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3404_Forsyth_TownofKernersville_MSWLF_GW_FID1359133_20191007
is Data - Email CD (data loaded: Yes / No) DoGEvent #: NC DENR I I Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information _ Name of entity submitting data (laboratory, consultant, facility owner): WithersRavenel, Inc. Contact for questions about data formatting. Include data preparees name, telephone number and E-mail address: Name: Mark Brown, LG, PG, RSM Phone: 336.605.3099 (p) / 919.608.4582 (c) E-mail: mbrown@withersravenel.com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Town of Kernersville Landfill Freeman Road 34-04 .0500 July 24, 2019 Kemersville, NC 27284 Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring X❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Groundwater monitoring data from private water supply wells ❑ Leachate monitoring data Surface water monitoring data ❑ Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? RNo. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Mark Brown, LG, PG, RSM Senior Geologist 336.605.3009 Name (Print) Title (Area Code) Telephone Number October 7, 2019 Signature / Date 424 Gallimore Dairy Road, Suite C, Greensboro, NC 27409 Facility Representative Address Affix NC Licensed/ Pr9fessional Geologist Seal .��4y````1��'•u�N EAL C-082 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 612009 _%0 WithersRavenel Our People. Your Success. October 7, 2019 Ms. Jaclynne Drummond Compliance Hydrogeologist NC Department of Environment and Natural Resources Division of Waste Management -Solid Waste Section 2090 US Highway 70 Swannanoa, NC 28778 RE: July 2019 Water Quality Monitoring Report Town of Kernersville Landfill, Permit No. 34-04 Forsyth County, North Carolina WR Project No. 06140180.33 Dear Ms. Drummond: On behalf of the Town of Kernersville, WithersRavenel appreciates the opportunity to submit the attached July 2019 Water Quality Monitoring Report for the Town of Kernersville Closed Landfill, Permit No. 34-04. The attached report contains electronic versions of the complete report, appendices for the July 2019 sampling event, and historic data from the semiannual sampling event performed January 2019. Also attached is the North Carolina Environmental Monitoring Reporting Form for the July 2019 monitoring event. Please contact me at lelliott@withersravenel.com with comments, questions or requests. Sincerely WithersRavenel Laura R. Elliott, PG Project Geologist Attachment C: Thad Buck -Town of Kernersville, Solid Waste Superintendent 424 Gallimore Dairy Road, Suite C I Greensboro, NC 27409 t: 336.605.3009 1 f: 919.467.6008 1 www.withersravenel.com I License No. C-0832 Asheville I Cary I Greensboro I Pittsboro I Raleigh I Wilmington ■■ WithersRavenei 40 Our People. Your Success. JULY 2019 WATER QUALITY MONITORING REPORT Town of Kernersville Closed Landfill 9900 Freeman Road Kernersville, Forsyth County, North Carolina NCDEQ Permit ID #: 34-04 Prepared for: Town of Kernersville Public Works Department PO Box 728 Kernersville, North Carolina 27285 Prepared By: WithersRavenei, Inc. 424 Gallimore Dairy Road, Suite C Greensboro, North Carolina 27409 WR Project #: 06140180.33 October 7, 2019 • Laura R. Elliott, PG Project Geologist CARp�'% S F #fleets ��s�► Mark BrownPG, RSM Senior Geologist 4- Our People. Your Success. TABLE OF CONTENTS 1.0 INTRODUCTION............................................................................................................................ 1.1 Site Information....................................................................................................................... 1.2 Site Geology and Hydrogeology............................................................................................... 1.3 Regulatory Status..................................................................................................................... 2.0 FACILITY MONITORING PROGRAM.............................................................................................. 2.1 Groundwater Monitoring Program.......................................................................................... 2.2 Surface Water Monitoring Program........................................................................................ 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT ........................................................ 3.1 Field Services............................................................................................................................ 3.2 Quality Control......................................................................................................................... 4.0 ANALYTICAL RESULTS................................................................................................................... 4.1 Groundwater............................................................................................................................ 4.2 Surface Water.......................................................................................................................... 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION...................................................... 5.1 MNA Parameters...................................................................................................................... 5.2 Biodegradation Screening Matrix............................................................................................ 6.0 FINDINGS...................................................................................................................................... 7.0 REFERENCES................................................................................................................................. Figures Figure 1 General Location Map Figure 2 Monitoring Well Location Map Figure 3A Potentiometric Map July 2019 Figure 313 Potentiometric Map January 2019 Figure 4 Groundwater 2L/GWP Exceedances Tables Table 1 Monitoring Well Construction Details Table 2 Groundwater Surface Elevations Table 3 Historical Groundwater Elevations Table 4 Groundwater Analytical Results Table 5 Surface Water Analytical Results Table 6 Summary of MNA Constituents 1 1 1 1 2 2 2 3 3 4 4 4 5 5 5 5 6 7 Page i of i r■ . ■ Our People. Your Success. Appendices Appendix I Laboratory Analytical Reports and Field Notes Appendix II Historical Summary Tables (reproduced from Joyce Reports) Table 1A Summary of Historical Groundwater Elevations Table 1B Monitoring Well and Boring Completion Summary Table 2 Summary of Estimated Hydraulic Gradient and Linear Velocity Table 3 Summary of Historical Groundwater Constituents Table 4 Summary of Historical Surface Water Constituents Table 5 Summary of MNA Constituents Table 6 MNA Screening Matrix Page i of i r■ . ■ Our People. Your Success. 1.0 INTRODUCTION 1.1 Site Information The Town of Kernersville Landfill is a closed, unlined municipal solid waste landfill located on approximately 58.2 acres in Forsyth and Guilford Counties, NC, approximately 10 miles north of the Town of Kernersville. The waste disposal area comprises approximately 13.8 acres. Figure 1, General Location Map illustrates the general location of the landfill on top of a 7.5-minute United States Geologic Survey (USGS) topographic map for the Belews Creek, North Carolina quadrangle (quad). The facility was issued a Permit to Operate by the North Carolina Department of Waste Management (DWM) on May 15, 1985, and a Letter of Closure on December 10, 1991. The landfill is zoned residential/agricultural and is bounded on the east and west by open fields and woodlands. The landfill is bounded on the north by property owned by Waste Management and farther north by Freeman Road, and on the south by an unnamed tributary of Belews Creek. Figure 2, Water Quality Sampling Locations Map illustrates the property boundaries, waste disposal boundaries, monitoring well locations, and surface water sample locations. 1.2 Site Geology and Hydrogeology The Town of Kernersville Landfill is located in the Piedmont Physiographic Province (Piedmont) of North Carolina and is underlain by intrusive granitic rocks of Pennsylvanian -to -Permian age, which are part of the Charlotte Belt Geologic Unit. The uppermost aquifer is unconfined and includes both saprolite and fractured bedrock, which are well-connected. Groundwater at the site has historically been reported flowing generally to the southwest. Joyce Engineering (JOYCE) conducted hydraulic conductivity testing in November 2013 and, using the modified Darcy equation (V=Ki/n), reported the following: • Hydraulic gradient (i) is 0.04 ft/ft; • An effective porosity value (n) of 30 percent was estimated; • Hydraulic conductivity (K) 1.73 ft/day: and • The calculated groundwater flow rate averaged approximately 0.20 ft/day. 1.3 Regulatory Status The Town of Kernersville (Town) is currently monitoring groundwater at the landfill in accordance with criteria set forth in Title 15A Subchapter 13B .0500 of the North Carolina Solid Waste Management Rules for municipal solid waste landfills (MSWLF) closed prior to October 9, 1993. Samples are analyzed for all constituents listed in 40 CFR Part 258, Appendix I Constituents for Detection Monitoring ("Appendix I") and compared to the North Carolina Groundwater Quality Standards as listed in 15A NCAC 2L (the "2L Standards"), or, when a 2L Standard is not established, the Solid Waste Section's Groundwater Protection Standards (GWPs). Based on the presence of targeted Appendix I constituents detected at concentrations above the referenced standards that could potentially be crossing the facility boundary, the North Carolina Department of Environment and Natural Resources (NCDENR), Solid Waste Section July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 1 of 7 r■ . ■ Our People. Your Success. (Section) requested that the Town submit a Groundwater Assessment Plan to evaluate site conditions as they relate to groundwater quality. JOYCE submitted a Groundwater Assessment Report to the Section on May 13, 2013, and concluded that, based on site hydrogeology, it would be very unlikely that the site impacts at concentrations above their respective standards would cross the property boundaries. In a July 16, 2013 response to information presented in the Groundwater Assessment Report, the Section determined that, despite the conclusions presented in JOYCE's Groundwater Assessment Report, the detection of volatile organic compounds (VOCs) at concentrations that exceeded the referenced standards beyond the compliance boundary of the site constituted a violation of Section regulations. JOYCE submitted a Corrective Action Plan (CAP) on behalf of the Town in July 2014, which the Section approved on November 4, 2014. Note that the NCDENR is now doing business as the North Carolina Department of Environmental Quality (NCDEQ). 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program The current groundwater quality monitoring network consists of six monitoring wells, including one upgradient (background) well and five downgradient (compliance) wells. Monitoring well locations are illustrated on Figure 2. Monitoring well MW-6 currently serves as the background well for the facility. Former background monitoring well MW-1 was replaced (by monitoring well MW-6) due to slow recharge in the well, low well volumes, or being dry during sampling events. Downgradient monitoring wells MW-2, MW-3S, MW-3D, MW-4, and MW-5 are monitored for the Appendix I list of constituents as part of the compliance network for the facility. Monitoring well MW-1 is currently monitored for water levels only. Well construction parameters are presented in Table 1, Monitoring Well Construction Details. As a condition of the aforementioned CAP, monitoring wells MW-2, MW-3S, MW-3D, MW-4 and MW-6 are also monitored for the following Monitored Natural Attenuation (MNA) constituents; • Nitrate, sulfate, chloride, sulfide, alkalinity; • Total organic carbon (TOC); • Methane, ethane, and ethane • Biological oxygen demand (BOD) and Chemical oxygen demand (COD). Groundwater samples collected semiannually are analyzed for the Appendix I list of constituents and for the above -referenced MNA parameters. Sample analyses are then compared to the 2L Standards or GWPs, where appropriate. 2.2 Surface Water Monitoring Program Surface water at the landfill is monitored semiannually in conjunction with the groundwater sampling events. Samples are collected from three surface water monitoring points (designated SW-1, SW-2, and SW-3). Surface water sample locations are also illustrated on Figure 2. July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 2 of 7 r■ . ■ Our People. Your Success. These surface water monitoring points are summarized below, along with their current monitoring program status. Surface Water Designation SW-1 SW-2 SW-3 Classifirntinn Upstream/Compliance Compliance Compliance Surface water samples are collected and analyzed for the Appendix I list of constituents during both semiannual monitoring events. Analytical results are compared to the Classifications and Water Quality Standards Applicable to Surface Waters of NC as listed in 15A NCAC 2B (213 Standards). 3.0 GROUNDWATER AND SURFACE WATER SAMPLING EVENT 3.1 Field Services On July 24, 2019, WithersRavenel (WR) personnel returned to the facility to purge and sample monitoring wells MW-1, MW-2, MW-3S, MW-3D, MW-4, MW-5 and MW -6 and sample surface water sample locations SW-1, SW-2, and SW-3. Prior to purging each well, the depth to the static water level was measured with an electronic water level indicator accurate to 0.01- foot. Due to the lack of water encountered within the well, monitoring well MW-1 was measured for static water level only. Table 2, Groundwater Surface Elevations presents groundwater surface elevations calculated from static water levels recorded by WR personnel compared to top -of -well casing elevations reported by JOYCE in their 2015 reports. For comparison purposes, the most recent sampling event (July 2019) data are illustrated on some of the figures. Figure 3A, Potentiometric Map (July 2019) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the July 2019 sampling event. Figure 313, Potentiometric Map (January 2019) illustrates estimated groundwater flow across the landfill site based on the reported groundwater surface elevations during the January 2019 sampling event. As shown on these figures and in recent sampling events, groundwater appears to be flowing in a southwesterly direction towards an unnamed tributary of Belews Creek. Table 3, Historical Groundwater Elevations presents groundwater surface elevations reported by JOYCE between 2009 and 2015, and by WR between 2016 and 2019. The wells were purged and sampled using either disposable bailers or submersible pump. Field parameters, including temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential and turbidity, were recorded in the site -specific log book prior to purging, after each purge volume, and during sampling. Groundwater samples from each monitoring well were collected directly from a submersible pump into laboratory -cleaned and -provided containers or decanted from disposable bailers into the containers immediately after purging. Samples were then placed into laboratory -provided coolers, chilled on ice to approximately 4°C, and delivered to a State of North Carolina -certified laboratory (Pace Analytical Laboratories) under standard Chain -of -Custody (COC) protocol. Field data logs are provided in the Appendix to this report. July 2019 Water Quality Monitoring Report WR Project Number 06140180.33 Town of Kernersville Closed Landfill, Permit 34-04 October 2019 Page 3 of 7 r■ . ■ Our People. Your Success. Surface water samples were collected either directly into laboratory -provided, non -preserved sample containers, or by decanting the sample from a non -preserved 1-Liter amber glass container into the appropriate containers. In both methods, samples were collected with the container opening facing into the current flow. When used, care was taken to not overflow the preserved sample containers (which could lead to preservative loss) and avoid sample -induced turbidity. Samples were collected initially from the downstream sample location (SW-2), and in sequence upstream, SW-3 and then SW-1 samples were collected (Figure 2). After sample collection, the samples were placed in a laboratory -provided cooler, chilled on ice to approximately 4°C, and submitted to Pace Analytical Laboratories under standard COC protocol. 3.2 Quality Control One Field Blank was collected by WR personnel as part of the July 2019 sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling containers during shipment to and from the laboratory. The Field Blank was analyzed for the Appendix I list of constituents only, while the Trip Blank was analyzed for VOCs only. 4.0 ANALYTICAL RESULTS 4.1 Groundwater Groundwater samples were analyzed for the Appendix I list and the modified list of MNA constituents and compared to the respective 2L Standards or GWPs where appropriate. As shown on Table 4, Groundwater Analytical Results, the following organic and/or inorganic constituents were detected in groundwater samples during the July 2019 sampling event. All concentrations are reported in micrograms per liter (µg/L). Concentrations detected above the 2L Standard or GWPs are illustrated in bold font. Constituent Referenced Standard Compliance Wells (2L/GWP) MW-2 MW-3S MW-3D MW-4 MW-5 MW-6 Benzene 1.0 3.4 0.37 J 0.58 J <1.00 <1.00 <1.00 1,1-Dichloroethane 6.0 12.5 0.831 J 2.05 1.41 <1.00 <1.00 1,2-Dichloroethane 0.4 <1.00 <1.00 0.696 J <1.00 <1.00 <1.00 1,2-Dichloropropane 0.6 4.22 0.508 J 1.24 0.328 J <1.00 <1.00 Lead 15 <5.00 6.12 <5.00 <5.00 23.5 1.9 J Vinyl chloride 0.03 4.5 3.3 13.6 12.3 <1.00 <1.00 Vanadium 0.3 <20.0 51.8 7.4 J <20.0 12.9 J 9.14 J Figure 4, Groundwater Standard Exceedances Map illustrates exceedances to the referenced standards at the monitoring well locations. In general, the organic and inorganic results are consistent with historical data. Historical groundwater data, laboratory quality assurance/quality control information and the chain -of -custody records are included in the Appendix. July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 4 of 7 r■ . ■ Our People. Your Success. 4.2 Surface Water Surface water samples were analyzed for the Appendix I list only. No analytes were detected at concentrations above the 2B Standards in surface water samples collected during the July 2019 sampling event. The results were consistent with historical data. Surface water data can be found in Table 5, Surface Water Analytical Results. The results, as reported by the laboratory, historical surface water data, the laboratory quality/assurance/quality control information, and the chain -of -custody records are included in the Appendix. 5.0 MONITORED NATURAL ATTENUATION (MNA) EVALUATION 5.1 MNA Parameters According to previous reports, in accordance with the facility CAP, MNA baseline sampling was initiated during the November 2014 sampling event and finished during the November 2015 sampling event. During those events, the full list of MNA parameters (shown below) were measured in samples collected from monitoring wells MW-2, MW-3S, MW-3D, and MW-4. MNA field (geochemical) parameters included: • Temperature; • pH; • Specific conductance; • Oxidation-reduction potential (ORP); • Turbidity; and • Dissolved oxygen. Laboratory parameters included: • Biological Oxygen Demand (BOD); • Chemical Oxygen Demand (COD); • Dissolved hydrogen; • Nitrate; • Sulfate: • Chloride; • Alkalinity; • Sulfide; • Total Organic Carbon (TOC); • Ethane, ethene, and methane; and • Volatile fatty acids. As shown on Table 6, Summary of MNA Constituents, WR sampled for the full list of MNA parameters during the July 2019 sampling event. Laboratory reports and field data forms are included in the Appendix. 5.2 Biodegradation Screening Matrix The MNA parameter data were evaluated in general accordance with the weighted system presented in Table 2.3, Biodegradation Screening Matrix (Matrix) of the United States Environmental Protection Agency's (USEPA's) Technical Protocol for Evaluation of Natural Attenuation of Chlorinated Solvents in Groundwater (Manual), to determine whether the conditions are conducive to, or whether there is evidence of, anaerobic degradation of the chlorinated hydrocarbons. According to information presented in the Manual, July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 5 of 7 r■ . ■ Our People. Your Success. • A score less than 5 indicates that there is "inadequate evidence" for anaerobic natural attenuation; • A score of 6 to 14 indicates that there is "limited evidence" for anaerobic natural attenuation; • A score of 15 to 19 indicates that there is "adequate evidence" for anaerobic natural attenuation; and • A score of 20 or more indicates that there is "strong evidence" that anaerobic natural attenuation is occurring. The MNA evaluation was performed based on the results from the July 2019 sampling event for downgradient wells located within the contaminant plume and compared, where appropriate, to samples collected from the background well (MW-6). Because it is unclear whether some of the target analytes are naturally -occurring or daughter products resulting from natural attenuation, the scores have been calculated with and without the daughter product points. The site -specific Matrix for this sampling event is presented in the Appendix. As shown, the scores ranged from 12 to 24 (characterized as "limited evidence of natural attenuation" to "strong evidence of natural attenuation.") The mid -range (or average score of 18), indicates there is "adequate evidence of natural attenuation." 6.0 FINDINGS Target analytes detected above their respective 2L Standards and/or GWPs in groundwater samples collected during the July 2019 sampling event appear to generally be consistent with previous events. In addition, there were no target analytes detected in the surface water samples at concentrations above their respective 213 Standards. The Town of Kernersville Landfill will continue to monitor groundwater in accordance with the approved CAP. The next semiannual sampling event is tentatively scheduled for January 2020. July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 6 of 7 r■ . ■ Our People. Your Success. 7.0 REFERENCES Brown, Philip M., Chief Geologist, 1985, Geologic Map of North Carolina, The North Carolina Geologic Survey, scale 1:500,000. Joyce Engineering, Inc. Water Quality Monitoring Plan, Piedmont Landfill & Recycling Center, September 2010. -----, Second Semiannual Water Quality Monitoring Report of 2014, Town of Kernersville Landfill, Permit 34-04, March 2015. -----, Second Semiannual Water Quality Monitoring Report of 2015, Town of Kernersville Landfill, Permit 34-04, March 2016. -----, Corrective Action Evaluation Report (CAER), Town of Kernersville Landfill, Permit 34-04, October 16, 2016. North Carolina Department of Environment and Natural Resources, 2016 Solid Waste Section Guidelines for Groundwater, Soil and Surface Water Sampling. -----, MNA Excerpt from Examples of Approved Groundwater Corrective Measures for Solid Waste Management Facilities, 2008. Technical Protocol for Evaluation Natural Attenuation of Chlorinated Solvents in Groundwater, EPA/600/R-98/128, September 1998. United States Geological Survey, 7.5-Minute Quadrangle, Belews Creek, North Carolina. July 2019 Water Quality Monitoring Report Town of Kernersville Closed Landfill, Permit 34-04 WR Project Number 06140180.33 October 2019 Page 7 of 7 FIGURES A,G/— Go, �G���1GG OKF H0410 WA GRAPHIC SCALE " .."�O�-- iL loch - 1000 ft. TOWN OF KERNER VILLE DRAWN BY: SCALE: FIGURE NO.: 0- W i t h e rs Ra ve n e l CLOSED LANDFILL - PERMIT #34-04 MDF 1"=1000' 1 I / Engineers Planners GOODWILL CHURCH ROAD Surveyors KERNERSVILLE, GUILFORD/FORSYTH COUNTY, NC APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive I Cary, NC 275111 t: 919.469.33401 license #:C-08321 GENERAL LOCATION MAP SMB 10/04/2019 06140180.33 C\YWdYiell\OaYlaeV016101!_Bete ler uSM am WE MAlis - Omen 4. 2012 - EuWOTI. LAMA f'► ; , F A ` SW-2 MW-3D MW-4 MW-3S MW-2R SW-3 � MW-5 MW-6 a T`� T GOODWILL CHURCH ROAD ,... "-k LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0 GROUNDWATER MONITORING WELL G SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. 1/ WithersRavenel Engineers I Planners I Surveyors TOWN OF KERNERSVILLE CLOSED LANDFILL —PERMIT #34-04 GOODWILL CHURCH ROAD WATER QUALITY SAMPLE LOCATIONS MAP DRAWN BY: MDF SCALE: = 1"300 ' FIGURE NO.: L APPROVED BY: DATE: PROJECT NO.: 115 MacKenan Drive Cary, NC 27511 t 919.469.3340 license #: C-0832 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA SMB 10/04/2019 06140180.33 C:Utrrs�Y:e11\OuMImV0171LSl1_Bue Is IAAm- Oelrow 4. 2012 - Eli1DII. W1G GOODWILL CHURCH ROAD ROA D LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY 0- GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION I NOTES: GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. -40- 1/ I15 MacKenan WithersRavenel Engineers I Planners I Surveyors Drive Cary, NC 27511 t 919.469.3340 license #: C-0832 TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA POTENTIOMETRIC MAP (JULY 2019) DRAWN BY: LRE SCALE: 1"=300' FIGURE NO.: 3A APPROVED BY: SMB DATE: 10/03/2019 PROJECT NO.: 06140180.33 I&XI4X14-0100N14018O33-Sm 833 Lmtlli S—km rVE 2070%Emkokll mlf O Dtltw %*O Evenl J 3019V0190918_0ete. - Ocl 4. 2012 - EuIOII. WFA 'P F� �q ti WithersRavenel 1/ Engineers I Planners I Surveyors 115 Ma,Kenan Drive I Cary, NC 275111 t 919,469.33401 license #: C-0832 � L c. ' -dir TOWN OF KERNERSVILLE CLOSED LANDFILL - PERMIT #34-04 GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA s , �T GOODWILL CHURCH ROAD ,... POTENTIOMETRIC MAP (JANUARY 2019) LEGEND FACILITY BOUNDARY WASTE DISPOSAL BOUNDARY ,Ii� GROUNDWATER MONITORING WELL (761.96) GROUNDWATER SURFACE ELEVATION GROUNDWATER SURFACE ELEVATION CONTOUR ESTIMATED GROUNDWATER FLOW DIRECTION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) NA = NOT APPLICABLE GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWN BY: SCALE: FIGURE NO.: JSc 1"=300' 3113 APPROVED BY: DATE: PROJECT NO.: SMB 02/04/2019 06140180.33 lai 13- Ocl 4. 2012 - EUIDII. WFA GOODWILL CHURCH ROAD AN LEGEND /y MW-3D JAN 2019 DULY 2019 I 1,2-DICHLOROETHANE <0.24 0.696 J FACILITY BOUNDARY 1,2-DICHLOROPROPANE <0.27 1.24 /Q VINYL CHLORIDE 12.6 13.6 O A ' VANADIUM 3.3 J 7.4 J WASTE DISPOSAL BOUNDARY I - MW-6 JAN2019 JULY2019 MW-4 JAN 2019 JULY 2019 VINYLCHLORIDE 10.9 12.3 SW-2 MW-3S JAN 2019 JULY 2019 CADMIUM <0.50 2.94 1,2-DICHLOROETHANE <0.24 <1.0 VANADIUM <2.5 51.8 VINYL CHLORIDE 2.6 3.3 SW-3 Q MW-2 JAN 2019 JULY 2019 BENZENE 3.5 3.4 1,1-DICHLOROETHANE 12.5 12.5 1,2-DICHLOROPROPANE <0.27 4.22 TRICHLOROETHENE 2.2 2.76 TETRACHLOROETHENE <0.46 0.641 J VINYLCHLORIDE 4.2 4.5 <2.5 9.14 J 0 SHALLOW MONITORING WELL h Mw-1 I I ® DEEP MONITORING WELL (NOT SAMPLED) Q SURFACE WATER SAMPLE LOCATION NOTES: 1.) 2014 AERIAL OBTAINED FROM FORSYTH COUNTY GIS DEPARTMENT 2.) PARCEL INFORMATION OBTAINED FROM GUILFORD AND FORSYTH COUNTY GIS DEPARTMENTS. 3.) ONLY ANALYTICAL RESULTS THAT EXCEEDED THE 2L STANDARD DURING A SAMPLING EVENT ARE ILLUSTRATED. 4.) FOR WELLS FROM WHICH DUPLICATE SAMPLES WERE COLLECTED, THE HIGHEST DETECTED CONCENTRATION OF EACH CONTAMINANT IS SHOWN. 5). DATA ARE PRESENTED IN ug/L; J = ESTIMATED CONCENTRATION ABOVE THE ADJUSTED METHOD DETECTION LIMIT AND BELOW THE ADJUSTED REPORTING LIMITS. GRAPHIC SCALE 0 150 300 600 1 inch = 300 ft. DRAWNY SCALE: FIGURE NO.: WithersRavenel TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT#34-04 LRE 41"=300' GROUNDWATER 2L STANDARD EXCEEDANCES MAP APPROVED BY: DATE: PROJECT NO.: Engineers I Planners I Surveyors GOODWILL CHURCH ROAD KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA SMB 09/19/2019 06140180.33 11,MacKenanIM-I Cary, NC 275111 t: 919,469.3340 1 11-se #: C-08321 *XI4%l4-0IWlLI40IWM-Sm 833 La Al S-ka ClE 2020%E,,*a%R�m e Dsra %00 Evan . 2019V01901118_0-r - Ocm 4. 2012 - EwOII. MR& TABLES TABLE 1 MONITORING WELL CONSTRUCTION DETAILS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Well ID Date Installed Well Casing Diameter (Inches) Casing Depth (ft-bTOC) Screen Interval (ft-bTOC) Total Depth (ft-bTOC) Top of Casing Elevation (feet above MSL) MW-1 Not Listed 2 24.96 24.96 - 34.96 34.96 806.42 MW-2R Not Listed 2 3.18 3.18 - 13.18 13.18 762.19 MW-3S Not Listed 2 14.00 14.00 - 24.00 24.00 764.57 MW-3D Not Listed 2 36.96 36.96 - 56.96 56.96 764.56 MW-4 Not Listed 2 4.40 4.40 - 14.40 14.40 760.26 MW-5 Not Listed 2 6.36 6.36 - 11.36 11.36 773.32 MW-6 Not Listed 2 10.46 10.46 - 20.46 20.46 804.87 Notes: 1) ft-bTOC = Feet below top of casing 2) MSL = Mean sea level Data, including "Top of Casing Elevation", reproduced from Second Semiannual Water Quality Monitoring 3) Report of 2014; Joyce Engineering; March 10, 2015. 1 of 15 TABLE 2 GROUNDWATER SURFACE ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 7/24/2019 GROUNDWATER SCREENED TOP OF CASING DEPTH WELL ID INTERVAL ELEVATION SURFACE (ft-bTOC) (feet above MSL) WATERR ELEVATION (ft-bTOC) (feet above MSL) MW-1 24.96 - 34.96 806.42 DRY MW-21R 3.18 - 13.18 762.19 3.40 758.79 MW-3S 14.00 - 24.00 764.57 13.96 750.61 MW-31D 36.96 - 56.96 764.56 11.86 752.70 MW-4 4.40 - 14.40 760.26 5.89 754.37 MW-5 6.36 - 11.36 773.32 4.03 769.29 MW-6 10.46 - 20.46 804.87 16.51 788.36 Notes: 1) All measurements are in feet. 2) Elevation data is measured in feet above Mean Sea Level (MSL). 3) Depth to water measured in feet below top of casing (ft-bTOC) 4) "Screened Interval" and "Top of Casing Elevation" components are reproduced from Second Semiannual Water Quality Monitoring Report of 2014; Joyce Engineering; March 10, 2015. 2of15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-1 806.42 12/30/2009 33.97 772.45 6/1/2010 32.97 773.45 11/16/2010 32.87 773.55 12/29/2010 33.13 773.29 6/29/2011 33.32 773.10 11/1/2011 34.50 771.92 5/1/2012 34.54 771.88 11/7/2012 34.77 771.65 5/9/2013 36.47 769.95 11/7/2013 34.96 771.46 6/5/2014 34.20 772.22 11/20/2014 34.69 771.73 7/29/2016 33.91 772.51 12/21/2016 34.47 771.95 9/13/2017 DRY DRY 7/10/2018 DRY DRY 1/9/2019 DRY DRY 7/24/2019 DRY DRY MW-2R 762.19 12/30/2009 3.03 759.16 6/1/2010 3.29 758.90 11/16/2010 3.05 759.14 12/29/2010 3.36 758.83 6/29/2011 3.81 758.38 11/1/2011 3.70 758.49 5/1/2012 3.65 758.54 11/7/2012 3.99 758.20 5/9/2013 2.99 759.20 11/7/2013 4.10 758.09 6/5/2014 3.74 758.45 11/20/2014 4.11 758.08 7/29/2016 4.01 758.18 12/21/2016 3.85 758.34 9/13/2017 4.22 757.97 7/10/2018 4.41 757.78 1/9/2019 2.84 759.35 7/24/2019 3.40 758.79 MW-3S 764.57 12/30/2009 13.03 751.54 6/1/2010 13.81 750.76 11/16/2010 13.59 750.98 12/29/2010 14.75 749.82 6/29/2011 14.03 750.54 11/1/2011 9.84 754.73 5/1/2012 13.71 750.86 11/7/2012 14.27 750.30 5/9/2013 12.05 752.52 11/7/2013 14.45 750.12 6/5/2014 13.90 750.67 11/20/2014 14.33 750.24 7/29/2016 14.04 750.53 12/21/2016 14.00 750.57 9/13/2017 14.29 750.28 7/10/2018 15.00 749.57 1/10/2019 12.50 752.07 7/24/2019 13.96 750.61 Notes: All measurements are in feet. Elevation data is relative to Mean Sea Level. Depth to water measured in feet below top of casing. NM = Not Measured NA = Not Applicable NS = Not surveyed 3 of 15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL I»:7u1If'fficyIS1LI KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-3D 764.56 12/30/2009 11.77 752.79 6/1/2010 11.93 752.63 11/16/2010 11.97 752.59 12/29/2010 12.11 752.45 6/29/2011 12.40 752.16 11/1/2011 12.66 751.90 5/1/2012 12.22 752.34 11/7/2012 12.95 751.61 5/9/2013 11.32 753.24 11/7/2013 13.06 751.50 6/5/2014 12.42 752.14 11/20/2014 13.03 751.53 7/29/2016 12.32 752.24 12/21/2016 12.46 752.10 9/13/2017 12.96 751.60 7/10/2018 15.00 749.56 1/10/2019 11.25 753.31 7/24/2019 11.86 752.70 MW-4 760.26 12/30/2009 5.93 754.33 6/1/2010 6.36 753.90 11/16/2010 6.52 753.74 12/29/2010 6.58 753.68 6/29/2011 6.85 753.41 11/1/2011 7.18 753.08 5/1/2012 6.71 753.55 11/7/2012 7.39 752.87 5/9/2013 5.82 754.44 11/7/2013 7.47 752.79 6/5/2014 6.90 753.36 11/20/2014 7.45 752.81 7/29/2016 7.00 753.26 12/21/2016 7.00 753.26 9/13/2017 7.33 752.93 7/10/2018 7.00 753.26 1/9/2019 5.24 755.02 7/24/2019 5.89 754.37 Notes: All measurements are in feet. Elevation data is relative to Mean Sea Level. Depth to water measured in feet below top of casing. NM = Not Measured NA = Not Applicable NS = Not surveyed 4of15 TABLE 3 HISTORICAL GROUNDWATER ELEVATIONS TOWN OF KERNERSVILLE CLOSED LANDFILL I»:7u1If'fficyIS1LI KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 WELL ID Top of Casing Elevation (feet) Date Depth to Groundwater (feet) Groundwater Elevation (feet) MW-5 773.32 12/30/2009 4.11 769.21 6/1/2010 3.63 769.69 11/16/2010 3.51 769.81 12/29/2010 3.76 769.56 6/29/2011 3.59 769.73 11/1/2011 3.69 769.63 5/1/2012 3.77 769.55 11/7/2012 4.75 768.57 5/9/2013 NM NM 11/7/2013 5.19 768.13 6/5/2014 4.75 768.57 11/20/2014 4.09 769.23 7/29/2016 11.36 761.96 12/21/2016 3.41 769.91 9/14/2017 5.48 767.84 7/10/2018 NM NM 1/10/2019 10.50 762.82 7/24/2019 4.03 769.29 MW-6 804.87 12/30/2009 18.21 786.66 6/1/2010 16.55 788.32 11/16/2010 16.94 787.93 12/29/2010 17.50 787.37 6/29/2011 18.06 786.81 11/1/2011 19.77 785.10 5/1/2012 19.55 785.32 11/7/2012 DRY DRY 5/9/2013 17.31 787.56 11/7/2013 DRY DRY 6/5/2014 19.03 785.84 11/20/2014 20.46 784.41 7/29/2016 20.46 784.41 12/21/2016 20.22 784.65 9/14/2017 20.64 784.23 7/10/2018 DRY DRY 1/9/2019 17.49 787.38 7/24/2019 16.51 788.36 Notes: All measurements are in feet. Elevation data is relative to Mean Sea Level. Depth to water measured in feet below top of casing. NM = Not Measured NA = Not Applicable NS = Not surveyed 5of15 TABLE 7 GROUNDWATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.24 Analytical Method EPA 6010 Contaminant Of Concern E ++ Q N Q 'i GO E _ co E -a U E E U c U fl. Q U -JZ U .2 W (n > in E • H E > C N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/24/2019 NOT SAMPLED (DRY WELL) MW-2 7/24/2019 <10.0 <10.0 245 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 <20.0 10.2 J MW-3S 7/24/2019 <10.0 <10.0 208 <2.00 2.94 4.69 J 9.6 J 16.9 6.120 5.4 J <10.0 <5.0 <10.0 51.8 592.0 MW-3D 7/24/2019 <10.0 <10.0 44 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 7.4 J <50 MW-4 7/24/2019 <10.0 <10.0 92.7 <2.00 <2.00 1.42 J <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 <20.0 5.9 J MW-5 7/24/2019 <10.0 <10.0 108 <2.00 <2.00 <10.0 7.2 J 11.0 23.5 <10.0 <10.0 <5.0 <10.0 1 12.9 J 45.3 J MW-6 7/24/2019 <10.0 <10.0 51.3 <2.00 <2.00 <10.0 <10.0 <10.0 1.9 1 <10.0 <10.0 <5.0 <10.0 9.14 1 <50 Trip Blank 7/24/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Field Blank 7/24/2019 <10.0 1 <10.0 <2.5 1 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.0 <10.0 <20.00 1 <50 2L Standard/GWP (µg/L) 131 10 700 1 4 3 2 10 13 1,000 15 100 20 20 0.2 0.3 3 1,000 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. 7) Cobalt and Thallium were analyzed by EPA Method 6020B. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 6 of 15 TABLE 7 GROUNDWATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.24 Analytical Method EPA 8260 a� t s � Y o Contaminant Of Concern E LU W L v V C o L E ++ !A +JU. cC E OO t u p O E O c 'i3 +O+ O +�+ O � N O E O E O E O E M 0 O O O O O o +0+ u >. o 0 0 o m Q Q m m m m m (V U U U s U U CAS # 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/24/2019 NOT SAMPLED (DRY WELL) MW-2 7/24/2019 <50 <10 3.4 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 <5.00 <5.00 MW-3S 7/24/2019 10.8 1 <10 0.37 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 1.2 0.71 J <5.00 MW-31D 7/24/2019 <50 <10 0.58 J <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 0.44 1 0.797 J <5.00 MW-4 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 0.875 1 <5.00 MW-5 7/24/2019 <50 <10 I <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 <5.00 <5.00 MW-6 1 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 <5.00 <5.00 Trip Blank 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 <5.00 <5.00 Field Blank 7/24/2019 <50 <10 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.2 <1.00 <1.00 <5.00 <5.00 2L Standard/GWP (µg/L) 6,000 NE 1 1 0.6 a 0.6 4 100 4,000 1 700 0.3 50 3,000 70 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 7 of 15 TABLE 7 GROUNDWATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.24 Analytical Method EPA 8260 a� c a � 0 c O O � �1 ,, O O N W i C 1 O C C C ++ O Contaminant Of Concern �, u E N N O s t o 0 M O L u W W W O s u +�+ E t E O O O O 0 o O U. O O u O E O O s t 1 NT s t t 0 N O E E u u u u u 1 O t 1 N 1 N -2 1 N 1 c6 1 1 N 1 tip cC U 0 + 'u CAS # 74-87-3 96-12-8 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/24/2019 NOT SAMPLED (DRY WELL) MW-2 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 4.04 1.03 12.5 <1.00 <1.00 28.7 1.03 MW-3S 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 1.56 <1.0 0.831 J <1.00 <1.00 3.81 <1.00 MW-31D 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 3.95 <1.0 2.05 0.696 1 <1.00 23.4 <1.00 MW-4 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 2.12 <1.0 1.41 <1.00 <1.00 13.3 <1.00 MW-5 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 MW-6 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 Trip Blank 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 Field Blank 7/24/2019 <2.5 <5.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.0 <1.00 <1.00 <1.00 <1.00 <1.00 2L Standard/GWP (µg/L) 3 0.04 0.4 0.02 70 20 6 NE 6 0.4 7 70 100 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 8 of 15 TABLE 7 GROUNDWATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.24 Analytical Method EPA 8260 Y m O sz O ca ca Q- O M o a O a O op- O Contaminant Of Concern o o O o c s t Q O O O Q- co ca G u O N O Cn C O s C O p O U � �; X O E � O C CV N U C CU r� !� O O r-I CV O N r-I U 4-& W (n r-I r-I CAS # 78-87-5 10061-01-5 10061-02-6 100-41-4 591-78-6 74-88-4 75-09-2 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/24/2019 NOT SAMPLED (DRY WELL) MW-2 7/24/2019 4.22 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 0.641 J <1.00 MW-3S 7/24/2019 0.508 J <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 MW-31D 7/24/2019 1.24 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 MW-4 7/24/2019 0.328 J <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 MW-5 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 MW-6 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 Trip Blank 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 Field Blank 7/24/2019 1 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 2L Standard/GWP (µg/L) 0.6 0.4 0.4 600 40 NE 5 100 70 1 0.2 0.7 600 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. C9= Common Laboratory Contaminant Page 9 of 15 TABLE 7 GROUNDWATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE PERMIT # 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.24 Analytical Method EPA 8260 o Contaminant Of Concern t o t o a 0 0 o c s o o o +; M U u 2 O s •L o o H H o .0 H u a� N _o t U s t� M Cq C C ri r-i H H i > X CAS # 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-1 7/24/2019 NOT SAMPLED (DRY WELL) MW-2 7/24/2019 <1.00 <1.00 2.76 <5.00 <2.50 <1.00 4.5 <3.00 MW-3S 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 3.3 <3.00 MW-3D 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 13.6 <3.00 MW-4 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 12.3 <3.00 MW-5 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 MW-6 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 Trip Blank 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 Field Blank 7/24/2019 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 2L Standard/GWP (µg/L) 200 0.6 3 2,000 0.005 88 0.03 500 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) Interim Maximum Allowable Concentration (IMAC) 4) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 5) NE = 2L Standard or GWP not established. A detection is considered an exceedance. 6) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers NA Not Analyzed by Method Shown Result Result Exceeds 2L Standard or GWP J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 10 of 15 TABLE 8 SURFACE WATER ANALYTICAL RESULTS (January 2019) TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 r Analytical Method EPA 6010 EPA 6010 Contaminant Of Concern >. E E E E G E u •� >_ � .E •o + fB Q *a •� - f6 U 75 i Q Q m m U U U U Z tii in H i N CAS # 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/24/2019 <10.0 <10.0 36.9 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.00 <10.0 8.02 J <50 SW-2 7/24/2019 <10.0 <10.0 38.4 <2.00 <2.00 <10.0 <10.0 <10.0 <5.00 <10.0 <10.0 <5.00 <10.0 5.97 J <50 SW-3 7/24/2019 <10.0 <10.0 38.7 <2.00 <2.00 <10.0 <10.0 <10.0 2.24 J <10.0 <10.0 <5.00 <10.0 6.81 J <50 2B Standard (µ /L) NE 10 1,000 65.0 0.82 183 NE 3.6 13.88 145 5 0.30 NE NE 1 36 Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 213 Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. * Hardness -Dependent 15A NCAC 02B Water Quality Standard, Calculated with default in -stream hardness of 25 mg/L NA Not Analyzed by Method Shown Result Result Exceeds 213 Standard Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 11 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 r Analytical Method EPA 8260 a� c ra Q. O a� o Contaminant Of Concern E a, '-'-' a, M E c ? ; u c •' o t E c (a E E O + � O � s U u "O p � O O � 'i3 +; N � +-+ O C � O � G +' O �. O N O E O E O E O E C O C O O O O O O O O u u W O O O O m -0 -0 O s N Q Q m m m m m N M U U U U U U r-I CAS # 67-64-1 107-13-1 71-43-2 74-97-5 75-27-4 75-25-2 74-83-9 78-93-3 75-15-0 56-23-5 108-90-7 75-00-3 67-66-3 74-87-3 96-12-8 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 SW-2 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 SW-3 7/24/2019 <50.0 <10.0 <1.00 <1.00 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <5.00 <5.00 <2.50 <5.00 2B Standard (µ /L) NE NE 1.19 NE NE NE NE NE NE 0.254 488 NE NE NE NE Notes: 1) All results provided in µg& (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 12 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 r Analytical Method EPA 8260 a� c � t LU O O N (D GCJ a) 4-a GJ C Q. a 0 +, O N C C N I O O O t O 0 C O a 0 Contaminant Of Concern E s N c f6 t fC s t W O c a O a O o u O O O O u a O u t E O E O O O O Q O O O O O O u Q O O Q u O 0 O s t t t t 0 N t M N C E 72 E u u u u u r-i u r-i N C N N ca e-� N v� co v� ca +, ri r-I -W r-I r-i r-I .0 -W r-I .0 -W W CAS # 124-48-1 106-93-4 74-95-3 95-50-1 106-46-7 110-57-6 75-34-3 107-06-2 75-35-4 156-59-2 156-60-5 78-87-5 10061-01-5 10061-02-6 100-41-4 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 SW-2 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 SW-3 7/24/2019 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 2B Standard (µ /L) NE NE NE 488 488 NE NE NE NE NE NE NE NE NE NE Notes: 1) All results provided in µg& (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 13 of 15 TABLE 5 SURFACE WATER ANALYTICAL RESULTS TOWN OF KERNERSVILLE CLOSED LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 r Analytical Method EPA 8260 EPA 8260 Y m a� c o o Q- 'a +�+ p p C +�+ O E O Contaminant Of Concern O s a O s V a� i i O 0 O o O c t 0 O O O c C C +�+ X +s+ E y �. O H N H N u 41 •i O O O _O •i U -0 s 0O ci a� C_ C c _ N G N e-i r-I r-i r-I 0 V r-i .i .i C i i X CAS # 591-78-6 74-88-4 75-09-2 108-10-1 100-42-5 630-20-6 79-34-5 127-18-4 108-88-3 71-55-6 79-00-5 79-01-6 75-69-4 96-18-4 108-05-4 75-01-4 1330-20-7 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual SW-1 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 SW-2 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 SW-3 7/24/2019 <1.00 <1.00 <5.00 <10.0 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <1.00 <5.00 <2.50 <1.00 <1.00 <3.00 2B Standard (µ /L) NE NE NE t NE NE NE NE 0.7 11 NE NE 2.5 NE NE NE 0.025 NE Notes: 1) All results provided in µg& (micrograms per liter) or parts per billion 2) 2B Standard = Classifications and Water Quality Standards Apllicable to Surface Waters and Wetlands of NC 3) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. NA Not Analyzed by Method Shown Result Result Exceeds 2B Standard Qualifiers J= Estimated concentration above the adjusted method detection limit and below the adjusted reporting limits. Page 14 of 15 TABLE 6 SUMMARY OF MNA CONSTITUENTS (JULY 2019) TOWN OF KERNERSVILLE LANDFILL PERMIT #: 34-04 KERNERSVILLE, FORSYTH COUNTY, NORTH CAROLINA WR Project # 06140180.33 Analytical Method EPA 300.0 EPA 353.2 RSK 175 SM 2320B SM 3500-Fe B SM 4500-CI-E SM 4500-S2D SM 5210B SM 5220D SM 5310B H U_ O C Contaminant Of Concern M O 'a c .o u c 0 c .�0 i M 0 .O _ .� E O U += += � 4-1 O o M o t O X O t X O 0 U 7 o ca o cn zz w w aHU = U V) 000C]m U 0 0 HUB CAS # 14808-79-8 NA 74-84-0 74-85-1 74-82-8 NA NA 16887-00-6 18496-25-8 NA NA 7440-44-0 Well ID Date Collected Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual Result Qual MW-2 7/24/2019 <5,000 80.0 J <13 <13 3,700 129,000 521 T8 9,650 <50 <2,000 K1, K6 <10,000 1,380 B MW-3S 7/24/2019 <5,000 <100 <13 <13 207 152,000 488 T8 31,300 <50 <2,000 K1, K6 10,200 1,870 B MW-3D 7/24/2019 97.5 J <100 <13 <13 590 156,000 35 J, T8 18,700 <50 <2,000 K1, K6 <10,000 1,370 B MW-4 7/24/2019 <5,000 58.1 J <13 <13 345 170,000 999 T8 17,500 <50 <2,000 K1, K6 <10,000 1,400 B MW-6 7/24/2019 4,070 J <100 <13 <13 1 27.2 17,300 J 3,160 T8 1,950 7 J <2,000 K1, K6 <10,000 1,370 B 2L Standard/GWP (µg/L) 250,000 10,0002 NE NE I NE NE 300 250,000 NE NE NE NE Notes: 1) All results provided in µg/L (micrograms per liter) or parts per billion 2) 2L Standard = North Carolina Groundwater Quality Standard as per NC Administrative Code 15A NCAC 02L 3) GWP = Solid Waste Section Groundwater Protection Standard when a 2L Standard not established 4) NE = Not Established 5) Chemical Abstract Service (CAS) Registry Numbers shown for compounds detected. Qualifiers: K1 = The sample dilutions set-up for the BOD-CBOD analysis did not meet the oxygen depletion criteria of at least 2mg/L. Reported result is an estimated value. K6 = Glucose/glutamic acid BOD/CBOD was below method acceptance criteria. J = Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit T8 = Sample(s) received past/too close to holding time expiration. B = The sample analyte is found in the associated blank. APPENDIX I Laboratory Analytical Reports and Field Notes qaceAnalXical o ANALYTICAL REPORT National Center for Testing & Innovation August 05, 2019 Withers & Ravenel Eng. - Standard Sample Delivery Group: L1122118 Samples Received: 07/25/2019 Project Number: 06140180.24 Description: Kernersville Landfill Report To: Laura Elliott 115 MacKenan Drive Cary, NC 27511 Entire Report Reviewed By: 4�41 Heather J Wagner Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace Analytical National is performed per guidance provided in laboratory standard operating procedures ENV-SOP-MTJL-0067 and ENV-SOP-MTJL-0068. Where sampling conducted by the customer, results relate to the accuracy of the information provided, and as the samples are received. JEW ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 1 of 55 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page 1 Fn Tc: Table of Contents 2 Ss: Sample Summary 3 Cn: Case Narrative 6 Sr: Sample Results 7 FS MW-2R L1122118-01 7 [Cn] MW-3S L1122118-02 10 MW-31D L1122118-03 13 FSr MW-4 L1122118-04 16 MW-5 L1122118-05 19 RC MW-6 L1122118-06 21 �GI SW-1 L1122118-07 24 SW-2 L1122118-08 26 rAl SW-3 L1122118-09 28 EB L1122118-10 30 FSC TRIP BLANK L1122118-11 32 Qc: Quality Control Summary 34 Wet Chemistry by Method 2320 B-2011 34 Wet Chemistry by Method 3500Fe B-2011 35 Wet Chemistry by Method 410.4 36 Wet Chemistry by Method 4500S2 D-2011 37 Wet Chemistry by Method 5210 B-2011 38 Wet Chemistry by Method 9056A 40 Wet Chemistry by Method 9060A 42 Metals (ICP) by Method 6010D 43 Volatile Organic Compounds (GC) by Method RSK175 47 Volatile Organic Compounds (GC/MS) by Method 8260D 48 GI: Glossary of Terms 52 Al: Accreditations & Locations 53 Sc: Sample Chain of Custody 54 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 2 of 55 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-2R L1122118-01 GW Laura Elliott 07/24/1910:20 07/25/1908:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FC Wet Chemistry by Method 2320 B-2011 WG1318097 1 07/29/1912:44 07/29/1912:44 LEB Mt. Juliet, TN Wet Chemistry by Method 3500Fe B-2011 WG1321133 1 08/01/1915:02 08/01/1915:02 JIC Mt. Juliet, TN Wet Chemistry by Method 410.4 WG1318879 1 07/29/1910:00 07/29/1913:15 BAM Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1317178 1 07/25/1917:48 07/25/1917:48 MJA Mt. Juliet, TN Wet Chemistry by Method 5210 B-2011 WG1317316 1 07/25/1915:37 07/30/1911:17 ARM Mt. Juliet, TN [Cn Wet Chemistry by Method 9056A WG1317503 1 07/25/1918:02 07/25/1918:02 ST Mt. Juliet, TN Wet Chemistry by Method 9060A WG1318069 1 07/26/1917:46 07/26/1917:46 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1317659 1 07/25/1918:38 07/26/19 09:11 CCE Mt. Juliet, TN FSr Volatile Organic Compounds (GC) by Method RSK175 WG1318305 1 07/27/19 05:32 07/27/19 05:32 DAH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1910:08 07/27/1910:08 ZJM Mt. Juliet, TN Fc Collected by Collected date/time Received date/time F MW-3S L1122118-02 GW Laura Elliott 07/24/1910:00 07/25/1908:45 Method Batch Dilution Preparation Analysis Analyst Location FAI date/time date/time Wet Chemistry by Method 2320 B-2011 WG1318097 1 07/29/1912:50 07/29/1912:50 LEB Mt. Juliet, TN Wet Chemistry by Method 3500Fe B-2011 WG1321133 1 08/01/1915:04 08/01/1915:04 JIC Mt. Juliet, TN FSC Wet Chemistry by Method 410.4 WG1318879 1 07/29/1910:00 07/29/1913:16 BAM Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1317178 1 07/25/1917:49 07/25/1917:49 MJA Mt. Juliet, TN Wet Chemistry by Method 5210 B-2011 WG1317316 1 07/25/1915:40 07/30/1911:19 ARM Mt. Juliet, TN Wet Chemistry by Method 9056A WG1317503 1 07/25/1918:17 07/25/1918:17 ST Mt. Juliet, TN Wet Chemistry by Method 9060A WG1318069 1 07/26/1918:14 07/26/1918:14 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1915:41 EL Mt. Juliet, TN Volatile Organic Compounds (GC) by Method RSK175 WG1318305 1 07/27/19 05:35 07/27/19 05:35 DAH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1910:28 07/27/1910:28 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-3D L1122118-03 GW Laura Elliott 07/24/1910:45 07/25/1908:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1318097 1 07/29/1912:57 07/29/1912:57 LEB Mt. Juliet, TN Wet Chemistry by Method 3500Fe B-2011 WG1321133 1 08/01/1915:05 08/01/1915:05 JIC Mt. Juliet, TN Wet Chemistry by Method 410.4 WG1318879 1 07/29/1910:00 07/29/1913:16 BAM Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1317178 1 07/25/1917:50 07/25/1917:50 MJA Mt. Juliet, TN Wet Chemistry by Method 5210 B-2011 WG1320384 1 07/31/1911:45 08/05/19 09:05 ARM Mt. Juliet, TN Wet Chemistry by Method 9056A WG1317503 1 07/25/1918:32 07/25/1918:32 ST Mt. Juliet, TN Wet Chemistry by Method 9060A WG1318069 1 07/26/1918:28 07/26/1918:28 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1915:52 EL Mt. Juliet, TN Volatile Organic Compounds (GC) by Method RSK175 WG1318305 1 07/27/19 05:37 07/27/19 05:37 DAH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1910:48 07/27/1910:48 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-4 L1122118-04 GW Laura Elliott 07/24/1911:00 07/25/1908:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1318097 1 07/29/1913:17 07/29/1913:17 LEB Mt. Juliet, TN Wet Chemistry by Method 3500Fe B-2011 WG1321133 1 08/01/1915:07 08/01/1915:07 JIC Mt. Juliet, TN Wet Chemistry by Method 410.4 WG1318879 1 07/29/1910:00 07/29/1913:16 BAM Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1317178 1 07/25/1917:50 07/25/1917:50 MJA Mt. Juliet, TN Wet Chemistry by Method 5210 B-2011 WG1317316 1 07/25/1915:47 07/30/1911:32 ARM Mt. Juliet, TN Wet Chemistry by Method 9056A WG1317503 1 07/25/1918:47 07/25/1918:47 ST Mt. Juliet, TN Wet Chemistry by Method 9060A WG1318069 1 07/26/1918:42 07/26/1918:42 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1915:55 EL Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 3 of 55 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-4 L1122118-04 GW Laura Elliott 07/24/1911:00 07/25/19 08:45 C P Method Volatile Organic Compounds (GC) by Method RSK175 Volatile Organic Compounds (GC/MS) by Method 8260D MW-5 L1122118-05 GW Batch WG1318305 WG1318241 Dilution 1 1 Preparation date/time 07/27/19 05:41 07/27/1911:07 Collected by Laura Elliott Analysis date/time 07/27/19 05:41 07/27/1911:07 Collected date/time 07/24/1913:40 Analyst Location DAH Mt. Juliet, TN ZJM Mt. Juliet, TN Received date/time 07/25/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1915:58 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1911:27 07/27/1911:27 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time MW-6 L1122118-06 GW Laura Elliott 07/24/1913:30 07/25/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Wet Chemistry by Method 2320 B-2011 WG1318097 1 07/29/1913:23 07/29/1913:23 LEB Mt. Juliet, TN Wet Chemistry by Method 3500Fe B-2011 WG1321133 2 08/01/1915:16 08/01/1915:16 JIC Mt. Juliet, TN Wet Chemistry by Method 410.4 WG1318879 1 07/29/1910:00 07/29/1913:16 BAM Mt. Juliet, TN Wet Chemistry by Method 4500S2 D-2011 WG1317178 1 07/25/1917:51 07/25/1917:51 MJA Mt. Juliet, TN Wet Chemistry by Method 5210 B-2011 WG1317316 1 07/25/1915:54 07/30/1911:37 ARM Mt. Juliet, TN Wet Chemistry by Method 9056A WG1317503 1 07/25/1919:01 07/25/1919:01 ST Mt. Juliet, TN Wet Chemistry by Method 9060A WG1318069 1 07/26/1918:57 07/26/1918:57 VRP Mt. Juliet, TN Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1916:06 EL Mt. Juliet, TN Volatile Organic Compounds (GC) by Method RSK175 WG1318305 1 07/27/19 05:43 07/27/19 05:43 DAH Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1911:47 07/27/1911:47 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time SW-1 L1122118-07 GW Laura Elliott 07/24/1911:55 07/25/19 08:45 FTC M [Cn] FSr FC-1 F, FAI FSC Method Metals (ICP) by Method 6010D Volatile Organic Compounds (GC/MS) by Method 8260D SW-2 L1122118-08 GW Batch WG1318465 WG1318241 Dilution Preparation date/time 1 07/29/19 07:41 1 07/27/1912:07 Collected by Laura Elliott Analysis date/time 07/29/1916:09 07/27/1912:07 Collected date/time 07/24/1911:30 Analyst Location EL Mt. Juliet, TN ZJM Mt. Juliet, TN Received date/time 07/25/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1916:12 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1912:27 07/27/1912:27 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time SW-3 L1122118-09 GW Laura Elliott 07/24/1911:45 07/25/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Metals (ICP) by Method 6010D WG1318465 1 07/29/19 07:41 07/29/1916:15 EL Mt. Juliet, TN Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1912:47 07/27/1912:47 ZJM Mt. Juliet, TN ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 4 of 55 EB L1122118-10 GW SAMPLE SUMMARY Collected by Laura Elliott Collected date/time 07/24/1911:00 ONE LAB. NATIONWIDE. Received date/time 07/25/1908:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Volatile Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/1913:06 07/27/1913:06 ZJM Mt. Juliet, TN Collected by Collected date/time Received date/time M TRIP BLANK L1122118-11 GW Laura Elliott 07/24/19 00:00 07/25/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location [Cn] date/time date/time Organic Compounds (GC/MS) by Method 8260D WG1318241 1 07/27/19 08:48 07/27/19 08:48 ZJM Mt. Juliet, TN FSrVolatile RC F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 5 of 55 CASE NARRATIVE ONE LAB. NATIONWIDE. FP1 All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples FTChave been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my FSS knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. FSr FC-1 4�j �GI Heather J Wagner FAI Project Manager FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 6 of 55 MW-2R SAMPLE RESULTS - 01 Collected date/time: 07/24/19 10:20 L1122118 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Alkalinity 129000 2710 20000 1 07/29/201912:44 WG1318097 Sample Narrative. L1122118-01 WG1318097: Endpoint pH 4.5 Wet Chemistry by Method 3500Fe B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Ferrous Iron 521 T8 15.0 Wet Chemistry by Method 410.4 50.0 1 08/01/201915:02 WG1321133 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time COD U 3000 10000 1 07/29/201913:15 WG1318879 Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Sulfide U 6.50 50.0 1 07/25/201917:48 WG1317178 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/I mg/I date / time BOD U K1 K6 2.00 1 07/30/201911:17 WG1317316 Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Chloride 9650 51.9 1000 1 07/25/201918:02 WG1317503 Nitrate 80.0 J 22.7 100 1 07/25/201918:02 WG1317503 Sulfate U 77.4 5000 1 07/25/201918:02 WG1317503 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time TOC (Total Organic Carbon) 1380 B Metals (ICP) by Method 6010D 102 1000 1 07/26/201917:46 WG1318069 ONE LAB. NATIONWIDE. Fp] FTC FSS [Cn] RC F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch ug/I Ug/I ug/I date / time U 7.50 10.0 1 07/26/2019 09:11 WG1317659 U 6.50 10.0 1 07/26/2019 09:11 WG1317659 245 1.70 5.00 1 07/26/2019 09:11 WG1317659 U 0.700 2.00 1 07/26/2019 09:11 WG1317659 U 0.700 2.00 1 07/26/2019 09:11 WG1317659 U 1.40 10.0 1 07/26/2019 09:11 WG1317659 U 2.30 10.0 1 07/26/2019 09:11 WG1317659 U 5.30 10.0 1 07/26/2019 09:11 WG1317659 U 1.90 5.00 1 07/26/2019 09:11 WG1317659 U 4.90 10.0 1 07/26/2019 09:11 WG1317659 U 7.40 10.0 1 07/26/2019 09:11 WG1317659 U 2.80 5.00 1 07/26/2019 09:11 WG1317659 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 7 of 55 SAMPLE RESULTS - 01 11122118 ONE LAB. NATIONWIDE. MW-2R Collected date/time: 07/24/19 10:20 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Thallium U 6.50 10.0 1 07/26/2019 09:11 WG1317659 Vanadium U 2.40 20.0 1 07/26/2019 09:11 WG1317659 Zinc 10.2 J 5.90 50.0 1 07/26/2019 09:11 WG1317659 Volatile Organic Compounds (GC) by Method RSK175 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Methane 3700 2.91 10.0 1 07/27/2019 05:32 WG1318305 Ethane U 4.07 13.0 1 07/27/2019 05:32 WG1318305 Ethene U 4.26 13.0 1 07/27/2019 05:32 WG1318305 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene 3.43 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene 4.04 Dichlorodifluoromethane U 1,1-Dichloroethane 12.5 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene 28.7 trans-1,2-Dichloroethene 1.03 1,2-Dichloropropane 4.22 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 10.0 50.0 1 07/27/2019 10:08 WG1318241 8.87 50.0 1 07/27/2019 10:08 WG1318241 1.87 10.0 1 07/27/2019 10:08 WG1318241 0.331 1.00 1 07/27/2019 10:08 WG1318241 0.352 1.00 1 07/27/2019 10:08 WG1318241 0.380 1.00 1 07/27/2019 10:08 WG1318241 0.469 1.00 1 07/27/2019 10:08 WG1318241 0.866 5.00 1 07/271201910:08 WG1318241 0.361 1.00 1 07/27/2019 10:08 WG1318241 0.365 1.00 1 07/27/2019 10:08 WG1318241 0.399 1.00 1 07/27/2019 10:08 WG1318241 0.379 1.00 1 07/27/2019 10:08 WG1318241 0.348 1.00 1 07/27/2019 10:08 WG1318241 0.327 1.00 1 07/27/2019 10:08 WG1318241 0.453 5.00 1 07/27/2019 10:08 WG1318241 0.324 5.00 1 07/27/2019 10:08 WG1318241 0.276 2.50 1 07/27/2019 10:08 WG1318241 0.375 1.00 1 07/27/2019 10:08 WG1318241 0.351 1.00 1 07/27/2019 10:08 WG1318241 1.33 5.00 1 07/27/2019 10:08 WG1318241 0.381 1.00 1 07/27/2019 10:08 WG1318241 0.346 1.00 1 07/27/2019 10:08 WG1318241 0.349 1.00 1 07/27/2019 10:08 WG1318241 0.220 1.00 1 07/27/2019 10:08 WG1318241 0.274 1.00 1 07/27/2019 10:08 WG1318241 0.551 5.00 1 07/27/2019 10:08 WG1318241 0.259 1.00 1 07/27/2019 10:08 WG1318241 0.361 1.00 1 07/27/2019 10:08 WG1318241 0.398 1.00 1 07/27/2019 10:08 WG1318241 0.260 1.00 1 07/27/2019 10:08 WG1318241 0.396 1.00 1 07/27/2019 10:08 WG1318241 0.306 1.00 1 07/27/2019 10:08 WG1318241 0.352 1.00 1 07/27/2019 10:08 WG1318241 0.366 1.00 1 07/27/2019 10:08 WG1318241 0.418 1.00 1 07/27/2019 10:08 WG1318241 0.419 1.00 1 07/27/2019 10:08 WG1318241 0.321 1.00 1 07/27/2019 10:08 WG1318241 0.320 1.00 1 07/27/2019 10:08 WG1318241 0.384 1.00 1 07/27/2019 10:08 WG1318241 0.256 1.00 1 07/271201910:08 WG1318241 0.326 1.00 1 07/27/2019 10:08 WG1318241 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1122118 08/05/1915:44 8 of 55 MW-2R SAMPLE RESULTS - 01 Collected date/time: 07/24/19 10:20 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time p-Isopropyltoluene U 0.350 1.00 1 07/27/2019 10:08 2-Butanone (M EK) U 3.93 10.0 1 07/27/2019 10:08 Methylene Chloride U 1.00 5.00 1 07/27/2019 10:08 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 07/27/2019 10:08 Methyl tert-butyl ether U 0.367 1.00 1 07/27/2019 10:08 Naphthalene U 1.00 5.00 1 07/27/2019 10:08 n-Propylbenzene U 0.349 1.00 1 07/27/2019 10:08 Styrene U 0.307 1.00 1 07/27/2019 10:08 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 07/27/2019 10:08 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 07/27/2019 10:08 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1 07/27/2019 10:08 Tetrachloroethene 0.641 J 0.372 1.00 1 07/27/2019 10:08 Toluene U 0.412 1.00 1 07/27/2019 10:08 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/27/2019 10:08 1,2,4-Trichlorobenzene U 0.355 1.00 1 07/27/2019 10:08 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/2019 10:08 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/2019 10:08 Trichloroethene 2.76 0.398 1.00 1 07/27/2019 10:08 Trichlorofluoromethane U 1.20 5.00 1 07/27/2019 10:08 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/2019 10:08 1,2,4-Trimethylbenzene U 0.373 1.00 1 07/27/2019 10:08 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/2019 10:08 1,3,5-Trimethyl benzene U 0.387 1.00 1 07/271201910:08 Vinyl chloride 4.51 0.259 1.00 1 07/27/2019 10:08 Xylenes, Total U 1.06 3.00 1 07/27/2019 10:08 (S) Toluene-d8 108 80.0-120 071271201910:08 (S) 4-Bromof/uorobenzene 99.8 77.0-126 071271201910.08 (S)1,2-Dich/oroethone-d4 109 70.0-130 071271201910:08 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 DATE/TIME: 08/05/1915:44 Cp FTc FSS 4 Cn Fc F, FAI FSC PAGE: 9 of 55 MW-3S SAMPLE RESULTS - 02 Collected date/time: 07/24/19 10:00 L1122118 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Alkalinity 152000 2710 20000 1 07/29/201912:50 WG1318097 Sample Narrative: L1122118-02 WG1318097: Endpoint pH 4.5 Wet Chemistry by Method 3500Fe B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Ferrous Iron 488 T8 15.0 Wet Chemistry by Method 410.4 50.0 1 08/01/201915:04 WG1321133 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time COD 10200 3000 10000 1 07/29/201913:16 WG1318879 Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Sulfide U 6.50 50.0 1 07/25/201917:49 WG1317178 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/I mg/I date / time BOD U K1 K6 2.00 1 07/30/201911:19 WG1317316 Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Chloride 31300 51.9 1000 1 07/25/201918:17 WG1317503 Nitrate U 22.7 100 1 07/25/201918:17 WG1317503 Sulfate U 77.4 5000 1 07/25/201918:17 WG1317503 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time TOC (Total Organic Carbon) 1870 B Metals (ICP) by Method 6010D 102 1000 1 07/26/201918:14 WG1318069 ONE LAB. NATIONWIDE. FP1 FTC FSS [Cn] N RC F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch ug/I Ug/I ug/I date / time U 7.50 10.0 1 07/29/201915:41 WG1318465 U 6.50 10.0 1 07/29/201915:41 WG1318465 208 1.70 5.00 1 07/29/201915:41 WG1318465 U 0.700 2.00 1 07/29/201915:41 WG1318465 2.94 0.700 2.00 1 07/29/201915:41 WG1318465 4.69 J 1.40 10.0 1 07/29/201915:41 WG1318465 9.60 J 2.30 10.0 1 07/29/201915:41 WG1318465 16.9 5.30 10.0 1 07/29/201915:41 WG1318465 6.12 1.90 5.00 1 07/29/201915:41 WG1318465 5.37 J 4.90 10.0 1 07/29/201915:41 WG1318465 U 7.40 10.0 1 07/29/201915:41 WG1318465 U 2.80 5.00 1 07/29/201915:41 WG1318465 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 10 of 55 SAMPLE RESULTS - 02 -1122118 ONE LAB. NATIONWIDE. MW-3S Collected date/time: 07/24/19 10:00 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Thallium U 6.50 10.0 1 07/29/201915:41 WG1318465 Vanadium 51.8 2.40 20.0 1 07/29/201915:41 WG1318465 Zinc 592 5.90 50.0 1 07/29/201915:41 WG1318465 Volatile Organic Compounds (GC) by Method RSK175 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Methane 207 2.91 10.0 1 07/27/2019 05:35 WG1318305 Ethane U 4.07 13.0 1 07/27/2019 05:35 WG1318305 Ethene U 4.26 13.0 1 07/27/2019 05:35 WG1318305 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone 10.8 Acrolein U Acrylonitrile U Benzene 0.365 Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U tert-Butylbenzene U Carbon tetrachloride U Chlorobenzene 1.16 Chlorodibromomethane U Chloroethane 0.705 Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene 1.56 Dichlorodifluoromethane U 1,1-Dichloroethane 0.831 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene 3.81 trans-1,2-Dichloroethene U 1,2-Dichloropropane 0.508 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U Qualifier MDL ug/I J 10.0 J J J J 8.87 1.87 0.331 0.352 0.380 0.469 0.866 0.361 0.365 0.399 0.379 0.348 0.327 0.453 0.324 0.276 0.375 0.351 1.33 0.381 0.346 0.349 0.220 0.274 0.551 0.259 0.361 0.398 0.260 0.396 0.306 0.352 0.366 0.418 0.419 0.321 0.320 0.384 0.256 0.326 RDL ug/I 50.0 50.0 10.0 1.00 1.00 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 5.00 2.50 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Dilution Analysis date / time 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 1 07/27/201910:28 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 Fp FTc FS Fn N FC] F ql FAI FSC ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1122118 08/05/1915:44 11 of 55 MW-3S SAMPLE RESULTS - 02 Collected date/time: 07/24/19 10:00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time p-Isopropyltoluene U 0.350 1.00 1 07/27/201910:28 2-Butanone (MEK) U 3.93 10.0 1 07/27/201910:28 Methylene Chloride U 1.00 5.00 1 07/27/201910:28 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 07/27/201910:28 Methyl tert-butyl ether U 0.367 1.00 1 07/27/201910:28 Naphthalene U 1.00 5.00 1 07/27/201910:28 n-Propylbenzene U 0.349 1.00 1 07/27/201910:28 Styrene U 0.307 1.00 1 07/27/201910:28 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 07/27/201910:28 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 07/27/201910:28 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1 07/27/201910:28 Tetrachloroethene U 0.372 1.00 1 07/27/201910:28 Toluene U 0.412 1.00 1 07/27/201910:28 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/27/201910:28 1,2,4-Trichlorobenzene U 0.355 1.00 1 07/27/201910:28 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/201910:28 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/201910:28 Trichloroethene U 0.398 1.00 1 07/27/201910:28 Trichlorofluoromethane U 1.20 5.00 1 07/27/201910:28 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/201910:28 1,2,4-Trimethylbenzene U 0.373 1.00 1 07/27/201910:28 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/201910:28 1,3,5-Trimethyl benzene U 0.387 1.00 1 07/27/201910:28 Vinyl chloride 3.29 0.259 1.00 1 07/27/201910:28 Xylenes, Total U 1.06 3.00 1 07/27/201910:28 (S) Toluene-d8 107 80.0-120 071271201910:28 (S) 4-Bromof/uorobenzene 98.6 77.0-126 071271201910:28 (S)1,2-Dich/oroethone-d4 109 70.0-130 071271201910.28 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 DATE/TIME: 08/05/1915:44 Cp FTc FSS 4 Cn Fc F, FAI FSC PAGE: 12of55 MW-3D SAMPLE RESULTS - 03 Collected date/time: 07/24/19 10:45 L1122118 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Alkalinity 156000 2710 20000 1 07/29/201912:57 WG1318097 Sample Narrative: L1122118-03 WG1318097:Endpoint pH 4.5 Wet Chemistry by Method 3500Fe B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Ferrous Iron 35.0 J T8 15.0 Wet Chemistry by Method 410.4 50.0 1 08/01/201915:05 WG1321133 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time COD U 3000 10000 1 07/29/201913:16 WG1318879 Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Sulfide U 6.50 50.0 1 07/25/201917:50 WG1317178 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/I mg/I date / time BOD U H K1 K6 Q 2.00 1 08/05/2019 09:05 WG1320384 Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Chloride 18700 51.9 1000 1 07/25/201918:32 WG1317503 Nitrate U 22.7 100 1 07/25/201918:32 WG1317503 Sulfate 97.5 B J 77.4 5000 1 07/25/201918:32 WG1317503 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time TOC (Total Organic Carbon) 1370 B Metals (ICP) by Method 6010D 102 1000 1 07/26/201918:28 WG1318069 ONE LAB. NATIONWIDE. CP FTC FSS [Cn] RC F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch ug/I Ug/I ug/I date / time U 7.50 10.0 1 07/29/201915:52 WG1318465 U 6.50 10.0 1 07/29/201915:52 WG1318465 44.0 1.70 5.00 1 07/29/201915:52 WG1318465 U 0.700 2.00 1 07/29/201915:52 WG1318465 U 0.700 2.00 1 07/29/201915:52 WG1318465 U 1.40 10.0 1 07/29/201915:52 WG1318465 U 2.30 10.0 1 07/29/201915:52 WG1318465 U 5.30 10.0 1 07/29/201915:52 WG1318465 U 1.90 5.00 1 07/29/201915:52 WG1318465 U 4.90 10.0 1 07/29/201915:52 WG1318465 U 7.40 10.0 1 07/29/201915:52 WG1318465 U 2.80 5.00 1 07/29/201915:52 WG1318465 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 13 of 55 SAMPLE RESULTS - 03 -1122118 ONE LAB. NATIONWIDE. MW-3D Collected date/time: 07/24/19 10:45 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Thallium U 6.50 10.0 1 07/29/201915:52 WG1318465 Vanadium 7.44 J 2.40 20.0 1 07/29/201915:52 WG1318465 Zinc U 5.90 50.0 1 07/29/201915:52 WG1318465 Volatile Organic Compounds (GC) by Method RSK175 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Methane 590 2.91 10.0 1 07/27/2019 05:37 WG1318305 Ethane U 4.07 13.0 1 07/27/2019 05:37 WG1318305 Ethene U 4.26 13.0 1 07/27/2019 05:37 WG1318305 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/2019 10:48 WG1318241 Acrolein U 8.87 50.0 1 07/27/2019 10:48 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/2019 10:48 WG1318241 Benzene 0.575 1_ 0.331 1.00 1 07/27/2019 10:48 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/2019 10:48 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/2019 10:48 WG1318241 Bromoform U 0.469 1.00 1 07/27/2019 10:48 WG1318241 Bromomethane U 0.866 5.00 1 07/27/2019 10:48 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/2019 10:48 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/2019 10:48 WG1318241 tert-Butylbenzene U 0.399 1.00 1 07/27/2019 10:48 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/2019 10:48 WG1318241 Chlorobenzene 0.441 J 0.348 1.00 1 07/27/2019 10:48 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/2019 10:48 WG1318241 Chloroethane 0.797 J 0.453 5.00 1 07/27/2019 10:48 WG1318241 Chloroform U 0.324 5.00 1 07/27/2019 10:48 WG1318241 Chloromethane U 0.276 2.50 1 07/27/2019 10:48 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/2019 10:48 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/2019 10:48 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/2019 10:48 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/2019 10:48 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/2019 10:48 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/2019 10:48 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/2019 10:48 WG1318241 1,4-Dichlorobenzene 3.95 0.274 1.00 1 07/27/2019 10:48 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/2019 10:48 WG1318241 1,1-Dichloroethane 2.05 0.259 1.00 1 07/27/2019 10:48 WG1318241 1,2-Dichloroethane 0.696 J 0.361 1.00 1 07/27/2019 10:48 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/2019 10:48 WG1318241 cis-1,2-Dichloroethene 23.4 0.260 1.00 1 07/27/2019 10:48 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/2019 10:48 WG1318241 1,2-Dichloropropane 1.24 0.306 1.00 1 07/27/2019 10:48 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/2019 10:48 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/2019 10:48 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/2019 10:48 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/2019 10:48 WG1318241 2,2-Dichloropropane U 0.321 1.00 1 07/27/2019 10:48 WG1318241 Di -isopropyl ether U 0.320 1.00 1 07/27/2019 10:48 WG1318241 Ethylbenzene U 0.384 1.00 1 07/27/2019 10:48 WG1318241 Hexachloro-1,3-butadiene U 0.256 1.00 1 07/27/2019 10:48 WG1318241 Isopropylbenzene U 0.326 1.00 1 07/27/2019 10:48 WG1318241 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 14 of 55 MW-3D SAMPLE RESULTS - 03 Collected date/time: 07/24/19 10:45 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time p-Isopropyltoluene U 0.350 1.00 1 07/27/201910:48 2-Butanone (MEK) U 3.93 10.0 1 07/27/201910:48 Methylene Chloride U 1.00 5.00 1 07/27/201910:48 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 07/27/201910:48 Methyl tert-butyl ether U 0.367 1.00 1 07/27/201910:48 Naphthalene U 1.00 5.00 1 07/27/201910:48 n-Propylbenzene U 0.349 1.00 1 07/27/201910:48 Styrene U 0.307 1.00 1 07/27/201910:48 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 07/27/201910:48 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 07/27/201910:48 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1 07/27/201910:48 Tetrachloroethene U 0.372 1.00 1 07/27/201910:48 Toluene U 0.412 1.00 1 07/27/201910:48 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/27/201910:48 1,2,4-Trichlorobenzene U 0.355 1.00 1 07/27/201910:48 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/201910:48 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/201910:48 Trichloroethene U 0.398 1.00 1 07/27/201910:48 Trichlorofluoromethane U 1.20 5.00 1 07/27/201910:48 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/201910:48 1,2,4-Trimethylbenzene U 0.373 1.00 1 07/27/201910:48 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/201910:48 1,3,5-Trimethyl benzene U 0.387 1.00 1 07/27/201910:48 Vinyl chloride 13.6 0.259 1.00 1 07/27/201910:48 Xylenes, Total U 1.06 3.00 1 07/27/201910:48 (S) Toluene-d8 107 80.0-120 071271201910.48 (S) 4-Bromof/uorobenzene 96.7 77.0-126 071271201910.48 (S)1,2-Dich/oroethone-d4 109 70.0-130 071271201910.48 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 DATE/TIME: 08/05/1915:44 Cp FTc FSS 4 Cn Fc F, FAI FSC PAGE: 15of55 MW-4 SAMPLE RESULTS - 04 Collected date/time: 07/24/19 11:00 L1122118 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Alkalinity 170000 2710 20000 1 07/29/201913:17 WG1318097 Sample Narrative: L1122118-04 WG1318097: Endpoint pH 4.5 Wet Chemistry by Method 3500Fe B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Ferrous Iron 999 T8 15.0 Wet Chemistry by Method 410.4 50.0 1 08/01/201915:07 WG1321133 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time COD U 3000 10000 1 07/29/201913:16 WG1318879 Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Sulfide U 6.50 50.0 1 07/25/201917:50 WG1317178 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/I mg/I date / time BOD U K1 K6 2.00 1 07/30/201911:32 WG1317316 Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Chloride 17500 51.9 1000 1 07/25/201918:47 WG1317503 Nitrate 58.1 J 22.7 100 1 07/25/201918:47 WG1317503 Sulfate U 77.4 5000 1 07/25/201918:47 WG1317503 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time TOC (Total Organic Carbon) 1400 B Metals (ICP) by Method 6010D 102 1000 1 07/26/201918:42 WG1318069 ONE LAB. NATIONWIDE. Cp FTC FSS [Cn] N RC F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch ug/I Ug/I ug/I date / time U 7.50 10.0 1 07/29/201915:55 WG1318465 U 6.50 10.0 1 07/29/201915:55 WG1318465 92.7 1.70 5.00 1 07/29/201915:55 WG1318465 U 0.700 2.00 1 07/29/201915:55 WG1318465 U 0.700 2.00 1 07/29/201915:55 WG1318465 1.42 J 1.40 10.0 1 07/29/201915:55 WG1318465 U 2.30 10.0 1 07/29/201915:55 WG1318465 U 5.30 10.0 1 07/29/201915:55 WG1318465 U 1.90 5.00 1 07/29/201915:55 WG1318465 U 4.90 10.0 1 07/29/201915:55 WG1318465 U 7.40 10.0 1 07/29/201915:55 WG1318465 U 2.80 5.00 1 07/29/201915:55 WG1318465 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 16 of 55 SAMPLE RESULTS - 04 L1122118 ONE LAB. NATIONWIDE. M W-4 Collected date/time: 07/24/19 11:00 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Thallium U 6.50 10.0 1 07/29/201915:55 WG1318465 Vanadium U 2.40 20.0 1 07/29/201915:55 WG1318465 Zinc 5.93 J 5.90 50.0 1 07/29/201915:55 WG1318465 Volatile Organic Compounds (GC) by Method RSK175 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Methane 345 2.91 10.0 1 07/27/2019 05:41 WG1318305 Ethane U 4.07 13.0 1 07/27/2019 05:41 WG1318305 Ethene U 4.26 13.0 1 07/27/2019 05:41 WG1318305 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/201911:07 WG1318241 Acrolein U 8.87 50.0 1 07/27/201911:07 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/201911:07 WG1318241 Benzene U 0.331 1.00 1 07/27/201911:07 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/201911:07 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/201911:07 WG1318241 Bromoform U 0.469 1.00 1 07/27/201911:07 WG1318241 Bromomethane U 0.866 5.00 1 07/271201911:07 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/201911:07 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/201911:07 WG1318241 tert-Butylbenzene U 0.399 1.00 1 07/27/201911:07 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/201911:07 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/201911:07 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/201911:07 WG1318241 Chloroethane 0.875 J 0.453 5.00 1 07/27/201911:07 WG1318241 Chloroform U 0.324 5.00 1 07/27/201911:07 WG1318241 Chloromethane U 0.276 2.50 1 07/27/201911:07 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/201911:07 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/201911:07 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/201911:07 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/201911:07 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/201911:07 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/201911:07 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/201911:07 WG1318241 1,4-Dichlorobenzene 2.12 0.274 1.00 1 07/27/2019 11:07 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/201911:07 WG1318241 1,1-Dichloroethane 1.41 0.259 1.00 1 07/27/201911:07 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/201911:07 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/201911:07 WG1318241 cis-1,2-Dichloroethene 13.3 0.260 1.00 1 07/27/201911:07 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/201911:07 WG1318241 1,2-Dichloropropane 0.328 J_ 0.306 1.00 1 07/27/201911:07 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/201911:07 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/201911:07 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/201911:07 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/201911:07 WG1318241 2,2-Dichloropropane U 0.321 1.00 1 07/27/201911:07 WG1318241 Di -isopropyl ether U 0.320 1.00 1 07/27/201911:07 WG1318241 Ethylbenzene U 0.384 1.00 1 07/27/201911:07 WG1318241 Hexachloro-1,3-butadiene U 0.256 1.00 1 07/271201911:07 WG1318241 Isopropylbenzene U 0.326 1.00 1 07/27/201911:07 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 Fp FTc FS Fn N FC] F ql FAI FSC PAGE: 17 of 55 MW-4 SAMPLE RESULTS - 04 Collected date/time: 07/24/19 11:00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time p-Isopropyltoluene U 0.350 1.00 1 07/27/201911:07 2-Butanone (MEK) U 3.93 10.0 1 07/27/201911:07 Methylene Chloride U 1.00 5.00 1 07/27/201911:07 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 07/27/201911:07 Methyl tert-butyl ether U 0.367 1.00 1 07/27/201911:07 Naphthalene U 1.00 5.00 1 07/27/201911:07 n-Propylbenzene U 0.349 1.00 1 07/27/201911:07 Styrene U 0.307 1.00 1 07/27/201911:07 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 07/27/201911:07 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 07/27/201911:07 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1 07/27/201911:07 Tetrachloroethene U 0.372 1.00 1 07/27/201911:07 Toluene U 0.412 1.00 1 07/27/201911:07 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/27/201911:07 1,2,4-Trichlorobenzene U 0.355 1.00 1 07/27/201911:07 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/201911:07 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/201911:07 Trichloroethene U 0.398 1.00 1 07/27/201911:07 Trichlorofluoromethane U 1.20 5.00 1 07/27/201911:07 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/201911:07 1,2,4-Trimethylbenzene U 0.373 1.00 1 07/27/201911:07 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/201911:07 1,3,5-Trimethyl benzene U 0.387 1.00 1 07/271201911:07 Vinyl chloride 12.3 0.259 1.00 1 07/27/201911:07 Xylenes, Total U 1.06 3.00 1 07/27/201911:07 (S Toluene-d8 106 80.0-120 071271201911.07 (S 4-Bromof/uorobenzene 96.1 77.0-126 071271201911.07 (S 1,2-Dich/oroethone-d4 111 70.0-130 071271201911.07 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 DATE/TIME: 08/05/1915:44 Cp FTc FSS 4 Cn Fc F, FAI FSC PAGE: 18 of 55 M W - 5 SAMPLE RESULTS - 05 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 13:40 L1122118 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 7.50 10.0 1 07/29/201915:58 WG1318465 FTc Arsenic U 6.50 10.0 1 07/29/2019 15:58 WG1318465 Barium 108 1.70 5.00 1 07/29/201915:58 WG1318465 F Beryllium U 0.700 2.00 1 07/29/201915:58 WG1318465 Cadmium U 0.700 2.00 1 07/29/201915:58 WG1318465 Chromium U 1.40 10.0 1 07/29/201915:58 WG1318465 4 Cfl Cobalt 7.24 J 2.30 10.0 1 07/29/201915:58 WG1318465 Copper 11.0 5.30 10.0 1 07/29/201915:58 WG1318465 Lead 23.5 1.90 5.00 1 07/29/201915:58 WG1318465 Nickel U 4.90 10.0 1 07/29/201915:58 WG1318465 Selenium U 7.40 10.0 1 07/29/201915:58 WG1318465 6 QC Silver U 2.80 5.00 1 07/29/201915:58 WG1318465 Thallium U 6.50 10.0 1 07/29/201915:58 WG1318465 GI Vanadium 12.9 J 2.40 20.0 1 07/29/201915:58 WG1318465 Zinc 45.3 J 5.90 50.0 1 07/29/201915:58 WG1318465 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/2019 11:27 WG1318241 Acrolein U 8.87 50.0 1 07/27/2019 11:27 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/2019 11:27 WG1318241 Benzene U 0.331 1.00 1 07/27/2019 11:27 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/2019 11:27 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/2019 11:27 WG1318241 Bromoform U 0.469 1.00 1 07/27/2019 11:27 WG1318241 Bromomethane U 0.866 5.00 1 07/27/2019 11:27 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/2019 11:27 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/2019 11:27 WG1318241 ter[-Butylbenzene U 0.399 1.00 1 07/27/2019 11:27 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/2019 11:27 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/2019 11:27 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/2019 11:27 WG1318241 Chloroethane U 0.453 5.00 1 07/27/2019 11:27 WG1318241 Chloroform U 0.324 5.00 1 07/27/2019 11:27 WG1318241 Chloromethane U 0.276 2.50 1 07/27/2019 11:27 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/2019 11:27 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/2019 11:27 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/2019 11:27 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/2019 11:27 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/2019 11:27 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/2019 11:27 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/2019 11:27 WG1318241 1,4-Dichlorobenzene U 0.274 1.00 1 07/27/2019 11:27 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/2019 11:27 WG1318241 1,1-Dichloroethane U 0.259 1.00 1 07/27/2019 11:27 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/2019 11:27 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/2019 11:27 WG1318241 cis-1,2-Dichloroethene U 0.260 1.00 1 07/27/2019 11:27 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/2019 11:27 WG1318241 1,2-Dichloropropane U 0.306 1.00 1 07/27/2019 11:27 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/2019 11:27 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/2019 11:27 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/2019 11:27 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/2019 11:27 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 19 of 55 ONE LAB. NATIONWIDE. MW-5 SAMPLE RESULTS - 05 Collected date/time: 07/24/19 13:40 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 106 (S) 4-Bromof/uorobenzene 96.0 (S)1,2-Dich/oroethane-d4 108 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.321 1.00 1 07/27/201911:27 WG1318241 0.320 1.00 1 07/27/201911:27 WG1318241 0.384 1.00 1 07/27/201911:27 WG1318241 0.256 1.00 1 07/27/201911:27 WG1318241 0.326 1.00 1 07/27/201911:27 WG1318241 0.350 1.00 1 07/27/201911:27 WG1318241 3.93 10.0 1 07/27/201911:27 WG1318241 1.00 5.00 1 07/27/201911:27 WG1318241 2.14 10.0 1 07/27/201911:27 WG1318241 0.367 1.00 1 07/27/201911:27 WG1318241 1.00 5.00 1 07/27/201911:27 WG1318241 0.349 1.00 1 07/27/201911:27 WG1318241 0.307 1.00 1 07/27/201911:27 WG1318241 0.385 1.00 1 07/271201911:27 WG1318241 0.130 1.00 1 07/27/201911:27 WG1318241 0.303 1.00 1 07/27/201911:27 WG1318241 0.372 1.00 1 07/27/201911:27 WG1318241 0.412 1.00 1 07/27/201911:27 WG1318241 0.230 1.00 1 07/27/201911:27 WG1318241 0.355 1.00 1 07/27/201911:27 WG1318241 0.319 1.00 1 07/27/201911:27 WG1318241 0.383 1.00 1 07/27/201911:27 WG1318241 0.398 1.00 1 07/27/201911:27 WG1318241 1.20 5.00 1 07/27/201911:27 WG1318241 0.807 2.50 1 07/27/201911:27 WG1318241 0.373 1.00 1 07/27/201911:27 WG1318241 0.321 1.00 1 07/27/201911:27 WG1318241 0.387 1.00 1 07/27/201911:27 WG1318241 0.259 1.00 1 07/27/201911:27 WG1318241 1.06 3.00 1 07/27/201911:27 WG1318241 80.0-120 071271201911:27 WG1318241 77.0-126 071271201911:27 WG1318241 70.0-130 071271201911:27 WG1318241 Fp FTc FS Fn N FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 20 of 55 MW-6 SAMPLE RESULTS - 06 Collected date/time: 07/24/19 13:30 L1122118 Wet Chemistry by Method 2320 B-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Alkalinity 17300 J 2710 20000 1 07/29/201913:23 WG1318097 Sample Narrative: L1122118-06 WG1318097: Endpoint pH 4.5 Wet Chemistry by Method 3500Fe B-2011 Result Qualifier MDL RDL Analyte ug/I Ug/I ug/I Ferrous Iron 3160 T8 30.0 100 Wet Chemistry by Method 410.4 Dilution Analysis Batch date / time 2 08/01/201915:16 WG1321133 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time COD U 3000 10000 1 07/29/201913:16 WG1318879 Wet Chemistry by Method 4500S2 D-2011 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Sulfide 7.00 J 6.50 50.0 1 07/25/201917:51 WG1317178 Wet Chemistry by Method 5210 B-2011 Result Qualifier RDL Dilution Analysis Batch Analyte mg/I mg/I date / time BOD U K1 K6 2.00 1 07/30/201911:37 WG1317316 Wet Chemistry by Method 9056A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time Chloride 1950 51.9 1000 1 07/25/201919:01 WG1317503 Nitrate U 22.7 100 1 07/25/201919:01 WG1317503 Sulfate 4070 B J P1 77.4 5000 1 07/25/201919:01 WG1317503 Wet Chemistry by Method 9060A Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I Ug/I ug/I date / time TOC (Total Organic Carbon) 1370 B Metals (ICP) by Method 6010D 102 1000 1 07/26/201918:57 WG1318069 ONE LAB. NATIONWIDE. FP1 FTC FSS [Cn] RC F FAI FSC Result Qualifier MDL RDL Dilution Analysis Batch ug/I Ug/I ug/I date / time U 7.50 10.0 1 07/29/201916:06 WG1318465 U 6.50 10.0 1 07/29/201916:06 WG1318465 51.3 1.70 5.00 1 07/29/201916:06 WG1318465 U 0.700 2.00 1 07/29/201916:06 WG1318465 U 0.700 2.00 1 07/29/201916:06 WG1318465 U 1.40 10.0 1 07/29/201916:06 WG1318465 U 2.30 10.0 1 07/29/201916:06 WG1318465 U 5.30 10.0 1 07/29/201916:06 WG1318465 1.90 J 1.90 5.00 1 07/29/201916:06 WG1318465 U 4.90 10.0 1 07/29/201916:06 WG1318465 U 7.40 10.0 1 07/29/201916:06 WG1318465 U 2.80 5.00 1 07/29/201916:06 WG1318465 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 21 of 55 MW-6 SAMPLE RESULTS - 06 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 13:30 L1122118 Metals (ICP) by Method 6010D Result Qualifier MDL RDL Dilution Analysis Batch F Analyte ug/I ug/I ug/I date / time Thallium U 6.50 10.0 1 07/29/201916:06 WG1318465 F Vanadium 9.14 J 2.40 20.0 1 07/29/201916:06 WG1318465 Zinc U 5.90 50.0 1 07/29/201916:06 WG1318465 FS Volatile Organic Compounds (GC) by Method RSK175 Qualifier MDL RDL Dilution Analysis Batch FnResult Analyte ug/I ug/I ug/I date / time Methane 27.2 2.91 10.0 1 07/27/2019 05:43 WG1318305 Ethane U 4.07 13.0 1 07/27/2019 05:43 WG1318305 Ethene U 4.26 13.0 1 07/27/2019 05:43 WG1318305 FC] Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch F q Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/201911:47 WG1318241 FAI Acrolein U 8.87 50.0 1 07/27/201911:47 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/201911:47 WG1318241 Benzene U 0.331 1.00 1 07/27/201911:47 WG1318241 FSC Bromobenzene U 0.352 1.00 1 07/27/201911:47 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/201911:47 WG1318241 Bromoform U 0.469 1.00 1 07/27/201911:47 WG1318241 Bromomethane U 0.866 5.00 1 07/27/201911:47 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/201911:47 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/201911:47 WG1318241 tert-Butylbenzene U 0.399 1.00 1 07/27/201911:47 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/201911:47 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/201911:47 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/201911:47 WG1318241 Chloroethane U 0.453 5.00 1 07/27/201911:47 WG1318241 Chloroform U 0.324 5.00 1 07/27/201911:47 WG1318241 Chloromethane U 0.276 2.50 1 07/27/201911:47 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/201911:47 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/201911:47 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/201911:47 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/201911:47 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/201911:47 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/201911:47 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/201911:47 WG1318241 1,4-Dichlorobenzene U 0.274 1.00 1 07/27/2019 11:47 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/201911:47 WG1318241 1,1-Dichloroethane U 0.259 1.00 1 07/27/201911:47 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/201911:47 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/201911:47 WG1318241 cis-1,2-Dichloroethene U 0.260 1.00 1 07/27/201911:47 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/201911:47 WG1318241 1,2-Dichloropropane U 0.306 1.00 1 07/27/201911:47 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/201911:47 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/201911:47 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/201911:47 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/201911:47 WG1318241 2,2-Dichloropropane U 0.321 1.00 1 07/27/201911:47 WG1318241 Di -isopropyl ether U 0.320 1.00 1 07/27/201911:47 WG1318241 Ethylbenzene U 0.384 1.00 1 07/27/201911:47 WG1318241 Hexachloro-1,3-butadiene U 0.256 1.00 1 07/27/201911:47 WG1318241 Isopropylbenzene U 0.326 1.00 1 07/27/201911:47 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 22 of 55 MW-6 SAMPLE RESULTS - 06 Collected date/time: 07/24/19 13:30 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D ONE LAB. NATIONWIDE. Result Qualifier MDL RDL Dilution Analysis Analyte ug/I ug/I ug/I date / time p-Isopropyltoluene U 0.350 1.00 1 07/27/201911:47 2-Butanone (MEK) U 3.93 10.0 1 07/27/201911:47 Methylene Chloride U 1.00 5.00 1 07/27/201911:47 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 07/27/201911:47 Methyl tert-butyl ether U 0.367 1.00 1 07/27/201911:47 Naphthalene U 1.00 5.00 1 07/27/201911:47 n-Propylbenzene U 0.349 1.00 1 07/27/201911:47 Styrene U 0.307 1.00 1 07/27/201911:47 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 07/27/201911:47 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 07/27/201911:47 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1 07/27/201911:47 Tetrachloroethene U 0.372 1.00 1 07/27/201911:47 Toluene U 0.412 1.00 1 07/27/201911:47 1,2,3-Trichlorobenzene U 0.230 1.00 1 07/27/201911:47 1,2,4-Trichlorobenzene U 0.355 1.00 1 07/27/201911:47 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/201911:47 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/201911:47 Trichloroethene U 0.398 1.00 1 07/27/201911:47 Trichlorofluoromethane U 1.20 5.00 1 07/27/201911:47 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/201911:47 1,2,4-Trimethylbenzene U 0.373 1.00 1 07/27/201911:47 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/201911:47 1,3,5-Trimethyl benzene U 0.387 1.00 1 07/27/201911:47 Vinyl chloride U 0.259 1.00 1 07/27/201911:47 Xylenes, Total U 1.06 3.00 1 07/27/201911:47 (S) Toluene-d8 109 80.0-120 071271201911.47 (S) 4-Bromof/uorobenzene 97.2 77.0-126 071271201911.47 (S)1,2-Dich/oroethone-d4 111 70.0-130 071271201911.47 ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 DATE/TIME: 08/05/1915:44 Cp FTc FSS 4 Cn Fc F, FAI FSC PAGE: 23 of 55 SW-1 SAMPLE RESULTS - 07 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 11:55 L1122118 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 7.50 10.0 1 07/29/201916:09 WG1318465 FTc Arsenic U 6.50 10.0 1 07/29/201916:09 WG1318465 Barium 36.9 1.70 5.00 1 07/29/201916:09 WG1318465 F Beryllium U 0.700 2.00 1 07/29/201916:09 WG1318465 Cadmium U 0.700 2.00 1 07/29/201916:09 WG1318465 Chromium U 1.40 10.0 1 07/29/201916:09 WG1318465 4 Cfl Cobalt U 2.30 10.0 1 07/29/201916:09 WG1318465 Copper U 5.30 10.0 1 07/29/201916:09 WG1318465 Lead U 1.90 5.00 1 07/29/201916:09 WG1318465 Nickel U 4.90 10.0 1 07/29/201916:09 WG1318465 Selenium U 7.40 10.0 1 07/29/201916:09 WG1318465 6 QC Silver U 2.80 5.00 1 07/29/201916:09 WG1318465 Thallium U 6.50 10.0 1 07/29/201916:09 WG1318465 GI Vanadium 8.02 J 2.40 20.0 1 07/29/201916:09 WG1318465 Zinc U 5.90 50.0 1 07/29/201916:09 WG1318465 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/2019 12:07 WG1318241 Acrolein U 8.87 50.0 1 07/27/2019 12:07 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/2019 12:07 WG1318241 Benzene U 0.331 1.00 1 07/27/2019 12:07 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/2019 12:07 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/2019 12:07 WG1318241 Bromoform U 0.469 1.00 1 07/27/2019 12:07 WG1318241 Bromomethane U 0.866 5.00 1 07/27/2019 12:07 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/2019 12:07 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/2019 12:07 WG1318241 ter[-Butylbenzene U 0.399 1.00 1 07/27/2019 12:07 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/2019 12:07 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/2019 12:07 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/2019 12:07 WG1318241 Chloroethane U 0.453 5.00 1 07/27/2019 12:07 WG1318241 Chloroform U 0.324 5.00 1 07/27/2019 12:07 WG1318241 Chloromethane U 0.276 2.50 1 07/27/2019 12:07 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/2019 12:07 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/2019 12:07 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/2019 12:07 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/2019 12:07 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/2019 12:07 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/2019 12:07 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/2019 12:07 WG1318241 1,4-Dichlorobenzene U 0.274 1.00 1 07/27/2019 12:07 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/2019 12:07 WG1318241 1,1-Dichloroethane U 0.259 1.00 1 07/27/2019 12:07 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/2019 12:07 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/2019 12:07 WG1318241 cis-1,2-Dichloroethene U 0.260 1.00 1 07/27/2019 12:07 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/2019 12:07 WG1318241 1,2-Dichloropropane U 0.306 1.00 1 07/27/2019 12:07 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/2019 12:07 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/2019 12:07 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/2019 12:07 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/2019 12:07 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 24 of 55 ONE LAB. NATIONWIDE. SW-1 SAMPLE RESULTS - 07 Collected date/time: 07/24/19 11:55 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 106 (S) 4-Bromof/uorobenzene 97.6 (S)1,2-Dich/oroethane-d4 112 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.321 1.00 1 07/27/2019 12:07 WG1318241 0.320 1.00 1 07/27/2019 12:07 WG1318241 0.384 1.00 1 07/27/2019 12:07 WG1318241 0.256 1.00 1 07/27/2019 12:07 WG1318241 0.326 1.00 1 07/27/2019 12:07 WG1318241 0.350 1.00 1 07/27/2019 12:07 WG1318241 3.93 10.0 1 07/27/2019 12:07 WG1318241 1.00 5.00 1 07/27/2019 12:07 WG1318241 2.14 10.0 1 07/27/2019 12:07 WG1318241 0.367 1.00 1 07/27/2019 12:07 WG1318241 1.00 5.00 1 07/27/2019 12:07 WG1318241 0.349 1.00 1 07/27/2019 12:07 WG1318241 0.307 1.00 1 07/27/2019 12:07 WG1318241 0.385 1.00 1 07/27/2019 12:07 WG1318241 0.130 1.00 1 07/27/2019 12:07 WG1318241 0.303 1.00 1 07/27/2019 12:07 WG1318241 0.372 1.00 1 07/27/2019 12:07 WG1318241 0.412 1.00 1 07/27/2019 12:07 WG1318241 0.230 1.00 1 07/27/2019 12:07 WG1318241 0.355 1.00 1 07/27/2019 12:07 WG1318241 0.319 1.00 1 07/27/2019 12:07 WG1318241 0.383 1.00 1 07/27/2019 12:07 WG1318241 0.398 1.00 1 07/27/2019 12:07 WG1318241 1.20 5.00 1 07/27/2019 12:07 WG1318241 0.807 2.50 1 07/27/2019 12:07 WG1318241 0.373 1.00 1 07/27/2019 12:07 WG1318241 0.321 1.00 1 07/27/2019 12:07 WG1318241 0.387 1.00 1 07/27/2019 12:07 WG1318241 0.259 1.00 1 07/27/2019 12:07 WG1318241 1.06 3.00 1 07/27/2019 12:07 WG1318241 80.0-120 071271201912:07 WG1318241 77.0-126 071271201912:07 WG1318241 70.0-130 071271201912:07 WG1318241 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 25 of 55 SW-2 SAMPLE RESULTS - 08 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 11:30 L1122118 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 7.50 10.0 1 07/29/201916:12 WG1318465 FTc Arsenic U 6.50 10.0 1 07/29/201916:12 WG1318465 Barium 38.4 1.70 5.00 1 07/29/201916:12 WG1318465 F Beryllium U 0.700 2.00 1 07/29/201916:12 WG1318465 Cadmium U 0.700 2.00 1 07/29/201916:12 WG1318465 Chromium U 1.40 10.0 1 07/29/201916:12 WG1318465 4 Cfl Cobalt U 2.30 10.0 1 07/29/201916:12 WG1318465 Copper U 5.30 10.0 1 07/29/201916:12 WG1318465 Lead U 1.90 5.00 1 07/29/201916:12 WG1318465 Nickel U 4.90 10.0 1 07/29/201916:12 WG1318465 Selenium U 7.40 10.0 1 07/29/201916:12 WG1318465 6 QC Silver U 2.80 5.00 1 07/29/201916:12 WG1318465 Thallium U 6.50 10.0 1 07/29/201916:12 WG1318465 GI Vanadium 5.97 J 2.40 20.0 1 07/29/201916:12 WG1318465 Zinc U 5.90 50.0 1 07/29/201916:12 WG1318465 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/2019 12:27 WG1318241 Acrolein U 8.87 50.0 1 07/27/2019 12:27 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/2019 12:27 WG1318241 Benzene U 0.331 1.00 1 07/27/2019 12:27 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/2019 12:27 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/2019 12:27 WG1318241 Bromoform U 0.469 1.00 1 07/27/2019 12:27 WG1318241 Bromomethane U 0.866 5.00 1 07/27/2019 12:27 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/2019 12:27 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/2019 12:27 WG1318241 ter[-Butylbenzene U 0.399 1.00 1 07/27/2019 12:27 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/2019 12:27 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/2019 12:27 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/2019 12:27 WG1318241 Chloroethane U 0.453 5.00 1 07/27/2019 12:27 WG1318241 Chloroform U 0.324 5.00 1 07/27/2019 12:27 WG1318241 Chloromethane U 0.276 2.50 1 07/27/2019 12:27 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/2019 12:27 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/2019 12:27 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/2019 12:27 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/2019 12:27 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/2019 12:27 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/2019 12:27 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/2019 12:27 WG1318241 1,4-Dichlorobenzene U 0.274 1.00 1 07/27/2019 12:27 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/2019 12:27 WG1318241 1,1-Dichloroethane U 0.259 1.00 1 07/27/2019 12:27 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/2019 12:27 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/2019 12:27 WG1318241 cis-1,2-Dichloroethene U 0.260 1.00 1 07/27/2019 12:27 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/2019 12:27 WG1318241 1,2-Dichloropropane U 0.306 1.00 1 07/27/2019 12:27 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/2019 12:27 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/2019 12:27 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/2019 12:27 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/2019 12:27 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 26 of 55 ONE LAB. NATIONWIDE. SW-2 SAMPLE RESULTS - 08 Collected date/time: 07/24/19 11:30 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte 2,2-Dichloropropane Di -isopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrach I oroeth a n e 1,1,2,2-Tetrachloroetha ne 1,1,2-Trichlorotrifluoroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-T ri c h l o ro eth a n e 1,1,2-Trich I oroetha n e Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Tri methyl benzen e 1,2,3-Trimethyl benzene 1,3,5-Trimethyl benzene Vinyl chloride Xylenes, Total (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Result Qualifier MDL RDL Dilution Analysis ug/I ug/I ug/I date / time IJ 0.321 1.00 1 07/27/201912:27 IJ 0.320 1.00 1 07/27/201912:27 IJ 0.384 1.00 1 07/27/201912:27 IJ 0.256 1.00 1 07/27/201912:27 IJ 0.326 1.00 1 07/27/201912:27 J 0.350 1.00 1 07/27/201912:27 IJ 3.93 10.0 1 07/27/201912:27 J 1.00 5.00 1 07/27/201912:27 IJ 2.14 10.0 1 07/27/201912:27 J 0.367 1.00 1 07/27/201912:27 IJ 1.00 5.00 1 07/27/201912:27 IJ 0.349 1.00 1 07/27/201912:27 IJ 0.307 1.00 1 07/27/201912:27 IJ 0.385 1.00 1 07/271201912:27 IJ 0.130 1.00 1 07/27/201912:27 IJ 0.303 1.00 1 07/27/201912:27 IJ 0.372 1.00 1 07/27/201912:27 IJ 0.412 1.00 1 07/27/201912:27 IJ 0.230 1.00 1 07/27/201912:27 IJ 0.355 1.00 1 07/27/201912:27 IJ 0.319 1.00 1 07/27/201912:27 IJ 0.383 1.00 1 07/27/201912:27 IJ 0.398 1.00 1 07/27/201912:27 J 1.20 5.00 1 07/27/201912:27 IJ 0.807 2.50 1 07/27/201912:27 J 0.373 1.00 1 07/27/201912:27 IJ 0.321 1.00 1 07/27/201912:27 J 0.387 1.00 1 07/27/201912:27 IJ 0.259 1.00 1 07/27/201912:27 IJ 1.06 3.00 1 07/27/201912:27 107 80.0-120 071271201912:27 97.1 77.0-126 071271201912:27 ill 70.0-130 071271201912:27 Batch WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 WG1318241 Fp FTc FS Fn FC] F FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 27 of 55 SW-3 SAMPLE RESULTS - 09 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 11:45 L1122118 Metals (ICP) by Method 6010D FP1 Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date /time Antimony U 7.50 10.0 1 07/29/201916:15 WG1318465 FTc Arsenic U 6.50 10.0 1 07/29/201916:15 WG1318465 Barium 38.7 1.70 5.00 1 07/29/201916:15 WG1318465 F Beryllium U 0.700 2.00 1 07/29/201916:15 WG1318465 Cadmium U 0.700 2.00 1 07/29/201916:15 WG1318465 Chromium U 1.40 10.0 1 07/29/201916:15 WG1318465 4 Cfl Cobalt U 2.30 10.0 1 07/29/201916:15 WG1318465 Copper U 5.30 10.0 1 07/29/201916:15 WG1318465 Lead 2.24 J 1.90 5.00 1 07/29/201916:15 WG1318465 Nickel U 4.90 10.0 1 07/29/201916:15 WG1318465 Selenium U 7.40 10.0 1 07/29/201916:15 WG1318465 6 QC Silver U 2.80 5.00 1 07/29/201916:15 WG1318465 Thallium U 6.50 10.0 1 07/29/201916:15 WG1318465 GI Vanadium 6.81 J 2.40 20.0 1 07/29/201916:15 WG1318465 Zinc U 5.90 50.0 1 07/29/201916:15 WG1318465 Al r Volatile Organic Compounds (GC/MS) by Method 8260D Qualifier MDL RDL Dilution Analysis Batch FSCResult Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 07/27/2019 12:47 WG1318241 Acrolein U 8.87 50.0 1 07/27/2019 12:47 WG1318241 Acrylonitrile U 1.87 10.0 1 07/27/2019 12:47 WG1318241 Benzene U 0.331 1.00 1 07/27/2019 12:47 WG1318241 Bromobenzene U 0.352 1.00 1 07/27/2019 12:47 WG1318241 Bromodichloromethane U 0.380 1.00 1 07/27/2019 12:47 WG1318241 Bromoform U 0.469 1.00 1 07/27/2019 12:47 WG1318241 Bromomethane U 0.866 5.00 1 07/27/2019 12:47 WG1318241 n-Butylbenzene U 0.361 1.00 1 07/27/2019 12:47 WG1318241 sec -Butyl benzene U 0.365 1.00 1 07/27/2019 12:47 WG1318241 ter[-Butylbenzene U 0.399 1.00 1 07/27/2019 12:47 WG1318241 Carbon tetrachloride U 0.379 1.00 1 07/27/2019 12:47 WG1318241 Chlorobenzene U 0.348 1.00 1 07/27/2019 12:47 WG1318241 Chlorodibromomethane U 0.327 1.00 1 07/27/2019 12:47 WG1318241 Chloroethane U 0.453 5.00 1 07/27/2019 12:47 WG1318241 Chloroform U 0.324 5.00 1 07/27/2019 12:47 WG1318241 Chloromethane U 0.276 2.50 1 07/27/2019 12:47 WG1318241 2-Chlorotoluene U 0.375 1.00 1 07/27/2019 12:47 WG1318241 4-Chlorotoluene U 0.351 1.00 1 07/27/2019 12:47 WG1318241 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 07/27/2019 12:47 WG1318241 1,2-Dibromoethane U 0.381 1.00 1 07/27/2019 12:47 WG1318241 Dibromomethane U 0.346 1.00 1 07/27/2019 12:47 WG1318241 1,2-Dichlorobenzene U 0.349 1.00 1 07/27/2019 12:47 WG1318241 1,3-Dichlorobenzene U 0.220 1.00 1 07/27/2019 12:47 WG1318241 1,4-Dichlorobenzene U 0.274 1.00 1 07/27/2019 12:47 WG1318241 Dichlorodifluoromethane U 0.551 5.00 1 07/27/2019 12:47 WG1318241 1,1-Dichloroethane U 0.259 1.00 1 07/27/2019 12:47 WG1318241 1,2-Dichloroethane U 0.361 1.00 1 07/27/2019 12:47 WG1318241 1,1-Dichloroethene U 0.398 1.00 1 07/27/2019 12:47 WG1318241 cis-1,2-Dichloroethene U 0.260 1.00 1 07/27/2019 12:47 WG1318241 trans-1,2-Dichloroethene U 0.396 1.00 1 07/27/2019 12:47 WG1318241 1,2-Dichloropropane U 0.306 1.00 1 07/27/2019 12:47 WG1318241 1,1-Dichloropropene U 0.352 1.00 1 07/27/2019 12:47 WG1318241 1,3-Dichloropropane U 0.366 1.00 1 07/27/2019 12:47 WG1318241 cis-1,3-Dichloropropene U 0.418 1.00 1 07/27/2019 12:47 WG1318241 trans-1,3-Dichloropropene U 0.419 1.00 1 07/27/2019 12:47 WG1318241 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 28 of 55 ONE LAB. NATIONWIDE. SW-3 SAMPLE RESULTS - 09 Collected date/time: 07/24/19 11:45 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U 1,2,4-Trimethylbenzene U 1,2,3-Trimethyl benzene U 1,3,5-Trimethyl benzene U Vinyl chloride U Xylenes, Total U (S) Toluene-d8 107 (S) 4-Bromof/uorobenzene 96.6 (S)1,2-Dich/oroethane-d4 109 Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 0.321 1.00 1 07/27/2019 12:47 WG1318241 0.320 1.00 1 07/27/2019 12:47 WG1318241 0.384 1.00 1 07/27/2019 12:47 WG1318241 0.256 1.00 1 07/27/2019 12:47 WG1318241 0.326 1.00 1 07/27/2019 12:47 WG1318241 0.350 1.00 1 07/27/2019 12:47 WG1318241 3.93 10.0 1 07/27/2019 12:47 WG1318241 1.00 5.00 1 07/27/2019 12:47 WG1318241 2.14 10.0 1 07/27/2019 12:47 WG1318241 0.367 1.00 1 07/27/2019 12:47 WG1318241 1.00 5.00 1 07/27/2019 12:47 WG1318241 0.349 1.00 1 07/27/2019 12:47 WG1318241 0.307 1.00 1 07/27/2019 12:47 WG1318241 0.385 1.00 1 07/27/2019 12:47 WG1318241 0.130 1.00 1 07/27/2019 12:47 WG1318241 0.303 1.00 1 07/27/2019 12:47 WG1318241 0.372 1.00 1 07/27/2019 12:47 WG1318241 0.412 1.00 1 07/27/2019 12:47 WG1318241 0.230 1.00 1 07/27/2019 12:47 WG1318241 0.355 1.00 1 07/27/2019 12:47 WG1318241 0.319 1.00 1 07/27/2019 12:47 WG1318241 0.383 1.00 1 07/27/2019 12:47 WG1318241 0.398 1.00 1 07/27/2019 12:47 WG1318241 1.20 5.00 1 07/27/2019 12:47 WG1318241 0.807 2.50 1 07/27/2019 12:47 WG1318241 0.373 1.00 1 07/27/2019 12:47 WG1318241 0.321 1.00 1 07/27/2019 12:47 WG1318241 0.387 1.00 1 07/27/2019 12:47 WG1318241 0.259 1.00 1 07/27/2019 12:47 WG1318241 1.06 3.00 1 07/27/2019 12:47 WG1318241 80.0-120 071271201912:47 WG1318241 77.0-126 071271201912:47 WG1318241 70.0-130 071271201912:47 WG1318241 Fp FTc FS Fn FC] F ql FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 29 of 55 E B SAMPLE RESULTS - 10 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 11,00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U ter[-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 10.0 50.0 1 07/27/201913:06 WG1318241 8.87 50.0 1 07/27/201913:06 WG1318241 1.87 10.0 1 07/27/201913:06 WG1318241 0.331 1.00 1 07/27/201913:06 WG1318241 0.352 1.00 1 07/27/201913:06 WG1318241 0.380 1.00 1 07/27/201913:06 WG1318241 0.469 1.00 1 07/27/201913:06 WG1318241 0.866 5.00 1 07/27/201913:06 WG1318241 0.361 1.00 1 07/27/201913:06 WG1318241 0.365 1.00 1 07/27/201913:06 WG1318241 0.399 1.00 1 07/27/201913:06 WG1318241 0.379 1.00 1 07/27/201913:06 WG1318241 0.348 1.00 1 07/27/201913:06 WG1318241 0.327 1.00 1 07/27/201913:06 WG1318241 0.453 5.00 1 07/27/201913:06 WG1318241 0.324 5.00 1 07/27/201913:06 WG1318241 0.276 2.50 1 07/27/201913:06 WG1318241 0.375 1.00 1 07/27/201913:06 WG1318241 0.351 1.00 1 07/27/201913:06 WG1318241 1.33 5.00 1 07/27/201913:06 WG1318241 0.381 1.00 1 07/27/201913:06 WG1318241 0.346 1.00 1 07/27/201913:06 WG1318241 0.349 1.00 1 07/27/201913:06 WG1318241 0.220 1.00 1 07/27/201913:06 WG1318241 0.274 1.00 1 07/27/201913:06 WG1318241 0.551 5.00 1 07/27/201913:06 WG1318241 0.259 1.00 1 07/27/201913:06 WG1318241 0.361 1.00 1 07/27/201913:06 WG1318241 0.398 1.00 1 07/27/201913:06 WG1318241 0.260 1.00 1 07/27/201913:06 WG1318241 0.396 1.00 1 07/27/201913:06 WG1318241 0.306 1.00 1 07/27/201913:06 WG1318241 0.352 1.00 1 07/27/201913:06 WG1318241 0.366 1.00 1 07/27/201913:06 WG1318241 0.418 1.00 1 07/27/201913:06 WG1318241 0.419 1.00 1 07/27/201913:06 WG1318241 0.321 1.00 1 07/27/201913:06 WG1318241 0.320 1.00 1 07/27/201913:06 WG1318241 0.384 1.00 1 07/27/201913:06 WG1318241 0.256 1.00 1 07/27/201913:06 WG1318241 0.326 1.00 1 07/27/201913:06 WG1318241 0.350 1.00 1 07/27/201913:06 WG1318241 3.93 10.0 1 07/27/201913:06 WG1318241 1.00 5.00 1 07/27/201913:06 WG1318241 2.14 10.0 1 07/27/201913:06 WG1318241 0.367 1.00 1 07/27/201913:06 WG1318241 1.00 5.00 1 07/27/201913:06 WG1318241 0.349 1.00 1 07/27/201913:06 WG1318241 0.307 1.00 1 07/27/201913:06 WG1318241 0.385 1.00 1 07/27/201913:06 WG1318241 0.130 1.00 1 07/27/201913:06 WG1318241 0.303 1.00 1 07/27/201913:06 WG1318241 0.372 1.00 1 07/27/201913:06 WG1318241 0.412 1.00 1 07/27/201913:06 WG1318241 0.230 1.00 1 07/27/201913:06 WG1318241 0.355 1.00 1 07/27/201913:06 WG1318241 FP1 ITC] IS-S] 4 Cn FC] F q, rAl FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 30 of 55 ONE LAB. NATIONWIDE. EB SAMPLE RESULTS - 10 Collected date/time: 07/24/19 11:00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/201913:06 WG1318241 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/201913:06 WG1318241 Trichloroethene IJ 0.398 1.00 1 07/27/201913:06 WG1318241 Trichlorofluoromethane U 1.20 5.00 1 07/27/201913:06 WG1318241 1,2,3-Trichloropropane IJ 0.807 2.50 1 07/27/201913:06 WG1318241 1,2,4-Trimethylbenzene J 0.373 1.00 1 07/27/201913:06 WG1318241 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/201913:06 WG1318241 1,3,5-Trimethyl benzene J 0.387 1.00 1 07/27/201913:06 WG1318241 Vinyl chloride U 0.259 1.00 1 07/27/201913:06 WG1318241 Xylenes, Total J 1.06 3.00 1 07/27/201913:06 WG1318241 (S) Toluene-d8 108 80.0-120 071271201913:06 WG1318241 (S) 4-Bromof/uorobenzene 96.1 77.0-126 071271201913:06 WG1318241 (S)1,2-Dich/oroethone-d4 110 70.0-130 071271201913:06 WG1318241 Fp FTc FS Fn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 31 of 55 TRIP BLANK SAMPLE RESULTS - 11 ONE LAB. NATIONWIDE. Collected date/time: 07/24/19 00:00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Result Analyte ug/I Acetone U Acrolein U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromoform U Bromomethane U n-Butylbenzene U sec -Butyl benzene U ter[-Butylbenzene U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U Isopropylbenzene U p-Isopropyltoluene U 2-Butanone (MEK) U Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U n-Propylbenzene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U 1,1,2-Trichlorotrifluoroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U Qualifier MDL RDL Dilution Analysis Batch ug/I ug/I date / time 10.0 50.0 1 07/27/2019 08:48 WG1318241 8.87 50.0 1 07/27/2019 08:48 WG1318241 1.87 10.0 1 07/27/2019 08:48 WG1318241 0.331 1.00 1 07/27/2019 08:48 WG1318241 0.352 1.00 1 07/27/2019 08:48 WG1318241 0.380 1.00 1 07/27/2019 08:48 WG1318241 0.469 1.00 1 07/27/2019 08:48 WG1318241 0.866 5.00 1 07/27/2019 08:48 WG1318241 0.361 1.00 1 07/27/2019 08:48 WG1318241 0.365 1.00 1 07/27/2019 08:48 WG1318241 0.399 1.00 1 07/27/2019 08:48 WG1318241 0.379 1.00 1 07/27/2019 08:48 WG1318241 0.348 1.00 1 07/27/2019 08:48 WG1318241 0.327 1.00 1 07/27/2019 08:48 WG1318241 0.453 5.00 1 07/27/2019 08:48 WG1318241 0.324 5.00 1 07/27/2019 08:48 WG1318241 0.276 2.50 1 07/27/2019 08:48 WG1318241 0.375 1.00 1 07/27/2019 08:48 WG1318241 0.351 1.00 1 07/27/2019 08:48 WG1318241 1.33 5.00 1 07/27/2019 08:48 WG1318241 0.381 1.00 1 07/27/2019 08:48 WG1318241 0.346 1.00 1 07/27/2019 08:48 WG1318241 0.349 1.00 1 07/27/2019 08:48 WG1318241 0.220 1.00 1 07/27/2019 08:48 WG1318241 0.274 1.00 1 07/27/2019 08:48 WG1318241 0.551 5.00 1 07/27/2019 08:48 WG1318241 0.259 1.00 1 07/27/2019 08:48 WG1318241 0.361 1.00 1 07/27/2019 08:48 WG1318241 0.398 1.00 1 07/27/2019 08:48 WG1318241 0.260 1.00 1 07/27/2019 08:48 WG1318241 0.396 1.00 1 07/27/2019 08:48 WG1318241 0.306 1.00 1 07/27/2019 08:48 WG1318241 0.352 1.00 1 07/27/2019 08:48 WG1318241 0.366 1.00 1 07/27/2019 08:48 WG1318241 0.418 1.00 1 07/27/2019 08:48 WG1318241 0.419 1.00 1 07/27/2019 08:48 WG1318241 0.321 1.00 1 07/27/2019 08:48 WG1318241 0.320 1.00 1 07/27/2019 08:48 WG1318241 0.384 1.00 1 07/27/2019 08:48 WG1318241 0.256 1.00 1 07/27/2019 08:48 WG1318241 0.326 1.00 1 07/27/2019 08:48 WG1318241 0.350 1.00 1 07/27/2019 08:48 WG1318241 3.93 10.0 1 07/27/2019 08:48 WG1318241 1.00 5.00 1 07/27/2019 08:48 WG1318241 2.14 10.0 1 07/27/2019 08:48 WG1318241 0.367 1.00 1 07/27/2019 08:48 WG1318241 1.00 5.00 1 07/27/2019 08:48 WG1318241 0.349 1.00 1 07/27/2019 08:48 WG1318241 0.307 1.00 1 07/27/2019 08:48 WG1318241 0.385 1.00 1 07/27/2019 08:48 WG1318241 0.130 1.00 1 07/27/2019 08:48 WG1318241 0.303 1.00 1 07/27/2019 08:48 WG1318241 0.372 1.00 1 07/27/2019 08:48 WG1318241 0.412 1.00 1 07/27/2019 08:48 WG1318241 0.230 1.00 1 07/27/2019 08:48 WG1318241 0.355 1.00 1 07/27/2019 08:48 WG1318241 FP1 ITC] IS-S] 4 Cn FC] F q, rAl FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 32 of 55 ONE LAB. NATIONWIDE. TRIP BLANK SAMPLE RESULTS - 11 Collected date/time: 07/24/19 00:00 L1122118 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time 1,1,1-Trichloroethane U 0.319 1.00 1 07/27/2019 08:48 WG1318241 1,1,2-Trichloroethane U 0.383 1.00 1 07/27/2019 08:48 WG1318241 Trichloroethene U 0.398 1.00 1 07/27/2019 08:48 WG1318241 Trichlorofluoromethane U 1.20 5.00 1 07/27/2019 08:48 WG1318241 1,2,3-Trichloropropane U 0.807 2.50 1 07/27/2019 08:48 WG1318241 1,2,4-Trimethylbenzene J 0.373 1.00 1 07/27/2019 08:48 WG1318241 1,2,3-Trimethyl benzene U 0.321 1.00 1 07/27/2019 08:48 WG1318241 1,3,5-Trimethyl benzene J 0.387 1.00 1 07/27/2019 08:48 WG1318241 Vinyl chloride U 0.259 1.00 1 07/27/2019 08:48 WG1318241 Xylenes, Total J 1.06 3.00 1 07/27/2019 08:48 WG1318241 (S) Toluene-d8 105 80.0-120 0712712019 08.48 WG1318241 (S) 4-Bromof/uorobenzene 96.6 77.0-126 0712712019 08.48 WG1318241 (S)1,2-Dich/oroethane-d4 115 70.0-130 0712712019 08.48 WG1318241 Fp FTc FS Fn Fc F, FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 33 of 55 WG1318097 QUALITY CONTROL SUMMARY Wet Chemistry by Method 2320 B-2011 L1122118-01,02,03,04,06 Method Blank (MB) (MB) R3435195-1 07/29/19 09:58 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Alkalinity U 2710 20000 Sample Narrative: BLANK: Endpoint pH 4.5 L1121437-01 Original Sample (OS) • Duplicate (DUP) (OS) L1121437-01 07/29/1910:44 • (DUP) R3435195-2 07/29/19 10:53 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 54600 54800 1 0.321 20 Sample Narrative: OS: Endpoint pH 4.5 DUP: Endpoint pH 4.5 L1122118-03 Original Sample (OS) • Duplicate (DUP) (OS) L1122118-03 07/29/1912:57 • (DUP) R3435195-4 07/29/1913:11 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Alkalinity 156000 160000 1 2.42 20 Sample Narrative: OS: Endpoint pH 4.5 DUP: Endpoint pH 4.5 Laboratory Control Sample (LCS) (LCS) R3435195-3 07/29/1911:17 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Alkalinity 100000 107000 107 85.0-115 Sample Narrative: LCS: Endpoint pH 4.5 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 34 of 55 WG1321133 Wet Chemistry by Method 35001'e B-2011 Method Blank (MB) (MB) R3436494-1 08/01/1915:01 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Ferrous Iron U 15.0 L1122118-03 Original Sample (OS) • Duplicate (DUP) MB RDL ug/1 50.0 QUALITY CONTROL SUMMARY L1122118-01,02,03,04,06 (OS) L1122118-03 08/01/1915:05 • (DUP) R3436494-5 08/01/1915:06 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Ferrous Iron 35.0 40.0 1 13.3 J 20 Laboratory Control Sample (LCS) (LCS) R3436494-2 08/01/1915:01 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Ferrous Iron 1000 1040 104 85.0-115 L1122118-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122118-02 08/01/1915:04 • (MS) R3436494-3 08/01/1915:04 • (MSD) R3436494-4 08/01/1915:05 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Ferrous Iron 1000 488 1480 1550 98.8 107 1 80.0-120 5.08 ONE LAB. NATIONWIDE. RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 35 of 55 WG1318879 QUALITY CONTROL SUMMARY Wet Chemistry by Method 410.4 L1122118-01,02,03,04,06 Method Blank (MB) (MB) R3435262-1 07/29/1913:13 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I COD U 3000 10000 L1122118-01 Original Sample (OS) • Duplicate (DUP) (OS) L1122118-01 07/29/1913:15 • (DUP) R3435262-3 07/29/1913:15 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % COD U 0.000 1 0.000 20 L1122987-03 Original Sample (OS) • Duplicate (DUP) (OS) L1122987-03 07/29/1913:21 • (DUP) R3435262-6 07/29/19 13:21 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % COD 64300 62900 1 2.11 20 Laboratory Control Sample (LCS) (LCS) R3435262-2 07/29/1913:14 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % COD 222000 224000 101 90.0-110 L1122308-09 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122308-09 07/29/1913:17 • (MS) R3435262-4 07/29/1913:17 • (MSD) R3435262-5 07/29/1913:18 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % COD 400000 ND 458000 456000 115 114 1 80.0-120 0.571 ONE LAB. NATIONWIDE. RPD Limits 20 — I Cp FTc FSS 4 — Cn FSr — �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 36 of 55 WG1317178 Wet Chemistry by Method 450052 D-2011 Method Blank (MB) (MB) R3434406-1 07/25/1917:43 MB Result MB Qualifier MB MDL Analyte ug/I ug/I Sulfide U 6.50 L1122118-01 Original Sample (OS) • Duplicate (DUP) MB RDL ug/1 50.0 QUALITY CONTROL SUMMARY L1122118-01,02,03,04,06 (OS) L1122118-01 07/25/1917:48 • (DUP) R3434406-5 07/25/1917:48 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I _ % % Sulfide U 0.000 1 0,000 20 L1122118-04 Original Sample (OS) • Duplicate (DUP) (OS) L1122118-04 07/25/1917:50 • (DUP) R3434406-6 07/25/1917:51 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Sulfide U 0.000 1 0.000 20 Laboratory Control Sample (LCS) (LCS) R3434406-2 07/25/1917:43 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % Sulfide 500 466 93.2 Rec. Limits LCS Qualifier 85.0-115 L1122061-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122061-01 07/25/1917:47 • (MS) R3434406-3 07/25/1917:47 • (MSD) R3434406-4 07/25/1917:47 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % Sulfide 1000 ND 894 896 89.4 89.6 1 80.0-120 0.223 ONE LAB. NATIONWIDE. RPD Limits 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 37 of 55 WG1317316 QUALITY CONTROL SUMMARY Wet Chemistry by Method 5210 B-2011 L1122118-01,02,04,06 Method Blank (MB) (MB) R3435641-1 07/30/1912:03 MB Result MB Qualifier MB MDL MB RDL Analyte mg/I mg/1 mg/I BOD U 0.2 0.200 L1121818-01 Original Sample (OS) • Duplicate (DUP) (OS) L1121818-01 07/30/19 09:42 • (DUP) R3435641-5 07/30/19 09:43 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/I mg/I % % BOD 21.4 21.6 1 1 30 L1122108-03 Original Sample (OS) • Duplicate (DUP) (OS) L1122108-03 07/30/1911:05 • (DUP) R3435641-6 07/30/19 11:07 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte mg/I mg/I % % BOD ND 0.000 1 0 30 Laboratory Control Sample (LCS) (LCS) R3435641-2 07/30/19 09:33 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I % % BOD 198 146 73.9 84.6-115 J- Laboratory Control Sample (LCS) (LCS) R3435641-3 07/30/1911:35 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I % % 30D 198 170 86 84.6-115 Laboratory Control Sample (LCS) (LCS) R3435641-4 07/30/1912:00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I % % BOD 198 185 93.3 84.6-115 ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 ONE LAB. NATIONWIDE. SDG: DATE/TIME: PAGE: L1122118 08/05/1915:44 38 of 55 M WG1320384 Wet Chemistry by Method 5210 B-2011 Method Blank (MB) (MB) R3437389-1 08/05/1911:18 MB Result Analyte mg/I BOD U MB Qualifier MB MDL MB RDL Mg/1 mg/I 0.2 0.200 Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY L1122118-03 (LCS) R3437389-2 08/05/19 09:00 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte mg/I mg/I % % BOD 198 149 75.3 84.6-115 J- Laboratory Control Sample (LCS) (LCS) R3437389-3 08/05/1910:25 Spike Amount LCS Result LCS Rec. Analyte mg/I mg/I % BOD 198 172 87 Laboratory Control Sample (LCS) (LCS) R3437389-4 08/05/1911:14 Spike Amount LCS Result LCS Rec. Analyte mg/I mg/I % BOD 198 152 76.9 Rec. Limits LCS Qualifier 84.6-115 Rec. Limits LCS Qualifier 84.6-115 J- ONE LAB. NATIONWIDE. — I Cp FTc FSS 4 — Cn FSr — �GI — $AI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 39 of 55 WG1317503 Wet Chemistry by Method 9056A Method Blank (MB) (MB) R3434469-1 07/25/19 08:32 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Chloride U 51.9 1000 Nitrate U 22.7 100 Sulfate 766 J 77.4 5000 L1122125-04 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1122118-01,02,03,04,06 (OS) L1122125-04 07/25/1915:18 • (DUP) R3434469-3 07/25/1915:33 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Chloride 20400 20600 1 0.736 15 Nitrate ND 0.000 1 0.000 15 Sulfate 32500 34000 1 4.31 15 L1122118-06 Original Sample (OS) • Duplicate (DUP) (OS) L1122118-06 07/25/1919:01 • (DUP) R3434469-6 07/25/19 19:46 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Chloride 1950 1860 1 4.99 15 Nitrate U 0.000 1 0.000 15 Sulfate 4070 5650 1 32.6 P1 15 Laboratory Control Sample (LCS) (LCS) R3434469-2 07/25/19 08:46 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Chloride 40000 40300 101 80.0-120 Nitrate 8000 8320 104 80.0-120 Sulfate 40000 42400 106 80.0-120 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 40 of 55 WG1317503 QUALITY CONTROL SUMMARY Wet Chemistry by Method 9056A L1122118-01,02,03,04,06 L1122125-04 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. (OS) L1122125-04 07/25/1915:18 • (MS) R3434469-4 07/25/1915:48 • (MSD) R3434469-5 07/25/1916:02 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % Chloride 50000 20400 70700 70900 101 101 1 80.0-120 0.215 15 Nitrate 5000 ND 5010 5060 100 101 1 80.0-120 0.941 15 Sulfate 50000 32500 80900 81100 96.8 97.1 1 80.0-120 0.179 15 L1122118-06 Original Sample (OS) • Matrix Spike (MS) (OS) L1122118-06 07/25/1919:01 • (MS) R3434469-7 07/25/19 20:01 Spike Amount Original Result MS Result MS Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I ug/I ug/I % % Chloride 50000 1950 53000 102 1 80.0-120 Nitrate 5000 U 5090 102 1 80.0-120 Sulfate 50000 4070 57200 106 1 80.0-120 FP1 FTC FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 41 of 55 WG1318069 Wet Chemistry by Method 9060A Method Blank (MB) (MB) R3434872-1 07/26/1916:46 MB Result MB Qualifier MB MDL Analyte ug/I ug/I TOC (Total Organic Carbon) 442 J 102 L1122118-01 Original Sample (OS) • Duplicate (DUP) MB ROL ug/I 1000 QUALITY CONTROL SUMMARY L1122118-01,02,03,04,06 (OS) L1122118-01 07/26/1917:46 • (DUP) R3434872-3 07/26/1917:58 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC 1380 1350 1 1.90 20 L1122308-14 Original Sample (OS) • Duplicate (DUP) (OS) L1122308-14 07/27/19 00:50 • (DUP) R3434872-8 07/27/19 01:08 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % TOC 7640 7590 1 0.644 20 Laboratory Control Sample (LCS) (LCS) R3434872-2 07/26/1917:19 Spike Amount LCS Result LCS Rec. Analyte ug/I ug/I % TOC 75000 75500 101 Rec. Limits LCS Qualifier 85.0-115 L1122118-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122118-06 07/26/1918:57 • (MS) R3434872-4 07/26/19 20:18 • (MSD) R3434872-5 07/26/19 20:38 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD Analyte ug/I ug/I ug/I ug/I % % % % TOC 50000 1370 50700 49500 98.6 96.3 1 80.0-120 2.32 L1122125-06 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) ONE LAB. NATIONWIDE. RPD Limits 20 (OS) L1122125-06 07/26/19 22:09 • (MS) R3434872-6 07/26/19 22:26 • (MSD) R3434872-7 07/26/19 23:42 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier MSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I ug/I % % % % % TOC 50000 11300 62800 60600 103 98.7 1 80.0-120 3.47 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 42 of 55 WG1317659 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Metals (ICP) by Method 6010D L1122118-01 Method Blank (MB) Cp (MB) R3434659-1 07/26/19 09:48 MB Result MB Qualifier MB MDL MB RDL 2 Analyte ug/I ug/I ug/I TC Antimony U 7.50 10.0 Arsenic U 6.50 10.0 E Barium U 1.70 5.00 Beryllium U 0.700 2.00 Cadmium U 0.700 2.00 FCn Chromium U 1.40 10.0 Cobalt U 2.30 10.0 E Copper U 5.30 10.0 Lead U 1.90 5.00 Nickel U 4.90 10.0 ce Selenium U 7.40 10.0 Silver U 2.80 5.00 FG I Thallium U 6.50 10.0 Vanadium U 2.40 20.0 Zinc U 5.90 50.0 rA I Laboratory Control Sample Laboratory Control Sample Duplicate E (LCS) • (LCSD) (LCS) R3434659-2 07/26/19 09:50 • (LCSD) R3434659-3 07/26/19 09:53 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Antimony 1000 964 991 96.4 99.1 80.0-120 2.74 20 Arsenic 1000 947 983 94.7 98.3 80.0-120 3.67 20 Barium 1000 1000 1040 100 104 80.0-120 4.11 20 Beryllium 1000 976 1010 97.6 101 80.0-120 3.57 20 Cadmium 1000 984 1020 98.4 102 80.0-120 3.51 20 Chromium 1000 933 973 93.3 97.3 80.0-120 4.21 20 Cobalt 1000 1000 1040 100 104 80.0-120 3.87 20 Copper 1000 952 990 95.2 99.0 80.0-120 3.94 20 Lead 1000 980 1020 98.0 102 80.0-120 3.68 20 Nickel 1000 994 1030 99.4 103 80.0-120 3.94 20 Selenium 1000 957 982 95.7 98.2 80.0-120 2.63 20 Silver 200 166 171 82.8 85.7 80.0-120 3.49 20 Thallium 1000 991 1000 99.1 100 80.0-120 1.21 20 Vanadium 1000 974 1020 97.4 102 80.0-120 4.66 20 Zinc 1000 962 997 96.2 99.7 80.0-120 3.57 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 43 of 55 WG1317659 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1122118-01 L1122070-01 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122070-01 07/26/19 09:56 • (MS) R3434659-5 07/26/19 10:01 • (MSD) R3434659-6 07/26/1910:04 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Dilution Rec. Limits MS Qualifier Analyte ug/I ug/I ug/I ug/I % % % Antimony 1000 ND 1020 985 102 98.5 1 75.0-125 Arsenic 1000 ND 1010 995 101 99.5 1 75.0-125 Barium 1000 58.7 1090 1080 103 102 1 75.0-125 Beryllium 1000 ND 1000 1010 100 101 1 75.0-125 Cadmium 1000 ND 1030 1020 103 102 1 75.0-125 Chromium 1000 ND 955 964 95.5 96.4 1 75.0-125 Cobalt 1000 ND 1050 1040 105 104 1 75.0-125 Copper 1000 ND 978 982 97.8 98.2 1 75.0-125 Lead 1000 ND 1020 1010 102 101 1 75.0-125 Nickel 1000 ND 1040 1030 104 103 1 75.0-125 Selenium 1000 ND 1020 1000 102 100 1 75.0-125 Silver 200 ND 172 172 86.2 86.0 1 75.0-125 Thallium 1000 ND 1070 1080 107 108 1 75.0-125 Vanadium 1000 ND 1020 1020 102 102 1 75.0-125 Zinc 1000 ND 998 985 99.8 98.5 1 75.0-125 MSD Qualifier RPD 3.31 1.49 0.603 0.690 1.35 0.900 1.05 0.336 1.23 0.874 1.52 0.165 0.262 0.0612 1.31 ONE LAB. NATIONWIDE. RPD Limits o� 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 FP1 FTc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 44 of 55 WG1318465 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Metals (ICP) by Method 6010D L1122118-02,03,04,05,06,07,08,09 Method Blank (MB) Cp (MB) R3435451-1 07/29/1915:33 MB Result MB Qualifier MB MDL MB RDL 2 Analyte ug/I ug/I ug/I TC Antimony U 7.50 10.0 Arsenic U 6.50 10.0 E Barium U 1.70 5.00 Beryllium U 0.700 2.00 Cadmium U 0.700 2.00 FCn Chromium U 1.40 10.0 Cobalt U 2.30 10.0 E Copper U 5.30 10.0 Lead U 1.90 5.00 Nickel U 4.90 10.0 ce Selenium U 7.40 10.0 Silver U 2.80 5.00 FG I Thallium U 6.50 10.0 Vanadium U 2.40 20.0 Zinc U 5.90 50.0 rA I Laboratory Control Sample Laboratory Control Sample Duplicate E (LCS) • (LCSD) (LCS) R3435451-2 07/29/1915:35 • (LCSD) R3435451-3 07/29/1915:38 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Antimony 1000 997 1000 99.7 100 80.0-120 0.225 20 Arsenic 1000 970 965 97.0 96.5 80.0-120 0.462 20 Barium 1000 1050 1050 105 105 80.0-120 0.378 20 Beryllium 1000 992 997 99.2 99.7 80.0-120 0.438 20 Cadmium 1000 997 1000 99.7 100 80.0-120 0.441 20 Chromium 1000 990 988 99.0 98.8 80.0-120 0.234 20 Cobalt 1000 1020 1020 102 102 80.0-120 0.369 20 Copper 1000 979 981 97.9 98.1 80.0-120 0.239 20 Lead 1000 992 993 99.2 99.3 80.0-120 0.179 20 Nickel 1000 1010 1010 101 101 80.0-120 0.479 20 Selenium 1000 985 990 98.5 99.0 80.0-120 0.556 20 Silver 200 197 195 98.6 97.6 80.0-120 1.01 20 Thallium 1000 1020 1000 102 100 80.0-120 1.46 20 Vanadium 1000 1010 998 101 99.8 80.0-120 0.711 20 Zinc 1000 974 978 97.4 97.8 80.0-120 0.401 20 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 45 of 55 WG1318465 QUALITY CONTROL SUMMARY Metals (ICP) by Method 6010D L1122118-02,03,04,05,06,07,08,09 L1122118-02 Original Sample (OS) • Matrix Spike (MS) • Matrix Spike Duplicate (MSD) (OS) L1122118-02 07/29/1915:41 • (MS) R3435451-5 07/29/1915:46 • (MSD) R3435451-6 07/29/1915:49 Spike Amount Original Result MS Result MSD Result MS Rec. MSD Rec. Analyte ug/I ug/I ug/I ug/I % % Antimony 1000 U 1000 1020 100 102 Arsenic 1000 U 975 1000 97.5 100 Barium 1000 208 1240 1260 103 106 Beryllium 1000 U 992 1020 99.2 102 Cadmium 1000 2.94 999 1020 99.6 102 Chromium 1000 4.69 976 1010 97.2 100 Cobalt 1000 9.60 1030 1060 102 105 Copper 1000 16.9 987 1010 97.0 99.7 Lead 1000 6.12 990 1010 98.4 101 Nickel 1000 5.37 1020 1040 101 104 Selenium 1000 U 994 1020 99.4 102 Silver 200 U 196 201 98.1 101 Thallium 1000 U 985 1040 98.5 104 Vanadium 1000 51.8 1050 1070 99.3 102 Zinc 1000 592 1530 1560 94.3 97.0 Dilution Rec. Limits MS Qualifier 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 75.0-125 MSD Qualifier RPD 1.58 2.47 2.30 2.33 2.03 2.98 2.11 2.69 2.42 2.51 2.32 2.61 5.62 2.33 1.78 ONE LAB. NATIONWIDE. RPD Limits o� 20 20 20 20 20 20 20 20 20 20 20 20 20 20 20 FP1 FTc FSS 4 Cn FSr �GI FAI FSC ACCOUNT: PROJECT: Withers & Ravenel Eng. - Standard 06140180.24 SDG: L1122118 DATE/TIME: 08/05/1915:44 PAGE: 46 of 55 WG1318305 Volatile Organic Compounds (GC) by Method RSK175 Method Blank (MB) (MB) R3434864-1 07/27/19 05:27 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Methane U 2.91 10.0 Ethane U 4.07 13.0 Ethene U 4.26 13.0 L1122118-01 Original Sample (OS) • Duplicate (DUP) QUALITY CONTROL SUMMARY L1122118-01,02,03,04,06 (OS) L1122118-01 07/27/19 05:32 • (DUP) R3434864-2 07/27/19 06:02 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Methane 3700 3600 1 2.67 20 Ethane U 0.000 1 0.000 20 Ethene U 0.000 1 0.000 20 L1122268-06 Original Sample (OS) • Duplicate (DUP) (OS) L1122268-06 07/27/19 06:04 • (DUP) R3434864-3 07/27/19 06:36 Original Result DUP Result Dilution DUP RPD DUP Qualifier DUP RPD Limits Analyte ug/I ug/I % % Methane ND 0.000 1 0.000 20 Ethane ND 0.000 1 0.000 20 Ethene ND 0.000 1 0.000 20 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3434864-4 07/27/19 06:38 • (LCSD) R3434864-5 07/27/19 06:42 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % Methane 67.8 70.7 74.7 104 110 85.0-115 5.49 20 Ethane 129 117 120 90.6 92.7 85.0-115 2.29 20 Ethene 127 116 119 91.5 93.7 85.0-115 2.35 20 ONE LAB. NATIONWIDE. FP1 FTc FSS 4 Cn FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 47 of 55 WG1318241 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1122118-01,02,03,04,05,06,07,08,09,10,11 Method Blank (MB) (MB) R3435409-4 07/27/19 07:38 MB Result Analyte ug/I MB Qualifier MB MDL MB RDL ug/I ug/I Acetone U 10.0 50.0 Acrolein U 8.87 50.0 Acrylonitrile U 1.87 10.0 Benzene U 0.331 1.00 Bromobenzene U 0.352 1.00 Bromodichloromethane U 0.380 1.00 Bromoform U 0.469 1.00 Bromomethane U 0.866 5.00 n-Butylbenzene U 0.361 1.00 sec -Butyl benzene U 0.365 1.00 tert-Butylbenzene U 0.399 1.00 Carbon tetrachloride U 0.379 1.00 Chlorobenzene U 0.348 1.00 Chlorodibromomethane U 0.327 1.00 Chloroethane U 0.453 5.00 Chloroform U 0.324 5.00 Chloromethane U 0.276 2.50 2-Chlorotoluene U 0.375 1.00 4-Chlorotoluene U 0.351 1.00 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1,2-Dibromoethane U 0.381 1.00 Dibromomethane U 0.346 1.00 1,2-Dichlorobenzene U 0.349 1.00 1,3-Dichlorobenzene U 0.220 1.00 1,4-Dichlorobenzene U 0.274 1.00 Dichlorodifluoromethane U 0.551 5.00 1,1-Dichloroethane U 0.259 1.00 1,2-Dichloroethane U 0.361 1.00 1,1-Dichloroethene U 0.398 1.00 cis-1,2-Dichloroethene U 0.260 1.00 trans-1,2-Dichloroethene U 0.396 1.00 1,2-Dichloropropane U 0.306 1.00 1,1-Dichloropropene U 0.352 1.00 1,3-Dichloropropane U 0.366 1.00 cis-1,3-Dichloropropene U 0.418 1.00 trans-1,3-Dichloropropene U 0.419 1.00 2,2-Dichloropropane U 0.321 1.00 Di -isopropyl ether U 0.320 1.00 Ethylbenzene U 0.384 1.00 Hexachloro-1,3-butadiene U 0.256 1.00 ACCOUNT: Withers & Ravenel Eng. - Standard PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1122118 08/05/1915:44 48 of 55 FP1 FTC FSS [Cn] FSr �GI FAI FSC WG1318241 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1122118-01,02,03,04,05,06,07,08,09,10,11 Method Blank (MB) (MB) R3435409-4 07/27/19 07:38 MB Result MB Qualifier MB MDL MB RDL Analyte ug/I ug/I ug/I Isopropylbenzene U 0.326 1.00 p-Isopropyltoluene U 0.350 1.00 2-Butanone (MEK) U 3.93 10.0 Methylene Chloride U 1.00 5.00 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 Methyl tert-butyl ether U 0.367 1.00 Naphthalene U 1.00 5.00 n-Propylbenzene U 0.349 1.00 Styrene U 0.307 1.00 1,1,1,2-Tetrachloroethane U 0.385 1.00 1,1,2,2-Tetrachloroethane U 0.130 1.00 Tetrachloroethene U 0.372 1.00 Toluene U 0.412 1.00 1,1,2-Trichlorotrifluoroethane U 0.303 1.00 1,2,3-Trichlorobenzene U 0.230 1.00 1,2,4-Trichlorobenzene U 0.355 1.00 1,1,1-Trichloroethane U 0.319 1.00 1,1,2-Trichloroethane U 0.383 1.00 Trichloroethene U 0.398 1.00 Trichlorofluoromethane U 1.20 5.00 1,2,3-Trichloropropane U 0.807 2.50 1,2,3-Trimethyl benzene U 0.321 1.00 1,2,4-Trimethylbenzene U 0.373 1.00 1,3,5-Trimethyl benzene U 0.387 1.00 Vinyl chloride U 0.259 1.00 Xylenes, Total U 1.06 3.00 (S) Toluene-d8 107 80.0-120 (S) 4-Bromof/uorobenzene 96.6 77.0-126 (S)1,2-Dich/oroethone-d4 107 70.0-130 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3435409-1 07/27/19 06:18 • (LCSD) R3435409-2 07/27/19 06:38 Spike Amount LCS Result LCSD Result LCS Rec. Analyte ug/I ug/I ug/I % Acetone 125 112 119 89.7 Acrolein 125 155 143 124 Acrylonitrile 125 118 115 94.0 Benzene 25.0 23.9 24.1 95.7 LCSD Rec. Rec. Limits 95.3 19.0-160 115 10.0-160 91.9 55.0-149 96.3 70.0-123 LCS Qualifier LCSD Qualifier RPD 6.01 7.53 2.29 0.681 RPD Limits 27 26 20 20 FP1 FTc FSS [Cn] FSr �GI FAI [Sc ACCOUNT: PROJECT: SDG: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 DATE/TIME: 08/05/1915:44 PAGE: 49 of 55 WG1318241 QUALITY CONTROL SUMMARY Volatile Organic Compounds (GC/MS) by Method 8260D L1122118-01,02,03,04,05,06,07,08,09,10,11 ONE LAB. NATIONWIDE. Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) (LCS) R3435409-1 07/27/19 06:18 • (LCSD) R3435409-2 07/27/19 06:38 Spike Amount LCS Result LCSD Result LCS Rec. Analyte ug/I ug/I ug/I % Bromobenzene 25.0 22.6 22.9 90.3 Bromodichloromethane 25.0 26.4 26.7 106 Bromoform 25.0 24.5 23.7 98.1 Bromomethane 25.0 26.2 26.5 105 n-Butylbenzene 25.0 24.7 24.9 98.7 sec -Butyl benzene 25.0 24.1 24.7 96.4 tert-Butylbenzene 25.0 24.8 25.3 99.1 Carbon tetrachloride 25.0 27.2 27.6 109 Chlorobenzene 25.0 24.8 24.2 99.0 Chlorodibromomethane 25.0 26.3 26.1 105 Chloroethane 25.0 26.8 26.8 107 Chloroform 25.0 23.4 23.4 93.7 Chloromethane 25.0 29.4 29.3 118 2-Chlorotoluene 25.0 24.5 24.9 97.9 4-Chlorotoluene 25.0 24.5 25.1 97.8 1,2-Dibromo-3-Chloropropane 25.0 21.0 21.3 83.8 1,2-Dibromoethane 25.0 26.5 25.8 106 Dibromomethane 25.0 25.6 25.4 102 1,2-Dichlorobenzene 25.0 23.8 24.6 95.1 1,3-Dichlorobenzene 25.0 24.2 24.7 96.7 1,4-Dichlorobenzene 25.0 23.3 23.9 93.2 Dichlorodifluoromethane 25.0 29.7 29.7 119 1,1-Dichloroethane 25.0 25.0 25.2 99.8 1,2-Dichloroethane 25.0 24.5 24.7 97.9 1,1-Dichloroethene 25.0 24.1 24.5 96.2 cis-1,2-Dichloroethene 25.0 23.9 23.8 95.6 trans-1,2-Dichloroethene 25.0 24.3 24.1 97.3 1,2-Dichloropropane 25.0 26.1 26.3 105 1,1-Dichloropropene 25.0 25.3 25.6 101 1,3-Dichloropropane 25.0 26.5 26.0 106 cis-1,3-Dichloropropene 25.0 26.3 26.5 105 trans-1,3-Dichloropropene 25.0 25.8 25.6 103 2,2-Dichloropropane 25.0 22.4 22.3 89.6 Di -isopropyl ether 25.0 26.5 26.6 106 Ethylbenzene 25.0 24.7 24.7 98.6 Hexachloro-1,3-butadiene 25.0 24.8 25.6 99.1 Isopropylbenzene 25.0 24.9 24.5 99.5 p-Isopropyltoluene 25.0 24.3 24.8 97.3 2-Butanone (MEK) 125 125 125 100 Methylene Chloride 25.0 22.7 22.5 90.8 ACCOUNT: Withers & Ravenel Eng. - Standard LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits 91.6 73.0-121 1.42 20 107 75.0-120 1.33 20 94.9 68.0-132 3.31 20 106 10.0-160 1.12 25 99.7 73.0-125 1.02 20 98.7 75.0-125 2.41 20 101 76.0-124 2.10 20 110 68.0-126 1.48 20 96.8 80.0-121 2.32 20 104 77.0-125 0.844 20 107 47.0-150 0.0589 20 93.6 73.0-120 0.159 20 117 41.0-142 0.400 20 99.6 76.0-123 1.69 20 100 75.0-122 2.59 20 85.2 58.0-134 1.58 20 103 80.0-122 2.68 20 102 80.0-120 0.711 20 98.6 79.0-121 3.56 20 98.7 79.0-120 2.04 20 95.4 79.0-120 2.29 20 119 51.0-149 0.211 20 101 70.0-126 1.16 20 98.8 70.0-128 0.949 20 97.8 71.0-124 1.68 20 95.4 73.0-120 0.213 20 96.3 73.0-120 1.03 20 105 77.0-125 0.504 20 102 74.0-126 0.970 20 104 80.0-120 1.84 20 106 80.0-123 0.948 20 102 78.0-124 0.866 20 89.1 58.0-130 0.612 20 106 58.0-138 0.295 20 98.7 79.0-123 0.119 20 102 54.0-138 3.30 20 97.9 76.0-127 1.64 20 99.3 76.0-125 2.07 20 100 44.0-160 0.121 20 90.1 67.0-120 0.795 20 PROJECT: SDG: DATE/TIME: PAGE: 06140180.24 L1122118 08/05/1915:44 50 of 55 FP1 FTC FSS [Cn] FSr �GI FAI FSC WG1318241 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1122118-01,02,03,04,05,06,07,08,09,10,11 Laboratory Control Sample (LCS) • Laboratory Control Sample Duplicate (LCSD) FP1(LCS) R3435409-1 07/27/19 06:18 • (LCSD) R3435409-2 07/27/19 06:38 Spike Amount LCS Result LCSD Result LCS Rec. LCSD Rec. Rec. Limits LCS Qualifier LCSD Qualifier RPD RPD Limits Analyte ug/I ug/I ug/I % % % % % z TC 4-Methyl-2-pentanone(MIBK) 125 127 123 101 98.0 68.0-142 3.34 20 Methyl tert-butyl ether 25.0 21.0 20.6 83.8 82.5 68.0-125 1.53 20 FSS Naphthalene 25.0 23.3 23.4 93.3 93.7 54.0-135 0.426 20 n-Propylbenzene 25.0 24.7 25.2 99.0 101 77.0-124 1.94 20 Styrene 25.0 25.9 24.9 104 99.7 73.0-130 4.02 20 [Cn] 1,1,1,2-Tetrachloroethane 25.0 23.7 22.9 94.7 91.6 75.0-125 3.32 20 1,1,2,2-Tetrachloroethane 25.0 22.3 22.0 89.1 88.1 65.0-130 1.17 20 FSr Tetrachloroethene 25.0 26.2 25.5 105 102 72.0-132 2.65 20 Toluene 25.0 24.1 23.8 96.3 95.1 79.0-120 1.30 20 1,1,2-Trichlorotrifluoroethane 25.0 22.5 22.3 89.9 89.4 69.0-132 0.575 20 1,2,3-Trichlorobenzene 25.0 25.0 25.7 100 103 50.0-138 2.61 20 1,2,4-Trichlorobenzene 25.0 24.7 24.9 99.0 99.7 57.0-137 0.712 20 7G1 1,1,1-Trichloroethane 25.0 27.4 27.3 110 109 73.0-124 0.519 20 1,1,2-Trichloroethane 25.0 26.9 26.2 108 105 80.0-120 2.67 20 Trichloroethene 25.0 26.5 27.1 106 108 78.0-124 2.14 20 FAI Trichlorofluoromethane 25.0 26.5 27.0 106 108 59.0-147 1.68 20 1,2,3-Trichloropropane 25.0 23.8 23.7 95.3 94.9 73.0-130 0.373 20 FSC 1,2,3-Trimethylbenzene 25.0 24.1 24.6 96.4 98.4 77.0-120 1.99 20 1,2,4-Trimethylbenzene 25.0 23.6 24.0 94.5 96.1 76.0-121 1.74 20 1,3,5-Trimethyl benzene 25.0 24.3 25.1 97.2 100 76.0-122 3.08 20 Vinyl chloride 25.0 28.3 28.5 113 114 67.0-131 0.789 20 Xylenes, Total 75.0 72.0 70.7 96.0 94.3 79.0-123 1.82 20 (S) Toluene-d8 108 107 80.0-120 (S) 4-Bromof/uorobenzene 98.9 97.3 77.0-126 (S)1,2-Dich/oroethane-d4 ill 114 70.0-130 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 51 of 55 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE. The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Results Disclaimer - Information that may be provided by the customer, and contained within this report, include Permit Limits, Project Name, Sample ID, Sample Matrix, Sample Preservation, Field Blanks, Field Spikes, Field Duplicates, On -Site Data, Sampling Collection Dates/Times, and Sampling Location. Results relate to the accuracy of this information provided, and as the samples are received. Abbreviations and Definitions CP IP FTC FSS MDL Method Detection Limit. ND Not detected at the Reporting Limit (or MDL where applicable). [Cn] RDL Reported Detection Limit. Rec. Recovery. FSr RPD Relative Percent Difference. SDG Sample Delivery Group. Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and 6 QC (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the a Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. FSC These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or duplicated within these ranges. Original Sample The non -spiked sample in the prep batch used to determine the Relative Percent Difference (RPD) from a quality control sample. The Original Sample may not be included within the reported SDG. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description B The same analyte is found in the associated blank. H The indicated analytical results were generated from a reinjection of the same sample extract or aliquot. J The identification of the analyte is acceptable; the reported value is an estimate. J- The associated batch QC was outside the lower control limits; associated data has a potential negative bias. K1 The sample dilutions set-up for the BOD/CBOD analysis did not meet the oxygen depletion criteria of at least 2 mg/L. Reported result is an estimated value. K6 Glucose/glutamic acid BOD/CBOD was below method acceptance criteria. P1 RPD value not applicable for sample concentrations less than 5 times the reporting limit. Q Sample was prepared and/or analyzed past holding time as defined in the method. Concentrations should be considered minimum values. T8 Sample(s) received past/too close to holding time expiration. ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: 08/05/1915:44 52 of 55 Withers & Ravenel Eng. - Standard 06140180.24 L1122118 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA ME MT NO OR MN T ID t WI NY SD WY MI NV t NE IA OH PA T f IL Ills WV vA UT T CA�� T KS MO KY N NM O� AR SC T MS AL`7GA T TX * LA T AK q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Withers & Ravenel Eng. - Standard 06140180.24 L1122118 08/05/1915:44 53 of 55 I BillingInformation: Analysis Container / Preservative Chain of Custody Page of Withers & Ravenel Eng. - Standard Accounts Payable PreS 215 MacKenan Drive Chk G ' 115 MacKenan Drive Cary, NC 27511 Cary, NC 27511 a, 120651ebanon Rd �i Report to: Email To: lellion@vvithersrawnel.com Laura Elliott o xbuel,uikt rx 9),:2 Z w 6. V Q Phone: 615-058-5858 - Phnne: SM767-5859 '�''a fax 61S Iss 1859 I] y Project City/Stat¢ \ Description: Kernersville Landfill Colected: �E �L o 0 2 + S L g l IQ z VV Phone:919-469-3340 Client Project # Lab Project # Fax: 919-467-6008 �140180.24 WITHRAVS-KERNERSVILL 2 0 0 E D242 O m 0 Collected by (print): Site/Facility t ID # P.O. # E'o p = U 2 a 00 _ = Acctnum: WITHRAVS o t ? W w c Q ^l a d iem Iate:T153277 P Collected by (signature): Rush? (Lab MUST Be Notified) QUOte# Same Day _Five Day Li N U v p LL O a E I Q Q Prelogin: P720388 Next Day _ 5 Day (Rad Only) Date Results Needed io 0 V _ ^1 O TSR: 873-HeatheU Wagner r(����/ny/,y� ediately Two Day _10 Day front Only) No. N ti O C w O Packed on Ice N _ Y _Three Day of ^� Z J O ry O n Y O 1N Lu O O LO C O W PB: ntrs Shippedvia:FedEX Ground Sample lD Comp/Grab Matrix Depth Date Time 1< OV aema.h SamPiexllah nnivl Q DO K N 0 > > W - GW .� �, v V v ✓ v ✓ ✓ -0 S. GW L41 ekIO: M V✓ v ✓ ✓ ✓ 0 �. GW 4 Z ✓ v v ✓ ✓ ✓ ✓ GW 11 1 ✓ ✓ / ✓ o 1� r GW 1 V U o r GW ✓ ✓ V ✓ ✓ I ✓ ✓ ✓ 1 -0i GW 14 A II'.S7 -r11 vi GW Cr ✓ ' Q�Sy GW -i lv4 il 11. iq4 GW ' Matrix:Remarks: sample Receipt k �9[� SS -Soil AIR -Air F - Filter PH Temp Cot seal Present/Intact: NPr�JLLY _N GW- Groundwater B-Bioassay me Signed/Accurate _N _7Y -Waste Water Flow Other Bottles arrive intact: _N -7Y DW- Drinking Water Samples ret ned via: Correct bottles used: N Sufficient volume sent: 1Y _N OT - Other _UPS _Fed Ex _Courier Tracking# /�?/� U J V v If Aoolicable VOA Zero Headspace: CY _N Preservation Correct/Checked: 14 _N Relin ished by : (Signature) Date: Time: Received by: (Signature) Trip Blank Received: No W L / McOH PM SCREEN: <0.5 mMr BR Rerhfqutshed by: (Signature) Date: Time: Received by: (Signature) Temp: a Bottles Received: If preservation required by Login: Date/Time Relinquished by: (Signature) Date: Time: Rec dfor lab by: Si n ure) Date: Time: Hold: Conditio y NCF / V Bi l l ing Information: Anal sis/Container/Preservative Chain of Custody Page Withers & Ravenel Eng. - Standard Accounts Payable Pres 115 MacKenan Drive Chk 115 MacKenan Drive Cary, NC 27511 (Cary, NC 27511 N 2 12o6s lelunon Re Q Q Reportto: Email To: lelliott@withersravenel.com Laura Elliott O Mount luliet, TN 37122 Z W Q Phone: 615758585fl Phone: BtxF)6h5859 `}''� Fax: 6lsJ585859 �:i• PfOJ2Ci City/state s"v""�SN`t<l Description: KHLandfill Collected.f o m Z c _ = L# �Il yn 2NlQ (O/ Client Project# Lab Project# Phone: 9-069-3340 06140180.24 WITH RAVS-KERN ERSVILL M p Table# Fax: 919-467-6008 a 0 n N ID a V Z N E Q E Y m Collected by (print): Site/Facility ID # P.O. # ACC'tnum: WITHRAVS �' A _ d N o u v Vli ` E V1 2 U Z W = i a E E C m x = Template:T153277 Collect d by (signature): Hush? (Lab MUST Be Notified) Quote # Q..�`_Nex[Day _Same Day _Five Day _SDay (Rad Onp) Date Results Needed N To v u, p _ = a ONy NLLn O E E Q E Prelogin: P720388 TSR: 873-Heathen Wagner s rely lNv ✓ Two Day _ 10 Day IRad Only) No. 7! m N o '� W o `t O `t Packed on Ice N _ y _ _ Three Day of O0 O Z y 'y' ry O � I` y O _ ti U O N O QD FN PB' nits Shipped via: Fed EX Ground Sample 10 Comp/Grab Matrix' Depth Date Time —I O O IA O O 00 00 m U Cr v, f— > > R—Im Sa mole a lbb onN) GW GW GW GW GW EQUIPMENT BLANK GW TRIP BLANK GW Lit�I ' Matrix: emarks: Sample Checklist nt/Irnt CDC Seal Prese/lvtact _NP �Y _N SS -Soil AIR -Air F- Filter PH Temp SW - Groundwater B-Bloassay CDC Signed/Accurate: LY _N -Wastewater Flow Other Bottles arrive intact: _Y _N Correct bottles used: �Y _N DW -Drinking Water OT Other Samples retu via: �c edEx TroOking# O Sufficient volume sent: �Y _N If Applicable - _UPS _Courier //3 Q �rA� 77 CC// t VOA Zero Neadspacs�. r-Y N P�`Qt?PrG�[e Vrih CAS h —N " I ,� N Relinq -shed by: (Signature) Date: Time: Received by: (Signature) Trip Blank Received y No / MCOM ai pj/Li( Q. 41 1 V U TBR ished by: (Signature) Date:Time: Received by: (Signature) Temp: 'C Bottles Received: If preservation required by Login: Date/Time Z , Z= , 4J Relinquished by: (Signature) Date: Time: Recei dfor lab by: (Signs re) Date: Time: Hold: Condit'geo1 q S NCF / GC{'v%1 G �w WithersRavenet Page of Job Number 6140180.24 Groundwater Sampling Form State ID Well ID —2. Site Name Town of Kernersville Closed Landfill Date Jul 2 , a19 Well Depth 13. / Z Depth to Water 3490 Well Diameter A, Casing Material Pye- Screen Length )d' WeII Water Volume Sampling Crew Pump Type Tubing Type Intake set at Weather Conditions 1.6114C Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC (Gals.) (m /L) (°C) S/cm standard) (mV) NTU Other Parameters Sampled at Parameters taken with Samples delivered to by at llcQo Anai sis Preservative Bottle ware Number of Bottles Hold Time o�c HCL 40 ml VOAs glass 14 Days None 1 Liter glass 7 Days Ps Nitric Acid 250 ml plastic 180 Days N�O? Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other :. keGI- v )►-tA 1,Al Well Volume Calculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4 tZfl1 Y.I+d► 0 4" well [well depth -depth to water] x 0.653 alions/ft. x 3 = 1.959/ft = 1 Lll*—G.. \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Deliverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 C ■Val �� �� i. +Cl y Page i of Our People, Your Success Job Number 6140180.24 Groundwater Sampling Form State ID Well ID LA -3S Site Name Town of Kernersville Closed Landfill Date July 2E-2019 Well Depth I_Lll.�_ Depth to Water 13.1 La Well Diameter Casing Material Nil!, Screen Length 1 J ` Well Water Volume Sampling Crew K.mM Pump Type Le.✓ Tubing Type Intake set at Weather Conditions q"(- -S Notes (eg odor or color) oc)d Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from TOC) (Gals.) m /L °C S/cm) (standard mV NTU v: vu 3 . I , I to. 3 'All i .'L-7 Other Parameters Sampled at I tj ; 00 Parameters taken with Samples delivered to by L:� at iJ: Lkn� I sis Preservative Bottle ware Number of Bottles Hold Time VDCs HCL 40 ml VOAs glass 14 Days Cs None 1 Liter glass 7 Days Nitric Acid 250 ml plastic 180 Days 1e NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days 4�s None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Well Volume Calculation 1" well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] X 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Deliverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 N■ M L n- %i : w, Page j of ■f ^..- People. Your Success Job Number 6140180.24 Groundwater Sampling Form State ID Well ID Site Name Town of Kernersville Closed Landfill Date July , 2019 Well Depth s(p,gI Casing Material Pl/ Sampling Crew cti &* Pump Type (1 Weather Conditions Depth to Water 11,s LA Well Diameter 2J Screen Length Zv t Well Water Volume ej,ny Tubing Type 3 to Intake set at ILA r Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity 24 Hr. from TOC Gals, m /L °G S/cm) (standard mV NTU Other Parameters Sampled at Parameters taken with _ S -r 1 Samples delivered to by at An I sis Other Parameters Sampled at Parameters taken with _ S -r 1 Samples delivered to by at An I sis Preservative Bottle ware Number of Bottles Hold Time VOC HCL 40 ml VOAs glass 14 Days Cs None 1 Liter glass 7 Days Nitric Acid 250 ml plastic 180 Days O3+N0 Sulfuric Acid 125 ml plastic 28 Days tR-e-706-ides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Well Volume Calculation I" well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Del iverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 Page of Job Number 6140180.24 Groundwater Sampling Form State ID Well ID K,,i - Site Name Town of Kernersville Closed Landfill Date July 2019 Well Depth 14. qzh Depth to Water�tA Well Diameter u Casing Material pvu Screen Length to' Well Water Volume. �( Sampling Crew j , Pump Type j84; Lt l Tubing Type Weather Conditions 1.0 i...., 4. Intake set at Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity �{�ja=ii%Tii1Ci1Is1! g iif.`IG1ii11< . • . • =©►� jkq11L1j Other Parameters Sampled at# Parameters taken with Ys I k To . ►a;�1 �^ }� 4-t,• Samples delivered to by ^cam at t A sis Other Parameters Sampled at# Parameters taken with Ys I k To . ►a;�1 �^ }� 4-t,• Samples delivered to by ^cam at t A sis Preservative Bottle ware Number of Bottles Hold Time OCs HCL 40 ml VOAs glass 14 Days S Cs None 1 Liter glass 7 Days Nitric Acid 250 ml plastic 180 Days 03+N Sulfuric Acid 125 ml plastic 28 Days Her lcl es None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Well Volume Calculation 1" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 7'si , ( 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Deliverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 =.. 1.=. Page Groundwater Sampling Form Site Name Well Depth Casing Material Sampling Crew Town of Kernersville Closed Landfill of Job Number 6140180.24 State I D Well ID/� } Date July 23, 2019 Depth to Water r' Well Diameter Screen Length Q�— ? Well Water Volume r Pump Type ' Tubing Type - Intake set at Weather Conditions Notes (eg. odor or color) Si L-& 1 JCIO,tc1 Time Water Level Volume Purged DO Temp EC pH ORP Turbidity ��a ja=[i a R to E rim, NA M■ Other Parameters Sampled at C) Parameters taken with Samples delivered to by rC- at 44r* r ?S Analysis Preservative Bottle ware Number of Bottles Hold Time VOCs HCL 40 ml VOAs glass 14 Days SVOCs None 1 Liter glass 7 Days Metals Nitric Acid 250 ml plastic 180 Days NO3+NO2 Sulfuric Acid 125 ml plastic 28 Days Herbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other Well Volume Calculation I" well [well depth -depth to water] x 0.0408 gallonsift. x 3 = 0.124/ft._ 2" well [well depth -depth to water] x 0.163 gallons/ft. x 3 = 0.489/ft = 4" well [well depth -depth to water] x 0.653 gallons/ft. x 3 = 1.959/ft = /, b7 , ), \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Deliverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 Page I of Our People, Your Success Job Number 6140180.24 Groundwater Sampling Form State ID Well ID to Site Name Town of Kernersville Closed Landfill Date Jul 2019 Well Depth 2") RP Depth to Water_ }. Well Diameter L Casing Material PVol Screen Length IIy z Well Water Volume AU6 Sampling Crew L�� Pump Type 6-i L-V Tubing Type Intake set at Weather Conditions �v 4 �,�,,,.,ti,� _ Notes (eg. odor or color) Time Water Level Volume Purged DO Temp EC pH ORP Turbidity (24 Hr.) (from TOC Gals. m 1L °C S/cm standard mV NTU 2? I - 52, 7 i h Other Parameters Sampled at Parameters taken with Samples delivered to by at Anal &s Preservative Bottle ware Number of Bottles Hold Time O HCL 40 ml VOAs glass 14 Days SVOCs None 1 Liter glass 7 Days e Nitric Acid 250 ml plastic 180 Days +N Sulfuric Acid 125 ml plastic 28 Days erbicides None 1 Liter glass 7 days Pesticides None 1 Liter glass 7 Days Other G Well Volume Calculation 1 " well [well depth -depth to water] x 2" well [well depth -depth to water] x 4" well [well depth -depth to water] x 0.0408 gallons/ft. x 3 = 0.124/ft. _ 0.163 gallons/ft. x 3 = 0.489/ft = 0.653 gallons/ft. x 3 = 1.959/ft = \\wrgreenfile.wrinternal01.com\greensboro\14\14-0180\140180.19-Landfill Services FYE 2018\Enviro\Reports and Deliverables\GROUNDWATER 2019\Revised GW Sampling Form 2019 APPENDIX II Historical Summary Tables TABLE1A SUMMARY OF HISTORICAL GROUNDWATER ELEVATIONS Background Downgradient Well ID: MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 TOC Elevation: 806.42 804.87 762.19 764.57 764.56 760.26 773.32 Well Depth: 34.69 20.46 13.18 24.00 56.96 14.40 11.36 30-Dec-09 772.45 786.66 759.16 751.54 752.79 754.33 769.21 01-Jun-10 773.45 788.32 758.90 750.76 752.63 753.90 769.69 16-Nov-10 773.55 787.93 759.14 750.98 752.59 753.74 769.81 29-Dec-10 773.29 787.37 758.83 749.82 752.45 753.68 769.56 29-Jun-11 773.10 786.81 758.38 750.54 752.16 753.41 769.73 01-Nov-11 771.92 785.10 758.49 754.73 751.90 753.08 769.63 01-May-12 771.88 785.32 758.54 750.86 752.34 753.55 769.55 07-Nov-12 771.65 DRY 758.20 750.30 751.61 752.87 768.57 09-May-13 769.95 787.56 759.20 752.52 753.24 754.44 - 07-Nov-13 771.46 DRY 758.09 750.12 751.50 752.79 768.13 05-Jun-14 772.22 785.84 758.45 750.67 752.14 753.36 768.57 20-Nov-14 771.73 784.41 758.08 750.24 751.53 752.81 769.23 Notes: TOC = Top of PVC well casing. Elevations in feet above mean sea level. Well depths in feet below TOC. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 1B MONITORING WELL AND BORING COMPLETION SUMMARY WELL NUMBER CASING DIAMETER inches WELL ELEVATIONS TOTAL DEPTH SCREENED INTERVAL* LITHOLOGY OF SCREENED INTERVAL* GROUND SURFACE T.O.C. B.G.S. feet B.T.O.C. feet DEPTH B.G.S. ELEV. M.S.L. feet above M.S.L. from to from to MW-1 2 803.89 806.42 32.16 34.69 24.69 34.96 779.2 768.9 SAPROLITE MW-2 2 760.07 762.19 11.06 13.18 3.18 13.18 756.9 746.9 SAPROLITE MW-3S 2 761.98 764.57 21.41 24.00 14 24 748.0 738.0 SAPROLITE MW-3D 2 762.02 764.56 54.42 56.96 36.96 56.96 725.1 705.1 SAPROLITE MW-4 2 757.00 760.26 11.14 14.40 4.4 14.4 752.6 742.6 SAPROLITE MW-5 2 771.00 773.32 9.04 11.36 6.36 11.36 764.6 759.6 SAPROLITE MW-6 2 801.77 1 804.87 17.36 20.46 10.46 20.46 791.3 781.3 SAPROLITE NOTES: B.G.S. Below Ground Surface M.S.L. Mean Sea Level B.T.O.C. Below Top of Casing T.O.C. Top of Casing * = Due to limited information this data is assumed based on field conditions Town of Kernersville Landfill Page 1 of 1 Joyce Engineering TABLE 2 SUMMARY OF ESTIMATED HYDRAULIC GRADIENT AND LINEAR VELOCITY November 2014 GRADIENT FLOW LINE GROUND- HORIZ. HYDRAULIC EFFECTIVE LINEAR FLOW WATER GRADIENT, CONDUCTIVITY POROSITY VELOCITY, CALCULATION LENGTH DIRECTION ELEV. i K n V SEGMENT (feet) feet ft/ft ft/da ft/da 11 851 SW 0.04 1.73 0.30 0.20 755 Notes: 1. Hydraulic conductivities ("K") was estimated from slug test completed by JOYCE in April 2013 2. Velocity = Ki/n; assume homogeneous isotropic porous aquifer. Town of Kernersville Landfill Permit No. 34-04 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 --- ND 5.4 B ND ND 4.5 B --- 1.4 J GWPS = 1.4 µg/L (10/23/07) 01-Jun-10 1.2 6.0 --- ND ND ND ND ND --- 3.9 J GWPS = 1 µg/L (8/1/10) 29-Dec-10 2.6 6.0 --- ND ND ND ND ND ND ND 29-Jun-11 5.0 6.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 6.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 6.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.48 6.0 --- --- ND ND ND ND --- ND 09-May-13 5.0 6.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 6.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 6.0 --- ND ND ND ND ND ND ND 20-Nov-14 3.8 6.0 --- --- ND ND ND ND ND ND Arsenic 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 6.2 J ND NC 2L = 10 µg/L (1/11/10) 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.094 10.0 --- --- 1.43 B 1.42 B 0.87 B 1.04 B --- 1.0 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 2.7 J ND Barium 30-Dec-09 1.1 100 --- 74.1 J 496 178 18.2 J 89.0 J --- 3.6 J NC 2L = 700 µg/L (1/11/10) 01-Jun-10 1.1 100 --- 58.1 J 326 187 22.2 J 94.9 J --- 2.0 1 29-Dec-10 0.20 100 --- 46.3 B 430 112 38.0 B 92.1 J 72.6 J 11.3 J 29-Jun-11 5.0 100 --- 77.7 J 370 128 41.2 J 98.4 J 113 ND 01-Nov-11 5.0 100 --- 125 413 132 41.7 J ill 72.1 J ND 01-May-12 5.0 100 --- 78.8 J 323 121 40.0 J 99.7 J 66.1 J ND 07-Nov-12 0.39 100 --- --- 369 127 41.0 B 98.7 J --- 12.2 J 09-May-13 5.0 100 --- 78.6 J 307 112 40.0 J 85.6 J --- ND 07-Nov-13 5.0 100 --- --- 302 113 38.0 J 89.6 J --- ND 05-Jun-14 5.0 100 --- 60.3 J 285 117 39.2 J 80.3 J 75.0 J ND 20-Nov-14 2.5 100 --- --- 301 113 39.5 J 83.3 J 108 ND Beryllium 30-Dec-09 0.2 1.0 --- ND 0.5 J ND ND ND --- ND GWPS = 4 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- 0.6 J 0.7 J ND ND ND --- ND 29-Dec-10 0.10 1.0 --- ND ND ND ND ND 0.48 J ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.049 1.00 --- --- 0.34 J ND ND 0.099 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Cadmium 30-Dec-09 0.2 1.0 --- ND 0.5 1 5.6 ND ND --- ND NC 2L = 2 µg/L (1/11/10) 01-Jun-10 0.2 1.0 --- 2.9 1.0 B 5.3 0.4 B 0.4 B --- 0.4 J 29-Dec-10 0.50 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 1.0 1.0 --- ND ND ND ND ND ND ND 01-May-12 1.0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.026 1.00 --- --- 0.15 J ND ND 0.043 J --- ND 09-May-13 1.0 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 1.0 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 1.0 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.5 1.0 --- --- ND ND ND ND ND ND Chromium 30-Dec-09 0.7 10.0 --- ND 2.7 J 9.7 J ND 3.1 J --- ND NC 2L = 10 µg/L (1/11/10) 01-Jun-10 0.7 10.0 --- 3.5 J 1.6 J 12.4 1.2 J 3.2 J --- ND 29-Dec-10 0.40 10.0 --- 0.48 J 1.3 J 0.57 J ND 5.5 J 3.8 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 10.3 ND ND 01-May-12 5.0 10.0 --- ND ND ND ND 5.8 J ND ND 07-Nov-12 0.030 10.0 --- --- 0.71 J 0.12 B 0.094 B 7.31 1 --- 0.099 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Cobalt 30-Dec-09 0.7 10.0 --- ND 6.4 J 11.2 ND 1.8 J --- ND GAPS = 70 µg/L (10/23/07) 01-Jun-10 0.7 10.0 --- 1.8 J 2.5 J 8.5 J ND 1.7 J --- ND GAPS = 1 µg/L (10/1/10) 29-Dec-10 0.60 10.0 --- ND 4.9 J 1.7 J ND 1.6 J 10.2 ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 9.9 J ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND 5.2 J ND 01-May-12 5.0 10.0 --- ND ND ND ND ND 13.9 ND 07-Nov-12 0.053 10.0 --- --- 1.98 J 3.89 J 0.43 B 2.02 J --- 0.24 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 12.0 ND 20-Nov-14 2.5 10.0 --- --- ND 2.5 J ND ND 10.2 ND Copper 30-Dec-09 2.0 10.0 --- ND ND 10.6 ND 1.5 J --- ND NC 2L = 1,000 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 12.2 B 3.3 B 33.2 3.9 B 6.8 B --- 4.8 J 29-Dec-10 0.30 10.0 --- ND ND 0.49 J 0.59 J 1.5 J 7.9 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 16.6 ND 01-Nov-11 5.0 10.0 --- ND ND ND ND 5.4 J ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.093 10.0 --- --- 3.56 B 0.54 B 0.98 B 1.83 B --- 1.23 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND 6.1 J ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 5.3 J ND Lead 30-Dec-09 2.0 10.0 --- ND ND 10.2 ND ND --- ND NC 2L - 15 µg/L (10/23/07) 01-Jun-10 2.0 10.0 --- 9.1 B 8.2 B 8.7 B 3.0 B 3.9 B --- 3.2 J 29-Dec-10 4.0 10.0 --- ND ND ND ND ND 6.5 J ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND 19.9 ND 01-Nov-11 5.0 10.0 --- 5.5 J ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.025 10.0 --- --- 1.00 B 0.091 B 0.066 B 1.12 B --- 0.58 J 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND 4.2 J ND Nickel 30-Dec-09 0.6 50.0 --- ND ND 8.1 J 1.8 J 1.6 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.6 50.0 --- ND ND 6.0 J ND 0.9 J --- ND 29-Dec-10 1.7 50.0 --- ND ND ND ND ND 2.0 B 3.1 J 29-Jun-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 50.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 50.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.26 50.0 --- --- 0.73 B 1.19 B 0.65 B 5.57 J --- 0.84 J 09-May-13 5.0 50.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 50.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 50.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 50.0 --- --- ND ND ND ND ND ND Selenium 30-Dec-09 6.3 10.0 --- ND ND 8.4 J ND ND --- ND NC 2L = 20 µg/L (1/11/10) 01-Jun-10 6.3 10.0 --- ND ND 6.3 J ND ND --- ND 29-Dec-10 3.8 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 10.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 10.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.11 10.0 --- --- 0.16 J 0.38 J 0.20 J 0.25 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 10.0 --- --- ND ND ND ND ND ND Silver 30-Dec-09 1.1 10.0 --- ND 1.7 B 2.2 B ND ND --- 1.9 J NC 2L = 20 µg/L (1/11/10) 01-Jun-10 1.1 10.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.10 10.0 --- ND 1.8 J 0.36 J 0.19 J 0.23 J ND ND 29-Jun-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-Nov-11 5.0 10.0 --- ND ND ND ND ND ND ND 01-May-12 5.0 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.017 10.0 --- --- 0.18 J ND ND 0.078 J --- ND 09-May-13 5.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 2.5 10.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Thallium 30-Dec-09 2.7 5.5 --- ND ND ND ND ND --- 3.7 J GWPS = 0.28 µg/L (10/23/07) 01-Jun-10 2.7 5.5 --- ND ND ND ND ND --- ND GWPS = 0.2 µg/L (10/1/10) 29-Dec-10 3.0 5.5 --- ND 3.2 J ND ND 4.8 J ND ND 29-Jun-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-Nov-11 5.4 5.5 --- ND ND ND ND ND ND ND 01-May-12 5.4 5.5 --- ND ND ND ND ND ND ND 07-Nov-12 0.060 5.50 --- --- 0.16 J ND ND 0.76 J --- ND 09-May-13 5.4 5.5 --- ND ND ND ND ND --- ND 07-Nov-13 5.4 5.5 --- --- ND ND ND ND --- ND 05-Jun-14 5.4 5.5 --- ND ND ND ND ND ND ND 20-Nov-14 5.0 5.5 --- --- ND ND ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 --- ND 1.4 J 37.4 1.5 J 4.3 J --- ND GWPS = 3.5 µg/L (10/23/07) 01-Jun-10 0.4 25.0 --- 1.2 J 3.4 J 84.2 1.4 J 4.8 J --- ND GWPS = 0.3 µg/L (10/1/10) 29-Dec-10 0.20 25.0 --- 1.2 B 2.8 J 2.3 J 1.6 J 5.5 J 14.5 J 0.26 J 29-Jun-11 5.0 25.0 --- ND ND ND ND ND 22.0 J ND 01-Nov-11 5.0 25.0 --- 7.2 J ND ND ND 12.0 J 7.2 J ND 01-May-12 5.0 25.0 --- ND ND ND ND 7.2 J 7.6 J ND 07-Nov-12 0.085 25.0 --- --- 2.48 J 2.02 J 2.35 J 4.55 J --- ND 09-May-13 5.0 25.0 --- ND ND ND ND ND --- ND 07-Nov-13 5.0 25.0 --- --- ND ND ND ND --- ND 05-Jun-14 5.0 25.0 --- ND ND 11.4 J ND ND ND ND 20-Nov-14 2.5 25.0 --- --- ND 3.2 J ND ND 9.4 J ND Zinc 30-Dec-09 2.7 10.0 --- ND 10.1 B 204 15.9 B 24.8 B --- 5.8 J NC 2L - 1,000 µg/L (1/11/10) 01-Jun-10 2.7 10.0 --- 16.2 13.5 415 8.5 J 22.2 --- ND 29-Dec-10 0.40 10.0 --- 12.2 B 15.8 B 8.9 B ND 4.6 B 38.1 B 12.5 29-Jun-11 10.0 10.0 --- ND 23.6 B 22.3 B ND 15.5 B 91.2 10.5 01-Nov-11 10.0 10.0 --- 16.6 ND 40.0 ND 16.2 31.4 ND 01-May-12 10.0 10.0 --- ND ND 13.5 ND 10.2 12.0 ND 07-Nov-12 1.31 10.0 --- --- 8.61 J 5.20 J 3.98 J 4.65 J --- ND 09-May-13 10.0 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 10.0 10.0 --- --- 13.8 10.4 ND ND --- ND 05-Jun-14 10.0 10.0 --- ND ND 89.0 ND ND 19.4 ND 20-Nov-14 5.0 10.0 --- --- ND 20.9 ND ND 55.0 ND Organic Compounds Acetone 29-Jun-11 2.2 100 --- ND 2.3 B 2.4 B 3.9 B ND 3.8 B 5.3 J NC 2L = 6,000 µg/L (1/11/10) 01-Nov-11 2.2 100 --- ND ND ND ND ND ND 14.6 J 01-May-12 2.2 100 --- ND ND ND ND ND ND ND 07-Nov-12 0.193 100 --- --- ND ND ND ND --- ND 09-May-13 10.0 100 --- ND ND ND ND ND --- 12.0 J 07-Nov-13 10.0 100 --- --- ND ND ND ND --- ND 05-Jun-14 10.0 100 --- ND ND ND ND ND ND ND 20-Nov-14 10.0 100 --- --- ND ND ND ND ND ND Benzene 30-Dec-09 0.1 1.0 --- ND 8.4 0.3 J 0.4 J 0.3 J --- ND NC 2L = 1 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND 2.9 ND ND ND --- ND 29-Dec-10 0.25 1.0 --- ND 8.1 ND ND ND ND ND 29-Jun-11 0.25 1.0 --- ND 7.2 0.38 J 0.45 J 0.42 J ND ND 01-Nov-11 0.25 1.0 --- ND 8.6 ND ND ND ND ND 01-May-12 0.25 1.0 --- ND 6.7 0.36 J 0.45 1 0.42 J ND ND 07-Nov-12 0.111 1.0 --- --- 8.63 0.430 J 0.504 J 0.478 J --- ND 09-May-13 0.25 1.0 --- ND 5.2 0.27 J 0.32 J 0.30 J --- ND 07-Nov-13 0.25 1.0 --- --- 6.9 0.33 J 0.38 J 0.39 J --- ND 05-Jun-14 0.25 1.0 --- ND 6.0 ND 0.42 J 0.40 J ND ND 20-Nov-14 0.25 1.0 --- --- 6.2 0.30 J ND 0.32 J ND ND Bromoform 09-May-13 0.26 3.0 --- ND ND 0.37 B ND ND --- 0.37 J NC 2L = µg/L 4 (10/23/07) 07-Nov-13 0.26 3.0 --- ND ND ND ND --- ND 05-Jun-14 0.26 3.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 3.0 --- --- ND ND ND ND ND ND Chlorobenzene 30-Dec-09 0.1 3.0 --- ND 0.5 J 0.6 J ND ND --- ND NC 2L = 50 µg/L (10/23/07) 01-Jun-10 0.1 3.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.23 3.0 --- ND 0.61 J ND ND ND ND ND 29-Jun-11 0.23 3.0 --- ND 0.46 J 1.0 J 0.37 J ND ND ND 01-Nov-11 0.23 3.0 --- ND 0.59 J 1.1 J 0.37 J ND ND ND 01-May-12 0.23 3.0 --- ND {0.42{ J 0.94 B 0.38 B ND ND 0.30 {ND{ J 07-Nov-12 0.083 3.00 --- --- 0.468 J 1.30 J 0.476 J ND --- ND 09-May-13 0.23 3.0 --- ND 0.27 J 0.72 J 0.27 J ND --- ND 07-Nov-13 0.23 3.0 --- --- 0.42 J 0.97 J 0.38 J ND --- ND 05-Jun-14 0.23 3.0 --- ND 0.30 J 0.78 J 0.33 J ND ND ND 20-Nov-14 0.23 3.0 --- --- 0.37 J 0.95 J 0.36 J ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 3 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks Chloroethane 30-Dec-09 0.1 10.0 --- ND ND 0.5 J 0.5 J ND --- 0.1 J NC 2L = 3,000 µg/L (1 / 11 / 10) 01-Jun-10 0.1 10.0 --- ND ND 0.4 J ND ND --- ND 29-Dec-10 0.54 10.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.54 10.0 --- ND ND 0.77 J ND 0.57 J ND ND 01-Nov-11 0.54 10.0 --- ND ND 0.79 J ND ND ND ND 01-May-12 0.54 10.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.235 10.0 --- --- ND ND ND ND --- ND 09-May-13 0.54 10.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.54 10.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.54 10.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.54 10.0 --- --- ND ND ND ND ND ND 1,4-Dichlorobenzene 30-Dec-09 0.1 1.0 --- ND 3.8 2.2 2.3 3.1 --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.2 0.9 J ND 1.2 --- ND 29-Dec-10 0.33 1.0 --- ND 3.9 1.1 2.3 1.9 ND ND 29-Jun-11 0.33 1.0 --- ND 3.8 2.8 3.6 3.2 ND ND 01-Nov-11 0.33 1.0 --- ND 4.7 4.1 4.1 3.5 ND ND 01-May-12 0.33 1.0 --- ND 4.0 2.7 4.1 3.2 ND ND 07-Nov-12 0.083 1.00 --- --- 5.12 2.93 4.08 3.64 --- ND 09-May-13 0.33 1.0 --- ND 3.6 2.0 3.1 2.3 --- ND 07-Nov-13 0.33 1.0 --- --- 5.4 2.5 4.2 3.2 --- ND 05-Jun-14 0.33 1.0 --- ND 5.0 1.9 4.0 2.7 ND ND 20-Nov-14 0.33 1.0 --- --- 4.7 1.9 3.8 2.6 ND ND 1, 1 -Dichloroethane 30-Dec-09 0.2 5.0 --- ND 22.8 1.9 J 4.0 J 2.4 J --- ND NC 2L = 6 µg/L (1/11/10) 01-Jun-10 0.2 5.0 --- ND 11.0 1.1 J ND 1.2 J --- ND 29-Dec-10 0.32 5.0 --- ND 28.2 2.4 1 4.1 J 2.6 J ND ND 29-Jun-11 0.32 5.0 --- ND 25.0 2.5 J 3.9 J 2.6 J ND ND 01-Nov-11 0.32 5.0 --- ND 27.2 2.3 1 4.0 J 2.3 J ND ND 01-May-12 0.32 5.0 --- ND 22.6 2.0 J 3.8 J 2.0 J ND ND 07-Nov-12 0.208 5.0 --- --- 28.1 2.06 J 4.08 J ND --- ND 09-May-13 0.32 5.0 --- ND 18.7 1.4 1 3.0 1 1.6 J --- ND 07-Nov-13 0.32 5.0 --- --- 26.6 1.7 J 4.2 J 2.2 J --- ND 05-Jun-14 0.32 5.0 --- ND 21.9 1.4 1 3.9 J 1.9 J ND ND 20-Nov-14 0.32 5.0 --- --- 21.5 1.3 J 3.2 J 1.8 J ND ND 1,2-Dichloroethane 30-Dec-09 0.1 1.0 --- ND 1.2 0.7 J 1.2 ND --- ND NC 2L = 0.4 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.12 1.0 --- ND ND 0.82 J 1.1 ND ND ND 29-Jun-11 0.12 1.0 --- ND 0.76 J 0.86 J 1.3 ND ND ND 01-Nov-11 0.12 1.0 --- ND 0.95 J ND 1.3 ND ND ND 01-May-12 0.12 1.0 --- ND 0.71 J 0.70 J 1.1 ND ND ND 07-Nov-12 0.171 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.12 1.0 --- ND 0.50 J 0.49 J 0.81 J ND --- ND 07-Nov-13 0.12 1.0 --- --- 0.93 J 0.66 1 1.3 ND --- ND 05-Jun-14 0.12 1.0 --- ND 0.76 J 0.52 J 0.99 J ND ND ND 20-Nov-14 0.12 1.0 --- --- 0.68 J 0.47 1 0.81 J ND ND ND 1, 1 -Dichloroethylene 30-Dec-09 0.1 5.0 --- ND 0.4 J ND ND ND --- ND NC 2L = 7 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.56 5.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.56 5.0 --- ND ND ND ND ND ND ND 01-May-12 0.56 5.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.208 5.00 --- --- ND ND ND ND --- ND NC 2L = 350 µg/L (04/01/2013) 09-May-13 0.56 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.56 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.56 5.0 --- ND 4.7 J ND ND ND ND ND 20-Nov-14 0.56 5.0 --- ND ND ND ND ND ND ND cis-1,2-Dichloroethee 30-Dec-09 0.1 5.0 --- ND 68.2 11.0 51.0 21.8 --- ND NC 2L = 70 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 23.0 7.6 ND 10.2 --- ND 29-Dec-10 0.19 5.0 --- ND 66.7 16.8 56.7 24.1 ND ND 29-Jun-11 0.19 5.0 --- ND 55.1 16.5 62.7 25.1 ND ND 01-Nov-11 0.19 5.0 --- ND 59.4 15.2 59.3 23.2 ND ND 01-May-12 0.19 5.0 --- ND {48.7{ 14.2 59.5 22.1 ND 0.21 {ND{ J 07-Nov-12 0.103 5.00 --- --- 59.7 13.6 71.3 26.4 --- ND 09-May-13 0.19 5.0 --- ND 39.9 10.9 49.7 17.4 --- ND 07-Nov-13 0.19 5.0 --- --- 53.9 10.7 67.1 21.8 --- ND 05-Jun-14 0.19 5.0 --- ND 47.0 11.2 58.1 20.0 ND ND 20-Nov-14 0.19 5.0 --- --- 44.9 9.6 55.4 19.3 ND ND Town of Kernersville Landfill Permit No. 34-04 Page 4 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Sample 11 Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-31) MW-4 MW-5 Blanks trans-1,2-Dichloroethene 30-Dec-09 0.1 5.0 --- ND 1.4 J ND 0.2 J 0.2 J --- ND NC 2L = 100 µg/L (10/23/07) 01-Jun-10 0.1 5.0 --- ND 0.6 J ND ND ND --- ND 29-Dec-10 0.49 5.0 --- ND 1.7 J ND ND ND ND ND 29-Jun-11 0.49 5.0 --- ND 1.5 J ND ND ND ND ND 01-Nov-11 0.49 5.0 --- ND 1.6 J ND ND ND ND ND 01-May-12 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 07-Nov-12 0.077 5.00 --- --- 1.59 J ND ND ND --- ND 09-May-13 0.49 5.0 --- ND 1.1 J ND ND ND --- ND 07-Nov-13 0.49 5.0 --- --- 1.6 J ND ND ND --- ND 05-Jun-14 0.49 5.0 --- ND 1.4 J ND ND ND ND ND 20-Nov-14 0.49 5.0 --- --- 1.4 J ND ND ND ND ND 1,2-Dichloropropane 30-Dec-09 0.1 1.0 --- ND 5.7 0.6 J 1.1 0.7 J --- ND NC 2L = 0.6 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 1.9 ND ND ND --- ND 29-Dec-10 0.27 1.0 --- ND 5.3 ND ND ND ND ND 29-Jun-11 0.27 1.0 --- ND 4.8 0.90 J 1.3 0.73 J ND ND 01-Nov-11 0.27 1.0 --- ND 4.9 0.76 J 1.3 ND ND ND 01-May-12 0.27 1.0 --- ND 4.4 0.76 J 1.4 0.62 J ND ND 07-Nov-12 0.150 1.0 --- --- 4.93 ND 1.66 ND --- ND 09-May-13 0.27 1.0 --- ND 3.3 0.51 J 0.96 J 0.45 J --- ND 07-Nov-13 0.27 1.0 --- --- 4.4 0.63 J 1.3 0.57 1 --- ND 05-Jun-14 0.27 1.0 --- ND 4.0 0.51 J ND 0.41 J ND ND 20-Nov-14 0.27 1.0 --- --- 4.1 0.56 J 1.2 0.36 J ND ND Ethylbenzene 30-Dec-09 0.1 1.0 --- ND ND ND 0.4 J ND --- ND NC 2L = 600 µg/L (10/23/07) 01-Jun-10 0.1 1.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.30 1.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.30 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.3 0 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.109 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.30 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.30 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.30 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.30 1.0 --- --- ND ND ND ND ND ND Tetrachloroethene 30-Dec-09 0.2 1.0 --- ND 1.2 ND ND ND --- ND NC 2L = 0.7 µg/L (10/23/07) 01-Jun-10 0.2 1.0 --- ND 1.4 ND ND ND --- ND 29-Dec-10 0.46 1.0 --- ND 2.8 ND ND ND ND ND 29-Jun-11 0.46 1.0 --- ND 3.6 ND ND ND ND ND 01-Nov-11 0.46 1.0 --- ND 2.9 ND ND ND ND ND 01-May-12 0.46 1.0 --- ND 3.0 ND ND ND ND ND 07-Nov-12 0.193 1.00 --- --- 2.52 ND ND ND --- ND 09-May-13 0.46 1.0 --- ND 1.9 ND ND ND --- ND 07-Nov-13 0.46 1.0 --- --- 1.8 ND ND ND --- ND 05-Jun-14 0.46 1.0 --- ND 2.3 ND ND ND ND ND 20-Nov-14 0.46 1.0 --- --- 1.1 ND ND ND ND ND Toluene 29-Jun-11 0.26 1.0 --- ND ND ND ND ND 0.76 J ND NC 2L = 600 µg/L (1 / 11 / 10) 01-Nov-11 0.26 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.26 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.122 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.26 1.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.26 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.26 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.26 1.0 --- --- ND ND ND ND ND ND Trichloroethene 30-Dec-09 0.1 1.0 --- ND 8.0 ND ND 0.2 J --- ND NC 2L = 3 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 6.4 ND ND ND --- ND 29-Dec-10 0.47 1.0 --- ND 10.1 ND ND ND ND ND 29-Jun-11 0.47 1.0 --- ND 14.6 ND ND ND ND ND 01-Nov-11 0.47 1.0 --- ND 10.2 ND ND ND ND ND 01-May-12 0.47 1.0 --- ND 11.6 ND ND ND ND ND 07-Nov-12 0.161 1.00 --- --- 9.97 ND ND ND --- ND 09-May-13 0.47 1.0 --- ND 8.4 ND ND ND --- ND 07-Nov-13 0.47 1.0 --- --- 8.0 ND ND ND --- ND 05-Jun-14 0.47 1.0 --- ND 8.9 ND ND ND ND ND 20-Nov-14 0.47 1.0 --- --- 5.1 ND ND ND ND ND Trichlorofluoromethane 29-Jun-11 0.20 1.0 --- ND 0.95 J ND ND ND ND ND NC 2L = 2000 µg/L (1/11/10) 01-Nov-11 0.20 1.0 --- ND ND ND ND ND ND ND 01-May-12 0.20 1.0 --- ND ND ND ND ND ND ND 07-Nov-12 0.157 1.00 --- --- ND ND ND ND --- ND 09-May-13 0.20 1.0 --- ND 0.66 J ND ND ND --- ND 07-Nov-13 0.20 1.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.20 1.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.20 1.0 --- --- ND ND ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 5 of 6 Joyce Engineering TABLE 3 SUMMARY OF HISTORICAL GROUNDWATER CONSTITUENTS Analyte Sample Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 MW-5 Blanks 11 Vinyl chloride 30-Dec-09 0.1 1.0 --- ND 4.0 2.8 4.1 26.2 --- ND NC 2L = 0.03 µg/L (1/11/10) 01-Jun-10 0.1 1.0 --- ND 2.2 3.0 ND 26.7 --- ND 29-Dec-10 0.62 1.0 --- ND 3.5 2.4 4.7 25.6 ND ND 29-Jun-11 0.62 1.0 --- ND 2.8 2.8 4.6 28.7 ND ND 01-Nov-11 0.62 1.0 --- ND 5.1 2.6 6.9 24.0 ND ND 01-May-12 0.62 1.0 --- ND 3.5 2.0 4.8 21.8 ND ND 07-Nov-12 0.127 1.00 --- --- 7.94 2.73 6.99 29.9 --- ND 09-May-13 0.62 1.0 --- ND 2.8 1.9 4.2 18.6 --- ND 07-Nov-13 0.62 1.0 --- --- 6.3 2.1 6.0 21.9 --- ND 05-Jun-14 0.62 1.0 --- ND 7.1 5.6 8.9 21.9 ND ND 20-Nov-14 0.62 1.0 --- --- 5.2 2.1 5.3 16.2 ND ND Xylene (Total) 30-Dec-09 0.3 4.0 --- ND ND ND 3.5 J ND --- ND NC 2L = 500 µg/L (1/11/10) 01-Jun-10 0.3 4.0 --- ND ND ND ND ND --- ND 29-Dec-10 0.66 2.0 --- ND ND ND ND ND ND ND 29-Jun-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-Nov-11 0.66 2.0 --- ND ND ND ND ND ND ND 01-May-12 0.66 2.0 --- ND 0.89 J ND ND ND ND ND 07-Nov-12 0.179 5.00 --- --- ND ND ND ND --- ND 09-May-13 0.66 5.0 --- ND ND ND ND ND --- ND 07-Nov-13 0.66 5.0 --- --- ND ND ND ND --- ND 05-Jun-14 0.66 5.0 --- ND ND ND ND ND ND ND 20-Nov-14 0.66 5.0 --- --- ND ND ND ND ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2L Standard is the groundwater quality standard established under 15A NCAC 2L. 4. MW = Monitoring well. 5. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 6. ND = Not detected at the laboratory's detection limit. 7. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 8. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. 9. Bold values are greater than the NC 2L Standard or GWPS. 10. DL = Detection limit. 11. GWPS = Groundwater Protection Standard (GWPS is used when the NC 2L Standard has not been established.) 12. --- = Monitoring well was no sampled. Town of Kernersville Landfill Permit No. 34-04 Page 6 of 6 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Inorganic Compounds Antimony 30-Dec-09 1.2 6.0 1.5 B 6.4 B NS 1.4 J NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.2 6.0 6.7 B 2.5 B NS 3.9 J 29-Dec-10 2.6 6.0 ND ND ND ND 29-Jun-11 5.0 6.0 ND ND ND ND 01-Nov-11 5.0 6.0 ND ND ND ND 01-May-12 5.0 6.0 ND ND ND ND 07-Nov-12 0.48 6.0 ND ND ND ND 09-May-13 5.0 6.0 ND ND ND ND 07-Nov-13 5.0 6.0 ND ND ND ND 05-Jun-14 5.0 6.0 ND ND ND ND 20-Nov-14 3.8 6.0 ND ND ND ND Arsenic 07-Nov-12 0.094 10.0 0.17 B 0.26 B 0.24 B 1.0 J NC 2B = 50 µg/L (05/01/07) 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Barium 30-Dec-09 1.1 100 25.1 J 34 J NS 3.4 1 NC 2B = NE µg/L (05/01/07) 01-Jun-10 1.1 100 28.8 J 31.5 J NS 2.0 J 29-Dec-10 0.20 100 22.3 B 27.8 B 27.9 B 11.3 J 29-Jun-11 5.0 100 40.0 J 39.4 J 39.3 J ND 01-Nov-11 5.0 100 30.1 J 35.2 J 34.3 J ND 01-May-12 5.0 100 66.1 J 35.4 J 33.3 J ND 07-Nov-12 0.39 100 27.6 B 31.5 B 29.9 B 12.2 J 09-May-13 5.0 100 33.6 J 33.8 J 32.6 J ND 07-Nov-13 5.0 100 36.6 J 32.0 J 29.8 J ND 05-Jun-14 5.0 100 31.2 J 35.8 J 33.6 J ND 20-Nov-14 2.5 100 26.6 J 31.2 J 29.4 J ND Cadmium 30-Dec-09 0.2 1.0 ND ND NS ND NC 2B = 2 µg/L (05/01/07) 01-Jun-10 0.2 1.0 0.9 B 0.4 B NS 0.4 J 29-Dec-10 0.50 1.0 ND ND ND ND 29-Jun-11 1.0 1.0 ND ND ND ND 01-Nov-11 1.0 1.0 ND ND ND ND 01-May-12 1.0 1.0 ND ND ND ND 07-Nov-12 0.026 1.000 ND ND ND ND 09-May-13 1.0 1.0 ND ND ND ND 07-Nov-13 1.0 1.0 ND ND ND ND 05-Jun-14 1.0 1.0 ND ND ND ND 20-Nov-14 0.5 1.0 ND ND ND ND Chromium 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = 50 µg/L (05/01/07) 01-Jun-10 0.7 10.0 1.7 J 1.2 J NS ND 29-Dec-10 0.40 10.0 0.69 J 0.53 J 0.41 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.030 10.0 0.29 B 0.13 B 0.11 B 0.099 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND 2.7 J ND Town of Kernersville Landfill Permit No. 34-04 Page 1 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Cobalt 30-Dec-09 0.7 10.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.7 10.0 ND ND NS ND 29-Dec-10 0.60 10.0 ND 1.8 J 1.9 J ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.053 10.0 0.34 B 0.76 B 0.76 B 0.24 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Copper 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 7 µg/L (05/01/07) 01-Jun-10 2.0 10.0 6.9 B 5.8 B NS 4.8 1 29-Dec-10 0.30 10.0 0.38 J ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.093 10.0 0.27 B 0.38 B 0.38 B 1.23 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Lead 30-Dec-09 2.0 10.0 ND ND NS ND NC 2B = 25 µg/L (05/01/07) 01-Jun-10 2.0 10.0 2.7 B 2.8 B NS 3.2 J 29-Dec-10 4.0 10.0 ND ND ND ND 29-Jun-11 5.0 10.0 ND ND ND ND 01-Nov-11 5.0 10.0 ND ND ND ND 01-May-12 5.0 10.0 ND ND ND ND 07-Nov-12 0.025 10.0 0.071 B 0.049 B 0.060 B 0.58 J 09-May-13 5.0 10.0 ND ND ND ND 07-Nov-13 5.0 10.0 ND ND ND ND 05-Jun-14 5.0 10.0 ND ND ND ND 20-Nov-14 2.5 10.0 ND ND ND ND Nickel 07-Nov-12 0.26 50.0 0.46 B 0.39 B 0.35 B 0.84 J NC 2B = 88 µg/L (05/01/07) 09-May-13 5.0 50.0 ND ND ND ND 07-Nov-13 5.0 50.0 ND ND ND ND 05-Jun-14 5.0 50.0 ND ND ND ND 20-Nov-14 2.5 50.0 ND ND ND ND Vanadium 30-Dec-09 0.4 25.0 2.0 J 0.8 J NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.4 25.0 2.2 J 2.4 J NS ND 29-Dec-10 0.20 25.0 0.67 B 0.37 B 0.62 B 0.26 J 29-Jun-11 5.0 25.0 ND ND ND ND 01-Nov-11 5.0 25.0 ND ND ND ND 01-May-12 5.0 25.0 ND ND ND ND 07-Nov-12 0.085 25.0 0.63 J 0.44 J 0.52 J ND 09-May-13 5.0 25.0 7.8 J 9.1 J 9.4 J ND 07-Nov-13 5.0 25.0 ND ND ND ND 05-Jun-14 5.0 25.0 ND ND ND ND 20-Nov-14 2.5 25.0 ND ND ND ND Town of Kernersville Landfill Permit No. 34-04 Page 2 of 3 Joyce Engineering TABLE 4 SUMMARY OF HISTORICAL SURFACE WATER CONSTITUENTS Sample Analyte Collection Date DL QL SW-1 SW-2 SW-3 Blanks Zinc 30-Dec-09 2.7 10.0 6.7 B ND NS 4.7 J NC 2B = 50 µg/L (05/01/07) 01-Jun-10 2.7 10.0 6.7 J 8.7 J NS ND 29-Dec-10 0.40 10.0 ND 1.2 B 1.2 B 12.5 29-Jun-11 10.0 10.0 ND ND ND 10.5 01-Nov-11 10.0 10.0 ND ND ND ND 01-May-12 10.0 10.0 ND ND ND ND 07-Nov-12 1.31 10.0 ND ND 1.56 J ND 09-May-13 10.0 10.0 ND ND ND ND 07-Nov-13 10.0 10.0 ND ND ND ND 05-Jun-14 10.0 10.0 ND ND ND ND 20-Nov- 14 5.0 10.0 ND ND ND ND Organic Compounds Acetone 29-Jun-11 2.2 100 2.8 B 3.3 B 4.4 B 5.3 1 NC 2B = NE µg/L (05/01/07) 01-Nov-11 2.2 100 ND ND ND 14.6 1 01-May-12 2.2 100 ND ND ND ND 07-Nov-12 0.193 100 ND ND ND ND 09-May-13 10.0 100 ND ND ND 12.0 J 07-Nov-13 10.0 100 ND ND ND ND 05-Jun-14 10.0 100 ND ND ND ND 20-Nov-14 10.0 100 ND ND ND ND cis-1,2-Dichloroethene 30-Dec-09 0.1 5.0 ND ND NS ND NC 2B = NE µg/L (05/01/07) 01-Jun-10 0.1 5.0 ND ND NS ND 29-Dec-10 0.19 5.0 ND 0.39 J ND ND 29-Jun-11 0.19 5.0 0.26 J 0.30 J 0.33 J ND 01-Nov-11 0.19 5.0 ND ND ND ND 01-May-12 0.19 5.0 0.31 B ND ND 0.21 (ND) J 07-Nov-12 0.103 5.00 ND ND ND ND 09-May-13 0.19 5.0 ND ND ND ND 07-Nov-13 0.19 5.0 ND 0.38 J ND ND 05-Jun-14 0.19 5.0 ND 0.33 J ND ND 20-Nov-14 0.19 5.0 ND 0.49 J ND ND Notes: 1. RL = Reporting limit (NC SWSL). 2. All concentrations are in micrograms per liter (ug/L). 3. NC 2B Standard is the surface water quality standard. Classification is currently Freshwater Aquatic Life. 4. NS = Not sampled. 5. SMP = Surface water monitoring point. 6. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. 7. ND = Not detected at the laboratory's detection limit. 8. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. 9. B = Blank Qualifed 10. Shaded values are greater than the established NC 2B Surface Water Quality Standards. 11. DL = Detection limit. 12. NE = Not established. Town of Kernersville Landfill Permit No. 34-04 Page 3 of 3 Joyce Engineering TABLE 5 SUMMARY OF MNA CONSTITUENTS Sample Analyte Collection Date DL QL MW-1 MW-6 MW-2 MW-3S MW-3D MW-4 Alkalinity, Total as CaCO3 Jun-14 1000.0 5000 --- 4600 J 148000 147000 160000 186000 (ug/L) Nov-14 1000.0 5000 --- --- 159000 151000 159000 181000 Sulfate Jun-14 2000 250000 --- 6500 J ND ND ND ND (ug/L) Nov-14 1000 250000 --- --- 1760 J 1730 J 1870 J 1560 J Nitrogen, Nitrate Jun-14 20.0 1000 --- 72 J 56 J ND ND ND (ug/L) Nov-14 10.0 1000 --- --- 45 J ND ND ND Methane Jun-14 3.3 6.6 --- --- 5530 254 242 515 (ug/L) Nov-14 3.3 6.6 --- --- 4980 159 182 186 Chloride Jun-14 1000 1000 --- 2220 11200 25900 16800 15600 (ug/L) Nov-14 500 1000 --- --- 17100 27900 17300 17100 Total Organic Carbon Jun-14 1000 1000 --- 3100 10600 8300 1500 8200 (ug/L) Nov-14 500 1000 --- --- 2150 1750 1370 1100 Hydrogen Jun-14 0.13 0.6 --- --- 1.5 1.2 120 3.5 (nM) Nov-14 0.13 0.6 --- --- 2.0 1.1 4.4 1.4 BOD, 5 day Jun-14 2000 2000 --- ND ND ND ND ND (ug/L) Nov-14 2000 2000 --- --- 4900 ND ND ND Chemical Oxygen Demand Jun-14 12500 25000 --- ND ND ND ND ND (ug/L) Nov-14 12500 25000 --- --- ND ND 431000 ND Notes: MW = Monitoring well. Blanks = Quality control blanks, including trip, field, and laboratory blanks. The listed concentration is the highest value reported in all blanks associated with the samples. ND = Not detected at the laboratory's detection limit. J = Estimated value since concentration is less than the laboratory's reporting limit and greater than the detection limit. B = Probable field and/or laboratory contamination since the concentration is within five times the concentration reported in the associated quality control blanks. DL = Detection limit. QL = Quantitation limit (NC SWSL). --- = Monitoring well was not sampled. Town of Kernersville Landfill Permit No. 34-04 Page 1 of 1 Joyce Engineering TABLE 6: BIODEGRADATION SCREENING MATRIX Parameter Concentration in Plume Interpretation Possible Points Points Awarded with DP points Points Awarded without DP points Oxygen < 0.5 mg/L Tolerated, suppresses the reductive pathway at higher 3 0 0 concentrations > 5 mg/L Not tolerated; however, vinyl chloride may be oxidized -3 0 0 aerobically Nitrate < 1 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Iron II (Ferrous Iron) > 1 mg/L Reductive pathway possible; vinyl chloride may be 3 0 0 oxidized under Fe (III) - reducing conditions Sulfate < 20 mg/L At higher concentrations may compete with reductive 2 2 2 pathway Sulfide > 1 mg/L Reductive pathway possible 3 0 0 Methane < 0.5 mg/L Vinyl chloride oxidizes 0 > 0.5 mg/L Ultimate reductive daughter product, vinyl chloride 3 0 0 accumulates Oxidation Reduction < 50 mV Reductive pathway possible 1 1 1 Potential < -100 mV Reductive pathway likely 2 pH 5 < pH < 9 Optimal range for reductive pathway 0 0 0 5 > pH > 9 Outside optimal range for reductive pathway -2 0 0 TOC > 20 mg/L Carbon and energy source; drives dechlorination; can 2 0 0 be natural or anthropogenic Temperature >200 C At T > 200C biochemical process is accelerated 1 0 0 Carbon Dioxide > 2x background Ultimate oxidative daughter product 1 0 0 Alkalinity > 2x background Results from interaction between CO2 and 1 1 1 aquifer minerals Chloride > 2x background Daughter product of organic chlorine 2 2 2 Hydrogen > 1 nM Reductive pathway possible 3 3 3 < 1 nM Vinyl chloride oxidizes 0 Volatile Fatty Acids > 0.1 mg/L Intermediates resulting from biodegradation of more 2 0 0 complex compounds; carbon and energy source BTEX > 0.1 mg/L Carbon and energy source; drives dechlorination 2 0 0 Tetrachloroethene (PCE) --- Material released 0 0 0 Trichloroethene (TCE) --- Material released 0 0 1 0 --- Daughter product of PCE 2 2 0 Dichloroethenes (DCE) --- Material released 0 0 0 Daughter product of TCE 2 2 0 Dichloroethene, cis-1,2, --- Material released 0 0 0 --- Daughter product of trichlorethene 2 2 0 Vinyl Chloride (VC) --- Material released 0 0 0 --- Daughter product of DCE 2 2 0 1, 1, 1 -Trichloroethane (TCA) --- Material released 0 0 0 1,1-Dichloroethane (DCA) --- Material released 0 0 0 Daughter product of TCA 2 2 0 Chloroethane --- Daughter product of dichloroethane or vinyl chloride 0 0 0 under reducing conditions 2 2 0 Ethene/Ethane > 0.01 mg/L Daughter products of vinyl chloride/ethene 2 0 0 > 0.1 mg/L 3 0 0 Chloroform --- Material released 0 0 0 --- Daughter product of carbon tetrachloride 2 0 0 Dichloromethane (MC) --- Material released 0 0 0 (Methylene Chloride) --- Daughter product of chloroform 2 0 0 Based on data collected in November 2014. Total Points Awarded: 23 11 mg/L = miligrams per liter mV = millivolts nM = Nanometer C = Celcius NOTE: Chloroethane, Methane, TCE, DCE, cis-1,2-DCE, MC, VC, DCA, and CO2 are all present in the plume; however, it is uncertain whether these are primary leachate constituents or daughter products (DPs); therefore, we have two calculation columns. The first column assumes all of these are daughter products, and the NA = Not Analyzed I second column assumes none of them are. The true score is probably between the two. BTEX = Sum of Benzene, Toluene, Ethylbenzene, and Total Xylenes This screening matrix is prepared in general accordance with the United Stated Environmental Protection Agency's (EPA's) Table 2.3 Analytical Parameters and Weighted for Preliminary Screening for Anaerobic Biodegradation Process presented in the EPA's Technical Protocol for Evaluating Natural Attenuation of Chlorinated Solvents in Groundwater, September 1988. SCORE: Evid. of Nat. Atten. < 5 inadequate 6-14 limited 15-19 adequate > 20 strong Town of Kernersville Joyce Engineering