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HomeMy WebLinkAbout5001_Jackson_WCU_MSWLF_GW_FID1358279_20190919wood. AUGUST 2019 SEMI-ANNUAL WATER QUALITY AND LANDFILL GAS MONITORING REPORT Western Carolina University Closed Municipal Solid Waste Landfill Monteith Gap Road Cullowhee, Jackson County, North Carolina 28723 NCDEQ Permit: 50-01 Prepared For: Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Prepared by: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 September 19, 2019 Wood Project 6252-15-0221 wood. Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, NC 28806 USA September 19, 2019 Mr. Roger Turk Western Carolina University 3476 Old Cullowhee Road Cullowhee, North Carolina 28723 Subject: August 2019 Water Quality and Landfill Gas Monitoring Report WCU Closed Municipal Solid Waste Landfill Cullowhee, Jackson County, North Carolina NCDEQ Permit: 50-01 Wood Project 6252-15-0221 Dear Mr. Turk: T:828-252-8130 www.woodpic.com Wood Environment & Infrastructure Solutions, Inc. (Wood) is pleased to submit this August 2019 Water Quality and Landfill Gas Monitoring Report for Western Carolina University's (WCU's) closed municipal solid waste landfill located in Cullowhee, North Carolina. The scope of work for this monitoring event was described in Wood's Proposal for Environmental Services, dated April 25, 2019. Wood appreciates the opportunity to provide our environmental services to WCU. If you have any questions concerning this report, please contact us at (828) 252-8130. Sincerely, Wood Environment & Infrastructure Solutions, Inc. Gw, Avv/-,�r Rodney M. Clark, L.G. Susan E. Avritt, P.E., L.G. ror n e C Iar K- Technical Professional with permis ion Senior Engineer RMC/SEA:rmc cc: Ms. Jaclynne Drummond — NCDEQ Solid Waste Section, Asheville Regional Office Mr. Lee Hill — NCDEQ Solid Waste Section, Asheville Regional Office North Carolina Corporate Engineering License No. F-1253; Geology No. C-247.., . o August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 TABLE OF CONTENTS Page 1. Introduction..................................................................................................................................1 1.1. Site -Specific Information............................................................................................................................1 1.2. Background Information............................................................................................................................1 2. Field Activities..............................................................................................................................3 2.1. Landfill Gas Monitoring..............................................................................................................................3 2.2. Water Quality Monitoring..........................................................................................................................3 3. Results and Discussion................................................................................................................5 3.1. Landfill Gas.......................................................................................................................................................5 3.2. Groundwater and Surface Water............................................................................................................5 3.2.1. Appendix I VOCs.......................................................................................................................................5 3.2.2. 1,4- D i oxa n e................................................................................................................................................. 6 3.2.3. Appendix I Metals....................................................................................................................................6 LIST OF TABLES 1 Landfill Gas Well Construction Details 2 Well Construction and Water Level Data — August 2019 3 Groundwater Quality Data — August 2019 4 Groundwater Analytical Results — August 2019 5 Surface Water Analytical Results — August 2019 6 Historical Groundwater Analytical Results 7 Historical Surface Water Analytical Results LIST OF FIGURES 1 Topographic Site Map 2 Site Map with Monitoring Locations APPENDICES A Landfill Gas Monitoring Data Form B Groundwater Sampling Logs C NCDEQ Environmental Monitoring Reporting Form D Laboratory Analytical Report August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 1. INTRODUCTION This report documents field activities and results from the August 2019 water quality and landfill gas monitoring event at Western Carolina University's (WCU's) closed Municipal Solid Waste Landfill (MSWLF) located in Cullowhee, North Carolina (Site) as shown on Figure 1. 1.1. Site -Specific Information Site Name: WCU Closed MSWLF Facility Permit Number: Facility Latitude/Longitude: Site Location Map: Facility Address: Facility Owner: 50-01 N 350 19' 30" / W 830 10' 55" Figure 1 Monteith Gap Road Cullowhee, North Carolina Jackson County Western Carolina University Attn. Mr. Roger Turk 3476 Old Cullowhee Road Cullowhee, North Carolina, 28723 (828) 227-3571 Primary Consultant: Wood Environment & Infrastructure Solutions, Inc. 1308-C Patton Avenue Asheville, North Carolina 28806 (828) 252-8130 1.2. Background Information WCU operated the MSWLF from approximately the 1960s until 1993. Jackson County also disposed of municipal solid waste at the landfill from approximately the early 1970s through the early 1980s. The landfill property is approximately 31.5 acres, approximately four acres of which contain the former landfill. The landfill was closed in accordance with the then applicable North Carolina Department of Environmental Quality (NCDEQ) closure standards (15A NCAC 13B 0.0510), and a closure letter was issued to WCU by NCDEQ on September 5, 1995. NCDEQ personnel conducted a facility audit on March 16, 2011 and determined that semi-annual water quality and landfill gas monitoring at the landfill must be performed in order for the landfill to be in compliance with the post -closure conditions identified in the 1995 closure letter. In response to the audit, a Landfill Gas Investigation Work Plan, which described the preliminary landfill gas investigation, as well as the 'full' landfill gas investigation, was submitted to NCDEQ on October 19, 2011, and approved by NCDEQ in a letter dated November 29, 2011. Wood August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 Environment & Infrastructure Solutions, Inc. (Wood) conducted the preliminary landfill gas investigation in January 2012 using the existing groundwater monitoring wells. NCDEQ indicated that when funding became available to WCU from the State of North Carolina, the 'full' landfill gas investigation was to be implemented. Wood has conducted semi-annual water quality monitoring since August 2011 and conducted semi-annual landfill gas monitoring utilizing the existing groundwater monitoring wells from August 2012 to November 2015 to comply with the post - closure conditions. The 'full' landfill gas investigation, including the installation of eight permanent landfill gas monitoring wells, was performed in February 2016. Quarterly landfill gas monitoring is now conducted. 2 August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 2. FIELD ACTIVITIES Wood personnel visited the Site on August 20, 2019 to conduct water quality monitoring and on August 21, 2019 to conduct landfill gas monitoring. 2.1. Landfill Gas Monitoring Wood personnel measured landfill gas at the eight landfill gas monitoring wells (LG-1, LG-2, LG-3S, LG-3D, LG-4, LG-5, LG-6 and LG-7) at the Site (Figure 2). The landfill gas monitoring wells are screened in the unsaturated zone and located between the landfill and the Site's property boundary (Table 1). The landfill gas monitoring wells are fitted with a slip cap and ball valve to allow for measurement of potential landfill gas. A calibrated gas monitoring instrument, a Landtec GEM 5000, was used to measure atmospheric barometric pressure, as well as the following landfill gas parameters: Methane (percent by volume) Oxygen (percent by volume) Carbon dioxide (percent by volume) The initial and stabilized readings for the above parameters were measured and recorded. The Solid Waste Section's Landfill Gas Monitoring Data Form was used to record measurements and other relevant information and is provided in Appendix A. 2.2. Water Quality Monitoring Wood personnel gauged static groundwater levels in the four Site monitoring wells (MW-1, MW-2, MW-3 and MW-4). Water levels were referenced to the top -of -casing at the wells. Depth to water measurements and water table elevations for the monitoring wells are presented in Table 2. The monitoring wells were purged and sampled using low -flow purging with a variable -speed submersible pump and new polyethylene tubing. The tubing intake was lowered to within five feet of the bottom of the monitoring wells. The pumping rate was minimized to prevent excessive drawdown in the well and simulate the groundwater recharge rate, which was monitored using an electronic water level indicator. Water quality parameters (temperature, pH, specific conductance, dissolved oxygen, oxidation-reduction potential, and turbidity) were measured using a water quality meter equipped with a flow -through cell (Table 3). Groundwater samples were collected from the monitoring wells after the water quality parameters stabilized. The purged water was discharged to the ground surface in proximity to each well in a manner that precluded erosion or surface runoff. Copies of the groundwater sampling logs are provided in Appendix B. The submersible pump was decontaminated by washing the pump and electrical cable in an industrial detergent and distilled water solution. The pump was then rinsed with distilled water. An equipment blank sample, EB-1, was collected from the pump discharge by operating the pump in deionized water and pumping the water into sample containers. August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 A surface water sample (SW-2) was collected at the approximate location depicted in Figure 2. The approximate location of surface water sample SW-1, as depicted in Figure 2, was observed to be dry. The water samples were placed in laboratory -supplied containers, labeled with sampling information, packed in an ice -chilled cooler, and shipped with appropriate chain -of -custody records via overnight delivery to Prism Analytical Laboratories (a North Carolina -accredited analytical laboratory). The samples were submitted for analysis of Appendix I volatile organic compounds (VOCs) according to Environmental Protection Agency (EPA) Method 8260, 1,4-dioxane via EPA Method 8260 SIM (selective ion monitoring), and Appendix I metals according to EPA Method 6020 (3030C preparation method). 4 August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 3. RESULTS AND DISCUSSION The results of the water quality and landfill gas monitoring event are reported in the NCDEQ Environmental Monitoring Report Form that is provided in Appendix C and summarized in the following sections. 3.1. Landfill Gas The Site landfill gas monitoring wells were tested for methane, carbon dioxide and oxygen. Refer to the attached Landfill Gas Monitoring Data Form for the testing results. Concentrations of methane were not detected in the landfill gas monitoring wells. The regulatory limit for methane at a MSWLF property boundary is equal to the lower explosive limit of methane (15A NCAC 1313.1627 (d)). The recorded results from the eight landfill gas wells do not exceed this limit indicating that regulatory limits are not being exceeded at the Site's property boundary. 3.2. Groundwater and Surface Water Monitoring well MW-1 is the u pg radient/backg round monitoring well. The groundwater analytical results were compared to the North Carolina Groundwater Classification and Standards (15A NCAC 2L .0202, amended effective April 1, 2013), which includes applicable interim standards updated April 6, 2018, herein referred to as the "21- Groundwater Standards", and the EPA Maximum Contaminant Levels (MCLs) established in the National Primary Drinking Water Regulations, dated May 2009. The surface water analytical results were compared to the North Carolina Surface Water Quality Standards, Criteria and Protective Values (15A NCAC 213, summary tables, dated June 10, 2019), which include EPA's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health and North Carolina Protective Values for Surface Waters, herein referred to as the "Surface Water Standards." Analytical results from the August 2019 water quality monitoring event are presented in Tables 4 and 5, and historical analytical results are presented in Tables 6 and 7. The laboratory analytical report is included in Appendix D. 3.2.1. Appendix I VOCs Appendix I VOCs were not detected above the method detection limit (MDL) in the groundwater sample collected from monitoring well MW-2. An estimated concentration (i.e., above the MDL but less than the laboratory reporting limit) of acetone was detected in the groundwater sample collected from MW-1. Five Appendix I VOCs were detected at concentrations above the MDL in the groundwater sample and duplicate (FD-1) collected from monitoring well MW-3 and four Appendix I VOCs were detected above the MDL in the groundwater sample collected from monitoring well MW-4. The detected VOC concentrations were below their respective 2L Groundwater Standards. Three Appendix I VOCs (acetone, chlorobenzene and 1,4-dichlorobenzene) were detected at concentrations above their respective MDLs in surface water sample SW-2. The detected VOC concentrations were below their respective Surface Water Standards. August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 3.2.2. 1,4-Dioxane 1,4-Dioxane was not detected above the MDL in the groundwater samples collected from monitoring wells MW-1 and MW-2. 1,4-Dioxane was detected at concentrations above its respective MDL in the groundwater samples collected from MW-3 (and duplicate FD-1) and MW-4 The groundwater 1,4-dioxane concentrations ranged from 2.5 to 3.7 micrograms per liter (pg/L). The concentrations of 1,4-dioxane detected in MW-3 (and duplicate FD-1) did not exceed the 2L Groundwater Standard. The concentration of 1,4-dioxane detected in the groundwater sample collected from MW-4 (3.7 pg/L), exceeds the 2L Groundwater Standard of 3 pg/L. An EPA MCL is not currently established for 1,4-dioxane. 1,4-Dioxane was detected in surface water sample SW-2 at a concentration of 5.0 pg/L, which is less than the applicable Surface Water Standard of 80 pg/L. 3.2.3. Appendix I Metals Five Appendix I metals were detected above the MDLs in the groundwater samples, including the field duplicate sample FD-1, which was collected from MW-3. Four of the five Appendix I metals were detected at concentrations and/or estimated concentrations below their respective 2L Groundwater Standards. Cobalt was detected at concentrations above the MDL, but below the 2L Groundwater Standard in groundwater samples collected from MW-1, MW-2, and MW-4. Cobalt was detected at concentrations of 9.2 pg/L and 9.5 pg/L in groundwater samples MW-3 and duplicate FD-1, respectively, which are greater than the 2L Groundwater Standard of 1 pg/L. An EPA MCL is not currently established for cobalt. Four Appendix I metals were detected at concentrations above the MDLs in surface water sample SW-2. Cobalt was detected at a concentration that exceeds its Surface Water Protective Value for Human Health in SW-2. Concentrations of Appendix I metals have generally been lower than historic concentrations with less exceedances above applicable Standards since low -flow purging/sampling has been implemented. Low -flow purging/sampling techniques will continue to be used for the next semi- annual water quality monitoring event. 0 August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 TABLES TABLE 1 Landfill Gas Well Construction Details Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Landfill Gas Well Installation Date Drilling Method Well Material Well Depth (bgs) Screened Interval (bgs) Ground Surface Elevation Top of Casing Elevation Latitude Longitude LG-1 LG-2 2/17/2016 2/17/2016 HSA PVC PVC 18.0 5.0 - 17.8 5.0 - 19.7 2,243.52 2,207.23 2,246.35 35.3241 -83.1822 HSA 20.0 2,209.97 35.3249 -83.1825 LG-3S 2/16/2016 HSA PVC 30.0 4.8 - 29.8 2,180.25 2,183.19 35.3261 -83.1831 LG-3D 2/16/2016 HSA PVC 66.2 36.0 - 66.0 2,180.25 2,183.14 35.3261 -83.1831 LG-4 2/18/2016 HSA PVC 7.9 4.9 - 7.7 2,125.80 2,128.58 35.3266 -83.1823 LG-5 2/18/2016 HSA PVC 30.4 5.3 - 30.1 2,166.48 2,169.12 35.3266 -83.1813 LG-6 2/18/2016 HSA PVC 10.7 5.6 - 10.4 2,208.23 2,210.92 35.3253 -83.1810 LG-7 2/17/2016 HSA PVC 35.3 5.2 - 35.0 2,266.43 2,269.08 35.3244-83.1811 Notes: 1. Depths are in feet relative to ground surface (bgs). 2. Elevations are in feet relative to mean sea level. 3. HSA - hollow -stem auger; PVC - Schedule 40 polyvinyl chloride. Prepared By: RMC 8/21/19 Checked By: SEA 9/09/19 TABLE 2 Well Construction Details and Water Level Data - August 2019 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Well Installation Date* Latitude Longitude Ground Surface Top of Casing Elevation Elevation Well Depth (feet MSL) (feet MSL) (feet BTOQ Depth to Water (feet BTOQ Groundwater Elevation (feet MSL) MW-1 1990 35.3240 -83.1811 2,302.50 2,306.01 93.28 65.85 2,240.16 MW-2 1990 35.3249 -83.1825 2,206.88 2,209.37 50.78 33.11 2,176.26 MW-3* 1990 35.3259 -83.1826 2,182.88 2,185.65 **62.92 53.92 2,131.73 MW-4 1990 35.3264 -83.1818 2,129.14 2,131.66 21.35 6.80 2,124.86 Notes: 1. Water levels were obtained on August 20, 2019. 2. * Actual date of well installation is not known, but monitoring wells were first sampled in March 1990 during closure activities (Law Engineering report dated January 16, 1991); screened interval depths are not known. 3. MSL - mean sea level; BTOC - below top of casing. 4. ** Well depth indicated in 2004 monitoring report (RETAW Corporation) indicates well depth is 71.7 feet. Prepared By: RMC 8/21/19 Checked By: SEA 9/09/19 TABLE 3 Groundwater Quality Data - August 2019 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Oxidation Reduction Dissolved Temperature Conductivity Potential Oxygen Turbidity Monitoring Well (°C) pH (mS/cm) (mv) (mg/L) (NTU) MW-1 16.88 5.07 0.024 323 8.88 5.5 MW-2 15.24 5.59 0.129 274 5.11 0.0 MW-3 17.31 5.83 0.381 -63 2.04 1.0 MW-4 18.29 5.70 0.293 559 2.92 0.5 Notes: 1. Groundwater quality data reported above collected prior to sample collection. 2. Water quality parameters were measured on August 20, 2019. 3. °C - degrees Celcius; mS/cm - milliSiemens per centimeter; my - millivolts; NTU - nephelometric turbidity units; mg/L - milligrams per liter. Prepared By: RMC 8/21/19 Checked By: SEA 9/09/19 TABLE 4 Groundwater Analytical Results - August 2019 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 2L Groundwater Standard EPA MCL MW-1 MW-2 MW-3 FD-1 (MW-3) MW-4 Appendix I VOCs and 1,4-Dioxane Acetone 6,000 NE 4.2 J <0.70 <0.70 3.3 J <0.70 Benzene 1 5 <0.34 <0.34 0.53 0.55 0.42 J Chlorobenzene 50 100 <0.34 <0.34 11 11 11 1,4-Dichlorobenzene 6 75 <0.42 <0.42 2.4 2.4 2.9 cis- 1,2-Dichloroethylene 70 70 <0.40 <0.40 2.2 2.2 1.8 1,4-Dioxane 3 NE <0.14 <0.14 2.5 3.0 3.7 Appendix I Metals Barium 700 2,000 32 89 120 120 130 Chromium (total) 10 100 <0.88 <0.88 <0.88 <0.88 1.7 J Cobalt 1 NE <0.67 <0.68 9.2 9.5 <0.68 Nickel 100 NE 1.6 J 1.7 J 3.2 3.3 1.8 J Zinc 1,000 NE I 13 J 191 15 J 11 J 16 J Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation method. 3. Concentrations are in micrograms per liter (pg/L). 4. 2L Groundwater Standard - from 15A NCAC 2L, effective April 1, 2013, including Interim Maximum Allowable Concentrations. 5. EPA MCL - Environmental Protection Agency Maximum Contaminant Level. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated MDL. 9. J - concentration is estimated. 10. Bold concentrations indicate exceedance of the 2L Groundwater Standard. Prepared by: RMC 9/09/19 Checked by: SEA 9/09/19 TABLE 5 Surface Water Analytical Results - August 2019 Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 NC Surface Water Standard (Freshwater Aquatic Life) NC Surface Water Standard (Human Health) NC Protective EPA NRWQC Values (Human (Freshwater Health) Aquatic Life) NC Protective Values (Human Health) SW-2 Appendix I VOCs and 1,4-Dioxane Acetone NE NE NE NE NE NE 2,000 1,100,000 NE NE 80 3.4 J 3.1 0.84 5.0 Chlorobenzene NE 800 140 1,4-Dichlorobenzene NE 900 100 1,4-Dioxane NE NE NE Appendix I Metals Barium NE NE 140 (acute)* NE NE 21,000 200,000 (t) 4 NE NE 190 10 1.6 J 17 J Cobalt NE NE 16 (acute) Nickel NE 4,600 NE NE NE Zinc 36 (acute)* NE Notes: 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Appendix I Metals analyzed according to EPA Method 6020B using EPA Method 3030C preparation. 3. Concentrations are in micrograms per liter (pg/L). 4. NC Surface Water Standard - From 15A NCAC 2B (tables dated June 10, 2019). 5. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. '<' - Constituent not detected above the indicated method detection limit. 9. J - concentration is estimated; B - analyte is found in the associated blank at a concentration greater than half the laboratory reporting limit. 10. Bold concentration indicates exceedance of NC Protective Value. 11. t - Based upon measurement of total recoverable metal. 12. * A hardness of 25 milligrams per liter was assumed to calculate the standard. Prepared By: RMC 9/09/19 Checked By: SEA 9/10/19 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Location Sample 1 Date C .4 Appendix I VOCs c X _O Appendix I Metals d N m c N a,0 o s v y OL y Ceq ^! y OL 0v y d a s o _O S a, ac, s d 2 t V ni L .. a, 'a 2 v �, c > O E c Q A!E ac, Q 3 CO E 7 �, a, m E _7 E u _ ` o o s = o v = o v a " Z E 7 c 0 {A = s H E > c N MW-1 8/3/11 - 0.35 JB 390 63 B 28 180 7.8 38 0.88 J 0.98 J 160 2/2/12 - 0.42 JB 62 1.7 3.5 J 0.79 JB 17 8/28/12 - 0.65 JB 0.32 J 270 0.35 J 0.59 J 8.2 JB 16 26 7.0 6.3 0.27 J 2.9 14 37 B 2/8/13 - 0.73 J 0.58 JB 530 0.84 J 0.59 J 17 B 42 64 19 17 0.34 J 0.48 J 0.64J 20 63 9/4/13 - 350 0.32 J 1.7 18 22 61 9.8 13 2.4 JB 0.15 J 26 80 2/19/14 - 0.20 J 39 0.054 J 0.16 J 0.26 J 1.1 J 0.20 J 0.47 J 0.074 J 6.0 J 9/9/14 - 3.7 0.38 J 45 0.096 J 0.16 J 1.4 2.8 J 0.53 J 0.67 JB 0.28 J 8.6 JA 6.1 JB 2/25/15 - 7.3 B /*0.27 J 0.64 J 110 0.14 J 1.1 2.1 J 0.63 J 0.91 J 0.83 J 26 6.8 J 11/6/15 - 0.082J 0.78J 40 0.14J 0.11J 4.3B 0.53J 2.0J 0.52J 1.0J 0.042J 0.17J 3.9J 3/2/16 - 0.21 J 2.6 B 37 0.59 J 6.3 B 0.16 J 1.9 J 0.39 J 3.0 0.045 J 0.12 J 13 B/*4.8 J 9/21/16 - 0.14 J 36 0.062 J 0.052 J 1.6 0.42 J 4.7 J 0.24 J 3.8 0.027 J 0.073 J 7.4 J 2/7/17 - 0.74J 37 0.14J 0.18J 0.97J 0.43J 4.5J 0.50J 0.96J 0.14J 0.26J 1.3J 5.2J 8/23/17 - 41 0.57 J 0.47 BL, J 1.8 J 0.17 J 0.39 J 0.86 J 0.15 J 24 3/15/18 - 1.0 B /*ND 48 B/*63 0.81 J 0.58 J 3.4 J 0.37 J 0.56 J 0.076 J 0.054 J 20 B /*21 8/21/18 - 110 0.12 J 0.076 J 14 5.9 13 2.6 37 0.034 J 3.1 17 3/25/19 2.9 B /*<0.19 54 0.88 J 0.68 J 1.7 J 0.62 J 2.1 0.022 J 16 8/20/19 4.2 J 32 1.6 J 13 J MW-2 8/3/11 - 0.48 J 0.22 J 130 0.20 J 2.0 1.8 1.2 J 0.59 J 2.5 0.54 J 0.076 J 0.76 J 3.8 J 9.5 J 2/2/12 - 0.93 JB 120 0.33 J 0.72 J 0.17 JB 2.3 0.064 J 0.26 J 9.3 J 8/28/12 - 0.46 JB 110 0.31 J 0.47 J 4.8 JB 0.62 J 1.5 J 0.50 J 2.5 0.040 J 3.0 2.5 J 11 B 2/8/13 - 100 0.16J 2.2 B 0.31 J 1.4J 0.15J 1.9J 0.21 J 0.14J 0.16J 16 9/4/13 - 100 0.38 J 0.66 J 2.9 J 1.8 J 21 2/19/14 - 0.22 J 0.36 J 100 0.15 J 0.17 J 0.21 J 0.13 J 1.5 J 0.18 J 0.093 J 0.050 J 7.5 J 9/9/14 - 4.2 92 0.18 J 0.26 J 0.62 J 1.2 J 0.18 J 1.5 JB 0.046 J 0.35 J 6.6 JA 9.0 JB 2/25/15 - 5.1 B /*0.22 J 62 1.6 2.7 7.0 1.2 1.7 J 12 33 11 /6/15 - 0.075 J 100 0.11 J 0.13 J 3.6 B 3.0 2.8 J 0.69 J 1.7 J 0.039 J 0.15 J 5.3 J 3/2/16 - 0.12 J 3.4 B 100 0.60 J 5.5 B 0.16 J 1.8 J 0.27 J 1.6 J 1.3 0.051 J 0.099 J 0.37 J 12 B/*4.3 J 9/21/16 2.4J - 0.12J 110 0.095J 1.1 0.28J 8.6 0.19J 2.6 0.018J 0.059J 8.6J 2/7/17 - 0.59J 89 0.24J 0.28J 0.57J 0.33J 1.2J 0.43J 1.6J 0.60J 0.14J 0.37J 1.1J 5.3J 8/23/17 - 0.38 J 100 0.081 J 0.071 J 0.53 J 0.80 BL, J 2.3 J 0.21 J 1.3 J 0.50 J 0.17 J 28 3/15/18 - 0.95 BJ/*0.70 J 110 B /*110 0.069 J 0.75 J 0.66 J 2.5 J 0.13 J 1.8 J 0.075 J 0.035 J 16 B /*16 8/21/18 - 100 0.085 J 0.082 J 0.53 J 0.083 J 4.2 J 0.32 J 1.5 J 13 3/25/19 3.9 B /*0.22 J 110 0.085 J 0.48 J 0.49 J 3.4 J 0.39 J 1.7 J 0.085 J 16 8/20/19 1 1 1 89 1 1 1 1 1 .7 J 19 J 2L GW Standard 6,000 1 50 20 6 70 100 0.030 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 1,000 EPA MCL NE 5 100 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE NE Page 1 of 2 TABLE 6 Historical Groundwater Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Monitoring Location Sample Date o v .4m Appendix I VOCs c X _O G Appendix I Metals c c N a,0 C O V y OL y C N y OL 0v y o d a s o _o S m v a, ac, s d 2 t V ni c r0 a`+ a, 'a 2 v = > O E +. c Q A!E c y Q L m CO E a m E E -0 m V _ ` o E ° s V to O V a C. O V M y J ar _� Z E c 0 ar Vl > - {A s H E to > c N MW-3 8/3/11 78 1.0 15 0.66 4.9 9.5 - 0.49 J 1.0 150 0.89 J 1.3 8.5 1.7 J 0.59 J 5.1 1.5 0.15 J 1.1 3.0 J 46 2/2/12 6.6 0.79 7.1 3.4 4.8 0.34 J - 0.72 JB 5.0 340 0.34 J 31 36 75 30 8.2 B 79 1.3 0.072 J 1.3 36 3,700 8/28/12 3.3 J 0.97 14 4.5 8.8 - 0.18 JB 0.97 J 130 0.48 J 4.7 JB 6.3 1.8 J 0.30 J 4.1 1.6 0.091 J 0.68 J 40 B 2/8/13 3.2 9.1 3.7 5.5 - 150 0.56 J 1.6 B 15 2.6 J 0.18 J 4.0 1.1 0.071 J 26 9/4/13 0.51 11 3.2 5.2 - 390 0.20 J 0.70 J 26 17 16 4.3 J 19 2.3 JB 50 95 2/19/14 0.71 12 3.7 6.4 - 0.13 J 0.37 J 150 0.073 J 0.37 J 7.3 2.1 J 0.33 J 2.5 0.77 J 0.068 J 0.054 J 1.8 J 18 9/9/14 0.61 12 4.1 4.5 - 3.4 130 0.076 J 0.24 J 9.0 1.6 J 0.19 J 3.0 B 0.16 J 9.5 JA 20 B 2/25/15 79 1.1 12 3.9 5.2 - 6.1 B /*0.41 J 1.2 340 0.28 J 2.1 14 13 20 4.8 16 0.83 J 0.074 J 0.38 J 38 120 11/6/15 250 1.1 17 0.53 4.9 5.6 - 1.2 390 0.23 J 1.1 25 B 16 25 6.3 19 1.1 0.058 J 0.33 J 54 120 3/2/16 5.4 0.59 10 2.3 4.0 - 0.095 J 3.1 B 120 0.048 J 0.43 J 5.2 B 6.2 1.4 J 0.34 J 1.5 J 4.5 0.048 J 0.035 J 12 B/*5.0 J 9/21/16 28 0.79 14 3.5 3.5 - 0.30 J 150 0.25 J 0.73 J 11 3.3 J 0.68 J 6.6 0.82 J 0.020 J 0.13 J 3.4 J 18 2/7/17 260 0.97 10 3.6 2.9 - 1.6 1.2 250 0.23 J 3.2 9.0 8.9 17 7.5 14 1.6 0.072 J 0.50 J 17 180 3/15/18 0.85 15 3.8 5.0 - 0.85BJ/*0.54 J 15o B /*150 0.46 J 13 4.1 280 13 0.51 J 67 1.2 J 0.074 J 0.38 J 0.90 J 300 B /*280 8/21/18 7.7 0.61 9.9 2.4 2.5 - 110 0.11 J 0.078 J 0.56 J 15 2.4 J 0.073 J 4.2 0.57 J 9.7 3/25/19 6.8 0.63 11 0.26 J 2.7 2.7 3.1 3.8 B /*<0.19 120 0.34 J 17 1.5 J 0.16 J 5.3 0.038 J 12 8/20/19 0.53 11 2.4 2.2 2.5 120 9.2 3.2 15 J MW-4 8/3/11 0.67 15 0.53 5.4 4.8 - 0.27 J 0.31 J 210 0.36 J 4.4 1.9 3.5 J 1.4 2.3 0.91 J 0.060 J 0.35 J 7.4 11 2/2/12 1.5 0.73 0.52 - 0.44 JB 89 0.38 J 1.0 J 0.46 JB 0.19 J 14 8/28/12 3.5 1.6 1.1 - 120 0.37 J 5.9 JB 0.82 J 2.8 J 0.65 J 1.5 J 0.59 J 0.41 J 4.1 J 28 B 2/8/13 1.7 0.83 0.65 - 85 0.13 J 3.0 B 0.47 J 1.9 J 0.33 J 0.67 J 0.33 J 0.041 J 18 9/4/13 10.0 3.9 2.8 - 190 0.26 J 8.0 J 3.1 J 7.8 1.6 J 3.0 J 1101 46 2/19/14 4.3 1.8 1.4 - 0.099 J 0.35 J 120 0.067 J 0.23 J 0.46 J 1.1 J 0.35 J 0.96 J 0.57 J 0.054 J 0.053 J 1.9 J 7.8 J 9/9/14 8.3 2.9 1.6 - 4.0 120 0.089 J 0.24 J 1.2 1.8 J 0.60 J 0.90 JB 0.11 J 12 A 5.9 JB 2/25/15 6.4 2.3 1.6 - 6.1 B /*0.21 J 90 0.19 J 0.47 J 1.1 J 0.30 J 1.5 J 8.3 J 11/6/15 4.6 1.5 0.89 - 100 0.074 J 0.19 J 9.2 B 0.16 J 0.95 J 0.28 J 2.1 0.97 J 0.041 J 0.10 J 3.2 J 3/2/16 6.6 2.6 1.5 - 0.084 J 3.7 B 120 0.60 J 4.3 B 0.099 J 1.3 J 0.20 J 0.46 J 0.85 J 0.045 J 0.032 J 9.5 B, J/*4.3 J 9/21/16 8.8 2.7 1.8 0.79 - 0.13 J 150 0.28 J 0.65 J 0.24 J 7.7 0.21 J 1.3 J 0.62 J 0.023 J 0.050 J 8.2 J 2/7/17 5.0 1.4 0.90 - 0.47 J 99 0.15 J 0.57 J 0.22 J 0.80 J 0.32 J 0.90 J 0.79 J 0.11 J 1.1 J 4.0 J 8/23/17 9.6 3.0 1.7 - 140 0.20 J 0.77 J 0.31 B, J 1.3 J 0.099 J 1.2 J 0.60 J 0.10 J 17 3/15/18 1.8 0.83 - 0.70 BJ /*0.20 J 90 B /*80 0.054 J 0.48 J 0.082 J 1.1 0.060 J 59 13 B /*13 8/21/18 2.6 0.98 - 110 0.13 J 0.094 J 1.2 0.85 J 3.0 J 1.0 1.11 2.6 21 3/25/19 4.3 1.9 0.70 3.6 3.6 B /*<0.19 110 0.14 J 0.62 J 0.47 J 1.1 J 0.22 J 0.84 J 0.020 J 14 8/20/19 0.42 J 11 2.9 1.8 3.7 130 1.7 J 1.8 J 2L GW Standard 6,000 1 50 20 6 70 100 0.030 3 1 10 700 4 2 10 1 1,000 15 100 20 20 0.2 0.3 il EPA MCL NE 5 100 600 75 70 100 2 NE 6 10 2,000 4 5 100 NE 1,300 15 NE 50 NE 2 NE Notes: Prepared By: RMC 9/10/19 1. VOCs - volatile organic compounds according to EPA Method 8260B and 1,4-dioxane analyzed via EPA Method 8260B SIM. 2. Metals according to EPA Method 6020, using EPA Method 3030C preparation. Checked By: SEA 9/10/19 2. Concentrations are in micrograms per liter (Ng/L). 3. 2L GW Standard - 2L Groundwater Standard from 15A NCAC 2L, effective April 1, 2013 (including interim maximum allowable concentrations). EPA MCL - Envirommnetal Protection Agency's Maximum Contaminant Level. 4. NE - associated standard has not been established. 5. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 6. Blank cells indicate constituent not detected in sample above the MDL. 7. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample. 8. Bold concentrations indicate exceedance of 2L GW Standard or EPA MCL. 9. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit. 10. '-' constituent not analyzed. Page 2 of 2 TABLE 7 Historical Surace Water Analytical Results Western Carolina University - Closed MSWLF Cullowhee, North Carolina Wood Project 6252-15-0221 Appendix I VOCs Appendix I Metals a c � a N s r N y O ^ � C a -0 0 0 0 -a v +�0+ N i t i C 7 1= _ 0 y o �! t _O C O E t+ 7 _3 E i L 3 -o Monitoring Sample 0 c = L. L. R O_ 10 d " C c s - _ 1= d o 0 Location Date Q m U > Q Q m CO W U u U Z in in SW-1 2/2/12 0.75 6.2 1.8 0.68 - 0.59 JB 250 6.5 1.2 J 0.20 JB 1.2 J 1.0 0.23 J 33 3/2/16 1.1 - 0.19 J 3.8 B 260 0.41 J 4.3 B 2.2 5.0 J 3.3 3.3 0.78 J 0.039 J 0.11 J 1.2 J 19 B/*21 8/21/18 6.4 - 0.44 J 240 0.16 J 0.13 J 0.49 J 4.8 7.2 3.4 5.8 0.076 J 2.4 14 2/25/19 2.2 0.66 4.1 B /*<0.20 J 190 0.16 J 2.5 4.1 J 1.5 3.2 0.084 J 29 SW-2 8/3/11 2.0 0.96 1.1 - 0.23 J 250 1.0 12 1.2 J 0.080 J 1.7 J 1.0 0.064 J 0.30 J 0.67 J 12 2/2/12 1.4 0.57 - 0.46 JB 0.22 J 170 5.5 0.25 JB 0.95 J 0.69 J 0.19 J 13 8/28/12 2.2 0.78 - 0.48 J 220 5.4 JB 9.4 0.56 J 1.7 J 1.0 0.37 J 1.1 J 14 B 2/8/13 1.6 0.55 - 0.97 JB 170 1.7 B 4.4 0.77 J 1.2 J 0.79 J 0.025 J 20 9/4/13 2.5 0.84 - 180 8.5 0.51 J 26 2/19/14 1.8 0.62 - 0.43 J 160 0.12 J 5.6 0.16 J 1.1 J 0.78 J 0.056 J 13 9/9/14 2.7 1.1 - 4.4 200 0.070 J 10 0.95 J 0.12 J 1.2 JB 0.089 J 9.6 JA 9.1 JB 2/25/15 2.1 0.90 - 6.3 B /*0.22 J 170 8.0 0.92 J 0.30 J 1.1 J 0.70 J 0.082 J 4.2 J 5.7 J 11/6/15 3.3 1.2 - 0.31 J 200 0.041 J 3.0 B 8.8 0.59 J 0.25 J 1.5 J 0.97 J 0.038 J 6.9 J 3/2/16 1.4 - 0.092 J 3.0 B 140 0.36 J 4.0 B 3.1 0.72 J 0.14 J 0.49 J 0.63 J 0.028 J 0.026 J 15 B/*8.9 J 9/21 /16 3.3 1.0 - 0.33 J 220 0.054 J 0.043 J 10 0.077 J 0.95 J 0.91 J 0.019 J 0.060 J 1.7 J 2/7/17 1.4 0.59 - 0.45 J 180 7.8 0.12 J 1.0 J 1.5 0.047 J 3.2 J 8/23/17 2.0 0.74 - 390 0.90 J 16 B 0.69 J 0.17 J 2.2 0.48 J 0.069 J 17 3/15/18 1.1 - 0.90 BJ /*0.29 J 180 B /*170 4.1 4.0 J 0.24 J 1.1 J 18 B /*14 8/21/18 8.1 2.0 0.57 - 460 0.16 J 0.10 J 0.97 17.0 2.7 J 1.4 3.0 1.1 19 2/25/19 0.80 4.1 B /*<0.19 110 2.0 1.0 J 0.14 J 1.2 J 0.022 J 19 8/20/19 3.4 J 1 3.1 0.84 1 1 5.0 190 1 1 10 1 1.6 J 17 J NCSW Standard 340 65 0.82 3.6 14 140 0.30 36 NE NE NE NE NE NE NE NE NE NE NE 5(t) NE NE (Freshwater Aquatic Life) (acute) (acute) (acute)** (acute)** (actute)** (acute)** (acute)** (acute)** NCSW Standard NE 51 NE NE NE 2.4 NE NE 10 (t) NE NE NE NE NE NE NE NE NE NE NE NE NE (Human Health) EPA NRWQC (Human NE NE 800 900 NE NE NE 640 NE NE NE NE NE NE NE NE 4,600 4,200 NE 0.47 NE NE Health) NCPV (Freshwater Aquatic 16 2,000 NE 140 100 NE NE NE NE NE 21,000 NE NE NE NE NE NE NE NE NE NE NE Life) (acute) NCPV (Human Health) 1,100,000 NE I NE I NE 1 720 1 NE 80 5,300 NE 1 200,000 (t) NE NE NE 1 4 1 NE NE NE NE NE NE NE NE Notes: Prepared By: RMC 9/10/19 1. Appendix I VOCs (volatile organic compounds) analyzed according to EPA Method 8260B and 1,4-diozane analyzed via EPA Method 8260B SIM. Metals anlyzed according to EPA Method 6020, using EPA Method 3030C preparation. Checked By: SEA 9/10/19 2. Concentrations are in micrograms per liter (pg/L). 3. NCSW Standard - North Carolina Surface Water Standards from 15A NCAC 2B (table dated June 10, 2019); a = acute 4. EPA NRWQC - Environmental Protection Agency's Nationally Recognized Water Quality Criteria for Aquatic Life and Human Health. 5. NCPV - North Carolina Protective Values from table dated June 10, 2019 22, 2017. 6. NE - associated standard has not been established. 7. Constituents detected above the method detection limit (MDL) are shown; refer to laboratory analytical report for list of constituents. 8. Blank cells indicate constituent not detected in sample above the MDL. 9. J - concentration is estimated; A - sample diluted due to internal standard recovery outside limits; B - constituent detected in method blank sample. 10. Bold concentrations indicate exceedance of a Surface Water Standard. 11. * Total antimony, total barium and/or total zinc re -analyzed and reported (second concentration indicated) due to detection of constituent in the associated blank at a concentration greater than half the laboratory reporting limit. 12. - indicates not analyzed. 13. ** A hardness of 25 milligrams per liter was assumed to calculate the standard. 14. t - based upon measurement of total recoverable metal. August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 FIGURES ��. BM u4t 10 'r, '�a ' � `" , i1 J—s r_ •I �l t,,- - -- � ' � JJff is BM LHT 1 a �e r 2043 f1 ,a _�%._,?'•'t 0 Z L 7 i1 C 2091340 • -,Jfi. I!.� _ /. �• •ptco � 1, Tr ^ "af �— .. • BM LHT`5>631 +!! A �� a V !I -. -�v :t____ f •`_ r 4f I �111111{` '.� -I �. ! ._i� _ : , I ` - rr � j-' � r / \ice^� • • a Z'o.'d� .�4� . f � � a •' �1' vr�t Sil ��'� �� ���' �_�: 11 a a ... � "��� •' ,�,�(f _ :�� ,' i�--.�� _ 1. •�'® •�L r.f' . Ty a r a�, • •�af1 s iJ���� i^� i �' a1� `I� '� i;l! fir'€rf t l �,. SYLVA SOUTH, N.C. QUADRANGLE 35083—C2—TF-024 DMA 4354 1 SW —SERIES V842 N.C. PRINTED 1946 PHOTOREMSED 1990 QUADRANGLE LOCATION NOTE: SITE BOUNDARY IS APPROXIMATE. CONTOUR INTERVAL 40 FEET GRAPHIC SCALE FEET wood 2,000 1,000 0 2,000 4,000 TOPOGRAPHIC SITE MAP DRAWN: RMC DATE: AUG. 2019 DFT CHECK: MEW SCALE: 1" = 2,000' WCU CLOSED MSWLF ENG CHECK: -- JOB: 6252-15-0221 MONTEITH GAP ROAD CULLOWHEE, NORTH CAROLINA APPROVAL: MEW FIG: 1 1 • � _ +� Y' �,'' '..i � .. .- s. .. ��, - Ate._ �'hd I -",}. 5" • .. - _ � •n'. Pw \ � �•�]i :�.fi*� •��� ��. • � _�; ��. ,r��1+.' 1,�- Y [L{t 4^ , JF r� ,L_ .'•i _ --�� t f.; -R 4r a `M4 Y 41k4� MW-4 - :� A LG- 3 �•- :' M W- 3 LG 06 Z�LG-1 --M-w-1 �ar'� ate' � �Y�� �'• �; •¢ - R IP 1 nu f �' • LEGEND GRAPHIC SCALE 180 0 180 360 r� Property Boundary 50—foot Property Boundary Buffer Landfill Extents +MW-1 Monitoring Well 00%Am— �i Unnamed Tributary/Stream A LG-1 Landfill Gas Well Location 1 INCH = 180 FT. Elevation Contour (10—foot interval) NOTE: Locations of depicted features are approximate. (approximate) LANDFILL GAS AND MONITORING WELL LOCATIONS WCU CLOSED MSWLF wood. CULLOWHEE, NORTH CAROLINA DRAWN: RMC ENG CHECK: -- DATE: AUGUST 2019 JOB: 6252-15-0221 DFT CHECK: MEW APPROVAL: MEW SCALE: APPROX. 1" = 180' FIG: 2 REFERENCE: JACKSON COUNTY GIS. August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 /_1» 4ilk 101 KV-11 LANDFILL GAS MONITORING DATA FORM NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice. Thisform and any information attached to it are "Public Records" as defined in NC GeneralStamte 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6), Facility Name: Vll1. U, - 14so%Llr Permit Number: 50.01 Sampling Date: / 2 �f n NC Landfill Rule (.0500 orr.tt6600): u 0 Spy© y� Sample Collector Name & Position:: fir 1f o dW-4 'AA. C%a r / 1 c'c%t� 'Gr., 1 r�,�g<�-��,�� y Gas Meter Type & Serial Number: c-6M COO Cs 5061410 Gas Meter Calibration Date: �6 1 Field Calibration Date & Time: /11`7 13:20 Field Calibration Gas Type (15/15 or 35/50): IS /15 Field Calibration Gas Canister Expiration Date: 12 Z.l 12Z, Gas Meter Pump Rate: Cis 5 L—/ , rn . Ambient Air Temperature: c` Barometric Pressure6.ormmHg):z-7'80 Weather Conditions: / o0e41X.21- Instructions: Under "Location or LEG Well", list monitoring well # or describe monitoring location (e.g., inside field office). Attach a test location man or drawing. Report methane readings as both % LEL and % CH4 by volume. Convert % CH4 (by volume) to %LEL as follows: % methane (by volume)/20 = %LEL. *Hydrogen Sulfide (H2S) gas monitoring may be required for Construction & Demolition Landfills (CDLFs). See individual permit conditions and/or Facility LFG monitoring plan. Location or LPG Well ID Sample Tube Purge. Time of Day Time Pumped (sec) Initial °% LEL Stabilized %LEL %CH4 (volume) %02 (volume) %CO2 (volume) %H25' (volume) NOTES GG -1 Q0 Zy yv CG 0 0 0. a 1q.1 q.3 G6-2 60 14(,6s 60 d 0 1R. 6,8 0 -35 6o 1y.25 6-0 0 0 O U 9 ,2 11.6 6 L G-- 3 n 60 1 el.-z0 Go Q 4 0,0 Z S, y S .3 0 �G-y Go -?U3s Go 0 D ao 9,6 11.1 0 GG -6 60 AE�vs60 0 0 0. 1q.3 i.6 6 G.r, 6a 15:a--:, Co 0 0p.D t,,6 3,0 6 44-7 0 13,•5S 60 6 6 .CG17 a�� a 33O EG t) -0 2(.6 1/).�� Q t OTK, i needed, attach m ltionat dataforms to include additional LFG monitoring data locations,for thefacility. ACTION LEVELS: Methane: >1.25% by volume (inside structures) AND >5% by volume (at facility boundary) Hydrogen Sulfidc: >l% by volume (inside structures) AND >4% by volume (at facility boundary) Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. I am aware that there are significant penalties for making any false statement, representation, or certification ccee/rt/iiff/ica/tion including the ossibility of a fine and imprisonment. TITLE Revised — March 6, 2017 August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 /_1»40101E41:3 GROUNDWATER SAMPLING LOGS FIELD INSTRUMENT CALIBRATION RECORD Project Name: Western Carolina University -Closed MSWLF Date: Project Number: 6252-15-0221.05 Name: teodwj�t A cilAr/J Water Quality Meter Calibration Standard Value Meter Value Acceotance Criteria Manufacturer: Ho K//-m pH: L/, 00 SU (low) pH: C/, 0C SU +/- 10% of standard Model No.: a �;7— pH:SU (med) pH: / SU +/-10% of standard Unit ID: Ep ire/o S b.,s t 6/6111 1/V pH: SU (high) pH: /TSU +/-10% of standard Conductivity: mS/cm Conductivity: /-%� ��%' mS/cm +/- 10% of standard Thermometer Temperature: / C. Temperature: C. +/-2.0 CO O2p z .?- Turbidity Meter Calibration Standard Value Meter Value Acceotance Criteria Manufacturer: Aok>/ 'A NTU (low) d, �j NTU +/-10% of standard Model No.: U S NTU (med) NTU +/-10% of standard Unit ID: 65 54.'iv li-&-6 NTU (high) NTU +/-10% of standard NTU (high) NTU +/_ 10% of standard Photoionization Detector Acceotance Criteria Manufacturer: Background: ppmv Meter: ppmv within 5 ppmv of Zero Model No.: Span Gas: ppmv Meter: ppmv +/-10% of standard Unit ID: Calibration Sources //'' Source Value Lot Number Expiration Date pH (low) CtS�Erry .�n/vkq / .G° SU ToEgSis -'-z/31/Zo pH (med) G SU pH (high) SU Conductivity MS/cm goge3S2f -7/31 /ZC7 Turbidity (low) NTU aO $ % S /31 /70 Turbidity (med): NTU Turbidity (high): NTU Turbidity (high): NTU PID gas: ppmv Other: Of"P NOTES: If a meter reading is not within acceptance criteria, clean or replace probe and re -calibrate, or use a different meter if available. If project requirements necessitate use of the instrument, clearly document on all data sheets and log book entries that the parameter was not calibrated to the acceptance criteria. FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING p f PROJECT Western Carolina University JOB NUMBER ,qJ/�6`�2522-15-0221.05 DATE 16 p caP WELL/ NUMBER �W" ACTIVITY TIME START 1 0 END TIME I1.160 (sample time) ��11 QC SAMPLES COLLECTED iQA qq ASSOCIATED TRIP BLANK Ty- 0 1• WATER LEVEL I PUMP DATA INITIAL / pp FINAL DTW C��O� ft TOC DTW SCREENED PUMP INTERVAL �/ �' ' S DEPTH VOLUME�ya,p� PURGED � i9 allons "v gg ft TOC SUBMERSIBLE PUMP PrER�.I.PTALJIC PUMP rg� C PURGE DATA TIME DTW n) PURGE RATE (Llmin) TEMP (C° H ORP (mV) SPECIFIC CONDUCTIVITY (mSICm) TURBIDITY (NTU) DO (m IL COMMENTS '0,1 7- 6•,10 Q 7 5 15. q? C, 6-6 2-3-1 a.033 1S -fD, 9-7 S au r� Zo,"7 6 .SS0• 5 25? S, 2 z9� G,02S � `f,SZ ®r � 0.71 So07Y 16,00 c�.G=?a I 0.C�-25: (5�i,z 10:35 ;. 1/V 0,ZZ 16.21 5Z6 2S6 0.0;?-q 50.1 92q 'cr,' Q,,ep o4�;-1'5".96 i;37- tog ©.ozq -qo q. -<;c a,'qs 0. 16.R_'G S,lq 30W O.O Z-q 10,5 q. a Z- to4(r o.-7> t6,92.5.12- --SZz 0.0?'I . 3 9.01 -7S36>q. Q 16 Al •Z0 3 2G O,OZ O.-�z `F.'7 j.0-7- -523 (J•dW 6•d� ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: SIGNATURE• FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University JOB NUMBER F 6252-15.0221.05 DATE % /� WELL I SAMPLE NUMBER AAfN- Z �CTIVITY TIME START .�� END TIME I O Ie, .t V (sample time) QC SAMPLES COLLECTED r^• r\ ASSOCIATED TRIP BLANK ��� ` J• WATER LEVEL / PUMP DATA INITIAL FINAL DTW .J�.1 J, ft TOC DTW SCREENED NTERVAL� SC1 • �/'' ..1A� .� lR TOC PUMP DEPTH VOLUME P^ PURGED 'V i allons SUBMERSIBLE PUMPFPOCI PERISTALTIC PUMP SS N32..9c'maA fZ • 1 PURGE DATA TIME DTW (a) PURGE RATE Llmin TEMP ORP ImV SPECIFIC CONDUCTIVITY mSlcm) TURBIDITY (NTU) DO (m IL COMMENTS 3ti,g8 o.(5 1ST s s Z'3E �•.2 :>s '41' -1 5,13 35.30 06 -15.?-F .� 22Cl (0 13?� 21,q q,4E /2.3,8 35.q_SC36 �S. 5,75 278' ®.122 )Z zl7 %'.tlo 0,16' Z5'3 0.133 0 Z ' 3 so G 1S• , e4 2-70 0, 1.3-3 1.7 14 V M.qq Xgl) oc IS-30 2.- 0.132- 502. 12.gg 0.(g . � m�sS ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I Metals via 6020 NOTES: SIGNA�9R : a. FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING O rs PROJECT I Western Carolina ��Unn�jjiv+e'rsity JOB NUMBER 6252.15-0221.05 7/ JJ DATE p/Z()�/f` WELL ISAMPLE NUMBER .�"YW"- ACTIVITYTIME START j • �� END/ ..'/Q TIME /b �!✓ pp�� (sample time) QC SAMPLES COLLECTED ��"� �. ASSOCIATED TRIP BLANK ) L? -J, WATER LEVEL / PUMP DATA INITIAL FINAL > J� DTW �� •� 2- ft TOC DTW �"t • �J� 0 TOC SCREENED PUMP INTERVAL i oTG > 6 3 • c'. o DEPTH VOLUME �/ PURGED %' allons -t1 59 ft TOC SUBMERSIBLE PUMP PERISTALTIC PUMP �{'S'' -�,50©,1 PURGE DATA TIME DTW n PURGE RATE Llmin TEMP C° H ORP mV SPECIFIC CONDUCTIVITY mSICm TURBIDITY NTU DO m IL COMMENTS .o � !IS 6-V �- s0 0,3�j 110 7. 0. % Bo �.�(� r93 D.SS� 7-9 ,01 46 /`,r,3 5gzir� 0--? 1-7.�< �•(51 F-Gcv C.S.R z,2. a. -919 1.6 1 Qaf ANALYSES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SW and Appendix I Metals via 6020 r (ZOZOI" NOTES: SIGNA UR (- �:� FIELD DATA RECORD - LOW FLOW GROUNDWATER SAMPLING PROJECT Western Carolina University / JOB NUMBER 6252-15-0221.05 D DATE WELL I SAMPLE NUMBER mw - i ACTIVITYTIME START % �� t END ! • Qo TIME (sample time) QC SAMPLES COLLECTED r J ASSOCIATED TRIP BLANK WATER LEVEL 1 PUMP DATA - . INITIAL i FINAL 1-S Q" DTW ft TOC DTW L ft TOC SCREENED PUMP INTERVAL p7n' = ZI ' DEPTH VOLUME PURGED allons ` ft TOC SUBMERSIBLE PUMP " PERISTALTIC PUMP 3 PURGE DATA ` TIME DTW a) PURGE RATE (Llmin) TEMP (C° H ORP m SPECIFIC CONDUCTIVITY mS/cm) TURBIDITY (NTU) DO (m IL COMMENTS Tl S m6 2q.�3Lf s.gct 32-3 0.30.E Lf I.o '5.G(-4 N-30 1M0 1r 1F, 71 5,� C S22- CO. E43 Zec. Z� �.� 0 l�(•7 � A 0•. � 9�.a�� r .�� 5'40 0.2zS 6% `D 3.803 5. 56J 0.7-9-9 q7 3,31 I S� 11.96 0.6 5,90 57gO 0. Z "70 ` - :�o `3 /9.96111 C 10,33 S .75 _S..S 3 0, ZJ1 11 1 ,! Z.qg- H Fr, 0,6 1 S. 29 S ` 0 03 Q-S Z ,2, ES: Appendix I VOCs via 8260, 1,4-Dioxane via 8260 SIM and Appendix I"Metals via 6020 J L 45 SIGNATUR . �,f" August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 APPENDIX C NCDEQ ENVIRONMENTAL MONITORING REPORTING FORM dffENR USE ONLY: [:]Paper Report ❑Electronic Data - Email CD data loaded: Yes I No Doc/Event #: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 139 .1629 (4)(a)(€). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Wood Environment & Infrastructure Solutions, Inc. Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Susan Avritt E-mai[; susan.avritt@woodplc.com Phone: 828-252-8130 NC Landfill Rule: Actual sampling dates (e.g.. Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Western Carolina University Monteith Gap Road (State Road 1336) 50-01 0.0500 August 20 - 21, 2019 MSW Landfill Cutlowhee, Jackson County, NC 28723 Environmental Status: (Check all that apply) Initial/Background Monitoring 0 Detection Monitoring Q Assessment Monitoring El Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Q Groundwater monitoring data from private water supply wells Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NG 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Susan Avritt, PE, LG f Senior Engineer (828) 252-8130 Representative Npme (PjrjLy Title (Area Code)Telephone Number Affix NC Lice,RWel19p44l1w&nal Geologist Seal Signature 1308 Patton Avenue, Asheville, NC 28806 Facility Representative Address F-1253 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 612009 August 2079 Water Quality and Landfill Gas Monitoring Report September 79, 2079 WCU Closed MSWLF Wood Project 6252-15-0227 /_1»4►1971:41101 LABORATORY ANALYTICAL REPORT LP R I S M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Wood Environ. & Infrastructure Inc (Asheville) Susan Avritt 1308 Patton Avenue (Suite C) Asheville, NC 28806 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: WCU MSWLF Project No.: 50-01 Lab Submittal Date: 08/21/2019 Prism Work Order: 9080321 Case Narrative 8/30/19 14:29 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Robbi A. Jones Reviewed By Robbi A. Jones President/Project Manager President/Project Manager Data Qualifiers Key Reference: J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 28 &GIE R I IS M LABORATORIES, INC. Full -Service Analytical R Environmental Solutions Sample Receipt Summary 08/30/2019 Prism Work Order: 9080321 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-1 9080321-01 Water 08/20/19 11:00 08/21/19 13:20 MW-2 9080321-02 Water 08/20/19 13:00 08/21/19 13:20 MW-3 9080321-03 Water 08/20/19 16:10 08/21/19 13:20 MW-4 9080321-04 Water 08/20/19 15:00 08/21/19 13:20 SW-2 9080321-05 Water 08/20/19 14:40 08/21/19 13:20 E13-1 9080321-06 Water 08/20/19 16:30 08/21/19 13:20 FD-1 9080321-07 Water 08/20/19 0:00 08/21/19 13:20 TB-1 9080321-08 Water 08/20/19 0:00 08/21/19 13:20 Samples were received in good condition at 2.6 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 28 /r P R I S M Full -Service Analytical s Environmental Solutions LABORATOR Summary of Detections 08/30/201S Prism Work Order: 9080321 Prism ID Client ID Parameter Method Result Units 9080321-01 MW-1 Barium 6020B 32 ug/L 9080321-01 MW-1 Nickel 6020B 1.6 J ug/L 9080321-01 MW-1 Zinc 6020B 13 J ug/L 9080321-01 MW-1 Acetone 8260D 4.2 J ug/L 9080321-02 MW-2 Barium 6020B 89 ug/L 9080321-02 MW-2 Nickel 6020B 1.7 J ug/L 9080321-02 MW-2 Zinc 6020B 19 J ug/L 9080321-03 MW-3 Barium 6020B 120 ug/L 9080321-03 MW-3 Cobalt 6020B 9.2 ug/L 9080321-03 MW-3 Nickel 6020B 3.2 ug/L 9080321-03 MW-3 Zinc 6020B 15 J ug/L 9080321-03 MW-3 1,4-Dichlorobenzene 8260D 2.4 ug/L 9080321-03 MW-3 Benzene 8260D 0.53 ug/L 9080321-03 MW-3 Chlorobenzene 8260D 11 ug/L 9080321-03 MW-3 cis-1,2-Dichloroethylene 8260D 2.2 ug/L 9080321-03 MW-3 1,4-Dioxane 8260D SIM 2.5 ug/L 9080321-04 MW-4 Barium 6020B 130 ug/L 9080321-04 MW-4 Chromium 6020B 1.7 .1 ug/L 9080321-04 MW-4 Nickel 6020B 1.8 J ug/L 9080321-04 MW-4 Zinc 6020B 16 J ug/L 9080321-04 MW-4 1,4-Dichlorobenzene 8260D 2.9 ug/L 9080321-04 MW-4 Benzene 8260D 0.42 J ug/L 9080321-04 MW-4 Chlorobenzene 8260D 11 ug/L 9080321-04 MW-4 cis-1,2-Dichloroethylene 8260D 1.8 ug/L 9080321-04 MW-4 1,4-Dioxane 8260D SIM 3.7 ug/L 9080321-05 SW-2 Barium 6020B 190 ug/L 9080321-05 SW-2 Cobalt 6020E 10 ug/L 9080321-05 SW-2 Nickel 6020B 1.6 J ug/L 9080321-05 SW-2 Zinc 6020B 17 J ug/L 9080321-05 SW-2 1,4-Dichlorobenzene 8260D 0.84 ug/L 9080321-05 SW-2 Acetone 8260D 3.4 J ug/L 9080321-05 SW-2 Chlorobenzene 8260D 3.1 ug/L 9080321-05 SW-2 1,4-Dioxane 8260D SIM 5.0 ug/L 9080321-06 EB-1 Zinc 6020B 18 J ug/L 9080321-06 EB-1 Acetone 8260D 4.1 J ug/L 9080321-07 FD-1 Barium 6020B 120 ug/L 9080321-07 FD-1 Cobalt 6020B 9.5 ug/L 9080321-07 FD-1 Nickel 6020B 3.3 ug/L 9080321-07 FD-1 Zinc 6020B 11 J ug/L 9080321-07 FD-1 1,4-Dichlorobenzene 8260D 2.4 ug/L 9080321-07 FD-1 Acetone 8260D 3.3 J ug/L 9080321-07 FD-1 Benzene 8260D 0.55 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 28 /P R I S Full -Service Analytical s Environmental Solutions � LABORATORIES, INC. Summary of Detections 08/30/201 S Prism Work Order: 9080321 Prism ID Client ID Parameter Method Result Units 9080321-07 FD-1 Chlorobenzene 8260D 11 ug/L 9080321-07 FD-1 cis-1,2-Dichloroethylene 8260D 2.2 ug/L 9080321-07 FD-1 1,4-Dioxane 8260D SIM 3.0 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 28 ,/P R I S M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-1 Prism Sample ID: 9080321-01 Prism Work Order: 9080321 Time Collected: 08/20/19 11:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.90 ug/L 6 2.9 0.90 1 6020B 8/22/19 13:20 JAB P91-10363 Arsenic <0.81 ug/L 10 2.9 0.81 1 6020B 8/22/19 13:20 JAB P91-10363 Barium 32 ug/L 100 9.7 3.1 1 6020B 8/22/19 13:20 JAB P9H0363 Beryllium <0,29 ug/L 1 0.97 0.29 1 6020B 8/22/19 13:20 JAB P91-10363 Cadmium <0.61 ug/L 1 1.9 0.61 1 6020B 8/22/19 13:20 JAB 1`91-10363 Chromium <0.88 ug/L 10 2.9 0.88 1 6020B 8/22/19 13:20 JAB P91-10363 Cobalt <0.67 ug/L 10 1.9 0.67 1 6020B 8/22/19 13:20 JAB 1`91-10363 Copper <4.5 ug/L 10 9.7 4.5 1 6020B 8/22/19 13:20 JAB P91-10363 Lead <0.43 ug/L 10 0.97 0.43 1 6020B 8/22/19 13:20 JAB 1`91-10363 Nickel 1.6 J ug/L 50 2.9 0.80 1 6020B 8/22/19 13:20 JAB P91HI0363 Selenium <0.95 ug/L 10 4.8 0.95 1 6020B 8/22/19 13:20 JAB 1`91-10363 Silver <0.33 ug/L 10 0.97 0.33 1 6020B 8/22/19 13:20 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 14:43 JAB 1`91-10382 Vanadium <1.4 ug/L 25 4.8 1.4 1 6020B 8/22/19 13:20 JAB P91-10363 Zinc 13 J ug/L 10 19 9.9 1 6020B 8/22/19 13:20 JAB P9H0363 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 14:44 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:44 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 14:44 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 14:44 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 14:44 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 14:44 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 14:44 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 14:44 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 14:44 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 14:44 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 14:44 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:44 KDM P91-10473 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 14:44 KDM P91-10473 Acetone 4.2 J ug/L 100 5.0 0.70 1 8260D 8/28/19 14:44 KDM P9H0473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 14:44 KDM P91-10473 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 8/28/19 14:44 KDM P91-10473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 14:44 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:44 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 14:44 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 14:44 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 28 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/30/2019 LABORATORIES INC. Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-1 Attn: Susan Avritt Prism Sample ID: 9080321-01 1308 Patton Avenue (Suite C) Project No.: 50-01 Prism Work Order: 9080321 Asheville, NC 28806 Sample Matrix: Water Time Collected: 08/20/19 11:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 14:44 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 14:44 KDM P91-10473 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 14:44 KDM 1`91-10473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 14:44 KDM P91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 14:44 KDM 1`91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:44 KDM P91-10473 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 8/28/19 14:44 KDM 1`91-10473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 14:44 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 14:44 KDM 1`91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 14:44 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:44 KDM 1`91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 14:44 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 14:44 KDM 1`91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 14:44 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 14:44 KDM 1`91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 14:44 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 14:44 KDM 1`91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 14:44 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 14:44 KDM 1`91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:44 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 14:44 KDM 1`91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 14:44 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 14:44 KDM 1`91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 14:44 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 14:44 KDM 1`91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 14:44 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 14:44 KDM 1`91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 14:44 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 14:44 KDM 1`91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 17:32 JLB P91-10470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-2 Prism Sample ID: 9080321-02 Prism Work Order: 9080321 Time Collected: 08/20/19 13:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.91 ug/L 6 2.9 0.91 1 6020B 8/22/19 13:40 JAB P91-10363 Arsenic <0.82 ug/L 10 2.9 0.82 1 6020B 8/22/19 13:40 JAB P91-10363 Barium 89 ug/L 100 9.8 3.1 1 6020B 8/22/19 13:40 JAB P9H0363 Beryllium <0.29 ug/L 1 0.98 0.29 1 6020B 8/22/19 13:40 JAB P91-10363 Cadmium <0.62 ug/L 1 2.0 0.62 1 6020B 8/22/19 13:40 JAB P91-10363 Chromium <0.88 ug/L 10 2.9 0.88 1 6020B 8/22/19 13:40 JAB P91-10363 Cobalt <0.68 ug/L 10 2.0 0.68 1 6020B 8/22/19 13:40 JAB P91-10363 Copper <4.6 ug/L 10 9.8 4.6 1 6020B 8/22/19 13:40 JAB P91-10363 Lead <0.43 ug/L 10 0.98 0.43 1 6020B 8/22/19 13:40 JAB P91-10363 Nickel 1.7 J ug/L 50 2.9 0.81 1 6020B 8/22/19 13:40 JAB P91HI0363 Selenium <0.95 ug/L 10 4.9 0.95 1 6020B 8/22/19 13:40 JAB P91-10363 Silver <0.33 ug/L 10 0.98 0.33 1 6020B 8/22/19 13:40 JAB P91-10363 Thallium <0.81 ug/L 5.5 1.9 0.81 1 6020B 8/23/19 14:23 JAB P91-10382 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 8/22/19 13:40 JAB P91-10363 Zinc 19 J ug/L 10 20 10 1 6020B 8/22/19 13:40 JAB P91-110363 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 15:10 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:10 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 15:10 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 15:10 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 15:10 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 15:10 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 15:10 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 15:10 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 15:10 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 15:10 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 15:10 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:10 KDM P91-10473 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 15:10 KDM P91-10473 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 8/28/19 15:10 KDM P91-10473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 15:10 KDM P91-10473 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 8/28/19 15:10 KDM P91-10473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 15:10 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:10 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 15:10 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 15:10 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 28 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/30/2019 LABORATORIES INC. Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: MW-2 Attn: Susan Avritt Prism Sample ID: 9080321-02 1308 Patton Avenue (Suite C) Project No.: 50-01 Prism Work Order: 9080321 Asheville, NC 28806 Sample Matrix: Water Time Collected: 08/20/19 13:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 15:10 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 15:10 KDM P91-10473 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 15:10 KDM 1`91-10473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 15:10 KDM P91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 15:10 KDM 1`91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:10 KDM P91-10473 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 8/28/19 15:10 KDM 1`91-10473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 15:10 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 15:10 KDM 1`91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 15:10 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:10 KDM 1`91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 15:10 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 15:10 KDM 1`91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 15:10 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 15:10 KDM 1`91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 15:10 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 15:10 KDM 1`91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 15:10 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 15:10 KDM 1`91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:10 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 15:10 KDM 1`91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 15:10 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 15:10 KDM 1`91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 15:10 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 15:10 KDM 1`91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 15:10 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 15:10 KDM 1`91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 15:10 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 15:10 KDM 1`91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 104 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 17:57 JLB P91-10470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-3 Prism Sample ID: 9080321-03 Prism Work Order: 9080321 Time Collected: 08/20/19 16:10 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.90 ug/L 6 2.9 0.90 1 6020B 8/22/19 13:46 JAB 1`91-10363 Arsenic <0.82 ug/L 10 2.9 0.82 1 6020B 8/22/19 13:46 JAB P91-10363 Barium 120 ug/L 100 9.7 3.1 1 6020B 8/22/19 13:46 JAB P9H0363 Beryllium <0.29 ug/L 1 0.97 0.29 1 6020B 8/22/19 13:46 JAB P91-10363 Cadmium <0.62 ug/L 1 1.9 0.62 1 6020B 8/22/19 13:46 JAB P91-10363 Chromium <0.88 ug/L 10 2.9 0.88 1 6020B 8/22/19 13:46 JAB P91-10363 Cobalt 9.2 ug/L 10 1.9 0.68 1 6020B 8/22/19 13:46 JAB 11391-110363 Copper <4.6 ug/L 10 9.7 4.6 1 6020B 8/22/19 13:46 JAB P91-10363 Lead <0.43 ug/L 10 0.97 0.43 1 6020B 8/22/19 13:46 JAB P91-10363 Nickel 3.2 ug/L 50 2.9 0.80 1 6020B 8/22/19 13:46 JAB P91-110363 Selenium <0.95 ug/L 10 4.9 0.95 1 6020B 8/22/19 13:46 JAB P91-10363 Silver <0.33 ug/L 10 0.97 0.33 1 6020B 8/22/19 13:46 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 14:50 JAB P91-10382 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 8/22/19 13:46 JAB P91-10363 Zinc 15 J ug/L 10 19 9.9 1 6020B 8/22/19 13:46 JAB P91-110363 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 15:36 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:36 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 15:36 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 15:36 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 15:36 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 15:36 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 15:36 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 15:36 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 15:36 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 15:36 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 15:36 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:36 KDM P91-10473 1,4-Dichlorobenzene 2.4 ug/L 1 0.50 0.42 1 8260D 8/28/19 15:36 KDM P91HI0473 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 8/28/19 15:36 KDM P91-10473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 15:36 KDM P91-10473 Benzene 0.53 ug/L 1 0.50 0.34 1 8260D 8/28/19 15:36 KDM 1391-110473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 15:36 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:36 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 15:36 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 15:36 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-3 Prism Sample ID: 9080321-03 Prism Work Order: 9080321 Time Collected: 08/20/19 16:10 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 15:36 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 15:36 KDM P91-10473 Chlorobenzene 11 ug/L 3 0.50 0.34 1 8260D 8/28/19 15:36 KDM P91-110473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 15:36 KDM 1`91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 15:36 KDM P91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 15:36 KDM 1`91-10473 cis-1,2-Dichloroethylene 2.2 ug/L 5 0.50 0.40 1 8260D 8/28/19 15:36 KDM 1391-110473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 15:36 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 15:36 KDM P91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 15:36 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:36 KDM P91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 15:36 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 15:36 KDM P91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 15:36 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 15:36 KDM P91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 15:36 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 15:36 KDM P91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 15:36 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 15:36 KDM P91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 15:36 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 15:36 KDM P91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 15:36 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 15:36 KDM P91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 15:36 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 15:36 KDM P91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 15:36 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 15:36 KDM P91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 15:36 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 15:36 KDM P91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 2.5 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 19:13 JLB P9H0470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-4 Prism Sample ID: 9080321-04 Prism Work Order: 9080321 Time Collected: 08/20/19 15:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.91 ug/L 6 2.9 0.91 1 6020B 8/22/19 13:53 JAB 1`91-10363 Arsenic <0.82 ug/L 10 2.9 0.82 1 6020B 8/22/19 13:53 JAB P91-10363 Barium 130 ug/L 100 9.8 3.1 1 6020B 8/22/19 13:53 JAB P9H0363 Beryllium <0.29 ug/L 1 0.98 0.29 1 6020B 8/22/19 13:53 JAB P91-10363 Cadmium <0.62 ug/L 1 2.0 0.62 1 6020B 8/22/19 13:53 JAB P91-10363 Chromium 1.7 J ug/L 10 2.9 0.89 1 6020B 8/22/19 13:53 JAB P9H0363 Cobalt <0.68 ug/L 10 2.0 0.68 1 6020B 8/22/19 13:53 JAB P91-10363 Copper <4.6 ug/L 10 9.8 4.6 1 6020B 8/22/19 13:53 JAB P91-10363 Lead <0.43 ug/L 10 0.98 0.43 1 6020B 8/22/19 13:53 JAB P91-10363 Nickel 1.8 J ug/L 50 2.9 0.81 1 6020B 8/22/19 13:53 JAB P9H0363 Selenium <0.96 ug/L 10 4.9 0.96 1 6020B 8/22/19 13:53 JAB P91-10363 Silver <0.33 ug/L 10 0.98 0.33 1 6020B 8/22/19 13:53 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 14:57 JAB P91-10382 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 8/22/19 13:53 JAB P91-10363 Zinc 16 J ug/L 10 20 10 1 6020B 8/22/19 13:53 JAB P91-110363 Volatile Organic Compounds by GUMS 1,1,1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:02 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:02 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:02 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:02 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 16:02 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:02 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 16:02 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 16:02 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 16:02 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 16:02 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:02 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:02 KDM P91-10473 1,4-Dichlorobenzene 2.9 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:02 KDM P9H0473 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 8/28/19 16:02 KDM P91-10473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 16:02 KDM P91-10473 Benzene 0.42 J ug/L 1 0.50 0.34 1 8260D 8/28/19 16:02 KDM P9H0473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 16:02 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:02 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 16:02 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 16:02 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: MW-4 Prism Sample ID: 9080321-04 Prism Work Order: 9080321 Time Collected: 08/20/19 15:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 16:02 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 16:02 KDM P91-10473 Chlorobenzene 11 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:02 KDM P91-110473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 16:02 KDM 1`91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 16:02 KDM P91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:02 KDM 1`91-10473 cis-1,2-Dichloroethylene 1.8 ug/L 5 0.50 0.40 1 8260D 8/28/19 16:02 KDM 1391-110473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 16:02 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 16:02 KDM P91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 16:02 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:02 KDM P91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 16:02 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 16:02 KDM P91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 16:02 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 16:02 KDM P91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 16:02 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 16:02 KDM P91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 16:02 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 16:02 KDM P91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:02 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 16:02 KDM P91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 16:02 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 16:02 KDM P91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 16:02 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 16:02 KDM P91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 16:02 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 16:02 KDM P91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:02 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 16:02 KDM P91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 103 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 3.7 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 20:03 JLB P9H0470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: SW-2 Prism Sample ID: 9080321-05 Prism Work Order: 9080321 Time Collected: 08/20/19 14:40 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.91 ug/L 6 2.9 0.91 1 6020B 8/22/19 14:06 JAB 1`91-10363 Arsenic <0.82 ug/L 10 2.9 0.82 1 6020B 8/22/19 14:06 JAB P91-10363 Barium 190 ug/L 100 9.8 3.1 1 6020B 8/22/19 14:06 JAB P9H0363 Beryllium <0.29 ug/L 1 0.98 0.29 1 6020B 8/22/19 14:06 JAB P91-10363 Cadmium <0.62 ug/L 1 2.0 0.62 1 6020B 8/22/19 14:06 JAB P91-10363 Chromium <0.88 ug/L 10 2.9 0.88 1 6020B 8/22/19 14:06 JAB P91-10363 Cobalt 10 ug/L 10 2.0 0.68 1 6020B 8/22/19 14:06 JAB 11391-110363 Copper <4.6 ug/L 10 9.8 4.6 1 6020B 8/22/19 14:06 JAB P91-10363 Lead <0.43 ug/L 10 0.98 0.43 1 6020B 8/22/19 14:06 JAB P91-10363 Nickel 1.6 J ug/L 50 2.9 0.81 1 6020B 8/22/19 14:06 JAB P91-110363 Selenium <0.95 ug/L 10 4.9 0.95 1 6020B 8/22/19 14:06 JAB P91-10363 Silver <0.33 ug/L 10 0.98 0.33 1 6020B 8/22/19 14:06 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 15:03 JAB P91-10382 Vanadium <1.4 ug/L 25 4.9 1.4 1 6020B 8/22/19 14:06 JAB P91-10363 Zinc 17 J ug/L 10 20 10 1 6020B 8/22/19 14:06 JAB P9H0363 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:28 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:28 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:28 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:28 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 16:28 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:28 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 16:28 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 16:28 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 16:28 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 16:28 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:28 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:28 KDM P91-10473 1,4-Dichlorobenzene 0.84 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:28 KDM P91-110473 Acetone 3.4 J ug/L 100 5.0 0.70 1 8260D 8/28/19 16:28 KDM P91-110473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 16:28 KDM P91-10473 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 8/28/19 16:28 KDM P91-10473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 16:28 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:28 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 16:28 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 16:28 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: SW-2 Prism Sample ID: 9080321-05 Prism Work Order: 9080321 Time Collected: 08/20/19 14:40 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 16:28 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 16:28 KDM P91-10473 Chlorobenzene 3.1 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:28 KDM P91-110473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 16:28 KDM 1`91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 16:28 KDM P91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:28 KDM 1`91-10473 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 8/28/19 16:28 KDM P91-10473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 16:28 KDM 1`91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 16:28 KDM P91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 16:28 KDM 1`91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:28 KDM P91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 16:28 KDM 1`91-10473 Methyl Butyl Ketone (2-Hexanone) <0,29 ug/L 50 5.0 0.29 1 8260D 8/28/19 16:28 KDM P91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 16:28 KDM 1`91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 16:28 KDM P91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 16:28 KDM 1`91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 16:28 KDM P91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 16:28 KDM 1`91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 16:28 KDM P91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:28 KDM 1`91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 16:28 KDM P91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 16:28 KDM 1`91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 16:28 KDM P91-10473 trans- 1,4-Dichloro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 16:28 KDM 1`91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 16:28 KDM P91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 16:28 KDM 1`91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 16:28 KDM P91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:28 KDM 1`91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 16:28 KDM P91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 5.0 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 18:23 JLB 11391-110470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: EB-1 Prism Sample ID: 9080321-06 Prism Work Order: 9080321 Time Collected: 08/20/19 16:30 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.90 ug/L 6 2.9 0.90 1 6020B 8/22/19 14:13 JAB 1`91-10363 Arsenic <0.81 ug/L 10 2.9 0.81 1 6020B 8/22/19 14:13 JAB P91-10363 Barium <3.0 ug/L 100 9.7 3.0 1 6020B 8/22/19 14:13 JAB 1`91-10363 Beryllium <0.29 ug/L 1 0.97 0.29 1 6020B 8/22/19 14:13 JAB P91-10363 Cadmium <0.61 ug/L 1 1.9 0.61 1 6020B 8/22/19 14:13 JAB 1`91-10363 Chromium <0.87 ug/L 10 2.9 0.87 1 6020B 8/22/19 14:13 JAB P91-10363 Cobalt <0.67 ug/L 10 1.9 0.67 1 6020B 8/22/19 14:13 JAB 1`91-10363 Copper <4.5 ug/L 10 9.7 4.5 1 6020B 8/22/19 14:13 JAB P91-10363 Lead <0.43 ug/L 10 0.97 0.43 1 6020B 8/22/19 14:13 JAB 1`91-10363 Nickel <0.80 ug/L 50 2.9 0.80 1 6020B 8/22/19 14:13 JAB P91-10363 Selenium <0.94 ug/L 10 4.8 0.94 1 6020B 8/22/19 14:13 JAB 1`91-10363 Silver <0.33 ug/L 10 0.97 0.33 1 6020B 8/22/19 14:13 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 15:10 JAB 1`91-10382 Vanadium <1.4 ug/L 25 4.8 1.4 1 6020B 8/22/19 14:13 JAB P91-10363 Zinc 18 J ug/L 10 19 9.8 1 6020B 8/22/19 14:13 JAB P9H0363 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 14:18 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:18 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 14:18 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 14:18 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 14:18 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 14:18 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 14:18 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 14:18 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 14:18 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 14:18 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 14:18 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:18 KDM P91-10473 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 14:18 KDM P91-10473 Acetone 4.1 J ug/L 100 5.0 0.70 1 8260D 8/28/19 14:18 KDM P9H0473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 14:18 KDM P91-10473 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 8/28/19 14:18 KDM P91-10473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 14:18 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:18 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 14:18 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 14:18 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 28 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/30/2019 LABORATORIES INC. Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: EB-1 Attn: Susan Avritt Prism Sample ID: 9080321-06 1308 Patton Avenue (Suite C) Project No.: 50-01 Prism Work Order: 9080321 Asheville, NC 28806 Sample Matrix: Water Time Collected: 08/20/19 16:30 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 14:18 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 14:18 KDM P91-10473 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 14:18 KDM 1`91-10473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 14:18 KDM P91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 14:18 KDM 1`91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 14:18 KDM P91-10473 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 8/28/19 14:18 KDM 1`91-10473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 14:18 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 14:18 KDM 1`91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 14:18 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:18 KDM 1`91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 14:18 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 14:18 KDM 1`91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 14:18 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 14:18 KDM 1`91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 14:18 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 14:18 KDM 1`91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 14:18 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 14:18 KDM 1`91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 14:18 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 14:18 KDM 1`91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 14:18 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 14:18 KDM 1`91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 14:18 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 14:18 KDM 1`91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 14:18 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 14:18 KDM 1`91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 14:18 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 14:18 KDM 1`91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 94 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 18:48 JLB P91-10470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: FD-1 Prism Sample ID: 9080321-07 Prism Work Order: 9080321 Time Collected: 08/20/19 00:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 3030C Metals Antimony <0.90 ug/L 6 2.9 0.90 1 6020B 8/22/19 14:00 JAB 1`91-10363 Arsenic <0.81 ug/L 10 2.9 0.81 1 6020B 8/22/19 14:00 JAB P91-10363 Barium 120 ug/L 100 9.7 3.1 1 6020B 8/22/19 14:00 JAB P9H0363 Beryllium <0.29 ug/L 1 0.97 0.29 1 6020B 8/22/19 14:00 JAB P91-10363 Cadmium <0.61 ug/L 1 1.9 0.61 1 6020B 8/22/19 14:00 JAB P91-10363 Chromium <0.88 ug/L 10 2.9 0.88 1 6020B 8/22/19 14:00 JAB P91-10363 Cobalt 9.5 ug/L 10 1.9 0.67 1 6020B 8/22/19 14:00 JAB 11391-110363 Copper <4.5 ug/L 10 9.7 4.5 1 6020B 8/22/19 14:00 JAB P91-10363 Lead <0.43 ug/L 10 0.97 0.43 1 6020B 8/22/19 14:00 JAB P91-10363 Nickel 3.3 ug/L 50 2.9 0.80 1 6020B 8/22/19 14:00 JAB P91-110363 Selenium <0.95 ug/L 10 4.8 0.95 1 6020B 8/22/19 14:00 JAB P91-10363 Silver <0.33 ug/L 10 0.97 0.33 1 6020B 8/22/19 14:00 JAB P91-10363 Thallium <0.82 ug/L 5.5 2.0 0.82 1 6020B 8/23/19 15:17 JAB P91-10382 Vanadium <1.4 ug/L 25 4.8 1.4 1 6020B 8/22/19 14:00 JAB P91-10363 Zinc 11 J ug/L 10 19 9.9 1 6020B 8/22/19 14:00 JAB P91-110363 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:55 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:55 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:55 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:55 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 16:55 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 16:55 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 16:55 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 16:55 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 16:55 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 16:55 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:55 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:55 KDM P91-10473 1,4-Dichlorobenzene 2.4 ug/L 1 0.50 0.42 1 8260D 8/28/19 16:55 KDM P91HI0473 Acetone 3.3 J ug/L 100 5.0 0.70 1 8260D 8/28/19 16:55 KDM 1391-110473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 16:55 KDM P91-10473 Benzene 0.55 ug/L 1 0.50 0.34 1 8260D 8/28/19 16:55 KDM 1391-110473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 16:55 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:55 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 16:55 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 16:55 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 28 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: FD-1 Prism Sample ID: 9080321-07 Prism Work Order: 9080321 Time Collected: 08/20/19 00:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 16:55 KDM 1`91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 16:55 KDM P91-10473 Chlorobenzene 11 ug/L 3 0.50 0.34 1 8260D 8/28/19 16:55 KDM P91-110473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 16:55 KDM 1`91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 16:55 KDM P91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 16:55 KDM 1`91-10473 cis-1,2-Dichloroethylene 2.2 ug/L 5 0.50 0.40 1 8260D 8/28/19 16:55 KDM 1391-110473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 16:55 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 16:55 KDM P91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 16:55 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:55 KDM P91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 16:55 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 16:55 KDM P91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 16:55 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 16:55 KDM P91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 16:55 KDM P91-10473 Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 16:55 KDM P91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 16:55 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 16:55 KDM P91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 16:55 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 16:55 KDM P91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 16:55 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 16:55 KDM P91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 16:55 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 16:55 KDM P91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 16:55 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 16:55 KDM P91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 16:55 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 16:55 KDM P91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 92 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 3.0 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 19:38 JLB P9H0470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 28 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 08/30/2019 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No.: 50-01 Asheville, NC 28806 Sample Matrix: Water Client Sample ID: TB-1 Prism Sample ID: 9080321-08 Prism Work Order: 9080321 Time Collected: 08/20/19 00:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 13:52 KDM P91-10473 1, 1, 1 -Trichloroethane <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 13:52 KDM P91-10473 1,1,2,2-Tetrachloroethane <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 13:52 KDM P91-10473 1,1,2-Trichloroethane <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 13:52 KDM P91-10473 1,1-Dichloroethane <0.29 ug/L 5 0.50 0.29 1 8260D 8/28/19 13:52 KDM P91-10473 1,1-Dichloroethylene <0.35 ug/L 5 0.50 0.35 1 8260D 8/28/19 13:52 KDM P91-10473 1,2,3-Trichloropropane <0.34 ug/L 1 1.0 0.34 1 8260D 8/28/19 13:52 KDM P91-10473 1,2-Dibromo-3-chloropropane <0.59 ug/L 13 2.0 0.59 1 8260D 8/28/19 13:52 KDM P91-10473 1,2-Dibromoethane <0.37 ug/L 1 0.50 0.37 1 8260D 8/28/19 13:52 KDM P91-10473 1,2-Dichlorobenzene <0.28 ug/L 5 0.50 0.28 1 8260D 8/28/19 13:52 KDM P91-10473 1,2-Dichloroethane <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 13:52 KDM P91-10473 1,2-Dichloropropane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 13:52 KDM P91-10473 1,4-Dichlorobenzene <0.42 ug/L 1 0.50 0.42 1 8260D 8/28/19 13:52 KDM P91-10473 Acetone <0.70 ug/L 100 5.0 0.70 1 8260D 8/28/19 13:52 KDM P91-10473 Acrylonitrile <0.85 ug/L 200 20 0.85 1 8260D 8/28/19 13:52 KDM P91-10473 Benzene <0.34 ug/L 1 0.50 0.34 1 8260D 8/28/19 13:52 KDM P91-10473 Bromochloromethane <0.53 ug/L 3 2.0 0.53 1 8260D 8/28/19 13:52 KDM P91-10473 Bromodichloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 13:52 KDM P91-10473 Bromoform <0.26 ug/L 3 1.0 0.26 1 8260D 8/28/19 13:52 KDM P91-10473 Bromomethane <0.48 ug/L 10 1.0 0.48 1 8260D 8/28/19 13:52 KDM P91-10473 Carbon disulfide <0.36 ug/L 100 5.0 0.36 1 8260D 8/28/19 13:52 KDM P91-10473 Carbon Tetrachloride <0.55 ug/L 1 2.0 0.55 1 8260D 8/28/19 13:52 KDM P91-10473 Chlorobenzene <0.34 ug/L 3 0.50 0.34 1 8260D 8/28/19 13:52 KDM P91-10473 Chloroethane <0.43 ug/L 10 0.50 0.43 1 8260D 8/28/19 13:52 KDM P91-10473 Chloroform <0.48 ug/L 5 0.50 0.48 1 8260D 8/28/19 13:52 KDM P91-10473 Chloromethane <0.29 ug/L 1 0.50 0.29 1 8260D 8/28/19 13:52 KDM P91-10473 cis- 1,2-Dichloroethylene <0.40 ug/L 5 0.50 0.40 1 8260D 8/28/19 13:52 KDM P91-10473 cis- 1,3-Dichloropropylene <0.36 ug/L 1 0.50 0.36 1 8260D 8/28/19 13:52 KDM P91-10473 Dibromochloromethane <0.42 ug/L 3 0.50 0.42 1 8260D 8/28/19 13:52 KDM P91-10473 Dibromomethane <0.54 ug/L 10 2.0 0.54 1 8260D 8/28/19 13:52 KDM P91-10473 Ethylbenzene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 13:52 KDM P91-10473 m,p-Xylenes <0.73 ug/L NE 1.0 0.73 1 8260D 8/28/19 13:52 KDM P91-10473 Methyl Butyl Ketone (2-Hexanone) <0.29 ug/L 50 5.0 0.29 1 8260D 8/28/19 13:52 KDM P91-10473 Methyl Ethyl Ketone (2-Butanone) <0.78 ug/L 100 5.0 0.78 1 8260D 8/28/19 13:52 KDM P91-10473 Methyl Iodide <0.41 ug/L 10 5.0 0.41 1 8260D 8/28/19 13:52 KDM P91-10473 Methyl Isobutyl Ketone <0.40 ug/L 100 5.0 0.40 1 8260D 8/28/19 13:52 KDM P91-10473 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 28 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 08/30/2019 LABORATORIES INC. Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Client Sample ID: TB-1 Attn: Susan Avritt Prism Sample ID: 9080321-08 1308 Patton Avenue (Suite C) Project No.: 50-01 Prism Work Order: 9080321 Asheville, NC 28806 Sample Matrix: Water Time Collected: 08/20/19 00:00 Time Submitted: 08/21/19 13:20 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.40 ug/L 1 1.0 0.40 1 8260D 8/28/19 13:52 KDM 1`91-10473 o-Xylene <0.40 ug/L NE 0.50 0.40 1 8260D 8/28/19 13:52 KDM P91-10473 Styrene <0.26 ug/L 1 0.50 0.26 1 8260D 8/28/19 13:52 KDM 1`91-10473 Tetrachloroethylene <0.31 ug/L 1 0.50 0.31 1 8260D 8/28/19 13:52 KDM P91-10473 Toluene <0.35 ug/L 1 0.50 0.35 1 8260D 8/28/19 13:52 KDM 1`91-10473 trans- 1,2-Dichloroethylene <0.27 ug/L 5 0.50 0.27 1 8260D 8/28/19 13:52 KDM P91-10473 trans- 1,3-Dichloropropylene <0.49 ug/L 1 0.50 0.49 1 8260D 8/28/19 13:52 KDM 1`91-10473 trans- 1,4-Dich loro-2-butene <0.22 ug/L 100 10 0.22 1 8260D 8/28/19 13:52 KDM P91-10473 Trichloroethylene <0.46 ug/L 1 0.50 0.46 1 8260D 8/28/19 13:52 KDM 1`91-10473 Trichlorofluoromethane <0.24 ug/L 1 0.50 0.24 1 8260D 8/28/19 13:52 KDM P91-10473 Vinyl acetate <0.26 ug/L 50 2.0 0.26 1 8260D 8/28/19 13:52 KDM 1`91-10473 Vinyl chloride <0.41 ug/L 1 0.50 0.41 1 8260D 8/28/19 13:52 KDM P91-10473 Xylenes, total <1.1 ug/L 5 1.5 1.1 1 8260D 8/28/19 13:52 KDM 1`91-10473 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 94 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 2.0 0.14 1 8260D SIM 8/28/19 17:07 JLB P91-10470 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 28 ,ot P R I IS M EService Analytical Environmental Solutions LABORATORIES, INC. Level II QC Report 8/30/19 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9HO473 - 5030B Blank (P9H0473-BLK1) Prepared &Analyzed: 08/28/19 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 2.0 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 2.0 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 2.0 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Toluene BRL 0.50 ug/L trans-1,2-Dichloroethylene BRL 0.50 ug/L trans-1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L Trichlorofluoromethane BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 28 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 8/30/19 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9HO473 - 5030B Blank (P9H0473-BLK1) Prepared &Analyzed: 08/28/19 Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 50.3 ug/L 50.00 101 80-124 Surrogate: Dibromofluoromethane 50.3 ug/L 50.00 101 75-129 Surrogate: Toluene-d8 48.3 ug/L 50.00 97 77-123 LCS (P9H0473-BS1) Prepared &Analyzed: 08/28/19 1,1-Dichloroethylene 21.2 0.50 ug/L 20.00 106 70-154 Benzene 22.7 0.50 ug/L 20.00 114 77-128 Chlorobenzene 21.8 0.50 ug/L 20.00 109 78-119 Toluene 21.7 0.50 ug/L 20.00 109 76-131 Trichloroethylene 22.9 0.50 ug/L 20.00 114 77-133 Surrogate:4-Bromofluorobenzene 49.5 ug/L 50.00 99 80-124 Surrogate: Dibromofluoromethane 49.7 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 48.4 ug/L 50.00 97 77-123 LCS Dup (P9HO473-BSD1) Prepared & Analyzed: 08/28/19 1,1-Dichloroethylene 20.9 0.50 ug/L 20.00 105 70-154 1 20 Benzene 22.2 0.50 ug/L 20.00 ill 77-128 2 20 Chlorobenzene 21.3 0.50 ug/L 20.00 106 78-119 3 20 Toluene 21.4 0.50 ug/L 20.00 107 76-131 1 20 Trichloroethylene 22.6 0.50 ug/L 20.00 113 77-133 1 20 Surrogate:4-Bromofluorobenzene 50.1 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 49.7 ug/L 50.00 99 75-129 Surrogate: Toluene-d8 47.7 ug/L 50.00 95 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 28 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 8/30/19 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Analyte Result Limit Units Batch P9HO470 - 5030B Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:OOPM Spike Source %REC RPD Level Result %REC Limits RPD Limit Notes Blank (P9H0470-BLK1) Prepared &Analyzed: 08/28/19 1,4-Dioxane BRL 2.0 ug/L LCS (P9H0470-BS1) Prepared &Analyzed: 08/28/19 1,4-Dioxane 43.8 2.0 ug/L 50.00 88 55-145 LCS Dup (P9H0470-BSD1) Prepared & Analyzed: 08/28/19 1,4-Dioxane 44.1 2.0 ug/L 50.00 88 55-145 0.8 30 Matrix Spike (P9H0470-MS1) Source: 9080321-01 Prepared & Analyzed: 08/28/19 1,4-Dioxane 51.8 2.0 ug/L 50.00 BRL 104 55-145 Matrix Spike Dup (P9H0470-MSD1) Source: 9080321-01 Prepared & Analyzed: 08/28/19 1,4-Dioxane 58.2 2.0 ug/L 50.00 BRL 116 55-145 12 30 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 28 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Level II QC Report 8/30/19 Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9H0363 - SM3030 C Blank (P9H0363-BLK1) Prepared & Analyzed: 08/22/19 Antimony BRL 2.9 ug/L Arsenic BRL 2.9 ug/L Barium BRL 9.6 ug/L Beryllium BRL 0.96 ug/L Cadmium BRL 1.9 ug/L Chromium BRL 2.9 ug/L Cobalt BRL 1.9 ug/L Copper BRL 9.6 ug/L Lead BRL 0.96 ug/L Nickel BRL 2.9 ug/L Selenium BRL 4.8 ug/L Silver BRL 0.96 ug/L Vanadium BRL 4.8 ug/L Zinc BRL 19 ug/L LCS (11291-10363-BS1) Prepared &Analyzed: 08/22/19 Antimony 88.7 3.0 ug/L 100.0 89 80-120 Arsenic 95.4 3.0 ug/L 100.0 95 80-120 Barium 93.2 9.8 ug/L 100.0 93 80-120 Beryllium 96.4 0.98 ug/L 100.0 96 80-120 Cadmium 95.8 2.0 ug/L 100.0 96 80-120 Chromium 95.9 3.0 ug/L 100.0 96 80-120 Cobalt 99.4 2.0 ug/L 100.0 99 80-120 Copper 102 9.8 ug/L 100.0 102 80-120 Lead 98.5 0.98 ug/L 100.0 98 80-120 Nickel 100 3.0 ug/L 100.0 100 80-120 Selenium 98.1 4.9 ug/L 100.0 98 80-120 Silver 103 0.98 ug/L 100.0 103 80-120 Vanadium 97.9 4.9 ug/L 100.0 98 80-120 Zinc 103 20 ug/L 100.0 103 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 28 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 8/30/19 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:OOPM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9H0363 - SM3030 C Matrix Spike (P9H0363-MS1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc Matrix Spike Dup (P9H0363-MSD1) Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc Source: 9080321-01 Prepared & Analyzed: 08/22/19 89.7 3.0 ug/L 100.0 BRL 90 75-125 96.4 3.0 ug/L 100.0 BRL 96 75-125 131 10 ug/L 100.0 32.2 98 75-125 95.7 1.0 ug/L 100.0 BRL 96 75-125 95.7 2.0 ug/L 100.0 BRL 96 75-125 102 3.0 ug/L 100.0 BRL 102 75-125 101 2.0 ug/L 100.0 BRL 101 75-125 106 10 ug/L 100.0 BRL 106 75-125 101 1.0 ug/L 100.0 BRL 101 75-125 105 3.0 ug/L 100.0 1.57 103 75-125 96.9 5.0 ug/L 100.0 BRL 97 75-125 99.8 1.0 ug/L 100.0 BRL 100 75-125 102 5.0 ug/L 100.0 BRL 102 75-125 116 20 ug/L 100.0 13.0 103 75-125 Source: 9080321-01 Prepared & Analyzed: 08/22/19 86.6 3.0 ug/L 100.0 BRL 87 75-125 4 20 95.1 3.0 ug/L 100.0 BRL 95 75-125 1 20 127 10 ug/L 100.0 32.2 95 75-125 3 20 96.4 1.0 ug/L 100.0 BRL 96 75-125 0.8 20 94.3 2.0 ug/L 100.0 BRL 94 75-125 1 20 102 3.0 ug/L 100.0 BRL 102 75-125 0.5 20 101 2.0 ug/L 100.0 BRL 101 75-125 0.3 20 105 10 ug/L 100.0 BRL 105 75-125 1 20 97.6 1.0 ug/L 100.0 BRL 98 75-125 4 20 105 3.0 ug/L 100.0 1.57 103 75-125 0.1 20 94.8 5.0 ug/L 100.0 BRL 95 75-125 2 20 98.8 1.0 ug/L 100.0 BRL 99 75-125 1 20 102 5.0 ug/L 100.0 BRL 102 75-125 0.8 20 115 20 ug/L 100.0 13.0 102 75-125 0.6 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 28 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 8/30/19 Wood Environ. & Infrastructure Inc (Asheville Project: WCU MSWLF Attn: Susan Avritt 1308 Patton Avenue (Suite C) Project No: 50-01 Asheville, NC 28806 3030C Metals - Quality Control Prism Work Order: 9080321 Time Submitted: 8/21/2019 1:20:00PM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9H0382 - SM3030 C Blank (P9H0382-BLK1) Prepared: 08/22/19 Analyzed: 08/23/19 Thallium BRL 1.9 ug/L LCS (P9H0382-BS1) Prepared: 08/22/19 Analyzed: 08/23/19 Thallium 99.2 2.0 ug/L 100.0 99 80-120 Matrix Spike (P9H0382-MS1) Source: 9080321-02 Prepared: 08/22/19 Analyzed: 08/23/19 Thallium 101 2.0 ug/L 100.0 BRL 101 75-125 Matrix Spike Dup (P9H0382-MSD1) Source: 9080321-02 Prepared: 08/22/19 Analyzed: 08/23/19 Thallium 101 2.0 ug/L 100.0 BRL 101 75-125 0.03 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 28 Sample Extraction Data Prep Method: SM3030 C Lab Number Batch Initial Final Date/Time 9080321-01 P91-10382 50 mL 48.9 mL 08/22/19 14:43 9080321-01 P91-10363 50 mL 48.37 mL 08/22/19 8:30 9080321-02 P91-10382 50 mL 48.56 mL 08/22/19 14:43 9080321-02 P91-10363 50 mL 48.82 mL 08/22/19 8:30 9080321-03 P91-10363 50 mL 48.65 mL 08/22/19 8:30 9080321-03 P91-10382 50 mL 48.8 mL 08/22/19 14:43 9080321-04 P91-10363 50 mL 49.04 mL 08/22/19 8:30 9080321-04 P91-10382 50 mL 48.95 mL 08/22/19 14:43 9080321-05 P91-10363 50 mL 48.82 mL 08/22/19 8:30 9080321-05 P91-10382 50 mL 49.16 mL 08/22/19 14:43 9080321-06 P91-10382 50 mL 49.02 mL 08/22/19 14:43 9080321-06 P91-10363 50 mL 48.25 mL 08/22/19 8:30 9080321-07 P91-10363 50 mL 48.42 mL 08/22/19 8:30 9080321-07 P91-10382 50 mL 48.86 mL 08/22/19 14:43 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9080321-01 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-02 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-03 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-04 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-05 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-06 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-07 P91-10473 10 mL 10 mL 08/28/19 9:08 9080321-08 P91-10473 10 mL 10 mL 08/28/19 9:08 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9080321-01 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-02 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-03 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-04 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-05 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-06 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-07 P91-10470 5 mL 5 mL 08/28/19 13:49 9080321-08 P91-10470 5 mL 5 mL 08/28/19 13:49 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. 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