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MO-3655_9362_CA_MRP_20190930_Semi-Annual Monitoring Report
MONITORING REPORT CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, CABARRUS COUNTY, NORTH CAROLINA GROUNDWATER INCIDENT NO.9362 Shield Project No. 1090032 Period: August -September 2019 Responsible Party: Security Oil Company, Inc. PO Box 5028 Concord, NC 28027 Contact: Bale Carpenter (704) 786-7235 Site Risk Classification: High (I65D) Land Use Category: C om merc is llRes identi al Site Latitude: 35' 26' 26" North Site Longitude: 800 43' 40" West PKv i"n P. �St Staff Geologist Consultant. Shield Engineering, Inc. 4301 Taggart Creek Road Charlotte, NC 28208 Contact: Kevin P. Stachura (704)394-6913 Release Discovered: December 1994 Quantity Released: Unknown Property Owner: Prime Business LLC A NC 1534 Copperplate Road Charlotte, NC 28262 Contact: Shailesh Panara (980) 722-3751 Suspected Release Source(s): One 3,000-gallon gasoline UST Release Cause: Possible spillage/leak from UST Thomas Witner, L.G..,— Principal NC License #916 ", :V - . s L 916 September 30, 2019 nnrr VNGINEEEIINC. TABLE OF CONTENTS Parma. 1.0 ❑ISCUSSION OF SAMPLING ACTIVITIES................................................................1 2.0 CONCLUSIONS AND RECOMMENDATIONS...........................................................4 3.0 STATEMENTS AND CERTIFICATION........................................................................5 4.0 LIMITATIONS..... ....... ........ ........................................................................................... 6 FIGURES Figure 1: Site Location Map Figure 2: Site Map Figure 3: 1,500' Radius Map Figure 4: Groundwater Elevation Contour Map Figure 5: Benzene Isoconcentration Map Figure 6: MTBE Isoconcentration Map Figure 7: Naphthalene Isoconcentration Map TABLES Table 1: Summary of Water Supply Well and Receptor Information Table 2: Summary of Well Construction and Historical Groundwater Elevation Data Table 3: Summary of Groundwater Analytical Results (August 12, 2019) Table 4: Summary of Historical Groundwater Analytical Results GRAPHS Graphs): Concentration vs. Time/ Hydrograph APPENDICES Appendix A: Calibration and Field Measurement Log Appendix B: Laboratory Report — Groundwater Samples 1-1Trojects1200911090032-01 Carl's Country Store\ReportsWR 9-20191MQ-3655_9362_CA_MRP_20190930_Semi-Annual Monitoring Report.doc Carl's Country Store Concord, Cabarras County, North Carolina GWI#: 9362 1.0 DISCUSSION OF SAMPLING ACTIVITIES 1.1 Site Location Refer to Figures): Figure 1 and Figure 2 1.2 Summary of Analytical Results and Free Product Thickness[s): 1.2.1 Date(s) of Sampling Event: August 12, 2019 1.2.2 Existing Area Receptors: Monitoring Report September 30, 2019 Page 1 During the April 2009 sampling event, Shield personnel were informed by the store attendant that water supply well WSW-i had been abandoned. Also, during the February 2009 sampling event, supply wells WSW-3 and WSW-4 were reported by community residents as being interconnected and serving the Hillsdell Drive and Odell Circle community. ■ A receptor survey update was performed by Shield personnel on March 14, 2019 in order to review the status of known receptors and present information on new receptors, if applicable. Water supply wells WSW-2, WSW-8, WSW-13 and WSW- 18 were not observed and appear to have been destroyed or abandoned due to parcel consolidation and redevelopment. Water supply well WSW-15 was abandoned as reported by the property owner. An additional receptor, WSW-24, was added as the property owner reported that there is a well in use on that property. Refer to the following Table and Figure for additional information and locations of area receptors within a 1,500-foot radius of the site. Refer to Table: Table 1 Refer to Figure: Figure 3 1.2.3 Groundwater Elevation Data: Historically, groundwater flows generally towards the west with a groundwater elevation high around monitoring well MW-6. Based on the groundwater elevations determined during the August 2019 sampling event, the groundwater flow direction is generally towards the west from monitoring well MW-6 with a slight convergence around MW-5. Groundwater elevation data from the August 12, 2019 sampling event is included in the following Table and Figure: Refer to Table: Table 2 Refer to Figure: Figure 4 Carl's Country Store Concord, Cabarrus County, North Carolina GWI#; 9362 1.2.4 Free Product: a Free product detected during this reporting period?: No Free product plume size and location: Not Applicable (NIA) • Free product recovered during this period: NIA 1.2.5 Field Measurements: Monitoring Report September 30, 2019 Page 2 Field measurement parameters were collected from each sampled monitoring well at the time of sample collection using a YSI Pro Plus meter. Parameters recorded include dissolved oxygen (DO), pH, specific conductivity (us/cm), temperature (T), and oxidation reduction potential [ORP (mVolts)]. Refer to Appendix: Appendix A Carl's Country Store Concord, Cabamts County, North Carolina G WI#: 9362 1.2.5 Groundwater Analytical Results: Monitoring Report September 30, 2019 Page 3 a Sampled points and analytical methods: The following monitoring wells and other points were sampled during this reporting period. Sampled Points and Analytical Methods for this Reporting Period Based on CAP and/or NORR Related Pre -Approval Task Authorization Sampling Requirements Type Points Sampled during this Reporting Analytical Method(s) Period 12* ■ EPA Method 6200B Monitoring Wells (MW-1, MW-2, MW-4 through MW-7, (including MTBE, IPE, & MW-9, MW-10, DMW-1, and DMW-3 EDB, 5 Oxygenates, Ethanol) through DMW-5 Water Supply Wells 1 • EPA Method 6200E WSW-9 * Per the North Carolina Department of Environmental Quality (NCDEQ) pre -approval. a Laboratory Used: Pace Analytical Services, Inc., Huntersville, NC Current groundwater analytical data: Refer to the following Table, Figures, and Appendix for current groundwater analytical data. Refer to Table: Table 3 Refer to Figure: Figure 5 through Figure 7 Refer to Appendix: Appendix B Historical groundwater analytical data: Refer to the following Table and Graphs for historical groundwater analytical data. Refer to Table: Table 4 Refer to Graph(s): Concentration vs. Time/ Hydrograph Carl's Country Store Monitoring Report Concord, Cabarrus County, North Carolina September 30, 2019 G W 1#: 9362 Page 4 • Predictive Rate of Contaminant Transport_ Refer to the 1993 Integrity Environmental Consultants Comprehensive Site Assessment and the Corrective Action Plan (CAP) dated October 19, 2012 completed by Shield Engineering, Inc. Contaminant transport is typically in the same direction as groundwater flow, but with a slower velocity. Refer to the following Tables and Figures: Refer to Table(s): Table 2, Table 3, and Table 4 Refer to Figure(s): Figure 4 through Figure 7 1.2.6 Other Field Data Collected: ■ No other field data was collected. 2.0 CONCLUSIONS AND RECOMMENDATIONS 2.1 Conclusions: • Dissolved phase petroleum constituent compounds were detected in concentrations exceeding 2L Standards and/or Interim Maximum Allowable Concentrations (IMACs) in MW-2, MW-4, MW-5, MW-6, MW-10, DMW-1, DMW-3, DMW-4 and DMW-5 during this reporting period. ■ Overall, constituent of concern (COC) concentrations in monitoring wells MW4, MW-5, and MW-6 have generally decreased since the previous sampling event in August 2018. CDC concentrations have generally increased in monitoring wells MW- 2, MW-10, DMW-1, DMW-3, DMW-4 and DMW-5 since the previous sampling event in February 2019. • In water supply well WSW-9, no COCs were reported above the laboratory detection limits. 2.2 Recommendations: • Continue sampling of groundwater on a semi-annual basis in accordance with the December 5, 2013 Notice of Regulatory Requirements. The next semi-annual sampling event will be in February 2020. Carl's Country Store Concord, Cabarrus County, North Carolina GWI#; 9362 3.0 STATEMENTS & CERTIFICATION Monitoring Report September 30, 2019 Page 5 1 Enter the date the monitoring report was due. 9/30/2019. Will this report be submitted the established due date? 4VESafter 2 Was any required information from the above template missing from this report? IF the answer to question # I or# 2 is "YES", please provide additional information in this cell to explain what was missing and why. 3 If applicable, will any of the proposed attenuation milestones under the schedule YES NO approved in the Corrective Action Plan not be met? (within a reasonable margin o,'error) IF the answer to question #3 is "NO", skip to the certification under #6 below. IF the answer to question #3 is "YES", please generally describe in this cell the possible reason(s) and outline proposed remedies. (This should be described in more detail in the report text above.) 4 Does any known or suspected source zone soil contamination or free product remain YES NO outside of the assessed area that could be inhibiting natural attenuation? S Has there been an unexpected increase in contaminant mass sufficient to suggest a YES NO potential new release from a separate onsite or offsite source? IF the answer to either question #4 or #5 is "YES", generally describe in this cell any actions recommended to further assess or clean up this known or suspected source. (This should be described in more detail in the report text above.) G Certification: 1, Thomas Witner, a Professional Geologist for Shield Engineering, Inc., do certify that the information contained in this report is correct and accurate to the best of my knowledge. ,�`tF,�isa►srrserr r Z-3E AL o awl = 916 'j*-! ,? a.ryry//1, '' If Ot ay1/' \ n �~ S f (Affix Seal and Signature) i� . •`� Shield Engineering, Inc. is licensed to practice geology and engineering in North Carolina The certification number of the company or corporation is C-170(Geology) and F-0856 (Engineering). Cart's Country Store Monitoring Report Concord, Cabarrus County, North Carolina September 30, 2019 GWI#: 9362 Page 6 4.0 LIMITATIONS Shield has performed environmental services at the subject site on behalf of Security Oil Company, Inc. Shield has performed this scope of work as an independent contractor/consultant using reasonable care and skill in accordance and consistent with customary industry standards of engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of care that can be applied to measure Shield's performance of the work. No other warranty, expressed or implied, is made or intended by Shield. The report has been prepared for the exclusive use by Security Oil Company, Inc. All recommendations, findings, and conclusions made by Shield have been made to the best of Shield's knowledge, opinion, and belief, based upon information obtained during this scope of work and is limited by the scope nature and type of services as agreed upon between Security Oil Company, Inc. and Shield. Conclusions are provided with the understanding that Shield is presenting information and not rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the responsibility of Security Oil Company, Inc., under advice of its counsel, to notify the appropriate federal, state, or local public agencies as required by law; or otherwise to disclose in a timely manner, any information that may be necessary to prevent damage to human health, safety, or the environment. Compliance with recommendations provided as part of this report in no way assures compliance with federal, state, and/or local laws, regulations, and/or requirements. Analytical data has been obtained. from Pace Analytical Services. This information, to the extent that it was relied on to generate this report, is assumed to be correct and complete. The work performed in conjunction with this report and the data developed are intended as a description of available information at the dates and specific Iocations given. Shield is not responsible for inspecting, examining, or reporting findings or recommendations with respect to any conditions that were knowingly or unknowingly withheld, concealed, hidden, or in any way not disclosed or observable at the time of this scope of work. FIGURES N GRAFW 5MA u r,aw t,rloa SCALE: 1 m. i, U00 f[. 77 SOURCE: NATIONAL GEOGRAPHIC USGS TOPO, 7.5 MINUTE MAP SERIES, CABARRUS COUNTY, NORTH CAROLINA I CREEIf ROR6 mWL01 rE• N� sax00 SHIELDM, M4 co"I w aw a".am axe n, ,ENGINEERING, lNC. •,"• `'"'d'"°'"••'�^� mm SITE LOCATION MAP CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SHIELD #1090032 DATE : 06/11 /09 1 DRAWN BY: RBS SCALE : AS SHOWN I FIGURE: 1 x N 1 GRAVEL PARKING , f f GRAVEL PARKINnMW-6 r SjOsE 0MW-5 ®MW-7 56-9 55 1( 8.6 B 1, ASPHALT SB-14 r-- MW•4 58-1 ' SB-17 SB-14 B 8.1 FORMER / +5 LIST PIT / MW DMW 54k 1, / TSB-13 Q�OMW ' In SB-16+ MW-2 D W-10 ~ ~ , `6-1 8, ®DMW-3 30' R/W FROM L (APPROXIMATE) LEGEND - RIGHT OF WAY (RIW) ® TYPE II MONITORING WELL TYPE III MONITORING WELL $ SOIL BORING LOCATION ■ APPROXIMATE LOCATION OF SOIL BORING COMPLETED BY INTEGRITY ENVIRONMENTAL CONSULTANTS, A.C. (]EC) AS PRESENTED IN FIGURE 7 - CONTAMINATED SOIL LOCATION IN THE CORRECTIVE ACTION PLAN REPORT BY IEC DATED JUNE 1993. NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5-12. 2. ALL LOCATIONS ARE APPROXIMATE. 3. SB-8 - SB-12 WERE COMPLETED ON 317/11. 58-13 Et SB-14 WERE COMPLETED ON 8/ 11 /12. SB-15 - SO-17 WERE COMPLETED ON 1141 1 I l ®MW-9 l l l ASPHALT l B-7 MW-1 D Qvt� l MW-N I s�r l CONCRETE DCURRENT l ASPHALT ■B-3W 10 1 OAVIflSON HIGHyyAY fN.0 HIGHWAY 73) GRAPHIC SCALE 0 10 ZD 30 SCALE: 1 in. = 30 ft. x SHIELDROAD SITE MAP CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SM1ELD #1090032 DATE : 3/21/2018 DRAWN BY: AGH SCALE: AS SHOWN FIGURE: 2 N / r r r r GRAVEL PARKING r r' rr �- r r GRAVEL PARKING 7 I 1 1 1 ® �Wt9 1 80.30" ` - 1 p� l ' L ! � � a 4 00 v }y ASPHALT � n x o .*�— 4r I ®Mwa .1iA- r` ■ [ao.tal' - i MW- v ir l 72 ASPHALT Jf � O� MW- ,a '6' j �'- , '8' w Mlr 1 @� FORM UST PI SVE-1 ± i+ �ONCRETE �'DM W-3 DMW•5 -4 [74.9�1 •,J 180.001 �VICURRENT�[7 `+a)-- f LIST PIT ! l ASPHALT D w ` )� ®DMW [80.171 MW-1O l (80,37) 30' RIW FROM € (APPROXIMATE) DAVIDSON HIGHyy AY ~ �1 (N.C. HIGHWgYr3) LEGEND — RIGHT OF WAY {RIW} ® TYPE II MONITORING WELL GRAPHIC SCALE a to 20 30 TYPE III MONITORING WELL (ft) FEET SCALE: 1 in- = 30 ft. jao.461 GROUNDWATER ELEVATION (ft) [89•17] GROUNDWATER ELEVATION (ft) NOT USED IN CONTOURING — — — — GROUNDWATER ELEVATION ft CONTOUR LINE (r CKARL cou+Tc2e�csonn � 2� SHIELD ESTIMATED GROUNDWATER FLOW DIRECTION Mlm4mM M&3% 6m ho ENCa1NEEF?ING, INC "" "•°° "'° °"" (NM) NOT MEASURED GROUNDWATER ELEVATION NOTES: CONTOUR MAP 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5-12. CARL'S COUNTRY STORE 2. ALL LOCATIONS ARE APPROXIMATE. 8952 DAVIDSON HIGHWAY 3. GROUNDWATER INFORMATION PRODUCED BY SHIELD PERSONNEL. CONCORD, NORTH CAROLINA 3. GROUNDWATER ELEVATION MEASURED ON 08112/2019. SHIELD #1090032 4. GROUNDWATER LEVELS ASSUME REFERENCE TOP OF CASING ELEVATION DATE : 9/25/2019 DRAWN BY: IMPS AT MW-1 OF 100 FEET. 5. GROUNDWATER CONTOUR INTERVALS AS SHOWN SCALE : AS SHOWN FIGURE: 4 �~ N // 1\ i GRAVEL PARKING , 1 MW-9i. r r GRAVEL PARKING / SRO ASPHALT 100,W-51i �M -6 I , ® 1 l MW-1 1 ® MW-7 1 1 (ND) ASPHALT NW-8 `{ SE 1 M6��®, r FORMER i S) UST PIT + + CONCRETE MW-3 INS} I3h�VW 1 [NDI4�-J , CURRENT UST PIT L ASPHALT l l 1 W-1 N41 DMwI-3 1 1. [61.41111- 30' RIW FROM E (APPROXIMATE) LEGEND DAVIDSOty HIGHWAY (N.C. HIGHWAY 731 RIGHT OF WAY (RIW) GRAPHIC SCALE ® TYPE II MONITORING WELL D ,0 3a sa TYPE Ili MONITORING WELL SCALE: 1 in. a 30ft. (ug/L) MICROGRAMS PER LITER (213) BENZENE CONCENTRATION (ug/L) [61.4] BENZENE CONCENTRATION (ug/L) NOT USED 1N — �— �- —� CONTOURING BENZENE 15OCONCENTRATION CONTOUR LINE (uglL) SHIELD CmAluo7 NG zm$ M& 41013 iCREIXROAD „*,„ o4aewee� (ND) NOT DETECTED AT OR ABOVE THE METHOD DETECTION ENGINEERING, INC. mvsRe We yntry a. LIMIT SPECIFIED IN THE LABORATORY REPORT. BENZENE ISOCONCENTRATION MAP (NS) NOT SAMPLED NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7-5-12. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 0811212019. 4. CONTOUR INTERVALS AS SHOWN. m CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SHIELD #1090032 DATE : 9/25/2019 DRAWN BY: KPS SCALE : AS SHOWN FIGURE: 5 MW-7 (ND) N / 1 rr 1 / GRAVEL PARKING , r r - r % GRAVEL PARKING l Mw LEGEND MW-60 1 , ASPHALT SVE- , (N5} �� r f 1 i ® MW-91 (ND) 1 I IASPHALT 1 %, N MW-5 4{ 148) t `- 'd i �f{ l iN I MW-1 IND) I MW-81 INS) �mry 9 FORMEP Ip I 5 41 LUST IT +4 o b CONCRETE l pND5 J ll mk-Z ! CURRENT �lt UST PIT I ASPHALT [�V i DMW-3 l 11�_3S ®Mw-10 y 30' R/W FROM 4. (APPRCXIMATE) — RIGHT OF WAY (RIW) 44 TYPE II MONITORING WELL ® TYPE III MONITORING WELL (ug/L) MICROGRAMS PER LITER MTBE METHYL TERT-BUTYL ETHER 11,350) MTBE CONCENTRATION (ug/L) (14.33 MTBE CONCENTRATION (ug/L) NOT USED IN CONTOURING — — — — MTBE ISOCONCENTRATION CONTOUR LINE (US/L) [ND} NOT DETECTED AT OR ABOVE THE METHOD DETECTION LIMIT SPECIFIED IN THE LABORATORY REPORT. (NS) NOT SAMPLED NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEYING DATED 7.5-1 z. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 0811212019. 4. CONTOUR INTERVALS AS SHOWN. DAVI N FfIGyWAY 1 ~ fN.C, FfIGyWRY 731 GRAPHIC SCALE 0 1D PO 30 SCALE: 1 in. = 30 ft. S'I�IELD� �;��"�R°� ENGINEERING, INC. MTBE ISOCONCENTRATION MAP CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SHIELD #1090032 DATE : 9/25/2019 DRAWN BY: KPS SCALE ; AS SHOWN FIGURE: 6 M � 1 � r GRAVEL PARKING , r _ i f GRAVEL PARKING ® MW.7 (ND) LEGEND MW-b 0 (ND) I MW-9� cNDy I 1 ASPHALT if 0MW65 y MW , ASPHALT SVE-1 M1N-4 INS) [NO] ® F ' U5TTF DMW-5 + Mw- DMW•4 IND) ~VJDMW [NDI 30' R/W FROM i (APPROXIMATE) v — RIGHT OF WAY (RIW) ® TYPE II MONITORING WELL ® TYPE III MONITORING WELL (ug/L) MICROGRAMS PER LITER (34.6) NAPHTHALENE CONCENTRATION (ug/L) [ND] NAPHTHALENE CONCENTRATION (ug/L) NOT USED IN CONTOURING — — — — NAPHTHALENE ISOCONCENTRATION CONTOUR LINE (ug/L) IN 0) NOT DETECTED AT OR ABOVE THE METHOD DETECTION LIMIT SPECIFIED IN THE LABORATORY REPORT. Mw•s Q {HS) � + \ CONCRTTA 1, �, r CURkN) UST PIT\ \ � ` ASPHALT �MW10 1� �1 DAVtDSON HIG ~ ~ NwAy fN.r. HIGffWAY 73) (NS) NOT SAMPLED NOTES: 1. SITE MAP BASED ON SURVEY PREPARED BY DEADMON SURVEY}NG DATED 7-5-12. 2. CONTOUR INTERVAL AS SHOWN. DATE 3. ALL LOCATIONS ARE APPROXIMATE. 4. GROUNDWATER SAMPLES COLLECTED ON 08/1212019. SCALE : GRAPHIC SCALE 0 10 2d 30 SCALE: 1 in. = ]Oft. SHIELDCREEK ENGWEERWG, INC. NAPHTHALENE CARL'S COUNTRY STORE 8952 DAVIDSON HIGHWAY CONCORD, NORTH CAROLINA SMECD JET 090G32 9/25/2019 DRAWN BY: KFs' AS SHOWN FIGURE : 7 TABLES TABLE 1 - SUMMARY OF WATER SUPPLY WELL AND RECEPTOR INFORMATION Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Cabarrus County, North Carolina Facility 10 Number: 0.007470 Incident Num be Jr. 9362 Wall Address and Parcel Photo Well Type of Casing Well Screen Interval Olatanca from Well ID Number Well Owner and Address Number Well Use Depth Well Depth (feet bit) source area of feel bla release !feet} VV5W-1 6%2 Davidson Highway VSP Business, LLC Unknown Abandoned Unk Unk Unk Ursk �250 (Subject P 1534 Copperplate Road CNulutra NC 282S2 Former 1Silo Odell School Abandoned -Parcel WSW-2 Road 4991-59-6415 OcWl 73 Inveatmanis LLC Unkrtowr Candevelopm ono Unk Unk Unk Unk 450 Former Ba45 Davidson 1151 Biscayne Or. Concord, NC 28027 Redevelopment Hi hwa 49B759-9347 2092l880O Odell School Road Wailer D. Dennis 4652-50.34a1 2082 WmIE Schoni Road Concord, NC 26027 Unknown Community Well - Serves 6 Lots Unk Unk Unk Unk 650 2140 Odell School Road 9Wdiam Andrew and Unda Mark 2140 Udkriorm Drinking NA NA NA NA NA 4682-50-27M Otlell Smoot Road Concord NC 26027 2114 Odell Saiml Road Dean D Evafiardl 2114 Uni,ocwn prirlkkg NA NA NA NA NA VVSW.3 4682-50-3524 Odell School Road Concord NC 28027 2098 Well School Road Thomas R and Sandra Smllh unknown Drinkkg NA NA NA NA NA 4692.50.4281 20M Odell School Road Concord NC 28027 2010 Odell School Road Nancy Brown Wrlipp[B 2010 Unknovrn Ddnkhng NA NA NA NA NA 4602.50.5151 Odell School Road Concord. NC 28027 2000 Odell Schoo! Road Ooeli Lions Club Unknown prinking NA tali NA f4A NA 4502-50.0001 200 Odell School Road Concod NC 20027 9730 Hlllsdell Drive todd G and Sharon Giblitseo known Cammunity Well Serves 12 Unk Unk Unk Unit 620 4alllz%6273 5W7 Hillsdell Olive Concod NO 26027 Known Leta 6835 H11lsdall Drlva 4682- George P Lawrence NA prinking NA NA NA NA NA 50-9322 8835 Hilledeir IX Cancers. NC 28027 9766 F llisdel€ Drive Darlene H Easley NA Drinking NA NA NA NA NA 4682-60-1472 8785 Hilledall !alive Concord NO 28027 87M HiBsdall Drive Nicholas R and Sally S P*ce NA Drinking NA NA NA NA NA 4682.604522 8736 Hil€sdell Drive Concord NC 28027 8711 Hr6sde11 Onvo Rosen K and Dorothy J Park NA Drinking NA NA NA NA NA Asn-so.5546 0711 Hilisdell Drive Concord NC 28027 Beal Hillsdell Dove Stevan A and Megan S. Earnhardt Drinking NA NA NA NA NA WSW-4 4882-60-5571 U91 Hllwdw onva Concord NC 28027 B690 Hiltsdek Drive Can R and Decorah P Parker NA Drinking NA NA NA NA -1600; Served by 4882-80-5945 86W Hillsdoll Drive Concoct NC 28027 -4 a774 Hrltsdea Onve Donald and Cynthia C Belush 8774 4882-60-1707 FkBOMI Dnva Concord NC 2027 NA prinking NA NA NA NA NA 2225 04011 Circle J03aph W Fagan Jr NA Drinking NA NA NA NA NA 4682-51-SM 2225 Wall CkCla Concord NC 26027 21at Odell Circle Doneire W Foresier 2161 NA Drinking NA NA NA NA NA 4602.50.6036 Odell Circle Concord NC 28C27 BB24 HIMadell Drive Franklin and Angola Holder IRA Orinkrng NA NA 14A NA NA 4682-50-9525 8824 Hillsdoll Drive CanCerd NC 28027 0850 Hilledell Drive Aaron and Aahlay Carswell NA Drinking NA NA NA NA NA 4882-50-7559 8850 Hillsdall Drive Concord NO 28O27 _ WSW-5 6835 H1Hadel€ DAva 489E Daorge P Lawrence Unknown Abandumed7No Longer Present Unk Unk Unk Unk 920 60-9322 5635 HIIlstlell Dr. ConcordNG 28027 VVSW6 BBOO Johnsian Slreul 4682• Robes L and Sherry K Harmon. Jr. M-7791 Crinkling Unk Unk Unk Unk 92f1 60.1076 1 g80 Well School Road WSW-7 0750 Davidson Highway Roger L Fortney 784-42M Drinking Unk Unk Unk Unk 900 4681-69 $750 Davidson H Concoct NC 28027 WSW-8 Former 1810 Odell School Odell 73 invastmanls LLC Unknown Abandoned - Parcel Consolidation and nick Unk link Unk 760 Road 4661-58-7688 1151 Biscayne Or. Concord, NC 28027 Redevel eM WSW-9 96,5i Davidson Highway Wall Volunteer File Depanrhent, Inc 781 1780 Outside Use Only (I a washing 60O Unk 86 Unk fi5U 4601-49-86=4631-49-S539 9051 Davidson Hwy, Concord, NC 29027 td vaolee) - 2 properties WSW 10 87M3 Jnrnncon Road Rodger 0 Baucom 755.6072 prinking 130 Unk Unk Unk '1000 4681-69-5884 8703 Johnson Street Concord, NO 28027 WSW 11 8747 Davidson Highway Mar -Mack Development tarried Parinership Unknown Drinking Unk Unk Unk Unk r1000 4887-ag-1381 p0 Box 6107 ConcordNC 28027 WSW-12 8699 Davidson Highway Mar -Mack Development Limited Partnership Unkrlawn prinking Unk Unk Unk Unk >1000 46a1-69-3383 PO Box 5107. Concord, NO M29 Former 1760 Odell School Ociall 73 invealments LLC Abandoned - Parcel WSW-13 Road 4051-65-2624 1151 Biscay"Unknown Or, Concord, NC 20027 Consolldavarl and link Unk Unk Unk -1000 Radeva[ ment WSW 14 9179 Davidson Highway 4601 Rocky River Crossing LLC Unknown Formerly Drinking - Wall not Unk Unk Unk Unk a1000 49-03M 4350 Main St STE 201, Hanlaburg, NC 28075 observer!; Vacant Land (2019) WSW-15 0150 Davidson Highway 4801 SusWOUttle LLC: Pairick Sus€ar WW-795-9005 Abandoned Unk Unk link Unk n 1000 A •397 917 Davidson Concord NC 28027 WSW_16 SuslarfLniiie LLC; Petrick Suelar 704-795-9005 Drinking. Cleaning, d Drinking 230 Unk 76 Unk r1009 9172 Dar]dsvn Highway 9172 Davidson Concord NC 28027 for Animals Onsite WSWASA 4882-30-9176 Suslor&ihle LLC; Palnek Suslar 704795-9005 Drinking, Cleaning, A Drinking 35q link 76 Unk 1000 9172 Davidson Concgnd. NC 28027 for Animals Onkn4 WSYY_17 2135 Odell School Road Harriet H Shivadecker Unknown Drinking Unk Urk D-29O' 290'-30V 950 4682.40.8462 27 Odell School Rd cGrd NC 7 WSW-18 Former 9105 Devfdson Cabamrs County Abandoned - Parcel Highway 4681-49-537a PO Box 707 Concord, NC 25026 Unknovm ConsoOdatlon win Cabarrus Unk Urlk Unk lhlk 725 C0u School P e 2Davidson Hlq sway 4562 David Yawn 7W3796 Crinkirig 100 Unk Unk Unk a1000 WSW-19 40-20.2979 2131 0de11 School Road. Concord, NC 29027 2145 Odell School Road Jenne H Yawn Unknown Drinking Unk Unk Unk Unk �1000 480240.4776 773a Rlve Ini Ln. 7ovme GA 31331 WSW-20 2338 Odell School Road Cribarrusca LLC 150 Drinking - Currently Not in Use Unk Unk Unk Unk �1000 4682-41-7025 2nd Ave N STE 1600, 61 Petersburg, FL 33701 Unknown (Properly Vacant) WSW-21 Unk Unk Unk Unk -1000 WSW-?7 2la2 Odell School Road JenniferH Clark 2192 Unknovm prinking Unk Unk link Unk �SDOe 4882-50-1997 Odell School Road Concord NC 28027 WSW 23 0851 Johnston Sireel 4601 Joyce Waller Co9kns W5% Unknown Drinking Ur* Unk Unk Unk �1L100 68-8998 Johnston Street ConcordNC 26027 WSW-2q 91 S0 Davidson Highway SualarlLinfaPainck Svslar 704.795.9005 Drinking LMk Unk Unk Unk -1000 7 N otas- Unk • Inrdrmatiar unknown. Enrowakon contained In this Tab!e dos erved by Shield Personnel or reperiBd by others TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store B952 Davidson Highway (NC 73) €Sannapolis, Cabarrus County, North Carolina Incident Number: 9362 Well ID Date Installed Top of Casing Elevatlon {feet) Well Diarneter {inches} As -built Dep Ih (feel] Screened Interval {Teat) Field Measurements Field Calculations Gau Date in 9 0 Tatat Depth {feet] Depth to Groundwater (feel) Diff. Between As - hair end Measured Total Depth (feet) Measured Water Column in Well tfeet] Groundwater Elevation (testy MW-1 5115f2003' 100.00 2 30 10.30 fi12r99 NA 9.47 NA NA 90.53 8123101 NA 8.13 NA NA 91.87 2112102 NA 8-66 NA NA 91.34 9125102 NA 10.63 NA NA 89.37 5119103 NA 18.36 NA NA 01.64 ii13103 NA 15.97 NA NA 83.03 514104 NA 17119 NA NA 82.91 1118107 NA 21-86 NA NA 78.14 5128108 NA 20.72 NA NA 79.28 an6109 29.83 19.12 0.17 10.71 80.68 1118109 2"7 21.48 0.13 B.39 78.52 8126110 2987 17.20 0.13 12.67 02.80 39/11 29.87 19-44 0.13 i0.43 86.56 612112 29.81 19.92 0.13 995 80.08 2126114 29.87 16.85 0.13 13.02 03.15 8125114 29.87 16.61 0.13 13.06 83.19 2JW15 29-87 18.46 0.13 11 Al 81.54 8117115 29%7 13.25 0.13 16.62 86.75 2122116 29-87 17.75 0.13 12.12 82.25 8130116 29.87 19.43 0.13 10.44 80-57 2121117 29-87 21-29 0.13 8-58 78-71 618117 29-87 20-76 0.13 9.11 79.24 2120/10 29-07 22.24 0.13 7.63 77-76 8131/18 29.87 22.36 0.13 7.51 77.64 8/12/19 29.87 18.55 0.13 1132 81.45 MW-2 511512003 98.39 2 30 10-30 1112199 NA 22-61 NA NA 75.88 2MV01 NA 22.57 NA NA 7522 812310i NA 21-18 NA NA 77.23 2112102 NA 22.62 NA NA 15-77 9125102 NA 23.01 NA NA 75-39 5l19103 NA 17.06 NA NA 81-33 11affl3 NA 15.91 NA NA 82A8 59*4 NA 16.12 NA NA 82.27 1IM07 NA 26.46 NA NA 7793 512810E NA 1930 NA NA 79-09 4116109 30.04 18.25 -0.04 1179 90.14 1116f09 30.07 19.63 -0.07 10A4 78.76 6128110 30.07 15.89 -0.07 14.18 82.50 3r1111 30.07 17.56 -0-07 12-51 e0.S3 WV12 30-07 16.43 -0.07 11-64 78.96 WOM4 30-07 15-02 -0-07 15-05 83.37 8125114 30D7 16,64 -0.07 14A3 82.75 219115 30.07 17-16 -0.07 12.91 81.23 8117115 30.07 19.20 AV 10 a7 79.19 2122118 30.07 16.84 -0 07 1323 0155 8130116 30-07 16-44 -0.07 11-63 79.95 W21117 30.07 20-35 -0.07 9.72 78.04 8AWI7 30.07 19-98 -0.07 10.09 70.41 2120118 30.07 20.09 -0.07 9.98 76.30 8131/18 30.07 21.20 -0.07 8.79 77,11 2119/19 30-07 18.11 -0.07 11,96 80-28 af12110 30.07 18.25 -0-07 11.82 $0-14 MW-3 511512003' 9416 2 30 10-30 1112199 NA 8.13 NA NA 8603 8123101 NA 7.12 NA NA 8704 2112102 NA 7.57 NA NA 86.59 9125102 NA 9,60 NA NA 8456 511g103 NA 13-09 NA NA $1.07 1113103 NA 12-00 NA NA 62-16 514104 NA 12.23 NA NA 81-93 1118107 NA 1658 NA NA 77.68 waffle NA 15.47 NA NA 78.69 4116109 29.59 13.55 0A1 16.04 ao.61 1116159 29.85 15-88 0.35 13-77 7028 6128110 29-65 12.11 0.35 1754 8265 3al? 1 29.65 13.89 0-35 15.76 60.27 812112 29.65 14-54 0.35 15.11 79.62 2128114 29.65 1129 0.35 18.36 02.07 0125114 29.65 11.89 0.35 17.76 0227 2WI5 29.65 13-32 0.35 16.33 80,54 V 7115 29.65 1 15.21 0-35 14.44 78-95 2122116 79.65 1 2-89 0-35 16-76 81.27 813011a NM linable to Locate 212i12017 8112119 NM Well has been paved over j I - 1 1 71--�i k�+ProJecn�091i 090032 01 C.d'c Country StamRepwtsiMR 9-20 TskTab:e 2 - HW CW Efev P.O. 1 .14 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl`s Country Store 8952 Davidson Highway (NC 73) Kanrlapolis, Catlarrus County, North Carolina Incident Number. 9362 Wel! iD Date Installed Top of Casing Elevation (feet) Wall Diameter (inches) As -built Depth (feet) Screened interval (feet) Field Measurements Field Calculations Gauging Date Total Depth {feel) Depth 1° Groundwater (feet) Ditf. Between As- built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation [feel) MWA 511512003' 9806 2 30 10-30 1112/99 NA 19-11 NA NA 78.95 10/18/01 NA 21-95 NA NA 76.11 10/30101 NA 21-62 NA NA 76.44 5119M3 NA 16-86 NA NA 01.20 1113103 NA 15.79 NA NA 82.27 59104 NA 15.90 NA NA 82.16 1116107 NA 26-40 NA NA 77.66 5128108 NA 1929 NA NA 76.77 411 e109 30.13 17 41 -0.13 12.72 80.65 1116109 3020 19.72 -0.20 10.48 78.34 6128110 30.20 15.80 -020 14.30 82-16 317111 30.20 17-78 -020 12.4P 80 88 812112 30.20 18.42 -0.20 11.78 79.64 2126114 3020 15.15 -0.20 15.05 82.91 8125114 3020 15.62 -0,20 14.58 82.44 2 WI5 3020 17.07 -0.20 73.13 80-09 8/17115 30-M 19.03 -0-20 11-17 79-03 2122116 3020 16-74 -020 13.46 81-32 8130116 30.20 18.22 -0-20 1199 79-84 2121117 30.20 20.12 -020 10 O6 77.94 W17 3020 19.61 -020 1059 7045 2120118 30.20 20-83 -020 9.37 7723 8131/18 30.20 19.90 -0.20 10.30 78.16 2119119 30.20 17.77 -0.20 12.43 80.29 B112119 30-20 17-82 -0.20 12-38 8024 MW-5 1011712001' 98.74 2 30 10-30 11/2199 NA 21.39 NA NA 77.98 5123f01 NA 2038 NA NA 78.99 9125102 NA 2193 NA NA 76.61 6119iO3 NA 17,61 NA NA 8113 IIrjJ03 NA 1648 NA NA 82.26 514104 NA 16-69 NA NA 82.05 111=7 NA 21.16 NA NA 77.56 5120M NA 20.03 NA NA 78.71 4116M 29.Bt 18.21 0.19 11.60 80.53 11/6109 29.87 2045 0.13 9.42 7829 6128110 29.87 16.65 0.13 13.22 82.09 3R111 29.87 18.56 0.13 11.31 80.18 812112 29.87 19.92 0.13 9,95 7882 2126114 29-87 15.94 0.13 13-93 82-00 8125114 29-87 16.40 0.13 13-47 8234 219115 29.87 17-82 0.13 12.05 8092 8117115 29.87 19.78 0.13 10.09 7896 2122116 29.87 17,47 0.13 12.40 81,27 8130116 29-07 19.95 0-13 10-92 79.79 2121117 29-07 20.85 0.13 9.02 77-69 M17 29.07 20-39 0.13 9.46 70.35 2120118 29.87 21-55 0.13 8-32 77.19 M 1118 2907 21-62 0.13 0.25 77.12 2J19119 2987 18-44 0.13 11.43 80.30 8112119 29.07 8.56 0.13 11 31 8018 MW-6 813l2004 9800 2 35 15.35 1112199 NA 20-77 NA NA 77.23 e123101 NA 19-35 NA NA 78.65 W25102 NA 21.23 NA NA 76.77 11MIM7 NA 19.15 NA NA 70.85 5F18108 NA 1005 NA NA 79.95 11VO9 35.39 18.49 -0-39 16.90 79.51 6128/10 35.39 14-70 -0-39 2069 83-30 317111 35.39 16.53 -0.39 1886 81 A7 812112 35.39 17-14 -0.39 18.25 80.86 2126114 35.39 13.93 -0.39 21.46 04.07 8125114 3539 14.52 -0.39 20.67 83.4E 219115 3539 15.89 -0.39 19.50 82.11 8117115 35-39 17.79 -0.39 17-60 80.21 2122116 35.39 15.46 -0-39 1993 8254 8130116 35.39 16.97 -0.39 18A2 81.03 2121117 35.39 18.82 -0.39 16.57 79 18 819117 35.39 18.35 -0.39 17.04 79.65 2120118 35.39 19A4 -0.39 15.95 78.56 8131118 35.39 19.61 -0.39 15.70 78.39 21i9119 35-39 18.43 -0.39 18.98 81.57 1112119 35-39 18.54 -0.39 18.85 81-46 H:1PrvJac3s120091f0eW32-01 Ca!'s Comlry Stwae RapurtsWR 9-29191Table 2 - Hial GW Ele Page 2 a! 4 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Stare 8952 Davidson Highway (NC 73) Kannapolis, Caharrus County, North Carolina Incident Number: 9362 Wen ID Date Installed Top of Casing Elevation (feet) Well Diameter (inchesy As -built Depth p (Feet) Screened Interval (feel) Field Measurements Field Celculahorns Gauging Date Total Depth {teat} Depth to Groundwater ( ) Diff Between As - built and Measured Total Depth (feet) Measured Water Catu (feet) Well Groundwater Elevation (feety MW-7 813120134 86.40 2 35 15.35 1112199 NA 8.98 NA NA 77.42 2114M1 NA 9.76 NA NA 76.64 8123101 NA 1 795 NA NA 78.45 21121D2 NA 853 NA NA 77.137 9125102 NA 10.44 NA NA 75.96 1118107 NA 20.71 NA NA 65.69 512BID6 NA 20.26 NA NA 66.14 11161D9 35.16 19.42 -0.16 15.74 65.98 6128110 35.16 15.31 -0.16 19.65 71.09 3R111 35.1E 17.34 -0.16 17,02 69.06 812112 35.16 17.53 -016 17,63 66,87 2r26114 35,16 13.76 -016 21.40 72,54 8125114 35-16 1524 -0.16 1992 71.16 219115 35.111 15.35 -0.16 19A1 71.05 8117115 35.16 17.64 -0.16 17.52 68,76 2122116 35.16 13.85 -0.16 21.31 72,55 8130116 35.16 16.39 -0.16 16.77 70.01 2121117 35.16 1671 -0.16 10.45 B9.69 8W17 3516 t626 -0.16 18.90 70.14 2120118 35A6 1684 -0,16 18.32 69.56 8131118 35.16 16.93 -0.16 10.23 69,47 8112119 35,16 15.38 •0.15 19.78 11,02 MWB Unknown Unknown 2 unknown Unknown 2112102 NA 7.38 NA NA Unknown W5102 NA 949 NA NA Unknown V26/14 19.55 17.44 NA NA Unknown W25114 19-55 17.36 NA NA Unknown 219115 19.65 19.03 NA NA Unknown 8117115 19.55 >19.95 NA NA Unknown 2122/16 19.55 18.31 NA NA Unknown 8130118 1955 19.54 NA NA Unknown 2121117 19.55 1 n 19.55 NA NA Unknown aW17 19.55 ?19.55 NA NA Unknown 212012018- 8/12119 19.55 >19.55 NA NA Unknown MW-9 313r2011 9816 2 28 B-28 317111 27.80 18.38 020 9A2 79.78 815112 27.80 18,06 0.2D 8.94 79.30 212ti114 27.80 15.04 0.20 11,96 82.32 Br25114 27.80 16.06 0.20 1174 02.10 2015 27.80 17,63 0.20 10.17 80.53 8117115 27.80 19.39 0.20 0.41 78.77 2122116 27 80 17,05 020 10.75 81,11 8rdW8t8 2780 18.51 020 929 7965 2121117 27.80 20313 020 7.42 77.78 W117 27,80 1969. 020 11.11 78.47 2120116 27,80 2107 0.20 6.73 77.09 8131/18 27.8D 21.17 0,20 6.63 76-99 8112119 27.80 17.85 0-20 9-95 80.31 MW-10 3131201' 99.52 2 28 8-28 317111 27,76 18.47 0.24 9,29 81.05 812112 27.76 t9.19 0-24 a.57 80-33 2126114 27.76 15.70 0-24 12.06 83.82 8125114 27.76 16,16 D24 11.60 8336 M115 27.76 17.74 024 10.02 81.78 a117116 27.76 1991. 024 7.85 7961 2122116 27.76 17.49 024 1027 82.03 8r30116 27.76 1931. 024 9.45 80.21 2121117 27.76 21.15 C-24 6.61 78.37 &9117 27.76 21.04 024 6.72 78.45 2120118 2776 21.98 024 5-70 77.54 8131116 2776 2238 0.24 5.30 77.14 2119119 27.76 19.05 024 8.71 80.47 9112119 27.76 19 15 0.24 8.61 8037 ❑M W 1 4/29/1993 9835 2 37 33.37 1112199 NA 8.94 NA NA 89.41 2123101 NA 20.75 NA NA 77.60 10118@1 NA 219D NA NA 76.45 10/30101 NA 21.70 NA NA 76.65 5119/03 NA 16.89 NA NA 0146 1113103 NA 15.67 NA NA 02.68 514104 NA 16.74 NA NA 82.61 1118107 NA 20.25 NA NA 79.10 5128108 NA 19.06 NA NA 79-29 411609 38.03 17.02 -1,83 21-01 81.33 1116109 38.90 19.45 -1.90 19.45 7890 6128110 38.90 15.61 -1.90 23.29 8274 317111 38A0 17.33 -1.90 21.57 81.02 812112 38.90 18.16 -1,90 20.74 80.19 2126114 3890 14,76 -1.90 24.14 83-59 0/25114 3890 15-64 -1 AD 23.26 02.71 219115 3090 16.80 -1.90 22.10 81.55 8/17115 38.9D 18.08 -1.90 20,02 7947 2122116 38.90 16.53 490 72.37 01.82 MW18 38 90 18.22 1 •1.90 20.69 80 13 rr 4Prolncl%QO rIaXW2-ot Cwra Cowntrr StajMuDomwNR w-2DIMto .2 roes cw t F- Page ; ar4 TABLE 2 - SUMMARY OF WELL CONSTRUCTION AND HISTORICAL GROUNDWATER ELEVATION DATA Carl's Country Store 8952 Davidson Highway (NC 73) Kannapolis, Caharrus County, North Carolina Incident Number: 9362 Well fD ❑ate nstalled Top of Casing Elevation [feet) Well Diameter (nches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth t° Groundwater (feet) Oiif Between As - built and Measured Td[al ]]spite [feet) measured Water Column in Weli (feet) Groundwater Elevation [feet) DMW 1 CON- 2121117 38.90 20.10 -1.9D i8-8o 76-25 SM17 38.90 19.84 -1.90 19-06 78-51 2120118 38.90 20.89 -1.90 18Af 77.46 8131118 38.90 21.24 -190 17.66 77.11 8112119 38.90 18.06 -1.90 20.84 80.29 DM W-2 Unknown 110028 2 Unknown Unknown 1112/99 NA 2274 NA NA 77-54 DMVV-3 3IN2011 9849 2 50 00 45-50 317111 49.57 17.38 0.43 32.19 81-11 812112 49.57 18.39 0-43 31.18 80-10 2126114 49.67 14,95 0.43 34.62 83-54 8125114 49.51 15-62 0-43 34.05 82.97 219115 4957 17.03 0.43 32.54 81.46 8117115 49.57 19.12 0-43 30-45 79.37 2MI16 49.57 16.78 0-43 32-79 81-71 BM16 49-57 18-48 0.43 31.09 80.01 ZJ21117 49-57 20-36 0.43 29.21 78.13 819117 49-57 20.04 0.43 29,53 78-45 2120118 49.57 21 13 043 2844 77.36 813111e 49.57 2144 043 2813 77D5 2119119 49.57 18-16 6-43 3141 80.33 8/12019 49.57 18-32 0-43 31.25 80 17 DMW-4 8/15/2011 90.40 2 70 65-70 &1e111 70-01 17-95 •0-01 52.D6 0045 W2112 70-01 18-60 -0 01 51.41 79.80 2126114 70.01 15-14 -0-01 54.87 0326 W5114 70.01 15.80 -0.01 54.21 82.60 2N115 70.01 17.30 -0.01 52,71 81-10 SM7115 70.01 1933 -0,01 50.68 79.07 2122116 70.01 17.02 -0 01 52.99 81.38 SAW16 70.01 18-62 -001 5139 7978 PJ21117 70.01 20.51 -0.01 4950 77.89 819117 70.01 20.15 -0-01 4986 70.25 2120118 70.01 21-27 -0.01 48.74 77.13 8131118 70-01 21-50 -0-01 40.51 76.90 8112119 70A1 11146 -0.01 51.55 79.94 DMW-5 1/612012 97.94 2 99 94-99 1111Y12 95-35 10.92 0.65 01.43 ME 2120112 98.35 16.70 0.65 81.65 8124 812112 98-35 17.96 0.65 803.9 79 98 2126114 98.35 14.57 0.55 8378 83-37 8125114 98.35 15-15 D-65 83.20 82.79 219116 98.35 16.76 0.65 81.59 81-18 8117/15 98.35 18.74 0.65 79.61 79.20 2122116 90.35 16.43 0.65 81,92 81.51 8730116 90.35 18.08 0.85 8027 7906 2/21/17 98.35 19.89 0.65 78.46 78-05 819117 90.35 19-57 0.65 78.78 78.37 2120118 98.35 20.71 0.65 77.64 77.23 8131118 98-35 21.04 0.65 77.31 76.90 211909 98.35 17.79 0.65 80-56 80-15 8112119 90.35 17.94 015 8041 80-00 SVF-1 5/112012 9794 2 25 10-25 6f7112 25-00 16-79 0.00 8.21 8115 719112 25-00 17.52 0.00 7.48 8042 813112 25.00 18.28 1 0.00 1 e.72 79.66 212811d NM NM NM NM NM 8125114 NM NM I NM I NM NM Notes Tap of Casing elevation teased on arbilrary datum of 100 feet = Replacement monitoring well NM= Not Measured NA = Date Not Available: data prior to 41161D9 reported by others. H:'Projous1200V 090032-01 Can's CDun1ry E aro+RnpprtsVOR 9-211I MI'ade 2 - Post GW E1e Pago 4 914 2 i r $ Ygg� z z z z i i i i a z z$$ n C dd o x$ z g z z z z z z z 9 g �n r! ❑ Z ❑ Z ❑ Z ❑ z Q x Q 2 P Z ❑ Z ❑ x ❑ x ❑ x ❑ z ❑ Z � H App p �p H C ❑ z N m ❑ z N n 6 x ❑ z ❑ z ❑ z ❑ r ❑ x ❑ r O r ❑ r ❑ x n g pF a ❑ a ❑ ❑ ❑ a ❑ ❑ ❑ ❑ ❑ ❑ ❑ y YF � a r r 2 2 2 2 x z 2 Y 2 Z 1' x M d yy ]w C ^� c a c ❑ z ❑ x ❑ r ❑ x o x ❑ x ❑ x o x ❑ x o x ❑ r ❑ x ❑ x o r. m S � z z z i i z z z z z z z 1O ti Ymy` z pN z z z z V z z z z "+ $ pm g i i a c O n❑❑ N ❑ o o r- o 0 0❑❑❑ n 2 x z x x r x n 4 SI LU z z z x x x ¢ n z z x x m m Y fY w L ❑ z ❑ Z ❑ x ❑ Z ❑ Z ❑ z O 2 ❑ r I` ❑ r ❑ x ❑ r Q L G, ' ❑ x ❑ x ❑ x ❑ x ❑ x ❑ x ❑ x ❑ x ❑ z ❑ x ❑ z a a ❑ z & f ❑ x z ❑ z ❑ x ❑ x ❑ x ❑ x n ❑ x P x P x ❑ x ❑ z ❑ z g� m a e ❑ ❑ ❑ in P ❑ O ❑ O 4 ❑ ❑ ❑ c8 x z x z x x x z x x z z z Q 4 L ❑ z o z ❑ x ❑ z ❑ z ❑ z ❑ z ❑ z ❑ z ❑ x o r ❑ x ❑ x o � Y { �q ❑ ❑ ❑ rn ❑ ❑ ❑ ❑ ❑ ❑ p ❑ ❑ ❑ a S z 2 2 z z z z z z x x x Z w y� 2 x x 2 Z Z 2 2 2 2 Z Z x Z 8 t6 � �p ❑ 2 ❑ x P 2 Q 2 ❑ P ❑ x ❑ x ❑ x ❑ x ❑ 2 ❑ x ❑ x Q x z g �3 C N n ❑ ❑ ❑ ❑ f ❑ ❑ In❑ , zz m a x z 6 ui z m z z z z � n N s z E ia ;a Z5 �5j S C F Table 4. Summary of Hiatori cal Groundwater Analytical Results Cari's Country Store 8952 Davidson Highway Concord, Caharrur County, North Carolina Facility ID Numher0-ft07470 Incident N umber 9362 Shield Project Number 1090032 Ana ical Welhod ---i EPA 602, 00 VW2 or 6200B EPA W4 1 or 6200B EPA 200 7 or E010 Analyle -- ..... a Benzene Toluene Ethyl. hen:ene Tote! XyRnao Meft14ert h(MTSulyl her [MT9Ej fartAmyl Akuhol tart AmeMer y] 91Ner larl-Beryl Alcohol D-eaopmpyl elhergff) 1,2- pir kwonlhane Haphlhabrle 1,2-Dlhrsmo-elnane [EDBy Talal Lead lands 1.0 600 600 500 20 40 128 10 70 0.4 a 0.02 15 GC L 5 00 2bil 000 64 500 65 500 20 000 40 000 126 000 10 000 70,000 400 aim 50 15 00C Sample LoceNan oceGa Onto Sam lea [41) WA WWI) [ugf¢ NWO (41) fu ) fU01=1 WW) W) 1u9f11 NO (W) MW-1 OV27193 Np NO N No No NR NR A NA N 04/16193 NO ND NO NO NO NR NR NR NO NR NA -NR NA avi 1Lin NO NO ND NO 3 NR NR NR 2 NR NA NR MA 11112W NO NO NO NO NO NR NR NR N❑ MR HA NR NA 05119W c1.0 •5.0 410 .1.0 -50 NR NR NR 45.0 NR NA 41 a NA f U03103 41.0 •5.0 00 0 41-0 4.0 NR NR NR 45A NR NA 41 0 NA 05104104 .$.0 45.0 -10 Q.0 t1-0 NR NR NR •1.0 -0.5 NA r1.0 NA 11f06107 0.0 c1.0 c10 43.0 41-0 NR NR NR cl0 .1.0 NA NR NA 05126111E 41.0 s1.6 t10 -3.0 410 NR MR NR 41.0 st.0 NA NR NA W18109 NO N❑ NO NO NO NR NR NR ND NR NA ND NA 1V06109 NO N❑ NO NO NO MR NR NR NO NO NO NR ND M28110 NO NO NO NO ND NR NR NR NO NO NO MR NO 0.V07111 N❑ NO Np NO NO NR NR NR N❑ NO NQ NR N❑ 09WJ12 ND NO ND NO NO NR NR NR N❑ NO NO ND N❑ 022&14 ND NO NO NO ND NR NR NR ND NO ND NO NO OMW14 ND NO NO NO ND NR NR NR NO ND NO NO ND 02A)SMS NO NO NO NO ND NR NR NR ND NO NO ND NO 06r17115 NO NO Np NO N❑ NR NR NR ND NO ND ND NO 02R2116 NO NO N❑ NR MR NR NO NO ND ND NO 0819W1B HD NO NO NR NR NR NO Np Nq ND NO 62r41117 NO ND NO NO ND NO NO NO ND ND ND 06/09117 Nq =NDNO N❑ No NR NR NR NO ND NO N❑ No 02ld011a NO N❑ ND NO NO NO NO ND ND NR NA 0Br9111B ND N❑ Ntl NO N❑ HD Hp NO HO NR NA 02/19119 NS • PER REQUEST FROM NGDEQ OB112119 NO ND NO NO NO NO NO NO NO NO NO NO MA MW2 0112753 it NO D NO NR MR NR NO NR NA NR NA 0tGM3 3 NO ND NO NO NR NR NR NO NR NA MR NA 0611 V93 13 NO ND NO ND NR NR NR ND NR HA MR NA 1lmm -1.11 -60 c1.0 41.0 8.1 NR NR NR <5.0 NR NA e10 NA 051M104 41.0 -5.0 -10 <.a 22 NR NR NR 410 40-5 NA 00 NA liffi U7 4.1 45.0 �50 c15 363 NR NR NR c5.0 c5.0 NA NR NA 05r2e109 6.2 cs0 c5.0 �15 624 NR NR NR 25 -5.0 NA NR NA 04116M NO NO ND ND 499 NR NR NR NO NO NO NO NA 11r06109 5.1 NO NO NO 1.090 MR NR NR ND NO NO NR NO 06R6110 NO ND ND NO 1,270 NR NR NR ND NO ND NR NO 0=7111 ND NO ND NO "I NR NR NR ND NO NO NR ND 0BMV12 ND NO NO ND 210 NR NR MR NO NO NO NO NO 02R5114 NO NO NO NO it2 NR NR NR NO NO N❑ NO NO OW5114 ND Np ND NO 281 NR NR NR 33 ND ND NO NO 02I09115 ND NO ND NO 204 NR MR NR 2 NO NO ND RD DB117115 NO NO NO ND 347 NR MR Hit 5.2 NO ND ND NO 02/22/16 NO NO NO NO 261 NR NR NR 56 Np NO ND NO 0913011E ND ND ND ND 455 NR MR NR 13-5 NO NO NO N❑ 02121l17 0-5 501 87 1 258 453 I'm NO 3.560 181 ND ND NO NO Gwft}7 3-6 7.1 23.6 1545 656 MR MR NR 220 NO 13.8 NO NO 02r20f18 4.3 41 2.1 18.3 503 1110 NO 8,050 236 NO f3.6 NR MR 0913111E 33 NO No 3 026 1B40 NO 759E 20.3 NO NO NR NR 02119119 2.2 NO NO NO 7f0 1470 NO 6030 26-8 NO ND NR NR W12J19 NO NO NO NO 1,350 1.400 NO 7,s>ta 34.6 NO NO ND NR MW-3 01127M ND NO ND NO NO NR MR NR NO NR NA NR NA Wie193 ND ND NO ND NO NR NR NR I NO NR NA NR NA 0&11193 NO NO NO NO NO HR NR MR NO NR NA NR NA 11112W ND NO NO ND NO MR MR NR ND MR NA MR NA o51t9103 -10 c5.0 44.0 41.0 32 NR MR MR 45.0 NR HA 41.0 NA 1W.V03 41.0 c50 410 e10 64 NR NR NR 45.0 NR RA 41-0 NA 051M104 410 -50 e10 r10 130 NR NR MR 45.0 co NA 41-0 NA 1110B107 410 -10 c1.0 S30 76.5 NR NR NR 11 410 NA Nit NA mom 410 �1.0 �1.0 �3.0 96 NR MR NR 0.5 c10 NA NR NA IWIG09 NO NO ND NO 4-6 NR NR NR NO NR NA NO NA 1t/05" NO NO NO ND 2.0 NR NR NR NO No NO NR 8.1 OW11/10 NO NO NO NO 11 NR NR NR ND NO NO MR NO 0=7111 NO NO N❑ NO 0.59 MR MR NR ND NO NO NR N❑ ONW12 ND NO ND ND ND NR MR NR NO Nq NO NO ND 0248114 ND ND NO NO NO OR NR NR NO ND NO NO NO OWN14 NO NO NO RD 0.51 NR NR NR NO Np ND NO NO 02MI5 NO ND NO NO NO NR NR MR ND HD NO NO NO =17115 NO NO ND NO ND NR NR NR NO ND NO NO ND 02/22116 NO ND NO I NO I HD RR NR NR NO I NO ND RD No. 08/30116 N& UNABLE TO LOCATE 2R112017 2119119 NS - WELL HAS BEEN PAVED OVER MW-4 ala7193 NO ND ND ND ND NR NR MR NO NR NA NR NA 04AW93 &a NO N❑ NO 79 NR NR NR I MR NA MR NA 08M1193 4.0 NO N❑ NO 265 NR NR NR 41 NR NA NR NA 041M5074 NO ND N❑ NO 1a0 NR NR NR 12 NR NA NR NA M23194 2.0 NO NO NO 140 NR NR NR NO NR NA NR NA 1 W2194 1.0 2.0 NO NO 30 NR MR NR 90 NR NA NR NA 031i3195 No MD NO ND 90 NR NR MR 11 NR NA MR NA 05tim 7.0 NO NO ND 66 NR NR NR 70 MR NA NR NA 04110197 NO I NO I NO I NO 1 4" MR NR MR S2 NO NA NR NA 11112W 2.0 ND NO NO 320 NR NR MR 37 NR NA NR NA 08105l99 NO I NO I NO I NO 1 359 MR I NR I NR I NO Hp HA I NR NA 071261W MD I NO I NO I NO 1 530 MR I MR MR I NO NR NA NR NA 0 115W 1 DRY H'IP1eJrchl]OOr11RlOn32-01 CM Came, SIaelF M. MR 9-MI MT.b 4 - H mz- 1 GraMwaler Pape 1 of a Table 4: Summary of Historical Groundwater Analytical ltcsul to Carl'i Country Stare 89S2llaridaoo Highway Concord, Cabarrlra County, North Carolina Facility 10 Number 0-1it17470 Incident Number 9362 Shield Miect Number 1090032 Mal scat Method -••• EPA 802 6011602 or 62008 EPA 504.1 or6200B EPA 200.7 or 6010 Analyle •••••••� Benzene Toluene Ethyl- benzene Total XA410S mew -tort 6(MTSEur IMTBE) ten -Amyl � W Am6111or y! OiTeT IeR-B1ely[ Aicahaz Deisopropyl ethar[IPE) :,2- Dichloreethane Naphthalene 1,2-0ibrmmo-alharrs (LOB] Total Lead L tend 1.0 80o B00 SW 20 40 128 In 70 04 6 0.02 t5 GCL 5.000 260 M 84.500 05 500 20 000 40M 128.000 10 000 70.000 400 8 000 so 000 Semple L9Cdlian Date NO (u9nj N90 (U911) ;U9lli (u9A) WWI) (UV (u971) (vnA) (Wifl) iu90) {t91r) MW-4 SCool) NO ND N❑ NO NO NR NR NR No NO NA NR NA s10 s50 tl0 s1.0 32 NR NR NR s5.0 NR NA r10 NA c10 -50 c10 �1.0 24 NR NR NR c5.0 NR NA c1.0 NA pliffivog 0.0 -5.0 s1.0 -2.D 22 NR NR NR 41.0 s0.5 NA s1.0 NA 7 410 -1.0 t1.0 -3.0 65 NR NR NR 2.3 sl0 NA NR NA 4t.0 41.0 s10 43-0 55 NR NR NR 1.4 41.0 NA NR NA ND NO NO NO 179 NR NR NR NO NR NA ND NA NO NO NO NO 343 NR NR NR NO NO ND NR NO W20110 L ND NO N❑NNO A" NR NR NR 14 ND Nq NR NO OU7111 NO ND N❑ 947 NR NR NR 25 ND NO NR NO 08M7112 ND N❑ NO 666 NR NR MR X0 ND NO N❑ ND 02r2$114 NO ND NO ISO NR NR NR 05 NO NO N❑ NO 0G25114 NO N❑ NO 2290 NR NR NR 57 ND ND N❑ NO 02109/15 ND NO ND 26" NR NR NR No NO NO ND ND W17115 N❑ NO NO 6390 NR NR NR 12.4 NO NO NO NO 02/22/10 ND ND ND 6670 NR NR NR ND NO NO ND NO BSr3006 NO No ND 3200 NR NR NR i9.8 ND NO ND ND 02121/17 No NO NO NO 2380 NO NO 1940 20.3 NO ND ND ND 08109/17 5.1 ND NO ND NO NR NR NR 08 Gies NO ND 5.3 02120ma NO NO NO ND 713 ND NO NO 5.7 NO NO NR NR =1119 Nq NO ND ND 412 ND NO 475 83 ND ND NR NR 07IM19 NO NO NO ND 324 NO NO 336 39 ND NO NR NR 06/12119 6.5 NO NO NO 34 NO ND a6 19 Nq NO NO NR NIW-5 0 ICA3 1 NO ND NO NO NR NR NR NO NR NA NR NA 06111 N3 NO NO ND NO 40 NR NR NR N❑ NR NA NR NA 1Imm s1.0 0.0 c1.0 -1.0 -50 NR I NR NR �1.0 NR NA �10 NA 051WV4 0.0 450 �i.0 q.0 53 NR NR NR 0.0 •0.6 NA 0.0 NA 11160007 et 0 s1 0 s1.0 �3.0 161 NR NR NR 9-9 41.0 NA NR NA ow8108 410 e1.0 -10 c30 03.8 NR NR NR B7 c10 NA NR NA 6411SM9 36-7 NO NO On 69A NR NR NR 12.5 NR NA ND NA 11MM9 184 ND ND 43-9 79-7 NR NR NR 12.3 ND 3.8 NR NO 06r26110 194 ND NO 141 176 NR NR NR 14.1 ND 32 NR NO 03107/11 477 NO NO 24.7 455 NR NR NR 154 ND AO NR N❑ 06102A2 287 Nq NO ND 1730 NR NR NR 12.2 NO NO NO ND OVM14 SOB NO 1 71 ND 5470 NR NR NR 162 NO 36.4 NO ND 08W14 2190 NO 42-6 NO 7030 NR I NR NR NO NO 161 ND NO 021=15 2A20 ND SS.3 ND 6210 NR NR NR NO NO 290 NO NO 08117/15 4470 ND 141 711 4070 NR NR NR NO ND 340 NO NO cv2211S 2II20 712 153 551.7 2740 NR NR NR NO NO 461 ND ND 08130/15 3600 174 456 $72 2890 NR NR NR NO NO 543 NO NO 02n1117 2670 37.1 365 317.2 2040 2050 5S6 415 ND ND 612 NO NO WWI 3080 13.2 458 143.7 1830 NR NR NR NO NO 463 NO NO 02120116 1040 NO 902 ND 1340 2290 440 ND NO ND 450 NR NR 08KIVIS 1320 17 411 NO 1200 2120 409 135 NO ND 464 NR NR 02/19719 213 NO 57 NO 1030 1470 1 234 11a NO NO 786 NR NR OW12119 101 NO 1.9 148 273 32-4 26.4 NO ND 34.8 NO NR a4W-8 04r18193 NO NO ND NO NR NR NR ND NR NA NR NA 00111/93 ND NO ND 6 NR NR NR 4 NR NA NR NA 04105/94 NO ND dNO ND NO NR NR NR ND NR NA NR NA 0W3194 NO NO ND NO NR NR NR Nq NR NA NR NA 11r22194 ND NO ND NO NR NO NR ND NR NA NR NA 0311W25 ND ND ND ND NR NR NR NO NR NA NR NA 0W16r95 ND NO NO NO NR NR NR NO NR I NA I NR I NA I I M3113 NS 05/04104 NS i1108107 s1 0 1 -1.0 1 t1.0 1 s3.0 I.3 NR NR NR c1 q 1 e1 0 1 NA NR NA 05128M �10 I 510 1 s1.0 1 s3.0 1 17 NR NR NR 41.0 1 c1.0 NA NR NA 04116109 NS 1110fl109 ND ND NO NO 5.8 NR NR NR NO ND ND NR 24-7 06126/10 Nq NO NO NO 0.71 NR NR NR NO NO NO NR 59 0=71iI NO ND ND NO NO NR NR NR N❑ NR ND NR NA 06I02112 NQ ND NO NO Nq NR NR NR NO N❑ NO NO ND 02126/14 NO ND NO ND ND NR NR NR NO 0,62 NO NO NO 08125/14 NO ND NO NO NO MR NR NR NO 669 NO NO ND 02MI5 NO ND ND ND ND NR NR NR NO 0-6 ND ND N❑ =17115 NO ND ND NO ND NR NR NR NO o.?3 NO ND NO 0N22116 NO ND ND NO ND NR NRDAUD7 NO 0,74 NO NO NO 05130/16 N❑ NO NO ND NO NR NR NO 0,74 NO ND NO 02U 10F N❑ NO Nq ND NO NO ND NO 0.0 ND NO 102 WWI ND ND ND ND NO NR NR Nq 0,66 ND NO 8 0212D118 ND ND kO NO 27A NO NDNO NO Np NO NR NR OB1 We ND NO ND ND 134 N NO 12 No NO NR NR 02119119 ND N❑ NO ND 342 NO NO 2 NO NO NR NR 08112119 NO ND NO NO 00.3 NO NO NO NO NO NO NR H:1PoojmWYM109C= 01 Cwrr C-try Swrsl apu WR e-2a1 a1Ttl 0 - Hlexn[al GreuM , Prpc 2 W 6 'Cable 4: Summary ofsiislaricaI Grovedwaler Analytical Results Carl's Country Stare 9952 Davidson Highway Concord, Cabarrus Co0aty, North Carolina Facility 1D Number 0-007470 Incident Number 5362 Shield Pra'ret Number 1090032 A.norPcsl Melhaa EPA 802, 6011602 or 82000 EPA 504A a 6200B EPA 2W 7 or 6010 Arlalyla ------� 8ensana Tolusns Elhyl- pe"ona Total xytenes Me1hy!-iod- butyl ether (MTBE) tart -Amyl lart- Rmylmelhyl ether �� Dplher [ PEj D3Woroe1ilarta Naphthalene 1,2-Dih B elhana TWaI Lead SiaqdarMMAC to SOO 600 5D0 20 40 128 10 70 04 6 002 15 L 5 000 280 64 500 SOo 7U oDQ 40 000 123 000 10 000 70 tl00 400 6.000 Sa 15 000 Sample Location Gate Sam led NO) (u9AY [u941 (ug11) NO Rvgl!) (UgA) NO) (u9+l) (Ug[0 {Ug)l) Nwl) Wghj hfW-7 1110af07 .S.p c1.0 c10 c30 c10 NR NR NR 110 CIO NA NR NA me= -1.0 -10 c1.0 c30 063 NR NR NR t 1 1 c10 NR I RR NA D4MOM NS 11 f06109 NR NO ND NO 0." MR NR NR 1.3 ND ND NR 60 08/28/10 NO NO N❑ NO 0.13 NR NR NR 0.19 NO No NR 11.7 03MTll1 NO ND ND ND 0.04 NR NR NR 0.83 NO NO NR NA OSY02112 NO ND ND ND NO NR NR NR N❑ NO NR ND NO 02iWi4 ND ND ND N❑ 1.1 NR NR NR N❑ NO NO ND ND 08125/14 NO NO N❑ NO 1.1 NR NR NR ND NO ND ND HD p2x39115 NO NO ND NO O68 NR NR NR ND NO No NO 7.8 O8117115 NO NO ND ND 18 NR NR NR ND NO Np ND 5.4 WWI, NO NO ND ND 1.3 NR NR NR N❑ ND NO NO ND MOMS NO NO NO N❑ 22 NR NR NR ND NO NO ND NO 02Iptf17 NO NO NO N❑ 1.9 NO NO NO ND NO NO ND NO OBf09f17 NO ND ND ND 23 NR NR NR NO NO NO NO 9-8 021201t6 MO ND NO ND 1.0 NO NO NO HQ ND NO NR NR 06131/16 ND N❑ NO ND 24 NO NO NO ND ND NO MR NR 02119/19 H - PER REQUEST FROM NCDEa 06112/19 NO NO I NO I ND NO NO NO 1 NO ND NO NO NO NR MW-8 02126/16 DRY 0fi125114 ND ND NO NO NO NR NR NR NO NO ND 1 ND 1 18.3 G2xw 5 NS- DRY 0&17115 _ NS- ORY 02122/16 ND ND NO NO NO NR NR NR I NO I ND NO I NO AS W30116 NS- DR 021211t7 MS- DRY 0tll03l17 NS- DRY N201201& e13117a NS- DRY 02/19/19 NS. PER REQUEST FROM NCDEQ MW-9 OW2112 NO NO NO NO 1.1 NR NR NR NO Np NO NO NO 02MM NO ND NO ND NO NR NR NR NO NO NO ND N❑ OeRSl14 ND ND NO ND ND NR NR NR No NO NO NO N❑ 02009115 NO NO NO ND NO NR NR NR NO NO NO ND NO Q6117015 ND NO NO NO NO NR NR NR NO ND ND NO N❑ 02f22116 Na NO NO ND NO NR NR NR ND No NO NO N❑ Oa330116 NO NO NO NO NO NR NR NR ND ND NO NO NO 02/21/17 NO NO Nq NO N❑ NR NO NO ND NO NO ND NO 0OM6417 056 NO NO ND 14 NR NR NR NO NO NO NO ND 021201fe NO ND I NO NO I J110 I ND NO I NO NO I ND NO I NR I NR Mille NO NO NO I NO I ND NO I ND I N❑ I NO I NO I NR I NR NR 021t9119 NS - PER REQUEST FROM NCOEQ 0Ing NO NO NO ND NO NQ NO N❑ ND NO ND NO NR MW-10 0B412112 NO NO 11 34.5 ND NR NR NR NO NO 35-3 ND NO 02l2&14 NO NO ND 3.1 NO NR NR NR NO NO 38.3 NO NO O8WSM4 054 NO 4-4 4.1 NO NR NR NR NO NO 105 NO ND 02109/15 ND NO 1.5 1-5 NO NR NR MR NO NO 64-6 ND NO wi 7115 0.57 ND 072 0-9 NO NR NR NR NO NO 36.9 NO NO 0212Y115 NO NO N❑ 1.2 NO NR NR NR ND NO 22.1 NO NO 0e130116 1-1 NO ND 0-56 NO NR NR NR NO ND 14.1 NO NO 02r21117 0.01 ND NO 091 NO ND NO ND NO NO 16.3 NO NO 069W17 2.3 ND ND N❑ ND NR NR NR NO N❑ $2 NO 53 D N❑ NO 096 ND NO NO ND ND ND 20-1 NR NR p8 Mille ND ND N❑ 1+0 No NO 2 NO ND to NR NR 02/1RD V95. ND 0-87 NO NO NO NO NO ND 17.3 NR NR OLVt No NO NO NO NO NO NO ND N❑ 11.1 ND MR ONWV-1 wle193 1 ND NQ ND NO NR NR NR NO NR NA NR UA 08/11/63 ND NO I NO ND NO NR NR NR NO NR NA NR NA 11112M7 NO HO ND N11 NO NR MR NR NO NR NA MR NA OW05M79 NO Nq N ND NO NR NR I NR I NO NO NA NR NA 0212&00 NO NO NO I NO NO I NR I NR I NR I ND MR i NA I NR NA 02RTP! 1a NO ND NO NO NR NR MR NO NR I NA I NR NA 08115A1 Na! Sam !pp 10130101 200 NO NO NO NO NR NR NR N❑ ND NA NR NA OSf4&03 .1.0 -5.0 .$0 41-0 c50 NR NR NR s50 NR NA e10 NA 11*3103 t.6 e5.0 c10 00 t50 NR NR NR �5.0 NR NA e10 NA Q:JQ41D4 12 55.0 s1-0 s2-0 s1.0 NR NR NR r1.0 r0-5 NA e10 NA 11f0&07 s1.0 .0.0 s1.0 s3-0 3.7 NR NR NR -1.0 �10 NA NR NA 0512=5 1.6 <1 0 00 r30 -1.D NR MR NR e1-O 1-0 NA NR NA 04115MB 121 ND NO NO NO NR NR NR ND NR NA NO NA 1110e109 84.6 NO ND 1 NO N❑ NR NR MR 1.1 12 NO NR NA 0612e110 6.1 NO ND NO ND NR NR NR 0-60 1i NO NR NO 0=7111 6.4 ND NDNND NO NR NR NR NO O.82 NO NR NO 0SM2112 N❑ NO NO ND MR NR NR NO NO NO NO NO OM14 ND ND NO ND NR NR NR ND NO ND NO NO peR5114 ND ND ND N❑ NR NR NR NO NO No NO ND 02/09115 NO N❑ N❑ NA NR NR NR NO NO NO NR NO D6117115 NO ND NO NO NR NR NR ND NO NO NO NO 02/22110 NO N❑ NO NO MR NR MR NO ND NO ND NO OW30116 ND N❑ NO NO HR NR NR NO NO ND NO NO p212tf17 ND NO NO ND ND NO ND NO ND NP ND NO 0910907 NO NO ND ND No NR NR NR Hp ND ND ND NO 0212011e HD NO HQ ND HD NO ND N❑ NO NO NO MR NR OB131116 NO NO NO N❑ NO N❑ NO NO NO NO NO MR NR 02119/19 NS- PER REQUEST OF NCD Q ❑ 1 ND ND 1 NA 1 0.68 1 0.95 NO NO �„ 'fable 4: Summary of Historical Groundweter Analytical Results Carl's Country Store 8952 Davidson Highway Concord, Caharrai Co u nty, North Ca rn I i n s Facility I N um h er 0- D07470 4ncideot Nu tuber 9362 Shield Pra'ect Number I09DD32 An :cal .Ylelhaa- EPA 6026DIJ602 or 62000 EPA504.Ior62DDO EPA20137ar6O10 Analyte ••••-••� eenzone Toluene Ethyl- htplena Total Xylanas Melhyl-lad- butyl alhar {MTRQ Iarb,Afnyt Aloand tort- Amaihy yknl ether torl-Butyl Alcaho! Olisopropy) alhar PIPE) 1.2- Oichloroathane Naphthelene 12-Dibr¢mo-elhana (EW Total lead SlarkdaiMMAC 10 600 600 5W 20 40 128 10 7D 0.4 a 002 15 G L 5.000 260 ,11A) 8 E 500 65.5130 20 000 40 G40 126 WD 10.000 70 000 49D 6 DOO 5o 15 ODO Sample Location Date Sam eb t�91I) .u9+1 f:+919 {uV) t++OO) W) Wv$ (vgrl) (wyl) (UOA) (ua1) (u911) (u4+t) OMW-3 CM7111 59's ND NOfND NO NR UR MR 1.0 2.0 NO No NO OW02112 ND NO ND NO NR NR NR 09 NO NO ND NO 02126114 ND NO ND ND NR NR MR ND ND NO ND NO Oa175114 ND NQ MDNO ND NR NR MR ND ND NO NO ND 024WIS NO NO NO NO NR NR MR NO ND NO NO ND 08,17175 NO ND NO NO NR MR NR ND No No NO N❑ ON22116 No NO NO ND NR NR NR ND NO NO ND ND 08r3W1e 14,6 NO ND ND NR NR NR 2.8 1.7 ND NO ND o7l21117 43A NO ND NO NO ND NO 7.3 5.1 ND NO NO 011W117 GSA NO N❑ NO NO MR NR NR 94 6.6 ND ND NQ 02wis 524 ND N❑ NO NO 123 NO NO 92 a's NO MR NR 08r31115 37.5 NO ND N❑ NO 141 ND 10-2 10.3 7.a NO MR NR 07119119 42 NO N0 ND ND 199 NO 13.8 13.6 10.4 NO NR NR O&12119 61.4 ND NO ND 14.3 ns NO 33 223 17.3 NO NO NR DMVV-4 OB116111 1560 ND NO 13 NO NR MR NR 313 4" NO ND NO OEW12 111 ND NO NO NO NR NR MR 5.3 13.1 NO NO N❑ O=W14 00.3 NO NO ND NO NR NR NR 64 14.2 NO NO NO 0&25114 NO NO NO NO NO NR MR NR 5.7 9-S NO NO NO OVOW15 37.2 NO NO NO ND NR MR NR 4 6.7 NO NO NO OWIW15 92.1 NO NO Nfl NO NR NR NR 46 8 NO NO NO 62/22116 23.7 NO NO NO ND NR NR NR 28 3 NO NO ND Oe73WI5 7.2 ND NO NO NO NR NR NR 1.2 i,3 NO NO NO 02i21117 02.2 ND ND NO NO NO ND NO 41 ki NO NO NO OEM9117 ND NO NO. NO 1350 NR NR NR 12.1 NO NO NO ND =201f9 9.5 O M NO NO ND NO NO ND 032 1.2 NO NR NR owllis NO NO 11 NO I NO I NO NO NO NO NO NO NO NR NR 0211911a NS - PER REQUEST FROM NCDEO 06/12/19 NO NO NO NO NO NO NO NO I NO 2.9 NO NO MR DMW-5 O111012 197 NO NO NO NO NR NR NR 7.9 13.9 NO ND NO 02YEW12 194 2.5 ND NO NO NR NR NR 75 i2.2 NO ND NA OOW12 7BA ND ND NO NO NR NR NR 72 11.4 ND NO NO t1M14 27,2 NO NO NO NO NR NR NR 4 5.1 NO NO NO 05f25114 2-9 ND NO NO ND NR NR NR 24 2A NO NO N❑ 02f09115 21.5 ND NO ND ND NR MR NR 2.3 3.7 ND NO NO 0&17115 5.2 NO ND ND NO NR NR NR 15 2 NO NO NO 021 le 2 ND NO Np NO NR NR NR 22 2.4 NO ND NO O913W16 1.6 12 ND NO ND NR NR NR 6 5.9 NO ND NO 02RI117 22 NO ND No NO 12a ND NO 66 &A NO NO NO 091MV 0.75 1.7 NO NO NO NR NR MR 5.3 &1 NO NO NO 02/1Or18 3.2 NO NO ND NO 289 NO 14.1 115 13 NO MR NR 05GIMB IlI NO NO NO NO 276 ND 16A 14.1 16.3 NO NR NR 0211W19 17 AID NO ND ND 399 NO 1913 146 M.1 NO NR NR O&12119 ND NO ND kO NO ND NO ND NO NO NO NO NR WSW-1 04l1&97 NO I ND NO NO NO NR NR NR ND NO NR NR NA 11r12197 NO ND N4 NO RD NR NR MR NO NR NA NR MA O2:WW NO I ND I NO NO ND NR NR NR NO NR NA I NR NA 02123f01 ND ND NO NO ND NR NR I MR ND ND NA I NR NA Wf07+11 Well AbarWorlW WSW-2 05M4r04 c1.0 -50 c1.0 a20 41-0 NR NR NR s10 0.50 NA -10 NA 0512&08 c1 ❑ c! 0 c1-0 s30 s1.0 MR NR NR <1.0 0.0 NA NR NA 04fFBr09 NO NO NO NO NO MR NR NR NO NO NO NO NR D&2a1fo NO NO NO NO NO NR MR NR NO NO NO NR NO 01mi2 NO NO NO NO NO NR NR NR NO NO NO NR NO 02126hil ND ND NO NO NO NR MR NR No NO NO ND ND 0&25114 NO NO NO NO NO NR NR NR NO NO NO ND ND 02109115 Not S4ma44. NO Power to Well 08017115 Not S rad - No Power to Wall WSW-2 (Cart.) 02122/16 Not Somptad - No Power to Well {i613Ol16 Not Sim Iod - No Power to W40 02/2717 Not Sampled - No Power10 Waif DIU!,7 Not 5am lad- Won 4t11tndoned WSW-3 04110MO NO NO NO ND NO MR NR NR NO NO NO NO NR 0Bf28mo NO ND N❑ NO NO MR MR NR NO NO NO NR 20•S 01MV12 ND ND N❑ NO NO NR MR NR NO ND NO NR 25.9 02126114 ND N❑ NO NO NO NR NR NR NO NO NO NO ND OWW14 NO NO NO ND NO MR NR NR NO ND NO NO NO 02f09115 NO NO NO NO NO NR NR MR NO NO ND NO NO 05117115 NO NO NO MD MD MR NR NR NO ND ND NO NO 02/22/16 Not Sampled - Not R ulred NCDEO OBYd01 to NOl 542rdNo Power td Wait 021211f7 N❑ NO NO NO ND NO ND NO NP ND NO NO S2 0&C8117 Not Sam ed • No Power to Wall H-Mn�cdl�lll3llWenal-01C 1%Ca "S-MgpM l?&A191TOM 4-HwMd Qrpndwrml tape!.rs Tablc 4: summary or Historical Groundwaler Ana lytkal Results Carl's Country Stare 8952 Daridsod Highway Coocerdf Ca barros County, North Carolina Facility 1D Number 0-OO747O 1 ocidmt Number 9362 Shield Pro'ecl Number 1090032 Ana ,cal Mdthod • .• EPA G02 6011602 or 6200R EPA 504 1 er52003 EPA 200 7 dr 6010 Anelyle ••-•••-� 8anrsne Toiuene Elhyl- bamx a Total Xylenes msthyl-tart- butyl alher (MTSE) Earl-�� Akohd len- Amytmelhyl et er tent-Ruto No"ettl0r Diisopropyl t.IPE} 1,2• Dichldroe thane Naphlha]ane 1.2-Dlhromo-e!hane 1;ED6j Total Lead rtdarWI 10 600 S00 500 20 40 129 10 70 04 5 002 15 GC L 5 000 280 000 54 5D0 85 500 20 000 40 000 128 000 10 000 70 000 400 0 ODO 50 15 000 Sarnpse location Data Sam `.ed (w) 1u9A) [uem (,ga) WA (UWI) (UV) (ugn) (ug+l) {ugll} WSW-4 05WdrD4 <1.0 450 c10 c20 cs0 NR NR NR <70 <050 NA ef0 NA 05128f06 c1.p ct 0 c1 0 c3-0 <1.9 NR NR NR et 0 <i 0 NA NR NA dvls?D9 NO NO ND ND NO j NR I NR NR ND NO No I NO NR 06125r10 Not Se G<due to No Water Flow 01112/12 Nat SaMI 48C due 10 No Water Flaw OZW12 ND NO NO ND NO NR NR NR NO NO NO NO NO 0212014 ND ND NO ND NO NR NR NR NO NO ND NO ND OWW14 NO NO NO NO NO NR NR NR NO ND NO N❑ ND 0210 IS RD NO NO NO NO NR NR NR NO NO ND NO NO 03117115 ND HD NO NO NO NN NR NR NO ND ND NO NO 02722/16 NGI Sa kd -NdftRO0U,rddbVNCOEQ OO W16 NO ND NO NO NO NR NR NR NO NO NO NO NO 021Y1117 NA ND NO NQ NO NO NO NO NO NO NO NO NO OBf09117 NO ND NO NO NO NR NR NR ND NO NO No N WSW-6 05MM4 <10 c6.0 <10 420 41.0 NR NR NR c1.0 450 NA c1.0 NA 11 m 410 0.0 410 -30 41.0 NR NR NR c1 0 41.0 NA NR NA 0411SW9 NO NO NO NO NO NR RR NR NO ND NO ND NR DOW10 NO ND NO Np NO NR NR NR NO NO NO NR NQ 02MN14 NO N❑ NO ND N NR NR NR NO NO NO N❑ NO 05P25114 NO N❑ NO NO NO NR NR NR NO NO NQ ND NO 02W9115 NO ND NO ND NO Nk NR NR NO NO NO NO RO 08/17/15 NO ND NO N❑ ND NR NR I NR NO NO NO ND NO 02/22/18 Not Sampled - Not Required by NCOEO 0813W18 NOISa la -NOIR4q-ir"byNGDEQ 02/21/17 Nut Si lad - No1 Rd unad by NC OEQ [IBN9117 NO NO NO NO ND NR NR NR NQ NO NO NO NO WSW-7 05r04M4 41.0 45-0 41-0 <20 41.0 NR NR NR el0 <050 NA c1.0 NA 11I08W7 <1.0 <1 0 <1.0 <3.0 41.0 NR NR NR ct 0 c1 0 NA NR NA 04116W9 NO NO NO N❑ ND NR NR NR NO NO ND NO NR W28110 HD NO NO No ND RR NR NR NO NO N❑ NR ND OVZW14 NO NO NO No NO NR NR NR NO NO NO ND 2l.1 Oaf2504 NO NO NO NO ND NR NR NR NO NO ND NO NO 02N9115 NO NO NO ND ND NR IN, NR NR NQ NQ ND NO NO MIMS ND NO ND NO No NR NR N13 ND ND ND NO 0=21i6 Not Si - Not Required q NCDEQ 0813W16 NatSa d-NolR used NCDEQ 02121N7 Not Sa d -NolliewradbyNCDEtl Del07117 NO ND Nb NO ND NR NR NR NO NO NA ND NO W54V•6 DWWM4 �1.0 c5.0 41.0 42.0 410 NR NR NR 41.0 4&50 NA 410 NA 05/28/08 �1-0 41.0 <1-0 43.0 41.0 NR NR NR 41-0 41-0 NA NR NA D012WI0 NO NO ND NO NO NR NR NR ND ND NO NR NO 0212W14 NO NO NO NO NO NR NR NR NO NO NO NO NO 0&25014 NO NO ND NO NO NR NR NR NO NO NO NO NO 02MW15 NA NO NO NO ND NR NR NR ND NO NO NO NO 0107115 NO NO NO I ND I No NR NR NR NO NO NO NO NO 0212P118 Nat Sampled - Mal R uued NCDEQ 98100116 Not Sem ed - Not R ured CDEQ (2/21/17 Not 59001od • N71 Rettutretl by NC DE WSW-9 05/04104 -10 c50 11.0 s20 <1.0 NR NR NR 410 <0.50 NA e1-0 NA D512aw c10 00 41-2 <30 41.0 NR MR NR 0.0 41-0 NA NR NA 05125/10 NO NO NO NO NO NR NR NR NO NO NO NR NO 0TMWI2 NO ND NO NO NO NR NR NR ND NO NO NR NO 02126r14 11.3 ND NO NO NO NR NR NR NO NO NO N❑ NO 08W25)$4 ND ND NO NO ND NR NR NR NO NO NO N❑ NO 02+9e115 NO ND NO NO NO NR NR NR NO ND NO NO NO D&}7115 NO NQ NO NO NO NR NR NR NO NO NO HO NO D2122116 Not Sam led -Not u NCDEQ OW30116 ND NO ND NO ND NR NR NR NO NO NO ND NO 02/21117 N❑ ND NO NO NO 90 NO NO NO NO NO NO ND 0510W17 ND NO NO ND NO NR NR NR NO NO NO NO N❑ 02t20116 ND ND NO NO NO ND 1412 NO NO NO NO NR NR 0813111e NO ND ND N❑ NO NO NO NO NO NO ND NR NR 0211911E NO NO NO ND NO NO NO NO NO NO NO MR NR 08/12119 NO No No NO NQ ND NO NO NO NO NO ND NR H.1PrejecdLVd.Rf090(132-01C9'a CaW rSia¢1RryorAtMfl 820191i.hrd 1bNblG�ndwnMr P.W5d6 Table 4: Summary o€Ilistorica€ Grouindwater Analytical Resells Carl's Country Store 8952 ➢ayidaorr Highway Concord, Cabarrua County, North Carolina Faeility I Number 0-007470 Inoident Number 9362 Shield Pro•e¢i Number 109DW2 AiraNilcal Named —a EPA 602 601l502 or 62410E EPA 504 1 vre20 0 EPA 200 7 0050:0 Malyle —••••� Benzene Toluene Ethyi• benzana To!ai Xylenes Mafhyl-tart- bu yP Other (MTBE) lent -Amyl AlcDhal red Amylmathyl ether tuft-BuyOasopropyt Alcohol ether (IPE) 7,2• DiefdoraeEhslee Naphthalene 5,2-Dlbram�ethe M1e tEDBj Total Lead 21. Standwd[IWAC 10 eat? OOa 500 20 40 128 10 t0 04 6 002 75 CL 5.000 260.000 84.500 95.500 2a OE10 40 0W 128.000 f0 000 7a 000 400 8 000 "so 75 p 00 Semple lmn Lvr�tion Sampled e (uWI) WI) (uWI) NO) (ugri) (uo) (u91f) [ego) W91'1 Pug1!1 Warl] (41) (UP WSW-17 o5M4l04 -10 <50 c1.0 c20 c1.o NR NR NR c1.0 Q.50 NA c1.0 NA 05 aW 00 <7.0 <to <30 <10 NR NR NR <1.0 <to NA NR NA OW&10 NO ND NO ND NO NR NR NR NO NO NO NR 146 02=14 ND NO NO ND NO NR NR NR NO NO NO NO NO GWW14 ND NO NO ND NO NR NR NR NO NO NO NO NO 0270&15 ND NO NO NO ND kR NR NR NO NO NO NO ND W17115 NO ND ND ND NO NR NR NR NO NO NO NO NO 0212R718 Not Sam l4d • Not Required by NCDEQ 08r30716 Net Sam - Not Required by NCOEO 02/21117 Nol 7iam ad • Nos R ulnae kCOEO 0e104l77 NO ND NO No NO NR NR HRI NO T NO ND NO ND WSW7e MIM10 Not sampled due Id Nd water low 02rM14 Nei UMP41M due to N0 Water flbrr OSQ6114 Not sarrWed Unable to Lormte 02M9115 Not slim lad Unable to Laca7a ORF17)15 Nd4 sam ed Unable to Locale 02/22/75 Nei S lad • NOt R.eguiradtoy NCO O OSP301fe Net Sampled • NO Wen visgslo an Property 02/21/17 Nei sanvrad - No Welt Visible an A TRW BLANK L1012&70 NO NO NO NO NO NR NR NR NO NO NO NR NR oUW12 No NO NO NO NO NR NR NR NO ND NO NR NR 02/MU NO NO NO NO No NR NR NR NO NO NO NR NR aW&14 NO NO NO NO NO NR NR NR NO NO ND NO NR 02109l15 NO NO NO NO NO NR NR NR NO NO NO NO NR =17115 NO NO NO NO NO NR NR NR NO NO NO NO NR 02722r16 NO NO NO NO NO NR NR NR NO NO NO N❑ NR 08►iW1B NO NO NO NA NO NR NR NR NO NO N❑ ND NR 02f11117 N4 ND N❑ Nq ND ND ND N❑ ND ND ND NR CEW17 No ND Nfl NO NR NR NR No NO N❑ N❑ NR 0MV1e NO EN N❑ N13 ND NR NR NR NO NO N❑ N❑ NR W12119 NO ND NO NO N❑ N❑ NO NO NO ND N❑ NR uglf = micrngmms per liter NO - Nei detected M or above laboratory method report limit NS = Net Sampled NR =Analysis Nei Regve sled NA = Data Not Avaira bl a NE = Not established Less than the Tabora" melhad report land NCOEO - Ndrltl Carolina Depafifnent of EnvironalaniN Ouatry (formarly North Carolina Department of Enviranmew and Natural Resources) 2L Standard = NCDENR-North Carahna Adimliristrati" Code Title 15A Subchapler 2L Class GA Gmundwater Standards IMAC= Interim Maximum ANows bta Concentrations GCL = NCDENR-North Camlins Adminiatratiive Code Trne 15A Subchapter 2L Standard far Rnit-B used Maximum Grass Contamination Levale For Groundwater BOLD denoMs cancaniraa Dos above 15A NCAC 2L Standards or'MAC s Dale prior to 4/1(112009 reported by olhats II:IPrq��?�'�ioaDDD2U1 Carly U—nhr &b Wv )UR 920191T�.4 - Hi.k SYnn U, P.D. a to GRAPHS) W y F Ei m` o � N p� 7 GY 2- LL1 y C T i m o r o Q m H w r � t7 t;aa;j uOl;eAG13 ja;rempunOl!D O C) O O O O Q Q a G O 0 O a Q C, G O O O o a o a et vi CN r a Cl) OD r� (D LO qCr m 00 co 00 0a as r-- rl- r` rl- ti r- r- n 0 v N O co o W Nr N IllBnj ual;ei;uaau0o 6t'G ma`s ov a� sty s °o �tt7 �D �` el t J y o �'e, l4_ p �t'✓ a� poi, moo, oa �h sad as col 0 w m v d o y a m Lu c N t m T2 iI}17 1 (;aa)y UORVAa13 joiBmpunoj!D C p O Q p v O v Q Q 9 O a v a� OD coo � � � n v a o v a v v v C> O 0 O v C> O C v v A a v v a n co r— (D LO v cn cv r [-I/6n] uoi;eijuaouoo ,gz;, �O c''Y `'o `e 20 SZ1, 14`, 0 4rd,)''o aQ sa r,, 1pa o rjo �Qk kp 9a �0' a �901 o 21�10 Ln o of z o a 70 0 v `V, a `'o w oro m o m a m m c o Ni C c � c n (;aal) u01;ena13 aajempunniE) 9 CJ O O Q It m 04 v rn ao 00 0o co 00 00 r` r` rl- vo a o 0 c0 u'i � ri a (v a vo o o v6ua 00 r` 0 ) a�it}eo r O6, J A .e, JN �. �O say, 8 � Gt� 5 �' toO� io 00, z ad of O;?J S:/ -76 ,g r� n61 10 A � v � VL Ra uoie! n ; ,mempunoj e 0 0 o c o 0 0 0 0 0 0 9 9 9 R 9 9 0 9 9 0 0 2 7 2 q % 2 ¢ f \ � r- R 2 0 q S ? 0 2 � n n a r (l ee)uglelua,uoo 0 a ? w m adi m a m N � c N Q fif Z (7 (;aa;) ua:;ienaja aa;empunojo d Q a a a O O o a a o 0 o 0 a o o� 0:)0No OOo r- � ti ti Q a O 0 Cl d N o 0o 0 v 04 r r (716n) uoi;ej;ua-3uo3 n m 2 ry 0001) uvl}ena13 jolumpunoaE) v voo9 a n a v o a a a a a a a a a 9 Ql co E— co Ln qr co N r O co O� C(D Lo � co N O fl (-Ii6n) uoijailuaouoo m Q E� P _� ui = 7 :3 C a ov C � G1 V L1 C O [;aa;j uol;ena13 ja;empunopD N (DLONrMNQ co O L v Ln o N CV � (-116n) uoi}e4ueouo3 APPENDIX A Carl's Country Store Calibration and Field Measurment Log Field Meter YSI Pro Plus Calibration Standard Pre -Calibration Read Calibration Read pH 7 7 7.01 7.00 pH 4 4 4.00 4.00 pH 10 10 9.98 10.00 Spec Cond (us/cm) 1413 1415 1413 ORP (mVolts) 200 202 200 Field Measuremnt Log ID DO pH Spec Cond (us/cm) Temp (0Q ORP (mV) MW-1 3.6 5.8 47.3 26.4 162.2 MW-2 1.12 5.71 412 22.6 59.6 MW-4 2.43 6.1 161.3 25.4 81.4 MW-5 1.55 5.63 170.3 24.1 88.2 MW-6 3.43 5.98 107.1 26.1 124.9 MW-7 4 6.53 97.9 26.2 93.9 MW-9 1.48 5.34 66.7 25.6 160.9 MW-10 0.82 6 517 22.0 6.3 DMW-1 1.88 6.27 495.2 23.2 88.9 DMW-3 1.23 6.32 356.6 22.2 132.2 DMW-4 3.09 6.07 365.8 22.0 92.3 DMW-5 4.41 6.87 93.5 27.4 65.6 WSW-9 4.58 6.96 125.4 19.6 61.1 APPENDIX B aceAnalyfical WWW-Pacela6a oom I September 09, 2019 Matt Smith Shield Engineering 4301 Taggart Creek Road Charlotte, NC 28208 RE: Project: Carl's Country Store Pace Project No.: 92441209 Dear Matt Smith: Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 [704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on August 13, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. This revision was issued on 09/09/19 to correctly report analyte list as per COC. If you have any questions concerning this report, please feel free to contact me. Sincerely, VCA] • tdh Amanda Payne amanda.payne@paGelabs.com (704)875-9092 Project Manager Enclosures cc: James Gamerisfelder, Shield Engineering, Inc. Mr. Tom Witner, Shield Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 48 (�IaeAnalytical www.p80ef81?S- am Projects Carl's Country Store Pace Project No.: 92441209 Charlotte Certification Ids 9800 Kinoey Ave. Ste 100, Hunto rsville, NC 28078 LouisianalNELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #! 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 FloridalNELAP Certification #: E87627 Kentucky UST Certification #: 84 VrginiaAIELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services. LLC. Pace Analytical Services, LLC 9800 Kin cey Ave. Suite 100 Huntersville, NC 2a078 (704)875-9092 Page 2 of 48 m l'!;a nww psc6labs com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: Carl's Country Store 92441209 Analytes Lab I❑ Sample IQ Method Analysts Reported Laboratory 92441209001 MW-1 SM 6200B GAW 69 PASI-C 92441209002 MW-2 SM 6200B CL 69 PASI-C 92441209003 MW-4 SM 6200B CL 69 PASI-C 92441209004 MW-5 SM 6200B CL 69 PASI-C 92441209005 MW-6 SM 6200B GAW 69 PASI-C 92441209006 MW-7 SM 6200B GAW 69 PAS]-C 92441209007 MW-9 SM 6200B GAW 69 PASI-C 92441209008 MW-10 SM 6200B GAW 69 PASI-C 92441209009 DMW-1 SM 6206E GAW 69 PASI-C 92441209010 DMW-3 SM 62008 GAW 69 PASI-C 92441209011 ❑MW-4 SM 62008 GAW 69 PASI-C 92441209012 DMW-5 SM 62008 GAW 69 PASI-C 92441209013 WSW-9 SM 62006 GAW 63 PASI-C 92441209014 Trip Blank SM 6200B GAW 69 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 48 aceAnalytical wwwpacelabs.cnm 1 ANALYTICAL RESULTS Project: Carl's Country Store Pace Analytical Services, LLC 9800 KinceyAve. Suite too Huntersville, NC 28078 [704]875-9092 Pace Project No.: 92441209 Sample: MWA Lab ID: 92441209001 Collected: 08/12/19 13:25 Received: 08113/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B tert-Amyl Alcohol NO uglL 100 1 08/15/19 02:07 75-85-4 tert-Amylmethyl ether NO uglL 10.0 1 08/15/19 02:07 994-05-8 Benzene NO uglL 0.50 1 08/15119 02:07 71-43-2 Bromobenzene NO uglL 0.50 1 08/15/19 02:07 108-86-1 Bromochloromethane NO uglL 0.50 1 08/15/19 02:07 74-97-5 Bromadichloromethane NO uglL 0,50 1 08/15/19 02:07 75-27-4 Bromoform NO ug1L 0.50 1 08115/19 02:07 75-25-2 Bromomethane NO uglL 5.0 1 08/15/19 02:07 74-83-9 tert-Butyl Alcohol NO uglL 10.0 1 08/15/19 02:07 75-65-0 n-8utylbenzene ND uglL 0.50 1 08/15/19 02.07 104-51-8 sec-8utylbenzene ND uglL 0.50 1 08115/19 02:07 135-98-8 tert-Butylbenzene N❑ uglL 0.50 1 0811511902:07 98-06-6 tert-Butyl Formate ND uglt- 20.0 1 08/15/19 02:07 762-75-4 Carbon tetrachloride ND ug1L 0,50 1 08115/19 02:07 56-23-5 Chlorobenzene NO uglL 0.50 1 08/15/19 02:07 108-90-7 Chloroethane NO uglL 1.0 1 08/15/19 02:07 75-00-3 Chloroform ND ug1L 5.0 1 08/15/19 02:07 67-66-3 Chloromethane NO uglL 1.0 1 08/15/19 02:07 74-87-3 2-Chlorotoluene NO uglL 0.50 1 08/15119 02:07 95-49-8 4-Chlorotoluene ND uglL 0,50 1 08115/1902:07 106-43-4 1,2-Dibromo-3-chloropropane ND uglL 1.0 1 08/15/19 02:07 96-12-8 Dibromochloromethane ND ug1L 0.50 1 08/15/19 02:07 124-48-1 1,2-Dibromoethane [EDB] NO uglL 0.50 1 08/15/19 02:07 106-93-4 Dibromomethane ND uglL 0.50 1 08/15/19 02:07 74-95-3 1,2-Dichlorobenzene NO ug)L 0.50 1 0811511902:07 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 1 08/15/19 02:07 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 06/15/19 02:07 106-46-7 Dichlorodifluoromethane ND uglL 0.50 1 08/15/19 02:07 75-71-8 1,1-Dichloroethene NO ug1L 0.50 1 08/15/19 02:07 75-34-3 1,2-Dichloroethane NO ug1L 0.50 1 08/15/19 02:07 107-06-2 1,1-Dichloroethene NO uglL 0.50 1 08115/1902:07 75-35.4 cis-1,2-Dichloroethene N❑ uglL 0,50 1 08/15/19 02:07 156-59-2 trans-1,2-Dichloroethene NO uglL 0.50 1 08115/19 02:07 156-60-5 1,2-Dichloropropane N❑ uglL 0.50 1 08115/19 02:07 78-87-5 1,3-Dichlaropropane NO ug1L 0.50 1 08115/1902:07 142-28-9 2,2-Dichloropropane ND uglL 0.50 1 0811511902:07 594-20-7 1,1-Dichloropropene NO uglL 0,50 1 08115/1902:07 563-56-6 cis-1,3-Dichloropropene ND uglL 0,50 1 0811511902:07 10061-01-5 trans-1,3-Dichloropropene ND uglL 0,50 1 08/15/1902:07 10061-02-6 Diisopropyl ether ND uglL 0,50 1 08115119 02:07 108-20-3 Ethanol NO uglL 200 1 08/15/19 02:07 64-17-5 Ethylbenzene NO ug1L 0,50 1 08/15119 02:07 100-41-4 Ethyl-teri-butyl ether NO ug1L 10.0 1 08/15/19 02:07 637-92-3 Hexachi oro-1,3-butadiene ND ug1L 2.0 1 08/15/19 02:07 87-68-3 Isopfopylbenzene (Cumene) NO uglL 0.50 1 08/15/19 02:07 98-82-8 Methylene Chloride NO ug1L 2.0 1 08/15/19 02:07 75-09-2 Methyl-terl-butyl ether NO uglL 0.50 1 08/15119 02:07 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2019 12:26 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 48 aceAnalj6cal + -mrw.pacelabs.com f ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No_: 92441209 Pace Analytical Services, LLC 9800 Kin cey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 sample: MW-1 Lab lD: 92441209001 Collected: 08112119 13:25 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit 6200E MSV Analytical Method: SM 6200B Naphthalene N❑ uglL 2.0 n-Propylbenzene ND ug)L 0.50 Styrene ND ugJL 0.50 1,1,1,2•Tetrachloroethane ND ug1L 0.50 1,1,2,2-Tetrachloroetharse N❑ ug1L 0.50 Tetrachlorcethene ND ug1L 0.50 Toluene ND ug1L 0.50 1,2,3-Trichlorobenzene ND ug1L 2.0 1,2,4-Trichlorobenzene ND ug1L 2.0 11,1-Trichloroethane ND ug/L 0.50 1,1,2-Trichloroethane ND uglL 0.50 Trchloroethane ND uglL 0.50 Trichloroflueromethane NO uglL 1.0 1,2,3-Trichloropropane ND uglL 0.50 1,2,4-Trimethylbenzene N❑ uglL 0.50 1,3,5-Trimethylbenzene ND uglL 0.50 Vinyl chloride ND uglL 1.0 m&p-Xylene ND uglL 1.0 o-Xylene ND uglL 0.50 Surrogates 1,2-Dichloreelhane-d4 (S) 101 % 70-130 4-Bromotlucrobenzene (S) 101 % 70-130 Toluene-0 (S) 102 % 70-130 Date: 09109120i9 12:28 PM DF Prepared 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analyzed CAS No. Qual 05/15119 02:07 91-20-3 08 / 15111302: 07 103. 65-1 08/15/19 02:07 100-42-5 08/15119 02:07 630-20-6 08/15/19 02:07 79-34-5 08/15/19 02:07 127-18-4 08/15/19 02:07 108-88-3 08115/19 02:07 87-61-6 08/15/19 02:07 120-82-1 08/15/19 02:07 71-55 6 08/15/19 02:07 79-00-5 08/15/19 02:07 79-01-6 08/15/19 02:07 75-69-4 06/15/19 02:07 96-1" 08/15/19 02:07 95-63-6 08/15/19 02:07 108-67-8 08115119 02:07 75-01-4 08/15/19 02:07 179601-23-1 08/15/19 02:07 95-47-6 08115/19 02:07 17060-07-0 08/15/19 02:07 460-00-4 08115119 02:07 2037-26-5 Page 5 of 48 aceRnalXical + wwwpscNabaceom I ANALYTICAL RESULTS Project: Carl's Country Store Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 2807E (704)875-9092 Pace Project No.: 92441209 Sample: MW-2 tab ID: 92441209002 Collected: 08/12/19 13:39 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 8200E M5V Analytical Method: SM 6200B tert-Amyl Alcohol 1400 ug1L 1000 10 08/15/19 18:15 75-854 ter[-Amyimethyl ether NO ug1L 100 10 06/15/19 18:15 994-05-8 Benzene ND ugiL 5.0 10 08/1511918:15 71-43-2 Bromobenzene N❑ ug1L 5.0 10 0811511918:15 108-86-1 Bromochloromethane ND ugiL 5.0 10 08115/1918:15 74-97-5 Bromodichloromethane NO ugiL 5.0 10 08115/1918:15 75-27-4 Bromoform ND ugiL 5.0 10 0811611918:15 75-25-2 Sfomomethane N❑ ugiL 50.0 10 08/15/19 1 BA 5 74-83-9 L1 tert-Butyl Alcohol 7980 ugiL 100 10 08115/19 18:15 75-65-0 n-Butylbenzene ND ugiL 5.0 10 0811511918:15 104-51-8 sec-Butylbenzene NO ugiL 5.0 10 08/15/1918:15 135-98-8 tert-Butylbenzene ND ug1L 5.0 10 08115/1918.15 98-06-6 tert-Butyl Formate ND ug1L 200 10 08/15/19 18:15 762-75-4 Carbon tetrachloride ND ugiL 5.0 10 08/15/19 18:15 56-23-5 Chlorobenzene ND ug1L 5.0 10 0811511918:15 108-90-7 Chloroethane N❑ ug1L 10.0 10 08/1511918:15 75-00-3 Chloroform ND ug1L 50.0 10 08/1511918:15 67-66-3 Chlaromethane ND ugiL 10.0 10 08/1511918:15 74-87-3 2-Chlorotoluene ND ugiL 5.0 10 08/1511918:15 95.49.8 4-Chlorotoluene ND ugiL 5.0 10 08115/1918:15 106-43-4 1,2-Dibromo-3-chloropropane ND ugiL 10.0 10 OW1511918:15 96-12-8 Dibromochloromethane NO ugiL 5.0 10 08/1511918:15 124-48-1 1,2-Dlbrornoethane (EDB) NO ugiL 5.0 10 08/15/19 18:15 106-93-4 Dibromomethane NO ugiL 5.0 10 08115/1918:45 74-95-3 1,2-Dichlorobenzene ND ugiL &0 10 0811511918:15 95-50-1 1,3-Dichiorobenzene ND ug1L 5.0 10 0811511918:15 541-73-1 1,4-Dichlorobenzene ND ug1L 5.0 10 081151191815 106-46-7 Dichlorodifluoromethane NO ugiL 5.0 10 0811511918:15 75-71-8 11-Dichloroe(hane NO ug1L 5.0 10 0811511918:15 75-34-3 1,2-Dichloroethane ND ugiL 5.0 10 08/15/1918:15 107-06-2 1,1-Dichloroethene ND ugiL 5.0 10 08115/1918:15 75-35-4 cis-1,2-Dichloroethene ND ugiL 5.0 10 08115/1918:15 158-59-2 trans-1,2-Dichloroethene NO ugiL 5.0 10 08/1511918:15 156-60-5 1,2-Dichloropropane ND ugiL 5.0 10 08/1511918:15 78-87-5 1,3-Dichloropropane NO ugiL 5.0 10 08115/1918:15 142-28-9 2,2-Dichloropropane N❑ ugiL 5.0 10 0811511918:15 594-20-7 1,1-Dichloropropene IN ug1L 5.0 la 08/15/1918:15 563-58-6 cis-1,3-Dichloropropene ND ugiL 5.0 10 08/1511918:15 10061-01-5 trans- l,3-Dichloropropane IN ugiL 5.0 10 08115/1918,15 10061-02-6 Diisopropyl ether 34.6 ugiL 5.0 10 08115M9 18:15 108-20-3 Ethanol ND ug1L 2000 10 081151191815 64-17-5 Ethylbenzene N❑ ugiL 5.0 10 0811511918:15 100-41-4 Ethyl-tert-butyl ether NO ugiL 100 10 08/15/19 18:15 637-92-3 Hexachloro-1,3-butadiene NO ugiL 20.0 10 08115/1918:15 87-68-3 Isopropylbenzene (Cumene) NO ugiL 5.0 10 08/15/19 1815 98-82-8 Methylene Chloride NO ugiL 20.0 10 08/15119 18:15 75-09-2 Methyl-tert-butyl ether 1350 ugiL 5.0 10 08/15/19 18:15 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in lull, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 48 aceAnalj6cal www.paeefabs.cam ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: l Carl's Country Store Pace Project No.: 92441209 Sample: MW 2 Lab lD: 92441209002 Collected: 08112119 13:39 Received: 08113/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qua! 6200B MSV Analytical Method: SM 6200B Naphthalene ND uglL 20,0 10 0811511918:15 91-20-3 n-Propy€benzene N❑ ug1L 5.0 10 08/1511918:15 103-65-1 Styrene ND uglL 5.0 10 08/15/1918:15 100-42-5 1,1,1,2-Tetrachloroethane ND uglL 5.0 10 0811511918:15 630-20-6 1,1,2,2-Tetrachloroethane N❑ uglL 5.0 10 08115/1918:15 79-34-5 Tetrachloroethene ND uglL 5.0 10 08/1511918:15 127-18-4 Toluene ND uglL 5.0 10 0811511918:15 108-88-3 1,25-Trichlorobenzene ND uglL 20-0 10 0811511918:15 87-61-6 1,2,4-Trichlorobenzene ND ugJL 20.0 10 08115/1918:15 120-82-1 1,1,1-Trichloroethane ND ug1L 5.0 10 08/1511918:15 71-55-6 1,1,2-Trichloroethane N❑ uglL 5.0 10 0811511918:15 79-00-5 Trichloroethene ND ug1L 5.0 10 0811511918:15 79-01-6 Trichlorafluoromethane ND ug1L 10.0 ifl (18/1511918-15 75-69-4 1,2,3-Trichloropropane ND ug1L 5.0 10 0811511918:15 96-18-4 1,2,4-Tdmethylbenzene 6.5 ug1L 5.0 10 0811511918:15 95-63-6 1,3,5-Trimethyibenzene ND ug1L 5.0 10 08115/1918:15 108-67-8 Vinyl chloride ND ug1L %0 10 08/15/19 18:15 75-01-4 m&p-Xylene N❑ ug1L %0 10 08115/1918:15 179601-23-1 o-Xylene N❑ ug1L &0 10 0811511918:15 95-47-6 Surrogafes 1,2-Dichloroethane-d4 (S) 104 % 70-130 10 08/15/19 18:15 17060-07-0 4-Bromofluarobenzene (5) 98 % 70-130 10 08/15/19 18:15 460-00-4 Toluene-d8 (S) 101 % 70-130 10 08/15/19 18:15 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 48 ! i ClGG11a1iCa1 f www.pacelabs.cum f ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: MW-4 Lab ID: 92441209003 Collected: 08/12/19 13:49 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit, DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B tent -Amyl Alcohol NO uglL 100 1 08/15/19 16:09 75-85-4 ter[-Amylmethyl ether NO ug1L 10.0 1 08/15/19 16:09 994-05-8 Benzene 6.5 uglL 0.50 1 08/15/1916:09 71-43-2 Bromobenzene ND uglL 0.50 1 0811511916:09 108-86-1 Bromochloromethane NO ug1L 0.50 1 08/15/1916:09 74-97-5 Bromodichloromethane NO uglL 0150 1 0811511916:09 75-27-4 Bromoform ND uglL 0.50 1 08/15/1916:09 75-25-2 Bromomethane NO uglL 5.0 1 0811511916:09 74-83-9 L1 tert-Butyl Alcohol 65.0 uglL 10.0 1 08/15/19 16:09 75-65-0 n-Butylbenzene NO uglL 0.50 1 D811511916:D9 104-51-8 sec-Butylbenzene NO uglL 0.50 1 0811511916:09 135-98-8 tert-Butylbenzene NO ug1L 0.50 1 0811511916:09 98-06-6 tert-Butyl Formate NO ug1L 20.0 1 08/15/19 16:09 762-75-4 Carbon tetrachloride NO ug1L 0.50 1 08/15/19 16:09 56-23-5 Chlorobenzene NO ug1L 0.50 1 08/1511916:09 108-90-7 Chloroethane NO ug1L 1.0 1 08/1511916-09 75-00-3 Chloroform ND ug1L 5.0 1 08/16/1916:09 67-66-3 Chloromethane NO ug1L 1.0 1 08/1511916:09 74-87-3 2-Chlorotoluene NO ug1L 0.50 1 08115/1916:09 95-49-8 4-Chlorotoluene ND ug1L 0.50 1 08/1511916:09 106-43-4 1,2-Dibromo-3-chloropropane NO uglL 1.0 1 08115/1916:09 96-12-8 Dibromochloromethane NO ug1L 0.50 1 08115/1916:09 124-48-1 1,2-Dibromoethane (EDB) NO uglL 0.50 1 08/15119 16:09 106-93-4 Dibromomethane NO uglL 0.50 1 08115/1916:09 74-95-3 1,2-Dichlorobenzene NO ug1L 0.50 1 0811511916:09 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 1 0811511916-09 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 0811511916:09 106-46-7 Dichlorodifluoromethane NO uglL 0.50 1 08115/1916:09 75-71-8 1,1-Dichloroethane NO uglL 0.50 1 0811511916:09 75-34-3 1,2-Dichloroethane NO uglL 0.50 1 0811511916:09 107-D6-2 1,1-Dichloroethene IN ug1L 0.50 1 0811511916:09 75-35-4 cis-1,2-Dichloroethene ND ug1L 0.50 1 0811511916:09 156-59-2 trans- 1,2-Dichloroethene NO uglL 0.50 1 08/1511916:09 156-6D-5 1,2-❑ichloropropane NO uglL 0.50 1 08115/1916:09 78-87-5 1,3-Dichloropropane ND uglL 0.50 1 08/15/1916:09 142-28-9 2,2-Dichloropropene NO uglL 0.50 1 08/1511916.09 594-20-7 1,1-Dichloropropene NO uglL 0.50 1 08/15/1916:09 563-58-6 cis- 1,3-Dichloropropene NO uglL 0.50 1 0811511916:09 10061-01-5 trans- 1,3-Dichloropropene ND uglL 0.50 1 08/1511916:09 10061-02-6 Diisopropyl ether 1.9 uglL 0.50 1 08/15/19 16:09 108-20-3 Ethanol NO uglL 200 1 08/15/1916:09 64-17-5 Ethylbenzene NO uglL 0.50 1 0811511916:09 100-41-4 Ethyl-tert-butyl ether ND ug1L 10.0 1 08/15/19 16:09 637-92-3 Hexachloro-1,3-butadiene NO ug1L 2.0 1 0811511916:09 87-68-3 Isopropylbenzene (Cumene) NO ugll- 0.50 1 08/15/19 16:09 98-82-8 Methylene Chloride N❑ uglL 2.0 1 08/15119 16:09 75.09-2 Methyl-tert-butyl ether 34.0 uglL 0.50 1 68/15119 16:09 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 48 aoAnalytical x7#w.psoefaas.cnm ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 20078 (704)875-9092 Sample: MW-4 Lab ID: 92441209003 Collected: 08112119 13:49 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6280E MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,12-Trichloroethane Trlchloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene -dB (S) Date: 09/09/2019 12:28 PM Analytical Method: SM 6200B NO uglL ND uglL ND uglL NO uglL NO ug/L ND uglL ND uglL NO uglL NO ug)L NO uglL ND uglL NO ug1L NO ug1L ND ug1L NO ug1L NO uglL ND ug1L N❑ ug1L NO ug1L 99 % 100 % 101 % 2.0 1 0811511916:09 91-20-3 D.50 1 08/15/19 16:09 103-65-1 0.50 1 08/15119 16:09 100-42-5 0,50 1 08/1511916:09 00-20-6 0} 50 1 08/15/19 15:09 79-34-5 0,50 1 08/15/19 16:09 127-18-4 0,50 1 08/15/19 16:09 108-88-3 2.0 1 08/15/19 16:09 87-61-6 2.0 1 08/15/19 16:09 120-82-1 0.50 1 0811511916:09 71-55-6 0.50 1 0811511916:09 79-00-5 0.50 1 08/15/19 16:09 79-01-6 lb 1 08/15/19 16:09 75-69-4 0.50 1 08/1511916:09 96-18.4 0.50 1 0811511916:09 95-63-6 0.50 1 08/15/19 16;09 108-67-8 1.0 1 08/15/1916:09 75-01-4 1.0 1 08115/19 16:09 179601-23-1 0.50 1 0811511916:09 95-47-6 70-130 1 08115/19 16.09 17060-07-0 70-130 1 08115/1916:09 460-00-4 70-130 1 08115/1916:09 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 9 of 48 aceAnalylrcal www.pecelahs.mm ANALYTICAL RESULTS Pace Ana lyttcaI Services, LLC 9800 Kincey Ave. Suite 100 Huntersvdie, NC 28078 (704)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: MW-5 Lab ll}: 92441209004 Collected: 08/12119 14:05 Received: 08113/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Llual 6200E MSV Analytical Method: SM 6200B tert-Amyl Alcohol 275 uglL 100 1 08/15/19 16:27 75-85-4 tert-Amylmethyl ether 32A uglL 10.0 1 08/15119 16:27 994-05-8 Benzene 101 uglL 0,50 1 0811511916-27 71-43-2 Bromobenzene ND uglL 0,50 1 0811511916:27 108-86-1 Bromochloromethane ND ug1L 0.50 1 0811511916:27 74-97-5 Bromodichloromethane ND uglL 0,50 1 08/15119 16:27 75-27-4 Bromoform ND ug1L 0.50 1 0811511916:27 75-25-2 Bromomethane N❑ uglL 5.0 1 0811511916:27 74-83-9 L1 ted-Butyl Alcohol 26A ug1L 10.0 1 08/15/19 16:27 75-65-0 n-Butylbenzene 1.1 ug1L 0,50 1 0811511916:27 104-51-8 sec-Butylbenzene N❑ uglL 0,50 1 08/15119 16:27 135-98-8 tent-Butylbenzene ND ug1L 0.50 1 0811511916:27 98-06-6 tert-Butyl Formate ND uglL 20.0 1 08/15119 16:27 762-75-4 Carbon tetrachloride N❑ uglL 0,50 1 08/15/19 16:27 56-23-5 Chlorobenzene ND uglL 0.50 1 08115M 9 16:27 108-90-7 Chloroethane ND uglL 1.0 1 08116/1916,27 75-00-3 Chloroform ND ug1L 5.0 1 08/1511916:27 67.66-3 Chloromethane ND uglL 1.0 1 08/1511916,27 74.87-3 2-Chlor❑toluene ND uglL 0.50 1 08/15119 16:27 95-49-8 4-Chlorot❑luene ND uglL 0,50 1 08115/1916:27 106-43-4 1,2-Dibromo-3-chloropropane N❑ uglL 1.0 1 0811511916:27 96-12-8 D ibrom ochloro methane N❑ ug1L 0,50 1 0811511916:27 124-48-1 1,2-Dibromoethane (EDB) ND uglL 0.50 1 08/15/19 16:27 106-93-4 Dibromomethane ND ug1L 0.50 1 08/15119 16:27 74-95-3 1,2-Dichlorobenzene N❑ ug1L 0-50 1 0811511916:27 95-50-1 1,3-Dichlorobenzene ND ug1L 0.50 1 08/15119 16:27 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 0811511916:27 106-46-7 Dichiorodi[luor❑methane ND uglL 0,50 1 09/15/1916:27 75-71-8 1,1-Dichloroethane ND ug1L 0,50 1 08115/1916:27 75-34-3 1,2-Dichloroethane ND ug1L 0,50 1 0811511916:27 107-06-2 1,1-Dichloroethene ND uglL 0.50 1 0811511916:27 75-35-4 cis-1,2-Dichloroethene ND uglL 0.50 1 0811511916:27 156-59-2 trans- 1,2-Dichloroethene ND uglL 0.50 1 08/15119 16:27 156-60-5 1,2-Dichloropropane ND uglL 0.50 1 08/15119 16:27 78-87-5 1,3-Dichloropropane ND uglL 0,50 1 0811511916:27 142-28-9 2,2-Dichloropropane ND uglL 0,50 1 0811511916:27 594-20-7 1,1-Dichloropropene ND uglL 0.50 1 0811511916:27 563-58-6 cis -1,3-Dichloropropene ND ug1L 0.50 1 08/1511916.27 10061-01-5 trans-1,3-Dichloropropene ND ug1L 0.50 1 08115/1916:27 1I061-02-6 Diisopropyl ether N❑ ug1L 0.50 1 08115/19 16,27 108.20-3 Ethanol N❑ uglL 200 1 0811511916:27 64-17.5 Ethylbenzene 1X uglL 0.50 1 08/15/19 16:27 100-41-4 Ethyl-tert-butyl ether ND ug1L 10.0 1 08/15119 16:27 637-92-3 Hexachloro-1,3-butadiene ND ug1L 2.0 1 0811511916:27 87-68-3 Isopropylbenzene (Cumene) 3.5 ug1L 9,50 1 08/15/19 16:27 98-82-8 Methylene Chloride ND uglL 2.0 1 08/15119 16:27 75-09-2 Methyl-tert-butyl ether 148 ug1L 0.50 1 08/15/19 16:27 1634-04-4 M1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date- 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 48 aceAnalylical —pacefahs.cam Project: Carl's Country Store Pace Project No.: 92441209 Sample-. MW-5 Parameters 620013 MSV Naphthalene n-Propylbenzene Styrene 1.1.1,2- Tetrachloroethane 1. 1, 2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1, 2 ,4-Trichlorobenzene 1,1,1-Trichloroethane 1.1.2-Trichloroetha ne Trichloroethene Trichl orofluorometha ne 1,2,3-Trichloropmpane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-❑ichloroethane-d4 (S) 4-Bromof)uorobenzene (S) Toluene-d8 (S) Date: 09/09/2019 12:28 PM Pace Analytical Services, LLC 9800 KinceyAve. Sufte 100 Huntersville, NC 20078 (704)875-9092 ANALYTICAL RESULTS Lab lD: 92441209004 Collected: 08/12/19 14:05 Received: 08113119 14:07 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Quat Analytical Method: SM 6200B 34.6 uglL 2.0 1 08/1511916:27 91-20-3 N❑ ug1L 0.50 1 081151191627 103-65-1 ND uglL 0.50 1 0811511916:27 100-42-5 ND uglL 0.50 1 0811511916:27 630-20-6 ND uglL 0.50 1 08/15/19 16:27 79-34-5 ND uglL 0.50 1 0811511916:27 127-18-4 ND ug1L 0.50 1 08/1511916:27 108-88-3 ND uglL 2.0 1 0811511916:27 87-61-6 N❑ uglL 2.0 1 08115/191627 120-82-1 ND uglL 0.50 1 0811511916:27 71-55-6 ND uglL 0.50 1 08115/1916.27 79-00-5 N❑ uglL 0.50 1 08115/1916:27 79-01-6 N❑ ug/L 1.0 1 0811511916:27 75-69-4 ND ug1L 0.50 1 08115/1916:27 96-18-4 2.5 UA 0.50 1 08115/1916:27 95-63-6 N❑ ug1L 0.50 1 081151191627 108-67-8 N❑ ug/L 1.0 1 08/15/1916:27 75-01-4 1.9 ug1L 1.0 1 0811511916:27 179601-23-1 ND ug1L 0.50 1 0811511916:27 95-47-6 101 % 70-130 f 0811511916:27 17060-07-0 99 % 70-130 1 0811511916:27 460-00.4 100 % 70-130 1 08115/1916:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 48 aceAnalyfrcal wwrwpacelahsxom ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No-: 92441209 Pace Analytical Services, LLC 9800 KinceyAve . Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-6 Parameters Lab ID: 92441209005 Collected: 08/12/19 14:18 Received: Results Units Report Limit DF Prepared 08/13/19 14:07 Matrix: Water Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 62008 tert-Amy{ Alcohol NO uglL 100 1 08/15/19 03:55 75-85-4 tent-Amylmethyl ether NO uglL 10.0 1 08/15/19 03:55 994-05-8 Benzene NO ug1L 0,50 1 08/15/19 03:55 71-43-2 Bromobenzene NO uglL 0.50 1 08/15/19 03:55 108-86-1 B romoch loro methane NO ug1L 0.50 1 06/15/19 03:55 74-97-5 Bromodichloromethane NO uglL 0,50 1 08/15/19 03:55 75-27-4 Bromoform NO ug1L 0.50 1 08/15119 03:55 75-25-2 Bromomethane NO ug1L 5.0 1 08/15/19 03:55 74-83-9 ter( -Butyl Alcohol 48.7 ug1L 10.0 1 08/15/19 03:55 75-65-0 n-Butylbenzene ND ug1L 0.50 1 08/15/19 03:55 104-51-8 sec-Butylbenzene ND ug1L 0.50 1 08/15119 03:55 135-98-8 tert-Butytbenzene NO ug1L 0.50 1 08/15/19 03:55 98-06-6 tent -Butyl Formate ND ug1L 20.0 1 08/15/19 03:55 762-75-4 Carbon tetrachloride N❑ uglL 0.50 1 08115/19 03:55 56-23-5 Chlorobenzene ND uglL 0.50 1 0811511903:55 108-90-7 Chloroethane ND ug1L 1.0 1 08/15/19 03:55 75-00-3 Chloroform NO uglL 5.0 1 08/15/19 03:55 67-66-3 Chloromethane NO ug1L 1.0 1 08/15119 03:55 74-87-3 2-Chlorotoluene NO ug1L 0.50 1 08/15119 03:55 95-49-8 4-Chlorotoluene N❑ uglL 0,50 1 0811511903:55 1D6-43-4 1,2-Dibromo-3-chloropropane NO uglL 1.0 1 0811511903:55 96-12-8 ❑ibromochloromethane NO uglL 0.50 1 08115119 03:55 124-48-1 1,2-Dibromoethane (EDB) NO ug1L 0,50 1 08/15/19 03:55 106-93-4 Dibromomethane NO uglL 0,50 1 08/15/19 03:55 74-95-3 1,2-Dichlorobenzene NO ug1L 0.50 1 0811511903:55 95-50-1 1,3-1)ichlorobenzene NO uglL 0,50 1 08/15/19 03:55 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 08115/19 03:55 106-46-7 Dichlorodifluoromethane NO ug1L 0.50 1 08/15/19 03:55 75-71-8 1,1-❑ichlofoethane ND ug1L 0,50 1 08/15/19 03:55 75-34-3 1,2-Dichloroethane ND ug1L 0.50 1 08/15/19 03:55 107-06-2 1,1-Dichloroethene ND uglL 0.50 1 08/15/19 03:55 75-35-4 cis-1,2-Dichloroethene ND ug1L 0.50 1 08/15/19 03:55 156-59-2 trans-1,2-Dichloroethene ND uglL 0.50 1 08/15/19 03:55 156-60-5 1,2-Dichloropropane NO uglL 0.50 1 08/15/19 03:55 78-87-5 1,3-Dichtoroprnpane NO ug1L 0.50 1 08/15/19 03:55 142-28-9 2,2-Dichloropropane NO ug1L 0.50 1 08/15/19 03:55 594-20-7 1,1-Dichloropropene NO uglL 0.50 1 08/15/19 03:55 563-58-6 cis-1,3-Dichloropropene NO ug1L 0.50 1 08/15/19 03:55 10061-01-5 1rans-1,3-Dichloropropane N❑ ug1L 0.50 1 08/15/19 03:55 10061-02-6 ❑iisopropyl ether ND uglL 0,50 1 08/15/19 03:55 108-20-3 Ethanol N❑ uglL 200 1 08/15/19 03:55 64-17-5 Ethylbenzene ND uglL 0.50 1 08115M9 03:55 100-41-4 Ethyl-tert-butyl ether N❑ uglL 10.0 1 06/15/19 03:55 637-92-3 Hexachloro-1,3-butadiene ND uglL 2.0 1 0811511903:55 87-68-3 Isopropylbenzene (Cumene) NO ug1L 0.50 1 08/15/19 03:55 98-82-8 Methylene Chloride NO uglL 2.0 1 08/15/19 03:55 75-09-2 Methyl-tert-butyl ether 88.3 ug1L 0,50 1 08/15119 03:55 1634-D4-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/0912019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 48 Pace Analytical Services, LLC aC❑�'��'r° 9800 KinceyAve. Suite 100 L+ c Huntersville. NC 28078 wwvwpacelabscam {704}875-9032 ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92441209 Sample- MW-6 Lab lD: 92441209005 Collected: 08112119 14:18 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Quaff 6200E MSV Analytical Method: SM 6200B Naphthalene N❑ uglL 2.0 1 08/15/19 03:55 91-20-3 n-Propylbenzene ND ug1L 0.50 1 08115/19 03:55 103-65-1 Styrene ND uglL 0,50 1 08/15/19 03:55 100-42-5 1,1.1.2-Telrachloroelhane ND uglL 0.50 1 08/15/19 03:55 630-20-6 1,1,2,2-Teirachloreethane ND uglL 0.50 1 08/15/19 03:55 79-34-5 Tetrachloroethene ND uglL 0.50 1 08/15/19 03:55 127-18-4 Toluene ND uglL 0.50 1 08/15/19 03:55 108-88-3 1,2,3-Trichlorobenzene ND ug1L 2.0 1 08/15/19 03:55 87-61-6 1,2,4-Trichlorobenzene N❑ ug1L 2.0 1 08/15119 03:55 120-82-1 1,1,1-Trichloroethane N❑ ug1L 0.50 1 08/15/19 03:55 71-55-6 1,1,2-Trichloroethane ND ug1L 0.50 1 08/15/19 03:55 79-00-5 Trichloroethene N❑ uglL 0.50 1 08/15/19 03:55 79-01-6 Tdchlorofluoromethane ND uglL 1.0 1 08/15/19 03:55 75-69-4 1,2,3-Trichloropropane N❑ uglL 0.50 1 08/1511903:55 9f 18-4 1,2,4-Trimethylbenzene ND uglL 0.50 1 08/1511903:55 95-63-6 1,3,5-Trimethylbenzene ND ug1L 0.50 1 08/1511903:55 108.67-8 Vinyl chloride ND ug/L 1.0 1 0&15119 03:55 75-01-4 m&p-Xylene N❑ uglL 1.0 1 08/15/19 03:55 179601-23-1 o-Xylene ND ug1L 0.50 1 08/15/19 03'55 95.47-6 Surrogates 1,2-Dichloroethane-d4 (S) 101 % 70-130 1 08/15/19 03:55 17060-07-0 4-Bromofluorohenzene (S) 100 % 70-130 1 08/15/19 03:55 460-00-4 Toluene-d8 (S) 101 % 70-130 1 08/15/19 03:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, Date: 09109/2019 12:28 PM without the written consent or Pace Analytical Services, LLC. Page 13 of 48 accAnalytical wwwpsce18bawM ANALYTICAL RESULTS Pace Analytical Services, LLC 8800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9082 Project: Carl's Country Store Pace Project No.: 92441209 Sample: MW-7 Lab lD: 92441209006 Collected: 08/12/19 13:46 Received: 08113119 14:07 Matrix: Water Parameters Results Units Report Limit ❑F Prepared Analyzed CAS No. 4ual 6200B MSV Analytical Method: SM 6200B tertAmyl Alcohol N❑ uglL 100 1 08/15/19 02:25 75-85-4 ter[-Amylmethyl ether N❑ uglL 10.0 1 081115/19 02.25 994-05-8 Benzene ND uglL 0.50 1 03115/19 02:25 71-43-2 Bromobenzene N❑ uglL 0.50 1 08/15/19 02:25 108-86-1 Bromochloromethane ND uglL 0.50 1 08115/19 02:25 74-97-5 Bromodi chloro methane ND ug1L 0,50 1 08/15/19 0225 75-27-4 Bromoform N❑ ug1L 0.50 1 08/15/19 02:25 75-25-2 Bromomelhane ND uglL 5.0 1 08/15/19 02:25 74-83-9 tert-Butyl Alcohol ND ug1L 10.0 1 08/15119 02:25 75-65-0 n-Butylbenzene N❑ uglL 0.50 1 08/15/19 02:25 104-51-8 ser Butylbenzene N❑ ug1L 0.50 1 08/15/19 02:25 135-98-8 tert-Butylbenzene ND uglL 0,50 1 08/15/19 02.25 98-06-6 ter! -Butyl Formale N❑ uglL 20.0 1 08/15/19 02:25 762-75-4 Carbon tetrachloride ND uglL 0.50 1 08/15/19 02:25 56-23-5 Chlorobenzene N❑ uglL 0,50 1 08/15/19 02:25 108-90-7 Chloroethane N❑ uglL 1.0 1 08/15/19 02.25 75-00-3 Chloroform N❑ uglt- 5.0 1 08/15/19 02:25 67-66-3 Chloromethane NO uglL 1.0 1 08115/19 02:25 74-87-3 2-Chiorotoluene ND uglL 0,50 1 08115/19 02:25 95-49-8 4-Chlorotoluene ND ug1L 0.50 1 08115/19 02:25 106-43-4 1,2-Dibromo-3-chloroprepane ND uglL 1.0 f 08/15/19 02:25 96-12-8 Dibromochloromethane ND ug1L 0.50 1 08/15/19 02:25 124-48-1 1,2-DibromoelhanejEDBj ND ug1L 0.50 1 0811511902:25 106-93-4 Dibromomethane ND uglL 0.50 1 08/15119 0225 74-95-3 1,2-Dichlorobenzene N❑ uglL 0.50 1 0811511902:25 95-50-1 1,3-Dichlorobenzene ND uglL 0,50 1 08/1511902:25 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 08/1511902:25 106-46-7 Dichlorodifluoromethane N❑ ug1L 0.50 1 08/15/19 02:26 75-71-8 1,1-Dichloroethane NO uglL 0.50 1 08115/19 02:25 75-34-3 1,2-Dichloroethane NO uglL 0.50 1 0811511902:25 107-06-2 1,1-Dichloroethene NO uglL 0,50 1 08/15/19 02,25 75-35-4 cis-1,2-Dichloroethene NO uglL 0,50 1 08115/19 02:25 156-69-2 trans- 1,2-Dichloroethene N❑ uglL 0,50 1 08115/19 02:25 156-60-5 1,2-Dichloropropane N❑ uglL 0,50 1 08115/19 02:25 78-87-5 1,3-Dichloropropane N❑ ug1L 0.50 1 08/15119 02:25 142-28-9 2,2-Dichloropropane ND uglL 0.50 1 08/15/19 02:25 594-20-7 1,1-Dichloropropene N❑ uglL 0.50 1 08/15119 02:25 563-58-6 cis-1,3-❑ichlompropene ND ug)L 0.50 1 08/15/19 02:25 10061-01-5 trans- 1,3-Dichloropropene ND uglL 0.50 1 08/1511902:25 10061-02-6 Diisopropyl ether N❑ ug1L 0.50 1 08/15/19 02:25 108-20-3 Ethanol ND ug1L 200 1 08/15/19 02:25 64-17-5 Ethyibenzene ND uglL 0.50 1 08/15/19 02:25 100-41-4 Ethyl-tert-butyl ether N❑ ug1L 10.0 1 08/15/19 02:25 637-92-3 Hexachloro-1.3-butadiene N❑ uglL 2.0 1 08/15/19 02:25 87-68-3 Isopropylbenzene [Cumene] N❑ uglL 0,50 1 08115/19 02:25 98-82-8 Methylene Chloride ND ug1L 2.0 1 08/15/19 02:25 75-09-2 Methyt-tert-butyl ether ND ug1L 0.50 1 08115/19 02:25 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2019 12:28 PM without the written can sent or Pace Analytical Services, LLC. Page 14 of 48 I eAnaiXical —pacehahscam ANALYTICAL RESULTS Project: Cad's Country Store Pace Project No.: 92441209 Pace Analytical Servicas, LLC 9800 Kin coy Ave. Suite 100 Huntersville, NC 28078 (7(14]875-9092 Sample. MW-7 Lab ID: 92441209006 Collected: 08/12/19 13:46 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 6200E MSV Naphthalene n-Propylbenzene Styrene 1.1,1,2-Tetrachloroethano 1,1,2,2-Tetrachloroethane Tetcachloreethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trich to rotiuorometha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromoiluorobenzene (S) Toluene-d8 (S) Date: 09/09/2019 12-28 PM Analytical Melhod: SM 6200B ND ug1L N❑ ug1L ND uglL ND uglL ND ug1L ND uglL ND ug1L ND ug1L ND uglL ND uglL ND uglL N❑ uglL N❑ uglL N❑ uglt- ND ug1L N❑ ug1L ND ug1L ND ug1L ND ug1L 98 °% 99 °% 100 °% 2.0 1 08115/19 02:25 91-20-3 0.50 1 OW15/19 02:25 103-65-1 MG 1 08115/19 02:25 100-42-5 0,50 1 08/15/19 02:25 630-20-6 0.50 1 08/15/19 02:25 79-34-5 0.50 1 08/15/19 02:25 127-18-4 0.50 1 08/15/19 02:25 108-88-3 2.0 1 08/15/19 02:25 87-61-6 2.0 1 08/15/19 02:25 120-82-1 0.50 1 08/151119 02:25 71-55-6 0.50 1 08/15/19 02:25 79-00-5 0,50 1 08/15/19 02:25 79-01-6 1.0 1 08/15/19 02:25 75-69-4 0.50 1 68/15/19 02:25 96-18-4 0.50 1 08/15/19 02:25 95-63-6 0,50 1 08/15/19 02:25 108-67-8 1.0 1 08/15/19 02:25 75-01-4 1.0 1 08/15/19 02:25 179601-23-1 0.50 1 08115/19 02,25 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC 08115119 02.25 17460-07-0 08/15119 02:25 460-00-4 08/15/19 02:25 2037-26-5 Page 15 of 48 aceAnalylicaf wwwPacalabs-com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 2807EI (704)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: MW-9 Lab ID: 92441209007 Collected: 08112/19 13:34 Received: 08/13119 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No, Qual 6200B AMSV Analytical Method: SM 6200B tent -Amyl Alcohol ND uglL 100 1 08115/19 02:43 75-85-4 tent-Amylmethyl ether ND ug1L 10.0 1 08/15/19 02:43 994-05-8 Benzene ND uglL 0.50 1 08/15/19 02:43 71-43-2 Bromobenzene ND uglL 0.50 1 08115/19 02:43 108-86-1 Bromochloromethane ND uglL 0.50 1 08/15/19 02:43 74-97-5 Bromodichloromethane N❑ uglL 0.50 1 08/15/19 02:43 75-27-4 Brumoform ND ug1L 0.50 1 08/15/19 02:43 75-25-2 Bromomethane ND uglL 5.0 1 08/15/19 02:43 74-83-9 ter( -Butyl Alcohol ND ug1L 10.0 1 08/15/19 02:43 75-65-0 n-Butylbenzene ND uglL 0.50 1 08/15/19 02:43 104-51-8 sec-Butylbenzene ND uglL 0.50 1 08/15119 02:43 135-98-8 tert-Butyl benzene ND uglL 0,50 1 08/15119 02:43 98-06-6 tert-Butyl Formate ND ug1L 20.0 1 08/15/19 02:43 762-75-4 Carbon tetrachloride ND uglL 0.50 1 08/15/19 02:43 56-23-5 Chlorobenzene ND ug1L 0.50 1 08/15/19 02:43 108-90-7 Chloroethane ND ug1L 1.0 1 08/15/19 02:43 75-00-3 Chloroform ND uglL 5.0 1 08/15/19 02:43 67-66-3 Chloromethane ND ug1L 1.0 1 08/15/19 02:43 74-87-3 2-Chlorotoluene ND ug1L 0.50 1 08115/19 02:43 95-49-8 4-Chlorotoluene N❑ uglL 0.50 1 08/15/19 02:43 106-43-4 1,2-Dibromo-3-chloropropane N❑ ug1L 1.0 1 08/15/19 02:43 96-12-8 Dibromochloromethane N❑ uglL 0.50 1 08115/19 02:43 124.48-1 1,2-Dibromoethane (EDB) N❑ uglL 0.50 1 08/15/19 02:43 106-93-4 Dibromomethane ND uglL 0,50 1 08/15/19 02:43 74-95-3 1,2-Dichlorobenzene ND ug1L 0.50 1 08/15/19 02:43 95.50-1 1,3-Dichlorobenzene ND uglL 0.50 1 08/15/19 02:43 541-73-1 1,4-Dichlorobenzene NO uglL 0.50 1 0811511902:43 106-46-7 Dichlorodifluoromethane N❑ uglL 0,50 1 08/15/19 02:43 75-71-8 1,1-Dichloroethane ND uglL 0.50 1 0811511902:43 75-34-3 1,2-Dichloroethane N❑ uglL 0.50 1 08/15119 02:43 107-06-2 1,1-Dichloroethene ND ug1L 0.50 1 0811511902:43 75-35-4 cis-1,2-Dichloroethene N❑ uglL 0,50 1 08/15119 02:43 156-59-2 trans-1,2-Dichloroethene ND uglL 0.50 1 08/15119 02-43 156-60-5 1,2-Dichloropropane ND uglL 0.50 1 08/15/19 02,43 78-87-5 1,3-Dichloropropane ND uglL 0.50 1 08/15/19 02:43 142-28-9 2,2-Dichloropropane ND uglL 0,50 1 08/15/19 02:43 594-20-7 1,1-Dichloropropene HD uglL 0.50 1 08/15/19 02:43 563-58.6 cis- 1,3-Dichloropropene N❑ ug1L 0,50 1 08/15/19 02:43 10061-01-5 trans- l,3-Dichloropropene N❑ ug1L 0.50 1 08/15/19 02:43 10061-02-6 Diisopropyl ether ND ug1L 0.50 1 08/15/19 02:43 108-20-3 Ethanol N❑ ug1L 200 1 08/15/19 02:43 64-17-5 Etylbenzene ND uglL 0.50 1 08/15/19 02:43 100-41-4 Ethyl -ter{ -butyl ether N❑ ug1L 10.0 1 08/15/19 02:43 637-92-3 Hexachloro-1,3-butad iene ND uglL 2.0 1 08115/1902:43 87-68-3 Isopropylbenzene (Cumene) ND uglL 0.50 1 08/15/19 02:43 98-82-8 Methylene Chloride ND uglL 2.0 1 08/15/19 02:43 75-09-2 Methyl-tert-butyl ether ND uglL 0.50 1 08/15/19 02:43 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09109/2019 12:28 PM without the written consent of Pace Analytical Services, LLC Page 16 of 48 e _ aceAnalyrcal mvw.pacelahs.MM ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunlersville, NC 28078 (704)875-9092 Project: Gail's Country Store Pace Project No.: 92441209 Sample: MW-9 Lab lD: 92441209007 Collected: 08/12/19 13:34 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62005 MSV Analytical Method: SM 6200B Naphthalene NO ug1L 2.0 1 08/15/19 02A3 91-20-3 n-Propylbenzene NO ug1L 0.50 1 08115/19 02:43 103-65-1 Styrene NO ug1L 0.50 1 08/15/19 02:43 100-42-5 1,1,12-Tetrachloroethane NO ug1L 0.50 1 08115/19 02:43 630-20-6 1,1,2,2-Tetrachloroethane NO ug1L 0.50 1 08115/19 02A3 79-34-5 Tetrachloroethene NO uglL 0.50 1 08/15/19 02:43 127-1" Toluene NO ug1L 0.50 1 08/15/19 02A3 108-8" 1,2,3-Trichlorobenzene ND ug1L 2.0 1 08115/19 02:43 87-61-6 1,2,4-Trichlorobenzene ND ug1L 2.0 1 0811511902:43 120-82-1 1, 1, 1 -Trichlo roetha ne ND ug1L 0.50 1 0811511902:43 71-55-6 1,1,2-Trichloroethane ND uglL 0.50 1 08115/19 02A3 79-00-5 Trichloroethene NO ug1L 0,50 1 08/15/19 02A3 79-01-6 Trichiorofluoromethane NO uglL 1.0 1 08/15/19 02:43 75-69-4 1,2,3-Trichloropropane NO uglL 0.50 1 08/15/19 02:43 96-18-4 1,2,4-Trimethylbenzene NO uglL 0.50 1 08/15/19 02:43 95-63-6 1,3,5-Trimethyibenzene NO ug1L 0.50 1 08/15/19 02:43 108-67-8 Vinyl chloride NO uglL 1.0 1 08/15/19 02:43 75-01-4 m&p-Xylene NO uglL 1.0 1 08/15/19 02:43 179601-23-1 o-Xyiene NO ug1L 0.50 1 08/15149 02:43 95-47-6 Surrogates 1,2-❑ichloroethane-d4 (S) 99 % 70-130 1 08/15/19 02:43 17G60.07-0 4-Bromofluorobenzene (S) 99 % 70-130 1 08/15/19 02:43 460-00-4 Toluene-d8 (S) 99 % 70-130 1 08/15/19 02:43 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, with out the written consent of Pace Analytical Services, LLC. Page 17 of 48 g acieAnaly4rcal www,pnv)ebs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kin coy Ave. Suite 100 Huntersvlle, NC 28078 [704)875-9092 Project: Carl's Country Store Pace Project No.7 92441209 Sample: MW-10 Lab ID: 92441209008 Collected: 06/12/19 13:24 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B terl-Amyl Alcohol NO uglL 100 1 08/15/19 03,01 75-85-4 tert-Amytmethyl ether NO uglL 10.0 1 08/15/19 03:01 994-05-8 Benzene 5.9 uglL 0.50 1 08/15/19 03:01 71-43-2 Bromobenzene NO uglL 0.50 1 08/15/19 03:01 10"6-1 Bromochloromethane ND ug1L 0.50 1 08/15/19 03:01 74-97-5 Bromodichloromethane ND uglL 0,50 1 08/1511903:01 75-27-4 Bromoform ND ug1L 0.50 1 08/15/19 03:01 75-25-2 Bromomethane ND ug1L &0 1 06/15/19 03:01 74-83-9 tert-Butyl Alcohol NO uglL 10.0 1 08/15/19 03:01 75-65.0 n-Butylbenzene ND ug1L 0.50 1 08/15/19 03:01 1D4-51-8 sec-Butylbenzene 15.5 ug1L D.50 1 08/15/19 03:01 135-98-8 tert-Butylbenzene 2.0 ug1L 0.50 1 081115M9 03:01 98-06-6 tert-Butyl Formate NO uglL 20.0 1 08/15/19 03:01 762-75-4 Carbon tetrachloride ND uglL 0,50 1 08/15/19 03:04 56-23-5 Chlorobenzene NO uglL 0,50 1 08/15/19 03:01 108-90-7 Chloroethane NO uglL 1.0 1 08/15/19 03:01 75-00-3 Chloroform N❑ ug1L 5.0 1 08/15/19 03:01 67-66-3 Chloromethane ND ug1L 1.0 1 08/15119 03:01 74-87-3 2-Chlorotoluene ND ug1L 0.50 1 08115119 03:01 95-49-8 4-Chlorotoluene NO uglL 0.50 1 08/15119 03:01 106-43-4 1,2-Dibroma-3-chloropropane ND uglL 1.0 1 08/15/19 03:01 96-12-8 Dibromochloromethane ND ug1L 0.50 1 08M5/1903:01 124-48-1 1,2-Dihromoethane(EDB) NO ug1L 0.50 1 08115/1903-01 106-93-4 Dibromomethane NO ug1L 0.50 1 08/15/19 03:01 74-95-3 1,2-Dichlorobenzene NO uglL 0.50 1 08/15/19 03:01 95-50-1 1,3-❑ichlorobenzene NO uglL 0.50 1 08/15/19 03:01 541-73-1 1,4-Dichlorobenzene NO uglL 0.50 1 08/15/19 03:01 106-46-7 Dichlorodifluoromethane ND uglL 0.50 1 08/15/19 03:01 75-71-8 1,1-Dichloroethane NO uglL 0.50 1 08/15/19 03:01 75-34-3 1,2-Dichloroethane NO uglL 0,50 1 08115/19 03:01 107-06-2 1,1-Dichloroethene NO ug)L 0,50 1 08/15/19 03:01 75-35-4 cis-1,2-Dichloroethene NO uglL 0.50 1 08/15/19 03:01 156-59-2 trans-1,2-Dichloroethene NO ug1L 0.50 1 08115M9 03:01 156-60-5 1,2-❑ichloropropane ND ug1L 0.50 1 08/15/19 03:01 78-87-5 1,3-Dichloropropane ND ug1L 0.50 1 08/15/19 03:01 142-28-9 2,2-Dichloropropane NO ug1L 0.50 1 08/15/19 03:01 594-20-7 1, 1 -Dichloropropene NO uglL 0.50 1 08/15/19 03:01 563-58-6 cis-1,3-Dichloropropene ND uglL 0,50 1 08/15/19 03:01 10061-01-5 trans- 1,3-Dichloropropene NO uglL 0,50 1 0811511903:01 10061-02-6 Diisopropyl ether ND ug1L 0,50 1 08/15/19 0&01 108-20-3 Ethanol ND uglL 200 1 08/15/19 03:01 64-17-5 Ethylbenzene NO uglL 0.50 1 08/15/19 03:01 100-41-4 Ethyl-tert-butyl ether NO uglL 10.0 1 08/15/19 03:01 637-92-3 Hexachloro-1,3-butadiene NO uglL 2.0 1 08/15/19 03:01 87-68-3 Isopropylbenzene (Gumene) 6.7 uglL 0,50 1 08/15/19 03:01 98-82-8 Methylene Chloride NO ug1L 2.0 1 08115/19 03:01 75-09-2 Methyl-tent-bulyl ether NO ug1L 0.50 1 08115/19 03:01 1634.04.4 REPORT OF LABORATORY ANALYSIS This report shall net be reproduced, except in Full, Date: 0910912019 12:28 PM without the written con sent of Pace An al ytical Servioes, LLC. Page 18 of 48 aceAnalytical� wwo.phcelabs.c m ANALYTICAL RESULTS Pace Anatyticat Services, LLC 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875.9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: NW--10 Lab ]D: 92441209008 Collected: 08/12/19 13:24 Received: 08/13/19 14.07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Quaff 62008 MSV Analytical Method: SM 6200B Naphthalene 11.1 uglL 2.0 1 08/15/19 03:01 91-20-3 n-Propylbenzene 0.57 ug1L 0,50 1 08/15119 03:01 103-05-1 Styrene ND uglL 0.50 1 08/15/19 03:01 100-42-5 1,1,1,2-Telrachloroethane ND ug1L 0.50 1 0811511903:01 630-20-6 1,12,2-Tetrachloroethane NO u91L 0,50 1 0811511903.01 79-34-5 Tetrachioroethene ND ug1L 0.50 1 08/15/19 03:01 127-18-4 Toluene NO uglL 0.50 1 08/15/19 03:01 1 D8-88-3 1,2,3-Trichlorobenzene ND ug1L 2.0 1 0811511903:01 87-61-6 1,2,4-Trichloroben7ene NO uglL 2.0 1 08/1611903:01 120-82-1 1,1,1-Trichloroethane NO uglL 0.50 1 08/1511903:01 71-55-6 1,1,2-Trichloroethane NO uglL 0.50 1 OW15119 03:01 79-00-5 Trichloroethene N❑ uglL 0.50 1 08/15/19 03:01 79-01-6 Trichlorofluoromelhane NO uglL 1.0 1 08/15/19 03:01 75-69-4 1,2,3-Trichloropropane ND UA 0.60 1 08115/19 03:01 96-18-4 1,2,4-Trimethylbenzene N❑ ug1L 0.50 1 08/15/19 03:01 95-63-6 1,3,5-Trimethylbenzene 0.63 uglL 0,50 1 08/15/1903:01 108-67-8 Vinyl chloride ND ug1L 1.0 1 08/15/19 03:01 75-01-4 m&p-Xylene NO ug1L 1.0 1 08115/19 03:01 179601-23.1 o-xylene ND uglL 0.50 1 08/15119 03:01 95-47-6 Swrogates 1,2-Dichloroethane-d4 (5) 104 % 70-130 1 08/15/19 03:01 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 08/15/19 03:01 460-00-4 Toluene-d8 (S) 102 % 70-130 1 08/15/19 03:01 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Face Analytical Services, LLC. Page 19 of 48 acmnalyticala www.pamiabs.cam ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kin ceyAve . Suite 100 Huntersville, NC 28078 (704)875.9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: DMW-1 Lab lO: 92441209009 Collected: 08/12/19 12:42 Received: OW13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B test -Amyl Alcohol NO ug1L 100 1 08/15/19 03:19 75-85-4 tert-Amylmethyl ether NO uglL 10.0 1 00/15/19 03.19 994-05-8 Benzene ND uglL 0.50 1 08/15/19 03,19 71-43-2 Bromobenzene ND ug1L 0,50 1 06/15/19 03:19 108.86-1 Bromochloromethane ND uglL 0.50 1 08/15/19 03:19 74-97-5 Bromodichloromethane NO uglL 0.50 1 08115/19 03:19 75-27-4 Bromoform NO uglL 0.50 1 08/15/19 03:19 75-25-2 Bromomethane ND uglL 5.0 1 08/15/19 03:19 74-83-9 tert-Butyl Alcohol N❑ ug1L 10.0 1 08115M9 03:19 75-65-0 n-Butylbenzene ND uglL 0.50 1 08/15/19 03:19 104-51-8 sec-Butylbenzerte ND uglL 0.50 1 08/15/19 03:19 135-98-8 lert-Butylbenzene N❑ ug1L 0.50 1 08/15/19 03:19 98-06-6 tert-Butyl Formate ND uglL 20.0 1 08/15/19 03:19 762-75-4 Carbon tetrachloride ND ug1L 0.50 1 08/15/19 03:19 56-23-5 Chlorobenzene NO ug1L 0,50 1 08/15/19 03:19 108-90-7 Chloroethane NO ug1L 1.0 1 08/15/19 03:19 75-00-3 Chloroform NO uglL 5.0 1 08/15/19 03:19 67-66-3 Chloromethane NO ug1L 1.0 1 08/15/19 03:19 74-87-3 2-Chlorotaluene ND ug1L 0.50 1 08/15/19 03:19 95-49-8 4-Chlorotoluene NO ug1L 0,50 1 08/15/19 03-19 106-434 1,2-Dibromo-3-chloropropane N❑ uglL 1.0 1 OW15119 03,19 96-12-8 Dibromochloromethane N❑ uglL 0.50 1 06/15/19 03:19 124-48-1 1,2-Dibromoethane (EDB) NO u91L 0.50 1 08115/19 03:19 106.93-4 Dibromomethane NO uglL 0.50 1 08/15/19 03:19 74-95-3 1,2-Dichlorobenzene ND ug1L 0.50 1 08/15/19 03:19 95-50-1 1,3-Dichtorobenzene ND ug1L 0.50 1 08115/19 03:19 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 0811511903-19 106-46-7 Dichlorodifluoromethane NO uglL 0.50 1 08/15/19 03:19 75-71-8 1,1-Dichloroethane NO uglL 0,50 1 0811511903:19 75-34-3 1,2-Dichloroethane 0.65 uglL 0.50 1 0-3/15/1903:19 107-06-2 1,1-Dichloroethene NO uglL 0.50 1 0811511903:19 75-35-4 cis- 1,2-Dichloroethene NO uglL 0,50 1 08/15/19 03:19 156-59-2 Trans-1,2-Dichloroethene N❑ uglL 0.50 1 08/15/19 03:19 156-60-5 1,2-Dichloropropane NO u91L 0.50 1 08/15/19 03:19 78-87-5 1,3-Dichloropropane ND uglL 0.50 1 08/15/19 03:19 142-28-9 2,2-Dichloropropane N❑ uglL 0.50 1 08/15/19 03:19 594-20-7 1,1-❑ichloropropene ND ug1L 0,50 1 08/15/19 03:19 563-58-0 cis-1,3-Dichloropropene NO uglL 0.50 1 08/15/19 03:19 10061-01-5 trans- l,3-Dichtoropropene NO ug1L 0.50 1 08115/19 03:19 10061-02-6 Diisopropyl ether 0.68 ug1L 0.50 1 08/15/19 03:19 108-20-3 Ethanol NO uglL 200 1 08/15/19 03:19 64-17-5 Ethylbenzene N❑ uglL 0,50 1 08/15119 03:19 100-41-4 Ethyl-tert-butyl ether ND uglL 10.0 1 08/15/19 03:19 637-92-3 Hexachloro-1,3-butadiene ND ug& 2.0 1 0811511903:19 87-68-3 Isopropylbenzene (Cumene) N❑ ug1L 0.50 1 08/15/19 03:19 98-82-8 Methylene Chloride ND ug1L 2.0 1 08/15119 03:19 75-09-2 Methyl-tert-butyl ether NO ug1L 0.50 1 08/15/19 03-19 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 09/09/2019 12:28 PM without the written consent of Pane Analytical Services, L.L.C. Page 20 of 48 aceAnalytical j wwwpm1abs.00rn I ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 {704}875-9092 Sample: DMW-1 Lab ID: 92441209009 Collected: 08/12/19 12:42 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 62008 MSV Analytical Method: SM 6200B Naphthalene ND uglL 2.0 1 08/15/19 03:19 91-20-3 n-Propylbenzene NO ug)L 0.50 1 08/15/19 03:19 103-65-1 Styrene NO t1a 0.50 1 08/15/19 03:19 100-42-5 1, 1, 1,2-Tetrachloroetha ne ND 4L 0.50 1 08/15/19 03:19 630-20-6 1,12,2-Tetrachloroethane ND uglL 0.50 1 08/15119 03:19 79-34-5 Tetrachloreathene ND ug1L 0.50 1 08/15119 03:19 127-18-4 Toluene N❑ ug1L 0.50 1 08/15119 03:19 108-88-3 1,2,3-Trichlorobenzene N❑ uglL 2.0 1 081151190119 87-61-6 1,2,4-Trichlorobenzene ND uglL 2.0 1 08/1511903:19 120-82-1 1, 1, 1 -Trichloroethane ND uglL 0.50 1 0811511903:19 71-55-6 1,1,2-Trichloroethane ND ug1L 0.50 1 08/1511903:19 79-00-5 Trichloroethene ND uglL 0.50 1 08/15/19 03:19 79-01-6 Trichloroiluoromethane N D uglL 1.0 1 08/15/19 03:19 75-69-4 1,2,3-Trichloropropane ND uglL 0.50 1 08/1511903,19 96-18-4 1,2,4-Trimethylbenzene ND uglL 0.50 1 08/15/19 03:19 95-63-6 1,3,5-Trimethyibenzene N❑ uglL 0.50 1 08115/19 03:19 108-07-8 Vinyl chloride ND uglL 1.0 1 08/15/19 03:19 75-01.4 m&p-Xylene N❑ uglL 1.0 1 08/15/19 03:19 179601-23-1 o-Xylene N❑ uglL 0.50 1 08/15/19 03:19 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 102 % 70-130 1 08/15/19 03:19 17060-07-0 4-Bromofiuorobenzene (S) 99 % 70-130 1 08/15/19 03:19 460-00-4 Toluene -dB (S) 99 % 70-130 1 08/15/19 03:19 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analyfrcal Services, LLC. Page 21 of 48 aceAnaljftalo ww.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kin coy Ave. Suite 100 Huntersville, NC 28078 (7n4)875-s092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: DMW-3 Lab ID: 92441209010 Collected: 08/12/19 12:45 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method: SM 6200B tert-Amyl Alcohol 385 uglL 100 1 08/15/19 04:13 75-05-4 tertAmylmethyl ether ND uglL 10.0 1 08/15/19 04:13 994-05-8 Benzene 61.4 uglL 0.50 1 08/15/19 04:13 71-43-2 Bromobenzene ND ug/L 0.50 1 0811511904,13 108-86-1 Bromochloromethane NO uglL 0,50 1 08/15/19 04A 3 74-97-5 Bromodichloramethane NO ug1L 0.50 1 08115119 04:13 75-27-4 Bromolorm ND ug1L 0.50 1 08/15/19 04A 3 75-25-2 Bromomethane ND ug1L &0 1 08115119 04:13 74-83-9 tart -Butyl Alcohol 53.0 ug1L 10.0 1 08/15/19 04,13 75-65-0 n-Butylbenzene NO ug1L 0,50 1 08115/19 04:13 104-51-8 sec-Butylbenzene N❑ ug1L 0.50 1 08115/19 04:13 135-98.8 tert-Butylbenzene N❑ uglL 0,50 1 08/15/19 04:13 98-06-6 tert-Butyl Formate NO uglL 20.0 1 08/15/19 04:13 762-75.4 Carbon tetrachloride NO uglL 0,50 1 08/15/19 04:13 56-23-5 Chlorobenzene ND uglL 0,50 1 08/15/19 04:13 11D8-90-7 Chloroethane NO uglL 1.0 1 08/15/19 D4:13 75-DO-3 Chloroform ND uglL 5.0 1 08/15/19 04:13 67-66-3 Chloromethane ND uglL 1.0 1 08/15/19 04:13 74-87-3 2-Chlorotoluene ND uglL 0.50 1 08/15/19 04:13 95-49-8 4-Chlorotoluene ND uglL Q.50 1 08115119 04:13 106-43-4 1,2-Dibromo-3-chloropropane ND uglL 1.0 1 06115/1904:13 96-12-8 Dibromochloromethane N❑ ug1L 0,50 1 08/15/19 04:13 124-48-1 1,2-Dibromoethane (EDB) NO ug1L 0.50 1 08/15119 04.13 106-93-4 Dibramomethane NO ug1L 0.50 1 08/15/19 04:13 74-95-3 1,2-Dichlorobenzene ND uglL 0.50 1 08/15/19 04:13 95-50-1 1,3-Dichlorobenzene ND u91L 0.50 1 08115119 04:13 541-73-1 1,4-Dichlorobenzene ND uglL 0,50 1 08115119 04: 13 10646-7 Dichlorodiliuoromethane ND uglL 0.50 1 08115/19 04:13 75-71-8 1,1-Dichloroethane ND uglL 0.50 1 08/15/19 04:13 75-34-3 1,2-Dichloroethane 17.3 uglL 0.50 1 08115119 04:13 107-05-2 1,1-Dichloroethene NO uglL 0.50 1 08/15/19 04:13 75-35A cis-1,2-Dichloroethene N❑ uglL 0.50 1 08/15/19 04:13 156-59-2 trans-1,2-Dichloroethene N❑ uglL 0.50 1 08/15/19 04:13 156-60-5 1,2-Dichloropropane NO ug1L 0.50 1 08/15/19 04:13 78.87-5 1,3-Dichloropropane NO ug1L 0.50 1 08/15/19 04:13 142-28-9 2,2-Dichloropropane NO ug1L 0.50 1 08/15/19 04:13 594-20-7 1,1-Dichloropropane N❑ uglL 0,50 1 08115119 04:13 563-58-6 cis- 1,3-❑ichloropropene ND ug1L 0.50 1 08115119 04:13 10061-01-5 trans-1,3-Dichloropropene NO u911- 0.50 1 08115119 04:13 10061-02-6 Diisopropyl ether 22.3 uglL 0.50 1 08/15/19 04:13 108-20-3 Ethanol ND ug1L 200 1 08/15/19 04:13 64-17-5 Ethylbenzene NO uglL 0,50 1 08/15/19 04:13 100-41-4 Ethyl-tert-butyl ether NO uglL 10.0 1 08/15119 04:13 637-92-3 Hexachloro-1,3-butadiene N❑ uglL 2.0 1 08/15/19 04.13 87-68-3 Isopropylbenzene (Cumene) NO uglL 0.50 1 08115119 04:13 98-82-8 Methylene Chloride NO uglL 2.0 1 08/15149 0413 75-09-2 Melhyl-teri-butyl ether 14.3 ug1L 0.50 1 D8115119 04:13 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall nut be reproduced, except in full, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 48 _ aceAnalytical mvw.Pa0efabs.a0,m ANALYTICAL RESULTS Project: Cad's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kinney Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: DMW-3 Lab ID: 92441209010 Collected: 08/12119 12:45 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1.1.2,2- Tet rachloraelhane Tetrachloroethene Toluene 1,2 , 3-Trichlorobenzene 1,2 ,4-Trichlorobenze ne 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Tdchlorofl uoromethane 1,2.3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-xylene o-Xylene Surrogates 1,2-Dichloraethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) l•FfC�il�lrrlrlY�rykiY�FI:I��■i] Analytical Method: SM 6200E ND ug/L ND ug1L ND ug ND ug/L ND ug/L ND ug/L ND ug/L N❑ ug/L ND ug/L ND ug/L ND ug/L ND ug/L N❑ ug1L ND uglL ND ug/L ND ug/L ND ugfL ND ug/L ND ug/L 100 °% 99 a% 102 °% 2.0 1 08/15/49 04:13 91-20-3 0,50 1 08/15/19 04:13 103-65-1 0.50 1 08/15/19 04:13 100-42-5 0.50 1 08/15/19 04:13 630-20-6 0.50 1 08/15/19 04:13 79-34-5 0,50 1 08/15/19 04:13 127-18-4 U0 1 08/15/19 04:13 108-88-3 2.0 1 08/15/19 04:13 87-61-6 2.0 1 08/15/19 04:13 120-82-1 0,50 1 08/15/19 04:13 71-55-6 0,50 1 08115/19 04:13 79-00-5 0.50 1 08/15/19 04:13 79-01-6 1.0 1 08/15/19 04:13 75-69-4 0.50 1 08/15/19 04:13 96-18-4 0.50 1 08115/19 04:13 95-63-6 0.50 1 08115/19 04:13 108-67-8 1.0 1 08115/19 04:13 75-01-4 1.0 1 08115M 9 04:13 179601-23-1 0.50 1 08115/19 0413 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, LLC. 08/15/19 04:13 17060-07-0 08/15/19 04:13 460-00-4 081151190413 2037-26-5 Page 23 of 48 Pace Analytical Services. LLC $ 9800 KinceyAve, Suite 100 aceAnalytircal Huntersville, NC 28078 www.pamlabs.com (704)875-9092 ANALYTICAL RESULTS Project.- Carl's Country Stare Pace Project No.: 92441209 Sample: DMVV-4 Lab ID: 92441209011 Collected: 08/12/19 12:53 Received. 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Analytical Method- SM 6200B tert-Amyl Alcohol ND uglL 100 1 08/15/19 03:37 75-85-4 tert-Amylmethyl ether ND uglL 10.0 1 08/15/19 03:37 994-05-8 Benzene ND uglL 0.59 1 08/15/19 03:37 71-43-2 Bromobenzene N❑ ug1L 0.50 1 08/15/19 03:37 108-86-1 Bromochloromelhane ND uglL 0.50 1 08/15/19 03:37 74-97-5 Bromodichloromethane ND uglL 0.50 1 08/15/19 03:37 75-27.4 Bromoform ND uglL 0.50 1 08/15/19 03:37 75-25-2 Bromomethane ND ug1L &0 1 08/15/19 03:37 74-83-9 tert-Butyl Alcohol N❑ ug1L 10.0 1 08/15/19 03:37 75-65-0 n-Butylbenzene ND ug1L 0.50 1 08/15/19 03-37 104-51-8 sec-Butylbenzene ND uglL 0,50 1 08/15/19 03:37 135-98-8 tert-Butylbenzene ND ug1L 0.50 1 08115/19 03:37 98-06-0 tert-Butyl Formate ND uglL 20.0 1 08/15119 03:37 762-75-4 Carbon tetrachloride N❑ uglL 0.50 1 08/15/19 03:37 56-23-5 Chlorobenzene N❑ uglL 0.50 1 08/15/19 03:37 108-90-7 Chloroethane ND ug1L 1.0 1 08/15119 03:37 75-00-3 Chloroform ND ug1L 5.0 1 08115119 03:37 67-66-3 Chioromethane ND uglL 1.0 1 08/15/19 03:37 74-87-3 2-Chlorotoluene N❑ uglL 0.50 1 08/15/19 03:37 95-49-8 4-Chloratoluene ND uglL 0.50 1 08/15/19 03:37 106-43-4 1,2-Dibromo-3-chloropropane ND ug1L 1.0 1 0811511903:37 96-12-8 Dibromochloromethane ND ug1L 0.50 1 08115/1903:37 124-48-1 1,2-Dibremoethane (EDB) ND ug1L 0.50 1 08/15/19 03:37 106-93-4 Dibromomethane ND ug1L 0.50 1 08/15/19 03:37 74-95-3 1,2-❑ichlorobenxene ND ug1L 0.50 1 08115/1903:37 95-50-1 1,3-Dichlorobenzene ND ug1L 0,50 1 08/15/190137 541-73-1 1,4-Dichlorobenzene N❑ ug1L D_50 1 08/15/1903.37 106-46-7 Dichlorodifluornmethane ND uglL 0.50 1 08/15/19 03:37 75-71-8 1.1-Dichloroethane ND uglL 0,50 1 08/15119 03:37 75-34-3 1,2-Dichloroethane 2.9 uglL 0,50 1 08/15/19 03:37 107-06-2 1,1-Dichloroethene ND ug1L 0,50 1 08/15119 03:37 75-35-4 cis-1,2-Dichloroethene ND uglL 0.50 1 08/15/19 03:37 156-59-2 trans-1,2-Dichloroethene ND uglL 0.50 1 08/15119 03:37 156-60-5 1,2-Dichloropropane ND uglL 0.50 1 08115M9 03:37 78-67-5 1,3-Dichlaropropane ND uglL 0.50 1 08115119 03:37 142-28-9 2,2-Dichloropropane N❑ ug1L 0.50 1 08/15/19 03:37 594-20-7 1.1-Dichloropropene ND uglL 0.50 1 08/15/19 03:37 563-58-6 cis-1,3-Dichloropropene ND ug1L 0.50 1 08115/1903:37 10061-01-5 trans-1,3-Dichloropropene N❑ uglL 0.50 1 08/15119 03:37 10061-02-6 Diisopropyl ether ND uglL 0.50 1 08/15/19 03:37 108-20-3 Ethanol ND ug1L 200 1 08/15/19 03:37 64-17-5 Eihylbenzene ND uglL 0,50 1 0811511903:37 100-01-4 Ethyl -tent -butyl ether ND uglL 10.0 1 08/15/19 03:37 637-92-3 Hexachloro-1,3-butadiene ND ug1L 2.0 1 0811511903:37 87-68-3 Isopropylbenzene (Cumene) ND uglL 0.50 1 08/15/19 03:37 98-82-8 Methylene Chloride ND uglL 2.0 1 08/15/19 03:37 75-09-2 Methyl -tent -butyl ether ND uglL 0.50 1 08115M9 03:37 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall no] be reproduced, except in full. Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 48 leAnalytical www.pscelabs.cam ANALYTICAL RESULTS Project: Carl's Country Stare Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 KinceyAve, Suite 100 Hu nte rsvil I e, NC 26078 (704)875-9092 Sample: DMW4 LabiD: 92441209011 Collected: 08112119 12:53 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit Di= Prepared Analyzed CAS No, Qual 6200E MSV Analytical Method: SM 6200B Naphthalene ND uglL 2.0 1 08/15/19 03:37 91-20-3 n-Pfopylbenzene ND uglL 0.50 1 08/15/19 03:37 103-65-1 Slyrene N❑ ug1L 0.50 1 08/15/19 03:37 100-42-5 1, 1, 1,2-Tetrachloroethane ND ug1L 0.50 1 0811511903:37 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 0811511903:37 79-34-5 Tetrachloroethene N❑ ug1L 0.50 1 08/15/19 03:37 127-18-4 Toluene ND uglL 0.50 1 08M511903:37 109-88-3 1,2,3-Trichlorobenzene ND ug1L 10 1 08/15/19 03:37 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 0B115119 03:37 120-82-1 1,1,1-Trichloroethane ND ug1L 0.50 1 08115/1903:37 71-55-6 1,1,2-Trichlcroethane ND ug1L 0.50 1 0811511903:37 79-00-5 Trichloroethene ND ug1L 0.50 1 08/15/19 03:37 79-01-6 Trichloroflucromethane ND uglL 1.0 1 08115/19 03:37 75-69-4 1,2,3-Trichloropropane N❑ uglL 0.50 1 08/15/19 03:37 96-18-4 1,2,4-Trimethyl benzene ND ug1L 0.50 1 08/15/19 03:37 95-63-6 1,3,5-Tri►nelhylbenzene N❑ uWL 0.50 1 08/16/19 03:37 1DM7-8 Vinyl chloride ND uglL 1.0 1 08/15/19 03:37 75.01-4 m&p-Xylene ND ug1L 1.0 1 08/15/19 03:37 179601-23-1 o-Xylene N❑ ug1L 0.50 1 08/15/19 03:37 95-47-6 Surrogates 1,2-Dlchloroethane-d4 (S) 100 % 70-130 1 08/15/19 03:37 17060-07-0 4-BromoRuorobenzene (S) 97 % 70-130 1 08/15/19 03:37 460-00-4 Toluene-d8 (S) 102 % 70-130 1 08/15119 0137 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in Tull, without the written consent of Pace Analytical Services, L-C. Page 25 of 48 laneAnalXicalo xwsvpaeelahs.cam ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kinsey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: DMW-5 Lab lD: 92441209012 Collected: 08112M9 14:02 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No_ Quat 62008 MSV Analytical Method: SM 6200B tert-Amyl Alcohol ND uglL 100 1 08/15/19 04:31 75-85-4 tert-Amylmethyl ether NO uglL 10.0 1 08/15/19 04:31 994-05-8 Benzene ND ug1L 0.50 1 08/15/19 04:31 71-43-2 Bromobenzene ND uglL 0.50 1 08/15119 04:31 108-86-1 Bromochloromethane N❑ uglL 0.50 1 08/15119 04:31 74-97-5 Bromodichloromethane ND uglL 0.50 1 08/15/19 04:31 75-27-4 Bromoform N❑ uglL 0.50 1 08/15/19 04:31 75-25-2 Bromomethane N❑ uglL 5.0 1 08/15119 04.31 74-83-9 tett-Butyl Alcohol ND uglL 10.0 1 08/15/19 04:31 75-65-0 n-Butylbenzene N❑ ug1L 0.50 1 08/1SM904:31 104-51-8 sec-Butylbenzene ND ug1L 0.50 1 08/15/19 04.31 135-98-8 tert-Butyl benzene NO ug1L 0.50 1 08/15/19 04:31 98-06-6 tert-Butyl Formate NO ug1L 20.0 1 08/15/19 04:31 762-75-4 Carbon tetrachloride ND ug1L 0.50 1 08/15/19 04:31 56-23-5 Chlorobenzene NO ug1L 0.50 1 08/15/19 04:31 108-90-7 Chloroethane N❑ ug1L 1.0 1 08115/19 04:31 75-00-3 Chloroform NO uglL 5,0 1 08/15/19 04:31 67-66-3 Chloromethane ND uglL 1 M 1 08115/19 D4:31 74-87-3 2-Chlorotoluene N❑ ug1L 0.50 1 08/15/19 04:31 95-49-8 4-Chlorotoluene ND ug1L 0,50 1 08115/1904:31 106-43-4 1,2-Dibromo-3-chloropropane N❑ uglL 10 1 0811511904:31 96-12-8 Dibromochloromethane ND uglL 0,50 1 08/15/19 04:31 124-48-1 1,2-❑ibromoethane (EDB) ND uglL 0,50 1 08/15/19 04:31 106-93-4 Dibromomethane N❑ ug1L 0,50 1 08/15/19 04:31 74-95-3 1,2-Dichlorobenzene ND uglL 0,50 1 0811511904.31 95-50-1 1,3-Dichlorobenzene ND uglL 0,50 1 08/15/1904.31 541-73-1 1,4-Dichlorobenzene ND uglL 0.50 1 08/15119 04:31 106-46-7 Dichloroditluoromethane NO ug1L 0.50 1 08115119 04:31 75-71-8 1,1-Dichloroethane N❑ ug1L 0.50 1 0811511904:31 75-34-3 1,2-Dichloroethane ND uglL 0.50 1 08/15/19 04:31 107-06-2 1,1-Dichloroethene N❑ uglL 0,50 1 08/15/19 04:31 75.35-4 cis-1,2-Dichloroethene N❑ uglL 0,50 1 08/15/19 04:31 156-59-2 trans-1,2-Dichloroethene ND ug)L 0.50 1 08115/19 04:31 156-60-5 1,2-Dichloropropane N❑ uglL 0.50 1 08/15/19 04:31 78-87-5 1,3-Dichtoropropane N❑ ug1L 0.50 1 08/15/19 04:31 142-28-9 2,2 -D ichloropro pane ND ug1L 0.50 1 08115/19 04:31 594-20-7 1,1-❑ichioropropene NO ug1L 0,50 1 08/15/19 04:31 563-58-6 cis-1,3-Dichloropropene N❑ uglL 0,50 1 08/15/19 04:31 10061-01-5 trans-1,3-Dichlofopropene ND uglL 0,50 1 0811511904:31 10061-02-6 Diisopropyl ether NO ug1L 0,50 1 08/15/19 04:31 108-20-3 Ethanol 446 uglL 200 1 08/15119 04:31 64-17-5 Etylbenzene N❑ ug1L 0.50 1 08/15119 04:31 100-41-4 Ethyl-tert-butyl ether N❑ uglL 10.0 1 08/15/19 04:31 637-92-3 Hexachloro-1,3-butadiene N❑ uglL 2.0 1 0811511904-31 87-68-3 Isopropylbenzene (Cunene) ND uglL 0.50 1 08/15/19 04:31 98-82-8 Methylene Chloride ND uglL 2.0 1 08/15/49 04:31 75-09-2 Methyl-tert-butyl ether N❑ ug1L 0,50 1 08/15/19 04:31 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 48 aceAnafyticaf WWWpaceisim-com ANALYTICAL RESULTS Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersv,Me, NC 28078 [704]B75-9092 Sample: DMW-5 Lab ID: 92441209012 Collected: 08/12/19 14:02 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Naphthalene n-Propyibenzene Styrene 1, 1, 1, 2-Teirachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 12,3-Trichloroberizene 1,2,4-Trichlorobenzene 1,1,1-Trichloraethane 1,1,2-Trichlornethane Trichloroethene Trich lorofiuoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromoiiuorobenzerte (S) Toluene -dB (S) Date: 09/09/2019 12:28 PM Analytical Method: SM 6200B N❑ uglL N❑ uglL NO uglL NO uglL NO uglL NO uglL ND ug1L NO uglL NO uglL NO uglL NO uglL NO uglL NO uglL N❑ ug1L N❑ ug1L NO ug1L NO uglL N❑ ug1L ND uglL 102 % 100 % 102 % 2.0 1 08/15/19 04:31 91-20-3 0.50 1 08115119 04:31 103 65-1 0.50 1 08/15/19 04:31 100-42-5 0.50 1 08/15/19 04:31 630-20-6 0.50 1 08/15119 04:31 79-34-5 0,50 1 08/15/19 04:31 127-18-4 0.50 1 08/15119 04:31 108-88-3 2.0 1 08/15119 04:31 87-61.6 2.0 1 08/15/19 04:31 120-82-1 0.50 1 08/15/19 04:31 71-55.6 0.50 1 08115/19 04:31 79-00-5 0.50 1 08/15/19 04:31 79-01-6 1.0 1 08/15/19 04:31 75-69-4 0,50 1 08/15/19 04:31 96-18-4 0,50 1 08/15/19 04:31 95-63-6 0,50 1 08/15/19 04,31 108-67-8 1.0 1 08/15/19 0421 75-01-4 1.0 1 08115/19 04:31 179601-23-1 0.50 1 08115119 04:31 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC 08115/19 04:31 17060-07-0 08/15/19 04:31 460-00-4 08/15/19 04:31 2037-26-5 Page 27 of 48 aceAnalytical� wsnxFrsce7abs.cam ANALYTICAL RESULTS Project: Carus Country Store Pace Project No.; 92441209 Pace Analytical Services, LLC 9EI00 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: WSW-9 Parameters Lab ID: 92441209013 Collected: 08112/19 14.55 Results Units Report Limit OF Received: 08/13/19 14:07 Matrix: Water Prepared Analyzed CAS. No, Qual 6200E MSV Analytical Method: SM 6200B Benzene ND uglL 0,50 1 08/15/19 06:38 71-43-2 Sromobenzene NO ug1L 0.50 1 08/15119 06:38 108-86-1 Bromochloromethane ND ug1L 0.50 1 08/15119 06:38 74-97-5 Bromodichloromethane ND ug1L 0,50 1 08/15119 06:38 75-27-4 Bromoform ND ug1L 0.50 1 08/15/19 06:38 75-25-2 Bromomethane NO ug1L 5.0 1 08/15/19 06:38 74-83-9 M1 n-Butyibenzene ND ug1L 0.50 1 08/15/19 06-38 104-51-8 sec-Butylbenzene ND ug1L 0.50 1 08/15/19 06:38 135-98-8 tert-Butyl benzene NO uglL 0.50 1 08/15/19 06:38 98-06-6 Carron tetrachloride NO uglL 0.50 1 08/15/19 06:38 56-23-5 Chlorobenzene ND uglL 0.50 1 08/15/19 06:38 108-90-7 Chlofoethane ND uglL 1.0 1 08/16/19 06:38 75-00-3 M1 Chloroform NO ugll. 5.0 1 08/15/19 06:38 67-66-3 Chloromethane NO uglL 1.0 1 OW1511906:38 74-87-3 M1 2-Chlorotoluerte NO ug1L 0.50 1 08/15/19 06:38 95-49-8 4-Chlorotoluene NO ug1L 0.50 1 08/15/19 06:38 106-43-4 1,2-Dibromo-3-chloropropane ND ug1L 1.0 1 0811511906:38 96-12-8 Dibromochloromethane ND ug1L 0,50 1 08115/19 06:38 124-48-1 1,2-Dibromoethane(EDB) ND uglL 0.50 1 08115/1906:38 106-93-4 Dibromomethane NO uglL 0,50 1 08/15/19 06:38 74-95-3 1,2-Dichlorobenzene ND uglL 0.50 1 08/15/19 06-38 95-50-1 1,3-Dichlorobenzene NO uglL 0.50 1 08/15119 06:38 541-73-1 1,4-Dichlorobenzene NO uglL 0.50 1 08/15/19 06:38 106-46-7 Dichlorodi€luoromethane NO uglL 0.50 1 08/15119 06:38 75-71-8 M1 1,1-Dichloroethane ND uglL 0.50 1 08/15/19 06:38 75-34-3 1,2-Dichloroethane NO uglL 0,50 1 08/15/19 06:38 107-06-2 1,1-Dichlor0ethene NO uglL 0.50 1 08/15/19 06:38 75-35-4 cis-1,2-Dichloroethene NO ug1L 0.50 1 081115119 06:38 156-59-2 trans-1,2-Dichloroethene ND ug1L 0,50 1 08/15/19 06:38 156-60-5 1,2-Dichloropropane NO ug1L 0,50 1 08/1511906:38 78-87-5 1,3-Dichloropropane NO uglL 0.50 1 08/15/19 06:38 142-28-9 2,2-Dichloropropane ND uglL 0,50 1 08/15/19 06:38 594-20-7 1.1-❑ichloropropene ND uglL 0.50 1 0811511906:38 563-58-6 cis-1,3-Dichlorapropene NO uglL 0,50 1 08/15/19 06:38 1OD61-01-5 trans- l,3-Dichloropropene ND uglL 0.50 1 08115119 06:38 10061-02-6 Diisopropyl ether ND ug1L 0.50 1 08/15119 06:38 108-20-3 Ethyl-tert-butyl ether NO uglL 10.0 1 08/15/19 06:38 637-92-3 Hexachloro-1,3-buladiene ND ug1L 2.0 1 08/15/19 06:38 87-68-3 Isopropylbenzene (Cumene) NO ug1L 0,50 1 08/15/19 06:38 98-82-8 Methylene Chloride ND ug1L 2.0 1 08/15/19 06:38 75-D9-2 Methyl-tert-butyl ether ND uglL 0.50 1 08/16/19 06:38 1634-04-4 Naphthalene NO ug1L 2.0 1 08/15/19 06:38 91-20-3 n-Propylbenzene NO uglL 0.50 1 08/15/19 06:38 103-65-1 Styrene ND uglL 0,50 1 08/15/19 D6:38 100-42-5 1.1.1.2-Tetrachloroethane ND uglL 0.50 1 08/1511906:38 630-20-6 1.1,22-Tetrachloroethane NO uglL 0.50 1 08/15/19 06:38 79-34-5 Tetrachlofoethene ND uglL 0,50 1 08/15/19 06:38 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 48 aD aceAnalytiical - - mnv.peceiahs.cam ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 t704j875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: WSW-9 Lab ID: 92441209013 Collected: 08/12/19 14:55 Received: D8113119 14:07 Matrix. Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200E MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Tr"rchlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Tri chlorofluorometha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-xyiene o-Xylene Surrogates 1,2-Dichloroethane-d4 +;Sy 4-Bromofluorobenzene (S) Toluene -dB {5} Date: 09/09/2019 12:28 PM Analytical Method: SM 6200B NO uglL NO uglL NO ug1L NO ug1L NO ug1L NO ug1L NO uglL NO uglL ND uglL NO uglL ND uglL NO ug1L ND ug/L 98 % 100 % 99 % 0.50 1 08/15119 06:38 108-88-3 2.0 1 08/15119 06:38 87-61-6 2.0 1 08/15/19 06:38 120-82-1 0.50 1 D8115119 D6:38 71-55-6 0.50 1 08/15/19 D6:38 79-00-5 D_50 1 08/15111306:38 79-01-6 1.0 1 08115/19 06:38 75-%4 0.50 1 08/15/19 06:38 96-18-4 0.50 1 0&15119 06:38 95-63-6 0.50 1 08115/19 06:38 108-67-8 1.0 1 08/15/19 06:38 75-01-4 M1 1.0 1 08/15/19 06:38 179601-23-1 0.50 1 08/15/19 0638 95-47-6 70-130 1 70-13D 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent or Pace Analytical Services, LLC 08/15/19 06:38 17060-07-0 08115119 06:38 460-00-4 08/15/19 06:38 2037-26-5 Page 29 of 48 I eAnaIXical tsww,pacelniYs.com I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Hunters0e, NC 28078 (104)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: Trip Blank Lab lD: 92441209014 Collected: 08/12/19 00:00 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit OF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 620013 tent -Amyl Alcohol NO uglL 100 1 08/15/19 01 A9 75-85-4 tert-Amylmethyl ether ND uglL 10.0 1 08/15/19 01-49 994-05-8 Benzene ND uglL 0.50 1 08/15/19 01:49 71-43-2 Bromobenzene ND uglL 0,50 1 08/15/19 01:49 108-86-1 Bromochloromethane ND ug1L 0.50 1 08/15/19 01:49 74-97-5 Bromodichloromethane N❑ ug1L 0.50 1 08/15/19 01:49 75-27-4 Bromofofm N❑ uglL 0.50 1 08/16/19 01:49 75-25-2 Bromomethane N❑ ug1L 5.0 1 08/15/19 01:49 74-83-9 tert-Butyl Alcohol NO uglL 10.0 1 08115/19 01:49 75.65-0 n-13utylbenzene ND ug1L 0.50 1 0811511901:49 104-51-8 sec-Butylbenzene ND ug1L 0,50 1 08/15/19 01:49 135-98-8 tert-S utyl benzene NO uglL 0,50 1 08115/19 01:49 98-06-6 ter( -Butyl Formate NO uglL 20.0 1 08/15/19 01:49 762-75-4 Carbon tetrachloride ND uglL 0.50 1 08/15/19 01:49 56-23-5 Chlorobenzene ND ug)L 0.50 1 08/15/19 01:49 108-90-7 Chloroelhane NO ug1L 1.0 1 08/15/19 01:49 75-00-3 Chloroform NO uglL 5.0 1 08/15/19 01:49 67-66-3 Chloromethane NO uglL 1.0 1 08/15119 01.49 74-87-3 2-Chlorotoluene NO ug1L 0.50 1 08/15119 01.49 95-49-8 4-Chlorotoluene ND uglL 0.50 1 08/15/19 01:49 106-43-4 1,2-Dibromo-3-chloropropane ND uglL 1.0 1 08/15/19 01:49 96-12-8 Dibromochloromelhane ND uglL 0,50 t 08/15/19 01:49 124-48-1 1,2-Dibromoethane (EDB) NO uglL 0.50 1 08/15/19 01:49 106-93-4 Dibromomethane ND uglL 0,50 1 08/15/19 01:49 74-95-3 1,2-Dichlorobenzene ND uglL 0.50 1 08/15/19 01:49 95-50-1 1,3-Dichiorobenzene NO uglL 0.50 1 101511901-49 541-73-1 1,4-Dichlorobenzene NO ug1L 0.50 1 08/15/19 01:49 106-46-7 Dichlorodi0uoromethane ND uglL 0.50 1 08/15/19 01:49 75-71-8 1,1-❑ichloroethane NO ug1L 0.50 1 08115/19 01:49 75-34-3 1,2-Dichloroethane NO uglL 0.50 1 08115/19 01:49 107-06-2 1,1-Dichloroethene ND uglL 0.50 1 08/15/19 01:49 75-35-4 cis-1,2-Dichloroethene NO uglL 0.50 1 08115/1901A9 156-59-2 trans-1 ,2-Dichloroethene NO uglL 0.50 1 08/15/19 01.49 156-60-5 1,2-Dichloropropane ND uglL 0,50 1 08/15/19 01:49 78-87-5 1,3-❑ichloropropane ND ug1L 0.50 1 08/15119 01:49 142-28-9 2,2-❑ichloropropane ND uglL 0.50 t 08/15/19 01:49 594-20-7 1,1-Dichloropropene ND uglL 0.50 1 08/15/19 01:49 563-58-6 cis-1,3-Dichlaropropene ND uglL 0.50 1 08/15/19 01:49 10061-01-5 trans-1,3-Dichtoropropene N❑ ug1L 0.50 1 08/15/19 01:49 10D61-02-6 Diisopropyl ether NO ug1L 0.50 1 08/15/19 01:49 108-20-3 Ethanol NO uglL 200 1 08/15/19 01:49 64-17-5 Ethylbenzene NO uglL 0.50 1 08/15/19 01:49 100-41-4 Ethyl-terl-butyl ether N❑ uglL 10.0 1 08/15/19 01:49 637-92-3 Hexachloro-1,3-butadiene ND uglL 2.0 1 08115M901:49 87-68-3 Isopropylbenzene (Cumene) NO uglL 0.50 1 08/15/19 01:49 98-82-8 Methylene Chloride 4.1 uglL 2.0 1 08115/19 01:49 75-09-2 C9 Methyl-tert-butyl ether N❑ uglL 0,50 1 08115/19 01:49 1634-04-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09109/2019 12:28 PM without the written consent or Pace Analytical Services, LLC Page 30 of 48 aceAnalytical ww.peaelaftwm ANALYTICAL RESULTS Pace Analytical Servlces, LLC 9800 Kincey Ave. Suite 100 Huntersville, NG 28078 t704j875-9092 Project: Carl's Country Store Pace Project No.: 92441209 Sample: Trip Blank Lab ID: 92441209014 Collected: 08112119 00:00 Received: 08/13/19 14:07 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No_ Qual 6200E MSV Analytical Method_ SM 62008 Naphthalene ND ug1L 2.0 1 08/15/19 01:49 91-20-3 n-Propylbenzene ND uglL 0,50 1 08/15/19 01:49 103-65-1 Styrene ND uglL 0.50 1 08/15/19 01:49 10042-5 1,1,1,2-Tetrachloroethane ND uglL 0.50 1 08/1511901.--49 630-20-6 1,1,22-Tetrachloroethane ND ug/L 0.50 1 08/15/19 01:49 79-34-5 Tetrachloroethene ND uglL 0.50 1 08/15/19 01:49 127-18-4 Toluene ND uglL 0.50 1 08/15/19 01:49 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 08/15/19 01:49 87-61-6 1,2,4-Trichlorobenzene ND ug)L 2.0 1 08/15/19 01:49 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 08/15/19 01:49 71-55-6 1,1,2-Trichloroethane ND ug1L 0.50 1 08/15/19 01:49 79-00-5 Trichioroethene ND uglL 0.50 1 08/15/19 01:49 79-01-6 Trichlorofluoromethane ND uglL 1.0 1 08/15/19 01:49 75-69-4 1,2,3-Trichloropropane ND uglL 0.50 1 08/15/19 01:49 96-18.4 1,2,4-Trimethylbenzene ND uglL 0,50 1 08115/1901:49 95-63.6 1,3,5-Trimelhylbenzene N❑ uglL 0.50 1 0811511901:49 108-67-8 Vinyl chloride ND uglL 1.0 1 08/15/19 01:49 75-01-4 m&p-Xylene ND ug/L 1.0 1 08115/19 01:49 179601-23-1 o-Xylene ND ug]L 0.50 1 08/15/19 01:49 95.47-6 Surrogafes 1,2-Dichioroethane-d4 (S) 99 % 70-130 1 08/15/19 01 A9 17060-07-0 4-Bromofluorobenzene (S) 100 % 70-130 1 08/15/19 01:49 460-00-4 Toluene -dB (S) 103 % 70-130 1 08/15119 01:49 2037-26-5 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the wiritten consent of Pace Analytical Services, LLC. Page 31 of 48 aceAnalj6cal wwtxpaeelahscorn QUALITY CONTROL DATA Project: Carl's Country Store Pace Projecl No.: 92441209 Pace Analytical Services, LLC 9aOO Kincey Ave Suite 100 Huntersville, NC 28070 (704)875-9092 QC Batch: 492314 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92441209001, 92441209005, 92441209006, 92441209007, 92441209068, 92441209009. 92441209010, 92441209011,92441209012,92441209013,92441209014 METHOD BLANK: 2654373 Matrix: Water Associated Lab Samples: 92441209001, 92441209005, 92441209006, 92441209007, 92441209008, 92441209009, 92441209010, 92441209011, 92441209012, 92441209013. 92441209014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachtoroethane uglL ND 0.50 08/15119 01:31 1,1,1-Trichioroethane uglL NO 0.50 0811511901-31 1,1.2,2-Telrachloroelhane ug1L ND 0.50 0811511901:31 1,1,2-Trichloroethane ug1L N❑ 0.50 08/15119 01:31 1,1-Dichloroethane ug1L N❑ 0.50 0811511901:31 1,1-Dichloroethene uglL ND 0.50 08/16/1901:31 1,1-Dichloropropene uglL ND 0.50 08/15119 01:31 12,3-Trichlofobenzene uglL N❑ 2.0 08/15119 01:31 1,2,3-Trichloropropane uglL N❑ 0.50 08/15119 01:31 1,2,4-Trichlorobenzene uglL ND 2.0 08115/19 01:31 1,2,4-Trimethylbenzene uglt. ND 0.50 08115/1901:31 1,2-Dibromo-3-chlompropane uglL ND 1.0 08/15/19 01:31 1,2-Dibromoethane (EDB) ug1L ND 0.50 08/15/19 01:31 1,2-Dichlorobenzene ug1L NO 0.50 08/15119 01:31 1,2-Dichloroethane uglL NO 0,50 08/15119 01.-31 1,2-Dichloropropane uglL N❑ 0.50 08/15119 01:31 1,3,5-Trimethylbenzene uglL NO 0.50 08/15119 01:31 13-Dichlorobenzene ug1L NO 0.50 0811511901:31 1,3-Dichloropropane uglL N❑ 0.50 0811511901-31 1,4-Dichlorobenzene UA ND 0,50 08/15119 01:31 2,2-Dichloropropane uglL ND 0.50 08115/1901:31 2-Chlorotoluene ug1L ND 0.50 08/15/19 01:31 4-Chlorotoluene uglL ND 0,50 08/15/19 01:31 Benzene uglL NO 0.50 08/15/19 01:31 Bromobenzene uglL NO 0.50 08/15119 01:31 Bromochloromethane uglL N❑ 0,50 D8115119 D1:31 Bromodichloromethane uglL N❑ 0.50 08/15/19 01:31 Bromoform uglL NO 0,50 08/15/19 01:31 Sfomomethane uglL NO 5.0 08/15119 01:31 Carbon tetrachloride uglL ND 0.50 08/15/19 01:31 Chlorobenzene uglL ND 0.50 08/15119 01:31 Chlofoethane uglL NO 1.0 0811511901:31 Chloroform uglL NO 5.0 08115/19 01:31 Chloromethane ug1L ND 1.0 08/15/19 01:31 cis-1,2-Dichloroethene uglL N❑ 0,50 0811511901:31 cis-1,3-Dichloropropene uglL NO 0.50 08/15/19 01:31 Dibromochloromethane uglL NO 0.50 08/15/19 01:31 Dibromomethane ug1L N❑ 0.50 08/15119 01.31 Dichlorodifluoromethane ug1L ND 0.50 08/15119 01.-31 ❑iisopropyl ether ug1L NO 0.50 08/15/19 01:31 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2Of 9 12:28 PIN without the written consent of Pace Analytical Services, LLC. Page 32 of 48 laceAnalytical"' www.pamahs.com QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kinsey Ave. Suite 100 HuntersvM e, NC 28078 (7t14)875-9092 METHOD BLANK: 2654373 Matrix: Water Associated Lab Samples' 92441209001, 92441209005. 92441209006, 92441209007, 92441209008, 92441209009, 92441209010, 92441209011,92441209012,92441209013,92441209014 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene ug1L No 0.50 06115/19 01:31 Hexachlaro-1,3-butadiene ug1L ND 2.0 0811511901:31 Isopropylbenzene(Cumene) ug1L ND 0.50 08115/19 01:31 m&p-Xylene uglL ND 1.0 08115/1901,31 Methyl-tert-butyl ether ug1L ND 0,50 08/15/19 01:31 Methylene Chloride uglL ND 2.0 08/15/19 01:31 n-Butylbenzene uglL ND 0.50 08/15/19 01:31 n-Propylbenzene ug1L N❑ 0.50 08/15119 01:31 Naphthalene ug1L NO 2-0 08/15119 01:31 o-Xylene uglL ND 0.50 08/15119 01:31 sec—Butylbenzene uglL NO 0.50 08/15/19 01:31 Styrene ug/t_ NO 0,50 08/15119 01:31 tert-Butylbenzene ug1L NO 0,50 08/15/19 01:31 Tetrachloroethene uglL N❑ 0.50 08/15/19 01:31 Toluene ug1L ND 0.50 08/15/19 01:31 Vans-1,2-Dichloroethene uglL NO 0.50 08/15/19 01:31 trans- l,3-Dichloropropene ug1L N❑ 0.50 0811511901:31 Trichloroethene uglL ND 0.50 08115/19 01:31 Trichloro luoromethane uglL ND 1.0 08115/19 01:31 Vinyl chloride uglL ND 1,0 08/1511901:31 1,2-Dichloroethane-d4 (S) % 101 70-130 08/15/19 01:31 4-Bromofiunrobenzene (S) % 100 70-130 08/15/19 01:31 Toluene-d8 (S) % 101 70-130 08115/19 01.-31 LABORATORY CONTROL SAMPLE:. Parameter 2654374 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1, 1. 1, 2 -Tetrachloroethane uglL 50 47.0 94 60-140 1,1.1-Trichloroethane uglL 50 49.1 98 60-140 1,1,2,2-Telrachloroethane uglL 50 45.5 91 60-140 1,1,2-Trichloroethane uglL 50 49A 99 60-140 1,1-Dichloroethane uglL 50 50.3 101 60-140 1,1-Dichlaroethene uglL 50 48.8 98 60-140 1,1-Dichloropropene uglL 50 45.6 91 60-140 1,2,3-Trichlorobenzene uglL 50 35.7 71 60-140 1,2,3-Trichloropropane ug1L 50 48.5 97 60-140 1,2,4-Trichlorobenzene uglL 50 40.0 80 60-140 1.2,4-Trimethylbenzene ug1L 50 43.8 88 60-140 1,2-Dibromo-3-chloropropane uglL 50 40.8 82 60-140 1,2-Dibromoethane (EDB) uglL 50 46.4 93 60-140 1,2-Dichlorobenzene uglL 50 43.9 88 60-140 1,2-Dichloroethane ug1L 50 45.8 92 60-140 1,2-Dichloropropane uglL 50 48.9 98 60-140 Results presented on this page are in the units indicated by the -Units' column except where an alternate unit Is presented to Out right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Dale: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC Page 33 of 48 aceAnalytical www.pecelabs.com QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92441209 LABORATORY CONTROL SAMPLE: 2654374 Pace Analytical services, LLC 9800 Kinney Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,3,5-Trimethylbenzene uglL 50 43.6 87 60-140 1,3-Dichlorobenzene uglL 50 43.3 87 60-140 1,3-Dichloropropane uglL 50 49.5 99 60-140 1,4-Dichlorobenzene uglL 50 43.2 86 60-140 2,2-Dichloroprepane uglL 50 43.5 87 60.140 2-Chlorololuene ug1L 50 43A 87 60-140 4-Chlarotoiuene uglL 50 43.3 87 60-140 Benzene uglL 50 47.0 94 60-140 Bromobenzene uglL 50 45,0 90 60-140 Bromochloromethane uglL 50 49.3 99 60-140 Bromodichloramethane uglL 50 50.6 101 60-140 Bromoform ug& 50 45.5 91 60-140 Bromomethane uglL 50 59.9 120 60-140 Carbon tetrachloride uglL 50 43.9 88 60-140 Chiorobenzene uglL 50 44.9 90 60-140 Chloroethane uglL 50 45.0 90 60-140 Chloroform ug1L 50 50.7 101 60-140 Chloromethane uglL 50 52.0 104 60-140 cis- 1,2-Dichloroethene uglL 50 49.6 99 60-140 cis-1, 3•Dichloropropene ug1L 50 50.5 101 60-140 Dibromochloromethane uglL 50 45.7 91 60-140 Dibromomethane ug1L 50 47.2 94 60-140 Dlchlorodlfluoromethane uglL 50 36.5 73 60.140 Diisopropyi ether uglL 50 51.4 103 SG-140 Euhylbenzene uglL 50 45.6 91 60-140 Hexachloro-1,3-butadfene uglL 50 40.4 81 60.140 Isopropylbenzene (Cumene) uglL 50 46A 92 60-140 m&p-Xylene uglL 100 91A 91 60-140 Methyl -lent -butyl ether uglL 50 50A 101 60-140 Methylene Chloride ug1L 50 45.4 91 60-140 n-Butylbenzene uglL 5o 40.5 81 60-140 n-Propylbenzene uglL 5o 43.3 87 60-140 Naphthalene uglL 50 36.7 73 60-140 o-Xylene uglL 50 46.2 92 60-140 sec-Butylbenzene uglL 50 44.7 89 60-140 Styrene uglL 50 45.9 92 60-140 tert-Butylbenzene uglL 50 38.0 76 60-140 Tetrachloreethene ug& 50 44.8 90 60-140 Toluene uglL 50 46.4 93 60-140 11rans-12-Dichloroethene uglL 50 49.4 99 60-140 train s-1.3-Dichloropropene uglL 50 49.2 98 60-140 Trichloroethene uglL 50 47.5 95 M140 Trichlorofluoromethane uglL 50 42.3 85 60-140 Vinyl chloride ug1L 50 46.6 93 60-140 1,2-0ichloroethane-d4 (5) % 94 70-130 4-Bromafluorobenzene (S) % 104 70.130 Toluene-d8 (S) % 99 70-130 Results presented on this page are in the units Indicated by the "Units' column except where an alternate unit is presented to She right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date. 09/09/2019 12:28 PM without the written consent or Pace Analytical Services, LLC. Page 34 of 48 aoAnalytical" wwtepscefabs.00m QUALITY CONTROL DATA Project: Cares Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kincey Ave. Suite l DC Huntersville, NC 2t3078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655463 MS 92441209013 Spike Parameter Units Result Conc. MSD Spike Cone, 2655464 MS Result MSD Result MS % Rec MSD % Rec 9% Rec Limits RPD Qual 1,1.1,2-Tetrachioroethane ug/L N❑ 20 20 21.3 21.0 106 105 60-140 1 1,1,1-Trichloroethane ug1L NO 20 20 25.7 24.8 128 124 60-140 4 1,1,2,2-Tetrachloroelhane ug1L NO 20 20 21A 20.1 106 101 60-140 5 1,1,2-Trichloroethane uglL NO 20 20 23.6 23.0 118 115 60-140 3 1,1-Dichloroethane uglL ND 20 20 25.7 24.8 129 124 60-140 4 1,1-Dichloroethene uglL ND 20 20 27.0 25.2 135 126 60-140 7 1,1-❑ichloropropene ug1L ND 20 20 24.4 23.3 122 117 60-140 5 1,2,3-Trichlorobenzene ug/L ND 20 29 19.4 18.9 97 95 60-140 2 1,2,3-Trichloropropane ug1L NO 20 20 21.9 21A 110 105 60-140 4 1,2,4-Trichlorobenzene ug/L NO 20 20 19.4 19.7 97 98 60-140 2 1,2,4-Trimethyibenzene ug/L NO 20 20 20.0 19.8 100 99 60-140 1 1,2-Dibromo-3-chloropropane ug1L ND 20 20 18.7 18.0 94 90 60-140 4 1,2-17ibromoethane (EDB) uglL NO 20 20 22A 21.1 ill 105 60-140 5 1,2-Dichlorobenzene uglL ND 20 20 20.0 19.8 100 99 60-140 1 1,2-Dichloroethane uglL NO 20 20 22A 22.6 110 113 60-14❑ 2 1,2-Dichlofopropane ug1L NO 20 20 22.6 22.7 113 114 60-140 1 1,3,5-Trimethylbenzene ug1L NO 20 20 20.5 20.0 102 100 60-140 3 1,3-Dichlorobenzene ug1L ND 20 20 19.7 19.3 98 97 60-140 2 1,3-Dichloropropane ug/L NO 20 20 23.2 22.6 116 113 60-140 3 1,4-Dichiorobenzene ug1L ND 20 20 19.8 19A 99 97 60-140 2 2,2-Dichloropropane uglL ND 20 20 25.9 24.7 130 124 60-140 5 2-Chlorotoluene uglL ND 20 20 19.6 19.9 98 99 60-140 1 4-Chlorotoluene uglL NO 20 20 20.2 19.5 101 97 60-140 4 Benzene uglL NO 20 20 23.0 22.2 115 111 60-140 4 Bromobenzene ug1L NO 20 20 20.8 20.8 104 104 60-140 0 Bromochloromethane ug/L NO 20 20 25A 23A 128 117 60-140 9 Bromodichiaromethane ug1L NO 20 20 23.7 22.6 118 113 60-140 4 Bromoform ug1L NO 20 20 20.0 19.7 100 98 60-140 2 Bromomethane ug/L NO 20 20 39.2 32.7 196 164 60-140 18 M1 Carbon tetrachloride ug1L NO 20 20 23.4 23.2 117 116 60-140 1 Chlorobenzene uglL ND 20 20 21.3 20.9 107 105 60-140 2 Chloroethane uglL NO 20 20 29.4 28.1 147 140 60-140 5 M1 Chloroform ug)L NO 20 20 25.3 25.0 127 125 60-140 1 ChForomethane uglL NO 20 20 28.3 28.6 142 143 60-140 1 M1 cis-1,2-Dichloroethene ug1L NO 20 20 25.1 23.6 125 118 60-140 6 cis-1,3-Dichloropropene ug/L NO 20 20 24.6 24.1 123 121 60-140 2 Dibromochloromethane ug/L NO 20 20 20.7 19.7 104 98 60-140 5 Dibromomethane uglL ND 20 20 22.0 22.3 110 112 60-140 1 Dichlorod i0uoromethane u91L ND 20 20 29.5 27.9 147 139 60-140 5 M1 ❑iisopropyl ether uglL ND 20 20 2C7 23.9 124 119 60-140 4 Ethylbenzene ugA- 20 20 22.1 21.8 111 1D9 60-140 1 Hexachloro-1,3-butadiene uglL NO 20 20 211 20.3 106 101 60-140 4 Isopropylbenzene (Cumene) ugJL ND 20 20 22.2 21.9 111 109 60-140 2 m&p-Xylene ug1L N❑ 40 40 43.8 43.5 110 109 60-140 1 Methyl-tert-butyl ether u911- NO 20 20 24.6 23.8 123 119 60-14D 3 Methylene Chloride ug/L N❑ 20 20 22.8 21.6 114 108 60-140 6 Results presented on this page are to the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 09/09/2019 12.28 PM without the written consent of Pace Analytical Services, L-C. Page 35 of 48 (�IaneAnalyti+cal www.Pacela6s.cbm QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92441209 Pace AnalyticaI Sorvices, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655463 MS 92441209013 Spike Parameter Units Result Conc. MS❑ Spike Conc. 2655464 MS Result MS❑ Result MS % Rec MSD °% Rec % Rec Limits RPD Qual n-Butylbenzene uglL ND 20 20 19.4 19.1 97 96 60-140 2 n-Propylbenzene ugJL NO 20 20 20A 20A 102 102 60-140 0 Naphthalene ug/L ND 20 20 18.9 18.7 94 94 60-140 1 o-Xylene ug/L ND 20 20 21.5 21.6 108 108 60-140 1 sec-Butylbenzene ug/L ND 20 20 21.3 21,0 107 105 60-140 2 Styrene uglL ND 20 20 21.2 21.3 106 106 60-140 0 tert-Butylbenzene uglL ND 20 20 17.8 17.6 89 88 60-140 1 Tetra chloroethene ug/L ND 20 20 22.3 21.5 111 108 60-140 3 Toluene uglL ND 20 20 22.3 22.6 112 113 60-140 1 trans- 1,2-Dichlorcethene ug/L N❑ 20 20 26.1 25.2 130 126 60-140 4 trans-1,3-Dichloropropene ug/L N❑ 20 20 22.3 22.6 112 113 60-140 1 Trichloroethene ug/L N❑ 20 20 23.9 23.7 120 116 60-140 1 Trichlorofluoromethane ug/L ND 20 20 27A 25.8 137 129 60-140 6 Vinyl chloride ug/L ND 20 20 28.3 27.0 142 135 60-140 5 M1 12-Dichloruethane-d4 (S) % 1D4 101 70-130 4-Bromofluorobert7ene (S) % 104 103 70-130 Toluene-d8 (S) % 401 100 70-130 Results presented on this page are In the units Indicated by the "units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not he reproduced, except in full, Dale: 09/09/2019 12:28 PM without the written consent of Pace Analytical services, LLC. Page 36 of 48 acmnaiX cal" Kwn Powiabs. com QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.- 92441209 QC Batch: 492595 Analysis Method: QC Batch Method: SM 6200B Analysis Description: Associated Lab Samples: 92441209002, 924412D9D03, 92441209004 SM 6200B 6200B MSV METHOD BLANK: 2655707 Matrix: Water Associated Lab Samples: 92441209002, 92441209003, 92441209004 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug1L ND 0.50 08115/1914-38 1,1,1-Trichioroethane ug1L ND 0.50 0811511914:38 1,1,2,2-Telrachloroethane uglL ND 0.50 0811511914:38 1,1,2-Trichlaroethane uglL NO 0.50 08115/1914:38 1,1-Dichloroethane uglL ND 0.50 0811511914:38 1,1-Dichloroethene uglL ND 0.50 0811511914:38 1,1-Dichloropropene ug1L NO 0.50 0811511914:38 1,2,3-Trichlorobenzene ug1L ND 2.0 08/1511914:38 1,2,3-Trichloropropane uglL ND 0.50 0811511914:38 1,2,4-Trichiorobenzene uglL ND 2.0 OW1511914:38 1,2,4-Trimelhylbenzene uglL ND 0.50 08/15/19 14:38 12-Dibramo-3-chloropropane ug1L ND 1.0 08115/1914:38 1,2-Dibromoethane (EDB) ug1L ND 0.50 08/15/19 14:38 1,2-Dichlorobenzene uglL ND 0.50 08/15/1914:38 1,2-❑ichloroethane u91L NO 0.50 08115/1914.38 1,2-Dichloropropane uglL NO 0.50 0811511914-38 1,3,5-Trimethylbenzene ug1L NO 0.50 08115/1914:38 1,3-Dichlorobenzene ug1L NO 0.50 0811511914:38 1,3-Dichloropropane ug1L NO 0.50 08/1511914:38 1,4-Dichlcrobenzene ug1L ND 0.50 08115/1914:38 2,2-Dichloropropane uglL NO 0.50 0811511914:38 2-Chlorotoluene uglL NO 0.50 08/1511914:38 4-Chlorotoluene uglL ND 0.50 08M511914:38 Benzene uglL ND 0.50 08/1511914:38 Bromobenzene uglL NO 0.50 0811511914:38 Bromochloromethane uglL NO 0.50 0811511914-38 Bromodichloromethane ug1L ND 0.50 0811511914:38 Bromoform ug1L NO 0,50 08115/1914:38 Bromomethane ug1L NO 5.0 08/15/1914:38 Carbon tetrachloride uglL NO 0.50 08/15/19 14.--38 Chlorobenzene ug1L ND 0.50 08115/1914.38 Chloroethane ug1L ND 1.0 08/1511914:38 Chloroform uglL NO 5.0 0811511914:38 Chloromethane uglL ND 1.0 0811511914:38 cis-1,2-Dichloroethene uglL ND 0.50 0811511914:38 cis-1,3-Dichloropropene ug1L NO 0.50 08/1511914:38 Dibromochloromethane uglL NO 0.50 0811511914:38 Dibromomethane uglL NO 0.50 0811511914-38 Dichlorodifluoromethane uglL NO D_50 0811511914-38 Diisopropyl ether uglL NO 0.50 08/15/19 14:38 Ethylbenzene uglL NO 0.50 08115/1914:38 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave- Suite 100 Huntersville, NC 28078 {7(14]875-9092 Results presented on this page are In the units Indicated by the 'Units" column except where an alternale unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 48 lacmnalyfical" wirw,pecelahxixflm QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92441209 METHOD BLANK: 2655707 Matrix: Water Associated Lab Samples- 92441209002, 92441209003, 92441209004 Blank Reporting Parameter Units Result Limil Analyzed Hexachloro-1,3-butadiene uglL ND 2.0 Dail 511914:38 lsopropylbenzene (Cumene) ug1L ND 0.50 08/15/19 14:38 m&p-Xylene uglL N❑ 1.0 08/15/19 14:38 Methyl-tert-butyl ether uglL ND 0.50 08/15/19 14:38 Methylene Chloride uglL ND 2.0 08/15/19 14:38 n-Butylberzene uglL N❑ 0.50 08115/1914:38 n-Propylbenzene ug1L ND 0.50 0811511914:38 Naphthalene ug1L ND 2.0 0811511914:38 o-Xylene ug1L ND 0.50 08/1511914:38 sec-Butylbenzene uglL ND 0.50 0811511914:38 Styrene uglL ND 0,50 08/15/1914:38 tert-Butylbenzene uglL ND 0.50 08/15/1914:38 Tetra chloroethene uglL ND 0.50 08/1511914:38 Toluene uglL ND 0.50 0811511914,36 trans-1,2-Dichloroethene uglL ND 0.50 08/1511914:38 trans-1,3-Dichloroproperle ug1L ND 0.50 08115/1914-38 Trichloroethene uglL ND 0.50 08/1511914:38 Trichlorofluoromelhane uglL ND 1.0 0811511914:38 Vinyl chloride ug1L ND 1.0 08/15119 14:38 1,2-Dichlorcethane-d4(S) % 102 70-130 06115/1914:38 4- Bromoll uo ro benzene (S) % 100 70-130 08/15/19 14:38 Toluene-d8 (S) % 99 70-130 08/15/19 14:38 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2655708 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-1e1rachloroethane ug1L 50 50.9 102 60-140 11,1-Trichlorcelhane ug1L 50 58A 117 60-140 1.1,2,2-Tetfachloroethane uglL 50 47.7 95 60-140 1,1,2-Trichlot oethane ug1L 50 55.1 110 60-140 1,1-Dichloroethane ug1L 50 58.3 117 60-140 1,1-❑ichloroethene uglL 50 57.7 115 60-140 1, 1 -Dichiorop ropene ug1L 50 55.3 111 60-140 1,2,3-Trichlorobenzene uglL 50 45.2 90 60-140 1,2,3-Trichloropropane uglL 50 51.5 103 60-140 1,2,4-Trichlorobenzene ug1L 50 48.0 96 60-140 1,2,4-Trimethy3benzene uglL 50 47.4 95 60-140 1,2-Dibromo-3-chloropropane uglL 50 45.7 91 60-140 1,2-Dibromeethane (EDB) ug1L 50 51.0 102 60-140 1,2-Dichlorobenzene uglL 50 47.8 96 60.140 1,2-Dichloroethane uglL 50 52.4 105 60.140 1,2-Dichloropropane uglL 50 52.4 105 60-140 1,3,5-Trimethylbenzene uglL 50 48A 97 60-140 1,3-Dichlorobenzene ug1L 50 47.5 95 60-140 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 2EI078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternale unit Is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, Date: 09/09/2019 12:28 PM without the written consent or PaceAnalyticsl Services, LLC. Page 38 ot48 aceAnalytical www.pacB1ah3.00ar 1 QUALITY CONTROL DATA Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 8800 Kincey Ave. Suite 100 Hlmtarsville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE_ Parameter 2655708 Units Spike Cone. LCS Result LCS % Rec % Ree Limits Qualifiers 1,3-Dichloropropane ug1L 50 52.3 105 60-140 1,4- Diehl orobenzene ug1L 50 47.4 95 60-140 2,2-Dichlaropropane uglL 50 57.6 115 60-140 2-Chlorotoluene uglL 50 47.4 95 60-140 4-Chlorotoluene uglL 50 48.2 96 60-140 Benzene uglL 50 52.1 104 60-140 Bromobenzene uglL 50 4U 99 60-140 Bromochloromethane uglL 50 56.2 112 6D-140 Bromodichloromethane uglL 50 56.3 113 60-140 Bromofonn uglL 50 49.4 99 60-140 Bromomethane ua 50 M3 141 60-140 L1 Carbon tetrachloride uglL 50 53.9 108 60-140 Chlorobenzene ug1L 50 49.2 98 60-140 Chloroethane uglL 50 55.2 110 60-140 Chloroform ug1L 50 56,9 114 60-140 Chloromethane uglL 50 63A 127 60-140 cis-1,2-Dichloroethene uglL 50 56.6 113 60-140 cis- 1,3- Diehl oropropene uglL 50 56.5 113 60-140 Dibromochloromethane ug1L 50 49.9 100 60-140 ❑ibromomelhane uglL 50 51.4 103 60-140 Dichlorodifluoromethane uglL 50 62.6 125 60-140 Diisopropyl ether uglL 50 57.2 114 60-140 Ethylbenzene uglL 50 50.3 101 60-140 Hexachloro-1,3-butadiene uglL 50 50.2 100 60-140 Isopropylbenzene (Cumene) ug& 50 51.6 103 60-140 m&p-Xylene ug1L 100 100 100 60-140 Methyl-tert-butyl ether uglL 50 56.5 113 60-140 Methylene Chloride uglL 50 50.8 102 60-140 n-Butylbenzene uglL 50 46.6 93 60-140 n-Propylbenzene u911- 50 48,0 96 60-140 Naphthalene uglL 50 44.2 88 60-140 o-Xylene uglL 50 50.8 102 60-140 sec-Butylbenzene uglL 50 50.8 102 60-140 Styrene ug1L 50 50.4 101 60-140 tert-Butytbenzene uglL 50 41.9 84 60-14D Tetrachlorcethene uglL 50 50.9 102 60-140 Toluene uglL 50 52.4 105 60-140 trans- 1.2-Dichlaroethene ug1L 50 57.6 115 60-140 trans- 1,3-Dichloropropene uglL 50 54.1 108 60-140 Trichloroethene ug1L 50 54.6 109 60-140 Trichlorofluoromethane uglL 50 5&5 113 60-140 Vinyl chloride ug1L 50 60.7 121 60-140 1,2-Dichloroethane-d4 (S) % 102 70-130 4-Bromottuorobenzene (S) % 103 70-130 Toluene -dB (5) % 102 70-130 Results presented on this page are In the units Indic aled by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 09/09/2019 12:28 PM without the written consent or Pace Analytical Services, LLC. Page 39 of 48 aceAnalylr'cal" -pa"b&cm [QUALITY CONTROL DATA Pace Analytical Services, LLC 9600 KinceyAve-Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Carl's Country Store Pace Project No.: 92441209 MATRIX SPIKE & MATRIX SPIKE DUPLICATE. 2655709 2655710 MS MS❑ 92441209004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane uglL ND 20 20 21.8 20.9 109 104 60-140 4 1, 1, 1 -Trichloroethane uglL ND 20 20 21.0 20.0 105 100 60.140 5 1,1,2,2-Tetrachloroethane uglL ND 20 20 20.0 20.0 100 100 60-140 0 1,1,2-Trichloroethane uglL ND 20 20 20.4 19.3 102 96 60-140 6 1,1-Dichloroethane uglL NO 20 20 20.8 20.2 104 101 60-140 3 1,1-Dichloroethene uglL N❑ 20 20 20-7 20.3 103 102 60-140 2 1, 1 -Dichloropropene ug1L NO 20 20 19.8 18.8 99 94 60-140 6 1,2,3-Trichlorobenzene ug1L ND 20 20 22A 20.6 112 103 60-140 8 1,2,3-Trichloropropane uglL NO 20 20 20.6 20.7 103 103 60-140 1 1,2,4-Trichlorobenzene uglL NO 20 20 21,0 19.9 105 99 60-140 6 1,2,4-Trimethylbenzene uglL 2-5 20 20 23.8 23.0 106 102 60-140 3 1,2-Dibromo-3-chloropropane ug1L NO 20 20 21A 21.7 107 108 60-140 1 1,2-Dibromoethane (EDB) uglL NO 20 20 21-1 21-1 106 106 60-140 0 1,2-Dichloroben7ene uglL NO 20 20 20.7 19.8 103 99 60-140 4 1,2-Dichloroethane uglL NO 20 20 17.6 17.2 88 86 60-140 2 1,2-Dichloropropene uglL NO 20 20 21.1 19.3 106 97 60-140 9 1,3,5-Trimethylbenzene uglL ND 20 20 23.4 22-6 117 113 60-140 3 1,3-Dichlorobenzene uglL ND 20 20 20.6 19.8 103 99 60-140 4 1,3-Dichloropropane ug1L NO 20 20 21.7 21.2 109 106 60-140 2 1,4-Dichlorobenzene uglL ND 20 20 20.0 19.8 100 99 60-140 1 2,2-Dichloropropene uglL N❑ 20 20 19.2 18.3 96 92 60-140 5 2-Chlorotoluene uglL N❑ 20 20 21.3 20.1 107 101 60-140 6 4-Chlorotoluene uglL ND 20 20 20-8 19.9 104 99 60-140 4 Benzene uglL 101 20 20 118 115 85 69 60-140 3 Bromobenzene uglL ND 20 20 21.1 21.1 106 106 60-140 0 Bromochloromethane uglL ND 20 20 19.8 19.1 99 95 60-140 4 Bromodichloramethane uglL ND 20 20 21-1 20.9 105 105 60-140 1 Bromoform uglL NO 20 20 21.1 21.2 106 106 60-140 1 Bromomethane ug1L ND 20 20 22.3 21.8 106 104 60-140 2 Carbon tetrachloride uglL NO 20 20 21A 19.4 106 97 60-140 8 Chlorobenzene uglL ND 20 20 20.9 20-1 ID4 100 60-140 4 Chloroethane uglL NO 20 20 19.3 18.6 97 93 60-140 4 Chloroform uglL NO 20 20 19.3 19.6 97 98 60-140 2 Chloromethane uglL NO 20 20 19.1 17.9 95 90 60-140 6 cis- 1,2-Dichloroethene uglL NO 20 20 20.1 19.4 100 97 60-140 3 cis-1,3-Dichloropropene uglL ND 20 20 24.8 20.5 109 102 60-140 6 Dibromochloromethane uglL NO 20 20 21.9 20.1 109 100 60-140 9 ❑ibromomethane ug1L NO 20 20 20.3 18.9 101 95 60-140 7 Dichlorodifiuoromethane uglL NO 20 20 16-9 16.8 85 84 60-140 1 Diisopropyl ether uglL ND 20 20 20.9 20.2 105 101 60-140 4 Ethylbenzene ug1L 1-6 20 20 22.9 22.3 106 104 60-140 2 Hexachloro-1,3-buladiene uglL NO 20 20 20.3 20.1 102 101 60-140 1 Isopropylbenzene (Cumene) uglL 3.5 20 2❑ 24-7 24-3 106 104 60-140 2 m&p-Xylene uglL 1.9 40 40 44.9 43.3 107 103 60-440 4 Methyl-terl-butyl ether uglL 148 20 20 144 148 -18 0 60-140 2 M1 Methylene Chloride uglL ND 20 20 18-5 18.1 92 91 60-140 2 Results presented on this page are In the snits indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date- 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC Page 40 of 48 aceAnaiXicai"; xwwpacslahs=rn QUALITY CONTROL DATA Project: Carl's Country Stare Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersvilie, NO 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2655709 MS 92441209004 Spike Parameter Units Result Conc. MSD Spike Conc. 2655710 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual n-Butylbenzene uglL 1.1 20 20 20.4 20.0 97 95 60-140 2 n-Propylbenzerie ug1L ND 20 20 23.2 22.3 116 112 60-140 4 Naphthalene ug1L 34.6 20 20 52.4 59.6 89 125 60-140 13 o-Xylene ug1L ND 20 20 21.9 21.3 107 104 60-140 2 sec-Butylbenzene ug/L ND 20 20 23.0 21.9 115 109 60-140 5 Styrene ug/i_ ND 20 20 21.4 20-8 107 104 60-140 3 terl-Butyibenzene ug/L ND 20 20 19.0 18.3 95 91 60-140 4 Tetrachloroethene ug/L ND 20 20 21.1 20.9 106 105 60-140 1 Toluene ug/L ND 20 20 21.0 1 B.8 105 94 60-140 11 trans-1,2-Dichloroethene ug/L ND 20 20 20.3 20.0 102 100 60-140 2 trans-1,3-Dichloropropene ug/L N❑ 20 20 20.2 19.7 101 99 60-140 3 Trichloroethene ug1L NO 20 20 20.6 19.4 103 97 60-140 6 Trichlorofluoromethane uglL ND 20 20 20.3 19.2 101 96 60-140 5 Vinyl chloride ug1L NO 20 20 20.4 19.3 102 97 60-14D 5 1,2-01chloroeihane-d4 (S) % 94 98 70-130 4-Bromofluorobenzene (S) % 99 98 70-130 Toluene -dB (S) % 99 99 70-130 Results presented an this page are in tha unfts Indicated by She "Units" column except where an alternate unit is presented to the right of She result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 09/09/2019 12:28 PM without the wtitten consent of Pace Analytical Services, LLC Page 41 of 48 Pace Analytical Services, LLC ® 9800 Kincey Ave. Suite 100 aceAnalytical Huniersville, NC 26078 www.pacambs.com 1704j875-9092 QUALIFIERS Project: Carl's Country Store Pace Project No.: 92441209 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL-Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirernents for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unfounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 82$0. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is T N I accredited. Contact your Pace PM for the current list of accredited analytes. l��f a1 r'..7iFl gLi�lfi�f if i1iC� IW.II*i7:7.Iita] IW PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS C9 Common Laboratory Contaminant. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits_ Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Dale: 09/09/2019 12:28 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 48 aceAnalytical rnrwpacelaas.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Carl's Country Store Pace Project No.: 92441209 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample Id QC Batch Method QC Batch Analytical Method 92441209001 MW-1 SM 6200B 492314 92441209002 MW-2 SM 6200E 492595 92441209003 MW-4 SM 6200B 492595 92441209004 MW-5 SM 6200B 492595 92441209005 MW-6 SM 6200B 492314 92441209006 MW-7 SM 62003 492314 92441209007 MW-9 SM 6200B 492314 92441209008 MW10 SM 520013 492314 92441209009 ❑MW-1 SM 6200B 492314 92441209010 DMW-3 SM 6200B 492314 92441209011 DMW-4 SM 6200B 492314 92441209012 DMW-5 SM 6200B 492314 92441209013 WSW-9 SM 6200B 492314 92441209014 Trip Blank SM 6200B 492314 Date: 09/09/2019 12:28 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without [he written consent of Pace AnaiyticaI Services, LLC Analytical Batch Page 43 of 48 0Deument Name: uacunrei ti PIC-3 — - , . , _---- C sample Condition Upon Recelpt(5CUR) Page 1 of 2 aceMalyfrcal Document No,; Issuing Authority: F-CAR•CS•033-Rev,06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Hunterstrille j��nn Raleei�igh❑/a� /a� Mechanicsville[] CAentName: WV# • ■ 2441209 Upon Ri!4:eipt�Project #: Laurier: PF50 Ex ❑UPs OUSPS ❑Client ❑ Commercial Lwace ❑Either: 92441209 Custody Seal Present? ❑Yes L.%o Seals Intact? ❑Yes EKI Racking Material: ❑Bubble Wrap EBuhble Bags []None ❑ Other Thermometer F,.,r/WE R Gun 10: 92TO48 Type of rce: ]wet ❑Blue Cooler Temp ('C): ' Correctlon Factor: AddJSubtract (°C) 0,0 Cooler Temp Corrected ('C):9 F OP/1 L1117 USDA Regulated 5oll ( N/A, yjater sampte) Did samples,arigi to in a quarantine zone within the United 5.tates: CA, NY, or SC (check maps)? ❑Yes No 0ase/in4lals Penon Examinfns Contents: 8Ioioglcal Tissue F en? ❑Nme ❑Yes ❑Na N/A Te nTPOuld be above freezing to VC Samples out of temp criteria. Samples an Ice, cooling process harbegun old samples orfginMe from a Foreign soatce (interna natty, Includngllawaii and Pueno RIto)? ❑Yes GINO • CommentflDissrepancy: Chaln of Cuitady Present? es ON ❑N/A 1. Sarttples Arrived within Hold Time? - es ❑No ❑NJA 2. short Hold -Time Analysis (e72 hr.)? Yes No ❑NIA 3. Rush TJrnAround Time Requested? ❑vcs C&JNa ❑r!/A 4. sufocient Volume? Yes ❑No ❑NI,% S. Correct Containers Used? LJYe []No ❑rr/A 6. -Pace Containers Used? [9fes ❑No ❑N/A Containers Intact? e5 Ne _ nN/A 7. Dissolved analysis: 5amptes Field Fri tered7 QYe [IN* N/A 9- Sample Labels Match CDC? es ❑No ❑NIA 9. -Includes Date/Time/lB/Analysis Matrix: HPad space in VDA Vials (>5.6mm)? Y s Elko ❑N/A 10. Trip fiiank Present? OeS [:]No ❑NIA 11. Trip Blank CustodySeais present? No QN/A COMMENTS/SAMPLE DISCREPANCY Lot 111 oft Atton talners: Field Data Required? []Yes []NO CLIENT NOTiFI{AT ON/RESCIL ON s Person contacted: 1+ l 11 J Y��� DateJT7me: r Project Manager SCURF Review; Data; / q ` GI Project iUianager 5RF Review: Date: C) Page 44 of 48 eAn�lytr+;a�� Condition Upon Recelpt(a[.un) Document No.: Issuing Authority: F-CAR-05.433 Rev.g6 Pace Carolinas Ruallty ❑ffice 1 2 3 4 6 7 9 9 30 ].1 12 *Check mark top half of box if pH and/or dechlor€nation Is ►rerifled and within the acceptance range for preservat!on samples. Exceptions: VDA, Coliform, TOC, 011 and Grease, ❑ROJ9015 (water) DOC, UKg " Bottom half of box is to fist number of bottle Project # WO# , 92441209 M AP flue Date: 08/22/19 CLIENT: 92-Shield �Ye y c V R D a M 47 N y C V S 7 4 a7 W a V L1 a m p a ' m d m Y 6 yO ry LJ a m V n 2 �+ 4 x oR'. oD Z If y Y 6 N a m R a 4 V R V a m '0 c 3 u C 4 a Q .� i ,7a l7 Q V u �[ V .d. y :. l7 Q Z E J C1 n [7 G V U n ,�, ti � t9 ¢ i v ¢ 61 Q 4 N - G a T 2 E ❑� N Rat l7 Q ? 2 > E Y 0 C 2 q x Q Q Y aF+ l4 7 2 ] D `! rn 0 7 x (] L 0 S i 3 D u7 6 n •7 a ❑ 7 73 G N '7 y � � ? a u y � �n N �n E p �n ry 2 ac G 0 ry m 4 Z d 7 4 J P � Q ~ J 4 r' � 7 a �I c E Q O r7 0 (.Cf (f� 7 1 i PH Adjustment Log for Preserved Samples Sample 10 7ype of Preservative pH upon receipt Date preser iatlon adlusted Time preservatlon Amounr of Preservative Lot H adluned ridded Note: Wheneverthere is a dlscrapancy affecting North Carolina compliance samples, a copy of this form will be seat to the North Carolina D&fNR Cenlficavon Office `i.e, put of hold, incarrectprpservative, oat of temp, incorrea containers. Page 45 of 48 Sample Condition Upon Retelpt{ILUnl ����jY� «�j • Document No.: issuing Authority: F-CM-CS-033•Rev.46 pace Carolinas Quality Office 'Check mark top half of box if pH and/or dechlorination Is Project # verified and wit hln the acceptance range for preservation samples. Exceptions: VOA, CoIiform, TOC, 011 and Grease, ❑R0/9015 (water) DoC, LLHg *'©ottom half of box is to list number of bottle u - a V E m 4 a E m a N a E m °e+ A. m a u a E a. m p M J E m `,�. w a E m a x❑ r Q E m 5 y ;d M E LL m a M a Q a nEE Q ~ 3 d 0. W rz !r) l7 a a M ! L7 a a D 'o d E {� 5:J a 2 C7 m ¢ i7 ¢ U Q O E pipg� l7 C M Q q E F L7 C O E ' U' n d M 0 E IL L7 a s Y ❑ n C n a Y ; a z J 6 n ? ❑. R 1 � 1K K K 1"l 2 3 4 S 5 7 8 9 1D I1 12 N z r• z � R � m i —° of V v eeq m n ry li � V y � E c Qj an 4 E E E E a ry q a At v� m a a o pH Adjustment Log for Preserved Samples Sample la Type of Preservative pH upon recelpt Date preservatlon adjusted Time preservt+tlon Amount of Preservative adjurted I added Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a Copy of this form will to sent to the North Carollna DFHNR CertircatiOn 0 u t of hold, incorrectpreservative, out of temp, Incorrect con talners. Lot Page 46 of 48 8ti;O Lti abed V F (NIA) ��- peluf safdweS • Sy `" (NIA rapa0 f pafeas •�� 1` j C' V A olsn �N1A} G a o u) o Lu n q i �- uo pama*88 r � (NIA) aw, ojg0p;nplswe a ry o N au!dWgl a � o 77— h � L li -C ` �{� til N n O t � of N � p y W o DOZs 3Qn ;.W() S' 1Puey13 OOZ7 JOA x x x x x x x x x x x x - n cf N9, ISa1 sasAleuy m cm R ? ', U n Y jou"Jayy m 2 d HOuN E O K e of H H H 7 IOH 1 m m S CONH d V m = d N, 9 G CGSZH W 0 pacasaidurl ❑ a d O cc NOI10JMO 1V d1'13131d lWS led La F ZW4N iB Vj q w w C L c- F w E w 0IrF rr7 a W a U U U w F V 1 d N T a N C, P L U O G r C� T "^�����•• E (dPiO:) I tlV'dD D) ddAL aIdRVS ' ij c Ilfol of saro�pilen aas� 30e)7 %Iu1VlY m v � R o v ❑ Vj cc fL 6 0. R 2 y e f _ F 6 U CI 7 N x Cr w o P w 'J a [[ y C n C w e N J Qcr QM ae Y _ N s_❑ q E °ft r o Q C7 E ¢ a C v r� m N o # W311r�- al qEq 8h P 8h afied O Ur iN�Ar _ IDe}ul r"' sa!dweg r = NIA -1 F e} 'z'IDO3 v -� � (� •�� � 1 poleaS Apolsn lNfAl o A —4 h E w a Z m uo pani0378 {tJrAr awolV� i¢nplsaZl - O•+ 0 u! dW3i i c rn � W a m � 1 , � R1 • w P Q Cl— ? s a o a DOZ9 OOn x x c.Sxp g . louuVl3 r WZd p�A X x of —L• s a) C NO, P8.1 SOs leuy m G n iaulp K ID ueVla yy �+ C x 01 ip E u m CpZSUN O A m MOON 1 MH w w v [r (1" CONH ry z" Y zi 4QSZH o - r• . n p 4 a` PaVasaiduH J7 � w N01173110�iV d1113131dIW5 � � W� N N F e-b � 13 O O w cl 51 u F W S H C (p Y P ldr4GD=-J RldS'--`3! 3dA13lJTYVS 0 � L 3 3W IN;k1 q sapm pgnx aasi 3a0G] xRilVl'1 r f r n 6 r ,i�;• � x u ii tt r y� zz i of V N V cr C ] % p � a T Steil a4 n w a v r c L U _• 6 C u1 r 6 C 37 N C n N a G a pC L c t cn - E 4F M E W 3 V N Y v� a J r Z» 4 O ? 6 N N _V --- rE