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HomeMy WebLinkAboutMO-9331_40792_CA_LSA_20190726_Limited Site AssessmentI 'AW-14 \I Civil-Geotechnical-Surveying July 26, 2019 Trudy Beverly, L.G. Hydrogeologist North Carolina Department of Environment and Natural Resources 601 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 Re: Limited Site Assessment Transmittal Letter Byrum Property 5628 Closeburn Road Charlotte, Mecklenburg County, North Carolina 28210 UST Incident Number 40792 Dear Ms. Beverly: On behalf of our client, Parkstone South, LLC, owner of the property at 5628 Closeburn Road (former Byrum Property), Charlotte, North Carolina (Property), Concord Engineering and Surveying, Inc. (CESI) is submitting the attached Limited Site Assessment for your review. CESI appreciates your assistance on this project. Should you have any questions, please do not hesitate to contact me at (704) 795-1585. Sincerely, Az� �— e--,— Steven E. Irminger, P.E. Senior Engineer 45 Spring Street, SW P.O. Box 268 Concord, NC 28026-0268 704-786-5404 www.cesicgs.com NC License Number C-0263 Limited Site Assessment Report A. Site Information 1. Site Identification -Date of Report: July 26, 2019 Facility I.D.: Unknown UST Incident Number (if known): 40792 Site Name: Byrum Property (MO-9331) Site Street Address: 5628 Closeburn Road City/Town: Charlotte Zip Code: 28210 County: Mecklenburg Description of Geographical Data Point (e.g., diesel fill port): Center of tank farm. Location Method (GPS, topographical map, other): GIS Address matching Latitude (decimal degrees): 35.149821 Longitude (decimal degrees):-80.845903 2. Information about Contacts Associated with the Leaking UST System BUST Owner: Parkstone South, LLC Address: Tel:704-701-9099 BUST Operator: N/A Address: Tel Property Owner: Parkstone South, LLC Address: 568 Jetton Street, Suite 200; Davidson, NC 28036 'Property Occupant: None (Vacant lot) Address: Tel Consultant/Contractor: Concord Engineering and Surveying, Inc. (CESI) Address: 46 Spring Street, Concord, NC 28026 Tel: (704) 701-9099 Analytical Laboratory: Pace Analytical, Inc. State Certification No. 37712 Address: 9800 Kincey Avenue, Huntersville, North Carolina Tel: (704) 875-9092 3. Information about Release Date Discovered: January 22, 2018 Estimated Quantity of Release: Unknown Cause of Release: Corrosion Source of Release (Dispenser/Piping/UST): UST Sizes and contents of UST system(s) from which the release occurred): (1) 550 gallon UST Approximately 67 gallons of heating oil was encountered in the tank and removed prior to removal of the UST. The dates of operation are not known. 4. Certification (The title page must display the seal and signature of the certifying P.E. or L.G. and the name and certification number of the company or corporation [See 15A NCAC 2L . 0103(e).]) I, Steven Irminger, a Professional Engineer, do certify that the information contained in this report is correct and accurate to the best of my knowledge. Steven E. Irminger, P.E. #21005 _` .'z ti9 SEAL = 021005 - Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 2 B. Site History and Characterization 1. Details regarding the ownership of the former UST is provided in Table B-2. 2. Details regarding information of the former UST are provided in Table B-1. Based on our review of the available information, the property was undeveloped and wooded land from at least 1940 until construction of a residential dwelling in 1955. On January 22, 2018, Summit Engineering, Laboratory, Testing (Summit) advanced two soil borings on either end of a heating oil UST at the property. The borings were conducted to assess soil conditions in the vicinity of the tank prior to a sale of the property. Analytical results of a soil sample from one end of the UST were reported with concentrations exceeding the Maximum Soil Cleanup Concentrations (MSCCs) for residential sites. Summit submitted form UST-61, on behalf of the owner, on April 22, 2018. A Notice of Regulatory Requirements (NORR) was issued for this site by DEQ on August 29, 2018. A copy of the NORR is attached in Appendix 1. In February and March 2019, the building was razed. On March 22, 2019, a 550 gallon heating oil UST was removed from the property. A closure assessment report for the tank removed March 22, 2019, was completed by ECS Southeast, LLP (ECS) and prepared in a report dated May 8, 2019. According to the ECS report, following removal of the UST, a total of 314.35 tons of petroleum impacted soil was removed from the site for treatment at Environmental Soil, Inc., of Shelby, North Carolina. In addition, 6,756 gallons of contact water was pumped from the excavation following heavy rain. The contact water was removed for offsite disposal. Analyses of confirmatory soil samples collected during the tank closure assessment revealed that none of the parameters tested exceeded the MSCCs for residential sites. Soil samples collected from the excavation bottom, east, and west walls, exceeded the soil -to -groundwater MSCC for 1-Methylnaphthalene and Extractable Aromatic (C11- C22) hydrocarbons. In addition, the sample collected from the bottom of the excavation exceeded the Volatile Aromatic (C09-C10) hydrocarbons soil -to -groundwater MSCC. Analysis of a groundwater sample collected during performance of this Limited Site Assessment (LSA) reported dissolved naphthalene at a concentration of 1.0 ug/L and total Chromium at a concentration of 6.3 ug/L. All other tested parameters were reported to be below the sample detection limit. A street atlas showing the property location is provided as Figure 1. The property location on a portion of a USGS topographic map is provided as Figure 2. 3. Provide non -UST information: a. The tank of this report was underground. No evidence of aboveground storage tanks were observed or reported. Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 3 b. No spills have been reported for the facility other than the discovery January 22, 2018. 4. Provide a comprehensive description of the release, including date discovered, cause and source (including tank identification number and contents), and the relationship of historical UST releases, non -UST releases, and off -site releases (indicate incident number) to contamination from current release. The precise source and timing of contamination is not known. No historical UST releases, non -UST releases, or off -site releases have been reported. 5. Provide a brief description of site characteristics (including status of facility (active or inactive), land use of site and surrounding area, water supply, topography, vegetation, surface water, wells, buildings, surface cover, soil type, depth to and nature of bedrock, depth to groundwater, direction of groundwater flow, etc.) Site Characteristics: The property is identified as Assessor Parcel Number (APN) 17125221 and is assigned the numerical street address 5628 Closeburn Road by Mecklenburg County. The property is currently vacant land. The property location is shown on a Street Atlas as Figure 1. A copy of the Mecklenburg County GIS assessor information and tax card is included in Appendix 2. Site Vicinity Characteristics: The property vicinity is residential. A site vicinity map is provided as Figure 3. DIRECTION ADDRESS/OCCUPIED TOPOGRAPHIC BY/USE POSITION RELATIVE TO PROPERTY North 5605, 5617, 5621, 5629, Closeburn Up gradient Road/ single family residences East 5700 Closeburn Road/single family Cross gradient residence West 5615 Glenkirk Road/single family Up gradient residence South 5640, 5700, 5728 Glenkirk Road/single Down gradient family residence Water Supply: The subject property and vicinity is provided water from the City of Charlotte. No potable or irrigation wells were observed on the subject property or nearby the property. Adjoining properties are provided potable water by municipal water from a main located along Closeburn Road and Glenkirk Road. Topographer CESI obtained a copy of the USGS 7.5-minute topographic map, Charlotte, North Carolina Quadrangle, dated 1993. A copy of a portion of the topographic map showing the property location is provided on Figure 2. The elevation of the property is approximately 660 feet above mean sea level (msl). Based Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 4 upon the topographic contours observed on the USGS topographic contour map, the property slope is generally downward toward the south. Vegetation: The property surface cover is turf and wooded land along its southern boundary. Surface Water: A tributary of Sugar Creek flows along the southern boundary of the Property. Wells: No wells were observed at the property. Buildings: The property is not improved with structures. The Property Layout is shown as Figure 3. Surface Cover: The majority of the property surface is covered by turf. Soil Type: According to the USDA web -based soil survey of Mecklenburg County, approximately 17 percent of the surficial soil at the property is comprised of Cecil - Urban Land Complex. The Cecil series consists of very deep, well drained, moderately permeable soils on ridges and side slopes of the Piedmont uplands. They are deep to saprolite and very deep to bedrock. They formed in residuum weathered from felsic, igneous and high-grade metamorphic rocks of the Piedmont uplands. Slopes range from 0 to 25 percent. Depth to bedrock ranges from 6 to 10 feet or more. Approximately 59 percent of the surficial soil at the Property is comprised of the Enon Series. The Enon series consists of very deep, well drained, slowly permeable soils on ridgetops and side slopes in the Piedmont. They have formed in residuum weathered from mafic or intermediate igneous and high-grade metamorphic rocks such as diorite, gabbro, diabase, or hornblende gneiss or schist. Slope ranges from 2 to 45 percent. The solum thickness ranges from 20 to 50 inches. Depth to bedrock is more than 60 inches. Urban soil is material that has been manipulated or disturbed. The urban soils typically consist of asphalt and concrete from construction sites. Approximately 23 percent of the surficial soils at the Property are of the Helena soil series. The Helena soil series is a very deep, moderately well -drained, with slow permeability sandy loam, that is usually found on a four percent slop in a cultivated field. Depth to and Nature of Bedrock: According to the Geologic Map of North Carolina 1985, the property is located in the Piedmont Physiographic Province. The dominant rocks in this region are composed mainly of metamorphic and igneous rocks ranging in age from Precambrian to Paleozoic. Bedrock was not observed at the surface in the vicinity of the Property. Onsite drilling encountered fine grained sand and silts to approximately 12-feet below ground. Competent bedrock was encountered from 12 feet to 45-feet (the maximum depth penetrated) below grade. Depth to groundwater: Drilling at the site revealed depth to water approximately 31- feet below grade. Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 5 6. Summarize initial abatement actions, assessment activities, and corrective actions performed to date and list all reports previously submitted. A closure assessment report for the tank removed March 22, 2019, was completed by ECS Southeast, LLP (ECS) and prepared in a report dated May 8, 2019. According to the ECS report, following removal of the UST, a total of 314.35 tons of petroleum impacted soil was removed from the site for treatment at Environmental Soil, Inc., of Shelby, North Carolina. In addition, 6,756 gallons of contact water was pumped from the excavation following heavy rain. The contact water was removed for offsite disposal. Analyses of confirmatory soil samples collected during the tank closure assessment revealed that none of the parameters tested exceeded the Maximum Soil Cleanup Concentrations (MSCCs) for residential sites. Soil samples collected from the excavation bottom, east, and west walls, exceeded the soil -to -groundwater MSCC for 1-Methylnaphthalene and Extractable Aromatic (C 11-C22) hydrocarbons. In addition, the sample collected from the bottom of the excavation exceeded the Volatile Aromatic (C09-C10) hydrocarbons soil -to -groundwater MSCC. The analytical results of soil samples collected during the tank closure are summarized in Table B-3. Analysis of a groundwater sample collected during the Limited Site Assessment revealed naphthalene at a concentration of 1.0 micrograms per Liter (ug/L) and Total Chromium at a concentration of 6.3 ug/L. The LSA sampling and analytical results are discussed in Section G of this report. C. Risk Characterization Submit the following questionnaire in its entirety. Answer all questions completely. Attach additional pages as needed to fully explain answers. Base answers/explanations on information obtained (or updated from preceding reports) during the current investigation. Note: Source area means point of release from a UST system. Limited Site Assessment Risk Classification and Land Use Form Part I — Groundwater/Surface WaterNapor Impacts High Risk 1. Has the release contaminated any water supply well including any well used for non -drinking purposes?YES 2. Is a water supply well used for drinking water located within 1,000 feet of the source area of the release?YES O 3. Is a water supply well not used for drinking water (e.g., irrigation, washing cars, industrial cooling water, filling swimming pools) located within 250 feet of the source area of the release? YES/i@) 4. Does groundwater within 500 feet of the source area of the release have the potential for future use (there no other source of water supply other than the groundwater)? YES9G 5. Do vapors from the release pose a threat of explosion because of accumulation of the vapors in a confined space or pose any other serious threat to public health, public safety or the environment? YE 6. Are there any other factors that would cause the release to pose an imminent danger to public health, pu is safety, or the environment? YES/ � Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 6 If yes, describe. Intermediate Risk 7. Is a surface water body located within 500 feet of the source area of the release? E /NO If YES, does the maximum groundwater contaminant concentration exceed the surface water quality standards and criteria found in 15A NCAC 2B .0200 by a factor of 10? YES® 8. Is the source area of the release located within a approved or planned wellhead protection area as defined in 42 USC 300h-7(e)? YES® If yes, describe. 9. Is the release located in the Coastal Plain physiographic region as designated on a map entitled "Geolog of North Carolina" published by the Department in 1985 YES N If YES, is the source area of the release located in an area in which there is recharge to an unconfined or semi -confined deeper aquifer that is being used or may be used as a source of drinking water? YES® If YES, describe. 10. Do the levels of groundwater contamination for any contaminant exceed the gross contamination levels (see Table 9) established by the Department? YES(9 Part II - Land Use Property Containing Source Area of Release The questions below pertain to the property containing the source area of the release. 1. Does the property contain one or more primary or secondary residences (permanent or temporary)?YES N& Describe. _The property is being redeveloped for residential use 2. Does the property contain a school, daycare center, hospital, playground, park, recreation area, church, nursing home, or other place of public assembly? YES T� Describe. 3. Does the property contain a commercial (e.g., retail, warehouse, office/business space, etc.) or industrial (e.g., manufacturing, utilities, industrial research and development, chemical/petroleum bulk storage, etc. enterprise, an inactive commercial or industrial enterprise, or is the land undeveloped? YE Describe. 4. Do children visit the property? E NO Explain. Children and adults will visit the property once redevelopment is complete. Is access to the property reliably restricted consistent with its use (e.g., by fences, security personnel or both)? YES/�T) Explain. The property is currently not provided with a fence or security system. 5. Do pavement, buildings, or other structures cap the contaminated soil? ENO Describe. Contaminated soil encountered during the tank closure was removed for offsite disposal in April 2019. A total of 314.35 tons were removed. The parcel is currently being redeveloped for residential use. The source area is within the footprint of the proposed building and driveway. 6. What is the zoning status of the property? The property is currently zoned Residential (R-3). 7. Is the use of the property likely to change in the next 20 years? YES/0 Explain. The use is unlikely to change. Limited Site Assessment July 26, 2019 5628 Closeburn Road, Charlotte, NC Page No. 7 Property Surrounding Source Area of Release The questions below pertain to the area within 1,500 feet of the source area of the release (excludes property containing source area of the release): 1. What is the distance from the source area of the release to the nearest primary or secondary residence (permanent or temporary)? A permanent residence will be placed above the former storage tank location. 2. What is the distance from the source area of the release to the nearest school, daycare center, hospital, playground, park, recreation area, church, nursing home or other place of public assembly? The Ivey Memory Wellness Day Center is located 250 feet east of the source area. 3. What is the zoning status of properties in the surrounding area? The site and adjoining areas are zoned Residential (R-3). The land use of neighboring properties is summarized in Table B-10 and shown in Figure 9. 4. Briefly characterize the use and activities of the land in the surrounding area. The properties surrounding the Property are primarily residential. D. Receptor Information Determine and describe all potential receptors, including those in the categories listed below. Compile this information in a table entitled Public and Private Water Supply Well and Other Receptor Information (Complete Table B-5 from the Guidelines, Appendix B.) in which an identification code is assigned to each potential receptor. Indicate the locations of each potential receptor, using the identification code, on a potential receptor map. Use information from all available sources and from site investigations. An unnamed tributary of Sugar Creek borders the property to the south. The Ivey Memory wellness Day Center is located 460 feet east of the source area. 1. Water Supply Wells Determine and describe the location, use, and ownership of public and private water supply wells in the area within 1,500 feet of the source of the release. Compile this information in Table B-5 and indicate the well locations on the potential receptor map. Note whether well users are also served by a municipal water supply. Refer to the instructions for a water supply well survey in Section 2.3 of the Guidelines. Properties within 500-feet of the release were walked. Properties between 500 and 1,500 feet from the site were observed from the public road. No water supply wells were observed within 1,500 feet of the release. All of the adjoining properties appear to be connected to the municipal water supply. The adjoining properties are numbered on the Sensitive Receptor Map (Figure 4). The key to the numbered locations is provided in Table B-5. 2. Public Water Supplies Determine the existence and availability of public water supplies within 1,500 feet of the source area of the release. Compile this information in Table B-5 and indicate the locations of the nearest public water lines and the source(s) of the public water supply on the potential receptor map. Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 8 The City of Charlotte receives drinking water from the Catawba River and Lake Norman which are in excess of five miles from the Property. A water main is located along Closeburn Road which borders the property. 3. Surface Water Identify all surface water bodies (e.g., ditch, pond, stream, lake, river) located within 1,500 feet of the source area of the release and indicate distance from source of release in Table B-5 and indicate locations on the potential receptor map. The distance to surface water is summarized on Table B-5 and shown on the potential receptor map (Figure 7). 4. Wellhead Protection Areas Indicate whether or not the UST release source area is located within an approved wellhead protection area. Refer to Section 2.3 of the Guidelines for instructions on how to access the list of currently approved wellhead protection plans and generate a map of UST and wellhead protection area locations. List any identified wellhead protection area in Table B-5 by PWS ID number and PWS system name and show the wellhead protection area on the potential receptor map. To document performance of the wellhead protection area investigation append to the potential receptor map a copy of the map generated using ArcIMS Viewer to show 1) the UST location, 2) the wellhead protection area, and 3) community wells. The area of the UST release is not located within a wellhead protection area. 5. Deep Aquifers in the Coastal Plain Physiographic Re, -ion Indicate if the source area of the release is located in an area in which there is recharge to an unconfined or semi -confined deeper aquifer and indicate if that aquifer is being used or may be used as a source of drinking water, referring to Section 2.3 of the Guidelines. Based on a review of scientific literature on the regional hydrogeology and well construction records and lithologic logs for deeper wells in the area, identify and describe the deep aquifers underlying the release. Include information on the depth of the deep aquifer in relation to the surficial saturated zone, the lithology and hydraulic conductivity of the strata between the surficial aquifer and the deeper aquifer, and the difference in groundwater head between the surficial aquifer and the deeper aquifer. Discuss the local and regional usage of the deep aquifer and the draw down from major pumping influences. Also, specify the distance from the source area of the release to major discharge areas, such as streams and rivers. Cite all sources and references used for this discussion. NOTE: This requirement only pertains to releases in the Coastal Plain physiographic region as designated on a map entitled "Geology of North Carolina" published by the Department in 1985. This map can be obtained for a fee from the North Carolina Geologic Survey,1612 MSC, Raleigh, NC 27699-1612. Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 9 Groundwater in the vicinity of the release is not used as a municipal source of potable water. 6. Subsurface Structures Describe subsurface features, including sewers, utility lines, conduits, basements, vaults, septic tanks, drainfields, etc., referring to Section 2.3 of the Guidelines. Compile this information in Table B-5 and indicate the locations on the potential receptor map. Discuss the risk of explosion due to the accumulation of vapors in confined space and the threat to public health, public safety or the environment posed by vapors in the subsurface features. No basements were observed on the property or adjoining properties. Underground utilities are located along Spring Street. Based on the lack of free product observed at the site, the risk of an explosion hazard at this site is considered low. E. Land Use 1. Property Owners and Occupants Determine the names and addresses of property owners and occupants within or contiguous to the area containing contamination and all property owners and occupants within or contiguous to the area where the contamination is expected to migrate. Compile this information in Table B-6 from the Guidelines, Appendix B, and indicate the property locations on the land use map. Please refer to Table B-6 and Figure 7. 2. Sensitive Land Use Features List features sensitive to impact from the release (schools, daycare centers, nursing homes, hospitals, playgrounds, parks and recreation areas, churches, camps and other places of assembly) and show the zoning status of the area within 1500' of the source of the release Compile this information in Table B-10 from the Guidelines, Appendix B, and indicate the feature locations on the land use map. Sensitive receptors were identified within 1,500 feet of the property and are listed in Table B- 10. The approximate locations of the sensitive receptors are shown on Figure 5. F. Site Geology and Hydrogeology Describe the soil and geology encountered at the site. Discuss the effects of soil and geological characteristics on the migration and attenuation of contaminants. Include information obtained during assessment activities (e.g., lithologic descriptions made during drilling, probe surveys, tank closure, etc). If a Phase II investigation is required include a discussion of groundwater flow direction and hydraulic gradient (vertical and horizontal). The site is underlain by Saprolite consisting of an orange and red sequence of silts and sands from approximately grade to 12 feet below grade. Crystalline bedrock is present from approximately 12 feet below grade to the maximum depth penetrated of 45 feet below grade. Limited Site Assessment 5628 Closeburn Road, Charlotte, NC July 26, 2019 Page No. 10 G. Sampling Results Phase IInvestigation Responsible parties must perform a Phase I investigation for all releases. A Phase I investigation includes the installation of one monitoring well in the source area of a release. Soil samples are to be collected every five feet in the unsaturated zone and should be analyzed in accordance with the methods specified in Table S of the Guidelines, Analytical Methods for Petroleum Contaminated Soil. If the water table is encountered at 25 feet or greater from the land surface, samples for laboratory analysis should be collected every 10 feet in the unsaturated zone. On May 30, 2019, CESI supervised the installation of one monitoring well in the location of the former UST. The boring of the well was conducted by South Atlantic Environmental Drilling and Construction Company (SAEDACCO) of Fort Mill, South Carolina. The boring of well MW-1 was advanced in the middle of the former excavation. The boring was advanced using the hollow stem auger drilling method. The approximate location of the boring is shown on a layout of the property as Figure 4. The first 12-feet of drilling encountered clean imported soil which had been backfilled to the excavation conducted by ECS in May 2019. During the drilling, a 2- foot long, washed, stainless steel spoon was advanced at five-foot intervals. An undisturbed core was retrieved from each of the spoons for observation and field screening by CESI personnel. The boring encountered orange silty sand and fine grained fill from grade to approximately 11- feet below grade. Auger refusal was encountered at 12-feet below grade and no returns were retrieved in the split spoon sampler. CESI directed SAEDACCO switch to air rotary drilling to continue the boring to a depth of 45-feet below grade. No undisturbed soil samples were retrieved during drilling through the rock. For this reason, no soil samples were collected. Suspect minor fractures were observed at approximately 36-feet and 43-feet below grade. No water was indicated during drilling or immediately following drilling. CESI instructed SAEDACCO to install a temporary well consisting of 2-inch diameter PVC. The well was constructed with 15-feet of 0.010-inch machine slotted PVC. A Number 2 filter sand was placed around the screen from the bottom of the well to two -feet above the top of the screen. The well head was covered with plastic and allowed to rest for two days. CESI returned to the site on June 3, 2019, and measured water in the well at a depth of approximately 31-feet from grade. Following purge of the well, CESI personnel collected a water sample intro laboratory provided sample jars. The water samples were immediately placed on ice. The samples were transported using chain -of -custody protocol to Pace Analytical, Inc. (Pace) of Huntersville, North Carolina. CESI requested that the samples be analyzed for Volatile Organic Compounds (VOCs) by EPA Method 8260, Semi-VOCs (SVOCs) by EPA Method 625, and Massachusetts Department of Environmental Protection (MADEP) Volatile Petroleum Hydrocarbons (VPH) and Extractable Petroleum Hydrocarbons (EPH), and Total Chromium and Lead. A summary of the analytical results is provided in Table B-4. Copies of laboratory reports and chain of custody records are provided in Appendix 5. Limited Site Assessment July 26, 2019 5628 Closeburn Road, Charlotte, NC Page No. 11 Phase II Investigation (if required) A Phase H investigation should only be conducted if the release is from a high risk commercial UST and the levels of groundwater contamination detected in the source area monitoring well exceed the groundwater standards or interim standards by a factor of 10. Based on the analytical results, a Phase II investigation is not required. H. Conclusions and Recommendations Discuss the risk criteria that apply to the release and identify any other site -specific factors related to the release that may pose a risk to human health and the environment. Also, discuss any site -specific conditions or possible actions that could result in lowering the level of risk posed by the release. The reported concentration of dissolved naphthalene (1.0 ug/L) and Chromium (6.3 ug/L), in the water sample collected from well MW-1 do not exceed the North Carolina Groundwater Quality 2L Standards. Based on the lack of dissolved parameters exceeding the 2L standards and the lack of adsorbed parameters exceeding the residential use MSCC, No Further Action is recommended. As this site is in the process of being redeveloped and a pending real estate transaction, CESI, on behalf of our client would appreciate a speedy review and return letter approving No Further Action for this incident. I. Free Product Investigation and Recovery (if applicable) No free product was observed at the site. LIST OF FIGURES FIGURE 1 Street Atlas FIGURE 2 Topographic Location Map FIGURE 3 Site Vicinity Map FIGURE 4 Site Layout FIGURE 5 Sensitive Receptor Map FIGURE 6 Adjoining Property Key FIGURE 7 Land Use Map LIST OF TABLES B-1 Site History — UST/AST Information B-2 Site History — Owner/Operator Information B-3 Soil Sample Analytical Results B-4 Groundwater Sample Analytical Results B-5 Receptor Information B-6 Adjoining Parcel Ownership B-7 Well Construction Information Limited Site Assessment July 26, 2019 5628 Closeburn Road, Charlotte, NC Page No. 12 B-8 NOT USED B-9 Groundwater Elevations B-10 Land Use LIST OF APPENDICES APPENDIX 1 DEQ Correspondence APPENDIX 2 Deed and GIS Information APPENDIX 3 Soil and Groundwater Laboratory Report and Chain -of -Custody Record FIGURES r 29 Subject Property 27 49 r { Charlotte 4� 51 Pineville f� _--,C Y r -Nf{ r+ } -- 521� r' FIGURE 1 STREET MAP Not to Scale N ? Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 Subject Property r `VyT'it � t - •, ••� k Ono+ �l {t �Q6 + _ tea # ♦ i r + f ti Al.dp Jw • N� sw 41 4 Y t pp Ir {'h [i 4 FIGURE 2 TOPOGRAPHIC MAP Not to Scale N ? Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 • U*I: Subject Property --:7'.T MO.- - '. FIGURE 3 SITE VICINITY Not to Scale N T Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 Subject Property s W s FIGURE 4 SITE LAYOUT Not to Scale N T Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 DEZI'D Dawde Enan r I - �r y. 1,500-foot G7" 7 radius a x. - - T. FIGURE 5 SENSITIVE Not to Scale N t RECEPTOR MAP Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 3 5 6 I-. '3 °fd r 33 8 33 /J 2 7 5628 4t 0 10 9 8 6 i i FIGURE 6 ADJOINING PROPERTY N t KEY Not to Scale Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 r 1 Park R4adj Par l7evelo ed -12MF(C R-2I(CD-.: Vd k Roeelop '4P/ �a-1� MUDD MUDD-0 \ /r ♦ MU D-0 .D NIUDI ♦ E I JR CD.} 0-1 Fib DD-a 0-2 I --1 0-1(CD) r�fi Butfi 1 F MUD-0 I UDD(CD) - -- - MUDD , Fr R 22MF(C •` 0-3(C UR�G� UDD-.I f f ard Barclay Downs D . `MU N ' ar DDT L� D) .. a-1 ' R-C(C r 0-15(GD'j � MF(CD FIGURE 7 LAND USE MAP Not to Scale N ? Site Name: Byrum Property CONCORD ENGINEERING 5628 Closeburn Rd AND SURVEYING, INC. Charlotte, North Carolina 28210 Project Number: 180453.000 TABLES Appendix B Reporting Tables Table B-1: Site History — UST/AST System and Other Release Information Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Description Was release UST ID Current/Last Previous Capacity (in Construction Tank of Associated Date Tank Status of associated Number Contents * Contents * gallons) Details ** Dimensions Piping and Installed UST *** with the UST Pumps S stem? 1 Heating oil None 550 Single wall 4' diameter Single wall 1955 Removed Yes steel 6' long steel 2019 Add additional records as necessary AST ID Number Current/Last Contents * Previous Contents * Capacity (in gallons) Construction Details ** Tank Dimensions Description of Associated Piping and Pumps Date Tank Installed Status of AST *** Was release associated with the AST System? Add additional records as necessary FIncident Material Date of Description of Release Number Released Release 40792 Heating oil 1/22/18 Soil impacted with heating oil was reported in a boring advanced alongside the heating oil UST as part of a due diligence assessment. Add additional records as necessary * Gasoline (unleaded or leaded), diesel, used oil, waste oil, aviation fuel, etc., or pesticides, non -halogenated or halogenated solvents, etc. ** Fiberglass (single- or double -walled), steel (single- or double -walled), steel with FRP (single- or double -walled), steel with liner, other, unknown. * * * Currently operational, not in use or temporarily closed (specify date), permanently closed in place (specify date), permanently closed by removal (specify date) Change 2 Appendix B Reporting Tables Table B-2: Site History - UST/AST Owner/Operator and Other Responsible Party Information Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property UST ID Number 1 Facility ID Number Name of Owner Dates of Operation mm/dd/ to mm/dd/yy) Parkstone South LLC Current DID NOT OPERATE UST Street Address 568 Jetton Street, Suite 200 City State Zip Telephone Number Davidson NC 28036 Name of Operator Dates of Operation mm/dd/ to mm/dd/ Street Address City State Zip lephone Number Incident Number Name of Other Responsible Party Dates of Release(s) mm/dd/ to mm/dd/ Byrum Land & Timber Inc. (Prior owner) January 22, 2018 Street Address P.O. Box 11795 City State Zip Telephone Number Charlotte NC 128220 Add additional records for all owners, operators and responsible parties as necessary. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Analytical Method (e.g., VOC by EPA 8260) � 8270D 8270D 8270D 8270D 8270D 8260B 8260B 82608 8260B 8260B Contaminant of Concern 4 .y Sample Date Source Sample Incident ID Collected Area Depth Phase p p (m/dd/yy) (eg. (ft BGS) (Closure Tank pit , 20Day, I) LSA, o 4 etc.) 4- Excavat 0.191 B-1 03/22/19 ion 10 Closure 0.28J 0.181 0.48 <0.37 0.0035j 0.0073 0.0089 0.028J 0.0024 bottom J North <0.39 <0.39 <0.39 <0.39 <0.39 <0.005 <0.005 <0.005 <0.051 <0.005 N-1 03/22/19 wall 8 Closure 1 1 I 1 East 0.55 E-1 03/22/19 wall 8 Closure 1.2 0.35J 0.93 0.111 0.012 0.034 0.027 <0.060 0.0060 West 0.34J <0.005 0.0033 0.0044 <0.005 <0.005 W 1 03/22/19 wall 8 Closure 0.87 0.28J 0.80 0.101 2 J J 2 2 Minimum Reporting Limit (mg/kg) 0.39 0.39 0.39 0.39 0.39 0.0051 0.0051 0.0051 0.051 0.0051 Soil to groundwater MSCC (mg/kg) 0.004 3.6 47 56 270 8.5 8.3 0.12 24 1.7 Residential MSCC (mg/kg) 20 63 620 469 469 782 782 100 14000 1564 Industrial/Commercial MSCC (mg/kg) 100 1635 16400 12264 12264 20440 20440 4000 360000 40880 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 12/19/2017 Incident Number and Name: Campus Gas Station Facility ID#: Analytical Method (e.g., VOC by EPA 8260) � 8260B 8260B 8260B 8260B 8260B Contaminant of Concern 4 Sample Date Source Sample Incident ID Collected Area Depth Phase N N Z (m/dd/yy) (eg. (ft BGS) (Closure Tank pit , 20Day, Y 1) LSA,71 a ° a etc.) Z a1 rn F� Excavat B-1 03/22/19 ion 10 Closure 0.033 0.013 <0.005 0.025J 0.0027 bottom 6 J North 0.0028 <0.005 <0.005 <0.005 <0.005 N-1 03/22/19 wall 8 Closure J 1 1 1 1 East 0.073 0.038 0.0036 E-1 03/22/19 wall 8 Closure 0.0076 0.039 J West 0.0047 <0.005 <0.005 W-1 03/22/19 wall 8 Closure 0.020 J 2 0.0077 2 Minimum Reporting Limit (mg/kg) 0.0051 0.0051 0.0051 0.0051 0.0051 Soil to groundwater MSCC (mg/kg) 0.16 4.3 1.7 3.3 3.4 Residential MSCC (mg/kg) 313 626 626 626 626 Industrial/Commercial MSCC (mg/kg) 8176 16350 16350 16350 16350 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Analytical Method (e.g., VOC by EPA 8260) 8270D 8270D 8270D 8270D 8270D 8260B 8260B 8260B 8260B 8260B Contaminant of Concern 4 y y Sample Date Source Sample Incident ID Collected Area Depth Phase Q p (m/dd/yy) (eg. (ft BGS) (Closure Tank pit 20Day, 1 LSA, 4 o 0 0 etc. C—'� - o South <0.40 <0.40 <0.40 <0.40 <0.40 <0.006 <0.006 <0.006 <0.063 <0.006 S-1 03/22/19 wall 8 Closure 3 3 3 3 Minimum Reporting Limit (mg/kg) 0.39 0.39 0.39 0.39 0.39 0.0051 0.0051 0.0051 0.051 0.0051 Soil to groundwater MSCC (mg/kg) 0.004 3.6 47 56 270 8.5 8.3 0.12 24 1.7 Residential MSCC (mg/kg) 20 63 620 469 469 782 782 100 14000 1564 Industrial/Commercial MSCC (mg/kg) 100 1635 16400 12264 1 12264 1 20440 1 20440 1 4000 1 360000 40880 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Analytical Method (e.g., VOC by EPA 8260) � 8260B 8260B 8260B 8260B 8260B Contaminant of Concern 4 Sample Date Source Sample Incident ID Collected Area Depth Phase N (m/dd/yy) (eg. (ft BGS) (Closure Q Tank pit 20Day, y 1) LSA, P� etc. F� South <0.006 <0.006 <0.006 <0.006 <0.006 S-1 03/22/19 wall 8 Closure 3 3 3 3 3 Minimum Reporting Limit (mg/kg) 0.0051 0.0051 0.0051 0.0051 0.0051 Soil to groundwater MSCC (mg/kg) 0.16 4.3 1.7 3.3 3.4 Residential MSCC (mg/kg) 313 626 626 626 626 Industrial/Commercial MSCC (mg/kg) 8176 16350 16350 16350 16350 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 12/19/2017 Incident Number and Name: Campus Gas Station Facility ID#: Analytical Method (e.g., VOC by EPA 8260) Contaminant of Concern 4 o, U a o, U a N U a o U U a U U a o U U a Sample ID Date Collected (m/dd/yy) Source Area (eg. Tank pit 1) Sample Depth (ft BGS) Incident Phase (Closure , 20Day, LSA, etc. S-1 03/22/19 South wall 8 Closure <30 <30 <12 <22 <22 <22 Minimum Reporting Limit (mg/kg) 29 29 11 20 19 19 Soil to groundwater MSCC (mg/kg) 540 31 68 540 31 Residential MSCC (mg/kg) 1500 31000 469 939 1500 469 Industrial/Commercial MSCC (mg/kg) 40000 810000 12264 24528 40000 12264 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-3: Summary of Soil Sampling Results (FROM CLOSURE REPORT) Revision Date: 12/19/2017 Incident Number and Name: Campus Gas Station Facility ID#: Analytical Method (e.g., VOC by EPA 8260) Contaminant of Concern 4 N o o Sample Date Source Sample Incident ID Collected Area Depth Phase U U U (m/dd/yy) (eg. (ft BGS) (Closure o, o, Tank pit , 20Day, U U U U U U 1) LSA, a a a a a a etc. Excavat B-1 03/22/19 ion 10 Closure 270 70 200 <20 36 36 bottom North <29 <29 <11 <19 <19 N-1 03/22/19 wall 8 Closure <19 East 160 50 E-1 03/22/19 wall 8 Closure 140 <20 43 21 West W-1 03/22/19 wall 8 Closure 220 75 170 <20 17J 9.81 Minimum Reporting Limit (mg/kg) 29 29 11 20 19 19 Soil to groundwater MSCC (mg/kg) 540 31 68 540 31 Residential MSCC (mg/kg) 1500 31000 469 939 1500 469 Industrial/Commercial MSCC (mg/kg) 40000 810000 12264 24528 40000 12264 Indicate detection limit for contaminants when analyzed, but not detected List any contaminant detected above the method detection limit MSCC = maximum soil contaminant concentration ft. BGS = feet below ground surface Results must be reported in mg/kg. mg/kg =milligrams per kilogram (e.g., < 1, 10, 42) Yellow shading indicates exceedance of Soil to Groundwater MSCC. Red shading indicates exceedance of Residential MSCC. Change 2 Appendix B Reporting Tables Table B-4: Summary of Groundwater and Surface Water Sampling Results Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Analytical Method (e.g., VOC by SM600013) or EPA Field Measurement (FM)-> 8260n 6oioD Contaminant of Concern/ Field Measurement4 Well or Date Sample Incident , SW ID Collected ID Phase (Closure, y 2013ay, o LSA, etc. HU MW-1 06/03/2019 Water LSA 1.0 6.3 Minimum Reporting Limit (ug/1) 1.0 5.0 2L Standard (ug/1) 6 10 GCL (ug/1) 6000 10000 NC 2B Standard or EPA National Criteria (ug/1) Field measurement parameters include temperature, pH, dissolved oxygen, specific conductivity, Eh, and alkalinity Indicate detection limit for contaminants when analyzed, but not detected (e.g., < 1, 10, 42) List any contaminant detected above the method detection limit Results for contaminants must be reported in ug/l µg/1=micrograms per liter GCL = gross contamination level Yellow shading indicates exceedance of NCAC 2L. Red shading indicates exceedance of GCL Change 2 Appendix B Reporting Tables Table B-5: Public and Private Water Supply Well and Other Receptor Information Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Public and Private Water Supply Wells Facility ID#: Latitude/ Distance Longitude * Well Well Well from Well Owner/ User (decimal Well Depth Type Casing Screen source s. a o Well # (indicate which) Address Phone Number degrees) Use (ft of Depth (ft. Interval area of p � BGS) Well BGS) `x to y ft. release ** BGS) (ft.) Other Receptors (Other public water supplies reservoirs, supply lines surface water bodies, wellhead protection areas recharge areas for deep aquifers subsurface structures) Latitude/ Longitude of Up or Distance from Receptor Description Location * any significant point(s) Contact Phone Usage down- source area of ID (describe to left) Number (decimal degrees) gradient release (ft.) 1 Stream (in pipe) South of release 35.149089/-80.845363 None Down 205 2 Park Road Park West of release 35.174884/-80.848570 Puab is Cross 1150 pk 3 Lake West of release 35.149427/-80.849556 None Cross 1186 4 Ivey Memory Day East of Release 35.149656/-80.843813 704-909- Senior Cross 380 Center 2070 Center 35.150122/-80.843016 Assiste 5 Brighton Gardens Northeast of Release 704-643- d Up 649 1400 Living * The location must be sufficiently accurate and precise to allow easy recovery of lost or damaged wells or replication of sampling points. ** Ft BGS = feet below ground surface 10 Change 2 Appendix B Reporting Tables Table B-6: Property Owners/ Occupants Revision Date: 7/26/2019 Incident Number and Name: 40792 Byrum Property Facility ID#: Tax Parcel Owner/ Occupant Name Number/ Address (Last, First MI) Map ID Cooper, Donnell and Karen B 17125222 /1 5615 Glenkirk Road, Charlotte, NC 28210 Copper Builders LLC 17125207 /2 1235 E Blvd Unit 155, Charlotte, NC 28203 Marrongelie, Kevin 17125155/3 5617 Closeburn Road, Charlotte, NC 28210 Bramley, Thomas J 17125156/4 5621 Closeburn Road, Charlotte, NC 28210 Travis, Van B 17125113 /5 5629 Closeburn Road, Charlotte, NC 28210 Lippard, John B 17125219 /6 5700 Closeburn Road, Charlotte, NC 28210 Green, Ned F 17125226 /7 5728 Glenkirk Road, Charlotte, NC 28210 Borachok, Gregg 17125227 /8 5700 Glenkirk Road, Charlotte, NC 28210 Sass, Daniel A 17125228 /9 5460 Glenkirk Road, Charlotte, NC 28210 Anderson, William M 17125229 /10 5634 Glenkirk Road, Charlotte, NC 28210 11 Change 2 Appendix B Reporting Tables Table B-7: Monitoring and Remediation Well Construction Information Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Well ID Date Installed (m/dd/yy) Date Water Level Measured (m/dd/yy) Well Casing Diameter (in.) Well Casing Depth (ft. BGS Screened Interval (x to y ft. BGS) Depth of Well (ft. BGS) Top of Casing Elevation* (ft.) Depth to Water from Top of Casing ft. Free Product Thickness ** (ft.) Groundwater Elevation* (ft.) Latitude/ Longitude (decimal degrees)*** MW-1 05/31/19 06/03/19 2 458 30-45 45 NM 31 None NM 35.149821/ -80.845903 ft BGS = feet below ground * Reference Point for Elevation Measurements , Assumed Elevation: ft. ** If free product is present in a well, groundwater elevation is calculated by: [Top of Casing Elevation - Depth to Water] + [free product thickness x 0.8581] *** The location must be sufficiently accurate and precise to allow easy recovery of lost or damaged wells. 12 Change 2 Appendix G Contaminant Sources Other than USTs Table B-9: Current and Historical Groundwater Elevations and Free Product Thickness Revision Date: 7/26/2019_ Incident Number and Name: 40792 Byrum Property Facility ID#: Well ID # Date Screened Interval (top of screen, bottom of screen) Depth to Water* Uncorrected (feet) Free Product Thickness feet Depth to Water* Corrected for Free Product Thickness feet) Top of Casing Elevation (MSL) Groundwater Surface Elevation (MSL MW-1 06/03/19 30-45 31 NA 31 NM NM *Depth to Water is measured from Top of Casing 14 Change 2 Appendix G Contaminant Sources Other than USTs Table B-10: Land Use Revision Date: 17/26/2019 Incident Number and Name: 40792 Byrum Property Facility ID#: Map ID # Date Determined Land Use Feature (include zoning) Location (complete street address if applicable) Distance and Direction from Source Area N,S,E,W of property 07/26/2019 Residential (R-3) Subject Property and adjoining properties 250 feet radial (except southeast SE of property 7/26/2019 Residential (R- 8MF) 250 feet southeast of property 250 feet southeast of pproperty 15 Change 2 APPENDIX I ROY COOPER Governor MICHAEL S. REGAN Secrerary MICHAEL SCOTT Director Sandra Gravely, President Byrum Land & Timber, Inc. P.O. Box 11795 Charlotte, NC 28220 (via email) Dear Ms. Gravely: NORTH CAROLINA Environmental Quality August 29, 2018 Re: Notice of Regulatory Requirements 15A NCAC 2L .0404 and 2L .0405 Risk -based Assessment and Corrective Action for Petroleum Underground Storage Tanks Byrum Property 5628 Closeburn Road, Charlotte Mecklenburg County Incident Number:40792 Risk Classification: Unknown Information received by this office of the UST Section, Division of Waste Management, on January 29, 2018 confirms a release or discharge from a petroleum underground storage tank (UST) system at the above -referenced location. Records indicate that you are the owner or operator of this UST system. Therefore, as a responsible party, you must comply with the initial response and abatement action requirements of Title 15A NCAC 2L .0404 and, if applicable, the assessment and reporting requirements of Title 15A NCAC 2L .0405, within the timeframes specified in the attached rules. (Be aware that if the latter rule is applicable, you must comply with its requirements even if you do not receive formal notification from the UST Section.) Initial abatement action requirements include the preparation and submittal of an Initial Abatement Action (IAA) Report, in accordance with Title 15A NCAC 2L .0404 and the most recent version of the Guidelines for Site Checks, Tank Closure, and Initial Response and Abatement for UST Releases, within 90 days of discovery of the release. Because a release or discharge has been confirmed, a Licensed Geologist or a Professional Engineer, certified by the State of North Carolina, is required to prepare and certify all reports submitted to the Department of Environmental Quality in accordance with Title 15A NCAC 2L .0103(e) and 2L .0111(b). NORTH C+4RpL D E Q u�prmwry of EmlmmYeHsl 9� North Carolina Department of Environmental Quality I Division of Waste Management Mooresville Regional Office 1 610 East Center Avenue, Suite 301 1 Mooresville. North Carolina 28115 704.663.1699 Please note that before you sell, transfer, or request a "No Further Action" determination for a property that has not been remediated to below "unrestricted use" standards, you must file a Notice of Residual Petroleum ("Notice") with the Register of Deeds in the county where the property is located (NCGS 14313-279.9 and 14313- 279.11). Failure to comply with the State's rules in the manner and time specified may result in the assessment of civil penalties and/or the use of other enforcement mechanisms. If you have any questions regarding the actions that must be taken or the rules mentioned in this letter, please contact me by phone at (704) 235-2182 or by email at Trudy.Beverlynncdenr.gov. Sincerely, a-1Y1- Zevad�, Trudy Beverly, L.G. Hydrogeologist Mooresville Regional Office UST Section, Division of Waste Management, NCDEQ cc: Shawna Caldwell, Mecklenburg County Groundwater & Wastewater Services Patrick Lowery, Summit Engineering (via email) NORTH C.4R0.'+1A�E Q� un of En- r,nn H-, 9Nor North Carolina Department of Environmental Quality I Division of Waste Management Mooresville Regional Office 1 610 East Center Avenue, Suite 301 1 Mooresville. North Carolina 28115 704.663.1699 Beverly, Trudy From: Beverly, Trudy Sent: Wednesday, August 29, 2018 2:49 PM To: sgravely2016@gmail.com' Cc: plowery@summit-companies.com' Subject: Byrum Property #40792 — Notice of Regulatory Requirements Letter Attachments: MO-9331_40792_G_NORR_20180829_NORR for Initial Assessment.pdf Ms. Gravely, It was lovely speaking with you this afternoon. As we discussed by phone, the Notice of Regulatory Requirements letter for the Byrum Property (UST incident number 40792) is attached to this email. Electronic files for this site can be found on Laserfiche at the following link for viewing and downloading, https://edocs.deg.nc.gov/WasteManagement/Search.aspx?dbid=0&searchcommand=%7B%SBWM%5D%3A%SBProgra m ID%5D%3D%22%2AMO-9331%2A%22%7D&cr=1. Below you will find some general information about home heating oil underground storage tanks: Home heating oil underground storage tanks are not and haven't been regulated in the state of North Carolina. The UST section only has records of those that have been reported to our agency. These reports a generally result from notifications of contamination or tank removals at properties where parties are seeing "no further action" status. Home heating oil tanks are non -regulated, non-commercial underground storage tanks (USTs) that are exempt from the "technical regulations" (e.g., leak detection monitoring, corrosion protection, spill and overfill control) that apply to regulated USTs. Even though home heating oil tanks are exempt from these technical regulations, sampling and cleanup regulations may apply if there is a leak or spill from your tank. If there is no evidence of a release, then there is no need to report to the UST Section. The links below provide additional information. If a leak is discovered under the current ownership of the property, the current property owner is considered the responsible party for clean-up. Many companies do environmental work related to underground storage tanks. Typically, they can be found in the yellow pages of a telephone book under "Environmental Consultants." The DWM UST Section provides a list where companies that do environmental work can provide their information. This list is called the "UST Service Provider Listing" it is located at http://deg.nc.gov/about/divisions/waste-management/ust/service- provider-listing. When choosing a company, we recommend getting several estimates and references. Site assessments and cleanup work must be conducted under the responsible charge of a licensed geologist or professional engineer. Please note that before you sell, transfer, or request a "No Further Action" determination for a property that has not been remediated to below "unrestricted use" standards, you must file a Notice of Residual Petroleum ("Notice") with the Register of Deeds in the county where the property is located (NCGS 143B-279.9 and 14313- 279.11). Underground — Heating Oil Tanks Non -Regulated Underground Storage Tanks — Frequently Asked Questions https://files.nc.gov/ncdeq/Waste%20Management/DWM/UST/Brochures-FAQs/Brochure-NonReg%20UST.Of Home Heating Oil Underground Storage Tanks — General Guidance https://files.nc.gov/ncdeq/Waste%20Management/DWM/UST/Brochures-FAQs/FAQ-Home%20Heating%20UST.Of Non -Regulated Noncommercial Petroleum UST Systems (Underground Heating Oil Tanks) Flowchart https://files.nc.gov/ncdeq/Waste%20Management/DWM/UST/Brochures- FAQs/H HO%20Tank%20Flowchart%20070717.odf Guidelines for Site Checks, Tank Closure and Initial Response (text and figures) "Portions that are Non -Regulated and Non -Regulated and Non -Commercial https://deg.nc.gov/about/divisions/waste-management/ust/guidance-documents Have a wonderful day, Trudy D�E NC RTH C;AR01. INA Department of Environmental quality Trudy Beverly, LG. Hydrogeologist, Division of Waste Management North Carolina Department of Environment Quality Underground Storage Tanks Section Corrective Action Branch Mooresville Regional Office (704) 235-2182 (Office) Trudy.Beverly@ncdenr.gov Er7k d C0fMSPQrxjL5,nC0 to and Yom this swans of wbjeCt to the Wh C rdire P. :; Regards Law aW may be dis� to third parries. Branch's Underground Storage Tanks Website Address: https://deg.nc.gov/about/divisions/waste-management/ust Branch's Above Ground Storage Tanks Website Address: https://deg.nc.gov/about/divisions/waste- management/ust/ast-program INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES: https://deg.nc.gov/about/divisions/waste-management/waste-management-rules-data/waste-management-gis-maps File Review Procedures: https://deg.nc.gov/about/divisions/waste-management/ust/file-review-procedures#mooresville-regional-office ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche): https://edocs.deg.nc.gov/WasteManagement/Search.aspx Document Submittal & UST File Names for Laserfiche Policies: https://files.nc.gov/ncdeg/Waste%20Management/DWM/UST/Corrective%2OAction/Electronic%2ODocument%2OSubmi ttal%20Memo%2OUpdate.pdf https://files.nc.gov/ncdeg/Waste%20Management/DWM/UST/Corrective%2OAction/UST%2Ofile%20names%20for%20 Laserfiche.docx APPENDIX 2 MECKLENBURG COUNTY — PROPERTY RECORD CARD PROPERTY SEARCH PARCEL ID: 17125220 PARKSTONE SOUTH LLC Total Appraised Value 5628 CLOSEBURN RD 568 JETTON ST STE 200 $1,046,000 CHARLOTTE NC DAVIDSON NC 28036 KEY INFORMATION Land Use Code R100 Neighborhood R120 Land Use Desc SINGLE FAMILY RESIDENTIAL Land 2.761 ACRE Exemption/Deferment - Municipality CHARLOTTE Last Sale Date 12/21/2018 Fire District CITY OF CHARLOTTE Last Sale Price $990,000 Special District NA Legal Description L11 M64-490 ASSESSMENT DETAILS Notice of 2019 Real Estate Assessed Value Land Value $1,043,700 Building Value $2,300 Features $0 Total $1,046,000 BUILDING (1) Finished Area 1,832 Year Built 1955 Built Use / Style SINGLE FAMILY RESIDENTIAL Story 1 STORY Heat FORCED AIR - Fuel GAS DUCTED Foundation CRAWL SPACE External Wall FACE BRICK Fireplace(s) 1 Full Bath(s) 2 Half Bath(s) Bedroom(s) 3 Total (SgFt) 3,045 LAND Use Units Type Neighborhood Assessment R100 2.761 ACRE R120 $1,043,700 RECENT SALES HISTORY The sales history includes only qualified sales made since January 1, 2016. A sale is qualified when it has been verified, by the appraiser, as an arm's length transaction for fair market value. Only qualified sales are considered in the appraisal process. For a complete history of sales and other transfers, please visit Polaris. The Register of Deeds records, indexes, and stores all real estate related documents that are presented for registration. Sale Date Sale Price LUC at Sale Legal Reference Deed Type Sold as Vacant Grantor Grantee 12/21/2018 $990,000 R100 33190-610 SPECIAL WARRANTY DEED No BYRUM LAND & TIMBER INC PARKSTONE SOUTH LLC VALUE CHANGES The value change history shows only changes in appraised value; it does not show exemptions, exclusions or deferrals that could reduce a property's taxable value. If any of these are in effect for a particular tax year, it will be shown on the property tax bill for that year. It is also possible that some previous value changes might be missing from this list or listed in the wrong order. If you have any questions, please call the County Assessor's Office at 704-336-7600. Date of Value Change Effective for Tax Year Reason for Change New Value 01/15/2019 2019 COUNTYWIDE REVALUATION $1,046,000 11 /09/2014 2011 REVALUATION REVIEW - PEARSON $676,400 02/04/2011 2011 COUNTYWIDE REVALUATION $800,700 01/02/2003 2003 COUNTYWIDE REVALUATION $373,100 I I, �5 200 ft Disclaimer Mecklenburg County makes every effort to produce the most accurate information possible. No warranties, expressed or implied, are provided for the data herein, its use or interpretation. https://property.spatialest.com/nc/mecklenburg/#/property/177855/print 2/2 APPENDIX 3 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 June 06, 2019 Mr. Steve Irminger Irminger Consulting 7015 Erinbrook Road Concord, NC 28025 RE: Project: Water Pace Project No.: 92431399 Dear Mr. Irminger: Enclosed are the analytical results for sample(s) received by the laboratory on June 03, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Tyriek Hooks tyriek.hooks@pacelabs.com (704)875-9092 Project Manager Enclosures REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 26 acmnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Water Pace Project No.: 92431399 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 Asheville Certification IDS 2225 Riverside Drive, Asheville, NC 28804 Florida/NELAP Certification #: E87648 Massachusetts Certification #: M-NC030 North Carolina Drinking Water Certification #: 37712 CERTIFICATIONS South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 North Carolina Wastewater Certification #: 40 South Carolina Certification #: 99030001 Virginia/VELAP Certification #: 460222 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 SAMPLE ANALYTE COUNT Project: Pace Project No.: Water 92431399 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92431399001 MW-1 MADEP EPH SEM 7 PASI-C MADEP VPH LMB 6 PASI-C EPA 6010D IDS 2 PASI-A EPA 625.1 PKS 58 PASI-C EPA 8260D DLK 63 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Water Pace Project No.: 92431399 Sample: MWA Lab ID: 92431399001 Collected: 06/03/19 09:00 Received: 06/03/19 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual MADEP EPH NC Water Analytical Method: MADEP EPH Preparation Method: MADEP EPH Aliphatic (C09-C18) ND ug/L 98.0 1 06/03/19 18:38 06/05/19 16:35 N2 Aliphatic (C19-C36) ND ug/L 98.0 1 06/03/19 18:38 06/05/19 16:35 N2 Aromatic (C11-C22) ND ug/L 98.0 1 06/03/19 18:38 06/05/19 16:35 N2 Surrogates Nonatriacontane (S) 55 % 40-140 1 06/03/19 18:38 06/05/19 16:35 7194-86-7 o-Terphenyl (S) 84 % 40-140 1 06/03/19 18:38 06/05/19 16:35 84-15-1 2-Fluorobiphenyl (S) 88 % 40-140 1 06/03/19 18:38 06/05/19 16:35 321-60-8 2-Bromonaphthalene (S) 85 % 40-140 1 06/03/19 18:38 06/05/19 16:35 580-13-2 VPH NC Water Analytical Method: MADEP VPH Aliphatic (C05-008) ND ug/L 50.0 1 06/04/19 13:45 N2 Aliphatic (C09-C12) ND ug/L 50.0 1 06/04/19 13:45 N2 Aliphatic(C09-C12) Adjusted ND ug/L 50.0 1 06/04/19 13:45 N2 Aromatic (C09-C10) ND ug/L 50.0 1 06/04/19 13:45 N2 Surrogates 4-Bromofluorobenzene (FID) (S) 93 % 70-130 1 06/04/19 13:45 460-00-4 4-Bromofluorobenzene (PID) (S) 91 % 70-130 1 06/04/19 13:45 460-00-4 6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A Chromium 6.3 ug/L 5.0 1 06/04/19 00:45 06/04/19 20:25 7440-47-3 Lead ND ug/L 5.0 1 06/04/19 00:45 06/04/19 20:25 7439-92-1 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Acenaphthene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 83-32-9 Acenaphthylene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 208-96-8 Anthracene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 120-12-7 Benzo(a)anthracene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 56-55-3 Benzo(a)pyrene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 50-32-8 Benzo(b)fluoranthene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 205-99-2 Benzo(g,h,i)perylene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 191-24-2 Benzo(k)fluoranthene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 207-08-9 4-Bromophenylphenyl ether ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 101-55-3 Butylbenzylphthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 85-68-7 4-Chloro-3-methyl phenol ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 59-50-7 bis(2-Chloroethoxy)methane ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 111-91-1 bis(2-Chloroethyl) ether ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 111-44-4 2-Chloronaphthalene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 91-58-7 2-Chlorophenol ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 95-57-8 4-Chlorophenylphenyl ether ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 7005-72-3 Chrysene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 218-01-9 Dibenz(a,h)anthracene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 53-70-3 3,3'-Dichlorobenzidine ND ug/L 25.0 1 06/05/19 14:47 06/05/19 21:33 91-94-1 2,4-Dichlorophenol ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 120-83-2 Diethylphthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 84-66-2 2,4-Dimethylphenol ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 105-67-9 Dimethylphthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 131-11-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Water Pace Project No.: 92431399 Sample: MW-1 Parameters ANALYTICAL RESULTS Lab ID: 92431399001 Collected: 06/03/19 09:00 Received: 06/03/19 14:35 Matrix: Water Results Units Report Limit DF Prepared Analyzed CAS No. Qual 625 RVE Analytical Method: EPA 625.1 Preparation Method: EPA 625.1 Di-n-butylphthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 84-74-2 4,6-Dinitro-2-methyl phenol ND ug/L 20.0 1 06/05/19 14:47 06/05/19 21:33 534-52-1 2,4-Dinitrophenol ND ug/L 50.0 1 06/05/19 14:47 06/05/19 21:33 51-28-5 2,4-Dinitrotoluene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 121-14-2 2,6-Dinitrotoluene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 606-20-2 Di-n-octylphthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 117-84-0 bis(2- Ethyl hexyl)phthalate ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 117-81-7 Fluoranthene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 206-44-0 Fluorene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 86-73-7 Hexachloro-1,3-butadiene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 87-68-3 Hexachlorobenzene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 118-74-1 Hexachlorocyclopentadiene ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 77-47-4 Hexachloroethane ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 67-72-1 Indeno(1,2,3-cd)pyrene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 193-39-5 Isophorone ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 78-59-1 Naphthalene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 91-20-3 Nitrobenzene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 98-95-3 2-Nitrophenol ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 88-75-5 4-Nitrophenol ND ug/L 50.0 1 06/05/19 14:47 06/05/19 21:33 100-02-7 N-Nitrosodimethylamine ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 62-75-9 N-Nitroso-di-n-propylamine ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 621-64-7 N-Nitrosodiphenylamine ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 86-30-6 2,2'-Oxybis(1-chloropropane) ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 108-60-1 Pentachlorophenol ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 87-86-5 Phenanthrene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 85-01-8 Phenol ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 108-95-2 Pyrene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 129-00-0 1,2,4-Trichlorobenzene ND ug/L 5.0 1 06/05/19 14:47 06/05/19 21:33 120-82-1 2,4,6-TrichIorophenol ND ug/L 10.0 1 06/05/19 14:47 06/05/19 21:33 88-06-2 Surrogates Nitrobenzene-d5 (S) 73 % 10-120 1 06/05/19 14:47 06/05/19 21:33 4165-60-0 2-Fluorobiphenyl (S) 65 % 15-120 1 06/05/19 14:47 06/05/19 21:33 321-60-8 Terphenyl-d14 (S) 94 % 11-131 1 06/05/19 14:47 06/05/19 21:33 1718-51-0 Phenol-d6 (S) 42 % 10-120 1 06/05/19 14:47 06/05/19 21:33 13127-88-3 2-Fluorophenol (S) 59 % 10-120 1 06/05/19 14:47 06/05/19 21:33 367-12-4 2,4,6-Tribromophenol (S) 83 % 10-137 1 06/05/19 14:47 06/05/19 21:33 118-79-6 8260D MSV Low Level Analytical Method: EPA 8260D Acetone ND ug/L 25.0 1 06/05/19 19:34 67-64-1 Benzene ND ug/L 1.0 1 06/05/19 19:34 71-43-2 Bromobenzene ND ug/L 1.0 1 06/05/19 19:34 108-86-1 Bromochloromethane ND ug/L 1.0 1 06/05/19 19:34 74-97-5 Bromodichloromethane ND ug/L 1.0 1 06/05/19 19:34 75-27-4 Bromoform ND ug/L 1.0 1 06/05/19 19:34 75-25-2 Bromomethane ND ug/L 2.0 1 06/05/19 19:34 74-83-9 2-Butanone (MEK) ND ug/L 5.0 1 06/05/19 19:34 78-93-3 Carbon tetrachloride ND ug/L 1.0 1 06/05/19 19:34 56-23-5 REPORT OF LABORATORY ANALYSIS M This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 5 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Water Pace Project No.: 92431399 Sample: MW-1 Lab ID: 92431399001 Collected: 06/03/19 09:00 Received: 06/03/19 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method: EPA 8260D Chlorobenzene ND ug/L 1.0 1 06/05/19 19:34 108-90-7 Chloroethane ND ug/L 1.0 1 06/05/19 19:34 75-00-3 Chloroform ND ug/L 5.0 1 06/05/19 19:34 67-66-3 Chloromethane ND ug/L 1.0 1 06/05/19 19:34 74-87-3 2-Chlorotoluene ND ug/L 1.0 1 06/05/19 19:34 95-49-8 4-Chlorotoluene ND ug/L 1.0 1 06/05/19 19:34 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 5.0 1 06/05/19 19:34 96-12-8 Dibromochloromethane ND ug/L 1.0 1 06/05/19 19:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 1.0 1 06/05/19 19:34 106-93-4 Dibromomethane ND ug/L 1.0 1 06/05/19 19:34 74-95-3 1,2-Dichlorobenzene ND ug/L 1.0 1 06/05/19 19:34 95-50-1 1,3-Dichlorobenzene ND ug/L 1.0 1 06/05/19 19:34 541-73-1 1,4-Dichlorobenzene ND ug/L 1.0 1 06/05/19 19:34 106-46-7 Dichlorodifluoromethane ND ug/L 1.0 1 06/05/19 19:34 75-71-8 1,1-Dichloroethane ND ug/L 1.0 1 06/05/19 19:34 75-34-3 1,2-Dichloroethane ND ug/L 1.0 1 06/05/19 19:34 107-06-2 1,1-Dichloroethene ND ug/L 1.0 1 06/05/19 19:34 75-35-4 cis-1,2-Dichloroethene ND ug/L 1.0 1 06/05/19 19:34 156-59-2 trans-1,2-Dichloroethene ND ug/L 1.0 1 06/05/19 19:34 156-60-5 1,2-Dichloropropane ND ug/L 1.0 1 06/05/19 19:34 78-87-5 1,3-Dichloropropane ND ug/L 1.0 1 06/05/19 19:34 142-28-9 2,2-Dichloropropane ND ug/L 1.0 1 06/05/19 19:34 594-20-7 1,1-Dichloropropene ND ug/L 1.0 1 06/05/19 19:34 563-58-6 cis-1,3-Dichloropropene ND ug/L 1.0 1 06/05/19 19:34 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 06/05/19 19:34 10061-02-6 Diisopropyl ether ND ug/L 1.0 1 06/05/19 19:34 108-20-3 Ethylbenzene ND ug/L 1.0 1 06/05/19 19:34 100-41-4 Hexachloro-1,3-butadiene ND ug/L 1.0 1 06/05/19 19:34 87-68-3 2-Hexanone ND ug/L 5.0 1 06/05/19 19:34 591-78-6 p-Isopropyltoluene ND ug/L 1.0 1 06/05/19 19:34 99-87-6 Methylene Chloride ND ug/L 5.0 1 06/05/19 19:34 75-09-2 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 06/05/19 19:34 108-10-1 Methyl-tert-butyl ether ND ug/L 1.0 1 06/05/19 19:34 1634-04-4 Naphthalene 1.0 ug/L 1.0 1 06/05/19 19:34 91-20-3 Styrene ND ug/L 1.0 1 06/05/19 19:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 06/05/19 19:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 06/05/19 19:34 79-34-5 Tetrachloroethene ND ug/L 1.0 1 06/05/19 19:34 127-18-4 Toluene ND ug/L 1.0 1 06/05/19 19:34 108-88-3 1,2,3-Trichlorobenzene ND ug/L 1.0 1 06/05/19 19:34 87-61-6 1,2,4-Trichlorobenzene ND ug/L 1.0 1 06/05/19 19:34 120-82-1 1,1,1-Trichloroethane ND ug/L 1.0 1 06/05/19 19:34 71-55-6 1,1,2-Trichloroethane ND ug/L 1.0 1 06/05/19 19:34 79-00-5 Trichloroethene ND ug/L 1.0 1 06/05/19 19:34 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 06/05/19 19:34 75-69-4 1,2,3-Trichloropropane ND ug/L 1.0 1 06/05/19 19:34 96-18-4 Vinyl acetate ND ug/L 2.0 1 06/05/19 19:34 108-05-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 ANALYTICAL RESULTS Project: Water Pace Project No.: 92431399 Sample: MW-1 Lab ID: 92431399001 Collected: 06/03/19 09:00 Received: 06/03/19 14:35 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Low Level Analytical Method: EPA 8260D Vinyl chloride ND ug/L 1.0 1 06/05/19 19:34 75-01-4 Xylene (Total) ND ug/L 1.0 1 06/05/19 19:34 1330-20-7 m&p-Xylene ND ug/L 2.0 1 06/05/19 19:34 179601-23-1 o-Xylene ND ug/L 1.0 1 06/05/19 19:34 95-47-6 Surrogates 4-Bromofluorobenzene (S) 97 % 70-130 1 06/05/19 19:34 460-00-4 1,2-Dichloroethane-d4 (S) 94 % 70-130 1 06/05/19 19:34 17060-07-0 Toluene-d8 (S) 101 % 70-130 1 06/05/19 19:34 2037-26-5 Date: 06/06/2019 05:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 QC Batch: 478940 Analysis Method: MADEP VPH QC Batch Method: MADEP VPH Analysis Description: VPH NC Water Associated Lab Samples: 92431399001 METHOD BLANK: 2592184 Associated Lab Samples: 92431399001 Parameter Units Aliphatic (C05-008) ug/L Aliphatic (C09-C12) ug/L Aromatic (C09-C10) ug/L 4-Bromofluorobenzene (FID) (S) % 4-Bromofluorobenzene (PID) (S) % Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 50.0 06/04/1913:16 N2 ND 50.0 06/04/1913:16 N2 ND 50.0 06/04/1913:16 N2 98 70-130 06/04/1913:16 96 70-130 06/04/1913:16 LABORATORY CONTROL SAMPLE & LCSD: 2592185 2592186 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Aliphatic (C05-CO8) ug/L 300 244 234 81 78 70-130 4 25 N2 Aliphatic (C09-C12) ug/L 300 297 292 99 97 30-130 2 25 N2 Aromatic (C09-C10) ug/L 100 95.3 94.0 95 94 70-130 1 25 N2 4-Bromofluorobenzene (FID) (S) % 105 98 70-130 4-Bromofluorobenzene (PID) (S) % 102 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 QC Batch: 478810 Analysis Method: EPA 6010D QC Batch Method: EPA 3010A Analysis Description: 6010 MET Associated Lab Samples: 92431399001 METHOD BLANK: 2591738 Matrix: Water Associated Lab Samples: 92431399001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chromium ug/L ND 5.0 06/04/1919:15 Lead ug/L ND 5.0 06/04/1919:15 LABORATORY CONTROL SAMPLE: 2591739 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chromium ug/L 500 441 88 80-120 Lead ug/L 500 442 88 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2591740 2591741 MS MSD 92430283001 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Chromium ug/L ND 500 500 521 507 104 101 75-125 3 Lead ug/L ND 500 500 507 495 101 99 75-125 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 QC Batch: 479106 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Low Level Associated Lab Samples: 92431399001 METHOD BLANK: 2592936 Associated Lab Samples: 92431399001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 06/05/19 13:22 1,1,1-Trichloroethane ug/L ND 1.0 06/05/19 13:22 1,1,2,2-Tetrachloroethane ug/L ND 1.0 06/05/19 13:22 1,1,2-Trichloroethane ug/L ND 1.0 06/05/19 13:22 1,1-Dichloroethane ug/L ND 1.0 06/05/19 13:22 1,1-Dichloroethene ug/L ND 1.0 06/05/19 13:22 1,1-Dichloropropene ug/L ND 1.0 06/05/19 13:22 1,2,3-Trichlorobenzene ug/L ND 1.0 06/05/19 13:22 1,2,3-Trichloropropane ug/L ND 1.0 06/05/19 13:22 1,2,4-Trichlorobenzene ug/L ND 1.0 06/05/19 13:22 1,2-Dibromo-3-chloropropane ug/L ND 5.0 06/05/19 13:22 1,2-Dibromoethane (EDB) ug/L ND 1.0 06/05/19 13:22 1,2-Dichlorobenzene ug/L ND 1.0 06/05/19 13:22 1,2-Dichloroethane ug/L ND 1.0 06/05/19 13:22 1,2-Dichloropropane ug/L ND 1.0 06/05/19 13:22 1,3-Dichlorobenzene ug/L ND 1.0 06/05/19 13:22 1,3-Dichloropropane ug/L ND 1.0 06/05/19 13:22 1,4-Dichlorobenzene ug/L ND 1.0 06/05/19 13:22 2,2-Dichloropropane ug/L ND 1.0 06/05/19 13:22 2-Butanone (MEK) ug/L ND 5.0 06/05/19 13:22 2-Chlorotoluene ug/L ND 1.0 06/05/19 13:22 2-Hexanone ug/L ND 5.0 06/05/19 13:22 4-Chlorotoluene ug/L ND 1.0 06/05/19 13:22 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 06/05/19 13:22 Acetone ug/L ND 25.0 06/05/19 13:22 Benzene ug/L ND 1.0 06/05/19 13:22 Bromobenzene ug/L ND 1.0 06/05/19 13:22 Bromochloromethane ug/L ND 1.0 06/05/19 13:22 Bromodichloromethane ug/L ND 1.0 06/05/19 13:22 Bromoform ug/L ND 1.0 06/05/19 13:22 Bromomethane ug/L ND 2.0 06/05/19 13:22 IK Carbon tetrachloride ug/L ND 1.0 06/05/19 13:22 Chlorobenzene ug/L ND 1.0 06/05/19 13:22 Chloroethane ug/L ND 1.0 06/05/19 13:22 Chloroform ug/L ND 5.0 06/05/19 13:22 Chloromethane ug/L ND 1.0 06/05/19 13:22 cis-1,2-Dichloroethene ug/L ND 1.0 06/05/19 13:22 cis-1,3-Dichloropropene ug/L ND 1.0 06/05/19 13:22 Dibromochloromethane ug/L ND 1.0 06/05/19 13:22 Dibromomethane ug/L ND 1.0 06/05/19 13:22 Dichlorodifluoromethane ug/L ND 1.0 06/05/19 13:22 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 METHOD BLANK: 2592936 Associated Lab Samples: 92431399001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Diisopropyl ether ug/L ND 1.0 06/05/19 13:22 Ethylbenzene ug/L ND 1.0 06/05/19 13:22 Hexachloro-1,3-butadiene ug/L ND 1.0 06/05/19 13:22 m&p-Xylene ug/L ND 2.0 06/05/19 13:22 Methyl-tert-butyl ether ug/L ND 1.0 06/05/19 13:22 Methylene Chloride ug/L ND 5.0 06/05/19 13:22 Naphthalene ug/L ND 1.0 06/05/19 13:22 o-Xylene ug/L ND 1.0 06/05/19 13:22 p-Isopropyltoluene ug/L ND 1.0 06/05/19 13:22 Styrene ug/L ND 1.0 06/05/19 13:22 Tetrachloroethene ug/L ND 1.0 06/05/19 13:22 Toluene ug/L ND 1.0 06/05/19 13:22 trans-1,2-Dichloroethene ug/L ND 1.0 06/05/19 13:22 trans- 1,3-Dichloropropene ug/L ND 1.0 06/05/19 13:22 Trichloroethene ug/L ND 1.0 06/05/19 13:22 Trichlorofluoromethane ug/L ND 1.0 06/05/19 13:22 Vinyl acetate ug/L ND 2.0 06/05/19 13:22 Vinyl chloride ug/L ND 1.0 06/05/19 13:22 Xylene (Total) ug/L ND 1.0 06/05/19 13:22 1,2-Dichloroethane-d4 (S) % 93 70-130 06/05/19 13:22 4-Bromofluorobenzene (S) % 96 70-130 06/05/19 13:22 Toluene-d8 (S) % 99 70-130 06/05/19 13:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2592937 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 51.9 104 70-130 1,1,1-Trichloroethane ug/L 50 50.7 101 70-130 1,1,2,2-Tetrachloroethane ug/L 50 51.0 102 70-130 1,1,2-Trichloroethane ug/L 50 51.1 102 70-130 1,1-Dichloroethane ug/L 50 52.6 105 70-130 1,1-Dichloroethene ug/L 50 54.7 109 70-130 1,1-Dichloropropene ug/L 50 50.6 101 70-130 1,2,3-Trichlorobenzene ug/L 50 55.9 112 70-130 1,2,3-Trichloropropane ug/L 50 54.1 108 70-130 1,2,4-Trichlorobenzene ug/L 50 55.8 112 70-130 1,2-Dibromo-3-chloropropane ug/L 50 50.9 102 70-130 1,2-Dibromoethane (EDB) ug/L 50 51.6 103 70-130 1,2-Dichlorobenzene ug/L 50 50.7 101 70-130 1,2-Dichloroethane ug/L 50 45.8 92 70-130 1,2-Dichloropropane ug/L 50 52.1 104 70-130 1,3-Dichlorobenzene ug/L 50 50.5 101 70-130 1,3-Dichloropropane ug/L 50 51.7 103 70-131 1,4-Dichlorobenzene ug/L 50 50.3 101 70-130 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 LABORATORY CONTROL SAMPLE: Parameter 2592937 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 2,2-Dichloropropane ug/L 50 53.5 107 69-130 2-Butanone (MEK) ug/L 100 101 101 64-135 2-Chlorotoluene ug/L 50 50.1 100 70-130 2-Hexanone ug/L 100 104 104 66-135 4-Chlorotoluene ug/L 50 51.2 102 70-130 4-Methyl-2-pentanone (MIBK) ug/L 100 103 103 70-130 Acetone ug/L 100 116 116 61-157 Benzene ug/L 50 51.4 103 70-130 Bromobenzene ug/L 50 51.5 103 70-130 Bromochloromethane ug/L 50 51.5 103 70-130 Bromodichloromethane ug/L 50 51.9 104 70-130 Bromoform ug/L 50 53.0 106 70-130 Bromomethane ug/L 50 59.5 119 38-130IK Carbon tetrachloride ug/L 50 50.1 100 70-130 Chlorobenzene ug/L 50 49.8 100 70-130 Chloroethane ug/L 50 54.5 109 37-142 Chloroform ug/L 50 51.2 102 70-130 Chloromethane ug/L 50 54.6 109 48-130 cis-1,2-Dichloroethene ug/L 50 51.9 104 70-130 cis-1,3-Dichloropropene ug/L 50 52.5 105 70-130 Dibromochloromethane ug/L 50 52.0 104 70-130 Dibromomethane ug/L 50 52.2 104 70-130 Dichlorodifluoromethane ug/L 50 62.9 126 53-134 Diisopropyl ether ug/L 50 53.4 107 70-135 Ethylbenzene ug/L 50 51.4 103 70-130 Hexachloro-1,3-butadiene ug/L 50 56.0 112 68-132 m&p-Xylene ug/L 100 102 102 70-130 Methyl-tert-butyl ether ug/L 50 52.4 105 70-130 Methylene Chloride ug/L 50 46.2 92 67-132 Naphthalene ug/L 50 54.1 108 70-130 o-Xylene ug/L 50 53.5 107 70-131 p-Isopropyltoluene ug/L 50 53.4 107 70-130 Styrene ug/L 50 51.5 103 70-130 Tetrachloroethene ug/L 50 49.0 98 69-130 Toluene ug/L 50 50.4 101 70-130 trans-1,2-Dichloroethene ug/L 50 54.1 108 70-130 trans- 1,3-Dichloropropene ug/L 50 53.2 106 70-130 Trichloroethene ug/L 50 50.5 101 70-130 Trichlorofluoromethane ug/L 50 53.0 106 63-130 Vinyl acetate ug/L 100 111 111 55-143 Vinyl chloride ug/L 50 58.3 117 70-131 Xylene (Total) ug/L 150 156 104 70-130 1,2-Dichloroethane-d4 (S) % 96 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2592938 2592939 MS MSD 92431212005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 500 500 615 579 123 116 73-134 6 1,1,1-Trichloroethane ug/L ND 500 500 637 591 127 118 82-143 7 1,1,2,2-Tetrachloroethane ug/L ND 500 500 608 547 122 109 70-136 11 1,1,2-Trichloroethane ug/L ND 500 500 590 551 118 110 70-135 7 1,1-Dichloroethane ug/L ND 500 500 649 611 130 122 70-139 6 1,1-Dichloroethene ug/L ND 500 500 684 604 137 121 70-154 13 1,1-Dichloropropene ug/L ND 500 500 622 587 124 117 70-149 6 1,2,3-Trichlorobenzene ug/L ND 500 500 609 511 122 102 70-135 18 1,2,3-Trichloropropane ug/L ND 500 500 557 581 111 116 71-137 4 1,2,4-Trichlorobenzene ug/L ND 500 500 613 559 123 112 73-140 9 1,2-Dibromo-3-chloropropane ug/L ND 500 500 587 552 117 110 65-134 6 1,2-Dibromoethane (EDB) ug/L ND 500 500 608 537 122 107 70-137 12 1,2-Dichlorobenzene ug/L ND 500 500 590 535 118 107 70-133 10 1,2-Dichloroethane ug/L ND 500 500 571 505 113 100 70-137 12 1,2-Dichloropropane ug/L ND 500 500 630 576 126 115 70-140 9 1,3-Dichlorobenzene ug/L ND 500 500 597 565 119 113 70-135 6 1,3-Dichloropropane ug/L ND 500 500 611 563 122 113 70-143 8 1,4-Dichlorobenzene ug/L ND 500 500 579 532 116 106 70-133 9 2,2-Dichloropropane ug/L ND 500 500 674 643 135 129 61-148 5 2-Butanone (MEK) ug/L ND 1000 1000 1260 1220 118 114 60-139 4 2-Chlorotoluene ug/L ND 500 500 657 630 131 126 70-144 4 2-Hexanone ug/L ND 1000 1000 1240 1160 124 116 65-138 6 4-Chlorotoluene ug/L ND 500 500 615 574 123 115 70-137 7 4-Methyl-2-pentanone (MIBK) ug/L ND 1000 1000 1230 1170 123 117 65-135 5 Acetone ug/L ND 1000 1000 1260 1210 126 121 60-148 5 Benzene ug/L ND 500 500 645 606 129 121 70-151 6 Bromobenzene ug/L ND 500 500 619 574 124 115 70-136 8 Bromochloromethane ug/L ND 500 500 623 607 125 121 70-141 3 Bromodichloromethane ug/L ND 500 500 627 571 125 114 70-138 9 Bromoform ug/L ND 500 500 574 535 115 107 63-130 7 Bromomethane ug/L ND 500 500 782 705 156 141 15-152 101K,M1 Carbon tetrachloride ug/L ND 500 500 606 574 121 115 70-143 6 Chlorobenzene ug/L ND 500 500 596 567 119 113 70-138 5 Chloroethane ug/L ND 500 500 819 508 164 102 52-163 47 M1,R1 Chloroform ug/L ND 500 500 612 599 122 120 70-139 2 Chloromethane ug/L ND 500 500 658 602 132 120 41-139 9 cis-1,2-Dichloroethene ug/L ND 500 500 640 581 128 116 70-141 10 cis-1,3-Dichloropropene ug/L ND 500 500 625 605 125 121 70-137 3 Dibromochloromethane ug/L ND 500 500 608 584 122 117 70-134 4 Dibromomethane ug/L ND 500 500 605 584 121 117 70-138 4 Dichlorodifluoromethane ug/L ND 500 500 716 650 143 130 47-155 10 Diisopropyl ether ug/L ND 500 500 671 613 134 123 63-144 9 Ethylbenzene ug/L 1270 500 500 1860 1710 116 87 66-153 8 Hexachloro-1,3-butadiene ug/L ND 500 500 599 531 120 106 65-149 12 m&p-Xylene ug/L 8040 1000 1000 8930 8230 89 19 69-152 8 M1 Methyl-tert-butyl ether ug/L ND 500 500 666 594 133 119 54-156 11 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2592938 2592939 MS MSD 92431212005 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual Methylene Chloride ug/L ND 500 500 589 542 111 102 42-159 8 Naphthalene ug/L 935 500 500 1480 1460 110 105 61-148 1 o-Xylene ug/L 4460 500 500 4930 4590 94 25 70-148 7 M1 p-Isopropyltoluene ug/L ND 500 500 636 595 123 115 70-146 7 Styrene ug/L ND 500 500 668 616 134 123 70-135 8 Tetrachloroethene ug/L ND 500 500 593 578 119 116 59-143 3 Toluene ug/L 2020 500 500 2610 2400 118 77 59-148 8 trans-1,2-Dichloroethene ug/L ND 500 500 686 615 137 123 70-146 11 trans- 1,3-Dichloropropene ug/L ND 500 500 606 576 121 115 70-135 5 Trichloroethene ug/L ND 500 500 621 569 124 114 70-147 9 Trichlorofluoromethane ug/L ND 500 500 640 609 128 122 70-148 5 Vinyl acetate ug/L ND 1000 1000 1330 1220 133 122 49-151 9 Vinyl chloride ug/L ND 500 500 734 663 147 133 70-156 10 Xylene (Total) ug/L 12500 1500 1500 13900 12800 91 21 63-158 8 MS 1,2-Dichloroethane-d4 (S) % 94 91 70-130 4-Bromofluorobenzene (S) % 96 96 70-130 Toluene-d8(S) % 100 99 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 QC Batch: 479101 Analysis Method: EPA 625.1 QC Batch Method: EPA 625.1 Analysis Description: 625 MSS Associated Lab Samples: 92431399001 METHOD BLANK: 2592913 Associated Lab Samples: 92431399001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,2,4-Trichlorobenzene ug/L ND 5.0 06/05/19 17:20 2,2'-Oxybis(1-chloropropane) ug/L ND 5.0 06/05/19 17:20 2,4,6-Trichlorophenol ug/L ND 10.0 06/05/19 17:20 2,4-Dichlorophenol ug/L ND 5.0 06/05/19 17:20 2,4-Dimethylphenol ug/L ND 10.0 06/05/19 17:20 2,4-Dinitrophenol ug/L ND 50.0 06/05/19 17:20 2,4-Dinitrotoluene ug/L ND 5.0 06/05/19 17:20 2,6-Dinitrotoluene ug/L ND 5.0 06/05/19 17:20 2-Chloronaphthalene ug/L ND 5.0 06/05/19 17:20 2-Chlorophenol ug/L ND 5.0 06/05/19 17:20 2-Nitrophenol ug/L ND 5.0 06/05/19 17:20 3,3'-Dichlorobenzidine ug/L ND 25.0 06/05/19 17:20 4,6-Dinitro-2-methyl phenol ug/L ND 20.0 06/05/19 17:20 4-Bromophenylphenyl ether ug/L ND 5.0 06/05/19 17:20 4-Chloro-3-methylphenol ug/L ND 5.0 06/05/19 17:20 4-Chlorophenylphenyl ether ug/L ND 5.0 06/05/19 17:20 4-Nitrophenol ug/L ND 50.0 06/05/19 17:20 Acenaphthene ug/L ND 5.0 06/05/19 17:20 Acenaphthylene ug/L ND 5.0 06/05/19 17:20 Anthracene ug/L ND 5.0 06/05/19 17:20 Benzo(a)anthracene ug/L ND 5.0 06/05/19 17:20 Benzo(a)pyrene ug/L ND 5.0 06/05/19 17:20 Benzo(b)fluoranthene ug/L ND 5.0 06/05/19 17:20 Benzo(g,h,i)perylene ug/L ND 5.0 06/05/19 17:20 Benzo(k)fluoranthene ug/L ND 5.0 06/05/19 17:20 bis(2-Chloroethoxy)methane ug/L ND 10.0 06/05/19 17:20 bis(2-Chloroethyl) ether ug/L ND 5.0 06/05/19 17:20 bis(2-Ethylhexyl)phthalate ug/L ND 5.0 06/05/19 17:20 Butylbenzylphthalate ug/L ND 5.0 06/05/19 17:20 Chrysene ug/L ND 5.0 06/05/19 17:20 Di-n-butylphthalate ug/L ND 5.0 06/05/19 17:20 Di-n-octylphthalate ug/L ND 5.0 06/05/19 17:20 Dibenz(a,h)anthracene ug/L ND 5.0 06/05/19 17:20 Diethylphthalate ug/L ND 5.0 06/05/19 17:20 Dimethylphthalate ug/L ND 5.0 06/05/19 17:20 Fluoranthene ug/L ND 5.0 06/05/19 17:20 Fluorene ug/L ND 5.0 06/05/19 17:20 Hexachloro-1,3-butadiene ug/L ND 5.0 06/05/19 17:20 Hexachlorobenzene ug/L ND 5.0 06/05/19 17:20 Hexachlorocyclopentadiene ug/L ND 10.0 06/05/19 17:20 Hexachloroethane ug/L ND 5.0 06/05/19 17:20 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 METHOD BLANK: 2592913 Associated Lab Samples: 92431399001 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Indeno(1,2,3-cd)pyrene ug/L ND 5.0 06/05/19 17:20 Isophorone ug/L ND 10.0 06/05/19 17:20 N-Nitroso-di-n-propylamine ug/L ND 5.0 06/05/19 17:20 N-Nitrosodimethylamine ug/L ND 5.0 06/05/19 17:20 N-Nitrosodiphenylamine ug/L ND 10.0 06/05/19 17:20 Naphthalene ug/L ND 5.0 06/05/19 17:20 Nitrobenzene ug/L ND 5.0 06/05/19 17:20 Pentachlorophenol ug/L ND 10.0 06/05/19 17:20 Phenanthrene ug/L ND 5.0 06/05/19 17:20 Phenol ug/L ND 5.0 06/05/19 17:20 Pyrene ug/L ND 5.0 06/05/19 17:20 2,4,6-Tribromophenol (S) % 98 10-137 06/05/19 17:20 2-Fluorobiphenyl (S) % 84 15-120 06/05/19 17:20 2-Fluorophenol (S) % 86 10-120 06/05/19 17:20 Nitrobenzene-d5 (S) % 95 10-120 06/05/19 17:20 Phenol-d6 (S) % 61 10-120 06/05/19 17:20 Terphenyl-d14 (S) % 106 11-131 06/05/19 17:20 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2592914 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,2,4-Trichlorobenzene ug/L 50 25.5 51 44-142 2,2'-Oxybis(1-chloropropane) ug/L 50 33.1 66 36-166 2,4,6-Trichlorophenol ug/L 50 39.0 78 37-144 2,4-Dichlorophenol ug/L 50 38.0 76 1-191 2,4-Dimethylphenol ug/L 50 36.5 73 32-119 2,4-Dinitrophenol ug/L 250 217 87 1-181 2,4-Dinitrotoluene ug/L 50 38.5 77 39-139 2,6-Dinitrotoluene ug/L 50 37.2 74 50-158 2-Chloronaphthalene ug/L 50 33.9 68 60-118 2-Chlorophenol ug/L 50 35.1 70 23-134 2-Nitrophenol ug/L 50 35.4 71 29-182 3,3'-Dichlorobenzidine ug/L 100 84.3 84 1-262 4,6-Dinitro-2-methyl phenol ug/L 100 94.1 94 1-181 4-Bromophenylphenyl ether ug/L 50 37.0 74 53-127 4-ChIoro-3-methyl phenol ug/L 100 80.7 81 22-147 4-Chlorophenylphenyl ether ug/L 50 36.1 72 25-158 4-Nitrophenol ug/L 250 171 68 1-132 Acenaphthene ug/L 50 33.6 67 47-145 Acenaphthylene ug/L 50 34.2 68 33-145 Anthracene ug/L 50 39.0 78 1-166 Benzo(a)anthracene ug/L 50 42.2 84 33-143 Benzo(a)pyrene ug/L 50 41.0 82 17-163 Benzo(b)fluoranthene ug/L 50 47.1 94 24-159 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 LABORATORY CONTROL SAMPLE: 2592914 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Benzo(g,h,i)perylene ug/L 50 42.4 85 1-219 Benzo(k)fluoranthene ug/L 50 41.6 83 11-162 bis(2-Chloroethoxy)methane ug/L 50 35.3 71 33-184 bis(2-Chloroethyl) ether ug/L 50 34.5 69 12-158 bis(2-Ethylhexyl)phthalate ug/L 50 39.0 78 8-158 Butylbenzylphthalate ug/L 50 39.0 78 1-152 Chrysene ug/L 50 37.4 75 17-168 Di-n-butylphthalate ug/L 50 36.7 73 1-118 Di-n-octylphthalate ug/L 50 38.8 78 4-146 Dibenz(a,h)anthracene ug/L 50 43.7 87 1-227 Diethylphthalate ug/L 50 36.0 72 1-114 Dimethylphthalate ug/L 50 36.1 72 1-112 Fluoranthene ug/L 50 40.5 81 26-137 Fluorene ug/L 50 36.7 73 59-121 Hexachloro-1,3-butadiene ug/L 50 23.3 47 24-116 Hexachlorobenzene ug/L 50 34.1 68 1-152 Hexachlorocyclopentadiene ug/L 50 23.2 46 25-150 Hexachloroethane ug/L 50 22.2 44 40-113 Indeno(1,2,3-cd)pyrene ug/L 50 42.8 86 1-171 Isophorone ug/L 50 31.3 63 21-196 N-Nitroso-di-n-propylamine ug/L 50 34.2 68 1-230 N-Nitrosodimethylamine ug/L 50 28.5 57 25-150 N-Nitrosodiphenylamine ug/L 50 37.1 74 25-150 Naphthalene ug/L 50 31.6 63 21-133 Nitrobenzene ug/L 50 31.4 63 35-180 Pentachlorophenol ug/L 100 89.4 89 14-176 Phenanthrene ug/L 50 38.3 77 54-120 Phenol ug/L 50 26.5 53 5-112 Pyrene ug/L 50 39.8 80 52-115 2,4,6-Tribromophenol (S) % 82 10-137 2-Fluorobiphenyl (S) % 66 15-120 2-Fluorophenol (S) % 63 10-120 Nitrobenzene-d5(S) % 71 10-120 Phenol-d6 (S) % 51 10-120 Terphenyl-d14 (S) % 80 11-131 MATRIX SPIKE SAMPLE: 2594284 92430410005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 1,2,4-Trichlorobenzene ug/L ND 50 22.0 44 44-142 2,2'-Oxybis(1-chloropropane) ug/L ND 50 21.1 42 36-166 2,4,6-Trichlorophenol ug/L ND 50 30.7 61 37-144 2,4-Dichlorophenol ug/L ND 50 29.1 58 1-191 2,4-Dimethylphenol ug/L ND 50 28.8 58 32-119 2,4-Dinitrophenol ug/L ND 250 218 87 1-181 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 26 aceAnalytical -pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 MATRIX SPIKE SAMPLE: 2594284 92430410005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 2,4-Dinitrotoluene ug/L ND 50 39.3 79 39-139 2,6-Dinitrotoluene ug/L ND 50 34.6 69 50-158 2-Chloronaphthalene ug/L ND 50 29.5 59 60-118 M1 2-Chlorophenol ug/L ND 50 28.6 57 23-134 2-Nitrophenol ug/L ND 50 28.1 56 29-182 3,3'-Dichlorobenzidine ug/L ND 100 82.5 83 1-262 4,6-Dinitro-2-methyl phenol ug/L ND 100 98.9 99 1-181 4-Bromophenylphenyl ether ug/L ND 50 34.5 69 53-127 4-Chloro-3-methylphenol ug/L ND 100 56.1 56 22-147 4-Chlorophenylphenyl ether ug/L ND 50 29.2 58 25-158 4-Nitrophenol ug/L ND 250 126 50 1-132 Acenaphthene ug/L ND 50 29.3 59 47-145 Acenaphthylene ug/L ND 50 30.1 60 33-145 Anthracene ug/L ND 50 43.6 87 1-166 Benzo(a)anthracene ug/L ND 50 46.9 94 33-143 Benzo(a)pyrene ug/L ND 50 46.9 94 17-163 Benzo(b)fluoranthene ug/L ND 50 50.0 100 24-159 Benzo(g,h,i)perylene ug/L ND 50 45.8 92 1-219 Benzo(k)fluoranthene ug/L ND 50 48.1 96 11-162 bis(2-Chloroethoxy)methane ug/L ND 50 26.0 52 33-184 bis(2-Chloroethyl) ether ug/L ND 50 27.6 55 12-158 bis(2-Ethylhexyl)phthalate ug/L ND 50 42.7 85 8-158 Butylbenzylphthalate ug/L ND 50 40.3 81 1-152 Chrysene ug/L ND 50 42.2 84 17-168 Di-n-butylphthalate ug/L ND 50 41.4 83 1-118 Di-n-octylphthalate ug/L ND 50 41.1 82 4-146 Dibenz(a,h)anthracene ug/L ND 50 45.4 91 1-227 Diethylphthalate ug/L ND 50 38.7 77 1-114 Dimethylphthalate ug/L ND 50 34.1 68 1-112 Fluoranthene ug/L ND 50 47.1 94 26-137 Fluorene ug/L ND 50 32.6 65 59-121 Hexachloro-1,3-butadiene ug/L ND 50 19.6 39 24-116 Hexachlorobenzene ug/L ND 50 34.8 70 1-152 Hexachlorocyclopentadiene ug/L ND 50 20.5 41 25-150 Hexachloroethane ug/L ND 50 19.6 39 40-113 M1 Indeno(1,2,3-cd)pyrene ug/L ND 50 47.2 94 1-171 Isophorone ug/L ND 50 25.5 51 21-196 N-Nitroso-di-n-propylamine ug/L ND 50 26.0 52 1-230 N-Nitrosodimethylamine ug/L ND 50 21.9 44 25-150 N-Nitrosodiphenylamine ug/L ND 50 37.4 75 25-150 Naphthalene ug/L ND 50 27.7 55 21-133 Nitrobenzene ug/L ND 50 25.9 52 35-180 Pentachlorophenol ug/L ND 100 81.5 81 14-176 Phenanthrene ug/L ND 50 42.7 85 54-120 Phenol ug/L ND 50 16.8 34 5-112 Pyrene ug/L ND 50 46.7 93 52-115 2,4,6-Tribromophenol (S) % 86 10-137 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 MATRIX SPIKE SAMPLE: 2594284 92430410005 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers 2-Fluorobiphenyl (S) % 56 15-120 2-Fluorophenol(S) % 44 10-120 Nitrobenzene-d5 (S) % 58 10-120 Phenol-d6 (S) % 33 10-120 Terphenyl-d14 (S) % 89 11-131 SAMPLE DUPLICATE: 2594285 Parameter Units 92430410006 Result Dup Result 1,2,4-Trichlorobenzene ug/L ND ND 2,2'-Oxybis(1-chloropropane) ug/L ND ND 2,4,6-Trichlorophenol ug/L ND ND 2,4-Dichlorophenol ug/L ND ND 2,4-Dimethylphenol ug/L ND ND 2,4-Dinitrophenol ug/L ND ND 2,4-Dinitrotoluene ug/L ND ND 2,6-Dinitrotoluene ug/L ND ND 2-Chloronaphthalene ug/L ND ND 2-Chlorophenol ug/L ND ND 2-Nitrophenol ug/L ND ND 3,3'-Dichlorobenzidine ug/L ND ND 4,6-Dinitro-2-methyl phenol ug/L ND ND 4-Bromophenylphenyl ether ug/L ND ND 4-Chloro-3-methylphenol ug/L ND ND 4-Chlorophenylphenyl ether ug/L ND ND 4-Nitrophenol ug/L ND ND Acenaphthene ug/L ND ND Acenaphthylene ug/L ND ND Anthracene ug/L ND ND Benzo(a)anthracene ug/L ND ND Benzo(a)pyrene ug/L ND ND Benzo(b)fluoranthene ug/L ND ND Benzo(g,h,i)perylene ug/L ND ND Benzo(k)fluoranthene ug/L ND ND bis(2-Chloroethoxy)methane ug/L ND ND bis(2-Chloroethyl) ether ug/L ND ND bis(2-Ethylhexyl)phthalate ug/L ND ND Butylbenzylphthalate ug/L ND ND Chrysene ug/L ND ND Di-n-butylphthalate ug/L ND ND Di-n-octylphthalate ug/L ND ND Dibenz(a,h)anthracene ug/L ND ND Diethylphthalate ug/L ND ND Dimethylphthalate ug/L ND ND Fluoranthene ug/L ND ND RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 SAMPLE DUPLICATE: 2594285 Parameter Units 92430410006 Result Dup Result Fluorene ug/L ND ND Hexachloro-1,3-butadiene ug/L ND ND Hexachlorobenzene ug/L ND ND Hexachlorocyclopentadiene ug/L ND ND Hexachloroethane ug/L ND ND Indeno(1,2,3-cd)pyrene ug/L ND ND Isophorone ug/L ND ND N-Nitroso-di-n-propylamine ug/L ND ND N-Nitrosodimethylamine ug/L ND ND N-Nitrosodiphenylamine ug/L ND ND Naphthalene ug/L ND ND Nitrobenzene ug/L ND ND Pentachlorophenol ug/L ND ND Phenanthrene ug/L ND ND Phenol ug/L ND ND Pyrene ug/L ND ND 2,4,6-Tribromophenol (S) % 79 51 2-Fluorobiphenyl (S) % 66 54 2-Fluorophenol (S) % 58 43 Nitrobenzene-d5 (S) % 67 54 Phenol-d6 (S) % 46 31 Terphenyl-d14 (S) % 103 57 RPD Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA Project: Water Pace Project No.: 92431399 QC Batch: 478758 Analysis Method: MADEP EPH QC Batch Method: MADEP EPH Analysis Description: MADEP EPH NC Water Associated Lab Samples: 92431399001 METHOD BLANK: 2591455 Matrix: Water Associated Lab Samples: 92431399001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Aliphatic (C09-C18) ug/L ND 100 06/05/19 06:50 N2 Aliphatic (C19-C36) ug/L ND 100 06/05/19 06:50 N2 Aromatic (C11-C22) ug/L ND 100 06/05/19 06:50 N2 2-Bromonaphthalene (S) % 85 40-140 06/05/19 06:50 2-Fluorobiphenyl (S) % 82 40-140 06/05/19 06:50 Nonatriacontane (S) % 55 40-140 06/05/19 06:50 o-Terphenyl (S) % 68 40-140 06/05/19 06:50 LABORATORY CONTROL SAMPLE & LCSD: 2591456 2591457 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limits RPD RPD Qualifiers Aliphatic (C09-C18) ug/L 300 147 171 49 57 40-140 15 50 N2 Aliphatic (C19-C36) ug/L 400 232 270 58 67 40-140 15 50 N2 Aromatic (C11-C22) ug/L 850 508 596 60 70 40-140 16 50 N2 2-Bromonaphthalene (S) % 82 85 40-140 2-Fluorobiphenyl (S) % 82 83 40-140 Nonatriacontane (S) % 60 61 40-140 o-Terphenyl(S) % 70 82 40-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 26 Pace Analytical Services, LLC ceAnalX cal ® 9800 Kiney Ave. Suite 100 Huntersville, NC 28078078 www.pacelabs.com (704)875-9092 QUALIFIERS Project: Water Pace Project No.: 92431399 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. LABORATORIES PASI-A Pace Analytical Services - Asheville PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS IK The recalculated concentration of the calibration standard(s) did not meet method acceptance criteria; this result should be considered an estimated value. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. MS Analyte recovery in the matrix spike was outside QC limits for one or more of the constituent analytes used in the calculated result. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/06/2019 05:02 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 26 aceAnalytical —pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Water 92431399 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 92431399001 MW-1 MADEP EPH 478758 MADEP EPH 479069 92431399001 MW-1 MADEP VPH 478940 92431399001 MW-1 EPA 3010A 478810 EPA 6010D 478829 92431399001 MW-1 EPA 625.1 479101 EPA 625.1 479360 92431399001 MW-1 EPA 8260D 479106 Date: 06/06/2019 05:02 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 26 + Sample Condition U on Retei C(SCUR Page 1 of 2 :aCi;Rnao--ca Document No.: Issuing Authority: F-CAR-CS-033-Rew06 Pace Carolinas Quality I Laboratory receiving samples: Asheville ❑ Eden❑ Greenwood ❑ Huntersvilf Raleigh❑ Mechanicsville(] SarrIple . . Client Name: �0#92431399 Upon ReceiptProjectA Courser: ❑.Fed Ex ❑UPS ❑USl'S Eclient ❑ Commercial r ❑Pace ❑Other, 92431399 Custody Sea! Present? Oyes 101NO Seals Intact? []Yeso Date/Initials Person Examining Contents: Packing Material: []Bubble Wrap Bubble Bags ❑None ❑ other Biological Tissue F,�zen? Thermometer ❑Yes ❑No N/A 92TO48 Type of Ice: Ljy / t ❑Blue []None R Gun 10: -�--- [ooler Terrip (°L): �-� ° Correction Factor: Add/Subtract ('Q 0.0 Tempshould be above freezing to VC Cooler Temp Corrected (°C). ❑Samples out of temp criteria. Samples on ice, cooling process has begun USDA Regulated SoN N/A, water sample) Did samples originate in a quarantine zone within the United States: CA, NY, or 5C (check maps)? Did samples originate from a foreign source (Internatlanally,.. ram.. - F-1-1 _ i—iE„rdauawaii and Puerto Rlcol? nYes []No - Comments/Discrepancy: Chain of Custody Present? a esEINO ❑N/A 1. Satno kn Arrived within Hold rime? Yes ONO ❑NIA 2. Short Hcld,Time Anal sls (<72 hr.)? ❑Yes r1do, ❑N A 3. Rush ruin Around Tune Requested? es NIA Sufficlentvolume? es EIN. ❑N/A S. Correct Containers Used? -Pace Containers Used? ess QNo EJNo ❑N/A N/A 6. Containers Intact? es ❑No NIA 7. Dissolved analysis: Samples Field R8ered?— ❑Yes ❑Na ONIA 6. Sample Labels Match COO -Includes Date/Time/ID/Analysis Matrix: Headspace in VOA Vials (>5-6mm)? Yes ❑Na o []N/A ❑N A 9. 10. Trip Blank Present? Trip Blank Custody Seals Present? ❑Yes Yes []No QNo /A IA COMMENTS/SAMPLE DISCREPANCY Field Data Required? ❑Yes [:]No Lot ID of split containers: CLIENT NOT1FKATION/RESC]LUrION Person contacted: Date/Time: Project Manager SCURF Review: a1W Date: Project Manager SRF Review: Date: Page 24 of 26 Document Name: Condition upon Rec Document No.: Document Revised: February 7, 2018 Page 1 of 2 Issuing Authority: Pace Carolinas Quality Office *Check mark top half of box if pH and/or dechlorination is Project # verified and within the acceptance range for preservation samples. Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg **Bottom half of box is to list number of bottle WQ#:92431399 PM: TIH Due Date. 06/05/19 CLIENT: 92-Irminger N E N ri m SS}} Q7 E kn N m 61 E G VI m m qL+� m v g yE, f�E m y L � E N m u H d E N m Aj CL 1n Q E N ! u e a 3 �T ai a E «! N v a _«' .SS-. is d m E ¢ o N N V Q s E cc ;; v 2 �tQ w 4 E N" S E G- n�i Q {M Z d O J t 4 q O 1 p } E x d O E 3 `y a W c� @ d (A J E `y m W E u� ,NN,_ Y m °. E yp� £ E c �n J E m E Q J E 1 G 2 1 N 3 T1 I I N \N 5 6 7 1 \\N\J I \N 'I I \\I 8 I \N\ 3.0 I1 12 pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservation adjusted Time preseryation adjusted Amount of Preservative added Lot N Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will nesent to the North Carolina ULHNK certmcation UrnCe tr.e. Out of hold, incorrect preservative, out of temp, Incorrect containers. Page 25 of 26 CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. Section A Section B Section C . Required Clie Irformaton: Required Project Information: Invoice Information: Pa e - 1 Of 1 mingerConsulting Inc Report To: Steve Irminger Attention: 015 Erinhrook Road Copy To: Company Name: 70 Company: ! Address: Concord, NC 2E D25 Address: 4� fit" Email: stEvei finger gmail.00m Purchase Order#: Pace Quote: Phone: 04)795-1585 Fax Project Name: Water Pace Project Manager: tyriek.hooks@pacelabs.com, ` Requested Due ate: Project#: Pace Profile #: 2138-1 NC :..Re nested Wig Filtered . - � } MATRIX CODE r0j COLLECTED Z Preservatives .... - Drinking Watf DW m U O Water WP ti li= Waste Water WW _ Q J u?�;�'.>. Product P SAMPLE ID S611S.14 SL } Oil OL START END F }.; 9 One Character per box. Wipe WP w fS # (A,Z, 0.91. �) Other OT AJr AR v w i I: U Sample Ids must be unique Tissue TS x TDATETIME o U m v W 1- 4 y O n c w N U z O N m T T j m M� v DATE TIME vt 5 z x r z z O '. m rNo uai 7Cd Cd - CiiO ;y' 4 g -,UA, PRINT Na.m f MPLE�(:� tp Cv a m m Z om mm`$ Z a_.� E m ? SIGNATU of MPLER: DATE Signed: N H} y Beverly, Trudy From: Beverly, Trudy Sent: Wednesday, July 31, 2019 11:25 AM To: Steven Irminger Subject: RE: [External] LSA Byrum Property Incident 40792 Good Morning Steve, No need to mail a hard copy of this report. Thank you, Trudy Trudy Eev erly . L.G. �i•a�roggoTo :st, Divirio�: of F�:asra .Fa�:agement D E Forth Carolina Department ofEnNironmental nRTF nRrn vn n.p-m—t 0 Environmental quality Quality UST Section: MooresAle Regional Office (7Cl4) 23i-21 R2 (nffiir�l Email correspondence to and from this address is subject to the North Carolina Public Records Law and may be disclosed to third parties. Office Mailing Address: 610 East Center Avenue, Suite 301 Mooresville, NC 28115 Branch's Underground Storage Tanks Website Address: hlWs:Hdeq.nc.gov/about/divisions/waste-management/ust Branch's Above Ground Storage Tanks Website Address: https://deq.nc.gov/about/divisions/waste-management/ust/ast- program INTERACTIVE MAPS WITH DWM SITES AND PERMITTED FACILITIES: https://deu.nc. cov/about/divisions/waste-manacement/waste-management-rules-data/waste-management-cis-maps File Review Procedures: hM2s:Hdeq.nc. gov/about/divisions/waste-management/ust/file-review-procedures#mooresville-regional-office ONLINE ACCESS TO UST SECTION DOCUMENTS (Laserfiche): httDs:Hedocs.dea.nc. cov/WasteManacement/Search.asnx Document Submittal & UST File Names for Laserfiche Policies: httDs:Hfiles.nc. cov/ncdea/Waste%20Manaeement/DWM/UST/Corrective%20Action/Electronic%20Document%20Submittal %20Memo%20Update.pdf https://files.nc.cov/ncdea/Waste%20Manaeement/DWM/ JST/Corrective%20Action/UST%20file%20names%20for%20Las erfiche.docx From: Steven Irminger [mailto:steveirminger@gmail.com] Sent: Wednesday, July 31, 2019 9:20 AM To: Beverly, Trudy <trudy.beverly@ncdenr.gov> Subject: [External] LSA Byrum Property Incident 40792 ernal email. Do not click links or open attachments unless you verify. Send all suspicious email as an �chm�o report.spam@nc.gov Good Morning Trudy, Hope you are having a good summer. Please find attached an LSA for the Byrum Property located at 5628 Closeburn Road, Charlotte, NC(Incident 40792). Soil contamination was discovered in 2018 during due diligence assessment of a heating oil UST. The UST was closed by removal this spring and impacted soil was removed. However, confirmation soil sampling revealed concentrations exceeding soil -to -groundwater. The LSA did not encounter groundwater above bedrock. Using air rotary methods, a well was installed to 45-feet below grade. This well produced water which was sampled for the LSA. Naphthalene was reported at 1.0 ug/L and chromium at 6.3 ug/L. No other parameters reported above the sample detection limit. This incident should qualify for closure with no land use restrictions. Hopefully, an easy review on your part. The owner is trying to complete a real estate deal so your speedy review would be much appreciated. Please call me with any questions. Do you need a hard copy? Steve Irminger 704-701-9099