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HomeMy WebLinkAbout8606_Surry_SubtitleD_MSWLF_May2019GW_FID1358254_20190917I IDENR USE ONLY: I ( ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event IF: NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6), Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646, Solid Waste Monitori Name of entitv submitting Data Submittal Information ratory, consultant, facility owner): Municipal Engineering Services Co., PA Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Jonathan Pfohl E-mail: Ipfohl a(),mesco.com Phone: Facility name: Facility Address: Facility Permit # Surry County Lined MSWLF 237 Landfill Road 86 06 Mt. Airy, NC 27030 NC Landfill Rule: Actual sampling dates (e.g., (.0500 or .1600) October 20-24, 2006) May 15-17, 2019 1600 July 8, 2019 (VOC verification MW-11 D) Environmental Status: (Check all that apply) InitiallBackground Monitoring ❑X Detection Monitoring �X Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells Leachate monitoring data ❑ Surface water monitorina data Notification attached? Methane gas monitoring data Corrective action data (specify) Other(specify) No. No groundwater or surface water standards were exceeded. X Yes, a nocation of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Steven R. Gandy, Ph.D., P.E. Senior Project Manager (919) 772-5393 Facility Representativm/Name (Pri Signature P.O. BOX 97, Garner, NC 27529 Facility Representative Address C-0281 Title NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 (Area Code) Telephone Number [�— Affix NC Licensed/ Professional Geologist Seal ®Date 0', 0 as r r ��t �i�Gi►�t� ���� Semi -Annual Water Quality Monitoring Report Prepared for Surry County Subtitle D Lined MSWLF Mt. Airy, North Carolina May 2019 Permit Number: 86-06 MESCO Project Number: G19031.0 MUNICIPAL ENGINEERING SERVICES COMPANY? P.A. 68 SHIPWASH DRIVE, GARNER, NC 27529 - PHONE: 919-772-5393 P.D. Box 349, BOONE, NC 28607 - PHONE: 828-262-1767 LICENSE NUMBER: C-0281 MUNICIPAL ENGINEERING 7n E� SERVICES COMPANY9 P.A. \ GARNER, NO AND B❑❑NE, NO September 16, 2019 Ms. Jaclynne Drummond Solid Waste Section (SWS) Division of Waste Management North Carolina Department of Environmental Quality (NCDEQ) 2090 US Highway 70 Swannanoa, NC 28778 Re: Semi -Annual Water Quality Monitoring Report Surry County Lined MSWLF, Phases 1 & 2 Permit No. 86-06 MESCO Project No. G19031.0 Sampling Date(s). May 15-17 & 20, 2019 July 8, 2019 Verification Event Dear Ms Drummond: Introduction On behalf of Surry County, Municipal Engineering Services Company, P.A. (MESCO) is pleased to present this Semi -Annual Water Quality Monitoring Report for an event performed at the Surry County Subtitle D Lined Municipal Solid Waste Landfill (MSWLF) in the Spring of 2019. NCDEQ Solid Waste Rules 15A NCAC 1313.1632 requires that Surry County provide this report to the SWS on a semi-annual basis. This report documents the quality of the ground and surface waters during a monitoring event performed on May 15-17 & 20, 2019 and includes results of a verification sample collected on July 8, 2019. During this event several metals were detected in groundwater samples collected both upgradient and downgradient of the lined landfill. The detected metals are likely not attributed to landfill activities but rather originating from erosion of natural deposits. Volatile organic compounds (VOCs) detected above the laboratory reporting limit and NC 2L Standard were vinyl chloride and benzene in sample MW-6R. Vinyl chloride was reported at an estimated concentration above the 2L Standard in sample MW-11D. However, vinyl chloride was absent in a verification sample collected 6 weeks later. Surface water samples did not contain constituents in levels above applicable 2B Standards. The leachate samples continue to contain a few contaminants but were in low concentrations relative to Standards and published values. Background The Surry County Subtitle D lined MSWLF, permit #86-06, is located at 237 Landfill Road, Mount Airy, Surry County, North Carolina. The site location topographic map is depicted in the attached Sheet 1. The lined MSWLF is comprised of contiguous Phases 1 & 2 which are treated as a single unit in this report. 68 Shipwash Drive • Garner, NC 27529 e ph: 919-772-5393 • fx: 919-772-1176 • www.mesco.com LICENSE NUMBER: C-0281 Water quality at this facility has been monitored at least semi-annually since 1998 with all historical data reviewed in support of this report. This event was performed in accordance with the NC SWS rules/regulations as promulgated in 15A NCAC 13B and as a condition of the permit to operate. Assessment monitoring (targeting Appendix H constituents) was initiated site -wide in response to detections above allowable Standards in the spring of 2016. Assessment monitoring will continue indefinitely which includes targeting Appendix II constituents annually at MW-2, MW-6R and MW-9 and monitoring for LFG at proximal LFG migration wells MGP-5 and MGP-12 quarterly. During this event supplemental samples from both background wells MW-1 (closed) and MW-1 (Lined) were tested in support of an Alternative Source Demonstration Addendum (ASD-Add) for metals which is planned to be submitted to the NCDEQ as approved by the NC SWS (DIN:28729). As specified within 15A NCAC 13B.16320), the SWS Environmental Monitoring Report Form and SWS memorandums this report contains sampling procedures, field and laboratory results, groundwater and surface water characterization. Well construction summary table, field observations table, field parameter data table, sampling and analysis summary table, detections compared to Standards tables, a groundwater flow directions/rates table, potentiometric map, quality assurance/quality control data, and laboratory analytical data results are enclosed herein. MW-6R Area Investigations During this event MESCO investigated the area around MW-6R in an attempt to identify the source of VOC detections. MW-6R is located in a ditch that previously conveyed stormwater originating from the lined landfill. During the construction of Phased 2 in 2009, stormwater originating near the landfill was rerouted so that it no longer flows adjacent to MW-6R. Elevated concentrations of stabilized landfill gas (LFG) was detected in shallow migration monitoring probe MGP-5, located less than 75 feet away from MW-6R during the December 4, 2018 event but absent on May 8, 2019 (Figure 1). Active LFG extraction has been initiated at Lined Phase 1 which includes vacuum applied at the closest leachate collection system cleanout. Vinyl chloride was detected in sample MW-6R during this and the previous 11 events above the 2L Standard and benzene levels were found above the 2L Standard for the first time. There were no detections in groundwater sample MW-8 or surface water samples (SWN- 2, SW-D) collected hydraulically downgradient of MW-6R. MW-9S Area Investigations MESCO investigated the area around MW-9S in an attempt to identify the source of VOC detections during previous events. MW-9S is located about 180 feet downgradient of the Phase 2 sump near a previous drainage feature. Low levels of chlorinated hydrocarbons have consistently been detected in samples collected from MW-9S since before waste was deposited in Phase 2. VOCs were not detected above Standards in sample MW-9S during this and the previous two events. Interpretation of analytical data indicates that the adjacent deeper cluster well MW-9D remains unimpacted. LFG has never been detected from head -space of MW-9S or from adjacent migration probe MGP-12. VOCs have not been detected in supplemental samples previously collected from P-4 which is located hydraulically downgradient of MW-9S. 2 Sampling Procedure MESCO personnel performed this sampling event using portable monitoring methodology in general accordance with the site -specific Water Quality Monitoring Plan dated July 12, 2018 (DIN:1234484) which was approved by the NC SWS on August 8, 2018 (DIN:1235187). Water samples were collected from 14 downgradient groundwater monitoring wells (MW-2, MW-3R, MW-4S, MW-4D, MW-5, MW-6R, MW-8, MW-9S, MW-9D, MW-10, MW- I IS, MW-I ID, MW-12 and MW-13), one background well (MW-1), four downstream surface water locations (SW- 4 , SWN-2, SW-C and SW-D), four upstream surface water points (SWN-1, SW-1, SW-2 and SW-3) and a pre- treated leachate sample (LAGOON). Quality control measures included analysis of equipment blanks (EB) and field blanks (FB). MW-11D was resampled and tested for VOCs on July 8, 2019 since the original sample contained vinyl chloride. Sampling locations are shown on the potentiometric map (Sheet 2). A summary detailing the construction of the water monitoring wells is presented on Table 1. The function and integrity of all monitoring locations were visually evaluated and no deficiencies identified as documented on Table 2. The depth to water in each well was electronically gaged prior to purging to quantify the static water level elevation. Low -flow pumping methodology or bailing was utilized to adequately purge the wells to a minimum of three times the volume of standing water in the well or until dry. Surface water samples were collected from Stoney Creek discharge feature at previously designated locations. During well purging and surface water sample collection the required field parameters were recorded. The samples were then placed into laboratory -prepared, pre - preserved containers via a new disposable polyethylene bailer. Samples were collected, kept on ice, and transported to a NC -certified laboratory under proper C-O-C protocols within the specified hold times for each analysis. Field Parameter Data Stabilized field parameters were recorded during purging which included pH, specific conductance, temperature, methane gas and visual turbidity. A summary of the field parameter data is presented in Table 3 and the field sampling data sheet is enclosed in Appendix B. Laboratory Results Pace Analytical Services, Inc. (PACE) performed the laboratory analysis of the water and leachate samples except for the MW-11D verification sample which was tested by Environmental Conservation Laboratories (ENCO). Groundwater and surface water samples were tested for constituents listed in 40 CFR 258 Appendix I and 1,4- dioxane. Groundwater samples were also tested for turbidity in support of an Alternative Source Demonstration (ASD) Addendum planned for 2020. Untreated leachate was tested for the specific parameters required by the SWS which includes VOCs, total metals, phosphorous, BOD, COD, sulfide and nitrate. A sampling and analysis table summarizing the locations, constituents and methods is presented as Table 4. Water samples were analyzed to the laboratory -established Method Detection Limits (MDL) and any value between the MDL and laboratory -established Reporting Limit (RL) is qualified by the laboratory as an estimated concentration hence qualified with a "J". Estimated concentrations are considered non -quantifiable and discretion should be made prior to making decisions based solely on an approximate value. Table 5 summarizes constituents detected in groundwater and QC samples compared to groundwater compliance standards which include SWS adopted Groundwater Protection Standards (GWP), SWS adopted Interim Maximum Allowable Concentrations (IMAC) and North Carolina Groundwater Standards (2L). Although not applicable for regulatory compliance purposes the detections are also compared to the Maximum Contaminant Level (MCL) commonly referenced as the Federal "Drinking Water Standard". Table 6 lists the constituents detected in surface water samples compared to K the North Carolina Surface Water Standards (2B) for a Class C water -body and the MCL. Table 7 presents detections of constituents and turbidity values of background samples compared to Standards which were obtained in support of a future ASD for inorganics. Quality Control Samples No constituents were detected in either of the quality control samples (EB, FB). Groundwater Samples Detected Above Standards Metals Sample MW-9S contained quantifiable concentrations of total recoverable cobalt (109 uq/L) above the NC IMAC Standard (1 uq/L). Volatile Organic Compounds VOCs, vinyl chloride 4.6 ug/L /2L Std is 0.3 ug/L) and benzene 2.9 ug/L / (2L is 1.0 ug/L), were detected in sample MW-6R above their respective NC 2L Standard. Surface Water Samples Detected Above Standards Contaminants were not detected above established NC 2B Surface Water Standards in any of the surface water samples. Leachate Samples Raw leachate samples contained total recoverable cobalt and an estimated concentration of 1,2-dichloroethane and benzene slightly above NC 2L groundwater Standards. Lower levels of metals in leachate relative to groundwater samples is a significant line of evidence that the source of metals observed in groundwater samples are not anthropogenic. Concentrations of contaminants in leachate remain low relative to values published from similar MSWLF's which is consistent with previous observations. The BOD and COD levels are low and the BOD/COD ratio is very high (1.18) compared to typical domestic wastewater. BOD/COD ratio above 0.5 may indicate the waste is considered to be easily treatable by biological means '. Groundwater and Surface Water Characterization A potentiometric map of the uppermost aquifer constructed from groundwater elevation data recorded during this monitoring event is on Sheet 2. Groundwater flow rates and directions were calculated and are included in the hydrologic properties table (Table 8). Groundwater flow directions remain generally in a southerly direction towards the Ararat River with groundwater velocities calculated by modified Darcy's equation varied considerably due to the anisotropic geologic conditions. Streams located within the facility boundaries were observed to be of low volume and flow with low turbidity. 'hW2s:Hcgi.tu-harburi!.de/—awwweb/wbt/emwater/lessons/lesson al/lm ng_1068.html 4 Findings The inorganic detections are not believed to have originated from an anthropogenic source rather a product of erosion of natural geologic deposits. An ASD which provides technical site specific facts and site specific analytical data including evaluations of interwell (background), intrawell (baseline), metals in leachate, dissolved compared to total metals and a discussion that substantiating evidence that the metals are not anthropogenic was not approved by the SWS. A revised time -line and workplan dated January 25, 2018 (DIN:28728) was approved by the NC SWS on January 30, 2018 (DIN: 28729). Turbidity and metal analysis is planned to be performed from a set of approved upgradient backgound wells over the next 2 years and results will be submitted within routine semi-annual water quality monitoring reports. An ASD addendum for metals is planned to be submitted in early 2020. MW-6R continues to be impacted by VOCs. Vinyl chloride has consistently been detected over the past 7 years. Vinyl chloride and benzene were detected in unprecedented concentrations above the 2L Standard during this event. MW-6R is located approximately 100 feet downgradient of the Phase 2 liner and within the compliance boundary. The portion of the aquifer impacted is believed to be small as evidenced by lack of detections in MW-8 located along the downgradient flow path. The active LFG extraction system has recently been expanded proximal to MW- 6R and is expected to operate indefinitely which may mitigate potential groundwater impacts. A sample collected from MW-I ID on May 16, 2019 contained an anomalous detection of vinyl chloride below the RL but above the 2L Standard. No VOCs were detected in a verification sample collected from MW-11D on July 8, 2019. Interpretation of results of surface water samples collected along Stoney Creek and the Ararat River, including those instituted directly downgradient of MW-6R, continue to indicate the local discharge features remain unimpaired. \ Closing Semi-annual water quality and quarterly LFG monitoring will continue with the next event scheduled for the fall of 2019. Construction of Phase 4, western horizontal expansion, is expected to be completed in 2019. If you have any questions or comments regarding this report, please contact us at (919) 772-5393 or by email at infohlnmesco.com or sgandy&mesco.com. Sincerely, MUNICIPAL ENGINEERING SERVICES CO., P.A. Jonathan Pfohl Environmental Specialist Enclosures cc: Ms. Jessica Montgomery Surry County Steven R. Gandy, Ph.D, P.E. Senior Project Manger 9 Sheets Topographic Map with Site Location Surry County Landfill, Mt. Airy fl 237 Landfill Road Mount Airy, NC 28621 Lat: 36-26-30.065 Long:-80-34-15.314 Northing:983356.18 Easting:1537885.48 0 Surry Co Property Line O Closed Unlined C&D Landfill O Closed Unlined Sanitary Landfill O Active Lined MSW Landfill SHEET 1 1/0 / SW-2 (\1J00/0' /F=U/RTHER/ Ur// /PS/T�i� Ri/EA/M- /) III II IllSlnE\D.\ . C\&\D \ OVER ICLOSED LOSED r fl MSW \\ STOPPED RECEIVING C&D BEFORE JUNE 1 2008 1it STOPPED RECEIVING MSW BY JAN. 1, 1999 i'Al ��/ / I !II)II) I I/� ��\��\� lj ///� l III Illl�i �\\\\ /�� \ \ \ \ \ ! \ \ \ \ NOW R FORMERLY \�,, � r \ 1 \\\ \� - - = � \\\\ \\ \\\ \\\\ \ I I �—_ �`\\\\\\\ \\ \ \\\\\\ \\ O O O ,- 1> \�\\\ 1 \\1 11\\\\\\ \� \ OWNED BY OWNED BY SURRY A\V A vv \V1\\V AV� V AvV v \\ - - _ \\\\\\\ \\\ \1//� �_����\\\\�\ \\\\�\\�\\\\\\\ 4� = JOHNNY cox COUNTY \ \\ ___ �Jo\ \�\ \ \ ( \\��\\\\�\�\� / \\\\\\\\\ \\\\\\\\\ _ - 1I \ \\\ / MW-18 / / // / / I \ I \ \\ \ �\ \\ /% ��\ �\\o\�\\\\ \\\ \�o \\\\\�\\ �\\\\\ — — — —/� _— z II I I I/ l IIII !ll !l 111 1 III! 1 /� I III 1J \ /// (�/// IIII/ llllll I �\\\ ✓IIII/�� \ \ i GWE=974.69 s / \ \ iii� / \�\"Fumi�/i///� \��/ MW-13/ 1040 // GWE=985.28 �I1 - / — / / /PROPERTYLINE OW4-9/MW-28_ GWE=1027.75 /��i //////l l/Ill 11l//� / / /� // l 1- - = = vii// I )/I - / J _ = �\ ` �- - ~�=\\�\`\�✓ 11 �I /l l ��� \ \\ 11 \\\ �\ \ �\ \\\ 1 ii/ 10 990 NOW OR FORMERLY OWNED 9$0/ // / / // // / l / ll ll/ l I / / // -- �/ BY SHAWNA SUMMERS �i / (l/l �) ll l 111 ! I /! IIII (I / / ////// / //// // /// / / I / / / / r� �j �, \ \ \ \ \ / // // /// / %/ //// l / / // / i I % / \\ \\GWE-1015.17 \\ \\ �\ \ ��\�\ \\\\\ _ 97p / �� INACTIVE LINED\\\ \\ /, /// /�i � / MW- PHASE 1 \ \\ \\\\\� 1 \ `\\��\\\\ \\\ PTO 12/1/98 / =\ � \ \\ r- \\ '\ \\\\ — \\\\ \ %030/ ,g50 I III I IT '11 II1I I ? IIJ III I III/ IIII III) h I \ I 1 J / ll (<\ L\\�\ �� IIIy r \ \� \\ o _ / (I I ill\ �\\ \�\ \ 4_Rsm ll// //iSW-4 //%,/,01 // //� /ii �--- \�\\ ACTIVE LFG EXTRACTION s�\�==ice /ai/ , Go /%o/ � I �P ACTIVE LINED GWE=4 T PHASE 2 ) ) \\�PTO � 1�1�\/20/09 — =_- i LE END 31 3R WE=3SW-C * GWE=925.60 _GWE=973.11 MW-5_— GWE=936.85 P-10 \\\\\�\\ \\�\\\ \ � -- \\\\ \ \ \ \ \s \ \\ GWE=934.96 �� 1° \ \\ \ \�/) \\72�= \\\\ \�J — '� `�\\\`\\\ X1, \\ \\ \ 11 IIIII III ( \ - \�\\S,\ \ \\ \� \ /= ��v o MIN 11D*/— vv — v�G11II 79 MW-11S_ BMW--_10„ MW-6 _ Vinyl Chloride- 4.6 ug/L GWE=942.59�`3O__MGP-12= / \ \ ` \ _— __ __ __�/ \\�\\\\\\\�\ \ _ Benzene- 2.9 MW_--8 = SWN-2� � ---____ MW-9S�SwE`s124a_===_\�J� \. �C IIIIII\\ \\\\�\\\\ Il / — — — — — 920- — — _ MW-9D*=GWE=921.191 Al sou RAILROAD SW-D RARAT OWNED BY SURRY COUNTY ESTIMATED WASTE LIMITS UNLINED LANDFILL WASTE LIMITS OF LINED LANDFILL FACILITY OUTERMOST PROPERTY BOUNDARY TOPOGRAPHIC CONTOURS -EXISTING RELATIVE GROUNDWATER COMPLIANCE BOUNDARY RAILROAD o� OBSERVATION WELL -EXISTING MONITORING WELL - IN NETWORK LANDFILL GAS MONITORING WELL ROADS STREAM/CREEK sw SURFACE WATER SAMPLING LOCATION 960 1 EQUIPOTENTIAL UPPERMOST GROUNDWATER CONTOURS (May 14-16, 2019) GWE = 941.66 GROUNDWATER POTENTIOMETRIC ELEVATION BMW- POTENTIOMETRIC ELEVATION NOT USED FOR CONTOURING GRAPHIC SCALE 200 0 100 200 400 ( IN FEET ) 800 SHEET 2 17 Q zd W; WZ zQ L9a z I w 0 .jV Q N IL U ti Z � 7 � W I En m 0) m r, Lp t0 N � � N 171 � o� W N Z m O i1i Z CL ao 0 N 0) a N . U O w N W m m 2 U Z N Z1 C] z � Z w wus z w z Q z w L9 0 _U O J w m 0 (y) = X N O 3 m IL = O rn a m t0 C Q � � N o U >- a Q QLij :�i Cc O ILL Lul z ° CL c� Q C) W ° w w CL CL U- O U, Q SCALE: SEE SCALE BAR DATE: 0111812019 DRWN. By. R. MOSS CHKD. BY: J. PFOHL PROJECT NUMBER G 18025.0 DRAWING NO. SHEET NO. SHEET 2 1 OF 1 Tables Table 1 Groundwater Monitoring Well Construction Table May 15-17, 2019 Monitoring Well Date Installed Well Diameter Total Well Depth Top of Screen Depth Screen Length Geology of Screened Interval Top of casing Elevation Ground Elevation Groundwater Elevation Depth to Water Latitude Longitude (inches) (ft bgs) (ft bgs) (ft) (ft amsl) (ft amsl) (ft amsl) (ft btoc) MW-1 8/14/98 2 68.5 53.5 15 Rock 1127.02 1124.23 1066.35 60.67 36.434494 -80.577989 MW-2 8/16/98 2 23.5 8.5 15 Rock 936.68 933.91 923.24 13.44 36.430833 -80.571161 MW-3R 12/2/98 2 20 5 15 Rock 930.00 928.15 925.60 4.40 36.430714 -80.571575 MW-4S 8/11/98 2 20 5 15 Saprolite 943.23 940.31 936.47 6.76 36.430853 -80.572400 MW-4D 8/11/98 2 45 35 10 Rock 942.80 940.31 936.85 5.95 36.430853 -80.572400 MW-5 8/18/98 2 47.5 32.5 15 Rock 977.93 971.57 934.96 42.97 36.430356 -80.572961 MW-6R 3/22/99 2 79 64 15 Fractured Rock 1004.75 1001.81 940.75 64.00 36.429958 -80.573508 MW-8 9/1/09 2 70.75 55.75 15 Fractured Rock 971.03 968.35 912.44 58.59 36.429283 -80.573453 MW-9S 6/16/06 2 42.28 27.28 15 Fractured Rock 952.83 949.75 921.19 31.64 36.429314 -80.574464 MW-9D 6/16/06 2 65.54 55.54 10 Competent Rock 952.47 949.49 918.53 33.94 36.429314 -80.574464 MW-10 6/16/06 2 47.13 27.13 20 Fractured Rock 970.24 967.35 942.59 27.65 36.429519 -80.575486 MW-11S 9/3/09 2 46.05 31.05 15 Competent Rock 969.09 965.95 938.83 30.26 36.430197 -80.577131 MW-11D 9/3/09 2 65.31 55.31 10 Competent Rock 965.38 962.38 933.79 31.59 36.430197 -80.577131 MW-12 9/4/09 2 65 50 15 Competent Rock 996.66 993.71 945.63 51.03 36.429831 -80.576750 MW-13 9/3/09 2 36.31 21.31 15 Fractured Rock 983.13 979.83 956.72 26.41 36.430625 -80.578531 MLW-A 8/19/98 2 84 69 15 Competent Rock 1095.51 1092.51 1015.17 80.34 36.432881 -80.573539 P2-11S 6/16/06 2 50.13 40.13 10 Competent Rock 1021.53 1018.40 973.31 48.22 36.430197 -80.577131 132-11D 6/16/06 2 65.45 60.45 5 Competent Rock 1021.13 1018.73 973.11 48.02 36.430197 -80.577131 P2-12 6/16/06 2 1 59.56 1 44.56 1 15 1 Competent Rock 1 986.61 1 983.54 1 934.72 1 51.89 36.429831 -80.576750 NOTE: bgs = below ground surface amsl= above mean sea level btoc = below top of casing (PVC well casing) Slurry County Lined Landfill Page 1 of 1 Table 2 Field Observations of Monitoring Locations May 15-17, 2019 Sample Location Viable Monitoring Location Lack of Any Evidence of Tampering Locked on Arrival & Departure Hinge/Hasp Operational Tagged or Labeled Concrete Surface Pad Appears Effective Comments MW-1 Yes Yes Yes Yes Yes Yes Background Well MW-2 Yes Yes Yes Yes Yes Yes MW-3R Yes Yes Yes Yes Yes Yes MW-4S Yes Yes Yes Yes Yes Yes MW-4D Yes Yes Yes Yes Yes Yes MW-5 Yes Yes Yes Yes Yes Yes MW-6R Yes Yes Yes Yes Yes Yes County improved surface seal in September 2013 MW-8 Yes Yes Yes Yes Yes Yes Path choked off with vegetation MW-9S Yes Yes Yes Yes Yes Yes MW-9D Yes Yes Yes Yes Yes Yes MW-10 Yes Yes Yes Yes Yes Yes MW-11S Yes Yes Yes Yes Yes Yes MW-11 D Yes Yes Yes Yes Yes Yes Very slow recharge MW-12 Yes Yes Yes Yes Yes Yes Slow recharge MW-13 Yes Yes Yes Yes Yes Yes Recently bumped by JR Lynch (Contractor). Case repaired by MESCO & seems fine SW-1 Yes Moderate gage height & flow SW-2 Yes Moderate gage height & flow SW-3 Yes Moderate gage height & flow SWN-1 Yes Moderate gage height & flow SWN-2 Yes Moderate gage height & flow SW-C Yes Moderate gage height & flow SW-D Yes Moderate gage height & flow LAGOON Yes Yes Yes Sample from invert which is typical Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes L Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Yes Any unusual field conditions, observations, or events: Phase 2 has an earthen berm built Win liner limits which may reduce any potential for overland flow from Phase 2. Paths leading to wells and around entire facility have been maintained by County. All are 4X4 accessible. Co performed well maintenance by pouring new concrete pads around several wells in the Fall of 2017. Slurry County Lined Landfill Page 1 of 1 Table 3 Hydrogeologic Prpoperties at Monitoring Locations May 15-17, 2019 Parameter Depth to Water Water Elevation TOC Elevation Temp. pH Specific Conductance ORP DO Hardness Methane Gas in Headspace Turbidity of Metal Sample Units ft (btoc) ft (amsl) ft (amsl) C SU umhos/cm my mg/L mg/L (%/Vol) (NTU) MW-1 60.67 1066.35 1127.02 15.1 5.1 67 NR NR NR NR 7.22 MW-2 13.44 923.24 936.68 13.6 5.4 85 NR NR NR NR 0.32 MW-3R 4.40 925.60 930.00 14.4 5.6 300 NR NR NR NR 1.60 MW-4S 6.76 936.47 943.23 14.6 5.4 122 NR NR NR NR 2.03 MW-4D 5.95 936.85 942.80 14.9 6.3 191 NR NR NR NR 0.78 MW-5 42.97 934.96 977.93 14.0 5.3 111 NR NR NR 0.0 4.63 MW-6R 64.00 940.75 1004.75 14.2 5.2 192 NR NR NR 0.0 0.30 MW-8 58.59 912.44 971.03 13.7 5.0 75 NR NR NR NR 4.55 MW-9S 31.64 921.19 952.83 14.6 6.4 260 NR NR NR 0.0 7.18 MW-9D 33.94 918.53 952.47 15.0 7.7 560 NR NR NR NR 30.5 MW-10 27.65 942.59 970.24 14.4 5.7 187 NR NR NR NR 9.59 MW-11S 30.26 938.83 969.09 14.2 6.6 125 NR NR NR NR 1.99 MW-11D 31.59 933.79 965.38 15.2 7.7 887 NR NR NR NR 18.0 MW-12 51.03 945.63 996.66 14.2 7.2 243 NR NR NR NR 5.34 MW-13 26.41 956.72 983.13 13.8 5.0 109 NR NR NR NR 0.32 MLW-A 80.34 1015.17 1095.51 NR NR NR NR NR NR NR NR Minimum 4.40 912.44 930.00 13.6 5.00 67 NR NR NR NR 0.30 Average 35.60 946.82 982.42 14.4 5.97 234 NR NR NR NR 6.29 Maximum 80.34 1066.35 1127.02 15.2 7.70 887 NR NR NR NR 30.5 SW-1 - - - 13.1 6.8 97 NR 8.1 20 - 6.60 SW-2 14.3 6.9 74 NR 7.3 60 - 11.1 SW-3 14.6 7.1 89 NR 8.1 20 - 7.48 SW-4 15.1 6.9 131 NR 8.1 30 - 4.63 SWN-1 14.5 6.9 31 107 9.8 20 - 3.94 SWN-2 15.3 6.9 38 105 9.3 20 - 4.61 SW-C 14.8 6.6 75 NR 8.2 20 - 5.03 SW-D 16.3 1 6.7 1 123 1 101 1 9.7 1 20 1 - 4.00 Minimum - 13.1 6.6 31 101 7.3 20 NR 3.94 Average 14.8 6.8 82 104 8.6 26 NR 5.92 Maximum - 16.3 7.1 131 107 9.8 60 NR 11.1 NR = No reading attempted btoc = Below top of casing amsl = Above mean sea level Slurry County Lined Landfill Page 1 of 1 Table 4 Sampling and Analysis Summary May 15-17 & 20, 2019 July 8, 2019 Verification Sample App. I Other App. II Field Parameter Leachate d O m a- O c � _ Q O 5 c Q 7 T co c Cz :3 co U � � � Q• "a .2:D � C "a � Q L ci 0 +0 (o O o o E -0-0uci X S2 o co = D 2� o O O > H H H H O 0 U S a U) a a- m U Z 0 0 O O C m0 O 0 O O CD O CD m 0 N CO N O t0 N CD c9 i O O O L6 O O O N� M o0 co :: :� co O CO N N LO M a- a a_ d m a� a� a� 2 a� 2 2� m a a 2 W W w W � � � � � w W W U w m � N N N G) N _� N � co -0 -0 -0 -0 -0 J J J J W W U_ LL U- u- LL J J J J J MW-1 x x x x x x x MW-2 x x x x x x x MW-3R x x x x x x x MW-4S x x x x x x x MW-4D x x x x x x x MW-5 x x x x x x x MW-6R x x x x x x x MW-8 x x x x x x x MW-9S x x x x x x x MW-91D x x x x x x x MW-10 x x x x x x x MW-11S x x x x x x x MW-11 D V x x x x x x MW-12 x x x x x x x MW-13 x x x x x x x SWN-1 x x x x x x x x x x SWN-2 x x x x x x x x x x SW-1 x x x x x x x x x SW-2 x x x x x x x x x SW-3 x x x x x x x x x SW-4 x x x x x x x x x SW-C x x x x x x x x x SW-D x x x x x x x x x x LAGOON x x x x x x x x x x EB x x x FIB I x X1 x Appendix I & II = Lists from current 40 CFR 258 V = Verification sample collected on July 8, 2019 Surry County Lined Landfill Page 1 of 1 Table 5 Groundwater, Leachate and QC Sample Detections May 15-17, & 20, 2019 July 8, 2019 (MW-11 D Verification) Parameter Name MDL RL 2L/GWP/IMAC MCL MW-1 I MW-2 MW-3R MW-4S MW-41D MW-5 MW-6R MW-8 MW-9S MW-9D MW-10 MW-11S MW-11D MW-111) (7/8/19) MW-12 MW-13 EB FB LAGOON STANDARD BG S S S S S S S S S S S S S S S QC QC LEACHATE Metals (Taraeted 40CFR 258 Appendix I Barium, total 1 5 700 2000 13.7 J 36.5 J 44.1 J 41.8 J 48 J 59.2 J 81.3 J 96.3 J 104 21.8 J 27.9 J 21.4 J 14.7 J - 8.6 J 26.3 J 253 Cadmium, total 0.4 1 2 5 0.63 J 0.72 J - 0.72 J Cobalt, total 1.1 5 1 NE 5.6 J 119 (N) - 21.4 Copper, total 2.1 5 1000 1300 3 J - Lead, total 1.6 5 15 15 2.5 J Nickel, total 0.9 5 100 NE 7.9 J 8 J 3.1 J 5.2 J Thallium, total 0.06 0.1 0.28 2 0.08 J 0.08 J 0.1 J 0.35 J 0.07 J Zinc, total 3.9 10 1000 NE 14.3 9.6 J 5.2 J 8.7 J Turbidity (Field Measured) (NTU) Turbidity (NTU) 0.01 NE NE 7.22 0.32 1.6 2.03 1 0.78 1 4.63 0.30 1 4.55 7.18 30.5 9.59 1.94 18.0 5.34 0.32 31.8 VOCs (Targeted 40CFR 258 Appendix 1) 1,1-Dichloroethane 0.27 1 6 NE 2.88 1.71 0.45 J 1,2-Dichloroethane 0.34 1 0.4 5 0.57 J 0.63 J 1.2 1,2-Dichloropropane 0.19 1 0.6 5 0.54 J Benzene 0.15 1 1 5 0.28 J 2.9 (L) 0.96 J 1 0.53 J 2.5 cis-1,2-Dichloroethene 0.29 1 70 70 2.13 2.29 0.43 J 1.4 J 14.2 6.8 1.44 1.8 J 0.63 J 1.3 J Ethylbenzene 0.26 1 600 700 0.33 J Methylene Chloride 0.23/1/3.7 1/5 5 5 Tetrachloroethene 0.16 1 0.7 5 0.52 J 0.51 J Toluene 0.24 1 600 1000 0.84 J trans-1,2-Dichloroethene 0.25 1 100 100 5.3 0.96 J 0.91 J 1.6 J Trichloroethene 0.22 1 3 5 0.52 J 0.74 J 0.63 J Vinyl chloride 0.24 1 0.03 2 4.6 (L) 0.56 J 0.82 J Mercury Mercury, total 0.1 1 0.2 1 2 1 - - - -- - - - - - - -- 0.14 J Leachate Parmeters BOD, 5 day 2000 1 2000 NE NE I - - - -- - - - - I - - - I - I - 174000 12500 25000 NE NE - - - - 147000 EC Sulfate 500 1 1000 1 250000 1 NE - - - 2430 J Notes Units ug/L unless shown otherwise, Blank cells means not detected above MDL, -- means parameter not analyzed, NE means not established Bold Above RL & Established 2L/GWP/IMAC Std. (Regulatory compliance Standard) Highlighted Above Established MCL Drinking Water Std. (No regulatory significance) MDL = Adjusted Method Detection Limit established by the laboratory via a statistical calculation. Since the MDL is below the point of calibration, results reported down to the MDL are not reliable and must be qualified as estimated values and, as such, carry a "J" qualifier designation. RL = Reporting Limit established by the laboratory. The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. 2L/GW P/IMAC Standard = INC 2L /GWP and IMAC Standards adopted and enforced by the NC SWS, 2L = NC 2L Groundater Standard 15A NCAC 02L .0202 adopted by NC SWS as a regulatory groundater Standard. GW P=Groundwater Protection Standard adopted by NC SWS as a regulatory groundater Standard. IMAC=Interim Maximum Allowable Concentration adopted by NC SWS as a regulatory groundater Standard. MCL = Maximum Contaminant Level for drinking water established by the USEPA. J = "J-qualified'. Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". (N) Preliminary source is believed to be Natural originating from erosion of natural deposits. Source not anthropogenic. (L) Prelilminary source is believed to be anthropogenic with Landfill Gas &/or leachate as suspected transport mechanism. A definitive source of the detections was not determined as part of this report. BG= Background Well Sample, QC = Quality Control Sample, S = Seminal Well Sample. Surry County Lined Landfill Page 1 of 1 Table 6 Surface Water Sample Detections May 17, 2019 Parameter Name MDL RL NC 213 STD' NC PVZ MCL I SWN-1 I SW-C SW-D SW-4 SWN-2 I Upstream I Downstream Downstream Downstream Downstream Metals (Tarcieted 40CFR 258 Appendix I Barium, total 1 5 NE 1200,000 2000 1 16 J 1 18.6 J 16.1 J 17.7 J 17.4 J Hardness as CaCo3 (Field Measured) Hardness mg/L)l 20 1 -- I NE I NE NE 1 20 20 1 20 30 1 20 Turbidity (Field Measured) Turbidity NTU 0.01 -- 50 1 NE - 3.94 1 5.03 1 4.00 4.63 4.61 Notes: Units ug/L unless indicated otherwise, Blank cells means Not Detected, NE means Standard Not Established J = "J-qualified". Defined by the lab as "estimated concentration above the adjusted method detection limit and below the adjusted reporting limit". Red Bold Above Applicable Established 2B Std. Above Established Federal MCL Drinking Water Std. Receivina surface waters are Stonev Creek (12-72-12) and Ararat River (12-7244.5) Both Class C. 03040101 (8-Diait HUC). ' NC 2B STD = North Carolina 15A NCAC 02B Water Quality Standards for Surface Waters. Presumed NC SWS adopted the numerical Standard for regulatory compliance purposes z INC PV= INC Protective Value. These criteria may be based on limited toxicological information and are offered as guidelines only. Contact DWR staff for further information. INC PV for barium based on fresh and salt (All Class C & SC) fish consumption. 3 MCL= Maximum Contaminant Level. Federal "Drinking Water Standard". Shown for comparison purposes only. Not applicable for regulatory compliance purposes. Surry County Lined Landfill Page 1 of 1 Table 7 Groundwater Sample Detections (Background) Designated Background Wells and those Approved by NC SWS* to Establish Background Conditions at the Site May 17, 2019 Parameter Name MDL 2L/GWP/IMAC MW-1 RL MCL STANDARD � (Closed) Metals (Appendix MW-1 (Lined) Barium, total 1 5 700 20001 13.7 J 47 J Cadmium, total 0.4 1 2 5 0.91 J Cobalt, total 1.1 5 1 NE 5.6 J 2.5 J Copper, total 2.1 5 1000 1300 3 J Lead, total 1.6 5 15 15 1.7 J Nickel, total 0.9 5 100 NE 7.9 J 1.6 J Thallium, total 0.06 0.1 0.28 2 0.08 J Zinc, total 3.9 1 10 1 1000 NE 14.3 9.3 J Turbidity (Measured in Lab) Turbidity 0.5 1 1 NE I NE 1 7.22 5.49 Units ug/L, Blank cells means Not Detected, -- means not tested Red Bold Above Established 2L/GWP/IMAC Std. Regulatory compliance Standard Highlighted Above Established MCL Drinking Water Std. No regulatory compliance significance. MDL = Method Detection Limit, 2L = NC 2L Groundater Standard, GWP=Groundwater Protection Standard, IMAC=Interim Maximum Allowable Con MCL = Maximum Contaminant Level Federal Standard for Drinking Water J = "J-qualified". Estimated concentration above the adjusted MDL and below the adjusted reporting limit. * = NC SWS Approved that data from wells MW-1 (Closed), MW-1 (Lined) and 22 other "OW42' wells may be used in support of an ASD for inorge Surry County Landfill -Mt. Airy Page 1 of 1 Table 8 Hydrogeologic Prpoperties at Monitoring Locations May 15-16, 2019 Monitoring Location Hydraulic Conductivity (cm/sec) Effective Porosity Hydraulic Gradient Flow Rate Flow Direction Depth to Groundwater Groundwater Potentiometric Elevation Screened Interval Lithology (cm/second) N (feet/feet) (feetlyear) (feet btoc) (feet amsl) MW-1 2.45E-04 3 0.127 1,074 N53E 60.67 1066.35 Rock MW-2 3.20E-04 3 0.104 1,148 S11E 13.44 923.24 Rock MW-3R 3.20E-04 3 0.062 684 S18E 4.40 925.60 Rock MW-4S 1.50E-04 3 0.106 552 S23E 6.76 936.47 Sandy Silt & Fractured Rock MW-4D 1.59E-04 3 - - - 5.95 936.85 Rock MW-5 3.20E-04 3 0.110 1,213 S53E 43.70 934.96 Rock MW-6R 3.20E-04 3 0.088 977 S27E 64.00 940.75 Fractured Rock MW-8 1.08E-03 3 0.103 3,840 S01 N 58.59 912.44 Fractured Rock MW-9S 7.45E-04 3 0.089 2,294 S23E 31.64 921.19 Fractured Rock MW-9D 1.07E-05 3 - - 33.94 918.53 Competent Rock MW-10 1.43E-04 3 0.116 573 S02E 27.65 942.59 Fractured Rock MW-11S 6.19E-05 3 0.109 232 S13W 30.26 938.83 Competent Rock MW-11 D na 3 - - - 37.35 933.79 Competent Rock MW-12 1.91 E-06 3 0.172 11 S25W 51.03 945.63 Competent Rock MW-13 2.71E-03 3 0.125 11,683 S35W 26.41 956.72 Fractured Rock P2-12 5.91 E-07 3 0.551 - na 51.89 934.72 Competent Rock MLW-A na 3 0.038 - N82E 80.34 1015.17 Competent Rock Minimum 5.91 E-07 3 0.038 11 4.40 912.44 Average 4.39E-04 3 0.136 1,145 - 36.94 946.11 Maximum 2.71 E-03 3 0.551 3,840 80.34 1066.35 NOTE: Hydraulic conductivity and effective porosity values derived from slug tests performed by MESCO. Hydrologic gradient from water levels recorded on May 14-16, 2019. Flow rate for MW-13 was considered an outlier; therefore not included in the average or maximum. Flow rate (Q) is defined by modified Darcy's equation: where K A Q ne dl K = hydraulic conductivity n e = effective porosity dh = head difference dl = horizontal distance Slurry County Lined MSWLF Page 1 of 1 Appendix A Laboratory Analysis Reports Chains of Custody lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 05, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory between May 16, 2019 and May 20, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. A revised laboratory report is being submitted on 6/10/19 to include a revised subcontract laboratory report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services r.Q _Kok Q REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 105 lacmnalytical' www.pacelabs.corn Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Pace Analytical National Certification IDs 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Certification #: T 104704245-17-14 Texas Mold Certification #: LAB0152 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Virginia Certification #: VT2006 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 9980939910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Lab ID Sample ID Matrix Date Collected Date Received 92429561001 MW-5 Water 05/15/19 13:20 05/16/19 09:00 92429561002 MW-6R Water 05/15/19 14:00 05/16/19 09:00 92429561003 MW-11S Water 05/15/19 14:20 05/16/19 09:00 92429561004 LAGOON Water 05/16/19 05:20 05/17/19 13:00 92429561005 MW-8 Water 05/16/1911:53 05/17/19 13:00 92429561006 MW-9S Water 05/16/1911:50 05/17/19 13:00 92429561007 MW-10 Water 05/16/19 09:40 05/17/19 13:00 92429561008 MW-12 Water 05/16/19 09:50 05/17/19 13:00 92429869002 MW-2 Water 05/17/19 08:50 05/20/19 11:26 92429869003 MW-3R Water 05/17/19 08:45 05/20/19 11:26 92429869004 MW-4S Water 05/17/19 08:35 05/20/19 11:26 92429869006 MW-91) Water 05/17/19 00:00 05/20/19 11:26 92429869007 MW-11D Water 05/17/19 00:00 05/20/19 11:26 92429869008 MW-13 Water 05/17/1915:50 05/20/19 11:26 92429869009 SW-D Water 05/17/19 07:35 05/20/19 11:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92429561001 MW-5 EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C 92429561002 MW-6R EPA 601 OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN 92429561003 MW-11S EPA 601OD DS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN 92429561004 LAGOON EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA7470A JMW1 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN SM 521OB-2011 JP1 1 PASI-A EPA 9040C ECH 1 PASI-A EPA 300.0 Rev 2.1 1993 CDC 1 PASI-A EPA 353.2 Rev 2.0 1993 MFO 1 PASI-A EPA 365.1 Rev 2.0 1993 MDW 1 PASI-A SM 5220D-2011 GC 1 PASI-A 92429561005 MW-8 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN 92429561006 MW-9S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN 92429561007 MW-10 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C EPA 8260D DWR 65 PAN 92429561008 MW-12 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D CL 51 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 8260D DWR 65 PAN 92429869002 MW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869003 MW-3R EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869004 MW-4S EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869006 MW-91) EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869007 MW-11D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869008 MW-13 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A 92429869009 SW-D EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-5 Lab ID: 92429561001 Collected: 05/15/19 13:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/20/19 11:15 05/23/19 02:17 7440-36-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:17 7440-38-2 59.2 ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-39-3 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:17 7440-41-7 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:17 7440-43-9 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-47-3 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-48-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-50-8 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7439-92-1 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-02-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:17 7782-49-2 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-22-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:17 7440-62-2 9.6J ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:17 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.083J ug/L 0.10 0.060 1 05/21 /19 11:15 05/22/19 08:50 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1917:50 67-64-1 ND ug/L 10.0 0.90 1 05/23/1917:50 107-13-1 0.28J ug/L 1.0 0.15 1 05/23/1917:50 71-43-2 ND ug/L 1.0 0.34 1 05/23/1917:50 74-97-5 ND ug/L 1.0 0.26 1 05/23/1917:50 75-27-4 ND ug/L 1.0 0.62 1 05/23/1917:50 75-25-2 ND ug/L 2.0 0.62 1 05/23/1917:50 74-83-9 ND ug/L 5.0 3.3 1 05/23/1917:50 78-93-3 ND ug/L 2.0 0.40 1 05/23/1917:50 75-15-0 ND ug/L 1.0 0.22 1 05/23/1917:50 56-23-5 ND ug/L 1.0 0.23 1 05/23/1917:50 108-90-7 ND ug/L 1.0 0.49 1 05/23/1917:50 75-00-3 ND ug/L 5.0 2.3 1 05/23/1917:50 67-66-3 ND ug/L 1.0 0.39 1 05/23/1917:50 74-87-3 ND ug/L 5.0 0.26 1 05/23/1917:50 96-12-8 ND ug/L 1.0 0.41 1 05/23/1917:50 124-48-1 ND ug/L 1.0 0.26 1 05/23/1917:50 106-93-4 ND ug/L 1.0 0.46 1 05/23/1917:50 74-95-3 ND ug/L 1.0 0.29 1 05/23/1917:50 95-50-1 ND ug/L 1.0 0.26 1 05/23/1917:50 106-46-7 ND ug/L 1.0 0.54 1 05/23/1917:50 110-57-6 ND ug/L 1.0 0.27 1 05/23/1917:50 75-34-3 ND ug/L 1.0 0.34 1 05/23/1917:50 107-06-2 ND ug/L 1.0 0.24 1 05/23/1917:50 75-35-4 1.4 ug/L 1.0 0.29 1 05/23/1917:50 156-59-2 ND ug/L 1.0 0.25 1 05/23/1917:50 156-60-5 ND ug/L 1.0 0.19 1 05/23/1917:50 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-5 Lab ID: 92429561001 Collected: 05/15/19 13:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 05/23/19 17:50 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 05/23/19 17:50 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 05/23/19 17:50 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 05/23/19 17:50 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 05/23/19 17:50 591-78-6 lodomethane ND ug/L 20.0 12.5 1 05/23/19 17:50 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 05/23/19 17:50 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 05/23/19 17:50 108-10-1 Styrene ND ug/L 1.0 0.27 1 05/23/19 17:50 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 05/23/19 17:50 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 05/23/19 17:50 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 05/23/19 17:50 127-18-4 Toluene ND ug/L 1.0 0.24 1 05/23/19 17:50 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 05/23/19 17:50 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 05/23/19 17:50 79-00-5 Trichloroethene ND ug/L 1.0 0.22 1 05/23/19 17:50 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 05/23/19 17:50 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 05/23/19 17:50 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 05/23/19 17:50 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 05/23/19 17:50 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 05/23/19 17:50 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 100 % 70-130 1 05/23/19 17:50 460-00-4 1,2-Dichloroethane-d4 (S) 110 % 70-130 1 05/23/19 17:50 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 05/23/19 17:50 2037-26-5 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-6R Lab ID: 92429561002 Collected: 05/15/19 14:00 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/20/19 11:15 05/23/19 02:21 7440-36-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:21 7440-38-2 81.3 ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-39-3 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:21 7440-41-7 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:21 7440-43-9 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-47-3 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-48-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-50-8 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7439-92-1 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-02-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:21 7782-49-2 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-22-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:21 7440-62-2 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.10 ug/L 0.10 0.060 1 05/21 /19 11:15 05/22/19 08:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1918:07 67-64-1 ND ug/L 10.0 0.90 1 05/23/1918:07 107-13-1 2.9 ug/L 1.0 0.15 1 05/23/1918:07 71-43-2 ND ug/L 1.0 0.34 1 05/23/1918:07 74-97-5 ND ug/L 1.0 0.26 1 05/23/1918:07 75-27-4 ND ug/L 1.0 0.62 1 05/23/1918:07 75-25-2 ND ug/L 2.0 0.62 1 05/23/1918:07 74-83-9 ND ug/L 5.0 3.3 1 05/23/1918:07 78-93-3 ND ug/L 2.0 0.40 1 05/23/1918:07 75-15-0 ND ug/L 1.0 0.22 1 05/23/1918:07 56-23-5 ND ug/L 1.0 0.23 1 05/23/1918:07 108-90-7 ND ug/L 1.0 0.49 1 05/23/1918:07 75-00-3 ND ug/L 5.0 2.3 1 05/23/1918:07 67-66-3 ND ug/L 1.0 0.39 1 05/23/1918:07 74-87-3 ND ug/L 5.0 0.26 1 05/23/1918:07 96-12-8 ND ug/L 1.0 0.41 1 05/23/1918:07 124-48-1 ND ug/L 1.0 0.26 1 05/23/1918:07 106-93-4 ND ug/L 1.0 0.46 1 05/23/1918:07 74-95-3 ND ug/L 1.0 0.29 1 05/23/1918:07 95-50-1 ND ug/L 1.0 0.26 1 05/23/1918:07 106-46-7 ND ug/L 1.0 0.54 1 05/23/1918:07 110-57-6 0.45J ug/L 1.0 0.27 1 05/23/1918:07 75-34-3 0.57J ug/L 1.0 0.34 1 05/23/1918:07 107-06-2 ND ug/L 1.0 0.24 1 05/23/1918:07 75-35-4 14.2 ug/L 1.0 0.29 1 05/23/1918:07 156-59-2 5.3 ug/L 1.0 0.25 1 05/23/1918:07 156-60-5 ND ug/L 1.0 0.19 1 05/23/1918:07 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-6R Lab ID: 92429561002 Collected: 05/15/19 14:00 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 05/23/19 18:07 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 05/23/19 18:07 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 05/23/19 18:07 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 05/23/19 18:07 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 05/23/19 18:07 591-78-6 lodomethane ND ug/L 20.0 12.5 1 05/23/19 18:07 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 05/23/19 18:07 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 05/23/19 18:07 108-10-1 Styrene ND ug/L 1.0 0.27 1 05/23/19 18:07 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 05/23/19 18:07 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 05/23/19 18:07 79-34-5 Tetrachloroethene 0.51J ug/L 1.0 0.16 1 05/23/19 18:07 127-18-4 Toluene ND ug/L 1.0 0.24 1 05/23/19 18:07 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 05/23/19 18:07 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 05/23/19 18:07 79-00-5 Trichloroethene 0.74J ug/L 1.0 0.22 1 05/23/19 18:07 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 05/23/19 18:07 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 05/23/19 18:07 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 05/23/19 18:07 108-05-4 Vinyl chloride 4.6 ug/L 1.0 0.24 1 05/23/19 18:07 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 05/23/19 18:07 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 103 % 70-130 1 05/23/19 18:07 460-00-4 1,2-Dichloroethane-d4 (S) 113 % 70-130 1 05/23/19 18:07 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 05/23/19 18:07 2037-26-5 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 19:36 05/28/19 19:36 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 19:36 05/28/19 19:36 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 19:36 05/28/19 19:36 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 19:36 05/28/19 19:36 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 19:36 05/28/19 19:36 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 19:36 05/28/19 19:36 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 19:36 05/28/19 19:36 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 19:36 05/28/19 19:36 74-83-9 CC Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 19:36 05/28/19 19:36 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 19:36 05/28/19 19:36 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 19:36 05/28/19 19:36 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 19:36 05/28/19 19:36 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 19:36 05/28/19 19:36 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 19:36 05/28/19 19:36 74-87-3 CC 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 19:36 05/28/19 19:36 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 19:36 05/28/19 19:36 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 19:36 05/28/19 19:36 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 19:36 05/28/19 19:36 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 19:36 05/28/19 19:36 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-6R Lab ID: 92429561002 Collected: 05/15/19 14:00 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.349 1 05/28/1919:36 05/28/1919:36 95-50-1 ND ug/L 1.00 0.220 1 05/28/1919:36 05/28/1919:36 541-73-1 ND ug/L 1.00 0.274 1 05/28/1919:36 05/28/1919:36 106-46-7 ND ug/L 5.00 0.551 1 05/28/1919:36 05/28/1919:36 75-71-8 2.88 ug/L 1.00 0.259 1 05/28/1919:36 05/28/1919:36 75-34-3 ND ug/L 1.00 0.361 1 05/28/1919:36 05/28/1919:36 107-06-2 ND ug/L 1.00 0.398 1 05/28/1919:36 05/28/1919:36 75-35-4 2.13 ug/L 1.00 0.260 1 05/28/1919:36 05/28/1919:36 156-59-2 ND ug/L 1.00 0.396 1 05/28/1919:36 05/28/1919:36 156-60-5 ND ug/L 1.00 0.306 1 05/28/1919:36 05/28/1919:36 78-87-5 ND ug/L 1.00 0.352 1 05/28/1919:36 05/28/1919:36 563-58-6 ND ug/L 1.00 0.366 1 05/28/1919:36 05/28/1919:36 142-28-9 ND ug/L 1.00 0.418 1 05/28/1919:36 05/28/1919:36 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1919:36 05/28/1919:36 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1919:36 05/28/1919:36 594-20-7 ND ug/L 1.00 0.320 1 05/28/1919:36 05/28/1919:36 108-20-3 ND ug/L 1.00 0.384 1 05/28/1919:36 05/28/1919:36 100-41-4 ND ug/L 1.00 0.256 1 05/28/1919:36 05/28/1919:36 87-68-3 ND ug/L 10.0 3.82 1 05/28/1919:36 05/28/1919:36 591-78-6 ND ug/L 1.00 0.350 1 05/28/1919:36 05/28/1919:36 99-87-6 ND ug/L 10.0 3.93 1 05/28/1919:36 05/28/1919:36 78-93-3 ND ug/L 5.00 1.00 1 05/28/1919:36 05/28/1919:36 75-09-2 ND ug/L 10.0 2.14 1 05/28/1919:36 05/28/1919:36 108-10-1 ND ug/L 1.00 0.367 1 05/28/1919:36 05/28/1919:36 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1919:36 05/28/1919:36 91-20-3 ND ug/L 1.00 0.307 1 05/28/1919:36 05/28/1919:36 100-42-5 ND ug/L 1.00 0.385 1 05/28/1919:36 05/28/1919:36 630-20-6 ND ug/L 1.00 0.130 1 05/28/1919:36 05/28/1919:36 79-34-5 0.519J ug/L 1.00 0.372 1 05/28/1919:36 05/28/1919:36 127-18-4 ND ug/L 1.00 0.412 1 05/28/1919:36 05/28/1919:36 108-88-3 ND ug/L 1.00 0.230 1 05/28/1919:36 05/28/1919:36 87-61-6 ND ug/L 1.00 0.355 1 05/28/1919:36 05/28/1919:36 120-82-1 ND ug/L 1.00 0.319 1 05/28/1919:36 05/28/1919:36 71-55-6 ND ug/L 1.00 0.383 1 05/28/1919:36 05/28/1919:36 79-00-5 0.518J ug/L 1.00 0.398 1 05/28/1919:36 05/28/1919:36 79-01-6 ND ug/L 5.00 1.20 1 05/28/1919:36 05/28/1919:36 75-69-4 ND ug/L 2.50 0.807 1 05/28/1919:36 05/28/1919:36 96-18-4 ND ug/L 10.0 1.63 1 05/28/1919:36 05/28/1919:36 108-05-4 ND ug/L 1.00 0.259 1 05/28/1919:36 05/28/1919:36 75-01-4 ND ug/L 1.00 0.341 1 05/28/1919:36 05/28/1919:36 95-47-6 ND ug/L 2.00 0.719 1 05/28/1919:36 05/28/1919:36 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1919:36 05/28/1919:36 1330-20-7 ND ug/L 100 36.0 1 05/28/1919:36 05/28/1919:36 123-91-1 92.8 % 80.0-120 1 05/28/1919:36 05/28/1919:36 2037-26-5 100 % 77.0-126 1 05/28/1919:36 05/28/1919:36 460-00-4 REPORT OF LABORATORY ANALYSIS CC J J This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-6R Lab ID: 92429561002 Collected: 05/15/19 14:00 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 88.9 % 70.0-130 1 05/28/19 19:36 05/28/19 19:36 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-11S Lab ID: 92429561003 Collected: 05/15/19 14:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/20/19 11:15 05/23/19 02:24 7440-36-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:24 7440-38-2 21.4 ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-39-3 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:24 7440-41-7 ND ug/L 1.0 0.50 1 05/20/19 11:15 05/23/19 02:24 7440-43-9 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-47-3 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-48-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-50-8 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7439-92-1 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-02-0 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:24 7782-49-2 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-22-4 ND ug/L 5.0 2.5 1 05/20/19 11:15 05/23/19 02:24 7440-62-2 ND ug/L 10.0 5.0 1 05/20/19 11:15 05/23/19 02:24 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/21/19 11:15 05/22/19 08:57 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1918:24 67-64-1 ND ug/L 10.0 0.90 1 05/23/1918:24 107-13-1 0.53J ug/L 1.0 0.15 1 05/23/1918:24 71-43-2 ND ug/L 1.0 0.34 1 05/23/1918:24 74-97-5 ND ug/L 1.0 0.26 1 05/23/1918:24 75-27-4 ND ug/L 1.0 0.62 1 05/23/1918:24 75-25-2 ND ug/L 2.0 0.62 1 05/23/1918:24 74-83-9 ND ug/L 5.0 3.3 1 05/23/1918:24 78-93-3 ND ug/L 2.0 0.40 1 05/23/1918:24 75-15-0 ND ug/L 1.0 0.22 1 05/23/1918:24 56-23-5 ND ug/L 1.0 0.23 1 05/23/1918:24 108-90-7 ND ug/L 1.0 0.49 1 05/23/1918:24 75-00-3 ND ug/L 5.0 2.3 1 05/23/1918:24 67-66-3 ND ug/L 1.0 0.39 1 05/23/1918:24 74-87-3 ND ug/L 5.0 0.26 1 05/23/1918:24 96-12-8 ND ug/L 1.0 0.41 1 05/23/1918:24 124-48-1 ND ug/L 1.0 0.26 1 05/23/1918:24 106-93-4 ND ug/L 1.0 0.46 1 05/23/1918:24 74-95-3 ND ug/L 1.0 0.29 1 05/23/1918:24 95-50-1 ND ug/L 1.0 0.26 1 05/23/1918:24 106-46-7 ND ug/L 1.0 0.54 1 05/23/1918:24 110-57-6 ND ug/L 1.0 0.27 1 05/23/1918:24 75-34-3 ND ug/L 1.0 0.34 1 05/23/1918:24 107-06-2 ND ug/L 1.0 0.24 1 05/23/1918:24 75-35-4 0.63J ug/L 1.0 0.29 1 05/23/1918:24 156-59-2 0.911 ug/L 1.0 0.25 1 05/23/1918:24 156-60-5 ND ug/L 1.0 0.19 1 05/23/1918:24 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-11S Lab ID: 92429561003 Collected: 05/15/19 14:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) VOA (GC/MS) 8260D Acetone Acrylonitrile Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Dibromomethane Date: 07/05/2019 03:57 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 05/23/1918:24 10061-01-5 ND ug/L 1.0 0.31 1 05/23/1918:24 10061-02-6 ND ug/L 150 56.2 1 05/23/1918:24 123-91-1 ND ug/L 1.0 0.26 1 05/23/1918:24 100-41-4 ND ug/L 5.0 0.57 1 05/23/1918:24 591-78-6 ND ug/L 20.0 12.5 1 05/23/1918:24 74-88-4 ND ug/L 5.0 3.7 1 05/23/1918:24 75-09-2 ND ug/L 5.0 4.5 1 05/23/1918:24 108-10-1 ND ug/L 1.0 0.27 1 05/23/1918:24 100-42-5 ND ug/L 1.0 0.34 1 05/23/1918:24 630-20-6 ND ug/L 1.0 0.22 1 05/23/1918:24 79-34-5 ND ug/L 1.0 0.16 1 05/23/1918:24 127-18-4 ND ug/L 1.0 0.24 1 05/23/1918:24 108-88-3 ND ug/L 1.0 0.18 1 05/23/1918:24 71-55-6 ND ug/L 1.0 0.24 1 05/23/1918:24 79-00-5 ND ug/L 1.0 0.22 1 05/23/1918:24 79-01-6 ND ug/L 1.0 0.31 1 05/23/1918:24 75-69-4 ND ug/L 1.0 0.35 1 05/23/1918:24 96-18-4 ND ug/L 2.0 1.4 1 05/23/1918:24 108-05-4 0.56J ug/L 1.0 0.24 1 05/23/1918:24 75-01-4 ND ug/L 1.0 0.63 1 05/23/1918:24 1330-20-7 103 % 70-130 1 05/23/1918:24 460-00-4 113 % 70-130 1 05/23/1918:24 17060-07-0 103 % 70-130 1 05/23/1918:24 2037-26-5 Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 50.0 10.0 1 05/28/1919:56 05/28/1919:56 67-64-1 ND ug/L 10.0 1.87 1 05/28/1919:56 05/28/1919:56 107-13-1 ND ug/L 1.00 0.331 1 05/28/1919:56 05/28/1919:56 71-43-2 ND ug/L 1.00 0.352 1 05/28/1919:56 05/28/1919:56 108-86-1 ND ug/L 5.00 0.520 1 05/28/1919:56 05/28/1919:56 74-97-5 ND ug/L 1.00 0.380 1 05/28/1919:56 05/28/1919:56 75-27-4 ND ug/L 1.00 0.469 1 05/28/1919:56 05/28/1919:56 75-25-2 ND ug/L 5.00 0.866 1 05/28/1919:56 05/28/1919:56 74-83-9 ND ug/L 1.00 0.379 1 05/28/1919:56 05/28/1919:56 56-23-5 ND ug/L 1.00 0.348 1 05/28/1919:56 05/28/1919:56 108-90-7 ND ug/L 1.00 0.327 1 05/28/1919:56 05/28/1919:56 124-48-1 ND ug/L 5.00 0.453 1 05/28/1919:56 05/28/1919:56 75-00-3 ND ug/L 5.00 0.324 1 05/28/1919:56 05/28/1919:56 67-66-3 ND ug/L 2.50 0.276 1 05/28/1919:56 05/28/1919:56 74-87-3 ND ug/L 1.00 0.375 1 05/28/1919:56 05/28/1919:56 95-49-8 ND ug/L 1.00 0.351 1 05/28/1919:56 05/28/1919:56 106-43-4 ND ug/L 5.00 1.33 1 05/28/1919:56 05/28/1919:56 96-12-8 ND ug/L 1.00 0.381 1 05/28/1919:56 05/28/1919:56 106-93-4 ND ug/L 1.00 0.346 1 05/28/1919:56 05/28/1919:56 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CC CC Page 13 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-11S Lab ID: 92429561003 Collected: 05/15/19 14:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 19:56 05/28/19 19:56 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 19:56 05/28/19 19:56 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 19:56 05/28/19 19:56 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 19:56 05/28/19 19:56 75-71-8 1,1-Dichloroethane 1.71 ug/L 1.00 0.259 1 05/28/19 19:56 05/28/19 19:56 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 19:56 05/28/19 19:56 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 19:56 05/28/19 19:56 75-35-4 cis-1,2-Dichloroethene 2.29 ug/L 1.00 0.260 1 05/28/19 19:56 05/28/19 19:56 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.00 0.396 1 05/28/19 19:56 05/28/19 19:56 156-60-5 1,2-Dichloropropane ND ug/L 1.00 0.306 1 05/28/19 19:56 05/28/19 19:56 78-87-5 1,1-Dichloropropene ND ug/L 1.00 0.352 1 05/28/19 19:56 05/28/19 19:56 563-58-6 1,3-Dichloropropane ND ug/L 1.00 0.366 1 05/28/19 19:56 05/28/19 19:56 142-28-9 cis-1,3-Dichloropropene ND ug/L 1.00 0.418 1 05/28/19 19:56 05/28/19 19:56 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.00 0.419 1 05/28/19 19:56 05/28/19 19:56 10061-02-6 2,2-Dichloropropane ND ug/L 1.00 0.321 1 05/28/19 19:56 05/28/19 19:56 594-20-7 Diisopropyl ether ND ug/L 1.00 0.320 1 05/28/19 19:56 05/28/19 19:56 108-20-3 Ethylbenzene ND ug/L 1.00 0.384 1 05/28/19 19:56 05/28/19 19:56 100-41-4 Hexachloro-1,3-butadiene ND ug/L 1.00 0.256 1 05/28/19 19:56 05/28/19 19:56 87-68-3 CC 2-Hexanone ND ug/L 10.0 3.82 1 05/28/19 19:56 05/28/19 19:56 591-78-6 p-Isopropyltoluene ND ug/L 1.00 0.350 1 05/28/19 19:56 05/28/19 19:56 99-87-6 2-Butanone (MEK) ND ug/L 10.0 3.93 1 05/28/19 19:56 05/28/19 19:56 78-93-3 Methylene Chloride ND ug/L 5.00 1.00 1 05/28/19 19:56 05/28/19 19:56 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 2.14 1 05/28/19 19:56 05/28/19 19:56 108-10-1 Methyl-tert-butyl ether ND ug/L 1.00 0.367 1 05/28/19 19:56 05/28/19 19:56 1634-04-4 Naphthalene ND ug/L 5.00 1.00 1 05/28/19 19:56 05/28/19 19:56 91-20-3 Styrene ND ug/L 1.00 0.307 1 05/28/19 19:56 05/28/19 19:56 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.00 0.385 1 05/28/19 19:56 05/28/19 19:56 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.00 0.130 1 05/28/19 19:56 05/28/19 19:56 79-34-5 Tetrachloroethene ND ug/L 1.00 0.372 1 05/28/19 19:56 05/28/19 19:56 127-18-4 Toluene ND ug/L 1.00 0.412 1 05/28/19 19:56 05/28/19 19:56 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.00 0.230 1 05/28/19 19:56 05/28/19 19:56 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.00 0.355 1 05/28/19 19:56 05/28/19 19:56 120-82-1 1,1,1-Trichloroethane ND ug/L 1.00 0.319 1 05/28/19 19:56 05/28/19 19:56 71-55-6 1,1,2-Trichloroethane ND ug/L 1.00 0.383 1 05/28/19 19:56 05/28/19 19:56 79-00-5 Trichloroethene ND ug/L 1.00 0.398 1 05/28/19 19:56 05/28/19 19:56 79-01-6 Trichlorofluoromethane ND ug/L 5.00 1.20 1 05/28/19 19:56 05/28/19 19:56 75-69-4 1,2,3-Trichloropropane ND ug/L 2.50 0.807 1 05/28/19 19:56 05/28/19 19:56 96-18-4 Vinyl acetate ND ug/L 10.0 1.63 1 05/28/19 19:56 05/28/19 19:56 108-05-4 Vinyl chloride ND ug/L 1.00 0.259 1 05/28/19 19:56 05/28/19 19:56 75-01-4 o-Xylene ND ug/L 1.00 0.341 1 05/28/19 19:56 05/28/19 19:56 95-47-6 m&p-Xylene ND ug/L 2.00 0.719 1 05/28/19 19:56 05/28/19 19:56 179601-23-1 Xylene (Total) ND ug/L 3.00 1.06 1 05/28/19 19:56 05/28/19 19:56 1330-20-7 1,4-Dioxane (p-Dioxane) ND ug/L 100 36.0 1 05/28/19 19:56 05/28/19 19:56 123-91-1 Surrogates Toluene-d8 (S) 91.5 % 80.0-120 1 05/28/19 19:56 05/28/19 19:56 2037-26-5 4-Bromofluorobenzene (S) 102 % 77.0-126 1 05/28/19 19:56 05/28/19 19:56 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-11S Lab ID: 92429561003 Collected: 05/15/19 14:20 Received: 05/16/19 09:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 86.2 % 70.0-130 1 05/28/19 19:56 05/28/19 19:56 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: LAGOON Lab ID: 92429561004 Collected: 05/16/19 05:20 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 7470 Mercury Mercury 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene Date: 07/05/2019 03:57 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A N D ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:21 7440-36-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:21 7440-38-2 253 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-39-3 ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:21 7440-41-7 N D ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:21 7440-43-9 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-47-3 21.4 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-48-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-50-8 ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7439-92-1 5.2 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-02-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:21 7782-49-2 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-22-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:21 7440-62-2 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 02:36 7440-28-0 Analytical Method: EPA 7470A Preparation Method: EPA 7470A 0.14J ug/L 0.20 0.10 1 05/20/19 11:51 05/28/19 09:38 7439-97-6 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1918:42 67-64-1 ND ug/L 10.0 0.90 1 05/23/1918:42 107-13-1 2.5 ug/L 1.0 0.15 1 05/23/1918:42 71-43-2 ND ug/L 1.0 0.34 1 05/23/1918:42 74-97-5 ND ug/L 1.0 0.26 1 05/23/1918:42 75-27-4 ND ug/L 1.0 0.62 1 05/23/1918:42 75-25-2 ND ug/L 2.0 0.62 1 05/23/1918:42 74-83-9 ND ug/L 5.0 3.3 1 05/23/1918:42 78-93-3 ND ug/L 2.0 0.40 1 05/23/1918:42 75-15-0 ND ug/L 1.0 0.22 1 05/23/1918:42 56-23-5 ND ug/L 1.0 0.23 1 05/23/1918:42 108-90-7 ND ug/L 1.0 0.49 1 05/23/1918:42 75-00-3 ND ug/L 5.0 2.3 1 05/23/1918:42 67-66-3 ND ug/L 1.0 0.39 1 05/23/1918:42 74-87-3 ND ug/L 5.0 0.26 1 05/23/1918:42 96-12-8 ND ug/L 1.0 0.41 1 05/23/1918:42 124-48-1 ND ug/L 1.0 0.26 1 05/23/1918:42 106-93-4 ND ug/L 1.0 0.46 1 05/23/1918:42 74-95-3 ND ug/L 1.0 0.29 1 05/23/1918:42 95-50-1 ND ug/L 1.0 0.26 1 05/23/1918:42 106-46-7 ND ug/L 1.0 0.54 1 05/23/1918:42 110-57-6 ND ug/L 1.0 0.27 1 05/23/1918:42 75-34-3 1.2 ug/L 1.0 0.34 1 05/23/1918:42 107-06-2 ND ug/L 1.0 0.24 1 05/23/1918:42 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: LAGOON Lab ID: 92429561004 Collected: 05/16/19 05:20 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) VOA (GC/MS) 8260D Acetone Acrylonitrile Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene Date: 07/05/2019 03:57 PM Analytical Method: EPA 8260D 1.3 ug/L 1.0 0.29 1 05/23/1918:42 156-59-2 1.6 ug/L 1.0 0.25 1 05/23/1918:42 156-60-5 0.54J ug/L 1.0 0.19 1 05/23/1918:42 78-87-5 ND ug/L 1.0 0.30 1 05/23/1918:42 10061-01-5 ND ug/L 1.0 0.31 1 05/23/1918:42 10061-02-6 ND ug/L 150 56.2 1 05/23/1918:42 123-91-1 0.33J ug/L 1.0 0.26 1 05/23/1918:42 100-41-4 ND ug/L 5.0 0.57 1 05/23/1918:42 591-78-6 ND ug/L 20.0 12.5 1 05/23/1918:42 74-88-4 ND ug/L 5.0 3.7 1 05/23/1918:42 75-09-2 ND ug/L 5.0 4.5 1 05/23/1918:42 108-10-1 ND ug/L 1.0 0.27 1 05/23/1918:42 100-42-5 ND ug/L 1.0 0.34 1 05/23/1918:42 630-20-6 ND ug/L 1.0 0.22 1 05/23/1918:42 79-34-5 ND ug/L 1.0 0.16 1 05/23/1918:42 127-18-4 ND ug/L 1.0 0.24 1 05/23/1918:42 108-88-3 ND ug/L 1.0 0.18 1 05/23/1918:42 71-55-6 ND ug/L 1.0 0.24 1 05/23/1918:42 79-00-5 ND ug/L 1.0 0.22 1 05/23/1918:42 79-01-6 ND ug/L 1.0 0.31 1 05/23/1918:42 75-69-4 ND ug/L 1.0 0.35 1 05/23/1918:42 96-18-4 ND ug/L 2.0 1.4 1 05/23/1918:42 108-05-4 ND ug/L 1.0 0.24 1 05/23/1918:42 75-01-4 ND ug/L 1.0 0.63 1 05/23/1918:42 1330-20-7 101 % 70-130 1 05/23/1918:42 460-00-4 112 % 70-130 1 05/23/1918:42 17060-07-0 102 % 70-130 1 05/23/1918:42 2037-26-5 Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 50.0 10.0 1 05/28/19 20:16 05/28/19 20:16 67-64-1 ND ug/L 10.0 1.87 1 05/28/19 20:16 05/28/19 20:16 107-13-1 ND ug/L 1.00 0.331 1 05/28/19 20:16 05/28/19 20:16 71-43-2 ND ug/L 1.00 0.352 1 05/28/19 20:16 05/28/19 20:16 108-86-1 ND ug/L 5.00 0.520 1 05/28/19 20:16 05/28/19 20:16 74-97-5 ND ug/L 1.00 0.380 1 05/28/19 20:16 05/28/19 20:16 75-27-4 ND ug/L 1.00 0.469 1 05/28/19 20:16 05/28/19 20:16 75-25-2 ND ug/L 5.00 0.866 1 05/28/19 20:16 05/28/19 20:16 74-83-9 ND ug/L 1.00 0.379 1 05/28/19 20:16 05/28/19 20:16 56-23-5 ND ug/L 1.00 0.348 1 05/28/19 20:16 05/28/19 20:16 108-90-7 ND ug/L 1.00 0.327 1 05/28/19 20:16 05/28/19 20:16 124-48-1 ND ug/L 5.00 0.453 1 05/28/19 20:16 05/28/19 20:16 75-00-3 ND ug/L 5.00 0.324 1 05/28/19 20:16 05/28/19 20:16 67-66-3 ND ug/L 2.50 0.276 1 05/28/19 20:16 05/28/19 20:16 74-87-3 ND ug/L 1.00 0.375 1 05/28/19 20:16 05/28/19 20:16 95-49-8 ND ug/L 1.00 0.351 1 05/28/19 20:16 05/28/19 20:16 106-43-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CC CC Page 17 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: LAGOON Lab ID: 92429561004 Collected: 05/16/19 05:20 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 20:16 05/28/19 20:16 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 20:16 05/28/19 20:16 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 20:16 05/28/19 20:16 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 20:16 05/28/19 20:16 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 20:16 05/28/19 20:16 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 20:16 05/28/19 20:16 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 20:16 05/28/19 20:16 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 20:16 05/28/19 20:16 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 20:16 05/28/19 20:16 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 20:16 05/28/19 20:16 75-35-4 cis-1,2-Dichloroethene 0.432J ug/L 1.00 0.260 1 05/28/19 20:16 05/28/19 20:16 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.00 0.396 1 05/28/19 20:16 05/28/19 20:16 156-60-5 1,2-Dichloropropane ND ug/L 1.00 0.306 1 05/28/19 20:16 05/28/19 20:16 78-87-5 1,1-Dichloropropene ND ug/L 1.00 0.352 1 05/28/19 20:16 05/28/19 20:16 563-58-6 1,3-Dichloropropane ND ug/L 1.00 0.366 1 05/28/19 20:16 05/28/19 20:16 142-28-9 cis-1,3-Dichloropropene ND ug/L 1.00 0.418 1 05/28/19 20:16 05/28/19 20:16 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.00 0.419 1 05/28/19 20:16 05/28/19 20:16 10061-02-6 2,2-Dichloropropane ND ug/L 1.00 0.321 1 05/28/19 20:16 05/28/19 20:16 594-20-7 Diisopropyl ether ND ug/L 1.00 0.320 1 05/28/19 20:16 05/28/19 20:16 108-20-3 Ethylbenzene ND ug/L 1.00 0.384 1 05/28/19 20:16 05/28/19 20:16 100-41-4 Hexachloro-1,3-butadiene ND ug/L 1.00 0.256 1 05/28/19 20:16 05/28/19 20:16 87-68-3 2-Hexanone ND ug/L 10.0 3.82 1 05/28/19 20:16 05/28/19 20:16 591-78-6 p-Isopropyltoluene ND ug/L 1.00 0.350 1 05/28/19 20:16 05/28/19 20:16 99-87-6 2-Butanone (MEK) ND ug/L 10.0 3.93 1 05/28/19 20:16 05/28/19 20:16 78-93-3 Methylene Chloride ND ug/L 5.00 1.00 1 05/28/19 20:16 05/28/19 20:16 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 2.14 1 05/28/19 20:16 05/28/19 20:16 108-10-1 Methyl-tert-butyl ether ND ug/L 1.00 0.367 1 05/28/19 20:16 05/28/19 20:16 1634-04-4 Naphthalene ND ug/L 5.00 1.00 1 05/28/19 20:16 05/28/19 20:16 91-20-3 Styrene ND ug/L 1.00 0.307 1 05/28/19 20:16 05/28/19 20:16 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.00 0.385 1 05/28/19 20:16 05/28/19 20:16 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.00 0.130 1 05/28/19 20:16 05/28/19 20:16 79-34-5 Tetrachloroethene ND ug/L 1.00 0.372 1 05/28/19 20:16 05/28/19 20:16 127-18-4 Toluene ND ug/L 1.00 0.412 1 05/28/19 20:16 05/28/19 20:16 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.00 0.230 1 05/28/19 20:16 05/28/19 20:16 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.00 0.355 1 05/28/19 20:16 05/28/19 20:16 120-82-1 1,1,1-Trichloroethane ND ug/L 1.00 0.319 1 05/28/19 20:16 05/28/19 20:16 71-55-6 1,1,2-Trichloroethane ND ug/L 1.00 0.383 1 05/28/19 20:16 05/28/19 20:16 79-00-5 Trichloroethene ND ug/L 1.00 0.398 1 05/28/19 20:16 05/28/19 20:16 79-01-6 Trichlorofluoromethane ND ug/L 5.00 1.20 1 05/28/19 20:16 05/28/19 20:16 75-69-4 1,2,3-Trichloropropane ND ug/L 2.50 0.807 1 05/28/19 20:16 05/28/19 20:16 96-18-4 Vinyl acetate ND ug/L 10.0 1.63 1 05/28/19 20:16 05/28/19 20:16 108-05-4 Vinyl chloride ND ug/L 1.00 0.259 1 05/28/19 20:16 05/28/19 20:16 75-01-4 o-Xylene ND ug/L 1.00 0.341 1 05/28/19 20:16 05/28/19 20:16 95-47-6 m&p-Xylene ND ug/L 2.00 0.719 1 05/28/19 20:16 05/28/19 20:16 179601-23-1 Xylene (Total) ND ug/L 3.00 1.06 1 05/28/19 20:16 05/28/19 20:16 1330-20-7 1,4-Dioxane (p-Dioxane) ND ug/L 100 36.0 1 05/28/19 20:16 05/28/19 20:16 123-91-1 REPORT OF LABORATORY ANALYSIS J CC This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: LAGOON Lab ID: 92429561004 Collected: 05/16/19 05:20 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates Toluene-d8 (S) 90.6 % 80.0-120 1 05/28/19 20:16 05/28/19 20:16 2037-26-5 4-Bromofluorobenzene (S) 100 % 77.0-126 1 05/28/19 20:16 05/28/19 20:16 460-00-4 1,2-Dichloroethane-d4 (S) 90.9 % 70.0-130 1 05/28/19 20:16 05/28/19 20:16 17060-07-0 5210B BOD, 5 day Analytical Method: SM 521 OB-2011 BOD, 5 day 174000 ug/L 2000 2000 1 05/18/19 00:14 05/22/19 23:46 B3,L1 9040 pH Analytical Method: EPA 9040C pH at 25 Degrees C 6.4 Std. Units 0.10 0.10 1 05/19/19 17:28 H3 300.0 IC Anions 28 Days Analytical Method: EPA 300.0 Rev 2.1 1993 Sulfate 2430 ug/L 1000 500 1 05/18/1915:50 14808-79-8 353.2 Nitrogen, NO2/NO3 unpres Analytical Method: EPA 353.2 Rev 2.0 1993 Nitrogen, Nitrate ND ug/L 40.0 10.0 1 05/18/19 02:03 14797-55-8 365.1 Phosphorus, Total Analytical Method: EPA 365.1 Rev 2.0 1993 Preparation Method: EPA 365.1 Rev 2.0 1993 Phosphorus ND ug/L 50.0 25.0 1 05/21/19 18:11 05/21/19 22:42 7723-14-0 5220D COD Analytical Method: SM 5220D-2011 Preparation Method: SM 5220D-2011 Chemical Oxygen Demand 147000 ug/L 25000 12500 1 05/20/19 16:36 05/20/19 20:43 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-8 Lab ID: 92429561005 Collected: 05/16/19 11:53 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A N D ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:33 7440-36-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:33 7440-38-2 96.3 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-39-3 ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:33 7440-41-7 0.63J ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:33 7440-43-9 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-47-3 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-48-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-50-8 ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7439-92-1 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-02-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:33 7782-49-2 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-22-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:33 7440-62-2 5.2J ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:33 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 03:22 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1918:59 67-64-1 ND ug/L 10.0 0.90 1 05/23/1918:59 107-13-1 ND ug/L 1.0 0.15 1 05/23/1918:59 71-43-2 ND ug/L 1.0 0.34 1 05/23/1918:59 74-97-5 ND ug/L 1.0 0.26 1 05/23/1918:59 75-27-4 ND ug/L 1.0 0.62 1 05/23/1918:59 75-25-2 ND ug/L 2.0 0.62 1 05/23/1918:59 74-83-9 ND ug/L 5.0 3.3 1 05/23/1918:59 78-93-3 ND ug/L 2.0 0.40 1 05/23/1918:59 75-15-0 ND ug/L 1.0 0.22 1 05/23/1918:59 56-23-5 ND ug/L 1.0 0.23 1 05/23/1918:59 108-90-7 ND ug/L 1.0 0.49 1 05/23/1918:59 75-00-3 ND ug/L 5.0 2.3 1 05/23/1918:59 67-66-3 ND ug/L 1.0 0.39 1 05/23/1918:59 74-87-3 ND ug/L 5.0 0.26 1 05/23/1918:59 96-12-8 ND ug/L 1.0 0.41 1 05/23/1918:59 124-48-1 ND ug/L 1.0 0.26 1 05/23/1918:59 106-93-4 ND ug/L 1.0 0.46 1 05/23/1918:59 74-95-3 ND ug/L 1.0 0.29 1 05/23/1918:59 95-50-1 ND ug/L 1.0 0.26 1 05/23/1918:59 106-46-7 ND ug/L 1.0 0.54 1 05/23/1918:59 110-57-6 ND ug/L 1.0 0.27 1 05/23/1918:59 75-34-3 ND ug/L 1.0 0.34 1 05/23/1918:59 107-06-2 ND ug/L 1.0 0.24 1 05/23/1918:59 75-35-4 ND ug/L 1.0 0.29 1 05/23/1918:59 156-59-2 ND ug/L 1.0 0.25 1 05/23/1918:59 156-60-5 ND ug/L 1.0 0.19 1 05/23/1918:59 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-8 Lab ID: 92429561005 Collected: 05/16/19 11:53 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) VOA (GC/MS) 8260D Acetone Acrylonitrile Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Dibromomethane Date: 07/05/2019 03:57 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 05/23/1918:59 10061-01-5 ND ug/L 1.0 0.31 1 05/23/1918:59 10061-02-6 ND ug/L 150 56.2 1 05/23/1918:59 123-91-1 ND ug/L 1.0 0.26 1 05/23/1918:59 100-41-4 ND ug/L 5.0 0.57 1 05/23/1918:59 591-78-6 ND ug/L 20.0 12.5 1 05/23/1918:59 74-88-4 ND ug/L 5.0 3.7 1 05/23/1918:59 75-09-2 ND ug/L 5.0 4.5 1 05/23/1918:59 108-10-1 ND ug/L 1.0 0.27 1 05/23/1918:59 100-42-5 ND ug/L 1.0 0.34 1 05/23/1918:59 630-20-6 ND ug/L 1.0 0.22 1 05/23/1918:59 79-34-5 ND ug/L 1.0 0.16 1 05/23/1918:59 127-18-4 ND ug/L 1.0 0.24 1 05/23/1918:59 108-88-3 ND ug/L 1.0 0.18 1 05/23/1918:59 71-55-6 ND ug/L 1.0 0.24 1 05/23/1918:59 79-00-5 ND ug/L 1.0 0.22 1 05/23/1918:59 79-01-6 ND ug/L 1.0 0.31 1 05/23/1918:59 75-69-4 ND ug/L 1.0 0.35 1 05/23/1918:59 96-18-4 ND ug/L 2.0 1.4 1 05/23/1918:59 108-05-4 ND ug/L 1.0 0.24 1 05/23/1918:59 75-01-4 ND ug/L 1.0 0.63 1 05/23/1918:59 1330-20-7 100 % 70-130 1 05/23/1918:59 460-00-4 116 % 70-130 1 05/23/1918:59 17060-07-0 103 % 70-130 1 05/23/1918:59 2037-26-5 Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 50.0 10.0 1 05/28/19 20:36 05/28/19 20:36 67-64-1 ND ug/L 10.0 1.87 1 05/28/19 20:36 05/28/19 20:36 107-13-1 ND ug/L 1.00 0.331 1 05/28/19 20:36 05/28/19 20:36 71-43-2 ND ug/L 1.00 0.352 1 05/28/19 20:36 05/28/19 20:36 108-86-1 ND ug/L 5.00 0.520 1 05/28/19 20:36 05/28/19 20:36 74-97-5 ND ug/L 1.00 0.380 1 05/28/19 20:36 05/28/19 20:36 75-27-4 ND ug/L 1.00 0.469 1 05/28/19 20:36 05/28/19 20:36 75-25-2 ND ug/L 5.00 0.866 1 05/28/19 20:36 05/28/19 20:36 74-83-9 ND ug/L 1.00 0.379 1 05/28/19 20:36 05/28/19 20:36 56-23-5 ND ug/L 1.00 0.348 1 05/28/19 20:36 05/28/19 20:36 108-90-7 ND ug/L 1.00 0.327 1 05/28/19 20:36 05/28/19 20:36 124-48-1 ND ug/L 5.00 0.453 1 05/28/19 20:36 05/28/19 20:36 75-00-3 ND ug/L 5.00 0.324 1 05/28/19 20:36 05/28/19 20:36 67-66-3 ND ug/L 2.50 0.276 1 05/28/19 20:36 05/28/19 20:36 74-87-3 ND ug/L 1.00 0.375 1 05/28/19 20:36 05/28/19 20:36 95-49-8 ND ug/L 1.00 0.351 1 05/28/19 20:36 05/28/19 20:36 106-43-4 ND ug/L 5.00 1.33 1 05/28/19 20:36 05/28/19 20:36 96-12-8 ND ug/L 1.00 0.381 1 05/28/19 20:36 05/28/19 20:36 106-93-4 ND ug/L 1.00 0.346 1 05/28/19 20:36 05/28/19 20:36 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CC CC Page 21 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-8 Lab ID: 92429561005 Collected: 05/16/19 11:53 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.349 1 05/28/19 20:36 05/28/19 20:36 95-50-1 ND ug/L 1.00 0.220 1 05/28/19 20:36 05/28/19 20:36 541-73-1 ND ug/L 1.00 0.274 1 05/28/19 20:36 05/28/19 20:36 106-46-7 ND ug/L 5.00 0.551 1 05/28/19 20:36 05/28/19 20:36 75-71-8 ND ug/L 1.00 0.259 1 05/28/19 20:36 05/28/19 20:36 75-34-3 ND ug/L 1.00 0.361 1 05/28/19 20:36 05/28/19 20:36 107-06-2 ND ug/L 1.00 0.398 1 05/28/19 20:36 05/28/19 20:36 75-35-4 ND ug/L 1.00 0.260 1 05/28/19 20:36 05/28/19 20:36 156-59-2 ND ug/L 1.00 0.396 1 05/28/19 20:36 05/28/19 20:36 156-60-5 ND ug/L 1.00 0.306 1 05/28/19 20:36 05/28/19 20:36 78-87-5 ND ug/L 1.00 0.352 1 05/28/19 20:36 05/28/19 20:36 563-58-6 ND ug/L 1.00 0.366 1 05/28/19 20:36 05/28/19 20:36 142-28-9 ND ug/L 1.00 0.418 1 05/28/19 20:36 05/28/19 20:36 10061-01-5 ND ug/L 1.00 0.419 1 05/28/19 20:36 05/28/19 20:36 10061-02-6 ND ug/L 1.00 0.321 1 05/28/19 20:36 05/28/19 20:36 594-20-7 ND ug/L 1.00 0.320 1 05/28/19 20:36 05/28/19 20:36 108-20-3 ND ug/L 1.00 0.384 1 05/28/19 20:36 05/28/19 20:36 100-41-4 ND ug/L 1.00 0.256 1 05/28/19 20:36 05/28/19 20:36 87-68-3 ND ug/L 10.0 3.82 1 05/28/19 20:36 05/28/19 20:36 591-78-6 ND ug/L 1.00 0.350 1 05/28/19 20:36 05/28/19 20:36 99-87-6 ND ug/L 10.0 3.93 1 05/28/19 20:36 05/28/19 20:36 78-93-3 ND ug/L 5.00 1.00 1 05/28/19 20:36 05/28/19 20:36 75-09-2 ND ug/L 10.0 2.14 1 05/28/19 20:36 05/28/19 20:36 108-10-1 ND ug/L 1.00 0.367 1 05/28/19 20:36 05/28/19 20:36 1634-04-4 ND ug/L 5.00 1.00 1 05/28/19 20:36 05/28/19 20:36 91-20-3 ND ug/L 1.00 0.307 1 05/28/19 20:36 05/28/19 20:36 100-42-5 ND ug/L 1.00 0.385 1 05/28/19 20:36 05/28/19 20:36 630-20-6 ND ug/L 1.00 0.130 1 05/28/19 20:36 05/28/19 20:36 79-34-5 ND ug/L 1.00 0.372 1 05/28/19 20:36 05/28/19 20:36 127-18-4 0.842J ug/L 1.00 0.412 1 05/28/19 20:36 05/28/19 20:36 108-88-3 ND ug/L 1.00 0.230 1 05/28/19 20:36 05/28/19 20:36 87-61-6 ND ug/L 1.00 0.355 1 05/28/19 20:36 05/28/19 20:36 120-82-1 ND ug/L 1.00 0.319 1 05/28/19 20:36 05/28/19 20:36 71-55-6 ND ug/L 1.00 0.383 1 05/28/19 20:36 05/28/19 20:36 79-00-5 ND ug/L 1.00 0.398 1 05/28/19 20:36 05/28/19 20:36 79-01-6 ND ug/L 5.00 1.20 1 05/28/19 20:36 05/28/19 20:36 75-69-4 ND ug/L 2.50 0.807 1 05/28/19 20:36 05/28/19 20:36 96-18-4 ND ug/L 10.0 1.63 1 05/28/19 20:36 05/28/19 20:36 108-05-4 ND ug/L 1.00 0.259 1 05/28/19 20:36 05/28/19 20:36 75-01-4 ND ug/L 1.00 0.341 1 05/28/19 20:36 05/28/19 20:36 95-47-6 ND ug/L 2.00 0.719 1 05/28/19 20:36 05/28/19 20:36 179601-23-1 ND ug/L 3.00 1.06 1 05/28/19 20:36 05/28/19 20:36 1330-20-7 ND ug/L 100 36.0 1 05/28/19 20:36 05/28/19 20:36 123-91-1 92.2 % 80.0-120 1 05/28/19 20:36 05/28/19 20:36 2037-26-5 101 % 77.0-126 1 05/28/19 20:36 05/28/19 20:36 460-00-4 REPORT OF LABORATORY ANALYSIS CC J This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-8 Lab ID: 92429561005 Collected: 05/16/19 11:53 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 92.7 % 70.0-130 1 05/28/19 20:36 05/28/19 20:36 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-9S Lab ID: 92429561006 Collected: 05/16/19 11:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A N D ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:36 7440-36-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:36 7440-38-2 104 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-39-3 ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:36 7440-41-7 N D ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:36 7440-43-9 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-47-3 119 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-48-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-50-8 ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7439-92-1 8.0 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-02-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:36 7782-49-2 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-22-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:36 7440-62-2 8.7J ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:36 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.35 ug/L 0.10 0.060 1 06/01 /19 01:19 06/06/19 03:26 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1919:17 67-64-1 ND ug/L 10.0 0.90 1 05/23/1919:17 107-13-1 0.96J ug/L 1.0 0.15 1 05/23/1919:17 71-43-2 ND ug/L 1.0 0.34 1 05/23/1919:17 74-97-5 ND ug/L 1.0 0.26 1 05/23/1919:17 75-27-4 ND ug/L 1.0 0.62 1 05/23/1919:17 75-25-2 ND ug/L 2.0 0.62 1 05/23/1919:17 74-83-9 ND ug/L 5.0 3.3 1 05/23/1919:17 78-93-3 ND ug/L 2.0 0.40 1 05/23/1919:17 75-15-0 ND ug/L 1.0 0.22 1 05/23/1919:17 56-23-5 ND ug/L 1.0 0.23 1 05/23/1919:17 108-90-7 ND ug/L 1.0 0.49 1 05/23/1919:17 75-00-3 ND ug/L 5.0 2.3 1 05/23/1919:17 67-66-3 ND ug/L 1.0 0.39 1 05/23/1919:17 74-87-3 ND ug/L 5.0 0.26 1 05/23/1919:17 96-12-8 ND ug/L 1.0 0.41 1 05/23/1919:17 124-48-1 ND ug/L 1.0 0.26 1 05/23/1919:17 106-93-4 ND ug/L 1.0 0.46 1 05/23/1919:17 74-95-3 ND ug/L 1.0 0.29 1 05/23/1919:17 95-50-1 ND ug/L 1.0 0.26 1 05/23/1919:17 106-46-7 ND ug/L 1.0 0.54 1 05/23/1919:17 110-57-6 ND ug/L 1.0 0.27 1 05/23/1919:17 75-34-3 ND ug/L 1.0 0.34 1 05/23/1919:17 107-06-2 ND ug/L 1.0 0.24 1 05/23/1919:17 75-35-4 6.8 ug/L 1.0 0.29 1 05/23/1919:17 156-59-2 0.96J ug/L 1.0 0.25 1 05/23/1919:17 156-60-5 ND ug/L 1.0 0.19 1 05/23/1919:17 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-9S Lab ID: 92429561006 Collected: 05/16/19 11:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D cis-1,3-Dichloropropene ND ug/L 1.0 0.30 1 05/23/19 19:17 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.31 1 05/23/19 19:17 10061-02-6 1,4-Dioxane (p-Dioxane) ND ug/L 150 56.2 1 05/23/19 19:17 123-91-1 Ethylbenzene ND ug/L 1.0 0.26 1 05/23/19 19:17 100-41-4 2-Hexanone ND ug/L 5.0 0.57 1 05/23/19 19:17 591-78-6 lodomethane ND ug/L 20.0 12.5 1 05/23/19 19:17 74-88-4 Methylene Chloride ND ug/L 5.0 3.7 1 05/23/19 19:17 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 4.5 1 05/23/19 19:17 108-10-1 Styrene ND ug/L 1.0 0.27 1 05/23/19 19:17 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.34 1 05/23/19 19:17 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.22 1 05/23/19 19:17 79-34-5 Tetrachloroethene ND ug/L 1.0 0.16 1 05/23/19 19:17 127-18-4 Toluene ND ug/L 1.0 0.24 1 05/23/19 19:17 108-88-3 1,1,1-Trichloroethane ND ug/L 1.0 0.18 1 05/23/19 19:17 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 0.24 1 05/23/19 19:17 79-00-5 Trichloroethene 0.63J ug/L 1.0 0.22 1 05/23/19 19:17 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.31 1 05/23/19 19:17 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 0.35 1 05/23/19 19:17 96-18-4 Vinyl acetate ND ug/L 2.0 1.4 1 05/23/19 19:17 108-05-4 Vinyl chloride ND ug/L 1.0 0.24 1 05/23/19 19:17 75-01-4 Xylene (Total) ND ug/L 1.0 0.63 1 05/23/19 19:17 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 101 % 70-130 1 05/23/19 19:17 460-00-4 1,2-Dichloroethane-d4 (S) 116 % 70-130 1 05/23/19 19:17 17060-07-0 Toluene-d8 (S) 102 % 70-130 1 05/23/19 19:17 2037-26-5 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 20:56 05/28/19 20:56 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 20:56 05/28/19 20:56 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 20:56 05/28/19 20:56 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 20:56 05/28/19 20:56 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 20:56 05/28/19 20:56 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 20:56 05/28/19 20:56 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 20:56 05/28/19 20:56 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 20:56 05/28/19 20:56 74-83-9 Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 20:56 05/28/19 20:56 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 20:56 05/28/19 20:56 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 20:56 05/28/19 20:56 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 20:56 05/28/19 20:56 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 20:56 05/28/19 20:56 67-66-3 Chloromethane 0.277 ug/L 2.50 0.276 1 05/28/19 20:56 05/28/19 20:56 74-87-3 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 20:56 05/28/19 20:56 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 20:56 05/28/19 20:56 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 20:56 05/28/19 20:56 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 20:56 05/28/19 20:56 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 20:56 05/28/19 20:56 74-95-3 REPORT OF LABORATORY ANALYSIS CC CC,J This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-9S Lab ID: 92429561006 Collected: 05/16/19 11:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 20:56 05/28/19 20:56 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 20:56 05/28/19 20:56 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 20:56 05/28/19 20:56 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 20:56 05/28/19 20:56 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 20:56 05/28/19 20:56 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 20:56 05/28/19 20:56 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 20:56 05/28/19 20:56 75-35-4 cis-1,2-Dichloroethene 1.44 ug/L 1.00 0.260 1 05/28/19 20:56 05/28/19 20:56 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.00 0.396 1 05/28/19 20:56 05/28/19 20:56 156-60-5 1,2-Dichloropropane ND ug/L 1.00 0.306 1 05/28/19 20:56 05/28/19 20:56 78-87-5 1,1-Dichloropropene ND ug/L 1.00 0.352 1 05/28/19 20:56 05/28/19 20:56 563-58-6 1,3-Dichloropropane ND ug/L 1.00 0.366 1 05/28/19 20:56 05/28/19 20:56 142-28-9 cis-1,3-Dichloropropene ND ug/L 1.00 0.418 1 05/28/19 20:56 05/28/19 20:56 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.00 0.419 1 05/28/19 20:56 05/28/19 20:56 10061-02-6 2,2-Dichloropropane ND ug/L 1.00 0.321 1 05/28/19 20:56 05/28/19 20:56 594-20-7 Diisopropyl ether ND ug/L 1.00 0.320 1 05/28/19 20:56 05/28/19 20:56 108-20-3 Ethylbenzene ND ug/L 1.00 0.384 1 05/28/19 20:56 05/28/19 20:56 100-41-4 Hexachloro-1,3-butadiene ND ug/L 1.00 0.256 1 05/28/19 20:56 05/28/19 20:56 87-68-3 CC 2-Hexanone ND ug/L 10.0 3.82 1 05/28/19 20:56 05/28/19 20:56 591-78-6 p-Isopropyltoluene ND ug/L 1.00 0.350 1 05/28/19 20:56 05/28/19 20:56 99-87-6 2-Butanone (MEK) ND ug/L 10.0 3.93 1 05/28/19 20:56 05/28/19 20:56 78-93-3 Methylene Chloride ND ug/L 5.00 1.00 1 05/28/19 20:56 05/28/19 20:56 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 2.14 1 05/28/19 20:56 05/28/19 20:56 108-10-1 Methyl-tert-butyl ether ND ug/L 1.00 0.367 1 05/28/19 20:56 05/28/19 20:56 1634-04-4 Naphthalene ND ug/L 5.00 1.00 1 05/28/19 20:56 05/28/19 20:56 91-20-3 Styrene ND ug/L 1.00 0.307 1 05/28/19 20:56 05/28/19 20:56 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.00 0.385 1 05/28/19 20:56 05/28/19 20:56 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.00 0.130 1 05/28/19 20:56 05/28/19 20:56 79-34-5 Tetrachloroethene ND ug/L 1.00 0.372 1 05/28/19 20:56 05/28/19 20:56 127-18-4 Toluene ND ug/L 1.00 0.412 1 05/28/19 20:56 05/28/19 20:56 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.00 0.230 1 05/28/19 20:56 05/28/19 20:56 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.00 0.355 1 05/28/19 20:56 05/28/19 20:56 120-82-1 1,1,1-Trichloroethane ND ug/L 1.00 0.319 1 05/28/19 20:56 05/28/19 20:56 71-55-6 1,1,2-Trichloroethane ND ug/L 1.00 0.383 1 05/28/19 20:56 05/28/19 20:56 79-00-5 Trichloroethene ND ug/L 1.00 0.398 1 05/28/19 20:56 05/28/19 20:56 79-01-6 Trichlorofluoromethane ND ug/L 5.00 1.20 1 05/28/19 20:56 05/28/19 20:56 75-69-4 1,2,3-Trichloropropane ND ug/L 2.50 0.807 1 05/28/19 20:56 05/28/19 20:56 96-18-4 Vinyl acetate ND ug/L 10.0 1.63 1 05/28/19 20:56 05/28/19 20:56 108-05-4 Vinyl chloride ND ug/L 1.00 0.259 1 05/28/19 20:56 05/28/19 20:56 75-01-4 o-Xylene ND ug/L 1.00 0.341 1 05/28/19 20:56 05/28/19 20:56 95-47-6 m&p-Xylene ND ug/L 2.00 0.719 1 05/28/19 20:56 05/28/19 20:56 179601-23-1 Xylene (Total) ND ug/L 3.00 1.06 1 05/28/19 20:56 05/28/19 20:56 1330-20-7 1,4-Dioxane (p-Dioxane) ND ug/L 100 36.0 1 05/28/19 20:56 05/28/19 20:56 123-91-1 Surrogates Toluene-d8 (S) 89.1 % 80.0-120 1 05/28/19 20:56 05/28/19 20:56 2037-26-5 4-Bromofluorobenzene (S) 99.3 % 77.0-126 1 05/28/19 20:56 05/28/19 20:56 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-9S Lab ID: 92429561006 Collected: 05/16/19 11:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 89.3 % 70.0-130 1 05/28/19 20:56 05/28/19 20:56 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-10 Lab ID: 92429561007 Collected: 05/16/19 09:40 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A N D ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:39 7440-36-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:39 7440-38-2 27.9 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-39-3 ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:39 7440-41-7 0.72J ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:39 7440-43-9 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-47-3 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-48-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-50-8 ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7439-92-1 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-02-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:39 7782-49-2 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-22-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:39 7440-62-2 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:39 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 03:44 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1919:34 67-64-1 ND ug/L 10.0 0.90 1 05/23/1919:34 107-13-1 1.0 ug/L 1.0 0.15 1 05/23/1919:34 71-43-2 ND ug/L 1.0 0.34 1 05/23/1919:34 74-97-5 ND ug/L 1.0 0.26 1 05/23/1919:34 75-27-4 ND ug/L 1.0 0.62 1 05/23/1919:34 75-25-2 ND ug/L 2.0 0.62 1 05/23/1919:34 74-83-9 ND ug/L 5.0 3.3 1 05/23/1919:34 78-93-3 ND ug/L 2.0 0.40 1 05/23/1919:34 75-15-0 ND ug/L 1.0 0.22 1 05/23/1919:34 56-23-5 ND ug/L 1.0 0.23 1 05/23/1919:34 108-90-7 ND ug/L 1.0 0.49 1 05/23/1919:34 75-00-3 ND ug/L 5.0 2.3 1 05/23/1919:34 67-66-3 ND ug/L 1.0 0.39 1 05/23/1919:34 74-87-3 ND ug/L 5.0 0.26 1 05/23/1919:34 96-12-8 ND ug/L 1.0 0.41 1 05/23/1919:34 124-48-1 ND ug/L 1.0 0.26 1 05/23/1919:34 106-93-4 ND ug/L 1.0 0.46 1 05/23/1919:34 74-95-3 ND ug/L 1.0 0.29 1 05/23/1919:34 95-50-1 ND ug/L 1.0 0.26 1 05/23/1919:34 106-46-7 ND ug/L 1.0 0.54 1 05/23/1919:34 110-57-6 ND ug/L 1.0 0.27 1 05/23/1919:34 75-34-3 0.63J ug/L 1.0 0.34 1 05/23/1919:34 107-06-2 ND ug/L 1.0 0.24 1 05/23/1919:34 75-35-4 1.8 ug/L 1.0 0.29 1 05/23/1919:34 156-59-2 ND ug/L 1.0 0.25 1 05/23/1919:34 156-60-5 ND ug/L 1.0 0.19 1 05/23/1919:34 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 28 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-10 Lab ID: 92429561007 Collected: 05/16/19 09:40 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) VOA (GC/MS) 8260D Acetone Acrylonitrile Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Dibromomethane Date: 07/05/2019 03:57 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 05/23/1919:34 10061-01-5 ND ug/L 1.0 0.31 1 05/23/1919:34 10061-02-6 ND ug/L 150 56.2 1 05/23/1919:34 123-91-1 ND ug/L 1.0 0.26 1 05/23/1919:34 100-41-4 ND ug/L 5.0 0.57 1 05/23/1919:34 591-78-6 ND ug/L 20.0 12.5 1 05/23/1919:34 74-88-4 ND ug/L 5.0 3.7 1 05/23/1919:34 75-09-2 ND ug/L 5.0 4.5 1 05/23/1919:34 108-10-1 ND ug/L 1.0 0.27 1 05/23/1919:34 100-42-5 ND ug/L 1.0 0.34 1 05/23/1919:34 630-20-6 ND ug/L 1.0 0.22 1 05/23/1919:34 79-34-5 ND ug/L 1.0 0.16 1 05/23/1919:34 127-18-4 ND ug/L 1.0 0.24 1 05/23/1919:34 108-88-3 ND ug/L 1.0 0.18 1 05/23/1919:34 71-55-6 ND ug/L 1.0 0.24 1 05/23/1919:34 79-00-5 ND ug/L 1.0 0.22 1 05/23/1919:34 79-01-6 ND ug/L 1.0 0.31 1 05/23/1919:34 75-69-4 ND ug/L 1.0 0.35 1 05/23/1919:34 96-18-4 ND ug/L 2.0 1.4 1 05/23/1919:34 108-05-4 ND ug/L 1.0 0.24 1 05/23/1919:34 75-01-4 ND ug/L 1.0 0.63 1 05/23/1919:34 1330-20-7 100 % 70-130 1 05/23/1919:34 460-00-4 115 % 70-130 1 05/23/1919:34 17060-07-0 103 % 70-130 1 05/23/1919:34 2037-26-5 Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 50.0 10.0 1 05/28/19 21:16 05/28/19 21:16 67-64-1 ND ug/L 10.0 1.87 1 05/28/19 21:16 05/28/19 21:16 107-13-1 ND ug/L 1.00 0.331 1 05/28/19 21:16 05/28/19 21:16 71-43-2 ND ug/L 1.00 0.352 1 05/28/19 21:16 05/28/19 21:16 108-86-1 ND ug/L 5.00 0.520 1 05/28/19 21:16 05/28/19 21:16 74-97-5 ND ug/L 1.00 0.380 1 05/28/19 21:16 05/28/19 21:16 75-27-4 ND ug/L 1.00 0.469 1 05/28/19 21:16 05/28/19 21:16 75-25-2 ND ug/L 5.00 0.866 1 05/28/19 21:16 05/28/19 21:16 74-83-9 ND ug/L 1.00 0.379 1 05/28/19 21:16 05/28/19 21:16 56-23-5 ND ug/L 1.00 0.348 1 05/28/19 21:16 05/28/19 21:16 108-90-7 ND ug/L 1.00 0.327 1 05/28/19 21:16 05/28/19 21:16 124-48-1 ND ug/L 5.00 0.453 1 05/28/19 21:16 05/28/19 21:16 75-00-3 ND ug/L 5.00 0.324 1 05/28/19 21:16 05/28/19 21:16 67-66-3 ND ug/L 2.50 0.276 1 05/28/19 21:16 05/28/19 21:16 74-87-3 ND ug/L 1.00 0.375 1 05/28/19 21:16 05/28/19 21:16 95-49-8 ND ug/L 1.00 0.351 1 05/28/19 21:16 05/28/19 21:16 106-43-4 ND ug/L 5.00 1.33 1 05/28/19 21:16 05/28/19 21:16 96-12-8 ND ug/L 1.00 0.381 1 05/28/19 21:16 05/28/19 21:16 106-93-4 ND ug/L 1.00 0.346 1 05/28/19 21:16 05/28/19 21:16 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CC CC Page 29 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-10 Lab ID: 92429561007 Collected: 05/16/19 09:40 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.349 1 05/28/19 21:16 05/28/19 21:16 95-50-1 ND ug/L 1.00 0.220 1 05/28/19 21:16 05/28/19 21:16 541-73-1 ND ug/L 1.00 0.274 1 05/28/19 21:16 05/28/19 21:16 106-46-7 ND ug/L 5.00 0.551 1 05/28/19 21:16 05/28/19 21:16 75-71-8 ND ug/L 1.00 0.259 1 05/28/19 21:16 05/28/19 21:16 75-34-3 ND ug/L 1.00 0.361 1 05/28/19 21:16 05/28/19 21:16 107-06-2 ND ug/L 1.00 0.398 1 05/28/19 21:16 05/28/19 21:16 75-35-4 ND ug/L 1.00 0.260 1 05/28/19 21:16 05/28/19 21:16 156-59-2 ND ug/L 1.00 0.396 1 05/28/19 21:16 05/28/19 21:16 156-60-5 ND ug/L 1.00 0.306 1 05/28/19 21:16 05/28/19 21:16 78-87-5 ND ug/L 1.00 0.352 1 05/28/19 21:16 05/28/19 21:16 563-58-6 ND ug/L 1.00 0.366 1 05/28/19 21:16 05/28/19 21:16 142-28-9 ND ug/L 1.00 0.418 1 05/28/19 21:16 05/28/19 21:16 10061-01-5 ND ug/L 1.00 0.419 1 05/28/19 21:16 05/28/19 21:16 10061-02-6 ND ug/L 1.00 0.321 1 05/28/19 21:16 05/28/19 21:16 594-20-7 ND ug/L 1.00 0.320 1 05/28/19 21:16 05/28/19 21:16 108-20-3 ND ug/L 1.00 0.384 1 05/28/19 21:16 05/28/19 21:16 100-41-4 ND ug/L 1.00 0.256 1 05/28/19 21:16 05/28/19 21:16 87-68-3 ND ug/L 10.0 3.82 1 05/28/19 21:16 05/28/19 21:16 591-78-6 ND ug/L 1.00 0.350 1 05/28/19 21:16 05/28/19 21:16 99-87-6 ND ug/L 10.0 3.93 1 05/28/19 21:16 05/28/19 21:16 78-93-3 ND ug/L 5.00 1.00 1 05/28/19 21:16 05/28/19 21:16 75-09-2 ND ug/L 10.0 2.14 1 05/28/19 21:16 05/28/19 21:16 108-10-1 ND ug/L 1.00 0.367 1 05/28/19 21:16 05/28/19 21:16 1634-04-4 ND ug/L 5.00 1.00 1 05/28/19 21:16 05/28/19 21:16 91-20-3 ND ug/L 1.00 0.307 1 05/28/19 21:16 05/28/19 21:16 100-42-5 ND ug/L 1.00 0.385 1 05/28/19 21:16 05/28/19 21:16 630-20-6 ND ug/L 1.00 0.130 1 05/28/19 21:16 05/28/19 21:16 79-34-5 ND ug/L 1.00 0.372 1 05/28/19 21:16 05/28/19 21:16 127-18-4 ND ug/L 1.00 0.412 1 05/28/19 21:16 05/28/19 21:16 108-88-3 ND ug/L 1.00 0.230 1 05/28/19 21:16 05/28/19 21:16 87-61-6 ND ug/L 1.00 0.355 1 05/28/19 21:16 05/28/19 21:16 120-82-1 ND ug/L 1.00 0.319 1 05/28/19 21:16 05/28/19 21:16 71-55-6 ND ug/L 1.00 0.383 1 05/28/19 21:16 05/28/19 21:16 79-00-5 ND ug/L 1.00 0.398 1 05/28/19 21:16 05/28/19 21:16 79-01-6 ND ug/L 5.00 1.20 1 05/28/19 21:16 05/28/19 21:16 75-69-4 ND ug/L 2.50 0.807 1 05/28/19 21:16 05/28/19 21:16 96-18-4 ND ug/L 10.0 1.63 1 05/28/19 21:16 05/28/19 21:16 108-05-4 0.821J ug/L 1.00 0.259 1 05/28/19 21:16 05/28/19 21:16 75-01-4 ND ug/L 1.00 0.341 1 05/28/19 21:16 05/28/19 21:16 95-47-6 ND ug/L 2.00 0.719 1 05/28/19 21:16 05/28/19 21:16 179601-23-1 ND ug/L 3.00 1.06 1 05/28/19 21:16 05/28/19 21:16 1330-20-7 ND ug/L 100 36.0 1 05/28/19 21:16 05/28/19 21:16 123-91-1 92.3 % 80.0-120 1 05/28/19 21:16 05/28/19 21:16 2037-26-5 104 % 77.0-126 1 05/28/19 21:16 05/28/19 21:16 460-00-4 REPORT OF LABORATORY ANALYSIS CC J This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-10 Lab ID: 92429561007 Collected: 05/16/19 09:40 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 89.7 % 70.0-130 1 05/28/19 21:16 05/28/19 21:16 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 31 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-12 Lab ID: 92429561008 Collected: 05/16/19 09:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Low Level Landfill Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane 2-Butanone (MEK) Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,4-Dichlorobenzene trans-1,4-Dichloro-2-butene 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane Date: 07/05/2019 03:57 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A N D ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:42 7440-36-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:42 7440-38-2 8.6 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-39-3 ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:42 7440-41-7 0.72J ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:42 7440-43-9 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-47-3 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-48-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-50-8 2.5J ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7439-92-1 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-02-0 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:42 7782-49-2 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-22-4 N D ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:42 7440-62-2 N D ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:42 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 03:47 7440-28-0 Analytical Method: EPA 8260D ND ug/L 25.0 6.2 1 05/23/1919:51 67-64-1 ND ug/L 10.0 0.90 1 05/23/1919:51 107-13-1 ND ug/L 1.0 0.15 1 05/23/1919:51 71-43-2 ND ug/L 1.0 0.34 1 05/23/1919:51 74-97-5 ND ug/L 1.0 0.26 1 05/23/1919:51 75-27-4 ND ug/L 1.0 0.62 1 05/23/1919:51 75-25-2 ND ug/L 2.0 0.62 1 05/23/1919:51 74-83-9 ND ug/L 5.0 3.3 1 05/23/1919:51 78-93-3 ND ug/L 2.0 0.40 1 05/23/1919:51 75-15-0 ND ug/L 1.0 0.22 1 05/23/1919:51 56-23-5 ND ug/L 1.0 0.23 1 05/23/1919:51 108-90-7 ND ug/L 1.0 0.49 1 05/23/1919:51 75-00-3 ND ug/L 5.0 2.3 1 05/23/1919:51 67-66-3 ND ug/L 1.0 0.39 1 05/23/1919:51 74-87-3 ND ug/L 5.0 0.26 1 05/23/1919:51 96-12-8 ND ug/L 1.0 0.41 1 05/23/1919:51 124-48-1 ND ug/L 1.0 0.26 1 05/23/1919:51 106-93-4 ND ug/L 1.0 0.46 1 05/23/1919:51 74-95-3 ND ug/L 1.0 0.29 1 05/23/1919:51 95-50-1 ND ug/L 1.0 0.26 1 05/23/1919:51 106-46-7 ND ug/L 1.0 0.54 1 05/23/1919:51 110-57-6 ND ug/L 1.0 0.27 1 05/23/1919:51 75-34-3 ND ug/L 1.0 0.34 1 05/23/1919:51 107-06-2 ND ug/L 1.0 0.24 1 05/23/1919:51 75-35-4 ND ug/L 1.0 0.29 1 05/23/1919:51 156-59-2 ND ug/L 1.0 0.25 1 05/23/1919:51 156-60-5 ND ug/L 1.0 0.19 1 05/23/1919:51 78-87-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-12 Lab ID: 92429561008 Collected: 05/16/19 09:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 1,4-Dioxane (p-Dioxane) Ethylbenzene 2-Hexanone lodomethane Methylene Chloride 4-Methyl-2-pentanone (MIBK) Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride Xylene (Total) Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) VOA (GC/MS) 8260D Acetone Acrylonitrile Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon tetrachloride Chlorobenzene Dibromochloromethane Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) Dibromomethane Date: 07/05/2019 03:57 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.30 1 05/23/1919:51 10061-01-5 ND ug/L 1.0 0.31 1 05/23/1919:51 10061-02-6 ND ug/L 150 56.2 1 05/23/1919:51 123-91-1 ND ug/L 1.0 0.26 1 05/23/1919:51 100-41-4 ND ug/L 5.0 0.57 1 05/23/1919:51 591-78-6 ND ug/L 20.0 12.5 1 05/23/1919:51 74-88-4 ND ug/L 5.0 3.7 1 05/23/1919:51 75-09-2 ND ug/L 5.0 4.5 1 05/23/1919:51 108-10-1 ND ug/L 1.0 0.27 1 05/23/1919:51 100-42-5 ND ug/L 1.0 0.34 1 05/23/1919:51 630-20-6 ND ug/L 1.0 0.22 1 05/23/1919:51 79-34-5 ND ug/L 1.0 0.16 1 05/23/1919:51 127-18-4 ND ug/L 1.0 0.24 1 05/23/1919:51 108-88-3 ND ug/L 1.0 0.18 1 05/23/1919:51 71-55-6 ND ug/L 1.0 0.24 1 05/23/1919:51 79-00-5 ND ug/L 1.0 0.22 1 05/23/1919:51 79-01-6 ND ug/L 1.0 0.31 1 05/23/1919:51 75-69-4 ND ug/L 1.0 0.35 1 05/23/1919:51 96-18-4 ND ug/L 2.0 1.4 1 05/23/1919:51 108-05-4 ND ug/L 1.0 0.24 1 05/23/1919:51 75-01-4 ND ug/L 1.0 0.63 1 05/23/1919:51 1330-20-7 100 % 70-130 1 05/23/1919:51 460-00-4 116 % 70-130 1 05/23/1919:51 17060-07-0 104 % 70-130 1 05/23/1919:51 2037-26-5 Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 50.0 10.0 1 05/28/19 21:36 05/28/19 21:36 67-64-1 ND ug/L 10.0 1.87 1 05/28/19 21:36 05/28/19 21:36 107-13-1 ND ug/L 1.00 0.331 1 05/28/19 21:36 05/28/19 21:36 71-43-2 ND ug/L 1.00 0.352 1 05/28/19 21:36 05/28/19 21:36 108-86-1 ND ug/L 5.00 0.520 1 05/28/19 21:36 05/28/19 21:36 74-97-5 ND ug/L 1.00 0.380 1 05/28/19 21:36 05/28/19 21:36 75-27-4 ND ug/L 1.00 0.469 1 05/28/19 21:36 05/28/19 21:36 75-25-2 ND ug/L 5.00 0.866 1 05/28/19 21:36 05/28/19 21:36 74-83-9 ND ug/L 1.00 0.379 1 05/28/19 21:36 05/28/19 21:36 56-23-5 ND ug/L 1.00 0.348 1 05/28/19 21:36 05/28/19 21:36 108-90-7 ND ug/L 1.00 0.327 1 05/28/19 21:36 05/28/19 21:36 124-48-1 ND ug/L 5.00 0.453 1 05/28/19 21:36 05/28/19 21:36 75-00-3 ND ug/L 5.00 0.324 1 05/28/19 21:36 05/28/19 21:36 67-66-3 ND ug/L 2.50 0.276 1 05/28/19 21:36 05/28/19 21:36 74-87-3 ND ug/L 1.00 0.375 1 05/28/19 21:36 05/28/19 21:36 95-49-8 ND ug/L 1.00 0.351 1 05/28/19 21:36 05/28/19 21:36 106-43-4 ND ug/L 5.00 1.33 1 05/28/19 21:36 05/28/19 21:36 96-12-8 ND ug/L 1.00 0.381 1 05/28/19 21:36 05/28/19 21:36 106-93-4 ND ug/L 1.00 0.346 1 05/28/19 21:36 05/28/19 21:36 74-95-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. CC CC Page 33 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-12 Lab ID: 92429561008 Collected: 05/16/19 09:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 21:36 05/28/19 21:36 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 21:36 05/28/19 21:36 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 21:36 05/28/19 21:36 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 21:36 05/28/19 21:36 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 21:36 05/28/19 21:36 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 21:36 05/28/19 21:36 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 21:36 05/28/19 21:36 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 21:36 05/28/19 21:36 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.00 0.396 1 05/28/19 21:36 05/28/19 21:36 156-60-5 1,2-Dichloropropane ND ug/L 1.00 0.306 1 05/28/19 21:36 05/28/19 21:36 78-87-5 1,1-Dichloropropene ND ug/L 1.00 0.352 1 05/28/19 21:36 05/28/19 21:36 563-58-6 1,3-Dichloropropane ND ug/L 1.00 0.366 1 05/28/19 21:36 05/28/19 21:36 142-28-9 cis-1,3-Dichloropropene ND ug/L 1.00 0.418 1 05/28/19 21:36 05/28/19 21:36 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.00 0.419 1 05/28/19 21:36 05/28/19 21:36 10061-02-6 2,2-Dichloropropane ND ug/L 1.00 0.321 1 05/28/19 21:36 05/28/19 21:36 594-20-7 Diisopropyl ether ND ug/L 1.00 0.320 1 05/28/19 21:36 05/28/19 21:36 108-20-3 Ethylbenzene ND ug/L 1.00 0.384 1 05/28/19 21:36 05/28/19 21:36 100-41-4 Hexachloro-1,3-butadiene ND ug/L 1.00 0.256 1 05/28/19 21:36 05/28/19 21:36 87-68-3 CC 2-Hexanone ND ug/L 10.0 3.82 1 05/28/19 21:36 05/28/19 21:36 591-78-6 p-Isopropyltoluene ND ug/L 1.00 0.350 1 05/28/19 21:36 05/28/19 21:36 99-87-6 2-Butanone (MEK) ND ug/L 10.0 3.93 1 05/28/19 21:36 05/28/19 21:36 78-93-3 Methylene Chloride ND ug/L 5.00 1.00 1 05/28/19 21:36 05/28/19 21:36 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 10.0 2.14 1 05/28/19 21:36 05/28/19 21:36 108-10-1 Methyl-tert-butyl ether ND ug/L 1.00 0.367 1 05/28/19 21:36 05/28/19 21:36 1634-04-4 Naphthalene ND ug/L 5.00 1.00 1 05/28/19 21:36 05/28/19 21:36 91-20-3 Styrene ND ug/L 1.00 0.307 1 05/28/19 21:36 05/28/19 21:36 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.00 0.385 1 05/28/19 21:36 05/28/19 21:36 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.00 0.130 1 05/28/19 21:36 05/28/19 21:36 79-34-5 Tetrachloroethene ND ug/L 1.00 0.372 1 05/28/19 21:36 05/28/19 21:36 127-18-4 Toluene ND ug/L 1.00 0.412 1 05/28/19 21:36 05/28/19 21:36 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.00 0.230 1 05/28/19 21:36 05/28/19 21:36 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.00 0.355 1 05/28/19 21:36 05/28/19 21:36 120-82-1 1,1,1-Trichloroethane ND ug/L 1.00 0.319 1 05/28/19 21:36 05/28/19 21:36 71-55-6 1,1,2-Trichloroethane ND ug/L 1.00 0.383 1 05/28/19 21:36 05/28/19 21:36 79-00-5 Trichloroethene ND ug/L 1.00 0.398 1 05/28/19 21:36 05/28/19 21:36 79-01-6 Trichlorofluoromethane ND ug/L 5.00 1.20 1 05/28/19 21:36 05/28/19 21:36 75-69-4 1,2,3-Trichloropropane ND ug/L 2.50 0.807 1 05/28/19 21:36 05/28/19 21:36 96-18-4 Vinyl acetate ND ug/L 10.0 1.63 1 05/28/19 21:36 05/28/19 21:36 108-05-4 Vinyl chloride ND ug/L 1.00 0.259 1 05/28/19 21:36 05/28/19 21:36 75-01-4 o-Xylene ND ug/L 1.00 0.341 1 05/28/19 21:36 05/28/19 21:36 95-47-6 m&p-Xylene ND ug/L 2.00 0.719 1 05/28/19 21:36 05/28/19 21:36 179601-23-1 Xylene (Total) ND ug/L 3.00 1.06 1 05/28/19 21:36 05/28/19 21:36 1330-20-7 1,4-Dioxane (p-Dioxane) ND ug/L 100 36.0 1 05/28/19 21:36 05/28/19 21:36 123-91-1 Surrogates Toluene-d8 (S) 90.3 % 80.0-120 1 05/28/19 21:36 05/28/19 21:36 2037-26-5 4-Bromofluorobenzene (S) 99.1 % 77.0-126 1 05/28/19 21:36 05/28/19 21:36 460-00-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-12 Lab ID: 92429561008 Collected: 05/16/19 09:50 Received: 05/17/19 13:00 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Surrogates 1,2-Dichloroethane-d4 (S) 87.3 % 70.0-130 1 05/28/19 21:36 05/28/19 21:36 17060-07-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-2 Lab ID: 92429869002 Collected: 05/17/19 08:50 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:15 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:15 7440-38-2 Barium 36.5 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:15 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:15 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:15 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:15 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:15 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:29 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 36 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-3R Lab ID: 92429869003 Collected: 05/17/19 08:45 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:18 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:18 7440-38-2 Barium 44.1 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:18 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:18 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:18 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:18 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:18 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:40 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 37 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-4S Lab ID: 92429869004 Collected: 05/17/19 08:35 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:21 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:21 7440-38-2 Barium 41.8 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:21 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:21 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:21 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:21 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:21 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:44 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 38 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-91) Lab ID: 92429869006 Collected: 05/17/19 00:00 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:36 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:36 7440-38-2 Barium 21.8 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:36 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:36 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7439-92-1 Nickel 3.1J ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:36 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:36 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:36 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:47 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-11D Lab ID: 92429869007 Collected: 05/17/19 00:00 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:39 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:39 7440-38-2 Barium 14.7 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:39 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:39 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:39 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:39 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:39 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:54 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: MW-13 Lab ID: 92429869008 Collected: 05/17/19 15:50 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:42 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:42 7440-38-2 Barium 26.3 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:42 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:42 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:42 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:42 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:42 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.071J ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 05:01 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 41 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 Sample: SW-D Lab ID: 92429869009 Collected: 05/17/19 07:35 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:45 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:45 7440-38-2 Barium 16.1 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:45 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:45 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:45 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:45 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:45 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 05:05 7440-28-0 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476262 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 92429561004 METHOD BLANK: 2580260 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Mercury ug/L ND 0.20 0.10 05/28/1915:07 LABORATORY CONTROL SAMPLE: 2580261 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2580262 2580263 MS MSD 92429626009 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.3 1.6 89 59 75-125 38 25 M1,R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476454 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92429561001, 92429561002, 92429561003 METHOD BLANK: 2581015 Matrix: Associated Lab Samples: 92429561001, 92429561002, 92429561003 Blank Parameter Units Result Water Reporting Limit Antimony ug/L ND 5.0 Arsenic ug/L ND 10.0 Barium ug/L ND 5.0 Beryllium ug/L ND 1.0 Cadmium ug/L ND 1.0 Chromium ug/L ND 5.0 Cobalt ug/L ND 5.0 Copper ug/L ND 5.0 Lead ug/L ND 5.0 Nickel ug/L ND 5.0 Selenium ug/L ND 10.0 Silver ug/L ND 5.0 Vanadium ug/L ND 5.0 Zinc ug/L ND 10.0 MDL Analyzed 3.0 05/23/19 19:28 4.7 05/23/19 19:28 1.0 05/23/19 19:28 0.20 05/23/19 19:28 0.40 05/23/19 19:28 1.0 05/23/19 19:28 1.1 05/23/19 19:28 2.1 05/23/19 19:28 1.6 05/23/19 19:28 0.90 05/23/19 19:28 4.7 05/23/19 19:28 2.5 05/23/19 19:28 1.3 05/23/19 19:28 3.9 05/23/19 19:28 LABORATORY CONTROL SAMPLE: Parameter 2581016 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 473 95 80-120 Arsenic ug/L 500 449 90 80-120 Barium ug/L 500 499 100 80-120 Beryllium ug/L 500 476 95 80-120 Cadmium ug/L 500 482 96 80-120 Chromium ug/L 500 488 98 80-120 Cobalt ug/L 500 476 95 80-120 Copper ug/L 500 477 95 80-120 Lead ug/L 500 468 94 80-120 Nickel ug/L 500 483 97 80-120 Selenium ug/L 500 464 93 80-120 Silver ug/L 250 240 96 80-120 Vanadium ug/L 500 466 93 80-120 Zinc ug/L 500 472 94 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2581017 2581018 MS MSD 92429209001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 503 513 101 103 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2581017 2581018 MS MSD 92429209001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L 5.8J 500 500 479 493 95 98 75-125 3 20 Barium ug/L 90.4 500 500 609 619 104 106 75-125 2 20 Beryllium ug/L ND 500 500 496 509 99 102 75-125 3 20 Cadmium ug/L ND 500 500 523 532 105 106 75-125 2 20 Chromium ug/L ND 500 500 514 525 103 105 75-125 2 20 Cobalt ug/L 12.2 500 500 517 527 101 103 75-125 2 20 Copper ug/L 3.OJ 500 500 504 518 100 103 75-125 3 20 Lead ug/L ND 500 500 498 508 100 102 75-125 2 20 Nickel ug/L 4.9J 500 500 517 528 102 105 75-125 2 20 Selenium ug/L ND 500 500 519 532 104 106 75-125 3 20 Silver ug/L ND 250 250 252 259 101 103 75-125 3 20 Vanadium ug/L ND 500 500 491 504 98 101 75-125 3 20 Zinc ug/L 15.4 500 500 525 534 102 104 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 478300 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92429561004, 92429561005, 92429561006, 92429561007, 92429561008, 92429869002, 92429869003, 92429869004,92429869006,92429869007,92429869008,92429869009 METHOD BLANK: 2589492 Matrix: Water Associated Lab Samples: 92429561004, 92429561005, 92429561006, 92429561007, 92429561008, 92429869002, 92429869003, 92429869004,92429869006,92429869007,92429869008,92429869009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 05/31/1919:09 Arsenic ug/L ND 10.0 5.0 05/31/1919:09 Barium ug/L ND 5.0 2.5 05/31/1919:09 Beryllium ug/L ND 1.0 0.50 05/31/1919:09 Cadmium ug/L ND 1.0 0.50 05/31/1919:09 Chromium ug/L ND 5.0 2.5 05/31/1919:09 Cobalt ug/L ND 5.0 2.5 05/31/1919:09 Copper ug/L ND 5.0 2.5 05/31/1919:09 Lead ug/L ND 5.0 2.5 05/31/1919:09 Nickel ug/L ND 5.0 2.5 05/31/1919:09 Selenium ug/L ND 10.0 5.0 05/31/1919:09 Silver ug/L ND 5.0 2.5 05/31/1919:09 Vanadium ug/L ND 5.0 2.5 05/31/1919:09 Zinc ug/L ND 10.0 5.0 05/31/1919:09 LABORATORY CONTROL SAMPLE: Parameter 2589493 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 487 97 80-120 Arsenic ug/L 500 466 93 80-120 Barium ug/L 500 495 99 80-120 Beryllium ug/L 500 496 99 80-120 Cadmium ug/L 500 489 98 80-120 Chromium ug/L 500 497 99 80-120 Cobalt ug/L 500 490 98 80-120 Copper ug/L 500 502 100 80-120 Lead ug/L 500 484 97 80-120 Nickel ug/L 500 486 97 80-120 Selenium ug/L 500 481 96 80-120 Silver ug/L 250 251 100 80-120 Vanadium ug/L 500 497 99 80-120 Zinc ug/L 500 478 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589494 2589495 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 486 499 97 100 75-125 3 20 Arsenic ug/L ND 500 500 485 496 97 99 75-125 2 20 Barium ug/L 253 500 500 750 759 99 101 75-125 1 20 Beryllium ug/L ND 500 500 502 515 100 103 75-125 2 20 Cadmium ug/L ND 500 500 483 489 97 98 75-125 1 20 Chromium ug/L ND 500 500 497 506 99 101 75-125 2 20 Cobalt ug/L 21.4 500 500 507 515 97 99 75-125 1 20 Copper ug/L ND 500 500 526 537 105 107 75-125 2 20 Lead ug/L ND 500 500 480 488 96 98 75-125 2 20 Nickel ug/L 5.2 500 500 486 495 96 98 75-125 2 20 Selenium ug/L ND 500 500 515 521 103 104 75-125 1 20 Silver ug/L ND 250 250 250 255 100 102 75-125 2 20 Vanadium ug/L ND 500 500 508 518 102 104 75-125 2 20 Zinc ug/L ND 500 500 475 482 94 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476448 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92429561001, 92429561002, 92429561003 METHOD BLANK: 2580997 Matrix: Water Associated Lab Samples: 92429561001, 92429561002, 92429561003 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 05/21/1918:04 LABORATORY CONTROL SAMPLE: 2580998 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10.0 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2580999 2581000 MS MSD 92429355001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.2 10.3 101 102 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 478331 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92429561004, 92429561005, 92429561006, 92429561007, 92429561008, 92429869002, 92429869003, 92429869004,92429869006,92429869007,92429869008,92429869009 METHOD BLANK: 2589562 Matrix: Water Associated Lab Samples: 92429561004, 92429561005, 92429561006, 92429561007, 92429561008, 92429869002, 92429869003, 92429869004,92429869006,92429869007,92429869008,92429869009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 06/06/19 02:29 LABORATORY CONTROL SAMPLE: 2589563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589564 2589565 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.6 10.0 96 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 477221 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92429561001, 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 METHOD BLANK: 2584603 Matrix: Water Associated Lab Samples: 92429561001, 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.34 05/23/19 11:10 1,1,1-Trichloroethane ug/L ND 1.0 0.18 05/23/19 11:10 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.22 05/23/19 11:10 1,1,2-Trichloroethane ug/L ND 1.0 0.24 05/23/19 11:10 1,1-Dichloroethane ug/L ND 1.0 0.27 05/23/19 11:10 1,1-Dichloroethene ug/L ND 1.0 0.24 05/23/19 11:10 1,2,3-Trichloropropane ug/L ND 1.0 0.35 05/23/19 11:10 1,2-Dibromo-3-chloropropane ug/L ND 5.0 0.26 05/23/19 11:10 1,2-Dibromoethane (EDB) ug/L ND 1.0 0.26 05/23/19 11:10 1,2-Dichlorobenzene ug/L ND 1.0 0.29 05/23/19 11:10 1,2-Dichloroethane ug/L ND 1.0 0.34 05/23/19 11:10 1,2-Dichloropropane ug/L ND 1.0 0.19 05/23/19 11:10 1,4-Dichlorobenzene ug/L ND 1.0 0.26 05/23/19 11:10 1,4-Dioxane (p-Dioxane) ug/L ND 150 56.2 05/23/19 11:10 2-Butanone (MEK) ug/L ND 5.0 3.3 05/23/19 11:10 2-Hexanone ug/L ND 5.0 0.57 05/23/19 11:10 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 4.5 05/23/19 11:10 Acetone ug/L ND 25.0 6.2 05/23/19 11:10 Acrylonitrile ug/L ND 10.0 0.90 05/23/19 11:10 Benzene ug/L ND 1.0 0.15 05/23/19 11:10 Bromochloromethane ug/L ND 1.0 0.34 05/23/19 11:10 Bromodichloromethane ug/L ND 1.0 0.26 05/23/19 11:10 Bromoform ug/L ND 1.0 0.62 05/23/19 11:10 Bromomethane ug/L ND 2.0 0.62 05/23/19 11:10 Carbon disulfide ug/L ND 2.0 0.40 05/23/19 11:10 Carbon tetrachloride ug/L ND 1.0 0.22 05/23/19 11:10 Chlorobenzene ug/L ND 1.0 0.23 05/23/19 11:10 Chloroethane ug/L ND 1.0 0.49 05/23/19 11:10 Chloroform ug/L ND 5.0 2.3 05/23/19 11:10 Chloromethane ug/L ND 1.0 0.39 05/23/19 11:10 cis-1,2-Dichloroethene ug/L ND 1.0 0.29 05/23/19 11:10 cis-1,3-Dichloropropene ug/L ND 1.0 0.30 05/23/19 11:10 Dibromochloromethane ug/L ND 1.0 0.41 05/23/19 11:10 Dibromomethane ug/L ND 1.0 0.46 05/23/19 11:10 Ethylbenzene ug/L ND 1.0 0.26 05/23/19 11:10 lodomethane ug/L ND 20.0 12.5 05/23/19 11:10 Methylene Chloride ug/L ND 5.0 3.7 05/23/19 11:10 Styrene ug/L ND 1.0 0.27 05/23/19 11:10 Tetrachloroethene ug/L ND 1.0 0.16 05/23/19 11:10 Toluene ug/L ND 1.0 0.24 05/23/19 11:10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 METHOD BLANK: 2584603 Matrix: Water Associated Lab Samples: 92429561001, 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.25 05/23/19 11:10 trans- 1,3-Dichloropropene ug/L ND 1.0 0.31 05/23/19 11:10 trans-1,4-Dichloro-2-butene ug/L ND 1.0 0.54 05/23/19 11:10 Trichloroethene ug/L ND 1.0 0.22 05/23/19 11:10 Trichlorofluoromethane ug/L ND 1.0 0.31 05/23/19 11:10 Vinyl acetate ug/L ND 2.0 1.4 05/23/19 11:10 Vinyl chloride ug/L ND 1.0 0.24 05/23/19 11:10 Xylene (Total) ug/L ND 1.0 0.63 05/23/19 11:10 1,2-Dichloroethane-d4 (S) % 113 70-130 05/23/19 11:10 4-Bromofluorobenzene (S) % 101 70-130 05/23/19 11:10 Toluene-d8 (S) % 103 70-130 05/23/19 11:10 LABORATORY CONTROL SAMPLE: 2584604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.6 109 70-130 1,1,1-Trichloroethane ug/L 50 51.8 104 70-130 1,1,2,2-Tetrachloroethane ug/L 50 50.8 102 70-130 1,1,2-Trichloroethane ug/L 50 51.0 102 70-130 1,1-Dichloroethane ug/L 50 52.8 106 70-130 1,1-Dichloroethene ug/L 50 53.3 107 70-130 1,2,3-Trichloropropane ug/L 50 51.0 102 70-130 1,2-Dibromo-3-chloropropane ug/L 50 54.0 108 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.3 103 70-130 1,2-Dichlorobenzene ug/L 50 51.2 102 70-130 1,2-Dichloroethane ug/L 50 49.7 99 70-130 1,2-Dichloropropane ug/L 50 51.4 103 70-130 1,4-Dichlorobenzene ug/L 50 50.4 101 70-130 1,4-Dioxane(p-Dioxane) ug/L 1000 1050 105 59-169 2-Butanone (MEK) ug/L 100 101 101 64-135 2-Hexanone ug/L 100 108 108 66-135 4-Methyl-2-pentanone (MIBK) ug/L 100 105 105 70-130 Acetone ug/L 100 115 115 61-157 Acrylonitrile ug/L 250 251 100 61-143 Benzene ug/L 50 51.0 102 70-130 Bromochloromethane ug/L 50 53.2 106 70-130 Bromodichloromethane ug/L 50 55.0 110 70-130 Bromoform ug/L 50 44.2 88 70-130 Bromomethane ug/L 50 50.5 101 38-130 Carbon disulfide ug/L 50 52.4 105 68-130 Carbon tetrachloride ug/L 50 51.7 103 70-130 Chlorobenzene ug/L 50 49.6 99 70-130 Chloroethane ug/L 50 56.1 112 37-142 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 51 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 LABORATORY CONTROL SAMPLE: 2584604 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloroform ug/L 50 55.6 111 70-130 Chloromethane ug/L 50 51.1 102 48-130 cis-1,2-Dichloroethene ug/L 50 52.3 105 70-130 cis-1,3-Dichloropropene ug/L 50 55.1 110 70-130 Dibromochloromethane ug/L 50 55.1 110 70-130 Dibromomethane ug/L 50 49.5 99 70-130 Ethylbenzene ug/L 50 51.1 102 70-130 lodomethane ug/L 100 97.3 97 40-130 Methylene Chloride ug/L 50 52.3 105 67-132 Styrene ug/L 50 51.0 102 70-130 Tetrachloroethene ug/L 50 48.5 97 69-130 Toluene ug/L 50 49.3 99 70-130 trans-1,2-Dichloroethene ug/L 50 52.2 104 70-130 trans- 1,3-Dichloropropene ug/L 50 53.5 107 70-130 trans-1,4-Dichloro-2-butene ug/L 50 60.7 121 35-189 Trichloroethene ug/L 50 48.5 97 70-130 Trichlorofluoromethane ug/L 50 54.4 109 63-130 Vinyl acetate ug/L 100 108 108 55-143 Vinyl chloride ug/L 50 53.1 106 70-131 Xylene (Total) ug/L 150 152 101 70-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 100 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2584851 2584852 MS MSD 92429596030 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 20 20 22.0 22.1 110 110 73-134 0 30 1,1,1-Trichloroethane ug/L ND 20 20 24.3 23.9 121 120 82-143 1 30 1,1,2,2-Tetrachloroethane ug/L ND 20 20 21.8 21.4 109 107 70-136 2 30 1,1,2-Trichloroethane ug/L ND 20 20 21.9 21.5 110 107 70-135 2 30 1,1-Dichloroethane ug/L ND 20 20 24.0 24.4 120 122 70-139 2 30 1,1-Dichloroethene ug/L ND 20 20 24.7 24.6 124 123 70-154 1 30 1,2,3-Trichloropropane ug/L ND 20 20 22.0 22.2 110 111 71-137 1 30 1,2-Dibromo-3- ug/L ND 20 20 19.8 19.1 99 96 65-134 3 30 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.1 20.5 106 103 70-137 3 30 1,2-Dichlorobenzene ug/L ND 20 20 20.7 21.1 104 105 70-133 1 30 1,2-Dichloroethane ug/L ND 20 20 22.1 22.7 110 113 70-137 3 30 1,2-Dichloropropane ug/L ND 20 20 22.4 22.3 112 111 70-140 1 30 1,4-Dichlorobenzene ug/L ND 20 20 21.3 20.7 106 103 70-133 3 30 1,4-Dioxane (p-Dioxane) ug/L ND 400 400 415 421 104 105 53-168 2 30 2-Butanone (MEK) ug/L ND 40 40 43.4 43.4 108 108 60-139 0 30 2-Hexanone ug/L ND 40 40 43.4 43.6 109 109 65-138 0 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 52 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2584851 2584852 MS MSD 92429596030 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 4-Methyl-2-pentanone ug/L ND 40 40 42.0 43.4 105 108 65-135 3 30 (MIBK) Acetone ug/L ND 40 40 49.0 46.7 122 117 60-148 5 30 Acrylonitrile ug/L ND 100 100 109 112 109 112 64-147 3 30 Benzene ug/L ND 20 20 21.9 22.2 109 111 70-151 1 30 Bromochloromethane ug/L ND 20 20 22.9 22.7 114 114 70-141 1 30 Bromodichloromethane ug/L ND 20 20 22.9 22.0 114 110 70-138 4 30 Bromoform ug/L ND 20 20 18.8 18.9 94 95 63-130 1 30 Bromomethane ug/L ND 20 20 23.8 23.6 119 118 15-152 1 30 Carbon disulfide ug/L ND 20 20 24.0 23.7 120 119 69-149 1 30 Carbon tetrachloride ug/L ND 20 20 22.2 22.5 111 112 70-143 1 30 Chlorobenzene ug/L ND 20 20 21.2 21.2 106 106 70-138 0 30 Chloroethane ug/L ND 20 20 24.6 23.9 123 119 52-163 3 30 Chloroform ug/L ND 20 20 23.6 23.7 118 118 70-139 1 30 Chloromethane ug/L ND 20 20 24.6 24.7 123 124 41-139 1 30 cis-1,2-Dichloroethene ug/L ND 20 20 24.0 23.5 120 117 70-141 2 30 cis-1,3-Dichloropropene ug/L ND 20 20 22.5 21.6 113 108 70-137 4 30 Dibromochloromethane ug/L ND 20 20 18.3 19.2 92 96 70-134 4 30 Dibromomethane ug/L ND 20 20 20.2 19.7 101 98 70-138 3 30 Ethylbenzene ug/L ND 20 20 22.3 22.7 112 114 66-153 2 30 lodomethane ug/L ND 40 40 40.9 39.6 102 99 20-138 3 30 Methylene Chloride ug/L ND 20 20 24.2 23.7 121 119 42-159 2 30 Styrene ug/L ND 20 20 21.1 21.5 105 108 70-135 2 30 Tetrachloroethene ug/L ND 20 20 20.8 21.2 104 106 59-143 2 30 Toluene ug/L ND 20 20 21.6 21.3 108 106 59-148 1 30 trans-1,2-Dichloroethene ug/L ND 20 20 23.9 24.1 120 120 70-146 1 30 trans-1,3-Dichloropropene ug/L ND 20 20 22.0 21.5 110 107 70-135 2 30 trans-1,4-Dichloro-2-butene ug/L ND 20 20 19.7 20.9 99 105 47-135 6 30 Trichloroethene ug/L ND 20 20 21.4 21.1 107 106 70-147 1 30 Trichlorofluoromethane ug/L ND 20 20 22.4 22.8 112 114 70-148 2 30 Vinyl acetate ug/L ND 40 40 45.2 45.1 113 113 49-151 0 30 Vinyl chloride ug/L ND 20 20 25.4 25.6 127 128 70-156 1 30 Xylene (Total) ug/L ND 60 60 66.1 67.1 110 112 63-158 2 30 1,2-Dichloroethane-d4 (S) % 111 110 70-130 4-Bromofluorobenzene (S) % 103 104 70-130 Toluene-d8 (S) % 102 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 1287536 Analysis Method: EPA 8260D QC Batch Method: 8260D Analysis Description: VOA (GC/MS) 8260D Associated Lab Samples: 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 METHOD BLANK: R3416175-3 Matrix: Water Associated Lab Samples: 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Acetone ug/L ND 50.0 10.0 05/28/19 15:13 Acrylonitrile ug/L ND 10.0 1.87 05/28/19 15:13 Benzene ug/L ND 1.00 0.331 05/28/19 15:13 Bromobenzene ug/L ND 1.00 0.352 05/28/19 15:13 Bromodichloromethane ug/L ND 1.00 0.380 05/28/19 15:13 Bromochloromethane ug/L ND 5.00 0.520 05/28/19 15:13 Bromoform ug/L ND 1.00 0.469 05/28/19 15:13 Bromomethane ug/L ND 5.00 0.866 05/28/19 15:13 Carbon tetrachloride ug/L ND 1.00 0.379 05/28/19 15:13 Chlorobenzene ug/L ND 1.00 0.348 05/28/19 15:13 Dibromochloromethane ug/L ND 1.00 0.327 05/28/19 15:13 Chloroethane ug/L ND 5.00 0.453 05/28/19 15:13 Chloroform ug/L ND 5.00 0.324 05/28/19 15:13 Chloromethane ug/L ND 2.50 0.276 05/28/19 15:13 2-Chlorotoluene ug/L ND 1.00 0.375 05/28/19 15:13 4-Chlorotoluene ug/L ND 1.00 0.351 05/28/19 15:13 1,2-Dibromo-3-chloropropane ug/L ND 5.00 1.33 05/28/19 15:13 1,2-Dibromoethane (EDB) ug/L ND 1.00 0.381 05/28/19 15:13 Dibromomethane ug/L ND 1.00 0.346 05/28/19 15:13 1,2-Dichlorobenzene ug/L ND 1.00 0.349 05/28/19 15:13 1,3-Dichlorobenzene ug/L ND 1.00 0.220 05/28/19 15:13 1,4-Dichlorobenzene ug/L ND 1.00 0.274 05/28/19 15:13 Dichlorodifluoromethane ug/L ND 5.00 0.551 05/28/19 15:13 1,1-Dichloroethane ug/L ND 1.00 0.259 05/28/19 15:13 1,2-Dichloroethane ug/L ND 1.00 0.361 05/28/19 15:13 1,1-Dichloroethene ug/L ND 1.00 0.398 05/28/19 15:13 cis-1,2-Dichloroethene ug/L ND 1.00 0.260 05/28/19 15:13 trans-1,2-Dichloroethene ug/L ND 1.00 0.396 05/28/19 15:13 1,2-Dichloropropane ug/L ND 1.00 0.306 05/28/19 15:13 1,1-Dichloropropene ug/L ND 1.00 0.352 05/28/19 15:13 1,3-Dichloropropane ug/L ND 1.00 0.366 05/28/19 15:13 cis-1,3-Dichloropropene ug/L ND 1.00 0.418 05/28/19 15:13 trans- 1,3-Dichloropropene ug/L ND 1.00 0.419 05/28/19 15:13 2,2-Dichloropropane ug/L ND 1.00 0.321 05/28/19 15:13 Diisopropyl ether ug/L ND 1.00 0.320 05/28/19 15:13 Ethylbenzene ug/L ND 1.00 0.384 05/28/19 15:13 Hexachloro-1,3-butadiene ug/L ND 1.00 0.256 05/28/19 15:13 2-Hexanone ug/L ND 10.0 3.82 05/28/19 15:13 p-Isopropyltoluene ug/L ND 1.00 0.350 05/28/19 15:13 2-Butanone (MEK) ug/L ND 10.0 3.93 05/28/19 15:13 Methylene Chloride ug/L ND 5.00 1.00 05/28/19 15:13 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 METHOD BLANK: R3416175-3 Matrix: Water Associated Lab Samples: 92429561002, 92429561003, 92429561004, 92429561005, 92429561006, 92429561007, 92429561008 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 2.14 05/28/19 15:13 Methyl-tert-butyl ether ug/L ND 1.00 0.367 05/28/19 15:13 Naphthalene ug/L ND 5.00 1.00 05/28/19 15:13 Styrene ug/L ND 1.00 0.307 05/28/19 15:13 1,1,1,2-Tetrachloroethane ug/L ND 1.00 0.385 05/28/19 15:13 1,1,2,2-Tetrachloroethane ug/L ND 1.00 0.130 05/28/19 15:13 Tetrachloroethene ug/L ND 1.00 0.372 05/28/19 15:13 Toluene ug/L ND 1.00 0.412 05/28/19 15:13 1,2,3-Trichlorobenzene ug/L ND 1.00 0.230 05/28/19 15:13 1,2,4-Trichlorobenzene ug/L ND 1.00 0.355 05/28/19 15:13 1,1,1-Trichloroethane ug/L ND 1.00 0.319 05/28/19 15:13 1,1,2-Trichloroethane ug/L ND 1.00 0.383 05/28/19 15:13 Trichloroethene ug/L ND 1.00 0.398 05/28/19 15:13 Trichlorofluoromethane ug/L ND 5.00 1.20 05/28/19 15:13 1,2,3-Trichloropropane ug/L ND 2.50 0.807 05/28/19 15:13 Vinyl acetate ug/L ND 10.0 1.63 05/28/19 15:13 Vinyl chloride ug/L ND 1.00 0.259 05/28/19 15:13 Xylene (Total) ug/L ND 3.00 1.06 05/28/19 15:13 o-Xylene ug/L ND 1.00 0.341 05/28/19 15:13 m&p-Xylene ug/L ND 2.00 0.719 05/28/19 15:13 1,4-Dioxane (p-Dioxane) ug/L ND 100 36.0 05/28/19 15:13 Toluene-d8 (S) % 90.2 80.0-120 05/28/19 15:13 4-Bromofluorobenzene (S) % 96.6 77.0-126 05/28/19 15:13 1,2-Dichloroethane-d4 (S) % 86.2 70.0-130 05/28/19 15:13 LABORATORY CONTROL SAMPLE: Parameter R3416175-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Acetone ug/L 125 143 114 19.0-160 Acrylonitrile ug/L 125 149 120 55.0-149 Benzene ug/L 25.0 26.7 107 70.0-123 Bromobenzene ug/L 25.0 22.1 88.5 73.0-121 Bromodichloromethane ug/L 25.0 27.3 109 75.0-120 Bromochloromethane ug/L 25.0 23.8 95.3 76.0-122 Bromoform ug/L 25.0 24.1 96.4 68.0-132 Bromomethane ug/L 25.0 12.9 51.7 10.0-160 Carbon tetrachloride ug/L 25.0 27.1 108 68.0-126 Chlorobenzene ug/L 25.0 24.5 98.1 80.0-121 Dibromochloromethane ug/L 25.0 24.7 99.0 77.0-125 Chloroethane ug/L 25.0 23.1 92.3 47.0-150 Chloroform ug/L 25.0 26.9 108 73.0-120 Chloromethane ug/L 25.0 16.0 63.9 41.0-142 2-Chlorotoluene ug/L 25.0 22.0 87.9 76.0-123 4-Chlorotoluene ug/L 25.0 23.2 92.8 75.0-122 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 55 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 LABORATORY CONTROL SAMPLE: Parameter R3416175-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dibromo-3-chloropropane ug/L 25.0 22.4 89.6 58.0-134 1,2-Dibromoethane (EDB) ug/L 25.0 25.1 100 80.0-122 Dibromomethane ug/L 25.0 26.6 107 80.0-120 1,2-Dichlorobenzene ug/L 25.0 24.4 97.6 79.0-121 1,3-Dichlorobenzene ug/L 25.0 23.1 92.4 79.0-120 1,4-Dichlorobenzene ug/L 25.0 22.6 90.6 79.0-120 Dichlorodifluoromethane ug/L 25.0 27.7 111 51.0-149 1,1-Dichloroethane ug/L 25.0 26.5 106 70.0-126 1,2-Dichloroethane ug/L 25.0 24.7 98.9 70.0-128 1,1-Dichloroethene ug/L 25.0 27.2 109 71.0-124 cis-1,2-Dichloroethene ug/L 25.0 27.7 111 73.0-120 trans-1,2-Dichloroethene ug/L 25.0 28.0 112 73.0-120 1,2-Dichloropropane ug/L 25.0 26.9 107 77.0-125 1,1-Dichloropropene ug/L 25.0 27.5 110 74.0-126 1,3-Dichloropropane ug/L 25.0 25.2 101 80.0-120 cis-1,3-Dichloropropene ug/L 25.0 28.1 112 80.0-123 trans- 1,3-Dichloropropene ug/L 25.0 24.1 96.5 78.0-124 2,2-Dichloropropane ug/L 25.0 25.5 102 58.0-130 Diisopropyl ether ug/L 25.0 26.8 107 58.0-138 Ethylbenzene ug/L 25.0 24.9 99.7 79.0-123 Hexachloro-1,3-butadiene ug/L 25.0 20.4 81.7 54.0-138 2-Hexanone ug/L 125 137 110 67.0-149 p-Isopropyltoluene ug/L 25.0 21.8 87.4 76.0-125 2-Butanone (MEK) ug/L 125 139 111 44.0-160 Methylene Chloride ug/L 25.0 26.3 105 67.0-120 4-Methyl-2-pentanone (MIBK) ug/L 125 126 100 68.0-142 Methyl-tert-butyl ether ug/L 25.0 27.8 111 68.0-125 Naphthalene ug/L 25.0 22.6 90.2 54.0-135 Styrene ug/L 25.0 24.7 98.7 73.0-130 1,1,1,2-Tetrachloroethane ug/L 25.0 24.6 98.4 75.0-125 1,1,2,2-Tetrachloroethane ug/L 25.0 23.3 93.3 65.0-130 Tetrachloroethene ug/L 25.0 25.5 102 72.0-132 Toluene ug/L 25.0 23.7 94.7 79.0-120 1,2,3-Trichlorobenzene ug/L 25.0 22.4 89.4 50.0-138 1,2,4-Trichlorobenzene ug/L 25.0 23.2 92.9 57.0-137 1,1,1-Trichloroethane ug/L 25.0 27.5 110 73.0-124 1,1,2-Trichloroethane ug/L 25.0 24.2 96.9 80.0-120 Trichloroethene ug/L 25.0 28.1 112 78.0-124 Trichlorofluoromethane ug/L 25.0 28.7 115 59.0-147 1,2,3-Trichloropropane ug/L 25.0 24.4 97.6 73.0-130 Vinyl acetate ug/L 125 134 107 11.0-160 Vinyl chloride ug/L 25.0 27.6 111 67.0-131 Xylene (Total) ug/L 75.0 71.6 95.5 79.0-123 o-Xylene ug/L 25.0 24.1 96.3 80.0-122 m&p-Xylene ug/L 50.0 47.5 95.0 80.0-122 Toluene-d8 (S) % 90.3 80.0-120 4-Bromofluorobenzene (S) % 102 77.0-126 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 LABORATORY CONTROL SAMPLE: R3416175-1 Parameter Units 1,2-Dichloroethane-d4 (S) % LABORATORY CONTROL SAMPLE: R3416175-2 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L Toluene-d8 (S) % 4-Bromofluorobenzene (S) % 1,2-Dichloroethane-d4 (S) % QUALITY CONTROL DATA Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 100 70.0-130 Spike LCS Conc. Result 1000 1100 LCS % Rec % Rec Limits Qualifiers 110 13.0-160 90.6 80.0-120 100 77.0-126 86.4 70.0-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 57 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476123 Analysis Method: SM 521 OB-2011 QC Batch Method: SM 521OB-2011 Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 92429561004 METHOD BLANK: 2579868 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers BOD, 5 day ug/L ND 2000 2000 05/22/19 23:38 B3 LABORATORY CONTROL SAMPLE: 2579869 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 256000 129 84.6-115 B3,1-1 SAMPLE DUPLICATE: 2579871 92429561004 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 174000 171000 2 10 B3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476220 Analysis Method: EPA 9040C QC Batch Method: EPA 9040C Analysis Description: 9040 pH Associated Lab Samples: 92429561004 SAMPLE DUPLICATE: 2580139 Parameter pH at 25 Degrees C SAMPLE DUPLICATE: 2580167 Parameter pH at 25 Degrees C 92429688001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 4.3 4.3 0 9 H3 92429240001 Dup Max Units Result Result RPD RPD Qualifiers Std. Units 7.1 7.1 0 9 H3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476147 Analysis Method: EPA 300.0 Rev 2.1 1993 QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions Associated Lab Samples: 92429561004 METHOD BLANK: 2579898 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Sulfate ug/L ND 1000 500 05/18/1912:12 LABORATORY CONTROL SAMPLE: 2579899 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfate ug/L 50000 51200 102 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579900 2579901 MS MSD 92429605008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfate ug/L 10.2 mg/L 50000 50000 57800 59400 95 98 90-110 3 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476129 Analysis Method: EPA 353.2 Rev 2.0 1993 QC Batch Method: EPA 353.2 Rev 2.0 1993 Analysis Description: 353.2 Nitrate + Nitrite, Unpres. Associated Lab Samples: 92429561004 METHOD BLANK: 2579879 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Nitrogen, Nitrate ug/L ND 40.0 10.0 05/18/19 01:40 LABORATORY CONTROL SAMPLE: 2579880 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrogen, Nitrate ug/L 1500 1520 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579881 2579882 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrogen, Nitrate ug/L ND 1500 1500 756 754 50 50 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476637 Analysis Method: EPA 365.1 Rev 2.0 1993 QC Batch Method: EPA 365.1 Rev 2.0 1993 Analysis Description: 365.1 Phosphorus, Total Associated Lab Samples: 92429561004 METHOD BLANK: 2581796 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Phosphorus ug/L ND 50.0 25.0 05/21/19 22:32 LABORATORY CONTROL SAMPLE: 2581797 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Phosphorus ug/L 2500 2570 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2581798 2581799 MS MSD 92429079007 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Phosphorus ug/L 23.6 mg/L 2500 2500 26100 26100 101 98 90-110 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 QC Batch: 476382 Analysis Method: SM 5220D-2011 QC Batch Method: SM 5220D-2011 Analysis Description: 5220D COD Associated Lab Samples: 92429561004 METHOD BLANK: 2580780 Matrix: Water Associated Lab Samples: 92429561004 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 25000 12500 05/20/19 20:40 LABORATORY CONTROL SAMPLE: 2580781 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 750000 754000 100 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2580782 2580783 MS MSD 92429840001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 847 mg/L 100000 100000 951000 946000 105 100 90-110 0 3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 63 of 105 Pace Analytical Services, LLC aceAnalXical� 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Surry Co. Lined MSWLF Pace Project No.: 92429561 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PAN Pace Analytical National PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS B3 The dissolved oxygen depletion of the dilution water blank exceeded 0.2 mg/L. CC The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The result may be biased. H3 Sample was received or analysis requested beyond the recognized method holding time. J Analyte detected below the reporting limit, therefore result is an estimate. This qualifier is also used for all TICs. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92429561001 MW-5 EPA 3010A 476454 EPA 6010D 476553 92429561002 MW-6R EPA 3010A 476454 EPA 6010D 476553 92429561003 MW-11S EPA 3010A 476454 EPA 6010D 476553 92429561004 LAGOON EPA 3010A 478300 EPA 6010D 478326 92429561005 MW-8 EPA 3010A 478300 EPA 6010D 478326 92429561006 MW-9S EPA 3010A 478300 EPA 6010D 478326 92429561007 MW-10 EPA 3010A 478300 EPA 6010D 478326 92429561008 MW-12 EPA 3010A 478300 EPA 6010D 478326 92429869002 MW-2 EPA 3010A 478300 EPA 6010D 478326 92429869003 MW-3R EPA 3010A 478300 EPA 6010D 478326 92429869004 MW-4S EPA 3010A 478300 EPA 6010D 478326 92429869006 MW-91) EPA 3010A 478300 EPA 6010D 478326 92429869007 MW-11 D EPA 3010A 478300 EPA 6010D 478326 92429869008 MW-13 EPA 3010A 478300 EPA 6010D 478326 92429869009 SW-D EPA 3010A 478300 EPA 6010D 478326 92429561001 MW-5 EPA 3010A 476448 EPA 6020B 476555 92429561002 MW-6R EPA 3010A 476448 EPA 6020B 476555 92429561003 MW-11S EPA 3010A 476448 EPA 6020B 476555 92429561004 LAGOON EPA 3010A 478331 EPA 6020B 478572 92429561005 MW-8 EPA 3010A 478331 EPA 6020B 478572 92429561006 MW-9S EPA 3010A 478331 EPA 6020B 478572 92429561007 MW-10 EPA 3010A 478331 EPA 6020B 478572 92429561008 MW-12 EPA 3010A 478331 EPA 6020B 478572 92429869002 MW-2 EPA 3010A 478331 EPA 6020B 478572 92429869003 MW-3R EPA 3010A 478331 EPA 6020B 478572 92429869004 MW-4S EPA 3010A 478331 EPA 6020B 478572 92429869006 MW-91) EPA 3010A 478331 EPA 6020B 478572 92429869007 MW-11 D EPA 3010A 478331 EPA 6020B 478572 92429869008 MW-13 EPA 3010A 478331 EPA 6020B 478572 92429869009 SW-D EPA 3010A 478331 EPA 6020B 478572 92429561004 LAGOON EPA 7470A 476262 EPA 7470A 476327 92429561001 MW-5 EPA 8260D 477221 92429561002 MW-6R EPA 8260D 477221 92429561003 MW-11S EPA 8260D 477221 92429561004 LAGOON EPA 8260D 477221 92429561005 MW-8 EPA 8260D 477221 92429561006 MW-9S EPA 8260D 477221 92429561007 MW-10 EPA 8260D 477221 92429561008 MW-12 EPA 8260D 477221 92429561002 MW-6R 8260D 1287536 EPA 8260D 1287536 92429561003 MW-11S 8260D 1287536 EPA 8260D 1287536 92429561004 LAGOON 8260D 1287536 EPA 8260D 1287536 92429561005 MW-8 8260D 1287536 EPA 8260D 1287536 92429561006 MW-9S 8260D 1287536 EPA 8260D 1287536 92429561007 MW-10 8260D 1287536 EPA 8260D 1287536 92429561008 MW-12 8260D 1287536 EPA 8260D 1287536 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 105 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Surry Co. Lined MSWLF 92429561 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92429561004 LAGOON SM 521OB-2011 476123 SM 521OB-2011 476137 92429561004 LAGOON EPA 9040C 476220 92429561004 LAGOON EPA 300.0 Rev 2.1 1993 476147 92429561004 LAGOON EPA 353.2 Rev 2.0 1993 476129 92429561004 LAGOON EPA 365.1 Rev 2.0 1993 476637 EPA 365.1 Rev 2.0 1993 476702 92429561004 LAGOON SM 5220D-2011 476382 SM 5220D-2011 476436 Date: 07/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 105 Document Name: Document Revised: February 7, 2018 Sample Condition Upon Receipt(SCURI Page 1 of 2 c?ce MdAcaf Document No.: Issuing Authority: + y F•CAR-0.033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvillej�K Raleigh[] Mechanicsville❑ Sample.Condition Client Name: '/I� 1 j W0# : 92429561 I Upon • % ` UIl1(f pz f project t# ++II'Courier: ❑F d Ex ❑TIPS USPS ❑ClientIIII!����III I 111111111 Commercial Pace ❑other; III III 61 Custody Seal Present? []Yes ETNo Seals Intact? []Yes 0No ! ry Date/Initials Person Examining Contents; ! 7 Packing Material: [-]Bubble Wrap E8ubble Bags ❑None ❑ Other Thermometer: ❑IR Gun ID; 92TO48 Type of ice: j�J'wet ❑Blue !! /� Cooler Temp (°Cj: L • V Correction Factor•. Add/Subtract {°Cj 4.0 Cooler Temp Corrected ('C): 1,6) USDA Regulated Soil OjN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? n,.__ r-r— Biological Tissue Frozen? ❑Yes []NoE N/A []None Temp should be above freezing to VC []Samples out of temp criteria. Samples on ice, cooling process hasbegun Did sarnplesoriginate from a foreign source (internationally, nrhidlnc WAwa ii and Puerto Rim]? MYES IINa Comments/Discrepancy: Chain of Custody Present? 2fes _[]No []N/A 1, Samples Arrived within Hold Time? J2fYeS []NO [)N/A 2, Short Hold Time Analysis (<72 hr,)? []Yes ❑N/A 3. Rush Turn Around Time Requested? ❑Yes moo ,.,,r+o t_ I []N/A 4. Sufficient Volume? es ❑No ❑N/A 5. Correct Containers Used? -Pace Containers Used? oyes [-]No [:]No []N/A []N/A 6. intact? des 2Tes ❑Na ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No ETN/A S. Sample Labels Match COC? -Includes Date/Time/lD/Analysis Matrix: Yes ❑No ❑N/A 9. Headspace in VOA Vials (?5-6mm)? EJ'Y�s ❑No []N/A 10, bil1°i Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes []No ❑Na N/A ­�N/A 11. COMMENTS/SAMPLE DISCREPANCY ( l Field Data Required? ❑Yes ❑Na n� ('e2E'Vej �t^n i,i^ed r UII;SvrtG il' G<<eti C,& cry lI/ tnIf'fs �Vf�rd klI Lot ID of split containers: CLIENT NOTIFICATION/RESCILUTION Person contacted: Date/Tlme: Project Manager SCURF Review: 1 r Date: Project Manager 5RF Review: Date:'i 1C' Gl Page 67 of 105 Document Name: Sample Condition Upon Rec Document No.: F-CAR•CS-033-Rev.( Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office *Check mark top Ralf of box if pH and/or dechlorina#ion is verified and within the acceptance range for preservation samples. Exceptions; VOA, Coliform,TOC, Oil and Grease, DRO/8015 (water) DOC, LLHk "Bottom half of box is to list number of bottle Project # WO# : 92429561 L PM: AMB Due Date: 05/31/29 CLIENT: 92—Municipal tr E a m N n ✓ o a �n N a a m Z v n N _v a o N m a m 2 a 41 a N m a o N a Co Z N V N w d «' .y ti d m . n v a 0 y m a rni a a m n V M O z u N a o N z Z a m Y Z dl y Q Z V M e. H N a a m N r+ n S p 10 Z V W a a vEivyy_ R U a a m a z a tl c A m .c 3 n E l7 Z v a 4J CL c Q °: 7 �7 Q ^i Q _ V ¢ °' 2 •, l7 Q V Q 2 di= CL c F E o N 7 ^ L7 Q rV v qq O LM " E ¢ v ey V1 i l7 Q V x n D Ln = N E a N V4 �+, l7 Q u Q x z -0 E ¢ E ui N M Q m l7 C Z a J o S m l7 r3 ¢ M ^' O V1 4 O E H a t7 7 Z c O aE 7 rn l7 Q 2 d 4 D c a Oi 0 2 " Ln Ln M a N a a r a _ = a y I Q M l7 ? Q ? `-' H a •. n ry u+ LA = z w it v v, J E a n y r g P w N 2 Z u a E N a m _ M a y a e v E ¢ J E L7 ¢ ? m 7 o 5 c u ry v�i a c E ¢ v V O 1 4 l 3 4 5 6 7 8 9 10 tl 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation Amount of Preservative Lot d adjusted I added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 68 of 105 L _T G) a r, a 9 ITEM# � 0 a ° 'n p _ a Z c o E ro 6, in i 2 m O � � ° 111 CA r .0 � O z c n W o rD .Ne m r n X x C fJ • E 2 N � n �1 N IJ �oagoN9��o� � n ti n a - n 9 r 2� A • m fJ I.'".TRI;S CODE 15eo valid cotles to heft) z � I o p X p co p p n p p w SA'dPLE TY PE (G=GRA9 C=COMP)Ph 111 th ryy D ZZI m Gl r z z m o m 0 z r C ➢ 1 O m 3i m m m z a o z } o 3 3 _L) 1 l.� y m v " w �'� m 54AIPLE TEh1P AT COLLECTlQ11 fit m p mJ ri OF COpITAINERS v m ;�� O N o LIn,7reserved v 3 m o o c •� � H2SO4 # HNO3 3 w w w w w w w w NCI N rD n. + iJa4N _ m to Ha2S203 (� rn' o '. 1(�M" m' Methanol m. Giher w1 j Analyses.Test YfN 2 �. Vacs-8260 App I 0 O N Metals-App I x Turbidity c LA,x x x x 1,4-Oioxane (Non-SIM) LE o - rt �. n n a f.t v n r r 1 ti in m 73 o a n w T FMP in C C o > n a 9eceived on Ice Y (YlPlj m a S Cuslodv Sea[eu Cooler (YIN) : o N a'ampl25lntac[ - � j /-' - {rrrlf I 1 1 j I 1n m g N n 3 3 0 O 0 n = �n w Z o O n � C r a 0 U m fit C D Q O C)n C M M m n n n ro r Qro Tv 6 g 0 0 O C v fD a � m rt 0 m gage 69 of 105 Document Name: Document Revised: February 7, 2018 a aceAnalytical Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.; Issuing Authority: F•CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville z Raleigh❑ Mechanicsville❑ Sample -Condition - Client Name:Upon : 92429561 Receipt Project t WOE Courier: ❑Fed Ex ❑UPS CUSPS ❑Client pn; qMg :►us Date: 05/31/19 ❑Commercial Pace ❑Other: CLIENT: 92-Municipal Dyes Custody Seal Present? UINO Seals Intact? [—]Yes 0411 _ { 1 L (7- (" Date/Initials Person Examining Contents!-- Packing Material: ❑9ubble Wrap Bubble Bags (—]None ❑ Other Thermomet f: 92TO48 Type of Ice: _ ]wet ❑Blue ZR Gun ID: Cooler Temp (°C): 1T Correction Factor: Add/Subtract (°C) Cooler Temp Corrected ('C): USDA Regulated Soil ZN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? FlYes nNo Biological Tissue Frozen? ❑None []Yes [:]No C_ZfN/A Temp should be above freezing to VC []Samples out of temp criteria. Samples an ice, cooling process hasbegun Did samples originate from a Foreign source (internationally, includine Hawaii and Puerto Rlcal? MYes nNo Comments/Discrepancy: Chain of Custody Present? ucs []No El N/A 1. Samples Arrived within Hold Time? Yes ❑No ❑N/A 2. Short Hold Time Analysis (<72 hr.)? Yes ❑No ❑N/A 3. Rush Turn Around Time Requested? ❑Yes *QD ❑NIA 4. Sufficient Volume? A e! ❑No ❑N/A S. Correct Containers Used? -Pace Containers Used? Y a' 2. ❑No ❑No ❑N/A ❑N/A 6. Containers Intact? 12165 ❑Np N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No on,/, 8. Sample Labels Match CDC? -Includes Date/Time/ID/Analysis Matrix: es ON. ❑N/A 9. Headspace in VOA Vials (55-6mm)? t.. W ❑No ON 10. Trip Blank Present? Trip Blank Custody 5eals Present? ❑Yes Oyes ❑No ❑No NIA N/A 11. COMMENTS/SAMPLE DISCREPANCY ({ /n { Field Data Reequiir'ed? /❑Y/es ❑No - li — .;) t , 1 l . 1 6A_ W l ° ti/ l ��� Y Lot ID of split containers; CLIENT NOTIFICAVON/RESOLUTION Person contacted; Project Manager SCURF Review: Project Manager SRF Review: Date/Time: Date: 5 0't C `1 q Date: 51�:10f 1 Page 70 of 105 Document Name: Document Revised: February 7, 2018 �} ' aceAnaWical a Sample Condition Upon Receipt(SCLJRI Page 1 of 2 Document No.; Issuing Authority: F-CAR-CS•033-Rev.06 Pace Carolinas Quality Office 'Check mark top half of box if pH and/or dechlorination is Project t -WO# ; 92429561 verified and within the acceptance range for preservation �+ _ samples. pal' AMB Due Date: 05/ 113 / 9 Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {water} DOC, LLHg CLIENT: 92—Municipal "Bottom half of box is to list number of bottle a E a ¢ 2 N W h E ❑ c a m ¢ 2 v v E 7 rn a m a 2 w d E N a m _ S Z N _ .r a m v N v V O H E R a m ry v m _ E Z M m m O m Z °� y ¢ z ii E N IT o- go N rl n x p 1° Z V a E U v a v a C ❑ ro a N .0 u ¢ Z cal m n c Ci a w 7 •+ 0 4 Q u = N Q m i •+ 0 Q Z � a c a a E ¢ of 7 �+1 t9 Q � y a ry 2 E m tii 0 Q N = O ut x Q E 4 E vt M t7 2 a a E o ni M Q M c9 d z u 2 4 O] T a,IM t9 ❑ O b Z ¢ O U 7 Z z c C ¢ D> 7 m L9 > v O ,4r, i ¢ O> a C1 t7 d C] vQ « ID a Y ¢ O > Z a > „j, a be W 7 a � E u1 vi '� a [+ � E Ln ey v7 T ?, a E N M m C ¢ p ¢ c m � E O l7 7 a j G E 4 ❑ 2 II 3 4 5 6 7 B 9 10 11 12 pH Adjustment Log for Preserved Samples sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot tt Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this farm will be sent to the North Carolina DEHNR Certification Office (i.e. out of hold, incorrect preservative, out of temp, incorrect containers. Page 71 of 105 rj TEMP in G Received On Ice (YIN) Custody Sealec Goolar {Y!N} Samples Intact (Y1N} C 1 1 o I C O z y-r i r l�f 0 4 z L b J rr m m m m a m A rrT_ y ti 0 z � q-:.I—� m v m G) D 0 R W ITEM# CU Gl Z cG Ci m 0 0 0 v z w p m ID ti p. 0 b; h � N �� C,C� WL).5 m n L CD x a o �e; r dwo cr v m, Ri o n v O rn C,< m 3 A x 0 t� x CD ` � 2 y N V• m a n 77 ^ p D p w v p v C MATRIX CODE (see valid codes to left) v o 7 ,^, C ° 0 SAMPLETYPE (G-GRA9 G=COMP) .l � v o O S m y - J tn � v 3. m CL m 0 � � �n D In r" v r— „ m h n c.. m 0 w 9' Z � o � p rn n SAMPLETEMPAT COLLECTION V. Er 0 # GF CONTAINERS 3 O CL C K Unpreserved � b ry v v N 3 v m H2504 ° 2 c. HNO3 v m o D w HGI ((D 4 NaOH _� '`° mC 3 Na2S203 rn m Methanol y Other D Analyses Test YIN C m X c (p x VOCs- App 1 z n' C x Metals-App 2 (Includes Hy) z V/ rn CD � n N x BOo z m rq� H x COD z a Ln 0 x NITRATE z m r x PHOSPHORUS z N 0 3T N •V x Ph z x SLNate z 'm Q (D a i x 1,4_vioxane(Non-SIM) 0 --0 7 7 A L N R m � cL s d g n c r. 5 3 _ c Its n — 7T-�) ageof1 Document Name: Oocument Revised: February 7, 2018 a Sample Condition Upon Receipt(SCUR) Page 1 of 2 . =AnaVidal Document No.: Issuing Authority: F•CAR-0-03341ev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvi)le [� Raleigh[] Methanitsvilfe�l ' . Condition Client Name: Receipt Project W0# : 92429561 PM: RMB Due Date: 05/31/19 Courier: ❑F -Ex ❑UPS / ❑USPS V ❑Client ❑ Commercial ace ❑Other CLIENT: 92—Municipal Custody Seal Present? ❑Yes 7610 Seals Intact? Oyes Dateilnitiais Person Examining Contents: �' [ G—/r Packing Material: ❑Bubble Wrap 21Bubble Bags ❑None ❑ Other Biological Tissue Frozen? Thermometer [—]Yes [3io []N/Ato Gun iD: 92TO4B Type of Ice: �et ❑Hlue ❑None Cooler Temp (°C): 03 Correction factor: Add/Subtract (°CE 0.0 Tempshould be above freezing to 6°C Cooler Temp Corrected VC): �'� ❑5amples out of temp criteria. Samples an ice, cooling process hasbegun USDA Regulated Sall (ZIN/A, water sample) Did samples or'igi to in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, 11v— nip inrindinp Hawaii and Puerto Rico)? f fYes RNo Comments/Discrepancy: Chain of Custody Present? UK.- ❑Nv []N/A 1, Samples Arrived within Hold Time? Yes []NO ❑N/A 2, Short Hold Time Analysis (02 hr.)? ❑Yes Lino [I N/A 3, Rush Turn Around Time Requested? Des o ❑N/A 4. Sufficient Volume? 21; ❑No ❑NIA S. Correct Containers Used? a<s [:)No❑N/A 6, -Pace Containers Used? g es [:]No ❑N/A Containers Intact? es ❑No E]N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No N/A 8. Sample Labels Match COC? ©Yes []No ❑N/A 9. 99 -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? []Yes ❑tGo ❑N/A 10. Trip Blank Present? []Yes 06o []N/A 11. Trip Blank Custody Seals Present? ❑Yes 171rm Diy/A C9MMENT5/SAMPLE DISCREPANCY Field Data Required? ❑Yes [:]No CLIENT NOTIFICATION/RESOLUTION S DU(Y} IDS ooz- o0Q OA Person contacted:�t=4= Project Manager SCURF Review: , I Project Manager SRF Review: Lot ID of split contain Date/Time: Date: 6 "a }' I q Date: 5 a I ` Q Page 73 of 105 Document Name: Document Revised: February 7, 2018 + Cel�77aj�/t+ICcil Sample Condition Upon Receipt(SOUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-Cs-033-Rev.06 Pace CarolMas quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform,TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg "Bottom half of box is to list number of bottle Project# WO# : 92429561 PM: AMLq Due Date: 05/31/19 CLIENT: 92-Municipal tr E am a Z di Z n 7 a E N.-I 7 v m a Z a 7 a E 7 �n m m 2 v a `o. M a E u? 7� M.v a m a Z u rl 7 a m r v a O N 2 a E i, 'h a m m v a m Z ^ CL E N 2 M a m 'Q' Z N c E �n N v m m a _ Z �- a E eq V a a m =o ku 4> y o E v vim. 3 m m ` C v 4 ? M L7 a Ni U 2 d n E ` m 2 •, t7 a DI Z a a a 7 m l7 a N v ss ry 2 m E Q a 7A *+ t7 a V = O 2 v Q E NN 1A M l7 a V z 4 E Ln N T a M c7 a z U 2 ¢ 0 J E 2 vs l9 o 2 '^ 0 N z O i E H m l7 > ? a 4 O E 0 0 > ? O 0. 2 a O E a m U c Y m N a ? Y .1 O > Z .+ = ] w x a 3 Y � > M I d W E F � a in +� 2 'u _ a en E F N a v, Ih cn N Z V a m a E a M a m } y a j E a 7 o a Q O !� = c vyi E N � ? v E C w` F 6 E o= 7 o, a 1 Z 4 S 3 4 l (> 5 \N\ 7 l; N\ N NN 9 N \XN\ 10 11 12 pH Adjustment log for Preserved Samples Sample In Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot k Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will he sent to the North Carolina DEHNR Certification Ottice (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 74 of 105 A s a G3 u a N .a c m otl v CT) o 02 w N ITEM# ; m b w n> 1 n 3 o m a o cvi 0� n p D= N D O zCID 3 orw, (N co � oW8 nO orm m o p C. 0 m " U) N C 4 CD C. N N V a n C o H Q AnO� v n0 � N. m � v a y O @ a N O O n O MATRIX CODE )see valid codes to left) 1 'y Z z Z Z 0 o N 0 G) 0 0 0 0 G) 0 0 0 0 G) SAMPLETYPE (G=GRAB C=COMP) I Z ❑ 3 n 1, I m co G r n R n o 3 r 1 �."� QN. a n a z t �� rl o co -nl z tia = '� z ❑ A 3 3 -A Q m I m m m o_, O_ n z ^`t ❑ A y y ❑ v \ m m m z m SAMPLE TEMP AT COLLECTION ' - G V # OF CONTAINERS n m - a 3 a m Unpreserved r-1 m H2SO4 m m m HNO3 d m 1, 1 CD f� 3 w w w w w w w w w w w w HCI NaOH I i m n N Na252O3 m O N Methanol ca v � Other a jLa F r 2 Analyses Test YIN z x x x x x x x x x x x x VOCS-8260 App I D S N x x x x x x x x x x x Matals-App I z w m ui O z z z x x x x x x x x x x x Turbidity x x x x x x x x x x x 5,4-Dioxane (Nan-SIM) cx z r m M { � z Rs 3 m A o 7 y w m c d G Q TEMP in C v� a o Received on Ice (YIN) m - O Custody Sealed C cooler (YIN) Cn a t - Sam les Intact (YIN) Cv �0 Mn n r 3 CD fD (� M a n n G m m 7 K age 75 of 105 A m D n m en m yr i w ITEM# 0 v v 0. a to a Q n Z o Ci m a O w �Nb 2. � > t0 W n. Q-- z o m ? nrr n m O m y 0 3 § c `� 3 m 8 a (] x _ z ta M - N !3 ro A m NO A 9O N a5 20 0 0 a �- , 3 C• O `1 R J a Co m E a MATRIX COCE (see valid codes to left) 0 0 ! z Y ? , L) D I7 0 SAMPLE TYPE (G=GRAB C=COMP) m Z m 7 0 A T \ jj m (n D p D S r- L to 3 \ a � m n O � z m ` r� o C A I, `� z n CcoC C ( n m m 2 m D O T m n y y z lJs S� o w A ` C,0 1 m Z m Z 7' A 6 z SAMPLE TEMP AT COLLECTION y C m p OF CONTAINERS m w a 0 D n /1 0, �c C Unpreserved C^� In m v p d o c v .� a 7 n —] H2SO4 m m m o m 0 HNO3 -0# ro m m m 'm D ❑ s m m HCICD m 3 v r m l On A NaOH m m Na2S203 y a m R1 t m Methanol C C D � W Other �• n n x x x Analyses Test VOCs-App I10 YIN U) ro ro, m m J3 n o x x Mai N m_ p ar z x x Turbidily G N e, x x x 1,4-Oioxane (Non-Slh1} r c❑ (; m a A O a Cr 0 _5 O r N 7 rt a a w n ,i m A m a s w O m TEMP in C C a r m 3 o In °� Received on Ice (YIN) m z Custody Sealed Cooler (YIN) 1 a les Intact E Uge 76 of 105 aceAnal ical ° A f �l A L Y T CAL REPORT National Center for Testing &Innovation June 10, 2019 FTc FSS Pace Analytical - Huntersville, NC Sample Delivery Group: L1101606 [Cn] Samples Received: 05/22/2019 FrProject Number: 92429869 Description: Surry Co. Lined MSWLF FC Site: 001 GI Report To: Angela Baioni 9800 Kincey Avenue, Suite 100 rAl Huntersville, NC 28078 Fc Entire Report Reviewed By: �vUnn �v, �. L L111-� Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. i 41 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 1 of 29 TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page Tc: Table of Contents Ss: Sample Summary Cn: Case Narrative Sr: Sample Results MW-2 L1101606-02 MW-3R L1101606-03 MW-4S L1101606-04 MW-4D L1101606-05 MW-91D L1101606-06 MW-11D L1101606-07 MW-13 L1101606-08 SW-D L1101606-09 Qc: Quality Control Summary Volatile Organic Compounds (GC/MS) by Method 8260D GI: Glossary of Terms Al: Accreditations & Locations Sc: Sample Chain of Custody 1 Fn 2 3 4 FS5 5 [Cn] 7 9 Fr 11 13 RC 15 �GI 17 19 rAl 21 21 FSC 25 26 27 Page 78 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 2 of 29 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-2 L1101606-02 GW 05/17/19 08:50 05/22/19 08:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1919:36 05/28/1919:36 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time M MW-3R L1101606-03 GW 05/17/19 08:45 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location [Cn] date/time date/time Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1919:56 05/28/1919:56 DWR Mt. Juliet, TN FSrVolatile Collected by Collected date/time Received date/time sQC MW-4S L1101606-04 GW 05/17/19 08:35 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location GI date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 20:16 05/28/19 20:16 DWR Mt. Juliet, TN FAI Collected by Collected date/time Received date/time MW-4D L1101606-05 GW 05/17/19 08:40 05/22/19 08:45 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 20:36 05/28/19 20:36 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time MW-9D L1101606-06 GW 05/17/1900:00 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 20:56 05/28/19 20:56 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time MW-11D L1101606-07 GW 05/17/1900:00 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 21:16 05/28/19 21:16 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time MW-13 L1101606-08 GW 05/17/1915:50 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 21:36 05/28/19 21:36 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time SW-D L1101606-09 GW 05/17/19 07:35 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/19 21:56 05/28/19 21:56 DWR Mt. Juliet, TN Page 79 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 3 of 29 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. VV VV� � �t La�'_ Nancy McLain Project Manager FP1 FTC FSS FSr FC-1 F, FAI FSC Page 80 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 4 of 29 MW-2 SAMPLE RESULTS - 02 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 08:50 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 19:36 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 19:36 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 19:36 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 19:36 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 19:36 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 19:36 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 19:36 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 19:36 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 19:36 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 19:36 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 19:36 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 19:36 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 19:36 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 19:36 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 19:36 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 19:36 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 19:36 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 19:36 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 19:36 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 19:36 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 19:36 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 19:36 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 19:36 WG1287536 1,1-Dichloroethane 2.88 0.259 1.00 1 05/28/2019 19:36 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 19:36 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 19:36 WG1287536 cis-1,2-Dichloroethene 2.13 0.260 1.00 1 05/28/2019 19:36 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 19:36 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 19:36 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 19:36 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 19:36 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 19:36 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 19:36 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 19:36 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 19:36 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 19:36 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 19:36 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 19:36 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 19:36 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 19:36 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 19:36 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 19:36 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 19:36 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 19:36 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 19:36 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 19:36 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 19:36 WG1287536 Tetrachloroethene 0.519 J 0.372 1.00 1 05/28/2019 19:36 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 19:36 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 19:36 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 19:36 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 19:36 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 19:36 WG1287536 Trichloroethene 0.518 J 0.398 1.00 1 05/28/2019 19:36 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 19:36 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 19:36 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 81 of 105 PAGE: 5 of 29 ONE LAB. NATIONWIDE. MW-2 SAMPLE RESULTS - 02 Collected date/time: 05/17/19 08:50 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201919:36 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201919:36 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 19:36 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201919:36 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201919:36 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201919:36 WG1287536 (S) Toluene-d8 92.8 80.0-120 05128120191936 WG1287536 (S) 4-Bromof/uorobenzene 100 77.0-126 051281201919:36 WG1287536 (S) 1,2-Dich/oroethane-d4 88.9 70.0-130 0512812019 1936 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 82 of 105 PAGE: 6 of 29 MW-3R SAMPLE RESULTS - 03 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 08:45 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 19:56 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 19:56 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 19:56 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 19:56 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 19:56 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 19:56 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 19:56 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 19:56 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 19:56 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 19:56 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 19:56 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 19:56 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 19:56 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 19:56 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 19:56 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 19:56 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 19:56 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 19:56 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 19:56 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 19:56 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 19:56 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 19:56 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 19:56 WG1287536 1,1-Dichloroethane 1.71 0.259 1.00 1 05/28/2019 19:56 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 19:56 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 19:56 WG1287536 cis-1,2-Dichloroethene 2.29 0.260 1.00 1 05/28/2019 19:56 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 19:56 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 19:56 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 19:56 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 19:56 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 19:56 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 19:56 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 19:56 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 19:56 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 19:56 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 19:56 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 19:56 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 19:56 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 19:56 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 19:56 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 19:56 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 19:56 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 19:56 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 19:56 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 19:56 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 19:56 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 19:56 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 19:56 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 19:56 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 19:56 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 19:56 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 19:56 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 19:56 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 19:56 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 19:56 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 83 of 105 PAGE: 7 of 29 ONE LAB. NATIONWIDE. MW-3R SAMPLE RESULTS - 03 Collected date/time: 05/17/19 08:45 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201919:56 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201919:56 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 19:56 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201919:56 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201919:56 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201919:56 WG1287536 (S) Toluene-d8 91.5 80.0-120 051281201919.56 WG1287536 (S) 4-Bromof/uorobenzene 102 77.0-126 051281201919.56 WG1287536 (S) 1,2-Dich/oroethane-d4 86.2 70.0-130 0512812019 19.56 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 84 of 105 PAGE: 8 of 29 MW-4S SAMPLE RESULTS - 04 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 08:35 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 20:16 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 20:16 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 20:16 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 20:16 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 20:16 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 20:16 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 20:16 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 20:16 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 20:16 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 20:16 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 20:16 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 20:16 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 20:16 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 20:16 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 20:16 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 20:16 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 20:16 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 20:16 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 20:16 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 20:16 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 20:16 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 20:16 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 20:16 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 20:16 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 20:16 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 20:16 WG1287536 cis-1,2-Dichloroethene 0.432 J 0.260 1.00 1 05/28/2019 20:16 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 20:16 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 20:16 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 20:16 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 20:16 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 20:16 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 20:16 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 20:16 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 20:16 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 20:16 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 20:16 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 20:16 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 20:16 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 20:16 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 20:16 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 20:16 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 20:16 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 20:16 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 20:16 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 20:16 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 20:16 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 20:16 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 20:16 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 20:16 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 20:16 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 20:16 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 20:16 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 20:16 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 20:16 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 20:16 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 85 of 105 PAGE: 9 of 29 ONE LAB. NATIONWIDE. MW-4S SAMPLE RESULTS - 04 Collected date/time: 05/17/19 08:35 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/2019 20:16 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/2019 20:16 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 20:16 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 20:16 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 20:16 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 20:16 WG1287536 (S)Toluene-d8 90.6 80.0-120 051281201920.16 WG1287536 (S) 4-Bromof/uorobenzene 100 77.0-126 0512812019 20.16 WG1287536 (S) 1,2-Dich/oroethane-d4 90.9 70.0-130 0512812019 20.16 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 86 of 105 PAGE: 10 of 29 MW-4D SAMPLE RESULTS - 05 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 08:40 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 20:36 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 20:36 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 20:36 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 20:36 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 20:36 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 20:36 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 20:36 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 20:36 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 20:36 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 20:36 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 20:36 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 20:36 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 20:36 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 20:36 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 20:36 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 20:36 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 20:36 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 20:36 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 20:36 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 20:36 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 20:36 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 20:36 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 20:36 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 20:36 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 20:36 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 20:36 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 20:36 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 20:36 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 20:36 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 20:36 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 20:36 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 20:36 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 20:36 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 20:36 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 20:36 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 20:36 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 20:36 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 20:36 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 20:36 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 20:36 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 20:36 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 20:36 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 20:36 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 20:36 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 20:36 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 20:36 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 20:36 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 20:36 WG1287536 Toluene 0.842 J 0.412 1.00 1 05/28/2019 20:36 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 20:36 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 20:36 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 20:36 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 20:36 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 20:36 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 20:36 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 20:36 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 87 of 105 PAGE: 11 of 29 ONE LAB. NATIONWIDE. MW-4D SAMPLE RESULTS - 05 Collected date/time: 05/17/19 08:40 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/2019 20:36 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/2019 20:36 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 20:36 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 20:36 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 20:36 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 20:36 WG1287536 (S)Toluene-d8 92.2 80.0-120 051281201920:36 WG1287536 (S) 4-Bromof/uorobenzene 101 77.0-126 0512812019 20:36 WG1287536 (S) 1,2-Dich/oroethane-d4 92.7 70.0-130 0512812019 2036 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 88 of 105 PAGE: 12 of 29 MW-9D SAMPLE RESULTS - 06 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 00:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 20:56 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 20:56 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 20:56 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 20:56 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 20:56 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 20:56 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 20:56 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 20:56 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 20:56 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 20:56 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 20:56 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 20:56 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 20:56 WG1287536 Chloromethane 0.277 J J0 0.276 2.50 1 05/28/2019 20:56 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 20:56 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 20:56 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 20:56 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 20:56 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 20:56 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 20:56 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 20:56 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 20:56 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 20:56 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 20:56 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 20:56 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 20:56 WG1287536 cis-1,2-Dichloroethene 1.44 0.260 1.00 1 05/28/2019 20:56 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 20:56 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 20:56 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 20:56 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 20:56 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 20:56 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 20:56 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 20:56 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 20:56 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 20:56 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 20:56 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 20:56 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 20:56 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 20:56 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 20:56 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 20:56 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 20:56 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 20:56 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 20:56 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 20:56 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 20:56 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 20:56 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 20:56 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 20:56 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 20:56 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 20:56 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 20:56 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 20:56 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 20:56 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 20:56 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 89 of 105 PAGE: 13 of 29 ONE LAB. NATIONWIDE. MW-9D SAMPLE RESULTS - 06 Collected date/time: 05/17/19 00:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/2019 20:56 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/2019 20:56 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 20:56 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 20:56 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 20:56 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 20:56 WG1287536 (S)Toluene-d8 89.1 80.0-120 051281201920.56 WG1287536 (S) 4-Bromof/uorobenzene 99.3 77.0-126 0512812019 20.56 WG1287536 (S) 1,2-Dich/oroethane-d4 89.3 70.0-130 0512812019 20.56 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 90 of 105 PAGE: 14 of 29 M W-11 D SAMPLE RESULTS - 07 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 00:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 21:16 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 21:16 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 21:16 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 21:16 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 21:16 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 21:16 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 21:16 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 21:16 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 21:16 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 21:16 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 21:16 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 21:16 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 21:16 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 21:16 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 21:16 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 21:16 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 21:16 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 21:16 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 21:16 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 21:16 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 21:16 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 21:16 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 21:16 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 21:16 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 21:16 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 21:16 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 21:16 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 21:16 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 21:16 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 21:16 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 21:16 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 21:16 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 21:16 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 21:16 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 21:16 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 21:16 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 21:16 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 21:16 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 21:16 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 21:16 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 21:16 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 21:16 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 21:16 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 21:16 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 21:16 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 21:16 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 21:16 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 21:16 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 21:16 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 21:16 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 21:16 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 21:16 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 21:16 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 21:16 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 21:16 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 21:16 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 91 of 105 PAGE: 15 of 29 ONE LAB. NATIONWIDE. MW-11D SAMPLE RESULTS - 07 Collected date/time: 05/17/19 00:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I Dilution Analysis date / time Batch Vinyl acetate U 1.63 10.0 1 05/28/2019 21:16 WG1287536 Vinyl chloride 0.821 J 0.259 1.00 1 05/28/2019 21:16 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 21:16 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 21:16 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 21:16 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 21:16 WG1287536 (S)Toluene-d8 92.3 80.0-120 051281201921.16 WG1287536 (S) 4-Bromof/uorobenzene 104 77.0-126 0512812019 21.16 WG1287536 (S) 1,2-Dich/oroethane-d4 89.7 70.0-130 0512812019 21.16 WG1287536 Fp FTc FS Fn Fc F, FAI FSC Page 92 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 16 of 29 M W-13 SAMPLE RESULTS - 08 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 15:50 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 21:36 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 21:36 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 21:36 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 21:36 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 21:36 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 21:36 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 21:36 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 21:36 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 21:36 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 21:36 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 21:36 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 21:36 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 21:36 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 21:36 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 21:36 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 21:36 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 21:36 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 21:36 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 21:36 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 21:36 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 21:36 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 21:36 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 21:36 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 21:36 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 21:36 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 21:36 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 21:36 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 21:36 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 21:36 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 21:36 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 21:36 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 21:36 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 21:36 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 21:36 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 21:36 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 21:36 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 21:36 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 21:36 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 21:36 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 21:36 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 21:36 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 21:36 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 21:36 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 21:36 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 21:36 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 21:36 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 21:36 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 21:36 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 21:36 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 21:36 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 21:36 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 21:36 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 21:36 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 21:36 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 21:36 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 21:36 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 93 of 105 PAGE: 17 of 29 ONE LAB. NATIONWIDE. MW-13 SAMPLE RESULTS - 08 Collected date/time: 05/17/19 15:50 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/2019 21:36 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/2019 21:36 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 21:36 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 21:36 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 21:36 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 21:36 WG1287536 (S)Toluene-d8 90.3 80.0-120 051281201921:36 WG1287536 (S) 4-Bromof/uorobenzene 99.1 77.0-126 0512812019 21:36 WG1287536 (S 1,2-Dich/oroethane-d4 87.3 70.0-130 0512812019 2136 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 94 of 105 PAGE: 18 of 29 S W - D SAMPLE RESULTS - 09 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 07:35 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 21:56 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 21:56 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 21:56 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 21:56 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 21:56 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 21:56 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 21:56 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 21:56 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 21:56 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 21:56 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 21:56 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 21:56 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 21:56 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 21:56 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 21:56 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 21:56 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 21:56 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 21:56 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 21:56 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 21:56 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 21:56 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 21:56 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 21:56 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 21:56 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 21:56 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 21:56 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 21:56 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 21:56 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 21:56 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 21:56 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 21:56 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 21:56 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 21:56 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 21:56 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 21:56 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 21:56 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 21:56 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 21:56 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 21:56 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 21:56 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 21:56 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 21:56 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 21:56 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 21:56 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 21:56 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 21:56 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 21:56 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 21:56 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 21:56 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 21:56 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 21:56 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 21:56 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 21:56 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 21:56 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 21:56 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 21:56 WG1287536 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 95 of 105 PAGE: 19 of 29 ACCOUNT: Pace Analytical - Huntersville, NC PROJECT: SDG: DATE/TIME: 92429869 L1101606 06/10/19 16:54 ONE LAB. NATIONWIDE. SW-D SAMPLE RESULTS - 09 Collected date/time: 05/17/19 07:35 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/2019 21:56 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/2019 21:56 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 21:56 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/2019 21:56 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/2019 21:56 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 21:56 WG1287536 (SToluene-d8 93.1 80.0-120 051281201921.56 WG1287536 (S 4-Bromof/uorobenzene 101 77.0-126 0512812019 21.56 WG1287536 (S 1,2-Dich/oroethane-d4 88.7 70.0-130 0512812019 21.56 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 Fp FTc FS Fn N Fc F, FAI FSC Page 96 of 105 PAGE: 20 of 29 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101606-02,03,04,05,06,07,08,09 Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Acetone U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromochloromethane U Bromoform U Bromomethane U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U 2-Hexanone U p-Isopropyltoluene U 2-Butanone (MEK) U MB Qualifier MB MDL MB RDL ug/I ug/I 10.0 50.0 1.87 10.0 0.331 1.00 0.352 1.00 0.380 1.00 0.520 5.00 0.469 1.00 0.866 5.00 0.379 1.00 0.348 1.00 0.327 1.00 0.453 5.00 0.324 5.00 0.276 2.50 0.375 1.00 0.351 1.00 1.33 5.00 0.381 1.00 0.346 1.00 0.349 1.00 0.220 1.00 0.274 1.00 0.551 5.00 0.259 1.00 0.361 1.00 0.398 1.00 0.260 1.00 0.396 1.00 0.306 1.00 0.352 1.00 0.366 1.00 0.418 1.00 0.419 1.00 0.321 1.00 0.320 1.00 0.384 1.00 0.256 1.00 3.82 10.0 0.350 1.00 3.93 10.0 FP1 FTC FSS [Cn] FSr �GI FAI FSC Page 97 of 105 PAGE: 21 of 29 ACCOUNT: Pace Analytical - Huntersville, NC PROJECT: SDG: DATE/TIME: 92429869 L1101606 06/10/19 16:54 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101606-02,03,04,05,06,07,08,09 Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U Vinyl acetate U Vinyl chloride U Xylenes, Total U o-Xylene U m&p-Xylenes U 1,4-Dioxane U (S) Toluene-d8 90.2 (S) 4-Bromof/uorobenzene 96.6 (S) 1,2-Dich/oroethone-d4 86.2 MB Qualifier MB MDL ug/I Laboratory Control Sample (LCS) 1.00 2.14 0.367 1.00 0.307 0.385 0.130 0.372 0.412 0.230 0.355 0.319 0.383 0.398 1.20 0.807 1.63 0.259 1.06 0.341 0.719 36.0 MB RDL ug/I 5.00 10.0 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 2.50 10.0 1.00 3.00 1.00 2.00 100 80.0-120 77.0-126 70.0-130 (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Acetone 125 143 114 19.0-160 Acrylonitrile 125 149 120 55.0-149 Benzene 25.0 26.7 107 70.0-123 Bromobenzene 25.0 22.1 88.5 73.0-121 Bromodichloromethane 25.0 27.3 109 75.0-120 Bromochloromethane 25.0 23.8 95.3 76.0-122 Bromoform 25.0 24.1 96.4 68.0-132 Bromomethane 25.0 12.9 51.7 10.0-160 FP1 FTC FSS 4 Cn FSr �GI FAI FSC Page 98 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 22 of 29 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101606-02,03,04,05,06,07,08,09 Laboratory Control Sample (LCS) (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Carbon tetrachloride 25.0 27.1 108 68.0-126 Chlorobenzene 25.0 24.5 98.1 80.0-121 Chlorodibromomethane 25.0 24.7 99.0 77.0-125 Chloroethane 25.0 23.1 92.3 47.0-150 Chloroform 25.0 26.9 108 73.0-120 Chloromethane 25.0 16.0 63.9 41.0-142 2-Chlorotoluene 25.0 22.0 87.9 76.0-123 4-Chlorotoluene 25.0 23.2 92.8 75.0-122 1,2-Dibromo-3-Chloropropane 25.0 22.4 89.6 58.0-134 1,2-Dibromoethane 25.0 25.1 100 80.0-122 Dibromomethane 25.0 26.6 107 80.0-120 1,2-Dichlorobenzene 25.0 24.4 97.6 79.0-121 1,3-Dichlorobenzene 25.0 23.1 92.4 79.0-120 1,4-Dichlorobenzene 25.0 22.6 90.6 79.0-120 Dichlorodifluoromethane 25.0 27.7 111 51.0-149 1,1-Dichloroethane 25.0 26.5 106 70.0-126 1,2-Dichloroethane 25.0 24.7 98.9 70.0-128 1,1-Dichloroethene 25.0 27.2 109 71.0-124 cis-1,2-Dichloroethene 25.0 27.7 111 73.0-120 trans-1,2-Dichloroethene 25.0 28.0 112 73.0-120 1,2-Dichloropropane 25.0 26.9 107 77.0-125 1,1-Dichloropropene 25.0 27.5 110 74.0-126 1,3-Dichloropropane 25.0 25.2 101 80.0-120 cis-1,3-Dichloropropene 25.0 28.1 112 80.0-123 trans-1,3-Dichloropropene 25.0 24.1 96.5 78.0-124 2,2-Dichloropropane 25.0 25.5 102 58.0-130 Di -isopropyl ether 25.0 26.8 107 58.0-138 Ethylbenzene 25.0 24.9 99.7 79.0-123 Hexachloro-1,3-butadiene 25.0 20.4 81.7 54.0-138 2-Hexanone 125 137 110 67.0-149 p-Isopropyltoluene 25.0 21.8 87.4 76.0-125 2-Butanone (MEK) 125 139 111 44.0-160 Methylene Chloride 25.0 26.3 105 67.0-120 4-Methyl-2-pentanone (MIBK) 125 126 100 68.0-142 Methyl tert-butyl ether 25.0 27.8 111 68.0-125 Naphthalene 25.0 22.6 90.2 54.0-135 Styrene 25.0 24.7 98.7 73.0-130 1,1,1,2-Tetrachloroethane 25.0 24.6 98.4 75.0-125 1,1,2,2-Tetrachloroethane 25.0 23.3 93.3 65.0-130 Tetrachloroethene 25.0 25.5 102 72.0-132 FP1 FTC FSS 4 Cn FSr �GI FAI FSC Page 99 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 23 of 29 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result Analyte ug/I ug/I Toluene 25.0 23.7 1,2,3-Trichlorobenzene 25.0 22.4 1,2,4-Trichlorobenzene 25.0 23.2 1,1,1-Trichloroethane 25.0 27.5 1,1,2-Trichloroethane 25.0 24.2 Trichloroethene 25.0 28.1 Trichlorofluoromethane 25.0 28.7 1,2,3-Trichloropropane 25.0 24.4 Vinyl acetate 125 134 Vinyl chloride 25.0 27.6 Xylenes, Total 75.0 71.6 o-Xylene 25.0 24.1 m&p-Xylenes 50.0 47.5 (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Laboratory Control Sample (LCS) LCS Rec 94.7 89.4 92.9 110 96.9 112 115 97.6 107 95.5 96.3 95.0 90.3 102 100 QUALITY CONTROL SUMMARY L1101606-02,03,04,05,06,07,08,09 Rec. Limits LCS Qualifier 79.0-120 50.0-138 57.0-137 73.0-124 80.0-120 78.0-124 59.0-147 73.0-130 11.0-160 67.0-131 79.0-123 80.0-122 80.0-122 80.0-120 77.0-126 70.0-130 ONE LAB. NATIONWIDE. FP1 FTC] IS-S] 4 Cn rs-r �GI rAl FSC (LCS) R3416175-2 05/28/1914:33 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % 1,4-Dioxane 1000 1100 110 13.0-160 (S) Toluene-d8 90.6 80.0-120 (S)4-Bromofluorobenzene 100 77.0-126 (S)1,2-Dich/oroethane-d4 86.4 70.0-130 Page 100 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 24 of 29 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE. The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions CP IP FTC MDL Method Detection Limit. RDL Reported Detection Limit. FSS Rec. Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. [Cn] Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. FSr U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes Fc reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or FAI duplicated within these ranges. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and FSC potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description J The identification of the analyte is acceptable; the reported value is an estimate. J0 JO: The identification of the analyte is acceptable, but the reported concentration is an estimate. The calibration met method criteria. Page 101 of 105 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:54 25 of 29 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT ND OR MN T ID T WI NY SD WY MI NV T NE IA OH T PA T f IL Ills WV vA UT T CA�� T KS MO KY W 11110 � NM O� AR N Sc T MS A`7L GA T TX * LA T AK T T q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:54 ME Page 102 of 105 PAGE: 26 of 29 Chain of Custody C! Samples were sent directly to the Subcontracting Laboratory. Workorder: 92429869 Workorder Name: SURRY CO. LINED MSWI_F 1171 State Of Origin: NC Cert. Needed: n Yes C No Owner Received Date: 5/2012019 K-�;a?eAnalyficaI »ww.pacelabs.cvm Results Requested By: 6/4/2019 i 4fn § Su Angela Baioni Pace Analytical Charlotte National ° 9800 Kincey Ave. Suite 100 Pace Huntersville, NC 28078 12pC5 Lebanon Rd 4 X. Phone (704)875-9092 Mt jtaiiet, TN 37122 615-758-5858 0 P r ne N �' a a Sample Collect - e Re m Sample II7 Type Date/Time . Lab ID Mal ' a ' z LAB USE ONLY 1 MW-1 PS 5/17/2019 13:00 92429869001 Water X l i 6 b -61 2 MW-2 PS 5/17/2019 08:50 92429869002 Water X D 3 MW-3R PS 5117/2019 08A5 92429869003 Water X 0 4 Mw-4S PS 5/17/2019 08:35 92429869004 Water X 0 5 MW4D PS 5/17/2019 08A0 92429869005 Water X O 6 MW-9D PS 5/17/2019 00:00 92429869006 Water X d�Q 7 MW-11D PS 5/17/2019 00:00 92429869007 Water X 07 8 MWA3 PS 5117/201915:50 92429869008 Water X 04 9 SW-D PS 5/17/2019 07:35 92429869009 Water X 6 Transfers Released By Datefrhm ecellwd By DatelTirne S 1 �} 2 3 L 51 -b Cooler Temperature on Receipt I - °C Custody Seal Y or NZ I Received on Ice Y or N Samples Intac Y r N ***In order to maintain client confiden i fity, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. RAD SCREEN: <0.5 mWhr Tuesday, May 21, 2019 2:23:45 Pall FMT-ALL-C-002rev.00 24March2009 Page lbfd A ' 10 03 m c m N O� E # O w ll} O o � F 4 Y it Q } K O H Q O m Q J w W H Z F°- 4 m � U y CD U) w r Z C O CD m 4 U O W c9 c a, cn c ❑ Q W m a _U C } p m C E L O N A a ❑ a` m C- M a ❑ m N (n w vIn ❑ (IA o m a� -o c n CD a w o 0 mro m m L 0 U I Z U rt p E4 � O uY N d O N 3 Q Q C C � C77 � 'C c 0 r C 0 G7 Oa O a N Q .0 0 C j Ocr � Q1 al N (n af (n w .5 C m E m .7 a CD w .0 d it N 0 z Page 104 of 1 m m a Pace Analytical National Center for Testing & Innovation Cooler Receipt Form Client: SDG#: Cooler Received/Opened On: 5/ Z tJ19 Temperature: Received By: Jordan Harris Signature: Receipt Check List NP Yes No COC Seal Present / Intact? ' COC Signed / Accurate? / Bottles arrive intact? Correct bottles used? Sufficient volume sent? If Applicable VOA Zero headspace? / Preservation Correct / Checked? Page 105 of 105 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 June 10, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: Surry Lined MW-1 Pace Project No.: 92429869 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on May 20, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. A revised laboratory report is being submitted on 6/10/19 to include a revised subcontract laboratory report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services r.Q _Kok Q REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Surry Lined MW-1 Pace Project No.: 92429869 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Surry Lined MW-1 Pace Project No.: 92429869 Lab ID Sample ID Matrix Date Collected Date Received 92429869001 MW-1 Water 05/17/1913:00 05/20/1911:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Surry Lined MW-1 Pace Project No.: 92429869 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92429869001 MW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Surry Lined MW-1 Pace Project No.: 92429869 Sample: MW-1 Lab ID: 92429869001 Collected: 05/17/19 13:00 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:12 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:12 7440-38-2 Barium 13.7 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:12 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:12 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-47-3 Cobalt 5.6 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-48-4 Copper 3.OJ ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7439-92-1 Nickel 7.9 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:12 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:12 7440-62-2 Zinc 14.3 ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:12 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium 0.078J ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:26 7440-28-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/10/2019 05:13 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Lined MW-1 Pace Project No.: 92429869 QC Batch: 478300 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92429869001 METHOD BLANK: 2589492 Associated Lab Samples: 92429869001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 05/31/1919:09 Arsenic ug/L ND 10.0 5.0 05/31/1919:09 Barium ug/L ND 5.0 2.5 05/31/1919:09 Beryllium ug/L ND 1.0 0.50 05/31/1919:09 Cadmium ug/L ND 1.0 0.50 05/31/1919:09 Chromium ug/L ND 5.0 2.5 05/31/1919:09 Cobalt ug/L ND 5.0 2.5 05/31/1919:09 Copper ug/L ND 5.0 2.5 05/31/1919:09 Lead ug/L ND 5.0 2.5 05/31/1919:09 Nickel ug/L ND 5.0 2.5 05/31/1919:09 Selenium ug/L ND 10.0 5.0 05/31/1919:09 Silver ug/L ND 5.0 2.5 05/31/1919:09 Vanadium ug/L ND 5.0 2.5 05/31/1919:09 Zinc ug/L ND 10.0 5.0 05/31/1919:09 LABORATORY CONTROL SAMPLE: Parameter 2589493 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 487 97 80-120 Arsenic ug/L 500 466 93 80-120 Barium ug/L 500 495 99 80-120 Beryllium ug/L 500 496 99 80-120 Cadmium ug/L 500 489 98 80-120 Chromium ug/L 500 497 99 80-120 Cobalt ug/L 500 490 98 80-120 Copper ug/L 500 502 100 80-120 Lead ug/L 500 484 97 80-120 Nickel ug/L 500 486 97 80-120 Selenium ug/L 500 481 96 80-120 Silver ug/L 250 251 100 80-120 Vanadium ug/L 500 497 99 80-120 Zinc ug/L 500 478 96 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589494 2589495 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 486 499 97 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/10/2019 05:13 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Surry Lined MW-1 92429869 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589494 2589495 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 485 496 97 99 75-125 2 20 Barium ug/L 253 500 500 750 759 99 101 75-125 1 20 Beryllium ug/L ND 500 500 502 515 100 103 75-125 2 20 Cadmium ug/L ND 500 500 483 489 97 98 75-125 1 20 Chromium ug/L ND 500 500 497 506 99 101 75-125 2 20 Cobalt ug/L 21.4 500 500 507 515 97 99 75-125 1 20 Copper ug/L ND 500 500 526 537 105 107 75-125 2 20 Lead ug/L ND 500 500 480 488 96 98 75-125 2 20 Nickel ug/L 5.2 500 500 486 495 96 98 75-125 2 20 Selenium ug/L ND 500 500 515 521 103 104 75-125 1 20 Silver ug/L ND 250 250 250 255 100 102 75-125 2 20 Vanadium ug/L ND 500 500 508 518 102 104 75-125 2 20 Zinc ug/L ND 500 500 475 482 94 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/10/2019 05:13 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Surry Lined MW-1 Pace Project No.: 92429869 QC Batch: 478331 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92429869001 METHOD BLANK: 2589562 Matrix: Water Associated Lab Samples: 92429869001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 06/06/19 02:29 LABORATORY CONTROL SAMPLE: 2589563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589564 2589565 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.6 10.0 96 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/10/2019 05:13 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Surry Lined MW-1 Pace Project No.: 92429869 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/10/2019 05:13 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 28 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Surry Lined MW-1 Pace Project No.: 92429869 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92429869001 MW-1 EPA 3010A 478300 EPA 6010D 478326 92429869001 MW-1 EPA 3010A 478331 EPA 6020B 478572 Date: 06/10/2019 05:13 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 28 Document Name: Document Revised: February 7, 2018 a Sample Condition Upon Receipt(SCUR) Page 1 of 2 ::a3CBARc?�jlCr3I Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: / Asheville ElEden❑ Greenwood ❑ Fluntersvilllp•.o-_ RalPiohf-1 ° - Client Name: WO# : 92429869 -UponReceipt l,2 Project II � I�� III II III I II I I �If Courier: ❑Fe Ex I ❑UPS / ❑USPS ❑Client ❑ Commercial LnPace ❑Other; 92429869 Custody Seal Present? ❑Yes � 0 Seals Intact? Des Elmo c Date/Initials Person Examining contents; Packing Material: ❑Bubble Wrap au6ble Bags ❑None ❑ Other Biological Tissue Frozen? Therrhortleter []Yes 2 o ❑N/A {R Gun ID: 92TQ48 TVPe of Ice: Wet ❑elue ❑Nave Cooler Temp ('C): V 1� Correctlon Factor: Add/Subtract (°C) 0.0 �, � Temp should be above freezing to 6°C Cooler Ternp Corrected Co.. []Samples out of temp criteria, Samples on ice, cooling process hasbegun USDA Regulated Soil ( N/A, water sample) Did samples origi to In a quarantine zone within the united States: CA, NY, or SC (check maps)? Did samplesorlginate from a foreign source {internationally, ❑Yes Na indudingHawaii and Puerto Rlco]7 ❑Yes ❑N❑ _. Corltments/Discre❑anew Chain of Custody Present? Ves ❑N❑ ❑N/A 1. Samples Arrived within Hold Time? Yes ❑N❑ ❑N/A 2. Short Hold Time Analysis (572 hr.)? ❑yes [ to ❑N/A 3. Rush Turn Around Time Requested? ❑Yes o N/A SufficientVolume? es ❑No Correct Containers Used? ❑No -Pace Containers Used? �es E es ❑No Containers Intact?DVes ❑No ❑N/ 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No N/A 8, Sample Labels Match CDC? p_res ❑No ❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: Headspace in VDA Vials (>5-6mm)? Des 0 ❑N/A 10. Trip Blank Present? ❑Yes o [)N/A 11. Trip Elan kCustody Seals Present? ©Yes [)No /A MENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes ❑No Lot ID of split containers: CLIENT NOTIFIfA71CiN/RE54LUTION Person contacted: _ �Lt�(` t����EitJ{ � �'� � Dake/Tlme: �✓�i f 5���.-� �'G} � ` 1 Project Manager SCURF Review; Project Manager SRF Review: r] Date: 6'a ) - I I Date: f5 a l—A q Page 11 of 28 Document Name: AnalAcal' SampleConditlon Upon Recei Document No.: F-CAR-CS-033-Rev.06 Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas QualitV Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8U15 (water) DOC, LLHg "Bottom half of box is to list dumber of bottle Project $w0# : 92429869 PM: AMB Due Dale: 06/04/19 CLIENT: 92-Municipal r 1 -�z 'O m Q.n `a E 7 b a 9 a a E rev ro ii ti v a E 7 a m Z E c 7 4 m ry V O = a N J, a °° ry n O a CL 'n i 4 m 2 ,n ¢ INZ a E N a m R G _ a E N ,ti V 6 m N a c ro —° a o E d y} Z Z c E ¢ .a Q V a u E 4 .a L? a a �- a w a E ¢ Qn ry l7 ¢ 2 ry s E ¢ = ,-, l7 a N 6 O 2 E ¢ o �n N m a ii ¢ 2 x a a aE Z E 2 a ¢ ; O n 7 m E o a S m a aCM rn Z ¢ >O E [� Y 7 ¢ 2 4 O 7 E o Y ? 2 O i Q > E o 9 Q1 b d ? vi N Y ? Q > Z y ' a MiL :Y a " LY7 > a ry Q Z N = u, E 0 N N h ^ u ro a t E a w N i4 N m n1 Q N r 2 V a E o M ry m m ¢ z n ] d m c v b ¢ E 0 o H p dt 2 m c a = E o ry 7 7 z H tv v u c c m E E a a 7 6 l _ 2 4 � 3 4 � S l fi 7 7 B 9 1 � 10 11 12 pH Adjustment Log for Preserved Samples sample IO Type of Preservative pH upon receipt pate preservation adjusted Time preservation Amount of Preservative d]usted Lot k a added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNRCertiflcation Out of hold, incorrect preservative, out of temp, incorrect containers. Page 12 of 28 -4 m 0 A w n� ITEM# Q n Z 3 'E ^ 0 a hr 1 Ln x° m M 2 3on Wy `m V 7 ID 19 r+ O W 13 7 0 m o s _ a ° ❑ ^ x 7 N a rn .I �u N N y _p � � a = v � � p ➢ � -4 a H OD�O:9 yA�r rm o m n ;. id O Ox a °° �i ll m 2 G a MATRIX CODE (see Yalid codes to !e9) Z z O n P 0 D V7 G1 0 0 0 0 0 SAMPLETYPE (G-GRAB C=COMP) 3Cn � m CDo o a. n _ N A , CA5 y .� a z z (��I o �. m o m 3 / rn O -11 a Z z O Cl n 03 i3� �� ❑ m Z r v r Z a Q m rn c SAMPLE TEMP AT COLLECTION C i1 4 ^i m � # OF CONTAINERS 9 N ci m a C> D o � eta � a n 0 K C �, m. Un reserved p a m H2SO4 Z 5�� G r m0 ! HNO3 7) m C D 0 w w w w w w w w w w w w HCI ° r 2 m ' n •'• n p� O y NaOH p: a C� n n Na2S203 m D m 1 m Melhanol m rn z ❑ rn —� -� Other CD 1 'n Analyses Test YIN cn m m ❑ x x x x x x x x x x x x VOCs-82o0App 1 z ro 2 y (D x x m 1 D0 x x x x x x x Melals-App I Z ro N t} I Z x x x x x x x x x x x x Turbidity z L c D (� 2 U) c x x x x x x x x 1,4-Dioxare (Non-SIh1) a m M a O m C ° r 13 M \w a CL 2 n m m � � m z M m 'TEMP in C a d. C m m 4 K �a � o Q � Received an e Ce(YIN) m �3 O Cuslody Seafed Z �] Cooler (YIN) 2 Samples Intact rn \' (YIN) I 4 t L Page 13 of 28 aceAnal ical ° A f �l A L Y T CAL REPORT National Center for Testing &Innovation June 10, 2019 FTc FSS Pace Analytical - Huntersville, NC Sample Delivery Group: L1101606 [Cn] Samples Received: 05/22/2019 FrProject Number: 92429869 Description: Surry Co. Lined MSWLF FC Site: 001 GI Report To: Angela Baioni 9800 Kincey Avenue, Suite 100 rAl Huntersville, NC 28078 Fc Entire Report Reviewed By: �vUnn �v, �. L L111-� Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. i 10 it Page 14 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 1 of 15 A TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page Tc: Table of Contents Ss: Sample Summary Cn: Case Narrative Sr: Sample Results MW-1 L1101606-01 Qc: Quality Control Summary Volatile Organic Compounds (GC/MS) by Method 8260D GI: Glossary of Terms Al: Accreditations & Locations Sc: Sample Chain of Custody CID 2 3 4 FS5 5 [Cn] 7 7 Fr 11 12 RC 13 F, rAI FSC Page 15 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:06 2 of 15 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time MW-1 L1101606-01 GW 05/17/1913:00 05/22/1908:45 C P Method Volatile Organic Compounds (GC/MS) by Method 8260D Batch Dilution Preparation Analysis Analyst Location I—J date/time date/time FT,] WG1287536 1 05/28/1919:16 05/28/1919:16 DWR Mt. Juliet, TN [Cn] FSr RC F, FAI FSC Page 16 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:06 3 of 15 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. VV VV� � �t La�'_ Nancy McLain Project Manager FP1 FTC FSS FSr FC-1 F, FAI FSC Page 17 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:06 4 of 15 M W-1 SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 13:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 19:16 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 19:16 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 19:16 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 19:16 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 19:16 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 19:16 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 19:16 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 19:16 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 19:16 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 19:16 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 19:16 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 19:16 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 19:16 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 19:16 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 19:16 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 19:16 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 19:16 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 19:16 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 19:16 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 19:16 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 19:16 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 19:16 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 19:16 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 19:16 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 19:16 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 19:16 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 19:16 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 19:16 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 19:16 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 19:16 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 19:16 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 19:16 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 19:16 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 19:16 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 19:16 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 19:16 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 19:16 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 19:16 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 19:16 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 19:16 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 19:16 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 19:16 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 19:16 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 19:16 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 19:16 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 19:16 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 19:16 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 19:16 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 19:16 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 19:16 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 19:16 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 19:16 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 19:16 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 19:16 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 19:16 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 19:16 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 18 of 28 PAGE: 5 of 15 ONE LAB. NATIONWIDE. MW-1 SAMPLE RESULTS - 01 Collected date/time: 05/17/19 13:00 L1101606 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201919:16 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201919:16 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 19:16 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201919:16 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201919:16 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201919:16 WG1287536 (S) Toluene-d8 90.9 80.0-120 051281201919.16 WG1287536 (S) 4-Bromof/uorobenzene 99.7 77.0-126 051281201919.16 WG1287536 (S) 1,2-Dich/oroethane-d4 86.5 70.0-130 0512812019 19.16 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:06 Fp FTc FS Fn Fc F, FAI FSC Page 19 of 28 PAGE: 6 of 15 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101606-01 Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Acetone U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromochloromethane U Bromoform U Bromomethane U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U 2-Hexanone U p-Isopropyltoluene U 2-Butanone (MEK) U MB Qualifier MB MDL ug/I 10.0 1.87 0.331 0.352 0.380 0.520 0.469 0.866 0.379 0.348 0.327 0.453 0.324 0.276 0.375 0.351 1.33 0.381 0.346 0.349 0.220 0.274 0.551 0.259 0.361 0.398 0.260 0.396 0.306 0.352 0.366 0.418 0.419 0.321 0.320 0.384 0.256 3.82 0.350 3.93 MB RDL ug/I 50.0 10.0 1.00 1.00 1.00 5.00 1.00 5.00 1.00 1.00 1.00 5.00 5.00 2.50 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 10.0 1.00 10.0 FP1 FTC FSS [Cn] FSr �GI FAI FSC Page 20 of 28 PAGE: 7of15 ACCOUNT: Pace Analytical - Huntersville, NC PROJECT: SDG: DATE/TIME: 92429869 L1101606 06/10/19 16:06 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U Vinyl acetate U Vinyl chloride U Xylenes, Total U o-Xylene U m&p-Xylenes U 1,4-Dioxane U (S) Toluene-d8 90.2 (S) 4-Bromof/uorobenzene 96.6 (S) 1,2-Dich/oroethone-d4 86.2 MB Qualifier MB MDL ug/I Laboratory Control Sample (LCS) 1.00 2.14 0.367 1.00 0.307 0.385 0.130 0.372 0.412 0.230 0.355 0.319 0.383 0.398 1.20 0.807 1.63 0.259 1.06 0.341 0.719 36.0 QUALITY CONTROL SUMMARY L1101606-01 MB RDL ug/I 5.00 10.0 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 2.50 10.0 1.00 3.00 1.00 2.00 100 80.0-120 77.0-126 70.0-130 (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Acetone 125 143 114 19.0-160 Acrylonitrile 125 149 120 55.0-149 Benzene 25.0 26.7 107 70.0-123 Bromobenzene 25.0 22.1 88.5 73.0-121 Bromodichloromethane 25.0 27.3 109 75.0-120 Bromochloromethane 25.0 23.8 95.3 76.0-122 Bromoform 25.0 24.1 96.4 68.0-132 Bromomethane 25.0 12.9 51.7 10.0-160 ONE LAB. NATIONWIDE. FP1 FTC FSS 4 Cn FSr �GI FAI FSC Page 21 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 8 of 15 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) QUALITY CONTROL SUMMARY L1101606-01 (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Carbon tetrachloride 25.0 27.1 108 68.0-126 Chlorobenzene 25.0 24.5 98.1 80.0-121 Chlorodibromomethane 25.0 24.7 99.0 77.0-125 Chloroethane 25.0 23.1 92.3 47.0-150 Chloroform 25.0 26.9 108 73.0-120 Chloromethane 25.0 16.0 63.9 41.0-142 2-Chlorotoluene 25.0 22.0 87.9 76.0-123 4-Chlorotoluene 25.0 23.2 92.8 75.0-122 1,2-Dibromo-3-Chloropropane 25.0 22.4 89.6 58.0-134 1,2-Dibromoethane 25.0 25.1 100 80.0-122 Dibromomethane 25.0 26.6 107 80.0-120 1,2-Dichlorobenzene 25.0 24.4 97.6 79.0-121 1,3-Dichlorobenzene 25.0 23.1 92.4 79.0-120 1,4-Dichlorobenzene 25.0 22.6 90.6 79.0-120 Dichlorodifluoromethane 25.0 27.7 111 51.0-149 1,1-Dichloroethane 25.0 26.5 106 70.0-126 1,2-Dichloroethane 25.0 24.7 98.9 70.0-128 1,1-Dichloroethene 25.0 27.2 109 71.0-124 cis-1,2-Dichloroethene 25.0 27.7 111 73.0-120 trans-1,2-Dichloroethene 25.0 28.0 112 73.0-120 1,2-Dichloropropane 25.0 26.9 107 77.0-125 1,1-Dichloropropene 25.0 27.5 110 74.0-126 1,3-Dichloropropane 25.0 25.2 101 80.0-120 cis-1,3-Dichloropropene 25.0 28.1 112 80.0-123 trans-1,3-Dichloropropene 25.0 24.1 96.5 78.0-124 2,2-Dichloropropane 25.0 25.5 102 58.0-130 Di -isopropyl ether 25.0 26.8 107 58.0-138 Ethylbenzene 25.0 24.9 99.7 79.0-123 Hexachloro-1,3-butadiene 25.0 20.4 81.7 54.0-138 2-Hexanone 125 137 110 67.0-149 p-Isopropyltoluene 25.0 21.8 87.4 76.0-125 2-Butanone (MEK) 125 139 111 44.0-160 Methylene Chloride 25.0 26.3 105 67.0-120 4-Methyl-2-pentanone (MIBK) 125 126 100 68.0-142 Methyl tert-butyl ether 25.0 27.8 111 68.0-125 Naphthalene 25.0 22.6 90.2 54.0-135 Styrene 25.0 24.7 98.7 73.0-130 1,1,1,2-Tetrachloroethane 25.0 24.6 98.4 75.0-125 1,1,2,2-Tetrachloroethane 25.0 23.3 93.3 65.0-130 Tetrachloroethene 25.0 25.5 102 72.0-132 ONE LAB. NATIONWIDE. FP1 FTC FSS 4 Cn FSr �GI FAI FSC Page 22 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 9 of 15 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result Analyte ug/I ug/I Toluene 25.0 23.7 1,2,3-Trichlorobenzene 25.0 22.4 1,2,4-Trichlorobenzene 25.0 23.2 1,1,1-Trichloroethane 25.0 27.5 1,1,2-Trichloroethane 25.0 24.2 Trichloroethene 25.0 28.1 Trichlorofluoromethane 25.0 28.7 1,2,3-Trichloropropane 25.0 24.4 Vinyl acetate 125 134 Vinyl chloride 25.0 27.6 Xylenes, Total 75.0 71.6 o-Xylene 25.0 24.1 m&p-Xylenes 50.0 47.5 (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Laboratory Control Sample (LCS) LCS Rec 94.7 89.4 92.9 110 96.9 112 115 97.6 107 95.5 96.3 95.0 90.3 102 100 QUALITY CONTROL SUMMARY L1101606-01 Rec. Limits LCS Qualifier 79.0-120 50.0-138 57.0-137 73.0-124 80.0-120 78.0-124 59.0-147 73.0-130 11.0-160 67.0-131 79.0-123 80.0-122 80.0-122 80.0-120 77.0-126 70.0-130 ONE LAB. NATIONWIDE. FP1 FTC] IS-S] 4 Cn rs-r �GI rAl FSC (LCS) R3416175-2 05/28/1914:33 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % 1,4-Dioxane 1000 1100 110 13.0-160 (S) Toluene-d8 90.6 80.0-120 (S)4-Bromofluorobenzene 100 77.0-126 (S)1,2-Dich/oroethane-d4 86.4 70.0-130 Page 23 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 10 of 15 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE. The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions CP IP FTC MDL Method Detection Limit. RDL Reported Detection Limit. FSS Rec. Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. [Cn] Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. FSr U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes Fc reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or FAI duplicated within these ranges. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and FSC potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description JO JO: The identification of the analyte is acceptable, but the reported concentration is an estimate. The calibration met method criteria. Page 24 of 28 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429869 L1101606 06/10/19 16:06 11 of 15 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT ND OR MN T ID T WI NY SD WY MI NV T NE IA OH T PA T f IL Ills WV vA UT T CA�� T KS MO KY W 11110 � NM O� AR N Sc T MS A`7L GA T TX * LA T AK T T q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429869 L1101606 06/10/19 16:06 ME Page 25 of 28 PAGE: 12 of 15 Chain of Custody C! Samples were sent directly to the Subcontracting Laboratory. Workorder: 92429869 Workorder Name: SURRY CO. LINED MSWI_F 1171 State Of Origin: NC Cert. Needed: n Yes C No Owner Received Date: 5/2012019 K-�;a?eAnalyficaI »ww.pacelabs.cvm Results Requested By: 6/4/2019 i 4fn § Su Angela Baioni Pace Analytical Charlotte National ° 9800 Kincey Ave. Suite 100 Pace Huntersville, NC 28078 12pC5 Lebanon Rd 4 X. Phone (704)875-9092 Mt jtaiiet, TN 37122 615-758-5858 0 P r ne N �' a a Sample Collect - e Re m Sample II7 Type Date/Time . Lab ID Mal ' a ' z LAB USE ONLY 1 MW-1 PS 5/17/2019 13:00 92429869001 Water X l i 6 b -61 2 MW-2 PS 5/17/2019 08:50 92429869002 Water X D 3 MW-3R PS 5117/2019 08A5 92429869003 Water X 0 4 Mw-4S PS 5/17/2019 08:35 92429869004 Water X 0 5 MW4D PS 5/17/2019 08A0 92429869005 Water X O 6 MW-9D PS 5/17/2019 00:00 92429869006 Water X d�Q 7 MW-11D PS 5/17/2019 00:00 92429869007 Water X 07 8 MWA3 PS 5117/201915:50 92429869008 Water X 04 9 SW-D PS 5/17/2019 07:35 92429869009 Water X 6 Transfers Released By Datefrhm ecellwd By DatelTirne S 1 �} 2 3 L 51 -b Cooler Temperature on Receipt I - °C Custody Seal Y or NZ I Received on Ice Y or N Samples Intac Y r N ***In order to maintain client confiden i fity, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. RAD SCREEN: <0.5 mWhr Tuesday, May 21, 2019 2:23:45 Pall FMT-ALL-C-002rev.00 24March2009 gagaegA of181 10 03 m c m N O� E # O w ll} O o � F 4 Y it Q } K O H Q O m Q J w W H Z F°- 4 m � U y CD U) w r Z C O CD m 4 U O W c9 c a, cn c ❑ Q W m a _U C } p m C E L O N A a ❑ a` m C- M a ❑ m N (n w vIn ❑ (IA o m a� -o c n CD a w o 0 mro m m L 0 U I Z U rt p E4 � O uY N d O N 3 Q Q C C � C77 � 'C c 0 r C 0 G7 Oa O a N Q .0 0 C j Ocr � Q1 al N (n af (n w .5 C m E m .7 a CD w .0 d it N 0 z Page 27 of m m a Pace Analytical National Center for Testing & Innovation Cooler Receipt Form Client: SDG#: Cooler Received/Opened On: 5/ Z tJ19 Temperature: Received By: Jordan Harris Signature: Receipt Check List NP Yes No COC Seal Present / Intact? ' COC Signed / Accurate? / Bottles arrive intact? Correct bottles used? Sufficient volume sent? If Applicable VOA Zero headspace? / Preservation Correct / Checked? Page 28 of 28 lacieAnalXical" www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 July 05, 2019 Mr. Jonathan Pfohl Municipal Engineering Services 68 Shipwash Dr. Garner, NC 27529 RE: Project: SURRY MSWLF SWS Pace Project No.: 92429863 Dear Mr. Pfohl: Enclosed are the analytical results for sample(s) received by the laboratory on May 20, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Angela Baioni angela.baioni@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Maddie German, Municipal Engineering Services r.Q _Kok Q REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 65 lacmnalytical' www.pacelabs.corn Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: SURRY MSWLF SWS Pace Project No.: 92429863 Pace Analytical National Certification IDs 12065 Lebanon Road, Mt. Juliet, TN 37122 Alabama Certification #: 40660 Alaska Certification 17-026 Arizona Certification #: AZ0612 Arkansas Certification #: 88-0469 California Certification #: 2932 Canada Certification #: 1461.01 Colorado Certification #: TN00003 Connecticut Certification #: PH-0197 DOD Certification: #1461.01 EPA# TN00003 Florida Certification #: E87487 Georgia DW Certification #: 923 Georgia Certification: NELAP Idaho Certification #: TN00003 Illinois Certification #: 200008 Indiana Certification #: C-TN-01 Iowa Certification #: 364 Kansas Certification #: E-10277 Kentucky UST Certification #: 16 Kentucky Certification #: 90010 Louisiana Certification #: A130792 Louisiana DW Certification #: LA180010 Maine Certification #: TN0002 Maryland Certification #: 324 Massachusetts Certification #: M-TNO03 Michigan Certification #: 9958 Minnesota Certification #: 047-999-395 Mississippi Certification #: TN00003 Missouri Certification #: 340 Montana Certification M CERT0086 Nebraska Certification #: NE-OS-15-05 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS Nevada Certification #: TN-03-2002-34 New Hampshire Certification #: 2975 New Jersey Certification #: TNO02 New Mexico DW Certification New York Certification #: 11742 North Carolina Aquatic Toxicity Certification #: 41 North Carolina Drinking Water Certification #: 21704 North Carolina Environmental Certificate #: 375 North Dakota Certification #: R-140 Ohio VAP Certification #: CL0069 Oklahoma Certification #: 9915 Oregon Certification #: TN200002 Pennsylvania Certification #: 68-02979 Rhode Island Certification #: LA000356 South Carolina Certification #: 84004 South Dakota Certification Tennessee DW/Chem/Micro Certification #: 2006 Texas Mold Certification #: LAB0152 Texas Certification #: T 104704245-17-14 USDA Soil Permit #: P330-15-00234 Utah Certification #: TN00003 Vermont Dept. of Health: ID# VT-2006 Virginia Certification #: VT2006 Virginia Certification #: 460132 Washington Certification #: C847 West Virginia Certification #: 233 Wisconsin Certification #: 9980939910 Wyoming UST Certification #: via A21-A 2926.01 A21-A-ISO 17025 Certification #: 1461.01 A21-A-ISO 17025 Certification #: 1461.02 AIHA-LAP/LLC EMLAP Certification #:100789 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: SURRY MSWLF SWS Pace Project No.: 92429863 Lab ID Sample ID Matrix Date Collected Date Received 92429863001 SW-1 Water 05/17/1911:19 05/20/1911:26 92429863002 SW-2 Water 05/17/1912:00 05/20/1911:26 92429863003 SW-3 Water 05/17/1914:35 05/20/1911:26 92429863004 SW-4 Water 05/17/1916:15 05/20/1911:26 92429863005 SWN-1 Water 05/17/1915:34 05/20/1911:26 92429863006 SWN-2 Water 05/17/1916:53 05/20/1911:26 92429863007 SW-C Water 05/17/19 08:43 05/20/19 11:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: SURRY MSWLF SWS 92429863 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92429863001 SW-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN 92429863002 SW-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN 92429863003 SW-3 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN 92429863004 SW-4 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN 92429863005 SWN-1 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN 92429863006 SWN-2 EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D BMB 65 PAN 92429863007 SW-C EPA 601OD SH1 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D DWR 65 PAN REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-1 Lab ID: 92429863001 Collected: 05/17/19 11:19 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:45 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:45 7440-38-2 Barium 23.1 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:45 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:45 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:45 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:45 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:45 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 03:58 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 17:15 05/28/19 17:15 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 17:15 05/28/19 17:15 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 17:15 05/28/19 17:15 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 17:15 05/28/19 17:15 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 17:15 05/28/19 17:15 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 17:15 05/28/19 17:15 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 17:15 05/28/19 17:15 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 17:15 05/28/19 17:15 74-83-9 CC Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 17:15 05/28/19 17:15 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 17:15 05/28/19 17:15 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 17:15 05/28/19 17:15 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 17:15 05/28/19 17:15 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 17:15 05/28/19 17:15 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 17:15 05/28/19 17:15 74-87-3 CC 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 17:15 05/28/19 17:15 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 17:15 05/28/19 17:15 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 17:15 05/28/19 17:15 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 17:15 05/28/19 17:15 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 17:15 05/28/19 17:15 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 17:15 05/28/19 17:15 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 17:15 05/28/19 17:15 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 17:15 05/28/19 17:15 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 17:15 05/28/19 17:15 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 17:15 05/28/19 17:15 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 17:15 05/28/19 17:15 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 17:15 05/28/19 17:15 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 17:15 05/28/19 17:15 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-1 Lab ID: 92429863001 Collected: 05/17/19 11:19 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1917:15 05/28/1917:15 156-60-5 ND ug/L 1.00 0.306 1 05/28/1917:15 05/28/1917:15 78-87-5 ND ug/L 1.00 0.352 1 05/28/1917:15 05/28/1917:15 563-58-6 ND ug/L 1.00 0.366 1 05/28/1917:15 05/28/1917:15 142-28-9 ND ug/L 1.00 0.418 1 05/28/1917:15 05/28/1917:15 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1917:15 05/28/1917:15 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1917:15 05/28/1917:15 594-20-7 ND ug/L 1.00 0.320 1 05/28/1917:15 05/28/1917:15 108-20-3 ND ug/L 1.00 0.384 1 05/28/1917:15 05/28/1917:15 100-41-4 ND ug/L 1.00 0.256 1 05/28/1917:15 05/28/1917:15 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1917:15 05/28/1917:15 591-78-6 ND ug/L 1.00 0.350 1 05/28/1917:15 05/28/1917:15 99-87-6 ND ug/L 10.0 3.93 1 05/28/1917:15 05/28/1917:15 78-93-3 ND ug/L 5.00 1.00 1 05/28/1917:15 05/28/1917:15 75-09-2 ND ug/L 10.0 2.14 1 05/28/1917:15 05/28/1917:15 108-10-1 ND ug/L 1.00 0.367 1 05/28/1917:15 05/28/1917:15 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1917:15 05/28/1917:15 91-20-3 ND ug/L 1.00 0.307 1 05/28/1917:15 05/28/1917:15 100-42-5 ND ug/L 1.00 0.385 1 05/28/1917:15 05/28/1917:15 630-20-6 ND ug/L 1.00 0.130 1 05/28/1917:15 05/28/1917:15 79-34-5 ND ug/L 1.00 0.372 1 05/28/1917:15 05/28/1917:15 127-18-4 ND ug/L 1.00 0.412 1 05/28/1917:15 05/28/1917:15 108-88-3 ND ug/L 1.00 0.230 1 05/28/1917:15 05/28/1917:15 87-61-6 ND ug/L 1.00 0.355 1 05/28/1917:15 05/28/1917:15 120-82-1 ND ug/L 1.00 0.319 1 05/28/1917:15 05/28/1917:15 71-55-6 ND ug/L 1.00 0.383 1 05/28/1917:15 05/28/1917:15 79-00-5 ND ug/L 1.00 0.398 1 05/28/1917:15 05/28/1917:15 79-01-6 ND ug/L 5.00 1.20 1 05/28/1917:15 05/28/1917:15 75-69-4 ND ug/L 2.50 0.807 1 05/28/1917:15 05/28/1917:15 96-18-4 ND ug/L 10.0 1.63 1 05/28/1917:15 05/28/1917:15 108-05-4 ND ug/L 1.00 0.259 1 05/28/1917:15 05/28/1917:15 75-01-4 ND ug/L 1.00 0.341 1 05/28/1917:15 05/28/1917:15 95-47-6 ND ug/L 2.00 0.719 1 05/28/1917:15 05/28/1917:15 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1917:15 05/28/1917:15 1330-20-7 ND ug/L 100 36.0 1 05/28/1917:15 05/28/1917:15 123-91-1 90.3 % 80.0-120 1 05/28/1917:15 05/28/1917:15 2037-26-5 98.3 % 77.0-126 1 05/28/1917:15 05/28/1917:15 460-00-4 88.6 % 70.0-130 1 05/28/1917:15 05/28/1917:15 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-2 Lab ID: 92429863002 Collected: 05/17/19 12:00 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:54 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:54 7440-38-2 Barium 23.1 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:54 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:54 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-47-3 Cobalt 19.9 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:54 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:54 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:54 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:01 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 17:35 05/28/19 17:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 17:35 05/28/19 17:35 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 17:35 05/28/19 17:35 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 17:35 05/28/19 17:35 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 17:35 05/28/19 17:35 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 17:35 05/28/19 17:35 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 17:35 05/28/19 17:35 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 17:35 05/28/19 17:35 74-83-9 CC Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 17:35 05/28/19 17:35 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 17:35 05/28/19 17:35 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 17:35 05/28/19 17:35 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 17:35 05/28/19 17:35 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 17:35 05/28/19 17:35 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 17:35 05/28/19 17:35 74-87-3 CC 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 17:35 05/28/19 17:35 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 17:35 05/28/19 17:35 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 17:35 05/28/19 17:35 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 17:35 05/28/19 17:35 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 17:35 05/28/19 17:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 17:35 05/28/19 17:35 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 17:35 05/28/19 17:35 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 17:35 05/28/19 17:35 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 17:35 05/28/19 17:35 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 17:35 05/28/19 17:35 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 17:35 05/28/19 17:35 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 17:35 05/28/19 17:35 75-35-4 cis-1,2-Dichloroethene 4.53 ug/L 1.00 0.260 1 05/28/19 17:35 05/28/19 17:35 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-2 Lab ID: 92429863002 Collected: 05/17/19 12:00 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1917:35 05/28/1917:35 156-60-5 ND ug/L 1.00 0.306 1 05/28/1917:35 05/28/1917:35 78-87-5 ND ug/L 1.00 0.352 1 05/28/1917:35 05/28/1917:35 563-58-6 ND ug/L 1.00 0.366 1 05/28/1917:35 05/28/1917:35 142-28-9 ND ug/L 1.00 0.418 1 05/28/1917:35 05/28/1917:35 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1917:35 05/28/1917:35 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1917:35 05/28/1917:35 594-20-7 ND ug/L 1.00 0.320 1 05/28/1917:35 05/28/1917:35 108-20-3 ND ug/L 1.00 0.384 1 05/28/1917:35 05/28/1917:35 100-41-4 ND ug/L 1.00 0.256 1 05/28/1917:35 05/28/1917:35 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1917:35 05/28/1917:35 591-78-6 ND ug/L 1.00 0.350 1 05/28/1917:35 05/28/1917:35 99-87-6 ND ug/L 10.0 3.93 1 05/28/1917:35 05/28/1917:35 78-93-3 ND ug/L 5.00 1.00 1 05/28/1917:35 05/28/1917:35 75-09-2 ND ug/L 10.0 2.14 1 05/28/1917:35 05/28/1917:35 108-10-1 ND ug/L 1.00 0.367 1 05/28/1917:35 05/28/1917:35 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1917:35 05/28/1917:35 91-20-3 ND ug/L 1.00 0.307 1 05/28/1917:35 05/28/1917:35 100-42-5 ND ug/L 1.00 0.385 1 05/28/1917:35 05/28/1917:35 630-20-6 ND ug/L 1.00 0.130 1 05/28/1917:35 05/28/1917:35 79-34-5 ND ug/L 1.00 0.372 1 05/28/1917:35 05/28/1917:35 127-18-4 ND ug/L 1.00 0.412 1 05/28/1917:35 05/28/1917:35 108-88-3 ND ug/L 1.00 0.230 1 05/28/1917:35 05/28/1917:35 87-61-6 ND ug/L 1.00 0.355 1 05/28/1917:35 05/28/1917:35 120-82-1 ND ug/L 1.00 0.319 1 05/28/1917:35 05/28/1917:35 71-55-6 ND ug/L 1.00 0.383 1 05/28/1917:35 05/28/1917:35 79-00-5 ND ug/L 1.00 0.398 1 05/28/1917:35 05/28/1917:35 79-01-6 ND ug/L 5.00 1.20 1 05/28/1917:35 05/28/1917:35 75-69-4 ND ug/L 2.50 0.807 1 05/28/1917:35 05/28/1917:35 96-18-4 ND ug/L 10.0 1.63 1 05/28/1917:35 05/28/1917:35 108-05-4 1.08 ug/L 1.00 0.259 1 05/28/1917:35 05/28/1917:35 75-01-4 ND ug/L 1.00 0.341 1 05/28/1917:35 05/28/1917:35 95-47-6 ND ug/L 2.00 0.719 1 05/28/1917:35 05/28/1917:35 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1917:35 05/28/1917:35 1330-20-7 ND ug/L 100 36.0 1 05/28/1917:35 05/28/1917:35 123-91-1 91.3 % 80.0-120 1 05/28/1917:35 05/28/1917:35 2037-26-5 100 % 77.0-126 1 05/28/1917:35 05/28/1917:35 460-00-4 88.0 % 70.0-130 1 05/28/1917:35 05/28/1917:35 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-3 Lab ID: 92429863003 Collected: 05/17/19 14:35 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 19:57 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:57 7440-38-2 Barium 17.8 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:57 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 19:57 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:57 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 19:57 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 19:57 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:08 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 17:55 05/28/19 17:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 17:55 05/28/19 17:55 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 17:55 05/28/19 17:55 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 17:55 05/28/19 17:55 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 17:55 05/28/19 17:55 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 17:55 05/28/19 17:55 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 17:55 05/28/19 17:55 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 17:55 05/28/19 17:55 74-83-9 CC Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 17:55 05/28/19 17:55 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 17:55 05/28/19 17:55 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 17:55 05/28/19 17:55 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 17:55 05/28/19 17:55 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 17:55 05/28/19 17:55 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 17:55 05/28/19 17:55 74-87-3 CC 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 17:55 05/28/19 17:55 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 17:55 05/28/19 17:55 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 17:55 05/28/19 17:55 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 17:55 05/28/19 17:55 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 17:55 05/28/19 17:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 17:55 05/28/19 17:55 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 17:55 05/28/19 17:55 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 17:55 05/28/19 17:55 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 17:55 05/28/19 17:55 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 17:55 05/28/19 17:55 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 17:55 05/28/19 17:55 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 17:55 05/28/19 17:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 17:55 05/28/19 17:55 156-59-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-3 Lab ID: 92429863003 Collected: 05/17/19 14:35 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1917:55 05/28/1917:55 156-60-5 ND ug/L 1.00 0.306 1 05/28/1917:55 05/28/1917:55 78-87-5 ND ug/L 1.00 0.352 1 05/28/1917:55 05/28/1917:55 563-58-6 ND ug/L 1.00 0.366 1 05/28/1917:55 05/28/1917:55 142-28-9 ND ug/L 1.00 0.418 1 05/28/1917:55 05/28/1917:55 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1917:55 05/28/1917:55 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1917:55 05/28/1917:55 594-20-7 ND ug/L 1.00 0.320 1 05/28/1917:55 05/28/1917:55 108-20-3 ND ug/L 1.00 0.384 1 05/28/1917:55 05/28/1917:55 100-41-4 ND ug/L 1.00 0.256 1 05/28/1917:55 05/28/1917:55 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1917:55 05/28/1917:55 591-78-6 ND ug/L 1.00 0.350 1 05/28/1917:55 05/28/1917:55 99-87-6 ND ug/L 10.0 3.93 1 05/28/1917:55 05/28/1917:55 78-93-3 ND ug/L 5.00 1.00 1 05/28/1917:55 05/28/1917:55 75-09-2 ND ug/L 10.0 2.14 1 05/28/1917:55 05/28/1917:55 108-10-1 ND ug/L 1.00 0.367 1 05/28/1917:55 05/28/1917:55 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1917:55 05/28/1917:55 91-20-3 ND ug/L 1.00 0.307 1 05/28/1917:55 05/28/1917:55 100-42-5 ND ug/L 1.00 0.385 1 05/28/1917:55 05/28/1917:55 630-20-6 ND ug/L 1.00 0.130 1 05/28/1917:55 05/28/1917:55 79-34-5 ND ug/L 1.00 0.372 1 05/28/1917:55 05/28/1917:55 127-18-4 ND ug/L 1.00 0.412 1 05/28/1917:55 05/28/1917:55 108-88-3 ND ug/L 1.00 0.230 1 05/28/1917:55 05/28/1917:55 87-61-6 ND ug/L 1.00 0.355 1 05/28/1917:55 05/28/1917:55 120-82-1 ND ug/L 1.00 0.319 1 05/28/1917:55 05/28/1917:55 71-55-6 ND ug/L 1.00 0.383 1 05/28/1917:55 05/28/1917:55 79-00-5 ND ug/L 1.00 0.398 1 05/28/1917:55 05/28/1917:55 79-01-6 ND ug/L 5.00 1.20 1 05/28/1917:55 05/28/1917:55 75-69-4 ND ug/L 2.50 0.807 1 05/28/1917:55 05/28/1917:55 96-18-4 ND ug/L 10.0 1.63 1 05/28/1917:55 05/28/1917:55 108-05-4 ND ug/L 1.00 0.259 1 05/28/1917:55 05/28/1917:55 75-01-4 ND ug/L 1.00 0.341 1 05/28/1917:55 05/28/1917:55 95-47-6 ND ug/L 2.00 0.719 1 05/28/1917:55 05/28/1917:55 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1917:55 05/28/1917:55 1330-20-7 ND ug/L 100 36.0 1 05/28/1917:55 05/28/1917:55 123-91-1 92.6 % 80.0-120 1 05/28/1917:55 05/28/1917:55 2037-26-5 102 % 77.0-126 1 05/28/1917:55 05/28/1917:55 460-00-4 89.2 % 70.0-130 1 05/28/1917:55 05/28/1917:55 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-4 Lab ID: 92429863004 Collected: 05/17/19 16:15 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:00 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:00 7440-38-2 Barium 17.7 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:00 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:00 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:00 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:00 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:00 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:12 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 18:15 05/28/19 18:15 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 18:15 05/28/19 18:15 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 18:15 05/28/19 18:15 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 18:15 05/28/19 18:15 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 18:15 05/28/19 18:15 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 18:15 05/28/19 18:15 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 18:15 05/28/19 18:15 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 18:15 05/28/19 18:15 74-83-9 Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 18:15 05/28/19 18:15 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 18:15 05/28/19 18:15 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 18:15 05/28/19 18:15 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 18:15 05/28/19 18:15 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 18:15 05/28/19 18:15 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 18:15 05/28/19 18:15 74-87-3 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 18:15 05/28/19 18:15 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 18:15 05/28/19 18:15 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 18:15 05/28/19 18:15 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 18:15 05/28/19 18:15 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 18:15 05/28/19 18:15 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 18:15 05/28/19 18:15 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 18:15 05/28/19 18:15 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 18:15 05/28/19 18:15 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 18:15 05/28/19 18:15 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 18:15 05/28/19 18:15 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 18:15 05/28/19 18:15 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 18:15 05/28/19 18:15 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 18:15 05/28/19 18:15 156-59-2 REPORT OF LABORATORY ANALYSIS CC CC This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-4 Lab ID: 92429863004 Collected: 05/17/19 16:15 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1918:15 05/28/1918:15 156-60-5 ND ug/L 1.00 0.306 1 05/28/1918:15 05/28/1918:15 78-87-5 ND ug/L 1.00 0.352 1 05/28/1918:15 05/28/1918:15 563-58-6 ND ug/L 1.00 0.366 1 05/28/1918:15 05/28/1918:15 142-28-9 ND ug/L 1.00 0.418 1 05/28/1918:15 05/28/1918:15 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1918:15 05/28/1918:15 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1918:15 05/28/1918:15 594-20-7 ND ug/L 1.00 0.320 1 05/28/1918:15 05/28/1918:15 108-20-3 ND ug/L 1.00 0.384 1 05/28/1918:15 05/28/1918:15 100-41-4 ND ug/L 1.00 0.256 1 05/28/1918:15 05/28/1918:15 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1918:15 05/28/1918:15 591-78-6 ND ug/L 1.00 0.350 1 05/28/1918:15 05/28/1918:15 99-87-6 ND ug/L 10.0 3.93 1 05/28/1918:15 05/28/1918:15 78-93-3 ND ug/L 5.00 1.00 1 05/28/1918:15 05/28/1918:15 75-09-2 ND ug/L 10.0 2.14 1 05/28/1918:15 05/28/1918:15 108-10-1 ND ug/L 1.00 0.367 1 05/28/1918:15 05/28/1918:15 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1918:15 05/28/1918:15 91-20-3 ND ug/L 1.00 0.307 1 05/28/1918:15 05/28/1918:15 100-42-5 ND ug/L 1.00 0.385 1 05/28/1918:15 05/28/1918:15 630-20-6 ND ug/L 1.00 0.130 1 05/28/1918:15 05/28/1918:15 79-34-5 ND ug/L 1.00 0.372 1 05/28/1918:15 05/28/1918:15 127-18-4 ND ug/L 1.00 0.412 1 05/28/1918:15 05/28/1918:15 108-88-3 ND ug/L 1.00 0.230 1 05/28/1918:15 05/28/1918:15 87-61-6 ND ug/L 1.00 0.355 1 05/28/1918:15 05/28/1918:15 120-82-1 ND ug/L 1.00 0.319 1 05/28/1918:15 05/28/1918:15 71-55-6 ND ug/L 1.00 0.383 1 05/28/1918:15 05/28/1918:15 79-00-5 ND ug/L 1.00 0.398 1 05/28/1918:15 05/28/1918:15 79-01-6 ND ug/L 5.00 1.20 1 05/28/1918:15 05/28/1918:15 75-69-4 ND ug/L 2.50 0.807 1 05/28/1918:15 05/28/1918:15 96-18-4 ND ug/L 10.0 1.63 1 05/28/1918:15 05/28/1918:15 108-05-4 ND ug/L 1.00 0.259 1 05/28/1918:15 05/28/1918:15 75-01-4 ND ug/L 1.00 0.341 1 05/28/1918:15 05/28/1918:15 95-47-6 ND ug/L 2.00 0.719 1 05/28/1918:15 05/28/1918:15 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1918:15 05/28/1918:15 1330-20-7 ND ug/L 100 36.0 1 05/28/1918:15 05/28/1918:15 123-91-1 89.0 % 80.0-120 1 05/28/1918:15 05/28/1918:15 2037-26-5 99.5 % 77.0-126 1 05/28/1918:15 05/28/1918:15 460-00-4 86.5 % 70.0-130 1 05/28/1918:15 05/28/1918:15 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SWN-1 Lab ID: 92429863005 Collected: 05/17/19 15:34 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:03 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:03 7440-38-2 Barium 16.0 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:03 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:03 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:03 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:03 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:03 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:15 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 18:35 05/28/19 18:35 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 18:35 05/28/19 18:35 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 18:35 05/28/19 18:35 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 18:35 05/28/19 18:35 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 18:35 05/28/19 18:35 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 18:35 05/28/19 18:35 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 18:35 05/28/19 18:35 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 18:35 05/28/19 18:35 74-83-9 Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 18:35 05/28/19 18:35 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 18:35 05/28/19 18:35 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 18:35 05/28/19 18:35 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 18:35 05/28/19 18:35 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 18:35 05/28/19 18:35 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 18:35 05/28/19 18:35 74-87-3 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 18:35 05/28/19 18:35 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 18:35 05/28/19 18:35 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 18:35 05/28/19 18:35 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 18:35 05/28/19 18:35 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 18:35 05/28/19 18:35 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 18:35 05/28/19 18:35 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 18:35 05/28/19 18:35 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 18:35 05/28/19 18:35 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 18:35 05/28/19 18:35 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 18:35 05/28/19 18:35 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 18:35 05/28/19 18:35 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 18:35 05/28/19 18:35 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 18:35 05/28/19 18:35 156-59-2 REPORT OF LABORATORY ANALYSIS CC CC This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SWN-1 Lab ID: 92429863005 Collected: 05/17/19 15:34 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1918:35 05/28/1918:35 156-60-5 ND ug/L 1.00 0.306 1 05/28/1918:35 05/28/1918:35 78-87-5 ND ug/L 1.00 0.352 1 05/28/1918:35 05/28/1918:35 563-58-6 ND ug/L 1.00 0.366 1 05/28/1918:35 05/28/1918:35 142-28-9 ND ug/L 1.00 0.418 1 05/28/1918:35 05/28/1918:35 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1918:35 05/28/1918:35 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1918:35 05/28/1918:35 594-20-7 ND ug/L 1.00 0.320 1 05/28/1918:35 05/28/1918:35 108-20-3 ND ug/L 1.00 0.384 1 05/28/1918:35 05/28/1918:35 100-41-4 ND ug/L 1.00 0.256 1 05/28/1918:35 05/28/1918:35 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1918:35 05/28/1918:35 591-78-6 ND ug/L 1.00 0.350 1 05/28/1918:35 05/28/1918:35 99-87-6 ND ug/L 10.0 3.93 1 05/28/1918:35 05/28/1918:35 78-93-3 ND ug/L 5.00 1.00 1 05/28/1918:35 05/28/1918:35 75-09-2 ND ug/L 10.0 2.14 1 05/28/1918:35 05/28/1918:35 108-10-1 ND ug/L 1.00 0.367 1 05/28/1918:35 05/28/1918:35 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1918:35 05/28/1918:35 91-20-3 ND ug/L 1.00 0.307 1 05/28/1918:35 05/28/1918:35 100-42-5 ND ug/L 1.00 0.385 1 05/28/1918:35 05/28/1918:35 630-20-6 ND ug/L 1.00 0.130 1 05/28/1918:35 05/28/1918:35 79-34-5 ND ug/L 1.00 0.372 1 05/28/1918:35 05/28/1918:35 127-18-4 ND ug/L 1.00 0.412 1 05/28/1918:35 05/28/1918:35 108-88-3 ND ug/L 1.00 0.230 1 05/28/1918:35 05/28/1918:35 87-61-6 ND ug/L 1.00 0.355 1 05/28/1918:35 05/28/1918:35 120-82-1 ND ug/L 1.00 0.319 1 05/28/1918:35 05/28/1918:35 71-55-6 ND ug/L 1.00 0.383 1 05/28/1918:35 05/28/1918:35 79-00-5 ND ug/L 1.00 0.398 1 05/28/1918:35 05/28/1918:35 79-01-6 ND ug/L 5.00 1.20 1 05/28/1918:35 05/28/1918:35 75-69-4 ND ug/L 2.50 0.807 1 05/28/1918:35 05/28/1918:35 96-18-4 ND ug/L 10.0 1.63 1 05/28/1918:35 05/28/1918:35 108-05-4 ND ug/L 1.00 0.259 1 05/28/1918:35 05/28/1918:35 75-01-4 ND ug/L 1.00 0.341 1 05/28/1918:35 05/28/1918:35 95-47-6 ND ug/L 2.00 0.719 1 05/28/1918:35 05/28/1918:35 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1918:35 05/28/1918:35 1330-20-7 ND ug/L 100 36.0 1 05/28/1918:35 05/28/1918:35 123-91-1 98.2 % 80.0-120 1 05/28/1918:35 05/28/1918:35 2037-26-5 84.2 % 77.0-126 1 05/28/1918:35 05/28/1918:35 460-00-4 69.7 % 70.0-130 1 05/28/1918:35 05/28/1918:35 17060-07-0 SR REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 14 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SWN-2 Lab ID: 92429863006 Collected: 05/17/19 16:53 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:06 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:06 7440-38-2 Barium 17.4 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:06 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:06 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:06 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:06 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:06 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:19 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 11:10 05/28/19 11:10 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 11:10 05/28/19 11:10 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 11:10 05/28/19 11:10 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 11:10 05/28/19 11:10 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 11:10 05/28/19 11:10 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 11:10 05/28/19 11:10 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 11:10 05/28/19 11:10 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 11:10 05/28/19 11:10 74-83-9 Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 11:10 05/28/19 11:10 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 11:10 05/28/19 11:10 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 11:10 05/28/19 11:10 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 11:10 05/28/19 11:10 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 11:10 05/28/19 11:10 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 11:10 05/28/19 11:10 74-87-3 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 11:10 05/28/19 11:10 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 11:10 05/28/19 11:10 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 11:10 05/28/19 11:10 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 11:10 05/28/19 11:10 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 11:10 05/28/19 11:10 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 11:10 05/28/19 11:10 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 11:10 05/28/19 11:10 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 11:10 05/28/19 11:10 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 11:10 05/28/19 11:10 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 11:10 05/28/19 11:10 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 11:10 05/28/19 11:10 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 11:10 05/28/19 11:10 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 11:10 05/28/19 11:10 156-59-2 REPORT OF LABORATORY ANALYSIS CC CC LO This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SWN-2 Lab ID: 92429863006 Collected: 05/17/19 16:53 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1911:10 05/28/1911:10 156-60-5 ND ug/L 1.00 0.306 1 05/28/1911:10 05/28/1911:10 78-87-5 ND ug/L 1.00 0.352 1 05/28/1911:10 05/28/1911:10 563-58-6 ND ug/L 1.00 0.366 1 05/28/1911:10 05/28/1911:10 142-28-9 ND ug/L 1.00 0.418 1 05/28/1911:10 05/28/1911:10 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1911:10 05/28/1911:10 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1911:10 05/28/1911:10 594-20-7 ND ug/L 1.00 0.320 1 05/28/1911:10 05/28/1911:10 108-20-3 ND ug/L 1.00 0.384 1 05/28/1911:10 05/28/1911:10 100-41-4 ND ug/L 1.00 0.256 1 05/28/1911:10 05/28/1911:10 87-68-3 ND ug/L 10.0 3.82 1 05/28/1911:10 05/28/1911:10 591-78-6 ND ug/L 1.00 0.350 1 05/28/1911:10 05/28/1911:10 99-87-6 ND ug/L 10.0 3.93 1 05/28/1911:10 05/28/1911:10 78-93-3 ND ug/L 5.00 1.00 1 05/28/1911:10 05/28/1911:10 75-09-2 ND ug/L 10.0 2.14 1 05/28/1911:10 05/28/1911:10 108-10-1 ND ug/L 1.00 0.367 1 05/28/1911:10 05/28/1911:10 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1911:10 05/28/1911:10 91-20-3 ND ug/L 1.00 0.307 1 05/28/1911:10 05/28/1911:10 100-42-5 ND ug/L 1.00 0.385 1 05/28/1911:10 05/28/1911:10 630-20-6 ND ug/L 1.00 0.130 1 05/28/1911:10 05/28/1911:10 79-34-5 ND ug/L 1.00 0.372 1 05/28/1911:10 05/28/1911:10 127-18-4 ND ug/L 1.00 0.412 1 05/28/1911:10 05/28/1911:10 108-88-3 ND ug/L 1.00 0.230 1 05/28/1911:10 05/28/1911:10 87-61-6 ND ug/L 1.00 0.355 1 05/28/1911:10 05/28/1911:10 120-82-1 ND ug/L 1.00 0.319 1 05/28/1911:10 05/28/1911:10 71-55-6 ND ug/L 1.00 0.383 1 05/28/1911:10 05/28/1911:10 79-00-5 ND ug/L 1.00 0.398 1 05/28/1911:10 05/28/1911:10 79-01-6 ND ug/L 5.00 1.20 1 05/28/1911:10 05/28/1911:10 75-69-4 ND ug/L 2.50 0.807 1 05/28/1911:10 05/28/1911:10 96-18-4 ND ug/L 10.0 1.63 1 05/28/1911:10 05/28/1911:10 108-05-4 ND ug/L 1.00 0.259 1 05/28/1911:10 05/28/1911:10 75-01-4 ND ug/L 1.00 0.341 1 05/28/1911:10 05/28/1911:10 95-47-6 ND ug/L 2.00 0.719 1 05/28/1911:10 05/28/1911:10 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1911:10 05/28/1911:10 1330-20-7 ND ug/L 100 36.0 1 05/28/1911:10 05/28/1911:10 123-91-1 91.8 % 80.0-120 1 05/28/1911:10 05/28/1911:10 2037-26-5 102 % 77.0-126 1 05/28/1911:10 05/28/1911:10 460-00-4 89.1 % 70.0-130 1 05/28/1911:10 05/28/1911:10 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 16 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-C Lab ID: 92429863007 Collected: 05/17/19 08:43 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/31/19 00:08 05/31/19 20:09 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:09 7440-38-2 Barium 18.6 ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:09 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/31/19 00:08 05/31/19 20:09 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:09 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/31/19 00:08 05/31/19 20:09 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/31/19 00:08 05/31/19 20:09 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 06/01/19 01:19 06/06/19 04:22 7440-28-0 VOA (GC/MS) 8260D Analytical Method: EPA 8260D Preparation Method: 8260D Acetone ND ug/L 50.0 10.0 1 05/28/19 18:55 05/28/19 18:55 67-64-1 Acrylonitrile ND ug/L 10.0 1.87 1 05/28/19 18:55 05/28/19 18:55 107-13-1 Benzene ND ug/L 1.00 0.331 1 05/28/19 18:55 05/28/19 18:55 71-43-2 Bromobenzene ND ug/L 1.00 0.352 1 05/28/19 18:55 05/28/19 18:55 108-86-1 Bromochloromethane ND ug/L 5.00 0.520 1 05/28/19 18:55 05/28/19 18:55 74-97-5 Bromodichloromethane ND ug/L 1.00 0.380 1 05/28/19 18:55 05/28/19 18:55 75-27-4 Bromoform ND ug/L 1.00 0.469 1 05/28/19 18:55 05/28/19 18:55 75-25-2 Bromomethane ND ug/L 5.00 0.866 1 05/28/19 18:55 05/28/19 18:55 74-83-9 Carbon tetrachloride ND ug/L 1.00 0.379 1 05/28/19 18:55 05/28/19 18:55 56-23-5 Chlorobenzene ND ug/L 1.00 0.348 1 05/28/19 18:55 05/28/19 18:55 108-90-7 Dibromochloromethane ND ug/L 1.00 0.327 1 05/28/19 18:55 05/28/19 18:55 124-48-1 Chloroethane ND ug/L 5.00 0.453 1 05/28/19 18:55 05/28/19 18:55 75-00-3 Chloroform ND ug/L 5.00 0.324 1 05/28/19 18:55 05/28/19 18:55 67-66-3 Chloromethane ND ug/L 2.50 0.276 1 05/28/19 18:55 05/28/19 18:55 74-87-3 2-Chlorotoluene ND ug/L 1.00 0.375 1 05/28/19 18:55 05/28/19 18:55 95-49-8 4-Chlorotoluene ND ug/L 1.00 0.351 1 05/28/19 18:55 05/28/19 18:55 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.00 1.33 1 05/28/19 18:55 05/28/19 18:55 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 1.00 0.381 1 05/28/19 18:55 05/28/19 18:55 106-93-4 Dibromomethane ND ug/L 1.00 0.346 1 05/28/19 18:55 05/28/19 18:55 74-95-3 1,2-Dichlorobenzene ND ug/L 1.00 0.349 1 05/28/19 18:55 05/28/19 18:55 95-50-1 1,3-Dichlorobenzene ND ug/L 1.00 0.220 1 05/28/19 18:55 05/28/19 18:55 541-73-1 1,4-Dichlorobenzene ND ug/L 1.00 0.274 1 05/28/19 18:55 05/28/19 18:55 106-46-7 Dichlorodifluoromethane ND ug/L 5.00 0.551 1 05/28/19 18:55 05/28/19 18:55 75-71-8 1,1-Dichloroethane ND ug/L 1.00 0.259 1 05/28/19 18:55 05/28/19 18:55 75-34-3 1,2-Dichloroethane ND ug/L 1.00 0.361 1 05/28/19 18:55 05/28/19 18:55 107-06-2 1,1-Dichloroethene ND ug/L 1.00 0.398 1 05/28/19 18:55 05/28/19 18:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.00 0.260 1 05/28/19 18:55 05/28/19 18:55 156-59-2 REPORT OF LABORATORY ANALYSIS CC CC This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: SURRY MSWLF SWS Pace Project No.: 92429863 Sample: SW-C Lab ID: 92429863007 Collected: 05/17/19 08:43 Received: 05/20/19 11:26 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual VOA (GC/MS) 8260D trans-1,2-Dichloroethene 1,2-Dichloropropane 1,1-Dichloropropene 1,3-Dichloropropane cis-1,3-Dichloropropene trans- 1,3-Dichloropropene 2,2-Dichloropropane Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene 2-Hexanone p-Isopropyltoluene 2-Butanone (MEK) Methylene Chloride 4-Methyl-2-pentanone (MIBK) Methyl-tert-butyl ether Naphthalene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetrachloroethene Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane Vinyl acetate Vinyl chloride o-Xylene m&p-Xylene Xylene (Total) 1,4-Dioxane (p-Dioxane) Surrogates Toluene-d8 (S) 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Date: 07/05/2019 02:15 PM Analytical Method: EPA 8260D Preparation Method: 8260D ND ug/L 1.00 0.396 1 05/28/1918:55 05/28/1918:55 156-60-5 ND ug/L 1.00 0.306 1 05/28/1918:55 05/28/1918:55 78-87-5 ND ug/L 1.00 0.352 1 05/28/1918:55 05/28/1918:55 563-58-6 ND ug/L 1.00 0.366 1 05/28/1918:55 05/28/1918:55 142-28-9 ND ug/L 1.00 0.418 1 05/28/1918:55 05/28/1918:55 10061-01-5 ND ug/L 1.00 0.419 1 05/28/1918:55 05/28/1918:55 10061-02-6 ND ug/L 1.00 0.321 1 05/28/1918:55 05/28/1918:55 594-20-7 ND ug/L 1.00 0.320 1 05/28/1918:55 05/28/1918:55 108-20-3 ND ug/L 1.00 0.384 1 05/28/1918:55 05/28/1918:55 100-41-4 ND ug/L 1.00 0.256 1 05/28/1918:55 05/28/1918:55 87-68-3 CC ND ug/L 10.0 3.82 1 05/28/1918:55 05/28/1918:55 591-78-6 ND ug/L 1.00 0.350 1 05/28/1918:55 05/28/1918:55 99-87-6 ND ug/L 10.0 3.93 1 05/28/1918:55 05/28/1918:55 78-93-3 ND ug/L 5.00 1.00 1 05/28/1918:55 05/28/1918:55 75-09-2 ND ug/L 10.0 2.14 1 05/28/1918:55 05/28/1918:55 108-10-1 ND ug/L 1.00 0.367 1 05/28/1918:55 05/28/1918:55 1634-04-4 ND ug/L 5.00 1.00 1 05/28/1918:55 05/28/1918:55 91-20-3 ND ug/L 1.00 0.307 1 05/28/1918:55 05/28/1918:55 100-42-5 ND ug/L 1.00 0.385 1 05/28/1918:55 05/28/1918:55 630-20-6 ND ug/L 1.00 0.130 1 05/28/1918:55 05/28/1918:55 79-34-5 ND ug/L 1.00 0.372 1 05/28/1918:55 05/28/1918:55 127-18-4 ND ug/L 1.00 0.412 1 05/28/1918:55 05/28/1918:55 108-88-3 ND ug/L 1.00 0.230 1 05/28/1918:55 05/28/1918:55 87-61-6 ND ug/L 1.00 0.355 1 05/28/1918:55 05/28/1918:55 120-82-1 ND ug/L 1.00 0.319 1 05/28/1918:55 05/28/1918:55 71-55-6 ND ug/L 1.00 0.383 1 05/28/1918:55 05/28/1918:55 79-00-5 ND ug/L 1.00 0.398 1 05/28/1918:55 05/28/1918:55 79-01-6 ND ug/L 5.00 1.20 1 05/28/1918:55 05/28/1918:55 75-69-4 ND ug/L 2.50 0.807 1 05/28/1918:55 05/28/1918:55 96-18-4 ND ug/L 10.0 1.63 1 05/28/1918:55 05/28/1918:55 108-05-4 ND ug/L 1.00 0.259 1 05/28/1918:55 05/28/1918:55 75-01-4 ND ug/L 1.00 0.341 1 05/28/1918:55 05/28/1918:55 95-47-6 ND ug/L 2.00 0.719 1 05/28/1918:55 05/28/1918:55 179601-23-1 ND ug/L 3.00 1.06 1 05/28/1918:55 05/28/1918:55 1330-20-7 ND ug/L 100 36.0 1 05/28/1918:55 05/28/1918:55 123-91-1 91.4 % 80.0-120 1 05/28/1918:55 05/28/1918:55 2037-26-5 101 % 77.0-126 1 05/28/1918:55 05/28/1918:55 460-00-4 90.7 % 70.0-130 1 05/28/1918:55 05/28/1918:55 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 QC Batch: 478300 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863006, 92429863007 METHOD BLANK: 2589492 Matrix: Water Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863006, 92429863007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 05/31/1919:09 Arsenic ug/L ND 10.0 5.0 05/31/1919:09 Barium ug/L ND 5.0 2.5 05/31/1919:09 Beryllium ug/L ND 1.0 0.50 05/31/1919:09 Cadmium ug/L ND 1.0 0.50 05/31/1919:09 Chromium ug/L ND 5.0 2.5 05/31/1919:09 Cobalt ug/L ND 5.0 2.5 05/31/1919:09 Copper ug/L ND 5.0 2.5 05/31/1919:09 Lead ug/L ND 5.0 2.5 05/31/1919:09 Nickel ug/L ND 5.0 2.5 05/31/1919:09 Selenium ug/L ND 10.0 5.0 05/31/1919:09 Silver ug/L ND 5.0 2.5 05/31/1919:09 Vanadium ug/L ND 5.0 2.5 05/31/1919:09 Zinc ug/L ND 10.0 5.0 05/31/1919:09 LABORATORY CONTROL SAMPLE: Parameter 2589493 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Antimony ug/L 500 487 97 80-120 Arsenic ug/L 500 466 93 80-120 Barium ug/L 500 495 99 80-120 Beryllium ug/L 500 496 99 80-120 Cadmium ug/L 500 489 98 80-120 Chromium ug/L 500 497 99 80-120 Cobalt ug/L 500 490 98 80-120 Copper ug/L 500 502 100 80-120 Lead ug/L 500 484 97 80-120 Nickel ug/L 500 486 97 80-120 Selenium ug/L 500 481 96 80-120 Silver ug/L 250 251 100 80-120 Vanadium ug/L 500 497 99 80-120 Zinc ug/L 500 478 96 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589494 2589495 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 486 499 97 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: SURRY MSWLF SWS 92429863 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589494 2589495 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 485 496 97 99 75-125 2 20 Barium ug/L 253 500 500 750 759 99 101 75-125 1 20 Beryllium ug/L ND 500 500 502 515 100 103 75-125 2 20 Cadmium ug/L ND 500 500 483 489 97 98 75-125 1 20 Chromium ug/L ND 500 500 497 506 99 101 75-125 2 20 Cobalt ug/L 21.4 500 500 507 515 97 99 75-125 1 20 Copper ug/L ND 500 500 526 537 105 107 75-125 2 20 Lead ug/L ND 500 500 480 488 96 98 75-125 2 20 Nickel ug/L 5.2 500 500 486 495 96 98 75-125 2 20 Selenium ug/L ND 500 500 515 521 103 104 75-125 1 20 Silver ug/L ND 250 250 250 255 100 102 75-125 2 20 Vanadium ug/L ND 500 500 508 518 102 104 75-125 2 20 Zinc ug/L ND 500 500 475 482 94 96 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 QC Batch: 478331 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863006, 92429863007 METHOD BLANK: 2589562 Matrix: Water Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863006, 92429863007 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 06/06/19 02:29 LABORATORY CONTROL SAMPLE: 2589563 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2589564 2589565 MS MSD 92429561004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.6 10.0 96 100 75-125 4 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 QC Batch: 1287157 Analysis Method: EPA 8260D QC Batch Method: 8260D Analysis Description: VOA (GC/MS) 8260D Associated Lab Samples: 92429863006 METHOD BLANK: R3415400-3 Associated Lab Samples: 92429863006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Acetone ug/L ND 50.0 10.0 05/28/19 04:50 Acrylonitrile ug/L ND 10.0 1.87 05/28/19 04:50 Benzene ug/L ND 1.00 0.331 05/28/19 04:50 Bromobenzene ug/L ND 1.00 0.352 05/28/19 04:50 Bromodichloromethane ug/L ND 1.00 0.380 05/28/19 04:50 Bromochloromethane ug/L ND 5.00 0.520 05/28/19 04:50 Bromoform ug/L ND 1.00 0.469 05/28/19 04:50 Bromomethane ug/L ND 5.00 0.866 05/28/19 04:50 Carbon tetrachloride ug/L ND 1.00 0.379 05/28/19 04:50 Chlorobenzene ug/L ND 1.00 0.348 05/28/19 04:50 Dibromochloromethane ug/L ND 1.00 0.327 05/28/19 04:50 Chloroethane ug/L ND 5.00 0.453 05/28/19 04:50 Chloroform ug/L ND 5.00 0.324 05/28/19 04:50 Chloromethane ug/L ND 2.50 0.276 05/28/19 04:50 2-Chlorotoluene ug/L ND 1.00 0.375 05/28/19 04:50 4-Chlorotoluene ug/L ND 1.00 0.351 05/28/19 04:50 1,2-Dibromo-3-chloropropane ug/L ND 5.00 1.33 05/28/19 04:50 1,2-Dibromoethane (EDB) ug/L ND 1.00 0.381 05/28/19 04:50 Dibromomethane ug/L ND 1.00 0.346 05/28/19 04:50 1,2-Dichlorobenzene ug/L ND 1.00 0.349 05/28/19 04:50 1,3-Dichlorobenzene ug/L ND 1.00 0.220 05/28/19 04:50 1,4-Dichlorobenzene ug/L ND 1.00 0.274 05/28/19 04:50 Dichlorodifluoromethane ug/L ND 5.00 0.551 05/28/19 04:50 1,1-Dichloroethane ug/L ND 1.00 0.259 05/28/19 04:50 1,2-Dichloroethane ug/L ND 1.00 0.361 05/28/19 04:50 1,1-Dichloroethene ug/L ND 1.00 0.398 05/28/19 04:50 cis-1,2-Dichloroethene ug/L ND 1.00 0.260 05/28/19 04:50 trans-1,2-Dichloroethene ug/L ND 1.00 0.396 05/28/19 04:50 1,2-Dichloropropane ug/L ND 1.00 0.306 05/28/19 04:50 1,1-Dichloropropene ug/L ND 1.00 0.352 05/28/19 04:50 1,3-Dichloropropane ug/L ND 1.00 0.366 05/28/19 04:50 cis-1,3-Dichloropropene ug/L ND 1.00 0.418 05/28/19 04:50 trans- 1,3-Dichloropropene ug/L ND 1.00 0.419 05/28/19 04:50 2,2-Dichloropropane ug/L ND 1.00 0.321 05/28/19 04:50 Diisopropyl ether ug/L ND 1.00 0.320 05/28/19 04:50 Ethylbenzene ug/L ND 1.00 0.384 05/28/19 04:50 Hexachloro-1,3-butadiene ug/L ND 1.00 0.256 05/28/19 04:50 2-Hexanone ug/L ND 10.0 3.82 05/28/19 04:50 p-Isopropyltoluene ug/L ND 1.00 0.350 05/28/19 04:50 2-Butanone (MEK) ug/L ND 10.0 3.93 05/28/19 04:50 Methylene Chloride ug/L ND 5.00 1.00 05/28/19 04:50 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 METHOD BLANK: R3415400-3 Associated Lab Samples: 92429863006 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 2.14 05/28/19 04:50 Methyl-tert-butyl ether ug/L ND 1.00 0.367 05/28/19 04:50 Naphthalene ug/L ND 5.00 1.00 05/28/19 04:50 Styrene ug/L ND 1.00 0.307 05/28/19 04:50 1,1,1,2-Tetrachloroethane ug/L ND 1.00 0.385 05/28/19 04:50 1,1,2,2-Tetrachloroethane ug/L ND 1.00 0.130 05/28/19 04:50 Tetrachloroethene ug/L ND 1.00 0.372 05/28/19 04:50 Toluene ug/L ND 1.00 0.412 05/28/19 04:50 1,2,3-Trichlorobenzene ug/L ND 1.00 0.230 05/28/19 04:50 1,2,4-Trichlorobenzene ug/L ND 1.00 0.355 05/28/19 04:50 1,1,1-Trichloroethane ug/L ND 1.00 0.319 05/28/19 04:50 1,1,2-Trichloroethane ug/L ND 1.00 0.383 05/28/19 04:50 Trichloroethene ug/L ND 1.00 0.398 05/28/19 04:50 Trichlorofluoromethane ug/L ND 5.00 1.20 05/28/19 04:50 1,2,3-Trichloropropane ug/L ND 2.50 0.807 05/28/19 04:50 Vinyl acetate ug/L ND 10.0 1.63 05/28/19 04:50 Vinyl chloride ug/L ND 1.00 0.259 05/28/19 04:50 Xylene (Total) ug/L ND 3.00 1.06 05/28/19 04:50 o-Xylene ug/L ND 1.00 0.341 05/28/19 04:50 m&p-Xylene ug/L ND 2.00 0.719 05/28/19 04:50 1,4-Dioxane (p-Dioxane) ug/L ND 100 36.0 05/28/19 04:50 Toluene-d8 (S) % 93 80.0-120 05/28/19 04:50 4-Bromofluorobenzene (S) % 98.8 77.0-126 05/28/19 04:50 1,2-Dichloroethane-d4 (S) % 89.8 70.0-130 05/28/19 04:50 LABORATORY CONTROL SAMPLE: Parameter R3415400-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Acetone ug/L 125 134 107 19.0-160 Acrylonitrile ug/L 125 148 118 55.0-149 Benzene ug/L 25.0 28.2 113 70.0-123 Bromobenzene ug/L 25.0 22.2 89.0 73.0-121 Bromodichloromethane ug/L 25.0 28.6 115 75.0-120 Bromochloromethane ug/L 25.0 24.7 98.7 76.0-122 Bromoform ug/L 25.0 25.1 100 68.0-132 Bromomethane ug/L 25.0 14.5 58.1 10.0-160 Carbon tetrachloride ug/L 25.0 29.3 117 68.0-126 Chlorobenzene ug/L 25.0 26.3 105 80.0-121 Dibromochloromethane ug/L 25.0 25.7 103 77.0-125 Chloroethane ug/L 25.0 26.2 105 47.0-150 Chloroform ug/L 25.0 28.1 112 73.0-120 Chloromethane ug/L 25.0 12.7 50.9 41.0-142 2-Chlorotoluene ug/L 25.0 22.2 88.8 76.0-123 4-Chlorotoluene ug/L 25.0 23.3 93.3 75.0-122 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 LABORATORY CONTROL SAMPLE: Parameter R3415400-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,2-Dibromo-3-chloropropane ug/L 25.0 21.8 87.4 58.0-134 1,2-Dibromoethane (EDB) ug/L 25.0 27.1 109 80.0-122 Dibromomethane ug/L 25.0 27.4 110 80.0-120 1,2-Dichlorobenzene ug/L 25.0 24.6 98.5 79.0-121 1,3-Dichlorobenzene ug/L 25.0 23.5 94.0 79.0-120 1,4-Dichlorobenzene ug/L 25.0 22.9 91.5 79.0-120 Dichlorodifluoromethane ug/L 25.0 12.4 49.5 51.0-149 LO 1,1-Dichloroethane ug/L 25.0 28.3 113 70.0-126 1,2-Dichloroethane ug/L 25.0 25.9 104 70.0-128 1,1-Dichloroethene ug/L 25.0 30.5 122 71.0-124 cis-1,2-Dichloroethene ug/L 25.0 28.0 112 73.0-120 trans-1,2-Dichloroethene ug/L 25.0 30.0 120 73.0-120 1,2-Dichloropropane ug/L 25.0 27.8 111 77.0-125 1,1-Dichloropropene ug/L 25.0 29.9 119 74.0-126 1,3-Dichloropropane ug/L 25.0 27.1 108 80.0-120 cis-1,3-Dichloropropene ug/L 25.0 29.1 116 80.0-123 trans- 1,3-Dichloropropene ug/L 25.0 25.8 103 78.0-124 2,2-Dichloropropane ug/L 25.0 25.9 104 58.0-130 Diisopropyl ether ug/L 25.0 27.5 110 58.0-138 Ethylbenzene ug/L 25.0 27.0 108 79.0-123 Hexachloro-1,3-butadiene ug/L 25.0 20.9 83.5 54.0-138 2-Hexanone ug/L 125 136 109 67.0-149 p-Isopropyltoluene ug/L 25.0 22.3 89.0 76.0-125 2-Butanone (MEK) ug/L 125 130 104 44.0-160 Methylene Chloride ug/L 25.0 27.3 109 67.0-120 4-Methyl-2-pentanone (MIBK) ug/L 125 127 102 68.0-142 Methyl-tert-butyl ether ug/L 25.0 28.8 115 68.0-125 Naphthalene ug/L 25.0 22.2 88.8 54.0-135 Styrene ug/L 25.0 28.0 112 73.0-130 1,1,1,2-Tetrachloroethane ug/L 25.0 26.1 104 75.0-125 1,1,2,2-Tetrachloroethane ug/L 25.0 23.1 92.4 65.0-130 Tetrachloroethene ug/L 25.0 28.4 114 72.0-132 Toluene ug/L 25.0 25.4 102 79.0-120 1,2,3-Trichlorobenzene ug/L 25.0 22.3 89.1 50.0-138 1,2,4-Trichlorobenzene ug/L 25.0 23.0 91.8 57.0-137 1,1,1-Trichloroethane ug/L 25.0 29.8 119 73.0-124 1,1,2-Trichloroethane ug/L 25.0 25.8 103 80.0-120 Trichloroethene ug/L 25.0 30.5 122 78.0-124 Trichlorofluoromethane ug/L 25.0 32.7 131 59.0-147 1,2,3-Trichloropropane ug/L 25.0 23.9 95.7 73.0-130 Vinyl acetate ug/L 125 113 90.7 11.0-160 Vinyl chloride ug/L 25.0 31.6 126 67.0-131 Xylene (Total) ug/L 75.0 77.1 103 79.0-123 o-Xylene ug/L 25.0 26.0 104 80.0-122 m&p-Xylene ug/L 50.0 51.1 102 80.0-122 Toluene-d8 (S) % 92.2 80.0-120 4-Bromofluorobenzene (S) % 104 77.0-126 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: SURRY MSWLF SWS Pace Project No.: 92429863 LABORATORY CONTROL SAMPLE: R3415400-1 Parameter Units 1,2-Dichloroethane-d4 (S) % LABORATORY CONTROL SAMPLE: R3415400-2 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L Toluene-d8 (S) % 4-Bromofluorobenzene (S) % 1,2-Dichloroethane-d4 (S) % QUALITY CONTROL DATA Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 86.0 70.0-130 Spike LCS Conc. Result 1000 988 LCS % Rec % Rec Limits Qualifiers 98.8 13.0-160 92.0 80.0-120 100 77.0-126 91.5 70.0-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 QC Batch: 1287536 Analysis Method: EPA 8260D QC Batch Method: 8260D Analysis Description: VOA (GC/MS) 8260D Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863007 METHOD BLANK: R3416175-3 Matrix: Water Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863007 Blank Reporting Parameter Units Result Limit MDL Analyzed Acetone ug/L ND 50.0 10.0 05/28/19 15:13 Acrylonitrile ug/L ND 10.0 1.87 05/28/19 15:13 Benzene ug/L ND 1.00 0.331 05/28/19 15:13 Bromobenzene ug/L ND 1.00 0.352 05/28/19 15:13 Bromodichloromethane ug/L ND 1.00 0.380 05/28/19 15:13 Bromochloromethane ug/L ND 5.00 0.520 05/28/19 15:13 Bromoform ug/L ND 1.00 0.469 05/28/19 15:13 Bromomethane ug/L ND 5.00 0.866 05/28/19 15:13 Carbon tetrachloride ug/L ND 1.00 0.379 05/28/19 15:13 Chlorobenzene ug/L ND 1.00 0.348 05/28/19 15:13 Dibromochloromethane ug/L ND 1.00 0.327 05/28/19 15:13 Chloroethane ug/L ND 5.00 0.453 05/28/19 15:13 Chloroform ug/L ND 5.00 0.324 05/28/19 15:13 Chloromethane ug/L ND 2.50 0.276 05/28/19 15:13 2-Chlorotoluene ug/L ND 1.00 0.375 05/28/19 15:13 4-Chlorotoluene ug/L ND 1.00 0.351 05/28/19 15:13 1,2-Dibromo-3-chloropropane ug/L ND 5.00 1.33 05/28/19 15:13 1,2-Dibromoethane (EDB) ug/L ND 1.00 0.381 05/28/19 15:13 Dibromomethane ug/L ND 1.00 0.346 05/28/19 15:13 1,2-Dichlorobenzene ug/L ND 1.00 0.349 05/28/19 15:13 1,3-Dichlorobenzene ug/L ND 1.00 0.220 05/28/19 15:13 1,4-Dichlorobenzene ug/L ND 1.00 0.274 05/28/19 15:13 Dichlorodifluoromethane ug/L ND 5.00 0.551 05/28/19 15:13 1,1-Dichloroethane ug/L ND 1.00 0.259 05/28/19 15:13 1,2-Dichloroethane ug/L ND 1.00 0.361 05/28/19 15:13 1,1-Dichloroethene ug/L ND 1.00 0.398 05/28/19 15:13 cis-1,2-Dichloroethene ug/L ND 1.00 0.260 05/28/19 15:13 trans-1,2-Dichloroethene ug/L ND 1.00 0.396 05/28/19 15:13 1,2-Dichloropropane ug/L ND 1.00 0.306 05/28/19 15:13 1,1-Dichloropropene ug/L ND 1.00 0.352 05/28/19 15:13 1,3-Dichloropropane ug/L ND 1.00 0.366 05/28/19 15:13 cis-1,3-Dichloropropene ug/L ND 1.00 0.418 05/28/19 15:13 trans- 1,3-Dichloropropene ug/L ND 1.00 0.419 05/28/19 15:13 2,2-Dichloropropane ug/L ND 1.00 0.321 05/28/19 15:13 Diisopropyl ether ug/L ND 1.00 0.320 05/28/19 15:13 Ethylbenzene ug/L ND 1.00 0.384 05/28/19 15:13 Hexachloro-1,3-butadiene ug/L ND 1.00 0.256 05/28/19 15:13 2-Hexanone ug/L ND 10.0 3.82 05/28/19 15:13 p-Isopropyltoluene ug/L ND 1.00 0.350 05/28/19 15:13 2-Butanone (MEK) ug/L ND 10.0 3.93 05/28/19 15:13 Methylene Chloride ug/L ND 5.00 1.00 05/28/19 15:13 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 METHOD BLANK: R3416175-3 Matrix: Water Associated Lab Samples: 92429863001, 92429863002, 92429863003, 92429863004, 92429863005, 92429863007 Blank Reporting Parameter Units Result Limit MDL Analyzed 4-Methyl-2-pentanone (MIBK) ug/L ND 10.0 2.14 05/28/19 15:13 Methyl-tert-butyl ether ug/L ND 1.00 0.367 05/28/19 15:13 Naphthalene ug/L ND 5.00 1.00 05/28/19 15:13 Styrene ug/L ND 1.00 0.307 05/28/19 15:13 1,1,1,2-Tetrachloroethane ug/L ND 1.00 0.385 05/28/19 15:13 1,1,2,2-Tetrachloroethane ug/L ND 1.00 0.130 05/28/19 15:13 Tetrachloroethene ug/L ND 1.00 0.372 05/28/19 15:13 Toluene ug/L ND 1.00 0.412 05/28/19 15:13 1,2,3-Trichlorobenzene ug/L ND 1.00 0.230 05/28/19 15:13 1,2,4-Trichlorobenzene ug/L ND 1.00 0.355 05/28/19 15:13 1,1,1-Trichloroethane ug/L ND 1.00 0.319 05/28/19 15:13 1,1,2-Trichloroethane ug/L ND 1.00 0.383 05/28/19 15:13 Trichloroethene ug/L ND 1.00 0.398 05/28/19 15:13 Trichlorofluoromethane ug/L ND 5.00 1.20 05/28/19 15:13 1,2,3-Trichloropropane ug/L ND 2.50 0.807 05/28/19 15:13 Vinyl acetate ug/L ND 10.0 1.63 05/28/19 15:13 Vinyl chloride ug/L ND 1.00 0.259 05/28/19 15:13 Xylene (Total) ug/L ND 3.00 1.06 05/28/19 15:13 o-Xylene ug/L ND 1.00 0.341 05/28/19 15:13 m&p-Xylene ug/L ND 2.00 0.719 05/28/19 15:13 1,4-Dioxane (p-Dioxane) ug/L ND 100 36.0 05/28/19 15:13 Toluene-d8 (S) % 90.2 80.0-120 05/28/19 15:13 4-Bromofluorobenzene (S) % 96.6 77.0-126 05/28/19 15:13 1,2-Dichloroethane-d4 (S) % 86.2 70.0-130 05/28/19 15:13 LABORATORY CONTROL SAMPLE: Parameter R3416175-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Acetone ug/L 125 143 114 19.0-160 Acrylonitrile ug/L 125 149 120 55.0-149 Benzene ug/L 25.0 26.7 107 70.0-123 Bromobenzene ug/L 25.0 22.1 88.5 73.0-121 Bromodichloromethane ug/L 25.0 27.3 109 75.0-120 Bromochloromethane ug/L 25.0 23.8 95.3 76.0-122 Bromoform ug/L 25.0 24.1 96.4 68.0-132 Bromomethane ug/L 25.0 12.9 51.7 10.0-160 Carbon tetrachloride ug/L 25.0 27.1 108 68.0-126 Chlorobenzene ug/L 25.0 24.5 98.1 80.0-121 Dibromochloromethane ug/L 25.0 24.7 99.0 77.0-125 Chloroethane ug/L 25.0 23.1 92.3 47.0-150 Chloroform ug/L 25.0 26.9 108 73.0-120 Chloromethane ug/L 25.0 16.0 63.9 41.0-142 2-Chlorotoluene ug/L 25.0 22.0 87.9 76.0-123 4-Chlorotoluene ug/L 25.0 23.2 92.8 75.0-122 Qualifiers Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: SURRY MSWLF SWS Pace Project No.: 92429863 LABORATORY CONTROL SAMPLE: Parameter R3416175-1 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2-Dibromo-3-chloropropane ug/L 25.0 22.4 89.6 58.0-134 1,2-Dibromoethane (EDB) ug/L 25.0 25.1 100 80.0-122 Dibromomethane ug/L 25.0 26.6 107 80.0-120 1,2-Dichlorobenzene ug/L 25.0 24.4 97.6 79.0-121 1,3-Dichlorobenzene ug/L 25.0 23.1 92.4 79.0-120 1,4-Dichlorobenzene ug/L 25.0 22.6 90.6 79.0-120 Dichlorodifluoromethane ug/L 25.0 27.7 111 51.0-149 1,1-Dichloroethane ug/L 25.0 26.5 106 70.0-126 1,2-Dichloroethane ug/L 25.0 24.7 98.9 70.0-128 1,1-Dichloroethene ug/L 25.0 27.2 109 71.0-124 cis-1,2-Dichloroethene ug/L 25.0 27.7 111 73.0-120 trans-1,2-Dichloroethene ug/L 25.0 28.0 112 73.0-120 1,2-Dichloropropane ug/L 25.0 26.9 107 77.0-125 1,1-Dichloropropene ug/L 25.0 27.5 110 74.0-126 1,3-Dichloropropane ug/L 25.0 25.2 101 80.0-120 cis-1,3-Dichloropropene ug/L 25.0 28.1 112 80.0-123 trans- 1,3-Dichloropropene ug/L 25.0 24.1 96.5 78.0-124 2,2-Dichloropropane ug/L 25.0 25.5 102 58.0-130 Diisopropyl ether ug/L 25.0 26.8 107 58.0-138 Ethylbenzene ug/L 25.0 24.9 99.7 79.0-123 Hexachloro-1,3-butadiene ug/L 25.0 20.4 81.7 54.0-138 2-Hexanone ug/L 125 137 110 67.0-149 p-Isopropyltoluene ug/L 25.0 21.8 87.4 76.0-125 2-Butanone (MEK) ug/L 125 139 111 44.0-160 Methylene Chloride ug/L 25.0 26.3 105 67.0-120 4-Methyl-2-pentanone (MIBK) ug/L 125 126 100 68.0-142 Methyl-tert-butyl ether ug/L 25.0 27.8 111 68.0-125 Naphthalene ug/L 25.0 22.6 90.2 54.0-135 Styrene ug/L 25.0 24.7 98.7 73.0-130 1,1,1,2-Tetrachloroethane ug/L 25.0 24.6 98.4 75.0-125 1,1,2,2-Tetrachloroethane ug/L 25.0 23.3 93.3 65.0-130 Tetrachloroethene ug/L 25.0 25.5 102 72.0-132 Toluene ug/L 25.0 23.7 94.7 79.0-120 1,2,3-Trichlorobenzene ug/L 25.0 22.4 89.4 50.0-138 1,2,4-Trichlorobenzene ug/L 25.0 23.2 92.9 57.0-137 1,1,1-Trichloroethane ug/L 25.0 27.5 110 73.0-124 1,1,2-Trichloroethane ug/L 25.0 24.2 96.9 80.0-120 Trichloroethene ug/L 25.0 28.1 112 78.0-124 Trichlorofluoromethane ug/L 25.0 28.7 115 59.0-147 1,2,3-Trichloropropane ug/L 25.0 24.4 97.6 73.0-130 Vinyl acetate ug/L 125 134 107 11.0-160 Vinyl chloride ug/L 25.0 27.6 111 67.0-131 Xylene (Total) ug/L 75.0 71.6 95.5 79.0-123 o-Xylene ug/L 25.0 24.1 96.3 80.0-122 m&p-Xylene ug/L 50.0 47.5 95.0 80.0-122 Toluene-d8 (S) % 90.3 80.0-120 4-Bromofluorobenzene (S) % 102 77.0-126 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: SURRY MSWLF SWS Pace Project No.: 92429863 LABORATORY CONTROL SAMPLE: R3416175-1 Parameter Units 1,2-Dichloroethane-d4 (S) % LABORATORY CONTROL SAMPLE: R3416175-2 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L Toluene-d8 (S) % 4-Bromofluorobenzene (S) % 1,2-Dichloroethane-d4 (S) % QUALITY CONTROL DATA Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 100 70.0-130 Spike LCS Conc. Result 1000 1100 LCS % Rec % Rec Limits Qualifiers 110 13.0-160 90.6 80.0-120 100 77.0-126 86.4 70.0-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: SURRY MSWLF SWS Pace Project No.: 92429863 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PAN Pace Analytical National PASI-A Pace Analytical Services - Asheville ANALYTE QUALIFIERS CC The continuing calibration for this compound is outside of Pace Analytical acceptance limits. The result may be biased. LO Analyte recovery in the laboratory control sample (LCS) was outside QC limits. SR Surrogate recovery was below laboratory control limits. Results may be biased low. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 65 aceAnalXical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: SURRY MSWLF SWS Pace Project No.: 92429863 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92429863001 SW-1 EPA 3010A 478300 EPA 6010D 478326 92429863002 SW-2 EPA 3010A 478300 EPA 6010D 478326 92429863003 SW-3 EPA 3010A 478300 EPA 6010D 478326 92429863004 SW-4 EPA 3010A 478300 EPA 6010D 478326 92429863005 SWN-1 EPA 3010A 478300 EPA 6010D 478326 92429863006 SWN-2 EPA 3010A 478300 EPA 6010D 478326 92429863007 SW-C EPA 3010A 478300 EPA 6010D 478326 92429863001 SW-1 EPA 3010A 478331 EPA 6020B 478572 92429863002 SW-2 EPA 3010A 478331 EPA 6020B 478572 92429863003 SW-3 EPA 3010A 478331 EPA 6020B 478572 92429863004 SW-4 EPA 3010A 478331 EPA 6020B 478572 92429863005 SWN-1 EPA 3010A 478331 EPA 6020B 478572 92429863006 SWN-2 EPA 3010A 478331 EPA 6020B 478572 92429863007 SW-C EPA 3010A 478331 EPA 6020B 478572 92429863001 SW-1 8260D 1287536 EPA 8260D 1287536 92429863002 SW-2 8260D 1287536 EPA 8260D 1287536 92429863003 SW-3 8260D 1287536 EPA 8260D 1287536 92429863004 SW-4 8260D 1287536 EPA 8260D 1287536 92429863005 SWN-1 8260D 1287536 EPA 8260D 1287536 92429863006 SWN-2 8260D 1287157 EPA 8260D 1287157 92429863007 SW-C 8260D 1287536 EPA 8260D 1287536 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 07/05/2019 02:15 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 65 m aeeAnalyfic Document Name: Sample Condition Upon Receipt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No., F•CAR-CS-033•itev.06 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden[:]Greenwood ❑ Huntersville 2--'Raleigh[] Methanitsville❑ Client Name: Wp# : 92429863 Upon Receipt Project i3 Courier: Fe Ex i UPS USPS ❑Client � []UPS'/ ❑❑ Commercial ace Other: 5 92428883 Custody Seal Present? []Yes No Seals Intact? []Yes la ' {late/Initials Person Examining Content d:- f 5 7C Packing Material: ❑Bubble Wrap 081bble Bags ❑None ❑ Other Biological Tissue Frozen? Therrrtomete►: [-]yes 2 o ❑N/A 1A Gun ID: 92Ta48 Type of ice: let ❑Blue ❑None Cooler Temp ('Q: Correction Factor: Add/Subtract (°C) 0.0 � Temp should be above freezing to 6°C Cooler Temp Corrected ('C): �' ! ❑5amples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated Soil (ZJ/N/A, water sample) Did samples on - to in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally, I—IVPa YINo including Hawaii and Puerto R1col7 ❑Yes ❑No Comments/Discrepancy: Chain of Custody Present? Yes ❑No ❑N/A 1. Samples Arrived within Hold Time? Yes ON. ❑N/A 2. Short Hold Time Analysis (02 hr.)? Oyes Mo ❑NJA 3. Rush Turn Around Time Requested? ❑Oyes.No ❑N/A 4, Sufficient Volume? BY. ❑Na ❑NJA S. Correct Containers Used? 41 ON. [-]NIA 6. -Pace Containers Used? []]Yes ❑No ❑N/A Containers Intact? 0 e5 ON. ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Yes ❑No Z`NJA S. Sample Labels Match COC? ZYes ❑No ❑NJA 9. -includes Date/Time/ID/Analysis Matrix: Headspace in VDA Vials (?5-6mm)? ❑Yes 0 Ca ❑NJA 10. Trip Blank Present? ❑Yes o ❑NJA 11. Trip Blank Custody Seals Present? ❑Yes ❑No ❑K/ COMMENTS/SAMPLE DISCREPANCY Field Data Required? []Yes ❑No CZ Lot ID of split containers: CLII NT NOT IFICATION/RESOLUTION Person contacted: JpiaAtf a I ') ►l_l Date/Time: �uT ffig- I—[ "f r_ Project Manager SCURF Review: Y Project Manager SRF Review: Date: 1� ` I '1 Date:- 1 _-( Pf Page 32 of 65 Document Name: Document Revised: February 7, 2013 a aceAnalytical Sample Condition Upon Receipti[SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-0-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle WO#:92429863 PM: AMB Due Date: 06/0 14/ 9 CLIENT: 92-Municipal E z di 2 a c a E N V m z W 2 a c a E Vl N M m z CV � u a E CZP C3 nr a m a Z. d H o. c a `m 7 .N a rm u N S v 0 = a E N .y J% v a m v m Z & a E N 2 A a m oM Z 0n 0 N a E N .y N w a co N n 2 Z a E N .. V c a ° u � N A {g v o' @ y ? u�. � = Z 9 dl r' a n 7 a E a v e-I 7 �4 l7 d N v a = a E a m — .1 = t9 d z y v n E E a E N t7 d N V a z E a m w de CA d ,v V 2 a G N 2 E a E E 'n IV (A L7 d z v T Z E a N v 4 l7 a 2 u a 4 � E O S l7 n _ a V M ON N a O E p H l7 7 2 a O y E O 7 S7 ] ? V a a O a J E p Q ai W ❑ z x � n N ; a g = Y a 0 > Z H '� A Za .,1+ a 3 '—" hd o > ,�0 Q z u a a n E N H N a En Q ? b a v E O H N a 'A �» v S Z s E N Q Al a cca ? ? Z N C E a J E 0 a i7 Z > O u N E c wA ? z ? Ql 4 c 7 a E E 7 W O 1 , 1 2 � l � 3 X 5 4 \X S ✓ 5 / I ' � 1 7 l I � 9 10 11 12 �sN pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot d Note: Wheneverthere is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina ❑EHNR Certification Office (i.e. out of hold, incorrect preservative, out of temp, incorrect containers. Page 33 of 65 a O 0 z n 3 m m z 3 N A r z Z m A z m 3 m a o n z co O D 0 A m > ' C m E -1 m 1 n im TEMP in C I I I J N a Received on v Ice (Yll m n v Custody Sealed p Cooler (Yfi ` O z Samples Intact N I"' to Iw Im I-4 I- IN IA Iw Im I, IITEM# u � v+yx�rr m MATRIX CODE (see valid codas to left) SAMPLE TYPE (G=GRAB C=COMP) �y m n � � m m n O m m n o m m v 2 v � m m SAMPLE TE PAP AT COLLECTION if OF CONTAINERS Unpreserved H2SO4 (D N m HNO3 HCI NaOH Na25203 N Mall Other Analyses Test YIN JOCs-App 1 z Oplals-App1 Z rurbidity z m m G) n n A N m m n o w N a 0 N C wN b 0' aCLa ro O z 0 Vg W y Ln C m o W o n x ? Cn y m (i 3 m �1 Q v1 ^rr1 m- v n o n 0 V 4! O N V/ P O p H 0 a n 0ro N mO Go d m 3o ' r 00 � n 9. � K �1 _ � mrtm m m � m m N y A 2 (p m C a N rF °w 0 ° O m C w p w T a (D a z n c z W A � 7 4 d d o co o b �n n .c a Page 34 of 65 aceAnal ical ° A f �l A L Y T CAL REPORT National Center for Testing & Innovation May 30, 2019 FTc FSS Pace Analytical - Huntersville, NC Sample Delivery Group: L1101602 [Cn] Samples Received: 05/22/2019 FrProject Number: 92429863 Description: SURRY MSWLF SWS FC Site: 001 GI Report To: Angela Baioni 9800 Kincey Avenue, Suite 100 rAl Huntersville, NC 28078 Fc Entire Report Reviewed By: �vUnn �v, �. L L111-� Nancy McLain Project Manager Results relate only to the items tested or calibrated and are reported as rounded values. This test report shall not be reproduced, except in full, without written approval of the laboratory. Where applicable, sampling conducted by Pace National is performed per guidance provided in laboratory standard operating procedures: 060302, 060303, and 060304. i 41 Page 35 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913.43 1 of 31 A TABLE OF CONTENTS ONE LAB. NATIONWIDE. Cp: Cover Page Tc: Table of Contents Ss: Sample Summary Cn: Case Narrative Sr: Sample Results SW-1 L1101602-01 SW-2 L1101602-02 SW-3 L1101602-03 SW-4 L1101602-04 SWN-1 L1101602-05 SWN-2 L1101602-06 SW-C L1101602-07 Qc: Quality Control Summary Volatile Organic Compounds (GC/MS) by Method 8260D GI: Glossary of Terms Al: Accreditations & Locations Sc: Sample Chain of Custody CID 2 3 4 FS5 5 [Cn] 7 9 Fr 11 13 RC 15 �GI 17 19 rAI 19 27 FSC 28 29 Page 36 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429863 L1101602 05/30/1913:43 2 of 31 SAMPLE SUMMARY ONE LAB. NATIONWIDE. Collected by Collected date/time Received date/time SW-1 L1101602-01 GW 05/17/1911:19 05/22/19 08:45 FP1 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time FTC Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1917:15 05/28/1917:15 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time M SW-2 L1101602-02 GW 05/17/1912:00 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location [Cn] date/time date/time Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1917:35 05/28/1917:35 DWR Mt. Juliet, TN FSrVolatile Collected by Collected date/time Received date/time 6QC SW-3 L1101602-03 GW 05/17/1914:35 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location GI date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1917:55 05/28/1917:55 DWR Mt. Juliet, TN FAI Collected by Collected date/time Received date/time SW-4 L1101602-04 GW 05/17/1916:15 05/22/1908:45 FSC Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1918:15 05/28/1918:15 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time SWN-1 L1101602-05 GW 05/17/1915:34 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1918:35 05/28/1918:35 DWR Mt. Juliet, TN Collected by Collected date/time Received date/time SWN-2 L1101602-06 GW 05/17/1916:53 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287157 1 05/28/1911:10 05/28/1911:10 BMB Mt. Juliet, TN Collected by Collected date/time Received date/time SW-C L1101602-07 GW 05/17/19 08:43 05/22/19 08:45 Method Batch Dilution Preparation Analysis Analyst Location date/time date/time Volatile Organic Compounds (GC/MS) by Method 8260D WG1287536 1 05/28/1918:55 05/28/1918:55 DWR Mt. Juliet, TN Page 37 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429863 L1101602 05/30/1913:43 3 of 31 CASE NARRATIVE ONE LAB. NATIONWIDE. All sample aliquots were received at the correct temperature, in the proper containers, with the appropriate preservatives, and within method specified holding times, unless qualified or notated within the report. Where applicable, all MDL (LOD) and RDL (LOQ) values reported for environmental samples have been corrected for the dilution factor used in the analysis. All Method and Batch Quality Control are within established criteria except where addressed in this case narrative, a non-conformance form or properly qualified within the sample results. By my digital signature below, I affirm to the best of my knowledge, all problems/anomalies observed by the laboratory as having the potential to affect the quality of the data have been identified by the laboratory, and no information or data have been knowingly withheld that would affect the quality of the data. VV VV� � �t La�'_ Nancy McLain Project Manager FP1 FTC FSS FSr FC-1 F, FAI FSC Page 38 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429863 L1101602 05/30/1913:43 4 of 31 SW-1 SAMPLE RESULTS - 01 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 11:19 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 17:15 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 17:15 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 17:15 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 17:15 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 17:15 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 17:15 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 17:15 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 17:15 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 17:15 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 17:15 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 17:15 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 17:15 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 17:15 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 17:15 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 17:15 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 17:15 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 17:15 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 17:15 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 17:15 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 17:15 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 17:15 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 17:15 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 17:15 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 17:15 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 17:15 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 17:15 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 17:15 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 17:15 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 17:15 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 17:15 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 17:15 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 17:15 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 17:15 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 17:15 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 17:15 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 17:15 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 17:15 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 17:15 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 17:15 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 17:15 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 17:15 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 17:15 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 17:15 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 17:15 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 17:15 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 17:15 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 17:15 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 17:15 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 17:15 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 17:15 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 17:15 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 17:15 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 17:15 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 17:15 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 17:15 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 17:15 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 39 of 65 PAGE: 5 of 31 ONE LAB. NATIONWIDE. SW-1 SAMPLE RESULTS - 01 Collected date/time: 05/17/19 11:19 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201917:15 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201917:15 WG1287536 o-Xylene U 0.341 1.00 1 05/28/201917:15 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201917:15 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201917:15 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201917:15 WG1287536 (S) Toluene-d8 90.3 80.0-120 051281201917.75 WG1287536 (S 4-Bromof/uorobenzene 98.3 77.0-126 051281201917.75 WG1287536 (S 1,2-Dich/oroethane-d4 88.6 70.0-130 0512812019 17.75 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn Fc F, FAI FSC Page 40 of 65 PAGE: 6 of 31 SW-2 SAMPLE RESULTS - 02 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 12:00 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/201917:35 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/201917:35 WG1287536 Benzene U 0.331 1.00 1 05/28/201917:35 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/201917:35 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/201917:35 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/201917:35 WG1287536 Bromoform U 0.469 1.00 1 05/28/201917:35 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/201917:35 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/201917:35 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/201917:35 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/201917:35 WG1287536 Chloroethane U 0.453 5.00 1 05/28/201917:35 WG1287536 Chloroform U 0.324 5.00 1 05/28/201917:35 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/201917:35 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/201917:35 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/201917:35 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/201917:35 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/201917:35 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/201917:35 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/201917:35 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/201917:35 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 17:35 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/201917:35 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/201917:35 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/201917:35 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/201917:35 WG1287536 cis-1,2-Dichloroethene 4.53 0.260 1.00 1 05/28/201917:35 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/201917:35 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/201917:35 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/201917:35 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/201917:35 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/201917:35 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/201917:35 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/201917:35 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/201917:35 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/201917:35 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/201917:35 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/201917:35 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/201917:35 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/201917:35 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/201917:35 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/201917:35 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/201917:35 WG1287536 Naphthalene U 1.00 5.00 1 05/28/201917:35 WG1287536 Styrene U 0.307 1.00 1 05/28/201917:35 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/201917:35 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/201917:35 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/201917:35 WG1287536 Toluene U 0.412 1.00 1 05/28/201917:35 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/201917:35 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/201917:35 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/201917:35 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/201917:35 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/201917:35 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/201917:35 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/201917:35 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 41 of 65 PAGE: 7of31 ONE LAB. NATIONWIDE. SW-2 SAMPLE RESULTS - 02 Collected date/time: 05/17/19 12:00 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201917:35 WG1287536 Vinyl chloride 1.08 0.259 1.00 1 05/28/201917:35 WG1287536 o-Xylene IJ 0.341 1.00 1 05/28/201917:35 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201917:35 WG1287536 Xylenes, Total IJ 1.06 3.00 1 05/28/201917:35 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201917:35 WG1287536 (S) Toluene-d8 91.3 80.0-120 051281201917.35 WG1287536 (S 4-Bromof/uorobenzene 100 77.0-126 051281201917.35 WG1287536 (S) 1,2-Dich/oroethane-d4 88.0 70.0-130 0512812019 17.35 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn Fc F, FAI FSC Page 42 of 65 PAGE: 8 of 31 SW-3 SAMPLE RESULTS - 03 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 14:35 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 17:55 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 17:55 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 17:55 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 17:55 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 17:55 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 17:55 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 17:55 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 17:55 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 17:55 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 17:55 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 17:55 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 17:55 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 17:55 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 17:55 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 17:55 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 17:55 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 17:55 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 17:55 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 17:55 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 17:55 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 17:55 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 17:55 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 17:55 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 17:55 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 17:55 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 17:55 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 17:55 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 17:55 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 17:55 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 17:55 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 17:55 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 17:55 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 17:55 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 17:55 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 17:55 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 17:55 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 17:55 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 17:55 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 17:55 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 17:55 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 17:55 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 17:55 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 17:55 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 17:55 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 17:55 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 17:55 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 17:55 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 17:55 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 17:55 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 17:55 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 17:55 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 17:55 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 17:55 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 17:55 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 17:55 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 17:55 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 43 of 65 PAGE: 9 of 31 ONE LAB. NATIONWIDE. SW-3 SAMPLE RESULTS - 03 Collected date/time: 05/17/19 14:35 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201917:55 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201917:55 WG1287536 o-Xylene U 0.341 1.00 1 05/28/201917:55 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201917:55 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201917:55 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/2019 17:55 WG1287536 (S) Toluene-d8 92.6 80.0-120 051281201917:55 WG1287536 (S 4-Bromof/uorobenzene 102 77.0-126 051281201917:55 WG1287536 (S 1,2-Dich/oroethane-d4 89.2 70.0-130 0512812019 17:55 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn Fc F, FAI FSC Page 44 of 65 PAGE: 10 of 31 SW-4 SAMPLE RESULTS - 04 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 16:15 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 18:15 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 18:15 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 18:15 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 18:15 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 18:15 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 18:15 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 18:15 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 18:15 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 18:15 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 18:15 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 18:15 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 18:15 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 18:15 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 18:15 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 18:15 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 18:15 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 18:15 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 18:15 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 18:15 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 18:15 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 18:15 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 18:15 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 18:15 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 18:15 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 18:15 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 18:15 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 18:15 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 18:15 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 18:15 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 18:15 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 18:15 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 18:15 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 18:15 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 18:15 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 18:15 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 18:15 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 18:15 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 18:15 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 18:15 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 18:15 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 18:15 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 18:15 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 18:15 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 18:15 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 18:15 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 18:15 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 18:15 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 18:15 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 18:15 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 18:15 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 18:15 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 18:15 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 18:15 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 18:15 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 18:15 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 18:15 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 45 of 65 PAGE: 11 of 31 ONE LAB. NATIONWIDE. SW-4 SAMPLE RESULTS - 04 Collected date/time: 05/17/19 16:15 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201918:15 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201918:15 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 18:15 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201918:15 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201918:15 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201918:15 WG1287536 (S) Toluene-d8 89.0 80.0-120 051281201918.15 WG1287536 (S) 4-Bromof/uorobenzene 99.5 77.0-126 051281201918.15 WG1287536 (S 1,2-Dich/oroethane-d4 86.5 70.0-130 0512812019 18.15 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, INC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn N Fc F, FAI FSC Page 46 of 65 PAGE: 12 of 31 S W N -1 SAMPLE RESULTS - 05 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 15:34 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 18:35 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 18:35 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 18:35 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 18:35 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 18:35 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 18:35 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 18:35 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 18:35 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 18:35 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 18:35 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 18:35 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 18:35 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 18:35 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 18:35 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 18:35 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 18:35 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 18:35 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 18:35 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 18:35 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 18:35 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 18:35 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 18:35 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 18:35 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 18:35 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 18:35 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 18:35 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 18:35 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 18:35 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 18:35 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 18:35 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 18:35 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 18:35 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 18:35 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 18:35 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 18:35 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 18:35 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 18:35 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 18:35 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 18:35 WG1287536 2-Butanone (MEK) U 3.93 10.0 1 05/28/2019 18:35 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 18:35 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 18:35 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 18:35 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 18:35 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 18:35 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 18:35 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 18:35 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 18:35 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 18:35 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 18:35 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 18:35 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 18:35 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 18:35 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 18:35 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 18:35 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 18:35 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 47 of 65 PAGE: 13 of 31 ONE LAB. NATIONWIDE. SWN-1 SAMPLE RESULTS - 05 Collected date/time: 05/17/19 15:34 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Analyte Result ug/I Qualifier MDL ug/I RDL ug/I Dilution Analysis date / time Batch Vinyl acetate U 1.63 10.0 1 05/28/201918:35 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201918:35 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 18:35 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201918:35 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201918:35 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201918:35 WG1287536 (S) Toluene-d8 98.2 80.0-120 051281201918:35 WG1287536 (S) 4-Bromof/uorobenzene 84.2 77.0-126 051281201918.35 WG1287536 (S)1,2-Dich/oroethane-d4 69.7 J2 70.0-130 051281201918:35 WG1287536 Fp FTc FS Fn Fc F, FAI FSC Page 48 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 14 of 31 S W N- 2 SAMPLE RESULTS - 06 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 16:53 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/201911:10 WG1287157 Acrylonitrile U 1.87 10.0 1 05/28/201911:10 WG1287157 Benzene U 0.331 1.00 1 05/28/201911:10 WG1287157 Bromobenzene U 0.352 1.00 1 05/28/201911:10 WG1287157 Bromochloromethane U 0.520 5.00 1 05/28/201911:10 WG1287157 Bromodichloromethane U 0.380 1.00 1 05/28/201911:10 WG1287157 Bromoform U 0.469 1.00 1 05/28/201911:10 WG1287157 Bromomethane U J0 0.866 5.00 1 05/28/201911:10 WG1287157 Carbon tetrachloride U 0.379 1.00 1 05/28/201911:10 WG1287157 Chlorobenzene U 0.348 1.00 1 05/28/201911:10 WG1287157 Chlorodibromomethane U 0.327 1.00 1 05/28/201911:10 WG1287157 Chloroethane U 0.453 5.00 1 05/28/201911:10 WG1287157 Chloroform U 0.324 5.00 1 05/28/201911:10 WG1287157 Chloromethane U J0 0.276 2.50 1 05/28/201911:10 WG1287157 2-Chlorotoluene U 0.375 1.00 1 05/28/201911:10 WG1287157 4-Chlorotoluene U 0.351 1.00 1 05/28/201911:10 WG1287157 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/201911:10 WG1287157 1,2-Dibromoethane U 0.381 1.00 1 05/28/201911:10 WG1287157 Dibromomethane U 0.346 1.00 1 05/28/201911:10 WG1287157 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/201911:10 WG1287157 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/201911:10 WG1287157 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/201911:10 WG1287157 Dichlorodifluoromethane U J4 0.551 5.00 1 05/28/201911:10 WG1287157 1,1-Dichloroethane U 0.259 1.00 1 05/28/201911:10 WG1287157 1,2-Dichloroethane U 0.361 1.00 1 05/28/201911:10 WG1287157 1,1-Dichloroethene U 0.398 1.00 1 05/28/201911:10 WG1287157 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/201911:10 WG1287157 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/201911:10 WG1287157 1,2-Dichloropropane U 0.306 1.00 1 05/28/201911:10 WG1287157 1,1-Dichloropropene U 0.352 1.00 1 05/28/201911:10 WG1287157 1,3-Dichloropropane U 0.366 1.00 1 05/28/201911:10 WG1287157 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/201911:10 WG1287157 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/201911:10 WG1287157 2,2-Dichloropropane U 0.321 1.00 1 05/28/201911:10 WG1287157 Di -isopropyl ether U 0.320 1.00 1 05/28/201911:10 WG1287157 Ethylbenzene U 0.384 1.00 1 05/28/201911:10 WG1287157 Hexachloro-1,3-butadiene U 0.256 1.00 1 05/28/201911:10 WG1287157 2-Hexanone U 3.82 10.0 1 05/28/201911:10 WG1287157 p-Isopropyltoluene U 0.350 1.00 1 05/28/201911:10 WG1287157 2-Butanone (MEK) U 3.93 10.0 1 05/28/201911:10 WG1287157 Methylene Chloride U 1.00 5.00 1 05/28/201911:10 WG1287157 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/201911:10 WG1287157 Methyl tert-butyl ether U 0.367 1.00 1 05/28/201911:10 WG1287157 Naphthalene U 1.00 5.00 1 05/28/201911:10 WG1287157 Styrene U 0.307 1.00 1 05/28/201911:10 WG1287157 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/201911:10 WG1287157 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/201911:10 WG1287157 Tetrachloroethene U 0.372 1.00 1 05/28/201911:10 WG1287157 Toluene U 0.412 1.00 1 05/28/201911:10 WG1287157 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/201911:10 WG1287157 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/201911:10 WG1287157 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/201911:10 WG1287157 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/201911:10 WG1287157 Trichloroethene U 0.398 1.00 1 05/28/201911:10 WG1287157 Trichlorofluoromethane U 1.20 5.00 1 05/28/201911:10 WG1287157 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/201911:10 WG1287157 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 49 of 65 PAGE: 15 of 31 ONE LAB. NATIONWIDE. SWN-2 SAMPLE RESULTS - 06 Collected date/time: 05/17/19 16:53 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201911:10 WG1287157 Vinyl chloride U 0.259 1.00 1 05/28/201911:10 WG1287157 o-Xylene U 0.341 1.00 1 05/28/201911:10 WG1287157 m&p-Xylene U 0.719 2.00 1 05/28/201911:10 WG1287157 Xylenes, Total U 1.06 3.00 1 05/28/201911:10 WG1287157 1,4-Dioxane U 36.0 100 1 05/28/201911:10 WG1287157 (S Toluene-d8 91.8 80.0-120 051281201911:10 WG1287157 (S 4-Bromof/uorobenzene 102 77.0-126 051281201911:10 WG1287157 (S 1,2-Dich/oroethane-d4 89.1 70.0-130 051281201911:10 WG1287157 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn Fc F, FAI FSC Page 50 of 65 PAGE: 16 of 31 SW-C SAMPLE RESULTS - 07 ONE LAB. NATIONWIDE. Collected date/time: 05/17/19 08:43 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Acetone U 10.0 50.0 1 05/28/2019 18:55 WG1287536 Acrylonitrile U 1.87 10.0 1 05/28/2019 18:55 WG1287536 Benzene U 0.331 1.00 1 05/28/2019 18:55 WG1287536 Bromobenzene U 0.352 1.00 1 05/28/2019 18:55 WG1287536 Bromochloromethane U 0.520 5.00 1 05/28/2019 18:55 WG1287536 Bromodichloromethane U 0.380 1.00 1 05/28/2019 18:55 WG1287536 Bromoform U 0.469 1.00 1 05/28/2019 18:55 WG1287536 Bromomethane U J0 0.866 5.00 1 05/28/2019 18:55 WG1287536 Carbon tetrachloride U 0.379 1.00 1 05/28/2019 18:55 WG1287536 Chlorobenzene U 0.348 1.00 1 05/28/2019 18:55 WG1287536 Chlorodibromomethane U 0.327 1.00 1 05/28/2019 18:55 WG1287536 Chloroethane U 0.453 5.00 1 05/28/2019 18:55 WG1287536 Chloroform U 0.324 5.00 1 05/28/2019 18:55 WG1287536 Chloromethane U J0 0.276 2.50 1 05/28/2019 18:55 WG1287536 2-Chlorotoluene U 0.375 1.00 1 05/28/2019 18:55 WG1287536 4-Chlorotoluene U 0.351 1.00 1 05/28/2019 18:55 WG1287536 1,2-Dibromo-3-Chloropropane U 1.33 5.00 1 05/28/2019 18:55 WG1287536 1,2-Dibromoethane U 0.381 1.00 1 05/28/2019 18:55 WG1287536 Dibromomethane U 0.346 1.00 1 05/28/2019 18:55 WG1287536 1,2-Dichlorobenzene U 0.349 1.00 1 05/28/2019 18:55 WG1287536 1,3-Dichlorobenzene U 0.220 1.00 1 05/28/2019 18:55 WG1287536 1,4-Dichlorobenzene U 0.274 1.00 1 05/28/2019 18:55 WG1287536 Dichlorodifluoromethane U 0.551 5.00 1 05/28/2019 18:55 WG1287536 1,1-Dichloroethane U 0.259 1.00 1 05/28/2019 18:55 WG1287536 1,2-Dichloroethane U 0.361 1.00 1 05/28/2019 18:55 WG1287536 1,1-Dichloroethene U 0.398 1.00 1 05/28/2019 18:55 WG1287536 cis-1,2-Dichloroethene U 0.260 1.00 1 05/28/2019 18:55 WG1287536 trans-1,2-Dichloroethene U 0.396 1.00 1 05/28/2019 18:55 WG1287536 1,2-Dichloropropane U 0.306 1.00 1 05/28/2019 18:55 WG1287536 1,1-Dichloropropene U 0.352 1.00 1 05/28/2019 18:55 WG1287536 1,3-Dichloropropane U 0.366 1.00 1 05/28/2019 18:55 WG1287536 cis-1,3-Dichloropropene U 0.418 1.00 1 05/28/2019 18:55 WG1287536 trans-1,3-Dichloropropene U 0.419 1.00 1 05/28/2019 18:55 WG1287536 2,2-Dichloropropane U 0.321 1.00 1 05/28/2019 18:55 WG1287536 Di -isopropyl ether U 0.320 1.00 1 05/28/2019 18:55 WG1287536 Ethylbenzene U 0.384 1.00 1 05/28/2019 18:55 WG1287536 Hexachloro-1,3-butadiene U J0 0.256 1.00 1 05/28/2019 18:55 WG1287536 2-Hexanone U 3.82 10.0 1 05/28/2019 18:55 WG1287536 p-Isopropyltoluene U 0.350 1.00 1 05/28/2019 18:55 WG1287536 2-Butanone(MEK) U 3.93 10.0 1 05/28/2019 18:55 WG1287536 Methylene Chloride U 1.00 5.00 1 05/28/2019 18:55 WG1287536 4-Methyl-2-pentanone (MIBK) U 2.14 10.0 1 05/28/2019 18:55 WG1287536 Methyl tert-butyl ether U 0.367 1.00 1 05/28/2019 18:55 WG1287536 Naphthalene U 1.00 5.00 1 05/28/2019 18:55 WG1287536 Styrene U 0.307 1.00 1 05/28/2019 18:55 WG1287536 1,1,1,2-Tetrachloroethane U 0.385 1.00 1 05/28/2019 18:55 WG1287536 1,1,2,2-Tetrachloroethane U 0.130 1.00 1 05/28/2019 18:55 WG1287536 Tetrachloroethene U 0.372 1.00 1 05/28/2019 18:55 WG1287536 Toluene U 0.412 1.00 1 05/28/2019 18:55 WG1287536 1,2,3-Trichlorobenzene U 0.230 1.00 1 05/28/2019 18:55 WG1287536 1,2,4-Trichlorobenzene U 0.355 1.00 1 05/28/2019 18:55 WG1287536 1,1,1-Trichloroethane U 0.319 1.00 1 05/28/2019 18:55 WG1287536 1,1,2-Trichloroethane U 0.383 1.00 1 05/28/2019 18:55 WG1287536 Trichloroethene U 0.398 1.00 1 05/28/2019 18:55 WG1287536 Trichlorofluoromethane U 1.20 5.00 1 05/28/2019 18:55 WG1287536 1,2,3-Trichloropropane U 0.807 2.50 1 05/28/2019 18:55 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 FP1 FTc FSS 4 Cn FC] F q, FAI FSC Page 51 of 65 PAGE: 17 of 31 ONE LAB. NATIONWIDE. SW-C SAMPLE RESULTS - 07 Collected date/time: 05/17/19 08:43 L1101602 Volatile Organic Compounds (GC/MS) by Method 8260D Result Qualifier MDL RDL Dilution Analysis Batch Analyte ug/I ug/I ug/I date / time Vinyl acetate U 1.63 10.0 1 05/28/201918:55 WG1287536 Vinyl chloride U 0.259 1.00 1 05/28/201918:55 WG1287536 o-Xylene U 0.341 1.00 1 05/28/2019 18:55 WG1287536 m&p-Xylene U 0.719 2.00 1 05/28/201918:55 WG1287536 Xylenes, Total U 1.06 3.00 1 05/28/201918:55 WG1287536 1,4-Dioxane U 36.0 100 1 05/28/201918:55 WG1287536 (S) Toluene-d8 91.4 80.0-120 051281201918:55 WG1287536 (S) 4-Bromof/uorobenzene 101 77.0-126 051281201918:55 WG1287536 (S)1,2-Dich/oroethane-d4 90.7 70.0-130 051281201918:55 WG1287536 ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 Fp FTc FS Fn Fc F, FAI FSC Page 52 of 65 PAGE: 18 of 31 WG1287157 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101602-06 Method Blank (MB) (MB) R3415400-3 05/28/19 04:50 MB Result Analyte ug/I Acetone U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromochloromethane U Bromoform U Bromomethane U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U 2-Hexanone U p-Isopropyltoluene U 2-Butanone (MEK) U MB Qualifier MB MDL ug/I 10.0 1.87 0.331 0.352 0.380 0.520 0.469 0.866 0.379 0.348 0.327 0.453 0.324 0.276 0.375 0.351 1.33 0.381 0.346 0.349 0.220 0.274 0.551 0.259 0.361 0.398 0.260 0.396 0.306 0.352 0.366 0.418 0.419 0.321 0.320 0.384 0.256 3.82 0.350 3.93 MB RDL ug/I 50.0 10.0 1.00 1.00 1.00 5.00 1.00 5.00 1.00 1.00 1.00 5.00 5.00 2.50 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 10.0 1.00 10.0 FP1 FTC FSS [Cn] FSr �GI FAI FSC Page 53 of 65 PAGE: 19 of 31 ACCOUNT: Pace Analytical - Huntersville, NC PROJECT: SDG: DATE/TIME: 92429863 L1101602 05/30/1913:43 WG1287157 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101602-06 Method Blank (MB) (MB) R3415400-3 05/28/19 04:50 MB Result Analyte ug/I Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U Vinyl acetate U Vinyl chloride U Xylenes, Total U o-Xylene U m&p-Xylenes U 1,4-Dioxane U (S) Toluene-d8 93.0 (S) 4-Bromof/uorobenzene 98.8 (S) 1,2-Dich/oroethone-d4 89.8 MB Qualifier MB MDL ug/I Laboratory Control Sample (LCS) 1.00 2.14 0.367 1.00 0.307 0.385 0.130 0.372 0.412 0.230 0.355 0.319 0.383 0.398 1.20 0.807 1.63 0.259 1.06 0.341 0.719 36.0 MB RDL ug/I 5.00 10.0 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 2.50 10.0 1.00 3.00 1.00 2.00 100 80.0-120 77.0-126 70.0-130 (LCS) R3415400-1 05/28/19 03:30 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Acetone 125 134 107 19.0-160 Acrylonitrile 125 148 118 55.0-149 Benzene 25.0 28.2 113 70.0-123 Bromobenzene 25.0 22.2 89.0 73.0-121 Bromodichloromethane 25.0 28.6 115 75.0-120 Bromochloromethane 25.0 24.7 98.7 76.0-122 Bromoform 25.0 25.1 100 68.0-132 Bromomethane 25.0 14.5 58.1 10.0-160 Page 54 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 20 of 31 WG1287157 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101602-06 Laboratory Control Sample (LCS) (LCS) R3415400-1 05/28/19 03:30 Spike Amount LCS Result Analyte ug/I ug/I Carbon tetrachloride 25.0 29.3 Chlorobenzene 25.0 26.3 Chlorodibromomethane 25.0 25.7 Chloroethane 25.0 26.2 Chloroform 25.0 28.1 Chloromethane 25.0 12.7 2-Chlorotoluene 25.0 22.2 4-Chlorotoluene 25.0 23.3 1,2-Dibromo-3-Chloropropane 25.0 21.8 1,2-Dibromoethane 25.0 27.1 Dibromomethane 25.0 27.4 1,2-Dichlorobenzene 25.0 24.6 1,3-Dichlorobenzene 25.0 23.5 1,4-Dichlorobenzene 25.0 22.9 Dichlorodifluoromethane 25.0 12.4 1,1-Dichloroethane 25.0 28.3 1,2-Dichloroethane 25.0 25.9 1,1-Dichloroethene 25.0 30.5 cis-1,2-Dichloroethene 25.0 28.0 trans-1,2-Dichloroethene 25.0 30.0 1,2-Dichloropropane 25.0 27.8 1,1-Dichloropropene 25.0 29.9 1,3-Dichloropropane 25.0 27.1 cis-1,3-Dichloropropene 25.0 29.1 trans-1,3-Dichloropropene 25.0 25.8 2,2-Dichloropropane 25.0 25.9 Di -isopropyl ether 25.0 27.5 Ethylbenzene 25.0 27.0 Hexachloro-1,3-butadiene 25.0 20.9 2-Hexanone 125 136 p-Isopropyltoluene 25.0 22.3 2-Butanone (MEK) 125 130 Methylene Chloride 25.0 27.3 4-Methyl-2-pentanone (MIBK) 125 127 Methyl tert-butyl ether 25.0 28.8 Naphthalene 25.0 22.2 Styrene 25.0 28.0 1,1,1,2-Tetrachloroethane 25.0 26.1 1,1,2,2-Tetrachloroethane 25.0 23.1 Tetrachloroethene 25.0 28.4 LCS Rec 117 105 103 105 112 50.9 88.8 93.3 87.4 109 110 98.5 94.0 91.5 49.5 113 104 122 112 120 119 108 116 103 104 110 108 83.5 109 89.0 104 109 102 115 88.8 112 104 92.4 114 Rec. Limits LCS Qualifier 68.0-126 80.0-121 77.0-125 47.0-150 73.0-120 41.0-142 76.0-123 75.0-122 58.0-134 80.0-122 80.0-120 79.0-121 79.0-120 79.0-120 51.0-149 70.0-126 70.0-128 71.0-124 73.0-120 73.0-120 77.0-125 74.0-126 80.0-120 80.0-123 78.0-124 58.0-130 58.0-138 79.0-123 54.0-138 67.0-149 76.0-125 44.0-160 67.0-120 68.0-142 68.0-125 54.0-135 73.0-130 75.0-125 65.0-130 72.0-132 J4 FP1 FTC FSS [Cn] FSr �GI FAI FSC Page 55 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 21 of 31 WG1287157 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) (LCS) R3415400-1 05/28/19 03:30 Spike Amount LCS Result Analyte ug/I ug/I Toluene 25.0 25.4 1,2,3-Trichlorobenzene 25.0 22.3 1,2,4-Trichlorobenzene 25.0 23.0 1,1,1-Trichloroethane 25.0 29.8 1,1,2-Trichloroethane 25.0 25.8 Trichloroethene 25.0 30.5 Trichlorofluoromethane 25.0 32.7 1,2,3-Trichloropropane 25.0 23.9 Vinyl acetate 125 113 Vinyl chloride 25.0 31.6 Xylenes, Total 75.0 77.1 o-Xylene 25.0 26.0 m&p-Xylenes 50.0 51.1 (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Laboratory Control Sample (LCS) LCS Rec. 102 89.1 91.8 119 103 122 131 95.7 90.7 126 103 104 102 92.2 104 86.0 QUALITY CONTROL SUMMARY L1101602-06 Rec. Limits LCS Qualifier 79.0-120 50.0-138 57.0-137 73.0-124 80.0-120 78.0-124 59.0-147 73.0-130 11.0-160 67.0-131 79.0-123 80.0-122 80.0-122 80.0-120 77.0-126 70.0-130 ONE LAB. NATIONWIDE. FP1 FTC] IS-S] 4 Cn rs-r �GI rAl FSC (LCS) R3415400-2 05/28/19 04:10 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % 1,4-Dioxane 1000 988 98.8 13.0-160 (S) Toluene-d8 92.0 80.0-120 (S)4-Bromofluorobenzene 100 77.0-126 (S)1,2-Dich/oroethane-d4 91.5 70.0-130 Page 56 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 22 of 31 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101602-01,02,03,04,05,07 Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Acetone U Acrylonitrile U Benzene U Bromobenzene U Bromodichloromethane U Bromochloromethane U Bromoform U Bromomethane U Carbon tetrachloride U Chlorobenzene U Chlorodibromomethane U Chloroethane U Chloroform U Chloromethane U 2-Chlorotoluene U 4-Chlorotoluene U 1,2-Dibromo-3-Chloropropane U 1,2-Dibromoethane U Dibromomethane U 1,2-Dichlorobenzene U 1,3-Dichlorobenzene U 1,4-Dichlorobenzene U Dichlorodifluoromethane U 1,1-Dichloroethane U 1,2-Dichloroethane U 1,1-Dichloroethene U cis-1,2-Dichloroethene U trans-1,2-Dichloroethene U 1,2-Dichloropropane U 1,1-Dichloropropene U 1,3-Dichloropropane U cis-1,3-Dichloropropene U trans-1,3-Dichloropropene U 2,2-Dichloropropane U Di -isopropyl ether U Ethylbenzene U Hexachloro-1,3-butadiene U 2-Hexanone U p-Isopropyltoluene U 2-Butanone (MEK) U MB Qualifier MB MDL MB RDL ug/I ug/I 10.0 50.0 1.87 10.0 0.331 1.00 0.352 1.00 0.380 1.00 0.520 5.00 0.469 1.00 0.866 5.00 0.379 1.00 0.348 1.00 0.327 1.00 0.453 5.00 0.324 5.00 0.276 2.50 0.375 1.00 0.351 1.00 1.33 5.00 0.381 1.00 0.346 1.00 0.349 1.00 0.220 1.00 0.274 1.00 0.551 5.00 0.259 1.00 0.361 1.00 0.398 1.00 0.260 1.00 0.396 1.00 0.306 1.00 0.352 1.00 0.366 1.00 0.418 1.00 0.419 1.00 0.321 1.00 0.320 1.00 0.384 1.00 0.256 1.00 3.82 10.0 0.350 1.00 3.93 10.0 FP1 FTC FSS [Cn] FSr �GI FAI FSC Page 57 of 65 PAGE: 23 of 31 ACCOUNT: Pace Analytical - Huntersville, NC PROJECT: SDG: DATE/TIME: 92429863 L1101602 05/30/1913:43 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Method Blank (MB) (MB) R3416175-3 05/28/1915:13 MB Result Analyte ug/I Methylene Chloride U 4-Methyl-2-pentanone (MIBK) U Methyl tert-butyl ether U Naphthalene U Styrene U 1,1,1,2-Tetrachloroethane U 1,1,2,2-Tetrachloroethane U Tetrachloroethene U Toluene U 1,2,3-Trichlorobenzene U 1,2,4-Trichlorobenzene U 1,1,1-Trichloroethane U 1,1,2-Trichloroethane U Trichloroethene U Trichlorofluoromethane U 1,2,3-Trichloropropane U Vinyl acetate U Vinyl chloride U Xylenes, Total U o-Xylene U m&p-Xylenes U 1,4-Dioxane U (S) Toluene-d8 90.2 (S) 4-Bromof/uorobenzene 96.6 (S) 1,2-Dich/oroethone-d4 86.2 MB Qualifier MB MDL ug/I Laboratory Control Sample (LCS) 1.00 2.14 0.367 1.00 0.307 0.385 0.130 0.372 0.412 0.230 0.355 0.319 0.383 0.398 1.20 0.807 1.63 0.259 1.06 0.341 0.719 36.0 QUALITY CONTROL SUMMARY L1101602-01,02,03,04,05,07 MB RDL ug/I 5.00 10.0 1.00 5.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 5.00 2.50 10.0 1.00 3.00 1.00 2.00 100 80.0-120 77.0-126 70.0-130 (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Acetone 125 143 114 19.0-160 Acrylonitrile 125 149 120 55.0-149 Benzene 25.0 26.7 107 70.0-123 Bromobenzene 25.0 22.1 88.5 73.0-121 Bromodichloromethane 25.0 27.3 109 75.0-120 Bromochloromethane 25.0 23.8 95.3 76.0-122 Bromoform 25.0 24.1 96.4 68.0-132 Bromomethane 25.0 12.9 51.7 10.0-160 ONE LAB. NATIONWIDE. FP1 FTC FSS 4 Cn FSr �GI FAI FSC Page 58 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 24 of 31 WG1287536 QUALITY CONTROL SUMMARY ONE LAB. NATIONWIDE. Volatile Organic Compounds (GC/MS) by Method 8260D L1101602-01,02,03,04,05,07 Laboratory Control Sample (LCS) (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % Carbon tetrachloride 25.0 27.1 108 68.0-126 Chlorobenzene 25.0 24.5 98.1 80.0-121 Chlorodibromomethane 25.0 24.7 99.0 77.0-125 Chloroethane 25.0 23.1 92.3 47.0-150 Chloroform 25.0 26.9 108 73.0-120 Chloromethane 25.0 16.0 63.9 41.0-142 2-Chlorotoluene 25.0 22.0 87.9 76.0-123 4-Chlorotoluene 25.0 23.2 92.8 75.0-122 1,2-Dibromo-3-Chloropropane 25.0 22.4 89.6 58.0-134 1,2-Dibromoethane 25.0 25.1 100 80.0-122 Dibromomethane 25.0 26.6 107 80.0-120 1,2-Dichlorobenzene 25.0 24.4 97.6 79.0-121 1,3-Dichlorobenzene 25.0 23.1 92.4 79.0-120 1,4-Dichlorobenzene 25.0 22.6 90.6 79.0-120 Dichlorodifluoromethane 25.0 27.7 111 51.0-149 1,1-Dichloroethane 25.0 26.5 106 70.0-126 1,2-Dichloroethane 25.0 24.7 98.9 70.0-128 1,1-Dichloroethene 25.0 27.2 109 71.0-124 cis-1,2-Dichloroethene 25.0 27.7 111 73.0-120 trans-1,2-Dichloroethene 25.0 28.0 112 73.0-120 1,2-Dichloropropane 25.0 26.9 107 77.0-125 1,1-Dichloropropene 25.0 27.5 110 74.0-126 1,3-Dichloropropane 25.0 25.2 101 80.0-120 cis-1,3-Dichloropropene 25.0 28.1 112 80.0-123 trans-1,3-Dichloropropene 25.0 24.1 96.5 78.0-124 2,2-Dichloropropane 25.0 25.5 102 58.0-130 Di -isopropyl ether 25.0 26.8 107 58.0-138 Ethylbenzene 25.0 24.9 99.7 79.0-123 Hexachloro-1,3-butadiene 25.0 20.4 81.7 54.0-138 2-Hexanone 125 137 110 67.0-149 p-Isopropyltoluene 25.0 21.8 87.4 76.0-125 2-Butanone (MEK) 125 139 111 44.0-160 Methylene Chloride 25.0 26.3 105 67.0-120 4-Methyl-2-pentanone (MIBK) 125 126 100 68.0-142 Methyl tert-butyl ether 25.0 27.8 111 68.0-125 Naphthalene 25.0 22.6 90.2 54.0-135 Styrene 25.0 24.7 98.7 73.0-130 1,1,1,2-Tetrachloroethane 25.0 24.6 98.4 75.0-125 1,1,2,2-Tetrachloroethane 25.0 23.3 93.3 65.0-130 Tetrachloroethene 25.0 25.5 102 72.0-132 FP1 FTC] IS-S] 4 Cn rs-r �GI rAl FSC Page 59 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 25 of 31 WG1287536 Volatile Organic Compounds (GC/MS) by Method 8260D Laboratory Control Sample (LCS) (LCS) R3416175-1 05/28/1913:53 Spike Amount LCS Result Analyte ug/I ug/I Toluene 25.0 23.7 1,2,3-Trichlorobenzene 25.0 22.4 1,2,4-Trichlorobenzene 25.0 23.2 1,1,1-Trichloroethane 25.0 27.5 1,1,2-Trichloroethane 25.0 24.2 Trichloroethene 25.0 28.1 Trichlorofluoromethane 25.0 28.7 1,2,3-Trichloropropane 25.0 24.4 Vinyl acetate 125 134 Vinyl chloride 25.0 27.6 Xylenes, Total 75.0 71.6 o-Xylene 25.0 24.1 m&p-Xylenes 50.0 47.5 (S) Toluene-d8 (S) 4-Bromof/uorobenzene (S) 1,2-Dich/oroethane-d4 Laboratory Control Sample (LCS) LCS Rec 94.7 89.4 92.9 110 96.9 112 115 97.6 107 95.5 96.3 95.0 90.3 102 100 QUALITY CONTROL SUMMARY L1101602-01,02,03,04,05,07 Rec. Limits LCS Qualifier 79.0-120 50.0-138 57.0-137 73.0-124 80.0-120 78.0-124 59.0-147 73.0-130 11.0-160 67.0-131 79.0-123 80.0-122 80.0-122 80.0-120 77.0-126 70.0-130 ONE LAB. NATIONWIDE. FP1 FTC] IS-S] 4 Cn rs-r �GI rAl FSC (LCS) R3416175-2 05/28/1914:33 Spike Amount LCS Result LCS Rec. Rec. Limits LCS Qualifier Analyte ug/I ug/I % % 1,4-Dioxane 1000 1100 110 13.0-160 (S) Toluene-d8 90.6 80.0-120 (S)4-Bromofluorobenzene 100 77.0-126 (S)1,2-Dich/oroethane-d4 86.4 70.0-130 Page 60 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 26 of 31 GLOSSARY OF TERMS Guide to Reading and Understanding Your Laboratory Report ONE LAB. NATIONWIDE. The information below is designed to better explain the various terms used in your report of analytical results from the Laboratory. This is not intended as a comprehensive explanation, and if you have additional questions please contact your project representative. Abbreviations and Definitions CP IP FTC MDL Method Detection Limit. RDL Reported Detection Limit. FSS Rec. Recovery. RPD Relative Percent Difference. SDG Sample Delivery Group. [Cn] Surrogate (Surrogate Standard) - Analytes added to every blank, sample, Laboratory Control Sample/Duplicate and (S) Matrix Spike/Duplicate; used to evaluate analytical efficiency by measuring recovery. Surrogates are not expected to be detected in all environmental media. FSr U Not detected at the Reporting Limit (or MDL where applicable). Analyte The name of the particular compound or analysis performed. Some Analyses and Methods will have multiple analytes Fc reported. If the sample matrix contains an interfering material, the sample preparation volume or weight values differ from the Dilution standard, or if concentrations of analytes in the sample are higher than the highest limit of concentration that the laboratory can accurately report, the sample may be diluted for analysis. If a value different than 1 is used in this field, the result reported has already been corrected for this factor. These are the target % recovery ranges or % difference value that the laboratory has historically determined as normal Limits for the method and analyte being reported. Successful QC Sample analysis will target all analytes recovered or FAI duplicated within these ranges. This column provides a letter and/or number designation that corresponds to additional information concerning the result Qualifier reported. If a Qualifier is present, a definition per Qualifier is provided within the Glossary and Definitions page and FSC potentially a discussion of possible implications of the Qualifier in the Case Narrative if applicable. The actual analytical final result (corrected for any sample specific characteristics) reported for your sample. If there was no measurable result returned for a specific analyte, the result in this column may state "ND" (Not Detected) or "BDL" Result (Below Detectable Levels). The information in the results column should always be accompanied by either an MDL (Method Detection Limit) or RDL (Reporting Detection Limit) that defines the lowest value that the laboratory could detect or report for this analyte. Uncertainty (Radiochemistry) Confidence level of 2 sigma. A brief discussion about the included sample results, including a discussion of any non -conformances to protocol Case Narrative (Cn) observed either at sample receipt by the laboratory from the field or during the analytical process. If present, there will be a section in the Case Narrative to discuss the meaning of any data qualifiers used in the report. Quality Control This section of the report includes the results of the laboratory quality control analyses required by procedure or Summary (Qc) analytical methods to assist in evaluating the validity of the results reported for your samples. These analyses are not being performed on your samples typically, but on laboratory generated material. This is the document created in the field when your samples were initially collected. This is used to verify the time and Sample Chain of date of collection, the person collecting the samples, and the analyses that the laboratory is requested to perform. This Custody (Sc) chain of custody also documents all persons (excluding commercial shippers) that have had control or possession of the samples from the time of collection until delivery to the laboratory for analysis. This section of your report will provide the results of all testing performed on your samples. These results are provided Sample Results (Sr) by sample ID and are separated by the analyses performed on each sample. The header line of each analysis section for each sample will provide the name and method number for the analysis reported. Sample Summary (Ss) This section of the Analytical Report defines the specific analyses performed for each sample ID, including the dates and times of preparation and/or analysis. Qualifier Description JO JO: The identification of the analyte is acceptable, but the reported concentration is an estimate. The calibration met method criteria. J2 Surrogate recovery limits have been exceeded; values are outside lower control limits. J4 The associated batch QC was outside the established quality control range for accuracy. Page 61 of 65 ACCOUNT: PROJECT: SDG: DATE/TIME: PAGE: Pace Analytical - Huntersville, INC 92429863 L1101602 05/30/1913:43 27 of 31 ACCREDITATIONS & LOCATIONS ONE LAB. NATIONWIDE. Pace National is the only environmental laboratory accredited/certified to support your work nationwide from one location. One phone call, one point of contact, one laboratory. No other lab is as accessible or prepared to handle your needs throughout the country. Our capacity and capability from our single location laboratory is comparable to the collective totals of the network laboratories in our industry. The most significant benefit to our one location design is the design of our laboratory campus. The model is conducive to accelerated productivity, decreasing FP1 turn -around time, and preventing cross contamination, thus protecting sample integrity. Our focus on premium quality and prompt service allows us to be YOUR LAB OF CHOICE. Not all certifications held by the laboratory are applicable to the results reported in the attached report. Accreditation is only applicable to the test methods specified on each scope of accreditation held by Pace National. Z Tc State Accreditations f—� Alabama 40660 Nebraska _ NE-OS-15-05 SS Alaska 17-026 Nevada TN-03-2002-34 Arizona AZO612 New Hampshire 2975 Arkansas 88-0469 New Jersey_NELAP TNO02 C n California 2932 New Mexico n/a Colorado TN00003 New York 11742 s Connecticut PH-0197 North Carolina Env375 Sr Florida E87487 North Carolina' DW21704 Georgia NELAP North Carolina' 41 Georgia' 923 North Dakota R-140 RC Idaho TN00003 Ohio—VAP CL0069 Illinois 200008 Oklahoma 9915 Indiana C-TN-01 Oregon TN200002 G Iowa 364 Pennsylvania 68-02979 Kansas E-10277 Rhode Island LA000356 Kentucky76 90010 South Carolina 84004 Kentucky 2 16 South Dakota n/a Louisiana A130792 Tennessee' 4 2006 Louisiana' LA180010 Texas T104704245-18-15 [SC Maine TN0002 Texas' LABO152 Maryland 324 Utah Massachusetts M-TNO03 Vermont Michigan 9958 Virginia Minnesota 047-999-395 Washington Mississippi TN00003 West Virginia Missouri 340 Wisconsin Montana CERT0086 Wyoming Third Party Federal Accreditations A21LA — ISO 17025 1461.01 AIHA-LAP,LLC EMLAP A21LA — ISO 17025 5 1461.02 DOD Canada 1461.01 USDA EPA—Crypto TN00003 ' Drinking Water 'Underground Storage Tanks 3 Aquatic Toxicity 4 Chemical/Microbiological 5 Mold 6 Wastewater n/a Accreditation not applicable Our Locations TN00003 VT2006 460132 C847 233 9980939910 A2LA 100789 1461.01 P330-15-00234 Pace National has sixty-four client support centers that provide sample pickup and/or the delivery of sampling supplies. If you would like assistance from one of our support offices, please contact our main office. Pace National performs all testing at our central laboratory. WA MT ND OR MN T ID T WI NY SD WY MI NV T NE IA OH T PA T f IL Ills WV vA UT T CA�� T KS MO KY W 11110 � NM O� AR N Sc T MS A`7L GA T TX * LA T AK T T q FL wo HI ACCOUNT: PROJECT: SDG: DATE/TIME: Pace Analytical - Huntersville, NC 92429863 L1101602 05/30/1913:43 ME Page 62 of 65 PAGE: 28 of 31 Chain of Custody ❑ Samples were sent directly to the Subcontracting Laboratory. Workorder: 92429863 Workorder Name: SURRY MSWLF SWS sRepQit o- - Subcont Angela Mom Pace Analytical Charlotte Pace National 9800 Kincey Ave. Suite 100 12065 Lebanon Rd Huntersville, NC 28078 Phone (704)875-9092 Mt Juliet, TN 37122 615-758-5858 Item Sarmp{e IB 1 SW-1 2 w-2 3 SW-3 4 SvV-4 5 SWN-1 6 SWN-2 7 SW-C Released By sample Collect Type' . aateMme _ Lab iD Matrix FS 5/17/20191ry1:19 92429863001 Water PS 5117/201912:00 92429863002 Water PS 51171201914:35 92429863003 Water 1 PS 5117/201916:15 92429863004 Water 1 PS 5117/201915:34 92429863005 Water PS 51171201916:53 92429863006 Water PS 5/17/2019 08:43 92429863007 Water t inn n nn•nA I 09d90Qr-A Dat rme=' - ecelved By Prese 1170 ace Analytical State Of Origin: -Q$c�jdj)sxc�m NYes Cert. Needed: ❑ No Owner Received Date: 5/20/2019 Results Requested By: 614/2().19 81111111111F-77---� -Reauested Anal U O n a L) 2 X Date/Time LAB USE ONLY G1 6d -6I 3 Cooler Temperature on Receipt 0.9-•1:0C[Custody Seal Y or N =eceived on Ice Y r N Samples Intact',Im- . Y r N ***In order to maintain client confide iallty, location/name of the sampling site, sampler's name and signature may not be provided on this COC document. This chain of custody is considered complete as is since this information is available in the owner laboratory. RAD S�-7E`N: <0.5 mWhr u Tuesday, May 21, 2D19 1:58:47 PM FMT-ALL-C-002rev.00 24March2009 Page 1 of 1 Page 63 of 65 k 2 � � f \ � a, §ƒ \ \§ g[ 2 a Cu @ - t o J $ � / / b z @ w Lu .0- - 5 @ < � Cl 0 / CD f z < f \ § 7 0 0 _ k.� { - o - � u n / f \ ..: o: j § \ \ \ / uj o Z § / 2 \ | / j ) j { F- ° �..a. 0 ` \ \ k } \ _ 2 �{ c � i § k � § $ 3 \\2 E � \ E 0 \ } Cl) ) z \ in z ■ � ❑ K 9 �f / \ ( \ j c � 3 ❑ k ❑ . $: z 2 ❑� .ƒ \ ❑ CD \ - \ � \ � o f I § / / k I _ � ,/ Pace Analytical National Centerfor TestingsInnovation Cooler Receipt Form i S°c#: Lved/opened On: 51ZL/19 Temperature:Jordan Harris E Receipt Check List NP Yes No COC Seal Present / Intact? COC Signed / Accurate? f Bottles arrive intact? Correct bottles used? Sufficient volume sent? If Applicable VOA Zero headspace? Preservation Correct / Checked? Page 65 of 65 Environmental Conservation Laboratories, Inc. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Thursday, September 12, 2019 Municipal Engineering Services (M0001) Attn: Jonathan Pfohl 68 Shipwash Drive Garner, NC 27529 RE: Laboratory Results for Project Number: [none], Project Name/Desc: Surry Lined MSWLF ENCO Workorder(s): CC14876 Dear Jonathan Pfohl, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Wednesday, September 4, 2019. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, 00, (/ L- - C�- A Chuck Smith Project Manager Enclosure(s) (� �C—O www.encolabs.com The total number of pages in this report, including this page is 9. (� 0a www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: MW-413 Lab ID: CC14876-01 Sampled: 05/16/19 10:50 Received: 09/04/19 16:39 Parameter Preparation Hold Date/Time(s) Prep Date/Time(s) Analysis Date/Time(s) EPA 6010D EPA 3005A 11/12/19 09/06/19 09:38 09/10/19 12:00 EPA 6020E EPA 3005A 11/12/19 09/10/19 16:30 09/11/19 14:32 Page 2 of 9 (� �C-O www.encolabs.com NORTH CAROLINA SWS SAMPLE DETECTION SUMMARY lient ID: MW-4D Lab ID: CC14876-01 Analyte Results Flag DF MDL MRL NC SWSL Units Method Notes - - - - - - - - - - - - - Barium - Total - - - - - - - - - - - - - - - - - - 48.0 1 1.10 - - - - - - - - 10.0 NE - - - - - - - - - - - - - - - - ug/L EPA 6010D Page 3 of 9 (� 0a www.encolabs.com ANALYTICAL RESULTS Description: MWAD Lab Sample ID: CC14876-01 Received: 09/04/19 16:39 Matrix: Ground Water Sampled: 05/16/19 10:50 Work Order: CC14876 Project: Surry Lined MSWLF Sampled By: 1. Kohl Metals (total recoverable) by EPA 6000/7000 Series Methods - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - ^ - ENCO Cary certified analyte [NC 591] Analyte rCAS Numberl Results Flaa Units DF MDL MRL INC SWSL Method Analyzed Notes Antimony [7440-36-0] ^ 0.740 u ug/L 2 0.740 2.00 EPA 6020B 09/11/19 14:32 RLF Arsenic [7440-38-2] ^ 7.60 u ug/L 1 7.60 10.0 EPA 6010D 09/10/19 12:00 JDH Barium [7440-39-3] ^ 48.0 ug/L 1 1.10 10.0 EPA 6010D 09/10/19 12:00 JDH Beryllium [7440-41-7] ^ 0.160 u ug/L 1 0.160 1.00 EPA 6010D 09/10/19 12:00 JDH Cadmium [7440-43-9] ^ 0.360 u ug/L 1 0.360 1.00 EPA 6010D 09/10/19 12:00 JDH Chromium [7440-47-3] ^ 1.40 u ug/L 1 1.40 10.0 EPA 6010D 09/10/19 12:00 JDH Cobalt [7440-48-4] ^ 1.40 u ug/L 1 1.40 10.0 EPA 6010D 09/10/19 12:00 JDH Copper [7440-50-8] ^ 1.60 u ug/L 1 1.60 10.0 EPA 6010D 09/10/19 12:00 JDH Lead [7439-92-1] ^ 3.10 u ug/L 1 3.10 10.0 EPA 6010D 09/10/19 12:00 JDH Nickel [7440-02-0] ^ 2.20 u ug/L 1 2.20 10.0 EPA 6010D 09/10/19 12:00 JDH Selenium [7782-49-2] ^ 1.82 u ug/L 2 1.82 2.00 EPA 6020B 09/11/19 14:32 RLF Silver [7440-22-4] ^ 1.90 u ug/L 1 1.90 10.0 EPA 6010D 09/10/19 12:00 JDH Thallium [7440-28-0] ^ 0.220 u ug/L 2 0.220 2.00 EPA 6020B 09/11/19 14:32 RLF Vanadium [7440-62-2] ^ 1.40 u ug/L 1 1.40 10.0 EPA 6010D 09/10/19 12:00 JDH Zinc [7440-66-6] ^ 4.40 u ug/L 1 4.40 10.0 EPA 6010D 09/10/19 12:00 JDH This report relates only to the sample as received by the laboratory, and may only be reproduced in full. Page 4 of 9 (� �C-O www.encolabs.com QUALITY CONTROL Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I06014 - EPA 3005A Blank (9I06014-BLK3) Prepared: 09/06/2019 09:38 Analyzed: 09/10/2019 11:34 Lalyte %REC RPD R4L Flag MRL Units %REC Limits Limit Notes Arsenic 7.60 U 10.0 ug/L Barium 1.10 U 10.0 ug/L Beryllium 0.160 U 1.00 ug/L Cadmium 0.360 U 1.00 ug/L Chromium 1.40 U 10.0 ug/L Cobalt 1.40 U 10.0 ug/L Copper 1.60 U 10.0 ug/L Lead 3.10 U 10.0 ug/L Nickel 2.20 U 10.0 ug/L Silver 1.90 U 10.0 ug/L Vanadium 1.40 U 10.0 ug/L Zinc 4.40 U 10.0 ug/L - - - - - - - - - - - - - - LCS (9I06014-BS1) - - - - - - - - - - - - - - - - - - - - Prepared: - - - - 09/06/2019 - - - - - - - - - - - 09:38 Analyzed: 09/10/2019 11:39 - - - - - - - - Spike Source .REC RPD MRL Units Level Result %REC Limits RPD Limit Notes Arsenic 201 10.0 ug/L 200 100 80-120 Barium 198 10.0 ug/L 200 99 80-120 Beryllium 20.1 1.00 ug/L 20.0 101 80-120 Cadmium 19.9 1.00 ug/L 20.0 100 80-120 Chromium 199 10.0 ug/L 200 99 80-120 Cobalt 204 10.0 ug/L 200 102 80-120 Copper 195 10.0 ug/L 200 97 80-120 Lead 202 10.0 ug/L 200 101 80-120 Nickel 200 10.0 ug/L 200 100 80-120 Silver 204 10.0 ug/L 200 102 80-120 Vanadium 199 10.0 ug/L 200 100 80-120 Zinc 203 10.0 ug/L 200 101 80-120 - - - Matrix Spike (9I06014-MS1) - - - - - - - - - - Prepared: - - - - 09/06/2019 - - - - - - - - - - - 09:38 Analyzed: 09/10/2019 11:42 - - Source:CC14298-01 �Analyte Spike Source %REC RPD Result FNEX MRL Units Level Result %REC Limits RPD Limit Notes Arsenic 192 10.0 ug/L 200 7.60 U 96 75-125 Barium 255 10.0 ug/L 200 56.6 99 75-125 Beryllium 20.3 1.00 ug/L 20.0 0.160 U 101 75-125 Cadmium 19.6 1.00 ug/L 20.0 0.360 U 98 75-125 Chromium 201 10.0 ug/L 200 1.40 U 100 75-125 Cobalt 203 10.0 ug/L 200 1.40 U 101 75-125 Copper 199 10.0 ug/L 200 1.60 U 100 75-125 Lead 197 10.0 ug/L 200 3.10 U 98 75-125 Nickel 199 10.0 ug/L 200 2.20 U 99 75-125 Silver 205 10.0 ug/L 200 1.90 U 102 75-125 Vanadium 202 10.0 ug/L 200 1.40 U 101 75-125 Zinc 206 10.0 ug/L 200 5.71 100 75-125 - - - - - - - - - - - - - - Matrix Spike Dup (9I06014-MSD1) - - - - - - - - - - - - - - - - - - - - Prepared: - - - - 09/06/2019 - - - - - - - - - - - 09:38 Analyzed: 09/10/2019 11:44 - - - - - - - - Page 5 of 9 (� �C-O www.encolabs.com QUALITY CONTROL Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9I06014 - EPA 3005A Matrix Spike Dup (9I06014-MSDI) Continued Prepared: 09/06/2019 09:38 Analyzed: 09/10/2019 11:44 Source:CC14298-01 �nalyte Spike Source %REC RPD Units Level Result %REC Limits D Limit Notes Arsenic 189 10.0 ug/L 200 7.60 U 94 75-125 2 20 Barium 247 10.0 ug/L 200 56.6 95 75-125 3 20 Beryllium 19.5 1.00 ug/L 20.0 0.160 U 98 75-125 4 20 Cadmium 19.3 1.00 ug/L 20.0 0.360 U 97 75-125 2 20 Chromium 195 10.0 ug/L 200 1.40 U 97 75-125 3 20 Cobalt 198 10.0 ug/L 200 1.40 U 99 75-125 2 20 Copper 193 10.0 ug/L 200 1.60 U 97 75-125 3 20 Lead 191 10.0 ug/L 200 3.10 U 96 75-125 3 20 Nickel 193 10.0 ug/L 200 2.20 U 97 75-125 3 20 Silver 199 10.0 ug/L 200 1.90 U 99 75-125 3 20 Vanadium 196 10.0 ug/L 200 1.40 U 98 75-125 3 20 Zinc 202 10.0 ug/L 200 5.71 98 75-125 2 20 - - - - Post Spike (9I06014-PSI) - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 09/06/2019 - - - - - - - - - - - 09:38 Analyzed: 09/10/2019 11:55 - - - - - - - - Source:CC14298-01 �Analyte Spike Source %REC W I Result MRL Units Level Result %REC Limits RPD Arsenic 0.201 0.0100 mg/L 0.200 -0.0131 100 80-120 Barium 0.263 0.0100 mg/L 0.200 0.0566 103 80-120 Beryllium 0.0212 0.00100 mg/L 0.0200 -6.90E-5 106 80-120 Cadmium 0.0207 0.00100 mg/L 0.0200 -3.77E-5 103 80-120 Chromium 0.209 0.0100 mg/L 0.200 0.000437 105 80-120 Cobalt 0.214 0.0100 mg/L 0.200 0.00111 106 80-120 Copper 0.208 0.0100 mg/L 0.200 -0.000596 104 80-120 Lead 0.216 0.0100 mg/L 0.200 -9.12E-5 108 80-120 Nickel 0.209 0.0100 mg/L 0.200 0.000212 104 80-120 Silver 0.220 0.0100 mg/L 0.200 -0.000289 110 80-120 Vanadium 0.210 0.0100 mg/L 0.200 -0.000245 105 80-120 Zinc - - - - - - - - - - - - 0.216 - - - - - - - 0.0100 - - - - - - mg/L - - - - 0.200 - - - - 0.00571 - - - - - 105 - - - 80-120 - - - - - - - - - - - - - - - - Batch 9I10030 - EPA 3005A Blank (9I10030-BLKI) Prepared: 09/10/2019 16:30 Analyzed: 09/11/2019 14:28 �Analyte ErMRL Spike Source %REC RPD Units Level Result %REC Limits RPD Limit Notes Antimony 0.370 U 1.00 ug/L Selenium 0.910 U 1.00 ug/L Thallium 0.110 U 1.00 ug/L - - - - - - - - - - - - LCS (9I10030-BS1) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 09/10/2019 16:30 Analyzed: 09/11/2019 14:36 - - - - - - - - ME Spike Source %REC RPD Result Fla Units Level Result %REC Limits RPD Limit Notes Antimony 20.5 1.00 ug/L 20.0 103 80-120 Selenium 20.3 1.00 ug/L 20.0 101 80-120 Thallium - - - - - - - - - - - 20.6 - - - - - - - 1.00 - - - - ug/L - - 20.0 103 80-120 - - - - - - - - - - - - - - - - Page 6 of 9 (� 0a www.encolabs.com QUALITY CONTROL Metals (total recoverable) by EPA 6000/7000 Series Methods - Quality Control Batch 9110030 - EPA 3005A Matrix Spike (9I10030-MS1) Prepared: 09/10/2019 16:30 Analyzed: 09/11/2019 14:41 Source: CC14876-01 �Analyte Spike Source %REC RPD Result Flag MRL Units Level Result %REC Limits RPD Limit Notes Antimony 41.5 2.00 ug/L 40.0 0.740 U 104 75-125 Selenium 39.8 2.00 ug/L 40.0 1.82 U 100 75-125 Thallium 41.1 2.00 ug/L 40.0 0.220 U 103 75-125 - - - - - - - - - - - - - Matrix Spike Dup (9I10030-MSD1) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 09/10/2019 16:30 Analyzed: 09/11/2019 14:45 - - - - - - - - Source: CC14876-01 �Analyte Spike Source %REC RPD Result Flag MRL Units Level Result %REC Limits RPD Limit Notes Antimony 40.9 2.00 ug/L 40.0 0.740 U 102 75-125 1 20 Selenium 41.6 2.00 ug/L 40.0 1.82 U 104 75-125 4 20 Thallium 39.9 2.00 ug/L 40.0 0.220 U 100 75-125 3 20 - - - - - - - - - - - - - - Post Spike (9I30030-PS1) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 09/10/2019 16:30 Analyzed: 09/11/2019 14:49 - - - - - - - - Source: CC14876-01 �Analyte Spike Source %REC RPD Result Flag MRL Units Level Result %REC Limits RPD Limit Notes Antimony 21.4 1.00 ug/L 20.0-0.00180 107 75-125 Selenium 33.9 1.00 ug/L 20.0 0.0944 169 75-125 QM-08 Thallium - - - - - - - - - - - - - - 20.9 - - - - - - - 1.00 - - - - ug/L - - - - 20.0 0.00358 104 75-125 - - - - - - - - - - - - - - - - - - - - - - - - - - - - Page 7 of 9 (� 0a www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-08 Post -digestion spike did not meet method requirements due to confirmed matrix effects (dilution test). Page 8 of 9 Sample Preservation Verification ENCo Cary cephh;'Jes Work Order: CC14876 Project: Surry Lined MSWLF Client: Municipal Engineering Services (MU001 ) Project #: G08024.0 Lined Lagged in: 04-Sep-19 17:43 �1 Lagged By: Jahn C King �1 1 Preservation Check Performed By: Date/Time: CC 14876-01 Cant Type Pres (pH) pH Checked f pH Adjusted Oate(T�me Reagent UsedrComments Requirement An Control Adjusted A 1250mLP,HNO3 1 �2 Y + N 1 NA I Y i.'N / NA Reagent Name I❑ 1 2 pH Strip ID: ( Reagent Name I❑ 3 4 Reactent Name I❑ 5 fi C:%ELMNT1Pdntlwka_PreservationCheck.rpt Page 1 Environmental Conservation Laboratories, Inc. 102-A Woodwinds Industrial Court Cary NC, 27511 Phone: 919.467.3090 FAX: 919.467.3515 Monday, September 16, 2019 Municipal Engineering Services (M0001) Attn: Jonathan Pfohl 68 Shipwash Drive Garner, NC 27529 RE: Laboratory Results for Project Number: G08024.0 Lined, Project Name/Desc: Surry Lined MSWLF ENCO Workorder(s): CC11486 Dear Jonathan Pfohl, Enclosed is a copy of your laboratory report for test samples received by our laboratory on Monday, July 8, 2019. Unless otherwise noted in an attached project narrative, all samples were received in acceptable condition and processed in accordance with the referenced methods/procedures. Results for these procedures apply only to the samples as submitted. The analytical results contained in this report are in compliance with NELAC standards, except as noted in the project narrative if applicable. This report shall not be reproduced except in full, without the written approval of the Laboratory. This report contains only those analyses performed by Environmental Conservation Laboratories. Unless otherwise noted, all analyses were performed at ENCO Cary. Data from outside organizations will be reported under separate cover. If you have any questions or require further information, please do not hesitate to contact me. Sincerely, 00, (/ L- - C�- A Chuck Smith Project Manager Enclosure(s) (� �C—O www.encolabs.com The total number of pages in this report, including this page is 9. (� 0a www.encolabs.com SAMPLE SUMMARY/LABORATORY CHRONICLE Client ID: MW-11D Lab ID: CC11486-02 Sampled: 07/08/19 08:50 Received: 07/08/19 13:55 Parameter Preparation Hold Date/Time(s) EPA 8260D EPA 5030B_MS 07/22/19 Pren Date/Time(s) Analysis Date/Time(s) 07/08/19 15:03 07/08/19 23:41 Page 2 of 9 SAMPLE DETECTION SUMMARY No positive results detected. (� 0a www.encolabs.com Page 3 of 9 (� �C-o www.encolabs.com ANALYTICAL RESULTS Description: MW-11D Lab Sample ID: CC11486-02 Received: 07/08/19 13:55 Matrix: Ground Water Sampled: 07/08/19 08:50 Work Order: CC11486 Project: Surry Lined MSWLF Sampled By: J.Pfohl Volatile Organic Compounds by GCMS - - - - - - - - - - - - - - - - - ^ - ENCO Cary certified analyte [NC 5911 Analyte rCAS Number] Results Flan Units DF MDL MRL NC SWSL Method Analyzed ft Notes 1,1,1,2-Tetrachloroethane [630-20-6] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK 1,1,1-Trichloroethane [71-55-6] ^ 0.12 U ug/L 1 0.12 1.0 EPA 8260D 07/08/19 23:41 MRK 1,1,2,2-Tetrachloroethane [79-34-5] ^ 0.28 U ug/L 1 0.28 1.0 EPA 8260D 07/08/19 23:41 MRK 1,1,2-Trichloroethane [79-00-5] ^ 0.14 U ug/L 1 0.14 1.0 EPA 8260D 07/08/19 23:41 MRK 1,1-Dichloroethane [75-34-3] ^ 0.13 U ug/L 1 0.13 1.0 EPA 8260D 07/08/19 23:41 MRK 1,1-Dichloroethene [75-35-4] ^ 0.21 U ug/L 1 0.21 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2,3-Trichloropropane [96-18-4] ^ 0.23 U ug/L 1 0.23 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2-Dibromo-3-chloropropane [96-12-8] ^ 0.48 U ug/L 1 0.48 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2-Dibromoethane [106-93-4] ^ 0.66 U ug/L 1 0.66 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2-Dichlorobenzene [95-50-1] ^ 0.19 U ug/L 1 0.19 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2-Dichloroethane [107-06-2] ^ 0.21 U ug/L 1 0.21 1.0 EPA 8260D 07/08/19 23:41 MRK 1,2-Dichloropropane [78-87-5] ^ 0.10 U ug/L 1 0.10 1.0 EPA 8260D 07/08/19 23:41 MRK 1,4-Dichlorobenzene [106-46-7] ^ 0.19 U ug/L 1 0.19 1.0 EPA 8260D 07/08/19 23:41 MRK 2-Butanone [78-93-3] ^ 1.3 U ug/L 1 1.3 5.0 EPA 8260D 07/08/19 23:41 MRK 2-Hexanone [591-78-6] ^ 0.88 U ug/L 1 0.88 5.0 EPA 8260D 07/08/19 23:41 MRK 4-Methyl-2-pentanone [108-10-1] ^ 1.1 U ug/L 1 1.1 5.0 EPA 8260D 07/08/19 23:41 MRK Acetone [67-64-1] ^ 10 U ug/L 1 10 20 EPA 8260D 07/08/19 23:41 MRK Acrylonitrile [107-13-1] ^ 3.5 U ug/L 1 3.5 10 EPA 8260D 07/08/19 23:41 MRK Benzene [71-43-2] ^ 0.15 U ug/L 1 0.15 1.0 EPA 8260D 07/08/19 23:41 MRK Bromochloromethane [74-97-5] ^ 0.48 U ug/L 1 0.48 1.0 EPA 8260D 07/08/19 23:41 MRK Bromodichloromethane [75-27-4] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK Bromoform [75-25-2] ^ 0.22 U ug/L 1 0.22 1.0 EPA 8260D 07/08/19 23:41 MRK Bromomethane [74-83-9] ^ 0.14 U ug/L 1 0.14 1.0 EPA 8260D 07/08/19 23:41 MRK Carbon disulfide [75-15-0] ^ 1.5 U ug/L 1 1.5 5.0 EPA 8260D 07/08/19 23:41 MRK Carbon tetrachloride [56-23-5] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK Chlorobenzene [108-90-7] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK Chloroethane [75-00-3] ^ 0.23 U ug/L 1 0.23 1.0 EPA 8260D 07/08/19 23:41 MRK Chloroform [67-66-3] ^ 0.18 U ug/L 1 0.18 1.0 EPA 8260D 07/08/19 23:41 MRK Chloromethane [74-87-3] ^ 0.13 U ug/L 1 0.13 1.0 EPA 8260D 07/08/19 23:41 MRK cis-1,2-Dichloroethene [156-59-2] ^ 0.15 U ug/L 1 0.15 1.0 EPA 8260D 07/08/19 23:41 MRK cis-1,3-Dichloropropene [10061-01-5] ^ 0.20 U ug/L 1 0.20 1.0 EPA 8260D 07/08/19 23:41 MRK Dibromochloromethane [124-48-1] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK Dibromomethane [74-95-3] ^ 0.27 U ug/L 1 0.27 1.0 EPA 8260D 07/08/19 23:41 MRK Ethylbenzene [100-41-4] ^ 0.13 U ug/L 1 0.13 1.0 EPA 8260D 07/08/19 23:41 MRK Iodomethane [74-88-4] ^ 1.7 U ug/L 1 1.7 5.0 EPA 8260D 07/08/19 23:41 MRK Methylene chloride [75-09-2] ^ 0.23 U ug/L 1 0.23 1.0 EPA 8260D 07/08/19 23:41 MRK Styrene [100-42-5] ^ 0.11 U ug/L 1 0.11 1.0 EPA 8260D 07/08/19 23:41 MRK Tetrachloroethene [127-18-4] ^ 0.17 U ug/L 1 0.17 1.0 EPA 8260D 07/08/19 23:41 MRK Toluene [108-88-3] ^ 0.14 U ug/L 1 0.14 1.0 EPA 8260D 07/08/19 23:41 MRK trans-1,2-Dichloroethene [156-60-5] ^ 0.21 U ug/L 1 0.21 1.0 EPA 8260D 07/08/19 23:41 MRK trans-1,3-Dichloropropene [10061-02-6] ^ 0.15 U ug/L 1 0.15 1.0 EPA 8260D 07/08/19 23:41 MRK trans-1,4-Dichloro-2-butene [110-57-6] ^ 0.70 U ug/L 1 0.70 1.0 EPA 8260D 07/08/19 23:41 MRK Trichloroethene [79-01-6] ^ 0.15 U ug/L 1 0.15 1.0 EPA 8260D 07/08/19 23:41 MRK Trichlorofluoromethane [75-69-4] ^ 0.24 U ug/L 1 0.24 1.0 EPA 8260D 07/08/19 23:41 MRK Vinyl acetate [108-05-4] ^ 0.95 U ug/L 1 0.95 5.0 EPA 8260D 07/08/19 23:41 MRK Vinyl chloride [75-01-4] ^ 0.32 U ug/L 1 0.32 1.0 EPA 8260D 07/08/19 23:41 MRK Xylenes(Total) [1330-20-7] ^ 0.45 U ug/L 1 0.45 3.0 EPA 8260D 07/08/19 23:41 MRK Page 4 of 9 Description: MW-11D Matrix: Ground Water Project: Surry Lined MSWLF Lab Sample ID: CC11486-02 Sampled: 07/08/19 08:50 Sampled By: J.Pfohl (� �Eo www.encolabs.com Received: 07/08/ 19 13: 55 Work Order: CC11486 Volatile Organic Compounds by GCMS - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - ^ - ENCO Cary certified anaiyte [NC 591] Analvte iCAS Numberl Results Flag Ynits DF MDL MRL NC SWSL Method Analyzed By Notes Surrogates Results DF Spike Lvi % Rec % Rec Limits Batch Method Analyzed By Notes 4-8romofluorobenzene 53 1 50.0 106 % 53-136 Dibromofluoromethane 49 1 50.0 98 % 67-129 Toluene-d8 50 1 50.0 100 % 59-134 This report relates only to the sample as received by the laboratory, and may only be reproduced in full. 9GO5030 EPA 8260D 07108119 23:41 MRK 9GO5030 EPA 8260D 07108119 23:41 MRK 9GO5030 EPA 8260D 07108119 23:41 MRK Page 5 of 9 QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 9GO5030 - EPA 5030E MS (� 0a www.encolabs.com Blank (9G05030-BLK3) Prepared: 07/05/2019 15:03 Analyzed: 07/08/2019 16:53 �Analyte Spike Source %REC RPD Result Flag MRL Units Level Result %REC Limits RPD Limit Notes 1,1,1,2-Tetrachloroethane 0.17 U 1.0 ug/L 1,1,1-Trichloroethane 0.12 U 1.0 ug/L 1,1,2,2-Tetrachloroethane 0.28 U 1.0 ug/L 1,1,2-Trichloroethane 0.14 U 1.0 ug/L 1,1-Dichloroethane 0.13 U 1.0 ug/L 1,1-Dichloroethene 0.21 U 1.0 ug/L 1,2,3-Trichloropropane 0.23 U 1.0 ug/L 1,2-Dibromo-3-chloropropane 0.48 U 1.0 ug/L 1,2-Dibromoethane 0.66 U 1.0 ug/L 1,2-Dichlorobenzene 0.19 U 1.0 ug/L 1,2-Dichloroethane 0.21 U 1.0 ug/L 1,2-Dichloropropane 0.10 U 1.0 ug/L 1,4-Dichlorobenzene 0.19 U 1.0 ug/L 2-Butanone 1.3 U 5.0 ug/L 2-Hexanone 0.88 U 5.0 ug/L 4-Methyl-2-pentanone 1.1 U 5.0 ug/L Acetone 10 U 20 ug/L Acrylonitrile 3.5 U 10 ug/L Benzene 0.15 U 1.0 ug/L Bromochloromethane 0.48 U 1.0 ug/L Bromodichloromethane 0.17 U 1.0 ug/L Bromoform 0.22 U 1.0 ug/L Bromomethane 0.14 U 1.0 ug/L Carbon disulfide 1.5 U 5.0 ug/L Carbon tetrachloride 0.17 U 1.0 ug/L Chlorobenzene 0.17 U 1.0 ug/L Chloroethane 0.23 U 1.0 ug/L Chloroform 0.18 U 1.0 ug/L Chloromethane 0.13 U 1.0 ug/L cis- 1,2-Dichloroethene 0.15 U 1.0 ug/L cis- 1,3-Dichloropropene 0.20 U 1.0 ug/L Dibromochloromethane 0.17 U 1.0 ug/L Dibromomethane 0.27 U 1.0 ug/L Ethylbenzene 0.13 U 1.0 ug/L Iodomethane 1.7 U 5.0 ug/L Methylene chloride 0.23 U 1.0 ug/L Styrene 0.11 U 1.0 ug/L Tetrachloroethene 0.17 U 1.0 ug/L Toluene 0.14 U 1.0 ug/L trans-1,2-Dichloroethene 0.21 U 1.0 ug/L trans-1,3-Dichloropropene 0.15 U 1.0 ug/L trans-1,4-Dichloro-2-butene 0.70 U 1.0 ug/L Trichloroethene 0.15 U 1.0 ug/L Trichlorofluoromethane 0.24 U 1.0 ug/L Vinyl acetate 0.95 U 5.0 ug/L Vinyl chloride 0.32 U 1.0 ug/L Xylenes (Total) 0.45 U 3.0 ug/L 5urrogate:4-Bromofluorobenzene 53 ug/L 50.0 107 53-136 Page 6 of 9 QUALITY CONTROL Volatile Organic Compounds by GCMS - Quality Control Batch 9GO5030 - EPA 5030B M5 (� �C-O www.encolabs.com Blank (9G05030-BLK1) Continued Prepared: 07/05/2019 15:03 Analyzed: 07/08/2019 16:53 Spike Source %REC RPD Analyte MRL Level ResultIII! o C Limits RPD Limit Notes Surrogate: Dibromofluoromethane 49 ug/L 50.0 98 67-129 Surrogate: Toluene-d8 52 ug/L 50.0 104 59-134 - - - - - - - - - - - - - - LCS (9G05030-BSI) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 07/05/2019 15:03 Analyzed: 07/08/2019 14:47 - - - - - - - - Spike Source %REC RPD Analyte MRL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 21 1.0 ug/L 20.0 104 75-133 Benzene 23 1.0 ug/L 20.0 114 80-134 Chlorobenzene 19 1.0 ug/L 20.0 94 80-120 Toluene 19 1.0 ug/L 20.0 95 71-120 Trichloroethene 20 1.0 ug/L 20.0 99 74-120 - - - - - - - - - - - - - - Matrix Spike (9G05030-MS1) - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 07/05/2019 15:03 Analyzed: 07/08/2019 15:18 - - - - - - - - Source: CC11353-04 �Analyte Mow -units Spike Source %REC RPD Result Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 21 1.0 ug/L 20.0 0.21 U 106 75-133 Benzene 22 1.0 ug/L 20.0 0.15 U ill 80-134 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 94 80-120 Toluene 19 1.0 ug/L 20.0 0.14 U 93 71-120 Trichloroethene 27 1.0 ug/L 20.0 0.15 U 134 74-120 QM-07 - - - - - - Matrix Spike Dup (9G05030-MSD1) - - - - - - - - - - - - - - - - - - - - - - - - - - - Prepared: 07/05/2019 15:03 Analyzed: 07/08/2019 15:50 Source:CC11353-04 �Analyte Spike Source %REC RPD Flag MRL Units Level Result %REC Limits RPD Limit Notes 1,1-Dichloroethene 20 1.0 ug/L 20.0 0.21 U 100 75-133 5 20 Benzene 21 1.0 ug/L 20.0 0.15 U 107 80-134 4 17 Chlorobenzene 19 1.0 ug/L 20.0 0.17 U 93 80-120 0.4 16 Toluene 18 1.0 ug/L 20.0 0.14 U 91 71-120 2 17 Trichloroethene - - - - - - - - - - - - - - 28 - - - - - - - 1.0 - - ug/L - 20.0 0.15 U 138 74-120 3 - - - - - - - - - - - - - - - - 22 QM-07 Page 7 of 9 (� 0a www.encolabs.com FLAGS/NOTES AND DEFINITIONS B The analyte was detected in the associated method blank. D The sample was analyzed at dilution. J The reported value is between the laboratory method detection limit (MDL) and the laboratory method reporting limit (MRL), adjusted for actual sample preparation data and moisture content, where applicable. U The analyte was analyzed for but not detected to the level shown, adjusted for actual sample preparation data and moisture content, where applicable. E The concentration indicated for this analyte is an estimated value above the calibration range of the instrument. This value is considered an estimate. MRL Method Reporting Limit. The MRL is roughly equivalent to the practical quantitation limit (PQL) and is based on the low point of the calibration curve, when applicable, sample preparation factor, dilution factor, and, in the case of soil samples, moisture content. PQL PQL: Practical Quantitation Limit. The PQL presented is the laboratory MRL. N The analysis indicates the presence of an analyte for which there is presumptive evidence (85% or greater confidence) to make a "tentative identification". P Greater than 25% concentration difference was observed between the primary and secondary GC column. The lower concentration is reported. [CALC] Calculated analyte - MDL/MRL reported to the highest reporting limit of the component analyses. QM-07 The spike recovery was outside acceptance limits for the MS and/or MSD. The batch was accepted based on acceptable LCS recovery. Page 8 of 9 I r a r� 0 cn ch m CD _OL CD e z 0 c cr 3 CL 0 z C) 0 ca CD cl zr CD 0 3 a CD Ln co X (A c a m CD I rpq CD 5 c tt c C qu lb- - � C, 0 � Co _ U) CD CD% co `' ..�MWW • ,� ..�. CD �. ,. "a ri -nCD .�* D (D �. y t CD CD�* • CD L > 'aF Q C 0 It o a D IOD Z COCD c CMD Cy 0 D cn c :3 - -� k 0 o CD cn CL �-, 0 C)' zw CD O CDcl } 0 OCR (Appendi 0 o ,j 0 0 ul CD CD cm CD CD CD CD CIS - CD CD 2 M z CD co CD CL � MGo 0 CD CD 07 to V! 0 r� CD 3 CD 0 CD C) U CD `° % D °? �- X � C: m —4 D _. 0 r • D 1 . la) CL 0 00 N3 i • :� O 0 cs� CD 4 M W iLLn LM 0 Appendix B Field Sampling Parameter Data Sheet(s) f Field Sampling Data Sheet Project: Surry Co Subtitle D Lined MSWLF Samplers: Page-1—of-2- Sampling Parameters Water Quality Parameters (Stabilized) Depth to p Water Depth to p Water Volume Sample Goes Dry Total Depth Total DO Temp. Specific Hardness � D eil2r- >�as- Monitoring Purge Purge Collect Collect Point Date Time Date Time (BTOP) (BTOP) Purged Type During Measured Depth Comments (mg/L) ORP pH © Cond. (mg/L)pofis P Static Collection (Gal) Purge as Expected (us/cm Hfva� expected MW-1 I ,a . 70.3 ( I l ? e' m 26.74MW-2 MW-3R : 4 1„ / 26 =' !j . �� s 22.1 ) D M W-4S _ � "_... s :. r `. ) 43.1 t!s - , i 079 MW-4D ,4;, u �' a: MW-5 Y�,`r i� ��`;' )" � , x 48.5 �,. �, 4>63 MW-6R _ �:,. a, r 81.3 s _ .030 MW-8 ? )'':`) e dw 70.75r� MW-9S d d #. f ' t' 42.28 MW-9D 65.54 (,..s t_ 0 47.13 jfLi R MW-10 MW-11S 46.05 .- MW-11D f '- „„ r \ ,a t)' $'f_ 65.31 eC- ` e MW-12 $' 65 5,34 MW-13 �{ r, (f, ". :f z in ;F 36.31 MLW-A 93.5 / es SW-D LAGOON r , e SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained Field Sampling Data Sheet Mnnlclpwl �LL �` H rin Project: Surry Co Subtitle D Lined MSWLF Samplers: Page-2—of 2 Monitoring Point Sample Date Sample Time Sample Date Sample Time Sampling Parameters �— Water Quality Parameters Depth to Water (BTOP) Static Lab Parameters to be analyzed for Volume Purged (Gal) Sample Type Goes Dry During Purge Total Depth Measured as expected Total Depth Expected Comments DO (mg/L) ORP pH Temp. © Specific Cond. (us/cm TDS (mg/L) a — � � ~ CH4 Gas Vapors (ppm) P-4 WL.Ronl - - - - - - - - - - MW-28 I - I WLR only P2-11S - - I E` WLR only - - - - P2-11 D I - I - `l> ,, WLR only P2-12 I - -iiq WLR only- MW-26 I - - WLR only I I I I I I I I I I I I I i I I I I I I I SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained •' • • .EEM rvl uniclPnl U IJ�L� FnN� ccrtne � Project: Surry Co Closed C&D over Closed MSWLF & Active Subtitle D Lined- Mt Airy (Shared Surface Waters) 5arnpiers: y , t �_ ,,. Sampling Parameters Water Quality Parameters (Stabilized) MonitoringCollect Point Date Collect Time Visual Flow Rate Lab Parameters to be analyzed for Visual Guage Ht. Sample Type Goes Dry During Purge Total Depth Measured as expected Comments DO m /L ( 9 ) ORP pH Temp. © Specific Cond. (us/cm Hardness (mg/L ) E— CHs Gas Vapors m (pp ) SW-2 Il ij i ` SW-3i�{ r . SW-4- SWN-1.* I L.n SWN-2 / SW - �� . _ �3 ., ' � : I - - 0 ,, 14 ? - SS B=Stainless Steel Baler, D B=Disposable Baler, P=Low flow Pump, PD=Purged Dry VT=Very Turbid, MT=Moderately Turbid, ST=Slightly Turbid, C=Clear NR=No Reading Attempted, NS=No Sample Obtained