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HomeMy WebLinkAbout21007_Hoke Street_VIR_20180108 VAPOR INTRUSION SOIL GAS SAMPLING REPORT PASSAGE HOME SITE 500 HOKE STREET, RALEIGH, NORTH CAROLINA RDHEC PROJECT NO. 1735.00 Prepared for: Aptus Management, PLLC 109 Amber Court Carrboro, NC 27510 Prepared by: RDH Environmental Consulting 4012 Ridgebrook Bluffs Drive Raleigh, North Carolina 27603 (919) 389-7747 January 8, 2018 4012 Ridgebrook Bluffs Dr. Raleigh, NC 27603 (919) 389-7747 info@rdhec.com January 8, 2018 John Gallagher Aptus Management, PLLC 109 Amber Court Carrboro, North Carolina 27510 Subject: VAPOR INTRUSION SOIL GAS SAMPLING REPORT PASSAGE HOME SITE – 500 HOKE STREET, RALEIGH, NORTH CAROLINA NCBF PROJECT NO: 21007-17-092 RDHEC PROJECT NO. 1735.00 Dear Mr. Gallagher: RDH Environmental Consulting (RDHEC) is pleased to provide the enclosed report for the vapor intrusion (VI) sampling that was conducted at the above-referenced site on October 17, 2017. The project was performed in accordance with the terms and conditions of RDHEC Proposal No. P1732 dated July 13, 2017, which was authorized by your email on July 17, 2017. The sampling was completed in general accordance with the work plan prepared by RDHEC on August 11, 2017, which was submitted via email by Aptus Management, PLLC (Aptus) to Sarah Hardison of the NCDEQ Brownfields Program on August 28, 2017. The work plan was revised on October 9, 2017, based on comments from Ms. Hardison on September 26, 2017, and approved on October 11, 2017. The findings from the sampling indicated minimal detections of various volatile organic compounds (VOCs) at each of the sampling locations except one analyte. Tetrachloroethylene (PCE) at the southwest building quadrant sample location (SS-3) was the only analyte detected at a concentration greater than the NC residential soil gas screening level (NCRSGSL). A risk assessment performed using the October 2017 NCDEQ’s Risk Calculator showed the cumulative risk from vapor intrusion acceptable. Moreover, the PCE concentration was well below the non- residential NCSGSL. Given that the building’s floor thickness was 6.5- to 8-inches thick and the site will employ a commercial grade heating, ventilating, and air conditioning (HVAC) system that increases air exchange rates compared to residential properties, the resulting attenuation should be greater than the conservative default values used to set the residential soil gas screening levels. Nevertheless, given the future use of the site may be a community center with children present, we recommend conducting indoor air quality testing to confirm that PCE is below acceptable guideline levels. TABLE OF CONTENTS 1.0 INTRODUCTION ...................................................................................................... 1 2.0 TESTING SUMMARY ................................................................................................ 1 3.0 SOIL GAS SAMPLING RESULTS .................................................................................. 3 4.0 RISK ASSESSMENT .................................................................................................. 4 5.0 CONCLUSIONS/RECOMMENDATIONS ...................................................................... 4 6.0 CLOSING ................................................................................................................ 5 TABLES Boring/Slab Details at Sampling Locations ..................................................................................... 2 Shut-In Test / Leak Check Details During Sampling ........................................................................ 3 Post-Sampling Leak Check Details .................................................................................................. 3 Table 1 - Laboratory Results from Sub-Slab Soil Gas Sampling on 10/17/2017 ............ Attachment DRAWINGS 1 Site Location Map 2 Facility Site Plan 3 Proposed Soil Gas Sampling Locations (From Work Plan) 4 Soil Gas Sampling Locations/Results APPENDICES Appendix A October 11, 2017 Approved Sampling Work Plan Appendix B Photographs Appendix C NCDWM Residential Vapor Intrusion Screening Levels Table (October 2017) Appendix D Laboratory Report and Chain of Custody Form Appendix E NCDEQ’s Risk Calculator Results 4012 Ridgebrook Bluffs Dr. Raleigh, NC 27603 (919) 389-7747 info@rdhec.com 1.0 INTRODUCTION Hoke Street PH Redevelopment LLC is pursuing a Brownfields Agreement (No. 21007-17-092) that will include use of the existing 14,500-square foot building as a new Passage Home property, located at 500 Hoke Street in Raleigh, NC (see Drawing 1 – Site Location Map and Drawing 2 – Facility Site Map, attached). Passage Home provides aid and human service assistance to local families in need. Consequently, the development is considered residential use due to the potential presence of children. Because of past industrial use of the building, the North Carolina Division of Environmental Quality (NCDEQ) Division of Waste Management (NCDWM) Brownfields Program requested that sub-slab soil gas sampling be performed to determine potential VI risk. This report summarizes the VI testing activities that were conducted in accordance with a Brownfields-approved work plan, as well as the laboratory results and conclusions. RDHEC conducted the vapor intrusion (VI) sampling on October 17, 2017. The testing involved collection of five (5) sub-slab soil gas canister samples from four quadrant locations across the building footprint. One of the locations, SS-1, included a duplicate sample, per the work plan and in accordance with DWM VI guidance1. The proposed soil gas sampling locations are shown in Drawing 3 from the work plan (a copy of the approved work plan is included in Appendix A). The actual sampling locations, with measurements and tabulated laboratory results for tetrachloroethylene (PCE), are provided in Drawing 4. Photographs from the day of the sampling are included in Appendix B. The NCDWM Residential Vapor Intrusion Screening Levels Table (October 2017) and Laboratory Report and Chain of Custody Form are provided in Appendices C and D, respectively. Printouts from the NCDEQ’s Risk Calculator Results, discussed later, are provided in Appendix E. 2.0 TESTING SUMMARY RDHEC arrived at the site at 1:00 pm on October 17, 2017. Upon entering the building, a measuring wheel was used to mark the locations on the slab where Vapor Pins® would be set as sampling probes and a TSI IAQ-Calc monitor was started to log temperature and relative humidity conditions during the sampling. The sample probes were placed in general accordance with the proposed locations shown in Drawing 3 from the work plan. Meteorological conditions during the sampling included clear and sunny skies with little to no winds. Temperatures during the testing ranged from 67.0 to 72.7 °F (average = 71.5 °F) and the relative humidity ranged from 32.7 to 53.9% (average = 48.4), as indicated by logs from the portable monitor. According to nearby weather stations, barometric pressure was steady, dropping slowly from 30.29 to 30.26 inches during the testing. A short rain event of approximately 0.22 to 0.25 inches 1 NCDEQ DWM VAPOR INTRUSION GUIDANCE document dated April 2014, page 30. Vapor Intrusion Soil Gas Sampling Report January 8, 2018 Passage Home Site – 500 Hoke Street Page 2 Raleigh, North Carolina occurred nearby (6 blocks to the north of the site) 24 hours prior to testing on October 16th. Prior to that, a 0.6-inch rain occurred on October 11th.Thus, there was no significant precipitation within 12 hours prior to (or during) the sampling event to induce pressure gradients that might affect soil vapor intrusion. A hammer drill was used to create 5/8-inch diameter borings at the each of the four sample locations. Details regarding each boring are noted in the table below. Boring/Slab Details at Sampling Locations Sample Location SS-1 SS-2 SS-3 SS-4 Boring Depth 9.5” 11.5” 9” 10.25” Sub-Slab Thickness 6.5” 7” 7.5” 8” Sub-Slab Conditions Hard-packed soil/clay, no stone or gravel fill beneath Hard-packed soil/clay, no stone or gravel fill beneath Hard-packed soil/clay, no stone or gravel fill beneath Hard-packed soil/clay, no stone or gravel fill beneath Vapor Pins® fitted with silicone sleeves were secured into each boring using a special tool and rubber hammer. Per the work plan, the probe locations were allowed to equilibrate for at least 20 minutes prior to connecting the sampling trains. The samples were collected using 1/4-inch rigid Teflon tubing and 400-mL Summa canisters. Small 1- to 2-inch pieces of 1/4-inch and 3/8- inch silicone tubing were employed to make connections to various valves and fittings of the sampling trains. Tubing was connected to the barbed fitting of the Vapor Pins, routed through a plastic shroud (which was placed over the probe site) and the other end connected to a 3-way valve and 60-milliliter (mL) syringe to form a sampling train for each sample location. The SS-1 sample location employed an inline tee to collect a duplicate sample for quality assurance purposes, in accordance with Brownfields Program guidance, for a total of five (5) soil gas samples/analyses. Shut-in tests were performed to ensure air tight conditions at each location. Per the work plan, once the sampling train was deemed leak-free, the probe tubing was purged of three dead volumes using a 60-mL syringe and leak checked while the shroud was filled with helium. With 1.5 feet of 1/4-Inch tubing (inner diameter of 0.177 inches), three dead volumes equaled 22 mL. (Note – approximately 120 mLs were purged to allow for sufficient volume for the helium leak checks, described below). The helium concentrations within the shroud were measured and noted using a MGD-2002 leak detector. The purged soil gas was collected into a 0.5-L Tedlar bag. After purging, the Tedlar bag was removed and the contents monitored for helium levels. A successful leak check was deemed when the purged soil gas contains less than 5% of the initial shroud concentration of helium. Each Vapor Intrusion Soil Gas Sampling Report January 8, 2018 Passage Home Site – 500 Hoke Street Page 3 Raleigh, North Carolina of the purged helium concentrations were 0 ppm, therefore leak-free conditions were achieved and no adjustments were necessary. Shut-In Test / Helium (He) Leak Check Details During Sampling Sample Location SS-1 SS-2 SS-3 SS-4 Maintained Shut-In Vacuum (5-Min Duration) -21” Hg -22” Hg -17” Hg -17” Hg Shroud He Concentration (%/ppm) 48.6% / 486,000 ppm 42.6% / 426,000 ppm 36.8% / 368,000 ppm 51.1% / 511,000 ppm Purge He Concentration (ppm) 0 ppm 0 ppm 0 ppm 0 ppm Each of soil gas samples was collected using 400-mL canisters fitted with 200 ml/min flow regulators over a period of approximately two minutes. Following completion of the sampling, post-sampling leak checks were performed again at each location using helium. After a successful post-sampling leak check, the probe tubing and Vapor Pins® were removed from each location and the borings were grouted flush to the slab foundation with cement. Post-Sampling Leak Check Details Sample Location SS-1 SS-2 SS-3 SS-4 Shroud He Concentration (%/ppm) 30.1% / 301,000 ppm 29.5% / 295,000 ppm 25.9% 259,000 ppm 48.0% 480,000 ppm Purge He Concentration (ppm) 0 ppm 0 ppm 0 ppm 0 ppm The laboratory analysis request forms were then completed for laboratory analysis using EPA Compendium Method TO-15 "Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially-Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry (GC/MS)" and the canisters were placed back in the laboratory packaging for return shipment. Since post-sampling leak checks were conducted, helium analysis by the laboratory was not required. The samples were then shipped to the lab under proper chain of custody. For this project, the full TO-15 analyte list was requested. 3.0 SOIL GAS SAMPLING RESULTS The results of the EPA Method TO-15 laboratory analyses were compared to the NCDEQ’s October 2017 list of Residential Vapor Intrusion Soil Gas Screening Levels (NCRSGSLs, attached in Appendix C) upon receipt of the laboratory report (Appendix D). Sample SS-3, located at the southwest quadrant of the building, exhibited the only detected analyte (PCE) at a concentration above a NCRSGSL. The remaining analytes among the five samples were each found to be well below their respective residential soil gas screening level (ranging from 0.01% to 34.29% of the NCRSGSLs, and averaging only 2.63% of the NCRSGSLs). The results for all Vapor Intrusion Soil Gas Sampling Report January 8, 2018 Passage Home Site – 500 Hoke Street Page 4 Raleigh, North Carolina detected analytes are provided in Table 1 (attached) and those of PCE are included on Drawing 4 for quick reference. Note also that further details are available in the original lab Electronic Data Deliverables (EDD) file in Excel spreadsheet format was attached to the email containing this report and should be included with the submittal to the Brownfields Program. 4.0 RISK ASSESSMENT Since PCE was the sole analyte with a detection above a screening level and the concentration was less than 10-times the NCRSGSL, a risk assessment was performed using the NCDEQ’s Risk Calculator (October 2017 version). The highest concentration of each detected analyte amongst the five samples was input to the model. Based on the risk calculator results, the cumulative carcinogenic risk was 4.7E-6 and the cumulative hazard index was 0.6 for residential receptors. Comparatively, for non-residential/commercial receptors, the cumulative carcinogenic risk was 3.6E-7 and the cumulative hazard index was 0.048. This shows that an unacceptable risk from vapor intrusion is unlikely. Printouts from the Risk Calculator are provided in Appendix E. 5.0 CONCLUSIONS/RECOMMENDATIONS The findings from this VI sampling study identified several low-level detections of petroleum and chlorinated hydrocarbons at the site. Except for PCE at the southeast quadrant of the building, however, the levels were well below the conservative VI screening levels for residential properties. A risk assessment using the highest levels of detected contaminants indicates that it is unlikely that the soil gas levels would result in unacceptable risks or exceedances of indoor air quality guidelines. Given that the building foundation slab was determined to be 1.6 to 2.0 times thicker than typical (4-inch) residential and commercial slabs, the floor should provide a good barrier to attenuate migration of VI to the indoors. Additionally, it was noted that the sub-slab is comprised of hard- packed clay rather than stone/gravel fill. This condition would provide additional barriers to VI to the indoors from the soil due to limiting the migration of soil gas beneath the slab. Lastly, the building is a commercial structure with corresponding HVAC systems that should provide greater fresh air exchange for occupants, further reducing the risk of VI at the site. In summary, comparison of the soil gas testing results with current NCDWM guidance indicate that there is not likely to be an unacceptable risk of vapor intrusion at the proposed Passage Home building. Nevertheless, given the future use of the site may be a community center with children present, we recommend conducting indoor air testing to confirm that PCE levels are below acceptable guideline levels. Vapor Intrusion Soil Gas Sampling Report January 8, 2018 Passage Home Site – 500 Hoke Street Page 5 Raleigh, North Carolina 6.0 CLOSING Thank you for allowing RDHEC to be of assistance with your vapor intrusion testing needs. If you should have questions regarding this submittal or associated documentation, please feel free to contact us at (919) 389-7747 at your convenience. Sincerely, RDH ENVIRONMENTAL CONSULTING Robert D. Hill, PE Principal Consulting Engineer Attachments TABLES SS-1 SS-1 (Dup)SS-2 SS-3 SS-4 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05 THQ=0.2 SS-1 SS-1 (Dup)SS-2 SS-3 SS-4 (Oct 2017) Acetone 97 98 2.20E+05 0.04%0.04% 2-Butanone (MEK)12 13 8.9 6.9 15 3.50E+04 0.03%0.04%0.03%0.02%0.04% Carbon Tetrachloride 11 1.60E+02 6.88% Chloroform 3.1 4.10E+01 7.56% Cyclohexane 6.2 8.5 72 4.20E+04 0.01%0.02%0.17% Ethanol 43 45 64 94 130 NA --------------- Ethyl Acetate 2.9 4.90E+02 0.59% Ethylbenzene 3.1 5.5 7.3 9.1 3.70E+02 0.84%1.49%1.97%2.46% 4-Ethyltoluene 2.3 3 3.8 NA --------- Heptane 3.8 3.3 9.4 13 200 2.80E+03 0.14%0.12%0.34%0.46%7.14% Hexane 11 11 28 40 470 4.90E+03 0.22%0.22%0.57%0.82%9.59% 2-Hexanone (MBK)72 2.10E+02 34.29% Isopropanol 2.1 3.1 3.8 1.40E+03 0.15%0.22%0.27% Naphthalene 3.7 2.10E+01 17.62% Propene 6.8 7.1 5.8 5.9 4.6 NA --------------- Tetrachloroethylene 36 26 24 590 16 2.80E+02 12.86%9.29%8.57%210.71%5.71% Tetrahydrofuran 1.6 2.6 1.40E+04 0.01%0.02% Toluene 7.9 6.3 12 17 24 3.50E+04 0.02%0.02%0.03%0.05%0.07% 1,1,1-Trichloroethane 12 3.50E+04 0.03% Trichlorofluoromethane (Freon 11)3.8 NA --- 1,2,4-Trimethylbenzene 6.5 5.3 7.1 9.4 11 4.20E+02 1.55%1.26%1.69%2.24%2.62% 1,3,5-Trimethylbenzene 4.1 2.3 3.5 4.20E+02 0.98%0.55%0.83% m&p-Xylene 13 10 20 27 36 7.00E+02 1.86%1.43%2.86%3.86%5.14% o-Xylene 4.3 3.8 7.1 9.5 13 7.00E+02 0.61%0.54%1.01%1.36%1.86% Notes:Detections Greater Than NC Residential Soil Gas Screening Level (NCRSGSL) Are Shown In Bold TABLE 1 - 10/17/2017 SUB-SLAB SOIL GAS TESTING RESULTS PASSAGE HOME SITE - 500 HOKE STREET, RALEIGH, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER: 21007-17-092 % of NCRSGSL Analyte RDHEC PROJECT NUMBER: 1719.00 Lab Results (ug/m3) DRAWINGS APPENDIX A OCTOBER 11, 2017 APPROVED SAMPLING WORK PLAN Aptus Management, PLLC Environmental Management Solutions Aptus Management, PLLC 109 Amber Court Carrboro, NC 27510 October 9, 2017 Sarah Hardison Young VIA EMAIL: sarah.hardison@ncdenr.gov Brownfields Project Manager NC Division of Waste Management 217 W Jones St. Raleigh, NC 27603-6100 SUBJECT: VAPOR INTRUSION SUB-SLAB SOIL GAS TESTING – WORK PLAN PASSAGE HOME SITE – RALEIGH, NORTH CAROLINA BROWNFIELDS PROJECT NUMBER: 21007-17-092 Dear Ms. Young: Aptus Management, LLC (Aptus) is pleased to provide this revised work plan for vapor intrusion (VI) testing at the Passage Home site located at 500 Hoke Street in Raleigh (see Figure 1 below). This work plan addresses only the vapor intrusion assessment comments for the existing building noted in your additional assessment letter dated June 27, 2017. This update incorporates your September 26, 2017 comments to the original work plan dated August 28, 2017. The objectives are to evaluate potential risks due to vapor intrusion, and to support our redevelopment planning. Figure 1. Site Location Map – Passage Home Site, 500, 506 Hoke Street 1412 Garner Road – Raleigh, NC (Source: Wake County GIS). BACKGROUND INFORMATION Hoke Street PH Redevelopment LLC is pursuing a Brownfields Agreement (No. 21007-17-092). A site location map is provided in Drawing 1. The site is comprised of the following three parcels (see Site Map in Drawing 2): Vapor Intrusion Soil Gas Testing Work Plan October 9, 2017 Passage Home Site - Raleigh, North Carolina Aptus Management, PLLC Page 2  500 Hoke Street (Parcel 1703828886)  506 Hoke Street (Parcel 1703920846)  1412 Garner Road (Parcel 1703920658) Due the past industrial use of the on-site building, including waste handling operations by a company called Nyetech which leased the property in 2003/2004, and known groundwater pollution conditions in the vicinity, you requested that we evaluate potential risks due to vapor intrusion (VI). In your letter dated June 27, 2017, you requested a minimum of four (4) sub-slab soil gas samples within the existing building. The adaptive reuse of the building is our current focus and redevelopment of the remainder of the property will be considered later. Therefore, the proposed VI testing is for only the building, and not the balance of the site. SAMPLING WORK PLAN Aptus proposes to collect four (4) sub-slab soil gas samples within the on-site building as shown in Drawing 3. The sampling locations will follow the suggested approach you outlined in the June 27 letter. The actual locations will be determined in the field based on visual observations, locations of walls, doors, flooring conditions, etc. The work will be conducted in accordance with guidance1. Two of the samples will be collected in the western portion of the building where we believe Nyetech stored waste materials near the outside loading dock as shown in the highlighted area in the figure below. Figure 2. Probable 10-Day Storage Area Locations within Site Building, 500 Hoke Street – Raleigh, NC (Source: 1972 Sanborn Map). 1 “Vapor Intrusion Guidance”, NCDENR, Division of Waste Management, Brownfields Program, April 2014. Vapor Intrusion Soil Gas Testing Work Plan October 9, 2017 Passage Home Site - Raleigh, North Carolina Aptus Management, PLLC Page 3 The third sampling location will be in the northeastern part of the building near the former fuel dispenser pad. Lastly, the fourth sample will be located at the southeast area of the building to provide assessment of the remaining quadrant. Sample Collection  Aptus will collect sub-slab soil gas samples from four (4) locations identified as SS-1 through SS-4.  One location (SS-1) will employ an inline tee to collect a duplicate sample for quality assurance purposes for a total of five (5) soil gas samples/analyses.  A hammer drill will be used to bore 5/8-inch diameter holes through the slab to the soil beneath (approximately 1-foot depth). The hole will be cleaned with a small bristle brush and vacuumed of residual dust with a shop vac. The thickness of the slab and the depth to and nature of fill media under the slab will be noted. Vapor Pins® fitted with silicone sleeves will be secured into each boring using a special tool and rubber hammer.  Each Vapor Pin location will be allowed to equilibrate for at least 20 minutes.  The samples will be collected using ¼-inch rigid Teflon tubing and 400-ml Summa canisters, per the attached H&P Sampling Guide: Collecting Soil Vapor into Summa Canisters (see Attachment 1). Small 1- to 2-inch pieces of 1/4" and 3/8" Tygon tubing will be employed to make connections to various valves and fittings of the sampling trains. Tubing will be connected to the barbed fitting of the Vapor Pins and a 3-way valve and 60- milliliter (mL) syringe to form a sampling train for each sample location. Dedicated tubing, fittings, and syringes will be utilized for each sampling point.  The probe tubing will be connected to the sampling train and a shut-in test will be performed to ensure air tight conditions per the Sampling Guide. Subsequently, once the sampling train is deemed leak-free, the probe tubing will be purged of three dead volumes using a 60-ml syringe and leak checked using helium in accordance with the Soil Vapor Sampling Using Shroud Method of Leak Detection in Attachment 2. Assuming 1.5 feet of ¼-inch tubing (inner diameter of 0.177 inches), three dead volumes equals 22 mL. (Note - up to 60 mLs may be purged to ensure sufficient volume for the helium leak check, described below). The actual purge volume will be calculated to account for the probe tubing length, sample train and the thickness of the slab. Shut in tests and leak checks of the sampling trains and probes will be performed at each sample location.  The helium concentration within the shroud will be measured using a MGD-2002 leak detector (or equivalent monitor). The purged soil gas will be collected into a 0.5-L Tedlar bag. After purging, the Tedlar bag will be removed and the contents monitored for helium levels. A successful leak check is deemed when the purged soil gas contains less than 5% of the initial shroud concentration of helium. If helium concentrations exceed 5% in the purged soil gas, adjustments will be made to achieve leak-free conditions and/or a new Vapor Pin location will be installed and tested.  If no leaks are detected, the canister sampling can begin at each of the sample locations.  Each of soil gas samples will be collected using canisters fitted with 100 – 200 ml/min flow regulators over a period of between two to four minutes.  A post-sampling leak check will be performed using helium. After a successful post- sampling leak check, the probe tubing and Vapor Pins will be removed from each location and the borings will be grouted flush to the slab foundation level with cement.  Laboratory analysis request forms will be prepared and the samples shipped under proper chain of custody for analysis using EPA Compendium Method TO-15 “Determination of Volatile Organic Compounds (VOCs) in Air Collected in Specially- Prepared Canisters and Analyzed by Gas Chromatography/Mass Spectrometry Vapor Intrusion Soil Gas Testing Work Plan October 9, 2017 Passage Home Site - Raleigh, North Carolina Aptus Management, PLLC Page 4 (GC/MS)”. (Note – when conducting a post-sampling leak check, helium analysis by the laboratory is not required.) The lab will be contacted ahead of time to ensure that reporting limits will be below applicable residential screening levels. The chain of custody/sample analysis forms will Include vacuum readings (initial and final) during testing and the lab will report the received vacuum on the form. Sampling will be stopped when a residual vacuum of 3 to 5 inches of mercury (Hg) is reached for each canister (i.e., sampling will be monitored closely to ensure that final vacuum does not reach 0 inches of Hg.) REPORTING Upon receipt of the laboratory results, the concentrations will be compared to the Division of Waste Management’s (DWM’s) residential soil gas screening levels (RSGSLs). A written report will be prepared summarizing our field activities, observations, laboratory results, conclusions and recommendations. The field readings for the shut in test, helium leak check and helium readings, and vacuum readings will be included. The findings and conclusions will be used to develop the recommendations regarding the risk of vapor intrusion. CLOSING If you have questions regarding this submittal or associated documentation, please feel free to contact us at (919) 522-7289 at your convenience. Sincerely, APTUS MANAGEMENT, PLLC John Gallagher, PE Robert D. Hill, PE Engineer of Record Principal Consulting Engineer Attachments Aptus Management, PLLC DRAWINGS SITE SITE PARCEL /PROPERTY BOUNDARYADJACENT PARCEL /PROPERTY BOUNDARIESLEGENDFORMERASHLANDCHEMICALFACILITYAUTO REPAIRSERVICEFACILITYSITE - EXISTING BUILDING(500 HOKE STREET) SS-1SUB-SLAB SOIL GASSAMPLE LOCATIONPARCEL / PROPERTYBOUNDARIESLEGENDPOSSIBLE FUELDISPENSER PADAREASOUTHWEST BUILDINGSAMPLE LOCATION(NEAR FORMER ASHLANDCHEMICAL SITE & POSSIBLE10-DAY STORAGE AREA)4TH SAMPLELOCATION(PLACEMENTPROVIDESCHARACTERIZATIONOF REMAININGSLAB AREA) Aptus Management, PLLC ATTACHMENT 1 H&P SAMPLING GUIDE: COLLECTING SOIL VAPOR INTO SUMMA CANISTERS d'T) Mobile Geochemistry Inc. 2470 Impala Drive, Carlsbad, CA 92010 Field Office in Signal Hill, CA Ph: 800-834-9888 www.handpmg.com Rev3, August 2014 SAMPLING GUIDE A: Collecting Soil Vapor into Summa Canisters Recommended Tools/Supplies > Scissors/Snips to cut tubing > Nitrile Gloves > Ball Point Pen > If using a Liquid Leak Check Compound: > 1,1-Difluoroethane "duster spray" or Isopropyl Alcohol > Cloth Towel(s) > Resealable plastic bag Sample Parts/Supplies Provided (Pic 1) These Items are sent 1 per sample (not including duplicate or back up Summa): > A-400 mL Summa Canister w/ male quick connect {may be substituted with 1 L Summa Canister) > B - Sample Kit (vacuum gauge, female quick connect, 100-200 or 50 mL/min flow restrictor, 1/4" barb) > C - Male Luer with 3/8" Tygon tubing connector > D-3-way valve These Items are sent 1 per project: > E - Consumables Bag (which contains): > D-3-way valves (2) > F - 60 mL plastic syringes (2) > G-1/4" Tygon tubing > H- 3/8" Tygon tubing > I-Cable Ties Picture 1 Mobile Geochemistry Inc. 2470 Impala Drive, Carlsbad, OA 92010 Field Office in Signal Hill, OA Ph: 800-834-9888 www.handpmg.com Rev3, August 2014 Connecting the Sample Train to the Soil Vapor Probe 1. 2. 3. 4. 5. Attach a 3-way valve (D) onto the vapor probe 1-way valve by twisting male luer fitting on 3-way valve into female luer fitting on valve. (See Pic 2) Note: If you ore not connecting to H&P's standard soil vapor probe 1-way valve, you will need to make the proper tubing connections to attach the 3-way valve onto the valve connection on the probe. It is highly recommended that the soil vapor probe be equipped with a termination valve in order to conduct a proper shut-in test which will be discussed later. Attach a separate 3-way valve onto plastic purge syringe and then twist male luer end of 3-way valve Into female luer end on the 3- way valve attached to the vapor probe. (See Pic 3) Attach a male luer fitting with 3/8" Tygon tubing connector (C) to 1/4" barb on inlet port of Sample Kit (B). (See Pic 4) Twist male luer fitting on Sample Kit into side port of 3-way valve attached to the sample probe valve. (See Pic 5) Attach Summa Canister to Sample Kit by using the quick connect fittings. Pull back collar on female quick connect attached to Sample Kit, and insert male quick connect on Summa. (See Pic 6) Pi Picture 2 cture Picture 4 -KCiW-Picture 5 Picture 6 d^T) Mobile Geochemistry Inc. Conducting a Shut-In Test 2470 Impala Drive. Carlsbad, CA 92010 Field Office in Signal Hill. CA Ph: 800-834-9888 www.handpmg.com Rev3, August 2014 1. 2. 3. 4. 5. The 1-way valve on the soil vapor probe should be in the Off position. Turn the 3-way valve attached to the 1-way valve so that It is Off in the direction pointing away from all ports on the valve. {See Pic 7) With the 3-way valve attached to the purge syringe turned so that the side port is closed, pull back on the plunger so that you draw a vacuum on all the fittings through to the Summa Canister. The vacuum gauge should now be reading vacuum pressure. Once the needle on the vacuum gauge reaches a vacuum of greater than 10" Hg, immediately turn the 3- way valve on the syringe so that it is Off towards the probe valves. (See Pic 8) Observe the vacuum gauge for at least 1 minute to determine if there is any vacuum loss. If the needle drops, indicating a leak in the sample train, retlghten all fittings and conduct shut-in test again. Note: The vacuum gauge reads in inches of Mercury. 7.4" Hg is equal to 100" H20. You should maintain a vacuum of at least 100" H20 (or 7 -8" Hg) when conducting the shut-in test. Picture 7 Turn 3-way valve so that it is Off in the direction pointing away from ail ports. Turn valve on the soil vapor probe to the Off position. Picture Apply vacuum until vacuum gauge reaches 10" Hg or more, then turn 3-way valve on syringe Off towards the vapor probe. lliP Mobilen Geochemistry Inc. Applying a Liquid Leak Check Compound 1. Be sure to have on Nitrile gloves. 2. Place towel in resealable plastic bag. 3. Carefully spray or pour liquid leak check compound onto towel in bag. Do not oversaturate towel with compound. Note: liquid leak compounds typically used are 1,1-Difluoroethane (duster spray), or Isopropyl Alcohol. 4. Seal up plastic bag. 5. Just prior to purging and sampling of the probe, gently place one saturated towel at the base of the soil vapor probe where the tubing enters the subsurface. Lay another towel near all of the sample train connections. Do not lay towel directly on fittings. (See Pic 9) 6. Discard Nitrile gloves, as compounds can be quite strong, and put on new pair prior to purging and sampling to prevent any cross contamination. 2470lmpaia Drive, Carlsbad, CA 92010 Field Office in Signal Hill, CA Ph: 800-834-9888 www.handpmg.com Rev3, August 2014 Picture 9 Purging Soil Vapor Probes 1. 2, 3. 4. 5. Determine the proper purge volume to be evacuated from the soil vapor probe (e.g. 3 dead volumes). Turn the 3-way valve connected to the probe valve so that it is Off towards the Sample Kit and Summa Canister. Note: There should still be a vacuum from the 3-way valve to the Summa Canister. This vacuum pressure should remain until Summa is to be sampled. Open the valve on the probe. (See Pic 10) Using the syringe to purge, slowly draw out the vapor by pulling back on the plunger to fill syringe. Then expel the purge air by turning the 3-way valve so it is Off towards the probe, and pushing the plunger In. Repeat this process until the desired purge volume is evacuated from the probe. Note: For larger purge volumes, inquire about H&P's Balkenbox purge pump. To maintain a flow rate of less than 200 ml/min, it should take approximately 20 seconds to pull back the plunger a full 60 mL. Picture 10 Valve Off toward Sample Kit and SummaOpen vapor probe valve Vapor Flow 11.?Mobile Geochemistry Inc. Collecting the Summa Canister Sample 2470 Impala Drive, Carlsbad, CA 92010 Field Office in Signal Hill, CA Ph; 800-834-9888 www.handpmg.com Rev3, August 2014 1. After purging has been completed, turn the 3-way valve attached to the On/Off probe valve so that it is Off towards the purge syringe. (See Pic 11) 2. The needle on the Sample Kit vacuum gauge should drop Indicating that the Sample Kit is filling with sample air from the probe. 3. Open the valve on the Summa Canister. 4. The needle on the Sample Kit will rise back up and show the initial vacuum of the Summa Canister. 5. Record starting time and the starting vacuum of Summa Canister. 6. The needle will slowly drop as the Summa Canister fills with the sample vapor. This should take 3-4 minutes to fill a 400 ml size Summa Canister at a flow rate of 100-200 mL/min. If using a slower flow rate, such as 50 mL/min, it should take 8-10 minutes to fill. 7. Allow the canister to completely fill and the needle to reach 0"Hg. 8. Close valve on Summa Canister and disconnect. Record sample end time and ending vacuum of the Summa Canister. 9. Label the Summa with the appropriate sample information. 10. Record sample on the Chain of Custody. Picture 11 Valve Off toward purge syringe Disconnecting Sample Train 1. Disconnect all fittings. 2. Because all sampling is done prior to the purge syringe and the attached 3-way valve, they may be reused for other samples. 3. All other fittings, adaptors, and valves should not be reused in the collection of other samples. Mobile Geochennistry Inc. 2470 Impala Drive, Carlsbad, OA 92010 Field Office in Signal Hill, CA Ph: 800-834-9888 www.handpmg.com RevS, August 2014 Collection Notes > If water is observed in the sample tubing, stop coilection Immediately. If you suspect that water may have entered the Summa Canister, make a note on the sample label and Chain of Custody. > Twist luer fittings into each other so that all valves and gauges are facing up. This may take some practice. > At the standard flow rate of 100 - 200 mL/mIn, each 400 mL Summa Canister should fill in 3 to 5 minutes depending upon soil permeability. If the Summa is not filled within 5 minutes, make note of the vacuum reading. Allow the Summa to fill for another 5 minutes. If it is not filled after 10 minutes, make a note of the vacuum reading and stop collection. > If using all Summa Canister, the canister should fill In 5 to 8 minutes at a flow rate of 100 - 200 mL/min. > Label samples with a ballpoint pen. DO NOT USE SHARPIE! > After sampling, return Summa Canister and Sample Kit back into same box they were shipped in. Please do not write on shipping boxes. > You do not need to return any of the consumable items (i.e. syringes, valves, tubing). > Keep Summa Canisters out of sun and do not chill. Keep at room temperature. > Wash hands or remove gloves between samples to ensure the leak/tracer compound is not on your fingers when connecting fittings. Aptus Management, PLLC ATTACHMENT 2 H&P SOIL VAPOR SAMPLING USING SHROUD METHOD OF LEAK DETECTION H&P Mobile Geochemistry, Inc. 2470 Impala Drive, Carlsbad, CA 92010 Ph. 760-804-9678 www.handpmg.com Soil Vapor Sampling using Shroud Method of Leak Detection Placing a plastic shroud over a soil vapor sampling probe and introducing a gaseous compound, such as helium, into the shroud can be implemented to ensure the probe seal integrity. It may also be used to assess the potential for leaks in the sample train. A plastic shroud is placed over the soil vapor probe location with the tubing of the probe exiting the shroud through a small hole. The valve on the probe termination is connected to the sampling apparatus that is to be used. Smaller purge volumes may only require a syringe to purge, while larger purge volumes may require a sample pump with flow meter and vacuum gauge. A “shut in” test is performed to check for leaks in all sample fittings and connections not contained within shroud. This is achieved by shutting the valve at the probe termination to the off position, then applying a vacuum to all connections between the valve and the sample container (i.e. syringe or summa canister). An in-line vacuum gauge is used to observe any loss in vacuum over a period of time (i.e. 60 seconds), which would indicate a leak in the system. Helium (or other compound) is released into the shroud and a hand held helium detector is used to monitor and maintain a reasonably steady concentration of approximately 50% helium in the shroud. Once the concentration is reached, the soil vapor probe is purged at the recommended flow rate and any probe vacuum is recorded. A Tedlar bag is then collected from the probe by connecting to the exhaust port of the purge syringe to fill, or by using a Tedlar lung box. The contents of the Tedlar bag are then screened with the Helium detector. If the concentration in the bag is ≤10% of the Helium concentration in the shroud, sampling is continued. If Helium concentration in the Tedlar bag is >10% of the shroud concentration, the sampling is stopped and efforts to improve or replace the probe are made. The soil vapor sample is then collected in the appropriate sample container (i.e. syringe or summa canister). Once the sample is taken, a final reading of the shroud concentration is measured with the meter and recorded. APPENDIX B PHOTOGRAPHS Creating boring at SS-3 location Slab thickness at SS-3 location (7.5”) Creating boring at SS-1 location Creating boring at SS-4 location Creating boring at SS-2 location Boring depth at SS-4 location (10.25”) Slab thickness at SS-4 location (8”) Vapor Pin placement at SS-4 location Slab thickness at SS-2 location (7”) Boring depth at SS-2 location (11.5”) Canister sampling - SS-3 location Shut-in test - SS-3 location Helium shroud leak check at SS-3 location Shroud helium level during leak check - SS-3 location Purge volume helium level – SS-3 location Post-sampling shroud helium concentration - SS-3 location Post-sampling purge volume helium level - SS-3 location Purge volume helium level – SS-3 location Duplicate canister sampling - SS-1 location Shut-in test - SS-1 location Shroud helium level during leak check - SS-1 location Post-sampling purge volume helium level - SS-1 location Sample collection - SS-1 location Shut-in test - SS-2 location Shroud helium level during leak check - SS-2 location Purge volume helium level – SS-2 location Canister sampling - SS-2 location Shut-in test - SS-4 location Shroud helium level during leak check - SS-4 location Purge volume helium level – SS-4 location Post-sampling purge volume helium level - SS-4 location Post-sampling purge volume helium level - SS-4 location APPENDIX C NCDWM RESIDENTIAL VAPOR INTRUSION SCREENING LEVELS TABLE (OCTOBER 2017) CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 30560-19-1 Acephate75-07-0 Acetaldehyde 6.9E+02 6.3E+01 N 1.3E+00 C 1.9E+00 N 1.9E+00 N Yes 34256-82-1 Acetochlor 67-64-1 Acetone 4.5E+06 2.2E+05 N 6.5E+03 N 6.5E+03 N 6.5E+03 N Yes 75-86-5 Acetone Cyanohydrin Not Volatile Not Volatile 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes 75-05-8 Acetonitrile 8.9E+03 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes 98-86-2 Acetophenone 53-96-3 Acetylaminofluorene, 2- Not Volatile Not Volatile 2.2E-03 C 2.2E-02 C 2.2E-01 C107-02-8 Acrolein 8.4E-01 1.4E-01 N 4.2E-03 N 4.2E-03 N 4.2E-03 N Yes79-06-1 Acrylamide Not Volatile Not Volatile 1.0E-02 C 1.0E-01 C 1.0E+00 C Yes 79-10-7 Acrylic Acid 1.4E+04 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 107-13-1 Acrylonitrile 7.3E+01 1.4E+01 C 4.1E-02 C 4.1E-01 C 4.2E-01 N Yes 111-69-3 Adiponitrile Not Volatile Not Volatile 1.3E+00 N 1.3E+00 N 1.3E+00 N Yes 15972-60-8 Alachlor 116-06-3 Aldicarb 1646-88-4 Aldicarb Sulfone1646-87-3 Aldicarb sulfoxide309-00-2 Aldrin 3.2E+00 1.9E-01 C 5.7E-04 C 5.7E-03 C 5.7E-02 C 107-18-6 Allyl Alcohol 1.0E+02 7.0E-01 N 2.1E-02 N 2.1E-02 N 2.1E-02 N Yes 107-05-1 Allyl Chloride 4.6E-01 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 7429-90-5 Aluminum Not Volatile Not Volatile 1.0E+00 N 1.0E+00 N 1.0E+00 N Yes 20859-73-8 Aluminum Phosphide 834-12-8 Ametryn 92-67-1 Aminobiphenyl, 4- Not Volatile Not Volatile 4.7E-04 C 4.7E-03 C 4.7E-02 C 591-27-5 Aminophenol, m-95-55-6 Aminophenol, o-123-30-8 Aminophenol, p- 33089-61-1 Amitraz 7664-41-7 Ammonia 1.6E+05 3.5E+03 N 1.0E+02 N 1.0E+02 N 1.0E+02 N Yes 7773-06-0 Ammonium Sulfamate 75-85-4 Amyl Alcohol, tert- 1.1E+03 2.1E+01 N 6.3E-01 N 6.3E-01 N 6.3E-01 N Yes 62-53-3 Aniline Not Volatile Not Volatile 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 84-65-1 Anthraquinone, 9,10-7440-36-0 Antimony (metallic)1314-60-9 Antimony Pentoxide 1332-81-6 Antimony Tetroxide 1309-64-4 Antimony Trioxide Not Volatile Not Volatile 4.2E-02 N 4.2E-02 N 4.2E-02 N Yes 7440-38-2 Arsenic, Inorganic Not Volatile Not Volatile 6.5E-04 C 3.1E-03 N 3.1E-03 N Yes 7784-42-1 Arsine Not Volatile Not Volatile 1.0E-02 N 1.0E-02 N 1.0E-02 N Yes 3337-71-1 Asulam 1912-24-9 Atrazine492-80-8 Auramine Not Volatile Not Volatile 1.1E-02 C 1.1E-01 C 1.1E+00 C65195-55-3 Avermectin B1 86-50-0 Azinphos-methyl Not Volatile Not Volatile 2.1E+00 N 2.1E+00 N 2.1E+00 N Yes 103-33-3 Azobenzene 1.6E+03 3.0E+01 C 9.1E-02 C 9.1E-01 C 9.1E+00 C 123-77-3 Azodicarbonamide Not Volatile Not Volatile 1.5E-03 N 1.5E-03 N 1.5E-03 N Yes 7440-39-3 Barium Not Volatile Not Volatile 1.0E-01 N 1.0E-01 N 1.0E-01 N Yes 10294-40-3 Barium Chromate Not Volatile Not Volatile 6.8E-06 C 6.8E-05 C 6.8E-04 C Yes 1861-40-1 Benfluralin 17804-35-2 Benomyl83055-99-6 Bensulfuron-methyl25057-89-0 Bentazon 100-52-7 Benzaldehyde 71-43-2 Benzene 1.6E+01 1.2E+02 C 3.6E-01 C 3.6E+00 C 6.3E+00 N Yes 6369-59-1 Benzenediamine-2-methyl sulfate, 1,4- 108-98-5 Benzenethiol 92-87-5 Benzidine Not Volatile Not Volatile 1.5E-05 C 1.5E-04 C 1.5E-03 C 65-85-0 Benzoic Acid98-07-7 Benzotrichloride100-51-6 Benzyl Alcohol North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) Page 1 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 100-44-7 Benzyl Chloride 1.2E+01 7.0E+00 N 5.7E-02 C 2.1E-01 N 2.1E-01 N Yes7440-41-7 Beryllium and compounds Not Volatile Not Volatile 1.2E-03 C 4.2E-03 N 4.2E-03 N Yes 42576-02-3 Bifenox 82657-04-3 Biphenthrin 92-52-4 Biphenyl, 1,1'- 6.6E+00 2.8E+00 N 8.3E-02 N 8.3E-02 N 8.3E-02 N Yes 108-60-1 Bis(2-chloro-1-methylethyl) ether 111-91-1 Bis(2-chloroethoxy)methane 111-44-4 Bis(2-chloroethyl)ether 1.2E+02 2.8E+00 C 8.5E-03 C 8.5E-02 C 8.5E-01 C542-88-1 Bis(chloromethyl)ether 2.5E-03 1.5E-02 C 4.5E-05 C 4.5E-04 C 4.5E-03 C80-05-7 Bisphenol A 7440-42-8 Boron And Borates Only Not Volatile Not Volatile 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 10294-34-5 Boron Trichloride 5.6E+00 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 7637-07-2 Boron Trifluoride 9.0E+01 N 2.7E+00 N 2.7E+00 N 2.7E+00 N Yes 15541-45-4 Bromate 107-04-0 Bromo-2-chloroethane, 1- 1.3E+00 1.6E+00 C 4.7E-03 C 4.7E-02 C 4.7E-01 C 108-86-1 Bromobenzene 1.2E+02 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes74-97-5 Bromochloromethane 1.4E+02 2.8E+02 N 8.3E+00 N 8.3E+00 N 8.3E+00 N Yes75-27-4 Bromodichloromethane 8.8E+00 2.5E+01 C 7.6E-02 C 7.6E-01 C 7.6E+00 C 75-25-2 Bromoform 1.2E+03 8.5E+02 C 2.6E+00 C 2.6E+01 C 2.6E+02 C 74-83-9 Bromomethane 3.5E+00 3.5E+01 N 1.0E+00 N 1.0E+00 N 1.0E+00 N Yes 2104-96-3 Bromophos 1689-84-5 Bromoxynil 1689-99-2 Bromoxynil Octanoate 106-99-0 Butadiene, 1,3- 1.4E-01 1.4E+01 N 9.4E-02 C 4.2E-01 N 4.2E-01 N Yes 94-82-6 Butanoic acid, 4-(2,4-dichlorophenoxy)-71-36-3 Butanol, N-78-92-2 Butyl alcohol, sec- 1.7E+07 2.1E+05 N 6.3E+03 N 6.3E+03 N 6.3E+03 N Yes 2008-41-5 Butylate 25013-16-5 Butylated hydroxyanisole Not Volatile Not Volatile 4.9E+01 C 4.9E+02 C 4.9E+03 C 128-37-0 Butylated hydroxytoluene 104-51-8 Butylbenzene, n- 135-98-8 Butylbenzene, sec- 98-06-6 Butylbenzene, tert-75-60-5 Cacodylic Acid7440-43-9 Cadmium (Diet) Not Volatile Not Volatile 1.6E-03 C 2.1E-03 N 2.1E-03 N Yes 7440-43-9 Cadmium (Water) Not Volatile Not Volatile 1.6E-03 C 2.1E-03 N 2.1E-03 N Yes 13765-19-0 Calcium Chromate Not Volatile Not Volatile 6.8E-06 C 6.8E-05 C 6.8E-04 C Yes 105-60-2 Caprolactam Not Volatile Not Volatile 4.6E-01 N 4.6E-01 N 4.6E-01 N Yes 2425-06-1 Captafol Not Volatile Not Volatile 6.5E-02 C 6.5E-01 C 6.5E+00 C 133-06-2 Captan Not Volatile Not Volatile 4.3E+00 C 4.3E+01 C 4.3E+02 C 63-25-2 Carbaryl1563-66-2 Carbofuran75-15-0 Carbon Disulfide 2.5E+02 4.9E+03 N 1.5E+02 N 1.5E+02 N 1.5E+02 N Yes 56-23-5 Carbon Tetrachloride 4.1E+00 1.6E+02 C 4.7E-01 C 4.7E+00 C 2.1E+01 N Yes 463-58-1 Carbonyl Sulfide 8.4E-01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 55285-14-8 Carbosulfan 5234-68-4 Carboxin 1306-38-3 Ceric oxide Not Volatile Not Volatile 1.9E-01 N 1.9E-01 N 1.9E-01 N Yes 302-17-0 Chloral Hydrate 133-90-4 Chloramben118-75-2 Chloranil12789-03-6 Chlordane 7.3E+01 4.9E+00 N 2.8E-02 C 1.5E-01 N 1.5E-01 N Yes 143-50-0 Chlordecone (Kepone) Not Volatile Not Volatile 6.1E-04 C 6.1E-03 C 6.1E-02 C 470-90-6 Chlorfenvinphos 90982-32-4 Chlorimuron, Ethyl- 7782-50-5 Chlorine 6.5E-02 1.0E+00 N 3.1E-02 N 3.1E-02 N 3.1E-02 N Yes 10049-04-4 Chlorine Dioxide 2.5E-02 1.4E+00 N 4.2E-02 N 4.2E-02 N 4.2E-02 N Yes 7758-19-2 Chlorite (Sodium Salt)75-68-3 Chloro-1,1-difluoroethane, 1- 4.3E+03 3.5E+05 N 1.0E+04 N 1.0E+04 N 1.0E+04 N Yes126-99-8 Chloro-1,3-butadiene, 2- 4.1E-02 3.1E+00 C 9.4E-03 C 9.4E-02 C 9.4E-01 C Yes Page 2 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 3165-93-3 Chloro-2-methylaniline HCl, 4-95-69-2 Chloro-2-methylaniline, 4- Not Volatile Not Volatile 3.6E-02 C 3.6E-01 C 3.6E+00 C 107-20-0 Chloroacetaldehyde, 2- 79-11-8 Chloroacetic Acid 532-27-4 Chloroacetophenone, 2- Not Volatile Not Volatile 6.3E-03 N 6.3E-03 N 6.3E-03 N Yes 106-47-8 Chloroaniline, p- 108-90-7 Chlorobenzene 8.2E+01 3.5E+02 N 1.0E+01 N 1.0E+01 N 1.0E+01 N Yes 98-66-8 Chlorobenzene sulfonic acid, p-510-15-6 Chlorobenzilate Not Volatile Not Volatile 9.1E-02 C 9.1E-01 C 9.1E+00 C74-11-3 Chlorobenzoic Acid, p- 98-56-6 Chlorobenzotrifluoride, 4- 4.4E+01 2.1E+03 N 6.3E+01 N 6.3E+01 N 6.3E+01 N Yes 109-69-3 Chlorobutane, 1- 75-45-6 Chlorodifluoromethane 6.3E+03 3.5E+05 N 1.0E+04 N 1.0E+04 N 1.0E+04 N Yes 107-07-3 Chloroethanol, 2- 67-66-3 Chloroform 8.1E+00 4.1E+01 C 1.2E-01 C 1.2E+00 C 1.2E+01 C Yes 74-87-3 Chloromethane 5.2E+01 6.3E+02 N 1.9E+01 N 1.9E+01 N 1.9E+01 N Yes107-30-2 Chloromethyl Methyl Ether 3.3E+00 1.4E+00 C 4.1E-03 C 4.1E-02 C 4.1E-01 C88-73-3 Chloronitrobenzene, o- Not Volatile Not Volatile 2.1E-03 N 2.1E-03 N 2.1E-03 N Yes 100-00-5 Chloronitrobenzene, p- Not Volatile Not Volatile 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes 95-57-8 Chlorophenol, 2- 76-06-2 Chloropicrin 1.0E+00 2.8E+00 N 8.3E-02 N 8.3E-02 N 8.3E-02 N Yes 1897-45-6 Chlorothalonil Not Volatile Not Volatile 3.2E+00 C 3.2E+01 C 3.2E+02 C 95-49-8 Chlorotoluene, o- 106-43-4 Chlorotoluene, p- 54749-90-5 Chlorozotocin Not Volatile Not Volatile 4.1E-05 C 4.1E-04 C 4.1E-03 C101-21-3 Chlorpropham2921-88-2 Chlorpyrifos 5598-13-0 Chlorpyrifos Methyl 64902-72-3 Chlorsulfuron 1861-32-1 Chlorthal-dimethyl 60238-56-4 Chlorthiophos 16065-83-1 Chromium(III), Insoluble Salts 18540-29-9 Chromium(VI) Not Volatile Not Volatile 1.2E-05 C 1.2E-04 C 1.2E-03 C Yes7440-47-3 Chromium, Total74115-24-5 Clofentezine 7440-48-4 Cobalt Not Volatile Not Volatile 3.1E-04 C 1.3E-03 N 1.3E-03 N Yes 8007-45-2 Coke Oven Emissions 3.6E-02 5.5E-01 C 1.6E-03 C 1.6E-02 C 1.6E-01 C 7440-50-8 Copper 108-39-4 Cresol, m- Not Volatile Not Volatile 1.3E+02 N 1.3E+02 N 1.3E+02 N Yes 95-48-7 Cresol, o- Not Volatile Not Volatile 1.3E+02 N 1.3E+02 N 1.3E+02 N Yes 106-44-5 Cresol, p- Not Volatile Not Volatile 1.3E+02 N 1.3E+02 N 1.3E+02 N Yes59-50-7 Cresol, p-chloro-m-1319-77-3 Cresols Not Volatile Not Volatile 1.3E+02 N 1.3E+02 N 1.3E+02 N Yes 123-73-9 Crotonaldehyde, trans- 98-82-8 Cumene 1.8E+02 2.8E+03 N 8.3E+01 N 8.3E+01 N 8.3E+01 N Yes 135-20-6 Cupferron Not Volatile Not Volatile 4.5E-02 C 4.5E-01 C 4.5E+00 C 21725-46-2 Cyanazine Cyanides 592-01-8 ~Calcium Cyanide 544-92-3 ~Copper Cyanide57-12-5 ~Cyanide (CN-) 4.0E+01 5.6E+00 N 1.7E-01 N 1.7E-01 N 1.7E-01 N Yes460-19-5 ~Cyanogen 506-68-3 ~Cyanogen Bromide 506-77-4 ~Cyanogen Chloride 74-90-8 ~Hydrogen Cyanide 3.1E+01 5.6E+00 N 1.7E-01 N 1.7E-01 N 1.7E-01 N Yes 151-50-8 ~Potassium Cyanide 506-61-6 ~Potassium Silver Cyanide 506-64-9 ~Silver Cyanide143-33-9 ~Sodium CyanideE1790664 ~Thiocyanates Page 3 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 463-56-9 ~Thiocyanic Acid557-21-1 ~Zinc Cyanide 110-82-7 Cyclohexane 2.0E+02 4.2E+04 N 1.3E+03 N 1.3E+03 N 1.3E+03 N Yes 87-84-3 Cyclohexane, 1,2,3,4,5-pentabromo-6- chloro- 108-94-1 Cyclohexanone 4.0E+05 4.9E+03 N 1.5E+02 N 1.5E+02 N 1.5E+02 N Yes 110-83-8 Cyclohexene 1.1E+02 7.0E+03 N 2.1E+02 N 2.1E+02 N 2.1E+02 N Yes108-91-8 Cyclohexylamine68359-37-5 Cyfluthrin 68085-85-8 Cyhalothrin 52315-07-8 Cypermethrin 66215-27-8 Cyromazine 72-54-8 DDD Not Volatile Not Volatile 4.1E-02 C 4.1E-01 C 4.1E+00 C 72-55-9 DDE, p,p'- 1.7E+02 9.6E+00 C 2.9E-02 C 2.9E-01 C 2.9E+00 C 50-29-3 DDT Not Volatile Not Volatile 2.9E-02 C 2.9E-01 C 2.9E+00 C75-99-0 Dalapon1596-84-5 Daminozide Not Volatile Not Volatile 5.5E-01 C 5.5E+00 C 5.5E+01 C 1163-19-5 Decabromodiphenyl ether, 2,2',3,3',4,4',5,5',6,6'- (BDE-209) 8065-48-3 Demeton 103-23-1 Di(2-ethylhexyl)adipate 2303-16-4 Diallate 333-41-5 Diazinon132-65-0 Dibenzothiophene96-12-8 Dibromo-3-chloropropane, 1,2- 2.8E-01 5.6E-02 C 1.7E-04 C 1.7E-03 C 1.7E-02 C Yes 108-36-1 Dibromobenzene, 1,3- 106-37-6 Dibromobenzene, 1,4- 124-48-1 Dibromochloromethane 106-93-4 Dibromoethane, 1,2- 1.8E+00 1.6E+00 C 4.7E-03 C 4.7E-02 C 4.7E-01 C Yes 74-95-3 Dibromomethane (Methylene Bromide) 2.5E+01 2.8E+01 N 8.3E-01 N 8.3E-01 N 8.3E-01 N Yes E1790660 Dibutyltin Compounds1918-00-9 Dicamba764-41-0 Dichloro-2-butene, 1,4- 1.9E-02 2.2E-01 C 6.7E-04 C 6.7E-03 C 6.7E-02 C 1476-11-5 Dichloro-2-butene, cis-1,4- 2.5E-01 2.2E-01 C 6.7E-04 C 6.7E-03 C 6.7E-02 C 110-57-6 Dichloro-2-butene, trans-1,4- 2.5E-01 2.2E-01 C 6.7E-04 C 6.7E-03 C 6.7E-02 C 79-43-6 Dichloroacetic Acid 95-50-1 Dichlorobenzene, 1,2- 5.3E+02 1.4E+03 N 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 106-46-7 Dichlorobenzene, 1,4- 2.6E+01 8.5E+01 C 2.6E-01 C 2.6E+00 C 2.6E+01 C Yes 91-94-1 Dichlorobenzidine, 3,3'- Not Volatile Not Volatile 8.3E-03 C 8.3E-02 C 8.3E-01 C90-98-2 Dichlorobenzophenone, 4,4'-75-71-8 Dichlorodifluoromethane 1.5E+00 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 75-34-3 Dichloroethane, 1,1- 7.6E+01 5.8E+02 C 1.8E+00 C 1.8E+01 C 1.8E+02 C 107-06-2 Dichloroethane, 1,2- 2.2E+01 3.6E+01 C 1.1E-01 C 1.1E+00 C 1.5E+00 N Yes 75-35-4 Dichloroethylene, 1,1- 3.9E+01 1.4E+03 N 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 156-59-2 Dichloroethylene, 1,2-cis- 156-60-5 Dichloroethylene, 1,2-trans- 120-83-2 Dichlorophenol, 2,4- 94-75-7 Dichlorophenoxy Acetic Acid, 2,4-78-87-5 Dichloropropane, 1,2- 6.6E+00 2.5E+01 C 7.6E-02 C 7.6E-01 C 8.3E-01 N Yes142-28-9 Dichloropropane, 1,3- 616-23-9 Dichloropropanol, 2,3- 542-75-6 Dichloropropene, 1,3- 2.9E+01 1.4E+02 N 7.0E-01 C 4.2E+00 N 4.2E+00 N Yes 62-73-7 Dichlorvos Not Volatile Not Volatile 3.4E-02 C 1.0E-01 N 1.0E-01 N Yes 141-66-2 Dicrotophos 77-73-6 Dicyclopentadiene 2.4E-02 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 60-57-1 Dieldrin Not Volatile Not Volatile 6.1E-04 C 6.1E-03 C 6.1E-02 CE17136615 Diesel Engine Exhaust Not Volatile Not Volatile 9.4E-03 C 9.4E-02 C 9.4E-01 C Yes111-42-2 Diethanolamine Not Volatile Not Volatile 4.2E-02 N 4.2E-02 N 4.2E-02 N Yes 112-34-5 Diethylene Glycol Monobutyl Ether Not Volatile Not Volatile 2.1E-02 N 2.1E-02 N 2.1E-02 N Yes 111-90-0 Diethylene Glycol Monoethyl Ether Not Volatile Not Volatile 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes Page 4 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 617-84-5 Diethylformamide56-53-1 Diethylstilbestrol Not Volatile Not Volatile 2.8E-05 C 2.8E-04 C 2.8E-03 C 43222-48-6 Difenzoquat 35367-38-5 Diflubenzuron 75-37-6 Difluoroethane, 1,1- 1.0E+04 2.8E+05 N 8.3E+03 N 8.3E+03 N 8.3E+03 N Yes 94-58-6 Dihydrosafrole 4.3E+03 7.2E+01 C 2.2E-01 C 2.2E+00 C 2.2E+01 C 108-20-3 Diisopropyl Ether 1.4E+03 4.9E+03 N 1.5E+02 N 1.5E+02 N 1.5E+02 N Yes 1445-75-6 Diisopropyl Methylphosphonate55290-64-7 Dimethipin60-51-5 Dimethoate 119-90-4 Dimethoxybenzidine, 3,3'- 756-79-6 Dimethyl methylphosphonate 60-11-7 Dimethylamino azobenzene [p-] Not Volatile Not Volatile 2.2E-03 C 2.2E-02 C 2.2E-01 C 21436-96-4 Dimethylaniline HCl, 2,4- 95-68-1 Dimethylaniline, 2,4- 121-69-7 Dimethylaniline, N,N-119-93-7 Dimethylbenzidine, 3,3'-68-12-2 Dimethylformamide 2.1E+06 2.1E+02 N 6.3E+00 N 6.3E+00 N 6.3E+00 N Yes 57-14-7 Dimethylhydrazine, 1,1- 7.9E-01 1.4E-02 N 4.2E-04 N 4.2E-04 N 4.2E-04 N Yes 540-73-8 Dimethylhydrazine, 1,2- 6.2E+01 5.8E-03 C 1.8E-05 C 1.8E-04 C 1.8E-03 C 105-67-9 Dimethylphenol, 2,4- 576-26-1 Dimethylphenol, 2,6- 95-65-8 Dimethylphenol, 3,4- 513-37-1 Dimethylvinylchloride 4.5E+01 7.2E+01 C 2.2E-01 C 2.2E+00 C 2.2E+01 C 534-52-1 Dinitro-o-cresol, 4,6-131-89-5 Dinitro-o-cyclohexyl Phenol, 4,6-528-29-0 Dinitrobenzene, 1,2- 99-65-0 Dinitrobenzene, 1,3- 100-25-4 Dinitrobenzene, 1,4- 51-28-5 Dinitrophenol, 2,4- E1615210 Dinitrotoluene Mixture, 2,4/2,6- 121-14-2 Dinitrotoluene, 2,4- Not Volatile Not Volatile 3.2E-02 C 3.2E-01 C 3.2E+00 C 606-20-2 Dinitrotoluene, 2,6-35572-78-2 Dinitrotoluene, 2-Amino-4,6-19406-51-0 Dinitrotoluene, 4-Amino-2,6- 25321-14-6 Dinitrotoluene, Technical grade 88-85-7 Dinoseb 123-91-1 Dioxane, 1,4- 2.9E+04 1.9E+02 C 5.6E-01 C 5.6E+00 C 6.3E+00 N Yes Dioxins NA ~Hexachlorodibenzo-p-dioxin, Mixture Not Volatile Not Volatile 2.2E-06 C 2.2E-05 C 2.2E-04 C 1746-01-6 ~TCDD, 2,3,7,8- 3.6E-04 2.5E-05 C 7.4E-08 C 7.4E-07 C 7.4E-06 C Yes957-51-7 Diphenamid127-63-9 Diphenyl Sulfone 122-39-4 Diphenylamine 122-66-7 Diphenylhydrazine, 1,2- Not Volatile Not Volatile 1.3E-02 C 1.3E-01 C 1.3E+00 C 85-00-7 Diquat 1937-37-7 Direct Black 38 Not Volatile Not Volatile 2.0E-05 C 2.0E-04 C 2.0E-03 C 2602-46-2 Direct Blue 6 Not Volatile Not Volatile 2.0E-05 C 2.0E-04 C 2.0E-03 C 16071-86-6 Direct Brown 95 Not Volatile Not Volatile 2.0E-05 C 2.0E-04 C 2.0E-03 C 298-04-4 Disulfoton505-29-3 Dithiane, 1,4-330-54-1 Diuron 2439-10-3 Dodine 759-94-4 EPTC 115-29-7 Endosulfan 145-73-3 Endothall 72-20-8 Endrin 106-89-8 Epichlorohydrin 1.7E+02 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes106-88-7 Epoxybutane, 1,2- 5.7E+02 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes111-77-3 Ethanol, 2-(2-methoxyethoxy)- Page 5 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 16672-87-0 Ethephon563-12-2 Ethion 111-15-9 Ethoxyethanol Acetate, 2- 9.6E+04 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes 110-80-5 Ethoxyethanol, 2- 2.2E+06 1.4E+03 N 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 141-78-6 Ethyl Acetate 2.7E+03 4.9E+02 N 1.5E+01 N 1.5E+01 N 1.5E+01 N Yes 140-88-5 Ethyl Acrylate 1.2E+02 5.6E+01 N 1.7E+00 N 1.7E+00 N 1.7E+00 N Yes 75-00-3 Ethyl Chloride (Chloroethane) 4.6E+03 7.0E+04 N 2.1E+03 N 2.1E+03 N 2.1E+03 N Yes 60-29-7 Ethyl Ether97-63-2 Ethyl Methacrylate 2.7E+03 2.1E+03 N 6.3E+01 N 6.3E+01 N 6.3E+01 N Yes2104-64-5 Ethyl-p-nitrophenyl Phosphonate 100-41-4 Ethylbenzene 3.5E+01 3.7E+02 C 1.1E+00 C 1.1E+01 C 1.1E+02 C Yes 109-78-4 Ethylene Cyanohydrin 107-15-3 Ethylene Diamine 107-21-1 Ethylene Glycol Not Volatile Not Volatile 8.3E+01 N 8.3E+01 N 8.3E+01 N Yes 111-76-2 Ethylene Glycol Monobutyl Ether Not Volatile Not Volatile 3.3E+02 N 3.3E+02 N 3.3E+02 N Yes 75-21-8 Ethylene Oxide 5.6E-01 1.1E-01 C 3.4E-04 C 3.4E-03 C 3.4E-02 C Yes96-45-7 Ethylene Thiourea Not Volatile Not Volatile 2.2E-01 C 2.2E+00 C 2.2E+01 C151-56-4 Ethyleneimine 3.0E+00 4.9E-02 C 1.5E-04 C 1.5E-03 C 1.5E-02 C 84-72-0 Ethylphthalyl Ethyl Glycolate 22224-92-6 Fenamiphos 39515-41-8 Fenpropathrin 51630-58-1 Fenvalerate 2164-17-2 Fluometuron 16984-48-8 Fluoride Not Volatile Not Volatile 2.7E+00 N 2.7E+00 N 2.7E+00 N Yes 7782-41-4 Fluorine (Soluble Fluoride) Not Volatile Not Volatile 2.7E+00 N 2.7E+00 N 2.7E+00 N Yes59756-60-4 Fluridone56425-91-3 Flurprimidol 85509-19-9 Flusilazole 66332-96-5 Flutolanil 69409-94-5 Fluvalinate 133-07-3 Folpet 72178-02-0 Fomesafen 944-22-9 Fonofos50-00-0 Formaldehyde 1.5E+05 6.8E+01 N 2.2E-01 C 2.0E+00 N 2.0E+00 N Yes64-18-6 Formic Acid 9.2E+03 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 39148-24-8 Fosetyl-AL Furans 132-64-9 ~Dibenzofuran 110-00-9 ~Furan 109-99-9 ~Tetrahydrofuran 1.4E+05 1.4E+04 N 4.2E+02 N 4.2E+02 N 4.2E+02 N Yes 67-45-8 Furazolidone98-01-1 Furfural 6.8E+04 3.5E+02 N 1.0E+01 N 1.0E+01 N 1.0E+01 N Yes531-82-8 Furium Not Volatile Not Volatile 6.5E-03 C 6.5E-02 C 6.5E-01 C 60568-05-0 Furmecyclox Not Volatile Not Volatile 3.3E-01 C 3.3E+00 C 3.3E+01 C 77182-82-2 Glufosinate, Ammonium 111-30-8 Glutaraldehyde Not Volatile Not Volatile 1.7E-02 N 1.7E-02 N 1.7E-02 N Yes 765-34-4 Glycidyl 1.0E+04 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 1071-83-6 Glyphosate 113-00-8 Guanidine 50-01-1 Guanidine Chloride506-93-4 Guanidine Nitrate69806-40-2 Haloxyfop, Methyl 76-44-8 Heptachlor 1.8E+00 7.2E-01 C 2.2E-03 C 2.2E-02 C 2.2E-01 C 1024-57-3 Heptachlor Epoxide 1.3E+01 3.6E-01 C 1.1E-03 C 1.1E-02 C 1.1E-01 C 142-82-5 Heptane, N- 1.0E+00 2.8E+03 N 8.3E+01 N 8.3E+01 N 8.3E+01 N Yes 87-82-1 Hexabromobenzene 68631-49-2 Hexabromodiphenyl ether, 2,2',4,4',5,5'- (BDE-153) 118-74-1 Hexachlorobenzene 8.8E-01 2.0E+00 C 6.1E-03 C 6.1E-02 C 6.1E-01 C 87-68-3 Hexachlorobutadiene 3.0E+00 4.3E+01 C 1.3E-01 C 1.3E+00 C 1.3E+01 C Page 6 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 319-84-6 Hexachlorocyclohexane, Alpha- Not Volatile Not Volatile 1.6E-03 C 1.6E-02 C 1.6E-01 C319-85-7 Hexachlorocyclohexane, Beta- Not Volatile Not Volatile 5.3E-03 C 5.3E-02 C 5.3E-01 C 58-89-9 Hexachlorocyclohexane, Gamma- (Lindane)Not Volatile Not Volatile 9.1E-03 C 9.1E-02 C 9.1E-01 C 608-73-1 Hexachlorocyclohexane, Technical Not Volatile Not Volatile 5.5E-03 C 5.5E-02 C 5.5E-01 C 77-47-4 Hexachlorocyclopentadiene 3.8E-02 1.4E+00 N 4.2E-02 N 4.2E-02 N 4.2E-02 N Yes 67-72-1 Hexachloroethane 1.6E+01 8.5E+01 C 2.6E-01 C 2.6E+00 C 6.3E+00 N Yes70-30-4 Hexachlorophene 121-82-4 Hexahydro-1,3,5-trinitro-1,3,5-triazine (RDX) 822-06-0 Hexamethylene Diisocyanate, 1,6- 1.1E+00 7.0E-02 N 2.1E-03 N 2.1E-03 N 2.1E-03 N Yes 680-31-9 Hexamethylphosphoramide 110-54-3 Hexane, N- 2.0E+00 4.9E+03 N 1.5E+02 N 1.5E+02 N 1.5E+02 N Yes 124-04-9 Hexanedioic Acid591-78-6 Hexanone, 2- 1.6E+03 2.1E+02 N 6.3E+00 N 6.3E+00 N 6.3E+00 N Yes51235-04-2 Hexazinone 78587-05-0 Hexythiazox 67485-29-4 Hydramethylnon 302-01-2 Hydrazine 2.3E+02 1.9E-01 C 5.7E-04 C 5.7E-03 C 6.3E-03 N Yes 10034-93-2 Hydrazine Sulfate Not Volatile Not Volatile 5.7E-04 C 5.7E-03 C 5.7E-02 C 7647-01-0 Hydrogen Chloride 5.0E-08 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 7664-39-3 Hydrogen Fluoride 6.9E+02 9.7E+01 N 2.9E+00 N 2.9E+00 N 2.9E+00 N Yes 7783-06-4 Hydrogen Sulfide 1.2E+00 1.4E+01 N 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes123-31-9 Hydroquinone35554-44-0 Imazalil 81335-37-7 Imazaquin 81335-77-5 Imazethapyr 7553-56-2 Iodine 36734-19-7 Iprodione 7439-89-6 Iron 78-83-1 Isobutyl Alcohol78-59-1 Isophorone Not Volatile Not Volatile 4.2E+02 N 4.2E+02 N 4.2E+02 N Yes33820-53-0 Isopropalin 67-63-0 Isopropanol 1.3E+05 1.4E+03 N 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 1832-54-8 Isopropyl Methyl Phosphonic Acid 82558-50-7 Isoxaben E1737665 JP-7 1.5E+02 2.1E+03 N 6.3E+01 N 6.3E+01 N 6.3E+01 N Yes 77501-63-4 Lactofen Lead Compounds7758-97-6 ~Lead Chromate Not Volatile Not Volatile 6.8E-06 C 6.8E-05 C 6.8E-04 C Yes7446-27-7 ~Lead Phosphate Not Volatile Not Volatile 2.3E-01 C 2.3E+00 C 2.3E+01 C 301-04-2 ~Lead acetate Not Volatile Not Volatile 2.3E-01 C 2.3E+00 C 2.3E+01 C 7439-92-1 ~Lead and Compounds Not Volatile Not Volatile 1.5E-01 N 1.5E-01 N 1.5E-01 N Yes 1335-32-6 ~Lead subacetate Not Volatile Not Volatile 2.3E-01 C 2.3E+00 C 2.3E+01 C 78-00-2 ~Tetraethyl Lead 541-25-3 Lewisite 330-55-2 Linuron 7439-93-2 Lithium94-74-6 MCPA94-81-5 MCPB 93-65-2 MCPP 121-75-5 Malathion 108-31-6 Maleic Anhydride Not Volatile Not Volatile 1.5E-01 N 1.5E-01 N 1.5E-01 N Yes 123-33-1 Maleic Hydrazide 109-77-3 Malononitrile 8018-01-7 Mancozeb12427-38-2 Maneb7439-96-5 Manganese (Diet) Not Volatile Not Volatile 1.0E-02 N 1.0E-02 N 1.0E-02 N Yes 7439-96-5 Manganese (Non-diet) Not Volatile Not Volatile 1.0E-02 N 1.0E-02 N 1.0E-02 N Yes 950-10-7 Mephosfolan Page 7 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 24307-26-4 Mepiquat Chloride149-30-4 Mercaptobenzothiazole, 2- Mercury Compounds 7487-94-7 ~Mercuric Chloride (and other Mercury salts)Not Volatile Not Volatile 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 7439-97-6 ~Mercury (elemental) 1.8E-01 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 22967-92-6 ~Methyl Mercury62-38-4 ~Phenylmercuric Acetate150-50-5 Merphos 78-48-8 Merphos Oxide 57837-19-1 Metalaxyl 126-98-7 Methacrylonitrile 6.2E+02 2.1E+02 N 6.3E+00 N 6.3E+00 N 6.3E+00 N Yes 10265-92-6 Methamidophos 67-56-1 Methanol 2.2E+07 1.4E+05 N 4.2E+03 N 4.2E+03 N 4.2E+03 N Yes 950-37-8 Methidathion16752-77-5 Methomyl99-59-2 Methoxy-5-nitroaniline, 2- Not Volatile Not Volatile 2.0E-01 C 2.0E+00 C 2.0E+01 C 72-43-5 Methoxychlor 110-49-6 Methoxyethanol Acetate, 2- 1.6E+04 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 109-86-4 Methoxyethanol, 2- 3.1E+05 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 79-20-9 Methyl Acetate 96-33-3 Methyl Acrylate 5.1E+02 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 78-93-3 Methyl Ethyl Ketone (2-Butanone) 4.5E+05 3.5E+04 N 1.0E+03 N 1.0E+03 N 1.0E+03 N Yes 60-34-4 Methyl Hydrazine 3.4E+01 1.4E-01 N 2.8E-03 C 4.2E-03 N 4.2E-03 N Yes 108-10-1 Methyl Isobutyl Ketone (4-methyl-2-pentanone)1.1E+05 2.1E+04 N 6.3E+02 N 6.3E+02 N 6.3E+02 N Yes 624-83-9 Methyl Isocyanate 5.5E+00 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 80-62-6 Methyl Methacrylate 1.1E+04 4.9E+03 N 1.5E+02 N 1.5E+02 N 1.5E+02 N Yes 298-00-0 Methyl Parathion 993-13-5 Methyl Phosphonic Acid 25013-15-4 Methyl Styrene (Mixed Isomers) 7.8E+01 2.8E+02 N 8.3E+00 N 8.3E+00 N 8.3E+00 N Yes66-27-3 Methyl methanesulfonate Not Volatile Not Volatile 1.0E-01 C 1.0E+00 C 1.0E+01 C1634-04-4 Methyl tert-Butyl Ether (MTBE) 4.5E+03 3.6E+03 C 1.1E+01 C 1.1E+02 C 6.3E+02 N Yes 615-45-2 Methyl-1,4-benzenediamine dihydrochloride, 2- 99-55-8 Methyl-5-Nitroaniline, 2- 70-25-7 Methyl-N-nitro-N-nitrosoguanidine, N- Not Volatile Not Volatile 1.2E-03 C 1.2E-02 C 1.2E-01 C 636-21-5 Methylaniline Hydrochloride, 2- Not Volatile Not Volatile 7.6E-02 C 7.6E-01 C 7.6E+00 C124-58-3 Methylarsonic acid 74612-12-7 Methylbenzene,1-4-diamine monohydrochloride, 2- 615-50-9 Methylbenzene-1,4-diamine sulfate, 2- 56-49-5 Methylcholanthrene, 3- Not Volatile Not Volatile 1.6E-04 C 1.6E-03 C 1.6E-02 C 75-09-2 Methylene Chloride 9.4E+02 4.2E+03 N 1.0E+02 C 1.3E+02 N 1.3E+02 N Yes 101-14-4 Methylene-bis(2-chloroaniline), 4,4'- Not Volatile Not Volatile 2.4E-03 C 2.4E-02 C 2.4E-01 C 101-61-1 Methylene-bis(N,N-dimethyl) Aniline, 4,4'-Not Volatile Not Volatile 2.2E-01 C 2.2E+00 C 2.2E+01 C 101-77-9 Methylenebisbenzenamine, 4,4'- Not Volatile Not Volatile 6.1E-03 C 6.1E-02 C 6.1E-01 C Yes 101-68-8 Methylenediphenyl Diisocyanate Not Volatile Not Volatile 1.3E-01 N 1.3E-01 N 1.3E-01 N Yes 98-83-9 Methylstyrene, Alpha- 51218-45-2 Metolachlor 21087-64-9 Metribuzin 74223-64-6 Metsulfuron-methyl8012-95-1 Mineral oils2385-85-5 Mirex 1.7E-01 1.8E-01 C 5.5E-04 C 5.5E-03 C 5.5E-02 C 2212-67-1 Molinate 7439-98-7 Molybdenum 10599-90-3 Monochloramine 100-61-8 Monomethylaniline 88671-89-0 Myclobutanil Page 8 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 74-31-7 N,N'-Diphenyl-1,4-benzenediamine300-76-5 Naled 64742-95-6 Naphtha, High Flash Aromatic (HFAN) 1.2E+03 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 91-59-8 Naphthylamine, 2- 15299-99-7 Napropamide 373-02-4 Nickel Acetate Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes 3333-67-3 Nickel Carbonate Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes 13463-39-3 Nickel Carbonyl 1.4E-04 9.7E-02 N 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes12054-48-7 Nickel Hydroxide Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes1313-99-1 Nickel Oxide Not Volatile Not Volatile 4.2E-03 N 4.2E-03 N 4.2E-03 N Yes E715532 Nickel Refinery Dust Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes 7440-02-0 Nickel Soluble Salts Not Volatile Not Volatile 1.1E-02 C 1.9E-02 N 1.9E-02 N Yes 12035-72-2 Nickel Subsulfide Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes 1271-28-9 Nickelocene Not Volatile Not Volatile 2.9E-03 N 2.9E-03 N 2.9E-03 N Yes 14797-55-8 Nitrate E701177 Nitrate + Nitrite (as N)14797-65-0 Nitrite88-74-4 Nitroaniline, 2- Not Volatile Not Volatile 1.0E-02 N 1.0E-02 N 1.0E-02 N Yes 100-01-6 Nitroaniline, 4- Not Volatile Not Volatile 1.3E+00 N 1.3E+00 N 1.3E+00 N Yes 98-95-3 Nitrobenzene 7.2E+02 2.3E+01 C 7.0E-02 C 7.0E-01 C 1.9E+00 N Yes 9004-70-0 Nitrocellulose 67-20-9 Nitrofurantoin 59-87-0 Nitrofurazone Not Volatile Not Volatile 7.6E-03 C 7.6E-02 C 7.6E-01 C 55-63-0 Nitroglycerin 556-88-7 Nitroguanidine75-52-5 Nitromethane 8.9E+02 3.5E+01 N 3.2E-01 C 1.0E+00 N 1.0E+00 N Yes79-46-9 Nitropropane, 2- 2.1E+00 3.5E-01 C 1.0E-03 C 1.0E-02 C 1.0E-01 C Yes 759-73-9 Nitroso-N-ethylurea, N- Not Volatile Not Volatile 1.3E-04 C 1.3E-03 C 1.3E-02 C 684-93-5 Nitroso-N-methylurea, N- Not Volatile Not Volatile 3.0E-05 C 3.0E-04 C 3.0E-03 C 924-16-3 Nitroso-di-N-butylamine, N- 3.3E+01 5.8E-01 C 1.8E-03 C 1.8E-02 C 1.8E-01 C 621-64-7 Nitroso-di-N-propylamine, N- Not Volatile Not Volatile 1.4E-03 C 1.4E-02 C 1.4E-01 C 1116-54-7 Nitrosodiethanolamine, N- Not Volatile Not Volatile 3.5E-03 C 3.5E-02 C 3.5E-01 C 55-18-5 Nitrosodiethylamine, N- Not Volatile Not Volatile 2.4E-05 C 2.4E-04 C 2.4E-03 C62-75-9 Nitrosodimethylamine, N- 9.7E+00 2.4E-02 C 7.2E-05 C 7.2E-04 C 7.2E-03 C Yes86-30-6 Nitrosodiphenylamine, N- Not Volatile Not Volatile 1.1E+00 C 1.1E+01 C 1.1E+02 C 10595-95-6 Nitrosomethylethylamine, N- 7.6E+01 1.5E-01 C 4.5E-04 C 4.5E-03 C 4.5E-02 C 59-89-2 Nitrosomorpholine [N-] Not Volatile Not Volatile 1.5E-03 C 1.5E-02 C 1.5E-01 C 100-75-4 Nitrosopiperidine [N-] Not Volatile Not Volatile 1.0E-03 C 1.0E-02 C 1.0E-01 C 930-55-2 Nitrosopyrrolidine, N- Not Volatile Not Volatile 4.6E-03 C 4.6E-02 C 4.6E-01 C 99-08-1 Nitrotoluene, m- 88-72-2 Nitrotoluene, o-99-99-0 Nitrotoluene, p-111-84-2 Nonane, n- 3.0E-02 1.4E+02 N 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 27314-13-2 Norflurazon 32536-52-0 Octabromodiphenyl Ether 2691-41-0 Octahydro-1,3,5,7-tetranitro-1,3,5,7- tetrazocine (HMX) 152-16-9 Octamethylpyrophosphoramide 19044-88-3 Oryzalin19666-30-9 Oxadiazon23135-22-0 Oxamyl 42874-03-3 Oxyfluorfen 76738-62-0 Paclobutrazol 1910-42-5 Paraquat Dichloride 56-38-2 Parathion 1114-71-2 Pebulate 40487-42-1 Pendimethalin32534-81-9 Pentabromodiphenyl Ether 60348-60-9 Pentabromodiphenyl ether, 2,2',4,4',5- (BDE-99) Page 9 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 608-93-5 Pentachlorobenzene76-01-7 Pentachloroethane 82-68-8 Pentachloronitrobenzene 87-86-5 Pentachlorophenol Not Volatile Not Volatile 5.5E-01 C 5.5E+00 C 5.5E+01 C 78-11-5 Pentaerythritol tetranitrate (PETN) 109-66-0 Pentane, n- 4.1E+00 7.0E+03 N 2.1E+02 N 2.1E+02 N 2.1E+02 N Yes Perchlorates 7790-98-9 ~Ammonium Perchlorate7791-03-9 ~Lithium Perchlorate14797-73-0 ~Perchlorate and Perchlorate Salts 7778-74-7 ~Potassium Perchlorate 7601-89-0 ~Sodium Perchlorate 375-73-5 Perfluorobutane sulfonic acid (PFBS) 45187-15-3 Perfluorobutanesulfonate 52645-53-1 Permethrin 62-44-2 Phenacetin Not Volatile Not Volatile 4.5E+00 C 4.5E+01 C 4.5E+02 C13684-63-4 Phenmedipham108-95-2 Phenol Not Volatile Not Volatile 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 114-26-1 Phenol, 2-(1-methylethoxy)-, methylcarbamate 92-84-2 Phenothiazine 103-72-0 Phenyl Isothiocyanate 108-45-2 Phenylenediamine, m- 95-54-5 Phenylenediamine, o-106-50-3 Phenylenediamine, p-90-43-7 Phenylphenol, 2- 298-02-2 Phorate 75-44-5 Phosgene 9.2E-02 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 732-11-6 Phosmet Phosphates, Inorganic 13776-88-0 ~Aluminum metaphosphate 68333-79-9 ~Ammonium polyphosphate7790-76-3 ~Calcium pyrophosphate7783-28-0 ~Diammonium phosphate 7757-93-9 ~Dicalcium phosphate 7782-75-4 ~Dimagnesium phosphate 7758-11-4 ~Dipotassium phosphate 7558-79-4 ~Disodium phosphate 13530-50-2 ~Monoaluminum phosphate 7722-76-1 ~Monoammonium phosphate7758-23-8 ~Monocalcium phosphate7757-86-0 ~Monomagnesium phosphate 7778-77-0 ~Monopotassium phosphate 7558-80-7 ~Monosodium phosphate 8017-16-1 ~Polyphosphoric acid 13845-36-8 ~Potassium tripolyphosphate 7758-16-9 ~Sodium acid pyrophosphate 7785-88-8 ~Sodium aluminum phosphate (acidic) 10279-59-1 ~Sodium aluminum phosphate (anhydrous) 10305-76-7 ~Sodium aluminum phosphate (tetrahydrate) 10124-56-8 ~Sodium hexametaphosphate 68915-31-1 ~Sodium polyphosphate 7785-84-4 ~Sodium trimetaphosphate7758-29-4 ~Sodium tripolyphosphate7320-34-5 ~Tetrapotassium phosphate 7722-88-5 ~Tetrasodium pyrophosphate Page 10 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 15136-87-5 ~Trialuminum sodium tetra decahydrogenoctaorthophosphate (dihydrate) 7758-87-4 ~Tricalcium phosphate 7757-87-1 ~Trimagnesium phosphate 7778-53-2 ~Tripotassium phosphate 7601-54-9 ~Trisodium phosphate7803-51-2 Phosphine 6.3E-02 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes7664-38-2 Phosphoric Acid Not Volatile Not Volatile 2.1E+00 N 2.1E+00 N 2.1E+00 N Yes 7723-14-0 Phosphorus, White Phthalates 117-81-7 ~Bis(2-ethylhexyl)phthalate Not Volatile Not Volatile 1.2E+00 C 1.2E+01 C 1.2E+02 C 85-68-7 ~Butyl Benzyl Phthalate 85-70-1 ~Butylphthalyl Butylglycolate 84-74-2 ~Dibutyl Phthalate84-66-2 ~Diethyl Phthalate120-61-6 ~Dimethylterephthalate 117-84-0 ~Octyl Phthalate, di-N- 100-21-0 ~Phthalic Acid, P- 85-44-9 ~Phthalic Anhydride Not Volatile Not Volatile 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 1918-02-1 Picloram 96-91-3 Picramic Acid (2-Amino-4,6- dinitrophenol) 88-89-1 Picric Acid (2,4,6-Trinitrophenol)29232-93-7 Pirimiphos, Methyl 59536-65-1 Polybrominated Biphenyls Not Volatile Not Volatile 3.3E-04 C 3.3E-03 C 3.3E-02 C Polychlorinated Biphenyls (PCBs) 12674-11-2 ~Aroclor 1016 1.7E+02 4.7E+01 C 1.4E-01 C 1.4E+00 C 1.4E+01 C 11104-28-2 ~Aroclor 1221 5.3E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C 11141-16-5 ~Aroclor 1232 1.6E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C 53469-21-9 ~Aroclor 1242 3.5E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C12672-29-6 ~Aroclor 1248 2.7E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C11097-69-1 ~Aroclor 1254 4.3E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C 11096-82-5 ~Aroclor 1260 3.6E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C 11126-42-4 ~Aroclor 5460 39635-31-9 ~Heptachlorobiphenyl, 2,3,3',4,4',5,5'- (PCB 189)1.2E+01 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 52663-72-6 ~Hexachlorobiphenyl, 2,3',4,4',5,5'- (PCB 167)9.1E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 69782-90-7 ~Hexachlorobiphenyl, 2,3,3',4,4',5'- (PCB 157)3.9E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 38380-08-4 ~Hexachlorobiphenyl, 2,3,3',4,4',5- (PCB 156)4.4E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 32774-16-6 ~Hexachlorobiphenyl, 3,3',4,4',5,5'- (PCB 169)9.1E-03 8.5E-04 C 2.6E-06 C 2.6E-05 C 2.6E-04 C Yes 65510-44-3 ~Pentachlorobiphenyl, 2',3,4,4',5- (PCB 123)3.3E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 31508-00-6 ~Pentachlorobiphenyl, 2,3',4,4',5- (PCB 118)2.2E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 32598-14-4 ~Pentachlorobiphenyl, 2,3,3',4,4'- (PCB 105)2.2E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 74472-37-0 ~Pentachlorobiphenyl, 2,3,4,4',5- (PCB 114)6.8E+00 8.5E-01 C 2.6E-03 C 2.6E-02 C 2.6E-01 C Yes 57465-28-8 ~Pentachlorobiphenyl, 3,3',4,4',5- (PCB 126)9.5E-04 2.5E-04 C 7.4E-07 C 7.4E-06 C 7.4E-05 C Yes 1336-36-3 ~Polychlorinated Biphenyls (high risk) 2.9E+00 1.6E+00 C 4.9E-03 C 4.9E-02 C 4.9E-01 C 1336-36-3 ~Polychlorinated Biphenyls (low risk) 1.7E+01 9.4E+00 C 2.8E-02 C 2.8E-01 C 2.8E+00 C 1336-36-3 ~Polychlorinated Biphenyls (lowest risk) 8.3E+01 4.7E+01 C 1.4E-01 C 1.4E+00 C 1.4E+01 C 32598-13-3 ~Tetrachlorobiphenyl, 3,3',4,4'- (PCB 77) Not Volatile Not Volatile 7.4E-04 C 7.4E-03 C 7.4E-02 C Yes Page 11 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 70362-50-4 ~Tetrachlorobiphenyl, 3,4,4',5- (PCB 81) 2.8E-01 8.5E-02 C 2.6E-04 C 2.6E-03 C 2.6E-02 C Yes 9016-87-9 Polymeric Methylene Diphenyl Diisocyanate (PMDI)Not Volatile Not Volatile 1.3E-01 N 1.3E-01 N 1.3E-01 N Yes Polynuclear Aromatic Hydrocarbons (PAHs) 83-32-9 ~Acenaphthene 120-12-7 ~Anthracene 56-55-3 ~Benz[a]anthracene 3.4E+02 5.6E+00 C 1.7E-02 C 1.7E-01 C 1.7E+00 C 205-82-3 ~Benzo(j)fluoranthene Not Volatile Not Volatile 2.6E-02 C 2.6E-01 C 2.6E+00 C 50-32-8 ~Benzo[a]pyrene Not Volatile Not Volatile 4.2E-04 N 4.2E-04 N 4.2E-04 N Yes 205-99-2 ~Benzo[b]fluoranthene Not Volatile Not Volatile 1.7E-02 C 1.7E-01 C 1.7E+00 C 207-08-9 ~Benzo[k]fluoranthene Not Volatile Not Volatile 1.7E-01 C 1.7E+00 C 1.7E+01 C91-58-7 ~Chloronaphthalene, Beta-218-01-9 ~Chrysene Not Volatile Not Volatile 1.7E+00 C 1.7E+01 C 1.7E+02 C 53-70-3 ~Dibenz[a,h]anthracene Not Volatile Not Volatile 1.7E-03 C 1.7E-02 C 1.7E-01 C 192-65-4 ~Dibenzo(a,e)pyrene Not Volatile Not Volatile 2.6E-03 C 2.6E-02 C 2.6E-01 C 57-97-6 ~Dimethylbenz(a)anthracene, 7,12- Not Volatile Not Volatile 1.4E-05 C 1.4E-04 C 1.4E-03 C 206-44-0 ~Fluoranthene 86-73-7 ~Fluorene 193-39-5 ~Indeno[1,2,3-cd]pyrene Not Volatile Not Volatile 1.7E-02 C 1.7E-01 C 1.7E+00 C 90-12-0 ~Methylnaphthalene, 1-91-57-6 ~Methylnaphthalene, 2-91-20-3 ~Naphthalene 3.5E+01 2.1E+01 N 8.3E-02 C 6.3E-01 N 6.3E-01 N Yes 57835-92-4 ~Nitropyrene, 4- Not Volatile Not Volatile 2.6E-02 C 2.6E-01 C 2.6E+00 C 129-00-0 ~Pyrene 29420-49-3 Potassium Perfluorobutane Sulfonate 67747-09-5 Prochloraz 26399-36-0 Profluralin 1610-18-0 Prometon7287-19-6 Prometryn1918-16-7 Propachlor 709-98-8 Propanil 2312-35-8 Propargite 107-19-7 Propargyl Alcohol 139-40-2 Propazine 122-42-9 Propham 60207-90-1 Propiconazole123-38-6 Propionaldehyde 5.6E+02 5.6E+01 N 1.7E+00 N 1.7E+00 N 1.7E+00 N Yes103-65-1 Propyl benzene 4.9E+02 7.0E+03 N 2.1E+02 N 2.1E+02 N 2.1E+02 N Yes 115-07-1 Propylene 7.8E+01 2.1E+04 N 6.3E+02 N 6.3E+02 N 6.3E+02 N Yes 57-55-6 Propylene Glycol 6423-43-4 Propylene Glycol Dinitrate Not Volatile Not Volatile 5.6E-02 N 5.6E-02 N 5.6E-02 N Yes 107-98-2 Propylene Glycol Monomethyl Ether 1.1E+07 1.4E+04 N 4.2E+02 N 4.2E+02 N 4.2E+02 N Yes 75-56-9 Propylene Oxide 2.2E+03 2.1E+02 N 7.6E-01 C 6.3E+00 N 6.3E+00 N Yes 23950-58-5 Propyzamide 110-86-1 Pyridine13593-03-8 Quinalphos91-22-5 Quinoline 76578-14-8 Quizalofop-ethyl E715557 Refractory Ceramic Fibers Not Volatile Not Volatile 6.3E+00 N 6.3E+00 N 6.3E+00 N Yes 10453-86-8 Resmethrin 299-84-3 Ronnel 83-79-4 Rotenone 94-59-7 Safrole Not Volatile Not Volatile 1.6E-02 C 1.6E-01 C 1.6E+00 C7783-00-8 Selenious Acid7782-49-2 Selenium Not Volatile Not Volatile 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 7446-34-6 Selenium Sulfide Not Volatile Not Volatile 4.2E+00 N 4.2E+00 N 4.2E+00 N Yes 74051-80-2 Sethoxydim 7631-86-9 Silica (crystalline, respirable) Not Volatile Not Volatile 6.3E-01 N 6.3E-01 N 6.3E-01 N Yes Page 12 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 7440-22-4 Silver122-34-9 Simazine 62476-59-9 Sodium Acifluorfen 26628-22-8 Sodium Azide 10588-01-9 Sodium Dichromate Not Volatile Not Volatile 6.8E-06 C 6.8E-05 C 6.8E-04 C Yes 148-18-5 Sodium Diethyldithiocarbamate 7681-49-4 Sodium Fluoride Not Volatile Not Volatile 2.7E+00 N 2.7E+00 N 2.7E+00 N Yes 62-74-8 Sodium Fluoroacetate13718-26-8 Sodium Metavanadate13472-45-2 Sodium Tungstate 10213-10-2 Sodium Tungstate Dihydrate 961-11-5 Stirofos (Tetrachlorovinphos) 7789-06-2 Strontium Chromate Not Volatile Not Volatile 6.8E-06 C 6.8E-05 C 6.8E-04 C Yes 7440-24-6 Strontium, Stable 57-24-9 Strychnine 100-42-5 Styrene 1.9E+03 7.0E+03 N 2.1E+02 N 2.1E+02 N 2.1E+02 N YesNA Styrene-Acrylonitrile (SAN) Trimer126-33-0 Sulfolane Not Volatile Not Volatile 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes 80-07-9 Sulfonylbis(4-chlorobenzene), 1,1'- 7446-11-9 Sulfur Trioxide 7.0E+00 N 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 7664-93-9 Sulfuric Acid Not Volatile Not Volatile 2.1E-01 N 2.1E-01 N 2.1E-01 N Yes 140-57-8 Sulfurous acid, 2-chloroethyl 2-[4-(1,1- dimethylethyl)phenoxy]-1-methylethyl ester Not Volatile Not Volatile 4.0E-01 C 4.0E+00 C 4.0E+01 C 21564-17-0 TCMTB34014-18-1 Tebuthiuron 3383-96-8 Temephos 5902-51-2 Terbacil 13071-79-9 Terbufos 886-50-0 Terbutryn 5436-43-1 Tetrabromodiphenyl ether, 2,2',4,4'- (BDE-47) 95-94-3 Tetrachlorobenzene, 1,2,4,5- 630-20-6 Tetrachloroethane, 1,1,1,2- 3.7E+01 1.3E+02 C 3.8E-01 C 3.8E+00 C 3.8E+01 C 79-34-5 Tetrachloroethane, 1,1,2,2- 3.2E+01 1.6E+01 C 4.8E-02 C 4.8E-01 C 4.8E+00 C 127-18-4 Tetrachloroethylene 1.2E+01 2.8E+02 N 8.3E+00 N 8.3E+00 N 8.3E+00 N Yes 58-90-2 Tetrachlorophenol, 2,3,4,6- 5216-25-1 Tetrachlorotoluene, p- alpha, alpha, alpha- 3689-24-5 Tetraethyl Dithiopyrophosphate 811-97-2 Tetrafluoroethane, 1,1,1,2- 8.2E+03 5.6E+05 N 1.7E+04 N 1.7E+04 N 1.7E+04 N Yes 479-45-8 Tetryl (Trinitrophenylmethylnitramine) 1314-32-5 Thallic Oxide 10102-45-1 Thallium (I) Nitrate 7440-28-0 Thallium (Soluble Salts) 563-68-8 Thallium Acetate 6533-73-9 Thallium Carbonate7791-12-0 Thallium Chloride12039-52-0 Thallium Selenite 7446-18-6 Thallium Sulfate 79277-27-3 Thifensulfuron-methyl 28249-77-6 Thiobencarb 111-48-8 Thiodiglycol 39196-18-4 Thiofanox 23564-05-8 Thiophanate, Methyl137-26-8 Thiram7440-31-5 Tin 7550-45-0 Titanium Tetrachloride 7.0E-01 N 2.1E-02 N 2.1E-02 N 2.1E-02 N Yes 108-88-3 Toluene 3.8E+03 3.5E+04 N 1.0E+03 N 1.0E+03 N 1.0E+03 N Yes 584-84-9 Toluene-2,4-diisocyanate 3.7E+00 5.6E-02 N 1.7E-03 N 1.7E-03 N 1.7E-03 N Yes Page 13 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 95-70-5 Toluene-2,5-diamine91-08-7 Toluene-2,6-diisocyanate 3.7E+00 5.6E-02 N 1.7E-03 N 1.7E-03 N 1.7E-03 N Yes 95-53-4 Toluidine, o- (Methylaniline, 2-) Not Volatile Not Volatile 5.5E-02 C 5.5E-01 C 5.5E+00 C 106-49-0 Toluidine, p- E1790670 Total Petroleum Hydrocarbons (Aliphatic High) E1790666 Total Petroleum Hydrocarbons (Aliphatic Low)1.7E+00 4.2E+03 N 1.3E+02 N 1.3E+02 N 1.3E+02 N Yes E1790668 Total Petroleum Hydrocarbons (Aliphatic Medium)1.5E-01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes E1790676 Total Petroleum Hydrocarbons (Aromatic High) E1790672 Total Petroleum Hydrocarbons (Aromatic Low)2.8E+01 2.1E+02 N 6.3E+00 N 6.3E+00 N 6.3E+00 N Yes E1790674 Total Petroleum Hydrocarbons (Aromatic Medium)3.2E+01 2.1E+01 N 6.3E-01 N 6.3E-01 N 6.3E-01 N Yes 8001-35-2 Toxaphene Not Volatile Not Volatile 8.8E-03 C 8.8E-02 C 8.8E-01 C 66841-25-6 Tralomethrin 688-73-3 Tri-n-butyltin102-76-1 Triacetin43121-43-3 Triadimefon 2303-17-5 Triallate 82097-50-5 Triasulfuron 101200-48-0 Tribenuron-methyl 615-54-3 Tribromobenzene, 1,2,4- 118-79-6 Tribromophenol, 2,4,6- 126-73-8 Tributyl PhosphateE1790678 Tributyltin Compounds56-35-9 Tributyltin Oxide 76-13-1 Trichloro-1,2,2-trifluoroethane, 1,1,2- 4.8E+01 3.5E+04 N 1.0E+03 N 1.0E+03 N 1.0E+03 N Yes 76-03-9 Trichloroacetic Acid 33663-50-2 Trichloroaniline HCl, 2,4,6- 634-93-5 Trichloroaniline, 2,4,6- 87-61-6 Trichlorobenzene, 1,2,3- 120-82-1 Trichlorobenzene, 1,2,4- 7.2E+00 1.4E+01 N 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes71-55-6 Trichloroethane, 1,1,1- 1.5E+03 3.5E+04 N 1.0E+03 N 1.0E+03 N 1.0E+03 N Yes79-00-5 Trichloroethane, 1,1,2- 1.2E+00 1.4E+00 N 4.2E-02 N 4.2E-02 N 4.2E-02 N Yes 79-01-6 Trichloroethylene 1.0E+00 1.4E+01 N 4.2E-01 N 4.2E-01 N 4.2E-01 N Yes 75-69-4 Trichlorofluoromethane 95-95-4 Trichlorophenol, 2,4,5- 88-06-2 Trichlorophenol, 2,4,6- Not Volatile Not Volatile 9.1E-01 C 9.1E+00 C 9.1E+01 C 93-76-5 Trichlorophenoxyacetic Acid, 2,4,5- 93-72-1 Trichlorophenoxypropionic acid, -2,4,5 598-77-6 Trichloropropane, 1,1,2-96-18-4 Trichloropropane, 1,2,3- 4.5E+00 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes96-19-5 Trichloropropene, 1,2,3- 8.7E-02 2.1E+00 N 6.3E-02 N 6.3E-02 N 6.3E-02 N Yes 1330-78-5 Tricresyl Phosphate (TCP) 58138-08-2 Tridiphane 121-44-8 Triethylamine 2.4E+02 4.9E+01 N 1.5E+00 N 1.5E+00 N 1.5E+00 N Yes 112-27-6 Triethylene Glycol 420-46-2 Trifluoroethane, 1,1,1- 1.3E+02 1.4E+05 N 4.2E+03 N 4.2E+03 N 4.2E+03 N Yes 1582-09-8 Trifluralin512-56-1 Trimethyl Phosphate526-73-8 Trimethylbenzene, 1,2,3- 7.0E+01 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes 95-63-6 Trimethylbenzene, 1,2,4- 5.0E+01 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes 108-67-8 Trimethylbenzene, 1,3,5- 3.5E+01 4.2E+02 N 1.3E+01 N 1.3E+01 N 1.3E+01 N Yes 25167-70-8 Trimethylpentene, 2,4,4- 99-35-4 Trinitrobenzene, 1,3,5- 118-96-7 Trinitrotoluene, 2,4,6- 791-28-6 Triphenylphosphine Oxide Page 14 or 15 CAS # Chemical Name: Ground Water Screening Level (GWSL) ug/L TCR=1.0E-05 THQ=0.2 Sub-slab and Exterior Soil Gas Screening Level (SGSL) ug/m3 TCR=1.0E-05THQ=0.2 Basis IASL (A) ug/m3 TCR=1.0E-06 THQ=0.2 Basis IASL (B) ug/m3 TCR=1.0E-05 THQ=0.2 Basis IASL (C)3 ug/m3 TCR=1.0E-04THQ=0.2 Basis Does Chemical Have a Non- Cancer Effect?4 North Carolina Department of Environmental Quality Residential Vapor Intrusion Screening Levels October 2017 (based on June 2017 USEPA Regional Screening Tables) 13674-87-8 Tris(1,3-Dichloro-2-propyl) Phosphate13674-84-5 Tris(1-chloro-2-propyl)phosphate 126-72-7 Tris(2,3-dibromopropyl)phosphate 4.8E+01 1.4E+00 C 4.3E-03 C 4.3E-02 C 4.3E-01 C 115-96-8 Tris(2-chloroethyl)phosphate 78-42-2 Tris(2-ethylhexyl)phosphate 7440-33-7 Tungsten E715565 Uranium (Soluble Salts) Not Volatile Not Volatile 8.3E-03 N 8.3E-03 N 8.3E-03 N Yes 51-79-6 Urethane Not Volatile Not Volatile 3.5E-03 C 3.5E-02 C 3.5E-01 C1314-62-1 Vanadium Pentoxide Not Volatile Not Volatile 3.4E-04 C 1.5E-03 N 1.5E-03 N Yes7440-62-2 Vanadium and Compounds Not Volatile Not Volatile 2.1E-02 N 2.1E-02 N 2.1E-02 N Yes 1929-77-7 Vernolate 50471-44-8 Vinclozolin 108-05-4 Vinyl Acetate 2.0E+03 1.4E+03 N 4.2E+01 N 4.2E+01 N 4.2E+01 N Yes 593-60-2 Vinyl Bromide 1.2E+00 2.1E+01 N 8.8E-02 C 6.3E-01 N 6.3E-01 N Yes 75-01-4 Vinyl Chloride 1.5E+00 5.6E+01 C 1.7E-01 C 1.7E+00 C 1.7E+01 C Yes 81-81-2 Warfarin106-42-3 Xylene, P- 7.4E+01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes108-38-3 Xylene, m- 7.1E+01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 95-47-6 Xylene, o- 9.8E+01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 1330-20-7 Xylenes 7.7E+01 7.0E+02 N 2.1E+01 N 2.1E+01 N 2.1E+01 N Yes 1314-84-7 Zinc Phosphide 7440-66-6 Zinc and Compounds 12122-67-7 Zineb 7440-67-7 Zirconium 1) TCR = Target Cancer Risk; THQ=Target Hazard Quotient; C= Carcinogenic; N = Non-Carcinogenic 2) Indoor Air/Crawlspace Screening Levels at target risk 1.0E-04 (IASL C) to be used if only one carcinogen is present. 3) If more than five compounds with non-cancer effects are present risk should be evaluated using NCDEQ Risk Calculator. Page 15 or 15 APPENDIX D LABORATORY REPORT AND CHAIN OF CUSTODY FORM Page 1 of 28 Page 2 of 28 Page 3 of 28 Page 4 of 28 Page 5 of 28 Page 6 of 28 Page 7 of 28 Page 8 of 28 Page 9 of 28 Page 10 of 28 Page 11 of 28 Page 12 of 28 Page 13 of 28 Page 14 of 28 Page 15 of 28 Page 16 of 28 Page 17 of 28 Page 18 of 28 Page 19 of 28 Page 20 of 28 Page 21 of 28 Page 22 of 28 Page 23 of 28 Page 24 of 28 Page 25 of 28 Page 26 of 28 Page 27 of 28 Page 28 of 28 APPENDIX E NCDEQ’S RISK CALCULATOR RESULTS Version Date: Basis: Site Name: Site Address: DEQ Section: Site ID: Exposure Unit ID: Submittal Date: Reviewed By: 12/19/2017 Prepared By:Rob Hill - RDH Environmental Consulting North Carolina Department of Environmental Quality Risk Calculator Passage Home 500 Hoke Street - Raleigh, NC Brownfields NCBF PROJECT NO: 21007-17-092 October 2017 June 2017 EPA RSL Table North Carolina DEQ Risk Calculator Table of Contents Version Date: October 2017 Basis: June 2017 EPA RSL Table Site ID: NCBF PROJECT NO: 21007-17-092 Exposure Unit ID: Form No. Input Form 1A Complete Exposure Pathways Input Form 1B Exposure Factors and Target Risks Input Form 1C Contaminant Migration Parameters Input Form 1D Sample Statistics Input Form 2A Surface Soil Exposure Point Concentration Table Input Form 2B Subsurface Soil Exposure Point Concentration Table Input Form 2C Groundwater Exposure Point Concentration Table Input Form 2D Surface Water Exposure Point Concentration Table Input Form 2E Soil Gas Exposure Point Concentration Table Input Form 2F Indoor Air Exposure Point Concentration Table Output Form 1A Summary of Risk Assessment Output Output Form 2A Resident Soil Combined Pathways Output Form 2B Resident Groundwater Combined Pathways Output Form 2C Non-Residential Worker Soil Combined Pathways Output Form 2D Non-Residential Worker Groundwater Combined Pathways Output Form 2E Construction Worker Soil Combined Pathways Output Form 2F User Defined Soil Combined Pathways Output Form 2G User Defined Surface Water Combined Pathways Output Form 3A Resident Groundwater to Indoor Air Output Form 3B Resident Soil Gas to Indoor Air Output Form 3C Resident Indoor Air Output Form 3D Non-Residential Worker Groundwater to Indoor Air Output Form 3E Non-Residential Worker Soil Gas to Indoor Air Output Form 3F Non-Residential Worker Indoor Air Output Form 4A Soil Source to Groundwater POE - Forward Mode Output Form 4B Groundwater Source to Groundwater POE - Forward Mode Output Form 4C Soil Source to Surface Water POE - Forward Mode Output Form 4D Groundwater Source to Surface Water POE - Forward Mode Output Form 4E Soil Source to Groundwater POE - Backward Mode Output Form 4F Groundwater Source to Groundwater POE - Backward Mode Output Form 4G Soil Source to Surface Water POE - Backward Mode Output Form 4H Groundwater Source to Surface Water POE - Backward Mode Output Section 4 - Contaminant Migration to Point of Exposure (POE) Worksheets Output Section 3 - Vapor Intrusion Calculators TOC Description DATA INPUT SHEETS Check box if included Input Section 1 - Exposure Pathways & Parameters Input Section 2 - Exposure Point Concentrations DATA OUTPUT SHEETS Output Section 1 - Summary Output for All Calculators Output Section 2 - Primary Calculators North Carolina DEQ Risk Calculator Exposure Point ConcentrationsVersion Date: October 2017Basis: June 2017 EPA RSL TableSite ID: NCBF PROJECT NO: 21007-17-092Exposure Unit ID: Note: Chemicals highlighted in orange are non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals.Exposure Point Concentration (ug/m3)Justification for Exposure Point ConcentrationCAS Number ChemicalMinimum Concentration (Qualifier)Maximum Concentration (Qualifier)UnitsLocation of Maximum ConcentrationDetection FrequencyRange of Detection LimitsConcentration Used for ScreeningBackground ValueScreening Toxicity Value (Screening Level) (n/c)Potential ARAR/TBC ValuePotential ARAR/TBC SourceCOPC Flag (Y/N)Rationale for Selection or Deletion98Max Concentration67-64-1 Acetone 97 98ug/m3SS-1 (Dup)11Max Concentration56-23-5 Carbon Tetrachloride 11 11ug/m3SS-33.1Max Concentration67-66-3 Chloroform 3.1 3.1ug/m3SS-372Max Concentration110-83-8 Cyclohexene 6.2 72ug/m3SS-42.9Max Concentration141-78-6 Ethyl Acetate 2.9 2.9ug/m3SS-49.1Max Concentration100-41-4 Ethylbenzene 3.1 9.1ug/m3SS-42.6Max Concentration109-99-9 ~Tetrahydrofuran 1.6 2.6ug/m3SS-4200Max Concentration142-82-5 Heptane, N- 3.3 200ug/m3SS-4470Max Concentration110-54-3 Hexane, N- 11 470ug/m3SS-472Max Concentration591-78-6 Hexanone, 2- 72 72ug/m3SS-23.8Max Concentration67-63-0 Isopropanol 2.1 3.8ug/m3SS-415Max Concentration78-93-3 Methyl Ethyl Ketone (2-Butanone) 6.9 15ug/m3SS-43.7Max Concentration91-20-3 ~Naphthalene 3.7 3.7ug/m3SS-47.1Max Concentration115-07-1 Propylene 4.6 7.1ug/m3SS-1 (Dup)590Max Concentration127-18-4 Tetrachloroethylene 16 590ug/m3SS-324Max Concentration108-88-3 Toluene 6.3 24ug/m3SS-412Max Concentration71-55-6 Trichloroethane, 1,1,1- 12 12ug/m3SS-33.8Max Concentration75-69-4 Trichlorofluoromethane 3.8 3.8ug/m3SS-311Max Concentration95-63-6 Trimethylbenzene, 1,2,4- 5.3 11ug/m3SS-44.1Max Concentration108-67-8 Trimethylbenzene, 1,3,5- 2.3 4.1ug/m3SS-136Max Concentration106-42-3 Xylene, P- 10 36ug/m3SS-436Max Concentration108-38-3 Xylene, m- 10 36ug/m3SS-413Max Concentration95-47-6 Xylene, o- 3.8 13ug/m3SS-4Input Form 2ESoil Gas Exposure Point Concentration TableNorth Carolina DEQ Risk Calculator Summary of Risk Assessment Output Output Form 1A Version Date: October 2017 Basis: June 2017 EPA RSL Table Site ID: NCBF PROJECT NO: 21007-17-092 Exposure Unit ID: Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Soil Combined Pathways 0.0E+00 0.0E+00 NO Groundwater Combined Pathways* 0.0E+00 0.0E+00 NO Soil Combined Pathways NC NC NC Groundwater Combined Pathways* NC NC NC Construction Worker Soil Combined Pathways NC NC NC Soil Combined Pathways NC NC NC Surface Water Combined Pathways* NC NC NC Receptor Pathway Carcinogenic Risk Hazard Index Risk exceeded? Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 4.7E-06 6.0E-01 NO Indoor Air NC NC NC Groundwater to Indoor Air NC NC NC Soil Gas to Indoor Air 3.6E-07 4.8E-02 NO Indoor Air NC NC NC Pathway Source Source Soil NC Source Groundwater NC Source Soil NC Source Groundwater NM PRIMARY CALCULATORS Resident Non-Residential Worker User Defined 2. * = If concentrations in groundwater exceed the NC 2L Standards or IMAC, or concentrations in surface water exceed the NC 2B Standards, appropriate remediation and/or institutional control measures will be necessary to be eligible for a risk-based closure. Protection of Surface Water Exceedence of 2B at POE? Exceedence of 2B at POE? VAPOR INTRUSION CALCULATORS Resident Non-Residential Worker CONTAMINANT MIGRATION CALCULATORS Target POE Concentrations Exceeded? Protection of Groundwater Use Exceedence of 2L at POE? Exceedence of 2L at POE? 1. If lead concentrations were entered in the exposure point concentration tables, see the individual calculator sheets for lead concentrations in comparison to screening levels. Note that lead is not included in cumulative risk calculations. Notes: North Carolina DEQ Risk Calculator DEQ Risk Calculator - Vapor Intrusion - Resident Soil Gas to Indoor Air Version Date: October 2017 Basis: June 2017 EPA RSL Table Site ID: NCBF PROJECT NO: 21007-17-092 Exposure Unit ID: CAS # Chemical Name: Soil Gas Concentration (ug/m3) Calculated Indoor Air Concentration (ug/m3) Target Indoor Air Conc. for Carcinogens @ TCR = 1E-06 Target Indoor Air Conc. for Non- Carcinogens @ THQ = 0.2 Calculated Carcinogenic Risk Calculated Non- Carcinogenic Hazard Quotient 67-64-1 Acetone 98 2.94 - 6.5E+03 9.1E-05 56-23-5 Carbon Tetrachloride 11 0.33 4.7E-01 2.1E+01 7.1E-07 3.2E-03 67-66-3 Chloroform 3.1 0.093 1.2E-01 2.0E+01 7.6E-07 9.1E-04 110-83-8 Cyclohexene 72 2.16 - 2.1E+02 2.1E-03 141-78-6 Ethyl Acetate 2.9 0.087 - 1.5E+01 1.2E-03 100-41-4 Ethylbenzene 9.1 0.273 1.1E+00 2.1E+02 2.4E-07 2.6E-04 109-99-9 ~Tetrahydrofuran 2.6 0.078 - 4.2E+02 3.7E-05 142-82-5 Heptane, N- 200 6 - 8.3E+01 1.4E-02 110-54-3 Hexane, N- 470 14.1 - 1.5E+02 1.9E-02 591-78-6 Hexanone, 2- 72 2.16 - 6.3E+00 6.9E-02 67-63-0 Isopropanol 3.8 0.114 - 4.2E+01 5.5E-04 78-93-3 Methyl Ethyl Ketone (2-Butanone) 15 0.45 - 1.0E+03 8.6E-05 91-20-3 ~Naphthalene 3.7 0.111 8.3E-02 6.3E-01 1.3E-06 3.5E-02 115-07-1 Propylene 7.1 0.213 - 6.3E+02 6.8E-05 127-18-4 Tetrachloroethylene 590 17.7 1.1E+01 8.3E+00 1.6E-06 4.2E-01 108-88-3 Toluene 24 0.72 - 1.0E+03 1.4E-04 71-55-6 Trichloroethane, 1,1,1- 12 0.36 - 1.0E+03 6.9E-05 75-69-4 Trichlorofluoromethane 3.8 0.114 - - 95-63-6 Trimethylbenzene, 1,2,4- 11 0.33 - 1.3E+01 5.3E-03 108-67-8 Trimethylbenzene, 1,3,5- 4.1 0.123 - 1.3E+01 2.0E-03 106-42-3 Xylene, P- 36 1.08 - 2.1E+01 1.0E-02 108-38-3 Xylene, m- 36 1.08 - 2.1E+01 1.0E-02 95-47-6 Xylene, o- 13 0.39 - 2.1E+01 3.7E-03 Cumulative: 4.7E-06 6.0E-01 All concentrations are in ug/m3 Output Form 3B Carcinogenic risk and hazard quotient cells highlighted in orange are associated with non-volatile chemicals. Since these chemicals do not pose a vapor intrusion risk, no risk values are calculated for these chemicals. North Carolina DEQ Risk Calculator