5802_Madison_MSWLF_GW_FID1323459_20190628

ENR USE ONLY: ElPaper Report ❑Electronic Data - Email CD fdata loaded: Yes / No Doc/Event #:
C DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitorina Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: Brian Gant
E-mail: [e-mail]
Phone: [phone]
Facility name: Facility Address: Facility Permit #
Madison County Closed Solid 389 Long Branch Road 58-02
Waste Facility Marshall, NC 28753
NC Landfill Rule:
(.0500 or .1600)
.0500
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring X❑ Detection Monitoring ❑ Assessment Monitoring
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data
Groundwater monitoring data from private water supply wells ❑ Corrective action data (specify)
Leachate monitoring data ❑ Other(specify)
Surface water monitoring data
Actual sampling dates (e.g
October 20-24, 2006)
Corrective Action
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 26 surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
Alec Macbeth, PG Senior Scientist 828-281-3350
Facility Representative Name (Print) Title (Area Code) Telephone Number
June 30, 2019 Affix NC Licensed/ Professional Geologist Seal
0
Signature Date �AN�raA1L4� ti�
CApfi;',,
231 Haywood Street, Asheville, North Carolina 28801
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

June 2019
Madison County Closed Solid Waste Facility, Permit No. 58-02
kzANCHOR
QEA
Spring 2019
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

June 2019
Madison County Closed Solid Waste Facility, Permit No. 58-02
Spring 2019
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
71. e--Z�
Alec Macbeth, PG
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Number: C81500-01.01
\\asheville1\Asheville\Projects\Madison County\Reports\2019\Spring\5802 - Closed\FINAL_Spring 2019 Semiannual Water Quality Report.docx

TABLE OF CONTENTS
1 Introduction
2 Methods
1
2
2.1 Monitoring Well Sampling Methods...........................................................................................................2
2.1.1 Monitoring Wells MW-01 OLD, MW-02 OLD, and BG SPRING OLD...............................2
2.1.2 Monitoring Wells MW-03 OLD and MW-04 OLD...................................................................2
2.2 Surface Water Sampling Methods................................................................................................................3
2.3 Domestic Well Sampling Methods...............................................................................................................3
2.4 Sample Handling, Documentation, and Analysis....................................................................................3
3 Findings........................................................................................................................................5
3.1 Groundwater.........................................................................................................................................................5
3.1.1 Field Parameters..................................................................................................................................6
3.1.2 RCRA Metals..........................................................................................................................................6
3.1.3 Appendix I VOCs..................................................................................................................................6
3.2 Surface Water.......................................................................................................................................................6
3.2.1 Field Parameters..................................................................................................................................6
3.2.2 RCRA Metals..........................................................................................................................................7
3.2.3 Appendix I VOCs..................................................................................................................................7
3.3 Site Hydrogeology..............................................................................................................................................7
4 Summary......................................................................................................................................8
4.1 Future Activities...................................................................................................................................................8
5 References
TABLES
Table 1
Table 2
FIGURES
Figure 1
Figure 2
Summary of Laboratory Analyses Performed on Samples
Summary of Detected Constituents
Site Location Map
Sample Location Map
E
Spring 2019 Semiannual
Water Quality Monitoring Report i June 2019

APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data
Sheets
Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation
Spring 2019 Semiannual
Water Quality Monitoring Report ii June 2019

ABBREVIATIONS
µg/L
micrograms per liter
µS/cm
microsiemens per centimeter
213 standard
surface water quality standards defined in 15A NCAC 213
2L standard
groundwater quality standards defined in 15A NCAC 2L .0202
Closed Landfill
closed municipal solid waste landfill
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
DWM
Division of Waste Management
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentration
MDL
method detection limit
mg/L
milligrams per liter
MRL
method reporting limit
mV
millivolt
NCAC
North Carolina Administrative Code
NTU
Nephelometric Turbidity Units
ORP
oxidation reduction potential
Prism
Prism Laboratories, Inc.
RCRA
Resource Conservation and Recovery Act
SC
specific conductivity
SU
Standard Units
SWS
Solid Waste Section
TOC
top of well casing
VOC
volatile organic compound
Spring 2019 Semiannual
Water Quality Monitoring Report iii June 2019

1 Introduction
The Madison County Solid Waste Department maintains a closed municipal solid waste landfill
(Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch Road
(State Route 1582) in Madison County, North Carolina. The site location is presented in Figure 1.
The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ),
Division of Waste Management (DWM), under Permit No. 58-02, which requires semiannual
monitoring of groundwater and surface water quality.
This report, prepared by Anchor QEA of North Carolina, PLLC (Anchor QEA), is being submitted in
accordance with monitoring requirements for closed landfills as stipulated in DEQ DWM Permit
No. 58-02 issued to the Madison County Solid Waste Department, with regulations codified in the
DEQ Solid Waste Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina
Administrative Code (15A North Carolina Administrative Code [NCAC] 13B .1600).
This report describes the first semiannual groundwater and surface water quality monitoring event
performed in 2019.
The water quality monitoring network for the Closed Landfill consists of four monitoring wells
(MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background groundwater quality
sampling location (BG SPRING OLD), and two surface water sampling locations (SW-01 OLD
[upstream] and SW-02 OLD [downstream]) located along Profitt Branch. Monitoring wells
MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the western part of
the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower elevations within
topographic drainages in the southern part of the landfill parcel and are screened in the upper
saturated zone.
The water sample collected from background sampling location BG SPRING OLD is treated as a
groundwater sample for the following reasons:
• Groundwater does not discharge to the ground surface at the sampling point.
• Construction of the sampling point is similar to that of a temporary monitoring well and is
located upslope and upgradient of a springhead.
• The sampling point consists of a PVC casing extending below ground surface with a screened
interval from which groundwater is collected and recharges.
See Figure 2 for a map of these approximate sampling locations.
Spring 2019 Semiannual
Water Quality Monitoring Report 1 June 2019

2 Methods
Groundwater samples and surface water samples were collected at the Closed Landfill by
Anchor QEA personnel on March 14, 2019.
2.1 Monitoring Well Sampling Methods
Prior to groundwater sample collection from the monitoring wells, the static water level was
measured and recorded to calculate the well's volume. At each sample location, an initial round of
field parameters (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], oxidation
reduction potential [ORP], turbidity, and temperature) was measured and recorded. Water level
measurements, field parameters, and observations pertaining to water quality are included in the
sampling logs in Appendix A.
2. 7. 7 Monitoring Wells MW-07 OLD, MW-02 OLD, and BG SPRING OLD
Following initial field parameter collection, groundwater monitoring wells MW-01 OLD and
MW-02 OLD and sampling point BG SPRING OLD were each purged using a new disposable
polyethylene bailer. MW-01 OLD and BG SPRING OLD were purged and sampled with a disposable
bailer due to poor well access. MW-02 OLD was purged and sampled with a disposable bailer
because this monitoring well recharges too slowly to be sampled via low -flow methods. As each
consecutive well volume was removed with the bailer, an additional round of groundwater
parameters was recorded. Each well was purged until a minimum of three well volumes had been
removed and field parameters had stabilized, or until the well had been bailed dry. Monitoring well
MW-02 OLD, which was bailed dry after about 1.6 well volumes had been purged, was allowed to
recharge prior to taking three consecutive readings, the last of which was used to collect the
groundwater sample.
A technician wearing a new pair of non -reactive nitrile gloves collected each groundwater sample
and placed it directly into a laboratory -supplied sample container.
2. 7.2 Monitoring Wells MW-03 OLD and MW-04 OLD
Monitoring wells MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump
using low -flow techniques in accordance with the procedures described in Low -Flow (Minimal
Drawdown) Ground -Water Sampling Procedures (Puls and Barcelona 1996). During purging, pH, SC,
DO, ORP, turbidity, and temperature were measured and recorded approximately every 3 minutes.
Well purging continued until these parameters had stabilized for three consecutive readings. The
following required stabilization criteria have been established by the U.S. Environmental Protection
Spring 2019 Semiannual
Water Quality Monitoring Report 2 June 2019

Agency (EPA) Region 4 Science and Ecosystem Support Division Operating Procedure: Groundwater
Sampling (EPA SESD 2017):
• pH values within ± 0.1 unit
• SC values within ± 5%
• Temperature, DO, and turbidity values within ± 10%
After these parameters had stabilized, a technician wearing a new pair of non -reactive nitrile gloves
collected a groundwater sample. Each sample was placed directly into laboratory -supplied sample
containers.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 OLD and SW-02 OLD were collected at designated locations along
Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a westerly direction
(Figure 2). The surface water sample collected at the SW-01 OLD location is interpreted to represent
surface water quality upstream of the Closed Landfill, and the surface water sample collected at the
SW-02 OLD location is interpreted to represent surface water quality downstream of the Closed Landfill.
One set of field parameters including temperature, pH, SC, DO, ORP, and turbidity was measured and
recorded at each surface water sampling location prior to sample collection (Appendix A). One surface
water sample was collected from each sampling location and transferred into laboratory -supplied
sample containers by a technician wearing a new pair of disposable nitrile gloves.
2.3 Domestic Well Sampling Methods
Anchor QEA personnel attempted to contact the resident of the property owned by Ms. J.V. Edwards
but was not able to make contact. As such, Anchor QEA was unable to collect a sample from the
water supply well (DW-01) owned by Ms. Edwards during the spring 2019 sampling event.
2.4 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to water quality sampling at the
Closed Landfill sampling locations are provided in the sampling logs in Appendix A. Following
sample collection, groundwater and surface water samples were immediately placed on ice in sample
coolers for transport to Prism Laboratories, Inc. (Prism), a laboratory certified in North Carolina and
located in Raleigh, North Carolina. Anchor QEA submitted all collected groundwater and surface
water samples to Prism for the following analyses:
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260B
— Appendix I parameters are identified in Appendix I of the Code of Federal Regulations,
Title 40, Part 258 (40 Code of Federal Regulations 258).
Spring 2019 Semiannual
Water Quality Monitoring Report 3 June 2019

• Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 6010D
and 7470A
• 1,4-Dioxane, using method 8260SIM
The North Carolina DEQ, DWM Solid Waste Section (SWS) issued the memorandum "1,4-Dioxane
Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods" dated May 29, 2018, which
requires the analysis of 1,4-dioxane at landfills after July 1, 2018 (DEQ 2018a). Per this memorandum,
1,4-dioxane was included in the sampling suite for site monitoring wells and surface water samples
during the spring 2019 sampling event.
A summary of laboratory analyses performed on the samples is provided in Table 1. Trip blanks,
provided by the laboratory and stored in each sample cooler, were analyzed for Appendix I VOCs
and 1,4-dioxane. Proper chain -of -custody documentation procedures were followed during
collection and transport of each sample. The laboratory analytical reports and chain -of -custody
documentation are included in Appendix B.
Spring 2019 Semiannual
Water Quality Monitoring Report 4 June 2019

3 Findings
The field parameter data and laboratory analytical results for the groundwater, surface water, and
trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively,
and are also submitted separately to the DEQ DWM SWS in the Electronic Data Deliverable format
(updated on May 5, 2010).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections (non -detects) are values reported by the laboratory as
"below method detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The
MDL is the minimum concentration of a substance that can be measured and reported by a
laboratory with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "Y' Qualified: A "Y qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit. The method reporting limit is the minimum concentration of a target
analyte that can be accurately determined by the referenced method.
• 2L Standard: Detected concentrations of constituents in groundwater samples were
compared to applicable North Carolina groundwater quality standards. For most constituents,
this standard is the 2L standard, defined in 15A NCAC 02L .0202. Detected concentrations of
analytes in groundwater with no established 2L standard were compared to the interim
maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L .0202). For the purposes of this report, groundwater
standards were taken from the October 15, 2018 list published by the North Carolina SWS
(DEQ 2018b).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Table 2 summarizes the field parameter results and laboratory analytical results for detected
constituents. The following discussion outlines constituents detected at concentrations that
exceeded their respective 2L standards (including IMACs, if applicable) or 2B standards.
3.1 Groundwater
The following sections summarize the results of field parameter and laboratory analyses of
groundwater samples collected on March 14, 2019.
Spring 2019 Semiannual
Water Quality Monitoring Report 5 June 2019

3.1.7 Field Parameters
The pH readings obtained from monitoring wells MW-01 OLD, MW-03 OLD, MW-04 OLD, and
BG-SPRING OLD (6.15 to 6.38 Standard Units [SU]) were below the range for pH (6.5 to 8.5 SU)
specified in the 2L standard (see Table 2). The pH from monitoring well MW-02 OLD (6.94) was
within the 2L standard.
Turbidity in the monitoring wells ranged from 3.52 Nephelometric Turbidity Units (NTUs) in
monitoring well MW-03 OLD to 208 NTUs in BG-SPRING OLD. Measured DO values ranged from
1.10 milligrams per liter (mg/L) in MW-03 OLD to 8.90 mg/L in MW-02 OLD. Specific conductivity
values ranged from 139.8 microsiemens per centimeter (pS/cm) in BG-SPRING OLD to 924 pS/cm in
MW-03 OLD. ORP values in the monitoring wells ranged from -51.4 millivolts (mV) in MW-03 OLD to
260.1 mV in MW-02 OLD (Table 2). These parameters do not have established groundwater quality
standards. Concentrations of field parameters are generally consistent with historical concentrations.
3.1.2 RCRA Metals
Four metals were detected in groundwater samples collected from one or more monitoring wells
(Table 2). Barium exceeded its 2L standard of 700 micrograms per liter (pg/L) in the samples
collected from monitoring wells MW-03 OLD (830 pg/L) and MW-04 OLD (760 pg/L).
3. 7.3 Appendix l VOCs
Fourteen VOCs were detected in groundwater samples collected from one or more of the
monitoring wells (Table 2). Benzene was detected at a concentration above its 2L standard (1 pg/L) in
monitoring well MW-03 OLD (2.1 pg/L). Vinyl chloride was detected in MW-01 OLD at a
concentration (2.8 pg/L) that exceeded the compound's 2L standard (0.03 pg/L). The VOC detections
are generally consistent with historical data.
3.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 OLD and SW-02 OLD.
3.2. 7 Field Parameters
The pH readings collected from SW-01 OLD and SW-02 OLD were 7.70 and 7.97 SU, respectively.
Both readings were within the 2B standard range established at 6.0 to 9.0 SU.
The turbidity readings collected from SW-01 OLD and SW-02 OLD were 25.9 NTUs and 25.6 NTUs,
respectively. Both readings were below the 2B standard of 50 NTUs.
Spring 2019 Semiannual
Water Quality Monitoring Report 6 June 2019

The DO readings collected from SW-01 OLD and SW-02 OLD were 11.89 and 13.37 mg/L, respectively.
Both values are within the 2B standard for Class C waters (greater than or equal to 5.0 mg/L).
SC measurements in SW-01 OLD and SW-02 OLD were recorded at 182.4 and 146.6 µS/cm,
respectively. ORP values for these samples were recorded at 275.1 and 272.8 mV, respectively
(Table 2). These parameters do not have established surface water quality standards.
3.2.2 RCRA Metals
Four metals were detected in the surface water samples collected at both locations. All metals were
detected at concentrations below their respective 2B standard in SW-01 OLD and SW-02 OLD
(Table 2).
3.2.3 Appendix/ VOCs
Acetone was detected in the samples collected from SW-01 OLD and SW-02 OLD at 6.8 and 6.3 µg/L,
respectively, which are below the 2B standard of 2,000 µg/L. No other VOCs were detected in the
surface water samples collected at either location.
3.3 Site Hydrogeology
Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD,
MW-03 OLD, and MW-04 OLD, at the Closed Landfill at depths of 5.32, 6.95, 34.49, and 36.73 feet
below the top of the well casing (TOC), respectively (Appendix A).
The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit
an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the
shallow groundwater is interpreted to generally mimic topography, flowing primarily southward
toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an
elevation of approximately 2,100 feet above mean sea level and slopes downward toward
Profitt Branch.
Spring 2019 Semiannual
Water Quality Monitoring Report 7 June 2019

4 Summary
Anchor QEA completed the first semiannual water quality monitoring event of 2019 at the
Closed Landfill on March 14, 2019. Table 1 summarizes the sampling and analyses that were
performed. Table 2, the field sampling logs (Appendix A), and the TestAmerica Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and
surface water quality at the Closed Landfill. The following bullets summarize the results of the sampling
event:
• The concentration of barium exceeded its 2L standard of 700 pg/L in the samples collected
from monitoring well MW-03 OLD (830 pg/L) and MW-04 OLD (760 pg/L).
• Benzene was detected at a concentration above its 2L standard of 1 pg/L in MW-03 OLD at
2.1 pg/L.
• Vinyl chloride was detected at a concentration of 2.8 pg/L in the sample collected from
MW-01 OLD, which exceeds the 2L standard of 0.03 pg/L.
• The measured depths to groundwater in the upper saturated zone within the topographic
drainages at the landfill ranged from 5.32 to 6.95 feet below TOC. The groundwater depths in
the bedrock monitoring wells at top of the ridge ranged from 34.49 to 36.73 feet TOC. The
shallow groundwater is interpreted to generally mimic topography, flowing primarily
southward toward Profitt Branch.
4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater and surface water monitoring points associated with the Closed Landfill. Water quality
samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and
Appendix I VOCs, including 1,4-dioxane, on a semiannual basis. The next sampling event is scheduled
for September 2019.
Spring 2019 Semiannual
Water Quality Monitoring Report 8 June 2019

5 References
DEQ (North Carolina Department of Environmental Quality), 2018a. Memorandum to: Solid Waste
Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding:
1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods.
May 29, 2018.
DEQ (North Carolina Department of Environmental Quality), 2018a. "Groundwater Protection
Compliance Standards — Constituents List". Last modified October 15, 2018. Available at:
https://edocs.deq.nc.gov/WasteManagement/0/edoc/1257181/SWS EnviroMonitoring Const
ituents List.pdf?searchid=13f8efbl-eel 1-485a-b03f-718f2287b271
EPA SESD (U.S. Environmental Protection Agency Science and Ecosystem Support Division), 2017.
Operating Procedure: Groundwater Sampling. April 26, 2017.
Puls, R.W., and M.J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling
Procedures. Prepared for the U.S. Environmental Protection Agency, Office of Solid Waste and
Emergency Response. EPA/540/5-95/504. April 1996.
Spring 2019 Semiannual
Water Quality Monitoring Report 9 June 2019

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Facility Permit
Well ID
Collect Date
VOCs
RCRA Metals
EPA 8260B & 8260B
SIM
EPA 6020B
EPA 7470A
58-02
MW-01 OLD
03/14/2019
X
X
58-02
MW-02 OLD
03/14/2019
X
X
58-02
MW-03 OLD
03/14/2019
X
X
58-02
MW-04 OLD
03/14/2019
X
X
58-02
BG SPRING OLD
03/14/2019
X
X
Surface Water Samples
Facility Permit
Sample ID
Collect Date
VOCs
RCRA Metals
Total Hardness
EPA 8260B & 8260B
SIM
EPA 6020B
EPA 7470A
EPA SM 2340C
58-02
SW-01 OLD
03/14/2019
X
X
X
58-02
SW-02 OLD
03/14/2019
X
X
X
Quality Control Samples
Facility Permit
Sample ID
Collect Date
VOCs
EPA 8260B & 8260B
SIM
58-02
TRIP BLANK (MW OLD)
03/14/2019
X
58-02
TRIP BLANK (SW OLD)
03/14/2019
X
Notes:
Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258).
A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event.
EPA: U.S. Environmental Protection Agency
RCRA: Resource Conservation and Recovery Act
SM: standard method
SIM: selective ion monitoring
VOC: volatile organic compound
Spring 2019 Semiannual Water Quality Monitoring Report Page 1 of 1
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 June 2019

Table 2
Summary of Detected Constituents
Lab Certification
Metals
402
Hardness
402
VOCs (Appendix 1)
402
Lab Method
EPA 6020B & 7470A
SM 2340C
EPA 8260B & 8260B SIM
Parameter
Arsenic
Barium
Chromium
Lead
Silver
Hardness
Acetone
Benzene
Chlorobenzene
Chloroethane
cis-1,2-
Dichloroethylene
1,4-Dichlorobenzene
1,1-Dichloroethane
CAS Number
7440-38-2
7440-39-3
7440-47-3
7439-92-1
7440-22-4
NA
67-64-1
71-43-2
108-90-7
75-00-3
156-59-2
106-46-7
75-34-3
SWS ID
14
15
51
131
184
NA
3
16
39
41
78
71
75
Units
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Ng/L
Sample ID
Collect Date
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Monitoring Well Samples
MW-01 OLD
03/14/2019
0.031 U
280
2.5
0.70 J
0.063 U
NA
0.31 U
0.70
1.4
1.1
1.6
2.1
0.43 J
MW-02 OLD
03/14/2019
0.031 U
43
0.19 U
0.37 J
0.063 U
NA
0.31 U
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.92
MW-03 OLD
03/14/2019
0.031 U
830
0.19 U
0.093 U
0.063 U
NA
0.31 U
2.1
7.1
1.2
0.056 U
4.1
0.083 U
MW-04 OLD
03/14/2019
0.031 U
760
2.0
0.82 J
0.063 J
NA
0.31 U
0.41 J
4.7
1.1
0.056 U
2.4
0.083 U
BG SPRING OLD
03/14/2019
0.031 U
120
9.2
2.2
0.063 U
NA
0.31 U
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.083 U
Surface Water Samples
SW-01 OLD
03/14/2019
0.27 J
66
0.98 J
0.29 J
0.063 U
50,000
6.8
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.083 U
SW-02 OLD
03/14/2019
0.28 J
46
1.7 J
0.32 J
0.063 U
41,000
6.3
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.083 U
Quality Control Sample
TRIP BLANK (MW OLD)
03/14/2019
NA
NA
NA
NA
NA
NA
0.31 U
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.083 U
TRIP BLANK (SW OLD)
03/14/2019
NA
NA
NA
NA
NA
NA
0.31 U
0.048 U
0.062 U
0.22 U
0.056 U
0.050 U
0.083 U
MDL
0.031
0.97
0.078
0.19
0.063
570
0.31
0.048
0.062
0.22
0.056
0.050
0.083
MRL
1.0
5.0
1.0
2.0
5.0
5000
5.0
0.50
0.50
0.50
0.50
0.50
0.50
2L
10
700
10
15
20
NE
6,000
1
50
3,000
70
6
6
IMAC
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
2B
10
21,000
38.89*
1.06*
0.83*
NE
2,000
51
800
NE
720
900
100
Spring 2019 Semiannual Water Quality Monitoring Report Page 1 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 June 2019

Table 2
Summary of Detected Constituents
Lab Certification
VOCs (Appendix 1)
402
Field Parameters
5445 (pH, Dissolved Oxygen, Specific Conductivity, and Temperature only)
Lab Method
EPA 8260B & 8260B SIM
Parameter
1,4-Dioxane
Ethylbenzene
m,p-Xylenes
o-Xylene
Trichloroethylene
Toluene
Vinyl Chloride
Total
Xylenes
pH
Turbidity
Dissolved
Oxygen
Temperature
Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number
123-91-1
100-41-4
108-38-3/106-42-3
95-47-6
79-01-6
108-88-3
75-01-4
1330-20-7
SW320
SW330
SW356
7782-44-7
SW323
SW336
SWSID 422
110
359
408
201
196
211
1 346
320
330
1 356
325
323
336
Units Ng/L
Ng/L
Ng/L
Ng/L
I Ng/L
I Ng/L
Ng/L
Ng/L
SU
NTU
mg/L
°CI
PS/cm
mV
Sample ID
Collect Date Result
Result 4-Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Monitoring Well Samples
MW-01 OLD
03/14/2019
2.3 J
0.061 U
0.12 U
0.044 U
0.38 J
0.044 U
2.8
0.15 U
6.15
109
3.80
10.6
368.7
106.7
MW-02 OLD
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
6.94
9.99
8.90
14.9
210.7
260.1
MW-03 OLD
03/14/2019
0.14 U
5.0
0.57 J
0.54
0.078 U
0.044 U
0.097 U
1.1 J
6.38
3.52
1.10
14.9
924
-51.4
MW-04 OLD
03/14/2019
0.14 U
0.061 U
0.89 J
0.33 J
0.078 U
0.25 J
0.097 U
1.2 J
6.27
14.9
4.10
15.6
881
112.2
BG SPRING OLD
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
6.22
208
5.69
11.1
139.8
256.0
Surface Water Samples
SW-01 OLD
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
7.70
25.9
11.89
11.0
182.4
275.1
SW-02 OLD
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
7.97
25.6
13.37
11.6
146.6
272.8
Quality Control Sample
TRIP BLANK (MW OLD)
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
NA
NA
NA
NA
NA
NA
TRIP BLANK (SW OLD)
03/14/2019
0.14 U
0.061 U
0.12 U
0.044 U
0.078 U
0.044 U
0.097 U
0.15 U
NA
NA
NA
NA
NA
NA
MDL
0.14
0.061
0.12
0.044
0.078
0.044
0.097
0.15
NA
NA
NA
NA
NA
NA
MRL
3.0
0.50
1.0
0.50
0.50
0.50
0.50
1.5
NA
NA
NE
NE
NE
NE
2L
3
600
500
500
3
600
0.03
500
6.5-8.5
NE
NE
NE
NE
NE
IMAC
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
2B
80
130
420
600
30
11
2.4
670
6.0-9.0
50
>_ 5.0
NE
NE
NE
Spring 2019 Semiannual Water Quality Monitoring Report Page 2 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 June 2019

Table 2
Summary of Detected Constituents
Notes:
Only detected constituents are listed in this table. Please refer to the Prism laboratory analysis reports for further details.
Shaded cell: indicates a result in exceedance of the 2L, IMAC, or 2B standard
Ng/L: micrograms per liter
pS/cm: microsiemens per centimeter
213: surface water standard, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017), or standard obtained from National Criteria per EPA table (current as of May
15, 2013)
2L: groundwater standard, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards (last amended October 15, 2018)
CAS Number: a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters
Collect Date: the date on which the sample was collected in the field
EPA: U.S. Environmental Protection Agency (method)
IMAC: interim maximum allowable concentration, per Appendix 1 of the 2L standards
J: a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL
Lab Method: the analytical method used to analyze the constituents
MDL: method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99 percent confidence that the analyte concentration is greater than zero
mg/L: milligrams per liter
MRL: method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method
mV: millivolt
NA: not applicable
NE: not established
NTU: Nephelometric Turbidity Unit
Result: analytical data reported by the laboratory, or field data collected by Anchor QEA
SM: Standard Method
SU: Standard Unit
SWS ID: Solid Waste Section identification number
U: laboratory data qualifier used for parameters not detected at concentrations above MDL
VOC: volatile organic compound
*: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A: Department of
Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017).
Spring 2019 Semiannual Water Quality Monitoring Report Page 3 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 June 2019

Figures

AR YJI/V C�
Semn
O -
I
12
^C�11HL
v (t
Y.
• �� I r +moo "� � � O • —
f
f l , also
LEGEND: SOURCES:
Basemap: USGS 1:24,000 Scale Topo Maps, Marshall 2,0
0
0
JZ3 Landfill Parcel Quadrangle, 1990
Parcels: Madison County GIS Feet
Publish Date: 2019/06/05, 11:43 AM I User: alesueur
Filepath: \\Ashevillel\Asheville\GIS_Projects\MadisonCounty\Maps\2019\Spring WaterQuality\AQ_F01_SiteLocationMap_ClosedLF_SpringWQ2019.mxd
ANCHOR Figure 1
QEA�`�.;" Site Location Map
Anchor QEA of North Carolina, PLLC
Spring 2019 Semiannual Water Quality Monitoring Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02

MW-03 OLD
q
0,
FD,
OR
-'A
-S LD
ff-coa ro,LD
C0 V"D
4
LEGEND:
NOTE:
Roads
Monitoring well and surface water
Monitoring Well Location
samples are approximate.
0
V Surface Water Sample Location
Streams
SOURCES:
--J Landfill Parcel Boundary
Basemap: NC OneMap 2010
Contours and Roads: NCDOT
0 400
— Elevation Contours (10-Foot Interval)
Streams: NC OneMap
Parcel Boundary: Madison County GIS
Feet
Publish Date: 2019/06/05,12:28 PM I User: alesueur
Filepath: \\Ashevillel\Asheville\GIS-Projects\MadisonCounty\Maps\2019\SpringWaterQuality\AQ-FO2-SampleLocationMap_ClosedLF-SpringWQ2019.mxd
ANCHOR
Figure 2
QEA -
Anchor QEA of North Carfi- PLLC
Sample Location Map
Spring 2019 Semiannual Water Quality Monitoring Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

ANCHOR
QEA
Well Sampling Log
r-
Date: 3 A,*1 j, ti Well Name: � a I ., I_ n I n I I%
Project Name:
MaA ism GJ, CLOWA l�
Project Number.
CQ.So6 - O t , o ( -Na t-- 02- Weather 5
Sampling Personnel:
lklm(iEilVi U,;,, Sample Time:
Well Information: Well Depth in Feet (WD):
_
Well Diameter. Water Level in Feet (WL): c,
Type of Casing: V(� Length of Water Column: ` feet
Screen Interval: J\ GL (WD) - (WL) = (LWC)
Flush Moun Stick
x
p One Casing Volume: 9
a e 3 allons
Comments:
(LwQ x (WM
t Three Casing Volumes: gallons
Tagged /,,n
bottom at d U �C6
2A:I Actual Volume Purged: gallons
Y '�j 1 V �/ g �� C
Well Casing Volumes (WCV)
1" = 0.041 GaVFt " = :17ZIJF)3" = 0.38 Gal/Ft _ 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft
Purge Method:
Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method:
Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
MAWi
'Gallons ;t l emp Dissgfved Specific to18 pH (S U) "� Redu grl, TurbtlT .. -a
3�
9 =}Tgne
r
Pupd'E
�9l°Ci. -0x)►9eo (m9)_ ' f_N?/cm) +Peport,to 0 i S`U Pgten Eial irt1U
:Readrn
, r .r {i�TU) 3.s ,-, Comtnentgi
1
was
3
2
13MP903
3
l
4
3
3
)121
5
f ' ao
6
it .
�.
7
.4SD52
8
9
10
Notes:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per centimeter
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U: Standard Units
Protective Casing: Pad: LoclC Vegetatio- Access: jem
Sa� mPling Personnel Signature: Date: 31 4M
initial if well information and sampling data has been verified _
well was tagged after sampling was complete

ANCHOR
QFA �-�-
Well Sampling Log
Date: 3 J ( uk I i 1:1 Well Name: AA tW-A 7_ in r ,►7
Project Name: MaA ism G6,
CLdsea
Project Number. _CRIGA6 -
Q i , 0 1 02,,, Weather.
Sampling Personnel: Mkt
G �� �� Sample Time:
Well Information:
Well Depth in Feet (WD):
Well Diameter lin
_
Water Level in Feet (WL): IS fl_,�
Type of Casing:
Length of Water Column: feet
Screen In�1:tN GL
(WD) - (WL) = (LWC)Flush
Mount S
One Casing Volume: gallons
Comments: _
-
_ (LWC) x (WCV)
Three Casing Volumes: �� �5� gallons
Tagged?� f T
T
7'p� Actual Volume Purged: %6.. %Sgallons
bottom at:
Well Casing Volumes (WCV)
1" = 0.041 Gal/Ft �-0_17QI/Ft3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft
Purge Method: ailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method: Bailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
.
`
_`
Gallons''
temp'
Di3soived
Spec(fic Conti «
f
Pi (S
1U)
f� �ReducEign'
htubidity
Re�din 9
< Time
r I�u r9 ..:`
E°4�'
�xY9en (mgri)
� �f CI9/cm)�
►ePott3to 01'f!
PotentTa�itti
i1TRl)
:.:.
•; � mot.. � a�
Comments r,
Q�63b
f
2
U
, ja,,1
i .,�;
q. V-7
Z2oeq
6 9Lf
3
�, b
5
!D
S.Z
�'• S
�l.Z-K
ZS5.2
/o_.
6
10•50
15.2
$
Z/2-G
6•T c,
7,59,.
7
210.
�,11 q
260 i
q_ R
8
9
10
Notes:
Samples are analyzed immediately upon collection.
°C degrees Celsius
pS/cm: micro-Siemen per centimeter
t
mg/L: milligrams per liter
mv: millivolt
NTU: neplielometric turbidity units
u
S.U.: Standard Units
��
Protective Casing: _b� W Pad: L% Lock _W Vegetation: Access: _-WQ(
Sampling Personnel Signature:
Date: 'bl i ql1 l
initial if well information and sampling data has been verified
well was tagged after sampling was complete

ANCHOR
Low -Flow Sampling Log Date: Jif Well Name: f1/ W 0:j o OLD
Project Name: -660AQ _ G(OV-A L Project Number. dJZJ G o p
Location: LL,NC
Personnel:- �!'h� A. a.to�,\ Weather: 05
Well Information: j
Screen Interval:y ��- bgs Arrive at Well: Gq�S
Depth to Water: 7�[ �.i,(�j i�r� toc Start Time: ©i
Well Diameter: J-1�T in Sample Time: 04
Pump Intake: ry toc Finish Sample Time: %
Drawdown Set: r-( I - toc Leave Well:
Pump Used (circle): Peristaltic B a� Other (description):
Comments: Purge Rate: 2•30 mL 1 "iI7
Tagged bottom at: 223-3 •••F+ ' 4- Total Purge Volume: Z �. `3 L
Pump Speed: S -- rr S' - I., 7' .0
Temj pp.
YF-
Ico0't'
34.57
ILf-q
+f.r►
32
3
2.
yo
I Os
,1f'4
q I
3y. 7s
�. 3�
K I
6, 37
—3 .
5.62
►� ►r
3�i �s
Ps.3
�•
aq
.37
-Y.S-V
3. 6-
lvlq
3� i�
)s.�
i.��
-1r4
-'t 3
1
elI`f
6- 3qC.
3.73
q2 q
i
-51.4.s�,
between
Sampling Personnel Signature: Date:
Notes:
Stabilization
3 successive readings, 3 minutes apart:
within +/- 10% DO and turbidity; +/- 3%Conductivity,• +/- a pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
pS: micro-Siemen mv: millivolt
'C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg/L: milligrams per liter toc: top of casing
'f
y S� aat=a
initial if well information and sampling data has been verified I�MJv
well was tagged after sampling was complete

ANCHOR
Z QEA � '
Low -Flow Sampling Log Date: L Well Name: M,W QL� Ott
Project Name: tSOAO UOs<A LF Project Number. Z'lSOQ
Location: Y'Swc,
Personnel: Weather. 6
Well Information:
Screen Interval: bgs Arrive at Well:
Depth to Water: '�j�kk—toc Start Time: 1L}-
Well Diameter: `a in Sample Time:
Pump Intake: toc Finish Sample Time_112D
Drawdown Set: 99 toc Leave Well: I ! q n
�+
Pump Used (circle): Peristaltic Bladder Other (description):
Comments: Slim • e Purge Rate: jr1^
Tagged bottom at: ay t Total Purge Volume: L
Pump Speed: `Sa- 5
X qr'
`h
r i° yi
V4 D;7 W Temp _ DO Specr'f➢C COnd pH {$ U) ORP :�� Turbrdity
{PS) report to 0 7�, {mVj " ` • {NTU) Comments-
15-. ti iCi..
MR
between recharge during Sample collection:
Sampling Personnel Signature: %LL"'- \'__- Date: 3 f i L f/ 1 I
Notes:
Stabilization
3 successive readings, 3 minutes apart:
within +/- 10% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit; +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
NS: micro-Siemen mv: millivolt
°C: degrees Celsius NTU: nephelometric turbidity units
bgs: below ground surface ORP: oxidation reduction potential
DO: dissolved oxygen S.U.: standard units
mg/L milligrams per liter toc: top of casing
initial if well information and sampling data has been verified t��
well was tagged after sampling was complete

4-0 ANCHOR
.a QEA
Well Sampling Log
Date: '� I e.1 I rA Well Name: P,)(n' -SP2_ I fir, Al T-)
Project Name: Iyll2A ism Go, UowA
Project Number. (_'(i1.Ci d 6 — 01 . 01
O 2, Weather y tj z
Sampling Personnel: �� �
c
Sample Time:
Well Information:
Well Depth in Feet (WD):
Well Diameter. a (�
Water Level in Feet (WL): q'06 /
Type of Casing: P
Length of Water Column; `��`� feet
Screen Screen Interval: y\_ p�,
(WD) - (WL) = (LWC)
Flush Mount Stick-U p
} '.'
One Casing Volume: , gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes: , a gallons
Tagged �/� a bO
", V rL �
Actual Volume Purged:;z gallons
�a
bottom at:
_.
Well Casing Volumes (WCV)
1" = 0.041 Gal/Ft 2" = 0.17 Gal/F 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft
Purge Method: ailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
' �
*,
� .
ZJE.
� -Y .. Yb'��
.-' �� ✓�
iL - r4V
- .tti
� 4'�Gallons.
.Yyq A�S"e� }
Temp
�� DissQived
`p°,pg'�
5pecificCont)�
�1.
pH(SU)f."t
• y
`fie�u�4np
>
Turiidity
�
ti ��
d,Y'�r Yy}. v"af SRw•
Reading
;,Timed
PuE �d;�
.
� i°c�f,'"
F� ia•.±�
�Y9en (m�l_�)
a."fv i _'S
x . C1+S/cFli),; ,,�
M. v'`a °T�,eld
+seporttb 0,i S.(j
� N ,^ (r
Ppt@rltial (r�fl}
<Y� ry
(l�T� ir,�
rY-eJ ,�.k�H
r_ �` [omihents
2
I�
,•
.�s0
44-
3
s
4,
4
a-
i1
5
�.
6
7
8
9
10
Notes:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: Standard Units
Protective Casing Pad: —0kLock Vegetation: L—j)��Access:
Sampling Personnel Signature:
Date:
initial if well information and sampling data has been verified J
well was tagged after sampling was complete

ANCHOR
C)EA
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: AAA A " f�, o
Project Number. U S6j) A a L 0' `T72 (�
Sampling Personnel: 'A G A-eAit
Sample Name: D "i -o l b ('[7 .
Comments:
�
UZ
mA
Date:_�jig C
Weather.
C
Sample Method: Grab (Syringe)
Pump
Bailer-Disp. Other.
lime
%
Ar �'.
Oxygen°109/ij-
pwff�
(}t5/tmj
report'to 0 T S:U.
Polientt�i (mV)
;
Sampling ContainerNumbers
of Co r,
.. _w-
Request eda4 '
sn^ mL PlasticQ
250 mL Plastic
I 1
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: WA-9 V'WAO & QMAsi, A
Access: 6 Y--
Sampling Personnel Signature: Date: 41
s._.__. Methnd Ref.mn
Samples are analyzed immediately upon collection.
'C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L• milligrams per liter,
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Temperature: SM 2550 B-2010
Speck conductivity. EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
Anchor QEA of North Carolina, PLLC
Surface Water Sampling Log
231 Haywood Street
Asheville, North Carolina 28801
Project Name:
r
Project NumbeMC
Sampling Personnel:
m
Sample Na e.
Comments:
_-N &W ka-A Ca CA av'A LE
() ; 0 i s
S Vq
co(LaucJ dewAetr� �A-
Date:
Weather
J
ca--t,A.6 11
Sample Method:
Grab
Syringe
Pump
Bailer-Disp. Other.
Vitt
S/C4'
�- U0
n 's, 11
ii4port to 0.1''S.U.
Rz
a
6 1 (Ihv)
zz
0-
mp
I+lumber of
IWquaMMA" t V 4'
500 mL Plastic
2F0 mL Plastic
125 mL. Plastic
40 mL Glass
1 L Glass
Other
Vegetation: (0 r&v-vl �0 Access:
Sampling Personnel Signature: Date: ,7 3-/
Ki M.th-1 Rf.-.,.-
Samples are analyzed immediately upon collection.
T: degrees Celsius
PS/cm: micro-Siemen per cubic centimeter
mg/L milligrams per liter.
m\t. millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Temperature SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev, 1982
DO, SM 4500 0 G-2011
PH: SM 4500-H * B-2011
Page 1 of 1

ANCHOR
Equipment Documentation and Instrument Calibration Data Sheet
CALIBRATION DOCUMENTATION
Project Name: f �' u -- Person Conducting Calibration:
Project Number. dJ - 1 �} I . Date of Calibration:
Project Location: A a .ice Xe A ` �jG Date of Field Measurements:
EQUIPMENT DOCUMENTATION
Equipment or meters used to take measurements (e.g.; water level meters, survey equipment):
Eoj iph7ent:7 ie
; 513 s tifumba r_..
13�atii3-.
Da3eivf
150-ft Water Level
26154
Solinist
150-ft Water Level
22754
Solinist
150-ft Water Level
150
Testwell
150-ft Drawdown
MP30-1527
QED
Other
Select Turbidimeter. Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Ins6iinnenl Reading
(Hacfa 210DQ)
Calibration 20 NTU 100 NTJJI 800 NTU
gdtkpiration Date: Ir 5 I-m I r,-Lv l7
Instrument Reading
(HF 5 ientific MicroTPW)
1,ODONTU 1 11J. NTU
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
are'
Ti e� Time TimeQ': 2/
Q�
Time:
Time:
Time:
YIIfJ
Verification (10 NTU):
Verification:
Verification:
Verificatio,..
.� .
Tim 10 NTU Cal. E> ion Date:
Timm
Time:
Time:
YSI Professional Plus MuWparameter
Meter
(sin 18810180z)
Instrument Readings
Initial: Cal: mmHg:
Temperature
Cali6ratianira_tiain p��g
Dissolved Oxygen
i f� �_ �, O
E V UlJ (A.
CC):
1 j•r D
Time:
u.
NA
PH 7 S.U.
report to 0.1 S.U.
Initial: pHmV: Cal:
-2) (y,b
pHmV:
-?,5
Time:
6_-�J �
a� r1.,K.-
�lJ
PH 4 S.U.
report too. IS. U.
I jniT'a1: pHmmV": Cal: f
' 1� ©J �'tpg/� *mot r/ �
pHm>V:
�iv�a�
Time:
1.
/�(�
V'I ; �
PH 10 S.U. Initial:
report to 0.1 S.U.
pHmV: Cal: //����
..
U 7 �' �� W
pHmV;
— G r3
Tim
0
QC* pH.7 S.U.
AM im-e: Mws:Mid Day Time:
raj:a
Check-
PM Time:
Check-,
report to 0.7 S.U.
y6
w
Sp/IID ellc. Cond. Initial:
SOOD
Cal:
Cal: Time: f�
�'J IrV
/�
1
66{I
QC*:
lid pS/cm
AM Time: �/ 4 M jieass: Mid Day Time:
� "^7 �-I V ( q
Check:
PM Time:
Check:
N /
ORP✓-(93' 9Initial:
mV
Cal: Temperature CC):
��� 0
Time:
()TX
_
Signature: LZ Date: 5/1 Z' I q
Notes:
1. Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibrationis as follows: Specific Conductivity, pH 7, pH 4, pH 16, DO, ORP, QC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
S. * Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours. .
6. •' Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location.
Method Reference: Temperature: SM 2550 8-2010 I Specific conductivity. EPA Method 120.7, Rev. 1982 1 DO: SM 4500 0 G-2011 I pH: SM 4500-H+ 8-2017
Page 1 of 1

Appendix B
Report of Laboratory Analysis and
Chain -of -Custody Documentation

LP R I S M Full -Service Analytical &
Environmental Solutions
LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC
Brian Gant
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Project: Madison Closed Landfill
Lab Submittal Date: 03/15/2019
Prism Work Order: 9030262
Case Narrative
4/2/19 15:37
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
Robbi A. Jones Reviewed By Robbi A. Jones
President/Project Manager President/Project Manager
Data Qualifiers Key Reference:
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 1 of 18

Sample Receipt Summary
Full -Service Analytical R
S
fflyaR I M Environmental Solutions
04/02/2019
LABORATORIES, INC.
Prism Work Order: 9030262
Client Sample ID
Lab Sample ID
Matrix
Date/Time Sampled Date/Time Received
SW-01 OLD
9030262-01
Water
03/14/19 13:13 03/15/19 9:00
SW-02 OLD
9030262-02
Water
03/14/19 12:46 03/15/19 9:00
Trip Blank
9030262-03
Water
03/14/19 0:00 03/15/19 9:00
Samples were received in good condition at 3.3 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 2 of 18

Full -Service Analytical &
/r PRISM Environmental Solutions
LABORATOR
Summary of Detections
04/02/201 g
Prism Work Order: 9030262
Prism ID
Client ID
Parameter
Method
Result Units
9030262-01
SW-01 OLD
Hardness
SM2340 C
50000 ug/L
9030262-01
SW-01 OLD
Arsenic
6020B
0.27 J ug/L
9030262-01
SW-01 OLD
Barium
6020B
66 ug/L
9030262-01
SW-01 OLD
Chromium
6020B
0.98 J ug/L
9030262-01
SW-01 OLD
Lead
6020B
0.29 J ug/L
9030262-01
SW-01 OLD
Acetone
8260B
6.8 ug/L
9030262-02
SW-02 OLD
Hardness
SM2340 C
41000 ug/L
9030262-02
SW-02 OLD
Arsenic
6020B
0.28 J ug/L
9030262-02
SW-02 OLD
Barium
6020B
46 ug/L
9030262-02
SW-02 OLD
Chromium
6020B
1.7 J ug/L
9030262-02
SW-02 OLD
Lead
6020B
0.32 J ug/L
9030262-02
SW-02 OLD
Acetone
8260B
6.3 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 3 of 18

%j6P R I S M Full -Service Analytical
Environmental Solutions
LABORATORIES, INC.
Laboratory Report
04/02/2019
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Project: Madison Closed Landfill
Sample Matrix: Water
Client Sample ID: SW-01 OLD
Prism Sample ID: 9030262-01
Prism Work Order: 9030262
Time Collected: 03/14/19 13:13
Time Submitted: 03/15/19 09:00
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
General Chemistry Parameters
Hardness 50000 ug/L 5000 570 1 SM2340 C 3/27/19 10:29 BMS P9C0520
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:05 MMR
P9C0329
Arsenic
0.27 J
ug/L
10
1.0
0.031
1
6020B
3/19/19
18:25
JAB
P9CO297
Barium
66
ug/L
100
5.0
0.97
1
6020B
3/19/19
18:25
JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
6020B
3/19/19
18:25
JAB
P9CO297
Chromium
0.98 J
ug/L
10
2.0
0.19
1
6020B
3/19/19
18:25
JAB
P9CO297
Lead
0.29 J
ug/L
10
1.0
0.093
1
6020B
3/21/19
19:22
JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19
18:25
JAB
P9CO297
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19
18:25
JAB
P9CO297
Volatile Organic Compounds by GUMS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/16/19
4:37
KDM
P9CO287
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/16/19
4:37
KDM
P9CO287
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/16/19
4:37
KDM
P9CO287
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/16/19
4:37
KDM
P9CO287
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/16/19
4:37
KDM
P9CO287
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/16/19
4:37
KDM
P9CO287
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/16/19
4:37
KDM
P9CO287
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/16/19
4:37
KDM
P9CO287
Acetone
6.8
ug/L
100
5.0
0.31
1
8260B
3/16/19
4:37
KDM
P9CO287
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/16/19
4:37
KDM
P9CO287
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/16/19
4:37
KDM
P9CO287
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/16/19
4:37
KDM
P9CO287
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/16/19
4:37
KDM
P9CO287
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/16/19
4:37
KDM
P9CO287
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/16/19
4:37
KDM
P9CO287
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/16/19
4:37
KDM
P9CO287
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/16/19
4:37
KDM
P9CO287
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/16/19
4:37
KDM
P9CO287
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/16/19
4:37
KDM
P9CO287
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/16/19
4:37
KDM
P9CO287
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 4 of 18

Laboratory Report
Full -Service
P R S M
Analytical &
Environmental
LABORATORIES INC.
Solutions
04/02/2019
Anchor QEA of North Carolina, PLLC
Project: Madison Closed
Landfill
Client
Sample ID:
SW-01 OLD
Attn: Brian Gant
Prism
Sample ID:
9030262-01
231 Haywood Street
Prism
Work Order:
9030262
Asheville, NC 28801
Sample Matrix: Water
Time
Collected: 03/14/19 13:13
Time
Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/16/19
4:37
KDM
P9CO287
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/16/19
4:37
KDM
P9CO287
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/16/19
4:37
KDM
P9CO287
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/16/19
4:37
KDM
P9CO287
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/16/19
4:37
KDM
P9CO287
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/16/19
4:37
KDM
P9CO287
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/16/19
4:37
KDM
P9CO287
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/16/19
4:37
KDM
P9CO287
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/16/19
4:37
KDM
P9CO287
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/16/19
4:37
KDM
P9CO287
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/16/19
4:37
KDM
P9CO287
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/16/19
4:37
KDM
P9CO287
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1
8260B
3/16/19
4:37
KDM
P9CO287
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/16/19
4:37
KDM
P9CO287
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/16/19
4:37
KDM
P9CO287
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/16/19
4:37
KDM
P9CO287
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/16/19
4:37
KDM
P9CO287
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/16/19
4:37
KDM
P9CO287
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/16/19
4:37
KDM
P9CO287
trans- 1,4-Dichloro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/16/19
4:37
KDM
P9CO287
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/16/19
4:37
KDM
P9CO287
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/16/19
4:37
KDM
P9CO287
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/16/19
4:37
KDM
P9CO287
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/16/19
4:37
KDM
P9CO287
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1
8260B
3/16/19
4:37
KDM
P9CO287
Surrogate
Recovery
Control Limits
4-Bromofluorobenzene
100 %
80-124
Dibromofluoromethane
106 %
75-129
Toluene-d8
98 %
77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/25/19 16:17 JLB
P9C0434
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 5 of 18

�Full-Service Analytical
P R I S M
Environmental Solutions
LABORATORIES INC.
Laboratory Report
04/02/2019
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Project: Madison Closed Landfill
Sample Matrix: Water
Client Sample ID: SW-02 OLD
Prism Sample ID: 9030262-02
Prism Work Order: 9030262
Time Collected: 03/14/19 12:46
Time Submitted: 03/15/19 09:00
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
General Chemistry Parameters
Hardness 41000 ug/L 5000 570 1 SM2340 C 3/27/19 10:29 BMS P9C0520
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:09 MMR
P9C0329
Arsenic
0.28 J
ug/L
10
1.0
0.031
1
6020B
3/19/19 18:31
JAB
P9CO297
Barium
46
ug/L
100
5.0
0.97
1
6020B
3/19/19 18:31
JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
6020B
3/19/19 18:31
JAB
P9CO297
Chromium
1.7 J
ug/L
10
2.0
0.19
1
6020B
3/19/19 18:31
JAB
P9CO297
Lead
0.32 J
ug/L
10
1.0
0.093
1
6020B
3/21/19 19:29
JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 18:31
JAB
P9CO297
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19 18:31
JAB
P9CO297
Volatile Organic Compounds by GUMS
1, 1, 1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/16/19 5:11
KDM
P9CO287
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/16/19 5:11
KDM
P9CO287
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/16/19 5:11
KDM
P9CO287
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/16/19 5:11
KDM
P9CO287
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/16/19 5:11
KDM
P9CO287
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/16/19 5:11
KDM
P9CO287
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/16/19 5:11
KDM
P9CO287
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/16/19 5:11
KDM
P9CO287
Acetone
6.3
ug/L
100
5.0
0.31
1
8260B
3/16/19 5:11
KDM
P9CO287
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/16/19 5:11
KDM
P9CO287
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/16/19 5:11
KDM
P9CO287
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/16/19 5:11
KDM
P9CO287
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/16/19 5:11
KDM
P9CO287
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/16/19 5:11
KDM
P9CO287
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/16/19 5:11
KDM
P9CO287
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/16/19 5:11
KDM
P9CO287
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/16/19 5:11
KDM
P9CO287
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/16/19 5:11
KDM
P9CO287
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/16/19 5:11
KDM
P9CO287
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/16/19 5:11
KDM
P9CO287
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 6 of 18

Laboratory Report
Full -Service
P R S M
Analytical &
Environmental
LABORATORIES INC.
Solutions
04/02/2019
Anchor QEA of North Carolina, PLLC
Project: Madison Closed
Landfill
Client
Sample ID:
SW-02 OLD
Attn: Brian Gant
Prism
Sample ID:
9030262-02
231 Haywood Street
Prism
Work Order:
9030262
Asheville, NC 28801
Sample Matrix: Water
Time
Collected: 03/14/19 12:46
Time
Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis
Analyst
Batch
Limit
Factor
Date/Time
ID
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/16/19
5:11
KDM
P9CO287
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/16/19
5:11
KDM
P9CO287
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/16/19
5:11
KDM
P9CO287
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/16/19
5:11
KDM
P9CO287
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/16/19
5:11
KDM
P9CO287
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/16/19
5:11
KDM
P9CO287
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/16/19
5:11
KDM
P9CO287
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/16/19
5:11
KDM
P9CO287
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/16/19
5:11
KDM
P9CO287
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/16/19
5:11
KDM
P9CO287
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/16/19
5:11
KDM
P9CO287
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/16/19
5:11
KDM
P9CO287
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1
8260B
3/16/19
5:11
KDM
P9CO287
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/16/19
5:11
KDM
P9CO287
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/16/19
5:11
KDM
P9CO287
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/16/19
5:11
KDM
P9CO287
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/16/19
5:11
KDM
P9CO287
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/16/19
5:11
KDM
P9CO287
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/16/19
5:11
KDM
P9CO287
trans- 1,4-Dichloro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/16/19
5:11
KDM
P9CO287
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/16/19
5:11
KDM
P9CO287
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/16/19
5:11
KDM
P9CO287
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/16/19
5:11
KDM
P9CO287
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/16/19
5:11
KDM
P9CO287
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1
8260B
3/16/19
5:11
KDM
P9CO287
Surrogate
Recovery
Control Limits
4-Bromofluorobenzene
97 %
80-124
Dibromofluoromethane
109 %
75-129
Toluene-d8
97 %
77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/25/19 16:43 JLB
P9C0434
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 7 of 18

�Full-Service Analytical s
P R I S M
Environmental Solutions
LABORATORIES INC.
Laboratory Report
04/02/2019
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Project: Madison Closed Landfill
Sample Matrix: Water
Client Sample ID: Trip Blank
Prism Sample ID: 9030262-03
Prism Work Order: 9030262
Time Collected: 03/14/19 00:00
Time Submitted: 03/15/19 09:00
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GUMS
1, 1, 1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/15/19 22:24 KDM
P9CO287
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/15/19 22:24 KDM
P9CO287
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/15/19 22:24 KDM
P9CO287
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/15/19 22:24 KDM
P9CO287
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/15/19 22:24 KDM
P9CO287
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/15/19 22:24 KDM
P9CO287
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/15/19 22:24 KDM
P9CO287
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/15/19 22:24 KDM
P9CO287
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/15/19 22:24 KDM
P9CO287
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/15/19 22:24 KDM
P9CO287
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/15/19 22:24 KDM
P9CO287
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/15/19 22:24 KDM
P9CO287
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/15/19 22:24 KDM
P9CO287
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/15/19 22:24 KDM
P9CO287
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/15/19 22:24 KDM
P9CO287
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/15/19 22:24 KDM
P9CO287
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/15/19 22:24 KDM
P9CO287
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/15/19 22:24 KDM
P9CO287
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/15/19 22:24 KDM
P9CO287
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/15/19 22:24 KDM
P9CO287
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/15/19 22:24 KDM
P9CO287
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/15/19 22:24 KDM
P9CO287
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/15/19 22:24 KDM
P9CO287
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/15/19 22:24 KDM
P9CO287
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/15/19 22:24 KDM
P9CO287
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/15/19 22:24 KDM
P9CO287
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/15/19 22:24 KDM
P9CO287
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/15/19 22:24 KDM
P9CO287
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/15/19 22:24 KDM
P9CO287
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/15/19 22:24 KDM
P9CO287
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/15/19 22:24 KDM
P9CO287
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 8 of 18

Laboratory Report
P R S M
Full -Service Analytical &
LABORATORIES INC.
Environmental Solutions
04/02/2019
Anchor QEA of North Carolina,
PLLC
Project: Madison Closed
Landfill
Client Sample ID: Trip Blank
Attn: Brian Gant
Prism Sample ID: 9030262-03
231 Haywood Street
Prism Work Order: 9030262
Asheville, NC 28801
Sample Matrix: Water
Time Collected: 03/14/19 00:00
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution Method Analysis Analyst
Batch
Limit
Factor Date/Time
ID
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1 8260B 3/15/19 22:24 KDM
P9CO287
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1 8260B 3/15/19 22:24 KDM
P9CO287
Styrene
<0.047
ug/L
1
0.50
0.047
1 8260B 3/15/19 22:24 KDM
P9CO287
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1 8260B 3/15/19 22:24 KDM
P9CO287
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1 8260B 3/15/19 22:24 KDM
P9CO287
Toluene
<0.044
ug/L
1
0.50
0.044
1 8260B 3/15/19 22:24 KDM
P9CO287
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1 8260B 3/15/19 22:24 KDM
P9CO287
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1 8260B 3/15/19 22:24 KDM
P9CO287
trans- 1,4-Dichloro-2-butene
<0.12
ug/L
100
10
0.12
1 8260B 3/15/19 22:24 KDM
P9CO287
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1 8260B 3/15/19 22:24 KDM
P9CO287
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1 8260B 3/15/19 22:24 KDM
P9CO287
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1 8260B 3/15/19 22:24 KDM
P9CO287
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1 8260B 3/15/19 22:24 KDM
P9CO287
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1 8260B 3/15/19 22:24 KDM
P9CO287
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
101 % 80-124
Dibromofluoromethane
106 % 75-129
Toluene-d8
99 % 77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1 8260B SIM 3/25/19 15:02 JLB
P9C0434
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 9 of 18

Full -Service Analytical &
14LANKO�TORIES�
S M Environmental Solutions
INC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO287 - 5030B
Blank (P9CO287-BLK1)
Prepared & Analyzed: 03/15/19
1,1,1,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,1-Trichloroethane
BRL
0.50
ug/L
1,1,2,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,2-Trichloroethane
BRL
0.50
ug/L
1,1-Dichloroethane
BRL
0.50
ug/L
1,1-Dichloroethylene
BRL
0.50
ug/L
1,2,3-Trichloropropane
BRL
1.0
ug/L
1,2-Dibromo-3-chloropropane
BRL
2.0
ug/L
1,2-Dibromoethane
BRL
0.50
ug/L
1,2-Dichlorobenzene
BRL
0.50
ug/L
1,2-Dichloroethane
BRL
0.50
ug/L
1,2-Dichloropropane
BRL
0.50
ug/L
1,4-Dichlorobenzene
BRL
0.50
ug/L
Acetone
BRL
5.0
ug/L
Acrylonitrile
BRL
20
ug/L
Benzene
BRL
0.50
ug/L
Bromochloromethane
BRL
0.50
ug/L
Bromodichloromethane
BRL
0.50
ug/L
Bromoform
BRL
1.0
ug/L
Bromomethane
BRL
1.0
ug/L
Carbon disulfide
BRL
5.0
ug/L
Carbon Tetrachloride
BRL
0.50
ug/L
Chlorobenzene
BRL
0.50
ug/L
Chloroethane
BRL
0.50
ug/L
Chloroform
BRL
0.50
ug/L
Chloromethane
BRL
0.50
ug/L
cis-1,2-Dichloroethylene
BRL
0.50
ug/L
cis-1,3-Dichloropropylene
BRL
0.50
ug/L
Dibromochloromethane
BRL
0.50
ug/L
Dibromomethane
BRL
0.50
ug/L
Ethylbenzene
BRL
0.50
ug/L
m,p-Xylenes
BRL
1.0
ug/L
Methyl Butyl Ketone (2-Hexanone)
BRL
5.0
ug/L
Methyl Ethyl Ketone (2-Butanone)
BRL
5.0
ug/L
Methyl Iodide
BRL
5.0
ug/L
Methyl Isobutyl Ketone
BRL
5.0
ug/L
Methylene Chloride
BRL
1.0
ug/L
o-Xylene
BRL
0.50
ug/L
Styrene
BRL
0.50
ug/L
Tetrachloroethylene
BRL
0.50
ug/L
Tetrahydrofuran
BRL
10
ug/L
Toluene
BRL
0.50
ug/L
trans- 1,2-Dichloroethylene
BRL
0.50
ug/L
trans- 1,3-Dichloropropylene
BRL
0.50
ug/L
trans-1,4-Dichloro-2-butene
BRL
10
ug/L
Trichloroethylene
BRL
0.50
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 10 of 18

PR I S M Full -Service Analytical Environmental Solutions
LABCFATCRIES, NC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO287 - 5030B
Blank (P9CO287-BLK1)
Prepared & Analyzed: 03/15/19
Trichlorofluoromethane
BRL
0.50
ug/L
Vinyl acetate
BRL
2.0
ug/L
Vinyl chloride
BRL
0.50
ug/L
Xylenes, total
BRL
1.5
ug/L
Surrogate:4-Bromofluorobenzene
51.7
ug/L
50.00
103
80-124
Surrogate: Dibromofluoromethane
52.0
ug/L
50.00
104
75-129
Surrogate: Toluene-d8
49.7
ug/L
50.00
99
77-123
LCS (P9CO287-BSI)
Prepared &Analyzed: 03/15/19
1,1,1,2-Tetrachloroethane
20.8
0.50
ug/L
20.00
104
79-134
1,1,1-Trichloroethane
23.1
0.50
ug/L
20.00
116
75-136
1,1,2,2-Tetrachloroethane
19.7
0.50
ug/L
20.00
99
62-127
1,1,2-Trichloroethane
20.9
0.50
ug/L
20.00
104
70-140
1,1-Dichloroethane
22.4
0.50
ug/L
20.00
112
78-130
1,1-Dichloroethylene
22.7
0.50
ug/L
20.00
113
70-154
1,2,3-Trichloropropane
21.0
1.0
ug/L
20.00
105
71-127
1,2-Dibromo-3-chloropropane
19.4
2.0
ug/L
20.00
97
63-134
1,2-Dibromoethane
19.3
0.50
ug/L
20.00
96
77-135
1,2-Dichlorobenzene
20.4
0.50
ug/L
20.00
102
78-128
1,2-Dichloroethane
21.7
0.50
ug/L
20.00
109
68-131
1,2-Dichloropropane
22.0
0.50
ug/L
20.00
110
77-130
1,4-Dichlorobenzene
19.2
0.50
ug/L
20.00
96
75-126
Acetone
46.3
5.0
ug/L
40.00
116
40-166
Acrylonitrile
39.9
20
ug/L
40.00
100
81-127
Benzene
22.2
0.50
ug/L
20.00
ill
77-128
Bromochloromethane
21.7
0.50
ug/L
20.00
109
78-135
Bromodichloromethane
21.5
0.50
ug/L
20.00
107
76-138
Bromoform
18.9
1.0
ug/L
20.00
95
71-135
Bromomethane
23.0
1.0
ug/L
20.00
115
41-168
Carbon disulfide
24.3
5.0
ug/L
20.00
122
59-135
Carbon Tetrachloride
20.4
0.50
ug/L
20.00
102
72-142
Chlorobenzene
20.5
0.50
ug/L
20.00
103
78-119
Chloroethane
25.3
0.50
ug/L
20.00
127
57-142
Chloroform
21.9
0.50
ug/L
20.00
110
77-130
Chloromethane
24.8
0.50
ug/L
20.00
124
47-145
cis-1,2-Dichloroethylene
22.5
0.50
ug/L
20.00
112
76-141
cis-1,3-Dichloropropylene
21.1
0.50
ug/L
20.00
106
65-140
Dibromochloromethane
20.8
0.50
ug/L
20.00
104
75-134
Dibromomethane
21.0
0.50
ug/L
20.00
105
76-138
Ethylbenzene
21.8
0.50
ug/L
20.00
109
80-127
m,p-Xylenes
45.5
1.0
ug/L
40.00
114
77-133
Methyl Butyl Ketone (2-Hexanone)
17.0
5.0
ug/L
20.00
85
64-137
Methyl Ethyl Ketone (2-Butanone)
19.3
5.0
ug/L
20.00
96
71-134
Methyl Iodide
20.0
5.0
ug/L
20.00
100
70-130
Methyl Isobutyl Ketone
18.6
5.0
ug/L
20.00
93
69-134
Methylene Chloride
23.2
1.0
ug/L
20.00
116
73-131
o-Xylene
21.4
0.50
ug/L
20.00
107
78-128
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 11 of 18

PR I S M Full -Service Analytical Environmental Solutions
LABCFATCRIES, NC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Prism Work Order: 9030262
Attn: Brian Gant Time Submitted: 3/15/2019 9:00:OOAM
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO287 - 5030B
LCS (P9CO287-BSI)
Prepared &Analyzed: 03/15/19
Styrene
20.5
0.50
ug/L
20.00
102
78-129
Tetrachloroethylene
21.8
0.50
ug/L
20.00
109
80-129
Tetrahydrofuran
21.7
10
ug/L
20.00
108
70-130
Toluene
22.6
0.50
ug/L
20.00
113
76-131
trans- 1,2-Dichloroethylene
23.0
0.50
ug/L
20.00
115
76-135
trans- 1,3-Dichloropropylene
20.9
0.50
ug/L
20.00
104
67-140
trans-1,4-Dichloro-2-butene
20.2
10
ug/L
20.00
101
70-130
Trichloroethylene
21.5
0.50
ug/L
20.00
108
77-133
Trichlorofluoromethane
21.6
0.50
ug/L
20.00
108
62-148
Vinyl acetate
19.6
2.0
ug/L
20.00
98
34-167
Vinyl chloride
23.3
0.50
ug/L
20.00
116
57-141
Xylenes, total
67.0
1.5
ug/L
60.00
112
77-133
Surrogate:4-Bromofluorobenzene
49.7
ug/L
50.00
99
80-124
Surrogate: Dibromofluoromethane
49.2
ug/L
50.00
98
75-129
Surrogate: Toluene-d8
49.7
ug/L
50.00
99
77-123
LCS Dup (P9CO287-BSD1)
Prepared &Analyzed: 03/15/19
1,1,1,2-Tetrachloroethane
20.8
0.50
ug/L
20.00
104
79-134
0.2
20
1,1,1-Trichloroethane
22.3
0.50
ug/L
20.00
112
75-136
3
20
1,1,2,2-Tetrachloroethane
19.9
0.50
ug/L
20.00
100
62-127
0.8
20
1,1,2-Trichloroethane
21.9
0.50
ug/L
20.00
109
70-140
5
20
1,1-Dichloroethane
22.6
0.50
ug/L
20.00
113
78-130
0.9
20
1,1-Dichloroethylene
22.1
0.50
ug/L
20.00
ill
70-154
2
20
1,2,3-Trichloropropane
21.0
1.0
ug/L
20.00
105
71-127
0.1
20
1,2-Dibromo-3-chloropropane
19.8
2.0
ug/L
20.00
99
63-134
2
20
1,2-Dibromoethane
19.7
0.50
ug/L
20.00
98
77-135
2
20
1,2-Dichlorobenzene
20.2
0.50
ug/L
20.00
101
78-128
0.6
20
1,2-Dichloroethane
22.2
0.50
ug/L
20.00
ill
68-131
2
20
1,2-Dichloropropane
21.4
0.50
ug/L
20.00
107
77-130
3
20
1,4-Dichlorobenzene
19.8
0.50
ug/L
20.00
99
75-126
3
20
Acetone
50.8
5.0
ug/L
40.00
127
40-166
9
20
Acrylonitrile
43.2
20
ug/L
40.00
108
81-127
8
20
Benzene
22.6
0.50
ug/L
20.00
113
77-128
1
20
Bromochloromethane
21.7
0.50
ug/L
20.00
108
78-135
0.2
20
Bromodichloromethane
21.9
0.50
ug/L
20.00
109
76-138
2
20
Bromoform
19.1
1.0
ug/L
20.00
95
71-135
0.9
20
Bromomethane
23.3
1.0
ug/L
20.00
117
41-168
1
20
Carbon disulfide
23.9
5.0
ug/L
20.00
119
59-135
2
20
Carbon Tetrachloride
20.3
0.50
ug/L
20.00
101
72-142
0.8
20
Chlorobenzene
20.2
0.50
ug/L
20.00
101
78-119
2
20
Chloroethane
25.2
0.50
ug/L
20.00
126
57-142
0.5
20
Chloroform
22.2
0.50
ug/L
20.00
ill
77-130
1
20
Chloromethane
25.0
0.50
ug/L
20.00
125
47-145
1
20
cis-1,2-Dichloroethylene
22.3
0.50
ug/L
20.00
ill
76-141
0.9
20
cis-1,3-Dichloropropylene
21.5
0.50
ug/L
20.00
107
65-140
2
20
Dibromochloromethane
20.4
0.50
ug/L
20.00
102
75-134
2
20
Dibromomethane
21.2
0.50
ug/L
20.00
106
76-138
0.9
20
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 12 of 18

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO287 - 5030B
LCS Dup (P9CO287-BSD1)
Prepared & Analyzed: 03/15/19
Ethylbenzene
21.4
0.50
ug/L
20.00
107
80-127
2
20
m,p-Xylenes
44.1
1.0
ug/L
40.00
110
77-133
3
20
Methyl Butyl Ketone (2-Hexanone)
18.2
5.0
ug/L
20.00
91
64-137
7
20
Methyl Ethyl Ketone (2-Butanone)
22.0
5.0
ug/L
20.00
110
71-134
13
20
Methyl Iodide
19.5
5.0
ug/L
20.00
98
70-130
3
20
Methyl Isobutyl Ketone
19.6
5.0
ug/L
20.00
98
69-134
5
20
Methylene Chloride
23.2
1.0
ug/L
20.00
116
73-131
0.2
20
o-Xylene
20.6
0.50
ug/L
20.00
103
78-128
4
20
Styrene
20.0
0.50
ug/L
20.00
100
78-129
2
20
Tetrachloroethylene
20.6
0.50
ug/L
20.00
103
80-129
6
20
Tetrahydrofuran
21.1
10
ug/L
20.00
105
70-130
3
20
Toluene
22.7
0.50
ug/L
20.00
114
76-131
0.4
20
trans-1,2-Dichloroethylene
23.0
0.50
ug/L
20.00
115
76-135
0.3
20
trans-1,3-Dichloropropylene
21.3
0.50
ug/L
20.00
107
67-140
2
20
trans-1,4-Dichloro-2-butene
20.2
10
ug/L
20.00
101
70-130
0
20
Trichloroethylene
21.0
0.50
ug/L
20.00
105
77-133
2
20
Trichlorofluoromethane
20.9
0.50
ug/L
20.00
104
62-148
3
20
Vinyl acetate
21.4
2.0
ug/L
20.00
107
34-167
9
20
Vinyl chloride
23.0
0.50
ug/L
20.00
115
57-141
1
20
Xylenes, total
64.7
1.5
ug/L
60.00
108
77-133
3
20
Surrogate:4-Bromofluorobenzene
50.0
ug/L
50.00
100
80-124
Surrogate: Dibromofluoromethane
52.2
ug/L
50.00
104
75-129
Surrogate: Toluene-d8
49.4
ug/L
50.00
99
77-123
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 13 of 18

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS SIM - Quality Control
Reporting
Analyte Result Limit Units
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
Batch P9CO434 - 5030B
Blank (P9C0434-BLK1) Prepared: 03/22/19 Analyzed: 03/25/19
1,4-Dioxane BRL 3.0 ug/L
LCS (P9C0434-BS1) Prepared: 03/22/19 Analyzed: 03/25/19
1,4-Dioxane 43.2 3.0 ug/L 50.00 86 55-145
LCS Dup (P9C0434-BSD1) Prepared: 03/22/19 Analyzed: 03/25/19
1,4-Dioxane 44.4 3.0 ug/L 50.00 89 55-145 3 30
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 14 of 18

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/2/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO297 - 3005A
Blank (P9CO297-BLK1)
Prepared: 03/18/19 Analyzed: 03/19/19
Arsenic
0.188
1.0
ug/L
J
Barium
0.991
5.0
ug/L
J
Cadmium
BRL
1.0
ug/L
Chromium
0.354
2.0
ug/L
J
Selenium
BRL
5.0
ug/L
Silver
BRL
5.0
ug/L
LCS (P9CO297-BSI)
Prepared: 03/18/19 Analyzed: 03/19/19
Arsenic
100
1.0
ug/L
100.0 100 80-120
Barium
93.1
5.0
ug/L
100.0 93 80-120
Cadmium
98.0
1.0
ug/L
100.0 98 80-120
Chromium
109
2.0
ug/L
100.0 109 80-120
Selenium
97.8
5.0
ug/L
100.0 98 80-120
Silver
98.8
5.0
ug/L
100.0 99 80-120
Batch P9C0329 - 7470A
Blank (P9C0329-BLK1)
Prepared & Analyzed: 03/19/19
Mercury
BRL 0.20 ug/L
LCS (P9C0329-BSI)
Prepared &Analyzed: 03/19/19
Mercury
8.70 0.20 ug/L 9.375 93 80-120
Batch P9C0395 - 3005A
Blank (P9C0395-BLK1)
Prepared &Analyzed: 03/21/19
Lead
BRL 1.0 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 15 of 18

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Project: Madison Closed Landfill
Level II QC Report
4/2/19
Prism Work Order: 9030262
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9C0395 - 3005A
LCS (P9C0395-BSI) Prepared &Analyzed: 03/21/19
Lead 106 1.0 ug/L 100.0 106 80-120
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]
Page 16 of 18

Level II QC Report
P R I IS M Full -Service Analytical 4/2/19
Environmental Solutions
. LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Prism Work Order: 9030262
Attn: Brian Gant Time Submitted: 3/15/2019 9:00:OOAM
231 Haywood Street
Asheville, NC 28801
General Chemistry Parameters - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO520 - NO PREP
Blank (P9C0520-BLK1)
Prepared &Analyzed: 03/27/19
Hardness
BRL
5000 ug/L
LCS (P9C0520-BS1)
Prepared &Analyzed: 03/27/19
Hardness
50000
5000 ug/L
50000 100 90-110
Sample Extraction
Data
Prep Method: 3005A
Lab Number
Batch
Initial
Final
Date/Time
9030262-01
P9C0395
50
mL
50 mL
03/21/19 7:45
9030262-01
P9CO297
50
mL
50 mL
03/18/19 8:00
9030262-02
P9C0395
50
mL
50 mL
03/21/19 7:45
9030262-02
P9CO297
50
mL
50 mL
03/18/19 8:00
Prep Method: 7470A
Lab Number
Batch
Initial
Final
Date/Time
9030262-01
P9C0329
20
mL
30 mL
03/19/19 8:50
9030262-02
P9C0329
20
mL
30 mL
03/19/19 8:50
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
9030262-01
P9CO287
10
mL
10 mL
03/15/19 14:37
9030262-02
P9CO287
10
mL
10 mL
03/15/19 14:37
9030262-03
P9CO287
10
mL
10 mL
03/15/19 14:37
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
9030262-01
P9C0434
5
mL
5 mL
03/22/19 10:43
9030262-02
P9C0434
5
mL
5 mL
03/22/19 10:43
9030262-03
P9C0434
5
mL
5 mL
03/22/19 10:43
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone] Page 17 of 18

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LP R I S M Full -Service Analytical &
Environmental Solutions
LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC
Brian Gant
231 Haywood Street
Asheville, NC 28801
NC Certification No. 402
NC Drinking Water Cert No. 37735
SC Certification No. 99012
Project: Madison Closed Landfill
Lab Submittal Date: 03/15/2019
Prism Work Order: 9030263
Case Narrative
4/4/19 13:36
This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample
Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed
according to the referenced methods.
Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case
narrative.
Narrative Notes:
This is a Revised Report and supercedes the original laboratory report dated 04/02/19. 8260 has been
reorted for MW-01 OLD.
Please call if you have any questions relating to this analytical report.
Respectfully,
PRISM LABORATORIES, INC.
Robbi A. Jones
President/Project Manager
Data Qualifiers Key Reference:
Reviewed By Angela D. Overcash For Robbi A. Jones
VP Laboratory Services
J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag).
BRL Below Reporting Limit
MDL Method Detection Limit
RPD Relative Percent Difference
* Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and
reporting limit indicated with a J.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Sample Receipt Summary
�P R I S M
Full -Service Analytical
s
Environmental Solutions
04/04/2019
LABORATORIES, INC.
Prism Work Order: 9030263
Client Sample ID
Lab Sample ID
Matrix
Date/Time Sampled Date/Time Received
MW-01OLD
9030263-01
Water
03/14/19 9:25 03/15/19 9:00
MW-02 OLD
9030263-02
Water
03/14/19 13:30 03/15/19 9:00
MW-03 OLD
9030263-03
Water
03/14/19 10:26 03/15/19 9:00
MW-04 OLD
9030263-04
Water
03/14/19 11:15 03/15/19 9:00
BIG Spring Old
9030263-05
Water
03/14/19 12:22 03/15/19 9:00
Trip Blank
9030263-06
Water
03/14/19 0:00 03/15/19 9:00
Samples were received in good condition at 3.4 degrees C unless otherwise noted.
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

/r P R I S M Full -Service Analytical s
Environmental Solutions
LABORATOR
Summary of Detections
04/04/201S
Prism Work Order: 9030263
Prism ID
Client ID
Parameter
Method
Result
Units
9030263-01
MW-01 OLD
Barium
'6020B
280
ug/L
9030263-01
MW-01 OLD
Chromium
`6020B
2.5
ug/L
9030263-01
MW-01 OLD
Lead
6020B
0.70
J
ug/L
9030263-01
MW-01 OLD
1,1-Dichloroethane
8260B
0.43
J
ug/L
9030263-01
MW-01 OLD
1,4-Dichlorobenzene
8260B
2.1
ug/L
9030263-01
MW-01 OLD
Benzene
8260B
0.70
ug/L
9030263-01
MW-01 OLD
Chlorobenzene
8260B
1.4
ug/L
9030263-01
MW-01 OLD
Chloroethane
8260B
1.1
ug/L
9030263-01
MW-01 OLD
cis-1,2-Dichloroethylene
8260B
1.6
ug/L
9030263-01
MW-01 OLD
Trichloroethylene
8260B
0.38
J
ug/L
9030263-01
MW-01 OLD
Vinyl chloride
8260B
2.8
ug/L
9030263-01
MW-01 OLD
1,4-Dioxane
8260B SIM
2.3
J
ug/L
9030263-02
MW-02 OLD
Barium
`602013
43
ug/L
9030263-02
MW-02 OLD
Lead
6020B
0.37
J
ug/L
9030263-02
MW-02 OLD
1,1-Dichloroethane
8260B
0.92
ug/L
9030263-03
MW-03 OLD
Barium
`602013
830
ug/L
9030263-03
MW-03 OLD
1,4-Dichlorobenzene
8260B
4.1
ug/L
9030263-03
MW-03 OLD
Benzene
8260B
2.1
ug/L
9030263-03
MW-03 OLD
Chlorobenzene
8260B
7.1
ug/L
9030263-03
MW-03 OLD
Chloroethane
8260B
1.2
ug/L
9030263-03
MW-03 OLD
Ethylbenzene
8260B
5.0
ug/L
9030263-03
MW-03 OLD
m,p-Xylenes
8260B
0.57
J
ug/L
9030263-03
MW-03 OLD
o-Xylene
8260B
0.54
ug/L
9030263-03
MW-03 OLD
Xylenes, total
8260B
1.1
J
ug/L
9030263-04
MW-04 OLD
Barium
'60208
760
ug/L
9030263-04
MW-04 OLD
Chromium
`6020B
2.0
ug/L
9030263-04
MW-04 OLD
Lead
6020B
0.82
J
ug/L
9030263-04
MW-04 OLD
Silver
6020B
0.063
J
ug/L
9030263-04
MW-04 OLD
1,4-Dichlorobenzene
8260B
2.4
ug/L
9030263-04
MW-04 OLD
Benzene
8260B
0.41
J
ug/L
9030263-04
MW-04 OLD
Chlorobenzene
8260B
4.7
ug/L
9030263-04
MW-04 OLD
Chloroethane
8260B
1.1
ug/L
9030263-04
MW-04 OLD
m,p-Xylenes
8260B
0.89
J
ug/L
9030263-04
MW-04 OLD
o-Xylene
8260B
0.33
J
ug/L
9030263-04
MW-04 OLD
Toluene
8260B
0.25
J
ug/L
9030263-04
MW-04 OLD
Xylenes, total
8260B
1.2
.1
ug/L
9030263-05
BG Spring Old
Barium
`6020B
120
ug/L
9030263-05
BG Spring Old
Chromium
`6020B
9.2
ug/L
9030263-05
BG Spring Old
Lead
6020B
2.2
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I S M Full -Service Analytical &
Laboratory Report
Environmental Solutions 04/04/2019
&
I LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-01 OLD
Attn: Brian Gant Prism Sample ID: 9030263-01
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 09:25
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:13 MMR
P9C0329
Arsenic
<0.031
ug/L
10
1.0
0.031
1
*6020B
3/19/19 18:51 JAB
P9CO297
Barium
280
ug/L
100
5.0
0.97
1
*6020B
3/19/19 18:51 JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
*6020B
3/19/19 18:51 JAB
P9CO297
Chromium
2.5
ug/L
10
2.0
0.19
1
*6020B
3/19/19 18:51 JAB
P9CO297
Lead
0.70 J
ug/L
10
1.0
0.093
1
6020B
3/21/19 19:35 JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 18:51 JAB
P9CO297
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19 18:51 JAB
P9CO297
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/20/19 23:21 KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 23:21 KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/20/19 23:21 KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 23:21 KDM
P9C0383
1,1-Dichloroethane
0.43 J
ug/L
5
0.50
0.083
1
8260B
3/20/19 23:21 KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 23:21 KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 23:21 KDM
P9C0383
1,4-Dichlorobenzene
2.1
ug/L
1
0.50
0.050
1
8260B
3/20/19 23:21 KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/20/19 23:21 KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/20/19 23:21 KDM
P9C0383
Benzene
0.70
ug/L
1
0.50
0.048
1
8260B
3/20/19 23:21 KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/20/19 23:21 KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/20/19 23:21 KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/20/19 23:21 KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/20/19 23:21 KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/20/19 23:21 KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 23:21 KDM
P9C0383
Chlorobenzene
1.4
ug/L
3
0.50
0.062
1
8260B
3/20/19 23:21 KDM
P9C0383
Chloroethane
1.1
ug/L
10
0.50
0.22
1
8260B
3/20/19 23:21 KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 23:21 KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 23:21 KDM
P9C0383
cis-1,2-Dichloroethylene
1.6
ug/L
5
0.50
0.056
1
8260B
3/20/19 23:21 KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R S M Laboratory Report
Full -Service Analytical &
Environmental Solutions 04/04/2019
LABORATORIES INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-01 OLD
Attn: Brian Gant Prism Sample ID: 9030263-01
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 09:25
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 23:21 KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/20/19 23:21 KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/20/19 23:21 KDM
P9C0383
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 23:21 KDM
P9C0383
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/20/19 23:21 KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/20/19 23:21 KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/20/19 23:21 KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/20/19 23:21 KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/20/19 23:21 KDM
P9C0383
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/20/19 23:21 KDM
P9C0383
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1
8260B
3/20/19 23:21 KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/20/19 23:21 KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/20/19 23:21 KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/20/19 23:21 KDM
P9C0383
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/20/19 23:21 KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/20/19 23:21 KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/20/19 23:21 KDM
P9C0383
trans- 1,4-Dich loro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/20/19 23:21 KDM
P9C0383
Trichloroethylene
0.38 J
ug/L
1
0.50
0.078
1
8260B
3/20/19 23:21 KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/20/19 23:21 KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/20/19 23:21 KDM
P9C0383
Vinyl chloride
2.8
ug/L
1
0.50
0.097
1
8260B
3/20/19 23:21 KDM
P9C0383
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1
8260B
3/20/19 23:21 KDM
P9C0383
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
103 % 80-124
Dibromofluoromethane
101 % 75-129
Toluene-d8
97 %
77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
2.3 J
ug/L
10
3.0
0.14
1
8260B SIM
3/27/19 18:40 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

�Full-Service Analytical
P R I S M
Environmental Solutions
LABORATORIES INC.
Laboratory Report
04/04/2019
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Project: Madison Closed Landfill
Sample Matrix: Water
Client Sample ID: MW-02 OLD
Prism Sample ID: 9030263-02
Prism Work Order: 9030263
Time Collected: 03/14/19 13:30
Time Submitted: 03/15/19 09:00
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:17 MMR
P9C0329
Arsenic
<0.031
ug/L
10
1.0
0.031
1
*6020B
3/19/19 18:57 JAB
P9CO297
Barium
43
ug/L
100
5.0
0.97
1
*6020B
3/19/19 18:57 JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
*6020B
3/19/19 18:57 JAB
P9CO297
Chromium
<0.19
ug/L
10
2.0
0.19
1
*6020B
3/19/19 18:57 JAB
P9CO297
Lead
0.37 J
ug/L
10
1.0
0.093
1
6020B
3/21/19 19:42 JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 18:57 JAB
P9CO297
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19 18:57 JAB
P9CO297
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/20/19 23:47 KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 23:47 KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/20/19 23:47 KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 23:47 KDM
P9C0383
1,1-Dichloroethane
0.92
ug/L
5
0.50
0.083
1
8260B
3/20/19 23:47 KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 23:47 KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 23:47 KDM
P9C0383
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/20/19 23:47 KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/20/19 23:47 KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/20/19 23:47 KDM
P9C0383
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/20/19 23:47 KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/20/19 23:47 KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/20/19 23:47 KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/20/19 23:47 KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/20/19 23:47 KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/20/19 23:47 KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 23:47 KDM
P9C0383
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/20/19 23:47 KDM
P9C0383
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/20/19 23:47 KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 23:47 KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 23:47 KDM
P9C0383
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/20/19 23:47 KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R S M Laboratory Report
Full -Service Analytical &
Environmental Solutions 04/04/2019
LABORATORIES INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-02 OLD
Attn: Brian Gant Prism Sample ID: 9030263-02
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 13:30
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 23:47 KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/20/19 23:47 KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/20/19 23:47 KDM
P9C0383
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 23:47 KDM
P9C0383
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/20/19 23:47 KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/20/19 23:47 KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/20/19 23:47 KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/20/19 23:47 KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/20/19 23:47 KDM
P9C0383
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/20/19 23:47 KDM
P9C0383
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1
8260B
3/20/19 23:47 KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/20/19 23:47 KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/20/19 23:47 KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/20/19 23:47 KDM
P9C0383
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/20/19 23:47 KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/20/19 23:47 KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/20/19 23:47 KDM
P9C0383
trans- 1,4-Dich loro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/20/19 23:47 KDM
P9C0383
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/20/19 23:47 KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/20/19 23:47 KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/20/19 23:47 KDM
P9C0383
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/20/19 23:47 KDM
P9C0383
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1
8260B
3/20/19 23:47 KDM
P9C0383
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
107 % 80-124
Dibromofluoromethane
109 % 75-129
Toluene-d8
96 %
77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/27/19 19:05 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
Full -Service
P R S M
Analytical &
Environmental
LABORATORIES INC.
Solutions
04/04/2019
Anchor QEA of North Carolina, PLLC
Project: Madison Closed Landfill
Client
Sample ID:
MW-03 OLD
Attn: Brian Gant
Prism
Sample ID:
9030263-03
231 Haywood Street
Prism Work Order: 9030263
Asheville, NC 28801
Sample Matrix: Water
Time Collected: 03/14/19 10:26
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:20 MMR
P9C0329
Arsenic
<0.031
ug/L
10
1.0
0.031
1
*6020B
3/19/19 18:38
JAB
P9CO297
Barium
830
ug/L
100
5.0
0.97
1
*6020B
3/19/19 18:38
JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
*6020B
3/19/19 18:38
JAB
P9CO297
Chromium
<0.19
ug/L
10
2.0
0.19
1
*6020B
3/19/19 18:38
JAB
P9CO297
Lead
<0.093
ug/L
10
1.0
0.093
1
6020B
3/21/19 19:48
JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 18:38
JAB
P9CO297
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19 18:38
JAB
P9CO297
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/21/19 0:12
KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/21/19 0:12
KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/21/19 0:12
KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 0:12
KDM
P9C0383
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 0:12
KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 0:12
KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 0:12
KDM
P9C0383
1,4-Dichlorobenzene
4.1
ug/L
1
0.50
0.050
1
8260B
3/21/19 0:12
KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/21/19 0:12
KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/21/19 0:12
KDM
P9C0383
Benzene
2.1
ug/L
1
0.50
0.048
1
8260B
3/21/19 0:12
KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/21/19 0:12
KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19 0:12
KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/21/19 0:12
KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/21/19 0:12
KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/21/19 0:12
KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 0:12
KDM
P9C0383
Chlorobenzene
7.1
ug/L
3
0.50
0.062
1
8260B
3/21/19 0:12
KDM
P9C0383
Chloroethane
1.2
ug/L
10
0.50
0.22
1
8260B
3/21/19 0:12
KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 0:12
KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19 0:12
KDM
P9C0383
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/21/19 0:12
KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R S M Laboratory Report
Full -Service Analytical &
Environmental Solutions 04/04/2019
LABORATORIES INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-03 OLD
Attn: Brian Gant Prism Sample ID: 9030263-03
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 10:26
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19
0:12
KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/21/19
0:12
KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/21/19
0:12
KDM
P9C0383
Ethylbenzene
5.0
ug/L
1
0.50
0.061
1
8260B
3/21/19
0:12
KDM
P9C0383
m,p-Xylenes
0.57 J
ug/L
NE
1.0
0.12
1
8260B
3/21/19
0:12
KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/21/19
0:12
KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/21/19
0:12
KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/21/19
0:12
KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/21/19
0:12
KDM
P9C0383
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/21/19
0:12
KDM
P9C0383
o-Xylene
0.54
ug/L
NE
0.50
0.044
1
8260B
3/21/19
0:12
KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/21/19
0:12
KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/21/19
0:12
KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/21/19
0:12
KDM
P9C0383
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/21/19
0:12
KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/21/19
0:12
KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/21/19
0:12
KDM
P9C0383
trans- 1,4-Dichloro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/21/19
0:12
KDM
P9C0383
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/21/19
0:12
KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19
0:12
KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/21/19
0:12
KDM
P9C0383
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/21/19
0:12
KDM
P9C0383
Xylenes, total
1.1 J
ug/L
5
1.5
0.15
1
8260B
3/21/19
0:12
KDM
P9C0383
Surrogate
Recovery
Control Limits
4-Bromofluorobenzene
105 %
80-124
Dibromofluoromethane
101 %
75-129
Toluene-d8
97 %
77-123
Volatile Organic Compounds by GUMS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/27/19
19:31 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
Full -Service
P R S M
Analytical &
Environmental
LABORATORIES INC.
Solutions
04/04/2019
Anchor QEA of North Carolina, PLLC
Project: Madison Closed Landfill
Client
Sample ID:
MW-04 OLD
Attn: Brian Gant
Prism
Sample ID:
9030263-04
231 Haywood Street
Prism Work Order: 9030263
Asheville, NC 28801
Sample Matrix: Water
Time Collected: 03/14/19 11:15
Time Submitted: 03/15/19 09:00
Parameter
Result Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/19/19 13:24 MMR
P9C0329
Arsenic
<0.031
ug/L
10
1.0
0.031
1
*6020B
3/19/19 18:44
JAB
P9CO297
Barium
760
ug/L
100
5.0
0.97
1
*6020B
3/19/19 18:44
JAB
P9CO297
Cadmium
<0.078
ug/L
1
1.0
0.078
1
*6020B
3/19/19 18:44
JAB
P9CO297
Chromium
2.0
ug/L
10
2.0
0.19
1
*6020B
3/19/19 18:44
JAB
P9CO297
Lead
0.82
J ug/L
10
1.0
0.093
1
6020B
3/21/19 19:55
JAB
P9C0395
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 18:44
JAB
P9CO297
Silver
0.063
J ug/L
10
5.0
0.063
1
6020B
3/19/19 18:44
JAB
P9CO297
Volatile Organic Compounds by GUMS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/21/19 0:38
KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/21/19 0:38
KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/21/19 0:38
KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 0:38
KDM
P9C0383
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 0:38
KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 0:38
KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 0:38
KDM
P9C0383
1,4-Dichlorobenzene
2.4
ug/L
1
0.50
0.050
1
8260B
3/21/19 0:38
KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/21/19 0:38
KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/21/19 0:38
KDM
P9C0383
Benzene
0.41
J ug/L
1
0.50
0.048
1
8260B
3/21/19 0:38
KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/21/19 0:38
KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19 0:38
KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/21/19 0:38
KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/21/19 0:38
KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/21/19 0:38
KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 0:38
KDM
P9C0383
Chlorobenzene
4.7
ug/L
3
0.50
0.062
1
8260B
3/21/19 0:38
KDM
P9C0383
Chloroethane
1.1
ug/L
10
0.50
0.22
1
8260B
3/21/19 0:38
KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 0:38
KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19 0:38
KDM
P9C0383
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/21/19 0:38
KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R S M Laboratory Report
Full -Service Analytical &
Environmental Solutions 04/04/2019
LABORATORIES INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: MW-04 OLD
Attn: Brian Gant Prism Sample ID: 9030263-04
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 11:15
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19
0:38
KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/21/19
0:38
KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/21/19
0:38
KDM
P9C0383
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/21/19
0:38
KDM
P9C0383
m,p-Xylenes
0.89
J ug/L
NE
1.0
0.12
1
8260B
3/21/19
0:38
KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/21/19
0:38
KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/21/19
0:38
KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/21/19
0:38
KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/21/19
0:38
KDM
P9C0383
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/21/19
0:38
KDM
P9C0383
o-Xylene
0.33
J ug/L
NE
0.50
0.044
1
8260B
3/21/19
0:38
KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/21/19
0:38
KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/21/19
0:38
KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/21/19
0:38
KDM
P9C0383
Toluene
0.25
J ug/L
1
0.50
0.044
1
8260B
3/21/19
0:38
KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/21/19
0:38
KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/21/19
0:38
KDM
P9C0383
trans- 1,4-Dich loro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/21/19
0:38
KDM
P9C0383
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/21/19
0:38
KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19
0:38
KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/21/19
0:38
KDM
P9C0383
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/21/19
0:38
KDM
P9C0383
Xylenes, total
1.2
J ug/L
5
1.5
0.15
1
8260B
3/21/19
0:38
KDM
P9C0383
Surrogate
Recovery
Control Limits
4-Bromofluorobenzene
103 %
80-124
Dibromofluoromethane
102 %
75-129
Toluene-d8
96 %
77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/27/19 19:56 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
Full -Service
P R S M
Analytical &
Environmental
LABORATORIES INC.
Solutions
04/04/2019
Anchor QEA of North Carolina, PLLC
Project: Madison Closed Landfill
Client
Sample ID:
BG Spring Old
Attn: Brian Gant
Prism
Sample ID:
9030263-05
231 Haywood Street
Prism Work Order: 9030263
Asheville, NC 28801
Sample Matrix: Water
Time Collected: 03/14/19 12:22
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis Analyst
Batch
Limit
Factor
Date/Time
ID
Total Metals
Mercury
<0.036
ug/L
0.2
0.20
0.036
1
7470A
3/26/19 12:21 MMR
P9C0474
Arsenic
<0.031
ug/L
10
1.0
0.031
1
*6020B
3/19/19 19:29 JAB
P9C0330
Barium
120
ug/L
100
5.0
0.97
1
*6020B
3/19/19 19:29 JAB
P9C0330
Cadmium
<0.078
ug/L
1
1.0
0.078
1
*6020B
3/19/19 19:29 JAB
P9C0330
Chromium
9.2
ug/L
10
2.0
0.19
1
*6020B
3/19/19 19:29 JAB
P9C0330
Lead
2.2
ug/L
10
1.0
0.093
1
6020B
3/19/19 19:29 JAB
P9C0330
Selenium
<0.63
ug/L
10
5.0
0.63
1
6020B
3/19/19 19:29 JAB
P9C0330
Silver
<0.063
ug/L
10
5.0
0.063
1
6020B
3/19/19 19:29 JAB
P9C0330
Volatile Organic Compounds by GC/MS
1, 1, 1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/21/19 1:04 KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/21/19 1:04 KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/21/19 1:04 KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 1:04 KDM
P9C0383
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 1:04 KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/21/19 1:04 KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 1:04 KDM
P9C0383
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/21/19 1:04 KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/21/19 1:04 KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/21/19 1:04 KDM
P9C0383
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/21/19 1:04 KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/21/19 1:04 KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19 1:04 KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/21/19 1:04 KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/21/19 1:04 KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/21/19 1:04 KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/21/19 1:04 KDM
P9C0383
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/21/19 1:04 KDM
P9C0383
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/21/19 1:04 KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/21/19 1:04 KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19 1:04 KDM
P9C0383
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/21/19 1:04 KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R S M Laboratory Report
Full -Service Analytical &
Environmental Solutions 04/04/2019
LABORATORIES INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Client Sample ID: BG Spring Old
Attn: Brian Gant Prism Sample ID: 9030263-05
231 Haywood Street Prism Work Order: 9030263
Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/14/19 12:22
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution
Method
Analysis
Analyst
Batch
Limit
Factor
Date/Time
ID
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/21/19
1:04
KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/21/19
1:04
KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/21/19
1:04
KDM
P9C0383
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/21/19
1:04
KDM
P9C0383
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/21/19
1:04
KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/21/19
1:04
KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/21/19
1:04
KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/21/19
1:04
KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/21/19
1:04
KDM
P9C0383
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1
8260B
3/21/19
1:04
KDM
P9C0383
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1
8260B
3/21/19
1:04
KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1
8260B
3/21/19
1:04
KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1
8260B
3/21/19
1:04
KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1
8260B
3/21/19
1:04
KDM
P9C0383
Toluene
<0.044
ug/L
1
0.50
0.044
1
8260B
3/21/19
1:04
KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1
8260B
3/21/19
1:04
KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1
8260B
3/21/19
1:04
KDM
P9C0383
trans- 1,4-Dich loro-2-butene
<0.12
ug/L
100
10
0.12
1
8260B
3/21/19
1:04
KDM
P9C0383
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1
8260B
3/21/19
1:04
KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/21/19
1:04
KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1
8260B
3/21/19
1:04
KDM
P9C0383
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1
8260B
3/21/19
1:04
KDM
P9C0383
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1
8260B
3/21/19
1:04
KDM
P9C0383
Surrogate
Recovery
Control Limits
4-Bromofluorobenzene
103 %
80-124
Dibromofluoromethane
100 %
75-129
Toluene-d8
96 %
77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1
8260B SIM
3/27/19 20:21 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

�Full-Service Analytical s
P R I S M
Environmental Solutions
LABORATORIES INC.
Laboratory Report
04/04/2019
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Project: Madison Closed Landfill
Sample Matrix: Water
Client Sample ID: Trip Blank
Prism Sample ID: 9030263-06
Prism Work Order: 9030263
Time Collected: 03/14/19 00:00
Time Submitted: 03/15/19 09:00
Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch
Limit Factor Date/Time ID
Volatile Organic Compounds by GC/MS
1,1,1,2-Tetrachloroethane
<0.11
ug/L
5
0.50
0.11
1
8260B
3/20/19 19:29 KDM
P9C0383
1, 1, 1 -Trichloroethane
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 19:29 KDM
P9C0383
1,1,2,2-Tetrachloroethane
<0.036
ug/L
3
0.50
0.036
1
8260B
3/20/19 19:29 KDM
P9C0383
1,1,2-Trichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 19:29 KDM
P9C0383
1,1-Dichloroethane
<0.083
ug/L
5
0.50
0.083
1
8260B
3/20/19 19:29 KDM
P9C0383
1,1-Dichloroethylene
<0.083
ug/L
5
0.50
0.083
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2,3-Trichloropropane
<0.14
ug/L
1
1.0
0.14
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2-Dibromo-3-chloropropane
<0.17
ug/L
13
2.0
0.17
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2-Dibromoethane
<0.051
ug/L
1
0.50
0.051
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2-Dichlorobenzene
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2-Dichloroethane
<0.066
ug/L
1
0.50
0.066
1
8260B
3/20/19 19:29 KDM
P9C0383
1,2-Dichloropropane
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 19:29 KDM
P9C0383
1,4-Dichlorobenzene
<0.050
ug/L
1
0.50
0.050
1
8260B
3/20/19 19:29 KDM
P9C0383
Acetone
<0.31
ug/L
100
5.0
0.31
1
8260B
3/20/19 19:29 KDM
P9C0383
Acrylonitrile
<0.20
ug/L
200
20
0.20
1
8260B
3/20/19 19:29 KDM
P9C0383
Benzene
<0.048
ug/L
1
0.50
0.048
1
8260B
3/20/19 19:29 KDM
P9C0383
Bromochloromethane
<0.14
ug/L
3
0.50
0.14
1
8260B
3/20/19 19:29 KDM
P9C0383
Bromodichloromethane
<0.062
ug/L
1
0.50
0.062
1
8260B
3/20/19 19:29 KDM
P9C0383
Bromoform
<0.040
ug/L
3
1.0
0.040
1
8260B
3/20/19 19:29 KDM
P9C0383
Bromomethane
<0.18
ug/L
10
1.0
0.18
1
8260B
3/20/19 19:29 KDM
P9C0383
Carbon disulfide
<0.075
ug/L
100
5.0
0.075
1
8260B
3/20/19 19:29 KDM
P9C0383
Carbon Tetrachloride
<0.11
ug/L
1
0.50
0.11
1
8260B
3/20/19 19:29 KDM
P9C0383
Chlorobenzene
<0.062
ug/L
3
0.50
0.062
1
8260B
3/20/19 19:29 KDM
P9C0383
Chloroethane
<0.22
ug/L
10
0.50
0.22
1
8260B
3/20/19 19:29 KDM
P9C0383
Chloroform
<0.076
ug/L
5
0.50
0.076
1
8260B
3/20/19 19:29 KDM
P9C0383
Chloromethane
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 19:29 KDM
P9C0383
cis- 1,2-Dichloroethylene
<0.056
ug/L
5
0.50
0.056
1
8260B
3/20/19 19:29 KDM
P9C0383
cis- 1,3-Dichloropropylene
<0.079
ug/L
1
0.50
0.079
1
8260B
3/20/19 19:29 KDM
P9C0383
Dibromochloromethane
<0.081
ug/L
3
0.50
0.081
1
8260B
3/20/19 19:29 KDM
P9C0383
Dibromomethane
<0.065
ug/L
10
0.50
0.065
1
8260B
3/20/19 19:29 KDM
P9C0383
Ethylbenzene
<0.061
ug/L
1
0.50
0.061
1
8260B
3/20/19 19:29 KDM
P9C0383
m,p-Xylenes
<0.12
ug/L
NE
1.0
0.12
1
8260B
3/20/19 19:29 KDM
P9C0383
Methyl Butyl Ketone (2-Hexanone)
<0.065
ug/L
50
5.0
0.065
1
8260B
3/20/19 19:29 KDM
P9C0383
Methyl Ethyl Ketone (2-Butanone)
<0.24
ug/L
100
5.0
0.24
1
8260B
3/20/19 19:29 KDM
P9C0383
Methyl Iodide
<0.33
ug/L
10
5.0
0.33
1
8260B
3/20/19 19:29 KDM
P9C0383
Methyl Isobutyl Ketone
<0.078
ug/L
100
5.0
0.078
1
8260B
3/20/19 19:29 KDM
P9C0383
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Laboratory Report
P R S M
Full -Service Analytical &
LABORATORIES INC.
Environmental Solutions
04/04/2019
Anchor QEA of North Carolina,
PLLC
Project: Madison Closed
Landfill
Client Sample ID: Trip Blank
Attn: Brian Gant
Prism Sample ID: 9030263-06
231 Haywood Street
Prism Work Order: 9030263
Asheville, NC 28801
Sample Matrix: Water
Time Collected: 03/14/19 00:00
Time Submitted: 03/15/19 09:00
Parameter
Result
Units
SWSL
Report
MDL
Dilution Method Analysis Analyst
Batch
Limit
Factor Date/Time
ID
Methylene Chloride
<0.083
ug/L
1
1.0
0.083
1 8260B 3/20/19 19:29 KDM
P9C0383
o-Xylene
<0.044
ug/L
NE
0.50
0.044
1 8260B 3/20/19 19:29 KDM
P9C0383
Styrene
<0.047
ug/L
1
0.50
0.047
1 8260B 3/20/19 19:29 KDM
P9C0383
Tetrachloroethylene
<0.098
ug/L
1
0.50
0.098
1 8260B 3/20/19 19:29 KDM
P9C0383
Tetrahydrofuran
<0.16
ug/L
NE
10
0.16
1 8260B 3/20/19 19:29 KDM
P9C0383
Toluene
<0.044
ug/L
1
0.50
0.044
1 8260B 3/20/19 19:29 KDM
P9C0383
trans- 1,2-Dichloroethylene
<0.094
ug/L
5
0.50
0.094
1 8260B 3/20/19 19:29 KDM
P9C0383
trans- 1,3-Dichloropropylene
<0.070
ug/L
1
0.50
0.070
1 8260B 3/20/19 19:29 KDM
P9C0383
trans- 1,4-Dichloro-2-butene
<0.12
ug/L
100
10
0.12
1 8260B 3/20/19 19:29 KDM
P9C0383
Trichloroethylene
<0.078
ug/L
1
0.50
0.078
1 8260B 3/20/19 19:29 KDM
P9C0383
Trichlorofluoromethane
<0.062
ug/L
1
0.50
0.062
1 8260B 3/20/19 19:29 KDM
P9C0383
Vinyl acetate
<0.060
ug/L
50
2.0
0.060
1 8260B 3/20/19 19:29 KDM
P9C0383
Vinyl chloride
<0.097
ug/L
1
0.50
0.097
1 8260B 3/20/19 19:29 KDM
P9C0383
Xylenes, total
<0.15
ug/L
5
1.5
0.15
1 8260B 3/20/19 19:29 KDM
P9C0383
Surrogate
Recovery Control Limits
4-Bromofluorobenzene
100 % 80-124
Dibromofluoromethane
102 % 75-129
Toluene-d8
98 % 77-123
Volatile Organic Compounds by GC/MS SIM
1,4-Dioxane
<0.14
ug/L
10
3.0
0.14
1 8260B SIM 3/27/19 18:15 JLB
P9C0537
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Full -Service Analytical &
14LANKO�TORIES�
S M Environmental Solutions
INC.
Level II QC Report
4/4/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9C0383 - 5030B
Blank (P9C0383-BLK1)
Prepared & Analyzed: 03/20/19
1,1,1,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,1-Trichloroethane
BRL
0.50
ug/L
1,1,2,2-Tetrachloroethane
BRL
0.50
ug/L
1,1,2-Trichloroethane
BRL
0.50
ug/L
1,1-Dichloroethane
BRL
0.50
ug/L
1,1-Dichloroethylene
BRL
0.50
ug/L
1,2,3-Trichloropropane
BRL
1.0
ug/L
1,2-Dibromo-3-chloropropane
BRL
2.0
ug/L
1,2-Dibromoethane
BRL
0.50
ug/L
1,2-Dichlorobenzene
BRL
0.50
ug/L
1,2-Dichloroethane
BRL
0.50
ug/L
1,2-Dichloropropane
BRL
0.50
ug/L
1,4-Dichlorobenzene
BRL
0.50
ug/L
Acetone
BRL
5.0
ug/L
Acrylonitrile
BRL
20
ug/L
Benzene
BRL
0.50
ug/L
Bromochloromethane
BRL
0.50
ug/L
Bromodichloromethane
BRL
0.50
ug/L
Bromoform
BRL
1.0
ug/L
Bromomethane
BRL
1.0
ug/L
Carbon disulfide
BRL
5.0
ug/L
Carbon Tetrachloride
BRL
0.50
ug/L
Chlorobenzene
BRL
0.50
ug/L
Chloroethane
BRL
0.50
ug/L
Chloroform
BRL
0.50
ug/L
Chloromethane
BRL
0.50
ug/L
cis-1,2-Dichloroethylene
BRL
0.50
ug/L
cis-1,3-Dichloropropylene
BRL
0.50
ug/L
Dibromochloromethane
BRL
0.50
ug/L
Dibromomethane
BRL
0.50
ug/L
Ethylbenzene
BRL
0.50
ug/L
m,p-Xylenes
BRL
1.0
ug/L
Methyl Butyl Ketone (2-Hexanone)
BRL
5.0
ug/L
Methyl Ethyl Ketone (2-Butanone)
BRL
5.0
ug/L
Methyl Iodide
BRL
5.0
ug/L
Methyl Isobutyl Ketone
BRL
5.0
ug/L
Methylene Chloride
BRL
1.0
ug/L
o-Xylene
BRL
0.50
ug/L
Styrene
BRL
0.50
ug/L
Tetrachloroethylene
BRL
0.50
ug/L
Tetrahydrofuran
BRL
10
ug/L
Toluene
BRL
0.50
ug/L
trans- 1,2-Dichloroethylene
BRL
0.50
ug/L
trans- 1,3-Dichloropropylene
BRL
0.50
ug/L
trans-1,4-Dichloro-2-butene
BRL
10
ug/L
Trichloroethylene
BRL
0.50
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Level II QC Report
P R I S M Full -Service Analytical 4/4/19
Environmental Solutions
LABOFATORIEs NC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Prism Work Order: 9030263
Attn: Brian Gant Time Submitted: 3/15/2019 9:00:OOAM
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO383 - 5030B
Blank (P9C0383-BLK1)
Prepared & Analyzed: 03/20/19
Trichlorofluoromethane
BRL
0.50
ug/L
Vinyl acetate
BRL
2.0
ug/L
Vinyl chloride
BRL
0.50
ug/L
Xylenes, total
BRL
1.5
ug/L
Surrogate:4-Bromofluorobenzene
51.1
ug/L
50.00
102
80-124
Surrogate: Dibromofluoromethane
51.2
ug/L
50.00
102
75-129
Surrogate: Toluene-d8
48.0
ug/L
50.00
96
77-123
LCS (P9C0383-BSI)
Prepared & Analyzed: 03/20/19
1,1,1,2-Tetrachloroethane
21.7
0.50
ug/L
20.00
109
79-134
1,1,1-Trichloroethane
22.7
0.50
ug/L
20.00
113
75-136
1,1,2,2-Tetrachloroethane
21.6
0.50
ug/L
20.00
108
62-127
1,1,2-Trichloroethane
22.4
0.50
ug/L
20.00
112
70-140
1,1-Dichloroethane
21.9
0.50
ug/L
20.00
109
78-130
1,1-Dichloroethylene
22.2
0.50
ug/L
20.00
111
70-154
1,2,3-Trichloropropane
21.8
1.0
ug/L
20.00
109
71-127
1,2-Dibromo-3-chloropropane
19.4
2.0
ug/L
20.00
97
63-134
1,2-Dibromoethane
21.0
0.50
ug/L
20.00
105
77-135
1,2-Dichlorobenzene
20.6
0.50
ug/L
20.00
103
78-128
1,2-Dichloroethane
22.0
0.50
ug/L
20.00
110
68-131
1,2-Dichloropropane
21.7
0.50
ug/L
20.00
108
77-130
1,4-Dichlorobenzene
20.7
0.50
ug/L
20.00
104
75-126
Acetone
48.0
5.0
ug/L
40.00
120
40-166
Acrylonitrile
38.8
20
ug/L
40.00
97
81-127
Benzene
21.6
0.50
ug/L
20.00
108
77-128
Bromochloromethane
21.7
0.50
ug/L
20.00
108
78-135
Bromodichloromethane
21.9
0.50
ug/L
20.00
110
76-138
Bromoform
19.8
1.0
ug/L
20.00
99
71-135
Bromomethane
22.5
1.0
ug/L
20.00
112
41-168
Carbon disulfide
21.8
5.0
ug/L
20.00
109
59-135
Carbon Tetrachloride
20.7
0.50
ug/L
20.00
103
72-142
Chlorobenzene
20.4
0.50
ug/L
20.00
102
78-119
Chloroethane
24.1
0.50
ug/L
20.00
120
57-142
Chloroform
22.2
0.50
ug/L
20.00
111
77-130
Chloromethane
20.2
0.50
ug/L
20.00
101
47-145
cis-1,2-Dichloroethylene
22.0
0.50
ug/L
20.00
110
76-141
cis-1,3-Dichloropropylene
22.1
0.50
ug/L
20.00
111
65-140
Dibromochloromethane
20.4
0.50
ug/L
20.00
102
75-134
Dibromomethane
22.3
0.50
ug/L
20.00
111
76-138
Ethylbenzene
21.7
0.50
ug/L
20.00
108
80-127
m,p-Xylenes
43.4
1.0
ug/L
40.00
108
77-133
Methyl Butyl Ketone (2-Hexanone)
18.2
5.0
ug/L
20.00
91
64-137
Methyl Ethyl Ketone (2-Butanone)
23.1
5.0
ug/L
20.00
116
71-134
Methyl Iodide
18.5
5.0
ug/L
20.00
93
70-130
Methyl Isobutyl Ketone
21.1
5.0
ug/L
20.00
106
69-134
Methylene Chloride
21.1
1.0
ug/L
20.00
106
73-131
o-Xylene
21.3
0.50
ug/L
20.00
106
78-128
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Level II QC Report
P R I S M Full -Service Analytical 4/4/19
Environmental Solutions
LABOFATORIEs NC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill Prism Work Order: 9030263
Attn: Brian Gant Time Submitted: 3/15/2019 9:00:OOAM
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO383 - 5030B
LCS (P9C0383-BSI)
Prepared & Analyzed: 03/20/19
Styrene
20.6
0.50
ug/L
20.00
103
78-129
Tetrachloroethylene
21.5
0.50
ug/L
20.00
107
80-129
Tetrahydrofuran
20.5
10
ug/L
20.00
102
70-130
Toluene
22.2
0.50
ug/L
20.00
111
76-131
trans- 1,2-Dichloroethylene
21.5
0.50
ug/L
20.00
107
76-135
trans- 1,3-Dichloropropylene
22.4
0.50
ug/L
20.00
112
67-140
trans-1,4-Dichloro-2-butene
16.6
10
ug/L
20.00
83
70-130
Trichloroethylene
21.7
0.50
ug/L
20.00
108
77-133
Trichlorofluoromethane
22.9
0.50
ug/L
20.00
114
62-148
Vinyl acetate
21.8
2.0
ug/L
20.00
109
34-167
Vinyl chloride
17.9
0.50
ug/L
20.00
90
57-141
Xylenes, total
64.7
1.5
ug/L
60.00
108
77-133
Surrogate:4-Bromofluorobenzene
51.0
ug/L
50.00
102
80-124
Surrogate: Dibromofluoromethane
52.3
ug/L
50.00
105
75-129
Surrogate: Toluene-d8
49.1
ug/L
50.00
98
77-123
LCS Dup (P9C0383-BSD1)
Prepared & Analyzed: 03/20/19
1,1,1,2-Tetrachloroethane
21.5
0.50
ug/L
20.00
107
79-134
1
20
1,1,1-Trichloroethane
22.1
0.50
ug/L
20.00
111
75-136
2
20
1,1,2,2-Tetrachloroethane
21.6
0.50
ug/L
20.00
108
62-127
0.05
20
1,1,2-Trichloroethane
22.2
0.50
ug/L
20.00
ill
70-140
1
20
1,1-Dichloroethane
21.0
0.50
ug/L
20.00
105
78-130
4
20
1,1-Dichloroethylene
21.2
0.50
ug/L
20.00
106
70-154
5
20
1,2,3-Trichloropropane
22.3
1.0
ug/L
20.00
112
71-127
2
20
1,2-Dibromo-3-chloropropane
18.7
2.0
ug/L
20.00
94
63-134
3
20
1,2-Dibromoethane
20.9
0.50
ug/L
20.00
105
77-135
0.3
20
1,2-Dichlorobenzene
20.4
0.50
ug/L
20.00
102
78-128
1
20
1,2-Dichloroethane
21.4
0.50
ug/L
20.00
107
68-131
3
20
1,2-Dichloropropane
21.0
0.50
ug/L
20.00
105
77-130
3
20
1,4-Dichlorobenzene
19.8
0.50
ug/L
20.00
99
75-126
4
20
Acetone
46.6
5.0
ug/L
40.00
116
40-166
3
20
Acrylonitrile
39.3
20
ug/L
40.00
98
81-127
1
20
Benzene
20.8
0.50
ug/L
20.00
104
77-128
4
20
Bromochloromethane
21.4
0.50
ug/L
20.00
107
78-135
1
20
Bromodichloromethane
21.3
0.50
ug/L
20.00
106
76-138
3
20
Bromoform
19.8
1.0
ug/L
20.00
99
71-135
0.5
20
Bromomethane
22.0
1.0
ug/L
20.00
110
41-168
2
20
Carbon disulfide
20.7
5.0
ug/L
20.00
104
59-135
5
20
Carbon Tetrachloride
20.2
0.50
ug/L
20.00
101
72-142
3
20
Chlorobenzene
19.8
0.50
ug/L
20.00
99
78-119
3
20
Chloroethane
22.6
0.50
ug/L
20.00
113
57-142
6
20
Chloroform
21.0
0.50
ug/L
20.00
105
77-130
6
20
Chloromethane
19.4
0.50
ug/L
20.00
97
47-145
4
20
cis-1,2-Dichloroethylene
20.7
0.50
ug/L
20.00
104
76-141
6
20
cis-1,3-Dichloropropylene
21.8
0.50
ug/L
20.00
109
65-140
1
20
Dibromochloromethane
20.2
0.50
ug/L
20.00
101
75-134
0.8
20
Dibromomethane
21.8
0.50
ug/L
20.00
109
76-138
2
20
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS - Quality Control
Level II QC Report
4/4/19
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO383 - 5030B
LCS Dup (P9C0383-BSD1)
Prepared & Analyzed: 03/20/19
Ethylbenzene
21.0
0.50
ug/L
20.00
105
80-127
3
20
m,p-Xylenes
42.0
1.0
ug/L
40.00
105
77-133
3
20
Methyl Butyl Ketone (2-Hexanone)
18.0
5.0
ug/L
20.00
90
64-137
0.8
20
Methyl Ethyl Ketone (2-Butanone)
22.1
5.0
ug/L
20.00
ill
71-134
4
20
Methyl Iodide
18.4
5.0
ug/L
20.00
92
70-130
0.6
20
Methyl Isobutyl Ketone
21.3
5.0
ug/L
20.00
106
69-134
0.8
20
Methylene Chloride
20.3
1.0
ug/L
20.00
102
73-131
4
20
o-Xylene
20.6
0.50
ug/L
20.00
103
78-128
3
20
Styrene
19.9
0.50
ug/L
20.00
99
78-129
4
20
Tetrachloroethylene
20.8
0.50
ug/L
20.00
104
80-129
3
20
Tetrahydrofuran
19.7
10
ug/L
20.00
98
70-130
4
20
Toluene
21.4
0.50
ug/L
20.00
107
76-131
3
20
trans-1,2-Dichloroethylene
20.6
0.50
ug/L
20.00
103
76-135
4
20
trans-1,3-Dichloropropylene
21.8
0.50
ug/L
20.00
109
67-140
3
20
trans-1,4-Dichloro-2-butene
16.8
10
ug/L
20.00
84
70-130
1
20
Trichloroethylene
20.5
0.50
ug/L
20.00
103
77-133
5
20
Trichlorofluoromethane
21.5
0.50
ug/L
20.00
107
62-148
6
20
Vinyl acetate
21.4
2.0
ug/L
20.00
107
34-167
2
20
Vinyl chloride
17.1
0.50
ug/L
20.00
85
57-141
5
20
Xylenes, total
62.7
1.5
ug/L
60.00
104
77-133
3
20
Surrogate:4-Bromofluorobenzene
50.8
ug/L
50.00
102
80-124
Surrogate: Dibromofluoromethane
50.4
ug/L
50.00
101
75-129
Surrogate: Toluene-d8
49.0
ug/L
50.00
98
77-123
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/4/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Volatile Organic Compounds by GC/MS SIM - Quality Control
Reporting
Analyte Result Limit Units
Batch P9CO537 - 5030B
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Spike Source %REC RPD
Level Result %REC Limits RPD Limit Notes
Blank (P9C0537-BLK1)
Prepared & Analyzed: 03/27/19
1,4-Dioxane
BRL 3.0 ug/L
LCS (P9C0537-BS1)
Prepared & Analyzed: 03/27/19
1,4-Dioxane
44.2 3.0 ug/L
50.00 88 55-145
LCS Dup (P9CO537-BSD1)
Prepared & Analyzed: 03/27/19
1,4-Dioxane
45.2 3.0 ug/L
50.00 90 55-145 2 30
Matrix Spike (P9C0537-MS1)
Source: 9030263-06
Prepared & Analyzed: 03/27/19
1,4-Dioxane
46.2 3.0 ug/L
50.00 BRL 92 55-145
Matrix Spike Dup (P9C0537-MSD1)
Source: 9030263-06
Prepared & Analyzed: 03/27/19
1,4-Dioxane
49.9 3.0 ug/L
50.00 BRL 100 55-145 8 30
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/4/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9CO297 - 3005A
Blank (P9CO297-BLK1)
Prepared: 03/18/19 Analyzed: 03/19/19
Arsenic
BRL
1.0
ug/L
Barium
BRL
5.0
ug/L
Cadmium
BRL
1.0
ug/L
Chromium
BRL
2.0
ug/L
Selenium
BRL
5.0
ug/L
Silver
BRL
5.0
ug/L
LCS (P9CO297-BSI)
Prepared: 03/18/19 Analyzed: 03/19/19
Arsenic
100
1.0
ug/L
100.0 100 80-120
Barium
93.1
5.0
ug/L
100.0 93 80-120
Cadmium
98.0
1.0
ug/L
100.0 98 80-120
Chromium
109
2.0
ug/L
100.0 109 80-120
Selenium
97.8
5.0
ug/L
100.0 98 80-120
Silver
98.8
5.0
ug/L
100.0 99 80-120
Batch P9C0329 - 7470A
Blank (P9C0329-BLK1)
Prepared & Analyzed: 03/19/19
Mercury
BRL
0.20
ug/L
LCS (P9C0329-BSI)
Prepared & Analyzed: 03/19/19
Mercury
8.70
0.20
ug/L
9.375 93 80-120
Batch P9C0330 - 3005A
Blank (P9C0330-BLK1)
Prepared & Analyzed: 03/19/19
Arsenic
BRL
1.0
ug/L
Barium
BRL
5.0
ug/L
Cadmium
BRL
1.0
ug/L
Chromium
BRL
2.0
ug/L
Lead
BRL
1.0
ug/L
Selenium
BRL
5.0
ug/L
Silver
BRL
5.0
ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Level II QC Report
4/4/19
Anchor QEA of North Carolina, PLLC Project: Madison Closed Landfill
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes
Batch P9C0330 - 3005A
LCS (P9C0330-BSI)
Prepared & Analyzed: 03/19/19
Arsenic
99.2
1.0
ug/L
100.0 99
80-120
Barium
91.0
5.0
ug/L
100.0 91
80-120
Cadmium
95.0
1.0
ug/L
100.0 95
80-120
Chromium
103
2.0
ug/L
100.0 103
80-120
Lead
98.5
1.0
ug/L
100.0 99
80-120
Selenium
94.9
5.0
ug/L
100.0 95
80-120
Silver
95.9
5.0
ug/L
100.0 96
80-120
Matrix Spike (P9C0330-MS1)
Source: 9030263-05
Prepared & Analyzed: 03/19/19
Arsenic
99.3
1.0
ug/L
100.0 0.811 99
75-125
Barium
213
5.0
ug/L
100.0 123 90
75-125
Cadmium
98.8
1.0
ug/L
100.0 0.0830 99
75-125
Chromium
118
2.0
ug/L
100.0 9.23 109
75-125
Lead
106
1.0
ug/L
100.0 2.16 104
75-125
Selenium
95.8
5.0
ug/L
100.0 BRL 96
75-125
Silver
101
5.0
ug/L
100.0 BRL 101
75-125
Matrix Spike Dup (P9C0330-MSD1)
Source: 9030263-05
Prepared & Analyzed: 03/19/19
Arsenic
99.3
1.0
ug/L
100.0 0.811 98
75-125
0.03
20
Barium
214
5.0
ug/L
100.0 123 91
75-125
0.6
20
Cadmium
101
1.0
ug/L
100.0 0.0830 101
75-125
2
20
Chromium
117
2.0
ug/L
100.0 9.23 107
75-125
1
20
Lead
103
1.0
ug/L
100.0 2.16 101
75-125
3
20
Selenium
95.8
5.0
ug/L
100.0 BRL 96
75-125
0.08
20
Silver
102
5.0
ug/L
100.0 BRL 102
75-125
1
20
Batch P9C0395 - 3005A
Blank (P9C0395-BLK1) Prepared & Analyzed: 03/21/19
Lead BRL 1.0 ug/L
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

P R I IS M Full -Service Analytical
Environmental Solutions
. LABORATORIES, INC.
Anchor QEA of North Carolina, PLLC
Attn: Brian Gant
231 Haywood Street
Asheville, NC 28801
Total Metals - Quality Control
Analyte
Batch P9C0395 - 3005A
Project: Madison Closed Landfill
Level II QC Report
4/4/19
Prism Work Order: 9030263
Time Submitted: 3/15/2019 9:00:OOAM
Reporting Spike Source %REC RPD
Result Limit Units Level Result %REC Limits RPD Limit Notes
LCS (P9C0395-BSI)
Prepared & Analyzed: 03/21/19
Lead
106 1.0 ug/L 100.0 106 80-120
Batch P9C0474 - 7470A
Blank (P9C0474-BLK1)
Prepared & Analyzed: 03/26/19
Mercury
BRL 0.20 ug/L
LCS (P9C0474-BS1)
Prepared & Analyzed: 03/26/19
Mercury
9.86 0.20 ug/L 9.375 105 80-120
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

Sample Extraction Data
Prep Method: 3005A
Lab Number Batch Initial Final Date/Time
9030263-01
P9CO297
50
mL
50 mL
03/18/19
8:00
9030263-01
P9C0395
50
mL
50 mL
03/21/19
7:45
9030263-02
P9CO297
50
mL
50 mL
03/18/19
8:00
9030263-02
P9C0395
50
mL
50 mL
03/21/19
7:45
9030263-03
P9C0395
50
mL
50 mL
03/21/19
7:45
9030263-03
P9CO297
50
mL
50 mL
03/18/19
8:00
9030263-04
P9CO297
50
mL
50 mL
03/18/19
8:00
9030263-04
P9C0395
50
mL
50 mL
03/21/19
7:45
9030263-05
P9C0330
50
mL
50 mL
03/19/19
7:40
Prep Method: 7470A
Lab Number
Batch
Initial
Final
Date/Time
9030263-01
P9C0329
20
mL
30 mL
03/19/19
8:50
9030263-02
P9C0329
20
mL
30 mL
03/19/19
8:50
9030263-03
P9C0329
20
mL
30 mL
03/19/19
8:50
9030263-04
P9C0329
20
mL
30 mL
03/19/19
8:50
9030263-05
P9C0474
20
mL
30 mL
03/26/19
8:25
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
9030263-01
P9C0383
10
mL
10 mL
03/20/19 16:00
9030263-02
P9C0383
10
mL
10 mL
03/20/19 16:00
9030263-03
P9C0383
10
mL
10 mL
03/20/19 16:00
9030263-04
P9C0383
10
mL
10 mL
03/20/19 16:00
9030263-05
P9C0383
10
mL
10 mL
03/20/19 16:00
9030263-06
P9C0383
10
mL
10 mL
03/20/19 16:00
Prep Method: 5030E
Lab Number
Batch
Initial
Final
Date/Time
9030263-01
P9C0537
5
mL
5 mL
03/27/19 8:37
9030263-02
P9C0537
5
mL
5 mL
03/27/19 8:37
9030263-03
P9C0537
5
mL
5 mL
03/27/19 8:37
9030263-04
P9C0537
5
mL
5 mL
03/27/19 8:37
9030263-05
P9C0537
5
mL
5 mL
03/27/19 8:37
9030263-06
P9C0537
5
mL
5 mL
03/27/19 8:37
This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc.
449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543
Phone: [phone] - Toll Free Number: 1-800/529-6364 - Fax: [phone]

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