1202_Burke_EastBurke_MSWLF_GW_FID1357482_20190904

pENR USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6)
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source. pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates (Joyce Engineering)
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or. 1600) October 20-24, 2006)
Burke Co. - East Burke Landfill Rhodiss Road 12-02 .0500 May 6, 2019
Rhodiss, NC July 23-24, 2019
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring �X Detection Monitoring Assessment Monitoring ❑ Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells Methane gas monitoring data
Groundwater monitoring data from private water supply wells Corrective action data (specify)
Leachate monitoring data
Surface water monitoring data Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. Van Ness Burbach. Ph.D., P.G. Sr. Technical Consultant [phone]
Facilityleyfes r�jive L4ne (Print) Title (Area Code) Telephone Number
Affix NC Lj /Professional Geologist Seal Q% O//�j
UAROl/GAS
J , y
Signature
2211 W. Meadowview Rd.. Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-0782
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009
SEAL
1349
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LaBeRa
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September 3, 2019
Jaclynne Drummond
Compliance Hydrogeologist
NC Department of Environmental Quality
Division of Waste Management - Solid Waste Section
2090 US Highway 70, Swannanoa, NC 28778
RE: Burke County, East Burke Landfill, Permit Number 12-02
May 2019 Semiannual Water Quality Monitoring Report
Project No. 2192621
Dear Ms. Drummond:
On behalf of Burke County, we are submitting the May 2019 Semiannual Water Quality Monitoring
Report in electronic format, as well as a copy of the Environmental Monitoring Form and the
laboratory EDD's for the East Burke Landfill, Permit # 12-02. This report completes the first
semiannual compliance monitoring event of 2019 as required by the North Carolina Division of
Waste Management, Solid Waste Section. If we can provide any additional information please call
me at [phone].
Respectfully submitted,
LaBella Associates
Van Burbach, Ph.D., P.G.
Sr. Technical Consultant
cc: Miles Champion, Burke County
2211 W. Meadowview Road #sos I Greensboro, NC 27407 1 p [phone]
www.LabeLLapc.com

Prepared For:
BOARD OF COMMISSIONERS
COUNTY OF BURKE
P.O. BOX 1486
MORGANTON, NORTH CAROLINA 28680
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Submitted by:
LaBella Associates (Joyce Engineering)
2211 West Meadow/view Rd.
Suite 1o1
Greensboro, NC 27407
(336) 323-00g2
NC License No. C-0782
LaBeRa
Powered by partnership.
MAY 2019 SEMIANNUAL WATER QUALITY
MONITORING REPORT
EAST BURKE LANDFILL
Permit No. 12-02
SEPTEMBER 2019
PROJECT NO. 2192621

May 2019 Semiannual Water Quality Monitoring Report
East Burke Landfill, Permit No. 12-02
Burke County, North Carolina
TABLE OF CONTENTS
1.0
INTRODUCTION.................................................................................................................1
1.1
Site Information................................................................................................................1
1.2
Regulatory Status.............................................................................................................1
2.0
FACILITY MONITORING PROGRAM...................................................................................1
2.1
Groundwater Monitoring Program...................................................................................1
2.2
Surface Water Monitoring Program.................................................................................2
3.0
MAY 2019 SEMIANNUAL SAMPLING EVENT...................................................................2
3.1 Field Work.........................................................................................................................2
3.2 Laboratory Analysis and Quality Control..........................................................................3
4.0 HYDROGEOLOGY..............................................................................................................3
5.0
DATA ANALYSIS................................................................................................................4
5.1
Analytical Results and Comparison to Standards...........................................................5
5.1.1 Groundwater................................................................................................................5
5.1.2 Surface Water............................................................................................................. 6
5.1.3 Resampling Event.......................................................................................................6
6.0
CONCLUSIONS..................................................................................................................6
7.0
REFERENCES....................................................................................................................7
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019

May 2019 Semiannual Water Quality Monitoring Report
East Burke Landfill, Permit No. 12-02
Burke County, North Carolina
TABLE OF CONTENTS CONTINUED
Tables
Table 1 May 2019 Groundwater Elevations
Table 2 May 2019 Estimated Hydraulic Gradients and Velocities
Table 3 May 2019 Detections
Table 4 May 2019 Exceedances
Table 5 May 2019 Field Parameters
Figure
Figure 1 Site Location Map
Drawing
Drawing 1 May 2019 Groundwater Potentiometric Surface Map
Appendix
Appendix 1
Laboratory Analytical Reports and Field Logs
Appendix 2
Historical Data
Table A2-1
Historical Groundwater Elevations
Table A2-2
Historical Groundwater Constituents
Table A2-3
Historical Surface Water Constituents
Table A2-4
Historical Groundwater Field Parameters
Table A2-5
Historical Surface Water Field Parameters
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019

1.0 INTRODUCTION
1.1 Site Information
The East Burke Landfill, Permit No. 12-02, is located in Burke County, North Carolina as
shown on Figure 1. The landfill was operated by Burke County as a municipal solid waste
(MSW) landfill between 1972 and 1988 and has been closed to the reception of waste
since 1988.
1.2 Regulatory Status
The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste
Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993.
The County monitors' groundwater at the landfill in accordance with criteria set forth in
Rule .0600 of the NCSWMR.
In March 1995, the North Carolina Department of Environment and Natural Resources
(NCDENR), now the Department of Environmental Quality (NCDEQ), requested that the
facility perform additional site contamination investigation activities due to the quantified
detections of organic constituents in the groundwater on site. In response to this request
a Water Quality Assessment Plan for the East Burke Landfill was submitted to the Solid
Waste Section (SWS) in September of 1995. Updates on Groundwater Assessment
Activities were submitted to NCDENR SWS in June 2003 and August 2003.
2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Groundwater monitoring at the East Burke Landfill is completed in accordance with the
monitoring requirements of Rule .0600 of the NCSWMR. Groundwater samples are
collected semiannually. The current compliance network consists of the following
monitoring wells: MW-1 (background), MW-2, MW-3, and AMW-1. A site plan indicating
the facility and waste boundaries in addition to monitoring well locations can be found in
Drawing 1. All monitoring wells are monitored for the NC Appendix I list of constituents.
Monitoring
Date
Classification
Monitoring
Total Depth
Lithology of Screened
Well
Installed
Program
from TOC (ft)
Interval
MW-1
Unknown
Background
.0600
50.55
Bedrock (Est.)
MW-2
Unknown
Compliance
.0600
71.05
Bedrock (Est.)
MW-3
Unknown
Compliance
.0600
32.50
Saprolite (Est.)
AMW-1
Apr. 1, 2003
Compliance
.0600
7.25
Saprolite
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
1

2.2 Surface Water Monitoring Program
Surface water monitoring at the East Burke Landfill is completed in accordance with the
monitoring requirements of Rule .0600 of NCSWMR. Surface water samples are collected
semiannually and are analyzed for the NC Appendix I constituents plus 1,4-dioxane.
The surface water monitoring network consists of two sampling points: SW-1 located
upstream from the sediment pond, and SW-2 located downstream from MW-3 and
AMW-1. The approximate locations of the sampling points are shown on Drawing 1.
Surface Point
Classification
Monitoring Program
SW-1
SW-2
Compliance
Compliance
.0600
.0600
3.0 MAY 2019 SEMIANNUAL SAMPLING EVENT
3.1 Field Work
On May 6, 2019, personnel from LaBella Associates (formerly Joyce Engineering) visited
the East Burke Landfill to obtain water levels to the nearest 0.01 foot, purge, and sample
monitoring wells MW-1, MW-2, MW-3, and AMW-1, and sample the two surface
monitoring points, SW-1 and SW-2. On July 23-24, 2019, personnel from LaBella
Associates were on site again to resample monitoring wells MW-2 and MW-3.
Monitoring wells were purged and sampled using disposable bailers during the May 2019
sampling event. Measurements of temperature, pH, specific conductivity, dissolved
oxygen, oxidation reduction potential, and turbidity were recorded in the site log book
prior to purging, after each purge volume, and during sampling. Prior to sampling,
laboratory -supplied containers were prepared with the following information:
• Monitoring well number (completed by field personnel);
• Date and time of sample collection (completed by field personnel);
• Initials of sampling personnel (completed by field personnel);
• Project name and number (completed by the laboratory);
• Chemical preservative (completed by the laboratory); and
• Requested chemical analysis (completed by the laboratory).
Groundwater samples from each monitoring well were collected directly from the
disposable bailers in the provided laboratory containers either immediately after purging
or within 24 hours of the final purge volume. Immediately after collection, the samples
were placed on ice in a laboratory -provided cooler. Copies of the field data logs are
provided in Appendix 1.
The surface water monitoring points SW-1 and SW-2 were collected directly from stream
by lowering a clean, unpreserved sample container into the stream flow and dispensing
the water into laboratory -prepared sample containers. Care was taken to avoid
sample -induced turbidity. At the time of sampling, surface water was also measured for
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
2

temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential,
and turbidity and recorded in the field data log. Immediately after collection, the samples
were placed on ice in a laboratory -provided cooler. Copies of the field data logs are
presented in Appendix 1.
3.2 Laboratory Analysis and Quality Control
The May 6, 2019, groundwater and surface water samples and the July 23-24, 2019,
groundwater samples were submitted to Pace Analytical Services, Inc. of Huntersville,
North Carolina under chain -of -custody control for analysis. LaBella requested a Level II
data report for the final laboratory report. The samples were received by the laboratory
on May 9, 2019, in good condition, properly preserved, and within analysis hold times.
In addition to samples collected for compliance monitoring at the East Burke Landfill, a
Field Blank was collected by LaBella Associates personnel as part of the May 2019
sampling event. A Trip Blank was also prepared by the laboratory to accompany the
volatile samples during shipment. The Field Blank was analyzed for the NC Appendix I list
compounds and 1,4-dioxane while the Trip Blank was analyzed for NC Appendix I VOCs
and 1,4-dioxane.
Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel
for the following:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Correct analyte lists;
• Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix
Spike Duplicate, and Laboratory Control Samples;
• Blank qualified data (B-flags);
• Detections above the Method Reporting Limits (MRL);
• Detections above the 15A NCAC2L (NC2L) Groundwater Standards, NC
Interim Maximum Allowable Concentrations (IMACs), 15A NCAC213 (NC2B)
Surface Water Standards, or NC Protective Values (NCPV); and
• Detections that are above historical levels.
4.0 HYDROGEOLOGY
The surFicial aquifer is believed to include the regolith and the underlying fractured
metamorphic bedrock. The regolith consists of alluvium, residual soils, saprolite, and
variably fractured and weathered layered metamorphic rock. In this regard, regolith
behaves similar to unweathered bedrock, except that fractures are more numerous and
better connected in the regolith, and will tend to have more isotropic hydraulic properties.
Groundwater discharges into an unnamed tributary to Lake Rhodhiss, northeast of the
landfill. A groundwater potentiometric surface map, developed from static water level
data obtained on May 6, 2019 is presented as Drawing 1.
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
3

Depth to groundwater was measured in the compliance monitoring wells at the site prior
to sampling. The groundwater elevations were calculated relative to the surveyed
measuring point (top of casing) for each monitoring well to ±0.01 ft. The groundwater
elevations are summarized in Table 1 for the May 2019 monitoring event. Historical
groundwater elevations are summarized in Table A2-1.
Groundwater flow beneath the waste management unit is primarily to the northeast.
Estimated horizontal groundwater gradients (i) from the May 2019 groundwater
elevations are presented in Table 2. The horizontal gradient (i) calculated for the facility
from the data was 0.0670.
Linear groundwater flow velocities (V) was estimated using the following modified Darcy
equation:
V = Ki/ne,
where:
V = average linear velocity (feet per day - ft/day);
K = hydraulic conductivity (ft/day);
i = horizontal hydraulic gradient; and
ne = effective porosity.
Hydraulic conductivity (K) was estimated at 3.28 ft/day based on slug tests from a nearby
site (John's River Landfill). An effective porosity (ne) of 20% was estimated based on
typical values for piedmont aquifers. The estimated linear groundwater flow velocity
under the facility is 401 ft/year (Table 2).
Because of our conservative estimate of effective porosity, actual groundwater velocities
may be significantly less than those calculated. Also, the modified Darcy equation makes
the simplified assumptions of a homogeneous and isotropic aquifer, which may yield
inaccurate results when applied to heterogeneous and/or anisotropic conditions such as
are believed to exist at this site.
Migration of groundwater contaminants are expected to follow the general groundwater
flow paths and there are no known preferred pathways or barriers to groundwater flow
that could significantly affect plume migration or the effectiveness of the groundwater
monitoring network to monitoring plume migration. The current groundwater monitoring
network remains sufficient for monitoring the groundwater at this facility.
5.0 DATA ANALYSIS
The final results from the May 2019 sampling event were received on May 21, 2019, for
all monitoring wells (MW-1, MW-2, MW-3, and AMW-1) and surface water monitoring
locations (SW-1 and SW-2). All analytical results can be found in Appendix 1. Table 3
summarizes the constituents detected at concentrations above the MDL in all monitoring
well and surface water samples for the May 2019 event. Constituents in exceedance of
the appropriate standards are summarized in Table 4. Field Parameters for the May
2019 sampling event are summarized in Table 5.
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
4

Analytical results from monitoring wells were compared directly to the North Carolina
Groundwater Standards found in 15A NCAC 02L.0202 (NC2L Standards) or the NC
Interim Maximum Allowable Concentrations (IMACs) for constituents with no listed NC2L
Standard. Note that estimated concentrations below the Method Reporting Limit (MRL)
are not considered exceedances of the standard, even if the estimated value is higher
than the standard.
Analytical results for surface water samples were compared directly to either the
Freshwater Aquatic Life Surface Water Standards or Fish Consumption Surface Water
Standards (whichever was lower) found in 15A NCAC 02B (NC2B Standards). For metals
which have hardness -dependent NC213 Standards, the hardness of the sample collected
was used to calculate the NC213 standard. For constituents which have NC213 standards
for both chronic and acute exposure, the chronic exposure standard was used. For
constituents with no NC2B standards, the results were compared to either the NC
protective standard (NCPS) or the EPA Nationally Recommended Water Quality Standard
(NRWQS). Note that estimated concentrations below the MRL are not considered
exceedances of the standard, even if the estimated value is greater than the standard.
5.1 Analytical Results and Comparison to Standards
5.1.1 Groundwater
Inorganic constituents detected at quantified concentrations in groundwater samples
during the May 2019 sampling event are listed in Table 3. All concentrations are
reported in micrograms per liter (pg/L). Concentrations with a "Y' are greater than the
method detection limit (MDL) but less than the method reporting limit (MRL), and are
considered to be estimated. Bold values indicate concentrations above the NC 2L or
IMAC in the groundwater samples. Historically detected constituents in groundwater can
be found in Table A2-2. Historical groundwater field parameters can be found in
Table A2-4.
The inorganic constituents detected above the MRL include: arsenic (MW-2), barium
(MW-1, MW-2, MW-3, AMW-1), cobalt (MW-1, MW-2, MW-3), nickel (MW-1, MW-2, MW-3),
and thallium (MW-1, MW-2, MW-3, AMW-1). The inorganic constituents detected at
quantified concentrations in exceedance of their respective NC 2L or IMAC include:
arsenic (MW-2), cobalt (MW-1, MW-2, and MW-3), and thallium (MW-2 and MW-3).
The organic constituents detected above the MRL include: benzene (MW-2, MW-3),
chlorobenzene (MW-2, MW-3), 1,4-dichlorobenzene (MW-2, MW-3), chloroethane (MW-2),
1,1-dichloroethene (MW-3), cis-1,2-dichloroethene (MW-1, MW-3, AMW-1),
1,2-dichloropropane (MW-2), 1,4-dioxane (MW-2, MW-3), tetrachloroethene (MW-3),
trichloroethene (MW-3), vinyl chloride (MW-3), xylene (MW-2). The organic constituents
detected at quantified concentrations in exceedance of their respective NC 2L or IMAC
standard include: benzene (MW-2, MW-3), 1,4-dichlorobenzene (MW-2),
1,2-dichloropropane (MW-2), 1,4-dioxane (MW-3), tetrachloroethene (MW-3),
trichloroethene (MW-3), vinyl chloride (MW-3). In general, these detections are consistent
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
5

with historical data for the inorganic and organic constituents, with the exception of the
exceedances of benzene in monitoring wells MW-2 and MW-3 and tetrachloroethene and
1,2-dichloropropane in MW-3.
5.1.2 Surface Water
During the May 2019 sampling event, the constituents detected above the MRL include:
barium (SW-1, SW-2), cobalt (SW-2), thallium (SW-2), and 1,4-dioxane (SW-1, SW-2).
Cobalt was detected above its respective NCPV in surface water monitoring point SW-2.
Historical surface water data can be found in Table A2-3. Historical surface water field
parameters can be found in Table A2-5.
5.1.3 Resampling Event
On July 23-24, 2019, LaBella Personnel collected detection verification samples from
monitoring well MW-2 for benzene, and from monitoring well MW-3 for benzene,
1,2-dichloropropane, and tetrachloroethene. Both exceedances of benzene were refuted
by the results of the resampling event. The exceedances of tetrachloroethene and
1,2-dichloropropane in monitoring well MW-3 were also refuted by the results of the
resampling event.
6.0 CONCLUSIONS
1,4-Dioxane was detected in exceedance of groundwater protection standards in
monitoring well MW-3. 1,4-Dioxane analyses were required by the NCDEQ for the first
time during the previous semiannual groundwater monitoring event, and the NCDEQ has
not yet issued a policy concerning regulatory response to 1,4-dioxane exceedances. We
recommend continuing to sample for 1,4-dioxane in order to establish possible trends
and/or seasonal variability. 1,4-Dioxane was detected in surface water samples SW-1
and SW-2. There is no NC213 surface water standard for 1,4-dioxane; however, there is a
NC Protective Value for 1,4-dioxane, which is 80 pg/I for non -water -supply surface waters.
None of the 1,4-dioxane detections exceeded the NCPV. Cobalt was detected in SW-2 in
exceedance of the NCPV.
According to historical groundwater data, inorganic and organic constituents detected
above the NC21- or IMAC in groundwater samples collected during the May 2019
sampling event are consistent with previous events with the exception of the benzene
exceedances in MW-2 and MW-3 and tetrachloroethene and 1,2-dichloropropane in
MW-3, all of which were refuted by resample data. Based on the results of this
groundwater monitoring event, the groundwater monitoring network remains adequate to
monitor groundwater at the site. The next semiannual sampling event is tentatively
scheduled for November 2019.
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
6

7.0 REFERENCES
North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995,
N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities.
RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD),
1986.
May 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Burke County - East Burke Landfill, Permit No. 12-02 September 2019
7

TABLES
Table 1 May 2019 Groundwater Elevations
Table 2 May 2019 Estimated Hydraulic Gradients and Velocities
Table 3 May 2019 Detections
Table 4 May 2019 Exceedances
Table 5 May 2019 Field Parameters

TABLE 1: May 2019 Groundwater Elevations
Depth to
Groundwater
TOC Elevation
Well Depth
Location
Groundwater
Lithology
Elevation
(Ft AMSL)
(Ft BTOC)
(Ft BTOC)
(Ft AMSL)
MW-1
1147
36.95
Saprolite
50.55
1110.05
MW-2
1096.5
54.47
Saprolite
71.05
1042.03
MW-3
1039
9.29
Bedrock
32.50
1029.71
AMW-1
1021
4.08
Bedrock
7.30
1016.92
Notes: TOC = Top of casing
Ft = feet
BTOC = Below TOC
BGS = Below ground surface
AMSL = Above mean sea level
Burke County -East Burke
Permit No. 12-02 Labella Associates

TABLE 2: May 2019 Estimated Hydraulic Gradients and Velocities
LINEAR
GRADIENT
FLOW LINE
FLOW
GROUNDWATER
HORIZONTAL
HYDRAULIC
EFFECTIVE
VELOCITY
CALCULATION
LENGTH
ELEVATION
CONDUCTIVITY K
POROSITY
DIRECTION
GRADIENT i
V
SEGMENT
(ft)
(ft)
(ft/day)
n e
(ft/year)
1100
i 1
1,194
NE
0.0670
3.28
0.20
401
1020
Notes:
The mean of K estimates from individual well slug tests from the Burke County
John's River Facility was used to calculate the hydraulic conductivity.
Velocity: V= Kiln e; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20).
Burke County -East Burke
Permit No. 12-02 LaBella Associates

TABLE 3: May 2019 Detections
Parameter
MDL
MRL
NC 2L/
IMAC*
GW Upg adient
GW Downgradient
MW-1
MW-2 MW-2* MW-3 MW-3*
AMW-1
Arsenic
5
10
10
5.0 J
20.4
ND
ND
Barium
2.5
5
700
56.3
40.6
113
50.8
Cobalt
2.5
5
1*
10.6
74.7
27.2
ND
Copper
2.5
10
1,000
ND
3.2 J
ND
ND
Nickel
2.5
5
100
5.5
62.0
9.7
ND
Thallium
0.06
0.1
.28*
0.13
0.42
0.91
0.17
Zinc
5
10
1,000
ND
8.0 J
- ND -
ND
Benzene
0.25
1
1
0.24 J
4.7
0.95 J 1.8 0.63 J
ND
Chlorobenzene
0.23
1
50
ND
35.5
- 8.9 -
ND
1,2-Dichlorobenzene
0.49
1
20
ND
0.88 J
ND
ND
1,4-Dichlorobenzene
0.33
1
6
0.74 J
14.0
4.9
ND
Chloroethane
0.52
1
3000
ND
1.7
ND
ND
1,1-Dichloroethane
0.32
5
6
ND
0.46 J
5.8
ND
cis-1,2-Dichloroethene
0.19
1
70
1.6
ND
18.0
1.4
1,2-Dichloropropane
0.6
1
0.6
ND
ND
1.0 ND
ND
1,4-Dioxane (p-Dioxane)
1.2
2
3
ND
2.7
33.1
1.9 J
Tetrachloroethene
0.78
1
0.7
ND
ND
11.3 ND
ND
Trichloroethene
0.34
1
3
ND
ND
6.0
ND
Vinyl Chloride
0.6
1
0.03
ND
ND
1.4
ND
Xylene(Total)
1.5
2
1 500
1 ND
17.2
ND
ND
Burke County -East Burke
Permit No. 12-02 1 of 2 LaBella Associates

TABLE 3: May 2019 Detections
Parameter
MDL
MRL
NC2B
SW-1 SW-2
Barium
2.5
5
21,000^
41.4 47.9
Beryllium
0.5
1
NE
ND 0.86 J
Cadmium
0.5
1
NE
ND 1.2 B
Cobalt
2.5
5
4^
3.5 J 7.8
Copper
2.5
5
3.09
ND 2.8 J
Lead
2.5
5
0.63
N D 2.7 J
Nickel
2.5
5
13.27
2.9 J 4.7 J
Thallium
0.06
0.1
0.47^^
0.072 J 0.10
Hardness (total)
662
662
NE
19900 28800
1,4-Dioxane (p-Dioxane)
1.2
2
80^
7.4 9.2
Chloroform
1 0.58
1 1
1 NE
I ND 0.72 J
Notes: All results are in micrograms per liter (pg/L).
MDL = Method Detection Limit
MRL = Method Reporting Limit
NC21L = NC Groundwater Standard from 15A NCAC 2L.0202
*IMAC = NC Interim Maximum Allowable Concentration
NC2B = NC Surface Water Standard from 15A NCAC 26
= NC Protective Value
^^ = EPA NRWQC (Naturally Recommended Water Quality Criteria)
NE = Not Established
ND = Not detected above the MDL
J = Estimated value below the MRL
* = Sample collected during July 23-24, 2019 resampling event
= Sample not analyzed for this constituent
Bold results are exceedances of the applicable standards.
Burke County -East Burke
Permit No. 12-02 2 of 2 La Bella Associates

TABLE 4: May 2019 Exceedances
Parameter
MDL
MRL
NC2L IMAC*
NCPV**
GW Upgradient
GW Downgradient
Surface Water
MW-1
MW-2 MW-2A MW-3 MW-3A
SW-2
Arsenic
5
10
10
-- 20.4 -- -- -- --
Cobalt
2.5
5
1*/4**
10.6 74.7 -- 27.2 -- 7.8
Thallium
0.06
0.1
0.28*
-- 0.42 -- 0.91 -- --
1,2-Dichloropropane
0.6
1
0.6
-- -- -- 1.0 ND --
1,4-Dichlorobenzene
0.33
1
6
-- 14.0 -- -- -- --
1,4-Dioxane
1.2
2
3
-- -- -- 33.1 --
Benzene
0.25
1
1
-- 4.7 0.95 J 1.8 0.63 J --
Tetrachloroethene
0.78
1
0.7
-- -- -- 11.3 ND --
Trichloroethene
0.34
1
3
-- -- -- 6.0 -- --
Vinyl Chloride
1 0.6
1 1
1 0.03
1 1.4 -- --
Notes: All results are in micrograms per liter (pg/L).
MDL = Method Detection Limit
MRL = Method Reporting Limit
NC21- = NC Groundwater Standard from 15A NCAC 2L.0202
*IMAC = NC Interim Maximum Allowable Concentrations
**= NC Protective Value (for surface water)
^ = Sample collected during 7/23-24/2019 resampling event
Burke County- East Burke Landfill
Permit No. 12-02
ND = not detected above the MDL
J = Estimated value below the MRL
LaBella Associates

TABLE 5: May 2019 Field Parameters
Parameter
Units
Collect Date
GW Upgradient
GW Downgradient
Surface Water
MW-1
MW-2 MW-2* MW-3 MW-3* AMW-1
SW-1 SW-2
pH
S.U.
5/6/2019
5.56
5.84
5.63
5.58
5.19
5.73
6.26
6.12
Temperature
°C
5/6/2019
17.3
17.4
18.6
16.8
16.7
15.6
16.5
16.6
Conductivity
pS/cm
5/6/2019
104.0
239.9
454.7
266.3
464.7
118.9
127.6
131.2
Dissolved Oxygen
mg/L
5/6/2019
1.29
2.31
2.93
1.35
0.69
3.28
5.90
6.32
Oxidation Reduction Potential
my
5/6/2019
96.9
69.6
119.6
176.0
147.9
146.1
145.3
155.3
Turbidity
NTU
5/6/2019
1.42
4.07
3.20
5.63
4.41
11.5
15.2
14.4
Static Water Level
Ft
5/6/2019
36.95
54.47
53.98
9.29
9.93
4.08
-
Well Depth
Ft
1
50.55
71.05
71.05
32.5
32.50
7.30
-
-
Notes: °C = degrees Centigrade
S.U. = Standard Units
pS/cm = microsemens per cm
NTU = Nephelometric Turbidity Units
Ft = feet
*=Sample collected during 7/23-24/2019 resampling event
Burke County -East Burke LaBella Associates
Permit No. 12-02

FIGURE
Figure 1 Site Location Map

0
. mxmw
lilk/ � 7A
_ ON
✓J
J
0 2211 WEST MEADOWVIEW ROAD SCALE PRoJEcT No. EAST BURKE LANDFILL
x FIGURE N0. 1 I ^�GREENSBORO, N.C. 27407
u r `� 1M2000' 277 =
PHONE: [phone] SITE LOCATION MAP
n
ENGINEERING ©2017 Joyce Engineering, Inc.
All dgM1is reserved.

DRAWING
Drawing 1 May 2019 Groundwater Potentiometric Surface Map

1020
1:1
- MW-1
ELEV
LEGEND
EXISTING 100' TOPOGRAPHIC CONTOUR
EXISTING 20' TOPOGRAPHIC CONTOUR
GROUNDWATER SURFACE CONTOUR [FEET
ABOVE MEAN SEA LEVEL (AMSL)]
PROPERTY LINE
GROUNDWATER FLOW PATHWAY USED TO
CALCULATE HYDRAULIC GRADIENT
EXISTING ROAD
APPROXIMATE LIMITS OF WASTE
CENTERLINE OF STREAM
COMPLIANCE WELL LOCATION AND IDENTIFICATION WITH STATIC
WATER LEVEL ELEVATION (FEET AMSL)
SURFACE MONITORING POINT LOCATION AND IDENTIFICATION
SEGMENT USED FOR GRADIENT CALCULATION
FLOW PATH LENGTH
Z� 1,194 LF
NOTES
� 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET.
I2. GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET.
\ 3. STATIC WATER LEVELS WERE MEASURED ON MAY 6, 2019.
4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION BETWEEN AND
EXTRAPOLATION FROM KNOWN DATA, TOPOGRAPHIC CONTOURS, AND KNOWN
FIELD CONDITIONS.
1 /
FIELD DETERMINED
EDGE OF WASTE
� I
1
1170.05
R / `>� �1100 I�
GP-5
o I�
Rr�
161,
SR 2300
FRIENDSHIP
METHODIST CHURCH
/ 1
GRAPHIC SCALE
0 150 300
(FEET)
Dr2=3
LaBeLLa
Powered by partnership.
9731-F SOUTHERN PINE BLVD
CHARLOTTE, NC 28273
PHONE: [phone]
labellapc.com
GO�S�
LNP,\
L
© 2019 LaBella Associates
EAST BURKE
LANDFILL
BURKE COUNTY, NORTH CAROLINA
NO: DATE: DESCRIPTION:
Revisions
PROJECT NUMBER:
2181871
DRAWN BY:
RH
REVIEWED BY:
MV
ISSUED FOR:
GROUNDWATER REPORT
DATE:
07/18/19
DRAWING NAME
PERMIT NO. 12-02
GROUNDWATER POTENTIOMETRIC
SURFACE MAP - MAY 65 2019
DRAWING NUMBER:
1

APPENDICES
Appendix 1 Laboratory Analytical Reports and Field Logs
Appendix 2 Historical Data

APPENDIX 1
Laboratory Analytical Reports and Field Logs

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 21, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on May 09, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Atlanta Certification IDs
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92428709001
1202-MW1
Water
05/06/19 08:50
05/09/19 09:31
92428709002
1202-MW2
Water
05/06/19 10:40
05/09/19 09:31
92428709003
1202-MW3
Water
05/06/19 12:09
05/09/19 09:31
92428709004
1202-AMW1
Water
05/06/19 12:45
05/09/19 09:31
92428709005
1202-SW1
Water
05/06/19 11:35
05/09/19 09:31
92428709006
1202-SW2
Water
05/06/19 12:40
05/09/19 09:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
BURKE CO. EAST BURKE
92428709
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92428709001
1202-MW1
EPA 601 OD
DS
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428709002
1202-MW2
EPA 601 OD
DS
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428709003
1202-MW3
EPA 601 OD
DS
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428709004
1202-AMW1
EPA 601 OD
DS
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428709005
1202-SW1
EPA 601 OD
DS
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428709006
1202-SW2
EPA 601 OD
DS
15
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
BURKE CO. EAST BURKE
92428709
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92428709001
1202-MW1
EPA 6010D
Arsenic
5.OJ
ug/L
10.0
05/20/19 09:27
EPA 6010D
Barium
56.3
ug/L
5.0
05/20/19 09:27
EPA 6010D
Cobalt
10.6
ug/L
5.0
05/20/19 09:27
EPA 6010D
Nickel
5.5
ug/L
5.0
05/20/19 09:27
EPA 6020B
Thallium
0.13
ug/L
0.10
05/20/19 23:57
EPA 8260D
1,4-Dichlorobenzene
0.74J
ug/L
1.0
05/16/19 22:09
EPA 8260D
Benzene
0.24J
ug/L
1.0
05/16/19 22:09
EPA 8260D
cis-1,2-Dichloroethene
1.6
ug/L
1.0
05/16/19 22:09
92428709002
1202-MW2
EPA 6010D
Arsenic
20.4
ug/L
10.0
05/20/19 09:40
EPA 6010D
Barium
40.6
ug/L
5.0
05/20/19 09:40
EPA 6010D
Cobalt
74.7
ug/L
5.0
05/20/19 09:40
EPA 6010D
Copper
3.2J
ug/L
5.0
05/20/19 09:40
EPA 6010D
Nickel
62.0
ug/L
5.0
05/20/19 09:40
EPA 6010D
Zinc
8.OJ
ug/L
10.0
05/20/19 09:40
EPA 6020B
Thallium
0.42
ug/L
0.10
05/21/19 00:04
EPA 8260D
1,1-Dichloroethane
0.46J
ug/L
1.0
05/16/19 22:35
EPA 8260D
1,2-Dichlorobenzene
0.88J
ug/L
1.0
05/16/19 22:35
EPA 8260D
1,4-Dichlorobenzene
14.0
ug/L
1.0
05/16/19 22:35
EPA 8260D
Benzene
4.7
ug/L
1.0
05/16/19 22:35
EPA 8260D
Chlorobenzene
35.5
ug/L
1.0
05/16/19 22:35
EPA 8260D
Chloroethane
1.7
ug/L
1.0
05/16/19 22:35
EPA 8260D
Xylene (Total)
17.2
ug/L
2.0
05/16/19 22:35
EPA 8260D
m&p-Xylene
17.2
ug/L
1.0
05/16/19 22:35
EPA 8260D
o-Xylene
0.61 J
ug/L
1.0
05/16/19 22:35
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
2.7
ug/L
2.0
05/16/19 17:39
92428709003
1202-MW3
EPA 6010D
Barium
113
ug/L
5.0
05/20/19 09:43
EPA 6010D
Cobalt
27.2
ug/L
5.0
05/20/19 09:43
EPA 6010D
Nickel
9.7
ug/L
5.0
05/20/19 09:43
EPA 6020B
Thallium
0.91
ug/L
0.10
05/21/19 00:11
EPA 8260D
1,1-Dichloroethane
5.8
ug/L
1.0
05/16/19 23:01
EPA 8260D
1,2-Dichloropropane
1.0
ug/L
1.0
05/16/19 23:01
EPA 8260D
1,4-Dichlorobenzene
4.9
ug/L
1.0
05/16/19 23:01
EPA 8260D
Benzene
1.8
ug/L
1.0
05/16/19 23:01
EPA 8260D
Chlorobenzene
8.9
ug/L
1.0
05/16/19 23:01
EPA 8260D
Tetrachloroethene
11.3
ug/L
1.0
05/16/19 23:01
EPA 8260D
Trichloroethene
6.0
ug/L
1.0
05/16/19 23:01
EPA 8260D
Vinyl chloride
1.4
ug/L
1.0
05/16/19 23:01
EPA 8260D
cis-1,2-Dichloroethene
18.0
ug/L
1.0
05/16/19 23:01
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
33.1
ug/L
2.0
05/16/19 17:59
92428709004
1202-AMW1
EPA 6010D
Barium
50.8
ug/L
5.0
05/20/19 09:46
EPA 6020B
Thallium
0.17
ug/L
0.10
05/21/19 00:26
EPA 8260D
cis-1,2-Dichloroethene
1.4
ug/L
1.0
05/16/19 23:27
EPA 8260D Mod.
1,4-Dioxane (p-Dioxane)
1.91
ug/L
2.0
05/16/19 18:18
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 30

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
BURKE CO. EAST BURKE
92428709
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92428709005
1202-SW1
EPA 601 OD
Barium
41.4
ug/L
5.0
05/20/19 09:49
EPA 601 OD
Cobalt
3.5J
ug/L
5.0
05/20/19 09:49
EPA 601 OD
Nickel
2.9J
ug/L
5.0
05/20/19 09:49
EPA 601 OD
Hardness, Total(SM 2340B)
19900
ug/L
662
05/20/19 09:49
EPA 6020B
Thallium
0.072J
ug/L
0.10
05/21/19 00:29
EPA8260D Mod.
1,4-Dioxane (p-Dioxane)
7.4
ug/L
2.0
05/16/19 18:38
92428709006
1202-SW2
EPA 601 OD
Barium
47.9
ug/L
5.0
05/20/19 10:05
EPA 601 OD
Beryllium
0.86J
ug/L
1.0
05/20/19 10:05
EPA 601 OD
Cadmium
1.2
ug/L
1.0
05/20/19 10:05 B
EPA 601 OD
Cobalt
7.8
ug/L
5.0
05/20/19 10:05
EPA 601 OD
Copper
2.8J
ug/L
5.0
05/20/19 10:05
EPA 601 OD
Lead
2.7J
ug/L
5.0
05/20/19 10:05
EPA 601 OD
Nickel
4.7J
ug/L
5.0
05/20/19 10:05
EPA 601 OD
Hardness, Total(SM 2340B)
28800
ug/L
662
05/20/19 10:05
EPA 6020B
Thallium
0.10
ug/L
0.10
05/21/19 00:33
EPA 8260D
Chloroform
0.72J
ug/L
1.0
05/17/19 00:19
EPA8260D Mod.
1,4-Dioxane (p-Dioxane)
9.2
ug/L
2.0
05/16/19 18:58
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
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ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW1 Lab ID: 92428709001 Collected: 05/06/19 08:50 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA
Antimony
ND
ug/L
5.0
3.9
1
05/17/19 11:00
05/20/19 09:27
7440-36-0
Arsenic
5.OJ
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:27
7440-38-2
Barium
56.3
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:27
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:27
7440-43-9
Chromium
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-47-3
Cobalt
10.6
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-48-4
Copper
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-50-8
Lead
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7439-92-1
Nickel
5.5
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:27
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-22-4
Vanadium
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:27
7440-62-2
Zinc
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:27
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
0.13
ug/L
0.10
0.060
1
05/17/19 15:02
05/20/19 23:57
7440-28-0
8260D MSV Water, Extend
Analytical Method: EPA 8260D
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.32
1
05/16/19 22:09
630-20-6
1,1,1-Trichloroethane
ND
ug/L
1.0
0.38
1
05/16/19 22:09
71-55-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.53
1
05/16/19 22:09
79-34-5
1,1,2-Trichloroethane
ND
ug/L
1.0
0.59
1
05/16/19 22:09
79-00-5
1,1-Dichloroethane
ND
ug/L
1.0
0.41
1
05/16/19 22:09
75-34-3
1,1-Dichloroethene
ND
ug/L
1.0
0.72
1
05/16/19 22:09
75-35-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.46
1
05/16/19 22:09
96-18-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.55
1
05/16/19 22:09
96-12-8
1,2-Dibromoethane (EDB)
ND
ug/L
2.0
0.28
1
05/16/19 22:09
106-93-4
1,2-Dichlorobenzene
ND
ug/L
1.0
0.49
1
05/16/19 22:09
95-50-1
1,2-Dichloroethane
ND
ug/L
1.0
0.67
1
05/16/19 22:09
107-06-2
1,2-Dichloropropane
ND
ug/L
1.0
0.60
1
05/16/19 22:09
78-87-5
1,4-Dichlorobenzene
0.74J
ug/L
1.0
0.58
1
05/16/19 22:09
106-46-7
2-Butanone (MEK)
ND
ug/L
5.0
3.2
1
05/16/19 22:09
78-93-3
2-Hexanone
ND
ug/L
5.0
0.89
1
05/16/19 22:09
591-78-6
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
0.86
1
05/16/19 22:09
108-10-1
Acetone
ND
ug/L
25.0
8.2
1
05/16/19 22:09
67-64-1
Acrylonitrile
ND
ug/L
50.0
2.5
1
05/16/19 22:09
107-13-1
Benzene
0.24J
ug/L
1.0
0.20
1
05/16/19 22:09
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.50
1
05/16/19 22:09
74-97-5 L1
Bromodichloromethane
ND
ug/L
1.0
0.36
1
05/16/19 22:09
75-27-4
Bromoform
ND
ug/L
1.0
0.55
1
05/16/19 22:09
75-25-2
Bromomethane
ND
ug/L
2.0
0.95
1
05/16/19 22:09
74-83-9
Carbon disulfide
ND
ug/L
10.0
0.79
1
05/16/19 22:09
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.42
1
05/16/19 22:09
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.53
1
05/16/19 22:09
108-90-7
Chloroethane
ND
ug/L
1.0
0.52
1
05/16/19 22:09
75-00-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW1 Lab ID: 92428709001 Collected: 05/06/19 08:50 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.58
1
05/16/19 22:09
67-66-3
ND
ug/L
1.0
0.38
1
05/16/19 22:09
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/16/19 22:09
124-48-1
ND
ug/L
1.0
0.62
1
05/16/19 22:09
74-95-3
ND
ug/L
1.0
0.45
1
05/16/19 22:09
100-41-4
ND
ug/L
10.0
3.1
1
05/16/19 22:09
74-88-4
ND
ug/L
1.0
0.50
1
05/16/19 22:09
75-09-2
ND
ug/L
1.0
0.50
1
05/16/19 22:09
100-42-5
ND
ug/L
1.0
0.78
1
05/16/19 22:09
127-18-4
ND
ug/L
1.0
0.31
1
05/16/19 22:09
108-88-3
ND
ug/L
1.0
0.34
1
05/16/19 22:09
79-01-6
ND
ug/L
1.0
0.51
1
05/16/19 22:09
75-69-4
ND
ug/L
2.0
0.42
1
05/16/19 22:09
108-05-4
ND
ug/L
1.0
0.60
1
05/16/19 22:09
75-01-4
ND
ug/L
2.0
1.5
1
05/16/19 22:09
1330-20-7
1.6
ug/L
1.0
0.66
1
05/16/19 22:09
156-59-2
ND
ug/L
1.0
0.22
1
05/16/19 22:09
10061-01-5
ND
ug/L
1.0
0.92
1
05/16/19 22:09
179601-23-1
ND
ug/L
1.0
0.54
1
05/16/19 22:09
95-47-6
ND
ug/L
1.0
0.46
1
05/16/19 22:09
156-60-5
ND
ug/L
1.0
0.30
1
05/16/19 22:09
10061-02-6
ND
ug/L
5.0
1.6
1
05/16/19 22:09
110-57-6
97
%.
81-119
1
05/16/19 22:09
17060-07-0
105
%.
82-114
1
05/16/19 22:09
1868-53-7
87
%.
82-120
1
05/16/19 22:09
460-00-4
83
%.
82-109
1
05/16/19 22:09
2037-26-5
Analytical Method: EPA 8260D Mod.
ND
ug/L
2.0
1.2
1
05/16/1917:19
123-91-1
103
%
50-150
1
05/16/1917:19
17060-07-0
111
%
50-150
1
05/16/1917:19
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW2 Lab ID: 92428709002 Collected: 05/06/19 10:40 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
3.9
1
05/17/19 11:00
05/20/19 09:40
7440-36-0
Arsenic
20.4
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:40
7440-38-2
Barium
40.6
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:40
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:40
7440-43-9
Chromium
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-47-3
Cobalt
74.7
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-48-4
Copper
3.2J
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-50-8
Lead
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7439-92-1
Nickel
62.0
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:40
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-22-4
Vanadium
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:40
7440-62-2
Zinc
8.01
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:40
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
0.42
ug/L
0.10
0.060
1
05/17/19 15:02
05/21/19 00:04
7440-28-0
8260D MSV Water, Extend
Analytical Method: EPA 8260D
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.32
1
05/16/19 22:35
630-20-6
1,1,1-Trichloroethane
ND
ug/L
1.0
0.38
1
05/16/19 22:35
71-55-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.53
1
05/16/19 22:35
79-34-5
1,1,2-Trichloroethane
ND
ug/L
1.0
0.59
1
05/16/19 22:35
79-00-5
1,1-Dichloroethane
0.46J
ug/L
1.0
0.41
1
05/16/19 22:35
75-34-3
1,1-Dichloroethene
ND
ug/L
1.0
0.72
1
05/16/19 22:35
75-35-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.46
1
05/16/19 22:35
96-18-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.55
1
05/16/19 22:35
96-12-8
1,2-Dibromoethane (EDB)
ND
ug/L
2.0
0.28
1
05/16/19 22:35
106-93-4
1,2-Dichlorobenzene
0.88J
ug/L
1.0
0.49
1
05/16/19 22:35
95-50-1
1,2-Dichloroethane
ND
ug/L
1.0
0.67
1
05/16/19 22:35
107-06-2
1,2-Dichloropropane
ND
ug/L
1.0
0.60
1
05/16/19 22:35
78-87-5
1,4-Dichlorobenzene
14.0
ug/L
1.0
0.58
1
05/16/19 22:35
106-46-7
2-Butanone (MEK)
ND
ug/L
5.0
3.2
1
05/16/19 22:35
78-93-3
2-Hexanone
ND
ug/L
5.0
0.89
1
05/16/19 22:35
591-78-6
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
0.86
1
05/16/19 22:35
108-10-1
Acetone
ND
ug/L
25.0
8.2
1
05/16/19 22:35
67-64-1
Acrylonitrile
ND
ug/L
50.0
2.5
1
05/16/19 22:35
107-13-1
Benzene
4.7
ug/L
1.0
0.20
1
05/16/19 22:35
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.50
1
05/16/19 22:35
74-97-5 L1
Bromodichloromethane
ND
ug/L
1.0
0.36
1
05/16/19 22:35
75-27-4
Bromoform
ND
ug/L
1.0
0.55
1
05/16/19 22:35
75-25-2
Bromomethane
ND
ug/L
2.0
0.95
1
05/16/19 22:35
74-83-9
Carbon disulfide
ND
ug/L
10.0
0.79
1
05/16/19 22:35
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.42
1
05/16/19 22:35
56-23-5
Chlorobenzene
35.5
ug/L
1.0
0.53
1
05/16/19 22:35
108-90-7
Chloroethane
1.7
ug/L
1.0
0.52
1
05/16/19 22:35
75-00-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 30

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW2 Lab ID: 92428709002 Collected: 05/06/19 10:40 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.58
1
05/16/19 22:35
67-66-3
ND
ug/L
1.0
0.38
1
05/16/19 22:35
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/16/19 22:35
124-48-1
ND
ug/L
1.0
0.62
1
05/16/19 22:35
74-95-3
ND
ug/L
1.0
0.45
1
05/16/19 22:35
100-41-4
ND
ug/L
10.0
3.1
1
05/16/19 22:35
74-88-4
ND
ug/L
1.0
0.50
1
05/16/19 22:35
75-09-2
ND
ug/L
1.0
0.50
1
05/16/19 22:35
100-42-5
ND
ug/L
1.0
0.78
1
05/16/19 22:35
127-18-4
ND
ug/L
1.0
0.31
1
05/16/19 22:35
108-88-3
ND
ug/L
1.0
0.34
1
05/16/19 22:35
79-01-6
ND
ug/L
1.0
0.51
1
05/16/19 22:35
75-69-4
ND
ug/L
2.0
0.42
1
05/16/19 22:35
108-05-4
ND
ug/L
1.0
0.60
1
05/16/19 22:35
75-01-4
17.2
ug/L
2.0
1.5
1
05/16/19 22:35
1330-20-7
ND
ug/L
1.0
0.66
1
05/16/19 22:35
156-59-2
ND
ug/L
1.0
0.22
1
05/16/19 22:35
10061-01-5
17.2
ug/L
1.0
0.92
1
05/16/19 22:35
179601-23-1
0.61J
ug/L
1.0
0.54
1
05/16/19 22:35
95-47-6
ND
ug/L
1.0
0.46
1
05/16/19 22:35
156-60-5
ND
ug/L
1.0
0.30
1
05/16/19 22:35
10061-02-6
ND
ug/L
5.0
1.6
1
05/16/19 22:35
110-57-6
96
%.
81-119
1
05/16/19 22:35
17060-07-0
104
%.
82-114
1
05/16/19 22:35
1868-53-7
85
%.
82-120
1
05/16/19 22:35
460-00-4
82
%.
82-109
1
05/16/19 22:35
2037-26-5
Analytical Method: EPA 8260D Mod.
2.7
ug/L
2.0
1.2
1
05/16/1917:39
123-91-1
102
%
50-150
1
05/16/1917:39
17060-07-0
110
%
50-150
1
05/16/1917:39
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 30

aceAnalytical
-pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW3 Lab ID: 92428709003 Collected: 05/06/19 12:09 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
1400111 �41 :4 9 [y :2 61.9
Thallium
8260D MSV Water, Extend
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
05/17/19 11:00
05/20/19 09:43
7440-36-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:43
7440-38-2
113
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-39-3
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:43
7440-41-7
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:43
7440-43-9
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-47-3
27.2
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-48-4
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-50-8
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7439-92-1
9.7
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-02-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:43
7782-49-2
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-22-4
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:43
7440-62-2
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:43
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
0.91 ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:11 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.32
1
05/16/19 23:01
630-20-6
ND
ug/L
1.0
0.38
1
05/16/19 23:01
71-55-6
ND
ug/L
1.0
0.53
1
05/16/19 23:01
79-34-5
ND
ug/L
1.0
0.59
1
05/16/19 23:01
79-00-5
5.8
ug/L
1.0
0.41
1
05/16/19 23:01
75-34-3
ND
ug/L
1.0
0.72
1
05/16/19 23:01
75-35-4
ND
ug/L
1.0
0.46
1
05/16/19 23:01
96-18-4
ND
ug/L
2.0
0.55
1
05/16/19 23:01
96-12-8
ND
ug/L
2.0
0.28
1
05/16/19 23:01
106-93-4
ND
ug/L
1.0
0.49
1
05/16/19 23:01
95-50-1
ND
ug/L
1.0
0.67
1
05/16/19 23:01
107-06-2
1.0
ug/L
1.0
0.60
1
05/16/19 23:01
78-87-5
4.9
ug/L
1.0
0.58
1
05/16/19 23:01
106-46-7
ND
ug/L
5.0
3.2
1
05/16/19 23:01
78-93-3
ND
ug/L
5.0
0.89
1
05/16/19 23:01
591-78-6
ND
ug/L
5.0
0.86
1
05/16/19 23:01
108-10-1
ND
ug/L
25.0
8.2
1
05/16/19 23:01
67-64-1
ND
ug/L
50.0
2.5
1
05/16/19 23:01
107-13-1
1.8
ug/L
1.0
0.20
1
05/16/19 23:01
71-43-2
ND
ug/L
1.0
0.50
1
05/16/19 23:01
74-97-5
ND
ug/L
1.0
0.36
1
05/16/19 23:01
75-27-4
ND
ug/L
1.0
0.55
1
05/16/19 23:01
75-25-2
ND
ug/L
2.0
0.95
1
05/16/19 23:01
74-83-9
ND
ug/L
10.0
0.79
1
05/16/19 23:01
75-15-0
ND
ug/L
1.0
0.42
1
05/16/19 23:01
56-23-5
8.9
ug/L
1.0
0.53
1
05/16/19 23:01
108-90-7
ND
ug/L
1.0
0.52
1
05/16/19 23:01
75-00-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1
Page 11 of 30

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-MW3 Lab ID: 92428709003 Collected: 05/06/19 12:09 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.58
1
05/16/19 23:01
67-66-3
ND
ug/L
1.0
0.38
1
05/16/19 23:01
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/16/19 23:01
124-48-1
ND
ug/L
1.0
0.62
1
05/16/19 23:01
74-95-3
ND
ug/L
1.0
0.45
1
05/16/19 23:01
100-41-4
ND
ug/L
10.0
3.1
1
05/16/19 23:01
74-88-4
ND
ug/L
1.0
0.50
1
05/16/19 23:01
75-09-2
ND
ug/L
1.0
0.50
1
05/16/19 23:01
100-42-5
11.3
ug/L
1.0
0.78
1
05/16/19 23:01
127-18-4
ND
ug/L
1.0
0.31
1
05/16/19 23:01
108-88-3
6.0
ug/L
1.0
0.34
1
05/16/19 23:01
79-01-6
ND
ug/L
1.0
0.51
1
05/16/19 23:01
75-69-4
ND
ug/L
2.0
0.42
1
05/16/19 23:01
108-05-4
1.4
ug/L
1.0
0.60
1
05/16/19 23:01
75-01-4
ND
ug/L
2.0
1.5
1
05/16/19 23:01
1330-20-7
18.0
ug/L
1.0
0.66
1
05/16/19 23:01
156-59-2
ND
ug/L
1.0
0.22
1
05/16/19 23:01
10061-01-5
ND
ug/L
1.0
0.92
1
05/16/19 23:01
179601-23-1
ND
ug/L
1.0
0.54
1
05/16/19 23:01
95-47-6
ND
ug/L
1.0
0.46
1
05/16/19 23:01
156-60-5
ND
ug/L
1.0
0.30
1
05/16/19 23:01
10061-02-6
ND
ug/L
5.0
1.6
1
05/16/19 23:01
110-57-6
97
%.
81-119
1
05/16/19 23:01
17060-07-0
105
%.
82-114
1
05/16/19 23:01
1868-53-7
87
%.
82-120
1
05/16/19 23:01
460-00-4
83
%.
82-109
1
05/16/19 23:01
2037-26-5
Analytical Method: EPA 8260D Mod.
33.1
ug/L
2.0
1.2
1
05/16/1917:59
123-91-1
104
%
50-150
1
05/16/1917:59
17060-07-0
111
%
50-150
1
05/16/1917:59
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 12 of 30

aceAnalytical
-pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-AMW1 Lab ID: 92428709004 Collected: 05/06/19 12:45 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
1400111 �41 :4 9 [y :2 61.9
Thallium
8260D MSV Water, Extend
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
05/17/19 11:00
05/20/19 09:46
7440-36-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:46
7440-38-2
50.8
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-39-3
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:46
7440-41-7
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:46
7440-43-9
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-47-3
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-48-4
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-50-8
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7439-92-1
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-02-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:46
7782-49-2
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-22-4
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:46
7440-62-2
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:46
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
0.17 ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:26 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.32
1
05/16/19 23:27
630-20-6
ND
ug/L
1.0
0.38
1
05/16/19 23:27
71-55-6
ND
ug/L
1.0
0.53
1
05/16/19 23:27
79-34-5
ND
ug/L
1.0
0.59
1
05/16/19 23:27
79-00-5
ND
ug/L
1.0
0.41
1
05/16/19 23:27
75-34-3
ND
ug/L
1.0
0.72
1
05/16/19 23:27
75-35-4
ND
ug/L
1.0
0.46
1
05/16/19 23:27
96-18-4
ND
ug/L
2.0
0.55
1
05/16/19 23:27
96-12-8
ND
ug/L
2.0
0.28
1
05/16/19 23:27
106-93-4
ND
ug/L
1.0
0.49
1
05/16/19 23:27
95-50-1
ND
ug/L
1.0
0.67
1
05/16/19 23:27
107-06-2
ND
ug/L
1.0
0.60
1
05/16/19 23:27
78-87-5
ND
ug/L
1.0
0.58
1
05/16/19 23:27
106-46-7
ND
ug/L
5.0
3.2
1
05/16/19 23:27
78-93-3
ND
ug/L
5.0
0.89
1
05/16/19 23:27
591-78-6
ND
ug/L
5.0
0.86
1
05/16/19 23:27
108-10-1
ND
ug/L
25.0
8.2
1
05/16/19 23:27
67-64-1
ND
ug/L
50.0
2.5
1
05/16/19 23:27
107-13-1
ND
ug/L
1.0
0.20
1
05/16/19 23:27
71-43-2
ND
ug/L
1.0
0.50
1
05/16/19 23:27
74-97-5
ND
ug/L
1.0
0.36
1
05/16/19 23:27
75-27-4
ND
ug/L
1.0
0.55
1
05/16/19 23:27
75-25-2
ND
ug/L
2.0
0.95
1
05/16/19 23:27
74-83-9
ND
ug/L
10.0
0.79
1
05/16/19 23:27
75-15-0
ND
ug/L
1.0
0.42
1
05/16/19 23:27
56-23-5
ND
ug/L
1.0
0.53
1
05/16/19 23:27
108-90-7
ND
ug/L
1.0
0.52
1
05/16/19 23:27
75-00-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1
Page 13 of 30

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-AMW1 Lab ID: 92428709004 Collected: 05/06/19 12:45 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.58
1
05/16/19 23:27
67-66-3
ND
ug/L
1.0
0.38
1
05/16/19 23:27
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/16/19 23:27
124-48-1
ND
ug/L
1.0
0.62
1
05/16/19 23:27
74-95-3
ND
ug/L
1.0
0.45
1
05/16/19 23:27
100-41-4
ND
ug/L
10.0
3.1
1
05/16/19 23:27
74-88-4
ND
ug/L
1.0
0.50
1
05/16/19 23:27
75-09-2
ND
ug/L
1.0
0.50
1
05/16/19 23:27
100-42-5
ND
ug/L
1.0
0.78
1
05/16/19 23:27
127-18-4
ND
ug/L
1.0
0.31
1
05/16/19 23:27
108-88-3
ND
ug/L
1.0
0.34
1
05/16/19 23:27
79-01-6
ND
ug/L
1.0
0.51
1
05/16/19 23:27
75-69-4
ND
ug/L
2.0
0.42
1
05/16/19 23:27
108-05-4
ND
ug/L
1.0
0.60
1
05/16/19 23:27
75-01-4
ND
ug/L
2.0
1.5
1
05/16/19 23:27
1330-20-7
1.4
ug/L
1.0
0.66
1
05/16/19 23:27
156-59-2
ND
ug/L
1.0
0.22
1
05/16/19 23:27
10061-01-5
ND
ug/L
1.0
0.92
1
05/16/19 23:27
179601-23-1
ND
ug/L
1.0
0.54
1
05/16/19 23:27
95-47-6
ND
ug/L
1.0
0.46
1
05/16/19 23:27
156-60-5
ND
ug/L
1.0
0.30
1
05/16/19 23:27
10061-02-6
ND
ug/L
5.0
1.6
1
05/16/19 23:27
110-57-6
98
%.
81-119
1
05/16/19 23:27
17060-07-0
105
%.
82-114
1
05/16/19 23:27
1868-53-7
86
%.
82-120
1
05/16/19 23:27
460-00-4
83
%.
82-109
1
05/16/19 23:27
2037-26-5
Analytical Method: EPA 8260D Mod.
1.91
ug/L
2.0
1.2
1
05/16/1918:18
123-91-1
100
%
50-150
1
05/16/1918:18
17060-07-0
113
%
50-150
1
05/16/1918:18
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 30

aceAnalytical
-pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-SW1 Lab ID: 92428709005 Collected: 05/06/19 11:35 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Water, Extend
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
05/17/19 11:00
05/20/19 09:49
7440-36-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:49
7440-38-2
41.4
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-39-3
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:49
7440-41-7
ND
ug/L
1.0
0.50
1
05/17/19 11:00
05/20/19 09:49
7440-43-9
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-47-3
3.5J
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-48-4
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-50-8
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7439-92-1
2.9J
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-02-0
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:49
7782-49-2
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-22-4
19900
ug/L
662
662
1
05/17/19 11:00
05/20/19 09:49
ND
ug/L
5.0
2.5
1
05/17/19 11:00
05/20/19 09:49
7440-62-2
ND
ug/L
10.0
5.0
1
05/17/19 11:00
05/20/19 09:49
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
0.072J ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:29 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.32
1
05/16/19 23:53
630-20-6
ND
ug/L
1.0
0.38
1
05/16/19 23:53
71-55-6
ND
ug/L
1.0
0.53
1
05/16/19 23:53
79-34-5
ND
ug/L
1.0
0.59
1
05/16/19 23:53
79-00-5
ND
ug/L
1.0
0.41
1
05/16/19 23:53
75-34-3
ND
ug/L
1.0
0.72
1
05/16/19 23:53
75-35-4
ND
ug/L
1.0
0.46
1
05/16/19 23:53
96-18-4
ND
ug/L
2.0
0.55
1
05/16/19 23:53
96-12-8
ND
ug/L
2.0
0.28
1
05/16/19 23:53
106-93-4
ND
ug/L
1.0
0.49
1
05/16/19 23:53
95-50-1
ND
ug/L
1.0
0.67
1
05/16/19 23:53
107-06-2
ND
ug/L
1.0
0.60
1
05/16/19 23:53
78-87-5
ND
ug/L
1.0
0.58
1
05/16/19 23:53
106-46-7
ND
ug/L
5.0
3.2
1
05/16/19 23:53
78-93-3
ND
ug/L
5.0
0.89
1
05/16/19 23:53
591-78-6
ND
ug/L
5.0
0.86
1
05/16/19 23:53
108-10-1
ND
ug/L
25.0
8.2
1
05/16/19 23:53
67-64-1
ND
ug/L
50.0
2.5
1
05/16/19 23:53
107-13-1
ND
ug/L
1.0
0.20
1
05/16/19 23:53
71-43-2
ND
ug/L
1.0
0.50
1
05/16/19 23:53
74-97-5
ND
ug/L
1.0
0.36
1
05/16/19 23:53
75-27-4
ND
ug/L
1.0
0.55
1
05/16/19 23:53
75-25-2
ND
ug/L
2.0
0.95
1
05/16/19 23:53
74-83-9
ND
ug/L
10.0
0.79
1
05/16/19 23:53
75-15-0
ND
ug/L
1.0
0.42
1
05/16/19 23:53
56-23-5
ND
ug/L
1.0
0.53
1
05/16/19 23:53
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L1
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ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-SW1 Lab ID: 92428709005 Collected: 05/06/19 11:35 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.52
1
05/16/19 23:53
75-00-3
ND
ug/L
1.0
0.58
1
05/16/19 23:53
67-66-3
ND
ug/L
1.0
0.38
1
05/16/19 23:53
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/16/19 23:53
124-48-1
ND
ug/L
1.0
0.62
1
05/16/19 23:53
74-95-3
ND
ug/L
1.0
0.45
1
05/16/19 23:53
100-41-4
ND
ug/L
10.0
3.1
1
05/16/19 23:53
74-88-4
ND
ug/L
1.0
0.50
1
05/16/19 23:53
75-09-2
ND
ug/L
1.0
0.50
1
05/16/19 23:53
100-42-5
ND
ug/L
1.0
0.78
1
05/16/19 23:53
127-18-4
ND
ug/L
1.0
0.31
1
05/16/19 23:53
108-88-3
ND
ug/L
1.0
0.34
1
05/16/19 23:53
79-01-6
ND
ug/L
1.0
0.51
1
05/16/19 23:53
75-69-4
ND
ug/L
2.0
0.42
1
05/16/19 23:53
108-05-4
ND
ug/L
1.0
0.60
1
05/16/19 23:53
75-01-4
ND
ug/L
2.0
1.5
1
05/16/19 23:53
1330-20-7
ND
ug/L
1.0
0.66
1
05/16/19 23:53
156-59-2
ND
ug/L
1.0
0.22
1
05/16/19 23:53
10061-01-5
ND
ug/L
1.0
0.92
1
05/16/19 23:53
179601-23-1
ND
ug/L
1.0
0.54
1
05/16/19 23:53
95-47-6
ND
ug/L
1.0
0.46
1
05/16/19 23:53
156-60-5
ND
ug/L
1.0
0.30
1
05/16/19 23:53
10061-02-6
ND
ug/L
5.0
1.6
1
05/16/19 23:53
110-57-6
99
%.
81-119
1
05/16/19 23:53
17060-07-0
101
%.
82-114
1
05/16/19 23:53
1868-53-7
87
%.
82-120
1
05/16/19 23:53
460-00-4
83
%.
82-109
1
05/16/19 23:53
2037-26-5
Analytical Method: EPA 8260D Mod.
7.4
ug/L
2.0
1.2
1
05/16/1918:38
123-91-1
102
%
50-150
1
05/16/1918:38
17060-07-0
109
%
50-150
1
05/16/1918:38
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 16 of 30

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ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-SW2 Lab ID: 92428709006 Collected: 05/06/19 12:40 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260D MSV Water, Extend
1,1,1,2-Tetrachloroethane
1,1,1-Trichloroethane
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichloroethane
1,1-Dichloroethene
1,2,3-Trichloropropane
1,2-Dibromo-3-chloropropane
1,2-Dibromoethane (EDB)
1,2-Dichlorobenzene
1,2-Dichloroethane
1,2-Dichloropropane
1,4-Dichlorobenzene
2-Butanone (MEK)
2-Hexanone
4-Methyl-2-pentanone (MIBK)
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
05/17/1911:00
05/20/1910:05
7440-36-0
ND
ug/L
10.0
5.0
1
05/17/1911:00
05/20/1910:05
7440-38-2
47.9
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-39-3
0.86J
ug/L
1.0
0.50
1
05/17/1911:00
05/20/1910:05
7440-41-7
1.2
ug/L
1.0
0.50
1
05/17/1911:00
05/20/1910:05
7440-43-9
ND
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-47-3
7.8
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-48-4
2.8J
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-50-8
2.7J
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7439-92-1
4.7J
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-02-0
ND
ug/L
10.0
5.0
1
05/17/1911:00
05/20/1910:05
7782-49-2
ND
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-22-4
28800
ug/L
662
662
1
05/17/1911:00
05/20/1910:05
ND
ug/L
5.0
2.5
1
05/17/1911:00
05/20/1910:05
7440-62-2
ND
ug/L
10.0
5.0
1
05/17/1911:00
05/20/1910:05
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
0.10 ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:33 7440-28-0
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.32
1
05/17/19 00:19
630-20-6
ND
ug/L
1.0
0.38
1
05/17/19 00:19
71-55-6
ND
ug/L
1.0
0.53
1
05/17/19 00:19
79-34-5
ND
ug/L
1.0
0.59
1
05/17/19 00:19
79-00-5
ND
ug/L
1.0
0.41
1
05/17/19 00:19
75-34-3
ND
ug/L
1.0
0.72
1
05/17/19 00:19
75-35-4
ND
ug/L
1.0
0.46
1
05/17/19 00:19
96-18-4
ND
ug/L
2.0
0.55
1
05/17/19 00:19
96-12-8
ND
ug/L
2.0
0.28
1
05/17/19 00:19
106-93-4
ND
ug/L
1.0
0.49
1
05/17/19 00:19
95-50-1
ND
ug/L
1.0
0.67
1
05/17/19 00:19
107-06-2
ND
ug/L
1.0
0.60
1
05/17/19 00:19
78-87-5
ND
ug/L
1.0
0.58
1
05/17/19 00:19
106-46-7
ND
ug/L
5.0
3.2
1
05/17/19 00:19
78-93-3
ND
ug/L
5.0
0.89
1
05/17/19 00:19
591-78-6
ND
ug/L
5.0
0.86
1
05/17/19 00:19
108-10-1
ND
ug/L
25.0
8.2
1
05/17/19 00:19
67-64-1
ND
ug/L
50.0
2.5
1
05/17/19 00:19
107-13-1
ND
ug/L
1.0
0.20
1
05/17/19 00:19
71-43-2
ND
ug/L
1.0
0.50
1
05/17/19 00:19
74-97-5
ND
ug/L
1.0
0.36
1
05/17/19 00:19
75-27-4
ND
ug/L
1.0
0.55
1
05/17/19 00:19
75-25-2
ND
ug/L
2.0
0.95
1
05/17/19 00:19
74-83-9
ND
ug/L
10.0
0.79
1
05/17/19 00:19
75-15-0
ND
ug/L
1.0
0.42
1
05/17/19 00:19
56-23-5
ND
ug/L
1.0
0.53
1
05/17/19 00:19
108-90-7
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
B
L1
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9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
Sample: 1202-SW2 Lab ID: 92428709006 Collected: 05/06/19 12:40 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroethane
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/21 /2019 12:08 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.52
1
05/17/19 00:19
75-00-3
0.72J
ug/L
1.0
0.58
1
05/17/19 00:19
67-66-3
ND
ug/L
1.0
0.38
1
05/17/19 00:19
74-87-3 v2
ND
ug/L
1.0
0.31
1
05/17/19 00:19
124-48-1
ND
ug/L
1.0
0.62
1
05/17/19 00:19
74-95-3
ND
ug/L
1.0
0.45
1
05/17/19 00:19
100-41-4
ND
ug/L
10.0
3.1
1
05/17/19 00:19
74-88-4
ND
ug/L
1.0
0.50
1
05/17/19 00:19
75-09-2
ND
ug/L
1.0
0.50
1
05/17/19 00:19
100-42-5
ND
ug/L
1.0
0.78
1
05/17/19 00:19
127-18-4
ND
ug/L
1.0
0.31
1
05/17/19 00:19
108-88-3
ND
ug/L
1.0
0.34
1
05/17/19 00:19
79-01-6
ND
ug/L
1.0
0.51
1
05/17/19 00:19
75-69-4
ND
ug/L
2.0
0.42
1
05/17/19 00:19
108-05-4
ND
ug/L
1.0
0.60
1
05/17/19 00:19
75-01-4
ND
ug/L
2.0
1.5
1
05/17/19 00:19
1330-20-7
ND
ug/L
1.0
0.66
1
05/17/19 00:19
156-59-2
ND
ug/L
1.0
0.22
1
05/17/19 00:19
10061-01-5
ND
ug/L
1.0
0.92
1
05/17/19 00:19
179601-23-1
ND
ug/L
1.0
0.54
1
05/17/19 00:19
95-47-6
ND
ug/L
1.0
0.46
1
05/17/19 00:19
156-60-5
ND
ug/L
1.0
0.30
1
05/17/19 00:19
10061-02-6
ND
ug/L
5.0
1.6
1
05/17/19 00:19
110-57-6
99
%.
81-119
1
05/17/19 00:19
17060-07-0
101
%.
82-114
1
05/17/19 00:19
1868-53-7
87
%.
82-120
1
05/17/19 00:19
460-00-4
83
%.
82-109
1
05/17/19 00:19
2037-26-5
Analytical Method: EPA 8260D Mod.
9.2
ug/L
2.0
1.2
1
05/16/1918:58
123-91-1
100
%
50-150
1
05/16/1918:58
17060-07-0
110
%
50-150
1
05/16/1918:58
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 30

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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
QC Batch: 475853 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
METHOD BLANK: 2578601 Matrix: Water
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.9
05/20/19 09:11
Arsenic
ug/L
ND
10.0
5.0
05/20/19 09:11
Barium
ug/L
ND
5.0
2.5
05/20/19 09:11
Beryllium
ug/L
ND
1.0
0.50
05/20/19 09:11
Cadmium
ug/L
0.51 J
1.0
0.50
05/20/19 09:11
Chromium
ug/L
ND
5.0
2.5
05/20/19 09:11
Cobalt
ug/L
ND
5.0
2.5
05/20/19 09:11
Copper
ug/L
ND
5.0
2.5
05/20/19 09:11
Hardness, Total(SM 2340B)
ug/L
ND
662
662
05/20/19 09:11
Lead
ug/L
ND
5.0
2.5
05/20/19 09:11
Nickel
ug/L
ND
5.0
2.5
05/20/19 09:11
Selenium
ug/L
ND
10.0
5.0
05/20/19 09:11
Silver
ug/L
ND
5.0
2.5
05/20/19 09:11
Vanadium
ug/L
ND
5.0
2.5
05/20/19 09:11
Zinc
ug/L
ND
10.0
5.0
05/20/19 09:11
LABORATORY CONTROL SAMPLE:
2578602
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
482
96
80-120
Arsenic
ug/L
500
462
92
80-120
Barium
ug/L
500
432
86
80-120
Beryllium
ug/L
500
428
86
80-120
Cadmium
ug/L
500
465
93
80-120
Chromium
ug/L
500
449
90
80-120
Cobalt
ug/L
500
471
94
80-120
Copper
ug/L
500
463
93
80-120
Hardness, Total(SM 2340B)
ug/L
33100
29100
88
80-120
Lead
ug/L
500
469
94
80-120
Nickel
ug/L
500
457
91
80-120
Selenium
ug/L
500
477
95
80-120
Silver
ug/L
250
239
96
80-120
Vanadium
ug/L
500
460
92
80-120
Zinc
ug/L
500
487
97
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 30

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QUALITY CONTROL DATA
Project: BURKE CO.
Pace Project No.: 92428709
EAST
BURKE
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE: 2578603
2578604
MS
MSD
92428709001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
487
530
97
106
75-125
9
20
Arsenic
ug/L
5.OJ
500
500
478
531
95
105
75-125
10
20
Barium
ug/L
56.3
500
500
479
528
85
94
75-125
10
20
Beryllium
ug/L
ND
500
500
425
465
85
93
75-125
9
20
Cadmium
ug/L
ND
500
500
473
516
94
103
75-125
9
20
Chromium
ug/L
ND
500
500
447
492
89
98
75-125
10
20
Cobalt
ug/L
10.6
500
500
485
533
95
105
75-125
10
20
Copper
ug/L
ND
500
500
457
506
91
101
75-125
10
20
Hardness, Total(SM 2340B)
ug/L
27200
33100
33100
53800
59400
80
97
75-125
10
Lead
ug/L
ND
500
500
472
514
94
103
75-125
9
20
Nickel
ug/L
5.5
500
500
463
509
92
101
75-125
9
20
Selenium
ug/L
ND
500
500
514
556
103
111
75-125
8
20
Silver
ug/L
ND
250
250
240
259
96
103
75-125
7
20
Vanadium
ug/L
ND
500
500
462
507
92
101
75-125
9
20
Zinc
ug/L
ND
500
500
505
555
100
111
75-125
10
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC.
Page 20 of 30

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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
QC Batch: 476009 Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A Analysis Description: 6020 MET
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
METHOD BLANK: 2579164 Matrix: Water
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Thallium ug/L ND 0.10 0.060 05/20/19 22:36
LABORATORY CONTROL SAMPLE: 2579165
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Thallium ug/L 10 10 100 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579166 2579167
MS MSD
92427335003 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND 10 10 10.3 10 103 100 75-125 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC.
Page 21 of 30

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
QC Batch: 28498 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Water, Extend
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
METHOD BLANK: 128350 Matrix: Water
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
Blank Reporting
Parameter Units Result Limit MDL Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.32
05/16/19 18:41
1,1,1-Trichloroethane
ug/L
ND
1.0
0.38
05/16/19 18:41
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.53
05/16/19 18:41
1,1,2-Trichloroethane
ug/L
ND
1.0
0.59
05/16/19 18:41
1,1-Dichloroethane
ug/L
ND
1.0
0.41
05/16/19 18:41
1,1-Dichloroethene
ug/L
ND
1.0
0.72
05/16/19 18:41
1,2,3-Trichloropropane
ug/L
ND
1.0
0.46
05/16/19 18:41
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.55
05/16/19 18:41
1,2-Dibromoethane (EDB)
ug/L
ND
2.0
0.28
05/16/19 18:41
1,2-Dichlorobenzene
ug/L
ND
1.0
0.49
05/16/19 18:41
1,2-Dichloroethane
ug/L
ND
1.0
0.67
05/16/19 18:41
1,2-Dichloropropane
ug/L
ND
1.0
0.60
05/16/19 18:41
1,4-Dichlorobenzene
ug/L
ND
1.0
0.58
05/16/19 18:41
2-Butanone (MEK)
ug/L
ND
5.0
3.2
05/16/19 18:41
2-Hexanone
ug/L
ND
5.0
0.89
05/16/19 18:41
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
0.86
05/16/19 18:41
Acetone
ug/L
ND
25.0
8.2
05/16/19 18:41
Acrylonitrile
ug/L
ND
50.0
2.5
05/16/19 18:41
Benzene
ug/L
ND
1.0
0.20
05/16/19 18:41
Bromochloromethane
ug/L
ND
1.0
0.50
05/16/19 18:41
Bromodichloromethane
ug/L
ND
1.0
0.36
05/16/19 18:41
Bromoform
ug/L
ND
1.0
0.55
05/16/19 18:41
Bromomethane
ug/L
ND
2.0
0.95
05/16/19 18:41
Carbon disulfide
ug/L
ND
10.0
0.79
05/16/19 18:41
Carbon tetrachloride
ug/L
ND
1.0
0.42
05/16/19 18:41
Chlorobenzene
ug/L
ND
1.0
0.53
05/16/19 18:41
Chloroethane
ug/L
ND
1.0
0.52
05/16/19 18:41
Chloroform
ug/L
ND
1.0
0.58
05/16/19 18:41
Chloromethane
ug/L
ND
1.0
0.38
05/16/19 18:41
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.66
05/16/19 18:41
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.22
05/16/19 18:41
Dibromochloromethane
ug/L
ND
1.0
0.31
05/16/19 18:41
Dibromomethane
ug/L
ND
1.0
0.62
05/16/19 18:41
Ethylbenzene
ug/L
ND
1.0
0.45
05/16/19 18:41
lodomethane
ug/L
ND
10.0
3.1
05/16/19 18:41
m&p-Xylene
ug/L
ND
1.0
0.92
05/16/19 18:41
Methylene Chloride
ug/L
ND
1.0
0.50
05/16/19 18:41
o-Xylene
ug/L
ND
1.0
0.54
05/16/19 18:41
Styrene
ug/L
ND
1.0
0.50
05/16/19 18:41
Tetrachloroethene
ug/L
ND
1.0
0.78
05/16/19 18:41
Toluene
ug/L
ND
1.0
0.31
05/16/19 18:41
v2
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 30

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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
METHOD BLANK: 128350
Associated Lab Samples:
Parameter
Matrix: Water
92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
Blank Reporting
Units Result Limit MDL Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.46
05/16/19 18:41
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.30
05/16/19 18:41
trans-1,4-Dichloro-2-butene
ug/L
ND
5.0
1.6
05/16/19 18:41
Trichloroethene
ug/L
ND
1.0
0.34
05/16/19 18:41
Trichlorofluoromethane
ug/L
ND
1.0
0.51
05/16/19 18:41
Vinyl acetate
ug/L
ND
2.0
0.42
05/16/19 18:41
Vinyl chloride
ug/L
ND
1.0
0.60
05/16/19 18:41
Xylene (Total)
ug/L
ND
2.0
1.5
05/16/19 18:41
1,2-Dichloroethane-d4 (S)
%.
96
81-119
05/16/19 18:41
4-Bromofluorobenzene (S)
%.
88
82-120
05/16/19 18:41
Dibromofluoromethane (S)
%.
101
82-114
05/16/19 18:41
Toluene-d8 (S)
%.
81
82-109
05/16/19 18:41 SO
LABORATORY CONTROL SAMPLE:
Parameter
128351
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
54.1
108
68-137
1,1,1-Trichloroethane
ug/L
50
62.3
125
72-134
1,1,2,2-Tetrachloroethane
ug/L
50
46.1
92
51-158
1,1,2-Trichloroethane
ug/L
50
59.4
119
78-131
1,1-Dichloroethane
ug/L
50
58.3
117
69-151
1,1-Dichloroethene
ug/L
50
55.4
111
64-158
1,2,3-Trichloropropane
ug/L
50
45.0
90
78-133
1,2-Dibromo-3-chloropropane
ug/L
50
45.9
92
58-124
1,2-Dibromoethane (EDB)
ug/L
50
57.0
114
71-134
1,2-Dichlorobenzene
ug/L
50
51.7
103
70-135
1,2-Dichloroethane
ug/L
50
56.8
114
72-129
1,2-Dichloropropane
ug/L
50
52.0
104
64-135
1,4-Dichlorobenzene
ug/L
50
50.2
100
70-131
2-Butanone (MEK)
ug/L
100
84.5
84
52-143
2-Hexanone
ug/L
100
83.6
84
61-136
4-Methyl-2-pentanone (MIBK)
ug/L
100
92.5
93
71-129
Acetone
ug/L
100
73.8
74
48-224
Acrylonitrile
ug/L
200
189
95
66-154
Benzene
ug/L
50
57.6
115
68-132
Bromochloromethane
ug/L
50
69.3
139
73-133 L1
Bromodichloromethane
ug/L
50
50.8
102
67-121
Bromoform
ug/L
50
51.5
103
57-125
Bromomethane
ug/L
50
43.3
87
35-156
Carbon disulfide
ug/L
100
98.3
98
47-141
Carbon tetrachloride
ug/L
50
60.9
122
66-122
Chlorobenzene
ug/L
50
49.3
99
71-126
Chloroethane
ug/L
50
41.7
83
43-143
Chloroform
ug/L
50
58.5
117
71-136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 30

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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
LABORATORY CONTROL SAMPLE:
Parameter
128351
Units
Spike LCS
Conc. Result
Chloromethane
ug/L
50
cis-1,2-Dichloroethene
ug/L
50
cis-1,3-Dichloropropene
ug/L
50
Dibromochloromethane
ug/L
50
Dibromomethane
ug/L
50
Ethylbenzene
ug/L
50
lodomethane
ug/L
100
m&p-Xylene
ug/L
100
Methylene Chloride
ug/L
50
o-Xylene
ug/L
50
Styrene
ug/L
50
Tetrachloroethene
ug/L
50
Toluene
ug/L
50
trans-1,2-Dichloroethene
ug/L
50
trans- 1,3-Dichloropropene
ug/L
50
trans-1,4-Dichloro-2-butene
ug/L
100
Trichloroethene
ug/L
50
Trichlorofluoromethane
ug/L
50
Vinyl acetate
ug/L
50
Vinyl chloride
ug/L
50
Xylene (Total)
ug/L
150
1,2-Dichloroethane-d4 (S)
%.
4-Bromofluorobenzene (S)
%.
Dibromofluoromethane (S)
%.
Toluene-d8 (S)
%.
LCS
% Rec
% Rec
Limits Qualifiers
40.2
80
47-123 v2
63.5
127
74-131
52.1
104
78-120
55.6
111
65-115
62.7
125
79-129
49.5
99
68-129
111
111
49-154
103
103
67-137
58.2
116
61-147
53.7
107
52-141
56.4
113
77-128
64.9
130
51-139
55.5
111
60-133
59.3
119
69-144
51.9
104
74-128
65.8
66
61-139
49.7
99
73-126
51.7
103
55-132
47.0
94
52-141
47.1
94
50-133
157
105
78-132
94
81-119
90
82-120
112
82-114
83
82-109
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128504
MS
92428710009 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
128505
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
50
50
41.9
46.7
84
93
68-137
11
11
1,1,1-Trichloroethane
ug/L
ND
50
50
57.9
62.0
116
124
66-142
7
11
1,1,2,2-Tetrachloroethane
ug/L
ND
50
50
33.3
36.9
67
74
39-171
10
13
1,1,2-Trichloroethane
ug/L
ND
50
50
44.4
52.1
89
104
73-136
16
12 R1
1,1-Dichloroethane
ug/L
ND
50
50
50.9
54.8
102
110
66-155
8
15
1,1-Dichloroethene
ug/L
ND
50
50
60.0
66.6
120
133
33-181
10
34
1,2,3-Trichloropropane
ug/L
ND
50
50
30.8
34.1
62
68
78-133
10
14 M1
1,2-Dibromo-3-
ug/L
ND
50
50
29.7
33.3
59
67
58-124
11
15
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
50
50
44.1
50.4
88
101
71-134
13
12 R1
1,2-Dichlorobenzene
ug/L
ND
50
50
37.6
44.3
75
89
69-135
16
10 R1
1,2-Dichloroethane
ug/L
ND
50
50
47.4
51.7
95
103
36-159
9
10
1,2-Dichloropropane
ug/L
ND
50
50
42.3
49.1
85
98
68-132
15
11 R1
1,4-Dichlorobenzene
ug/L
ND
50
50
35.7
42.2
71
84
49-153
17
9 R1
2-Butanone (MEK)
ug/L
ND
100
100
67.0
63.9
67
64
10-189
5
23
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 30

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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128504 128505
Parameter Units
2-Hexanone
ug/L
4-Methyl-2-pentanone
ug/L
(MIBK)
Acetone
ug/L
Acrylonitrile
ug/L
Benzene
ug/L
Bromochloromethane
ug/L
Bromodichloromethane
ug/L
Bromoform
ug/L
Bromomethane
ug/L
Carbon disulfide
ug/L
Carbon tetrachloride
ug/L
Chlorobenzene
ug/L
Chloroethane
ug/L
Chloroform
ug/L
Chloromethane
ug/L
cis-1,2-Dichloroethene
ug/L
cis-1,3-Dichloropropene
ug/L
Dibromochloromethane
ug/L
Dibromomethane
ug/L
Ethylbenzene
ug/L
lodomethane
ug/L
m&p-Xylene
ug/L
Methylene Chloride
ug/L
o-Xylene
ug/L
Styrene
ug/L
Tetrachloroethene
ug/L
Toluene
ug/L
trans-1,2-Dichloroethene
ug/L
trans-1,3-Dichloropropene
ug/L
trans-1,4-Dichloro-2-butene
ug/L
Trichloroethene
ug/L
Trichlorofluoromethane
ug/L
Vinyl acetate
ug/L
Vinyl chloride
ug/L
Xylene (Total)
ug/L
1,2-Dichloroethane-d4 (S)
%.
4-Bromofluorobenzene (S)
%.
Dibromofluoromethane (S)
%.
Toluene-d8 (S)
%.
MS
MSD
92428710009
Spike
Spike
MS
MSD
Result
Conc.
Conc.
Result
Result
ND
100
100
59.3
66.1
ND
100
100
67.2
69.9
ND
100
100
69.5
71.1
ND
200
200
154
160
ND
50
50
49.6
54.6
ND
50
50
56.8
61.1
ND
50
50
40.3
46.4
ND
50
50
37.9
42.3
ND
50
50
34.9
41.7
ND
100
100
104
113
ND
50
50
60.4
64.1
ND
50
50
39.0
43.7
ND
50
50
41.3
42.2
ND
50
50
49.5
55.2
ND
50
50
37.9
41.8
ND
50
50
51.8
58.4
ND
50
50
37.3
42.6
ND
50
50
43.8
50.0
ND
50
50
48.5
55.6
ND
50
50
39.6
44.2
ND
100
100
108
118
ND
100
100
81.4
91.8
ND
50
50
48.0
55.9
ND
50
50
42.0
47.1
ND
50
50
43.2
49.0
ND
50
50
53.5
61.8
ND
50
50
45.4
51.5
ND
50
50
53.1
59.5
ND
50
50
37.1
42.4
ND
100
100
46.1
50.7
ND
50
50
40.5
46.5
ND
50
50
59.8
66.4
ND
50
50
53.0
57.0
ND
50
50
47.9
51.8
ND
150
150
123
139
MS
% Rec
59
67
69
77
99
114
81
76
70
104
121
78
83
99
76
104
75
88
97
79
108
81
96
84
86
107
91
106
74
46
81
120
106
96
82
97
86
109
82
MSD % Rec
% Rec Limits
66 40-135
70 30-177
71 44-223
80 13-189
109 66-139
122 73-133
93 57-120
85 48-128
83 10-187
113 47-141
128 58-127
87 63-137
84 52-146
110 74-137
84 41-127
117 71-138
85 32-145
100 52-116
111 79-129
88 31-174
118 49-154
92 27-179
112 61-146
94 52-141
98 77-128
124 36-155
103 52-146
119 61-152
85 37-146
51 61-139
93 61-141
133 51-141
114 52-141
104 22-156
93 78-132
96 81-119
89 82-120
109 82-114
82 82-109
Max
RPD RPD Qual
11 18
4 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC.
2 14
4 12
10 10
7 13
14 13 R1
11 13
18 32
9 322
6 14 M1
12 10 R1
2 16
11 9 R1
10 10 v2
12 16
13 12 R1
13 13
14 14
11 10 R1
8 30
12 10 R1
15 15
11 65
13 14
14 14
13 11 R1
11 14
13 12 R1
9 12 M1
14 12 R1
10 13
7 14
8 26
12 7 RS
Page 25 of 30

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9800 Kincey Ave. Suite 100
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QUALITY CONTROL DATA
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
QC Batch: 475719 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
METHOD BLANK: 2578023
Matrix:
Water
Associated Lab Samples:
92428709001, 92428709002, 92428709003, 92428709004, 92428709005, 92428709006
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 05/16/19 12:43
1,2-Dichloroethane-d4 (S)
%
95
50-150
05/16/19 12:43
Toluene-d8 (S)
%
106
50-150
05/16/19 12:43
LABORATORY CONTROL SAMPLE: 2578024
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 17.7 89 70-130
1,2-Dichloroethane-d4 (S) % 103 50-150
Toluene-d8(S) % 107 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578025
2578026
MS
MSD
92427335014 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 8.2 20
20 26.0 30.0
89
109
50-150
14 30
1,2-Dichloroethane-d4 (S)
%
104
107
50-150
30
Toluene-d8 (S)
%
109
108
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC.
Page 26 of 30

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: BURKE CO. EAST BURKE
Pace Project No.: 92428709
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-GA Pace Analytical Services - Atlanta, GA
ANALYTE QUALIFIERS
B Analyte was detected in the associated method blank.
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
RS The RPD value in one of the constituent analytes was outside the control limits.
SO Surrogate recovery outside laboratory control limits.
v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the
associated samples and the sensitivity of the instrument was verified with a reporting limit check standard.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/21 /2019 12:08 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 30

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
BURKE CO. EAST BURKE
92428709
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92428709001
1202-MW1
EPA 3010A
475853
EPA 6010D
475974
92428709002
1202-MW2
EPA 3010A
475853
EPA 6010D
475974
92428709003
1202-MW3
EPA 3010A
475853
EPA 6010D
475974
92428709004
1202-AMW1
EPA 3010A
475853
EPA 6010D
475974
92428709005
1202-SW1
EPA 3010A
475853
EPA 6010D
475974
92428709006
1202-SW2
EPA 3010A
475853
EPA 6010D
475974
92428709001
1202-MW1
EPA 3010A
476009
EPA 6020B
476047
92428709002
1202-MW2
EPA 3010A
476009
EPA 6020B
476047
92428709003
1202-MW3
EPA 3010A
476009
EPA 6020B
476047
92428709004
1202-AMW1
EPA 3010A
476009
EPA 6020B
476047
92428709005
1202-SW1
EPA 3010A
476009
EPA 6020B
476047
92428709006
1202-SW2
EPA 3010A
476009
EPA 6020B
476047
92428709001
1202-MW1
EPA 8260D
28498
92428709002
1202-MW2
EPA 8260D
28498
92428709003
1202-MW3
EPA 8260D
28498
92428709004
1202-AMW1
EPA 8260D
28498
92428709005
1202-SW1
EPA 8260D
28498
92428709006
1202-SW2
EPA 8260D
28498
92428709001
1202-MW1
EPA 8260D Mod.
475719
92428709002
1202-MW2
EPA 8260D Mod.
475719
92428709003
1202-MW3
EPA 8260D Mod.
475719
92428709004
1202-AMW1
EPA 8260D Mod.
475719
92428709005
1202-SW1
EPA 8260D Mod.
475719
92428709006
1202-SW2
EPA 8260D Mod.
475719
Date: 05/21 /2019 12:08 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 28 of 30

e
c3C2AnaViCal
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
F-CAR-CS-033-Rev.06
Issuing Authority:
Pace Carolinas quality Office
Laboratory receiving samples:
Asheville ❑ Eden[] Greenwood ❑ Huntersville Raleigh❑ Mechanicsville[]
Sample Condition. Client Name: WO# ' 9242V r 09
Upon Receipt Projectlt: I
F EN UPS usP5 Client
Caurler: ❑ ed- ❑ ❑ ❑
❑ Commercial lace ❑other: 92428709
Custody Seal Present? ❑Yes ❑N-o' Seals Intact? ❑Yes [Jff r z ](
Oate/Initials Person Examining Contents:
Packing Material: []Bubble Wrap efaubble Sags ❑None ❑ Other Biological Tissue Frozen?
Thermometer; [R Gun I[:]Yes 2 o ❑N/A
D:
92TQ48 . Type of Ice: et ❑Brae ©None
Cooler Temp ('C): l Correction Factor: Add/Subtract ('C) Q.0
—�-`----- -7 Temp shouEd be above freezing to 6°C
Cooler Temp Corrected {'C}; J _ []Samples out of temp criteria. Samples on ice, cooling process
hasbegun
USDA Regulated Soil (01N/A, water sample)
Did samples originate in a quarantine zone within the United Slates: CA, NY, at SC (check maps)? Did samples originate from a Foreign source (internationally,
❑Yes 00
including mawanana ruerw mmolr vies uiro
Comments/Discrepancy;
Chain of Custody Present?
.6es
ONO
El N/A
I.
Samples Arrived within Hold Time?
Yes
[:]No
❑N/A
2,
Short Hold Time Analysls (<72 hr.)?
❑Yes
No
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
ON
❑N/A
4.
Sufficient Volume?
re
[]No
[]N/A
S.
Correct Containers Used?
Yew
❑No
❑N/A
6.
-Pace Containers Used?
i�es
❑No
❑N/A
Containers Intact?
2 es
[:]No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
Dyes
❑Na
,TN/A
S.
Sample Labels Match COC?
Yes
[]No
❑N/A
9.
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (55-6mm)?
Des
El Nk
IfflIA
10.
Trip Blank Present?
[]Yes
ZINO
❑N/A
11.
Trip Blank Custody Seals Present?
❑Yes
❑No
N/A
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICAT ION/RE$OLUTION
Field Data Required? ❑Yes ONO
Pe+ser}cer+ HEed: nate/Time:
Project Manager SCURF Review: 6ffi�"1 Date:
Project Manager SRF Review: fy 1J Y �Date:
Page 29 of 30

a
ceAnalytical
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR•C5.033•Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VGA, Collform,TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # WV # ; 924287a9
PM: NMG Due Date: 05/23/19
CLIENT: 92-Joyce Eng
4
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pH Adjustment Log for Preserved Samples
sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot 0
Note: Whenevefthere is a discrepancy affecting North Carolina compliance samples, a copy of this forrrm will besent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 30 of 30

ceAna"ca"
Section A
SAMPLE
One Cha ecter per
I (AZ. M1,-)
Sarryde Ids must be
UI
CHAIN -OF -CUSTODY / Analytical Request Document
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section e
Section C
Requiretl Project Info
'ion: invoice Information:
ach Pa e : t Of t
AheiHion: Lecia Jones
Report To: Van 13urt
COPY To: Gretta El
er Company Name: La Bella Associates
1 Purchase
Oicer No.
Addroes:
1664 Ombv Lane, Richmond,
VA
2322
t.-
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Client
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Project ID: Burk
Omer Number.'
Co. -East Burke
Pace
Pace
Quote Reference:
Project Manager. Nicole GaslorowSki
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aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
May 20, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on May 09, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Atlanta Certification IDs
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92428652001
92428652002
Field Blank
Trip Blank
Water
Water
05/06/19 19:23
05/06/19 06:00
05/09/19 09:31
05/09/19 09:31
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 21

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Burke Co. Blanks EB&Kirksey
92428652
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92428652001
Field Blank
EPA 601 OD
IDS
14
PASI-A
EPA 6020E
JOR
1
PASI-A
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
92428652002
Trip Blank
EPA 8260D
LIH
53
PASI-GA
EPA 8260D Mod.
SAS
3
PASI-C
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 4 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Sample: Field Blank Lab ID: 92428652001 Collected: 05/06/19 19:23 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
3.9
1
05/16/19 18:40
05/20/19 07:28
7440-36-0
Arsenic
ND
ug/L
10.0
5.0
1
05/16/19 18:40
05/20/19 07:28
7440-38-2
Barium
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
05/16/19 18:40
05/20/19 07:28
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
05/16/19 18:40
05/20/19 07:28
7440-43-9
Chromium
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-47-3
Cobalt
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-48-4
Copper
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-50-8
Lead
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7439-92-1
Nickel
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
05/16/19 18:40
05/20/19 07:28
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-22-4
Vanadium
ND
ug/L
5.0
2.5
1
05/16/19 18:40
05/20/19 07:28
7440-62-2
Zinc
ND
ug/L
10.0
5.0
1
05/16/19 18:40
05/20/19 07:28
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
0.10
0.060
1
05/16/19 18:40
05/18/1910:09
7440-28-0
8260D MSV Water, Extend
Analytical Method: EPA 8260D
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.32
1
05/15/19 23:42
630-20-6
1,1,1-Trichloroethane
ND
ug/L
1.0
0.38
1
05/15/19 23:42
71-55-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.53
1
05/15/19 23:42
79-34-5
1,1,2-Trichloroethane
ND
ug/L
1.0
0.59
1
05/15/19 23:42
79-00-5
1,1-Dichloroethane
ND
ug/L
1.0
0.41
1
05/15/19 23:42
75-34-3
1,1-Dichloroethene
ND
ug/L
1.0
0.72
1
05/15/19 23:42
75-35-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.46
1
05/15/19 23:42
96-18-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.55
1
05/15/19 23:42
96-12-8
1,2-Dibromoethane (EDB)
ND
ug/L
2.0
0.28
1
05/15/19 23:42
106-93-4
1,2-Dichlorobenzene
ND
ug/L
1.0
0.49
1
05/15/19 23:42
95-50-1
1,2-Dichloroethane
ND
ug/L
1.0
0.67
1
05/15/19 23:42
107-06-2
1,2-Dichloropropane
ND
ug/L
1.0
0.60
1
05/15/19 23:42
78-87-5
1,4-Dichlorobenzene
ND
ug/L
1.0
0.58
1
05/15/19 23:42
106-46-7
2-Butanone (MEK)
ND
ug/L
5.0
3.2
1
05/15/19 23:42
78-93-3
2-Hexanone
ND
ug/L
5.0
0.89
1
05/15/19 23:42
591-78-6
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
0.86
1
05/15/19 23:42
108-10-1
Acetone
ND
ug/L
25.0
8.2
1
05/15/19 23:42
67-64-1
Acrylonitrile
ND
ug/L
50.0
2.5
1
05/15/19 23:42
107-13-1
Benzene
ND
ug/L
1.0
0.20
1
05/15/19 23:42
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.50
1
05/15/19 23:42
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.36
1
05/15/19 23:42
75-27-4
Bromoform
ND
ug/L
1.0
0.55
1
05/15/19 23:42
75-25-2
Bromomethane
ND
ug/L
2.0
0.95
1
05/15/19 23:42
74-83-9
Carbon disulfide
ND
ug/L
10.0
0.79
1
05/15/19 23:42
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.42
1
05/15/19 23:42
56-23-5 L1
Chlorobenzene
ND
ug/L
1.0
0.53
1
05/15/19 23:42
108-90-7
Chloroethane
ND
ug/L
1.0
0.52
1
05/15/19 23:42
75-00-3
REPORT OF LABORATORY ANALYSIS
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Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 21

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ANALYTICAL RESULTS
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Sample: Field Blank Lab ID: 92428652001 Collected: 05/06/19 19:23 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend
Chloroform
Chloromethane
Dibromochloromethane
Dibromomethane
Ethylbenzene
lodomethane
Methylene Chloride
Styrene
Tetrachloroethene
Toluene
Trichloroethene
Trichlorofluoromethane
Vinyl acetate
Vinyl chloride
Xylene (Total)
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
m&p-Xylene
o-Xylene
trans-1,2-Dichloroethene
trans- 1,3-Dichloropropene
trans-1,4-Dichloro-2-butene
Surrogates
1,2-Dichloroethane-d4 (S)
Dibromofluoromethane (S)
4-Bromofluorobenzene (S)
Toluene-d8 (S)
8260D MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 05/20/2019 05:10 PM
Analytical Method: EPA 8260D
ND
ug/L
1.0
0.58
1
05/15/19 23:42
67-66-3
ND
ug/L
1.0
0.38
1
05/15/19 23:42
74-87-3
ND
ug/L
1.0
0.31
1
05/15/19 23:42
124-48-1
ND
ug/L
1.0
0.62
1
05/15/19 23:42
74-95-3
ND
ug/L
1.0
0.45
1
05/15/19 23:42
100-41-4
ND
ug/L
10.0
3.1
1
05/15/19 23:42
74-88-4
ND
ug/L
1.0
0.50
1
05/15/19 23:42
75-09-2
ND
ug/L
1.0
0.50
1
05/15/19 23:42
100-42-5
ND
ug/L
1.0
0.78
1
05/15/19 23:42
127-18-4
ND
ug/L
1.0
0.31
1
05/15/19 23:42
108-88-3
ND
ug/L
1.0
0.34
1
05/15/19 23:42
79-01-6
ND
ug/L
1.0
0.51
1
05/15/19 23:42
75-69-4
ND
ug/L
2.0
0.42
1
05/15/19 23:42
108-05-4
ND
ug/L
1.0
0.60
1
05/15/19 23:42
75-01-4
ND
ug/L
2.0
1.5
1
05/15/19 23:42
1330-20-7
ND
ug/L
1.0
0.66
1
05/15/19 23:42
156-59-2
ND
ug/L
1.0
0.22
1
05/15/19 23:42
10061-01-5
ND
ug/L
1.0
0.92
1
05/15/19 23:42
179601-23-1
ND
ug/L
1.0
0.54
1
05/15/19 23:42
95-47-6
ND
ug/L
1.0
0.46
1
05/15/19 23:42
156-60-5
ND
ug/L
1.0
0.30
1
05/15/19 23:42
10061-02-6
ND
ug/L
5.0
1.6
1
05/15/19 23:42
110-57-6
98
%.
81-119
1
05/15/19 23:42
17060-07-0
107
%.
82-114
1
05/15/19 23:42
1868-53-7
87
%.
82-120
1
05/15/19 23:42
460-00-4
83
%.
82-109
1
05/15/19 23:42
2037-26-5
Analytical Method: EPA 8260D Mod.
ND
ug/L
2.0
1.2
1
05/16/1913:03
123-91-1
106
%
50-150
1
05/16/1913:03
17060-07-0
108
%
50-150
1
05/16/1913:03
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 21

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9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Sample: Trip Blank Lab ID: 92428652002 Collected: 05/06/19 06:00 Received: 05/09/19 09:31 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260D MSV Water, Extend Analytical Method: EPA 8260D
1,1,1,2-Tetrachloroethane
ND
ug/L
1.0
0.32
1
05/16/19 00:08
630-20-6
1,1,1-Trichloroethane
ND
ug/L
1.0
0.38
1
05/16/19 00:08
71-55-6
1,1,2,2-Tetrachloroethane
ND
ug/L
1.0
0.53
1
05/16/19 00:08
79-34-5
1,1,2-Trichloroethane
ND
ug/L
1.0
0.59
1
05/16/19 00:08
79-00-5
1,1-Dichloroethane
ND
ug/L
1.0
0.41
1
05/16/19 00:08
75-34-3
1,1-Dichloroethene
ND
ug/L
1.0
0.72
1
05/16/19 00:08
75-35-4
1,2,3-Trichloropropane
ND
ug/L
1.0
0.46
1
05/16/19 00:08
96-18-4
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.55
1
05/16/19 00:08
96-12-8
1,2-Dibromoethane (EDB)
ND
ug/L
2.0
0.28
1
05/16/19 00:08
106-93-4
1,2-Dichlorobenzene
ND
ug/L
1.0
0.49
1
05/16/19 00:08
95-50-1
1,2-Dichloroethane
ND
ug/L
1.0
0.67
1
05/16/19 00:08
107-06-2
1,2-Dichloropropane
ND
ug/L
1.0
0.60
1
05/16/19 00:08
78-87-5
1,4-Dichlorobenzene
ND
ug/L
1.0
0.58
1
05/16/19 00:08
106-46-7
2-Butanone (MEK)
ND
ug/L
5.0
3.2
1
05/16/19 00:08
78-93-3
2-Hexanone
ND
ug/L
5.0
0.89
1
05/16/19 00:08
591-78-6
4-Methyl-2-pentanone (MIBK)
ND
ug/L
5.0
0.86
1
05/16/19 00:08
108-10-1
Acetone
ND
ug/L
25.0
8.2
1
05/16/19 00:08
67-64-1
Acrylonitrile
ND
ug/L
50.0
2.5
1
05/16/19 00:08
107-13-1
Benzene
ND
ug/L
1.0
0.20
1
05/16/19 00:08
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.50
1
05/16/19 00:08
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.36
1
05/16/19 00:08
75-27-4
Bromoform
ND
ug/L
1.0
0.55
1
05/16/19 00:08
75-25-2
Bromomethane
ND
ug/L
2.0
0.95
1
05/16/19 00:08
74-83-9
Carbon disulfide
ND
ug/L
10.0
0.79
1
05/16/19 00:08
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.42
1
05/16/19 00:08
56-23-5 L1
Chlorobenzene
ND
ug/L
1.0
0.53
1
05/16/19 00:08
108-90-7
Chloroethane
ND
ug/L
1.0
0.52
1
05/16/19 00:08
75-00-3
Chloroform
ND
ug/L
1.0
0.58
1
05/16/19 00:08
67-66-3
Chloromethane
ND
ug/L
1.0
0.38
1
05/16/19 00:08
74-87-3
Dibromochloromethane
ND
ug/L
1.0
0.31
1
05/16/19 00:08
124-48-1
Dibromomethane
ND
ug/L
1.0
0.62
1
05/16/19 00:08
74-95-3
Ethylbenzene
ND
ug/L
1.0
0.45
1
05/16/19 00:08
100-41-4
lodomethane
ND
ug/L
10.0
3.1
1
05/16/19 00:08
74-88-4
Methylene Chloride
ND
ug/L
1.0
0.50
1
05/16/19 00:08
75-09-2
Styrene
ND
ug/L
1.0
0.50
1
05/16/19 00:08
100-42-5
Tetrachloroethene
ND
ug/L
1.0
0.78
1
05/16/19 00:08
127-18-4
Toluene
ND
ug/L
1.0
0.31
1
05/16/19 00:08
108-88-3
Trichloroethene
ND
ug/L
1.0
0.34
1
05/16/19 00:08
79-01-6
Trichlorofluoromethane
ND
ug/L
1.0
0.51
1
05/16/19 00:08
75-69-4
Vinyl acetate
ND
ug/L
2.0
0.42
1
05/16/19 00:08
108-05-4
Vinyl chloride
ND
ug/L
1.0
0.60
1
05/16/19 00:08
75-01-4
Xylene (Total)
ND
ug/L
2.0
1.5
1
05/16/19 00:08
1330-20-7
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.66
1
05/16/19 00:08
156-59-2
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.22
1
05/16/19 00:08
10061-01-5
m&p-Xylene
ND
ug/L
1.0
0.92
1
05/16/19 00:08
179601-23-1
o-Xylene
ND
ug/L
1.0
0.54
1
05/16/19 00:08
95-47-6
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM
without the written consent of Pace Analytical Services, LLC.
Page 7 of 21

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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Sample: Trip Blank
Lab ID:
92428652002
Collected:
05/06/19 06:00
Received: 05/09/19 09:31 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Water, Extend
Analytical
Method: EPA 8260D
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.46
1
05/16/19 00:08
156-60-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
05/16/19 00:08
10061-02-6
trans-1,4-Dichloro-2-butene
ND
ug/L
5.0
1.6
1
05/16/19 00:08
110-57-6
Surrogates
1,2-Dichloroethane-d4 (S)
99
%.
81-119
1
05/16/19 00:08
17060-07-0
Dibromofluoromethane (S)
105
%.
82-114
1
05/16/19 00:08
1868-53-7
4-Bromofluorobenzene (S)
86
%.
82-120
1
05/16/19 00:08
460-00-4
Toluene-d8 (S)
83
%.
82-109
1
05/16/19 00:08
2037-26-5
8260D MSV SIM
Analytical
Method: EPA 8260D
Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1.2
1
05/16/19 13:23
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
50-150
1
05/16/19 13:23
17060-07-0
Toluene-d8 (S)
108
%
50-150
1
05/16/19 13:23
2037-26-5
Date: 05/20/2019 05:10 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 21

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Pace Analytical Services, LLC
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QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
QC Batch: 475606 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92428652001
METHOD BLANK: 2577609
Associated Lab Samples: 92428652001
Parameter
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
Antimony
ug/L
ND
5.0
3.9
05/20/19 06:13
Arsenic
ug/L
ND
10.0
5.0
05/20/19 06:13
Barium
ug/L
ND
5.0
2.5
05/20/19 06:13
Beryllium
ug/L
ND
1.0
0.50
05/20/19 06:13
Cadmium
ug/L
ND
1.0
0.50
05/20/19 06:13
Chromium
ug/L
ND
5.0
2.5
05/20/19 06:13
Cobalt
ug/L
ND
5.0
2.5
05/20/19 06:13
Copper
ug/L
ND
5.0
2.5
05/20/19 06:13
Lead
ug/L
ND
5.0
2.5
05/20/19 06:13
Nickel
ug/L
ND
5.0
2.5
05/20/19 06:13
Selenium
ug/L
ND
10.0
5.0
05/20/19 06:13
Silver
ug/L
ND
5.0
2.5
05/20/19 06:13
Vanadium
ug/L
ND
5.0
2.5
05/20/19 06:13
Zinc
ug/L
ND
10.0
5.0
05/20/19 06:13
LABORATORY CONTROL SAMPLE:
Parameter
2577610
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
Antimony
ug/L
500
489
98
80-120
Arsenic
ug/L
500
463
93
80-120
Barium
ug/L
500
503
101
80-120
Beryllium
ug/L
500
504
101
80-120
Cadmium
ug/L
500
491
98
80-120
Chromium
ug/L
500
498
100
80-120
Cobalt
ug/L
500
488
98
80-120
Copper
ug/L
500
503
101
80-120
Lead
ug/L
500
479
96
80-120
Nickel
ug/L
500
487
97
80-120
Selenium
ug/L
500
484
97
80-120
Silver
ug/L
250
250
100
80-120
Vanadium
ug/L
500
490
98
80-120
Zinc
ug/L
500
482
96
80-120
Qualifiers
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577611 2577612
MS MSD
92428534001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Antimony ug/L ND 500 500 498 500 99 100 75-125 1 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 9 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project:
Pace Project No.:
Burke Co. Blanks EB&Kirksey
92428652
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577611
2577612
MS
MSD
92428534001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Arsenic
ug/L
ND
500
500
474
476
95
95
75-125
0
20
Barium
ug/L
54.1
500
500
560
567
101
103
75-125
1
20
Beryllium
ug/L
ND
500
500
509
512
102
102
75-125
1
20
Cadmium
ug/L
ND
500
500
506
507
101
101
75-125
0
20
Chromium
ug/L
ND
500
500
507
509
101
102
75-125
0
20
Cobalt
ug/L
ND
500
500
494
496
99
99
75-125
0
20
Copper
ug/L
ND
500
500
507
508
101
102
75-125
0
20
Lead
ug/L
ND
500
500
485
488
97
97
75-125
1
20
Nickel
ug/L
ND
500
500
495
497
99
99
75-125
0
20
Selenium
ug/L
ND
500
500
515
523
103
105
75-125
2
20
Silver
ug/L
ND
250
250
254
256
101
102
75-125
1
20
Vanadium
ug/L
ND
500
500
502
501
100
100
75-125
0
20
Zinc
ug/L
10.4
500
500
509
508
100
100
75-125
0
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
QC Batch: 475600
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92428652001
METHOD BLANK: 2577596
Matrix: Water
Associated Lab Samples: 92428652001
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Thallium ug/L
ND 0.10 0.060 05/18/19 07:40
LABORATORY CONTROL SAMPLE: 2577597
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 9.1 91
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577598 2577599
MS MSD
92427326018
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND
10 10 9.2 9.5
92 95 75-125 3 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
QC Batch: 28443 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Water, Extend
Associated Lab Samples: 92428652001, 92428652002
METHOD BLANK: 128030
Associated Lab Samples: 92428652001, 92428652002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.32
05/15/19 18:29
1,1,1-Trichloroethane
ug/L
ND
1.0
0.38
05/15/19 18:29
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.53
05/15/19 18:29
1,1,2-Trichloroethane
ug/L
ND
1.0
0.59
05/15/19 18:29
1,1-Dichloroethane
ug/L
ND
1.0
0.41
05/15/19 18:29
1,1-Dichloroethene
ug/L
ND
1.0
0.72
05/15/19 18:29
1,2,3-Trichloropropane
ug/L
ND
1.0
0.46
05/15/19 18:29
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.55
05/15/19 18:29
1,2-Dibromoethane (EDB)
ug/L
ND
2.0
0.28
05/15/19 18:29
1,2-Dichlorobenzene
ug/L
ND
1.0
0.49
05/15/19 18:29
1,2-Dichloroethane
ug/L
ND
1.0
0.67
05/15/19 18:29
1,2-Dichloropropane
ug/L
ND
1.0
0.60
05/15/19 18:29
1,4-Dichlorobenzene
ug/L
ND
1.0
0.58
05/15/19 18:29
2-Butanone (MEK)
ug/L
ND
5.0
3.2
05/15/19 18:29
2-Hexanone
ug/L
ND
5.0
0.89
05/15/19 18:29
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
0.86
05/15/19 18:29
Acetone
ug/L
ND
25.0
8.2
05/15/19 18:29
Acrylonitrile
ug/L
ND
50.0
2.5
05/15/19 18:29
Benzene
ug/L
ND
1.0
0.20
05/15/19 18:29
Bromochloromethane
ug/L
ND
1.0
0.50
05/15/19 18:29
Bromodichloromethane
ug/L
ND
1.0
0.36
05/15/19 18:29
Bromoform
ug/L
ND
1.0
0.55
05/15/19 18:29
Bromomethane
ug/L
ND
2.0
0.95
05/15/19 18:29
Carbon disulfide
ug/L
ND
10.0
0.79
05/15/19 18:29
Carbon tetrachloride
ug/L
ND
1.0
0.42
05/15/19 18:29
Chlorobenzene
ug/L
ND
1.0
0.53
05/15/19 18:29
Chloroethane
ug/L
ND
1.0
0.52
05/15/19 18:29
Chloroform
ug/L
ND
1.0
0.58
05/15/19 18:29
Chloromethane
ug/L
ND
1.0
0.38
05/15/19 18:29
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.66
05/15/19 18:29
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.22
05/15/19 18:29
Dibromochloromethane
ug/L
ND
1.0
0.31
05/15/19 18:29
Dibromomethane
ug/L
ND
1.0
0.62
05/15/19 18:29
Ethylbenzene
ug/L
ND
1.0
0.45
05/15/19 18:29
lodomethane
ug/L
ND
10.0
3.1
05/15/19 18:29
m&p-Xylene
ug/L
ND
1.0
0.92
05/15/19 18:29
Methylene Chloride
ug/L
ND
1.0
0.50
05/15/19 18:29
o-Xylene
ug/L
ND
1.0
0.54
05/15/19 18:29
Styrene
ug/L
ND
1.0
0.50
05/15/19 18:29
Tetrachloroethene
ug/L
ND
1.0
0.78
05/15/19 18:29
Toluene
ug/L
ND
1.0
0.31
05/15/19 18:29
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
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QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
METHOD BLANK: 128030
Associated Lab Samples:
Parameter
92428652001, 92428652002
Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.46
05/15/19 18:29
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.30
05/15/19 18:29
trans-1,4-Dichloro-2-butene
ug/L
ND
5.0
1.6
05/15/19 18:29
Trichloroethene
ug/L
ND
1.0
0.34
05/15/19 18:29
Trichlorofluoromethane
ug/L
ND
1.0
0.51
05/15/19 18:29
Vinyl acetate
ug/L
ND
2.0
0.42
05/15/19 18:29
Vinyl chloride
ug/L
ND
1.0
0.60
05/15/19 18:29
Xylene (Total)
ug/L
ND
2.0
1.5
05/15/19 18:29
1,2-Dichloroethane-d4 (S)
%.
96
81-119
05/15/19 18:29
4-Bromofluorobenzene (S)
%.
86
82-120
05/15/19 18:29
Dibromofluoromethane (S)
%.
101
82-114
05/15/19 18:29
Toluene-d8 (S)
%.
84
82-109
05/15/19 18:29
LABORATORY CONTROL SAMPLE:
Parameter
128031
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
53.2
106
68-137
1,1,1-Trichloroethane
ug/L
50
60.6
121
72-134
1,1,2,2-Tetrachloroethane
ug/L
50
44.5
89
51-158
1,1,2-Trichloroethane
ug/L
50
56.8
114
78-131
1,1-Dichloroethane
ug/L
50
58.2
116
69-151
1,1-Dichloroethene
ug/L
50
56.5
113
64-158
1,2,3-Trichloropropane
ug/L
50
41.7
83
78-133
1,2-Dibromo-3-chloropropane
ug/L
50
43.2
86
58-124
1,2-Dibromoethane (EDB)
ug/L
50
56.7
113
71-134
1,2-Dichlorobenzene
ug/L
50
49.7
99
70-135
1,2-Dichloroethane
ug/L
50
56.7
113
72-129
1,2-Dichloropropane
ug/L
50
52.5
105
64-135
1,4-Dichlorobenzene
ug/L
50
47.6
95
70-131
2-Butanone (MEK)
ug/L
100
94.0
94
52-143
2-Hexanone
ug/L
100
79.9
80
61-136
4-Methyl-2-pentanone (MIBK)
ug/L
100
89.1
89
71-129
Acetone
ug/L
100
119
119
48-224
Acrylonitrile
ug/L
200
188
94
66-154
Benzene
ug/L
50
57.8
116
68-132
Bromochloromethane
ug/L
50
66.5
133
73-133
Bromodichloromethane
ug/L
50
49.2
98
67-121
Bromoform
ug/L
50
48.6
97
57-125
Bromomethane
ug/L
50
44.5
89
35-156
Carbon disulfide
ug/L
100
97.3
97
47-141
Carbon tetrachloride
ug/L
50
61.6
123
66-122 L1
Chlorobenzene
ug/L
50
48.5
97
71-126
Chloroethane
ug/L
50
43.4
87
43-143
Chloroform
ug/L
50
58.8
118
71-136
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
LABORATORY CONTROL SAMPLE:
Parameter
128031
Units
Spike LCS
Conc. Result
Chloromethane
ug/L
50
cis-1,2-Dichloroethene
ug/L
50
cis-1,3-Dichloropropene
ug/L
50
Dibromochloromethane
ug/L
50
Dibromomethane
ug/L
50
Ethylbenzene
ug/L
50
lodomethane
ug/L
100
m&p-Xylene
ug/L
100
Methylene Chloride
ug/L
50
o-Xylene
ug/L
50
Styrene
ug/L
50
Tetrachloroethene
ug/L
50
Toluene
ug/L
50
trans-1,2-Dichloroethene
ug/L
50
trans- 1,3-Dichloropropene
ug/L
50
trans-1,4-Dichloro-2-butene
ug/L
100
Trichloroethene
ug/L
50
Trichlorofluoromethane
ug/L
50
Vinyl acetate
ug/L
50
Vinyl chloride
ug/L
50
Xylene (Total)
ug/L
150
1,2-Dichloroethane-d4 (S)
%.
4-Bromofluorobenzene (S)
%.
Dibromofluoromethane (S)
%.
Toluene-d8 (S)
%.
LCS
% Rec
% Rec
Limits
42.9
86
47-123
62.6
125
74-131
49.7
99
78-120
55.7
111
65-115
61.0
122
79-129
48.6
97
68-129
117
117
49-154
101
101
67-137
58.1
116
61-147
53.2
106
52-141
54.6
109
77-128
63.5
127
51-139
54.0
108
60-133
58.0
116
69-144
49.5
99
74-128
62.3
62
61-139
47.6
95
73-126
52.1
104
55-132
41.4
83
52-141
48.3
97
50-133
154
103
78-132
96
81-119
89
82-120
112
82-114
82
82-109
Qualifiers
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032
MS
92428710001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
128033
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
1,1,1,2-Tetrachloroethane
ug/L
ND
50
50
49.1
53.5
98
107
68-137
9
11
1,1,1-Trichloroethane
ug/L
ND
50
50
68.1
71.3
136
143
66-142
5
11 M1
1,1,2,2-Tetrachloroethane
ug/L
ND
50
50
43.9
47.2
88
94
39-171
7
13
1,1,2-Trichloroethane
ug/L
ND
50
50
55.3
59.2
111
118
73-136
7
12
1,1-Dichloroethane
ug/L
0.68J
50
50
60.9
62.9
120
125
66-155
3
15
1,1-Dichloroethene
ug/L
ND
50
50
65.8
68.9
132
138
33-181
5
34
1,2,3-Trichloropropane
ug/L
ND
50
50
39.8
43.1
80
86
78-133
8
14
1,2-Dibromo-3-
ug/L
ND
50
50
46.3
48.5
93
97
58-124
5
15
chloropropane
1,2-Dibromoethane (EDB)
ug/L
ND
50
50
54.1
58.6
108
117
71-134
8
12
1,2-Dichlorobenzene
ug/L
2.4
50
50
51.4
53.8
98
103
69-135
5
10
1,2-Dichloroethane
ug/L
ND
50
50
55.0
55.8
110
112
36-159
1
10
1,2-Dichloropropane
ug/L
ND
50
50
51.3
55.2
103
110
68-132
7
11
1,4-Dichlorobenzene
ug/L
47.3
50
50
95.7
97.4
97
100
49-153
2
9
2-Butanone (MEK)
ug/L
448
100
100
544
551
96
103
10-189
1
23 M3
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032
MS
92428710001 Spike
Parameter Units Result Conc.
MSD
Spike
Conc.
128033
MS
Result
MSD
Result
MS
% Rec
MSD
% Rec
% Rec
Limits
RPD
Max
RPD Qual
2-Hexanone
ug/L
8.0
100
100
83.0
88.5
75
81
40-135
6
18
4-Methyl-2-pentanone
ug/L
311
100
100
440
454
129
143
30-177
3
10 M3
(MIBK)
Acetone
ug/L
299
100
100
403
407
104
108
44-223
1
14 M3
Acrylonitrile
ug/L
ND
200
200
180
194
90
97
13-189
8
12
Benzene
ug/L
10.4
50
50
69.4
72.2
118
124
66-139
4
10
Bromochloromethane
ug/L
ND
50
50
66.1
69.6
132
139
73-133
5
13 M1
Bromodichloromethane
ug/L
ND
50
50
47.8
51.1
96
102
57-120
7
13
Bromoform
ug/L
ND
50
50
46.1
50.3
92
101
48-128
9
13
Bromomethane
ug/L
ND
50
50
29.7
38.7
59
77
10-187
26
32
Carbon disulfide
ug/L
ND
100
100
113
120
113
120
47-141
6
322
Carbon tetrachloride
ug/L
ND
50
50
69.4
73.6
139
147
58-127
6
14 MO
Chlorobenzene
ug/L
26.6
50
50
73.1
77.6
93
102
63-137
6
10
Chloroethane
ug/L
ND
50
50
47.2
47.7
93
94
52-146
1
16
Chloroform
ug/L
ND
50
50
58.8
61.7
118
123
74-137
5
9
Chloromethane
ug/L
ND
50
50
45.7
47.1
91
94
41-127
3
10
cis-1,2-Dichloroethene
ug/L
ND
50
50
62.0
64.0
124
128
71-138
3
16
cis-1,3-Dichloropropene
ug/L
ND
50
50
45.4
49.0
91
98
32-145
8
12
Dibromochloromethane
ug/L
ND
50
50
51.5
55.4
103
111
52-116
7
13
Dibromomethane
ug/L
ND
50
50
57.6
62.1
115
124
79-129
7
14
Ethylbenzene
ug/L
24.1
50
50
72.7
77.0
97
106
31-174
6
10
lodomethane
ug/L
ND
100
100
113
122
113
122
49-154
8
30
m&p-Xylene
ug/L
48.5
100
100
150
159
102
111
27-179
6
10
Methylene Chloride
ug/L
ND
50
50
57.2
58.7
114
117
61-146
3
15
o-Xylene
ug/L
7.3
50
50
59.5
63.1
104
111
52-141
6
65
Styrene
ug/L
ND
50
50
53.1
57.8
106
116
77-128
9
14
Tetrachloroethene
ug/L
ND
50
50
66.8
70.8
134
142
36-155
6
14
Toluene
ug/L
4.8
50
50
59.2
63.5
109
117
52-146
7
11
trans-1,2-Dichloroethene
ug/L
ND
50
50
63.8
65.0
128
130
61-152
2
14
trans-1,3-Dichloropropene
ug/L
ND
50
50
45.2
48.8
90
98
37-146
8
12
trans-1,4-Dichloro-2-butene
ug/L
ND
100
100
52.8
65.6
53
66
61-139
22
12 M1,R1
Trichloroethene
ug/L
ND
50
50
48.1
52.2
96
104
61-141
8
12
Trichlorofluoromethane
ug/L
ND
50
50
67.1
71.4
134
143
51-141
6
13 M1
Vinyl acetate
ug/L
ND
50
50
65.1
32.4
130
65
52-141
67
14 R1
Vinyl chloride
ug/L
ND
50
50
56.9
59.9
113
119
22-156
5
26
Xylene (Total)
ug/L
55.8
150
150
210
222
102
111
78-132
6
7
1,2-Dichloroethane-d4 (S)
%.
98
97
81-119
4-Bromofluorobenzene (S)
%.
88
86
82-120
Dibromofluoromethane (S)
%.
109
111
82-114
Toluene-d8 (S)
%.
82
83
82-109
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 21

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
QC Batch: 475719 Analysis Method: EPA 8260D Mod.
QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM
Associated Lab Samples: 92428652001, 92428652002
METHOD BLANK: 2578023
Matrix:
Water
Associated Lab Samples:
92428652001, 92428652002
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.2 05/16/19 12:43
1,2-Dichloroethane-d4 (S)
%
95
50-150
05/16/19 12:43
Toluene-d8 (S)
%
106
50-150
05/16/19 12:43
LABORATORY CONTROL SAMPLE: 2578024
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane(p-Dioxane) ug/L 20 17.7 89 70-130
1,2-Dichloroethane-d4 (S) % 103 50-150
Toluene-d8(S) % 107 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578025
2578026
MS
MSD
92427335014 Spike
Spike MS MSD
MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result Result
% Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane(p-Dioxane)
ug/L 8.2 20
20 26.0 30.0
89
109
50-150
14 30
1,2-Dichloroethane-d4 (S)
%
104
107
50-150
30
Toluene-d8 (S)
%
109
108
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 21

Pace Analytical Services, LLC
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Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-GA Pace Analytical Services - Atlanta, GA
ANALYTE QUALIFIERS
L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated
samples may be biased high.
MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21

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[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Burke Co. Blanks EB&Kirksey
Pace Project No.: 92428652
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
Batch
92428652001
Field Blank
EPA 3010A
475606 EPA6010D
475865
92428652001
Field Blank
EPA 3010A
475600 EPA6020B
475863
92428652001
Field Blank
EPA 8260D
28443
92428652002
Trip Blank
EPA 8260D
28443
92428652001
Field Blank
EPA 8260D Mod.
475719
92428652002
Trip Blank
EPA 8260D Mod.
475719
Date: 05/20/2019 05:10 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 18 of 21

Document Name:
Document Revised: February 7, 2018
. ARalXlcal
Sample Condition Upon Receipt(SCUR
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersviile /❑� Raleigh❑ Mechanicsville❑
ConditionSample Client Name: W V # : 92428652
ReceiptUpon Project
Courier:❑acx ds ❑[-]Client
❑Commercial Pe ❑Other:
92428652
Custody Seal Present? []Yes ONo Seals Intact? ❑Yes ❑No
Date/Initials person Examining Contents:
Packing Material: ❑Bubble Wrap dBubble Bags ❑None ❑ Other
The►mometel 92T948 Type of Ice: J2 et ❑slue
,3IR Gun ID:
Cooler Temp (°C): II Correction Factor: Add/Subtract (•C) d,()
Cooler Temp Corrected (+C): 4 ) r ,
i
USDA Regulated Soil (❑ N/A, water sample)
Did samples origi ate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
I—IYPc X.
Biological Tissue Frozen?
[]Yes[]No�]i N/A
[]None
Temp should be above freezing to VC
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source lintern�icnally,
inrludin¢ Hawaii and Puerto Rlcol? f—IYes -PNo
Comments/Discrepancy:
Chain of Custody Present?
©des
❑No
❑N/A
1.
Samples Arrived within Hold Time?
Ves
[]No
❑N/A
2.
Short Hold Time Analysis (02 hr.)?
❑Yes
❑9c,
❑N/A
3.
Rush Turn Around Time Requested?
[]Yes
' No
❑N/A
4.
Sufficient Volume?
LJYes
❑No
❑N/A
S.
Correct Containers Used?
�y s
[]No
[]N/A
6.
-Pace Containers Used?
Yes
❑No
❑N/A
Containers Intact?
Yes
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Ye;
❑No
EfN/A
8.
Sample Labels Watch COC?
Oyes
❑No
❑N/A
9.
-Includes Date/Time/ID/Analysis Matrix:
Headspace in VOA Vials (>5-6mm)?
❑Yes
ji]1ID
❑N/A
10,
Trip Blank Present?
ErYes
[:]No
❑N/A
11.
Trip Blank Custody Seals Present?
oes
No
[]N/A
COMMENTS/SAMPLE DISCREPANCY
Field Data Required? Dyes ❑No
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION , ,fJ
4 ) (0 i6 i'J lYh %� S1L � Y� �lL5 d t? ri! J, t
= � M-MMEMENEDON
Project Manager SCURF Review: Date:
Project Manager SRF Review: 1) ' �� Date: ! 73 1
Page 19 of 21

Document Name:
Document Revised: February 7, 2018
o
��aceAnalytica!
Sample Condition Upon Receipt(5CUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project WO# ; 92428652
PM: NMS Due Date: 05/23/19
CLIENT: 92—Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample 10
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 20 of 21

I.PaceAralyticar
CHAIN -OF -CUSTODY 1 Analytical Request Document
,,
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately.
Section A
Section 8
Section C
Required Client Information:
Required Project Information:
Invoice Information: ?a @
l
Of 1
Company: La Bella Associates Report To: Van Burbach Attention: Lecia Jones
Address: 2211 West Meadowview Rd
Copy To: Gretta Eller
Company Name: La Bella Associates
Greensboro, NC 27407
Address: 1604 Ownby Lane, Richmond, VA 2322
Re ulata A
Email To: vbUrbach D Ceen ineerin
.nom
Purchase Order No.
Pace Quote Reference.
Phone: [phone]U92 Fax
Client Project ID: Burke Co.BlankS EB & Kirksey
Pace Project Manager: Nicole Gasiorowskl
State! Locati
Requested Due Date/TAT: 10 Da Default
Container Order Number.
Pace Profile #: 2327-5
North Caroli
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Analysis
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MATRIX
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JDATE
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ADDITIONAL COMMENTS
RELINQUISHED BY I AFFILIATION
DATE
TIME
ACCEPTED BY I AFFILIATION
TIME
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•T ilt � l(�
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SAMPLER NAME AND SIGNATURE
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PRINT Name of SAMPLER: }� `` yy� v
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� '� ",;G

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
September 03, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on July 25, 2019. The
results relate only to the samples included in this report. Results reported herein conform to the most
current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where
applicable, unless otherwise noted in the body of the report.
This revision was issued on 9/3/19 to remove tetrachloroethene from MW-2, and to report additional
compounds for MW-3, per client request.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
J,u
6=.-/1�/_M1 /
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Ashley Martin, Labella Associates
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
�pQ ACrfFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9e0 without the written consent of Pace Analytical Services, LLC.
Page 1 of 14

acmnalytical
www.pacelabs.com
Pace Analytical Services, LLC
9800 KinceyAve. Suite 100
Huntersville, NC 28078
[phone]
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92438585001
MW - 2
Water
07/23/19 12:50
07/25/19 13:07
92438585002
MW - 3
Water
07/24/19 15:57
07/25/19 13:07
92438585003
Trip Blank
Water
07/23/19 09:30
07/25/19 13:07
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Burke Co - East Burke Resample
92438585
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92438585001
MW - 2
EPA 8260D
CL
4
PASI-C
92438585002
MW - 3
EPA 8260D
CL
6
PASI-C
92438585003
Trip Blank
EPA 8260D
CL
5
PASI-C
REPORT OF LABORATORY ANALYSIS
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aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Lab Sample ID Client Sample ID
Method Parameters Result Units Report Limit Analyzed Qualifiers
92438585001 MW - 2
EPA 8260D Benzene 0.95J ug/L 1.0 08/02/19 23:15
92438585002 MW - 3
EPA 8260D Benzene 0.63J ug/L 1.0 08/02/19 23:33
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC. Page 5 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Sample: MW - 2
Lab ID:
92438585001
Collected:
07/23/19 12:50
Received: 07/25/19 13:07 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Benzene
0.95J
ug/L
1.0
0.15 1
08/02/19 23:15
71-43-2
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
08/02/19 23:15
460-00-4
1,2-Dichloroethane-d4 (S)
83
%
70-130
1
08/02/19 23:15
17060-07-0
Toluene-d8 (S)
108
%
70-130
1
08/02/19 23:15
2037-26-5
Date: 09/03/2019 09:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Sample: MW - 3
Lab ID:
92438585002
Collected:
07/24/19 15:57
Received: 07/25/19 13:07 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Benzene
0.63J
ug/L
1.0
0.15
1
08/02/19 23:33
71-43-2
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
08/02/19 23:33
78-87-5
Tetrachloroethene
ND
ug/L
1.0
0.16
1
08/02/19 23:33
127-18-4
Surrogates
4-Bromofluorobenzene (S)
100
%
70-130
1
08/02/19 23:33
460-00-4
1,2-Dichloroethane-d4 (S)
85
%
70-130
1
08/02/19 23:33
17060-07-0
Toluene-d8 (S)
109
%
70-130
1
08/02/19 23:33
2037-26-5
Date: 09/03/2019 09:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Sample: Trip Blank
Lab ID:
92438585003
Collected:
07/23/19 09:30
Received: 07/25/19 13:07 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260D MSV Low Level Landfill
Analytical
Method: EPA 8260D
Benzene
ND
ug/L
1.0
0.15 1
08/02/19 22:05
71-43-2
Tetrachloroethene
ND
ug/L
1.0
0.16 1
08/02/19 22:05
127-18-4
Surrogates
4-Bromofluorobenzene (S)
95
%
70-130
1
08/02/19 22:05
460-00-4
1,2-Dichloroethane-d4 (S)
83
%
70-130
1
08/02/19 22:05
17060-07-0
Toluene-d8 (S)
108
%
70-130
1
08/02/19 22:05
2037-26-5
Date: 09/03/2019 09:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 14

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
QC Batch: 490158 Analysis Method: EPA 8260D
QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill
Associated Lab Samples: 92438585001, 92438585002, 92438585003
METHOD BLANK: 2644586
Matrix:
Water
Associated Lab Samples:
92438585001, 92438585002, 92438585003
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,2-Dichloropropane
ug/L
ND
1.0
0.19 08/02/19 17:23
Benzene
ug/L
ND
1.0
0.15 08/02/19 17:23
Tetrachloroethene
ug/L
ND
1.0
0.16 08/02/19 17:23
1,2-Dichloroethane-d4 (S)
%
94
70-130
08/02/19 17:23
4-Bromofluorobenzene (S)
%
100
70-130
08/02/19 17:23
Toluene-d8 (S)
%
104
70-130
08/02/19 17:23
LABORATORY CONTROL SAMPLE:
2644587
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
1,2-Dichloropropane
ug/L
50
50.4
101
70-130
Benzene
ug/L
50
50.7
101
70-130
Tetrachloroethene
ug/L
50
48.2
96
69-130
1,2-Dichloroethane-d4 (S)
%
104
70-130
4-Bromofluorobenzene (S)
%
94
70-130
Toluene-d8 (S)
%
96
70-130
MATRIX SPIKE SAMPLE:
2644589
92439759009
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,2-Dichloropropane
ug/L
ND
20
21.2
106
70-140
Benzene
ug/L
ND
20
22.2
111
70-151
Tetrachloroethene
ug/L
ND
20
23.0
115
59-143
1,2-Dichloroethane-d4 (S)
%
110
70-130
4-Bromofluorobenzene (S)
%
99
70-130
Toluene-d8 (S)
%
97
70-130
SAMPLE DUPLICATE: 2644588
92439759008
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
1,2-Dichloropropane
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Tetrachloroethene
ug/L
ND
ND
30
1,2-Dichloroethane-d4 (S)
%
80
94
4-Bromofluorobenzene (S)
%
98
95
Toluene-d8 (S)
%
106
104
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 09/03/2019 09:29 AM without the written consent of Pace Analytical Services, LLC. Page 9 of 14

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-C Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 09/03/2019 09:29 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 14

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Burke Co - East Burke Resample
Pace Project No.: 92438585
Lab ID
Sample ID
QC Batch Method
QC Batch Analytical Method
92438585001
MW - 2
EPA 8260D
490158
92438585002
MW - 3
EPA 8260D
490158
92438585003
Trip Blank
EPA 8260D
490158
Date: 09/03/2019 09:29 AM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Analytical
Batch
Page 11 of 14

o
aceAnalytrcal
Document Name:
Sample Condition Upon Receipt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No,;
F.CAr a_rc_naa.a
Issuing Authority:
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden[ —]
Greenwood❑
j
Huntersville Raleigh[]Mechanicsville❑
W O# : 92438585
ClientName:
on Receipt iri• ��'f�l IrI
,�
Project
„I
Courier: ❑F •Ea ❑UPS ❑USPS
❑ Commercial Pace ❑Other:
❑Client
92438585
E 1 No
Custody Seal Present? ❑Yes No
5eals Intact? []Yes
Date/Init}als Person Examining
Packing Material; []Bubble Wrap
i
❑Bubble Bags []None
❑ Other Biological Tissuee F oxen?
Dyes ❑No E]N/A
Thermometer
92TD48
TYpe of Ise: Wet
❑Blue []None
IR Gun ID:
Cooler Temp (°C): Correction Factor: Add/Subtract ('C) 0• fl
Tempshould be above freezing to 6°C
Cooler Temp Corrected ('C): y
❑5amples out oftemp criteria. Samples on ice, cooling process
water sample)
has begun
USDA Regulated Soil ([3-`N/A,
Did samples on ate in a quarantine zone within the United Slates; CA, NY, or SC (check maps)? Did samples originate from a foreign source (intemat anally,
including Hawaii and Puerto Rico)? [:]Ye-❑
❑Yes Na
Comm ents/Discrepancv :
Chain of Custody Present? (Yes ❑No ❑N/A 1 1.
Samples Arrived within Hold Time?
[Dyes
❑No
❑N/A
2.
Short Hold Time Ana lysls (<72 hr.)?
Dyes
DNNo
❑N/A
3.
Rush Turn Around Time Requested?
Dyes
i
❑No
C] N/A
4.
Sufficient volume?
❑Yes
[-]NO
❑N/A
S.
Correct Containers Used?
i
❑%f
❑No
❑N/A
6.
Pace Containers Used?
ElYes
❑No
❑N/A
Containers Intact?
Yes
[]No
N/A
7.
Dissolved analysis: Samples Field Filtered?
DYES,
❑No
NIA
6.
Sample Labels Match COC?
es
❑No
❑N/A
9.
-Includes Date/Time/ID/Analysis Matrix: W I
Headspace in VOA Vials I>5-6mm)? a ❑No ❑N/A 10.
Trip Blank Present? ClYes ❑No ❑N/A 11.
Trip Blank Custody Seals Present? Yes ❑No ❑N/A
COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes [—]No
CLIENT NOT
Person contacted: Date/Time:
Project Manager SCURF Review:
Project Manager SRF Review:
Lot ID of split containers:
Date:
Date: 1 (�
Page 12 of 14

Document Name:
Sample Condition Upon Rec
pocument No.:
Document Revised: February 7, 2018
Page 1 of 2
Issuing Authority:
D— r arnlinns Quality Office
*Check mark top half of box if pH and/or dechlorination Is Project t#
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, ORO/801S (water). DOC, LLHS
**13ottom half of box is to list number of bottle
u
ss
Z
z
N
N
C
v
a
v
v
2
i-1
Z
v
2
2
H
2
io
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t?
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=
Y
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ry
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19
a
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m
92
mm
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4
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7
8
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1D
11
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WO#:92438585
PM: NMG Due Dale: 08/08/19
CLIENT: 92-Joyce Eng
pH Adjustment Log for Preserved Samples
Sample ID Type of Preservative pH upon receipt pate preservation adjusted Tim adjusted preservation Amount added Preservative Lot q
rm will he to the North Carolina OEHNR Certification Office (i.e.
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this fo
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 13 of 14

u
Section A
Required C
W
F-
1
2
3
4
5
8
7
8
9
10
11
ant Information:
Labelfa Assoc
221 1 W t fvl
a, NC 2 4407
336 323-009,
is RatelTAT: 10
SAMPLE ID
One ChWacter per box.
(A-Z. 0-9 f , -)
Sample Ids must be unique
ADDITIONAL COMMENTS
Section B
Required Project Information:
Report To: Van Burbach
Uuya enI Protect ID: Burke Co. - Ea
ContaiOrder Number:
m a
MATRIX CODE o COLLECTED
❑-king Water
tiW
a
Water
WT
o
U
w;,,te worm
Ww
c
Product
P
m
SaWsdid
SL
Oil
oL
w
c7 START
Wien
WP
A,r
AR
w
Other
oT
p
>
Tissue
TS
U
I—
x
1+
c
q
m DATE TIMI
RELINOUISHEDBYIAFFILIATION DATE TIME
Si /Lc4 lc� 7iz j
NAME AND SIGNATURE
Name of SAMPLER:--
I
Boom
MaNNE
IMMEENNNEMEN
IMMEMENEMENEW
IMMENNEMENEEN
IMMENNEEMEMES
IMMEMENNOMENN
CHAIN -OF -CUSTODY / Analytical Request Document °'
tT
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. d
Section C
Invoice Information:
Attention: Lecia Jones Page . of 1
company Name: LabNa Assoc.
Address: 1604 Ownby Lane, Richmond, VA 23220
Q
Regulatory Agency
uote Reference:
gHesaii le Project Manager: Nicole Gasiorowski
Profile n' State / Location
NC
Preservatives
N z
m i
F m _
N m c
� L o
N al =
C c r
x x
x
� o0
ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS
J
a _
C N
�y✓ _ > BATE Signed: / �j CL
CHAIN -OF -CUSTODY / Analytical Request Document °'
tT
The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. d
Section C
Invoice Information:
Attention: Lecia Jones Page . of 1
company Name: LabNa Assoc.
Address: 1604 Ownby Lane, Richmond, VA 23220
Q
Regulatory Agency
uote Reference:
gHesaii le Project Manager: Nicole Gasiorowski
Profile n' State / Location
NC
Preservatives
N z
m i
F m _
N m c
� L o
N al =
C c r
x x
x
� o0
ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS
J
a _
C N
�y✓ _ > BATE Signed: / �j CL

DATE: 201 q
ENGINEERING GROUND WATER SAMPLING LOG
Project Name: & rye Co. — E&Sf R rje. Project No. /Task No.: 01g1g7J � 07-
Well ID: Mw —1 Sampler(s):' 1 AUSSon / S, sl2%OAY3
Well Location: V.
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with
W inches
feet
J�D SS feet
3- ('0 feet [DTB-DTW]
_ gallons
�.9 gallons
Z&.7 gallons
26 , 7 gallons
Depth to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(µS/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0��
17.y
7,�g
100,E
3,3�
Io3.9
1.8q
SS
%,1
09
j�,
S,(�2
115-,'7
3, 17
1A,,9
7.'70
17.1
083(o
1 ,0
5-,5-V
17$.
-7
153,
S66
--5S
0&, 7
08 5D
7,
J0q, o
►, 2
I . Z,l z
SS
Date of sample:
(1'l j
Before Sampling I
om
-7, 3
SE S&
I p r f C)
�. 2
��-
- 21 z
sS
Comments (weather conditions, odor, color, silt, etc.):
Signature: Date:
QA/QC Sign Off: Date:

DATE: 5-61,WY9
AJu r Lc
ENGINEER/NG GROUND WATER SAMPLING LOG
Project Name: a-s k" Project No. /Task No.: 21 g1$71 tiase— 01
Well ID• Aw Sampler(s): S 5feG
Well Location: &k'-'tJ 6 p- f
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with
Depth to Water before Sampling:
inches
,9% 1(7 feet
7� CX� feet
51 feet [DTB-DTW]
_
gallons
gallons
gallons
3Z `�
gallons
feet
Gallons
Time
Temp
(°C)
pH
Cond.
(PS/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
©
°9z
16.3
S:4,
GAS.6
%, >i
13Y /
-3.93
7-Y
1o.11
615-1
/&, 5/
S: &q
/5?4 7
2.6/
0. i
i7. C.
T" v
X. (
1 a1s
RP-3
, _7
�/3, y
a.65-
79 2
I7 s
7K
34,Y
INO
y
�.��
239:9
q,67
7ff
Date of sample:
54v
Before Sampling
Lo4lD
l 7. y
S.
.2-3j 9
02
7
T/f
Co�nts (weather conditions, odor, color, silt, etc.):
Ike-
Q1Signature: Date: 17D�
QA/QC Sign Off• Date•

DATE: 7J031zD1q
LaBelLa
GROUND WATER SAMPLING LOG
Project Name: bvy-'b Co.-- A254,x_ Project No. /Task No.: Z) S )8 11`a�- 02
Well ID: -Z be--65A CLSampler(s): 5. L�1CY. lY1;F
Well Location: 4 be�,rA uJQsiP ccIle&t'on fend
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volum� (WV):
2
inches
55 • $
feet
71, 0 5
feet
17. 0-7 feet [DTB-DTW]
For 2" Well: WCT X 0.163 = — gallons
For 4" Well: WCT X 0.653 = 11. gallons
For THREE Well Volumes: WV X 3 = 3�• gallons
Actual Amount Purged/Bailed:_gallons
Purged with: Bailer Pump Other:
Sampled with: �� Pump Other:
Depth to Water before Sampling: 1 ' feet
Gallons
Time
Temp
(°C)
pH
Cond.
(us/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
H57
17Z
(o,7q�1�3,0
Z, 55
S
5,25-
SS
I1,1
121�1
It0,9
5-, (d,-;'
q 9a•0
,52
1DT I
q,-72
ZZ. Z
) Z35
.7
5,- S9
2$. t�
Z, S
101. (0
, 01
�S
3S . 3
) 2.rC)
3, 2.0
S&
Date of sample:
71Z31)9
Before Sampling
17,5p
cd,
c!
q5-q, ', I
-Z09_�
}`
20
Comments (weather conditions, odor, color, silt, etc.):
f
Signature:4!��& Date: W o) q
• • • _ - •
�1, . l I ' L 1

DATE:��
au r `G
ENGINEERING GROUND WATER SAMPLING LOG
Project Name: _bv/4e Q) vv- j&— Project No. /Task No.: ZIS►$'71 Phosc, OZ
Well ID: NIW- 3 Sampler(s):- i L'J5'o0
Well Location:
-?r-
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
Calculation for One Well Volume (WV):
For 2" Well:
For 4" Well:
WCT X 0.163
WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled with
2 inches
- Z _feet
3Z , 50 feet
Z3, Z 1 feet [DTB-DTW]
gallons
6, Z- gallons
gallons
5, (0 gallons
Depth'to Water before Sampling: feet
Gallons
Time
Temp
(°C)
pH
Cond.
(µS/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
1(p , D
SS'
281, Z
1,36
y y
7 Z-F
SS
K, Z
113
1S-
5- 63
Z66. !
z, (e
)70.9
11,1
S�
3C)•q
i 5q
5-,&5
Zkn
337
le9,0
10,2
SS
K
)Z®q
I.35
17&.0
5,, 6,3
TIk
Date of sample:
�57/(,/Iq
Before Sampling
12
)( , $
5 S $
06&'s
J, 35
17& , o I
S & 3
-rj+
C— m. ments (weather conditions, odor, color, silt, etc.):
we. I Ci"t VJQ5 00,rA V 01 `n, Ak 1 4- 70 S 6A S/
Z4
1 / 1 /�L

DATE: �ZC'I q
� La BeUa
GROUND WATER SAMPLING LOG
Project Name: Ey,4e 0D." I�L4 BUS Fes- Project No. /Task No.: 21915 71 �1'1 C)z
Well ID: —3 C� S� Sampler(s): S. sk +
Well Location: ivn—_ r000& Y lem
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 =
For 4" Well: WCT X 0.653
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled wit[
Depth to Water before Sampling:
nches
q, 9 3 feet
j52- S-- feet
ZZ , --7 feet [DTB-DTW]
feet
Ilons
gallons
gallons
gallons
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
)`Z�
SZ(o
SO`3
3,L}Z
ZZ(o,2
lq,
CC
JS
1 �1
I S 3
.0
70
-7,33
5s
Zq-q
155D
. Z
3. T
J
5'l
SS-1
! (o+ "
A 7
0,
l q7,
14,q1
jS
Date of sample:
Before Sampling
GJ
,,
�)
"l��
�C'
i47f
is
Comments (weather conditions, odor, color, silt, etc.):
Signature: a,i/, Date: 7�21i/wig
QA/QC Sign Off: k �n Q." Date: O1

DATE: 5AP/ ZO1 q
&jLJ i `c
ENGINEERING GROUND WATER SAMPLING LOG
Project Name: 19vr6- Cv, -- Ls� gurlf,_ Project No. /Task No.: Z1$ 1$71 !' phase OZ
Well ID: A �\�" i
Sampler(s):'I_&, son 1 S, v l� bode
WellLocation: LeA an 161cng19 Poll 4, 4rough WooAs Ckcfc5s 4f-eam
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
2 inches
7 - g feet
7. 3 feet
3. 2 2 feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = 0,15 gallons
For 4" Well: WCT X 0.653 = — gallons
For THREE Well Volumes: WV X 3 = 1. � gallons
Actual Amount Purged/Bailed: gallons
Purged with: ailer Pump Other:
Sampled with: ailer _ Pump Other:
Depth to Water before Sampling:
feet
Gallons
Time
Temp
(°C)
pH
Cond.
(PS/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
C�
133Z
l�.
&. 01
107, Z
q, 25-
)7S 3
11.0
15S
O.S
J233
fsSr
5,76
109.7
Z•73
17b.7
S1. o
S,
I.O
► Z3'�
� )
S. 73
11 q, 3
3.33
(H9,1
11(o
JS
Date of sample:
Before Sampling
73
)I$,l
3 Z$ I
I�(p 1
11, S
SS
Comments (weather conditions, odor, color, silt, etc.):
-Tilt- w eA-I L.-- t 5 70 `s -4- Aar+� vd y ort
Signature: ,f Date•��/20Iq
QA/QC Date: S

DATE: 05/6/2019
&'u i `r
ENGINEERING SURFACE WATER MONITORING LOG
Project Name: Burke County- East Burke Project/Task No.: 2181871 / phase 02
Surface Point ID: SW-1 Sampler(s): T. Hudson / S. Slebodnik
Location: Old sed. pond, up old rd. from MW-3
Field Parameters:
Time of Sampling:
1135
pH:
6.26
Temperature:
16.5
(°C)
Conductivity:
127.6
(µS/cm)
Dissolved Oxygen:
5.90
(mg/L)
ORP:
145.3
(mV)
Turbidity:
15.2
(NTU)
Comments/Sample Description (weather conditions, odor, color, silt, etc.): The
weather was 70's and partlycudy on 5/6/2019.
Signature: _ Date:ell"
QA/QC Sign Off:_ ./Le�j Date: c
Revised 5/9/19

DATE: 5/6/2019
&"u i a c
E1\1GINEEl4/NG SURFACE WATER MONITORING LOG
Project Name: Burke County- East Burke Project/Task No.: 2181871 / phase 02
Surface Point ID: SW-2 Sampler(s): T. Hudson / S. Slebodnik
Location: downstream from MW-3 & AMW-1
Field Parameters:
Time of Sampling:
pH:
Temperature:
Conductivity:
Dissolved Oxygen:
ORP:
Turbidity:
1240
6.12
16.6
(°C)
131.2
—(AS/cm)
6.32
(mg/L)
155.3
(mV)
14.4
(NTU)
Comments/Sample Description (weather conditions, odor, color, silt, etc.): The
weather was 70's and partly cloudy on 5/6/2019.
Sketch of Sample Location (include flow direction, drainage pathways, etc.):
QA/QC Sign Off:
Date:
Date:

APPENDIX 2
Historical Data
Table A2-1 Historical Groundwater Elevations
Table A2-2
Historical Groundwater Constituents
Table A2-3
Historical Surface Water Constituents
Table A2-4
Historical Groundwater Field Parameters
Table A2-5
Historical Surface Water Field Parameters

TABLE A2-1: Historical Groundwater Elevations
Well ID:
MW-1
MW-2
MW-3
AMW-1
TOC Elevation:
1147.00
1096.50
1039.00
1021.00
Well Depth (Ft):
50.55
71.05
32.50
7.30
05/18/15
1108.36
1032.09
1030.10
1016.35
12/07/15
1108.30
1030.95
1028.55
1016.55
05/02/16
1109.15
1037.00
1026.50
1016.69
12/12/16
1108.05
1036.20
1026.85
1016.35
06/26/17
1108.15
1042.85
1026.00
1016.30
12/14/17
1107.54
1031.67
1028.00
1016.45
05/16/18
1108.44
1030.65
1028.14
1016.35
12/03/18
1107.91
1034.32
1028.61
1016.55
05/06/19
1110.05
1042.03
1029.71
1016.92
Notes: All elevations are in feet above mean sea level.
Well depths are in feet belwo top of casing.
TOC Elevations are estimated from best available data.
Burke County -East Burke
Permit 12-02
LaBella Associates

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
INORGANICS
Arsenic
28-Apr-94
NR
1
ND
3.0
ND
NI
ND
2-May-00
NR
10
ND
15
J ND
NI
ND
8-Nov-00
NR
10
ND
18.0
ND
NI
ND
31-May-01
NR
10
ND
14
J ND
NI
ND
6-Nov-01
NR
10
ND
ND
ND
NI
ND
21-May-02
NR
10
13.0
10
ND
NI
ND
13-Nov-02
NR
10
ND
ND
ND
NI
ND
13-May-03
NR
10
24.0
15.0
ND
NI
ND
18-Nov-03
NR
10
ND
27.0
ND
ND
ND
4-May-04
NR
10
ND
23.0
ND
ND
ND
9-Nov-04
NR
10
ND
27.0
ND
ND
ND
25-May-05
NR
10
ND
22.0
ND
ND
ND
1-Nov-05
NR
10
ND
31.0
ND
ND
ND
23-May-06
NR
10
ND
32.8
ND
ND
ND
1-Nov-06
NR
10
ND
31.5
ND
ND
ND
29-May-07
NR
10
4.4
J
21.8
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
27-Nov-07
NR
10
8.2
J
40.1
5.4
J
ND
ND
27-May-08
2.7
10.0
7.8
J
16.8
ND
ND
ND
4-Nov-08
2.7
10.0
8.4
B
18.5
B 4.2
B
ND
4.8 J
1-Jun-09
2.7
10.0
33.5
Dry
5.1
J
ND
ND
19-Nov-09
2.7
10.0
19.1
16.3
ND
ND
ND
NC 2L = 10 pg/L (01/01/10)
14-Jun-10
2.7
10.0
3.0
J
26.5
3.5
J
ND
ND
29-Nov-10
2.7
10.0
4.0
J
30.7
3.8
J
ND
ND
31-May-11
2.7
10.0
3.1
J
34.4
5.5
J
ND
ND
19-Dec-11
5.0
10.0
6.5
J
30.7
ND
ND
ND
30-May-12
5.0
10.0
5.3
J
22.0
ND
ND
ND
3-Dec-12
5.0
10.0
8.2
J
35.8
9.8
J
ND
ND
10-Jun-13
5.0
10.0
ND
14.0
ND
ND
ND
28-Oct-13
5.0
10.0
ND
34.0
ND
ND
ND
5-May-14
5.0
10.0
ND
32.7
ND
ND
ND
20-Oct-14
5.0
10.0
ND
39.7
ND
ND
ND
18-May-15
2.5
10.0
ND
30.4
3.5
J
3.2 J
ND
7-Dec-15
2.5
10.0
9.9
J
28.4
4.3
J
ND
ND
2-May-16
2.5
10.0
ND
24.1
6.5
J
ND
ND
12-Dec-16
2.5
10.0
ND
26.3
5.4
J
3.8 J
ND
26-Jun-17
5.0
10.0
6.1
J
35.4
8.8
J
5.1 J
ND
14-Dec-17
5.0
10.0
7.1
J
25.5
ND
ND
ND
14-May-18
5.0
10.0
10.8
24.4
8.9
J
ND
ND
6-May-19
5.0
10.0
5
J
20.4
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 1 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Barium
28-Apr-94
NR
100
ND
ND
ND
NI
ND
2-May-00
NR
500
ND
ND
ND
NI
ND
8-Nov-00
NR
500
ND
ND
ND
NI
ND
31-May-01
NR
500
ND
ND
ND
NI
ND
6-Nov-01
NR
500
ND
ND
ND
NI
ND
21-May-02
NR
500
ND
ND
ND
NI
ND
13-Nov-02
NR
500
ND
ND
ND
NI
ND
13-May-03
NR
500
ND
ND
ND
NI
ND
18-Nov-03
NR
500
ND
ND
ND
ND
ND
4-May-04
NR
500
ND
ND
ND
ND
ND
9-Nov-04
NR
500
ND
ND
ND
ND
ND
25-May-05
NR
500
ND
ND
ND
ND
ND
1-Nov-05
NR
500
ND
ND
ND
ND
ND
23-May-06
NR
500
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
100
74.6
J
70.6
J 109
60.4 J
ND
NC 2L = 2,000 pg/L (10/23/07)
27-Nov-07
NR
100
71.5
J
63.9
J 110
45.5 J
0.30
J
27-May-08
0.2
100
65.6
J
64.0
J 92.4
J
35.6 J
0.41
J
4-Nov-08
0.20
100
57.3
J
60.9
J 93.0
J
34.1 B
10.5
J
1-Jun-09
0.20
100
62.0
B
Dry
81.8
J
32.3 B
15.2
J
19-Nov-09
0.20
100
57.7
B
149
90.5
B
30.1 B
19.8
J
NC 2L = 700 pg/L (01/01/10)
14-Jun-10
0.20
100
66.3
J
85.9
J 101
60.2 J
0.58
J
29-Nov-10
0.20
100
67.2
J
76.7
J 111
46.6 J
ND
31-May-11
0.20
100
67.0
J
66.8
J 96.2
J
41.7 J
ND
19-Dec-11
5.0
100
86.3
J
81.3
J 103
39.5 J
ND
30-May-12
5.0
100
70.7
J
61.2
J 92.7
J
39.4 J
ND
3-Dec-12
5.0
100
65.2
J
54.2
J 111
27.7 J
ND
10-Jun-13
5.0
100
69.8
J
125
93.9
J
25.6 B
13.7
J
28-Oct-13
5.0
100
66.4
J
101
71.5
J
45.5 J
ND
5-May-14
5.0
100
65.3
J
68.9
J 110
42.2 J
ND
20-Oct-14
5.0
100
62.1
J
56.5
J 116
47.6 J
ND
18-May-15
2.5
100
65.0
J
49.7
J 98.6
J
43.4 J
ND
7-Dec-15
2.5
100
74.5
J
63.0
J 114
38.7 J
ND
2-May-16
2.5
100
62.8
J
80.4
J 111
45.0 J
ND
12-Dec-16
2.5
100
65.3
J
48.4
J 119
47.8 J
ND
26-Jun-17
2.5
100
65.5
J
62.5
J 136
53.4 J
2.5
J
14-Dec-17
2.5
100
60.2
J
52.0
J 120
37.6 J
ND
14-May-18
2.5
100
63.3
J
49.2
J 124
42.6 J
ND
6-May-19
2.5
5
56.3
40.6
113
50.8
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 2 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Beryllium
19-Oct-99
NR
2
ND
ND
ND
NI
ND
2-May-00
NR
2
ND
ND
ND
NI
ND
8-Nov-00
NR
2
ND
ND
ND
NI
NA
31-May-01
NR
2
ND
ND
ND
NI
ND
6-Nov-01
NR
2
ND
ND
ND
NI
ND
21-May-02
NR
2
ND
ND
ND
NI
ND
13-Nov-02
NR
2
2.3
3.4
3.7
NI
ND
13-May-03
NR
2
ND
ND
ND
NI
ND
18-Nov-03
NR
2
ND
ND
ND
ND
ND
4-May-04
NR
2
ND
ND
ND
ND
ND
9-Nov-04
NR
2
ND
ND
ND
ND
ND
25-May-05
NR
2
ND
ND
ND
ND
ND
1-Nov-05
NR
2
ND
ND
ND
ND
ND
23-May-06
NR
2
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
1
ND
ND
ND
ND
ND
GWPS = 4 pg/L (10/23/07)
27-Nov-07
NR
1
ND
ND
ND
ND
ND
27-May-08
0.1
1.0
0.11 J
0.11
J 0.26
J ND
ND
4-Nov-08
0.10
1.0
0.12 J
0.29
J 0.24
J ND
ND
1-Jun-09
0.10
1.0
ND
Dry
0.17
J ND
ND
19-Nov-09
0.10
1.0
ND
0.41
J 0.22
J ND
ND
14-Jun-10
0.10
1.0
ND
0.18
J 0.15
J ND
ND
29-Nov-10
0.10
1.0
ND
ND
ND
ND
ND
31-May-11
0.10
1.0
0.27 J
0.18
J 0.25
J ND
ND
19-Dec-11
1.0
1.0
ND
ND
ND
ND
ND
30-May-12
1.0
1.0
ND
ND
ND
ND
ND
3-Dec-12
1.0
1.0
ND
ND
ND
ND
ND
10-Jun-13
1.0
1.0
ND
ND
ND
ND
ND
28-Oct-13
1.0
1.0
ND
ND
ND
ND
ND
5-May-14
1.0
1.0
ND
ND
ND
ND
ND
20-Oct-14
1.0
1.0
ND
ND
ND
ND
ND
18-May-15
0.5
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.5
1.0
ND
0.54
J ND
ND
ND
2-May-16
0.5
1.0
ND
ND
ND
ND
ND
12-Dec-16
0.5
1.0
ND
ND
ND
ND
ND
26-Jun-17
0.5
1.0
ND
0.5
J 0.57
J ND
ND
14-Dec-17
0.5
1.0
ND
ND
ND
ND
ND
14-May-18
0.5
1.0
ND
ND
ND
ND
ND
6-May-19
0.5
1.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 3 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
Cadmium
28-Apr-94
NR 1
18.0
ND ND NI
ND
2-May-00
NR 1
ND
1.0 J ND NI
ND
8-Nov-00
NR 1
ND
2.0 ND NI
ND
31-May-01
NR 1
ND
3.0 J 1.0 J NI
ND
6-Nov-01
NR 1
ND
1.4 ND NI
ND
21-May-02
NR 1
1.1
1.6 1.7 NI
ND
13-Nov-02
NR 1
1.4
2.3 2.4 NI
ND
13-May-03
NR 1
1.4
1.4 1.2 NI
ND
18-Nov-03
NR 1
ND
ND 1.7 ND
ND
4-May-04
NR 1
ND
ND 1.8 ND
ND
9-Nov-04
NR 1
ND
2.6 1.6 ND
ND
25-May-05
NR 1
ND
ND ND ND
ND
1-Nov-05
NR 1
ND
ND ND ND
ND
23-May-06
NR 1
ND
ND ND ND
ND
1-Nov-06
NR 10
ND
ND ND ND
ND
29-May-07
NR 1
ND
ND ND ND
ND
NC 2L = 1.75 pg/L (10/23/07)
27-Nov-07
NR 1
ND
ND ND ND
ND
27-May-08
0.5 1.0
ND
ND ND ND
ND
4-Nov-08
0.50 1.0
ND
ND ND ND
ND
1-Jun-09
0.50 1.0
ND
Dry ND ND
ND
19-Nov-09
0.50 1.0
ND
ND ND ND
ND
NC 2L = 2 pg/L (01/01/10)
14-Jun-10
0.50 1.0
ND
ND ND ND
ND
29-Nov-10
0.50 1.0
ND
ND ND ND
ND
31-May-11
0.50 1.0
ND
0.55 J ND ND
ND
19-Dec-11
1.0 1.0
ND
ND ND ND
ND
30-May-12
1.0 1.0
ND
ND ND ND
ND
3-Dec-12
1.0 1.0
ND
ND ND ND
ND
10-Jun-13
1.0 1.0
ND
ND ND ND
ND
28-Oct-13
1.0 1.0
ND
ND ND ND
ND
5-May-14
1.0 1.0
ND
ND ND ND
ND
20-Oct-14
1.0 1.0
ND
ND ND ND
ND
18-May-15
0.5 1.0
ND
ND ND ND
ND
7-Dec-15
0.5 1.0
ND
ND ND ND
ND
2-May-16
0.5 1.0
ND
ND ND ND
ND
12-Dec-16
0.5 1.0
ND
ND ND ND
ND
26-Jun-17
0.5 1.0
ND
ND ND ND
ND
14-Dec-17
0.5 1.0
ND
ND ND ND
ND
14-May-18
0.5 1.0
ND
ND ND ND
ND
6-May-19
0.5 1.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 4 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Chromium
28-Apr-94
NR
20
ND
ND
ND
NI
ND
2-May-00
NR
10
ND
ND
ND
NI
ND
8-Nov-00
NR
10
ND
ND
ND
NI
ND
31-May-01
NR
10
ND
ND
ND
NI
ND
6-Nov-01
NR
10
ND
ND
ND
NI
ND
21-May-02
NR
10
ND
ND
ND
NI
ND
13-Nov-02
NR
10
ND
ND
ND
NI
ND
13-May-03
NR
10
ND
ND
ND
NI
ND
18-Nov-03
NR
10
ND
ND
ND
ND
ND
4-May-04
NR
10
ND
ND
ND
ND
ND
9-Nov-04
NR
10
ND
ND
ND
ND
ND
25-May-05
NR
10
ND
ND
ND
ND
ND
1-Nov-05
NR
10
ND
ND
ND
ND
ND
23-May-06
NR
10
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
10
ND
ND
ND
ND
ND
NC 2L = 50 pg/L (10/23/07)
27-Nov-07
NR
10
ND
ND
ND
ND
ND
27-May-08
0.4
10.0
ND
0.66
B
ND
1.0 B
0.85 J
4-Nov-08
0.40
10.0
0.68
J
1.4
J
ND
1.4 J
ND
1-Jun-09
0.40
10.0
ND
Dry
ND
1.3 J
ND
19-Nov-09
0.40
10.0
ND
6.3
J
ND
ND
1.1 J
NC 2L = 10 pg/L (01/01/10)
14-Jun-10
0.40
10.0
0.97
J
1.3
J
ND
2.5 J
ND
29-Nov-10
0.40
10.0
1.7
J
ND
ND
1.0 J
ND
31-May-11
0.40
10.0
2.3
B
1.4
B
6.2
J 1.8 B
0.73 J
19-Dec-11
5.00
10.0
11.5
5.3
J
ND
7.7 J
ND
30-May-12
5.00
10.0
ND
ND
ND
7.9 J
ND
3-Dec-12
5.00
10.0
ND
ND
ND
ND
ND
10-Jun-13
5.0
10.0
ND
ND
ND
ND
ND
28-Oct-13
5.0
10.0
ND
ND
ND
ND
ND
5-May-14
5.0
10.0
ND
ND
ND
ND
ND
20-Oct-14
5.0
10.0
ND
ND
ND
ND
ND
18-May-15
2.5
10.0
ND
ND
ND
ND
ND
7-Dec-15
2.5
10.0
3.8
J
9.5
J
ND
ND
ND
2-May-16
2.5
10.0
2.5
J
ND
ND
ND
ND
12-Dec-16
2.5
10.0
ND
ND
ND
3 J
ND
26-Jun-17
2.5
10.0
ND
3.6
J
ND
ND
ND
14-Dec-17
2.5
10.0
ND
ND
ND
3.9 J
ND
14-May-18
2.5
10.0
ND
ND
ND
ND
ND
6-May-19
2.5
5.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 5 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Cobalt
28-Apr-94
NR
20
ND
ND
ND
NI
ND
2-May-00
NR
10
ND
54.0
ND
NI
ND
8-Nov-00
NR
10
ND
40.0
26.0
NI
ND
31-May-01
NR
10
44.0
27.0
40.0
NI
ND
6-Nov-01
NR
10
ND
22.0
41.0
NI
ND
21-May-02
NR
10
18.0
19.0
51.0
NI
NA
13-Nov-02
NR
10
10.0
19.0
48.0
NI
ND
13-May-03
NR
10
67.0
44.0
47.0
NI
ND
18-Nov-03
NR
10
29.0
120
45.0
ND
ND
4-May-04
NR
10
21.0
110
35.0
ND
ND
9-Nov-04
NR
10
22.0
110
36.0
ND
ND
25-May-05
NR
10
23.0
120
32.0
ND
ND
1-Nov-05
NR
10
17.0
120
34.0
ND
ND
23-May-06
NR
10
14.6
116
31.3
ND
ND
6-Nov-06
NR
10
14.8
104
32.0
ND
ND
29-May-07
NR
10
17.3
79.0
30.1
2.9 J
ND
GWPS = 70 pg/L (10/23/07)
27-Nov-07
NR
10
11.6
84.4
32.2
3.0 J
ND
27-May-08
0.6
10.0
8.9
J
8.1 J
16.5
ND
ND
4-Nov-08
0.6
10.0
15.5
B
20.5
26.1
4.5 B
3.5 J
1-Jun-09
0.60
10.0
36.1
Dry
29.8
6.0 B
3.3 J
19-Nov-09
0.60
10.0
19.6
39.8
23.5
1.4 J
ND
14-Jun-10
0.60
10.0
20.1
160
31.1
4.0 J
ND
GWPS = 1 pg/L (10/1/10)
29-Nov-10
0.60
10.0
10.2
156
37.7
5.4 J
ND
31-May-11
0.60
10.0
12.2
111
27.1
ND
ND
19-Dec-11
5.0
10.0
14.7
75.7
24.8
ND
ND
30-May-12
5.0
10.0
23.5
78.4
26.2
ND
ND
3-Dec-12
5.0
10.0
27.5
124
34.9
ND
ND
10-Jun-13
5.0
10.0
19.5
58.9
29.8
ND
ND
28-Oct-13
5.0
10.0
14.6
178
14.0
6.6 J
ND
5-May-14
5.0
10.0
9.7
J
115
24.8
ND
ND
20-Oct-14
5.0
10.0
8.6
J
144
25.3
ND
ND
18-May-15
2.5
10.0
10.3
95.3
23.5
ND
ND
7-Dec-15
2.5
10.0
16.3
88.6
26.1
ND
ND
2-May-16
2.5
10.0
10.4
128
25.6
ND
ND
12-Dec-16
2.5
10.0
9.3
J
94.0
24.1
ND
ND
26-Jun-17
2.5
10.0
13.9
110
26.3
ND
ND
14-Dec-17
2.5
10.0
15.8
102
24.3
ND
ND
14-May-18
2.5
10.0
17.9
84.7
21.0
ND
ND
6-May-19
2.5
5.0
10.6
74.7
27.2
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 6 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Copper
28-Apr-94
NR
10
ND
ND
ND
NI
ND
2-May-00
NR
200
ND
ND
ND
NI
ND
8-Nov-00
NR
200
ND
ND
ND
NI
ND
31-May-01
NR
200
ND
ND
ND
NI
ND
6-Nov-01
NR
200
ND
ND
ND
NI
ND
21-May-02
NR
200
ND
ND
ND
NI
ND
13-Nov-02
NR
200
ND
ND
ND
NI
ND
13-May-03
NR
200
ND
ND
ND
NI
ND
18-Nov-03
NR
200
ND
ND
ND
ND
ND
4-May-04
NR
200
ND
ND
ND
ND
ND
9-Nov-04
NR
200
ND
ND
ND
ND
ND
25-May-05
NR
200
ND
ND
ND
ND
ND
1-Nov-05
NR
200
ND
ND
ND
ND
ND
23-May-06
NR
200
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
10
ND
ND
ND
ND
ND
NC 2L = 1,000 pg/L (10/23/07)
27-Nov-07
NR
10
ND
ND
ND
ND
ND
27-May-08
0.3
10.0
ND
3.0
J
ND
ND
ND
4-Nov-08
0.30
10.0
ND
2.2
B
ND
ND
0.94 J
1-Jun-09
0.30
10.0
0.36
J
Dry
ND
ND
ND
19-Nov-09
0.30
10.0
0.31
J
3.9
J
ND
ND
ND
14-Jun-10
0.30
10.0
0.99
B
6.1
B
ND
ND
3.4 J
29-Nov-10
0.30
10.0
0.80
J
2.9
J
ND
ND
ND
31-May-11
0.30
10.0
ND
0.63
J
ND
ND
ND
19-Dec-11
5.0
10.0
5.2
J
ND
ND
ND
ND
30-May-12
5.0
10.0
ND
ND
ND
ND
ND
3-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
10-Jun-13
5.0
10.0
ND
ND
ND
ND
10.8
28-Oct-13
5.0
10.0
ND
11
ND
ND
ND
5-May-14
5.0
10.0
ND
ND
ND
ND
ND
20-Oct-14
5.0
10.0
ND
ND
ND
ND
ND
18-May-15
2.5
10.0
ND
ND
ND
ND
ND
7-Dec-15
2.5
10.0
ND
8.5
J
ND
ND
ND
2-May-16
2.5
10.0
ND
4.6
J
ND
ND
ND
12-Dec-16
2.5
10.0
ND
ND
ND
ND
ND
26-Jun-17
2.5
10.0
ND
ND
ND
ND
ND
14-Dec-17
2.5
10.0
2.9
J
ND
ND
ND
ND
14-May-18
2.5
10.0
ND
3.0
J
ND
ND
ND
6-May-19
2.5
5.0
ND
3.2
J
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 7 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
Lead
28-Apr-94
NR 1
21.0
3.0 4.0 NI
ND
2-May-00
NR 10
ND
ND ND NI
ND
8-Nov-00
NR 10
ND
ND ND NI
ND
31-May-01
NR 10
ND
ND ND NI
ND
6-Nov-01
NR 10
ND
ND ND NI
ND
21-May-02
NR 10
ND
ND ND NI
ND
13-Nov-02
NR 10
ND
10.0 ND NI
ND
13-May-03
NR 10
ND
ND ND NI
ND
18-Nov-03
NR 10
ND
ND ND ND
ND
4-May-04
NR 10
ND
ND ND ND
ND
9-Nov-04
NR 10
ND
ND ND ND
ND
25-May-05
NR 10
ND
ND ND ND
ND
1-Nov-05
NR 10
ND
ND ND ND
ND
23-May-06
NR 10
ND
ND ND ND
ND
1-Nov-06
NR 10
ND
ND ND ND
ND
29-May-07
NR 10
ND
2.5 B 6.9 B 3.9 B
6.1 J
NC 2L = 15 pg/L (10/23/07)
27-Nov-07
NR 10
ND
ND ND ND
ND
27-May-08
4 10.0
ND
ND ND ND
ND
4-Nov-08
4.0 10.0
ND
ND ND ND
ND
1-Jun-09
4.0 10.0
ND
Dry ND ND
ND
19-Nov-09
4.0 10.0
ND
ND ND ND
ND
14-Jun-10
4.0 10.0
ND
ND ND ND
ND
29-Nov-10
4.0 10.0
ND
ND ND ND
ND
31-May-11
4.0 10.0
ND
ND ND ND
ND
19-Dec-11
5.0 10.0
6.2 J
ND ND ND
ND
30-May-12
5.0 10.0
ND
ND ND ND
ND
3-Dec-12
5.0 10.0
ND
ND ND ND
ND
10-Jun-13
5.0 10.0
ND
ND ND ND
ND
28-Oct-13
5.0 10.0
ND
ND ND ND
ND
5-May-14
5.0 10.0
ND
ND ND ND
ND
20-Oct-14
5.0 10.0
ND
ND ND ND
ND
18-May-15
2.5 10.0
ND
ND ND ND
ND
7-Dec-15
2.5 10.0
ND
6.6 J ND ND
ND
2-May-16
2.5 10.0
ND
ND ND ND
ND
12-Dec-16
2.5 10.0
ND
ND ND ND
ND
26-Jun-17
2.5 10.0
ND
3.0 J ND ND
ND
14-Dec-17
2.5 10.0
ND
ND ND ND
ND
14-May-18
2.5 10.0
ND
ND ND ND
ND
6-May-19
2.5 5.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 8 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Nickel
28-Apr-94
NR
50
ND
ND
ND
NI
ND
2-May-00
NR
50
ND
ND
ND
NI
ND
8-Nov-00
NR
50
ND
ND
ND
NI
ND
31-May-01
NR
50
ND
ND
ND
NI
ND
6-Nov-01
NR
50
ND
ND
ND
NI
ND
21-May-02
NR
50
60.0
ND
ND
NI
ND
13-Nov-02
NR
50
ND
ND
ND
NI
ND
13-May-03
NR
50
ND
ND
ND
NI
ND
18-Nov-03
NR
50
ND
110
ND
ND
ND
4-May-04
NR
50
ND
99
ND
ND
ND
9-Nov-04
NR
50
ND
110
ND
ND
ND
25-May-05
NR
50
ND
100
ND
ND
ND
1-Nov-05
NR
50
ND
110
ND
ND
ND
23-May-06
NR
50
ND
103
ND
ND
ND
6-Nov-06
NR
50
ND
92.6
ND
ND
ND
29-May-07
NR
50
11.5
J
78.3
7.7
J
ND
ND
NC 2L = 100 pg/L (10/23/07)
27-Nov-07
NR
50
7.7
J
66.4
7.2
J
ND
ND
27-May-08
1.7
50.0
12.1
J
24.3 J
7.4
J
ND
ND
4-Nov-08
1.7
50.0
16.5
J
19.2 J
9.1
B
2.2 B
2.2 J
1-Jun-09
1.7
50.0
14.9
J
Dry
6.1
J
ND
ND
19-Nov-09
1.7
50.0
13.2
J
39.9 J
7.7
B
ND
2.2 J
14-Jun-10
1.7
50.0
8.6
J
157
6.3
J
ND
ND
29-Nov-10
1.7
50.0
7.3
J
133
7.2
J
ND
ND
31-May-11
1.7
50.0
9.1
B
116
9.6
B
ND
2.3 J
19-Dec-11
5.0
50.0
10.9
J
85.8
6.8
J
ND
ND
30-May-12
5.0
50.0
9.9
J
57.4
5.8
J
ND
ND
3-Dec-12
5.0
50.0
8.0
J
63.3
6.7
J
ND
ND
10-Jun-13
5.0
50.0
8.1
J
40.9 J
6.5
J
ND
ND
28-Oct-13
5.0
50.0
ND
161
ND
ND
ND
5-May-14
5.0
50.0
ND
124
6.8
J
ND
ND
20-Oct-14
5.0
50.0
ND
132
7.5
J
ND
ND
18-May-15
2.5
50.0
5.1
J
88.2
7.9
J
ND
ND
7-Dec-15
2.5
50.0
8.8
J
75.2
8.9
J
ND
ND
2-May-16
2.5
50.0
5.6
J
122
8.4
J
ND
ND
12-Dec-16
2.5
50.0
4.3
J
92.5
8.5
J
ND
ND
26-Jun-17
2.5
50.0
6.0
J
98.8
8.2
J
ND
ND
14-Dec-17
2.5
50.0
8.1
J
84.0
9.4
J
ND
ND
14-May-18
2.5
50.0
7.2
J
64.3
6.2
J
ND
ND
6-May-19
2.5
5.0
5.5
62.0
9.7
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 9 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
Selenium
19-Oct-99
NR 20
ND
ND ND NI
NA
2-May-00
NR 20
ND
ND ND NI
ND
8-Nov-00
NR 20
ND
ND ND NI
NA
31-May-01
NR 20
ND
ND ND NI
ND
6-Nov-01
NR 20
ND
ND ND NI
ND
21-May-02
NR 20
ND
ND ND NI
ND
13-Nov-02
NR 20
ND
ND ND NI
ND
1-Apr-03
NR 20
NA
NA NA ND
NA
13-May-03
NR 20
ND
ND ND NA
ND
18-Nov-03
NR 20
ND
ND ND ND
ND
4-May-04
NR 20
ND
ND ND ND
ND
9-Nov-04
NR 20
ND
ND ND ND
ND
25-May-05
NR 20
ND
ND ND ND
ND
1-Nov-05
NR 20
ND
ND ND ND
ND
29-May-07
NR 10
ND
ND ND ND
ND
NC 2L = 50 pg/L (10/23/07)
27-Nov-07
NR 10
ND
ND ND ND
2.4 J
27-May-08
3.8 10.0
ND
ND ND ND
ND
4-Nov-08
3.8 10.0
ND
7.2 B 5.7 B ND
4.2 J
1-Jun-09
3.8 10.0
ND
Dry 5.0 J ND
ND
19-Nov-09
3.8 10.0
ND
ND ND ND
ND
NC 2L = 20 pg/L (01/01/10)
14-Jun-10
3.8 10.0
ND
ND ND ND
ND
29-Nov-10
3.8 10.0
ND
ND ND ND
ND
31-May-11
3.8 10.0
ND
ND ND ND
ND
19-Dec-11
10.0 10.0
ND
ND ND ND
ND
30-May-12
10.0 10.0
ND
ND ND ND
ND
3-Dec-12
10.0 10.0
ND
ND ND ND
ND
10-Jun-13
10.0 10.0
ND
ND ND ND
ND
28-Oct-13
10.0 10.0
ND
ND ND ND
ND
5-May-14
10.0 10.0
ND
ND ND ND
ND
20-Oct-14
10.0 10.0
ND
ND ND ND
ND
18-May-15
5.0 10.0
ND
ND ND ND
ND
7-Dec-15
5.0 10.0
ND
ND ND ND
ND
2-May-16
5.0 10.0
ND
ND ND ND
ND
12-Dec-16
5.0 10.0
ND
ND ND ND
ND
26-Jun-17
5.0 10.0
ND
ND ND ND
ND
14-Dec-17
5.0 10.0
ND
ND ND ND
ND
14-May-18
5.0 10.0
ND
ND ND ND
ND
6-May-19
5.0 10.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 10 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Silver
19-Oct-99
NR
10
ND
ND
ND
NI
ND
2-May-00
NR
10
ND
ND
ND
NI
ND
8-Nov-00
NR
10
ND
ND
ND
NI
NA
31-May-01
NR
10
ND
ND
ND
NI
ND
6-Nov-01
NR
10
ND
ND
ND
NI
ND
21-May-02
NR
10
ND
ND
ND
NI
15.0
13-Nov-02
NR
10
ND
ND
ND
NI
ND
13-May-03
NR
10
ND
ND
ND
NI
ND
18-Nov-03
NR
10
ND
ND
ND
ND
ND
4-May-04
NR
10
ND
ND
ND
ND
ND
9-Nov-04
NR
10
ND
ND
ND
ND
ND
25-May-05
NR
10
ND
ND
ND
ND
ND
1-Nov-05
NR
10
ND
ND
ND
ND
ND
23-May-06
NR
10
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
10
ND
ND
ND
ND
ND
NC 2L = 17.5 pg/L (10/23/07)
27-Nov-07
NR
10
ND
ND
ND
ND
ND
27-May-08
0.1
10.0
ND
ND
0.30
B
ND
0.14 J
4-Nov-08
0.10
10.0
0.19
B
0.31
B 0.76
B
0.18 B
0.20 J
1-Jun-09
0.10
10.0
0.18
J
Dry
0.45
J
ND
ND
19-Nov-09
0.10
10.0
0.22
J
0.34
J 0.42
J
0.16 J
ND
NC 2L = 20 pg/L (01/01/10)
14-Jun-10
0.10
10.0
ND
ND
ND
ND
ND
29-Nov-10
0.10
10.0
ND
ND
ND
ND
ND
31-May-11
0.10
10.0
0.18
J
0.14
J ND
0.31 J
ND
19-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
30-May-12
5.0
10.0
ND
ND
ND
ND
ND
3-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
10-Jun-13
5.0
10.0
ND
ND
ND
ND
ND
28-Oct-13
5.0
10.0
ND
ND
ND
ND
ND
5-May-14
5.0
10.0
ND
ND
ND
ND
ND
20-Oct-14
5.0
10.0
ND
ND
ND
ND
ND
18-May-15
2.5
10.0
ND
ND
ND
ND
ND
7-Dec-15
2.5
10.0
ND
ND
ND
ND
ND
2-May-16
2.5
10.0
ND
ND
ND
ND
ND
12-Dec-16
2.5
10.0
ND
ND
ND
ND
ND
26-Jun-17
2.5
10.0
ND
ND
ND
ND
ND
14-Dec-17
2.5
10.0
ND
ND
ND
ND
ND
14-May-18
2.5
10.0
ND
ND
ND
ND
ND
6-May-19
2.5
5.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 11 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Thallium
28-Apr-94
NR
1
ND
ND
ND
NI
ND
2-May-00
NR
10
ND
ND
ND
NI
ND
8-Nov-00
NR
10
ND
ND
ND
NI
ND
31-May-01
NR
10
ND
ND
ND
NI
ND
6-Nov-01
NR
10
ND
ND
ND
NI
ND
21-May-02
NR
10
ND
ND
ND
NI
ND
13-Nov-02
NR
10
ND
ND
ND
NI
ND
13-May-03
NR
10
ND
ND
ND
NI
ND
18-Nov-03
NR
10
ND
ND
ND
ND
ND
4-May-04
NR
10
ND
ND
ND
ND
ND
9-Nov-04
NR
10
ND
ND
ND
ND
ND
25-May-05
NR
10
ND
ND
12.0
ND
ND
1-Nov-05
NR
10
ND
12.0
14.0
ND
ND
23-May-06
NR
10
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
5.5
0.167
J
0.525
J 0.625
J 0.053 J
ND
GWPS = 0.28 pg/L (10/23/07)
27-Nov-07
NR
5.5
0.422
J
0.475
J 0.593
J 0.073 J
ND
27-May-08
3
5.5
ND
ND
ND
ND
ND
4-Nov-08
3.0
5.5
ND
ND
ND
ND
ND
1-Jun-09
3.0
5.5
ND
Dry
ND
ND
ND
19-Nov-09
3.0
5.5
ND
ND
ND
ND
ND
14-Jun-10
3.0
5.5
3.8
J
5.3
J 4.1
J ND
ND
GWPS = 0.28 pg/L (10/1/10)
29-Nov-10
3.0
5.5
ND
ND
ND
ND
ND
31-May-11
3.0
5.5
ND
ND
ND
ND
ND
19-Dec-11
5.4
5.5
ND
ND
ND
ND
ND
30-May-12
5.4
5.5
ND
ND
ND
ND
ND
3-Dec-12
5.4
5.5
7.6
ND
ND
ND
ND
10-Jun-13
5.4
5.5
ND
ND
ND
ND
ND
28-Oct-13
5.4
5.5
ND
ND
ND
ND
ND
5-May-14
5.4
5.5
ND
ND
ND
ND
ND
20-Oct-14
5.4
5.5
ND
ND
ND
ND
ND
18-May-15
5.0
5.5
ND
ND
ND
ND
ND
7-Dec-15
5.0
5.5
ND
ND
ND
ND
ND
2-May-16
5.0
5.5
ND
ND
ND
ND
ND
12-Dec-16
5.0
5.5
ND
ND
ND
ND
5.5 J
26-Jun-17
5.0
5.5
0.083
J
0.57
J 1.4
J 0.034 J
ND
14-Dec-17
0.03
0.10
0.10
0.54
1.4
0.040 J
14-May-18
0.50
5.5
ND
ND
1.2
J ND
ND
6-May-19
0.06
0.1
0.13
0.42
0.91
0.17
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 12 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Vanadium
28-Apr-94
NR
80
ND
ND
ND
NI
ND
2-May-00
NR
40
ND
ND
ND
NI
ND
8-Nov-00
NR
40
ND
ND
ND
NI
ND
31-May-01
NR
40
ND
ND
ND
NI
ND
6-Nov-01
NR
40
ND
ND
ND
NI
ND
21-May-02
NR
40
ND
ND
ND
NI
ND
13-Nov-02
NR
40
ND
ND
ND
NI
ND
13-May-03
NR
40
ND
ND
ND
NI
ND
18-Nov-03
NR
40
ND
ND
ND
ND
ND
4-May-04
NR
40
ND
ND
ND
ND
ND
9-Nov-04
NR
40
ND
ND
ND
ND
ND
25-May-05
NR
40
ND
ND
ND
ND
ND
1-Nov-05
NR
40
ND
ND
ND
ND
ND
23-May-06
NR
40
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
25
ND
ND
ND
ND
ND
GWPS = 3.5 pg/L (10/23/07)
27-Nov-07
NR
25
ND
ND
ND
ND
ND
27-May-08
0.2
25.0
0.90
B
4.5
J 1.0
B
0.93 B
0.22
J
4-Nov-08
0.20
25.0
1.4
B
4.5
J 0.62
B
1.4 B
0.85
J
1-Jun-09
0.20
25.0
0.99
B
Dry
0.93
B
2.1 B
1.2
J
19-Nov-09
0.20
25.0
0.81
B
9.1
J 0.96
B
1.4 B
0.58
J
14-Jun-10
0.20
25.0
0.85
B
1.7
J 1.0
B
1.8 J
0.25
J
GWPS = 0.3 pg/L (10/1/10)
29-Nov-10
0.20
25.0
1.0
J
ND
ND
ND
ND
31-May-11
0.20
25.0
ND
ND
ND
1.4 J
ND
19-Dec-11
5.0
25.0
12.1
J
6.9
J ND
6.7 J
ND
30-May-12
5.0
25.0
ND
ND
ND
6.8 J
ND
3-Dec-12
5.0
25.0
ND
ND
ND
6.9 J
ND
10-Jun-13
5.0
25.0
ND
ND
ND
ND
ND
28-Oct-13
5.0
25.0
ND
ND
ND
ND
ND
5-May-14
5.0
25.0
ND
ND
ND
ND
ND
20-Oct-14
5.0
25.0
ND
ND
ND
ND
ND
18-May-15
2.5
25.0
ND
7.8
J 3.6
J
ND
ND
7-Dec-15
2.5
25.0
4.4
J
18.8
J 5.7
J
3.4 J
ND
2-May-16
2.5
25.0
ND
ND
ND
3.2 J
ND
12-Dec-16
2.5
25.0
ND
ND
ND
2.7 J
ND
26-Jun-17
2.5
25.0
ND
4.3
J ND
ND
ND
14-Dec-17
2.5
25.0
ND
ND
ND
ND
ND
14-May-18
2.5
25.0
ND
ND
ND
ND
ND
6-May-19
2.5
5.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 13 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Zinc
28-Apr-94
NR
10
ND
ND
ND
NI
ND
2-May-00
NR
50
ND
ND
ND
NI
ND
8-Nov-00
NR
50
ND
ND
ND
NI
ND
31-May-01
NR
50
ND
ND
ND
NI
ND
6-Nov-01
NR
50
ND
ND
ND
NI
ND
21-May-02
NR
50
ND
ND
ND
NI
ND
13-Nov-02
NR
50
ND
ND
ND
NI
ND
13-May-03
NR
50
ND
ND
ND
NI
ND
18-Nov-03
NR
50
ND
ND
ND
ND
ND
4-May-04
NR
50
ND
ND
ND
ND
ND
9-Nov-04
NR
50
ND
ND
ND
ND
ND
25-May-05
NR
50
ND
ND
ND
ND
ND
1-Nov-05
NR
50
ND
ND
ND
ND
ND
23-May-06
NR
50
ND
ND
ND
76.9
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
10
4.7
B
11.3
4.6
B
2.9 B
2.0
J
NC 2L = 1,050 pg/L (10/23/07)
27-Nov-07
NR
10
9.1
J
9.5
J
7.3
J
1.6 J
ND
27-May-08
0.4
10.0
2.6
J
8.6
B
6.4
B
ND
4.8
J
4-Nov-08
0.40
10.0
3.3
B
5.4
B
0.77
B
ND
8.9
J
1-Jun-09
0.40
10.0
8.7
B
Dry
6.5
B
7.0 B
83.0
19-Nov-09
0.40
10.0
6.0
B
14.0
B
5.0
B
4.2 B
3.5
J
NC 2L = 1,000 pg/L (01/01/10)
14-Jun-10
0.40
10.0
2.1
BB
17.4
B
20.1
B
ND
10.1
29-Nov-10
0.40
10.0
1.9
J
13.0
1.8
J
ND
ND
31-May-11
0.40
10.0
6.5
B
20.5
B
6.8
B
4.3 B
13.7
19-Dec-11
10.0
10.0
21.3
17.0
ND
10.3
ND
30-May-12
10.0
10.0
ND
ND
ND
ND
ND
3-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
10-Jun-13
10.0
10.0
ND
ND
ND
ND
76.3
28-Oct-13
10.0
10.0
ND
21.4
ND
ND
ND
5-May-14
10.0
10.0
ND
18.7
ND
ND
ND
20-Oct-14
10.0
10.0
ND
13.4
ND
ND
ND
18-May-15
5.0
10.0
ND
21.7
ND
ND
ND
7-Dec-15
5.0
10.0
7.8
B
16.7
B
6.3
B
ND
7.2
J
2-May-16
5.0
10.0
5.4
J
17.0
5.3
J
ND
ND
12-Dec-16
5.0
10.0
ND
9.7
J
6.0
J
9.0 J
ND
26-Jun-17
5.0
10.0
ND
11.1
5.1
J
6.4 J
ND
14-Dec-17
5.0
10.0
5.6
J
10.8
6.6
J
9.9 J
ND
14-May-18
5.0
10.0
13
15.4
5.6
J
ND
ND
6-May-19
5.0
10.0
ND
8.0
J
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 14 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
ORGANICS
Acetone
28-Apr-94
NR
100
ND
ND
ND
NI
ND
2-May-00
NR
100
ND
ND
ND
NI
ND
8-Nov-00
NR
100
ND
ND
ND
NI
ND
31-May-01
NR
100
ND
ND
ND
NI
ND
6-Nov-01
NR
100
ND
ND
ND
NI
ND
21-May-02
NR
100
ND
ND
ND
NI
ND
13-Nov-02
NR
100
ND
ND
ND
NI
ND
13-May-03
NR
100
210
ND
ND
NI
ND
18-Nov-03
NR
100
ND
ND
ND
ND
ND
4-May-04
NR
100
ND
ND
ND
ND
ND
9-Nov-04
NR
100
ND
ND
ND
ND
ND
25-May-05
NR
100
150
ND
ND
ND
ND
1-Nov-05
NR
100
ND
ND
ND
ND
ND
23-May-06
NR
100
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
100
ND
ND
ND
ND
ND
NC 2L = 700 pg/L (10/23/07)
27-Nov-07
NR
100
7.6
B
5.9
B
4.0
B
4.1 B
4.3
J
27-May-08
20
100
ND
ND
ND
ND
ND
4-Nov-08
20.0
100
ND
ND
ND
ND
ND
1-Jun-09
2.2
100
65.9
J
Dry
ND
ND
3.2
J
19-Nov-09
2.2
100
ND
2.8
B
3.8
B
21.9 B
3.8
J
NC 2L = 6,000 pg/L (01/01/10)
14-Jun-10
2.2
100
6.3
B
4.0
B
ND
ND
8.9
J
29-Nov-10
2.2
100
ND
ND
ND
ND
2.3
J
31-May-11
2.2
100
3.0
B
4.0
B
4.0
B
ND
3.9
J
19-Dec-11
2.2
100
ND
ND
ND
ND
6.6
J
30-May-12
2.2
100
ND
ND
ND
ND
ND
3-Dec-12
10.0
100
ND
ND
ND
ND
ND
10-Jun-13
10.0
100
ND
ND
ND
ND
ND
28-Oct-13
10.0
100
ND
11.4
J
ND
ND
ND
5-May-14
10.0
100
ND
ND
ND
ND
ND
20-Oct-14
10.0
100
ND
ND
ND
ND
ND
18-May-15
10.0
100
ND
ND
ND
ND
ND
7-Dec-15
10.0
100
ND
ND
ND
ND
ND
2-May-16
10.0
100
ND
ND
ND
ND
ND
12-Dec-16
10.0
100
ND
ND
ND
ND
ND
26-Jun-17
10.0
100
11.6
J
21.1
J
11
J
17.8 J
23
J
14-Dec-17
10.0
100
ND
ND
N
ND
ND
ND
14-May-18
10.0
100
ND
10.5
J
ND
ND
ND
6-May-19
8.2
25
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 15 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Benzene
28-Apr-94
NR
5
ND
6.1
ND
NI
ND
2-May-00
NR
5
ND
ND
ND
NI
ND
8-Nov-00
NR
5
ND
ND
ND
NI
ND
31-May-01
NR
5
ND
ND
ND
NI
ND
6-Nov-01
NR
5
ND
ND
ND
NI
ND
21-May-02
NR
5
ND
ND
ND
NI
ND
13-Nov-02
NR
5
ND
ND
ND
NI
ND
13-May-03
NR
5
ND
ND
ND
NI
ND
18-Nov-03
NR
5
ND
ND
ND
ND
ND
4-May-04
NR
5
ND
ND
ND
ND
ND
9-Nov-04
NR
5
ND
ND
ND
ND
ND
25-May-05
NR
5
ND
ND
ND
ND
ND
1-Nov-05
NR
5
ND
ND
ND
ND
ND
23-May-06
NR
5
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
1.0
1.0
2.0
0.9
J ND
ND
NC 2L = 1 pg/L (10/23/07)
27-Nov-07
NR
1
ND
ND
ND
ND
ND
27-May-08
0.25
1.0
0.83
J
2.0
0.74
J ND
ND
4-Nov-08
0.25
1.0
0.38
J
2.5
0.88
J ND
ND
1-Jun-09
0.25
1.0
0.92
J
Dry
0.74
J ND
ND
19-Nov-09
0.25
1.0
ND
ND
ND
1.1
ND
14-Jun-10
0.25
1.0
0.62
J
2.3
0.81
J ND
ND
29-Nov-10
0.25
1.0
ND
2.4
ND
ND
ND
31-May-11
0.25
1.0
0.62
J
2.1
0.75
J ND
ND
19-Dec-11
0.25
1.0
0.68
J
1.7
0.75
J ND
ND
30-May-12
0.25
1.0
0.81
J
1.6
0.68
J ND
ND
3-Dec-12
0.25
1.0
0.87
J
1.3
0.67
J ND
ND
10-Jun-13
0.25
1.0
0.79
J
2.0
0.75
J ND
ND
28-Oct-13
0.25
1.0
ND
1.1
0.70
J ND
ND
5-May-14
0.25
1.0
0.38
J
1.6
0.78
J ND
ND
20-Oct-14
0.25
1.0
0.36
J
1.3
0.62
J ND
ND
18-May-15
0.25
1.0
ND
0.80
J 0.50
J ND
ND
7-Dec-15
0.25
1.0
ND
0.76
J ND
ND
ND
2-May-16
0.25
1.0
0.33
J
0.89
J 0.65
J ND
ND
12-Dec-16
0.25
1.0
0.3
J
1.2
0.62
J ND
ND
26-Jun-17
0.25
1.0
0.34
J
0.94
J 0.65
J ND
ND
14-Dec-17
0.25
1.0
0.44
J
0.65
J 0.56
J ND
ND
14-May-18
0.25
1.0
0.28
J
0.90
J 0.49
J ND
ND
6-May-19
0.20
1.0
0.24
J
4.7
1.8
ND
ND
Resample >
24-Jul-19
0.15
1.0
0.95
J 0.63
J
Burke County -East Burke La Bella Associates
Permit No. 12-02 16 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
2-Butanone (MEK)
19-Nov-09
0.96 100
ND
ND ND 2.8 J
ND
NC 2L = 4,000 pg/L (01/01/10)
14-Jun-10
0.96 100
ND
ND ND ND
1.6 J
29-Nov-10
0.96 100
ND
ND ND ND
ND
31-May-11
0.96 100
ND
ND ND ND
ND
19-Dec-11
0.96 100
ND
ND ND ND
ND
30-May-12
0.96 100
ND
ND ND ND
ND
3-Dec-12
0.96 100
ND
ND ND ND
ND
10-Jun-13
0.96 100
ND
ND ND ND
ND
28-Oct-13
0.96 100
ND
ND ND ND
ND
5-May-14
0.96 100
ND
ND ND ND
ND
20-Oct-14
0.96 100
ND
ND ND ND
ND
18-May-15
0.96 100
ND
ND ND ND
ND
7-Dec-15
0.96 100
ND
ND ND ND
ND
2-May-16
0.96 100
ND
ND ND ND
ND
12-Dec-16
0.96 100
ND
ND ND ND
ND
26-Jun-17
0.96 100
ND
ND ND ND
ND
14-Dec-17
0.96 100
ND
ND ND ND
ND
14-May-18
0.96 100
ND
ND ND ND
ND
6-May-19
3.20 5
ND
ND ND ND
ND
Carbon Disulfide
12-May-99
NR 5
5.8
ND ND NI
ND
19-Oct-99
NR 100
ND
ND ND NI
ND
2-May-00
NR 100
ND
ND ND NI
ND
8-Nov-00
NR 100
ND
ND ND NI
ND
31-May-01
NR 100
ND
ND ND NI
ND
6-Nov-01
NR 100
ND
ND ND NI
ND
21-May-02
NR 100
ND
ND ND NI
ND
13-Nov-02
NR 100
ND
ND ND NI
ND
13-May-03
NR 100
ND
ND ND NI
ND
18-Nov-03
NR 100
ND
ND ND ND
ND
4-May-04
NR 100
ND
ND ND ND
ND
9-Nov-04
NR 100
ND
ND ND ND
ND
25-May-05
NR 100
ND
ND ND ND
ND
1-Nov-05
NR 100
ND
ND ND ND
ND
23-May-06
NR 100
ND
ND ND ND
ND
1-Nov-06
NR 10
ND
ND ND ND
ND
29-May-07
NR 100
ND
ND ND ND
ND
INC 2L = 700 pg/L (10/23/07)
27-Nov-07
NR 100
ND
ND ND ND
ND
27-May-08
1.2 100
ND
ND ND ND
ND
4-Nov-08
1.2 100
ND
ND ND ND
ND
1-Jun-09
1.2 100
ND
Dry ND ND
ND
19-Nov-09
1.2 100
ND
ND ND ND
ND
14-Jun-10
1.2 100
ND
ND ND ND
ND
29-Nov-10
1.2 100
ND
ND ND ND
ND
31-May-11
1.2 100
ND
ND ND ND
ND
19-Dec-11
1.2 100
ND
ND ND ND
ND
30-May-12
1.2 100
ND
ND ND ND
ND
3-Dec-12
1.2 100
ND
ND ND ND
ND
10-Jun-13
1.2 100
ND
ND ND ND
ND
28-Oct-13
1.2 100
ND
ND ND ND
ND
5-May-14
1.2 100
ND
ND ND ND
ND
20-Oct-14
1.2 100
ND
ND ND ND
ND
18-May-15
1.2 100
ND
ND ND ND
ND
7-Dec-15
1.2 100
ND
ND ND ND
ND
2-May-16
1.2 100
ND
ND ND ND
ND
12-Dec-16
1.2 100
ND
ND ND ND
ND
26-Jun-17
1.2 100
ND
ND ND ND
ND
14-Dec-17
1.2 100
ND
ND ND ND
ND
14-May-18
1.2 100
ND
ND ND ND
ND
6-May-19
0.8 10
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 17 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Chlorobenzene
29-May-07
NR
3
ND
0.73
J 0.76
J 0.24 J
ND
NC 2L = 50 pg/L (10/23/07)
27-Nov-07
NR
3
ND
ND
ND
ND
ND
27-May-08
0.23
3.0
ND
0.57
J 0.58
J ND
ND
4-Nov-08
0.23
3.0
ND
0.41
J 0.56
J ND
ND
1-Jun-09
0.23
3.0
ND
Dry
0.55
J ND
ND
19-Nov-09
0.23
3.0
ND
ND
ND
0.23 J
ND
14-Jun-10
0.23
3.0
ND
0.70
J 0.58
J ND
ND
29-Nov-10
0.23
3.0
ND
0.84
J ND
ND
ND
31-May-11
0.23
3.0
ND
0.65
J 0.63
J ND
ND
19-Dec-11
0.23
3.0
ND
0.59
J 0.65
J ND
ND
30-May-12
0.23
3.0
ND
0.42
J 0.68
J ND
ND
3-Dec-12
0.23
3.0
ND
0.32
J 0.60
J ND
ND
10-Jun-13
0.23
3.0
ND
0.43
J 0.60
J ND
ND
28-Oct-13
0.23
3.0
ND
0.50
J 0.64
J ND
ND
5-May-14
0.23
3.0
ND
0.73
J 0.72
J ND
ND
20-Oct-14
0.23
3.0
ND
0.67
J 0.70
J ND
ND
18-May-15
0.23
3.0
ND
ND
0.77
J ND
ND
7-Dec-15
0.23
3.0
ND
0.42
J 0.58
J ND
ND
2-May-16
0.23
3.0
ND
0.54
J 0.84
J ND
ND
12-Dec-16
0.23
3.0
ND
0.46
J 0.67
J ND
ND
26-Jun-17
0.23
3.0
ND
ND
ND
ND
ND
14-Dec-17
0.23
3.0
ND
0.37
J 0.73
J ND
ND
14-May-18
0.23
3.0
ND
0.26
J 0.72
J ND
ND
6-May-19
0.53
1.0
ND
35.50
8.90
ND
ND
Chloromethane
1-Jun-09
0.11
1.0
ND
Dry
0.21
J ND
ND
NC 2L = 2.6 pg/L (10/23/07)
19-Nov-09
0.11
1.0
ND
ND
ND
ND
ND
NC 2L = 3 pg/L (01/01/10)
14-Jun-10
0.11
1.0
ND
ND
ND
ND
0.12 J
29-Nov-10
0.11
1.0
ND
ND
ND
ND
ND
31-May-11
0.11
1.0
ND
ND
ND
ND
ND
19-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
30-May-12
0.11
1.0
ND
ND
ND
ND
ND
3-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
10-Jun-13
0.11
1.0
ND
ND
ND
ND
ND
28-Oct-13
0.11
1.0
ND
ND
ND
ND
ND
5-May-14
0.11
1.0
ND
ND
ND
ND
ND
20-Oct-14
0.11
1.0
ND
ND
ND
ND
ND
18-May-15
0.11
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.11
1.0
ND
ND
ND
ND
ND
2-May-16
0.11
1.0
ND
ND
ND
ND
ND
12-Dec-16
0.11
1.0
ND
ND
ND
ND
0.36 J
26-Jun-17
0.11
1.0
ND
ND
ND
ND
ND
14-Dec-17
0.11
1.0
ND
ND
ND
ND
ND
14-May-18
0.11
1.0
ND
ND
ND
ND
ND
6-May-19
0.38
1.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 18 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
1,2-Dichlorobenzene
28-Oct-13
5.00
30.0
ND
ND
ND
0.86 J
ND
NC 2L = 20 pg/L (01/01/10)
5-May-14
0.30
5.0
ND
ND
ND
ND
ND
20-Oct-14
0.30
5.0
ND
ND
ND
ND
ND
18-May-15
0.30
5.0
ND
ND
ND
ND
ND
NC 2L = 20 pg/L (01/01/10)
7-Dec-15
0.30
5.0
ND
ND
ND
ND
ND
2-May-16
0.30
5.0
ND
ND
ND
ND
ND
12-Dec-16
0.30
5.0
ND
ND
ND
ND
ND
26-Jun-17
0.30
5.0
ND
ND
ND
ND
ND
14-Dec-17
0.30
5.0
ND
ND
ND
ND
ND
14-May-18
0.30
5.0
ND
ND
ND
ND
ND
6-May-19
0.49
1.0
ND
0.88 J
ND
ND
ND
1,4-Dichlorobenzene
28-Apr-94
NR
5
ND
7.1
ND
NI
ND
2-May-00
NR
5
ND
10.0
5.2
NI
ND
8-Nov-00
NR
5
ND
9.9
5.9
NI
ND
31-May-01
NR
5
ND
ND
ND
NI
ND
6-Nov-01
NR
5
ND
ND
ND
NI
ND
21-May-02
NR
5
ND
8.2
6.4
NI
ND
13-Nov-02
NR
5
ND
7.6
ND
NI
ND
13-May-03
NR
5
5.0
5.5
ND
NI
ND
18-Nov-03
NR
5
ND
5.4
5.4
ND
ND
4-May-04
NR
5
ND
7.4
5.0
ND
ND
9-Nov-04
NR
5
ND
7.4
5.1
ND
ND
25-May-05
NR
5
ND
6.0
5.0
ND
ND
1-Nov-05
NR
5
ND
8.0
5.0
ND
ND
23-May-06
NR
5
ND
5.8
ND
ND
ND
6-Nov-06
NR
3
ND
6.7
5.5
ND
ND
29-May-07
NR
1
3.6
8.1
6.5
2.2
ND
NC 2L = 1.4 pg/L (10/23/07)
27-Nov-07
NR
1
2.7
7.2
5.5
ND
ND
27-May-08
0.33
1.0
2.5
8.2
4.7
1.0
ND
4-Nov-08
0.33
1.0
1.2
6.3
4.8
0.94 J
ND
1-Jun-09
0.33
1.0
3.4
Dry
4.6
1.2
ND
19-Nov-09
0.33
1.0
ND
ND
ND
3.7
ND
NC 2L = 6 pg/L (01/01/10)
14-Jun-10
0.33
1.0
1.7
2.4
4.6
1.2
ND
29-Nov-10
0.33
1.0
0.97
J
4.2
5.3
1.4
ND
31-May-11
0.33
1.0
1.4
5.6
4.8
0.96 J
ND
19-Dec-11
0.33
1.0
1.4
6.3
4.7
0.62 J
ND
30-May-12
0.33
1.0
1.9
5.0
4.3
0.73 J
ND
3-Dec-12
0.33
1.0
1.7
3.4
4.3
0.63 J
ND
10-Jun-13
0.33
1.0
1.5
4.1
4.1
0.77 J
ND
28-Oct-13
0.30
1.0
1.1
1.6
4.5
0.88 J
ND
5-May-14
0.33
1.0
0.89
J
4.7
4.7
0.78 J
ND
20-Oct-14
0.33
1.0
0.92
J
5.3
4.6
0.91 J
ND
18-May-15
0.33
1.0
1.2
5.1
4.6
0.68 J
ND
7-Dec-15
0.33
1.0
1.2
4.8
4.1
0.50 J
ND
2-May-16
0.33
1.0
1.1
2.7
4.4
0.65 J
ND
12-Dec-16
0.33
1.0
0.60
J
3.6
4.3
0.60 J
ND
26-Jun-17
0.33
1.0
ND
3.5
4.3
ND
ND
14-Dec-17
0.33
1.0
1.10
4.7
4.4
0.80 J
ND
14-May-18
0.33
1.0
1.20
2.9
3.6
0.63 J
ND
6-May-19
0.58
1.0
0.74
J
14
4.9
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 19 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
1,1-Dichloroethane
28-Apr-94
NR
5
ND
6.1
16.0
NI
ND
2-May-00
NR
5
ND
ND
8.8
J NI
ND
8-Nov-00
NR
5
ND
ND
11.0
NI
ND
31-May-01
NR
5
ND
ND
8.4
NI
ND
6-Nov-01
NR
5
ND
ND
7.4
NI
ND
21-May-02
NR
5
ND
ND
11.0
NI
ND
13-Nov-02
NR
5
ND
ND
8.1
NI
ND
13-May-03
NR
5
ND
ND
6.0
NI
ND
18-Nov-03
NR
5
ND
ND
6.0
ND
ND
4-May-04
NR
5
ND
ND
5.2
ND
ND
9-Nov-04
NR
5
ND
ND
ND
ND
ND
25-May-05
NR
5
ND
ND
5.0
ND
ND
1-Nov-05
NR
5
ND
ND
5.0
ND
ND
23-May-06
NR
5
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
5
1.9
J
2.3
J 5.1
4.0 J
ND
NC 2L = 70 pg/L (10/23/07)
27-Nov-07
NR
5.0
ND
0.58
J 2.7
J 1.2 J
ND
27-May-08
0.32
5.0
0.36
J
0.71
J 2.8
J 1.1 J
ND
4-Nov-08
0.32
5.0
0.34
J
0.79
J 3.4
J 0.88 J
ND
1-Jun-09
0.32
5.0
0.35
J
Dry
2.6
J 0.62 J
ND
19-Nov-09
0.32
5.0
ND
ND
ND
0.32 J
ND
NC 2L = 6 pg/L (01/01/10)
14-Jun-10
0.32
5.0
0.32
J
0.41
J 2.3
J 1.5 J
ND
29-Nov-10
0.32
5.0
ND
ND
2.7
J ND
ND
31-May-11
0.32
5.0
0.35
J
0.40
J 2.6
J 0.67 J
ND
19-Dec-11
0.32
5.0
ND
ND
2.2
J ND
ND
30-May-12
0.32
5.0
ND
ND
1.9
J ND
ND
3-Dec-12
0.32
5.0
ND
ND
1.7
J ND
ND
10-Jun-13
0.32
5.0
ND
ND
1.8
J ND
ND
28-Oct-13
0.32
5.0
ND
ND
1.5
J 0.42 J
ND
5-May-14
0.32
5.0
ND
ND
1.6
J 0.57 J
ND
20-Oct-14
0.32
5.0
ND
ND
1.3
J 0.46 J
ND
18-May-15
0.32
5.0
ND
ND
0.87
J ND
ND
7-Dec-15
0.32
5.0
ND
ND
0.91
J ND
ND
2-May-16
0.32
5.0
ND
ND
0.95
J ND
ND
12-Dec-16
0.32
5.0
ND
ND
0.97
J ND
ND
26-Jun-17
0.32
5.0
ND
ND
0.97
J ND
ND
14-Dec-17
0.32
5.0
ND
ND
0.89
J ND
ND
14-May-18
0.32
5.0
ND
ND
0.63
J ND
ND
6-May-19
0.41
1.0
ND
0.46
J 5.8
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 20 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
1,2-Dichloroethane
31-May-11
0.12
1.0
ND
ND
0.12 J
ND
ND
NC 2L = 0.4 pg/L (01/01/10)
19-Dec-11
0.12
1.0
ND
ND
ND
ND
ND
30-May-12
0.12
1.0
ND
ND
ND
ND
ND
3-Dec-12
0.12
1.0
ND
ND
ND
ND
ND
10-Jun-13
0.12
1.0
ND
ND
ND
ND
ND
28-Oct-13
0.12
1.0
ND
ND
ND
ND
ND
5-May-14
0.12
1.0
ND
ND
ND
ND
ND
20-Oct-14
0.12
1.0
ND
ND
ND
ND
ND
18-May-15
0.12
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.24
1.0
ND
ND
ND
ND
ND
2-May-16
0.24
1.0
ND
ND
ND
ND
ND
12-Dec-16
0.24
1.0
ND
ND
ND
ND
ND
26-Jun-17
0.24
1.0
ND
ND
ND
ND
ND
14-Dec-17
0.24
1.0
ND
ND
ND
ND
ND
14-May-18
0.24
1.0
ND
ND
ND
ND
ND
6-May-19
0.67
1.0
ND
ND
ND
ND
ND
cis-1,2-Dichloroethene
28-Apr-94
NR
5
12.0
80.0
20.0
NI
ND
2-May-00
NR
5
11.0
58.0
22.0
NI
ND
8-Nov-00
NR
5
16.0
65.0
33.0
NI
ND
31-May-01
NR
5
11.0
75.0
26.0
NI
ND
6-Nov-01
NR
5
15.0
68.0
22.0
NI
ND
21-May-02
NR
5
21.0
92.0
34.0
NI
ND
13-Nov-02
NR
5
16.0
100
29.0
NI
ND
1-Apr-03
NR
5
NA
NA
NA
ND
NA
13-May-03
NR
5
21.0
82.0
26.0
NA
ND
1-Jul-03
NR
5
NA
NA
NA
NA
ND
18-Nov-03
NR
5
9.0
91.0
28.0
23.0
ND
4-May-04
NR
5
11.0
78.0
26.0
19.0
ND
9-Nov-04
NR
5
11.0
66.0
24.0
13.0
N D
25-May-05
NR
5
14.0
59.0
28.0
17.0
ND
1-Nov-05
NR
5
ND
26.0
11.0
7.0
ND
23-May-06
NR
5
ND
26.8
14.0
7.4
ND
1-Nov-06
NR
5
13.0
53.0
25.0
13.0
ND
29-May-07
NR
5
15.0
49.0
24.0
20.0
ND
NC 2L = 70 pg/L (10/23/07)
27-Nov-07
NR
5
ND
43.0
20.0
7.7
ND
27-May-08
0.19
5.0
9.8
50.3
22.0
7.4
ND
4-Nov-08
0.19
5.0
5.1
61.4
27.9
4.2 J
ND
1-Jun-09
0.19
5.0
12.1
Dry
21.1
2.7 J
ND
19-Nov-09
0.19
5.0
ND
ND
ND
12.6
0.26 J
14-Jun-10
0.19
5.0
6.6
51.4
21.7
21.4
ND
29-Nov-10
0.19
5.0
4.4
J
56.5
23.0
11.6
ND
31-May-11
0.19
5.0
7.0
56.2
25.6
12.2
ND
19-Dec-11
0.19
5.0
6.8
41.1
20.9
1.7 J
ND
30-May-12
0.19
5.0
8.8
40.1
19.6
1.3 J
ND
3-Dec-12
0.19
5.0
7.3
30.0
18.7
0.58 J
ND
10-Jun-13
0.19
5.0
7.0
43.0
20.4
0.61 J
ND
28-Oct-13
0.19
5.0
4.4
J
23.6
18.4
4.7 J
ND
5-May-14
0.19
5.0
2.9
J
40.5
19.2
8.5
ND
20-Oct-14
0.19
5.0
2.7
J
33.9
16.6
7.0
ND
18-May-15
0.19
5.0
2.7
J
19.2
13.4
5.8
ND
7-Dec-15
0.19
5.0
4.0
J
26.9
15.4
3.2 J
ND
2-May-16
0.19
5.0
2.1
J
17.2
13.8
7.1
ND
12-Dec-16
0.19
5.0
2.1
J
31.2
16.9
5.2
ND
26-Jun-17
0.19
5.0
2.3
J
24.0
14.7
4.9 J
ND
14-Dec-17
0.19
5.0
3.0
J
21.6
15.3
2.6 J
ND
14-May-18
0.19
5.0
1.9
J
18.9
10.6
3.6 J
ND
6-May-19
0.66
1.0
1.6
ND
18
1.4
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 21 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
trans-1,2-Dichloroethene
29-May-07
NR 5
ND
ND ND 0.4 J
ND
NC 2L = 100 pg/L (10/23/07)
27-Nov-07
NR 5
ND
ND ND ND
ND
27-May-08
0.49 5.0
ND
ND ND ND
ND
4-Nov-08
0.49 5.0
ND
ND ND ND
ND
1-Jun-09
0.49 5.0
ND
Dry ND ND
ND
19-Nov-09
0.49 5.0
ND
ND ND ND
ND
14-Jun-10
0.49 5.0
ND
ND ND ND
ND
29-Nov-10
0.49 5.0
ND
ND ND ND
ND
31-May-11
0.49 5.0
ND
ND ND ND
ND
19-Dec-11
0.49 5.0
ND
ND ND ND
ND
30-May-12
0.49 5.0
ND
ND ND ND
ND
3-Dec-12
0.49 5.0
ND
ND ND ND
ND
10-Jun-13
0.49 5.0
ND
ND ND ND
ND
28-Oct-13
0.49 5.0
ND
ND ND ND
ND
5-May-14
0.49 5.0
ND
ND ND ND
ND
20-Oct-14
0.49 5.0
ND
ND ND ND
ND
18-May-15
0.49 5.0
ND
ND ND ND
ND
7-Dec-15
0.49 5.0
ND
ND ND ND
ND
2-May-16
0.49 5.0
ND
ND ND ND
ND
12-Dec-16
0.49 5.0
ND
ND ND ND
ND
26-Jun-17
0.49 5.0
ND
ND ND ND
ND
14-Dec-17
0.49 5.0
ND
ND ND ND
ND
14-May-18
0.49 5.0
ND
ND ND ND
ND
6-May-19
0.46 1.0
ND
ND ND ND
ND
Bromomethane
27-May-08
0.29 10.0
3.4 J
ND ND ND
ND
NC 2L = NE pg/L (10/23/07)
4-Nov-08
0.29 10.0
ND
ND ND ND
ND
1-Jun-09
0.29 10.0
ND
Dry ND ND
ND
19-Nov-09
0.29 10.0
ND
ND ND ND
ND
14-Jun-10
0.29 10.0
ND
ND ND ND
ND
GWPS = 10 pg/L (8/1/10)
29-Nov-10
0.29 10.0
ND
ND ND ND
ND
31-May-11
0.29 10.0
ND
ND ND ND
ND
19-Dec-11
0.29 10.0
ND
ND ND ND
ND
30-May-12
0.29 10.0
ND
ND ND ND
ND
3-Dec-12
0.29 10.0
ND
ND ND ND
ND
10-Jun-13
0.29 10.0
ND
ND ND ND
ND
28-Oct-13
0.29 10.0
ND
ND ND ND
ND
5-May-14
0.29 10.0
ND
ND ND ND
ND
20-Oct-14
0.29 10.0
ND
ND ND ND
ND
18-May-15
0.29 10.0
ND
ND ND ND
ND
7-Dec-15
0.29 10.0
ND
ND ND ND
ND
2-May-16
0.29 10.0
ND
ND ND ND
ND
12-Dec-16
0.29 10.0
ND
ND ND ND
ND
26-Jun-17
0.29 10.0
ND
ND ND ND
ND
14-Dec-17
0.29 10.0
ND
ND ND ND
ND
14-May-18
0.29 10.0
ND
ND ND ND
ND
6-May-19
0.95 2.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 22 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
1,2-Dichloropropane
14-Jun-10
0.27 1.0
ND
ND ND 0.32 J
ND
NC 2L = 0.6 pg/L (01/01/10)
29-Nov-10
0.27 1.0
ND
ND ND ND
ND
31-May-11
0.27 1.0
ND
ND ND ND
ND
19-Dec-11
0.27 1.0
ND
ND ND ND
ND
30-May-12
0.27 1.0
ND
ND ND ND
ND
3-Dec-12
0.27 1.0
ND
ND 0.28 J ND
ND
10-Jun-13
0.27 1.0
ND
ND ND ND
ND
28-Oct-13
0.27 1.0
ND
ND ND ND
ND
5-May-14
0.27 1.0
ND
ND ND ND
ND
20-Oct-14
0.27 1.0
ND
ND ND ND
ND
18-May-15
0.27 1.0
ND
ND ND ND
ND
7-Dec-15
0.27 1.0
ND
ND ND ND
ND
2-May-16
0.27 1.0
ND
ND ND ND
ND
12-Dec-16
0.27 1.0
ND
ND ND ND
ND
26-Jun-17
0.27 1.0
ND
ND ND ND
ND
14-Dec-17
0.27 1.0
ND
ND ND ND
ND
14-May-18
0.27 1.0
ND
ND ND ND
ND
6-May-19
0.60 1.0
ND
ND 1.0 ND
ND
Resample >
24-Jul-19
0.60 1.0
ND
ND ND ND
ND
Ethylbenzene
14-Jun-10
0.26 1.0
ND
0.35 J ND ND
ND
NC 2L = 600 pg/L (01/01/10)
29-Nov-10
0.30 1.0
ND
ND ND ND
ND
31-May-11
0.30 1.0
ND
ND ND ND
ND
19-Dec-11
0.30 1.0
ND
ND ND ND
ND
30-May-12
0.30 1.0
ND
ND ND ND
ND
3-Dec-12
0.30 1.0
ND
ND ND ND
ND
10-Jun-13
0.30 1.0
ND
ND ND ND
ND
28-Oct-13
0.30 1.0
ND
ND ND ND
ND
5-May-14
0.30 1.0
ND
ND ND ND
ND
20-Oct-14
0.30 1.0
ND
ND ND ND
ND
18-May-15
0.30 1.0
ND
ND ND ND
ND
7-Dec-15
0.30 1.0
ND
ND ND ND
ND
2-May-16
0.30 1.0
ND
ND ND ND
ND
12-Dec-16
0.30 1.0
ND
ND ND ND
ND
26-Jun-17
0.30 1.0
ND
ND ND ND
ND
14-Dec-17
0.30 1.0
ND
ND ND ND
ND
14-May-18
0.30 1.0
ND
ND ND ND
ND
6-May-19
0.45 1.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 23 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL RL
MW-1
MW-2 MW-3 AMW-1
Blanks
Styrene
1-Jun-09
0.26 1.0
2.0
Dry ND ND
ND
NC 2L = 100 pg/L (10/23/07)
19-Nov-09
0.26 1.0
ND
ND ND ND
ND
NC 2L = 70 pg/L (01/01/10)
14-Jun-10
0.26 1.0
ND
ND ND ND
ND
29-Nov-10
0.26 1.0
ND
ND ND ND
ND
31-May-11
0.26 1.0
ND
ND ND ND
ND
19-Dec-11
0.26 1.0
ND
ND ND ND
ND
30-May-12
0.26 1.0
ND
ND ND ND
ND
3-Dec-12
0.26 1.0
ND
ND ND ND
ND
10-Jun-13
0.26 1.0
ND
ND ND ND
ND
28-Oct-13
0.26 1.0
ND
ND ND ND
ND
5-May-14
0.26 1.0
ND
ND ND ND
ND
20-Oct-14
0.26 1.0
ND
ND ND ND
ND
18-May-15
0.26 1.0
ND
ND ND ND
ND
7-Dec-15
0.26 1.0
ND
ND ND ND
ND
2-May-16
0.26 1.0
ND
ND ND ND
ND
12-Dec-16
0.26 1.0
ND
ND ND ND
ND
26-Jun-17
0.26 1.0
ND
ND ND ND
ND
14-Dec-17
0.26 1.0
ND
ND ND ND
ND
14-May-18
0.26 1.0
ND
ND ND ND
ND
6-May-19
0.50 1.0
ND
ND ND ND
ND
Methylene Chloride
28-Apr-94
NR 5
ND
5.8 7.8 NI
ND
2-May-00
NR 10
ND
ND ND NI
ND
8-Nov-00
NR 10
ND
ND ND NI
ND
31-May-01
NR 10
ND
ND ND NI
ND
6-Nov-01
NR 10
ND
ND ND NI
ND
21-May-02
NR 10
ND
ND ND NI
ND
13-Nov-02
NR 10
ND
ND ND NI
ND
13-May-03
NR 10
ND
ND ND NI
ND
18-Nov-03
NR 10
ND
ND ND ND
ND
4-May-04
NR 10
ND
ND ND ND
ND
9-Nov-04
NR 10
ND
ND ND ND
ND
25-May-05
NR 10
ND
ND ND ND
ND
1-Nov-05
NR 10
ND
ND ND ND
ND
23-May-06
NR 10
ND
ND ND ND
ND
1-Nov-06
NR 10
ND
ND ND ND
ND
29-May-07
NR 1
ND
ND ND ND
ND
NC 2L = 4.6 pg/L (10/23/07)
27-Nov-07
NR 1
ND
ND ND ND
ND
27-May-08
0.97 2.0
ND
ND ND ND
1.5 J
4-Nov-08
0.97 2.0
ND
ND ND ND
2.8
1-Jun-09
0.97 2.0
ND
Dry ND ND
ND
19-Nov-09
0.97 2.0
ND
ND ND ND
ND
NC 2L = 5 pg/L (01/01/10)
14-Jun-10
0.97 2.0
ND
ND ND ND
ND
29-Nov-10
0.97 1.0
ND
ND ND ND
ND
31-May-11
0.97 1.0
ND
ND ND ND
ND
19-Dec-11
0.97 1.0
ND
ND ND ND
3.3
30-May-12
0.97 1.0
ND
ND ND ND
ND
3-Dec-12
0.97 1.0
ND
ND ND ND
ND
10-Jun-13
0.97 1.0
ND
ND ND ND
ND
28-Oct-13
0.97 1.0
ND
ND ND ND
ND
5-May-14
0.97 1.0
ND
ND ND ND
2.6
20-Oct-14
0.97 1.0
ND
ND ND ND
ND
18-May-15
0.97 1.0
ND
ND ND ND
1.3
7-Dec-15
0.97 1.0
ND
ND ND ND
ND
2-May-16
0.97 1.0
ND
ND ND ND
ND
12-Dec-16
0.97 1.0
ND
ND ND ND
ND
26-Jun-17
0.97 1.0
ND
ND ND ND
1.3 C9
14-Dec-17
0.97 1.0
ND
ND ND ND
2.1 C9
14-May-18
0.97 1.0
ND
ND ND ND
ND
6-May-19
0.50 1.0
ND
ND ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 24 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Tetrachloroethene
28-Apr-94
NR
5.0
ND
14.0
6.2
NI
ND
(PCE)
6-Oct-94
NR
5.0
ND
13.0
10.0
NI
ND
2-May-00
NR
5
ND
ND
ND
NI
ND
8-Nov-00
NR
5
ND
ND
ND
NI
ND
31-May-01
NR
5
ND
ND
ND
NI
ND
6-Nov-01
NR
5
ND
ND
ND
NI
ND
21-May-02
NR
5
ND
ND
ND
NI
ND
13-Nov-02
NR
5
ND
ND
ND
NI
ND
13-May-03
NR
5
ND
ND
ND
NI
ND
18-Nov-03
NR
5
ND
ND
ND
ND
ND
4-May-04
NR
5
ND
ND
ND
ND
ND
9-Nov-04
NR
0.6
ND
ND
ND
ND
ND
25-May-05
NR
5
ND
ND
ND
ND
ND
1-Nov-05
NR
5
ND
ND
ND
ND
ND
23-May-06
NR
5
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
1
0.6
J
0.57 J
1.0
ND
ND
NC 2L = 0.7 pg/L (10/23/07)
27-Nov-07
NR
1
ND
0.43 J
0.67
J
ND
ND
27-May-08
0.46
1.0
0.53
J
0.54 J
0.60
J
ND
ND
4-Nov-08
0.46
1.0
0.48
J
ND
0.58
J
ND
ND
1-Jun-09
0.46
1.0
0.49
J
Dry
0.48
J
ND
ND
19-Nov-09
0.46
1.0
ND
ND
ND
ND
ND
14-Jun-10
0.46
1.0
0.53
J
ND
ND
ND
ND
29-Nov-10
0.46
1.0
ND
ND
ND
ND
ND
31-May-11
0.46
1.0
ND
ND
ND
ND
ND
19-Dec-11
0.46
1.0
ND
ND
0.49
B
ND
0.77 J
30-May-12
0.46
1.0
ND
ND
ND
ND
ND
3-Dec-12
0.46
1.0
ND
ND
ND
ND
ND
10-Jun-13
0.46
1.0
0.50
J
ND
ND
ND
ND
28-Oct-13
0.46
1.0
ND
ND
ND
ND
ND
5-May-14
0.46
1.0
ND
ND
ND
ND
ND
20-Oct-14
0.46
1.0
ND
ND
ND
ND
ND
18-May-15
0.46
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.46
1.0
ND
ND
ND
ND
ND
2-May-16
0.46
1.0
0.55
J
ND
ND
ND
ND
12-Dec-16
0.46
1.0
ND
ND
ND
ND
ND
26-Jun-17
0.46
1.0
ND
ND
ND
ND
ND
14-Dec-17
0.46
1.0
ND
ND
ND
ND
ND
14-May-18
0.46
1.0
ND
ND
ND
ND
ND
6-May-19
0.78
1.0
ND
ND
11.3
ND
ND
Resample >
24-Jul-19
0.78
1.0
ND
ND
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 25 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Trichloroethene
28-Apr-94
NR
5
ND
9.9
7.2
NI
ND
(TCE)
6-Oct-94
NR
5
ND
10.0
7.6
NI
ND
2-May-00
NR
5
ND
ND
ND
NI
ND
8-Nov-00
NR
5
ND
ND
5.5
NI
ND
31-May-01
NR
5
ND
ND
ND
NI
ND
6-Nov-01
NR
5
ND
ND
ND
NI
ND
21-May-02
NR
5
ND
ND
ND
NI
ND
13-Nov-02
NR
5
ND
ND
ND
NI
ND
13-May-03
NR
5
ND
ND
ND
NI
ND
18-Nov-03
NR
5
ND
ND
ND
ND
ND
4-May-04
NR
5
ND
ND
ND
ND
ND
9-Nov-04
NR
5
ND
ND
ND
ND
ND
25-May-05
NR
5
ND
ND
ND
ND
ND
1-Nov-05
NR
5
ND
ND
ND
ND
ND
23-May-06
NR
5
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
1
ND
2.9
3.1
3.0
ND
NC 2L = 2.8 pg/L (10/23/07)
27-Nov-07
NR
1
ND
1.5
1.7
ND
ND
27-May-08
0.47
1.0
ND
1.5
1.6
0.56 J
ND
4-Nov-08
0.47
1.0
ND
1.6
1.6
ND
ND
1-Jun-09
0.47
1.0
ND
Dry
1.4
ND
ND
19-Nov-09
0.47
1.0
ND
ND
ND
ND
ND
NC 2L = 3 pg/L (01/01/10)
14-Jun-10
0.47
1.0
ND
0.92
J 1.3
1.2
ND
29-Nov-10
0.47
1.0
ND
1.3
1.5
ND
ND
31-May-11
0.47
1.0
ND
0.84
J 1.3
0.59 J
ND
19-Dec-11
0.47
1.0
ND
0.87
J 1.3
ND
ND
30-May-12
0.47
1.0
ND
0.61
J 1.1
ND
ND
3-Dec-12
0.47
1.0
ND
0.68
J 1.0
ND
ND
10-Jun-13
0.47
1.0
ND
1.8
1.1
ND
ND
28-Oct-13
0.47
1.0
ND
0.50
J 0.86
J ND
ND
5-May-14
0.47
1.0
ND
0.85
J 0.92
J 0.57 J
ND
20-Oct-14
0.47
1.0
ND
0.69
J 0.81
J ND
ND
18-May-15
0.47
1.0
ND
ND
0.66
J ND
ND
7-Dec-15
0.47
1.0
ND
ND
0.71
J ND
ND
2-May-16
0.47
1.0
ND
ND
0.55
J ND
ND
12-Dec-16
0.47
1.0
ND
0.51
J 0.65
J ND
ND
26-Jun-17
0.47
1.0
ND
ND
0.60
J ND
ND
14-Dec-17
0.47
1.0
ND
ND
0.57
J ND
ND
14-May-18
0.47
1.0
ND
ND
ND
ND
ND
6-May-19
0.34
1.0
ND
ND
6.0
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 26 of 28

TABLE A2-2: Historical Groundwater Constituents
Analyte
Sample
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Toluene
19-Nov-09
0.26
1.0
ND
ND
ND
0.49 J
ND
NC 2L = 6,000 pg/L (01/01/10)
14-Jun-10
0.26
1.0
1.1
ND
ND
ND
ND
29-Nov-10
0.26
1.0
ND
ND
ND
ND
ND
31-May-11
0.26
1.0
ND
ND
ND
ND
ND
19-Dec-11
0.26
1.0
ND
ND
ND
ND
ND
30-May-12
0.26
1.0
ND
ND
ND
ND
ND
3-Dec-12
0.26
1.0
ND
ND
ND
ND
ND
10-Jun-13
0.26
1.0
ND
ND
ND
ND
ND
28-Oct-13
0.26
1.0
ND
ND
ND
ND
ND
5-May-14
0.26
1.0
ND
ND
ND
ND
ND
20-Oct-14
0.26
1.0
ND
ND
ND
ND
ND
18-May-15
0.26
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.26
1.0
ND
ND
ND
ND
ND
2-May-16
0.26
1.0
ND
ND
ND
ND
ND
12-Dec-16
0.26
1.0
ND
ND
ND
ND
ND
26-Jun-17
0.26
1.0
ND
ND
ND
ND
ND
14-Dec-17
0.26
1.0
ND
ND
ND
ND
ND
14-May-18
0.26
1.0
ND
ND
ND
ND
ND
6-May-19
0.31
1.0
ND
ND
ND
ND
ND
Vinyl Chloride
12-May-97
NR
5
ND
ND
3.1
J NI
ND
2-May-00
NR
10
ND
ND
ND
NI
ND
8-Nov-00
NR
10
ND
ND
ND
NI
ND
31-May-01
NR
10
ND
ND
ND
NI
ND
6-Nov-01
NR
10
ND
ND
ND
NI
ND
21-May-02
NR
10
ND
ND
ND
NI
ND
13-Nov-02
NR
10
ND
ND
ND
NI
ND
13-May-03
NR
10
ND
ND
ND
NI
ND
18-Nov-03
NR
10
ND
ND
ND
ND
ND
4-May-04
NR
10
ND
ND
ND
ND
ND
9-Nov-04
NR
10
ND
ND
ND
ND
ND
25-May-05
NR
10
ND
ND
ND
ND
ND
1-Nov-05
NR
10
ND
ND
ND
ND
ND
23-May-06
NR
10
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
1
1.8
ND
1.3
2.0
ND
NC 2L = 0.015 pg/L (10/23/07)
27-Nov-07
NR
1
0.75
J
ND
0.69
J ND
ND
27-May-08
0.62
1.0
1.3
ND
1.0
ND
ND
4-Nov-08
0.62
1.0
0.67
J
ND
1.0
ND
ND
1-Jun-09
0.62
1.0
1.4
Dry
0.83
J ND
ND
19-Nov-09
0.62
1.0
ND
ND
ND
1.6
ND
NC 2L = 0.03 pg/L (01/01/10)
14-Jun-10
0.62
1.0
1.3
ND
1.3
0.67 J
ND
29-Nov-10
0.62
1.0
1.1
0.63 J
1.3
0.65 J
ND
31-May-11
0.62
1.0
1.3
ND
1.0
0.81 J
ND
19-Dec-11
0.62
1.0
1.2
ND
0.84
J ND
ND
30-May-12
0.62
1.0
2.1
ND
ND
ND
ND
3-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
10-Jun-13
0.62
1.0
1.4
ND
0.86
J ND
ND
28-Oct-13
0.62
1.0
0.64
J
ND
ND
ND
ND
5-May-14
0.62
1.0
0.65
J
ND
0.76
J ND
ND
20-Oct-14
0.62
1.0
ND
ND
ND
ND
ND
18-May-15
0.62
1.0
ND
ND
ND
ND
ND
7-Dec-15
0.62
1.0
1
ND
ND
ND
ND
2-May-16
0.62
1.0
ND
ND
ND
ND
ND
12-Dec-16
0.62
1.0
ND
ND
ND
ND
ND
26-Jun-17
0.62
1.0
ND
ND
0.63
J ND
ND
14-Dec-17
0.62
1.0
0.69
J
ND
0.71
J ND
ND
14-May-18
0.62
1.0
ND
ND
ND
ND
ND
6-May-19
0.60
1.0
ND
ND
1.4
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 27 of 28

TABLE A2-2: Historical Groundwater Constituents
Sample
Analyte
Collection Date
DL
RL
MW-1
MW-2
MW-3
AMW-1
Blanks
Xylene (Total)
28-Apr-94
NR
5
5.1
15.0
ND
NI
ND
8-Nov-00
NR
5
ND
ND
ND
NI
ND
1-Oct-99
NR
5
ND
5.9
ND
NI
ND
NC 2L = 530 pg/L (10/23/07)
2-May-00
NR
5
ND
ND
ND
NI
ND
31-May-01
NR
5
ND
ND
ND
NI
ND
NC 2L = 500 pg/L (01/01/10)
6-Nov-01
NR
5
ND
ND
ND
NI
ND
21-May-02
NR
5
ND
ND
ND
NI
ND
13-Nov-02
NR
5
ND
ND
ND
NI
ND
13-May-03
NR
5
ND
ND
ND
NI
ND
18-Nov-03
NR
5
ND
ND
ND
ND
ND
4-May-04
NR
5
ND
ND
ND
ND
ND
9-Nov-04
NR
5
ND
ND
ND
ND
ND
25-May-05
NR
5
ND
ND
ND
ND
ND
1-Nov-05
NR
5
ND
ND
ND
ND
ND
23-May-06
NR
10
ND
ND
ND
ND
ND
1-Nov-06
NR
10
ND
ND
ND
ND
ND
29-May-07
NR
4
ND
1.3
J ND
ND
ND
27-Nov-07
NR
5
ND
1.4
J ND
ND
ND
27-May-08
0.89
10.0
ND
1.5
J ND
ND
ND
4-Nov-08
0.66
10.0
ND
1.3
J ND
ND
ND
NC 2L = 530 pg/L (10/23/07)
1-Jun-09
0.66
2.0
ND
Dry
ND
ND
ND
19-Nov-09
0.66
2.0
ND
ND
ND
ND
ND
NC 2L = 500 pg/L (01/01/10)
14-Jun-10
0.66
2.0
ND
3.1
ND
ND
ND
29-Nov-10
0.66
2.0
ND
2.3
ND
ND
ND
31-May-11
0.66
2.0
ND
0.80
J ND
ND
ND
19-Dec-11
0.66
2.0
ND
0.89
J ND
ND
ND
30-May-12
0.66
2.0
ND
ND
ND
ND
ND
3-Dec-12
0.66
2.0
ND
ND
ND
ND
ND
10-Jun-13
0.66
5.0
ND
ND
ND
ND
ND
28-Oct-13
0.66
5.0
ND
ND
ND
ND
ND
5-May-14
0.66
5.0
ND
ND
ND
ND
ND
20-Oct-14
0.66
5.0
ND
ND
ND
ND
ND
18-May-15
0.66
5.0
ND
ND
ND
ND
ND
7-Dec-15
0.66
5.0
ND
ND
ND
ND
ND
2-May-16
0.66
5.0
ND
ND
ND
ND
ND
12-Dec-16
0.66
5.0
ND
ND
ND
ND
ND
26-Jun-17
0.66
5.0
ND
ND
ND
ND
ND
14-Dec-17
0.66
5.0
ND
ND
ND
ND
ND
14-May-18
0.66
5.0
ND
ND
ND
ND
ND
6-May-19
1.50
2.0
ND
17.2
ND
ND
ND
1,4 Dioxane (p-Dioxane)
6-May-19
1.2
2
ND
2.7
33.1
1.9 J
ND
NC 2L = 3 pg/L
Chloroethane
6-May-19
0.5
1
---
1.7
ND
---
ND
Notes:
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006;
and Solid Waste Section Reporting Limit (SWSL) for December 2006 - 2017; NC PQL for 2018 - present ).
DL = Laboratory detection limit
ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006).
NA = No data available. NR = Not reported. NI = Not installed. NE = Not established.
J = Estimated concentration less than the RL but greater than the DL.
B = Blank -Qualified (Concentration suspected to reflect laboratory or field contamination).
NC2L = North Carolina 2L Groundwater Standards (15A NCAC 2L).
IMAC = NC Interim Maximum Allowable Concentration.
Bold values are greater than the NC2L Standards or IMAC.
Historical data between 1994-1999 availible upon request
Burke County -East Burke La Bella Associates
Permit No. 12-02 28 of 28

TABLE A2-3: Historical Surface Water Constituents
Sample
Collection
Analyte
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
INORGANICS
Arsenic
29-May-07
NR 10
Dry 2.3 J
ND
27-Nov-07
NR 10
Dry 2.8 J
ND
NC 2B/EPA NC = 10 pg/L (03/28/08)
27-May-08
2.7 10.0
Dry ND
ND
04-Nov-08
2.6 10.0
Dry ND
4.8 J
01-Jun-09
2.6 10.0
Dry ND
ND
19-Nov-09
2.7 10.0
ND ND
ND
NC 2B = 10 ug/L (05/01/07)
14-Jun-10
2.7 10.0
ND 3.3 J
ND
29-Nov-10
2.7 10.0
ND ND
ND
31-May-11
2.7 10.0
ND ND
ND
19-Dec-11
5.0 10.0
Dry ND
ND
29-May-12
5.0 10.0
Dry ND
ND
03-Dec-12
5.0 10.0
Dry ND
ND
10-Jun-13
5.0 10.0
ND ND
ND
28-Oct-13
5.0 10.0
ND ND
ND
05-May-14
EPA 6010
5.0 10.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 10.0
ND ND
ND
18-May-15
EPA 6010
2.5 10.0
Dry 3.2 J
ND
07-Dec-15
EPA 6010
2.5 10.0
Dry ND
ND
02-May-16
EPA 6010
2.5 10.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 10.0
Dry ND
ND
26-Jun-17
EPA 6010
5.0 10.0
Dry ND
ND
14-May-18
EPA 6010
5.0 10.0
ND ND
ND
03-Dec-18
EPA 6010
5.0 10.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 1 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Barium
Nov-97
NR
100
ND
1000
NA
May-98
NR
100
ND
ND
ND
Nov-98
NR
100
ND
ND
ND
May-99
NR
5
18.0
19.0
ND
Oct-99
NR
500
ND
ND
ND
May-00
NR
500
ND
ND
ND
Nov-00
NR
500
Dry
ND
ND
May-01
NR
500
Dry
ND
ND
Nov-01
NR
500
Dry
ND
ND
May-02
NR
500
Dry
ND
ND
Nov-02
NR
500
ND
ND
ND
May-03
NR
500
ND
ND
ND
Nov-03
NR
500
ND
ND
ND
May-04
NR
500
Dry
ND
ND
Nov-04
NR
500
ND
ND
ND
May-05
NR
500
Dry
ND
ND
Nov-05
NR
500
Dry
ND
ND
23-May-06
NR
500
Dry
ND
ND
01-Nov-06
NR
10
ND
ND
ND
29-May-07
NR
100
Dry
44.1 J
ND
27-Nov-07
NR
100
Dry
46.5 J
0.30
J
NC 2B/EPA NC = 1,000 ug/L (03/28/08)
27-May-08
0.2
100
Dry
48.8 J
0.41
J
04-Nov-08
0.20
100
Dry
51.7 B
10.5
J
01-Jun-09
0.20
100
Dry
41.2 B
15.2
J
19-Nov-09
0.20
100
81.4
B
40.5 B
19.8
J
NC 2B = 1,000 ug/L (05/01/07)
14-Jun-10
0.20
100
111
39.8 J
0.58
J
29-Nov-10
0.20
100
94.7
J
39.2 J
ND
31-May-11
0.20
100
92.9
J
37.6 J
ND
19-Dec-11
5.0
100
Dry
38.2 J
ND
29-May-12
5.0
100
Dry
38.5 J
ND
03-Dec-12
5.0
100
Dry
43.0 J
ND
10-Jun-13
5.0
100
21.3
B
86.4 J
13.7
J
28-Oct-13
5.0
100
15.4
J
36.8 J
ND
05-May-14
EPA 6010
5.0
100
13.7
J
44.5 J
ND
20-Oct-14
EPA 6010
5.0
100
13.3
J
39.8 J
ND
18-May-15
EPA 6010
2.5
100
Dry
38.9 J
ND
07-Dec-15
EPA 6010
2.5
100
Dry
54.3 J
ND
02-May-16
EPA 6010
2.5
100
Dry
41.6 J
ND
12-Dec-16
EPA 6010
2.5
100
Dry
45.4 J
ND
26-Jun-17
EPA 6010
2.5
100
Dry
53.1 J
2.5
J
14-May-18
EPA 6010
2.5
100
23.2
J
41.9 J
ND
03-Dec-18
EPA 6010
2.5
5
39.1
49.3
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 2 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Beryllium
Nov-02
NR 2
3.2 3.6
ND
May-03
NR 2
ND ND
ND
Nov-03
NR 2
ND ND
ND
May-04
NR 2
Dry ND
ND
Nov-04
NR 2
ND ND
ND
May-05
NR 2
Dry ND
ND
Nov-05
NR 2
Dry ND
ND
23-May-06
NR 2
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 1
Dry ND
ND
27-Nov-07
NR 1
Dry ND
ND
NC 2B/EPA NC = 6.5 ug/L (03/28/08)
27-May-08
0.1 1.0
Dry N D
N D
04-Nov-08
0.10 1.0
Dry ND
ND
01-Jun-09
0.10 1.0
Dry ND
ND
19-Nov-09
0.10 1.0
ND ND
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.10 1.0
ND ND
ND
29-Nov-10
0.10 1.0
ND ND
ND
31-May-11
0.10 1.0
ND ND
ND
19-Dec-11
1.0 1.0
Dry ND
ND
29-May-12
1.0 1.0
Dry ND
ND
03-Dec-12
1.0 1.0
Dry ND
ND
10-Jun-13
1.0 1.0
ND ND
ND
28-Oct-13
1.0 1.0
ND ND
ND
05-May-14
EPA 6010
1.0 1.0
ND ND
ND
20-Oct-14
EPA 6010
1.0 1.0
ND ND
ND
18-May-15
EPA 6010
0.5 1.0
Dry ND
ND
07-Dec-15
EPA 6010
0.5 1.0
Dry ND
ND
02-May-16
EPA 6010
0.5 1.0
Dry ND
ND
12-Dec-16
EPA 6010
0.5 1.0
Dry ND
ND
26-Jun-17
EPA 6010
0.5 1.0
Dry ND
ND
14-May-18
EPA 6010
0.5 1.0
ND ND
ND
03-Dec-18
EPA 6010
0.5 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 3 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Cadmium
Oct-99
NR 1
ND 1.0
ND
May-00
NR 1
ND ND
ND
Nov-00
NR 1
Dry ND
ND
May-01
NR 1
Dry ND
ND
Nov-01
NR 1
Dry ND
ND
May-02
NR 1
Dry 1.0
ND
Nov-02
NR 1
1.2 1.5
ND
May-03
NR 1
ND ND
ND
Nov-03
NR 1
ND ND
ND
May-04
NR 1
Dry ND
ND
Nov-04
NR 1
ND ND
ND
May-05
NR 1
Dry ND
ND
Nov-05
NR 1
Dry ND
ND
23-May-06
NR 1
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 1
Dry ND
ND
27-Nov-07
NR 1
Dry ND
ND
NC 2B/EPA NC = 2 Ng/L (03/28/08)
27-May-08
0.5 1.0
Dry ND
ND
04-Nov-08
0.50 1.0
Dry ND
ND
01-Jun-09
0.50 1.0
Dry ND
ND
19-Nov-09
0.50 1.0
ND ND
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.50 1.0
ND ND
ND
29-Nov-10
0.50 1.0
ND ND
ND
31-May-11
0.50 1.0
ND ND
ND
19-Dec-11
1.0 1.0
Dry ND
ND
29-May-12
1.0 1.0
Dry ND
ND
03-Dec-12
1.0 1.0
Dry ND
ND
10-Jun-13
1.0 1.0
ND ND
ND
28-Oct-13
1.0 1.0
ND ND
ND
05-May-14
EPA 6010
1.0 1.0
ND ND
ND
20-Oct-14
EPA 6010
1.0 1.0
ND ND
ND
18-May-15
EPA 6010
0.5 1.0
Dry ND
ND
07-Dec-15
EPA 6010
0.5 1.0
Dry ND
ND
02-May-16
EPA 6010
0.5 1.0
Dry ND
ND
12-Dec-16
EPA 6010
0.5 1.0
Dry ND
ND
26-Jun-17
EPA 6010
0.5 1.0
Dry ND
ND
14-May-18
EPA 6010
0.5 1.0
ND ND
ND
03-Dec-18
EPA 6010
0.5 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 4 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Chromium
May-97
NR 1
2.0 1.0
ND
Nov-97
NR 1
ND ND
NA
May-98
NR 1
ND ND
ND
Nov-98
NR 1
ND ND
ND
May-99
NR 5
ND ND
ND
Oct-99
NR 10
ND ND
ND
May-00
NR 10
ND ND
ND
Nov-00
NR 10
Dry ND
ND
May-01
NR 10
Dry ND
ND
Nov-01
NR 10
Dry ND
ND
May-02
NR 10
Dry ND
ND
Nov-02
NR 10
ND ND
ND
May-03
NR 10
ND ND
ND
Nov-03
NR 10
ND ND
ND
May-04
NR 10
Dry ND
ND
Nov-04
NR 10
ND ND
ND
May-05
NR 10
Dry ND
ND
Nov-05
NR 10
Dry ND
ND
23-May-06
NR 10
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 10
Dry ND
ND
27-Nov-07
NR 10
Dry ND
ND
NC 2B/EPA NC = 50 pg/L (03/28/08)
27-May-08
0.4 10.0
Dry ND
0.85 J
04-Nov-08
0.40 10.0
Dry ND
ND
01-Jun-09
0.40 10.0
Dry ND
ND
NC 2B/EPA NC = 20 pg/L (02/05/10)
19-Nov-09
0.40 10.0
0.48 B ND
1.1 J
NC 2B = 20 pg/L (05/01/07)
14-Jun-10
0.40 10.0
7 J 0.42 J
ND
29-Nov-10
0.40 10.0
ND ND
ND
31-May-11
0.40 10.0
1.2 B 1.2 B
0.73 J
19-Dec-11
5.0 10.0
Dry ND
ND
29-May-12
5.0 10.0
Dry ND
ND
03-Dec-12
5.0 10.0
Dry ND
ND
10-Jun-13
5.0 10.0
ND 16.7
ND
28-Oct-13
5.0 10.0
ND ND
ND
05-May-14
EPA 6010
5.0 10.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 10.0
ND ND
ND
18-May-15
EPA 6010
2.5 10.0
Dry ND
ND
07-Dec-15
EPA 6010
2.5 10.0
Dry ND
ND
02-May-16
EPA 6010
2.5 10.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 10.0
Dry ND
ND
26-Jun-17
EPA 6010
2.5 10.0
Dry ND
ND
14-May-18
EPA 6010
2.5 10.0
ND ND
ND
03-Dec-18
EPA 6010
2.5 5.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 5 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Cobalt
May-98
NR 1.0
ND 3.0
ND
Nov-98
NR 1.0
ND ND
ND
May-99
NR 5.0
ND ND
ND
Oct-99
NR 10
ND ND
ND
May-00
NR 10
ND ND
ND
Nov-00
NR 10
Dry ND
ND
May-01
NR 10
Dry ND
ND
Nov-01
NR 10
Dry ND
ND
May-02
NR 10
Dry ND
NA
Nov-02
NR 10
ND ND
ND
May-03
NR 10
23.0 ND
ND
Nov-03
NR 10
34.0 10.0
ND
May-04
NR 10
Dry 10.0
ND
Nov-04
NR 10
16.0 12.0
ND
May-05
NR 10
Dry ND
ND
Nov-05
NR 10
Dry 11.0
ND
23-May-06
NR 10
Dry 12.4
ND
06-Nov-06
NR 10
17.5 ND
ND
29-May-07
NR 10
Dry 10.7
ND
27-Nov-07
NR 10
Dry 10.4
ND
INC 2B/EPA NC = 190 ug/L (03/28/08)
27-May-08
0.6 10.0
Dry 11.3
ND
05-Nov-08
0.60 10.0
Dry 14.9 B
3.5 J
01-Jun-09
0.60 10.0
Dry 15.0 B
3.3 J
NC 2B = NE ug/L (05/01/07)
19-Nov-09
0.60 10.0
ND 5.5 J
ND
14-Jun-10
0.60 10.0
64.4 11.0
ND
29-Nov-10
0.60 10.0
54.1 10.3
ND
31-May-11
0.60 10.0
23.6 8.1 J
ND
19-Dec-11
5.0 10.0
Dry 8.2 J
ND
29-May-12
5.0 10.0
Dry 8.9 J
ND
03-Dec-12
5.0 10.0
Dry 11.7
ND
10-Jun-13
5.0 10.0
ND 18.2
ND
28-Oct-13
5.0 10.0
ND 11.4
ND
05-May-14
EPA6010
5.0 10.0
ND 6.9 J
ND
20-Oct-14
EPA6010
5.0 10.0
ND 8.2 J
ND
18-May-15
EPA6010
2.5 10.0
Dry 8.5 J
ND
07-Dec-15
EPA6010
2.5 10.0
Dry 6.2 J
ND
02-May-16
EPA6010
2.5 10.0
Dry 6.3 J
ND
12-Dec-16
EPA6010
2.5 10.0
Dry 9.2 J
ND
26-Jun-17
EPA6010
2.5 10.0
Dry 10.0 J
ND
14-May-18
EPA6010
2.5 10.0
ND 8.5 J
ND
03-Dec-18
EPA 6010
2.5 5.0
2.7 J 7.4
ND
10D
2.5 5.0
3.5
Burke County -East Burke La Bella Associates
Permit No. 12-02 6 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Copper
May-97
NR 10
40.0 ND
ND
Nov-97
NR 10
ND ND
ND
May-98
NR 10
ND ND
ND
Nov-98
NR 10
ND ND
ND
May-99
NR 5
ND ND
ND
Oct-99
NR 200
ND ND
ND
May-00
NR 200
ND ND
ND
Nov-00
NR 200
Dry ND
ND
May-01
NR 200
Dry ND
ND
Nov-01
NR 200
Dry ND
ND
May-02
NR 200
Dry ND
ND
Nov-02
NR 200
ND ND
ND
May-03
NR 200
ND ND
ND
Nov-03
NR 200
ND ND
ND
May-04
NR 200
Dry ND
ND
Nov-04
NR 200
ND ND
ND
May-05
NR 200
Dry ND
ND
Nov-05
NR 200
Dry ND
ND
23-May-06
NR 200
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 10
Dry ND
ND
27-Nov-07
NR 10
Dry ND
ND
NC 2B/EPA NC = 7 Ng/L (03/28/08)
27-May-08
0.3 10.0
Dry ND
ND
05-Nov-08
0.30 10.0
Dry ND
0.94 J
01-Jun-09
0.30 10.0
Dry ND
ND
19-Nov-09
0.30 10.0
1.1 J ND
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.30 10.0
1.9 B ND
3.4 J
29-Nov-10
0.30 10.0
ND ND
ND
31-May-11
0.30 10.0
0.47 J ND
ND
19-Dec-11
5.0 10.0
Dry ND
ND
29-May-12
5.0 10.0
Dry ND
ND
03-Dec-12
5.0 10.0
Dry ND
ND
10-Jun-13
5.0 10.0
ND 7.7 B
10.8
28-Oct-13
5.0 10.0
ND ND
ND
05-May-14
EPA 6010
5.0 10.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 10.0
ND ND
ND
18-May-15
EPA 6010
2.5 10.0
Dry ND
ND
07-Dec-15
EPA 6010
2.5 10.0
Dry ND
ND
02-May-16
EPA 6010
2.5 10.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 10.0
Dry ND
ND
26-Jun-17
EPA 6010
2.5 10.0
Dry ND
ND
14-May-18
EPA 6010
2.5 10.0
ND ND
ND
03-Dec-18
EPA 6010
2.5 5.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 7 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Lead
29-May-07
NR 10
Dry 2.9 B
6.1 J
27-Nov-07
NR 10
Dry ND
ND
NC 2B/EPA NC = 25 pg/L (03/28/08)
27-May-08
4 10.0
Dry ND
ND
04-Nov-08
4.0 10.0
Dry ND
ND
01-Jun-09
4.0 10.0
Dry ND
ND
19-Nov-09
4.0 10.0
ND ND
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
4.0 10.0
ND ND
ND
29-Nov-10
4.0 10.0
ND ND
ND
31-May-11
4.0 10.0
ND ND
ND
19-Dec-11
5.0 10.0
Dry ND
ND
29-May-12
5.0 10.0
Dry ND
ND
03-Dec-12
5.0 10.0
Dry ND
ND
10-Jun-13
5.0 10.0
ND 8.7 J
ND
28-Oct-13
5.0 10.0
ND ND
ND
05-May-14
EPA 6010
5.0 10.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 10.0
ND ND
ND
18-May-15
EPA 6010
2.5 10.0
Dry ND
ND
07-Dec-15
EPA 6010
2.5 10.0
Dry ND
ND
02-May-16
EPA 6010
2.5 10.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 10.0
Dry ND
ND
26-Jun-17
EPA 6010
2.5 10.0
Dry ND
ND
14-May-18
EPA 6010
2.5 10.0
ND ND
ND
03-Dec-18
EPA 6010
2.5 5.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 8 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Nickel
May-97
NR
50
4500
140
ND
Nov-97
NR
50
ND
ND
ND
May-98
NR
50
ND
ND
ND
Nov-98
NR
50
ND
ND
ND
May-99
NR
5
ND
ND
ND
Oct-99
NR
50
ND
ND
ND
May-00
NR
50
ND
ND
ND
Nov-00
NR
50
Dry
ND
ND
May-01
NR
50
Dry
ND
ND
Nov-01
NR
50
Dry
ND
ND
May-02
NR
50
Dry
ND
ND
Nov-02
NR
50
ND
ND
ND
May-03
NR
50
ND
ND
ND
Nov-03
NR
50
ND
ND
ND
May-04
NR
50
Dry
ND
ND
Nov-04
NR
50
ND
ND
ND
May-05
NR
50
Dry
ND
ND
Nov-05
NR
50
Dry
ND
ND
23-May-06
NR
50
Dry
ND
ND
06-Nov-06
NR
50
ND
ND
ND
29-May-07
NR
50
Dry
3.7
J
ND
27-Nov-07
NR
50
Dry
4.3
J
ND
NC 2B/EPA NC = 25 pg/L (03/28/08)
27-May-08
1.7
50.0
Dry
6.0
J
ND
04-Nov-08
1.7
50.0
Dry
7.9
B
2.2 J
01-Jun-09
1.7
50.0
Dry
4.7
J
ND
19-Nov-09
1.7
50.0
4.8
B
3.6
B
2.2 J
INC 213 = 25 ug/L (05/01/07)
14-Jun-10
1.7
50.0
14.1
J
3.3
J
ND
29-Nov-10
1.7
50.0
5.3
J
2.4
J
ND
31-May-11
1.7
50.0
7.6
B
5.2
B
2.3 J
19-Dec-11
5.0
50.0
Dry
ND
ND
29-May-12
5.0
50.0
Dry
ND
ND
03-Dec-12
5.0
50.0
Dry
ND
ND
10-Jun-13
5.0
50.0
ND
12.8
J
ND
28-Oct-13
5.0
50.0
ND
ND
ND
05-May-14
EPA 6010
5.0
50.0
ND
ND
ND
20-Oct-14
EPA 6010
5.0
50.0
ND
ND
ND
18-May-15
EPA 6010
2.5
50.0
Dry
4.4
J
ND
07-Dec-15
EPA 6010
2.5
50.0
Dry
4.7
J
ND
02-May-16
EPA 6010
2.5
50.0
Dry
3.8
J
ND
12-Dec-16
EPA 6010
2.5
50.0
Dry
4.8
J
ND
26-Jun-17
EPA 6010
2.5
50.0
Dry
5.7
J
ND
14-May-18
EPA 6010
2.5
50.0
ND
5
J
ND
03-Dec-18
EPA 6010
2.5
5.0
ND
4.3
J
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 9 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Silver
27-May-08
0.1 10.0
Dry 0.11 B
0.14 J
04-Nov-08
0.10 10.0
Dry 0.41 B
0.20 J
01-Jun-09
0.10 10.0
Dry 0.12 J
ND
19-Nov-09
0.10 10.0
ND 0.14 J
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.10 10.0
ND ND
ND
29-Nov-10
0.10 10.0
ND ND
ND
31-May-11
0.10 10.0
1.0 J 0.68 J
ND
19-Dec-11
5.0 10.0
Dry ND
ND
29-May-12
5.0 10.0
Dry ND
ND
03-Dec-12
5.0 10.0
Dry ND
ND
10-Jun-13
5.0 10.0
ND ND
ND
28-Oct-13
5.0 10.0
ND ND
ND
05-May-14
EPA 6010
5.0 10.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 10.0
ND ND
ND
18-May-15
EPA 6010
2.5 10.0
Dry ND
ND
07-Dec-15
EPA 6010
2.5 10.0
Dry ND
ND
02-May-16
EPA 6010
2.5 10.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 10.0
Dry ND
ND
26-Jun-17
EPA 6010
2.5 10.0
Dry ND
ND
14-May-18
EPA 6010
2.5 10.0
ND ND
ND
03-Dec-18
EPA 6010
2.5 5.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 10 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Thallium
Nov-97
NR 1
ND 1.0
ND
May-98
NR 1
ND ND
ND
Nov-98
NR 1
ND ND
ND
May-99
NR 2
ND ND
ND
Oct-99
NR 10
ND ND
ND
May-00
NR 10
ND ND
ND
Nov-00
NR 10
Dry ND
ND
May-01
NR 10
Dry ND
ND
Nov-01
NR 10
Dry ND
ND
May-02
NR 10
Dry ND
ND
Nov-02
NR 10
ND ND
ND
May-03
NR 10
ND ND
ND
Nov-03
NR 10
ND ND
ND
May-04
NR 10
Dry ND
ND
Nov-04
NR 10
ND ND
ND
May-05
NR 10
ND ND
ND
Nov-05
NR 10
Dry ND
ND
23-May-06
NR 10
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 5.5
Dry 0.168 J
ND
27-Nov-07
NR 5.5
Dry 0.136 J
ND
NC 2B/EPA NC = 0.24 ug/L (03/28/08)
27-May-08
3 5.5
Dry ND
ND
04-Nov-08
3.0 5.5
Dry ND
ND
01-Jun-09
3.0 5.5
Dry ND
ND
19-Nov-09
3.0 5.5
ND ND
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
3.0 5.5
3.0 J ND
ND
29-Nov-10
3.0 5.5
ND ND
ND
31-May-11
3.0 5.5
ND ND
ND
19-Dec-11
5.4 5.5
Dry ND
ND
29-May-12
5.4 5.5
Dry ND
ND
03-Dec-12
5.4 5.5
Dry ND
ND
10-Jun-13
5.4 5.5
ND ND
ND
28-Oct-13
5.4 5.5
ND ND
ND
05-May-14
EPA 6010
5.4 5.5
ND ND
ND
20-Oct-14
EPA 6010
5.4 5.5
ND ND
ND
18-May-15
EPA 6010
5.0 5.5
Dry ND
ND
07-Dec-15
EPA 6010
5.0 5.5
Dry ND
ND
02-May-16
EPA 6010
5.0 5.5
Dry ND
ND
12-Dec-16
EPA 6010
5.0 5.5
Dry ND
5.5 J
26-Jun-17
EPA 6020E
0.0 5.5
Dry 0.12 J
ND
14-May-18
EPA 6020
0.5 5.5
ND ND
ND
03-Dec-18
EPA 6020E
0.06 0.1
ND 0.11
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 11 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Vanadium
01-Jun-09
0.20 25.0
Dry 0.24 B
1.2 J
NC 2B/EPA NC = NE pg/L (03/28/08)
19-Nov-09
0.20 25.0
0.33 B 0.30 B
0.58 J
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.20 25.0
5.9 J 0.22 B
0.25 J
29-Nov-10
0.20 25.0
ND ND
ND
31-May-11
0.20 25.0
ND ND
ND
19-Dec-11
5.0 25.0
Dry ND
ND
29-May-12
5.0 25.0
Dry ND
ND
03-Dec-12
5.0 25.0
Dry ND
ND
10-Jun-13
5.0 25.0
ND 21.2 J
ND
28-Oct-13
5.0 25.0
ND ND
ND
05-May-14
EPA 6010
5.0 25.0
ND ND
ND
20-Oct-14
EPA 6010
5.0 25.0
ND ND
ND
18-May-15
EPA 6010
2.5 25.0
Dry ND
ND
07-Dec-15
EPA 6010
2.5 25.0
Dry ND
ND
02-May-16
EPA 6010
2.5 25.0
Dry ND
ND
12-Dec-16
EPA 6010
2.5 25.0
Dry ND
ND
26-Jun-17
EPA 6010
2.5 25.0
Dry ND
ND
14-May-18
EPA 6010
2.5 25.0
ND ND
ND
03-Dec-18
EPA 6010
2.5 5.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 12 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Zinc
Oct-94
NR
10
10.0
10.0
14.0
Jun-95
NR
10
ND
ND
12.0
Oct-95
NR
10
NA
46.0
ND
Oct-96
NR
10
ND
ND
NA
May-97
NR
10
40.0
10.0
ND
Nov-97
NR
10
ND
ND
NA
May-98
NR
10
ND
ND
ND
Nov-98
NR
10
ND
ND
ND
May-99
NR
5
ND
ND
ND
Oct-99
NR
50
ND
ND
ND
May-00
NR
50
ND
ND
ND
Nov-00
NR
50
Dry
ND
ND
May-01
NR
50
Dry
ND
ND
Nov-01
NR
50
Dry
ND
ND
May-02
NR
50
Dry
ND
ND
Nov-02
NR
50
ND
ND
ND
May-03
NR
50
ND
ND
ND
Nov-03
NR
50
ND
ND
ND
May-04
NR
50
Dry
ND
ND
Nov-04
NR
50
ND
ND
ND
May-05
NR
50
Dry
ND
ND
Nov-05
NR
50
Dry
ND
ND
23-May-06
NR
50
Dry
ND
ND
01-Nov-06
NR
10
ND
ND
ND
29-May-07
NR
10
Dry
1.2 B
2.0
J
27-Nov-07
NR
10
Dry
ND
ND
NC 2B/EPA NC = 50 pg/L (03/28/08)
27-May-08
0.4
10.0
Dry
2.3 B
4.8
J
04-Nov-08
0.40
10.0
Dry
ND
8.9
J
01-Jun-09
0.40
10.0
Dry
8.2 B
83.0
19-Nov-09
0.40
10.0
9.1
B
31.9
3.5
J
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.40
10.0
18.0
B
ND
10.1
29-Nov-10
0.40
10.0
8.3
J
0.44 J
ND
31-May-11
0.40
10.0
7.7
B
8.9 B
13.7
19-Dec-11
10.0
10.0
Dry
ND
ND
29-May-12
10.0
10.0
Dry
ND
ND
03-Dec-12
10.0
10.0
Dry
ND
ND
10-Jun-13
10.0
10.0
ND
30.7 B
76.3
28-Oct-13
10.0
10.0
ND
ND
ND
05-May-14
EPA 6010
10.0
10.0
ND
ND
ND
20-Oct-14
EPA 6010
10.0
10.0
ND
ND
ND
18-May-15
EPA 6010
5.0
10.0
Dry
ND
ND
07-Dec-15
EPA 6010
5.0
10.0
Dry
5.5 B
7.2
J
02-May-16
EPA 6010
5.0
10.0
Dry
ND
ND
12-Dec-16
EPA 6010
5.0
10.0
Dry
ND
ND
26-Jun-17
EPA 6010
5.0
10.0
Dry
ND
ND
14-May-18
EPA 6010
5.0
10.0
ND
ND
ND
03-Dec-18
EPA 6010
5.0
10.0
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 13 of 21

TABLE A2-3: Historical Surface Water Constituents
Sample
Collection
Analyte
Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Organic Compounds
Acetone
27-Nov-07
NR
100
Dry
4.4 B
4.3
J
NC 2B/EPA NC = 2,000 ug/L (03/28/08)
27-May-08
20
100
Dry
ND
ND
04-Nov-08
20.0
100
Dry
ND
ND
01-Jun-09
20.0
100
Dry
ND
3.2
J
19-Nov-09
2.2
100
ND
ND
3.8
J
NC 2B = NE ug/L (05/01/07)
14-Jun-10
2.2
100
5.5
B ND
8.9
J
29-Nov-10
2.2
100
ND
ND
2.3
J
31-May-11
2.2
100
5.8
B 2.3 B
3.9
J
19-Dec-11
2.2
100
Dry
ND
6.6
J
29-May-12
2.2
100
Dry
ND
ND
03-Dec-12
10.0
100.0
Dry
ND
ND
10-Jun-13
10.0
100.0
ND
ND
ND
28-Oct-13
10.0
100.0
ND
ND
ND
05-May-14
EPA 8260
10.0
100.0
ND
ND
ND
20-Oct-14
EPA 8260
10.0
100.0
ND
ND
ND
18-May-15
EPA 8260
10.0
100.0
Dry
ND
ND
07-Dec-15
EPA 8260
10.0
100.0
Dry
ND
ND
02-May-16
EPA 8260
10.0
100.0
Dry
ND
ND
12-Dec-16
EPA 8260
10.0
100.0
Dry
ND
ND
26-Jun-17
EPA 8260
10.0
100.0
Dry
20.9 B
23.0
J
14-May-18
EPA 8260
10.0
100.0
ND
ND
ND
03-Dec-18
EPA 8260
10.0
25.0
ND
ND
ND
Benzene
19-Nov-09
0.25
1.0
3.6
0.76 J
ND
Resample>
15-Feb-10
0.25
1.0
ND
NS
ND
NC 2B = 1.19 pg/L (05/01/07)
14-Jun-10
0.25
1.0
ND
ND
ND
29-Nov-10
0.25
1.0
ND
ND
ND
31-May-11
0.25
1.0
ND
ND
ND
19-Dec-11
0.25
1.0
Dry
ND
ND
29-May-12
0.25
1.0
Dry
ND
ND
03-Dec-12
0.25
1.0
Dry
ND
ND
10-Jun-13
0.25
1.0
ND
ND
ND
28-Oct-13
0.25
1.0
ND
ND
ND
05-May-14
EPA 8260
0.25
1.0
ND
ND
ND
20-Oct-14
EPA 8260
0.25
1.0
ND
ND
ND
18-May-15
EPA 8260
0.25
1.0
Dry
ND
ND
07-Dec-15
EPA 8260
0.25
1.0
Dry
ND
ND
02-May-16
EPA 8260
0.25
1.0
Dry
ND
ND
12-Dec-16
EPA 8260
0.25
1.0
Dry
ND
ND
26-Jun-17
EPA 8260
0.25
1.0
Dry
ND
ND
14-May-18
EPA 8260
0.25
1.0
ND
ND
ND
03-Dec-18
EPA 8260
0.25
1.0
ND
ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 14 of 21

TABLE A2-3: Historical Surface Water Constituents
Sample
Collection
Analyte
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Chlorobenzene
19-Nov-09
0.23 3.0
0.70 J 0.61 J
ND
NC 2B/EPA NC = 130 pg/L (03/28/08)
14-Jun-10
0.23 3.0
ND ND
ND
NC 2B = 488 pg/L (05/01/07)
29-Nov-10
0.23 3.0
ND ND
ND
31-May-11
0.23 3.0
ND ND
ND
19-Dec-11
0.23 3.0
Dry ND
ND
29-May-12
0.23 3.0
Dry ND
ND
03-Dec-12
0.23 3.0
Dry ND
ND
10-Jun-13
0.23 3.0
ND ND
ND
28-Oct-13
0.23 3.0
ND ND
ND
05-May-14
EPA 8260
0.23 3.0
ND ND
ND
20-Oct-14
EPA 8260
0.23 3.0
ND ND
ND
18-May-15
EPA 8260
0.23 3.0
Dry ND
ND
07-Dec-15
EPA 8260
0.23 3.0
Dry ND
ND
02-May-16
EPA 8260
0.23 3.0
Dry ND
ND
12-Dec-16
EPA 8260
0.23 3.0
Dry ND
ND
26-Jun-17
EPA 8260
0.23 3.0
Dry ND
ND
14-May-18
EPA 8260
0.23 3.0
ND ND
ND
03-Dec-18
EPA 8260
0.23 1.0
ND ND
I ND
1,4-Dioxane (p-Dioxane)
03-Dec-18
EPA 8260E
1.90 2.0
6.2 10.1
ND
06-May-19
Mod.
1.20 2.0
7.40
1,4-Dichlorobenzene
29-May-07
NR 1
Dry 0.94 J
ND
27-Nov-07
NR 1
Dry ND
ND
NC 2B/EPA NC = 63 pg/L (03/28/08)
27-May-08
0.33 1.0
Dry 0.64 J
ND
04-Nov-08
0.33 1.0
Dry 0.96 J
ND
01-Jun-09
0.33 1.0
Dry 0.76 J
ND
19-Nov-09
0.33 1.0
4.8 4.9
ND
NC 2B = 488 pg/L (05/01/07)
14-Jun-10
0.33 1.0
ND 0.63 J
ND
29-Nov-10
0.33 1.0
0.78 J ND
ND
31-May-11
0.33 1.0
ND 0.62 J
ND
19-Dec-11
0.33 1.0
Dry 0.68 J
ND
29-May-12
0.33 1.0
Dry 0.58 J
ND
03-Dec-12
0.33 1.0
Dry 0.51 J
ND
10-Jun-13
0.33 1.0
ND ND
ND
28-Oct-13
0.33 1.0
ND 0.55 J
ND
05-May-14
EPA 8260
0.33 1.0
ND 0.55 J
ND
20-Oct-14
EPA 8260
0.33 1.0
ND 0.64 J
ND
18-May-15
EPA 8260
0.33 1.0
Dry 0.57 J
ND
07-Dec-15
EPA 6010
0.33 1.0
Dry 0.44 J
ND
02-May-16
EPA 8260
0.33 1.0
Dry 0.43 J
ND
12-Dec-16
EPA 8260
0.33 1.0
Dry 0.51 J
ND
26-Jun-17
EPA 8260
0.33 1.0
Dry ND
ND
14-May-18
EPA 8260
0.33 1.0
ND 0.44 J
ND
03-Dec-18
EPA 8260
0.33 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 15 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
1,1-Dichloroethane
29-May-07
NR 5
Dry 2.3 J
ND
27-Nov-07
NR 5.0
Dry 0.43 J
ND
NC 2B/EPA NC = 6,700 ug/L (03/28/08)
27-May-08
0.32 5.0
Dry 0.55 J
ND
04-Nov-08
0.32 5.0
Dry 1.2 J
ND
01-Jun-09
0.32 5.0
Dry 0.41 J
ND
19-Nov-09
0.32 5.0
0.65 J 2.4 J
ND
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.32 5.0
ND 0.34 J
ND
29-Nov-10
0.32 5.0
ND ND
ND
31-May-11
0.32 5.0
ND 0.42 J
ND
19-Dec-11
0.32 5.0
Dry 0.37 J
ND
29-May-12
0.32 5.0
Dry ND
ND
03-Dec-12
0.32 5.0
Dry ND
ND
10-Jun-13
0.32 5.0
ND ND
ND
28-Oct-13
0.32 5.0
ND ND
ND
05-May-14
EPA 8260
0.32 5.0
ND ND
ND
20-Oct-14
EPA 8260
0.32 5.0
ND ND
ND
18-May-15
EPA 8260
0.32 5.0
Dry ND
ND
07-Dec-15
EPA 8260
0.32 5.0
Dry ND
ND
02-May-16
EPA 8260
0.32 5.0
Dry ND
ND
12-Dec-16
EPA 8260
0.32 5.0
Dry ND
ND
26-Jun-17
EPA 8260
0.32 5.0
Dry ND
ND
14-May-18
EPA 8260
0.32 5.0
ND ND
ND
03-Dec-18
EPA 8260
0.32 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 16 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
cis-1,2-Dichloroethene
May-03
NR 5
ND 5.0
ND
Jul-03
NR 5
Dry ND
ND
Nov-03
NR 5
ND ND
ND
May-04
NR 5
Dry ND
ND
Nov-04
NR 5
ND ND
ND
May-05
NR 5
Dry 5.0
ND
Resample>
Aug-05
NR 5
NS ND
NS
Nov-05
NR 5
Dry ND
ND
23-May-06
NR 5
Dry ND
ND
01-Nov-06
NR 5
ND ND
ND
29-May-07
NR 5
Dry 6.4
ND
27-Nov-07
NR 5
Dry 10.4
ND
NC 2B/EPA NC = 290 Ng/L (03/28/08)
27-May-08
0.19 5.0
Dry 4.2 J
N D
04-Nov-08
0.19 5.0
Dry 8.3
ND
01-Jun-09
0.19 5.0
Dry 3.9 J
ND
19-Nov-09
0.19 5.0
73.8 21.1
0.26 J
NC 2B = NE ug/L (05/01/07)
14-Jun-10
0.19 5.0
ND 3.2 J
ND
29-Nov-10
0.19 5.0
3.6 J ND
ND
31-May-11
0.19 5.0
ND 3.5 J
ND
19-Dec-11
0.19 5.0
Dry 3.4 J
ND
29-May-12
0.19 5.0
Dry 2.5 J
ND
03-Dec-12
0.19 5.0
Dry 2.5 J
ND
10-Jun-13
0.19 5.0
ND ND
ND
28-Oct-13
0.19 5.0
ND 2.3 J
ND
05-May-14
EPA 8260
0.19 5.0
ND 1.9 J
ND
20-Oct-14
EPA 8260
0.19 5.0
ND 2.2 J
ND
18-May-15
EPA 8260
0.19 5.0
Dry 1.8 J
ND
07-Dec-15
EPA 6010
0.19 5.0
Dry 1.4 J
ND
02-May-16
EPA 8260
0.19 5.0
Dry 1.0 J
ND
12-Dec-16
EPA 8260
0.19 5.0
Dry 1.9 J
ND
26-Jun-17
EPA 8260
0.19 5.0
Dry 1.5 J
ND
14-May-18
EPA 8260
0.19 5.0
ND 1.1 J
ND
03-Dec-18
EPA 8260
0.19 1.0
ND 0.97 J
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 17 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Methylene Chloride
May-97
NR 5
7.0 B ND
6.0
Nov-97
NR 5
ND ND
NA
May-98
NR 10
ND ND
ND
Nov-98
NR 5
ND ND
ND
May-99
NR 5
ND ND
ND
Oct-99
NR 10
ND ND
21.0
May-00
NR 10
ND ND
ND
Nov-00
NR 10
Dry ND
ND
May-01
NR 10
Dry ND
ND
Nov-01
NR 10
Dry ND
ND
May-02
NR 10
Dry ND
ND
Nov-02
NR 10
ND ND
ND
May-03
NR 10
ND ND
ND
Nov-03
NR 10
ND ND
ND
May-04
NR 10
Dry ND
ND
Nov-04
NR 10
ND ND
ND
May-05
NR 10
Dry ND
ND
Nov-05
NR 10
Dry ND
ND
23-May-06
NR 10
Dry ND
ND
01-Nov-06
NR 10
ND ND
ND
29-May-07
NR 1
Dry ND
ND
27-Nov-07
NR 1
Dry ND
ND
NC 2B/EPA NC = 4.6 ug/L (03/28/08)
27-May-08
0.97 2.0
Dry N D
1.5 J
04-Nov-08
0.97 2.0
Dry ND
2.8
01-Jun-09
0.97 2.0
Dry ND
ND
19-Nov-09
0.97 2.0
1.6 J ND
ND
NC 213 = NE ug/L (05/01/07)
14-Jun-10
0.97 2.0
ND ND
ND
29-Nov-10
0.97 1.0
ND ND
ND
31-May-11
0.97 1.0
ND ND
ND
19-Dec-11
0.97 1.0
Dry ND
3.3
29-May-12
0.97 1.0
Dry ND
ND
03-Dec-12
0.97 1.0
Dry ND
ND
10-Jun-13
0.97 1.0
ND ND
ND
28-Oct-13
0.97 1.0
ND ND
ND
05-May-14
EPA 8260
0.97 1.0
ND ND
2.6
20-Oct-14
EPA 8260
0.97 1.0
ND ND
ND
18-May-15
EPA 8260
0.97 1.0
Dry ND
1.3
07-Dec-15
EPA 8260
0.97 1.0
Dry ND
4.8
02-May-16
EPA 8260
0.97 1.0
Dry ND
ND
12-Dec-16
EPA 8260
0.97 1.0
Dry ND
ND
26-Jun-17
EPA 8260
0.97 1.0
Dry ND
1.3
14-May-18
EPA 8260
0.97 1.0
ND ND
ND
03-Dec-18
EPA 8260
0.97 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 18 of 21

TABLE A2-3: Historical Surface Water Constituents
Sample
Collection
Analyte
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Tetrachloroethene
19-Nov-09
0.46 1.0
1.5 ND
ND
NC 2B = 0.07ug/L (5/1/07) Resample>
15-Feb-10
0.46 1.0
ND NS
ND
NC 2B = 0.07 pg/L (05/01/07)
14-Jun-10
0.46 1.0
ND ND
ND
29-Nov-10
0.46 1.0
ND ND
ND
31-May-11
0.46 1.0
ND ND
ND
19-Dec-11
0.46 1.0
Dry ND
0.77 J
29-May-12
0.46 1.0
Dry ND
ND
03-Dec-12
0.46 1.0
Dry ND
ND
10-Jun-13
0.46 1.0
ND ND
ND
28-Oct-13
0.46 1.0
ND ND
ND
05-May-14
EPA 8260
0.46 1.0
ND ND
ND
20-Oct-14
EPA 8260
0.46 1.0
ND ND
ND
18-May-15
EPA 8260
0.46 1.0
Dry ND
ND
07-Dec-15
EPA 6010
0.46 1.0
Dry 0.64 J„
ND
02-May-16
EPA 8260
0.46 1.0
Dry ND
ND
12-Dec-16
EPA 8260
0.46 1.0
Dry ND
ND
26-Jun-17
EPA 8260
0.46 1.0
Dry ND
ND
14-May-18
EPA 8260
0.46 1.0
ND ND
ND
03-Dec-18
EPA 8260
0.46 1.0
ND ND
ND
Trichloroethene
19-Nov-09
0.47 1.0
3.6 1.4
ND
Resample>
15-Feb-10
0.47 1.0
ND NS
ND
NC 2B=2.5 pg/L (5/1/07)
14-Jun-10
0.47 1.0
ND ND
ND
29-Nov-10
0.47 1.0
ND ND
ND
31-May-11
0.47 1.0
ND ND
ND
19-Dec-11
0.47 1.0
Dry ND
ND
29-May-12
0.47 1.0
Dry ND
ND
03-Dec-12
0.47 1.0
Dry ND
ND
10-Jun-13
0.47 1.0
ND ND
ND
28-Oct-13
0.47 1.0
ND ND
ND
05-May-14
EPA 8260
0.47 1.0
ND ND
ND
20-Oct-14
EPA 8260
0.47 1.0
ND ND
ND
18-May-15
EPA 8260
0.47 1.0
Dry ND
ND
07-Dec-15
EPA 8260
0.47 1.0
Dry ND
ND
02-May-16
EPA 8260
0.47 1.0
Dry ND
ND
12-Dec-16
EPA 8260
0.47 1.0
Dry ND
ND
26-Jun-17
EPA 8260
0.47 1.0
Dry ND
ND
14-May-18
EPA 8260
0.47 1.0
ND ND
ND
03-Dec-18
EPA 8260
0.47 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 19 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Vinyl Chloride
19-Nov-09
0.62 1.0
ND 0.74 J
ND
INC 213 = 0.025 ug/L (05/01/07)
14-Jun-10
0.62 1.0
ND ND
ND
29-Nov-10
0.62 1.0
ND ND
ND
31-May-11
0.62 1.0
ND ND
ND
19-Dec-11
0.62 1.0
Dry ND
ND
29-May-12
0.62 1.0
Dry ND
ND
03-Dec-12
0.62 1.0
Dry ND
ND
10-Jun-13
0.62 1.0
ND ND
ND
28-Oct-13
0.62 1.0
ND ND
ND
05-May-14
EPA 8260
0.62 1.0
ND ND
ND
20-Oct-14
EPA 8260
0.62 1.0
ND ND
ND
18-May-15
EPA 8260
0.62 1.0
Dry ND
ND
07-Dec-15
EPA 8260
0.62 1.0
Dry ND
ND
02-May-16
EPA 8260
0.62 1.0
Dry ND
ND
12-Dec-16
EPA 8260
0.62 1.0
Dry ND
ND
26-Jun-17
EPA 8260
0.62 1.0
Dry ND
ND
14-May-18
EPA 8260
0.62 1.0
ND ND
ND
03-Dec-18
EPA 8260
0.62 1.0
ND ND
ND
Burke County -East Burke La Bella Associates
Permit No. 12-02 20 of 21

TABLE A2-3: Historical Surface Water Constituents
Analyte
Sample
Collection
Date
EPA Method
DL RL
SW-1 SW-2
Blanks
Xylene (Total)
19-Nov-09
0.66 2.0
8.8 ND
NO
NC 2B = NE pg/L (05/01/07)
14-Jun-10
0.66 2.0
ND ND
ND
29-Nov-10
0.66 2.0
ND ND
NO
31-May-11
0.66 2.0
ND ND
NO
19-Dec-11
0.66 2.0
Dry ND
NO
29-May-12
0.66 2.0
Dry ND
NO
03-Dec-12
0.66 5.0
Dry ND
NO
10-Jun-13
0.66 5.0
ND ND
NO
28-Oct-13
0.66 5.0
ND ND
NO
05-May-14
EPA 8260
0.66 5.0
ND ND
NO
20-Oct-14
EPA 8260
0.66 5.0
ND ND
NO
18-May-15
EPA 8260
0.66 5.0
Dry ND
NO
07-Dec-15
EPA 8260
0.66 5.0
Dry ND
NO
02-May-16
EPA 8260
0.66 5.0
Dry ND
NO
12-Dec-16
EPA 8260
0.66 5.0
Dry ND
NO
26-Jun-17
EPA 8260
0.66 5.0
Dry ND
NO
14-May-18
EPA 8260
0.66 5.0
ND ND
NO
03-Dec-18
I EPA 8260
1 0.66 1.0
ND NO
NO
ND
ND
Chloroform
FEW-7
ND
Notes:
RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999;
NC PQL for October 1999 -December 2006; and SWSL for December 2006 - 2017; NC PQL for 2018- present).
DL = Laboratory method deteciton limt.
ND = Not Detected at or above the laboratory RL (prior to Dec. 2006)
or the DL (after Dec. 2006).
NS = Not sampled.
NA = No data available.
NR = Not reported.
J = Estimated concentration less than the RL but greater than the DL.
B = Blank -Qualified (Concentration suspected to reflect laboratory or field contamination).
NE = Not established.
Dry = Surface water point was considered to be dry and no sample collected.
Values above the NC 2B are bold.
Surface water is classified as Water Supply IV - Highly Developed, Primary Rec., Critical Area.
Burke County -East Burke La Bella Associates
Permit No. 12-02 21 of 21

TABLE A2-4: Historical Groundwater Field Parameters
Parameter
Collection Date
MW-1
MW-2
MW-3
AMW-1
Well Depth [ft]
50.55
71.05
32.50
7.30
Conductivity
10-Jun-13
123.0
275.0
299
149.1
(at 25°C) [mS/cm]
28-Oct-13
90.1
164.5
228.2
126.2
5-May-14
94.7
209.9
234.1
123.7
20-Oct-14
119.5
186.0
254
189
18-May-15
117.0
250.0
264
135
7-Dec-15
133.0
274.0
287
170
2-May-16
86.0
177.2
241
125.4
12-Dec-16
124.5
254.0
265
176.3
26-Jun-17
126.0
228.0
268
182.3
14-Dec-17
140.0
272.0
283
200
14-May-18
123.0
275.0
299
168
3-Dec-18
96.2
187.6
244.8
124.5
6-May-19
104.0
239.9
266.3
118.90
23-J u I-19 *
--
454.7
464.7
--
pH [standard units]
10-Jun-13
5.97
5.88
5.75
5.64
28-Oct-13
5.18
5.4
5.53
5.85
5-May-14
5.53
5.53
5.61
5.61
20-Oct-14
4.69
5.39
5.49
6.85
18-May-15
5.05
5.55
5.39
6.09
7-Dec-15
5.22
5.57
5.46
6.29
2-May-16
4.79
5.08
5.15
5.55
12-Dec-16
5.46
5.84
5.6
5.94
26-Jun-17
5.51
5.24
5.18
5.61
14-Dec-17
5.54
5.87
5.73
5.95
14-May-18
5.97
5.88
5.75
6.19
3-Dec-18
5.57
5.7
6.03
5.38
6-May-19
5.56
5.84
5.58
5.73
23-Jul-19*
--
5.63
5.19
--
Burke County -East Burke LaBella Associates
Permit No. 12-02 1 of 2

TABLE A2-4: Historical Groundwater Field Parameters
Parameter
Collection Date
MW-1
MW-2
MW-3
AMW-1
Temperature [°C]
10-Jun-13
18.7
17.6
17.5
15.4
28-Oct-13
16.8
15.9
16
15.1
5-May-14
18.1
17.9
15.7
13.6
20-Oct-14
16.0
15.3
15.3
16.7
18-May-15
17.9
17.3
16.1
18
7-Dec-15
15.4
14.9
15.9
13.9
2-May-16
17.4
17.2
16.1
15.7
12-Dec-16
16.0
15.6
15.9
12.3
26-Jun-17
17.5
16.6
15.8
18.6
14-Dec-17
17.1
14.7
13.7
10.9
14-May-18
18.7
17.6
17.5
18.2
3-Dec-18
15.1
15.5
16.0
12.5
6-May-19
17.3
17.4
16.8
15.6
23-Jul-19*
--
18.6
16.7
--
Dissolved Oxygen [mg/L]
6-May-19
1.29
2.31
1.35
3.28
23-Jul-19*
--
2.93
0.69
--
Oxidation Reduction Potential [mV]
6-May-19
96.9
69.6
176.0
146.1
23-Jul-19*
--
119.6
147.9
--
Turbidity [NTU]
10-Jun-13
0.92
0.99
4.58
9.8
28-Oct-13
5.11
3.0
4.38
10.11
5-May-14
6.15
25.30
12.33
21.8
20-Oct-14
17.20
18.40
3.49
20.5
18-May-15
6.95
11.00
3.88
6.29
7-Dec-15
4.29
26.20
6.75
7.26
2-May-16
6.63
15.11
14.56
14.23
12-Dec-16
2.32
2.29
5.81
6.49
26-Jun-17
4.07
4.57
11.8
8.67
14-Dec-17
12.75
8.41
15.71
7.09
14-May-18
0.92
0.99
4.58
0.96
3-Dec-18
5.41
8.26
5.98
15.5
6-May-19
1.42
4.07
5.63
11.5
23-Jul-19*
--
3.20
4.41
--
NOTES: C` = degrees Centigrade
S.U. = Standard Units
pS/cm = microSemens per centimeter
NTU = Nephelometric Turbidity Units
ft = Feet
*= resampling event
= data not available or not sampled.
Burke County -East Burke LaBella Associates
Permit No. 12-02 2 of 2

TABLE A2-5: Historical Surface Water Field Parameters
Parameter
Collection Date
SW-1 SW-2
pH [standard units]
10-Jun-13
6.45 6.78
28-Oct-13
6.31 6.09
5-May-14
6.29 5.5
20-Oct-14
5.84 6.97
18-May-15
- 6.07
7-Dec-15
6.1
2-May-16
5.38
12-Dec-16
6.22
26-Jun-17
- 5.04
14-Dec-17
6.32 5.9
14-May-18
7.43 6.48
3-Dec-18
6.55 6.16
6-May-19
6.26 6.12
Temperature [°C]
10-Jun-13
18.3 19.5
28-Oct-13
13.8 13.7
5-May-14
15.2 14.6
20-Oct-14
14 14.2
18-May-15
- 17.7
7-Dec-15
10.4
2-May-16
16.2
12-Dec-16
8.5
26-Jun-17
- 17.6
14-Dec-17
8.9 9.5
14-May-18
18.8 18.4
3-Dec-18
12.6 12
6-May-19
16.5 16.6
Dissolved Oxygen [mg/L]
6-May-19
5.90 6.32
Oxidation Reduction Potential [mg/L]
6-May-19
145.3 155.3
Turbidity [NTU]
10-Jun-13
16.8 32.7
28-Oct-13
15.21 12.94
5-May-14
9.05 10.57
20-Oct-14
7.18 19.2
18-May-15
- 6.19
7-Dec-15
6.27
2-May-16
11.89
12-Dec-16
13.61
26-Jun-17
- 8.95
14-Dec-17
19.06 10.15
14-May-18
0 0
3-Dec-18
13.9 47.6
6-May-19
15.2 14.4
Conductivity
10-Jun-13
31.5 115.9
(at 25c) [mS/cm]
28-Oct-13
27.5 89.7
5-May-14
26.5 116.1
20-Oct-14
44.2 49.7
18-May-15
- 131
7-Dec-15
171
2-May-16
112.4
12-Dec-16
168.4
26-Jun-17
- 169.8
14-Dec-17
362 300
14-May-18
95 153
3-Dec-18
129 139
6-May-19
127.6 131.2
NOTES: °C= degrees Centigrade
S.U.= Standard Units
pS/cm= microSemens per centimeter
NTU= Nephelometric Turbidity Units
ft= Feet
- = Dry/Could not sample
Burke County -East Burke LaBella Associates
Permit No. 12-02 1 of 1