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HomeMy WebLinkAbout0601_Avery_MSWLF_Nov2019GW_FID1386877_20200103DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 ENkR USE ONLY_ . ❑Raper Report ❑Electronic Data - Email CD data loaded: Yes / No Doc/Event # NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached le it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6) Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B 1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Smith Gardner, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Joan A. Smyth E-mail: Joan@smithgardnerinc.com Phone: 919-828-0577 x 221 Facility name: Facility Address: Facility Permit # Avery County Closed MSW Landfill Brushy Creek Road, Spruce Pine, NC 06-01 NC Landfill Rule: Actual sampling dates (e.g.. (.0500 or .1600) October 20-24, 2006) .0500 November 21, 2019 Environmental Status: (Check all that apply) Initial/Background Monitoring ❑X Detection Monitoring Assessment Monitoring Tie of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data X Surface water monitoring data Other(specify) ❑ Corrective Action Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Joan A. Smyth, PG Senior Hydrogeologist 919-828-0577 x 221 Facility Representativ aWe' W,i'WO °Y Title (Area Code) Telephone Number 1/2/2020 Affix NC Licensed/ Professional Geologist Seal Signature 14 N. Boylan Ave, Raleigh, NC 27603 Facility Representative Address F-1370 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 Date Q�CA O. �SE� �r SEAL 1369 1 211020 COL O G�5_ r 4� "bft.q i g DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 November 2019 Semi -Annual Groundwater Monitoring Report Avery County Closed MSW Landfill Spruce Pine, North Carolina NC Solid Waste Permit No. 06-01 Prepared for: Avery County Solid Waste 175 Linville Street Newland, North Carolina 28657 Prepared by: NCEIC.NO.E-137O (rNGINEERING) SMITH GARDNER 14 N. Boylan Avenue, Raleigh NE 27603 1919.B28.0577 December 2019 4 PBINTE. ON W.1 1E11.1ED PAPER O 2019 Smith Gardner; Inc. This document is intended for the sole use of the client for which it was prepared and for the purpose agreed on by the client and Smith Gardner Inc. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 November 2019 Semi -Annual Groundwater Monitoring Report Avery County Closed MSW Landfill NC Solid Waste Permit No. 06-01 Prepared For: Avery County Solid Waste Newland, North Carolina S+G Project No. Avery U-6 DocuSigned by: es7e Seth C. Rickerts Staff Geologist �0 CA a o � DocuSigned by: '-S� a 7 SEAL 1 2 / �369 RQ77QERA711 FdRR Joan A. Smyth, P.G. Senior Hydrogeologist , QF ola�5 i As pq� , December 2019 NGLIG.N0.f-wo (ENGINEERING) SMITH+GARONER 14 N. Boylan Avenue, Raleigh NC 27603 1919.828.0577 20 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Avery County Closed MSW Landfill NC Solid Waste Permit No. 06-01 November 2019 Semi -Annual Groundwater Monitoring Report Table of Contents Paqe 1.0 INTRODUCTION......................................................................................................... 1 2.0 SITE GEOLOGY........................................................................................................... 1 3.0 SAMPLING PROCEDURES......................................................................................... 1 4.0 FIELD AND LABORATORY DATA................................................................................ 2 4.1 Field Measurements............................................................................................... 2 4.2 Laboratory Analysis................................................................................................ 2 4.3 Laboratory Results................................................................................................. 2 5.0 GROUNDWATER CHARACTERIZATION...................................................................... 2 6.0 CONCLUSIONS.......................................................................................................... 3 FIGURES Figure 1 Potentiometric Surface Map TABLES Table 1 Groundwater Elevation Data Table 2 Field Parameters Table 3 Detected Inorganic Constituents Table 4 Detected Organic Constituents APPENDICES Appendix A Laboratory Analytical Report Avery County Closed MSW landfill November 2019 Semi -Annual Report December 2019 Table of Contents Page i DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 1.0 INTRODUCTION Avery County is required to submit semi-annual groundwater monitoring reports for the Closed unlined MSW landfill (permit # 06-01) in accordance with Solid Waste Section Rule 15A NCAC 13B. This report, prepared by Smith Gardner, Inc (S+G), presents the semi-annual sampling for the event conducted on November 21, 2019. The groundwater monitoring network for the closed unlined MSW landfill includes three groundwater monitoring wells and two surface water monitoring locations. This report includes field procedure summaries, laboratory analyses and groundwater characterization for the closed MSW facility. 2.0 SITE GEOLOGY The Avery County Closed MSW Landfill is located in the North Carolina Blue Ridge province, along the eastern limb of the Blue Ridge anticlinorium. Published geologic mapping' places the site approximately twelve miles west of the Brevard Zone (measured perpendicular to strike), which is the boundary of the Blue Ridge Belt and the Piedmont. The principal geologic units mapped in the immediate vicinity of the site include a mix of metamorphosed sedimentary and igneous rocks — termed paragneiss and orthogneiss, respectively — interlayered with contemporaneous schist, phyllite, and marble, later injected with various granitic intrusions, including plutons, pegmatites, and hydrothermal veins. Regional metamorphic grades in the region include kyanite-grade (high grade) and retrograde chlorite-biotite metamorphism (low grade). 3.0 SAMPLING PROCEDURES S+G personnel performed this sampling event that involved collecting samples from three groundwater wells (MW-1, MW-2 and MW-3R) and two surface water locations (SW-1 and SW- 21. MW-3R is the replacement well for the previously damaged MW-3 and will be monitored in its place in future sampling events. Sampling methods followed the protocol outlined in the North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilitiesz. The depth to water in each well was gauged prior to purging and sampling. Samples were collected using new factory sealed Teflon bailers and placed in laboratory prepared containers for the specified analytical procedures. Groundwater samples were properly preserved, placed on ice, and transported to the laboratory facility within the specified hold times for each analysis. 1 North Carolina Geologic Survey at http://www. eq oLogV.enr.state.nc.us 2 Solid Waste Section Guidelines for Groundwater, Soil, and Surface Water Sampling, NCDENR, DWM, SWS, Rev 4-08. Avery County Closed MSW Landfill November 2019 Semi -Annual Report December 2019 Page 1 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 A map showing sampling locations is presented as Figure available construction details are presented in Table 1. 4.0 FIELD AND LABORATORY DATA 4.1 Field Measurements Water table elevations and Following purging, field parameters for temperature, pH, turbidity and specific conductance were measured and recorded at each sampling location. These results are summarized in Table 2. In general these measurements were consistent with data from previous events. 4.2 Laboratory Analysis Ground and surface water samples were transported to Prism Laboratories, Inc. (Charlotte, NCI) where they were analyzed for Appendix I metals and volatile organic compounds (VOC) via the SWS approved EPA Test Method presented in the laboratory report. The additional compound, 1,4 Dioxane was analyzed via EPA Method 8260 SIM. Samples were transported under proper chain of custody. The laboratory report is included in Appendix A. 4.3 Laboratory Results Cobalt (MW-1 and MW-3R) was the only inorganic constituent detected at concentrations above the associated standard in samples collected this event. Turbidity for these samples were all below 10 NTUs. One inorganic constituent was detected in samples during this sampling event. 1,4- Dioxane was detected at concentrations above the NC2L standard in MW-1 and MW-2. No inorganic or organic constituents were detected in surface water samples above their 2B Standard for Class C Waters in samples collected this event. Analytical results are presented in Tables 3 and 4. 5.0 GROUNDWATER CHARACTERIZATION A potentiometric surface map was prepared from groundwater data collected this sampling event. The general groundwater flow is toward the southeast across the site toward Brushy Creek. Hydraulic conductivity data was not available for these wells so groundwater velocities could not be calculated. The potentiometric surface map is included as Figure 1. 3449 Springbrook Road, Charlotte, NC 28224, NC DENR No.402. Avery County Closed MSW Landfill November 2019 Semi -Annual Report Decemher2019 Page 2 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 6.0 CONCLUSIONS Laboratory results indicate the water quality at the Avery County Closed unlined MSW Landfill is generally consistent with historically reported results. Cobalt is a naturally occurring metal in North Carolina soils, exceedances can be attributed to suspended solids in the groundwater samples. 1,4-Dioxane was present in samples collected from MW-1 and MW-2 during the April 2019 and November 2018 sampling events, however they had not exceeded NC2L standards at those times. 1,4-Dioxane has exhibited concentrations fluctuating seasonally at other similar solid waste sites. Concentrations may lower again when sampled during the next scheduled event. S+G will continue to monitor theses parameters. The next groundwater monitoring event is scheduled for April 2020. A report summarizing that event will be submitted to NCDEQ with laboratory analyses. Avery County Closed MSW Landfill November 2019 Semi -Annual Report December 2019 Page 3 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 INI'M November 2019 — Semi -Annual Groundwater Report Avery County Closed MSW Landfill NC Solid Waste Permit No. 06-01 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-47OF-B82F-AFB30702E125 \ \ r l \ `\ 11 o N o •�b / � o I I z 0i 1A D�1LL I I w ® E Q 10 Y iCR 271(�1\I\I\ \ I I IIIIIIII III/ ,�\ �-=_ ___ - � �'/' i'i/ 'r/r / 2'Ik ';-�' , � ,�,/ I _ •r / / // '�'/, IN— \ I I IIII 1 It i \,I II IIIj, Illl//-__= \\N 1 111 \ _ \ \\ ----- --� -' �- _ --- -- \ `, \ \\\ -�-��_ -- MW-3 TOC=2696.62 I \ \ \ / -° DTW=6.55iI1 1 I \\ \ \\ \ m L `;GWE=2691.72 I Ill, IIIIIli 11111 d\\ \\ II\1 III, 11111 IIII I11 IIII / \` \ `\\ \ `\\ `\ `\\ \ \\\\ IIII 11j 1 1 11 I II! / / \` \\ \` LEGEND flP1LL rn STREAM1WATER BODY z N N � GATED ANDFI// I \ \ I II 1 II I / lll Il/l11I,ll,,Il IIII _-----_PERM/TTED PHASE LIMITS D w0 ------ L-I> , III IIIIIII II/ �' �\� \\\\\ _ a > Ill, I, III,, IIII , � —� \ \\ �69\` GATED UN/MIN' --- --_ FACILITY BOUNDARY � ir I Il O ii /i 11 ,i i i /� 1 \`--- _MW-3 EXlS7ING GROUNDWATER MONITORING WELL� J '// / Q P o Lu P—� EXISTING PIEZOMETER z w . EXISTING SURFACE WATER MONITORING o SW-2 LOCATION � C� UNIMIN C- 2970POTENTIOMETRIC CONTOUR \ DASHED WHERE INFERRED — \ oN /�. / GROUNDWATER FLOW DIRECTION u ' ' / z t] TOC=2666.81 / / / MW-1 � w \ \ �%/„ „/,,, //, �, ,� � , � , / � MONITORING WELL DESIGNATION o 0 �� i\ \ \'���.iiiii'/i�/ii /,/,/ , / ' ,'' r / / / / / TOP OF CASING a \ I I \I 1, I DTW=9.35 , / / Toc= `\I` Ij I If GWE=2657.46 DTW= DEPTH TO WATER GWE= GROUNDWATER ELEVATION I \ it/,a°'/i / �/ NOTES 1. DEPTH TO WATER MEASUREMENTS COLLECTED BY SMITH GARDNER a INC. PERSONNEL ON NOVEMBER 11, 2019. Q p C� REFERENCES ME cm 1 \ \\ \ \ \\\ \1 I I111 1\\\\\\I 1. ADJACENT PROPERTY BOUNDARIES FROM AVERY COUNTY GIS o MAPPING DEPARTMENT. cv cn 2sso y i r / 1 �I _ ''� , / I \ 2. MONITORING WELL LOCATIONS FROM FIELD SURVEY DATED 5/27/10, c-3 W BY SURVEYING SOLUTIONS, P.C. Ck-' � ; 3. PROPERTY LINE, EXISTING PROGRESS ENERGY POWER LINE AND = , ..LLj \�� A, EASEMENT \ l l�� //,�'/'r// /,��—=�4 ���� EASEMENT SHOWN FROM FIELD SURVEY DATED APRIL 9, 2010, BY o o APPALACHIAN PROFESSIONAL LAND SURVEYORS & CONSULTANTS. TOC=2672.60 /r„/ 4. LFG PROBES LOCATIONS FROM FIELD SURVEY DATED APRIL 9, 2010, Z \ , // / /// / / / / , / / / ,/// W .. DTW=8.42 / /,/ , /// ,, , /r/ / // // / , , //1/1 BY APPALACHIAN PROFESSIONAL LAND SURVEYORS & CONSULTANTS. /2I70/0` G/W1E1 1= 2664.�1\8 l 5. OVERALL SITE TOPOGRAPHY FROM M AERIAL SURVEY BY NCDOT, 0w DATE a OF PHOTOGRAPHY MARCH 2O05. -Arfip% C0UNTY/0 150' 300'AIRPORT G o © 19 Smi Gardner, Inc. \ ``` `\``�\ — ^�` ` /�/ /'/'. �,,� \`��\\\\\ \ / I I 1 I it DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 IFA.11V November 2019 — Semi -Annual Groundwater Report Avery County Closed MSW Landfill NC Solid Waste Permit No. 06-01 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 SMITH+GARONER Table 1 Groundwater Elevations Avery County MSW Landfill November 21, 2019 By: SCR Date:11/25/2019 Ground Well Well Total Well TOC Depth to Groundwater Screen Surface Screen Well Installation Latitude Longitude Diameter Depth (ft. Elevation Water (ft. Elevation (ft. Interval Elevation Geology Date (inches) bgs) (ft. amsl) bgs) amsl) (ft. bgs) (ft. amsl) MW-1 NA 35.94624 81.99304 2 23.36 2672.60 2672.60 8.42 2664.18 10' - 20' NA MW-2 NA 35.94720 81.99173 2 19.23 2666.81 2666.81 9.35 2657.46 4' - 14' NA MW-3R NA 35.94840 81.99174 2 15.27 2696.62 2696.62 6.55 2691.72 4' - 14' NA NOTE: No boring logs or well records are available Depth to Water and Well Depth measured from the Top of Casing November 21, 2019 Screen Interval is assumed based on field measurements. H:\Projects\Groundwater Monitoring\2. Groundwater Monitoring Reports\Avery county\Avery MSW Report\25. November 2019\November 2019 Avery MSW tables.xls DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 SMITH+GARONER Table 2 Field Parameters Avery County MSW Landfill November 21, 2019 Well Temperature (*Celsius) Turbidity (NTU) Specific Conductivity (MS/cm) pH MW-1 13.9 21.20 102.8 5.67 MW-2 13.2 4.2 52.6 5.92 MW-3R 11.7 14.6 201.9 5.66 SW-1 6.8 3.98 71 6.01 SW-2 9.1 2.93 170.9 5.93 NOTE: Data collected by S+G personnel. By: SCR Date:11/25/2019 H:\Projects\Groundwater Monitoring\2. Groundwater Monitoring Reports\Avery county\Avery MSW Report\25. November 2019\November 2019 Avery MSW tables.xls DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 SMITHGARDNER Table Detect 3ituents By, SCR Date,12/23/2019 Avery County MSW Landfill November 21, 2019 Well ID Parameter Standard Limit Result Inorganic Constituents MW-1 Arsenic NC2L 10 0.52 J Barium NC2L 700 180 Cadmium NC2L 2 1.5 Cobalt NCGWP 1 14 Lead NC2L 15 0.81 J Nickel NC2L 100 2.8 J Zinc NC2L 1000 31 MW-2 Barium NC2L 700 34 Chromium NC2L 10 2.8 J Copper NC2L 1000 10 Lead NC2L 15 0.99 J Nickel NC2L 100 1.1 J MW-3R Arsenic NC2L 10 1.5 Barium NC2L 700 39 Chromium NC2L 10 1.4 J Cobalt NCGWP 1 11 Lead NC2L 15 0.47 J SW-1 Barium NC2B protect 21000 15 SW-2 Barium NC213 protect 21000 24 Organic Constituents MW-1 1,4-Dichlorobenzene NC2L 6 0.82 1,4-Dioxane NC2L 3 3.2 cis- 1,2-Dichloroeth lene NC2L 70 0.42 J MW-2 1,4-Dioxane NC2L 3 3.6 MW-3R 1,4-Dichlorobenzene NC2L 1 6 1 0.56 1,4-Dioxane NC2L 1 3 1 1.2 J NOTE: NC2L - North Carolina groundwater standards per 15A NCA 0 2L.0202 NC2L IMAC - 2L Interim Maximum Allowable Concentration NC213 - NCAC 2E Standard for Class C waters Bold - Concetration exceeding 2L or GWP Standard J - A concentration detected by the laboratory above the method detection limit, but below the reporting limit; therefore, result is estimated concentration. Data from this table is presented in µg/L from Prism Lab report Work Order #9110455 dated 12/6/2019 H:\Projects\Groundwater Monitoring\2. Groundwater Monitoring Reports\Avery county\Avery MSW Repart\25. November 2019\November 2019 Avery MSWtables.xls DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Appendix A Laboratory Analytical Report November 2019 — Semi -Annual Groundwater Report Avery County Closed MSW Landfill NC Solid Waste Permit No. 06-01 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 This page intentionally left blank. DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 P R I S M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Smith + Gardner, Inc. Seth C. Rickerts 14 N. Boylan Avenue Raleigh, NC 27603 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Avery MSW Landfill Project No.: 0601 Lab Submittal Date: 11/27/2019 Prism Work Order: 9110455 Case Narrative 12/6/19 14:42 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. a,j Angela D. Overcash VP Laboratory Services Data Qualifiers Key Reference: Reviewed By Terri W. Cole For Angela D. Overcash Project Manager J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Sample Receipt Summary �y Full -Service Analytical & PRISM / Environmental Solutions 12/06/2019 LABORATORIES, INC. Prism Work Order: 9110455 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-1 9110455-01 Water 11/21/19 10:30 11/27/19 8:20 MW-2 9110455-02 Water 11/21/19 10:45 11/27/19 8:20 MW-3 9110455-03 Water 11/21/19 11:00 11/27/19 8:20 SW-1 9110455-04 Water 11/21/19 10:40 11/27/19 8:20 SW-2 9110455-05 Water 11/21/19 11:10 11/27/19 8:20 Trip Blank 9110455-06 Water 11/21/19 0:00 11/27/19 8:20 Samples were received in good condition at 1.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Full -Service Analytical & / Environmental Solutions PRISM LABORATOR Summary of Detections 12/06/201 S Prism Work Order: 9110455 Prism ID Client ID Parameter Method Result Units 9110455-01 MW-1 Arsenic 6020B 0.52 .1 ug/L 9110455-01 MW-1 Barium 6020B 180 ug/L 9110455-01 MW-1 Cadmium 6020B 1.5 ug/L 9110455-01 MW-1 Cobalt 6020B 14 ug/L 9110455-01 MW-1 Lead 6020B 0.81 J ug/L 9110455-01 MW-1 Nickel 6020B 2.8 J ug/L 9110455-01 MW-1 Zinc 6020B 31 ug/L 9110455-01 MW-1 1,4-Dichlorobenzene 8260D 0.82 ug/L 9110455-01 MW-1 cis-1,2-Dichloroethylene 8260D 0.42 J ug/L 9110455-01 MW-1 1,4-Dioxane 8260D SIM 3.2 ug/L 9110455-02 MW-2 Barium 6020B 34 ug/L 9110455-02 MW-2 Chromium 6020B 2.8 J ug/L 9110455-02 MW-2 Copper 6020B 10 ug/L 9110455-02 MW-2 Lead 6020B 0.99 J ug/L 9110455-02 MW-2 Nickel 6020B 1.1 J ug/L 9110455-02 MW-2 1,4-Dioxane 8260D SIM 3.6 ug/L 9110455-03 MW-3 Arsenic 6020B 1.5 ug/L 9110455-03 MW-3 Barium 6020B 39 ug/L 9110455-03 MW-3 Chromium 6020B 1.4 .1 ug/L 9110455-03 MW-3 Cobalt 6020B 11 ug/L 9110455-03 MW-3 Lead 6020B 0.47 J ug/L 9110455-03 MW-3 1,4-Dichlorobenzene 8260D 0.56 ug/L 9110455-03 MW-3 1,4-Dioxane 8260D SIM 1.2 J ug/L 9110455-04 SW-1 Barium 6020B 15 ug/L 9110455-05 SW-2 Barium 6020B 24 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 /r Full -Service Analytical P R I S M Environmental Solutions LABORATORIES, INC. Laboratory Report 12/06/2019 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No.: 0601 Raleigh, NC 27603 Sample Matrix: Water Client Sample ID: MW-1 Prism Sample ID: 9110455-01 Prism Work Order: 9110455 Time Collected: 11/21/19 10:30 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Antimony <0.93 ug/L 6 3.0 0.93 1 6020B 12/2/19 19:11 MMR P91-0006 Arsenic 0.52 J ug/L 10 1.0 0.34 1 6020B 12/2/19 19:11 MMR P911-0006 Barium 180 ug/L 100 10 3.2 1 6020B 12/2/19 19:11 MMR P91-0006 Beryllium <0.30 ug/L 1 1.0 0.30 1 6020B 12/2/19 19:11 MMR P91-0006 Cadmium 1.5 ug/L 1 1.0 0.22 1 6020B 12/2/19 19:11 MMR 1391-0006 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 12/2/19 19:11 MMR 1`91-0006 Cobalt 14 ug/L 10 2.0 0.70 1 6020B 12/2/19 19:11 MMR P91-0006 Copper <4.7 ug/L 10 10 4.7 1 6020B 12/2/19 19:11 MMR P91-0006 Lead 0.81 j ug/L 10 1.0 0.44 1 6020B 12/2/19 19:11 MMR P911-0006 Nickel 2.8 j ug/L 50 3.0 0.83 1 6020B 12/2/19 19:11 MMR 1391-0006 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 12/2/19 19:11 MMR 1`91-0006 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:11 MMR P91-0006 Thallium <0.84 ug/L 5.5 2.0 0.84 1 6020B 12/2/19 19:11 MMR 1`91-0006 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 12/2/19 19:11 MMR P91-0006 Zinc 31 ug/L 10 20 10 1 6020B 12/2/19 19:11 MMR P911-0006 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 5:55 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 5:55 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 5:55 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 5:55 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 5:55 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 5:55 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 5:55 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 5:55 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 5:55 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 5:55 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 5:55 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 5:55 ANG P91-0053 1,4-Dichlorobenzene 0.82 ug/L 1 0.50 0.42 1 8260D 12/4/19 5:55 ANG P911-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 5:55 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 5:55 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 5:55 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 5:55 ANG P91-0053 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 5:55 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 5:55 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 5:55 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: MW-1 Attn: Seth C. Rickerts Prism Sample ID: 9110455-01 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 10:30 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 5:55 ANG 1`91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 5:55 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 5:55 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 5:55 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 5:55 ANG P91-0053 Chloromethane <0,29 ug/L 1 0.50 0.29 1 8260D 12/4/19 5:55 ANG P91-0053 cis-1,2-Dichloroethylene 0.42 J ug/L 5 0.50 0.40 1 8260D 12/4/19 5:55 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 5:55 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 5:55 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 5:55 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 5:55 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 5:55 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 5:55 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 5:55 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 5:55 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 5:55 ANG P91-0053 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 5:55 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 5:55 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 5:55 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 5:55 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 5:55 ANG 1`91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 5:55 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 5:55 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 5:55 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 5:55 ANG P91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 5:55 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 5:55 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 5:55 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 5:55 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 89 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 3.2 ug/L 10 2.0 0.14 1 8260D SIM 11/27/19 18:18TBL P9K0502 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: MW-2 Attn: Seth C. Rickerts Prism Sample ID: 9110455-02 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 10:45 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Antimony <0.93 ug/L 6 3.0 0.93 1 6020B 12/2/19 19:18 MMR 1`91-0006 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:18 MMR P91-0006 Barium 34 ug/L 100 10 3.2 1 6020B 12/2/19 19:18 MMR P911-0006 Beryllium <0.30 ug/L 1 1.0 0.30 1 6020B 12/2/19 19:18 MMR P91-0006 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 12/2/19 19:18 MMR P91-0006 Chromium 2.8 1 ug/L 10 3.0 0.90 1 6020B 12/2/19 19:18 MMR P911-0006 Cobalt <0.70 ug/L 10 2.0 0.70 1 6020B 12/2/19 19:18 MMR P91-0006 Copper 10 ug/L 10 10 4.7 1 6020B 12/2/19 19:18 MMR P911-0006 Lead 0.99 J ug/L 10 1.0 0.44 1 6020B 12/2/19 19:18 MMR P911-0006 Nickel 1.1 J ug/L 50 3.0 0.83 1 6020B 12/2/19 19:18 MMR P91-0006 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 12/2/19 19:18 MMR 1`91-0006 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:18 MMR P91-0006 Thallium <0.84 ug/L 5.5 2.0 0.84 1 6020B 12/2/19 19:18 MMR P91-0006 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 12/2/19 19:18 MMR P91-0006 Zinc <10 ug/L 10 20 10 1 6020B 12/2/19 19:18 MMR P91-0006 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 6:21 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:21 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 6:21 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 6:21 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 6:21 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 6:21 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 6:21 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 6:21 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 6:21 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 6:21 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 6:21 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:21 ANG P91-0053 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 6:21 ANG P91-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 6:21 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 6:21 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 6:21 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 6:21 ANG P91-0053 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:21 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 6:21 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 6:21 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: MW-2 Attn: Seth C. Rickerts Prism Sample ID: 9110455-02 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 10:45 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 6:21 ANG 1`91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 6:21 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 6:21 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 6:21 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 6:21 ANG P91-0053 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:21 ANG P91-0053 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 12/4/19 6:21 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 6:21 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 6:21 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 6:21 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:21 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 6:21 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 6:21 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 6:21 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 6:21 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 6:21 ANG P91-0053 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 6:21 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 6:21 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 6:21 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:21 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 6:21 ANG P91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 6:21 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 6:21 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 6:21 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 6:21 ANG 1`91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 6:21 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 6:21 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 6:21 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 6:21 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 97 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 88 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 3.6 ug/L 10 2.0 0.14 1 8260D SIM 11/27/19 18:43TBL P9K0502 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Full -Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 12/06/2019 Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: MW-3 Attn: Seth C. Rickerts Prism Sample ID: 9110455-03 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 11:00 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Antimony <0.93 ug/L 6 3.0 0.93 1 6020B 12/2/19 19:24 MMR 1`91-0006 Arsenic 1.5 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:24 MMR P91-0006 Barium 39 ug/L 100 10 3.2 1 6020B 1212/19 19:24 MMR P911-0006 Beryllium <0.30 ug/L 1 1.0 0.30 1 6020B 12/2/19 19:24 MMR P91-0006 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 12/2/19 19:24 MMR P91-0006 Chromium 1.4 j ug/L 10 3.0 0.90 1 6020B 12/2/19 19:24 MMR P911-0006 Cobalt 11 ug/L 10 2.0 0.70 1 6020B 12/2/19 19:24 MMR P911-0006 Copper <4.7 ug/L 10 10 4.7 1 6020B 12/2/19 19:24 MMR P91-0006 Lead 0.47 J ug/L 10 1.0 0.44 1 6020B 12/2/19 19:24 MMR P911-0006 Nickel <0.83 ug/L 50 3.0 0.83 1 6020B 12/2/19 19:24 MMR 1`91-0006 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 12/2/19 19:24 MMR P91-0006 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:24 MMR 1`91-0006 Thallium <0.84 ug/L 5.5 2.0 0.84 1 6020B 12/2/19 19:24 MMR P91-0006 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 12/2/19 19:24 MMR 1`91-0006 Zinc <10 ug/L 10 20 10 1 6020B 12/2/19 19:24 MMR P91-0006 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 6:47 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:47 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 6:47 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 6:47 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 6:47 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 6:47 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 6:47 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 6:47 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 6:47 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 6:47 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 6:47 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:47 ANG P91-0053 1,4-Dichlorobenzene 0.56 ug/L 1 0.50 0.42 1 8260D 12/4/19 6:47 ANG P911-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 6:47 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 6:47 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 6:47 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 6:47 ANG P91-0053 Bromodichloromethane <0,29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:47 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 6:47 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 6:47 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: MW-3 Attn: Seth C. Rickerts Prism Sample ID: 9110455-03 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 11:00 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 6:47 ANG 1`91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 6:47 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 6:47 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 6:47 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 6:47 ANG P91-0053 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 6:47 ANG P91-0053 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 12/4/19 6:47 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 6:47 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 6:47 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 6:47 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:47 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 6:47 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 6:47 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 6:47 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 6:47 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 6:47 ANG P91-0053 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 6:47 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 6:47 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 6:47 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 6:47 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 6:47 ANG P91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 6:47 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 6:47 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 6:47 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 6:47 ANG 1`91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 6:47 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 6:47 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 6:47 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 6:47 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 89 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 1.2 J ug/L 10 2.0 0.14 1 8260D SIM 11/27/19 19:08TBL P9K0502 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: SW-1 Attn: Seth C. Rickerts Prism Sample ID: 9110455-04 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 10:40 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Antimony <0.93 ug/L 6 3.0 0.93 1 6020B 12/2/19 19:31 MMR 1`91-0006 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:31 MMR P91-0006 Barium 15 ug/L 100 10 3.2 1 6020B 12/2/19 19:31 MMR P911-0006 Beryllium <0.30 ug/L 1 1.0 0.30 1 6020B 12/2/19 19:31 MMR P91-0006 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 12/2/19 19:31 MMR P91-0006 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 12/2/19 19:31 MMR P91-0006 Cobalt <0.70 ug/L 10 2.0 0.70 1 6020B 12/2/19 19:31 MMR P91-0006 Copper <4.7 ug/L 10 10 4.7 1 6020B 12/2/19 19:31 MMR P91-0006 Lead <0.44 ug/L 10 1.0 0.44 1 6020B 12/2/19 19:31 MMR P91-0006 Nickel <0.83 ug/L 50 3.0 0.83 1 6020B 12/2/19 19:31 MMR P91-0006 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 12/2/19 19:31 MMR P91-0006 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:31 MMR P91-0006 Thallium <0.84 ug/L 5.5 2.0 0.84 1 6020B 12/2/19 19:31 MMR P91-0006 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 12/2/19 19:31 MMR P91-0006 Zinc <10 ug/L 10 20 10 1 6020B 12/2/19 19:31 MMR P91-0006 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 7:13 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:13 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 7:13 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 7:13 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 7:13 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 7:13 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 7:13 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 7:13 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 7:13 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 7:13 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 7:13 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:13 ANG P91-0053 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 7:13 ANG P91-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 7:13 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 7:13 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 7:13 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 7:13 ANG P91-0053 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:13 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 7:13 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 7:13 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: SW-1 Attn: Seth C. Rickerts Prism Sample ID: 9110455-04 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 10:40 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 7:13 ANG 1`91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 7:13 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 7:13 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 7:13 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 7:13 ANG P91-0053 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:13 ANG P91-0053 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 12/4/19 7:13 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 7:13 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 7:13 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 7:13 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:13 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 7:13 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 7:13 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 7:13 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 7:13 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 7:13 ANG P91-0053 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 7:13 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 7:13 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 7:13 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:13 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 7:13 ANG P91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 7:13 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 7:13 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 7:13 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 7:13 ANG 1`91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 7:13 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 7:13 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 7:13 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 7:13 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 89 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 11/27/19 19:33TBL P91<0502 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: SW-2 Attn: Seth C. Rickerts Prism Sample ID: 9110455-05 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 11:10 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Total Metals Antimony <0.93 ug/L 6 3.0 0.93 1 6020B 12/2/19 19:38 MMR 1`91-0006 Arsenic <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:38 MMR P91-0006 Barium 24 ug/L 100 10 3.2 1 6020B 12/2/19 19:38 MMR P911-0006 Beryllium <0.30 ug/L 1 1.0 0.30 1 6020B 12/2/19 19:38 MMR P91-0006 Cadmium <0.22 ug/L 1 1.0 0.22 1 6020B 12/2/19 19:38 MMR P91-0006 Chromium <0.90 ug/L 10 3.0 0.90 1 6020B 12/2/19 19:38 MMR P91-0006 Cobalt <0.70 ug/L 10 2.0 0.70 1 6020B 12/2/19 19:38 MMR P91-0006 Copper <4.7 ug/L 10 10 4.7 1 6020B 12/2/19 19:38 MMR P91-0006 Lead <0.44 ug/L 10 1.0 0.44 1 6020B 12/2/19 19:38 MMR P91-0006 Nickel <0.83 ug/L 50 3.0 0.83 1 6020B 12/2/19 19:38 MMR P91-0006 Selenium <0.98 ug/L 10 5.0 0.98 1 6020B 12/2/19 19:38 MMR P91-0006 Silver <0.34 ug/L 10 1.0 0.34 1 6020B 12/2/19 19:38 MMR P91-0006 Thallium <0.84 ug/L 5.5 2.0 0.84 1 6020B 12/2/19 19:38 MMR P91-0006 Vanadium <1.5 ug/L 25 5.0 1.5 1 6020B 12/2/19 19:38 MMR P91-0006 Zinc <10 ug/L 10 20 10 1 6020B 12/2/19 19:38 MMR P91-0006 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 7:39 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:39 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 7:39 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 7:39 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 7:39 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 7:39 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 7:39 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 7:39 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 7:39 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 7:39 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 7:39 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:39 ANG P91-0053 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 7:39 ANG P91-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 7:39 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 7:39 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 7:39 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 7:39 ANG P91-0053 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:39 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 7:39 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 7:39 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report Full -Service Analytical & P R I S M Environmental Solutions 12/06/2019 LABORATORIES INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: SW-2 Attn: Seth C. Rickerts Prism Sample ID: 9110455-05 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 11:10 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 7:39 ANG 1`91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 7:39 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 7:39 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 7:39 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 7:39 ANG P91-0053 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 7:39 ANG P91-0053 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 12/4/19 7:39 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 7:39 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 7:39 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 7:39 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:39 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 7:39 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 7:39 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 7:39 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 7:39 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 7:39 ANG P91-0053 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 7:39 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 7:39 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 7:39 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 7:39 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 7:39 ANG P91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 7:39 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 7:39 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 7:39 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 7:39 ANG 1`91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 7:39 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 7:39 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 7:39 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 7:39 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 89 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 11/27/19 19:58TBL P91<0502 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Full -Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 12/06/2019 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No.: 0601 Raleigh, NC 27603 Sample Matrix: Water Client Sample ID: Trip Blank Prism Sample ID: 9110455-06 Prism Work Order: 9110455 Time Collected: 11/21/19 00:00 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 2:28 ANG P91-0053 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 2:28 ANG P91-0053 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 2:28 ANG P91-0053 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 2:28 ANG P91-0053 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 12/4/19 2:28 ANG P91-0053 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 12/4/19 2:28 ANG P91-0053 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 12/4/19 2:28 ANG P91-0053 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 12/4/19 2:28 ANG P91-0053 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 12/4/19 2:28 ANG P91-0053 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 12/4/19 2:28 ANG P91-0053 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 2:28 ANG P91-0053 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 2:28 ANG P91-0053 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 12/4/19 2:28 ANG P91-0053 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 12/4/19 2:28 ANG P91-0053 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 12/4/19 2:28 ANG P91-0053 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 12/4/19 2:28 ANG P91-0053 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 12/4/19 2:28 ANG P91-0053 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 2:28 ANG P91-0053 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 12/4/19 2:28 ANG P91-0053 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 12/4/19 2:28 ANG P91-0053 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 12/4/19 2:28 ANG P91-0053 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 12/4/19 2:28 ANG P91-0053 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 12/4/19 2:28 ANG P91-0053 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 12/4/19 2:28 ANG P91-0053 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 12/4/19 2:28 ANG P91-0053 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 12/4/19 2:28 ANG P91-0053 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 12/4/19 2:28 ANG P91-0053 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 12/4/19 2:28 ANG P91-0053 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 12/4/19 2:28 ANG P91-0053 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 12/4/19 2:28 ANG P91-0053 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 2:28 ANG P91-0053 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 12/4/19 2:28 ANG P91-0053 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 12/4/19 2:28 ANG P91-0053 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 12/4/19 2:28 ANG P91-0053 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 12/4/19 2:28 ANG P91-0053 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 12/4/19 2:28 ANG P91-0053 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Laboratory Report P R I S M Full -Service Analytical & LABORATORIES INC. Environmental Solutions 12/06/2019 Smith + Gardner, Inc. Project: Avery MSW Landfill Client Sample ID: Trip Blank Attn: Seth C. Rickerts Prism Sample ID: 9110455-06 14 N. Boylan Avenue Project No.: 0601 Prism Work Order: 9110455 Raleigh, NC 27603 Sample Matrix: Water Time Collected: 11/21/19 00:00 Time Submitted: 11/27/19 08:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 12/4/19 2:28 ANG P91-0053 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 12/4/19 2:28 ANG P91-0053 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 12/4/19 2:28 ANG P91-0053 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 12/4/19 2:28 ANG P91-0053 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 12/4/19 2:28 ANG P91-0053 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 12/4/19 2:28 ANG P91-0053 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 12/4/19 2:28 ANG P91-0053 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 12/4/19 2:28 ANG P91-0053 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 12/4/19 2:28 ANG P91-0053 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 12/4/19 2:28 ANG P91-0053 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 12/4/19 2:28 ANG P91-0053 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 12/4/19 2:28 ANG P91-0053 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 12/4/19 2:28 ANG P91-0053 Surrogate Recovery Control Limits 4-Bromofluorobenzene 97 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 88 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 P R I IS M Full-ServiceAnalytical s Environmental Solutions LABO-RIES, INC. Level II QC Report 12/6/19 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No: 0601 Raleigh, NC 27603 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P911-0053 - 5030B Blank (P91-0053-131-K1) Prepared: 12/03/19 Analyzed: 12/04/19 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 2.0 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 2.0 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 2.0 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 PR I IS M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 12/6/19 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No: 0601 Raleigh, NC 27603 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P911_0053 - 5030B Reporting Result Limit Units Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P9L0053-BLK1) Prepared: 12/03/19 Analyzed: 12/04/19 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 48.5 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 51.1 ug/L 50.00 102 75-129 Surrogate: Toluene -dB 44.5 ug/L 50.00 89 77-123 LCS (P9L0053-BSI) Prepared & Analyzed: 12/03/19 1,1,1,2-Tetrachloroethane 19.0 0.50 ug/L 20.00 95 79-134 1,1,1-Trichloroethane 22.8 0.50 ug/L 20.00 114 75-136 1,1,2,2-Tetrachloroethane 17.7 0.50 ug/L 20.00 89 62-127 1,1,2-Trichloroethane 21.8 0.50 ug/L 20.00 109 70-140 1,1-Dichloroethane 21.7 0.50 ug/L 20.00 109 78-130 1,1-Dichloroethylene 23.5 0.50 ug/L 20.00 118 70-154 1,2,3-Trichloropropane 18.3 1.0 ug/L 20.00 91 71-127 1,2-Dibromo-3-chloropropane 18.1 2.0 ug/L 20.00 91 63-134 1,2-Dibromoethane 19.7 0.50 ug/L 20.00 98 77-135 1,2-Dichlorobenzene 17.9 0.50 ug/L 20.00 90 78-128 1,2-Dichloroethane 21.4 0.50 ug/L 20.00 107 68-131 1,2-Dichloropropane 21.6 0.50 ug/L 20.00 108 77-130 1,4-Dichlorobenzene 17.6 0.50 ug/L 20.00 88 75-126 Acetone 38.4 5.0 ug/L 40.00 96 40-166 Acrylonitrile 42.0 20 ug/L 40.00 105 81-127 Benzene 22.3 0.50 ug/L 20.00 112 77-128 Bromochloromethane 22.7 2.0 ug/L 20.00 113 78-135 Bromodichloromethane 21.9 0.50 ug/L 20.00 109 76-138 Bromoform 19.3 1.0 ug/L 20.00 97 71-135 Bromomethane 22.9 1.0 ug/L 20.00 114 41-168 Carbon disulfide 23.6 5.0 ug/L 20.00 118 59-135 Carbon Tetrachloride 23.9 2.0 ug/L 20.00 120 72-142 Chlorobenzene 19.5 0.50 ug/L 20.00 98 78-119 Chloroethane 27.8 0.50 ug/L 20.00 139 57-142 Chloroform 21.7 0.50 ug/L 20.00 108 77-130 Chloromethane 22.0 0.50 ug/L 20.00 110 47-145 cis-1,2-Dichloroethylene 21.9 0.50 ug/L 20.00 109 76-141 cis-1,3-Dichloropropylene 22.1 0.50 ug/L 20.00 ill 65-140 Dibromochloromethane 19.2 0.50 ug/L 20.00 96 75-134 Dibromomethane 21.9 2.0 ug/L 20.00 110 76-138 Ethylbenzene 19.3 0.50 ug/L 20.00 97 80-127 m,p-Xylenes 38.3 1.0 ug/L 40.00 96 77-133 Methyl Butyl Ketone (2-Hexanone) 16.7 5.0 ug/L 20.00 84 64-137 Methyl Ethyl Ketone (2-Butanone) 22.2 5.0 ug/L 20.00 ill 71-134 Methyl Iodide 19.2 5.0 ug/L 20.00 96 70-130 Methyl Isobutyl Ketone 19.8 5.0 ug/L 20.00 99 69-134 Methylene Chloride 21.3 1.0 ug/L 20.00 106 73-131 o-Xylene 19.1 0.50 ug/L 20.00 95 78-128 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 PR I IS M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 12/6/19 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No: 0601 Raleigh, NC 27603 Volatile Organic Compounds by GC/MS - Quality Control Analyte Batch P9L0053 - 5030B Reporting Result Limit Units Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes LCS (P9L0053-BS1) Prepared &Analyzed: 12/03/19 Styrene 19.2 0.50 ug/L 20.00 96 78-129 Tetrachloroethylene 20.7 0.50 ug/L 20.00 103 80-129 Tetrahydrofuran 20.0 10 ug/L 20.00 100 70-130 Toluene 21.8 0.50 ug/L 20.00 109 76-131 trans-1,2-Dichloroethylene 22.2 0.50 ug/L 20.00 ill 76-135 trans-1,3-Dichloropropylene 22.1 0.50 ug/L 20.00 110 67-140 trans-1,4-Dichloro-2-butene 16.8 10 ug/L 20.00 84 70-130 Trichloroethylene 22.6 0.50 ug/L 20.00 113 77-133 Trichlorofluoromethane 27.1 0.50 ug/L 20.00 135 62-148 Vinyl acetate 23.0 2.0 ug/L 20.00 115 34-167 Vinyl chloride 24.3 0.50 ug/L 20.00 122 57-141 Xylenes, total 57.4 1.5 ug/L 60.00 96 77-133 Surrogate:4-Bromofluorobenzene 47.9 ug/L 50.00 96 80-124 Surrogate: Dibromofluoromethane 50.0 ug/L 50.00 100 75-129 Surrogate: Toluene-d8 45.0 ug/L 50.00 90 77-123 LCS Dup (P9L0053-BSD1) Prepared: 12/03/19 Analyzed: 12/04/19 1,1,1,2-Tetrachloroethane 19.0 0.50 ug/L 20.00 95 79-134 0.05 20 1,1,1-Trichloroethane 22.8 0.50 ug/L 20.00 114 75-136 0.09 20 1,1,2,2-Tetrachloroethane 17.7 0.50 ug/L 20.00 89 62-127 0 20 1,1,2-Trichloroethane 21.3 0.50 ug/L 20.00 107 70-140 2 20 1,1-Dichloroethane 21.3 0.50 ug/L 20.00 107 78-130 2 20 1,1-Dichloroethylene 23.3 0.50 ug/L 20.00 116 70-154 1 20 1,2,3-Trichloropropane 17.3 1.0 ug/L 20.00 86 71-127 6 20 1,2-Dibromo-3-chloropropane 17.5 2.0 ug/L 20.00 88 63-134 4 20 1,2-Dibromoethane 19.3 0.50 ug/L 20.00 96 77-135 2 20 1,2-Dichlorobenzene 17.6 0.50 ug/L 20.00 88 78-128 2 20 1,2-Dichloroethane 21.0 0.50 ug/L 20.00 105 68-131 2 20 1,2-Dichloropropane 21.5 0.50 ug/L 20.00 107 77-130 0.7 20 1,4-Dichlorobenzene 17.5 0.50 ug/L 20.00 87 75-126 0.9 20 Acetone 38.8 5.0 ug/L 40.00 97 40-166 1 20 Acrylonitrile 41.2 20 ug/L 40.00 103 81-127 2 20 Benzene 22.0 0.50 ug/L 20.00 110 77-128 1 20 Bromochloromethane 23.0 2.0 ug/L 20.00 115 78-135 2 20 Bromodichloromethane 21.7 0.50 ug/L 20.00 109 76-138 0.6 20 Bromoform 19.1 1.0 ug/L 20.00 95 71-135 1 20 Bromomethane 23.6 1.0 ug/L 20.00 118 41-168 3 20 Carbon disulfide 23.4 5.0 ug/L 20.00 117 59-135 0.8 20 Carbon Tetrachloride 23.7 2.0 ug/L 20.00 118 72-142 1 20 Chlorobenzene 19.1 0.50 ug/L 20.00 96 78-119 2 20 Chloroethane 27.4 0.50 ug/L 20.00 137 57-142 1 20 Chloroform 21.7 0.50 ug/L 20.00 109 77-130 0.09 20 Chloromethane 21.6 0.50 ug/L 20.00 108 47-145 2 20 cis-1,2-Dichloroethylene 21.7 0.50 ug/L 20.00 109 76-141 0.7 20 cis-1,3-Dichloropropylene 21.8 0.50 ug/L 20.00 109 65-140 1 20 Dibromochloromethane 19.2 0.50 ug/L 20.00 96 75-134 0.05 20 Dibromomethane 21.6 2.0 ug/L 20.00 108 76-138 1 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 P R I IS M Full -Service Analytical s Environmental Solutions LABORATORIES, INC. Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No: 0601 Raleigh, NC 27603 Volatile Organic Compounds by GC/MS - Quality Control Level II QC Report 12/6/19 Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9L0053 - 5030B LCS Dup (P9L0053-BSD1) Prepared: 12/03/19 Analyzed: 12/04/19 Ethylbenzene 19.2 0.50 ug/L 20.00 96 80-127 0.5 20 m,p-Xylenes 37.9 1.0 ug/L 40.00 95 77-133 1 20 Methyl Butyl Ketone (2-Hexanone) 17.0 5.0 ug/L 20.00 85 64-137 2 20 Methyl Ethyl Ketone (2-Butanone) 22.9 5.0 ug/L 20.00 115 71-134 3 20 Methyl Iodide 19.5 5.0 ug/L 20.00 97 70-130 1 20 Methyl Isobutyl Ketone 19.8 5.0 ug/L 20.00 99 69-134 0 20 Methylene Chloride 21.1 1.0 ug/L 20.00 105 73-131 1 20 o-Xylene 18.8 0.50 ug/L 20.00 94 78-128 2 20 Styrene 18.9 0.50 ug/L 20.00 94 78-129 2 20 Tetrachloroethylene 20.3 0.50 ug/L 20.00 102 80-129 2 20 Tetrahydrofuran 21.1 10 ug/L 20.00 106 70-130 5 20 Toluene 21.7 0.50 ug/L 20.00 109 76-131 0.5 20 trans-1,2-Dichloroethylene 21.9 0.50 ug/L 20.00 110 76-135 1 20 trans-1,3-Dichloropropylene 21.7 0.50 ug/L 20.00 109 67-140 2 20 trans-1,4-Dichloro-2-butene 17.7 10 ug/L 20.00 88 70-130 5 20 Trichloroethylene 22.7 0.50 ug/L 20.00 114 77-133 0.5 20 Trichlorofluoromethane 26.9 0.50 ug/L 20.00 135 62-148 0.6 20 Vinyl acetate 24.1 2.0 ug/L 20.00 120 34-167 5 20 Vinyl chloride 23.8 0.50 ug/L 20.00 119 57-141 2 20 Xylenes, total 56.6 1.5 ug/L 60.00 94 77-133 1 20 Surrogate:4-Bromofluorobenzene 47.9 ug/L 50.00 96 80-124 Surrogate: Dibromofluoromethane 49.8 ug/L 50.00 100 75-129 Surrogate: Toluene-d8 44.9 ug/L 50.00 90 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 PR I IS M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 12/6/19 Smith + Gardner, Inc. Project: Avery MSW Landfill Attn: Seth C. Rickerts 14 N. Boylan Avenue Project No: 0601 Raleigh, NC 27603 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Analyte Result Limit Units Batch P9KO502 - 5030B Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P9K0502-BLK1) Prepared &Analyzed: 11/27/19 1,4-Dioxane BRL 2.0 ug/L LCS (P9K0502-BS1) Prepared &Analyzed: 11/27/19 1,4-Dioxane 45.8 2.0 ug/L 50.00 92 55-145 LCS Dup (P9K0502-BSD1) Prepared & Analyzed: 11/27/19 1,4-Dioxane 44.3 2.0 ug/L 50.00 89 55-145 3 30 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 PR I IS M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 12/6/19 Smith + Gardner, Inc. Attn: Seth C. Rickerts 14 N. Boylan Avenue Raleigh, NC 27603 Total Metals - Quality Control Analyte Batch P9L0006 - 3005A Project: Avery MSW Landfill Project No: 0601 Prism Work Order: 9110455 Time Submitted: 11/27/2019 8:20:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (P9L0006-BLK1) Prepared & Analyzed: 12/02/19 Antimony BRL 3.0 ug/L Arsenic BRL 1.0 ug/L Barium BRL 10 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 3.0 ug/L Cobalt BRL 2.0 ug/L Copper BRL 10 ug/L Lead BRL 1.0 ug/L Nickel BRL 3.0 ug/L Selenium BRL 5.0 ug/L Silver BRL 1.0 ug/L Thallium BRL 2.0 ug/L Vanadium BRL 5.0 ug/L Zinc BRL 20 ug/L LCS (P91_0006-13S1) Prepared &Analyzed: 12/02/19 Antimony 105 3.0 ug/L 100.0 105 80-120 Arsenic 96.6 1.0 ug/L 100.0 97 80-120 Barium 99.7 10 ug/L 100.0 100 80-120 Beryllium 101 1.0 ug/L 100.0 101 80-120 Cadmium 100 1.0 ug/L 100.0 100 80-120 Chromium 104 3.0 ug/L 100.0 104 80-120 Cobalt 101 2.0 ug/L 100.0 101 80-120 Copper 102 10 ug/L 100.0 102 80-120 Lead 100 1.0 ug/L 100.0 100 80-120 Nickel 102 3.0 ug/L 100.0 102 80-120 Selenium 99.3 5.0 ug/L 100.0 99 80-120 Silver 101 1.0 ug/L 100.0 101 80-120 Thallium 102 2.0 ug/L 100.0 102 80-120 Vanadium 103 5.0 ug/L 100.0 103 80-120 Zinc 101 20 ug/L 100.0 101 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 Sample Extraction Data Prep Method: 3005A Lab Number Batch Initial Final Date/Time 9110455-01 P91-0006 50 mL 50 mL 12/02/19 7:51 9110455-02 P91-0006 50 mL 50 mL 12/02/19 7:51 9110455-03 P91-0006 50 mL 50 mL 12/02/19 7:51 9110455-04 P91-0006 50 mL 50 mL 12/02/19 7:51 9110455-05 P91-0006 50 mL 50 mL 12/02/19 7:51 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 9110455-01 P91-0053 10 mL 10 mL 12/03/19 13:56 9110455-02 P91-0053 10 mL 10 mL 12/03/19 13:56 9110455-03 P91-0053 10 mL 10 mL 12/03/19 13:56 9110455-04 P91-0053 10 mL 10 mL 12/03/19 13:56 9110455-05 P91-0053 10 mL 10 mL 12/03/19 13:56 9110455-06 P91-0053 10 mL 10 mL 12/03/19 13:56 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 9110455-01 P91<0502 5 mL 5 mL 11/27/19 11:37 9110455-02 P91<0502 5 mL 5 mL 11/27/19 11:37 9110455-03 P91<0502 5 mL 5 mL 11/27/19 11:37 9110455-04 P91<0502 5 mL 5 mL 11/27/19 11:37 9110455-05 P91<0502 5 mL 5 mL 11/27/19 11:37 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 23 DocuSign Envelope ID: F82929E6-4A18-470E-B82F-AFB30702E125 D D 0, CD C) u ID Iv N cn T I I -o !v K r u CD 0 0 7 (D a C� m D n o� m CD O 0I N N U) y cND oI CD Iv a v N O DO G) z D r ❑ ❑Z \ p NC cn U7 cecnMMI �. c O C-) n B° ❑�x ��W � � VL) 333 r r 0 — R QQ,�n. 0 o a a s N C) e 3� ^em m A e/? �) "' n o�i a 1 `, y m 0 0 0 cn 0AO �� c r V" 1 `< p a �a.•• g Z m o rrr -V r K CL Z:V om f �0 p Dn tom, m� 0m P� m k nc �n Z n00 N 1 0 N O im cn �+ z a (` I' O /� C19� r u n =�0 C7 n a G co) �'< � N C 5 Q o0 �`< < r °a m e O fr L)i or01 c 0 m 3 � M y �� A CO d „m 1c d out © yDnm M jo ❑ ❑O m ❑ oD mom' zZ > Dm M. cn 7Cv Dy ? I•, rDy3 S n� 0 3' a n o W D 0 g. s �- mo- x z z � m a CE�' 33 o a c m�� rt -C7 m m-I 00j ymv m 0 mo �4 0o Z ❑❑� m w 'm o' � a G � m D mmccW M m U u © a m r m m v (D m m m � O C) Q v 0(D ❑ 2� �I g s�i a �j+ Y � n rom w a W m m m '�° cn(n m �y-i oF. Q� w �m m �s _i< A- p O v'Ium D Z yAa ❑ ❑ . 5 d W09 y m am o.n m W o �3QC8' m — O , M r :3 El ❑X i0� 7d y m N 7 m w c i m,ju OR. LA, o. ❑ � 10 Zn zD � C) {O (fin (D /y1 m I Liro m OZ nu N 0 -V Z'a cn O S y n C) z <M O m w a N 7 Zym In ° ❑ m M m � D ❑cn my �; \ -q m mm P;u w ocmiQx o Z rZJ O 7 M r�tn = y r .; pip or .<G m - [n : r y ❑ Y O .Q 'D z Z W m ❑ d0z W ❑ A " cn Nm D n (D • v -am Aj 4Ny m aD y ,`I] < W p� r m mm��� n� `, �o ~° o n�+ lVs� X a�p�� = � o a m \J�, �• '� 3 ` • ��]] 17 Q Fi m - m � 03 N CD Z D ❑O S �� , c -e m nm \ v�� `° W ❑ V1 W - m c = m m Q c� n 2) -n r o 0. ° � m D a a c v 0'D co m Z o 3 C. C1 - o �I � '' 0 tmn O �I 3 3_ � Z Z m v -! z 3 CA O v D CMI 3 g T cn cn y r CD 0. m m ro 0 D r1 Z Z r ����. z D I - CD IO m 1 0 n c)O m G y 5 z p OD cn r m m = 3 n (a3 T' Q. O y a V IZ .3i Q Q � = ('D Z O fA .O. N AC a 3 O �/ ) •• NO O a (nX N 1 a T '� n K m m m c P V O AN (D 7J N z 3 < C\� O N = CD w Cii tON c) w' o r1 -.0 m po n 2' < C (pp O L0 A xc (-a 3 D o Z N --1 a d V 3 M m r z O = K N � / 0 `� [1 P p �! _0• C ID u O `N% 'm r. i o •• y} m 3 0 y Fie'� A m O I 9 a C n r m C) l0 r A 3. nI n O i 7 rm � M .°. M r M mu 0 O w O W 3 -i M r, O Wa M a N m a (MnC X Z tWi D = m D o y a� Z; m r �.� O r0 � 3 1 I� 1 n 0< M D, o cr � (�p N 0 N 2 m CD J 0 C' 0 f c Page 23 of 23 Certificate Of Completion Envelope Id: F82929E64A18470FB82FAFB30702El25 Subject: Please DocuSign: 06-01 Avery Nov 2019 Avery MSW Water Quality Report.pdf Source Envelope: Document Pages: 46 Signatures: 3 Certificate Pages: 2 Initials: 1 AutoNav: Enabled Envelopeld Stamping: Enabled Time Zone: (UTC-08:00) Pacific Time (US & Canada) Record Tracking Status: Original 12/31/2019 10:24:55 AM Signer Events Seth C. Rickerts seth@smithgardnerinc.com Smith Gardner, Inc. Security Level: Email, Account Authentication (None) Electronic Record and Signature Disclosure: Not Offered via DocuSign Joan Smyth joan@smithgardnerinc.com Vice President Smith Gardner, Inc. Security Level: Email, Account Authentication (None) Electronic Record and Signature Disclosure: Not Offered via DocuSign In Person Signer Events Editor Delivery Events Agent Delivery Events Intermediary Delivery Events Certified Delivery Events Carbon Copy Events Witness Events Notary Events Envelope Summary Events Envelope Sent Certified Delivered Signing Complete Holder: Joan Smyth joan@smithgardnerinc.com Signature EDII"Sil"Id by: ati L. 2,<t�s 3B8305CMEME6... Signature Adoption: Pre -selected Style Using IP Address: 24.106.183.110 byyy:,yEDI-Sig"_SId EBA711F S Signature Adoption: Pre -selected Style Using IP Address: 24.106.183.110 Signature Status Status Status Status Status Signature Signature Status Hashed/Encrypted Security Checked Security Checked Docu5�". 6 S E C U R E D Status: Completed Envelope Originator: Joan Smyth 14 N. Boylan Ave Raleigh, NC 27603 joan@smithgardnerinc.com IP Address: 24.106.183.110 Location: DocuSign Timestamp Sent: 12/31/2019 10:25:57 AM Resent: 1/2/2020 5:11:55 AM Viewed: 1/2/2020 8:24:00 AM Signed: 1/2/2020 8:24:09 AM Sent: 1/2/2020 8:24:10 AM Viewed: 1/2/2020 12:17:15 PM Signed: 1/2/2020 12:17:18 PM Timestamp Timestamp Timestamp Timestamp Timestamp Timestamp Timestamp Timestamp Timestamps 1/2/2020 8:24:10 AM 1/2/2020 12:17:16 PM 1/2/2020 12:17:18 PM Envelope Summary Events Completed Status Security Checked Timestamps 1/2/2020 12:17:18 PM Payment Events Status Timestamps