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HomeMy WebLinkAbout16055-Loftis-Blythe-2018 Annual Methane Monitoring Report2018 Annual Methane Monitoring Report Loftis-Blythe Construction Site (aka InnerLoop North Industrial Park) 5600 and 5518 David Cox Rd. Charlotte, North Carolina Brownfields Project No. 16055-12-060 H&H Job No. HTZ-001 February 8, 2019 i S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc 2018 Annual Methane Monitoring Report Loftis-Blythe Construction Site (aka InnerLoop North Industrial Park) 5600 and 5518 David Cox Rd. Charlotte, North Carolina H&H Job No. HTZ-001 Table of Contents Section Page No. 1.0 Introduction ................................................................................................................ 1 2.0 Background ................................................................................................................ 2 3.0 Quarterly Methane Monitoring, Alarms, and Annual System Testing ................ 5 3.1 Quarterly Methane Monitoring Results ................................................................... 5 3.2 Methane Warning System Alarm and Inspection .................................................... 6 4.0 Summary and Conclusions ........................................................................................ 8 List of Tables Table 1 Methane Probe Monitoring Results Table 2 Indoor Methane Monitoring Results Table 3 Manhole & Trench Methane Monitoring Results List of Figures Figure 1 Site Location Map Figure 2 Subsurface Methane Monitoring Probe Location Map Figure 3 Indoor Methane Monitoring Location Map Figure 4 Manhole & Trench Sample Location Map List of Appendices Appendix A Equipment Calibration Documents 1 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc 2018 Annual Methane Monitoring Report Loftis-Blythe Construction Site (aka InnerLoop North Industrial Park) 5600 and 5518 David Cox Rd. Charlotte, North Carolina H&H Job No. HTZ-001 1.0 Introduction Hart & Hickman, PC (H&H), has prepared this Annual Methane Monitoring Report to document quarterly methane monitoring and annual methane warning system inspection and testing conducted at the Loftis-Blythe Construction Brownfields site (Brownfields Project No. 16055- 12-060) located at 5600 and 5518 David Cox Rd. in Charlotte, North Carolina. A site location map is provided as Figure 1. The site consists of two industrial buildings (Building 1 and Building 2) that were constructed in 2015 as part of redevelopment of the site. Building 1 (5600 David Cox Rd.) is located in the western portion of the site and is approximately 300,000 sq ft, and Building 2 (5518 David Cox Rd.) is located in the eastern portion of the site and is approximately 100,000 sq ft. A site layout is provided on Figure 2. The methane monitoring and methane warning system inspection and testing were conducted in accordance with the June 12, 2017 Methane Warning System Installation Report provided to the Brownfields Program. The quarterly methane monitoring events were conducted in March 2018, June 2018, September 2018, and December 2018 and included the collection of methane readings from four subsurface methane monitoring probes, ambient air methane readings from Building 1 and Building 2, and methane readings from sewer manholes and a drainage trench located in the vicinity of Building 2. The annual inspection and testing of the methane warning system installed in the western portion of Building 2 was conducted on October 12, 2018. The western portion of Building 2 has been vacant since December 2017. A brief summary of the site background is provided in Section 2.0, and the results of the methane monitoring and methane system inspection and testing for 2018 are provided in Section 3.0. 2 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc 2.0 Background Loftis Construction (also listed as Blythe Construction) previously occupied the property from the 1970s to 1983 and operated a permitted land clearing and inert debris landfill in the central portion of the site. The landfill was closed in 1984, and a notice was placed on the deed indicating the location of the buried materials. The estimated extent of the landfilled materials based upon the test pits is indicated in Figure 2. Results of test pits conducted as part of previous assessment activities indicated that the materials present in the landfill consist of soil, rock, tires, stumps, trees, woody debris, bricks, concrete, rebar, scrap metal, paper trash, and plastic. In July 2013, H&H conducted Brownfields assessment activities at the site. As part of the assessment activities, H&H conducted methane monitoring in and around the area of the former landfill. The methane monitoring conducted during the Brownfields assessment included the installation of 11 temporary methane probes. Five of the probes (MP-1, MP-6, MP-7, MP-10, and MP-13) were installed within the landfill area (as identified by previous test pits), and six of the sample locations (MP-2, MP-8, MP-9, MP-11, MP-12, and MP-14) were installed at locations around the perimeter of the identified landfill area. The locations of the temporary methane probes are shown on Figure 2. The results of the initial methane monitoring indicated that MP-10 contained a concentration of methane below the North Carolina Department of Environmental Quality (DEQ) Solid Waste screening level of 100% of the LEL (5% methane) for property boundaries, but above the screening level of 20% of the LEL (1.25% methane) for interior air. No other methane probes, including methane probes surrounding MP-10, contained concentrations of methane above the Regulation Level. The results of the methane monitoring in July 2013 are provided in Table 1. Based on the results of the methane monitoring during the 2013 Brownfields assessment activities, a methane monitoring plan was included in the Environmental Management Plan (EMP) for the site to further evaluate subsurface methane concentrations as part of and after construction activities. The methane monitoring plan included the installation and monitoring of 3 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc four methane monitoring probes (MP-10R, MP-15, MP-16, and MP-17) installed in the vicinity of previous methane monitoring probe MP-10. In accordance with the approved EMP, methane monitoring probes were installed in January 2015 and monitored approximately semi-annually (some events were delayed due to rainy weather conditions preceding or on the planned sampling day) after completion of the construction of the site buildings. The results of the methane monitoring indicated increasing levels of methane in probes MP-15, MP-16, and MP-10R near Building 2 (Figure 2 and Table 1). As shown on Figure 2, the highest concentrations of methane were measured in MP-16 located closer to the center of the landfill area. Because of the elevated levels of methane detected in the probes, H&H also measured methane in indoor air in both buildings during the August 2016 and March 2017 monitoring events to ensure that there was not an imminent hazard, and no methane was detected. Based on the results of the post-building construction methane monitoring, the property owner at the time submitted a Methane Warning System Design Plan (Design Plan) for the western portion of Building 2 to the Brownfields Program on May 16, 2017. In addition to the installation of a methane warning system, the Design Plan included quarterly monitoring of subsurface methane probes and possible methane accumulation areas (i.e. manholes and trenches), indoor air monitoring for methane, and inspection and testing of the methane warning system. Following approval of the Design Plan, the methane warning system was installed in the western portion of Building 2 in May 2017. A report documenting the installation of the methane warning system (Methane Warning System Installation Report) was provided to the Brownfields Program on June 12, 2017. During 2017, the quarterly methane monitoring was conducted in March, June, September, and December and included the collection of methane readings from four subsurface methane monitoring probes, ambient air methane readings from Building 1 and Building 2, and methane readings from sewer manholes and a drainage trench located in the vicinity of Building 2. In addition, during the December 2017 quarterly methane monitoring event, inspection and testing 4 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc of the methane warning system installed in the western portion of Building 2 was conducted. The western portion of Building 2 was occupied by JD Generators until December 2017. JD Generators has moved out and the western portion of Building 2 is currently vacant. Additionally, the current landowner elected to install methane vent wells within the footprint of the landfill and adjacent to the building to reduce the buildup of methane gas within the landfill, and reduce or eliminate the migration of such gas under the building slab. A work plan detailing the proposed installation of six methane vent wells was submitted to the Brownfields program on October 19, 2017 by Engineering Consulting Services (ECS). The work plan was approved by the Brownfields program on December 12, 2017 with the contingency of the installation of a seventh vent well in the southern end of the footprint of the landfill. In January 2018, ECS installed the methane vent wells at the site. Five methane vent wells were installed within the footprint of the landfill and two vent wells are were installed between the landfill and Building 2. Locations of the methane vent wells, labeled MVW-1 through MVW-7, are shown on Figure 2. 5 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc 3.0 Quarterly Methane Monitoring, Alarms, and Annual System Testing In accordance with the approved Design Plan, H&H conducted quarterly monitoring of methane probes MP-10R, MP-15, MP-16, and MP-17 in 2018, and collected ambient air methane readings from inside Building 1 and Building 2. Locations of the methane probes and ambient air samples are shown on Figure 2 and Figure 3, respectively. During each quarterly visit, the sanitary sewer manholes north of Building 2 and the drainage trench south of Building 2 were also screened for methane. Locations of the sewer manholes and drainage trench are shown on Figure 4. In addition, as part of the monitoring, unpaved and paved areas were inspected for the presence of settlement areas which could be locations of potential methane gas accumulation. Quarterly monitoring events were conducted on March 23, 2018, June 29, 2018, September 21, 2018, and December 26, 2018. Methane levels in the monitoring probes, indoor ambient air, sewer manholes, and drainage trench were collected utilizing a calibrated Landtec GEM 5000. Equipment calibration documents for the Landtec GEM 5000 are provided as Appendix A. The readings collected during monitoring included methane, carbon dioxide, and oxygen. Barometric pressure was also recorded with the GEM 5000 for each monitoring event. During the monitoring events, an in-line carbon filter was used. Prior to sampling, the carbon filter was conditioned with methane in accordance with the manufacturer’s specifications prior to monitoring. The annual methane warning system inspection and testing was performed on October 12, 2018 after an alarm notice from the warning system as discussed in Section 3.2. The inspection included verifying communication of the sensors to the central control panel, testing a representative number of sensors, and confirming that each sensor’s green “armed” light was illuminated at the time of the inspection. 3.1 Quarterly Methane Monitoring Results The results of methane monitoring conducted in March, June, September, and December 2018 indicated the presence of methane in MP-16 (ranging from 33.4% to 56.7%), MP-10R (ranging 6 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc from 10.8% to 16.6%), and MP-15 (ranging from 11.9% to 14.7%) above the most conservative methane screening level of 1.25% during each of the quarterly monitoring events. Methane was also detected in MP-17 (0.1%) during the December 2018 monitoring event, but the concentration detected was below the most conservative methane screening level of 1.25%. Methane was not detected (0.0%) in MP-17 during the other 2018 quarterly sampling events. In general, the methane concentrations detected were consistent with recent and previous methane monitoring events conducted at the site, and methane concentrations detected in the subsurface monitoring points appear to be generally stable since quarterly sampling began in March 2017. A summary of the methane probe readings is provided in Table 1. Methane was not detected inside either of the two buildings at the site during the quarterly methane monitoring events. In addition, methane was not detected in the sanitary sewer manholes or trench drain during the quarterly methane sampling events. The results of the site visual inspections did not indicate the presence of settlement areas at the site that could result in potential accumulation of methane gas. Results of indoor air methane monitoring conducted at the site are provided as Table 2 and depicted on Figure 3. Results of manhole and trench methane monitoring conducted at the site are summarized in Table 3 and depicted on Figure 4. As part of the quarterly methane monitoring activities in 2018, H&H also screened the exhaust of the methane vent wells (MVW-1 through MVW-7) utilizing the Landtec GEM 5000. The result of the screening did not indicate the presence of methane in the exhaust of the methane vent wells. 3.2 Methane Warning System Alarm and Inspection On October 12, 2018, H&H was notified of an alarm from the methane warning system. H&H mobilized to site and conducted methane screening in the western portion of Building 2 utilizing the Landtec GEM 5000. The result of the screening did not indicate the presence of methane. Following correspondence with the alarm company, it was determined that the alarm was likely triggered as a result of a power outage and the methane alarm was reset. 7 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc Following the methane warning system reset, the methane warning system was inspected by H&H in accordance with the Design Plan. The inspection included observing the alarm system panel for faults, testing a representative number of methane sensors, and ensuring that the green “armed” light was illuminated on each of the sensors. The result of the inspection and testing indicated that the methane warning system was functional and operated normally. 8 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc 4.0 Summary and Conclusions The results of the 2018 quarterly methane probe monitoring events indicated concentrations of methane in MP-16, MP-10R, and MP-15 above the most conservative methane screening level of 1.25%. Detected methane concentrations are consistent with recent previous methane monitoring events conducted at the site and appear to be generally stable. Methane was not detected in ambient air inside either of the two buildings at the site or the trench drain near Building 2 during the quarterly methane monitoring events. In addition, settlement areas where methane gas could potentially accumulate were not observed during the quarterly monitoring events. To date, methane has not been observed in ambient air in either of the two on-site buildings or potential receptors in the vicinity of the landfill area. However, as a precautionary measure, the current landowner elected to install seven methane gas vent wells to assist with the ventilation and reduce the potential for migration of methane gas within and around the landfill area. In January 2018, ECS installed the methane vent wells at the site. Based on the data collected following the installation of the methane vent wells, it does not appear that they have had a significant effect on reducing methane levels at the locations of the subsurface methane monitoring probes, although methane levels in the probes are stable. H&H responded to a methane warning system alarm on October 12, 2018, but it was determined that the alarm was likely activated due to a power outage. In addition, H&H confirmed that methane was not present in the building. During the October 12, 2018 visit, H&H also conducted a methane warning system inspection in accordance with the approved Design Plan. The inspection included observing the alarm system panel for faults, testing a representative number of methane sensors, and ensuring that the green “armed” light was illuminated on each of the sensors. The result of the inspection and testing indicated that the methane warning system was functional and operated normally. 9 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\DRAFT 2018 Annual Methane Monitoring Report.doc Based on the generally stable subsurface methane levels, no detections of methane in ambient indoor air in Building 1 or Building 2, and the presence of a methane warning system in Building 2, H&H recommends reducing the quarterly methane monitoring to a semi-annual monitoring basis beginning in 2019. It is anticipated that the semi-annual methane monitoring will be conducted in April and August of each year. The August semi-annual methane monitoring event will also include the annual system testing and inspection. Following the August monitoring event, an Annual Methane Monitoring Report will be provided to DEQ. The report will include the methods and results of the semi-annual methane monitoring and annual methane warning system inspection. TABLES Table 1 (Page 1 of 2) Methane Probe Monitoring Results Loftis-Blythe Construction Site (aka Innerloop North Industrial Park) 5600 David Cox Rd H&H Job No. HTZ-001 Ambient 0.1 0.0 20.5 79.2 Subsurface 0.2 1.7 18.9 79.0 Ambient 0.0 0.0 20.6 79.1 Subsurface 0.2 0.2 20.5 79.2 Ambient 0.1 0.0 20.6 79.1 Subsurface 0.1 5.8 13.5 80.4 Ambient 0.1 0.0 20.6 79.1 Subsurface 0.1 2.2 17.1 80.3 Ambient 0.1 0.0 20.5 79.1 Subsurface 0.1 1.1 19.4 79.3 Ambient 0.1 0.1 20.5 79.3 Subsurface 0.1 1.5 19.5 79.2 Ambient 0.1 0.0 20.6 79.2 Subsurface 1.6 6.9 11.2 80.1 Ambient 0.1 0.1 20.5 79.1 Subsurface 0.2 2.3 18.0 79.4 Ambient 0.1 0.2 20.4 79.2 Subsurface 0.1 3.6 18.3 77.9 Ambient 0.1 0.0 20.6 79.1 Subsurface 0.2 2.1 18.3 79.3 Ambient 0.1 0.0 20.5 79.3 Subsurface 0.1 1.2 18.1 80.4Ambient 0.0 0.6 21.4 78.0Subsurface0.0 6.8 2.8 90.0 Ambient 0.0 0.1 20.9 78.8Subsurface4.2 9.7 0.2 85.0 Ambient 0.1 0.8 22.1 77.0Subsurface11.6 13.1 0.9 74.4 Ambient 0.0 0.1 20.8 79.1Subsurface16.0 10.8 0.5 72.6 Ambient 0.0 0.2 20.5 79.3Subsurface14.9 11.2 0.9 73.0 Ambient 0.0 0.2 19.8 80.0Subsurface13.5 12.7 0.7 73.1 Ambient 0.0 0.3 20.1 77.8Subsurface15.5 11.5 0.0 73.0 Ambient 0.0 0.1 22.7 77.2Subsurface16.6 8.7 0.1 74.7 Ambient 0 0 20.5 79.4Subsurface13.6 9.5 0.7 76.1 Ambient 0.0 0 21.2 79.2Subsurface10.8 10.8 0.1 78.3 Ambient 0.0 0.1 21.8 78.1Subsurface14.2 11.8 0.5 73.5 Ambient 0.0 0.9 21.2 78.0 Subsurface 0.0 6.9 2.1 78.0 Ambient 0.0 0.2 20.7 79.1 Subsurface 2.6 11.1 0.6 83.9 Ambient 0.0 0.2 22.1 77.7 Subsurface 8.7 23.3 0.2 67.8 Ambient 0.0 0.1 21.4 78.5Subsurface12.4 23.1 0.8 63.4 Ambient 0.0 0.6 20.5 78.9Subsurface13.8 21.7 0.4 63.9 Ambient 0.0 0.2 19.5 80.3Subsurface13.1 24.3 0.2 62.4 Ambient 0.0 0.2 19.9 78.7Subsurface13.8 22.8 1.5 63.2 Ambient 0.0 0.1 23.6 76.3Subsurface14.5 19.2 0.3 66.0 Ambient 0.0 0.0 20.5 79.5Subsurface14.7 20.0 0.8 65.0 Ambient 0.0 0.1 20.2 79.6Subsurface12.5 22.5 0.2 64.8 Ambient 0.0 0.1 21.7 78.2Subsurface11.9 28.8 1.7 57.5 Perimeter MP-10R 12/26/18 Landfill 04/02/15 11/17/15 08/04/16 03/23/18 06/29/18 06/29/18 03/23/18 09/21/18 12/27/17 09/21/18 09/28/17 09/28/17 Landfill MP-14 07/17/13 Perimeter 04/02/15 Landfill MP-11 07/17/13 Perimeter MP-12 07/17/13 Perimeter BalancePercent (%) MP-1 07/17/13 Landfill Sampling Date Ambient/Subsurface Location (Landfill/Perimeter)Methane (CH4)Carbon dioxide (CO₂)Oxygen (O2)Landfill MP-8 07/17/13 Perimeter Well ID MP-2 07/17/13 Perimeter MP-6 07/17/13 Landfill 06/30/17 MP-9 07/17/13 MP-10 07/17/13 MP-13 07/17/13 11/17/15 MP-15 12/26/18 03/08/17 12/27/17 03/08/17 08/04/16 06/30/17 Perimeter MP-7 07/17/13 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\Tables\Methane point data table 12-26-181/4/2019 Table 1 (Page 1 of 2) Hart & Hickman, PC Table 1 (Page 2 of 2) Methane Probe Monitoring Results Loftis-Blythe Construction Site (aka Innerloop North Industrial Park) 5600 David Cox Rd H&H Job No. HTZ-001 BalancePercent (%)Sampling Date Ambient/Subsurface Location (Landfill/Perimeter)Methane (CH4)Carbon dioxide (CO₂)Oxygen (O2)Well ID Ambient 0.0 0.4 21.4 78.1 Subsurface 31.3 16.4 0.5 51.5 Ambient 0.0 0.1 20.9 79.0 Subsurface 34.6 14.7 0.4 48.9 Ambient 0.1 0.2 22.8 76.9 Subsurface 46.0 16.0 1.2 36.8 Ambient 0.0 0.1 20.4 79.5Subsurface36.2 22.0 0.3 41.5 Ambient 0.0 0.7 20.5 78.9Subsurface36.1 17.5 1.9 44.0 Ambient 0.0 0.3 19.4 80.3Subsurface40.3 20.5 0.2 39.5 Ambient 0.0 0.1 20.0 78.4Subsurface39.5 19.5 0.4 40.8 Ambient 0.0 0.2 22.7 77.2Subsurface33.4 16.8 0.2 49.6 Ambient 0.0 0.0 20.8 79.4Subsurface33.6 17.9 0.2 48.3 Ambient 0.0 0.0 20.9 79.0Subsurface35.6 17.2 0.2 47.0 Ambient 0.0 0.1 21.9 78.0Subsurface56.7 17.4 0.5 25.5 Ambient 0.0 1.8 14.6 83.7 Subsurface 0.0 0.3 21.5 78.2 Ambient 0.0 0.1 20.8 79.2 Subsurface 0.0 5.7 0.4 93.0 Ambient 0.0 0.4 22.1 77.5 Subsurface 0.4 12.2 0.1 87.3 Ambient 0.0 0.1 19.9 80.0Subsurface0.6 8.7 2.4 88.0 Ambient 0.0 0.2 20.6 79.2Subsurface0.1 10.6 0.1 89.2 Ambient 0.0 0.5 19.8 79.8Subsurface0.1 11.6 0.2 87.9 Ambient 0.0 0.2 20.6 79.2Subsurface0.2 9.3 0.4 89.9 Ambient 0.0 0.1 22.7 77.2Subsurface0.0 8.4 0.3 91.3 Ambient 0.0 0.0 20.6 79.3Subsurface0.0 9.4 0.3 90.2 Ambient 0.0 0.3 20.2 79.1Subsurface0.0 10.6 0.2 89.1 Ambient 0.0 0.0 21.4 78.5Subsurface0.1 11.7 0.8 87.5 <1.25 Notes Bold indicates concentration exceeds screening level. Screening level based upon DEQ Solid Waste Section regulations for facility structures of 25% LEL (1.25% methane). MP = Methane Probe Ambient Measurements were taken adjacent to MP locations immediatley prior to subsurface reading. Readings collected with a conditioned in-line charcoal filter. DEQ Soild Waste Section Sceening Level MP-17 Perimeter 12/26/18 MP-16 12/26/18 Landfill 06/29/18 06/29/18 03/23/18 12/27/17 03/08/17 09/21/18 09/21/18 12/27/17 06/30/17 04/02/15 03/23/18 04/02/15 11/17/15 08/04/16 09/28/17 03/08/17 11/17/15 08/04/16 06/30/17 09/28/17 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\Tables\Methane point data table 12-26-181/4/2019 Table 1 (Page 2 of 2) Hart & Hickman, PC Table 2 Indoor Methane Monitoring Results Loftis-Blythe Construction Site (aka Innerloop North Industrial Park) 5600 David Cox Rd H&H Job No. HTZ-001 8/4/2016 0.0 0.4 22.5 77.1 3/8/2017 0.0 0.2 21.0 78.8 6/30/2017 0.0 0.2 20.6 79.1 9/28/2017 0.0 0.2 19.7 80.1 12/27/2017 0.0 0.4 19.9 78.5 3/23/2018 0.0 0.1 23.0 76.9 6/29/2018 0.0 0.1 20.9 79.0 9/21/2018 0.0 0.1 20.9 79.0 12/26/2018 0.0 0.1 21.7 78.1 8/4/2016 0.0 0.1 22.8 77.1 3/8/2017 0.0 0.1 21.1 78.8 6/30/2017 0.0 0.2 20.8 79.1 9/28/2017 0.0 0.2 19.6 80.2 12/27/2017 0.0 0.3 19.9 78.6 3/23/2018 0.0 0.1 22.8 77.1 6/29/2018 0.0 0.0 21.0 79.0 9/21/2018 0.0 0.0 20.8 79.1 12/26/2018 0.0 0.0 21.8 78.2 8/4/2016 0.0 0.1 22.8 77.1 3/8/2017 0.0 0.1 21.1 78.8 6/30/2017 0.0 0.2 20.7 79.1 9/28/2017 0.0 0.2 19.9 79.9 12/27/2017 0.0 0.2 20.0 78.8 3/23/2018 0.0 0.1 22.7 77.2 6/29/2018 0.0 0.0 21.1 78.9 9/21/2018 0.0 0.0 20.6 79.3 12/26/2018 0.0 0.0 21.9 78.1 8/4/2016 0.0 0.1 22.7 77.2 3/8/2017 0.0 0.1 21.1 78.8 6/30/2017 0.0 0.2 20.9 78.9 9/28/2017 0.0 0.2 19.7 80.1 12/27/2017 0.0 0.3 19.8 78.7 3/23/2018 0.0 0.1 22.8 77.0 6/29/2018 0.0 0.0 21.0 79.0 9/21/2018 0.0 0.1 20.8 79.1 12/26/2018 0.0 0.1 21.7 78.2 8/4/2016 0.0 0.1 23.0 76.9 3/8/2017 0.0 0.1 21.3 78.6 6/30/2017 0.0 0.3 20.7 79.0 9/28/2017 0.0 0.2 19.9 79.9 12/27/2017 0.0 0.2 19.9 78.1 3/23/2018 0.0 0.1 22.6 77.3 6/29/2018 0.0 0.1 20.5 79.4 9/21/2018 0.0 0.1 20.9 79.0 12/26/2018 0.0 0.0 21.9 78.0 8/4/2016 0.0 0.1 22.9 77.0 3/8/2017 0.0 0.1 21.3 78.6 6/30/2017 0.0 0.2 20.8 79.0 9/28/2017 0.0 0.2 19.9 79.9 12/27/2017 0.0 0.2 19.9 78.1 3/23/2018 0.0 0.1 22.6 77.3 6/29/2018 0.0 0.0 20.5 79.4 9/21/2018 0.0 0.1 20.9 79.0 12/26/2018 0.0 0.0 21.9 78.0 8/4/2016 0.0 0.1 23.1 76.8 3/8/2017 0.0 0.1 21.2 78.7 6/30/2017 0.0 0.2 20.8 79.0 9/28/2017 0.0 0.2 20.0 79.9 12/27/2017 0.0 0.3 19.8 78.0 3/23/2018 0.0 0.1 22.6 77.3 6/29/2018 0.0 0.1 20.8 79.1 9/21/2018 0.0 0.1 20.6 79.3 12/26/2018 0.0 0.1 21.8 78.1 8/4/2016 0.0 0.1 23.2 76.7 3/8/2017 0.0 0.1 21.3 78.6 6/30/2017 0.0 0.2 20.9 78.9 9/28/2017 0.0 0.1 20.0 79.9 12/27/2017 0.0 0.2 19.9 78.1 3/23/2018 0.0 0.1 22.6 77.3 6/29/2018 0.0 0.0 20.8 79.2 9/21/2018 0.0 0.0 20.6 79.3 12/26/2018 0.0 0.0 22.0 78.0 DEQ Soild Waste Section Sceening Level <1.25 Notes Screening level based upon DEQ Solid Waste Section regulations for facility structures of 25% LEL (1.25% methane). Ambient Measurements were taken at breathing zone level from ground. AMB = ambient air Readings collected with a conditioned in-line charcoal filter. Building 1AMB-2 Building 1AMB-1 AMB-8 Building 2 AMB-7 Building 2 AMB-6 Building 2 Building 2AMB-5 Building 1AMB-4 Building 1AMB-3 BalanceMethane (CH4)Carbon dioxide (CO₂)Oxygen (O2)Well ID Sampling Date Location Percent (%) S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\Tables\Methane point data table 12-26-18 1/4/2019 Table 2 Hart & Hickman, PC Table 3 Manhole & Trench Methane Monitoring Results Loftis-Blythe Construction Site (aka Innerloop North Industrial Park) 5600 David Cox Rd H&H Job No. HTZ-001 Ambient 0.0 0.1 20.6 79.3 Subsurface 0.0 0.1 20.4 79.5 Ambient 0.0 0.1 19.6 80.3Subsurface0.0 0.1 19.7 80.2 Ambient 0.0 0.2 19.8 78.6Subsurface0.0 0.2 19.9 78.6 Ambient 0.0 0.1 19.6 80.3Subsurface0.0 0.1 19.7 80.2 Ambient 0.0 0.0 20.3 79.6 Subsurface 0.0 0.1 20.2 79.7 Ambient 0.0 0.0 20.3 79.5Subsurface0.0 0.1 20.2 79.5 Ambient 0.0 0.0 22.1 77.8Subsurface0.0 0.1 22.2 77.8 Ambient 0.0 0.1 20.2 79.7 Subsurface 0.0 0.1 20.0 79.9 Ambient 0.0 0.1 19.8 80.1Subsurface0.1 0.1 20.0 79.8 Ambient 0.0 0.1 20.0 78.4Subsurface0.0 0.2 19.9 78.5 Ambient 0.0 0.1 19.8 80.1Subsurface0.0 0.1 20.0 79.9 Ambient 0.0 0.1 20.3 79.6 Subsurface 0.0 0.0 20.3 79.5 Ambient 0.0 0.1 20.2 79.6Subsurface0.0 0.1 20.1 79.5 Ambient 0.0 0.0 22.1 77.8Subsurface0.0 0.1 22.1 77.9 Ambient 0.0 0.1 20.0 79.9 Subsurface 0.0 0.2 20.0 79.8 Ambient 0.1 0.1 20.1 79.7Subsurface0.1 0.1 20.2 79.6 Ambient 0.0 0.1 20.0 78.3Subsurface0.0 0.2 19.9 78.2 Ambient 0.0 0.1 19.8 80.1Subsurface0.0 0.1 20.0 79.8 Ambient 0.0 0.0 20.4 79.5 Subsurface 0.0 0.1 20.3 79.6 Ambient 0.0 0.1 20.2 79.5Subsurface0.0 0.1 20.1 79.5 Ambient 0.0 0.0 22.1 77.8Subsurface0.0 0.0 22.1 77.9Ambient0.0 0.2 20.8 79.0Subsurface0.0 0.1 20.8 79.0Ambient0.0 0.2 19.3 80.5Subsurface0.0 0.2 19.4 80.5Ambient0.0 0.2 19.8 77.9Subsurface0.0 0.1 20.0 78.2 Ambient 0.0 0.1 19.6 80.3Subsurface0.0 0.1 19.7 80.2 Ambient 0.0 0.1 20.4 79.5 Subsurface 0.0 0.0 20.4 79.5 Ambient 0.0 0.0 20.1 79.4Subsurface0.0 0.0 20.1 79.4 Ambient 0.0 0.0 21.9 78.0Subsurface0.0 0.0 22.1 77.8 DEQ Soild Waste Section Sceening Level <1.25 Notes Bold indicates concentration exceeds screening level. Screening level based upon DEQ Solid Waste Section regulations for facility structures of 25% LEL (1.25% methane). Ambient Measurements were taken adjacent to manhole/trench locations immediatley prior to subsurface reading. Readings collected with a conditioned in-line charcoal filter. 06/29/18 09/21/18 09/21/18 09/21/18 09/21/18 06/30/17 09/28/17 12/27/17 06/30/17 09/28/17 12/27/17 06/30/17 09/28/17 12/27/17 03/23/18 03/23/18 Well ID Sampling Date Ambient/Subsurface Percent (%)Methane (CH4)Carbon dioxide (CO₂)Oxygen (O2)BalanceTrench 12/26/18 Manhole-1 12/26/18 Manhole-2 12/26/18 Manhole-3 12/26/18 06/29/18 03/23/18 03/23/18 06/29/18 06/29/18 06/30/17 09/28/17 12/27/17 S:\AAA-Master Projects\Loftis-Blythe Brownfields site (HTZ)\Reports\Methane monitoring\2018 Annual Report\Tables\Methane point data table 12-26-18 1/4/2019 Table 3 Hart & Hickman, PC FIGURES 0 2000 4000 APPROXIMATE SCALE IN FEET N U.S.G.S. QUADRANGLE MAP QUADRANGLE7.5 MINUTE SERIES (TOPOGRAPHIC) TITLE PROJECT SITE LOCATION MAP LOFTIS-BLYTHE CONSTRUCTION SITE 5600 AND 5518 DAVID COX ROAD CHARLOTTE, NORTH CAROLINA DATE: JOB NO: REVISION NO: FIGURE: 01-26-18 0 1HTZ-001 SITE 2923 S. Tryon Street, Suite 100 Charlotte, NC 28203 704.586.0007(p) 704.586.0373(f)DERITA, NC 1996 MP-16 MP-15 DAVID C O X R O A D BUILDING 1 (5600 DAVID COX ROAD)OLD STATESVILLE ROADMP-17 MP-2 MP-14 MP-12 MP-10 MP-13 MP-7 MP-8 MP-9 MP-11 MP-6 MP-1 MP-10R PAVED AREA PAVED AREA BUILDING 2 (5518 DAVID COX ROAD) OFFICES OFFICES WAREHOUSE (VACANT) WAREHOUSE (TIRE WHOLESALES) OFFICES WAREHOUSE BATHROOMS WAREHOUSE MVW-6 MVW-7 MVW-5 MVW-4 MVW-3 MVW-8 MVW-2 MVW-1 LEGEND SITE PROPERTY BOUNDARY CHAINLINK FENCE APPROXIMATE EXTENT OF LANDFILL AREA PERMANENT METHANE PROBE LOCATION TEMPORARY METHANE PROBE LOCATION (JULY 2013) APPROXIMATE LOCATION OF METHANE VENT WELL (INSTALLED JANUARY 2018) DUKE POWER RIGHT-OF-WAY JOB NO. HTZ-001 REVISION NO. 0DATE: 1-4-19 FIGURE NO. 2 LOFTIS-BLYTHE CONSTRUCTION SITE 5600 DAVID COX ROAD CHARLOTTE, NORTH CAROLINA SUBSURFACE METHANE MONITORING PROBE LOCATION MAP NOTE: BOLD CONCENTRATION INDICATES EXCEEDANCE OF DEQ SOLID WASTE SECTION SCREENING LEVEL OF 1.25%. CONSTITUENT CONCENTRATION % METHANE PROBE ID MP-10R 4/2/15 11/17/15 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 METHANE 0.0 4.2 11.6 16.0 14.9 13.5 15.5 16.6 13.6 MP-15 4/2/15 11/17/15 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 2.6 8.7 12.4 13.8 13.1 13.8 14.5 14.2 12.5 11.9 MP-17 4/2/15 11/17/15 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.4 0.6 0.1 0.1 0.2 0.0 0.0 0.0 0.1 SAMPLE DATE PAVED AREA PAVED AREA PAVED AREA PAVED AREA PAVED AREA MP-10R 4/2/15 11/17/15 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 4.2 11.6 16.0 14.9 13.5 15.5 16.6 13.6 10.8 14.2 MP-16 4/2/15 11/17/15 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 31.3 34.6 46.0 36.2 36.1 40.3 39.5 33.4 33.6 35.6 56.7 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology MP-16 MP-15 DAVID C O X R O A D BUILDING 1 (5600 DAVID COX ROAD)OLD STATESVILLE ROADMP-17 MP-10R PAVED AREA PAVED AREA BUILDING 2 (5518 DAVID COX ROAD) OFFICES OFFICES WAREHOUSE (VACANT) WAREHOUSE (TIRE WHOLESALES) OFFICES WAREHOUSE BATHROOMS WAREHOUSE AMB-6 AMB-5 AMB-8 AMB-7 AMB-3 AMB-2 AMB-4 AMB-1 MVW-6 MVW-7 MVW-5 MVW-4 MVW-3 MVW-8 MVW-2 MVW-1 AMB-1 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 LEGEND SITE PROPERTY BOUNDARY CHAINLINK FENCE APPROXIMATE EXTENT OF LANDFILL AREA PERMANENT METHANE PROBE LOCATION AMBIENT AIR SAMPLE APPROXIMATE LOCATION OF METHANE VENT WELL DUKE POWER RIGHT-OF-WAY JOB NO. HTZ-001 REVISION NO. 0DATE: 1-4-19 FIGURE NO. 3 LOFTIS-BLYTHE CONSTRUCTION SITE 5600 DAVID COX ROAD CHARLOTTE, NORTH CAROLINA INDOOR METHANE MONITORING LOCATION MAP NOTE: BOLD CONCENTRATION INDICATES EXCEEDANCE OF DEQ SOLID WASTE SECTION SCREENING LEVEL. CONSTITUENT CONCENTRATION % METHANE PROBE ID SAMPLE DATE PAVED AREA PAVED AREA PAVED AREA AMB-1 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-2 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-3 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-4 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-5 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-6 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-8 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 AMB-7 8/4/16 3/8/17 6/30/17 9/28/17 12/27/17 3/23/18 6/29/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 0.0 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology MP-16 MP-15 MP-10R MANHOLE-2 MANHOLE-3 MANHOLE-1 TR E N C H - 1 MVW-7 MVW-8 MVW-2 BUILDING 2 (5518 DAVID COX ROAD) LEGEND SITE PROPERTY BOUNDARY DUKE POWER RIGHT-OF-WAY TRENCH DRAIN SANITARY SEWER MANHOLE PERMANENT METHANE PROBE LOCATION APPROXIMATE LOCATION OF METHANE VENT WELL JOB NO. HTZ-001 REVISION NO. 0DATE: 1-4-19 FIGURE NO. 4 LOFTIS-BLYTHE CONSTRUCTION SITE 5600 AND 5518 DAVID COX ROAD CHARLOTTE, NORTH CAROLINA MANHOLE & TRENCH SAMPLE LOCATION MAP PAVED AREA OFFICES OFFICES WAREHOUSE (VACANT) WAREHOUSE (TIRE WHOLESALES) 2923 South Tryon Street-Suite 100 Charlotte, North Carolina 28203 704-586-0007(p) 704-586-0373(f) License # C-1269 / #C-245 Geology CONSTITUENT CONCENTRATION % SAMPLE ID MANHOLE-2 6/30/17 9/28/17 12/27/17 3/25/18 6/26/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 SAMPLE DATE MANHOLE-2 6/30/17 9/28/17 12/27/17 3/25/18 6/26/18 9/21/18 12/26/18 METHANE 0.0 0.1 0.0 0.0 0.0 0.0 0.0 MANHOLE-3 6/30/17 9/28/17 12/27/17 3/25/18 6/26/18 9/21/18 12/26/18 METHANE 0.0 0.1 0.0 0.0 0.0 0.0 0.0 MANHOLE-1 6/30/17 9/28/17 12/27/17 3/23/18 6/26/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 TRENCH-1 6/30/17 9/28/17 12/27/17 3/25/18 6/26/18 9/21/18 12/26/18 METHANE 0.0 0.0 0.0 0.0 0.0 0.0 0.0 Appendix A Equipment Calibration Documents CALIBRATION LOG LANDTEC - GEM 5000+ Instrument: LANDTEC Serial Number: G502512 Calibrated materials required:Lot:KBH-341TSM-1 Lot:JBH-1-15 Exp:10/6/2021 Exp:10/6/2021 Lot:IBH-399-7 Lot:BBI-161-4-4 Exp:10/6/2021 Exp:2/9/2022 Lot:CBI-49-1000-2 Lot:CBI-98-200-1 Exp:02/09/2022 Exp:2/9/2020 . Carbon Filter Saturation (CH4) - Condition: PASS Gas Calibration Check Performed at Room Temperature GEM 5000+ (FRESH AIR CALIBRATION) SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)0.1 0.1 +/- 0.5% CO (ppm)0.0 0.0 +/- 5 ppm H2S (ppm)0.0 0.0 +/- 5 ppm H2 (%)-34.0 0 +/- 1.5% GEM 5000+ (MULTI SPAN GAS CALIBRATION) CH4 HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)48.8 50.0 +/- 0.5% C02 (%)35.1 35.0 +/- 1.5% O2 (%)0.1 0.0 +/- 1.5% 02 HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)11.9 10.0 +/- 0.5% C02 (%)11.5 10.0 +/- 1.5% O2 (%)0.0 0.0 +/- 1.5% 02 HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)19.7 20.9 +/- 0.5% 02 LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)4.1 4.0 +/- 0.5% CO CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CO (ppm)992 1000 +/- 50 ppm H2S CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments H2S (ppm)192 200 +/- 10 ppm Signature: lms Date: 3/23/2018 CALIBRATION LOG LANDTEC - GEM 5000+ ES # 1255 Instrument: LANDTEC Serial Number: G502512 Calibrated materials required:Lot:GBH-341TSM-1 Lot:FBI-161-4-1 Exp:6/27/2021 Exp:5/9/2022 Lot:KBH-49-1000-3 Lot:BBI-1-4 Exp:10/6/2021 Exp:2/9/2022 Lot:FBI-98-200-1 Lot:CBI-399-2 Exp:05/09/20 Exp:2/9/2022 . Carbon Filter Saturation (CH4) - Condition: PASS Gas Calibration Check Performed at Room Temperature GEM 5000+ (FRESH AIR CALIBRATION) SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)0.0 0.0 +/- 0.5% CO (ppm)0.0 0.0 +/- 5 ppm H2S (ppm)0.0 0.0 +/- 5 ppm H2 (%)-1.0 0 +/- 1.5% GEM 5000+ (MULTI SPAN GAS CALIBRATION) METHANE HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)41.5 50.0 +/- 0.5% C02 (%)28.9 35.0 +/- 1.5% O2 (%)0.2 0.0 +/- 1.5% METHANE LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)11.9 10.0 +/- 0.5% C02 (%)11.3 10.0 +/- 1.5% O2 (%)0.0 0.0 +/- 1.5% OXYGEN HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)20.7 20.9 +/- 0.5% OXYGEN LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)4.2 4.0 +/- 0.5% CARBON MONOXIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CO (ppm)992 1000 +/- 50 ppm HYDROGEN SULFIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments H2S (ppm)190 200 +/- 10 ppm Signature: RQA Date: 6/29/2018 METHANE LOWOXYGEN LOW CARBON MONOXIDEOXYGEN HIGH HYDROGEN SULFIDEMethane High CALIBRATION LOG LANDTEC - GEM 5000+ ES # 1255 Instrument: LANDTEC Serial Number: G502512 Calibrated materials required:Lot:GBI-341TSM-1 Lot:FBI-161-4-1 Exp:6/12/2022 Exp:5/9/2022 Lot:KBH-49-1000-3 Lot:BBI-1-4 Exp:10/6/2021 Exp:2/9/2022 Lot:GBI-98-200-1 Lot:EBI-399-6 Exp:06/12/20 Exp:5/9/2022 . Carbon Filter Saturation (CH4) - Condition: PASS Gas Calibration Check Performed at Room Temperature GEM 5000+ (FRESH AIR CALIBRATION) SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)0.0 0.0 +/- 0.5% CO (ppm)0.0 0.0 +/- 5 ppm H2S (ppm)0.0 0.0 +/- 5 ppm H2 (%)-0.7 0.0 +/- 1.5% GEM 5000+ (MULTI SPAN GAS CALIBRATION) METHANE HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)50.0 50.0 +/- 0.5% C02 (%)35.1 35.0 +/- 1.5% O2 (%)0.0 0.0 +/- 1.5% METHANE LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)9.3 10.0 +/- 0.5% C02 (%)9.7 10.0 +/- 1.5% O2 (%)-0.3 0.0 +/- 1.5% OXYGEN HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)20.1 20.9 +/- 0.5% OXYGEN LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)3.9 4.0 +/- 0.5% CARBON MONOXIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CO (ppm)955 1000 +/- 50 ppm HYDROGEN SULFIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments H2S (ppm)196 200 +/- 10 ppm Signature: RQA Date: 9/21/2018 METHANE LOWOXYGEN LOW CARBON MONOXIDEOXYGEN HIGH HYDROGEN SULFIDEMethane High CALIBRATION LOG LANDTEC - GEM 5000+ ES # 1255 Instrument: LANDTEC Serial Number: G502512 Calibrated materials required:Lot:CBI-341TSM-1 Lot:GBI-161-4-1 Exp:2/9/2022 Exp:6/12/2022 Lot:GBI-49-1000-4 Lot:EBI-1-8 Exp:6/12/2022 Exp:5/9/2022 Lot:GBI-98-200-1 Lot:KBI-399-1 Exp:06/12/20 Exp:10/10/2022 . Carbon Filter Saturation (CH4) - Condition: PASS Gas Calibration Check Performed at Room Temperature GEM 5000+ (FRESH AIR CALIBRATION) SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)0.0 0.0 +/- 0.5% CO (ppm)0.0 0.0 +/- 5 ppm H2S (ppm)0.0 0.0 +/- 5 ppm H2 (%)-0.2 0.0 +/- 1.5% GEM 5000+ (MULTI SPAN GAS CALIBRATION) METHANE HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)50.0 50.0 +/- 0.5% C02 (%)35.0 35.0 +/- 1.5% O2 (%)0.0 0.0 +/- 1.5% METHANE LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CH4 (%)10.0 10.0 +/- 0.5% C02 (%)10.0 10.0 +/- 1.5% O2 (%)0.0 0.0 +/- 1.5% OXYGEN HIGH CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)21.0 20.9 +/- 0.5% OXYGEN LOW CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments O2 (%)4.0 4.0 +/- 0.5% CARBON MONOXIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments CO (ppm)970 1000 +/- 50 ppm HYDROGEN SULFIDE CALIBRATION SENSOR Initial Reading CAL Reading Tolerance Comments H2S (ppm)198 200 +/- 10 ppm Signature: RQA Date: 12/26/2018 METHANE LOWOXYGEN LOW CARBON MONOXIDEOXYGEN HIGH HYDROGEN SULFIDEMethane High