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MO-88110_88110_CA_O_20180510_April 2018 WSW Sampling Event - No Sample Collected
E r 1 V E C442imo. May 7, 2018 Delivery via FedEx Mrs. Pam Mercer 10655 Stonewall Road Huntersville, NC 28078 MAY 10 2018 d wed' Subject: April 2017 Water Well Sampling Event - No Sample Collected Poplar Tent Road Site, Concord, North Carolina NCDEQ Groundwater Incident Number 88110 Dear Mrs. Mercer: CH2M HILL North Carolina, Inc. 14120 Ballantyne Corporate Place Suite 200 Charlotte, NC 28277 O +1 '704 544 4040 F +1 704.544 4041 www.ch2m.corn As you are aware, CH2M HILL North Carolina, Inc. (CH2M), working on behalf of Plantation Pipe Line Company (Plantation), has been monitoring groundwater in the area of the above referenced site as part of a Corrective Action Plan (CAP) required by the North Carolina Department of Environmental Quality (NCDEQ) in response to a turbine fuel release that occurred in April 1976. As part of this monitoring, in April 2018, our team attempted to collect a sample from the water supply well located on the late Ms. Mary Mercer property located at 15700 Poplar Tent Road. The team discovered that the well pump is not operational and it appears that electrical service to the home has been turned off. We will attempt to collect a sample during the next semiannual monitoring event, which is scheduled for October 2018. If you have any questions, or wish to discuss any matter involving the previous sampling results or Plantation's monitoring in the area, please do not hesitate to contact Mr. Jerry Aycock with Plantation at 770.751.4165. Sincerely, CH2M HILL North Carolina, Inc. Mike Skeean, P.E. Project Manager N.C. Professional Engineer License No. 030914 cc: Jerry Aycock/Plantation Brett Morris/NCDEQ DWM MRO William F. Pilkington, D.P.A, Cabarrus County Health Director/Cabarrus Health Alliance David Troutman, R.S., Environmental Health/Cabarrus Health Alliance File — CH2M May 7, 2018 Delivery via Fed Ex Stephen and Teresa Duffey 11092 Poplar Tent Road Huntersville, NC 28078 Subject: April 2018 Water Well Sampling Results Poplar Tent Road Site, Concord, North Carolina NCDEQ Groundwater Incident Number 88110 Dear Mr. and Ms. Duffey: CH2M HILL North Carolina, Inc. 14120 Callantyne Corporate Place Suite 200 Charlotte, NC 28277 O +1 704 544 4040 F +1 704 544 4041 www.ch2m.com RECEIVED MAY 1 0 2018 NCDEQ MR.. USSOT As you are aware, CH2M HILL North Carolina, Inc. (CH2M), working on behalf of Plantation Pipe Line Company (Plantation), has been monitoring groundwater in the area of your property as part of a Corrective Action Plan (CAP) required by the North Carolina Department of Environmental Quality (NCDEQ) in response to a turbine fuel release that occurred in April 1976. As part of this monitoring, samples were collected in April 2018 from the water supply well located on your property. For the purposes of our monitoring activities, we have designated this well as WSW-13. The samples were analyzed by SGS Accutest Laboratories of Scott, Louisiana and Gulf Coast Analytical Laboratories (GCAL) of Baton Rouge, Louisiana for benzene, toluene, ethylbenzene, xylenes (BTEX), and naphthalene using Environmental Protection Agency (EPA) Method 8260B. The BTEX and naphthalene compounds are found in petroleum products and serve as an indicator of petroleum contamination in the environment. The following is a summary of the April 2018 analytical results: The samples collected on April 17, 2018, from well WSW-13, did not contain detectable concentrations of BTEX or naphthalene. Copies of the validated laboratory analytical reports are attached for your review (Attachment A). When reviewing the attached laboratory reports, please refer to the results associated with Sample ID WSW-13. If you have any questions, or wish to discuss any matter involving these results or Plantation's monitoring in the area, please do not hesitate to contact Mr. Jerry Aycock with Plantation at 770.751.4165. STEPHEN AND TERESA DUFFEY PAGE 2 MAY 7, 2018 Sincerely, CH2M HILL North Carolina, Inc. A� Mike Skeean, P.E. Project Manager N.C. Professional Engineer License No. 030914 Attachment Laboratory Analytical Reports cc: Jerry Aycock/Plantation Brett Morris/NCDEQ DWM MRO William F. Pilkington, D.P.A, Cabarrus County Health Director/Cabarrus Health Alliance David Troutman, R.S., Environmental Health/Cabarrus Health Alliance File — CH2M Attachment A Laboratory Analytical Report April 17, 2018 Sample (Sample ID WSW-13) MEMORANDUM Ch2' Data Validation Summary— Plantation Pipe Line Company Poplar Tent Road Site PREPARED FOR: Kelly Ramsey/CH2M/CLT PREPARED BY: Tiffany Davis/CH2M/GNV cOPYTO: Juan Acaron/CH2M/GNV DATE: May 1, 2018 Introduction The purpose of this memorandum is to present the results of the data validation process for the water supply well samples collected at the Plantation Pipe Line Company (PPL) Poplar Tent Road Site. The samples were collected in April 2018. Samples were submitted to Accutest Laboratories in Scott, Louisiana and GCAL in Baton Rouge, Louisiana for the following analyses: • SW8260B Volatile Organic Compounds (VOCs) These data were validated for compliance with the analytical method requirements. This process included a review of these data to assess the accuracy, precision, and completeness based upon procedures described in guidance documents such as the Environmental Protection Agency (EPA) National Functional Guidelines for Organic Data Review (EPA 2017). The quality assurance/quality control (QA/QC) summary forms and data reports were reviewed and the resulting findings are documented within each subsection that follows. During the data validation, if QA/QC parameters were not within the acceptance limits, associated sample results were appended with a primary qualifying flag that indicated a possible anomaly with these data. The qualifying flags originated during the data review and validation processes. This qualification also included the use of secondary sub -qualifier flags. The secondary qualifiers provide the reasoning behind the assignment of a qualifier to these data. The definitions of the primary qualifiers are presented below. Validation Flag Definitions The following primary qualifiers were used to qualify the data: [=]: Detected. The analyte was analyzed for and detected at the concentration shown. [J]: Estimated. The analyte was present but the reported value may not be accurate or precise. [U]: Undetected. The analyte was analyzed for but not detected above the method detection limit. [UJ]: Detection limit estimated. The analyte was analyzed for but qualified as not detected; the detection limit is estimated. [R]: Rejected. The data are not useable. [X]: Excluded. Data were not used due to another value being more appropriate. DATA VALIDATION SUMMARY- PLANTATION PIPELINE COMPANY POPLAR TENT ROAD SITE Organic Parameters Quality Control Review The following list represents the QA/QC measures that were reviewed during the data quality evaluation procedure for organic data: • Holding Times — The holding times are evaluated to verify that samples were extracted and analyzed within holding times. • Blank samples — Method blank and trip blank samples were provided for this project. Blank samples enable the reviewer to determine if an analyte may be attributed to sampling or laboratory procedures, rather than environmental contamination from site activities. • Surrogate Recoveries — Surrogate compounds are added to each sample and the recoveries are used to monitor lab performance and possible matrix interference. • Lab Control Sample/Lab Control Sample Duplicate (LCS/LCSD) —These samples are a "controlled matrix," laboratory reagent water, in which target compounds have been added prior to extraction/analysis. The recoveries serve as a monitor of the overall performance of each step during the analysis, including sample preparation. • Matrix Spike/Matrix Spike Duplicate (MS/MSD) Samples — Spike recovery is used to evaluate potential matrix interferences, as well as accuracy. Precision information is also determined by calculating the reproducibility between the recoveries of each spiked parameter. • Field Duplicate Samples —These samples are collected to determine precision between a native and its duplicate. This information can only be determined when target compounds are detected. Volatile Organic Compound Analyses The QA/QC parameters for VOC analyses by SW-846 8260E for all of the samples were within acceptable control limits with the exceptions listed below. A brief overview of the data evaluation follows. Holding Time All holding time requirements were met. Field Duplicates Duplicate field samples were collected and submitted to the laboratory for analysis. There are two conditions under which the native and field duplicate are deemed outside acceptance criteria. For condition one, if a result for the native and field duplicate are less than five times the reporting limit, the two results must be within one times the reporting limit to meet acceptance criteria. In condition two, if the result is greater than five times the reporting limit, the two results must agree to within 20 percent relative percent difference to meet acceptance criteria. All field duplicate precision criteria were met. Recoveries - Surrogate, MS/MSD, and LCS/LCSD Surrogates, MS/MSD, and LCS/LCSD recoveries all met acceptance criteria. Analytical Blanks No detects were found in the analytical blanks. DATA VALIDATION SUMMARY- PLANTATION PIPE LINE COMPANY POPLAR TENT ROAD SITE PARCC Precision is defined as the agreement between duplicate results, and was estimated by comparing duplicate MS recoveries, and field duplicate sample results. The precision between the native and field duplicate sample results for the analyses were within acceptable criteria indicating that the sample matrix did not significantly interfere with the overall analytical process. Accuracy is a measure of the agreement between an experimental determination and the true value of the parameter. In the case of VOC analysis, each of the samples were spiked with a surrogate compound with a known concentration before preparation. The surrogate and MS/MSD data provides a measure of the matrix effects as they may affect accuracy and precision of the analytical method. The LCS results demonstrate accuracy of the method. Spike recoveries were within the method acceptance limits, showing no evidence of matrix interferences that affect the usability of the data. Representativeness criteria are a qualitative measure of the degree to which sample data accurately and precisely represent a characteristic environmental condition. Representativeness is a subjective parameter and is used to evaluate the efficacy of the sampling plan design. Representativeness was demonstrated by providing full descriptions in the project scoping documents of the sampling techniques and the rationale used for selecting sampling locations. Completeness is defined as the percentage of measurements that are judged to be valid compared to the total number of measurements made. There were no data rejected and or seen as not usable due to quality control or sampling issues. Comparability is another qualitative measure designed to express the confidence with which one data set may be compared to another. Factors that affect comparability are sample collection and handling techniques, sample matrix type, and analytical method. Comparability is limited by the other PARCC parameters because data sets can be compared with confidence only when precision and accuracy are known. Data from this investigation are comparable with other previous data collected at the site due to the laboratories use of EPA or appropriate methods to analyze the samples and supported by the results of the laboratory's analytical reports. Conclusion A review of the analytical data submitted regarding the investigation of the PPL Poplar Tent Road Site sampling event in April 2018 by CH2M has been completed. The validation demonstrated that the analytical systems were in control and all data results can be used in the decision making process. e4f NELAP CERTIFICATE NUMBER: 01955 DOD ELAP CERTIFICATE NUMBER: L14-243 RECEIVED MAY 10 2018 ANALYTICAL RESULTS NCDEQ PERFORMED BY GOAL, LLC 7979 Innovation Park Dr. Baton Rouge, LA 70820 Report Date 04/26/2018 �1111 Report 21I80419¢9 l�ll�l�lull11�1ll III Project Poplar Tent Rd Deliver To Kelly Ramsey Jacobs 11301 Carmel Commons Blvd. Suite 304 Charlotte, NC 28226 704-543-3295 PJLA Test Ing DOD ELAP Additional Recipients Mike Skeean, Jacobs GCAL Report#: 218041949 Page 1 of 11 Report#: 218041949 Project ID: Poplar Tent Rd Laboratory Endorsement Report Date: 04/26/2018 Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or 1 Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature GCAL Report 218041949 GCAL Report#: 218041949 Page 2 of 11 Report#: 218041949 Project ID: Poplar Tent Rd Certifications Report Date: 04/26/2018 Certification Certification Number DOD ELAP L14-243 Alabama 01955 Arkansas 12-060-0 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 USDA Soil Permit P330-10-00117 GCAL Report#: 218041949 Page 3 of 11 a Client: Kinder Morgan Energy Partners Report#: 218041949 Project ID: Poptar Tent Rd Case Narrative Report: 218041949 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Report Date: 04/26/2018 GCAL Report#: 218041949 Page 4 of 11 0"'4®��� Report#: 218041949 Project ID: Poplar Tent Rd Report Date: 04/26/2018 Sample Summary GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21804194901 WSW-13 Water 04/17/2018 09:40 04/19/2018 09:30 21804194902 WSW-1 3-MS Water 04/17/2018 09:40 04/19/2018 09:30 21804194903 WSW-13-MSD Water 04/17/2018 09:40 04/19/2018 09:30 21804194904 Trip Blank Water 04/17/2018 00:01 04/19/2018 09:30 GCAL Report#: 218041949 Page 5 of 11 M= Report#: 218041949 Project ID: Poplar Tent Rd Summary of Compounds Detected No analytes were detected for analyses performed by GCAL. Report Date: 04/26/2018 GCAL Report#: 218041949 Page 6 of 11 Report#; 218041949 GCAL Project ID: Poplar Tent Rd Sample Results Report Date: 04/26/2018 Collect Date 04/17/2018 09:40 GCAL ID 21804194901 WSW-13 Receive Date 04/19l2018 09:30 Matrix Water Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 04/26/2018 05:35 JCK 634281 CAS# Parameter Result LOCI Units 71-43-2 Benzene ND 1.00 ug/L 100-41-4 Ethylbenzene ND 1.00 ug/L 91-20-3 Naphthalene ND 1.00 ug/L 108-88-3 Toluene ND 1.00 ug/L 1330-20-7 Xylene (total) ND 3.00 ug/L CAS# Surrogate Conc. Spiked Conc. Rec Units % Recovery Rec Limits 460-00-4 4-Bromofluorobenzene 50 45.3 ug/L 91 78 - 130 1868-53-7 Dibromofluoromethane 50 48.4 ug/L 97 77 - 127 2037-26-5 Toluene d8 50 50.9 ug/L 102 76 - 134 17060-07-0 1,2-Dichloroethane-d4 50 50.3 ug/L 101 71 - 127 Collect Date 04/17/2018 09:40 GCAL ID 21804194902 WSW-13-MS Receive Date 04/19/2018 09:30 Matrix Water : .1: Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 04/26/2018 06:20 JCK 634281 CAS# Parameter Result LOQ Units 71-43-2 Benzene 53.3 1.00 ug/L 100-41-4 Ethylbenzene 46.2 1.00 ug/L 91-20-3 Naphthalene 51.8 1.00 ug/L 108-88-3 Toluene 49.9 1.00 ug/L 1330-20-7 Xylene (total) 148 3.00 ug/L CAS# Surrogate Conc. Spiked Conc. Rec Units % Recovery Rec Limits 460-00-4 4-Bromofluorobenzene 50 48.9 ug/L 98 78 - 130 1868-53-7 Dibromofluoromethane 50 49.4 ug/L 99 77 - 127 2037-26-5 Toluene d8 50 47.3 ug/L 95 76 - 134 17060-07-0 1,2-Dichloroethane-d4 50 53.4 ug/L 107 71 - 127 GCAL Report#: 218041949 Page 7 of 11 AMW AL� Report#: 218041949 Project ID: Poplar Tent Rd Sample Results Report Date: 04/26/2018 WSW-13-MSD Collect Date 04/17/2018 09:40 GCAL ID 21804194903 Receive Date 04/19/2018 09:30 Matrix Water Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 04/26/2018 06:42 JCK 634281 CAS# Parameter 7143-2 Benzene 100-414 Ethylbenzene 91-20-3 Naphthalene 108-88-3 Toluene 1330-20-7 Xylene (total) CAS# Surrogate 460-00-4 4-Bromofluorobenzene 1868-53-7 Dibromofluoromethane 2037-26-5 Toluene d8 17060-07-0 1,2-Dichloroethane-d4 Result LOQ Units 51.4 1.00 ug/L 45.5 1.00 ug/L 50.6 1.00 ug/L 47.4 1.00 ug/L 143 3.00 ug/L Conc. Spiked Conc. Rec Units % Recovery Rec Limits 50 48.8 ug/L 98 78 - 130 50 49 ug/L 98 77 - 127 50 47.5 ug/L 95 76 - 134 50 51.1 ug/L 102 71 - 127 Trip Blank Collect Date 04/17/2018 00:01 GCAL ID 21804194904 Receive Date 04/19/2018 09:30 Matrix Water Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 04/26/2018 08:34 JCK 634281 CAS# Parameter 71-43-2 Benzene 100-41-4 Ethylbenzene 91-20-3 Naphthalene 108-88-3 Toluene 1330-20-7 Xylene (total) CAS# Surrogate 460-00-4 4-Bromofluorobenzene 1868-53-7 Dibromofluoromethane 2037-26-5 Toluene d8 17060-07-0 1,2-Dichloroethane-d4 Result LOCI Units ND 1.00 ug/L ND 1.00 ug/L ND 1.00 ug/L ND 1.00 ug/L ND 3.00 ug/L Conc. Spiked Conc. Rec Units % Recovery Rec Limits 50 43.9 ug/L 88 78 - 130 50 49.4 ug/L 99 77 - 127 50 50.5 ug/L 101 76 - 134 50 51.5 ug/L 103 71 - 127 GCAL Report#: 218041949 Page 8 of 11 Report#: 218041949 Project ID: Poplar Tent Rd GC/MS Volatiles QC Summary Report Date: 04/26/2018 Analytical Batch Client ID MB634281 LCS634281 LCSD634281 634281 GCALID 1801826 1801827 1801828 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 04/26/2018 05:13 04/26/2018 03:43 04/26/2018 04:05 Matrix Water Water Water EPA 8260B Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result LOQ Added Limits%R Added Limit Benzene 71-43-2 ND 1.00 50.0 52.8 106 70- 129 50.0 49.3 99 7 20 Ethylbenzene 100-41-4 ND 1.00 50.0 48.7 97 74 - 126 50.0 45.1 90 8 30 Naphthalene 91-20-3 ND 1.00 50.0 59.1 118 57 - 138 50.0 53.7 107 10 35 Toluene 108-88-3 ND 1.00 50.0 50.2 100 72 - 120 50.0 47.0 94 7 20 Xylene (total) 1330-20-7 ND 3.00 150 152 101 74 - 127 150 140 93 8 30 Surrogate 1,2-Dichloroethane-d4 17060-07-0 51.1 102 50 51.7 103 71 - 127 50 50.5 101 NA NA 4-Bromofluorobenzene 460-00-4 44.5 89 50 49.4 99 78 - 130 50 48.4 97 NA NA Dibromofluoromethane 1868-53-7 47.9 96 50 48.6 97 77 - 127 50 48.7 97 NA NA Toluene d8 2037-26-5 50.6 101 50 48.4 97 76 - 134 50 48.8 98 NA NA Analytical Batch Client ID WSW-13 WSW-13-MS WSW-13-MSD 634281 GCALID 21804194901 21804194902 21804194903 Sample Type SAMPLE MS MSD Prep Date NA NA NA Analysis Date 04/26/2018 05:35 04/26/2018 06:20 04/26/2018 06:42 Matrix Water Water Water EPA 8260E Units ug/L Spike Result %R Control Spike Result %R RPD RPD Result LOQ Added Limits%R Added Limit Benzene 71-43-2 0.00 1.00 50.0 53.3 107 70 - 129 50.0 51.4 103 4 20 Ethylbenzene 100-41-4 0.00 1.00 50.0 46.2 92 74 - 126 50.0 45.5 91 2 30 Naphthalene 91-20-3 0.00 1.00 50.0 51.8 104 57 - 138 50.0 50.6 101 2 35 Toluene 108-88-3 0.00 1.00 50.0 49.9 100 72 - 120 50.0 47.4 95 5 20 Xylene (total) 1330-20-7 0.00 3.00 150 148 99 74 - 127 150 143 95 3 30 Surrogate 1,2-Dichloroethane-d4 17060-07-0 50.3 101 50 53.4 107 71 - 127 50 51.1 102 NA NA 4-Bromofluorobenzene 460-00-4 45.3 91 50 48.9 98 78 - 130 50 48.8 98 NA NA Dibromofluoromethane 1868-53-7 48.4 97 50 49.4 99 77 - 127 50 49 98 NA NA Toluene d8 2037-26-5 50.9 102 50 47.3 95 76 - 134 50 47.5 95 NA NA GCAL Report#: 218041949 Page 9 of 11 1-0,00 561 6m IN3110 '-,k8VNVO - 1,80d3H IVNIA INDI-10 :311HM ro cr TT j 0 0 c c W a) cc X D '0 LD \P I J. 2 0 V) �o '0 a) a) ci :3 12 E tsl-- T k I cy 1 16 68 off As Pq, N� A N) T4 cu 'D w 2 Lb 39men. < e.." 00 E C\j CL 0) 1 a 3p, CD cu 0 91 4i c 0 E E -a: .- :3 < 'x -0 rL r- , w < C) z b a: R C 0 � � � � U W m U 0 z 5; W U W w W J LL. � U) 2 ❑ ❑ ❑ ❑ ❑ ❑ ❑ q � � � � � ❑ � � 2 c / k > k \ / E f Cl. n � g E IDE ƒ / = E a © q@ / 2 F __j k ƒ 0- E $ 2 ° E \ E o » & / E 2 7 \ k / / k g ( a) c o c / E / / 7 o \ § a E \ » ƒ E \ E E E o c ° o 3 ° ° ± t C e / / o' k 7 o m m E m S ® 7 % / ( \ \ SO_- \_ e ® n m \ ® \7-5k % f E \ ƒ m / / \ ) / % ° U m 12 O < < E e @ O$ u 2 a. E CD� OfFL m kw CM // M° OR / / 2 i� c � § / � k CL 2 \ 52¥ \ t/ t � / / \ ) � The results set forth herein are provided by SGS North America Inc. e-Hardcopy 2. Automated Report Technical Report for Kinder Morgan CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC 699855. PT. EM SGS Job Number: LA43280 Sampling Date: 04/17/18 Report to: CH2M Hill 14120 Ballantyne Corporate Place Charlotte, NC 28277 mike.skeean@ch2m.com; kelly.ramsey@ch2m.com ATTN: Mike Skeean Total number of pages in report: 18 pctto. /VANE Test results contained within this data package meet the requirements Ron Benja iill n of the National Environmental Laboratory Accreditation Program Lab Director and/or state specific certification programs as applicable. Client Service contact: Ralph Frye 337-237-4775 Certifications: LDEQ(2048), LDHH(LA150012), AR(14-045-04), AZ(AZ0805), FL(E87657), IL(200082), KY(#31), NC(487), SC(73004001), NJ(LA007), TX(T104704186-15-7), WV(257) This report shall not be reproduced, except in its entirety, without the written approval of SGS. Test results relate only to samples analyzed. SGS North America Inc. • 500 Ambassador Caffery • Scott, LA 70583 • tel: 337-237-4775 SGS is the sole authority for authorizing edits or modifications to this document. Please :,hare your ideas 11)OLIt Unauthorized modification of this report is strictly prohibited. how we can serve you better at: Review standard terms at: littp://www.sgs.com/en/tenns-and-conditions EFI'S.US.CustomerCare@sgs.coni LA43280 Table of Contents -K- SectionD:Sample Summary ................................................................................................... 3 N�N� SectionZ:Summary ofHits .................................................................................................... 4 .......... 5 LA43280-1: W8W-13 -------.-------------------------.. 6 LA43200-2: TRlPBLAN}I.......................................................................................... 7 Section4;Misc. Forms ............................................................................................................ ___-, 4.1: Chain of -------.----------------------------. 8 g Section 5/NIS Volwtilem-Q(" Data Summaries ..................................................................... 12 5.X:Method Blank Summary ----.-------------.--------------. 13 5.2:B}oukSpike/Blank Spike Duplicate Summary .............................................................. 15 SGS North America Inc. Sample Summary Kinder Morgan Job No: LA43280 CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Project No: 699855.PT.EM Sample Collected Matrix Client Number Date Time By Received Code Type Sample ID LA43280-1 04/17/18 09:40 NU/JR 04/19/18 AQ Ground Water WSW-13 LA43280-ID 04/17/18 09:40 NU/JR04/19/18 AQ Water Dup/MSD WSW-13 LA43280-IS 04/17/18 09:40NU/JR04/19/18 AQ Water Matrix Spike WSW-13 LA43280-2 04/17/18 00:00 NU/JR04/19/18 AQ Trip Blank Water TRIP BLANK n 3of18 ;_ LA43280 Summary of Hits Page I of 1 Job Number: LA43280 Account: Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Collected: 04/ 17/ 18 Lab Sample ID Client Sample ID Result/ Analyte Qual RL MDL Units Method LA43280-1 WSW-13 No hits reported in this sample. LA43280-2 TRIP BLANK No hits reported in this sample. 4of18 SGS LA43280 SC3 Scf.)tt, LA Sample Results Report of Analysis 5 of 18 LA43280 SGS North America Inc. Report of Analysis Client Sample ID: WSW-13 Lab Sample ID: LA43280-1 Date Sampled: 04/ 17/ 18 Matrix: AQ - Ground Water Date Received: 04/ 19/ 18 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Page 1 of l File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 1I031923.13 1 04/20/18 12:28 NN n/a n/a V1I1471 Run #2 Purge Volume Run #1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound 71-43-2 Benzene 108-88-3 Toluene 100-414 Ethylbenzene 1330-20-7 Xylene (total) 91-20-3 Naphthalene CAS No. Surrogate Recoveries 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-138 460-00-4 4-Bromofluorobenzene Result RL Units Q ND 1.0 ug/1 ND 1.0 ug/1 ND 1.0 ug/1 ND 2.0 ug/I ND 5.0 ug/1 Run# 1 Run# 2 Limits 100% 84-124% 97% 83-115% 92% 89-111 % ND = Not detected RL = Reporting Limit E = Indicates value exceeds calibration range J = Indicates an estimated value B = Indicates analyte found in associated method blank N = Indicates presumptive evidence of a compound Sof18 - LA43280 SGS North America Inc. Report of Analysis Client Sample ID: TRIP BLANK Lab Sample ID: LA43280-2 Date Sampled: 04/ 17/ 18 Matrix: AQ - Trip Blank Water Date Received: 04/ 19/ 18 Method: SW846 8260B Percent Solids: n/a Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Page I of I File ID DF Analyzed By Prep Date Prep Batch Analytical Batch Run #1 2X0044076.D 1 04/20/18 18:07 LS n/a n/a V2X781 Run #2 Purge Volume Run # 1 5.0 ml Run #2 Purgeable Aromatics, Naphthalene CAS No. Compound Result RL Units Q 71.-43-2 Benzene ND 1.0 ug/1 1.08-88-3 Toluene ND 1.0 ug/1 1.00-41-4 Ethylbenzene ND 1.0 ug/I 1330-20-7 Xylene (total) ND 2.0 ug/1 91-20-3 Naphthalene ND 5.0 ug/1 CAS No. Surrogate Recoveries Run# 1 Run# 2 Limits 17060-07-0 1,2-Dichloroethane-D4 94% 84-124% 2037-26-5 Toluene-D8 100% 83-115% 460-00-4 4-Bromofluorobenzene 101% 89-111% ND = Not detected J = Indicates an estimated value RL = Reporting Limit B = Indicates analyte found in associated method blank E = Indicates value exceeds calibration range N = Indicates presumptive evidence of a compound 7of18 SGS_,_ LA43264 Misc. Forms Custody Documents and Other Forms Includes the following where applicable: • Chain of Custody Section 4 � 41 8of18 l A43280 01, SGS ACOUTEST CHAIN OF CUSTODY SGS Acc" 00 AmbassadorAmbassadorCffy=Y, tSc.0, LA 70583 TEL. 337-237.4775 FAA: 337.237.7938 stalest. rom PAGE OF A Z sqS matrix Codes Cc.kp,y Name LM")M Project Name I 04 - wwWarr 1 sw - Sez. Wow so � so.; SL- $Iidg. SED-ScMm.. 01-04 U0-Other Uq.L' AR S. -oc Sod "Vp - wzp. FS-F; WWFl M-Eq. —t EMar. k 'p RZ10.1111n, 11 -Tn Street Add.. 14 Skeet (ifdftrent*MRe� i city Stun city 'E'nal prole's # 911 1000 �Ykjw" CJLWPu,� to N, M .... J F- M-1 N4 (50 6- E Field ID nj. Poi collection oaw T.. sanded ME ONLY Of Q04112 OCI14D k)1QV- 6V) S.,I) Niau N49 wbt 60 I �' T-P i46LA V, —3 .F p1l I 7--,, T2 (Busmess days) ROM Data Deliverable In adon 7, MR rl,dl,d y Rush [M 4 Day RUSH 0 3 0.y RUSH ❑ 2 Dy RUSH ❑1 D.y RUSH ❑ other E..menw & Rush TlAdsl, v7agable VIALaUnk ConurnercialW (Lovell)5 Conunemuil"S,(L-12) FULTI (L-1344) REDTI (L.-13.$) [=I C—W,c" j C-6.1 W R— ftolay, I N C.—..W T' R.1A. - OC S—,y� c—..WC: R—lbi.0c & S.".g.st—.,y EDD Format Slit. F— Other 0� Vao-4,-, j��-VV4, (4> (M lice. S�ceeo-A INote: Sample invenio is venfled u on recei t In the Laboalo I k*Ie Custody must be documented below each time samples thangi jissession, 1n;Iuding couiier davery. /)A-3,� .MW MR M,7 JILMMMOMPNIV F-Rw —0MV- Zl�,'� TM by sander ant TM: eceNed By: Rdingtr�F.ed BY 2 IMT 137W 3 4 4 b, LA43280: Chain of Custody Page I of 3 SGS: 9 of 18 LA43280 APR HOLD OVERNIGHT HLD 70508 1-4:kh LA43280: Chain of Custody Page 2 of 3 ,--SGS 10 of 18 LA43280 SGS Sample Receipt Summary Job Number: LA43280 Client: CH2M/JACOBS Project: POPLAR TENT ROAD Date / Time Received: 4/19/2018 9:05:00 AM Delivery Method: FedEx Airbill Ws: 780571913556 Cooler Temps (Initial/Adjusted): #1: (2.7/2.7): Cooler Security Y or N Y or N 1. Custody Seals Present: W L 3. COC Present: 2. Custody Seals Intact: FV _, 4. Smpl Dates/Time OK Cooler Temperature 1. Temp criteria achieved: Y or 1y'; N 2. Thermometer ID: DV439; 3. Cooler media: Ice (direct contact) 4. No. Coolers: 1 Quality Control Preservation Y or N N/A 1. Trip Blank present / cooler: ❑ ❑ ❑� 2. Trip Blank listed on COC: ❑ ❑ 0 3. Samples preserved properly: ❑ ❑ 4. VOCs headspace free: ❑ ❑ V Samole Integrity - Documentation Y or IN 1. Sample labels present on bottles: ❑ 2. Container labeling complete: C El 3. Sample container label / COC agree: J ❑ Sample Intearity - Condition Y or N 1. Sample recvd within HT: 2. All containers accounted for: ® ❑ 3. Condition of sample: Intact Sample Intearity - Instructions Y or N IN 1. Analysis requested is clear: ® ❑ 2. Bottles received for unspecified tests ❑ 0 3. Sufficient volume recvd for analysis: ] ❑ 4. Compositing instructions clear: ❑ ❑ W 5. Filtering instructions clear: ❑ ❑ 1 LA43280. Chain of Custody Page 3 of 3 LA43280 a nti 1 0 \ ti MS Volatiles QC Data Summaries Includes the following where applicable: • Method Blank Summaries • Blank Spike Summaries • Matrix Spike and Duplicate Summaries 12of1$ LA43280 Method Blank Summary Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Page I of 1 Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V 1 I1471-MB2 1 I031921. D 1 04/20/ 18 NN n/a n/a V 1 I 1471 The QC reported here applies to the following samples: LA43280-1 CAS No. Compound Result RL Units Q 71-43-2 Benzene ND 1.0 ug/l 100-41-4 Ethylbenzene ND 1.0 ug/l 91-20-3 Naphthalene ND 5.0 ug/I 108-88-3 Toluene ND 1.0 ug/l 1330-20-7 Xylene (total) ND 2.0 ug/l CAS No. Surrogate Recoveries Limits 17060-07-0 1,2-Dichloroethane-D4 97% 84-124% 2037-26-5 Toluene-138 97% 83-115% 460-00-4 4-Bromofluorobenzene 91% 89-111% Method: SW846 8260B 0 13 of 18 LA43280 Method Blank Summary Page 1 of 1 Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2X781-MB2 2X0044050.D 1 04/20/18 LS n/a n/a V2X781 The QC reported here applies to the following samples: Method: SW846 8260B LA43280-2 CAS No. Compound 71-43-2 Benzene 100-41-4 Ethylbenzene 91-20-3 Naphthalene 108-88-3 Toluene 1330-20-7 Xylene (total) CAS No. Surrogate Recoveries 17060-07-0 1,2-Dichloroethane-D4 2037-26-5 Toluene-138 460-00-4 4-Bromofluorobenzene Result RL Units Q ND 1.0 ug/I ND 1.0 ug/I ND 5.0 ug/I ND 1.0 ug/l ND 2.0 ug/l Limits 92% 84-124% 98% 83-115% 96% 89-111% 14 of 18 LA43280 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V1I1471-BS1 11031915.1) 1 04/20/18 NN n/a n/a V1I1471 V 1I1471-BSD 1 1I031917. D 1 04/20/ l 8 NN n/a n/a V 111471 The QC reported here applies to the following samples: Method: SW846 8260B LA43280-1 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/I % ug/1 % RPD Rec/RPD 71-43-2 Benzene 20 20.1 101 19.5 98 3 82-119/30 100-414 Ethylbenzene 20 19.6 98 19.0 95 3 84-117/30 91-20-3 Naphthalene 20 18.0 90 18.0 90 0 74-136/30 1.08-88-3 Toluene 20 19.7 99 1.9.0 95 4 80-121/30 1330-20-7 Xylene (total) 60 60.0 100 5T8 96 4 81-122/30 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 95% 94% 84-124% 2037-26-5 Toluene-138 99% 98% 83-115% 460-00-4 4-Bromofluorobenzene 98% 98% 89-111% * = Outside of Control Limits. t5of18 LA43280 Blank Spike/Blank Spike Duplicate Summary Page 1 of 1 Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch V2X781-BSI 2X0044044.13 1 04/20/18 LS n/a n/a V2X781 V2X781-BSD2 2X0044046.D 1 04/20/18 LS n/a n/a V2X781 The QC reported here applies to the following samples: Method: SW846 8260B LA43280-2 Spike BSP BSP BSD BSD Limits CAS No. Compound ug/l ug/l % ug/1 % RPD Rec/RPD 71-43-2 Benzene 20 20.9 105 19.9 100 5 82-119/30 100-41-4 Ethylbenzene 20 20.7 104 19.6 98 5 84-117/30 91-20-3 Naphthalene 20 19.2 96 18.6 93 3 74-136/30 108-88-3 Toluene 20 21.0 105 20.1 101 4 80-121/30 1330-20-7 Xylene (total) 60 63.8 106 60.7 101 5 81-122/30 CAS No. Surrogate Recoveries BSP BSD Limits 17060-07-0 1,2-Dichloroethane-D4 98% 94% 84-124% 2037-26-5 Toluene-138 99% 100% 83-115% 460-00-4 4-Bromofluorobenzene 99% 100% 89-111% * = Outside of Control Limits. 1 16 of 18 _.._ . LA43280 Matrix Spike/Matrix Spike Duplicate Summary Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF LA43280-1MS 1I031955.13 2 LA43280-IMSD 1I031957.13 2 LA43280-1 1.1031923. D 1 Analyzed By Prep Date 04/20/18 NN n/a 04/20/18 NN n/a 04/20/18 NN n/a Page 1 of 1 Prep Batch Analytical Batch n/a V1I1471 n/a V 1I1471 n/a VlI1471 The QC reported here applies to the following samples: Method: SW846 8260B LA43280-1 LA43280-1 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/1 % ug/I ug/I % RPD Rec/RPD 71-43-2 Benzene ND 40 38.4 96 40 36.1 90 6 31-161/15 100-41-4 Ethylbenzene ND 40 36.5 91 40 34.9 87 4 47-146/30 91-20-3 Naphthalene ND 40 32.5 81 40 33.1 83 2 34-169/42 108-88-3 Toluene ND 40 37.0 93 40 35.0 88 6 36-155/17 1330-20-7 Xylene (total) ND 120 111 93 120 106 88 5 41-154/29 CAS No. Surrogate Recoveries MS MSD LA43280-1 Limits 17060-07-0 1,2-Dichloroethane-D4 95% 96% 100% 84-124% 2037-26-5 Toluene-138 98% 98% 97% 83-115% 460-00-4 4-Bromofluorobenzene 99% 98% 92% 89-111% * = Outside of Control Limits. 17 of 18 LA43280 Matrix Spike/Matrix Spike Duplicate Summary Page I of I Job Number: LA43280 Account: KINDERGA Kinder Morgan Project: CHMHNCC:PPL/Poplar Tent Road (Water Wells), Concord, NC Sample File ID DF Analyzed By Prep Date Prep Batch Analytical Batch LA43291-6MS 2X0044088.13 5 04/20/18 LS n/a n/a V2X781 LA43291-6MSD 2X0044090.D 5 04/20/18 LS n/a n/a V2X781 LA43291-6 2X0044064. D 1 04/20/18 LS n/a n/a V2X781 The QC reported here applies to the following samples: Method: SW846 8260B LA43280-2 LA43291-6 Spike MS MS Spike MSD MSD Limits CAS No. Compound ug/l Q ug/l ug/l % ug/l ug/l % RPD Rec/RPD 71-43-2 Benzene ND 100 101 101 100 97.0 97 4 31-161/15 100-41-4 Ethylbenzene ND 100 97.4 97 100 95.2 95 2 47-146/30 91-20-3 Naphthalene ND 100 85.3 85 100 86.7 87 2 34-169/42 108-88-3 Toluene ND 100 98.0 98 100 97.5 98 1 36-155/17 1330-20-7 Xylene (total) ND 300 293 98 300 285 95 3 41-154/29 CAS No. Surrogate Recoveries MS MSD LA43291-6 Limits 17060-07-0 1,2-Dichloroethane-D4 96% 96% 93% 84-124% 2037-26-5 Toluene-138 99% 99% 99% 83-115% 460-00-4 4-Bromofluorobenzene 99% 99% 98% 89-111% * = Outside of Control Limits. 18 of 18 SGS LA43280