3902_Granville_Butner_MSWLF_GW_FID1378349_20191202

%ENR USE ONLY ❑Paper Report []Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR " Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
Butner Landfill State Road 1004 0
6, 2019
39-02 .1600 August 14, 2019
Butner, NC
September 4, 2019
Environmental Status: (Check all that apply)
Initial/Background Monitoring Detection Monitoring Assessment Monitoring �X Corrective Action
T e of data submitted: (Check all that apply)
X Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data
Groundwater monitoring data from private water supply wells ❑X Corrective action data (specify) MNA Data
Leachate monitoring data
X Surface water monitoring data Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach, Ph.D., PG Technical Consultant [phone]
Facili epee tiv a (Pri tle (Area Code) Telephone Number
Affix NC Licensed/ Professional Geologist Seal
Signature f 4�_ Date
2211 W. Meadowview Rd., Ste, 101 Greensboro, NC 27407 .l�_� `CFj�{SFA y'9
SEAL
1349 r
V
GAG �FOLOG�
Facility Representative Address
C-0782
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

Prepared For:
Granville County
Solid Waste Department
P.O. Box go6
Oxford, North Carolina 27565
r'o11�t� �F C*
A
Mi
774 •'
�ry''ATH .
h ....CAR�.a....+.+.
Submitted by:
LaBella Associates (Joyce Engineering)
2211 West Meadow/view Rd.
Suite 101
Greensboro, NC 27407
(336) 323-oog2
NC License No. C-0782
LaBeRa
Powered by partnership.
AUGUST 2019 SEMIANNUAL WATER QUALITY
MONITORING REPORT
BUTNER LANDFILL
Permit NO.39-02
NOVEMBER 2019
PROJECT NO. 21923S2.01.07

August 2019 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS
ACRONYMS
1.0 INTRODUCTION...........................................................................................................................
1.1 Site Information.........................................................................................................................
1.2 Site Geology................................................................................................................................
1.3 Regulatory Status.......................................................................................................................
2.0 FACILITY MONITORING PROGRAM............................................................................................
2.1 Groundwater Monitoring Program............................................................................................
2.2 Surface Water Monitoring Program..........................................................................................
3.0 AUGUST 2019 SEMIANNUAL SAMPLING EVENT......................................................................
3.1 Field Work...................................................................................................................................
3.2 Resampling Field Work..............................................................................................................
3.3 Laboratory Analyses and Quality Control..................................................................................
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES...............................................................
4.1 Analytical Results for Groundwater and Comparisons to Standards ......................................
4.1.1 Inorganic Analyses..........................................................................................................
4.1.2 Organic Analyses.............................................................................................................
4.2 Statistical Analyses....................................................................................................................
4.2.1 Statistical Methods.........................................................................................................
4.2.2 Results of Statistical Analyses.......................................................................................
4.3 Analytical Results for Surface Water and Comparisons to Standards ...................................
5.0 HYDROGEOLOGICAL CONDITIONS ............................................................................................
6.0 CORRECTIVE ACTION EVALUATION...........................................................................................
6.1 Monitored Natural Attenuation Parameters.............................................................................
6.2 Phytoremediation.......................................................................................................................
6.3 Evaluation of Plume Stability and Trends.................................................................................
7.0 CONCLUSIONS............................................................................................................................
8.0 REFERENCES..............................................................................................................................
1
1
1
1
2
2
3
3
3
4
4
5
5
5
5
6
6
6
6
6
7
7
7
8
Granville County - Butner Landfill, Permit No. 39-02 LaBella Associates
August 2019 Semiannual Water Quality Monitoring Report November 2019
i

Tables
Charts
Figure
August 2019 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (Continued)
Table 1 August 2019 Groundwater Elevations
Table 2 August 2019 Field Parameters
Table 3 August 2019 Detected Constituents in Groundwater and Surface Water
Table 4 August 2019 Exceedances of Groundwater Standards
Table 5 August 2019 Hydraulic Gradients and Groundwater Flow Velocities
Table 6 August 2019 Monitored Natural Attenuation Parameters
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time
Figure 1 Site Location Map
Drawings
Drawing 1 Groundwater Potentiometric Surface Map
Drawing 2 2019 Tree Survey
Appendices
Appendix A
Monitoring Well Construction Data
Appendix B
Field Data Logs
Appendix C
Laboratory Analytical Reports and Chains of Custody
Appendix D
Historical Groundwater Elevations
Appendix E
Historical Constituents in Groundwater
Appendix F
Historical Constituents in Surface Water
Appendix G
Historical Monitoring Natural Attenuation Parameters
Granville County - Butner Landfill, Permit No. 39-02 La Bella Associates
August 2019 Semiannual Water Quality Monitoring Report November 2019
ii

ACRONYMS
ACM Assessment of Corrective Measures (Report)
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site -specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
IMAC Interim maximum Allowable Concentration
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC213 North Carolina Surface Water Standards found in 15A NCAC 2B
NC2L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
0&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
RL Reporting Limit (for laboratory data)
SWS Solid Waste Section (of NCDENR/NCDEQ)
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)
Granville County - Butner Landfill, Permit No. 39-02 La Bella Associates
August 2019 Semiannual Water Quality Monitoring Report November 2019
iii

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the town of Butner, in Granville County, North Carolina (Figure 1). The Butner facility started
receiving solid waste prior to May 1973. Permit Number 39-02, was issued by the State of North
Carolina on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the
present, a small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.
In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the Butner
Landfill entered an Assessment Monitoring Program in December of 1997 as a result of detections
of volatile organic compounds and pesticides above Title 15A of the North Carolina Administrative
Code Subchapter 2L (NC2L) Groundwater Standards. An Assessment of Corrective Measures (ACM)
was initiated in 2003, and then suspended by North Carolina Department of Environment and
Natural Resources (NCDENR) [now the North Carolina Department of Environmental Quality
(NCDEQ)] since there had been no more NC2L exceedances. The Nature and Extent Study (NES) and
ACM recommenced in 2007 when apparent volatile organic compound (VOC) exceedances of the
NC2L Standards began to appear; however, they were again suspended when it was determined that
the apparent exceedances were not statistically significant increases (SSTs) above background. An
ACM was reinitiated after an exceedance of benzene in MW-2R in December 2012, and was
submitted to NCDENR in May 2013. Approval of the ACM was granted in a letter from NCDENR
dated June 27, 2013. A Corrective Action Plan (CAP) for monitored natural attenuation (MNA) plus
phytoremediation was submitted to NCDENR on May 23, 2014, and was approved by NCDENR on
June 18, 2014.
1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the area
consists of rolling hills that support farmland and forest. The majority of the landfill area is underlain
by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into greenish grey
foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford Formation
(conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina Slate Belt
felsic volcanic rocks. There is no exposure of the Sanford Formation at the site; however, float
material consisting of grey, coarse -grained sandstone with quartz pebbles was observed. Diabase
dikes have also been observed in the vicinity of the site. Geologic descriptions were taken from GAI
Consultants' Groundwater and Surface Water Monitoring System report (GAI, 1994).
1.3 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance with
NCSWMR §.1634-.1637. The site is currently in Assessment Monitoring and a Corrective Action
Monitoring Program. Groundwater samples are collected semiannually and analyzed in accordance
with the approved Corrective Action Plan. Surface water samples are collected and sampled for
Appendix I of 40 CFR Part 258, from here on known as North Carolina (NC) Appendix I list of
constituents during each sampling event.
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
1

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Seven active groundwater monitoring wells comprise the monitoring network at the Butner Landfill:
MW-1R (facility background well), MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1 (which was
installed as part of a Nature and Extent Study on November 14, 2007). The following table
summarizes the monitoring network and required analytical parameters. A summary of well
construction details is provided in Appendix A.
Groundwater Monitoring Network
Total
Lithology
1st SA
2nd SA
Monitoring
Date
Classification
Monitoring
Depth
of
Event
Event
Well
Installed
Program
ift)
Screened
Analyses
Analyses
Interval
App. I +
MW-1R
4/21/94
Background
Assessment/
45.1
Saprolite
App. I*,
Det. plus
CAMP
MNA
1,4-
Dioxane
App. I +
Compliance/
Assessment/
App.11,
Det. plus
MW-2R
4/12/94
CAMP
19.0
Saprolite
MNA
14
Performance
Dioxane,
MNA
App. I +
Compliance/
Assessment/
App.11,
Det. plus
MW-3R
4/14/94
CAMP
37.2
Bedrock
MNA
14
Performance
Dioxane,
MNA
App. I
MW-4
4/18/94
Compliance
Detection
31.5
Bedrock
App. I
plus 1,4-
Dioxane
App. I
MW-5
4/18/94
Compliance
Detection
23.4
Saprolite
App. I
plus 1,4-
Dioxane
Saprolite/
App. I
MW-6
4/19/94
Compliance
Detection
31.7
App. I
plus 1,4-
Bedrock
Dioxane
Nature &
Saprolite/
COCs,
NES-1
11/14/07
Extent
Sentinel
33.0
MNA*
COCs
Bedrock
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
2

Notes:
Ft = Feet
App. I = NCSWMR Appendix I list of constituents plus 1,4-Dioxane.
App. 11 = NCSWMR Appendix 11 list of constituents plus 1,4-Dioxane.
App. I + Det. = App. I list plus detected App. 11 constituents.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation parameters.
CAMP = Corrective Action Monitoring Plan.
Current Appendix II detected constituents: Tin.
Current COCs: Benzene, 1,4-dioxane, cobalt.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide will be
tested during both events every third year (next in 2022).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon
(TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane and ethene are analyzed
during both events every third year, which includes 2019 (next in 2022).
MNA parameters are only required annually for MW-1R & NES-1.
2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994, at the Butner
Landfill. The surface water sample points SW-1 and SW-2 are located respectively upstream and
downstream of the facility, along an unnamed tributary of Picture Creek. The surface water samples
are analyzed for the NC Appendix I list of constituents plus 1,4-dioxane during both semiannual
events.
3.0 August 2019 SEMIANNUAL SAMPLING EVENT
3.1 Field Work
On August 6-7, 2019, LaBella Associates PC (LaBella) personnel visited the Butner Landfill to purge
and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. All
monitoring wells were purged and sampled using new, disposable bailers or a submersible pump.
An electronic water level meter was used to take the depth to water to 0.01 foot. Calculated
groundwater elevations can be found in Table 1. Measurements of temperature, pH, turbidity,
dissolved oxygen, oxidation reduction potential (ORP), and conductivity were recorded in a field log.
Ferrous Iron was also measured for monitoring wells MW-2R and MW-3R for this sampling event and
recorded in the field log. Prior to sampling, laboratory -supplied containers were prepared with the
following information:
• Monitoring well number (completed by laboratory/field personnel),
• Date and time of sample collection (completed by laboratory/field personnel),
• Initials of sampling personnel (completed by laboratory/field personnel),
• Project name and number (completed by the laboratory/field personnel),
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
3

• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers or tubing
into the provided laboratory containers, within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory provided cooler and preserved on ice. Field Logs
are provided in Appendix B and field parameters are summarized in Table 2.
Surface water points SW-1 and SW-2 were also sampled during the August 6-7, 2019, event. Field
Logs are included in Appendix B and field parameters are summarized in Table 2.
3.2 Resampling Field Work
On August 14, 2019 LaBella Associates (LaBella) personnel were on site to resample well MW-6 for
VOCs due to a laboratory issue with the original samples. On September 4, 2019, LaBella personnel
were on site to resample well MW-3R for vinyl chloride due to an initial exceedance. The resampling
events followed the same protocol as described above.
3.3 Laboratory Analyses and Quality Control
Pace Analytical Services, Inc. of Huntersville, North Carolina, analyzed the August 2019, groundwater
and surface water samples under chain -of -custody control. The groundwater samples from
monitoring wells MW-1R, MW-2R, and MW-3R were analyzed for the Appendix 11 of 4CFR part 258
from here on known as NC Appendix II list of constituents, plus 1,4-dioxane. Groundwater samples
from monitoring wells MW-1R, MW-2R, MW-3R, and NES-1 were analyzed for MNA parameters.
Additionally, groundwater from monitoring well NES-1 was analyzed for benzene as a constituent of
concern. The groundwater samples from monitoring wells MW-4, MW-5, and MW-6 were analyzed
for the NC Appendix I list of constituents plus 1,4-Dioxane.
The surface water samples from SW-1 and SW-2 were analyzed for NC Appendix I constituents plus
1,4-dioxane. According to the Laboratory Sample Conditions and Verification reports, the samples
were received by the laboratory on August 9, 2019 in good condition, properly preserved, at proper
temperatures, and within analysis hold times.
In addition to samples collected for compliance monitoring at the Butner Landfill, LaBella personnel
collected a Field Blank for the August 2019 Semiannual Sampling Event as part of the Quality
Control/Quality Assurance program. The Field Blank was analyzed for the NC Appendix II
constituents plus 1,4-dioxane. Also, a Trip Blank that was prepared by the laboratory accompanied
the volatile sampling containers to and from the laboratory. The Trip Blank was analyzed for the NC
Appendix II volatile organic compounds plus 1,4-dioxane. A Equipment Blank was also collected by
LaBella personnel and was analyzed for the NC Appendix II constituents plus 1,4-dioxane. The
complete laboratory analytical reports are included in Appendix C.
Upon receipt of the laboratory data package, LaBella personnel reviewed the following data for:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
• Blank qualified data (B-flags);
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
4

• Detections above Groundwater Protection Standards (GPS) as defined in NCSWMR §
.1634(g), which are generally either the Groundwater Standards found in 15A NCAC 2L.0202
(NC2L), the Interim Maximum Allowable Concentrations (IMAC), or a NCDEQ-approved
statistical background value;
• Detections above NC Surface Water Standards established in 15A NCAC 2B (NC2B); and
• Detections that are above historical levels.
The complete laboratory analytical reports and the chains of custody from the August 2019
Semiannual Sampling Event are included in Appendix C. The historical groundwater elevation data
are presented in Appendix D. Historical analytical results for groundwater and surface water are
presented in Appendices E and F, respectively.
4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the method
detection limit (MDL) or practical quantitation limit (PQL) in one or more wells during the August
2019 semiannual sampling event: barium, cobalt, copper, nickel, vanadium, and tin. Table 3
summarizes all of the detections from the August 2019 semiannual sampling event.
Cobalt was detected in exceedance of the GWPS in MW-213 and MW-5. Vanadium was detected in
exceedance of the GWPS in MW-4. The result for cobalt in MW-2R and MW-5 is consistent with
historical data. Exceedances of groundwater standards from the August 2019 Semiannual Sampling
Event are summarized in Table 4.
No other inorganic constituents were detected above their NC2L/IMAC during the August 2019
semiannual sampling event. The laboratory analytical reports and the chains of custody are included
in Appendix C. Complete historical analytical results for inorganic constituents are included in
Appendix E.
4.1.2 Organic Analyses
Benzene, chlorobenzene, chloroethane, 1,2-dichlorobenzene, vinyl chloride, and 1,4-dioxane were
detected in one or more monitoring wells at quantified concentrations above the MRL or PQL during
the August 2019 sampling event. Table 3 summarizes all of the detections from the August 2019
Semiannual Sampling Event. These results are consistent with historical data as shown in Appendix
E.
1,4-dioxane was detected in exceedance of the NC21- standard in MW-2R, MW-3R, MW-4, and MW-5.
Benzene was detected above the NC21- Standard in MW-2R. The benzene in MW-2R is consistent
with historical data and has been addressed in the ACM, approved in June 2013, and the CAP,
approved in June 2014. Vinyl Chloride was detected in quantified concentrations above NC21-
standards in MW-3R; however, after resampling MW-3R on September 4, 2019, there was no
detection of vinyl chloride, so the initial exceedance was refuted. Exceedances of groundwater
standards from the August 2019 Semiannual Sampling Event are summarized in Table 4.
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
5

No other organic constituents were detected above their GPS during the August 2019 semiannual
sampling event. The laboratory analytical reports and the chains of custody are included in Appendix
C. Historical analytical results for organic constituents are presented in Appendix E.
4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up -gradient background well for the facility. Data from
MW-1R between September 1994 and August 2019 have been used to determine interwell
statistical background concentrations for constituents detected at the facility.
The background data are evaluated using the Shapiro-Francia Test of Normality, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction
Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the
background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one -tailed tests. The data are evaluated to
determine the appropriate procedure for calculation of the background value for each parameter.
4.2.2 Results of Statistical Analyses
No statistical analyses were performed for this event.
4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were sampled during the August 2019 Semiannual Sampling
Event. Three Appendix I constituents were detected above the MRL and MDL in the SW-1 and/or
SW-2 samples. Barium, nickel, and 1,4-dioxane were detected but were below NC213 standards. The
detections in surface water samples are included in Table 3 and historical surface water data are
presented in Appendix G.
5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks northeast
of the landfill. Groundwater flow direction at deeper levels within the fractured bedrock is controlled
by fracture orientation.
Depth to groundwater was measured in the compliance monitoring wells at the site prior to purging.
The groundwater elevations were calculated relative to the surveyed measuring point (top of casing)
for each monitoring well. A groundwater surface contour map, developed with static water level data
obtained on August 6, 2019, is presented as Drawing 1. The static water elevations depict
groundwater flow to the southeast. The historical groundwater elevations are summarized in
Table 1.
Horizontal groundwater gradients along a representative flow path was estimated from the August
2019 groundwater contours shown on Drawing 1 and are summarized in Table 5. The average
horizontal hydraulic gradient (i) across the site was approximately 0.0505.
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
6

Linear groundwater flow velocities were computed using the modified Darcy equation:
Where:
V = K►/ne
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from single
well aquifer test commonly known as slug -tests conducted in 1994 (GAI, 1994) was used in these
calculations. The average effective porosity (ne = 18%) based on 90% of reported total porosity for
soils (GAI, 1994). Although the regolith and bedrock are hydraulically connected, the effective
porosity generally decreases with depth into the underlying fractured bedrock. Groundwater flow
direction beneath the landfill is predominantly to the south and southeast. The calculated flow
velocity was 6.34 feet/year.
Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for this
site.
6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Monitoring wells MW-2R and MW-3R were analyzed for the following MNA parameters during the
August 2019 sampling event:
MNA Field Parameters: Temperature, pH, conductivity, oxidation reduction potential,
turbidity, dissolved oxygen, dissolved carbon dioxide and ferrous iron.
MNA Laboratory Parameters: Alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC), Volatile
Fatty Acids, methane, ethane, ethane, and dissolved hydrogen.
The current and historical MNA parameter data are presented in Table 6, and the laboratory
analytical report for MNA parameters for the August 2019 semiannual sampling event is included in
Appendix C. Based on response from NCSWMR to the first Corrective Action Evaluation Report
(CAER) submitted in December 2016, changes to the CAP were implemented starting with the
February 2017 event and the following parameters are now monitored during both sampling events
every third year (including 2019): Dissolved carbon dioxide, dissolved hydrogen, sulfide, volatile fatty
acids, dissolved methane, ethene, and ethane. The next time these parameters will be monitored
will be in February 2022.
6.2 Phytoremediation
The seventh phytoremediation tree survey for the Butner Landfill was conducted on August 12,
2019, and the results are presented in Drawing 2. The results indicate that the flora in the
remediation zone remain healthy and are adequate to significantly remediate organic compounds in
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
7

the shallow groundwater. The CAP requires annual tree surveys and the next survey is scheduled for
summer 2020.
6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006; however, from December 2006 to present, benzene in MW-2R has fluctuated
between 1 pg/l and 2 pg/l and shows a slight downward trend overall; however, the last few events
suggest a recent upward trend. Also, there is a possible seasonal fluctuation. From December 2007
to present, benzene in MW-3R has fluctuated between 0.3 pg/L and 0.7 pg/L and shows a slight
upward trend. Benzene in MW-4 has fluctuated between non -detect and 0.4 pg/L.
The benzene concentrations from the August 2019 Semiannual Sampling Event are within the range
of historical fluctuations. Since there have been no detections of benzene in either the surface
water or sentinel well NES-1, there is no indication that the plume in migrating toward the property
boundary. The plume appears to be stable or decreasing.
Chart 2 presents a plot of the cobalt concentrations versus time in the monitoring wells where it has
been detected in exceedance of the GPS (MW-2R and MW-5). Cobalt in MW-2R has ranged between
non -detection and 38.0 pg/l, but has been consistently between 8.3 and 10.7 pg/l since August
2014. Cobalt in MW-5 has fluctuated between non -detection and 251 pg/l, with large fluctuations
that appear to have a seasonal component (lower in winter and higher in summer); however, there
are inconsistencies (the highest historical concentration was in June 2002). There is no apparent
increasing or decreasing trend for cobalt in either well.
7.0 CONCLUSIONS
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site.
Benzene was detected above the NC2L in MW-2R during the August 2019 semiannual sampling
event. Review of MNA parameter data, plume stability, and benzene trends indicate that the
selected remedies of natural attenuation and phytoremediation are adequately controlling the
plume.
Cobalt was detected in MW-2R and MW-5 above its corresponding IMAC. This exceedance is
consistent with historical detections. Cobalt has been added to the COC list.
Vanadium was detected above the IMAC in MW-4. The exceedance is consistent with historical
detections. Vanadium was detected in MW-1R, MW-2R, MW-3R, and MW-5 but was below
quantifiable standards. An Alternate Source Demonstration (ASD) to determine the statistical
background for vanadium is recommended. If the vanadium in MW-4 is above the statistical
background, it should be added to the COC list.
1,4-dioxane was detected above the NC2L standard in MW-2R, MW-3R, MW-4, and MW-5. 1,4-
dioxane is not a constituent required by the NCSWMR, but was added as a required analyte by the
NCDEQ beginning in July 2018. 1,4-Dioxane has been added to the COC list.
The facility will remain in Assessment Monitoring and Corrective Action. The next semiannual
sampling event is tentatively scheduled for February 2020.
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
8

9.0 REFERENCES
GAI Consultants - NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System, Granville
County, Butner Landfill, NC Permit No. 39-02. June, 1994.
Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County, Permit
No. 39-02. May 2014.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN Natural
Attenuation Decision Support System User's Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington DC.
EPA/600/R-96/087. August 1996.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN Natural
Attenuation Decision Support System, Version 1.4 Revisions. United States Environmental
Protection Agency, Office of Research and Development, Washington DC. July 1997.
North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.
NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste
Management Facilities. March 2007.
August 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 November 2019
9

TABLES
Table 1 August 2019 Groundwater Elevations
Table 2 August 2019 Field Parameters
Table 3 Detected Constituents in Groundwater and Surface Water
Table 4 Exceedances of Groundwater Standards
Table 5 Hydraulic Gradients and Groundwater Flow Velocities
Table 6 Monitored Natural Attenuation Parameters

TABLE 1: August 2019 Groundwater Elevations
Location
Date
TOC Elevation
(Ft AMSL)
Depth to
Groundwater
(Ft BTOC)
Lithology
Well Depth
(Ft BTOC)
Groundwater
Elevation
(Ft AMSL)
MW-1R
2/4/2019
460.51
40.46
Bedrock
56
420.05
MW-2R
2/4/2019
331.60
2.25
Alluvial/
18.85
329.35
Residual
MW-31R
2/4/2019
330.96
2.59
Saprolite
35.83
328.37
MW-4
2/4/2019
340.80
7.82
Bedrock
31.43
332.98
MW-5
2/4/2019
343.88
14.15
Saprolite
23.52
329.73
MW-6
2/4/2019
362.53
11.07
Bedrock
32.63
351.46
NES-1
2/4/2019
328.40
18.06
Bedrock
32.8
310.34
Notes:
Butner Landfill, Granville County
Permit # 39-02
TOC = Top of casing
Ft = feet
BTOC = Below TOC AMSL = Above mean sea level
BGS = Below ground surface
LaBella Associates

TABLE 2: August 2019 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
pH
8.84
S.U.
Temperature
17.0
°C
Conductivity
113.4
PS/cm
Turbidity
3.71
NTU
3902-MW1R
8/7/2019
Dissolved Oxygen
3.77
mg/L
Oxidation Reduction Potential
164.7
mV
Static Water Level
40.46
ft
Well Depth
56.00
ft
pH
6.17
S.U.
Temperature
22.7
°C
Conductivity
1,719
PS/cm
Turbidity
5.66
NTU
Dissolved Carbon Dioxide
475
mg/L
3902-MW2R
8/6/2019
Dissolved Oxygen
0.32
mg/L
Ferrous Iron
3.5
mg/L
Oxidation Reduction Potential
-69.3
mV
Static Water Level
2.25
ft
Well Depth
18.85
ft
pH
6.49
S.U.
Temperature
17.6
°C
Conductivity
1,307
PS/cm
Turbidity
2.18
NTU
Dissolved Carbon Dioxide
250
mg/L
3902-MW3R
8/6/2019
Dissolved Oxygen
0.26
mg/L
Ferrous Iron
0.5
mg/L
Oxidation Reduction Potential
-33.7
mV
Static Water Level
2.59
ft
Well Depth
35.83
ft
pH
6.64
S.U.
Temperature
17.5
°C
Conductivity
1,557
PS/cm
Turbidity
2.24
NTU
3902-MW3R**
9/4/2019
Dissolved Oxygen
5.51
mg/L
Oxidation Reduction Potential
143.7
mV
Static Water Level
2.91
ft
Well Depth
35.83
ft
pH
6.69
S.U.
Temperature
19.9
°C
Conductivity
1,287
PS/cm
Dissolved Oxygen
4.55
mg/L
3902-MW4
8/6/2019
Oxidation Reduction Potential
171.6
mV
Turbidity
3.16
NTU
Static Water Level
7.82
ft
Well Depth
31.43
ft
LaBella Associates
Butner Landfill, Granville Co.
Permit No. 39-02 1 of 2

TABLE 2: August 2019 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
pH
7.44
S.U.
Temperature
17.3
°C
Conductivity
775
PS/cm
Turbidity
4.23
NTU
3902-MW5
8/6/2019
Dissolved Oxygen
5.30
mg/L
Oxidation Reduction Potential
188.6
mV
Static Water Level
14.15
ft
Well Depth
23.52
ft
pH
7.49
S.U.
Temperature
18.2
°C
Conductivity
545.3
PS/cm
Dissolved Oxygen
2.76
mg/L
3902-MW6
8/7/2019
Oxidation Reduction Potential
232.6
mV
Turbidity
6.91
NTU
Static Water Level
11.07
ft
Well Depth
32.63
ft
pH
6.47
S.U.
Temperature
24.3
°C
Conductivity
559
PS/cm
Dissolved Oxygen
1.95
mg/L
3902-MW6*
8/14/2019
Oxidation Reduction Potential
237.6
mV
Turbidity
3.54
NTU
Static Water Level
11.50
ft
Well Depth
32.63
ft
pH
6.79
S.U.
Temperature
16.0
°C
Conductivity
98.5
PS/cm
Turbidity
16.27
NTU
3902-NES1
8/7/2019
Dissolved Oxygen
3.04
mg/L
Oxidation Reduction Potential
231.8
mV
Static Water Level
18.06
ft
Well Depth
36.10
ft
pH
6.95
S.U.
Temperature
21.4
°C
Conductivity
577
PS/cm
3902-SW1
8/7/2019
Turbidity
10.10
NTU
Dissolved Oxygen
3.42
mg/L
Oxidation Reduction Potential
235.8
mV
pH
6.30
S.U.
Temperature
21.6
°C
Conductivity
786
PS/cm
3902-SW2
8/7/2019
Turbidity
5.88
NTU
Dissolved Oxygen
3.30
mg/L
Oxidation Reduction Potential
241.5
mV
Units: °C = degrees Centigrade pS/cm = micro-Seimens per centimeter
S.U. = Standard Units NTU = Nephelometric Turbidity Units
my = milivolts mg/L = miligrams per liter
Notes: * = Sample collected during 8/14/2019 resample
**= Sample collected during 9/4/2019 resample
LaBella Associates
Butner Landfill, Granville Co.
Permit No. 39-02 2 of 2

TABLE 3: Detected Constituents in Groundwater and Surface Water
SAMPLE
NC2L/*IMAC
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
NC213/*ISTV
DATE
MR-113
Barium
5.4
pg/L
1.0
5.0
700
8/7/2019
MR-1R
Vanadium
2.6 J
pg/L
1.3
5.0
0.3*
8/7/2019
MR-1R
Zinc
8.3 J
pg/L
3.9
10.0
1,000
8/7/2019
MW-2R
Barium
113
pg/L
1.0
5.0
700
8/6/2019
MW-2R
Cobalt
11.3
pg/L
1.1
5.0
1*
8/6/2019
MW-2R
Copper
3.5 J
pg/L
2.1
5.0
1,000
8/6/2019
MW-2R
Lead
2.0 J
pg/L
1.6
5.0
15
8/6/2019
MW-2R
Nickel
92.6
pg/L
0.90
5.0
100
8/6/2019
MW-2R
Tin
29.3
pg/L
1.6
5.0
2,000*
8/6/2019
MW-2R
Vanadium
4.1 J
pg/L
1.3
5.0
0.3*
8/6/2019
MW-2R
Benzene
1.7
pg/L
0.15
1.0
1
8/6/2019
MW-2R
Chlorobenzene
10.2
pg/L
0.23
1.0
50
8/6/2019
MW-2R
Chloroethane
0.94 J
pg/L
0.49
1.0
3,000
8/6/2019
MW-2R
1,2-Dichlorobenzene
0.62 J
pg/L
0.29
1.0
20
8/6/2019
MW-2R
1,4-Dioxane
98.1
pg/L
1.2
2.0
3
8/6/2019
MW-3R
Barium
73.8
pg/L
1.0
5.0
700
8/6/2019
MW-3R
Copper
6.0
pg/L
2.1
5.0
1,000
8/6/2019
MW-3R
Nickel
27.8
pg/L
0.90
5.0
100
8/6/2019
MW-3R
Tin
9.7
pg/L
1.6
5.0
2,000*
8/6/2019
MW-3R
Vanadium
1.9 J
pg/L
1.3
5.0
0.3*
8/6/2019
MW-3R
Benzene
0.54 J
pg/L
0.15
1.0
1
8/6/2019
MW-3R
Chlorobenzene
16.9
pg/L
0.23
1.0
50
8/6/2019
MW-3R
Chloroethane
1.9
pg/L
0.49
1.0
3,000
8/6/2019
MW-3R
1,2-Dichlorobenzene
1.2
pg/L
0.29
1.0
20
8/6/2019
MW-3R
Vinyl Chloride
1.1
pg/L
0.24
1.0
0.03
8/6/2019
MW-3R**
Vinyl Chloride
ND
pg/L
0.24
1.0
0.03
9/4/2019
MW-3R
1,4-Dioxane
51.7
pg/L
1.2
2.0
3
8/6/2019
VW-4
Barium
1.2 J
pg/L
1.0
5.0
700
8/6/2019
VW-4
Cadmium
0.48 J
pg/L
0.40
1.0
2
8/6/2019
VW-4
Copper
7.2
pg/L
2.1
5.0
1,000
8/6/2019
VW-4
Nickel
11.7
pg/L
0.90
5.0
100
8/6/2019
MW-4
Vanadium
22.1
pg/L
1.3
5.0
0.3*
8/6/2019
VW-4
Benzene
0.30 J
pg/L
0.15
1.0
1
8/6/2019
VW-4
Chloroethane
1.3
pg/L
0.49
1.0
3,000
8/6/2019
MW-4
1,4-Dioxane
32.7
pg/L
1.2
2.0
3
8/6/2019
VW-5
Barium
95.1
pg/L
1.0
5.0
700
8/6/2019
MW-5
Cobalt
127
pg/L
1.1
5.0
1*
8/6/2019
VW-5
Copper
4.4 J
pg/L
2.1
5.0
1,000
8/6/2019
VW-5
Nickel
18.7
pg/L
0.90
5.0
100
8/6/2019
VW-5
Vanadium
1.7 J
pg/L
1.3
5.0
0.3*
8/6/2019
MW-5
1,4-Dioxane
3.1
pg/L
1.2
2.0
3
8/6/2019
VW-6
Barium
1.9 J
pg/L
1.0
5.0
700
8/6/2019
VW-6
Copper
2.3 J
pg/L
2.1
5.0
1,000
8/6/2019
VW-6
Vanadium
2.4 J
pg/L
1.3
5.0
0.3*
8/6/2019
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 1 of 2

TABLE 3: Detected Constituents in Groundwater and Surface Water
SAMPLE
ID
PARAMETER
RESULT
UNITS
MDL
MRL
NC2L/*IMAC
NC2B/*ISTV
SAMPLE
DATE
SW-1
Barium
70
pg/L
1
5
21,000
8/7/2019
SW-1
Cobalt
2.5 J
pg/L
1.1
5
4*
8/7/2019
SW-1
Copper
3.2 J
pg/L
2.1
5
23.94
8/7/2019
SW-1
Lead
2.2 J
pg/L
1.6
5
8.58
8/7/2019
SW-1
Nickel
8.8
pg/L
0.9
5
137.6
8/7/2019
SW-1
Vanadium
1.4 J
pg/L
1.3
5
NE
8/7/2019
SW-1
Hardness, Total
316,000
pg/L
131
662
NE
8/7/2019
SW-1
1,4-Dioxane (p-Dioxane)
10.5
pg/L
1.2
2
80*
8/7/2019
SW-2
Barium
94.4
pg/L
1
5
21,000
8/7/2019
SW-2
Copper
3.3 J
pg/L
2.1
5
32.9
8/7/2019
SW-2
Nickel
14.8
pg/L
0.9
5
189.13
8/7/2019
SW-2
Vanadium
2.3 J
pg/L
1.3
5
NE
8/7/2019
SW-2
Hardness, Total
460,000
pg/L
655
3310
NE
8/7/2019
SW-2
1,4-Dioxane (p-Dioxane)
22.3
pg/L
1.2
2
80*
8/7/2019
NOTES: All Results in micorgrams per liter (pg/L)
MDL = Method Detection Level .
MRL = Method Reporting Limit.
J = Estimated concentration below the MRL.
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
*IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
NC2B = NC Surface Water Standard from 15A NCAC 2B (lowest of the Aquatic Life or Fish Consumption Standards).
(for copper, lead, & nickel, the NC213 is dependant on hardness.)
*ISPV = NC In -stream Protective Values (for constituents with no NC2b).
NE = No established standard.
NA= Not applicable.
Bold = GPS Exceedance.
**= Confirmation Sample collected on 9/4/19 (resample).
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 2 of 2

TABLE 4: Exceedances of Groundwater Standards
WED L
SDATEE
PARAMETER
RESULT
UNITS
MDL
MRL
NC2L/*IMAC
MW-2R
Cobalt
11.3
pg/L
1.1
5.0
1*
8/6/2019
MW-2R
Benzene
1.7
pg/L
0.15
1.0
1
8/6/2019
MW-2R
1,4-Dioxane
98.1
pg/L
1.2
2.0
3
8/6/2019
MW-3R
Vinyl Chloride
1.1
pg/L
0.24
1.0
0.03
8/6/2019
MW-3R**
Vinyl Chloride
ND
pg/L
0.24
1.0
0.03
9/4/2019
MW-3R
1,4-Dioxane
51.7
pg/L
1.2
2.0
3
8/6/2019
MW-4
Vanadium
22.1
pg/L
1.3
5.0
0.3*
8/6/2019
MW-4
1,4-Dioxane
32.7
pg/L
1.2
2.0
3
8/6/2019
MW-5
Cobalt
127
pg/L
1.1
5.0
1*
8/6/2019
MW-5
1,4-Dioxane
3.1
pg/L
1.2
2.0
3
8/6/2019
NOTES: All Results in micorgrams per liter (pg/L).
NC21- = INC Groundwater Standard from 15A NCAC 2L.0202.
*IMAC = NC Interim Maximum Allowable Concentration (for constituents with no NC2L).
MDL = Method Detection Limit.
MRL = Method Reporting Limit.
Bold = GPS Exceedance.
**= Confirmation Sample collected on 9/4/19 (resample).
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02

TABLE 5: Hydraulic Gradients and Groundwater Flow Velocities
Based on Water Level Data obtained on: August 6, 2019
GROUND-
HORIZ.
HYDRAULIC
EFFECTIVE
LINEAR
GRADIENT
FLOW LINE
FLOW
WATER
GRADIENT
CONDUCTIVITY
POROSITY
VELOCITY
CALCULATION
LENGTH
DIRECTION
ELEVATION
1
K
n e
V
SEGMENT
(feet)
(feet)
(ft/day)
(ft/year)
42420
1
1781
SE
0.0505
6.18E-02
0.18
6.34
0
Notes:
Hydraulic conductivity (K) value is the average of results from slug -tests conducted in 1994 (GAI, 1994).
Effective Porosity (n e) based on average of 90% of reported Total Porosity (GAI, 1995) for site soils.
Linear flow velocity: V = Kiln e (modified Darcy equation).
See Drawing 1 for Flow Segments.
Granville County, Butner Landfill LaBella Associates
Permit No. 39-02

TABLE 6: August 2019 Monitored Natural Attenuation Parameters
Background
Downgradient
Sentinel
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MWA
MW-5
MW-6
NES-1
Temperature
08/06/19
°C
17.0
22.7
17.6
19.9
17.3
18.2
16.0
Temperature (Resample)
08/14/19
°C
-
-
-
-
-
24.3
-
pH
12/30/03
SU
7.31
6.54
6.81
6.90
7.24
7.29
-
pH
08/06/19
SU
8.84
6.17
6.49
6.69
7.44
7.49
6.79
pH (Resample)
08/14/19
SU
-
-
-
-
-
6.47
-
Conductivity
08/06/19
pS/cm
113.4
1719.0
1307.0
1287.0
775.0
545.3
98.5
Conductivity (Resample)
08/14/19
pS/cm
-
-
-
-
-
559
-
Redox Potential (ORP)
08/06/19
mV
164.7
-69.3
-33.7
171.6
188.6
232.6
231.8
Redox Potential (Resample)
08/14/19
mV
-
-
-
-
-
237.6
-
Dissolved Oxygen
08/06/19
mg/L
3.77
0.32
0.26
4.55
5.30
2.76
3.04
Dissolved Oxygen (Resample)
08/14/19
mg/L
-
-
-
-
-
1.95
-
Dissolved CO2
08/06/19
mg/L
475.0
250.0
-
Fe, Ferrous (+2)
08/06/19
mg/L
3.5
0.5
Alkalinity (as CaCO3)
08/06/19
mg/L
5.00
5.00
839
754
Chloride
08/06/19
mg/L
2.40
4.00
203
154
Dissolved Hydrogen
08/06/19
nM
0.75
1.0
2.0
5.4
Nitrate-N
08/06/19
mg/L
0.010
0.0
ND
ND
Sulfate
08/06/19
mg/L
0.500
1
ND
0.711 J
Sulfide
08/06/19
mg/L
0.05
0.1
ND
ND
Total Organic Carbon
08/06/19
mg/L
2.50
5.00
33.3
15.10
Biochemical Oxygen Demand
08/06/19
mg/L
2.00
2.00
8.0
ND
Chemical Oxygen Demand
08/06/19
mg/L
12.5
25.0
123.0
45.5
Dissolved Ethane
08/06/19
mg/L
0.0012
0.0100
2.0 J
.0041 J
Dissolved Ethene
08/06/19
mg/L
0.0012
0.0100
ND
.0016 J
Dissolved Methane
08/06/19
mg/L
0.0034
0.0100
5.0
0.5
Lactic Acid
08/06/19
mg/L
0.043
0.20
ND
0.087 J
Acetic Acid
08/06/19
mg/L
0.028
0.10
0.097 J
0.34
Propionic Acid
08/06/19
mg/L
0.004
0.10
0.0058 J
0.0045 J
Butyric Acid
08/06/19
mg/L
0.011
0.10
0.22
ND
Formic Acid
08/06/19
mg/L
0.086
0.50
1.10
1.60
Total Volatile Fatty Acids
08/06/19
mg/L
I -
1.32
1.94
NOTES:
DL = laboratory detection limit.
RL = laboratory reporting limit.
NO = not detected above detection limit.
J = estimated concentration between the DL and the RL.
= not analyzed or not applicable.
mg/L = milligrams per liter
mV = millivolt
SU = standard unit
nM = nano -Molar
°C = degress Celcius
pS/cm = micro-Siemen per centimeter
ntu = nephelometric turbidity units
Butner Landfill, Granville Co.
Permit No. 39-02
La Bella Associates

CHARTS
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time

2.0
1.8
1.6
J\ 1.4
M
C
O
(6
C
N
V
C
U 1.0
N
C
N
N
C
N 0.8
CO
0.6
0.4
0.2
0.0
Chart 1: Benzene Concentration vs. Time in MW-2R, MW-3R, & MW-4
(0 r- r 00 00 O 0) O O -1 -1 N N M M V V LO LO (D (O r r 00 00 O 0)
O O O O O O O ei ci ci ci -1 -1 -1 ei -1
VA a ri.0 � '00 a tiD a ti.0 � tiD � tiD a tiD � tiD � U0 � tiD � tiD � '00 � '00
Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

Chart 2: Cobalt Concentration vs. Time in MW-2R & MW-5
300.0
250.0
J\
ll0
200.0
c
0
m
Y
C
N
U
C
O
U 150.0
_Y
0
O
U
100.0
50.0
tMW-2R
0.0 • W
In u'1 l0 lD I� n W 00 O1 01 O O N c-I N N m m V V lfl lf1 lD lD I� n W 00 Ol Ol O O r-I c-I N N m M C V lfl u'1 t� lD I� n W 00 01 Ol
T T T Ol 01 Ol Ol Ol Ol Ol O O O O O O O O O O O O O O O O O O O O r-1 c-I r-1 c-I r-1 c-I c-I c-I c-I c-I c-I c-I c-1 c-I c-1 c-I c-1 c-I c-1 c-I
a to -c bA -D bA -D bA -D w -a 00 -D 09 -a 00 4 00 4 b0 -a w -D b0 -D b0 -a 09 4 00 4 09 4 bA 4 b0 -a b0 -a b0 -a 00 -a 00 -a 00 -a b0 -a b0
N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N 3 N N 3 N 3
LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q LL Q
Granville Co., Butner Landfill
Permit # 39-02 LaBella Associates

FIGURE
Figure 1 Site Location Map

I,\GmdAIe\Ewa\ButneI Site location Mape.dwa

DRAWINGS
Drawing 1 Groundwater Potentiometric Surface Map
Drawing 2 2019 Tree Survey

LaBeLLa
Powered by partnership.
J �� — ��\ \ - \ \ \ _ \ _ \_ \ —\
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
PHONE: [phone]
labellapc.com
%-%32
MW // _ / ///j \ \ \\\ \\\\ \\\\ \\\\ \\\ \\\\\ \\\ \\ \ \ \ \ \ \ \ \ \ \ \ \ �
- -_---- --
©2019 LaB II Associates
_ / /
t?,\ _
610
-
IIII
GRANVILLE COUNTY
OXFORD, NORTH CAROLINA
I `I
0� M�M II II�
II oI II IM I
II
Io
N�o_ oM
I I LEGEND
I
130 EXISTING 10' TOPOGRAPHIC CONTOURA GrtN
I
32.48�
G EXISTING 2'TOPOGRAPHIC CONTOUR
\
\ \ I I I I I
�
\ � �/
� �"`Y- •` \ / //� / i/I I I I I
/ =/ / I I I
\ = \ \\ / l 1
\ \\� �y- �.�`."' .,Y_.R
�%j
PROPERTY LINEPSO ATSETELIAMIT
�\ —
_\\ o \
- APPROXIMATE LIMITS OF WASTE
I I I / /
,r I I
\�O \ _ \ _ \� _- \ _ \ \—� �// �- _ / I I I I I GROUNDWATER SURFACE CONTOUR
380 (FEET ABOVE MEAN SEA LEVEL)
GROUNDWATER FLOW DIRECTION WITH
GRADIENT CALCULATION SEGMENT
I I
� ���\\___---_�\) \\\
\ LQ
\ \ / / � EXISTING ROAD
CENTERLINE OF STREAM
GROUNDWATER MONITORING WELL
SW3103 I \ - MW-1 R
�2 \ \ ELEV LOCATION AND IDENTIFICATION
\ \ \ \
/
MW-2R \ \ \ \\ \ \ \ SEGMENT USED FOR GRADIENT
BUTNER LANDFILL
i
329.35 1 \ I I O CALCULATIONS
\ \ \ \y
2796 OLD NC 75
BUTNER, NORTH CAROLINA
GAS PROBE LOCATION AND
GP-1 IDENTIFICATION
GV GAS VENT
�,-O SW-1 SURFACE WATER MONITORING POINT
\�\
O (NM) NOT MEASURED
\\ —
NO:
DATE:
DESCRIPTION:
\ —
_ _ \ \ 1 1 \ I I I I \ I \\ \� / / / ►d- = FLOW PATH LENGTH
Revisions
420_\
1,781 LF
PROJECT NUMBER:
2182022
w 1 \ 1 I 1 I I I I I I ( _ \ \
= I I \ Y I
DRAWN BY:
MW-1 \ V I \\\\\\
42q.05 l l Y. r I I \I o I I \ o\\ \ \ II I I I < < \ \-�\\ \\ \\\�30 _
coII I \ \ I I I I
REVIEWED BY: RH
\-
-
I I \ \ \\ - \
\ - \ -
MAV
ISSUED FOR:
GROUNDWATER REPORT
\_
I I \ \ _ \ \ \� \�o
NOTES
\\�\
\
DATE:
09/16/19
1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
*GP 4 / = J I I \ \\\ \ \ I I \ — \ 2. GROUNDWATER SURFACE CONTOUR INTERVAL= 10 FEET
DRAWING NAME:
-
T 3. STATIC WATER LEVELS MEASURED ON 8/6/19.
POTENTIOMETRIC
_
GP-5\ \ \ R X _ \ _ \ _
� \ \ \ \ \ \ \ \ \ \� �\ \ 4. GROUNDWATER CONTOURS BASED ON KNOWN DATA,
L�
G}�-6 \F� T \ \ \\ \ \ \ \ \ TOPOGRAPHIC CONTOURS, LINEAR INTERPOLATION AND
\ _ / \ _ \\ \ \ _ \ EXTRAPOLATION FROM KNOWN FIELD CONDITIONS.
\ \ \ _ -
\ - \
SURFACE MAP
c
\
- \ - _ \ \ _ \�\ \ \ _ \ 5. ELEVATION RELATIVE TO MEAN SEA LEVEL.
AUGUST 6, 2019
6. GROUNDWATER ELEVATION IS BASED ON A WELL SURVEY
PERFORMED IN APRIL 2008
7. TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
DRAWING NUMBER:
2007 DATA OBTAINED FROM NCDOT WEBSITE.
GRAP I SSA
\ I \ \ \ \ \ I I \ 0 \ 1 0 20 \ \ 8. BOUNDARY SURVEY PROVIDED BY BATEMAN CIVIL SURVEY
—� �� I \ \ COMPANY DATED MARCH 15, 2013.

TREE COVERAGE SURVEY �� \ \\ \ \ \ \ \
\ �/�/ -\ �//� ��\�)/I— ��I J \/ \% /� /�� / �\� _/�//_�/j _///� I �// i�/�//���I //��i�/ /,�� /�\///ce/�`_--II I -- —�_— _\/\/\i_��I = I —\ II\\/ \\— �I \\ / \ \(I \ \ �\\ 1\ \1I\'�\\\ I,' \ I\ \ \\ \ �\ \� \ \\\ I\\\� \\_\- ��\\ \' \ �_I\ \ _ _\\—�\ - �_\ \\\\\ _-�\\ _ \ _\\\_\�-\__1_\ \/ —/ --\ \ __- I— _-_ \ \/ /�\ �\ _/\— _--- /\��-\ —\__�_—_ \ ��— =. �/ — /\ \�\I_� /�� \/ /�/I\ / I\\� /II\///�\I/\/I\/1\� \//// \\// _I /\__/� / \I _� �—//I I /\// �/\/_/_(= / �/ \/�//I /// \—II /I \I_ l\I _ I I_I�/I /\ I�I��\I—I\/ II I .I1 I�� \II—I\I,I/I//I\IIIII _-II� III1II II \II I\Ii I II� I \ 11I/\1 IIIII \ II\1 1\ II\ II\/ \I/1I1 \ � /I\\ � \� I\\\\\ \ �\II \ JI\ I / 1 II I \ \ \ I I I �\ \\I \\\ I I\►I \ \i/\; �\ JI I- I_ \ \\\ � II I I\\I /I\
I —\\ \\\III\I IIII \,\II\I I\\ II\\III \ \ (I\\II\I\\I \ \<\\ II` 1I 1 1 I/II \I\I< 1 \1 II\IIII I /1I ' \I/\III I �I I I\ \ I ��I II�\ \,I1I�II�� IIIIII I\ III \I I I i II_ II \ I \ l\\\IIIIJ�I \ III\ II \ III I I III I I I I III \ \I\ I\IIII II\\I I I1\I I I/III \ I I I II1 \ �\ III I I I II II \\II\\I\1\I\I I\ I II I�III\I III I I III ► I\I \II I II\I IIIIIIIIIIII III I IIII\ II\1 I\\IIII_I II III I IIGIIIIIIIIIIIIIII\ III� IIIIIII �I I_�-I\II\\ II\\ 4IIIIIIII I\/\II_�I\\//� III I II / I/\\1I \/��I=I/ III/I'I\I 1\
\ \\
\ I\\
\ I
I
I\
\
\\
�'— —
_—
\-
_ \—
\
-
\
\
\
\\
II I \
/\-
\
WITH EMERGING LONG LEAF PINE.
r /\
LOGGED RECENTLY, WITH STANDING SWEET GUM AND BEECH SAPLINGS
1. SWEET GUM t
2. BLUE BEECH 1'
3. •' • -
TULIP5.
• BLACK MAPLE
1. TULIP POPLAR (50%)
A-APPROX.CON RETE 3
PAS 'OXIMATE\APP
LIMTS 07ASE /eE�K
��EE LIME
1W
YWf3R/ N �1
W-2R(REA7CONCRETE
SHED CONCR
WAL�\ \APR
LIM�SOkIT \ II III I 3
OFATE
SHED SED
ALEHOUSE SCALD
GRAVEL �7SPHALT G6
\
I II-
\ -
III
\ ou
� //// --\ \\ • // /// _ // // ( _ \\� I IIII I I _ -
-.• 41.
40
F `
- - r
�
Y
all
win
-rz
1011
I

APPENDICES
Appendix A
Appendix B
Appendix C
Appendix D
Appendix E
Appendix F
Appendix G
Monitoring Well Construction Data
Field Data Logs
Laboratory Analytical Reports
Historical Groundwater Elevations
Historical Constituents in Groundwater
Historical Constituents in Surface Water
Historical MNA Parameters

Appendix
Monitoring Well Construction Data

Appendix A: Well Construction Details
Surface
TOC
Top of
Top of
Bottom of
Water
Depth to
Geologic
Construction
Drillers
Permit#
Well ID
Latitude
Longitude
Total Depth
Comments
Elevation
Elevation
Casing
Screen
Screen
Level*
Bedrock
Unit**
Date
Reg.#
Ft-AMSL
Ft-AMSL
Ft-AGS
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Ft-BTOC
Fractured
background well
39-02
MW-1 R
N360 09' 55.49"
W780 45' 37.80"
461.01
461.01
0.00
41.00
56.00
56.00
41.00
30.00
4/21/1994
446
Bedrock
replacement
Weathered
compliance well
39-02
MW-2 R
N36° 09' 38.57"
W780 45' 34.97"
326.60
328.94
2.34
3.85
18.85
18.85
2.60
13.00
4/12/1994
446
Bedrock
replacement
Fractured
compliance well
39-02
MW-3 R
N36° 09' 38.58"
W780 45' 34.85"
328.77
330.95
2.18
25.83
35.83
35.83
3.00
13.00
4/14/1994
446
Bedrock
replacement
Fractured
39-02
MW-4
N36° 09' 38.93"
W780 45' 30.15"
338.97
340.92
1.95
16.43
31.43
31.43
9.80
13.00
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-5
N360 09' 39.35"
W780 45' 23.77"
341.88
344.00
2.12
8.52
23.52
23.52
12.80
17.00
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-6
N360 09' 47.00"
W780 45' 25.47"
360.80
362.80
2.00
17.63
32.63
32.63
11.70
21.20
4/19/1994
446
compliance well
Bedrock
Fractured
nature & extent
39-02
NES-1
N360 09' 35.65"
W780 45' 31.59"
326.22
328.72
2.50
15.00
30.00
30.00
22.00
26.00
11/14/2007
I
2675
I
Bedrock
study well
Notes:
TOC = Top of Casing. *Water Level from TOC, approx. 24 hours after drilling.
Ft-AMSL = Feet above mean sea level. **Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Ft-AGS = Feet above ground surface. Typical Monitoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Ft-BTOC = Feet below TOC. Monitoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007 and field observations.
Locations and elevations from March 2013 survey.
Butner Landfill, Granville County La Bella Associates
Permit # 39-02

Appendix B
Field Data Logs

DATE: gI,-7/Zon
LaBetLa
part, GROUND WATER SAMPLING LOG
Project Name: Granville Co. -Butner LF Project No. /Task No.: 2182022.01 / 04
Well ID: MW-1R Sampler(s): S. Slebodnik/ A. Martin
Well Location: North of entrance at tree line under tower *FLUSH MOUNT*
Well Diameter:
2
inches
Initial Depth to Water (DTW):
�b- y(0
feet
Depth to Bottom (DTB):
56.00
feet
Water Column Thickness (WCT):
S S y
feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
2 S
gallons
For 4" Well: WCT X 0.653 =
gallons
For THREE Well Volumes: WV X 3 =
7.
gallons
7
Actual Amount Purged/Bailed: gallons
Purged with: Baile Pump Other:
Sampled with: Bail PumpOther:
/)
Depth to Water before Sampling: `� D• 50 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
O
CW q
57,S1
113• `:5'
Z. 5q
2'9q.9
q,qq
SS
Z-5
Dg3y
1(o,(a
�5.-72
l-73.9
Z.(�,q
2&'�•3
SS.go
Ss
-5, 0
Nqq
IG,G
5,9 q
115,3
3. Z$
ZZS.q
-7q, )'
ss
7, s
0&s
1(o._1
(e,01
10Z,1
y.-7--,
zZ2 9
75,3s
Ss
Date of sample:
5 /71lq
Before Sampling
Xqc)
1-7, o
`� ��
` 1
I l 3 , `l
3• -7
1(0 q, .�
S, -71
Comments (weather conditions, odor, color, silt, etc.):
Ike- tltjw_�VK was ZO5 �',5%p�rv�v ov-\ S/-to and 705-+-sunov on $/7,
Signature: La,��z Date:- •

LaBeLLa Project Name:
Location:
2211W. Meadowview Rd Suite 101 Project No.:
Greensboro, NC 27407 Sampled By:
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: MVO/- Zf- Weather:
WELL SAMPLING INFORMATION
218ZOLZ. r�l
• S
Well Diameter: � Static Water Level: Z.Z
Depth of Well: �$,$S Length of Well Screen:
Measuring Point: Depth to Top of Pump:
Pump Type: J,� DI/MD Tubing Type: �k-�n boll�tci h%l;oq
FIELD PARAMETER MEASUREMENT
MwPurged
(mg/L) (rnV)
i uLai uauuns rurgeo
Purge Time 15 Start:
OBSERVATIONS
Purge Time End: ( ZZZ.
Final Static Water Level: Z , (D to
Notes:
Z2 bo&3 CrjmVVaence, ►s MNh�
�- I eZ}: 2�. 5 M /L C�z _ q S droQs ��i alms �c�
J�550W 1ny�f 3 3 2 � g

LaBella Project Name:
Location:
2211W. Meadowview Rd Suite 101 Project No.:
Greensboro, NC 27407 Sampled By:
Telephone: [phone]
Facsimile: [phone] Date:
WELL I.D.: MW —,3y' Weather:
$/!Q/ Zo19
_80 s-
WELL SAMPLING INFORMATION
Well Diameter: Z 11
Depth of Well: 35. S
Measuring Point:
Pump Type:
FIELD PARAMETER MRAC111RF.MUNT
Static Water Level:
Length of Well Screen:
Depth to Top of Pump:
Tubing Type:
2.59
da-ilons
Purged
=w.--(rnS/crn).
Conductivity
d
I L • v�-�� •1'• 1
='
IIII
�"�
--_�
i
�
KVwM
AJ
-_
Y
Purge Time `�1 \
Start: 1
OBSERVATIONS
Notes:
vauuua rutguu
Purge Time End: 150% Final Static Water Level:
�e7-4- - o ,bs"^VJIL
C 02 _ GO 611e-opds
40 6 V�
cAsr'o'�Ve.$A e & 0,%0's 6
�IIA,

DATE: 9/4/2019
La BelLa
GROUND WATER SAMPLING LOG
Project Name: _ Granville Co. - Butner Resample Project No. /Task No.: 2182022
Well ID: MW-3R Sampler(s): S. Slebodnik
Well Location: South side of landfill, north of NES-1, next to MW-2R
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
2inches
Z- U l feet
35.83 feet
3Z ,9 Z feet [DTB-DTW]
J - 0 gallons
gallons
Z_gallons
Actual Amount Purged/Bailed: 7._gallons
Purged with: Bailer ' Pump Other:
Sampled with: ailer Pump Other:
Depth to Water before Sampling: 27- Lia feet
Gallons
Time
Temp
(°C)
pH
Cond.
(us/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
R<5
���s
)3$�
ySs
l ��0
2
17,
(c;,. 5
1569
- 9 3
1 Q8- b
n )S
1kS
Date of sample:
Li� f
Before Sampling
� I
`icb
+
l-7. s
//
(D• &q
r
155 1
9 �5`
I I q3, 11
2- Z�%
S'KS
Comments (weather conditions, odor, color, silt, etc.):
1q
�� / ZD
Signature:Lf ,�i° C Date: �/ 19
O /
QA/QC Sign Off: Date: _ q I S

DATE: S/(a / Zo ►G�
LaBelLa
GROUND WATER SAMPLING LOG
Project Name: Granville Co. - Butner LF Project No. /Task No.: 2182022.01 / 04
Well ID: MW-4 Sampler(s): S. Slebodnik/ A. Martin
Well Location: South side of LF, just inside tree line
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
inches
7,'6 Z feet
31.43 feet
2 :3- 6-feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = g gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = i `q gallons
Actual Amount Purged/Bailed: L� , gallons
Purged with: C Bail Pump Other:
Sampled with: CiZLPump Other:
Depth to Water before Sampling: 10, 3 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
(�
10h
l7 `7
(. 73
1-L51
2,52
119,y
,qg
Ah,,
3-$
loss
ko,-7
(o,
I2-1Z
,2i
I-72.
ANC
Date of sample:
5/(0/ 19
Before Sampling
lg57q
)q,q
Comments (weather conditions, odor, color, silt, etc.):
Signature:/� �./ �1 �� Date: •

DATE: O��ZO)q
� La Bella
Nefed hy pcvtrier.�-hip, GROUND WATER SAMPLING LOG
Project Name: Granville Co. - Butner LF Project No. /Task No.: 2182022.01 / 04
Well ID: MW-5 Sampler(s): S. Slebodnik/ A. Martin
Well Location: South side of old sed basin in the woods
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
2 inches
I y , 15 feet
23.52 feet
9 , 3 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = S gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = y, gallons
Actual Amount Purged/Bailed: gallons
Purged with: Bailer Pump Other:
Sampled with: Bailer Pump Other:
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0
095Z
I�. -7
��
9�7
2— ZO
ZS(v,0
L-)0.95
SS
1,5
095y
1b,7
(o,70
qO3
Z-5z-
)9io.(
ZID, 1
�s
3.o
dq5�
J&. q
(a,7q
gyS
2,9 7
1-71,0
S3, q3
SS
3, q5
allon
-
Date of sample:
Before Sampling
151(,,
17. ,3
7. L q
7 7 S
S 30
18$ . (o
�, Z3
43S
Comments (weather conditions, odor, color, silt, etc.):
I k-1-weattu r wa5 80 5 -+- s�orrn\, on 916
Signature: L�I�liwl'mll_ Date: �3115_120)q

DATE: 9& - 7 Z o I g
LaBeRa
GROUND WATER SAMPLING LOG
Project Name: Granville Co. - Butner LF Project No. /Task No.: 2182022.01 / 04
Well ID: MW-6 Sampler(s):_ S. Slebodnik / A. Martin
Well Location: Inside LF beside large mulch pile
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
2 inches
11, 0 -7 feet
32.63 feet
Z 1, S& feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = S gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = ) 0, gallons
Actual Amount Purged/Bailed: -S 1 gallons
Purged with: Baile Pump Other:
Sampled with: ciaile Pump Other:
Depth to Water before Sampling: I k I Z feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
09 2y
s-7.'-)
�,1 Z
S sy,o
2. 3�l
Zy2,g
s.
\M
12,S
DgZS
I(-0,5-
�.�13
��Z
3.-7
235.y
�l.qq
�M
Date of sample:
S/-7/ l9
Before Sampling
Qq Z!
S< .Z
7
Sq 5-, 3
2, -7 1
232, (P
(o, � �
Comments (weather conditions, odor, color, silt, etc.):
Cv� v o, 8/�, 4-pi J- 70i o r Y/7.

LaBetta DATE: `�)1 q / Z�j�J
/r GROUND WATER SAMPLING LOG
Project Name: Crarcv� ��e(j,-�CF Project No. /Phase No.:
Well ID: V,£5AWLE Sampler(s): 5.5 � - /VIG d/1
i
Well Location:. n iL _ L- F bes &_ lw-w= mJ6 Q;>e
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
For THREE Well Volumes:
Actual Amount Pur
Purged with:
Sampled with:
2 inches
5C` feet
32. 3 feet
2 ) • feet [DTB-DTW]
WCT X 0.163 = gallons
WCT X 0.653 = gallons
WV X 3 gallons
Bailed: `��-gallons
Depth to Water before Sampling: 1 '-7- O 1 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
706
-563J
y. 3v
M, 6
v, g7
5
6,6�
561.qgg
Date of sample:
gMAq
Before Sampling
1,5�
Z� j
7
__J
5237
4,p
Comments (weather conditions, odor, color, silt, etc.):
Signature: Date:
_ I

DATE: g/(o - 7/ Z o I q
LaBelLa
PDSwese(1+, utnership GROUND WATER SAMPLING LOG
Project Name: Granville Co. - Butner LF Project No. /Task No.: 2182022.01 / 04
Well ID: NES-1 Sampler(s): S. Slebodnik / A. Martin
Well Location: South of LF, access through Wildlife Area hunt camp
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
2 inches
S •" (a feet
36.10 feet
1'9, O I feet [DTB-DTW]
2,9 gallons
_ gallons
gallons
Actual Amount Purged/Bailed: C) , gallons
Purged with: Bail Pump Other:
Sampled with: Baile Pump Other:
Depth to Water before Sampling: 10. 1 2 feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0
0737
15:-7
%.
10 ,�
2.1-10
135.Z-
10,J3
�M
Z.q
(]7�II
ISM
y,3S
�10.(o
2. Cos
Z�4,S
I ��q
AM
S, S
D7y6
IS- I
q, 23
2, q(
301,
'99 1-$
AM
5.-7
07 s"1
ls.l
q,-7
.3, 33
ZSO.)
Date of sample:
Before Sampling
O7ZS
o, ``
�^7q
Q
1$ `�
3, 0'�
Z3j,$
I1�.7
5<
Comments (weather conditions, odor, color, silt, etc.):
Ilse_,. Wea Wos �'S�� On 6' k MA -7C)e * V -7-
r&� ID15 on 3/70 J� 0 103� bn '3/-7•
Signature: L�4&2a4--Z- Date: �g/J5/zoig
a-

,�)/7/2o\q (0
DATE:-&f6>26i9�
� LaBetta
SURFACE WATER MONITORING LOG
Project Name: Granville Co. - Butner LF Project No. /Phase No.: 2182022.01/ 04
Surface Point ID: SW-1 Sampler(s): S. Slebodnik / A. Martin
Location: Near sed basin
Field Parameters:
Time of Sampling: ©_ S
pH: S
Temperature: Z l ,I -A (° C)
Conductivity: (US/cm)
Turbidity: 10011�) (ntu)
Dissolved Oxygen 3. a (mg/L)
Oxidation -Reduction Potential 3�3.� (mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
I i WP.GtK'Le-I () �Ol �11/lh f ��O 5 ©✓t C�� �/ l
Sketch of Sample Location (include flow direction,
N
LVJOO?C*D)
��---- low �'
r' i jl ,_.
Date: a 1 l') l at
Date: S11512o)q
r
etc.):

DATE:
LaBetta
SURFACE WATER MONITORING LOG
Project Name: Granville Co. - Butner LF Project No. /Phase No.: 2182022.01/ 04
Surface Point ID: SW-2 Sampler(s): S. Slebodnik / A. Martin
Location: Near MW-2R and MW-3R
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Turbidity:
Dissolved Oxygen
Oxidation -Reduction Potential
C -4i-\ 0
0 (°C)
(0 (US/CM)
e Q V (ntu)
C) (mg/L)
2�1 13 (mv)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
I r2Q_ uJecri u>a 5 70,�
Sketeb of Sample. Location (include flow direction, drainage pathways, etc.):
b167
Mw�-2R htiw�3jZ
t �
man r2E Doi i
f
1 4
r
` S W Z
Si nature0I.X
Date: owl c7`�-(1 "I
Date: 6/fS/20 19

Appendix C
Laboratory Analytical Reports

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 15, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill Compliance
Pace Project No.: 92440312
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 07, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 29

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92440312001
3902-MW2R
Water
08/06/1912:22
08/07/1910:20
92440312002
3902-MW3R
Water
08/06/1914:32
08/07/1910:20
92440312003
3902-MW4
Water
08/06/1914:54
08/07/1910:20
92440312004
3902-MW5
Water
08/06/1915:16
08/07/1910:20
92440312005
3902-Trip Blank
Water
08/06/19 05:45
08/07/19 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill Compliance
92440312
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92440312001
3902-MW2R
EPA 6010D
IDS
15
PASI-A
EPA 6020E
SER
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440312002
3902-MW3R
EPA 6010D
IDS
15
PASI-A
EPA 6020E
SER
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440312003
3902-MW4
EPA 6010D
IDS
14
PASI-A
EPA 6020E
SER
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440312004
3902-MW5
EPA 6010D
IDS
14
PASI-A
EPA 6020E
SER
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440312005
3902-Trip Blank
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92440312
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92440312001
3902-MW2R
EPA 6010D
Barium
113
ug/L
5.0
08/12/19 10:36
EPA 6010D
Cobalt
11.3
ug/L
5.0
08/12/19 10:36
EPA 6010D
Copper
3.5J
ug/L
5.0
08/12/19 10:36
EPA 6010D
Lead
2.OJ
ug/L
5.0
08/12/19 10:36
EPA 6010D
Nickel
92.6
ug/L
5.0
08/12/19 10:36
EPA 6010D
Tin
29.3
ug/L
5.0
08/12/19 10:36
EPA 6010D
Vanadium
4.1 J
ug/L
5.0
08/12/19 10:36
EPA 8260D
Benzene
1.7
ug/L
1.0
08/15/19 04:08
EPA 8260D
Chlorobenzene
10.2
ug/L
1.0
08/15/19 04:08
EPA 8260D
Chloroethane
0.94J
ug/L
1.0
08/15/19 04:08
EPA 8260D
1,2-Dichlorobenzene
0.62J
ug/L
1.0
08/15/19 04:08
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
98.1
ug/L
2.0
08/09/19 15:48
92440312002
3902-MW3R
EPA 6010D
Barium
73.8
ug/L
5.0
08/12/19 10:39
EPA 6010D
Copper
6.0
ug/L
5.0
08/12/19 10:39
EPA 6010D
Nickel
27.8
ug/L
5.0
08/12/19 10:39
EPA 6010D
Tin
9.7
ug/L
5.0
08/12/19 10:39
EPA 6010D
Vanadium
1.91
ug/L
5.0
08/12/19 10:39
EPA 8260D
Benzene
0.54J
ug/L
1.0
08/15/19 04:25
EPA 8260D
Chlorobenzene
16.9
ug/L
1.0
08/15/19 04:25
EPA 8260D
Chloroethane
1.9
ug/L
1.0
08/15/19 04:25
EPA 8260D
1,2-Dichlorobenzene
1.2
ug/L
1.0
08/15/19 04:25
EPA 8260D
Vinyl chloride
1.1
ug/L
1.0
08/15/19 04:25
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
51.7
ug/L
2.0
08/09/19 15:29
92440312003
3902-MW4
EPA 6010D
Barium
1.2J
ug/L
5.0
08/12/19 10:43
EPA 6010D
Cadmium
0.48J
ug/L
1.0
08/12/19 10:43
EPA 6010D
Copper
7.2
ug/L
5.0
08/12/19 10:43
EPA 6010D
Nickel
11.7
ug/L
5.0
08/12/19 10:43
EPA 6010D
Vanadium
22.1
ug/L
5.0
08/12/19 10:43
EPA 8260D
Benzene
0.30J
ug/L
1.0
08/15/19 04:43
EPA 8260D
Chloroethane
1.3
ug/L
1.0
08/15/19 04:43
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
32.7
ug/L
2.0
08/09/19 15:10
92440312004
3902-MW5
EPA 6010D
Barium
95.1
ug/L
5.0
08/12/19 10:46
EPA 6010D
Cobalt
127
ug/L
5.0
08/12/19 10:46
EPA 6010D
Copper
4AJ
ug/L
5.0
08/12/19 10:46
EPA 6010D
Nickel
18.7
ug/L
5.0
08/12/19 10:46
EPA 6010D
Vanadium
1.7J
ug/L
5.0
08/12/19 10:46
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
3.1
ug/L
2.0
08/09/19 14:50
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW2R Lab ID: 92440312001 Collected: 08/06/19 12:22 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
3.0
1
08/10/1911:49
08/12/1910:36
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:36
7440-38-2
Barium
113
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:36
7440-39-3
Beryllium
ND
ug/L
1.0
0.20
1
08/10/1911:49
08/12/1910:36
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
08/10/1911:49
08/12/1910:36
7440-43-9
Chromium
ND
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:36
7440-47-3
Cobalt
11.3
ug/L
5.0
1.1
1
08/10/1911:49
08/12/1910:36
7440-48-4
Copper
3.5J
ug/L
5.0
2.1
1
08/10/1911:49
08/12/1910:36
7440-50-8
Lead
2.OJ
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:36
7439-92-1
Nickel
92.6
ug/L
5.0
0.90
1
08/10/1911:49
08/12/1910:36
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:36
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
08/10/1911:49
08/12/1910:36
7440-22-4
Tin
29.3
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:36
7440-31-5
Vanadium
4.1J
ug/L
5.0
1.3
1
08/10/1911:49
08/12/1910:36
7440-62-2
Zinc
ND
ug/L
10.0
3.9
1
08/10/1911:49
08/12/1910:36
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
0.10
0.060
1
08/10/19 11:49
08/12/19 20:04
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Acetone
ND
ug/L
25.0
6.2
1
08/15/19 04:08
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/15/19 04:08
107-13-1
Benzene
1.7
ug/L
1.0
0.15
1
08/15/19 04:08
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/15/19 04:08
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/15/19 04:08
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/15/19 04:08
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/15/19 04:08
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/15/19 04:08
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/15/19 04:08
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/15/19 04:08
56-23-5
Chlorobenzene
10.2
ug/L
1.0
0.23
1
08/15/19 04:08
108-90-7
Chloroethane
0.94J
ug/L
1.0
0.49
1
08/15/19 04:08
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/15/19 04:08
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/15/19 04:08
74-87-3 v2
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/15/19 04:08
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/15/19 04:08
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/15/19 04:08
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/15/19 04:08
74-95-3
1,2-Dichlorobenzene
0.62J
ug/L
1.0
0.29
1
08/15/19 04:08
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
08/15/19 04:08
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/15/19 04:08
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/15/19 04:08
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/15/19 04:08
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
08/15/19 04:08
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
08/15/19 04:08
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
08/15/19 04:08
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW2R Lab ID: 92440312001 Collected: 08/06/19 12:22 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/19 04:08
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 04:08
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 04:08
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 04:08
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 04:08
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 04:08
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 04:08
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 04:08
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 04:08
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 04:08
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 04:08
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 04:08
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 04:08
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 04:08
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 04:08
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 04:08
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 04:08
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 04:08
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 04:08
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 04:08
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 04:08
1330-20-7
108
%
70-130
1
08/15/19 04:08
460-00-4
104
%
70-130
1
08/15/19 04:08
17060-07-0
103
%
70-130
1
08/15/19 04:08
2037-26-5
Analytical Method: EPA 8260D Mod.
98.1
ug/L
2.0
1.2
1
08/09/1915:48
123-91-1
103
%
50-150
1
08/09/1915:48
17060-07-0
107
%
50-150
1
08/09/1915:48
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW3R Lab ID: 92440312002 Collected: 08/06/19 14:32 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
3.0
1
08/10/1911:49
08/12/1910:39
7440-36-0
Arsenic
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:39
7440-38-2
Barium
73.8
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:39
7440-39-3
Beryllium
ND
ug/L
1.0
0.20
1
08/10/1911:49
08/12/1910:39
7440-41-7
Cadmium
ND
ug/L
1.0
0.40
1
08/10/1911:49
08/12/1910:39
7440-43-9
Chromium
ND
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:39
7440-47-3
Cobalt
ND
ug/L
5.0
1.1
1
08/10/1911:49
08/12/1910:39
7440-48-4
Copper
6.0
ug/L
5.0
2.1
1
08/10/1911:49
08/12/1910:39
7440-50-8
Lead
ND
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:39
7439-92-1
Nickel
27.8
ug/L
5.0
0.90
1
08/10/1911:49
08/12/1910:39
7440-02-0
Selenium
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:39
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
08/10/1911:49
08/12/1910:39
7440-22-4
Tin
9.7
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:39
7440-31-5
Vanadium
1.91
ug/L
5.0
1.3
1
08/10/1911:49
08/12/1910:39
7440-62-2
Zinc
ND
ug/L
10.0
3.9
1
08/10/1911:49
08/12/1910:39
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
0.10
0.060
1
08/10/19 11:49
08/12/19 20:12
7440-28-0
8260D MSV Low Level Landfill
Analytical Method: EPA 8260D
Acetone
ND
ug/L
25.0
6.2
1
08/15/19 04:25
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
08/15/19 04:25
107-13-1
Benzene
0.54J
ug/L
1.0
0.15
1
08/15/19 04:25
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
08/15/19 04:25
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
08/15/19 04:25
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
08/15/19 04:25
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
08/15/19 04:25
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
08/15/19 04:25
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
08/15/19 04:25
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
08/15/19 04:25
56-23-5
Chlorobenzene
16.9
ug/L
1.0
0.23
1
08/15/19 04:25
108-90-7
Chloroethane
1.9
ug/L
1.0
0.49
1
08/15/19 04:25
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
08/15/19 04:25
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
08/15/19 04:25
74-87-3 v2
1,2-Dibromo-3-chloropropane
ND
ug/L
5.0
0.26
1
08/15/19 04:25
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
08/15/19 04:25
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
08/15/19 04:25
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
08/15/19 04:25
74-95-3
1,2-Dichlorobenzene
1.2
ug/L
1.0
0.29
1
08/15/19 04:25
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
08/15/19 04:25
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
08/15/19 04:25
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
08/15/19 04:25
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
08/15/19 04:25
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
08/15/19 04:25
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
08/15/19 04:25
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
08/15/19 04:25
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW3R Lab ID: 92440312002 Collected: 08/06/19 14:32 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/19 04:25
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 04:25
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 04:25
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 04:25
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 04:25
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 04:25
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 04:25
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 04:25
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 04:25
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 04:25
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 04:25
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 04:25
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 04:25
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 04:25
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 04:25
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 04:25
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 04:25
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 04:25
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 04:25
108-05-4
1.1
ug/L
1.0
0.24
1
08/15/19 04:25
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 04:25
1330-20-7
108
%
70-130
1
08/15/19 04:25
460-00-4
104
%
70-130
1
08/15/19 04:25
17060-07-0
103
%
70-130
1
08/15/19 04:25
2037-26-5
Analytical Method: EPA 8260D Mod.
51.7
ug/L
2.0
1.2
1
08/09/1915:29
123-91-1
103
%
50-150
1
08/09/1915:29
17060-07-0
108
%
50-150
1
08/09/1915:29
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW4 Lab ID: 92440312003 Collected: 08/06/19 14:54 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/10/1911:49
08/12/1910:43
7440-36-0
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:43
7440-38-2
1.2J
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:43
7440-39-3
ND
ug/L
1.0
0.20
1
08/10/1911:49
08/12/1910:43
7440-41-7
0.48J
ug/L
1.0
0.40
1
08/10/1911:49
08/12/1910:43
7440-43-9
ND
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:43
7440-47-3
ND
ug/L
5.0
1.1
1
08/10/1911:49
08/12/1910:43
7440-48-4
7.2
ug/L
5.0
2.1
1
08/10/1911:49
08/12/1910:43
7440-50-8
ND
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:43
7439-92-1
11.7
ug/L
5.0
0.90
1
08/10/1911:49
08/12/1910:43
7440-02-0
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:43
7782-49-2
ND
ug/L
5.0
2.5
1
08/10/1911:49
08/12/1910:43
7440-22-4
22.1
ug/L
5.0
1.3
1
08/10/1911:49
08/12/1910:43
7440-62-2
ND
ug/L
10.0
3.9
1
08/10/1911:49
08/12/1910:43
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/10/19 11:49 08/12/19 20:19 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 04:43
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 04:43
107-13-1
0.30J
ug/L
1.0
0.15
1
08/15/19 04:43
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 04:43
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 04:43
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 04:43
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 04:43
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 04:43
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 04:43
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 04:43
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 04:43
108-90-7
1.3
ug/L
1.0
0.49
1
08/15/19 04:43
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 04:43
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 04:43
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 04:43
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 04:43
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 04:43
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 04:43
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 04:43
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 04:43
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 04:43
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 04:43
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 04:43
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 04:43
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 04:43
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 04:43
156-60-5
ND
ug/L
1.0
0.19
1
08/15/19 04:43
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 10 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW4 Lab ID: 92440312003 Collected: 08/06/19 14:54 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.30
1
08/15/19 04:43
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 04:43
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 04:43
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 04:43
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 04:43
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 04:43
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 04:43
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 04:43
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 04:43
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 04:43
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 04:43
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 04:43
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 04:43
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 04:43
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 04:43
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 04:43
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 04:43
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 04:43
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 04:43
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 04:43
1330-20-7
109
%
70-130
1
08/15/19 04:43
460-00-4
105
%
70-130
1
08/15/19 04:43
17060-07-0
104
%
70-130
1
08/15/19 04:43
2037-26-5
Analytical Method: EPA 8260D Mod.
32.7
ug/L
2.0
1.2
1
08/09/1915:10
123-91-1
109
%
50-150
1
08/09/1915:10
17060-07-0
110
%
50-150
1
08/09/1915:10
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW5 Lab ID: 92440312004 Collected: 08/06/19 15:16 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/10/1911:49
08/12/1910:46
7440-36-0
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:46
7440-38-2
95.1
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:46
7440-39-3
ND
ug/L
1.0
0.20
1
08/10/1911:49
08/12/1910:46
7440-41-7
ND
ug/L
1.0
0.40
1
08/10/1911:49
08/12/1910:46
7440-43-9
ND
ug/L
5.0
1.0
1
08/10/1911:49
08/12/1910:46
7440-47-3
127
ug/L
5.0
1.1
1
08/10/1911:49
08/12/1910:46
7440-48-4
4.4J
ug/L
5.0
2.1
1
08/10/1911:49
08/12/1910:46
7440-50-8
ND
ug/L
5.0
1.6
1
08/10/1911:49
08/12/1910:46
7439-92-1
18.7
ug/L
5.0
0.90
1
08/10/1911:49
08/12/1910:46
7440-02-0
ND
ug/L
10.0
4.7
1
08/10/1911:49
08/12/1910:46
7782-49-2
ND
ug/L
5.0
2.5
1
08/10/1911:49
08/12/1910:46
7440-22-4
1.7J
ug/L
5.0
1.3
1
08/10/1911:49
08/12/1910:46
7440-62-2
ND
ug/L
10.0
3.9
1
08/10/1911:49
08/12/1910:46
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/10/19 11:49 08/12/19 20:27 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 05:00
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 05:00
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 05:00
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 05:00
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 05:00
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 05:00
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 05:00
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 05:00
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 05:00
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 05:00
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 05:00
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 05:00
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 05:00
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 05:00
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 05:00
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 05:00
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 05:00
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 05:00
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 05:00
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 05:00
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 05:00
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 05:00
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 05:00
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 05:00
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 05:00
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 05:00
156-60-5
ND
ug/L
1.0
0.19
1
08/15/19 05:00
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v3
v2
v1
Page 12 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-MW5 Lab ID: 92440312004 Collected: 08/06/19 15:16 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.30
1
08/15/19 05:00
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 05:00
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 05:00
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 05:00
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 05:00
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 05:00
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 05:00
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 05:00
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 05:00
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 05:00
79-34-5 v1
ND
ug/L
1.0
0.16
1
08/15/19 05:00
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 05:00
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 05:00
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 05:00
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 05:00
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 05:00
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 05:00
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 05:00
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 05:00
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 05:00
1330-20-7
110
%
70-130
1
08/15/19 05:00
460-00-4
107
%
70-130
1
08/15/19 05:00
17060-07-0
105
%
70-130
1
08/15/19 05:00
2037-26-5
Analytical Method: EPA 8260D Mod.
3.1
ug/L
2.0
1.2
1
08/09/1914:50
123-91-1
101
%
50-150
1
08/09/1914:50
17060-07-0
109
%
50-150
1
08/09/1914:50
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-Trip Blank Lab ID: 92440312005 Collected: 08/06/19 05:45 Received: 08/07/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Date: 08/15/2019 05:42 PM
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 03:33
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 03:33
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 03:33
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 03:33
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 03:33
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 03:33
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 03:33
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 03:33
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 03:33
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 03:33
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 03:33
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 03:33
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 03:33
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 03:33
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 03:33
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 03:33
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 03:33
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 03:33
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 03:33
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 03:33
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 03:33
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 03:33
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 03:33
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 03:33
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 03:33
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 03:33
156-60-5
ND
ug/L
1.0
0.19
1
08/15/19 03:33
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 03:33
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 03:33
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 03:33
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 03:33
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 03:33
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 03:33
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 03:33
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 03:33
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 03:33
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 03:33
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 03:33
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 03:33
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 03:33
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 03:33
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 03:33
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 03:33
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 03:33
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 03:33
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 03:33
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v2
Page 14 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
Sample: 3902-Trip Blank
Lab ID:
92440312005
Collected:
08/06/19 05:45
Received: 08/07/19 10:20 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Xylene (Total)
ND
ug/L
1.0
0.63 1
08/15/19 03:33
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
110
%
70-130
1
08/15/19 03:33
460-00-4
1,2-Dichloroethane-d4 (S)
105
%
70-130
1
08/15/19 03:33
17060-07-0
Toluene-d8 (S)
104
%
70-130
1
08/15/19 03:33
2037-26-5
8260D MSV SIM
Analytical
Method: EPA 8260D
Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1.2 1
08/09/19 13:52
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
96
%
50-150
1
08/09/19 13:52
17060-07-0
Toluene-d8 (S)
106
%
50-150
1
08/09/19 13:52
2037-26-5
Date: 08/15/2019 05:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 15 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
QC Batch: 491536 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92440312001, 92440312002, 92440312003, 92440312004
METHOD BLANK: 2651050
Matrix:
Water
Associated Lab Samples: 92440312001, 92440312002, 92440312003,
92440312004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.0
08/12/19 09:23
Arsenic
ug/L
ND
10.0
4.7
08/12/19 09:23
Barium
ug/L
ND
5.0
1.0
08/12/19 09:23
Beryllium
ug/L
ND
1.0
0.20
08/12/19 09:23
Cadmium
ug/L
ND
1.0
0.40
08/12/19 09:23
Chromium
ug/L
ND
5.0
1.0
08/12/19 09:23
Cobalt
ug/L
ND
5.0
1.1
08/12/19 09:23
Copper
ug/L
ND
5.0
2.1
08/12/19 09:23
Lead
ug/L
ND
5.0
1.6
08/12/19 09:23
Nickel
ug/L
ND
5.0
0.90
08/12/19 09:23
Selenium
ug/L
ND
10.0
4.7
08/12/19 09:23
Silver
ug/L
ND
5.0
2.5
08/12/19 09:23
Tin
ug/L
ND
5.0
1.6
08/12/19 09:23
Vanadium
ug/L
ND
5.0
1.3
08/12/19 09:23
Zinc
ug/L
ND
10.0
3.9
08/12/19 09:23
LABORATORY CONTROL SAMPLE:
2651051
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
509
102
80-120
Arsenic
ug/L
500
495
99
80-120
Barium
ug/L
500
477
95
80-120
Beryllium
ug/L
500
475
95
80-120
Cadmium
ug/L
500
489
98
80-120
Chromium
ug/L
500
475
95
80-120
Cobalt
ug/L
500
504
101
80-120
Copper
ug/L
500
490
98
80-120
Lead
ug/L
500
498
100
80-120
Nickel
ug/L
500
490
98
80-120
Selenium
ug/L
500
503
101
80-120
Silver
ug/L
250
245
98
80-120
Tin
ug/L
500
514
103
80-120
Vanadium
ug/L
500
494
99
80-120
Zinc
ug/L
500
503
101
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Landfill Compliance
92440312
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2651052
2651053
MS
MSD
92439773005
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
552
555
110
111
75-125
1
20
Arsenic
ug/L
ND
500
500
542
543
108
109
75-125
0
20
Barium
ug/L
21.2
500
500
523
523
100
100
75-125
0
20
Beryllium
ug/L
ND
500
500
504
503
101
101
75-125
0
20
Cadmium
ug/L
ND
500
500
532
534
106
107
75-125
0
20
Chromium
ug/L
ND
500
500
503
503
101
101
75-125
0
20
Cobalt
ug/L
ND
500
500
528
530
106
106
75-125
0
20
Copper
ug/L
2.3J
500
500
524
525
104
105
75-125
0
20
Lead
ug/L
ND
500
500
524
528
105
106
75-125
1
20
Nickel
ug/L
ND
500
500
510
512
102
102
75-125
0
20
Selenium
ug/L
ND
500
500
564
566
113
113
75-125
0
20
Silver
ug/L
ND
250
250
263
263
105
105
75-125
0
20
Tin
ug/L
ND
500
500
548
553
110
111
75-125
1
20
Vanadium
ug/L
ND
500
500
531
531
106
106
75-125
0
20
Zinc
ug/L
ND
500
500
538
542
107
108
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
QC Batch: 491519
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92440312001, 92440312002,
92440312003, 92440312004
METHOD BLANK: 2650984
Matrix: Water
Associated Lab Samples: 92440312001, 92440312002,
92440312003, 92440312004
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Thallium ug/L
ND 0.10 0.060 08/12/1916:18
LABORATORY CONTROL SAMPLE: 2650985
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 9.9 99
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2650986 2650987
MS MSD
92439773004
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND
10 10 9.8 9.8
98 98 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
QC Batch: 492152 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92440312001, 92440312002, 92440312003, 92440312004, 92440312005
METHOD BLANK: 2653683 Matrix: Water
Associated Lab Samples: 92440312001, 92440312002, 92440312003, 92440312004, 92440312005
Blank Reporting
Parameter Units Result Limit MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/15/19 02:41
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/15/19 02:41
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/15/19 02:41
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/15/19 02:41
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/15/19 02:41
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/15/19 02:41
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/15/19 02:41
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/15/19 02:41
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/15/19 02:41
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/15/19 02:41
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/15/19 02:41
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/15/19 02:41
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/15/19 02:41
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/15/19 02:41
2-Hexanone
ug/L
ND
5.0
0.57
08/15/19 02:41
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/15/19 02:41
Acetone
ug/L
ND
25.0
6.2
08/15/19 02:41
Acrylonitrile
ug/L
ND
10.0
0.90
08/15/19 02:41
Benzene
ug/L
ND
1.0
0.15
08/15/19 02:41
Bromochloromethane
ug/L
ND
1.0
0.34
08/15/19 02:41
Bromodichloromethane
ug/L
ND
1.0
0.26
08/15/19 02:41
Bromoform
ug/L
ND
1.0
0.62
08/15/19 02:41
Bromomethane
ug/L
ND
2.0
0.62
08/15/19 02:41
Carbon disulfide
ug/L
ND
2.0
0.40
08/15/19 02:41
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/15/19 02:41
Chlorobenzene
ug/L
ND
1.0
0.23
08/15/19 02:41
Chloroethane
ug/L
ND
1.0
0.49
08/15/19 02:41
Chloroform
ug/L
ND
5.0
2.3
08/15/19 02:41
Chloromethane
ug/L
ND
1.0
0.39
08/15/19 02:41
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/15/19 02:41
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/15/19 02:41
Dibromochloromethane
ug/L
ND
1.0
0.41
08/15/19 02:41
Dibromomethane
ug/L
ND
1.0
0.46
08/15/19 02:41
Ethylbenzene
ug/L
ND
1.0
0.26
08/15/19 02:41
lodomethane
ug/L
ND
20.0
12.5
08/15/19 02:41
Methylene Chloride
ug/L
ND
5.0
3.7
08/15/19 02:41
Styrene
ug/L
ND
1.0
0.27
08/15/19 02:41
Tetrachloroethene
ug/L
ND
1.0
0.16
08/15/19 02:41
Toluene
ug/L
ND
1.0
0.24
08/15/19 02:41
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/15/19 02:41
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/15/19 02:41
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
METHOD BLANK: 2653683
Matrix:
Water
Associated Lab Samples:
92440312001, 92440312002, 92440312003, 92440312004, 92440312005
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/15/19 02:41
Trichloroethene
ug/L
ND
1.0
0.22
08/15/19 02:41
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/15/19 02:41
Vinyl acetate
ug/L
ND
2.0
1.4
08/15/19 02:41
Vinyl chloride
ug/L
ND
1.0
0.24
08/15/19 02:41
Xylene (Total)
ug/L
ND
1.0
0.63
08/15/19 02:41
1,2-Dichloroethane-d4 (S)
%
106
70-130
08/15/19 02:41
4-Bromofluorobenzene (S)
%
110
70-130
08/15/19 02:41
Toluene-d8 (S)
%
104
70-130
08/15/19 02:41
LABORATORY CONTROL SAMPLE: 2653684
Parameter
Qualifiers
Spike LCS LCS % Rec
Units Conc. Result % Rec Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
49.7
99
70-130
1,1,1-Trichloroethane
ug/L
50
53.4
107
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
50.2
100
70-130
1,1,2-Trichloroethane
ug/L
50
53.3
107
70-130
1,1-Dichloroethane
ug/L
50
54.8
110
70-130
1,1-Dichloroethene
ug/L
50
55.4
111
70-130
1,2,3-Trichloropropane
ug/L
50
52.3
105
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
50.1
100
70-130
1,2-Dibromoethane (EDB)
ug/L
50
49.6
99
70-130
1,2-Dichlorobenzene
ug/L
50
43.9
88
70-130
1,2-Dichloroethane
ug/L
50
51.6
103
70-130
1,2-Dichloropropane
ug/L
50
52.2
104
70-130
1,4-Dichlorobenzene
ug/L
50
43.5
87
70-130
2-Butanone (MEK)
ug/L
100
118
118
64-135
2-Hexanone
ug/L
100
106
106
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
115
115
70-130
Acetone
ug/L
100
122
122
61-157
Acrylonitrile
ug/L
250
286
114
61-143
Benzene
ug/L
50
51.4
103
70-130
Bromochloromethane
ug/L
50
55.3
111
70-130
Bromodichloromethane
ug/L
50
54.0
108
70-130lK
Bromoform
ug/L
50
56.7
113
70-130
Bromomethane
ug/L
50
47.4
95
38-130
Carbon disulfide
ug/L
50
54.1
108
68-130
Carbon tetrachloride
ug/L
50
50.6
101
70-130
Chlorobenzene
ug/L
50
45.9
92
70-130
Chloroethane
ug/L
50
40.7
81
37-142 F3,IK
Chloroform
ug/L
50
53.5
107
70-130
Chloromethane
ug/L
50
51.8
104
48-130 v3
cis-1,2-Dichloroethene
ug/L
50
53.6
107
70-130
cis-1,3-Dichloropropene
ug/L
50
56.7
113
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 29

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
LABORATORY CONTROL SAMPLE:
2653684
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
51.8
104
70-130
Dibromomethane
ug/L
50
51.5
103
70-130
Ethylbenzene
ug/L
50
47.2
94
70-130
lodomethane
ug/L
100
116
116
40-130
Methylene Chloride
ug/L
50
50.4
101
67-132
Styrene
ug/L
50
49.1
98
70-130
Tetrachloroethene
ug/L
50
45.4
91
69-130
Toluene
ug/L
50
50.0
100
70-130
trans-1,2-Dichloroethene
ug/L
50
54.7
109
70-130
trans- 1,3-Dichloropropene
ug/L
50
56.7
113
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
55.5
111
35-189
Trichloroethene
ug/L
50
49.9
100
70-130
Trichlorofluoromethane
ug/L
50
52.4
105
63-130
Vinyl acetate
ug/L
100
127
127
55-143
Vinyl chloride
ug/L
50
55.6
111
70-131
Xylene (Total)
ug/L
150
145
97
70-130
1,2-Dichloroethane-d4 (S)
%
111
70-130
4-Bromofluorobenzene (S)
%
107
70-130
Toluene-d8 (S)
%
102
70-130
MATRIX SPIKE SAMPLE:
2653686
92440312004
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.9
109
73-134
1,1,1-Trichloroethane
ug/L
ND
20
20.9
104
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
23.0
115
70-136 v1
1,1,2-Trichloroethane
ug/L
ND
20
23.7
118
70-135
1,1-Dichloroethane
ug/L
ND
20
19.4
97
70-139
1,1-Dichloroethene
ug/L
ND
20
22.4
112
70-154
1,2,3-Trichloropropane
ug/L
ND
20
17.2
86
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.9
95
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
22.2
111
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.6
103
70-133
1,2-Dichloroethane
ug/L
ND
20
19.5
96
70-137
1,2-Dichloropropane
ug/L
ND
20
23.0
115
70-140
1,4-Dichlorobenzene
ug/L
ND
20
19.7
98
70-133
2-Butanone (MEK)
ug/L
ND
40
47.9
120
60-139
2-Hexanone
ug/L
ND
40
45.7
114
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
48.6
121
65-135
Acetone
ug/L
ND
40
39.4
99
60-148
Acrylonitrile
ug/L
ND
100
87.5
88
64-147
Benzene
ug/L
ND
20
23.4
117
70-151
Bromochloromethane
ug/L
ND
20
17.6
88
70-141
Bromodichloromethane
ug/L
ND
20
22.1
111
70-138
Bromoform
ug/L
ND
20
21.2
106
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
MATRIX SPIKE SAMPLE:
Parameter
2653686
Units
92440312004
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
13.2
66
15-152 v3
Carbon disulfide
ug/L
ND
20
22.3
111
69-149
Carbon tetrachloride
ug/L
ND
20
20.8
104
70-143
Chlorobenzene
ug/L
ND
20
21.1
105
70-138
Chloroethane
ug/L
ND
20
25.3
127
52-163
Chloroform
ug/L
ND
20
18.8
94
70-139
Chloromethane
ug/L
ND
20
20.5
103
41-139
cis-1,2-Dichloroethene
ug/L
ND
20
19.9
100
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
20.8
104
70-137
Dibromochloromethane
ug/L
ND
20
19.8
99
70-134
Dibromomethane
ug/L
ND
20
19.8
99
70-138
Ethylbenzene
ug/L
ND
20
21.2
106
66-153
lodomethane
ug/L
ND
40
32.5
81
20-138
Methylene Chloride
ug/L
ND
20
18.1
91
42-159
Styrene
ug/L
ND
20
21.2
106
70-135
Tetrachloroethene
ug/L
ND
20
21.7
109
59-143
Toluene
ug/L
ND
20
22.2
111
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
21.4
107
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.7
104
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
17.5
87
47-135 v1
Trichloroethene
ug/L
ND
20
23.2
116
70-147
Trichlorofluoromethane
ug/L
ND
20
22.7
114
70-148
Vinyl acetate
ug/L
ND
40
42.7
107
49-151
Vinyl chloride
ug/L
ND
20
23.3
117
70-156
Xylene (Total)
ug/L
ND
60
64.0
107
63-158
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
100
70-130
SAMPLE DUPLICATE: 2653685
Parameter
Units
92439777001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 22 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
SAMPLE DUPLICATE: 2653685
Parameter
Units
92439777001
Result
Dup
Result RPD
Max
RPD
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30 v2
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
108
95
4-Bromofluorobenzene (S)
%
110
100
Toluene-d8 (S)
%
106
109
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 23 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440312
QC Batch: 491444 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92440312001, 92440312002, 92440312003, 92440312004, 92440312005
METHOD BLANK: 2650540
Matrix:
Water
Associated Lab Samples:
92440312001, 92440312002, 92440312003, 92440312004, 92440312005
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0 1.2
08/09/19 13:14
1,2-Dichloroethane-d4 (S)
%
99
50-150
08/09/19 13:14
Toluene-d8 (S)
%
105
50-150
08/09/19 13:14
LABORATORY CONTROL SAMPLE: 2650541
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.3 91 70-130
1,2-Dichloroethane-d4 (S) % 97 50-150
Toluene-d8(S) % 106 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2650542
2650543
MS
MSD
92440312004 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 3.1 20
20 20.9 21.1
89
90
50-150
1 30
1,2-Dichloroethane-d4 (S)
%
101
102
50-150
30
Toluene-d8(S)
%
105
104
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill Compliance
Pace Project No.: 92440312
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
F3 The recovery of the second source standard used to verify the initial calibration curve for this analyte is outside the
laboratory's control limits. The result is estimated.
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
v3 The continuing calibration verification was below the method acceptance limit. Any detection for the analyte in the
associated samples may have low bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/15/2019 05:42 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 29

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill Compliance
92440312
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92440312001
3902-MW2R
EPA 3010A
491536
EPA 6010D
491657
92440312002
3902-MW3R
EPA 3010A
491536
EPA 6010D
491657
92440312003
3902-MW4
EPA 3010A
491536
EPA 6010D
491657
92440312004
3902-MW5
EPA 3010A
491536
EPA 6010D
491657
92440312001
3902-MW2R
EPA 3010A
491519
EPA 6020B
491636
92440312002
3902-MW3R
EPA 3010A
491519
EPA 6020B
491636
92440312003
3902-MW4
EPA 3010A
491519
EPA 6020B
491636
92440312004
3902-MW5
EPA 3010A
491519
EPA 6020B
491636
92440312001
3902-MW2R
EPA 8260D
492152
92440312002
3902-MW3R
EPA 8260D
492152
92440312003
3902-MW4
EPA 8260D
492152
92440312004
3902-MW5
EPA 8260D
492152
92440312005
3902-Trip Blank
EPA 8260D
492152
92440312001
3902-MW2R
EPA 8260D Mod.
491444
92440312002
3902-MW3R
EPA 8260D Mod.
491444
92440312003
3902-MW4
EPA 8260D Mod.
491444
92440312004
3902-MW5
EPA 8260D Mod.
491444
92440312005
3902-Trip Blank
EPA 8260D Mod.
491444
Date: 08/15/2019 05:42 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 29

. laceAnalytical
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
F-CAR-CS-433-Rev.06
Pace Carolinas Quality Office
Laboratory receiving sa pies:
Asheville Eden❑ Greenwood ❑ Huntersville❑ Raleigh❑ Mechanicsville❑
Sample Condition Client Name; Wp# 92440312
Upon Project #: ■
Ssc�
❑Courier: Fed ex [,UPS EIUSPS❑other: ❑Client H1111111111111111111
Commercial ❑Pace
Custody Seal Present? ❑Yes ❑No Seals Intact? ❑Yes [:]No
Packing Material- ❑Bubble Wrap ✓ Bubble Bags ❑None ❑ Other
Thermometer'
IR Gun ID: I Q'N, Type of Ice: Wet ❑etue
/ 7 '
Cooler Temp (°C): Z • 7 Correction Factor: Add/Subtract (°C) �r
Cooler Temp Corrected (°C): 2--
USDA Regulated Soil ([D/N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
MYes MNo
L 92440312
Date/Initials Person Examining Contents: it ,Y/ 211 q
Biological Tissue zen?
❑Yes []No N/A
❑None
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
Comments/Discrepancy. u
Chain of Custody Present?
�es
❑No
❑N/A
1.
Samples Arrived within Hold Time?
`U' Yes
❑No
❑N/A
2.
Short Hold Time Analysis (<72 hr.)?
/'✓S F g
N2
El N/A
3.
Rush Turn Around Time Requested?
[]Yes
ENo
❑NIA
4.
Sufficient Volume?
es
❑No
❑N/A
S.
Correct Containers Used?
-Pace Containers Used?
Y
des
[:]No
❑No
[]N/A
❑N/A
6.
Containers Intact?
Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
[]NO
N/A
8.
Sample Labels Match COC? / es
-Includes Date/Time/ID/Analysis Matrix: w
❑No
❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
❑Yes
No
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
❑NO
❑No
❑N/A
❑N/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
Project Manager SCURF Review: "+ L
Project Manager SRF Review: 41M&
Field Data Required? [:]Yes No
Date:
R/&�?
Date:
gle
Page 27 of 29

�._-P�CeAr�alyflCa�
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document -No.:
issuing Authority,
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is Project # UO# ; 9244Q312
verified and within the acceptance range for preservation
samples. PM: NMG Due Date: 08/21/19
Exceptions: VDA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg CLIENT: 92—Joyce Eng
**Bottom half of box is to list number of bottle
v
_ y
u
a °' ¢
a a V V n Z)
> y
v `1 N M Y h v
u =
a L CL m
7 U D n T T Z
M- a. a o
a ° a a a E ¢
E E t y E E E E m`
ui o o Y N o yr in
—
R 7 7 7 7
LL
vt Z
m It rM a a a a� a a a
m m m m m m m m 3 a
1
2
3
4
5
6
7
8
9
10
11
12
U
U
a
Q
-6
y
v w
= y
U Z)
2 i
v
E ¢
E
m a
.i rn
l9 W
a ¢
N
N V
V T
x o.
a Q
O �v
T T
a
E 4
° a
. cn
l9 [9
a a
u
z
E
o
M
C9
¢
¢
Z
? N ?
U N a
'- z 7
O Op 0
J
V ,U�. C
cn m a'
0 l7 0
o >
Q
0
2
O
CD
M
U
c
Z rtl
¢
? ¢
Y n, Z
o o.
2
Y s w
a
`� 1 N
a Y h
o � a
> > ,,
�
Z
Q.
°
n
uQ'7
N
H
a
w
M
m
a
�
'
Z
a
Ln
a
a
m
'7
�
CU
a
=
Q
E
O
=
C7
a
¢
Z
c
-°
'u
E
O
>
LD
LM
>
5
a
Z
W
E
E
00
>
lm7
o
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot fi
adjusted added
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form tivill be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 28 of 29

Section A
Required Client Information.
Company: La Bella Assoc
Address: 2211 West ME
Greensboro, NC 27407
Email ro: vburbachk:'ov
Phone: 336 323-O09,
Requested Due DaterrAT10
N
O
CHAIN -OF -CUSTODY 1 Analytical Request Document N
The Chain -of -Custody is a LFGAI_ DOCUMENT. All relevant fields must be completed accurately. m
Section B
ILSection C
Required Projecl Informalionr Invoice Information:
Reporl To Van Burbach Pa e = l Of i
Aucnrion. Jason Falls
Rd copy To: Mi uel Vazquez Company Name: Granville County, Solid Waste
ltddi css. P-O. Box 906, Oxford NC 27565 'rr,h rnrri P h
SAMPLE ID
One Character per box.
(A-Z. a.y 1 , -)
Sample Ids must be unique
W
H
1
2
39
2-MW2R
3
39
2-MW3R
4
39
2-MW4
5
39
2-MW5
6
7
_
8
9 39p2-Tri 81ank
10
11
12
ADDITIONAL COMMENTS
urc asc
Orticr N❑
Client Project ID: Butner Landfill Comp Fiance
Container
Order Number:
3566-3
Re uesled A
I�sa,rltlx
co❑E
-
`o
COLLECTED
Preservatives
z
>`-
orr�k,�gw.,hr
wv«r
ow
wT
n
;'
o
w
wnsec water ww
SaiuSalid SL
0,1 oL
a
ca
START
END
q
N
m
in
V7
U
W.
WP
<
Q
I-
N
O
(1)
air
AR
n
a
N
2
j
c
om�r
or
ct
—
TISSYtl
TS
X
TDATLTIME
=
O
m
O
0
-
�'
N
d
Q
C-
q
O
�
a
a
n
O
in
=
Q
Q❑
DATE
TIME
1
__=
O
z
Z
L
L
Q
U
U
4
C
ill
Z
Z
Ca
Wr
WTIG
�i,1r9
I ZZZ
7
x
1v
-.
RELINQUISHED BY I AFFILIATION DATE TIME ACCEPTED BYIAFFILIATION
S1ebc n �{Lc'1�
S.�
Locatiol
I Carolina
DATE I TIME SAMPLE CONDITIONS
IPLER NAME AND SIGNATURE a
`u
PRINT Name of SAMPLER: 11 G
SIGNATURE of SAMPLER :n i J1
DATE Signed-, j� - �j /`� a } o °' E
9 0 U to

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 19, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill Compliance
Pace Project No.: 92440792
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 31

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92440792001
3902-MW1R
Water
08/07/19 06:40
08/09/19 10:20
92440792002
3902-MW6
Water
08/07/19 09:25
08/09/19 10:20
92440792003
3902-NES-1
Water
08/07/19 07:34
08/09/19 10:20
92440792004
3902-Field Blank
Water
08/07/19 10:15
08/09/19 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill Compliance
92440792
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92440792001
3902-MW1R
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440792002
3902-MW6
EPA 601OD
SH1
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440792003
3902-NES-1
EPA 601OD
SH1
1
PASI-A
EPA 8260D
CL
4
PASI-C
92440792004
3902-Field Blank
EPA 601OD
SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Landfill Compliance
92440792
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92440792001
3902-MW1 R
EPA 601 OD
Barium
5.4
ug/L
5.0
08/17/19 00:55
EPA 601 OD
Vanadium
2.6J
ug/L
5.0
08/17/19 00:55
EPA 601 OD
Zinc
8.3J
ug/L
10.0
08/17/19 00:55
92440792002
3902-MW6
EPA 601 OD
Barium
1.91
ug/L
5.0
08/17/19 00:58
EPA 601 OD
Copper
2.3J
ug/L
5.0
08/17/19 00:58
EPA 601 OD
Vanadium
2AJ
ug/L
5.0
08/17/19 00:58
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-MW1R Lab ID: 92440792001 Collected: 08/07/19 06:40 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/15/19 10:21
08/17/19 00:55
7440-36-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 00:55
7440-38-2
5.4
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 00:55
7440-39-3
ND
ug/L
1.0
0.20
1
08/15/19 10:21
08/17/19 00:55
7440-41-7
ND
ug/L
1.0
0.40
1
08/15/19 10:21
08/17/19 00:55
7440-43-9
ND
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 00:55
7440-47-3
ND
ug/L
5.0
1.1
1
08/15/19 10:21
08/17/19 00:55
7440-48-4
ND
ug/L
5.0
2.1
1
08/15/19 10:21
08/17/19 00:55
7440-50-8
ND
ug/L
5.0
1.6
1
08/15/19 10:21
08/17/19 00:55
7439-92-1
ND
ug/L
5.0
0.90
1
08/15/19 10:21
08/17/19 00:55
7440-02-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 00:55
7782-49-2
ND
ug/L
5.0
2.5
1
08/15/19 10:21
08/17/19 00:55
7440-22-4
ND
ug/L
5.0
1.6
1
08/15/19 10:21
08/17/19 00:55
7440-31-5
2.6J
ug/L
5.0
1.3
1
08/15/19 10:21
08/17/19 00:55
7440-62-2
8.3J
ug/L
10.0
3.9
1
08/15/19 10:21
08/17/19 00:55
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 22:30 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 03:58
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 03:58
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 03:58
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 03:58
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 03:58
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 03:58
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 03:58
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 03:58
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 03:58
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 03:58
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 03:58
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 03:58
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 03:58
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 03:58
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 03:58
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 03:58
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 03:58
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 03:58
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 03:58
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 03:58
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 03:58
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 03:58
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 03:58
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 03:58
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 03:58
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 03:58
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-MW1R Lab ID: 92440792001 Collected: 08/07/19 06:40 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/19 03:58
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 03:58
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 03:58
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 03:58
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 03:58
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 03:58
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 03:58
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 03:58
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 03:58
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 03:58
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 03:58
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 03:58
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 03:58
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 03:58
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 03:58
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 03:58
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 03:58
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 03:58
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 03:58
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 03:58
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 03:58
1330-20-7
92
%
70-130
1
08/15/19 03:58
460-00-4
91
%
70-130
1
08/15/19 03:58
17060-07-0
102
%
70-130
1
08/15/19 03:58
2037-26-5
Analytical Method: EPA 8260D Mod.
ND
ug/L
2.0
1.2
1
08/12/1917:38
123-91-1
104
%
50-150
1
08/12/1917:38
17060-07-0
107
%
50-150
1
08/12/1917:38
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-MW6 Lab ID: 92440792002 Collected: 08/07/19 09:25 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/15/19 10:21
08/17/19 00:58
7440-36-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 00:58
7440-38-2
1.91
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 00:58
7440-39-3
ND
ug/L
1.0
0.20
1
08/15/19 10:21
08/17/19 00:58
7440-41-7
ND
ug/L
1.0
0.40
1
08/15/19 10:21
08/17/19 00:58
7440-43-9
ND
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 00:58
7440-47-3
ND
ug/L
5.0
1.1
1
08/15/19 10:21
08/17/19 00:58
7440-48-4
2.3J
ug/L
5.0
2.1
1
08/15/19 10:21
08/17/19 00:58
7440-50-8
ND
ug/L
5.0
1.6
1
08/15/19 10:21
08/17/19 00:58
7439-92-1
ND
ug/L
5.0
0.90
1
08/15/19 10:21
08/17/19 00:58
7440-02-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 00:58
7782-49-2
ND
ug/L
5.0
2.5
1
08/15/19 10:21
08/17/19 00:58
7440-22-4
2.4J
ug/L
5.0
1.3
1
08/15/19 10:21
08/17/19 00:58
7440-62-2
ND
ug/L
10.0
3.9
1
08/15/19 10:21
08/17/19 00:58
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 22:34 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 04:17
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 04:17
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 04:17
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 04:17
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 04:17
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 04:17
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 04:17
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 04:17
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 04:17
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 04:17
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 04:17
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 04:17
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 04:17
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 04:17
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 04:17
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 04:17
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 04:17
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 04:17
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 04:17
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 04:17
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 04:17
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 04:17
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 04:17
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 04:17
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 04:17
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 04:17
156-60-5
ND
ug/L
1.0
0.19
1
08/15/19 04:17
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-MW6 Lab ID: 92440792002 Collected: 08/07/19 09:25 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.30
1
08/15/19 04:17
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 04:17
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 04:17
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 04:17
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 04:17
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 04:17
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 04:17
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 04:17
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 04:17
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 04:17
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 04:17
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 04:17
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 04:17
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 04:17
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 04:17
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 04:17
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 04:17
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 04:17
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 04:17
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 04:17
1330-20-7
119
%
70-130
1
08/15/19 04:17
460-00-4
88
%
70-130
1
08/15/19 04:17
17060-07-0
107
%
70-130
1
08/15/19 04:17
2037-26-5
Analytical Method: EPA 8260D Mod.
ND
ug/L
2.0
1.2
1
08/12/1917:58
123-91-1
104
%
50-150
1
08/12/1917:58
17060-07-0
106
%
50-150
1
08/12/1917:58
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-NES-1
Lab ID:
92440792003
Collected:
08/07/19 07:34 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF Prepared
Analyzed
CAS No. Qual
6010 MET ICP
Analytical
Method: EPA 6010D
Preparation Method: EPA 3010A
Cobalt
ND
ug/L
5.0
1.1 1 08/15/19 10:21
08/17/19 01:01
7440-48-4
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Benzene
ND
ug/L
1.0
0.15 1
08/15/19 04:35
71-43-2
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/15/19 04:35
460-00-4
1,2-Dichloroethane-d4 (S)
85
%
70-130
1
08/15/19 04:35
17060-07-0
Toluene-d8 (S)
106
%
70-130
1
08/15/19 04:35
2037-26-5
Date: 08/19/2019 01:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-Field Blank Lab ID: 92440792004 Collected: 08/07/19 10:15 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/15/19 10:21
08/17/19 01:05
7440-36-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 01:05
7440-38-2
ND
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 01:05
7440-39-3
ND
ug/L
1.0
0.20
1
08/15/19 10:21
08/17/19 01:05
7440-41-7
ND
ug/L
1.0
0.40
1
08/15/19 10:21
08/17/19 01:05
7440-43-9
ND
ug/L
5.0
1.0
1
08/15/19 10:21
08/17/19 01:05
7440-47-3
ND
ug/L
5.0
1.1
1
08/15/19 10:21
08/17/19 01:05
7440-48-4
ND
ug/L
5.0
2.1
1
08/15/19 10:21
08/17/19 01:05
7440-50-8
ND
ug/L
5.0
1.6
1
08/15/19 10:21
08/17/19 01:05
7439-92-1
ND
ug/L
5.0
0.90
1
08/15/19 10:21
08/17/19 01:05
7440-02-0
ND
ug/L
10.0
4.7
1
08/15/19 10:21
08/17/19 01:05
7782-49-2
ND
ug/L
5.0
2.5
1
08/15/19 10:21
08/17/19 01:05
7440-22-4
ND
ug/L
5.0
1.6
1
08/15/19 10:21
08/17/19 01:05
7440-31-5
ND
ug/L
5.0
1.3
1
08/15/19 10:21
08/17/19 01:05
7440-62-2
ND
ug/L
10.0
3.9
1
08/15/19 10:21
08/17/19 01:05
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/15/19 10:29 08/15/19 22:42 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/1919:57
67-64-1
ND
ug/L
10.0
0.90
1
08/15/1919:57
107-13-1
ND
ug/L
1.0
0.15
1
08/15/1919:57
71-43-2
ND
ug/L
1.0
0.34
1
08/15/1919:57
74-97-5
ND
ug/L
1.0
0.26
1
08/15/1919:57
75-27-4
ND
ug/L
1.0
0.62
1
08/15/1919:57
75-25-2
ND
ug/L
2.0
0.62
1
08/15/1919:57
74-83-9
ND
ug/L
5.0
3.3
1
08/15/1919:57
78-93-3
ND
ug/L
2.0
0.40
1
08/15/1919:57
75-15-0
ND
ug/L
1.0
0.22
1
08/15/1919:57
56-23-5
ND
ug/L
1.0
0.23
1
08/15/1919:57
108-90-7
ND
ug/L
1.0
0.49
1
08/15/1919:57
75-00-3
ND
ug/L
5.0
2.3
1
08/15/1919:57
67-66-3
ND
ug/L
1.0
0.39
1
08/15/1919:57
74-87-3
ND
ug/L
5.0
0.26
1
08/15/1919:57
96-12-8
ND
ug/L
1.0
0.41
1
08/15/1919:57
124-48-1
ND
ug/L
1.0
0.26
1
08/15/1919:57
106-93-4
ND
ug/L
1.0
0.46
1
08/15/1919:57
74-95-3
ND
ug/L
1.0
0.29
1
08/15/1919:57
95-50-1
ND
ug/L
1.0
0.26
1
08/15/1919:57
106-46-7
ND
ug/L
1.0
0.54
1
08/15/1919:57
110-57-6
ND
ug/L
1.0
0.27
1
08/15/1919:57
75-34-3
ND
ug/L
1.0
0.34
1
08/15/1919:57
107-06-2
ND
ug/L
1.0
0.24
1
08/15/1919:57
75-35-4
ND
ug/L
1.0
0.29
1
08/15/1919:57
156-59-2
ND
ug/L
1.0
0.25
1
08/15/1919:57
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 11 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
Sample: 3902-Field Blank Lab ID: 92440792004 Collected: 08/07/19 10:15 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/19/2019 01:07 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/1919:57
78-87-5
ND
ug/L
1.0
0.30
1
08/15/1919:57
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/1919:57
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/1919:57
100-41-4
ND
ug/L
5.0
0.57
1
08/15/1919:57
591-78-6
ND
ug/L
20.0
12.5
1
08/15/1919:57
74-88-4
ND
ug/L
5.0
3.7
1
08/15/1919:57
75-09-2
ND
ug/L
5.0
4.5
1
08/15/1919:57
108-10-1
ND
ug/L
1.0
0.27
1
08/15/1919:57
100-42-5
ND
ug/L
1.0
0.34
1
08/15/1919:57
630-20-6
ND
ug/L
1.0
0.22
1
08/15/1919:57
79-34-5
ND
ug/L
1.0
0.16
1
08/15/1919:57
127-18-4
ND
ug/L
1.0
0.24
1
08/15/1919:57
108-88-3
ND
ug/L
1.0
0.18
1
08/15/1919:57
71-55-6
ND
ug/L
1.0
0.24
1
08/15/1919:57
79-00-5
ND
ug/L
1.0
0.22
1
08/15/1919:57
79-01-6
ND
ug/L
1.0
0.31
1
08/15/1919:57
75-69-4
ND
ug/L
1.0
0.35
1
08/15/1919:57
96-18-4
ND
ug/L
2.0
1.4
1
08/15/1919:57
108-05-4
ND
ug/L
1.0
0.24
1
08/15/1919:57
75-01-4
ND
ug/L
1.0
0.63
1
08/15/1919:57
1330-20-7
106
%
70-130
1
08/15/1919:57
460-00-4
99
%
70-130
1
08/15/1919:57
17060-07-0
102
%
70-130
1
08/15/1919:57
2037-26-5
Analytical Method: EPA 8260D Mod.
ND
ug/L
2.0
1.2
1
08/12/1913:46
123-91-1
103
%
50-150
1
08/12/1913:46
17060-07-0
105
%
50-150
1
08/12/1913:46
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
QC Batch: 492378 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92440792001, 92440792002, 92440792003, 92440792004
METHOD BLANK: 2654936
Matrix:
Water
Associated Lab Samples: 92440792001, 92440792002, 92440792003,
92440792004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.0
08/17/19 00:05
Arsenic
ug/L
ND
10.0
4.7
08/17/19 00:05
Barium
ug/L
ND
5.0
1.0
08/17/19 00:05
Beryllium
ug/L
ND
1.0
0.20
08/17/19 00:05
Cadmium
ug/L
ND
1.0
0.40
08/17/19 00:05
Chromium
ug/L
ND
5.0
1.0
08/17/19 00:05
Cobalt
ug/L
ND
5.0
1.1
08/17/19 00:05
Copper
ug/L
ND
5.0
2.1
08/17/19 00:05
Lead
ug/L
ND
5.0
1.6
08/17/19 00:05
Nickel
ug/L
ND
5.0
0.90
08/17/19 00:05
Selenium
ug/L
ND
10.0
4.7
08/17/19 00:05
Silver
ug/L
ND
5.0
2.5
08/17/19 00:05
Tin
ug/L
ND
5.0
1.6
08/17/19 00:05
Vanadium
ug/L
ND
5.0
1.3
08/17/19 00:05
Zinc
ug/L
ND
10.0
3.9
08/17/19 00:05
LABORATORY CONTROL SAMPLE:
2654937
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
502
100
80-120
Arsenic
ug/L
500
472
94
80-120
Barium
ug/L
500
522
104
80-120
Beryllium
ug/L
500
491
98
80-120
Cadmium
ug/L
500
498
100
80-120
Chromium
ug/L
500
499
100
80-120
Cobalt
ug/L
500
496
99
80-120
Copper
ug/L
500
510
102
80-120
Lead
ug/L
500
492
98
80-120
Nickel
ug/L
500
495
99
80-120
Selenium
ug/L
500
482
96
80-120
Silver
ug/L
250
248
99
80-120
Tin
ug/L
500
498
100
80-120
Vanadium
ug/L
500
492
98
80-120
Zinc
ug/L
500
471
94
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 13 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Landfill Compliance
92440792
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
2654938
2654939
MS
MSD
92440784001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
488
500
98
100
75-125
2
20
Arsenic
ug/L
ND
500
500
466
474
93
94
75-125
2
20
Barium
ug/L
40.2
500
500
542
546
100
101
75-125
1
20
Beryllium
ug/L
ND
500
500
478
481
96
96
75-125
1
20
Cadmium
ug/L
ND
500
500
490
498
98
100
75-125
2
20
Chromium
ug/L
ND
500
500
484
491
97
98
75-125
1
20
Cobalt
ug/L
ND
500
500
473
480
95
96
75-125
1
20
Copper
ug/L
8.3
500
500
498
503
98
99
75-125
1
20
Lead
ug/L
ND
500
500
473
479
95
96
75-125
1
20
Nickel
ug/L
ND
500
500
472
479
94
96
75-125
1
20
Selenium
ug/L
ND
500
500
492
504
98
100
75-125
2
20
Silver
ug/L
ND
250
250
242
244
97
98
75-125
1
20
Tin
ug/L
ND
500
500
480
490
96
98
75-125
2
20
Vanadium
ug/L
ND
500
500
479
486
96
97
75-125
1
20
Zinc
ug/L
ND
500
500
465
470
93
94
75-125
1
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
QC Batch: 492377
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92440792001, 92440792002,
92440792004
METHOD BLANK: 2654906
Matrix: Water
Associated Lab Samples: 92440792001, 92440792002,
92440792004
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Thallium ug/L
ND 0.10 0.060 08/15/19 20:43
LABORATORY CONTROL SAMPLE: 2654907
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 9.7 97
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2654908 2654909
MS MSD
92440783001
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND
10 10 9.6 9.8
96 98 75-125 2 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
QC Batch: 492311 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92440792001, 92440792002, 92440792003
METHOD BLANK: 2654361 Matrix:
Associated Lab Samples: 92440792001, 92440792002, 92440792003
Blank
Parameter Units Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/15/19 03:40
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/15/19 03:40
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/15/19 03:40
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/15/19 03:40
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/15/19 03:40
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/15/19 03:40
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/15/19 03:40
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/15/19 03:40
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/15/19 03:40
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/15/19 03:40
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/15/19 03:40
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/15/19 03:40
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/15/19 03:40
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/15/19 03:40
2-Hexanone
ug/L
ND
5.0
0.57
08/15/19 03:40
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/15/19 03:40
Acetone
ug/L
ND
25.0
6.2
08/15/19 03:40
Acrylonitrile
ug/L
ND
10.0
0.90
08/15/19 03:40
Benzene
ug/L
ND
1.0
0.15
08/15/19 03:40
Bromochloromethane
ug/L
ND
1.0
0.34
08/15/19 03:40
Bromodichloromethane
ug/L
ND
1.0
0.26
08/15/19 03:40
Bromoform
ug/L
ND
1.0
0.62
08/15/19 03:40
Bromomethane
ug/L
ND
2.0
0.62
08/15/19 03:40
Carbon disulfide
ug/L
ND
2.0
0.40
08/15/19 03:40
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/15/19 03:40
Chlorobenzene
ug/L
ND
1.0
0.23
08/15/19 03:40
Chloroethane
ug/L
ND
1.0
0.49
08/15/19 03:40
Chloroform
ug/L
ND
5.0
2.3
08/15/19 03:40
Chloromethane
ug/L
ND
1.0
0.39
08/15/19 03:40
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/15/19 03:40
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/15/19 03:40
Dibromochloromethane
ug/L
ND
1.0
0.41
08/15/19 03:40
Dibromomethane
ug/L
ND
1.0
0.46
08/15/19 03:40
Ethylbenzene
ug/L
ND
1.0
0.26
08/15/19 03:40
lodomethane
ug/L
ND
20.0
12.5
08/15/19 03:40
Methylene Chloride
ug/L
ND
5.0
3.7
08/15/19 03:40
Styrene
ug/L
ND
1.0
0.27
08/15/19 03:40
Tetrachloroethene
ug/L
ND
1.0
0.16
08/15/19 03:40
Toluene
ug/L
ND
1.0
0.24
08/15/19 03:40
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/15/19 03:40
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/15/19 03:40
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
METHOD BLANK: 2654361
Matrix:
Water
Associated Lab Samples: 92440792001,
92440792002, 92440792003
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/15/19 03:40
Trichloroethene
ug/L
ND
1.0
0.22
08/15/19 03:40
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/15/19 03:40
Vinyl acetate
ug/L
ND
2.0
1.4
08/15/19 03:40
Vinyl chloride
ug/L
ND
1.0
0.24
08/15/19 03:40
Xylene (Total)
ug/L
ND
1.0
0.63
08/15/19 03:40
1,2-Dichloroethane-d4 (S)
%
84
70-130
08/15/19 03:40
4-Bromofluorobenzene (S)
%
117
70-130
08/15/19 03:40
Toluene-d8 (S)
%
110
70-130
08/15/19 03:40
LABORATORY CONTROL SAMPLE:
Parameter
2654362
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
51.5
103
70-130
1,1,1-Trichloroethane
ug/L
50
54.2
108
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
52.1
104
70-130
1,1,2-Trichloroethane
ug/L
50
44.1
88
70-130
1,1-Dichloroethane
ug/L
50
51.2
102
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
52.7
105
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-130
1,2-Dibromoethane (EDB)
ug/L
50
51.4
103
70-130
1,2-Dichlorobenzene
ug/L
50
42.4
85
70-130
1,2-Dichloroethane
ug/L
50
51.8
104
70-130
1,2-Dichloropropane
ug/L
50
52.5
105
70-130
1,4-Dichlorobenzene
ug/L
50
43.9
88
70-130
2-Butanone (MEK)
ug/L
100
104
104
64-135
2-Hexanone
ug/L
100
93.2
93
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
80.3
80
70-130
Acetone
ug/L
100
96.1
96
61-157
Acrylonitrile
ug/L
250
242
97
61-143
Benzene
ug/L
50
52.4
105
70-130
Bromochloromethane
ug/L
50
51.5
103
70-130
Bromodichloromethane
ug/L
50
53.5
107
70-130lK
Bromoform
ug/L
50
51.6
103
70-130
Bromomethane
ug/L
50
47.3
95
38-130
Carbon disulfide
ug/L
50
53.3
107
68-130
Carbon tetrachloride
ug/L
50
50.2
100
70-130
Chlorobenzene
ug/L
50
46.5
93
70-130
Chloroethane
ug/L
50
55.2
110
37-142
Chloroform
ug/L
50
50.9
102
70-130
Chloromethane
ug/L
50
55.0
110
48-130
cis-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
cis-1,3-Dichloropropene
ug/L
50
47.1
94
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
LABORATORY CONTROL SAMPLE:
2654362
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
44.7
89
70-130
Dibromomethane
ug/L
50
50.2
100
70-130
Ethylbenzene
ug/L
50
46.6
93
70-130
lodomethane
ug/L
100
94.6
95
40-1301K
Methylene Chloride
ug/L
50
49.4
99
67-132
Styrene
ug/L
50
50.2
100
70-130
Tetrachloroethene
ug/L
50
41.2
82
69-130
Toluene
ug/L
50
44.6
89
70-130
trans-1,2-Dichloroethene
ug/L
50
54.8
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
40.7
81
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
45.1
90
35-189
Trichloroethene
ug/L
50
50.9
102
70-130
Trichlorofluoromethane
ug/L
50
52.9
106
63-130
Vinyl acetate
ug/L
100
104
104
55-143 IK
Vinyl chloride
ug/L
50
59.6
119
70-131
Xylene (Total)
ug/L
150
147
98
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
94
70-130
MATRIX SPIKE SAMPLE:
2654364
92440811002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20.4
102
73-134
1,1,1-Trichloroethane
ug/L
ND
20
20.5
103
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
19.7
98
70-136
1,1,2-Trichloroethane
ug/L
ND
20
22.0
110
70-135
1,1-Dichloroethane
ug/L
ND
20
20.0
100
70-139
1,1-Dichloroethene
ug/L
ND
20
22.5
113
70-154
1,2,3-Trichloropropane
ug/L
ND
20
14.0
70
71-137 M1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.5
92
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.4
102
70-137
1,2-Dichlorobenzene
ug/L
ND
20
18.3
91
70-133
1,2-Dichloroethane
ug/L
ND
20
19.9
99
70-137
1,2-Dichloropropane
ug/L
ND
20
22.2
111
70-140
1,4-Dichlorobenzene
ug/L
ND
20
17.8
89
70-133
2-Butanone (MEK)
ug/L
ND
40
42.5
106
60-139
2-Hexanone
ug/L
ND
40
40.2
100
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
42.2
105
65-135
Acetone
ug/L
ND
40
39.8
99
60-148
Acrylonitrile
ug/L
ND
100
88.1
88
64-147
Benzene
ug/L
ND
20
21.8
109
70-151
Bromochloromethane
ug/L
ND
20
19.4
97
70-141
Bromodichloromethane
ug/L
ND
20
21.4
107
70-138
Bromoform
ug/L
ND
20
18.4
92
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
MATRIX SPIKE SAMPLE:
Parameter
2654364
Units
92440811002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
19.1
95
15-152
Carbon disulfide
ug/L
ND
20
22.1
110
69-149
Carbon tetrachloride
ug/L
ND
20
21.0
105
70-143
Chlorobenzene
ug/L
ND
20
19.8
99
70-138
Chloroethane
ug/L
ND
20
25.6
128
52-163
Chloroform
ug/L
ND
20
19.1
96
70-139
Chloromethane
ug/L
ND
20
22.0
109
41-139
cis-1,2-Dichloroethene
ug/L
ND
20
19.5
97
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
19.9
100
70-137
Dibromochloromethane
ug/L
ND
20
18.6
93
70-134
Dibromomethane
ug/L
ND
20
20.4
102
70-138
Ethylbenzene
ug/L
ND
20
19.8
99
66-153
lodomethane
ug/L
ND
40
30.4
76
20-138
Methylene Chloride
ug/L
ND
20
18.7
93
42-159
Styrene
ug/L
ND
20
19.4
97
70-135
Tetrachloroethene
ug/L
ND
20
19.8
99
59-143
Toluene
ug/L
ND
20
20.2
101
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
21.4
107
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
19.5
98
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.0
75
47-135
Trichloroethene
ug/L
ND
20
21.9
109
70-147
Trichlorofluoromethane
ug/L
ND
20
23.4
117
70-148
Vinyl acetate
ug/L
ND
40
37.2
93
49-151
Vinyl chloride
ug/L
ND
20
24.7
123
70-156
Xylene (Total)
ug/L
ND
60
59.8
100
63-158
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
103
70-130
SAMPLE DUPLICATE: 2654363
Parameter
Units
92440811001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
SAMPLE DUPLICATE: 2654363
Parameter
Units
92440811001
Result
Dup
Result RPD
Max
RPD
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
96
98
4-Bromofluorobenzene (S)
%
105
99
Toluene-d8 (S)
%
97
103
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
QC Batch: 492312 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92440792004
METHOD BLANK: 2654368
Associated Lab Samples: 92440792004
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/15/19 19:40
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/15/19 19:40
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/15/19 19:40
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/15/19 19:40
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/15/19 19:40
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/15/19 19:40
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/15/19 19:40
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/15/19 19:40
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/15/19 19:40
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/15/19 19:40
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/15/19 19:40
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/15/19 19:40
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/15/19 19:40
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/15/19 19:40
2-Hexanone
ug/L
ND
5.0
0.57
08/15/19 19:40
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/15/19 19:40
Acetone
ug/L
ND
25.0
6.2
08/15/19 19:40
Acrylonitrile
ug/L
ND
10.0
0.90
08/15/19 19:40
Benzene
ug/L
ND
1.0
0.15
08/15/19 19:40
Bromochloromethane
ug/L
ND
1.0
0.34
08/15/19 19:40
Bromodichloromethane
ug/L
ND
1.0
0.26
08/15/19 19:40
Bromoform
ug/L
ND
1.0
0.62
08/15/19 19:40
Bromomethane
ug/L
ND
2.0
0.62
08/15/19 19:40
Carbon disulfide
ug/L
ND
2.0
0.40
08/15/19 19:40
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/15/19 19:40
Chlorobenzene
ug/L
ND
1.0
0.23
08/15/19 19:40
Chloroethane
ug/L
ND
1.0
0.49
08/15/19 19:40
Chloroform
ug/L
ND
5.0
2.3
08/15/19 19:40
Chloromethane
ug/L
ND
1.0
0.39
08/15/19 19:40
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/15/19 19:40
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/15/19 19:40
Dibromochloromethane
ug/L
ND
1.0
0.41
08/15/19 19:40
Dibromomethane
ug/L
ND
1.0
0.46
08/15/19 19:40
Ethylbenzene
ug/L
ND
1.0
0.26
08/15/19 19:40
lodomethane
ug/L
ND
20.0
12.5
08/15/19 19:40
Methylene Chloride
ug/L
ND
5.0
3.7
08/15/19 19:40
Styrene
ug/L
ND
1.0
0.27
08/15/19 19:40
Tetrachloroethene
ug/L
ND
1.0
0.16
08/15/19 19:40
Toluene
ug/L
ND
1.0
0.24
08/15/19 19:40
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/15/19 19:40
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/15/19 19:40
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
METHOD BLANK: 2654368
Matrix:
Water
Associated Lab Samples: 92440792004
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/15/19 19:40
Trichloroethene
ug/L
ND
1.0
0.22
08/15/19 19:40
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/15/19 19:40
Vinyl acetate
ug/L
ND
2.0
1.4
08/15/19 19:40
Vinyl chloride
ug/L
ND
1.0
0.24
08/15/19 19:40
Xylene (Total)
ug/L
ND
1.0
0.63
08/15/19 19:40
1,2-Dichloroethane-d4 (S)
%
99
70-130
08/15/19 19:40
4-Bromofluorobenzene (S)
%
106
70-130
08/15/19 19:40
Toluene-d8 (S)
%
101
70-130
08/15/19 19:40
LABORATORY CONTROL SAMPLE:
Parameter
2654369
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.1
108
70-130
1,1,1-Trichloroethane
ug/L
50
50.9
102
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
50.1
100
70-130
1,1,2-Trichloroethane
ug/L
50
52.4
105
70-130
1,1-Dichloroethane
ug/L
50
51.0
102
70-130
1,1-Dichloroethene
ug/L
50
51.9
104
70-130
1,2,3-Trichloropropane
ug/L
50
51.8
104
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
50.8
102
70-130
1,2-Dibromoethane (EDB)
ug/L
50
52.6
105
70-130
1,2-Dichlorobenzene
ug/L
50
48.9
98
70-130
1,2-Dichloroethane
ug/L
50
47.2
94
70-130
1,2-Dichloropropane
ug/L
50
51.3
103
70-130
1,4-Dichlorobenzene
ug/L
50
49.2
98
70-130
2-Butanone (MEK)
ug/L
100
106
106
64-135
2-Hexanone
ug/L
100
109
109
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
110
110
70-130
Acetone
ug/L
100
104
104
61-157
Acrylonitrile
ug/L
250
255
102
61-143
Benzene
ug/L
50
51.7
103
70-130
Bromochloromethane
ug/L
50
53.9
108
70-130
Bromodichloromethane
ug/L
50
53.8
108
70-130lK
Bromoform
ug/L
50
55.3
111
70-130
Bromomethane
ug/L
50
50.4
101
38-130
Carbon disulfide
ug/L
50
47.7
95
68-130
Carbon tetrachloride
ug/L
50
51.3
103
70-130
Chlorobenzene
ug/L
50
50.1
100
70-130
Chloroethane
ug/L
50
40.8
82
37-142
Chloroform
ug/L
50
50.5
101
70-130
Chloromethane
ug/L
50
46.1
92
48-130
cis-1,2-Dichloroethene
ug/L
50
49.8
100
70-130
cis-1,3-Dichloropropene
ug/L
50
56.2
112
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 31

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
LABORATORY CONTROL SAMPLE:
2654369
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
54.5
109
70-130
Dibromomethane
ug/L
50
51.2
102
70-130
Ethylbenzene
ug/L
50
51.3
103
70-130
lodomethane
ug/L
100
78.4
78
40-1301K
Methylene Chloride
ug/L
50
47.6
95
67-132
Styrene
ug/L
50
51.7
103
70-130
Tetrachloroethene
ug/L
50
51.8
104
69-130
Toluene
ug/L
50
50.1
100
70-130
trans-1,2-Dichloroethene
ug/L
50
50.7
101
70-130
trans- 1,3-Dichloropropene
ug/L
50
55.9
112
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
57.6
115
35-189
Trichloroethene
ug/L
50
51.3
103
70-130
Trichlorofluoromethane
ug/L
50
49.4
99
63-130
Vinyl acetate
ug/L
100
114
114
55-143
Vinyl chloride
ug/L
50
48.3
97
70-131
Xylene (Total)
ug/L
150
155
103
70-130
1,2-Dichloroethane-d4 (S)
%
104
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE SAMPLE:
2654371
92440784006
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.6
108
73-134
1,1,1-Trichloroethane
ug/L
ND
20
22.6
113
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
21.1
106
70-136
1,1,2-Trichloroethane
ug/L
ND
20
21.3
107
70-135
1,1-Dichloroethane
ug/L
ND
20
22.9
115
70-139
1,1-Dichloroethene
ug/L
ND
20
23.9
120
70-154
1,2,3-Trichloropropane
ug/L
ND
20
22.3
112
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
19.0
95
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.0
105
70-137
1,2-Dichlorobenzene
ug/L
ND
20
20.6
103
70-133
1,2-Dichloroethane
ug/L
ND
20
21.0
105
70-137
1,2-Dichloropropane
ug/L
ND
20
22.1
111
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.5
102
70-133
2-Butanone (MEK)
ug/L
ND
40
43.0
108
60-139
2-Hexanone
ug/L
ND
40
42.6
107
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
42.1
105
65-135
Acetone
ug/L
ND
40
53.0
132
60-148
Acrylonitrile
ug/L
ND
100
109
109
64-147
Benzene
ug/L
ND
20
22.8
114
70-151
Bromochloromethane
ug/L
ND
20
24.1
121
70-141
Bromodichloromethane
ug/L
ND
20
21.9
110
70-138
Bromoform
ug/L
ND
20
19.9
99
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
MATRIX SPIKE SAMPLE:
Parameter
2654371
Units
92440784006
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
19.9
99
15-152
Carbon disulfide
ug/L
ND
20
25.3
127
69-149
Carbon tetrachloride
ug/L
ND
20
22.3
111
70-143
Chlorobenzene
ug/L
ND
20
21.1
105
70-138
Chloroethane
ug/L
ND
20
24.9
125
52-163
Chloroform
ug/L
ND
20
22.1
111
70-139
Chloromethane
ug/L
ND
20
28.6
143
41-139 M1
cis-1,2-Dichloroethene
ug/L
ND
20
22.3
111
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
22.7
114
70-137
Dibromochloromethane
ug/L
ND
20
20.6
103
70-134
Dibromomethane
ug/L
ND
20
20.8
104
70-138
Ethylbenzene
ug/L
ND
20
22.3
111
66-153
lodomethane
ug/L
ND
40
42.9
107
20-138
Methylene Chloride
ug/L
ND
20
22.3
111
42-159
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
21.6
108
59-143
Toluene
ug/L
ND
20
21.6
108
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
23.1
115
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
22.0
110
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
20.9
104
47-135
Trichloroethene
ug/L
ND
20
22.1
111
70-147
Trichlorofluoromethane
ug/L
ND
20
22.9
114
70-148
Vinyl acetate
ug/L
ND
40
45.5
114
49-151
Vinyl chloride
ug/L
ND
20
22.9
115
70-156
Xylene (Total)
ug/L
ND
60
66.2
110
63-158
1,2-Dichloroethane-d4 (S)
%
96
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
99
70-130
SAMPLE DUPLICATE: 2654370
Parameter
Units
92440784005
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
SAMPLE DUPLICATE: 2654370
Parameter
Units
92440784005
Result
Dup
Result
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
10.2J
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
ND
ND
Chloroethane
ug/L
ND
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
ND
ND
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
99
101
4-Bromofluorobenzene (S)
%
104
104
Toluene-d8(S)
%
101
100
Max
RPD RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 25 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill Compliance
Pace Project No.: 92440792
QC Batch: 492032 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92440792001, 92440792002, 92440792004
METHOD BLANK: 2653245
Matrix:
Water
Associated Lab Samples:
92440792001, 92440792002, 92440792004
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 08/12/19 12:09
1,2-Dichloroethane-d4 (S)
%
97
50-150
08/12/19 12:09
Toluene-d8 (S)
%
103
50-150
08/12/19 12:09
LABORATORY CONTROL SAMPLE: 2653246
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 18.9 94 70-130
1,2-Dichloroethane-d4 (S) % 97 50-150
Toluene-d8(S) % 103 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2653247
2653248
MS
MSD
92440795005 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 4.0 20
20 21.8 22.3
89
92
50-150
2 30
1,2-Dichloroethane-d4 (S)
%
98
100
50-150
30
Toluene-d8 (S)
%
102
102
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC.
Page 26 of 31

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: Butner Landfill Compliance
Pace Project No.: 92440792
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/19/2019 01:07 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill Compliance
92440792
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92440792001
3902-MW1 R
EPA 3010A
492378
EPA 6010D
492489
92440792002
3902-MW6
EPA 3010A
492378
EPA 6010D
492489
92440792003
3902-NES-1
EPA 3010A
492378
EPA 6010D
492489
92440792004
3902-Field Blank
EPA 3010A
492378
EPA 6010D
492489
92440792001
3902-MW1 R
EPA 3010A
492377
EPA 6020B
492487
92440792002
3902-MW6
EPA 3010A
492377
EPA 6020B
492487
92440792004
3902-Field Blank
EPA 3010A
492377
EPA 6020B
492487
92440792001
3902-MW1R
EPA 8260D
492311
92440792002
3902-MW6
EPA 8260D
492311
92440792003
3902-NES-1
EPA 8260D
492311
92440792004
3902-Field Blank
EPA 8260D
492312
92440792001
3902-MW1 R
EPA 8260D Mod.
492032
92440792002
3902-MW6
EPA 8260D Mod.
492032
92440792004
3902-Field Blank
EPA 8260D Mod.
492032
Date: 08/19/2019 01:07 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 31

Document Name:
Sample Condition Upon Receipt(SCUR) Page 1 of 2
Zmocal-j�Document No.: issuingAuthoritY:
F-CAR-0-033-Rev.06 Pace Carolin as Quality Office
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑f Raleigh❑ Mechanicsville
Sample Condition Client Nance: `,�O . 9244m792
Upon Receipt Project #; W
l} t�l�l�til�tl��tti
Courier: ❑Fed l:x []UPS ❑LISPS ❑Client
❑ Commercial []Pace []Other: 92440192
Custody Seal Present? ❑Yes ❑No Seals Intact? ❑Yes QNo
f Date/Initials Person Examining Contents:
Packing Material: []Bubble Wrap ❑Bubble Bags ❑None ❑ Other SiDI0gical Tissue Frozenr
[]Yes []No l❑N/A
Thermometer: 92TQ4$ Type of Ice: ❑wet [:]Blue❑None
❑IR Gun 10:
Cooler Tenip ('C): 1 Correctlon Factor: Add/Subtract {`C) Q,Q
' Tempshauld be above freezing to 6°C
Cooler Temp Corrected ('C): ' ❑Samples out of temp criteria. Samples on ice, cooiing process
hashegun
USDA Regulated Soil (0 N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from aforeign source (internationally,
I —Iv— mrv,, including Hawaii and Puetto Rico)? []Yes []NO
Chain of Custody Present?
Sarnbles Aritved within Hold
Short Hold. Time Analysis (02 hr.)?
Rush Turn Around Time Requested?
5uffic"sent Volume?
Correct Containers Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/ID/Anatysis
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Seals Present?
COMMENTSISAMPLE DISCREPANCY
❑Na
❑N/A
1.
[]No
❑NIA
2.
❑No
[]N/A
3.
[]No
❑N/A
4.
❑No ❑N/A 5
[]No ❑N/A 6
F.1Na - El N/A
❑Yes ONO ❑NIA ?.
[]Yes ❑No ❑N/A 8.
[]Yes [:]No ❑N/A 9.
IN
b-d
❑No ❑N/A 10, C rh
[]No []NIA 11.
Lot ID oftplit containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/nme:
Field Data Required? ❑Yes ❑No
Project Manager SCURF Review: Date: Z
Project Manager 5RF Review:
�I tN1(1 Date: g
Page 29 of 31

1FdCeAnalytkal m bampre wnDanlr
Issuing Authority:
Carolinas Quallty Office
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, 011 and Grease, DRO/8015 (water) OOC, LLHg
**Bottom half of box is to list number of bottle
U
A
S
z
m m d
v
y
otl
z
C
c C c
Ln
a 7 :3
C
i
=
N
V V u
u
V
V
10 i4
u,
1�
IO
a19
Ln O Ci
—
Ln
Ln
N Ln O
,0
N
a
m
v
E
a m ry
.�i
m
m
m
m
m
m m cc
f
2
i
3
4
5
s
7
a
4
10
11
12
PM: NMG Due Date: 08 2/ 3/19
CLIENT: 92-Joyce Eng
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH uponretelpt Date preservation adjusted Timepreservat€an Amount of
Preservative
adjusted adjusted
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form w€116e sent to the North Carolina OEHNA Certif cation Office (i.e.
Out of hold, incorrect preservative, out of ternp, incorrect containers.
Page 30 of 31

is
5
u
m
G ?'
N �
0
.Q
O y
E
N -No
d ,m
crc
c
CD
_T ~
z
w
� U
ao
°W
OLd
N R
m
U0
LL
7
O"
O
Z C
aL
=v
U�
N
M
(N/A)
TIT[N
�'
Q
D
Q
I�elul seldweS
QSNIM
O
J81000
z
y
paleaS Apolsno
7
U
U
w
J
a
(NIA)
..)-
aol uo pan!aaay
v7
C
'm
o
(N11,) awialyD lenpisab
D u! dV431
r
a
C
m
~!
z°
z
y
U
m
�
U.
m
❑
llugoo
x
cr
a
auezua8
x
0
m
auexol❑ y' R
x
x
x
v
Z
H
a
cc
a
LU
c
S,OQA I ddd ON
x
x
x
N
SlelaW I ddy ON
x
x
x
x
NIA
;sal sasl�}eud
o
v
a
c
Z
k,
�
,aylD
v
>
�`
loueylaW
ox
0
r
EDZSZEN
yprn
w
wU
4
>
xHDN
e
Il
00
OH
xi
x
o
y
C7
O
soNH
,�
K i
I I
I
EL
6DSEH
3
z
r c
o u
..
c
T
o
W
E
ki
pavasaiduD
E
-°
N C
4
co)
Q
Skf3NItl11V0��0#
r`
r
—
�.
-
I
.�
NO!l331103 ltl dW31-FIMYS
d
w
w
W
H
Z
J
a
J
a
O
in
ZIL
Q
O
O
^
U^^
Z
z
Z
f
Z
O
J
F
W
Z
ir
U
D
J
d
a
VI
a~
Q
1�rVC-
V]
O
L
7
-i
F
T
m
�1
E
10
N
N13
..
Q
❑
w
>
m
>
7
C17
m
x
j
(dWD�=� 8Vk3�J=�) 3dAi 3ld WVS
(�
C7
(�
°m
j
o
Z
p
Z
O
Y
Ti
£3
y�
(CHI of sapoa P4en Has) 3000 XIk11VW
72
w
°
m
o
rr
f0 9
N
p
m
o
0o33awo3ao°
c
a
T
t
m
m m
m
0
`
m
C°
'A ¢
Z.
U
4.
U
U
x� aea
aZ,o3a0,
O
U
7
N
m
ro
z
W
'L
U)
w
O
v
c
q
V
❑
W $. a
L)
717
u
f6
N
mo
J mar 3
C
o
w
N
g
o
cal.cal.R
o
r
a@ o E
Y
z
z
O
Q
to
C:
M
N ycu
j
CC
r
CO
❑
E
cu2
�
Tema
CIJL!
a Uu
cta
a
w
CO
0
3
m
N o E
L
f0
N
Z
.O
m
m
i°
O
m
vl
Z
ILL
e
J
N
m
❑
0) ^A
01
m
c m
c
H
C
H
; '�
m
n
o
Ul
m
—
E
c
#W311
N (7
li7
0
n
m
CDQ
N
m
U) [t
U
¢
C.'3
w
a
m
Page 31 of 31

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 20, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner LF Surface Water
Pace Project No.: 92440811
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner LF Surface Water
Pace Project No.: 92440811
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 23

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner LF Surface Water
Pace Project No.: 92440811
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92440811001
92440811002
3902-SW1
3902-SW2
Water
Water
08/07/19 07:55
08/07/19 07:40
08/09/19 10:20
08/09/19 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner LF Surface Water
92440811
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92440811001
3902-SW1
EPA 601 OD
IDS
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
92440811002
3902-SW2
EPA 601OD
DS, SH1
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
CL
50
PASI-C
EPA 8260D Mod.
LMB
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner LF Surface Water
92440811
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92440811001
3902-SW1
EPA 601 OD
Barium
70.0
ug/L
5.0
08/19/19 00:58
EPA 601 OD
Cobalt
2.5J
ug/L
5.0
08/19/19 00:58
EPA 601 OD
Copper
3.2J
ug/L
5.0
08/19/19 00:58
EPA 601 OD
Lead
2.2J
ug/L
5.0
08/19/19 00:58
EPA 601 OD
Nickel
8.8
ug/L
5.0
08/19/19 00:58
EPA 601 OD
Hardness, Total(SM 2340B)
316000
ug/L
662
08/19/19 00:58
EPA 601 OD
Vanadium
1 AJ
ug/L
5.0
08/19/19 00:58
EPA8260D Mod.
1,4-Dioxane (p-Dioxane)
10.5
ug/L
2.0
08/14/19 15:37
92440811002
3902-SW2
EPA 601 OD
Barium
94.4
ug/L
5.0
08/19/19 01:01
EPA 601 OD
Copper
3.3J
ug/L
5.0
08/19/19 01:01
EPA 601 OD
Nickel
14.8
ug/L
5.0
08/19/19 01:01
EPA 601 OD
Hardness, Total(SM 2340B)
460000
ug/L
3310
08/20/19 00:19
EPA 601 OD
Vanadium
2.3J
ug/L
5.0
08/19/19 01:01
EPA8260D Mod.
1,4-Dioxane (p-Dioxane)
22.3
ug/L
2.0
08/14/19 15:57
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Surface Water
Pace Project No.: 92440811
Sample: 3902-SW1 Lab ID: 92440811001 Collected: 08/07/19 07:55 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/20/2019 03:24 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/15/19 17:10
08/19/19 00:58
7440-36-0
ND
ug/L
10.0
4.7
1
08/15/19 17:10
08/19/19 00:58
7440-38-2
70.0
ug/L
5.0
1.0
1
08/15/19 17:10
08/19/19 00:58
7440-39-3
ND
ug/L
1.0
0.20
1
08/15/19 17:10
08/19/19 00:58
7440-41-7
ND
ug/L
1.0
0.40
1
08/15/19 17:10
08/19/19 00:58
7440-43-9
ND
ug/L
5.0
1.0
1
08/15/19 17:10
08/19/19 00:58
7440-47-3
2.5J
ug/L
5.0
1.1
1
08/15/19 17:10
08/19/19 00:58
7440-48-4
3.2J
ug/L
5.0
2.1
1
08/15/19 17:10
08/19/19 00:58
7440-50-8
2.2J
ug/L
5.0
1.6
1
08/15/19 17:10
08/19/19 00:58
7439-92-1
8.8
ug/L
5.0
0.90
1
08/15/19 17:10
08/19/19 00:58
7440-02-0
ND
ug/L
10.0
4.7
1
08/15/19 17:10
08/19/19 00:58
7782-49-2
ND
ug/L
5.0
2.5
1
08/15/19 17:10
08/19/19 00:58
7440-22-4
316000
ug/L
662
131
1
08/15/19 17:10
08/19/19 00:58
1.4J
ug/L
5.0
1.3
1
08/15/19 17:10
08/19/19 00:58
7440-62-2
ND
ug/L
10.0
3.9
1
08/15/19 17:10
08/19/19 00:58
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/15/1917:17 08/16/1916:47 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 04:53
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 04:53
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 04:53
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 04:53
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 04:53
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 04:53
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 04:53
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 04:53
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 04:53
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 04:53
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 04:53
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 04:53
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 04:53
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 04:53
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 04:53
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 04:53
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 04:53
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 04:53
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 04:53
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 04:53
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 04:53
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 04:53
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 04:53
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 04:53
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 04:53
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 04:53
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Surface Water
Pace Project No.: 92440811
Sample: 3902-SW1 Lab ID: 92440811001 Collected: 08/07/19 07:55 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/20/2019 03:24 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/19 04:53
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 04:53
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 04:53
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 04:53
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 04:53
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 04:53
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 04:53
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 04:53
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 04:53
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 04:53
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 04:53
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 04:53
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 04:53
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 04:53
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 04:53
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 04:53
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 04:53
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 04:53
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 04:53
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 04:53
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 04:53
1330-20-7
105
%
70-130
1
08/15/19 04:53
460-00-4
96
%
70-130
1
08/15/19 04:53
17060-07-0
97
%
70-130
1
08/15/19 04:53
2037-26-5
Analytical Method: EPA 8260D Mod.
10.5
ug/L
2.0
1.2
1
08/14/1915:37
123-91-1
112
%
50-150
1
08/14/1915:37
17060-07-0
103
%
50-150
1
08/14/1915:37
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Surface Water
Pace Project No.: 92440811
Sample: 3902-SW2 Lab ID: 92440811002 Collected: 08/07/19 07:40 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 08/20/2019 03:24 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.0
1
08/15/19 17:10
08/19/19 01:01
7440-36-0
ND
ug/L
10.0
4.7
1
08/15/19 17:10
08/19/19 01:01
7440-38-2
94.4
ug/L
5.0
1.0
1
08/15/19 17:10
08/19/19 01:01
7440-39-3
ND
ug/L
1.0
0.20
1
08/15/19 17:10
08/19/19 01:01
7440-41-7
ND
ug/L
1.0
0.40
1
08/15/19 17:10
08/19/19 01:01
7440-43-9
ND
ug/L
5.0
1.0
1
08/15/19 17:10
08/19/19 01:01
7440-47-3
ND
ug/L
5.0
1.1
1
08/15/19 17:10
08/19/19 01:01
7440-48-4
3.3J
ug/L
5.0
2.1
1
08/15/19 17:10
08/19/19 01:01
7440-50-8
ND
ug/L
5.0
1.6
1
08/15/19 17:10
08/19/19 01:01
7439-92-1
14.8
ug/L
5.0
0.90
1
08/15/19 17:10
08/19/19 01:01
7440-02-0
ND
ug/L
10.0
4.7
1
08/15/19 17:10
08/19/19 01:01
7782-49-2
ND
ug/L
5.0
2.5
1
08/15/19 17:10
08/19/19 01:01
7440-22-4
460000
ug/L
3310
655
5
08/15/19 17:10
08/20/19 00:19
2.3J
ug/L
5.0
1.3
1
08/15/19 17:10
08/19/19 01:01
7440-62-2
ND
ug/L
10.0
3.9
1
08/15/19 17:10
08/19/19 01:01
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 08/15/1917:17 08/16/1916:55 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/15/19 05:12
67-64-1
ND
ug/L
10.0
0.90
1
08/15/19 05:12
107-13-1
ND
ug/L
1.0
0.15
1
08/15/19 05:12
71-43-2
ND
ug/L
1.0
0.34
1
08/15/19 05:12
74-97-5
ND
ug/L
1.0
0.26
1
08/15/19 05:12
75-27-4
ND
ug/L
1.0
0.62
1
08/15/19 05:12
75-25-2
ND
ug/L
2.0
0.62
1
08/15/19 05:12
74-83-9
ND
ug/L
5.0
3.3
1
08/15/19 05:12
78-93-3
ND
ug/L
2.0
0.40
1
08/15/19 05:12
75-15-0
ND
ug/L
1.0
0.22
1
08/15/19 05:12
56-23-5
ND
ug/L
1.0
0.23
1
08/15/19 05:12
108-90-7
ND
ug/L
1.0
0.49
1
08/15/19 05:12
75-00-3
ND
ug/L
5.0
2.3
1
08/15/19 05:12
67-66-3
ND
ug/L
1.0
0.39
1
08/15/19 05:12
74-87-3
ND
ug/L
5.0
0.26
1
08/15/19 05:12
96-12-8
ND
ug/L
1.0
0.41
1
08/15/19 05:12
124-48-1
ND
ug/L
1.0
0.26
1
08/15/19 05:12
106-93-4
ND
ug/L
1.0
0.46
1
08/15/19 05:12
74-95-3
ND
ug/L
1.0
0.29
1
08/15/19 05:12
95-50-1
ND
ug/L
1.0
0.26
1
08/15/19 05:12
106-46-7
ND
ug/L
1.0
0.54
1
08/15/19 05:12
110-57-6
ND
ug/L
1.0
0.27
1
08/15/19 05:12
75-34-3
ND
ug/L
1.0
0.34
1
08/15/19 05:12
107-06-2
ND
ug/L
1.0
0.24
1
08/15/19 05:12
75-35-4
ND
ug/L
1.0
0.29
1
08/15/19 05:12
156-59-2
ND
ug/L
1.0
0.25
1
08/15/19 05:12
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner LF Surface Water
Pace Project No.: 92440811
Sample: 3902-SW2 Lab ID: 92440811002 Collected: 08/07/19 07:40 Received: 08/09/19 10:20 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 08/20/2019 03:24 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.19
1
08/15/19 05:12
78-87-5
ND
ug/L
1.0
0.30
1
08/15/19 05:12
10061-01-5
ND
ug/L
1.0
0.31
1
08/15/19 05:12
10061-02-6
ND
ug/L
1.0
0.26
1
08/15/19 05:12
100-41-4
ND
ug/L
5.0
0.57
1
08/15/19 05:12
591-78-6
ND
ug/L
20.0
12.5
1
08/15/19 05:12
74-88-4
ND
ug/L
5.0
3.7
1
08/15/19 05:12
75-09-2
ND
ug/L
5.0
4.5
1
08/15/19 05:12
108-10-1
ND
ug/L
1.0
0.27
1
08/15/19 05:12
100-42-5
ND
ug/L
1.0
0.34
1
08/15/19 05:12
630-20-6
ND
ug/L
1.0
0.22
1
08/15/19 05:12
79-34-5
ND
ug/L
1.0
0.16
1
08/15/19 05:12
127-18-4
ND
ug/L
1.0
0.24
1
08/15/19 05:12
108-88-3
ND
ug/L
1.0
0.18
1
08/15/19 05:12
71-55-6
ND
ug/L
1.0
0.24
1
08/15/19 05:12
79-00-5
ND
ug/L
1.0
0.22
1
08/15/19 05:12
79-01-6
ND
ug/L
1.0
0.31
1
08/15/19 05:12
75-69-4
ND
ug/L
1.0
0.35
1
08/15/19 05:12
96-18-4
ND
ug/L
2.0
1.4
1
08/15/19 05:12
108-05-4
ND
ug/L
1.0
0.24
1
08/15/19 05:12
75-01-4
ND
ug/L
1.0
0.63
1
08/15/19 05:12
1330-20-7
104
%
70-130
1
08/15/19 05:12
460-00-4
90
%
70-130
1
08/15/19 05:12
17060-07-0
102
%
70-130
1
08/15/19 05:12
2037-26-5
Analytical Method: EPA 8260D Mod.
22.3
ug/L
2.0
1.2
1
08/14/1915:57
123-91-1
110
%
50-150
1
08/14/1915:57
17060-07-0
104
%
50-150
1
08/14/1915:57
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
M1
Page 9 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
QC Batch: 492603 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92440811001, 92440811002
METHOD BLANK: 2655797
Associated Lab Samples: 92440811001, 92440811002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.0
08/19/19 00:30
Arsenic
ug/L
ND
10.0
4.7
08/19/19 00:30
Barium
ug/L
ND
5.0
1.0
08/19/19 00:30
Beryllium
ug/L
ND
1.0
0.20
08/19/19 00:30
Cadmium
ug/L
ND
1.0
0.40
08/19/19 00:30
Chromium
ug/L
ND
5.0
1.0
08/19/19 00:30
Cobalt
ug/L
ND
5.0
1.1
08/19/19 00:30
Copper
ug/L
ND
5.0
2.1
08/19/19 00:30
Hardness, Total(SM 2340B)
ug/L
ND
662
131
08/19/19 00:30
Lead
ug/L
ND
5.0
1.6
08/19/19 00:30
Nickel
ug/L
ND
5.0
0.90
08/19/19 00:30
Selenium
ug/L
ND
10.0
4.7
08/19/19 00:30
Silver
ug/L
ND
5.0
2.5
08/19/19 00:30
Vanadium
ug/L
ND
5.0
1.3
08/19/19 00:30
Zinc
ug/L
ND
10.0
3.9
08/19/19 00:30
LABORATORY CONTROL SAMPLE:
2655798
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
518
104
80-120
Arsenic
ug/L
500
498
100
80-120
Barium
ug/L
500
512
102
80-120
Beryllium
ug/L
500
514
103
80-120
Cadmium
ug/L
500
506
101
80-120
Chromium
ug/L
500
508
102
80-120
Cobalt
ug/L
500
513
103
80-120
Copper
ug/L
500
514
103
80-120
Hardness, Total(SM 2340B)
ug/L
33100
33700
102
80-120
Lead
ug/L
500
510
102
80-120
Nickel
ug/L
500
508
102
80-120
Selenium
ug/L
500
504
101
80-120
Silver
ug/L
250
255
102
80-120
Vanadium
ug/L
500
515
103
80-120
Zinc
ug/L
500
507
101
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
MATRIX SPIKE & MATRIX SPIKE
Parameter
DUPLICATE: 2655799
MS
92440808001 Spike
Units Result Conc.
MSD
Spike
Conc.
2655800
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
Antimony
ug/L
ND
500
500
510
505
102
101
75-125
1
20
Arsenic
ug/L
ND
500
500
495
489
99
98
75-125
1
20
Barium
ug/L
4.5J
500
500
494
496
98
98
75-125
1
20
Beryllium
ug/L
ND
500
500
495
498
99
100
75-125
1
20
Cadmium
ug/L
ND
500
500
498
496
100
99
75-125
0
20
Chromium
ug/L
ND
500
500
499
498
100
100
75-125
0
20
Cobalt
ug/L
ND
500
500
489
485
98
97
75-125
1
20
Copper
ug/L
2.5J
500
500
502
502
100
100
75-125
0
20
Hardness, Total(SM 2340B)
ug/L
158000
33100
33100
188000
189000
93
96
75-125
1
Lead
ug/L
ND
500
500
489
486
97
97
75-125
1
20
Nickel
ug/L
0.93J
500
500
482
479
96
96
75-125
1
20
Selenium
ug/L
ND
500
500
520
512
104
102
75-125
2
20
Silver
ug/L
ND
250
250
255
254
102
102
75-125
0
20
Vanadium
ug/L
2.2J
500
500
514
510
102
102
75-125
1
20
Zinc
ug/L
ND
500
500
501
500
100
99
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
QC Batch: 492601
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92440811001, 92440811002
METHOD BLANK: 2655785
Matrix: Water
Associated Lab Samples: 92440811001, 92440811002
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Thallium ug/L
ND 0.10 0.060 08/16/1910:56
LABORATORY CONTROL SAMPLE: 2655786
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 10 100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655787 2655788
MS MSD
92440808001
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND
10 10 9.9 10
99 100 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
QC Batch: 492311 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92440811001, 92440811002
METHOD BLANK: 2654361
Associated Lab Samples: 92440811001, 92440811002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/15/19 03:40
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/15/19 03:40
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/15/19 03:40
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/15/19 03:40
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/15/19 03:40
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/15/19 03:40
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/15/19 03:40
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/15/19 03:40
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/15/19 03:40
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/15/19 03:40
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/15/19 03:40
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/15/19 03:40
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/15/19 03:40
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/15/19 03:40
2-Hexanone
ug/L
ND
5.0
0.57
08/15/19 03:40
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/15/19 03:40
Acetone
ug/L
ND
25.0
6.2
08/15/19 03:40
Acrylonitrile
ug/L
ND
10.0
0.90
08/15/19 03:40
Benzene
ug/L
ND
1.0
0.15
08/15/19 03:40
Bromochloromethane
ug/L
ND
1.0
0.34
08/15/19 03:40
Bromodichloromethane
ug/L
ND
1.0
0.26
08/15/19 03:40
Bromoform
ug/L
ND
1.0
0.62
08/15/19 03:40
Bromomethane
ug/L
ND
2.0
0.62
08/15/19 03:40
Carbon disulfide
ug/L
ND
2.0
0.40
08/15/19 03:40
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/15/19 03:40
Chlorobenzene
ug/L
ND
1.0
0.23
08/15/19 03:40
Chloroethane
ug/L
ND
1.0
0.49
08/15/19 03:40
Chloroform
ug/L
ND
5.0
2.3
08/15/19 03:40
Chloromethane
ug/L
ND
1.0
0.39
08/15/19 03:40
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/15/19 03:40
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/15/19 03:40
Dibromochloromethane
ug/L
ND
1.0
0.41
08/15/19 03:40
Dibromomethane
ug/L
ND
1.0
0.46
08/15/19 03:40
Ethylbenzene
ug/L
ND
1.0
0.26
08/15/19 03:40
lodomethane
ug/L
ND
20.0
12.5
08/15/19 03:40
Methylene Chloride
ug/L
ND
5.0
3.7
08/15/19 03:40
Styrene
ug/L
ND
1.0
0.27
08/15/19 03:40
Tetrachloroethene
ug/L
ND
1.0
0.16
08/15/19 03:40
Toluene
ug/L
ND
1.0
0.24
08/15/19 03:40
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/15/19 03:40
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/15/19 03:40
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
METHOD BLANK: 2654361
Matrix:
Water
Associated Lab Samples: 92440811001,
92440811002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/15/19 03:40
Trichloroethene
ug/L
ND
1.0
0.22
08/15/19 03:40
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/15/19 03:40
Vinyl acetate
ug/L
ND
2.0
1.4
08/15/19 03:40
Vinyl chloride
ug/L
ND
1.0
0.24
08/15/19 03:40
Xylene (Total)
ug/L
ND
1.0
0.63
08/15/19 03:40
1,2-Dichloroethane-d4 (S)
%
84
70-130
08/15/19 03:40
4-Bromofluorobenzene (S)
%
117
70-130
08/15/19 03:40
Toluene-d8 (S)
%
110
70-130
08/15/19 03:40
LABORATORY CONTROL SAMPLE:
Parameter
2654362
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
51.5
103
70-130
1,1,1-Trichloroethane
ug/L
50
54.2
108
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
52.1
104
70-130
1,1,2-Trichloroethane
ug/L
50
44.1
88
70-130
1,1-Dichloroethane
ug/L
50
51.2
102
70-130
1,1-Dichloroethene
ug/L
50
53.6
107
70-130
1,2,3-Trichloropropane
ug/L
50
52.7
105
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.6
97
70-130
1,2-Dibromoethane (EDB)
ug/L
50
51.4
103
70-130
1,2-Dichlorobenzene
ug/L
50
42.4
85
70-130
1,2-Dichloroethane
ug/L
50
51.8
104
70-130
1,2-Dichloropropane
ug/L
50
52.5
105
70-130
1,4-Dichlorobenzene
ug/L
50
43.9
88
70-130
2-Butanone (MEK)
ug/L
100
104
104
64-135
2-Hexanone
ug/L
100
93.2
93
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
80.3
80
70-130
Acetone
ug/L
100
96.1
96
61-157
Acrylonitrile
ug/L
250
242
97
61-143
Benzene
ug/L
50
52.4
105
70-130
Bromochloromethane
ug/L
50
51.5
103
70-130
Bromodichloromethane
ug/L
50
53.5
107
70-130lK
Bromoform
ug/L
50
51.6
103
70-130
Bromomethane
ug/L
50
47.3
95
38-130
Carbon disulfide
ug/L
50
53.3
107
68-130
Carbon tetrachloride
ug/L
50
50.2
100
70-130
Chlorobenzene
ug/L
50
46.5
93
70-130
Chloroethane
ug/L
50
55.2
110
37-142
Chloroform
ug/L
50
50.9
102
70-130
Chloromethane
ug/L
50
55.0
110
48-130
cis-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
cis-1,3-Dichloropropene
ug/L
50
47.1
94
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 23

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
LABORATORY CONTROL SAMPLE:
2654362
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
44.7
89
70-130
Dibromomethane
ug/L
50
50.2
100
70-130
Ethylbenzene
ug/L
50
46.6
93
70-130
lodomethane
ug/L
100
94.6
95
40-1301K
Methylene Chloride
ug/L
50
49.4
99
67-132
Styrene
ug/L
50
50.2
100
70-130
Tetrachloroethene
ug/L
50
41.2
82
69-130
Toluene
ug/L
50
44.6
89
70-130
trans-1,2-Dichloroethene
ug/L
50
54.8
110
70-130
trans- 1,3-Dichloropropene
ug/L
50
40.7
81
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
45.1
90
35-189
Trichloroethene
ug/L
50
50.9
102
70-130
Trichlorofluoromethane
ug/L
50
52.9
106
63-130
Vinyl acetate
ug/L
100
104
104
55-143 IK
Vinyl chloride
ug/L
50
59.6
119
70-131
Xylene (Total)
ug/L
150
147
98
70-130
1,2-Dichloroethane-d4 (S)
%
98
70-130
4-Bromofluorobenzene (S)
%
102
70-130
Toluene-d8 (S)
%
94
70-130
MATRIX SPIKE SAMPLE:
2654364
92440811002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
20.4
102
73-134
1,1,1-Trichloroethane
ug/L
ND
20
20.5
103
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
19.7
98
70-136
1,1,2-Trichloroethane
ug/L
ND
20
22.0
110
70-135
1,1-Dichloroethane
ug/L
ND
20
20.0
100
70-139
1,1-Dichloroethene
ug/L
ND
20
22.5
113
70-154
1,2,3-Trichloropropane
ug/L
ND
20
14.0
70
71-137 M1
1,2-Dibromo-3-chloropropane
ug/L
ND
20
18.5
92
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
20.4
102
70-137
1,2-Dichlorobenzene
ug/L
ND
20
18.3
91
70-133
1,2-Dichloroethane
ug/L
ND
20
19.9
99
70-137
1,2-Dichloropropane
ug/L
ND
20
22.2
111
70-140
1,4-Dichlorobenzene
ug/L
ND
20
17.8
89
70-133
2-Butanone (MEK)
ug/L
ND
40
42.5
106
60-139
2-Hexanone
ug/L
ND
40
40.2
100
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
42.2
105
65-135
Acetone
ug/L
ND
40
39.8
99
60-148
Acrylonitrile
ug/L
ND
100
88.1
88
64-147
Benzene
ug/L
ND
20
21.8
109
70-151
Bromochloromethane
ug/L
ND
20
19.4
97
70-141
Bromodichloromethane
ug/L
ND
20
21.4
107
70-138
Bromoform
ug/L
ND
20
18.4
92
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
MATRIX SPIKE SAMPLE:
Parameter
2654364
Units
92440811002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
19.1
95
15-152
Carbon disulfide
ug/L
ND
20
22.1
110
69-149
Carbon tetrachloride
ug/L
ND
20
21.0
105
70-143
Chlorobenzene
ug/L
ND
20
19.8
99
70-138
Chloroethane
ug/L
ND
20
25.6
128
52-163
Chloroform
ug/L
ND
20
19.1
96
70-139
Chloromethane
ug/L
ND
20
22.0
109
41-139
cis-1,2-Dichloroethene
ug/L
ND
20
19.5
97
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
19.9
100
70-137
Dibromochloromethane
ug/L
ND
20
18.6
93
70-134
Dibromomethane
ug/L
ND
20
20.4
102
70-138
Ethylbenzene
ug/L
ND
20
19.8
99
66-153
lodomethane
ug/L
ND
40
30.4
76
20-138
Methylene Chloride
ug/L
ND
20
18.7
93
42-159
Styrene
ug/L
ND
20
19.4
97
70-135
Tetrachloroethene
ug/L
ND
20
19.8
99
59-143
Toluene
ug/L
ND
20
20.2
101
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
21.4
107
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
19.5
98
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
15.0
75
47-135
Trichloroethene
ug/L
ND
20
21.9
109
70-147
Trichlorofluoromethane
ug/L
ND
20
23.4
117
70-148
Vinyl acetate
ug/L
ND
40
37.2
93
49-151
Vinyl chloride
ug/L
ND
20
24.7
123
70-156
Xylene (Total)
ug/L
ND
60
59.8
100
63-158
1,2-Dichloroethane-d4 (S)
%
95
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
103
70-130
SAMPLE DUPLICATE: 2654363
Parameter
Units
92440811001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
SAMPLE DUPLICATE: 2654363
Parameter
Units
92440811001
Result
Dup
Result RPD
Max
RPD
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
ND
ND
30
Chloroethane
ug/L
ND
ND
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
Toluene
ug/L
ND
ND
30
trans-1,2-Dichloroethene
ug/L
ND
ND
30
trans- 1,3-Dichloropropene
ug/L
ND
ND
30
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
30
Trichloroethene
ug/L
ND
ND
30
Trichlorofluoromethane
ug/L
ND
ND
30
Vinyl acetate
ug/L
ND
ND
30
Vinyl chloride
ug/L
ND
ND
30
Xylene (Total)
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
96
98
4-Bromofluorobenzene (S)
%
105
99
Toluene-d8 (S)
%
97
103
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner LF Surface Water
Pace Project No.: 92440811
QC Batch: 492255 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92440811001, 92440811002
METHOD BLANK: 2654104
Matrix:
Water
Associated Lab Samples:
92440811001, 92440811002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 08/14/19 13:56
1,2-Dichloroethane-d4 (S)
%
103
50-150
08/14/19 13:56
Toluene-d8 (S)
%
102
50-150
08/14/19 13:56
LABORATORY CONTROL SAMPLE: 2654105
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130
1,2-Dichloroethane-d4 (S) % 101 50-150
Toluene-d8(S) % 102 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2654106
2654107
MS
MSD
92440808001 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 22.5 22.9
113
115
50-150
2 30
1,2-Dichloroethane-d4 (S)
%
108
109
50-150
30
Toluene-d8 (S)
%
104
103
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 23

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: Butner LF Surface Water
Pace Project No.: 92440811
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/20/2019 03:24 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 23

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Butner LF Surface Water
Pace Project No.: 92440811
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92440811001
3902-SW1
EPA 3010A
492603
EPA 6010D
492651
92440811002
3902-SW2
EPA 3010A
492603
EPA 6010D
492651
92440811001
3902-SW1
EPA 3010A
492601
EPA 6020B
492655
92440811002
3902-SW2
EPA 3010A
492601
EPA 6020B
492655
92440811001
3902-SW1
EPA 8260D
492311
92440811002
3902-SW2
EPA 8260D
492311
92440811001
3902-SW1
EPA 8260D Mod.
492255
92440811002
3902-SW2
EPA 8260D Mod.
492255
Date: 08/20/2019 03:24 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 23

Document Name: Document rtevimw. rein poi y r, —w
,onditian Upon Receipt(SCUR) Page i of 2
Document No.: Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
Laboratorytrecel lngsample:b;
Asheville ❑ Eden[] Greenwood ❑ Huntersvilie ❑ Raleigh[] Mechanicsville[]
Sample Condition Client Name: W0# : 92440811
-Upon Receipt Project
; Courier: [-]Fed EEx ❑UPS ❑LISPS []client
❑ Commercial Peace ❑Other: 92440811
Custody Seat Present? ❑Yes QAio Seals Intact? ❑Yes QNo
Date/Initials Person Examining Contents:
Packing Material: 06.ubble Wrap (bubble Bags ❑None ❑ Other Biological Tissue Frozen?
. Des []No ❑M/A
Thermometer; 92TD48 Type of ice: Qwet ❑Blue ❑None
❑IR Gun ID:
Cooler Temp J°Cl: Correction Factor: Add/Subtract VC) ().fl � ��
l Temp should be above Ereezingto 6°C
CeolerTemp Corrected (°C): ❑iamples outoftemp criter4a. Samples an ice, cooling process
hasbegun
USDA keguiatedSoil (q N/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did. samples originate from a foreign scutce {internationally,
r-I.,_- r-I— includi gHawaii and Puerto Ricol? ❑Yes ❑No
Chain of Cuitbdv Present?
®Yes
❑No
[I N/A
1.
Samples Arrived within Hold Time? , .
)Yes
❑No
❑NIA
2,
Short Hbld,Time Analysis (572 hr.)?
❑Yes
❑No
❑NIA
3.
Rush Turn Around Time Requested?
[]Yes
❑Na
[]NIA
4.
Sufficient Volume?
3 Yes
[!No
❑NIA
S.
Correct Containers Used?
[•Yes
[]No
❑NIA
6.
-Pace Containers Used?
I]Yes
[]No
[]N/A
Containers Intact?
❑Yes
[]No
❑NIA
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
❑N/A
B.
Sample Labels Match CDC?
[, Yes
❑Na
❑NIA
9.
-Includes Date/Time/iD/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
❑Yes
❑No
❑NIA
i 10.
Trip Blank Present?
❑Yes
[]No
❑NIA
11.
Trio Blank Custodv Seals Present?
❑Yes
")No
❑NIA
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: U(/( Date:
Project Manager SRF Review: Date:
Field Data Required? ❑Yes []NO
Page 21 of 23

sample Condition Upon Re
CeAf7c1yUr,a Document No.:
Issuing Authority:
Pace Carolinas Quality Office
*Check mark top half of box It phi ana/or aecnionnamun rb
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, UH'g
**Bottom half of box is to list number of bottle
m
¢
z
m
C
V
ij
a
<
z
v
G
V
N
a
a
z
d
C
V
f0
4L
z
E
C
vYj
Y
v
0
0
y
U
R
i
v
M
S
V
A
a
a
z
°a
U
Q
N
V
A
a
u
ry
n
Z
Z
V
ro
a
E
a
p
[�
a
.aC
O
E
a
z
Z
d
C
v
¢
E
E
.H
C
Oa
E
1nl
N
rH
coin
E
O
WS
N
fL
H
0
E
N
r1
II
J
E
O
N
On
E
rn
a
m
E
�n
N
C
t0
ro
y
?
ID
}
°1
N
rl
Q
1
2
3
4
5
6
7
8
9
to
11
}.2
WO# '
PM: NMG Due Date: 08/23/19
CLIENT: 92-Joyce Eno
pH Adjustment Log for Preserved Samples
Sample 10 Type olPreseruative pH upon receipt Date preservation adJasted Time preservat€9n Amount adPreservative Lot q
adJustad
Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will iesentta the North Carolina DEHNR Certification Office (i.e.
out of hold, incorrect preservative, out of temp, incorrect containers.
Page 22 of 23

9
0
CHAIN -OF -CUSTODY 1 Analytical Request Document N
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
co
-
Section A
Section B Section C
Required Cli
nt Information: Required Project Information: Invoice Information: P2CIC : 1 Of 1
La Bella Associates Report To: Van Burbach Attention: Jason Falls
2211 West Meadowview Rd Copy To: Miguel Vazquez Company Name Granville County. Solid Waste
Company
Address:
Greensboro,
NC 27407
Address: P.O. Box 906, Oxford NC 27565
Reoulatory Agent
Email Ti
vburbach jo Ceen ineerin .com
Purchase Order No.
Phone:
336 323-0092 Fax
Client ProiID: Butner Landfill Surface Water
State I Location
Requested Due
DalefTAT: 10 Da Default
Container Order Number:
3566-3
North Carolina
Requested
Anal
sis
Filtered
(YIN)
kwrRlx cooE
e
a
o
COLLECTED
=
Preservatives
Z
r
❑inking Vd.- DW
(J
O
Wnli,r WT
W-ji, War', V✓W
_=
Q
W
P,uduct P
SAMPLE ID ail 50°�
d_
START
ENO
°
u,
S
}
o�
a,
One Character per box. W.P. wa
w
w
a
z
a
y
In
A,, AIR
O
0.
i
;Z
N
••-•
_-.
X
0
rn
Sample Ids must be unique a,v, Ts
x
o
`O
2
O
N
c
r
CC
+
0.
C
a
h
—
C
4
DATE
TIME
DATE
TIME
C
m
C
N In
=
Z
x
C)
x
0
C
z
N
z
m
a
0
//Q♦♦
z
IQ1
z
1
39
2-SWI
wT
G
I
ym
05-5
7
x
X
X
X
X
Ix
I'
2
39
2-SW2
vvT
G
F 7
D7gc)
7
iC
X
X
X
X
3
4
5
6
7
8
9
10
11
12
ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIATION
DATE
TIME
ACC D BY I FFILIATION
DATE
TIME
SAMPLE CONDITIONS
S.51eba�
llQr�
4��
c o, z
r ---
a
1
ItO
SAMPLER NAME AND SIGNATURE
R
o
w Z
PRINT Name of SAMPLER:
'I
}
o
UU
E
SIGNATURE of SAMPLER: I DATE Signed:
8 1612
tY
'iY

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 21, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill MNA
Pace Project No.: 92440311
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 07, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
�pQ ACrfFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9e0 without the written consent of Pace Analytical Services, LLC.
Page 1 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Landfill MNA
Pace Project No.: 92440311
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 33

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Landfill MNA
Pace Project No.: 92440311
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92440311001
92440311002
3902-MW2R
3902-MW3R
Water
Water
08/06/1912:22
08/06/1914:32
08/07/1910:20
08/07/1910:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill MNA
92440311
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92440311001
3902-MW2R
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
92440311002
3902-MW3R
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
BRJ
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Butner Landfill MNA
Pace Project No.: 92440311
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92440311001
3902-MW2R
RSK 175 Modified
Ethane
2.OJ
ug/L
10.0
08/08/19 13:17
RSK 175 Modified
Methane
4980
ug/L
10.0
08/08/19 13:17
SM 2320B-2011
Alkalinity, Total as CaCO3
839000
ug/L
5000
08/15/19 17:48
SM 5210B-2011
BOD, 5 day
7960
ug/L
2000
08/12/19 11:46
EPA 300.0 Rev 2.1 1993
Chloride
203000
ug/L
4000
08/08/19 22:26
SM 5220D-2011
Chemical Oxygen Demand
123000
ug/L
25000
08/09/19 22:29
SM 5310B-2011
Total Organic Carbon
33300
ug/L
5000
08/20/19 20:13
92440311002
3902-MW3R
RSK 175 Modified
Ethane
4.1J
ug/L
10.0
08/08/19 13:02
RSK 175 Modified
Ethene
1.6J
ug/L
10.0
08/08/19 13:02
RSK 175 Modified
Methane
486
ug/L
10.0
08/08/19 13:02 M1
SM 2320B-2011
Alkalinity, Total as CaCO3
754000
ug/L
5000
08/15/19 17:58
EPA 300.0 Rev 2.1 1993
Chloride
154000
ug/L
3000
08/08/19 22:41
EPA 300.0 Rev 2.1 1993
Sulfate
711 J
ug/L
1000
08/08/19 20:24
SM 5220D-2011
Chemical Oxygen Demand
45500
ug/L
25000
08/09/19 22:29
SM 5310B-2011
Total Organic Carbon
15100
ug/L
1000
08/20/19 20:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92440311
Sample: 3902-MW2R
Lab ID: 92440311001 Collected:
08/06/19 12:22
Received: 08/07/19 10:20 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Ethane
2.OJ ug/L 10.0
1.2
1
08/08/1913:17
74-84-0
Ethene
ND ug/L 10.0
1.2
1
08/08/1913:17
74-85-1
Methane
4980 ug/L 10.0
3.4
1
08/08/1913:17
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
839000 ug/L 5000
5000
1
08/15/19 17:48
450OS2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Sulfide
ND ug/L 100
50.0
1
08/07/1918:19
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
7960 ug/L 2000
2000
1
08/07/19 17:11 08/12/19 11:46
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Chloride
203000 ug/L 4000
2400
4
08/08/19 22:26
16887-00-6
Sulfate
ND ug/L 1000
500
1
08/08/19 20:10
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
08/07/19 15:51
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
123000 ug/L 25000
12500
1
08/09/19 16:22 08/09/19 22:29
531013 TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
33300 ug/L 5000
2500
5
08/20/19 20:13
7440-44-0
Date: 08/21 /2019 10:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92440311
Sample: 3902-MW3R
Lab ID: 92440311002 Collected:
08/06/19 14:32
Received: 08/07/19 10:20 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Ethane
4.1J ug/L 10.0
1.2
1
08/08/1913:02
74-84-0
Ethene
1.6J ug/L 10.0
1.2
1
08/08/1913:02
74-85-1
Methane
486 ug/L 10.0
3.4
1
08/08/1913:02
74-82-8 M1
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
754000 ug/L 5000
5000
1
08/15/19 17:58
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Sulfide
ND ug/L 100
50.0
1
08/07/1918:19
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
ND ug/L 2000
2000
1
08/07/19 17:11 08/12/19 12:03
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Chloride
154000 ug/L 3000
1800
3
08/08/19 22:41
16887-00-6
Sulfate
711J ug/L 1000
500
1
08/08/19 20:24
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Nitrogen, Nitrate
ND ug/L 40.0
10.0
1
08/07/19 15:55
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
45500 ug/L 25000
12500
1
08/09/19 16:22 08/09/19 22:29
531013 TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
15100 ug/L 1000
500
1
08/20/19 20:24
7440-44-0
Date: 08/21 /2019 10:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 491131 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2649071
Matrix:
Water
Associated Lab Samples: 92440311001, 92440311002
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Ethane
ug/L
ND
10.0
1.2 08/08/1912:47
Ethene
ug/L
ND
10.0
1.2 08/08/1912:47
Methane
ug/L
ND
10.0
3.4 08/08/1912:47
LABORATORY CONTROL SAMPLE:
2649072
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Ethane
ug/L
658
678
103
70-130
Ethene
ug/L
1120
1110
99
70-130
Methane
ug/L
396
393
99
70-130
MATRIX SPIKE SAMPLE:
2649793
92440311002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Ethane
ug/L
4.1J
658
636
96
70-130
Ethene
ug/L
1.6J
1120
1110
98
70-130
Methane
ug/L
486
396
755
68
70-130 M1
SAMPLE DUPLICATE: 2649794
92440311001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
2.OJ
2.1J
20
Ethene
ug/L
ND
1.6J
20
Methane
ug/L
4980
5020
1
20
SAMPLE DUPLICATE: 2649795
92440463008
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
ND
ND
20
Ethene
ug/L
ND
3.9J
20
Methane
ug/L
8510
8070
5
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 492453
Analysis Method:
SM 2320B-2011
QC Batch Method: SM 2320B-2011
Analysis Description:
2320E Alkalinity
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2655136
Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed Qualifiers
Alkalinity, Total as CaCO3 ug/L
ND 5000 5000 08/15/19 15:29
LABORATORY CONTROL SAMPLE: 2655137
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L
50000 53500
107 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655138 2655139
MS MSD
92439773009
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 329000
50000 50000 368000
373000 80 89 80-120 1 25
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655140 2655141
MS MSD
92439980037 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L ND 50000 50000 52400 53900 105 108 80-120 3 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 9 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 490934
Analysis Method:
SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011
Analysis Description:
4500S2D Sulfide
Water
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2648000
Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Sulfide ug/L
ND 100
50.0 08/07/1918:09
LABORATORY CONTROL SAMPLE: 2648001
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Sulfide ug/L
500 512
102
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2648002 2648003
MS MSD
92439719002
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND
500 500 511
518
102 104 80-120 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2648004 2648005
MS MSD
92440174001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 476 471 95 94 80-120 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 10 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 490882
Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011
Analysis Description: 5210E BOD, 5 day
Associated Lab Samples: 92440311001,
92440311002
METHOD BLANK: 2647682
Matrix: Water
Associated Lab Samples: 92440311001,
92440311002
Blank Reporting
Parameter
Units
Result Limit MDL Analyzed Qualifiers
BOD, 5 day
ug/L
ND 2000 2000 08/12/19 11:49
LABORATORY CONTROL SAMPLE: 2647683
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000 193000 97 84.6-115
SAMPLE DUPLICATE: 2647684
92440231001 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
BOD, 5 day
ug/L
301 mg/L 305000 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 491009 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2648321 Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 600 08/08/1912:55
Sulfate ug/L ND 1000 500 08/08/1912:55
LABORATORY CONTROL SAMPLE: 2648322
Spike
LCS LCS
% Rec
Parameter Units
Conc.
Result % Rec
Limits Qualifiers
Chloride ug/L
50000
51500 103
90-110
Sulfate ug/L
50000
51200 102
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2648323
2648324
MS
MSD
92440153001
Spike
Spike
MS
MSD MS
MSD % Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec Limits
RPD RPD Qual
Chloride ug/L
60.3 mg/L
50000
50000
99900
100000 79
80 90-110
1 10 M1
Sulfate ug/L
58.4 mg/L
50000
50000
96800
97300 77
78 90-110
1 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2648325
2648326
MS
MSD
92440389009
Spike
Spike
MS
MSD MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec
Limits
RPD RPD Qual
Chloride ug/L
3.5 mg/L
50000
50000
56100
56200 105
105
90-110
0 10
Sulfate ug/L
0.71J
50000
50000
53200
52400 105
103
90-110
2 10
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 12 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 490883
Analysis Method:
EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description:
353.2 Nitrate
+ Nitrite, Unpres.
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2647686
Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Nitrogen, Nitrate ug/L
ND 40.0
10.0 08/07/19 15:38
LABORATORY CONTROL SAMPLE: 2647687
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Nitrogen, Nitrate ug/L
1500 1470
98
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2647688 2647689
MS MSD
92440284001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 0.049
1500 1500 1550
1550
100 100 90-110 0 10
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 13 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 491482
Analysis Method:
SM 5220D-2011
QC Batch Method: SM 5220D-2011
Analysis Description:
5220D COD
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2650721
Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed Qualifiers
Chemical Oxygen Demand ug/L
ND 25000 12500 08/09/19 22:25
LABORATORY CONTROL SAMPLE: 2650722
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chemical Oxygen Demand ug/L
750000 756000
101 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2650723 2650724
MS MSD
92440448001
Spike Spike MS
MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 36.1 mg/L
100000 100000 142000
135000 106 99 90-110 5 3 R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2650725 2650726
MS MSD
92440091001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 770 mg/L 100000 100000 848000 850000 78 80 90-110 0 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 14 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92440311
QC Batch: 493214
Analysis Method:
SM 531 OB-2011
QC Batch Method: SM 531 OB-2011
Analysis Description:
5310E TOC
Associated Lab Samples: 92440311001, 92440311002
METHOD BLANK: 2658503
Matrix: Water
Associated Lab Samples: 92440311001, 92440311002
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Total Organic Carbon ug/L
ND 1000
500 08/20/19 18:57
LABORATORY CONTROL SAMPLE: 2658504
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Total Organic Carbon ug/L
25000 24900
99
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2658507 2658508
MS MSD
92441448001
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L ND
25000 25000 25300
25200
99 98 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2658516 2658517
MS MSD
92440914005 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 7.6 mg/L 25000 25000 30300 30400 91 91 90-110 0 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC.
Page 15 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill MNA
Pace Project No.: 92440311
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/21 /2019 10:23 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill MNA
92440311
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92440311001
3902-MW2R
RSK 175 Modified
491131
92440311002
3902-MW3R
RSK 175 Modified
491131
92440311001
3902-MW2R
SM 2320B-2011
492453
92440311002
3902-MW3R
SM 2320B-2011
492453
92440311001
3902-MW2R
SM 4500-S2D-2011
490934
92440311002
3902-MW3R
SM 4500-S2D-2011
490934
92440311001
3902-MW2R
SM 5210B-2011
490882
SM 5210B-2011
490973
92440311002
3902-MW3R
SM 5210B-2011
490882
SM 5210B-2011
490973
92440311001
3902-MW2R
EPA 300.0 Rev 2.1 1993
491009
92440311002
3902-MW3R
EPA 300.0 Rev 2.1 1993
491009
92440311001
3902-MW2R
EPA 353.2 Rev 2.0 1993
490883
92440311002
3902-MW3R
EPA 353.2 Rev 2.0 1993
490883
92440311001
3902-MW2R
SM 5220D-2011
491482
SM 5220D-2011
491550
92440311002
3902-MW3R
SM 5220D-2011
491482
SM 5220D-2011
491550
92440311001
3902-MW2R
SM 5310B-2011
493214
92440311002
3902-MW3R
SM 5310B-2011
493214
Date: 08/21 /2019 10:23 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 17 of 33

/p�
I c�C��inalytical
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
Quality Office
Laboratory receiving s4ples:
Asheville Eden❑ Greenwood ❑ Huntersville ❑ Raleigh[]Mechanicsville❑
ConditionSample Client Name: WO# : 92440311
Upon Receipt 1 r t� Project #:
Courier: Fed Ex ❑UPS ❑USPS ❑Client
❑ Commercial ❑Pace ❑other. 92440311
Custody Seal Present? []Yes [:]No Seals Intact? ❑Yes [:]No �Vioc
pate/Initials Person Examining Contents:
Packing Material: []Bubble Wrap (Bubble Bags ❑None ❑ other Biological Tissue Wze
n?
[]Yes []No N/A
Thermometer/ Type of Ice: Wet ❑Blue ❑Non=
lR Gun ID: �7 -(�
Cooler Temp (°C): Z a L Correction Factor, Add/Subtract (°C)
Z,� Temp should be alcove freezing to 6°C
Cooler Temp Corrected (°C): []samples out of temp criteria. Samples on ice, cooling process
hasaegun
USDA Regulated Soil ([�KN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did sarnplesorigiriate from a foreign source (internationally,
I—lYes l—lNo including Hawaii and Puerto Rico)? ❑Yes ❑No
Chain of Custody Present?
Samples Arrived within Hold Tme?
Short Hold Time Analysis (<72 hr.)?
Rush Turn Around Time Requested?
Sufficient Volume?
Correct Contai ners Used?
-Pace Containers Used?
Containers Intact?
Dissolved analysis: Samples Field Filtered?
Sample Labels Match COC?
-Includes Date/Time/4D/Analysis Matrix: A
Headspace in VOA Vials (>5-6mm)?
Trip Blank Present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
]No
❑N/A
1.
]No
[]N/A
2.
❑No
[]N/A
3.
No
❑NIA
4.
❑No
❑N/A
5.
[]NO
❑N/A
6.
[]No
[]N/A
[]No
❑N/A
7.
❑No
N/A
$.
❑No
❑N/A
9.
❑Yes �No (—]N/A i-11.
0.
❑Yes ❑No ❑N/A
D
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
Field Data Required? ❑Yes
Project Manager SCURF Review: Date:
/gO
Project Manager SRF Review: C1/ Date:
Page 18 of 33

Document Name:
Sample Condition Upon Rec
/_- aceAna ical Document No.:
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (%eater) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # W®# : 92440311
PM: NMG Due Date: 08/21/19
CLIENT: 92-Joyce Eno
z
z
z
u
v
fl
4
v
v
�?
z
n
_
0
m
m
a3
R
N
❑,
S1
d
N
Q
v
O
N
v
C?
Z
2
N
u
z
h
0.
N
T7
'O
C.
_
V
❑.
U
N
`
d
N
V
CL
C
O
V
r
Ln
=
Z
"U
.Ff
Q
_
Q
z
?
a
Z
M
a
SN/7
Q
Z
Q,
w
Q
Z
W1
O
Ill
"
Y
7
I
Q
1
¢ N
i
2 C
a Z
Z
C
is
G
O.
V
a
u
M
V
d
2
U
a
U
°
N
U
a
Z
U
a
al
E
v
a
2
m
a
41
..t7
E
a
2
N
a
i
�l
a
E
1'
J
F
o
V
Y
¢
O
N
N
¢
4
C
O
y
m
_
>Q
i,
=
Y
a
N
01 \A y
N "g
Y
J J
_
'�
u
d
E
>r
E
'N-I
V
E
LA
N
M
E
0to
0
N
.--I
=-1
.
'N-I
a
E
O
N
M
E
r
rN-I
Vt
.N-I
V
u'
m
rl
7
rl
L7
ai
,`--
'-1
rl
l9
E
O
N
O
M
l7
`m
-
'1
V]
N
C7
E
N
A
M
i7
m
l7
d
M
[7
E
O
7
C3
U'
E
'�U
M
l7
E
W
K
0
<'1
E
O
�
en
U'
S
::
a
O
°
.?-
-M.+
::1
E
v7
rN-[
N
n.
E
of Q
P y 0 O
N N
[V M
a a C7
E
O
vl
E
O
U
6
tom
b
d
m
a
m
a
m
a
m
4
m
0.
m
¢
a
4
a
a
a
o
>
>
d
>
>
vA
Ln m a
>
o
1
2
�ti
3�
2
3
4
5
6
j
}
7
8
9
IQ
11
lz
PH Adjustment Log for Preserved Sarnples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot N
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form vd[l. be sent to the North Carolina DEHNR Certification office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 19 of 33

Section 1�
RequiredilClieat lnforrnation:
Section B
Required Project Infofmation:
Report To. Van Burbach
Copy To: Miguel Vazcluez
t JPUrChasepnderNo,
Client Aroj ID: 11 lner Landfil,
Container Ord9r Number:
K �
m 0.
o
M
cm
CHAIN -OF -CUSTODY ! Analytical Request Document N
-Fhe Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. N
m
Section C
d
tnvojge IllforTnation• Pae
Jason Falls
Attention; Qf 1
Company Name: Granville Couni , Solid Waste
Address; P.Q. Box 906, Oxford NC 27566
WTRLK OBOE
0rl.WrQWw. ttw
wmr Wl
—
a
O
U
r+VL1.ti:
11=t7
x
o
Preservatives
'
wau�w.t.r wW
a�
"w'uc` P
SAMPLE ID So: rw s�
'
`"
o
Q
oil CL
One ChWaCler per bam W'p WP
_
m
.-
START
END
U 0:.a..
4
w
jA,7, D.91, -j rw Alt
fl
4 z
m..
m
t
Sample US must be ique Otnr or
un
cbi
TDATERMEQATflTIMF
W
- �+,_
df a.
LL
W
lu
.—
e+
m
z
X
z?
O
h
j
75
-,
r
t/j
U Q
0
0
U
5
`ADDI7{OT111LCOli'1MENl'S ��->�'i;�''- ;;
1{T Ydi
�o O SS
COZ, F- - PH. T-M. ORP, Cond. Turb
TNT Name of SAMPLER:
WATURE of SAMPLER:
ES
r
0
U
t r r�MA&I ®TWA®

lacmnalyficalo
August 20, 2019
Nicole Gasiorowski
Pace Analytical Services, Inc.
9800 Kincey Avenue
Suite 100
Huntersville, NC 28078
RE: BUTNER LF / 92440311
Pace Workorder. 31139
Dear Nicole Gasiorowski:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Friday, August 09, 2019.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 08/20/2019
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 31139 - 1194831
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 13
Page 1 of 11
Page 21 of 33

Pace Analytical Energy Services LLC
220 William Pitt Way
.,-- A__1.X__1 o Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 31139 - 1194831
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 11
Page 22 of 33

lacmnalyficalo
SAMPLE SUMMARY
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Workorder: 31139 BUTNER LF / 92440311
Lab ID Sample ID Matrix Date Collected Date Received
311390001 3902-MW2R Water 8/6/201912:22 8/9/201911:30
311390002 3902-MW3R Water 8/6/201914:32 8/9/201911:30
Report ID: 31139 - 1194831 Page 3 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 23 of 33

lacmnalyficalo
PROJECT SUMMARY
Workorder: 31139 BUTNER LF / 92440311
Batch Comments
Batch: EDON/4159 -Low Level Volatile Fatty Acids
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
The percent recovery for the laboratory control sample was above laboratory control limits. Analytes Formic acid. Results
associated to the analytes in samples may be bias high.
Report ID: 31139 - 1194831
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Phone: [phone]
Fax: [phone]
Page 4 of 11
Page 24 of 33

lacmnalyficalo
Workorder: 31139 BUTNER LF / 92440311
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 311390001
Sample ID: 3902-MW2R
Date Received: 8/9/2019 11:30
Date Collected: 8/6/2019 12:22
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.043U mg/I
0.20
0.043 1
8/13/2019 10:46
KB
Acetic Acid
0.097J mg/I
0.10
0.028 1
8/13/2019 10:46
KB
B
Propionic Acid
0.0058J mg/I
0.10
0.0040 1
8/13/2019 10:46
KB
Formic Acid
1.1 mg/I
0.50
0.086 1
8/13/2019 10:46
KB
M2,B
Butyric Acid
0.22 mg/I
0.10
0.011 1
8/13/2019 10:46
KB
B
i-Pentanoic Acid
0.0060U mg/I
0.10
0.0060 1
8/13/2019 10:46
KB
Pentanoic Acid
0.0070U mg/I
0.10
0.0070 1
8/13/2019 10:46
KB
Report ID: 31139 - 1194831 Page 5 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 25 of 33

lacmnalyficalo
Workorder: 31139 BUTNER LF / 92440311
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 311390002
Sample ID: 3902-MW3R
Date Received: 8/9/2019 11:30
Date Collected: 8/6/2019 14:32
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.087J mg/I
0.20
0.043 1
8/13/2019 11:39
KB
Acetic Acid
0.34 mg/I
0.10
0.028 1
8/13/2019 11:39
KB
B
Propionic Acid
0.0045J mg/I
0.10
0.0040 1
8/13/2019 11:39
KB
Formic Acid
1.6 mg/I
0.50
0.086 1
8/13/2019 11:39
KB
M2,B
Butyric Acid
0.011U mg/I
0.10
0.011 1
8/13/2019 11:39
KB
B
i-Pentanoic Acid
0.0060U mg/I
0.10
0.0060 1
8/13/2019 11:39
KB
Pentanoic Acid
0.0070U mg/I
0.10
0.0070 1
8/13/2019 11:39
KB
Report ID: 31139 - 1194831 Page 6 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 26 of 33

lacmnalyficalo
ANALYTICAL RESULTS QUALIFIERS
Workorder: 31139 BUTNER LF / 92440311
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
B The analyte was detected in the associated blank.
M2 The laboratory control sample recovery was outside laboratory control limits.
Report ID: 31139 - 1194831
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 7 of 11
Page 27 of 33

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 31139 BUTNER LF / 92440311
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: EDON/4159
Analysis Method:
AM23G
QC Batch Method: AM23G
Associated Lab Samples: 311390001, 311390002
METHOD BLANK: 62644
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
EDonors
Lactic Acid mg/I
0.043U
0.043
Acetic Acid mg/I
0.044J
0.028 B
Propionic Acid mg/I
0.0040U
0.0040
Formic Acid mg/I
0.49J
0.086 M2,13
Butyric Acid mg/I
0.012J
0.011 B
i-Pentanoic Acid mg/I
0.0060U
0.0060
Pentanoic Acid mg/I
0.0070U
0.0070
LABORATORY CONTROL SAMPLE: 62645
Spike
LCS
LCS
% Rec
Parameter Units
Cone.
Result
% Rec
Limits
Qualifiers
Lactic Acid mg/I
2
2.0
99
70-130
Acetic Acid mg/I
2
2.1
107
70-130
B
Propionic Acid mg/I
2
2.1
104
70-130
Formic Acid mg/I
2
2.8
141
70-130
M2,13
Butyric Acid mg/I
2
2.1
103
70-130
B
i-Pentanoic Acid mg/I
2
2.0
102
70-130
Pentanoic Acid mg/I
2
1.9
96
70-130
MATRIX SPIKE & MATRIX SPIKE DUPLICATE:
62646
62647
Original:
311140001
Original
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Cone.
Result
Result
% Rec
% Rec
Limit
RPD
RPD
Qualifiers
EDonors
Lactic Acid
mg/I
0.21
20
19
19
94
93
70-130
1.3
30
d
Acetic Acid
mg/I
0.31
20
23
21
113
104
70-130
8.5
30
d,B
Propionic Acid
mg/I
0.028
20
21
21
104
105
70-130
0.31
30
d
Formic Acid
mg/I
4.2
20
26
23
108
93
70-130
13
30
d,M2,B
Butyric Acid
mg/I
0.035
20
21
21
106
106
70-130
0.15
30
d,B
i-Pentanoic Acid
mg/I
0
20
22
22
109
108
70-130
0.82
30
d
Pentanoic Acid
mg/I
0
20
21
21
104
106
70-130
1.3
30
d
Report ID: 31139 - 1194831 Page 8 of 11
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 28 of 33

lacmnalyficalo
Workorder: 31139 BUTNER LF / 92440311
Report ID: 31139 - 1194831
4r-tiela(f
QUALITY CONTROL DATA
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 9 of 11
Page 29 of 33

lacmnalyficalo
QUALITY CONTROL DATA QUALIFIERS
Workorder: 31139 BUTNER LF / 92440311
QUALITY CONTROL PARAMETER QUALIFIERS
The analyte was detected in the associated blank.
M2 The laboratory control sample recovery was outside laboratory control limits.
The analyte concentration was determined from a dilution.
Report ID: 31139 - 1194831
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 10 of 11
Page 30 of 33

lacmnalyficalo
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 31139 BUTNER LF / 92440311
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Analysis
Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch
311390001 3902-MW2R
311390002 3902-MW3R
Report ID: 31139 - 1194831
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
AM23G
AM23G
EDON/4159
EDON/4159
Page 11 of 11
Page 31 of 33

M
M
Chain
of Custody
N
M
PASI Charlotte
Laboratory
aceAna! JCaI
-7....
riww.pace►�soum
Workor
er: 92440311 Workorder
Name:
Butner Landfill MNA
Results Requested By:
8/21/2019
Nicole G
-� -
slorowski-
—
Pace An
lyfical Charlotte
Pace Energy P.O.
Z�
9800 Kin
y Ave. Suite 100
Huntersvi
le, NC 28078
220 William Pitt Way
`Phone 0
4)875-9092
Pittsburgh,
PA 15238
Email: ni
[e-mail]
412-826-2389
a"
LL
= State of
ample Origin• NC
1
LAB USE ONLY
39
-MW2R
816/201912:22
924403--- Water
x
2 39
-MW3R 1
18/61201914:32
192440311002
Water
?j
X
Released By
-�"�—
�.
aLR
NMI
Thursday, August 08, 2019 12:51:11 PA
Received By DaterHme
°1 �v
2.
eel:"o--hr,
. :r .:. N ..
Sari les intact '. Y or.: N
FMT-ALL-C-002rev.00 24March2009 Page 1 of 1

Cooler ReLeipt Form
Client Name. �. �.. Pro;ect: b�-Iclf 1 er �'
Lab Work Ord ✓ �� `I
A. Shipping/Container Information (circle appropriate response)
Courier: Fed Ex UPS LISPS Client Other: .Air bill Present: es No
Tracking number:
Custody Seal on Cooler/Box Present: -Yes No Seals Intact: &e'sI No
Cooler/Boy: Packing Material: ubble Wrap'Absorbent Foam Other:
Type of Ice: (Wet Blue None Ice Intact: Yes elted
Cooler Temperature: v, Radiation Screened: Yes 0 Chain of Custody Present: Yes No
,.
Comments:
B. Laboratory Assignment/Log-in (check appropriate response)
I
YES
NO
N/A
Comment
Reference non -Conformance
Chain of Custody properly filled out
Chain of Custody relinquished
Sampler Name & Signature on COC
Containers intact
Were samples in separate bags
I
Sample container labels match COC
j Sample name/date and time collected
Sufficient volume provided
PAES containers used
Are containers properly preserved for the requested testing?
(as labeled)
If an unknown preservation state, were containers checked?
Exception: VOA's coiiform
✓
if yes, see pH form.
Was volume for dissolved testing field filtered, as noted on
the COC? Was volume received in a preserved container?
Headspace present?
U/
Corn
Cooler contents examined/received by : 5 Date: l
Project Manager Review Date:
OAE-Q-009-rev.01, 30ct2017
Page 33 of 33

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 22, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner LF Dissolved Hydrogen
Pace Project No.: 92440779
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 09, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
�pQ ACrfFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9e0 without the written consent of Pace Analytical Services, LLC.
Page 1 of 15

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner LF Dissolved Hydrogen
Pace Project No.: 92440779
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92440779001
92440779002
3902-MW2R
3902-MW3R
Air
Air
08/06/1913:32
08/07/19 09:05
08/09/1910:20
08/09/19 10:20
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 15

sample Condition Upon Recetpt(SCUR) ra�
,:dC8AI*ftCdl' Qatument No.: lssumffAuthority:
F.CAR-05.033-Rev.06 Pate Carolinas [ivality
Laboratory receiving samples: ] M an��lpn
Asheville . Eden Greenwood[ un ersville[� Ramath�-•
Client WO# 92440779
-Upon Receipt S Project
Courier: ❑F Ex 6UPS ❑USPS ❑Client
❑ Commercial Pace ❑Other: 92440779
Custody Sea! Present? Dyes- QNo l Seats Intact? []Yes �(N o l
oatellnitialsPersonEasamining Cantents:�
Packing Material: []Bubble Wrap ❑Bubble Bags []Nonetither Biotagiia#Tissue Fr en?
[],(es []No N/A
Theroitamete Type of Ice: ❑Wet ❑Blue None
,
[R Gu n 10; 92T��a
Cooler Terri (°C): J mCorrectlon Factor: Add/Subtract (°C) 0.0
Temps uld be above fteezing to 6°C
Cooler Temp Corrected ('C):. i — samples aut of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated it (❑ NIA, water sample)
Did samples on ate in a quarantine zone within the United States: CA, NY, pr SC (check maps)? Did sanples originate €ram a foreign soutce (ia _es ovally,
�.. indudinaHawaii and Puerto Rico)? ❑Yes L-d1�o
Chain of Custody Present?
j7�Yes
❑No
❑NIA
1.
Samples Ariived within bold Time? ..
❑Yes
)�N
❑NIA
2•
Short Hold rime Analysts (02 hr.)?
❑Yes
Na
❑NIA
3.
Rush Tum Around Ttdre Requested?
❑Ye
o
❑N/A
4.
SufficientVolurne?
[:]NO[:]NIAS•
Carrect.ContalnersUSed?
ryy.
[]No❑N/A
6.
Pace Containers Used?
[]no❑NIA
Containers Intact?
Yes
❑No
❑N A
7,
Dissolved analysis: Samples Field Filtered? ❑Y
[]No
NIA
B.
Sample Labels Klatch COC?
Yes
❑No
❑NIA
I
-lhcludes Oate/Time/ID/Anatysis
Matrix:
Headspace in VOA Vials (�54rnm)?
❑
ONO
iYes NIA
10.
Trip Blank Present?
[]Yes
ND
[]NIA
Trip Blank Custody Seals Present?
❑Yes
❑N°
��i/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes [:]No
r 1 ) ,' �C
Lot ID ofiloitcontairters.
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Date;
Project Manager SRF Review:
`~~ � Date:
Page-3-�

f �ii Ce/lnaiyuca1 Document No.: I issu ng Auinor ty,
— nL Pace Carolinas Quality Office
*cheek mark tan half of box If pH and/or dechlorination is
verified and within the acceptance range for preservation
Samples.
EMceptions: VOA, Coliform, TOC, Oil and Grease, oRO/6015 (water) HOC, LLHg
"Bottom half of box is to list number of bottle
I,
'p
?
'{3
?
'O
N
N
Z
�)
V
r1
n
a
=1
M
C
S
N
Z
a
s
4+
y
a
4
u
E
a
m
E
N
a
m
E
u5
a
m
�
a
0
E
N
a
m
E
i
m
E
a
E
N
a
J
7
F
4
I-N-
6
�-
[11
12
Project
440779
PM: NMG Due Date: 08/23/
CLIENT: 92-Joyce E09
PH Adjustment Log for Preserved Samples
Sample IO Type of preservative pH upon receipt pate preservation adjusted Time preserratlan Amount of added preservative
adjurted
Note: Whenever then: is a discrepancy affecting North Carolina compliance samples, a copy of this form will hesent ty the North Carolina DEHNft
Out of bold, incorrect preservative, out of temp, incorrect containers.
Lot
Office (i.e.
__Eat 4 of 1

r
Section A
Required CLr nt Infonnaticn:
Company. LaBeda Associates
Address: 2211 West Meadowvii
Greensbor , NC 27407
E mad To: vburbach(aYoyceengir
?hone: 336 323-0092 IFax
Requested D e palelTAT: 10 Dav f D
LU
W
1
2
3
4
5
6
7
8
9
10
11
12
SAMPLE ID
One Character per box-
(A-Z, 9-9 1. -)
Sample Ids must he unique
0
LO
CHAIN -OF -CUSTODY 1 Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. d
Section a Section C
Required Project Information; Invoice information: Of 1
Report To: Van Burbach Aaention: Jason Falls
Rd Copy To: Miguel Vazquez Company Name: Granville County, Solid Waste
Address: P.O, Box 906. Oxford NC 27565
Purchase Order No.
Client Project 10: Butner Landfill Dissolved Ff
Container Order Number:
3566-2
a
Z
r TRIX copF. O COLLECTED
Preservatives
p �k Wm,, Dw o
WT U —
Wasrr W.ft, WW
usaiia
oa oL START Et~so
m
Wipe WP V Q
w
w
�
}
2
AR
O =
¢
m
Omer OT
Tis TS U w ~
Z
N
p
W
,
Q7
%
it a
�U
m
0
rt
=
m
O
w DATE TIME DATE TIME u¢i
o
C
D
N
x
x
x
�
z
ry
z
z
v
2
o
a
n
r>s
p
wT G l
TrXX
wT G 5/�/I� �`�?�
!
i�
ADDITIONAL COMMENTS RELINQUISHED BY I AFFILIATION DATE TIME
IPLER NAME AND SIGNATURE
PRINT Name o(SAMPLER: j
SIGNATURE of SAMPLER: (",
CI
AFFILIATION
DATE
State 1 Location
North Carolina
TIME SAMPLE CONDITIONS
p
� � R
ell u -o
r M = 0 U n

lacmnalyficalo
August 22, 2019
Nicole Gasiorowski
Pace Analytical Services, Inc.
9800 Kincey Avenue
Suite 100
Huntersville, NC 28078
RE: BUTNER LF / 92440779
Pace Workorder. 31157
Dear Nicole Gasiorowski:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Tuesday, August 13, 2019.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 08/22/2019
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 31157 - 1195321
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 10
Page 1 of 9
Page 6 of 15

Pace Analytical Energy Services LLC
220 William Pitt Way
A „ 1, X__ f � Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 31157 - 1195321
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 9
Page 7 of 15

lacmnalyficalo
SAMPLE SUMMARY
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID Sample ID Matrix Date Collected Date Received
311570001
311570002
Report ID: 31157 - 1195321
4nela(f
3902-MW2R
3902-MW3R
Bubble Strip
Bubble Strip
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
8/6/201913:32 8/13/201911:00
8/7/2019 09:05 8/13/2019 11:00
Page 3 of 9
Page 8 of 15

lacmnalyficalo
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 311570001 Date Received: 8/13/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-MW2R Date Collected: 8/6/2019 13:32
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 2.0 nM 1.0 0.75 1 8/15/2019 07:06 TD n
Report ID: 31157 - 1195321 Page 4 of 9
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 9 of 15

lacmnalyficalo
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 311570002 Date Received: 8/13/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-MW3R Date Collected: 8/7/2019 09:05
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 5.4 nM 1.0 0.75 1 8/15/2019 07:21 TD n
Report ID: 31157 - 1195321 Page 5 of 9
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 10 of 15

lacmnalyficalo
ANALYTICAL RESULTS QUALIFIERS
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
n The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 31157 - 1195321
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 6 of 9
Page 11 of 15

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/7723
Analysis Method:
AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 311570001, 311570002
METHOD BLANK: 62696
Blank
Reporting
Parameter Units
Result
Limit Qualifiers
RISK
Hydrogen nM
0.75U
0.75 n
LABORATORY CONTROL SAMPLE & LCSD:
62699
62702
Spike
LCS LCSD LCS
LCSD % Rec Max
Parameter Units
Conc. Result Result % Rec
% Rec Limit RPD RPD Qualifiers
Hydrogen nM
24
22 22 92
92 80-120 0.55 20 n
Report ID: 31157 - 1195321
.4r-tielac�,
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 7 of 9
Page 12 of 15

lacmnalyficalo
QUALITY CONTROL DATA QUALIFIERS
Workorder: 31157 BUTNER LF / 92440779
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 31157 - 1195321
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 8 of 9
Page 13 of 15

lacmnalyficalo
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 31157 BUTNER LF / 92440779
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Analysis
Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch
311570001 3902-MW2R
311570002 3902-MW3R
Report ID: 31157 - 1195321
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
AM20GAX
AM20GAX
DISG/7723
DISG/7723
Page 9 of 9
Page 14 of 15

Chain of Custody
PASI Charlotte Laboratory
Workorder: 92440779 Workorder Name: Butner LF Dissolved Hydrogen
�-� aceAnalyticl
LO
www.paca(abs.cn
a)
0)
M
d
Results Requested By: 8/23/2019
: Requested
Aralysis
Nicole Gasiorowski
Pace Analytical Charlotte P.O.
9800 Kincey Ave. Suite 100 Pace Energy
Huntersville, NC 28078 220 William Pitt Way
Phone [phone] Pittsburgh, PA 15238
g
Email: [e-mail]
412-826-2389
,
State of Sample Origin: NC
preserved-.JG iiaexs
>
�terft
5ain le1D'� F
baefie
Lafi ID
Nfatmc _
"
LAB USE ONLY
Re-
1
3902-MW2R
8/6/201913:32
92440779001
Air
t
X
2
3902-MW3R
8/7/2019 09:05
92440779002
Air
I
X
3
4
5
-
Transfers
Released By
Date/Time
Received By
Daterrime
2
/
3
Cooler Tem erature on'Recei t °C
Custody -Seal Y.. or. ,,N- , .
---Rece ved,on Ice Y. or N_
Samples Intact Y or N-:
Monday, August 12, 2019 3:52:13 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
August 22, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Granville Co Butner Resample
Pace Project No.: 92441606
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on August 15, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
CERTIFICATIONS
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
South Carolina Certification #: 99006001
Louisiana/NELAP Certification # LA170028
Florida/NELAP Certification #: E87627
North Carolina Drinking Water Certification #: 37706
Kentucky UST Certification #: 84
North Carolina Field Services Certification #: 5342
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 12
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 17

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Lab ID Sample ID
92441606001 MW-6
SAMPLE SUMMARY
Matrix Date Collected Date Received
Water 08/14/1915:30 08/15/1913:42
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92441606001 MW-6 EPA 8260D CL 50 PASI-C
EPA 8260D Mod. CL 3 PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 17

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Sample: MW-6 Lab ID: 92441606001 Collected: 08/14/19 15:30 Received: 08/15/19 13:42 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Date: 08/22/2019 03:55 PM
Analytical Method: EPA 8260D
ND
ug/L
25.0
6.2
1
08/16/19 20:56
67-64-1
ND
ug/L
10.0
0.90
1
08/16/19 20:56
107-13-1
ND
ug/L
1.0
0.15
1
08/16/19 20:56
71-43-2
ND
ug/L
1.0
0.34
1
08/16/19 20:56
74-97-5
ND
ug/L
1.0
0.26
1
08/16/19 20:56
75-27-4
ND
ug/L
1.0
0.62
1
08/16/19 20:56
75-25-2
ND
ug/L
2.0
0.62
1
08/16/19 20:56
74-83-9
ND
ug/L
5.0
3.3
1
08/16/19 20:56
78-93-3
ND
ug/L
2.0
0.40
1
08/16/19 20:56
75-15-0
ND
ug/L
1.0
0.22
1
08/16/19 20:56
56-23-5
ND
ug/L
1.0
0.23
1
08/16/19 20:56
108-90-7
ND
ug/L
1.0
0.49
1
08/16/19 20:56
75-00-3
ND
ug/L
5.0
2.3
1
08/16/19 20:56
67-66-3
ND
ug/L
1.0
0.39
1
08/16/19 20:56
74-87-3
ND
ug/L
5.0
0.26
1
08/16/19 20:56
96-12-8
ND
ug/L
1.0
0.41
1
08/16/19 20:56
124-48-1
ND
ug/L
1.0
0.26
1
08/16/19 20:56
106-93-4
ND
ug/L
1.0
0.46
1
08/16/19 20:56
74-95-3
ND
ug/L
1.0
0.29
1
08/16/19 20:56
95-50-1
ND
ug/L
1.0
0.26
1
08/16/19 20:56
106-46-7
ND
ug/L
1.0
0.54
1
08/16/19 20:56
110-57-6
ND
ug/L
1.0
0.27
1
08/16/19 20:56
75-34-3
ND
ug/L
1.0
0.34
1
08/16/19 20:56
107-06-2
ND
ug/L
1.0
0.24
1
08/16/19 20:56
75-35-4
ND
ug/L
1.0
0.29
1
08/16/19 20:56
156-59-2
ND
ug/L
1.0
0.25
1
08/16/19 20:56
156-60-5
ND
ug/L
1.0
0.19
1
08/16/19 20:56
78-87-5
ND
ug/L
1.0
0.30
1
08/16/19 20:56
10061-01-5
ND
ug/L
1.0
0.31
1
08/16/19 20:56
10061-02-6
ND
ug/L
1.0
0.26
1
08/16/19 20:56
100-41-4
ND
ug/L
5.0
0.57
1
08/16/19 20:56
591-78-6
ND
ug/L
20.0
12.5
1
08/16/19 20:56
74-88-4
ND
ug/L
5.0
3.7
1
08/16/19 20:56
75-09-2
ND
ug/L
5.0
4.5
1
08/16/19 20:56
108-10-1
ND
ug/L
1.0
0.27
1
08/16/19 20:56
100-42-5
ND
ug/L
1.0
0.34
1
08/16/19 20:56
630-20-6
ND
ug/L
1.0
0.22
1
08/16/19 20:56
79-34-5
ND
ug/L
1.0
0.16
1
08/16/19 20:56
127-18-4
ND
ug/L
1.0
0.24
1
08/16/19 20:56
108-88-3
ND
ug/L
1.0
0.18
1
08/16/19 20:56
71-55-6
ND
ug/L
1.0
0.24
1
08/16/19 20:56
79-00-5
ND
ug/L
1.0
0.22
1
08/16/19 20:56
79-01-6
ND
ug/L
1.0
0.31
1
08/16/19 20:56
75-69-4
ND
ug/L
1.0
0.35
1
08/16/19 20:56
96-18-4
ND
ug/L
2.0
1.4
1
08/16/19 20:56
108-05-4
ND
ug/L
1.0
0.24
1
08/16/19 20:56
75-01-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
v1
Page 5 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Sample: MW-6
Lab ID:
92441606001
Collected:
08/14/19 15:30
Received: 08/15/19 13:42 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Xylene (Total)
ND
ug/L
1.0
0.63 1
08/16/19 20:56
1330-20-7
Surrogates
4-Bromofluorobenzene (S)
105
%
70-130
1
08/16/19 20:56
460-00-4
1,2-Dichloroethane-d4 (S)
101
%
70-130
1
08/16/19 20:56
17060-07-0
Toluene-d8 (S)
100
%
70-130
1
08/16/19 20:56
2037-26-5
8260D MSV SIM
Analytical
Method: EPA 8260D
Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1.2 1
08/20/19 11:14
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
106
%
50-150
1
08/20/19 11:14
17060-07-0
Toluene-d8 (S)
110
%
50-150
1
08/20/19 11:14
2037-26-5
Date: 08/22/2019 03:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 17

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
QC Batch: 492856 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92441606001
METHOD BLANK: 2656775
Associated Lab Samples: 92441606001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
08/16/19 16:01
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
08/16/19 16:01
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
08/16/19 16:01
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
08/16/19 16:01
1,1-Dichloroethane
ug/L
ND
1.0
0.27
08/16/19 16:01
1,1-Dichloroethene
ug/L
ND
1.0
0.24
08/16/19 16:01
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
08/16/19 16:01
1,2-Dibromo-3-chloropropane
ug/L
ND
5.0
0.26
08/16/19 16:01
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
08/16/19 16:01
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
08/16/19 16:01
1,2-Dichloroethane
ug/L
ND
1.0
0.34
08/16/19 16:01
1,2-Dichloropropane
ug/L
ND
1.0
0.19
08/16/19 16:01
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
08/16/19 16:01
2-Butanone (MEK)
ug/L
ND
5.0
3.3
08/16/19 16:01
2-Hexanone
ug/L
ND
5.0
0.57
08/16/19 16:01
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
08/16/19 16:01
Acetone
ug/L
ND
25.0
6.2
08/16/19 16:01
Acrylonitrile
ug/L
ND
10.0
0.90
08/16/19 16:01
Benzene
ug/L
ND
1.0
0.15
08/16/19 16:01
Bromochloromethane
ug/L
ND
1.0
0.34
08/16/19 16:01
Bromodichloromethane
ug/L
ND
1.0
0.26
08/16/19 16:01
Bromoform
ug/L
ND
1.0
0.62
08/16/19 16:01
Bromomethane
ug/L
ND
2.0
0.62
08/16/19 16:01
Carbon disulfide
ug/L
ND
2.0
0.40
08/16/19 16:01
Carbon tetrachloride
ug/L
ND
1.0
0.22
08/16/19 16:01
Chlorobenzene
ug/L
ND
1.0
0.23
08/16/19 16:01
Chloroethane
ug/L
ND
1.0
0.49
08/16/19 16:01
Chloroform
ug/L
ND
5.0
2.3
08/16/19 16:01
Chloromethane
ug/L
ND
1.0
0.39
08/16/19 16:01
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
08/16/19 16:01
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
08/16/19 16:01
Dibromochloromethane
ug/L
ND
1.0
0.41
08/16/19 16:01
Dibromomethane
ug/L
ND
1.0
0.46
08/16/19 16:01
Ethylbenzene
ug/L
ND
1.0
0.26
08/16/19 16:01
lodomethane
ug/L
ND
20.0
12.5
08/16/19 16:01
Methylene Chloride
ug/L
ND
5.0
3.7
08/16/19 16:01
Styrene
ug/L
ND
1.0
0.27
08/16/19 16:01
Tetrachloroethene
ug/L
ND
1.0
0.16
08/16/19 16:01
Toluene
ug/L
ND
1.0
0.24
08/16/19 16:01
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
08/16/19 16:01
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
08/16/19 16:01
v1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 17

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
METHOD BLANK: 2656775
Matrix:
Water
Associated Lab Samples: 92441606001
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
08/16/19 16:01
Trichloroethene
ug/L
ND
1.0
0.22
08/16/19 16:01
Trichlorofluoromethane
ug/L
ND
1.0
0.31
08/16/19 16:01
Vinyl acetate
ug/L
ND
2.0
1.4
08/16/19 16:01
Vinyl chloride
ug/L
ND
1.0
0.24
08/16/19 16:01
Xylene (Total)
ug/L
ND
1.0
0.63
08/16/19 16:01
1,2-Dichloroethane-d4 (S)
%
99
70-130
08/16/19 16:01
4-Bromofluorobenzene (S)
%
104
70-130
08/16/19 16:01
Toluene-d8 (S)
%
100
70-130
08/16/19 16:01
LABORATORY CONTROL SAMPLE:
Parameter
2656776
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
52.5
105
70-130
1,1,1-Trichloroethane
ug/L
50
50.8
102
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
50.5
101
70-130
1,1,2-Trichloroethane
ug/L
50
51.2
102
70-130
1,1-Dichloroethane
ug/L
50
51.3
103
70-130
1,1-Dichloroethene
ug/L
50
53.2
106
70-130
1,2,3-Trichloropropane
ug/L
50
52.6
105
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
48.3
97
70-130
1,2-Dibromoethane (EDB)
ug/L
50
51.1
102
70-130
1,2-Dichlorobenzene
ug/L
50
48.4
97
70-130
1,2-Dichloroethane
ug/L
50
47.2
94
70-130
1,2-Dichloropropane
ug/L
50
50.8
102
70-130
1,4-Dichlorobenzene
ug/L
50
48.1
96
70-130
2-Butanone (MEK)
ug/L
100
104
104
64-135
2-Hexanone
ug/L
100
107
107
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
105
105
70-130
Acetone
ug/L
100
105
105
61-157
Acrylonitrile
ug/L
250
249
100
61-143
Benzene
ug/L
50
51.2
102
70-130
Bromochloromethane
ug/L
50
50.1
100
70-130lK
Bromodichloromethane
ug/L
50
52.6
105
70-130
Bromoform
ug/L
50
52.6
105
70-130
Bromomethane
ug/L
50
46.8
94
38-130
Carbon disulfide
ug/L
50
49.6
99
68-130
Carbon tetrachloride
ug/L
50
51.3
103
70-130
Chlorobenzene
ug/L
50
48.8
98
70-130
Chloroethane
ug/L
50
43.2
86
37-142
Chloroform
ug/L
50
49.9
100
70-130
Chloromethane
ug/L
50
50.7
101
48-130 v1
cis-1,2-Dichloroethene
ug/L
50
50.1
100
70-130
cis-1,3-Dichloropropene
ug/L
50
56.0
112
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 17

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
LABORATORY CONTROL SAMPLE:
2656776
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
52.2
104
70-130
Dibromomethane
ug/L
50
48.9
98
70-130
Ethylbenzene
ug/L
50
50.6
101
70-130
lodomethane
ug/L
100
105
105
40-1301K
Methylene Chloride
ug/L
50
48.9
98
67-132
Styrene
ug/L
50
51.2
102
70-130
Tetrachloroethene
ug/L
50
49.9
100
69-130
Toluene
ug/L
50
48.7
97
70-130
trans-1,2-Dichloroethene
ug/L
50
51.6
103
70-130
trans- 1,3-Dichloropropene
ug/L
50
54.8
110
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
58.7
117
35-189
Trichloroethene
ug/L
50
49.9
100
70-130
Trichlorofluoromethane
ug/L
50
50.6
101
63-130
Vinyl acetate
ug/L
100
116
116
55-143
Vinyl chloride
ug/L
50
52.4
105
70-131
Xylene (Total)
ug/L
150
153
102
70-130
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
100
70-130
MATRIX SPIKE SAMPLE:
2656778
92441606001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.0
105
73-134
1,1,1-Trichloroethane
ug/L
ND
20
23.0
115
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
18.5
92
70-136
1,1,2-Trichloroethane
ug/L
ND
20
20.4
102
70-135
1,1-Dichloroethane
ug/L
ND
20
21.2
106
70-139
1,1-Dichloroethene
ug/L
ND
20
24.3
122
70-154
1,2,3-Trichloropropane
ug/L
ND
20
17.1
85
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
23.2
116
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.4
107
70-137
1,2-Dichlorobenzene
ug/L
ND
20
22.9
114
70-133
1,2-Dichloroethane
ug/L
ND
20
22.1
110
70-137
1,2-Dichloropropane
ug/L
ND
20
21.0
105
70-140
1,4-Dichlorobenzene
ug/L
ND
20
20.6
103
70-133
2-Butanone (MEK)
ug/L
ND
40
39.1
98
60-139
2-Hexanone
ug/L
ND
40
43.3
108
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
40.4
101
65-135
Acetone
ug/L
ND
40
40.7
102
60-148
Acrylonitrile
ug/L
ND
100
101
101
64-147
Benzene
ug/L
ND
20
22.2
111
70-151
Bromochloromethane
ug/L
ND
20
20.5
102
70-141
Bromodichloromethane
ug/L
ND
20
23.5
118
70-138
Bromoform
ug/L
ND
20
20.2
101
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
MATRIX SPIKE SAMPLE:
Parameter
2656778
Units
92441606001
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
18.5
93
15-152
Carbon disulfide
ug/L
ND
20
22.0
110
69-149
Carbon tetrachloride
ug/L
ND
20
25.1
125
70-143 v1
Chlorobenzene
ug/L
ND
20
21.4
107
70-138
Chloroethane
ug/L
ND
20
25.7
129
52-163
Chloroform
ug/L
ND
20
21.3
107
70-139
Chloromethane
ug/L
ND
20
23.3
117
41-139
cis-1,2-Dichloroethene
ug/L
ND
20
21.6
108
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
19.0
95
70-137
Dibromochloromethane
ug/L
ND
20
20.7
103
70-134
Dibromomethane
ug/L
ND
20
21.2
106
70-138
Ethylbenzene
ug/L
ND
20
21.7
109
66-153
lodomethane
ug/L
ND
40
38.2
96
20-138
Methylene Chloride
ug/L
ND
20
21.6
108
42-159
Styrene
ug/L
ND
20
19.4
97
70-135
Tetrachloroethene
ug/L
ND
20
21.5
108
59-143
Toluene
ug/L
ND
20
19.9
100
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
23.1
116
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
19.5
97
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
21.2
106
47-135 v1
Trichloroethene
ug/L
ND
20
23.0
115
70-147
Trichlorofluoromethane
ug/L
ND
20
25.1
126
70-148
Vinyl acetate
ug/L
ND
40
34.7
87
49-151
Vinyl chloride
ug/L
ND
20
27.0
135
70-156
Xylene (Total)
ug/L
ND
60
63.5
106
63-158
1,2-Dichloroethane-d4 (S)
%
107
70-130
4-Bromofluorobenzene (S)
%
92
70-130
Toluene-d8 (S)
%
93
70-130
SAMPLE DUPLICATE: 2656777
Parameter
Units
92441559001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
ND
ND
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
SAMPLE DUPLICATE: 2656777
Parameter
Units
92441559001
Result
Dup
Result
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
1.2
0.94J
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
13.3
ND
Chloroethane
ug/L
0.55J
ND
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
ND
ND
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
100
101
4-Bromofluorobenzene (S)
%
104
108
Toluene-d8 (S)
%
101
111
Max
RPD RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30 v1
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30 v1
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville Co Butner Resample
Pace Project No.: 92441606
QC Batch: 493308 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92441606001
METHOD BLANK: 2658811
Associated Lab Samples: 92441606001
Parameter
Units
1,4-Dioxane (p-Dioxane)
ug/L
1,2-Dichloroethane-d4 (S)
%
Toluene-d8 (S)
%
Matrix: Water
Blank Reporting
Result Limit
ND 2.0
100 50-150
107 50-150
MDL Analyzed
1.2 08/20/19 09:15
08/20/19 09:15
08/20/19 09:15
Qualifiers
LABORATORY CONTROL SAMPLE: 2658812
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 19.2 96 70-130
1,2-Dichloroethane-d4 (S) % 101 50-150
Toluene-d8(S) % 106 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2658813
2658814
MS
MSD
92441776021 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 40
20 36.5 19.4
91
97
50-150
61 30 R1
1,2-Dichloroethane-d4 (S)
%
101
100
50-150
30
Toluene-d8 (S)
%
114
115
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 17

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: Granville Co Butner Resample
Pace Project No.: 92441606
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should
be considered an estimated value.
R1 RPD value was outside control limits.
v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the
associated samples may have a high bias.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 08/22/2019 03:55 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 17

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Granville Co Butner Resample
Pace Project No.: 92441606
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92441606001
92441606001
MW-6
MW-6
EPA 8260D
EPA 8260D Mod.
492856
493308
Date: 08/22/2019 03:55 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 14 of 17

Sample Condition Upon ReceipOCUR) "age 1 of 2
�VaxAmO'01!Document No.: uingAuthority:
F w-05.033-Rev.06 t—p—aceclsa5mlinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville Ralelgh❑ Mechanicsville[]
ition Client Nanie. WO# : 92441606
Project it:
Courier: []FO Ex ❑UPS CUSPS ❑Client �� ��� III I� k I I �I�� ��■
❑ Commercial �ace ❑Other: 92441606
Custody Seal ?resent? ❑Yes' HNo Seals Intact? Oyes [ ;Io
DitelinifialsPerson Examining Contents: /
Packing Material: []Bubble Wrap Bubble Bags ❑None ❑ Other Biological Tissue5;ozen?
Therrhometq/ [:]Yes[:]NoON/A
IA Gun 10:
92TO48 . type of Ice: pwet ❑blue ❑None
CoolerTerrip (°C]- O. Y . Correction Factor: Add/Subtract ('C) 0.0
Tempshould be above freezing to 6°C
Cooler Temp Corrected (°C): []samples out of temp criteria. Samples on ice, cooling process
hashegun
USDA itegulated Sail S[9/N/A, water sample)
Did samples.or'gin to in a quarantine zone within the United States: CternA, NY, or SC (check maps)? Did samples originate from a foreign source (inanally,
rs„_- mcludnnilawaii and Puerto Rlca)? ❑Yes a
Chain of CuRady Present?
[RfYes
[]No
[]N/A
11
Samples Arrived within Hold Time? ..
2Yes
❑No
❑N/A
2.
Short Hold Time Analysts (<72 hr.)?
❑Yes
mflo
❑N/A
3-
Rush Turn Around Time Requested?
[]yes
G] o
❑NIA
4.
Sufficient Volume?
IR (Ys
❑No
❑N/A
S.
Correct Containers Used?
Bjq,
[:]No
[]N/A
6.
-Pace Containers Used?
L//res
❑No
[]N/AContainers
Intact?
Cc7Yes
ON,
QNN/A
7.
Dissolved analysis: Samples Field Filtered?
❑Y
[:]No
t34/A
8•
Sample Latrels Match COO
es
❑No
❑N/A
-Ihcludes Hate/Time/lD/Anatysis Matrix:
Headspace in VOA Vials (>5-6mm)?
❑Yes
LKNo
I✓7N/A
10•
Trip Blank Present?
[]Yes❑No
Trip Blank Custody Seals present?
❑Yes
[:]No
COMMENT5/SAMPLE 011SCREPANCY
Field DataRequtred? Oyes ❑No
Lot ID ofspit containers:
CLIENT NOTIFICATION/RESQLUT1014
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Date:
�1 Date: V JL
Page 15 of 17

% . aceAnalyftar
Issuing Authority,
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: voA, Coliform, TOC, Oil and Grease, DRO/9035 (water) DOC, LLHg
"*Bottom half of box is to list number of bottle
g
CLP
w
a
c
7
2
a
c
u
F'
a
:
a
c
•~
N3
Z
d
v
a
r
U
N
x
a
d
ti
rt
S
u
V
s
a
m
O
Z
z
u
%
n
Z'
J
m
u
Q
Z
N
u
p
m
N
ry
_
a-
x
O
f4
Z
"
N
z
d
[ Z
_?
y
n v
- `a
c
v
s
7 1
q E
E Q
a
m
E
m
E
CL
m
E
m
n.
m
J
J+
m
J
zLr
-E
N
m
J
u
m
=
1
z
3
4
5
6
7
8
9'
sa
11
iz
Project # WQ# : 92441606
PM: NMG Due Date: 08/29/19
CLIENT: 92-Joyce Eng
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount added ervauve
of Lot 4
adjusted
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Carolina DEHNR Certlff.tion office 57
Out of hold, incmeetpreservative, out of temp, incorrect containers.
Page 16 of 17

CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. `6
d
Section A Section B Section C
Required Client Information: Required Project Information: invoice Infarmwtiom
Company, Labella Associates
Report TD: Van Burbach
Attention: Lecia Jones
[iyG 1 V I 7 I
Address: 2211 West Meadouvview Rd, Suite 101
Copy To: Miguel Vazquez
Company Name, Labella Assoc.
Greensboro, NC 27407
Address:
1604 pwnp Lane, Richmond, VA
23220
RegMoto q enc
Email TO: n1v3Z LICZ(n-labella C.COfTI Purchase Order No.
Quote
Reference:
Phone: [phone] Fax: [phone] Client Project to:
Granville
Co. - Butner LF Resam le
Project
Manager: Nicole Gasiorowski
State I Location
Requested Due CaleffAT: 10 Da Default COnlalnerOrder Number:
Profile
9:
NC
Re
uesletl
Analysis
Filtered
YM
a
S
MATRIX CODE _
O
COLLECTED Z
Preservatives }
Drinking water oW
WAor WT 4
ii
U
O
Wstn Wutnr wW a_
U
PlOeucl p
SAMPLE ID 5°014;cold s�
a
Oil oL
c7
START
END
One Character per bon.-
tA-Z, D-91 , -) A. AR
CO., O7 O
Sample Ids must he unique T,— TS x
>
w
w
c
N
�i
O
o
T"T'T",
O
W
~
;z
N
DATE
TIME
s
U
a
O
in
_
_=
Oy
z
N
z
t
L
O
C
a
Q
v
f
1 MW-6 WT
G
�t/1 i/19
3G
x
X
% J
2
3
4
5
6
7
B
9
10
11
12
ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIATION
DATE
TIME
ACCEPTED BY I AFFILIATION
DATE
TIME
SAMPLE CONDITIONS
S.S
1M-)
JOC)57
c
in
,
-E
J
SAMPLER NAME AND SIGNATURE
d
PRINT Name of SAMPLER:
M6l7�/l
_7lMcir976767.� ./ ClIY1r 15�1
SIGNATURE of SAMPLER: j /� /
DATE Signed{^
zof�

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
September 09, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Granville - Butner Resample
Pace Project No.: 92444312
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on September 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Gretta Eller, LaBella Associates, D.P.C.
Ashley Martin, Labella Associates
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 12

acmnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Granville - Butner Resample
Pace Project No.: 92444312
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 12

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Granville - Butner Resample
Pace Project No.: 92444312
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92444312001
92444312002
MW-3R
Trip Blank
Water
Water
09/04/1911:40
09/04/19 09:15
09/05/1911:10
09/05/19 11:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Granville - Butner Resample
Pace Project No.: 92444312
Analytes
Lab ID Sample ID Method Analysts Reported Laboratory
92444312001 MW-3R EPA 8260E SAS 4 PASI-C
92444312002 Trip Blank EPA 8260E SAS 4 PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Granville - Butner Resample
Pace Project No.: 92444312
Sample: MW-3R
Lab ID:
92444312001
Collected:
09/04/19 11:40
Received: 09/05/19 11:10 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260 MSV Low Level Landfill
Analytical
Method: EPA 8260E
Vinyl chloride
ND
ug/L
1.0
0.24 1
09/06/19 18:15
75-01-4
Surrogates
4-Bromofluorobenzene (S)
104
%
70-130
1
09/06/19 18:15
460-00-4
1,2-Dichloroethane-d4 (S)
79
%
70-130
1
09/06/19 18:15
17060-07-0
Toluene-d8 (S)
104
%
70-130
1
09/06/19 18:15
2037-26-5
Date: 09/09/2019 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 5 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Granville - Butner Resample
Pace Project No.: 92444312
Sample: Trip Blank
Lab ID:
92444312002
Collected:
09/04/19 09:15
Received: 09/05/19 11:10 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260 MSV Low Level Landfill
Analytical
Method: EPA 8260E
Vinyl chloride
ND
ug/L
1.0
0.24 1
09/06/19 17:57
75-01-4
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
09/06/19 17:57
460-00-4
1,2-Dichloroethane-d4 (S)
75
%
70-130
1
09/06/19 17:57
17060-07-0
Toluene-d8 (S)
104
%
70-130
1
09/06/19 17:57
2037-26-5
Date: 09/09/2019 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Granville - Butner Resample
Pace Project No.: 92444312
QC Batch: 496489 Analysis Method: EPA 8260B
QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill
Associated Lab Samples: 92444312001, 92444312002
METHOD BLANK: 2673917
Matrix:
Water
Associated Lab Samples:
92444312001, 92444312002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
Vinyl chloride
ug/L
ND
1.0
0.24 09/06/19 16:12
1,2-Dichloroethane-d4 (S)
%
77
70-130
09/06/19 16:12
4-Bromofluorobenzene (S)
%
100
70-130
09/06/19 16:12
Toluene-d8 (S)
%
103
70-130
09/06/19 16:12
LABORATORY CONTROL SAMPLE:
2673918
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Vinyl chloride
ug/L
50
48.7
97
70-131
1,2-Dichloroethane-d4 (S)
%
87
70-130
4-Bromofluorobenzene (S)
%
97
70-130
Toluene-d8 (S)
%
96
70-130
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2673919
2673920
MS
MSD
92443516002
Spike
Spike MS
MSD
MS MSD
% Rec Max
Parameter
Units
Result
Conc.
Conc. Result
Result
% Rec % Rec
Limits RPD RPD Qual
Vinyl chloride
ug/L
ND
20
20 23.9
22.5
120 113
70-156 6 30
1,2-Dichloroethane-d4 (S)
%
92 92
70-130
4-Bromofluorobenzene (S)
%
96 100
70-130
Toluene-d8 (S)
%
99 100
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/09/2019 04:05 PM without the written consent of Pace Analytical Services, LLC.
Page 7 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Granville - Butner Resample
Pace Project No.: 92444312
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/09/2019 04:05 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Granville - Butner Resample
Pace Project No.: 92444312
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92444312001
92444312002
MW-3R
Trip Blank
EPA 8260B
EPA 8260B
496489
496489
Date: 09/09/2019 04:05 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 9 of 12

Document Name:
Document Revised: February 7, 2018
aceAnalytiol m
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville Raleigh❑ Mechanicsville❑
ConditionSample Client Name;Upon WQ# : 92444312
Receipt LG2.J�c f fI(il,- Project #f:
P Client
ther: 1111111111111111111111111111111
Ehe
82444312 _
Custody Seal Present? Des to seals Intact? Dyes No
C_
Date/lnitials Person Examiningtontents: 5��
Packing Materfal: ❑Bubble Wrap Bubble Bags ❑None ❑ Other alological � ue Frozen?
Thermometer: ❑Yes MNO ❑N/A
IR Gun ID: 921049 Type of Ice: 2<et ❑Brue ❑None
Cooler Temp {'C): _ a, & Correction Factor: Add/Subtract {°C} 0.0
1 I Temp should be above freezing to VC
Cooler Temp Corrected i°C}: ^ge,esa;errn i OF M 2IJ rrtMild. -samplFson ice, coaling process
hashegun
USDA Regulated Soil { /A, water sample}
Did samples originpJt in a quarantine zone within the United States: CA, NY, or SC {check maps}? Did samples originate from a foreign source (intemationally,
❑yes o including Hawaii and Puerto Rico)? [:]Yes ❑No
Comments/Discrena ncv:
Chain of Custody Present?
Orr-
EIN.
El N/A
1.
Samples Arrived within Hold Time?
❑ esf s
[]NO
❑NIA
2.
Short Hold Time Analysls {c72 hr.}?
Dyes
QNo
[]N/A
3.
Rush Turn Around Time Requested?
❑yes
rTo-
[]N/A
4.
Sufficient Volume? _
Yes
❑No
[I N/A
S.
Correct Containers Used?
0�,Y�
❑No
❑N/A
6.
Pace Containers Used?
1�es
❑No
❑N/A
Containersrnta:t?
fryes
❑No
❑N/A
Z
Dissolved analysis: Samples Field Filtered?
❑Yes
[]No
©QA
S.
Sample Labels Match COC?
QY r
❑No
[]N/A
1 g
-Includes Date/Time/ID/AnalyS
Headspace in VOA Vials {>5-6mm
Trip Blank present?
Trip Blank Custody Seals Present?
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
s ❑Na ❑N/A
s ❑No I7N/A
11.
Date/Time:
Lot ID of split containers:
Field Data Required? []Yes ❑No
Project Manager SCURF Review: Date:
Project Manager SRF Review: of Date:
Page 10 of 12

_� aceArraViCal
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page i of 2
Document No.:
F-CAR-CS-031-Rev.06
Issuing Authority:
Pace Carolinas quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHS
**Bottom half of box is to list number of bottle
Project # Wp# : 92444312
PM: NMG Due Date: 09/19/19
CLIENT: 92-Joyce Eng
vQJu
u�i
Q
u
i
v
u�i
la
2
Z
v�i
u
¢
9
at
Z
M
c
D
u
T
a
0rn
=
v
G
T
u
R
d
ti
V
N
_
T
C
2
O
z
u
1
i7
�
w
t
d
v
a
c
7
m
N
y
—
2
v
z
t'
a
c
=
s
V
G
p
N
=
0
T
v
z
2
E
¢
E
=
z
U
_
0
�n
Z v
a O
T
a
�n
Y
n
a
U
m
y
m
V
a
m
tl1
S
N
_
Z
m
`
c
7
m
N
o
m
H
rq
c
a�
_
a
rn
,-{
O
a.
m
a
0
N
m
a
m
a
-�
o.
H
a
m
rl
°
""�
.Za
a
m
a
J
E
n
r
0.
m
a
J
of
N
en
a
m
a
J
E
v,
eN-I
a
a
Co
a
..,
E
ur
R
�
a
m
E
G
p
�
3
E
Q
:
'_
e-I
m
to
¢
E
Q
Y
rl
A
G
a
Q
aE
N
M
0
¢
E
Q
°
_
ri
.�+
C7
a
a
E
o
N
m
a
rev
m
0
m
0
a
O
7
E
Q
'n
l4
a
DQ
>
E
4
�
�7
0 O
i ?
J J
E E
C
1 �
onOat
U to
7 8
a
e9
a
""
Q
0
7
N
=
f�l
W
>
E
fY
�
p
v,
E
to
N
a
H
,
E
Vim!
M
a
m
E
o
C
0
l7
a
E
O
N
0
in
?
J
E
O
V
0
Q
O
1
\\N—)
C..
3
a
\
5
fi
7
8
9
I
10
11
12
\L-.
I
F
pH Adjustment Log for Preserved Samples
Sample 10
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amountofpreservative
added
Lot It
Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will besentto the North Carolina DEHNR Certification Office (Le,
Out of hold, Incorrect preservative, out oftemp, Incorrect containers.
Page 11 of 12

PaceMalyllcal
Section A
Required Client Information:
Company. LaBella Associ;
Address: 2211 West Mez
Greensboro, NC 27407
Email vburbach labeliapc.,
Phone: (33G}707-3874
Requested Due ❑ate; 1 rl !S
Section B
Required Project
P.C. -NC Report To. Van
w Rd -------------
Copy To:
Purchase Order #:
Fax Project Name:
. CA U I Project #:
SAMPLE ID
One Character per box.
(A-4 0-9 1r -)
Sample Ids must be unique
LU
F
MW-3R
2
Trip Blank
3
4
6
7
a
9
10
11
12
ADDITIONAL COMMENTS
a
MATRtx CODE
_ 0
Drinhmg Wdiq DW
a
Wotm WT
U
W-t. Water WW
b C
Preduei p
SUIVS'nlld SL
ix
U
oil oL
START
MpP WP
Av AR
o a
Other oT
O F
TI._ue TS
K w
✓r a
a a
V'
7E
Ti
WT
WT
N
CHAIN -OF -CUSTODY 1 Analytical Request Document N
The Chain -Of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
N
Section C D_
Invoice Information:
Attention: Pd e : 1 Of 1
Z Company Name:
Address: iri G'L4-}'i M Gr'L - Fi
Pace Quote: Ra lulato A nc
- Butner Resample Pace Project Manager: nicole,gasiorowski pacelabs.com,
Pace Profile #. 3566 State! Location
NC
RELINQUISHED I YTAFFILJATION
F
W
Dfl�c,:
C,CIYdUve5
T
END
J
0
F N
Q
m
�
w
N
z
Q. z
QN4Z
M
c
aO
is
QTIME=
L
J
z
z
Qf
If�1C
3
x
�i 15
Z
X
DATE TIME AOCEPTED BY I AFFILIATION DATE TIME
SAMPLE CONDITIONS
U �L V I/lam
!PLER NAME AND SIGNATURE
PRINT Name of SAMPLER: <tD
TVYIGY1 rL�G , 7 thCAnA—
SIGNATUR£ of SAMPLER: DATE Signed: �] Zo I 4 i u 2 m °1
�� %/ '"( Z o z

Appendix D
Historical Groundwater Elevations

APPENDIX D: Historical Groundwater Elevations
Well ID:
Background
Downgradient
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Well TOC Elev.:
460.51
331.60
330.96
340.80
343.88
362.53
328.40
Well Depth:
56.00
18.85
35.83
31.43
23.52
32.63
32.80
21-Aug-99
418.68
329.13
328.06
330.50
330.83
352.10
NI
16-Nov-99
419.75
325.38
324.51
331.53
334.33
352.97
NI
10-May-00
424.53
329.60
328.83
334.15
334.49
355.72
NI
26-Oct-00
419.21
329.26
328.15
331.33
330.94
352.78
NI
18-Apr-01
418.76
329.42
328.63
333.57
334.36
354.22
NI
26-Oct-01
412.53
329.04
327.94
330.57
330.23
350.92
NI
13-Jun-02
413.70
328.38
327.41
330.21
330.29
351.04
NI
19-Nov-02
413.40
329.25
328.35
331.57
337.17
350.94
NI
27-Jun-03
423.61
329.57
328.93
334.24
333.99
355.21
NI
29-Dec-03
420.23
329.70
329.11
334.49
334.78
354.92
NI
30-Jun-04
418.81
329.38
328.48
332.26
331.39
353.10
NI
28-Dec-04
418.02
329.50
328.91
333.45
334.14
355.14
NI
29-Jun-05
418.81
329.10
329.26
331.62
330.90
352.76
NI
29-Dec-05
413.38
329.29
328.71
332.78
334.27
351.52
NI
27-Jun-06
414.75
329.17
328.40
332.18
333.56
353.43
NI
28-Dec-06
415.54
329.40
328.86
333.57
335.24
354.02
NI
12-Jul-07
438.64
328.69
327.97
331.31
330.52
352.30
NI
18-Dec-07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
8-Jul-08
414.52
329.20
326.00
331.46
330.85
351.03
NM
17-Dec-08
412.79
329.39
328.84
333.15
335.03
350.82
NM
9-Jul-09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
16-Dec-09
418.11
329.55
329.09
334.57
336.94
352.87
NM
24-Jun-10
422.42
329.41
328.77
333.65
333.15
353.62
NM
13-Dec-10
415.96
329.49
328.85
332.81
330.34
350.08
NM
20-Jun-11
416.00
328.95
328.18
336.77
331.38
351.83
NM
5-Dec-11
412.94
329.31
328.65
332.32
329.51
349.87
NM
11-Jun-12
414.56
329.10
328.35
332.52
331.33
351.75
312.50
12-Dec-12
412.83
329.19
328.36
331.67
330.35
349.48
NM
1-May-13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
5-Aug-13
417.97
329.02
328.41
333.32
332.83
353.01
NM
24-Feb-14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
11-Aug-14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
10-Mar-15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
17-Aug-15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
17-Feb-16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
9-Aug-16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
13-Feb-17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
22-Aug-17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
5-Feb-18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
14-Aug-18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
4-Feb-19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
6-Aug-19
420.05
329.35
328.37
332.98
329.73
351.46
310.34
Notes: TOC = Top of casing.
Elevations in feet above mean sea level
Granville County -Butner Landfill
Permit No. 39-02
NM = Water level not measured.
NI = Well not yet installed.
La Bella Associates

Appendix E
Historical Constituents in Groundwater

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
INORGANICS
Antimony
8-Sep-94
---
30
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
--
30
ND
ND
ND
ND
ND
ND
--
9-Feb-95
30
ND
ND
ND
ND
ND
ND
2-Mar-95
--
30
ND
ND
ND
ND
ND
ND
--
--
15-Nov-95
30
ND
ND
ND
ND
ND
ND
28-May-96
--
30
ND
ND
ND
ND
ND
ND
--
--
22-Nov-96
30
ND
ND
ND
ND
ND
ND
17-Jun-97
--
30
ND
ND
ND
ND
ND
ND
--
--
1-Dec-97
30
ND
ND
ND
ND
ND
ND
20-May-98
--
30
ND
ND
ND
ND
ND
ND
--
--
19-Nov-98
30
ND
ND
ND
ND
ND
ND
21-Jul-99
--
30
ND
ND
ND
ND
ND
ND
--
--
16-Nov-99
30
ND
ND
ND
ND
ND
ND
10-May-00
--
30
ND
80.0
38.0
32.0
33.0
31.0
--
--
26-Oct-00
-
30
30.0
ND
ND
ND
ND
ND
18-Apr-01
-
30
ND
ND
ND
ND
ND
ND
--
--
27-Oct-01
-
30
ND
ND
ND
ND
ND
ND
13-Jun-02
-
30
ND
ND
ND
ND
ND
ND
---
--
19-Nov-02
-
30
ND
ND
ND
ND
ND
ND
27-Jun-03
-
30
ND
ND
ND
ND
ND
ND
--
-
30-Dec-03
-
30
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
-
30
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
-
30
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
-
30
ND
ND
ND
ND
ND
ND
ND
29-Dec-05
-
30
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
30
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
6
ND
ND
ND
ND
ND
ND
ND
12-Jul-07
-
6
ND
ND
ND
ND
ND
ND
---
ND
IMAC = 1.4 ug/L (10/23/07)
19-Dec-07
-
6
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
6
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
24-Jun-10
2.6
6.0
ND
ND
ND
2.9 J
ND
ND
-
ND
IMAC = 1 ug/L (8/1/10)
13-Dec-10
2.6
6.0
ND
ND
3.0 J
ND
2.8 J
ND
-
ND
20-Jun-11
5.0
6.0
ND
ND
ND
ND
6.0
ND
-
ND
5-Dec-11
5.0
6.0
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
5.0
6.0
8.8
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
6.0
ND
10.5
8.0
ND
ND
ND
ND
10-Mar-15
3.8
6.0
ND
7.1
6.5
3.9 J
ND
ND
--
ND
18-Aug-15
3.8
6.0
ND
6.2
4.8 J
4.1 J
ND
ND
ND
16-Feb-16
3.8
6.0
ND
9.9
6.5
4.3 J
ND
ND
-
ND
9-Aug-16
3.8
6.0
ND
7.7
ND
ND
ND
ND
-
ND
13-Feb-17
3.9
6.0
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
3.9
6.0
ND
ND
ND
ND
ND
ND
ND
5-Feb-18
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
3.9
5.0
ND
ND
ND
ND
ND
ND
-
ND
7-Aug-19
3.0
5.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-113
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Arsenic
8-Sep-94
-
10
ND
ND
ND
ND
ND
ND
--
---
1-Dec-94
-
10
ND
ND
ND
ND
ND
ND
9-Feb-95
-
10
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
-
10
ND
ND
ND
ND
ND
ND
15-Nov-95
---
10
ND
ND
ND
ND
ND
ND
--
--
28-May-96
-
10
ND
ND
ND
ND
ND
ND
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
-
10
6.0 J
15.0
ND
ND
ND
ND
1-Dec-97
-
10
ND
5.0 J
ND
ND
ND
ND
--
--
20-May-98
-
10
ND
ND
ND
ND
ND
ND
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
10
ND
ND
ND
ND
ND
ND
19-Nov-02
--
10
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
10
2.0 J
ND
ND
ND
ND
ND
---
ND
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
-
10
ND
4.1 J
ND
ND
ND
ND
ND
ND
8-Jul-08
-
10
ND
4.9 J
ND
ND
ND
ND
-
ND
17-Dec-08
2.7
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
2.7
10.0
ND
13.5
10.9
5.6 J
ND
4.0 J
ND
ND
16-Dec-09
2.7
10.0
ND
10.6
6.4 J
5.0 J
ND
3.6 J
-
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
2.7
10.0
ND
11.8
8.1 J
8.2 J
3.3 J
3.1 J
-
ND
Resample >
12-Aug-10
2.7
10.0
-
-
7.2 J
-
-
-
--
ND
Resample >
31-Aug-10
2.7
10.0
-
15.4
-
-
-
-
-
ND
13-Dec-10
2.7
10.0
ND
4.9 J
2.7 J
5.4 J
ND
ND
-
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
--
ND
11-Jun-12
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
--
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
5.6 J
ND
ND
ND
-
ND
24-Feb-14
5.0
10.0
ND
6.4 J
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
--
ND
10-Mar-15
2.5
10.0
4.1 J
5.4 J
ND
ND
3.1 J
3.2 J
-
3.0 J
18-Aug-15
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
-
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
--
5.1 J
13-Feb-17
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
5.0
10.0
ND
5.4 J
ND
ND
ND
ND
-
ND
4-Feb-19
5.0
10.0
ND
5.7 J
ND
ND
ND
ND
-
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Barium
8-Sep-94
-
500
ND
270
ND
ND
830
860
1-Dec-94
-
500
ND
ND
ND
ND
ND
ND
9-Feb-95
-
500
ND
ND
ND
ND
510
ND
--
--
2-Mar-95
-
500
ND
ND
ND
ND
ND
ND
15-Nov-95
-
500
ND
ND
ND
ND
ND
ND
--
--
28-May-96
500
ND
ND
ND
ND
ND
ND
22-Nov-96
--
500
ND
82.0
30.0
ND
15.0
ND
--
--
17-Jun-97
500
200
320
37.0
17.0
210
31.0
1-Dec-97
-
500
61.0
180
43.0
46.0
220
33.0
--
20-May-98
-
500
30.0
150
45.0
13.0
180
22.0
19-Nov-98
--
500
48.0
120
42.0
ND
380
12.0
--
21-Jul-99
500
ND
ND
ND
ND
ND
ND
16-Nov-99
--
500
ND
ND
ND
ND
ND
ND
---
--
10-May-00
500
ND
ND
ND
ND
ND
ND
26-Oct-00
--
500
ND
ND
ND
ND
ND
ND
---
--
18-Apr-01
-
500
ND
ND
ND
ND
ND
ND
27-Oct-01
-
500
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
500
ND
ND
ND
ND
ND
ND
-
19-Nov-02
-
500
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
500
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
500
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
500
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
500
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
500
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
100
5.2 J
120
64.9
1.5 J
64.1
1.8 J
-
0.20 J
12-Jul-07
-
100
2.5 J
129
65.7 J
1.1 J
77.0 J
1.3 J
-
ND
NC 2L = 2,000 pg/L (10/23/07)
19-Dec-07
-
100
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
11.7
8-Jul-08
-
100
5.8 J
102
58.4 J
1.1 B
57.9 J
1.2 B
-
0.29 J
17-Dec-08
0.20
100
2.7 B
92.9 J
53.1 B
1.2 B
55.5 J
1.1 B
-
10.7 J
9-Jul-09
0.20
100
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
17.6 J
16-Dec-09
0.20
100
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
17.1 J
NC 2L = 700 pg/L (02/05/10)
24-Jun-10
0.20
100
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
27.3 J
13-Dec-10
0.20
100
4.3 B
122
67.9 J
1.3 B
90.6 J
1.5 B
-
12.1 J
20-Jun-11
5.0
100
ND
108
70.7 J
ND
84.7 J
ND
-
ND
5-Dec-11
5.0
100
ND
118
73.0 J
ND
90.6 J
ND
-
ND
11-Jun-12
5.0
100
ND
138
65.2 J
ND
76.4 J
ND
61.3 J
ND
12-Dec-12
5.0
100
ND
113
64.7 J
ND
73.6 J
ND
-
ND
1-May-13
5.0
100
ND
118
69.1 J
ND
84.2 J
ND
81.2 J
ND
5-Aug-13
5.0
100
ND
111
65.1 J
ND
95.6 J
ND
-
ND
24-Feb-14
5.0
100
ND
93.8 J
44.8 J
ND
139
ND
ND
ND
12-Aug-14
5.0
100
ND
125
66.4 J
ND
121
ND
-
ND
10-Mar-15
2.5
100
3.0 J
109
61.8 J
ND
116
ND
-
ND
18-Aug-15
2.5
100
4.4 J
119
63.1 J
ND
81.3 J
ND
-
ND
16-Feb-16
2.5
100
5.2 J
123
72.7 J
3.0 J
126
ND
-
ND
9-Aug-16
2.5
100
4.5 J
123
73.3 J
ND
109
ND
-
ND
13-Feb-17
2.5
100
7.8 J
112
68.3 J
ND
151
5.6 J
-
ND
22-Aug-17
2.5
100
ND
102
64.5 J
ND
99.9 J
ND
-
ND
5-Feb-18
2.5
100
8.0 J
117
73.5 J
ND
161
ND
-
ND
13-Aug-18
2.5
100
3.8 J
116
67.6 J
ND
103
ND
-
ND
4-Feb-19
2.5
5
ND
104
44.3
ND
110
ND
-
ND
7-Aug-19
1.0
5.0
5.4
113
73.8
1.2 J
95.1
1.9 J
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-113
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Beryllium
8-Sep-94
-
2
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
2
ND
ND
ND
ND
4.0
ND
9-Feb-95
-
2
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
-
2
ND
ND
ND
ND
2.0
ND
15-Nov-95
-
2
ND
ND
ND
ND
ND
ND
--
--
28-May-96
-
2
ND
ND
ND
ND
6.0
ND
22-Nov-96
-
2
ND
ND
ND
ND
3.0
ND
--
--
17-Jun-97
-
2
2.0
3.0
ND
ND
1.0
ND
1-Dec-97
-
2
ND
ND
ND
ND
ND
ND
--
--
20-May-98
-
2
ND
ND
ND
ND
ND
ND
19-Nov-98
-
2
ND
ND
ND
ND
2.0
ND
--
--
21-Jul-99
-
2
ND
ND
ND
ND
ND
ND
16-Nov-99
-
2
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
2
ND
ND
ND
ND
ND
ND
26-Oct-00
-
2
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
2
ND
12.0
ND
ND
ND
ND
27-Oct-01
-
2
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
-
2
ND
ND
ND
ND
ND
ND
19-Nov-02
-
2
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
-
2
ND
ND
ND
ND
ND
ND
30-Dec-03
-
2
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
2
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
2
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
-
2
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
-
2
ND
ND
ND
ND
ND
ND
ND
29-Dec-05
-
2
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
2
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
1
ND
ND
ND
ND
ND
ND
ND
12-Jul-07
-
1
ND
ND
ND
ND
ND
ND
--
ND
IMAC = 4 pg/L (10/23/07)
19-Dec-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
1
ND
ND
ND
ND
ND
ND
--
ND
17-Dec-08
0.10
1.0
ND
ND
ND
ND
0.14 J
ND
ND
9-Jul-09
0.10
1.0
ND
0.18 J
0.22 J
0.17 J
ND
ND
0.23 J
ND
16-Dec-09
0.10
1.0
ND
0.15 J
0.17 J
0.15 J
0.25 J
ND
--
ND
24-Jun-10
0.10
1.0
ND
ND
0.27 J
0.16 J
ND
ND
-
ND
13-Dec-10
0.10
1.0
ND
ND
ND
ND
ND
ND
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
0.57 J
ND
---
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
7-Aug-19
0.20
1.0
ND
ND
ND
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cadmium
8-Sep-94
-
1
ND
ND
ND
ND
ND
4.0
---
---
1-Dec-94
-
1
ND
ND
ND
ND
ND
ND
9-Feb-95
-
1
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
-
1
ND
ND
ND
ND
ND
ND
15-Nov-95
-
1
ND
ND
ND
ND
ND
ND
--
--
28-May-96
-
1
ND
ND
ND
ND
ND
ND
22-Nov-96
-
1
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
-
1
ND
3.0
1.0
ND
ND
ND
1-Dec-97
-
1
ND
2.0
ND
ND
ND
ND
--
--
20-May-98
-
1
ND
ND
ND
ND
ND
ND
19-Nov-98
-
1
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
1
ND
ND
ND
ND
ND
ND
16-Nov-99
-
1
ND
3.0
3.0
ND
2.0
ND
--
--
10-May-00
-
1
5.0
ND
ND
ND
ND
ND
26-Oct-00
-
1
ND
2.0
ND
ND
ND
ND
--
--
18-Apr-01
-
1
ND
11.0
ND
ND
ND
ND
27-Oct-01
-
1
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
-
1
ND
2.0
ND
ND
ND
ND
19-Nov-02
-
1
2.0
2.0
ND
ND
2.0
ND
---
--
27-Jun-03
-
1
ND
ND
ND
ND
ND
ND
30-Dec-03
-
1
ND
1.0
ND
ND
ND
ND
--
ND
30-Jun-04
-
1
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
1
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
1
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
1
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
1
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
1
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
-
1
ND
ND
ND
ND
ND
ND
-
ND
NC 2L = 1.75 pg/L (10/23/07)
19-Dec-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
1
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
0.50
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
16-Dec-09
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 2 pg/L (02/05/10)
24-Jun-10
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
5-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.50
1.0
ND
ND
ND
ND
ND
ND
--
ND
7-Aug-19
0.40
1.0
ND
ND
ND
0.48 J
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chromium
8-Sep-94
-
10
8.0
44.0
ND
6.0
48.0
80.0
1-Dec-94
-
10
14.0
ND
ND
ND
18.0
ND
9-Feb-95
-
10
14.0
ND
ND
10.0
ND
ND
--
2-Mar-95
10
ND
ND
ND
ND
ND
ND
15-Nov-95
--
10
13.0
13.0
ND
ND
ND
ND
--
28-May-96
10
33.0
ND
ND
ND
ND
ND
22-Nov-96
--
10
3.0
ND
ND
ND
ND
3.0
--
--
17-Jun-97
10
57.0
43.0
ND
3.0
2.0
6.0
1-Dec-97
--
10
29.0
ND
ND
ND
ND
ND
--
--
20-May-98
10
10.0
3.0
ND
ND
12.0
ND
19-Nov-98
--
10
17.0
3.0
ND
ND
5.0
ND
--
--
21-Jul-99
10
ND
ND
ND
ND
ND
ND
16-Nov-99
---
10
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
12.0
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
10
ND
ND
ND
ND
ND
ND
19-Nov-02
--
10
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
--
10
ND
2.0 B
ND
ND
ND
ND
1.1 B
1.4 J
8-Jul-08
-
10
ND
0.54 J
0.58 J
ND
ND
ND
ND
17-Dec-08
0.40
10.0
0.73 J
1.8 J
0.96 J
ND
0.96 J
0.70 J
--
ND
9-Jul-09
0.40
10.0
1.2 J
2.4 J
1.1 J
1.6 J
0.68 J
0.53 J
4.8 J
ND
16-Dec-09
0.40
10.0
1.3 J
ND
ND
ND
0.95 J
ND
--
ND
NC 2L = 10 pg/L (02/05/10)
24-Jun-10
0.40
10.0
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
0.71 J
13-Dec-10
0.40
10.0
2.5 J
1.3 J
1.8 J
0.69 J
0.57 J
1.2 J
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
8.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
5.2 J
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
2.5
10.0
ND
2.7 J
ND
ND
ND
6.7 J
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
2.5
10.0
2.8 B
2.8 B
ND
ND
ND
ND
--
2.9 J
13-Feb-17
2.5
10.0
ND
2.6 J
ND
ND
ND
ND
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
--
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
7-Aug-19
1.0
5.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-113
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cobalt
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
10
11.0
ND
13.0
16.0
22.0
ND
9-Feb-95
-
10
20.0
14.0
ND
48.0
39.0
ND
--
2-Mar-95
-
10
16.0
21.0
ND
29.0
121.0
ND
15-Nov-95
-
10
20.0
21.0
ND
ND
27.0
ND
--
28-May-96
10
30.0
16.0
ND
ND
122
ND
22-Nov-96
--
10
6.0
13.0
ND
4.7
93.0
ND
--
--
17-Jun-97
10
130
38.0
ND
6.0
45.0
3.0
1-Dec-97
-
10
32.0
21.0
ND
12.0
36.0
4.0
--
20-May-98
-
10
15.0
16.0
2.0
9.0
100
3.0
19-Nov-98
--
10
21.0
16.0
2.0
7.0
180
3.0
--
--
21-Jul-99
10
ND
16.0
ND
ND
100
ND
16-Nov-99
--
10
ND
15.0
ND
ND
38.0
ND
--
--
10-May-00
10
ND
17.0
ND
ND
61.0
ND
26-Oct-00
--
10
ND
15.0
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
27.0
ND
ND
74.0
ND
27-Oct-01
-
10
ND
12.0
ND
ND
47.0
ND
--
--
13-Jun-02
-
10
ND
14.0
ND
ND
251
ND
19-Nov-02
--
10
ND
10.0
ND
ND
57.0
ND
--
--
27-Jun-03
10
ND
15.0
ND
ND
75.0
ND
30-Dec-03
--
10
ND
17.0
ND
ND
52.0
ND
---
ND
30-Jun-04
10
ND
16.0
ND
ND
31.0
ND
-
ND
29-Dec-04
10
ND
11.0
ND
ND
46.0
ND
-
ND
29-Jun-05
--
10
ND
11.0
ND
ND
43.0
ND
--
ND
29-Dec-05
--
10
ND
12.0
ND
ND
30.0
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
72.5
ND
-
ND
29-Dec-06
-
10
ND
11.4
ND
ND
37.5
ND
---
ND
12-Jul-07
10
ND
11.8
ND
2.7
58.4
ND
ND
IMAC = 70 pg/L (10/23/07)
19-Dec-07
--
10
2.5 B
ND
ND
2.0 B
103
2.6 B
8.0 B
1.8 J
8-Jul-08
-
10
10.3 B
12.1 B
2.0 B
9.0 B
130
4.8 B
--
6.2 J
17-Dec-08
0.60
10.0
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
2.5 J
9-Jul-09
0.60
10.0
ND
6.2 J
ND
ND
100
ND
2.2 J
ND
16-Dec-09
0.60
10.0
ND
4.7 J
ND
ND
6.6 J
ND
--
ND
24-Jun-10
0.60
10.0
ND
16.3
ND
ND
25.0
ND
ND
IMAC = 1 pg/L (2/05/10)
13-Dec-10
0.60
10.0
2.5 B
15.5
ND
ND
(129)
{ND}
-
1.6 [1.0 J) J
20-Jun-11
5.0
10.0
ND
14.2
ND
ND
81.8
ND
-
ND
5-Dec-11
5.0
10.0
ND
12.7
ND
ND
146
ND
--
ND
Resample >
25-Jan-12
5.0
10.0
-
-
-
-
47.5
-
-
ND
11-Jun-12
5.0
10.0
ND
14.2
ND
ND
101
ND
ND
ND
12-Dec-12
5.0
10.0
ND
11.3
ND
ND
113
ND
ND
1-May-13
5.0
10.0
ND
24.3
ND
ND
34.0
ND
ND
ND
5-Aug-13
5.0
10.0
ND
24.7
ND
ND
50.9
ND
ND
24-Feb-14
5.0
10.0
ND
18.4
ND
ND
9.6 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
9.4 J
ND
ND
46.3
ND
-
ND
10-Mar-15
2.5
10.0
ND
8.7 J
ND
ND
39.2
ND
-
ND
18-Aug-15
2.5
10.0
ND
9.3 J
ND
ND
116
ND
ND
16-Feb-16
2.5
10.0
ND
10.0
ND
ND
13.1
ND
--
ND
9-Aug-16
2.5
10.0
ND
10.0 J
ND
ND
144
ND
ND
13-Feb-17
2.5
10.0
ND
8.3 J
ND
ND
78.7
ND
--
ND
22-Aug-17
2.5
10.0
ND
7.4 J
ND
ND
51.1
ND
-
ND
5-Feb-18
2.5
10.0
ND
8.3 J
ND
ND
172
ND
--
ND
13-Aug-18
2.5
10.0
ND
10.7
ND
ND
98
ND
-
ND
4-Feb-19
2.5
5.0
ND
9.9
ND
ND
24
ND
--
ND
7-Aug-19
1.1
5.0
ND
11.3
ND
ND
127
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Copper
8-Sep-94
-
200
ND
ND
ND
ND
ND
660
--
---
1-Dec-94
-
200
ND
ND
ND
ND
ND
ND
9-Feb-95
-
200
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
200
ND
ND
ND
ND
ND
ND
15-Nov-95
--
200
ND
ND
ND
ND
ND
ND
--
--
28-May-96
200
ND
ND
ND
ND
ND
ND
22-Nov-96
--
200
ND
ND
32.0
13.0
100
ND
--
17-Jun-97
200
34.0
350
13.0
37.0
28.0
77.0
1-Dec-97
--
200
19.0
72.0
14.0
88.0
15.0
34.0
--
20-May-98
200
12.0
48.0
380
41.0
53.0
28.0
19-Nov-98
--
200
10.0
ND
410
28.0
53.0
14.0
--
--
21-Jul-99
200
ND
ND
ND
ND
ND
ND
16-Nov-99
--
200
ND
ND
ND
ND
ND
ND
--
--
10-May-00
200
ND
ND
ND
ND
ND
ND
26-Oct-00
--
200
ND
ND
ND
ND
ND
ND
---
--
18-Apr-01
200
ND
ND
ND
ND
ND
ND
27-Oct-01
--
200
ND
ND
ND
ND
ND
ND
---
--
13-Jun-02
200
ND
ND
ND
ND
ND
ND
19-Nov-02
--
200
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
200
ND
ND
ND
ND
ND
ND
30-Dec-03
--
200
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
200
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
200
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
--
200
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
200
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
200
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
10
ND
ND
11.3
5.50 J
10.4
1.90 B
0.60 J
12-Jul-07
-
10
ND
ND
13.4
7.90
2.6 J
ND
ND
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
-
10
2.0 B
ND
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
9.8
8-Jul-08
-
10
0.64 J
ND
12.1
3.7 J
8.5 J
ND
--
ND
17-Dec-08
0.30
10.0
0.80 J
13.6
10.2
3.9 J
11.9
0.37 J
--
ND
9-Jul-09
0.30
10.0
ND
ND
6.3 J
ND
5.7 J
ND
8.8 J
ND
16-Dec-09
0.30
10.0
ND
ND
9.2 J
1.6 J
5.7 J
ND
--
ND
24-Jun-10
0.30
10.0
ND
ND
10
1.2 J
5.1 J
ND
ND
13-Dec-10
0.30
10.0
1.1 B
ND
13.6
5.8 J
5.6 J
0.59 B
0.49 J
20-Jun-11
5.0
10.0
ND
ND
15.3
8.1 J
8.7 J
ND
ND
5-Dec-11
5.0
10.0
ND
ND
16.9
10.0 J
7.6 J
ND
ND
11-Jun-12
5.0
10.0
ND
10.7
12.2
6.3 J
7.4 J
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
11.6
8.5 J
10.4
ND
ND
1-May-13
5.0
10.0
ND
ND
13.6
5.8 J
9.6 J
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
14.3
ND
10.2
ND
ND
24-Feb-14
5.0
10.0
ND
ND
12.2
ND
5.1 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
10.5
ND
ND
ND
ND
10-Mar-15
2.5
10.0
ND
ND
8.7 J
ND
15.5
ND
ND
18-Aug-15
2.5
10.0
ND
ND
6.7 J
5.6 J
10.1
ND
ND
NC 2L = 50 pg/L (06/01/2016)
16-Feb-16
2.5
10.0
ND
ND
7.8 J
ND
5.1 J
ND
ND
9-Aug-16
2.5
10.0
ND
ND
5.4 J
ND
7.8 J
ND
--
ND
13-Feb-17
2.5
10.0
ND
ND
6.8 J
4.3 J
14.5
9.4 J
ND
22-Aug-17
2.5
10.0
ND
ND
6.5 J
ND
5.7 J
4.4 J
--
ND
5-Feb-18
2.5
10.0
ND
6.5 J
9.0 J
5.5 J
12.4
2.6 J
ND
13-Aug-18
2.5
10.0
ND
5.5 J
12.2
3.7 J
48.8
ND
-
ND
4-Feb-19
2.5
5.0
ND
3.0 J
5.4
8.0
4.3 J
ND
-
ND
7-Aug-19
2.1
5.0
ND
3.5 J
6.0
7.2
4.4 J
2.3 J
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Lead
8-Sep-94
-
10
ND
13.0
ND
ND
30.0
36.0
--
1-Dec-94
-
10
11.0
ND
ND
ND
36.0
ND
9-Feb-95
-
10
ND
ND
ND
10.0
37.0
ND
--
--
2-Mar-95
-
10
ND
ND
ND
ND
44.0
ND
15-Nov-95
-
10
ND
ND
ND
ND
ND
ND
--
--
28-May-96
10
ND
ND
ND
ND
42.0
ND
22-Nov-96
--
10
ND
ND
ND
ND
13.0
ND
--
--
17-Jun-97
10
20.0
29.0
ND
ND
13.0
ND
1-Dec-97
-
10
8.0
14.0
ND
5.0
14.0
ND
--
--
20-May-98
-
10
ND
6.0
ND
6.0
21.0
ND
19-Nov-98
-
10
5.0
ND
ND
ND
58.0
ND
--
--
21-Jul-99
-
10
ND
12.0
14.0
ND
ND
ND
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
-
10
11.0
ND
ND
ND
ND
ND
19-Nov-02
--
10
ND
ND
ND
ND
12.0
ND
---
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
10
ND
ND
ND
ND
ND
2.1 J
---
ND
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 15 pg/L (10/23/07)
19-Dec-07
-
10
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
10
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
9-Jul-09
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
4.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
4.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
ND
5.1 J
ND
ND
ND
ND
--
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
2.5
10.0
ND
2.8 J
ND
ND
ND
ND
--
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
4.6 J
ND
--
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
ND
7-Aug-19
1.6
5.0
ND
2.0 J
ND
ND
ND
ND
-
ND
Mercury
1-Dec-97
-
0.5
ND
ND
ND
ND
ND
ND
-
---
19-Nov-98
-
0.5
ND
ND
ND
ND
ND
ND
16-Nov-99
-
0.5
ND
0.59
0.65
0.65
0.76
ND
--
10-May-00
0.5
-
ND
ND
ND
ND
-
26-Oct-00
--
0.5
-
ND
ND
ND
ND
--
--
-
18-Apr-01
0.5
-
ND
ND
ND
ND
-
13-Jun-02
--
0.5
-
ND
ND
ND
ND
-
--
--
27-Jun-03
0.5
-
ND
ND
ND
ND
-
--
30-Dec-03
--
0.5
-
-
-
-
-
-
-
-
30-Jun-04
0.5
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
--
---
---
-
29-Jun-05
--
0.5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
--
-
-
28-Jun-06
2.0
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
--
-
-
-
-
-
--
-
12-Jul-07
-
0.2
ND
ND
ND
ND
ND
ND
-
ND
NC 2L = 1.05 pg/L (10/23/07)
19-Dec-07
-
-
-
-
-
-
-
ND
-
8-Jul-08
-
0.2
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
-
-
-
-
-
-
-
-
-
9-Jul-09
0.070
0.2
ND
ND
ND
ND
ND
ND
-
ND
16-Dec-09
-
-
-
-
-
-
-
-
-
NC 21 1 pg/L (02/05/10)
24-Jun-10
0.070
0.20
ND
ND
ND
ND
ND
0.098 J
ND
13-Dec-10
-
-
-
-
-
-
-
-
20-Jun-11
0.10
0.20
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
-
---
---
-
-
-
-
-
-
-
1-May-13
0.10
0.20
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
-
-
-
-
24-Feb-14
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
-
-
-
-
10-Mar-15
0.10
0.20
ND
ND
ND
-
-
-
ND
16-Feb-16
0.10
0.20
ND
ND
ND
-
-
--
ND
13-Feb-17
0.10
0.20
ND
ND
ND
-
-
ND
22-Aug-17
0.10
0.20
ND
ND
ND
-
-
--
--
ND
5-Feb-18
0.10
0.20
ND
ND
ND
-
-
ND
4-Feb-A
0.10
0.20
ND
ND
ND
-
-
--
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 9 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Nickel
8-Sep-94
-
50
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
50
ND
ND
ND
ND
ND
ND
9-Feb-95
-
50
ND
72
ND
ND
ND
ND
---
--
2-Mar-95
-
50
ND
100
ND
ND
ND
ND
15-Nov-95
-
50
ND
61.0
ND
ND
ND
ND
---
--
28-May-96
50
ND
85.0
ND
ND
ND
ND
22-Nov-96
--
50
ND
72.0
ND
ND
ND
ND
--
--
17-Jun-97
50
75
98.0
ND
ND
ND
ND
1-Dec-97
--
50
ND
89.0
ND
ND
ND
ND
--
--
20-May-98
50
ND
91.0
ND
ND
ND
ND
19-Nov-98
--
50
ND
83.0
ND
ND
ND
ND
--
--
21-Jul-99
50
ND
109
ND
ND
ND
ND
16-Nov-99
--
50
ND
122
ND
ND
ND
ND
--
--
10-May-00
50
ND
104
ND
ND
ND
ND
26-Oct-00
--
50
ND
93.0
ND
ND
ND
ND
--
--
18-Apr-01
50
ND
107
ND
ND
ND
ND
27-Oct-01
--
50
ND
92.0
ND
ND
ND
ND
--
--
13-Jun-02
50
ND
98.0
ND
ND
ND
ND
19-Nov-02
--
50
ND
74.0
ND
ND
ND
ND
--
--
27-Jun-03
50
ND
85.0
ND
ND
ND
ND
--
30-Dec-03
--
50
ND
100
ND
ND
ND
ND
---
ND
30-Jun-04
50
ND
120 (81.0)
ND
ND
ND
ND
-
ND
29-Dec-04
-
50
ND
100
ND
ND
ND
ND
-
ND
29-Jun-05
-
50
ND
150
ND
ND
ND
ND
--
ND
29-Dec-05
-
50
ND
96.0
ND
ND
ND
ND
-
ND
28-Jun-06
-
50
ND
88.7
ND
ND
ND
ND
-
ND
29-Dec-06
-
50
ND
94.7
30.1
14.2
8.9 J
ND
ND
12-Jul-07
-
50
ND
99.0
30.6 J
13.9 J
13.7 J
ND
--
ND
NC 2L = 100 pg/L (10/23/07)
19-Dec-07
-
50
ND
83.4
23.7
11.0
18.3
ND
11.4
ND
8-Jul-08
-
50
ND
76.0
28.1 J
11.5 J
27.0 J
ND
--
ND
17-Dec-08
1.7
50.0
ND
75.5
27.8 J
12.2 J
11.0 B
ND
--
2.4 J
9-Jul-09
1.7
50.0
2.2 J
93.5
29.4 J
11.7 J
23.2 J
ND
13.1 J
ND
16-Dec-09
1.7
50.0
ND
81.2
28.2 J
11.8 B
2.6 B
ND
-
3.0 J
24-Jun-10
1.7
50.0
ND
76.3
19.7 J
9.0 J
7.0 J
4.5 J
-
ND
13-Dec-10
1.7
50.0
ND
83.0
23.5 J
6.8 B
20.7 J
ND
2.7 J
20-Jun-11
5.0
50.0
ND
78.8
30.1 J
11.2 J
15.3 J
ND
ND
5-Dec-11
5.0
50.0
ND
89.1
32.8 J
11.7 J
24.3 J
ND
ND
11-Jun-12
5.0
50.0
ND
91.8
28.9 J
10.0 J
17.3 J
ND
ND
ND
12-Dec-12
5.0
50.0
ND
91.8
29.2 J
9.3 J
21.1 J
ND
ND
1-May-13
5.0
50.0
ND
89.6
31.9 J
10.4 J
5.7 J
ND
ND
ND
5-Aug-13
5.0
50.0
ND
87.9
28.1 J
9.0 J
8.4 J
ND
ND
24-Feb-14
5.0
50.0
ND
83.1
16.7 J
10.4 J
ND
ND
ND
ND
12-Aug-14
5.0
50.0
ND
97.9
29 J
12.9 J
13.2 J
ND
ND
10-Mar-15
2.5
50.0
ND
91.9
32.9 J
12.3 J
8.2 J
ND
ND
18-Aug-15
2.5
50.0
ND
98.0
28.0 J
11.9 J
26.2 J
5.4 J
--
ND
16-Feb-16
2.5
50.0
ND
92.0
35.4 J
12.7 J
3.7 J
ND
ND
9-Aug-16
2.5
50.0
3.3 J
88.9
29.0 J
12.2 J
30.7 J
ND
--
ND
13-Feb-17
2.5
50.0
ND
89.6
30.4 J
13.5 J
16.2 J
ND
ND
22-Aug-17
2.5
50.0
ND
84.2
28.2 J
12.3 J
13.5 J
ND
--
ND
5-Feb-18
2.5
50.0
ND
87.6
29.8 J
11.7 J
28.5 J
ND
ND
13-Aug-18
2.5
50.0
ND
88.9
29.0 J
12.3 J
21.9 J
ND
-
ND
4-Feb-19
2.5
5.0
ND
85.7
17.4
10.7
5.5
ND
-
ND
7-Aug-19
0.90
5.0
ND
92.6
27.8
11.7
18.7
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 10 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Selenium
8-Sep-94
---
20
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
20
ND
ND
ND
ND
ND
ND
9-Feb-95
-
20
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
20
ND
ND
ND
ND
ND
ND
15-Nov-95
--
20
ND
ND
ND
ND
ND
ND
--
--
28-May-96
20
ND
ND
ND
ND
ND
ND
22-Nov-96
--
20
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
20
ND
ND
ND
ND
ND
ND
1-Dec-97
--
20
ND
ND
ND
ND
ND
ND
--
--
20-May-98
20
ND
ND
ND
ND
ND
ND
19-Nov-98
--
20
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
20
ND
ND
ND
ND
36.0
ND
16-Nov-99
--
20
ND
ND
ND
ND
ND
ND
--
--
10-May-00
20
ND
ND
ND
ND
ND
ND
26-Oct-00
--
20
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
20
ND
ND
ND
ND
ND
ND
27-Oct-01
-
20
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
20
ND
ND
ND
ND
ND
ND
19-Nov-02
--
20
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
20
ND
ND
ND
ND
ND
ND
30-Dec-03
--
20
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
20
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
20
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
20
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
20
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
20
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
--
10
ND
11.5
ND
ND
ND
ND
ND
ND
8-Jul-08
-
10
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
3.8
10
4.8 B
5.1 B
4.8 B
ND
ND
ND
4.9 J
9-Jul-09
3.8
10
ND
ND
4.2 J
ND
ND
ND
ND
ND
16-Dec-09
3.8
10
ND
ND
ND
5.1 J
ND
ND
--
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
3.8
10
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
3.8
10
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
10.0
10
ND
ND
ND
ND
ND
ND
ND
5-Dec-11
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
16-Feb-16
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
7-Aug-19
4.7
10.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 11 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Silver
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
10
ND
ND
ND
ND
ND
ND
9-Feb-95
-
10
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
10
ND
ND
ND
ND
ND
ND
15-Nov-95
--
10
ND
ND
ND
ND
ND
ND
--
--
28-May-96
10
ND
ND
ND
ND
ND
ND
22-Nov-96
--
10
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
10
ND
ND
ND
ND
ND
ND
1-Dec-97
--
10
ND
8.0
ND
ND
ND
3.0
--
--
20-May-98
10
ND
ND
ND
ND
ND
ND
19-Nov-98
---
10
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
15.0
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
10
ND
ND
ND
ND
ND
ND
19-Nov-02
--
10
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
---
10
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
10
ND
ND
ND
ND
ND
ND
--
ND
NC 2L = 17.5 pg/L (10/23/07)
19-Dec-07
--
10
ND
0.57 J
0.60 J
0.55 J
ND
0.33 J
ND
ND
8-Jul-08
-
10
ND
2.7 J
2.3 J
1.1 J
0.22 J
0.69 J
-
0.12 J
17-Dec-08
0.10
10.0
0.13 J
1.8 J
1.4 J
0.85 J
0.12 J
0.51 J
-
ND
9-Jul-09
0.10
10.0
ND
0.84 J
0.63 J
0.45 J
ND
0.11 J
ND
ND
16-Dec-09
0.10
10.0
0.12 J
2.0 J
1.6 J
1.0 J
0.12 J
0.52 J
-
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.10
10.0
ND
0.38 J
0.33 J
0.35 J
ND
ND
-
ND
13-Dec-10
0.10
10.0
0.15 B
1.3 J
0.99 J
0.45 B
fND}
fND}
-
0.21(0.19 J J
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
--
ND
13-Feb-17
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
7-Aug-19
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 12 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Thallium
8-Sep-94
---
10
ND
ND
ND
ND
ND
ND
---
---
1-Dec-94
-
10
ND
ND
ND
ND
ND
ND
9-Feb-95
-
10
ND
ND
ND
ND
ND
ND
--
--
2-Mar-95
10
ND
ND
ND
ND
ND
ND
15-Nov-95
--
10
ND
ND
ND
ND
ND
ND
--
--
28-May-96
10
ND
ND
ND
ND
ND
ND
22-Nov-96
--
10
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
10
ND
3.0
ND
ND
ND
ND
1-Dec-97
-
10
ND
ND
ND
ND
ND
ND
--
--
20-May-98
-
10
ND
ND
ND
ND
ND
ND
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
10
ND
ND
ND
ND
ND
ND
19-Nov-02
--
10
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
10
ND
10 J
ND
ND
ND
ND
--
ND
29-Jun-05
--
10
ND
22.0
13.0
ND
ND
ND
ND
29-Dec-05
--
10
ND
23.0
20.0
ND
ND
ND
ND
28-Jun-06
-
10
ND
25.7
12.6
ND
ND
ND
-
ND
29-Dec-06
---
6
ND
ND
ND
ND
ND
ND
--
ND
12-Jul-07
5.5
ND
ND
ND
ND
ND
ND
-
ND
IMAC = 0.28 p9/L (10/23/07)
19-Dec-07
--
5.5
ND
4.0 J
ND
ND
ND
ND
ND
ND
8-Jul-08
-
5.5
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
3.0
5.5
ND
3.2 J
3.2 J
ND
ND
ND
--
ND
9-Jul-09
3.0
5.5
ND
ND
ND
4.1 J
ND
ND
ND
ND
16-Dec-09
3.0
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
3.0
5.5
ND
ND
5.2 J
3.1 J
ND
ND
-
ND
IMAC = 0.2 p9/L (10/1/10)
13-Dec-10
3.0
5.5
ND
ND
7.7
ND
ND
ND
--
ND
20-Jun-11
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
5-Dec-11
5.4
5.5
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.4
5.5
ND
ND
ND
ND
ND
ND
---
ND
10-Mar-15
5.0
5.5
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
5.0
5.5
ND
ND
ND
ND
ND
ND
--
ND
16-Feb-16
5.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
5.0
5.5
ND
ND
ND
ND
ND
ND
--
ND
13-Feb-17
0.02
5.5
0.023 J
0.040 J
ND
ND
0.035 J
ND
-
ND
22-Aug-17
0.02
5.5
ND
ND
ND
ND
0.033 J
ND
-
ND
5-Feb-18
0.03
0.1
ND
ND
ND
ND
0.047 J
ND
-
ND
13-Aug-18
0.02
5.5
ND
ND
ND
ND
0.037 J
ND
-
ND
4-Feb-19
0.06
0.1
ND
ND
ND
ND
ND
ND
-
ND
7-Aug-19
0.060
0.10
ND
ND
ND
ND
ND
ND
-
ND
Tin
1-Dec-97
-
100
ND
ND
ND
ND
ND
ND
-
---
19-Nov-98
-
100
ND
ND
ND
ND
ND
ND
-
16-Nov-99
---
100
ND
ND
ND
ND
ND
ND
---
--
26-Oct-00
100
-
ND
ND
ND
ND
-
-
18-Apr-01
--
100
-
ND
ND
ND
ND
-
--
-
27-Oct-01
100
-
-
-
-
-
-
13-Jun-02
--
100
ND
ND
ND
ND
ND
ND
--
--
19-Nov-02
-
100
-
-
-
-
-
-
27-Jun-03
-
100
ND
149
127
ND
ND
ND
--
-
30-Dec-03
-
100
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
--
100
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
--
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
100
ND
ND
ND
ND
ND
ND
ND
29-Dec-05
--
100
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
--
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
100
ND
41.1
14.4
3.2 J
ND
ND
ND
12-Jul-07
--
100
ND
35.2 J
13.9 J
5.2 J
ND
ND
--
ND
19-Dec-07
-
100
ND
33.6
7.4
ND
ND
ND
ND
ND
8-Jul-08
-
100
4.4 J
28.6 J
15.1 J
5.4 J
3.0 J
3.6 J
-
ND
17-Dec-08
1.8
100
ND
22.5 J
9.2 J
ND
ND
ND
ND
9-Jul-09
1.8
100
ND
21.4 J
8.6 J
ND
ND
ND
--
ND
16-Dec-09
1.8
100
ND
26.3 J
10.7 J
ND
ND
ND
ND
IMAC = 2100 p9/L (02/05/10)
24-Jun-10
1.8
100
ND
23.4 J
10.7 J
3.2 J
2.2 J
1.9 J
-
ND
13-Dec-10
1.8
100
ND
30.3 J
12.1 J
5.8 J
ND
ND
ND
20-Jun-11
5.0
100
ND
26.8 J
13.8 J
ND
ND
ND
--
ND
5-Dec-11
5.0
100
ND
25.8 J
13.9 J
ND
ND
ND
ND
11-Jun-12
5.0
100
ND
22.2 J
9.0 J
ND
ND
ND
ND
ND
12-Dec-12
5.0
100
ND
30.0 J
13.2 J
ND
ND
ND
ND
1-May-13
5.0
100
ND
25.8 J
12.2 J
ND
ND
ND
ND
5-Aug-13
5.0
100
ND
22.7 J
12.5 J
ND
ND
ND
ND
24-Feb-14
5.0
100
ND
26.7 J
11.7 J
9.8 J
ND
ND
ND
ND
12-Aug-14
5.0
100
ND
30.7 J
8.2 J
ND
ND
ND
ND
10-Mar-15
2.5
100
ND
28.7 J
11.1 J
ND
ND
ND
ND
18-Aug-15
2.5
100
ND
27.7 J
7.5 J
ND
ND
ND
ND
16-Feb-16
2.5
100
ND
28.6 J
10.4 J
-
-
-
--
ND
9-Aug-16
2.5
100
ND
20.9 J
5.4 J
-
-
ND
13-Feb-17
2.5
100
ND
25.5 B
7.8 B
-
-
--
--
3.6 J,
22-Aug-17
2.5
100
ND
17.2 J
5.3 J
-
-
ND
5-Feb-18
2.5
100
ND
20.3 J
9.5 J
-
-
--
ND
13-Aug-18
2.5
100
ND
22.2 J
7.4 J
-
-
ND
ND
4-Feb-19
2.5
5.0
ND
24.8
5.5
-
-
--
--
ND
7-Aug-19
1.6
5.0
ND
29.3
9.7
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 13 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vanadium
8-Sep-94
---
40
ND
ND
ND
ND
ND
130
---
---
1-Dec-94
-
40
63.0
ND
ND
45.0
ND
ND
9-Feb-95
-
40
ND
ND
ND
ND
ND
ND
---
--
2-Mar-95
-
40
41.0
ND
ND
45.0
ND
ND
--
15-Nov-95
-
40
ND
ND
ND
ND
ND
ND
---
--
28-May-96
40
83.0
ND
ND
ND
ND
ND
22-Nov-96
--
40
7.0
17
ND
21.0
ND
ND
--
--
17-Jun-97
40
450
560
ND
19.0
ND
ND
1-Dec-97
--
40
62.0
88.0
ND
41.0
ND
10.0
--
--
20-May-98
40
25.0
15.0
ND
10.0
5.0
ND
19-Nov-98
--
40
33.0
29.0
5.0
16.0
9.0
5.0
--
--
21-Jul-99
40
ND
ND
ND
ND
ND
ND
16-Nov-99
--
40
ND
ND
ND
ND
ND
ND
--
--
10-May-00
40
ND
ND
ND
ND
ND
ND
26-Oct-00
--
40
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
40
ND
ND
ND
ND
ND
ND
27-Oct-01
-
40
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
40
ND
ND
ND
ND
ND
ND
19-Nov-02
--
40
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
40
ND
ND
ND
ND
ND
ND
30-Dec-03
--
40
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
40
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
40
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
--
40
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
40
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
40
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
--
25
2.7 J
ND
ND
14.5
ND
1.0 J
--
ND
12-Jul-07
25
ND
ND
ND
19.4 J
ND
ND
ND
IMAC = 3.5 Ug/L (10/23/07)
19-Dec-07
--
25
2.2 B
2.2 B
ND
15.7 J
3.0 B
1.2 B
4.0 J
0.62 J
8-Jul-08
-
25
2.6 J
2.4 J
ND
14.6 J
1.4 J
1.2 J
0.20 J
17-Dec-08
0.20
25.0
1.9 B
2.3 B
ND
13.9 J
2.5 B
1.2 B
0.76 J
9-Jul-09
0.20
25.0
3.9 B
9.7 J
2.5 B
18.4 J
2.9 B
2.2 B
8.5 J
1.30 J
16-Dec-09
0.20
25.0
2.0 B
4.4 J
1.3 B
14.0 J
2.2 B
1.5 B
-
0.53 J
24-Jun-10
0.20
25.0
1.8 J
4.4 J
1.5 J
13.3 J
2.2 J
1.3 J
-
ND
IMAC = 0.3 Ug/L (10/1/10)
13-Dec-10
0.20
25.0
3.2 J
3.6 J
0.35 B
16.6 J
1.8 B
1.0 B
0.36 J
20-Jun-11
5.0
25.0
ND
ND
ND
14.5 J
ND
ND
ND
5-Dec-11
5.0
25.0
ND
ND
ND
13.5 J
ND
ND
---
ND
11-Jun-12
5.0
25.0
ND
18.0 J
ND
12.3 J
ND
ND
ND
ND
12-Dec-12
5.0
25.0
ND
ND
ND
13.6 J
ND
ND
ND
1-May-13
5.0
25.0
ND
ND
ND
6.3 J
ND
ND
ND
ND
5-Aug-13
5.0
25.0
ND
ND
ND
10.2 J
ND
ND
ND
24-Feb-14
5.0
25.0
ND
ND
ND
12.9 J
ND
ND
ND
ND
12-Aug-14
5.0
25.0
ND
ND
ND
18.6 J
ND
ND
ND
10-Mar-15
2.5
25.0
3.1 J
11.6 J
6.2 J
13.4 J
ND
ND
ND
18-Aug-15
2.5
25.0
3.4 J
6.8 J
3.6 J
19.6 J
2.8 J
ND
ND
16-Feb-16
2.5
25.0
2.7 J
3.3 J
ND
14.4 J
ND
ND
ND
9-Aug-16
2.5
25.0
2.5 J
3.5 J
ND
21.2 J
ND
ND
--
ND
13-Feb-17
2.5
25.0
4.4 J
4.1 J
ND
18.4 J
3.0 J
2.9 J
ND
22-Aug-17
2.5
25.0
ND
6.6 J
ND
20.6 J
2.6 J
ND
--
ND
5-Feb-18
2.5
25.0
3.6 J
4.4 J
ND
17.6 J
ND
2.5 J
ND
13-Aug-18
2.5
25.0
ND
5.3 J
ND
20.4 J
2.9 J
ND
-
ND
4-Feb-19
2.5
5.0
ND
3.5 J
ND
12
ND
ND
-
ND
7-Aug-19
1.3
5.0
2.6 J
4.1 J
1.9 J
22.1
1.7 J
2.4 J
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 14 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Zinc
8-Sep-94
-
50
110
160
ND
ND
320
430
1-Dec-94
-
50
132
ND
ND
70
164
ND
--
9-Feb-95
-
50
144
89
ND
91
79
74
--
2-Mar-95
-
50
67
ND
ND
ND
111
ND
--
15-Nov-95
-
50
ND
50
ND
ND
ND
ND
---
--
28-May-96
50
136
ND
ND
ND
122
ND
22-Nov-96
--
50
79.0
48.0
28.0
ND
38.0
ND
--
17-Jun-97
50
370
410
33.0
39.0
36.0
69.0
1-Dec-97
--
50
140
110
11.0
45.0
34.0
30.0
20-May-98
50
70.0
63.0
23.0
31.0
47.0
34.0
19-Nov-98
--
50
61.0
33.0
21.0
17.0
53.0
10.0
--
--
21-Jul-99
50
ND
ND
ND
ND
ND
ND
16-Nov-99
--
50
ND
ND
ND
ND
ND
ND
--
--
10-May-00
50
ND
ND
ND
ND
ND
ND
26-Oct-00
--
50
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
50
ND
ND
ND
ND
ND
ND
27-Oct-01
--
50
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
50
ND
ND
ND
ND
382
ND
19-Nov-02
--
50
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
50
ND
ND
ND
ND
ND
ND
30-Dec-03
--
50
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
50
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
50
ND
ND
ND
66.0
ND
ND
--
ND
29-Jun-05
-
50
ND
54.0
56.0
ND
ND
ND
ND
29-Dec-05
-
50
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
50
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
50
8.0 J
ND
ND
4.1 J
4.3 J
4.1 J
--
ND
12-Jul-07
-
10
9.6 J
ND
ND
ND
ND
ND
-
ND
INC 2L = 1,050 pg/L (10/23/07)
19-Dec-07
-
10
4.3 B
14.3 B
6.3 B
ND
ND
ND
2.4 B
102
8-Jul-08
-
10
5.9 B
ND
ND
ND
4.1 B
ND
1.2 J
17-Dec-08
0.40
10.0
2.4 B
6.3 J
ND
ND
4.6 J
0.60 B
0.49 J
9-Jul-09
0.40
10.0
3.4 B
ND
ND
ND
ND
ND
6.1 B
1.6 J
16-Dec-09
0.40
10.0
4.6 B
ND
ND
ND
7.4 B
ND
7.7 J
NC 2L - 1,000 pg/L (02/05/10)
24-Jun-10
0.40
10.0
0.58 J
ND
ND
ND
ND
1.3 J
-
ND
13-Dec-10
0.40
10.0
4.5 B
ND
ND
ND
ND
ND
-
6.7 J
20-Jun-11
10.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
10.0
10.0
ND
ND
ND
ND
ND
ND
-
12.4
11-Jun-12
10.0
10.0
ND
20.9
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
1-May-13
10.0
10.0
ND
ND
ND
ND
11.8
ND
10.0
ND
5-Aug-13
10.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
10.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10.0
ND
ND
ND
ND
16.9
ND
-
ND
18-Aug-15
5.0
10.0
7.4 J
ND
ND
ND
5.2 1
ND
ND
16-Feb-16
5.0
10.0
14.5
16.7
17.8
46.1
5.9 J
ND
--
ND
9-Aug-16
5.0
10.0
12.0
7.7 J
ND
ND
ND
ND
ND
13-Feb-17
5.0
10.0
12.3
ND
ND
ND
9.8 J
6.0 J
--
ND
22-Aug-17
5.0
10.0
ND
6.3 J
ND
ND
ND
ND
ND
5-Feb-18
5.0
10.0
6.7 J
17.9
ND
ND
ND
ND
--
ND
13-Aug-18
5.0
10.0
ND
ND
ND
ND
8.1 J
ND
ND
4-Feb-19
5.0
10.0
6.8 J
ND
5.0 J
ND
ND
ND
--
ND
7-Aug-19
3.9
10.0
8.3 J
ND
ND
ND
ND
ND
ND
Iron
4-Feb-19
25.0
50.0
230
9,420
184.0
-
---
---
---
---
NC 2L = 300 pFVL 2017
Manganese
4-Feb-19
2.5
5.0
121
7,640
51.8
---
---
---
---
---
NC 2L = 50 pFVL 2017
Cyanide
9-Jul-09
5.0
10
ND
ND
ND
ND
46.9
ND
ND
ND
Resample >
28-Sep-09
5.0
10
-
-
-
---
ND
-
--
ND
NC 2L = 70 pg/L (10/23/07)
16-Dec-09
-
-
-
-
-
-
-
-
24-Jun-10
5.0
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
-
-
-
-
-
-
-
--
-
Resample >
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
5.0
10.0
ND
6.4 J
ND
ND
8.7 J
ND
--
ND
12-Dec-12
-
-
-
-
-
-
-
-
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
-
-
-
-
-
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5.5 J
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
5.0
10.0
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
5.6 J
16-Feb-16
4.0
10.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
4.0
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
4.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
4.0
10.0
ND
ND
ND
-
-
-
-
ND
4-Feb-19
6.0
8.0
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 15 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
ORGANICS
Acetone
27-Oct-01
--
100
244 B
109 B
ND
130 B
128 B
476 B
479
13-Jun-02
---
100
ND
ND
ND
ND
ND
ND
---
---
13-Jun-02
100
ND
ND
ND
ND
ND
ND
19-Nov-02
-
100
ND
ND
ND
ND
ND
ND
---
--
27-Jun-03
-
100
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
100
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
-
100
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
100
ND
ND
ND
ND
ND
ND
ND
28-Jun-06
-
100
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
100
ND
ND
ND
ND
ND
ND
---
ND
12-Jul-07
-
100
ND
ND
ND
ND
ND
ND
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
-
100
ND
ND
ND
ND
ND
ND
ND
4.5 J
8-Jul-08
-
100
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
20.0
100
ND
ND
ND
ND
ND
ND
-
ND
9-Jul-09
20.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
2.2
100
ND
ND
ND
ND
ND
ND
-
2.8 J
NC 2L = 6,000 pg/L (02/05/10)
24-Jun-10
2.2
100
ND
18.5 B
6.5 B
ND
2.2 B
ND
-
7.7 J
13-Dec-10
2.2
100
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
2.2
100
ND
ND
ND
ND
ND
2.4 B
--
3.9 J
5-Dec-11
2.2
100
ND
2.3 B
ND
ND
ND
ND
--
8.8 J
11-Jun-12
2.2
100
ND
3.5 B
ND
ND
ND
ND
ND
4.7 J
12-Dec-12
10.0
100
ND
ND
ND
ND
ND
ND
ND
1-May-13
10.0
100
ND
ND
ND
ND
ND
ND
ND
14.6 J
5-Aug-13
10.0
100
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
25.7 J
12-Aug-14
10.0
100
ND
ND
ND
ND
ND
ND
ND
22.0 J
10-Mar-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
10.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
10.0
100
ND
ND
ND
ND
ND
ND
--
ND
13-Feb-17
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
10.0
100
ND
ND
ND
ND
ND
ND
--
ND
5-Feb-18
10.0
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
10.0
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
6.2
25
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for MW-6->
7-Aug-19
6.2
25.0
ND
ND
ND
ND
ND
ND
-
ND
Benzene
8-Sep-94
-
5
ND
ND
ND
ND
ND
ND
-
---
1-Dec-94
-
5
ND
ND
ND
ND
ND
ND
-
9-Feb-95
-
5
ND
ND
ND
ND
ND
ND
---
--
2-Mar-95
-
5
ND
ND
ND
ND
ND
ND
-
15-Nov-95
-
5
ND
ND
ND
ND
ND
ND
--
-
28-May-96
-
5
ND
ND
ND
ND
ND
ND
22-Nov-96
--
5
ND
ND
ND
ND
ND
ND
--
--
17-Jun-97
5
ND
ND
ND
ND
ND
ND
1-Dec-97
-
5
ND
ND
ND
ND
ND
ND
-
--
20-May-98
-
5
ND
ND
ND
ND
ND
ND
19-Nov-98
-
5
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
5
ND
ND
ND
ND
ND
ND
26-Oct-00
---
5
ND
ND
ND
ND
ND
ND
---
--
18-Apr-01
5
ND
ND
ND
ND
ND
ND
-
27-Oct-01
--
5
ND
ND
ND
ND
ND
ND
---
--
13-Jun-02
5
ND
ND
ND
ND
ND
ND
19-Nov-02
--
5
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
5
ND
ND
ND
ND
ND
ND
-
30-Dec-03
--
5
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
5
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
--
3
ND
1.5
ND
ND
ND
ND
---
ND
Resample >
23-Feb-07
3
-
1.2
-
-
-
-
ND
12-Jul-07
--
1
ND
1.9
ND
ND
ND
ND
---
ND
NC 2L = 1 pg/L (10/23/07)
19-Dec-07
-
1
ND
1.8
0.48 J
0.26 J
ND
ND
ND
ND
8-Jul-08
-
1
ND
1.4
0.51 J
0.32 J
ND
ND
ND
17-Dec-08
0.25
1.0
ND
1.7
0.54 J
ND
ND
ND
ND
9-Jul-09
0.25
1.0
ND
1.7
0.34 J
ND
ND
ND
ND
ND
16-Dec-09
0.25
1.0
ND
1.7
0.60 J
0.29 J
ND
ND
ND
24-Jun-10
0.25
1.0
ND
0.77 J
0.49 J
0.33 J
ND
ND
ND
13-Dec-10
0.25
1.0
ND
1.8
0.59 J
0.37 J
ND
ND
ND
Resample >
8-Feb-11
0.25
1.0
-
1.4
-
-
-
-
---
ND
20-Jun-11
0.25
1.0
ND
1.7
0.60 J
0.39 J
ND
ND
ND
5-Dec-11
0.25
1.0
ND
1.4
0.69 J
0.40 J
ND
ND
ND
11-Jun-12
0.25
1.0
ND
ND
0.51 J
ND
ND
ND
ND
ND
12-Dec-12
0.25
1.0
ND
1.6
0.73 J
0.32 J
ND
ND
ND
Resample >
10-Jan-13
0.25
1.0
ND
1.4
-
-
-
-
ND
ND
1-May-13
0.25
1.0
ND
1.3
0.56 J
0.27 J
ND
ND
ND
ND
5-Aug-13
0.25
1.0
ND
1.6
0.64 J
0.44 J
ND
ND
ND
24-Feb-14
0.25
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
12-Aug-14
0.25
1.0
ND
1.7
0.61 J
0.25 J
ND
ND
ND
ND
10-Mar-15
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
18-Aug-15
0.25
1.0
ND
1.5
0.66 J
0.32 J
ND
ND
ND
16-Feb-16
0.25
1.0
ND
1.3
0.56 J
ND
ND
ND
ND
ND
9-Aug-16
0.25
1.0
ND
1.4
0.53 J
0.29 J
ND
ND
ND
ND
13-Feb-17
0.25
1.0
ND
1.2
0.61 J
ND
ND
ND
ND
ND
22-Aug-17
0.25
1.0
ND
1.3
0.54 J
ND
ND
ND
ND
ND
5-Feb-18
0.25
1.0
ND
1.2
0.67 J
ND
ND
ND
ND
ND
13-Aug-18
0.25
1.0
ND
1.3
0.61 J
0.29 J
ND
ND
ND
ND
4-Feb-19
0.15
1.0
ND
1.6
ND
ND
ND
ND
ND
ND
14-Aug-19for Mw-6->
7-Aug-19
0.15
1.0
ND
1.7
0.54 J
0.30 J
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 16 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Bromomethane
17-Dec-08
0.29
10.0
ND
ND
0.58 J
ND
ND
ND
---
ND
9-Jul-09
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
IMAC = 10 pg/L (8/1/10)
13-Dec-10
0.29
10.0
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.29
10.0
ND
ND
ND
ND
ND
ND
--
ND
22-Aug-17
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.62
2.0
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.62
2.0
ND
ND
ND
ND
ND
ND
-
ND
2-Butanone (MEK)
17-Dec-08
0.96
100
ND
ND
ND
ND
1.2 J
ND
-
ND
NC 2L = 4,200 pg/L (10/23/07)
9-Jul-09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
NC 2L = 4,000 pg/L (02/05/10)
24-Jun-10
0.96
100
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
8-May-13
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.96
100
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.96
100
ND
ND
ND
ND
ND
ND
ND
22-Aug-17
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
3.30
5
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
3.3
5.0
ND
ND
ND
ND
ND
ND
-
ND
Carbon Disulfide
17-Jun-97
-
100
ND
64.0
ND
ND
ND
ND
-
-
1-Dec-97
-
100
ND
5.0
8.0
ND
ND
ND
-
-
20-May-98
--
100
ND
7.5
6.2
ND
ND
ND
-
-
19-Nov-98
100
ND
ND
ND
ND
ND
ND
-
-
21-Jul-99
--
100
ND
ND
ND
ND
ND
ND
-
---
16-Nov-99
100
ND
ND
ND
ND
ND
ND
-
10-May-00
--
100
ND
ND
ND
ND
ND
ND
-
--
26-Oct-00
100
ND
ND
ND
ND
ND
ND
-
18-Apr-01
--
100
ND
ND
ND
ND
ND
ND
---
--
27-Oct-01
-
100
ND
ND
ND
ND
ND
ND
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
--
--
19-Nov-02
-
100
ND
ND
ND
ND
ND
ND
27-Jun-03
-
100
ND
ND
ND
ND
ND
ND
--
-
30-Dec-03
100
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
--
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
--
100
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
100
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-05
--
100
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
---
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 700 pg/L (10/23/07)
19-Dec-07
-
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
100
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
9-Jul-09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Dec-10
1.2
100
ND
ND
ND
ND
ND
ND
ND
20-Jun-11
1.2
100
ND
ND
ND
ND
ND
ND
--
ND
5-Dec-11
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
1-May-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.2
100
ND
ND
ND
ND
ND
ND
ND
13-Feb-17
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
22-Aug-17
1.2
100
ND
ND
ND
ND
ND
ND
ND
5-Feb-18
1.2
100
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.4
2
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.40
2.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 17 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chlorobenzene
8-Sep-94
-
5
ND
10.0
7.0
ND
ND
ND
-
--
1-Dec-94
-
5
ND
ND
7.0
ND
ND
ND
9-Feb-95
-
5
ND
13.0
8.0
6.0
ND
ND
--
2-Mar-95
-
5
ND
12.0
9.0
ND
ND
ND
-
15-Nov-95
-
5
ND
14.0
8.0
9.0
ND
ND
-
--
28-May-96
5
ND
15.0
9.0
10.0
ND
ND
22-Nov-96
--
5
ND
15.0
ND
11.0
ND
ND
--
--
17-Jun-97
5
ND
19.0
11.0
14.0
ND
ND
1-Dec-97
--
5
ND
17.0
9.0
14.0
ND
ND
--
--
20-May-98
5
ND
20.0
8.6
12.0
ND
ND
19-Nov-98
--
5
ND
17.2
9.2
10.0
ND
ND
--
--
21-Jul-99
5
ND
14.0
10.0
11.0
ND
ND
16-Nov-99
--
5
ND
16.0
10.0
8.0
ND
ND
--
--
10-May-00
5
ND
17.0
11.0
10.0
ND
ND
26-Oct-00
--
5
ND
16.0
12.0
9.0
ND
ND
--
--
18-Apr-01
5
ND
16.0
13.0
6.0
ND
ND
27-Oct-01
-
0.5
ND
17.0
12.0
9.0
ND
ND
--
--
13-Jun-02
-
0.5
ND
16.0
11.0
8.0
ND
ND
19-Nov-02
-
0.5
ND
18.0
15.0
9.0
ND
ND
--
-
27-Jun-03
-
0.5
ND
17.7
13.3
7.4
ND
ND
ND
30-Dec-03
--
5
ND
20.0
15.0
6.1
ND
ND
--
ND
30-Jun-04
5
ND
18.0
15.0
9.9
ND
ND
ND
29-Dec-04
-
5
ND
19.0
16.0
9.4
ND
ND
ND
29-Jun-05
-
5
ND
15.0
13.0
8.0
ND
ND
ND
29-Dec-05
-
5
ND
18.0
16.0
5.0
ND
ND
ND
28-Jun-06
-
5
ND
16.5
10.8
7.8
ND
ND
ND
29-Dec-06
-
3
ND
17.0
17.0
4.2
ND
ND
---
ND
12-Jul-07
-
3
ND
17.0
16.0
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
19-Dec-07
-
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
8-Jul-08
-
3
ND
17.2
17.4
6.5
ND
ND
ND
17-Dec-08
0.23
3.0
ND
15.9
15.6
2.6 J
ND
ND
---
ND
9-Jul-09
0.23
3.0
ND
16.1
17.2
6.1
ND
ND
ND
ND
16-Dec-09
0.23
3.0
ND
15.5
17.7
4.8
ND
ND
---
ND
24-Jun-10
0.23
3.0
ND
8.3
15.7
6.3
ND
ND
--
ND
13-Dec-10
0.23
3.0
ND
17.7
18.2
6.4
ND
ND
---
0.28 J
20-Jun-11
0.23
3.0
ND
16.3
17.2
6.7
ND
ND
ND
5-Dec-11
0.23
3.0
ND
14.2
17.0
5.8
ND
ND
---
ND
11-Jun-12
0.23
3.0
ND
12
14.8
4.4
ND
ND
ND
ND
12-Dec-12
0.23
3.0
ND
15.8
17.9
4.5
ND
ND
ND
1-May-13
0.23
3.0
ND
14.0
16.6
3.0 J
ND
ND
ND
ND
5-Aug-13
0.23
3.0
ND
14.4
15.9
4.6
ND
ND
ND
24-Feb-14
0.23
3.0
ND
16.3
2.5 J
1.4 J
ND
ND
ND
ND
12-Aug-14
0.23
3.0
ND
15.6
18.3
3.6
ND
ND
ND
ND
10-Mar-15
0.23
3.0
ND
16.0
17.0
2.1 J
ND
ND
ND
ND
18-Aug-15
0.23
3.0
ND
12.8
17.6
4.3
ND
ND
ND
16-Feb-16
0.23
3.0
ND
13.5
16.4
1.5 J
ND
ND
ND
ND
9-Aug-16
0.23
3.0
ND
13.5
16.9
4.2
ND
ND
ND
13-Feb-17
0.23
3.0
ND
13.6
18.0
1.3 J
ND
ND
-
ND
22-Aug-17
0.23
3.0
ND
14.2
19.9
4.2
ND
ND
-
ND
5-Feb-18
0.23
3.0
ND
13.5
17.3
0.54 J
ND
ND
-
ND
13-Aug-18
0.23
3.0
ND
14.5
22.2
3.40
ND
ND
-
ND
4-Feb-19
0.23
1.0
ND
13.6
0.4 J
1.30
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.23
1.0
ND
10.2
16.9
ND
ND
ND
-
ND
Chloroethane
1-Dec-97
-
10
ND
5.0
2.0
2.0
ND
ND
-
-
20-May-98
-
10
ND
ND
ND
ND
ND
ND
-
-
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
---
-
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
-
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
--
-
10-May-00
-
10
ND
ND
ND
ND
ND
ND
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
10
ND
ND
ND
ND
ND
ND
30-Dec-03
--
10
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
10
ND
ND
ND
ND
ND
ND
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
10
ND
2.2
1.9
ND
ND
ND
---
ND
12-Jul-07
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2,800 pg/L (10/23/07)
19-Dec-07
--
10
ND
1.9
1.9
1.5
ND
ND
ND
ND
8-Jul-08
10
ND
2.2 J
2.5 J
1.8 J
ND
ND
-
ND
17-Dec-08
0.54
10.0
ND
1.6 J
ND
ND
ND
ND
--
ND
9-Jul-09
0.54
10.0
ND
ND
ND
3.8 J
ND
ND
ND
ND
16-Dec-09
0.54
10.0
ND
ND
2.2 J
2.0 J
ND
ND
-
ND
NC 2L = 3,000 pg/L (02/05/10)
24-Jun-10
0.54
10.0
ND
ND
2.1 J
2.0 J
ND
ND
-
ND
13-Dec-10
0.54
10.0
ND
1.8 J
2.0 J
1.7 J
ND
ND
ND
20-Jun-11
0.54
10.0
ND
1.2 J
2.2 J
2.0 J
ND
ND
ND
5-Dec-11
0.54
10.0
ND
1.3 J
2.0 J
1.7 J
ND
ND
ND
11-Jun-12
0.54
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.54
10.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.54
10.0
ND
ND
1.9 J
2.7 J
ND
ND
ND
ND
5-Aug-13
0.54
10.0
ND
ND
2.0 J
2.2 J
ND
ND
---
ND
24-Feb-14
0.54
10.0
ND
1.1 J
0.82 J
ND
ND
ND
ND
ND
12-Aug-14
0.54
10.0
ND
1.1 J
1.50 J
1.1 J
ND
ND
ND
ND
10-Mar-15
0.54
10.0
ND
1.0 J
1.80 J
0.81 J
ND
ND
ND
ND
18-Aug-15
0.54
10.0
ND
1.2 J
2.0 J
3.7 J
ND
ND
ND
16-Feb-16
0.54
10.0
ND
1.1 J
1.8 J
0.79 J
ND
ND
ND
ND
9-Aug-16
0.54
10.0
ND
0.68 J
2.4 J
1.5 J
ND
ND
--
ND
13-Feb-17
0.54
10.0
ND
0.76 J
1.6 J
1.1 J
ND
ND
ND
22-Aug-17
0.54
10.0
ND
1.3 J
2.0 J
1.6 J
ND
ND
ND
5-Feb-18
0.54
10.0
ND
1.7 J
1.7 J
0.68 J
ND
ND
-
ND
13-Aug-18
0.54
10.0
ND
1.2 J
2.4 J
1.40 J
ND
ND
ND
4-Feb-19
0.49
1.0
ND
1.3
ND
0.79 J
ND
ND
ND
14-Aug-19for Mw-6->
7-Aug-19
0.49
1.0
ND
0.94 J
1.9
1.3
ND
ND
--
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 18 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chloromethane
9-Jul-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
NC 2L = 2.6 pg/L (10/23/07)
16-Dec-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
24-Jun-10
0.11
1.0
ND
ND
ND
ND
ND
0.11 J
--
ND
NC 2L = 3 pg/L (02/05/10)
13-Dec-10
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
20-Jun-11
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
ND
--
ND
11-Jun-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
1-May-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
0.25 J
12-Aug-14
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
16-Feb-16
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
13-Feb-17
0.11
1.0
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
0.18 J
22-Aug-17
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
5-Feb-18
0.11
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
4-Feb-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for Mw-6->
7-Aug-19
0.39
1.0
ND
ND
ND
ND
ND
ND
---
ND
1,2-Dichlorobenzene
1-Dec-97
-
5
ND
3.0
2.0
1.0
ND
ND
-
-
20-May-98
-
5
ND
ND
ND
ND
ND
ND
---
-
19-Nov-98
-
5
ND
2.4
2.3
ND
ND
ND
-
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
---
---
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
-
10-May-00
-
5
ND
ND
ND
ND
ND
ND
---
--
26-Oct-00
-
5
ND
ND
ND
ND
ND
ND
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
--
--
27-Oct-01
-
5
ND
ND
ND
ND
ND
ND
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
--
--
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
--
-
30-Dec-03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
5
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-06
-
5
ND
1.5
2.3
ND
ND
ND
ND
12-Jul-07
-
5
ND
1.4 J
1.7 J
0.31 J
ND
ND
---
ND
NC 2L = 24 pg/L (10/23/07)
19-Dec-07
-
5
ND
1.6
2.0
0.37 J
ND
ND
ND
ND
8-Jul-08
-
5
ND
1.6 J
2.0 J
0.39 J
ND
ND
ND
17-Dec-08
0.30
5.0
ND
1.4 J
1.9 J
ND
ND
ND
ND
9-Jul-09
0.30
5.0
ND
1.6 J
2.0 J
0.36 J
ND
ND
ND
ND
16-Dec-09
0.30
5.0
ND
1.6 J
2.0 J
0.33 J
ND
ND
ND
NC 2L = 20 pg/L (02/05/10)
24-Jun-10
0.30
5.0
ND
0.96 J
1.7 J
0.31 J
ND
ND
ND
13-Dec-10
0.30
5.0
ND
1.9 J
1.9 J
0.43 J
ND
ND
ND
20-Jun-11
0.30
5.0
ND
1.5 J
1.7 J
0.37 J
ND
ND
ND
5-Dec-11
0.30
5.0
ND
1.3 J
1.6 J
ND
ND
ND
ND
11-Jun-12
0.30
5.0
ND
1.0 J
1.5 J
ND
ND
ND
ND
ND
12-Dec-12
0.30
5.0
ND
1.3 J
1.7 J
ND
ND
ND
ND
1-May-13
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
ND
ND
5-Aug-13
0.30
5.0
ND
1.2 J
1.6 J
0.30 J
ND
ND
ND
24-Feb-14
0.30
5.0
ND
1.4 J
0.64 J
ND
ND
ND
ND
ND
12-Aug-14
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
ND
ND
10-Mar-15
0.30
5.0
ND
1.1 J
1.1 J
ND
ND
ND
ND
ND
18-Aug-15
0.30
5.0
ND
0.88 J
1.3 J
ND
ND
ND
ND
16-Feb-16
0.30
5.0
ND
1.1 J
1.4 J
ND
ND
ND
ND
ND
9-Aug-16
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
ND
13-Feb-17
0.30
5.0
ND
1.2 J
1.4 J
ND
ND
ND
--
ND
22-Aug-17
0.30
5.0
ND
1.2 J
1.5 J
ND
ND
ND
ND
5-Feb-18
0.30
5.0
ND
1.0 J
1.4 J
ND
ND
ND
ND
13-Aug-18
0.30
5.0
ND
1.2 J
1.6 J
ND
ND
ND
ND
4-Feb-19
0.29
1.0
ND
1.0 J
ND
ND
ND
ND
--
ND
14-Aug-19for Mw-6->
7-Aug-19
0.29
1.0
ND
0.62 J
1.2
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 19 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,4-Dichlorobenzene
8-Sep-94
-
5
ND
ND
5.0
ND
ND
ND
--
---
1-Dec-94
-
5
ND
ND
5.0
ND
ND
ND
9-Feb-95
-
5
ND
8.0
6.0
ND
ND
ND
---
--
2-Mar-95
5
ND
7.0
6.0
ND
ND
ND
15-Nov-95
--
5
ND
7.0
6.0
ND
ND
ND
---
--
28-May-96
5
ND
ND
ND
ND
ND
ND
22-Nov-96
---
5
ND
ND
ND
ND
ND
ND
---
--
17-Jun-97
-
5
ND
7.6
6.2
ND
ND
ND
1-Dec-97
--
5
ND
6.0
5.0
4.0
ND
ND
--
20-May-98
5
ND
7.6
ND
ND
ND
ND
19-Nov-98
--
5
ND
3.7
2.8
ND
ND
ND
--
--
21-Jul-99
5
ND
ND
ND
ND
ND
ND
16-Nov-99
--
5
ND
ND
ND
ND
ND
ND
--
--
10-May-00
5
ND
ND
ND
ND
ND
ND
26-Oct-00
--
5
ND
5.0
6.0
ND
ND
ND
--
--
18-Apr-01
5
ND
ND
5.0
6.0
ND
ND
27-Oct-01
--
5
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
5
ND
ND
ND
ND
ND
ND
19-Nov-02
--
5
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
5
ND
ND
ND
ND
ND
ND
30-Dec-03
-
5
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
5
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
--
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
5
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
3
ND
3.0
3.3
ND
ND
ND
--
ND
Resample >
23-Feb-07
-
3
-
3.2
3.3
-
-
-
ND
12-Jul-07
-
1
ND
3.3
2.9
0.31 J
ND
ND
--
ND
NC 2L = 1.4 pg/L (10/23/07)
19-Dec-07
-
1
ND
3.0
2.7
ND
ND
ND
ND
ND
8-Jul-08
-
1
ND
3.0
2.4
ND
ND
ND
---
ND
17-Dec-08
0.33
1.0
ND
2.9
2.5
ND
ND
ND
ND
9-Jul-09
0.33
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.33
1.0
ND
2.8
2.2
ND
ND
ND
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.33
1.0
ND
1.6
ND
ND
ND
ND
-
ND
13-Dec-10
0.33
1.0
ND
3.1
1.9
ND
ND
ND
ND
20-Jun-11
0.33
1.0
ND
2.7
1.6
ND
ND
ND
-
ND
5-Dec-11
0.33
1.0
ND
2.2
1.4
ND
ND
ND
-
ND
11-Jun-12
0.33
1.0
ND
1.8
1.4
ND
ND
ND
ND
ND
12-Dec-12
0.33
1.0
ND
2.4
1.3
ND
ND
ND
-
ND
1-May-13
0.33
1.0
ND
2.1
1.2
ND
ND
ND
ND
ND
5-Aug-13
0.33
1.0
ND
2.0
1.3
ND
ND
ND
ND
24-Feb-14
0.33
1.0
ND
2.2
1.8
ND
ND
ND
ND
ND
12-Aug-14
0.33
1.0
ND
2.4
1.3
ND
ND
ND
ND
ND
10-Mar-15
0.33
1.0
ND
2.2
1.1
ND
ND
ND
ND
ND
18-Aug-15
0.33
1.0
ND
1.5
1.1
ND
ND
ND
ND
16-Feb-16
0.33
1.0
ND
2.0
1.0
ND
ND
ND
ND
ND
9-Aug-16
0.33
1.0
ND
1.9
1.0
ND
ND
ND
ND
13-Feb-17
0.33
1.0
ND
1.9
0.90 J
ND
ND
ND
-
ND
22-Aug-17
0.33
1.0
ND
1.9
0.96 J
ND
ND
ND
ND
5-Feb-18
0.33
1.0
ND
1.6
1.1
ND
ND
ND
--
ND
13-Aug-18
0.33
1.0
ND
1.9
1.1
ND
ND
ND
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
--
ND
14-Aug-19for Mw-6->
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
---
ND
Trans-1,4-Dichloro-2-Butene
20-May-98
100
ND
ND
5.1
ND
ND
ND
-
-
19-Nov-98
--
100
ND
ND
ND
ND
ND
ND
---
-
21-Jul-99
100
ND
ND
ND
ND
ND
ND
-
-
16-Nov-99
--
100
ND
ND
ND
ND
ND
ND
---
-
10-May-00
-
100
ND
ND
ND
ND
ND
ND
-
26-Oct-00
-
100
ND
ND
ND
ND
ND
ND
---
--
18-Apr-01
-
100
ND
ND
ND
ND
ND
ND
-
27-Oct-01
-
100
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
100
ND
ND
ND
ND
ND
ND
27-Jun-03
-
100
ND
ND
ND
ND
ND
ND
---
-
30-Dec-03
-
100
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
-
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
-
100
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
100
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
100
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
100
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = NE pg/L
19-Dec-07
-
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
100
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
1.0
100
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
24-Jun-10
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
1.0
100
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
1.0
100
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
1-May-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.0
100
ND
ND
ND
ND
ND
ND
ND
13-Feb-17
1.0
100
ND
ND
ND
ND
ND
ND
--
ND
22-Aug-17
1.0
100
ND
ND
ND
ND
ND
ND
ND
5-Feb-18
1.0
100
ND
ND
ND
ND
ND
ND
--
ND
13-Aug-18
1.0
100
ND
ND
ND
ND
ND
ND
ND
4-Feb-19
0.5
1
ND
ND
ND
ND
ND
ND
--
ND
14-Aug-19for Mw-6->
7-Aug-19
0.54
1.0
ND
ND
ND
ND
ND
ND
---
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 20 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
1,4-Dioxane (p-Dioxane)
13-Aug-18
1.9
10
ND
88
53.1
40.7
2.0 J
ND
---
ND
NC 2L = 3 pg/L (2017)
4-Feb-19
1.9
2
ND
132
49.6
49.8
ND
ND
ND
ND
14-Aug-19for Mw-6->
7-Aug-19
1.2
2.0
ND
98.1
51.7
32.7
3.1
ND
---
ND
1,1-Dichloroethane
1-Dec-97
-
5
ND
ND
1.0
ND
ND
ND
--
--
20-May-98
-
5
ND
ND
ND
ND
ND
ND
19-Nov-98
-
5
ND
ND
ND
ND
ND
ND
--
--
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
--
--
10-May-00
-
5
ND
ND
ND
ND
ND
ND
26-Oct-00
-
5
ND
ND
ND
ND
ND
ND
--
--
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
27-Oct-01
-
5
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
--
--
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
5
ND
ND
ND
ND
ND
ND
--
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
5
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
5
ND
ND
ND
ND
ND
ND
--
ND
12-Jul-07
-
5
ND
ND
0.36 J
0.52 J
ND
ND
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
-
5
ND
ND
ND
0.57 J
ND
ND
ND
ND
8-Jul-08
-
5
ND
ND
ND
0.60 J
ND
ND
ND
17-Dec-08
0.32
5.0
ND
ND
ND
0.51 J
ND
ND
---
ND
9-Jul-09
0.32
5.0
ND
ND
ND
0.84 J
ND
ND
ND
ND
16-Dec-09
0.32
5.0
ND
ND
ND
0.73 J
ND
ND
---
ND
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
ND
13-Dec-10
0.32
5.0
ND
ND
ND
0.60 J
ND
ND
---
ND
20-Jun-11
0.32
5.0
ND
ND
ND
0.63 J
ND
ND
ND
5-Dec-11
0.32
5.0
ND
ND
ND
0.67 J
ND
ND
---
ND
11-Jun-12
0.32
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.32
5.0
ND
ND
ND
0.61 J
ND
ND
---
ND
1-May-13
0.32
5.0
ND
ND
ND
0.62 J
ND
ND
ND
ND
8-May-13
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
---
ND
24-Feb-14
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
12-Aug-14
0.32
5.0
ND
ND
ND
0.47 J
ND
ND
ND
ND
10-Mar-15
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
18-Aug-15
0.32
5.0
ND
ND
ND
0.49 J
ND
ND
---
ND
16-Feb-16
0.32
5.0
ND
ND
ND
0.45 J
ND
ND
ND
ND
9-Aug-16
0.32
5.0
ND
ND
ND
0.34 J
ND
ND
---
ND
13-Feb-17
0.32
5.0
ND
ND
ND
0.33 J
ND
ND
ND
22-Aug-17
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
-
ND
5-Feb-18
0.32
5.0
ND
ND
ND
0.38 J
ND
ND
-
ND
13-Aug-18
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
-
ND
4-Feb-19
0.27
1.0
ND
ND
ND
0.36 J
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.27
1.0
ND
ND
ND
ND
ND
ND
-
ND
1,2-Dichloroethane
17-Dec-08
0.12
1.0
ND
ND
0.15 J
ND
ND
ND
-
ND
NC 2L = 0.38 pg/L (10/23/07)
9-Jul-09
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
0.19 J
16-Dec-09
0.12
1.0
ND
ND
0.14 J
ND
ND
ND
-
ND
NC 2L = 0.4 pg/L (02/05/10)
24-Jun-10
0.12
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.12
1.0
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
0.12
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.12
1.0
ND
ND
ND
ND
0.18 J
ND
---
ND
11-Jun-12
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.12
1.0
ND
ND
ND
ND
-0.20 J
ND
---
0.20 (ND) J
1-May-13
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.12
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.24
1.0
ND
ND
0.33 J
0.29 J
0.36 J
ND
-
16-Feb-16
0.24
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.24
1.0
ND
ND
ND
ND
ND
ND
ND
22-Aug-17
0.24
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.24
1.0
0.25 J
ND
0.37 J
ND
0.43 J
ND
ND
13-Aug-18
0.24
1.0
ND
ND
ND
ND
ND
ND
--
ND
4-Feb-19
0.34
1.0
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.34
1.0
ND
ND
ND
ND
ND
ND
-
ND
Ethylbenzene
17-Dec-08
0.30
1.0
ND
0.31 J
ND
ND
ND
ND
-
ND
NC 2L = 550 pg/L (10/23/07)
9-Jul-09
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.30
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.30
1.0
ND
ND
ND
ND
ND
ND
--
ND
20-Jun-11
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.30
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Aug-18
0.30
1.0
ND
ND
ND
ND
ND
ND
---
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
--
ND
14-Aug-19for Mw-6->
7-Aug-19
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 21 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Isobutanol
24-Jun-10
35.0
100
ND
59.0 J
ND
ND
ND
ND
---
ND
NC 2L = NE pg/L (02/05/10)
13-Dec-10
-
--
-
-
-
-
-
-
20-Jun-11
35.0
100
ND
39.5 J
ND
ND
ND
ND
--
ND
5-Dec-11
-
-
-
-
-
-
-
--
-
11-Jun-12
35.0
100.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
-
--
-
-
-
-
-
-
1-May-13
35.0
100
ND
ND
ND
ND
ND
ND
--
ND
5-Aug-13
-
-
-
-
24-Feb-14
35.0
100
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
35.0
100
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
35.0
100
ND
ND
ND
-
-
--
ND
16-Feb-16
35.0
100
ND
42.5 J
ND
-
-
ND
13-Feb-17
35.0
100
ND
ND
ND
-
-
--
ND
22-Aug-17
35.0
100
ND
ND
ND
-
-
-
ND
5-Feb-18
35.0
100
ND
ND
ND
-
-
ND
4-Feb-19
66.4
100
ND
ND
ND
-
-
ND
Methylene Chloride
9-Jul-09
0.97
2.0
ND
ND
ND
ND
ND
ND
ND
9.6
NC 2L = 4.3 pg/L (10/23/07)
16-Dec-09
0.97
2.0
ND
ND
ND
ND
ND
ND
--
ND
24-Jun-10
0.97
1.0
ND
19.0
ND
ND
ND
ND
ND
Resample >
12-Aug-10
0.97
1.0
-
ND
-
---
-
-
--
ND
NC 2L = 5 pg/L (02/05/10)
13-Dec-10
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
20-Jun-11
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.97
1.0
ND
ND
ND
ND
ND
ND
--
ND
11-Jun-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.97
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.97
1.0
1.3
1.1
1.6
ND
ND
ND
ND
ND
16-Feb-16
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.97
1.0
ND
ND
1.0 B
ND
ND
ND
2.2 B
13-Feb-17
0.97
1.0
ND
ND
ND
ND
ND
ND
--
ND
22-Aug-17
0.97
1.0
ND
ND
ND
ND
ND
ND
1.4 C
5-Feb-18
0.97
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Aug-18
0.97
1.0
ND
ND
ND
ND
ND
ND
6.6
4-Feb-19
3.70
5.0
ND
ND
ND
ND
ND
ND
---
ND
14-Aug-19for Mw-6->
7-Aug-19
3.7
5.0
ND
ND
ND
ND
ND
ND
---
ND
Naphthalene
8-Jul-08
-
10
ND
3.8 J
ND
ND
ND
ND
-
ND
NC 2L = 21 pg/L (10/23/07)
17-Dec-08
-
--
-
-
-
-
-
-
-
9-Jul-09
0.24
10.0
ND
2.4 J
ND
ND
ND
ND
-
ND
16-Dec-09
-
-
-
-
-
-
-
-
-
NC 2L = 6 pg/L (02/05/10)
24-Jun-10
0.24
10.0
ND
7.4 J
ND
ND
ND
ND
-
ND
13-Dec-10
-
-
-
-
-
-
-
-
-
20-Jun-11
0.24
10.0
ND
4.6 J
ND
ND
ND
ND
0.39 J
5-Dec-11
-
-
-
-
11-Jun-12
0.2
10.0
ND
4.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
-
---
-
-
-
---
-
-
--
-
1-May-13
0.24
10.0
ND
5.1 J
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
24-Feb-14
0.24
10.0
ND
5.8 J
ND
ND
ND
ND
ND
12-Aug-14
-
---
-
-
-
---
10-Mar-15
0.2
10
ND
5.4 J
ND
-
ND
16-Feb-16
0.2
10
ND
5.7 J
ND
--
-
--
--
ND
13-Feb-17
0.2
10
ND
6.1 J
ND
-
-
ND
22-Aug-17
0.2
10
ND
7.0 J
0.45 J
--
-
--
-
ND
5-Feb-18
0.2
10
ND
5.7 J
ND
-
ND
4-Feb-19
0.4
1
ND
4.2
ND
--
-
--
--
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 22 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Toluene
20-May-98
-
5
ND
ND
8.1
ND
ND
ND
---
---
19-Nov-98
-
5
ND
ND
ND
ND
ND
ND
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
---
--
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
10-May-00
-
5
ND
ND
ND
ND
ND
ND
---
--
26-Oct-00
-
5
ND
ND
ND
ND
ND
ND
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
--
--
27-Oct-01
-
5
ND
ND
ND
ND
ND
ND
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
--
--
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
--
-
30-Dec-03
-
5
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
-
5
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-05
-
5
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-06
-
5
ND
ND
ND
ND
ND
ND
ND
12-Jul-07
-
1
ND
0.49 B
ND
ND
ND
ND
--
0.34 J
NC 2L = 1,000 pg/L (10/23/07)
19-Dec-07
-
1
ND
0.51 J
ND
ND
ND
ND
ND
ND
8-Jul-08
-
1
ND
0.39 J
ND
ND
1.3
ND
--
ND
17-Dec-08
0.26
1.0
1.4
1.6
ND
ND
11.7
ND
ND
9-Jul-09
0.26
1.0
ND
0.46 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.26
1.0
ND
0.42 J
ND
ND
ND
ND
ND
NC 2L = 600 pg/L (02/05/10)
24-Jun-10
0.26
1.0
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.26
1.0
ND
0.54 J
ND
ND
ND
ND
-
ND
20-Jun-11
0.26
1.0
ND
0.34 J
ND
ND
ND
ND
-
ND
5-Dec-11
0.26
1.0
ND
0.28 J
ND
ND
0.30 J
ND
-
ND
11-Jun-12
0.26
1.0
ND
0.28 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.26
1.0
ND
0.29 J
ND
ND
0.36 J
ND
-
ND
1-May-13
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.26
1.0
ND
0.29 J
ND
ND
ND
ND
-
ND
24-Feb-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
16-Feb-16
0.26
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.26
1.0
ND
0.33 J
ND
ND
ND
ND
-
ND
13-Feb-17
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.26
1.0
ND
ND
ND
ND
0.44 J
ND
-
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
Vinyl Chloride
8-Sep-94
-
10
ND
ND
12.0
ND
ND
ND
--
1-Dec-94
-
10
ND
ND
13.0
ND
ND
ND
--
--
9-Feb-95
-
10
ND
ND
15.0
ND
ND
ND
2-Mar-95
-
10
ND
ND
14.0
ND
ND
ND
-
-
15-Nov-95
-
10
ND
ND
11.0
ND
ND
ND
-
28-May-96
-
10
ND
ND
ND
ND
ND
ND
--
--
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
17-Jun-97
-
10
ND
ND
ND
ND
ND
ND
--
--
1-Dec-97
-
10
ND
ND
7.0
4.0
ND
ND
20-May-98
-
10
ND
ND
ND
ND
ND
ND
---
--
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
-
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
---
--
16-Nov-99
10
ND
ND
ND
ND
ND
ND
10-May-00
--
10
ND
ND
ND
ND
ND
ND
--
--
26-Oct-00
-
10
ND
ND
ND
ND
ND
ND
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
--
--
27-Oct-01
-
10
ND
ND
ND
ND
ND
ND
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
--
--
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
--
-
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
--
10
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
--
10
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
10
ND
ND
ND
ND
ND
ND
ND
29-Dec-05
--
10
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
--
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
5.5
ND
ND
0.98 J
ND
ND
ND
ND
Resample >
23-Feb-07
-
5.5
-
-
1.0
-
-
-
--
ND
12-Jul-07
-
1
ND
ND
ND
ND
ND
ND
ND
NC 2L = 0.015 pg/L (10/23/07)
19-Dec-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
1
ND
ND
0.76 J
ND
ND
ND
-
ND
17-Dec-08
0.62
1.0
ND
ND
0.76 J
ND
ND
ND
--
ND
9-Jul-09
0.62
1.0
ND
ND
0.99 J
ND
ND
ND
ND
ND
16-Dec-09
0.62
1.0
ND
ND
0.81 J
ND
ND
ND
--
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.62
1.0
ND
ND
0.77 J
ND
ND
ND
-
ND
13-Dec-10
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.62
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.62
1.0
ND
ND
ND
ND
ND
ND
---
ND
13-Feb-17
0.62
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.62
1.0
ND
ND
ND
ND
ND
ND
--
ND
5-Feb-18
0.62
1.0
ND
ND
0.63 J
ND
ND
ND
-
ND
13-Aug-18
0.62
1.0
ND
ND
0.72 J
ND
ND
ND
-
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.24
1.0
ND
ND
1.1
ND
ND
ND
-
ND
Resample >
4-Sep-19
0.24
1.0
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 23 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Xylene (Total)
29-Dec-06
---
5
ND
1.4
ND
ND
ND
ND
---
ND
12-Jul-07
-
4
ND
1.2 J
ND
ND
ND
ND
---
ND
NC 2L = 530 pg/L (10/23/07)
19-Dec-07
-
4
ND
2.0
ND
ND
ND
ND
ND
ND
8-Jul-08
-
4
ND
1.1 J
ND
ND
ND
ND
ND
17-Dec-08
0.66
2.0
1.4 J
2.7
ND
ND
ND
ND
---
ND
9-Jul-09
0.66
2.0
ND
1.5 J
ND
ND
ND
ND
ND
ND
16-Dec-09
0.66
2.0
ND
2.2
ND
ND
ND
ND
--
ND
NC 2L = 500 pg/L (02/05/10)
24-Jun-10
0.66
2.0
ND
0.73 J
ND
ND
ND
ND
-
ND
13-Dec-10
0.66
2.0
ND
2.0
ND
ND
ND
ND
--
ND
20-Jun-11
0.66
2.0
ND
1.4 J
ND
ND
ND
ND
-
ND
5-Dec-11
0.66
2.0
ND
1.1 J
ND
ND
ND
ND
-
ND
11-Jun-12
0.66
2.0
ND
0.91 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.66
5.0
ND
0.97 J
ND
ND
ND
ND
---
ND
1-May-13
0.66
5.0
ND
0.68 J
ND
ND
ND
ND
ND
ND
5-Aug-13
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Feb-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
16-Feb-16
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
0.66
5.0
ND
ND
ND
ND
ND
ND
--
ND
13-Feb-17
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
22-Aug-17
0.66
5.0
ND
ND
ND
ND
ND
ND
---
ND
5-Feb-18
0.66
5.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.66
5.0
ND
ND
ND
ND
ND
ND
--
ND
4-Feb-19
0.63
1.0
ND
ND
ND
ND
ND
ND
-
ND
14-Aug-19for Mw-6->
7-Aug-19
0.63
1.0
ND
ND
ND
ND
ND
ND
-
ND
Bis(2-Ethylhexyl)phthalate
24-Feb-14
0.79
15.0
2.6 J
ND
ND
ND
ND
ND
ND
ND
NC 2L = 3 pg/L (2/5/10)
15-Apr-14
0.79
15.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
-
-
-
-
-
10-Mar-15
0.5
15.0
ND
ND
ND
-
-
-
ND
16-Feb-16
0.9
15.0
ND
ND
ND
-
-
-
ND
13-Feb-17
0.9
15.0
ND
ND
ND
-
-
-
ND
22-Aug-17
2.3
15.0
ND
ND
ND
-
---
--
-
ND
5-Feb-18
2.4
15.6
ND
ND
ND
-
-
ND
4-Feb-A
1.4
6.0
ND
ND
ND
--
-
ND
N-Nitroso-di-n-butylamine
24-Feb-14
7.5
10.0
ND
ND
ND
8.6 J
ND
ND
ND
ND
12-Aug-14
-
-
-
-
10-Mar-15
1.3
10
ND
ND
ND
-
-
-
-
ND
16-Feb-16
2.2
10
ND
ND
ND
-
-
-
-
ND
13-Feb-17
2.2
10
ND
ND
ND
-
-
-
-
ND
22-Aug-17
1.6
10
ND
ND
ND
-
-
-
-
ND
5-Feb-18
1.6
10
ND
ND
ND
-
-
-
-
ND
4-Feb-19
2.2
10
ND
ND
ND
-
-
-
-
ND
Benzo(g,h,i)perylene
20-Jun-11
0.4
10.0
ND
ND
ND
ND
ND
1.4 J
-
ND
NC 2L = 200 pg/L (2/5/10)
5-Dec-11
-
-
-
-
-
-
-
-
11-Jun-12
0.38
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
---
---
-
-
-
-
-
-
-
1-May-13
0.38
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
24-Feb-14
0.38
10.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
-
-
-
ND
16-Feb-A
0.4
10.0
ND
ND
ND
-
-
ND
13-Feb-17
0.4
10.0
ND
ND
ND
-
-
-
ND
22-Aug-17
2.1
10.0
ND
ND
ND
-
-
-
--
ND
5-Feb-18
2.2
10.4
ND
ND
ND
-
-
-
ND
4-Feb-A
1.8
10.0
ND
ND
ND
-
-
-
--
ND
Dibenz(a,h)anthracene
20-Jun-11
0.55
10.0
ND
ND
ND
ND
ND
1.5 J
-
ND
NC 2L = 0.005 pg/L (2/5/10)
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
0.55
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
-
-
-
-
-
-
-
-
1-May-13
0.55
10.0
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
-
-
-
-
-
24-Feb-14
0.55
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
-
-
-
-
-
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.6
10.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.6
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
2.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.1
10.4
ND
ND
ND
-
-
-
--
ND
4-Feb-19
1.9
10.0
ND
ND
ND
-
-
ND
Fluorene
24-Jun-10
3.8
12.2
ND
4.3 J
ND
ND
ND
ND
ND
Resample >
12-Aug-10
3.1
10.0
-
ND
-
-
-
-
-
ND
NC 2L = 300 pg/L (2/5/10)
13-Dec-10
-
-
-
-
-
-
-
-
-
-
20-Jun-11
0.2
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
0.21
10.0
ND
ND
ND
ND
ND
ND
--
ND
12-Dec-12
-
--
-
-
-
-
-
-
-
-
1-May-13
0.21
10.0
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
-
-
-
-
24-Feb-14
0.21
10.0
ND
ND
ND
ND
ND
ND
--
ND
12-Aug-14
-
-
-
-
10-Mar-15
1.0
10.0
ND
ND
ND
-
-
--
ND
16-Feb-16
0.2
10.0
ND
ND
ND
-
-
ND
13-Feb-17
0.2
10.0
ND
ND
ND
-
-
--
---
ND
22-Aug-17
1.6
10.0
ND
ND
ND
-
-
ND
5-Feb-18
1.6
10.4
ND
ND
ND
-
-
--
--
ND
4-Feb-19
3.0
10.0
ND
ND
ND
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 24 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
Indeno(1,2,3-cd)pyrene
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
1.3 J
---
ND
NC 2L = 0.05 pg/L (2/5/10)
5-Dec-11
-
-
-
-
-
-
-
-
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
--
ND
12-Dec-12
-
-
-
-
-
-
-
-
1-May-13
0.29
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Aug-13
-
-
-
-
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
--
-
-
---
ND
16-Feb-16
0.3
10.0
ND
ND
ND
--
-
ND
13-Feb-17
0.3
10.0
ND
ND
ND
--
-
---
---
ND
22-Aug-17
2.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.1
10.4
ND
ND
ND
-
-
-
--
ND
4-Feb-19
1.7
10.0
ND
ND
ND
-
-
-
-
ND
2-Methylnaphthalene
24-Jun-10
5.1
12.2
ND
38.9
ND
ND
ND
ND
ND
Resample>
12-Aug-10
4.2
10
-
ND
-
-
-
--
ND
NC 2L = 30 pg/L (02/05/10)
13-Dec-10
-
--
-
-
-
-
-
-
-
20-Jun-11
0.3
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
0.28
10.0
ND
ND
ND
ND
ND
ND
--
ND
12-Dec-12
-
-
-
-
-
-
-
--
-
1-May-13
0.28
10.0
ND
ND
ND
ND
ND
ND
--
ND
5-Aug-13
-
-
-
-
24-Feb-14
0.28
10.0
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
-
-
-
-
10-Mar-15
1.0
10.0
ND
ND
ND
--
-
-
---
ND
16-Feb-16
0.3
10.0
ND
ND
ND
--
-
-
ND
13-Feb-17
0.3
10.0
ND
ND
ND
--
-
-
---
ND
22-Aug-17
1.4
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
1.5
10.4
ND
ND
ND
-
-
-
--
ND
4-Feb-19
2.8
10.0
ND
ND
ND
-
-
-
-
ND
Phorate
18-Apr-01
10
-
3.2
ND
ND
ND
-
-
-
27-Oct-01
--
5
ND
8.1
ND
ND
ND
ND
--
-
27-Oct-01
0.5
-
8.1
1.3
ND
ND
-
-
13-Jun-02
--
5
ND
ND
ND
ND
ND
ND
--
--
13-Jun-02
0.5
-
ND
ND
ND
ND
-
-
19-Nov-02
---
5
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-05
-
-
-
-
--
-
-
--
-
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
-
-
-
-
-
-
-
-
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 1.4 pg/L (10/23/07)
19-Dec-07
-
-
-
-
-
-
-
ND
-
8-Jul-08
-
10
ND
ND
ND
ND
ND
ND
ND
17-Dec-08
-
-
-
-
-
-
-
-
-
9-Jul-09
6.6
22.2
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
-
-
-
-
-
-
-
--
-
NC 2L = 1 pg/L (02/05/10)
24-Jun-10
6.5
24.1
ND
ND
ND
ND
ND
ND
ND
13-Dec-10
-
-
-
-
-
-
-
--
-
20-Jun-11
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
11-Jun-12
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
---
-
-
-
-
-
-
--
-
1-May-13
5.4
10.0
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
24-Feb-14
5.4
10.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.8
10.0
ND
ND
ND
-
-
-
ND
16-Feb-16
1.1
10.0
ND
ND
ND
--
-
-
ND
13-Feb-17
1.1
10.0
ND
ND
ND
-
-
-
ND
22-Aug-17
1.7
10.0
ND
ND
ND
-
-
-
--
ND
5-Feb-18
1.8
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.1
10.0
ND
ND
ND
-
-
-
-
ND
Beta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.16
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
-
-
ND
-
-
-
-
12-Dec-12
-
---
-
-
-
-
-
-
--
-
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
-
-
-
-
24-Feb-14
0.050
0.050
ND
0.052
ND
ND
ND
ND
-
ND
Resample >
15-Apr-14
0.050
0.050
-
ND
-
-
-
-
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.1
0.1
ND
ND
ND
-
-
--
ND
16-Feb-16
0.1
0.1
ND
ND
ND
-
-
ND
13-Feb-17
0.1
0.1
ND
ND
ND
-
-
ND
5-Feb-18
0.1
0.1
ND
ND
ND
-
-
-
ND
4-Feb-A
0.1
0.1
ND
ND
ND
-
-
-
-
ND
Delta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.090
ND
ND
ND
---
ND
NC 2L = 0.019 pg/L (10/23/07)
19-Jul-12
0.050
0.050
-
-
ND
-
-
-
-
12-Dec-12
-
---
-
-
-
-
-
-
--
-
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
-
-
-
-
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
--
-
-
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
--
ND
13-Feb-17
0.050
0.050
ND
ND
ND
-
-
ND
5-Feb-18
0.052
0.052
ND
ND
ND
-
-
ND
4-Feb-19
0.050
0.050
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 25 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
gamma-BHC (Lindane)
27-Jun-03
-
1.05
ND
0.085
ND
ND
ND
ND
---
ND
30-Dec-03
-
0.05
ND
ND
ND
ND
ND
ND
ND
30-Jun-04
-
0.05
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-04
-
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Jun-05
-
0.05
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-05
-
0.05
ND
ND
ND
ND
ND
ND
---
ND
28-Jun-06
-
0.05
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-06
-
0.05
ND
ND
ND
ND
ND
ND
ND
12-Jul-07
-
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.2 pg/L (10/23/07)
19-Dec-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
0.50
ND
ND
ND
ND
ND
ND
---
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
--
ND
16-Dec-09
0.01
0.1
ND
ND
ND
ND
ND
ND
ND
NC 2L = 0.03 pg/L (02/05/10)
24-Jun-10
0.00021
0.010
ND
ND
0.052
ND
ND
ND
--
ND
Resample >
12-Aug-10
0.00020
0.010
-
-
ND
-
-
-
ND
13-Dec-10
0.00020
0.050
ND
ND
0.013 J
ND
ND
ND
-
ND
20-Jun-11
0.00020
0.050
ND
ND
0.066
ND
ND
ND
ND
Resample >
28-Jul-11
0.00020
0.010
-
-
ND
-
-
-
--
ND
5-Dec-11
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
--
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
12-Aug-14
0.050
0.050
ND
ND
ND
-
-
-
-
ND
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
18-Aug-15
0.050
0.050
ND
ND
ND
-
-
-
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
ND
9-Aug-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.050
0.050
ND
ND
ND
-
-
-
ND
5-Feb-18
0.052
0.052
ND
ND
ND
-
-
-
-
ND
4-Feb-A
0.050
0.050
ND
ND
ND
-
-
-
-
ND
Heptachlor
27-Jun-03
-
1.05
ND
0.03
0.17
ND
ND
ND
-
ND
30-Dec-03
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-04
-
0.05
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
--
0.05
ND
ND
ND
ND
ND
ND
--
ND
28-Jun-06
---
0.05
ND
ND
ND
ND
ND
ND
---
ND
29-Dec-06
-
0.05
ND
ND
ND
ND
ND
ND
ND
12-Jul-07
-
0.05
ND
ND
ND
ND
ND
ND
---
ND
NC 2L = 0.0078 pg/L (10/23/07)
19-Dec-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
-
0.05
ND
ND
ND
ND
ND
ND
--
ND
17-Dec-08
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
16-Dec-09
0.02
0.1
ND
ND
ND
ND
ND
ND
ND
NC 2L = 0.008 pg/L (02/05/10)
24-Jun-10
0.0015
0.010
ND
ND
ND
ND
ND
ND
--
ND
13-Dec-10
0.0500
0.0015
ND
ND
ND
ND
ND
ND
ND
20-Jun-11
0.050
0.0015
ND
ND
ND
ND
ND
ND
---
ND
5-Dec-11
0.050
0.056
ND
0.062
ND
ND
ND
ND
-
ND
Resample >
25-Jan-12
0.050
0.0500
-
ND
-
-
-
-
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
--
ND
12-Aug-14
0.050
0.050
ND
ND
ND
-
-
-
--
ND
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
-
ND
18-Aug-15
0.050
0.050
ND
ND
ND
-
-
--
--
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
ND
9-Aug-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.050
0.050
ND
ND
ND
-
-
-
ND
5-Feb-18
0.052
0.052
ND
ND
ND
-
-
-
--
ND
4-Feb-19
0.050
0.050
ND
ND
ND
-
-
-
-
ND
2,4-D
27-Jun-03
-
3
-
5.9
ND
ND
ND
-
-
-
30-Dec-03
-
2
ND
ND
ND
ND
ND
ND
---
ND
30-Jun-04
-
2
ND
ND
ND
ND
ND
ND
ND
29-Dec-04
-
2
ND
ND
ND
ND
ND
ND
--
ND
29-Jun-05
-
2
ND
ND
ND
ND
ND
ND
--
ND
29-Dec-05
-
2
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
2
ND
ND
ND
ND
ND
ND
ND
29-Dec-06
-
2
ND
ND
ND
ND
ND
ND
--
ND
12-Jul-07
-
2
ND
ND
ND
ND
ND
ND
ND
NC 2L = 70 pg/L (10/23/07)
19-Dec-07
-
2
ND
ND
ND
ND
ND
ND
ND
ND
8-Apr-08
-
2
ND
ND
ND
ND
ND
ND
ND
17-Dec-08
--
2.0
ND
ND
ND
ND
ND
ND
--
ND
9-Jul-09
2.0
ND
ND
ND
ND
ND
ND
-
ND
16-Dec-09
0.11
5.0
ND
ND
ND
ND
ND
ND
---
ND
24-Jun-10
0.23
2.1
ND
ND
ND
ND
ND
ND
-
ND
10-Dec-10
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
20-Jun-11
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
11-Jun-12
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
0.22
2.0
ND
ND
ND
ND
ND
ND
---
ND
1-May-13
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.22
2.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.22
2.0
ND
ND
ND
---
-
-
--
ND
10-Mar-15
0.24
2.1
ND
ND
ND
-
-
-
ND
18-Aug-15
0.24
2.1
ND
ND
ND
---
-
--
--
ND
16-Feb-16
0.23
1.0
ND
ND
ND
-
-
ND
9-Aug-16
0.24
1.0
ND
ND
ND
---
-
--
--
ND
13-Feb-17
0.22
0.9
ND
ND
ND
-
-
ND
22-Aug-17
0.24
1.0
ND
ND
ND
---
-
--
---
ND
5-Feb-18
0.24
1.0
ND
ND
ND
-
-
-
ND
4-Feb-A
1.60
5.0
ND
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 26 of 27

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Blanks
4,4'-DDD
11-Jun-12
0.05
0.05
ND
ND
0.13
ND
ND
ND
---
ND
Resample>
19-Jul-12
0.05
0.10
-
-
ND
-
-
-
-
NC 2L = 0.1 pg/L (2/5/10)
12-Dec-12
-
-
-
-
-
-
-
--
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
-
-
-
-
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
--
-
-
10-Mar-15
0.050
0.10
ND
ND
ND
-
-
ND
16-Feb-16
0.050
0.10
ND
ND
ND
-
-
ND
13-Feb-17
0.050
0.10
ND
ND
ND
-
-
-
ND
5-Feb-18
0.052
0.10
ND
ND
ND
-
-
--
---
ND
4-Feb-19
0.050
0.05
ND
ND
ND
-
-
-
ND
4,4'-DDT
11-Jun-12
0.05
0.05
ND
ND
0.10
ND
ND
ND
-
ND
Resample>
19-Jul-12
0.05
0.10
-
-
0.063 J
-
-
-
-
--
NC 2L = 0.1 pg/L (2/5/10)
12-Dec-12
-
-
-
-
-
-
-
-
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
-
-
-
-
-
-
-
-
-
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
--
ND
12-Aug-14
-
-
-
-
-
-
-
-
-
10-Mar-15
0.050
0.10
ND
ND
ND
-
-
-
ND
16-Feb-16
0.050
0.10
ND
ND
ND
-
-
-
ND
13-Feb-17
0.050
0.10
ND
ND
ND
-
-
--
-
ND
5-Feb-18
0.052
0.10
ND
ND
ND
-
-
--
ND
4-Feb-19
0.050
0.05
ND
ND
ND
-
-
--
-
ND
Dinoseb
10-Mar-15
0.061
1.1
ND
ND
0.11 J
-
-
-
ND
16-Feb-16
0.058
0.19
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.057
0.19
ND
ND
ND
-
-
-
--
ND
22-Aug-17
0.062
0.20
ND
ND
ND
-
-
-
ND
5-Feb-18
0.061
0.20
ND
ND
ND
-
-
-
---
ND
4-Feb-19
1.200
5.00
ND
ND
ND
-
-
-
ND
Endrin aldehyde
11-Jun-12
0.050
0.050
ND
ND
0.14
ND
ND
ND
NC 2L= 2 (2/5/10)
12-Dec-12
0.050
0.10
ND
ND
ND
ND
ND
ND
-
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
0.050
0.10
ND
ND
ND
ND
ND
ND
--
ND
24-Feb-14
0.050
0.10
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.050
0.10
ND
ND
ND
-
-
--
ND
10-Mar-15
0.050
0.10
ND
ND
ND
--
-
--
ND
18-Aug-15
0.050
0.10
ND
ND
ND
-
ND
16-Feb-16
0.050
0.10
ND
ND
ND
--
-
--
-
ND
9-Aug-16
0.050
0.10
ND
ND
ND
-
ND
13-Feb-17
0.050
0.10
ND
ND
ND
--
-
--
ND
5-Feb-18
0.052
0.10
ND
ND
ND
ND
4-Feb-19
0.050
0.05
ND
ND
ND
--
--
ND
Diethylphthalate
4-Feb-19
2.00
10.00
ND
7.1 J
ND
---
---
---
---
ND
Endosulfan I
4-Feb-19
0.05
0.05
-
0.078
0.19
---
---
---
---
-
Dichlorodifluoromethane
5-Feb-18
0.21
5.0
ND
0.36 J
ND
ND
4-Feb-19
0.23
1.0
ND
ND
ND
--
--
--
--
ND
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
INC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
IMAC = Interim Maximum Allowable Concetration (for constituents with no NC2L).
Bold values for groundwater are above the NC 2L Standards or IMAC.
= Well was not monitored and/or not reported.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 27 of 27

Appendix F
Historical Constituents in Surface Water

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
NC 2B = 10 ug/L (03/28/08)
12/13/10
2.7
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
3.0 J
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
EPA 6010
5.0
10.0
ND
ND
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
ND
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
-
08/07/19
EPA 6010D
4.7
10.0
ND
ND
ND
Barium
11/22/96
-
500
37.0
37.0
-
06/17/97
-
500
37.0
62.0
-
12/01/97
-
500
53.0
45.0
-
05/20/98
-
500
24.0
69.0
-
11/19/98
-
500
ND
100.0
-
07/21/99
-
500
ND
ND
-
11/16/99
-
500
ND
ND
-
05/10/00
-
500
ND
ND
-
10/26/00
-
500
ND
ND
-
04/18/01
-
500
ND
ND
-
10/27/01
-
500
ND
ND
-
06/13/02
-
500
-
-
-
11/19/02
-
500
ND
ND
-
06/27/03
-
500
ND
ND
-
12/30/03
-
500
ND
ND
ND
06/30/04
-
500
ND
ND
ND
12/29/04
-
500
ND
ND
ND
12/29/04
-
500
ND
ND
ND
06/29/05
-
500
ND
ND
ND
12/29/05
-
500
ND
ND
ND
06/28/06
-
500
ND
ND
ND
12/29/06
-
100
37.5
40.6
0.20 J
07/12/07
-
100
33.3 J
-
ND
12/19/07
-
100
52.6 B
149.0
11.7
07/08/08
-
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 J
12.1 J
06/20/11
5.0
100
40.3 J
93.0 J
ND
12/05/11
5.0
100
32.9 J
59.0 J
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 J
79.8 J
ND
02/24/14
5.0
100
29.0 J
30.4 J
ND
08/12/14
EPA 6010
5.0
100
-
121
ND
03/10/15
EPA 6010
2.5
100
29.0 J
32.1 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
100
33.1 J
33.5 J
ND
08/09/16
EPA 6010
2.5
100
43.3 J
105
ND
02/13/17
EPA 6010
2.5
100
45.3 J
60.4 J
ND
08/22/17
EPA 6010
2.5
100
39.7 J
88.7 J
ND
02/05/18
EPA 6010
2.5
100
32.5 J
29.1 J
ND
08/13/18
EPA 6010D
2.5
100
70.0 J
86.6 J
ND
02/04/19
EPA 6010D
2.5
5
29.1
33.1
-
ISTV = 21,000 Ng/L
08/07/19
EPA 6010D
1.0
5.0
70.0
94.4
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Beryllium
07/08/08
--
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
NC 2B = 6.5 ug/L (02/05/10)
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
EPA 6010
1.0
1.0
-
ND
ND
03/10/15
EPA 6010
0.50
1.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
0.50
1.0
ND
ND
ND
08/09/16
EPA 6010
0.50
1.0
ND
ND
ND
02/13/17
EPA 6010
0.50
1.0
ND
ND
ND
08/22/17
EPA 6010
0.50
1.0
ND
ND
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
0.50
1.0
ND
ND
ND
08/13/18
EPA 6010D
0.50
1.0
ND
ND
ND
02/04/19
EPA 6010D
0.50
1.0
ND
ND
-
08/07/19
EPA 6010D
0.20
1.0
ND
ND
ND
Chromium
06/17/97
-
10.0
ND
3.00
-
12/01/97
-
10.0
ND
ND
-
05/20/98
-
10.0
ND
ND
-
11/19/98
-
10.0
ND
ND
-
07/21/99
-
10.0
ND
ND
-
11/16/99
-
10.0
ND
ND
-
05/10/00
-
10.0
ND
ND
-
10/26/00
-
10.0
ND
ND
-
04/18/01
-
10.0
ND
ND
-
10/27/01
-
10.0
ND
ND
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
ND
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
2.20 B
2.60 B
1.40 J
NC 2B = 50 ug/L (03/28/08)
07/08/08
-
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 J
2.60 J
ND
07/09/09
0.4
10.0
2.6 J
1.2 J
ND
12/16/09
0.4
10.0
4.1 J
3.4 J
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
2.90 J
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
6.9 J
7.9 J
ND
NC 2B = Hardness Dependant
08/13/18
EPA 6010D
2.5
10.0
5.9 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
08/07/19
EPA 6010D
1.0
5.0
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Cobalt
05/20/98
-
10
2.0
2.0
-
11/19/98
-
10
ND
3.0
-
07/21/99
-
10
ND
ND
-
11/16/99
-
10
ND
ND
-
05/10/00
-
10
ND
ND
-
10/26/00
-
10
ND
ND
-
04/18/01
-
10
ND
ND
-
10/27/01
-
10.0
ND
22.0
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
10.0
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
4.2 B
1.20 B
1.8 J
07/08/08
-
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
NC 2B = NE pWL (03/24/10)
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
(4.4} B
(ND)
1.6 (1.0 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resample >
01/25/12
5.0
10.0
-
-
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
ISTV = 4 Ng/L
08/07/19
EPA 6010D
1.1
5.0
2.5 J
ND
ND
Copper
12/29/06
--
10.0
1.3 B
1.10 B
0.60 J
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
5.3 B
ND
9.8
NC 2B = 7 ug/L (03/28/08)
07/08/08
-
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/13/10
0.3
10.0
0.31 B
ND
0.49 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
3.8 J
3.8 J
ND
08/13/18
EPA 6010D
2.5
10.0
4.1 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
08/07/19
EPA 6010D
2.1
5.0
3.2 J
3.3 J
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Lead
05/20/98
-
10.0
ND
8.00
-
11/19/98
-
10.0
ND
ND
-
07/21/99
-
10.0
ND
10.0
-
11/16/99
-
10.0
ND
ND
-
05/10/00
-
10.0
ND
ND
-
10/26/00
-
10.0
ND
ND
-
04/18/01
-
10.0
ND
ND
-
10/27/01
-
10.0
ND
ND
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
ND
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
ND
ND
ND
NC 2B = 25 ug/L (03/28/08)
07/08/08
-
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
08/07/19
EPA 6010D
1.6
5.0
2.2 J
ND
ND
Nickel
12/29/04
-
50.0
ND
50.0 (ND)
ND
06/29/05
-
50.0
ND
ND
ND
12/29/05
-
50.0
ND
ND
ND
06/28/06
-
50.0
ND
ND
ND
12/29/06
-
50.0
ND
2.9 J
ND
07/12/07
-
50.0
3.8 J
-
ND
12/19/07
-
50.0
6.0
31.5
ND
NC 2B = 25 ug/L (03/28/08)
07/08/08
-
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13.8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
EPA 6010
5.0
50.0
-
20.3 J
ND
03/10/15
EPA 6010
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
EPA 6010
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
EPA 6010
2.5
50.0
ND
7.3 J
ND
08/22/17
EPA 6010
2.5
50.0
ND
16.3 J
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
2.5
50.0
5.3 J
4.4 J
ND
08/13/18
EPA 6010D
2.5
50.0
7.3 J
12.4 J
ND
02/04/19
EPA 6010D
2.5
5.0
ND
2.7 J
-
08/07/19
EPA 6010D
0.90
5.0
8.8
14.8
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Silver
07/12/07
-
10.0
2.20 J
-
ND
12/19/07
-
10.0
ND
0.34 J
ND
NC 2B = 0.06 ug/L (03/28/08)
07/08/08
-
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
(ND)
{0.28) B
0.21 (0.19 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
08/07/19
EPA 6010D
2.5
5.0
ND
ND
ND
Thallium
12/29/04
-
10.0
ND
10.0 (ND)
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
6.00
ND
ND
ND
07/12/07
-
5.5
ND
-
ND
12/19/07
-
5.5
3.60 J
ND
ND
07/08/08
-
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
NC 2B = NE (03/24/10)
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
EPA 6010
5.4
5.5
-
ND
ND
03/10/15
EPA 6010
5.0
5.5
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
5.0
5.5
ND
ND
ND
08/09/16
EPA 6010
5.0
5.5
ND
ND
ND
02/13/17
EPA 6020B
0.020
5.5
ND
ND
ND
08/22/17
EPA 6020B
0.020
5.5
ND
ND
ND
02/05/18
EPA 6020B
0.028
0.10
ND
ND
ND
08/13/18
EPA 6020B
0.020
5.50
ND
ND
ND
02/04/19
EPA 6020B
0.060
0.10
ND
ND
-
08/07/19
EPA 6020B
0.060
0.10
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Vanadium
12/29/06
-
25.0
1.60 J
2.00 J
ND
07/12/07
-
25.0
4.60 J
-
ND
12/19/07
-
25.0
3.30 J
1.40 B
0.62 J
NC 2B = NE Ng/L (03/28/08)
07/08/08
-
25.0
5.20 J
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 J
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.50 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
EPA 6010
5.0
25.0
-
ND
ND
03/10/15
EPA 6010
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
EPA 6010
2.5
25.0
2.9 J
2.8 J
ND
02/13/17
EPA 6010
2.5
25.0
ND
ND
ND
08/22/17
EPA 6010
2.5
25.0
2.8 J
ND
ND
02/05/18
EPA 6010
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
EPA 6010D
2.5
25.0
8.3 J
3.1 J
ND
02/04/19
EPA 6010D
2.5
5.0
2.9 J
2.7 J
-
08/07/19
EPA 6010D
1.3
5.0
1.4 J
2.3 J
ND
Zinc
11/22/96
-
50.0
11.0
ND
-
06/17/97
-
50.0
ND
ND
-
12/01/97
-
50.0
20.0
ND
-
05/20/98
-
50.0
20.0
28.0
-
11/19/98
-
50.0
ND
ND
-
07/21/99
-
50.0
ND
ND
-
11/16/99
-
50.0
ND
ND
-
05/10/00
-
50.0
ND
ND
-
10/26/00
-
50.0
ND
ND
-
04/18/01
-
50.0
ND
ND
-
10/27/01
-
50.0
ND
ND
-
06/13/02
-
50.0
-
-
-
11/19/02
-
50.0
ND
ND
-
06/27/03
-
50.0
ND
ND
-
12/30/03
-
50.0
ND
ND
ND
06/30/04
-
50.0
ND
ND
ND
12/29/04
-
50.0
ND
ND
ND
06/29/05
-
50.0
ND
ND
ND
12/29/05
-
50.0
ND
ND
ND
06/28/06
-
50.0
ND
ND
ND
12/29/06
-
50.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
24.6 B
ND
102
NC 2B = 50 ug/L (03/28/08)
07/08/08
-
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
EPA 6010
10.0
10.0
-
ND
ND
03/10/15
EPA 6010
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
5.0
10.0
7.0 J
ND
ND
08/09/16
EPA 6010
5.0
10.0
ND
ND
ND
02/13/17
EPA 6010
5.0
10.0
ND
5.2 J
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
NC 2B = Hardness Dependant
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
-
08/07/19
EPA 6010D
3.9
10.0
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Hardness, Total(SM 2340B)
02/04/19
EPA 6010D
662
662
57.1
85.3
-
08/07/19
EPA 6010D
131
662
316
460
ND
ORGANICS
Acetone
10/27/01
-
100
168.0 B
337.0 B
479.0
06/13/02
-
100
-
--
--
06/13/02
-
100
-
-
-
11/19/02
-
100
ND
ND
-
06/27/03
-
100
ND
ND
-
12/30/03
-
100
ND
ND
ND
06/30/04
-
100
ND
ND
ND
12/29/04
-
100
ND
ND
ND
06/29/05
-
100
ND
ND
ND
12/29/05
-
100
ND
ND
ND
06/28/06
-
100
ND
ND
ND
12/29/06
-
100
ND
ND
ND
07/12/07
-
100
ND
-
ND
12/19/07
-
100
12.70 B
ND
4.50 J
NC 2B = 2,000 ug/L (03/28/08)
07/08/08
-
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
NC 2B = NE (03/24/10)
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
EPA8260
10.0
100
-
ND
22.0 J
03/10/15
EPA8260
10.0
100
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA8260
10.0
100
ND
ND
ND
08/09/16
EPA8260
10.0
100
ND
ND
ND
02/13/17
EPA8260
10.0
100
ND
ND
ND
08/22/17
EPA8260
10.0
100
ND
ND
ND
02/05/18
EPA8260
10.0
100
ND
ND
ND
08/13/18
EPA8260B
10.0
100
ND
ND
ND
02/04/19
EPA8260B
6.2
25
ND
ND
-
ISTV = 2000 ug/L
08/07/19
EPA 8260D
6.2
25.0
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Chlorobenzene
06/27/03
-
5.0
ND
7.20
ND
12/30/03
-
5.0
ND
ND
ND
06/30/04
-
5.0
ND
ND
ND
12/29/04
-
5.0
ND
ND
ND
06/29/05
-
5.0
ND
ND
ND
12/29/05
-
5.0
ND
ND
ND
06/28/06
-
5.0
ND
ND
ND
12/29/06
-
3.0
ND
ND
ND
07/12/07
-
3.0
ND
-
ND
12/19/07
-
3.0
ND
ND
ND
NC 2B = 130 ug/L (03/28/08)
07/08/08
-
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
EPA 8260
0.23
3.0
-
ND
ND
03/10/15
EPA 8260
0.23
3.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 8260
0.23
3.0
ND
ND
ND
08/09/16
EPA 8260
0.23
3.0
ND
ND
ND
02/13/17
EPA 8260
0.23
3.0
ND
ND
ND
08/22/17
EPA 8260
0.23
3.0
ND
ND
ND
02/05/18
EPA 8260
0.23
3.0
ND
ND
ND
08/13/18
EPA8260B
0.23
3.0
ND
ND
ND
02/04/19
EPA8260B
0.23
1.0
ND
ND
-
08/07/19
EPA 8260D
0.23
1.0
ND
ND
ND
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
NC 2B = NE (03/24/10)
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
EPA 8260
0.11
1.0
-
ND
ND
03/10/15
EPA 8260
0.11
1.0
ND
ND
ND
08/18/15
-
--
Dry
Dry
-
02/16/16
EPA 8260
0.11
1.0
ND
ND
ND
08/09/16
EPA 8260
0.11
1.0
ND
ND
ND
02/13/17
EPA 8260
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
EPA 8260
0.11
1.0
ND
ND
ND
02/05/18
EPA 8260
0.11
1.0
ND
ND
ND
08/13/18
EPA8260B
0.11
1.0
ND
ND
ND
02/04/19
EPA8260B
0.39
1.0
ND
ND
-
08/07/19
EPA 8260D
0.39
1.0
ND
ND
ND
1,4-Dioxane (p-Dioxane)
08/13/18
EPA 8260B Mod.
1.9
2.0
ND
14.1
ND
02/04/19
EPA 8260BMod.
1.9
2.0
ND
ND
-
ISTV = 80 ug/L
08/07/19
EPA 8260D Mod.
1.2
2.0
10.50
22.3
ND
Methylene Chloride
08/09/16
EPA 8260
0.97
1.0
ND
ND
2.20 J
02/13/17
EPA 8260
0.97
1.0
ND
ND
ND
NC 2L = 5 Ng/L (2/5/10)
08/22/17
EPA 8260
0.97
1.0
ND
ND
1.4 C9
02/05/18
EPA 8260
0.97
1.0
ND
ND
ND
08/13/18
EPA8260B
0.97
1.0
ND
ND
6.60
02/04/19
EPA8260B
3.7
5.0
ND
ND
-
ISTV = 11,000 ug/L
08/07/19
EPA 8260D
3.7
5.0
ND
ND
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 9

APPENDIX F: Historical Constituents in Surface Water
Analytes Sample Date EPA Method DL RL SW-1 SW-2 Blanks
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
INS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 213 = North Carolina Surface Water Standards from 15A NCAC 213.0101
ISTV = NC In -stream Target Values (for constituents with no NC 2B).
NE = Not established.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 9 of 9

Appendix G
Historical MINA Parameters

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MAR
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Temperature
12/30/03
°C
15.4
11.1 11.2 12.5 13.6 14.2
-
(FP)
12/19/07
°C
12.3
12.5 13.1 14.4 14.9 14.4
13.3
05/01/13
°C
15.7
13.7 15.1 14.4 14.2 14.2
12.5
08/14/14
°C
17.8
18.0 19.2 19.4 16.8 17.2
16.0
03/10/15
°C
17.3
16.0 15.9 13.8 13.3 13.7
16.1
08/18/15
°C
16.43
17.78 17.79 17.25 16.47 16.64
16.05
02/16/16
°C
14.6
13.8 14.4 14.0 12.0 13.4
13.1
08/09/16
°C
16.4
17.3 19.4 18.2 17.1 16.8
17.9
02/13/17
°C
14.8
14.4 14.9 15.7 14.1 15.3
15.2
08/22/17
°C
17.4
17.9 17.9 17.5 17.4 16.6
17.8
02/05/18
°C
13.06
11.66 13.05 14.46 13.83 14.53
12.25
08/13/18
°C
17.4
21.1 18.2 19.3 20.6 18.4
16.6
02/04/19
°C
13.2
15.5 16.5 14.9 14.5 15.4
13.7
08/06/19
°C
17.0
22.7 17.6 19.9 17.3 18.2
16.0
Resample ->
08/14/19
°C
-
- - - - 24.3
-
pH
12/30/03
SU
7.31
6.54 6.81 6.90 7.24 7.29
-
(FP)
12/19/07
SU
6.89
6.90 7.07 6.87 7.39 6.67
7.64
05/01/13
SU
7.32
6.37 6.61 6.42 6.92 7.13
6.10
08/14/14
SU
5.84
6.36 6.96 6.79 7.00 6.48
5.59
03/10/15
SU
6.11
6.37 6.56 6.30 6.25 6.55
5.68
08/18/15
SU
5.12
6.68 6.48 6.76 7.03 6.78
4.94
02/16/16
SU
6.15
6.15 6.61 6.69 7.14 6.10
6.52
08/09/16
SU
4.79
5.05 5.30 5.06 4.41 5.75
6.46
02/13/17
SU
6.10
6.55 6.76 6.78 6.24 7.37
6.23
08/22/17
SU
6.58
6.46 6.45 6.98 7.53 7.16
7.16
02/05/18
SU
7.11
6.80 7.01 7.33 7.22 7.54
5.53
08/13/18
SU
6.30
6.45 6.64 6.38 7.15 7.03
5.54
02/04/19
SU
6.17
6.44 7.16 6.87 6.07 7.02
5.13
08/06/19
SU
8.84
6.17 6.49 6.69 7.44 7.49
6.79
Resample ->
08/14/19
Su
-
- - - - 6.47
-
Conductivity
12/19/07
pS/cm
96
1,964 1,591 1,245 - -
510
(FP)
05/01/13
pS/cm
111
1,587 1,357 1,150 195 594
69.6
08/14/14
pS/cm
231
1,897 1,534 1,413 522 565
172.6
03/10/15
pS/cm
90
996 1,277 1,186 106 504
114
08/18/15
pS/cm
134
1,630 1,680 1,244 617 534
83
02/16/16
pS/cm
72.4
1,611 1,369 1,234 164 474
78.2
08/09/16
pS/cm
100.7
1,924 1,535 1,475 660 600
95.6
02/13/17
pS/cm
68.0
1,535 1,314 1,155 272 508
89.6
08/22/17
pS/cm
77.1
1,752 1,350 1,446 755 560
175
02/05/18
pS/cm
80.0
1,460 1,247 1,230 676 633
50.0
08/13/18
pS/cm
101.2
2,013 1,608 1,569 870 620
131.2
02/04/19
pS/cm
107.9
1692.0 1266.0 1364.0 276.1 546.0
91.6
08/06/19
pS/cm
113.4
1719.0 1307.0 1287.0 775.0 545.3
98.5
Resample ->
08/14/19
pS/cm
-
- - - - 559
-
Redox Potential
12/30/03
mV
257.2
76.2 207.6 212.7 187.3 123.6
-
ORP
12/19/07
mV
146
45.0 142 134 - -
138
(FP)
05/01/13
mV
111.7
-26.7 55.2 120.5
227.1
08/14/14
mV
115.8
-37.2 86.9 -
-
03/10/15
mV
87.0
0.8 56.3 -
96.7
08/18/15
mV
134.7
-96.3 -68.8 -33.9 -49.9
182.8
02/16/16
mV
111.7
-47.3 16.9 - -
173.4
08/09/16
mV
56.0
-43.1 -6.9
-
02/13/17
mV
87.4
0.8 -16.5
-
08/22/17
mV
102.9
-37.1 87.0
116.7
02/05/18
mV
57.1
29.5 49.4
109.2
08/13/18
mV
117.9
-60.5 -49.3 - 64.4
28.4
02/04/19
mV
197.7
-64.3 132.2 - 9.6 -
281.2
08/06/19
mV
164.7
-69.3 -33.7 171.6 188.6 232.6
231.8
Resample->
08/14/19
mV
-
- - - - 237.6
-
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 1 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Oxygen
12/30/03
mg/L
9.49
4.84 26.19 24.19 15.31 20.17
-
DO
12/19/07
mg/L
-
1.88 1.44 3.21 - -
0.70
(FP)
05/01/13
mg/L
4.40
1.37 1.79 4.65
2.90
08/14/14
mg/L
4.44
3.26 2.48 -
2.80
03/10/15
mg/L
3.84
1.47 1.80
1.85
08/18/15
mg/L
4.95
5.75 1.30 3.79
1.77
02/16/16
mg/L
4.45
3.66 2.51 -
3.72
08/09/16
mg/L
3.17
2.87 2.29
-
02/13/17
mg/L
5.37
3.16 2.14
-
08/22/17
mg/L
5.43
2.24 4.02
5.86
02/05/18
mg/L
8.08
6.61 9.16 -
8.36
08/13/18
mg/L
6.31
3.20 2.35 - 4.80
3.91
02/04/19
mg/L
1.26
1.82 4.17 4.17 -
1.63
08/06/19
mg/L
3.77
0.32 0.26 4.55 5.30 2.76
3.04
Resample ->
08/14/19
mg/L
-
- - - - 1.95
-
Dissolved CO2
12/19/07
mg/L
25
365 175 295
60
(FP)
05/01/13
mg/1-
30.0
245 125 225
45
08/14/14
mg/1-
60.0
390 185 -
75
03/10/15
mg/L
50.0
110 75
50
08/18/15
mg/L
30.0
275 125
60
02/16/16
mg/L
30.0
210 230
20
08/09/16
mg/L
-
185 210
-
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
-
08/13/18
mg/L
-
02/04/19
mg/L
75.0
- 130.0
08/06/19
mg/1-
-
475.0 250.0
Fe, Ferrous (+2)
12/30/03
mg/L
ND
1.5 ND ND 0.22 ND
-
(FP)
12/19/07
mg/L
ND
7.2 ND ND -
0.2
05/01/13
mg/L
0.0
1.0 0.0 0.0
0.0
08/14/14
mg/L
0.0
2.5 0.0 -
0.0
03/10/15
mg/L
0.0
5.3 0.0
0.0
08/18/15
mg/L
0.0
4.5 1.0
0.0
02/16/16
mg/L
0.0
4.0 1.3
0.0
08/09/16
mg/1-
-
3.1 1.0
-
02/13/17
mg/1-
0.0
3.0 1.5
-
08/22/17
mg/L
0.0
3.5 1.5
0.0
02/05/18
mg/L
0.0
4.0 0.5
0.0
08/13/18
mg/1-
0.0
5.5 0.2
-
02/04/19
mg/L
0.0
- 0.0
08/06/19
mg/L
-
3.5 0.5
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 2 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Alkalinity (as CaCO3)
12/30/03
mg/L
9.00 10.0
37.0
800 690 640 68.0 350
-
12/19/07
mg/L
- 5.00
39.0
763 726 619 - -
190
05/01/13
mg/L
1.00 5.00
43.4
757 660 645
10.4
08/14/14
mg/L
1.00 5.00
41.1
784 661 -
14.5
03/10/15
mg/L
1.00 5.00
38.0
744 653
8.8
08/18/15
mg/L
1.00 5.00
37.8
772 664
10.3
02/16/16
mg/L
1.00 5.00
41.2
792 741
8.73
08/09/16
mg/L
1.00 5.00
-
783 629
-
02/13/17
mg/L
1.00 5.00
37.9
753 654
8.79
08/22/17
mg/L
1.00 5.00
42.4
766 678
10.20
02/05/18
mg/L
1.00 5.00
44.4
821 752
7.52
08/13/18
mg/L
1.00 5.00
-
768 722
-
02/04/19
mg/L
1.00 5.00
62.0
856 638
7.02
08/06/19
mg/L
5.00 5.00
-
839 754 - - -
Chloride
12/30/03
mg/1-
0.200 1.00
3.50
280 170 82.0 13.0 44.0
-
12/19/07
mg/L
- 5.00
ND
13.1 297 89.1 - -
7.90
NC 2L = 250,000 Ng/L
05/01/13
mg/1-
0.50 1.00
3.54
258 180 123
2.85
(250 mg/L)
08/14/14
mg/1-
0.50 1.00
5.53
264 144 -
5.00
03/10/15
mg/L
0.50 1.00
3.80
266 194
4.09
08/18/15
mg/L
0.50 1.00
4.69
267 178
3.90
02/16/16
mg/L
0.50 1.00
3.92
274 186
3.24
08/09/16
mg/L
0.50 1.00
-
269 191
-
02/13/17
mg/L
0.50 1.00
3.45
309 215
5.09
08/22/17
mg/1-
0.50 1.00
3.73
318 214
5.86
02/05/18
mg/1-
0.50 1.00
3.92
280 205
2.52
08/13/18
mg/1-
0.50 1.00
-
221 165
-
02/04/19
mg/1-
0.50 1.00
3.42
221 147
4.52
08/06/19
mg/L
2.40 4.00
-
203 154 -
-
Dissolved Hydrogen
05/01/13
nM
0.074 0.60
0.400
0.630 0.610 0.500
0.470
08/14/14
nM
0.13 0.60
1.4
1.6 5.4 -
1.4
03/10/15
nM
0.13 0.60
1.2
1.4 1.4 1.0
1.4
08/18/15
nM
0.13 0.60
1.7
2.2 1.7 -
1.5
02/16/16
nM
0.13 0.60
2.0
1.7 1.9
1.5
08/09/16
nM
0.13 0.60
-
1.5 1.6
-
02/13/17
nM
- -
- -
08/22/17
nM
02/05/18
nM
08/13/18
nM
02/04/19
nM
0.65 1.0
6.7
7.6 7.4
6.8
08/06/19
nM
0.75 1.0
-
2.0 5.4
-
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 3 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Nitrate-N
12/30/03
mg/L
0.020 0.050
0.120
ND ND ND ND 0.13
-
12/19/07
mg/L
- 0.100
ND
ND ND ND -
13.0
05/01/13
mg/L
0.001 10.0
0.163
ND ND ND
3.58
08/14/14
mg/L
0.001 10.0
0.115 J
ND ND
2.02 J
03/10/15
mg/L
0.001 10.0
0.252J
ND ND
2.56J
08/18/15
mg/L
0.001 10.0
0.124 J
ND ND
3.27 J
02/16/16
mg/L
0.001 10.0
0.36 J
ND ND
2.54 J
08/09/16
mg/L
0.001 10.0
-
ND ND
-
02/13/17
mg/L
0.001 10.0
0.248 J
0.189 J ND
2.63 J
08/22/17
mg/1-
0.001 10.0
0.118 J
0.0186 J 0.0451 J
4.06 J
02/05/18
mg/L
0.010 10.0
0.310 J
ND 0.0120 J
1.15 J
08/13/18
mg/L
0.050 0.1
-
ND ND
-
02/04/19
mg/1-
0.050 0.1
0.196
ND 0.113
6.5
08/06/19
mg/L
0.010 0.0
-
ND ND
-
Sulfate
12/30/03
mg/L
0.0600 2.00
ND
ND ND 2.60 9.60 9.00
-
12/19/07
mg/L
- 5.00
ND
ND ND ND - -
36.8
NC 2L = 250,000 Ng/L
05/01/13
mg/L
1.00 250
ND
ND ND 4.69
10.7
(250 mg/L)
08/14/14
mg/L
1.00 250
1.08 J
1.2 J ND -
5.84 J
03/10/15
mg/L
1.00 250
1.52 J
1.13 J 1.52 J
7.04 J
08/18/15
mg/L
1.00 250
1.56 J
1.31 J 2.49 J
524 J
02/16/16
mg/L
1.0 250
1.5 J
1.7 J 1.8 J
10.0 J
08/09/16
mg/1-
1.00 250
-
1.22 J 1.75 J
-
02/13/17
mg/L
1.00 250
1.53 J
1.59 J 1.78 J
11.9 J
08/22/17
mg/L
1.00 250
ND
ND 0.626 J
11.2 J
02/05/18
mg/L
0.500 250
ND
ND 0.627J
7.48J
08/13/18
mg/1-
0.500 250
ND
ND 0.630 J
-
02/04/19
mg/1-
0.500 250
1.15
ND 1.10
6.75
08/06/19
mg/L
0.500 1
-
ND 0.711.1
Sulfide
08/14/14
mg/L
0.05 1.00
ND
ND ND
ND
03/10/15
mg/L
0.05 1.00
ND
ND ND
ND
08/18/15
mg/L
0.05 1.00
ND
ND ND
1.0
02/16/16
mg/L
0.05 1.00
ND
ND ND
ND
08/09/16
mg/L
0.05 1.00
-
ND ND
02/13/17
mg/L
0.05 1.00
ND
ND ND
08/22/17
mg/L
0.05 1.00
ND
ND ND
02/05/18
mg/L
- -
08/13/18
mg/L
- -
02/04/19
mg/L
0.05 1
ND
ND ND
ND
08/06/19
mg/L
0.05 0.1
-
ND ND
-
Total Organic Carbon
12/19/07
mg/L
- 1.0 *
2.9
54.3 23.2 17.2
7.20
05/01/13
mg/1-
0.50 1.00
2.24
29.5 30.0 19.4
5.74
08/14/14
mg/1-
0.50 1.00
ND
229.00 25.5 -
8.39
03/10/15
mg/1-
0.50 1.00
0.781.1
34.8 9.5
1.88
08/18/15
mg/1-
0.50 1.00
0.917.1
32.9 9.86
27.80
02/16/16
mg/1-
0.50 1.00
1.500
27.6 8.46
40.90
08/09/16
mg/L
0.50 1.00
-
29.4 9.53
-
02/13/17
mg/L
0.50 1.00
ND
28.5 9.72
1.36
08/22/17
mg/L
0.50 1.00
ND
29.1 9.92
1.71
02/05/18
mg/L
0.50 1.00
ND
25.9 11.4
4.24
08/13/18
mg/L
0.50 1.00
ND
25.8 10.2
ND
02/04/19
mg/L
0.50 1.00
ND
27.9 8.02
1.6
08/06/19
mg/L
2.50 5.00
-
33.3 15.10
-
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 4 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MAR
MW-2R
MW-3R
MW-4
MW-5 MW-6
NES-1
Biochemical Oxygen Demand
08/14/14
mg/L
2.00
2.00
ND
83.4
2.49
BOD (5-day)
03/10/15
mg/L
2.00
2.00
2.55
10.6
ND
ND
08/18/15
mg/L
2.00
2.00
2.22
11.8
2.0
2.00
02/16/16
mg/L
2.00
2.00
ND
60.0
6.6
ND
08/09/16
mg/L
2.00
2.00
-
11.6
ND
02/13/17
mg/L
2.00
2.00
ND
9.501
ND
ND
08/22/17
mg/L
2.00
2.00
ND
ND
ND
ND
02/05/18
mg/L
2.00
2.00
ND
5.6
ND
ND
08/13/18
mg/L
2.00
2.00
ND
71.8
3.56
ND
02/04/19
mg/L
2.00
2.00
ND
7.5
ND
ND
08/06/19
mg/L
2.00
2.00
8.0
ND
-
Chemical oxygen Demand
08/14/14
mg/L
12.5
25.0
ND
132.0
ND
50.00
COD
03/10/15
mg/L
12.5
25.0
15.01
235.0
96.0
ND
08/18/15
mg/L
12.5
25.0
25.0
110.0
756.0
25.00
02/16/16
mg/L
12.5
25.0
ND
295.0
50.0
ND
08/09/16
mg/L
12.5
25.0
-
131.0
50.0
-
02/13/17
mg/L
12.5
25.0
17.0 J
119.0
43.0
22.0 J
08/22/17
mg/L
12.5
25.0
ND
121.0
74.0
16.0 J
02/05/18
mg/L
12.5
25.0
ND
113.0
51.0
46.0
08/13/18
mg/L
12.5
25.0
ND
112.0
73.9
ND
02/04/19
mg/L
12.5
25.0
ND
101.0
26.5
ND
08/06/19
mg/L
12.5
25.0
123.0
45.5
Dissolved Ethane
12/30/03
mg/L
0.0002
0.0010
ND
ND
ND
ND
ND ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
ND
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
0.0036J
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
1.6 J
2.6 J
02/13/17
mg/L
-
-
-
-
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.0100
2.0 J
.0041 J
Dissolved Ethene
12/01/03
mg/L
0.0003
0.0010
ND
ND
ND
ND
ND ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
0.0017
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
ND
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
ND
ND
02/13/17
mg/L
-
-
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND ND
ND
08/06/19
mg/L
0.0012
0.0100
-
ND
.0016 J
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 5 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
0.0002 0.0010
ND
0.660 0.130 0.0099 0.0010 ND
12/19/07
mg/L
- 10.0
ND
0.116 0.186 ND -
ND
05/01/13
mg/L
0.0033 0.0066
ND
0.0379 0.100 0.0337
ND
08/14/14
mg/L
0.0033 0.0066
ND
1.2900 0.284 -
ND
03/10/15
mg/L
0.0033 0.0066
0.0072
0.9960 0.158
ND
08/18/15
mg/L
0.0033 0.0066
0.0027
2.16 0.316
0.0013
02/16/16
mg/L
0.0033 0.0066
0.007 J
0.87 0.098
0.0016 J
08/09/16
mg/L
0.0033 0.0066
-
1.85 0.206
-
02/13/17
mg/L
- -
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
0.001 0.0010
ND
27.2 ND ND ND ND
ND
08/06/19
mg/L
0.0034 0.0100
-
5.0 0.5 -
-
Pyruvic Acid
12/19/07
mg/L
- -
2.50
ND 1.50 2.00
1.20
05/01/13
mg/L
2 10
ND
ND ND ND
ND
08/14/14
mg/L
0.77 10
ND
ND ND
ND
03/10/15
mg/L
0.77 10
0.41J
0.41J 0.41J
0.41J
08/18/15
mg/L
0.77 10
ND
ND ND
ND
02/16/16
mg/L
0.77 10
ND
ND ND
ND
08/09/16
mg/L
0.77 10
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
Lactic Acid
12/19/07
mg/L
ND
5.40 11.9 3.10
ND
05/01/13
mg/L
2.3 25
ND
ND ND ND
ND
08/14/14
mg/L
2.5 25
4.2 J
ND ND
ND
03/10/15
mg/L
2.5 25
ND
ND ND
ND
08/18/15
mg/L
2.5 25
ND
ND ND
ND
02/16/16
mg/L
2.5 25
ND
ND ND
ND
08/09/16
mg/L
2.5 25
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.043 0.20
ND 0.087 J
Acetic Acid
12/19/07
mg/L
ND
ND ND ND
ND
05/01/13
mg/L
1.8 5
ND
ND ND ND
ND
08/14/14
mg/L
0.81 5.0
ND
ND ND
ND
03/10/15
mg/L
0.81 5.0
ND
ND ND
ND
08/18/15
mg/L
0.81 5.0
ND
ND 0.97 J
ND
02/16/16
mg/L
0.81 5.0
ND
ND ND
ND
08/09/16
mg/L
0.81 5.0
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.028 0.10
0.097 J 0.34
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 6 of 7

Appendix G: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Propionic Acid
12/19/07
mg/L
ND
63.7 38.3 12.8
ND
05/01/13
mg/L
1 5
ND
ND ND ND
ND
08/14/14
mg/L
0.66 5.0
ND
ND ND
ND
03/10/15
mg/L
0.66 5.0
ND
ND ND
ND
08/18/15
mg/L
0.66 5.0
ND
ND ND
ND
02/16/16
mg/L
0.66 5.0
ND
ND ND
ND
08/09/16
mg/L
0.66 5.0
ND ND
08/22/17
mg/L
- -
02/13/17
mg/L
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.004 0.10
0.0058 J 0.0045 J
Butyric Acid
12/19/07
mg/L
ND
ND ND ND
ND
05/01/13
mg/L
0.87 5
ND
ND ND ND
ND
08/14/14
mg/L
0.70 5.0
ND
ND ND
ND
03/10/15
mg/L
0.70 5.0
ND
ND ND
ND
08/18/15
mg/L
0.70 5.0
ND
ND ND
ND
02/16/16
mg/L
0.70 5.0
ND
ND ND
ND
08/09/16
mg/L
0.70 5.0
ND ND
02/13/17
mg/L
- -
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
08/06/19
mg/L
0.011 0.10
0.22 ND
Formic Acid
08/06/19
mg/L
0.086 0.50
1.10 1.60 -
-
Total Volatile Fatty Acids
12/19/07
mg/L
- -
2.50
69.10 51.70 17.90
1.20
(sum of above 6 acids)
05/01/13
mg/L
ND
ND ND -
ND
08/14/14
mg/L
4.2 J
ND ND
ND
03/10/15
mg/L
ND
ND ND
ND
08/18/15
mg/L
ND
ND 0.97 J
ND
02/16/16
mg/L
ND
ND ND
ND
08/09/16
mg/L
ND ND
02/13/17
mg/L
08/22/17
mg/L
02/05/18
mg/L
08/13/18
mg/L
02/04/19
mg/L
- -
08/06/19
mg/L
1.32 1.94
NOTES:
DL = laboratory detection limit. mg/L = milligrams per liter °C = degress Celcius
RL = laboratory reporting limit. mV = millivolt pS/cm = micro-Siemen per centimeter
NO = not detected above detection limit. SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL. nM = nano -Molar
= not analyzed or not applicable.
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 7 of 7