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MO_88110_88110_CA_O_20191111_Letter to Wilson Residents (Lot 6)
JACOBS November 11, 2019 Delivered via Email (wilsodg@gmail.com) Mr. and Mrs. Derek Wilson 1243 Middlecrest Drive NW Concord, North Carolina 28027 Subject: Results from Recent Soil Vapor Monitoring Plantation Pipe Line Company Poplar Tent Road Site NCDEQ Groundwater Incident No. 88110 Dear Mr. and Mrs. Wilson, 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 www.jacobs.com Thank you for allowing Plantation Pipe Line Company's representatives (Jacobs) to conduct semiannual soil vapor monitoring activities on your property in October 2019. The purpose of this letter is to provide a summary of the monitoring activities conducted on your property, along with a summary of the analytical results. October 2019 Monitoring Activities On October 10, 2019, Jacobs sent you an email requesting access to your property to collect samples from soil vapor monitoring points SV-5R and SV-14R (see attached figure). On October 17, 2019, leak checks were conducted on each soil vapor monitoring point prior to collecting a vapor sample. Both soil vapor monitoring points passed the leak check and were purged with an electric sampling pump prior to sample collection. Soil vapor samples were then collected using vacuum canisters and sampling syringes with charcoal tubes. The samples were submitted to Eurofins TestAmerica in Knoxville, Tennessee for analysis of benzene, toluene, ethylbenzene, xylenes (BTEX), naphthalene, and 2-methyl naphthalene. Analytical Results The analytical data from the October 17, 2019 monitoring event are attached to this letter and are summarized in Table 1. When reviewing the laboratory analytical report, please note the sample identifications for your soil vapor monitoring points are SV-5R-101719, and SV-14R-101719. Duplicate samples were collected from soil vapor monitoring point SV-5R as part of a standard practice to measure field and laboratory precision, as well as to provide an indication of the comparability of the results. The duplicate sample identification is SV-5RD-101719. Data from historical monitoring events are shown in Table 2. The analytical results show that the samples collected in October 2019 were significantly lower than North Carolina Department of Environmental Quality (NCDEQ) and United States Environmental Protection Agency (USEPA) regulatory screening criteria, as shown in Table 1. The purpose of these soil gas criteria is for "screening" site data to help identify areas, contaminants, and conditions that may require further evaluation or attention. Jacobs Engineering Group Inc. Mr. and Mrs. Derek Wilson November 11, 2019 JACOBS Page 2 of 2 The results of the October 2019 monitoring event are generally consistent with the results of the previous monitoring events. As shown in Table 2, some variability is apparent when comparing the data from the historical monitoring events. In general, soil vapor monitoring results are expected to vary due to several factors, including seasonal temperature changes, changes in barometric pressure, changes in water table elevations, changes in subsurface conditions due to precipitation prior to a monitoring event, changes in subsurface conditions due to operation of the remediation system, and variations in the contaminant source concentrations. Soil Vapor Monitoring Plan The next semiannual monitoring event is planned for April 2020. A Jacobs representative will contact you separately to coordinate this monitoring event. As discussed in the Meeting Summary and Rebound Monitoring Plan letter that Jacobs submitted to NCDEQ on May 30, 2019, the biosparging and SVE systems were turned off at the end of April 2019 for rebound monitoring through April 2020. Thank you for your assistance and we apologize for any inconvenience this sampling program may cause. Please feel free to contact me at 704.543.3285 or Jerry Aycock with Plantation at 770.751.4165 if you have any questions about the monitoring results. The NCDEQ is an additional resource to discuss aspects of the site and our monitoring activities. Ms. Trudy Beverly is the NCDEQ case manager and can be contacted at 704.663.1699 concerning this site (NCDEQ Incident #88110). Again, thank you for your cooperation. Sincerely, Mike Skeean, P.E. Senior Project Manager Copies to: Jerry Aycock, Plantation (via email) Trudy Beverly, North Carolina Department of Environmental Quality (via email and USPS) Brian Pace, Laureldale LLC (via email) File —Jacobs Attachments: Table 1 — Soil Vapor Analytical Results (October 2019) Table 2 — Historical Soil Vapor Analytical Results (October 2007 through October 2019) Figure 1 — Biosparging/SVE System As -Built Analytical Laboratory Report Tables Table 1 Soil Vapor Analytical Results (October 2019) Poplar Tent Road Plantation Pipe Line Company Concord, Cabarrus County, North Carolina C L19 = v N LCl C c h aD c %+ ti Date Collected G> c 0 y 0 r 0 r X O G1 r �' O M O t M r °' O Sample ID (MM/DD/YYYY) m � >+ t a X 0 Q. a LU Z C p /m3 SV-5 R-101719 10/17/2019 ND <2.6 N D <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.74 ND <2.64 SV-5RD-1017191 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.74 ND <2.64 SV-14R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 ND <1.74 ND <2.64 Soil Gas Screening Criteria 120 34,800 374 695 695 20.9 NS Soil Gas Screening Criteria 120 34,800 374 695 695 21 NS Notes: 'Duplicate sample collected from SV-5R. 2February 2018 North Carolina Department of Environmental Quality Division of Waste Management Residential Vapor Intrusion Screening Levels for Sub -Slab and Exterior Soil Gas (SGSL) based on an attenuation factor of 0.03. https://files.nc.gov/ncdeq[Waste%20Management/DWM/SF/RiskBasedRemediation/Feb2018_Res_VISLs.pdf 3USEPA Vapor Intrusion Screening Levels (VISL) Calculator (AF = 0.03), TRL = 10-5 or THQ = 0.2, accessed June 19, 2019. https://epa-visl.ornl.gov/cgi-bin/visl_search 4The method detection limit is presented for samples analyzed by TO-17 in October 2019. < - Indicates value is less than the shown reporting limit pg/m3 - micrograms per cubic meter J - estimated value ND - not detected NS - no soil gas screening criteria available AF - Attenuation Factor TRL - Target Risk Level THQ - Target Hazard Quotient USEPA - United States Environmental Protection Agency Bold text with gray highlighting indicates exceedance of one or more screening criteria Table 2 Historical Soil Vapor Analytical Results (October 2007 through October 2019) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina Sample ID Date Collected (MM/DD/YYYY) v C ll1 O1 rl C O v co y C ll1 y .y 3 O o ~ v I N IA c O r {y w N Ill x 0 c £' C Ill 5' O x v L O a ;, m Z a _ s O a F , Z v T Ol y r ? CL N m C v T Ol y r O ? c F- N m C ^ O IA a p w y x µg/ms SV-05-100307 10/3/2007 ND < 2.4 0.6 J ND < 2.4 0.6 1 ND < 2.4 ND < 2.4 NA 0.49 1 NA 3.0 J SV-5 11/27/2007 ND < 1.9 11 2.9 8.5 3.0 ND < 1.9 NA ND < 1.9 NA 11.5 SV-5R-111612 11/16/2012 ND<2.36 7.86 J ND<3.20 ND<6.40 ND<3.20 ND<3.87 4.8 ND<4.29 ND<2.1 ND<3.20 SV-5R-D-1116121 11/16/2012 ND < 2.45 6.67 J ND < 3.33 18.3 1 4.33 il ND < 4.03 7.3 J 6.33 J ND < 2.2 22.6 J SV-5R-030413Z 03/04/2013 ND<0.23 0.14 J,B ND<0.30 ND<0.30 0.016 J ND<0.30 ND<2.50 ND<1.50 ND<2.50 NA SV-5RD-0304131'Z 03/04/2013 ND < 0.22 0.25 J, B 0.021 J 0.054 1 0.024 J ND < 0.29 ND < 2.50 ND < 1.40 ND < 2.50 NA SV-5R-0304133 03/04/2013 ND < 1.66 1.20 J ND < 2.26 0.663 J ND < 2.26 ND < 2.73 ND < 2.40 ND < 6.03 ND < 2.40 ND < 6.80 SV-5RD-0304131'3 03/04/2013 ND < 1.76 0.556 J ND < 2.39 ND < 4.77 ND < 2.39 ND < 2.89 ND < 2.40 ND < 6.39 1.0 J ND < 7.20 SV-5R-080513 8/5/2013 0.071 J 0.30 0.029 J 0.11 1 0.085 J 0.085 J ND < 2.5 ND < 0.77 ND < 2.5 NA SV-5RD-0805131 8/5/2013 0.071 J 0.26 0.020 J 0.049 1 0.03 J 0.039 J ND < 2.5 ND < 0.82 ND < 2.5 NA SV-5R-022714 02/27/2014 0.091 J 0.28 0.048 J 0.19 0.087 J 0.056 J ND < 2.5 0.18 X ND < 2.5 NA SV-5RD-0227141 02/27/2014 0.13 0.27 0.052 J 0.18 0.082 J 0.049 J ND < 2.5 ND < 0.16 X ND < 2.5 NA SV-5R-092314 09/23/2014 0.039 J 0.11 J ND < 0.15 0.035 J 0.015 J NA ND < 2.S NA ND < 2.5 NA SV-5RD-0923141 09/23/2014 0.14 J 0.054 J ND < 0.14 0.026 1 ND < 0.14 J NA ND < 2.5 NA ND < 2.5 NA SV-5R-04281S 04/28/2015 ND<0.16 ND<0.81 ND<0.81 ND<0.81 ND<0.81 NA ND<2.S R NA ND<2.5 R NA SV-5RD-0428151 04/28/2015 0.2S 0.27 J ND<0.78 ND<0.78 ND<0.78 NA ND<2.S R NA ND<2.5 R NA SV-5R-10131S 10/13/2015 62 J ND <360 150 J 440 160 J NA ND <2.5 NA ND <2.5 NA SV-5RD-1013151 10/13/2015 ND <68 ND <340 150 1 430 180 1 NA ND <2.S NA ND <2.5 NA SV5R-121015 12/10/2015 91 ND <86 480 2,400 2,100 NA NA NA NA NA SV5RD-1210151 12/10/2015 120 ND <87 600 2,900 2,600 NA NA NA NA NA SV-5R-022916 02/29/2016 5.1 1 ND <3.5 57 J 340 J 510 J NA 3.1 NA 3.0 NA SV-5RD-0229161 02/29/2016 12 1 4.2 J 140 1 820 1 1,200 1 NA 2.0 1 NA 2.1 J NA SV-5R-041116 04/11/2016 21 ND<42 320 1,700 1,600 NA 2.2 1 NA ND<2.5 NA SV-5RD-0411161 04/11/2016 21 ND < 38 310 1,700 1,600 NA 2.3 1 NA ND < 2.5 NA SV-5R-062716 06/27/2016 1.2 1.2 17 110 260 D NA 1.1 1 NA ND < 2.5 NA SV-5RD-0627161 06/27/2016 0.90 0.57 J 16 110 250 D NA 1.5 1 NA 0.77 J NA SV-5R-090716 09/07/2016 0.17 1 1.3 ND <0.89 ND <0.89 ND <0.89 NA ND <2.5 NA 0.64 J NA SV-5RD-0907161 09/07/2016 ND <0.20 0.54 J ND <1.0 ND <1.0 ND <1.0 NA ND <2.5 NA 0.45 1 NA SV-5R-101816 10/18/2016 ND <0.15 0.30 J ND <0.76 ND <0.76 ND <0.76 NA ND <2.5 NA ND <2.5 NA SV-5RD-1018161 10/18/2016 ND <0.15 ND <0.74 ND <0.74 ND <0.74 ND <0.74 NA ND <2.5 NA ND <2.5 NA SV-5R-041817 04/18/2017 ND <7.5 ND <37 13 1 97 130 NA ND <2.5 NA 0.44 1 NA SV-5RD-0418171 04/18/2017 ND <7.3 ND <36 13 1 100 140 NA ND <2.5 NA ND < 2.5 NA SV-5R-100917 10/09/2017 ND <0.73 1.4 J 1.8 1 14 27 NA 2.0 1 NA 0.63 J NA SV-5RD-100917 10/09/2017 ND <0.75 ND <3.8 1.9 J 14 27 NA 1.6 J NA ND < 2.5 NA SV-5R-041718 04/17/2018 ND <7.3 ND <36 ND <36 ND <36 12 NA ND <2.5 NA 5.0 NA SV-5RD-0417181 04/17/2018 NA NA NA NA NA NA ND <2.5 NA 4.9 NA SV-5R-101718 10/17/2018 NA NA NA NA NA NA ND <2.5 NA 3.5 NA SV-5RD-1017181 10/17/2018 NA NA NA NA NA NA ND <2.5 NA 3.1 NA SV-5R-101918 10/19/2018 ND <7.6 5.6 J ND <39 ND <83 5.9 J NA NA NA NA NA SV-5RD-1019181 10/19/2018 ND <8.0 ND <42 ND <42 ND <88 ND <42 NA NA NA NA NA SV-5R-042419 04/24/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA 280 1 NA 34 J NA SV-5RD-0424191 04/24/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA 260 1 NA 32 J NA SV-5R-071019 07/10/2019 NA NA NA NA NA NA ND <1.7 NA ND <2.6 NA SV-5RD-0710191 07/10/2019 NA NA NA NA NA NA ND <1.7 NA ND <2.6 NA SV-5R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA ND <1.7 NA ND <2.6 NA SV-5RD-1017191 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA ND <1.7 NA ND <2.6 NA SV-14-100307 10/3/2007 ND < 2.3 0.3 J ND < 2.3 ND < 4.7 ND < 2.3 4.0 NA 1.3 1 NA ND < 7 SV-14 11/28/2007 ND < 1.8 1.4 J 0.53 J 1.5 1 0.56 J ND < 1.8 NA ND < 1.8 NA 2.06 J SV-14R-111612 11/16/2012 ND < 0.89 ND < 1.05 1.50 Ji 4.15 J ND < 1.21 ND < 1.47 4.6 ND < 1.63 ND < 1.7 5.30 J SV-14R-0304132 03/04/2013 ND < 0.21 0.27 J, B 0.016 J 0.059 1 0.046 J 0.12 J ND < 2.50 ND < 1.40 ND < 2.50 NA SV-14R-0304133 03/04/2013 0.679 J 0.521 J ND < 1.99 ND < 3.98 ND < 1.99 ND < 2.4 ND < 2.40 ND < 5.32 2.4 J ND < 5.96 SV-14R-080513 8/5/2013 0.054 J 0.40 0.054 J 0.23 0.18 J 0.13 J ND < 2.5 0.98 ND < 2.5 NA SV-14R-022714 2/27/2014 0.084 J 0.24 0.042 J 0.13 .11 0.18 J 0.035 J ND < 2.5 0.15 X ND < 2.5 NA SV-14R-092314 09/23/2014 0.024 J 0.073 J ND < 0.14 0.034 J 0.013 J NA ND < 2.5 NA ND < 2.5 NA SV-14R-042815 04/28/2015 ND<0.13 ND<0.66 ND<0.66 ND<0.66 ND<0.66 NA ND<2.5 R NA 0.50 1 NA SV-14R-101315 10/13/2015 ND <0.14 1.7 ND <0.70 ND <0.70 ND <0.70 NA ND <2.5 NA ND <2.5 NA SV14R-12101S 12/10/2015 ND <170 ND <170 ND <170 ND <330 ND <170 NA NA NA NA NA SV-14R-022916 02/29/2016 ND <0.13 0.31 J ND <0.65 ND <0.65 ND <0.65 NA 1 2.3 J1 NA 1 2.6 NA SV-14R-041116 04/11/2016 ND <0.15 0.70 1 ND <0.73 ND <0.73 ND <0.73 NA I ND <2.5 1 NA ND <2.5 NA Table 2 Historical Soil Vapor Analytical Results (October 2007 through October 2019) Poplar Tent Road Site Plantation Pipe Line Company Concord, Cabarrus County, North Carolina C 111 Ifl N Ln N Date Collected c 0 3 0 o a 0 x 0 7' 0 x L 0 a~ 0 °' 0 r d+ O ... d 0 Sample ID (MM/DD/YYYY) a `° ~ > r r a H £' r °' m n v m a e i C 2 a 2 e.i C , r W Z Z C C X µg/ms SV-14R-062716 06/27/2016 0.15 J 0.31 1 ND <0.84 ND <0.84 ND <0.84 NA ND <2.5 NA ND <2.5 NA SV-14R-101816 10/18/2016 ND <0.16 ND <0.80 ND <0.80 2.8 1.0 NA ND <2.5 NA ND <2.5 NA SV-14R-041817 04/18/2017 ND <0.14 ND <0.69 ND <0.69 ND <0.69 ND <0.69 NA ND <2.5 NA ND <2.5 NA SV-14R-100917 10/09/2017 ND <0.15 0.33 J ND <0.77 ND <0.77 ND <0.77 NA 2.0 1 NA 0.65 1 NA SV-14R-041718 04/17/2018 ND <0.15 0.591 ND <0.76 ND <0.76 ND <0.76 NA NA NA NA NA SV-14RD-0417184 04/17/2018 ND <0.15 ND <0.74 ND <0.74 ND <0.74 ND <0.74 NA NA NA NA NA SV-14R-050318 05/03/2018 0.14J 0.86 ND<0.85 1.81 1.0 NA ND<2.5 NA ND<2.5 NA SV-14RD-0503194 05/03/2018 0.23 3.6 0.40 J 1.51 0.55 J I NA ND <2.5 NA ND <2.5 NA SV-14R-101718 10/17/2018 0.191 0.161 ND <2.3 ND <5.0 ND <2.4 NA ND <2.5 NA 2.3 J NA SV-14R-042419 04/24/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA ND <9.4 J NA ND <4.2 J NA SV-14R-101719 10/17/2019 ND <2.6 ND <4.5 ND <3.5 ND <3.5 ND <3.5 NA ND <1.7 NA ND <2.6 NA l Gas Screening Criteria5 120 34800 374 695 695 20.9 20.9 NS NS 695 l Gas Screening Criteria' LO 120 35000 370 700 700 21 21 NS NS 700 Notes: 'Duplicate sample collected from SV-5R 2 Sample analyzed at AILS Environmental 3aample analyzed at ASL/Eurofins Air Toxics °Duplicate sample collected from SV-14R 5February 2018 North Carolina Department of Environmental Quality Division of Waste Management Residential Vapor Intrusion Screening Levels for Sub -Slab and Exterior Soil Gas (SGSL) based on an attenuation factor of 0.03. https://fiiles.nc.gov/ncdeq/Waste%2OManagement/DWM/SF/RiskBasedRemediation/Feb2O18_Res_VISLs.pdf 6USEPA Vapor Intrusion Screening Levels (VISL) Calculator (AF = 0.03). TRL = 10-5 or THQ = 0.2, accessed June 19, 2019. https://epa-visi.orni.gov/cgi-bin/visl_search 'The method detection limit is presented for samples analyzed by TO-17. < - Indicates value is less than the shown reporting limit. pg/m3 - micrograms per cubic meter D - reported result is from a dilution J - estimated value R - data was rejected during validation x - excluded. Preferred analytical method for 2-Methylnaphthalene is TO-17. See case narrative in laboratory report. ND - not detected NS - no soil gas screening criteria available B - Analyte detected in both the sample and associated method blank NA - not analyzed AF - Attenuation Factor TRL - Target Risk Level THQ - Target Hazard Quotient USEPA - United States Environmental Protection Agency Id text with gray highlighting indicates exceedance of one or more screening criteria Figure WF TREED /_ 1,000 GALLON / / // / // / / / \ IOU 4%� 7I7ANSEORMER f 4\�� STORAGE TANK /MW-12 / CONRETE PAD I II / MW-13 a BuO T BIOSPARGING AND SVE I II / II I SVE / BIOSPARGING I r s EQUIPMENT BUILDING I II a III CONVEYANCE LINES I (HDD UTILITY BORE) I II HOUSE U SVE/BIOSPARGING CONVEYANCE LINES I II I I I 430' 1 TOTAL I / \ / TRENCH I Iq III III 21.5' j MAX. DEPTH 1 36' CM11 --, Hrcc,ti I I I • ..:�.. WALNUT ., TREE O r--------- I I II �iiii -1 - ---� �,/ D - - I DRAIN C-2UNDERGROUND, �— =_ _— — 'a IOSPARGING I MW-11D I A ONVEYANCE LINE rc, 6" PLASTIC I T+�\�\ \ \ \ _ C-1 RENCHI / UNDERGROUND I DRAIN OUTLET \\ \ \ \\ PZ-14\� \ \\��ePZ \\ I GATE " • GRAVEL EXISTING DPE TRENCH _ , _ DRIVE I ` `y_ 4 HBS-1- \\\ SV-16A \\ \ \\ -15 O_ -'��-------------- - 1 --- ------------- - -------- _ — — — — — ——Si�15B- - sv-15 _ 6T • - — J� — — - --- - \ -�F - _ _ 6 — �T31— - ----_----------- ---------- " --------------- ----------- -----------�� �\ W 9_P M - R 11 .or � Mw_IO LOCATION OF ° HBS2 ---- I R 1 r , / — 1976 RELEASE _ RW-9 l 11 p 17 % F-F F MW-Fl —F _F —F i� - RW-1 - — — _ ------------------- ,' MW-1T------------ P—Q---- _ - _ - R HORIZONTAL I HORIZONTAL I I - BIOSPARGING WELL BIOSPARGING WELL FORMER DPE WELLS 298 RISER 304' RISER OPERATING AS SVE \) 216' SCREEN (RW-7,RW-15,RW-16, 298' SCREEN RW-12, RW-13 AND 514' TOTAL 602' 60' TOTAL DEPTH FROM ENTRY POINT 14 60' DEPTH FROM ENTRY POINT F F F -F F F -F LOT 6 1 .:>':; .. LOT 1+ SV- / \ NNW-B 1 It sv �� HORIZONTAL SOIL VAPOR EXTRACTION WELL 20' SIDE 18RISER 120' SCREEN y 4/ \ 136' TOTAL /J •-� /4/ T-13' DEPTH >1\m w M`ppLE 103 E 0t) V PRE 6 SURVEY BY TAYLOR WISEMAN & TAYLOR DRAINAGEWAY SVE / BIOSPARGING TRENCH (TO SVE CONVEYANCE LINES ACCESS CLEAN OUTSNERTICAL. VAULT BIOSPARGING \ WELLS) 18" DEPTH p V V-10R SV- ,SVE--, 1 0 14 SVE-3 DEEP VERTICAL BIOSPARGING WELLS 71'-74' DEPTH 14W-704. \\ t k 1 \ DEEP V MIDDLECREST DRF IOSPA GENGICAL WELLS /4� 60'PUBLIC R/I VEYANCE TRENCHPIPING LEGEND SANITARY SEWER MANHOLE FIRE HYDRANT CURB INLET CONCRETE CURB LIGHT POLE CONCRETE ® WOOD WALKWAY - — — - PROPERTY LINE RIGHT OF WAY — — — SANITARY SEWER —"'— WATERLINE ------- STORM SEWER EXISTING 26" U/G GASOLINE LINE — °—°—°— °— EXISTING 10" U/G FIBER OPTIC LINE — F -- F — ° — EXISTING 14" U/G DIESEL FUEL LINE ——"°F— UNDERGROUND ELECTRIC > + OVERHEAD ELECTRIC TREE LINE (qMW-8 SHALLOW MONITORING WELL Q�MW-BD DEEP MONITORING WELL ®MW-BT TRANSITION ZONE MONITORING WELL OPZ-9 PIEZOMETER +SW--101 SURFACE WATER SAMPLING LOCATION °❑ RECOVERY WELL + - DPE ANGLED WELL QO SV-5R SOIL VAPOR MONITORING POINT SVE-2 ❑ VERTICAL SVE WELL 19 SVE ACCESS VAULT ■ SOURCE AREA SVE WELL VERTICAL BIOSPARGING WELL CONVEYANCE PIPING ASSOCIATED WITH THE BIOSPARGING SYSTEM CONVEYANCE PIPING ASSOCIATED WITH THE SVE SYSTEM ++++++++++++++++++++++++ SCREEN ED I NTERVAL -+++++++++++++++++++++#+ = = = = INSTALLATION VIA HDD o� 0 30 60 120 APPROXIMATE SCALE IN FEET Figure 1. Biosparging/SVE System As -Built Poplor Tent Road Site Plantation Pipe Line Company JACOBS® Concord, North Carolina KinderMorgan\358526PoplarTent\Reports\Groundwater Monitoring Reports\2018 Annual Report\Figures\CADD Analytical Laboratory Report JACOBS Memorandum 14120 Ballantyne Corporate Place, Suite 200 Charlotte, North Carolina 28277 United States T +1.704.544.4040 F +1.704.544.4041 Subject Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site Soil Vapor Project Name Plantation Pipe Line Poplar Tent Road Site Attention Kelly Gutowski/CLT, Jacobs Mike Skeean/CLT, Jacobs From Tiffany Davis/GNV, Jacobs Date November 4, 2019 Copies to Juan Acaron/GNV, Jacobs 1. Introduction The purpose of this memorandum is to present the results of the data validation process for the soil vapor samples collected at the Plantation Pipe Line Company (PPL) Poplar Tent Road Site located in Concord, North Carolina. The samples were collected on October 17, 2019. Samples were submitted to Eurofins TestAmerica, Knoxville in Tennessee for the following analyses: • T015 SIM Volatiles • T017 Volatiles These data for Sample Delivery Groups (SDGs) J17050 and J17112 were validated for compliance with the analytical method requirements. This process included a review of these data to assess the accuracy, precision, and completeness based upon procedures described in guidance documents such as the Environmental Protection Agency (EPA) National Functional Guidelines for Organic Data Review (EPA 2017) and the USEPA, Compendium of Methods for the Determination of Toxic Organic Compounds in Ambient Air, Second Edition (EPA 1999). The Quality assurance/quality control (QA/QC) summary forms and data reports were reviewed and the resulting findings are documented within each subsection that follows. During the data validation, if QA/QC parameters were not within the acceptance limits, associated sample results were appended with a primary qualifying flag that indicated a possible anomaly with these data. The qualifying flags originated during the data review and validation processes. This qualification also included the use of secondary sub -qualifier flags. The secondary qualifiers provide the reasoning behind the assignment of a qualifier to these data. The definitions of the primary qualifiers are presented below. 2. Validation Flag Definitions The following primary qualifiers were used to qualify the data: [_]: Detected. The analyte was analyzed for and detected at the concentration shown. [J]: Estimated. The analyte was present, but the reported value may not be accurate or precise. [U]: Undetected. The analyte was analyzed for but not detected above the method detection limit. [UJ]: Detection limit estimated. The analyte was analyzed for but qualified as not detected; the detection limit is estimated. JACOBS' Data Validation Summary- Plantation Pipe Line Poplar Tent Road Site Soil Vapor [R]: Rejected. The data are not useable. [X]: Excluded. Data were not used due to another value being more appropriate. 3. Organic Parameters 3.1 Quality Control Review The following list represents the QA/QC measures that were reviewed during the data quality evaluation procedure for organic data: • Holding Times — The holding times are evaluated to verify that samples were extracted and analyzed within holding times. • Blank samples — Method blank samples were provided for this project. Blank samples enable the reviewer to determine if an analyte may be attributed to sampling or laboratory procedures, rather than environmental contamination from site activities. • Surrogate Recoveries — A surrogate compound is added to each sample and the recovery is used to monitor lab performance and possible matrix interference. • Lab Control Sample (LCS) — These samples are a "controlled matrix", such as humidified nitrogen, in which target compounds have been added prior to extraction/analysis. The recoveries serve as a monitor of the overall performance of each step during the analysis, including sample preparation. • Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples — Spike recovery is used to evaluate potential matrix interferences, as well as accuracy. Precision information is also determined by calculating the reproducibility between the recoveries of each spiked parameter. • Field Duplicate Samples — These samples are collected to determine precision between a native and its duplicate. This information can only be determined when target compounds are detected. 4. Volatile Organic Compound Analyses The QA/QC parameters for VOC analyses by EPA Methods TO-15 and TO-17 for all samples were within acceptable control limits with the exceptions listed below. A brief overview of the data evaluation follows: 4.1 Holding Times (and Sample Receipt) All holding time requirements were met. 4.2 Analytical Blanks No target analytes were detected in the blanks. 4.3 Recoveries — Surrogates, MS/MSD, LCS/LCSD Surrogates and LCS/LCSD recoveries all met acceptance criteria. A MS/MSD set was not collected for this event. 4.4 Field Duplicates Duplicate field samples were collected and submitted to the laboratory for analysis. There are two conditions under which the native and field duplicate are deemed outside acceptance criteria. For condition one, if a result for the native and field duplicate are less than five times the reporting limit, the two results must be within one times the reporting limit to meet acceptance criteria. In condition two, if the result is greater than five times the reporting limit, the two results must agree to within 20 percent relative percent difference to meet acceptance criteria. All acceptance criteria were met. Data Validation Summary— Plantation Pipe Line Poplar Tent Road Site Soil Vapor JACOBS 5. PARCC Precision is defined as the agreement between duplicate results, and was estimated by comparing duplicate LCS recoveries, and field duplicate sample results. The precision between the native and field duplicate sample results for all analyses were within acceptable criteria indicating that the sample matrix did not interfere with the overall analytical process. Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter. In the case of VOC analysis, each of the samples were spiked with a surrogate compound with a known concentration before preparation. The surrogate data provides a measure of the matrix effects as they may affect accuracy and precision of the analytical method. The LCS results demonstrate accuracy of the method. Spike recoveries were within the method acceptance limits, showing no evidence of matrix interferences that affect the usability of the data. Representativeness criteria are a qualitative measure of the degree to which sample data accurately and precisely represent a characteristic environmental condition. Representativeness is a subjective parameter and is used to evaluate the efficacy of the sampling plan design. Representativeness was demonstrated by providing full descriptions in the project scoping documents of the sampling techniques and the rationale used for selecting sampling locations. Comparability is another qualitative measure designed to express the confidence with which one data set may be compared to another. Factors that affect comparability are sample collection and handling techniques, sample matrix type, and analytical method. Comparability is limited by the other PARCC parameters because data sets can be compared with confidence only when precision and accuracy are known. Data from this investigation are comparable with other previous data collected at the site due to the laboratories use of EPA or appropriate methods to analyze the samples and supported by the results of the laboratory's analytical reports. Completeness is defined as the percentage of measurements that are judged to be valid compared to the total number of measurements made. There were no data rejected and or seen as not usable due to quality control or sampling issues. 6. Conclusion A review of the laboratory's analytical data submitted regarding the investigation of PPL Poplar Tent Road soil vapor sampling event in October 2019 by Jacobs has been completed. The validation demonstrated that the analytical systems were in control at the time of sample analyses and all data results can be used in the decision -making process as qualified by the data validation process. urofins Environment Testing TestAmerica ANALYTICAL REPORT Eurofins TestAmerica, Knoxville 5815 Middlebrook Pike Knoxville, TN 37921 Tel: (865)291-3000 Laboratory Job ID: 140-17050-1 Client Project/Site: Poplar Tent Road CH2M Hill, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, North Carolina 28277 Attn: Mike Skeean Authorized for release by. 1013012019 5:12:29 PM Jamie McKinney, Senior Project Manager (865)291-3000 jamie.mckinney@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Table of Contents Laboratory Job ID: 140-17050-1 CoverPage .............................................. 1 Table of Contents ......................................... 2 Definitions/Glossary....................................... 3 Case Narrative ........................................... 4 Detection Summary ........................................ 5 Client Sample Results ...................................... 6 Default Detection Limits .................................... 9 Surrogate Summary ....................................... 10 QC Sample Results ........................................ 11 QC Association Summary ................................... 12 Lab Chronicle ............................................ 13 Certification Summary ...................................... 15 Method Summary ......................................... 16 Sample Summary ......................................... 17 Chain of Custody .......................................... 18 Receipt Checklists ......................................... 20 Eurofins TestAmerica, Knoxville Page 2 of 20 10/30/2019 Definitions/Glossary Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. a Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Eurofins TestAmerica, Knoxville Page 3 of 20 10/30/2019 Case Narrative Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Laboratory: Eurofins TestAmerica, Knoxville Narrative Job ID: 140-17050-1 0 Job Narrative 140-17050-1 Comments No additional comments. Receipt The samples were received on 10/18/2019 10:00 AM; the samples arrived in good condition, properly preserved and, where required, on ice. Air - GC/MS VOA Methods TO 15 LL, TO-14A, TO-15: EPA methods TO-14A and TO-15 specify the use of humidified "zero air" as the blank reagent for canister cleaning, instrument calibration and sample analysis. Ultra -high purity humidified nitrogen from a cryogenic reservoir is used in place of "zero air" by Eurofins TestAmerica Knoxville. No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page. Eurofins TestAmerica, Knoxville Page 4 of 20 10/30/2019 Detection Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 ENo Detections. Client Sample ID: SV-10R2-101719 INo Detections. Client Sample ID: SV-14R-101719 LNo Detections. Client Sample ID: SV-5R-101719 ENo Detections. Client Sample ID: SV-5RD-101719 1 No Detections. This Detection Summary does not include radiochemical test results. F Job ID: 140-17050-1 Lab Sample ID: 140-17050-1 Lab Sample ID: 140-17050-2 Lab Sample ID: 140-17050-3 Lab Sample ID: 140-17050-4 Lab Sample ID: 140-17050-5 Page 5 of 20 Eurofins TestAmerica, Knoxville 10/30/2019 Client Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: SV-12R-101719 Lab Sample ID: 140-17050-1 Date Collected: 10/17/19 11:44 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyzed Dil Fac 10/21/19 23:26 1 u 10/21/19 23:26 1 10/21/19 23:26 1 10/21/19 23:26 1 10/21/19 23:26 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/21/19 23:26 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/21/19 23:26 1 Toluene ND 4.5 2.9 ug/m3 10/21/19 23:26 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/21/19 23:26 1 o-Xylene ND 3.5 0.65 ug/m3 10/21/19 23:26 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 96 60 - 140 10121119 23:26 1 Client Sample ID: SV-10R2-101719 Lab Sample ID: 140-17050-2 Date Collected: 10/17/19 14:51 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene Surrogate 4-Bromofluorobenzene (Surr) Analyzed Dil Fac 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 10/22/19 00:13 1 Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac ND 2.6 0.26 ug/m3 10/22/19 00:13 1 ND 3.5 0.56 ug/m3 10/22/19 00:13 1 ND 4.5 2.9 ug/m3 10/22/19 00:13 1 ND 3.5 1.3 ug/m3 10/22/19 00:13 1 ND 3.5 0.65 ug/m3 10/22/19 00:13 1 %Recovery Qualifier Limits Prepared Analyzed Dil Fac 95 60 - 140 10122119 00:13 1 Client Sample ID: SV-14R-101719 Lab Sample ID: 140-17050-3 Date Collected: 10/17/19 15:10 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.80 0.080 ppb v/v 10/22/19 00:59 1 Ethylbenzene ND 0.80 0.13 ppb v/v 10/22/19 00:59 1 Toluene ND 1.2 0.78 ppb v/v 10/22/19 00:59 1 m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v 10/22/19 00:59 1 o-Xylene ND 0.80 0.15 ppb v/v 10/22/19 00:59 1 Eurofins TestAmerica, Knoxville Page 6 of 20 10/30/2019 Client Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: SV-14R-101719 Lab Sample ID: 140-17050-3 Date Collected: 10/17/19 15:10 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 00:59 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 00:59 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 00:59 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 00:59 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 00:59 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac C 4-Bromofluorobenzene (Surr) 94 60 - 140 10122119 00:59 1 Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17050-4 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Benzene ND 0.80 0.080 ppb v/v Ethylbenzene ND 0.80 0.13 ppb v/v Toluene ND 1.2 0.78 ppb v/v m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v o-Xylene ND 0.80 0.15 ppb v/v Analyzed Dil Fac 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 10/22/19 01:47 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 01:47 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 01:47 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 01:47 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 01:47 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 01:47 1 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 60 - 140 10122119 01:47 1 Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17050-5 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.80 0.080 ppb v/v 10/22/19 02:34 1 Ethylbenzene ND 0.80 0.13 ppb v/v 10/22/19 02:34 1 Toluene ND 1.2 0.78 ppb v/v 10/22/19 02:34 1 m-Xylene & p-Xylene ND 0.80 0.29 ppb v/v 10/22/19 02:34 1 o-Xylene ND 0.80 0.15 ppb v/v 10/22/19 02:34 1 Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 2.6 0.26 ug/m3 10/22/19 02:34 1 Ethylbenzene ND 3.5 0.56 ug/m3 10/22/19 02:34 1 Toluene ND 4.5 2.9 ug/m3 10/22/19 02:34 1 m-Xylene & p-Xylene ND 3.5 1.3 ug/m3 10/22/19 02:34 1 o-Xylene ND 3.5 0.65 ug/m3 10/22/19 02:34 1 Eurofins TestAmerica, Knoxville Page 7 of 20 10/30/2019 Client Sample Results Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17050-5 Date Collected: 10/17/19 15:59 Matrix: Air Date Received: 10/18/19 10:00 Sample Container: Summa Canister 1 L Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac 4-Bromofluorobenzene (Surr) 99 60 - 140 10122119 02:34 1 Eurofins TestAmerica, Knoxville Page 8 of 20 10/30/2019 Default Detection Limits Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Analyte RL MDL Units Benzene 0.080 0.0080 ppb v/v Benzene 0.26 0.026 ug/m3 Ethylbenzene 0.080 0.013 ppb v/v Ethylbenzene 0.35 0.056 ug/m3 m-Xylene & p-Xylene 0.080 0.029 ppb v/v m-Xylene & p-Xylene 0.35 0.13 ug/m3 o-Xylene 0.080 0.015 ppb v/v o-Xylene 0.35 0.065 ug/m3 Toluene 0.12 0.078 ppb v/v Toluene 0.45 0.29 ug/m3 Eurofins TestAmerica, Knoxville Page 9 of 20 10/30/2019 Surrogate Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Matrix: Air Prep TVDe: Total/NA BFB Lab Sample ID Client Sample ID (60-140) 140-17050-1 SV-12R-101719 96 140-17050-2 SV-10R2-101719 95 140-17050-3 SV-14R-101719 94 140-17050-4 SV-5R-101719 99 140-17050-5 SV-5RD-101719 99 LCS 140-34462/1002 Lab Control Sample 97 MB 140-34462/4 Method Blank 90 Surrogate Legend BFB = 4-Bromofluorobenzene (Surr) Percent Surrogate Recovery (Acceptance Limits) 0 Eurofins TestAmerica, Knoxville Page 10 of 20 10/30/2019 QC Sample Results Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17050-1 Method: TO 15 LL - Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) Lab Sample ID: MB 140-34462/4 Client Sample ID: Method Blank Matrix: Air Prep Type: Total/NA Analysis Batch: 34462 MB MB Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac Benzene ND 0.080 0.0080 ppb v/v 10/21/19 11:26 1 Ethylbenzene ND 0.080 0.013 ppb v/v 10/21/19 11:26 1 Toluene ND 0.12 0.078 ppb v/v 10/21/19 11:26 1 m-Xylene & p-Xylene ND 0.080 0.029 ppb v/v 10/21/19 11:26 1 o-Xylene ND 0.080 0.015 ppb v/v 10/21/19 11:26 1 Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene MB MB Result Qualifier ND ND ND ND ND MB MB Surrogate %Recovery Qualifier 4-Bromofluorobenzene (Surr) 90 Lab Sample ID: LCS 140-34462/1002 Matrix: Air Analysis Batch: 34462 Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene Analyte Benzene Ethylbenzene Toluene m-Xylene & p-Xylene o-Xylene RL MDL Unit D Prepared Analyzed Dil Fac 0.26 0.026 ug/m3 10/21/19 11:26 1 0.35 0.056 ug/m3 10/21/19 11:26 1 0.45 0.29 ug/m3 10/21/19 11:26 1 0.35 0.13 ug/m3 10/21/19 11:26 1 0.35 0.065 ug/m3 10/21/19 11:26 1 Limits Prepared Analyzed Dil Fac 60 - 140 10/21/19 11:26 1 Client Sample ID: Lab Control Sample Prep Type: Total/NA Spike Added 1.00 1.00 1.00 2.00 1.00 Spike Added 3.2 4.3 3.8 8.7 4.3 LCS LCS Surrogate %Recovery Qualifier Limits 4-Bromofluorobenzene (Surr) 97 60 - 140 LCS Result LCS Qualifier Unit D %Rec %Rec. Limits 0.831 ppb v/v 83 70 -130 0.865 ppb v/v 86 70 -130 0.895 ppb v/v 90 70 -130 1.71 ppb v/v 86 70 -130 0.887 ppb v/v 89 70 -130 LCS LCS %Rec. Result Qualifier Unit D %Rec Limits 2.65 ug/m3 83 70 -130 3.76 ug/m3 86 70 -130 3.37 ug/m3 90 70 -130 7.44 ug/m3 86 70 -130 3.85 ug/m3 89 70 -130 Page 11 of 20 Eurofins TestAmerica, Knoxville 10/30/2019 QC Association Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17050-1 Air - GUMS VOA Analysis Batch: 34462 Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch 140-17050-1 SV-12R-101719 Total/NA Air TO 15 LL 140-17050-2 SV-10R2-101719 Total/NA Air TO 15 LL 140-17050-3 SV-14R-101719 Total/NA Air TO 15 LL 140-17050-4 SV-5R-101719 Total/NA Air TO 15 LL 140-17050-5 SV-5RD-101719 Total/NA Air TO 15 LL MB 140-34462/4 Method Blank Total/NA Air TO 15 LL LCS 140-34462/1002 Lab Control Sample Total/NA Air TO 15 LL Eurofins TestAmerica, Knoxville Page 12 of 20 10/30/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 Date Collected: 10/17/19 11:44 Date Received: 10/18/19 10:00 Job ID: 140-17050-1 Lab Sample ID: 140-17050-1 Matrix: Air F Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 50 mL 500 mL 34462 10/21/19 23:26 S1K TAL KNX Instrument ID: MR Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 14:51 Date Received: 10/18/19 10:00 Batch Batch Prep Type Type Method Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 15:10 Date Received: 10/18/19 10:00 Batch Batch Prep Type Type Method Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-5R-101719 Date Collected: 10/17/19 15:59 Date Received: 10/18/19 10:00 Lab Sample ID: 140-17050-2 Matrix: Air Dil Initial Final Batch Prepared Run Factor Amount A- --mount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 00:13 S1 K TAL KNX Lab Sample ID: 140-17050-3 m Matrix: Air Dil Run Factor Initial Amount Final Amount Batch Number Prepared or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 00:59 S-1—K TAL KNX L Batch Batch Prep Type Type Method Run Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: SV-5RD-101719 Date Collected: 10/17/19 15:59 Date Received: 10/18/19 10:00 F Batch Batch Prep Type Type Method Run Total/NA Analysis TO 15 LL Instrument ID: MR Client Sample ID: Method Blank Date Collected: N/A Date Received: N/A Lab Sample ID: 140-17050-4 Matrix: Air FR- Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 01:47 S1 K TAL KNX Lab Sample ID: 140-17050-5 Matrix: Air Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 50 mL 500 mL 34462 10/22/19 02:34 S1 K TAL KNX Lab Sample ID: MB 140-34462/4 Matrix: Air Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 500 mL 500 mL 34462 10/21/19 11:26 S 1 K TAL KNX Instrument ID: MR Eurofins TestAmerica, Knoxville Page 13 of 20 10/30/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17050-1 Client Sample ID: Lab Control Sample Lab Sample ID: LCS 140-34462/1002 Date Collected: N/A Matrix: Air Date Received: N/A Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Analysis TO 15 LL 1 500 mL 500 mL 34462 10/21/19 09:50 S1K TAL KNX Instrument ID: MR Laboratory References: TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 Eurofins TestAmerica, Knoxville Page 14 of 20 10/30/2019 Accreditation/Certification Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Laboratory: Eurofins TestAmerica, Knoxville All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report. Authority Program Identification Number Expiration Date AFCEE N/A ANAB Dept. of Defense ELAP L2311 02-14-22 ANAB Dept. of Energy L2311.01 02-14-22 ANAB ISO/IEC 17025 L2311 02-13-22 Arkansas DEQ State 2423 06-16-20 California State 2423 06-30-20 Colorado State TN00009 02-29-20 Connecticut State PH-0223 09-30-21 Florida NELAP E87177 06-30-20 Georgia (DW) State 906 04-13-20 Hawaii State NA 04-13-20 Kansas NELAP E-10349 10-31-19 Kentucky (DW) State 90101 12-31-19 Louisiana NELAP 83979 06-30-20 Louisiana NELAP 83979 06-30-20 Louisiana (DW) State LA019 12-31-19 Maryland State 277 03-31-20 Michigan State 9933 04-13-20 Nevada State TN00009 07-31-20 New Hampshire NELAP 2999 01-17-20 New Hampshire NELAP 299919 01-17-20 New Jersey NELAP TN001 06-30-20 New York NELAP 10781 03-31-20 North Carolina (DW) State 21705 07-31-20 North Carolina (WW/SW) State 64 12-31-19 North Carolina (WW/SW) State Program 64 12-31-19 Ohio VAP State CL0059 08-28-20 Oklahoma State 9415 09-01-20 Oregon NELAP TN I O189 01-01-20 Pennsylvania NELAP 68-00576 12-31-19 Tennessee State 02014 04-13-20 Texas NELAP T104704380-18-12 08-31-20 US Fish & Wildlife US Federal Programs 058448 07-31-20 USDA US Federal Programs P330-19-00236 08-20-22 Utah NELAP TN00009 07-31-20 Virginia NELAP 460176 09-15-20 Washington State C593 01-19-20 West Virginia (DW) State 9955C 12-31-19 West Virginia DEP State 345 04-30-20 Wisconsin State 998044300 08-31-20 Job ID: 140-17050-1 Eurofins TestAmerica, Knoxville Page 15 of 20 10/30/2019 Method Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Method Method Description Protocol TO 15 LL Volatile Organic Compounds in Ambient Air, Low Concentration (GC/MS) EPA Protocol References: EPA = US Environmental Protection Agency Laboratory References: TAL KNX = Eurofins TestAmerica, Knoxville, 5815 Middlebrook Pike, Knoxville, TN 37921, TEL (865)291-3000 F Job ID: 140-17050-1 Laboratory TAL KNX L Eurofins TestAmerica, Knoxville Page 16 of 20 10/30/2019 Sample Summary Client: CH21VI Hill, Inc. Job ID: 140-17050-1 Project/Site: Poplar Tent Road Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 140-17050-1 SV-12R-101719 Air 10/17/19 11:44 10/18/19 10:00 Air Canister (I-Liter)#34002420 140-17050-2 SV-10R2-101719 Air 10/17/19 14:51 10/18/19 10:00 Air Canister (I-Liter)#11885 140-17050-3 SV-14R-101719 Air 10/17/19 15:10 10/18/19 10:00 Air Canister (I-Liter)#11540 140-17050-4 SV-5R-101719 Air 10/17/19 15:59 10/18/19 10:00 Air Canister (1-Liter) #11871 140-17050-5 SV-5RD-101719 Air 10/17/19 15:59 10/18/19 10:00 Air Canister (I-Liter)#11726 14 Eurofins TestAmerica, Knoxville Page 17 of 20 10/30/2019 I V 0 c Y N Y E•• O a N N in cc M c8, M co 63 0 N U W u O o X Lu uCO Y� a u_ E y £ N41N G OU Z Q U m z E a C9 (6 U uo. `� (uollues selou ul hpaeds sseeld) a0410 seo 114pOel _ OAS) uolloealx3 aodeA lloS C� i SUE) IIuSICY gelS-goS v NWIN AM JUslgwV/jlV aoopul I adi( a�tlale ` p� (uolloas selou ul Ajpeds eseeld) J0410 K/96 Vd3 v, 9t,W0 W1SV z- i •� 09Z Vd3 �_ •--y / 0E Vd3 (� WIS 9VO1 , G (lanai MO / paepuelS) 96/17 of > > � m �❑ ��-TNT �� V a D !n d O a� a ti c ° f CT \✓ 'v 'd ''a's E E 0 N w w U Ma f y E x a o E-" "1i1e3 A c c� s vN _LO �U1' E ` c N;= cva ya T- E o l(i `T �T N ( ° Fes- n �) wFvim+ � m O `o_ `o_ F- F F US waas N y o j E c c a •R w LL c s M l'/O A Fs :.j1 'C a 't awl 11 U V)SIR v s E V c S 0 l `n a otl zzIN ..J E a 0 T e 4b - E�+- c E CL EL c 'El]" a E o �%�� J 1 1 y S c ar d c J CL O. C O '�O L Q O` O_- iL G CEO t� c ¢U au aina ti to: ) Page 18 of 20 10/30/2019 -d rn N C4 '� A O d y d y •� ei is Z x a�aWdI'm r• o U UU d d U d cUA° a Ri ZZ U �' q oO a. o a o +•+ a y q o � a. c� a Cd ° o a O d o ed a lw 'L� i. •p 'O 14 H Z .d r: Z � rai z L. q `{ 4Oq^, q uUUU U*ci �UUU U iti d °oU as 00o � O5 g000.O ex �UU 000 urn v�U 0to000 U ❑�❑❑ r. ❑U❑�❑❑U❑❑❑❑❑❑v❑❑❑❑ ❑ ❑❑s❑❑❑ ❑❑ z e z r ai •� d b; .� aqi � � � •� C, ^_ � c• 'c� o, a' � chi �' n U u• U 9," w^ q w° O °0 U aQi O ai �.• �'�' t' cv cOd c� q o O +�v+ �„ a 'b � O is W O S1 N N ° U N o F. .cd y t�/� •�+ w �. N Q, p N W `" avi y ^ ? 0 00 ^- 3 p ° A O� `r. dO N N ° U N N ti Qvi CO �+ N CO N N N b bA O O. N CV .M .,q. �t U vi t\ 00 O\ .-� .-� �-r .-� r-+ V1 .-� �G H .--� C�. l� •--i 00 .--i Oi .--i N W M Page 19 of 20 10/30/2019 Gauge ID: Date: G5 10/19/2019 TestAmerica Knoxville - Air Canister Initial Pressure Check Analyst Sample ID Asset # Cleaning Job Cert Size (L) Pressure @ Receipt (-in Hg or +psig) Time Comments BKK 140-17050-A-1 34002420 16760 B 1 -4.5 11:35 BKK 140-17050-A-2 11885 16621 B 1 1 -1.3 11:36 BKK 140-17050-A-3 11540 16760 B 1 -4.8 11:37 BKK 140-17050-A-4 11871 16760 B 1 -6.0 11:38 BKK 140-17050-A-5 11726 16760 B 1 -5.5 11:39 ❑ Receiving —Air Can —Calve Open (NCM # ) ❑ Air - Can P -24 to -25 " - Flow Contr. Works (NCM# ) ❑ Air - Can P -24 to -25 " - Flow Contr. Faulty (NCM# ) ❑ Air - Can P Out -26" - Flow Contr. Works (NCM# ) ❑ Air - Can P Out -26" - Flow Comr. Faulty (NCM# ) ❑ Air - Can P Low -24 to -25 " - Grab Sample (NCM# ) ❑ Air - Can P Low -26 "- Grab Sample (NCM# ) 16 101113MIl.UM Page 20 of 20 MS038 r14, 6/19/15 10/30/2019 urofins � Environment Testing TestAmerica ANALYTICAL REPORT C Eurofins TestAmerica, Knoxville 5815 Middlebrook Pike Knoxville, TN 37921 Tel: (865)291-3000 Laboratory Job ID: 140-17112-1 Laboratory Sample Delivery Group: WO 1910445 Client Project/Site: Poplar Tent Road Foi CH2M Hill, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, North Carolina 28277 Attn: Mike Skeean 't_ 0- �4c? r Authorized for release by: 1012412019 2:51:19 PM Jamie McKinney, Senior Project Manager (865)291-3000 jamie.mckinney@testamericainc.com The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited parameters, exceptions are noted in this report. This report may not be reproduced except in full, and with written approval from the laboratory. For questions please contact the Project Manager at the e-mail address or telephone number listed on this page. This report has been electronically signed and authorized by the signatory. Electronic signature is intended to be the legally binding equivalent of a traditionally handwritten signature. Results relate only to the items tested and the sample(s) as received by the laboratory. Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Table of Contents Laboratory Job ID: 140-17112-1 F SDG: WO 1910445 U CoverPage .............................................. 1 Table of Contents ......................................... 2 Definitions/Glossary....................................... 3 Case Narrative ........................................... 4 Detection Summary ........................................ 5 Client Sample Results ...................................... 6 Surrogate Summary ....................................... 7 QC Sample Results ........................................ 8 QC Association Summary ................................... 9 Lab Chronicle ............................................ 10 Method Summary ......................................... 12 Sample Summary ......................................... 13 Chain of Custody .......................................... 14 Eurofins TestAmerica, Knoxville Page 2 of 14 10/24/2019 Definitions/Glossary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Qualifiers Subcontract Qualifier Qualifier Description U COMPOUND ANALYZED FOR BUT NOT DETECTED ABOVE THE DETECTION LIMIT Glossary Abbreviation These commonly used abbreviations may or may not be present in this report. Listed under the "D" column to designate that the result is reported on a dry weight basis %R Percent Recovery CFL Contains Free Liquid CNF Contains No Free Liquid DER Duplicate Error Ratio (normalized absolute difference) Dil Fac Dilution Factor DL Detection Limit (DoD/DOE) DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample DLC Decision Level Concentration (Radiochemistry) EDL Estimated Detection Limit (Dioxin) LOD Limit of Detection (DoD/DOE) LOQ Limit of Quantitation (DoD/DOE) MDA Minimum Detectable Activity (Radiochemistry) MDC Minimum Detectable Concentration (Radiochemistry) MDL Method Detection Limit ML Minimum Level (Dioxin) NC Not Calculated ND Not Detected at the reporting limit (or MDL or EDL if shown) PQL Practical Quantitation Limit QC Quality Control RER Relative Error Ratio (Radiochemistry) RL Reporting Limit or Requested Limit (Radiochemistry) RPD Relative Percent Difference, a measure of the relative difference between two points TEF Toxicity Equivalent Factor (Dioxin) TEQ Toxicity Equivalent Quotient (Dioxin) Job ID: 140-17112-1 SDG: WO 1910445 Eurofins TestAmerica, Knoxville Page 3 of 14 10/24/2019 Case Narrative Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17112-1 Laboratory: Eurofins TestAmerica, Knoxville Narrative Job ID: 140-17112-1 SDG: WO 1910445 0 Job Narrative 140-17112-1 Comments No additional comments. Receipt The samples were received on 10/18/2019 9:45 AM; the samples arrived in good condition, properly preserved and, where required, on ice. T017 A sampling volume of 0.250 L was used to convert ng to ug/m3 for the associated Lab BLank. No analytical or quality issues were noted, other than those described in the Definitions/Glossary page. Eurofins TestAmerica, Knoxville Page 4 of 14 10/24/2019 Detection Summary Client: CH2M Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 ENo Detections. Client Sample ID: SV-14R-101719 INo Detections. Client Sample ID: SV-10R2-101719 LNo Detections. Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID: 140-17112-1 Lab Sample ID: 140-17112-2 Lab Sample ID: 140-17112-3 Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17112-4 ENo Detections. Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17112-5 F ENo Detections. F This Detection Summary does not include radiochemical test results. Eurofins TestAmerica, Knoxville Page 5 of 14 10/24/2019 Client Sample Results Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Client Sample ID: SV-12R-101719 Date Collected: 10/17/19 11:59 Date Received: 10/18/19 09:45 Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID: 140-17112-1 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1912:45 10/18/1912:45 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1912:45 10/18/1912:45 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 91 50 - 150 10118119 12:45 10118119 12:45 1.00 Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 13:02 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-2 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1914:33 10/18/1914:33 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1914:33 10/18/1914:33 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 80 50 - 150 10118119 14:33 10118119 14:33 1.00 Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 15:24 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-3 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1913:51 10/18/1913:51 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1913:51 10/18/1913:51 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed DY Fac NAPHTHALENE-D8 84 50 - 150 10118119 13:51 10118119 13:51 1.00 Client Sample ID: SV-5R-101719 Date Collected: 10/17/19 16:09 Date Received: 10/18/19 09:45 Lab Sample ID: 140-17112-4 Matrix: Air Method: TO17 - General Subcontract Method Analyte Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac 2-METHYLNAPHTHALENE ND U 20 2.6 UG/M3 10/18/1915:15 10/18/1915:15 1.00 NAPHTHALENE ND U 20 1.7 UG/M3 10/18/1915:15 10/18/1915:15 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 78 50 - 150 10118119 15:15 10118119 15:15 1.00 Client Sample ID: SV-5RD-101719 Date Collected: 10/17/19 16:18 Date Received: 10/18/19 09:45 Method: TO17 - General Subcontract Method Analyte Result Qualifier 2-METHYLNAPHTHALENE ND U NAPHTHALENE ND U Surrogate NAPHTHALENE-D8 RL MDL Unit 20 2.6 UG/M3 20 1.7 UG/M3 %Recovery Qualifier Limits 87 50-150 Lab Sample ID: 140-17112-5 Matrix: Air D Prepared Analyzed Dil Fac 10/18/19 15:57 10/18/19 15:57 1.00 10/18/19 15:57 10/18/19 15:57 1.00 Prepared Analyzed Dil Fac 10118119 15:57 10118119 15:57 1.00 Eurofins TestAmerica, Knoxville Page 6 of 14 10/24/2019 Surrogate Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method: T017 - General Subcontract Method Matrix: Air ATHALEN Lab Sample ID Client Sample ID (50-150) Job ID: 140-17112-1 SDG: WO 1910445 Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) 140-17112-1 SV-12R-101719 91 140-17112-2 SV-14R-101719 80 140-17112-3 SV-10R2-101719 84 140-17112-4 SV-5R-101719 78 140-17112-5 SV-5RD-101719 87 Surrogate Legend C NAPHTHALENE-D8 = NAPHTHALENE-D8 Method: T017 - General Subcontract Method Matrix: AIR Prep Type: Total/NA Percent Surrogate Recovery (Acceptance Limits) ATHALEN Lab Sample ID Client Sample ID (50-150) 1910445-06A Method Blank 90 1910445-08A Lab Control Sample 90 1910445-08AA Lab Control Sample Dup 92 Surrogate Legend NAPHTHALENE-D8 = NAPHTHALENE-D8 Eurofins TestAmerica, Knoxville Page 7 of 14 10/24/2019 QC Sample Results Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method: T017 - General Subcontract Method Lab Sample ID: 1910445-06A Matrix: AIR Analysis Batch: 11101801 Blank Blank Analyte Result Qualifier RL MDL Unit 2-METHYLNAPHTHALENE ND U 20 UG/M3 NAPHTHALENE ND U 20 UG/M3 Blank Blank Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: Method Blank Prep Type: Total/NA Prep Batch: 11101801_P D Prepared Analyzed Dil Fac 10/18/19 11:29 10/18/19 11:29 1.00 10/18/19 11:29 10/18/19 11:29 1.00 Surrogate %Recovery Qualifier Limits Prepared Analyzed Dil Fac NAPHTHALENE-D8 90 50 - 150 10118119 11:29 10118119 11:29 1.06 Lab Sample ID: 1910445-08A Client Sample ID: Lab Control Sample C Matrix: AIR Prep Type: Total/NA Analysis Batch: 11101801 Prep Batch: 11101801_P Spike LCS LCS %Rec. Analyte Added Result Qualifier Unit D %Rec Limits 2-METHYLNAPHTHALENE 100 95 UG/M3 95 70-130 NAPHTHALENE 100 93 UG/M3 93 70-130 LCS LCS Surrogate %Recovery Qualifier NAPHTHALENE-D8 90 Lab Sample ID: 1910445-08AA Matrix: AIR Analysis Batch: 11101801 Analyte 2-METHYLNAPHTHALENE NAPHTHALENE LCS Dup LCS Dup Surrogate %Recovery Qualifier NAPHTHALENE-D8 92 Limits 50-150 Client Sample ID: Lab Control Sample Dup Prep Type: Total/NA Prep Batch: 11101801 P Spike LCS Dup LCS Dup %Rec. RPD Added Result Qualifier Unit D %Rec Limits RPD Limit 100 94 UG/M3 94 70-130 1.0 25 100 92 UG/M3 92 70-130 1.1 25 Limits 50-150 Eurofins TestAmerica, Knoxville Page 8 of 14 10/24/2019 QC Association Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Subcontract Analysis Batch: 11101801 Lab Sample ID Client Sample ID 140-17112-1 SV-12R-101719 140-17112-2 SV-14R-101719 140-17112-3 SV-10R2-101719 140-17112-4 SV-5R-101719 140-17112-5 SV-5RD-101719 1910445-06A Method Blank 1910445-08A Lab Control Sample 1910445-08AA Lab Control Sample Dup Prep Batch: 11101801_P Lab Sample ID Client Sample ID 140-17112-1 SV-12R-101719 140-17112-2 SV-14R-101719 140-17112-3 SV-10R2-101719 140-17112-4 SV-5R-101719 140-17112-5 SV-5RD-101719 1910445-06A Method Blank 1910445-08A Lab Control Sample 1910445-08AA Lab Control Sample Dup F Job ID: 140-17112-1 SDG: WO 1910445 Prep Type Matrix Method Prep Batch Total/NA Air T017 11101801—P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA Air T017 11101801 P Total/NA AIR T017 11101801 P Total/NA AIR T017 11101801_P Total/NA AIR T017 11101801_P Prep Type Matrix Method Prep Batch Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA Air NONE Total/NA AIR NONE Total/NA AIR NONE Total/NA AIR NONE Eurofins TestAmerica, Knoxville Page 9 of 14 10/24/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: SV-12R-101719 Lab Sample ID: 140-17112-1 Date Collected: 10/17/19 11:59 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Client Sample ID: SV-14R-101719 Date Collected: 10/17/19 13:02 Date Received: 10/18/19 09:45 Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Client Sample ID: SV-10R2-101719 Date Collected: 10/17/19 15:24 Date Received: 10/18/19 09:45 Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 11101801 10/18/1912:45 Eurofins _P 1.00 11101801 10/18/1912:45 SU Eurofins Ldu Jdfitple ILJ: I'FU- I / I IL-L Matrix: Air Dil Initial Final Batch Prepared F Factor Amount Amount Number or Analyzed Analyst Lab M 1 11101801 10/18/1914:33 Eurofins _P 1.00 11101801 10/18/1914:33 SU Eurofins Lab Sample ID: 140-17112-3 Matrix: Air C Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1913:51 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1913:51 SU Eurofins Instrument ID: Client Sample ID: SV-5R-101719 Lab Sample ID: 140-17112-4 Date Collected: 10/17/19 16:09 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1915:15 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1915:15 SU Eurofins Instrument ID: Client Sample ID: SV-5RD-101719 Lab Sample ID: 140-17112-5 Date Collected: 10/17/19 16:18 Matrix: Air Date Received: 10/18/19 09:45 Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1915:57 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1915:57 SU Eurofins Instrument ID: Page 10 of 14 Eurofins TestAmerica, Knoxville 10/24/2019 Lab Chronicle Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road F Job ID: 140-17112-1 SDG: WO 1910445 Client Sample ID: Method Blank Lab Sample ID: 1910445-06A Date Collected: N/A Matrix: AIR Date Received: N/A Batch Batch Prep Type Type Method Run Total/NA Prep NONE Total/NA Analysis T017 Instrument ID: Dil Initial Final Batch Prepared Factor Amount Amount Number or Analyzed Analyst Lab 1 11101801 10/18/1911:29 Eurofins _P 1.00 11101801 10/18/1911:29 SU Eurofins Client Sample ID: Lab Control Sample Date Collected: N/A Date Received: N/A Batch Batch Dil Initial Prep Type Type Method Run Factor Amount Total/NA Prep NONE 1 Total/NA Analysis T017 1.00 Instrument ID: Client Sample ID: Lab Control Sample Dup Date Collected: N/A Date Received: N/A L-dri adrnpiu iu: iy iuwfa-uom Matrix: AIR Final Batch Prepared F Amount Number or Analyzed Analyst Lab M 11101801 10/18/19 09:23 Eurofins _P 11101801 10/18/19 09:23 SU Eurofins Lab Sample ID: 1910445-08AA Matrix: AIR C Batch Batch Dil Initial Final Batch Prepared Prep Type Type Method Run Factor Amount Amount Number or Analyzed Analyst Lab Total/NA Prep NONE 1 11101801 10/18/1910:05 Eurofins _P Total/NA Analysis T017 1.00 11101801 10/18/1910:05 SU Eurofins Instrument ID: Laboratory References: Eurofins = Eurofins Air Toxics, 180 Blue Ravine Road, Suite B, Folsom, CA 95630 Page 11 of 14 Eurofins TestAmerica, Knoxville 10/24/2019 Method Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Method Method Description Protocol Subcontract T017 - naphthalene and 2-methylnaphthalene None Protocol References: None = None Laboratory References: Eurofins = Eurofins Air Toxics, 180 Blue Ravine Road, Suite B, Folsom, CA 95630 F Job ID: 140-17112-1 SDG: WO 1910445 Laboratory Eurofins L Eurofins TestAmerica, Knoxville Page 12 of 14 10/24/2019 Sample Summary Client: CH21VI Hill, Inc. Project/Site: Poplar Tent Road Job ID: 140-17112-1 SDG: WO 1910445 Lab Sample ID Client Sample ID Matrix Collected Received Asset ID 140-17112-1 SV-12R-101719 Air 10/17/19 11:59 10/18/19 09:45 140-17112-2 SV-14R-101719 Air 10/17/19 13:02 10/18/19 09:45 140-17112-3 SV-10R2-101719 Air 10/17/19 15:24 10/18/19 09:45 140-17112-4 SV-5R-101719 Air 10/17/19 16:09 10/18/19 09:45 140-17112-5 SV-5RD-101719 Air 10/17/19 16:18 10/18/19 09:45 Eurofins TestAmerica, Knoxville Page 13 of 14 10/24/2019 CD M CD cr cr 0- < C 1 i (D a ^�gsN fY 1 F : CD m --41 CD -� p � (D€(D(D 7J ( 17 Q Q Q N � p*1 � b] Q �n _0 c m c� m CD m m (D 3 m 3 (D 3'CD the (:t CD Ed°i F� CD Vi CL d, : _ s D 0 0 0 0 O `0 p 0 a m ncp O [D N o > S ((DD 6 N D T In — C I 0 r m CL cmamv a +t 0 ♦ I O m z o X 3 f7C]NOgS7il: ro m-o T- e„ =r 0- - -i cu CD � W n �� 3 c 0 N o u mao�m �c m m2L0 W -6 8 0 - m m n Z � § cc p y ro 0 ID ' J_j B� p Q O p 0m�'o a tD' IDm Z o 4*: OmW'< a. "—" 3 3 O m Q2.4Q ep oR m� m CD M,!± 5 0,cn -� `A00 W ID m —fQ .. .... O CL \ c 7p � sm :3n CD CL m c° a n m c C - � © m ©gin s s Q❑❑ �'�'' o p C -� Z -- N' (o.o' I" n m (D O — a ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ ❑ I Indoor Air ca c a CO cn C i =1 ❑ ❑ ❑ ❑ L ❑ ❑ G ❑ I ❑ I outdoor Air F C- Soil Vapor - t ©o®o©ram®a®a Page 4 of O m o 03