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1201_Burke_KirkseyDrive_MSWLF_GW_FID1357460_20190903
[fDENR USE ONLY ❑Paper Report [:]Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: ' 'NC DENR Environmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 26 surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.) Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 136 .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): LaBella Associates (Joyce Engineering) Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: G. Van Ness Burbach, Ph.D,, P.G. E-mail: vburbach@labellapc.com Phone: (336) 323-0092 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Kirksey Drive May 6, 2019 Burke Co. - Kirksey Dr. Landfill Morganton, NC 12-01 .0500 July 23, 2019 Environmental Status: (Check all that apply) Initial/Background Monitoring ❑X Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify) Leachate monitoring data Surface water monitoring data Other(specify) Notification attached? No. No groundwater or surface water standards were exceeded. RX Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points.. dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. G. Van Ness Burbach, Ph.D., P.G. Sr. Technical Consultant (336) 323-0092 FacilityRe_n�*senta_tiw]D Nanla gxiW) _ Title (Area Code) Telephone Number Signature Date 2211 W. Meadowview Rd Ste. 101 Greensboro, NC 27407 Facility Representative Address C-0782 NC PE Firm License Number (if applicable effective May 1, 2009) Affi,�0�@�frOes,,ional Geologist Seal AL 12 q 349 LC .-AIES NO Revised 6/2009 LaBeRa Powered by oartnershiD. August 27, 2019 Ms. Jackie Drummond North Carolina Department of Environmental Quality Division of Waste Management, Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 RE: May 2019 Semiannual Water Quality Monitoring Report Burke County Kirksey Drive Landfill, Permit No. 12-01 Project No. 2192621 Dear Ms. Drummond: Please find the attached May 2019 Semiannual Groundwater Monitoring Report for the Burke County Kirksey Drive Landfill (Permit No. 12-01). Attached are electronic versions of the complete report and all appendices for the May 2019 sampling event. Also attached is the North Carolina Environmental Monitoring Reporting Form for the May 2019 monitoring event and the laboratory EDD's. If you wish to have a hard copy of the report, drawings, or appendices, we will be happy to provide it upon your request. Please feel free to contact me at (336) 323-0092 if you have any questions regarding this report. Respectfully submitted, LaBella Associates ��Z5411r� Van Burbach, Ph.D., P.G. Sr. Technical Consultant Cc: Miles Champion - Burke County 2211 W. Meadowview Road #1o1 i Greensboro. NC 27407 p (336) 323-0092 www.LabeLLapc.com Prepared For: BOARD OF COMMISSIONERS COUNTY OF BURKE P.O. BOX 1486 MORGANTON, NORTH CAROLINA 2868o r"c" Z-7 if v Submitted by: LaBella Associates (Joyce Engineering) 2211 West Meadowview Rd. Suite 101 Greensboro, NC 27407 (336) 323-0092 NC License No. C-0782 LaBeRa Powered by partnership. MAY 2019 SEMIANNUAL WATER QUALITY MONITORING REPORT KIRKSEY DRIVE LANDFILL Permit No. 12-01 AUGUST 2019 PROJECT NO. 2192621 May 2019 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS 1.0 INTRODUCTION.................................................................................................................1 1.1 Site Information....................................................................................................... 1 1.2 Site Geology.............................................................................................................1 1.3 Regulatory Status.................................................................................................... 2 2.0 FACILITY MONITORING PROGRAM...................................................................................2 2.1 Groundwater Monitoring Program......................................................................... 2 2.2 Surface Water Monitoring Program........................................................................ 2 3.0 MAY 2019 SEMIANNUAL SAMPLING EVENT...................................................................3 3.1 Field Work................................................................................................................ 3 3.2 Laboratory Analysis and Quality Control................................................................ 4 4.0 HYDROGEOLOGY..............................................................................................................5 5.0 DATA ANALYSIS................................................................................................................6 5.1 Analytical Results and Comparisons to Standards ............................................... 6 5.1.1 Groundwater.............................................................................................................................6 5.1.2 Surface Water........................................................................................................................... 6 5.1.3 Resample Event........................................................................................................................ 7 6.0 CONCLUSION....................................................................................................................7 7.0 REFERENCES....................................................................................................................7 Burke County- Kirksey Drive Landfill, Permit No. 12-01 LaBella Associates May 2019 Semiannual Water Quality Monitoring Report August 2019 i May 2019 Semiannual Water Quality Monitoring Report Kirksey Drive Landfill Burke County, North Carolina TABLE OF CONTENTS CONTINUED Tables Table 1 May 2019 Groundwater Elevations Table 2 May 2019 Estimated Hydraulic Gradients and Velocities Table 3 May 2019 Detections Table 4 May 2019 Exceedances Table 5 May 2019 Field Parameters Figure Figure 1 Site Location Map Drawing Drawing 1 Groundwater Potentiometric Surface Map Appendices Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 1.0 INTRODUCTION 1.1 Site Information The Kirksey Drive Sanitary Landfill, Permit No. 12-01, is located in Burke County, North Carolina, approximately two miles northwest of downtown Morganton, North Carolina. The Landfill is on Kirksey Drive, which is accessed by U.S. Highway 70 (Figure 1). The landfill was operated by Burke County as a municipal solid waste (MSW) landfill between 1968 and 1985 but has been closed since 1985. 1.2 Site Geology The Kirksey Drive Landfill is located in the Inner Piedmont Belt of the Piedmont Physiographic Province in western North Carolina. The Inner Piedmont Belt is separated from the Blue Ridge Belt to the northwest by the Brevard Fault Zone and from the Charlotte and Milton Belts to the east by the Kings Mountain Shear Zone. The Inner Piedmont Belt consists primarily of amphibolite facies metamorphic rock. The rocks are predominantly thinly layered mica schist and biotite gneiss interlayered with lesser amounts of amphibolite, calc-silicate rock, hornblende gneiss, quartzite, and in rare instances, marble (Goldsmith, et. al., 1989). Protoliths of Inner Piedmont Belt rocks were mostly sedimentary (graywacke) with intermediate volcanic flows and tuffs. Numerous large and small bodies of granite and granodiorite and a few quartz diorite bodies are scattered throughout the Inner Piedmont. The history of emplacement of igneous intrusives and of structural deformation in the Inner Piedmont is complex. The rocks have been extensively folded, sheared, and faulted. Granite dikes and larger granite masses have been emplaced along shear zones and discordances. A major east -west trending lineament coincides with the course of the Catawba River in Caldwell, Burke, and Alexander Counties, but no offset has been documented. According to Goldsmith et al. (1978), the site is located in an area underlain by a rock unit comprised of gneisses and schists of various compositions, calc-silicates, and felsic metavolcanics. This unit occupies the nose of a northeast -plunging broad synclinal feature, surrounded by a unit mapped as foliated -to -massive migmatitic granitic gneiss with biotite gneiss and amphibolite, approximately three miles to the northwest and one mile to the south. Map patterns suggest that regional metamorphic foliation near the site would be generally east -west, with gentle dips. Outcrop foliations are likely to have steeper dips, with northeast -trending strikes parallel to the map -scale folds shown on the regional map of Goldsmith, et al. Approximately three miles to the east of the site is a small area around Rhodhiss Lake that has been mapped as metamorphosed granitic rock. A major diabase dike May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 1 system, oriented northwest -southeast, has been mapped over a distance of more than 40 miles and passes approximately two miles to the northeast of the site. 1.3 Regulatory Status The landfill is regulated under Rules .0500 and .0600 of the North Carolina Solid Waste Management Regulations (NCSWMR) for MSW landfills closed prior to October 9, 1993. The County monitors groundwater at the landfill in accordance with criteria set forth in Rule .0600 of the NCSWMR. 2.0 FACILITY MONITORING PROGRAM 2.1 Groundwater Monitoring Program Groundwater monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Eight active groundwater monitoring wells comprise the groundwater monitoring network at the Kirksey Drive Landfill and groundwater samples are collected semiannually. The current compliance network consists of the following monitoring wells: MW-1 (background), MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well classification and monitored geologic unit of the upper most aquifer is summarized in the table below. A site plan indicating the facility and waste boundaries in addition to monitoring well locations can be found in Drawing 1. All monitoring wells are monitored the constituents listed in Appendix I of 40 CFR Part 258 (NC Appendix 1) plus 1,4-dioxane, with the exception of well MW-1 which is damaged and unable to be monitored. Monitoring Well Date Installed Classification Monitoring Program Total Depth from TOC (ft) Lithology of Screened Interval MW-1 1992 Background .0600 35.65 Saprolite MW-2 1992 Compliance .0600 45.70 Saprolite MW-3D Feb. 27, 1998 Compliance .0600 78.40 Bedrock MW-3S 1992 Compliance .0600 26.69 Bedrock MW-4 Feb. 24, 1998 Compliance .0600 29.50 Saprolite MW-5 Feb. 24, 1998 Compliance .0600 49.80 Saprolite MW-6D Apr. 7, 2000 Compliance .0600 60.00 Bedrock MW-6S Apr. 6, 2000 Compliance .0600 25.00 Saprolite 2.2 Surface Water Monitoring Program Surface water monitoring at the Kirksey Drive Landfill is completed in accordance with the monitoring requirements of Rule .0600 of the NCSWMR. Three surface water monitoring points comprise the surface water monitoring program for the Kirksey Drive Landfill. The locations of the monitoring points are shown on Drawing 1. The NC Division of Water Resources has classified the surface water at the Kirksey May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 E Drive landfill as water supply IV. All surface water monitoring points are monitored semiannually for the NC Appendix I list of constituents plus 1,4-dioxane. Surface Point Classification Monitoring Location Program SW-1 (SMP-1) Compliance .0600 Upstream of bridge on Quarry Rd. SW-2 (SMP-2) Compliance .0600 Downstream of SW-3 SW-3 (SMP-3) Compliance .0600 24" pipe @ base of landfill along river 3.0 MAY 2019 SEMIANNUAL SAMPLING EVENT 3.1 Field Work On May 6t", 2019, personnel from LaBella Associates (formerly Joyce Engineering) visited the Kirksey Drive Landfill to purge and sample monitoring wells MW-2, MW-3D, MW-3S, MW-4, MW-5, MW-6D, and MW-6S. Well MW-1 is damaged and was not able to be monitored during this sampling event. This well should be evaluated for replacement. Depth -to -water measurements were obtained to the nearest 0.01 foot using an electronic water level indicator for all monitoring wells in the compliance network prior to purging. Groundwater elevations for the May 2019 monitoring event can be found in Table 1. Monitoring wells were purged using either disposable bailers, or a 12-volt submersible pump. Measurements of temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and at the time of sampling. Field parameters are summarized in Table 2. Prior to sampling, laboratory -supplied containers were prepared with the following information: • Monitoring well number (completed by field personnel); • Date and time of sample collection (completed by field personnel); • Initials of sampling personnel (completed by field personnel); • Project name and number (completed by the laboratory); • Chemical preservative (completed by the laboratory); and • Requested chemical analysis (completed by the laboratory). Groundwater samples from each monitoring well were collected either directly from the disposable bailers or directly from the pump discharge tube in the provided laboratory containers either immediately after purging or within 24 hours of the final purge volume. Immediately after collection, the samples were placed on ice in a laboratory -provided cooler. Analytical reports, chain of custody documents and field sampling logs are provided in Appendix 1. On July 23, 2019, personnel from LaBella were on -site to collect a detection verification sample from monitoring well MW-3D. Measurements of temperature, pH, May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 3 specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity were recorded in the site log book and on field log forms prior to purging, after each purge volume, and after sampling. Groundwater samples from the monitoring well were collected directly from the discharge tube of the 12-volt submersible pump in the provided laboratory containers either immediately after purging. Immediately after collection, the sample was placed on ice in a laboratory -provided cooler. Analytical reports, chain of custody documents and field sampling logs for the resampling event are provided in Appendix 1. Surface monitoring points SW-1, SW-2 and SW-3 were sampled during the May 2019 monitoring event. The surface water samples were collected directly from the stream by lowering a clean, unpreserved sample container into the stream flow and dispensing the water into laboratory -prepared sample containers. Care was taken to avoid sample -induced turbidity. At the time of sampling, surface water was also measured for temperature, pH, specific conductivity, dissolved oxygen, oxidation reduction potential, and turbidity and recorded in the site log book. Immediately after sample collection, the samples were placed on ice in a laboratory -provided cooler. Analytical reports, chains -of -custody, and field sampling logs are provided in Appendix 1. 3.2 Laboratory Analysis and Quality Control The May 2019 groundwater and surface water samples were submitted to Pace Analytical Services, Inc. of Huntersville, North Carolina under chain -of -custody control for analysis. LaBella requested a Level II data report for the final laboratory report. According to laboratory sample receipts, the samples were received by the laboratory on May 9t", 2019, in good condition, properly preserved, at proper temperature, and within analysis hold times. In addition to samples collected for compliance monitoring at the Kirksey Drive Landfill, a Field Blank was collected by LaBella personnel as part of the sampling event. Also, a Trip Blank was prepared by the laboratory to accompany the volatile sampling during shipment. The Field Blank was analyzed for the NC Appendix I list compounds while the Trip Blank was analyzed for NC Appendix I VOCs only. Upon receipt of the laboratory data package, the data was reviewed by LaBella personnel for the following: • General typographical errors; • Correct analyses performed and within method specified hold times; • Biased data results based on Surrogate Recoveries, Matrix Spike, Matrix Spike Duplicate, and Laboratory Control Samples; • Blank qualified data (B-flags); • Detections above the Method Reporting Limits (MRL); May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 0 Detections above the 15A NCAC 2L Groundwater Standards (NC2L), NC Interim Maximum Allowable Concentrations (IMACs), 15A NCAC 2B Surface Water Standards (NC2B), or NC Protective Values (NCPV); and • Detections that are above historical levels. Review of the laboratory analytical reports indicated that the laboratory data package was acceptable. The complete analytical data packages and chains -of -custody are included in Appendix 1. The surficial aquifer is believed to include the regolith and the underlying fractured metamorphic bedrock. The regolith consists of alluvium, residual soils, saprolite, and variably fractured and weathered layered metamorphic rock. In this regard, regolith behaves similar to unweathered bedrock, except that fractures are more numerous and better connected in the regolith, and will tend to have more isotropic hydraulic properties. Groundwater discharges into Hunting Creek to the east of the site, which flows northward to the Catawba River. A groundwater potentiometric surface map, developed from static water level data obtained in May 2019, is presented as Drawing 1. Horizontal groundwater gradients along representative flow paths were estimated from the May 2019 groundwater contours shown on Drawing 1 and are summarized in Table 2. Horizontal gradients across the site ranged from 0.0541 to 0.0894, with an average of approximately 0.0669. Linear groundwater flow velocities for wells screened in saprolite were computed using the modified Darcy equation: V = Ki/ne where V = average linear velocity, K = hydraulic conductivity, i = horizontal hydraulic gradient and ne = effective porosity. The mean of hydraulic conductivities from slug - tests conducted at the Burke County John's River facility (K = 3.28 ft/day) was used in these calculations, along with an estimated effective porosity of n = 0.20 (20%) for regolith. The estimated linear groundwater flow velocity under the facility ranged from 323 to 535 ft/year, with an average flow velocity of approximately 400.5 ft/year (Table 2). Because of our conservative estimate of effective porosity, actual groundwater velocities may be significantly less than those calculated. Also, the modified Darcy equation makes the simplified assumptions of a homogeneous and isotropic aquifer, May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 5 which may yield inaccurate results when applied to heterogeneous and/or anisotropic conditions such as are believed to exist at this site. Migration of groundwater contaminants are expected to follow the general groundwater flow paths and there are no known barriers to groundwater flow that could significantly affect plume migration or the effectiveness of the groundwater monitoring network to monitoring plume migration. The current groundwater monitoring network remains sufficient for monitoring the groundwater at this facility. 5.0 DATA ANALYSIS 5.1 Analytical Results and Comparison to Standards 5.1.1 Groundwater Inorganic and organic constituents detected in the groundwater during the May 2019 sampling event are listed in Table 3. All concentrations are reported in micrograms per liter (pg/L). Concentrations with a "J" are detected above the method detection limit (MDL) but below the method reporting limit (MRL) and are considered estimated. Bold values indicate quantified concentrations above their respective NC 2L or IMAC and can be found in Table 4. Historically detected groundwater constituents can be found in Appendix 2 (Table A2-2). During the May 2019 sampling event, the constituents detected at quantified concentrations above the MRL in the groundwater samples include: barium (all monitoring wells), cobalt (MW-2, MW-3S), copper (MW-2, MW-3S), nickel (MW-2, MW-3D), acetone (MW-2), benzene (MW-2, MW-3S, MW-3D), chlorobenzene (MW-2, MW-3S, MW-3D), chloroethane (MW-3S), ethylbenzene (MW-2), tetrachloroethene (MW-3S, MW-3D), toluene (MW-2), trichloroethene (MW-3D), vinyl chloride (MW-3D), xylene (MW-2, MW-3S), 1,1-dichloroethane (MW-3D), 1,2-dichlorobenzene (MW-2), 1,2-dichloropropane (MW-3D), 1,4-dichlorobenzene (MW-2, MW-3S, MW-3D), 2-butanone (MW-2), 2-hexanone (MW-2), 4-methyl-2-pentanone (MW-2), 1,4-dioxane (MW-2, MW-3S, MW-3D, MW-4), and cis-1,2-dichloroethene (MW-3D, MW-4). The constituents detected at quantified concentrations in exceedance of their respective NC 2L or IMAC standard during the May 2019 sampling event include: barium (MW-2), cobalt (MW-2, MW-3S), benzene (MW-2, MW-3S, MW-3D), tetrachloroethene (MW-3D), trichloroethene (MW-3D), vinyl chloride (MW-3D), 1,1- dichloroethane (MW-3D), 1,2-dichloropropane (MW-3D), 1,4-dichlorobenzene (MW-2, MW-3S), 1,4-dioxane (MW-2, MW-3S, MW-3D). In general, these detections are consistent with historical data for the site with the exception of 1,1-dichloroethane, 1,2-dichloropropane, and tetrachloroethene in monitoring well MW-3D. A resampling event for these constituents took place on July 23, 2019 (see Section 5.3.1). May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 1.1 5.1.2 Surface Water Inorganic and organic constituents detected in the surface water during the May 2019 sampling event are presented in Table 3. Historically detected surface water constituents can be found in Appendix 2 (Table A2-4). All concentrations are reported in micrograms per liter (pg/L). The NC Division of Water Resources has classified the surface water at the Kirksey Drive landfill as Water Supply IV. There were no organic or inorganic constituents detected at quantified concentrations above their respective NC 213 standards or NC Protective Values for class WS-IV waters during this sampling event except 1,4-dioxane. Inorganic constituents arsenic, barium, chromium, cobalt, nickel, and thallium, were detected at one or more of the surface water sampling locations, but not above the NC 2B surface water standards or the North Carolina Protective Value. 1,4-dioxane (p-dioxane) was detected in the surface water sample for SW-3 in exceedance of the NC Protective Value. 5.1.3 Resampling Event As stated previously, a resampling event was conducted on July 23, 2019, on monitoring well MW-3D. This sample was collected to confirm the presence of 1,1-dichloroethane, 1,2-dichloropropane, and tetrachloroethene in monitoring well MW-3D, which were in exceedance of their respective GWPS during the May 2019 sampling event. Based on the analytical results of the resampling event, the initial exceedances of 1,1-dichloroethane and 1,2-dichloropropane were refuted and the exceedance of tetrachloroethene was confirmed. The results of the resampling event are displayed in Table 4. The Burke County Kirksey Drive Landfill will continue monitoring groundwater in accordance with criteria set forth in Rules .0500 and .0600 of the NCSWMR for MSW landfills closed prior to October 9, 1993. The next scheduled semiannual sampling event is tentatively scheduled for November 2019. 7.0 REFERENCES Goldsmith, R., Milton, D.J., and Wilson, F.A., 1978, Preliminary geologic map, geologic map index, and annotated bibliography, Charlotte 1x2 degree sheet, North and South Carolina, U.S.G.S. Open File Report 78-590. Goldsmith, R., Milton, D.J., and Horton J.W., 1989, Geology of the Charlotte 1x2 degree quadrangle, in Gair, J.E., eds., Mineral resources of the Charlotte 1x2 degree quadrangle, North and South Carolina: U.S.G.S. Professional Paper 1462. May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 7 Harned, Douglas A., 1989, The Hydrogeologic Framework and a Reconnaissance of Ground -Water Quality in the Piedmont Province of North Carolina, U.S. Geological Survey, Water Resources Investigations Report 88-4130 Heath, R.C., 1989, The Piedmont ground -water system, in Ground Water in the Piedmont; Edited by Daniel, C.,White, R., and Stone, P., Proceedings published by Clemson University, pp. 1-13. Joyce Engineering, Inc., October 29, 1999. Water Quality Assessment Plan. Prepared for Burke County Kirksey Drive Landfill. LeGrand, Harry E. Sr., 1989, A Conceptual Model of Ground Water Settings in the Piedmont Region, Conference on Ground Water in the Piedmont, Charlotte, North Carolina North Carolina Dept. Environment, Health, and Natural Resources (NCDEHNR), 1995, N.C. Water Quality Monitoring Guidance Document for Solid Waste Facilities. Sumsion, C.T., and Laney, R.L., 1967, Geology and ground -water resources of the Morganton area North Carolina, N.C. Department of Water Resources, Ground Water Bulletin No. 12, P. 119 RCRA Ground Water Monitoring Technical Enforcement Guidance Document (TEGD), 1986. May 2019 Semiannual Water Quality Monitoring Report LaBella Associates Burke County - Kirksey Drive Landfill, Permit No. 12-01 August 2019 TABLES Table 1 May 2019 Groundwater Elevations Table 2 May 2019 Estimated Hydraulic Gradients and Velocities Table 3 May 2019 Detections Table 4 May 2019 Exceedances Table 5 May 2019 Field Parameters TABLE 1: May 2019 Groundwater Elevations Location TOC Elevation (ft AMSL) Depth to Groundwater (ft BTOC) Lithology Well Depth (ft BTOC) Groundwater Elevation (ft AMSL) MW-1 1119.82 24.54 Saprolite 35.65 1095.28 MW-2 1077.23 25.97 Saprolite 45.70 1051.26 MW-3S 1022.76 5.70 Bedrock 26.69 1017.06 MW-3D 1021.90 0.00 Bedrock 78.40 1021.90 MW-4 1054.99 17.79 Saprolite 29.50 1037.20 MW-5 1137.43 33.21 Saprolite 49.80 1104.22 MW-6S 1065.00 9.95 Bedrock 25.00 1055.05 MW-6D 1065.00 11.56 Saprolite 60.00 1053.44 Notes: TOC = Top of casing ft = feet BTOC = Below TOC BGS = Below ground surface AMSL = Above mean sea level Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 TABLE 2: May 2019 Hydraulic Gradients and Velocities May 2019 LINEAR GRADIENT CALCULATION SEGMENT FLOW LINE LENGTH (ft) FLOW DIRECTION GROUNDWATER ELEVATION (ft) HORIZONTAL GRADIENT i HYDRAULIC CONDUCTIVITY K (fVday) EFFECTIVE POROSITY n VELOCITY V ( r) 1090 11 783 NW 0.0894 3.28E+00 0.20 535 1020 1090 12 872 NE 0.0573 3.28E+00 0.20 343 1040 1090 13 925 N 0.0541 3.28E+00 0.20 323 1040 AVERAGE: 0.0669 AVERAGE: 400.5 Notes: The mean of K estimates from individual well slug tests from the Burke Co. John's River facility was used to calculate the hydraulic conductivity. Velocity: V = Kiln ; assumes homogeneous isotropic porous aquifer and an effective porosity of 20% (0.20). Gradient segments based on the December 03, 2018 groundwater potentiometric surface map (Drawing 1) . Burke County, Kirksey Drive Landfill Permit No. 12-01 LaBella Associates TABLE 3: May 2019 Detections Parameter MDL MRL NC 21-/ GINDowngradient IMAC* MW-2 MW-3S MW-3D MW-3D** MW-4 MW-5 MW-6S MW-6D Barium 2.5 5 700 1040 454 181 - 82.6 37.5 43.7 12.2 Chromium 2.5 5 10 2.5 J ND ND - ND ND ND ND Cobalt 2.5 5 1* 107 14.4 ND -- ND ND ND ND Copper 2.5 5 1000 8.3 5.8 3.2J - ND 3.1J ND ND Lead 2.5 5 15 4.9J 3.2J ND - ND ND ND ND Nickel 2.5 5 100 14.5 4.4J 25.7 - 3.0J ND ND ND Thallium 0.06 0.1 0.28* ND ND ND - ND 0.087J ND ND Vanadium 2.5 5 0.3 4.1J ND ND - ND ND ND ND Zinc 5 10 1,000 ND 5.91 ND - ND 7.5J ND 7.6J Acetone 10 25 6,000 299 ND ND - ND ND ND ND Benzene 0.25 1 1 10.4 4.6 1.7 - ND ND ND ND Chlorobenzene 0.23 1 50 26.6 36.4 8.7 - ND ND ND ND Chloroethane 0.54 1 3,000 ND 1.8 0.56J - ND ND ND ND Chloroform 0.58 1 70 ND ND ND - ND ND 0.67 J ND Ethylbenzene 0.3 1 600 24.1 ND ND - ND ND ND ND Methylene Chloride 0.5 1 5 ND ND 0.63J - ND ND ND ND Tetrachloroethene 0.46 1 0.7 ND ND 11.1 6.5 ND ND ND ND Toluene 0.26 1 600 4.8 ND ND - ND ND ND ND Trichloroethene 0.47 1 3 ND ND 5.9 - ND ND ND ND Vinyl Chloride 0.62 1 0.03 ND ND 1.4 - ND ND ND ND Xylene (Total) 0.66 1 500 55.8 17.7 ND - ND ND ND ND 1,1-Dichloroethane 0.32 1 6 0.68J ND 6.1 4.8 ND ND ND ND 1,2-Dichlorobenzene 0.3 1 20 2.4 0.88J ND - ND ND ND ND 1,2-Dichloropropane 0.27 1 0.6 ND ND 1.1 0.81J ND ND ND ND 1,4-Dichlorobenzene 0.33 1 6 47.3 14.6 4.8 - ND ND ND ND 2-Butanone (MEK) 0.96 5 4,000 448 ND ND - ND ND ND ND 2-Hexanone 0.46 5 280 8.0 ND ND - ND ND ND ND 4-Methyl-2-pentanone (MIBK) 0.33 5 560* 311 ND ND - ND ND ND ND 1,4-Dioxane(p-Dioxane) 1.9 2 3 218 57 128 - 2.4 ND ND ND cis-1,2-Dichloroethene 0.19 1 70 ND ND 18.7 - 1.2 ND ND ND Parameter MDL MRL NC 26 Surface Water SW-1 SW-2 I SW-3 Arsenic 5 10 150 ND ND 5.2J Barium 2.5 5 21,000^ 26.4 26.2 239 Chromium 2.5 5 123.21 ND ND 4.4J Cobalt 2.5 5 3^ ND ND 4.2J Nickel 2.5 5 87.92 ND ND 6.3J Thallium 0.06 0.1 0.24^^ ND ND 0.11 Bromomethane 0.95 2 NE ND ND 1.51 1,4-Dioxane 1.9 2 0.35^^ ND ND 7.6 Note: NC 2B values for Chromium and Nickel were calculated based on hardness results Notes: All results are in micrograms per liter (Ng/L). J = Estimated concentration below the SWSL. MDL = Method Detection Limit MRL = Method Reporting Limit NC21- = NC Groundwater Standard from 15A NCAC 2L.0202 *IMAC= NC Interim Maximum Allowable Concentration NC2B = NC Surface Water Standard from 15A NCAC 2B Surface water has been classified as Water Supply IV Bold results are exceedances of the applicable standards. ^ = NC Protective Value ^^ = EPA NRWQC (Nationally Recommended Water Quality Criteria) - = Data not available ** = Sample collected during 7/23/2019 resampling event Burke County, Kirksey Drive Landfill Permit No. 12-01 La Bella Associates TABLE 4: May 2019 Exceedances Parameter MDL MRL NC 2L /IMAC* GW Downgradient MW-2 MW-3S MW-31D MW-3D* MW-4 MW-5 MW-6S MW-61D Barium 2.5 5 700 1040 -- Cobalt 2.5 5 1* 107 14.4 -- - - - - Benzene 0.25 1 1 10.4 4.6 1.7 - - - - - Tetra chloroethene 0.46 1 0.7 -- -- 11.1 6.5 - - - - Trichloroethene 0.47 1 3 5.9 - - - - - Vinyl Chloride 0.62 1 0.03 - 1.4 - - - - - 1,1-Dichloroethane 0.32 1 6 6.1 4.8 - - - - 1,2-Dichloropropane 0.27 1 0.6 -- -- 1.1 0.81 J - - - - 1,4-Dichlorobenzene 0.33 1 6 47.3 14.6 -- -- - - - - 1,4-Dioxane 9.5 10 3 218 57 128 - - - - - Dioxane Surface Water Parameter MDL MRL NC213 SW-3 1,4-Dioxane 1.9 2 0.35 7.6 Dioxane Notes: All results are in micrograms per liter (pg/L) MDL = Method Detection Limit MRL = Method Reporting Limit J = Extimarted concentration below the MRL NC2L = INC Groundwater Standard from 15A NCAC 2L.0202 *IMAC = NC Interim Maximum Allowable Concentrations NC2B = INC Surface Water Standard from 15A NCAC 2B -- = Concentration not in exceedance of respective standard Bold Results are excedances of repective standards * = Sample collected during 7/23/2019 resampling event Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 TABLE 5: May 2019 Sampling Event Field Parameters Parameter Units Collect Date GW Upgradient Groundwater Downgradient Surface Water MW-1 MW-2 I MW-3S I MW-3D I MW-31)* I MW-4 I MW-5 I MW-6S I MW-61) SW-1 SW-2 I SW-3 Well Depth Ft. - 50.55 45.70 26.69 78.40 78.40 29.50 49.80 25.00 60.00 - - - pH S.U. 5/6/2019 - 6.01 6.49 6.17 6.00 6.66 5.86 6.56 6.08 8.51 6.98 7.92 Temperature °C 5/6/2019 - 17.3 15.4 17.0 17.3 16.1 17.4 15.1 15.5 20.1 19.4 18.5 Conductivity PS/cm 5/6/2019 - 1923 916 792 1454 59.6 23.3 50.6 85.6 96.1 91.8 986 Dissolved Oxygen mg/L 5/6/2019 - 0.92 3.59 1.09 0.91 5.18 5.73 5.44 2.13 5.89 6.14 5.93 Oxidation Reduction Potential my 5/6/2019 - 14.1 -4.6 222.3 210.5 165.4 235.3 183.1 126.9 135.0 119.8 183.3 Turbidity NTU 5/6/2019 - 5.29 11.5 0.65 3.12 5.71 17.8 22.1 5.08 11.1 10.2 17.5 Static Water Level I Ft. 1 5/6/2019 1 24.54 1 25.97 5.70 0.00 0.00 17.79 33.21 9.95 11.56 - -- - Notes: °C = degrees Centigrade S.U. = Standard Units pS/cm = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet * = Sample collected during 7/23/2019 resampling event Burke County, Kirksey Drive Landfill LaBella Associates Permit No. 12-01 FIGURE Figure 1 Site Location Map � has Yiivar 10 O 4 D 00 co soh b s �'Ler O ��zoo U 18- -r B64 us O r n� SOURCE: U.S.G.S. TOPOGRAPHIC MAP FOR NORTH MORGANTON, NC. n BUS `e o 70 ^��C 2211 WEST MEADOWVIEW ROAD SCALE PROJECT NO. FIGURE N0. 1 Y ��=��� PHONN...)O.NC,2407 1"=2000' 277 KIRKSEY DRIVE LANDFILL ENGINEERING 323-0092 02016 Joyce Engineering, lnc. SITE LOCATION MAP All nghte reservetl. J DRAWING Drawing 1 Groundwater Potentiometric Surface Map LaBella Powered by partnership. 9731-F SOUTHERN PINE BLVD CHARLOTTE, NC 28273 PHONE: 817-2037 (704) labellapc.com / SMP-1 I \ LIMITS OF WASTE-(TYP) --------------- LIMITS OF WASTE „c/ \ —Mw` _ \\��\�� \ \ \ T � — — _ 1051.26 \ // /— \ — I I SMP-SMP-2 1016.20� / 19 1, \ SMP-3 O icnW 3�/ / 1022.76/ — — G / \ \ I\ \ \ / ` © 2019 LaBella Associates \ \ O� — \ / �-- KIRKSEY DRIVE LANDFILL / _ \ >/' 10 BURKE COUNTY, NORTH CAROLINA 0 No No 1050 \O / n / •n1055.05 1060 MW-6D — — 053.44 p MW" -�. 1070 � � 080 — —� 1095,28 _ \ �`---- — — �1100 MW-5 // GRAPHIC SCALE 1104.22 0 �150 300 (FE&I NOTES LEGEND 1. TOPOGRAPHIC CONTOUR INTERVAL = 20 FEET. N0: DATE: DESCRIPTION Revisions 1080 EXISTING 100' TOPOGRAPHIC CONTOUR EXISTING ROAD 2• GROUNDWATER SURFACE CONTOUR INTERVAL = 10 FEET. PROJECT NUMBER: 2181871 EXISTING 20' TOPOGRAPHIC CONTOUR APPROXIMATE LIMITS OF WASTE 3. STATIC WATER LEVELS WERE MEASURED ON MAY 6, 2019. DRAWN BY: RH RENEWED BY: MV ISSUED FOR: GROUNDWATER REPORT OHO — — — — — GROUNDWATER SURFACE CONTOUR [FEET CENTERLINE OF STREAM 4. GROUNDWATER CONTOURS BASED ON LINEAR INTERPOLATION DATE: omens ABOVE MEAN SEA LEVEL (AMSL)] COMPLIANCE WELL LOCATION - MW-5 BETWEEN AND EXTRAPOLATION FROM KNOWN DATA, AND TOPOGRAPHIC CONTOURS, AND KNOWN FIELD CONDITIONS. DRAWING NAME: IDENTIFICATION WITH STATIC WATER — — PROPERTY LINE ELEV GROUNDWATER FLOW PATHWAY USED TO LEVEL ELEVATION (FEET AMSL) FLOW PATH LENGTH PERMIT N0. 12 01 CALCULATE HYDRAULIC GRADIENT O SW-2 SURFACE MONITORING POINT LOCATION GROUNDWATER POTENTIOMETRIC 21 SEGMENT USED FOR GRADIENT CALCULATION AND IDENTIFICATION Q 783 LF SURFACE MAP -MAY 6, 2019 Z2 872 LF DRAWING NUMBER: i3 925 LF 1 APPENDICIES Appendix 1 Laboratory Analytical Reports and Field Logs Appendix 2 Historical Data APPENDIX 1 Laboratory Analytical Reports and Field Logs aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 21, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on May 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 49 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Lab ID Sample ID Matrix Date Collected Date Received 92428710001 1201-MW2 Water 05/06/19 16:01 05/09/19 09:31 92428710002 1201-MW3S Water 05/06/19 16:46 05/09/19 09:31 92428710003 1201-MW3D Water 05/06/19 17:41 05/09/19 09:31 92428710004 1201-MW4 Water 05/06/19 18:13 05/09/19 09:31 92428710005 1201-MW5 Water 05/06/19 19:18 05/09/19 09:31 92428710006 1201-MW6S Water 05/06/19 18:25 05/09/19 09:31 92428710007 1201-MW6D Water 05/06/19 15:11 05/09/19 09:31 92428710008 1201-SW1 Water 05/06/19 17:50 05/09/19 09:31 92428710009 1201-SW2 Water 05/06/19 17:15 05/09/19 09:31 92428710010 1201-SW3 Water 05/06/19 17:25 05/09/19 09:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co Kirksey Dr Closed LF 92428710 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92428710001 1201-MW2 EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710002 1201-MW3S EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710003 1201-MW3D EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710004 1201-MW4 EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710005 1201-MW5 EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710006 1201-MW6S EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710007 1201-MW6D EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710008 1201-SW1 EPA 601 OD IDS 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710009 1201-SW2 EPA 601 OD IDS 15 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428710010 1201-SW3 EPA 601 OD IDS 15 PASI-A REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Analytes Lab ID Sample ID Method Analysts Reported Laboratory EPA 6020E JOR 1 PASI-A EPA8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co Kirksey Dr Closed LF 92428710 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92428710001 1201-MW2 EPA 601 OD Barium 1040 ug/L 5.0 05/20/19 10:08 EPA 601 OD Chromium 2.5J ug/L 5.0 05/20/19 10:08 EPA 601 OD Cobalt 107 ug/L 5.0 05/20/19 10:08 EPA 601 OD Copper 8.3 ug/L 5.0 05/20/19 10:08 EPA 601 OD Lead 4.9J ug/L 5.0 05/20/19 10:08 EPA 601 OD Nickel 14.5 ug/L 5.0 05/20/19 10:08 EPA 601 OD Vanadium 4.1 J ug/L 5.0 05/20/19 10:08 EPA 8260D 1,1-Dichloroethane 0.68J ug/L 1.0 05/16/19 00:34 EPA 8260D 1,2-Dichlorobenzene 2.4 ug/L 1.0 05/16/19 00:34 EPA 8260D 1,4-Dichlorobenzene 47.3 ug/L 1.0 05/16/19 00:34 EPA 8260D 2-Butanone (MEK) 448 ug/L 5.0 05/16/19 00:34 E,M3 EPA 8260D 2-Hexanone 8.0 ug/L 5.0 05/16/19 00:34 EPA 8260D 4-Methyl-2-pentanone (MIBK) 311 ug/L 5.0 05/16/19 00:34 E,M3 EPA 8260D Acetone 299 ug/L 25.0 05/16/19 00:34 M3 EPA 8260D Benzene 10.4 ug/L 1.0 05/16/19 00:34 EPA 8260D Chlorobenzene 26.6 ug/L 1.0 05/16/19 00:34 EPA 8260D Ethylbenzene 24.1 ug/L 1.0 05/16/19 00:34 EPA 8260D Toluene 4.8 ug/L 1.0 05/16/19 00:34 EPA 8260D Xylene (Total) 55.8 ug/L 2.0 05/16/19 00:34 EPA 8260D m&p-Xylene 48.5 ug/L 1.0 05/16/19 00:34 EPA 8260D o-Xylene 7.3 ug/L 1.0 05/16/19 00:34 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 218 ug/L 10.0 05/16/19 19:17 92428710002 1201-MW3S EPA 601 OD Barium 454 ug/L 5.0 05/20/19 10:11 EPA 601 OD Cobalt 14.4 ug/L 5.0 05/20/19 10:11 EPA 601 OD Copper 5.8 ug/L 5.0 05/20/19 10:11 EPA 601 OD Lead 3.2J ug/L 5.0 05/20/19 10:11 EPA 601 OD Nickel 4AJ ug/L 5.0 05/20/19 10:11 EPA 601 OD Zinc 5.9J ug/L 10.0 05/20/19 10:11 EPA 8260D 1,2-Dichlorobenzene 0.88J ug/L 1.0 05/16/19 01:00 EPA 8260D 1,4-Dichlorobenzene 14.6 ug/L 1.0 05/16/19 01:00 EPA 8260D Benzene 4.6 ug/L 1.0 05/16/19 01:00 EPA 8260D Chlorobenzene 36.4 ug/L 1.0 05/16/19 01:00 EPA 8260D Chloroethane 1.8 ug/L 1.0 05/16/19 01:00 EPA 8260D Xylene (Total) 17.7 ug/L 2.0 05/16/19 01:00 EPA 8260D m&p-Xylene 17.7 ug/L 1.0 05/16/19 01:00 EPA 8260D o-Xylene 0.66J ug/L 1.0 05/16/19 01:00 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 57.0 ug/L 2.0 05/17/19 12:54 92428710003 1201-MW3D EPA 601 OD Barium 181 ug/L 5.0 05/20/19 10:14 EPA 601 OD Copper 3.2J ug/L 5.0 05/20/19 10:14 EPA 601 OD Nickel 25.7 ug/L 5.0 05/20/19 10:14 EPA 8260D 1,1-Dichloroethane 6.1 ug/L 1.0 05/16/19 01:26 EPA 8260D 1,2-Dichloropropane 1.1 ug/L 1.0 05/16/19 01:26 EPA 8260D 1,4-Dichlorobenzene 4.8 ug/L 1.0 05/16/19 01:26 EPA 8260D Benzene 1.7 ug/L 1.0 05/16/19 01:26 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Pace Project No.: Burke Co Kirksey Dr Closed LF 92428710 Lab Sample ID Client Sample ID Method Parameters Result Units Report Limit Analyzed Qualifiers 92428710003 1201-MW3D EPA 8260D Chlorobenzene 8.7 ug/L 1.0 05/16/19 01:26 EPA 8260D Chloroethane 0.56J ug/L 1.0 05/16/19 01:26 EPA 8260D Methylene Chloride 0.63J ug/L 1.0 05/16/19 01:26 EPA 8260D Tetrachloroethene 11.1 ug/L 1.0 05/16/19 01:26 EPA 8260D Trichloroethene 5.9 ug/L 1.0 05/16/19 01:26 EPA 8260D Vinyl chloride 1.4 ug/L 1.0 05/16/19 01:26 EPA 8260D cis-1,2-Dichloroethene 18.7 ug/L 1.0 05/16/19 01:26 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 128 ug/L 4.0 05/20/19 12:50 92428710004 1201-MW4 EPA 6010D Barium 82.6 ug/L 5.0 05/20/19 10:17 EPA 6010D Nickel 3.OJ ug/L 5.0 05/20/19 10:17 EPA 8260D cis-1,2-Dichloroethene 1.2 ug/L 1.0 05/16/19 01:52 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 2.4 ug/L 2.0 05/17/19 13:33 92428710005 1201-MW5 EPA 6010D Barium 37.5 ug/L 5.0 05/20/19 10:21 EPA 6010D Copper 3.1 J ug/L 5.0 05/20/19 10:21 EPA 6010D Zinc 7.5J ug/L 10.0 05/20/19 10:21 EPA 6020B Thallium 0.087J ug/L 0.10 05/21/19 01:12 92428710006 1201-MW6S EPA 6010D Barium 43.7 ug/L 5.0 05/20/19 10:24 EPA 8260D Chloroform 0.67J ug/L 1.0 05/16/19 02:44 92428710007 1201-MW6D EPA 6010D Barium 12.2 ug/L 5.0 05/20/19 10:27 EPA 6010D Zinc 7.6J ug/L 10.0 05/20/19 10:27 92428710008 1201-SW1 EPA 6010D Barium 26.4 ug/L 5.0 05/20/19 10:30 EPA 6010D Hardness, Total(SM 2340B) 20500 ug/L 662 05/20/19 10:30 92428710009 1201-SW2 EPA 6010D Barium 26.2 ug/L 5.0 05/20/19 10:33 EPA 6010D Hardness, Total(SM 2340B) 20200 ug/L 662 05/20/19 10:33 92428710010 1201-SW3 EPA 6010D Arsenic 5.2J ug/L 10.0 05/18/19 20:23 EPA 6010D Barium 239 ug/L 5.0 05/18/19 20:23 EPA 6010D Chromium 4AJ ug/L 5.0 05/18/19 20:23 EPA 6010D Cobalt 4.2J ug/L 5.0 05/18/19 20:23 EPA 6010D Nickel 6.3 ug/L 5.0 05/18/19 20:23 EPA 6010D Hardness, Total(SM 2340B) 186000 ug/L 662 05/18/19 20:23 EPA 6020B Thallium 0.11 ug/L 0.10 05/21/19 05:34 EPA 8260D Bromomethane 1.51 ug/L 2.0 05/16/19 21:43 EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 7.6 ug/L 2.0 05/17/19 15:32 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW2 Lab ID: 92428710001 Collected: 05/06/19 16:01 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:08 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:08 7440-38-2 1040 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:08 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:08 7440-43-9 2.5J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-47-3 107 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-48-4 8.3 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-50-8 4.9J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7439-92-1 14.5 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:08 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-22-4 4.1J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:08 7440-62-2 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:08 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:40 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 00:34 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 00:34 71-55-6 M1 ND ug/L 1.0 0.53 1 05/16/19 00:34 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 00:34 79-00-5 0.68J ug/L 1.0 0.41 1 05/16/19 00:34 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 00:34 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 00:34 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 00:34 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 00:34 106-93-4 2.4 ug/L 1.0 0.49 1 05/16/19 00:34 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 00:34 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 00:34 78-87-5 47.3 ug/L 1.0 0.58 1 05/16/19 00:34 106-46-7 448 ug/L 5.0 3.2 1 05/16/19 00:34 78-93-3 E,M3 8.0 ug/L 5.0 0.89 1 05/16/19 00:34 591-78-6 311 ug/L 5.0 0.86 1 05/16/19 00:34 108-10-1 E,M3 299 ug/L 25.0 8.2 1 05/16/19 00:34 67-64-1 M3 ND ug/L 50.0 2.5 1 05/16/19 00:34 107-13-1 10.4 ug/L 1.0 0.20 1 05/16/19 00:34 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 00:34 74-97-5 M1 ND ug/L 1.0 0.36 1 05/16/19 00:34 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 00:34 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 00:34 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 00:34 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 00:34 56-23-5 L1,M0 26.6 ug/L 1.0 0.53 1 05/16/19 00:34 108-90-7 ND ug/L 1.0 0.52 1 05/16/19 00:34 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW2 Lab ID: 92428710001 Collected: 05/06/19 16:01 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 00:34 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 00:34 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 00:34 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 00:34 74-95-3 24.1 ug/L 1.0 0.45 1 05/16/19 00:34 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 00:34 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 00:34 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 00:34 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 00:34 127-18-4 4.8 ug/L 1.0 0.31 1 05/16/19 00:34 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 00:34 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 00:34 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 00:34 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 00:34 75-01-4 55.8 ug/L 2.0 1.5 1 05/16/19 00:34 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 00:34 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 00:34 10061-01-5 48.5 ug/L 1.0 0.92 1 05/16/19 00:34 179601-23-1 7.3 ug/L 1.0 0.54 1 05/16/19 00:34 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 00:34 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 00:34 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 00:34 110-57-6 98 %. 81-119 1 05/16/19 00:34 17060-07-0 106 %. 82-114 1 05/16/19 00:34 1868-53-7 89 %. 82-120 1 05/16/19 00:34 460-00-4 84 %. 82-109 1 05/16/19 00:34 2037-26-5 Analytical Method: EPA 8260D Mod. 218 ug/L 10.0 5.8 5 05/16/1919:17 123-91-1 104 % 50-150 5 05/16/1919:17 17060-07-0 109 % 50-150 5 05/16/1919:17 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. M1 R1 M1,R1 Page 9 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW3S Lab ID: 92428710002 Collected: 05/06/19 16:46 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:11 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:11 7440-38-2 454 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:11 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:11 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-47-3 14.4 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-48-4 5.8 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-50-8 3.2J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7439-92-1 4.4J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:11 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:11 7440-62-2 5.9J ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:11 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:47 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 01:00 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 01:00 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 01:00 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 01:00 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 01:00 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 01:00 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 01:00 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 01:00 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 01:00 106-93-4 0.88J ug/L 1.0 0.49 1 05/16/19 01:00 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 01:00 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 01:00 78-87-5 14.6 ug/L 1.0 0.58 1 05/16/19 01:00 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 01:00 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 01:00 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 01:00 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 01:00 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 01:00 107-13-1 4.6 ug/L 1.0 0.20 1 05/16/19 01:00 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 01:00 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 01:00 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 01:00 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 01:00 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 01:00 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 01:00 56-23-5 36.4 ug/L 1.0 0.53 1 05/16/19 01:00 108-90-7 1.8 ug/L 1.0 0.52 1 05/16/19 01:00 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 10 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW3S Lab ID: 92428710002 Collected: 05/06/19 16:46 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 01:00 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 01:00 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 01:00 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 01:00 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 01:00 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 01:00 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 01:00 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 01:00 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 01:00 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 01:00 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 01:00 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 01:00 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 01:00 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 01:00 75-01-4 17.7 ug/L 2.0 1.5 1 05/16/19 01:00 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 01:00 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 01:00 10061-01-5 17.7 ug/L 1.0 0.92 1 05/16/19 01:00 179601-23-1 0.66J ug/L 1.0 0.54 1 05/16/19 01:00 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 01:00 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 01:00 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 01:00 110-57-6 99 %. 81-119 1 05/16/19 01:00 17060-07-0 103 %. 82-114 1 05/16/19 01:00 1868-53-7 88 %. 82-120 1 05/16/19 01:00 460-00-4 81 %. 82-109 1 05/16/19 01:00 2037-26-5 SO Analytical Method: EPA 8260D Mod. 57.0 ug/L 2.0 1.2 1 05/17/1912:54 123-91-1 98 % 50-150 1 05/17/1912:54 17060-07-0 110 % 50-150 1 05/17/1912:54 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 11 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW3D Lab ID: 92428710003 Collected: 05/06/19 17:41 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 6010D Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:14 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:14 7440-38-2 181 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:14 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:14 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-48-4 3.2J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7439-92-1 25.7 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:14 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:14 7440-62-2 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:14 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 00:54 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 01:26 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 01:26 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 01:26 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 01:26 79-00-5 6.1 ug/L 1.0 0.41 1 05/16/19 01:26 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 01:26 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 01:26 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 01:26 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 01:26 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 01:26 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 01:26 107-06-2 1.1 ug/L 1.0 0.60 1 05/16/19 01:26 78-87-5 4.8 ug/L 1.0 0.58 1 05/16/19 01:26 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 01:26 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 01:26 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 01:26 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 01:26 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 01:26 107-13-1 1.7 ug/L 1.0 0.20 1 05/16/19 01:26 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 01:26 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 01:26 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 01:26 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 01:26 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 01:26 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 01:26 56-23-5 8.7 ug/L 1.0 0.53 1 05/16/19 01:26 108-90-7 0.56J ug/L 1.0 0.52 1 05/16/19 01:26 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 12 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW3D Lab ID: 92428710003 Collected: 05/06/19 17:41 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 01:26 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 01:26 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 01:26 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 01:26 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 01:26 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 01:26 74-88-4 0.63J ug/L 1.0 0.50 1 05/16/19 01:26 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 01:26 100-42-5 11.1 ug/L 1.0 0.78 1 05/16/19 01:26 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 01:26 108-88-3 5.9 ug/L 1.0 0.34 1 05/16/19 01:26 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 01:26 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 01:26 108-05-4 1.4 ug/L 1.0 0.60 1 05/16/19 01:26 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 01:26 1330-20-7 18.7 ug/L 1.0 0.66 1 05/16/19 01:26 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 01:26 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 01:26 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 01:26 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 01:26 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 01:26 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 01:26 110-57-6 98 %. 81-119 1 05/16/19 01:26 17060-07-0 105 %. 82-114 1 05/16/19 01:26 1868-53-7 86 %. 82-120 1 05/16/19 01:26 460-00-4 84 %. 82-109 1 05/16/19 01:26 2037-26-5 Analytical Method: EPA 8260D Mod. 128 ug/L 4.0 2.3 2 05/20/1912:50 123-91-1 93 % 50-150 2 05/20/1912:50 17060-07-0 80 % 50-150 2 05/20/1912:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 13 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW4 Lab ID: 92428710004 Collected: 05/06/19 18:13 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:17 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:17 7440-38-2 82.6 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:17 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:17 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-48-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7439-92-1 3.OJ ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:17 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:17 7440-62-2 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:17 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:08 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 01:52 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 01:52 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 01:52 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 01:52 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 01:52 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 01:52 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 01:52 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 01:52 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 01:52 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 01:52 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 01:52 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 01:52 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 01:52 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 01:52 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 01:52 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 01:52 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 01:52 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 01:52 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 01:52 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 01:52 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 01:52 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 01:52 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 01:52 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 01:52 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 01:52 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 01:52 108-90-7 ND ug/L 1.0 0.52 1 05/16/19 01:52 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 14 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW4 Lab ID: 92428710004 Collected: 05/06/19 18:13 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 01:52 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 01:52 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 01:52 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 01:52 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 01:52 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 01:52 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 01:52 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 01:52 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 01:52 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 01:52 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 01:52 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 01:52 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 01:52 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 01:52 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 01:52 1330-20-7 1.2 ug/L 1.0 0.66 1 05/16/19 01:52 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 01:52 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 01:52 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 01:52 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 01:52 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 01:52 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 01:52 110-57-6 96 %. 81-119 1 05/16/19 01:52 17060-07-0 103 %. 82-114 1 05/16/19 01:52 1868-53-7 87 %. 82-120 1 05/16/19 01:52 460-00-4 83 %. 82-109 1 05/16/19 01:52 2037-26-5 Analytical Method: EPA 8260D Mod. 2.4 ug/L 2.0 1.2 1 05/17/1913:33 123-91-1 101 % 50-150 1 05/17/1913:33 17060-07-0 114 % 50-150 1 05/17/1913:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW5 Lab ID: 92428710005 Collected: 05/06/19 19:18 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:21 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:21 7440-38-2 37.5 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:21 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:21 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-48-4 3.1J ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7439-92-1 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:21 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:21 7440-62-2 7.5J ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:21 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.087J ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:12 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 02:18 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 02:18 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 02:18 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 02:18 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 02:18 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 02:18 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 02:18 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 02:18 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 02:18 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 02:18 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 02:18 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 02:18 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 02:18 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 02:18 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 02:18 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 02:18 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 02:18 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 02:18 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 02:18 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 02:18 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 02:18 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 02:18 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 02:18 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 02:18 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 02:18 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 02:18 108-90-7 ND ug/L 1.0 0.52 1 05/16/19 02:18 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 16 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW5 Lab ID: 92428710005 Collected: 05/06/19 19:18 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 02:18 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 02:18 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 02:18 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 02:18 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 02:18 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 02:18 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 02:18 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 02:18 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 02:18 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 02:18 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 02:18 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 02:18 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 02:18 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 02:18 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 02:18 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 02:18 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 02:18 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 02:18 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 02:18 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 02:18 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 02:18 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 02:18 110-57-6 93 %. 81-119 1 05/16/19 02:18 17060-07-0 103 %. 82-114 1 05/16/19 02:18 1868-53-7 87 %. 82-120 1 05/16/19 02:18 460-00-4 83 %. 82-109 1 05/16/19 02:18 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/17/1913:53 123-91-1 97 % 50-150 1 05/17/1913:53 17060-07-0 112 % 50-150 1 05/17/1913:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW6S Lab ID: 92428710006 Collected: 05/06/19 18:25 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:24 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:24 7440-38-2 43.7 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:24 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:24 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-48-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7439-92-1 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:24 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:24 7440-62-2 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:24 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:15 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 02:44 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 02:44 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 02:44 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 02:44 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 02:44 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 02:44 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 02:44 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 02:44 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 02:44 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 02:44 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 02:44 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 02:44 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 02:44 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 02:44 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 02:44 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 02:44 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 02:44 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 02:44 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 02:44 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 02:44 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 02:44 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 02:44 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 02:44 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 02:44 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 02:44 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 02:44 108-90-7 ND ug/L 1.0 0.52 1 05/16/19 02:44 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 18 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW6S Lab ID: 92428710006 Collected: 05/06/19 18:25 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D 0.67J ug/L 1.0 0.58 1 05/16/19 02:44 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 02:44 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 02:44 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 02:44 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 02:44 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 02:44 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 02:44 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 02:44 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 02:44 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 02:44 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 02:44 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 02:44 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 02:44 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 02:44 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 02:44 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 02:44 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 02:44 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 02:44 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 02:44 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 02:44 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 02:44 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 02:44 110-57-6 96 %. 81-119 1 05/16/19 02:44 17060-07-0 103 %. 82-114 1 05/16/19 02:44 1868-53-7 87 %. 82-120 1 05/16/19 02:44 460-00-4 84 %. 82-109 1 05/16/19 02:44 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/17/1914:13 123-91-1 98 % 50-150 1 05/17/1914:13 17060-07-0 113 % 50-150 1 05/17/1914:13 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 19 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW6D Lab ID: 92428710007 Collected: 05/06/19 15:11 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Vanadium Zinc 1400111 �41 :4 9 [y :2 61.9 Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:27 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:27 7440-38-2 12.2 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:27 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:27 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-48-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7439-92-1 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:27 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-22-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:27 7440-62-2 7.6J ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:27 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:19 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 20:25 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 20:25 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 20:25 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 20:25 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 20:25 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 20:25 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 20:25 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 20:25 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 20:25 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 20:25 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 20:25 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 20:25 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 20:25 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 20:25 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 20:25 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 20:25 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 20:25 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 20:25 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 20:25 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 20:25 74-97-5 L1 ND ug/L 1.0 0.36 1 05/16/19 20:25 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 20:25 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 20:25 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 20:25 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 20:25 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 20:25 108-90-7 ND ug/L 1.0 0.52 1 05/16/19 20:25 75-00-3 v2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 20 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-MW6D Lab ID: 92428710007 Collected: 05/06/19 15:11 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/16/19 20:25 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 20:25 74-87-3 ND ug/L 1.0 0.31 1 05/16/19 20:25 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 20:25 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 20:25 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 20:25 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 20:25 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 20:25 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 20:25 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 20:25 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 20:25 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 20:25 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 20:25 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 20:25 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 20:25 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 20:25 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 20:25 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 20:25 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 20:25 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 20:25 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 20:25 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 20:25 110-57-6 98 %. 81-119 1 05/16/19 20:25 17060-07-0 107 %. 82-114 1 05/16/19 20:25 1868-53-7 89 %. 82-120 1 05/16/19 20:25 460-00-4 82 %. 82-109 1 05/16/19 20:25 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/17/1914:33 123-91-1 98 % 50-150 1 05/17/1914:33 17060-07-0 114 % 50-150 1 05/17/1914:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW1 Lab ID: 92428710008 Collected: 05/06/19 17:50 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:30 7440-36-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:30 7440-38-2 26.4 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-39-3 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:30 7440-41-7 ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:30 7440-43-9 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-47-3 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-48-4 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-50-8 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7439-92-1 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-02-0 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:30 7782-49-2 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-22-4 20500 ug/L 662 662 1 05/17/1911:00 05/20/1910:30 ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:30 7440-62-2 ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:30 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:22 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 20:51 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 20:51 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 20:51 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 20:51 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 20:51 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 20:51 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 20:51 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 20:51 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 20:51 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 20:51 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 20:51 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 20:51 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 20:51 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 20:51 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 20:51 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 20:51 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 20:51 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 20:51 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 20:51 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 20:51 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 20:51 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 20:51 75-25-2 ND ug/L 2.0 0.95 1 05/16/19 20:51 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 20:51 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 20:51 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 20:51 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 22 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW1 Lab ID: 92428710008 Collected: 05/06/19 17:50 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.52 1 05/16/19 20:51 75-00-3 ND ug/L 1.0 0.58 1 05/16/19 20:51 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 20:51 74-87-3 v2 ND ug/L 1.0 0.31 1 05/16/19 20:51 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 20:51 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 20:51 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 20:51 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 20:51 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 20:51 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 20:51 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 20:51 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 20:51 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 20:51 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 20:51 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 20:51 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 20:51 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 20:51 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 20:51 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 20:51 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 20:51 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 20:51 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 20:51 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 20:51 110-57-6 97 %. 81-119 1 05/16/19 20:51 17060-07-0 105 %. 82-114 1 05/16/19 20:51 1868-53-7 86 %. 82-120 1 05/16/19 20:51 460-00-4 83 %. 82-109 1 05/16/19 20:51 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/17/1914:52 123-91-1 101 % 50-150 1 05/17/1914:52 17060-07-0 113 % 50-150 1 05/17/1914:52 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW2 Lab ID: 92428710009 Collected: 05/06/19 17:15 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/17/1911:00 05/20/1910:33 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:33 7440-38-2 Barium 26.2 ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:33 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/17/1911:00 05/20/1910:33 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:33 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-22-4 Hardness, Total(SM 2340B) 20200 ug/L 662 662 1 05/17/19 11:00 05/20/19 10:33 Vanadium ND ug/L 5.0 2.5 1 05/17/1911:00 05/20/1910:33 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/17/1911:00 05/20/1910:33 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 01:26 7440-28-0 8260D MSV Water, Extend Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.32 1 05/16/19 21:17 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 05/16/19 21:17 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.53 1 05/16/19 21:17 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 05/16/19 21:17 79-00-5 R1 1,1-Dichloroethane ND ug/L 1.0 0.41 1 05/16/19 21:17 75-34-3 1,1-Dichloroethene ND ug/L 1.0 0.72 1 05/16/19 21:17 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 05/16/19 21:17 96-18-4 M1 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.55 1 05/16/19 21:17 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 05/16/19 21:17 106-93-4 R1 1,2-Dichlorobenzene ND ug/L 1.0 0.49 1 05/16/19 21:17 95-50-1 R1 1,2-Dichloroethane ND ug/L 1.0 0.67 1 05/16/19 21:17 107-06-2 1,2-Dichloropropane ND ug/L 1.0 0.60 1 05/16/19 21:17 78-87-5 R1 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 05/16/19 21:17 106-46-7 R1 2-Butanone (MEK) ND ug/L 5.0 3.2 1 05/16/19 21:17 78-93-3 2-Hexanone ND ug/L 5.0 0.89 1 05/16/19 21:17 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.86 1 05/16/19 21:17 108-10-1 Acetone ND ug/L 25.0 8.2 1 05/16/19 21:17 67-64-1 Acrylonitrile ND ug/L 50.0 2.5 1 05/16/19 21:17 107-13-1 Benzene ND ug/L 1.0 0.20 1 05/16/19 21:17 71-43-2 Bromochloromethane ND ug/L 1.0 0.50 1 05/16/19 21:17 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 0.36 1 05/16/19 21:17 75-27-4 R1 Bromoform ND ug/L 1.0 0.55 1 05/16/19 21:17 75-25-2 Bromomethane ND ug/L 2.0 0.95 1 05/16/19 21:17 74-83-9 Carbon disulfide ND ug/L 10.0 0.79 1 05/16/19 21:17 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 05/16/19 21:17 56-23-5 M1 Chlorobenzene ND ug/L 1.0 0.53 1 05/16/19 21:17 108-90-7 R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW2 Lab ID: 92428710009 Collected: 05/06/19 17:15 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.52 1 05/16/19 21:17 75-00-3 ND ug/L 1.0 0.58 1 05/16/19 21:17 67-66-3 R1 ND ug/L 1.0 0.38 1 05/16/19 21:17 74-87-3 v2 ND ug/L 1.0 0.31 1 05/16/19 21:17 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 21:17 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 21:17 100-41-4 R1 ND ug/L 10.0 3.1 1 05/16/19 21:17 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 21:17 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 21:17 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 21:17 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 21:17 108-88-3 R1 ND ug/L 1.0 0.34 1 05/16/19 21:17 79-01-6 R1 ND ug/L 1.0 0.51 1 05/16/19 21:17 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 21:17 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 21:17 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 21:17 1330-20-7 RS ND ug/L 1.0 0.66 1 05/16/19 21:17 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 21:17 10061-01-5 R1 ND ug/L 1.0 0.92 1 05/16/19 21:17 179601-23-1 R1 ND ug/L 1.0 0.54 1 05/16/19 21:17 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 21:17 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 21:17 10061-02-6 R1 ND ug/L 5.0 1.6 1 05/16/19 21:17 110-57-6 M1 97 %. 81-119 1 05/16/19 21:17 17060-07-0 102 %. 82-114 1 05/16/19 21:17 1868-53-7 87 %. 82-120 1 05/16/19 21:17 460-00-4 82 %. 82-109 1 05/16/19 21:17 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/17/1915:12 123-91-1 101 % 50-150 1 05/17/1915:12 17060-07-0 114 % 50-150 1 05/17/1915:12 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 25 of 49 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW3 Lab ID: 92428710010 Collected: 05/06/19 17:25 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Hardness, Total(SM 2340B) Vanadium Zinc 6020 MET ICPMS Thallium 8260D MSV Water, Extend 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) 2-Hexanone 4-Methyl-2-pentanone (MIBK) Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Date: 05/21 /2019 03:30 PM Analytical Method: EPA 601 OD Preparation Method: EPA 3010A ND ug/L 5.0 3.9 1 05/17/19 11:00 05/18/19 20:23 7440-36-0 5.2J ug/L 10.0 5.0 1 05/17/19 11:00 05/18/19 20:23 7440-38-2 239 ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-39-3 ND ug/L 1.0 0.50 1 05/17/19 11:00 05/18/19 20:23 7440-41-7 ND ug/L 1.0 0.50 1 05/17/19 11:00 05/18/19 20:23 7440-43-9 4.4J ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-47-3 4.2J ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-48-4 ND ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-50-8 ND ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7439-92-1 6.3 ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-02-0 ND ug/L 10.0 5.0 1 05/17/19 11:00 05/18/19 20:23 7782-49-2 ND ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-22-4 186000 ug/L 662 662 1 05/17/19 11:00 05/18/19 20:23 ND ug/L 5.0 2.5 1 05/17/19 11:00 05/18/19 20:23 7440-62-2 ND ug/L 10.0 5.0 1 05/17/19 11:00 05/18/19 20:23 7440-66-6 Analytical Method: EPA 6020E Preparation Method: EPA 3010A 0.11 ug/L 0.10 0.060 1 05/17/19 15:02 05/21/19 05:34 7440-28-0 Analytical Method: EPA 8260D ND ug/L 1.0 0.32 1 05/16/19 21:43 630-20-6 ND ug/L 1.0 0.38 1 05/16/19 21:43 71-55-6 ND ug/L 1.0 0.53 1 05/16/19 21:43 79-34-5 ND ug/L 1.0 0.59 1 05/16/19 21:43 79-00-5 ND ug/L 1.0 0.41 1 05/16/19 21:43 75-34-3 ND ug/L 1.0 0.72 1 05/16/19 21:43 75-35-4 ND ug/L 1.0 0.46 1 05/16/19 21:43 96-18-4 ND ug/L 2.0 0.55 1 05/16/19 21:43 96-12-8 ND ug/L 2.0 0.28 1 05/16/19 21:43 106-93-4 ND ug/L 1.0 0.49 1 05/16/19 21:43 95-50-1 ND ug/L 1.0 0.67 1 05/16/19 21:43 107-06-2 ND ug/L 1.0 0.60 1 05/16/19 21:43 78-87-5 ND ug/L 1.0 0.58 1 05/16/19 21:43 106-46-7 ND ug/L 5.0 3.2 1 05/16/19 21:43 78-93-3 ND ug/L 5.0 0.89 1 05/16/19 21:43 591-78-6 ND ug/L 5.0 0.86 1 05/16/19 21:43 108-10-1 ND ug/L 25.0 8.2 1 05/16/19 21:43 67-64-1 ND ug/L 50.0 2.5 1 05/16/19 21:43 107-13-1 ND ug/L 1.0 0.20 1 05/16/19 21:43 71-43-2 ND ug/L 1.0 0.50 1 05/16/19 21:43 74-97-5 ND ug/L 1.0 0.36 1 05/16/19 21:43 75-27-4 ND ug/L 1.0 0.55 1 05/16/19 21:43 75-25-2 1.5J ug/L 2.0 0.95 1 05/16/19 21:43 74-83-9 ND ug/L 10.0 0.79 1 05/16/19 21:43 75-15-0 ND ug/L 1.0 0.42 1 05/16/19 21:43 56-23-5 ND ug/L 1.0 0.53 1 05/16/19 21:43 108-90-7 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 Page 26 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 Sample: 1201-SW3 Lab ID: 92428710010 Collected: 05/06/19 17:25 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroethane Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/21 /2019 03:30 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.52 1 05/16/19 21:43 75-00-3 ND ug/L 1.0 0.58 1 05/16/19 21:43 67-66-3 ND ug/L 1.0 0.38 1 05/16/19 21:43 74-87-3 v2 ND ug/L 1.0 0.31 1 05/16/19 21:43 124-48-1 ND ug/L 1.0 0.62 1 05/16/19 21:43 74-95-3 ND ug/L 1.0 0.45 1 05/16/19 21:43 100-41-4 ND ug/L 10.0 3.1 1 05/16/19 21:43 74-88-4 ND ug/L 1.0 0.50 1 05/16/19 21:43 75-09-2 ND ug/L 1.0 0.50 1 05/16/19 21:43 100-42-5 ND ug/L 1.0 0.78 1 05/16/19 21:43 127-18-4 ND ug/L 1.0 0.31 1 05/16/19 21:43 108-88-3 ND ug/L 1.0 0.34 1 05/16/19 21:43 79-01-6 ND ug/L 1.0 0.51 1 05/16/19 21:43 75-69-4 ND ug/L 2.0 0.42 1 05/16/19 21:43 108-05-4 ND ug/L 1.0 0.60 1 05/16/19 21:43 75-01-4 ND ug/L 2.0 1.5 1 05/16/19 21:43 1330-20-7 ND ug/L 1.0 0.66 1 05/16/19 21:43 156-59-2 ND ug/L 1.0 0.22 1 05/16/19 21:43 10061-01-5 ND ug/L 1.0 0.92 1 05/16/19 21:43 179601-23-1 ND ug/L 1.0 0.54 1 05/16/19 21:43 95-47-6 ND ug/L 1.0 0.46 1 05/16/19 21:43 156-60-5 ND ug/L 1.0 0.30 1 05/16/19 21:43 10061-02-6 ND ug/L 5.0 1.6 1 05/16/19 21:43 110-57-6 98 %. 81-119 1 05/16/19 21:43 17060-07-0 108 %. 82-114 1 05/16/19 21:43 1868-53-7 86 %. 82-120 1 05/16/19 21:43 460-00-4 83 %. 82-109 1 05/16/19 21:43 2037-26-5 Analytical Method: EPA 8260D Mod. 7.6 ug/L 2.0 1.2 1 05/17/1915:32 123-91-1 103 % 50-150 1 05/17/1915:32 17060-07-0 113 % 50-150 1 05/17/1915:32 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 475853 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008,92428710009 METHOD BLANK: 2578601 Matrix: Water Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008,92428710009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Antimony ug/L ND 5.0 3.9 05/20/19 09:11 Arsenic ug/L ND 10.0 5.0 05/20/19 09:11 Barium ug/L ND 5.0 2.5 05/20/19 09:11 Beryllium ug/L ND 1.0 0.50 05/20/19 09:11 Cadmium ug/L 0.511 1.0 0.50 05/20/19 09:11 Chromium ug/L ND 5.0 2.5 05/20/19 09:11 Cobalt ug/L ND 5.0 2.5 05/20/19 09:11 Copper ug/L ND 5.0 2.5 05/20/19 09:11 Hardness, Total(SM 2340B) ug/L ND 662 662 05/20/19 09:11 Lead ug/L ND 5.0 2.5 05/20/19 09:11 Nickel ug/L ND 5.0 2.5 05/20/19 09:11 Selenium ug/L ND 10.0 5.0 05/20/19 09:11 Silver ug/L ND 5.0 2.5 05/20/19 09:11 Vanadium ug/L ND 5.0 2.5 05/20/19 09:11 Zinc ug/L ND 10.0 5.0 05/20/19 09:11 LABORATORY CONTROL SAMPLE: 2578602 Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Hardness, Total(SM 2340B) Lead Nickel Selenium Silver Vanadium Zinc Units Spike Conc. LCS Result LCS % Rec % Rec Limits ug/L 500 482 96 80-120 ug/L 500 462 92 80-120 ug/L 500 432 86 80-120 ug/L 500 428 86 80-120 ug/L 500 465 93 80-120 ug/L 500 449 90 80-120 ug/L 500 471 94 80-120 ug/L 500 463 93 80-120 ug/L 33100 29100 88 80-120 ug/L 500 469 94 80-120 ug/L 500 457 91 80-120 ug/L 500 477 95 80-120 ug/L 250 239 96 80-120 ug/L 500 460 92 80-120 ug/L 500 487 97 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578603 2578604 MS MSD 92428709001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 487 530 97 106 75-125 9 20 Arsenic ug/L 5.OJ 500 500 478 531 95 105 75-125 10 20 Barium ug/L 56.3 500 500 479 528 85 94 75-125 10 20 Beryllium ug/L ND 500 500 425 465 85 93 75-125 9 20 Cadmium ug/L ND 500 500 473 516 94 103 75-125 9 20 Chromium ug/L ND 500 500 447 492 89 98 75-125 10 20 Cobalt ug/L 10.6 500 500 485 533 95 105 75-125 10 20 Copper ug/L ND 500 500 457 506 91 101 75-125 10 20 Hardness, Total(SM 2340B) ug/L 27200 33100 33100 53800 59400 80 97 75-125 10 Lead ug/L ND 500 500 472 514 94 103 75-125 9 20 Nickel ug/L 5.5 500 500 463 509 92 101 75-125 9 20 Selenium ug/L ND 500 500 514 556 103 111 75-125 8 20 Silver ug/L ND 250 250 240 259 96 103 75-125 7 20 Vanadium ug/L ND 500 500 462 507 92 101 75-125 9 20 Zinc ug/L ND 500 500 505 555 100 111 75-125 10 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 475854 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92428710010 METHOD BLANK: 2578606 Associated Lab Samples: 92428710010 Parameter Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Hardness, Total(SM 2340B) Lead Nickel Selenium Silver Vanadium Zinc Matrix: Water Units Blank Result Reporting Limit MDL Analyzed ug/L ND 5.0 3.9 05/18/1919:41 ug/L ND 10.0 5.0 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 1.0 0.50 05/18/1919:41 ug/L ND 1.0 0.50 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 662 662 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 10.0 5.0 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 5.0 2.5 05/18/1919:41 ug/L ND 10.0 5.0 05/18/1919:41 Qualifiers LABORATORY CONTROL SAMPLE: 2578607 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 500 428 86 80-120 Arsenic ug/L 500 407 81 80-120 Barium ug/L 500 436 87 80-120 Beryllium ug/L 500 428 86 80-120 Cadmium ug/L 500 434 87 80-120 Chromium ug/L 500 432 86 80-120 Cobalt ug/L 500 429 86 80-120 Copper ug/L 500 434 87 80-120 Hardness, Total(SM 2340B) ug/L 33100 28600 87 80-120 Lead ug/L 500 422 84 80-120 Nickel ug/L 500 425 85 80-120 Selenium ug/L 500 420 84 80-120 Silver ug/L 250 222 89 80-120 Vanadium ug/L 500 432 86 80-120 Zinc ug/L 500 431 86 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 MATRIX SPIKE & MATRIX SPIKE Parameter DUPLICATE: 2578608 MS 92427335001 Spike Units Result Conc. MSD Spike Conc. 2578609 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Antimony ug/L ND 500 500 475 462 95 92 75-125 3 20 Arsenic ug/L ND 500 500 459 446 91 88 75-125 3 20 Barium ug/L 160 500 500 637 619 95 92 75-125 3 20 Beryllium ug/L ND 500 500 481 462 96 92 75-125 4 20 Cadmium ug/L ND 500 500 459 447 92 89 75-125 3 20 Chromium ug/L 28.3 500 500 496 482 94 91 75-125 3 20 Cobalt ug/L ND 500 500 461 445 92 89 75-125 3 20 Copper ug/L ND 500 500 479 463 96 93 75-125 3 20 Hardness, Total(SM 2340B) ug/L 206000 33100 33100 250000 243000 132 112 75-125 3 Lead ug/L ND 500 500 453 438 91 87 75-125 3 20 Nickel ug/L ND 500 500 455 442 90 88 75-125 3 20 Selenium ug/L ND 500 500 486 476 97 95 75-125 2 20 Silver ug/L ND 250 250 241 233 96 93 75-125 3 20 Vanadium ug/L ND 500 500 475 463 95 92 75-125 3 20 Zinc ug/L ND 500 500 462 448 92 89 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 476009 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008,92428710009 METHOD BLANK: 2579164 Matrix: Water Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008,92428710009 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 05/20/19 22:36 LABORATORY CONTROL SAMPLE: 2579165 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 10 100 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579166 2579167 MS MSD 92427335003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 10.3 10 103 100 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 476010 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92428710010 METHOD BLANK: 2579169 Matrix: Water Associated Lab Samples: 92428710010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 05/21/19 05:27 LABORATORY CONTROL SAMPLE: 2579170 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.8 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579171 2579172 MS MSD 92428710010 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L 0.11 10 10 10.2 10.1 101 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 28443 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Water, Extend Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006 METHOD BLANK: 128030 Matrix: Water Associated Lab Samples: 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.32 05/15/19 18:29 1,1,1-Trichloroethane ug/L ND 1.0 0.38 05/15/19 18:29 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 05/15/19 18:29 1,1,2-Trichloroethane ug/L ND 1.0 0.59 05/15/19 18:29 1,1-Dichloroethane ug/L ND 1.0 0.41 05/15/19 18:29 1,1-Dichloroethene ug/L ND 1.0 0.72 05/15/19 18:29 1,2,3-Trichloropropane ug/L ND 1.0 0.46 05/15/19 18:29 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 05/15/19 18:29 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 05/15/19 18:29 1,2-Dichlorobenzene ug/L ND 1.0 0.49 05/15/19 18:29 1,2-Dichloroethane ug/L ND 1.0 0.67 05/15/19 18:29 1,2-Dichloropropane ug/L ND 1.0 0.60 05/15/19 18:29 1,4-Dichlorobenzene ug/L ND 1.0 0.58 05/15/19 18:29 2-Butanone (MEK) ug/L ND 5.0 3.2 05/15/19 18:29 2-Hexanone ug/L ND 5.0 0.89 05/15/19 18:29 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.86 05/15/19 18:29 Acetone ug/L ND 25.0 8.2 05/15/19 18:29 Acrylonitrile ug/L ND 50.0 2.5 05/15/19 18:29 Benzene ug/L ND 1.0 0.20 05/15/19 18:29 Bromochloromethane ug/L ND 1.0 0.50 05/15/19 18:29 Bromodichloromethane ug/L ND 1.0 0.36 05/15/19 18:29 Bromoform ug/L ND 1.0 0.55 05/15/19 18:29 Bromomethane ug/L ND 2.0 0.95 05/15/19 18:29 Carbon disulfide ug/L ND 10.0 0.79 05/15/19 18:29 Carbon tetrachloride ug/L ND 1.0 0.42 05/15/19 18:29 Chlorobenzene ug/L ND 1.0 0.53 05/15/19 18:29 Chloroethane ug/L ND 1.0 0.52 05/15/19 18:29 Chloroform ug/L ND 1.0 0.58 05/15/19 18:29 Chloromethane ug/L ND 1.0 0.38 05/15/19 18:29 cis-1,2-Dichloroethene ug/L ND 1.0 0.66 05/15/19 18:29 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 05/15/19 18:29 Dibromochloromethane ug/L ND 1.0 0.31 05/15/19 18:29 Dibromomethane ug/L ND 1.0 0.62 05/15/19 18:29 Ethylbenzene ug/L ND 1.0 0.45 05/15/19 18:29 lodomethane ug/L ND 10.0 3.1 05/15/19 18:29 m&p-Xylene ug/L ND 1.0 0.92 05/15/19 18:29 Methylene Chloride ug/L ND 1.0 0.50 05/15/19 18:29 o-Xylene ug/L ND 1.0 0.54 05/15/19 18:29 Styrene ug/L ND 1.0 0.50 05/15/19 18:29 Tetrachloroethene ug/L ND 1.0 0.78 05/15/19 18:29 Toluene ug/L ND 1.0 0.31 05/15/19 18:29 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 METHOD BLANK: 128030 Associated Lab Samples: Parameter Matrix: Water 92428710001, 92428710002, 92428710003, 92428710004, 92428710005, 92428710006 Blank Reporting Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.46 05/15/19 18:29 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 05/15/19 18:29 trans-1,4-Dichloro-2-butene ug/L ND 5.0 1.6 05/15/19 18:29 Trichloroethene ug/L ND 1.0 0.34 05/15/19 18:29 Trichlorofluoromethane ug/L ND 1.0 0.51 05/15/19 18:29 Vinyl acetate ug/L ND 2.0 0.42 05/15/19 18:29 Vinyl chloride ug/L ND 1.0 0.60 05/15/19 18:29 Xylene (Total) ug/L ND 2.0 1.5 05/15/19 18:29 1,2-Dichloroethane-d4 (S) %. 96 81-119 05/15/19 18:29 4-Bromofluorobenzene (S) %. 86 82-120 05/15/19 18:29 Dibromofluoromethane (S) %. 101 82-114 05/15/19 18:29 Toluene-d8 (S) %. 84 82-109 05/15/19 18:29 LABORATORY CONTROL SAMPLE: Parameter 128031 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.2 106 68-137 1,1,1-Trichloroethane ug/L 50 60.6 121 72-134 1,1,2,2-Tetrachloroethane ug/L 50 44.5 89 51-158 1,1,2-Trichloroethane ug/L 50 56.8 114 78-131 1,1-Dichloroethane ug/L 50 58.2 116 69-151 1,1-Dichloroethene ug/L 50 56.5 113 64-158 1,2,3-Trichloropropane ug/L 50 41.7 83 78-133 1,2-Dibromo-3-chloropropane ug/L 50 43.2 86 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.7 113 71-134 1,2-Dichlorobenzene ug/L 50 49.7 99 70-135 1,2-Dichloroethane ug/L 50 56.7 113 72-129 1,2-Dichloropropane ug/L 50 52.5 105 64-135 1,4-Dichlorobenzene ug/L 50 47.6 95 70-131 2-Butanone (MEK) ug/L 100 94.0 94 52-143 2-Hexanone ug/L 100 79.9 80 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 89.1 89 71-129 Acetone ug/L 100 119 119 48-224 Acrylonitrile ug/L 200 188 94 66-154 Benzene ug/L 50 57.8 116 68-132 Bromochloromethane ug/L 50 66.5 133 73-133 Bromodichloromethane ug/L 50 49.2 98 67-121 Bromoform ug/L 50 48.6 97 57-125 Bromomethane ug/L 50 44.5 89 35-156 Carbon disulfide ug/L 100 97.3 97 47-141 Carbon tetrachloride ug/L 50 61.6 123 66-122 L1 Chlorobenzene ug/L 50 48.5 97 71-126 Chloroethane ug/L 50 43.4 87 43-143 Chloroform ug/L 50 58.8 118 71-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 LABORATORY CONTROL SAMPLE: Parameter 128031 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 m&p-Xylene ug/L 100 Methylene Chloride ug/L 50 o-Xylene ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 100 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 50 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. LCS % Rec % Rec Limits 42.9 86 47-123 62.6 125 74-131 49.7 99 78-120 55.7 111 65-115 61.0 122 79-129 48.6 97 68-129 117 117 49-154 101 101 67-137 58.1 116 61-147 53.2 106 52-141 54.6 109 77-128 63.5 127 51-139 54.0 108 60-133 58.0 116 69-144 49.5 99 74-128 62.3 62 61-139 47.6 95 73-126 52.1 104 55-132 41.4 83 52-141 48.3 97 50-133 154 103 78-132 96 81-119 89 82-120 112 82-114 82 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032 MS 92428710001 Spike Parameter Units Result Conc. MSD Spike Conc. 128033 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 49.1 53.5 98 107 68-137 9 11 1,1,1-Trichloroethane ug/L ND 50 50 68.1 71.3 136 143 66-142 5 11 M1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 43.9 47.2 88 94 39-171 7 13 1,1,2-Trichloroethane ug/L ND 50 50 55.3 59.2 111 118 73-136 7 12 1,1-Dichloroethane ug/L 0.68J 50 50 60.9 62.9 120 125 66-155 3 15 1,1-Dichloroethene ug/L ND 50 50 65.8 68.9 132 138 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 39.8 43.1 80 86 78-133 8 14 1,2-Dibromo-3- ug/L ND 50 50 46.3 48.5 93 97 58-124 5 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 54.1 58.6 108 117 71-134 8 12 1,2-Dichlorobenzene ug/L 2.4 50 50 51.4 53.8 98 103 69-135 5 10 1,2-Dichloroethane ug/L ND 50 50 55.0 55.8 110 112 36-159 1 10 1,2-Dichloropropane ug/L ND 50 50 51.3 55.2 103 110 68-132 7 11 1,4-Dichlorobenzene ug/L 47.3 50 50 95.7 97.4 97 100 49-153 2 9 2-Butanone (MEK) ug/L 448 100 100 544 551 96 103 10-189 1 23 M3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032 MS 92428710001 Spike Parameter Units Result Conc. MSD Spike Conc. 128033 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 2-Hexanone ug/L 8.0 100 100 83.0 88.5 75 81 40-135 6 18 4-Methyl-2-pentanone ug/L 311 100 100 440 454 129 143 30-177 3 10 M3 (MIBK) Acetone ug/L 299 100 100 403 407 104 108 44-223 1 14 M3 Acrylonitrile ug/L ND 200 200 180 194 90 97 13-189 8 12 Benzene ug/L 10.4 50 50 69.4 72.2 118 124 66-139 4 10 Bromochloromethane ug/L ND 50 50 66.1 69.6 132 139 73-133 5 13 M1 Bromodichloromethane ug/L ND 50 50 47.8 51.1 96 102 57-120 7 13 Bromoform ug/L ND 50 50 46.1 50.3 92 101 48-128 9 13 Bromomethane ug/L ND 50 50 29.7 38.7 59 77 10-187 26 32 Carbon disulfide ug/L ND 100 100 113 120 113 120 47-141 6 322 Carbon tetrachloride ug/L ND 50 50 69.4 73.6 139 147 58-127 6 14 MO Chlorobenzene ug/L 26.6 50 50 73.1 77.6 93 102 63-137 6 10 Chloroethane ug/L ND 50 50 47.2 47.7 93 94 52-146 1 16 Chloroform ug/L ND 50 50 58.8 61.7 118 123 74-137 5 9 Chloromethane ug/L ND 50 50 45.7 47.1 91 94 41-127 3 10 cis-1,2-Dichloroethene ug/L ND 50 50 62.0 64.0 124 128 71-138 3 16 cis-1,3-Dichloropropene ug/L ND 50 50 45.4 49.0 91 98 32-145 8 12 Dibromochloromethane ug/L ND 50 50 51.5 55.4 103 111 52-116 7 13 Dibromomethane ug/L ND 50 50 57.6 62.1 115 124 79-129 7 14 Ethylbenzene ug/L 24.1 50 50 72.7 77.0 97 106 31-174 6 10 lodomethane ug/L ND 100 100 113 122 113 122 49-154 8 30 m&p-Xylene ug/L 48.5 100 100 150 159 102 111 27-179 6 10 Methylene Chloride ug/L ND 50 50 57.2 58.7 114 117 61-146 3 15 o-Xylene ug/L 7.3 50 50 59.5 63.1 104 111 52-141 6 65 Styrene ug/L ND 50 50 53.1 57.8 106 116 77-128 9 14 Tetrachloroethene ug/L ND 50 50 66.8 70.8 134 142 36-155 6 14 Toluene ug/L 4.8 50 50 59.2 63.5 109 117 52-146 7 11 trans-1,2-Dichloroethene ug/L ND 50 50 63.8 65.0 128 130 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 45.2 48.8 90 98 37-146 8 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 52.8 65.6 53 66 61-139 22 12 M1,R1 Trichloroethene ug/L ND 50 50 48.1 52.2 96 104 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.1 71.4 134 143 51-141 6 13 M1 Vinyl acetate ug/L ND 50 50 65.1 32.4 130 65 52-141 67 14 R1 Vinyl chloride ug/L ND 50 50 56.9 59.9 113 119 22-156 5 26 Xylene (Total) ug/L 55.8 150 150 210 222 102 111 78-132 6 7 1,2-Dichloroethane-d4 (S) %. 98 97 81-119 4-Bromofluorobenzene (S) %. 88 86 82-120 Dibromofluoromethane (S) %. 109 111 82-114 Toluene-d8 (S) %. 82 83 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 37 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 28498 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Water, Extend Associated Lab Samples: 92428710007, 92428710008, 92428710009, 92428710010 METHOD BLANK: 128350 Matrix: Water Associated Lab Samples: 92428710007, 92428710008, 92428710009, 92428710010 Blank Reporting Parameter Units Result Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.32 05/16/19 18:41 1,1,1-Trichloroethane ug/L ND 1.0 0.38 05/16/19 18:41 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 05/16/19 18:41 1,1,2-Trichloroethane ug/L ND 1.0 0.59 05/16/19 18:41 1,1-Dichloroethane ug/L ND 1.0 0.41 05/16/19 18:41 1,1-Dichloroethene ug/L ND 1.0 0.72 05/16/19 18:41 1,2,3-Trichloropropane ug/L ND 1.0 0.46 05/16/19 18:41 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 05/16/19 18:41 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 05/16/19 18:41 1,2-Dichlorobenzene ug/L ND 1.0 0.49 05/16/19 18:41 1,2-Dichloroethane ug/L ND 1.0 0.67 05/16/19 18:41 1,2-Dichloropropane ug/L ND 1.0 0.60 05/16/19 18:41 1,4-Dichlorobenzene ug/L ND 1.0 0.58 05/16/19 18:41 2-Butanone (MEK) ug/L ND 5.0 3.2 05/16/19 18:41 2-Hexanone ug/L ND 5.0 0.89 05/16/19 18:41 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.86 05/16/19 18:41 Acetone ug/L ND 25.0 8.2 05/16/19 18:41 Acrylonitrile ug/L ND 50.0 2.5 05/16/19 18:41 Benzene ug/L ND 1.0 0.20 05/16/19 18:41 Bromochloromethane ug/L ND 1.0 0.50 05/16/19 18:41 Bromodichloromethane ug/L ND 1.0 0.36 05/16/19 18:41 Bromoform ug/L ND 1.0 0.55 05/16/19 18:41 Bromomethane ug/L ND 2.0 0.95 05/16/19 18:41 Carbon disulfide ug/L ND 10.0 0.79 05/16/19 18:41 Carbon tetrachloride ug/L ND 1.0 0.42 05/16/19 18:41 Chlorobenzene ug/L ND 1.0 0.53 05/16/19 18:41 Chloroethane ug/L ND 1.0 0.52 05/16/19 18:41 Chloroform ug/L ND 1.0 0.58 05/16/19 18:41 Chloromethane ug/L ND 1.0 0.38 05/16/19 18:41 cis-1,2-Dichloroethene ug/L ND 1.0 0.66 05/16/19 18:41 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 05/16/19 18:41 Dibromochloromethane ug/L ND 1.0 0.31 05/16/19 18:41 Dibromomethane ug/L ND 1.0 0.62 05/16/19 18:41 Ethylbenzene ug/L ND 1.0 0.45 05/16/19 18:41 lodomethane ug/L ND 10.0 3.1 05/16/19 18:41 m&p-Xylene ug/L ND 1.0 0.92 05/16/19 18:41 Methylene Chloride ug/L ND 1.0 0.50 05/16/19 18:41 o-Xylene ug/L ND 1.0 0.54 05/16/19 18:41 Styrene ug/L ND 1.0 0.50 05/16/19 18:41 Tetrachloroethene ug/L ND 1.0 0.78 05/16/19 18:41 Toluene ug/L ND 1.0 0.31 05/16/19 18:41 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 METHOD BLANK: 128350 Associated Lab Samples: Parameter Matrix: Water 92428710007, 92428710008, 92428710009, 92428710010 Blank Reporting Units Result Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.46 05/16/19 18:41 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 05/16/19 18:41 trans-1,4-Dichloro-2-butene ug/L ND 5.0 1.6 05/16/19 18:41 Trichloroethene ug/L ND 1.0 0.34 05/16/19 18:41 Trichlorofluoromethane ug/L ND 1.0 0.51 05/16/19 18:41 Vinyl acetate ug/L ND 2.0 0.42 05/16/19 18:41 Vinyl chloride ug/L ND 1.0 0.60 05/16/19 18:41 Xylene (Total) ug/L ND 2.0 1.5 05/16/19 18:41 1,2-Dichloroethane-d4 (S) %. 96 81-119 05/16/19 18:41 4-Bromofluorobenzene (S) %. 88 82-120 05/16/19 18:41 Dibromofluoromethane (S) %. 101 82-114 05/16/19 18:41 Toluene-d8 (S) %. 81 82-109 05/16/19 18:41 SO LABORATORY CONTROL SAMPLE: Parameter 128351 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 54.1 108 68-137 1,1,1-Trichloroethane ug/L 50 62.3 125 72-134 1,1,2,2-Tetrachloroethane ug/L 50 46.1 92 51-158 1,1,2-Trichloroethane ug/L 50 59.4 119 78-131 1,1-Dichloroethane ug/L 50 58.3 117 69-151 1,1-Dichloroethene ug/L 50 55.4 111 64-158 1,2,3-Trichloropropane ug/L 50 45.0 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 45.9 92 58-124 1,2-Dibromoethane (EDB) ug/L 50 57.0 114 71-134 1,2-Dichlorobenzene ug/L 50 51.7 103 70-135 1,2-Dichloroethane ug/L 50 56.8 114 72-129 1,2-Dichloropropane ug/L 50 52.0 104 64-135 1,4-Dichlorobenzene ug/L 50 50.2 100 70-131 2-Butanone (MEK) ug/L 100 84.5 84 52-143 2-Hexanone ug/L 100 83.6 84 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 92.5 93 71-129 Acetone ug/L 100 73.8 74 48-224 Acrylonitrile ug/L 200 189 95 66-154 Benzene ug/L 50 57.6 115 68-132 Bromochloromethane ug/L 50 69.3 139 73-133 L1 Bromodichloromethane ug/L 50 50.8 102 67-121 Bromoform ug/L 50 51.5 103 57-125 Bromomethane ug/L 50 43.3 87 35-156 Carbon disulfide ug/L 100 98.3 98 47-141 Carbon tetrachloride ug/L 50 60.9 122 66-122 Chlorobenzene ug/L 50 49.3 99 71-126 Chloroethane ug/L 50 41.7 83 43-143 Chloroform ug/L 50 58.5 117 71-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 39 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 LABORATORY CONTROL SAMPLE: Parameter 128351 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 m&p-Xylene ug/L 100 Methylene Chloride ug/L 50 o-Xylene ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 100 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 50 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. LCS % Rec % Rec Limits Qualifiers 40.2 80 47-123 v2 63.5 127 74-131 52.1 104 78-120 55.6 111 65-115 62.7 125 79-129 49.5 99 68-129 111 111 49-154 103 103 67-137 58.2 116 61-147 53.7 107 52-141 56.4 113 77-128 64.9 130 51-139 55.5 111 60-133 59.3 119 69-144 51.9 104 74-128 65.8 66 61-139 49.7 99 73-126 51.7 103 55-132 47.0 94 52-141 47.1 94 50-133 157 105 78-132 94 81-119 90 82-120 112 82-114 83 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128504 MS 92428710009 Spike Parameter Units Result Conc. MSD Spike Conc. 128505 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 41.9 46.7 84 93 68-137 11 11 1,1,1-Trichloroethane ug/L ND 50 50 57.9 62.0 116 124 66-142 7 11 1,1,2,2-Tetrachloroethane ug/L ND 50 50 33.3 36.9 67 74 39-171 10 13 1,1,2-Trichloroethane ug/L ND 50 50 44.4 52.1 89 104 73-136 16 12 R1 1,1-Dichloroethane ug/L ND 50 50 50.9 54.8 102 110 66-155 8 15 1,1-Dichloroethene ug/L ND 50 50 60.0 66.6 120 133 33-181 10 34 1,2,3-Trichloropropane ug/L ND 50 50 30.8 34.1 62 68 78-133 10 14 M1 1,2-Dibromo-3- ug/L ND 50 50 29.7 33.3 59 67 58-124 11 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 44.1 50.4 88 101 71-134 13 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 37.6 44.3 75 89 69-135 16 10 R1 1,2-Dichloroethane ug/L ND 50 50 47.4 51.7 95 103 36-159 9 10 1,2-Dichloropropane ug/L ND 50 50 42.3 49.1 85 98 68-132 15 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 35.7 42.2 71 84 49-153 17 9 R1 2-Butanone (MEK) ug/L ND 100 100 67.0 63.9 67 64 10-189 5 23 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 40 of 49 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128504 128505 Parameter Units 2-Hexanone ug/L 4-Methyl-2-pentanone ug/L (MIBK) Acetone ug/L Acrylonitrile ug/L Benzene ug/L Bromochloromethane ug/L Bromodichloromethane ug/L Bromoform ug/L Bromomethane ug/L Carbon disulfide ug/L Carbon tetrachloride ug/L Chlorobenzene ug/L Chloroethane ug/L Chloroform ug/L Chloromethane ug/L cis-1,2-Dichloroethene ug/L cis-1,3-Dichloropropene ug/L Dibromochloromethane ug/L Dibromomethane ug/L Ethylbenzene ug/L lodomethane ug/L m&p-Xylene ug/L Methylene Chloride ug/L o-Xylene ug/L Styrene ug/L Tetrachloroethene ug/L Toluene ug/L trans-1,2-Dichloroethene ug/L trans-1,3-Dichloropropene ug/L trans-1,4-Dichloro-2-butene ug/L Trichloroethene ug/L Trichlorofluoromethane ug/L Vinyl acetate ug/L Vinyl chloride ug/L Xylene (Total) ug/L 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. MS MSD 92428710009 Spike Spike MS MSD Result Conc. Conc. Result Result ND 100 100 59.3 66.1 ND 100 100 67.2 69.9 ND 100 100 69.5 71.1 ND 200 200 154 160 ND 50 50 49.6 54.6 ND 50 50 56.8 61.1 ND 50 50 40.3 46.4 ND 50 50 37.9 42.3 ND 50 50 34.9 41.7 ND 100 100 104 113 ND 50 50 60.4 64.1 ND 50 50 39.0 43.7 ND 50 50 41.3 42.2 ND 50 50 49.5 55.2 ND 50 50 37.9 41.8 ND 50 50 51.8 58.4 ND 50 50 37.3 42.6 ND 50 50 43.8 50.0 ND 50 50 48.5 55.6 ND 50 50 39.6 44.2 ND 100 100 108 118 ND 100 100 81.4 91.8 ND 50 50 48.0 55.9 ND 50 50 42.0 47.1 ND 50 50 43.2 49.0 ND 50 50 53.5 61.8 ND 50 50 45.4 51.5 ND 50 50 53.1 59.5 ND 50 50 37.1 42.4 ND 100 100 46.1 50.7 ND 50 50 40.5 46.5 ND 50 50 59.8 66.4 ND 50 50 53.0 57.0 ND 50 50 47.9 51.8 ND 150 150 123 139 MS % Rec 59 67 69 77 99 114 81 76 70 104 121 78 83 99 76 104 75 88 97 79 108 81 96 84 86 107 91 106 74 46 81 120 106 96 82 97 86 109 82 MSD % Rec % Rec Limits 66 40-135 70 30-177 71 44-223 80 13-189 109 66-139 122 73-133 93 57-120 85 48-128 83 10-187 113 47-141 128 58-127 87 63-137 84 52-146 110 74-137 84 41-127 117 71-138 85 32-145 100 52-116 111 79-129 88 31-174 118 49-154 92 27-179 112 61-146 94 52-141 98 77-128 124 36-155 103 52-146 119 61-152 85 37-146 51 61-139 93 61-141 133 51-141 114 52-141 104 22-156 93 78-132 96 81-119 89 82-120 109 82-114 82 82-109 Max RPD RPD Qual 11 18 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. 2 14 4 12 10 10 7 13 14 13 R1 11 13 18 32 9 322 6 14 M1 12 10 R1 2 16 11 9 R1 10 10 v2 12 16 13 12 R1 13 13 14 14 11 10 R1 8 30 12 10 R1 15 15 11 65 13 14 14 14 13 11 R1 11 14 13 12 R1 9 12 M1 14 12 R1 10 13 7 14 8 26 12 7 IRS Page 41 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 475719 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92428710001 METHOD BLANK: 2578023 Associated Lab Samples: 92428710001 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 95 50-150 106 50-150 MDL Analyzed 1.2 05/16/19 12:43 05/16/19 12:43 05/16/19 12:43 Qualifiers LABORATORY CONTROL SAMPLE: 2578024 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 17.7 89 70-130 1,2-Dichloroethane-d4 (S) % 103 50-150 Toluene-d8(S) % 107 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578025 2578026 MS MSD 92427335014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 8.2 20 20 26.0 30.0 89 109 50-150 14 30 1,2-Dichloroethane-d4 (S) % 104 107 50-150 30 Toluene-d8 (S) % 109 108 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 42 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 475932 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92428710002, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008, 92428710009, 92428710010 METHOD BLANK: 2578793 Matrix: Water Associated Lab Samples: 92428710002, 92428710004, 92428710005, 92428710006, 92428710007, 92428710008, 92428710009, 92428710010 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/17/19 12:34 1,2-Dichloroethane-d4 (S) % 97 50-150 05/17/19 12:34 Toluene-d8 (S) % 113 50-150 05/17/19 12:34 LABORATORY CONTROL SAMPLE: 2578794 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8(S) % 115 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578795 2578796 MS MSD 92428710002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 57.0 20 20 69.9 77.7 65 104 50-150 11 30 1,2-Dichloroethane-d4 (S) % 106 103 50-150 30 Toluene-d8(S) % 122 119 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 43 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 QC Batch: 476323 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92428710003 METHOD BLANK: 2580465 Associated Lab Samples: 92428710003 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit ND 2.0 93 50-150 84 50-150 MDL Analyzed 1.2 05/20/19 10:54 05/20/19 10:54 05/20/19 10:54 Qualifiers LABORATORY CONTROL SAMPLE: 2580466 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.8 99 70-130 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8 (S) % 87 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2580467 2580468 MS MSD 92428710003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 128 40 40 183 178 137 125 50-150 3 30 1,2-Dichloroethane-d4 (S) % 94 93 50-150 30 Toluene-d8 (S) % 80 79 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 49 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Burke Co Kirksey Dr Closed LF Pace Project No.: 92428710 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS E Analyte concentration exceeded the calibration range. The reported result is estimated. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. SO Surrogate recovery outside laboratory control limits. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/21 /2019 03:30 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 49 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Burke Co Kirksey Dr Closed LF 92428710 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92428710001 1201-MW2 EPA 3010A 475853 EPA 6010D 475974 92428710002 1201-MW3S EPA 3010A 475853 EPA 6010D 475974 92428710003 1201-MW3D EPA 3010A 475853 EPA 6010D 475974 92428710004 1201-MW4 EPA 3010A 475853 EPA 6010D 475974 92428710005 1201-MW5 EPA 3010A 475853 EPA 6010D 475974 92428710006 1201-MW6S EPA 3010A 475853 EPA 6010D 475974 92428710007 1201-MW6D EPA 3010A 475853 EPA 6010D 475974 92428710008 1201-SW1 EPA 3010A 475853 EPA6010D 475974 92428710009 1201-SW2 EPA 3010A 475853 EPA 6010D 475974 92428710010 1201-SW3 EPA 3010A 475854 EPA 6010D 475973 92428710001 1201-MW2 EPA 3010A 476009 EPA 6020B 476047 92428710002 1201-MW3S EPA 3010A 476009 EPA 6020B 476047 92428710003 1201-MW3D EPA 3010A 476009 EPA 6020B 476047 92428710004 1201-MW4 EPA 3010A 476009 EPA 6020B 476047 92428710005 1201-MW5 EPA 3010A 476009 EPA 6020B 476047 92428710006 1201-MW6S EPA 3010A 476009 EPA 6020B 476047 92428710007 1201-MW6D EPA 3010A 476009 EPA 6020B 476047 92428710008 1201-SW1 EPA 3010A 476009 EPA 6020B 476047 92428710009 1201-SW2 EPA 3010A 476009 EPA 6020B 476047 92428710010 1201-SW3 EPA 3010A 476010 EPA 6020B 476049 92428710001 1201-MW2 EPA 8260D 28443 92428710002 1201-MW3S EPA 8260D 28443 92428710003 1201-MW3D EPA 8260D 28443 92428710004 1201-MW4 EPA 8260D 28443 92428710005 1201-MW5 EPA 8260D 28443 92428710006 1201-MW6S EPA 8260D 28443 92428710007 1201-MW6D EPA 8260D 28498 92428710008 1201-SW1 EPA 8260D 28498 92428710009 1201-SW2 EPA 8260D 28498 92428710010 1201-SW3 EPA 8260D 28498 92428710001 1201-MW2 EPA 8260D Mod. 475719 92428710002 1201-MW3S EPA 8260D Mod. 475932 92428710003 1201-MW3D EPA 8260D Mod. 476323 92428710004 1201-MW4 EPA 8260D Mod. 475932 92428710005 1201-MW5 EPA 8260D Mod. 475932 92428710006 1201-MW6S EPA 8260D Mod. 475932 92428710007 1201-MW6D EPA 8260D Mod. 475932 92428710008 1201-SW1 EPA 8260D Mod. 475932 92428710009 1201-SW2 EPA 8260D Mod. 475932 92428710010 1201-SW3 EPA 8260D Mod. 475932 Date: 05/21 /2019 03:30 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 46 of 49 Document Name: Document Revised: February 7, 2018 a aceAnalXical Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersville,y Raleigh❑ Mechanicsville[] Sample Condition. - CllentName: W0# . 92428710 Upon -Project # Courier: d Ex UPS USPS Client 11111111 ❑ Commercial E/ Pace ❑ ❑ [-]Client ❑Other: 92428710 Custody Seal Present? (]Yes (D4 Seals Intact? ❑Yes ❑No l Packing Material: []Bubble Wrap [�ubble Bags Done ❑ Other Thermometer 92TO48 Type of Ice: wet ❑Blue I yr Gun 10: 2 Cooler Temp ('C): 'A - ) Correction Factor: Add/Subtract (°C) 0.0 Cooler Temp Corrected ('C): USDA Regulated Soil (dN/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? F-1ve r-lN� Date/Initials Person Examining Contents: Biological Tissue Frozen? Des [:]No❑ /A ©None Temp should be above freezing to 6'C ❑Samples out of temp criteria. Samples an ice, cooling process has begun Did samples originate from a foreign source (internationally, inAurnna Hawaii and Nipon Rlcnl? ❑Y25 ❑No Comments/Discrepancy: Chain of Custody Present? es []No ❑N/A 1. Samples Arrived within Hold Time? es ❑No El NIA 2. Short Hold Time Analysts (<72 hr.)? 1-1 ❑Yes o ❑N/A 3. Rush Turn Around Time Requested? No []N/A 4, Sufficient Volume? —[:]Yes ❑Yes []No ❑N/A S. Correct Containers Used? -Pace Containers Used? E]Yes ❑Yes [:]No [_-]No []N/A [3N/A 6. Containers Intact? [gYes ❑No i]N/A 7. Dissolved analysis: Samples Field Filtered? ❑Y s []No QN/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Yes Matrix: []No ❑N/A 9. Headspace in VOA Vials (>5-6mm)? ❑Yes X24, ❑ a 10, Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes ❑Yes ❑No ONO NIA D /A 11. COMMENTS/SAMPLE DISCREPANCY Lot ID of Split Containers: CLIENT NOTIFICATION/RESOLUTION Project Manager SCURF Review:p Date: Project Manager SRF Review: _ _ /� 1 [ + (��% Date: Field Data Required? [:]Yes ❑No Page 47 of 49 Document Name: Document Revised: February 7, 2018 �ace*?alyftCal' Sample Condition Upon Receipt4SCURl Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project ft WQ#:92428710 PM: NMG Due Date: 05/23/19 CLIENT: 92-Joyce Eng 1z E a z Ul a c a y Z a E r, 5 V a m 2 G! a c > c� m a E fV > rn a ccm z 'p GI C00 c > o a E O > N a 4 Z .; c n M ro y 'i 7 /i a m N V N u m d E ,N. ,h 7 a m V z u a E z M a m OM Z z ev G. E N O a to u N A Om �, V o a E V V a m v C a w a o E � ti 3 z Uhl 7 a` a E Q m a •i (D ¢ iy 2 w Q E a `a •1 t7 a z L ? v E ¢ J E en W ¢ V r�, = E a a 'i 0W a _ N V m � ¢ �.! E ear a z U J E 0 N , rqn ¢ er1 ca a U 2 Q O > E CD x O1 t7 a 0 O z q 0 > J If a, t7 > � Z c IS 4 0 > E q a m l7 > ? p m x 4 O > E 9 a OI C7 o z m Y `m a X Y a O > w t7 � 7 a1+ y a . g Y kD > n IO u so a w a J E r a v, 'N° W - d in E LA r N a %A FZ a ry ry z u A a E N ¢ rn d m U d a 7 G E ¢ J aE N 3 o l7 a m � p C u J EL11 N > iA a 5 4 c m E a E V > m t7 o 1 r z l 3 4 5 I b 7 I it 8 9 X NN to 11 11 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot# Note: Whenever there is a discrepancy affecting Narth Carolina compliance samples, a copy of this form will he sent to the North Carolina DfHNR Certitication office p.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 48 of 49 N c m CO -4 m (Ao A w ro ITEM# m 3 C a 3 n m. Cr a o m m m c. o. D UI fn N C�`C Ts 0 6 z j w .� 1 D W N O d 0 � N A /A 0 o Y and w 3 a> o V . N Z N ib r O (0C N Cc, C1 �. iP^ n0 n r m CL N v '- x v jo 2 za CID CID H•C—. � Q n n p � •• �. A o n - e 1 p m pb m Non 9o�v}SS} n p a ei G• a o `4 2 d p O a W p O m O v MATRIX CODE (sae valid codes 10 ]on) X `-+ O +) 4i N � m m Od o G� Li GT G) cT Cf 6> G7 SAMPLE TYPE (G=GRA6 C=COMP) re C{o n m U m -4 0 3 3 n p re m 0 O x Z r m S j m m m m m 4 �� -^=' a w l m re S° C)> 3 °, z z a 0 m _ — _ _ CA '� 'AV J� J� a m CL 0 17, vCD l!'� v'I r n SAMPLE TEMP AT COLLECTION re 1-1m In > n N Ire a C� C S m K ' o n � til # OF CONTAINERS n n c°'i a 1 y m m v m 4 m p' d m Unpreserved C U m H2504 o o U C a m 5 n o R1 HNO3 o y m n n X -x'X X x X �C k' G p— 1r- HCI N� HOC O� X XX X XXX XX �� m O V \ D NaOH a cJn a or v m C mNa252O3 m n N y r mMethanol r n ? n Omer Qt D O 3 N Analyses Test YIN '•�, n r O N C :D x x x x x X X x NO Appendix I I 5 " a C @ a XXXXXIXXX x x NO Apperdix I VOC 8260 m 0 z z m n N x x x x x x x x x x i,4-Dioxans rn 0to C c� a ro N p^^^,, b CD L Vi O m CD m 0 �} 3 m a d m TEMP in C V �3 Residual Chlorine (YIN} c d D Received on _ - �•� m v Ice (YIN) re o p p Custody Sealed Cooler {Y1N) p v, C Samples Intact c-, 1-7-1 f'-,I C P [ (YIN) C- _")-- '— Page 49 of 49 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 May 20, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on May 09, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDs 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 21 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Lab ID Sample ID Matrix Date Collected Date Received 92428652001 92428652002 Field Blank Trip Blank Water Water 05/06/19 19:23 05/06/19 06:00 05/09/19 09:31 05/09/19 09:31 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Burke Co. Blanks EB&Kirksey 92428652 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92428652001 Field Blank EPA 601 OD IDS 14 PASI-A EPA 6020E JOR 1 PASI-A EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 92428652002 Trip Blank EPA 8260D LIH 53 PASI-GA EPA 8260D Mod. SAS 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 21 aceAnalytical -pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Sample: Field Blank Lab ID: 92428652001 Collected: 05/06/19 19:23 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Antimony ND ug/L 5.0 3.9 1 05/16/19 18:40 05/20/19 07:28 7440-36-0 Arsenic ND ug/L 10.0 5.0 1 05/16/19 18:40 05/20/19 07:28 7440-38-2 Barium ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-39-3 Beryllium ND ug/L 1.0 0.50 1 05/16/19 18:40 05/20/19 07:28 7440-41-7 Cadmium ND ug/L 1.0 0.50 1 05/16/19 18:40 05/20/19 07:28 7440-43-9 Chromium ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-47-3 Cobalt ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-48-4 Copper ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-50-8 Lead ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7439-92-1 Nickel ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-02-0 Selenium ND ug/L 10.0 5.0 1 05/16/19 18:40 05/20/19 07:28 7782-49-2 Silver ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-22-4 Vanadium ND ug/L 5.0 2.5 1 05/16/19 18:40 05/20/19 07:28 7440-62-2 Zinc ND ug/L 10.0 5.0 1 05/16/19 18:40 05/20/19 07:28 7440-66-6 6020 MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3010A Thallium ND ug/L 0.10 0.060 1 05/16/19 18:40 05/18/1910:09 7440-28-0 8260D MSV Water, Extend Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.32 1 05/15/19 23:42 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 05/15/19 23:42 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.53 1 05/15/19 23:42 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 05/15/19 23:42 79-00-5 1,1-Dichloroethane ND ug/L 1.0 0.41 1 05/15/19 23:42 75-34-3 1,1-Dichloroethene ND ug/L 1.0 0.72 1 05/15/19 23:42 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 05/15/19 23:42 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.55 1 05/15/19 23:42 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 05/15/19 23:42 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 0.49 1 05/15/19 23:42 95-50-1 1,2-Dichloroethane ND ug/L 1.0 0.67 1 05/15/19 23:42 107-06-2 1,2-Dichloropropane ND ug/L 1.0 0.60 1 05/15/19 23:42 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 05/15/19 23:42 106-46-7 2-Butanone (MEK) ND ug/L 5.0 3.2 1 05/15/19 23:42 78-93-3 2-Hexanone ND ug/L 5.0 0.89 1 05/15/19 23:42 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.86 1 05/15/19 23:42 108-10-1 Acetone ND ug/L 25.0 8.2 1 05/15/19 23:42 67-64-1 Acrylonitrile ND ug/L 50.0 2.5 1 05/15/19 23:42 107-13-1 Benzene ND ug/L 1.0 0.20 1 05/15/19 23:42 71-43-2 Bromochloromethane ND ug/L 1.0 0.50 1 05/15/19 23:42 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 05/15/19 23:42 75-27-4 Bromoform ND ug/L 1.0 0.55 1 05/15/19 23:42 75-25-2 Bromomethane ND ug/L 2.0 0.95 1 05/15/19 23:42 74-83-9 Carbon disulfide ND ug/L 10.0 0.79 1 05/15/19 23:42 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 05/15/19 23:42 56-23-5 L1 Chlorobenzene ND ug/L 1.0 0.53 1 05/15/19 23:42 108-90-7 Chloroethane ND ug/L 1.0 0.52 1 05/15/19 23:42 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Sample: Field Blank Lab ID: 92428652001 Collected: 05/06/19 19:23 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Chloroform Chloromethane Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene m&p-Xylene o-Xylene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/20/2019 05:10 PM Analytical Method: EPA 8260D ND ug/L 1.0 0.58 1 05/15/19 23:42 67-66-3 ND ug/L 1.0 0.38 1 05/15/19 23:42 74-87-3 ND ug/L 1.0 0.31 1 05/15/19 23:42 124-48-1 ND ug/L 1.0 0.62 1 05/15/19 23:42 74-95-3 ND ug/L 1.0 0.45 1 05/15/19 23:42 100-41-4 ND ug/L 10.0 3.1 1 05/15/19 23:42 74-88-4 ND ug/L 1.0 0.50 1 05/15/19 23:42 75-09-2 ND ug/L 1.0 0.50 1 05/15/19 23:42 100-42-5 ND ug/L 1.0 0.78 1 05/15/19 23:42 127-18-4 ND ug/L 1.0 0.31 1 05/15/19 23:42 108-88-3 ND ug/L 1.0 0.34 1 05/15/19 23:42 79-01-6 ND ug/L 1.0 0.51 1 05/15/19 23:42 75-69-4 ND ug/L 2.0 0.42 1 05/15/19 23:42 108-05-4 ND ug/L 1.0 0.60 1 05/15/19 23:42 75-01-4 ND ug/L 2.0 1.5 1 05/15/19 23:42 1330-20-7 ND ug/L 1.0 0.66 1 05/15/19 23:42 156-59-2 ND ug/L 1.0 0.22 1 05/15/19 23:42 10061-01-5 ND ug/L 1.0 0.92 1 05/15/19 23:42 179601-23-1 ND ug/L 1.0 0.54 1 05/15/19 23:42 95-47-6 ND ug/L 1.0 0.46 1 05/15/19 23:42 156-60-5 ND ug/L 1.0 0.30 1 05/15/19 23:42 10061-02-6 ND ug/L 5.0 1.6 1 05/15/19 23:42 110-57-6 98 %. 81-119 1 05/15/19 23:42 17060-07-0 107 %. 82-114 1 05/15/19 23:42 1868-53-7 87 %. 82-120 1 05/15/19 23:42 460-00-4 83 %. 82-109 1 05/15/19 23:42 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1.2 1 05/16/1913:03 123-91-1 106 % 50-150 1 05/16/1913:03 17060-07-0 108 % 50-150 1 05/16/1913:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Sample: Trip Blank Lab ID: 92428652002 Collected: 05/06/19 06:00 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 0.32 1 05/16/19 00:08 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 0.38 1 05/16/19 00:08 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 0.53 1 05/16/19 00:08 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 0.59 1 05/16/19 00:08 79-00-5 1,1-Dichloroethane ND ug/L 1.0 0.41 1 05/16/19 00:08 75-34-3 1,1-Dichloroethene ND ug/L 1.0 0.72 1 05/16/19 00:08 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 0.46 1 05/16/19 00:08 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 0.55 1 05/16/19 00:08 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 0.28 1 05/16/19 00:08 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 0.49 1 05/16/19 00:08 95-50-1 1,2-Dichloroethane ND ug/L 1.0 0.67 1 05/16/19 00:08 107-06-2 1,2-Dichloropropane ND ug/L 1.0 0.60 1 05/16/19 00:08 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 0.58 1 05/16/19 00:08 106-46-7 2-Butanone (MEK) ND ug/L 5.0 3.2 1 05/16/19 00:08 78-93-3 2-Hexanone ND ug/L 5.0 0.89 1 05/16/19 00:08 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 0.86 1 05/16/19 00:08 108-10-1 Acetone ND ug/L 25.0 8.2 1 05/16/19 00:08 67-64-1 Acrylonitrile ND ug/L 50.0 2.5 1 05/16/19 00:08 107-13-1 Benzene ND ug/L 1.0 0.20 1 05/16/19 00:08 71-43-2 Bromochloromethane ND ug/L 1.0 0.50 1 05/16/19 00:08 74-97-5 Bromodichloromethane ND ug/L 1.0 0.36 1 05/16/19 00:08 75-27-4 Bromoform ND ug/L 1.0 0.55 1 05/16/19 00:08 75-25-2 Bromomethane ND ug/L 2.0 0.95 1 05/16/19 00:08 74-83-9 Carbon disulfide ND ug/L 10.0 0.79 1 05/16/19 00:08 75-15-0 Carbon tetrachloride ND ug/L 1.0 0.42 1 05/16/19 00:08 56-23-5 L1 Chlorobenzene ND ug/L 1.0 0.53 1 05/16/19 00:08 108-90-7 Chloroethane ND ug/L 1.0 0.52 1 05/16/19 00:08 75-00-3 Chloroform ND ug/L 1.0 0.58 1 05/16/19 00:08 67-66-3 Chloromethane ND ug/L 1.0 0.38 1 05/16/19 00:08 74-87-3 Dibromochloromethane ND ug/L 1.0 0.31 1 05/16/19 00:08 124-48-1 Dibromomethane ND ug/L 1.0 0.62 1 05/16/19 00:08 74-95-3 Ethylbenzene ND ug/L 1.0 0.45 1 05/16/19 00:08 100-41-4 lodomethane ND ug/L 10.0 3.1 1 05/16/19 00:08 74-88-4 Methylene Chloride ND ug/L 1.0 0.50 1 05/16/19 00:08 75-09-2 Styrene ND ug/L 1.0 0.50 1 05/16/19 00:08 100-42-5 Tetrachloroethene ND ug/L 1.0 0.78 1 05/16/19 00:08 127-18-4 Toluene ND ug/L 1.0 0.31 1 05/16/19 00:08 108-88-3 Trichloroethene ND ug/L 1.0 0.34 1 05/16/19 00:08 79-01-6 Trichlorofluoromethane ND ug/L 1.0 0.51 1 05/16/19 00:08 75-69-4 Vinyl acetate ND ug/L 2.0 0.42 1 05/16/19 00:08 108-05-4 Vinyl chloride ND ug/L 1.0 0.60 1 05/16/19 00:08 75-01-4 Xylene (Total) ND ug/L 2.0 1.5 1 05/16/19 00:08 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 0.66 1 05/16/19 00:08 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 0.22 1 05/16/19 00:08 10061-01-5 m&p-Xylene ND ug/L 1.0 0.92 1 05/16/19 00:08 179601-23-1 o-Xylene ND ug/L 1.0 0.54 1 05/16/19 00:08 95-47-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 7 of 21 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Sample: Trip Blank Lab ID: 92428652002 Collected: 05/06/19 06:00 Received: 05/09/19 09:31 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Water, Extend Analytical Method: EPA 8260D trans-1,2-Dichloroethene ND ug/L 1.0 0.46 1 05/16/19 00:08 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 0.30 1 05/16/19 00:08 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1.6 1 05/16/19 00:08 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 %. 81-119 1 05/16/19 00:08 17060-07-0 Dibromofluoromethane (S) 105 %. 82-114 1 05/16/19 00:08 1868-53-7 4-Bromofluorobenzene (S) 86 %. 82-120 1 05/16/19 00:08 460-00-4 Toluene-d8 (S) 83 %. 82-109 1 05/16/19 00:08 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1.2 1 05/16/19 13:23 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 98 % 50-150 1 05/16/19 13:23 17060-07-0 Toluene-d8 (S) 108 % 50-150 1 05/16/19 13:23 2037-26-5 Date: 05/20/2019 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 QC Batch: 475606 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92428652001 METHOD BLANK: 2577609 Associated Lab Samples: 92428652001 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Antimony ug/L ND 5.0 3.9 05/20/19 06:13 Arsenic ug/L ND 10.0 5.0 05/20/19 06:13 Barium ug/L ND 5.0 2.5 05/20/19 06:13 Beryllium ug/L ND 1.0 0.50 05/20/19 06:13 Cadmium ug/L ND 1.0 0.50 05/20/19 06:13 Chromium ug/L ND 5.0 2.5 05/20/19 06:13 Cobalt ug/L ND 5.0 2.5 05/20/19 06:13 Copper ug/L ND 5.0 2.5 05/20/19 06:13 Lead ug/L ND 5.0 2.5 05/20/19 06:13 Nickel ug/L ND 5.0 2.5 05/20/19 06:13 Selenium ug/L ND 10.0 5.0 05/20/19 06:13 Silver ug/L ND 5.0 2.5 05/20/19 06:13 Vanadium ug/L ND 5.0 2.5 05/20/19 06:13 Zinc ug/L ND 10.0 5.0 05/20/19 06:13 LABORATORY CONTROL SAMPLE: Parameter 2577610 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 500 489 98 80-120 Arsenic ug/L 500 463 93 80-120 Barium ug/L 500 503 101 80-120 Beryllium ug/L 500 504 101 80-120 Cadmium ug/L 500 491 98 80-120 Chromium ug/L 500 498 100 80-120 Cobalt ug/L 500 488 98 80-120 Copper ug/L 500 503 101 80-120 Lead ug/L 500 479 96 80-120 Nickel ug/L 500 487 97 80-120 Selenium ug/L 500 484 97 80-120 Silver ug/L 250 250 100 80-120 Vanadium ug/L 500 490 98 80-120 Zinc ug/L 500 482 96 80-120 Qualifiers Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577611 2577612 MS MSD 92428534001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 500 500 498 500 99 100 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Pace Project No.: Burke Co. Blanks EB&Kirksey 92428652 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577611 2577612 MS MSD 92428534001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Arsenic ug/L ND 500 500 474 476 95 95 75-125 0 20 Barium ug/L 54.1 500 500 560 567 101 103 75-125 1 20 Beryllium ug/L ND 500 500 509 512 102 102 75-125 1 20 Cadmium ug/L ND 500 500 506 507 101 101 75-125 0 20 Chromium ug/L ND 500 500 507 509 101 102 75-125 0 20 Cobalt ug/L ND 500 500 494 496 99 99 75-125 0 20 Copper ug/L ND 500 500 507 508 101 102 75-125 0 20 Lead ug/L ND 500 500 485 488 97 97 75-125 1 20 Nickel ug/L ND 500 500 495 497 99 99 75-125 0 20 Selenium ug/L ND 500 500 515 523 103 105 75-125 2 20 Silver ug/L ND 250 250 254 256 101 102 75-125 1 20 Vanadium ug/L ND 500 500 502 501 100 100 75-125 0 20 Zinc ug/L 10.4 500 500 509 508 100 100 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 QC Batch: 475600 Analysis Method: EPA 6020B QC Batch Method: EPA 3010A Analysis Description: 6020 MET Associated Lab Samples: 92428652001 METHOD BLANK: 2577596 Matrix: Water Associated Lab Samples: 92428652001 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers Thallium ug/L ND 0.10 0.060 05/18/19 07:40 LABORATORY CONTROL SAMPLE: 2577597 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Thallium ug/L 10 9.1 91 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2577598 2577599 MS MSD 92427326018 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Thallium ug/L ND 10 10 9.2 9.5 92 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 QC Batch: 28443 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Water, Extend Associated Lab Samples: 92428652001, 92428652002 METHOD BLANK: 128030 Associated Lab Samples: 92428652001, 92428652002 Parameter Units Matrix: Blank Result Water Reporting Limit MDL Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 0.32 05/15/19 18:29 1,1,1-Trichloroethane ug/L ND 1.0 0.38 05/15/19 18:29 1,1,2,2-Tetrachloroethane ug/L ND 1.0 0.53 05/15/19 18:29 1,1,2-Trichloroethane ug/L ND 1.0 0.59 05/15/19 18:29 1,1-Dichloroethane ug/L ND 1.0 0.41 05/15/19 18:29 1,1-Dichloroethene ug/L ND 1.0 0.72 05/15/19 18:29 1,2,3-Trichloropropane ug/L ND 1.0 0.46 05/15/19 18:29 1,2-Dibromo-3-chloropropane ug/L ND 2.0 0.55 05/15/19 18:29 1,2-Dibromoethane (EDB) ug/L ND 2.0 0.28 05/15/19 18:29 1,2-Dichlorobenzene ug/L ND 1.0 0.49 05/15/19 18:29 1,2-Dichloroethane ug/L ND 1.0 0.67 05/15/19 18:29 1,2-Dichloropropane ug/L ND 1.0 0.60 05/15/19 18:29 1,4-Dichlorobenzene ug/L ND 1.0 0.58 05/15/19 18:29 2-Butanone (MEK) ug/L ND 5.0 3.2 05/15/19 18:29 2-Hexanone ug/L ND 5.0 0.89 05/15/19 18:29 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 0.86 05/15/19 18:29 Acetone ug/L ND 25.0 8.2 05/15/19 18:29 Acrylonitrile ug/L ND 50.0 2.5 05/15/19 18:29 Benzene ug/L ND 1.0 0.20 05/15/19 18:29 Bromochloromethane ug/L ND 1.0 0.50 05/15/19 18:29 Bromodichloromethane ug/L ND 1.0 0.36 05/15/19 18:29 Bromoform ug/L ND 1.0 0.55 05/15/19 18:29 Bromomethane ug/L ND 2.0 0.95 05/15/19 18:29 Carbon disulfide ug/L ND 10.0 0.79 05/15/19 18:29 Carbon tetrachloride ug/L ND 1.0 0.42 05/15/19 18:29 Chlorobenzene ug/L ND 1.0 0.53 05/15/19 18:29 Chloroethane ug/L ND 1.0 0.52 05/15/19 18:29 Chloroform ug/L ND 1.0 0.58 05/15/19 18:29 Chloromethane ug/L ND 1.0 0.38 05/15/19 18:29 cis-1,2-Dichloroethene ug/L ND 1.0 0.66 05/15/19 18:29 cis-1,3-Dichloropropene ug/L ND 1.0 0.22 05/15/19 18:29 Dibromochloromethane ug/L ND 1.0 0.31 05/15/19 18:29 Dibromomethane ug/L ND 1.0 0.62 05/15/19 18:29 Ethylbenzene ug/L ND 1.0 0.45 05/15/19 18:29 lodomethane ug/L ND 10.0 3.1 05/15/19 18:29 m&p-Xylene ug/L ND 1.0 0.92 05/15/19 18:29 Methylene Chloride ug/L ND 1.0 0.50 05/15/19 18:29 o-Xylene ug/L ND 1.0 0.54 05/15/19 18:29 Styrene ug/L ND 1.0 0.50 05/15/19 18:29 Tetrachloroethene ug/L ND 1.0 0.78 05/15/19 18:29 Toluene ug/L ND 1.0 0.31 05/15/19 18:29 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 METHOD BLANK: 128030 Associated Lab Samples: Parameter 92428652001, 92428652002 Units Matrix: Blank Result Water Reporting Limit MDL Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 0.46 05/15/19 18:29 trans- 1,3-Dichloropropene ug/L ND 1.0 0.30 05/15/19 18:29 trans-1,4-Dichloro-2-butene ug/L ND 5.0 1.6 05/15/19 18:29 Trichloroethene ug/L ND 1.0 0.34 05/15/19 18:29 Trichlorofluoromethane ug/L ND 1.0 0.51 05/15/19 18:29 Vinyl acetate ug/L ND 2.0 0.42 05/15/19 18:29 Vinyl chloride ug/L ND 1.0 0.60 05/15/19 18:29 Xylene (Total) ug/L ND 2.0 1.5 05/15/19 18:29 1,2-Dichloroethane-d4 (S) %. 96 81-119 05/15/19 18:29 4-Bromofluorobenzene (S) %. 86 82-120 05/15/19 18:29 Dibromofluoromethane (S) %. 101 82-114 05/15/19 18:29 Toluene-d8 (S) %. 84 82-109 05/15/19 18:29 LABORATORY CONTROL SAMPLE: Parameter 128031 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.2 106 68-137 1,1,1-Trichloroethane ug/L 50 60.6 121 72-134 1,1,2,2-Tetrachloroethane ug/L 50 44.5 89 51-158 1,1,2-Trichloroethane ug/L 50 56.8 114 78-131 1,1-Dichloroethane ug/L 50 58.2 116 69-151 1,1-Dichloroethene ug/L 50 56.5 113 64-158 1,2,3-Trichloropropane ug/L 50 41.7 83 78-133 1,2-Dibromo-3-chloropropane ug/L 50 43.2 86 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.7 113 71-134 1,2-Dichlorobenzene ug/L 50 49.7 99 70-135 1,2-Dichloroethane ug/L 50 56.7 113 72-129 1,2-Dichloropropane ug/L 50 52.5 105 64-135 1,4-Dichlorobenzene ug/L 50 47.6 95 70-131 2-Butanone (MEK) ug/L 100 94.0 94 52-143 2-Hexanone ug/L 100 79.9 80 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 89.1 89 71-129 Acetone ug/L 100 119 119 48-224 Acrylonitrile ug/L 200 188 94 66-154 Benzene ug/L 50 57.8 116 68-132 Bromochloromethane ug/L 50 66.5 133 73-133 Bromodichloromethane ug/L 50 49.2 98 67-121 Bromoform ug/L 50 48.6 97 57-125 Bromomethane ug/L 50 44.5 89 35-156 Carbon disulfide ug/L 100 97.3 97 47-141 Carbon tetrachloride ug/L 50 61.6 123 66-122 L1 Chlorobenzene ug/L 50 48.5 97 71-126 Chloroethane ug/L 50 43.4 87 43-143 Chloroform ug/L 50 58.8 118 71-136 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 LABORATORY CONTROL SAMPLE: Parameter 128031 Units Spike LCS Conc. Result Chloromethane ug/L 50 cis-1,2-Dichloroethene ug/L 50 cis-1,3-Dichloropropene ug/L 50 Dibromochloromethane ug/L 50 Dibromomethane ug/L 50 Ethylbenzene ug/L 50 lodomethane ug/L 100 m&p-Xylene ug/L 100 Methylene Chloride ug/L 50 o-Xylene ug/L 50 Styrene ug/L 50 Tetrachloroethene ug/L 50 Toluene ug/L 50 trans-1,2-Dichloroethene ug/L 50 trans- 1,3-Dichloropropene ug/L 50 trans-1,4-Dichloro-2-butene ug/L 100 Trichloroethene ug/L 50 Trichlorofluoromethane ug/L 50 Vinyl acetate ug/L 50 Vinyl chloride ug/L 50 Xylene (Total) ug/L 150 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. LCS % Rec % Rec Limits 42.9 86 47-123 62.6 125 74-131 49.7 99 78-120 55.7 111 65-115 61.0 122 79-129 48.6 97 68-129 117 117 49-154 101 101 67-137 58.1 116 61-147 53.2 106 52-141 54.6 109 77-128 63.5 127 51-139 54.0 108 60-133 58.0 116 69-144 49.5 99 74-128 62.3 62 61-139 47.6 95 73-126 52.1 104 55-132 41.4 83 52-141 48.3 97 50-133 154 103 78-132 96 81-119 89 82-120 112 82-114 82 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032 MS 92428710001 Spike Parameter Units Result Conc. MSD Spike Conc. 128033 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 49.1 53.5 98 107 68-137 9 11 1,1,1-Trichloroethane ug/L ND 50 50 68.1 71.3 136 143 66-142 5 11 M1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 43.9 47.2 88 94 39-171 7 13 1,1,2-Trichloroethane ug/L ND 50 50 55.3 59.2 111 118 73-136 7 12 1,1-Dichloroethane ug/L 0.68J 50 50 60.9 62.9 120 125 66-155 3 15 1,1-Dichloroethene ug/L ND 50 50 65.8 68.9 132 138 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 39.8 43.1 80 86 78-133 8 14 1,2-Dibromo-3- ug/L ND 50 50 46.3 48.5 93 97 58-124 5 15 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 54.1 58.6 108 117 71-134 8 12 1,2-Dichlorobenzene ug/L 2.4 50 50 51.4 53.8 98 103 69-135 5 10 1,2-Dichloroethane ug/L ND 50 50 55.0 55.8 110 112 36-159 1 10 1,2-Dichloropropane ug/L ND 50 50 51.3 55.2 103 110 68-132 7 11 1,4-Dichlorobenzene ug/L 47.3 50 50 95.7 97.4 97 100 49-153 2 9 2-Butanone (MEK) ug/L 448 100 100 544 551 96 103 10-189 1 23 M3 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 21 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128032 MS 92428710001 Spike Parameter Units Result Conc. MSD Spike Conc. 128033 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 2-Hexanone ug/L 8.0 100 100 83.0 88.5 75 81 40-135 6 18 4-Methyl-2-pentanone ug/L 311 100 100 440 454 129 143 30-177 3 10 M3 (MIBK) Acetone ug/L 299 100 100 403 407 104 108 44-223 1 14 M3 Acrylonitrile ug/L ND 200 200 180 194 90 97 13-189 8 12 Benzene ug/L 10.4 50 50 69.4 72.2 118 124 66-139 4 10 Bromochloromethane ug/L ND 50 50 66.1 69.6 132 139 73-133 5 13 M1 Bromodichloromethane ug/L ND 50 50 47.8 51.1 96 102 57-120 7 13 Bromoform ug/L ND 50 50 46.1 50.3 92 101 48-128 9 13 Bromomethane ug/L ND 50 50 29.7 38.7 59 77 10-187 26 32 Carbon disulfide ug/L ND 100 100 113 120 113 120 47-141 6 322 Carbon tetrachloride ug/L ND 50 50 69.4 73.6 139 147 58-127 6 14 MO Chlorobenzene ug/L 26.6 50 50 73.1 77.6 93 102 63-137 6 10 Chloroethane ug/L ND 50 50 47.2 47.7 93 94 52-146 1 16 Chloroform ug/L ND 50 50 58.8 61.7 118 123 74-137 5 9 Chloromethane ug/L ND 50 50 45.7 47.1 91 94 41-127 3 10 cis-1,2-Dichloroethene ug/L ND 50 50 62.0 64.0 124 128 71-138 3 16 cis-1,3-Dichloropropene ug/L ND 50 50 45.4 49.0 91 98 32-145 8 12 Dibromochloromethane ug/L ND 50 50 51.5 55.4 103 111 52-116 7 13 Dibromomethane ug/L ND 50 50 57.6 62.1 115 124 79-129 7 14 Ethylbenzene ug/L 24.1 50 50 72.7 77.0 97 106 31-174 6 10 lodomethane ug/L ND 100 100 113 122 113 122 49-154 8 30 m&p-Xylene ug/L 48.5 100 100 150 159 102 111 27-179 6 10 Methylene Chloride ug/L ND 50 50 57.2 58.7 114 117 61-146 3 15 o-Xylene ug/L 7.3 50 50 59.5 63.1 104 111 52-141 6 65 Styrene ug/L ND 50 50 53.1 57.8 106 116 77-128 9 14 Tetrachloroethene ug/L ND 50 50 66.8 70.8 134 142 36-155 6 14 Toluene ug/L 4.8 50 50 59.2 63.5 109 117 52-146 7 11 trans-1,2-Dichloroethene ug/L ND 50 50 63.8 65.0 128 130 61-152 2 14 trans-1,3-Dichloropropene ug/L ND 50 50 45.2 48.8 90 98 37-146 8 12 trans-1,4-Dichloro-2-butene ug/L ND 100 100 52.8 65.6 53 66 61-139 22 12 M1,R1 Trichloroethene ug/L ND 50 50 48.1 52.2 96 104 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.1 71.4 134 143 51-141 6 13 M1 Vinyl acetate ug/L ND 50 50 65.1 32.4 130 65 52-141 67 14 R1 Vinyl chloride ug/L ND 50 50 56.9 59.9 113 119 22-156 5 26 Xylene (Total) ug/L 55.8 150 150 210 222 102 111 78-132 6 7 1,2-Dichloroethane-d4 (S) %. 98 97 81-119 4-Bromofluorobenzene (S) %. 88 86 82-120 Dibromofluoromethane (S) %. 109 111 82-114 Toluene-d8 (S) %. 82 83 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 QC Batch: 475719 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 92428652001, 92428652002 METHOD BLANK: 2578023 Matrix: Water Associated Lab Samples: 92428652001, 92428652002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 1.2 05/16/19 12:43 1,2-Dichloroethane-d4 (S) % 95 50-150 05/16/19 12:43 Toluene-d8 (S) % 106 50-150 05/16/19 12:43 LABORATORY CONTROL SAMPLE: 2578024 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane(p-Dioxane) ug/L 20 17.7 89 70-130 1,2-Dichloroethane-d4 (S) % 103 50-150 Toluene-d8(S) % 107 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578025 2578026 MS MSD 92427335014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 8.2 20 20 26.0 30.0 89 109 50-150 14 30 1,2-Dichloroethane-d4 (S) % 104 107 50-150 30 Toluene-d8 (S) % 109 108 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 21 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. M3 Matrix spike recovery was outside laboratory control limits due to matrix interferences. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/20/2019 05:10 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 21 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co. Blanks EB&Kirksey Pace Project No.: 92428652 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92428652001 Field Blank EPA 3010A 475606 EPA6010D 475865 92428652001 Field Blank EPA 3010A 475600 EPA6020B 475863 92428652001 Field Blank EPA 8260D 28443 92428652002 Trip Blank EPA 8260D 28443 92428652001 Field Blank EPA 8260D Mod. 475719 92428652002 Trip Blank EPA 8260D Mod. 475719 Date: 05/20/2019 05:10 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 21 Document Name: Document Revised: February 7, 2018 . ARalXlcal Sample Condition Upon Receipt(SCUR Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersviile /❑� Raleigh❑ Mechanicsville❑ ConditionSample Client Name: W V # : 92428652 ReceiptUpon Project Courier:❑acx ds ❑[-]Client ❑Commercial Pe ❑Other: 92428652 Custody Seal Present? []Yes ONo Seals Intact? ❑Yes ❑No Date/Initials person Examining Contents: Packing Material: ❑Bubble Wrap dBubble Bags ❑None ❑ Other The►mometel 92T948 Type of Ice: J2 et ❑slue ,3IR Gun ID: Cooler Temp (°C): II Correction Factor: Add/Subtract (•C) d,() Cooler Temp Corrected (+C): 4 ) r , i USDA Regulated Soil (❑ N/A, water sample) Did samples origi ate in a quarantine zone within the United States: CA, NY, or SC (check maps)? I—IYPc X. Biological Tissue Frozen? []Yes[]No�]i N/A []None Temp should be above freezing to VC ❑Samples out of temp criteria. Samples on ice, cooling process has begun Did samples originate from a foreign source lintern�icnally, inrludin¢ Hawaii and Puerto Rlcol? f—IYes -PNo Comments/Discrepancy: Chain of Custody Present? ©des ❑No ❑N/A 1. Samples Arrived within Hold Time? Ves []No ❑N/A 2. Short Hold Time Analysis (02 hr.)? ❑Yes ❑9c, ❑N/A 3. Rush Turn Around Time Requested? []Yes ' No ❑N/A 4. Sufficient Volume? LJYes ❑No ❑N/A S. Correct Containers Used? �y s []No []N/A 6. -Pace Containers Used? Yes ❑No ❑N/A Containers Intact? Yes ❑No ❑N/A 7. Dissolved analysis: Samples Field Filtered? ❑Ye; ❑No EfN/A 8. Sample Labels Watch COC? Oyes ❑No ❑N/A 9. -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? ❑Yes ji]1ID ❑N/A 10, Trip Blank Present? ErYes [:]No ❑N/A 11. Trip Blank Custody Seals Present? oes No []N/A COMMENTS/SAMPLE DISCREPANCY Field Data Required? Dyes ❑No Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION , ,fJ 4 ) (0 i6 i'J lYh %� S1L � Y� �lL5 d t? ri! J, t = � M-MMEMENEDON Project Manager SCURF Review: Date: Project Manager SRF Review: 1) ' �� Date: ! 73 1 Page 19 of 21 Document Name: Document Revised: February 7, 2018 o ��aceAnalytica! Sample Condition Upon Receipt(5CUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 {water) DOC, LLHg **Bottom half of box is to list number of bottle Project WO# ; 92428652 PM: NMS Due Date: 05/23/19 CLIENT: 92—Joyce Eng E Q - z a c a v a n rNi 6 m 2 W c c 7 V a a N := a m Z d `o. c V a o N a m vV °Ji a c " a ry ti a, oo G c O yr = V m y E N A d m v G D z L U N a o N M d to M t~6 d N u n. u N C a m ry a T 4 Z V @ a vE N uV 6 m a w a .0 o 0 u' V h v a d a E m U 4 V S m a C "v S l7 4 z a a c = 4 n E ¢ o N 7 l7 d C N = y E a m rY VI U' a C O Y y E 4 0 l7 d - Z z E C E C) N ran d 0 d 2 ... U 2 4 0 E q i 0 a Z 0 N i0 Z ¢ O > H WU' > - ? G C O ¢ 0 E G 7 l7 > = v a m O E 6 C7 0 Y m o yr a .3 v Y O > @ Q) = a i+ a N .@ > a ;� E ^1 •-r a rn Z V '- '^ Q. W .n J E N n 'n N iv = V a ., E N 0. m 2 N "' p, c p/ a -+ of ri 0 d - 'i c N H E N M ? !l n E d E t7 O 1N 1 1 j 3 4 5 6 7 B 9 10 11 12 pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt Date preservation adjusted Time preservation adjusted Amount of Preservative added Lot Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 20 of 21 z z m n M z rn 3 m 0 o D z n n �r Z m m X �l ;U I'd i� TEMP in C Received on Ice (YIN) Custody Sealed Cooler (Y/N) Samples Intact (YIN) C D O 0 0 z n C' m m z N N _1 3 m 8 m a 0 m a z H z M n O z O 0 z V) d -• rr co -4 m cn A w to ITEM# N -� i T N EF 02 w Cn/^ F F 0 n x N m 3 p °fin r m_ L X ri '_g_°win $g'S B O MATRIX CCOE (see valid codes Ic IeB) SAMPLETYPE IG=GRAB C=COMP) a m � ...n m an z o m W a m SAMPLE TEMP AT COLLECTION S J * or CONTAINERS Unpreserved H2SO4 HNO3 X HCI N m NaOH Nazsza3 m Methanol Other Analyses Test Y/N X NC Appendix 1 Metals X x NC Appendix I VOC 82699 x x 9,4-Dioxane Residual Chlorine, (YIN) 713 n a m a° n N a H @ a c, n O L.4 Q C O N Y a D) O C ° lO C 7 7 oWcrZiDa rn n C m > n i ° n i(D p 4 3 p N m .. o o o N N Q K _ � N M a 1 --1 n " D m » �Z o c O N 1 w w m m a a 0 0. c N o a n ill 1D mm ° m n O Z M � > 0 'm m 0� r °ro D n, o r N A� O 03 w` .. o 0 > cn f Z ° DMai � ID o n m Z] D d! O 7 cn E r C n � cL N N rwa N r . 3 N C �aa � 0 r cb o 3 CD m � m �* a n n c v S Page 21 of 21 aceAnalytical _pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 August 05, 2019 Mr. Van Burbach Joyce Engineering -Greensboro 2211 West Meadowview Rd Boone Bldg, Suite 101 Greensboro, NC 27407 RE: Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Dear Mr. Burbach: Enclosed are the analytical results for sample(s) received by the laboratory on July 25, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, ��i Flo _ _.1I , .�: Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Van Burbach, Joyce Engineering -NC Gretta Eller, LaBella Associates, D.P.C. Daniel Girdner, LaBella Associates, D.P.C. Rochelle Mesubed, Joyce Engineering Miguel Vazquez, Joyce Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 13 acmnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 13 aceAnalytical —pacelabsxom Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE SUMMARY Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Lab ID Sample ID Matrix Date Collected Date Received 92438634001 92438634002 MW-31) TRIP BLANK Water Water 07/23/1916:50 07/23/19 09:30 07/25/1910:41 07/25/19 10:41 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92438634001 MW-31) EPA 8260D CL 6 PASI-C 92438634002 TRIP BLANK EPA 8260D CL 6 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SUMMARY OF DETECTION Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Lab Sample ID Client Sample ID Method Parameters Result Units 92438634001 MW-311) EPA 8260D 1,1-Dichloroethane 4.8 ug/L EPA 8260D 1,2-Dichloropropane 0.81 J ug/L EPA 8260D Tetrachloroethene 6.5 ug/L REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Report Limit Analyzed 1.0 08/02/19 23:50 1.0 08/02/19 23:50 1.0 08/02/19 23:50 Qualifiers Page 5 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Sample: MW-31) Lab ID: 92438634001 Collected: 07/23/19 16:50 Received: 07/25/19 10:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D 1,1-Dichloroethane 4.8 ug/L 1.0 0.27 1 08/02/19 23:50 75-34-3 1,2-Dichloropropane 0.811 ug/L 1.0 0.19 1 08/02/19 23:50 78-87-5 Tetrachloroethene 6.5 ug/L 1.0 0.16 1 08/02/19 23:50 127-18-4 Surrogates 4-Bromofluorobenzene (S) 99 % 70-130 1 08/02/19 23:50 460-00-4 1,2-Dichloroethane-d4 (S) 89 % 70-130 1 08/02/19 23:50 17060-07-0 Toluene-d8 (S) 109 % 70-130 1 08/02/19 23:50 2037-26-5 Date: 08/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Sample: TRIP BLANK Lab ID: 92438634002 Collected: 07/23/19 09:30 Received: 07/25/19 10:41 Matrix: Water Report Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Landfill Analytical Method: EPA 8260D 1,1-Dichloroethane ND ug/L 1.0 0.27 1 08/02/19 22:22 75-34-3 1,2-Dichloropropane ND ug/L 1.0 0.19 1 08/02/19 22:22 78-87-5 Tetrachloroethene ND ug/L 1.0 0.16 1 08/02/19 22:22 127-18-4 Surrogates 4-Bromofluorobenzene (S) 96 % 70-130 1 08/02/19 22:22 460-00-4 1,2-Dichloroethane-d4 (S) 82 % 70-130 1 08/02/19 22:22 17060-07-0 Toluene-d8 (S) 108 % 70-130 1 08/02/19 22:22 2037-26-5 Date: 08/05/2019 03:57 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 QC Batch: 490158 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Landfill Associated Lab Samples: 92438634001, 92438634002 METHOD BLANK: 2644586 Matrix: Water Associated Lab Samples: 92438634001, 92438634002 Blank Reporting Parameter Units Result Limit MDL Analyzed Qualifiers 1,1-Dichloroethane ug/L ND 1.0 0.27 08/02/19 17:23 1,2-Dichloropropane ug/L ND 1.0 0.19 08/02/19 17:23 Tetrachloroethene ug/L ND 1.0 0.16 08/02/19 17:23 1,2-Dichloroethane-d4 (S) % 94 70-130 08/02/19 17:23 4-Bromofluorobenzene (S) % 100 70-130 08/02/19 17:23 Toluene-d8 (S) % 104 70-130 08/02/19 17:23 LABORATORY CONTROL SAMPLE: 2644587 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1-Dichloroethane ug/L 50 51.0 102 70-130 1,2-Dichloropropane ug/L 50 50.4 101 70-130 Tetrachloroethene ug/L 50 48.2 96 69-130 1,2-Dichloroethane-d4 (S) % 104 70-130 4-Bromofluorobenzene (S) % 94 70-130 Toluene-d8 (S) % 96 70-130 MATRIX SPIKE SAMPLE: 2644589 92439759009 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,1-Dichloroethane ug/L ND 20 22.9 115 70-139 1,2-Dichloropropane ug/L ND 20 21.2 106 70-140 Tetrachloroethene ug/L ND 20 23.0 115 59-143 1,2-Dichloroethane-d4 (S) % 110 70-130 4-Bromofluorobenzene (S) % 99 70-130 Toluene-d8 (S) % 97 70-130 SAMPLE DUPLICATE: 2644588 92439759008 Dup Max Parameter Units Result Result RPD RPD Qualifiers 1,1-Dichloroethane ug/L ND ND 30 1,2-Dichloropropane ug/L ND ND 30 Tetrachloroethene ug/L ND ND 30 1,2-Dichloroethane-d4 (S) % 80 94 4-Bromofluorobenzene (S) % 98 95 Toluene-d8 (S) % 106 104 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALIFIERS Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 08/05/2019 03:57 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 13 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Burke Co-Kirksey Dr Resample Pace Project No.: 92438634 Lab ID 92438634001 92438634002 Sample ID MW-3D TRIP BLANK Date: 08/05/2019 03:57 PM QC Batch Method QC Batch EPA 8260D 490158 EPA 8260D 490158 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 10 of 13 aceAnall,trcal a � Document Name: Sam le Condition Upon Receipt(SCUR) Document Revised: February 7, 2018 Page 1 of 2 Document No.: F-CAR-CS-033-Rev.06 Issuing Authority: Pace Carolinas Quality Office Laboratory receiving samples: �/ Asheville ❑ Eden❑ Greenwood ❑ Huntersville F'_ Raleigh❑ Mechanicsville❑ sample.Condition-Client Name: WO# : 92438634 .. • . �Project ; ljw �5 5� � .111111111IIII Ir ! ll� III Courier: ❑Fed Ex ❑UPS ❑USPS []Client 92438634 ❑ Commercial (Pace ❑Other: I _ Custody Seal Present? ❑Yes No Seals Intact? ❑Yes lz�o patellnitials Person Examining Contents: Packing Material: ❑Bubble Wrap dalbhle Bags ❑None ❑ Other Biological Tissue F'Oxen? Therm omele . []Yes []NOFAIJA IR Gun Ip; 92T048 Type of Ice: jet ❑Blue ❑None Cooler Temp ('Cl; i Correction Factor: Add/Subtract ('C) 0.0 Tempshould be above freezing to 6°C Cooler Temp Corrected ('C): [—]Samples out of temp criteria, Samples on ice, cooling process has begun USDA Regulated Soil { N/A, water samples Did samples on ate in a quarantine zone within the United States: CA, NY, or 5C [check maps]? Did samples originate from a foreign source (intern naily, []Yes LJNo including Hawaii and Puerto Rlco]? []Yes No Comments/Discrepancy: Chain of Custody Present? crYes ❑No ❑N/A 1, Samples Arrived within Hold Time? ❑yes [3rJ ❑N/A 2. Short Hold Time Analysis (<71 hr.)? DesND ❑N/A 3. Rush Turn Around Time Requested? []Yes 0 No ❑N/A 4. Sufficient Volume? QYes ❑ND ❑N/A S. Correct Containers Used? -Pace Containers Used? S' Q es []No ❑No ❑N/A []N/A 5. Containers Intact? a Yes ONO ❑N/9 7. Dissolved analysis: Sampies Field Filtered? ❑Yes. []NO N/A 8. Sample Labels Match COC? -Includes Date/Time/ID/Analysis Matrix; 01Yes l✓ i ❑ND ❑N/A 9. Headspace in VOA Vials (p5-6mm)? d s ❑No ❑N/A 10, Trip Blank Present? Trip Blank Custody Seals Present? ye Yes ❑ND ❑ND ❑N/A ❑N/A 11. COMMENTSIStAMPLE DISCREPANCY / Field Data Required? ❑Yes ❑No '. Lot ID of split containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Time: Project Manager SCURF Review: oko Project Manager SRF Review: f � 7 Date: Date: f�iSl1� Page 11 of 13 Document Name: Document Revised: February 7, 2018 Analytical Sample Condition Upon Receipt(SCUR) Page 1 of 2 Document No.: Issuing Authority: F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle Project WQ# : 92438634 PM: NMG Due Date: 08/08/19 CLIENT: 92-Joyce Eng E a z �. �Cl 2 a c 5 ii J E N v a 0o z N Z a a c a J E N e.�i a m z N Z v a c O u a J E 4�11 e=r a m 4 z w u a c M d U r-� � a 0 V V 2 V 0 cn N n a rV Q a m N v M O 2 2 o. J E N T a m OM 2 u v 4� � u a a J E N e a Co U 11 x O ro 2 m a E o a m a H ro V, a w o E v � z d a c 7 a E Q a`i .i l7 Q N Y a U Y vDIrlE a E d `m S C9 4 2 n c n ¢ J E N 7 m l7 Q N y ry 2I E q a iA Q � Z N _ y V 2 x w O r u1 E N 4 E Ln 4 J t E rin7 N O VI Q en m 0 U Q q Q Z _ U x O > E O Y 4M 0 O _ d m O v z O 7 J O F o� 0 > < 2 D O % E C3 m l7 ] 2 v p z O 7 E o 6 a 0 O in m ❑ Y a 'A �p Y a 0 ] Z = a > C rs m ] :am m u ;,, `O v Y N J E N u~i a � -- - w '0 v n J E � N N a u1 rr en !c O ry ,^y y 2 a a E y❑j N M m 3 M v a G � `v E d J E O c ¢ 2 1° � c O c 4 VI E p ? _M ? v a c 9 E ¢ E Q m ❑ 2 1� 3 4 5 \\NN I N NN 7 8 9 10 11 12 A\NN -L�s-\NN I pH Adjustment Log for Preserved Samples Sample 10 Type of Preservative pH upon receipt date preservation adjusted Time preservation adjusted Amount of Preservative added Lot p Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le. Out of hold, incorrect preservative, out of tempr incorrect containers. Page 12 of 13 G 9 1 z r n 0 m z to C Zn m 0 m > n (n n7 1 - 1- 5 A a Z ~ y= i O ` 2 a m m m m N p } b v b � 1 C l' m m u.S 1 m ` a 0 0 m m T z 0 1 m -4) i` 3 4 m TEMP in C J� 144 Received on fce N b (Y!N) m 0 Custody Sealed z Cooler(YIN) 0 z m Samples Intact �._C (Y!N} 773 p n x u "n m c cR m y at ctl a ry ro i ITEIM!# 3 a m= m N e 5. n 7 2 i ❑ O p m _ w m O a m � ». 1 m N — 0 C', ° m EL p m n m rr W 'J oT @ n m m 'Q _ ^, V w y i o ro = h rn o "' ' a co xv d J 0N p x c F. m N � re � �O G. O (0 o Q O m m ee o. `m m mo 0 CU a o m MATRIX CODE (see valid codes ID left) `�° O m K: C m' z z ° � m ° SAHPLETYPE (G=GRA9 C-COMP) C� n o` l N D m In O Iy w IN 0 3 In a C m i N m m 0 Or m N Op 0 Q j \ i m m ❑ <' ro m ZO n n N J Z m � O s O SAMPLE TEMPAT COLLECTION c N 1 n a OF CCNTAINEFts v 7 0> n D g in p_ C Unpreserved m y �, n a U", (%J a y ] j m 3 H2SO4 d z ' 0 d a r O m HNO3 b m o m r a❑ HCI O �. a NaOH p2i m O n Q Cu 0 Na25203 N Z r y y fl1 N Methanol EAZ - -Izrt Other w ➢ 0 Analyses Test YIN N o � � m 1,1-dichloroethane n C 1.2-dichloroprcpane a N) _ �. ro tetrachlorcethena m r'.)i O Q- N C N �v c 0 cr0 i n o w D fD m 0 � (D m a c C t n c y S m d � m m Residual Chlorine {YIN) rzi o� a m L J N o' 3 m � S `S f 0 rn c- CN Page 13 of 13 DATE:./(0 / zo 19 &j! J't it ENGINEERING GROUND WATER SAMPLING LOG Project Name: 9u(-b _ t �+ d . ' i ( kse-,,I Project No. /Task No.: 2V S )g 7 Well ID: M1N — Sampler(s): ' 1. H odso n Well Location: 5"Ci2 11 e4ew n Qvarry Qa 4r'1 1 e_A Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with 2 inches Zg-, 97 feet 45_.7Q feet R 73 feet [DTB-DTW] = J • 2 gallons gallons = 6P gallons Q19 l . Gv gallons Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (AS/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials D Is�lg 18.o S.q2 19�o rj.$a 10.E-�� T"N 17,3 (e,oeo ZzW9 I.q3 1.S 21•Z �N l 7, ) (o , 0 (�, 2 I I L) 1.10 -T" CQ l (Q 01 IT 3 (0,01 1 g 23 p,q z I L4, t .S zq i H Date of sample: .57/�, Before Sampling 1(001 ) 7, 3 (0.01 1 l q 23 a Comments (weather conditions, odor, color, silt, etc.): 1 1� U&.at � Wa5 10S elocjV or, Signature: .c y Date: ' �_ DATE: S/6 / Z 0 l 9 &Ju r `r ENGINEERING GROUND WATER SAMPLING LOG Project Name: Project No. /Task No.: Z 09 7 ! ZIP Hasc O z Well ID: M W - 3 7-i) Sampler(s):___) NuAso v, Well Location: Down rcmS/Pam fo4o_ ie-P'-F Qf 4f o- br; or, Q✓�ry Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches 7 C? feet feet ' 9 feet [DTB-DTW] 3, W gallons = gallons Z gallons 1 D, Z gallons Purged with: 5Bailer Puma Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (0/cm) Dis.O2 mg/L ORP my Turb. (ntu) Initials 11032 I(.S (. 31 R7(o I. S(o 9C00 qD R39 Z,7DO /o, 2 Is Date of sample: 5/6 / )J Before Sampling I j� q (p Comments (weather conditions, odor, color, silt, etc.): D A 5/ Signature:, Date: 51 2011 Q • /;i /Date:izI DATE:.5/CP/ ) aju r `C ENGINEERING GROUND WATER SAMPLING LOG Project Name: sur _Co,— 14i r l�T_ Project No. /Task No.: Z S 7 ha — Z Well ID: _ � - 17 Sampler(s): I � �-i t J SD rt /6, S)e 6oj r-) ; Well Location: Powrt da]q2 OA 61�� o✓J Qi 6,rrxl R� Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: 2 inches 0, D feet d feet '767• q a feet [DTB-DTW] _ g gallons gallons = 3S' gallons 3S. gallons Purged with: Bailer Other: Sampled with: Bailer m Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (µS/cm) Dis.O2 mg/L ORP my Turb. (ntu) Initials )( 's &1 9)3 2.2) —)o,� �, �� S15 12 IO 5 1908 111-7 - ,Q 1,3) s5 2 17►3 33 S13 aqq 125, -1 C), qI , fl M, 17,1) �a, 17 767Z 1.09 2ZZ, 0,�� 5-1' Date of sample: s/6,I16� Before Sampling 1'1q) ) , (g J 7 7q 2 1, 09 z Z Z, 3 0, Co SS Comments (weather conditions, odor, color, silt, as 705 _-1- Pa(+Iv doLdv orl Sl Signature: Date: 2D ig QA/QC Sign Off: Date: . A Z/ 7 _ _ 0 La BelLa DATE: ,71Z Iq GROUND WATER SAMPLING LOG Project Name: 19vfL Co. - k-i&Sc a`DC, 0L Project No. /Task No.: Well ID: �VJr�t/M� Sampler(s): � Well Location: PICA tb AA\N -3 Well Diameter: Initial Depth to Water (DTW) Depth to Bottom (DTP): Water Column Thickness (WCT): Calculation for One Well Volume (WV): 1 For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled witF Depth to Water before Sampling: 2 inches 0,00 feet 79, LIO feet 7S • Ll d feet [DTB-DTW] gallons _ gallons = 3'3,L4 gallons 346,_gallons feet Gallons Time Temp (°C) pH Cond. (us/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials CD E5 1q ,1 5:75 I ;,6-7 HS, a 5 9:� a-5 1Z.q 1(oDl 1-7.3 Ig5zy Z,5z ?,'2 1I,t5l % Z5, (C 1 1, S- 1/, S G, S3 5-(V 3/'1 O Z Z 10 1 ,-7 I )7,3 co, an 14�q 0A l3612- Date of sample: `712S/i� Before Sampling I(eC-p 1 1-7, DO 1 qs 0A1 ZID, J?. I -z Comments (weather conditions, odor, color, silt, etc.): Signature: Date: 714 3 ,/ZOIq QA/QC Sign Off: Date:2-1 STD q DATE: v�LJ' l iG ENGlNEER/NG GROUND_ WATER SAMPLING LOG Project Name: _gyrk. 0o . - 41 C 14- Se_U Project No. /Task No.: Well ID: MW- q Sampler(s): T. 14 L)JSon I S , Siebop vl Well Location: l osk Moud or7 Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): _ CIP Ovarr\ Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 2 inches 1T -79 feet Z q . 50 feet I � - I I feet [DTB-DTW] )'q gallons r = gallons Jam• % gallons Actual Amount Purged/Bailed: S -7 gallons Purged with: QB-ail-eV Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: i-1, g Z feet Gallons Time Temp (°C) pH Cond. (N.S/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials D 153 1-7, N s> c� , 3, qD l97. 5 q SS 1,9 !S3 I(�. I 5-, &Z 6-3, 3, Z.N i9q. q 10q 55 15, cp s &3 5-2.1 3, y Z. ZD , 2 I Z ,5- S5 Z, 9S Date of sample: Before Sampling Comments (weather conditions, odor, color, silt, etc.): �l �t ct9� wc�s rf�V G�Dc,y -74 s o ✓i "DI& / R Signature: Date: QA/QC Sign Off: Date: s�y�f DATE: -161ZU l l ENGINEERING GROUND WATER SAMPLING LOG Project Name: eiSui Project No. /Task No.: 21 0 �g 71 �p�� 0 Z Well ID: MVO Sampler(s): -rt6 5c,.i / 5, Well Location: Well Diameter: !.A M301.1 Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT): Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with Depth to Water before Sampling: 2 inches 13, 2-1 feet feet feet [DTB-DTW] 2- -7 gallons gallons gallons g. gallons 33.25 feet Gallons Time Temp (°C) pH Cond. (NQS/cm`/) Dis.02 ORP Turb. (ntuu�) Initials (x) II y/R r IS, J ,4/Img I . g Q�Qmy , � C�iy Cs Z, i 0i ! `. �`QV & z U , O 57 qq �%� C—O . lr �r� W O �+ l/�l 3.9 1 25, ?L oa f/ L . ✓'cJ i ✓ • O lL/s �J 1. lJ�� Date of sample: Before Sampling f q 1 '? `J t� S, g(o 2 �, 2, `7 3 Z 3 ,S 3 17, $ SS Comments (weather conditions, odor, color, silt, etc.): 1e� tow7Q r '�- �Id hlan k- @ Iq Z Signature: J!e��v Date: 1 • 1 1 /I�i / I� Date: DATE:. &/2©(q ®u r `r ENGINEERING GROUND WATER SAMPLING LOG Project Name: � v,'k Cd. — � f ks,� y Project No. /Task No.: 1S'1 g-71 1y ham" 02 Well ID: KAI - S Sampler(s): `/. )4 u son 1 S• S)ebc J n % V Well Location: Pow^ 4raj L-Lcr-os5 I lri -S" iy-c Pr,myO� an Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: WCT X 0.163 For 4" Well: WCT X 0.653 For THREE Well Volumes: WV X 3 2q inches feet 2� Oy feet S, O S feet [DTB-DTWI 2' S gallons gallons _ % S gallons Actual Amount Purged/Bailed: / , '_�' gallons Purged with: ail Pump Other: Sampled with: Bailer Pump Other: Depth to Water before Sampling: %� feet Gallons Time Temp (°C) pH Cond. (0/cm) Dis.O2 ml� ORP mfy Turb. Initials y V.S 5-0-5.7 ��D • f�[Lo `! /�(ntu) J 'qS T� 2.S IN qqq Co$.1 151 r� t7 1y5_5_ /y 3 (op3Z 5`, ►Z SS-1 152 714 7.5 I SOJ 1 �. s � (, Co . 2 Co 11 S, to Z I Z 71i Date of sample: S/6/11 Before Sampling /00 z S� S, ( �, �(p �� . (P-5. Llq193.1 2 Z . I �$ Comments (weather conditions, odor, color, silt, etc.): Vjo 0' a-,00f-9\/ 0-10UJv on S161ZO19, Signature: ^4� ���'y« 4 1 Date: 4 2d1 QA/QC Sign Off: Xw / � Date: ��� DATE: �/�/ZO 1 q aju r `r ENGINEERING GROUND WATER SAMPLING LOG Project Name: &urge CO. — F—►()LSeV Project No. /Task No.: zl8 g 71 lQ�'St OZ Well ID: /kAw — A'' D JJ Sampler(s): T i�yc_ So,-7 15 S% �jn,lk- Well Location: Next -D MW — 65. Well Diameter: Initial Depth to Water (DTW): Depth to Bottom (DTB): Water Column Thickness (WCT) Calculation for One Well Volume (WV): For 2" Well: For 4" Well: WCT X 0.163 WCT X 0.653 For THREE Well Volumes: WV X 3 Actual Amount Purged/Bailed: Purged with: Sampled with: 2 inches A feet 60, DO feet /9, q q feet [DTB-DTW] = 7 gallons _ Qallons gallons gallons Other: Other: Depth to Water before Sampling: feet Gallons Time Temp (°C) pH Cond. (gS/cm) Dis.02 mg/L ORP my Turb. (ntu) Initials s, 3 I. 3 -IZo. 9 1 15.3 ,32 101,00 1,70 -50.5 1D.9 TP i_ 1 S. Z. (0, S1 8.3, q 1 � 71 3.5.9 )5.E S S 3. I S1) 15, S (o , 05 3 5, (0 2 , IS )2-(,,9 5, 6B Ti+ Date of sample: 5/&/19 Before Sampling I lsl1 _-LS.� (Q, pg �s,(p 2, t3 1Z(2,q 5,(Q5 .7.},F Comments (weather conditions, odor, color, silt, etc.): Signature: "H /l., Date: QA/QC Sign Off: Date: 9 / DATE: 5/6/2019 &'u i `� ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. Project/Task No.: 2181871 / phase 02 Surface Point ID: SW-1 Sampler(s): T. Hudson / S. Slebodnik Location: Upstream of bridge on Quarry Rd. Field Parameters: Time of Sampling: pH: Temperature: Conductivity: Dissolved Oxygen: ORP: 1750 8.51 20.1 (°C) 96.1 —(PS/cm) 5.89 (mg/L) 135.0 (mV) Turbidity: 11.1 (ntu) Comments/Sample Description (weather conditions, odor, color, silt, etc.): The weather was partly loudy and 70's on 5/6/2019. Sketch of Sample Location (include flow direction, drainage pathways, etc.): i Ao "5 Signature•21"w- Date: ,/ Cyzo 1� QA/QC Sign Off: Date: SXiAl` DATE: 5/6/2019 &iu i `C ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. Project/Task No.: 2181871 phase 02 Surface Point ID: SW-2 Location: Down stream of SW- 3 Field Parameters: Sampler(s): T. Hudson / S. Slebodnik Time of Sampling: 1715 pH: 6.98 Temperature: 19.4 (° C) Conductivity: 91.8 (µS/cm) Dissolved Oxygen: 6.14 (mg/L) ORP: 119.8 (mV) Turbidity: 10.2 (NTU) Comments/Sample Description (weather conditions, odor, color, silt, etc.): The weather was partly cloudy and 70's on 5/6/2019. Sketch of Sample Location (include flow direction, drainage pathways, etc.): W oa�e� Aces <r-10� Signature: "9_ Date: !�I9IZ0/!2 QA/QC Sign Off: Date:_ ��ly/fig DATE: 5/6/2019 ENGINEERING SURFACE WATER MONITORING LOG Project Name: Burke County- Kirksey Dr. Project/Task No.: 2181871 phase 02 Surface Point ID: SW-3 Sampler(s): T. Hudson / S. Slebodnik Location: 24" pipe @ base of landfill along river Field Parameters: Time of Sampling: 1725 pH: 7.92 Temperature: 18.5 (° C) Conductivity: 986 (µS/cm) Dissolved Oxygen: 5.93 (mg/L) ORP: 183.3 (mV) Turbidity: 17.5 (NTU) Comments/Sample Description (weather conditions, odor, color, silt, etc.): The weather was partlycy and 70's on 5/6/2019. Sketch of Sample Location (include flow direction, drainage pathways, etc.): 0601d Gre� ' rlaw M� r ' Q• %.:/ D• APPENDIX 2 Historical Data Table A2-1 Historical Groundwater Elevations Table A2-2 Historical Groundwater Constituents Table A2-3 Historical Groundwater Field Parameters Table A2-4 Historical Surface Water Constituents Table A2-5 Historical Surface Water Field Parameters TABLE A2-1: Historical Groundwater Elevations Location Background Downgradient MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-6D TOC Elevation: 1119.82 1077.23 1021.90 1022.76 1054.99 1137.43 1065.00 1065.00 Well Depth: 35.65 45.70 26.69 78.40 29.50 49.80 25.00 60.00 31-Oct-06 1086.68 1049.61 1014.16 1022.76 1030.93 1096.03 1054.60 1053.22 29-May-07 1087.59 1050.65 1015.08 1022.76 1032.01 1096.91 1054.24 1053.12 27-Nov-07 1085.59 1049.67 1014.06 1022.76 1029.75 1095.15 1054.31 1053.15 2 7-May-08 1085.5 6 1049.5 7 1014.24 102 2.7 6 1030.43 1093.61 1054.21 1053.05 05-Nov-08 1085.12 1049.59 1013.66 1022.46 1029.28 1092.43 1054.23 1053.00 f 1085.94 1050.03 1014.99 1022.76 1032.62 1092.41 1054.85 1053.55 19-Nov-09 1086.91 1050.06 1015.18 1022.76 1032.27 1094.75 1054.84 1053.44 14-Jun-10 1089.98 1050.93 1015.53 1022.76 1033.36 1100.14 1054.33 1053.09 29-Nov-10 1087.62 1050.02 1014.63 1022.76 1030.43 1098.45 1054.53 1053.02 31-May-11 1087.43 1050.02 1014.86 1022.76 1031.78 1096.47 1054.31 1053.06 19-Dec-11 1085.70 1049.85 1014.33 1022.76 1030.57 1094.41 1053.78 1053.00 30-May-12 1086.81 1050.13 1014.99 1022.76 1032.28 1094.12 1054.44 1053.05 03-Dec-12 1085.72 1052.89 1014.46 1022.76 1030.11 1092.06 1054.29 1052.88 11-Jun-13 1088.62 1050.98 1016.30 1022.76 1035.70 1096.08 1058.81 1054.43 29-Oct-13 1090.35 1050.82 1015.75 1022.76 1033.21 1100.48 1054.50 1053.10 05-May-14 1090.34 1031.53 1015.96 1022.76 1034.94 1101.05 1054.76 1053.36 20-Oct-14 1089.05 1050.36 1015.37 1022.76 1032.09 1100.06 1054.57 1044.10 19-May-15 1088.08 1050.25 1015.64 1022.76 1032.77 1097.66 1054.30 1053.05 7-Dec-15 1088.07 1050.26 1014.93 1022.76 1033.54 1096.38 1055.20 1053.55 2-May-16 1090.09 1050.09 1015.40 1022.76 1031.24 1100.12 1054.00 1052.75 12-Dec-16 1087.07 1050.26 1014.80 1022.76 1029.99 1097.68 1054.15 1052.83 26-Jun-17 1086.82 1050.03 1015.10 1022.76 1031.89 1095.63 1053.84 1052.30 14-Dec-17 - 1050.18 1015.15 1022.76 1030.75 1094.65 1054.55 1053.07 16-May-18 - 1050.98 1015.88 1022.76 1033.79 1095.32 1055.10 1053.60 3-Dec-18 1098.92 1050.53 1016.07 1022.76 1034.70 1098.14 1055.09 1053.34 6-May-19 1095.28 1051.26 1016.20 1022.76 1037.20 1104.22 1055.05 1053.44 Notes: TOC = Top of Casing. All elevations are referenced as feet above mean sea level. All depths measured in feet below TOC. MW-6S and MW-6D TOC Elevations are estimated. MW-3D exhibits artesian conditions. MW-1 damaged approx. June 2017 Burke County, Kirksey Drive Landfill Permit No. 12-01 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6s MW-6D Blanks INORGANICS Antimony 28-Apr-94 NR 1 1.0 ND 4.0 NI NI NI NI NI NA 3-May-00 NR 30 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 30 NA ND ND ND ND ND ND ND NA 29-May-01 NR 30 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 30 NA ND ND ND ND ND ND ND ND 21-May-02 NR 30 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 30 NA ND ND ND ND ND ND ND ND 14-May-03 NR 30 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 30 ND ND ND ND ND ND ND ND ND 5-May-04 NR 30 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 30 ND ND ND ND ND ND ND ND ND 25-May-05 NR 30 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 30 ND ND ND ND ND ND ND ND ND 24-May-06 NR 30 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 30 ND ND ND ND ND ND ND ND ND 29-May-07 NR 6 ND ND ND ND ND ND ND ND ND GWPS = 1.4 ug/L (10/23/07) 28-Nov-07 NR 6 ND ND ND ND ND ND ND ND ND 28-May-08 2.7 6.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.6 6.0 Dry 14.1 3.8 J ND ND ND ND ND ND 2-Jun-09 2.6 6.0 ND 2.9 J ND ND ND ND ND ND ND 19-Nov-09 2.6 6.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 2.6 6.0 ND ND ND ND ND ND ND ND ND GWPS = 1 pg/L (8/1/10) 29-Nov-10 2.6 6.0 ND ND ND ND ND ND ND ND ND 31-May-11 2.6 6.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 6.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 6.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 6.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 6.0 6.5 7.6 ND ND ND ND ND ND ND 6-May-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA6010 5.0 6.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA6010 3.8 6.0 ND 7.1 ND ND ND ND ND ND ND 7-Dec-15 EPA6010 3.8 6.0 ND 4.9 J ND ND ND ND ND ND ND 2-May-16 EPA6010 3.8 6.0 ND 6.4 ND ND ND ND ND ND ND 12-Dec-16 EPA6010 3.8 6.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA6010 3.9 6.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA6010D 3.9 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA6010D 3.9 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 1 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Arsenic 6-Oct-94 NR 5 ND ND 5.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.9 J 2.5 J ND 4.1 J 3.0 J ND NC2L = 50 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 2.6 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 2.7 10.0 Dry ND 6.0 B ND ND 3.3 B ND ND 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 2.7 10.0 3.0 J ND 5.9 J ND ND ND ND ND ND NC21- = 10 ug/L (01/01/10) 15-Jun-10 2.7 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 2.7 10.0 ND ND 4.9 J ND ND ND ND ND ND 31-May-11 2.7 10.0 3.3 J 3.0 J 9.9 J ND ND ND ND ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND 3.4 J ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND 5.2 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.4 J ND 6.8 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 5.1 J ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 2 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL P16 MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Barium 28-Apr-94 NR 100 110 840 590 NI NI NI NI NI NA 3-May-00 NR 500 NA 870 550 ND ND ND ND ND ND 8-Nov-00 NR 500 NA 810 ND ND ND ND ND ND ND 29-May-01 NR 500 NA 890 540 ND ND ND ND ND ND 6-Nov-01 NR 500 NA 790 ND ND ND ND ND ND ND 21-May-02 NR 500 NA 800 510 ND ND ND ND ND ND 13-Nov-02 NR 500 NA 650 ND ND ND ND ND ND ND 14-May-03 NR 500 ND 690 530 ND ND ND ND ND ND 19-Nov-03 NR 500 ND 780 ND ND ND ND ND ND ND 5-May-04 NR 500 ND 810 ND ND ND ND ND ND ND 9-Nov-04 NR 500 ND 890 ND ND ND ND ND ND ND 25-May-05 NR 500 ND 730 ND ND ND ND ND ND ND 2-Nov-05 NR 500 ND 930 ND ND ND ND ND ND ND 24-May-06 NR 500 ND 915 ND ND ND ND ND ND ND 1-Nov-06 NR 500 ND 937 ND ND ND ND ND ND ND 29-May-07 NR 100 107 882 484 127 94.9 J 29.9 J 33.0 J 15.1 J ND NC21- = 2,000 pg/L (10/23/07) 28-Nov-07 NR 100 159 945 434 132 128 34.5 J 25.0 J 16.9 J 0.30 J 28-May-08 0.2 100 Dry 812 394 124 101 31.0 J 37.0 J 13.8 J 0.33 J 5-Nov-08 0.20 100 Dry 773 385 119 88.4 J 22.6 B 74.4 J 13.0 B 10.5 J 2-Jun-09 0.20 100 80.4 J 795 432 118 90.8 J 20.8 B 85.4 J 10.5 B 15.2 J 19-Nov-09 0.20 100 114 758 464 138 103 32.6 B 106 12.5 B 19.8 J NC21L = 700 pg/L (01/01/10) 15-Jun-10 0.20 100 141 751 495 162 163 43.1 B 72.8 B 13.1 B 26.3 J 29-Nov-10 0.20 100 89.0 J 843 416 169 128 36.2 J 71.8 J 11.9 J ND 31-May-11 0.20 100 92.4 J 949 464 190 103 30.8 J 33.5 J 13.9 J ND 19-Dec-11 5.0 100 126 809 435 164 214 39.5 J 39.7 J 13.0 J ND 30-May-12 5.0 100 64.7 J 905 475 175 151 27.9 J 26.3 J 13.1 J ND 3-Dec-12 5.0 100 107 739 431 177 97.8 J 25.3 J 51.9 J 14.7 J ND 11-Jun-13 5.0 100 136 662 539 INS 96.2 J 35.6 B 55.9 B 12.0 B 13.7 J 29-Oct-13 5.0 100 135 906 534 199 88.8 J 34.5 J 23.9 J 12.6 J ND 6-May-14 EPA 6010 5.0 100 81.4 J 772 439 186 110 31.9 J 45.2 J 12.4 J ND 21-Oct-14 EPA 6010 5.0 100 82.2 J 1050 415 194 86.2 J 29.2 J 22.4 J 11.8 J ND 19-May-15 EPA 6010 2.5 100 94.0 J 421 192 85.6 J 32.9 J 43.6 J 12.2 J ND 7-Dec-15 EPA 6010 2.5 100 109.0 1210 470 205 157 44.7 J 43.6 J 12.3 J ND 2-May-16 EPA 6010 2.5 100 100.0 J 1060 497 186 73.2 J 38.5 J 59.8 J 11.4 J ND 12-Dec-16 EPA 6010 2.5 100 78.7 J 1040 388 167 82 J 28 J 16.3 J 8.1 J ND 26-Jun-17 EPA 6010 2.5 100 --- 1470 547 218 89.3 J 35.4 J 29.3 J 12.8 J 2.5 J 14-Dec-17 EPA 6010 2.5 100 --- 1240 498 212 87.8 J 27.7 J 62.2 J 12.8 J ND 14-May-18 EPA 6010 2.5 100 --- 888 566 206 75.5 J 40.4 J 214 12.0 J ND 4-Dec-18 EPA 6010D 2.5 5 --- 1160 507 205 82 27.1 42.6 12.8 ND 6-May-19 EPA 6010D 2.5 5 --- 1040 454 181 82.6 37.5 43.7 12.2 ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 3 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Beryllium 12-May-99 NR 2 ND 2.0 ND ND 2.0 2.1 NI NI ND 19-Oct-99 NR 2 ND ND ND ND ND 4.0 NI NI ND 3-May-00 NR 2 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 2 NA ND ND ND ND 2.0 ND ND ND 29-May-01 NR 2 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 2 NA ND ND ND ND ND ND ND ND 21-May-02 NR 2 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 2 NA 2.4 2.3 2.1 ND ND ND ND ND 14-May-03 NR 2 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 2 ND ND ND ND ND ND ND ND ND 5-May-04 NR 2 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 2 ND ND ND ND ND ND ND ND ND 25-May-05 NR 2 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 2 ND ND ND ND ND ND ND ND ND 24-May-06 NR 2 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 2 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND GWPS = 4 ug/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.10 1.0 Dry ND ND ND ND 0.11 J 0.17 J ND ND 2-Jun-09 0.10 1.0 ND ND ND ND ND ND 0.18 J ND ND 19-Nov-09 0.10 1.0 ND ND ND ND ND ND 0.11 J ND ND 15-Jun-10 0.10 1.0 ND ND ND ND 0.26 J 0.18 J ND ND ND 29-Nov-10 0.10 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.10 1.0 ND ND 0.21 J ND ND 0.24 J ND ND ND 19-Dec-11 1.0 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 4 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cadmium 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 1 NA 8.0 4.0 J 2.0 J 2.0 J 2.0 J 2.0 J ND ND 8-Nov-00 NR 1 NA 13.0 4.0 ND ND 4.0 1.0 ND ND 29-May-01 NR 1 NA 13.0 5.0 ND ND 2.0 J 1.0 J ND ND 6-Nov-01 NR 1 NA 10.0 3.6 ND ND ND ND ND ND 21-May-02 NR 1 NA 7.9 3.0 ND ND ND ND ND ND 13-Nov-02 NR 1 NA 11.0 4.7 1.5 ND ND ND 1.1 ND 14-May-03 NR 1 11.0 12.0 7.1 ND ND ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND ND 2.3 1.1 ND ND 5-May-04 NR 1 ND 1.6 ND ND ND ND ND ND ND 9-Nov-04 NR 1 2.2 13.0 4.5 ND ND ND ND ND ND 25-May-05 NR 1 ND ND ND ND 16.0 ND ND ND ND 2-Nov-05 NR 1 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 1 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 1 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC2L = 1.75 Ng/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND ND ND ND ND ND 28-May-08 0.5 1.0 Dry 1.7 ND ND 2.6 ND ND ND ND 5-Nov-08 0.50 1.0 Dry 0.50 J ND ND ND ND ND ND ND 1-Jun-09 0.50 1.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND ND 1.3 ND ND ND NC21- = 2 pg/L (01/01/10) 15-Jun-10 0.50 1.0 ND ND ND ND 1.1 ND ND ND ND 29-Nov-10 0.50 1.0 ND ND ND ND ND 0.80 J ND ND ND 31-May-11 0.50 1.0 ND 0.78 J ND ND ND ND ND ND ND 19-Dec-11 1.0 1.0 ND 1.6 ND ND ND 6.6 ND ND ND 30-May-12 1.0 1.0 ND 5.0 ND ND ND ND ND ND ND 3-Dec-12 1.0 1.0 ND 2.3 ND ND ND ND ND ND ND 11-Jun-13 1.0 1.0 ND 2.0 ND INS ND ND ND ND ND 29-Oct-13 1.0 1.0 ND 4.5 ND 2.0 ND ND ND ND ND 6-May-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 1.0 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 0.5 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 0.5 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 0.5 1.0 --- 0.91 J ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 0.5 1.0 --- 2 0.78 J ND ND ND ND ND ND 6-May-19 EPA 6010D 0.5 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 5 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chromium 28-Apr-94 NR 20 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA 16.0 ND ND 14.0 14.0 12.0 ND ND 8-Nov-00 NR 10 NA 17.0 ND ND ND 20.0 ND ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 10.0 J ND ND ND 6-Nov-01 NR 10 NA 12.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 12.0 ND ND ND ND ND ND ND 14-May-03 NR 10 12.0 ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC2L = 50 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 2.9 J ND ND ND ND 28-May-08 0.4 10.0 Dry ND ND ND 2.3 B 0.80 B ND ND 0.85 J 5-Nov-08 0.40 10.0 Dry ND ND ND ND 0.46 J 0.59 J ND ND 2-Jun-09 0.40 10.0 ND ND ND ND 2.8 J 0.42 J 0.65 J ND ND 19-Nov-09 0.40 10.0 ND 1.8 B 0.65 B ND 2.7 B ND ND ND 1.1 J NC21- = 10 pg/L (01/01/10) 15-Jun-10 0.40 10.0 ND 0.89 J 2.0 J 1.7 J 12.6 1.9 J 1.3 J ND ND 29-Nov-10 0.40 10.0 ND 3.8 J 3.5 J 1.2 J 5.1 J 0.88 J ND ND ND 31-May-11 0.40 10.0 1.4 B 2.1 B 8.4 J 1.3 B 3.6 B 2.1 B 2.2 B 2.5 B 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 15.4 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 8.3 J ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS 5.2 J ND ND 6.2 J ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND 8.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND 2.8 J ND ND 4.2 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 3.7 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 3.1 J ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND 3.4 J ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 2.5 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 6 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Cobalt 6-Oct-94 NR 10 32.0 172 35.0 NI NI NI NI NI NA 3-May-00 NR 10 NA 110 26.0 ND ND 18.0 21.0 ND ND 8-Nov-00 NR 10 NA 110 ND ND ND 25.0 11.0 ND ND 29-May-01 NR 10 NA 130 21.0 ND ND 12.0 ND ND ND 6-Nov-01 NR 10 NA 110 14.0 ND ND ND ND ND ND 21-May-02 NR 10 NA 110 15.0 ND ND ND ND ND ND 13-Nov-02 NR 10 NA 110 15.0 12.0 ND ND ND ND ND 14-May-03 NR 10 140 100 26.0 ND ND ND ND ND ND 19-Nov-03 NR 10 150 110 27.0 ND ND ND ND ND ND 5-May-04 NR 10 51.0 110 17.0 13.0 ND ND ND ND ND 9-Nov-04 NR 10 54.0 100 ND ND ND ND ND ND ND 25-May-05 NR 10 79.0 95.0 15.0 ND ND ND ND ND ND 2-Nov-05 NR 10 47.0 100 ND ND ND ND ND ND ND 24-May-06 NR 10 62.9 116 10.0 ND ND 10.4 ND ND ND 1-Nov-06 NR 10 63.2 114 ND ND ND ND ND ND ND 29-May-07 NR 10 60.1 105 6.3 J 10.7 ND ND 2.4 J ND ND GWPS = 70 ug/L (10/23/07) 28-Nov-07 NR 10 43.1 110 3.6 J 5.1 J ND ND ND ND ND 28-May-08 0.6 10.0 Dry ND ND 8.8 J ND ND ND ND ND 5-Nov-08 0.60 10.0 Dry 35.7 ND 9.4 B 0.86 B 3.9 B 5.3 B 1.6 B 3.5 J 1-Jun-09 0.60 10.0 158 158 52.8 10.9 B 12.3 B 7.8 B 14.9 B 6.8 B 3.3 J 19-Nov-09 0.60 10.0 126 87.7 18.7 4.5 J ND 0.96 J 5.9 J ND ND 15-Jun-10 0.60 10.0 155 186 53.3 2.9 J 5.2 J 2.2 J 2.9 J 2.3 J ND GWPS = 1 ug/L (10/1/10) 29-Nov-10 0.60 10.0 110 233 67.3 0.69 J ND 1.2 J 3.9 J 3.7 J ND 31-May-11 0.60 10.0 38.6 111 19.2 19.3 1.3 J ND 1.1 J ND ND 19-Dec-11 5.0 10.0 ND 63.8 ND ND ND ND ND ND ND 30-May-12 5.0 10.0 85.6 144 38.4 5.2 J ND ND ND ND ND 3-Dec-12 5.0 10.0 36.0 92.9 10.4 5.2 J ND ND ND ND ND 11-Jun-13 5.0 10.0 178 220 85.7 INS 5.4 J ND 7.1 J 5.8 J ND 29-Oct-13 5.0 10.0 226 267 96.1 ND ND ND ND 6.6 J ND 6-May-14 EPA 6010 5.0 10.0 39.0 65.2 ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 43.8 118 9.1 J ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 47.7 117 10.7 ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 52.0 126 13.9 ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 56.2 120 15.6 ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 24.6 99.8 7.1 J ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 - 137 12.4 ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 - 114 11.0 ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 - 102 20.2 ND ND ND 4.2 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 - 120 17.3 2.6 J ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 - 107 14.4 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 7 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Copper 12-May-99 NR 5 13.0 22.0 ND ND 45.0 5.1 NI NI ND 19-Oct-99 NR 200 ND ND ND ND ND ND NI NI ND 3-May-00 NR 200 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 200 NA ND ND ND ND ND ND ND ND 29-May-01 NR 200 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 200 NA ND ND ND ND ND ND ND ND 21-May-02 NR 200 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 200 NA ND ND ND ND ND ND ND ND 14-May-03 NR 200 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 200 ND ND ND ND ND ND ND ND ND 5-May-04 NR 200 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 200 ND ND ND ND ND ND ND ND ND 25-May-05 NR 200 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 200 ND ND ND ND ND ND ND ND ND 24-May-06 NR 200 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 200 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 1.7 J ND ND 1.6 J ND ND NC21- = 1,000 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND 3.30 J ND ND ND ND 28-May-08 0.3 10 Dry 0.49 B ND ND 2.8 J 0.76 B 0.50 B ND 0.38 J 5-Nov-08 0.30 10 Dry 0.89 B ND ND ND ND 0.72 B ND 0.94 J 2-Jun-09 0.30 10 9.7 J ND ND ND 1.5 J ND ND ND ND 19-Nov-09 0.30 10 5.3 J ND 0.35 J ND 2.1 J 0.41 J 1.0 J ND ND 15-Jun-10 0.30 10 13.9 ND ND ND 11.0 5.9 J 1.4 J ND ND 29-Nov-10 0.30 10 2.0 J ND 2.6 J 0.31 J 6.0 J 1.2 J 1.2 J ND ND 31-May-11 0.30 10 4.5 J 5.1 J 13.2 ND 0.98 J ND ND ND ND 19-Dec-11 5.0 10 10.9 ND 5.5 J ND 14.1 ND ND ND ND 30-May-12 5.0 10 ND ND ND ND 10.8 ND ND ND ND 3-Dec-12 5.0 10.0 5.2 J ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 13.1 B 5.1 B ND INS ND ND ND ND 10.8 29-Oct-13 5.0 10.0 10.2 ND ND 8.9 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 5.2 J 3.7 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 7.9 J 7.7 J 3.6 J ND 7.4 J ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 5.8 J ND ND ND 3.6 J ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 7.9 J ND ND 3.2 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.9 J 2.8 J 51.3 ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 8.3 5.8 3.2 J ND 3.1 J ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 8 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Lead 28-Apr-94 NR 1 6.0 5.0 2.0 NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND 12.0 ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND 31.0 10.0 ND ND 29-May-01 NR 10 NA 12.0 J ND ND ND 12.0 J ND ND ND 6-Nov-01 NR 10 NA 11.0 ND ND ND ND ND ND ND 21-May-02 NR 10 NA 10.0 J ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 14.0 ND ND ND ND ND ND ND 14-May-03 NR 10 38.0 10.0 J ND ND ND ND ND ND ND 19-Nov-03 NR 10 16.0 ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND 14.0 ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND 11.7 ND ND ND 22.6 ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 2.5 B 4.2 B 3.5 B 4.6 B 6.0 B 4.5 B 2.9 B ND 6.1 J NC21- = 15 pg/L (10/23/07) 28-Nov-07 NR 10 9.8 J 7.4 J 2.0 J ND ND ND ND ND ND 28-May-08 4 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 4.0 10.0 Dry ND ND ND ND ND ND ND ND 1-Jun-09 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 4.0 10.0 4.6 J ND ND ND ND ND ND ND ND 15-Jun-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 4.0 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 4.0 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.0 10.0 6.1 J ND ND ND 5.4 J ND ND ND ND 30-May-12 5.0 10.0 ND 5.9 J ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 5.0 10.0 6.7 J ND ND 5.4 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND 5.1 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 2.9 J 6.2 J ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 4.6 J 6.6 J 2.9 J 4.4 J 2.6 J 3.0 J ND ND ND 2-May-16 EPA 6010 2.5 10.0 4.4 J 5 J ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 6.1 J 6.1 J ND 3.9 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- 6.8 J 2.6 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- 5.4 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND 3.5 J 4.1 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6O1OD 2.5 5.0 --- 4.9 J 3.2 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 9 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Nickel 12-May-99 NR 5 11.0 36.0 11.0 NA 23.0 30.0 NI NI ND 19-Oct-99 NR 50 ND ND ND ND ND 59.0 NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND 21.3 J ND ND ND ND ND NC21- = 100 Ng/L (10/23/07) 28-Nov-07 NR 50 ND 2.4 J ND 20.4 J 2.5 J ND ND ND ND 28-May-08 1.7 50.0 Dry 9.1 J 10.5 J 31.9 J 2.1 J ND ND ND ND 5-Nov-08 1.7 50.0 Dry 11.6 J 5.9 B 26.3 J 2.8 B ND ND ND 2.2 J 2-Jun-09 1.7 50.0 14 J 8.9 J 3.8 J 21.8 J 2.3 J ND ND ND ND 19-Nov-09 1.7 50.0 10.3 B 8.6 B 3.1 B 19.8 J 2.3 B ND ND ND 2.2 J 15-Jun-10 1.7 50.0 5.9 J 6.7 J ND 14.5 J 4.8 J ND ND ND ND 29-Nov-10 1.7 50.0 4.7 J 7.6 J ND 17.3 J ND ND ND ND ND 31-May-11 1.7 50.0 3.5 B 15.9 J 11.8 J 23.0 J 2.8 B ND ND ND 2.3 J 19-Dec-11 5.0 50.0 ND 8.8 J ND 18.9 J ND ND ND ND ND 30-May-12 5.0 50.0 ND 9.4 J ND 19.9 J ND ND ND ND ND 3-Dec-12 5.0 50.0 ND 7.5 J ND 20.8 J ND ND ND ND ND 11-Jun-13 5.0 50.0 ND 6.8 J ND INS ND ND ND ND ND 29-Oct-13 5.0 50.0 ND 7.1 J ND 20.6 J ND ND ND ND ND 6-May-14 EPA 6010 5.0 50.0 ND 10.1 J ND 21.1 J ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 50.0 ND 16.9 J ND 24.3 J ND ND ND ND ND 19-May-15 EPA 6010 2.5 50.0 ND 15.8 J 3.1 J 23.8 J ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 50.0 2.6 J 17.0 J 4.3 J 26.4 J 3.8 J ND ND ND ND 2-May-16 EPA 6010 2.5 50.0 ND 14.9 J 3.8 J 23.3 J ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 50.0 2.6 J 14.6 J 3.5 J 21.0 J ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 50.0 --- 20.9 J 4.6 J 25.6 J ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 50.0 --- 17.6 J 3.6 J 26.6 J ND ND ND ND ND 14-May-18 EPA 6010 2.5 50.0 --- 13.9 J 5.1 J 27.9 J ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- 17.2 4.3 J 26.3 ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- 14.5 4.4 J 25.7 3 J ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 10 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Selenium 12-May-97 NR 5 ND ND ND NI NI NI NI NI NA 3-May-00 NR 20 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 20 NA ND ND ND ND ND ND ND ND 29-May-01 NR 20 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 20 NA ND ND ND ND ND ND ND ND 21-May-02 NR 20 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 20 NA ND ND ND ND ND ND ND ND 14-May-03 NR 20 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 20 ND ND ND ND ND ND ND ND ND 5-May-04 NR 20 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 20 ND ND ND ND ND ND ND ND ND 25-May-05 NR 20 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 20 ND ND ND ND ND ND ND ND ND 24-May-06 NR 20 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 20 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND 2.5 J 4.6 J ND ND ND NC2L = 50 ug/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND 2.4 J 28-May-08 3.8 10.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 3.8 10.0 Dry 29.6 12.3 B ND ND 5.6 B ND 5.1 B 4.2 J 2-Jun-09 3.8 10.0 ND 5.6 J ND ND ND ND ND ND ND 19-Nov-09 3.8 10.0 ND 5.6 J ND ND ND 5.5 J 5.0 J ND ND NC21- = 20 ug/L (01/01/10) 15-Jun-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 3.8 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 3.8 10.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 10.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 10.0 10.0 11.5 16.8 ND ND ND ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 10.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 16.2 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 10.0 ND 5.2 J 5.7 J ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 11 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Silver 28-Apr-94 NR 1 ND ND ND NI NI NI NI NI NA 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10.0 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND 2.5 J ND ND 2.2 J ND ND NC2L = 17.5 pg/L (10/23/07) 28-Nov-07 NR 10 ND ND ND ND ND ND ND ND ND 28-May-08 0.1 10.0 Dry 1.4 J 0.41 J 0.54 J ND ND ND ND ND 5-Nov-08 0.10 10.0 Dry 2.4 J 0.86 B 0.87 B 0.12 B 0.15 B 0.18 B 0.18 B 0.20 J 2-Jun-09 0.10 10.0 ND 0.90 J ND 0.37 J ND ND ND ND ND 19-Nov-09 0.10 10.0 0.68 J 1.7 J 0.86 J 1.0 J 0.19 J 0.22 J 0.30 J 0.30 J ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.10 10.0 ND 0.25 J 0.31 J 0.50 J 0.15 J ND ND 0.14 J ND 29-Nov-10 0.10 10.0 ND 0.58 J 0.11 J 0.59 J ND ND ND ND ND 31-May-11 0.10 10.0 0.91 J 2.9 J 0.81 J 0.71 J ND 0.11 J 0.30 J ND ND 19-Dec-11 5.0 10.0 ND ND ND ND ND ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.0 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.0 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 2.5 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 6010D 2.5 5.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 12 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Thallium 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA 26.0 ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 10.0 ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 13.0 16.0 12.0 ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5.5 ND ND ND ND ND 0.066 ND ND ND GWPS = 0.28 Ng/L (10/23/07) 28-Nov-07 NR 5.5 0.215 J ND ND ND 0.155 J 0.074 J ND ND ND 28-May-08 3 5.5 Dry ND ND ND 3.8 J ND ND ND ND 5-Nov-08 3.0 5.5 Dry 3.1 J ND ND ND ND ND ND ND 2-Jun-09 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Nov-09 3.0 5.5 ND ND ND ND ND 3.5 J ND ND ND 15-Jun-10 3.0 5.5 5.5 B 7.8 B 4.2 B ND ND 7.0 B ND ND 3 J GWPS = 0.2 ug/L (10/1/10) 29-Nov-10 3.0 5.5 4.6 B 4.1 B 4.1 B ND ND {4.8) J ND ND 4.0 {ND) J 31-May-11 3.0 5.5 ND ND ND ND ND ND ND ND ND 19-Dec-11 5.4 5.5 ND ND ND ND ND ND ND ND ND 30-May-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 3-Dec-12 5.4 5.5 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.4 5.5 ND ND ND INS ND ND ND ND ND 29-Oct-13 5.4 5.5 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 6010 5.4 5.5 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 6010 5.0 5.5 6.9 7.5 ND ND ND ND ND ND ND 2-May-16 EPA 6010 5.0 5.5 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 6010 5.0 5.5 8.3 B ND ND ND ND ND ND ND 5.5 J 26-Jun-17 EPA 6020B 0.0 5.5 - ND ND ND ND 0.075 J ND ND ND 14-Dec-17 EPA 6020B 0.03 0.1 - ND ND ND ND 0.061 J ND ND ND 14-May-18 EPA 6020 0.50 5.5 - ND ND ND ND ND ND ND ND 4-Dec-18 EPA 6020B 0.06 0.1 - ND ND ND ND ND ND ND ND 6-May-19 EPA 6020B 0.06 0.1 - ND ND ND ND 0.087 J ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 13 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Vanadium 19-Oct-99 NR 40 110 51.0 ND ND 61.0 210 NI NI ND 3-May-00 NR 40 NA 61.0 ND ND ND 49.0 ND ND ND 8-Nov-00 NR 40 NA ND ND ND ND 69.0 ND ND ND 29-May-01 NR 40 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 40 NA ND ND ND ND ND ND ND ND 21-May-02 NR 40 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 40 NA ND ND ND ND ND ND ND ND 14-May-03 NR 40 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 40 ND ND ND ND ND ND ND ND ND 5-May-04 NR 40 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND ND ND ND ND ND 25-May-05 NR 40 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 40 ND ND ND ND ND ND ND ND ND 24-May-06 NR 40 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 40 ND ND ND ND ND ND ND ND ND 29-May-07 NR 25 ND ND ND ND ND ND 1.5 J ND ND GWPS = 3.5 pg/L (10/23/07) 28-Nov-07 NR 25 ND ND ND ND 10.0 J 1.1 J ND ND ND 28-May-08 0.2 25.0 Dry 0.75 J 0.90 J ND 5.5 J 2.5 J 1.2 J 0.22 J ND 5-Nov-08 0.20 25.0 Dry 1.2 B 0.78 B ND 0.86 B 0.82 B 1.5 B ND 0.85 J 2-Jun-09 0.20 25.0 1.0 B 3.1 B 1.8 B 1.0 B 9.5 J 1.3 B 2.4 B 0.41 B 1.2 J 19-Nov-09 0.20 25.0 0.74 B 2.2 B 2.9 B 0.86 B 6.6 J 1.2 B 2.0 B 0.25 B 0.58 J 15-Jun-10 0.20 25.0 2.0 B 1.4 B 1.3 B 0.34 B 27.4 5.0 B 2.2 B ND 1.2 J GWPS = 0.3 pg/L (10/1/10) 29-Nov-10 0.20 25.0 ND 1.3 J 5.4 J 1.6 J 9.4 J 1.4 J 0.45 J ND ND 31-May-11 0.20 25.0 ND ND 12.0 J 3.3 J 6.1 J 2.2 J 0.85 J 0.31 J ND 19-Dec-11 5.0 25.0 6.6 J ND 6.2 J ND 24.3 J 6.3 J ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 19.3 J ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 5.0 25.0 ND ND ND INS 13.2 J ND ND ND ND 29-Oct-13 5.0 25.0 ND ND ND ND 7.5 J ND ND ND ND 6-May-14 EPA 6010 5.0 25.0 ND ND ND ND 7.6 J ND ND ND ND 21-Oct-14 EPA 6010 5.0 25.0 ND 5.4 J ND ND ND ND ND ND ND 19-May-15 EPA 6010 2.5 25.0 5.7 J 13 J 5.3 J ND 4.3 J ND ND ND ND 7-Dec-15 EPA 6010 2.5 25.0 8.3 J 16.6 J 7.3 J ND 19.4 J 5.6 J ND ND ND 2-May-16 EPA 6010 2.5 25.0 3.9 J 5.0 J 3.7 J ND 7.9 J 3.4 J ND ND ND 12-Dec-16 EPA 6010 2.5 25.0 6.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 6010 2.5 25.0 --- 4.2 J 3.3 J ND ND 2.9 J ND ND ND 14-Dec-17 EPA 6010 2.5 25.0 --- 5.1 J ND ND ND ND ND ND ND 14-May-18 EPA 6010 2.5 25.0 --- 3.6 J ND ND 2.5 J 5.8 J 2.7 J ND ND 4-Dec-18 EPA 6010D 2.5 5.0 --- ND 3.0 J ND 6.0 ND ND ND ND Resample > 8-Feb-19 EPA 6010D 2.5 5.0 --- - --- --- ND - - 6-May-19 EPA 6010D 2.5 5.0 --- 4.1 J ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 14 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Zinc 28-Apr-94 NR 10 12.0 ND ND NI NI NI NI NI NA 3-May-00 NR 50 NA ND ND 81.0 50.0 J ND ND ND ND 8-Nov-00 NR 50 NA 50.0 ND ND 50.0 100 50.0 ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND 80.0 ND ND ND 5-May-04 NR 50 110 ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 5.1 B ND ND 7.9 B 5.0 B 4.5 B 3.2 B 4.7 B 2.0 J NC2L = 1,050 pg/L (10/23/07) 28-Nov-07 NR 10 26.3 ND 4.5 J 8.4 J 6.7 J 5.8 J ND 4.2 J ND 28-May-08 0.4 10.0 Dry 18.9 2.9 B 93.9 5.7 B 7.0 B 5.5 B 4.9 B 2.1 J 5-Nov-08 0.40 10.0 Dry ND ND 5.2 B ND 2.7 B 2.2 B 1.4 B 8.9 J 2-Jun-09 0.40 10.0 19.1 B 0.48 B ND 6.5 B 8.2 B 4.8 B 3.2 B 0.65 B 83.0 19-Nov-09 0.40 10.0 20.4 7.4 B 12.1 B 15.4 B 6.7 B 11.2 B 5.6 B 5.6 B 3.5 J NC21- = 1,000 pg/L (01/01/10) 15-Jun-10 0.40 10.0 16.9 0.50 J ND 2.3 J 15.0 9.2 J 3.8 J ND ND 29-Nov-10 0.40 10.0 9.6 J 15.3 8.8 J 2.9 J 6.0 J 13.8 1.1 J ND ND 31-May-11 0.40 10.0 6.5 B 11.9 B 47.1 B 12.5 B 12.0 B 10.4 B 9.9 B 4.8 B 13.7 19-Dec-11 10.0 10.0 47.0 ND 13.7 183 24.6 15.6 ND ND ND 30-May-12 10.0 10.0 ND 12.1 ND ND 12.0 ND 13.8 ND ND 3-Dec-12 10.0 10.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 10.0 10.0 17.9 B 12.0 B 14.8 B NS ND ND ND ND 76.3 29-Oct-13 10.0 10.0 12.9 ND ND 118 10.1 ND ND ND ND 6-May-14 EPA 6010 10.0 10.0 ND ND ND 17.5 ND ND ND ND ND 21-Oct-14 EPA 6010 10.0 10.0 ND ND ND 19.7 ND ND ND ND ND 19-May-15 EPA 6010 5.0 10.0 ND ND ND 6.1 J ND 5.7 J ND 5.5 J ND 7-Dec-15 EPA 6010 5.0 10.0 6.5 B ND 8.7 B 5.2 B 16.3 B 11.2 B ND ND 7.2 J 2-May-16 EPA 6010 5.0 10.0 6.0 J ND 7.6 J 10.2 7.1 J 6.5 J ND ND ND 12-Dec-16 EPA 6010 5.0 10.0 9.2 J ND 27.8 26.3 ND ND ND ND ND 26-Jun-17 EPA 6010 5.0 10.0 --- ND 5.9 J ND ND ND ND ND ND 14-Dec-17 EPA 6010 5.0 10.0 --- ND ND 28.8 ND ND ND ND ND 14-May-18 EPA 6010 5.0 10.0 --- 6.2 J ND 5.4 J ND 9.7 J 11.5 ND ND 4-Dec-18 EPA 6010D 5.0 10.0 --- ND 12.7 ND 5.3 J ND ND ND ND 6-May-19 EPA 6010D 5.0 10.0 --- ND 5.9 J ND ND 7.5 J ND 7.6 J ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 15 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Organics Acetone 28-Apr-94 NR 100 200 2000 ND NI NI NI NI NI NA 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 390 600 ND ND ND ND ND ND ND 19-Nov-03 NR 100 4900 180 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 230 ND ND ND ND ND ND ND ND 25-May-05 NR 100 580 ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 450 ND ND ND ND ND ND ND ND 24-May-06 NR 100 1380 D ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 340 ND ND ND ND ND ND ND ND 29-May-07 NR 100 1070 28.0 J ND ND ND ND ND ND ND NC21- = 700 pWL (10/23/07) 28-Nov-07 NR 100 690 D ND ND ND 2.8 B 2.5 B ND 2.7 B 4.3 J 28-May-08 20 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 20.0 100 Dry 34.4 J ND ND ND ND ND ND ND 2-Jun-09 2.2 100 13.3 B 45.7 J ND ND 3.9 B ND ND ND 3.2 J 19-Nov-09 2.2 100 3.1 B ND ND 159 50.0 J 5.4 B ND ND 3.8 J NC21- = 6,000 pg/L (01/01/10) 15-Jun-10 2.2 100 193 101 5.7 B 5.4 B ND ND ND ND 9.8 J 29-Nov-10 2.2 100 123 15.7 B ND ND ND ND ND ND 4.3 J 31-May-11 2.2 100 26.3 B ND ND 10.3 B ND ND ND ND 3.9 J 19-Dec-11 2.2 100 24.4 B ND ND ND ND ND ND ND 6.6 J 30-May-12 2.2 100 283 91.3 J ND ND ND ND ND ND ND 3-Dec-12 10.0 100 43.4 J 46.8 J ND ND ND ND ND ND ND 11-Jun-13 10.0 100 763 1190 J ND NS ND ND ND ND ND 29-Oct-13 50.0 500 611 32.9 J ND ND ND ND ND ND ND 6-May-14 EPA 8260 10.0 100 104 109 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 10.0 100 91.2 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 10.0 100 239 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 10.0 100 118 21.8 J ND ND ND ND ND ND ND 2-May-16 EPA 8260 10.0 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 10.0 100 69.0 J ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 10.0 100 --- ND ND ND 10.6 J 23.6 J 12.5 J 20.7 J 23.0 J 14-Dec-17 EPA 8260 10.0 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 10.0 100 --- 484 ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 10.0 25 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 8.2 25 --- 299 M3 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 16 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Benzene 28-Apr-94 NR 5 ND 15.0 8.7 NI NI NI NI NI NA 3-May-00 NR 5 NA 9.2 10.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 9.4 6.3 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.4 7.4 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 7.3 6.4 ND ND ND ND ND ND 21-May-02 NR 5 NA 9.2 8.4 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 7.6 6.8 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 8.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 8.9 6.4 ND ND ND ND ND ND 5-May-04 NR 5 ND 7.3 6.4 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 8.4 6.4 ND ND ND ND ND ND 25-May-05 NR 5 ND 9.0 6.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 6.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 5.5 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 7.5 ND ND ND ND ND ND ND 29-May-07 NR 1 1.1 8.3 5.5 3.0 ND ND ND ND ND NC2L = 1 pg/L (10/23/07) 28-Nov-07 NR 1 ND 7.0 3.9 ND ND ND ND ND ND 28-May-08 0.3 1.0 Dry 6.4 5.1 2.5 0.78 J ND ND ND ND 5-Nov-08 0.25 1.0 Dry 5.8 4.0 2.3 1.1 ND ND ND ND 2-Jun-09 0.25 1.0 1.2 6.4 6.6 2.1 0.58 J ND ND ND ND 19-Nov-09 0.25 1.0 ND ND ND 0.82 J 6.5 5.9 ND ND ND 15-Jun-10 0.25 1.0 1.1 7.9 5.1 1.9 ND ND ND ND ND 29-Nov-10 0.25 1.0 ND 7.1 4.2 2.2 ND ND ND ND ND 31-May-11 0.25 1.0 0.45 J 7.6 4.6 2.0 0.60 J ND ND ND ND 19-Dec-11 0.25 1.0 0.77 J 7.4 4.9 2.2 0.89 J ND ND ND ND 30-May-12 0.25 1.0 0.5 J 6.6 ND 1.6 ND ND ND ND ND 3-Dec-12 0.25 1.0 0.31 J 6.9 4.5 1.6 ND ND ND ND ND 11-Jun-13 0.25 1.0 1.5 8.9 5.7 INS ND ND ND ND ND 29-Oct-13 0.25 1.0 0.81 J 8.7 4.5 1.4 ND ND ND ND ND 6-May-14 EPA 8260 0.25 1.0 0.37 J 9.5 5.4 1.6 ND ND ND ND ND 21-Oct-14 EPA 8260 0.25 1.0 ND 8.4 3.9 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.25 1.0 ND 7.2 4.1 1.3 ND ND ND ND ND 7-Dec-15 EPA 8260 0.25 1.0 ND 7.7 4.3 1.3 ND ND ND ND ND 2-May-16 EPA 8260 0.25 1.0 0.48 J 9.1 3.9 1.2 ND ND ND ND ND 12-Dec-16 EPA 8260 0.25 1.0 ND 8.0 3.5 1.3 ND ND ND ND ND 26-Jun-17 EPA 8260 0.25 1.0 --- 6.7 3.7 1.3 ND ND ND ND ND 14-Dec-17 EPA 8260 0.25 1.0 --- 6.3 3.9 1.2 ND ND ND ND ND 14-May-18 EPA 8260 0.25 1.0 --- 6.2 3.9 1.1 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.25 1.0 --- 7.5 3.8 1.3 ND ND ND ND ND 6-May-19 EPA8260D 0.20 1.0 --- 10.4 4.6 1.7 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 17 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Carbon disulfide 27-May-98 NR 5 ND ND 8.2 ND ND ND NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND NC2L = 700 Ng/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 1.2 101 Dry ND ND ND ND ND ND ND ND 5-Nov-08 1.2 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 1.2 100 ND ND ND ND ND ND ND ND ND 19-Nov-09 1.2 100 ND ND ND ND ND ND ND ND ND 15-Jun-10 1.2 100 ND ND ND ND ND ND ND ND ND 29-Nov-10 1.2 100 ND ND ND ND ND ND ND ND ND 31-May-11 1.2 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 1.2 100 ND ND ND ND ND ND ND ND ND 30-May-12 1.2 100 ND ND ND ND ND ND ND ND ND 3-Dec-12 1.2 100 ND ND ND ND ND ND ND ND ND 11-Jun-13 1.2 100 ND ND ND INS ND ND ND ND ND 29-Oct-13 1.2 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 1.2 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 1.2 100 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 1.2 2 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.8 10 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 18 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Chlorobenzene 28-Apr-94 NR 5 ND 5.4 12.0 NI NI NI NI NI NA 3-May-00 NR 5 NA 8.8 16.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 8.5 19.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 9.3 18.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND 17.0 ND ND ND ND ND ND 21-May-02 NR 5 NA ND 20.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND 17.0 ND ND ND ND ND ND 14-May-03 NR 5 ND ND 19.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 10.0 21.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 11.0 20.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 12.0 24.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 13.0 24.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 24-May-06 NR 5 ND 11.3 24.3 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 15.0 29.0 ND ND ND ND ND ND 29-May-07 NR 3 0.47 J 16.0 31.0 4.9 0.28 J ND ND ND ND NC21- = 50 pg/L (10/23/07) 28-Nov-07 NR 3 ND 13.0 28.0 4.1 ND ND ND ND ND 28-May-08 0.23 3.0 Dry 13.7 24.3 4.0 0.67 J ND ND ND ND 5-Nov-08 0.23 3.0 Dry 13.5 21.6 4.0 0.89 J ND ND ND ND 2-Jun-09 0.23 3.0 0.30 J 15.0 24.7 3.9 0.49 J ND ND ND ND 19-Nov-09 0.23 3.0 ND ND 1.7 J 0.30 J 14.9 27.0 ND ND ND 15-Jun-10 0.23 3.0 0.31 J 15.5 25.7 4.0 ND ND ND ND ND 29-Nov-10 0.23 3.0 ND 15.4 28.8 5.2 0.76 J ND ND ND ND 31-May-11 0.23 3.0 ND 17.9 26.8 5.7 0.43 J ND ND ND ND 19-Dec-11 0.23 3.0 ND 17.4 28.2 5.7 0.65 J ND ND ND ND 30-May-12 0.23 3.0 0.26 J 17.8 27.6 5.4 ND ND ND ND ND 3-Dec-12 0.23 3.0 ND 18.9 29.0 5.7 ND ND ND ND ND 11-Jun-13 0.23 3.0 0.56 J 18.2 28.4 NS ND ND ND ND ND 29-Oct-13 0.23 3.0 ND 19.0 30.0 5.9 ND ND ND ND ND 6-May-14 EPA 8260 0.23 3.0 ND 19.5 32.1 6.4 ND ND ND ND ND 21-Oct-14 EPA 8260 0.23 3.0 ND 20.5 33.8 6.8 0.32 J ND ND ND ND 19-May-15 EPA 8260 0.23 3.0 ND 21.5 31.5 7.0 ND ND ND ND ND 7-Dec-15 EPA 8260 0.23 3.0 ND 20.6 33.2 7.0 ND ND ND ND ND 2-May-16 EPA 8260 0.23 3.0 0.31 J 24.2 31.1 6.6 ND ND ND ND ND 12-Dec-16 EPA 8260 0.23 3.0 ND 19.9 32.3 7.0 0.27 J ND ND ND ND 26-Jun-17 EPA 8260 0.23 3.0 --- 21.4 29.0 7.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.23 3.0 --- 22.2 30.5 6.9 ND ND ND ND ND 14-May-18 EPA 8260 0.23 3.0 --- 20.4 29.3 6.7 ND ND ND ND ND 4-Dec-18 EPA 8260E 0.23 1.0 --- 23.7 34.4 7.1 ND ND ND ND ND 6-May-19 EPA 8260D 0.53 1.0 --- 26.6 36.4 8.7 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 19 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Chloroethane 12-May-99 NR 10 ND ND ND ND ND ND NI NI ND 19-Oct-99 NR 10 ND ND ND ND ND ND NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND NA ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND NA ND NA 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 10 ND ND ND ND ND ND ND ND ND NC21- = 2,800 Ng/L (10/23/07) 28-Nov-07 NR 10 ND ND 3.4 J ND ND ND ND ND ND 28-May-08 0.54 10.0 Dry ND 2.5 J ND ND ND ND ND ND 5-Nov-08 0.54 10.0 Dry ND 2.3 J ND ND ND ND ND ND 2-Jun-09 0.54 10.0 ND ND 2.7 J ND ND ND ND ND ND 19-Nov-09 0.54 10.0 ND ND ND ND 0.81 J ND ND ND ND NC2L = 3,000 Ng/L (01/01/10) 15-Jun-10 0.54 10.0 ND 0.86 J 2.1 J ND ND ND ND ND ND 29-Nov-10 0.54 10.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.54 10.0 ND ND 4.1 J ND ND ND ND ND ND 19-Dec-11 0.54 10.0 ND 0.58 J ND 0.56 J ND ND ND ND ND 30-May-12 0.54 10.0 ND ND 1.9 J ND ND ND ND ND ND 3-Dec-12 0.54 10.0 ND 0.60 J 2.8 J ND ND ND ND ND ND 11-Jun-13 0.54 10.0 ND ND 1.2 J INS ND ND ND ND ND 29-Oct-13 0.54 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.54 10.0 ND ND 1.7 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.54 10.0 ND ND 2.5 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.54 10.0 ND ND 2.1 J ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.54 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.54 10.0 ND ND 2.6 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.54 10.0 --- ND 2.0 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.54 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.54 10.0 --- ND 1.2 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.54 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.52 1.0 --- ND 1.8 0.56 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 20 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks Chloroform 19-Nov-09 0.14 5.0 ND ND 0.21 J ND ND ND ND ND ND NC21- = 70 ug/L (10/23/07) 15-Jun-10 0.14 5.0 ND ND ND ND ND ND 0.33 B ND 0.28 J 29-Nov-10 0.14 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.14 5.0 ND ND ND ND ND ND 0.35 B ND 0.63 J 19-Dec-11 0.14 5.0 ND ND ND ND ND ND 0.44 J ND ND 30-May-12 0.14 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.14 5.0 ND ND ND ND ND ND 0.37 J ND ND 11-Jun-13 0.14 5.0 ND ND ND NS ND ND ND ND 42.4 29-Oct-13 0.14 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.18 J ND ND 21-Oct-14 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.20 J ND NA 7-Dec-15 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.14 5.0 ND ND ND ND ND ND 0.56 J ND ND 26-Jun-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.56 J ND ND 14-Dec-17 EPA 8260 0.14 5.0 --- ND ND ND ND ND 0.31 J ND ND 14-May-18 EPA 8260 0.14 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.14 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 --- ND ND ND ND ND 0.67 J ND ND Chloromethane 2-Jun-09 0.11 1.0 ND ND 0.28 J ND ND ND ND 0.17 J ND NC21- = 2.6 pg/L (10/23/07) 19-Nov-09 0.11 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 ug/L (01/01/10) 15-Jun-10 0.11 1.0 ND ND ND ND ND ND ND 0.14 B 0.15 J 29-Nov-10 0.11 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.11 1.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.11 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.11 1.0 0.33 J ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.11 1.0 ND ND ND ND ND ND ND ND 0.36 J 26-Jun-17 EPA 8260 0.11 1.0 --- 0.26 J 0.16 J ND 0.30 J 1 J 0.33 J 0.45 J ND 14-Dec-17 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.11 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.11 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.38 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 21 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichlorobenzene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND 1.1 J ND ND ND ND ND ND ND NC2L = 24 pg/L (10/23/07) 28-Nov-07 NR 5 ND 2.8 J 0.63 J ND 0.74 J ND ND ND ND 28-May-08 0.3 5.0 Dry 2.6 J 0.66 J ND 0.49 J ND ND ND ND 5-Nov-08 0.30 5.0 Dry 2.2 J 0.51 J ND 0.61 J ND ND ND ND 2-Jun-09 0.30 5.0 ND 2.5 J 0.79 J ND 0.34 J ND ND ND ND 19-Nov-09 0.30 5.0 ND ND ND ND 2.7 J 1.2 J ND ND ND NC21- = 20 pg/L (01/01/10) 15-Jun-10 0.30 5.0 ND 2.3 J 1.1 J 0.33 J ND ND ND ND ND 29-Nov-10 0.30 5.0 ND 2.3 J 0.63 J ND ND ND ND ND ND 31-May-11 0.30 5.0 ND 2.2 J 0.51 J ND ND ND ND ND ND 19-Dec-11 0.30 5.0 ND 2.4 J 0.67 J ND ND ND ND ND ND 30-May-12 0.30 5.0 ND 2.3 J 0.72 J ND ND ND ND ND ND 3-Dec-12 0.30 5.0 ND 2.2 J 0.85 J 0.32 J ND ND ND ND ND 11-Jun-13 0.30 5.0 ND 2.2 J 0.91 J INS ND ND ND ND ND 29-Oct-13 0.30 5.0 ND 2.4 J 1.1 J ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 5.0 ND 2.3 J 0.77 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 5.0 ND 2.5 J 0.64 J ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 5.0 ND ND 0.6 J 0.3 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 5.0 ND 2.5 J 0.57 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 5.0 ND 2.7 J 0.7 J ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 5.0 ND 2.3 J 0.58 J ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 5.0 --- 2.4 J 0.45 J 0.33 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 5.0 --- 2.2 J 0.66 J 0.31 J ND ND ND ND ND 14-May-18 EPA 8260 0.30 5.0 --- 1.7 J 0.79 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 2.2 0.91 J ND ND ND ND ND ND 6-May-19 EPA 8260D 0.49 1.0 --- 2.4 0.88 J ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 22 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dichlorobenzene 28-Apr-94 NR 5 ND 34.0 22.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 50.0 12.0 ND ND ND ND ND ND 8-Nov-00 NR 5 NA 54.0 13.0 ND ND ND ND ND ND 29-May-01 NR 5 NA 58.0 12.0 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 57.0 15.0 ND ND ND ND ND ND 21-May-02 NR 5 NA 59.0 14.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 52.0 13.0 ND ND ND ND ND ND 14-May-03 NR 5 ND 50.0 15.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 50.0 19.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 48.0 18.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 53.0 14.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 59.0 13.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 57.0 14.0 5.0 ND ND ND ND ND 24-May-06 NR 5 ND 42.9 11.2 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 57.0 10.0 ND ND ND ND ND ND 29-May-07 NR 1 2.3 60.0 16.0 4.7 1.1 ND ND ND ND NC2L = 1.4 pg/L (10/23/07) 28-Nov-07 NR 1 ND 48.0 10.0 ND 3.3 ND ND ND ND 28-May-08 0.33 1.0 Dry 52.9 9.5 3.8 2.5 ND ND ND ND 5-Nov-08 0.33 1.0 Dry 48.6 8.1 3.7 3.2 ND ND ND ND 2-Jun-09 0.33 1.0 1.9 58.2 12.0 4.2 2.1 ND ND ND ND 19-Nov-09 0.33 1.0 ND ND ND 2.4 49.2 18.5 ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.33 1.0 2.1 46.2 16.4 4.2 0.93 J ND ND ND ND 29-Nov-10 0.33 1.0 1.2 45.8 12.0 4.4 1.8 ND ND ND ND 31-May-11 0.33 1.0 1.2 47.6 8.3 4.2 1.3 ND ND ND ND 19-Dec-11 0.33 1.0 2.1 44.8 10.8 4.3 1.3 ND ND ND ND 30-May-12 0.33 1.0 1.4 47.1 12.0 4.4 0.71 J ND ND ND ND 3-Dec-12 0.33 1.0 0.99 J 47.9 13.1 4.6 0.52 J ND ND ND ND 11-Jun-13 0.33 1.0 1.6 50.0 15.3 INS 0.46 J ND ND ND ND 29-Oct-13 0.33 1.0 1.4 48.3 19.2 5.0 0.48 J ND ND ND ND 6-May-14 EPA 8260 0.33 1.0 0.95 J 47.6 14.2 5.0 0.37 J ND ND ND ND 21-Oct-14 EPA 8260 0.33 1.0 1.2 45.2 12.3 5.0 0.99 J ND ND ND ND 19-May-15 EPA 8260 0.33 1.0 0.56 J 47.5 11.2 4.9 0.54 J ND ND ND ND 7-Dec-15 EPA 8260 0.33 1.0 0.81 J 47.1 11.2 4.3 ND ND ND ND ND 2-May-16 EPA 8260 0.33 1.0 0.97 J 50.5 14.7 4.4 ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 1.0 0.47 J 39.7 10.1 4.9 0.69 J ND ND ND ND 26-Jun-17 EPA 8260 0.33 1.0 --- 42.6 10.5 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 1.0 --- 41.6 11.5 4.5 0.69 J ND ND ND ND 14-May-18 EPA 8260 0.33 1.0 --- 35.9 13.7 4.4 0.41 J ND ND ND ND 4-Dec-18 EPA 8260B 0.33 1.0 --- 39.9 14.8 ND ND ND ND ND ND 6-May-19 EPA8260D 0.58 1.0 --- 47.3 14.6 4.8 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 23 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethane 28-Apr-94 NR 5 14.0 ND 8.4 NI NI NI NI NI ND 3-May-00 NR 5 NA ND 8.4 J 7.6 J 6.1 J ND ND ND ND 8-Nov-00 NR 5 NA ND 7.0 10.0 8.1 ND ND ND ND 29-May-01 NR 5 NA ND 8.7 11.0 9.9 ND ND ND ND 6-Nov-01 NR 5 NA ND 7.3 12.0 7.0 ND ND ND ND 21-May-02 NR 5 NA ND 7.4 12.0 8.9 ND ND ND ND 13-Nov-02 NR 5 NA ND 5.4 11.0 9.0 ND ND ND ND 14-May-03 NR 5 ND ND ND 8.1 5.4 ND ND ND ND 19-Nov-03 NR 5 ND ND ND 7.9 5.3 ND ND ND ND 5-May-04 NR 5 ND ND ND 7.8 7.1 ND ND ND ND 9-Nov-04 NR 5 ND ND ND 7.5 7.0 ND ND ND ND 25-May-05 NR 5 ND ND ND 8.0 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 7.0 5.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 2.8 J 2.6 J 2.7 J 8.8 11.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND 0.76 J 1.2 J 5.7 11.0 ND ND ND ND 28-May-08 0.32 5.0 Dry 0.87 J 2.0 J 6.6 10.6 ND ND ND ND 5-Nov-08 0.32 5.0 Dry 0.85 J 1.9 J 6.3 11.3 ND ND ND ND 2-Jun-09 0.32 5.0 1.3 J 0.98 J 2.3 J 6.5 8.6 ND ND ND ND 19-Nov-09 0.32 5.0 ND ND ND 0.51 J 1.0 J 1.5 J ND ND ND NC21- = 6 pg/L (01/01/10) 15-Jun-10 0.32 5.0 1.3 J 1.2 J 0.93 J 5.6 3.7 J ND ND ND ND 29-Nov-10 0.32 5.0 ND ND 1.4 J 6.2 8.0 ND ND ND ND 31-May-11 0.32 5.0 0.42 J 1.3 J 2.1 J 6.3 7.8 ND ND ND ND 19-Dec-11 0.32 5.0 0.58 J 1.2 J 1.8 J 5.9 6.7 ND ND ND ND 30-May-12 0.32 5.0 ND 1.0 J 1.2 J 5.4 4.1 J ND ND ND ND 3-Dec-12 0.32 5.0 ND 1.1 J 1.4 J 4.7 J 2.1 J ND ND ND ND 11-Jun-13 0.32 5.0 0.37 J 1.1 J 1.1 J INS 2.2 J ND ND ND ND 29-Oct-13 0.32 5.0 ND 1.1 J 0.67 J 5.1 3 J ND ND ND ND 6-May-14 EPA 8260 0.32 5.0 0.34 J 0.98 J 0.81 J 5.2 2.4 J ND ND ND ND 21-Oct-14 EPA 8260 0.32 5.0 ND 0.90 J 0.83 J 4.2 J 4.6 J ND ND ND ND 19-May-15 EPA 8260 0.32 5.0 ND 0.79 J 0.64 J 4.4 J 2.5 J ND ND ND ND 7-Dec-15 EPA 8260 0.32 5.0 ND 0.59 J 0.75 J 4.9 J 1.9 J ND ND ND ND 2-May-16 EPA 8260 0.32 5.0 ND 0.43 J 0.65 J 4.3 J 0.72 J ND ND ND ND 12-Dec-16 EPA 8260 0.32 5.0 ND 0.71 J 0.87 J 4.9 J 3.1 J ND ND ND ND 26-Jun-17 EPA 8260 0.32 5.0 --- 0.71 J 0.83 J 4.5 J 2.1 J ND ND ND ND 14-Dec-17 EPA 8260 0.32 5.0 --- 0.59 J 0.68 J 4.6 J 2.2 J ND ND ND ND 14-May-18 EPA 8260 0.32 5.0 --- ND 0.5 J 4.3 J 1.3 J ND ND ND ND 4-Dec-18 EPA 8260B 0.32 1.0 --- 0.37 J 0.46 J 4.0 1.1 ND ND ND ND 6-May-19 EPA8260D 0.41 1.0 --- 0.68 J ND 6.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 24 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-61) Blanks 1,2-Dichloroethane 19-Nov-09 0.12 1.0 ND ND ND ND 0.15 J ND ND ND ND NC21- = 0.4 Ng/L (01/01/10) 15-Jun-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.12 1.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.12 1.0 ND 0.14 J ND ND ND ND ND ND ND 19-Dec-11 0.12 1.0 ND 0.13 J ND ND ND ND ND ND ND 30-May-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.12 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.12 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.12 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.12 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.24 1.0 ND 0.25 J ND ND ND ND ND ND ND 2-May-16 EPA8260 0.24 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.24 1.0 ND 0.27 J ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.24 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.24 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.67 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 25 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1-Dichloroethene 28-Apr-94 NR 5 ND ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND ND ND ND ND ND NC2L = 7 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND ND ND ND ND ND 28-May-08 0.56 1.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.56 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.56 5.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.56 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.56 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.56 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.56 5.0 ND ND ND ND ND ND ND ND ND NC 21 350 pg/L (04/01/2013) 11-Jun-13 0.56 5.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.56 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.56 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.56 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.56 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.72 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 26 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,4-Dioxane (p-Dioxane) 4-Dec-18 PA 8260B Moc 9.5 10 ND 219 56.3 127 ND ND ND 4.0 ND 6-May-19 PA 8260D Moc 5.8 10 --- 218 57.0 128 2 ND ND ND ND NC 21 = 3 pg/L cis-1,2-Dichloroethene 28-Apr-94 NR 5 40 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND 23.0 61.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND 31.0 69.0 ND ND ND ND 29-May-01 NR 5 NA ND ND 34.0 61.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND 34.0 56.0 ND ND ND ND 21-May-02 NR 5 NA ND ND 29.0 69.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND 25.0 75.0 ND ND ND ND 14-May-03 NR 5 46.0 ND ND 14.0 36.0 ND ND ND ND 19-Nov-03 NR 5 26.0 ND ND 13.0 38.0 ND ND ND ND 5-May-04 NR 5 10.0 ND ND 10.0 46.0 ND ND ND ND 9-Nov-04 NR 5 6.0 ND ND 9.1 47.0 ND ND ND ND 25-May-05 NR 5 6.0 ND ND 7.0 29.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 11.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 9.3 ND ND ND ND 1-Nov-06 NR 5 ND ND ND 6.8 2.1 ND ND ND ND 29-May-07 NR 5 8.3 ND ND 7.5 36.0 ND ND ND ND NC2L = 70 pg/L (10/23/07) 28-Nov-07 NR 5 ND ND ND 4.5 J 58.0 ND ND ND ND 28-May-08 0.19 5.0 Dry 0.31 J 0.29 J 5.1 56.3 ND ND ND ND 5-Nov-08 0.19 5.0 Dry ND 0.22 J 4.9 J 65.7 ND ND ND ND 2-Jun-09 0.19 5.0 17.3 0.33 J 0.44 J 5.3 47.6 ND ND ND ND 19-Nov-09 0.19 5.0 ND ND ND 9.1 0.31 B ND ND ND 0.26 J 15-Jun-10 0.19 5.0 9.9 0.45 J ND 6.2 20.9 ND ND ND ND 29-Nov-10 0.19 5.0 4.8 J 0.31 J ND 6.4 37.1 0.46 J ND ND ND 31-May-11 0.19 5.0 3.0 J 0.33 J ND 7.3 38.6 ND ND ND ND 19-Dec-11 0.19 5.0 3.1 J 0.41 J 0.25 J 6.8 30.3 ND ND ND ND 30-May-12 0.19 5.0 4 J ND ND 7.4 17.1 ND ND ND ND 3-Dec-12 0.19 5.0 0.96 J ND ND 7.0 9.2 ND ND ND ND 11-Jun-13 0.19 5.0 9.4 0.69 J 0.20 J INS 8.8 ND ND ND ND 29-Oct-13 0.19 5.0 4.0 J 0.32 J ND 8.1 12.2 ND ND ND ND 6-May-14 EPA 8260 0.19 5.0 2.2 J 0.40 J ND 7.9 9.3 ND ND ND ND 21-Oct-14 EPA 8260 0.19 5.0 1.1 J 0.30 J ND 7.3 21.4 ND ND ND ND 19-May-15 EPA 8260 0.19 5.0 1.1 J 0.34 J ND 7.7 11.3 ND ND ND ND 7-Dec-15 EPA 8260 0.19 5.0 2.1 J ND ND 8.9 8.9 ND ND ND ND 2-May-16 EPA 8260 0.19 5.0 1.7 J 0.38 J ND 7.8 3.6 J ND ND ND ND 12-Dec-16 EPA 8260 0.19 5.0 0.8 J 0.36 J ND 10.4 17.2 ND ND ND ND 26-Jun-17 EPA 8260 0.19 5.0 --- 0.31 J ND 10.0 10.7 ND ND ND ND 14-Dec-17 EPA 8260 0.19 5.0 --- 0.38 J 0.22 J 10.8 11.1 ND ND ND ND 14-May-18 EPA 8260 0.19 5.0 --- ND 0.22 J 10.7 6.9 ND ND ND ND 4-Dec-18 EPA 8260B 0.19 1.0 --- 0.30 J ND 10.8 5.8 ND ND ND ND 6-May-19 EPA8260D 0.66 1.0 --- ND ND 18.7 1.2 ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 27 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trans-1,2-Dichloroethene 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 5 ND ND ND ND 0.2 J ND ND ND ND NC2L = 100 Ng/L (10/23/07) 28-Nov-07 NR 5 ND ND ND ND 0.43 J ND ND ND ND 28-May-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.49 5.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.49 5.0 ND ND 0.55 J ND ND ND ND ND ND 19-Nov-09 0.49 5.0 ND ND ND ND ND 0.54 J ND ND ND 15-Jun-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.49 5.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.49 5.0 ND ND ND ND ND ND ND ND ND 30-May-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.49 5.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.49 5.0 ND ND 0.57 J INS ND ND ND ND ND 29-Oct-13 0.49 5.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.49 5.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.49 5.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.49 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.46 1.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 28 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,2-Dichloropropane 19-Oct-99 NR 5 ND ND ND ND ND ND NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND NA 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND 5.3 ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND 6.0 ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND 4.3 ND ND ND ND ND NC2L = 0.51 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 1.4 ND ND ND ND 28-May-08 0.27 1.0 Dry ND ND 2.5 1.2 ND ND ND ND 5-Nov-08 0.27 1.0 Dry ND ND 2.3 1.3 ND ND ND ND 2-Jun-09 0.27 1.0 ND ND ND 2.4 0.84 J ND ND ND ND 19-Nov-09 0.27 1.0 ND ND ND ND ND ND ND ND ND NC21- = 0.6 pg/L (01/01/10) 15-Jun-10 0.27 1.0 ND ND ND 2.3 0.30 J ND ND ND ND 29-Nov-10 0.27 1.0 ND ND ND 2.5 ND ND ND ND ND 31-May-11 0.27 1.0 ND ND ND 2.3 0.61 J ND ND ND ND 19-Dec-11 0.27 1.0 ND ND ND 2.1 0.66 J ND ND ND ND 30-May-12 0.27 1.0 ND ND ND 1.9 ND ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND 1.6 ND ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 6-May-14 EPA 8260 0.27 1.0 ND ND ND 1.5 ND ND ND ND ND 21-Oct-14 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 19-May-15 EPA 8260 0.27 1.0 ND ND ND 1.2 ND ND ND ND ND 7-Dec-15 EPA 8260 0.27 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.27 1.0 ND ND ND 1.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.27 1.0 ND ND ND 1.1 0.37 J ND ND ND ND 26-Jun-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-Dec-17 EPA 8260 0.27 1.0 --- ND ND 0.92 J ND ND ND ND ND 14-May-18 EPA 8260 0.27 1.0 --- ND ND 0.87 J ND ND ND ND ND 4-Dec-18 EPA 8260B 0.27 1.0 --- ND ND 0.94 J ND ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 --- ND ND 1.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 29 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Ethylbenzene 28-Apr-94 NR 50 ND 310 29.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 130 ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA 110 ND ND ND ND ND ND ND 29-May-01 NR 5 NA 120 ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA 89.0 ND ND ND ND ND ND ND 21-May-02 NR 5 NA 100 ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA 86.0 ND ND ND ND ND ND ND 14-May-03 NR 5 ND 160 11.0 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 66.0 ND ND ND ND ND ND ND 5-May-04 NR 5 ND 58.0 ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND 65.0 ND ND ND ND ND ND ND 25-May-05 NR 5 ND 80.0 ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND 75.0 ND ND ND ND ND ND ND 24-May-06 NR 5 ND 45.8 ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND 64.0 ND ND ND ND ND ND ND 29-May-07 NR 1 ND 59.1 ND ND ND ND ND ND ND NC2L = 550 Ng/L (10/23/07) 28-Nov-07 NR 1 ND 39.0 ND ND 0.50 J ND ND ND ND 28-May-08 0.3 1.0 Dry 39.3 ND ND ND ND ND ND ND 5-Nov-08 0.30 1.0 Dry 30.8 ND ND ND ND ND ND ND 2-Jun-09 0.30 1.0 ND 28.7 1.2 ND ND ND ND ND ND 19-Nov-09 0.30 1.0 ND ND ND ND 27.2 0.42 J ND ND ND NC21- = 600 Ng/L (01/01/10) 15-Jun-10 0.30 1.0 ND 39.0 0.32 J ND ND ND ND ND ND 29-Nov-10 0.30 1.0 ND 27.3 ND ND ND ND ND ND ND 31-May-11 0.30 1.0 ND 23.8 ND ND ND ND ND ND ND 19-Dec-11 0.30 1.0 ND 18.1 ND ND ND ND ND ND ND 30-May-12 0.30 1.0 ND 16.8 ND ND ND ND ND ND ND 3-Dec-12 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 11-Jun-13 0.30 1.0 ND 27.7 6.5 INS ND ND ND ND ND 29-Oct-13 0.30 1.0 ND 21.5 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.30 1.0 ND 18.9 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.30 1.0 ND 16.5 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.30 1.0 ND 14.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.30 1.0 ND 16.2 0.41 J ND ND ND ND ND ND 2-May-16 EPA 8260 0.30 1.0 ND 22.2 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.30 1.0 ND 13.9 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.30 1.0 --- 12.7 ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.30 1.0 --- 10.5 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.30 1.0 --- 10.5 3.9 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.30 1.0 --- 10.7 ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.45 1.0 --- 24.1 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 30 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Hexanone 19-Oct-99 NR 50 ND 80.0 ND ND ND ND NI NI ND 3-May-00 NR 50 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 50 NA ND ND ND ND ND ND ND ND 29-May-01 NR 50 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 50 NA ND ND ND ND ND ND ND ND 21-May-02 NR 50 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 50 NA ND ND ND ND ND ND ND ND 14-May-03 NR 50 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND ND ND ND ND ND 5-May-04 NR 50 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND ND ND ND ND ND 25-May-05 NR 50 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 50 ND ND ND ND ND ND ND ND ND 24-May-06 NR 50 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 50 ND ND ND ND ND ND ND ND ND 29-May-07 NR 50 ND ND ND ND ND ND ND ND ND GWPS = 280 Ng/L (10/23/07) 28-Nov-07 NR 50 ND ND ND ND ND ND ND ND ND 28-May-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.46 50.0 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-Nov-09 0.46 50.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.46 50.0 ND ND ND ND ND ND ND ND ND 31-May-11 0.46 50.0 ND 1.4 J ND ND ND ND ND ND ND 19-Dec-11 0.46 50.0 0.48 J ND ND ND ND 0.81 J ND ND ND 30-May-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.46 50.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.46 50.0 ND ND ND INS ND ND ND ND ND 29-Oct-13 0.46 50.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.46 50.0 ND 1.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.46 50.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.46 50.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.46 50.0 --- 2.8 J ND ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.46 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.89 5.0 --- 8 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 31 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Fr— Analyte Collection Date Method D RL MW-1 MW-2 MW-3S MW-31D MW-4 MW-5 MW-6S MW-61) Blanks lodomethane 11-Jun-13 0.32 10.0 ND ND ND INS ND 7.4 J ND ND ND NULL = NE Ng/L (01/01/10) 29-Oct-13 0.32 10.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.32 10.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.32 10.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.32 5.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 3.10 10.0 --- ND ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 32 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Methylene chloride 12-May-99 NR 5 ND ND ND ND 5.5 NI NI NI NA 19-Oct-99 NR 10 ND ND ND ND 12.0 B ND NI NI 21.0 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND 10.0 ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND ND ND ND ND ND ND ND ND NC21- = 4.6 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 2.7 ND ND ND ND 28-May-08 0.97 2.0 Dry ND ND ND ND ND ND ND 1.5 J 5-Nov-08 0.97 2.0 Dry ND ND ND 6.1 B ND ND ND 2.8 2-Jun-09 0.97 2.0 ND ND ND ND 18.8 ND ND ND ND 19-Nov-09 0.97 2.0 ND ND ND ND ND ND ND ND ND NC21- = 5 ug/L (01/01/10) 15-Jun-10 0.97 2.0 ND ND ND ND ND ND ND ND ND 29-Nov-10 0.97 1.0 ND ND ND ND 2.9 B ND ND ND 1.2 31-May-11 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.97 1.0 ND ND ND ND 1.4 B ND ND ND 3.3 30-May-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 3-Dec-12 0.97 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.97 1.0 ND ND ND NS ND ND ND ND ND 29-Oct-13 0.97 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 2.6 21-Oct-14 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND 4.8 2-May-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.97 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND 1.3 J 14-Dec-17 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.97 1.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.97 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA 8260D 0.50 1.0 --- ND ND 0.63 J ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 33 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 2-Butanone (MEK) 28-Apr-94 NR 2000 ND 2500 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND 490 ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 250 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 26.0 J 81.0 J ND ND ND ND ND ND ND NC21- = 4,200 pg/L (10/23/07) 28-Nov-07 NR 100 18.0 JD ND ND ND ND ND ND ND ND 28-May-08 0.96 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.96 100 Dry 17.5 J ND ND ND ND ND ND ND 2-Jun-09 0.96 100 ND 56.1 J ND ND ND ND ND ND ND 19-Nov-09 0.96 100 ND ND ND 24.2 J 17.8 J ND 1.5 J ND ND NC21- = 4,000 ug/L (01/01/10) 15-Jun-10 0.96 100 42.3 J 202 ND ND ND ND ND ND 1.4 J 29-Nov-10 0.96 100 60.6 J 1.9 J ND ND ND ND ND ND ND 31-May-11 0.96 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.96 100 1.9 J ND ND ND ND ND ND ND ND 30-May-12 0.96 100 8.1 J ND ND ND ND ND ND ND ND 3-Dec-12 0.96 100 2.2 J 29.5 J ND ND ND ND ND ND ND 11-Jun-13 0.96 100 14.0 J 1650 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.96 100 158 ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.96 100 13.3 J 128 ND ND ND ND ND ND ND 21-Oct-14 EPA826O 0.96 100 9.1 J ND ND ND ND ND ND ND ND 19-May-15 EPA826O 0.96 100 6.4 J ND ND ND ND ND ND ND ND 7-Dec-15 EPA826O 0.96 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA826O 0.96 100 ND 60.7 J ND ND ND ND ND ND ND 12-Dec-16 EPA826O 0.96 100 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA826O 0.96 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA826O 0.96 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA826O 0.96 100 --- 268 ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.96 5 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 3.20 5 --- 448 M3' ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 34 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MM MW-4 MW-5 MW-6S MW-6D Blanks 4-Methyl-2-pentanone (MIBK) 28-Apr-94 NR 500 ND 910 ND NI NI NI NI NI ND 3-May-00 NR 100 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 100 NA ND ND ND ND ND ND ND ND 29-May-01 NR 100 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 100 NA ND ND ND ND ND ND ND ND 21-May-02 NR 100 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 100 NA ND ND ND ND ND ND ND ND 14-May-03 NR 100 ND 1200 ND ND ND ND ND ND ND 19-Nov-03 NR 100 ND ND ND ND ND ND ND ND ND 5-May-04 NR 100 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 100 ND ND ND ND ND ND ND ND ND 25-May-05 NR 100 ND 160 ND ND ND ND ND ND ND 2-Nov-05 NR 100 ND ND ND ND ND ND ND ND ND 24-May-06 NR 100 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 100 ND ND ND ND ND ND ND ND ND 29-May-07 NR 100 ND ND ND ND ND ND ND ND ND GWPS = 560 pg/L (10/23/07) 28-Nov-07 NR 100 ND ND ND ND ND ND ND ND ND 28-May-08 0.33 100 Dry ND ND ND ND ND ND ND ND 5-Nov-08 0.33 100 Dry ND ND ND ND ND ND ND ND 2-Jun-09 0.33 100 ND 113 ND ND ND ND ND ND ND 19-Nov-09 0.33 100 ND ND ND ND 2.3 J ND ND ND ND 15-Jun-10 0.33 100 ND 56.0 J 0.88 J ND ND ND ND ND ND 29-Nov-10 0.33 100 ND ND ND ND ND ND ND ND ND 31-May-11 0.33 100 ND ND ND ND ND ND ND ND ND 19-Dec-11 0.33 100 ND ND ND ND ND ND ND ND ND 30-May-12 0.33 100 ND 13.9 J ND ND ND ND ND ND ND 3-Dec-12 0.33 100 ND 1.9 J ND ND ND ND ND ND ND 11-Jun-13 0.33 100 ND 760 J 4.0 J NS ND ND ND ND ND 29-Oct-13 0.33 100 ND ND ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.33 100 ND 41.4 J 0.44 J ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.33 100 ND 3.3 J ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.33 100 ND ND ND ND ND ND ND ND ND 2-May-16 EPA 8260 0.33 100 ND 61.6 J ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.33 100 ND 3.2 J ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.33 100 --- ND ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.33 100 --- 169 J ND ND ND ND ND ND ND 4-Dec-18 EPA826OB 0.33 5 --- 2.7 J ND ND ND ND ND ND ND 6-May-19 EPA826OD 0.86 5 --- 311 E3, ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 35 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Tetrachloroethene 28-Apr-94 NR 5 20.0 ND ND NI NI NI NI NI ND (PCE) 6-Oct-94 NR 5 16.0 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 24.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 21.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 15.0 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND 13.0 ND ND ND ND 21-May-02 NR 5 NA ND ND ND 17.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 12.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 10.0 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 12.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 14.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 12.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND 5.0 28.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND 10.2 ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND 7.0 ND ND ND ND 29-May-07 NR 1 ND ND ND 1.9 11.0 ND ND ND ND NC2L = 0.7 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.2 13.0 ND ND ND ND 28-May-08 0.46 1.0 Dry ND ND 1.6 10.3 ND ND ND ND 5-Nov-08 0.46 1.0 Dry ND ND 1.6 13.1 ND ND ND ND 2-Jun-09 0.46 1.0 1.7 ND ND 1.2 9.1 ND ND ND ND 19-Nov-09 0.46 1.0 ND ND ND ND ND ND ND ND ND 15-Jun-10 0.46 1.0 ND ND ND 0.79 J 4.8 ND ND ND ND 29-Nov-10 0.46 1.0 ND ND ND ND 11.0 ND ND ND ND 31-May-11 0.46 1.0 ND ND ND 0.75 J 6.2 ND ND ND ND 19-Dec-11 0.46 1.0 ND ND ND 0.95 J 8.4 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND 1.3 4.7 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND 1.8 3.2 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND INS 2.6 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND ND 3.5 3.3 ND ND ND ND 6-May-14 EPA 8260 0.46 1.0 ND ND ND 3.8 3.0 ND ND ND ND 21-Oct-14 EPA 8260 0.46 1.0 ND ND ND 3.9 5.9 ND ND ND ND 19-May-15 EPA 8260 0.46 1.0 ND ND ND 4.6 3.7 ND ND ND ND 7-Dec-15 EPA 8260 0.46 1.0 ND ND ND 3.5 1.9 ND ND ND ND 2-May-16 EPA 8260 0.46 1.0 ND ND ND 4.5 1.0 ND ND ND ND 12-Dec-16 EPA 8260 0.46 1.0 ND ND ND 4.7 2.1 ND ND ND ND 26-Jun-17 EPA 8260 0.46 1.0 --- ND ND 5.7 1.7 ND ND ND ND 14-Dec-17 EPA 8260 0.46 1.0 --- ND ND 5.0 2.0 ND ND ND ND 14-May-18 EPA 8260 0.46 1.0 --- ND ND 5.6 1.3 ND ND ND ND 4-Dec-18 EPA 8260B 0.46 1.0 --- ND ND 6.6 1.2 ND ND ND ND 6-May-19 EPA8260D 0.78 1.0 --- ND ND 11.1 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 36 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Toluene 28-Apr-94 NR 5 ND 55.0 10.0 NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND ND ND ND ND ND 29-May-01 NR 5 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND ND ND ND ND ND 14-May-03 NR 5 ND ND 5.6 ND ND ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND ND ND ND ND ND 5-May-04 NR 5 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND ND ND ND ND ND 25-May-05 NR 5 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND ND ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 ND 2.8 0.39 B 0.26 B ND ND ND ND 0.52 J NC2L = 1,000 pg/L (10/23/07) 28-Nov-07 NR 1 ND 1.7 ND ND ND ND ND ND ND 28-May-08 0.26 1.0 Dry 2.0 0.35 J ND ND ND ND ND ND 5-Nov-08 0.26 1.0 Dry 1.5 0.44 J ND ND ND ND ND ND 2-Jun-09 0.26 1.0 ND 2.3 0.51 J ND ND ND ND ND ND 19-Nov-09 0.26 1.0 ND ND ND ND 1.6 0.26 J ND ND ND NC21- = 600 pg/L (01/01/10) 15-Jun-10 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 29-Nov-10 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 31-May-11 0.26 1.0 ND 1.5 ND ND ND ND ND ND ND 19-Dec-11 0.26 1.0 ND 1.9 ND ND ND ND ND ND ND 30-May-12 0.26 1.0 ND 1.4 0.38 J ND ND ND ND ND ND 3-Dec-12 0.26 1.0 ND 1.0 J 0.27 J ND ND ND ND ND ND 11-Jun-13 0.26 1.0 ND 4.1 2.7 INS ND ND ND ND ND 29-Oct-13 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 6-May-14 EPA 8260 0.26 1.0 ND 1.6 ND ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.26 1.0 ND 1.3 ND ND ND ND ND ND ND 19-May-15 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.26 1.0 ND 1.6 0.52 J ND ND ND ND ND --- 2-May-16 EPA 8260 0.26 1.0 ND 2.4 ND ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.26 1.0 ND 1.2 ND ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.26 1.0 --- 1.2 0.27 J ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.26 1.0 --- 1.1 ND ND ND ND ND ND ND 14-May-18 EPA 8260 0.26 1.0 --- 1.7 J 0.48 J ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.26 1.0 --- 0.9 J ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.31 1.0 --- 4.8 ND ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 37 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Trichloroethene 28-Apr-94 NR 5 11.0 ND ND NI NI NI NI NI ND (TCE) 6-Oct-94 NR 5 9.3 ND ND NI NI NI NI NI ND 3-May-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 8-Nov-00 NR 5 NA ND ND ND 12.0 ND ND ND ND 29-May-01 NR 5 NA ND ND ND 8.6 ND ND ND ND 6-Nov-01 NR 5 NA ND ND ND ND ND ND ND ND 21-May-02 NR 5 NA ND ND ND 11.0 ND ND ND ND 13-Nov-02 NR 5 NA ND ND ND 10.0 ND ND ND ND 14-May-03 NR 5 ND ND ND ND 7.5 ND ND ND ND 19-Nov-03 NR 5 ND ND ND ND 7.1 ND ND ND ND 5-May-04 NR 5 ND ND ND ND 8.0 ND ND ND ND 9-Nov-04 NR 5 ND ND ND ND 10.0 ND ND ND ND 25-May-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 2-Nov-05 NR 5 ND ND ND ND 6.0 ND ND ND ND 24-May-06 NR 5 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 5 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.4 ND ND 2.6 8.3 ND ND ND ND NC2L = 2.8 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND ND 12.0 ND ND ND ND 28-May-08 0.47 1 Dry ND ND 1.0 10.0 ND ND ND ND 5-Nov-08 0.47 1.0 Dry ND ND 1.1 9.7 ND ND ND ND 2-Jun-09 0.47 1.0 2.4 ND ND 1.4 7.9 ND ND ND ND 19-Nov-09 0.47 1.0 ND ND ND ND ND ND ND ND ND NC21- = 3 pg/L (01/01/10) 15-Jun-10 0.47 1.0 0.56 J ND ND 2.2 2.9 ND ND ND ND 29-Nov-10 0.47 1.0 ND ND ND 2.5 5.7 ND ND ND ND 31-May-11 0.47 1.0 ND ND ND 2.3 3.9 ND ND ND ND 19-Dec-11 0.47 1.0 1.4 ND ND 3.0 5.2 ND ND ND ND 30-May-12 0.47 1.0 0.49 J ND ND 2.8 2.4 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND 2.5 1.4 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND INS 1.1 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND ND 2.6 1.4 ND ND ND ND 6-May-14 EPA 8260 0.47 1.0 ND ND ND 2.8 ND ND ND ND ND 21-Oct-14 EPA 8260 0.47 1.0 ND ND ND 2.6 2.6 ND ND ND ND 19-May-15 EPA 8260 0.47 1.0 ND ND ND 3.0 1.4 ND ND ND ND 7-Dec-15 EPA 8260 0.47 1.0 ND ND ND 2.5 0.62 J ND ND ND ND 2-May-16 EPA 8260 0.47 1.0 ND ND ND 3.3 ND ND ND ND ND 12-Dec-16 EPA 8260 0.47 1.0 ND ND ND 3.5 1.3 ND ND ND ND 26-Jun-17 EPA 8260 0.47 1.0 --- ND ND 3.3 0.76 J ND ND ND ND 14-Dec-17 EPA 8260 0.47 1.0 --- ND ND 3.7 0.86 J ND ND ND ND 14-May-18 EPA 8260 0.47 1.0 --- ND ND 3.6 0.52 J ND ND ND ND 4-Dec-18 EPA 8260B 0.47 1.0 --- ND ND 4.7 0.66 J ND ND ND ND 6-May-19 EPA8260D 0.34 1.0 --- ND ND 5.9 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 38 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-31) MW-4 MW-5 MW-6S MW-61) Blanks Vinyl Chloride 28-Apr-94 NR 10 ND ND ND NI NI NI NI NI ND 3-May-00 NR 10 NA ND ND ND ND ND ND ND ND 8-Nov-00 NR 10 NA ND ND ND ND ND ND ND ND 29-May-01 NR 10 NA ND ND ND ND ND ND ND ND 6-Nov-01 NR 10 NA ND ND ND ND ND ND ND ND 21-May-02 NR 10 NA ND ND ND ND ND ND ND ND 13-Nov-02 NR 10 NA ND ND ND ND ND ND ND ND 14-May-03 NR 10 ND ND ND ND ND ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND ND ND ND ND ND 5-May-04 NR 10 ND ND ND ND ND ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND ND ND ND ND ND 25-May-05 NR 10 ND ND ND ND ND ND ND ND ND 2-Nov-05 NR 10 ND ND ND ND ND ND ND ND ND 24-May-06 NR 10 ND ND ND ND ND ND ND ND ND 1-Nov-06 NR 10 ND ND ND ND ND ND ND ND ND 29-May-07 NR 1 2.6 ND ND 2.7 0.52 J ND ND ND ND NC2L = 0.015 pg/L (10/23/07) 28-Nov-07 NR 1 ND ND ND 1.8 1.9 ND ND ND ND 28-May-08 0.62 1.0 Dry ND ND 2.4 1.5 ND ND ND ND 5-Nov-08 0.62 1.0 Dry ND ND 2.1 1.9 ND ND ND ND 2-Jun-09 0.62 1.0 1.9 ND ND 2.4 0.80 J ND ND ND ND 19-Nov-09 0.62 1.0 ND ND ND 1.3 ND ND ND ND ND NC21- = 0.03 pg/L (01/01/10) 15-Jun-10 0.62 1.0 1.4 ND ND 2.3 ND ND ND ND ND 29-Nov-10 0.62 1.0 0.73 J ND ND 2.5 0.73 J ND ND ND ND 31-May-11 0.62 1.0 0.66 J ND ND 2.2 ND ND ND ND ND 19-Dec-11 0.62 1.0 2.8 ND ND 1.9 ND ND ND ND ND 30-May-12 0.62 1.0 1.2 ND ND 1.6 ND ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND ND ND ND ND ND 11-Jun-13 0.62 1.0 1.7 ND ND INS ND ND ND ND ND 29-Oct-13 0.62 1.0 0.64 J ND ND 0.99 J ND ND ND ND ND 6-May-14 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 21-Oct-14 EPA 8260 0.62 1.0 ND ND ND 0.91 J ND ND ND ND ND 19-May-15 EPA 8260 0.62 1.0 ND ND ND 0.89 J ND ND ND ND ND 7-Dec-15 EPA 8260 0.62 1.0 ND ND ND 1.1 ND ND ND ND ND 2-May-16 EPA 8260 0.62 1.0 ND ND ND 0.62 J ND ND ND ND ND 12-Dec-16 EPA 8260 0.62 1.0 ND ND ND 0.88 J ND ND ND ND ND 26-Jun-17 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 14-Dec-17 EPA 8260 0.62 1.0 --- ND ND 1.1 ND ND ND ND ND 14-May-18 EPA 8260 0.62 1.0 --- ND ND 1.0 ND ND ND ND ND 4-Dec-18 EPA 8260B 0.62 1.0 --- ND ND 1.2 ND ND ND ND ND 6-May-19 EPA8260D 0.60 1.0 --- ND ND 1.4 ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 39 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Analyte Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks Xylene (Total) 28-Apr-94 NR 5 6.2 330 80.0 NI NI NI NI NI ND 3-May-00 NR 5 NA 120 34.0 ND ND ND ND ND ND 8-Nov-00 NR 5 120 7.2 ND ND ND ND ND ND NA 29-May-01 NR 5 NA 177 20 ND ND ND ND ND ND 6-Nov-01 NR 5 NA 125 7.6 ND ND ND ND ND ND 21-May-02 NR 5 NA 149 18.0 ND ND ND ND ND ND 13-Nov-02 NR 5 NA 126 21.0 ND ND ND ND ND ND 14-May-03 NR 5 7.0 222 65.9 ND ND ND ND ND ND 19-Nov-03 NR 5 ND 107 29.0 ND ND ND ND ND ND 5-May-04 NR 5 ND 90.0 41.0 ND ND ND ND ND ND 9-Nov-04 NR 5 ND 106 41.0 ND ND ND ND ND ND 25-May-05 NR 5 ND 152 46.0 ND ND ND ND ND ND 2-Nov-05 NR 5 ND 209 39.0 ND ND ND ND ND ND 24-May-06 NR 10 ND 82.8 22.5 ND ND ND ND ND ND 1-Nov-06 NR 5 ND 118 14.0 ND ND ND ND ND ND 29-May-07 NR 4 1.1 J 120 37.0 ND ND ND ND ND ND NC2L = 530 Ng/L (10/23/07) 28-Nov-07 NR 5 ND 71.0 5.7 ND 2.0 J ND ND ND ND 28-May-08 0.89 5 Dry 76.1 14.4 ND 1.3 J ND ND ND ND 5-Nov-08 0.66 5 Dry 58.5 4.1 ND 2.5 ND ND ND ND 2-Jun-09 0.66 5 ND 56.5 24.6 ND 0.76 J ND ND ND ND 19-Nov-09 0.66 2.0 ND ND ND ND 50.6 29.4 ND ND ND NC2L = 500 Ng/L (01/01/10) 15-Jun-10 0.66 2.0 ND 78.1 24.7 ND ND ND ND ND ND 29-Nov-10 0.66 2.0 ND 46.3 12.9 ND 0.72 J ND ND ND ND 31-May-11 0.66 2.0 ND 45.0 15.9 ND ND ND ND ND ND 19-Dec-11 0.66 2.0 ND 39.3 14.0 ND 0.74 J ND ND ND ND 30-May-12 0.66 2.0 ND 30.2 24.5 ND ND ND ND ND ND 3-Dec-12 0.66 2.0 ND 23.7 12.6 ND ND ND ND ND ND 11-Jun-13 0.66 5.0 ND 67.7 59.4 INS ND ND ND ND ND 29-Oct-13 0.66 5.0 ND 33.8 23.1 ND ND ND ND ND ND 6-May-14 EPA 8260 0.66 5.0 ND 42.7 32.6 ND ND ND ND ND ND 21-Oct-14 EPA 8260 0.66 5.0 ND 37.1 15.4 ND ND ND ND ND ND 19-May-15 EPA 8260 0.66 5.0 ND 32.5 25.4 ND ND ND ND ND ND 7-Dec-15 EPA 8260 0.66 5.0 ND 38.6 23.1 ND ND ND ND ND ND 2-May-16 EPA 8260 0.66 5.0 ND 43.2 21.1 ND ND ND ND ND ND 12-Dec-16 EPA 8260 0.66 5.0 ND 31.3 8.10 ND ND ND ND ND ND 26-Jun-17 EPA 8260 0.66 5.0 --- 28.0 15.20 ND ND ND ND ND ND 14-Dec-17 EPA 8260 0.66 5.0 --- 23.3 16.90 ND ND ND ND ND ND 14-May-18 EPA 8260 0.66 5.0 --- 21.8 51.60 ND ND ND ND ND ND 4-Dec-18 EPA 8260B 0.66 1.0 --- 21.4 28.00 ND ND ND ND ND ND 6-May-19 EPA 8260D 1.50 2.0 --- 55.8 17.7 ND ND ND ND ND ND Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 40 of 41 Labella Associates TABLE A2-2: Historical Groundwater Constituents Collection Date Method DL RL MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Blanks 1,1,2-Trichloroethane 11-Jun-13 0.29 1.0 ND 0.79 J ND INS ND ND ND ND ND GWPS = 0.6 pg/L (10/23/07) 29-Oct-13 0.29 1.0 ND ND ND ND ND ND ND ND ND 6-May-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 21-Oct-14 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 19-May-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 7-Dec-15 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 2-May-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 12-Dec-16 EPA8260 0.29 1.0 ND ND ND ND ND ND ND ND ND 26-Jun-17 EPA8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-Dec-17 EPA8260 0.29 1.0 --- ND ND ND ND ND ND ND ND 14-May-18 EPA8260 0.58 2.0 --- ND ND ND ND ND ND ND ND 4-Dec-18 EPA8260B 0.29 1.0 --- ND ND ND ND ND ND ND ND 6-May-19 EPA8260D 0.59 1.0 --- ND ND ND ND ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. INS = Not sampled. NE = Not established. NR = Not reported. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). NC2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202. GWPS = Groundwater Protection Standards established by the DENR-SWS for constituents with no listed NC2L standard.. Bold values are greater than the NC2L Groundwater Standards or GWPS. Burke County, Kirksey Drive Landfill Permit No. 12-01 Page 41 of 41 Labella Associates TABLE A2-3: Historical Groundwater Field Parameters Parameter Collection Date Upgradient Downgradient MW-1 MW-2 MW-3S MW-3D MW-4 MW-5 MW-6S MW-6D Well Depth [ft] - 50.55 45.70 26.69 78.40 29.50 49.80 25.00 60.00 Conductivity (at 25c) 11-Jun-13 233.1 1168.0 847 - 56.9 14.2 62.8 74.1 [MS/cm] 28-Oct-13 326.9 1721.0 107.8 702 52.3 17.9 46.2 87.1 5-May-14 214.0 1161.0 828 687 70.6 28.8 65.3 102.3 20-Oct-14 376.0 1891.0 841 793 161.1 24.7 70.2 120.1 18-May-15 232.0 2160.0 878 823 99 19 66 106 7-Dec-15 273.0 2102.0 902 833 108 24 84 112 2-May-16 246.7 1873.0 936 746 69.8 18.4 64.9 86 12-Dec-16 176.7 2059.0 767 793 111 24.6 66.6 115.9 26-Jun-17 -- 1937.0 791 791 100.4 24.1 72 107 14-Dec-17 2185.0 920 875 99 25 97 114 14-May-18 1658.0 1117 923 131 22.2 118 59 4-Dec-18 1604.0 776 661 70 48 64.3 92.8 Resample-> 8-Feb-19 -- -- -- 55.9 - - -- 6-May-19 1923 916 792 59.6 23.3 50.6 85.6 Resample-> 23-Jul-19 -- -- -- 1454 - - - -- pH 11-Jun-13 5.9 6.1 6.36 - 5.36 5.54 5.3 6.27 [standard units] 28-Oct-13 5.7 6.1 6.42 6.22 5.47 6.64 5.8 6.3 5-May-14 6.4 6.6 7.18 7.2 6.43 6.52 6.84 6.88 20-Oct-14 6.0 6.1 6.38 6.61 6.3 5.59 5.56 6.39 18-May-15 5.8 5.9 6.24 5.99 5.34 4.92 5.65 6.18 7-Dec-15 6.2 6.0 6.3 6.03 5.42 5.66 5.68 6.29 2-May-16 5.5 5.9 5.84 6.09 5.37 5.81 5.61 5.9 12-Dec-16 6.2 6.2 6.5 6.38 5.62 6.28 5.51 5.99 26-Jun-17 -- 5.9 6.19 6.21 5.3 6.92 5.35 5.31 14-Dec-17 6.2 6.44 6.47 5.84 5.47 5.9 6.63 14-May-18 6.2 6.65 6.4 6.11 5.72 6.1 6.76 4-Dec-18 6.0 6.55 6.55 6.54 8.07 7.21 6.15 Resample--> 8-Feb-19 - - -- 5.64 -- -- -- 6-May-19 6.01 6.49 6.17 6.66 5.86 6.56 6.08 Resample--> 23-Jul-19 -- -- - 6.00 -- -- -- -- Temperature 11-Jun-13 17.0 17.4 15.2 - 15.9 16.4 14 15.4 [ ° C] 28-Oct-13 15.9 16.0 16.6 15.8 15.3 15.1 15.7 15.7 5-May-14 16.4 17.9 15.4 16.7 16.7 16.2 14.6 15.6 20-Oct-14 14.5 15.0 16.3 15.2 12.7 15.0 14.5 13.2 18-May-15 22.5 17.1 15.7 16.1 17.3 21.0 16.1 17.1 7-Dec-15 14.7 16.1 15.9 15.7 14.9 14.6 15.7 14.9 2-May-16 17.7 16.8 15.7 17.0 16.8 17.0 14 15.6 12-Dec-16 15.0 15.9 16.6 15.6 15.2 15.5 15.6 14.8 26-Jun-17 -- 17.4 17.1 16.5 16 17.2 14.6 15 14-Dec-17 16.4 15.7 13.4 14.8 14.7 14.3 10.9 14-May-18 19.3 14.4 15.4 18.1 18.5 18.8 19.3 4-Dec-18 15.3 14.6 13.9 14 14 13.3 14.5 Resample--> 8-Feb-19 -- -- - 15.2 -- -- -- 6-May-19 17.3 15.4 17.0 16.1 17.4 15.1 15.5 Resample--> 23-Jul-19 -- -- 17.3 -- -- -- -- Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 1 of 2 TABLE A2-3: Historical Groundwater Field Parameters Dissolved Oxygen [mg/L] 6-May-19 23-Jul-19 0.92 -- 3.59 -- 1.09 0.91 5.18 -- 5.73 - 5.44 - 2.13 - Oxidation Reduction Potential 6-May-19 14.1 -4.6 222.3 165.4 235.3 183.1 126.9 [mv] 23-Jul-19 -- -- -- 210.5 - - - - Turbidity 11-Jun-13 27.4 4.50 3.65 - 4.14 12.72 7.62 3.84 [NTU] 28-Oct-13 7.86 10.05 8.42 4.31 12.91 6.81 6.08 5.91 5-May-14 13.90 9.25 18.12 7.68 24.30 6.99 6.98 10.55 20-Oct-14 10.50 6.13 11.75 6.03 4.89 7.67 25.10 4.82 18-May-15 15.30 4.09 6.14 4.65 21.10 15.30 14.60 5.57 7-Dec-15 21.90 3.93 7.11 5.15 17.70 13.33 26.10 6.71 2-May-16 12.55 4.44 4.05 7.05 19.85 22.06 24.80 25.75 12-Dec-16 13.12 9.29 7.33 6.75 4.45 8.11 3.39 1.38 26-Jun-17 -- 7.55 7.15 6.15 9.15 12.13 6.58 6.87 14-Dec-17 10.05 4.75 2.26 12.01 20.15 12.75 5.21 14-May-18 2.79 0.24 0.00 20.90 36.92 3.30 0.00 4-Dec-18 8.39 29.40 4.31 31.00 10.30 6.71 4.17 Resample-> 8-Feb-19 -- -- -- 7.96 - - - 6-May-19 5.29 11.5 0.65 5.71 17.8 22.1 5.08 Resample-> 23-Jul-19 -- -- 3.12 - - - - Notes: °C= degrees Centigrade S.U.= Standard Units pS = microsemens per cm NTU = Nephelometric Turbidity Units ft = feet mg/L = milligrams per liter my = millivolts Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 2 of 2 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks INORGANICS Arsenic 28-Jun-95 NR 5 ND ND 10.0 NA 25-Oct-95 NR 5 ND ND 10.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND 3.1 J Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 2.6 10.0 ND ND Dry ND 5-Nov-08 2.7 10.0 ND ND Dry 4.8 J 2-Jun-09 2.7 10.0 ND ND ND ND 19-Nov-09 2.7 10.0 ND ND ND ND NC213 = 10 pg/L (05/01/2007) 14-Jun-10 2.7 10.0 ND ND Dry ND 29-Nov-10 2.7 10.0 ND ND Dry ND 31-May-11 2.7 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND 6-May-19 5.0 10.0 ND ND 5.2 J ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 1 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Barium 28-Apr-94 NR 100 ND ND 550 NA 6-Oct-94 NR 100 ND ND 356 NA 28-Jun-95 NR 100 ND ND 32.0 NA 25-Oct-95 NR 100 ND ND 301 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 100 ND ND 540 NA 12-May-97 NR 100 ND ND 480 NA 19-Nov-97 NR 100 ND ND 400 NA 27-May-98 NR 100 ND 2000 500 NA 24-Nov-98 NR 100 ND ND 430 NA 12-May-99 NR 10 32.0 30.0 370 ND 19-Oct-99 NR 500 ND ND NA ND 3-May-00 NR 500 ND ND ND ND 8-Nov-00 NR 500 ND ND ND ND 29-May-01 NR 500 ND ND ND ND 6-Nov-01 NR 500 ND ND ND ND 21-May-02 NR 500 ND ND ND ND 13-Nov-02 NR 500 ND ND ND ND 14-May-03 NR 500 ND ND ND ND 19-Nov-03 NR 500 ND ND ND ND 5-May-04 NR 500 ND ND ND ND 9-Nov-04 NR 500 ND ND ND ND 25-May-05 NR 500 ND ND Dry ND 2-Nov-05 NR 500 ND ND Dry ND 24-May-06 NR 500 ND ND Dry ND 1-Nov-06 NR 500 ND ND ND ND 29-May-07 NR 100 33.6 J 35.2 J Dry ND 28-Nov-07 NR 100 31.9 J 32.3 J Dry 0.30 J 28-May-08 0.2 100 40.2 J 40.4 J Dry 0.33 J 5-Nov-08 0.20 100 33.8 B 35.0 B Dry 10.5 J 2-Jun-09 0.20 100 29.6 B 32.6 B 320 15.2 J 19-Nov-09 0.20 100 36.3 B 41.2 B 364 19.8 J NC2B = 1,000 pg/L (05/01/2007) 14-Jun-10 0.20 100 31.0 B 32.5 B Dry 26.3 J 29-Nov-10 0.20 100 28.2 J 29.0 J Dry ND 31-May-11 0.20 100 30.1 J 29.9 J Dry ND 19-Dec-11 5.0 100 32.4 J 41.4 J 558 ND 30-May-12 5.0 100 33.1 J 33.7 J 34.2 J ND 3-Dec-12 5.0 100 31.0 J 28.9 J ND ND 11-Jun-13 5.0 100 43.8 B 45.7 B 261 13.7 J 29-Oct-13 5.0 100 31.4 J 33.1 J Dry ND 5-May-14 5.0 100 31.0 J 33.1 J 301 ND 21-Oct-14 5.0 100 33.6 J 34.3 J 343 ND 19-May-15 2.5 100 33.6 J 34.1 J Dry NA 7-Dec-15 2.5 100 36.5 J 37.8 J 350 ND 2-May-16 2.5 100 32.5 J 32.9 J 766 ND 12-Dec-16 2.5 100 22.8 J 82.1 J NS ND 26-Jun-17 2.5 100 38.1 J 38.0 J 301 2.5 J 14-Dec-17 2.5 100 36.0 J 36.8 J 282 ND 14-May-18 2.5 100 32.9 J 33.5 J 32.9 J ND 4-Dec-18 2.5 5 33.1 32.0 267 ND 6-May-19 2.5 5 26.4 26.2 239 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 2 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cadmium 28-Jun-95 NR 1 2.0 2.0 4.0 NA 25-Oct-95 NR 1 1.0 ND 1.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 1 ND ND ND NA 12-May-97 NR 1 ND ND ND NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 1 ND ND NA ND 3-May-00 NR 1 ND ND ND ND 8-Nov-00 NR 1 ND ND ND ND 29-May-01 NR 1 ND ND ND ND 6-Nov-01 NR 1 ND ND ND ND 21-May-02 NR 1 ND ND ND ND 13-Nov-02 NR 1 ND ND ND ND 14-May-03 NR 1 ND ND ND ND 19-Nov-03 NR 1 ND ND ND ND 5-May-04 NR 1 ND ND ND ND 9-Nov-04 NR 1 ND ND ND ND 25-May-05 NR 1 ND ND Dry ND 2-Nov-05 NR 1 ND ND Dry ND 24-May-06 NR 1 ND ND Dry ND 1-Nov-06 NR 1 ND ND ND ND 29-May-07 NR 1 ND ND Dry ND 28-Nov-07 NR 1 ND ND Dry ND 28-May-08 0.5 1.0 ND ND Dry ND 5-Nov-08 0.50 1.0 ND ND Dry ND 2-Jun-09 0.50 1.0 ND ND ND ND 19-Nov-09 0.50 1.0 ND ND ND ND NC2B = 2 pg/L (05/01/2007) 14-Jun-10 0.50 1.0 ND ND Dry ND 29-Nov-10 0.50 1.0 ND ND Dry ND 31-May-11 0.50 1.0 ND ND Dry ND 19-Dec-11 1.0 1.0 ND ND ND ND 30-May-12 1.0 1.0 ND ND ND ND 3-Dec-12 1.0 1.0 ND ND ND ND 11-Jun-13 1.0 1.0 ND ND ND ND 29-Oct-13 1.0 1.0 ND ND Dry ND 5-May-14 1.0 1.0 ND ND ND ND 21-Oct-14 1.0 1.0 ND ND ND ND 19-May-15 0.5 1.0 ND ND Dry NA 7-Dec-15 0.5 1.0 ND ND ND ND 2-May-16 0.5 1.0 ND ND ND ND 12-Dec-16 0.5 1.0 ND ND NS ND 26-Jun-17 0.5 1.0 ND ND ND ND 14-Dec-17 0.5 1.0 ND ND ND ND 14-May-18 0.5 1.0 ND ND ND ND 4-Dec-18 0.5 1.0 ND ND ND ND 6-May-19 0.5 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 3 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Chromium 12-May-97 NR 1 2.0 1.0 2.0 NA 19-Nov-97 NR 1 ND ND ND NA 27-May-98 NR 1 ND ND ND NA 24-Nov-98 NR 1 ND ND 1.0 NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 12.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 24.0 22.0 24.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 0.87 J 1.0 J Dry 0.85 J 5-Nov-08 0.40 10.0 0.76 J 0.76 J Dry ND 2-Jun-09 0.40 10.0 0.45 J 0.48 J 4.7 J ND 19-Nov-09 0.40 10.0 0.67 B 0.66 B 2.2 B 1.1 J NC2B = 20 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 0.75 J 1.0 J Dry ND 29-Nov-10 0.40 10.0 ND 0.80 J Dry ND 31-May-11 0.40 10.0 1.2 B 0.84 B Dry 0.73 J 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 7.4 J ND 21-Oct-14 5.0 10.0 ND ND 6.3 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.3 J ND 2-May-16 2.5 10.0 ND ND 3.8 J ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 7.7 J ND 14-Dec-17 2.5 10.0 ND ND 4.6 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 2.8 J ND 6-May-19 2.5 5.0 ND ND 4.4 J ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 4 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Cobalt 28-Jun-95 NR 10 ND ND 13.0 NA 25-Oct-95 NR 10 ND ND 12.0 NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 ND ND 20.0 NA 12-May-97 NR 6 ND ND 11.0 NA 19-Nov-97 NR 5 ND ND 13.0 NA 27-May-98 NR 1 2.0 ND 13.0 NA 24-Nov-98 NR 1 ND ND 11.0 NA 12-May-99 NR 10 ND ND 6.9 ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND 23.0 ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 ND ND ND ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 ND ND Dry ND 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.6 10.0 ND ND Dry ND 5-Nov-08 0.60 10.0 4.0 B 3.4 B Dry 3.5 J 2-Jun-09 0.60 10.0 4.8 B 7.0 B 8.6 B 3.3 J 19-Nov-09 0.60 10.0 ND ND 1.1 J ND NC213 = NE (05/01/2007) 14-Jun-10 0.60 10.0 ND ND Dry ND 29-Nov-10 0.60 10.0 ND ND Dry ND 31-May-11 0.60 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND 7.9 J ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 6.0 J ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND 9.6 J NS ND 26-Jun-17 2.5 10.0 ND ND 7.5 J ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 3.6 J ND 6-May-19 2.5 5.0 ND ND 4.2 J ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 5 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Copper 28-May-08 0.3 10 2.1 J 2.2 J Dry 0.38 J 5-Nov-08 0.30 10 1.4 B 0.71 B Dry 0.94 J 2-Jun-09 0.30 10 ND ND 1.8 J ND 19-Nov-09 0.30 10 1.5 J 1.9 J 1.9 J ND NC2B = 7 pg/L (05/01/2007)* 14-Jun-10 0.30 10 0.95 J 1.1 J Dry ND 29-Nov-10 0.30 10 ND 0.39 J Dry ND 31-May-11 0.30 10 ND 1.3 J Dry ND 19-Dec-11 5.0 10 ND ND 8.6 J ND 30-May-12 5.0 10 ND ND ND ND 3-Dec-12 5.0 10 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND 10.8 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND 5.5 J ND 21-Oct-14 5.0 10.0 ND ND 6.4 J ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND 3.0 J ND 2-May-16 2.5 10.0 ND ND 12.1 * ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND 6.4 J ND 14-Dec-17 2.5 10.0 ND ND 4.7 J ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 6 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Lead 28-Apr-94 NR 1 1.0 ND ND NA 6-Oct-94 NR 5 ND ND ND NA 28-Jun-95 NR 5 ND ND ND NA 25-Oct-95 NR 5 ND ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 5 ND ND ND NA 12-May-97 NR 5 ND ND ND NA 19-Nov-97 NR 5 ND ND ND NA 27-May-98 NR 5 ND ND ND NA 24-Nov-98 NR 5 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 10 ND ND NA ND 3-May-00 NR 10 ND ND ND ND 8-Nov-00 NR 10 ND ND ND ND 29-May-01 NR 10 ND ND ND ND 6-Nov-01 NR 10 ND ND ND ND 21-May-02 NR 10 ND ND ND ND 13-Nov-02 NR 10 ND ND ND ND 14-May-03 NR 10 ND ND ND ND 19-Nov-03 NR 10 16.0 14.0 16.0 ND 5-May-04 NR 10 ND ND ND ND 9-Nov-04 NR 10 ND ND ND ND 25-May-05 NR 10 ND ND Dry ND 2-Nov-05 NR 10 ND ND Dry ND 24-May-06 NR 10 ND ND Dry ND 1-Nov-06 NR 10 ND ND ND ND 29-May-07 NR 10 2.3 B 2.5 B Dry 6.1 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 4 10.0 ND ND Dry ND 5-Nov-08 4.0 10.0 ND ND Dry ND 2-Jun-09 4.0 10.0 ND ND ND ND 19-Nov-09 4.0 10.0 ND ND ND ND NC2B = 25 pg/L (05/01/2007) 14-Jun-10 4.0 10.0 ND ND Dry ND 29-Nov-10 4.0 10.0 ND ND Dry ND 31-May-11 4.0 10.0 ND ND Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 4.1 J ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 7 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Nickel 12-May-99 NR 5 ND ND 5.6 ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 ND ND ND ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 50 ND ND Dry ND 28-Nov-07 NR 50 ND ND Dry ND 28-May-08 1.7 50.0 ND ND Dry ND 5-Nov-08 1.7 50.0 ND ND Dry 2.2 J 2-Jun-09 1.7 50.0 ND ND 9.4 J ND 19-Nov-09 1.7 50.0 ND ND 4.6 B 2.2 J NC213 = 25 pg/L (05/01/2007) 14-Jun-10 1.7 50.0 ND ND Dry ND 29-Nov-10 1.7 50.0 ND ND Dry ND 31-May-11 1.7 50.0 ND ND Dry 2.3 J 19-Dec-11 5.0 50.0 ND ND 10.2 J ND 30-May-12 5.0 50.0 ND ND ND ND 3-Dec-12 5.0 50.0 ND ND ND ND 11-Jun-13 5.0 50.0 ND ND 5.8 J ND 29-Oct-13 5.0 50.0 ND ND Dry ND 5-May-14 5.0 50.0 ND ND 9.6 J ND 21-Oct-14 5.0 50.0 ND ND 10.4 J ND 19-May-15 2.5 50.0 ND ND Dry NA 7-Dec-15 2.5 50.0 ND ND 5.1 J ND 2-May-16 2.5 50.0 ND ND 10.2 J ND 12-Dec-16 2.5 50.0 ND ND NS ND 26-Jun-17 2.5 50.0 ND ND 14.4 J ND 14-Dec-17 2.5 50.0 ND ND 8.7 J ND 14-May-18 2.5 50.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND 5.9 ND 6-May-19 2.5 5.0 ND ND 6.3 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 8 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Selenium 29-May-07 NR 10 ND 4.5 J Dry ND 28-Nov-07 NR 10 ND ND Dry 2.4 J 28-May-08 3.8 10.0 ND ND Dry ND 5-Nov-08 3.8 10.0 ND 4.3 B Dry 4.2 J 2-Jun-09 3.8 10.0 ND ND ND ND 19-Nov-09 3.8 10.0 4.5 J ND ND ND NC213 = 5 pg/L (05/01/2007) 14-Jun-10 3.8 10.0 ND ND Dry ND 29-Nov-10 3.8 10.0 ND ND Dry ND 31-May-11 3.8 10.0 ND ND Dry ND 19-Dec-11 10.0 10.0 ND ND ND ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 ND ND ND ND 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND ND ND 21-Oct-14 10.0 10.0 ND ND ND ND 19-May-15 5.0 10.0 ND ND Dry NA 7-Dec-15 5.0 10.0 ND ND ND ND 2-May-16 5.0 10.0 ND ND ND ND 12-Dec-16 5.0 10.0 ND ND NS ND 26-Jun-17 5.0 10.0 ND ND ND ND 14-Dec-17 5.0 10.0 ND ND ND ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND ND ND 6-May-19 5.0 10.0 ND ND ND ND Silver 5-Nov-08 0.1 10.0 0.17 B 0.11 B Dry 0.20 J 2-Jun-09 0.10 10.0 ND ND ND ND 19-Nov-09 0.10 10.0 0.17 J 0.21 J 0.38 J ND NC213 = 0.06 pg/L (05/01/2007) 14-Jun-10 0.10 10.0 ND ND ND ND 29-Nov-10 0.10 10.0 ND ND Dry ND 31-May-11 0.10 10.0 ND 0.30 J Dry ND 19-Dec-11 5.0 10.0 ND ND ND ND 30-May-12 5.0 10.0 ND ND ND ND 3-Dec-12 5.0 10.0 ND ND ND ND 11-Jun-13 5.0 10.0 ND ND ND ND 29-Oct-13 5.0 10.0 ND ND Dry ND 5-May-14 5.0 10.0 ND ND ND ND 21-Oct-14 5.0 10.0 ND ND ND ND 19-May-15 2.5 10.0 ND ND Dry NA 7-Dec-15 2.5 10.0 ND ND ND ND 2-May-16 2.5 10.0 ND ND ND ND 12-Dec-16 2.5 10.0 ND ND NS ND 26-Jun-17 2.5 10.0 ND ND ND ND 14-Dec-17 2.5 10.0 ND ND ND ND 14-May-18 2.5 10.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 9 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Thallium 4-Dec-18 0.1 0.1 ND ND 0.077 J --- 6-May-19 0.1 0.1 ND ND 0.11 ND Vanadium 19-Nov-03 NR 40.0 62 56 60 ND 5-May-04 NR 40 ND ND ND ND 9-Nov-04 NR 40 ND ND ND ND 25-May-05 NR 40 ND ND Dry ND 2-Nov-05 NR 40 ND ND Dry ND 24-May-06 NR 40 ND ND Dry ND 1-Nov-06 NR 40 ND ND ND ND 29-May-07 NR 25 ND ND Dry ND 28-Nov-07 NR 25 ND ND Dry ND 28-May-08 0.2 25.0 3.2 J 4.1 J Dry ND 5-Nov-08 0.20 25.0 0.63 B 0.78 B Dry 0.85 J 2-Jun-09 0.20 25.0 1.9 B 2.1 B 1.1 B 1.2 J 19-Nov-09 0.20 25.0 2.6 B 3.0 J 0.95 B 0.58 J NC2B = NE (05/01/2007) 14-Jun-10 0.20 25.0 2.3 B 2.2 B Dry 1.2 J 29-Nov-10 0.20 25.0 ND ND Dry ND 31-May-11 0.20 25.0 1.7 J 1.7 J Dry ND 19-Dec-11 5.0 25.0 ND ND ND ND 30-May-12 5.0 25.0 ND ND ND ND 3-Dec-12 5.0 25.0 ND ND ND ND 11-Jun-13 5.0 25.0 8.5 J 8.0 J ND ND 29-Oct-13 5.0 25.0 ND ND Dry ND 5-May-14 5.0 25.0 ND ND ND ND 21-Oct-14 5.0 25.0 ND ND ND ND 19-May-15 2.5 25.0 ND ND Dry NA 7-Dec-15 2.5 25.0 ND ND ND ND 2-May-16 2.5 25.0 3.3 J 3.1 J ND ND 12-Dec-16 2.5 25.0 ND ND NS ND 26-Jun-17 2.5 25.0 4 J 4.4 J 4.1 J ND 14-Dec-17 2.5 25.0 ND ND ND ND 14-May-18 2.5 25.0 ND ND ND ND 4-Dec-18 2.5 5.0 ND ND ND ND 6-May-19 2.5 5.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 10 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Zinc 6-Oct-94 NR 10 ND ND 11.0 NA 28-Jun-95 NR 10 17.0 21.0 60.0 NA 25-Oct-95 NR 10 28.0 ND ND NA 2-May-96 NA NA NA NA NA NA 16-Oct-96 NR 10 18.0 ND 34.0 NA 12-May-97 NR 10 50.0 30.0 30.0 NA 19-Nov-97 NR 10 ND ND ND NA 27-May-98 NR 10 ND 20.0 10.0 NA 24-Nov-98 NR 10 ND ND ND NA 12-May-99 NR 10 ND ND ND ND 19-Oct-99 NR 50 ND ND NA ND 3-May-00 NR 50 ND ND ND ND 8-Nov-00 NR 50 ND ND ND ND 29-May-01 NR 50 ND ND ND ND 6-Nov-01 NR 50 ND ND ND ND 21-May-02 NR 50 ND ND ND ND 13-Nov-02 NR 50 ND ND ND ND 14-May-03 NR 50 ND ND ND ND 19-Nov-03 NR 50 70.0 60.0 70.0 ND 5-May-04 NR 50 ND ND ND ND 9-Nov-04 NR 50 ND ND ND ND 25-May-05 NR 50 ND ND Dry ND 2-Nov-05 NR 50 ND ND Dry ND 24-May-06 NR 50 ND ND Dry ND 1-Nov-06 NR 50 ND ND ND ND 29-May-07 NR 10 3.2 B 3.3 B Dry 2.0 J 28-Nov-07 NR 10 ND ND Dry ND 28-May-08 0.4 10.0 2.4 B 3.5 B Dry 2.1 J 5-Nov-08 0.40 10.0 2.8 B 1.6 B Dry 8.9 J 2-Jun-09 0.40 10.0 0.70 B 2.7 B 3.9 B 83.0 19-Nov-09 0.40 10.0 6.7 B 8.0 B 14.5 B 3.5 J NC2B = 50 pg/L (05/01/2007) 14-Jun-10 0.40 10.0 ND ND Dry ND 29-Nov-10 0.40 10.0 ND ND Dry ND 31-May-11 0.40 10.0 14.9 B 11.6 B Dry 13.7 19-Dec-11 10.0 10.0 ND ND 181 ND 30-May-12 10.0 10.0 ND ND ND ND 3-Dec-12 10.0 10.0 ND ND ND ND 11-Jun-13 10.0 10.0 11.8 B 13.0 B 11.7 B 76.3 29-Oct-13 10.0 10.0 ND ND Dry ND 5-May-14 10.0 10.0 ND ND 10.3 ND 21-Oct-14 10.0 10.0 ND ND 18.0 ND 19-May-15 5.0 10.0 ND 10.4 Dry NA 7-Dec-15 5.0 10.0 ND ND 15.7 B 7.2 J 2-May-16 5.0 10.0 ND 5.9 J 49.2 ND 12-Dec-16 5.0 10.0 ND 8.0 J NS ND 26-Jun-17 5.0 10.0 ND ND 29.9 ND 14-Dec-17 5.0 10.0 ND ND 13.5 ND 14-May-18 5.0 10.0 ND ND ND ND 4-Dec-18 5.0 10.0 ND ND 7.4 J ND 6-May-19 5.0 10.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 11 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks ORGANICS Acetone 28-Nov-07 NR 100 3.0 B 3.3 B Dry 4.3 J 28-May-08 20 100 ND ND Dry ND 5-Nov-08 20.0 100 ND ND Dry ND 2-Jun-09 2.2 100 ND ND 6.0 B 3.2 J 19-Nov-09 2.2 100 4.0 B ND ND 3.8 J NC2B = NE (05/01/2007) 14-Jun-10 2.2 100 ND ND Dry 9.8 J 29-Nov-10 2.2 100 ND ND Dry 4.3 J 31-May-11 2.2 100 ND ND Dry 3.9 J 19-Dec-11 2.2 100 ND ND ND 6.6 J 30-May-12 2.2 100 ND ND ND ND 3-Dec-12 2.2 100 ND ND ND ND 11-Jun-13 2.2 100 ND ND ND ND 29-Oct-13 50.0 500 ND ND Dry ND 5-May-14 10.0 100 ND ND 17.6 J ND 21-Oct-14 10.0 100 ND ND ND ND 19-May-15 10.0 100 ND ND Dry NA 7-Dec-15 10.0 100 ND ND ND ND 2-May-16 10.0 100 ND ND ND ND 12-Dec-16 10.0 100 ND ND NS ND 26-Jun-17 10.0 100 10.8 J 26.9 J 13.4 J 23.0 J 14-Dec-17 10.0 100 ND ND ND ND 14-May-18 10.0 100 ND ND ND ND 4-Dec-18 10.0 25 ND ND ND ND 6-May-19 8.2 25 ND ND ND ND Benzene 19-Nov-09 0.25 1.0 2.1 0.48 J ND ND Resample> 15-Feb-10 0.25 1.0 ND NS NS ND NC2B = 1.19 pg/L (05/01/2007) 14-Jun-10 0.25 1.0 ND ND Dry ND 29-Nov-10 0.25 1.0 ND ND Dry ND 31-May-11 0.25 1.0 ND ND Dry ND 19-Dec-11 0.25 1.0 ND ND ND ND 30-May-12 0.25 1.0 ND ND ND ND 3-Dec-12 0.25 1.0 ND ND ND ND 11-Jun-13 0.25 1.0 ND ND ND ND 29-Oct-13 0.25 1.0 ND ND Dry ND 5-May-14 0.25 1.0 ND ND ND ND 21-Oct-14 0.25 1.0 ND ND ND ND 19-May-15 0.25 1.0 ND ND Dry NA 7-Dec-15 0.25 1.0 ND ND ND ND 2-May-16 0.25 1.0 ND ND ND ND 12-Dec-16 0.25 1.0 ND ND NS ND 26-Jun-17 0.25 1.0 ND ND ND ND 14-Dec-17 0.25 1.0 ND ND ND ND 14-May-18 0.25 1.0 ND ND ND ND 4-Dec-18 0.25 1.0 ND ND ND ND 6-May-19 0.20 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 12 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Bromomethane 5-May-14 0.29 10.0 ND ND 4.6 J ND NC2B = NE (05/01/2007) 21-Oct-14 0.29 10.0 ND ND 0.41 J ND 19-May-15 0.29 10.0 ND ND Dry NA 7-Dec-15 0.29 10.0 ND ND ND ND 2-May-16 0.29 10.0 ND ND ND ND 12-Dec-16 0.29 10.0 ND ND NS ND 26-Jun-17 0.29 10.0 ND ND ND ND 14-Dec-17 0.29 10.0 ND ND ND ND 14-May-18 0.29 10.0 ND ND ND ND 4-Dec-18 0.29 2.0 ND ND ND ND 6-May-19 0.95 2.0 ND ND 1.5 J ND Chlorobenzene 19-Nov-09 0.23 3.0 4.2 0.44 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.23 3.0 ND ND Dry ND 29-Nov-10 0.23 3.0 ND ND Dry ND 31-May-11 0.23 3.0 ND ND Dry ND 19-Dec-11 0.23 3.0 ND 0.58 J ND ND 30-May-12 0.23 3.0 ND ND ND ND 3-Dec-12 0.23 3.0 ND ND ND ND 11-Jun-13 0.23 3.0 ND ND ND ND 29-Oct-13 0.23 3.0 ND ND Dry ND 5-May-14 0.23 3.0 ND ND ND ND 21-Oct-14 0.23 3.0 ND ND ND ND 19-May-15 0.23 3.0 ND ND Dry NA 7-Dec-15 0.23 3.0 ND ND ND ND 2-May-16 0.23 3.0 ND ND ND ND 12-Dec-16 0.23 3.0 ND ND NS ND 26-Jun-17 0.23 3.0 ND ND ND ND 14-Dec-17 0.23 3.0 ND ND ND ND 14-May-18 0.23 3.0 ND ND ND ND 4-Dec-18 0.23 1.0 ND ND ND ND 6-May-19 0.53 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 13 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Chloromethane 14-Jun-10 0.11 1.0 0.14 B 0.17 B Dry 0.15 J NC2B = NE (05/01/2007) 29-Nov-10 0.11 1.0 ND ND Dry ND 31-May-11 0.11 1.0 ND ND Dry ND 19-Dec-11 0.11 1.0 ND ND ND ND 30-May-12 0.11 1.0 ND ND ND ND 3-Dec-12 0.11 1.0 ND ND ND ND 11-Jun-13 0.11 1.0 ND ND ND ND 29-Oct-13 0.11 1.0 ND ND Dry ND 5-May-14 0.11 1.0 ND ND ND ND 21-Oct-14 0.11 1.0 ND ND 0.19 J ND 19-May-15 0.11 1.0 ND ND Dry NA 7-Dec-15 0.11 1.0 ND ND ND ND 2-May-16 0.11 1.0 ND ND ND ND 12-Dec-16 0.11 1.0 ND ND ND 0.36 J 26-Jun-17 0.11 1.0 ND 0.28 J 0.54 J ND 14-Dec-17 0.11 1.0 ND ND ND ND 14-May-18 0.11 1.0 ND ND ND ND 4-Dec-18 0.11 1.0 ND ND ND ND 6-May-19 0.38 1.0 ND ND ND ND 1,2-Dichlorobenzene 19-Nov-09 0.30 5.0 0.31 J 0.34 J ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.30 5.0 ND ND Dry ND 29-Nov-10 0.30 5.0 ND ND Dry ND 31-May-11 0.30 5.0 ND ND Dry ND 19-Dec-11 0.30 5.0 ND ND ND ND 30-May-12 0.30 5.0 ND ND ND ND 3-Dec-12 0.30 5.0 ND ND ND ND 11-Jun-13 0.30 5.0 ND ND ND ND 29-Oct-13 0.30 5.0 ND ND Dry ND 5-May-14 0.30 5.0 ND ND ND ND 21-Oct-14 0.30 5.0 ND ND ND ND 19-May-15 0.30 5.0 ND ND Dry NA 7-Dec-15 0.30 5.0 ND ND ND ND 2-May-16 0.30 5.0 ND ND ND ND 12-Dec-16 0.30 5.0 ND ND NS ND 26-Jun-17 0.30 5.0 ND ND ND ND 14-Dec-17 0.30 5.0 ND ND ND ND 14-May-18 0.30 5.0 ND ND ND ND 4-Dec-18 0.30 1.0 ND ND ND ND 6-May-19 0.49 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 14 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks 1,4-Dichlorobenzene 19-Nov-09 0.33 1.0 4.5 1.9 ND ND NC2B = 488 pg/L (05/01/2007) 14-Jun-10 0.33 1.0 ND ND Dry ND 29-Nov-10 0.33 1.0 ND ND Dry ND 31-May-11 0.33 1.0 ND ND Dry ND 19-Dec-11 0.33 1.0 ND ND ND ND 30-May-12 0.33 1.0 ND ND ND ND 3-Dec-12 0.33 1.0 ND ND ND ND 11-Jun-13 0.33 1.0 ND ND ND ND 29-Oct-13 0.33 1.0 ND ND Dry ND 5-May-14 0.33 1.0 ND ND ND ND 21-Oct-14 0.33 1.0 ND ND ND ND 19-May-15 0.33 1.0 ND ND Dry NA 7-Dec-15 0.33 1.0 ND ND ND ND 2-May-16 0.33 1.0 ND ND ND ND 12-Dec-16 0.33 1.0 ND ND NS ND 26-Jun-17 0.33 1.0 ND ND ND ND 14-Dec-17 0.33 1.0 ND ND ND ND 14-May-18 0.33 1.0 ND ND ND ND 4-Dec-18 0.33 1.0 ND ND ND ND 6-May-19 0.58 1.0 ND ND ND ND 1,1-Dichloroethane 19-Nov-09 0.32 5.0 6.3 7.8 ND ND NC2B = NE (05/01/2007) 14-Jun-10 0.32 5.0 ND ND Dry ND 29-Nov-10 0.32 5.0 ND ND Dry ND 31-May-11 0.32 5.0 ND ND Dry ND 19-Dec-11 0.32 5.0 ND ND ND ND 30-May-12 0.32 5.0 ND ND ND ND 3-Dec-12 0.32 5.0 ND ND ND ND 11-Jun-13 0.32 5.0 ND ND ND ND 29-Oct-13 0.32 5.0 ND ND Dry ND 5-May-14 0.32 5.0 ND ND ND ND 21-Oct-14 0.32 5.0 ND ND ND ND 19-May-15 0.32 5.0 ND ND Dry NA 7-Dec-15 0.32 5.0 ND ND ND ND 2-May-16 0.32 5.0 ND ND ND ND 12-Dec-16 0.32 5.0 ND ND NS ND 26-Jun-17 0.32 5.0 ND ND ND ND 14-Dec-17 0.32 5.0 ND ND ND ND 14-May-18 0.32 5.0 ND ND ND ND 4-Dec-18 0.32 1.0 ND ND ND ND 6-May-19 0.41 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 15 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks cis-1,2-Dichloroethene 19-Nov-09 0.19 5.0 5.5 43.8 ND 0.26 J NC2B = NE (05/01/2007) 14-Jun-10 0.19 5.0 ND ND Dry ND 29-Nov-10 0.19 5.0 ND ND Dry ND 31-May-11 0.19 5.0 ND ND Dry ND 19-Dec-11 0.19 5.0 ND ND ND ND 30-May-12 0.19 5.0 ND ND ND ND 3-Dec-12 0.19 5.0 ND ND ND ND 11-Jun-13 0.19 5.0 ND ND ND ND 29-Oct-13 0.19 5.0 ND ND Dry ND 5-May-14 0.19 5.0 ND ND ND ND 21-Oct-14 0.19 5.0 ND ND ND ND 19-May-15 0.19 5.0 ND ND Dry NA 7-Dec-15 0.19 5.0 ND ND ND ND 2-May-16 0.19 5.0 ND ND ND ND 12-Dec-16 0.19 5.0 ND ND NS ND 26-Jun-17 0.19 5.0 ND ND ND ND 14-Dec-17 0.19 5.0 ND ND ND ND 14-May-18 0.19 5.0 ND ND ND ND 4-Dec-18 0.19 1.0 ND ND ND ND 6-May-19 0.66 1.0 ND ND ND ND 1,2-Dichloropropane 19-Nov-09 0.27 1.0 2.3 1.0 ND ND Resample> 15-Feb-10 0.27 1.0 ND ND NS ND NC2B = NE (05/01/2007) 14-Jun-10 0.27 1.0 ND ND Dry ND 29-Nov-10 0.27 1.0 ND ND Dry ND 31-May-11 0.27 1.0 ND ND Dry ND 19-Dec-11 0.27 1.0 ND ND ND ND 30-May-12 0.27 1.0 ND ND ND ND 3-Dec-12 0.27 1.0 ND ND ND ND 11-Jun-13 0.27 1.0 ND ND ND ND 29-Oct-13 0.27 1.0 ND ND Dry ND 5-May-14 0.27 1.0 ND ND ND ND 21-Oct-14 0.27 1.0 ND ND ND ND 19-May-15 0.27 1.0 ND ND Dry NA 7-Dec-15 0.27 1.0 ND ND ND ND 2-May-16 0.27 1.0 ND ND ND ND 12-Dec-16 0.27 1.0 ND ND NS ND 26-Jun-17 0.27 1.0 ND ND ND ND 14-Dec-17 0.27 1.0 ND ND ND ND 14-May-18 0.27 1.0 ND ND ND ND 4-Dec-18 0.27 1.0 ND ND ND ND 6-May-19 0.60 1.0 ND ND ND ND 1,4-Dioxane (p-Dioxane) 4-Dec-18 1.90 2.0 ND ND 10.5 ND 6-May-19 1.20 2.0 ND ND 7.6 ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 16 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Tetrachloroethene 19-Nov-09 0.46 1.0 0.58 J 8.8 ND ND Resample> 15-Feb-10 0.46 1.0 NS ND NS ND NC2B = 0.7 pg/L (05/01/2007) 14-Jun-10 0.46 1.0 ND ND Dry ND 29-Nov-10 0.46 1.0 ND ND Dry ND 31-May-11 0.46 1.0 ND ND Dry ND 19-Dec-11 0.46 1.0 ND ND ND ND 30-May-12 0.46 1.0 ND ND ND ND 3-Dec-12 0.46 1.0 ND ND ND ND 11-Jun-13 0.46 1.0 ND ND ND ND 29-Oct-13 0.46 1.0 ND ND Dry ND 5-May-14 0.46 1.0 ND ND ND ND 21-Oct-14 0.46 1.0 ND ND ND ND 19-May-15 0.46 1.0 ND ND Dry NA 7-Dec-15 0.46 1.0 ND ND ND ND 2-May-16 0.46 1.0 ND ND ND ND 12-Dec-16 0.46 1.0 ND ND NS ND 26-Jun-17 0.46 1.0 ND ND ND ND 14-Dec-17 0.46 1.0 ND ND ND ND 14-May-18 0.46 1.0 ND ND ND ND 4-Dec-18 0.46 1.0 ND ND ND ND 6-May-19 0.78 1.0 ND ND ND ND Trichloroethene 19-Nov-09 0.47 1.0 2.1 6.9 ND ND Resample> 15-Feb-10 0.47 1.0 NS ND NS ND NC2B = 2.5 pg/L (05/01/2007) 14-Jun-10 0.47 1.0 ND ND Dry ND 29-Nov-10 0.47 1.0 ND ND Dry ND 31-May-11 0.47 1.0 ND ND Dry ND 19-Dec-11 0.47 1.0 ND ND ND ND 30-May-12 0.47 1.0 ND ND ND ND 3-Dec-12 0.47 1.0 ND ND ND ND 11-Jun-13 0.47 1.0 ND ND ND ND 29-Oct-13 0.47 1.0 ND ND Dry ND 5-May-14 0.47 1.0 ND ND ND ND 21-Oct-14 0.47 1.0 ND ND ND ND 19-May-15 0.47 1.0 ND ND Dry NA 7-Dec-15 0.47 1.0 ND ND ND ND 2-May-16 0.47 1.0 ND ND ND ND 12-Dec-16 0.47 1.0 ND ND NS ND 26-Jun-17 0.47 1.0 ND ND ND ND 14-Dec-17 0.47 1.0 ND ND ND ND 14-May-18 0.47 1.0 ND ND ND ND 4-Dec-18 0.47 1.0 ND ND ND ND 6-May-19 0.34 1.0 ND ND ND ND Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 17 of 18 TABLE A2-4: Historical Surface Water Constituents Analyte Sample Date DL RL SW-1 SW-2 SW-3 Blanks Vinyl Chloride 19-Nov-09 0.62 1.0 2.6 ND ND ND Resample> 15-Feb-10 0.62 1.0 ND NS NS ND NC213 = 0.025 pg/L (05/01/2007) 14-Jun-10 0.62 1.0 ND ND Dry ND 29-Nov-10 0.62 1.0 ND ND Dry ND 31-May-11 0.62 1.0 ND ND Dry ND 19-Dec-11 0.62 1.0 ND ND ND ND 30-May-12 0.62 1.0 ND ND ND ND 3-Dec-12 0.62 1.0 ND ND ND ND 11-Jun-13 0.62 1.0 ND ND ND ND 29-Oct-13 0.62 1.0 ND ND Dry ND 5-May-14 0.62 1.0 ND ND ND ND 21-Oct-14 0.62 1.0 ND ND ND ND 19-May-15 0.62 1.0 ND ND Dry NA 7-Dec-15 0.62 1.0 ND ND ND ND 2-May-16 0.62 1.0 ND ND ND ND 12-Dec-16 0.62 1.0 ND ND NS ND 26-Jun-17 0.62 1.0 ND ND ND ND 14-Dec-17 0.62 1.0 ND ND ND ND 14-May-18 0.62 1.0 ND ND ND ND 4-Dec-18 0.62 1.0 ND ND ND ND 6-May-19 0.60 1.0 ND ND ND ND Notes: RL = Reporting Limit (Lab. Reporting Limit for September 1994 - May 1999; NC PQL for October 1999 - December 2006; and SWSL for December 2006 - present). DL = Laboratory Detection Limit. ND = Not Detected at or above the RL (prior to Dec. 2006) or the DL (after Dec. 2006). NA = No data available. NI = Not installed. NR = Not reported. NS = Not sampled. NE = Not established. J = Estimated concentration less than the RL but above the DL. B = Blank -Qualified Concentration (suspected to reflect laboratory or field contamination). Dry = Surface water point was considered to be dry and no sample collected. NC2B = 15A NCAC 2B Surface Water Standards. Bold values are greater than the NC2B. Surface water has been classified as Water Supply IV - Highly Developed, Freshwater, Critical Area. Burke County, Kirksey Drive Landfill Labella Associates Permit No. 12-01 Page 18 of 18 TABLE A2-5: Historical Surface Water Field Parameters Parameter Collection Date SW-1 SW-2 SW-3 Conductivity (at 25c) 11-Jun-13 54.4 63.2 655 [MS/cm] 29-Oct-13 78.2 67.8 -- 5-May-14 90.0 115.9 1036 20-Oct-14 103.2 130.7 1099 18-May-15 92.0 97 -- 7-Dec-15 90.0 94 647 2-May-16 73.8 71 1391 12-Dec-16 95.8 506 -- 26-Jun-17 92.0 1152 1032 14-Dec-17 122.0 61 869 14-May-18 137.0 220 105 4-Dec-18 102.9 90.6 395.4 6-May-19 96.1 91.8 986 pH 11-Jun-13 7.8 8.25 7.81 [standard units] 29-Oct-13 7.2 6.85 -- 5-May-14 8.1 8.42 8.17 20-Oct-14 7.0 7.38 7.8 18-May-15 7.0 6.87 -- 7-Dec-15 7.3 7.27 8.03 2-May-16 8.0 6.91 6.78 12-Dec-16 7.0 6.51 -- 26-Jun-17 7.2 5.64 7.36 14-Dec-17 8.3 8.26 8.3 14-May-18 7.6 7.61 7.14 4-Dec-18 7.4 7.36 6.78 6-May-19 8.51 6.98 7.92 Temperature 11-Jun-13 19.2 18.1 19.7 [ ° C] 29-Oct-13 13.1 12.4 -- 5-May-14 19.2 19 17.9 20-0 ct-14 14.3 14.1 13.8 18-May-15 19.1 19.5 -- 7-Dec-15 10.6 10.4 10.7 2-May-16 19.6 19.3 20.2 12-Dec-16 8.7 11 -- 26-Jun-17 20.0 19.9 19.8 14-Dec-17 6.2 6 6.8 14-May-18 12.4 19.9 19.4 4-Dec-18 11.5 11.7 6.3 6-May-19 20.1 19.4 18.5 Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01 TABLE A2-5: Historical Surface Water Field Parameters Dissolved Oxygen [mg/L] 6-May-19 5.89 6.14 5.93 Oxidation Reduction Potential 6-May-19 135.0 119.8 183.3 [mV] Turbidity 11-Jun-13 48.10 34.60 19.71 [NTU] 29-Oct-13 7.34 4.89 -- 5-M ay-14 15.50 16.70 15.80 20-Oct-14 12.02 11.85 20.40 18-May-15 8.63 6.09 -- 7-Dec-15 6.75 5.25 4.86 2-May-16 7.05 8.75 7.85 12-Dec-16 8.05 9.20 -- 26-Jun-17 15.05 8.70 9.01 14-Dec-17 61.00 4.04 4.34 14-May-18 0.40 0.00 0.40 4-Dec-18 12.30 20.60 7.37 6-May-19 11.1 10.2 17.5 Notes: °C= degrees Centigrade S.U.= Standard Units pS = microsemens per cm NTU = Nephelometric Turbidity Units Burke County, Kirksey Drive Landfill La Bella Associates Permit No. 12-01