does not interfere with the sample analysis. 4. Change gloves after preliminary activities, after collecting all the samples at a single sampling point, if torn or used to handle extremely dirty or highly contaminated surfaces. Properly dispose of all used gloves as investigation derived wastes. b.) Properly manage all investigation derived waste (IDW). 5. To prevent contamination into previously uncontaminated areas, properly manage all IDW. This includes all water, soil, drilling mud, decontamination wastes, discarded personal protective equipment (PPE), etc. from site investigations, exploratory borings, piezometer and monitoring well installation, refurbishment, abandonment, and other investigative activities. Manage all IDW that is determined to be RCRA-regulated hazardous waste according to the local, state and federal requirements. 6. Properly dispose of IDW that is not a RCRA-regulated hazardous waste but is contaminated above the Department's Soil Cleanup Target Levels or the state standards and/or minimum criteria for ground water quality. If the drill cuttings/mud orpurged well water is contaminated with hazardous waste, contact the DWM Hazardous Waste Section (919-508-8400) for disposal options. Maintain all containers holding IDW in good condition. Periodically inspect the containers for damage and ensure that all required labeling (DOT, RCRA, etc.) are clearly visible. Rev 4-08 Sample Storage and Transport Store samples for transport carefully. Pack samples to prevent from breaking and to maintain a temperature of approximately 4 degrees Celsius (°C), adding ice if necessary. Transport samples to a North Carolina -certified laboratory as soon as possible. Avoid unnecessary handling of sample containers. Avoid heating (room temperature or above, including exposure to sunlight) or freezing of the sample containers. Reduce the time between sample collection and delivery to a laboratory whenever possible and be sure that the analytical holding times of your samples can be met by the laboratory. a.) A complete chain -of -custody (COC) form must be maintained to document all transfers and receipts of the samples. Be sure that the sample containers are labeled with the sample location and/or well number, sample identification, the date and time of collection, the analysis to be performed, the preservative added (if any), the sampler's initials, and any other pertinent information for sample identification. The labels should contain a unique identifier (i.e., unique well numbers) that can be traced to the COC form. The details of sample collection must be documented on the COC. The COC must include the following: 1. Description of each sample (including QA/QC samples) and the number of containers (sample location and identification) 2. Signature of the sampler 3. Date and time of sample collection 4. Analytical method to be performed 5. Sample type (i.e., water or soil) 6. Regulatory agency (i.e., NCDENR/DWM — SW Section) 7. Signatures of all persons relinquishing and receiving custody of the samples 8. Dates and times of custody transfers b.) Pack samples so that they are segregated by site, sampling location or by sample analysis type. When COC samples are involved, segregate samples in coolers by site. If samples from multiple sites will fit in one cooler, they may be packed in the same cooler with the associated field sheets and a single COC form for all. Coolers should not exceed a maximum weight of 50 lbs. Use additional coolers as necessary. All sample containers should be placed in plastic bags (segregated by analysis and location) and completely surrounded by ice. 1. Prepare and place trip blanks in an ice filled cooler before leaving for the field. 2. Segregate samples by analysis and place in sealable plastic bags. 3. Pack samples carefully in the cooler placing ice around the samples. 4. Review the COC. The COC form must accompany the samples to the laboratory. The trip blank(s) must also be recorded on the COC form. 5. Place completed COC form in a waterproof bag, sealed and taped under the lid of the cooler. 6. Secure shipping containers with strapping tape to avoid accidental opening. 7. For COC samples, a tamper -proof seal may also be placed over the cooler lid or over a bag or container containing the samples inside the shipping cooler. Rev 4-08 4 8. "COC" or "EMERG" should be written in indelible ink on the cooler seal to alert sample receipt technicians to priority or special handling samples. 9. The date and sample handler's signature must also be written on the COC seal. 10. Deliver the samples to the laboratory or ship by commercial courier. NOTE: If transport time to the laboratory is not long enough to allow samples to be cooled to 4° C, a temperature reading of the sample source must be documented as the field temperature on the CDC form. A downward trend in temperature will be adequate even if cooling to 4° C is not achieved. The field temperature should always be documented if there is any question as to whether samples will have time to cool to 4° C during shipment. Thermometers must be calibrated annually against an NIST traceable thermometer and documentation must be retained. Rev 4-08 Appendix A - Decontamination of Field Equipment Decontamination of personnel, sampling equipment, and containers - before and after sampling - must be used to ensure collection of representative samples and to prevent the potential spread of contamination. Decontamination of personnel prevents ingestion and absorption of contaminants. It must be done with a soap and water wash and deionized or distilled water rinse. Certified pre -cleaned sampling equipment and containers may also be used. All previously used sampling equipment must be properly decontaminated before sampling and between sampling locations. This prevents the introduction of contamination into uncontaminated samples and avoids cross -contamination of samples. Cross -contamination can be a significant problem when attempting to characterize extremely low concentrations of organic compounds or when working with soils that are highly contaminated. Clean, solvent -resistant gloves and appropriate protective equipment must be worn by persons decontaminating tools and equipment. Cleaning Reagents Recommendations for the types and grades of various cleaning supplies are outlined below. The recommended reagent types or grades were selected to ensure that the cleaned equipment is free from any detectable contamination. a.) Detergents: Use Liqui-Nox (or a non -phosphate equivalent) or Alconox (or equivalent). Liqui-Nox (or equivalent) is recommended by EPA, although Alconox (or equivalent) may be substituted if the sampling equipment will not be used to collect phosphorus or phosphorus containing compounds. b.) Solvents: Use pesticide grade isopropanol as the rinse solvent in routine equipment cleaning procedures. This grade of alcohol must be purchased from a laboratory supply vendor. Rubbing alcohol or other commonly available sources of isopropanol are not acceptable. Other solvents, such as acetone or methanol, may be used as the final rinse solvent if they are pesticide grade. However, methanol is more toxic to the environment and acetone may be an analyte of interest for volatile organics. 1. Do not use acetone if volatile organics are of interest 2. Containerize all methanol wastes (including rinses) and dispose as a hazardous waste. Pre -clean equipment that is heavily contaminated with organic analytes. Use reagent grade acetone and hexane or other suitable solvents. Use pesticide grade methylene chloride when cleaning sample containers. Store all solvents away from potential sources of contamination. c.) Analyte-Free Water Sources: Analyte-free water is water in which all analytes of interest and all interferences are below method detection limits. Maintain documentation (such as results from equipment blanks) to demonstrate the reliability and purity of analyte-free water source(s). The source of the water must meet the requirements of the analytical method and must be free from the analytes of interest. In general, the following water types are associated with specific analyte groups: 1. Milli-Q (or equivalent polished water): suitable for all analyses. Rev 4-08 2. Organic free: suitable for volatile and extractable organics. 3. Deionized water: may not be suitable for volatile and extractable organics. 4. Distilled water: not suitable for volatile and extractable organics, metals or ultratrace metals. Use analyte-free water for blank preparation and the final decontamination water rinse. In order to minimize long-term storage and potential leaching problems, obtain or purchase analyte-free water just prior to the sampling event. If obtained from a source (such as a laboratory), fill the transport containers and use the contents for a single sampling event. Empty the transport container(s) at the end of the sampling event. Discard any analyte-free water that is transferred to a dispensing container (such as a wash bottle or pump sprayer) at the end of each sampling day. d.) Acids: 1. Reagent Grade Nitric Acid: 10 - 15% (one volume concentrated nitric acid and five volumes deionized water). Use for the acid rinse unless nitrogen components (e.g., nitrate, nitrite, etc.) are to be sampled. If sampling for ultra -trace levels of metals, use an ultra -pure grade acid. 2. Reagent Grade Hydrochloric Acid: 10% hydrochloric acid (one volume concentrated hydrochloric and three volumes deionized water). Use when nitrogen components are to be sampled. 3. If samples for both metals and the nitrogen -containing components are collected with the equipment, use the hydrochloric acid rinse, or thoroughly rinse with hydrochloric acid after a nitric acid rinse. If sampling for ultra trace levels of metals, use an ultra -pure grade acid. 4. Freshly prepared acid solutions may be recycled during the sampling event or cleaning process. Dispose of any unused acids according to local ordinances. Reagent Storage Containers The contents of all containers must be clearly marked. a.) Detergents: 1. Store in the original container or in a HDPE or PP container. b.) Solvents: 1. Store solvents to be used for cleaning or decontamination in the original container until use in the field. If transferred to another container for field use, use either a glass or Teflon container. 2. Use dispensing containers constructed of glass, Teflon or stainless steel. Note: If stainless steel sprayers are used, any gaskets that contact the solvents must be constructed of inert materials. c.) Analyte-Free Water: 1. Transport in containers appropriate for the type of water stored. If the water is commercially purchased (e.g., grocery store), use the original containers when transporting the water to the field. Containers made of glass, Teflon, polypropylene or HDPE are acceptable. 2. Use glass or Teflon to transport organic -free sources of water on -site. Polypropylene or HDPE may be used, but are not recommended. Rev 4-08 7 3. Dispense water from containers made of glass, Teflon, HDPE or polypropylene. 4. Do not store water in transport containers for more than three days before beginning a sampling event. 5. If working on a project that has oversight from EPA Region 4, use glass containers for the transport and storage of all water. 6. Store and dispense acids using containers made of glass, Teflon or plastic. General Requirements a.) Prior to use, clean/decontaminate all sampling equipment (pumps, tubing, lanyards, split spoons, etc.) that will be exposed to the sample. b.) Before installing, clean (or obtain as certified pre -cleaned) all equipment that is dedicated to a single sampling point and remains in contact with the sample medium (e.g., permanently installed groundwater pump). If you use certified pre -cleaned equipment no cleaning is necessary. 1. Clean this equipment any time it is removed for maintenance or repair. 2. Replace dedicated tubing if discolored or damaged. c.) Clean all equipment in a designated area having a controlled environment (house, laboratory, or base of field operations) and transport it to the field, pre -cleaned and ready to use, unless otherwise justified. d.) Rinse all equipment with water after use, even if it is to be field -cleaned for other sites. Rinse equipment used at contaminated sites or used to collect in -process (e.g., untreated or partially treated wastewater) samples immediately with water. e.) Whenever possible, transport sufficient clean equipment to the field so that an entire sampling event can be conducted without the need for cleaning equipment in the field. f.) Segregate equipment that is only used once (i.e., not cleaned in the field) from clean equipment and return to the in-house cleaning facility to be cleaned in a controlled environment. g.) Protect decontaminated field equipment from environmental contamination by securely wrapping and sealing with one of the following: 1. Aluminum foil (commercial grade is acceptable) 2. Untreated butcher paper 3. Clean, untreated, disposable plastic bags. Plastic bags may be used for all analyte groups except volatile and extractable organics. Plastic bags may be used for volatile and extractable organics, if the equipment is first wrapped in foil or butcher paper, or if the equipment is completely dry. Cleaning Sample Collection Equipment a.) On-Site/In-Field Cleaning — Cleaning equipment on -site is not recommended because environmental conditions cannot be controlled and wastes (solvents and acids) must be containerized for proper disposal. 1. Ambient temperature water may be substituted in the hot, sudsy water bath and hot water rinses. NOTE: Properly dispose of all solvents and acids. Rev 4-08 2. Rinse all equipment with water after use, even if it is to be field -cleaned for other sites. 3. Immediately rinse equipment used at contaminated sites or used to collect in -process (e.g., untreated or partially treated wastewater) samples with water. b.) Heavily Contaminated Equipment - In order to avoid contaminating other samples, isolate heavily contaminated equipment from other equipment and thoroughly decontaminate the equipment before further use. Equipment is considered heavily contaminated if it: 1. Has been used to collect samples from a source known to contain significantly higher levels than background. 2. Has been used to collect free product. 3. Has been used to collect industrial products (e.g., pesticides or solvents) or their byproducts. NOTE: Cleaning heavily contaminated equipment in the field is not recommended. c.) On -Site Procedures: 1. Protect all other equipment, personnel and samples from exposure by isolating the equipment immediately after use. 2. At a minimum, place the equipment in a tightly sealed, untreated, plastic bag. 3. Do not store or ship the contaminated equipment next to clean, decontaminated equipment, unused sample containers, or filled sample containers. 4. Transport the equipment back to the base of operations for thorough decontamination. 5. If cleaning must occur in the field, document the effectiveness of the procedure, collect and analyze blanks on the cleaned equipment. d.) Cleaning Procedures: 1. If organic contamination cannot be readily removed with scrubbing and a detergent solution, pre -rinse equipment by thoroughly rinsing or soaking the equipment in acetone. 2. Use hexane only if preceded and followed by acetone. 3. In extreme cases, it may be necessary to steam clean the field equipment before proceeding with routine cleaning procedures. 4. After the solvent rinses (and/or steam cleaning), use the appropriate cleaning procedure. Scrub, rather than soak, all equipment with sudsy water. If high levels of metals are suspected and the equipment cannot be cleaned without acid rinsing, soak the equipment in the appropriate acid. Since stainless steel equipment should not be exposed to acid rinses, do not use stainless steel equipment when heavy metal contamination is suspected or present. 5. If the field equipment cannot be cleaned utilizing these procedures, discard unless further cleaning with stronger solvents and/or oxidizing solutions is effective as evidenced by visual observation and blanks. 6. Clearly mark or disable all discarded equipment to discourage use. Rev 4-08 e.) General Cleaning - Follow these procedures when cleaning equipment under controlled conditions. Check manufacturer's instructions for cleaning restrictions and/or recommendations. 1. Procedure for Teflon, stainless steel and glass sampling equipment: This procedure must be used when sampling for ALL analyte groups. (Extractable organics, metals, nutrients, etc. or if a single decontamination protocol is desired to clean all Teflon, stainless steel and glass equipment.) Rinse equipment with hot tap water. Soak equipment in a hot, sudsy water solution (Liqui-Nox or equivalent). If necessary, use a brush to remove particulate matter or surface film. Rinse thoroughly with hot tap water. If samples for trace metals or inorganic analytes will be collected with the equipment that is not stainless steel, thoroughly rinse (wet all surfaces) with the appropriate acid solution. Rinse thoroughly with analyte-free water. Make sure that all equipment surfaces are thoroughly flushed with water. If samples for volatile or extractable organics will be collected, rinse with isopropanol. Wet equipment surfaces thoroughly with free - flowing solvent. Rinse thoroughly with analyte-free water. Allow to air dry. Wrap and seal as soon as the equipment has air-dried. If isopropanol is used, the equipment may be air-dried without the final analyte-free water rinse; however, the equipment must be completely dry before wrapping or use. Wrap clean sampling equipment according to the procedure described above. 2. General Cleaning Procedure for Plastic Sampling Equipment: Rinse equipment with hot tap water. Soak equipment in a hot, sudsy water solution (Liqui-Nox or equivalent). If necessary, use a brush to remove particulate matter or surface film. Rinse thoroughly with hot tap water. Thoroughly rinse (wet all surfaces) with the appropriate acid solution. Check manufacturer's instructions for cleaning restrictions and/or recommendations. Rinse thoroughly with analyte-free water. Be sure that all equipment surfaces are thoroughly flushed. Allow to air dry as long as possible. Wrap clean sampling equipment according to the procedure described above. Rev 4-08 10 Appendix B - Collecting Soil Samples Soil samples are collected for a variety of purposes. A methodical sampling approach must be used to assure that sample collection activities provide reliable data. Sampling must begin with an evaluation of background information, historical data and site conditions. Soil Field Screening Procedures Field screening is the use of portable devices capable of detecting petroleum contaminants on a real-time basis or by a rapid field analytical technique. Field screening should be used to help assess locations where contamination is most likely to be present. When possible, field -screening samples should be collected directly from the excavation or from the excavation equipment's bucket. If field screening is conducted only from the equipment's bucket, then a minimum of one field screening sample should be collected from each 10 cubic yards of excavated soil. If instruments or other observations indicate contamination, soil should be separated into stockpiles based on apparent degrees of contamination. At a minimum, soil suspected of contamination must be segregated from soil observed to be free of contamination. a.) Field screening devices — Many field screen instruments are available for detecting contaminants in the field on a rapid or real-time basis. Acceptable field screening instruments must be suitable for the contaminant being screened. The procdedure for field screening using photoionization detectors (PIDs) and flame ionization detectors (FIDs) is described below. If other instruments are used, a description of the instrument or method and its intended use must be provided to the Solid Waste Section. Whichever field screening method is chosen, its accuracy must be verified throughout the sampling process. Use appropriate standards that match the use intended for the data. Unless the Solid Waste Section indicates otherwise, wherever field screening is recommended in this document, instrumental or analytical methods of detection must be used, not olfactory or visual screening methods. b.) Headspace analytical screening procedure for filed screening (semi -quantitative field screening) - The most commonly used field instruments for Solid Waste Section site assessments are FIDs and PIDs. When using FIDs and PIDs, use the following headspace screening procedure to obtain and analyze field -screening samples: 1. Partially fill (one-third to one-half) a clean jar or clean ziplock bag with the sample to be analyzed. The total capacity of the jar or bag may not be less than eight ounces (app. 250 ml), but the container should not be so large as to allow vapor diffusion and stratification effects to significantly affect the sample. 2. If the sample is collected from a spilt -spoon, it must be transferred to the jar or bag for headspace analysis immediately after opening the split - spoon. If the sample is collected from an excavation or soil pile, it must be collected from freshly uncovered soil. Rev 4-08 11 3. If a jar is used, it must be quickly covered with clean aluminum foil or a jar lid; screw tops or thick rubber bands must be used to tightly seal the jar. If a zip lock bag is used, it must be quickly sealed shut. 4. Headspace vapors must be allowed to develop in the container for at least 10 minutes but no longer than one hour. Containers must be shaken or agitated for 15 seconds at the beginning and the end of the headspace development period to assist volatilization. Temperatures of the headspace must be warmed to at least 5° C (approximately 40' F) with instruments calibrated for the temperature used. 5. After headspace development, the instrument sampling probe must be inserted to a point about one-half the headspace depth. The container opening must be minimized and care must be taken to avoid the uptake of water droplets and soil particulates. 6. After probe insertion, the highest meter reading must be taken and recorded. This will normally occur between two and five seconds after probe insertion. If erratic meter response occurs at high organic vapor concentrations or conditions of elevated headspace moisture, a note to that effect must accompany the headspace data. 7. All field screening results must be documented in the field record or log book. Soil Sample Collection Procedures for Laboratory Samples The number and type of laboratory samples collected depends on the purpose of the sampling activity. Samples analyzed with field screening devices may not be substituted for required laboratory samples. a.) General Sample Collection - When collecting samples from potentially contaminated soil, care should be taken to reduce contact with skin or other parts of the body. Disposable gloves should be worn by the sample collector and should be changed between samples to avoid cross -contamination. Soil samples should be collected in a manner that causes the least disturbance to the internal structure of the sample and reduces its exposure to heat, sunlight and open air. Likewise, care should be taken to keep the samples from being contaminated by other materials or other samples collected at the site. When sampling is to occur over an extended period of time, it is necessary to insure that the samples are collected in a comparable manner. All samples must be collected with disposable or clean tools that have been decontaminated. Disposable gloves must be worn and changed between sample collections. Sample containers must be filled quickly. Soil samples must be placed in containers in the order of volatility, for example, volatile organic aromatic samples must be taken first, organics next, then heavier range organics, and finally soil classification samples. Containers must be quickly and adequately sealed, and rims must be cleaned before tightening lids. Tape may be used only if known not to affect sample analysis. Sample containers must be clearly labeled. Containers must immediately be preserved according to procedures in this Section. Unless specified Rev 4-08 12 otherwise, at a minimum, the samples must be immediately cooled to 4 ± 2°C and this temperature must be maintained throughout delivery to the laboratory. b.) Surface Soil Sampling - Surface soil is generally classified as soil between the ground surface and 6-12 inches below ground surface. Remove leaves, grass and surface debris from the area to be sampled. Select an appropriate, pre -cleaned sampling device and collect the sample. Transfer the sample to the appropriate sample container. Clean the outside of the sample container to remove excess soil. Label the sample container, place on wet ice to preserve at 4°C, and complete the field notes. c.) Subsurface Soil Sampling — The interval begins at approximately 12 inches below ground surface. Collect samples for volatile organic analyses. For other analyses, select an appropriate, pre -cleaned sampling device and collect the sample. Transfer the sample to the appropriate sample container. Clean the outside of the sample container to remove excess soil. Label the sample container, place on wet ice to preserve at 4°C, and complete field notes. d.) Equipment for Reachingthe Appropriate Soil Sampling Depth - Samples may be collected using a hollow stem soil auger, direct push, Shelby tube, split -spoon sampler, or core barrel. These sampling devices may be used as long as an effort is made to reduce the loss of contaminants through volatilization. In these situations, obtain a sufficient volume of so the samples can be collected without volatilization and disturbance to the internal structure of the samples. Samples should be collected from cores of the soil. Non -disposable sampling equipment must be decontaminated between each sample location. NOTE: If a confining layer has been breached during sampling, grout the hole to land. e.) Equipment to Collect Soil Samples - Equipment and materials that may be used to collect soil samples include disposable plastic syringes and other "industry -standard" equipment and materials that are contaminant -free. Non -disposable sampling equipment must be decontaminated between each sample location. Rev 4-08 13 Appendix C - Collecting Groundwater Samples Groundwater samples are collected to identify, investigate, assess and monitor the concentration of dissolved contaminant constituents. To properly assess groundwater contamination, first install sampling points (monitoring wells, etc.) to collect groundwater samples and then perform specific laboratory analyses. All monitoring wells should be constructed in accordance with 15A NCAC 2C .0100 and sampled as outlined in this section. Groundwater monitoring is conducted using one of two methods: 1. Portable Monitoring: Monitoring that is conducted using sampling equipment that is discarded between sampling locations. Equipment used to collect a groundwater sample from a well such as bailers, tubing, gloves, and etc. are disposed of after sample collection. A new set of sampling equipment is used to collect a groundwater sample at the next monitor well. 2. Dedicated Monitoriniz: Monitoring that utilizes permanently affixed down -well and well head components that are capped after initial set-up. Most dedicated monitoring systems are comprised of an in -well submersible bladder pump, with air supply and sample discharge tubing, and an above -ground driver/controller for regulation of flow rates and volumes. The pump and all tubing housed within the well should be composed of Teflon or stainless steel components. This includes seals inside the pump, the pump body, and fittings used to connect tubing to the pump. Because ground water will not be in contact with incompatible constituents and because the well is sealed from the surface, virtually no contamination is possible from intrinsic sources during sampling and between sampling intervals. All dedicated monitoring systems must be approved by the Solid Waste Section before installation. Groundwater samples may be collected from a number of different configurations. Each configuration is associated with a unique set of sampling equipment requirements and techniques: 1. Wells without Plumbing: These wells require equipment to be brought to the well to purge and sample unless dedicated equipment is placed in the well. 2. Wells with In -Place Plumbing: Wells with in -place plumbing do not require equipment to be brought to the well to purge and sample. In -place plumbing is generally considered permanent equipment routinely used for purposes other than purging and sampling, such as for water supply. 3. Air Strippers or Remedial Systems: These types of systems are installed as remediation devices. Rev 4-08 14 Groundwater Sample Preparation The type of sample containers used depends on the type of analysis performed. First, determine the type(s) of contaminants expected and the proper analytical method(s). Be sure to consult your selected laboratory for its specific needs and requirements prior to sampling. Next, prepare the storage and transport containers (ice chest, etc.) before taking any samples so that each sample can be placed in a chilled environment immediately after collection. Use groundwater purging and sampling equipment constructed of only non -reactive, non - leachable materials that are compatible with the environment and the selected analytes. In selecting groundwater purging and sampling equipment, give consideration to the depth of the well, the depth to groundwater, the volume of water to be evacuated, the sampling and purging technique, and the analytes of interest. Additional supplies, such as reagents and preservatives, may be necessary. All sampling equipment (bailers, tubing, containers, etc.) must be selected based on its chemical compatibility with the source being sampled (e.g., water supply well, monitoring well) and the contaminants potentially present. a.) Pumps - All pumps or pump tubing must be lowered and retrieved from the well slowly and carefully to minimize disturbance to the formation water. This is especially critical at the air/water interface. 1. Above -Ground Pumps • Variable Speed Peristaltic Pump: Use a variable speed peristaltic pump to purge groundwater from wells when the static water level in the well is no greater than 20- 25 feet below land surface (BLS). If the water levels are deeper than 18-20 feet BLS, the pumping velocity will decrease. A variable speed peristaltic pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. Most analyte groups can be sampled with a peristaltic pump if the tubing and pump configurations are appropriate. • Variable Speed Centrifugal Pump: A variable speed centrifugal pump can be used to purge groundwater from 2-inch and larger internal diameter wells. Do not use this type of pump to collect groundwater samples. When purging is complete, do not allow the water that remains in the tubing to fall back into the well. Install a check valve at the end of the purge tubing. 2. Submersible Pumps • Variable Speed Electric Submersible Pump: A variable speed submersible pump can be used to purge and sample groundwater from 2-inch and larger internal diameter wells. A variable speed submersible pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. The pump housing, fittings, check valves and associated hardware must be constructed of stainless steel. All other materials must be Rev 4-08 15 b.) Bailers compatible with the analytes of interest. Install a check valve at the output side of the pump to prevent backflow. If purging and sampling for organics, the entire length of the delivery tube must be Teflon, polyethylene or polypropylene (PP) tubing; the electrical cord must be sealed in Teflon, polyethylene or PP and any cabling must be sealed in Teflon, polyethylene or PP, or be constructed of stainless steel; and all interior components that contact the sample water (impeller, seals, gaskets, etc.) must be constructed of stainless steel or Teflon. 3. Variable Speed Bladder Pump: A variable speed, positive displacement, bladder pump can be used to purge and sample groundwater from 3/4-inch and larger internal diameter wells. • A variable speed bladder pump can be used for normal purging and sampling, and sampling low permeability aquifers or formations. • The bladder pump system is composed of the pump, the compressed air tubing, the water discharge tubing, the controller and a compressor, or a compressed gas supply. • The pump consists of a bladder and an exterior casing or pump body that surrounds the bladder and two (2) check valves. These parts can be composed of various materials, usually combinations of polyvinyl chloride (PVC), Teflon, polyethylene, PP and stainless steel. Other materials must be compatible with the analytes of interest. • If purging and sampling for organics, the pump body must be constructed of stainless steel. The valves and bladder must be Teflon, polyethylene or PP; the entire length of the delivery tube must be Teflon, polyethylene or PP; and any cabling must be sealed in Teflon, polyethylene or PP, or be constructed of stainless steel. • Permanently installed pumps may have a PVC pump body as long as the pump remains in contact with the water in the well. I. Purging: Bailers must be used with caution because improper bailing can cause changes in the chemistry of the water due to aeration and loosening particulate matter in the space around the well screen. Use a bailer if there is non -aqueous phase liquid (free product) in the well or if non -aqueous phase liquid is suspected to be in the well. 2. Sampling: Bailers must be used with caution. 3. Construction and Type: Bailers must be constructed of materials compatible with the analytes of interest. Stainless steel, Teflon, rigid medical grade PVC, polyethylene and PP bailers may be used to sample all analytes. Use disposable bailers when sampling grossly contaminated sample sources. NCDENR recommends using dual check valve bailers when collecting samples. Use bailers with a controlled flow bottom to collect volatile organic samples. Rev 4-08 16 4. Contamination Prevention: Keep the bailer wrapped (foil, butcher paper, etc.) until just before use. Use protective gloves to handle the bailer once it is removed from its wrapping. Handle the bailer by the lanyard to minimize contact with the bailer surface. c.) Lans 1. Lanyards must be made of non -reactive, non -leachable material. They may be cotton twine, nylon, stainless steel, or may be coated with Teflon, polyethylene or PP. 2. Discard cotton twine, nylon, and non -stainless steel braided lanyards after sampling each monitoring well. 3. Decontaminate stainless steel, coated Teflon, polyethylene and PP lanyards between monitoring wells. They do not need to be decontaminated between purging and sampling operations. Water Level and Purge Volume Determination The amount of water that must be purged from a well is determined by the volume of water and/or field parameter stabilization. a.) General Equipment Considerations - Selection of appropriate purging equipment depends on the analytes of interest, the well diameter, transmissivity of the aquifer, the depth to groundwater, and other site conditions. 1. Use of a pump to purge the well is recommended unless no other equipment can be used or there is non -aqueous phase liquid in the well, or non -aqueous phase liquid is suspected to be in the well. 2. Bailers must be used with caution because improper bailing: • Introduces atmospheric oxygen, which may precipitate metals (i.e., iron) or cause other changes in the chemistry of the water in the sample (i.e., pH). • Agitates groundwater, which may bias volatile and semi - volatile organic analyses due to volatilization. • Agitates the water in the aquifer and resuspends fine particulate matter. • Surges the well, loosening particulate matter in the annular space around the well screen. • May introduce dirt into the water column if the sides of the casing wall are scraped. NOTE: It is critical for bailers to be slowly and gently immersed into the top of the water column, particularly during the final stages of purging. This minimizes turbidity and disturbance of volatile organic constituents. b.) Initial Inspection 1. Remove the well cover and remove all standing water around the top of the well casing (manhole) before opening the well. 2. Inspect the exterior protective casing of the monitoring well for damage. Document the results of the inspection if there is a problem. 3. It is recommended that you place a protective covering around the well head. Replace the covering if it becomes soiled or ripped. Rev 4-08 17 4. Inspect the well lock and determine whether the cap fits tightly. Replace the cap if necessary. c.) Water Level Measurements - Use an electronic probe or chalked tape to determine the water level. Decontaminate all equipment before use. Measure the depth to groundwater from the top of the well casing to the nearest 0.01 foot. Always measure from the same reference point or survey mark on the well casing. Record the measurement. I. Electronic Probe: Decontaminate all equipment before use. Follow the manufacturer's instructions for use. Record the measurement. 2. Chalked Line Method: Decontaminate all equipment before use. Lower chalked tape into the well until the lower end is in the water. This is usually determined by the sound of the weight hitting the water. Record the length of the tape relative to the reference point. Remove the tape and note the length of the wetted portion. Record the length. Determine the depth to water by subtracting the length of the wetted portion from the total length. Record the result. d.) Water Column Determination - To determine the length of the water column, subtract the depth to the top of the water column from the total well depth (or gauged well depth if silting has occurred). The total well depth depends on the well construction. If gauged well depth is used due to silting, report total well depth also. Some wells may be drilled in areas of sinkhole, karst formations or rock leaving an open borehole. Attempt to find the total borehole depth in cases where there is an open borehole below the cased portion. e.) Well Water Volume - Calculate the total volume of water, in gallons, in the well using the following equation: V = (0.041)d x d x h Where: V = volume in gallons d = well diameter in inches h = height of the water column in feet The total volume of water in the well may also be determined with the following equation by using a casing volume per foot factor (Gallons per Foot of Water) for the appropriate diameter well: V = [Gallons per Foot of Water] x h Where: V = volume in gallons h = height of the water column in feet Record all measurements and calculations in the field records. f.) Purging Equipment Volume - Calculate the total volume of the pump, associated tubing and flow cell (if used), using the following equation: V= p + ((0.041)d x dx 1)+fc Where: V = volume in gallons p = volume of pump in gallons d = tubing diameter in inches 1= length of tubing in feet Rev 4-08 18 fc = volume of flow cell in gallons g.) If the groundwater elevation data are to be used to construct groundwater elevation contour maps, all water level measurements must be taken within the same 24 hour time interval when collecting samples from multiple wells on a site, unless a shorter time period is required. If the site is tidally influenced, complete the water level measurements within the time frame of an incoming or outgoing tide. Well Purging Techniques The selection of the purging technique and equipment is dependent on the hydrogeologic properties of the aquifer, especially depth to groundwater and hydraulic conductivity. a.) Measuring the Purge Volume - The volume of water that is removed during purging must be recorded. Therefore, you must measure the volume during the purging operation. 1. Collect the water in a graduated container and multiply the number of times the container was emptied by the volume of the container, OR 2. Estimate the volume based on pumping rate. This technique may be used only if the pumping rate is constant. Determine the pumping rate by measuring the amount of water that is pumped for a fixed period of time, or use a flow meter. • Calculate the amount of water that is discharged per minute: D = Measured Amount/Total Time In Minutes • Calculate the time needed to purge one (1) well volume or one (1) purging equipment volume: Time = V/D Where: V = well volume or purging equipment volume D = discharge rate • Make new measurements each time the pumping rate is changed. 3. Use a totalizing flow meter. • Record the reading on the totalizer prior to purging. • Record the reading on the totalizer at the end of purging. • To obtain the volume purged, subtract the reading on the totalizer prior to purging from the reading on the totalizer at the end of purging. • Record the times that purging begins and ends in the field records. b.) Purging Measurement Frequency - When purging a well that has the well screen fully submerged and the pump or intake tubing is placed within the well casing above the well screen or open hole, purge a minimum of one (1) well volume prior to collecting measurements of the field parameters. Allow at least one quarter (1/4) well volume to purge between subsequent measurements. When purging a well that has the pump or intake tubing placed within a fully submerged well screen or open hole, purge until the water level has stabilized (well recovery rate equals the purge rate), then purge a minimum of one (1) volume of the pump, associated tubing and flow cell (if used) prior to collecting measurements of the field parameters. Take measurements of the field parameters no sooner than two (2) to three (3) minutes apart. Purge at least Rev 4-08 19 three (3) volumes of the pump, associated tubing and flow cell, if used, prior to collecting a sample. When purging a well that has a partially submerged well screen, purge a minimum of one (1) well volume prior to collecting measurements of the field parameters. Take measurements of the field parameters no sooner than two (2) to three (3) minutes apart. c.) Purging ompletion - Wells must be adequately purged prior to sample collection to ensure representation of the aquifer formation water, rather than stagnant well water. This may be achieved by purging three volumes from the well or by satisfying any one of the following three purge completion criteria: 1.) Three (3) consecutive measurements in which the three (3) parameters listed below are within the stated limits, dissolved oxygen is no greater than 20 percent of saturation at the field measured temperature, and turbidity is no greater than 20 Nephelometric Turbidity Units (NTUs). • Temperature: + 0.2° C • pH: + 0.2 Standard Units • Specific Conductance: + 5.0% of reading Document and report the following, as applicable. The last four items only need to be submitted once: • Purging rate. • Drawdown in the well, if any. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. 2.) If it is impossible to get dissolved oxygen at or below 20 percent of saturation at the field measured temperature or turbidity at or below 20 NTUs, then three (3) consecutive measurements of temperature, pH, specific conductance and the parameter(s) dissolved oxygen and/or turbidity that do not meet the requirements above must be within the limits below. The measurements are: • Temperature: + 0.2° C • pH: + 0.2 Standard Units • Specific Conductance: + 5.0% of reading • Dissolved Oxygen: + 0.2 mg/L or 10%, whichever is greater • Turbidity: + 5 NTUs or 10%, whichever is greater Additionally, document and report the following, as applicable, except that the last four(4) items only need to be submitted once: • Purging rate. • Drawdown in the well, if any. • A description of conditions at the site that may cause the dissolved oxygen to be high and/or dissolved oxygen measurements made within the screened or open hole portion of the well with a downhole dissolved oxygen probe. Rev 4-08 20 • A description of conditions at the site that may cause the turbidity to be high and any procedures that will be used to minimize turbidity in the future. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. 3.) If after five (5) well volumes, three (3) consecutive measurements of the field parameters temperature, pH, specific conductance, dissolved oxygen, and turbidity are not within the limits stated above, check the instrument condition and calibration, purging flow rate and all tubing connections to determine if they might be affecting the ability to achieve stable measurements. It is at the discretion of the consultant/contractor whether or not to collect a sample or to continue purging. Further, the report in which the data are submitted must include the following, as applicable. The last four (4) items only need to be submitted once. • Purging rate. • Drawdown in the well, if any. • A description of conditions at the site that may cause the Dissolved Oxygen to be high and/or Dissolved Oxygen measurements made within the screened or open hole portion of the well with a downhole dissolved oxygen probe. • A description of conditions at the site that may cause the turbidity to be high and any procedures that will be used to minimize turbidity in the future. • A description of the process and the data used to design the well. • The equipment and procedure used to install the well. • The well development procedure. • Pertinent lithologic or hydrogeologic information. If wells have previously and consistently purged dry, and the current depth to groundwater indicates that the well will purge dry during the current sampling event, minimize the amount of water removed from the well by using the same pump to purge and collect the sample: • Place the pump or tubing intake within the well screened interval. • Use very small diameter Teflon, polyethylene or PP tubing and the smallest possible pump chamber volume. This will minimize the total volume of water pumped from the well and reduce drawdown. • Select tubing that is thick enough to minimize oxygen transfer through the tubing walls while pumping. Rev 4-08 21 • Pump at the lowest possible rate (100 mL/minute or less) to reduce drawdown to a minimum. • Purge at least two (2) volumes of the pumping system (pump, tubing and flow cell, if used). • Measure pH, specific conductance, temperature, dissolved oxygen and turbidity, then begin to collect the samples. Collect samples immediately after purging is complete. The time period between completing the purge and sampling cannot exceed six hours. If sample collection does not occur within one hour of purging completion, re -measure the five field parameters: temperature, pH, specific conductance, dissolved oxygen and turbidity, just prior to collecting the sample. If the measured values are not within 10 percent of the previous measurements, re -purge the well. The exception is "dry" wells. d.) Lanyards 1. Securely fasten lanyards, if used, to any downhole equipment (bailers, pumps, etc.). 2. Use bailer lanyards in such a way that they do not touch the ground surface. Wells Without Plumbing a.) Tubin /gip Placement 1. If attempting to minimize the volume of purge water, position the intake hose or pump at the midpoint of the screened or open hole interval. 2. If monitoring well conditions do not allow minimizing of the purge water volume, position the pump or intake hose near the top of the water column. This will ensure that all stagnant water in the casing is removed. 3. If the well screen or borehole is partially submerged, and the pump will be used for both purging and sampling, position the pump midway between the measured water level and the bottom of the screen. Otherwise, position the pump or intake hose near the top of the water column. b.) Non -dedicated (portable) pumps 1. Variable Speed Peristaltic Pump • Wear sampling gloves to position the decontaminated pump and tubing. • Attach a short section of tubing to the discharge side of the pump and into a graduated container. • Attach one end of a length of new or precleaned tubing to the pump head flexible hose. • Place the tubing as described in one of the options listed above. • Change gloves before beginning to purge. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. Rev 4-08 22 • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells (see Appendix C) or if precleaned tubing is used for each well, only the pump. 2. Variable Speed Centrifugal Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Place the decontaminated suction hose so that water is always pumped from the top of the water column. • Change gloves before beginning to purge. • Equip the suction hose with a foot valve to prevent purge water from re-entering the well. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing at the approximate rate of drawdown so that the water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or if precleaned tubing is used for each well, only the pump. 3. Variable Speed Electric Submersible Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Carefully position the decontaminated pump. Rev 4-08 23 • Change gloves before beginning to purge. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing or pump at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or only the pump if precleaned tubing is used for each well. 4. Variable Speed Bladder Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves to position the decontaminated pump and tubing. • Attach the tubing and carefully position the pump. • Change gloves before beginning purging. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • To minimize drawdown, adjust the purging rate so that it is equivalent to the well recovery rate. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdrawal rate with the recharge rate. • If the water table continues to drop during pumping, lower the tubing or pump at the approximate rate of drawdown so that water is removed from the top of the water column. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. • Decontaminate the pump and tubing between wells or if precleaned tubing is used for each well, only the pump. c.) Dedicated Portable Pumps 1. Variable Speed Electric Submersible Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves. Rev 4-08 24 • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdraw with the recharge rate. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. 2. Variable Speed Bladder Pump • Position fuel powered equipment downwind and at least 10 feet from the well head. Make sure that the exhaust faces downwind. • Wear sampling gloves. • Measure the depth to groundwater at frequent intervals. • Record these measurements. • Adjust the purging rate so that it is equivalent to the well recovery rate to minimize drawdown. • If the purging rate exceeds the well recovery rate, reduce the pumping rate to balance the withdraw with the recharge rate. • Record the purging rate each time the rate changes. • Measure the purge volume. • Record this measurement. 3. Bailers - Using bailers for purging is not recommended unless care is taken to use proper bailing technique, or if free product is present in the well or suspected to be in the well. • Minimize handling the bailer as much as possible. • Wear sampling gloves. • Remove the bailer from its protective wrapping just before use. • Attach a lanyard of appropriate material. • Use the lanyard to move and position the bailer. • Lower and retrieve the bailer slowly and smoothly. • Lower the bailer carefully into the well to a depth approximately a foot above the water column. • When the bailer is in position, lower the bailer into the water column at a rate of 2 cm/sec until the desired depth is reached. • Do not lower the top of the bailer more than one (1) foot below the top of the water table so that water is removed from the top of the water column. • Allow time for the bailer to fill with aquifer water as it descends into the water column. Rev 4-08 25 • Carefully raise the bailer. Retrieve the bailer at the same rate of 2 cm/sec until the bottom of the bailer has cleared to top of the water column. • Measure the purge volume. • Record the volume of the bailer. • Continue to carefully lower and retrieve the bailer as described above until the purging is considered complete, based on either the removal of 3 well volumes. • Remove at least one (1) well volume before collecting measurements of the field parameters. Take each subsequent set of measurements after removing at least one quarter (1/4) well volume between measurements. Groundwater Sampling Techniques a.) Purge wells. b.) Replace protective covering around the well if it is soiled or torn after completing purging operations. c.) Equipment Considerations 1. The following pumps are approved to collect volatile organic samples: • Stainless steel and Teflon variable speed submersible PUMPS • Stainless steel and Teflon or polyethylene variable speed bladder pumps • Permanently installed PVC bodied pumps (As long as the pump remains in contact with the water in the well at all times) 2. Collect sample from the sampling device and store in sample container. Do not use intermediate containers. 3. To avoid contamination or loss of analytes from the sample, handle sampling equipment as little as possible and minimize equipment exposure to the sample. 4. To reduce chances of cross -contamination, use dedicated equipment whenever possible. "Dedicated" is defined as equipment that is to be used solely for one location for the life of that equipment (e.g., permanently mounted pump). Purchase dedicated equipment with the most sensitive analyte of interest in mind. • Clean or make sure dedicated pumps are clean before installation. They do not need to be cleaned prior to each use, but must be cleaned if they are withdrawn for repair or servicing. • Clean or make sure any permanently mounted tubing is clean before installation. • Change or clean tubing when the pump is withdrawn for servicing. • Clean any replaceable or temporaiy parts. Rev 4-08 26 • Collect equipment blanks on dedicated pumping systems when the tubing is cleaned or replaced. • Clean or make sure dedicated bailers are clean before placing them into the well. • Collect an equipment blank on dedicated bailers before introducing them into the water column. • Suspend dedicated bailers above the water column if they are stored in the well. Sampling Wells Without Plumbing a.) Sampling with Pumps — The following pumps may be used to sample for organics: • Peristaltic pumps • Stainless steel, Teflon or polyethylene bladder pumps • Variable speed stainless steel and Teflon submersible PUMPS Peristaltic Pump • Volatile Organics: One of three methods may be used. ■ Remove the drop tubing from the inlet side of the pump; submerge the drop tubing into the water column; prevent the water in the tubing from flowing back into the well; remove the drop tubing from the well; carefully allow the groundwater to drain into the sample vials; avoid turbulence; do not aerate the sample; repeat steps until enough vials are filled. OR ■ Use the pump to fill the drop tubing; quickly remove the tubing from the pump; prevent the water in the tubing from flowing back into the well; remove the drop tubing from the well; carefully allow the groundwater to drain into the sample vials; avoid turbulence; do not aerate the sample; repeat steps until enough vials are filled. OR ■ Use the pump to fill the drop tubing; withdraw the tubing from the well; reverse the flow on the peristaltic pumps to deliver the sample into the vials at a slow, steady rate; repeat steps until enough vials are filled. • Extractable Organics: If delivery tubing is not polyethylene or PP, or is not Teflon lined, use pump and vacuum trap method. Connect the outflow tubing from the container to the influent side of the peristaltic pump. Turn pump on and reduce flow until smooth and even. Discard a Rev 4-08 27 small portion of the sample to allow for air space. Preserve (if required), label, and complete field notes. • Inorganic samples: These samples may be collected from the effluent tubing. If samples are collected from the pump, decontaminate all tubing (including the tubing in the head) or change it between wells. Preserve (if required), label, and complete field notes. 2. Variable Speed Bladder Pump • If sampling for organics, the pump body must be constructed of stainless steel and the valves and bladder must be Teflon. All tubing must be Teflon, polyethylene, or PP and any cabling must be sealed in Teflon, polyethylene or PP, or made of stainless steel. • After purging to a smooth even flow, reduce the flow rate. • When sampling for volatile organic compounds, reduce the flow rate to 100-200mL/minute, if possible. 3. Variable Speed Submersible Pump • The housing must be stainless steel. • If sampling for organics, the internal impellers, seals and gaskets must be constructed of stainless steel, Teflon, polyethylene or PP. The delivery tubing must be Teflon, polyethylene or PP; the electrical cord must be sealed in Teflon; any cabling must be sealed in Teflon or constructed of stainless steel. • After purging to a smooth even flow, reduce the flow rate. • When sampling for volatile organic compounds, reduce the flow rate to 100-200mL/minute, if possible. b.) Sampling with Bailers - A high degree of skill and coordination are necessary to collect representative samples with a bailer. 1. General Considerations • Minimize handling of bailer as much as possible. • Wear sampling gloves. • Remove bailer from protective wrapping just before use. • Attach a lanyard of appropriate material. • Use the lanyard to move and position the bailers. • Do not allow bailer or lanyard to touch the ground. • If bailer is certified precleaned, no rinsing is necessary. • If both a pump and a bailer are to be used to collect samples, rinse the exterior and interior of the bailer with sample water from the pump before removing the pump. • If the purge pump is not appropriate for collecting samples (e.g., non -inert components), rinse the bailer by collecting a single bailer of the groundwater to be sampled. • Discard the water appropriately. Rev 4-08 28 • Do not rinse the bailer if Oil and Grease samples are to be collected. 2. Bailing Technique • Collect all samples that are required to be collected with a pump before collecting samples with the bailer. • Raise and lower the bailer gently to minimize stirring up particulate matter in the well and the water column, which can increase sample turbidity. • Lower the bailer carefully into the well to a depth approximately a foot above the water column. When the bailer is in position, lower the bailer into the water column at a rate of 2 cm/sec until the desired depth is reached. • Do not lower the top of the bailer more than one foot below the top of the water table, so that water is removed from the top of the water column. • Allow time for the bailer to fill with aquifer water as it descends into the water column. • Do not allow the bailer to touch the bottom of the well or particulate matter will be incorporated into the sample. Carefully raise the bailer. Retrieve the bailer at the same rate of 2 cm/sec until the bottom of the bailer has cleared to top of the water column. • Lower the bailer to approximately the same depth each time. • Collect the sample. Install a device to control the flow from the bottom of the bailer and discard the first few inches of water. Fill the appropriate sample containers by allowing the sample to slowly flow down the side of the container. Discard the last few inches of water in the bailer. • Repeat steps for additional samples. • As a final step measure the DO, pH, temperature, turbidity and specific conductance after the final sample has been collected. Record all measurements and note the time that sampling was completed. c.) Sampling Low Permeability Aquifers or Wells that have Purged Dry 1. Collect the sample(s) after the well has been purged. Minimize the amount of water removed from the well by using the same pump to purge and collect the sample. If the well has purged dry, collect samples as soon as sufficient sample water is available. 2. Measure the five field parameters temperature, pH, specific conductance, dissolved oxygen and turbidity at the time of sample collection. 3. Advise the analytical laboratory and the client that the usual amount of sample for analysis may not be available. Rev 4-08 29 Appendix D - Collecting Samples from Wells with Plumbing in Place In -place plumbing is generally considered permanent equipment routinely used for purposes other than purging and sampling, such as for water supply. a.) Air Strippers or Remedial Systems - These types of systems are installed as remediation devices. Collect influent and effluent samples from air stripping units as described below. 1. Remove any tubing from the sampling port and flush for one to two minutes. 2. Remove all hoses, aerators and filters (if possible). 3. Open the spigot and purge sufficient volume to flush the spigot and lines and until the purging completion criteria have been met. 4. Reduce the flow rate to approximately 500 mUminute (a 1/8" stream) or approximately 0.1 gal/minute before collecting samples. 5. Follow procedures for collecting samples from water supply wells as outlined below. b.) Water Supply Wells — Water supply wells with in -place plumbing do not require equipment to be brought to the well to purge and sample. Water supply wells at UST facilities must be sampled for volatile organic compounds (VOCs) and semivolatile compounds (SVOCs). 1. Procedures for Sampling Water Supply Wells • Label sample containers prior to sample collection. • Prepare the storage and transport containers (ice chest, etc.; before taking any samples so each collected sample can be placed in a chilled environment immediately after collection. • You must choose the tap closest to the well, preferably at the wellhead. The tap must be before any holding or pressurization tank, water softener, ion exchange, disinfection process or before the water line enters the residence, office or building. If no tap fits the above conditions, a new tap that does must be installed. • The well pump must not be lubricated with oil, as that may contaminate the samples. • The sampling tap must be protected from exterior contamination associated with being too close to a sink bottom or to the ground. If the tap is too close to the ground for direct collection into the appropriate container, it is acceptable to use a smaller (clean) container to transfer the sample to a larger container. • Leaking taps that allow water to discharge from around the valve stem handle and down the outside of the faucet, or taps in which water tends to run up on the outside of the lip, are to be avoided as sampling locations. Rev 4-08 30 • Disconnect any hoses, filters, or aerators attached to the tap before sampling. • Do not sample from a tap close to a gas pump. The gas fumes could contaminate the sample. 2. Collecting Volatile Organic Samples • Equipment Needed: VOC sample vials [40 milliliters, glass, may contain 3 to 4 drops of hydrochloric acid (HCl) as preservative]; Disposable gloves and protective goggles; Ice chest/cooler; Ice; Packing materials (sealable plastic bags, bubble wrap, etc.); and Lab forms. • Sampling Procedure: Run water from the well for at least 15 minutes. If the well is deep, run water longer (purging three well volumes is best). If tap or spigot is located directly before a holding tank, open a tap after the holding tank to prevent any backflow into the tap where you will take your sample. This will ensure that the water you collect is "fresh" from the well and not ftom the holding tank. After running the water for at least 15 minutes, reduce the flow of water. The flow should be reduced to a trickle but not so slow that it begins to drip. A smooth flow of water will make collection easier and more accurate. Remove the cap of a VOC vial and hold the vial under the stream of water to fill it. Be careful not to spill any acid that is in the vial. For best results use a low flow of water and angle the vial slightly so that the water runs down the inside of the vial. This will help keep the sample ftom being agitated, aerated or splashed out of the vial. It will also increase the accuracy of the sample. As the vial fills and is almost full, turn the vial until it is straight up and down so the water won't spill out. Fill the vial until the water is just about to spill over the lip of the vial. The surface of the water sample should become mounded. It is a good idea not to overfill the vial, especially if an acid preservative is present in the vial. Carefully replace and screw the cap onto the vial. Some water may overflow as the cap is put on. After the cap is secure, turn the vial upside down and gently tap the vial to see if any bubbles are present. If bubbles are present in the vial, remove the cap, add more water and check again to see if bubbles are present. Repeat as necessary. After two samples without bubbles have been collected, the samples should be labeled and prepared for shipment. Store samples at 4° C. Rev 4-08 31 3. Collecting Extractable Organic and/or Metals Samples • Equipment Needed: SVOC sample bottle [1 liter, amber glass] and/or Metals sample bottle [0.5 liter, polyethylene or glass, 5 milliliters of nitric acid (HNO3) preservative]; Disposable gloves and protective goggles; Ice Chest/Cooler; Ice; Packing materials (sealable plastic bags, bubble wrap, etc.); and Lab forms. • Sampling Procedure: Run water from the well for at least 15 minutes. If the well is deep, run the water longer (purging three well volumes is best). If tap or spigot is located directly before a holding tank, open a tap after the holding tank to prevent any backflow into the tap where you will take your sample. This will ensure that the water you collect is "fresh" from the well and not from the holding tank. After running the water for at least 15 minutes, reduce the flow. Low water flow makes collection easier and more accurate. Remove the cap of a SVOC or metals bottle and hold it under the stream of water to fill it. The bottle does not have to be completely filled (i.e., you can leave an inch or so of headspace in the bottle). After filling, screw on the cap, label the bottle and prepare for shipment. Store samples at 4° C. Rev 4-08 32 Appendix E - Collecting Surface Water Samples The following topics include 1.) acceptable equipment selection and equipment construction materials and 2.) standard grab, depth -specific and depth-composited surface water sampling techniques. Facilities which contain or border small rivers, streams or branches should include surface water sampling as part of the monitoring program for each sampling event. A simple procedure for selecting surface water monitoring sites is to locate a point on a stream where drainage leaves the site. This provides detection of contamination through, and possibly downstream of, site via discharge of surface waters. The sampling points selected should be downstream from any waste areas. An upstream sample should be obtained in order to determine water quality upstream of the influence of the site. a.) General Cautions 1. When using watercraft take samples near the bow away and upwind from any gasoline outboard engine. Orient watercraft so that bow is positioned in the upstream direction. 2. When wading, collect samples upstream from the body. Avoid disturbing sediments in the immediate area of sample collection. 3. Collect water samples prior to taking sediment samples when obtaining both from the same area (site). 4. Unless dictated by permit, program or order, sampling at or near man- made structures (e.g., dams, weirs or bridges) may not provide representative data because of unnatural flow patterns. 5. Collect surface water samples from downstream towards upstream. b.) Equipment and Supplies - Select equipment based on the analytes of interest, specific use, and availability. c.) Surface Water Sampling Techniques - Adhere to all general protocols applicable to aqueous sampling when following the surface water sampling procedures addressed below. 1. Manual Sampling: Use manual sampling for collecting grab samples for immediate in -situ field analyses. Use manual sampling in lieu of automatic equipment over extended periods of time for composite sampling, especially when it is necessary to observe and/or note unusual conditions. • Surface Grab Samples - Do not use sample containers containing premeasured amounts of preservatives to collect grab samples. If the sample matrix is homogeneous, then the grab method is a simple and effective technique for collection purposes. If homogeneity is not apparent, based on flow or vertical variations (and should never be assumed), then use other collection protocols. Where practical, use the actual sample container submitted to the laboratory for collecting samples to be analyzed for oil and grease, volatile organic compounds (VOCs), and microbiological samples. This procedure eliminates the possibility of contaminating the sample with an intermediate collection container. The use of Rev 4-08 33 unpreserved sample containers as direct grab samplers is encouraged since the same container can be submitted for laboratory analysis after appropriate preservation. This procedure reduces sample handling and eliminates potential contamination from other sources (e.g., additional sampling equipment, environment, etc.). 1. Grab directly into sample container. 2. Slowly submerge the container, opening neck first, into the water. 3. Invert the bottle so the neck is upright and pointing towards the direction of water flow (if applicable). Allow water to run slowly into the container until filled. 4. Return the filled container quickly to the surface. 5. Pour out a few mL of sample away from and downstream of the sampling location. This procedure allows for the addition of preservatives and sample expansion. Do not use this step for volatile organics or other analytes where headspace is not allowed in the sample container. 6. Add preservatives, securely cap container, label, and complete field notes. If sample containers are attached to a pole via a clamp, submerge the container and follow steps 3 — 5 but omit steps 1 and 2. • Sampling with an Intermediate Vessel or Container: If the sample cannot be collected directly into the sample container to be submitted to the laboratory, or if the laboratory provides prepreserved sample containers, use an unpreserved sample container or an intermediate vessel (e.g., beakers, buckets or dippers) to obtain the sample. These vessels must be constructed appropriately, including any poles or extension arms used to access the sample location. 1. Rinse the intermediate vessel with ample amounts of site water prior to collecting the first sample. 2. Collect the sample as outlined above using the intermediate vessel. 3. Use pole mounted containers of appropriate construction to sample at distances away from shore, boat, etc. Follow the protocols above to collect samples. • Peristaltic Pump and Tubing: The most portable pump for this technique is a 12 volt peristaltic pump. Use appropriately precleaned, silastic tubing in the pump head and attach polyethylene, Tygon, etc. tubing to the pump. This technique is not acceptable for Oil and Grease, EPH, VPH or VOCs. Extractable organics can be collected through the pump if flexible interior -wall Teflon, polyethylene or PP tubing is used in the pump head or if used with the organic trap setup. Rev 4-08 34 1. Lower appropriately precleaned tubing to a depth of 6 — 12 inches below water surface, where possible. 2. Pump 3 — 5 tube volumes through the system to acclimate the tubing before collecting the first sample. 3. Fill individual sample bottles via the discharge tubing. Be careful not to remove the inlet tubing from the water. 4. Add preservatives, securely cap container, label, and complete field notes. Mid -Depth Grab Samples: Mid -depth samples or samples taken at a specific depth can approximate the conditions throughout the entire water column. The equipment that may be used for this type of sampling consists of the following depth -specific sampling devices: Kemmerer, Niskin, Van Dorn type, etc. You may also use pumps with tubing or double check -valve bailers. Certain construction material details may preclude its use for certain analytes. Many Kemmerer samplers are constructed of plastic and rubber that preclude their use for all volatile and extractable organic sampling. Some newer devices are constructed of stainless steel or are all Teflon or Teflon -coated. These are acceptable for all analyte groups without restriction. 1. Measure the water column to determine maximum depth and sampling depth prior to lowering the sampling device. 2. Mark the line attached to the sampler with depth increments so that the sampling depth can be accurately recorded. 3. Lower the sampler slowly to the appropriate sampling depth, taking care not to disturb the sediments. 4. At the desired depth, send the messenger weight down to trip the closure mechanism. 5. Retrieve the sampler slowly. 6. Rinse the sampling device with ample amounts of site water prior to collecting the first sample. Discard rinsate away from and downstream of the sampling location. 7. Fill the individual sample bottles via the discharge tube. Double Check -Valve Bailers: Collect samples using double check - valve bailers if the data requirements do not necessitate a sample from a strictly discrete interval of the water column. Bailers with an upper and lower check -valve can be lowered through the water column. Water will continually be displaced through the bailer until the desired depth is reached, at which point the bailer is retrieved. Sampling with this type of bailer must follow the same protocols outlined above, except that a messenger weight is not applicable. Although not designed specifically for this kind of sampling, a bailer is acceptable when a mid -depth sample is required Rev 4-08 35 1. As the bailer is dropped through the water column, water is displaced through the body of the bailer. The degree of displacement depends upon the check -valve ball movement to allow water to flow freely through the bailer body. 2. Slowly lower the bailer to the appropriate depth. Upon retrieval, the two check valves seat, preventing water from escaping or entering the bailer. 3. Rinse the sampling device with ample amounts of site water prior to collecting the first sample. 4. Fill the individual sample bottles via the discharge tube. Sample bottles must be handled as described above. Peristaltic Pump and Tubing: The most portable pump for this technique is a 12 volt peristaltic pump. Use appropriately precleaned, silastic tubing in the pump head and attach HDPE, Tygon, etc. tubing to the pump. This technique is not acceptable for Oil and Grease, EPH, VPH or VOCs. Extractable organics can be collected through the pump if flexible interior -wall Teflon, polyethylene or PP tubing is used in the pump head, or if used with an organic trap setup. 1. Measure the water column to determine the maximum depth and the sampling depth. 2. Tubing will need to be tied to a stiff pole or be weighted down so the tubing placement will be secure. Do not use a lead weight. Any dense, non -contaminating, non - interfering material will work (brick, stainless steel weight, etc.). Tie the weight with a lanyard (braided or monofilament nylon, etc.) so that it is located below the inlet of the tubing. 3. Turn the pump on and allow several tubing volumes of water to be discharged before collecting the first sample. 4. Fill the individual sample bottles via the discharge tube. Sample bottles must be handled as described above. Rev 4-08 36 (� GOLDER golder.com