9209_Wake_North_Unlined_MSWLF_GW_FID1386737_20191223

North Wake Unlined Landfill
Facility Permit No. 9209-MSWLF-1984
Semi -Annual Groundwater
Sampling Report
(November 2019 Sampling Event)
Wake County
Prepared December 2019
WAKE
COUNTY
NORTH CAROLI NA

I pENR USE ONLY: I I (JPaper Report ❑Electronic Data -Email CD (data loaded: Yes / No) Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management -Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
• Please type or print legibly.
• Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
• Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
• Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
• Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
entity submitting data (laboratory, consultant,
Consultant - CDM Smith Inc.
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Mathew F. Colone Phone: [phone]
E-mail: colonemfCa�cdmsmith.com
Facility name:
Wake County -North Wake
Closed Unlined Landfill
Facility Address:
9004 Deponie Drive
Raleigh, North Carolina 27615
Facility Permit #
9209-MSWLF-
1984
NC Landfill Rule:
(.0500 or .1600)
1600
Actual sampling dates (e.g.,
October 20-24, 2006)
November 4 - 7, 2019
Environmental Status: (Check all that apply)
Initial/Background Monitoring ❑X Detection Monitoring ❑X Assessment Monitoring ❑X Corrective Action
T e of data submitted: (Check all that apply)
X Groundwater monitoring data from monitoring wells � Methane gas monitoring data
Groundwater monitoring data from private water supply wells � Corrective action data (specify) MNA Sampling Results
Leachate monitoring data
X Surface water monitoring data � Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, 1 have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Mathew F. Colone
19)325-3500
(Print) Title (Area Code) Telephone N
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Signature Date
5400 Glenwood Avenue, Suite 400, Raleigh, North Carolina 27612
Facility Representative Address
F-0412
NC PE Firm License Number (if applicable effective May 1, 2009)
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Smith
5400 Glenwood Avenue, Suite 400
Raleigh, North Carolina 27612
tel: [phone]
fax: [phone]
December 23, 2019
Ms. Jaclynne Drummond
North Carolina Department of Environmental Quality
Division of Waste Management
Solid Waste Section
2090 U.S. 70 Highway
Swannanoa, North Carolina 28778
Subject: November 2019 Semi -Annual Groundwater Sampling Report
North Wake Closed Unlined Landfill
Facility Permit No. 9209-MSWLF-1984
Dear Ms. Drummond:
CDM Smith Inc., on behalf of Wake County (County), is submitting an electronic copy of the November
2019 semi-annual sampling event report. This letter report presents the results of the semi-annual
sampling event that was recently completed at the North Wake Closed Unlined Landfill (Site) and
constitutes the second semi-annual sampling event for 2019. The groundwater monitoring network
consists of the following wells: MW-11 (shallow background well), -11d (deep background well), -5R,
-6, -6d, -7, -8, -8d, -9, -10, -10d, -22, -23, -23d, -24, -28, -28d, -29d, -30, -31, -31d, -32, -33, -34, -34d,
-35, -36, -36d, TB-1a, TB-1a deep and surface water sampling locations: SW-2, -3, -7, and -8.
Monitoring wells MW-28, -28d, -33, and -35 are sampled annually during the spring event. Field
activities, sampling results for all wells and surface water locations, an evaluation of the groundwater
corrective action effectiveness, and recommendations are discussed below.
Field Activities
Groundwater and surface water samples from the Site were collected on November 4-7, 2019.
Monitoring well and surface water sample locations are shown on Figure 1. Construction details for
each monitoring well are summarized in Table 1.
Samples were collected from the monitoring wells by use of a peristaltic pump or disposable,
laboratory decontaminated bailers. Groundwater elevations were measured at each well prior to
sampling using an electronic water level indicator with an accuracy of 0.01 feet and are presented in
Table 1. These groundwater elevations were used to construct potentiometric contours for this
sampling event and are shown on Figure 1. The groundwater elevations and potentiometric contours
were also used to estimate groundwater velocities at each well as presented in Table 2.
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December 23, 2019
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After depth to groundwater was measured, three well volumes of water were removed from each
well prior to sampling to provide fresh formation water within the well water column. Each well
volume and surface water sample were measured for pH, conductivity, temperature, turbidity,
dissolved oxygen (DO), and oxidation-reduction potential (ORP) using a YSI-556 multi -parameter
water quality meter and a HANNA HI 98703 turbidity meter. Wells that had elevated turbidity were
allowed to stabilize prior to sample collection. The water quality measurements at the time of sample
collection are provided in Table 3.
Sampling Results
All groundwater and surface water samples were analyzed by Shealy Environmental Services, Inc.
located in West Columbia, South Carolina, for North Carolina Appendix I volatile organic compounds
(VOCs) plus dichlorodifluoromethane and Appendix I metals plus mercury. Monitoring wells MW-22,
-24, -30, -31, and TB-1a were not sampled during the November 2019 sampling event due to the low
volume of groundwater in the wells.
Samples from monitoring wells MW-5R, -6, -8, -9, -10, -11, -34, -34d, and -36 were analyzed for
natural attenuation parameters per the Corrective Action Plan (CAP) and CAP Addendum that were
approved by the North Carolina Department of Environmental Quality (NCDEQ) - Solid Waste Section
(SWS) in March 2010 and on June 10, 2019, respectively. The CAP and CAP Addendum are discussed
below.
In a letter dated May 29, 2018, the SWS stated that all groundwater and surface water samples
collected from landfills be analyzed for 1,4-dioxane after July 1, 2018. On June 26, 2019, the SWS
approved the removal of 1,4-dioxane from the sampling program for all monitoring wells and surface
water locations, with the exceptions of MW-6, -8, and -9, due to two non -detect events (October 2018
and April 2019). Samples were collected from MW-6, -8, and -9 during the November 2019 sampling
event and analyzed for 1,4-dioxane. Sample results are provided below.
The analytical results were reported to the laboratory specific method detection limit (MDL) and are
quantifiable at or below the laboratory limit of quantitation (LOQ). All monitoring wells for the Site
had detections of analytes above the MDL but below the LOQs that were qualified as estimated or "J"
flags. In samples collected from MW-7, -10d, -11d, -23d, -29d, and -31d, zinc detections had "B" flags,
indicating that the analyte was detected in the method blank. In samples collected from MW-6, -7, -8,
-10d, -23, -23d, -29d, -34d, TB-1a deep, SW-3, -7, and -8, mercury detections also had "B" flags.
Additionally, MW-36 had a "B" flag detection of thallium and MW-5R, -6, -8, -9, -10, -34, -34d, and -36
had "B" flag detections of methane.
Samples collected from MW-6 had nitrate detections that were qualified with "H" and "D" flags,
indicating that the sample was analyzed out of hold time and at dilution, respectively. Samples
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collected from MW-10 also had a "D" flag detection of methane. Samples collected from these wells
had matrix interference which resulted in reanalysis at dilution. Samples collected from MW-6 were
analyzed out of the hold time for nitrate when they were reanalyzed.
The following list summarizes which analytes were detected above the LOQ at each sample location.
Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) Groundwater Quality Standard,
Interim Maximum Allowable Concentration (IMAC), or the 15A NCAC 02B (NC 2B) or North Carolina In -
Stream Target Value Surface Water Quality Standard for Class C Waters. No "J" flag detections are
listed. A complete summary of all detected and estimated concentrations from the March 2011
through the November 2019 sampling events is presented in Table 4. Laboratory data reports are
provided in Appendix A.
MW-11 (Shallow Background)
Metals: Barium, Mercury, Vanadium, Zinc
Volatile Organic Compounds: None Detected
MW-11d (Deep Background)
Metals: Barium, Zinc
Volatile Organic Compounds: None Detected
MW-5R
Metals: Barium, Nickel, Zinc
Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane
MW-6
Metals: Barium, Cobalt, Nickel
Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane, 1,4-Dioxane
MW-6d
Metals: Barium, Cadmium, Zinc
Volatile Organic Compounds: Dichlorodifluoromethane, 1,1-Dichloroethane
MW-7
Metals: Barium, Cadmium, Chromium, Cobalt, Copper, Lead, Nickel,
Vanadium, Zinc
Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene
MW-8
Metals: Barium, Chromium, Mercury, Nickel, Vanadium, Zinc
Volatile Organic Compounds: 1,4-Dichlorobenzene, cis-1,2-Dichloroethene, 1,4-Dioxane
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MW-8d
Metals: Barium, Zinc
Volatile Organic Compounds: None Detected
MW-9
Metals: Barium, Cadmium, Copper, Lead, Mercury, Vanadium, Zinc
Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane,
cis-1,2-Dichloroethene, Vinyl Chloride
MW-10
Metals: Barium, Zinc
Volatile Organic Compounds: Benzene, 1,4-Dichlorobenzene, 1,1-Dichloroethane, cis-1,2-
Dichloroethene, Trichloroethene
MW-10d
Metals: None Detected
Volatile Organic Compounds: 1,1-Dichloroethane
MW-22
Metals: Dry
Volatile Organic Compounds: Dry
MW-23
Metals: Barium, Chromium, Copper, Lead, Vanadium, Zinc
Volatile Organic Compounds: None Detected
MW-23d
Metals: Barium, Cadmium, Zinc
Volatile Organic Compounds: None Detected
M W-24
Metals: Dry
Volatile Organic Compounds: Dry
MW-28
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-28d
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
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MW-29d
Metals: Barium, Zinc
Volatile Organic Compounds: None Detected
MW-30
Metals: Dry
Volatile Organic Compounds: Dry
MW-31
Metals: Dry
Volatile Organic Compounds: Dry
MW-31d
Metals: Barium, Vanadium, Zinc
Volatile Organic Compounds: Chloroform
MW-32
Metals: Barium, Mercury
Volatile Organic Compounds: Chloroform
TB-1 a
Metals: Dry
Volatile Organic Compounds: Dry
TB-1a deep
Metals: Barium, Cadmium, Copper, Zinc
Volatile Organic Compounds: Chloroform
MW-33
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-34
Metals: Barium, Beryllium, Cadmium, Chromium, Copper, Lead, Mercury,
Nickel, Vanadium, Zinc
Volatile Organic Compounds: Chloroform, 1,4-Dichlorobenzene, Dichlorodifluoromethane,
1,1-Dichloroethane, cis-1,2-Dichloroethene, Methylene Chloride,
Tetra chloroethene, Trichloroethene, Trichlorofluoromethane
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MW-34d
Metals: Barium, Cadmium, Chromium, Mercury, Zinc
Volatile Organic Compounds: Dichlorodifluoromethane, 1,1-Dichloroethane,
cis-1,2-Dichloroethene, Methylene Chloride, Trichloroethene
MW-35
Metals: Not Sampled
Volatile Organic Compounds: Not Sampled
MW-36
Metals: Barium, Beryllium, Chromium, Copper, Lead, Mercury, Nickel,
Vanadium, Zinc
Volatile Organic Compounds: 1,1-Dichloroethane, cis-1,2-Dichloroethene
MW-36d
Metals: Beryllium
Volatile Organic Compounds: 1,4-Dichlorobenzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene
SW-2
Metals: Barium
Volatile Organic Compounds: None Detected
SW-3
Metals: Barium
Volatile Organic Compounds: None Detected
SW-7
Metals: Barium
Volatile Organic Compounds: None Detected
SW-8
Metals: Barium
Volatile Organic Compounds: None Detected
"J" flags were not included in the previous list, but several locations had "J" flag detections that
exceeded the standards. The "J" flag constituents above the standards along with their locations are
listed below.
Antimony: MW-23d and TB-1a deep
Cobalt: MW-8, -10, -23, -32, -34, and -36
Mercury: SW-3, -7, and -8
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Thallium: MW-6, -9, -23, and -34
Vanadium: MW-6d, -8d, -23d, -36d, and TB-1a deep
It is likely that the recent and historic detections of chloroform in wells MW-6d, -24, -31, -31d, -32,
TB-1a and -1a deep are attributed to a release from a municipal water line in the Falls River
development and are not related to a release from the Site.
In a letter dated March 22, 2012, the SWS approved the County's request to discontinue collecting
samples from select wells for herbicide and pesticide analyses during the semi-annual spring sampling
event. However, the SWS requested that MW-29d continue to be sampled for bis(2-ethylhexyl)
phthalate during spring sampling events due to a detection from the March 2011 event.
Bis(2-ethylhexyl) phthalate was detected above the NC 2L Standard (3 parts per billion (ppb)) at 28.5
ppb in samples collected from MW-29d during the April 2014 sampling event. A confirmatory sample
collected from MW-29d during the November 2014 sampling event had an estimated detection of
bis(2-ethylhexyl) phthalate at 4.61 ppb, which is above the NC 2L Standard. Bis(2-ethylhexyl)
phthalate has not been detected above the laboratory MDL in samples collected from MW-29d since
the November 2014 sampling event, except for J flag detections below the NC 2L Standard in samples
collected during the April and October 2018 events. The concentration trend for bis(2-ethylhexyl)
phthalate in MW-29d will continue to be evaluated.
Equipment and trip blanks were analyzed for quality control. A duplicate sample was also collected for
quality control. There were no detections in the equipment blank above the MDL. Two trip blanks
were analyzed for VOCs and had no detections above the MDL. The duplicate sample, identified as
DUP, was collected from MW-11d and had similar analyte concentrations as those detected in
MW-11d. Table 5 presents a summary of all analytes detected during the November 2019 sampling
event that exceeded the NC 2L or IMAC Standards.
As part of an ongoing Alternate Source Demonstration for the Site, filtered samples were collected
from monitoring wells MW-6, -8, -9, -10, -10d, -11, -23, -32, -34, -36, and -36d during the November
2019 sampling event due to elevated turbidity (i.e. greater than 10 Nephelometric Turbidity Units).
These samples were collected to demonstrate that select metals exceeding the NC 2L or IMAC
Standards are naturally occurring and not related to a release from the Site. Total metals that
exceeded the NC 2L or IMAC Standards from these wells were analyzed for dissolved metals to
determine if turbidity was a contributing factor to total reported metals.
Based on qualitative and quantitative evaluation of current and historic groundwater sampling data,
the NC 2L or IMAC Standard metal exceedances from the November 2019 sampling event were
determined to be indicative of naturally occurring background concentrations as opposed to a release
from the landfill. Below is a summary of the dissolved metals exceedances. Wells with a "*' qualifier
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had a "J" flag detection for that analyte. Dissolved metal sample results are provided in Table 4 and
the laboratory data report is provided in Appendix A.
Cobalt: MW-6, -8*, and -10*
Thallium: MW-6*, -9*, and -23*
Vanadium: MW-8,*-9, and -36*
Corrective Action via Air Sparging
The SWS expressed concern in May 2008 that VOCs may be migrating beyond the Site property
boundary and into Abbott's Creek based on detections above the NC 2L Standard in monitoring well
MW-9. As a result, the SWS directed the County to install and sample groundwater monitoring wells,
one shallow and one deep (i.e. MW-36 and -36d), downgradient of MW-9 to determine if VOCs may
be migrating beyond the Site property boundary, possibly discharging into Abbott's Creek. Initial
groundwater samples collected from MW-36 and -36d in December 2008 had detections of VOCs
above NC 2L Standards.
Surface water sample locations SW-7 and -8, located on Abbott's Creek, were added to the semi-
annual monitoring program in November 2008. Samples collected from SW-7 and -8 since being
added to the monitoring program have never had VOCs detected above the NC 2B Surface Water
Quality Standards.
An Assessment of Corrective Measures Report was submitted to the SWS in accordance with the
North Carolina Solid Waste Management Rule 15 NCAC 13B .1635 and approved in December 2009.
The SWS approved the selected remedy of monitored natural attenuation paired with in situ
remediation by air sparging to address groundwater contamination at the facility. A pilot test was
conducted in July and August 2010 near MW-6 and -6d to evaluate the effectiveness of the air
sparging remedy and to collect data for the full-scale system design in accordance with the CAP. The
pilot test successfully reduced the concentrations of 1,1-dichloroethane and vinyl chloride to below
their respective NC 2L Standard in MW-6d and vinyl chloride was not detected in samples collected
from MW-6 during the October 2010 semi-annual sampling event.
The full-scale system was installed in October 2011 and was operational in August 2012. The air
sparging system consists of 15 shallow wells screened across saturated saprolite and partially
weathered rock and 14 wells screened in the shallow fractured bedrock. In addition to the air sparging
wells, the system also consists of an air compressor and control panel that are housed in a secured
on -site control building. Routine inspections are performed on the system and a Field Inspection Log
completed during each inspection is kept on file at the facility.
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The County installed a vacuum extraction system around the perimeter of the Site in January 2002 to
prevent offsite migration of soil gas. The air sparging system was designed to work in tandem with the
existing perimeter migration control system (PMCS) by recovering air and gas vapors produced by the
air sparging system. Since previous work has indicated a relationship between the soil gas and the
contaminated groundwater, the installation of the PMCS is likely to further reduce groundwater
contaminant concentrations. As discussed in the approved CAP, the vacuum extraction system will be
used in conjunction with the air sparging system to reduce VOCs in the bedrock and partially
weathered rock between MW-9 and the MW-6 nested pair.
As part of the corrective action effectiveness evaluation, contaminant concentration trends for
monitoring wells MW-6, -6d, -9, -36, and -36d were evaluated. Total VOC concentration trends for
each well are presented on Figures 2 through 6. Trend results for each well are discussed below.
Figure 2 presents a total VOC concentration trend analysis for samples collected from MW-6. VOCs in
MW-6 significantly decreased after January 2002 when the PMCS was operational and were not
detected from November 2004 to April 2007. The total VOC concentration in MW-6 increased in May
2008 to 24 ppb compared to the November 2007 concentration of 14 ppb. The total VOC
concentration in MW-6 has shown a decreasing trend since the May 2008 sampling event with the
exception of an increase in total VOCs in samples collected during the October 2018 and November
2019 sampling events that is related to the introduction of the 1,4-dioxane analysis. The
concentration of 1,4-dioxane in samples collected from MW-6 during the October 2018 and
November 2019 sampling events was 26 ppb and 24 ppb, respectively.
Vinyl chloride has not been detected above the laboratory MDL in MW-6 since the April 2013
sampling event. Benzene detections in MW-6, which historically have exceeded the NC 2L Standard,
have been below the laboratory MDL since April 2013 with the exception of the November 2014
sampling when it was detected slightly above the standard at 1.1 ppb and October 2018 when it was
detected above the MDL at 0.61 ppb.
The trend analysis for total VOC concentrations in MW-6d is presented on Figure 3. VOCs were not
detected at MW-6d from December 2001 through November 2007. The increase in total VOCs from
samples collected during the May 2008 sampling event is a result of reporting "J" flag detections as
required by the SWS. VOC concentrations in MW-6d have been below the NC 2L Standards since the
March 2011 sampling event.
Figure 4 presents a total VOC concentration trend analysis for samples collected from MW-9.
Historically, MW-9 has had the highest concentration of VOCs compared to the other monitoring
wells. VOCs were not detected above the NC 2L Standards in MW-9 from October 2012 through April
2015. There was a "J" flag detection above the NC 2L Standard of 1,2-dichloroethane in samples
collected from MW-9 during the October 2015 sampling event and a detection of vinyl chloride (1.0
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ppb) above the NC 2L Standard in samples collected during the April 2016 sampling event. Benzene
and vinyl chloride were detected above their respective NC 2L Standard in samples collected during
the April 2019 sampling event. Vinyl chloride was also detected above its standard in samples
collected during the November 2019 sampling event. Total VOC concentrations in MW-9 show a
decreasing trend.
Trend analyses for total VOC concentrations in MW-36 and -36d are presented on Figures 5 and 6,
respectively. VOC concentrations in MW-36 have been below the NC 2L Standards since the April 2012
sampling event and have shown a decreasing trend since the air sparging system has been
operational. No VOCs have been detected above the NC 2L Standards in MW-36d since the October
2015 sampling event. Total VOC concentrations in both monitoring wells will continue to be
monitored and are expected to decrease while the air sparging system is operational.
Additional groundwater samples were collected from MW-5R, -6, -8, -9, -10, -11, and -36 for
evaluation of monitored natural attenuation parameters (i.e. biochemical oxygen demand, chemical
oxygen demand, alkalinity, nitrate, chloride, sulfate, sulfide, total organic carbon, carbon dioxide,
methane, ethane, ethene, ferrous iron, volatile fatty acids, dissolved hydrogen, and field
measurements of pH, temperature, conductivity, ORP and DO) as part of the corrective action
program as required by SWS guidelines. Geochemical results are presented in Table 6. The laboratory
data for the additional parameters is included in Appendix A.
As discussed in the approved CAP, concentrations of some of the natural attenuation data from select
wells indicates that environments are present which favor reductive dechlorination; notably, the
concentrations of nitrate, ferrous iron, sulfate, and carbon dioxide. The following evidence indicates
that one or more mechanisms of natural attenuation and/or reductive dechlorination may be
occurring at the site:
• VOC concentrations in contaminated wells continue to decline;
• The ratio of parent to daughter compounds continues to decrease over time;
• Nitrate, ferrous iron, sulfate, and carbon dioxide continue to be detected at concentrations
favoring reductive dechlorination; and
• Concentrations of cis-1,2-dichloroethene continue to be greater than dichloroethene isomers
trans 1,2-dichloroethene and 1,1-dichloroethene.
Corrective Action via In Situ Bioremediation Injection
VOCs that exceed the NC 2L Standards, including benzene, 1,4-dichlorobenzene, 1,1-dichloroethane,
methylene chloride, tetrachloroethene, trichloroethene, and vinyl chloride, have been detected in the
area of MW-5R, -34, and -34d. MW-5R is located near the Site property line and the MW-34 cluster is
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located west of MW-5R on the adjacent parcel, more than 900 feet from the air sparging system. The
VOC exceedances are likely from the migration of leachate from the Site into the surficial aquifer.
In accordance with the CAP Addendum that was approved by the SWS on July 10, 2019, and an
injection permit obtained from the Division of Water Quality — Underground Injection Control
Program on July 24, 2019, an in situ enhanced anaerobic bioremediation (EAB) injection was
completed by adding sodium lactate and emulsified vegetable oil (EVO) substrates through a
biobarrier injection system in order to reduce total VOC concentrations at the property line. Sodium
lactate and EVO enhance biologically reducing conditions that favor and support dechlorination of
VOCs to non -toxic end products.
On August 26-28, 2019, eight injection wells (i.e. NWIW-1 through -5) were installed upgradient of
MW-5R, -35, and -34d, as shown on Figure 1. An initial injection of sodium lactate was completed on
October 8-16, 2019. A total of 54,181 gallons of a 2.4 percent sodium lactate solution were injected.
Post -sodium lactate injection samples were collected 1 month after the injection during the
November 2019 semi-annual sampling event. Samples collected from monitoring wells MW-5R, -34,
and -34d were analyzed for natural attenuation parameters and sodium. VOCs were also collected
from injection well NWIW-5. Analytical results are summarized in Tables 4 and 6. Analytical results for
NWIW-5 are provided in the laboratory data report in Appendix A.
In order to assess the biological conditions in the injection area prior to initiating the EVO injection,
groundwater samples were collected from MW-5R and NWIW-5 and analyzed for Dehalococcoides
spp. (DHC), Dehalobacter spp., Dehalogenimonas spp., Desulfitobacterium spp., and Desulfuromonas
spp., which are the bacteria responsible for degrading the chlorinated ethene species of VOCs. The
specific genes of the bacteria that promote dechlorination were also analyzed. DHC was detected at
low concentrations in samples collected from NWIW-5, but sufficient populations of other bacteria
exist for reductive dichlorination by EAB. The laboratory data report for the bacteria analyses is
provided in Appendix B.
The EVO injection was completed on November 18-30 and December 1-6, 2019, with a 3.3 percent
solution of 98 percent LactOil® EVO formulation. A total of 80,751 gallons of the solution was injected.
The effectiveness of the EAB injection will be evaluated with quarterly sampling of MW-5R, -34, and
-34d. The first quarterly sampling event is tentatively scheduled for February 2020. The second and
third quarterly sampling event will be completed in conjunction of the semi-annual sampling events.
Following the completion of the fourth quarterly sampling, CDM Smith will prepare an injection report
for the SWS and the County.
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December 23, 2019
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Recommendations
The County will continue with the semi-annual assessment monitoring program. In addition to
sampling for Appendix I metals plus mercury, Appendix I VOCs plus dichlorodifluoromethane, and the
Appendix 11 constituent, bis(2-ethylhexyl) phthalate (sampled at MW-29d only during the spring
sampling event), samples collected from MW-5R, -6, -8, -9, -10, -11, -34, -34d, and -36 will continue to
be analyzed for natural attenuation parameters during the semi-annual events. MW-6, -8, and -9 will
continue to be analyzed for 1,4-dioxane.
The air sparging system will continue to operate and the effectiveness of the system will be re-
evaluated after the next semi-annual sampling event in the spring of 2020. Following the fourth
quarterly post-EAB injection sampling event, sampling of wells MW-5R, -34, and -34d will return to
semi-annually.
If you have any questions or require further explanation, do not hesitate to call me at [phone].
Sincerely,
%&4 Ivit-C
Mathew F. Colone, P.G.
CDM Smith Inc.
cc: John Roberson, WCSWM
Elliott Cornell, WCSWM
0

Table 1
Monitoring Well Construction Summary and Groundwater Elevations
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Depth Depths
.. Depth
Facility Permit Monitoring Completion Screened Total Number Well Code I I I I IntE Interval Interval Ele% Groundwater Elevation
TOC) Casing
9209-MSWLF-1984 MW-5R 1/30/2004 35.91192 78.57159 Regolith 27.5 10.0-25.0 8.0-25.0 6.0-8.0 2 225.28 17.50 207.78
9209-MSWLF-1984
MW-6
March-94
35.91423
78.57122
Regolith
22.0
10.0-20.0
8.0-20.0
6.0-8.0
2
219.80
12.88
206.92
9209-MSWLF-1984
MW-6d
5/1/2001
35.91423
78.57122
Bedrock
65.0
0-45.0
52.0-62.0
50.0-62.0
48.0-50.0
2
218.61
13.09
205.52
9209-MSWLF-1984
MW-7
March-94
35.91098
78.57436
Regolith
21.5
9.0-19.0
7.0-19.0
5.0-7.0
2
234.15
12.50
221.65
9209-MSWLF-1984
MW-8
March-94
35.91078
78.57266
Regolith
21.5
--
9.0-19.0
7.0-19.0
5.0-7.0
2
226.38
11.71
214.67
9209-MSWLF-1984
MW-8d
5/3/2001
35.91078
78.57266
Bedrock
45.0
0-30.0
37.0-42.0
35.0-42.0
29.0-35.0
2
226.16
12.87
213.29
9209-MSWLF-1984
MW-9
March-94
35.91484
78.57273
Regolith
44.0
--
32.0-42.0
30.0-42.0
28.0-30.0
2
242.69
30.66
212.03
9209-MSWLF-1984
MW-10
4/1/1998
35.91499
78.57494
Bedrock
55.5
43.0-53.0
41.0-53.0
39.0-41.0
2
274.76
43.27
231.49
9209-MSWLF-1984
MW-10d
5/1/2001
35.91499
78.57494
Bedrock
93.0
80.0-90.0
78.0-92.0
75.0-78.0
2
274.54
47.27
227.27
9209-MSWLF-1984
MW-11
Oct 1995
35.90574
78.58251
Regolith
57.0
39.0 - 54.0
37.0-54.0
35.0-37.0
2
343.63
43.29
300.34
9209-MSWLF-1984
MW-11d
Oct1995
35.90578
78.58248
Bedrock
72.0
64.0-69.0
62.0-69.0
60.0-62.0
2
343.27
43.45
299.82
9209-MSWLF-1984
MW-22
June-97
35.91596
78.57453
Regolith
39.0
27.0-37.0
25.0-37.0
23.0-25.0
2
254.62
35.31
219.31
9209-MSWLF-1984
MW-23
June-97
35.91373
78.57540
Regolith
50.0
38.0-48.0
36.0-48.0
34.0-36.0
2
274.83
45.16
229.67
9209-MSWLF-1984
MW-23d
4/27/1998
35.91373
78.57540
Bedrock
91.0
0-43.0
78.0-88.0
76.0-88.0
74.0-76.0
2
274.89
45.24
229.65
9209-MSWLF-1984
MW-24
June-97
35.91232
78.57546
Regolith
47.5
35.0-45.0
33.0-45.0
31.0-33.0
2
266.64
45.72
220.92
9209-MSWLF-1984
MW-28
4/9/1998
35.91644
78.57439
Regolith
30.0
--
20.0-30.0
18.0-30.0
16.0-18.0
2
237.89
18.75
219.14
9209-MSWLF-1984
MW-28d
4/22/1998
35.91644
78.57439
Bedrock
51.0
0-28.0
41.0-51.0
39.0-51.0
37.0-39.0
2
238.44
18.67
219.77
9209-MSWLF-1984
MW-29d
4/22/1998
35.91472
78.57572
Bedrock
52.0
0-40.5
47.0-52.0
45.0-52.0
43.0-45.0
2
275.06
41.53
233.53
9209-MSWLF-1984
MW-30
4/14/1998
35.91374
78.57596
Regolith
55.0
40.0-55.0
38.0-55.0
36.0-38.0
2
282.32
50.43
231.89
9209-MSWLF-1984
MW-31
4/2/1998
35.91231
78.57595
Regolith
35.5
--
25.5-35.5
23.0-35.5
21.0-23.0
2
261.67
33.11
228.56
9209-MSWLF-1984
MW-31d
4/23/1998
35.91231
78.57595
Bedrock
66.0
0-51.0
56.0-66.0
54.0-66.0
52.0-54.0
2
260.92
32.60
228.32
9209-MSWLF-1984
MW-32
4/3/1998
35.91142
78.57564
Regolith
26.0
13.0-23.0
11.0-23.0
9.0-11.0
2
242.99
17.71
225.28
9209-MSWLF-1984
TB-1a
4/7/1998
35.91188
78.57595
Regolith
30.0
--
20.0-30.0
17.5-30.0
14.0-17.5
2
255.05
29.06
225.99
9209-MSWLF-1984
TB-1a deep
1 5/7/2001
35.91188
78.57595
Bedrock
62.0
0-23.0
52.0-62.0
50.0-62.0
47.0-50.0
2
256.01
31.19
224.82
9209-MSWLF-1984
MW-33
7/22/1998
35.91077
78.57169
Regolith
28.0
10.0-25.0
8.0-25.0
6.0-8.0
2
222.01
13.35
208.66
9209-MSWLF-1984
MW-34
7/23/1998
35.91192
78.57116
Regolith
28.0
--
15.0-25.0
13.0-25.0
11.013.0
2
221.96
15.55
206.41
9209-MSWLF-1984
MW-34d
7/23/1998
35.91192
78.57116
Bedrock
58.0
0-38.0
45.0-55.0
43.0-55.0
41.0-43.0
1 2
1 222.16
15.80
206.36
9209-MSWLF-1984
MW-35
7/23/1998
35.91322
78.57052
Regolith
28.0
10.0-25.0
8.0-25.0
6.0-8.0
2
223.48
18.33
205.15
9209-MSWLF-1984
MW-36
11/25/2008
35.91491
78.57193
Regolith
40.0
25.0-40.0
23.0-40.0
21.0-23.0
1 2
1 237.40
27.22
210.18
9209-MSWLF-1984
MW-36d
11/25/2008
35.91491
78.57193
Bedrock
55.0
0-45.0
50.0-55.0
48.0-55.0
45.0-48.0
1 2
1 237.68
27.44
210.24
Notes:
1. TOC - Top of Casing
2. bgs - Below Ground Surface
3. Latitude and Longitude Coordinates - World Geodetic System 1983
Smith Page 1 of 1 December 2019

Table 2
Summary of Calculated Groundwater Flow Velocities
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
9209-MSWLF-1984
MW-5R
0.33 0.18
0.0233
4.28E-02
0.0233F4.27E-02r0.!O!23!2
4.25E-02
0.0234
4.29E-02
0.0232
4.25E-021.16E-04
9209-MSWLF-1984
MW-6
10.58
0.13
0.0204
1.66E+00
0.0203
1.65E+00
1.65E+00
0.0204
1.66E+00
0.0203
1.65E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0254
1.62E-01
0.0253
1.62E-01
0.0253
1.62E-01
0.0254
1.62E-01
0.0254
1.62E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0246
4.93E-01
0.0245
4.91E-01
0.0246
4.93E-01
0.0245
4.91E-01
0.0244
4.90E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0199
8.09E-02
0.0198
8.06E-02
0.0198
8.07E-02
0.0199
8.10E-02
0.0198
8.06E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0172
1.75E-01
0.0171
1.74E-01
0.0170
1.73E-01
0.0173
1.76E-01
0.0170
1.73E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0213
9.28E-01
0.0213
9.26E-01
0.0213
9.25E-01
0.0213
9.30E-01
0.0212
9.25E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0183
7.11E-03
0.0183
7.10E-03
0.0182
7.09E-03
0.0183
7.11E-03
0.0182
7.08E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0197
2.36E-01
0.0197
2.36E-01
0.0198
2.36E-01
0.0198
2.37E-01
0.0198
2.37E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0248
2.81E-02
0.0249
2.82E-02
0.0248
2.82E-02
0.0250
2.83E-02
0.0249
2.82E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0195
1.14E+00
0.0195
1.14E+00
0.0195
1.14E+00
0.0196
1.14E+00
0.0195
1.14E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0194
1.51E-01
0.0193
1.51E-01
0.0194
1.51E-01
0.0194
1.51E-01
0.0193
1.51E-01
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the exception of MW-361).
smt� Page 1 of 4 December 2019

Table 2
Summary of Calculated Groundwater Flow Velocities
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Hydraulic
9209-MSWLF-1984
MW-513
Conductivity
feet/day (cm/s)
0.33 0.18
0.0237
4.34E-02
0.0230
4.22E-02
0.0237
4.34E-02
0.023374.27E-02
0.0240
4.40E-021.16E-049209-MSWLF-1984
MW-6
10.58
0.13
0.0206
1.68E+00
0.0204
1.66E+00
0.0206
1.68E+00
0.0206
0.0208
1.69E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0257
1.64E-01
0.0255
1.63E-01
0.0257
1.64E-01
0.0257
0. 2257
1.64E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0248
4.97E-01
0.0246
4.94E-01
0.0248
4.98E-01
0.0249
4.99E-01
0.0250
5.02E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0201
8.17E-02
0.0199
8.09E-02
0.0201
8.17E-02
0.0200
8.15E-02
0.0202
8.22E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0171
1.74E-01
0.0170
1.73E-01
0.0171
1.74E-01
0.0170
1.73E-01
0.0172
1.76E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0215
9.36E-01
0.0213
9.27E-01
0.0215
9.36E-01
0.0214
9.32E-01
0.0216
9.41E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0184
7.16E-03
0.0183
7.10E-03
0.0184
7.15E-03
0.0183
7.10E-03
0.0186
7.22E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0198
2.37E-01
0.0197
2.36E-01
0.0197
2.36E-01
0.0197
2.36E-01
0.0199
2.38E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0251
2.84E-02
0.0249
2.82E-02
0.0250
2.84E-02
0.0249
2.83E-02
0.0253
2.87E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0198
1.16E+00
0.0196
1.15E+00
0.0197
1.15E+00
0.0197
1.15E+00
0.0196
1.15E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0196
1.53E-01
0.0195
1.52E-01
0.0196
1.53E-01
0.0196
1.53E-01
0.0197
1.54E-01
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the exception of MW-361).
Smith Page 2 of 4 December 2019

Table 2
Summary of Calculated Groundwater Flow Velocities
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
9209-MSWLF-1984
MW-513
0.33 0.18
0.0233
4.28E-02
0.0241
4.43E-02
0.0235
4.31E-02
0.0257
4.72E-02
1.16E-04
9209-MSWLF-1984
MW-6
10.58
0.13
0.0206
1.68E+00
0.0209
1.70E+00
0.0208
1.69E+00
0.0206
1.68E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0257
1.64E-01
0.0261
1.66E-01
0.0256
1.64E-01
0.0257
1.64E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0249
5.00E-01
0.0252
5.06E-01
0.0248
4.98E-01
0.0249
4.99E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0201
8.16E-02
0.0199
8.10E-02
0.0200
8.15E-02
0.0198
8.06E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0168
1.72E-01
0.0171
1.74E-01
0.0171
1.74E-01
0.0172
1.75E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0214
9.31E-01
0.0217
9.44E-01
0.0215
9.35E-01
0.0217
9.46E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0182
7.09E-03
0.0185
7.21E-03
0.0182
7.07E-03
0.0185
7.21E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0196
2.35E-01
0.0198
2.36E-01
0.0197
2.36E-01
0.0198
2.37E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0248
2.81E-02
0.0253
2.86E-02
0.0251
2.84E-02
0.0251
2.85E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0197
1.16E+00
0.0200
1.17E+00
0.0197
1.15E+00
0.0197
1.16E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0196
1.53E-01
0.0199
1.55E-01
0.0195
1.52E-01
0.0196
1.53E-01
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously perfomed slug tests and grain size
analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the
exception of MW-36D.
smt� Page 3 of 4 December 2019

Table 2
Summary of Calculated Groundwater Flow Velocities
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Average
9209-MSWLF-1984
MW-5R
0.33 0.18
Linear Velocity
M
0.0233
4.27E-02
0.0233
4.27E-02
0.0229
4.20E-02
0.0238
4.36E-02
1.16E-04
9209-MSWLF-1984
MW-6
10.58
0.13
0.0204
1.66E+00
0.0203
1.65E+00
0.0204
1.66E+00
0.0206
1.67E+00
3.73E-03
9209-MSWLF-1984
MW-7
1.15
0.18
0.0255
1.63E-01
0.0253
1.62E-01
0.0256
1.64E-01
0.0257
1.64E-01
4.06E-04
9209-MSWLF-1984
MW-8
3.61
0.18
0.0247
4.96E-01
0.0245
4.92E-01
0.0249
4.98E-01
0.0249
4.99E-01
1.27E-03
9209-MSWLF-1984
MW-9
1.22
0.30
0.0200
8.12E-02
0.0198
8.06E-02
0.0199
8.10E-02
0.0201
8.18E-02
4.30E-04
9209-MSWLF-1984
MW-10
0.509
0.05
0.0174
1.78E-01
0.0173
1.76E-01
0.0169
1.72E-01
0.0170
1.73E-01
1.80E-04
9209-MSWLF-1984
MW-11
5.66
0.13
0.0215
9.35E-01
0.0213
9.28E-01
0.0213
9.27E-01
0.0215
9.36E-01
2.00E-03
9209-MSWLF-1984
MW-22
0.07
0.18
0.0185
7.21E-03
0.0183
7.12E-03
0.0181
7.04E-03
0.0184
7.16E-03
2.47E-05
9209-MSWLF-1984
MW-23
3.59
0.30
0.0198
2.37E-01
0.0199
2.38E-01
0.0197
2.36E-01
0.0197
2.36E-01
1.27E-03
9209-MSWLF-1984
MW-24
0.34
0.30
0.0251
2.85E-02
0.0250
2.83E-02
0.0248
2.82E-02
0.0251
2.84E-02
1.20E-04
9209-MSWLF-1984
MW-36
17.56
0.30
0.0197
1.16E+00
0.0195
1.14E+00
0.0196
1.15E+00
0.0198
1.16E+00
6.19E-03
9209-MSWLF-1984
MW-36D
0.78
0.10
0.0196
1.53E-01
0.0194
1.51E-01
0.0195
1.52E-01
0.0043
3.35E-02
2.75E-04
Notes:
1. cm/s - centimeters per second
2. Hydraulic conductivity and effective porosity values are estimated from previously perfomed slug tests and grain size
analyses.
3. The gradient and linear velocity values shown for MW-11 are based on the average of all the listed wells, with the
exception of MW-36D.
smt� Page 4 of 4 December 2019

Table 3
Water Quality Parameters
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill
Permit Number 9209-MSWLF-1984
9209-MSWLF-1984 MW-5R
Temperature
229.2
6.11 305 17.3 9 !1.
9209-MSWLF-1984
MW-6
6.38
761
19.8
29
39.3
9209-MSWLF-1984
MW-6d
6.12
156
18.2
10
336.5
9209-MSWLF-1984
MW-7
6 227
735
18.8
9
-17.1
9209-MSWLF-1984
MW-8
6.07
396
19.0
58
0.49
116.9
9209-MSWLF-1984
MW-8d
6.19
187
17.7
8
1.29
139.9
9209-MSWLF-1984
MW-9
6.50
728
19.4
61
1.55
105.4
9209-MSWLF-1984
MW-10
5.85
245
19.0
54
0.80
44.3
9209-MSWLF-1984
MW-10d
6.25
198
18.5
19
5.95
133.9
9209-MSWLF-1984
MW-11
6.16
119
12.5
23
6.46
183.2
9209-MSWLF-1984
MW-11d
6.12
121
17.9
9
6.03
187.2
9209-MSWLF-1984
MW-22
DRY
9209-MSWLF-1984
MW-23
6.06
82
17.1
322
7.88
191.4
9209-MSWLF-1984
MW-23d
6.05
176
17.0
3
4.89
186.5
9209-MSWLF-1984
MW-24
DRY
9209-MSWLF-1984
MW-28
(2)
9209-MSWLF-1984
MW-28d
(2)
9209-MSWLF-1984
MW-29d
6.08 1 149 16.9 4 6.76 145.8
9209-MSWLF-1984
MW-30
DRY
9209-MSWLF-1984
MW-31
DRY
9209-MSWLF-1984
MW-31d
6.26
182
17.7
7
3.84
156.3
9209-MSWLF-1984
MW-32
5.88
153
16.8
24
1.28
187.3
9209-MSWLF-1984
TB-1a
DRY
9209-MSWLF-1984
TB-1a deep
6.08 1 216 16.7 10 6.09 200.5
9209-MSWLF-1984
MW-33
9209-MSWLF-1984
MW-34
5.63
113
16.1
762
1.52
195.8
9209-MSWLF-1984
MW-34d
6.08
190
16.2
1
0.61
1 466.0
9209-MSWLF-1984
MW-35
9209-MSWLF-1984
MW-36
6.00 172 17.0 489 0.57 1 146.4
9209-MSWLF-1984
9209-MSWLF-1984
MW-36d
SampleSurface Water Location ..
SW-2
6.59 251 17.3 33 0.71 1 59.5
7.20 162 13.2 45 8.67 130.5
9209-MSWLF-1984
SW-3
8.17 176 11.4 15 11.64 59.1
9209-MSWLF-1984
SW-7
7.76 124 11.6 24 11.23 101.9
9209-MSWLF-1984
SW-8
7.53 136 11.6 11 10.00 104.3
Notes:
1. Water quality measurements were collected on November 4-7, 2019.
2. (21- Monitoring wells MW-28, -28d, -33, and -35 are sampled yearly during the spring event.
3. Turbidity readings were recorded at the time samples were collected.
4. µS/cm - Microsiemens per centimeter
5. mg/L - Milligrams per liter
6. ORP - Oxidation -Reduction Potential
7. NTUs
- Nephelometric Turbidity Units
8. mvs -
Millivolts
9. S.U. -
Standard Units
10. DO -
Dissolved Oxygen
Smith Page 1 of 1 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
M C v 3 3 V
i £ s M e> r_
O O J N N in M C N
CO CO V L V V Z N F M
V 7
I 7nn 1 4* 1 2 in I 1* 1.nnn I is 1 1 inn I 2n I 2n n-2* I ns* 1-nnc
MW-11
1-Nov-11
80.7J
1. 91
6.33JB
2.14JB
3.61J
19.6
MW-11
25-Apr-12
65.3J
2.37J
3.23J
12.1
MW-11
23-Oct-12
80.6J
1.42.11
3.66J
5.32J
19.7
MW-11
17-Apr-13
901
0.2J
2J
21
8J
11
11
9.11
20B
MW-11
16-Oct-13
100
0.1J
0.2J
2J
11
4J
0.5J
0.91
5.11
15B
MW-11
16-Apr-14
170
0.5J
0.2J
4J
61
18
3J
3J
0.08J
40
50B
MW-11
12-Nov-14
901
0.2J
0.2J
2J
21
8J
11
11
0.051
7.11
24
MW-11
30-Apr-15
100
0.2J
2J
31
101
11
2J
0.06J
12J
27
MW-11
15-Oct-15
110
0.1
0.1J
1
31
11
11
0.04J
2J
0.05J
13JB
27
MW-11
21-Apr-16
0.5J
130
0.1
1
41
16
2J
2J
O.11B
18.11
32
MW-11
1-Sep-16
90J
0.28J
0.54J
2.4J
2.61
8.3J
1.3J
1.6J
11.11
20
M W-11
20-Apr-17
61J
1.2J
1.51
11
MW-11
22-Sep-17
45J
2.4J
1. 8J
3.7.11
6.3J
MW-11
13-Apr-18
61J
2.1
2.OJ
0.27J
12
MW-11
25-Oct-18
71J
2.2J
3.9J
0.50J
5.1.11
66
MW-11 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
26-Feb-19
57J
2.OJ
1.4J
10
MW-11
25-Apr-19
120
0.30J
3.8J
3.3.11
20
2.2J
1. 8J
17J
28
MW-11 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
2-Jul-19
170
0.70
5.1
7.4
25
4.1
4.1
33
45B
MW-11 (dissolved)
2-Jul-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11
7-Nov-19
59
2.1J
4.3J
0.66J
0.48
5.6
25
MW-11 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-11d
2-Nov-11
45.5J
2.18J
4.14JB
2.45J
5.86J
MW-11d
26-Apr-12
0.247J
44.2J
3.04J
9.68JB
3.31J
2.05J
4.62J
MW-11d
24-Oct-12
43.71
0.375J
2.40J
2.53J
5.10J
MW-11d
18-Apr-13
0.4J
50J
0.11
2JB
0.21
11
0.6J
4JB
MW-11d
17-Oct-13
0.6J
0.61
50J
0.1
11
0.2J
11
0.02J
0.6J
2J
2JB
MW-11d
17-Apr-14
300
2.1
0.2J
15
13
56
11
91
0.21
99
88
MW-11d
13-Nov-14
150
0.7J
0.11
5J
4.11
18
4J
1
0.071
37
35
MW-11d
29-Apr-15
0.6J
O.SJ
60J
0.11
0.11
21
0.61
3J
0.6J
0.91
51
8J
MW-11d
15-Oct-15
0.4J
901
0.1
0.11
1
2.11
91
2J
0.05J
2J
14JB
16
MW-11d
21-Apr-16
0.3J
60J
21
0.1
4J
0.5J
2J
12
MW-11d
1-Sep-16
0.43B1
45J
0.0761
1.21
2.1J
0.25J
0.75J
2.7.11
9.2JB
MW-11d
20-Apr-17
48J
2.21
2.2J
2.2J
5.OJ
MW-11d
22-Sep-17
45J
2.81
1.6J
3.3J
5.1J
MW-11d
12-Apr-18
43J
5.81
2.8J
4.4J
MW-11d
23-Oct-18
46J
25
13J
4.2J
MW-11d
25-Feb-19
46J
7.OJ
3.4J
3.6J
MW-11d (dup)
25-Feb-19
45J
9.91
4.9J
4.OJ
MW-11d
25-Apr-19
46J
5.OJ
2.2J
2.8J
MW-lid
2-Jul-19
90
0.42
4.1J
2.51
12
1.8
2.4J
17
18B
MW-lid (dissolved)
2-Jul-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-lid
5-Nov-19
43
2.31
2.61
0.29J
1.91
13B
MW-lid (dup)
5-Nov-19
44
2.51
2.11
0.26J
1.81
11B
MW-5R
31-Oct-11
123
3.281
2.171
5.83JB
1.131
0.1521
8.331
MW-5R
24-Apr-12
0.4111
97.31
2.791
2.47J
0.170J
4.281
MW-5R
22-Oct-12
99.31
1.821
3.611
0.1141
23.9
MW-5R
17-Apr-13
80J
0.081
21
0.1
31
0.11
5113
MW-5R
16-Oct-13
901
0.051
11
0.51
0.41
31
0.11
5J13
MW-5R
16-Apr-14
80J
0.1
0.1
0.21
0.51
iJ
0.2J
2J
5J13
MW-5R
12-Nov-14
80J
21
0.21
21
0.3J
6113
MW-5R
30-Apr-15
70J
0.11
0.81
0.11
11
0.11
41
MW-5R
15-Oct-15
110
0.21
71
0.81
21
0.61
0.041
41
0.11
61
MW-5R
21-Apr-16
60J
0.071
11
0.21
0.41
iJ
0.1113
21
MW-5R
14-Sep-16
79J
0.0631
1.71
0.45113
0.046JB
2.4J
0.0801
1.11
5.31B
MW-5R
20-Apr-17
71J
1.5J
MW-5R
20-Sep-17
430
13
1.71
1.4J
5.81
MW-5R
11-Apr-18
76J
1.4J
1.5J
2.61
MW-5R
24-Oct-18
84J
2.1J
3.31
MW-5R
22-Apr-19
68J
0.23J
MW-5R
6-Nov-19
130
2.2J
2.31
5.7
15
Smith Page 1 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-6
1-Nov-11
0.229.1
3.981
454
6.35.1
65.7
4.04JB
18.21E 2.55.1
4.11.1
5.36.1
MW-6
24-Apr-12
0.244.1
182
3.49.1
54.9
8.45J
2.18.1
0.1341
117
MW-6
22-Oct-12
258
0.148J
1.59.1
80.4
15.1J
MW-6
17-Apr-13
100J
0.051
1.6
35
4.1
0.17.1
6J
O.W
9J13
MW-6
16-Oct-13
90J
0.041
0.31
34
2.1
0.02.1
5J
21
0.2J
3J
5J13
MW-6 (dup)
16-Oct-13
90.1
0.21
0.61
35
2.1
0.04.1
6J
21
0.21
31
MW-6
16-Apr-14
0.21
60J
0.101
0.81
11
18
3.1
0.21
4J
0.31
21
8J13
MW-6 (dup)
16-Apr-14
60J
0.071
0.71
11
18
2.1
0.21
4J
0.2J
3J
8J13
MW-6
12-Nov-14
0.8.1
310
49
1.1
0.02.1
15J
2J
0.1J
2J13
MW-6
30-Apr-15
70J
0.061
0.11
25
1.1
0.08.1
4J
0.1J
3.1
MW-6
14-Oct-15
230
0.21
32
4.1
0.03.1
13J
21
MW-6
20-Apr-16
70J
0.041
8J
0.5J
0.03.1
3J
1.1
0.08.1
MW-6 (dup)
20-Apr-16
70J
0.1
7J
0.6J
0.03.1
3J
1.1
0.07.1
MW-6
14-Sep-16
0.19JB
0.29.1
210
0.131
19
2.1J13
0.032JB
9.31
1.1J
0.084.1
1.2J
6.0J13
MW-6
20-Apr-17
120
2.5J
8.3J
0.98.1
0.40
4.21
MW-6 (dup)
20-Apr-17
130
2.6J
8.2J
1.0.1
0.41
4.81
21
MW-6
21-Sep-17
160
5.3J
2.2.1
7.61
MW-6
12-Apr-18
130
0.14J
7.9J
4.61
MW-6
24-Oct-18
240
0.131
1.31
18
1.5.1
6.91
MW-6
22-Apr-19
120
0.171
0.131
19
0.17.1
4.51
MW-6
7-Nov-19
270
0.181
67
1.6.1
0.1613J
18
2.5.1
0.281
6.4.1
MW-6 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
77
NA
NA
NA
NA
NA
NA
0.321
NA
NA
MW-6d
2-Nov-11
2.6
100
5.421
1.26J
6.46JB
4.68J
3.981
13.1
MW-6d
26-Apr-12
1.59J
72J
5.68J
7.24JB
2.37J
2.61J
41
6.97J
MW-6d (dup)
26-Apr-12
1.22J
66J
5.53J
6.45JB
2.10J
2.20J
3.781
5.88J
MW-6d
23-Oct-12
1.21J
2.84J
71.1J
0.407J
4.83J
2.83J
2.11J
3.59J
6.02J
MW-6d
18-Apr-13
3.1J
80J
0.11
0.51
41
0.91
31
0.41
A8JB
MW-6d (dup)
18-Apr-13
2.8J
70J
0.091
0.4J
41
0.81
31
0.41
21
6J13
MW-6d
17-Oct-13
6.9
80J
0.11
0.51
41
41
0.61
0.031
3J
3J
7J13
MW-6d
17-Apr-14
1.2J
60J
0.11
0.11
41
21
0.31
21
6J
7J13
MW-6d
12-Nov-14
1.2J
60J
0.11
0.21
31
21
0.31
21
4113
MW-6d
30-Apr-15
1.7J
0.6J
50J
0.081
0.11
41
0.91
21
0.21
21
3J
41
MW-6d (dup)
30-Apr-15
2.1J
80J
0.051
0.21
41
0.91
21
0.31
0.051
21
3J
6J13
MW-6d
15-Oct-15
1.1J
60J
0.11
0.21
41
0.61
21
0.41
0.041
3J
2JB
61
MW-6d
20-Apr-16
0.41
50J
0.071
0.11
41
0.61
21
3J
41
MW-6d
12-Sep-16
1.0J
65J
0.211
4.41
0.851
6.6JB
1.71
2.41
4.7J
15
MW-6d
20-Apr-17
51J
2.61
2.41
1.61
9.11
MW-6d
22-Sep-17
0.66.1
33J
4.2.1
6.31
MW-6d
13-Apr-18
1.0J
41J
3.81
1.41
7.61
MW-6d
24-Oct-18
31J
7.91
2.41
3.5J
MW-6d
23-Apr-19
57J
0.151
8.21
5.31
0.51J
2.91
8.21
6.51
MW-6d
6-Nov-19
0.55J
70
0.81
4.4J
3.51
0.39J
2.2J
3.51
16
MW-7
2-Nov-11
67.11
0.38J
14.9
31.6
21.2E
13.4J
1.171
3.271
9.741
44.8
MW-7
26-Apr-12
50.31
0.8051
13.3
27.1
10.7E
4.04J
10.91
3.631
7.241
13.9
MW-7
22-Oct-12
80.71
29.6
30.8
37.4
6.69J
11.5J
2.021
0.152J
24.21
24.1
MW-7
16-Apr-13
80J
0.51
0.61
35
27
61
91
0.18J
13J
2J
0.2J
24J
25B
MW-7
16-Oct-13
60J
0.11
0.61
5J
37
11
11
0.041
12J
3J
12J
11B
MW-7
16-Apr-14
50J
0.21
1.1
101
46
19
31
0.041
17J
3J
0.09J
23J
40B
MW-7
11-Nov-14
0.5J
70J
0.41
0.71
23
26
45
71
0.28
13J
21
51
22
=
MW-7
30-Apr-15
60J
0.11
0.91
5J
48
11
21
0.041
17J
0.081
33
MW-7
14-Oct-15
40J
0.1J
0.41
7J
30
10
21
0.021
10J
11
0.05J
31
MW-7
20-Apr-16
40J
0.06J
1.0
2J
52
71
21
0.031
17J
2J
11
MW-7
13-Sep-16
0.24J
44J
1.6
1.4J
41
5.51E
1.1J
12J
13
MW-7
18-Apr-17
34J
0.13J
0.831
6.1J
31
30
16
0.037J
9.2J
7.41
MW-7
18-Sep-17
0.52J
27J
23
1.11
6.8J
MW-7
11-Apr-18
41J
1.5
3.7J
32
7.6J
1.11
111
5.7J
29
MW-7 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
31
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
25-Oct-18
52J
1.3
3.31
34
22
8.6J
101
8.6)
30
MW-7 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
37
NA
NA
NA
NA
NA
NA
NA
NA
MW-7
24-Apr-19
35J
17
6.41
12
MW-7
4-Nov-19
46
0.381
0.84
13
27
38
10
0.17131
8.9
0.26J
0.181
26
24B
�m 1t�1 Page 2 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-8
31-Oct-11
56.5.1
7.42.1
4.53J13 4.951B
5.18J 7.32.1
MW-8
24-Apr-12
0.937.1 41.3.1
1.21.1
3.19J
1.83J 515
MW-8
22-Oct-12
41.8.1 0.146.1
0.404.1
1.20.1
2.76J
1.97J
MW-8
17-Apr-13
0.8.1 50J 0.081
2.1
0.03.1 4J
9J13
MW-8
16-Oct-13
50J 0.11
0.21
21
4J
MW-8
16-Apr-14
50J 0.071
11
51
51 107
M W-8
12-Nov-14
50J
0.61
0.4J 51
5.113
MW-8
30-Apr-15
80J 0.1.1
0.11
41
2J 2.1 0.2J 7J
14
MW-8
15-Oct-15
80J 0.08.1
0.11
21
2J 0.3J 0.04.1 6J
6.1
MW-8
21-Apr-16
70J
0.81
2J 0.02.1 6J 0.05JB
6.1
MW-8
14-Sep-16
65J
0.13.1
1.9J 0.27.113 6.61
8.5JB
MW-8
20-Apr-17
61J
4.9.1
4.7J
MW-8
18-Sep-17
73J
0.14J
0.851 4.6.1
5.71
M W-8
12-Apr-18
65J
4.2J 5.2.1
4.51
MW-8
24-Oct-18
71J
2.7J 5.0.1
7.01
MW-8
22-Apr-19
110
1.3.1
9.4J 0.11.1 8.2.1
120
MW-8 (dup)
22-Apr-19
110
9.51 8.1.1
2.5J 5.6.1
MW-8
7-Nov-19
48
6.4
1.61 2.5.1 0.32B 5.4
6.0 12
MW-8 (dissolved)
7-Nov-19
NA NA NA NA
NA
NA
1.51 NA NA NA NA NA NA NA
2.61 NA
MW-8d
2-Nov-11
0.724.1
25.0.1
1.05
5.02.1
5.02.113
2.00J
4.221
7.28.1
MW-8d
26-Apr-12
1.63J
34.5.1
11B
2.82J
4.151
7.52.1
MW-8d
24-Oct-12
1.591
30.6.1
0.483.1
5.46.1
3.21J
4.791
9.99.1
MW-8d
18-Apr-13
0.61
20J
4.1
0.3.1
1.1
0.2J
11
0.06J
2J13
MW-8d
17-Oct-13
40J
0.2.1
0.3.1
6.1
M
6.1
1.1
0.03.1
21
71
MW-8d
17-Apr-14
0.91
20J
0.1.1
4.1
0.4.1
2.1
0.31
0.8.1
7J
5J13
MW-8d
12-Nov-14
1.01
20J
4.1
0.3.1
21
0.3J
0.9.1
2J13
MW-8d
30-Apr-15
2.5J
0.6J
20J
0.1.1
3.1
0.4.1
11
0.4J
iJ
2J
4.1
MW-8d
15-Oct-15
0.21
20J
3.1
0.061
0.05.1
0.5.1
11B
MW-8d
21-Apr-16
20J
3.1
0.5.1
MW-8d
14-Sep-16
16J
1.7.1
0.60JB
0.047JB
0.72J
4.8J
2.0J13
MW-8d
20-Apr-17
19.1
2.6.1
4.3J
4.01
3.11
MW-8d
18-Sep-17
16J
2.9.1
3.31
MW-8d (dup)
18-Sep-17
17J
3.2.1
2.81
MW-8d
12-Apr-18
17J
3.5.1
MW-8d
23-Oct-18
18.1
6.5.1
2.2.1
4.4J
MW-8d (dup)
23-Oct-18
17J
6.3.1
2.0.1
4.51
MW-8d
23-Apr-19
17J
4.0.1
3.91
MW-8d
6-Nov-19
21
0.221
IT
3.2.1
1.4.1
3.91
14
MW-9
1-Nov-11
209
0.425.1
14.9
6.79J
8.83.113
6.37J
4.11J13
0.982J
4.52.1
0.164J
6.881
69.2
MW-9 (dup)
1-Nov-11
191
0.256.1
10.4
5.81J
5.32.113
3.99J
3.08J13
0.874J
3.66.1
0.127J
3.26J
50.1
MW-9
25-Apr-12
176
0.220.1
5.68.1
4.81J
2.721
13.5
MW-9
23-Oct-12
5.17J
210
0.7111
6.96J
17.1
27.2
3.41J
7.49.1
0.521J
30.2
141
MW-9
17-Apr-13
160
0.3JB
3J
4J
4.1
4J
4J
0.3J
81
27B
MW-9
16-Oct-13
120
0.2J
1.1
2J
0.4J
21
11
2J
0.2J
61
16B
MW-9
16-Apr-14
130
0.4J
1.3
4J
0.81
51
41
1
0.3J
16J
36B
MW-9
12-Nov-14
120
0.3J
0.4J
4J
0.61
41
31
2J
0.21
17
MW-9 (dup)
12-Nov-14
140
0.5J
0.4J
6J
61
61
2J
0.3J
4J
28
MW-9
29-Apr-15
0.7J
901
0.1J
0.3J
2J
0.11
11
0.81
0.8J
0.2J
31
81
MW-9
15-Oct-15
160
0.71
0.2J
91
61
71
0.071
11
0.3J
111B
31
0.2J
MW-9
20-Apr-16
150
0.21
2J
11
0.71
0.91
0.11
31
MW-9
13-Sep-16
100
0.151
0.121
1.7J
1.31E
1.01
1.2J
0.16J
11JB
9.41
MW-9
19-Apr-17
130
2.1J
1.01
0.52J
7.41
4.61
MW-9
21-Sep-17
160
1.4
0.371
11
2.1J
0.401
34
49
M
MW-9 (dissolved)
21-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
111
NA
MW-9
11-Apr-18
130
0.161
3.2J
0.61J
3.0J
0.20J
5.51
4.5.1
MW-9 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
5.61
NA
MW-9
25-Oct-18
891
2.11
0.15J
111
MW-9
25-Apr-19
150
1.1
2.31
0.391
2.41
7.11
6.91
MW-9
7-Nov-19
230
0.171
1.5
3.81
11
2.1
0.22
4.71
1.71
0.22J
10
57
MW-9 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.211
6.7
NA
�m 1t�1 Page 3 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-10
31-Oct-11
28.1J
1.72.1
1.61J
3.56.113
3.00J
1.94.1
12.8
MW-10
25-Apr-12
34.7.1
0.320.1
0.438.1
1.79.1
2.04J
4.81.1
2.64J
0.538
2.25J
21.7
MW-10
23-Oct-12
31.1.1
0.302.1
0.965.1
2.07J
2.51J
2.57J
0.910
2.07J
16.5
MW-10
17-Apr-13
30J
0.3J13
0.4.1
0.4.1
2J
2.113
1.1
0.43
1
0.06.1
14B
MW-10
16-Oct-13
30J
0.3.1
0.2.1
0.4.1
2J
2.1
1.1
0.29
1
0.05.1
9J13
MW-10
16-Apr-14
30J
0.3.1
0.2.1
2J
1.1
0.5J
0.05.1
1
38B
MW-10
12-Nov-14
30J
0.3.1
2J
0.03.1
1
9J13
MW-10
29-Apr-15
0.2.1
40J
0.3.1
0.1J
3J
2.1
1.1
0.10.1
5J
0.05.1
10
MW-10
14-Oct-15
30J
0.3.1
0.2.1
2J
0.8.1
0.4.1
0.08.1
1
27
MW-10
20-Apr-16
30J
0.3.1
0.1J
4J
0.6J
0.3J
0.03.1
51
11
0.05.1
4.1
MW-10
13-Sep-16
0.47.1
31J
0.36.1
0.19.1
3.8J
2.0.113
1.2J
0.14.1
4.8.1
FW6J 1
280
MW-10
19-Apr-17
27J
0.32.1
2.9J
0.93.1
0.38J
0.064.1
3.4.1
17
MW-10
22-Sep-17
17J
0.18.1
1.3J
2.2.1
0.30J
2.3.1
2.1J 1
8.9.1
MW-10
11-Apr-18
20J
0.32.1
0.87.1
1.9.1
2.4J
1.3J
0.55J
0.27
2.5.1
51
MW-10
25-Oct-18
24J
0.16.1
0.72.1
2.3J
0.57J
0.39
2.7.1
77
MW-10 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
2.6J
NA
NA
NA
NA
NA
NA
NA
NA
MW-10
25-Apr-19
25J
1.7.1
2.7J
0.45J
5.1J
2.5.1
MW-10
7-Nov-19
20
0.24J
2.6J
2.6.1
0.50J
0.12.1
4.3.1
2.5.1
66
MW-10 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
2.2J
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-10d
2-Nov-11
3.81.1
2.10.1
3.18.113
4.14.1
MW-10d
26-Apr-12
0.232.1
4.36.1
3.50.1
3.47JB
4.57J
MW-10d
24-Oct-12
3.11.1
MW-10d
18-Apr-13
4J13
1J13
0.07.1
0.7.1
11
MW-10d
16-Oct-13
0.3.1
3J13
0.2.1
1.1
0.05.1
0.7.1
0.61
MW-10d
17-Apr-14
2.1
0.4.1
0.6J
4J
3J13
MW-10d
12-Nov-14
3.1
0.5.1
0.04.1
0.4.1
MW-10d
30-Apr-15
0.81
0.5J
31
0.3.1
0.3.1
0.05.1
0.6J
41
MW-10d
15-Oct-15
0.51
51
0.071
0.8.1
0.08J
1.1
0.2J
0.07.1
0.6.1
5.1
MW-10d
21-Apr-16
0.31
51
0.2.1
2.1
1.1
2J
6.1
MW-10d
14-Sep-16
2.51
0.67.113
0.15J
3M
5.5JB
MW-10d
19-Apr-17
2.51
0.14J
0.70.1
MW-10d
18-Sep-17
4.11
0.35.1
1.4.1
3.1J
0.32J
6.91
MW-10d
11-Apr-18
0.60J
3.71
0.60J
1.8J
2.1J
0.34J
14
MW-10d
25-Oct-18
2.51
MW-10d
25-Apr-19
2.81
3.01
MW-10d
5-Nov-19
3.71
0.141
1.3J
0.34J
0.09813.11
6.281
MW-22
1-Nov-11
41.2.1 7.96 4.25.1 46.7 5.24J13 17.2JB 2.871 3.22J 43.9
MW-22
25-Apr-12
61.5.1 0.224.1 4.78 4.77.1 63.8 14J 2.561 0.162J 33.1 18.4
MW-22
23-Oct-12
34.7.1 8.27 2.28.1 44.7 16.8J 4.021 19.2
MW-22
17-Apr-13
70J 0.1J 4 0.91 76 1J13 0.71 15J 0.06J 12B
MW-22
16-Oct-13
50J 0.1J 3.5 1.1 25 1.1 11 10J 31 8113
MW-22
16-Apr-14
50J 0.1J 2.5 0.9.1 43 1.1 11 14J 41 14B
MW-22
12-Nov-14
40J 0.1J 2.5 3.1 17 2.1 2.1 101 9.1
MW-22
30-Apr-15
50J 1.5 0.6.1 31 0.7J 0.6J 101 9.1
MW-22
15-Oct-15
80J 0.7J 91 29 5.1 9.1 0.05.1 13J 4J 0.2J 14JB 56
MW-22
20-Apr-16
40J 0.07.1 1.3 18 0.5J 0.3J 7J 6J
MW-22
13-Sep-16
82J 0.821 3.1 12 38 6.9JB 11 14J 3.11 47
MW-22
19-Apr-17
451 0.26J 2.8 1.91 18 2.6.1 1.6.1 6.5J 0.931 13
MW-22
18-Sep-17
Not Sampled(4)
MW-22
13-Apr-18
Not Sampled(4)
MW-22
23-Oct-18
NotSampled(4)
MW-22
23-Apr-19
NotSampled(4)
MW-22
4-Nov-19
Not Samoled(4)
�m 1t�1 Page 4 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-23
26-Apr-12
42.7J
6.68J
1.63.11
10.41B
7.07J
4.20J
12.5J
17.5
MW-23
24-Oct-12
38.9J
5.76J
1.83.11
8.02J
4.12J
3.92J
13.3J
18.5
MW-23
18-Apr-13
0.2J
240
1.8
0.11
30
15
56
30
0.06J
28J
11
106
147
MW-23
16-Oct-13
30J
0.2J
0.1J
1
0.71
4J
2J
0.02J
2J
5.11
6JB
MW-23
16-Apr-14
50J
0.1
0.2J
7J
21
10
5J
4J
0.11
16J
25B
MW-23
12-Nov-14
50J
O.4J
7J
2.11
12
61
0.02J
5J
0.11
12J
19
MW-23
30-Apr-15
0.4J
50J
0.1
7J
2.11
13
61
0.03J
6J
0.11
15.11
26
MW-23
15-Oct-15
110
1.1
20
7J
34
18
0.06J
16J
0.51
39
69
MW-23 (dup)
15-Oct-15
170
1.6
32
11
51
30
0.12J
25J
0.81
60
112
MW-23
20-Apr-16
40J
0.1
51
11
91
5J
4J
0.11
9.11
21
MW-23
13-Sep-16
54J
0.59J
0.083J
8.9J
3.3.11
15B
7.7J
6.9J
0.22J
23J
39
MW-23
19-Apr-17
26J
0.19J
3.1
4.5J
2.11
2.4J
6.5J
7.2J
MW-23
20-Sep-17
110
1.5
0.14J
19
6.6.11
33
17
16J
0.48J
59
67
MW-23 (dissolved)
20-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.3J
NA
MW-23
11-Apr-18
85J
0.86J
0.22J
12
4.4.11
21
11
14J
0.28J
30
44
MW-23 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
25-Oct-18
51J
0.26J
0.62J
9.2J
3.1J
12
5.6J
8.1
0.191
21J
45
MW-23 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
25-Apr-19
42J
0.19J
5.6J
1.8J
8.OJ
4.6J
4.2J
13J
30
MW-23 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-23
5-Nov-19
39
0.35J
6.0
1.7.11
10
5.3
4.1
0.23J
13
24B
MW-23 (dissolved)
5-Nov-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
0.20.11
NA
MW-23d
25-Apr-12
0.754J
35J
0.746J
4.03J
16.81B
3.321
4.05.11
6.65J
MW-23d
23-Oct-12
0.552J
33.2J
0.644J
4.73J
4.38J
4.48J
8.66J
MW-23d
18-Apr-13
2.61
40J
1.5
3JB
0.1
4J
0.41
1J
12B
MW-23d
17-Oct-13
1.71
40J
0.05J
0.7J
2J
0.1
3J
0.3J
0.02J
1J
3.11
3JB
MW-23d
17-Apr-14
1.31
30J
0.1
2J
0.1
2J
0.3J
11
6J
8JB
MW-23d
13-Nov-14
1.11
40J
0.2J
2J
0.1
2J
0.3J
0.81
2J
6J
MW-23d
29-Apr-15
1.61
40J
0.2J
2J
0.1
2J
0.3J
0.91
2J
6J
MW-23d
15-Oct-15
3.61
40J
0.04J
0.5J
3J
O.4J
4J
0.6J
0.05J
11
216
13
MW-23d
20-Apr-16
1.11
40J
0.2J
31
0.31
2J
0.2J
4J
7J
MW-23d
13-Sep-16
1.21
37J
0.23J
2.3J
0.26J
2.5JB
0.48J
2.5J
6.1J
13
MW-23d (dup)
13-Sep-16
0.971
36J
0.22J
1.9J
2.2JB
0.36J
2.2J
5.7J
10
MW-23d
19-Apr-17
0.531
34J
0.24J
2.OJ
4.9J
1.4J
3.7J
6.9J
MW-23d
21-Sep-17
34J
2.7J
3.8J
3.5J
5.8J
MW-23d
10-Apr-18
38J
5.2J
2.4J
0.32J
1.81
2.61
3.4J
MW-23d (dup)
10-Apr-18
36J
4.8J
2.3J
1.7J
3.11
MW-23d
23-Oct-18
36J
14
7.OJ
4.011
MW-23d
23-Apr-19
41J
2.2J
3.9J
MW-23d
4-Nov-19
1.71
34
0.91
2.2J
4.11
0.35J
0.096BJ
1.1
3.8J
21B
MW-24
26-Apr-12
57.6J
0.281J
7.54J
7.09JB
9.801
3.35.1
1.82J
0.190J
8.38J
58.7
MW-24
23-Oct-12
35.91
2.101
2.501
4.011
0.1201
5.34J
28.3
MW-24
17-Apr-13
120
1.41
0.1J
91
21
11
17
0.24
51
0.51
17J
128
MW-24
16-Oct-13
60J
0.61
0.1J
41
0.91
51
71
0.091
21
0.21
81
46
MW-24
16-Apr-14
120
1.1
61
21
91
14
0.171
41
0.41
22J
120
MW-24
12-Nov-14
130
1.5
81
21
11
17
0.21
51
0.61
14J
117
MW-24
29-Apr-15
80J
0.81
41
11
71
91
0.121
31
0.31
101
69
MW-24
14-Oct-15
240
2.5
0.21
12
41
18
29
0.43
71
0.91
34
182
MW-24
20-Apr-16
170
1.8
101
31
13
22
0.21
6J
0.71
23J
140
MW-24
13-Sep-16
34J
0.371
0.0861
1.41
0.551
2.31B
3.61
1.5J
0.121
7.5J
31
MW-24
19-Apr-17
66J
0.771
3.81
0.981
5.01
7.91
0.086J
2.5J
0.24J
9.11
56
MW-24
20-Sep-17
51J
0.761
3.91
0.711
4.61
5.81
2.4J
0.191
7.5J
47
MW-24 (dissolved)
20-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3.6J
NA
MW-24
11-Apr-18
62J
0.751
4.81
5.01
7.11
2.6J
0.22J
6.9J
49
MW-24 (dissolved)
11-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-24
23-Oct-18
Not Sampled
(4)
MW-24
24-Apr-19
Not Sampled
(4)
MW-24
4-Nov-19
Not Sampledi4i
CMti1 Page 5 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-28
26-Apr-12
67.71
14.2
3.90J
2.8116
5.18J
5.84J
0.229J
20.7J
69.8
MW-28
18-Apr-13
60J
0.31
10
3J
11
11
4J
0.21
101
34B
MW-28
17-Apr-14
170
1.5
41
14
51
71
0.021
20J
1.01
53
159
MW-28
30-Apr-15
80J
0.51
16
5J
21
21
0.021
7J
0.41
22J
62
MW-28
21-Apr-16
20J
4J
0.06J
91
MW-28
20-Apr-17
29J
0.181
3.91
0.30J
1.31
6.11
11
MW-28
13-Apr-18
55J
0.411
W1
2.7J
1.31
5.11
0.16J
15J
22
MW-28 (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
2.61
NA
MW-28
25-Apr-19
56J
0.171
8.91
2.6J
1.21
4.41
0.15J
15J
37
MW-28 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA NA
NA
NA
2.81
NA
MW-28d
26-Apr-12
28.71
10.1
1.34J
13.313
4.99J
9.42J
4.73J
106
0.3.1
MW-28d
18-Apr-13
9J13
2JB
0.1J
0.91
0.9.1
4113
MW-28d
17-Apr-14
0.4J
1.1
6.1
4.1
0.4.1
31
1.01
51
6JE
10B
MW-28d
30-Apr-15
0.2.1
101
2.1
0.09.1
0.61
0.9.1
71
MW-28d
21-Apr-16
9.1
2.1
0.81
91
91
MW-28d
20-Apr-17
8.1.1
1.3.1
0.681
5.91
MW-28d
13-Apr-18
5.8.1
1.9.1
72.5J
6.91
MW-28d
25-Apr-19
7.1J
2.0.1
1.51
1.5.1
9.91
MW-28d (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-29d
18-Mar-11
0.39E
3.081
54.81
9.571
16.2
4.091
4.151
7.41
15.5
MW-29d
1-Nov-11
42.71
6.461
1.21J
12.4E
2.701
4.251
17.2
MW-29d
26-Apr-12
0.3171
41.5.1
6.481
8.7318
3.941
1.971
3.721
23.2
MW-29d
24-Oct-12
38.01
4.871
6.361
2.481
4.36J
7.641
MW-29d
18-Apr-13
40J
0.08.1
4.1
0.4.1
51
0.31
11
0.051
3113
MW-29d
17-Oct-13
40J
0.1.1
4.1
0.2.1
31
11
MW-29d
17-Apr-14
40J
0.08.1
3.1
0.2.1
31
0.8.1
25B
MW-29d
13-Nov-14
40J
0.07.1
3.1
0.5.1
4.1
0.31
21
2.1
MW-29d
29-Apr-15
0.2.1
0.51
40J
0.1.1
4.1
0.3.1
4.1
0.31
11
13
MW-29d
15-Oct-15
0.2.1
40J
0.1.1
4.1
0.3.1
4.1
0.61
0.041
11
81
MW-29d
21-Apr-16
0.6J
40J
4.1
0.3.1
51
0.21
11
61
MW-29d
12-Sep-16
0.381
39J
2.7.1
3.118
0.251
0.901
4.81
22
MW-29d
19-Apr-17
36J
2.7.1
1.91
2.31
13
MW-29d
22-Sep-17
35J
3.9.1
2.81
5.91
MW-29d
12-Apr-18
34J
3.71
1.31
5.41
MW-29d
24-Oct-18
34J
3.21
3.3J
2.71
MW-29d
25-Apr-19
38J
3.3.1
MW-29d
5-Nov-19
33
3.41
3.91
0.361
0.092131
2.01
39B
MW-30
1-Nov-11
147
0.3021
47.5
8.80J
69.8E 3.901
22.21B
3.51J
0.196J
44
60.8
MW-30
25-Apr-12
169
0.7731
58
9.94J
73.9 9.171
22.71
2.15J
0.360J
51.7
54.7
MW-30
23-Oct-12
197
57.5
11.3
80.2 9.441
26.3
0.3591
54.4
62.6
MW-30
17-Apr-13
450
2.8
0.1J
124
24
155
0.041
56
11
146
141
MW-30
16-Oct-13
220
1.4
49
91
63 61
0.031
21J
0.31
50
40
MW-30
16-Apr-14
220
1.4
66
11
78 71
0.021
26J
0.51
73
71
MW-30
12-Nov-14
500
3.0
0.2J
148
24
169 M
0.071
59
2J
1.11
154
148
MW-30
29-Apr-15
180
1.2
59
91
67 61
23J
0.41
48
53
MW-30
15-Oct-15
0.41
60J
1.2
0.7J
48
11
12 21
0.051
10J
0.06J
63
44
MW-30
21-Apr-16
150
0.81
46
7J
54 51
0.021
18J
0.31B
29
38
MW-30
14-Sep-16
0.17JB
50J
0.36J
0.0531
8.8J
1.6J
11B 0.951
4.5J
111
18B
MW-30
20-Apr-17
79J
0.56J
25
3.1J
28 2.21
8.7J
0.14J
191
22
MW-30
22-Sep-17
NotSampled(4)
MW-30
12-Apr-18
Not Sampled(4)
MW-30
24-Oct-18
NotSampledl4J
MW-30
25-Apr-19
NotSampled(4)
MW-30
5-Nov-19
Not Sampled(4)
�m 1t�1 Page 6 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-31
1-Nov-11
84.21 0.1511 33.3 2.57J 23.9B 7.27J 13.7JB 2.661
0.129J 26.2 57.9
MW-31
25-Apr-12
33.41 0.1221 13.1 6.711 3.56J 5.401 0.904J
9.25J 33.1
MW-31
23-Oct-12
35.71 14 6.521 3.76J 5.09J
9.26J 53.6
MW-31
17-Apr-13
70J 0.41 24 11 14 71 0.031 81
0.051 181 29B
MW-31
16-Oct-13
30J 0.11 11 0.4J 51 21 5J
51 13B
MW-31
16-Apr-14
901 0.51 0.2J 32 2J 18 10 0.071 81
0.071 35 70
MW-31
12-Nov-14
0.51 110 0.71 41 2J 26 14 0.081 11J
0.11 37 29
MW-31
29-Apr-15
50J 0.21 14 0.6J 71 41 0.031 3J
13J 14
MW-31
14-Oct-15
0.51 120 0.61 38 2J 24 13 0.111 91
0.08J 37 37
MW-31
21-Apr-16
0.61 70J 0.51 30 2J 17 12 0.141 5J
0.07JB 26 17
MW-31
13-Sep-16
29J 0.231 13 0.64J 5.68 3.41 2.01
12J 12
MW-31
19-Apr-17
28J 8.1 3.9.1 1 1.8.1 2.6.1
5.2J 12
MW-31
21-Sep-17
Not Sampled(4)
MW-31
12-Apr-18
Not Sampled(4)
MW-31
24-Oct-18
Not Sampled(4)
MW-31
24-Apr-19
Not Sampled(4)
MW-31
5-Nov-19
Not Sampled (4)
MW-31d
31-Oct-11
1.211
21.2.1
34.2E
4.991B
10.2J
69.6
6.79.1
MW-31d
24-Apr-12
1.681
17.1.1
26.5
0.944J
7.62J
12.6
MW-31d
22-Oct-12
7.20J
19.3.1
8.24.1
1.82.1
7.99J
43.5
MW-31d
16-Apr-13
0.5J
20J
6.1
0.08J
0.8J13
11
6J
21B
MW-31d
15-Oct-13
0.8J
20J
6.1
0.06J
1.1
0.8.1
51
16B
MW-31d
15-Apr-14
0.7J
20J
5.1
0.09J
0.8.1
0.9.1
91
24B
MW-31d
11-Nov-14
0.51
20J
6.1
0.08J
0.8.1
0.7.1
21
71
MW-31d
28-Apr-15
20J
6.1
0.07J
0.9.1
0.8.1
51
24
MW-31d
13-Oct-15
20J
0.3.1
6.1
0.05J
3.1
0.2J
0.04J
11
4J
30
MW-31d
21-Apr-16
20J
4.1
0.7.1
0.9.1
2J
5.1
MW-31d
13-Sep-16
0.59J
18.1
0.14J
5.3.1
1.5J13
1.2.1
7.2J
56
MW-31d
19-Apr-17
18.1
5.4.1
2.6.1
6.6J
53
MW-31d
18-Sep-17
19J
4.4.1
1.0.1
7.8J
2.61
MW-31d
13-Apr-18
0.51J
18.1
5.3.1
4.6J
25
MW-31d (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4.3J
NA
MW-31d
24-Oct-18
21J
6.6.1
0.281
1.81
9.91
4.01
MW-31d
24-Apr-19
21J
4.2.1
7.8J
MW-31d
5-Nov-19
0.63J
17
0.211
4.1J
1.6J
0.092J
6.3
84B
MW-32
1-Nov-11
5.75J
14.2.1
3.41.1
1.47J
10.0E
3.391
2.96J
27.7
MW-32
25-Apr-12
0.393J
3.37J
15.4.1
0.261.1
1.92.1
2.34J
8.49.1
1.961
5.711
6.221
MW-32
23-Oct-12
30J
6.71.1
3.30J
27.2
5.041
11.8J
13.1
MW-32
17-Apr-13
30J
0.31
51
3J
22
0.5J
51
91
8JB
MW-32
16-Oct-13
70J
0.61
0.31
11
6J
50
0.9J
101
0.11
32
25
MW-32
16-Apr-14
20J
0.31
2J
2J
8.1
0.2J
21
7J
10B
MW-32
12-Nov-14
50J
0.5J
11
Si
37
0.91
91
0.11
151
18
MW-32
29-Apr-15
0.6J
140
1.6
0.1J
27
18
131
31
24J
0.3J
77
58
MW-32
14-Oct-15
170
1.4
O.1J
29
18
135
21
0.041
25J
0.3J
91
53
MW-32
21-Apr-16
40J
0.51
6J
Si
28
O.SJ
61
0.08JB
17J
18
MW-32
13-Sep-16
40J
0.631
0.201
8.51
5.61
27B
0.75J
7.2J
0.086J
181
19
MW-32
20-Apr-17
11J
0.30J
1.61
0.90J
5.11
1.4J
2.7J
3.51
MW-32
22-Sep-17
0.66J
14J
0.17J
1.61
1.31
1.1
4.01
MW-32
13-Apr-18
8.5J
0.301
1.51
2.71
MW-32
25-Oct-18
13J
0.26J
1.81
1.6J
2.51
MW-32 (dissolved)
25-Oct-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-32
25-Apr-19
26J
0.331
0.301
2.61
9.51
5.OJ
27
MW-32 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-32
7-Nov-19
13
0.21J
3.61
0.28
2.2J
3.01
MW-32 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
NA
NA
I NA
NA
NA
NA
NA
NA
NA
NA
Smith Page 7 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
TB-1a
1-Nov-11
126
5.39
19.1
11.5
99.3E
19.01
40.5
91.8
TB -la
25-Apr-12
0.269J
190
1.5
29
22
158 7.33J
0.348
27.9J
0.186J
61.3
89.4
TB -la
23-Oct-12
85.4.1
0.584.1
11.3
14.8
59.6 2.35J
13.3J
25
48.2
TB -la
17-Apr-13
40J
0.061
0.31
51
91
24 0.9J
0.1J
6J
91
11B
TB -la
16-Oct-13
60J
0.081
0.31
61
10
35 1.1
0.12.1
91
14J
14B
TB -la
16-Apr-14
10J
1.2
0.71
51
3.1 0.3J
0.13.1
3J
51
16B
TB -la
12-Nov-14
80J
0.2.1
ME.7
301
91
54 2.1
0.34
12J
0.081
191
41
TB -la
29-Apr-15
0.6J
30J
0.061
1.9
4J
51
18 1.1
0.22
6J
6J
17
TB -la
15-Oct-15
70J
0.11
=
81
11
40 2.1
0.22
13J
17JB
45
TB -la
21-Apr-16
50J
0.71
61
6J
33 1.1
0.22
7J
0.06JB
6J
18
TB -la
14-Sep-16
0.17JB
99.1
0.231
1.7
11
72B 3.5.1
0.7213
15J
0.111
29
49B
TB -la
20-Apr-17
17J
0.371
1.OJ
3.6.1
0.0501
1.91
5.11
5.5.1
TB -la
22-Sep-17
Not Sampled')
TB -la
12-Apr-18
Not Sampled')
TB -la
24-Oct-18
Not Sampled')
TB -la
24-Apr-19
Not Sampled')
TB -la
5-Nov-19
Not Sampled(')
TB -la deep
31-Oct-11
0.8651
14.21
22.9
4.52.113
6.601E
1.13.1
7.66J
13.2
TB-1a deep
24-Apr-12
0.9281
15.51
15
11.5
3.87J
1.23.1
6.58J
8.41.1
TB-1a deep
23-Oct-12
18.01
14.9
6.85.1
8.29J
6.51J
10.4
TB-1a deep
16-Apr-13
2.3J
20J
0.21
12
0.91
8.1
0.5.1
51
21
16B
TB-1a deep
15-Oct-13
2.2J
1
20J
0.11
6.1
6.1
5.1
4J
3J
9J13
TB-1a deep
15-Apr-14
2.1J
20J
0.11
71
0.81
5.1
0.4.1
3J
81
17B
TB-1a deep
11-Nov-14
2.9J
30J
0.11
71
11
5.1
0.5.1
4J
18
TB-1a deep
28-Apr-15
2.4J
30J
0.11
71
0.81
41
0.41
5J
21
12
TB-1a deep
14-Oct-15
101
41
0.041
11
TB-1a deep
20-Apr-16
0.4J
20J
41
0.71
21
0.21
3J
61
TB-1a deep
13-Sep-16
0.66J
22J
0.0701
3.11
0.461
1.718
0.26J
3.21
6.4J
12
TB-1a deep
19-Apr-17
0.74J
25J
3.21
3.01
3.31
3.9J
13
TB-1a deep
22-Sep-17
0.761
15J
3.41
3.41
6.8J
TB-1a deep
13-Apr-18
13J
3.11
1.41
0.28J
13
TB-1a deep
24-Oct-18
13J
5.21
1.61
6.5J
TB-1a deep
24-Apr-19
13J
29
15J
3.9J
TB-1a deep
5-Nov-19
23
0.66
2.41
5.0
0.64J
2.81
4.1J
38B
MW-33
25-Apr-12
112
0.2081
44.4
15.1
37
6.441
20.2J
0.917J
72.1
102
MW-33
17-Apr-13
70J
0.31
17
5J
13
21
7J
34
33
M W-33
15-Apr-14
40J
51
0.61
11
2J
81
9.113
MW-33
29-Apr-15
50J
0.071
71
11
31
0.41
1
8J
15
MW-33
21-Apr-16
0.5J
100J
0.11
M7
4J
12
21
7J
21J
35
MW-33
20-Apr-17
29J
5.1J
1.51
5.91
7.41
MW-33
13-Apr-18
28J
5.3J
3.3J
6.31
MW-33
24-Apr-19
59J
4.3J
1.61
1.71
4.OJ
4.81
MW-34
26-Apr-12
0.2611
184
1.27
25.4
4.771
23.8E
8.31
0.255
13.21
37.4
53.7
MW-34
17-Apr-13
560
0.3J
75
17
90
=
0.45
49J
0.3J
239
282
=
MW-34
15-Apr-14
110
0.3J
0.21
3J
11
0.81
0.25
21
3J
16B
MW-34
29-Apr-15
220
1.5
0.21
24
Si
24
51
0.33
15J
0.11
47
76
91
MW-34
21-Apr-16
150
0.5J
21
51
0.81
0.171
51
0.08JB
21
32
MW-34
20-Apr-17
84J
0.29J
4.41
1.41
0.25
2.OJ
1.51
13
MW-34
13-Apr-18
130
0.63J
8.61
1.81
6.81
1.21
1.1
5.2J
7.1J
21
MW-34 (dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
25-Apr-19
170
0.62J
0.21J
14
2.51
10
1.91
0.30
6.9J
14J
30
MW-34 (dissolved)
25-Apr-19
NA
NA
NA
NA
NA
2.01
1.71
NA
NA
NA
NA
NA
NA
NA
NA
MW-34
7-Nov-19
190
1.7
0.966
31
4.01
26
5.0
16
1.51
37
49
MW-34 (dissolved)
7-Nov-19
NA
NA
NA
NA
NA
4.2J
NA
NA
0.49
NA
NA
NA
NA
�m 1t�1 Page 8 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
MW-34d
16-Mar-11
25-Apr-12
16-Apr-13
15-Apr-14
28-Apr-15
21-Apr-16
20-Apr-17
11-Apr-18
23-Apr-19
6-Nov-19
0.351J
0.575J
0.6J
0.4J
0.8J
0.5J
33.2J
32.5J
20J
20J
20J
180
20J
20J
21J
25
0.1J
0.1J
0.1J
0.8J
0.14J
0.15J
0.1
0.2J
0.1
0.1J
1.8
9.87J
8.02J
4J
4J
5J
15
6.4J
12
6.5J
8.7
0.11
0.091
O.OBJ
3J
8.59J
5.86JB
1JB
2J
1J
12
4.3J
2.06J
2.66J
0.6J
0.5J
0.5J
2J
0.90J
0.05J
0.191
0.073J
0.46
0.20E
0.7J
0.5J
8J
1.4J
0.946J
1J
0.209J
O.1J6
1.83J
1.57J
4J
12J
2.111
11.2
7.83J
2JB
11B
6J
35
3.OJ
19
MW-35
25-Apr-12
51.3J
0.616J
3.96J
2.36J
5.67J
3.10J
11.3J
17.8
MW-35
17-Apr-13
60J
0.8J
0.1J
5J
21
7J
2J
41
161
12B
MW-35
16-Apr-14
60J
1.OJ
0.1
6J
3J
8J
2J
4J
22J
26B
MW-35
29-Apr-15
70J
1.0
0.11
7J
4J
91
2J
0.02J
5J
0.061
22J
20
MW-35
20-Apr-16
50J
0.7J
4J
2J
5J
11
3J
111
12
MW-35
20-Apr-17
38J
0.39J
2.3J
6.5J
2.4J
5.OJ
3.7J
3.9J
66
MW-35
13-Apr-18
29J
0.28J
0.24J
1.5J
3.3J
0.48J
32
MW-35
24-Apr-19
38J
0.41J
2.1J
1.6J
1.6J
0.38J
1.31
3.1J
14
MW-36
1-Nov-11
74.6J
12.1
3.63J
14.7E
7.15JB
14.8J
31.8
MW-36
25-Apr-12
64.7J
7.901
2.61J
9.44J
4.33J
12.5J
12.1
MW-36
23-Oct-12
216
68.8
18.8
84
8.62J
29.31
0.420J
91.7
72
MW-36 (dup)
23-Oct-12
73.7J
11.6
3.49J
13.4
6.09J
0.1211
16.8J
18.4
MW-36
17-Apr-13
50J
0.11
61
2J
6J
0.5J
4J
81
12B
MW-36
16-Oct-13
0.6J
60J
0.2J
71
2J
81
0.6J
4J
0.051
301
4JB
MW-36
16-Apr-14
901
0.1
19
51
23
2J
91
0.11
33
32B
MW-36
12-Nov-14
130
0.6J
32
91
39
3J
15J
OX
40
46
MW-36
30-Apr-15
0.6J
1001
0.1
24
71
27
2J
0.02J
11J
OX
29
27
MW-36
15-Oct-15
130
0.7J
38
10
46
3J
0.05J
16J
0.3J
37
41
MW-36
20-Apr-16
70J
0.1
13
3J
15
11
6J
0.11
111
17
MW-36
13-Sep-16
62J
0.24J
0.047J
11
3.OJ
106
0.88J
5.31
0.088J
14J
16
MW-36
20-Apr-17
40J
2.8J
2.9J
1.8J
4.4J
11
MW-36
22-Sep-17
70J
0.32J
16
3.3J
18
1.3J
6.6J
20J
16
MW-36(dissolved)
22-Sep-17
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
4.9J
NA
MW-36
13-Apr-18
54J
0.29J
5.4J
3.3J
0.75J
1.8J
3.2J
4.OJ
MW-36(dissolved)
13-Apr-18
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
25-Oct-18
80J
0.20J
27
4.8J
20
1.6J
12J
25
25
MW-36(dissolved)
25-Oct-18
NA
NA
NA
NA
NA
2.3J
NA
NA
NA
NA
NA
NA
NA
NA
MW-36
25-Apr-19
180
0.33J
57
11
55
4.3J
18J
0.31J
55
59
MW-36(dissolved)
25-Apr-19
NA
NA
NA
NA
NA
3.8J
NA
NA
NA
NA
NA
NA
NA
MW-36
7-Nov-19
81
0.40
21
4.5J
23
1.5
0.21
8.2
0.17BJ
23
25
CMti1 Page 9 of 20 December 2019

Table 4a
Detected Groundwater Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes:
1. All units are in micrograms per liter (parts per billion).
2."- Interim Maximum Allowable Concentration (IMAC)
3. dup - Duplicate Sample
4. (4) - Monitoring wells MW-22, -24, -30, -31, and TB-1a were not sampled during the April 2019 sampling events due to insufficient volumes of water in the wells.
5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
6. B - The analyte concentration detected in the method blank was greater than the method detection limit.
7. Monitoring wells MW-28, -28d, -33, -34, -34d, and -35 are sampled yearly during the spring event.
8. Dissolved metal samples were collected to evaluate the influence of turbidity on total metal concentrations as part of an ongoing Alternate Source Demonstration.
9. NA - Not Analyzed
11- Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or IMAC Standard.
Indicates the result is below the detection limit.
�m 1t�1 Page 10 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
=1 I
I-Nov-11
NEW
ME
MW-11
MW-11
25-Apr-12
MW-11
23-OU-12
MW-11
17-Apr-13
MW-11
I6-OU-13
MW-11
16-Apr-14
MW-11
12-Nov-14
MW-11
30-Apr-15
0.541
MW-11
15-Od-15
0.28JB
MW-11
21-Apr-16
MW-11
1-Sep-16
MW-11
20-Apr-17
MW-11
22-Sep-17
MW-11
13-Apr-18 2.11
MW-11
25-OU-18
MW-11
25-Apr-19
MW-11
5-Nov-19
MW-lid
2-Nov-11
MW-lid
26-Apr-12
MW-lid
24-OC-12
MW-lid
18-Apr-13
MW-lld
17-OC-13
MW-lid
17-Apr-14
MW-lid
13-Nov-14
MW-lid
29-Apr-15
MW-lid
15-OC-15
0.24JB
MW-lid
21-Apr-16
1.3J
0.71J
MW-lid
1-5ep-16
MW-lid
20-Apr-17
MW-lid
22-5ep-17
MW-lid
12-Apr-18
MW-lid
23-OC-18
MW-lid
25-Apr-19
MW-lid
5-Nov-19
--
MW-lid du
5-Nov-19
MW-5R
16-Mar-11
2.1
MW-SR
31-Od-11
MW-SR
24-Apr-12
MW-SR
22-Od-12
0.671
MW-5R
17-Apr-13
0.221
MW-5R
16-Oc-13
MW-5R
16-Apr-14
MW-5R
12-Nov-14
MW-5R
30-Apr-15
MW-5R
15-0c45
0.49J
0.34JB
MW-SR
21-Apr-16
MW-SR
14-Sep-16
MW-SR
20-Apr-17
MW-SR
20-Sep-17
5.01
2.7
3.4
1.11
15
0.61J
0.721
4.8
MW-5R
11-Apr-18
MW-5R
24-O' 8
0.41J
MW-5R
22-Apr-19
0.75
0.54
2.5
0.51
52
0.4.
0.54
MW-5R
6--19
Nov
0.61
0.62
MW-6
1-Nov-11
3.6
1.11
1.7
1.01
0.951
MW-6
24-Apr-12
0.7J
O.S1
0.51
0.421
O.S61
MW-6
22-OU-12
4.61
2.3
1.71
1.3
2.51
0.581
2.4
MW-6
17-Apr-13
0.79J
1.7J
0.431
MW-6
JIZ-13
0.481
3.01
0.60J
0.571
MW-6 (dup)
16-Oc -13
8.21
0.541
3.OJ
0.551
0.54J
M W-6
16-Apr-14
0.521
0.971
MW-6 (dup)
16-Apr-14
0.501
1.01
MW-6
12-Nov-14
1.1
0.251
1.21
1.3
0.801
MW-6
30-Apr-15
0.481
0.601
1.2J
MW-6
14-0pb15
2.31
0.501
MW-6
20-Apr-16
221
OA51
0.52)
3.01
MW-6(dup)
20-Apr-16
0.381
0.581
MW-6
14-Sep-16
0.831
1.51
MW-6
20-Apr-17
0.821
0.981
MW-6 (dup)
20-Apr-17
0.901
1.21
MW-6
21-Sep-17
0.831
2.81
0.611
0.561
M W-6
12-Apr-18
0.691
0.841
MW-6
24-Od-I8
0.61
1.3
2.2
0.56
26
0.471
MW-6
22-Apr-19
4.9
MW-6
6-Nov-19
1.3
1.8
1
1
1 24
MW-6d
2-Nov-11
0.72)
I.SJ
34
0.43J
MW-6d
26-Apr-12
0.611
0.531
2.31
0.401
0.421
MW-6d(dup)
26-Apr-12
0.58)
2.31
0.43J
MW-6d
23-OC-12
0.77J
1.11
3.01
0.541
0.481
0.531
0.52J
MW-6d
18-Apr-13
0.52)
2.31
0.48J
0.3J
0.391
MW-6d(dup)
18-Apr-13
0.5"
2.41
0.471
0.39J
0.44J
0.361
MW-6d
17-Oct-13
0.75)
I.SJ
3.3)
0.65J
0.531
MW-6d
17-Apr-14
0.421
0.931
0.281
MW-6d
12-Nov-14
0.511
1.51
0.391
MW-6d
30-Apr-15
0.30J
0.501
0.871
1.5JB
0.221
MW-6d (dup)
30-Apr-15
0.401
0.831
1.51E
MW-6d
IS-Oc[-15
0.351
0.371
0.821
0.251B
MW-6d
20-Apr-16
0.51)
2.OJ
0.351E
MW-6d
12 Sep-16
0.41J
1.01
MW-6d
20-Apr-17
0.51J
0.43J
1.51
0.51J
1.6J
MW-6d
22-Sep-17
0.601
0.711
1.91
0.491
MW-6d
13-Apr-18
0.81J
MW-6d
24-Op[-18
0.99
MW-6d
23-Apr-19
0.97
MW-6d
6-Nov-19
0.50
1.1
Smith Page 11 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-7
2-Nov-11
7.61 1.3 1.6
1.4
MW-7
26-Apr-12
120 0.661 0.791
0.491
MW-7
22-OU-12
15 0.75J 1.4
0.93
MW-7
16-Apr-13
0.66J 0.25J 1.2 1.21
MW-7
I6-OU-13
0.811 0.401 1.5
MW-7
16-Apr-14
0.611 0.52J 1.2
0.311
MW-7
11-Nov-14
0.70) 0.571 0.561 1.2
0.321
0.80J
MW-7
30-Apr-15
1.1 0.69J 2.7 2.81 0.511
0.591 1.5JB
0.851
MW-7
14-0c-15
0.521 0.691 1.1
MW-7
20-Apr-16
0.831 0.52J 2.2
0.461 1.61
1.5
MW-7
13-Sep-16
1.0 1.31 1.6 0.421
0.411
0.60J
MW-7
18-Apr-17
0.74J 1.11 1.4
MW-7
18-Sep-17
0.551 0.941 0.731
MW-7
11-Apr-18
0.561 0.511
MW-7
25-OU-18
0.66
MW-7
24-Apr-19
0.48J 1.0
MW-7
4-Nov-19
0.411 0.83 0.77
MW-8
31-OC-11
0.661
14
MW-8
24-Apr-12
0.751
23
MW-8
22-OC-12
0.47J
0.401
1.11
25
0.651
0.41J
MW-8
17-Apr-13
0.511
0.231
0.531
0.771
35
0.321
0.471
MW-8
16-OC-13
0.481
0.17J
0.471
0.621
37
MW-8
16-Apr-14
0.471
0.671
0.581
39
0.401
MW-8
12-Nov-14
O.SOJ
0.181
0.2
0.641
48
0.321
MW-8
30-Apr-15
0.841
0.351
1.1
0.941
98
1.61B
0.291
0.641
0.401
MW-8
15-025
0.561
0.27J
1.0
0.551
64
0.441B
0.541
MW-8
21-Apr-I6
0.70J
0.361
1.4
0.741
0.251
0.451
MW-8
14-Sep-16
0.53J
1"
0.711
61
0.72J
MW-8
20-Apr-17
0.491
1.2
0.501
48
0.611
0.571
MW-8
18-Sep-17
0.541
1.4
0.441
46
0.521
MW-8
12-Apr-18
0.621
1.6
0.431
42
0.411
1.8
MW-8
24-OC-18
0.56
1.6
33
5.8
MW-8
22-APr-19
8.3
MW-8(dup)
22-Apr-19
8.4
MW-8
6-Nov-19
0.471
1.4
24
4.1
MW-ed
2-Nov-11
MW-8d
26-Apr-12
0.42J
MW-ed
24-OC-12
O.SL
MW-8d
18-Apr-13
0.361
MW-ed
17-Ocb13
0.43J
MW-8d
17-Apr-14
MW-ed
12-Nov-14
MW-8d
30-Apr-15
0.381
MW-ed
15-Oc[-15
0.441
MW-8d
21-Apr-16
0.60J
MW-8d
14- Sep-16
0.481
MW-8d
20-Apr-17
0.501
MW-8d
18-Sep-17
MW-8d (dup)
18-Sep-17
MW-ed
12-Apr-18
MW-8d
23-Oct-18
MW-8d(dup)
23-OU-18
MW-8d
23-Apr-19
MW-8d
6-Nov-19
MW-9
1-Nov-11
1.3
5.9
11
12
MW-9 (dup)
1-Nov-11
6.11
1.0
1.3J
5.9
12
10
MW-9
25-Apr-12
1.8
8.1
15
0.681
0.54J
0.47J
19
MW-9
23-OU-12
2.01
3.31
MW-9
17-Apr-13
1.31
2.11
MW-9
16-OU-13
2.01
4.21
MW-9
16-Apr-14
0.371
0.251
2.81
6.4
0.361
MW-9
12-No114
2.31
0.251
5.3
MW-9 (dup)
12-Nov-14
2.11
4.61
MW-9
29-Apr-15
2.11
5.9
MW-9
15-Oct-15
OA2)
2.91
8.6
0.251
028JB
MW-9
20-Apr-16
0.291
2.5J
0.271
5.7
wo
MW-9
13-Sep-16
2.71
8.6
MW-9
19-Apr-17
2.31
7.2
MW-9
21-Sep-17
1.81
6.2
MW-9
11-Apr-18
8.11
1.61
3.41
MW-9
25-Oct-18
0.63
2.1
2.1J
MW-9
25-Apr-19
2.1
2.7
4.7
12
0.42J
5.2
MW-9
5-Nov-19
0.72
4.5
4.0
12
2.81
9.9
MW-30
31-OC-11
3.2
1.41
0.901
4.91
42
2.9
2.6
1.3
MW-10
25-Apr-12
101
2.3
1
3.2J
44
2.9
2.5
1.4
MW-30
23-OC-12
3.3
1.81
1.3
5.3
52
0.411
2.3
2.6
3.1
MW-10
17-Apr-13
3.2
0.231
2.3
6.3
0.231
39
0.21J
0.261
4.7
6.1
0.181
MW-30
16-OC-13
1.1
0.171
2.4
4.01
23
2.1
3.0
0.761
MW-10
16-Apr-14
1.4
0.681
2.0
2.91
24
2.6
2.5
0.161
MW-30
12-Nov-14
1.5
1.01
2.4
4.61
0.241
39
0.271
10
12
3.9
MW-10
29-Apr-15
2.6
0.29J
2.6
24
29
2.5
3.7
1.5
MW-30
14-Oct-I5
1.2
0.361
4.4
3.41
0.341
29
0.211
3.0
3.3
MW-10
20-Apr-16
2.9
24
1.71
0.311
18
0.37JB
2.2
3.4
2.0
0.23J
MW-30
13-Sep-16
2.9
4.5
2.71
25
1.6
1.3
MW-10
19-Apr-17
1.5
0.501
0.561
3.51
0.501
22
0.561
4.9
1.9
MW-30
22-Sep-17
0.951
4.6
2.61
0.421
7.1
1.0
3A
MW-10
11-Apr-18
151
0.491
2.91
1.71
3.41
0.581
1.6
MW-30
25-OC-18
0.75
4.0
1.9
4.1
0.69
1.7
0.85
MW-10
25-Apr-19
2.11
1.7
1.7
0.89
8.0
0.93
0.67
0.811
MW-10
5-Nov-19
0.77
1.5
0.89
4.1
0.96
Smith Page 12 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
2-Nov-11
2.21
0.921
MW-10d
MW-10d
26-Apr-12
0.70J
2.21
0.61
0.52J 0.501
MW-10d
24-Oct-12
0.551
2.31
0.471
0.641 0.671 0.451
MW_I0d
18-Apr-13
2J
0.62J
0.57J 0.641 0.36J
MW-10d
I6-Oct-13
1.81
0.561
0.571
MW-lOd
17-Apr-14
1.81
0.541
0.42J
MW-IOd
12-Nov-14
2.01
0.681
0.251
0.24J
MW-lOd
30-Apr-15 0.56J
0.45J
1.7J
0.561
1.91B O.61J
MW-IOd
15-0ct-15
0.461
1.41
0.451
0.551B 0.421 0.381
MW-lOd
21-Apr-16
0.51J
1.4J
0.391
0.39J
MW-IOd
14-Sep-16
1.51
0.491
MW_10d
19-Apr-17
0.59J
1.31
0.45J
0.47J
MW-10d
18-Sep-17
1.11
MW-10d
11-Apr-18
0.48HJ
1.2J
0.41J
0.42J
MW-IOd
25-OU-18
1.2
0.45J
MW-10d
25-Apr-19
0.98
MW-10d
5-Nov-19
1.1
MW-22
1-Nov-11
MW-22
25-Apr-12
MW-22
23-OC-12
MW-22
17-Apr-13
MW-22
16-OC-13
MW-22
16-Apr-14
MW-22
12-Nov-14
5.9J
MW-22
30-Apr-15
0.431
MW-22
15-OC-15
MW-22
20-Apr-16
0.801
MW-22
13-Sep-16
M W-22
19-A17
Not sampled"°
M W-22
13-Appr-r-18
Not sampledM
MW-22
23-Oct-18
Not sampled"4"
MW-22
23-Apr-19
Not sampled"4"
MW-22
4-Nov-19
Not samt,1441
MW-23
2-Nov-11
MW-23
23-Apr-12
MW-23
24-OC-12
MW-23
18-Apr-13
MW-23
16-OC-13
MW-23
16-Apr-14
MW-23
12-Nov-14
MW-23
30-Apr-15
MW-23
15-OU-15
MW-23 (dup)
15-0ct-15
MW-23
20-Apr-16
0.721
MW-23
13-Sep-16
MW-23
19-Apr-17
MW-23
11-Apr-18
MW-23
25-0ct-18
MW-23
25-Apr-19
MW-23
5-Nov-19
MW-231
25-Apr-12
MW-23d
23-0ct-12
MW-23d
18-Apr-13
MW-23d
17-OU-13
MW-23d
17-Apr-14
MW-23d
13-Nov-14
MW-23d
29-Apr-15
MW-23d
15-OU-15
MW-23d
20-Apr-16
0.611
MW-23d
13-Sep-16
MW-23d(dup)
13-Sep-16
MW-23d
19-Apr-17
0.441
MW-23d
21-Sep-17
3.41
MW-23d
10- Apr-18
MW-23d(dup)
10-Apr-18
MW-23d
23-Oct-18
MW-23d
23-Apr-19
MW-23d
4-Nov-19
MW-24
2-Nov-11
8.9
MW-24
26-Apr-12
7.3
MW-24
23-Oct-12
8
M W-24
17-Apr-13
8.7
MW-24
16-Oct-13
7.9
M W-24
16-Apr-14
6.2
MW-24
12-Nov-14
5.9
MW-24
29-Apr-15
6.0
MW-24
14025
4.91
MW-24
20-Apr-16
4.71
0.461
MW-24
13-Sep-16
3.81
M W-24
19-Apr-17
4.31
MW-24
20-Sep-17
3.61
M W-24
11-Apr-18
3.21
MW-24
23-Oct-18
Notsaled"
mp
MW-24
24-Apr-19
Not lampled((4�
MW-24
4-Nov-19
Not sampled"4�
M W-28
18-Apr-13
0.581
M W-28
17-Apr-14
0.38)
MW-28
30-Apr-15
MW-28
21-Apr-16
MW-28
20-Apr-17
M W-28
13-Apr-18
0.54J
MW-28
25-A r-19
smith
DM Page 13 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
MW-28d
26-Apr-12
19)
MW-28d
18-Apr-13
MW-28d
17-Apr-14
MW-28d
30-Apr-15
0.291
MW-28d
21-Apr-16
MW-28d
20-Apr-17
MW-28d
13-Apr-I8
MW-28d
25-Apr-19
MW-29d
I-Nov-11
MW-29d
26-Apr-12
MW-29d
24-Oct-12
MW-29d
18-Apr-13
MW-29d
17-OU-13
MW-29d
17-Apr-14
28.5
MW-29d
13-Nov-14
0.231
4.61)
MW-29d
29-Apr-15
6.71
MW-29d
15-Oct-15
0.291B
0.251
MW-29d
21-Apr-16
MW-29d
12- Sep- I6
MW-29d
19-Apr-17
MW-29d
22-Sep-17
MW-29d
12-Apr-18
0.511
MW-29d
24-Oct-18
0.411
MW-29d
25-Apr-19
MW-29d
5-Nov-19
MW-30
1-Nov-11
MW-30
25-Apr-12
MW-30
23-Ocb12
MW-30
17-Apr-13
MW-30
16-Ocb13
MW-30
16-Apr-14
MW-30
12-Nov-14
MW-30
29-Apr-15
MW-30
15-025
MW-30
21-Apr-16
MW-30
14- Sop-16
MW-30
20-Apr-17
MW-30
22-5ep-17
Notsampled�4.
M W-30
12-Apr-18
No,sampledl4,
MW-30
24-Ocb18
Not sampled.
MW-30
25-Feb-19
Not sampled14'
MW-30
5-Nov-19
Not sampled'
MW-31
I-Nov-11
2.11
M W-31
25-Apr-12
1.31
MW-31
23-0ct-12
2.01
M W-31
17-Apr-13
1.41
MW-31
16-0ct-13
1.41
M W-31
16-Apr-14
1.61
MW-31
12-Nov-14
1.01
M W-31
29-Apr-15
1.61
MW-31
14-Oct-I5
0.821
M W-31
21-Apr-16
2.11
MW-31
13-Sep-16
0.761
M W-31
19-Apr-17
0.411
M W-31
21- Sep- 17
Not sampled'4
M W-31
12-Apr-18
Not sampled
M W-31
24-0ct-18
Not sampl:d14�
M W-31
24-Apr-19
Not sampld141
MW-31
4-Nov-19
Not sam ledl41
MW-31d
31-OU-11
23
MW-31d
24-Apr-12
23
MW-31d
22-OU-12
22
MW-31d
16-Apr-13
21
MW-31d
15-0ct-13
17
MW-31d
15-Apr-14
17
MW-31d
11-Nov-14
17
MW-31d
28-Apr-15
16
MW-31d
13-Oct-I5
12
MW-31d
21-Apr-16
13
MW-31d
13-Set, 6
10
MW-33d
19-Apr-17
13
MW-31d
18-Sep-17
12
MW-33d
13-Apr-18
9.2
MW-31d
24-OC-I8
9.4
MW-31d
24-Apr-19
6.8
MW-31d
5-Nov-19
6.3
MW-32
I-Nov-11
MW-32
25-Apr-12
MW-32
23-Oct-12
MW-32
17-Apr-13
MW-32
16-Oct-13
MW-32
16-Apr-14
MW-32
12-Nov-14
MW-32
29-Apr-15
0.411
MW-32
140ct-15
MW-32
21-Apr-16
MW-32
13-Sep-16
MW-32
20-Apr-17
MW-32
22-Sep-17
MW-32
13-Apr-I8
MW-32
25-Oct-18
MW-32
25-Apr-19
MW-32
7-Nov-19
0.64
Smith Page 14 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
I-Nov-11 1.61
TB -la
TB -la
25-Apr-12 0.91
TB -la
23-OU-12 0.74J
TB -la
17-Apr-13 0.70J
TB -la
I6-Oet-13 0.35J
TB -la
16-Apr-14 0.45J 0.321
TB -la
12-Nov-14 0.60J
TB -la
29-Apr-15 1.51
TB -la
15-0ct-I5 0.45J 0.27JB
TB -la
21-Apr-16
TB -la
14-Sep-16 0.651
TB -la
20-Apr-17 0.42)
TB -la
22-Sep-17 Not sampled(°
TB la
12-Apr-18 Not sampled"
TB -la
24-OU-18 Not sampled(41
TB -la
24-Apr-19 Not sampled(41
TB -la
5-Nov-19 Not sam led(4'
TB- lad eep
31-OC-11
31
TB-ladeep
24-Apr-12
23
TB- lad eep
23-OC-12
22
TB - la deep
16-Apr-13
20
TB-ladeep
15-OC-13
16
TB -la deep
15-Apr-14
13
TB-ladeep
11-Nov-14
10
TB -la deep
28-Apr-15
8.9
0.421
TB -la deep
140c[-15
4.91
TB -la deep
20-Apr-16
2.61
0.411
TB -la deep
13-Sep-16
2.61
TB -la deep
19-Apr-17
2.7J
1.41
TB -la deep
22-Sep-17
1.91
TB -la deep
13-Apr-18
1.3J
TB -la deep
24-OU-18
0.85
TB -la deep
24-Apr-19
0.56
TB-ladeep
5-Nov-19
0.65
MW-34
17-Mar-11
0.891
10
11
11
2.2
3.4
MW-34
26-Apr-12
0.601
0.62J
0.60J
1.1
1.81
14
9
7.6
2.2
3.3
0.921
MW-34
17-Apr-13
0.56J
0.601
0.521
1.1
1.81
13
9.1
7.6
2.1
2.6
0.701
0.191
MW-34
15-Apr-14
0.501
0.99J
0.41J
1.0
1.41
14
7.5
4.11
1.0
2.2
0.591
MW-34
29-Apr-15
0.85J
0.351
0.511
0.651
1.5
1.71
18
0.341
10
7.2
1.3
3.0
0.641
1.71
MW-34
21-Apr-16
0.77J
0.71J
1.9
2.01
17
0.301
11
6.4
2.3
1.01
MW-34
20-Apr-17
0.75J
0.65J
1.4
2.61
13
0.51J
12
9.3
2.4
2.9
1.2
MW-34
13-Apr-18
0.57J
0.44J
2.11
8.2
12
9.7
1.8
2.1
0.771
MW-34
25-Apr-19
0.65
0.56
1.4
2
8.2
7.1
1.4
0.71
MW-34
6-Nov-19
0.421
0.61
1.1
1.4
7.7
6.6
1.3
1.6
0.72
MW-34d
16-Mar-11
1.71
1.61
0.43J
MW-34d
25-Apr-12
0.771
0.931
MW-34d
16-Apr-13
0.831
1.11
MW-34d
15-Apr-14
0.461
0.991
3.41
2.71
0.961
0.581
0.761
0.751
MW-34d
28-Apr-15
0.27J
0.42J
0.651
0.70J
3.11
2.31
2.1J
0.541
0.67J
0.381
MW-34d
21-Apr-16
0.79J
0.661
2.0
2.11
0.331
10
.1
2.3
1.1
MW-34d
20-Apr-17
0.49J
I.01
3.11
2.91
0.78J
0.721
0.85J
0.591
MW-34d
11-Apr-18
1.71
1.41
0.571
MW-34d
23-Apr-19
2.0
1.9
0.80
0.411
0.52
MW-34d
6-Nov-19
0.401
0.75
2.9
2.4
0.93
0.481
0.55
MW-35
25-Apr-12
MW-35
17-Apr-13
0.531
MW-35
16-Apr-14
0.251
MW-35
29-Apr-15
0.441
0.621
0.271
MW-35
20-Apr-16
0.891
0.391
0.411
MW-35
20-Apr-17
1.61
0.621
0.611
1.2
MW-35
13-Apr-18
2.21
1.0J
0.961
0.81
MW-35
24-Apr-19
0.55
0.54
0.56
MW-36
1-Nov-11
0.86J
4.31
1.1
MW-36
25-Apr-12
5.5
3.31
0.741
MW-36
23-Oct-12
5
2.91
0.66J
MW-36(dup)
23-Oet-12
5.4
2.81
0.671
MW-36
18-Apr-13
0.18)
3.71
2.31
0.421
MW-36
I6-OC-13
3.81
2.51
MW-36
16-Apr-14
3.11
2.1J
0.26J
0.371
MW-36
12-Nov-14
3.51
2.51
MW-36
30-Apr-15
0.46J
2.8)
2.31
0.231
MW-36
15-OC-15
2.41
2.11
0.371E
0.251
MW-36
20-Apr-16
1.81
2.1J
MW-36
13-Sep-16
4.51
4.31
MW-36
20-Apr-17
2.4
2.6J
MW-36
22-Set, 7
2.41
3.11
MW-36
13-Apr-18
3.21
1.6)
2.1J
MW-36
25-OC-I8
1.8
3.2
MW-36
25-Apr-19
1.4
2.8
MW-36
5-Nov-19
1.5
2.8
smith
DM Page 15 of 20 December 2019

Table 4b
Detected Groundwater Constituents - Volatile and Semi -Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes.
1. All units are in micrograms per liter (parts per billion).
2.' -inter! Maximum Allowable Concentration (I MAC)
3. NS -Not Sampled; NE -Standard Not Established; dup -Duplicate Sample
4 Inl -Monitoring wells MW-22, -24, -30, -31, and TB -la were not sampled during the April 2019 sampling event due to insufficient volumes of water in the wells.
5.1- Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
6. B-The analyte concentration detected in the method blank was greater than the method detection limit.
7. H - The analyte was out of holding time.
8. Monitoring wells M W-28, -28d, -33, -34, -34d, and -35 are sampled yearly during the spring event.
9. (--) - Not Analyzed. 1,4-Dioxane was removed from the sampling program for all wells on June 26, 2019, with the exceptions of MW-6, -8, and -9, due to two consecutive non -detect events.
Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or IMAC Standard
- Indicates the result is below the detection limits.
smith
DM Page 16 of 20 December 2019

Table 4c
Detected Surface Water Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
SW-2
1-Nov-11
77.1J
9.49J
5.46J
14.1E
4.12J
5.20BJ
2.35J
22.OJ
25.7
SW-2
26-Apr-12
33.6J
1.951
2.03J
SW-2
24-Oct-12
35J
SW-2
18-Apr-13
40J
0.5BJ
0.1J
1J
2BJ
SW-2
17-Oct-13
0.5J
40J
0.11
11
SW-2
16-Apr-14
0.7J
40J
0.81
0.2J
3J
0.4J
0.6J
5J
10BJ
SW-2
12-Nov-14
40J
0.4J
0.06J
0.7J
2BJ
SW-2
29-Apr-15
40J
0.6J
0.2J
1J
4J
SW-2
15-Oct-15
30J
0.2J
0.5J
0.7J
0.5J
0.07J
SW-2
21-Apr-16
0.6J
40J
0.6J
0.7J
SW-2
14-Sep-16
37J
1.1JB
0.15J
2.2J
4.9JB
SW-2
20-Apr-17
130
0.901
5.OJ
SW-2
21-Sep-17
35J
0.26J
1.6J
1.7J
6.1J
SW-2
13-Apr-18
36J
1.4J
2.6J
SW-2
24-Oct-18
34J
2.9J
SW-2
24-Apr-19
33J
1.3J
4.1J
SW-2
7-Nov-19
36
1.4J
5.6J
SW-3
1-Nov-11
33.4J
2.11J
5.21JB
2.22BJ
4.06J
6.46J
SW-3
26-Apr-12
29.35J
1.63J
2.37J
3.87J
4.22J
SW-3
24-Oct-12
31.3J
1.69J
SW-3
18-Apr-13
60J
0.11
3BJ
41
4J
1J
2J
2J
10BJ
SW-3
15-Oct-13
30J
26
0.2J
11
0.81
SW-3
15-Apr-14
0.91
20J
0.04J
2J
1.0J
7J
1J
11
91
12B
SW-3
11-Nov-14
30J
0.3J
0.05J
0.4J
0.81
SW-3
29-Apr-15
0.6J
30J
0.3J
0.11
0.5J
SW-3
14-Oct-15
40J
0.04J
11
0.91
11
0.5J
2J
3J
SW-3
21-Apr-16
30J
0.5J
0.11
0.5J
SW-3
12-Sep-16
0.26J
49J
1.3J
3.1J
2.9JB
1.11
1.11
6.9J
12
SW-3
20-Apr-17
40J
1.7J
0.43J
3.3J
4.7J
SW-3
20-Sep-17
30J
0.26J
1.2J
1.5J
6.9J
SW-3
13-Apr-18
31J
1.3J
SW-3
24-Oct-18
32J
3.1J
SW-3
24-Apr-19
33J
SW-3
7-Nov-19
35
0.29J
0.095BJ
3.6J
�m lti1 Page 17 of 20 December 2019

Table 4c
Detected Surface Water Constituents - Metals
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes:
1. All units are in micrograms per liter (parts per billion).
2. Izl - A Standard for total chromium has not been established. The value provided is for chromium (III).
3. NS - No Standard
4. * - North Carolina In -Stream Target Value
5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
6. B - The analyte concentration detected in the method blank was greater than the method detection limit.
Concentration exceeds the North Carolina 15A NCAC 02B or In -Stream Target Value Freshwater Aquatic Life Standard for Class C Waters -
June 2019
Indicates the result is below the detection limit.
�m lti1 Page 18 of 20 December 2019

Table 4d
Detected Surface Water Constituents - Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Smith Page 19 of 20 December 2019

Table 4d
Detected Surface Water Constituents - Volatile Organic Compounds
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Notes.
1. All units are in micrograms per liter (parts per billion).
2. NS - No Standard
3. * - North Carolina In -Stream Target Value
4. J - Indicates the analytical result is an estimated concentration between the method
detection limit and the limit of quantitation.
5. B - Analyte found in the associated method blank as well as in the sample.
Concentration exceeds the North Carolina 15A NCAC 02B or
In -Stream Target Value Freshwater Aquatic Life Standard for Class
Waters -June 2019
Indicates the result is below the detection limit.
Smith Page 20 of 20 December 2019

Table 5
Constiuents Exceeding Standards
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
FACILITY PERMIT MONITORING NOVEMBER 2019 PARAMETERS EXCEEDING THE NORTH MONITORING NOVEMBER 2019 PARAMETERS EXCEEDING THE NORTH
CAROLINA 2L OR INTERIM MAXIMUM ALLOWABLE
NUMBER WELL .. ..
I CONCENTRATION CONCENTRATION
9209-MSWLF-1984 MW-11 Vanadium* MW-28 Not Sampled (3)
9209-MSWLF-1984
MW-11d
None Detected
MW-28d
Not Sampled (3)
9209-MSWLF-1984
MW-5R
None Detected
MW-29d
None Detected
9209-MSWLF-1984
MW-6
Cobalt*, Thallium*, 1,4-Dioxane
MW-30
Not Sampled (4)
9209-MSWLF-1984
MW-6d
Vanadium*
MW-31
Not Sampled (4)
9209-MSWLF-1984
MW-7
Chromium, Cobalt*, Vanadium*
MW-31d
Vanadium*
9209-MSWLF-1984
MW-8
Cobalt*, Vanadium*, 1,4-Dioxane
MW-32
Cobalt*
9209-MSWLF-1984
MW-8d
Vanadium*
TB-1a
Not Sampled (4)
9209-MSWLF-1984
MW-9
Thallium*, Vanadium*, Vinyl Chloride
TB-1a deep
Antimony*, Vanadium*
9209-MSWLF-1984
MW-10
Cobalt*
MW-33
Not Sampled(3)
9209-MSWLF-1984
MW-10d
None Detected
MW-34
Chromium, Cobalt*, Mercury, Thallium*, Vanadium*,
1,1-Dichloroethane, Methylene Chloride, Tetra chIoroethene
9209-MSWLF-1984
MW-22
Not Sampled (4)
MW-34d
None Detected
9209-MSWLF-1984
MW-23
Cobalt*, Thallium*, Vanadium*
MW-35
Not Sampled (3)
9209-MSWLF-1984
MW-23d
Antimony*, Vanadium*
MW-36
Chromium, Cobalt*, Vanadium*
9209-MSWLF-1984
MW-24
Not Sampled (4)
MW-36d
Vanadium*
Notes:
1. * - Interim Maximum Allowable Concentration
2. Bold - Indicates a J flag detection in which the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
3. (3) MW-28, -28d, -33, and -35 are sampled annually during the spring sampling event.
4. (4) MW-22, -24, -30, -31 and TB-1a were dry during the fall 2019 sampling event.
Smith Page 1 of 1 December 2019

Table 6
Geochemical Data
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - 9209-MSWLF-1984
MW-SR
mc
16-Mar-11 141.9 5.94 789 <2 <30 1.60 <2 12 -- 3.818 0.531 0.921 250D 6.3J <0.1 164 10.05
<0.5
<0.5
<0.5
1=5
<0.5
o
o
2.7
MW-5R
31-0ct-11 156.8 5.71 0.75 <2 <10 3.88 <2 <3 -- 2.7JB 12.0 1.4 110D 3.9J <0.1 335D 0.140
0.51
<0.07
O.1L
<0.07
<0.07
1.9
MW-5R
24-Apr-12 192.5 5.72 1.48 <2 <10 <0.43 <0.2 <0.54 -- 2.2J 10.0 1.1 110 3.4J <0.01 321D <0.046
<0.04
<0.24 <0.87
<0.62
<0.048
<0.057
<0.061
2.4
MW-5R
22-Oct-12 96.1 6.20 2.22 <2 13 1.64 <0.2 <0.54 -- 3.1JB 4.3J 1.4 190 5J <0.01 375D <0.046
<0.031
<0.031 <0.078
<0.095
<0.052
<0.063
<0.01
9.1
MW-5R
17-Apr-13 110.1 6.46 0.73 <4 <16 0.311 <0.061 <0.069 -- 1.4 9.07 1.4 135 2.11 <0.4 180 0*
<0.5
<1
<0.5
<0.5
<0.25
0.38J
MW-5R
16-Oct-13 132.5 6.08 1.88 <4 <16 2.3 <0.061 <0.069 -- 1.70 9.90 1.1 184 2.98 <0.4 210B 0.2*
<O.S
<1
<O.5
<O.5
<0.25
0.82
MW-SR
16-Apr-14 139.7 5.48 3.09 (1) <16 <3.3 <0.61 <0.069 -- 1.4 9.35 0.71 11.5 1.3 <0.4 180 0*
<0.5
<1
<0.5
<0.5
<0.25
1.2
MW-5R
12-Nov-14 -116.7 6.74 1.41 (1) <16 1.1J <0.61 <0.069 -- 2.1 6.25 <0.09 211 2.9B 0.4JB 130 0*
<O.S
<1
<O.5
<O.5
<0.25
11
MW-5R
30-Apr-15 14.4 5.39 2.41 <2 <16 <0.30 <0.61 <0.069 -- 1.6 8.00 0.91 62.1 1.5 <0.4 120 0*
<0.5
<1
<0.5
<0.5
<0.25
2.8
MW-5R
15-Oct-15 156.1 6.38 2.12 <2.0 <16 1.9 <0.061 <0.069 -- 2.8 0.137 1.0 272 9.5 O.SJ 110 0*
<0.50
<1.0
<0.50
<0.50
<0.020
2.4
MW-5R
21-Apr-16 116.7 5.54 1.36 <2.0 <16 <0.30 <0.061 <0.069 -- 1.6 3.65 0.91 39.1 1.1 <0.4 110 0.5*
<0.50
<1.0
<0.50
<0.50
<0.020
14.0
MW-5R
14-Sep-16 109.2 5.88 1.99 <2.0 <10 4.2J <10 <10 -- 2.6 1.8 0.56J 220 3.4B <1.0 430 0.5*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
3.9
MW-5R
20-Apr-17 94.2 6.29 1.30 <2.0 130 3.6 <10 <10 -- 2.6 1.6 1.1 200 1.1 <1.0 350 0*
<1.0
<1.0 <2.0
<2.0
<1.0
<1.0
<1.0
1.6
MW-SR
20-Sep-17 -29.0 6.60 2.58 <2.0 SS 4,100D <10 <10 -- 220D 0.23 0.67 350 11D <2.5 990 S.0*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
0.26
3.0
MW-SR
11-Apr-18 40.9 5.90 1.56 <2.0 <10 <10 <10 <10 -- 2.5 3.6 0.961 100B 2.2 <1.0 130 0*
<.0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
2.7
MW-SR
24-0ct-18 52.8 6.33 0.24 <2.0 <20 11B <10 <10 -- 4.6 0.064 1.6 260 2.6 <1.0 300 0*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
4.6
MW-5R
22-Apr-19 179.2 4.83 2.27 <2.0 <20 <10 <30 <30 -- 1.8 5.1 <1.0 <20 0.541 <1.0 71 0*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
<1.0
MW-SR
6-Nov-19 229.2 6.11 1.98 Q.0 <20 17B <10 <10 8,900 6.6 0.23 1.1 120 4.4 <1.0 470 0*
<0.10
<0.10 <0.20
<0.20
<O. 10
<O. 10
<0.30
2.5
MW-6
16-Mar-11
25.3
5.89
2.48
<2
75
899
<2
<2
--
14 BD
0.0291
14
SOOD
6.31
<0.1
349D
0.77
<0.5
<0.5
<0.5
18
<0.5
2.2
MW-6
1-Nov-11
10.1,
6.09
1.34
Q
94
4,600
<2
<3
--
170BD
O.OS3J
22
600D
12J
<0.1
820D
1.50
<0.07
8.7
<0.14
34
<0.07
1.9
MW-6
24-Apr-12
168.6
5.85
2.14
<2
32
5,660D
<0.2
<0.54
--
97
0.251
4.4
190D
3.5J
<0.01
549D
<0.046
<0.04
<0.24
<0.87
<0.62
0.56
1.7
<0.061
2.6
MW-6
22-0ct-12
-134.6
6.34
4.33
<2
100
732D
<0.2
<0.54
--
160BD
<0.025
21
430D
11J
0.029
725D
3.6
<0.031
<0.031
<0.078
26
<0.052
30
<0.01
5.9
MW-6
17-Apr-13
-158.3
6.25
0.91
14
<16
16
<0.061
<0.069
--
54.4
0.181
3.5
105
2.82
<0.4
110
1.4*
<0.5
<1
<0.5
<0.5
<0.25
0.76
MW-6
16-Oct-13
12.9
6.32
1.81
<4
40
45
<0.061
<0.069
--
93
0.16J
S.2
136
2.63
<0.4
98B
5.4*
<0.5
<1
<0.5
<0.5
<0.25
0.93
MW-6
16-Apr-14
43.1
5.99
1.81
(1)
<16
51
<0.061
<0.069
--
40.3
0.42
1.6
40.2
1.5
<0.4
69
0.5*
<0.5
<1
<0.5
<0.5
<0.25
1.3
MW-6
12-Nov-14
-121.4
6.81
0.87
(1)
74
1,400
<0.061
<0.069
--
184
0.09J
14.4
607
47.3
<0.4
180
1.S*
<0.5
<1
<0.5
<0.5
<0.25
7.3
MW-6
30-Apr-15
-52.3
6.05
2.01
<2
<16
23
<0.061
<0.069
--
50.9
0.161
2.6
192
5.9
<0.4
95
0.5*
<0.5
<1
<0.5
<0.5
<0.25
2.5
MW-6
14-Oct-15
58.9
6.68
2.39
<2.0
60
0.62J
<0.061
<0.069
--
208
0.017
14.7
422
19.7
0.4 UX
87
0*
2.1
<1.0
<0.50
<0.50
<0.020
2.4
MW-6
20-Apr-16
38.7
6.53
1.53
<2.0
<12
0.32J
<0.061
<0.069
--
58.5
0.37
2.3
164
4.1
<0.4
62
1.5*
<0.50
<1.0
<0.50
<0.50
0.151
12
MW-6
14-Sep-16
11.0
6.42
1.40
<2.0
44
3.71
<10
<10
--
210D
0.037
11
390
13D
<1.0
470
1.5*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
3.8
MW-6
20-Apr-17
119.3
6.70
2.16
12.0
22
4.2J
<10
<10
--
110
0.46
6.4
250
11
<1.0
350
0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
22
MW-6
21-Sep-17
-59.0
7.54
2.87
<2.0
31
<10
<10
<10
--
140
0.069
10
430
19
<1.0
520
2.0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
3.4
MW-6
12-Apr-18
13.0
6.34
1.74
<2.0
15
140
<10
<10
--
<10
1.5
5.1
140E
5.5
<1.0
150
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
3.6
MW-6
24-Oct-18
49.6
6.64
0.60
3.6
37
1,900B
<10
<10
--
160
<0.020
12
590
20
<1.0
590
1.0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
30
MW-6
22-Apr-19
100.4
6.12
0.51
5.3
<20
1,800
QO
<10
--
74
1.5
2.8
220
4.1
<1.0
450
1.0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
<1.0
MW-6
6-Nov-19
39.3
6.38
1. 11
<2.0
33
56B
QO
<10
180
0.48HD
14
410
7.7
<1.0
750
1.0*
<0.10
<0.10
0.76
<0.10
<0.10
<0.10
<0.30
3.0
MW-8
16-Mar-11
208.4
5.49
1.28
<2
<10
600
<2
<2
--
9.5B
0.121
<1
68
2.81
<0.1
148
<0.05
<0.5
<0.5
<0.5
<0.5
<0.5
2.2
MW-8
31-Oct-11
138.1
5.61
0.65
<2
11
1,750
<2
<3
--
7.8B
0.12J
0.84J
68
2.5J
<0.1
273D
0.130
0.99
<0.07
<0.14
0.33
<0.07
1.7
MW-8
24-Apr-12
161.7
5.64
1.67
<2
<10
1,870D
<0.2
<0.54
--
12
0.191
0.951
74
2.6J
<0.01
324D
<0.046
<0.04
<0.24
<0.87
<0.62
<0.048
<0.057
<0.061
2.0
MW-8
22-Oct-12
128.4
5.86
2.11
<2
<10
477D
<0.2
<0.54
--
14B
0.32J
0.820J
77
3.1J
<0.01
323D
<0.046
<0.031
<0.031
<0.078
1.1
<0.052
<0.063
O.OIJ
9.8
MW-8
17-Apr-13
96.8
6.23
0.48
<4
<16
520
0.14J
O.1J
--
16.9
0.21
1.4
86.8
1.49
<0.4
180
0.9*
<0.5
<1
<0.5
<0.5
<0.25
0.72
MW-8
16-0ct-13
146.8
5.79
1.74
<4
<16
430
0.11J
<0.069
--
19.7
0.18J
1.5
86.8
1.57
<0.4
200B
0.8*
<0.5
<1
<0.5
<0.5
<0.25
1U1
MW-8
16-Apr-14
122.9
5.79
0.19
(1)
<16
180
<0.60
<0.069
--
23.7
0.181
1.3
87.7
1.7
<0.4
230
0*
<0.5
<1
<0.5
<0.5
<0.25
1.4
MW-8
12-Nov-14
-84.6
6.09
0.79
(1)
20
320
0.13J
0.17J
--
29.4
0.12J
1.5
95.5
2.2B
0.4JB
160
0*
<0.5
<1
<0.5
<0.5
<0.25
17
MW-8
30-Apr-15
22.5
5.62
1.85
<2
17J
160
<0.061
0.111
--
44.0
0.111
2.8
132
2.5
<0.4
180
0*
<0.5
<1
<0.5
<0.5
<0.25
4.1
MW-8
15-Oct-15
113.1
5.93
1.63
<2.0
17J
150
<0.061
<0.069
--
44.9
0.007J
2.3
114
4.2
O.S1
130
0*
0.68J
<1.0
<0.50
<0.50
<0.020
2.0
MW-8
21-Apr-16
81.5
5.99
1.86
<2.0
<12
110
<0.061
<0.069
--
39.6
<0.04
2.6
123
2.4
<0.4
150
0*
<0.50
<1.0
<0.50
<0.50
<0.020
15
MW-8
14-Sep-16
116.9
5.75
1.77
<2.0
6.7J
640
QO
<10
--
45
0.021
1.9
120
2.3B
<1.0
370
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.30
3.8
MW-8
20-Apr-17
113.7
5.97
1.25
<2.0
8.31
180
<10
<10
--
37
0.069
1.8
110
0.98J
<1.0
300
0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
1.6
MW-8
20-Sep-17
154.0
6.41
1.78
<2.0
9.3
ISO
QO
<10
--
44
0.055
2.4
120
1.5
<1.0
320
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.30
4.4
MW-8
12-Apr-18
25.6
5.79
1.21
2.2
<10
150
<10
<10
--
45
0.035
2.2
140B
1.2
<1.0
150
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
2.8
MW-8
24-0ct-18
68.9
5.87
0.10
<2.0
<20
200E
<SO
<SO
--
49
<0.020
2.8
130
2.2
<1.0
180
0.5*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
3.4
MW-8
22-Apr-19
55.7
5.94
1.29
<4.0
<20
350
d0
<10
--
78
0.042
5.1
170
1.6
<3.0
770
1.0*
<0.10
0.10
<0.20
<0.20
<O.10
<O.10
<0.10
<1.0
MW-8
6-Nov-19
116.9
6.07
0.49
<2.0
71
410E
QO
<10
29
0.016J
3.6
110
2.0
<1.0
340
0.5*
0.14
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
1.5
MW-9
17-Mar-11
2.4
5.78
2.29
3
68
438
2.27
<2
--
18B
0.11
5.8
220D
2.7J
<0.1
231D
7.7
<O.5
<O.5
<0.5
1.8
<0.5
-
MW-9
1-Nov-11
6.3
5.95
1.94
<2
53
1,080
<2
<3
--
15B
0.075J
4.4
210D
2.9J
<0.1
414D
1.3
0.86
<0.07
<0.14
1.5
<0.07
--
MW-9
25-Apr-12
94.8
5.95
3.11
5.4
34
2,810D
<0.2
1.59J
--
18
0.079J
6.1
250D
2.8J
<0.01
503D
7.8
<0.04
<0.24
<0.87
<0.62
<0.048
1.7
<0.061
-
MW-9
23-Oct-12
83.4
6.72
8.77
<2
61
5.47
<0.2
<0.54
--
17B
<0.025
3.2
120
8.8J
<0.01
16.6
<0.230
<0.031
<0.031
<0.078
<0.095
<0.052
0.840
0.017
-
MW-9
17-Apr-13
91.3
6.88
6.84
3.1
22
8.5
<0.061
<0.069
--
17.1
<0.03
3.5
130
7.42
<0.4
10
2.1*
<O.5
<1
<0.5
<O.5
<0.25
-
MW-9
16-Oct-13
165.7
6.88
7.89
<4
28
0.53J
<0.061
<0.069
--
20.4
0.171
2.9
117
5.60
<0.4
27B
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-9
16-Apr-14
160.2
6.44
3.69
(1)
17J
17
<0.061
<0.069
--
18.5
0.15J
3.1
127
4.8
<0.4
39
0*
<O.5
<1
<0.5
<O.5
<0.25
-
MW-9
12-Nov-14
33.5
6.80
5.67
(1)
30
1.8
<0.061
<0.069
--
22.7
0.101
<0.09
136
3.9B
0.4JB
28
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-9
29-Apr-15
20.6
6.57
9.69
2.8
17J
2.9
<0.061
<0.069
--
19.2
<0.03
3.8
156
3.6
<0.4
27
0*
<O.5
<1
<0.5
<O.5
<0.25
-
MW-9
15-Oct-15
132.2
6.65
4.66
6.5
<16
<0.30
<0.061
<0.069
--
25.4
0.040
2.0
171
5.4
<0.4
53
0*
<0.50
<1.0
<0.50
<0.50
<0.020
-
MW-9
20-Apr-15
75.9
6.81
5.40
<2.0
<12
7.8
<0.061
<0.069
--
18.2
0.05J
1.7
182
3.4
<0.4
46
0*
<0.50
Q.0
<0.50
<0.50
<0.020
-
MW-9
13-Sep-16
151.7
6.72
7.15
<4.0
8.OJ
-
-
-
--
25
0.052
1.6
200
3.8
<1.0
-
1.0*
-
-
-
-
-
-
MW-9
19-Apr-17
130.8
6.93
7.28
<2.0
<10
6.1B1
<10
<10
--
24
0.0096J
1.8
210
2.1
<1.0
240
1.0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
-
MW-9
21-Sep-17
140.0
7.57
6.01
<2.0
<10
<10
<10
<10
--
24
0.056
1.9
200
2.8
<1.0
220
1.0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-9
11-Apr-18
41.4
6.79
7.50
<2.0
<10
<10
<10
<10
--
23
0.080
1.8
190B
2.2
<1.0
180
1.5*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-9
25-Oct-18
51.1
7.07
8.83
2.6
<20
6.9BJ
<SO
<SO
--
22
<0.020
2.2
210
2.5
1.5
190
0*
<0.10
<11.10
<0.20
<0.20
<0.10
<O.10
<0.10
-
MW-9
25-Apr-19
102.7
6.46
1.63
<2.0
<20
1,500
d0
<10
--
11
<0.020
3.7
270
1.4
<3.0
680
0*
<0.10
<0.10
<0.20
<0.20
<O.10
<O.10
<0.10
-
MW-9
5-Nov-19
105.4
6.50
1.55
<2.0
<20
5308
<10
<S0
30
<0.10
3.5
370
2.7
<S.0
990
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
Smith Page 1 of 2 December 2019

Table 6
Geochemical Data
November 2019 Semi -Annual Sampling Event
North Wake Unlined Landfill - 9209-MSWLF-1984
o
MW-10
mc
17-Mar-11 119.7 5.29 3.18
12
<10
2,000
12 12
--
4.31B
0.0391
2.7
130
2.41
<0.1
399D
0.26
<0.5
<0.5
<0.5
<0.5T<0.25--
o
MW-10
31-Oct-11 120.1 5.41 2.12
<2
15
9,630
<2 <3
--
3.6JB
<0.1
1.1
130
2.41
<0.1
777D
0.47
0.99
<0.07
0.M
0.22MW-10
25-Apr-12 127.9 5.41 2.62
<2
30
10,300D
<0.2 <0.54
--
3.5J
<0.025
3.3
120
3.11
<0.01
832D
0.17
0.26
<0.24 0.59
0.17
<0.048
<0.057-
MW-10
23-Oct-12 99.2 5.68 2.94
<2
28
8,220D
<0.2 <0.54
--
3.7JB
<0.025
3.6
120
2.41
<0.01
646D
0.083
0.087
<0.031 <0.078
<0.095
<0.052
<0.063MW-10
17-Apr-13 113.9 6.08 2.93
<4
<16
920
<0.061 <0.069
--
2.71
<0.03
1.5
132
0.75
<0.4
370
1.4*
<0.5
<1
<0.5
<0.5-
MW-10-
MW-10
16-Oct-13 84.8 5.65 4.05
<4
19J
3,100
<0.061 <0.069
--
2.74
<0.03
0.9J
117
0.73
<0.4
300B
1.8*
<0.5
<1
<0.5
<0.5MW-10
16-Apr-14 68.9 5.71 3.11
(1)
<16
3,200
<0.061 <0.069
--
3.4
<0.03
2.3
129
0.7J
<0.4
400
1.5*
<0.5
<1
<0.5
<0.5-
MW-10
12-Nov-14 10.9 5.84 1.81
(1)
27
3,900
0.0941 0.111
--
3.0
<0.03
2.5
147
1.18
<0.4
360
2.0*
<0.5
<1
<0.5
<0.5-
MW-10
29-Apr-15 30.6 5.56 2.82
3.1
<16
1,300
<0.061 <0.069
--
3.4
<0.03
3.0
184
0.9J
<0.4
320
2.0*
<0.5
<1
<0.5
<0.5
<0.25
--
MW-10
14-Oct-15 89.3 5.74 2.44
5.6
<16
1,200
<0.061 <0.069
--
3.3
<0.002
1.0
140
<1.8
<0.4
250
1.5*
0.67J
<1.0
<0.050
<0.50
<0.020
-
MW-10
20-Apr-16 30.9 5.79 2.34
6.5
16J
1,200
<0.061 <0.069
--
3.4
<0.04
1.6
128
<0.06
<0.4
200
1.0*
0.57J
<1.0
<0.20
<0.50
<0.020
-
MW-10
13-Sep-16 28.2 5.44 1.61
4.3
30
-
- -
--
3.6
0.024
<1.0
160
<1.0
<1.0
-
4.5*
-
-
-
-
-
-
MW-30
19-Apr-17 125.9 5.74 3.39
8.3
<10
4,800B
<10 <10
--
3.6
0.0141
1.2
160
<1.0
<1.0
720
3.0*
<1.0
<1.0 <2.0
<2.0
<1.0
<1.0
<1.0
-
MW-10
22-Sep-17 118.0 6.20 1.90
<2.0
QO
1,100
<10 <10
--
3.0
0.017
1.9
110
<1.0
<1.0
440
3.0*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.30
-
MW-10
11-Apr-18 44.1 5.60 0.71
<2.0
9.41
750
<10 <10
--
3.0
0.089
0.9
88B
0.431
<1.0
140
2.5*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
-
MW-10
25-Oct-18 74.0 5.61 3.64
5.5
<20
3,200
10 <10
--
12
<0.020
1.3
120
Q.0
<1.0
450
3.S*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.30
-
MW-10
25-Apr-19 7.9 5.47 0.39
5.111
<20
4,200D
<30 <10
--
3.9
<0.020
2.9
130
<1.0
<1.0
1,300
3.0*
0.34
<0.10 <0.20
<0.20
<0.10
<0.10
<0.10
--
MW-10
5-Nov-19 44.3 5.85 0.80
5.4
QO
4,3006D
<100 <100
3.5
0.0161
1.2
120
0.49J
<1.0
770
3.0*
<0.10
<0.10 <0.20
<0.20
<0.10
<0.10
<0.30
MW-11
17-Mar-11
211.2
5.21
8.02
<2
17
0.521
12
12
--
5B
0.61
0.531
32
2.11
<0.1
67.6
<0.05
<0.5
<0.5
<0.5
<0.5
<0.5
--
MW-11
1-Nov-11
161.6
5.62
5.89
3.20
QO
<1
<2
<3
--
4.1JB
0.71J
0.351
25
2.21
<0.1
164
<O.OS
0.8
<0.07
0.077J
0.16
<0.07
-
MW-11
25-Apr-12
112.2
5.47
6.22
<2
<10
<0.43
<0.2
<0.54
--
3.11
0.086)
0.761
22
1.7J
<0.01
161D
<0.046
<0.04
<0.24
<0.87
0.131
<0.048
<0.057
<0.061
-
MW-11
23-Oct-12
237.1
5.82
7.22
<2
13
<0.43
<0.2
<0.54
--
3.7JB
O.1SOJ
1.S
27
2.11
<0.01
147D
<0.046
<0.031
<0.031
<0.078
<0.095
<0.052
<0.063
<0.01
-
MW-11
17-Apr-13
102.3
5.94
5.73
<4
<16
<0.30
<0.061
<0.069
--
2.62
0.23
1.1
33.1
0.69
<0.4
100
0.8*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-11
16-Oct-13
211.6
5.49
7.94
<4
<16
<0.30
<0.061
<0.069
--
3.16
0.26
0.7J
34.8
0.66
<0.4
82B
0.4*
<0.5
<3
<0.5
<0.5
<0.25
-
MW-11
16-Apr-14
198.8
5.62
5.63
(1)
34
0.59
<0.061
<0.069
--
3.4
0.36
0.51
38.9
0.7J
<0.4
110
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-11
12-Nov-14
116.3
5.80
4.68
(1)
57
<0.30
<0.061
<0.069
--
4.1
0.46
0.8J
36.4
0.91B
0.518
82
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-11
30-Apr-15
20.1
5.52
7.18
<2
<16
<0.30
<0.061
<0.069
--
3.9
0.43
0.91
35.8
0.91E
10.4
82
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-11
15-Oct-15
196.8
5.91
5.70
<2.0
<16
<0.30
<0.061
<0.069
--
3.6
0.480
0.3J
34.9
<1.8
<0.4
66
0*
<O.SO
<1.0
<O.50
<O.50
<0.020
-
MW-11
21-Apr-16
135.3
5.72
5.75
<2.0
<12
<0.30
<0.061
<0.069
--
4.0
0.53
0.51
33.9
0.7J
0.518
75
1.5*
<0.50
<1.0
<0.50
<0.50
<0.020
-
MW-11
1-Sep-16
149.9
S.S6
6.49
15
<10
-
-
-
--
5.1
0.81
<1.0
42
<1.0
<1.0
-
1.S*
-
-
-
-
-
-
MW-11
20-Apr-17
142.3
5.87
4.82
12.0
110
2.7J
<10
<10
--
4.8
0.89
<1.0
36
<1.0
<1.0
150.0
0.5*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
-
MW-11
22-Sep-17
244.0
6.39
4.SS
<2.0
<10
<10
<10
<10
--
5.2
0.88
<1.0
47
<1.0
<1.0
130
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-11
13-Apr-18
46.3
5.71
5.74
<2.0
<10
<10
<10
<10
--
5.4
0.89
<1.0
46B
0.271
<1.0
75
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-11
25-Oct-18
44.6
6.02
5.97
<2.0
<20
2.5BJ
QO
<10
--
5.9
0.95
<1.0
46
1.0
<1.0
82
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.30
--
MW-11
25-Apr-19
87.8
5.91
5.94
3.4, 1
<20
<10
<10
<10
--
5.8
0.94
1.9
49
<1.0
170
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
--
MW-11
5-Nov-19
183.2
6.16
6.46
2.1
<20
<10
QO
<10
5.5
0.90
<1.0
42
)1.0
0.26J
<1.0
230
0*
0.51
<0.10
<0.20
<0.20
<0.10
<0.10
<0.30
MW-34
6-Nov-19
195.8
5.63
1.52
<2.0
<20
260B
<10
<10
7,300
11
0.14
1.0
35
0.471
<1.0
330
0*
0.12
0.29
<0.20
<0.20
<0.10
0.21
<0.10
MW-34d
6-Nov-19
466.9
6.08
0.61
2.8
<20
3.OBJ
<10
<10
12,000
9.2
1.0
1.6
65
1.4
<1.0
150
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.30
MW-36
17-Mar-11
99.4
5.45
2.36
<2
38
44
<2
<2
--
7.28
0.671
1.5
84
4.6J
<0.1
140
<0.25
<0.5
<0.5
<0.5
<0.5
<0.5
--
MW-36
1-Nov-11
129.6
5.66
1.96
<2
36
618
<2
<3
--
6.48
0.511
0.8J
62
4.41
<0.1
242D
0.052
0.99
<0.07
<0.14
0.21
<0.07
--
MW-36
25-Apr-12
122.2
5.71
2.84
5.2
29
186D
<0.2
<0.54
--
5.9
0.51
1.1
60
3.9J
<0.01
336D
<0.046
<0.04
<0.24
<0.87
0.0731
<0.048
<0.057
<0.061
-
MW-36
23-Oct-12
139.1
5.92
8.39
<2
<10
39.6
<0.2
<0.54
--
6B
0.490J
1.7
67
3.9J
<0.01
196D
<0.046
<0.031
<0.031
<0.078
<0.095
<0.052
<0.063
<0.01
-
MW-36
17-Apr-13
118.1
6.01
2.44
12
<16
6.4
<0.061
<0.069
--
5.59
0.59
1.1
66.3
2.19
10.4
98
0.8*
10.1
<1
<0.5
10.5
<0.25
-
MW-36
16-Oct-13
188.5
5.82
3.89
<4
38
9.8
<0.061
<0.069
--
5.50
0.73
1.1
59.2
2.19
<0.4
81B
1.5*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-36
16-Apr-14
165.3
5.76
3.08
(1)
71
17
<0.061
<0.069
--
5.8
0.86
0.61
55.6
2.3
<0.4
110
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-36
12-Nov-14
96.2
5.76
2.23
(1)
37
25
<0.061
<0.069
--
5.8
0.98
<0.09
55.3
2.68
<0.4
83
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-36
30-Apr-15
1.6
5.69
3.15
4.10
<16
3.6
<0.061
<0.069
--
5.8
0.89
1.4
58.4
2.3
<0.4
81
0*
<0.5
<1
<0.5
<0.5
<0.25
-
MW-36
15-Oct-15
167.8
5.97
3.78
<2.0
33
2.5
<0.061
<0.069
--
5.5
0.704
1.2
59.3
3.0
0.4J
72
0*
<0.50
<1.0
<0.50
<0.50
<0.020
-
MW-36
20-Apr-16
125.4
5.80
2.49
<2.0
<12
2.5
<0.061
<0.069
--
5.9
0.60
1.0
53.7
2.3
<0.4
76
2.0*
<0.50
<1.0
<0.50
<0.50
<0.020
-
MW-36
13-Sep-16
176.6
5.13
2.15
<2.0
<10
-
-
-
--
6.7
0.81
<1.0
55
2.5
<1.0
-
0.5*
-
-
-
-
-
-
MW-36
20-Apr-17
143.0
5.79
1.77
<2.0
<10
5.OJ
<10
<10
--
6.9
0.79
0.701
51
1.3
<1.0
190.0
2.0*
<1.0
<1.0
<2.0
<2.0
<1.0
<1.0
<1.0
-
MW-36
22-Sep-17
143.0
6.00
1.95
<2.0
<10
2.9
<SO
<10
--
7.3
0.66
0.78
63
2.4
<1.0
220.0
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-36
13-Apr-18
45.2
5.81
1.35
<2.0
<10
<30
<10
<30
--
6.9
0.66
0.83J
58B
3.3
<3.0
71.0
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-36
25-0ct-18
98.4
5.53
0.86
<2.0
20
3.9BJ
<10
<10
--
7.8
0.64
1.5
60
1.8
<1.0
190
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.10
<0.10
-
MW-36
25-Apr-19
123.4
5.77
0.94
<2.0
<20
<10
<10
<10
--
8.9
0.62
1.0
61
2.3
<3.0
280
0*
<0.10
<0.10
<0.20
<0.20
<0.30
<0.10
<0.10
-
MW-36
5-Nov-19
146.4
6.00
0.57
<2.0
<20
4.SBJ
<SO
<SO
8.8
0.60
1.0
58
1.9
1.1
390
0*
<0.10
<0.10
<0.20
<0.20
<0.10
<0.30
<0.10
Note'
1. All units are in milligrams per liter ((mg/L) parts per million), unless otherwise noted.
2. µg/L- micrograms per liter (parts per billion)
3. CaCO3-Calcium Carbonate
4. MW-11 is a background well for the North Wake Unlined Landfill.
5. * - Field analysis performed using a HACH kit.
6. (--( - Not Measured
7.1- Indicates the analytical result is an estimated concentration between the method detection limit and the limit of quantitation.
8. B - The analyze concentration detected in the method blank was greater than the method detection limit.
9. D - Analyzed at dilution.
10. UX - The compound was analyzed for, but not detected. 1 mL HNOa was added to MW-6 for metals upon receipt to get the pH to <2.
11. (1) - BOD was measured following dilution and did not meet the oxygen depletion criterion of at least 2 mg/L. The elevated BOD concentrations are a result of laboratory error and were not used to evaluate natural
attenuation for the April and November 2014 sampling events.
12. 1-The average BOD for MW-9, -30, -36, and -11 is lower than the valid range.
13. (-) Samples not collected and analyzed for the fall 2016 sampling event.
14. H -The analyze was analyzed outside of holding time.
�- Blank cells indicate no data collected
Smith Page 2 of 2 December 2019

N
y' i e LEGEND
w�e MW28 MW-28d, —'� i Groundwater Monitoring Well
219.14 219.77': Surface Water Sample Location
/� • Injection Well Location r
Potentiometric Contour
218—(dashed where inferred)
MW 22 I Contour Interval = 2 Feet
'219 31 - 19rpvSW
rr
-
9M+
MW-10' -
1231.49> �� + �� MW-36 1 _
i MW-10d ` ` i '_ 210.18 ..•.
227.27 f ' -.\.' /MW-9 MW-36d
212.03 210.24
MW-29d SW-7
233.53 ty ^sO ' i ' ' f t
N N O I f r.w- MW-6d
BMW-30' t f N N mwt
I t 'MW-6 / 205.52
231.89 N N o 120612 I
N N00
N/ O
MW-23 I r� ' ' .f�' i I N
229.6� 0 ,y r
p ' i f
MW-23rd
U61ine'd Lbndtill '
229.6
' f f
MW-31df228.32 Biobaerier Igjectign '
Area NWIW-21NWIW-1
MW-31.W-24 ' ' NWIW 3
228.560.92 ' '''°NWIW 4
TB99 ,` .f, 1i NWIW 5"NWIW-7
I
�``
f
TB-1a deep '� ` % f MW-5R \
224.82 �� ��� tf ' NEW-8 207.78
MW-32
225.28 `\
SW-3 1I 1...
MW-7 - MW-8 MW-8d MW-33
221.65 , 214.67 213.29 208.66
f
r
�- k:Y
,y Map Data Source: Augusf 2017 Aerial Photograp/r, rake
MW-35
205.15
v
MW 34
206 41 -.'„
M W-34d
-__ ,,.-
206.365''
-'S `
County. North Carolina CneMap.

300
250
F
O 200
r;
a�
CL
FY1i
J
Figure 2
MW-6 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Air Sparging System Operational
Completion of (August 2012)
the Landfill Cap Perimeter Migration Control
(July 1997) : System Operational (January 2002)
W M M O r-I -I N M M 1:T M M l0 I- n W M M O r-I r-I N M M -It M Ln l0 r- r- W M M
a> al 01 a> 01 01 a> al 01 Ol O O O O O O O O O O O O O O O r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I
O O O O O O O O O O O O O O
z z z z z z z z z z z z z z
Date
Smith December 2019

20
18
16
14
O
12
Q
i
fC
Q. 10
7
4
7
U
Figure 3
MW-6d - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
c-I ci N N M M Ill lIl N N M M M Ill lD lD I� r, W W M Ol
ro O to O M O M O to O M O to O to O M O M O ca O to O M O ca O to O M O ca O to O to O
2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z
Date
Smith December 2019

800
700
c
2 600
v
CL
v, 500
i
M
Q
C
400
co
a�
U
C 300
U
200
100
M
Figure 4
MW-9 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Completion of
the Landfill Cap
(July 1997)
n
Air Sparging System Operational
(August 2012)
Perimeter Migration Control
System Operational (January 2002)
M�-:T u1 u1 l0 LO I, r, W W M M O O rl rl N N M M-It -It Ln V1 l0 l0 I- r- w W M M O O rl rl N N M M�-:T u1 u1 l0 LO I, r, w W M M
at Ol O1 Ol 01 Ol a> Q> Q� a> Q� Ql Q� O O O O O O O O O O O O O O O O O O O O c-I rl a --I rl rl rl .--i rl c-I rl c-I rl c-I rl a --I rl rl rl rl rl
O ro O ro O O ro O ra O ra O ro O ro O ca O ca O ra O ra O to O ca O ca O ca O O ro O ca O ca O ro O ro O O ro O ro O ra O
z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z
Date
Smith December 2019

50
45
E1110
35
0
r.;
- 30
Q
i
fC
Q. 25
U 15
10
5
No
Figure 5
MW-36 - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Air Sparging System Operational
(August 2012)
00 Dl Ol O O N N M M Ln Ln lD lD I, n 00 00 D1 Q1
O O O
O co O co O rLs O nz O ra O ro O ro O co O ns O co O ro O
z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z
Date
Smith December 2019

35
30
25
O
r.;
W
Q 20
i
fC
Q.
r—
O
10
5
M
Figure 6
MW-36d - Total Volatile Organic Compounds Concentration Trend
North Wake Unlined Landfill - Permit Number 9209-MSWLF-1984
Air Sparging System Operational
(August 2012)
00 Ol Ol M M O O O O r-I c I c-I c-I N N N N M M M M M M M M lD lD lD lD r� n n n w W W W M M M M
O O O O O
> -0 >T to > -0 T w > -0 T w > -0 >- w > -0 >1 bA > -0 � bA > -0 >� w > -0 >� dA > -0 >T CA > -0 T w > -0 T w >
O N 7 O v to O O v ro 7 O N O O N cB O N to O O N 7 O N 7 O N 7 O v to O O v ro 7 O
Z Q Z LL Q Z LL Q Z LL Q Z Q Z 2 Q Z LL Q Z LL Q Z Q Z LL Q Z LL Q Z
Date
Smith December 2019

Appendix A
Analytical Data

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: North Wake Unlined Landfill
Lot Number:UK06022
Date Completed:12/12/2019
Revision Date: 12/11/2019
12/17/2019 6:37 PM
Approved and released by:
Project Manager: Cathy S. Dover
�p
nC C'itui'�tu
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 1 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: UK06022
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality
Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any
exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or
discussed below.
Nitrate-N 300.0
The initial analysis continuing calibration blank had a nitrate detection above the limit in the original
analysis of UK06022-012 (MW-10), UK06022-013 (MW-11), and UK06022-014 (MW-36). These
samples were re -analyzed outside holding times and both sets of data have been reported.
Sample UK06022-011 (MW-9) was run in hold but contained matrix that interfered with the retention
window for nitrate. As a result, the sample was analyzed at a 5x dilution for reduce the interference with
the retention window of nitrate, but it was analyzed out of hold. The matrix was resolved in the out of hold
5x dilution and the result is reported with the LOQ reflecting this dilution.
Sample UK06022-017 (MW-6) was analyzed at a 1x in hold but contained matrix that interfered with the
retention window of nitrate. The sample was analyzed out of hold at a dilution to resolve the matrix. The
result will be reported out of hold from the dilution.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the
cover page.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 2 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
CDM Smith
Lot Number: UK06022
Project Name: North Wake Unlined Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-7
Aqueous
11/04/20191710
11/06/2019
002
MW-23
Aqueous
11/05/20191330
11/06/2019
003
MW-23d
Aqueous
11/04/20191615
11/06/2019
004
MW-29d
Aqueous
11/05/20191100
11/06/2019
005
MW-31d
Aqueous
11/05/2019 0830
11/06/2019
006
TB -la deep
Aqueous
11/05/2019 0930
11/06/2019
007
MW-10D
Aqueous
11/05/20191400
11/06/2019
008
MW-11D
Aqueous
11/05/20191300
11/06/2019
009
DUP
Aqueous
11/05/2019 0800
11/06/2019
010
TB01
Aqueous
11/05/2019
11/06/2019
011
MW-9
Aqueous
11/05/20191545
11/06/2019
012
MW-10
Aqueous
11/05/20191430
11/06/2019
013
MW-11
Aqueous
11/05/20191200
11/06/2019
014
MW-36
Aqueous
11/05/20191645
11/06/2019
015
TB02
Aqueous
11/05/2019
11/06/2019
016
MW-5R
Aqueous
11/06/20191215
11/07/2019
017
MW-6
Aqueous
11/06/20191415
11/07/2019
018
MW-8
Aqueous
11/06/2019 0845
11/07/2019
019
MW-8d
Aqueous
11/06/2019 0800
11/07/2019
020
MW-34
Aqueous
11/06/20191100
11/07/2019
021
MW-34d
Aqueous
11/06/20191130
11/07/2019
022
NWIW-5
Aqueous
11/06/20191500
11/07/2019
023
EQ BLANK
Aqueous
11/06/2019 1615
11/07/2019
024
MW-6d
Aqueous
11/06/20191400
11/07/2019
025
MW-5R
Aqueous
11/06/20191240
11/07/2019
026
MW-6
Aqueous
11/06/20191435
11/07/2019
027
MW-8
Aqueous
11/06/2019 0915
11/07/2019
028
SW-2
Aqueous
11/07/20191020
11/08/2019
029
SW-3
Aqueous
11/07/2019
0800
11/08/2019
030
SW-7
Aqueous
11/07/2019
0930
11/08/2019
031
SW-8
Aqueous
11/07/2019
0840
11/08/2019
032
MW-6
Aqueous
11/07/2019
0855
11/08/2019
033
MW-8
Aqueous
11/07/2019
0835
11/08/2019
034
MW-9
Aqueous
11/07/2019
0950
11/08/2019
035
MW-10
Aqueous
11/07/20191000
11/08/2019
036
MW-11
Aqueous
11/07/2019
0820
11/08/2019
037
MW-32
Aqueous
11/07/2019
0745
11/08/2019
038
MW-34
Aqueous
11/07/2019
0845
11/08/2019
039
MW-36
Aqueous
11/07/2019
0920
11/08/2019
040
MW-36d
Aqueous
11/07/2019
0915
11/08/2019
(40 samples)
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 3 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-001
Description: MW-7 Matrix: Aqueous
Date Sampled:11/04/2019 1710 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191525 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.41
J
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.83
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.77
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 4 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-001
Description: MW-7 Matrix: Aqueous
Date Sampled:11/04/2019 1710 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191525 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
89 70-130
97 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 5 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-001
Description: MW-7 Matrix: Aqueous
Date Sampled:11/04/2019 1710 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1750 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00017 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 6 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-001
Description: MW-7 Matrix: Aqueous
Date Sampled:11/04/2019 1710 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 1928 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
46
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.38
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.84
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
13
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
27
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
38
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
10
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
8.9
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
0.26
J
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.18
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
26
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
24
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 7 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-002
Description: MW-23 Matrix: Aqueous
Date Sampled:11/05/2019 1330 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191843 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 8 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-002
Description: MW-23 Matrix: Aqueous
Date Sampled:11/05/2019 1330 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191843 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
91 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 9 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-002
Description: MW-23 Matrix: Aqueous
Date Sampled:11/05/2019 1330 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1803 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 10 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-002
Description: MW-23 Matrix: Aqueous
Date Sampled:11/05/2019 1330 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2011 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
39
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.35
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
6.0
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.7
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
10
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
5.3
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
4.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.23
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
13
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
24
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 11 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-003
Description: MW-23d Matrix: Aqueous
Date Sampled:11/04/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191547 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 12 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-003
Description: MW-23d Matrix: Aqueous
Date Sampled:11/04/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191547 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
89 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 13 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-003
Description: MW-23d Matrix: Aqueous
Date Sampled:11/04/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1805 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000096 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 14 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-003
Description: MW-23d Matrix: Aqueous
Date Sampled:11/04/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2036 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
1.7
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
34
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.91
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.2
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
4.1
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.35
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.8
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
21
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 15 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-004
Description: MW-29d Matrix: Aqueous
Date Sampled:11/05/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191609 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 16 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-004
Description: MW-29d Matrix: Aqueous
Date Sampled:11/05/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191609 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
91 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 17 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-004
Description: MW-29d Matrix: Aqueous
Date Sampled:11/05/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1808 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000092 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 18 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-004
Description: MW-29d Matrix: Aqueous
Date Sampled:11/05/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2042 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
33
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.4
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.9
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.36
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.0
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
39
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 19 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-005
Description: MW-31d Matrix: Aqueous
Date Sampled:11/05/2019 0830 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191631 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
6.3
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 20 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-005
Description: MW-31d Matrix: Aqueous
Date Sampled:11/05/2019 0830 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191631 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
91 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 21 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-005
Description: MW-31d Matrix: Aqueous
Date Sampled:11/05/2019 0830 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1810 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000092 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 22 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-005
Description: MW-31d Matrix: Aqueous
Date Sampled:11/05/2019 0830 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2049 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
0.63
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
17
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.21
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
4.1
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
6.3
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
84
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 23 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-006
Description: TB-1a deep Matrix: Aqueous
Date Sampled:11/05/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191441 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.65
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 24 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-006
Description: TB-1a deep Matrix: Aqueous
Date Sampled:11/05/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191441 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
90 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 25 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-006
Description: TB-1a deep Matrix: Aqueous
Date Sampled:11/05/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1813 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 26 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-006
Description: TB-1a deep Matrix: Aqueous
Date Sampled:11/05/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2055 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
1.7
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
23
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.66
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.4
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.64
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.8
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.1
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
38
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 27 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-007
Description: MW-10D Matrix: Aqueous
Date Sampled:11/05/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191821 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.1
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 28 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-007
Description: MW-10D Matrix: Aqueous
Date Sampled:11/05/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191821 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
94 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 29 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-007
Description: MW-10D Matrix: Aqueous
Date Sampled:11/05/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1815 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000098 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 30 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-007
Description: MW-10D Matrix: Aqueous
Date Sampled:11/05/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2101 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
3.7
J
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.14
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.34
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
6.2
BJ
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 31 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-008
Description: MW-11D Matrix: Aqueous
Date Sampled:11/05/2019 1300 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191653 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 32 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-008
Description: MW-11D Matrix: Aqueous
Date Sampled:11/05/2019 1300 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191653 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
99 70-130
94 70-130
104 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 33 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-008
Description: MW-11D Matrix: Aqueous
Date Sampled:11/05/2019 1300 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1818 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 34 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-008
Description: MW-11D Matrix: Aqueous
Date Sampled:11/05/2019 1300 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2120 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
43
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.3
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.29
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.9
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
13
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 35 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-009
Description: DUP Matrix: Aqueous
Date Sampled:11/05/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191715 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 36 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-009
Description: DUP Matrix: Aqueous
Date Sampled:11/05/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191715 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
93 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 37 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-009
Description: DUP Matrix: Aqueous
Date Sampled:11/05/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1820 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 38 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-009
Description: DUP Matrix: Aqueous
Date Sampled:11/05/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/15/2019 2126 BPK
Prep Date Batch
11/06/2019 1706 34766
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
44
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.5
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.1
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.26
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.8
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
11
B
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 39 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-010
Description: TB01 Matrix: Aqueous
Date Sampled:11/05/2019 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191504 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 40 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-010
Description: TB01 Matrix: Aqueous
Date Sampled:11/05/2019 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191504 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
91 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 41 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-011
Description: MW-9 Matrix: Aqueous
Date Sampled:11/05/2019 1545 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/07/2019 1756 KFE
34964
1
(BOD, 5 day) SM 521OB-2011
1 11/11/2019 1857 MOM
11/06/2019
1538
12987
1
(Chloride) 300.0
1 11/07/2019 0914 SLU
34965
1
(CO2 (calcula) SM 4500-CO2 D
1 11/07/2019 1756 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2128 HET
35742
2
(Nitrate - N) 300.0
5 11/09/2019 0814 SLU
35335
1
(Sulfate) 300.0
1 11/07/2019 0914 SLU
34970
1
(Sulfide) SM 4500-S2 F-2011
1 11/11/2019 1822 HET
35290
1
(TOC) SM 531OC-2011
1 11/13/2019 1822 DMA
35255
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
370
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0
U
2.0
0.18
mg/L
1
Chloride
300.0
30
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
990
27
27
mg/L
1
COD
SM 5220D-
20
U
20
20
mg/L
1
Nitrate - N
300.0
0.10
UH
0.10
0.025
mg/L
2
Sulfate
300.0
2.7
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0
U
1.0
0.99
mg/L
1
TOC
SM 5310C-
3.5
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 42 of 238

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:UK06022-011
Description: MW-9 Matrix: Aqueous
Date Sampled:11/05/2019 1545 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B (SIM) 1 11/13/2019 1714 TML 35540
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260B (SIM) 2.8 J 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
103 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 43 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-011
Description: MW-9 Matrix: Aqueous
Date Sampled:11/05/2019 1545 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191217 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.72
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
4.5
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
4.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
12
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 44 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-011
Description: MW-9 Matrix: Aqueous
Date Sampled:11/05/2019 1545 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191217 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50 U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0 U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
9.9
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0 U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
93 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 45 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-011
Description: MW-9 Matrix: Aqueous
Date Sampled:11/05/2019 1545 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2133 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 530 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 46 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-012
Description: MW-10 Matrix: Aqueous
Date Sampled:11/05/2019 1430 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/07/2019 1816 KFE
34964
1
(BOD, 5 day) SM 521OB-2011
1 11/11/2019 1857 MOM
11/06/2019
1538 12987
1
(Chloride) 300.0
1 11/07/2019 0933 SLU
34965
1
(CO2 (calcula) SM 4500-CO2 D
1 11/07/2019 1816 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2130 HET
35742
1
(Nitrate - N) 300.0
1 11/07/2019 0933 SLU
34967
2
(Nitrate - N) 300.0
1 11/09/2019 0833 SLU
35335
1
(Sulfate) 300.0
1 11/07/2019 0933 SLU
34970
1
(Sulfide) SM 4500-S2 F-2011
1 11/11/2019 1822 HET
35290
1
(TOC) SM 531OC-2011
1 11/13/2019 1835 DMA
35255
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
120
20
20
mg/L
1
BOD, 5 day
SM 5210B-
5.4
2.0
0.18
mg/L
1
Chloride
300.0
3.5
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
770
27
27
mg/L
1
COD
SM 5220D-
20
U
20
20
mg/L
1
Sulfate
300.0
0.49
J
1.0
0.20
mg/L
1
Nitrate - N
300.0
0.016
J
0.020
0.0050
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0
U
1.0
0.99
mg/L
1
Nitrate - N
300.0
0.022
H
0.020
0.0050
mg/L
2
TOC
SM 5310C-
1.2
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 47 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-012
Description: MW-10 Matrix: Aqueous
Date Sampled:11/05/2019 1430 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191240 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.77
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.5
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.89
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
4.1
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.96
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 48 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-012
Description: MW-10 Matrix: Aqueous
Date Sampled:11/05/2019 1430 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191240 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
91 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 49 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-012
Description: MW-10 Matrix: Aqueous
Date Sampled:11/05/2019 1430 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 10 11/07/2019 2341 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 100 U 100 25 ug/L 1
Ethene 74-85-1 RSK - 175 100 U 100 25 ug/L 1
Methane 74-82-8 RSK - 175 4300 BD 100 25 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 50 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-013
Description: MW-11 Matrix: Aqueous
Date Sampled:11/05/2019 1200 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/07/2019 1826 KFE
34964
1
(BOD, 5 day) SM 521OB-2011
1 11/11/2019 1857 MOM
11/06/2019
1538 12987
1
(Chloride) 300.0
1 11/07/2019 0952 SLU
34965
1
(CO2 (calcula) SM 4500-CO2 D
1 11/07/2019 1826 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2130 HET
35742
1
(Nitrate - N) 300.0
1 11/07/2019 0952 SLU
34967
2
(Nitrate - N) 300.0
1 11/09/2019 0155 SLU
35335
1
(Sulfate) 300.0
1 11/07/2019 0952 SLU
34970
1
(Sulfide) SM 4500-S2 F-2011
1 11/11/2019 1822 HET
35290
1
(TOC) SM 531OC-2011
1 11/13/2019 1849 DMA
35255
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
42
20
20
mg/L
1
BOD, 5 day
SM 5210B-
2.1
2.0
0.18
mg/L
1
Chloride
300.0
5.5
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
230
27
27
mg/L
1
COD
SM 5220D-
20
U
20
20
mg/L
1
Sulfate
300.0
0.26
J
1.0
0.20
mg/L
1
Nitrate - N
300.0
0.90
0.020
0.0050
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0
U
1.0
0.99
mg/L
1
Nitrate - N
300.0
0.90
H
0.020
0.0050
mg/L
2
TOC
SM 5310C-
1.0
U
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 51 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-013
Description: MW-11 Matrix: Aqueous
Date Sampled:11/05/2019 1200 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191737 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 52 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-013
Description: MW-11 Matrix: Aqueous
Date Sampled:11/05/2019 1200 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191737 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
91 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 53 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-013
Description: MW-11 Matrix: Aqueous
Date Sampled:11/05/2019 1200 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2149 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 10 U 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 54 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-014
Description: MW-36 Matrix: Aqueous
Date Sampled:11/05/2019 1645 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/07/2019 1830 KFE
34964
1
(BOD, 5 day) SM 521OB-2011
1 11/11/2019 1857 MOM
11/06/2019 1538 12987
1
(Chloride) 300.0
1 11/07/2019 1011 SLU
34965
1
(CO2 (calcula) SM 4500-CO2 D
1 11/07/2019 1830 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2131 HET
35742
1
(Nitrate - N) 300.0
1 11/07/2019 1011 SLU
34967
2
(Nitrate - N) 300.0
1 11/09/2019 0252 SLU
35335
1
(Sulfate) 300.0
1 11/07/2019 1011 SLU
34970
1
(Sulfide) SM 4500-S2 F-2011
1 11/11/2019 1822 HET
35290
1
(TOC) SM 531OC-2011
1 11/13/2019 1902 DMA
35255
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 232013-
58
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
8.8
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
390
27
27
mg/L
1
COD
SM 5220D-
20 U
20
20
mg/L
1
Sulfate
300.0
1.9
1.0
0.20
mg/L
1
Nitrate - N
300.0
0.60
0.020
0.0050
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.1
1.0
0.99
mg/L
1
Nitrate - N
300.0
0.61 H
0.020
0.0050
mg/L
2
TOC
SM 5310C-
1.0
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 55 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-014
Description: MW-36 Matrix: Aqueous
Date Sampled:11/05/2019 1645 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191905 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.5
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
2.8
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 56 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-014
Description: MW-36 Matrix: Aqueous
Date Sampled:11/05/2019 1645 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191905 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
92 70-130
90 70-130
98 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 57 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-014
Description: MW-36 Matrix: Aqueous
Date Sampled:11/05/2019 1645 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2205 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 4.5 BJ 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 58 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-015
Description: TB02 Matrix: Aqueous
Date Sampled:11/05/2019 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/09/20191759 STM
35130
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 59 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-015
Description: TB02 Matrix: Aqueous
Date Sampled:11/05/2019 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/09/20191759 STM 35130
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
95 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 60 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/14/2019 1555 KFE
35757
1
(BOD, 5 day) SM 521OB-2011
1 11/12/2019 1937 MOM
11/07/2019 1553 12991
1
(Chloride) 300.0
1 11/08/2019 0214 SLU
35048
1
(CO2 (calcula) SM 4500-CO2 D
1 11/14/2019 1555 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2131 HET
35742
1
(Nitrate - N) 300.0
1 11/08/2019 0214 SLU
35049
1
(Sulfate) 300.0
1 11/08/2019 0214 SLU
35051
1
(Sulfide) SM 4500-S2 F-2011
1 11/13/2019 1749 HET
35633
1
(TOC) SM 531OC-2011
1 11/13/2019 1915 DMA
35255
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
120
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
6.6
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
470
27
27
mg/L
1
COD
SM 5220D-
20 U
20
20
mg/L
1
Nitrate - N
300.0
0.23
0.020
0.0050
mg/L
1
Sulfate
300.0
4.4
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0 U
1.0
0.99
mg/L
1
TOC
SM 5310C-
1.1
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 61 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191301 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.61
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.62
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 62 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191301 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
95 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 63 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2220 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 17 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 64 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1823 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 65 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-016
Description: MW-5R Matrix: Aqueous
Date Sampled:11/06/2019 1215 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2049 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
130
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.2
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.7
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Sodium
7440-23-5
6020B
8900
400
150
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
15
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 66 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-017
Description: MW-6 Matrix: Aqueous
Date Sampled:11/06/2019 1415 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/14/2019 1610 KFE
35757
1
(BOD, 5 day) SM 521OB-2011
1 11/12/2019 1937 MOM
11/07/2019 1553
12991
1
(Chloride) 300.0
1 11/08/2019 0233 SLU
35048
1
(CO2 (calcula) SM 4500-CO2 D
1 11/14/2019 1610 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2131 HET
35742
2
(Nitrate - N) 300.0
5 11/09/2019 1327 SLU
35335
1
(Sulfate) 300.0
1 11/08/2019 0233 SLU
35051
1
(Sulfide) SM 4500-S2 F-2011
1 11/13/2019 1749 HET
35633
1
(TOC) SM 531OC-2011
1 11/13/2019 1928 DMA
35255
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
410
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
180
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
750
27
27
mg/L
1
COD
SM 5220113-
33
20
20
mg/L
1
Nitrate - N
300.0
0.48 HD
0.10
0.025
mg/L
2
Sulfate
300.0
7.7
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0 U
1.0
0.99
mg/L
1
TOC
SM 5310C-
14
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 67 of 238

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:UK06022-017
Description: MW-6 Matrix: Aqueous
Date Sampled:11/06/2019 1415 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B (SIM) 1 11/13/2019 1738 TML 35540
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260B (SIM) 24 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
104 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 68 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-017
Description: MW-6 Matrix: Aqueous
Date Sampled:11/06/2019 1415 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191323 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.3
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.8
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 69 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-017
Description: MW-6 Matrix: Aqueous
Date Sampled:11/06/2019 1415 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191323 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
93 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 70 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-017
Description: MW-6 Matrix: Aqueous
Date Sampled:11/06/2019 1415 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2236 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 56 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 71 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-018
Description: MW-8 Matrix: Aqueous
Date Sampled:11/06/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/14/2019 1616 KFE
35757
1
(BOD, 5 day) SM 521OB-2011
1 11/12/2019 1937 MOM
11/07/2019 1553 12991
1
(Chloride) 300.0
1 11/08/2019 0251 SLU
35048
1
(CO2 (calcula) SM 4500-CO2 D
1 11/14/2019 1616 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2131 HET
35742
1
(Nitrate - N) 300.0
1 11/08/2019 0251 SLU
35049
1
(Sulfate) 300.0
1 11/08/2019 0251 SLU
35051
1
(Sulfide) SM 4500-S2 F-2011
1 11/13/2019 1818 HET
35634
1
(TOC) SM 531OC-2011
1 11/13/2019 1941 DMA
35255
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
110
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0 U
2.0
0.18
mg/L
1
Chloride
300.0
29
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
340
27
27
mg/L
1
COD
SM 5220113-
71
20
20
mg/L
1
Nitrate - N
300.0
0.016 J
0.020
0.0050
mg/L
1
Sulfate
300.0
2.0
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0 U
1.0
0.99
mg/L
1
TOC
SM 5310C-
3.6
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 72 of 238

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:UK06022-018
Description: MW-8 Matrix: Aqueous
Date Sampled:11/06/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B (SIM) 1 11/13/2019 1802 TML 35540
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260B (SIM) 4.1 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
107 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 73 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-018
Description: MW-8 Matrix: Aqueous
Date Sampled:11/06/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191345 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.47
J
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.4
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
24
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 74 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-018
Description: MW-8 Matrix: Aqueous
Date Sampled:11/06/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191345 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
92 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 75 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-018
Description: MW-8 Matrix: Aqueous
Date Sampled:11/06/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2252 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 410 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 76 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-019
Description: MW-8d Matrix: Aqueous
Date Sampled:11/06/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191407 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 77 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-019
Description: MW-8d Matrix: Aqueous
Date Sampled:11/06/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191407 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
93 70-130
91 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 78 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-019
Description: MW-8d Matrix: Aqueous
Date Sampled:11/06/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1830 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 79 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-019
Description: MW-8d Matrix: Aqueous
Date Sampled:11/06/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2054 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
21
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.22
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.9
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.2
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.9
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
14
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 80 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-020
Description: MW-34 Matrix: Aqueous
Date Sampled:11/06/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/14/2019 1620 KFE
35757
1
(BOD, 5 day) SM 521OB-2011
1 11/12/2019 1937 MOM
11/07/2019
1553 12991
1
(Chloride) 300.0
1 11/08/2019 0310 SLU
35048
1
(CO2 (calcula) SM 4500-CO2 D
1 11/14/2019 1620 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2131 HET
35742
1
(Nitrate - N) 300.0
1 11/08/2019 0310 SLU
35049
1
(Sulfate) 300.0
1 11/08/2019 0310 SLU
35051
1
(Sulfide) SM 4500-S2 F-2011
1 11/13/2019 1749 HET
35633
1
(TOC) SM 531OC-2011
1 11/13/2019 2021 DMA
35255
CAS Analytical
Parameter
Number Method
Result
Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
35
20
20
mg/L
1
BOD, 5 day
SM 521013-
2.0
U
2.0
0.18
mg/L
1
Chloride
300.0
11
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
330
27
27
mg/L
1
COD
SM 5220D-
20
U
20
20
mg/L
1
Nitrate - N
300.0
0.14
0.020
0.0050
mg/L
1
Sulfate
300.0
0.47
J
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0
U
1.0
0.99
mg/L
1
TOC
SM 5310C-
1.0
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 81 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-020
Description: MW-34 Matrix: Aqueous
Date Sampled:11/06/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191429 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.42
J
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.61
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
1.1
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
1.4
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
6.8
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
7.7
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
6.6
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
1.3
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
1.6
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.72
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 82 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-020
Description: MW-34 Matrix: Aqueous
Date Sampled:11/06/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191429 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
97 70-130
95 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 83 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-020
Description: MW-34 Matrix: Aqueous
Date Sampled:11/06/2019 1100 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2308 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 260 B 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 84 of 238

Inorganic non-metals
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1
(Alkalinity) SM 2320B-2011
1 11/14/2019 1626 KFE
35757
1
(BOD, 5 day) SM 521OB-2011
1 11/12/2019 1937 MOM
11/07/2019 1553 12991
1
(Chloride) 300.0
1 11/08/2019 0329 SLU
35048
1
(CO2 (calcula) SM 4500-CO2 D
1 11/14/2019 1626 KFE
1
(COD) SM 5220D-2011
1 11/14/2019 2132 HET
35742
1
(Nitrate - N) 300.0
1 11/08/2019 0329 SLU
35049
1
(Sulfate) 300.0
1 11/08/2019 0329 SLU
35051
1
(Sulfide) SM 4500-S2 F-2011
1 11/13/2019 1749 HET
35633
1
(TOC) SM 531OC-2011
1 11/13/2019 2035 DMA
35255
CAS Analytical
Parameter
Number Method
Result Q
LOQ
DL
Units
Run
Alkalinity
SM 2320B-
65
20
20
mg/L
1
BOD, 5 day
SM 5210B-
2.8
2.0
0.18
mg/L
1
Chloride
300.0
9.2
1.0
0.20
mg/L
1
CO2 (calculation)
124-38-9 SM 4500-CO2
150
27
27
mg/L
1
COD
SM 5220D-
20 U
20
20
mg/L
1
Nitrate - N
300.0
1.0
0.020
0.0050
mg/L
1
Sulfate
300.0
1.4
1.0
0.20
mg/L
1
Sulfide
18496-25-8 SM 4500-S2 F-
1.0 U
1.0
0.99
mg/L
1
TOC
SM 5310C-
1.6
1.0
1.0
mg/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 85 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191452 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.40
J
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.75
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
2.9
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
2.4
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.93
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.48
J
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.55
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 86 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191452 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
92 70-130
102 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 87 of 238

Dissolved Gases
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 RSK - 175 1 11/07/2019 2324 ALR1 34986
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Ethane 74-84-0 RSK - 175 10 U 10 2.5 ug/L 1
Ethene 74-85-1 RSK - 175 10 U 10 2.5 ug/L 1
Methane 74-82-8 RSK - 175 3.0 BJ 10 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 88 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1833 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 B 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 89 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-021
Description: MW-34d Matrix: Aqueous
Date Sampled:11/06/2019 1130 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2100 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
25
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
1.8
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
8.7
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
4.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.90
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.4
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Sodium
7440-23-5
6020B
12000
400
150
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
19
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 90 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-022
Description: NWIW-5 Matrix: Aqueous
Date Sampled:11/06/2019 1500 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191514
TML
35148
2 5030B 8260D
5 11/12/2019 0246 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
17
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
280
D
50
10
ug/L
2
Carbon disulfide
75-15-0
8260D
1.1
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
12
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1, 1 -Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
3.1
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 91 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-022
Description: NWIW-5 Matrix: Aqueous
Date Sampled:11/06/2019 1500 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run
Prep Method
Analytical Method
Dilution
Analysis Date Analyst Prep Date
Batch
1
5030B
8260D
1
11/10/20191514 TML
35148
2
5030B
8260D
5
11/12/2019 0246 ALR1
35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Run 2 Acceptance
Surrogate
Q % Recovery Limits
Q %
Recovery
Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130 92 70-130
92 70-130 99 70-130
102 70-130 100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 92 of 238

Volatile Organic Compounds by GC/MS (SIM)
Client:CDM Smith Laboratory ID:UK06022-023
Description: EQ BLANK Matrix: Aqueous
Date Sampled:11/06/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260B (SIM) 1 11/13/2019 1041 TML 35540
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,4-Dioxane 123-91-1 8260B (SIM) 3.0 U 3.0 1.0 ug/L 1
Run Acceptance
Surrogate Q % Recovery Limits
1,2-Dichloroethane-d4
109 40-170
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 93 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-023
Description: EQ BLANK Matrix: Aqueous
Date Sampled:11/06/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191155 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 94 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-023
Description: EQ BLANK Matrix: Aqueous
Date Sampled:11/06/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191155 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
92 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 95 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-023
Description: EQ BLANK Matrix: Aqueous
Date Sampled:11/06/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1836 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 96 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-023
Description: EQ BLANK Matrix: Aqueous
Date Sampled:11/06/2019 1615 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2105 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
5.0
U
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
10
U
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 97 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-024
Description: MW-6d Matrix: Aqueous
Date Sampled:11/06/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/10/20191536 TML
35148
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
1.1
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 98 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-024
Description: MW-6d Matrix: Aqueous
Date Sampled:11/06/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/10/20191536 TML 35148
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
88 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 99 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-024
Description: MW-6d Matrix: Aqueous
Date Sampled:11/06/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1838 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 100 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-024
Description: MW-6d Matrix: Aqueous
Date Sampled:11/06/2019 1400 Project Name: North Wake Unlined Landfill
Date Received: 11 /07/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2111 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
0.55
J
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
70
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.81
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
4.4
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.5
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.39
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.2
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
3.5
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
16
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 101 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-028
Description: SW-2 Matrix: Aqueous
Date Sampled:11/07/2019 1020 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2126 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 102 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-028
Description: SW-2 Matrix: Aqueous
Date Sampled:11/07/2019 1020 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2126 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
96 70-130
98 70-130
103 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 103 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-028
Description: SW-2 Matrix: Aqueous
Date Sampled:11/07/2019 1020 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1841 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00020 U 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 104 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-028
Description: SW-2 Matrix: Aqueous
Date Sampled:11/07/2019 1020 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2116 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
36
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.4
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.6
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 105 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-029
Description: SW-3 Matrix: Aqueous
Date Sampled:11/07/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2151 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 106 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-029
Description: SW-3 Matrix: Aqueous
Date Sampled:11/07/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2151 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
97 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 107 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-029
Description: SW-3 Matrix: Aqueous
Date Sampled:11/07/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1843 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000095 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 108 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-029
Description: SW-3 Matrix: Aqueous
Date Sampled:11/07/2019 0800 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2122 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
35
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.29
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.6
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 109 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-030
Description: SW-7 Matrix: Aqueous
Date Sampled:11/07/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2215 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 110 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-030
Description: SW-7 Matrix: Aqueous
Date Sampled:11/07/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2215 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
90 70-130
95 70-130
99 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 111 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-030
Description: SW-7 Matrix: Aqueous
Date Sampled:11/07/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1846 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00012 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 112 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-030
Description: SW-7 Matrix: Aqueous
Date Sampled:11/07/2019 0930 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2127 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
25
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
3.4
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
4.5
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 113 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-031
Description: SW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0840 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2240 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 114 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-031
Description: SW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0840 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2240 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
95 70-130
97 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 115 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-031
Description: SW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0840 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1848 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.000094 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 116 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-031
Description: SW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0840 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2133 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
25
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
5.0
U
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
5.3
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 117 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-032
Description: MW-6 Matrix: Aqueous
Date Sampled:11/07/2019 0855 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1851 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00016 BJ 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 118 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-032
Description: MW-6 Matrix: Aqueous
Date Sampled:11/07/2019 0855 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2139 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
270
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.18
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
67
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
18
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
2.5
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.28
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
6.4
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 119 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-033
Description: MW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0835 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1853 KSH2 11/12/2019 1004 35243
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00032 B 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 120 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-033
Description: MW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0835 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2155 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
48
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
6.4
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
1.6
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.5
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.4
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
6.0
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
12
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 121 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-034
Description: MW-9 Matrix: Aqueous
Date Sampled:11/07/2019 0950 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1532 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00022 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 122 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-034
Description: MW-9 Matrix: Aqueous
Date Sampled:11/07/2019 0950 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2201 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
230
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.17
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
1.5
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
3.8
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
11
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
2.1
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
4.7
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
1.7
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.22
J
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
10
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
57
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 123 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-035
Description: MW-10 Matrix: Aqueous
Date Sampled:11/07/2019 1000 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1540 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00012 J 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 124 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-035
Description: MW-10 Matrix: Aqueous
Date Sampled:11/07/2019 1000 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/14/2019 2206 BNW
Prep Date Batch
11/10/2019 2054 35139
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
20
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.24
J
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
2.6
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
2.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.50
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
4.3
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
2.5
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
66
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 125 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-036
Description: MW-11 Matrix: Aqueous
Date Sampled:11/07/2019 0820 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1543 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00048 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 126 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-036
Description: MW-11 Matrix: Aqueous
Date Sampled:11/07/2019 0820 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/16/2019 0548 BPK
Prep Date Batch
11/12/2019 1338 35309
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
59
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
2.1
J
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
4.3
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
0.66
J
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
5.0
U
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.6
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
25
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 127 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-037
Description: MW-32 Matrix: Aqueous
Date Sampled:11/07/2019 0745 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2305 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.64
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.50
U
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,2-Dichloroethene
156-59-2
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 128 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-037
Description: MW-32 Matrix: Aqueous
Date Sampled:11/07/2019 0745 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2305 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
97 70-130
100 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 129 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-037
Description: MW-32 Matrix: Aqueous
Date Sampled:11/07/2019 0745 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1545 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00028 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 130 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-037
Description: MW-32 Matrix: Aqueous
Date Sampled:11/07/2019 0745 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/16/2019 0555 BPK
Prep Date Batch
11/12/2019 1338 35309
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
13
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.21
J
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
2.4
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
3.6
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
2.2
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
3.0
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 131 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-038
Description: MW-34 Matrix: Aqueous
Date Sampled:11/07/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1548 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.0016 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 132 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-038
Description: MW-34 Matrix: Aqueous
Date Sampled:11/07/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/16/2019 0613 BPK
Prep Date Batch
11/12/2019 1338 35309
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
190
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
1.7
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.96
B
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
31
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
4.0
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
26
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
5.0
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
16
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
1.5
J
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Sodium
7440-23-5
6020B
7300
400
150
ug/L
1
Thallium
7440-28-0
6020B
0.20
BJ
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
37
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
49
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 133 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-039
Description: MW-36 Matrix: Aqueous
Date Sampled:11/07/2019 0920 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1551 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00021 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 134 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-039
Description: MW-36 Matrix: Aqueous
Date Sampled:11/07/2019 0920 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/16/2019 0619 BPK
Prep Date Batch
11/12/2019 1338 35309
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
81
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
21
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
4.5
J
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
23
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.5
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
8.2
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.17
BJ
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
23
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
25
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 135 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-040
Description: MW-36d Matrix: Aqueous
Date Sampled:11/07/2019 0915 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method
Dilution Analysis Date Analyst
Prep Date
Batch
1 5030B 8260D
1 11/11/2019 2329 ALR1
35283
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Acetone
67-64-1
8260D
10
U
10
4.0
ug/L
1
Acrylonitrile
107-13-1
8260D
5.0
U
5.0
0.80
ug/L
1
Benzene
71-43-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromochloromethane
74-97-5
8260D
0.50
U
0.50
0.40
ug/L
1
Bromodichloromethane
75-27-4
8260D
0.50
U
0.50
0.40
ug/L
1
Bromoform
75-25-2
8260D
0.50
U
0.50
0.40
ug/L
1
Bromomethane (Methyl bromide)
74-83-9
8260D
0.50
U
0.50
0.40
ug/L
1
2-Butanone (MEK)
78-93-3
8260D
10
U
10
2.0
ug/L
1
Carbon disulfide
75-15-0
8260D
0.50
U
0.50
0.40
ug/L
1
Carbon tetrachloride
56-23-5
8260D
0.50
U
0.50
0.40
ug/L
1
Chlorobenzene
108-90-7
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroethane
75-00-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloroform
67-66-3
8260D
0.50
U
0.50
0.40
ug/L
1
Chloromethane (Methyl chloride)
74-87-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromo-3-chloropropane (DBCP)
96-12-8
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromochloromethane
124-48-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dibromoethane (EDB)
106-93-4
8260D
0.50
U
0.50
0.40
ug/L
1
Dibromomethane (Methylene bromide)
74-95-3
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,4-Dichloro-2-butene
110-57-6
8260D
2.0
U
2.0
0.40
ug/L
1
1,2-Dichlorobenzene
95-50-1
8260D
0.50
U
0.50
0.40
ug/L
1
1,4-Dichlorobenzene
106-46-7
8260D
0.51
0.50
0.40
ug/L
1
Dichlorodifluoromethane
75-71-8
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethane
75-34-3
8260D
3.0
0.50
0.40
ug/L
1
1,2-Dichloroethane
107-06-2
8260D
0.50
U
0.50
0.40
ug/L
1
1,1-Dichloroethene
75-35-4
8260D
0.50
U
0.50
0.40
ug/L
1
cis-1,2-Dichloroethene
156-59-2
8260D
4.5
0.50
0.40
ug/L
1
trans- 1,2-Dichloroethene
156-60-5
8260D
0.50
U
0.50
0.40
ug/L
1
1,2-Dichloropropane
78-87-5
8260D
0.50
U
0.50
0.40
ug/L
1
cis- 1,3-Dichloropropene
10061-01-5
8260D
0.50
U
0.50
0.40
ug/L
1
trans- 1,3-Dichloropropene
10061-02-6
8260D
0.50
U
0.50
0.40
ug/L
1
Ethylbenzene
100-41-4
8260D
0.50
U
0.50
0.40
ug/L
1
2-Hexanone
591-78-6
8260D
10
U
10
2.0
ug/L
1
Methyl iodide (lodomethane)
74-88-4
8260D
5.0
U
5.0
0.40
ug/L
1
4-Methyl-2-pentanone
108-10-1
8260D
10
U
10
2.0
ug/L
1
Methylene chloride
75-09-2
8260D
0.50
U
0.50
0.40
ug/L
1
Styrene
100-42-5
8260D
0.50
U
0.50
0.41
ug/L
1
1,1,1,2-Tetrachloroethane
630-20-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2,2-Tetrachloroethane
79-34-5
8260D
0.50
U
0.50
0.40
ug/L
1
Tetrachloroethene
127-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Toluene
108-88-3
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,1-Trichloroethane
71-55-6
8260D
0.50
U
0.50
0.40
ug/L
1
1,1,2-Trichloroethane
79-00-5
8260D
0.50
U
0.50
0.40
ug/L
1
Trichloroethene
79-01-6
8260D
0.50
U
0.50
0.40
ug/L
1
Trichlorofluoromethane
75-69-4
8260D
0.50
U
0.50
0.40
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank
E = Quantitation of
compound exceeded the calibration range
DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria
P = The RPD between two GC columns exceeds 40 %
J = Estimated result <
LOQ and > DL
H = Out of holding time W = Reported on wet weight basis
D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 136 of 238

Volatile Organic Compounds by GC/MS
Client:CDM Smith Laboratory ID:UK06022-040
Description: MW-36d Matrix: Aqueous
Date Sampled:11/07/2019 0915 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 5030B 8260D 1 11/11/2019 2329 ALR1 35283
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
1,2,3-Trichloropropane
96-18-4
8260D
0.50
U
0.50
0.40
ug/L
1
Vinyl acetate
108-05-4
8260D
5.0
U
5.0
1.2
ug/L
1
Vinyl chloride
75-01-4
8260D
0.50
U
0.50
0.40
ug/L
1
Xylenes (total)
1330-20-7
8260D
1.0
U
1.0
0.40
ug/L
1
Run 1 Acceptance
Surrogate
Q % Recovery Limits
Bromofluorobenzene
1,2-Dichloroethane-d4
Toluene-d8
94 70-130
96 70-130
101 70-130
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 137 of 238

CVAA
Client:CDM Smith Laboratory ID:UK06022-040
Description: MW-36d Matrix: Aqueous
Date Sampled:11/07/2019 0915 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/12/2019 1558 KSH2 11/12/2019 1004 35245
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Mercury 7439-97-6 7470A 0.00018 J 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 138 of 238

ICP-MS Metals
Client:CDM Smith Laboratory ID:UK06022-040
Description: MW-36d Matrix: Aqueous
Date Sampled:11/07/2019 0915 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method
1 3005A
Analytical Method Dilution Analysis Date Analyst
6020B 1 11/16/2019 0626 BPK
Prep Date Batch
11/12/2019 1338 35309
CAS
Analytical
Parameter
Number
Method
Result
Q
LOQ
DL
Units
Run
Antimony
7440-36-0
6020B
2.0
U
2.0
0.50
ug/L
1
Arsenic
7440-38-2
6020B
2.0
U
2.0
1.3
ug/L
1
Barium
7440-39-3
6020B
48
5.0
1.3
ug/L
1
Beryllium
7440-41-7
6020B
0.40
U
0.40
0.15
ug/L
1
Cadmium
7440-43-9
6020B
0.50
U
0.50
0.13
ug/L
1
Chromium
7440-47-3
6020B
5.0
U
5.0
1.3
ug/L
1
Cobalt
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L
1
Copper
7440-50-8
6020B
1.5
J
5.0
1.3
ug/L
1
Lead
7439-92-1
6020B
1.0
U
1.0
0.25
ug/L
1
Nickel
7440-02-0
6020B
1.9
J
5.0
1.3
ug/L
1
Selenium
7782-49-2
6020B
5.0
U
5.0
1.3
ug/L
1
Silver
7440-22-4
6020B
1.0
U
1.0
0.25
ug/L
1
Thallium
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L
1
Vanadium
7440-62-2
6020B
4.3
J
5.0
2.5
ug/L
1
Zinc
7440-66-6
6020B
9.6
J
10
2.5
ug/L
1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 139 of 238

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 140 of 238

Inorganic non-metals - MB
Sample ID: UQ34964-001 Matrix: Aqueous
Batch: 34964
Analytical Method: SM 2320B-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Alkalinity 20 U 1 20 20 mg/L 11/07/20191648
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 141 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ34964-002 Matrix: Aqueous
Batch: 34964
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 100 1 101 90-110 11/07/2019 1655
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 142 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - Duplicate
Sample ID: UK06022-012DU Matrix: Aqueous
Batch: 34964
Analytical Method: SM 2320B-2011
Sample
Amount Result % RPD
Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date
Alkalinity 120 120 1 2.1 20 11/07/2019 1821
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 143 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ34965-001 Matrix: Aqueous
Batch: 34965
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.20 mg/L 11/06/20191059
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 144 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ34965-002 Matrix: Aqueous
Batch: 34965
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 21 1 103 90-110 11/06/20191137
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 145 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-014MS Matrix: Aqueous
Batch: 34965
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 8.8 20 29 1 100 90-110 11/07/20191030
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 146 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-014MD Matrix: Aqueous
Batch: 34965
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Chloride 8.8 20 29 1 103 2.1 90-110 20 11/07/20191049
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 147 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ34967-001 Matrix: Aqueous
Batch: 34967
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/06/2019 1059
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 148 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ34967-002 Matrix: Aqueous
Batch: 34967
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.83 1 104 90-110 11/06/2019 1137
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 149 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-014MS Matrix: Aqueous
Batch: 34967
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.60 0.80 1.4 1 100 90-110 11/07/2019 1030
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 150 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-014MD Matrix: Aqueous
Batch: 34967
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Nitrate - N 0.60 0.80 1.4 1 100 0.00 90-110 20 11/07/2019 1049
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 151 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ34970-001 Matrix: Aqueous
Batch: 34970
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.20 mg/L 11/06/20191059
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 152 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ34970-002 Matrix: Aqueous
Batch: 34970
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 21 1 103 90-110 11/06/20191137
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 153 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-014MS Matrix: Aqueous
Batch: 34970
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 1.9 20 22 1 99 90-110 11/07/20191030
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 154 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-014MD Matrix: Aqueous
Batch: 34970
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfate 1.9 20 22 1 102 2.3 90-110 20 11/07/20191049
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 155 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35048-001 Matrix: Aqueous
Batch: 35048
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Chloride 1.0 U 1 1.0 0.20 mg/L 11/07/2019 2208
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 156 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35048-002 Matrix: Aqueous
Batch: 35048
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Chloride 20 20 1 102 90-110 11/08/2019 0020
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 157 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35049-001 Matrix: Aqueous
Batch: 35049
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/07/2019 2208
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 158 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35049-002 Matrix: Aqueous
Batch: 35049
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.82 1 102 90-110 11/08/2019 0020
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 159 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35051-001 Matrix: Aqueous
Batch: 35051
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfate 1.0 U 1 1.0 0.20 mg/L 11/07/2019 2208
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 160 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35051-002 Matrix: Aqueous
Batch: 35051
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfate 20 20 1 102 90-110 11/08/2019 0020
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 161 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35255-001 Matrix: Aqueous
Batch: 35255
Analytical Method: SM 531 OC-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
TOC 1.0 U 1 1.0 1.0 mg/L 11/13/20191756
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 162 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35255-002 Matrix: Aqueous
Batch: 35255
Analytical Method: SM 531 OC-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
TOC 20 20 1 98 90-110 11/13/20191809
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 163 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35290-001 Matrix: Aqueous
Batch: 35290
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 0.99 mg/L 11/11/20191822
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 164 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35290-002 Matrix: Aqueous
Batch: 35290
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 10 1 100 80-120 11/11/20191822
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 165 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35335-001 Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Parameter Result Q Dil LOQ DL Units Analysis Date
Nitrate - N 0.020 U 1 0.020 0.0050 mg/L 11/08/2019 2149
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 166 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35335-002 Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.80 0.81 1 101 90-110 11/09/2019 0058
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 167 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-013MS Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.90 0.80 1.7 1 100 90-110 11/09/2019 0214
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 168 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-013MD Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Nitrate - N 0.90 0.80 1.7 1 100 0.00 90-110 20 11/09/2019 0233
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 169 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-014MS Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Nitrate - N 0.61 0.80 1.4 1 99 90-110 11/09/2019 0311
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 170 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-014MD Matrix: Aqueous
Batch: 35335
Analytical Method: 300.0
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Nitrate - N 0.61 0.80 1.4 1 99 0.00 90-110 20 11/09/2019 0330
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 171 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35633-001 Matrix: Aqueous
Batch: 35633
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 0.99 mg/L 11/13/20191749
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 172 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35633-002 Matrix: Aqueous
Batch: 35633
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 10 1 101 80-120 11 /13/2019 1749
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 173 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-017MS Matrix: Aqueous
Batch: 35633
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 0.0 10 9.3 1 93 70-130 11/13/20191749
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 174 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-017MD Matrix: Aqueous
Batch: 35633
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfide 0.0 10 9.2 1 92 0.54 70-130 20 11/13/20191749
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 175 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35634-001 Matrix: Aqueous
Batch: 35634
Analytical Method: SM 4500-S2 F-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Sulfide 1.0 U 1 1.0 0.99 mg/L 11/13/20191818
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 176 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35634-002 Matrix: Aqueous
Batch: 35634
Analytical Method: SM 4500-S2 F-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 10 10 1 101 80-120 11 /13/2019 1818
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 177 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-018MS Matrix: Aqueous
Batch: 35634
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Sulfide 0.0 10 10 1 103 70-130 11/13/20191818
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 178 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-018MD Matrix: Aqueous
Batch: 35634
Analytical Method: SM 4500-S2 F-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Sulfide 0.0 10 9.7 1 97 5.9 70-130 20 11/13/20191818
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 179 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35742-001 Matrix: Aqueous
Batch: 35742
Analytical Method: SM 5220D-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
COD 20 U 1 20 20 mg/L 11/14/2019 2120
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 180 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35742-002 Matrix: Aqueous
Batch: 35742
Analytical Method: SM 5220D-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 40 40 1 100 95-105 11/14/2019 2120
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 181 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MS
Sample ID: UK06022-011 MS Matrix: Aqueous
Batch: 35742
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
COD 0.0 40 44 1 109 90-110 11/14/2019 2129
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 182 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MSD
Sample ID: UK06022-011 MD Matrix: Aqueous
Batch: 35742
Analytical Method: SM 5220D-2011
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
COD 0.0 40 41 1 104 5.1 90-110 20 11/14/2019 2130
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 183 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - MB
Sample ID: UQ35757-001 Matrix: Aqueous
Batch: 35757
Analytical Method: SM 2320B-2011
Parameter Result Q Dil LOQ DL Units Analysis Date
Alkalinity 20 U 1 20 20 mg/L 11/14/20191535
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 184 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - LCS
Sample ID: UQ35757-002 Matrix: Aqueous
Batch: 35757
Analytical Method: SM 2320B-2011
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Alkalinity 100 100 1 102 90-110 11/14/20191542
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 185 of 238
QC Data for Lot Number: UK06022

Inorganic non-metals - Duplicate
Sample ID: UK06022-016DU Matrix: Aqueous
Batch: 35757
Analytical Method: SM 2320B-2011
Sample
Amount Result % RPD
Parameter (mg/L) (mg/L) Q Dil % RPD Limit Analysis Date
Alkalinity 120 120 1 4.4 20 11/14/20191603
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 186 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35130-001 Matrix: Aqueous
Batch: 35130 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/09/2019 1402
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/09/2019 1402
Benzene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/09/2019 1402
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Dibromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,2-Dibromoethane (EDB)
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Dibromomethane (Methylene bromide)
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
trans- 1,4-Dichloro-2-butene
2.0
U
1
2.0
0.40
ug/L
11/09/2019 1402
1,2-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,4-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Dichlorodifluoromethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,1-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
2-Hexanone
10
U
1
10
2.0
ug/L
11/09/2019 1402
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/09/2019 1402
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/09/2019 1402
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Styrene
0.50
U
1
0.50
0.41
ug/L
11/09/2019 1402
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Toluene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 187 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35130-001 Matrix: Aqueous
Batch: 35130 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/09/2019 1402
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/09/2019 1402
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/09/2019 1402
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 95 70-130
1,2-Dichloroethane-d4 90 70-130
Toluene-d8 98 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 188 of 238

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35130-002
Matrix: Aqueous
Batch: 35130
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
110
1
107
60-140
11/09/2019 1244
Acrylonitrile
100
94
1
94
70-130
11/09/2019 1244
Benzene
50
47
1
94
70-130
11/09/2019 1244
Bromochloromethane
50
45
1
91
70-130
11/09/2019 1244
Bromodichloromethane
50
46
1
91
70-130
11/09/2019 1244
Bromoform
50
51
1
103
70-130
11/09/2019 1244
Bromomethane (Methyl bromide)
50
53
1
105
70-130
11/09/2019 1244
2-Butanone (MEK)
100
120
1
121
70-130
11/09/2019 1244
Carbon disulfide
50
47
1
94
70-130
11/09/2019 1244
Carbon tetrachloride
50
45
1
91
70-130
11/09/2019 1244
Chlorobenzene
50
48
1
97
70-130
11/09/2019 1244
Chloroethane
50
57
1
114
70-130
11/09/2019 1244
Chloroform
50
46
1
91
70-130
11/09/2019 1244
Chloromethane (Methyl chloride)
50
56
1
113
60-140
11/09/2019 1244
1,2-Dibromo-3-chloropropane (DBCP)
50
45
1
89
70-130
11/09/2019 1244
Dibromochloromethane
50
50
1
99
70-130
11/09/2019 1244
1,2-Dibromoethane (EDB)
50
48
1
97
70-130
11/09/2019 1244
Dibromomethane (Methylene bromide)
50
46
1
92
70-130
11/09/2019 1244
trans- 1,4-Dichloro-2-butene
50
47
1
95
70-130
11/09/2019 1244
1,2-Dichlorobenzene
50
46
1
91
70-130
11/09/2019 1244
1,4-Dichlorobenzene
50
45
1
90
70-130
11/09/2019 1244
Dichlorodifluoromethane
50
54
1
109
60-140
11/09/2019 1244
1,1-Dichloroethane
50
46
1
92
70-130
11/09/2019 1244
1,2-Dichloroethane
50
47
1
93
70-130
11/09/2019 1244
1,1-Dichloroethene
50
44
1
89
70-130
11/09/2019 1244
cis- 1,2-Dichloroethene
50
45
1
91
70-130
11/09/2019 1244
trans- 1,2-Dichloroethene
50
44
1
89
70-130
11/09/2019 1244
1,2-Dichloropropane
50
47
1
93
70-130
11/09/2019 1244
cis- 1,3-Dichloropropene
50
45
1
91
70-130
11/09/2019 1244
trans- 1,3-Dichloropropene
50
49
1
98
70-130
11/09/2019 1244
Ethylbenzene
50
48
1
97
70-130
11/09/2019 1244
2-Hexanone
100
110
1
113
70-130
11/09/2019 1244
Methyl iodide (lodomethane)
50
48
1
95
70-130
11/09/2019 1244
4-Methyl-2-pentanone
100
92
1
92
70-130
11/09/2019 1244
Methylene chloride
50
43
1
87
70-130
11/09/2019 1244
Styrene
50
48
1
97
70-130
11/09/2019 1244
1,1,1,2-Tetrachloroethane
50
49
1
97
70-130
11/09/2019 1244
1,1,2,2-Tetrachloroethane
50
49
1
98
70-130
11/09/2019 1244
Tetrachloroethene
50
50
1
100
70-130
11/09/2019 1244
Toluene
50
49
1
98
70-130
11/09/2019 1244
1,1,1-Trichloroethane
50
44
1
87
70-130
11/09/2019 1244
1,1,2-Trichloroethane
50
49
1
99
70-130
11/09/2019 1244
Trichloroethene
50
47
1
94
70-130
11/09/2019 1244
Trichlorofluoromethane
50
50
1
100
70-130
11/09/2019 1244
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 189 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35130-002
Matrix: Aqueous
Batch: 35130
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
45
1 90
70-130
11/09/2019 1244
Vinyl acetate
50
53
1 106
60-140
11/09/2019 1244
Vinyl chloride
50
54
1 109
70-130
11/09/2019 1244
Xylenes (total)
100
97
1 97
70-130
11/09/2019 1244
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 88 70-130
Toluene-d8 99 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 190 of 238

Volatile Organic Compounds by GC/MS - Duplicate
Sample ID: UK06022-001DU Matrix: Aqueous
Batch: 35130 Prep Method: 5030E
Analytical Method: 8260D
Sample
Amount
Result
% RPD
Parameter
(ug/L)
(ug/L)
Q
Dil
% RPD
Limit
Analysis Date
Acetone
ND
U
1
0.00
20
11/09/2019 1927
Acrylonitrile
ND
U
1
0.00
20
11/09/2019 1927
Benzene
0.41
U
1
0.00
20
11/09/2019 1927
Bromochloromethane
ND
U
1
0.00
20
11/09/2019 1927
Bromodichloromethane
ND
U
1
0.00
20
11/09/2019 1927
Bromoform
ND
U
1
0.00
20
11/09/2019 1927
Bromomethane (Methyl bromide)
ND
U
1
0.00
20
11/09/2019 1927
2-Butanone (MEK)
ND
U
1
0.00
20
11/09/2019 1927
Carbon disulfide
ND
U
1
0.00
20
11/09/2019 1927
Carbon tetrachloride
ND
U
1
0.00
20
11/09/2019 1927
Chlorobenzene
0.83
0.72
1
14
20
11/09/2019 1927
Chloroethane
ND
U
1
0.00
20
11/09/2019 1927
Chloroform
ND
U
1
0.00
20
11/09/2019 1927
Chloromethane (Methyl chloride)
ND
U
1
0.00
20
11/09/2019 1927
1,2-Dibromo-3-chloropropane (DBCP)
ND
U
1
0.00
20
11/09/2019 1927
Dibromochloromethane
ND
U
1
0.00
20
11/09/2019 1927
1,2-Dibromoethane (EDB)
ND
U
1
0.00
20
11/09/2019 1927
Dibromomethane (Methylene bromide)
ND
U
1
0.00
20
11/09/2019 1927
trans- 1,4-Dichloro-2-butene
ND
U
1
0.00
20
11/09/2019 1927
1,2-Dichlorobenzene
ND
U
1
0.00
20
11/09/2019 1927
1,4-Dichlorobenzene
0.77
0.78
1
0.78
20
11/09/2019 1927
Dichlorodifluoromethane
ND
U
1
0.00
20
11/09/2019 1927
1,1-Dichloroethane
ND
U
1
0.00
20
11/09/2019 1927
1,2-Dichloroethane
ND
U
1
0.00
20
11/09/2019 1927
1,1-Dichloroethene
ND
U
1
0.00
20
11/09/2019 1927
cis- 1,2-Dichloroethene
ND
U
1
0.00
20
11/09/2019 1927
trans- 1,2-Dichloroethene
ND
U
1
0.00
20
11/09/2019 1927
1,2-Dichloropropane
ND
U
1
0.00
20
11/09/2019 1927
cis- 1,3-Dichloropropene
ND
U
1
0.00
20
11/09/2019 1927
trans- 1,3-Dichloropropene
ND
U
1
0.00
20
11/09/2019 1927
Ethylbenzene
ND
U
1
0.00
20
11/09/2019 1927
2-Hexanone
ND
U
1
0.00
20
11/09/2019 1927
Methyl iodide (lodomethane)
ND
U
1
0.00
20
11/09/2019 1927
4-Methyl-2-pentanone
ND
U
1
0.00
20
11/09/2019 1927
Methylene chloride
ND
U
1
0.00
20
11/09/2019 1927
Styrene
ND
U
1
0.00
20
11/09/2019 1927
1,1,1,2-Tetrachloroethane
ND
U
1
0.00
20
11/09/2019 1927
1,1,2,2-Tetrachloroethane
ND
U
1
0.00
20
11/09/2019 1927
Tetrachloroethene
ND
U
1
0.00
20
11/09/2019 1927
Toluene
ND
U
1
0.00
20
11/09/2019 1927
1,1,1-Trichloroethane
ND
U
1
0.00
20
11/09/2019 1927
1,1,2-Trichloroethane
ND
U
1
0.00
20
11/09/2019 1927
Trichloroethene
ND
U
1
0.00
20
11/09/2019 1927
Trichlorofluoromethane
ND
U
1
0.00
20
11/09/2019 1927
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 191 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - Duplicate
Sample ID: UK06022-001DU Matrix: Aqueous
Batch: 35130 Prep Method: 5030E
Analytical Method: 8260D
Sample
Amount
Result
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil
% RPD
Limit
Analysis Date
1,2,3-Trichloropropane
ND
U
1
0.00
20
11/09/2019 1927
Vinyl acetate
ND
U
1
0.00
20
11/09/2019 1927
Vinyl chloride
ND
U
1
0.00
20
11/09/2019 1927
Xylenes (total)
ND
U
1
0.00
20
11/09/2019 1927
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 95 70-130
1,2-Dichloroethane-d4 89 70-130
Toluene-d8 100 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 192 of 238

Volatile Organic Compounds by GC/MS - MS
Sample ID: UK06022-003MS
Matrix: Aqueous
Batch: 35130
Prep Method: 5030E
Analytical Method: 8260D
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
0.0
100
56
N 1
56
60-140
11/09/2019 1949
Acrylonitrile
0.0
100
87
1
87
70-130
11/09/2019 1949
Benzene
0.0
50
49
1
97
70-130
11/09/2019 1949
Bromochloromethane
0.0
50
46
1
93
70-130
11/09/2019 1949
Bromodichloromethane
0.0
50
47
1
95
70-130
11/09/2019 1949
Bromoform
0.0
50
50
1
99
70-130
11/09/2019 1949
Bromomethane (Methyl bromide)
0.0
50
59
1
117
70-130
11/09/2019 1949
2-Butanone (MEK)
0.0
100
79
1
79
70-130
11/09/2019 1949
Carbon disulfide
0.0
50
52
1
103
70-130
11/09/2019 1949
Carbon tetrachloride
0.0
50
51
1
102
70-130
11/09/2019 1949
Chlorobenzene
0.0
50
49
1
97
70-130
11/09/2019 1949
Chloroethane
0.0
50
65
1
129
70-130
11/09/2019 1949
Chloroform
0.0
50
49
1
98
70-130
11/09/2019 1949
Chloromethane (Methyl chloride)
0.0
50
57
1
114
60-140
11/09/2019 1949
1,2-Dibromo-3-chloropropane (DBCP)
0.0
50
45
1
91
70-130
11/09/2019 1949
Dibromochloromethane
0.0
50
49
1
97
70-130
11/09/2019 1949
1,2-Dibromoethane (EDB)
0.0
50
46
1
92
70-130
11/09/2019 1949
Dibromomethane (Methylene bromide)
0.0
50
45
1
91
70-130
11/09/2019 1949
trans- 1,4-Dichloro-2-butene
0.0
50
44
1
89
70-142
11/09/2019 1949
1,2-Dichlorobenzene
0.0
50
48
1
96
70-130
11/09/2019 1949
1,4-Dichlorobenzene
0.0
50
46
1
91
70-130
11/09/2019 1949
Dichlorodifluoromethane
0.0
50
59
1
118
60-140
11/09/2019 1949
1,1-Dichloroethane
0.0
50
49
1
98
70-130
11/09/2019 1949
1,2-Dichloroethane
0.0
50
47
1
94
70-130
11/09/2019 1949
1,1-Dichloroethene
0.0
50
57
1
114
70-130
11/09/2019 1949
cis- 1,2-Dichloroethene
0.0
50
47
1
94
70-130
11/09/2019 1949
trans- 1,2-Dichloroethene
0.0
50
50
1
101
70-130
11/09/2019 1949
1,2-Dichloropropane
0.0
50
48
1
95
70-130
11/09/2019 1949
cis- 1,3-Dichloropropene
0.0
50
48
1
95
70-130
11/09/2019 1949
trans- 1,3-Dichloropropene
0.0
50
49
1
97
70-130
11/09/2019 1949
Ethylbenzene
0.0
50
49
1
98
70-130
11/09/2019 1949
2-Hexanone
0.0
100
96
1
96
70-130
11/09/2019 1949
Methyl iodide (lodomethane)
0.0
50
50
1
100
70-130
11/09/2019 1949
4-Methyl-2-pentanone
0.0
100
91
1
91
70-130
11/09/2019 1949
Methylene chloride
0.0
50
43
1
86
70-130
11/09/2019 1949
Styrene
0.0
50
49
1
98
70-130
11/09/2019 1949
1,1,1,2-Tetrachloroethane
0.0
50
51
1
101
70-130
11/09/2019 1949
1,1,2,2-Tetrachloroethane
0.0
50
48
1
96
70-130
11/09/2019 1949
Tetrachloroethene
0.0
50
51
1
101
70-130
11/09/2019 1949
Toluene
0.0
50
49
1
98
70-130
11/09/2019 1949
1,1,1-Trichloroethane
0.0
50
49
1
98
70-130
11/09/2019 1949
1,1,2-Trichloroethane
0.0
50
48
1
96
70-130
11/09/2019 1949
Trichloroethene
0.0
50
48
1
97
70-130
11/09/2019 1949
Trichlorofluoromethane
0.0
50
57
1
115
70-130
11/09/2019 1949
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 193 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - MS
Sample ID: UK06022-003MS
Matrix: Aqueous
Batch: 35130
Prep
Method: 5030E
Analytical Method: 8260D
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
1,2,3-Trichloropropane
0.0
50
45
1
90
70-130
11/09/2019 1949
Vinyl acetate
0.0
50
53
1
107
60-140
11/09/2019 1949
Vinyl chloride
0.0
50
54
1
109
70-130
11/09/2019 1949
Xylenes (total)
0.0
100
100
1
101
70-130
11/09/2019 1949
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 88 70-130
Toluene-d8 97 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 194 of 238

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35148-001 Matrix: Aqueous
Batch: 35148 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/10/2019 1118
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/10/2019 1118
Benzene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/10/2019 1118
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Dibromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,2-Dibromoethane (EDB)
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Dibromomethane (Methylene bromide)
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
trans- 1,4-Dichloro-2-butene
2.0
U
1
2.0
0.40
ug/L
11/10/2019 1118
1,2-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,4-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Dichlorodifluoromethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,1-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
2-Hexanone
10
U
1
10
2.0
ug/L
11/10/2019 1118
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/10/2019 1118
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/10/2019 1118
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Styrene
0.50
U
1
0.50
0.41
ug/L
11/10/2019 1118
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Toluene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 195 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35148-001 Matrix: Aqueous
Batch: 35148 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/10/2019 1118
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/10/2019 1118
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/10/2019 1118
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 96 70-130
1,2-Dichloroethane-d4 91 70-130
Toluene-d8 101 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 196 of 238

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35148-002
Matrix: Aqueous
Batch: 35148
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
110
1
107
60-140
11/10/2019 1012
Acrylonitrile
100
91
1
91
70-130
11/10/2019 1012
Benzene
50
46
1
92
70-130
11/10/2019 1012
Bromochloromethane
50
45
1
89
70-130
11/10/2019 1012
Bromodichloromethane
50
44
1
88
70-130
11/10/2019 1012
Bromoform
50
46
1
93
70-130
11/10/2019 1012
Bromomethane (Methyl bromide)
50
59
1
118
70-130
11/10/2019 1012
2-Butanone (MEK)
100
100
1
104
70-130
11/10/2019 1012
Carbon disulfide
50
51
1
102
70-130
11/10/2019 1012
Carbon tetrachloride
50
46
1
92
70-130
11/10/2019 1012
Chlorobenzene
50
46
1
91
70-130
11/10/2019 1012
Chloroethane
50
60
1
120
70-130
11/10/2019 1012
Chloroform
50
45
1
90
70-130
11/10/2019 1012
Chloromethane (Methyl chloride)
50
63
1
125
60-140
11/10/2019 1012
1,2-Dibromo-3-chloropropane (DBCP)
50
44
1
88
70-130
11/10/2019 1012
Dibromochloromethane
50
46
1
92
70-130
11/10/2019 1012
1,2-Dibromoethane (EDB)
50
45
1
90
70-130
11/10/2019 1012
Dibromomethane (Methylene bromide)
50
44
1
88
70-130
11/10/2019 1012
trans- 1,4-Dichloro-2-butene
50
46
1
91
70-130
11/10/2019 1012
1,2-Dichlorobenzene
50
44
1
88
70-130
11/10/2019 1012
1,4-Dichlorobenzene
50
42
1
84
70-130
11/10/2019 1012
Dichlorodifluoromethane
50
60
1
119
60-140
11/10/2019 1012
1,1-Dichloroethane
50
47
1
93
70-130
11/10/2019 1012
1,2-Dichloroethane
50
45
1
89
70-130
11/10/2019 1012
1,1-Dichloroethene
50
45
1
89
70-130
11/10/2019 1012
cis- 1,2-Dichloroethene
50
45
1
90
70-130
11/10/2019 1012
trans- 1,2-Dichloroethene
50
44
1
89
70-130
11/10/2019 1012
1,2-Dichloropropane
50
46
1
91
70-130
11/10/2019 1012
cis- 1,3-Dichloropropene
50
43
1
86
70-130
11/10/2019 1012
trans- 1,3-Dichloropropene
50
46
1
92
70-130
11/10/2019 1012
Ethylbenzene
50
46
1
92
70-130
11/10/2019 1012
2-Hexanone
100
94
1
94
70-130
11/10/2019 1012
Methyl iodide (lodomethane)
50
50
1
99
70-130
11/10/2019 1012
4-Methyl-2-pentanone
100
89
1
89
70-130
11/10/2019 1012
Methylene chloride
50
43
1
87
70-130
11/10/2019 1012
Styrene
50
46
1
92
70-130
11/10/2019 1012
1,1,1,2-Tetrachloroethane
50
49
1
99
70-130
11/10/2019 1012
1,1,2,2-Tetrachloroethane
50
47
1
95
70-130
11/10/2019 1012
Tetrachloroethene
50
46
1
92
70-130
11/10/2019 1012
Toluene
50
46
1
92
70-130
11/10/2019 1012
1,1,1-Trichloroethane
50
45
1
90
70-130
11/10/2019 1012
1,1,2-Trichloroethane
50
47
1
94
70-130
11/10/2019 1012
Trichloroethene
50
45
1
90
70-130
11/10/2019 1012
Trichlorofluoromethane
50
54
1
108
70-130
11/10/2019 1012
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 197 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35148-002
Matrix: Aqueous
Batch: 35148
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
42
1 84
70-130
11/10/2019 1012
Vinyl acetate
50
52
1 103
60-140
11/10/2019 1012
Vinyl chloride
50
60
1 120
70-130
11/10/2019 1012
Xylenes (total)
100
93
1 93
70-130
11/10/2019 1012
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 87 70-130
Toluene-d8 95 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 198 of 238

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35283-001 Matrix: Aqueous
Batch: 35283 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Acetone
10
U
1
10
4.0
ug/L
11/11/2019 1929
Acrylonitrile
5.0
U
1
5.0
0.80
ug/L
11/11/2019 1929
Benzene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Bromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Bromodichloromethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Bromoform
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Bromomethane (Methyl bromide)
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
2-Butanone (MEK)
10
U
1
10
2.0
ug/L
11/11/2019 1929
Carbon disulfide
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Carbon tetrachloride
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Chlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Chloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Chloroform
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Chloromethane (Methyl chloride)
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,2-Dibromo-3-chloropropane (DBCP)
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Dibromochloromethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,2-Dibromoethane (EDB)
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Dibromomethane (Methylene bromide)
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
trans- 1,4-Dichloro-2-butene
2.0
U
1
2.0
0.40
ug/L
11/11/2019 1929
1,2-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,4-Dichlorobenzene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Dichlorodifluoromethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,1-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,2-Dichloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,1-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
cis- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
trans- 1,2-Dichloroethene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,2-Dichloropropane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
cis- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
trans- 1,3-Dichloropropene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Ethylbenzene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
2-Hexanone
10
U
1
10
2.0
ug/L
11/11/2019 1929
Methyl iodide (lodomethane)
5.0
U
1
5.0
0.40
ug/L
11/11/2019 1929
4-Methyl-2-pentanone
10
U
1
10
2.0
ug/L
11/11/2019 1929
Methylene chloride
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Styrene
0.50
U
1
0.50
0.41
ug/L
11/11/2019 1929
1,1,1,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,1,2,2-Tetrachloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Tetrachloroethene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Toluene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,1,1-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
1,1,2-Trichloroethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Trichloroethene
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Trichlorofluoromethane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
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Page 199 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - MB
Sample ID: UQ35283-001 Matrix: Aqueous
Batch: 35283 Prep Method: 5030E
Analytical Method: 8260D
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
1,2,3-Trichloropropane
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Vinyl acetate
5.0
U
1
5.0
1.2
ug/L
11/11/2019 1929
Vinyl chloride
0.50
U
1
0.50
0.40
ug/L
11/11/2019 1929
Xylenes (total)
1.0
U
1
1.0
0.40
ug/L
11/11/2019 1929
Acceptance
Surrogate Q % Rec Limit
Bromofluorobenzene 94 70-130
1,2-Dichloroethane-d4 98 70-130
Toluene-d8 100 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 200 of 238

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35283-002
Matrix: Aqueous
Batch: 35283
Prep Method:
5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Acetone
100
98
1
98
60-140
11/11/2019 1804
Acrylonitrile
100
99
1
99
70-130
11/11/2019 1804
Benzene
50
49
1
99
70-130
11/11/2019 1804
Bromochloromethane
50
46
1
92
70-130
11/11/2019 1804
Bromodichloromethane
50
51
1
101
70-130
11/11/2019 1804
Bromoform
50
52
1
104
70-130
11/11/2019 1804
Bromomethane (Methyl bromide)
50
50
1
101
70-130
11/11/2019 1804
2-Butanone (MEK)
100
98
1
98
70-130
11/11/2019 1804
Carbon disulfide
50
48
1
96
70-130
11/11/2019 1804
Carbon tetrachloride
50
49
1
97
70-130
11/11/2019 1804
Chlorobenzene
50
48
1
96
70-130
11/11/2019 1804
Chloroethane
50
49
1
99
70-130
11/11/2019 1804
Chloroform
50
48
1
96
70-130
11/11/2019 1804
Chloromethane (Methyl chloride)
50
45
1
90
60-140
11/11/2019 1804
1,2-Dibromo-3-chloropropane (DBCP)
50
53
1
105
70-130
11/11/2019 1804
Dibromochloromethane
50
49
1
98
70-130
11/11/2019 1804
1,2-Dibromoethane (EDB)
50
48
1
96
70-130
11/11/2019 1804
Dibromomethane (Methylene bromide)
50
48
1
96
70-130
11/11/2019 1804
trans- 1,4-Dichloro-2-butene
50
51
1
102
70-130
11/11/2019 1804
1,2-Dichlorobenzene
50
50
1
101
70-130
11/11/2019 1804
1,4-Dichlorobenzene
50
49
1
98
70-130
11/11/2019 1804
Dichlorodifluoromethane
50
45
1
89
60-140
11/11/2019 1804
1,1-Dichloroethane
50
48
1
95
70-130
11/11/2019 1804
1,2-Dichloroethane
50
48
1
96
70-130
11/11/2019 1804
1,1-Dichloroethene
50
45
1
91
70-130
11/11/2019 1804
cis- 1,2-Dichloroethene
50
48
1
97
70-130
11/11/2019 1804
trans- 1,2-Dichloroethene
50
46
1
93
70-130
11/11/2019 1804
1,2-Dichloropropane
50
48
1
96
70-130
11/11/2019 1804
cis- 1,3-Dichloropropene
50
50
1
100
70-130
11/11/2019 1804
trans- 1,3-Dichloropropene
50
51
1
101
70-130
11/11/2019 1804
Ethylbenzene
50
49
1
98
70-130
11/11/2019 1804
2-Hexanone
100
110
1
106
70-130
11/11/2019 1804
Methyl iodide (lodomethane)
50
48
1
97
70-130
11/11/2019 1804
4-Methyl-2-pentanone
100
110
1
106
70-130
11/11/2019 1804
Methylene chloride
50
48
1
97
70-130
11/11/2019 1804
Styrene
50
51
1
102
70-130
11/11/2019 1804
1,1,1,2-Tetrachloroethane
50
49
1
98
70-130
11/11/2019 1804
1,1,2,2-Tetrachloroethane
50
49
1
99
70-130
11/11/2019 1804
Tetrachloroethene
50
48
1
97
70-130
11/11/2019 1804
Toluene
50
48
1
97
70-130
11/11/2019 1804
1,1,1-Trichloroethane
50
48
1
97
70-130
11/11/2019 1804
1,1,2-Trichloroethane
50
49
1
98
70-130
11/11/2019 1804
Trichloroethene
50
47
1
94
70-130
11/11/2019 1804
Trichlorofluoromethane
50
52
1
103
70-130
11/11/2019 1804
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 201 of 238
QC Data for Lot Number: UK06022

Volatile Organic Compounds by GC/MS - LCS
Sample ID: UQ35283-002
Matrix: Aqueous
Batch: 35283
Prep Method: 5030E
Analytical Method: 8260D
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
Limit
Analysis Date
1,2,3-Trichloropropane
50
48
1 97
70-130
11/11/2019 1804
Vinyl acetate
50
53
1 106
60-140
11/11/2019 1804
Vinyl chloride
50
48
1 96
70-130
11/11/2019 1804
Xylenes (total)
100
97
1 97
70-130
11/11/2019 1804
Surrogate
Q % Rec
Acceptance
Limit
Bromofluorobenzene 93 70-130
1,2-Dichloroethane-d4 95 70-130
Toluene-d8 93 70-130
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 202 of 238

Volatile Organic Compounds by GC/MS (SIM) - MB
Sample ID: UQ35540-001 Matrix: Aqueous
Batch: 35540 Prep Method: 5030E
Analytical Method: 8260B (SIM)
Parameter Result Q Dil LOQ DL Units Analysis Date
1,4-Dioxane 3.0 U 1 3.0 1.0 ug/L 11/13/2019 0952
Acceptance
Surrogate Q % Rec Limit
1,2-Dichloroethane-d4 107 40-170
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 203 of 238

Volatile Organic Compounds by GC/MS (SIM) - LCS
Sample ID: UQ35540-002
Matrix: Aqueous
Batch: 35540
Prep Method: 5030E
Analytical Method: 8260B (SIM)
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L) Q
Dil % Rec Limit Analysis Date
1,4-Dioxane
50
45
1 90 70-130 11/13/2019 0903
Surrogate
Q % Rec
Acceptance
Limit
1,2-Dichloroethane-d4 106 40-170
LOQ = Limit of Quantitation P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
DL = Detection Limit J = Estimated result < LOQ and > DL + = RPD is out of criteria
LOD = Limit of Detection U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06022
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 204 of 238

Dissolved Gases - MB
Sample ID: UQ34986-001 Matrix: Aqueous
Batch: 34986
Analytical Method: RSK - 175
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Ethane
10
U
1
10
2.5
ug/L
11/07/2019 2109
Ethene
10
U
1
10
2.5
ug/L
11/07/2019 2109
Methane
2.8
J
1
10
2.5
ug/L
11/07/2019 2109
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 205 of 238
QC Data for Lot Number: UK06022

Dissolved Gases - LCS
Sample ID: UQ34986-002 Matrix: Aqueous
Batch: 34986
Analytical Method: RSK - 175
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Ethane
550
650
1
117
70-130
11/07/2019 2030
Ethene
520
610
1
118
70-130
11/07/2019 2030
Methane
300
330
1
112
70-130
11/07/2019 2030
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 206 of 238
QC Data for Lot Number: UK06022

Dissolved Gases - LCSD
Sample ID: UQ34986-003 Matrix: Aqueous
Batch: 34986
Analytical Method: RSK - 175
Spike
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L) Q
Dil % Rec
% RPD
Limit
Limit
Analysis Date
Ethane
550
660
1 119
1.0
70-130
30
11/07/2019 2043
Ethene
520
610
1 119
0.97
70-130
30
11/07/2019 2043
Methane
300
330
1 113
1.6
70-130
30
11/07/2019 2043
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 207 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MB
Sample ID: UQ34766-001 Matrix: Aqueous
Batch:34766 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/06/2019 1706
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/15/20191916
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/15/20191916
Barium
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/15/20191916
Cadmium
0.50
U
1
0.50
0.13
ug/L
11/15/20191916
Chromium
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Copper
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Lead
1.0
U
1
1.0
0.25
ug/L
11/15/20191916
Nickel
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Selenium
5.0
U
1
5.0
1.3
ug/L
11/15/20191916
Silver
1.0
U
1
1.0
0.25
ug/L
11/15/20191916
Thallium
0.50
U
1
0.50
0.15
ug/L
11/15/20191916
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/15/20191916
Zinc
2.5
J
1
10
2.5
ug/L
11115/20191916
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 208 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - LCS
Sample ID: UQ34766-002
Matrix: Aqueous
Batch:34766
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/06/2019 1706
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Antimony
100
96
1 96
80-120
11/15/20191922
Arsenic
100
100
1 102
80-120
11/15/20191922
Barium
100
95
1 95
80-120
11/15/20191922
Beryllium
100
97
1 97
80-120
11/15/20191922
Cadmium
100
98
1 98
80-120
11/15/20191922
Chromium
100
96
1 96
80-120
11/15/20191922
Cobalt
100
93
1 93
80-120
11/15/20191922
Copper
100
100
1 103
80-120
11/15/20191922
Lead
100
100
1 104
80-120
11/15/20191922
Nickel
100
95
1 95
80-120
11/15/20191922
Selenium
100
100
1 103
80-120
11/15/20191922
Silver
100
98
1 98
80-120
11/15/20191922
Thallium
100
90
1 90
80-120
11/15/20191922
Vanadium
100
93
1 93
80-120
11/15/20191922
Zinc
100
110
1 107
80-120
11/15/20191922
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 209 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MS
Sample ID: UK06022-001 MS
Matrix: Aqueous
Batch:34766
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/06/2019 1706
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
92
1
92
70-130
11/15/20191934
Arsenic
0.0
100
92
1
92
70-130
11/15/20191934
Barium
46
100
140
1
98
70-130
11/15/20191934
Beryllium
0.38
100
92
1
91
70-130
11/15/20191934
Cadmium
0.84
100
92
1
92
70-130
11/15/20191934
Chromium
13
100
100
1
90
70-130
11/15/20191934
Cobalt
27
100
110
1
87
70-130
11/15/20191934
Copper
38
100
130
1
93
70-130
11/15/20191934
Lead
10
100
100
1
94
70-130
11/15/20191934
Nickel
8.9
100
94
1
85
70-130
11/15/20191934
Selenium
0.0
100
91
1
91
70-130
11/15/20191934
Silver
0.26
100
91
1
91
70-130
11/15/20191934
Thallium
0.18
100
92
1
92
70-130
11/15/20191934
Vanadium
26
100
110
1
86
70-130
11/15/20191934
Zinc
24
100
110
1
87
70-130
11/15/20191934
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 210 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MSD
Sample ID: UK06022-001 MD
Matrix: Aqueous
Batch:34766
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/06/2019 1706
Sample
Spike
Amount
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil % Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
92
1 92
0.27
70-130
20
11/15/20191941
Arsenic
0.0
100
93
1 93
1.5
70-130
20
11/15/20191941
Barium
46
100
140
1 98
0.21
70-130
20
11/15/20191941
Beryllium
0.38
100
92
1 91
0.094
70-130
20
11/15/20191941
Cadmium
0.84
100
92
1 92
0.052
70-130
20
11/15/20191941
Chromium
13
100
100
1 91
0.66
70-130
20
11/15/20191941
Cobalt
27
100
120
1 89
1.8
70-130
20
11/15/20191941
Copper
38
100
140
1 97
2.9
70-130
20
11/15/20191941
Lead
10
100
110
1 95
0.71
70-130
20
11 /15/2019 1941
Nickel
8.9
100
97
1 88
2.4
70-130
20
11/15/20191941
Selenium
0.0
100
91
1 91
0.050
70-130
20
11/15/20191941
Silver
0.26
100
92
1 92
1.0
70-130
20
11/15/20191941
Thallium
0.18
100
92
1 92
0.054
70-130
20
11/15/20191941
Vanadium
26
100
110
1 87
0.91
70-130
20
11/15/20191941
Zinc
24
100
110
1 90
2.4
70-130
20
11/15/20191941
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 211 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MS
Sample ID: UK06022-002MS
Matrix: Aqueous
Batch:34766
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/06/2019 1706
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
90
1
90
70-130
11/15/2019 2018
Arsenic
0.0
100
94
1
94
70-130
11/15/2019 2018
Barium
39
100
140
1
97
70-130
11/15/2019 2018
Beryllium
0.35
100
92
1
92
70-130
11/15/2019 2018
Cadmium
0.0
100
95
1
95
70-130
11/15/2019 2018
Chromium
6.0
100
98
1
92
70-130
11/15/2019 2018
Cobalt
1.7
100
92
1
90
70-130
11/15/2019 2018
Copper
10
100
110
1
99
70-130
11/15/2019 2018
Lead
5.3
100
100
1
98
70-130
11/15/2019 2018
Nickel
4.3
100
96
1
92
70-130
11/15/2019 2018
Selenium
0.0
100
91
1
91
70-130
11/15/2019 2018
Silver
0.0
100
95
1
95
70-130
11/15/2019 2018
Thallium
0.23
100
92
1
92
70-130
11/15/2019 2018
Vanadium
13
100
100
1
87
70-130
11/15/2019 2018
Zinc
24
100
120
1
94
70-130
11/15/2019 2018
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 212 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MB
Sample ID: UQ35139-001 Matrix: Aqueous
Batch: 35139 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/10/2019 2054
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/14/20191943
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/14/20191943
Barium
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/14/20191943
Cadmium
0.50
U
1
0.50
0.13
ug/L
11/14/20191943
Chromium
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Copper
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Lead
1.0
U
1
1.0
0.25
ug/L
11/14/20191943
Nickel
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Selenium
5.0
U
1
5.0
1.3
ug/L
11/14/20191943
Silver
1.0
U
1
1.0
0.25
ug/L
11/14/20191943
Sodium
400
U
1
400
150
ug/L
11/14/20191943
Thallium
0.50
U
1
0.50
0.15
ug/L
11/14/20191943
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/14/20191943
Zinc
10
U
1
10
2.5
ug/L
11/14/20191943
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 213 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - LCS
Sample ID: UQ35139-002
Matrix: Aqueous
Batch: 35139
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/10/2019 2054
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Antimony
100
95
1 95
80-120
11/14/20191948
Arsenic
100
97
1 97
80-120
11/14/20191948
Barium
100
99
1 99
80-120
11/14/20191948
Beryllium
100
100
1 100
80-120
11/14/20191948
Cadmium
100
100
1 100
80-120
11/14/20191948
Chromium
100
100
1 103
80-120
11/14/20191948
Cobalt
100
100
1 102
80-120
11/14/20191948
Copper
100
110
1 110
80-120
11/14/20191948
Lead
100
100
1 101
80-120
11 /14/2019 1948
Nickel
100
100
1 103
80-120
11/14/20191948
Selenium
100
110
1 107
80-120
11/14/20191948
Silver
100
100
1 100
80-120
11/14/20191948
Sodium
1000
1100
1 108
80-120
11/14/20191948
Thallium
100
100
1 100
80-120
11/14/20191948
Vanadium
100
100
1 102
80-120
11/14/20191948
Zinc
100
110
1 110
80-120
11/14/20191948
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 214 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MS
Sample ID: UK06022-035MS
Matrix: Aqueous
Batch: 35139
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/10/2019 2054
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
95
1
95
70-130
11/14/2019 2212
Arsenic
0.0
100
96
1
96
70-130
11/14/2019 2212
Barium
20
100
120
1
99
70-130
11/14/2019 2212
Beryllium
0.0
100
45
N 1
45
70-130
11/14/2019 2212
Cadmium
0.24
100
99
1
99
70-130
11/14/2019 2212
Chromium
0.0
100
100
1
101
70-130
11/14/2019 2212
Cobalt
2.6
100
100
1
99
70-130
11/14/2019 2212
Copper
2.6
100
110
1
107
70-130
11/14/2019 2212
Lead
0.50
100
100
1
100
70-130
11/14/2019 2212
Nickel
4.3
100
100
1
99
70-130
11/14/2019 2212
Selenium
2.5
100
100
1
101
70-130
11/14/2019 2212
Silver
0.0
100
100
1
100
70-130
11/14/2019 2212
Thallium
0.0
100
99
1
99
70-130
11/14/2019 2212
Vanadium
0.0
100
100
1
101
70-130
11/14/2019 2212
Zinc
66
100
170
1
101
70-130
11/14/2019 2212
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 215 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MSD
Sample ID: UK06022-035MD
Matrix: Aqueous
Batch: 35139
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/10/2019 2054
Sample
Spike
Amount
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil % Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
97
1 97
2.1
70-130
20
11/14/2019 2217
Arsenic
0.0
100
96
1 96
0.15
70-130
20
11/14/2019 2217
Barium
20
100
120
1 100
1.0
70-130
20
11/14/2019 2217
Beryllium
0.0
100
45
N 1 45
0.16
70-130
20
11/14/2019 2217
Cadmium
0.24
100
100
1 101
1.4
70-130
20
11/14/2019 2217
Chromium
0.0
100
100
1 101
0.40
70-130
20
11/14/2019 2217
Cobalt
2.6
100
100
1 99
0.20
70-130
20
11/14/2019 2217
Copper
2.6
100
110
1 109
1.8
70-130
20
11/14/2019 2217
Lead
0.50
100
100
1 101
1.2
70-130
20
11/14/2019 2217
Nickel
4.3
100
100
1 100
0.87
70-130
20
11/14/2019 2217
Selenium
2.5
100
100
1 100
0.78
70-130
20
11/14/2019 2217
Silver
0.0
100
100
1 101
0.89
70-130
20
11/14/2019 2217
Thallium
0.0
100
100
1 100
0.98
70-130
20
11/14/2019 2217
Vanadium
0.0
100
100
1 103
1.3
70-130
20
11/14/2019 2217
Zinc
66
100
170
1 104
1.8
70-130
20
11/14/2019 2217
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 216 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MB
Sample ID: UQ35309-001 Matrix: Aqueous
Batch: 35309 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/12/2019 1338
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Antimony
2.0
U
1
2.0
0.50
ug/L
11/16/2019 0530
Arsenic
2.0
U
1
2.0
1.3
ug/L
11/16/2019 0530
Barium
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Beryllium
0.40
U
1
0.40
0.15
ug/L
11/16/2019 0530
Cadmium
0.13
J
1
0.50
0.13
ug/L
11/16/2019 0530
Chromium
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Cobalt
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Copper
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Lead
1.0
U
1
1.0
0.25
ug/L
11/16/2019 0530
Nickel
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Selenium
5.0
U
1
5.0
1.3
ug/L
11/16/2019 0530
Silver
1.0
U
1
1.0
0.25
ug/L
11/16/2019 0530
Sodium
400
U
1
400
150
ug/L
11/16/2019 0530
Thallium
0.45
J
1
0.50
0.15
ug/L
11/16/2019 0530
Vanadium
5.0
U
1
5.0
2.5
ug/L
11/16/2019 0530
Zinc
10
U
1
10
2.5
ug/L
11/16/2019 0530
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 217 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - LCS
Sample ID: UQ35309-002
Matrix: Aqueous
Batch: 35309
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/12/2019 1338
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Antimony
100
94
1 94
80-120
11/16/2019 0536
Arsenic
100
100
1 104
80-120
11/16/2019 0536
Barium
100
95
1 95
80-120
11/16/2019 0536
Beryllium
100
97
1 97
80-120
11/16/2019 0536
Cadmium
100
95
1 95
80-120
11/16/2019 0536
Chromium
100
97
1 97
80-120
11/16/2019 0536
Cobalt
100
95
1 95
80-120
11/16/2019 0536
Copper
100
100
1 104
80-120
11/16/2019 0536
Lead
100
100
1 102
80-120
11/16/2019 0536
Nickel
100
96
1 96
80-120
11/16/2019 0536
Selenium
100
100
1 105
80-120
11/16/2019 0536
Silver
100
96
1 96
80-120
11/16/2019 0536
Sodium
1000
860
1 86
80-120
11/16/2019 0536
Thallium
100
90
1 90
80-120
11/16/2019 0536
Vanadium
100
94
1 94
80-120
11/16/2019 0536
Zinc
100
110
1 107
80-120
11/16/2019 0536
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 218 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MS
Sample ID: UK06022-04OMS
Matrix: Aqueous
Batch: 35309
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/12/2019 1338
Sample
Spike
Amount
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil
% Rec
Limit
Analysis Date
Antimony
0.0
100
90
1
90
70-130
11/16/2019 0632
Arsenic
0.0
100
97
1
97
70-130
11/16/2019 0632
Barium
48
100
140
1
91
70-130
11/16/2019 0632
Beryllium
0.0
100
88
1
88
70-130
11/16/2019 0632
Cadmium
0.0
100
91
1
91
70-130
11/16/2019 0632
Chromium
0.0
100
92
1
92
70-130
11/16/2019 0632
Cobalt
0.0
100
90
1
90
70-130
11/16/2019 0632
Copper
1.5
100
96
1
95
70-130
11/16/2019 0632
Lead
0.0
100
97
1
97
70-130
11/16/2019 0632
Nickel
1.9
100
90
1
88
70-130
11/16/2019 0632
Selenium
0.0
100
93
1
93
70-130
11/16/2019 0632
Silver
0.0
100
91
1
91
70-130
11/16/2019 0632
Thallium
0.0
100
91
1
91
70-130
11/16/2019 0632
Vanadium
4.3
100
94
1
89
70-130
11/16/2019 0632
Zinc
9.6
100
100
1
92
70-130
11/16/2019 0632
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 219 of 238
QC Data for Lot Number: UK06022

ICP-MS Metals - MSD
Sample ID: UK06022-04OMD
Matrix: Aqueous
Batch: 35309
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/12/2019 1338
Sample
Spike
Amount
Amount
Result
% Rec
% RPD
Parameter
(ug/L)
(ug/L)
(ug/L)
Q Dil % Rec % RPD
Limit
Limit
Analysis Date
Antimony
0.0
100
92
1 92
2.3
70-130
20
11/16/2019 0638
Arsenic
0.0
100
100
1 100
3.5
70-130
20
11/16/2019 0638
Barium
48
100
140
1 95
3.3
70-130
20
11/16/2019 0638
Beryllium
0.0
100
88
1 88
0.57
70-130
20
11/16/2019 0638
Cadmium
0.0
100
94
1 94
2.5
70-130
20
11/16/2019 0638
Chromium
0.0
100
95
1 95
3.4
70-130
20
11/16/2019 0638
Cobalt
0.0
100
93
1 93
3.4
70-130
20
11/16/2019 0638
Copper
1.5
100
100
1 99
3.8
70-130
20
11/16/2019 0638
Lead
0.0
100
99
1 99
2.1
70-130
20
11/16/2019 0638
Nickel
1.9
100
94
1 92
4.6
70-130
20
11/16/2019 0638
Selenium
0.0
100
94
1 94
0.88
70-130
20
11/16/2019 0638
Silver
0.0
100
93
1 93
2.1
70-130
20
11/16/2019 0638
Thallium
0.0
100
94
1 94
3.1
70-130
20
11/16/2019 0638
Vanadium
4.3
100
97
1 93
3.8
70-130
20
11/16/2019 0638
Zinc
9.6
100
100
1 94
2.0
70-130
20
11/16/2019 0638
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 220 of 238
QC Data for Lot Number: UK06022

CVAA -MB
Sample ID: UQ35243-001 Matrix: Aqueous
Batch: 35243 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury 0.000091 J 1 0.00020 0.000091 mg/L 11/12/20191745
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 221 of 238
QC Data for Lot Number: UK06022

CVAA - LCS
Sample ID: UQ35243-002 Matrix: Aqueous
Batch: 35243 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0020 0.0021 1 107 80-120 11/12/20191747
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 222 of 238
QC Data for Lot Number: UK06022

CVAA - MS
Sample ID: UK06022-001 MS Matrix: Aqueous
Batch: 35243 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.00017 0.0020 0.0020 1 92 85-115 11/12/20191752
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 223 of 238
QC Data for Lot Number: UK06022

CVAA - MSD
Sample ID: UK06022-001 MD Matrix: Aqueous
Batch: 35243 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Mercury 0.00017 0.0020 0.0021 1 97 4.6 85-115 20 11/12/20191800
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 224 of 238
QC Data for Lot Number: UK06022

CVAA -MB
Sample ID: UQ35245-001 Matrix: Aqueous
Batch: 35245 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Parameter Result Q Dil LOQ DL Units Analysis Date
Mercury 0.00020 U 1 0.00020 0.000091 mg/L 11/12/20191527
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 225 of 238
QC Data for Lot Number: UK06022

CVAA - LCS
Sample ID: UQ35245-002 Matrix: Aqueous
Batch: 35245 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.0020 0.0020 1 101 80-120 11/12/20191530
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 226 of 238
QC Data for Lot Number: UK06022

CVAA - MS
Sample ID: UK06022-034MS Matrix: Aqueous
Batch: 35245 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Sample Spike
Amount Amount Result % Rec
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Mercury 0.00022 0.0020 0.0017 N 1 72 85-115 11/12/20191535
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 227 of 238
QC Data for Lot Number: UK06022

CVAA - MSD
Sample ID: UK06022-034MD Matrix: Aqueous
Batch: 35245 Prep Method:
Analytical Method: 7470A Prep Date: 11/12/2019 1004
Sample Spike
Amount Amount Result % Rec % RPD
Parameter (mg/L) (mg/L) (mg/L) Q Dil % Rec % RPD Limit Limit Analysis Date
Mercury 0.00022 0.0020 0.0015 N 1 66 7.3 85-115 20 11/12/20191537
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 228 of 238
QC Data for Lot Number: UK06022

Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 229 of 238

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 230 of 238

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 231 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
Fht Envi+.gnr'nenal ` 'oes� lat. Page 1 id'.
Dvc.lmeutMwal:ci: MEN IRC-14 r.*CdVe Dr4e: &n,201 i
Sample. eipt Chocklist
Chem C-D- 1 SMITH Conler Ins mexi h !fl t,-, LF-H ? 11.06-2019 Lot #: UK"022
%'Ieans of recei Pt. El SF,$l -] Client UPS 0 FarlEr,
0 00i.tx,
❑ Yes
® Nol
11. Were custody seals present on the oaoleO
❑ Y.e
Noj
21 TEA 2. If custody seals were pfwerit, were they intact and tlnbmken?
pH Strip M, 19-2194 Clllorifle Strip Ti}; 19- I M7 Tcslnd by; LKH
Original temperature up&n receipt ii DerivedJS(-Corrco7t�cd) tmT peratjum upon receipt %Sa1id SaoLp-Cup [D, NA
2-0 /10 nC 2.4 jZA 'q-- I A iA ,C NA iNA q4
'Vletl7L1 = ®Tmmperatuec Blank ❑Against lioutles 1R Uin 1D: _.. 5 1R Gun Conwtion Fwtor: 0 eC
Vlct[,od ofemlant: W1 wtil. Ico ❑ kr, Fw:&s ❑ Diry Ice ❑ Nape —
❑ Yn
❑ No
21 NA
3, If tumperaturc al'any cooler exceeded 6.1 1'. %vas Project h,ianager-Notilied?
PNT Notified by. phone? email Iface-to-faee (chyle uile)L
® Yeas
❑ No
❑ NA
4- is the eommercia[ coorler's packing slip attachod to this form?
Yes
❑ No
5, Were propercustod� pubeedures (relinrluislitx[`rxxciucd) followed?
17 y1.
NO
6, here s�lnplc IDs listr�lvn tht: COC'?
® Yes
[l No
7, YWcm sample IDs 1 [sted on all swn ple urIrl laiTlMnr'
® Yes
❑Teo
8, Yr aS is olleotion date & time listed on the COC?
m Yes
0 N0
9- Was ec Electiort date & time lisLA on all sam pie container?
❑ files
❑Teo
10. Did all container label inform atiou (ID. date, tirr u) o- Lr= with iho COC?
0 Yes
❑ No
11. Were teas to be pertarmed ] isGad un thu COC`7
@i Yes
[� 1Jn
12- Did ;ill �m,plcs arrivrc in the proper cgrttai nm t4r h test an&or ki good zondition
,�unhmlrcn. Inds Oil. etc.p. .
'1'as
❑ No
11 Was adequaleIaunplc volume available,'
Yasi
❑ No
14. Were all samples recei wed within `r4 thrhold 'olgtimeor42 hours, whichever corn es first?
21 Yes
�l0
15. Wt re arty samphn containers missin aeRs circle clne scri3 les Not listed an COC?
® Yes
El No
❑ NA
145, I or VOA and RSK-175 samp[es, were hu le& prevent z�!" ('Ja"or 6mm irl diameter)
in any efthe VOA vials?
I Ybs
'ivlo
NA
17- Were all DRQ,rrnettl[sfnutrlent mrnpla-& received at a pi r of
Yes
ff No
NA
I $. Wem all cyanid e! sntrkplcs received at a pH > 12 aild sulfi& tampIcs received at: a p H > 9?
® 'Yes
❑ No
❑ NA
19. Wt ull upplicab]cNHV'J'K.NoeyaniUVpheno1f625 (<(,&n Q samples freea »Sr aril
C hlunnc?
❑ Yes
❑ Na
ON'
�D- 1kemQUentrcrnar&jvqumts (i.e. reque%teddiloons, MS, ISO desi:V2110113, etc..-)
currac.;tly tran%crihe,d f om the COC into the comment s, c on i n LAMS?
0 Yes
Na
2.. Was the quoltp nulnher listed an tha container label'? if yee, uote� 19190
Sample Pneserviatiou (1%11l stbe wuiplacd [ur any sampM's) iri=rectty Xreserved ar With headspace)
Sampka s) NA were rel:aiytxl itrcorrsatly pre3erved rtiW wel'e tldjusLLd ac x1ildingly
in sample rWc[viug with -NA mLofcirdre mu. MS04,1 03, Hal, NaQH using SR # NA
itne ofpawtNatiorl NA If mom than one pn:ser%ative is needed. plen5e mole in the oammelms Mnw.
5auiple(�) .j l I L J W-5wcro rece[v1&d with buhhles =6 Turn in diameter.
&nriptes(s) NA wm rt ocived with TPC =- 0,5 n4l (If 4119 is no) znd vvere
Mirlstcd accordingly in sample reaching with sodium th!oculfWr l a2S2%) with Shealy In-. NA _
SR burwde labels applied hi !. 1i�. Dalte;
C oraramts- WE RECEIVED TWO SEI'S OF VIALS FOR TWO TRIP CLANKS THAT ARE NOT T.191.1-11 UN THE COC
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 232 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 233 of 238

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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 234 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
shTUIY 6Wiremr=tal ticrvuCxai, 3nr
nrcumcnLNW31ber MbtQ19C-14 hate I a t
SH[I P16 Rfteipt Cheektist (SRC'} killivive ae�e er#�DiB
Client: C,D44 WITH C1c� Irss eeted bylr]ae_ ii ! J t,1fl7fl9 Lu[ [1kU[i022
Ftrij
cipr SESI Client Uf'S F dEx Odser: _
o [_ Note c:�MI.Vdy scale t on [bn -Daft s`?
Nt� NA12. Ifcu�todv seals wca,e rt were theytnrack and unlw acn?
19=1194 _ Ch lorine Su;tl 11D., t 9-1167 _ Tested trv; JSI
gPr-rZIraWy--C MP01n+�reecipt}I Derived (Corrcc�ted) remperature upon receipt %Solid 5nWCup ID_ NA
aC 2.1 =,1.f -C i11A FNA �' NA NA d
M-0hod: 0T9mpe3•aW" Stank ❑ �lgainnt Ilotdes TI{ Uun IT}: _ .3 IR Curt Correclic-n Factor: 0 OC
Method of cto[ai>t; 0 wet. lot ❑ lea Packs ❑ Dry lcc ❑ bone
❑ Yes i] Na ®'A 3, [frerrtrxmture crf any coolcreweexle l Cs.O°C, wtla Proje # Massager N tii"ied?
Ph! wayivtrtied by. phase f t Trail r tuctboo-tace [c[rc[e ortu),
Yes 0 No ❑ NA 4. Is the umnmercial Courier'; packing .0 ip anachW to this form?
Yes ❑ Nn 5_ ta4'ere prop-- custody edunca (me iyubh�!dvfe€ dL-) fM-t ,-d?
Y03 No 6. 5idceesample IDts listed on the LOC?
Yes ❑ No 7_ %VQre Saml, k IDS listed tm all saln le syuminers?
Yrs 21 NO 8_ W8s co Ift-Uun date & time listed an tho COC?
❑ Yes ONO I WT: eollection dote -& tine listed LIR all sarst.plc contairicrs_f
Yes ❑ %jo 10, Did all container Ia l informatiCM (ID, date, rime) use with the COC?
Yes ❑ No 11. Wtxc torts M he pertprmud listed on the CGK ?
YeS ❑ N-G 12. Did all Namiples ,�rdye in ill4 Pnnper Mjtai,srfr for each lnyt andFor in good condition
(un6rokos), lids rm, etc.}?
ls€I Ye$ I) T�lp 13. 1 Fay adequate mmp•]C uialuCnc at•,at]ablo?
Yes ®No [ �_ �l r:M al l samples received within :�a the Jsol dlr�v time or U hours, whichever cars ; f lstx
i Yes No 15- Wcm any sent les Lumtainer issilti zcess cit�la one ram left Nut listed -ryn C~
1 0 Yes ❑ No Q NA 1-6, For VOA avid R5 -175 ssamplas, wane bubbles V'6q nt >'•p -size- Ve';'ur 6mm [n diamel
I
In an of the VOA vials'?
i 91 Ye S No 71 NA 17, Were A DRO) metalshsutricnr samples rec vived at a H of : 2'?
® -Gs No Q NA 19 Were Ali �nidc say Istrl�s rece.1 vod at a pH > 12 aura suifidc SamPleg rccei►1ed at a pH > V,
Yes ❑o ❑ VA 19. 14'e1 aI apP icahts NHa, C. c}^aei a }� sr��IG625 {�. . utig+i,) ram plus ee of rest clef
® Yex, U N ❑ N. V4' 's oliertt rrmarks,�rtquests (i _c, r equestc� dilations MS�Tv1SD do siglsations, etc... l
�orrecily. transcri fi'om the COC; into th+r cossu n ept section in LlhiS? .
3`e4 —Ko "1_ Was 1}se uptC nwntw listed on the Container lab>el2 if yes, 2ricite iY 19190
aamPlr PnMCrV4tion (MI.Lst he eomplei xi for anv sfflnpL0() incorrwdy IA — —red d or with headspaca-
r '1° s) ---"re h ived inwri-ectly pxwnreri and were adjusted ar:cordiryr�ly
1 Sample receiving with NA _ml.ofpise1eone: H2_SCf4, DW)3, lIC;J, N&OH Cuing S]L01 NA
ime 0proavwion NA if moue thsan one pmetv.�liwe h netdod, ts[ease note iti the cnmltlents below,
am1ple(s)=0171T4+W-fr(I ),-01WMW-8D{2),-012fNW1V�'-5(3 } %vm tec ciYed with babbleh .
-�-C11nm in diameter,
ample4L,) RSA wens received with TRO > 0.5 mpt (If tt19 is juo) and wore
Ijusted acoordinglyv in sansp]e receiving -with sadiwn thiosuTfaldc (Na21;2Ut) with S1sa e1y 11): NA
R Fmrcode It&lsapplied by, JSTAIUMIJ DaW; 11?07f19
O mmtrits; MUSSING: KNO3 CON T.+4f_VFl{FOR MW-34(42t}l
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 235 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 236 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
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106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 237 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
Shealy l-rwhymnu7ml WLviOta. JW. Iaae I qr I
Do eni Nuabcv: MEW 1.8C-14 Effim ilv Dale: ErZW1$
Sample Receipt Checklist ( RQ
{`,lions: CDM SMf M Coolcr limpmed by date: i&H 111J04+I Lot = UI;O(+0221U}GU5U33
Leans 4f receipt. .; ❑ Clieait ❑ UPS m rtxiF.x 2 Other.
71 YeSl
23 Nol
11, Were cust*d}'sacalm p,rR, mrr on Ibc gaoler°
Yes
N,I,IZ
NA
2. If cu5t(ydy seals were eaent, wcr�, the intact and unbToken?
I I Snip li]_ 19-2194 Clllur iiw Strip ID: NA � `1`csted by 15H _
nginai WMPerahtre upM xcceilat r Derived (i oi-FtL.Atd) L-MPMtUW kTpCLD receipt %Solid Snap -Cup ID: NA
? ! 3_ aC NA ?IAA 7C NA INA °C NA ,+NA aG
blcthod: OTcissperaurre Blink OAgainst Botlles IR Cvll ID; 5 IR Chun CoL Trion factor 0 'U
M0110d of cupltr-al= 2 Wct toe ❑lee Packs ❑ DrY Foe ❑ Nalle —
❑ Y=i
❑ No
ONA
3_ It tcrttiprr+ttut? of any cablL-r ratc�secicri fi_0°C', }V»s Project Maan4ner N,tEflcd-?
Ply u'ar Notified by, phone et -mail r facr-to-face (oiicle one)_
® Ymi
❑ No
❑ NA
4. Ih the commercial ootiiier'�pw3ing zilip attachod m this form"
Yes
D NL'
5. WeTe ppuper Castody procedur�R (relthluished4w.aived) followtxl?
® Yos
11 No
6, Were Rample Mr, listed oil the Cam"?
0 yes
j] No
17. Were Hamplo ID5 listed on all sample rontainGi9?
0 yes
❑ NU
�, Was coil-vtaiium dnto do time listed oe the )
® Ycs
❑ No
19. Was enliflction date & time 1[gO op at11 sumpic containerf?
® Ycs
❑ 1d0
JO_ Did all urmininer 14ki i itbfinalion (ID„ date, tirl i) agree with aw C'ClCr'
0 Ycsi
No
1 l , Were tests ter be pmformc d listed cm, the Ct7C?
F✓'] Yes
Nv
12_ Laid all aamplcm PRrI,-T, i-n The proper ocmniner5 far mch test arrd+„r in t;md camdition
(tea -en' tid4 o11F -ew-y? ,
Yeaa
❑ No
13. Was adequate swtpk volume available:°
Yr
No
1+4. Wrrc all samples nbbnived within 1,i die. hohling time or 4,� Wpm, comas firs#?
Yes
VFNo
15, W= Roy samples C,m taincTA missing+exmss (circle cme} samples Nor listed on C:t?C 9 ...
e'er
Yr!6
❑7dn�Clillq"'
No
l
lfr. For VOA snd RSK-1? 5 samples„ wcx� bubbles present ?„pea -sire" (! "iar 6mm in diattretar j
.
in any at r]'te v0A vials`+
V. Were all DRCk?rritUhVntitricnl samples received nt a pH of •, 2'?
❑ Y--
No
0 NAI
1 R. Wem all 7aLnide samples received a4 u PH > 12 and NUIP3 a +carllla Icr, W.Ci{rod at a PEI r• +r"
r]
❑ No
❑ r'o
O NA
19, Were all (-<U.SiiWL) sannples tW o r,-%i j I
cltl rrrinr„
❑ Yus
0 NA
20_ R'cre clEcnt rawa-rk3i1Nucsts (i.e_ rrqumled dilutsmg, MSA 43T) designations„ etc„-)
Correctly traii5cAbed from the CDC into the ownment section in LIMS?
❑ Yes
1tia
2 I '.vm 117c uotc nuinber iisilod ore the contaiRe' label'? Il' eb. wtc k NA
Sian*
Preswersation (N4uct bo oompleted for auY ; ass tplu(s) iu=ctly preser'verl ,iT witli headspace-)
�d911i k(q) Vie► yvete C$ ived iIl Nmcct1v preserved and w" adjusced accol:li=_wly
in samplc rccanririg'Lrith 1%A MI, of circle One; H2$04, HNW, HCl. NaUli using SR # NA
ime of pm3cn°miov NA If nitre [than one prt!brP a{ive is nccd,-,d pleme nnm Iri tbly oDailtla=bel pve.
arnpre(s) -j4(}1J51Y- (2) wc,~ro rxviyad with buhbless >6 nun in diameter_
Sampim(s) _NA were re€civc cd with TRJC } 0.5 rnpeL (ff #19 is no) and were
Ajored accordiugly ill sample rc�xising with Radium thiosalfata (NkS-oO3) with Shealy ID: NA
SR b4nGNk latbcls applied3)r 15Fl{LKH Dais; 11-IN119
Crx=cats:
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 238 of 238

SHEALY ENVIRONMENTAL SERVICES, INC.
Report of Analysis
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleigh, NC 27612
Attention: Mathew Colone
Project Name: North Wake Unlined Landfill
Lot Number:UK06023
Date Completed:11/29/2019
11 /29/2019 2:00 PM
Approved and released by:
Project Manager: Cathy S. Dover
�p
nC C'itui'�tu
The electronic signature above is the equivalent of a handwritten signature.
This report shall not be reproduced, except in its entirety, without the written approval of Shealy Environmental Services, Inc.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 1 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
SC DHEC No: 32010001 NELAC No: E87653 NC DENR No: 329 NC Field Parameters No: 5639
Case Narrative
CDM Smith
Lot Number: UK06023
This Report of Analysis contains the analytical result(s) for the sample(s) listed on the Sample Summary
following this Case Narrative. The sample receiving date is documented in the header information
associated with each sample.
All results listed in this report relate only to the samples that are contained within this report.
Sample receipt, sample analysis, and data review have been performed in accordance with the most
current approved NELAC standards, the Shealy Environmental Services, Inc. ("Shealy") Quality
Assurance Management Plan (QAMP), standard operating procedures (SOPS), and Shealy policies. Any
exceptions to the NELAC standards, the QAMP, SOPS or policies are qualified on the results page or
discussed below.
If you have any questions regarding this report please contact the Shealy Project Manager listed on the
cover page.
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 2 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
Sample Summary
CDM Smith
Lot Number: UK06023
Project Name: North Wake Unlined Landfill
Project Number:
Sample Number
Sample ID
Matrix
Date Sampled
Date Received
001
MW-23
Aqueous
11/05/20191330
11/06/2019
002
MW-10D
Aqueous
11/05/20191400
11/06/2019
003
MW-6
Aqueous
11/07/2019 0855
11/08/2019
004
MW-8
Aqueous
11/07/2019 0835
11/08/2019
005
MW-9
Aqueous
11/07/2019 0950
11/08/2019
006
MW-10
Aqueous
11/07/20191000
11/08/2019
007
MW-11
Aqueous
11/07/2019 0820
11/08/2019
008
MW-32
Aqueous
11/07/2019 0745
11/08/2019
009
MW-34
Aqueous
11/07/2019 0845
11/08/2019
010
MW-36
Aqueous
11/07/2019 0920
11/08/2019
011
MW-36d
Aqueous
11/07/2019 0915
11/08/2019
(11 samples)
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 3 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-003
Description: MW-6 Matrix: Aqueous
Date Sampled:11/07/2019 0855 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1849 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
Dissolved Thallium
7440-48-4 6020B 77 5.0 1.3 ug/L 1
7440-28-0 6020B 0.32 J 0.50 0.15 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 5 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-004
Description: MW-8 Matrix: Aqueous
Date Sampled:11/07/2019 0835 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1855 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
Dissolved Vanadium
7440-48-4 6020B 1.5 J 5.0 1.3 ug/L 1
7440-62-2 6020B 2.6 J 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 6 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-005
Description: MW-9 Matrix: Aqueous
Date Sampled:11/07/2019 0950 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1901 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Thallium
Dissolved Vanadium
7440-28-0 6020B 0.21 J 0.50 0.15 ug/L 1
7440-62-2 6020B 6.7 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 7 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-006
Description: MW-10 Matrix: Aqueous
Date Sampled:11/07/2019 1000 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1907 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
7440-48-4 6020B 2.2 J 5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 8 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-007
Description: MW-11 Matrix: Aqueous
Date Sampled:11/07/2019 0820 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1913 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Vanadium
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 9 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-001
Description: MW-23 Matrix: Aqueous
Date Sampled:11/05/2019 1330 Project Name: North Wake Unlined Landfill
Date Received: 11 /06/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1842 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt
Dissolved Thallium
Dissolved Vanadium
7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1
7440-28-0 6020B 0.20 J 0.50 0.15 ug/L 1
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 4 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-008
Description: MW-32 Matrix: Aqueous
Date Sampled:11/07/2019 0745 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1919 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Cobalt 7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 10 of 25

CVAA
Client:CDM Smith Laboratory ID:UK06023-009
Description: MW-34 Matrix: Aqueous
Date Sampled:11/07/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 7470A 1 11/27/20191513 KSH2 11/26/20191721 37113
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Mercury
7439-97-6 7470A 0.00049 0.00020 0.000091 mg/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 11 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-009
Description: MW-34 Matrix: Aqueous
Date Sampled:11/07/2019 0845 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1926 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Chromium
Dissolved Cobalt
Dissolved Thallium
Dissolved Vanadium
7440-47-3
6020B
4.2
J
5.0
1.3
ug/L 1
7440-48-4
6020B
5.0
U
5.0
1.3
ug/L 1
7440-28-0
6020B
0.50
U
0.50
0.15
ug/L 1
7440-62-2
6020B
5.0
U
5.0
2.5
ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 12 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-010
Description: MW-36 Matrix: Aqueous
Date Sampled:11/07/2019 0920 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1944 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Chromium
Dissolved Cobalt
Dissolved Vanadium
7440-47-3 6020B 1.5 J 5.0 1.3 ug/L 1
7440-48-4 6020B 5.0 U 5.0 1.3 ug/L 1
7440-62-2 6020B 5.0 U 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 13 of 25

ICP-MS
Client:CDM Smith Laboratory ID:UK06023-011
Description: MW-36d Matrix: Aqueous
Date Sampled:11/07/2019 0915 Project Name: North Wake Unlined Landfill
Date Received: 11 /08/2019 Project Number:
Run Prep Method Analytical Method Dilution Analysis Date Analyst Prep Date Batch
1 3005A 6020B 1 11/26/2019 1950 BPK 11/25/2019 1113 36903
CAS Analytical
Parameter Number Method Result Q LOQ DL Units Run
Dissolved Vanadium
7440-62-2 6020B 4.0 J 5.0 2.5 ug/L 1
LOQ = Limit of Quantitation B = Detected in the method blank E = Quantitation of compound exceeded the calibration range DL = Detection Limit
U = Not detected at or above the DL N = Recovery is out of criteria P = The RPD between two GC columns exceeds 40 % J = Estimated result < LOQ and > DL
H = Out of holding time W = Reported on wet weight basis D = Dilution > 1
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 14 of 25

QC Summary
Shealy Environmental Services, Inc. QC Data for Lot Number: UK06023
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 15 of 25

ICP-MS - MB
Sample ID: UQ36903-001 Matrix: Aqueous
Batch: 36903 Prep Method: 3005A
Analytical Method: 6020B Prep Date: 11/25/2019 1113
Parameter
Result
Q
Dil
LOQ
DL
Units
Analysis Date
Dissolved Chromium
5.0
U
1
5.0
1.3
ug/L
11/26/2019 1830
Dissolved Cobalt
5.0
U
1
5.0
1.3
ug/L
11/26/2019 1830
Dissolved Thallium
0.50
U
1
0.50
0.15
ug/L
11/26/2019 1830
Dissolved Vanadium
5.0
U
1
5.0
2.5
ug/L
11/26/2019 1830
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 16 of 25
QC Data for Lot Number: UK06023

ICP-MS - LCS
Sample ID: UQ36903-002
Matrix: Aqueous
Batch: 36903
Prep Method: 3005A
Analytical Method: 6020B
Prep Date: 11/25/2019 1113
Spike
Amount
Result
% Rec
Parameter
(ug/L)
(ug/L)
Q Dil % Rec
Limit
Analysis Date
Dissolved Chromium
100
110
1 108
80-120
11/26/2019 1836
Dissolved Cobalt
100
110
1 108
80-120
11/26/2019 1836
Dissolved Thallium
100
97
1 97
80-120
11/26/2019 1836
Dissolved Vanadium
100
100
1 101
80-120
11/26/2019 1836
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 17 of 25
QC Data for Lot Number: UK06023

CVAA -MB
Sample ID: UQ37113-001 Matrix: Aqueous
Batch: 37113 Prep Method:
Analytical Method: 7470A Prep Date: 11/26/2019 1721
Parameter Result Q Dil LOQ DL Units Analysis Date
Dissolved Mercury 0.00020 U 1 0.00020 0.000091 mg/L 11/27/2019 1508
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 18 of 25
QC Data for Lot Number: UK06023

CVAA - LCS
Sample ID: UQ37113-002 Matrix: Aqueous
Batch: 37113 Prep Method:
Analytical Method: 7470A Prep Date: 11/26/2019 1721
Spike
Amount Result % Rec
Parameter (mg/L) (mg/L) Q Dil % Rec Limit Analysis Date
Dissolved Mercury 0.0020 0.0017 1 87 80-120 11/27/2019 1510
LOQ = Limit of Quantitation
DL = Detection Limit
LOD = Limit of Detection
P = The RPD between two GC columns exceeds 40 % N = Recovery is out of criteria
J = Estimated result < LOQ and > DL + = RPD is out of criteria
U = Not detected at or above the detection limit
Note: Calculations are performed before rounding to avoid round -off errors in calculated results
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 19 of 25
QC Data for Lot Number: UK06023

Chain of Custody
and
Miscellaneous Documents
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 20 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 21 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
$:7eel* EILVI:UIIOINIIIaI $ary iue Im P}af I of [
Vo umam `cumber. h4W0i9C. M �+ Effective Dipic 81i1'�GI
Sample Receipt CheckfiSt (SRC)
Client; CDM $MFTH CoAr hisImcled hy1daw LKH ' 11-06-2019 T.nt#; UK015022 IJ Z.
nsofmccipr: ❑ SFST Cliorit [IUPS FeJFX
O(ht�';
�fcs
FS
® _N()
1. Were a=asn" SnJs present on the moleO
Yes
No NA
2, If ustu J setals wt:rc sent, wem Oe � intact and nnbrolren7
trip IT]_ 19-2194 Chlorins Strip ID: 19-1867 Tested by, LK�-[
OrlgiInl temperature upon rccx pt; Derived (Garrected) temperatura uponreceipC NiSulid Snap -Cup ID= NA
40 r 2-0 cC 2A 1j2.4 aC -KA f KA ^C NA r A oC
Method ®1'etnperature Blaal€ ❑A�taira9t BOtClcs JK Gun 11J; IR Ckoi Correei nn Faelor, °C.
—
tafolhnci fcx plant: 'r�Jct Ice Ice f' ks ❑ T)ry rco El None
p Yes
❑ No
NA
If tempe-snare of any caolcr Lxceeded b-0°C, tivas Pro ect Nima [' Nuti lied?
PM was Notified by- plk me 1 amail f face-tD-face (ci ri' 1 e orpp).
Yes
❑ N10
❑TJA
4. is I is commaroial courier's parking slip sttached to dds; rurm?
Yes
❑ N(3
5, Wcrc proper cushy pmccduras ralinquishe dircmived) fol lowed?
Yes
1fn
6. Wcm sample IDs list on thuCOC 7
Yes
❑ No
+ Were sample IDs listed on all sample urnmjnors?
yes
[] Nij
8. %5 c y1lectiaal date & time listed on the C[ CI
Yes
❑ No
9- W&-; crtlloetlon date plc time listed wi all sample containers?
Yes
❑ Nat
1 D. Did all mrrtaimr lalx] informaEiau (lD, data, lime) asyee with tNL COO?
® Yo
❑ No
11. Were tesbj to bo performed Ii,%1W on the COC7
FO Yes
[I No
11 Did all samples arrivef in the proper ppntAin s far eac1T [esl:r�rr Ynrin g-Dod condition
(1a1113aokei), lido itn, etc-p
-
® YCS
ND
13. Wm ad wft sample volume available?
Y;
[] YD
14. 11v om all samples roccivcd w1thi n 'A il,c holding dine or 4-S hours, wh kficvor c ales
Yes
❑ Flo
15. Wm any sam les coutl�hers iyjssingrmcffs ]role aria) samples Not liz�tcd on C'S]L ;
® Y4e8
❑ o
❑ NA
IG. For VOA and RSK-175 sampler., were u 1cq prx�cat>~pea-size, (:" Gm },or min that iicl�r) 4
in any of the VQA vials?
® Y*
•Na
UNA
17. Weir, al DR.O/mr-tals,fnutrieut saMPlcw received at a pH of < 2'f
Yff
❑ No
© NA
H. Were all cyanide sample received at a pH ;�- t2"sulfide samples received at a pH -- 0
Ytrb
❑ Na
© NA
1 9- Were all applicabip, €VHy 'NLA'G -anideipheno]1625 (: 4.5n1$rL f sarnplcs e of residual
Dfiiorine7
d Yes
N
ONA
20, Imclietttren-grWrcquc3ts(i,e. reque and dilutions: MOINISD dcsignatione, etc.,.)
corroo ly ttamo ibcd from the C OC into the cairatient section in LIMS?
® Yes
No
7 I , Was the colt number listed {tie tin cuntairier label? If yes, Quote 4 19190
Soupple Preservation (1elast be conapietad for any s amplc(s) incrwrwl'4• preserwed of with hrads mo-_)
Si nple(s) NA were rcwivcd incorrectly prcw.-rvcd and �ue� x�d�tlst�d aocc}� eai��4;u
in sample rmciviug w i 11i NA mL of circle oneH2SC4, 4iNN, HC1, NaOH usi ng SR iy NA
ime of preac�rvalicn NA If more thw) ojw presuva#ive is neekd, please ante iTt the oommeots hel[>w,
rrmPlc(s) '' I ii j ? wets received with brtbblt=6 --6 mm in diaTncl,,7-
StaTn#k-3(s) NA svett received Witlt TRC �,- 0.5
adjusted accordingly in s&.mpk receiving, with sodivan 111ios41falr (Na,8,0j) with Shealy ID- NA
Sid barcnde lab t�] s appEied b, ,'_ _ L
Coilulmifz; WE RECTiSVT-,D TWO SETS OF VIALS FOR TWO TRIP BL-�NK S THAT AR-E NOT LISTED ON T14 COC
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 22 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
I
t.&
� 4:a41f4 i �'��1\�•"F
H o
VV
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ti
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.
i
ti
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 23 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
Q
8
403
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4
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SN SMY
Vh
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a
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1.6
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ad
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Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 24 of 25

SHEALY ENVIRONMENTAL SERVICES, INC.
spry FawonmCM13L semeds, fait. rh„r orl
i}C-C wraxnL NumlipT; ]I00,�C- 14 61r�1 ive Doha
�rrlpl� ]'receipt klc�c�list (���'�
Clieni: CDAI Sfw1 I'll i Coalcr hispecred byrdatc: JSy 1 I POW19 Imt . UKOW2210KQ6023
3-2
arts of rie SESI ❑ C'licnt ❑ UPS FedEx El Ordicr-
Yes VINC 1- Wexe Cw bDdy seals present on the cmler7
Yms No 10 3�1A 2- if r ugt,i seals wvCiC res�n it rn the [n#aet and ux,1?rvkcnfi
S trip ID: 19-2194 C'JA&ri w $ trip ID- NA 1 cs#od by. J$H
,inat feutpea- 1111-C Upan rWeipt. r Derived (Ctuzrrlod) tamparaftim upon receipt °'} ohd Snap -Cop ID: NA
_,+3.2 4C NA, ,NA ¢C NA /NA "C NA 1NA ac
hush 14'1-lxnper;Ltvm 8lartllc L]Agaimt liolties 1R Gun IID; 5 1& Chun Corrcctirm Factor: () `C;
I%vd of co-13lattt: or Ice ❑ lcs; Yachts ❑ PEY Ice ❑ Nunc
3 if t"m er m—P -.,1— 9
�] yes
❑Igo
0_A
- IP onvc c(uccu%A16.0 C,v,uPirojectI+funagcrNotixted?
PM aw NolJfied by. irhonc 1 r aLl i (airlcle otee).
Yrs
❑ No
❑NA
4, Is the onmrriw ial c4i ior's parkin%s]ip attached N 1U, form?
ifs
101 No
S. Wem custodyprocexlaurs {relit aiArCVr�xeiwd foliowed?
0 ices
❑ NO
b, WEm Rample, ]Ds listed an Ric OC
0 Yes
❑ ldo
17. Wer& skmmplc ID7s !fated on al[ sampla crmfaincf
® -yes
71 N13
R- Wss eoliachou date & d- ]idted om Ilae C OC?
o ycs
0 No
- Was ec`lleetion data & ti " linlnd an all sarrt to couatniner�?
o Yoe
❑ NO
1 I)- Did all conwiw labcl infnnmatic,u (ID, daLe, limo) agree with the COC.`s
0 Ytrt
❑ No
1 L Werc tests to be P=fan1wd listedcm the C-OCF
Ycs
❑ N"
12- DW all samples arr ivc in the fnr cFwh test avdror in goad umidi tiro,
(=broken, lids on, eto.)7
—
'
No
13. Ww' adcq Tale samplo xoJunie availabk?
ayG5
❑ No
14. 1Vcm all sartrl" rani }red wiGu ri the holding timc or 481toum ,whichever cares first?
❑ Yes
No
15. LVe_M airy sampitr contairlers mjasirs cxccss (win le cNTo) scut les Not ]% ttd on CCIC ?
0 Yes
❑ No
❑ N,
16. For VGA and l K-175 sairaplcs, were bubbW present >`pca-sizc" ('4"or 6mrn in dinaleu
31L any vfdw VOA vial s?
0 Yes
Iwlo
NA
17- Were Ql C RO/tneL.l�lnutncnt ie� rcoeived nt 4 pH of < 2''
19- Vu &-o all cyanide sautples ree-6 vcd at a phi �- 12 wKj snJfidc aamiAosccci vcd at a pH : 42
Yes
h-o
NA
❑ Yey
❑ No
® NA I
N- %Fero all app ica c .i KNeruyanidcc+phaaalrfs25 ( g ) samples ree of n a
.. . _
❑ Y� Q No 0 � IA �� ''Vere. c}ient r�uarksrreyttca4� {i,c. raqueste�i dilutia.tts, [�fS+h48IJ de<sigi,atinrra, etc, , . j
1wrfeck transrr]bed E+atn lho COC into the ovrttment sedum in LhAS7
Yes h1n I. WaA the MkOte 31u71lh{.T ;ist d r►tt tl]t Container Jlab l? r1 s, t loots # NA
a it' Pie Y reservstlou (Must be oompiated for fang Wrnplc(s) fftC nrrc by pre€e wW ar with head"cc )
ample(s) N,4 _ mere "c'Xivcd iria-n=tly presen?ed and wue adjusicd accord.i i.& y
i sample nrc6 `hig with NA mLof circle one: 1125Ct4, HNCI� , HCI, ltiaOB usin- SR y NA
ime crfprcaervation l�l. IPmtKc tlu�ri One p1 r ,^ative is i%e4M, please TIUW IIr the eommiMllS below.
ample(s}-001."SW-2 (2) were Tecci}red wiO; b;mbblos �,fi mTn in r[iamef,ar.
Awplas(s) NA v�Gre rbce7vtd %with TkC > 0-5 tagI (If ti14 is Tro) ffitd wana
dja111cl in sample iecaLvilkg x'ith SO
diutn 111i sulfate (N¢tz zDi) with Shealy ]D= N.
kbarm* labels app]iGd b): !SH?I_ 1S 1 Dale: I1,'09,'19 �—
Cormnants,
Shealy Environmental Services, Inc.
106 Vantage Point Drive West Columbia, SC 29172 [phone] Fax [phone] www.shealylab.com
Page 25 of 25

?ceAnalytical
i
November 26, 2019
Cathy Dover
Shealy Environmental Services, Inc.
106 Vantage Point Drive
West Columbia, SC 29172
RE: NORTH WAKE UNLINE LF
Pace Workorder. 32126
Dear Cathy Dover:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Thursday, November 14, 2019.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 11/26/2019
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 27
Page 1 of 21

Pace Analytical Energy Services LLC
220 William Pitt Way
2ceAnalyfica(. Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
�rl`p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 21

?ceAnalytical
i
SAMPLE SUMMARY
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Matrix
Date Collected
Date Received
321260001
M W-9
Water
11 /5/2019 15:45
11/14/2019 11:30
321260002
M W-10
Water
11 /5/2019 14:30
11/14/2019 11:30
321260003
M W-11
Water
11 /5/2019 12:00
11/14/2019 11:30
321260004
M W-36
Water
11 /5/2019 16:45
11/14/2019 11:30
321260005
M W-5R
Water
11/6/2019 12:15
11/14/2019 11:30
321260006
M W-6
Water
11/6/2019 14:15
11/14/2019 11:30
321260007
MW-8
Water
11/6/2019 08:45
11/14/2019 11:30
321260008
M W-34
Water
11/6/2019 11:00
11/14/2019 11:30
321260009
M W-34D
Water
11/6/2019 11:30
11/14/2019 11:30
321260010
MW-5R
Bubble Strip
11/6/2019 12:40
11/14/2019 11:30
321260011
MW-6
Bubble Strip
11/6/2019 14:39
11/14/2019 11:30
321260012
MW-8
Bubble Strip
11/6/2019 09:15
11/14/2019 11:30
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 3 of 21

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260001
Sample ID: MW-9
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/5/2019 15:45
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201919:09
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/19/201919:09
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201919:09
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201919:09
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201919:09
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201919:09
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201919:09
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201919:09
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/201919:09
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/19/201919:09
KB
Report ID: 32126 - 1230674 Page 4 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260002
Sample ID: MW-10
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/5/2019 14:30
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201920:02
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/19/201920:02
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201920:02
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201920:02
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201920:02
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201920:02
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201920:02
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201920:02
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/2019 20:02
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/19/201920:02
KB
Report ID: 32126 - 1230674 Page 5 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260003
Sample ID: MW-11
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/5/2019 12:00
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201920:55
KB
Acetic Acid
0.51 mg/I
0.10
0.028 1
11/19/201920:55
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201920:55
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201920:55
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201920:55
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201920:55
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201920:55
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201920:55
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/2019 20:55
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/19/201920:55
KB
Report ID: 32126 - 1230674 Page 6 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260004
Sample ID: MW-36
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/5/2019 16:45
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201921:49
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/19/201921:49
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201921:49
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201921:49
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201921:49
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201921:49
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201921:49
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201921:49
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/2019 21:49
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/19/201921:49
KB
Report ID: 32126 - 1230674 Page 7 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260005
Sample ID: MW-5R
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/6/2019 12:15
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201922:42
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/19/201922:42
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201922:42
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201922:42
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201922:42
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201922:42
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201922:42
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201922:42
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/2019 22:42
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/19/201922:42
KB
Report ID: 32126 - 1230674 Page 8 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260006
Sample ID: MW-6
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/6/2019 14:15
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/19/201923:35
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/19/201923:35
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/19/201923:35
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/19/201923:35
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/19/201923:35
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/19/201923:35
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/19/201923:35
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/19/201923:35
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/19/2019 23:35
KB
Hexanoic Acid
0.76 mg/I
0.20
0.010 1
11/19/201923:35
KB
Report ID: 32126 - 1230674 Page 9 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260007
Sample ID: MW-8
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/6/2019 08:45
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/20/201900:28
KB
Acetic Acid
0.14 mg/I
0.10
0.028 1
11/20/201900:28
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/20/201900:28
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/20/201900:28
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/20/201900:28
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/20/201900:28
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/20/201900:28
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/20/201900:28
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/20/2019 00:28
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/20/201900:28
KB
Report ID: 32126 - 1230674 Page 10 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260008
Sample ID: MW-34
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/6/2019 11:00
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/20/201901:22
KB
Acetic Acid
0.12 mg/I
0.10
0.028 1
11/20/201901:22
KB
Propionic Acid
0.21 mg/I
0.10
0.0040 1
11/20/201901:22
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/20/201901:22
KB B
Butyric Acid
0.29 mg/I
0.10
0.011 1
11/20/201901:22
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/20/201901:22
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/20/201901:22
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/20/201901:22
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/20/2019 01:22
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/20/201901:22
KB
Report ID: 32126 - 1230674 Page 11 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260009
Sample ID: MW-34D
Date Received: 11/14/2019 11:30 Matrix: Water
Date Collected: 11/6/2019 11:30
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
<0.20 mg/I
0.20
0.043 1
11/20/201902:15
KB
Acetic Acid
<0.10 mg/I
0.10
0.028 1
11/20/201902:15
KB
Propionic Acid
<0.10 mg/I
0.10
0.0040 1
11/20/201902:15
KB
Formic Acid
<0.50 mg/I
0.50
0.086 1
11/20/201902:15
KB B
Butyric Acid
<0.10 mg/I
0.10
0.011 1
11/20/201902:15
KB
Pyruvic Acid
<0.10 mg/I
0.10
0.0050 1
11/20/201902:15
KB
i-Pentanoic Acid
<0.10 mg/I
0.10
0.0060 1
11/20/201902:15
KB
Pentanoic Acid
<0.10 mg/I
0.10
0.0070 1
11/20/201902:15
KB
i-Hexanoic Acid
<0.20 mg/I
0.20
0.029 1
11/20/2019 02:15
KB
Hexanoic Acid
<0.20 mg/I
0.20
0.010 1
11/20/201902:15
KB
Report ID: 32126 - 1230674 Page 12 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260010 Date Received: 11/14/2019 11:30 Matrix: Bubble Strip
Sample ID: MW-5R Date Collected: 11/6/2019 12:40
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.5 nM 1.0 0.75 1 11/18/201914:37 TD n
Report ID: 32126 - 1230674 Page 13 of 21
CERTIFICATE OF ANALYSIS
�rl`p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260011 Date Received: 11/14/2019 11:30 Matrix: Bubble Strip
Sample ID: MW-6 Date Collected: 11/6/2019 14:39
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 3.0 nM 1.0 0.75 1 11/18/201914:50 TD n
Report ID: 32126 - 1230674 Page 14 of 21
CERTIFICATE OF ANALYSIS
�rl`p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 321260012 Date Received: 11/14/2019 11:30 Matrix: Bubble Strip
Sample ID: MW-8 Date Collected: 11/6/2019 09:15
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 1.5 nM 1.0 0.75 1 11/18/201915:02 TD n
Report ID: 32126 - 1230674 Page 15 of 21
CERTIFICATE OF ANALYSIS
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without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical
i
ANALYTICAL RESULTS QUALIFIERS
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
n The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
B The analyte was detected in the associated blank.
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 16 of 21

?ceAnalytical
QUALITY CONTROL DATA
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/7925 Analysis Method: AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 321260010, 321260011, 321260012
METHOD BLANK: 64437
Blank Reporting
Parameter Units Result Limit Qualifiers
RISK
Hydrogen nM <1.0 1.0 n
LABORATORY CONTROL SAMPLE & LCSD: 64438 64439
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers
Hydrogen nM 24 23 23 93 96 80-120 3.2 20 n
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
�rl`p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 17 of 21

?ceAnalytical
i
QUALITY CONTROL DATA
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: EDON/4275 Analysis Method: AM23G
QC Batch Method: AM23G
Associated Lab Samples: 321260001, 321260002, 321260003, 321260004, 321260005, 321260006, 321260007, 321260008, 321260009
METHOD BLANK: 64456
Blank Reporting
Parameter Units Result Limit Qualifiers
EDonors
Lactic Acid
mg/I
<0.20
0.20
Acetic Acid
mg/I
<0.10
0.10
Propionic Acid
mg/I
<0.10
0.10
Formic Acid
mg/I
<0.50
0.50 B
Butyric Acid
mg/I
<0.10
0.10
Pyruvic Acid
mg/I
<0.10
0.10
i-Pentanoic Acid
mg/I
<0.10
0.10
Pentanoic Acid
mg/I
<0.10
0.10
i-Hexanoic Acid
mg/I
<0.20
0.20
Hexanoic Acid
mg/I
<0.20
0.20
LABORATORY CONTROL SAMPLE:
64457
Spike
LCS
LCS
% Rec
Parameter
Units
Cone.
Result
% Rec
Limits
Qualifiers
Lactic Acid
mg/I
2
1.9
95
70-130
Acetic Acid
mg/I
2
1.8
89
70-130
Propionic Acid
mg/I
2
1.9
93
70-130
Formic Acid
mg/I
2
2.0
101
70-130
B
Butyric Acid
mg/I
2
1.9
95
70-130
Pyruvic Acid
mg/I
2
1.7
86
70-130
i-Pentanoic Acid
mg/I
2
1.9
96
70-130
Pentanoic Acid
mg/I
2
2.0
98
70-130
i-Hexanoic Acid
mg/I
2
2.0
100
70-130
Hexanoic Acid
mg/I
2
1.8
93
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 64458
64459
Original:
321330004
Original Spike
MS
MSD MS
MSD
% Rec Max
Parameter
Units
Result Cone.
Result
Result % Rec
% Rec
Limit RPD RPD Qualifiers
EDonors
Lactic Acid
mg/I
0.015 2
1.7
1.8 86
92
70-130 6.7 30
Acetic Acid
mg/I
0.026 2
1.9
1.9 93
93
70-130 0.54 30
Report ID: 32126 - 1230674
Page 18 of 21
CERTIFICATE OF ANALYSIS
ne""p
This report shall
not be reproduced,
except in full,
without the written consent
of Pace Analytical
Energy Services LLC.

?ceAnalytical
i
QUALITY CONTROL DATA
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
64458
64459
Original:
321330004
Original
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Cone.
Result
Result
% Rec
% Rec
Limit
RPD
RPD Qualifiers
Propionic Acid
mg/I
0.0017
2
1.9
1.9
97
95
70-130
1.7
30
Formic Acid
mg/I
0.37
2
2.1
2.1
86
87
70-130
0.82
30 B
Butyric Acid
mg/I
0.0027
2
2.0
2.0
98
98
70-130
0.13
30
Pyruvic Acid
mg/I
0.0001
2
1.7
1.7
85
87
70-130
1.6
30
i-Pentanoic Acid
mg/I
0
2
1.9
1.9
97
93
70-130
3.7
30
Pentanoic Acid
mg/I
0
2
2.0
1.8
99
92
70-130
7.5
30
i-Hexanoic Acid
mg/I
0
2
1.9
1.9
95
94
70-130
1.6
30
Hexanoic Acid
mg/I
0.0042
2
1.8
1.7
88
84
70-130
5.5
30
Report ID: 32126 - 1230674 Page 19 of 21
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.

?ceAnalytical @
QUALITY CONTROL DATA QUALIFIERS
Workorder: 32126 NORTH WAKE UNLINE LF
QUALITY CONTROL PARAMETER QUALIFIERS
The analyte was detected in the associated blank.
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
�rl`p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 20 of 21

?ceAnalytical
i
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 32126 NORTH WAKE UNLINE LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Prep Method Prep Batch Analysis Method
Analysis
Batch
321260010
MW-5R
AM20GAX
DISG/7925
321260011
MW-6
AM20GAX
DISG/7925
321260012
MW-8
AM20GAX
DISG/7925
321260001
MW-9
AM23G
EDON/4275
321260002
MW-10
AM23G
EDON/4275
321260003
MW-11
AM23G
EDON/4275
321260004
MW-36
AM23G
EDON/4275
321260005
MW-5R
AM23G
EDON/4275
321260006
MW-6
AM23G
EDON/4275
321260007
MW-8
AM23G
EDON/4275
321260008
MW-34
AM23G
EDON/4275
321260009
MW-34D
AM23G
EDON/4275
Report ID: 32126 - 1230674
CERTIFICATE OF ANALYSIS
ne""p This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 21 of 21

o
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Cooler Receipt Form
Client Name: Project: Lab Work Order: w°
A. Shipping/Container Information (circle appropriate response)
Courier: /'FedEx UPS LISPS Client Other: Air bill Present; Yes` No
s
Tracking dumber: 6'
n,.
Custody Seal on Cooler/Box Present: F Yes' No Seals Intact: Y'es.� No
Cooler/Box Packing Material: Bdbble WrapAbsorbent Foam Other:
Type of Ice:,/ Wet Blue None Ice Intact: "Yes %Melted
Cooler Temperature ` "C Radiation Screened: Yes /Ao Chain of Custody Present: 4es No
Comments:
B. Laboratory Assignment/Log-in (check appropriate response)
YES
NO
N/A
Comment
Reference non -Conformance
Chain of Custody properly filled out
Chain of Custody relinquished
Sampler Name & Signature on COC
Containers intact
Were samples in separate bags
Sample container labels match COC
Sample name/date and time collected
Sufficient volume provided
PAES containers used
Are containers properly preserved for the requested testing?
(as labeled)
If an unknown preservation state, were containers checked?
Exception: VOA's coliform
If yes, see pH form.
Was volume for dissolved testing field filtered, as noted on
the COC? Was volume received in a preserved container?
Headspace present?
Comments:
Cooler contents examined/received by: _ Date:
Project Manager Review : Date:
F-PAE-Q-009-rev.01, 30ct2017

NON-CONFORMANCE FORM
PAES Work Order
Date: Time of Receipt: Receiver:
Client:
REASON FOR NON-CONFORMANCE:
-------------
ACTION TAKEN:
Client name: Date: i 0 'rime:
Customer Service Initials: Date:
F-PAE-Q-014-rev.00, 20 Nov2014

Page 1 of 2
Joseph Ward - RE: North Wake Unline LF
From: Cathy Dover <[e-mail]>
To: Joseph Ward <Joseph. Ward@pacelabs. com>
Date: 11/14/2019 3:09 PM
Subject: RE: North Wake Unline LF
Hi Joseph,
Sorry for the discrepancies! Our sample receiving folks were supposed to double-check if the COC
and the vials matched before shipping...
For now, go with the COC time of 1645 for MW-36 and I will confirm the collection time with the
client.
IV!W-6 for dissolved hydrogen should be 14:39, but it was not written clearly on the COC from the
client.
Thanks for letting me know about the times! I will get back to you on the time for MW-36.
Have a great day!
Cathy
Cathy Dover
Project Manager
Shealy Environmental Services, Inc.
106 Vantage Point Drive
West Columbia, SC 29172
[phone] (direct)
[phone] cell
[phone] lab main #
From: Joseph Ward [[e-mail]]
Sent: Thursday, November 14, 2019 3:02 PM
To: Cathy Dover<[e-mail]>
Subject: North Wake Unline LF
Upon receiving your samples for the project referenced above, We noticed the following.
file:///C:/Users/jward/AppData/Local/Temp/XPGrpWise/5DCD6E27PACE DOMAINP... 11/14/2019

Page 2 of 2
Sample MW-36 the time of collection on the sample vials was 16:55 but on the COC it states the time of
collection is 16:45. Can you confirm the correct time of collection.
Sample MW-6 the time of collection on the sample vial was 14:35 but on the COC it states the time of
collection is 14:39. Can you confirm the correct time of collection.
Thank you
Joseph Ward
Customer Service
Pace Analytical Energy Services
220 William Pitt Way
Pittsburgh PA 15238
412-826-5245/412-826-2384(Direct)
NOTICE: The information contained in this email and any document attached hereto is intended
only for the named recipient(s). If you are not the intended recipient, nor the employee or agent
responsible for delivering this message in confidence to the intended recipient(s), you are hereby
notified that you have received this transmittal in error, and any review, dissemination, distribution
or copying of this transmittal or its attachments is strictly prohibited. If you have received this
transmittal and/or attachments in error, please notify me immediately by reply e-mail and then
delete this message, including any attachments.
file:///C:/Users/jward/AppData/Local/Temp/XPGrpWise/5DCD6E27PACE DOMAINP... 11/14/2019

Appendix B
Bacterial Analytical Data

0
microdialinsights
10515 Research Drive
Knoxville, TN 37932
Phone: [phone]
Fax: [phone]
Client: Mat Colone Phone: [phone]
CDM Smith
5400 Glenwood Avenue
Suite 400
Raleiqh, NC 27612 Fax:
Identifier: 027QK Date Rec: 11/07/2019 Report Date: 11/12/2019
Client Project #: 238209
Purchase Order #: North Wake Unlined LF
Analysis Requested: CENSUS
Reviewed By:
Client Project Name: North Wake Unlined Project
NOTICE: This report is intended only for the addressee shown above and may contain confidential or privileged information. If
the recipient of this material is not the intended recipient or if you have received this in error, please notify Microbial Insights, Inc.
immediately. The data and other information in this report represent only the sample(s) analyzed and are rendered upon
condition that it is not to be reproduced without approval from Microbial Insights, Inc. Thank you for your cooperation.
Page 1 of 3

MICROBIAL INSIGHTS, INC.
10515 Research Dr., Knoxville, TN 37932 CENSUS
Tel. [phone] Fax. [phone]
Client: CDM Smith MI Project Number: 027QK
Project: North Wake Unlined Project Date Received: 11/07/2019
Sample Information
Client Sample ID: MW-5R NWIW-5
Sample Date: 11/06/2019 11/06/2019
Units: cells/mL cells/mL
Analyst/Reviewer: HT HT
Dechlorinating Bacteria
Dehalococcoides
DHC
<5.00E-01
2.30E+00 (J)
tceA Reductase
TCE
<5.00E-01
1.40E+00 (J)
BAV1 Vinyl Chloride Reductase
BVC
<5.00E-01
<2.60E+00
Vinyl Chloride Reductase
VCR
<5.00E-01
<2.60E+00
Dehalobacter spp.
DHBt
<4.90E+00
3.00E+05
Dehalogenimonas spp.
DHG
<4.90E+00
6.52E+03
Desulfitobactedum spp.
DSB
<4.90E+00
2.46E+05
Desulfuromones spp.
DSM
9.25E+02
<2.56E+01
Legend:
NA = Not Analyzed NS = Not Sampled J = Estimated gene copies below PQL but above LQL
< = Result not detected
Page 2 of 3
I = Inhibited

Quality Assurance/Quality Control Data
Samples Received 11/7/2019
Arrival Positive Extraction Negative
Component Date Prepared Date Analyzed Temperature Control Blank Control
DHBt
11/07/2019
11/12/2019
0 °C
100%
non -detect
non -detect
DHG
11/07/2019
11/12/2019
0 °C
100%
non -detect
non -detect
DSB
11/07/2019
11/12/2019
0 °C
100%
non -detect
non -detect
DSM
11/07/2019
11/12/2019
0 °C
100%
non -detect
non -detect
DHC
11/07/2019
11/12/2019
0 °C
100%
non -detect
non -detect
BVC
11/07/2019
11/12/2019
0 °C
103%
non -detect
non -detect
TCE
11/07/2019
11/12/2019
0 °C
101%
non -detect
non -detect
VCR
11/07/2019
11/12/2019
0 °C
101%
non -detect
non -detect
Page 3of3