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HomeMy WebLinkAbout5002_Jackson_MSWLF_GW_FID1323366_20190628I WR USE ONLY ❑Paper Report ❑Electronic Data - Email CD rdata loaded: Yes / No Doc/Event #: "NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are 'Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each individually monitored unit. • Please type or print legibly. • Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). • Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. • Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). • Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Anchor QEA of North Carolina, PLLC Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Brian Gant E-mail: bgant@anchorgea.com Phone:828-281-3350 NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Jackson County Municipal Solid US Highway 441 58-02 .1600 March 19, 20, and 21, 2019 Waste Landfill Dillsboro, North Carolina 28725 i Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑X Detection Monitoring Assessment Monitoring T e of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells ❑ Methane gas monitoring data Groundwater monitoring data from private water supply wells ❑X Corrective action data (specify) X Leachate monitoring data X Surface water monitoring; data Other(specify) Corrective Action Natural Attenuation Parameters Notification attached? No. No groundwater or surface water standards were exceeded. X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Alec Macbeth, PG Senior Scientist 828-281-3350 Facility Representative Name (Print) Title (Area Code) Telephone Number 00_ , A � ,� June 30, 2019 Affix NC Licensed! Professional Geologist Seal Signature Date 231 Haywood Street, Asheville, North Carolina 28801 Facility Representative Address P-1649 NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 CAPti:1 ti9 r •may a June 2019 ANCHOR Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 0EAA-4-" Spring 2019 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department June 2019 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Spring 2019 Semiannual Water Quality Monitoring Report Prepared for Jackson County Solid Waste Department 401 Grindstaff Cove Road Sylva, North Carolina 28779 Alec Macbeth, PG Project Geologist Prepared by Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Number: C81480-01.01 \\asheville1\Asheville\Projects\Jackson County\Dillsboro GW\Reports\2019\Spring\Spring 2019 Semiannual Water Quality Report.docx TABLE OF CONTENTS 1 Introduction 1 2 Semiannual Monitoring...........................................................................................................3 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling..........................................3 2.1.1 Monitoring Well Purging and Sampling Methods.................................................................3 2.1.2 Surface Water Sampling Methods................................................................................................4 2.1.3 Leachate Sampling Methods..........................................................................................................5 2.1.4 Domestic Well Sampling Methods...............................................................................................5 2.2 Sample Handling, Documentation, and Analysis....................................................................................5 3 Findings........................................................................................................................................7 3.1 Groundwater.........................................................................................................................................................7 3.1.1 Field Parameters..................................................................................................................................8 3.1.2 Appendix I Metals...............................................................................................................................8 3.1.3 Appendix I VOCs and 1,4-Dioxane...............................................................................................9 3.1.4 Natural Attenuation Parameters................................................................................................. 10 3.2 Surface Water.................................................................................................................................................... 10 3.2.1 Field Parameters............................................................................................................................... 10 3.2.2 Appendix I Metals............................................................................................................................ 11 3.2.3 Appendix I VOCs and 1,4-Dioxane............................................................................................ 11 3.3 Leachate...............................................................................................................................................................11 3.4 Domestic Well.................................................................................................................................................... 11 3.4.1 Field Parameters............................................................................................................................... 11 3.5 Groundwater Flow Directions...................................................................................................................... 12 4 Summary....................................................................................................................................13 4.1 Groundwater Quality...................................................................................................................................... 13 4.1.1 Metals....................................................................................................................................................13 4.1.2 Volatile Organic Compounds....................................................................................................... 13 4.1.3 Field Parameters and Other Constituents............................................................................... 13 4.2 Surface Water Quality..................................................................................................................................... 13 4.3 Leachate Quality............................................................................................................................................... 14 4.4 Domestic Well Water Quality...................................................................................................................... 14 Spring 2019 Semiannual Water Quality Monitoring Report i June 2019 5 Future Activities.......................................................................................................................15 6 References.................................................................................................................................16 TABLES Table 1 Summary of Laboratory Analyses Performed on Samples Table 2 Well Construction Details and Corresponding Elevations Table 3 Summary of Analytical Results FIGURES Figure 1 Site Location Map Figure 2 Site Layout Map Figure 3 Generalized Groundwater Flow Direction Figure 4 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-01) Figure 5 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-01) Figure 6 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-05R) Figure 7 Hydrograph and Vinyl Chloride Concentration vs. Time (Monitoring Well MW-05R) Figure 8 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-07) APPENDICES Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis Spring 2019 Semiannual Water Quality Monitoring Report ii June 2019 ABBREVIATIONS pg/L micrograms per liter PS/cm microsiemens per centimeter 2B standard North Carolina surface water quality standards, as defined in 15A NCAC 2B 2L standard North Carolina groundwater quality standards, as defined in 15A NCAC 2L .0202 AM Analytical Method bgs Below ground surface BOD biochemical oxygen demand CAER Corrective Action Evaluation Report CAP Corrective Action Plan COD chemical oxygen demand DENR North Carolina Department of Environment and Natural Resources DEQ North Carolina Department of Environmental Quality DO dissolved oxygen DWM Division of Waste Management EPA U.S. Environmental Protection Agency IMAC interim maximum allowable concentration MDL method detection limit mg/L milligrams per liter MNA monitored natural attenuation MSWLF Municipal Solid Waste Landfill mV millivolts NCAC North Carolina Administrative Code NTU Nephelometric Turbidity Unit ORP oxidation reduction potential PWR Partially Weathered Rock SC specific conductivity Site Closed Municipal Solid Waste Landfill, approximately 0.75 miles west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74) SM Standard Method SU Standard Unit SVOC semivolatile organic compound SWS Solid Waste Section TOC total organic carbon TWSA Tuckasegee Water & Sewer Authority VOC volatile organic compound Spring 2019 Semiannual Water Quality Monitoring Report iii June 2019 1 Introduction The Jackson County Solid Waste Department maintains a closed Municipal Solid Waste Landfill (MSWLF; the Site) approximately 0.75 miles west of Dillsboro, North Carolina, on the northeast side of Old Dillsboro Road (Old U.S. Highway 74; Figure 1). Water quality monitoring at the landfill is governed by the North Carolina Department of Environmental Quality (DEQ), Division of Waste Management (DWM), Solid Waste Section (SWS), under Permit No. 50-02 issued to Jackson County. The landfill permit requires semiannual monitoring of groundwater and surface water quality. Since October 2007, when Anchor QEA of North Carolina, PLLC (formerly Altamont Environmental, Inc. [Altamont]), began performing water quality monitoring events at the Site, groundwater quality monitoring has indicated persistent low-level concentrations of constituents that exceed groundwater standards. In response to the continued exceedances of the analyzed constituents, an Assessment of Corrective Measures was submitted to the North Carolina Department of Environment and Natural Resources (DENR; now the DEQ) on September 7, 2010 (Altamont 2010). A Corrective Action Plan (CAP; Altamont 2011) was implemented upon approval by the DENR, as recorded in the September 1, 2011 letter regarding "Approval of the County's Corrective Action Plan" (DENR 2011). The implemented remedy includes the extraction of leachate through dedicated submersible pumps installed within landfill gas extraction wells and disposal of the leachate into the Tuckasegee Water & Sewer Authority (TWSA) collection system. In addition to the leachate extraction, groundwater natural attenuation parameters are monitored, and natural attenuation processes are evaluated. As discussed in the CAP, a corrective action evaluation report is prepared every 5 years. The evaluation report analyzes the progress of the approved corrective action remedy based on semiannual water quality monitoring data. The remedy was implemented in a phased approach, with full implementation occurring on September 6, 2013. The first Five -Year Corrective Action Evaluation Report (CAER), submitted by Altamont on October 31, 2016 (Altamont 2016), concluded that the current conditions of the monitored natural attenuation (MNA) parameters and Site geochemical parameters allow for the slow degradation of the select contaminants identified in the CAER. The second CAER is scheduled to be submitted in 2021. This report serves as the first semiannual water quality monitoring report for 2019. The report provides an evaluation of groundwater and surface water quality. The water quality monitoring network is presented in Figure 2. The generalized groundwater flow direction in the upper parts of the underlying aquifer system is provided in Figure 3. In addition to groundwater and surface water monitoring, this report includes volatile organic compound (VOC) analysis of the extracted leachate and one domestic water well. The water samples collected from selected monitoring points during the spring sampling event were analyzed for a range of parameters, as presented in Section 2.2 and Table 1. Spring 2019 Semiannual Water Quality Monitoring Report 1 June 2019 The spring 2019 sampling event was performed on March 19, 20, and 21, 2019, and is being reported in accordance with requirements stipulated in the DEQ Solid Waste Management Rules codified under Title 15A, Subchapter 13B of the North Carolina Administrative Code (NCAC). Spring 2019 Semiannual Water Quality Monitoring Report 2 June 2019 2 Semiannual Monitoring 2.1 Groundwater, Surface Water, Domestic Well, and Leachate Sampling The Site monitoring wells (MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07), surface water sample locations (SW-01 and SW-02), leachate sample location (LT-01), and domestic well (DW-01) were sampled on March 19, 20, and 21, 2019, by Anchor QEA. Static groundwater level measurements and field parameter data are included on the sampling logs presented in Appendix A. Field equipment calibration logs for the YSI Professional Plus Multiparameter Water Quality Meter and the Hach 2100Q Turbidimeter are also provided in Appendix A. The full suite of groundwater and surface water laboratory analytical results is presented in the laboratory analysis reports in Appendix B. Monitoring well MW-02 serves as the Site's background monitoring well, due to its location outside of the contaminant plume. Monitoring wells MW-01 and MW-06 are the Site's upgradient monitoring wells. MW-03 and MW-05R are located in the midgradient portion of the Site and MW-04 and MW-07 monitor downgradient portions of the Site. As summarized in Table 2, the total depths of the monitoring wells range from 40 to 110 feet below ground surface (bgs). The geology of the screened intervals of the monitoring wells is as follows: • Saprolite': MW-04 and MW-05R • Partially Weathered Rock (PWR)z: MW-03 • Bedrock3: MW-01, MW-02, MW-06, and MW-07 The locations of the monitoring wells, surface water samples, leachate, and domestic well sample locations are depicted in Figure 2. 2.7. 7 Monitoring Well Purging and Sampling Methods Before the monitoring wells were sampled, the static water level was gauged in each well, and an initial round of field parameters was measured (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], turbidity, temperature, and oxidation reduction potential [ORP]). Anchor QEA personnel used either low -flow techniques or disposable bailers to purge the monitoring wells and collect groundwater samples. The total depth, condition of the casing, and groundwater recharge rate determined the purging and sample collection method employed at each monitoring well. Saprolite is the result of in -place weathering that produces soil -like material that retains relict features of the parent rock. z PWR is generally found above the bedrock and is softer than bedrock, but not as soft as saprolite. 3 Bedrock is solid competent rock that underlies Saprolite and partially weathered rock. Spring 2019 Semiannual Water Quality Monitoring Report 3 June 2019 2.1.1.1 Monitoring Wells Four of the monitoring wells (MW-03, MW-04, MW-06, and MW-07) were purged using low -flow techniques in accordance with the procedures described by the U.S. Environmental Protection Agency (EPA) in Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures (EPA 1996). During purging, the field parameters (pH, SC, DO, ORP, turbidity, and temperature) were measured and recorded approximately every 3 minutes. Well purging continued until these parameters had generally stabilized for three consecutive readings. The required stabilization criteria are determined by the EPA Region 4 Science and Ecosystem Support Division in Operating Procedure: Groundwater Sampling (EPA 2017) and are summarized as follows: • pH values within ± 0.1 Standard Unit (SU) • SC values within ± 5% • Temperature, DO, and turbidity values within ± 10% • ORP values within ± 10 millivolts (mV) Once the parameters had stabilized, a groundwater sample was collected by a technician wearing a new pair of nitrile gloves, using laboratory -supplied sample containers. Because of their slow recharge rates, monitoring wells MW-01, MW-02, and MW-05R were purged and sampled using disposable polyethylene bailers. The wells were purged of three successive well volumes or purged dry, whichever occurred first. Monitoring wells MW-01 and MW-5R were purged and sampled on March 21 and 20, 2019. Monitoring well MW-02 was purged dry on March 19, checked the following day, and sampled on March 21 after the well had had sufficient time to recharge. A round of field parameters was measured and recorded at the start of purging and after each consecutive well volume had been purged. All field parameter data are shown in the well sampling logs included in Appendix A. 2.1.2 Surface Water Sampling Methods Surface water samples SW-01 and SW-02 were collected on March 19 and 20, 2019, respectively, at designated locations from the Tuckasegee River, which is adjacent to and southwest of the landfill (Figure 2). Sampling location SW-01 is assumed to represent surface water quality upstream of the landfill, and sampling location SW-02 is assumed to represent surface water quality downstream of the landfill. One round of field parameters was measured and recorded at each surface water sampling location immediately prior to collecting the sample (Appendix A). The surface water samples were collected in laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves. Spring 2019 Semiannual Water Quality Monitoring Report 4 June 2019 2.1.3 Leachate Sampling Methods Dedicated bottom -loading air -powered pumps, air pressure lines, and a leachate force main collection system are installed at the landfill. Pumps are installed in landfill gas extraction wells EW-1 R, EW-2R, EW-3R, EW-4, EW-5, EW-6, EW-7, EW-8, EW-9, and EW-10. The gas extraction well locations are presented in Figure 2. The leachate is pumped from the wells into a flow equalization tank, which is connected to the TWSA wastewater collection system. The flow equalization tank is east of the landfill, adjacent to the existing landfill gas flare. A grab sample of leachate (LT-01) was acquired on March 19, 2019, by collecting a sample as the leachate entered the flow equalization tank. One round of field parameters was measured and recorded after the sample was collected (Appendix A). 2. 7.4 Domestic Well Sampling Methods The domestic well water sample (DW-01) was collected on March 21, 2019, from an outside spigot at the residence located at 318 Joe Wilkey Road, bordering the northern boundary of the landfill (Figure 2). The well was purged of three successive well volumes of 10 gallons each prior to sample collection. One round of field parameters was measured and recorded after 30 gallons had been purged. After the third consecutive volume had been purged, a groundwater sample was collected. The domestic well water sample was collected in laboratory -provided sample containers by a technician wearing a new pair of nitrile gloves. 2.2 Sample Handling, Documentation, and Analysis Field parameters and additional observations pertaining to the Site sampling locations are provided in the sampling logs (Appendix A). Following sample collection, each groundwater, surface water, leachate, and domestic well water sample was immediately placed on ice in a sample cooler for transport to Prism Laboratories, Inc., a North Carolina -certified laboratory in Charlotte, North Carolina. The groundwater samples collected from the monitoring wells were analyzed for the following parameters (Table 1): • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I VOCs, using EPA Method 8260B • 1,4-Dioxane, using EPA Method 8260SIM • MNA parameters: — Alkalinity, using Standard Method (SM) 2320B — Biochemical oxygen demand (5-day; BOD), using SM 5210B — Carbon dioxide, ethane, ethene, and methane, using Analytical Method (AM) 20GAX — Hydrogen (only in MW-03, MW-04, MW-06, and MW-07), using AM20GAX — Chemical oxygen demand (COD), using SM 5220D — Chloride, nitrate, and sulfate, using EPA Method 9056A Spring 2019 Semiannual Water Quality Monitoring Report 5 June 2019 - Cyanide, using EPA Method 9014 - Ferrous iron, using SM 3500-Fe D - Sulfide, using SM 4500-5 F - Total organic carbon (TOC), using SM 5310B - Volatile fatty acids, using AM23G The surface water samples were analyzed for the following parameters: • Appendix I metals, including mercury, using EPA Methods 6020B and 7470A • Appendix I VOCs, using EPA Method 8260B • 1,4-Dioxane, using EPA Method 8260SIM • Hardness, using SM2340C The leachate sample was analyzed for the following parameters: • Appendix I VOCs, using EPA Method 8260B • 1,4-Dioxane, using EPA Method 8260SIM The domestic well sample was analyzed for the following parameters: • Appendix I VOCs, using EPA Method 524.2 The SWS issued the memorandum "1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods" dated May 29, 2018, which requires the analysis of 1,4-dioxane at landfills after July 1, 2018 (DEQ 2018a). Per this memorandum, 1,4-dioxane was included in the sampling suite for Site monitoring wells and surface water samples beginning with the October 2018 sampling event. Appendix I and II parameters are identified in Appendix I and II of the Code of Federal Regulations (CFR), Title 40, Part 258. Proper chain -of -custody documentation procedures were followed during collection and transportation of each sample (Appendix B). Five trip blank samples for quality control/quality assurance purposes were included in the sample coolers and analyzed for Appendix I VOCs and for 1,4-dioxane when applicable. The reports of the laboratory analyses are provided in Appendix B. Laboratory analyses performed on the samples are summarized in Table 1. Spring 2019 Semiannual Water Quality Monitoring Report 6 June 2019 3 Findings The laboratory analytical results and field parameter data for the groundwater samples (from monitoring wells MW-01 through MW-07), surface water samples (SW-01 and SW-02), leachate sample (LT-01), and domestic well sample (DW-01) collected at the landfill are included in Appendices A and B. The results are also submitted separately to the DEQ DWM SWS in the Electronic Data Deliverable format, per DEQ guidelines (most recently updated on May 5, 2010). As stipulated in the May 2010 DWM documents referenced in the preceding paragraph, all laboratory analytical results were reported and appropriately qualified as follows: • Non -Detections: Non -detections (non -detects) are values reported by the laboratory as below the method detection limits (MDLs). They are tabulated in Table 3 and flagged with a "U" qualifier. The MDL is the minimum concentration of a substance that can be measured and reported by a laboratory with 99% confidence that the constituent concentration is greater than zero. • Estimated or " Y' Qualified: A "Y' qualifier is used by the laboratory for parameters that are detected at estimated concentrations greater than the MDL but less than the laboratory's method reporting limit. The method reporting limit is the minimum concentration of a target analyte that can be accurately determined by the referenced method. 2L Standard: Detected concentrations of constituents in groundwater samples were compared to applicable North Carolina groundwater quality standards. For most constituents, this standard is the 2L standard, defined in 15A NCAC 2L .0202. Detected concentrations of analytes in groundwater with no established 2L standard were compared to the interim maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in accordance with 15A NCAC 02L .0202 [c]). For the purposes of this report, groundwater standards were taken from the October 15, 2018 list published by the NC SWS (DEQ 2018b). • 2B Standard: Detections of analytes in surface water samples were compared to the surface -water quality standards 2B standards, defined in 15A NCAC 2B. Hardness -dependent 2B surface water standards were calculated using the average analyzed hardness value (calculated from the upstream and downstream surface water sampling location results) via the most stringent hardness -dependent metal calculation. Table 3 presents a summary of detected concentrations of analytes that exceeded their respective 2L standard, IMAC, or 2B standard. 3.1 Groundwater Measured field parameters and analytical results for groundwater samples collected from the monitoring wells are discussed in the following sections. Spring 2019 Semiannual Water Quality Monitoring Report 7 June 2019 3.1. 7 Field Parameters During groundwater sampling on March 19, 20, and 21, 2019, pH readings were obtained from samples collected from monitoring wells MW-01, MW-02, MW-03, MW-04, MW-05R, MW-06, and MW-07. The readings ranged from 5.33 to 7.06 SU (Table 3). Of these monitoring wells, the pH values for MW-01, MW-02, MW-04, MW-06, and MW-07 were outside the 2L Standard pH range of 6.5to8.5SU. The measured turbidity was measured at 3.49 to 165 Nephelometric Turbidity Units (NTU). Generally, the higher values were measured at the monitoring wells (MW-1, MW-02, and MW-05R) that were purged and sampled using the bailer method (Section 2.1.1). The bailers were lowered gently to minimize water column disturbance when the samples were collected. The lowest turbidity (3.49 NTU) was measured in the groundwater sample collected from monitoring well MW-04. DO concentrations at the Site ranged from 1.53 milligrams per liter (mg/L) in monitoring well MW-01 to 9.44 mg/L in monitoring well MW-03. SC concentrations at the Site ranged from 60.4 microsiemens per centimeter (pS/cm) in monitoring well MW-06 to 774 pS/cm in monitoring well MW-05R. ORP concentrations at the Site ranged from -85.8 mV in monitoring well MW-05R to 419.7 mV in monitoring well MW-04. Groundwater standards are not established for DO, SC, or ORP. These measured field parameter values are consistent with historical data. 3. 7.2 Appendix I Metals Three metals (cobalt, thallium, and vanadium) were detected at concentrations above their respective 2L or IMAC water quality standards in the groundwater samples collected from one or more of the monitoring wells during the spring 2019 water quality monitoring event. Vanadium exceeded its 2L standard; cobalt and thallium exceeded their applicable IMACs. Cobalt was detected above its IMAC (1 micrograms per liter [pg/L]) in groundwater samples collected from each of the monitoring wells. Cobalt concentrations in these samples ranged from 1.3 pg/L (MW-07) to 180 pg/L (MW-01). Historically, cobalt has been present at concentrations above its applicable water quality standard in groundwater samples from each of the seven monitoring wells. Thallium was detected in five groundwater samples collected from the landfill. Two of the groundwater samples (collected from MW-01 and MW-06) contained thallium at concentrations above the IMAC (0.2 pg/L), at concentrations of 0.52 J pg/L (MW-01) and 0.43 J pg/L (MW-06). Historically, thallium has been detected at concentrations above its water quality standard in the samples collected from groundwater monitoring wells MW-01, MW-05R, and MW-06. Vanadium was detected in the groundwater samples collected from six monitoring wells, MW-01, MW-02, MW-03, MW-05R, MW-06, and MW-07, at concentrations ranging from 0.91 J pg/L (MW-07) Spring 2019 Semiannual Water Quality Monitoring Report 8 June 2019 to 7.0 pg/L (MW-02). Each of these detected vanadium concentrations exceeded the metal's 2L standard (0.03 pg/L). Historically, vanadium has been present at concentrations above its water quality standard in samples collected from multiple groundwater monitoring wells at the Site. 3. 7.3 Appendix 1 VOCs and 1,4-Dioxane Four VOCs (1,4-dichlorobenzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at concentrations above their respective 2L standards in the groundwater samples collected from one or more monitoring wells during the spring 2019 water quality monitoring event. Except for 1,4-dioxane, concentration -versus -time graphs (trend plots) were created for the monitoring wells that have historically exhibited VOC concentrations above the associated 2L standards (Figures 4 through 8). As noted in Section 2.2, 1,4 dioxane has only been analyzed for since October 2018. This compound will be included in the trend plots in future semiannual reports, as warranted. The detected concentration of 1,4-dichlorobenzene exceeded its 2L standard (6 pg/L) in monitoring well MW-01 (13 pg/L), as shown in Table 3. The historical 1,4-dichlorobenzene concentration trend in MW-01 remains relatively stable (Figure 4). Benzene was detected at concentrations above its 2L standard of 1 pg/L in three monitoring wells: MW-01 (2.3 pg/L), MW-05R (1.4 pg/L), and MW-07 (1.4 pg/L). Overall, historical benzene concentration trends in monitoring wells MW-01, MW-05R, and MW-07 have been stable and slightly above the 2L standard (Figures 5, 6, and 8). The concentration of vinyl chloride in the sample collected from one monitoring well, MW-05R, (2.7 pg/L) was above the compound's 2L standard (0.03 pg/L). A trend plot for vinyl chloride concentrations in MW-05R is presented in Figure 7 and shows a fluctuating trend of concentrations above the 2L standard. Vinyl chloride was not detected in the other monitoring wells during this sampling event (Table 3). Historically, vinyl chloride has exceeded its 2L standard in monitoring wells MW-04, MW-05R, and MW-07, located in the southwestern part of the landfill. The detected concentrations of 1,4-dioxane exceeded its 2L standard (3 pg/L) in MW-04, MW-05R, and MW-07, with concentrations ranging from 3.5 pg/L (MW-04) to 18 pg/L (MW-07). 1,4-Dioxane was not detected in monitoring wells MW-01 or MW-06 and was detected at concentrations below the 2L standard in the samples collected from monitoring wells MW-02 and MW-03. The spring 2019 sampling event represents the second sampling event that 1,4-dioxane was included in the analytical suite, in accordance with the SWS May 29, 2018 memorandum (DEQ 2018a). A review of historical groundwater data indicates that four VOCs (1,4-dichlorobenzene; benzene; tetrachloroethene; and vinyl chloride) have been detected at relatively consistent concentrations for the past several years. As described in Section 3.2.3, historical surface water samples from the Spring 2019 Semiannual Water Quality Monitoring Report 9 June 2019 Tuckasegee River, which likely receives discharge from the saprolite groundwater -bearing zone, have consistently shown no detections of these compounds, or other VOCs. 3.7.4 Natural Attenuation Parameters During this sampling event, the groundwater samples were analyzed for MNA parameters as described in Section 2.2 (Table 1). The results of these analyses are summarized in Table 3. These parameters were detected in one or more groundwater samples collected from the monitoring wells. Many of these parameters do not have established groundwater standards. Of the parameters that do have established groundwater standards, chloride and sulfate, there were no exceedances. An in- depth analysis of the MNA parameters that apply to the Site's select contaminants was presented in the first Five -Year CAER (Altamont 2016). The CAER concluded that the MNA data provide evidence that both reductive degradation and aerobic degradation are occurring in different portions of the Site. The current data on the MNA parameters will be used in the second Five -Year CAER (scheduled for 2021) to evaluate the degradation processes at the Site. 3.2 Surface Water The following sections summarize the measured field parameters and analytical results associated with the two surface water samples collected during the spring 2019 sampling event. 3.2.7 Field Parameters The pH readings for the upstream (SW-1) and downstream (SW-2) surface water samples collected during the spring 2019 sampling event were 7.45 and 7.68 SU, respectively. The pH readings for both surface water samples were within the 2B standard range of 6.0 to 9.0 SU. The turbidity values measured in SW-01 (7.10 NTUs) and SW-02 (12.1 NTUs) were below the 2B standard, which is established at less than or equal to 50 NTU for the receiving water in streams not designated as trout waters. DO was measured at a concentration of 13.25 mg/L in SW-01 and 13.66 mg/L in SW-02. The 2B standard is established as greater than or equal to 5.0 mg/L; thus, each sample is within the acceptable DO range. SC concentrations in surface water samples SW-01 and SW-02 were recorded at 25.5 and 24.5 pS/cm, respectively. ORP values for SW-01 and SW-02 were 146.2 and 149.3 mV. These concentrations of SC and ORP are consistent with historical data for both surface water samples. 2B standards do not exist for these parameters. Spring 2019 Semiannual Water Quality Monitoring Report 10 June 2019 3.2.2 Appendix I Metals Copper, lead, nickel, and zinc were all detected at concentrations exceeding the applicable 2B standards during this sampling event. Copper concentrations in surface water samples SW-01 and SW-02 were 15 pg/L and 0.66 J pg/L, respectively, exceeding the metal's 2B Standard of 0.60 pg/L. Lead concentrations in SW-01 and SW-02 were 0.40 J pg/L and 0.20 J pg/L; the 2B standard for lead is 0.07 pg/L. Nickel exceeded its 2B standard (3.59 pg/L) in one of the surface water samples, SW-01 at 15 pg/L. Zinc concentrations in SW-01 and SW-02 were 23 pg/L and 15 pg/L, which exceeded the associated 2B standard of 8.07 pg/L. According to historical data, metals have consistently been detected at various concentrations upstream and downstream of the landfill. 3.2.3 Appendix 1 VOCs and 7,4-Dioxane Acetone was detected at a concentration below the 2B standard in SW-01. No other VOCs were detected at concentrations above their respective MDLs in either the upstream or downstream surface water samples (Table 3). 3.3 Leachate Eleven VOCs (1,4-dichlorobenzene; acetone; benzene; chlorobenzene; ethylbenzene; m,p-xylenes; o-xylene; tetrahydrofuran; toluene; total xylenes; and 1,4-dioxane) were detected in the leachate sample (LT-01), as summarized in Table 3. On September 1, 2012, leachate extraction was initiated following installation of leachate extraction pumps in the 10 landfill gas extraction wells at the Site (Figure 2). Due to a malfunction with the leachate flow meter, an accurate calculation of cumulative leachate removed can no longer be obtained. Therefore, the total volume of leachate removed since September 2012 is not known. 3.4 Domestic Well The following sections summarize measured field parameters and analytical results associated with the domestic well water sample collected during the spring 2019 sampling event. 3.4. 7 Field Parameters The pH reading for the domestic well sample (DW-01) was 6.67 SU, which is within the 2L standard range of 6.5 to 8.5 SU. Turbidity measured in DW-01 was 5.32 NTUs. DO was measured at a concentration of 5.91 mg/L in DW-01. SC and ORP values in DW-01 were recorded at 60.8 pS/cm and 308.8 mV, respectively. These parameters do not have established water quality standards. Spring 2019 Semiannual Water Quality Monitoring Report 11 June 2019 3.5 Groundwater Flow Directions Groundwater levels in the saprolite, PWR, and bedrock are monitored at the Site. Three bedrock monitoring wells (MW-01, MW-02, and MW-06) are located in the northern and northwestern portions of the Site (Figure 3; Table 2). The fourth bedrock monitoring well (MW-07) is located southwest of the landfill (Figure 3). The fall 2018 water level data collected from these four bedrock wells were used to determine the generalized bedrock groundwater flow direction, which is to the southwest (Figure 3). PWR monitoring well MW-03 and saprolite monitoring wells MW-04 and MW-05R (Figure 3) are located in the central, southwest, and southern parts of the landfill, respectively. The spring 2019 water level data collected from monitoring wells MW-03, MW-04, and MW-05R (Table 2) indicate that groundwater flow direction in the combined saprolite and PWR zones is generally to the south- southwest, toward the Tuckasegee River (Figure 3). Spring 2019 Semiannual Water Quality Monitoring Report 12 June 2019 4 Summary The first semiannual water quality monitoring event of 2019 for the Jackson County closed MSWLF was performed on March 19, 20, and 21, 2019. Table 3 and the Reports of Laboratory Analysis (Appendix B) provide detailed analytical results and field data summarizing the groundwater, surface water, and leachate quality at the landfill. 4.1 Groundwater Quality 4.7.7 Metals Three metals (cobalt, thallium, and vanadium) were detected at concentrations above their associated groundwater quality standards in one or more of the monitoring wells (Table 3). Cobalt concentrations exceeded its 2L standard in all of the collected groundwater samples. These results are consistent with historical data. 4.1.2 Volatile Organic Compounds Four VOCs (1,4-dichlorobenzene; benzene; vinyl chloride; and 1,4-dioxane) were detected at concentrations above their respective 2L standards (Table 3) in one or more monitoring wells. Concentration -versus -time graphs were created for samples from monitoring wells that had VOC concentrations above their 2L standards, with the exception of 1,4-dioxane. The graphs are provided as Figures 4 through 8. 4. 7.3 Field Parameters and Other Constituents Five of the seven of the samples collected from the monitoring wells had pH readings outside of the 2L standard range (6.5 to 8.5 SU). These results are consistent with historical data and are characteristic of the natural groundwater quality of the region. Turbidity readings ranged from 3.49 NTUs (MW-04) to 165 NTUs (MW-02). Natural attenuation parameters (alkalinity, BOD, COD, chloride, carbon dioxide, hydrogen, ferrous iron, methane, nitrate, sulfate, and TOC) were detected at various concentrations in groundwater samples collected from one or more of the monitoring wells. Natural attenuation parameters are being monitored to fulfill CAP requirements; further evaluation of these parameters will be performed in the second Five -Year CAER (scheduled for 2021). 4.2 Surface Water Quality Copper, lead, nickel, and zinc were detected at or above the applicable 2B standards for surface water during this monitoring event. Concentrations in the upstream sample exceeded concentrations Spring 2019 Semiannual Water Quality Monitoring Report 13 June 2019 in the downstream sample for all metals that were greater than applicable 2B standards. No VOCs were detected at or above the applicable surface water standards. Based on these data, the groundwater migrating from the landfill toward the Tuckasegee River does not appear to be impacting surface water quality with regard to metals and VOCs. Field parameters measured in both surface water samples, including pH, turbidity, and DO, were within the 2B standards established for these parameters. 4.3 Leachate Quality The leachate sample (LT-01) was collected from the flow equalization tank and analyzed for Appendix I VOCs and metals. Eleven VOCs were detected in the leachate sample (Table 3). There are no established water quality standards for leachate. 4.4 Domestic Well Water Quality No VOCs were detected at concentrations above their respective MDLs in the domestic well water samples. Spring 2019 Semiannual Water Quality Monitoring Report 14 June 2019 5 Future Activities Anchor QEA will continue to monitor the water quality on a semiannual basis at the Jackson County closed MSWLF. During the fall of 2019, domestic well owners will be contacted, and groundwater samples will be collected from domestic wells if permitted by the well owner, and if possible, based on well pump operability. Domestic well samples will be analyzed for VOCs only. Samples will be collected from the monitoring wells, surface water monitoring points, and leachate flow equalization tank during the fall of 2019 and spring of 2020. In addition to the natural attenuation parameters that were added to the monitoring requirements as part of the CAP, the analytical suites associated with the current and future sampling events are outlined in the 2011 CAP (Altamont 2011) and the first Five -Year CAER (Altamont 2016). The upcoming sampling event parameters are as follows: Sampling Event Analytical Suite (not inclusive of natural attenuation parameters) Appendix II VOCs (including 1,4-dioxane) Fall 2019 Appendix II Metals Appendix II SVOCs Sulfide Appendix I VOCs (including 1,4-dioxane) Spring 2020 Appendix I Metals Sulfide Spring 2019 Semiannual Water Quality Monitoring Report 15 June 2019 6 References Altamont (Altamont Environmental, Inc.), 2010. Assessment of Corrective Measures. Prepared for the North Carolina Department of Environment and Natural Resources. September 7, 2010. Altamont, 2011. Corrective Action Plan. Prepared for the North Carolina Department of Environment and Natural Resources. June 30, 2011. Altamont, 2016. Five -Year Corrective Action Evaluation Report. Prepared for the North Carolina Department of Environmental Quality. October 31, 2016. DENR, 2011. Letter to: Altamont Environmental, Inc. Regarding: Approval of the County's Corrective Action Plan. September 1, 2011. DEQ (North Carolina Department of Environmental Quality), 2018a. Memorandum to: Solid Waste Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding: 1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods. May 29, 2018. DEQ, 2018b. "Groundwater Protection Compliance Standards — Constituents List". Last modified October 1 S, 2018. Available at: https://edocs.deq.nc.gov/WasteManagement/0/edoc/l257181/SWS_EnviroMonitoring_Const ituents_List.pdf?searchid=13f8efbl -eel l-485a-b03f-718f2287b271 EPA (U.S. Environmental Protection Agency), 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. OSWER, EPA/540/5-95/504. EPA, 2017. Science and Ecosystem Support Division. Operating Procedure: Groundwater Sampling. April 26, 2017. Spring 2019 Semiannual Water Quality Monitoring Report 16 June 2019 Tables Table 1 Summary of Laboratory Analyses Performed on Samples Groundwater Samples Analysis Metals Mercury VOCs 1,4-Dioxane Sample Name Date Collected EPA 6020B EPA 7470A EPA 8260B EPA 8260SIM MW-01 03/21/2019 X X X X MW-02 03/21/2019 X X X X MW-03 03/20/2019 X X X X MW-04 03/19/2019 X X X X MW-05R 03/20/2019 X X X X MW-06 03/21/2019 X X X X MW-07 03/19/2019 X X X X Surface Water, Leachate, Domestic Well, and Quality Control Samples Analysis Metals Mercury VOCs VOCs 1,4-Dioxane Hardness Sample Name Date Collected EPA 6020B EPA 7470A EPA 8260B EPA 524.2 EPA 8260SIM SM2340 C DW-01 03/21/2019 X SW-01 03/19/2019 X X X X X SW-02 03/20/2019 X X X X X LT-01 03/19/2019 X X Trip Blank (1) 03/19/2019 X X Trip Blank (2) 03/20/2019 X X Trip Blank (3) 03/21/2019 X X Trip Blank (4) 03/21/2019 X X Trip Blank (5 - DW) 03/21/2019 X Groundwater Samples: Natural Attenuation Parameters Analysis Total Alkalinity to pH 4.5 BOD COD Cyanide Volatile Fatty Acids Ferrous Iron Nitrate as N Chloride Sulfate TOC Sulfide Ethane, Ethene, Methane Hydrogen Carbon Dioxide Sample Name Date Collected SM 2320B SM 5210B SM 5220D 9014 AM23G SM 3500-Fe D EPA 9056A SM 5310B SM4500-S F AM20GAX MW-01 03/21/2019 X X X X X X X X X X X X X MW-02 03/20/2019 X X X X X X X X X X X X X MW-03 03/19/2019 X X X X X X X X X X X X X X MW-04 03/20/2019 X X X X X X X X X X X X X X MW-05R 03/21/2019 X X X X X X X X X X X X X MW-06 03/19/2019 X X X X X X X X X X X X X X MW-07 01/00/1900 X X X X X X X X X X X X X X Notes: Appendix I constituents were analyzed per Title 40 Code of Federal Requlations, Part 258. AM: Analytical Method Blank cell: Analysis was not performed on that sample. BOD: biochemical oxyqen demand COD: chemical oxygen demand EPA: U.S. Environmental Protection Agency (method) SIM: Selective Ion Monitoring SM: Standard Method TOC: total organic carbon VOC: volatile organic compound Spring 2019 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 2 Well Construction Details and Corresponding Elevations Depth to Depth to Elevation of Ground Depth To Approximate Approximate Top of Bottom of Top Elevation Bottom of Surface TOC Stick Up Total Well Water Depth to Top of Bedrock Screened Screened of Screened Screened Geology of Source of Well Facility Elevation Elevation (feet Depth (feet below Groundwater Bedrock Elevation Interval Interval Interval Interval Screened Construction Permit Well ID Date Drilled (feet) (feet) above gs) (feet bgs) TOC) Elevation (feet) (feet bgs) (feet) (feet bgs) (feet bgs) (feet) (feet) Interval Information MW-01 04/23/1992 2,169.40 2,171.42 1 2.0 110.5 97.95 2,073.47 83.0 2,086.40 95.0 110.0 2,074.40 2,059.40 Bedrock MW-02 04/22/1992 2,013.15 2,015.38 2.3 60.7 34.65 1,980.73 13.0 2,000.15 45.0 60.0 1,968.15 1,953.15 Bedrock Partially S&ME, Inc. MW-03 04/21/1992 2,044.16 2,045.53 1.3 65.5 36.70 2,008.83 57.0 1,987.16 48.5 63.5 1,995.66 1,980.66 50-02 Weathered Rock MW-04 04/21/1992 1,978.68 1,980.77 2.0 43.0 24.38 1,956.39 NA NA 25.0 40.0 1,953.68 1,938.68 Saprolite MW-05R 01/26/2012 2,027.98 2,030.95 2.8 54.0 47.21 1,983.74 NA NA 44.0 54.0 1,983.98 1,973.98 Saprolite Altamont MW-06 03/23/2004 2,136.58 2,139.57 3.0 94.0 76.49 2,063.08 47.6 2,088.98 84.6 94.6 2,051.98 2,041.98 Bedrock Environmental, Inc. MW-07 07/30/2010 1,978.71 1,981.29 2.6 95.0 31.15 1,950.14 44.0 1,935.00 70.0 95.0 1,908.71 1,883.71 Bedrock Notes: Elevations associated with wells MW-01, MW-02, MW-03, MW-04, and MW-06 are measured relative to mean sea level and are based on surveying completed by Davenport & Associates, Inc. Elevations associated with wells MW-05R and MW-07 are measured relative to horizontal North American Datum 83 and are based on surveying completed by Wes Cole Land Surveying, PA. Depth to water was measured on March 19, 20, and 21, 2019. Depth to bedrock and screened interval for MW-01 through MW-04 was taken from S&ME, Inc., boring logs completed April 21 through 23, 1992. Depth to bedrock and screened interval for MW-06 was taken from an Altamont Environmental, Inc., boring log completed March 23, 2004. Depth to bedrock and screened interval for MW-07 was taken from an Altamont Environmental, Inc., boring log completed July 30, 2010. Depth to bedrock and screened interval for MW-05R was taken from an Altamont Environmental, Inc., boring log completed January 26, 2012. Monitoring well MW-05 was abandoned on January 26, 2012, by NYEG Drilling, LLC. Monitoring well MW-05R was installed by NYEG Drilling, LLC, on January 26, 2012, as a replacement to MW-05. Monitoring well MW-05R was surveyed by Wes Cole Land Surveying, PA, on September 28, 2012. bgs: below ground surface gs: ground surface NA: not applicable TOC: top of casing Spring 2019 Semiannual Water Quality Monitoring Report Page 1 of 1 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 3 Summary of Analytical Results Lab Certification Lab Method Metals 402, 415 EPA 6020A, 7470A Parameter >, _ Q _ Q V •i Q •to m .O m R v E 3 t v O U L O v y -j �, 47 a v Z E .O IA L V) E t H R > O N ra 2 CAS Number 7440-36-0 7440-38-2 7440-39-3 7440-41-7 7440-43-9 7440-47-3 7440-48-4 7440-50-8 7439-92-1 7439-97-6 7440-02-0 7782-49-2 7440-22-4 7440-28-0 7440-62-2 7440-66-6 NE SWSID 13 14 15 23 34 51 53 54 131 132 152 183 184 194 209 213 NE Units Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L Ng/L N /L Ng/L Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-01 03/21/2019 0.19 U 0.64 J 100 0.062 J 1.1 0.84 J 180 9.9 0.72 J 0.043 J 15 0.63 U 0.063 U 0.52 J 1.1 38 NA MW-02 03/21/2019 0.19 U 0.87 J 50 0.15 J 0.078 U 5.9 13 5.2 1.5 0.058 J 3.9 0.63 U 0.063 U 0.12 J 7.0 29 NA MW-03 03/20/2019 0.22 J 0.98 J 160 0.060 J 0.23 J 5.6 3.5 10 0.81 J 0.042 J 8.7 0.63 U 0.063 U 0.099 U 3.3 27 NA MW-04 03/19/2019 0.21 J 0.30 J 98 0.065 J 0.18 J 0.35 J 1.4 0.38 J 0.093 U 0.036 J 2.5 0.64 J 0.073 J 0.15 J 0.10 U 16 NA MW-05R 03/20/2019 0.19 U 0.59 J 150 0.057 U 0.28 J 0.97 J 9.4 2.5 J 0.37 J 0.036 U 3.0 0.63 U 0.063 U 0.099 U 0.98 J 20 NA MW-06 03/21/2019 0.19 U 0.17 J 56 0.094 J 0.20 J 0.77 J 5.9 3.8 J 0.10 J 0.036 U 19 0.63 U 0.063 U 0.43 J 0.95 J 28 NA MW-07 03/19/2019 0.19 U 0.23 J 470 0.057 U 0.096 J 1.2 J 1.3 0.69 J 0.28 J 0.036 U 8.3 0.63 U 0.063 U 0.12 J 0.91 J 15 NA Leachate Sample LT-01 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Surface Water Samples SW-01 03/19/2019 0.19 U 0.26 J 14 0.057 U 0.078 U 1.0 J 0.24 J 15 0.40 J 0.036 U 15 0.63 U 0.063 U 0.099 U 0.50 J 23 2,000 J SW-02 03/20/2019 0.19 U 0.15 J 13 0.057 U 0.078 U 0.76 J 0.16 J 0.66 J 0.20 J 0.036 U 0.85 U 0.63 U 0.063 U 0.099 U 0.54 J 15 6,500 Domestic Well Sample DW-01 1 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Quality Control Samples Trip Blank (1) 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trip Blank (2) 03/20/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trip Blank (3) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trip Blank (4) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA Trip Blank (5 - DW) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA NA MDL 0.19 0.031 0.97 0.057 0.078 0.19 0.0071 0.22 0.093 0.036 0.85 0.63 0.063 0.099 0.10 2.8 35 Laboratory and Regulatory MRL 1.0 1.0 5.0 1.0 1.0 2.0 1.0 5.0 1.0 0.20 2.0 5.0 5.0 1.0 1.0 10 910 Thresholds 2L NE 10 700 NE 2 10 NE 1,000 15 1 100 20 20 NE 0.03 1,000 NE IMAC 1 NE NE 4 NE NE 1 NE NE NE NE NE NE 0.2 NE NE NE 213 640 10 21,000 6.5 0.04* 5.58* 4 0.60* 0.07* 0.012 3.59* 5 0.01* 0.47 NE 8.07* NE Spring 2019 Semiannual Water Quality Monitoring Report Page 1 of 5 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 3 Summary of Analytical Results Lab Certification Lab Method Volatile Organic Compounds 402, 618 EPA 826013, 524.2 EPA 8260SIM Parameter M O a N c O O - a N C O O - O v Q N N N m = N i O t V N t 'v C C N �+ w d C d X E i O V GJ O o = a C *' H •� ` `� H C H a, O O H V �O v 7+ > + +0 vi u� d X dcR Nt CAS Number 75-34-3 95-50-1 106-46-7 67-64-1 71-43-2 108-90-7 156-59-2 100-41-4 108-38-3/ 106-42-3 75-09-2 95-47-6 127-18-4 109-99-9 108-88-3 79-01-6 75-01-4 1330-20-7 123-91-1 SWSID 75 69 71 3 16 39 78 110 359 140 408 192 458 196 201 211 346 10 Units N /L I N /L I N /L N /L N /L I N /L N /L N /L N /L N /L N /L N /L N /L N /L N /L N /L N /L N /L Sample Name Collect Date Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-01 03/21/2019 4.3 0.26 J 13 32 2.3 3.2 6.9 0.061 U 1.9 0.083 U 1.4 0.66 0.16 U 0.044 U 0.81 0.097 U 3.3 0.14 U MW-02 03/21/2019 0.35 J 0.076 U 0.050 U 6.3 0.048 U 0.062 U 0.55 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 2.8 J MW-03 03/20/2019 0.083 U 0.076 U 0.050 U 8.3 0.048 U 0.062 U 0.056 U 0.061 U 0.42 J 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.42 J 1.8 J MW-04 03/19/2019 0.083 U 0.076 U 1.0 6.3 0.048 U 0.70 0.44 J 0.061 U 0.35 J 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.35 J 3.5 MW-05R 03/20/2019 0.083 U 0.076 U 5.4 11 1.4 7.2 4.2 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 2.7 0.15 U 4.3 MW-06 03/21/2019 2.2 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 1.6 0.061 U 0.51 J 0.61 A, J 0.044 U 0.098 U 0.16 U 0.044 U 0.26 J 0.097 U 0.51 J 0.14 U MW-07 03/19/2019 0.083 U 0.33 J 4.5 6.3 1.4 4.8 2.3 0.061 U 0.70 J 0.083 U 0.26 J 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.96 J 18 Leachate Sample LT-01 03/19/2019 0.083 U 0.076 U 4.2 7.7 1.9 2.7 0.056 U 0.45 J 0.55 J 0.083 U 0.72 0.098 U 110 0.53 0.078 U 0.097 U 1.3 J 51 Surface Water Samples SW-01 03/19/2019 0.083 U 0.076 U 0.050 U 6.3 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U SW-02 03/20/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U Domestic Well Sample DW-01 1 03/21/2019 0.0050 U 0.0050 U 0.0050 U NA 0.0050 U 0.0050 U 0.0050 U 0.0050 U NA 0.0050 U 0.0050 U 0.0050 U NA 0.0050 U 0.0050 U 0.0050 U 0.0050 U NA Quality Control Samples Trip Blank (1) 03/19/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.64 A, J 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U Trip Blank (2) 03/20/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U Trip Blank (3) 03/21/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U Trip Blank (4) 03/21/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U Trip Blank (5 - DW) 03/21/2019 0.083 U 0.076 U 0.050 U 0.31 U 0.048 U 0.062 U 0.056 U 0.061 U 0.12 U 0.083 U 0.044 U 0.098 U 0.16 U 0.044 U 0.078 U 0.097 U 0.15 U 0.14 U MDL 0.083/0.0050 0.076/0.0050 0.050/0.0050 0.31 0.048/0.0050 0.062/0.0050 0.056/0.0050 0.061/0.0050 0.12 0.083/0.0050 0.044/0.0050 0.098/0.0050 0.16 0.044/0.0050 0.078/0.0050 0.097/0.0050 0.15/0.0050 0.14 Laboratory and Regulatory MRL 0.50 0.50 0.50 5.0 0.50 0.50 0.50 0.50 1.0 1.0 0.50 0.50 10 0.50 0.50 0.50 1.5 3.0 Thresholds 2L 6 20 6 6,000 1 50 70 600 NE 5 NE 0.7 NE 600 3 0.03 500 3 IMACI NE I NE I NE I NE I NE NE NE I NE I NE I NE I NE I NE I NE I NE I NE I NE I NE I NE 213 100 1 3,000 1 900 1 2,000 1 51 800 720 1 97 1 670 1 1,000 1 600 1 120 1 110,000 1 11 1 30 1 2.4 1 670 1 80 Spring 2019 Semiannual Water Quality Monitoring Report Page 2 of 5 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 3 Summary of Analytical Results Lab Certification Lab Method Natural Attenuation Parameters 402, 618 SM 2320B SM 5210B EPA 9056A SM 5220D SM 3500-Fe-D EPA 9056A EPA 9056A SM4500-S F EPA 9060A AM23G Sample Name Parameter +. Y Q r Q $ G CO G1 a O v 0 O 3 i LL _ ° Z H +d+ Z +d+ in y Q V i+ a V Q V LL CAS Number SW337 SW316 16887-00-6 SW317 NA SW303 14808-79-8 184-96-258 C-012 64-19-7 64-18-6 SWSID 337 316 301 317 334 303 315 187 357 NE NE Units Ng/L pg/L pg/L pg/L pg/L pg/L pg/L pg/L mg/L mg/L mg/L Collect Date Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-01 03/21/2019 110,000 13,000 850 J 97,000 37,000 57 J 490 U 1,200 J 21.9 0.91 0.22 MW-02 03/21/2019 39,000 1,000 J 19,000 27,000 J 46 U 340 10,000 1,200 J 2.44 0.18 0.20 U MW-03 03/20/2019 170,000 1,900 J 20,000 48,000 J 150 J 3,400 7,200 1,400 J 9.36 0.10 U 0.55 MW-04 03/19/2019 84,000 3,200 27,000 17,000 U 46 U 11,000 63,000 1,000 J 0.600 U 0.10 U 0.62 MW-05R 03/20/2019 330,000 4,400 44,000 44,000 J 46 U 100 490 U 830 U 10.5 0.17 0.20 U MW-06 03/21/2019 22,000 200 U 1,100 17,000 U 46 U 590 1,100 J 2,700 4.97 1 2.0 0.20 U MW-07 03/19/2019 250,000 240 J 78,000 17,000 U 46 U 65 J 22,000 1,800 J 0.600 U 0.10 U 0.20 U Leachate Sample LT-01 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA Surface Water Samples SW-01 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA SW-02 03/20/2019 NA NA NA NA NA NA NA NA NA NA NA Domestic Well Sample DW-01 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Quality Control Samples Trip Blank (1) 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (2) 03/20/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (3) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (4) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (5 - DW) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Laboratory and Regulatory Thresholds MDL 770 NE 120 17,000 46/230 41 490 830 0.3/0.6 0.024 0.048 MRL 5,000 2,000 1,000 50,000 200/5,000 100 2,000 2,000 2/4 0.1 0.2 2L NE NE 250,000 NE NE NE 250,000 NE NE NE NE IMAC NE NE NE NE NE NE NE NE NE 5,000 NE 2B 20,000 NE 230,000 NE 1,000 NE NE NE NE NE NE Spring 2019 Semiannual Water Quality Monitoring Report Page 3 of 5 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 3 Summary of Analytical Results Lab Certification Lab Method Natural Attenuation Parameters 402, 618 Field Parameters 5445 (pH only) AM20GAX Sample Name Parameter N s c „ c W y 0 G c G7 2 c a X 0 y c LA 0 L 3 i E r •Z ++ V O 0 V V a, IA � 0 ..• V C 0 Iii -O Gl X + O 0. c. r L � CAS Number 74-82-8 74-84-0 74-85-1 124-38-9 1333-74-0 7782-44-7 SW325 SW323 SW336 SW320 SW330 SWSID 456 332 331 459 420 356 325 323 336 320 NE Units N /L N /L N /L m /L nM m /L °C PS/cm mV SU NTU Collect Date Result Result Result Result Result Result Result Result Result Result Result Groundwater Samples MW-01 03/21/2019 1,800 0.16 0.10 U 280 NA 1.53 14.9 266.9 45.3 5.96 75.0 MW-02 03/21/2019 0.50 U 0.10 U 0.10 U 54 NA 8.01 14.7 164.3 279.3 6.19 165 MW-03 03/20/2019 0.20 U 0.020 U 0.020 U 55 120 9.44 13.7 413.6 236.3 6.71 74.1 MW-04 03/19/2019 14 0.020 U 0.020 U 140 110 5.24 14.3 449.5 419.7 5.92 3.49 MW-05R 03/20/2019 2,500 0.28 0.10 61 NA 3.39 16.7 774 -85.8 7.06 47.7 MW-06 03/21/2019 0.45 0.020 U 0.020 U 160 4.8 5.32 13.2 60.4 322.1 5.33 4.17 MW-07 03/19/2019 190 0.081 0.10 210 46 2.02 14.3 733 155.8 6.09 11.1 Leachate Sample LT-01 03/19/2019 NA NA NA NA NA 4.45 11.9 3,612 48.4 1 6.80 20.5 Surface Water Samples SW-01 03/19/2019 NA NA NA NA NA 13.25 8.2 25.5 146.2 7.45 7.10 SW-02 1 03/20/2019 NA I NA NA NA NA 13.66 8.3 24.5 149.3 7.68 12.1 Domestic Well Sample DW-01 103/21/2019 NA NA NA NA NA 5.91 13.6 60.8 308.8 1 6.67 5.32 Quality Control Samples Trip Blank (1) 03/19/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (2) 03/20/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (3) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (4) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Trip Blank (5 - DW) 03/21/2019 NA NA NA NA NA NA NA NA NA NA NA Laboratory and Regulatory Thresholds MDL 0.044/0.046 0.005/0.006 0.004/0.01 0.45/1.6 1.5/3 NA NA NA NA NA NA MRL 0.2/0.5 0.1/0.02 0.1/0.02 5/4 2/4 NA NA NA NA NA NA 2L NE NE NE NE NE NE NE NE NE 6.5-8.5 NE IMAC NE NE NE NE NE NE NE NE NE NE NE 213 NE NE NE NE NE > 5.0 NE NE NE 6.0-9.0 <_ 50 Spring 2019 Semiannual Water Quality Monitoring Report Page 4 of 5 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Table 3 Summary of Analytical Results Notes: Only results, MDLs, MRLs, certification numbers, and methods for detected constituents are listed in this table. Please refer to the Prism Report of Laboratory Analysis in Appendix B for further details. °C: degrees Celsius pg/L: micrograms per liter pS/cm: microsiemens per centimeter 213: surface water standard per North Carolina Administrative Code (NCAC), Title 15A: Department of Environmental Quality, Subchapter 213: Surface Water and Wetland Standards (last amended June 2016). Where no 2B standard exists, the most stringent, applicable standards were selected from the EPA Nationally Recommended Water Quality Criteria for Aquatic Life and Human Health or the North Carolina Protective Values for Surface Waters (current as of September 22, 2017). 2L: groundwater standard per NCAC, Title 15A: Department of Environmental Quality, Subchapter 2L: Groundwater Classifications and Standards (amended April 1, 2013) A: a laboratory data qualifier used to indicate that the relative percent difference value between the primary and secondary column was outside the quality control limits for the parameter, and therefore the result is considered as an estimated concentration BOD: biochemical oxygen demand CAS Number: a unique number assigned by the Chemical Abstract Service (CAS) to all identified parameters COD: chemical oxygen demand Collect Date: the date on which the sample was collected in the field EPA: U.S. Environmental Protection Agency (Method) IMAC: Interim Maximum Allowable Concentration. Analytes that do not have an established 2L standard were compared to the IMAC in accordance with 15A NCAC 02L .0202 (c). J: a laboratory data qualifier used for parameters detected at estimated concentrations above the MDL, but below the MRL Lab Method: the analytical method used to analyze the constituents MDL: method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero mg/L: milligrams per liter MRL: method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method mV: millivolt NA: not analyzed NE: not established nM: nanomoles NTU: Nephelometric Turbidity Units Result: analytical data reported by the laboratory, or field data collected by Anchor QEA Shaded cell indicates a result in exceedance of the 2L standard or IMAC, or greater than or equal to the groundwater protection standards (if no 2L or IMAC exists) and 2B standard, if applicable SU: Standard Unit SVOC: semivolatile organic compound SWS ID: Solid Waste Section Identification Number TOC: total organic carbon U: a laboratory data qualifier used for parameters not detected at concentrations above the MDL *: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per NCAC, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017). Spring 2019 Semiannual Water Quality Monitoring Report Page 5 of 5 Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Figures LEGEND: E3 Site Parcel Boundary SOURCES: 1. Basemap: USGS Topographic Maps - Greens Creek and Whittier 7.5-minute Quadrangles 2. Parcels: Jackson County GIS 0 0 2,000 Feet Publish Date: 2019/06/05, 9:41 AM I User: alesueur Filepath: \\Ashevillel\Asheville\GIS-Projects\JacksonCounty\Maps\2019\SpringWaterQuality\AQ-FigOl-JacksonCounty-SpringWQ-SiteLocationMap.mxd kZANCHOR Figure 1 Q E A Site Location Map Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 LEGEND: NOTE: Sample locations are approximate. Monitoring Well Road Elevation Contour (20 Foot Interval) SOURCES: * Landfill Gas Extraction Well Basemap: NC OneMap 2015 ® Domestic Well Sample Location Property Boundary GIS Contours, Roads, and Parcels: Jackson County Leachate Sample Location and Flow Equalization Tank Surface Water Sample Location Publish Date: 2019/06/05, 9:40 AM I User: alesueur Filepath: \\Ashevillel\Asheville\GIS-Projects\JacksonCounty\Maps\2019\spring WaterQuality\AQ-Fig02-JacksonCounty-SpringWCZSampleLocationMap.mxd n 0 500 Feet j� ANCHOR Figure 2 lam► QEA Anchor QEA of North Carolina, PLLC Site Layout Map Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 \ MW-02 nmAi-nr 2o0o\2O2o —MW--01 (2,073.47)/ 274p 2120 eaGo C�eo MW-03 (2,008.83) N \ MW-04 (1,956.39) WII �pP E� / G MW-05R A',,983'14) y9 00 FAG •o LEGEND: NOTES: 1. Monitoring well locations are approximate. ® Saprolite Monitoring Well — Stream 2. Groundwater elevations and flow direction are updated on a semiannual basis following sample collection events in March and October. ® PWR Monitoring Well — Road 3. Groundwater flow direction is based on groundwater elevations from all Site monitoring wells. Direction is ® Bedrock Monitoring Well Elevation Contour (20-Foot Interval) calculated based on depth to water measured on March 19, 20, and 21, 2019. 4. Last names of property owners are shown in parcels that border the landfill property. Property Boundary (2,008.83) Groundwater Elevation 5. PWR: partially weathered rock (March 19, 20, and 21, 2019) 6. Groundwater elevation in feet (North American Vertical Datum 1988) Publish Date: 2019/06/26, 9:35 AM I User: alesueur Filepath: \\Ashevillel\Asheville\GIS_ProjectsVacksonCounty\Maps\2019\Spring WaterQuality\AQ_Fig03-JacksonCounty-SpringWQ-GroundwaterElevationMap.mxd SOURCES: 1. Elevation contours, roads, and parcels: Jackson County GIS 2. Groundwater elevations: calculated from surveys performed by Davenport & Associates, Inc. (MW-01, MW-02, MW-03, MW-04, and MW-06) and Wes Cole Land Surveying, PA (MW-05R and MW-07) RD 0 0 200 Feet N 0 Zy� ANCHOR Figure 3 QEA—`-�" Generalized Groundwater Flow Direction Anchor QEA of North Carolina, PLLC Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Figure 4 Hydrograph and 1,4-Dichlorobenzene Concentration vs. Time (Monitoring Well MW-01) 20 HE 16 J a1 = 14 0 �a c 12 a 0 v 10 a d N _ a 8 0 0 v 6 G 4 2 I r- r` W 00 M M O O N N M M Ln Ln to to r- r` W co m CD CD CD CD CD CD O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N Q U Q U Q V Q U U Q U Q U U Q U U U Q 0 Q 0 Q 0 Q 0 Q 0 Q 0 Q 0 Q 0 Q 0 Q 0 0 0 2076 2074 2072 G1 2070 ° R a, W i 2068 +; M 3 M _ 3 2066 2064 2062 2060 Notes: Sampling Date 1. 2L Standard = 6 micrograms per liter (µg/L ) 2 "J" indicates result is estimated by laboratory. 3. "<" indicates result is less than method detection limit. O 1,4-Dichlorobenzene 4 Groundwater Elevation 4. Oct 2017 result reported in semivolatile organic compound list. Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Figure 5 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-01) 20 18 16 6 4 2 0 r- r` 00 00 M Cr) O O N N M M Ln Ln l0 LD r- r` 00 CO M O O O O O O O O O O O O O O O O O O O O O O O O O N N N N N N N N N N N N N N N N N N N N N N N N N Q Q U �(Q U Q V 0 Q 0 Q 0 Q Q U 0 �(� U Q Q 0 Q U U Q U �(� 0 Q 0 Q U 0 �(Q Q U 0 Q Q U 0 M U U 0 L M U L U 0 Notes: 1. 2L Standard = 1 microgram per liter (µg/L) Sampling Date 2. "J' indicates result is estimated by laboratory. 3. "U" indicates result is less than method detection limit. 2076 2074 2072 G1 a, 2070 0 R a, W 2068 a, 3 _ 2066 0 W 2064 2062 2060 O Benzene * Groundwater Elevation Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Figure 6 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-OSR) 20 18 16 J 14 0 a 12 L a v 0 10 V a N 8 _ N m 6 4 2 0 N rV rn m 0 0 0 0 0 0 N N N N N N Q U Q V Q V Q 0 Q O Q 0 Notes: 1. 2L Standard = 1 microgram per liter (µg/L) 2. "J" indicates result is estimated by laboratory. 3. "<" indicates result is less than method detection limit. Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 L!1 L( l0 0 0 0 N N N Q 0 Q Sampling Date 1990 1988 1986 1984 a°1, 0 %p 1982 m> a, W L a 1980 0 3 _ 7 1978 0 iGII:� 1974 1972 �0 r` r 00 00 rn 0 0 0 0 0 0 N N rV N N N V fp U (p V (p O � 0 2! O 2� O Benzene s Groundwater Elevation June 2019 Figure 7 Hydrograph and Vinyl Chloride Concentration vs. Time (Monitoring Well MW-0511) 20 18 16 J 14 o +' �a 12 a v c 10 V a 0 8 s u c 6 4 ' 2.5 2 2 F--i F 0 O O O O O O O O O O O CDO O O N N N N N N N N N N N N N N N Q V Q V Q V Q V Q V (0 V (0 V (6 Q O Q O Q O Q O Q O O -2: O 2 Notes: 1. 2L Standard = 0.03 microgram per liter (µg/L) 2. "J' indicates result is estimated by laboratory. 3. "<" indicates result is less than method detection limit. Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 Sampling Date 1990 1988 1986 1984 _ 0 1982 a a W L d 1980 3 3 1978 0 1976 1974 1972 OVinyl Chloride Groundwater Elevation June 2019 Figure 8 Hydrograph and Benzene Concentration vs. Time (Monitoring Well MW-07) 20 18 16 J 14 0 .a c 12 a v _ 0 v 10 a a N W 8 m 6 4 1.7 1.7 1.6 2 1.4 1.4 1.4 1.3 1.1 1.2 0.87 0 1::1 F-I L] -�. [:11:1 El 1:1 � :] 1 N N M M O O O O O O N N N N N N a-U Q U 0-U Q 0 Q 0 Q O Notes: 1. 2L Standard = 1 microgram per liter (µg/L) 2. "J" indicates result is estimated by laboratory. 3. "<" indicates result is less than method detection limit. V IliL(1 L2 l0 lO O O O O O O N N N N N N Q U Q U Q U Q 0 Q 0 Q 0 Sampling Date 1.6 KINIL'RV 1.7 1.5 1.4 1952 + 1950 a 1948 LSO, 0 r R a, LU 1946 a, M 3 _ 3 O L 1944 0 1942 ' I ' ' I ' ' ' 1940 r c2 2 dl O O O O O N N N N N p U p U 6 O 0 OBenzene *GroundwaterElevation Spring 2019 Semiannual Water Quality Monitoring Report Jackson County Closed Municipal Solid Waste Landfill, Permit No. 50-02 June 2019 Appendix A Well Sampling Logs, and Equipment Documentation and Instrument Calibration Data Sheets ANCHOR .�I► QEA Well Sampling Log Date: �a'� �,� Well Name: Project Name: Jackson Dilisboro LF Project Number. C81480-01.01 task 03 Weather. 0A j, CACkL& S50 Sampling Personnel: VV Sample Time: Well Information: Well Depth in Feet (WD): Well Diameter ti h Water Level in Feet (WL): l q Type of Casing: Length of Water Column: feet Screen Int al: (WD) - (WL) = (LWC) Flush Mount Stick -Up One Casing volume: y 15 gallons Comments: (LWC) x (WCV) Three Casing Volumes: �, gallons Tagged bottom Actual Volume Purged: 5 gallons at Well Casing Volumes (WC\0 1" = 0.041 Gal/Ft 2- = 0.17 Gal/Ft) 3" _ 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/R 12" = 5.8 Gal/Ft Purge Method: ailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: ailer-Disp. Bailer -Teflon Dedicated Pump . Whale Pump Grundfos Other. Tempu 015s6h►ed $ Speciflt Gong' .pH (S U)19>IrWdity, Cixidat,on ; Reading : w#loos' °, Time < Purged ; .fit oxygen (iatg/L), _ (!i5/tm report to 0:1 &U. Potential (mAq . �`(NTUJ • '-.. Coirtment#'' 3 4 1 �" fJ S• �% a4' 5 6 7 8 9 10 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius PS/cm: micro-Siemen per centimeter mg/L milligrams per liter W. millivolt NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing: -+� Pad: Lock: Vegetation: Access: Sampling Personnel Signature: A Date. * 19A / l I initial if well information and sampling data has been verified 1 well was tagged after sampling was complete F 'rm 41 7- ANCHOR .7 QEA 4-19-09-01 Well Sampling Log Date: 1 t(�A ) is l Well Name: M.,NAr>/) ] Project Name: Jackson Dillsboro LF Project Number. C81480-01.01 task 03 Weather. 30 C. t "Y1 „ Sampling Personnel: Sample Time: E. Well Information: Well Depth in Feet (WD): tOO : T © — G Well Diameter: ^� 1�1 Water Level in Feet (WL): dx ( -#�-�D[- Type of Casing: Pkf C., Length of Water Column: .2(,q-0,5 feet Screen Interval: �, (/�, (WD) - (WL) = (LWC) Flush Mount Stick, Up One Casing Volume: 3 gallons Comments: (LWC) x (WCV) Three Casing Volumes: 13.3 gallons Tagged bottom Actual Volume Purged: gallons at Well Casing Volumes (WCV) 1" = 0.041 Gal/Ft 2" = 0.17 Gal/ 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft Purge Method: ailer-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer-Dis Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. 0Gallons Tem p Dissolved "$ pecfflcCoiad pH (9 U ): Roduc}ion Pugged 4 �.(°G) ` 01iYgen (Mg/�) t =b {E+S/c+n) t` reportxo 0.1$ U. Potential {mlil tdk �U) .'"' �: ' Comr�en# 2 3 m , _ (9 J-12.� >> 4 .0 0 r-� , (OD . C Y� t 5 r . zio 6 y L-1 7 i CzO 8 ! �. ` 0 Le 9 1 4 'a D ,3 t�,, 044 10 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing:. Pad: ,J%!!� Lock Vegetation:w Access: Sampling Personnel Signature: Date: —V'A' I CA initial if well information and sampling data has been verified MW well was tagged after sampling was complete 7261 ,, ANCHOR .�. QEA 4`�'`� Low -Flow Sampling Log Date: 747JAQ Well Name: LAW-1 Y_-2, Project Name: Jackson Dills = LF Project Number. C81480-01.01 task 03 Location:. Dillsboro, NC Personnel: AW ,A{ -. Weather. ;.J, S VV1', Well Information: Screen Interval: bgs Arrive at Well: t Depth to Water. � �® toc Start Time: Well Diameter. in Sample Time: [Ziiz Pump Intake: •wiy.® ,f-�- toc Finish Sample Time: 1 Z,2_0 Drawdown Set: 9j19_e17 toc Leave Well: 13 Irp Pump Used (circle): Peristaltic Bladder Other (description): Comments: ��A�P%1'h,t` ar epu �i Z30 5'"11, vvi CAaVe - i2.50 Purge Rate: Tagged bottom at T—otal. Purge Volume: Pump Speed: fly© r�.(— w, v+ 4Z,�;, S ' 'J�U Time DTIN (feet) ? Temp - (C)"y. �. ���).. Sp e ficCon& :i�)�< .- pH(Su� nepoit�0.7.. OJ(P _ (m� -5. {���_� b in�Tu� � t�rvtnmevns I13s . ® q io, Ist ss r-5- 3 1,3s t35- 6t9 1' L4 Lq 1-3.3 ,(, 7 re,b. i 1144 3 b.'1 .70 1-;�S L. Lo 2..1 r t' -q% I N3. g.90 4[3 3 ,.7o 207. IOb u 3 13. is , 06 413 • 3 (v 73 `-t 5 . o 1 13•'-J` 9.07 L41 -2- (0.'7�3 22.1, 7 i©a Il 193 3 -ct 7 13. '-t H 3 413 .i 6.75 225 , 7 MG ii 3b. 3,J Ct Lt G, L113, 1 t 23t�. , W :SG, Iq 7 13r T i 1r5 zi G ( 4-- Q-6, , . , i l'ao Z IT, 7 it 4131 ca z Time between recharge during sample collection: Sampling Personnel Signature: Date.. f. Notes: f� Stabilization 3 successive readings, 3 minutes apart within +/- 10% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit +/- 10 mV for ORP 3 J �5 ( fit � ��v Q vvL- from EPA - Low -Flow (Minima( Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) �J Samples are analyzed immediately upon collection, pS: micro-Siemen mv: millivolt 'C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L: milligrams per liter toc: top of casing initial if well information and sampling data has been verified r L I well was tagged after sampling was complete ANCHOR QEA Low -Flow Sampling Log Date: h f 4fil f I el Well Name: NW—;_ 4 Project Name: JaCkSon blllS = LF Location: Dillsboro, NC Personnel: Project Number. C81480-01.01 task 03 Weather. 3 ':y Well Information: Screen Interval: d 5—.i-�O bgs _ Arrive at Well: i0is Depth to Water. toc Start Time: 5 Well Diameter: in Sample Time: f a,r Pump Intake: n- _ toc Finish Sample Time: 1/1 -7 Drawdown Set:, toc Leave Well: Pump Used (circle): Peristaltic Bladder Other (description): Comments: \Wbvo Purge Rate: A,(, y1n, Tagged bottom. at ' ( Total Purge " K4 _ rge Volume: +- Pump Speed: p Time . Diil)I if et) _t T el1-4 ('�' inp rJG ,, t g/L) Specific Coed' iF>S) ,6 Mpor tool (tn i Tui tli 1 _ Cmments=. ij lit-) 3 57 9 `Z 3&-3. 0 f3.L. I'0 4 4. 7S 1 S. � 7, to 1 5.9 l'Llf 5 ' L- 0°"l �Tq-5 5- tom 0 - 14.1 T. y 14L, 66.r z 412 A, 3-7 1 —to S7 24_7S i. ,1 '5- 7-9 q4 1 5 9'2- L111-7 3. Time between recharge during sample collection: Sampling Personnel Signature: ," ,— Date: 3h� Notes: Stabilization 3 successive readings, 3 minutes apart: within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit,- +/- 10 mV for ORP from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. pS: micro-Siemen mv: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L• milligrams per liter toc: top of casing initial if well information and sampling data has been verified well was tagged after sampling was complete_ ANCHOR QEA 4." Well Sampling Log Date: %j��r` '� Well Name: Illl[W Y0.5 F— Project Name: Jackson Dillsboro LF Project Number. C81480-01.01 task 03 Weather. S S 00 yti. Sampling Personnel: e I- a in , 1ti Sample Well Information: Well Depth in Feet (WD): 5, Q Well Diameter: �. y� Water Level in Feet (WL):� Cr Type of Casing: 2 y-( Length of Water Column: 7 01 feet Screen Interval: i!AA- (WD) - (WL) = (LWC) Flush Mount / tick-U One Casing Volume: � 3 gallons Comments: v;� 'Ilcw 1 150 1 D (LWC) x (WCV) a-�.. I ow. Three Casing Volumes: , HID gallons Tagged r bottom at (.. 5 Actual Volume Purged: !� (� gallons Well Casing Volumes (WCV) 1" = 0.041 Gal/Ft =2'=017Gal/F 3" = 0.38 Gal/Ft 4" = 0.66 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.8 Gal/Ft Purge Method: ailer-Disp.l Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Sample Method: Bailer -Di Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other. Oxidation Gallons Temp Dissolved Specific Cond. pH (S.U.) Reduction Turbidity Reading Time Purged (°C) Oxygen (mg/L) (PS/cm) report to 0.1 S.U. Potential (m1) (NTU) Comments 1 ows eko L•S a 3 ogqfic 3 7-1 , Z.O - -3rq ih 5 Cod -"3_ S 7 7.0 1 -7b , 2- 6 0410 3 > 1 , 00 , 7 byAwu 7 8 9 10 Notes: Samples are analyzed immediately upon collection. °C: degrees Celsius pS/cm: micro-Siemen per centimeter mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units S.U.: Standard Units Protective Casing: Pad: Lock Vegetation: Access: Sampling Personnel Signa Date: �.�`�-�/� ;��, ESL •�� � �-.- "-tiet SCAw initial if well information and sampling data has been verified11i well was tagged after sampling was complete ANCHOR a QEA 4L.4-4_.4_� Low -Flow Sampling Log Date: � ('�, � Well Name: KV4'0(a Project Name: JaCkson D'lIM= LF Project Number. C81480-01.01 task 03 Location: Dlllsboro, NC Personnel: u\ UAA IAA N f [,tom Weather Cj� r SVVI rV Well Information: Screen Interval: } { A T_ bgs Arrive at Well: (�� S' Depth to Water. =� r�vl toc Start Time: Oci ] 0 Well Diameter: 1;l'-M in Sample Time: Q Pump Intake: rid�A toc Finish Sample Time: 7©30 Drawdown Set: -7 toc Leave Well: Nf—' Pump Used (circle): Peristaltic Bladder Other (description): Comments: SUA &I ' 10�0 SA-10 LN ,fp i 050 Purge Rate: A, Tagged bottom at: C1 7 -0 2- ( _ Total Purge Volume: �'�4 Pump Speed: Z _b .. Tmet'i5 .. ttiiw ; r { �,(feet� s k 7 Db` , ;.is� �h� Spec [� lodTpH `� p UA T. QRI' ,; � 7uFrbid�r, �9, if7rY11:lent5.�. JA-Al 11 Y.i 3✓ 4 7 .16 4 /i V 31 t V (Ak lij,s ,,- y�c-)W S. --4 —L 1 4.5N L(-S ZI A I1c1: Vr 13 47- _J� 01.0 S•" 3i '.� -7 5-`3 7 S 3 2 `Z �, Time between recharge during sample collection: [Sampling Personnel Signature: /"� Date:" Notes: • v Stabilization 3 successive readings, 3 minutes apart within +/- 10% Do and turbidity, +/- 3% Conductivity, +/- 0.1 pH unit +/- 10 mV (or ORP from EPA - Low -Row (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. NS: micro-Siemen mV: millivolt °C: degrees Celsius NTU: nephelometric turbidity units bgs: below ground surface ORP: oxidation reduction potential DO: dissolved oxygen S.U.: standard units mg/L• milligrams per liter toc: top of casing initial if well information and sampling data has been verified well was tagged after sampling was complete ANCHOR. Low -Flow Sampling Log Date: �5 iq Well Name: "W_`6 �1 Project Name: Jackson Dillsboro LF Project Number: C81480-01.01 task 03 Location: Dillsboro, NC Personnel: hivy (k- �' V/ Weather: 0 Well Information: Screen Interval: 5 bgs Arrive at Well: Depth to Water: All �r=) CA t C; toc StartTime: `C Well Diameter: -y-k in Sample Time: Pump Intake: e— fir'' toc Finish Sample Time: 1300 Drawdown Set: �. �j toc Leave Well: Pump Used (circle): Peristaltic Gddebother (description): Comments: V — Purge Rate: ( � k%, � yyt i to Tagged bottom at: CA , I . Total Purge Volume: /Q.31 Pump Speed: - "S•- Time DTWFTe!m (feet) DO (mg/L) Specific Cond. (NS) pH (S.U.) report to 0.1. ORP (m1) Turbidity (NTU) Comments j. ` W90 20 4 2 12l 7 3 t • $ 13 ifal 7 27 . �2,2 0 1.4 0 G . b . 1. 7 3-0 1 to ` l 3 I x `2.Q 3 ' . U L, IL4 . 2 a 8 3 732, 6.09 t6l .14 2-1 I2 i A4 2 011 _733 (-01 11VU- • y n r 73- �•�� l• . 1131 114 - 145 1. if 1 Time between recharge during sample collection: Z44letSampling Personnel Signature: Date: Notes: Stabilization 3 successive readings, 3 minutes apart: w S "c, , i CCkc_ within +/- 10% DO and turbidity, +/- 3% Conductivity,' +/- 0.7 pH unit; +/- 70 mV for ORP from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010) Samples are analyzed immediately upon collection. pS: micro-Siemen 'C: degrees Celsius bgs: below ground surface DO: dissolved oxygen mg/L: milligrams per liter mv: millivolt NTU: nephelometric turbidity units ORP: oxidation reduction potential S.U.: standard units toc: top of casing initial if well information and sampling data has been verified / \V well was tagged after sampling was complete 1� ANCHOR ClEA400&009.00 46-6009.10, Surface Water Sampling Log Project Name: Jackson Dillsboro LF Date: qIL4 Project Number. C81480-01.01 task 03 Weather. Sampling Personnel: Sample Name: Comments: ArAAin 4-111� n A 4-N-A71. /'IT Sample MeOwd: .e ��VW) I o- DGrab Syringe Pump 'A 44 25.L '4. G M ml. Plastic 250 mL Plastic 125 ml. Plastic 40 mL Glass 1 L Glass Other Vegetation: Sampling Personnel Signature: Notes: Samples are analyzed immediately upon collection. *0 degrees Celsius pS/cm: micro-Slemen per cubic centimeter mg/L milligrams per liter MV. mitlivolt NTU nephelometric turbidity units S.U.: standard units Sailer-Disp. Other likotell" faw) qI0, Access: 5 Date: le I A vtj Method Reference: - Temperature: SM 2550 B-2010 Specific conductivity r EPA Method 120.1, Rev. 1982 DO: SM 45W 0 G-2011 pH: SM 4500-H* 8-2011 Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Page 1 of 1 ANCHOR CIEA e..c.09.oe Surface Water Sampling Log Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: Jackson DIIM= LF Project Number. C81480-01.01 task 03 Sampling Personnel: G,A(Avow � f)r 1) A Sample Name: s , o Comments:- CI L (- Date: weather. Sample Method: Grab Syringe Pump Bailer-Disp. Other: Time Temp (•C) Dissolved Oxygen (mg/L) Specific Cond. (pS/cm) pH (S.U.) report to 0.1 S.U. Oiddlation Reduction Potential (m1) Turbidity (NTU) Comments � 0,i! 9A 12- � Sampling Container Number of Containers Requested Analysis 300 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass tL t 1 L Glass Other Vegetation: Sampling Personnel Signature: Notes: — `— Samples are analyzed immediately upon collection, "C: degrees Celsius pS/cm: micro-Siemen per cubic centimeter mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Access: Md— Date: Method Reference: Temperature: SM 2550 B-2010 Speck conductivity: EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 PH: SM 4500-H' B-2011 Page 1 of 1 ANCHOR 96..v Sampling Log Anchor QFA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name:'SQ fs%m Dslwo JI/o ;LF- Dater) i Project Number. C��oV-��,�� 7y Weather. Sampling Personnel: Sample Name: Comments: Sample Method: Grab Syringe Pump Bailer-Disp. Other: Dissolved Oxidation Temp Specific Cond. Oxygen pH (S.U.) Reduction Turbidity Time VC) (PS) (mg/L) reportto 0.1 S.U. Potential (mV) (NTU) Comments 1435 01 3(o12 L ,q,5 YO 5 Sampling Container Number of Containers Requested Analysis 500 mL Plastic 250 mL Plastic 125 mL Plastic 40 mL Glass 1 L Glass Other Vegetation: Access: f a Sampling Personnel Signature: 1 Date: Notes: Method Reference: pS: micro-Siemen per cubic centimeter Temperature: SM 2550 B-2010 °C: degrees Celsius Specific conductivity. EPA Method 120.1, Rev. 1982 mg/L: milligrams per liter DO: SM 4500 O G-2011 mV: millivolt pH: SM 4500-H' B-2011 NTU: nephelometric turbidity units S.U.: standard units Page 1 of 1 ANCHOR QEA 404-46.0 Samplinq Loq Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 Project Name: 5Q(J�i� �"�`S Project Number i., e�LS���,�� { Sampling Personnel: M � Sample Name: — 4 l Comments:y"F&,�Q�� Date: Weather. 1Iq u o Sample Method: Grab Syringe [ Pump Bailer-DiSp. Other. �. Time Temp CC) _ Specific Card. (IS) err Oxygen (mg/L) y < pH (S.O.) report to 0. t S. U. .. Roduco" Potential (mv) Turbidity (NTU) Comments Sampling Contain_ Number aittarnes ems, 't. _. Requested Analysis 500 mL Plastic 250 mi. Plastic 125 mi. Plastic 40 mL Glass ' 1 L Glass Other Vegetation: Access: 141�k- CA Sampling Personnel Signature:. Notes: NS: micro-Siemen per cubic centimeter °C: degrees Celsius mg/L: milligrams per liter mV: millivolt NTU: nephelometric turbidity units S.U.: standard units Date: 3 Vt) � 9 Method Reference: Temperature: SM 2550 B-2010 Specific conductivity. EPA Method 120.1, Rev. 1982 DO: SM 4500 O G-2011 pH:SM 4500-H' B-2011 Page 1 of 1 ANCHOR Anchor QEA of North Carolina, PLLC QEA e.c_v 231 Haywood Street Asheville, North Carolina 28801 Equipment Documentation and Instrument Calibration Data Sheet CALIBRATION DOCUMENTATION Project Name:as� Person Conducting Calibration: Project Number. _ Date of Calibration: "C Project Location: D i JJS6DV6NCi Date of Field Measurements: EQUiPMeNT DOCUMENTATION Equipment or meters used to take measurements (e.g.; water level meters, survey equipment): Equipment °fie,"-"-', ::Spr;v'1.. iieriber:. " . : Br'aii d. bateesf Use 150-ft Water Level 26154 Solinist 150-ft Water Level 22754 Solinist 1504 Water Level 150 Testwell 150-ft Drawdown MP30-1527 QED Other Select Turbidimeter. Hach 21000 (s/n 151006045207) HF Scientific MicroTPW (s/n 200601045) Instrument Reading Instrum-rtt Reading (Hach 2100Q) (HF SrIerrtifir Micro.v Pw) Calibration 20 7i r ]f3UFNT13 800 N7U 7;000.rt i t9 117:4 iiTU Expiration Date; � � z+. Cali a (17 Cal: r I Cal: 4,.A 2 Cal: Cal: Cal: �!. Ilme: 00� Time, Time: Time: Time: Verification (10 NTU): oy /^ Vercation: Verification: Verb 4.' A Time: ., 10 NTU Cal. Expiration Date: Time: Time: Time: 6' sIl �t YS1 ta10e6406.1 Plus MoltiparaMeter. Meter (s/n 1861018; instrument Readlnc s - Dissolved Oxygen Initial: �/a i L Cal: I ©�, t (� mmHg: v J temperature (°C): Time: PH 7 S.U. Initial: pHmV: Cal: pHmV: Time: report to 0.1 S.U. PH 4 S.U. report to 0.1 S.U. Initial:/� q i Vk pHmV: �" Cal.' . �D pHmV: . -- Time pH 10 S.U. Initial: pHmV: Cal: pHmV: Time: report to0.IS. U. �_ � ��� 53 QC* pH.7 S.U. report to 0.1 S.U. AM ime: M!eas: Q Mid Day Time: Check: PM Time: Spe//cc.,. Cond. Initial:: Cal: Time: i V) pS/cm** ( dd L— / 1 CIO 6 nq QC*: AM Time: Meas: 7�/�V Mid Day Time: 1200 pS/cm .ORN— 1 a U ^`' Initia�l:�j Cal:/ _ Temperature (°C): ORP�`0 mV 96 t,r a(oq, x v rI0 PM Time: I Check: Calibration Expiration Date NA V� -at (01 Dl �a'p v51 A0i Signature: Date: o 3 h ot Notes: -� 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range, 3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 16, DO, ORR QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. S. * Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours: 6. ** Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location. Method Reference:' Temperature: SM 2550 B-2070 I Specific conductivity: EPA Method 120.7, Rev. 1982 1 DO: SM 4500 O G-2077 I pH: SM 4500-H+ B-2077 Page 1 of 1 Anchor QEA of North Carolina, PLLC .say ANCHOR QEA Equipment Documentation and Instrument Calibration Data Sheet 231 Haywood Street Asheville, North Carolina 28801 CALIBRATION DOCUMENTATION Project Name: Person Conducting Calibration: —JO-1- ON Project Number: Date of Calibration: 3VZ0/1 y Project Location: fV----Bb` : u ?csoo (f�Vq- - Date of Field Measurements: 3/zo// y Calibration Standards Instrument Reading 'Z(16 (HF Scienpq MicroTPW) {� / (� V d c=, Expiration Date 4.0Z. NTU NTU 114WNTU l �� Cal: Cal- Cal: 0 Cal: 1 Time:: pJ� Time.. ;1A��� me� I Time: �S © Time: c� sae— T:—r- YSI ProPlus Instrument Readings Calibration Expiration Date Dissolved Oxygen Initial: i O �r� l Cal: pHmV: mmH : Cal: r /1 `g Time: pHmV: Time: I V pHmV: Time: �L pHmV: Tim NA 02-1- (/ / C) ( 7 pH 7 S.U. report to 0.1 S.U. Initial: —7 T� 7`- pH 4 S.U. report to0.1 S.U. Initial: c� pHmV: Cal%•� �1 �,drJ73 pH 10 S.U. report to 0.7 S. U. Initial: pHmV: Mess, ! (P Cal: l pH 7 S.U. Tirne_Q� report to 0.1 S.U. 0 Spec. Cond. Initial: PS/Cm Cal: /� rrf�� l V V 0 Time: QC: NS/cml� Time: y `7 Mixed date: I L( L4o 1 Meas: p /1 q ! U Cal: C Time�� J [®RP my Initial:, I l Signature- . Date: Notes: r 1. Electronic equipment calibrated actor g to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3.Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated. Page 1 of 1 150-ft Water Level 26154 Solinist 150-ft Water Level 22754 Solinist 150-ft�WaterLevel 150 Testweil 15D ft Drawdown MP30 1527 QED . Other Select Turbidimeter. Hach 2100Q (s%n 151606045267) HF Scientific MicroTPW (s/n 2D0601 a ANCHOR Equipment Documentation and Instrument Calibration Data Sheet CALIBRATION DOCUMENTATION Project Name: ��� LF Person Conducting Calibration: Project Number. Date of Calibration: Project Location: NI, Date of Field Measurements: EQUIPMENT DOCUMENTATION' Equipment or meters used to take measurements (e.g.; water level meters, survey equipment): I5) Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 �. e,. - ..a C.ar Cal: Cal- I�r Tim Timg: ! lsl Tim : C v Time: Time:. Time:. me: VarFHcetivn (10 NTU): Verification: verification: Verbcation: Time: 10 NTU Cal. tion Date: Tr.' Time: Time Dissolved Oxygen Initial: Cal: J11 mmHg: Temperature (°C): � ,� Time: � s NA pH 7 S.U. Inial: �, pHmV: Cal: pHmV: Time report toais.U. pH 4 S.U. report to a i S.U. Initi l: -7 � Q � pHmV: ✓ Cal � pHmV: � Time: � UJVL nn jt pH 105.U. report to 0.1 S U. Initial: - rr11 i pHmV: Time - '. ;. . QC* pH,7 S.U. report to0.7.S.U. AM Time: �0 Meas- O Mid Day Time: - Check: `-- PM Time: Check r'� tt'J "Wb Spec.Cond. ' Initial: OMB Cal: Time: _ ?i; "..Fie±: 7VIt--; VV Qe*.. AM Time. Meeas: Mid Day Time: Check: .��'.: `s `-•7:a' �:ac:_a+i...c' PMTime: 1-Y';.y,...; Check Oq twtl_ ORP mV Initial �l G Cal: Temperature (C): Time x� a R" ; ;:_; c Signature: Date: 3tbn Notes: 1. Electronic equipment calibrated according to the manufacturer's operation manual. 2. Specific Conductivity should be calibrated according to values representative of historic range. 3. Order of Calibration isas follows: Specific Conductivity, pH 7, pH 4, pH 16, DO, ORP,.QC checks. 4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibreted. 5. *Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours: . 6.'* Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which Is closest to historical readings from the project location. Method Reference: Temperature: SM 2550 B-2070 I Specific conductivity: EPA Method 720.7, Rev. 19a2 I DO: SM 4500 O G-2077 I pH: SM 4500-H+ B-2017 Page 1 of 1 Appendix B Reports of Laboratory Analysis, Chain -of -Custody Documentation, and Certificates of Analysis LP R I S M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Anchor QEA of North Carolina, PLLC Brian Gant 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Lab Submittal Date: 03/20/2019 Prism Work Order: 9030325 Case Narrative 4/8/19 15:36 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: TOC analysis was subcontracted to GCAL. Laboratory report is attached. Prism Summary of Detections does not include subcontracted data. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. )� �_ a_-1��_ 6(_- &I Robbi A. Jones Reviewed By Robbi A. Jones President/Project Manager President/Project Manager Data Qualifiers Key Reference: A Probable laboratory contamination. D RPD value outside of the control limits. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). L1 LCS recovery outside of the QC limits. LCSD recovery within the limits. No further action taken. BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 42 Sample Receipt Summary R I IS M Full -Service Analytical R Environmental Solutions 04/08/2019 &GIE LABORATORIES, INC. Prism Work Order: 9030325 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-04 9030325-01 Water 03/19/19 10:57 03/20/19 8:40 MW-07 9030325-02 Water 03/19/19 12:35 03/20/19 8:40 SW-01 9030325-03 Water 03/19/19 14:15 03/20/19 8:40 LT-01 9030325-04 Water 03/19/19 14:35 03/20/19 8:40 TB-20190319 9030325-05 Water 03/19/19 0:00 03/20/19 8:40 Samples were received in good condition at 3.3 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 42 /r P R I S M Full -Service Analytical s Environmental Solutions LABORATOR Summary of Detections 04/08/201S Prism Work Order: 9030325 Prism ID Client ID Parameter Method Result Units 9030325-01 MW-04 Chloride 9056A 27000 ug/L 9030325-01 MW-04 Nitrate as N 9056A 11000 ug/L 9030325-01 MW-04 Sulfate 9056A 63000 ug/L 9030325-01 MW-04 Biochemical Oxygen Demand SM5210 B 3200 ug/L 9030325-01 MW-04 Sulfide SM4500-S F 1000 J ug/L 9030325-01 MW-04 Total Alkalinity to pH 4.5 SM2320 B 84000 ug/L 9030325-01 MW-04 Mercury 7470A 0.036 J ug/L 9030325-01 MW-04 Antimony 6020B 0.21 J ug/L 9030325-01 MW-04 Arsenic 6020B 0.30 J ug/L 9030325-01 MW-04 Barium 6020B 98 ug/L 9030325-01 MW-04 Beryllium 6020B 0.065 J ug/L 9030325-01 MW-04 Cadmium 6020B 0.18 J ug/L 9030325-01 MW-04 Chromium 6020B 0.35 J ug/L 9030325-01 MW-04 Cobalt 6020B 1.4 ug/L 9030325-01 MW-04 Copper 6020B 0.38 J ug/L 9030325-01 MW-04 Nickel 6020B 2.5 ug/L 9030325-01 MW-04 Selenium 6020B 0.64 J ug/L 9030325-01 MW-04 Silver 6020E 0.073 .1 ug/L 9030325-01 MW-04 Thallium 6020B 0.15 J ug/L 9030325-01 MW-04 Zinc 6020B 16 ug/L 9030325-01 MW-04 1,4-Dichlorobenzene 8260B 1.0 ug/L 9030325-01 MW-04 Acetone 8260B 6.3 ug/L 9030325-01 MW-04 Chlorobenzene 8260B 0.70 ug/L 9030325-01 MW-04 cis-1,2-Dichloroethylene 8260B 0.44 J ug/L 9030325-01 MW-04 m,p-Xylenes 8260E 0.35 .1 ug/L 9030325-01 MW-04 Xylenes, total 8260B 0.35 J ug/L 9030325-01 MW-04 1,4-Dioxane 8260E SIM 3.5 ug/L 9030325-02 MW-07 Chloride 9056A 78000 ug/L 9030325-02 MW-07 Nitrate as N 9056A 65 J ug/L 9030325-02 MW-07 Sulfate 9056A 22000 ug/L 9030325-02 MW-07 Biochemical Oxygen Demand SM5210 B 240 J ug/L 9030325-02 MW-07 Sulfide SM4500-S F 1800 J ug/L 9030325-02 MW-07 Total Alkalinity to pH 4.5 SM2320 B 250000 ug/L 9030325-02 MW-07 Arsenic 6020B 0.23 J ug/L 9030325-02 MW-07 Barium 6020B 470 ug/L 9030325-02 MW-07 Cadmium 6020B 0.096 J ug/L 9030325-02 MW-07 Chromium 6020B 1.2 J ug/L 9030325-02 MW-07 Cobalt 6020B 1.3 ug/L 9030325-02 MW-07 Copper 6020B 0.69 J ug/L 9030325-02 MW-07 Lead 6020B 0.28 J ug/L 9030325-02 MW-07 Nickel 6020B 8.3 ug/L 9030325-02 MW-07 Thallium 6020E 0.12 .1 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 42 /P R I S Full -Service Analytical s Environmental Solutions � LABORATORIES, INC. Summary of Detections 04/08/201S Prism Work Order: 9030325 Prism ID Client ID Parameter Method Result Units 9030325-02 MW-07 Vanadium 6020B 0.91 J ug/L 9030325-02 MW-07 Zinc 6020B 15 ug/L 9030325-02 MW-07 1,2-Dichlorobenzene 8260B 0.33 J ug/L 9030325-02 MW-07 1,4-Dichlorobenzene 8260B 4.5 ug/L 9030325-02 MW-07 Acetone 8260B 6.3 ug/L 9030325-02 MW-07 Benzene 8260B 1.4 ug/L 9030325-02 MW-07 Chlorobenzene 8260B 4.8 ug/L 9030325-02 MW-07 cis-1,2-Dichloroethylene 8260B 2.3 ug/L 9030325-02 MW-07 m,p-Xylenes 8260B 0.70 J ug/L 9030325-02 MW-07 o-Xylene 8260B 0.26 J ug/L 9030325-02 MW-07 Xylenes, total 8260B 0.96 J ug/L 9030325-02 MW-07 1,4-Dioxane 8260B SIM 18 ug/L 9030325-03 SW-01 Hardness SM2340 C 2000 J ug/L 9030325-03 SW-01 Arsenic 6020B 0.26 J ug/L 9030325-03 SW-01 Barium 6020B 14 ug/L 9030325-03 SW-01 Chromium 6020B 1.0 J ug/L 9030325-03 SW-01 Cobalt 6020B 0.24 J ug/L 9030325-03 SW-01 Copper 6020B 15 ug/L 9030325-03 SW-01 Lead 6020E 0.40 J ug/L 9030325-03 SW-01 Nickel 6020B 15 ug/L 9030325-03 SW-01 Vanadium 6020B 0.50 J ug/L 9030325-03 SW-01 Zinc 6020B 23 ug/L 9030325-03 sW-01 Acetone 8260B 6.3 ug/L 9030325-04 LT-01 1,4-Dichlorobenzene 8260B 4.2 ug/L 9030325-04 LT-01 Acetone 8260B 7.7 ug/L 9030325-04 LT-01 Benzene 8260B 1.9 ug/L 9030325-04 LT-01 Chlorobenzene 8260B 2.7 ug/L 9030325-04 LT-01 Ethylbenzene 8260B 0.45 J ug/L 9030325-04 LT-01 m,p-Xylenes 8260B 0.55 J ug/L 9030325-04 LT-01 o-Xylene 8260B 0.72 ug/L 9030325-04 LT-01 Tetrahydrofuran 8260B 110 ug/L 9030325-04 LT-01 Toluene 8260B 0.53 ug/L 9030325-04 LT-01 Xylenes, total 8260B 1.3 J ug/L 9030325-04 LT-01 1,4-Dioxane 8260E SIM 51 ug/L 9030325-05 TB-20190319 Methylene Chloride 8260B 0.64 A, J ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 42 PRISM Laboratory Report Full -Service Analytical & Environmental Solutions 04/08/2019 LABORATORIES, INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: MW-04 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-01 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 10:57 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 27000 ug/L NE 1000 120 1 9056A 3/20/19 18:19 BMS P9C0398 Nitrate as N 11000 ug/L 10000 100 41 1 9056A 3/20/19 18:19 BMS P9C0398 Sulfate 63000 ug/L 250000 2000 490 1 9056A 3/20/19 18:19 BMS P9C0398 General Chemistry Parameters Biochemical Oxygen Demand 3200 ug/L NE 2000 200 1 SM5210 B 3/20/19 16:55 CBM P9C0484 Chemical Oxygen Demand <17000 ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron <46 ug/L NE 200 46 1 SM3500-Fe D 3/20/19 15:02 BMS P9C0409 Sulfide 1000 J ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 84000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury 0.036 J ug/L 0.2 0.20 0.036 1 7470A 3/26/19 12:47 MMR P9C0474 Antimony 0.21 J ug/L 6 1.0 0.19 1 6020B 3/28/19 15:47 JAB P9C0451 Arsenic 0.30 J ug/L 10 1.0 0.031 1 6020B 3/28/19 15:47 JAB P9C0451 Barium 98 ug/L 100 5.0 0.97 1 6020B 3/28/19 15:47 JAB P9C0451 Beryllium 0.065 J ug/L 1 1.0 0.057 1 6020B 3/28/19 15:47 JAB P9C0451 Cadmium 0.18 J ug/L 1 1.0 0.078 1 6020B 3/28/19 15:47 JAB P9C0451 Chromium 0.35 J ug/L 10 2.0 0.19 1 6020B 3/28/19 15:47 JAB P9C0451 Cobalt 1.4 ug/L 10 1.0 0.0071 1 6020B 3/28/19 15:47 JAB P9C0451 Copper 0.38 J ug/L 10 5.0 0.22 1 6020B 3/28/19 15:47 JAB P9C0451 Lead <0.093 ug/L 10 1.0 0.093 1 6020B 3/28/19 15:47 JAB P9C0451 Nickel 2.5 ug/L 50 2.0 0.85 1 6020B 3/28/19 15:47 JAB P9C0451 Selenium 0.64 J ug/L 10 5.0 0.63 1 6020B 3/28/19 15:47 JAB P9C0451 Silver 0.073 J ug/L 10 5.0 0.063 1 6020B 3/28/19 15:47 JAB P9C0451 Thallium 0.15 J ug/L 5.5 1.0 0.099 1 6020B 3/28/19 15:47 JAB P9C0451 Vanadium <0.10 ug/L 25 1.0 0.10 1 6020B 3/28/19 15:47 JAB P9C0451 Zinc 16 ug/L 10 10 2.8 1 6020B 3/28/19 15:47 JAB P9C0451 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/22/19 16:09 KDM P9C0443 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 16:09 KDM P9C0443 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/22/19 16:09 KDM P9C0443 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 16:09 KDM P9C0443 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 16:09 KDM P9C0443 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 16:09 KDM P9C0443 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/22/19 16:09 KDM P9C0443 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/22/19 16:09 KDM P9C0443 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/22/19 16:09 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 42 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/08/2019 Client Sample ID: MW-04 Prism Sample ID: 9030325-01 Prism Work Order: 9030325 Time Collected: 03/19/19 10:57 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 16:09 KDM P9C0443 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 16:09 KDM P9C0443 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 16:09 KDM P9C0443 1,4-Dichlorobenzene 1.0 ug/L 1 0.50 0.050 1 8260B 3/22/19 16:09 KDM P9C0443 Acetone 6.3 ug/L 100 5.0 0.31 1 8260B 3/22/19 16:09 KDM P9C0443 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/22/19 16:09 KDM P9C0443 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/22/19 16:09 KDM P9C0443 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/22/19 16:09 KDM P9C0443 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 16:09 KDM P9C0443 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/22/19 16:09 KDM P9C0443 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/22/19 16:09 KDM P9C0443 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/22/19 16:09 KDM P9C0443 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 16:09 KDM P9C0443 Chlorobenzene 0.70 ug/L 3 0.50 0.062 1 8260B 3/22/19 16:09 KDM P9C0443 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/22/19 16:09 KDM P9C0443 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 16:09 KDM P9C0443 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 16:09 KDM P9C0443 cis-1,2-Dichloroethylene 0.44 j ug/L 5 0.50 0.056 1 8260B 3/22/19 16:09 KDM P9C0443 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 16:09 KDM P9C0443 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/22/19 16:09 KDM P9C0443 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/22/19 16:09 KDM P9C0443 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 16:09 KDM P9C0443 m,p-Xylenes 0.35 j ug/L NE 1.0 0.12 1 8260B 3/22/19 16:09 KDM P9C0443 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/22/19 16:09 KDM P9C0443 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/22/19 16:09 KDM P9C0443 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/22/19 16:09 KDM P9C0443 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/22/19 16:09 KDM P9C0443 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/22/19 16:09 KDM P9C0443 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/22/19 16:09 KDM P9C0443 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/22/19 16:09 KDM P9C0443 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/22/19 16:09 KDM P9C0443 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/22/19 16:09 KDM P9C0443 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/22/19 16:09 KDM P9C0443 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/22/19 16:09 KDM P9C0443 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/22/19 16:09 KDM P9C0443 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/22/19 16:09 KDM P9C0443 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/22/19 16:09 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 42 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/08/2019 Client Sample ID: MW-04 Prism Sample ID: 9030325-01 Prism Work Order: 9030325 Time Collected: 03/19/19 10:57 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 16:09 KDM P9C0443 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/22/19 16:09 KDM P9C0443 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/22/19 16:09 KDM P9C0443 Xylenes, total 0.35 J ug/L 5 1.5 0.15 1 8260B 3/22/19 16:09 KDM P9C0443 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 96 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 3.5 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 13:13 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 42 Laboratory Report Full -Service P R S M Analytical & Environmental LABORATORIES INC. Solutions 04/08/2019 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: MW-07 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-02 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 12:35 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 78000 ug/L NE 1000 120 1 9056A 3/20/19 18:35 BMS P9C0398 Nitrate as N 65 J ug/L 10000 100 41 1 9056A 3/20/19 18:35 BMS P9C0398 Sulfate 22000 ug/L 250000 2000 490 1 9056A 3/20/19 18:35 BMS P9C0398 General Chemistry Parameters Biochemical Oxygen Demand 240 J ug/L NE 2000 200 1 SM5210 B 3/20/19 16:55 CBM P9C0484 Chemical Oxygen Demand <17000 ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron <46 ug/L NE 200 46 1 SM3500-Fe D 3/20/19 15:02 BMS P9C0409 Sulfide 1800 J ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 250000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury <0.036 ug/L 0.2 0.20 0.036 1 7470A 3/26/19 12:51 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 16:06 JAB P9C0451 Arsenic 0.23 J ug/L 10 1.0 0.031 1 6020B 3/28/19 16:06 JAB P9C0451 Barium 470 ug/L 100 5.0 0.97 1 6020B 3/28/19 16:06 JAB P9C0451 Beryllium <0.057 ug/L 1 1.0 0.057 1 6020B 3/28/19 16:06 JAB P9C0451 Cadmium 0.096 J ug/L 1 1.0 0.078 1 6020B 3/28/19 16:06 JAB P9C0451 Chromium 1.2 J ug/L 10 2.0 0.19 1 6020B 3/28/19 16:06 JAB P9C0451 Cobalt 1.3 ug/L 10 1.0 0.0071 1 6020B 3/28/19 16:06 JAB P9C0451 Copper 0.69 J ug/L 10 5.0 0.22 1 6020B 3/28/19 16:06 JAB P9C0451 Lead 0.28 J ug/L 10 1.0 0.093 1 6020B 3/28/19 16:06 JAB P9C0451 Nickel 8.3 ug/L 50 2.0 0.85 1 6020B 3/28/19 16:06 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 16:06 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 16:06 JAB P9C0451 Thallium 0.12 J ug/L 5.5 1.0 0.099 1 6020B 3/28/19 16:06 JAB P9C0451 Vanadium 0.91 J ug/L 25 1.0 0.10 1 6020B 3/28/19 16:06 JAB P9C0451 Zinc 15 ug/L 10 10 2.8 1 6020B 3/28/19 16:06 JAB P9C0451 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/22/19 16:43 KDM P9C0443 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 16:43 KDM P9C0443 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/22/19 16:43 KDM P9C0443 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 16:43 KDM P9C0443 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 16:43 KDM P9C0443 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 16:43 KDM P9C0443 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/22/19 16:43 KDM P9C0443 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/22/19 16:43 KDM P9C0443 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/22/19 16:43 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 42 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/08/2019 Client Sample ID: MW-07 Prism Sample ID: 9030325-02 Prism Work Order: 9030325 Time Collected: 03/19/19 12:35 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene 0.33 J ug/L 5 0.50 0.076 1 8260B 3/22/19 16:43 KDM P9C0443 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 16:43 KDM P9C0443 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 16:43 KDM P9C0443 1,4-Dichlorobenzene 4.5 ug/L 1 0.50 0.050 1 8260B 3/22/19 16:43 KDM P9C0443 Acetone 6.3 ug/L 100 5.0 0.31 1 8260B 3/22/19 16:43 KDM P9C0443 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/22/19 16:43 KDM P9C0443 Benzene 1.4 ug/L 1 0.50 0.048 1 8260B 3/22/19 16:43 KDM P9C0443 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/22/19 16:43 KDM P9C0443 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 16:43 KDM P9C0443 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/22/19 16:43 KDM P9C0443 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/22/19 16:43 KDM P9C0443 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/22/19 16:43 KDM P9C0443 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 16:43 KDM P9C0443 Chlorobenzene 4.8 ug/L 3 0.50 0.062 1 8260B 3/22/19 16:43 KDM P9C0443 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/22/19 16:43 KDM P9C0443 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 16:43 KDM P9C0443 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 16:43 KDM P9C0443 cis-1,2-Dichloroethylene 2.3 ug/L 5 0.50 0.056 1 8260B 3/22/19 16:43 KDM P9C0443 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 16:43 KDM P9C0443 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/22/19 16:43 KDM P9C0443 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/22/19 16:43 KDM P9C0443 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 16:43 KDM P9C0443 m,p-Xylenes 0.70 J ug/L NE 1.0 0.12 1 8260B 3/22/19 16:43 KDM P9C0443 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/22/19 16:43 KDM P9C0443 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/22/19 16:43 KDM P9C0443 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/22/19 16:43 KDM P9C0443 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/22/19 16:43 KDM P9C0443 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/22/19 16:43 KDM P9C0443 o-Xylene 0.26 J ug/L NE 0.50 0.044 1 8260B 3/22/19 16:43 KDM P9C0443 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/22/19 16:43 KDM P9C0443 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/22/19 16:43 KDM P9C0443 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/22/19 16:43 KDM P9C0443 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/22/19 16:43 KDM P9C0443 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/22/19 16:43 KDM P9C0443 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/22/19 16:43 KDM P9C0443 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/22/19 16:43 KDM P9C0443 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/22/19 16:43 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 42 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/08/2019 Client Sample ID: MW-07 Prism Sample ID: 9030325-02 Prism Work Order: 9030325 Time Collected: 03/19/19 12:35 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 16:43 KDM P9C0443 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/22/19 16:43 KDM P9C0443 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/22/19 16:43 KDM P9C0443 Xylenes, total 0.96 J ug/L 5 1.5 0.15 1 8260B 3/22/19 16:43 KDM P9C0443 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 106 % 75-129 Toluene-d8 97 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 18 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 13:39 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 42 Laboratory Report Full -Service P R S M Analytical & Environmental LABORATORIES INC. Solutions 04/08/2019 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: SW-01 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-03 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 14:15 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 2000 J ug/L 5000 570 1 SM2340 C 3/27/19 10:29 BMS P9C0520 Total Metals Mercury <0.036 ug/L 0.2 0.20 0.036 1 7470A 3/26/19 12:55 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 16:12 JAB P9C0451 Arsenic 0.26 J ug/L 10 1.0 0.031 1 6020B 3/28/19 16:12 JAB P9C0451 Barium 14 ug/L 100 5.0 0.97 1 6020B 3/28/19 16:12 JAB P9C0451 Beryllium <0.057 ug/L 1 1.0 0.057 1 6020B 3/28/19 16:12 JAB P9C0451 Cadmium <0.078 ug/L 1 1.0 0.078 1 6020B 3/28/19 16:12 JAB P9C0451 Chromium 1.0 J ug/L 10 2.0 0.19 1 6020B 3/28/19 16:12 JAB P9C0451 Cobalt 0.24 J ug/L 10 1.0 0.0071 1 6020B 3/28/19 16:12 JAB P9C0451 Copper 15 ug/L 10 5.0 0.22 1 6020B 3/28/19 16:12 JAB P9C0451 Lead 0.40 J ug/L 10 1.0 0.093 1 6020B 3/28/19 16:12 JAB P9C0451 Nickel 15 ug/L 50 2.0 0.85 1 6020B 3/28/19 16:12 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 16:12 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 16:12 JAB P9C0451 Thallium <0.099 ug/L 5.5 1.0 0.099 1 6020B 3/28/19 16:12 JAB P9C0451 Vanadium 0.50 J ug/L 25 1.0 0.10 1 6020B 3/28/19 16:12 JAB P9C0451 Zinc 23 ug/L 10 10 2.8 1 6020B 3/28/19 16:12 JAB P9C0451 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/22/19 17:17 KDM P9C0443 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 17:17 KDM P9C0443 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/22/19 17:17 KDM P9C0443 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 17:17 KDM P9C0443 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 17:17 KDM P9C0443 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 17:17 KDM P9C0443 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/22/19 17:17 KDM P9C0443 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/22/19 17:17 KDM P9C0443 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/22/19 17:17 KDM P9C0443 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 17:17 KDM P9C0443 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 17:17 KDM P9C0443 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 17:17 KDM P9C0443 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/22/19 17:17 KDM P9C0443 Acetone 6.3 ug/L 100 5.0 0.31 1 8260B 3/22/19 17:17 KDM P9C0443 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/22/19 17:17 KDM P9C0443 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/22/19 17:17 KDM P9C0443 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/22/19 17:17 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 42 Laboratory Report Full -Service P R S M Analytical & Environmental LABORATORIES INC. Solutions 04/08/2019 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: SW-01 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-03 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 14:15 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 17:17 KDM P9C0443 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/22/19 17:17 KDM P9C0443 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/22/19 17:17 KDM P9C0443 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/22/19 17:17 KDM P9C0443 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 17:17 KDM P9C0443 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/22/19 17:17 KDM P9C0443 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/22/19 17:17 KDM P9C0443 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 17:17 KDM P9C0443 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 17:17 KDM P9C0443 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/22/19 17:17 KDM P9C0443 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 17:17 KDM P9C0443 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/22/19 17:17 KDM P9C0443 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/22/19 17:17 KDM P9C0443 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 17:17 KDM P9C0443 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/22/19 17:17 KDM P9C0443 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/22/19 17:17 KDM P9C0443 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/22/19 17:17 KDM P9C0443 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/22/19 17:17 KDM P9C0443 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/22/19 17:17 KDM P9C0443 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/22/19 17:17 KDM P9C0443 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/22/19 17:17 KDM P9C0443 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/22/19 17:17 KDM P9C0443 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/22/19 17:17 KDM P9C0443 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/22/19 17:17 KDM P9C0443 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/22/19 17:17 KDM P9C0443 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/22/19 17:17 KDM P9C0443 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/22/19 17:17 KDM P9C0443 trans- 1,4-Dich loro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/22/19 17:17 KDM P9C0443 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/22/19 17:17 KDM P9C0443 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 17:17 KDM P9C0443 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/22/19 17:17 KDM P9C0443 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/22/19 17:17 KDM P9C0443 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/22/19 17:17 KDM P9C0443 Surrogate Recovery Control Limits 4-Bromofluorobenzene 95 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 95 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 42 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/08/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: SW-01 Prism Sample ID: 9030325-03 Prism Work Order: 9030325 Time Collected: 03/19/19 14:15 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 14:04 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 42 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/08/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: LT-01 Prism Sample ID: 9030325-04 Prism Work Order: 9030325 Time Collected: 03/19/19 14:35 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/22/19 17:50 KDM P9C0443 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 17:50 KDM P9C0443 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/22/19 17:50 KDM P9C0443 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 17:50 KDM P9C0443 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 17:50 KDM P9C0443 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 17:50 KDM P9C0443 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/22/19 17:50 KDM P9C0443 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/22/19 17:50 KDM P9C0443 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/22/19 17:50 KDM P9C0443 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 17:50 KDM P9C0443 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 17:50 KDM P9C0443 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 17:50 KDM P9C0443 1,4-Dichlorobenzene 4.2 ug/L 1 0.50 0.050 1 8260B 3/22/19 17:50 KDM P9C0443 Acetone 7.7 ug/L 100 5.0 0.31 1 8260B 3/22/19 17:50 KDM P9C0443 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/22/19 17:50 KDM P9C0443 Benzene 1.9 ug/L 1 0.50 0.048 1 8260B 3/22/19 17:50 KDM P9C0443 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/22/19 17:50 KDM P9C0443 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 17:50 KDM P9C0443 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/22/19 17:50 KDM P9C0443 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/22/19 17:50 KDM P9C0443 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/22/19 17:50 KDM P9C0443 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 17:50 KDM P9C0443 Chlorobenzene 2.7 ug/L 3 0.50 0.062 1 8260B 3/22/19 17:50 KDM P9C0443 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/22/19 17:50 KDM P9C0443 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 17:50 KDM P9C0443 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 17:50 KDM P9C0443 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/22/19 17:50 KDM P9C0443 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 17:50 KDM P9C0443 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/22/19 17:50 KDM P9C0443 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/22/19 17:50 KDM P9C0443 Ethylbenzene 0.45 j ug/L 1 0.50 0.061 1 8260B 3/22/19 17:50 KDM P9C0443 m,p-Xylenes 0.55 J ug/L NE 1.0 0.12 1 8260B 3/22/19 17:50 KDM P9C0443 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/22/19 17:50 KDM P9C0443 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/22/19 17:50 KDM P9C0443 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/22/19 17:50 KDM P9C0443 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/22/19 17:50 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 42 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 04/08/2019 LABORATORIES INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: LT-01 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-04 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 14:35 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/22/19 17:50 KDM P9C0443 o-Xylene 0.72 ug/L NE 0.50 0.044 1 8260B 3/22/19 17:50 KDM P9C0443 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/22/19 17:50 KDM P9C0443 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/22/19 17:50 KDM P9C0443 Tetrahydrofuran 110 ug/L NE 10 0.16 1 8260B 3/22/19 17:50 KDM P9C0443 Toluene 0.53 ug/L 1 0.50 0.044 1 8260B 3/22/19 17:50 KDM P9C0443 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/22/19 17:50 KDM P9C0443 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/22/19 17:50 KDM P9C0443 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/22/19 17:50 KDM P9C0443 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/22/19 17:50 KDM P9C0443 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 17:50 KDM P9C0443 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/22/19 17:50 KDM P9C0443 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/22/19 17:50 KDM P9C0443 Xylenes, total 1.3 J ug/L 5 1.5 0.15 1 8260B 3/22/19 17:50 KDM P9C0443 Surrogate Recovery Control Limits 4-Bromofluorobenzene 102 % 80-124 Dibromofluoromethane 108 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane 51 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 14:29 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 42 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/08/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: TB-20190319 Prism Sample ID: 9030325-05 Prism Work Order: 9030325 Time Collected: 03/19/19 00:00 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/22/19 15:01 KDM P9C0443 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 15:01 KDM P9C0443 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/22/19 15:01 KDM P9C0443 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 15:01 KDM P9C0443 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 15:01 KDM P9C0443 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/22/19 15:01 KDM P9C0443 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/22/19 15:01 KDM P9C0443 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/22/19 15:01 KDM P9C0443 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/22/19 15:01 KDM P9C0443 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 15:01 KDM P9C0443 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/22/19 15:01 KDM P9C0443 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 15:01 KDM P9C0443 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/22/19 15:01 KDM P9C0443 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/22/19 15:01 KDM P9C0443 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/22/19 15:01 KDM P9C0443 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/22/19 15:01 KDM P9C0443 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/22/19 15:01 KDM P9C0443 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 15:01 KDM P9C0443 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/22/19 15:01 KDM P9C0443 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/22/19 15:01 KDM P9C0443 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/22/19 15:01 KDM P9C0443 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/22/19 15:01 KDM P9C0443 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/22/19 15:01 KDM P9C0443 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/22/19 15:01 KDM P9C0443 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/22/19 15:01 KDM P9C0443 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 15:01 KDM P9C0443 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/22/19 15:01 KDM P9C0443 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/22/19 15:01 KDM P9C0443 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/22/19 15:01 KDM P9C0443 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/22/19 15:01 KDM P9C0443 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/22/19 15:01 KDM P9C0443 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/22/19 15:01 KDM P9C0443 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/22/19 15:01 KDM P9C0443 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/22/19 15:01 KDM P9C0443 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/22/19 15:01 KDM P9C0443 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/22/19 15:01 KDM P9C0443 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 42 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 04/08/2019 LABORATORIES INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: TB-20190319 Attn: Brian Gant 50-02) Prism Sample ID: 9030325-05 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030325 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/19/19 00:00 Time Submitted: 03/20/19 08:40 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride 0.64 A, J ug/L 1 1.0 0.083 1 8260B 3/22/19 15:01 KDM P9C0443 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/22/19 15:01 KDM P9C0443 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/22/19 15:01 KDM P9C0443 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/22/19 15:01 KDM P9C0443 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/22/19 15:01 KDM P9C0443 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/22/19 15:01 KDM P9C0443 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/22/19 15:01 KDM P9C0443 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/22/19 15:01 KDM P9C0443 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/22/19 15:01 KDM P9C0443 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/22/19 15:01 KDM P9C0443 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/22/19 15:01 KDM P9C0443 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/22/19 15:01 KDM P9C0443 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/22/19 15:01 KDM P9C0443 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/22/19 15:01 KDM P9C0443 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 111 % 75-129 Toluene-d8 97 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 12:23 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 42 Full -Service Analytical & LIPMVP S M Environmental Solutions OR TORIEB, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO443 - 5030B Blank (P9C0443-BLK1) Prepared & Analyzed: 03/22/19 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 42 PR I S M Full -Service Analytical Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030325 Attn: Brian Gant 50-02) Time Submitted: 3/20/2019 8:40:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO443 - 5030B Blank (P9C0443-BLK1) Prepared & Analyzed: 03/22/19 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 49.2 ug/L 50.00 98 80-124 Surrogate: Dibromofluoromethane 53.3 ug/L 50.00 107 75-129 Surrogate: Toluene-d8 48.3 ug/L 50.00 97 77-123 LCS (P9CO443-BSI) Prepared &Analyzed: 03/22/19 1,1,1,2-Tetrachloroethane 19.6 0.50 ug/L 20.00 98 79-134 1,1,1-Trichloroethane 21.4 0.50 ug/L 20.00 107 75-136 1,1,2,2-Tetrachloroethane 19.6 0.50 ug/L 20.00 98 62-127 1,1,2-Trichloroethane 21.8 0.50 ug/L 20.00 109 70-140 1,1-Dichloroethane 21.4 0.50 ug/L 20.00 107 78-130 1,1-Dichloroethylene 21.2 0.50 ug/L 20.00 106 70-154 1,2,3-Trichloropropane 20.6 1.0 ug/L 20.00 103 71-127 1,2-Dibromo-3-chloropropane 18.3 2.0 ug/L 20.00 91 63-134 1,2-Dibromoethane 19.6 0.50 ug/L 20.00 98 77-135 1,2-Dichlorobenzene 18.5 0.50 ug/L 20.00 92 78-128 1,2-Dichloroethane 20.8 0.50 ug/L 20.00 104 68-131 1,2-Dichloropropane 21.5 0.50 ug/L 20.00 108 77-130 1,4-Dichlorobenzene 18.0 0.50 ug/L 20.00 90 75-126 Acetone 69.6 5.0 ug/L 40.00 174 40-166 L1 Acrylonitrile 46.5 20 ug/L 40.00 116 81-127 Benzene 22.0 0.50 ug/L 20.00 110 77-128 Bromochloromethane 20.9 0.50 ug/L 20.00 105 78-135 Bromodichloromethane 21.6 0.50 ug/L 20.00 108 76-138 Bromoform 19.6 1.0 ug/L 20.00 98 71-135 Bromomethane 22.9 1.0 ug/L 20.00 115 41-168 Carbon disulfide 23.1 5.0 ug/L 20.00 116 59-135 Carbon Tetrachloride 19.9 0.50 ug/L 20.00 100 72-142 Chlorobenzene 18.9 0.50 ug/L 20.00 95 78-119 Chloroethane 23.7 0.50 ug/L 20.00 119 57-142 Chloroform 21.7 0.50 ug/L 20.00 108 77-130 Chloromethane 23.7 0.50 ug/L 20.00 118 47-145 cis-1,2-Dichloroethylene 21.5 0.50 ug/L 20.00 108 76-141 cis-1,3-Dichloropropylene 21.2 0.50 ug/L 20.00 106 65-140 Dibromochloromethane 20.3 0.50 ug/L 20.00 101 75-134 Dibromomethane 22.0 0.50 ug/L 20.00 110 76-138 Ethylbenzene 20.0 0.50 ug/L 20.00 100 80-127 m,p-Xylenes 41.6 1.0 ug/L 40.00 104 77-133 Methyl Butyl Ketone (2-Hexanone) 20.3 5.0 ug/L 20.00 102 64-137 Methyl Ethyl Ketone (2-Butanone) 27.0 5.0 ug/L 20.00 135 71-134 L1 Methyl Iodide 17.6 5.0 ug/L 20.00 88 70-130 Methyl Isobutyl Ketone 19.9 5.0 ug/L 20.00 100 69-134 Methylene Chloride 22.7 1.0 ug/L 20.00 113 73-131 o-Xylene 19.6 0.50 ug/L 20.00 98 78-128 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 42 P R I S M Full -Service Analytical s Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030325 Attn: Brian Gant 50-02) Time Submitted: 3/20/2019 8:40:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO443 - 5030B LCS (P9C0443-BSI) Prepared &Analyzed: 03/22/19 Styrene 19.3 0.50 ug/L 20.00 96 78-129 Tetrachloroethylene 19.8 0.50 ug/L 20.00 99 80-129 Tetrahydrofuran 22.2 10 ug/L 20.00 ill 70-130 Toluene 22.2 0.50 ug/L 20.00 ill 76-131 trans- 1,2-Dichloroethylene 21.2 0.50 ug/L 20.00 106 76-135 trans- 1,3-Dichloropropylene 20.7 0.50 ug/L 20.00 103 67-140 trans-1,4-Dichloro-2-butene 18.5 10 ug/L 20.00 92 70-130 Trichloroethylene 21.3 0.50 ug/L 20.00 107 77-133 Trichlorofluoromethane 20.2 0.50 ug/L 20.00 101 62-148 Vinyl acetate 20.5 2.0 ug/L 20.00 103 34-167 Vinyl chloride 22.1 0.50 ug/L 20.00 ill 57-141 Xylenes, total 61.2 1.5 ug/L 60.00 102 77-133 Surrogate:4-Bromofluorobenzene 48.2 ug/L 50.00 96 80-124 Surrogate: Dibromofluoromethane 52.8 ug/L 50.00 106 75-129 Surrogate: Toluene-d8 47.7 ug/L 50.00 95 77-123 LCS Dup (P9C0443-113SDI) Prepared &Analyzed: 03/22/19 1,1,1,2-Tetrachloroethane 19.4 0.50 ug/L 20.00 97 79-134 1 20 1,1,1-Trichloroethane 21.3 0.50 ug/L 20.00 106 75-136 0.4 20 1,1,2,2-Tetrachloroethane 20.2 0.50 ug/L 20.00 101 62-127 3 20 1,1,2-Trichloroethane 22.0 0.50 ug/L 20.00 110 70-140 0.6 20 1,1-Dichloroethane 21.3 0.50 ug/L 20.00 106 78-130 0.7 20 1,1-Dichloroethylene 20.8 0.50 ug/L 20.00 104 70-154 2 20 1,2,3-Trichloropropane 21.3 1.0 ug/L 20.00 106 71-127 3 20 1,2-Dibromo-3-chloropropane 20.3 2.0 ug/L 20.00 101 63-134 10 20 1,2-Dibromoethane 19.8 0.50 ug/L 20.00 99 77-135 0.7 20 1,2-Dichlorobenzene 18.9 0.50 ug/L 20.00 95 78-128 2 20 1,2-Dichloroethane 21.9 0.50 ug/L 20.00 109 68-131 5 20 1,2-Dichloropropane 21.5 0.50 ug/L 20.00 108 77-130 0.05 20 1,4-Dichlorobenzene 17.8 0.50 ug/L 20.00 89 75-126 1 20 Acetone 49.2 5.0 ug/L 40.00 123 40-166 34 20 D Acrylonitrile 47.0 20 ug/L 40.00 117 81-127 0.9 20 Benzene 21.4 0.50 ug/L 20.00 107 77-128 2 20 Bromochloromethane 21.3 0.50 ug/L 20.00 106 78-135 2 20 Bromodichloromethane 21.0 0.50 ug/L 20.00 105 76-138 3 20 Bromoform 19.5 1.0 ug/L 20.00 98 71-135 0.3 20 Bromomethane 22.0 1.0 ug/L 20.00 110 41-168 4 20 Carbon disulfide 22.9 5.0 ug/L 20.00 114 59-135 1 20 Carbon Tetrachloride 18.9 0.50 ug/L 20.00 95 72-142 5 20 Chlorobenzene 18.9 0.50 ug/L 20.00 94 78-119 0.2 20 Chloroethane 23.0 0.50 ug/L 20.00 115 57-142 3 20 Chloroform 20.9 0.50 ug/L 20.00 104 77-130 4 20 Chloromethane 24.1 0.50 ug/L 20.00 121 47-145 2 20 cis-1,2-Dichloroethylene 21.3 0.50 ug/L 20.00 106 76-141 1 20 cis-1,3-Dichloropropylene 21.1 0.50 ug/L 20.00 105 65-140 0.4 20 Dibromochloromethane 20.1 0.50 ug/L 20.00 100 75-134 0.9 20 Dibromomethane 21.1 0.50 ug/L 20.00 106 76-138 4 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO443 - 5030B LCS Dup (P9C0443-BSD1) Prepared & Analyzed: 03/22/19 Ethylbenzene 19.8 0.50 ug/L 20.00 99 80-127 1 20 m,p-Xylenes 41.4 1.0 ug/L 40.00 104 77-133 0.4 20 Methyl Butyl Ketone (2-Hexanone) 19.5 5.0 ug/L 20.00 97 64-137 4 20 Methyl Ethyl Ketone (2-Butanone) 24.7 5.0 ug/L 20.00 123 71-134 9 20 Methyl Iodide 16.6 5.0 ug/L 20.00 83 70-130 6 20 Methyl Isobutyl Ketone 21.1 5.0 ug/L 20.00 106 69-134 6 20 Methylene Chloride 22.5 1.0 ug/L 20.00 113 73-131 0.7 20 o-Xylene 19.1 0.50 ug/L 20.00 96 78-128 2 20 Styrene 18.9 0.50 ug/L 20.00 94 78-129 2 20 Tetrachloroethylene 19.3 0.50 ug/L 20.00 97 80-129 2 20 Tetrahydrofuran 22.6 10 ug/L 20.00 113 70-130 2 20 Toluene 21.4 0.50 ug/L 20.00 107 76-131 4 20 trans-1,2-Dichloroethylene 21.6 0.50 ug/L 20.00 108 76-135 2 20 trans-1,3-Dichloropropylene 21.7 0.50 ug/L 20.00 109 67-140 5 20 trans-1,4-Dichloro-2-butene 19.9 10 ug/L 20.00 99 70-130 7 20 Trichloroethylene 20.6 0.50 ug/L 20.00 103 77-133 4 20 Trichlorofluoromethane 20.3 0.50 ug/L 20.00 102 62-148 0.5 20 Vinyl acetate 21.3 2.0 ug/L 20.00 107 34-167 4 20 Vinyl chloride 21.4 0.50 ug/L 20.00 107 57-141 3 20 Xylenes, total 60.6 1.5 ug/L 60.00 101 77-133 1 20 Surrogate:4-Bromofluorobenzene 49.4 ug/L 50.00 99 80-124 Surrogate: Dibromofluoromethane 51.3 ug/L 50.00 103 75-129 Surrogate: Toluene-d8 48.2 ug/L 50.00 96 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO573 - 5030B Blank (P9C0573-BLK1) Prepared & Analyzed: 03/28/19 1,4-Dioxane BRL 3.0 ug/L LCS (P9C0573-BS1) Prepared &Analyzed: 03/28/19 1,4-Dioxane 45.1 3.0 ug/L 50.00 90 55-145 LCS Dup (P9CO573-BSD1) Prepared & Analyzed: 03/28/19 1,4-Dioxane 46.4 3.0 ug/L 50.00 93 55-145 3 30 Matrix Spike (P9C0573-MS1) Source: 9030325-05 Prepared & Analyzed: 03/28/19 1,4-Dioxane 47.4 3.0 ug/L 50.00 BRL 95 55-145 Matrix Spike Dup (P9C0573-MSD1) Source: 9030325-05 Prepared & Analyzed: 03/28/19 1,4-Dioxane 52.4 3.0 ug/L 50.00 BRL 105 55-145 10 30 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0451 - 3005A Blank (P9C0451-BLK1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 0.214 1.0 ug/L J Arsenic 0.225 1.0 ug/L J Barium BRL 5.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead 0.103 1.0 ug/L J Nickel BRL 2.0 ug/L Selenium BRL 5.0 ug/L Silver 0.0650 5.0 ug/L J Thallium BRL 1.0 ug/L Vanadium BRL 1.0 ug/L Zinc 3.28 10 ug/L J LCS (P9130451-113S1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 98.8 1.0 ug/L 100.0 99 80-120 Arsenic 100 1.0 ug/L 100.0 100 80-120 Barium 98.0 5.0 ug/L 100.0 98 80-120 Beryllium 98.5 1.0 ug/L 100.0 99 80-120 Cadmium 99.1 1.0 ug/L 100.0 99 80-120 Chromium 101 2.0 ug/L 100.0 101 80-120 Cobalt 105 1.0 ug/L 100.0 105 80-120 Copper 104 5.0 ug/L 100.0 104 80-120 Lead 102 1.0 ug/L 100.0 102 80-120 Nickel 103 2.0 ug/L 100.0 103 80-120 Selenium 98.9 5.0 ug/L 100.0 99 80-120 Silver 102 5.0 ug/L 100.0 102 80-120 Thallium 103 1.0 ug/L 100.0 103 80-120 Vanadium 101 1.0 ug/L 100.0 101 80-120 Zinc 103 10 ug/L 100.0 103 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 42 Level II QC Report P R I IS M Full -Service Analytical 4/8/19 Environmental Solutions . LABORATORIES, INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030325 Attn: Brian Gant 50-02) Time Submitted: 3/20/2019 8:40:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Total Metals - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0451 - 3005A Matrix Spike (P9C0451-MS1) Source: 9030325-01 Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 103 1.0 ug/L 100.0 0.208 103 75-125 Arsenic 102 1.0 ug/L 100.0 0.301 102 75-125 Barium 200 5.0 ug/L 100.0 97.5 103 75-125 Beryllium 100 1.0 ug/L 100.0 0.0650 100 75-125 Cadmium 101 1.0 ug/L 100.0 0.180 101 75-125 Chromium 98.4 2.0 ug/L 100.0 0.348 98 75-125 Cobalt 105 1.0 ug/L 100.0 1.41 103 75-125 Copper 103 5.0 ug/L 100.0 0.376 102 75-125 Lead 102 1.0 ug/L 100.0 BRL 102 75-125 Nickel 104 2.0 ug/L 100.0 2.55 101 75-125 Selenium 99.4 5.0 ug/L 100.0 0.637 99 75-125 Silver 102 5.0 ug/L 100.0 0.0730 102 75-125 Thallium 104 1.0 ug/L 100.0 0.149 104 75-125 Vanadium 101 1.0 ug/L 100.0 BRL 101 75-125 Zinc 115 10 ug/L 100.0 15.8 100 75-125 Matrix Spike Dup (P9C0451-MSD1) Source: 9030325-01 Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 104 1.0 ug/L 100.0 0.208 104 75-125 1 20 Arsenic 101 1.0 ug/L 100.0 0.301 101 75-125 0.8 20 Barium 198 5.0 ug/L 100.0 97.5 101 75-125 1 20 Beryllium 100 1.0 ug/L 100.0 0.0650 100 75-125 0.01 20 Cadmium 103 1.0 ug/L 100.0 0.180 102 75-125 1 20 Chromium 104 2.0 ug/L 100.0 0.348 104 75-125 5 20 Cobalt 103 1.0 ug/L 100.0 1.41 102 75-125 1 20 Copper 102 5.0 ug/L 100.0 0.376 101 75-125 1 20 Lead 104 1.0 ug/L 100.0 BRL 104 75-125 1 20 Nickel 103 2.0 ug/L 100.0 2.55 100 75-125 0.6 20 Selenium 97.2 5.0 ug/L 100.0 0.637 97 75-125 2 20 Silver 103 5.0 ug/L 100.0 0.0730 103 75-125 1 20 Thallium 105 1.0 ug/L 100.0 0.149 105 75-125 0.9 20 Vanadium 106 1.0 ug/L 100.0 BRL 106 75-125 5 20 Zinc 115 10 ug/L 100.0 15.8 99 75-125 0.5 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0474 - 7470A Blank (P9C0474-BLK1) Prepared &Analyzed: 03/26/19 Mercury BRL 0.20 ug/L LCS (P9C0474-BS1) Prepared &Analyzed: 03/26/19 Mercury 9.86 0.20 ug/L 9.375 105 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO398 - NO PREP Blank (P9C0398-BLK1) Prepared &Analyzed: 03/20/19 Chloride 155 1000 ug/L J Nitrate as N BRL 100 ug/L Sulfate BRL 2000 ug/L LCS (P9130398-13S1) Prepared &Analyzed: 03/20/19 Chloride 40700 1000 ug/L 40000 102 80-120 Nitrate as N 4000 100 ug/L 4000 100 80-120 Sulfate 40200 2100 ug/L 40000 100 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030325 Attn: Brian Gant 50-02) Time Submitted: 3/20/2019 8:40:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO409 - NO PREP Blank (P9C0409-BLK1) Prepared &Analyzed: 03/21/19 Ferrous Iron BRL 200 ug/L LCS (P9C0409-BS1) Prepared &Analyzed: 03/21/19 Ferrous Iron 2010 200 ug/L 2000 100 90-110 Matrix Spike (P9C0409-MS1) Source: 9030325-02 Prepared &Analyzed: 03/21/19 Ferrous Iron 2100 200 ug/L 2000 BRL 105 80-120 Matrix Spike Dup (P9C0409-MSD1) Source: 9030325-02 Prepared & Analyzed: 03/21/19 Ferrous Iron 2120 200 ug/L 2000 BRL 106 80-120 0.9 20 Batch P9CO418 - 9010C Blank (P9C0418-BLK1) Prepared & Analyzed: 03/25/19 Cyanide BRL 25 ug/L LCS (P9C0418-BS1) Prepared &Analyzed: 03/25/19 Cyanide 93.5 25 ug/L 100.0 94 85-115 Batch P9CO446 - NO PREP Blank (P9C0446-BLK1) Prepared &Analyzed: 03/22/19 Chemical Oxygen Demand BRL 50000 ug/L LCS (P9C0446-BS1) Prepared &Analyzed: 03/22/19 Chemical Oxygen Demand 496000 50000 ug/L 500000 99 90-110 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO484 - NO PREP Blank (P9C0484-BLK1) Prepared &Analyzed: 03/20/19 Biochemical Oxygen Demand BRL 2000 ug/L LCS (P9C0484-BS1) Prepared &Analyzed: 03/20/19 Biochemical Oxygen Demand 178000 2000 ug/L 198000 90 84.6-115.4 Batch P9CO520 - NO PREP Blank (P9C0520-BLK1) Prepared & Analyzed: 03/27/19 Hardness BRL 5000 ug/L LCS (P9C0520-BSI) Prepared &Analyzed: 03/27/19 Hardness 50000 5000 ug/L 50000 100 90-110 Batch P9CO532 - SM4500-S C Blank (P9C0532-BLK1) Prepared & Analyzed: 03/26/19 Sulfide BRL 2000 ug/L LCS (P9C0532-BSI) Prepared &Analyzed: 03/26/19 Sulfide 8000 2000 ug/L 10000 80 70-130 Batch P9CO574 - NO PREP Blank (P9C0574-BLK1) Prepared & Analyzed: 03/29/19 Total Alkalinity to pH 4.5 BRL 5000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 42 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/8/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Prism Work Order: 9030325 Time Submitted: 3/20/2019 8:40:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO574 - NO PREP LCS (P9C0574-BS1) Prepared &Analyzed: 03/29/19 Total Alkalinity to pH 4.5 255000 5000 ug/L 250000 102 90-110 Duplicate (P9C0574-DUP1) Source: 9030325-01 Prepared & Analyzed: 03/29/19 Total Alkalinity to pH 4.5 86100 5000 ug/L 83600 3 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 42 Sample Extraction Data Prep Method: 9010C Lab Number Batch Initial Final Date/Time 9030325-01 P9C0418 50 mL 50 mL 03/25/19 7:20 9030325-02 P9C0418 50 mL 50 mL 03/25/19 7:20 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 9030325-01 P9C0532 200 mL 200 mL 03/26/19 12:45 9030325-02 P9C0532 200 mL 200 mL 03/26/19 12:45 Prep Method: 3005A Lab Number Batch Initial Final DatelTime 9030325-01 P9C0451 50 mL 50 mL 03/25/19 7:25 9030325-02 P9C0451 50 mL 50 mL 03/25/19 7:25 9030325-03 P9C0451 50 mL 50 mL 03/25/19 7:25 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 9030325-01 P9C0474 20 mL 30 mL 03/26/19 8:25 9030325-02 P9C0474 20 mL 30 mL 03/26/19 8:25 9030325-03 P9C0474 20 mL 30 mL 03/26/19 8:25 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 9030325-01 P9C0443 10 mL 10 mL 03/22/19 9:17 9030325-02 P9C0443 10 mL 10 mL 03/22/19 9:17 9030325-03 P9C0443 10 mL 10 mL 03/22/19 9:17 9030325-04 P9C0443 10 mL 10 mL 03/22/19 9:17 9030325-05 P9C0443 10 mL 10 mL 03/22/19 9:17 Prep Method: 5030B Lab Number Batch Initial Final DatelTime 9030325-01 P9C0573 5 mL 5 mL 03/28/19 9:42 9030325-02 P9C0573 5 mL 5 mL 03/28/19 9:42 9030325-03 P9C0573 5 mL 5 mL 03/28/19 9:42 9030325-04 P9C0573 5 mL 5 mL 03/28/19 9:42 9030325-05 P9C0573 5 mL 5 mL 03/28/19 9:42 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 9030325-01 TOC (Sub) 9030325-02 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 30 of 42 rJ is' Z � U _. 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'~a� C I-V O qU m c Ea+ m• m) pa m d Ul Cl "� nb U Z II m a`m `o cLi �' y U a 3U ac w m a a iv w � U) m u) 'o N-2 z C7 ' Z ❑ ❑ �b 7 H m w LL m� w c zQ 0 o W U v� to a� �cU/) a N 0 u z❑ Q V` a cpi¢ ��O II of ao 0: Q Cw IL LU (9❑ ❑ L U) .,( w U p U p� ^� a = m y o ❑ U w a w m r- G x F Z _rn U N Q� m m W 0 U w Z d tlm - n xy❑ W g cL U) ° ' c of 42 z Page 31 = w � r ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte, NC 28224 ATTENTION RobbiJones PROJECTID 9030325 LABORATORY REPORT NUMBER 219032140 DATE 03/26/2019 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. ,Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 Innovation Park Dr., Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781 4243 or toll free at 888.315.4243. Lab Report#: 219032140 Page 1 of 11 Page 32 of 42 # GCA&L LELAP CERTIFICATE NUMBER: 01955 DOD-ELAP ACCREDITATION NUMBER: 74960 ANALYTICAL RESULTS Deliver To Robbi Jones Prism Laboratories PO Box 240543 Charlotte, NC 28224 800-529-6364 PJ LA Testing DoD F.tAP PERFORMED BY GCAL, LLC 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/26/2019 GCAL Report 219032100 �1�11 III �11 111 III u �1�11 111�1 �1� III Project 9030325 Additional Recipients NONE N14 N ISO ,V �17025��� 4+ti�p FCCAte)z�;e` Lab Report#: 219032140 Page 2 of 11 Page 33 of 42 Ifqk GC&L Report#: 219032140 ProjectID: 9030325 Laboratory Endorsement Report Date: 03/26/2019 Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CIF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or t Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) * Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature GCAL Report 219032140 Lab Report#: 219032140 Page 3 of 11 Page 34 of 42 41% Report#: 219032140 Project ID: 9030325 Certifications Report Date: 03/26/2019 Certification Certification Number DOD ELAP 74960 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michigan 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washin ton C929 USDA Soil Permit P330-16-00234 Lab Report#: 219032140 Page 4 of 11 Page 35 of 42 Client: Access Analytical Report#: 219032140 Project ID: 9030325 Report: 219032140 Case Narrative Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Report Date: 03/26/2019 Lab Report#: 219032140 Page 5 of 11 Page 36 of 42 o GCALL af i . GCAL ID Client ID 21903214001 MW-04 21903214002 MW-07 Report#: 219032140 Project ID: 9030325 Sample Summary Matrix Collect Date/Time Water 03/19/201910:57 Water 03/19/201912:35 Report Date: 03/26/2019 Receive Date/Time 03/21/2019 10:00 03/21 /2019 10:00 Lab Report#: 219032140 Page 6 of 11 Page 37 of 42 4� GCAL Report#: 219032140 ProjectID: 9030325 Summary of Compounds Detected No analytes were detected for analyses performed by GCAL. Report Date: 03/26/2019 Lab Report#: 219032140 Page 7 of 11 Page 38 of 42 4 GCAL Report#: 219032140 Project 9030325 Sample Results Report Date: 03/26/2019 Collect Date 03/19/2019 10:57 GCAL ID 21903214001 MW-�4 Receive Date 03/21/2019 10:00 Matrix Water SM 5310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 2 03/23/2019 02:30 PLH 656417 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ Units 0.6000 0.600 4.00 mg/L MW-07 Collect Date 03/19/2019 12:35 GCAL ID 21903214002 Receive Date 03/21/2019 10:00 Matrix Water SM 5310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 2 03/23/2019 02:47 PLH 656417 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ Units 0.6000 0.600 4.00 mg/L Lab Report#: 219032140 Page 8 of 11 Page 39 of 42 Report#: 219032140 Project ID: 9030325 General Chemistry QC Summary Report Date: 03/26/2019 Analytical Batch Client ID MB656417 LCS656417 LCSD656417 656417 GCALID 1908202 1908203 1908611 Sample Type MB LCS LCSD Prep Date NA NA NA Analysis Date 03/22/2019 17:03 03/22/2019 11:28 03/22/2019 22:27 Matrix Water Water Water SM 5310 B-2011 Units mg/L Spike Result %R Control Spike Result %R RPD RPD Result DL Added Limits%R Added Limit Total Organic Carbon C-012 ND 0.3 00 50.01 49.6199 1 90 - 110 1 50.01 49.6 991 0 20 Lab Report#: 219032140 Page 9 of 11 Page 40 of 42 a a)tD O O M I Client ioi 4565 - Access Analytical �/ �(� `►" `�`�A (" SSG: 219032140 PRISMR n I Full-ScrWce Anall,llcal 8 PW DLL `~ J I V I Environmental Solutions LA&IUEMI INC SUBCONTRACT ORDER 0:101icatiun: ! LAC USA('L Prism Laboratories, Inc. N[ SC'^ 0111cr _ 9030325 NIA� .I .'irti„. 1,,�IiURaT1SR �• 1ECL'1 NC, LABORATORY, Prism Lahominrics, Inc Gulf Coast Analytical Labs, Inc. 4 ' (� • aQ P. O. Box 240543 10781 Coarsey Blvd I 1 1 Charlotte, NC 28224-0543 Mmi Rouge, LA 70816 (? jV\ Phone:800-529-6364 Phanc:(225)769.4900 / Fnx:704-525-0409 rax: (225) 767-5717 Project M; n3pr. Rabbi A. Jones —04- - An klrli• Due V,puri t.+4ni a:mr fD Comments S..ir1,• 1D:903032541 Water 6-000d:03119/19 10:57 M W r 6 1 TOC (Suh) 04/16119 I0:37 Cnntabtem S:gy lied. .J1 ^ A m6v V A A' O � Sample I DI 0030325-u; Water I t.am;1.4: Off III 4 12:3S TOC (Sub) W/I (d 19 12:35 Caruni w75iipldial: ` r [-a •d h� ,n. Rtealvnl B) I)•l1 �' Rcl:nwd Fly I r)A )tnLriV vI G jLJ f� L D,ur R, 1:.:.;.1 By ilah umvie,4l IV Mc Relcased By Daw Re"Wed By 1),nc Page 1 Ul Page 41 of 42 s N no 00000❑o❑ P N Cl. Cl CI- E w o O Cl. F o a E U) 02 E ° ° O L O U � � J J ° E U c U Y E m ° o I♦ N d cn = E U W U co Q _ _ a O O : O FD C-. 5 U ° o c U o CL U _ _ ..=O. C O U (o O Ln Z a= o c C Cl. E `o U � rZ >, 0 c LLI ° CL ° 0 c=o a ° U U � C O -,On _ Wm p V ,,��-p U U N L +p3 LLJ N D N m CL J (d n () L� co E E o U 0 co Q) a) E Q 2 co co _ Cl) U cn U O Q Q a � U 0 a 0 E o � m in H cu M >CDCL 0~ EdCD C,' N a �`- `c� o M E o 75 w a in0 E Cl) E J E I a Q y u� u� c S Q H 0 T 0 0 Page 42 of 42 1 LP R I S M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Anchor QEA of North Carolina, PLLC Brian Gant 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Lab Submittal Date: 03/21/2019 Prism Work Order: 9030340 Case Narrative 4/3/19 14:20 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: TOC analysis was subcontracted to GCAL. Laboratory report is attached. Prism Summary of Detections does not include subcontracted data. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. &.I- RobbiA.Jones Reviewed By Robbi A. Jones President/Project Manager President/Project Manager Data Qualifiers Key Reference: J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 39 Sample Receipt Summary Full -Service Analytical R S fflyaR I M Environmental Solutions 04/03/2019 LABORATORIES, INC. Prism Work Order: 9030340 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-05R 9030340-01 Water 03/20/19 10:40 03/21/19 8:15 MW-03 9030340-02 Water 03/20/19 12:02 03/21/19 8:15 SW-02 9030340-03 Water 03/20/19 13:45 03/21/19 8:15 Trip Blank-20190320 9030340-04 Water 03/20/19 0:00 03/21/19 8:15 Samples were received in good condition at 3.4 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 39 /r P R I S M Full -Service Analytical s Environmental Solutions LABORATOR Summary of Detections 04/03/201S Prism Work Order: 9030340 Prism ID Client ID Parameter Method Result Units 9030340-01 MW-05R Chloride 9056A 44000 ug/L 9030340-01 MW-05R Nitrate as N 9056A 100 ug/L 9030340-01 MW-05R Biochemical Oxygen Demand SM5210 B 4400 ug/L 9030340-01 MW-05R Chemical Oxygen Demand SM5220 D 44000 J ug/L 9030340-01 MW-05R Total Alkalinity to pH 4.5 SM2320 B 330000 ug/L 9030340-01 MW-05R Arsenic 6020B 0.59 J ug/L 9030340-01 MW-05R Barium 6020B 150 ug/L 9030340-01 MW-05R Cadmium 6020B 0.28 J ug/L 9030340-01 MW-05R Chromium 6020B 0.97 J ug/L 9030340-01 MW-05R Cobalt 6020B 9.4 ug/L 9030340-01 MW-05R Copper 6020B 2.5 J ug/L 9030340-01 MW-05R Lead 6020B 0.37 J ug/L 9030340-01 MW-05R Nickel 6020B 3.0 ug/L 9030340-01 MW-05R Vanadium 6020B 0.98 J ug/L 9030340-01 MW-05R Zinc 6020B 20 ug/L 9030340-01 MW-05R 1,4-Dichlorobenzene 8260B 5.4 ug/L 9030340-01 MW-05R Acetone 8260B 11 ug/L 9030340-01 MW-05R Benzene 8260B 1.4 ug/L 9030340-01 MW-05R Chlorobenzene 8260B 7.2 ug/L 9030340-01 MW-05R cis-1,2-Dichloroethylene 8260B 4.2 ug/L 9030340-01 MW-05R Vinyl chloride 8260B 2.7 ug/L 9030340-01 MW-05R 1,4-Dioxane 8260B SIM 4.3 ug/L 9030340-02 MW-03 Chloride 9056A 20000 ug/L 9030340-02 MW-03 Nitrate as N 9056A 3400 ug/L 9030340-02 MW-03 Sulfate 9056A 7200 ug/L 9030340-02 MW-03 Biochemical Oxygen Demand SM5210 B 1900 J ug/L 9030340-02 MW-03 Chemical Oxygen Demand SM5220 D 48000 J ug/L 9030340-02 MW-03 Ferrous Iron SM3500-Fe D 150 J ug/L 9030340-02 MW-03 Sulfide SM4500-S F 1400 J ug/L 9030340-02 MW-03 Total Alkalinity to pH 4.5 SM2320 B 170000 ug/L 9030340-02 MW-03 Mercury 7470A 0.042 J ug/L 9030340-02 MW-03 Antimony 6020B 0.22 J ug/L 9030340-02 MW-03 Arsenic 6020B 0.98 J ug/L 9030340-02 MW-03 Barium 6020B 160 ug/L 9030340-02 MW-03 Beryllium 6020B 0.060 J ug/L 9030340-02 MW-03 Cadmium 6020B 0.23 J ug/L 9030340-02 MW-03 Chromium 6020B 5.6 ug/L 9030340-02 MW-03 Cobalt 6020B 3.5 ug/L 9030340-02 MW-03 Copper 6020B 10 ug/L 9030340-02 MW-03 Lead 6020B 0.81 J ug/L 9030340-02 MW-03 Nickel 6020B 8.7 ug/L 9030340-02 MW-03 Vanadium 6020E 3.3 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 39 /P R I S Full -Service Analytical Environmental Solutions � LABORATORIES, INC. Summary of Detections 04/03/201S Prism Work Order: 9030340 Prism ID Client ID Parameter Method Result Units 9030340-02 MW-03 Zinc 6020B 27 ug/L 9030340-02 MW-03 Acetone 8260B 8.3 ug/L 9030340-02 MW-03 m,p-Xylenes 8260B 0.42 J ug/L 9030340-02 MW-03 Xylenes, total 8260B 0.42 J ug/L 9030340-02 MW-03 1,4-Dioxane 8260B SIM 1.8 J ug/L 9030340-03 SW-02 Hardness SM2340 C 6500 ug/L 9030340-03 SW-02 Arsenic 6020B 0.15 J ug/L 9030340-03 SW-02 Barium 6020B 13 ug/L 9030340-03 SW-02 Chromium 6020B 0.76 J ug/L 9030340-03 SW-02 Cobalt 6020B 0.16 .1 ug/L 9030340-03 SW-02 Copper 6020B 0.66 J ug/L 9030340-03 SW-02 Lead 6020B 0.20 J ug/L 9030340-03 SW-02 Vanadium 6020B 0.54 J ug/L 9030340-03 SW-02 Zinc 6020B 15 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 39 %j6P R I S M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Laboratory Report 04/03/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: MW-05R Prism Sample ID: 9030340-01 Prism Work Order: 9030340 Time Collected: 03/20/19 10:40 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Anions by Ion Chromatography Chloride 44000 ug/L NE 1000 120 1 9056A 3/21/19 14:51 BMS P9C0438 Nitrate as N 100 ug/L 10000 100 41 1 9056A 3/21/19 14:51 BMS P9C0438 Sulfate <490 ug/L 250000 2000 490 1 9056A 3/21/19 14:51 BMS P9C0438 General Chemistry Parameters Biochemical Oxygen Demand 4400 ug/L NE 2000 200 1 SM5210 B 3/22/19 10:12 CBM P9C0550 Chemical Oxygen Demand 44000 J ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron <46 ug/L NE 200 46 1 SM3500-Fe D 3/21/19 13:45 BMS P9C0407 Sulfide <830 ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 330000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury <0.036 ug/L 0.2 0.20 0.036 1 7470A 3/26/19 12:59 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 17:30 JAB P9C0451 Arsenic 0.59 J ug/L 10 1.0 0.031 1 6020B 3/28/19 17:30 JAB P9C0451 Barium 150 ug/L 100 5.0 0.97 1 6020B 3/28/19 17:30 JAB P9C0451 Beryllium <0.057 ug/L 1 1.0 0.057 1 6020B 3/28/19 17:30 JAB P9C0451 Cadmium 0.28 J ug/L 1 1.0 0.078 1 6020B 3/28/19 17:30 JAB P9C0451 Chromium 0.97 J ug/L 10 2.0 0.19 1 6020B 3/28/19 17:30 JAB P9C0451 Cobalt 9.4 ug/L 10 1.0 0.0071 1 6020B 3/28/19 17:30 JAB P9C0451 Copper 2.5 J ug/L 10 5.0 0.22 1 6020B 3/28/19 17:30 JAB P9C0451 Lead 0.37 J ug/L 10 1.0 0.093 1 6020B 3128/19 17:30 JAB P9C0451 Nickel 3.0 ug/L 50 2.0 0.85 1 6020B 3/28/19 17:30 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 17:30 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 17:30 JAB P9C0451 Thallium <0.099 ug/L 5.5 1.0 0.099 1 6020B 3/28/19 17:30 JAB P9C0451 Vanadium 0.98 J ug/L 25 1.0 0.10 1 6020B 3/28/19 17:30 JAB P9C0451 Zinc 20 ug/L 10 10 2.8 1 6020B 3/28/19 17:30 JAB P9C0451 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/28/19 16:55 KDM P9C0555 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 16:55 KDM P9C0555 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/28/19 16:55 KDM P9C0555 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 16:55 KDM P9C0555 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 16:55 KDM P9C0555 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 16:55 KDM P9C0555 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/28/19 16:55 KDM P9C0555 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/28/19 16:55 KDM P9C0555 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/28/19 16:55 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 39 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/03/2019 Client Sample ID: MW-05R Prism Sample ID: 9030340-01 Prism Work Order: 9030340 Time Collected: 03/20/19 10:40 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 16:55 KDM P9C0555 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 16:55 KDM P9C0555 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 16:55 KDM P9C0555 1,4-Dichlorobenzene 5.4 ug/L 1 0.50 0.050 1 8260B 3/28/19 16:55 KDM P9C0555 Acetone 11 ug/L 100 5.0 0.31 1 8260B 3/28/19 16:55 KDM P9C0555 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/28/19 16:55 KDM P9C0555 Benzene 1.4 ug/L 1 0.50 0.048 1 8260B 3/28/19 16:55 KDM P9C0555 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/28/19 16:55 KDM P9C0555 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 16:55 KDM P9C0555 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/28/19 16:55 KDM P9C0555 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/28/19 16:55 KDM P9C0555 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/28/19 16:55 KDM P9C0555 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 16:55 KDM P9C0555 Chlorobenzene 7.2 ug/L 3 0.50 0.062 1 8260B 3/28/19 16:55 KDM P9C0555 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/28/19 16:55 KDM P9C0555 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 16:55 KDM P9C0555 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 16:55 KDM P9C0555 cis-1,2-Dichloroethylene 4.2 ug/L 5 0.50 0.056 1 8260B 3/28/19 16:55 KDM P9C0555 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 16:55 KDM P9C0555 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/28/19 16:55 KDM P9C0555 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/28/19 16:55 KDM P9C0555 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 16:55 KDM P9C0555 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/28/19 16:55 KDM P9C0555 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/28/19 16:55 KDM P9C0555 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/28/19 16:55 KDM P9C0555 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/28/19 16:55 KDM P9C0555 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/28/19 16:55 KDM P9C0555 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/28/19 16:55 KDM P9C0555 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/28/19 16:55 KDM P9C0555 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/28/19 16:55 KDM P9C0555 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/28/19 16:55 KDM P9C0555 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/28/19 16:55 KDM P9C0555 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/28/19 16:55 KDM P9C0555 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/28/19 16:55 KDM P9C0555 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/28/19 16:55 KDM P9C0555 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/28/19 16:55 KDM P9C0555 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/28/19 16:55 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 39 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/03/2019 Client Sample ID: MW-05R Prism Sample ID: 9030340-01 Prism Work Order: 9030340 Time Collected: 03/20/19 10:40 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 16:55 KDM P9C0555 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/28/19 16:55 KDM P9C0555 Vinyl chloride 2.7 ug/L 1 0.50 0.097 1 8260B 3/28/19 16:55 KDM P9C0555 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/28/19 16:55 KDM P9C0555 Surrogate Recovery Control Limits 4-Bromofluorobenzene 101 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 90 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 4.3 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 14:54 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 39 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/03/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: MW-03 Prism Sample ID: 9030340-02 Prism Work Order: 9030340 Time Collected: 03/20/19 12:02 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 20000 ug/L NE 1000 120 1 9056A 3/21/19 14:02 BMS P9C0438 Nitrate as N 3400 ug/L 10000 100 41 1 9056A 3/21/19 14:02 BMS P9C0438 Sulfate 7200 ug/L 250000 2000 490 1 9056A 3/21/19 14:02 BMS P9C0438 General Chemistry Parameters Biochemical Oxygen Demand 1900 J ug/L NE 2000 200 1 SM5210 B 3/22/19 10:12 CBM P9C0550 Chemical Oxygen Demand 48000 J ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron 150 J ug/L NE 200 46 1 SM3500-Fe D 3/21/19 13:45 BMS P9C0407 Sulfide 1400 J ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 170000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury 0.042 J ug/L 0.2 0.20 0.036 1 7470A 3/26/19 13:02 MMR P9C0474 Antimony 0.22 J ug/L 6 1.0 0.19 1 6020B 3/28/19 17:37 JAB P9C0451 Arsenic 0.98 J ug/L 10 1.0 0.031 1 6020B 3/28/19 17:37 JAB P9C0451 Barium 160 ug/L 100 5.0 0.97 1 6020B 3/28/19 17:37 JAB P9C0451 Beryllium 0.060 J ug/L 1 1.0 0.057 1 6020B 3/28/19 17:37 JAB P9C0451 Cadmium 0.23 J ug/L 1 1.0 0.078 1 6020B 3/28/19 17:37 JAB P9C0451 Chromium 5.6 ug/L 10 2.0 0.19 1 6020B 3/28/19 17:37 JAB P9C0451 Cobalt 3.5 ug/L 10 1.0 0.0071 1 6020B 3/28/19 17:37 JAB P9C0451 Copper 10 ug/L 10 5.0 0.22 1 6020B 3/28/19 17:37 JAB P9C0451 Lead 0.81 J ug/L 10 1.0 0.093 1 6020B 3/28/19 17:37 JAB P9C0451 Nickel 8.7 ug/L 50 2.0 0.85 1 6020B 3/28/19 17:37 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 17:37 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 17:37 JAB P9C0451 Thallium <0.099 ug/L 5.5 1.0 0.099 1 6020B 3/28/19 17:37 JAB P9C0451 Vanadium 3.3 ug/L 25 1.0 0.10 1 6020B 3/28/19 17:37 JAB P9C0451 Zinc 27 ug/L 10 10 2.8 1 6020B 3/28/19 17:37 JAB P9C0451 Volatile Organic Compounds by GC/MS 1,1,1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/28/19 17:20 KDM P9C0555 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 17:20 KDM P9C0555 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/28/19 17:20 KDM P9C0555 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 17:20 KDM P9C0555 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 17:20 KDM P9C0555 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 17:20 KDM P9C0555 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/28/19 17:20 KDM P9C0555 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/28/19 17:20 KDM P9C0555 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/28/19 17:20 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 39 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/03/2019 Client Sample ID: MW-03 Prism Sample ID: 9030340-02 Prism Work Order: 9030340 Time Collected: 03/20/19 12:02 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 17:20 KDM P9C0555 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 17:20 KDM P9C0555 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 17:20 KDM P9C0555 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/28/19 17:20 KDM P9C0555 Acetone 8.3 ug/L 100 5.0 0.31 1 8260B 3/28/19 17:20 KDM P9C0555 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/28/19 17:20 KDM P9C0555 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/28/19 17:20 KDM P9C0555 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/28/19 17:20 KDM P9C0555 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 17:20 KDM P9C0555 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/28/19 17:20 KDM P9C0555 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/28/19 17:20 KDM P9C0555 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/28/19 17:20 KDM P9C0555 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 17:20 KDM P9C0555 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/28/19 17:20 KDM P9C0555 Chloroethane <0,22 ug/L 10 0.50 0.22 1 8260B 3/28/19 17:20 KDM P9C0555 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 17:20 KDM P9C0555 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 17:20 KDM P9C0555 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/28/19 17:20 KDM P9C0555 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 17:20 KDM P9C0555 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/28/19 17:20 KDM P9C0555 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/28/19 17:20 KDM P9C0555 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 17:20 KDM P9C0555 m,p-Xylenes 0.42 j ug/L NE 1.0 0.12 1 8260B 3/28/19 17:20 KDM P9C0555 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/28/19 17:20 KDM P9C0555 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/28/19 17:20 KDM P9C0555 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/28/19 17:20 KDM P9C0555 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/28/19 17:20 KDM P9C0555 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/28/19 17:20 KDM P9C0555 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/28/19 17:20 KDM P9C0555 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/28/19 17:20 KDM P9C0555 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/28/19 17:20 KDM P9C0555 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/28/19 17:20 KDM P9C0555 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/28/19 17:20 KDM P9C0555 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/28/19 17:20 KDM P9C0555 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/28/19 17:20 KDM P9C0555 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/28/19 17:20 KDM P9C0555 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/28/19 17:20 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 39 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/03/2019 Client Sample ID: MW-03 Prism Sample ID: 9030340-02 Prism Work Order: 9030340 Time Collected: 03/20/19 12:02 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 17:20 KDM P9C0555 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/28/19 17:20 KDM P9C0555 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/28/19 17:20 KDM P9C0555 Xylenes, total 0.42 J ug/L 5 1.5 0.15 1 8260B 3/28/19 17:20 KDM P9C0555 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 1.8 J ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 15:19 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 39 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/03/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: SW-02 Prism Sample ID: 9030340-03 Prism Work Order: 9030340 Time Collected: 03/20/19 13:45 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID General Chemistry Parameters Hardness 6500 ug/L 5000 570 1 SM2340 C 3/27/19 10:29 BMS P9C0520 Total Metals Mercury <0.036 ug/L 0.2 0.20 0.036 1 7470A 3/26/19 13:06 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 17:43 JAB P9C0451 Arsenic 0.15 J ug/L 10 1.0 0.031 1 6020B 3/28/19 17:43 JAB P9C0451 Barium 13 ug/L 100 5.0 0.97 1 6020B 3/28/19 17:43 JAB P9C0451 Beryllium <0.057 ug/L 1 1.0 0.057 1 6020B 3/28/19 17:43 JAB P9C0451 Cadmium <0.078 ug/L 1 1.0 0.078 1 6020B 3/28/19 17:43 JAB P9C0451 Chromium 0.76 J ug/L 10 2.0 0.19 1 6020B 3/28/19 17:43 JAB P9C0451 Cobalt 0.16 J ug/L 10 1.0 0.0071 1 6020B 3/28/19 17:43 JAB P9C0451 Copper 0.66 J ug/L 10 5.0 0.22 1 6020B 3/28/19 17:43 JAB P9C0451 Lead 0.20 J ug/L 10 1.0 0.093 1 6020B 3/28/19 17:43 JAB P9C0451 Nickel <0.85 ug/L 50 2.0 0.85 1 6020B 3/28/19 17:43 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 17:43 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 17:43 JAB P9C0451 Thallium <0.099 ug/L 5.5 1.0 0.099 1 6020B 3/28/19 17:43 JAB P9C0451 Vanadium 0.54 J ug/L 25 1.0 0.10 1 6020B 3/28/19 17:43 JAB P9C0451 Zinc 15 ug/L 10 10 2.8 1 6020B 3/28/19 17:43 JAB P9C0451 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/28/19 17:46 KDM P9C0555 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 17:46 KDM P9C0555 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/28/19 17:46 KDM P9C0555 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 17:46 KDM P9C0555 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 17:46 KDM P9C0555 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 17:46 KDM P9C0555 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/28/19 17:46 KDM P9C0555 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/28/19 17:46 KDM P9C0555 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/28/19 17:46 KDM P9C0555 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 17:46 KDM P9C0555 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 17:46 KDM P9C0555 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 17:46 KDM P9C0555 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/28/19 17:46 KDM P9C0555 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/28/19 17:46 KDM P9C0555 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/28/19 17:46 KDM P9C0555 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/28/19 17:46 KDM P9C0555 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/28/19 17:46 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 39 Laboratory Report Full -Service P R S M Analytical & Environmental LABORATORIES INC. Solutions 04/03/2019 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: SW-02 Attn: Brian Gant 50-02) Prism Sample ID: 9030340-03 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030340 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/20/19 13:45 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 17:46 KDM P9C0555 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/28/19 17:46 KDM P9C0555 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/28/19 17:46 KDM P9C0555 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/28/19 17:46 KDM P9C0555 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 17:46 KDM P9C0555 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/28/19 17:46 KDM P9C0555 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/28/19 17:46 KDM P9C0555 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 17:46 KDM P9C0555 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 17:46 KDM P9C0555 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/28/19 17:46 KDM P9C0555 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 17:46 KDM P9C0555 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/28/19 17:46 KDM P9C0555 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/28/19 17:46 KDM P9C0555 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 17:46 KDM P9C0555 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/28/19 17:46 KDM P9C0555 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/28/19 17:46 KDM P9C0555 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/28/19 17:46 KDM P9C0555 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/28/19 17:46 KDM P9C0555 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/28/19 17:46 KDM P9C0555 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/28/19 17:46 KDM P9C0555 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/28/19 17:46 KDM P9C0555 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/28/19 17:46 KDM P9C0555 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/28/19 17:46 KDM P9C0555 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/28/19 17:46 KDM P9C0555 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/28/19 17:46 KDM P9C0555 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/28/19 17:46 KDM P9C0555 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/28/19 17:46 KDM P9C0555 trans- 1,4-Dich loro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/28/19 17:46 KDM P9C0555 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/28/19 17:46 KDM P9C0555 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 17:46 KDM P9C0555 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/28/19 17:46 KDM P9C0555 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/28/19 17:46 KDM P9C0555 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/28/19 17:46 KDM P9C0555 Surrogate Recovery Control Limits 4-Bromofluorobenzene 97 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 92 % 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 39 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/03/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: SW-02 Prism Sample ID: 9030340-03 Prism Work Order: 9030340 Time Collected: 03/20/19 13:45 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 15:44 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 39 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/03/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit Client Sample ID: Trip Blank-20190320 50-02) Prism Sample ID: 9030340-04 Project No.: 50-02 Prism Work Order: 9030340 Sample Matrix: Water Time Collected: 03/20/19 00:00 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/28/19 14:20 KDM P9C0555 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 14:20 KDM P9C0555 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/28/19 14:20 KDM P9C0555 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 14:20 KDM P9C0555 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 14:20 KDM P9C0555 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/28/19 14:20 KDM P9C0555 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/28/19 14:20 KDM P9C0555 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/28/19 14:20 KDM P9C0555 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/28/19 14:20 KDM P9C0555 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 14:20 KDM P9C0555 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/28/19 14:20 KDM P9C0555 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 14:20 KDM P9C0555 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/28/19 14:20 KDM P9C0555 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/28/19 14:20 KDM P9C0555 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/28/19 14:20 KDM P9C0555 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/28/19 14:20 KDM P9C0555 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/28/19 14:20 KDM P9C0555 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 14:20 KDM P9C0555 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/28/19 14:20 KDM P9C0555 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/28/19 14:20 KDM P9C0555 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/28/19 14:20 KDM P9C0555 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/28/19 14:20 KDM P9C0555 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/28/19 14:20 KDM P9C0555 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/28/19 14:20 KDM P9C0555 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/28/19 14:20 KDM P9C0555 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 14:20 KDM P9C0555 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/28/19 14:20 KDM P9C0555 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/28/19 14:20 KDM P9C0555 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/28/19 14:20 KDM P9C0555 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/28/19 14:20 KDM P9C0555 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/28/19 14:20 KDM P9C0555 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/28/19 14:20 KDM P9C0555 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/28/19 14:20 KDM P9C0555 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/28/19 14:20 KDM P9C0555 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/28/19 14:20 KDM P9C0555 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/28/19 14:20 KDM P9C0555 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 39 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 04/03/2019 LABORATORIES INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: Trip Blank-20190320 Attn: Brian Gant 50-02) Prism Sample ID: 9030340-04 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030340 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/20/19 00:00 Time Submitted: 03/21/19 08:15 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/28/19 14:20 KDM P9C0555 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/28/19 14:20 KDM P9C0555 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/28/19 14:20 KDM P9C0555 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/28/19 14:20 KDM P9C0555 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/28/19 14:20 KDM P9C0555 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/28/19 14:20 KDM P9C0555 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/28/19 14:20 KDM P9C0555 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/28/19 14:20 KDM P9C0555 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/28/19 14:20 KDM P9C0555 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/28/19 14:20 KDM P9C0555 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/28/19 14:20 KDM P9C0555 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/28/19 14:20 KDM P9C0555 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/28/19 14:20 KDM P9C0555 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/28/19 14:20 KDM P9C0555 Surrogate Recovery Control Limits 4-Bromofluorobenzene 97 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 92 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 3/28/19 12:48 JLB P9C0573 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 39 Full -Service Analytical & LIPMVP S M Environmental Solutions OR TORIEB, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO555 - 5030B Blank (P9C0555-BLK1) Prepared & Analyzed: 03/28/19 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 39 PR I S M Full -Service Analytical Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030340 Attn: Brian Gant 50-02) Time Submitted: 3/21/2019 8:15:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO555 - 5030B Blank (P9C0555-BLK1) Prepared & Analyzed: 03/28/19 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 49.2 ug/L 50.00 98 80-124 Surrogate: Dibromofluoromethane 48.6 ug/L 50.00 97 75-129 Surrogate: Toluene-d8 47.9 ug/L 50.00 96 77-123 LCS (P9CO555-BSI) Prepared &Analyzed: 03/28/19 1,1,1,2-Tetrachloroethane 20.3 0.50 ug/L 20.00 102 79-134 1,1,1-Trichloroethane 21.3 0.50 ug/L 20.00 107 75-136 1,1,2,2-Tetrachloroethane 19.1 0.50 ug/L 20.00 96 62-127 1,1,2-Trichloroethane 21.2 0.50 ug/L 20.00 106 70-140 1,1-Dichloroethane 21.4 0.50 ug/L 20.00 107 78-130 1,1-Dichloroethylene 22.1 0.50 ug/L 20.00 110 70-154 1,2,3-Trichloropropane 18.5 1.0 ug/L 20.00 92 71-127 1,2-Dibromo-3-chloropropane 16.2 2.0 ug/L 20.00 81 63-134 1,2-Dibromoethane 20.0 0.50 ug/L 20.00 100 77-135 1,2-Dichlorobenzene 18.0 0.50 ug/L 20.00 90 78-128 1,2-Dichloroethane 20.9 0.50 ug/L 20.00 105 68-131 1,2-Dichloropropane 21.3 0.50 ug/L 20.00 107 77-130 1,4-Dichlorobenzene 18.0 0.50 ug/L 20.00 90 75-126 Acetone 59.0 5.0 ug/L 40.00 148 40-166 Acrylonitrile 42.0 20 ug/L 40.00 105 81-127 Benzene 20.7 0.50 ug/L 20.00 103 77-128 Bromochloromethane 21.4 0.50 ug/L 20.00 107 78-135 Bromodichloromethane 20.9 0.50 ug/L 20.00 104 76-138 Bromoform 18.5 1.0 ug/L 20.00 93 71-135 Bromomethane 23.1 1.0 ug/L 20.00 115 41-168 Carbon disulfide 21.2 5.0 ug/L 20.00 106 59-135 Carbon Tetrachloride 18.9 0.50 ug/L 20.00 94 72-142 Chlorobenzene 19.1 0.50 ug/L 20.00 96 78-119 Chloroethane 23.3 0.50 ug/L 20.00 116 57-142 Chloroform 20.4 0.50 ug/L 20.00 102 77-130 Chloromethane 20.9 0.50 ug/L 20.00 105 47-145 cis-1,2-Dichloroethylene 21.0 0.50 ug/L 20.00 105 76-141 cis-1,3-Dichloropropylene 20.7 0.50 ug/L 20.00 104 65-140 Dibromochloromethane 19.2 0.50 ug/L 20.00 96 75-134 Dibromomethane 21.2 0.50 ug/L 20.00 106 76-138 Ethylbenzene 19.7 0.50 ug/L 20.00 98 80-127 m,p-Xylenes 39.6 1.0 ug/L 40.00 99 77-133 Methyl Butyl Ketone (2-Hexanone) 19.0 5.0 ug/L 20.00 95 64-137 Methyl Ethyl Ketone (2-Butanone) 23.2 5.0 ug/L 20.00 116 71-134 Methyl Iodide 19.2 5.0 ug/L 20.00 96 70-130 Methyl Isobutyl Ketone 21.6 5.0 ug/L 20.00 108 69-134 Methylene Chloride 22.0 1.0 ug/L 20.00 110 73-131 o-Xylene 19.9 0.50 ug/L 20.00 99 78-128 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 39 P R I S M Full -Service Analytical s Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030340 Attn: Brian Gant 50-02) Time Submitted: 3/21/2019 8:15:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO555 - 5030B LCS (P9C0555-BSI) Prepared &Analyzed: 03/28/19 Styrene 18.9 0.50 ug/L 20.00 94 78-129 Tetrachloroethylene 19.9 0.50 ug/L 20.00 100 80-129 Tetrahydrofuran 21.6 10 ug/L 20.00 108 70-130 Toluene 21.0 0.50 ug/L 20.00 105 76-131 trans- 1,2-Dichloroethylene 21.2 0.50 ug/L 20.00 106 76-135 trans- 1,3-Dichloropropylene 20.9 0.50 ug/L 20.00 105 67-140 trans-1,4-Dichloro-2-butene 15.6 10 ug/L 20.00 78 70-130 Trichloroethylene 20.5 0.50 ug/L 20.00 103 77-133 Trichlorofluoromethane 22.2 0.50 ug/L 20.00 ill 62-148 Vinyl acetate 22.8 2.0 ug/L 20.00 114 34-167 Vinyl chloride 18.1 0.50 ug/L 20.00 91 57-141 Xylenes, total 59.5 1.5 ug/L 60.00 99 77-133 Surrogate:4-Bromofluorobenzene 48.4 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 49.2 ug/L 50.00 98 75-129 Surrogate: Toluene-d8 46.9 ug/L 50.00 94 77-123 LCS Dup (P9C0555-113SD1) Prepared &Analyzed: 03/28/19 1,1,1,2-Tetrachloroethane 19.5 0.50 ug/L 20.00 98 79-134 4 20 1,1,1-Trichloroethane 20.6 0.50 ug/L 20.00 103 75-136 3 20 1,1,2,2-Tetrachloroethane 18.9 0.50 ug/L 20.00 94 62-127 1 20 1,1,2-Trichloroethane 21.5 0.50 ug/L 20.00 107 70-140 1 20 1,1-Dichloroethane 20.9 0.50 ug/L 20.00 105 78-130 2 20 1,1-Dichloroethylene 21.6 0.50 ug/L 20.00 108 70-154 2 20 1,2,3-Trichloropropane 18.7 1.0 ug/L 20.00 94 71-127 1 20 1,2-Dibromo-3-chloropropane 16.6 2.0 ug/L 20.00 83 63-134 2 20 1,2-Dibromoethane 19.1 0.50 ug/L 20.00 96 77-135 4 20 1,2-Dichlorobenzene 18.0 0.50 ug/L 20.00 90 78-128 0.3 20 1,2-Dichloroethane 20.9 0.50 ug/L 20.00 104 68-131 0.2 20 1,2-Dichloropropane 20.9 0.50 ug/L 20.00 105 77-130 2 20 1,4-Dichlorobenzene 17.8 0.50 ug/L 20.00 89 75-126 1 20 Acetone 62.8 5.0 ug/L 40.00 157 40-166 6 20 Acrylonitrile 42.3 20 ug/L 40.00 106 81-127 0.7 20 Benzene 20.1 0.50 ug/L 20.00 100 77-128 3 20 Bromochloromethane 20.9 0.50 ug/L 20.00 105 78-135 2 20 Bromodichloromethane 20.3 0.50 ug/L 20.00 102 76-138 3 20 Bromoform 17.9 1.0 ug/L 20.00 90 71-135 3 20 Bromomethane 22.0 1.0 ug/L 20.00 110 41-168 5 20 Carbon disulfide 20.3 5.0 ug/L 20.00 101 59-135 4 20 Carbon Tetrachloride 18.0 0.50 ug/L 20.00 90 72-142 4 20 Chlorobenzene 18.4 0.50 ug/L 20.00 92 78-119 4 20 Chloroethane 22.4 0.50 ug/L 20.00 112 57-142 4 20 Chloroform 20.2 0.50 ug/L 20.00 101 77-130 1 20 Chloromethane 20.3 0.50 ug/L 20.00 102 47-145 3 20 cis-1,2-Dichloroethylene 20.6 0.50 ug/L 20.00 103 76-141 2 20 cis-1,3-Dichloropropylene 20.3 0.50 ug/L 20.00 101 65-140 2 20 Dibromochloromethane 18.5 0.50 ug/L 20.00 92 75-134 4 20 Dibromomethane 21.0 0.50 ug/L 20.00 105 76-138 0.8 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO555 - 5030B LCS Dup (P9C0555-BSD1) Prepared & Analyzed: 03/28/19 Ethylbenzene 19.0 0.50 ug/L 20.00 95 80-127 4 20 m,p-Xylenes 37.8 1.0 ug/L 40.00 95 77-133 5 20 Methyl Butyl Ketone (2-Hexanone) 18.5 5.0 ug/L 20.00 92 64-137 2 20 Methyl Ethyl Ketone (2-Butanone) 24.2 5.0 ug/L 20.00 121 71-134 4 20 Methyl Iodide 18.3 5.0 ug/L 20.00 92 70-130 4 20 Methyl Isobutyl Ketone 21.7 5.0 ug/L 20.00 108 69-134 0.4 20 Methylene Chloride 21.3 1.0 ug/L 20.00 107 73-131 3 20 o-Xylene 18.5 0.50 ug/L 20.00 93 78-128 7 20 Styrene 18.0 0.50 ug/L 20.00 90 78-129 5 20 Tetrachloroethylene 19.4 0.50 ug/L 20.00 97 80-129 3 20 Tetrahydrofuran 21.7 10 ug/L 20.00 108 70-130 0.1 20 Toluene 20.2 0.50 ug/L 20.00 101 76-131 4 20 trans-1,2-Dichloroethylene 20.4 0.50 ug/L 20.00 102 76-135 4 20 trans-1,3-Dichloropropylene 20.4 0.50 ug/L 20.00 102 67-140 3 20 trans-1,4-Dichloro-2-butene 15.0 10 ug/L 20.00 75 70-130 4 20 Trichloroethylene 20.1 0.50 ug/L 20.00 100 77-133 2 20 Trichlorofluoromethane 21.6 0.50 ug/L 20.00 108 62-148 3 20 Vinyl acetate 22.4 2.0 ug/L 20.00 112 34-167 2 20 Vinyl chloride 17.6 0.50 ug/L 20.00 88 57-141 3 20 Xylenes, total 56.4 1.5 ug/L 60.00 94 77-133 5 20 Surrogate:4-Bromofluorobenzene 48.7 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 50.1 ug/L 50.00 100 75-129 Surrogate: Toluene-d8 46.4 ug/L 50.00 93 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO573 - 5030B Blank (P9C0573-BLK1) Prepared & Analyzed: 03/28/19 1,4-Dioxane BRL 3.0 ug/L LCS (P9C0573-BS1) Prepared &Analyzed: 03/28/19 1,4-Dioxane 45.1 3.0 ug/L 50.00 90 55-145 LCS Dup (P9CO573-BSD1) Prepared & Analyzed: 03/28/19 1,4-Dioxane 46.4 3.0 ug/L 50.00 93 55-145 3 30 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0451 - 3005A Blank (P9C0451-BLK1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 0.214 1.0 ug/L J Arsenic 0.225 1.0 ug/L J Barium BRL 5.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead 0.103 1.0 ug/L J Nickel BRL 2.0 ug/L Selenium BRL 5.0 ug/L Silver 0.0650 5.0 ug/L J Thallium BRL 1.0 ug/L Vanadium BRL 1.0 ug/L Zinc 3.28 10 ug/L J LCS (P9130451-113S1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 98.8 1.0 ug/L 100.0 99 80-120 Arsenic 100 1.0 ug/L 100.0 100 80-120 Barium 98.0 5.0 ug/L 100.0 98 80-120 Beryllium 98.5 1.0 ug/L 100.0 99 80-120 Cadmium 99.1 1.0 ug/L 100.0 99 80-120 Chromium 101 2.0 ug/L 100.0 101 80-120 Cobalt 105 1.0 ug/L 100.0 105 80-120 Copper 104 5.0 ug/L 100.0 104 80-120 Lead 102 1.0 ug/L 100.0 102 80-120 Nickel 103 2.0 ug/L 100.0 103 80-120 Selenium 98.9 5.0 ug/L 100.0 99 80-120 Silver 102 5.0 ug/L 100.0 102 80-120 Thallium 103 1.0 ug/L 100.0 103 80-120 Vanadium 101 1.0 ug/L 100.0 101 80-120 Zinc 103 10 ug/L 100.0 103 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0474 - 7470A Blank (P9C0474-BLK1) Prepared &Analyzed: 03/26/19 Mercury BRL 0.20 ug/L LCS (P9C0474-BS1) Prepared &Analyzed: 03/26/19 Mercury 9.86 0.20 ug/L 9.375 105 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch MUM - NO PREP Blank (P9C0438-BLK1) Prepared &Analyzed: 03/21/19 Chloride 150 1000 ug/L J Nitrate as N BRL 100 ug/L Sulfate BRL 2000 ug/L LCS (P9C0438-BSI) Prepared &Analyzed: 03/21/19 Chloride 41500 1000 ug/L 40000 104 80-120 Nitrate as N 4070 100 ug/L 4000 102 80-120 Sulfate 43900 2100 ug/L 40000 110 80-120 Matrix Spike (P9C0438-MS1) Source: 9030340-02 Prepared &Analyzed: 03/21/19 Chloride 60300 1000 ug/L 40000 20400 100 80-120 Nitrate as N 7400 100 ug/L 4000 3420 99 80-120 Sulfate 46300 2100 ug/L 40000 7210 98 80-120 Matrix Spike Dup (P9C0438-MSD1) Source: 9030340-02 Prepared & Analyzed: 03/21/19 Chloride 60700 1000 ug/L 40000 20400 101 80-120 0.6 15 Nitrate as N 7420 100 ug/L 4000 3420 100 80-120 0.3 15 Sulfate 46500 2100 ug/L 40000 7210 98 80-120 0.6 15 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030340 Attn: Brian Gant 50-02) Time Submitted: 3/21/2019 8:15:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO407 - NO PREP Blank (P9C0407-BLK1) Prepared &Analyzed: 03/21/19 Ferrous Iron BRL 200 ug/L LCS (P9C0407-BS1) Prepared &Analyzed: 03/21/19 Ferrous Iron 1970 200 ug/L 2000 98 90-110 Matrix Spike (P9C0407-MS1) Source: 9030340-01 Prepared &Analyzed: 03/21/19 Ferrous Iron 2030 200 ug/L 2000 BRL 101 80-120 Matrix Spike Dup (P9C0407-MSD1) Source: 9030340-01 Prepared & Analyzed: 03/21/19 Ferrous Iron 1940 200 ug/L 2000 BRL 97 80-120 4 20 Batch P9CO418 - 9010C Blank (P9C0418-BLK1) Prepared & Analyzed: 03/25/19 Cyanide BRL 25 ug/L LCS (P9C0418-BS1) Prepared &Analyzed: 03/25/19 Cyanide 93.5 25 ug/L 100.0 94 85-115 Batch P9CO446 - NO PREP Blank (P9C0446-BLK1) Prepared &Analyzed: 03/22/19 Chemical Oxygen Demand BRL 50000 ug/L LCS (P9C0446-BS1) Prepared &Analyzed: 03/22/19 Chemical Oxygen Demand 496000 50000 ug/L 500000 99 90-110 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Batch P9CO520 - NO PREP Project: Jackson Cty Landfill (Permit Prism Work Order: 9030340 50-02) Time Submitted: 3/21/2019 8:15:OOAM Project No: 50-02 Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Blank (P9C0520-BLK1) Prepared &Analyzed: 03/27/19 Hardness BRL 5000 ug/L LCS (P9C0520-BS1) Prepared &Analyzed: 03/27/19 Hardness 50000 5000 ug/L 50000 100 90-110 Matrix Spike (P9C0520-MS1) Source: 9030340-03 Prepared & Analyzed: 03/27/19 Hardness 16500 5000 ug/L 10000 6500 100 80-120 Matrix Spike Dup (P9C0520-MSD1) Source: 9030340-03 Prepared & Analyzed: 03/27/19 Hardness 17000 5000 ug/L 10000 6500 105 80-120 3 20 Batch P9CO532 - SM4500-S C Blank (P9C0532-BLK1) Prepared & Analyzed: 03/26/19 Sulfide BRL 2000 ug/L LCS (P9C0532-BSI) Prepared &Analyzed: 03/26/19 Sulfide 8000 2000 ug/L 10000 80 70-130 Matrix Spike (P9C0532-MS1) Source: 9030340-01 Prepared & Analyzed: 03/26/19 Sulfide 7800 2000 ug/L 10000 BRL 78 70-130 Matrix Spike Dup (P9C0532-MSD1) Source: 9030340-01 Prepared & Analyzed: 03/26/19 Sulfide 7900 2000 ug/L 10000 BRL 79 70-130 1 20 Batch P9CO550 - NO PREP Blank (P9C0550-BLK1) Prepared & Analyzed: 03/22/19 Biochemical Oxygen Demand BRL 2000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 39 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/3/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Prism Work Order: 9030340 Time Submitted: 3/21/2019 8:15:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO550 - NO PREP LCS (P9C0550-BSI) Prepared &Analyzed: 03/22/19 Biochemical Oxygen Demand 206000 2000 ug/L 198000 104 84.6-115.4 Batch P9C0574 - NO PREP Blank (P9C0574-BLK1) Prepared & Analyzed: 03/29/19 Total Alkalinity to pH 4.5 BRL 5000 ug/L LCS (P9C0574-BS1) Prepared &Analyzed: 03/29/19 Total Alkalinity to pH 4.5 255000 5000 ug/L 250000 102 90-110 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 39 Sample Extraction Data Prep Method: 9010C Lab Number Batch Initial Final Date/Time 9030340-01 P9C0418 50 mL 50 mL 03/25/19 9:40 9030340-02 P9C0418 50 mL 50 mL 03/25/19 9:40 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 9030340-01 P9C0532 200 mL 200 mL 03/26/19 12:45 9030340-02 P9C0532 200 mL 200 mL 03/26/19 12:45 Prep Method: 3005A Lab Number Batch Initial Final DatelTime 9030340-01 P9C0451 50 mL 50 mL 03/25/19 7:25 9030340-02 P9C0451 50 mL 50 mL 03/25/19 7:25 9030340-03 P9C0451 50 mL 50 mL 03/25/19 7:25 Prep Method: 7470A Lab Number Batch Initial Final DatelTime 9030340-01 P9C0474 20 mL 30 mL 03/26/19 8:25 9030340-02 P9C0474 20 mL 30 mL 03/26/19 8:25 9030340-03 P9C0474 20 mL 30 mL 03/26/19 8:25 Prep Method: 5030B Lab Number Batch Initial Final Date/Time 9030340-01 P9C0555 10 mL 10 mL 03/28/19 11:32 9030340-02 P9C0555 10 mL 10 mL 03/28/19 11:32 9030340-03 P9C0555 10 mL 10 mL 03/28/19 11:32 9030340-04 P9C0555 10 mL 10 mL 03/28/19 11:32 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9030340-01 P9C0573 5 mL 5 mL 03/28/19 9:42 9030340-02 P9C0573 5 mL 5 mL 03/28/19 9:42 9030340-03 P9C0573 5 mL 5 mL 03/28/19 9:42 9030340-04 P9C0573 5 mL 5 mL 03/28/19 9:42 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 9030340-01 TOC (Sub) 9030340-02 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 39 Z tp.t 7,- C)f zlllllfl I p Z U0 \i �I�IV V 4 Y1 Cl.w. p. V 0) L U O Cl. F �. > E w z _ Qul v o z w d L) = y z w ~ ` 0 € z 0 a. �wc�t a� w > p J w ~ in a 0> a Iw ce z� 0 ILL W m z S aU0 r 0 m 7 � c W t O0. pic d s z C N W F NOEI y S . � Q L6 0in CY a ry I O Ear- m O Z O Q 0 H w V a d> >> 9 d a`w a5 a r of c C o U '— _7 > O ca Cl) r a) c V N N G U 6i1 1 > E � c Z C4 fn `O y O � c 01 r � ie LL W tL-L U � m a7Nt w Y ¢ O N d .. Q 2 d j o6' 00 _ 0 oro E Z m c n W g o c Z V rn z �o �o G Eta 0 FO C m a a w Z Nm, Zxl age O Z s rn �J WCL a Z 0 C9 Z J LL I IL y c I 0 U) LU Z Hj p / WJ >< m m W Z V U) C a '�.^,- ?� yjLL. mu W '-Ex m ; 4;L r ❑ U` � a m C p � N U) ID v ❑ Z Z Z N r ❑ y� 3 o w Q n 0 7 V O wa O ti M X 1' V LU N T lCp U (a h w nNzO U))O H tll N •�. a) a c V w N �" „ = A �tl C m 32Um W U)COO z omoc�g�y m�6a� ❑ ❑ wo M Z Z LL a N N w m 0 Z �. a7 m-U)c w O p m E w w L d �v so w Q 00 WJ `I 7 M C y 7 W W L a) ` a) 2 fn K a y F m w .. ti > m ` a-O E E O a) 3 m n w w \ IL a cn F x O w 11 J N Q N C 3 l� E 4 E F- > S m a o ti t 0 m y LL w E 0 U m c 0 v Q 1 � � w N 11 W A c0 C )� a Q N N IN M'_ O •E_ mC N N a) W O� p' N l>Or N Z a) T . � � c C � � � F L� Y d C N L •� a) � m o 0.. E� C ch a cc > �a 8 m � L w S V 9 y ao a E '° .3 fV N U) ` 01 7 F 7 N O IM TW, c N CO i O � « w U� a O E c L N o) O1 C .-. C a.3 C y ) 7 c v -. U) c -0 - y m ` c E R U)i � w m U CO U a co V1 _ <D �� ❑ u m U z ° 0 ❑ ❑ : N �z U � .� n J N U' LLL > m U u 0 L) If c � n L 7\ U) Q 0 ?� ac U z m U Y Q U ❑ ❑ O Z 0 g J 0 � FL• a 0 ❑ -Oj aZ w�- tl01❑ 0mw :) nF 7� W a II T a U N x Zzm ❑ f0 C� Z O ❑ ❑ u� pu�i N U Z U) u I I U � O �W H V.� d LL U U D U c Z❑ Q L) -1 � C n Q O� f ZLU C7 ❑ vai < _jy > a U W p awCO0 wa ❑ U gw c l w a Z ❑ ❑ E IL 7 ❑ U C/) W z o w W ❑ H ie 28 of 39 ACCESS ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte, NC 28224 ATTENTION RobbiJones PROJECTID 9030340 LABORATORY REPORT NUMBER 219032205 DATE 03/26/2019 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amic Project Manager, Access Analytical, Inc- aamick@accessanalyticalinc.com - Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 Innovation Park Dr., Baton Rouge, LA 70820. GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 219032205 Page 1 of 11 Page 29 of 39 GCA�L LELAP CERTIFICATE NUMBER: 01955 DOD-ELAP ACCREDITATION NUMBER: 74960 ANALYTICAL RESULTS Deliver To Robbi Jones Prism Laboratories PO Box 240543 Charlotte, NC 28224 800-529-6364 PJ LA Test Iitq 6oA EIAP PERFORMED BY GCAL, LLC 7979Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/26/2019 GOAL Report 319033205 II��I III II II � III II III Project 9030340 Additional Recipients NONE ..ISO �i 17025 s CCR��J d4`~ f�� F^ d $DffRYn Lab Report#: 219032205 Page 2 of 11 Page 30 of 39 �� Report#: 219032205 Project ID: 9030340 Report Date: 03/26/2019 Laboratory Endorsement Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) * Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis — when appended to Client Sample ID Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature GCAL Report 219032205 Lab Report#: 219032205 Page 3 of 11 Page 31 of 39 I� GCAL Report#: 219032205 Project ID: 9030340 Certifications Report Date: 03/26/2019 Certification Certification Number DOD ELAP 74960 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michi an 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Virginia 460215 Washin ton C929 USDA Soil Permit P330-16-00234 Lab Report#: 219032205 Page 4 of 11 Page 32 of 39 do' �L Report#: 219032205 l� Project ID: 9030340 Case Narrative Client: Access Analytical Report: 219032205 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Report Date: 03/26/2019 Lab Report#: 219032205 Page 5 of 11 Page 33 of 39 l� G�/.�L Report#: 219032205 Project ID: 9030340 Sample Summary GCAL ID Client ID Matrix Collect Date/Time 21903220501 MW-05R Water 03/20/201910:40 21903220502 MW-03 Water 03/20/201912:02 Report Date: 03/26/2019 Receive Date/Time 03/22/2019 09:30 03/22/2019 09:30 Lab Report#: 219032205 Page 6 of 11 Page 34 of 39 Report#: 219032205 Project ID: 9030340 Report Date: 03/26/2019 Summary of Compounds Detected MW-05R Collect Date 03/20/2019 10:40 GCAL ID 21903220501 Receive Date 03/22/2019 09:30 Matrix Water SM 5310 B-2011 CAS# Parameter Result DL LOQ Units C-012 Total Organic Carbon 10.5 0.300 2.00 mg/L MW-03 Collect Date 03/20/2019 12:02 GCAL ID 21903220502 Receive Date 03/22/2019 09:30 Matrix Water SM 5310 B-2011 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ Units 9.36 0.300 2.00 mg/L Lab Report#: 219032205 Page 7 of 11 Page 35 of 39 Report#: 219032205 Project ID: 9030340 Sample Results Report Date: 03/26/2019 MW-05R Collect Date 03/20/2019 10:40 GCAL ID 21903220501 Receive Date 03/22/2019 09:30 Matrix Water 5310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 03/23/2019 06:22 PLH 656447 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ 10.5 0.300 2.00 Collect Date 03/20/2019 12:02 GCAL ID 21903220502 MW-�3 Receive Date 03/22/2019 09:30 Matrix Water 5310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 03/23/2019 07:49 PLH 656447 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ Units 9.36 0.300 2.00 mg/L Lab Report#: 219032205 Page 8 of 11 Page 36 of 39 Report#: 219032205 c:1 Project ID: 9030340 General Chemistry QC Summary Report Date: 03/26/2019 Analytical Batch Client ID MB656447 LCS656447 656447 GCALID 1908323 1908324 Sample Type MB LCS Prep Date NA NA Analysis Date 03/22/2019 22:33 03/22/2019 21:55 Matrix Water Water SM 5310 B-2011 Units mg/L Spike Result "/oR Control Result DL Added Limlts%R Total Organic Carbon C-012 0.300U 0.300 50.0 50.9 102 90 - 110 Lab Report#: 219032205 Page 9 of 11 Page 37 of 39 r m o- Client 10'. 4565 - Access Analytical E 0 5013, 219032205 o PM' DLH N PRISM Fuu. c ,.. :.. Anel loco} b y Cn Eo-: r•+,Ir : ntol 5o1u11ans SUBCONTRACT ORDER — '.n•ri, .. �,m .'I Ar'- USAC[_ Prism Laboratories, Inc. I y Sl'_ Other _, 9030340 NIA_ ._ +SLNIIING I,A0011ATU"i RIiCF VINytrUJL='QRV, Prism Laboratories, Inc. Gulf Coast Analytical Labs, Inc. P. O. Box 240543 107E 1 Courscy Blvd Charlotte, NC 28224-0543 Baton Rouge, LA 70816 a, a`l CiezC� a�C Phone. 900-529-6364 Phonc :(225) 769.4900 Fax- 704-525-0409 Project Munagcc Pax: (225) 767-5717 I� � �cl ^ ,� Robbi A. )ones Analysis Due Expires ID Comments yy�1.ah,rarary I + •' W r As ` Sarpple ID: 903034MI Water Sampled:03120/19 10:40 i TOC (Sub) 04/17/19 10:40 CmrrnkHu v 5ryNlgrJ 2. A f 4ce H LL VVA SarnpreID; 903W40.02 Wwer Sonrpledr0312011912:02 1 r 1 L"j r Q� JJ.. •• TCC (Sub) 04/17/1912:02 ^^ Cnafrjjaen, SMN+G'ML 3 1 2 -r�.- I! c ILL1p1] BY C DIN R.Yc iYcll k}' t }.•Il •4 b Relta.ed Ry D+,r arc.•;syl1 r Dars• C.� RCI aaecl Tay . Dare Received By Dile w Rc1c:L.W Hy D,ur Received Hy Daw EQ Pager 1 01 1 0 0 Page 38 of 39 2 $ ❑ � ❑ � ❑ � Cl. ❑ � ❑ � ❑ ❑ � ❑ \ & \ { c 2 , � E / 0 ca 0 g § § 2 E k / % \ o $ f 9 E \ § 0 _0 0 coq 0 v2 E �_ \ § C / § 2 _q E E �§ � � ƒ % 0 7 \ E W � 2 E 2 7 m 2 § % 2 e m / / ) L ƒ C f / § CD / _ f / 0 § $ / E b y 7 9 0 0 E L / 0 0 / / w $ 7 \ / \ 3 m / 7 v _0 o m 2 7 / / / / / / / Q J \ E k J ) J _ 2 / / / 0 § ) D ) E E U 3 / 12 / k k d $ o 2 0 2 CL E o t � 3 e _ CN 0 ki § 2E E i _ \ j / \ 12CL / 7 � 2 E o § $ 12 �ƒLO cli u. En® @ \ \ w CL / f } k q = / / # & � / m v# �@ I Page 3 dag 1 LP R I S M Full -Service Analytical & Environmental Solutions LABORATORIES, INC. Anchor QEA of North Carolina, PLLC Brian Gant 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 NC Drinking Water Cert No. 37735 SC Certification No. 99012 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Lab Submittal Date: 03/22/2019 Prism Work Order: 9030362 Case Narrative 4/9/19 13:45 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: TOC analysis was subcontracted to GCAL. Laboratory report is attached. Prism Summary of Detections does not include subcontracted data. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. )� �_ a_. In-- Robbi A. Jones President/Project Manager Data Qualifiers Key Reference: &.I - Reviewed By Robbi A. Jones President/Project Manager A Probable laboratory contamination. J Detected but below the Reporting Limit; therefore, result is an estimated concentration (CLP J-Flag). BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 1 of 41 Sample Receipt Summary R I IS M Full -Service Analytical R Environmental Solutions 04/09/2019 &GIE LABORATORIES, INC. Prism Work Order: 9030362 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-01 9030362-01 Water 03/21/19 13:13 03/22/19 8:25 MW-02 9030362-02 Water 03/21/19 11:28 03/22/19 8:25 MW-06 9030362-03 Water 03/21/19 9:58 03/22/19 8:25 Trip Blank (1) 9030362-04 Water 03/21/19 0:00 03/22/19 8:25 Trip Blank (2) 9030362-05 Water 03/21/19 0:00 03/22/19 8:25 Samples were received in good condition at 3.1 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 2 of 41 /r P R I S M Full -Service Analytical s Environmental Solutions LABORATOR Summary of Detections 04/09/201S Prism Work Order: 9030362 Prism ID Client ID Parameter Method Result Units 9030362-01 MW-01 Chloride 9056A 850 .1 ug/L 9030362-01 MW-01 Nitrate as N 9056A 57 J ug/L 9030362-01 MW-01 Biochemical Oxygen Demand SM5210 B 13000 ug/L 9030362-01 MW-01 Chemical Oxygen Demand SM5220 D 97000 ug/L 9030362-01 MW-01 Ferrous Iron SM3500-Fe D 37000 ug/L 9030362-01 MW-01 Sulfide SM4500-S F 1200 J ug/L 9030362-01 MW-01 Total Alkalinity to pH 4.5 SM2320 B 110000 ug/L 9030362-01 MW-01 Mercury 7470A 0.043 J ug/L 9030362-01 MW-01 Arsenic 6020B 0.64 J ug/L 9030362-01 MW-01 Barium 6020B 100 ug/L 9030362-01 MW-01 Beryllium 6020B 0.062 J ug/L 9030362-01 MW-01 Cadmium 6020B 1.1 ug/L 9030362-01 MW-01 Chromium 6020B 0.84 J ug/L 9030362-01 MW-01 Cobalt 6020B 180 ug/L 9030362-01 MW-01 Copper 6020B 9.9 ug/L 9030362-01 MW-01 Lead 6020B 0.72 J ug/L 9030362-01 MW-01 Nickel 6020B 15 ug/L 9030362-01 MW-01 Thallium 6020B 0.52 .1 ug/L 9030362-01 MW-01 Vanadium 6020B 1.1 ug/L 9030362-01 MW-01 Zinc 6020B 38 ug/L 9030362-01 MW-01 1,1-Dichloroethane 8260B 4.3 ug/L 9030362-01 MW-01 1,2-Dichlorobenzene 8260B 0.26 J ug/L 9030362-01 MW-01 1,4-Dichlorobenzene 8260B 13 ug/L 9030362-01 MW-01 Acetone 8260B 32 ug/L 9030362-01 MW-01 Benzene 8260B 2.3 ug/L 9030362-01 MW-01 Chlorobenzene 8260B 3.2 ug/L 9030362-01 MW-01 cis-1,2-Dichloroethylene 8260B 6.9 ug/L 9030362-01 MW-01 m,p-Xylenes 8260B 1.9 ug/L 9030362-01 MW-01 o-Xylene 8260B 1.4 ug/L 9030362-01 MW-01 Tetrachloroethylene 8260B 0.66 ug/L 9030362-01 MW-01 Trichloroethylene 8260B 0.81 ug/L 9030362-01 MW-01 Xylenes, total 8260B 3.3 ug/L 9030362-02 MW-02 Chloride 9056A 19000 ug/L 9030362-02 MW-02 Nitrate as N 9056A 340 ug/L 9030362-02 MW-02 Sulfate 9056A 10000 ug/L 9030362-02 MW-02 Biochemical Oxygen Demand SM5210 B 1000 J ug/L 9030362-02 MW-02 Chemical Oxygen Demand SM5220 D 27000 J ug/L 9030362-02 MW-02 Sulfide SM4500-S F 1200 J ug/L 9030362-02 MW-02 Total Alkalinity to pH 4.5 SM2320 B 39000 ug/L 9030362-02 MW-02 Mercury 7470A 0.058 J ug/L 9030362-02 MW-02 Arsenic 6020B 0.87 J ug/L 9030362-02 MW-02 Barium 6020B 50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 3 of 41 /P R I S Full -Service Analytical Environmental Solutions � LABORATORIES, INC. Summary of Detections 04/09/201S Prism Work Order: 9030362 Prism ID Client ID Parameter Method Result Units 9030362-02 MW-02 Beryllium 6020B 0.15 J ug/L 9030362-02 MW-02 Chromium 6020B 5.9 ug/L 9030362-02 MW-02 Cobalt 6020B 13 ug/L 9030362-02 MW-02 Copper 6020B 5.2 ug/L 9030362-02 MW-02 Lead 6020B 1.5 ug/L 9030362-02 MW-02 Nickel 6020B 3.9 ug/L 9030362-02 MW-02 Thallium 6020B 0.12 J ug/L 9030362-02 MW-02 Vanadium 6020B 7.0 ug/L 9030362-02 MW-02 Zinc 6020B 29 ug/L 9030362-02 MW-02 1,1-Dichloroethane 8260B 0.35 .1 ug/L 9030362-02 MW-02 Acetone 8260B 6.3 ug/L 9030362-02 MW-02 cis-1,2-Dichloroethylene 8260B 0.55 ug/L 9030362-02 MW-02 1,4-Dioxane 8260B SIM 2.8 J ug/L 9030362-03 MW-06 Chloride 9056A 1100 ug/L 9030362-03 MW-06 Nitrate as N 9056A 590 ug/L 9030362-03 MW-06 Sulfate 9056A 1100 J ug/L 9030362-03 MW-06 Sulfide SM4500-S F 2700 ug/L 9030362-03 MW-06 Total Alkalinity to pH 4.5 SM2320 B 22000 ug/L 9030362-03 MW-06 Arsenic 6020B 0.17 1 ug/L 9030362-03 MW-06 Barium 6020B 56 ug/L 9030362-03 MW-06 Beryllium 6020B 0.094 J ug/L 9030362-03 MW-06 Cadmium 6020B 0.20 J ug/L 9030362-03 MW-06 Chromium 6020B 0.77 J ug/L 9030362-03 MW-06 Cobalt 6020B 5.9 ug/L 9030362-03 MW-06 Copper 6020B 3.8 J ug/L 9030362-03 MW-06 Lead 6020B 0.10 J ug/L 9030362-03 MW-06 Nickel 6020B 19 ug/L 9030362-03 MW-06 Thallium 6020B 0.43 J ug/L 9030362-03 MW-06 Vanadium 6020B 0.95 J ug/L 9030362-03 MW-06 Zinc 6020B 28 ug/L 9030362-03 MW-06 1,1-Dichloroethane 8260B 2.2 ug/L 9030362-03 MW-06 cis-1,2-Dichloroethylene 8260B 1.6 ug/L 9030362-03 MW-06 m,p-Xylenes 8260B 0.51 1 ug/L 9030362-03 MW-06 Methylene Chloride 8260B 0.61 A, J ug/L 9030362-03 MW-06 Trichloroethylene 8260B 0.26 J ug/L 9030362-03 MW-06 Xylenes, total 8260B 0.51 J ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 4 of 41 %j6P R I S M Full -Service Analytical Environmental Solutions LABORATORIES, INC. Laboratory Report 04/09/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: MW-01 Prism Sample ID: 9030362-01 Prism Work Order: 9030362 Time Collected: 03/21/19 13:13 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report Limit MDL Dilution Factor Method Analysis Analyst Date/Time Batch ID Anions by Ion Chromatography Chloride 850 J ug/L NE 1000 120 1 9056A 3/22/19 14:34 BMS P9C0454 Nitrate as N 57 J ug/L 10000 100 41 1 9056A 3/22/19 14:34 BMS P9C0454 Sulfate <490 ug/L 250000 2000 490 1 9056A 3/22/19 14:34 BMS P9C0454 General Chemistry Parameters Biochemical Oxygen Demand 13000 ug/L NE 2000 200 1 SM5210 B 3/22/19 11:41 CBM P9C0550 Chemical Oxygen Demand 97000 ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron 37000 ug/L NE 5000 1100 1 SM3500-Fe D 3/22/19 13:10 BMS P9C0445 Sulfide 1200 J ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 110000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury 0.043 J ug/L 0.2 0.20 0.036 1 7470A 3/26/19 13:10 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 17:50 JAB P9C0451 Arsenic 0.64 J ug/L 10 1.0 0.031 1 6020B 3/28/19 17:50 JAB P9C0451 Barium 100 ug/L 100 5.0 0.97 1 6020B 3/28/19 17:50 JAB P9C0451 Beryllium 0.062 J ug/L 1 1.0 0.057 1 6020B 3/28/19 17:50 JAB P9C0451 Cadmium 1.1 ug/L 1 1.0 0.078 1 6020B 3/28/19 17:50 JAB P9C0451 Chromium 0.84 J ug/L 10 2.0 0.19 1 6020B 3/28/19 17:50 JAB P9C0451 Cobalt 180 ug/L 10 1.0 0.0071 1 6020B 3/28/19 17:50 JAB P9C0451 Copper 9.9 ug/L 10 5.0 0.22 1 6020B 3/28/19 17:50 JAB P9C0451 Lead 0.72 J ug/L 10 1.0 0.093 1 6020B 3/28/19 17:50 JAB P9C0451 Nickel 15 ug/L 50 2.0 0.85 1 6020B 3/28/19 17:50 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 17:50 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 17:50 JAB P9C0451 Thallium 0.52 J ug/L 5.5 1.0 0.099 1 6020B 3/28/19 17:50 JAB P9C0451 Vanadium 1.1 ug/L 25 1.0 0.10 1 6020B 3/28/19 17:50 JAB P9C0451 Zinc 38 ug/L 10 10 2.8 1 6020B 3/28/19 17:50 JAB P9C0451 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/29/19 17:28 KDM P9C0588 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:28 KDM P9C0588 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/29/19 17:28 KDM P9C0588 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:28 KDM P9C0588 1,1-Dichloroethane 4.3 ug/L 5 0.50 0.083 1 8260B 3/29/19 17:28 KDM P9C0588 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 17:28 KDM P9C0588 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/29/19 17:28 KDM P9C0588 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/29/19 17:28 KDM P9C0588 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/29/19 17:28 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 5 of 41 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/09/2019 Client Sample ID: MW-01 Prism Sample ID: 9030362-01 Prism Work Order: 9030362 Time Collected: 03/21/19 13:13 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene 0.26 J ug/L 5 0.50 0.076 1 8260B 3/29/19 17:28 KDM P9C0588 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:28 KDM P9C0588 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:28 KDM P9C0588 1,4-Dichlorobenzene 13 ug/L 1 0.50 0.050 1 8260B 3/29/19 17:28 KDM P9C0588 Acetone 32 ug/L 100 5.0 0.31 1 8260B 3/29/19 17:28 KDM P9C0588 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/29/19 17:28 KDM P9C0588 Benzene 2.3 ug/L 1 0.50 0.048 1 8260B 3/29/19 17:28 KDM P9C0588 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/29/19 17:28 KDM P9C0588 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:28 KDM P9C0588 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/29/19 17:28 KDM P9C0588 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/29/19 17:28 KDM P9C0588 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/29/19 17:28 KDM P9C0588 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:28 KDM P9C0588 Chlorobenzene 3.2 ug/L 3 0.50 0.062 1 8260B 3/29/19 17:28 KDM P9C0588 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/29/19 17:28 KDM P9C0588 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 17:28 KDM P9C0588 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:28 KDM P9C0588 cis-1,2-Dichloroethylene 6.9 ug/L 5 0.50 0.056 1 8260B 3/29/19 17:28 KDM P9C0588 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:28 KDM P9C0588 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/29/19 17:28 KDM P9C0588 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/29/19 17:28 KDM P9C0588 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:28 KDM P9C0588 m,p-Xylenes 1.9 ug/L NE 1.0 0.12 1 8260B 3/29/19 17:28 KDM P9C0588 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/29/19 17:28 KDM P9C0588 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/29/19 17:28 KDM P9C0588 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/29/19 17:28 KDM P9C0588 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/29/19 17:28 KDM P9C0588 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/29/19 17:28 KDM P9C0588 o-Xylene 1.4 ug/L NE 0.50 0.044 1 8260B 3/29/19 17:28 KDM P9C0588 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/29/19 17:28 KDM P9C0588 Tetrachloroethylene 0.66 ug/L 1 0.50 0.098 1 8260B 3/29/19 17:28 KDM P9C0588 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/29/19 17:28 KDM P9C0588 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/29/19 17:28 KDM P9C0588 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/29/19 17:28 KDM P9C0588 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/29/19 17:28 KDM P9C0588 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/29/19 17:28 KDM P9C0588 Trichloroethylene 0.81 ug/L 1 0.50 0.078 1 8260B 3/29/19 17:28 KDM P9C0588 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:28 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 6 of 41 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/09/2019 Client Sample ID: MW-01 Prism Sample ID: 9030362-01 Prism Work Order: 9030362 Time Collected: 03/21/19 13:13 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/29/19 17:28 KDM P9C0588 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/29/19 17:28 KDM P9C0588 Xylenes, total 3.3 ug/L 5 1.5 0.15 1 8260B 3/29/19 17:28 KDM P9C0588 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 94 % 77-123 Volatile Organic Compounds by GUMS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 4/1/19 15:51 JLB P9D0010 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 7 of 41 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/09/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: MW-02 Prism Sample ID: 9030362-02 Prism Work Order: 9030362 Time Collected: 03/21/19 11:28 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 19000 ug/L NE 1000 120 1 9056A 3/22/19 14:50 BMS P9C0454 Nitrate as N 340 ug/L 10000 100 41 1 9056A 3/22/19 14:50 BMS P9C0454 Sulfate 10000 ug/L 250000 2000 490 1 9056A 3/22/19 14:50 BMS P9C0454 General Chemistry Parameters Biochemical Oxygen Demand 1000 J ug/L NE 2000 200 1 SM5210 B 3/22/19 11:41 CBM P9C0550 Chemical Oxygen Demand 27000 J ug/L NE 50000 17000 1 SM5220 D 3/22/19 12:44 SLS P9C0446 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron <46 ug/L NE 200 46 1 SM3500-Fe D 3/22/19 13:10 BMS P9C0445 Sulfide 1200 J ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 39000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury 0.058 J ug/L 0.2 0.20 0.036 1 7470A 3/26/19 13:14 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 17:56 JAB P9C0451 Arsenic 0.87 J ug/L 10 1.0 0.031 1 6020B 3/28/19 17:56 JAB P9C0451 Barium 50 ug/L 100 5.0 0.97 1 6020B 3/28/19 17:56 JAB P9C0451 Beryllium 0.15 J ug/L 1 1.0 0.057 1 6020B 3/28/19 17:56 JAB P9C0451 Cadmium <0.078 ug/L 1 1.0 0.078 1 6020B 3/28/19 17:56 JAB P9C0451 Chromium 5.9 ug/L 10 2.0 0.19 1 6020B 3/28/19 17:56 JAB P9C0451 Cobalt 13 ug/L 10 1.0 0.0071 1 6020B 3/28/19 17:56 JAB P9C0451 Copper 5.2 ug/L 10 5.0 0.22 1 6020B 3/28/19 17:56 JAB P9C0451 Lead 1.5 ug/L 10 1.0 0.093 1 6020B 3/28/19 17:56 JAB P9C0451 Nickel 3.9 ug/L 50 2.0 0.85 1 6020B 3/28/19 17:56 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 17:56 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 17:56 JAB P9C0451 Thallium 0.12 J ug/L 5.5 1.0 0.099 1 6020B 3/28/19 17:56 JAB P9C0451 Vanadium 7.0 ug/L 25 1.0 0.10 1 6020B 3/28/19 17:56 JAB P9C0451 Zinc 29 ug/L 10 10 2.8 1 6020B 3/28/19 17:56 JAB P9C0451 Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/29/19 17:54 KDM P9C0588 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:54 KDM P9C0588 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/29/19 17:54 KDM P9C0588 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:54 KDM P9C0588 1,1-Dichloroethane 0.35 J ug/L 5 0.50 0.083 1 8260B 3/29/19 17:54 KDM P9C0588 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 17:54 KDM P9C0588 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/29/19 17:54 KDM P9C0588 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/29/19 17:54 KDM P9C0588 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/29/19 17:54 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 8 of 41 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/09/2019 Client Sample ID: MW-02 Prism Sample ID: 9030362-02 Prism Work Order: 9030362 Time Collected: 03/21/19 11:28 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 17:54 KDM P9C0588 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:54 KDM P9C0588 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:54 KDM P9C0588 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/29/19 17:54 KDM P9C0588 Acetone 6.3 ug/L 100 5.0 0.31 1 8260B 3/29/19 17:54 KDM P9C0588 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/29/19 17:54 KDM P9C0588 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/29/19 17:54 KDM P9C0588 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/29/19 17:54 KDM P9C0588 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:54 KDM P9C0588 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/29/19 17:54 KDM P9C0588 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/29/19 17:54 KDM P9C0588 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/29/19 17:54 KDM P9C0588 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:54 KDM P9C0588 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/29/19 17:54 KDM P9C0588 Chloroethane <0,22 ug/L 10 0.50 0.22 1 8260B 3/29/19 17:54 KDM P9C0588 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 17:54 KDM P9C0588 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:54 KDM P9C0588 cis-1,2-Dichloroethylene 0.55 ug/L 5 0.50 0.056 1 8260B 3/29/19 17:54 KDM P9C0588 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:54 KDM P9C0588 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/29/19 17:54 KDM P9C0588 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/29/19 17:54 KDM P9C0588 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:54 KDM P9C0588 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/29/19 17:54 KDM P9C0588 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/29/19 17:54 KDM P9C0588 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/29/19 17:54 KDM P9C0588 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/29/19 17:54 KDM P9C0588 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/29/19 17:54 KDM P9C0588 Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/29/19 17:54 KDM P9C0588 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/29/19 17:54 KDM P9C0588 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/29/19 17:54 KDM P9C0588 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/29/19 17:54 KDM P9C0588 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/29/19 17:54 KDM P9C0588 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/29/19 17:54 KDM P9C0588 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/29/19 17:54 KDM P9C0588 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/29/19 17:54 KDM P9C0588 trans- 1,4-Dich loro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/29/19 17:54 KDM P9C0588 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/29/19 17:54 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 9 of 41 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Laboratory Report 04/09/2019 Project: Jackson Cty Landfill (Permit Client Sample ID: MW-02 50-02) Prism Sample ID: 9030362-02 Project No.: 50-02 Prism Work Order: 9030362 Sample Matrix: Water Time Collected: 03/21/19 11:28 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:54 KDM P9C0588 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/29/19 17:54 KDM P9C0588 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/29/19 17:54 KDM P9C0588 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/29/19 17:54 KDM P9C0588 Surrogate Recovery Control Limits 4-Bromofluorobenzene 100 % 80-124 Dibromofluoromethane 102 % 75-129 Toluene-d8 92 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane 2.8 J ug/L 10 3.0 0.14 1 8260B SIM 4/1119 16:16 JLB P9D0010 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 10 of 41 Laboratory Report Full -Service P R S M Analytical & Environmental LABORATORIES INC. Solutions 04/09/2019 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: MW-06 Attn: Brian Gant 50-02) Prism Sample ID: 9030362-03 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030362 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/21/19 09:58 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Anions by Ion Chromatography Chloride 1100 ug/L NE 1000 120 1 9056A 3/22/19 13:45 BMS P9C0454 Nitrate as N 590 ug/L 10000 100 41 1 9056A 3/22/19 13:45 BMS P9C0454 Sulfate 1100 J ug/L 250000 2000 490 1 9056A 3/22/19 13:45 BMS P9C0454 General Chemistry Parameters Biochemical Oxygen Demand <200 ug/L NE 2000 200 1 SM5210 B 3/22/19 11:41 CBM P9C0550 Chemical Oxygen Demand <17000 ug/L NE 50000 17000 1 SM5220 D 3/27/19 9:59 SLS P9C0516 Cyanide <5.0 ug/L 10 25 5.0 5 9014 3/25/19 14:35 BMS P9C0418 Ferrous Iron <46 ug/L NE 200 46 1 SM3500-Fe D 3/22/19 13:10 BMS P9C0445 Sulfide 2700 ug/L 1000 2000 830 1 SM4500-S F 3/26/19 12:45 CBM P9C0532 Total Alkalinity to pH 4.5 22000 ug/L NE 5000 770 1 SM2320 B 3/29/19 10:10 CLB P9C0574 Total Metals Mercury <0.036 ug/L 0.2 0.20 0.036 1 7470A 3/26/19 13:18 MMR P9C0474 Antimony <0.19 ug/L 6 1.0 0.19 1 6020B 3/28/19 18:03 JAB P9C0451 Arsenic 0.17 J ug/L 10 1.0 0.031 1 6020B 3/28/19 18:03 JAB P9C0451 Barium 56 ug/L 100 5.0 0.97 1 6020B 3/28/19 18:03 JAB P9C0451 Beryllium 0.094 J ug/L 1 1.0 0.057 1 6020B 3/28/19 18:03 JAB P9C0451 Cadmium 0.20 J ug/L 1 1.0 0.078 1 6020B 3/28/19 18:03 JAB P9C0451 Chromium 0.77 J ug/L 10 2.0 0.19 1 6020B 3/28/19 18:03 JAB P9C0451 Cobalt 5.9 ug/L 10 1.0 0.0071 1 6020B 3/28/19 18:03 JAB P9C0451 Copper 3.8 J ug/L 10 5.0 0.22 1 6020B 3/28/19 18:03 JAB P9C0451 Lead 0.10 J ug/L 10 1.0 0.093 1 6020B 3/28/19 18:03 JAB P9C0451 Nickel 19 ug/L 50 2.0 0.85 1 6020B 3/28/19 18:03 JAB P9C0451 Selenium <0.63 ug/L 10 5.0 0.63 1 6020B 3/28/19 18:03 JAB P9C0451 Silver <0.063 ug/L 10 5.0 0.063 1 6020B 3/28/19 18:03 JAB P9C0451 Thallium 0.43 J ug/L 5.5 1.0 0.099 1 6020B 3/28/19 18:03 JAB P9C0451 Vanadium 0.95 J ug/L 25 1.0 0.10 1 6020B 3128/19 18:03 JAB P9C0451 Zinc 28 ug/L 10 10 2.8 1 6020B 3/28/19 18:03 JAB P9C0451 Volatile Organic Compounds by GC/MS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/29/19 18:20 KDM P9C0588 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 18:20 KDM P9C0588 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/29/19 18:20 KDM P9C0588 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 18:20 KDM P9C0588 1,1-Dichloroethane 2.2 ug/L 5 0.50 0.083 1 8260B 3/29/19 18:20 KDM P9C0588 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 18:20 KDM P9C0588 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/29/19 18:20 KDM P9C0588 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/29/19 18:20 KDM P9C0588 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/29/19 18:20 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 11 of 41 Full -Service Analytical & P R S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/09/2019 Client Sample ID: MW-06 Prism Sample ID: 9030362-03 Prism Work Order: 9030362 Time Collected: 03/21/19 09:58 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 18:20 KDM P9C0588 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 18:20 KDM P9C0588 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 18:20 KDM P9C0588 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/29/19 18:20 KDM P9C0588 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/29/19 18:20 KDM P9C0588 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/29/19 18:20 KDM P9C0588 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/29/19 18:20 KDM P9C0588 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/29/19 18:20 KDM P9C0588 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 18:20 KDM P9C0588 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/29/19 18:20 KDM P9C0588 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/29/19 18:20 KDM P9C0588 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/29/19 18:20 KDM P9C0588 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 18:20 KDM P9C0588 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/29/19 18:20 KDM P9C0588 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/29/19 18:20 KDM P9C0588 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 18:20 KDM P9C0588 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 18:20 KDM P9C0588 cis-1,2-Dichloroethylene 1.6 ug/L 5 0.50 0.056 1 8260B 3/29/19 18:20 KDM P9C0588 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 18:20 KDM P9C0588 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/29/19 18:20 KDM P9C0588 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/29/19 18:20 KDM P9C0588 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 18:20 KDM P9C0588 m,p-Xylenes 0.51 J ug/L NE 1.0 0.12 1 8260B 3/29/19 18:20 KDM P9C0588 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/29/19 18:20 KDM P9C0588 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/29/19 18:20 KDM P9C0588 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/29/19 18:20 KDM P9C0588 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/29/19 18:20 KDM P9C0588 Methylene Chloride 0.61 A, J ug/L 1 1.0 0.083 1 8260B 3/29/19 18:20 KDM P9C0588 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/29/19 18:20 KDM P9C0588 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/29/19 18:20 KDM P9C0588 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/29/19 18:20 KDM P9C0588 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/29/19 18:20 KDM P9C0588 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/29/19 18:20 KDM P9C0588 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/29/19 18:20 KDM P9C0588 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/29/19 18:20 KDM P9C0588 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/29/19 18:20 KDM P9C0588 Trichloroethylene 0.26 J ug/L 1 0.50 0.078 1 8260B 3/29/19 18:20 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 12 of 41 �Full-Service Analytical P R I S M Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Laboratory Report 04/09/2019 Client Sample ID: MW-06 Prism Sample ID: 9030362-03 Prism Work Order: 9030362 Time Collected: 03/21/19 09:58 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 18:20 KDM P9C0588 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/29/19 18:20 KDM P9C0588 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/29/19 18:20 KDM P9C0588 Xylenes, total 0.51 J ug/L 5 1.5 0.15 1 8260B 3/29/19 18:20 KDM P9C0588 Surrogate Recovery Control Limits 4-Bromofluorobenzene 98 % 80-124 Dibromofluoromethane 100 % 75-129 Toluene-d8 93 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 4/1/19 16:41 JLB P9D0010 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 13 of 41 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/09/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: Trip Blank (1) Prism Sample ID: 9030362-04 Prism Work Order: 9030362 Time Collected: 03/21/19 00:00 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/29/19 16:37 KDM P9C0588 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 16:37 KDM P9C0588 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/29/19 16:37 KDM P9C0588 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 16:37 KDM P9C0588 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 16:37 KDM P9C0588 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 16:37 KDM P9C0588 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/29/19 16:37 KDM P9C0588 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/29/19 16:37 KDM P9C0588 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/29/19 16:37 KDM P9C0588 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 16:37 KDM P9C0588 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 16:37 KDM P9C0588 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 16:37 KDM P9C0588 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/29/19 16:37 KDM P9C0588 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/29/19 16:37 KDM P9C0588 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/29/19 16:37 KDM P9C0588 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/29/19 16:37 KDM P9C0588 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/29/19 16:37 KDM P9C0588 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 16:37 KDM P9C0588 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/29/19 16:37 KDM P9C0588 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/29/19 16:37 KDM P9C0588 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/29/19 16:37 KDM P9C0588 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 16:37 KDM P9C0588 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/29/19 16:37 KDM P9C0588 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/29/19 16:37 KDM P9C0588 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 16:37 KDM P9C0588 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 16:37 KDM P9C0588 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/29/19 16:37 KDM P9C0588 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 16:37 KDM P9C0588 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/29/19 16:37 KDM P9C0588 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/29/19 16:37 KDM P9C0588 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 16:37 KDM P9C0588 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/29/19 16:37 KDM P9C0588 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/29/19 16:37 KDM P9C0588 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/29/19 16:37 KDM P9C0588 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/29/19 16:37 KDM P9C0588 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/29/19 16:37 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 14 of 41 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 04/09/2019 LABORATORIES INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: Trip Blank (1) Attn: Brian Gant 50-02) Prism Sample ID: 9030362-04 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030362 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/21/19 00:00 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/29/19 16:37 KDM P9C0588 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/29/19 16:37 KDM P9C0588 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/29/19 16:37 KDM P9C0588 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/29/19 16:37 KDM P9C0588 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/29/19 16:37 KDM P9C0588 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/29/19 16:37 KDM P9C0588 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/29/19 16:37 KDM P9C0588 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/29/19 16:37 KDM P9C0588 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/29/19 16:37 KDM P9C0588 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/29/19 16:37 KDM P9C0588 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 16:37 KDM P9C0588 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/29/19 16:37 KDM P9C0588 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/29/19 16:37 KDM P9C0588 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/29/19 16:37 KDM P9C0588 Surrogate Recovery Control Limits 4-Bromofluorobenzene 96 % 80-124 Dibromofluoromethane 101 % 75-129 Toluene-d8 91 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 4/1/19 15:25 JLB P9D0010 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 15 of 41 �Full-Service Analytical s P R I S M Environmental Solutions LABORATORIES INC. Laboratory Report 04/09/2019 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Sample Matrix: Water Client Sample ID: Trip Blank (2) Prism Sample ID: 9030362-05 Prism Work Order: 9030362 Time Collected: 03/21/19 00:00 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Volatile Organic Compounds by GUMS 1, 1, 1,2-Tetrachloroethane <0.11 ug/L 5 0.50 0.11 1 8260B 3/29/19 17:03 KDM P9C0588 1, 1, 1 -Trichloroethane <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:03 KDM P9C0588 1,1,2,2-Tetrachloroethane <0.036 ug/L 3 0.50 0.036 1 8260B 3/29/19 17:03 KDM P9C0588 1,1,2-Trichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:03 KDM P9C0588 1,1-Dichloroethane <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 17:03 KDM P9C0588 1,1-Dichloroethylene <0.083 ug/L 5 0.50 0.083 1 8260B 3/29/19 17:03 KDM P9C0588 1,2,3-Trichloropropane <0.14 ug/L 1 1.0 0.14 1 8260B 3/29/19 17:03 KDM P9C0588 1,2-Dibromo-3-chloropropane <0.17 ug/L 13 2.0 0.17 1 8260B 3/29/19 17:03 KDM P9C0588 1,2-Dibromoethane <0.051 ug/L 1 0.50 0.051 1 8260B 3/29/19 17:03 KDM P9C0588 1,2-Dichlorobenzene <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 17:03 KDM P9C0588 1,2-Dichloroethane <0.066 ug/L 1 0.50 0.066 1 8260B 3/29/19 17:03 KDM P9C0588 1,2-Dichloropropane <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:03 KDM P9C0588 1,4-Dichlorobenzene <0.050 ug/L 1 0.50 0.050 1 8260B 3/29/19 17:03 KDM P9C0588 Acetone <0.31 ug/L 100 5.0 0.31 1 8260B 3/29/19 17:03 KDM P9C0588 Acrylonitrile <0.20 ug/L 200 20 0.20 1 8260B 3/29/19 17:03 KDM P9C0588 Benzene <0.048 ug/L 1 0.50 0.048 1 8260B 3/29/19 17:03 KDM P9C0588 Bromochloromethane <0.14 ug/L 3 0.50 0.14 1 8260B 3/29/19 17:03 KDM P9C0588 Bromodichloromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:03 KDM P9C0588 Bromoform <0.040 ug/L 3 1.0 0.040 1 8260B 3/29/19 17:03 KDM P9C0588 Bromomethane <0.18 ug/L 10 1.0 0.18 1 8260B 3/29/19 17:03 KDM P9C0588 Carbon disulfide <0.075 ug/L 100 5.0 0.075 1 8260B 3/29/19 17:03 KDM P9C0588 Carbon Tetrachloride <0.11 ug/L 1 0.50 0.11 1 8260B 3/29/19 17:03 KDM P9C0588 Chlorobenzene <0.062 ug/L 3 0.50 0.062 1 8260B 3/29/19 17:03 KDM P9C0588 Chloroethane <0.22 ug/L 10 0.50 0.22 1 8260B 3/29/19 17:03 KDM P9C0588 Chloroform <0.076 ug/L 5 0.50 0.076 1 8260B 3/29/19 17:03 KDM P9C0588 Chloromethane <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:03 KDM P9C0588 cis- 1,2-Dichloroethylene <0.056 ug/L 5 0.50 0.056 1 8260B 3/29/19 17:03 KDM P9C0588 cis- 1,3-Dichloropropylene <0.079 ug/L 1 0.50 0.079 1 8260B 3/29/19 17:03 KDM P9C0588 Dibromochloromethane <0.081 ug/L 3 0.50 0.081 1 8260B 3/29/19 17:03 KDM P9C0588 Dibromomethane <0.065 ug/L 10 0.50 0.065 1 8260B 3/29/19 17:03 KDM P9C0588 Ethylbenzene <0.061 ug/L 1 0.50 0.061 1 8260B 3/29/19 17:03 KDM P9C0588 m,p-Xylenes <0.12 ug/L NE 1.0 0.12 1 8260B 3/29/19 17:03 KDM P9C0588 Methyl Butyl Ketone (2-Hexanone) <0.065 ug/L 50 5.0 0.065 1 8260B 3/29/19 17:03 KDM P9C0588 Methyl Ethyl Ketone (2-Butanone) <0.24 ug/L 100 5.0 0.24 1 8260B 3/29/19 17:03 KDM P9C0588 Methyl Iodide <0.33 ug/L 10 5.0 0.33 1 8260B 3/29/19 17:03 KDM P9C0588 Methyl Isobutyl Ketone <0.078 ug/L 100 5.0 0.078 1 8260B 3/29/19 17:03 KDM P9C0588 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 16 of 41 P R S M Laboratory Report Full -Service Analytical & Environmental Solutions 04/09/2019 LABORATORIES INC. Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Client Sample ID: Trip Blank (2) Attn: Brian Gant 50-02) Prism Sample ID: 9030362-05 231 Haywood Street Project No.: 50-02 Prism Work Order: 9030362 Asheville, NC 28801 Sample Matrix: Water Time Collected: 03/21/19 00:00 Time Submitted: 03/22/19 08:25 Parameter Result Units SWSL Report MDL Dilution Method Analysis Analyst Batch Limit Factor Date/Time ID Methylene Chloride <0.083 ug/L 1 1.0 0.083 1 8260B 3/29/19 17:03 KDM P9C0588 o-Xylene <0.044 ug/L NE 0.50 0.044 1 8260B 3/29/19 17:03 KDM P9C0588 Styrene <0.047 ug/L 1 0.50 0.047 1 8260B 3/29/19 17:03 KDM P9C0588 Tetrachloroethylene <0.098 ug/L 1 0.50 0.098 1 8260B 3/29/19 17:03 KDM P9C0588 Tetrahydrofuran <0.16 ug/L NE 10 0.16 1 8260B 3/29/19 17:03 KDM P9C0588 Toluene <0.044 ug/L 1 0.50 0.044 1 8260B 3/29/19 17:03 KDM P9C0588 trans- 1,2-Dichloroethylene <0.094 ug/L 5 0.50 0.094 1 8260B 3/29/19 17:03 KDM P9C0588 trans- 1,3-Dichloropropylene <0.070 ug/L 1 0.50 0.070 1 8260B 3/29/19 17:03 KDM P9C0588 trans- 1,4-Dichloro-2-butene <0.12 ug/L 100 10 0.12 1 8260B 3/29/19 17:03 KDM P9C0588 Trichloroethylene <0.078 ug/L 1 0.50 0.078 1 8260B 3/29/19 17:03 KDM P9C0588 Trichlorofluoromethane <0.062 ug/L 1 0.50 0.062 1 8260B 3/29/19 17:03 KDM P9C0588 Vinyl acetate <0.060 ug/L 50 2.0 0.060 1 8260B 3/29/19 17:03 KDM P9C0588 Vinyl chloride <0.097 ug/L 1 0.50 0.097 1 8260B 3/29/19 17:03 KDM P9C0588 Xylenes, total <0.15 ug/L 5 1.5 0.15 1 8260B 3/29/19 17:03 KDM P9C0588 Surrogate Recovery Control Limits 4-Bromofluorobenzene 99 % 80-124 Dibromofluoromethane 99 % 75-129 Toluene-d8 95 % 77-123 Volatile Organic Compounds by GC/MS SIM 1,4-Dioxane <0.14 ug/L 10 3.0 0.14 1 8260B SIM 4/1/19 15:00 JLB P9D0010 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 17 of 41 Full -Service Analytical & LIPMVP S M Environmental Solutions OR TORIEB, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO588 - 5030B Blank (P9C0588-BLK1) Prepared & Analyzed: 03/29/19 1,1,1,2-Tetrachloroethane BRL 0.50 ug/L 1,1,1-Trichloroethane BRL 0.50 ug/L 1,1,2,2-Tetrachloroethane BRL 0.50 ug/L 1,1,2-Trichloroethane BRL 0.50 ug/L 1,1-Dichloroethane BRL 0.50 ug/L 1,1-Dichloroethylene BRL 0.50 ug/L 1,2,3-Trichloropropane BRL 1.0 ug/L 1,2-Dibromo-3-chloropropane BRL 2.0 ug/L 1,2-Dibromoethane BRL 0.50 ug/L 1,2-Dichlorobenzene BRL 0.50 ug/L 1,2-Dichloroethane BRL 0.50 ug/L 1,2-Dichloropropane BRL 0.50 ug/L 1,4-Dichlorobenzene BRL 0.50 ug/L Acetone BRL 5.0 ug/L Acrylonitrile BRL 20 ug/L Benzene BRL 0.50 ug/L Bromochloromethane BRL 0.50 ug/L Bromodichloromethane BRL 0.50 ug/L Bromoform BRL 1.0 ug/L Bromomethane BRL 1.0 ug/L Carbon disulfide BRL 5.0 ug/L Carbon Tetrachloride BRL 0.50 ug/L Chlorobenzene BRL 0.50 ug/L Chloroethane BRL 0.50 ug/L Chloroform BRL 0.50 ug/L Chloromethane BRL 0.50 ug/L cis-1,2-Dichloroethylene BRL 0.50 ug/L cis-1,3-Dichloropropylene BRL 0.50 ug/L Dibromochloromethane BRL 0.50 ug/L Dibromomethane BRL 0.50 ug/L Ethylbenzene BRL 0.50 ug/L m,p-Xylenes BRL 1.0 ug/L Methyl Butyl Ketone (2-Hexanone) BRL 5.0 ug/L Methyl Ethyl Ketone (2-Butanone) BRL 5.0 ug/L Methyl Iodide BRL 5.0 ug/L Methyl Isobutyl Ketone BRL 5.0 ug/L Methylene Chloride BRL 1.0 ug/L o-Xylene BRL 0.50 ug/L Styrene BRL 0.50 ug/L Tetrachloroethylene BRL 0.50 ug/L Tetrahydrofuran BRL 10 ug/L Toluene BRL 0.50 ug/L trans- 1,2-Dichloroethylene BRL 0.50 ug/L trans- 1,3-Dichloropropylene BRL 0.50 ug/L trans-1,4-Dichloro-2-butene BRL 10 ug/L Trichloroethylene BRL 0.50 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 18 of 41 PR I S M Full -Service Analytical Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030362 Attn: Brian Gant 50-02) Time Submitted: 3/22/2019 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO588 - 5030B Blank (P9C0588-BLK1) Prepared & Analyzed: 03/29/19 Trichlorofluoromethane BRL 0.50 ug/L Vinyl acetate BRL 2.0 ug/L Vinyl chloride BRL 0.50 ug/L Xylenes, total BRL 1.5 ug/L Surrogate:4-Bromofluorobenzene 49.9 ug/L 50.00 100 80-124 Surrogate: Dibromofluoromethane 51.1 ug/L 50.00 102 75-129 Surrogate: Toluene-d8 46.5 ug/L 50.00 93 77-123 LCS (P9CO588-BSI) Prepared &Analyzed: 03/29/19 1,1,1,2-Tetrachloroethane 21.0 0.50 ug/L 20.00 105 79-134 1,1,1-Trichloroethane 22.0 0.50 ug/L 20.00 110 75-136 1,1,2,2-Tetrachloroethane 19.4 0.50 ug/L 20.00 97 62-127 1,1,2-Trichloroethane 22.4 0.50 ug/L 20.00 112 70-140 1,1-Dichloroethane 22.5 0.50 ug/L 20.00 113 78-130 1,1-Dichloroethylene 23.5 0.50 ug/L 20.00 117 70-154 1,2,3-Trichloropropane 19.1 1.0 ug/L 20.00 95 71-127 1,2-Dibromo-3-chloropropane 16.9 2.0 ug/L 20.00 85 63-134 1,2-Dibromoethane 20.4 0.50 ug/L 20.00 102 77-135 1,2-Dichlorobenzene 18.8 0.50 ug/L 20.00 94 78-128 1,2-Dichloroethane 22.3 0.50 ug/L 20.00 112 68-131 1,2-Dichloropropane 22.3 0.50 ug/L 20.00 112 77-130 1,4-Dichlorobenzene 18.5 0.50 ug/L 20.00 92 75-126 Acetone 65.1 5.0 ug/L 40.00 163 40-166 Acrylonitrile 44.6 20 ug/L 40.00 ill 81-127 Benzene 21.8 0.50 ug/L 20.00 109 77-128 Bromochloromethane 22.9 0.50 ug/L 20.00 115 78-135 Bromodichloromethane 21.8 0.50 ug/L 20.00 109 76-138 Bromoform 19.0 1.0 ug/L 20.00 95 71-135 Bromomethane 22.6 1.0 ug/L 20.00 113 41-168 Carbon disulfide 21.9 5.0 ug/L 20.00 110 59-135 Carbon Tetrachloride 19.9 0.50 ug/L 20.00 100 72-142 Chlorobenzene 19.7 0.50 ug/L 20.00 98 78-119 Chloroethane 24.0 0.50 ug/L 20.00 120 57-142 Chloroform 21.9 0.50 ug/L 20.00 109 77-130 Chloromethane 21.6 0.50 ug/L 20.00 108 47-145 cis-1,2-Dichloroethylene 22.4 0.50 ug/L 20.00 112 76-141 cis-1,3-Dichloropropylene 22.1 0.50 ug/L 20.00 110 65-140 Dibromochloromethane 19.6 0.50 ug/L 20.00 98 75-134 Dibromomethane 22.3 0.50 ug/L 20.00 112 76-138 Ethylbenzene 20.3 0.50 ug/L 20.00 101 80-127 m,p-Xylenes 40.4 1.0 ug/L 40.00 101 77-133 Methyl Butyl Ketone (2-Hexanone) 19.6 5.0 ug/L 20.00 98 64-137 Methyl Ethyl Ketone (2-Butanone) 25.2 5.0 ug/L 20.00 126 71-134 Methyl Iodide 19.3 5.0 ug/L 20.00 96 70-130 Methyl Isobutyl Ketone 23.2 5.0 ug/L 20.00 116 69-134 Methylene Chloride 23.3 1.0 ug/L 20.00 116 73-131 o-Xylene 20.0 0.50 ug/L 20.00 100 78-128 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 19 of 41 P R I S M Full -Service Analytical s Environmental Solutions LABCFATCRIES, NC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030362 Attn: Brian Gant 50-02) Time Submitted: 3/22/2019 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO588 - 5030B LCS (P9C0588-BSI) Prepared &Analyzed: 03/29/19 Styrene 19.4 0.50 ug/L 20.00 97 78-129 Tetrachloroethylene 20.0 0.50 ug/L 20.00 100 80-129 Tetrahydrofuran 22.2 10 ug/L 20.00 ill 70-130 Toluene 22.1 0.50 ug/L 20.00 110 76-131 trans- 1,2-Dichloroethylene 22.2 0.50 ug/L 20.00 ill 76-135 trans- 1,3-Dichloropropylene 22.3 0.50 ug/L 20.00 ill 67-140 trans-1,4-Dichloro-2-butene 15.6 10 ug/L 20.00 78 70-130 Trichloroethylene 21.7 0.50 ug/L 20.00 108 77-133 Trichlorofluoromethane 22.0 0.50 ug/L 20.00 110 62-148 Vinyl acetate 23.6 2.0 ug/L 20.00 118 34-167 Vinyl chloride 18.7 0.50 ug/L 20.00 94 57-141 Xylenes, total 60.4 1.5 ug/L 60.00 101 77-133 Surrogate:4-Bromofluorobenzene 48.4 ug/L 50.00 97 80-124 Surrogate: Dibromofluoromethane 50.6 ug/L 50.00 101 75-129 Surrogate: Toluene-d8 46.4 ug/L 50.00 93 77-123 LCS Dup (P9C0588-113SD1) Prepared &Analyzed: 03/29/19 1,1,1,2-Tetrachloroethane 21.0 0.50 ug/L 20.00 105 79-134 0 20 1,1,1-Trichloroethane 21.5 0.50 ug/L 20.00 107 75-136 3 20 1,1,2,2-Tetrachloroethane 20.1 0.50 ug/L 20.00 100 62-127 4 20 1,1,2-Trichloroethane 22.0 0.50 ug/L 20.00 110 70-140 2 20 1,1-Dichloroethane 21.8 0.50 ug/L 20.00 109 78-130 3 20 1,1-Dichloroethylene 22.2 0.50 ug/L 20.00 ill 70-154 6 20 1,2,3-Trichloropropane 20.3 1.0 ug/L 20.00 102 71-127 6 20 1,2-Dibromo-3-chloropropane 17.0 2.0 ug/L 20.00 85 63-134 0.1 20 1,2-Dibromoethane 20.5 0.50 ug/L 20.00 102 77-135 0.5 20 1,2-Dichlorobenzene 19.0 0.50 ug/L 20.00 95 78-128 1 20 1,2-Dichloroethane 21.8 0.50 ug/L 20.00 109 68-131 3 20 1,2-Dichloropropane 22.0 0.50 ug/L 20.00 110 77-130 1 20 1,4-Dichlorobenzene 18.8 0.50 ug/L 20.00 94 75-126 2 20 Acetone 58.0 5.0 ug/L 40.00 145 40-166 12 20 Acrylonitrile 44.7 20 ug/L 40.00 112 81-127 0.3 20 Benzene 21.2 0.50 ug/L 20.00 106 77-128 3 20 Bromochloromethane 21.8 0.50 ug/L 20.00 109 78-135 5 20 Bromodichloromethane 21.1 0.50 ug/L 20.00 106 76-138 3 20 Bromoform 19.2 1.0 ug/L 20.00 96 71-135 1 20 Bromomethane 22.8 1.0 ug/L 20.00 114 41-168 0.7 20 Carbon disulfide 21.0 5.0 ug/L 20.00 105 59-135 4 20 Carbon Tetrachloride 19.1 0.50 ug/L 20.00 95 72-142 4 20 Chlorobenzene 19.4 0.50 ug/L 20.00 97 78-119 1 20 Chloroethane 22.9 0.50 ug/L 20.00 114 57-142 5 20 Chloroform 21.3 0.50 ug/L 20.00 106 77-130 3 20 Chloromethane 21.2 0.50 ug/L 20.00 106 47-145 1 20 cis-1,2-Dichloroethylene 21.5 0.50 ug/L 20.00 107 76-141 4 20 cis-1,3-Dichloropropylene 21.7 0.50 ug/L 20.00 108 65-140 2 20 Dibromochloromethane 19.4 0.50 ug/L 20.00 97 75-134 0.9 20 Dibromomethane 22.4 0.50 ug/L 20.00 112 76-138 0.2 20 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 20 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS - Quality Control Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO588 - 5030B LCS Dup (P9C0588-BSD1) Prepared & Analyzed: 03/29/19 Ethylbenzene 20.4 0.50 ug/L 20.00 102 80-127 0.6 20 m,p-Xylenes 40.5 1.0 ug/L 40.00 101 77-133 0.3 20 Methyl Butyl Ketone (2-Hexanone) 19.2 5.0 ug/L 20.00 96 64-137 2 20 Methyl Ethyl Ketone (2-Butanone) 22.6 5.0 ug/L 20.00 113 71-134 11 20 Methyl Iodide 18.9 5.0 ug/L 20.00 95 70-130 2 20 Methyl Isobutyl Ketone 22.8 5.0 ug/L 20.00 114 69-134 1 20 Methylene Chloride 22.6 1.0 ug/L 20.00 113 73-131 3 20 o-Xylene 20.0 0.50 ug/L 20.00 100 78-128 0 20 Styrene 19.7 0.50 ug/L 20.00 98 78-129 1 20 Tetrachloroethylene 20.2 0.50 ug/L 20.00 101 80-129 1 20 Tetrahydrofuran 21.8 10 ug/L 20.00 109 70-130 2 20 Toluene 21.3 0.50 ug/L 20.00 107 76-131 3 20 trans-1,2-Dichloroethylene 21.4 0.50 ug/L 20.00 107 76-135 3 20 trans-1,3-Dichloropropylene 21.9 0.50 ug/L 20.00 110 67-140 1 20 trans-1,4-Dichloro-2-butene 15.9 10 ug/L 20.00 80 70-130 2 20 Trichloroethylene 20.9 0.50 ug/L 20.00 104 77-133 4 20 Trichlorofluoromethane 21.7 0.50 ug/L 20.00 108 62-148 2 20 Vinyl acetate 23.5 2.0 ug/L 20.00 117 34-167 0.6 20 Vinyl chloride 18.1 0.50 ug/L 20.00 90 57-141 3 20 Xylenes, total 60.5 1.5 ug/L 60.00 101 77-133 0.2 20 Surrogate:4-Bromofluorobenzene 48.9 ug/L 50.00 98 80-124 Surrogate: Dibromofluoromethane 50.7 ug/L 50.00 101 75-129 Surrogate: Toluene-d8 47.6 ug/L 50.00 95 77-123 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 21 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Volatile Organic Compounds by GC/MS SIM - Quality Control Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch MOM - 5030B Blank (P9D0010-BLK1) Prepared &Analyzed: 04/01/19 1,4-Dioxane BRL 3.0 ug/L LCS (P9D0010-BS1) Prepared &Analyzed: 04/01/19 1,4-Dioxane 47.2 3.0 ug/L 50.00 94 55-145 LCS Dup (P9D0010-BSD1) Prepared &Analyzed: 04/01/19 1,4-Dioxane 48.4 3.0 ug/L 50.00 97 55-145 3 30 Matrix Spike (P9D0010-MS1) Source: 9030362-05 Prepared &Analyzed: 04/01/19 1,4-Dioxane 46.6 3.0 ug/L 50.00 BRL 93 55-145 Matrix Spike Dup (P9D0010-MSD1) Source: 9030362-05 Prepared & Analyzed: 04/01/19 1,4-Dioxane 48.2 3.0 ug/L 50.00 BRL 96 55-145 3 30 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 22 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0451 - 3005A Blank (P9C0451-BLK1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 0.214 1.0 ug/L J Arsenic 0.225 1.0 ug/L J Barium BRL 5.0 ug/L Beryllium BRL 1.0 ug/L Cadmium BRL 1.0 ug/L Chromium BRL 2.0 ug/L Cobalt BRL 1.0 ug/L Copper BRL 5.0 ug/L Lead 0.103 1.0 ug/L J Nickel BRL 2.0 ug/L Selenium BRL 5.0 ug/L Silver 0.0650 5.0 ug/L J Thallium BRL 1.0 ug/L Vanadium BRL 1.0 ug/L Zinc 3.28 10 ug/L J LCS (P9130451-113S1) Prepared: 03/25/19 Analyzed: 03/28/19 Antimony 98.8 1.0 ug/L 100.0 99 80-120 Arsenic 100 1.0 ug/L 100.0 100 80-120 Barium 98.0 5.0 ug/L 100.0 98 80-120 Beryllium 98.5 1.0 ug/L 100.0 99 80-120 Cadmium 99.1 1.0 ug/L 100.0 99 80-120 Chromium 101 2.0 ug/L 100.0 101 80-120 Cobalt 105 1.0 ug/L 100.0 105 80-120 Copper 104 5.0 ug/L 100.0 104 80-120 Lead 102 1.0 ug/L 100.0 102 80-120 Nickel 103 2.0 ug/L 100.0 103 80-120 Selenium 98.9 5.0 ug/L 100.0 99 80-120 Silver 102 5.0 ug/L 100.0 102 80-120 Thallium 103 1.0 ug/L 100.0 103 80-120 Vanadium 101 1.0 ug/L 100.0 101 80-120 Zinc 103 10 ug/L 100.0 103 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 23 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 Total Metals - Quality Control Analyte Project: Jackson Cty Landfill (Permit 50-02) Project No: 50-02 Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9C0474 - 7470A Blank (P9C0474-BLK1) Prepared &Analyzed: 03/26/19 Mercury BRL 0.20 ug/L LCS (P9C0474-BS1) Prepared &Analyzed: 03/26/19 Mercury 9.86 0.20 ug/L 9.375 105 80-120 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 24 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 Anions by Ion Chromatography - Quality Control Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch MUM - NO PREP Blank (P9C0454-BLK1) Prepared &Analyzed: 03/22/19 Chloride 498 1000 ug/L J Nitrate as N BRL 100 ug/L Sulfate BRL 2000 ug/L LCS (139130454-13SI) Prepared &Analyzed: 03/22/19 Chloride 41000 1000 ug/L 40000 102 80-120 Nitrate as N 4140 100 ug/L 4000 103 80-120 Sulfate 41600 2100 ug/L 40000 104 80-120 Matrix Spike (P9C0454-MSI) Source: 9030362-03 Prepared & Analyzed: 03/22/19 Chloride 41500 1000 ug/L 40000 1120 101 80-120 Nitrate as N 4690 100 ug/L 4000 588 102 80-120 Sulfate 42300 2100 ug/L 40000 1060 103 80-120 Matrix Spike Dup (P9C0454-MSD1) Source: 9030362-03 Prepared & Analyzed: 03/22/19 Chloride 41500 1000 ug/L 40000 1120 101 80-120 0.1 15 Nitrate as N 4700 100 ug/L 4000 588 103 80-120 0.3 15 Sulfate 42100 2100 ug/L 40000 1060 103 80-120 0.5 15 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 25 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Prism Work Order: 9030362 Attn: Brian Gant 50-02) Time Submitted: 3/22/2019 8:25:OOAM 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO418 - 9010C Blank (P9C0418-BLK1) Prepared &Analyzed: 03/25/19 Cyanide BRL 25 ug/L LCS (P9C0418-BS1) Prepared &Analyzed: 03/25/19 Cyanide 93.5 25 ug/L 100.0 94 85-115 Matrix Spike (P9C0418-MS1) Source: 9030362-03 Prepared & Analyzed: 03/26/19 Cyanide 88.5 25 ug/L 100.0 BRL 88 80-120 Matrix Spike Dup (P9C0418-MSD1) Source: 9030362-03 Prepared & Analyzed: 03/26/19 Cyanide 90.0 25 ug/L 100.0 BRL 90 80-120 2 20 Batch P9CO445 - NO PREP Blank (M0445-BLK1) Prepared & Analyzed: 03/22/19 Ferrous Iron BRL 200 ug/L LCS (P9C0445-BSI) Prepared &Analyzed: 03/22/19 Ferrous Iron 1930 200 ug/L 2000 97 90-110 Matrix Spike (P9C0445-MSI) Source: 9030362-02 Prepared & Analyzed: 03/22/19 Ferrous Iron 2000 200 ug/L 2000 BRL 100 80-120 Matrix Spike Dup (P9C0445-MSD1) Source: 9030362-02 Prepared & Analyzed: 03/22/19 Ferrous Iron 2090 200 ug/L 2000 BRL 105 80-120 5 20 Batch P9CO446 - NO PREP Blank (P9C0446-BLK1) Prepared & Analyzed: 03/22/19 Chemical Oxygen Demand BRL 50000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 26 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Attn: Brian Gant 231 Haywood Street Asheville, NC 28801 General Chemistry Parameters - Quality Control Analyte Batch P9CO446 - NO PREP Project: Jackson Cty Landfill (Permit Prism Work Order: 9030362 50-02) Time Submitted: 3/22/2019 8:25:OOAM Project No: 50-02 Reporting Spike Source %REC RPD Result Limit Units Level Result %REC Limits RPD Limit Notes LCS (P9C0446-BS1) Prepared &Analyzed: 03/22/19 Chemical Oxygen Demand 496000 50000 ug/L 500000 99 90-110 Matrix Spike (P9C0446-MS2) Source: 9030362-01 Prepared & Analyzed: 03/22/19 Chemical Oxygen Demand 558000 50000 ug/L 500000 96800 92 80-120 Matrix Spike Dup (P9C0446-MSD2) Source: 9030362-01 Prepared & Analyzed: 03/22/19 Chemical Oxygen Demand 552000 50000 ug/L 500000 96800 91 80-120 1 20 Batch P9CO516 - NO PREP Blank (P9C0516-BLK1) Prepared & Analyzed: 03/27/19 Chemical Oxygen Demand BRL 50000 ug/L LCS (P9C0516-BSI) Prepared &Analyzed: 03/27/19 Chemical Oxygen Demand 494000 50000 ug/L 500000 99 90-110 Matrix Spike (P9C0516-MS1) Source: 9030362-03 Prepared & Analyzed: 03/27/19 Chemical Oxygen Demand 476000 50000 ug/L 500000 BRL 95 80-120 Matrix Spike Dup (P9C0516-MSD1) Source: 9030362-03 Prepared & Analyzed: 03/27/19 Chemical Oxygen Demand 477000 50000 ug/L 500000 BRL 95 80-120 0.2 20 Batch P9CO532 - SM4500-S C Blank (P9C0532-BLK1) Prepared &Analyzed: 03/26/19 Sulfide BRL 2000 ug/L This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 27 of 41 P R I IS M Full -Service Analytical Environmental Solutions . LABORATORIES, INC. Level II QC Report 4/9/19 Anchor QEA of North Carolina, PLLC Project: Jackson Cty Landfill (Permit Attn: Brian Gant 50-02) 231 Haywood Street Project No: 50-02 Asheville, NC 28801 General Chemistry Parameters - Quality Control Prism Work Order: 9030362 Time Submitted: 3/22/2019 8:25:OOAM Reporting Spike Source %REC RPD Analyte Result Limit Units Level Result %REC Limits RPD Limit Notes Batch P9CO532 - SM4500-S C LCS (P9130532-113SI) Prepared &Analyzed: 03/26/19 Sulfide 8000 2000 ug/L 10000 80 70-130 Batch P9CO550 - NO PREP Blank (P9C0550-BLK1) Prepared & Analyzed: 03/22/19 Biochemical Oxygen Demand BRL 2000 ug/L LCS (P9C0550-BS1) Prepared &Analyzed: 03/22/19 Biochemical Oxygen Demand 206000 2000 ug/L 198000 104 84.6-115.4 Batch P9CO574 - NO PREP Blank (P9C0574-BLK1) Prepared & Analyzed: 03/29/19 Total Alkalinity to pH 4.5 BRL 5000 ug/L LCS (P9C0574-13SI) Prepared &Analyzed: 03/29/19 Total Alkalinity to pH 4.5 255000 5000 ug/L 250000 102 90-110 This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 28 of 41 Sample Extraction Data Prep Method: 9010C Lab Number Batch Initial Final Date/Time 9030362-01 P9C0418 50 mL 50 mL 03/25/19 9:40 9030362-02 P9C0418 50 mL 50 mL 03/25/19 9:40 9030362-03 P9C0418 50 mL 50 mL 03/25/19 9:40 Prep Method: SM4500-S C Lab Number Batch Initial Final Date/Time 9030362-01 P9C0532 200 mL 200 mL 03/26/19 12:45 9030362-02 P9C0532 200 mL 200 mL 03/26/19 12:45 9030362-03 P9C0532 200 mL 200 mL 03/26/19 12:45 Prep Method: 3005A Lab Number Batch Initial Final Date/Time 9030362-01 P9C0451 50 mL 50 mL 03/25/19 7:25 9030362-02 P9C0451 50 mL 50 mL 03/25/19 7:25 9030362-03 P9C0451 50 mL 50 mL 03/25/19 7:25 Prep Method: 7470A Lab Number Batch Initial Final Date/Time 9030362-01 P9C0474 20 mL 30 mL 03/26/19 8:25 9030362-02 P9C0474 20 mL 30 mL 03/26/19 8:25 9030362-03 P9C0474 20 mL 30 mL 03/26/19 8:25 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9030362-01 P9C0588 10 mL 10 mL 03/29/19 11:57 9030362-02 P9C0588 10 mL 10 mL 03/29/19 11:57 9030362-03 P9C0588 10 mL 10 mL 03/29/19 11:57 9030362-04 P9C0588 10 mL 10 mL 03/29/19 11:57 9030362-05 P9C0588 10 mL 10 mL 03/29/19 11:57 Prep Method: 5030E Lab Number Batch Initial Final Date/Time 9030362-01 P9D0010 5 mL 5 mL 04/01/19 11:32 9030362-02 P9D0010 5 mL 5 mL 04/01/19 11:32 9030362-03 P9D0010 5 mL 5 mL 04/01/19 11:32 9030362-04 P9D0010 5 mL 5 mL 04/01/19 11:32 9030362-05 P9D0010 5 mL 5 mL 04/01/19 11:32 Subcontracted Analyses The following analyses were subcontracted to Gulf Coast Analytical Labs, Inc. Lab Number Analysis 9030362-01 TOC (Sub) 9030362-02 TOC (Sub) 9030362-03 TOC (Sub) This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 Page 29 of 41 w�IV�h14V�l�l a IM ( = a m=_ J W w '• W v J N Z o U I'L IM m C W OIL 0 o c � w z o Fa c W l� ? E 1 tr L6 LU 0 aU O N Z R U v c Q 0'Eaa Z p a = H _ �• fY.1 = M a °ra ° > 10 d n.tn« a5 a od N c m 0 U i•+ 7 %o M (n n a` m m a N c N N U N U .` E z � c N V L� fn O S. o •� o n LL W t li U� o� �zo O O N N dS N w g m 5 °'o E 1 E z m vi Z N rn o Lvo �a C O O a Q E U :. 0 H C C O O d a a 4) 4) v y m O ago Z; IL V Z lQ J z zl U. I Y � O W t 4 DI W z C_ W QJU yl W Z V N 0 C PL C O Q. 0 ;p 0 v 4� O CL m T r N 7 Y d L I Q oa w �� oxaNYU) ❑ C z Z ❑ N 3 W y U C U N W W Z 0 0 0 O LU M v -0 XKv zl- ZO Z v p v ai a vi — m o�Hy w 0 aNZp d N �NOF d' ❑ c w N N c > m '3�wm LY m c o c g z obi m (O �' H y F p❑❑ y am 2 Z x m LL a V Z d L > 9 Q 0 KG w N O ' >Eww IL d c ��zc �y C IL a w-j h U, GI WZ N O y Du aW Cc L v w J Er a E E }T rn IL tr in F . C KD _ y 'O O m o z a N O' O O CL O is Q F J 0 5-wwmu� a W w�- ~U aLU � J O U z 0 a_ Fa ZU W LU W J a a �r,l v1 a I n 0 E E d LL Ea) ¢ 0 m °"' 9 d ai cu m in in iL w E E 0 U m C O V Q J Q Z cc 0 L) U n r c-)� ` _❑ m 7 O Q ❑ ❑ p W -� ;° U N U a J In C �� M o rY]t6 , C ay � ❑ U ad Q > ~ WE > U o fn 2 m U Z N W CD Me � w O U ❑ ❑> II Qy y t W ~O vUj O Dr' ❑ > CL �U mT Tlo C r?�r I�� m U Z U ❑ ❑ Io w�' m 2 � �U 0 M(n F- dL >.2 i�� m on Na 9w ❑ Z EO 0 N /W> U7 ❑❑ Z O 40 L li G w �7R N E E �' m m IL m J a a 2 I..0 o `L C� co a c IY I x x m Z ❑ C7 Co oda °a oZZ CD o ❑ ❑ 7 F- W I+ 0 A o z i.i LU U L A N G Q a p o ` �W LL3U) W IL E p❑ E H!� 1 OU c 00 IL Z Q oEl f '10 wZ a c.to EW yC7❑❑ Lc IL L a In ¢ >_ N W U t J y N U Q co U i EMAm IL �-Mo ClF ❑ w d m zy Z QC a.� =O )-- Z N C•p tU N `o ❑ m x w�U f� FQ'- E ca_� r Q cPaae 8 Z 30 of M D N 41 P AccEss ANALYTICAL, INC. ANALYTICAL REPORT CLIENT Prism Laboratories PO Box 240543 Charlotte, NC 28224 ATTENTION RobbiJones PROJECTID 9030362 LABORATORY REPORT NUMBER 219032610 DATE 03/28/2019 Primary Data Review By Authorized Signature PLEASE NOTE: Secondary Data Review By Ashley B. Amick Project Manager, Access Analytical, Inc. aamick@accessanalyticalinc.com Unless otherwise noted, all analysis on this report performed at Gulf Coast Analytical Labs (GCAL), 7979 Innovation Park Dr., Baton Rouge, LA 70820. - GCAL is SCDHEC certified laboratory # 73006, NCDENR certified lab # 618, GA certified lab # LA-01955, NELAP certified laboratory # 01955 - Local support services for this project are provided by Access Analytical, Inc.. Access Analytical is a representative of GCAL serving clients in the SC/NC/GA areas. All questions regarding this report should be directed to your local Access Analytical representative at 803.781.4243 or toll free at 888.315.4243. Lab Report#: 219032610 Page 1 of 11 Page 31 of 41 J"' CSC,&L LELAP CERTIFICATE NUMBER: 01955 DOD -FLAP ACCREDITATION NUMBER: 74960 ANALYTICAL RESULTS Deliver To Robbi Jones Prism Laboratories PO Box 240543 Charlotte, NC 28224 800-529-6364 L*-wk' PJ LA Testing DOD EIAP PERFORMED BY GCAL, LLC 7979 Innovation Park Dr. Baton Rouge, LA 70820 (225) 769-4900 Report Date 03/28/2019 11111111111111111111111111111111111111111111111111111111 Report 2I19032630 Ii Project 9030362 Additional Recipients NONE `%I ISO 1�4� 17025�0" Lab Report#: 219032610 Page 2 of 11 Page 32 of 41 Report#: 219032610 4"4 GCAL Project ID: 9030362 Laboratory Endorsement Report Date: 03/28/2019 Sample analysis was performed in accordance with approved methodologies provided by the Environmental Protection Agency or other recognized agencies. The samples and their corresponding extracts will be maintained for a period of 30 days unless otherwise arranged. Following this retention period the samples will be disposed in accordance with GCAL's Standard Operating Procedures. Common Abbreviations that may be Utilized in this Report ND Indicates the result was Not Detected at the specified reporting limit NO Indicates the sample did not ignite when preliminary test performed for EPA Method 1030 DO Indicates the result was Diluted Out MI Indicates the result was subject to Matrix Interference TNTC Indicates the result was Too Numerous To Count SUBC Indicates the analysis was Sub -Contracted FLD Indicates the analysis was performed in the Field DL Detection Limit LOD Limit of Detection LOQ Limit of Quantitation RE Re -analysis CF HPLC or GC Confirmation 00:01 Reported as a time equivalent to 12:00 AM Reporting Flags that may be Utilized in this Report J or I Indicates the result is between the MDL and LOQ J DOD flag on analyte in the parent sample for MS/MSD outside acceptance criteria U Indicates the compound was analyzed for but not detected B or V Indicates the analyte was detected in the associated Method Blank Q Indicates a non -compliant QC Result (See Q Flag Application Report) Indicates a non -compliant or not applicable QC recovery or RPD — see narrative E Organics - The result is estimated because it exceeded the instrument calibration range E Metals - % diference for the serial dilution is > 10% L Reporting Limits adjusted to meet risk -based limit. P RPD between primary and confirmation result is greater than 40 DL Diluted analysis —when appended to Client Sample ID Sample receipt at GCAL is documented through the attached chain of custody. In accordance with NELAC, this report shall be reproduced only in full and with the written permission of GCAL. The results contained within this report relate only to the samples reported. The documented results are presented within this report. This report pertains only to the samples listed in the Report Sample Summary and should be retained as a permanent record thereof. The results contained within this report are intended for the use of the client. Any unauthorized use of the information contained in this report is prohibited. I certify that this data package is in compliance with The NELAC Institute (TNI) Standard 2009 and terms and conditions of the contract and Statement of Work both technically and for completeness, for other than the conditions in the case narrative. Release of the data contained in this hardcopy data package and in the computer readable data submitted has been authorized by the Quality Assurance Manager or his/her designee, as verified by the following signature. Estimated uncertainty of measurement is available upon request. This report is in compliance with the DOD QSM as specified in the contract if applicable. Authorized Signature GCAL Report 219032610 Lab Report#:219032610 Page 3 of 11 Page 33 of 41 Report#: 219032610 Project ID: 9030362 Certifications Report Date: 03/28/2019 Certification Certification Number DOD ELAP 74960 Alabama 01955 Arkansas 88-0655 Colorado 01955 Delaware 01955 Florida E87854 Georgia 01955 Hawaii 01955 Idaho 01955 Illinois 200048 Indiana 01955 Kansas E-10354 Kentucky 95 Louisiana 01955 Maryland 01955 Massachusetts 01955 Michi an 01955 Mississippi 01955 Missouri 01955 Montana N/A Nebraska 01955 New Mexico 01955 North Carolina 618 North Dakota R-195 Oklahoma 9403 South Carolina 73006001 South Dakota 01955 Tennessee 01955 Texas T104704178 Vermont 01955 Vir inia 460215 Washin ton C929 USDA Soil Permit P330-16-00234 Lab Report#:219032610 Page 4 of 11 Page 34 of 41 far ���� Report#: 219032610 Project ID: 9030362 Case Narrative Client: Access Analytical Report: 219032610 Gulf Coast Analytical Laboratories received and analyzed the sample(s) listed on the Report Sample Summary page of this report. Receipt of the sample(s) is documented by the attached chain of custody. This applies only to the sample(s) listed in this report. No sample integrity or quality control exceptions were identified unless noted below. No anomalies were found for the analyzed sample(s). Report Date: 03/28/2019 Lab Report#:219032610 Page 5 of 11 Page 35 of 41 (V� C5C,&L Report#: 219032610 Project ID: 9030362 Sample Summary Report Date: 03/28/2019 GCAL ID Client ID Matrix Collect Date/Time Receive Date/Time 21903261001 MW-01 Water 03/21/201913:13 03/26/201910:25 21903261002 MW-02 Water 03/21/201911:28 03/26/201910:25 21903261003 MW-06 Water 03/21/2019 09:58 03/26/2019 10:25 Lab Report#: 219032610 Page 6 of 11 Page 36 of 41 _ p GCAL Report#: 219032610 � Project lD: 9030362 Report Date: 03/28/2019 Summary of Compounds Detected W-01 Collect Date 03/21/2019 13:13 GCAL ID 21903261001 Receive Date 03/26/2019 10:25 Matrix Water SM 5310 B-2011 CAS# Parameter Result DL LOQ Units C-012 Total Organic Carbon 21.9 0.600 4.00 mg/L Collect Date 03/21/2019 11:28 GCAL ID 21903261002 M W-02 Receive Date 03/26/2019 10:25 Matrix Water SM 5310 B-2011 CAS# Parameter Result DL LOCI Units C-012 Total Organic Carbon 2.44 0.300 2.00 mg/L MW-06 Collect Date 03/21/2019 09:58 GCAL ID 21903261003 Receive Date 03/26/2019 10:25 Matrix Water SM 5310 B-2011 CAS# Parameter C-012 Total Organic Carbon Result DL LOCI Units 4.97 0.600 4.00 mg/L Lab Report#: 219032610 Page 7 of 11 Page 37 of 41 GCAL Report#: 219032610 Project ID: 9030362 Sample Results Report Date: 03/28/2019 Collect Date 03/21/2019 13:13 GCAL ID 21903261001 MW-01 Receive Date 03/26/2019 10:25 Matrix Water SM 5310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 2 03/27/201912:23 PLH 656703 CAS# Parameter C-012 Total Organic Carbon Result DL LOQ 21.9 0.600 4.00 Collect Date 03/21/2019 11:28 GCAL ID 21903261002 MW-02 Receive Date 03/26/2019 10:25 Matrix Water i310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 1 03/26/201918:40 PLH 656649 CAS# Parameter C-012 Total Organic Carbon Result DL LOCI 2.44 0.300 2.00 Collect Date 03/21/2019 09:58 GCAL ID 21903261003 MW-06 Receive Date 03/26/2019 10:25 Matrix Water i310 B-2011 Prep Date Prep Batch Prep Method Dilution Analysis Date By Analytical Batch NA NA NA 2 03/26/201918:57 PLH 656649 CAS# Parameter C-012 Total Organic Carbon Result DL LOCI Units 4.97 0.600 4.00 mg/L Lab Report#:219032610 Page 8 of 11 Page 38 of 41 Report#: 219032610 Project ID: 9030362 General Chemistry QC Summary Report Date: 03/28/2019 Analytical Batch Client ID MB656649 LCS656649 656649 GCALID 1909161 1909162 Sample Type MB LCS Prep Date NA NA Analysis Date 03/26/2019 09:32 03/26/2019 08:42 Matrix Water Water SM 5310 B-2011 Units mg/L Spike Result %R Control Result DL Added Limits%R Total Organic Carbon J C-012 0.300U 1 0.300 50.01 50.3 101 90 - 110 Analytical Batch Client ID MB666703 LCS656703 656703 GCALID 1909347 1909348 Sample Type MB LCS Prep Date NA NA Analysis Date 03/27/2019 11:32 03/27/2019 10:43 Matrix Water Water SM 5310 B-2011 Units mg/L Spike Result I %R I Control Result DL Added Limits%R Total Organic Carbon C-012 0.300U 1 0,3001 50.01 50.3 101 90 - 110 Lab Report#: 219032610 Page 9 of 11 Page 39 of 41 r m v rb 0 C) W N 0) C) N (13 CD 0 C) Client ID: 4565 - Access Analytical SDG: 219032610 PM: DLH PRISMI Enlvlrgnmcntalnlucal sotions l' SUBCONTRACT ORDER celliticaIiun :LAC ,itiA(.I:_— Prism I.ahormorlesr Inc. NtSC_ 01her 9030362 N/A_ r�14Dl�t:I:.jOj)IlATORS'. iti: VWINC IAb+'IItATOIL Prism Laboratories, I:Ie. Gulf Coast Analylieal Labs, Inc. P. O, Box 240543 10791 Courscy Blvd . ; IgC1F111&N Char IUltc, NC 28224.0543 Aaiun Ruugc, LA 70816 L Phonc:800.529-6364 Pllune:(225)769.4900 Fax: 704-525-0,109 Fax: (225) 767-5717 Pmjccl !.linage: Rabbi A. Juncs - 47 4W -.99D R-- �I�Q Analysis Due F-spirrs laboratory►D comments Sample ID: 9030362.01 Water Swwled: 03/21/19 13:13 m W ^ U I ... I TOG (Sub) 0411 RI19 13:13 C4 u n r+n r r. r .Sr q rr r7+rA n ttr JOAS C 1 r' SamplclD:9030362-02 I Water Sampled: 0312111911:211 TOC (Sub) 04MV19 11 2A C'nnrninela SupplicA; tiampin ID: 9030362-117 Water Saniylyd: 03121II9 09:56 ruc (Sub) 0411 R/19 09:54 C'nnruine.c SuppLcrl. m 40. r .. Ily t iil1�/.�7 Received A.% R-6"d 115 D.IIe Pago 1 of 1 Page 40 of 41 \ 2 ❑ ❑ ❑ ❑ ❑ ❑ no ❑ Cl. £ E / 0 e e • g $ / o E E @ / a) / Cl. / = E a \ § / _ $ / co v q @ 7 % 12 m 2 Cl)Cl.R k / £ 2 k � � \ \ I 7 E S W ) CL 2 cm 2 7 2 § / f 2 V ƒ / : a.)k 3 a)/ E $ / b \ 7 0 0 E 2 a E E \ E % \ S _ / CD / 7 2 w 7 2 v / \ ° -8 _ a) _ � � - k 5 k m u Q E / / \ § a) Cl)v h k k ± o 2 / 12 / 0 0 E CD :E; ? A o w q �/ kCLcn k/ 92 § CN k \ \ a \ t Q j $ 2 / 1 / Ed \ r LLJ m E m 7.-5j I z • 5 0 / k I # Page 41 of 41 � ISM I Full -Service Analytical & r Environmental Solutions LABORATORIES INC. Anchor QEA of North Carolina, PLLC Brian Gant 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 Case Narrative NC Drinking Water Cert No. 37735 4/9/19 11:28 SC Certification No. 99012 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Lab Submittal Date: 03/22/2019 Prism Work Order: 9030363 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Method 524 analysis was subcontracted to Pace. Laboratory report is attached with a total page count of 15 pages. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Robbi A. Jones President/Project Manager Data Qualifiers Key Reference: Reviewed By Robbi A. Jones President/Project Manager BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference * Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 P�SM Sample Receipt Summary Full-5®rvice Analytical 8 •'° Environmental Solutions 04/09/2019 y r .APOMTORIM INC. Prism Work Order: 9030363 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received DW-01 9030363-01 Water 03/21/19 12:00 03/22/19 8:25 Trip Blank 9030363-02 Water 03/21/19 0:00 03/22/19 8:25 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 7041525-0409 V9 0 LU �1 zi J J m C oW 6 7 LLI W F L W 0 OO a z a° 6 '6 c io O U' 7 O m U) a ;v a)C NO 0 m U �n > E ZC4 y c fn o 3 Or LL W M L U. i 09 w ad�p� U)0 4N a$ Q �K°m �m L.l g rn o CY) L �a a v a 0 f' C d a m N W n m T r q ❑ o� � w 7�l N y W O 4. N Y VJ ❑ m 3 w >. (a�KU o as c9 0 U 0 c+1 � -0X N V V❑ p I. N Z N> m U m O F W � m o�oE w aO N N m 0 n C � K I OT m 3�mm O ❑ ❑ N C C z a) a LL j � m m wm 'a �N06o O 0 7 T ' E > at .0wm m y c ��wow Co z L a) Y N O y K C1 > a m Q o` E E o' O u) F- O N N LL '0 � - v U Q x � � v Ul m z y o z If Sn 0- O 0 a N W W ►e o a 0 0 Eow awwCID Un 2 M d a g z O ai E ai E d r m a m O LL aj rn m cn Fn LL w E E O U m c 0 a A . YE U to fn p 7 y � J `� 0' ❑ uj w m �~ � O❑ O o ,��/� U N IM C-kw c� ``s z° e Q �-+ O a C C, O IL T m ' ° e ❑ N Q > o m a« .E :o O) i ❑ p i w mm [] w; ma im WZ o LU a J cr ccC] = u N L O > _ NT z} ❑ CL �ULU z m IN O �❑ CI in �M W O� a7 z aL+ M I '� m —� W c H p O Z Y N 30, m � 0 H {] O w oa z! M�O �_ J J VJ d X �o�j (0 a m m r I w❑❑ y m w c E w m a d .Lf H� N atoLU aW LIS u a II m ` L q 0, V �0_ Q X JOB��yQJ 0)m C a _ Ow a O N_ p¢SN XL) CInCD Z❑ o � L L ~ O ~ W z U U0 ZI�I ❑ ❑ N H � to �w<w m ca �aa E :>> U F J=10 TO =z IlLU kC.)Off= am I4 �Q rw UJIIL w E G❑ E W w F .�. 7 Q c� a DU a u a 110 Z Q U II aw of �o �z 0 fr to m I W ya �� aw W U p (A O z O rr wa = ❑ U w o z a ZV p) n y. N a 0 IM d Ea �❑ ❑� wW UW 1 In�� oc w � U W U z d d a o ` W O C E Z e Analytical rwww.pacelabs.com I April 05, 2019 Robbi A. Jones Prism Laboratories, Inc. P.O. Box 240543 Charlotte, NC 28224 RE: Project: 9030363 Pace Project No.: 92422569 Dear Robbi Jones: Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on March 25, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Matthew Brainard matthew.brainard@pacelabs.com (704)875-9092 Project Manager Enclosures cc: Angela Overcash, Prism REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 1 of 12 PaceAnalXical j wwwpacelabs.com I r CERTIFICATIONS Project: 9030363 Pace Project No.: 92422569 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Ormond Beach Certification IDs 8 East Tower Circle, Ormond Beach, FL 32174 Nebraska Certification: NE-OS-28-14 Alabama Certification #: 41320 New Hampshire Certification #: 2958 Colorado Certification: FL NELAC Reciprocity New Jersey Certification #: FL022 Connecticut Certification #: PH-0216 New York Certification #: 11608 Florida Certification #: E83079 North Carolina Environmental Certificate #: 667 Georgia Certification #: 955 North Carolina Certification #: 12710 Guam Certification: FL NELAC Reciprocity North Dakota Certification #: R-216 Hawaii Certification: FL NELAC Reciprocity Oklahoma Certification #: D9947 Illinois Certification #: 200068 Pennsylvania Certification #: 68-00547 Indiana Certification: FL NELAC Reciprocity Puerto Rico Certification #: FLO1264 Kansas Certification* E-10383 South Carolina Certification: #96042001 Kentucky Certification #: 90050 Tennessee Certification #: TN02974 Louisiana Certification #: FL NELAC Reciprocity Texas Certification: FL NELAC Reciprocity Louisiana Environmental Certificate #: 05007 US Virgin Islands Certification: FL NELAC Reciprocity Maryland Certification: #346 Virginia Environmental Certification #: 460165 Michigan Certification #: 9911 West Virginia Certification #: 9962C Mississippi Certification: FL NELAC Reciprocity Wisconsin Certification #: 399079670 Missouri Certification #: 236 Wyoming (EPA Region 8): FL NELAC Reciprocity Montana Certification #: Cert 0074 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 2 of 12 ace Analytical wwwpacelabacom SAMPLE ANALYTE COUNT Project: 9030363 Pace Project No.: 92422569 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92422569001 DW-01 EPA 524.2 JLR 24 PASI-O 92422569002 TRIP BLANK EPA 524.2 JLR 24 PASI-O REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 12 �PaceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: 9030363 Pace Project No.: 92422569 Sample: DW-01 Lab ID: 92422569001 Collected: 03/21/19 12:00 Received: 03/25/19 11:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Benzene ND mg/L 0.0050 10 04/04/19 19:32 71-43-2 Carbon tetrachloride ND mg/L 0.0050 10 04/04/19 19:32 56-23-5 Chlorobenzene ND mg/L 0.0050 10 04/04/19 19:32 108-90-7 1,2-Dichlorobenzene ND mg/L 0.0050 10 04/04/19 19:32 95-50-1 1,4-Dichlorobenzene ND mg/L 0.0050 10 04/04/19 19:32 106-46-7 1,2-Dichloroethane ND mg/L 0.0050 10 04/04/19 19:32 107-06-2 1,1-Dichloroethene ND mg/L 0.0050 10 04/04/19 19:32 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.0050 10 04/04/19 19:32 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.0050 10 04/04/19 19:32 156-60-5 1,2-Dichloropropane ND mg/L 0.0050 10 04/04/19 19:32 78-87-5 Ethylbenzene ND mg/L 0.0050 10 04/04/19 19:32 100-41-4 Methylene Chloride ND mg/L 0.0050 10 04/04/19 19:32 75-09-2 Styrene ND mg/L 0.0050 10 04/04/19 19:32 100-42-5 Tetra chloroethene ND mg/L 0.0050 10 04/04/19 19:32 127-18-4 Toluene ND mg/L 0.0050 10 04/04/19 19:32 108-88-3 1,2,4-Trichlorobe nzene ND mg/L 0.0050 10 04/04/19 19:32 120-82-1 1,1,1-Trichloroethane ND mg/L 0.0050 10 04/04/19 19:32 71-55-6 1,1,2-Trichloroethane ND mg/L 0.0050 10 04/04/19 19:32 79-00-5 Trichloroethene ND mg/L 0.0050 10 04/04/19 19:32 79-01-6 Vinyl chloride ND mg/L 0.0050 10 04/04/19 19:32 75-01-4 Xylene (Total) ND mg/L 0.0050 10 04/04/19 19:32 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 106 % 70-130 10 04/04/19 19:32 460-00-4 D3 Toluene-d8 (S) 95 % 70-130 10 04/04/19 19:32 2037-26-5 1,2-Dichloroethane-d4 (S) 110 % 70-130 10 04/04/19 19:32 17060-07-0 Sample: TRIP BLANK Lab ID: 92422569002 Collected: 03/21/19 00:00 Received: 03/25/19 11:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 Benzene ND mg/L 0.00050 1 04/04/19 19:56 71-43-2 Carbon tetrachloride ND mg/L 0.00050 1 04/04/19 19:56 56-23-5 Chlorobenzene ND mg/L 0.00050 1 04/04/19 19:56 108-90-7 1,2-Dichlorobenzene ND mg/L 0.00050 1 04104/1919:56 95-50-1 1,4-Dichlorobenzene ND mg/L 0.00050 1 04/04/19 19:56 106-46-7 1,2-Dichloroethane ND mg/L 0.00050 1 04/04/19 19:56 107-06-2 1,1-Dichloroethene ND mg/L 0.00050 1 04/04/19 19:56 75-35-4 cis-1,2-Dichloroethene ND mg/L 0.00050 1 04/04/19 19:56 156-59-2 trans-1,2-Dichloroethene ND mg/L 0.00050 1 04/04/19 19:56 156-60-5 1,2-Dichloropropane ND mg/L 0.00050 1 04/04/19 19:56 78-87-5 Ethylbenzene ND mg/L 0.00050 1 04/04/19 19:56 100-41-4 Methylene Chloride ND mg/L 0.00050 1 04/04/19 19:56 75-09-2 Styrene ND mg/L 0.00050 1 04/04/19 19:56 100-42-5 Tetrachloroethene ND mg/L 0.00050 1 04/04/19 19:56 127-18-4 Toluene ND mg/L 0,00050 i 04/04/19 19:56 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2019 06:40 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 12 ceAnalytical0 j www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: 9030363 Pace Project No.: 92422569 Sample: TRIP BLANK Lab ID: 92422569002 Collected: 03/21/19 00:00 Received: 03/25/19 11:45 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 524.2 MSV Analytical Method: EPA 524.2 1,2,4-Trichlorobe nzene ND mg/L 0.00050 1 04/04/19 19:56 120-82-1 1,1,1-Trichloroethane ND mg/L 0.00050 1 04/04/19 19:56 71-55-6 1,1,2-Trichloroethane ND mg/L 0.00050 1 04/04/19 19:56 79-00-5 Trichloroethene ND mg/L 0.00050 1 04/0411919:56 79-01-6 Vinyl chloride ND mg/L 0.00050 1 04/04/19 19:56 75-01-4 Xylene (Total) ND mg/L 0.00050 1 04/04/19 19:56 1330-20-7 Surrogates 4-Bromofluorobenzene (S) 105 % 70-130 1 04/04/19 19:56 460-00-4 Toluene-d8 (S) 96 % 70-130 1 04/04/19 19:56 2037-26-5 1,2-Dichloroethane-d4 (S) 111 % 70-130 1 04/04/19 19:56 17060-07-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2019 06:40 PM without the written consent of Pace Analytical Services, LLC Page 5 of 12 �Jx dace Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 9030363 Pace Project No.: 92422569 QC Batch: 528474 Analysis Method: EPA 524.2 QC Batch Method: EPA 524.2 Analysis Description: 524.2 MSV Associated Lab Samples: 92422569001. 92422569002 METHOD BLANK: 2860408 Associated Lab Samples: 92422569001. 92422569002 Parameter Units 1,1,1-Trichloroethane mg/L 1,1,2-Trichloroethane mg/L 1,1-Dichloroethene mg/L 1,2,4-Trichlorobenzene mg/L 1,2-Dichlorobenzene mg/L 1,2-Dichloroethane mg/L 1,2-Dichloropropane mg/L 1,4-Dichlorobenzene mg/L Benzene mg/L Carbon tetrachloride mg/L Chlorobenzene mg/L cis- 1,2-Dichloroethene mg/L Ethylbenzene mg/L Methylene Chloride mg/L Styrene mg/L Tetrachloroethene mg/L Toluene mg/L trans-1,2-Dichloroethene mg/L Trichloroethene mg/L Vinyl chloride mg/L Xylene (Total) mg/L 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % Matrix: Water Blank Result Reporting Limit Analyzed ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 ND 0.00050 04/04/1913:33 104 70-130 04/04/1913:33 103 70-130 04/04/1913:33 95 70-130 04/04/1913:33 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: Parameter 2860409 Units Spike Conc. 2860410 LCS LCSD Result Result LCS % Rec LCSD % Rec % Rec Limits RPD Max RPD Qualifiers 1,1,1-Trichloroethane mg/L 0.04 0.040 0.038 100 94 70-130 6 40 1,1,2-Trichloroethane mg/L 0.04 0.039 0.040 97 101 70-130 4 40 1,1-Dichloroethene mg/L 0.04 0.037 0.036 92 91 70-130 1 40 1,2,4-Trichlorobe nzene mg/L 0.04 0.039 0.039 98 96 70-130 1 40 1,2-Dichlorobenzene mg/L 0.04 0.041 0.040 102 100 70-130 3 40 1,2-Dichloroethane mg/L 0.04 0.036 0.033 90 83 70-130 8 40 1,2-Dichloropropane mg/L 0.04 0.033 0.033 83 82 70-130 1 40 1,4-Dichlorobenzene mg/L 0.04 0.039 0.038 97 96 70-130 1 40 Benzene mg/L 0.04 0.033 0.032 83 81 70-130 2 40 Carbon tetrachloride mg/L 0.04 0.041 0.039 102 97 70-130 5 40 Chlorobenzene mg/L 0.04 0.040 0.041 99 101 70-130 2 40 cis-1.2-Dichloroethene mg/L 0.04 0.033 0.032 83 81 70-130 2 40 Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2019 06:40 PM without the written consent or Pace Analytical Services, LLC Page 6 of 12 Pace Analytical www.pacelabs.com QUALITY CONTROL DATA Project: 9030363 Pace Project No.: 92422569 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 LABORATORY CONTROL SAMPLE & LCSD: 2860409 2860410 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Cone. Result Result % Rec % Rec Limits RPD RPD Qualifiers Ethylbenzene mg/L 0.04 0.040 0.042 101 104 70-130 3 40 Methylene Chloride mg/L 0.04 0.041 0.038 101 95 70-130 7 40 Styrene mg/L 0.04 0.042 0.043 104 108 70-130 4 40 Tetrachloroethene mg/L 0.04 0.050 0.050 126 126 70-130 0 40 Toluene mg/L 0.04 0.038 0.039 95 98 70-130 3 40 trans- 1,2-Dichloroethene mg/L 0.04 0.036 0.036 90 90 70-130 1 40 Trichloroethene mg/L 0.04 0.037 0.037 93 91 70-130 2 40 Vinyl chloride mg/L 0.04 0.033 0.037 83 92 70-130 10 40 Xylene (Total) mg/L 0.12 0.12 0.13 104 106 70-130 2 40 1,2-Dichloroethane-d4 (S) % 105 101 70-130 4-Bromofluorobenzene (S) % 112 114 70-130 Toluene-d8 (S) % 98 96 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit Is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2019 06:40 PM without the written consent of Pace Analytical Services, LLC, Page 7 of 12 0 ceAnalytical www.pacelabs.com QUALIFIERS Project: 9030363 Pace Project No.: 92422569 L]4yI.I111111161,1K DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 PQL- Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-O Pace Analytical Services - Ormond Beach ANALYTE QUALIFIERS D3 Sample was diluted due to the presence of high levels of non -target analytes or other matrix interference. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 04/05/2019 06:40 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 aceAnalXical wwwpacelabs.com Project: 9030363 Pace Project No.: 92422569 Lab ID 92422569001 92422569002 Sample ID DW-01 TRIP BLANK QUALITY CONTROL DATA CROSS REFERENCE TABLE QC Batch Method EPA 524.2 EPA 524.2 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch Analytical Method 528474 528474 REPORT OF LABORATORY ANALYSIS Analytical Batch This report shall not be reproduced, except in full. Date: 04/05/2019 06:40 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 12 Document Name: Document Revised: February 7, 2018 Condition Upon Recelpt(SOUR) Pa e 1 of 2 Document No,:, Issuing Authority: F-CAR-CS•033-Rev.06 Pace Carollnas4uality Office Laboratory receiving samples: Asheville Q Eden❑ Greenwood ❑ HuntersvilleiO( Raleigh❑ Mechanicsville[] .. • SampleClient Nanie: Upon Receipt �+ I ,� IL S Project it; LJO# : 92422569 Courier: (--]Fed Ex ❑UPS ❑USPS ❑ Commercial ❑Race ❑Other: 92422569 Custody Seal Present? ❑Yes .450 Seals Intact? ❑Yes / I` o Dat9/InitlalsPerson Examining Contents*l ' Packing Material: []Bubble Wrap ❑Bubble Bags []None �f Other Biological Tissu Fr en? Thermo eter, []Yes []No �2-rQS�� Type of Ice:�INet ❑Blue ❑None Gun 10; ] Cooler Terrip (`Cl: e�—' ' Correctlon Factor: Add/Subtract (°C) 0,0 _ Temp should be above ftee:ing to 6'C Cooler Temp Corrected ('C): []samples out of temp criteria. Samples on Ice, cooling process has begun USDA Regulated Soil N A, water sample) Did samples oOPanate In`a quarantine none within the United States: CA, NY, or SC (check maps)? Did samples onglnate from a foreign source pn emdlIon aHY, - ri�e. ru including Hawaii and Puerto We)? ❑Yes a Chain of Custody Present? Barnpies Arrived within Hold Time? Short Hold Time Analvsls 02hr.)? Rush Tuin Around Time Requested? Sufficient Volome? Correct Containers Used? .Pace Containers Used? Containers Intact? Dissolved analysis: Sarnples Field Filtered? Sample Labels Match COC? -IhcludesDate/Tifne/tD/Analysis Matrix: Headspace in VOA Vials [a5-6mm)? Trip Blank Present? Trip Blank Custody Seals Present? COMMENTS/SAMPLE DISCREPANCY ❑No ❑N/A gy- ❑No [ V 1. 2. 3. 4. S. 6. No ❑NIA 10. No ❑N/A 11. No f]N/A Lot ID of spilt containers: CLIENT NOTIFICATION/RESOLUTION Person contacted: Date/Tlme: �• - I I Project Manager SCURF Review: Project Manager SRF Review: --J Field Data Required? ❑Yes ❑No Date: Date: I Page 10 of 12 Document Name: Sample Condition Upon Rec Document No.: F-CAR-CS-033-Rev.1 Document Revised: Feoruary 1, Lu,o page 1 of z Issuing Authority: Pace Carollnas quality Office *Check mark top half of box' if pH and/or dechlorination is Project #i f WO # : 924 225 6 d verified and within the acceptance range for preservation PM: MWB Due Date: 04/08/19 samples. CLIENT: 92-Pr ism Exceptions: VOA, Coliform, TOG, Oil and Grease, DRO/9015 (water) DOC, LLHg "Bottom half of box is to list number of bottle tr u 2 u E N rr a m zZ v c u E ✓1 N d m c u E O `4 a m a ? v v t 'M i m u N v O eq T u_ E ei a m v O a E 0 a m ON = N U ,� E aq m u A 2 m J E N i m v e ' �a L7 e E v 3 3 _ y w 7 v a W W l7 a S `m a Q r W S W t7 a z lu 2 C `w n E J E r�1 l7 a v = X a G u .i .� t7 a v a E ..J E O rh Vf l7 a .. U z o Q E �7 a U z O E O = a1 t7 o> Z ,� z O J E O F al l9 c O J E O q 7 OI ` ?��� m z O J E O a 01 C Z 3 m " Y 4 ? C A = a „ .M.. Y t7 > Z N K J E ry F N N I NS 2c E o �n fV H N vat k_ z �� m vt Nv P „ a c o N in m ? m > w u01i a Q E o rl O ¢ a Z e 2 •run J c N 177 j ? M -> u v c 6 J o Q a�i o z 3 4 5 6 7 8 9 10 11 lz pH Adjustment Log for Preserved Samples Sample ID Type of Preservative pH upon receipt Date preservatian adjusted Time preservation Amount of Preservative Loth adjusted added Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (i.e. Out of hold, incorrect preservative, out of temp, incorrect containers. Page 11 of 12 h��d Secvr[ej Z,..,.PR1S%� I Full-SeruiceArtalylieal8 3 (-1(I e V^ fin- J v Environmental Solutions rl SUBCONTRACT ORDER Cct't1 IICDl Foil: AC USACE Prism Laboratories, Inc. NC SC_ Othlr 9030363 N/A^ SfiN❑INijLAB[IRATORY: UCEIVIm-, LAnORATORY: Prism Laboratories, Inc. Pace Analytical, Inc P. O. Box 240543 980U Kincey Avenue Suite 100 sf, ?ae_e_. Charlotic. NC 25224-0543 Hunicrsville, NC 28073 lE f Phone: 800-529-6364 'Fax: Phone :(704) S 75-9092 pf 0, q L Y 4Y 1 DD 704-525-0409 /�`� [ �G Fax: (704) 375-9091 PIDMCt Manager: Robbi A. Fortes "`(-, J ` ?,I I j 10 I�v I I A Analysls Due Expires Labornlory ID Comments Sample ID: 91130363.01 524.2(Sub) Cnuariuera Supplied: 3WAs Smnple ID: V030363.02 524 2 (Sub) Cnnminers Srgrplicd Water S--,*d: 03/21119 12:411 D w — 6 t 60 04/04/19 12 00 Arc-{6ic klt� r,�-I( zW 1_)s Water S-mplyd: D3/21/19 00:1111- 04/0.1/1900:00 Aw Nc Sys F ebb w)4 ktrafT D. i tc 1: iCw n cr: H •. D:,t: ,:',', I >>' PACE lw. - D;nr I:, L •a1itY I)'I.t P.a•.:i.irn, lbr, Rrlc,rSrd liy Page Iof1 N C, Page 12 of 12 .. `_PRISM Full -Service Analytical 8 Environinental Solutions `>>— '_V LABORATORIES INC. Anchor QEA of North Carolina, PLLC Brian Gant 231 Haywood Street Asheville, NC 28801 NC Certification No. 402 Case Narrative NC Drinking Water Cert No. 37735 4/9/19 14:35 SC Certification No. 99012 Project: Jackson Cty Landfill (Permit 50-02) Project No.: 50-02 Lab Submittal Date: 03/22/2019 Prism Work Order: 9030367 This data package contains the analytical results for the project identified above and includes a Case Narrative, Sample Results and Chain of Custody. Unless otherwise noted, all samples were received in acceptable condition and processed according to the referenced methods. Data qualifiers are flagged individually on each sample. A key reference for the data qualifiers appears at the end of this case narrative. Narrative Notes: Dissolved Hydrogen, Carbon Dioxide, Ethane, Ethene, Methane and Volatile Fatty Acides analysed subcontracted to Pace. Laboratory report is attached with a total page count of 32 pages. Please call if you have any questions relating to this analytical report. Respectfully, PRISM LABORATORIES, INC. Robbi A. Jones President/Project Manager Data Qualifiers Key Reference: BRL Below Reporting Limit MDL Method Detection Limit RPD Relative Percent Difference Reviewed By Robbi A. Jones President/Project Manager Results reported to the reporting limit. All other results are reported to the MDL with values between MDL and reporting limit indicated with a J. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-800/529-6364 - Fax: 704/525-0409 PRISMEnvi�Ii�Full- ti -• en Analyticallal Solutionss ... ......IEG. INC. Sample Receipt Summary 04/09/2019 Prism Work Order: 9030367 Client Sample ID Lab Sample ID Matrix Date/Time Sampled Date/Time Received MW-03 9030367-01 Water 03/20/19 12:02 03/22/19 8:25 MW-04 9030367-02 Water 03/19/19 10:57 03/22/19 8:25 MW-06 9030367-03 Water 03/21/19 9:58 03/22/19 8:25 MW-07 9030367-04 Water 03/19/19 12:35 03/22/19 8:25 MW-05R 9030367-05 Water 03/20/19 10:40 03/22/19 8:25 MW-01 9030367-06 Water 03/21/19 13:13 03/22/19 8:25 MW-02 9030367-07 Water 03/21/19 11:28 03/22/19 8:25 Samples were received in good condition at 3.0 degrees C unless otherwise noted. This report should not be reproduced, except in its entirety, without the written consent of Prism Laboratories, Inc. 449 Springbrook Road - P.O. Box 240543 - Charlotte, NC 28224-0543 Phone: 704/529-6364 - Toll Free Number: 1-8001529-6364 - Fax: 704/525-0409 T W p M u E r 2u ?j _0 0 o � N d C w ci Y " vN � /A) (Nse QO �oelu dweS N Z Z 0 Z = = y z o T (NOO -,el000 peleeS c Q 0 d w CD 0. 0. f (N/A) Bol t°7i d w uo penleoea Q � (NIJ.) auuol40 Ienplsaa 00 0, ul dwel a w a a ~ = o �M �Q IOU CO W w W �R- AD co 0 w M w Y! „ r z O Q m N O P_ N 4 t Z 1. 3 ? G r_' 7� U. a Q c 'm 1 N /Al t ;sal SISAIL'Uvt a. 0 ia410 s HOM '8 ale;aoy OUIZ iL cwi iid8 1 !J'S y j U Q dSl IOH ° r �' eONH _ °OSZH LUPaivasaaduNo v •u 'i�o CY a¢af CL a , f0 SlBNIV1N00 0 #G¢f W N0110311001V duel EldWVS ,n w w w Q z Q Q W ...J H m ~ m z o E O ww •=! .J ° o= o V a Z z z S z a N �� _ Kl J o -d ~ 1 W a. 2 ai fJ`1 S ca �— a m w O v 0 W Z, (dW00=0 9V2iJ=`J) 3d1.13ldWVS a d z = (gel of sePo3 Pllen ees) 3400 XRl1VW a E E J ap d 0 m o Q 2S CL 0 i� c FL 4) 0o >aNO3¢F0 ap m0 9 Z U) w W- U 3- 0. U O r �rt V I l I 1 K x m 0 3 " U) � N O o`33a�io3aP LE O V S .� w z z w 77 z o U S u_ o � H w c W m J m� Q o z€ o N R oIF E w v Oy`I a iw n K # wall w M a us �o i. ao rn PaceAnalytical I April 10, 2019 Robbi A. Jones Prism Laboratories, Inc. P.O. Box 240543 Charlotte, NC 28224-0543 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RE: 9030367 Pace Workorder: 29815 Dear Robbi Jones: Enclosed are the analytical results for sample(s) received by the laboratory on Tuesday, March 26, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Ruth Welsh 04/10/2019 Ruth.Welsh@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS YI��aC This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC Total Number of Pages 29 Pagel of 23 aceAnalytical LABORATORY ACCREDITATIONS & CERTIFICATIONS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and RecoveryAct (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS 1�7��C This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 23 IA,2 aceAnalytical +1 I SAMPLE SUMMARY Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 298150001 MW-03 Water 3/20/201912:02 3/26/2019 10:35 298150002 MW-03 Bubble Strip 3/20/2019 12:02 3/26/2019 10:35 298150003 MW-04 Water 3/19/201910:57 3/26/2019 10:35 298150004 MW-04 Bubble Strip 3/19/2019 10:57 3/26/2019 10:35 298150005 MW-06 Water 3/21/2019 09:58 3/26/2019 10:35 298150006 MW-06 Bubble Strip 3/21/2019 09:58 3/26/2019 10:35 298150007 MW-07 Water 3/19/201912:35 3/26/2019 10:35 298150008 MW-07 Bubble Strip 3/19/2019 12:35 3/26/2019 10:35 298150009 MW-05R Water 3/20/201910:40 3/26/2019 10:35 298150010 MW-01 Water 3/21/201913:13 3/26/2019 10:35 298150011 MW-02 Water 3/21/201911:28 3/26/2019 10:35 Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS �7 '�� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 23 _ ceAnalytical PROJECT SUMMARY Workorder: 29815 9030367 Workorder Comments Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Sample headspace vial not sufficiently pressurized for analysis. Vial pressurized with an equal volume of UHP Nitrogen and analyzed. Results reported at a dilution. Samples 29815 (0002, 0004, 0006, 0008). This report is being revised to correct sample collection dates for samples 298150004-0007 and 298150010-0011 Report ID: 29815 - 1154846 11 CERTIFICATE OF ANALYSIS rM This report shall not be reproduced, except In full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 23 Pace Analytical Energy Services LLC 220 William Pitt Way aceAnalytical Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 ANALYTICAL RESULTS Workorder: 29815 9030367 Lab ID: 298150010 Date Received: 3/26/2019 10:35 Matrix: Water Sample ID: MW-01 Date Collected: 3/21/2019 13:13 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.20 U mg/I 0.20 0.014 1 3/29/2019 14:39 KB Acetic Acid 0.91 mg/I 0.10 0.024 1 3/29/2019 14:39 KB Propionic Acid 0.10 U mg/I 0.10 0.0044 1 3/29/2019 14:39 KB Formic Acid 0.22 mg/I 0.20 0.048 1 3/29/2019 14:39 KB B Butyric Acid 0.10 U mg/I 0.10 0.0047 1 3/29/2019 14:39 KB Pyruvic Acid 0.10 U mg/I 0.10 0.0057 1 3/29/2019 14:39 KB i-Pentanoic Acid 0.10 U mg/I 0.10 0.0075 1 3/29/2019 14:39 KB Pentanoic Acid 0.10 U mg/I 0.10 0.012 1 3/29/2019 14:39 KS i-Hexanoic Acid 0.20 U mg/I 0.20 0.0049 1 3/29/2019 14:39 KB Hexanoic Acid 0.20 U mg/I 0.20 0.012 1 3/29/2019 14:39 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1800 ug/I 0.50 0.046 1 4/3/2019 09:40 BW n Ethane 0.16 ug/I 0.10 0.0050 1 4/3/2019 09:40 BW n Ethene 0.10 U ug/I 0.10 0.0040 1 4/3/2019 09:40 BW n Carbon Dioxide 280 mg/I 5.0 0.45 1 4/3/2019 09:40 BW n Report ID: 29815 - 1154846 Page 14 of 23 CERTIFICATE OF ANALYSIS ���� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC aceAnalytical I ANALYTICAL RESULTS Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150011 Sample ID: MW-02 Date Received: 3/26/2019 10:35 Matrix: Water Date Collected: 3/21/2019 11:28 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.20 U mg/I 0.20 0.014 1 3/29/2019 15:36 KB Acetic Acid 0.18 mg/I 0.10 0.024 1 3/29/2019 15:36 KB Propionic Acid 0.10 U mg/I 0.10 0.0044 1 3/29/2019 15:36 KB Formic Acid 0.20 U mg/I 0.20 0.048 1 3/29/2019 15:36 KB B Butyric Acid 0.10 U mg/I 0.10 0.0047 1 3/29/2019 15:36 KB Pyruvic Acid 0.10 U mg/I 0.10 0.0057 1 3/29/2019 15:36 KB i-Pentanoic Acid 0.10 U mg/I 0.10 0.0075 1 3/29/2019 15:36 KB Pentanoic Acid 0.10 U mg/I 0.10 0.012 1 3/29/2019 15:36 KB i-Hexanoic Acid 0.20 U mg/I 0.20 0.0049 1 3/29/2019 15:36 KB Hexanoic Acid 0.20 U mg/I 0.20 0.012 1 3/29/2019 15:36 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.50 U ug/I 0.50 0.046 1 4/3/2019 10:55 BW n Ethane 0.10 U ug/I 0.10 0.0050 1 4/3/2019 10:55 BW n Ethene 0.10 U ug/I 0.10 0.0040 1 4/3/2019 10:55 BW n Carbon Dioxide 54 mg/I 5.0 0.45 1 4/3/2019 10:55 BW n Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS f•IE�C This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 15 of 23 lacieAnalXical Workorder: 29815 9030367 ANALYTICAL RESULTS Pace Analytical Energy Services LLC 220 William PittVVay Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150001 Date Received: 3/26/2019 10:35 Matrix: Water Sample ID: MW-03 Date Collected: 3/20/2019 12:02 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G LacticAcid Acetic Acid Proplonlc Acid Formic Acid Butyric Acid Pyruvlc Acid I-Pentanolc Acid Pentanoic Acid 1-Hexanoic Acid Hexanoic Acid Report ID: 29815 - 1154846 ' nelac =: Analytical Method: AM23G 0.20 U mg/I 0.20 0.014 ' 0.10 U mg/I 0.10 0.024 ' 0.10 U mg/I 0.10 0.0044 ' 0.55 mg/I 0.20 0.048 0.10 U mg/I 0.10 0.0047 ' 0.10 U mg/I 0.10 0.0057 ' 0.10 U mg/I 0.10 0.0075 ' 0.10 U mg/I 0.10 0.012 ' 0.20 U mg/I 0.20 0.0049 ' 0.20 U mg/I 0.20 0.012 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB 3/29/2019 08:05 KB CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. B Page 5 of 23 lac,Analytical ANALYTICAL RESULTS Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-6245 Fax: (412) 826-3433 Lab ID: 298150002 Sample ID: MW-03 Date Received: 3/26/2019 10:35 Matrix: Date Collected: 3/20/2019 12:02 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX AnatylIcal Method: AM20GAX Methane 0.20 U ug/I 0.20 0,044 2 4/3/2019 05A3 TD d,n Ethane 0.020 U ug/I 0.020 0.0060 2 4/3/2019 05:43 TD d,n Ethene 0.020 U ug/I 0.020 0.010 2 413)2019 05:43 TD d,n Carbon Dioxide 55 mg/I 4.0 1.6 2 4/3/2019 05:43 TD d,n Hydrogen 120 nM 4.0 10 4 402019 08-05 TD d,n Report ID: 29815 - 1154846 Page 6 of 23 CERTIFICATE OF ANALYSIS r7���C This report shall not be reproduced. except in full, without the written consent of Pace Analytical Energy Services LLC. aceAnalytical ANALYTICAL RESULTS Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150003 Date Received: 3/26/2019 10:35 Matrix: Water Sample ID: MW-04 Date Collected: 3/19/2019 10:57 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G /0alylical Method: AM23G LacticAcid 0.20 U mg/I 0.20 0.014 1 3/29/2019 10:54 KB Acetic Acid 0.10 U mg/I 0.10 0.024 1 3/29/2019 10:54 KB ProplonicAcld 0.10 U mg/I 0.10 0.0044 1 3/29/2019 10:54 KB FormicAcld 0.62 mg/I 0.20 0.048 1 3/29/2019 10:54 KB B ButyricAcld 0.10 U mg/I 0.10 0.0047 1 3/29/2019 10:54 KB PyruvlcAcid 0.10 U mg/I 0.10 0.0057 1 3/29/2019 10:54 KB i-Pentanoic Acid 0.10 U mg/I 0.10 0.0075 1 3/29/2019 10:54 KB Pentanoic Acid 0.10 U mg/I 0,10 0.012 1 3/29/2019 10:54 KB i-Hexanolc Acid 0.20 U mg/l 0.20 0.0049 1 3/29/2019 10:54 KB HexanoicAcid 0.20 U mg/1 0.20 0.012 1 3/29/2019 10:54 KB Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS �ila� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 7 of 23 0 aceAnalXical ANALYTICAL RESULTS Workorder. 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150004 Sample ID: MW-04 Date Received: 3/26/2019 10:35 Matrix: Date Collected: 3/19/2019 10:57 Bubble Strip Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysts Desc: AM20GAX Analy#iCal Method: AM20GAX Methane 14 ugA 0,20 0,044 2 4/3/2019 06:02 TD d.n Ethane 0.020 U ug/I 0,020 0.0060 2 4/3/2019 06 02 TD d.n Ethene 0.020 U ug/i 0.020 0,010 2 4/3/2019 06:02 TD d.n Carbon Dioxide 140 mg/I 4,0 1.6 2 413/2019 06: 02 TD d.n Hydrogen 110 nM CO 3.0 4 4131201908:20 TD d.n Report ID: 29815 - 1154846 Page 8 of 23 CERTIFICATE OF ANALYSIS f"1��C . This report sholl not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way aceAnalytical Pittsburgh, PA 15238 Phone: (412) 826-5245 I Fax: (412) 826-3433 ANALYTICAL RESULTS Workorder: 29815 9030367 Lab ID: 298150009 Date Received: 3/26/2019 10:35 Matrix: Water Sample ID: MW-05R Date Collected: 3/20/2019 10:40 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.20 U mg/I 0.20 0.014 1 3/29/2019 13:43 KB Acetic Acid 0.17 mg/I 0.10 0.024 1 3/29/2019 13:43 KB Propionic Acid 0.10 U mg/I 0.10 0.0044 1 3/29/2019 13:43 KB Formic Acid 0.20 U mg/I 0.20 0.048 1 3/29/2019 13:43 KB B Butyric Acid 0.10 U mg/I 0.10 0.0047 1 3/29/2019 13:43 KB Pyruvic Acid 0.10 U mg/I 0.10 0.0057 1 3/29/2019 13:43 KB i-Pentanoic Acid 0.10 U mg/I 0.10 0.0075 1 3/29/2019 13:43 KB Pentanoic Acid 0.10 U mg/I 0.10 0.012 1 3/29/2019 13:43 KB i-HexanoicAcid 0.20 U mg/I 0.20 0.0049 1 3/29/2019 13:43 KB HexanoicAcid 0.20 U mg/I 0.20 0.012 1 3/29/2019 13:43 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 2500 ug/I 0.50 0.046 1 4/3/2019 09:30 BW n Ethane 0.28 ug/I 0.10 0.0050 1 4/3/2019 09:30 BW n Ethene 0.10 ug/I 0.10 0.0040 1 4/3/2019 09:30 BW n Carbon Dioxide 61 mg/I 5.0 0.45 1 4/3/2019 09:30 BW n Report ID: 29815 - 1154846 Page 13 of 23 CERTIFICATE OF ANALYSIS r12��iC This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. aceAnalytical i ANALYTICAL RESULTS Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID- 298150005 Date Received: 3/26/2019 10:35 Matrix: Water Sample ID: MW-06 Date Collected: 3/21/2019 09:58 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES �.ni dyci;, Desc: AM23G Analytical Method; AM23G LacticAcld 0.20 U mg/1 0.20 0.014 1 3/29/2019 11:50 KB Acetic Acid 2.0 mg/1 0.10 0.024 1 3/29/2019 11:50 KB Proplonic Acid 0.10 U mg/I 0.10 0.0044 1 3/29/2019 11:50 KB Formic Acid 0.20 U mg/I 0.20 0.048 1 3/29/2019 11:50 KB B Butyric Acid 0.10 U mg/I 0.10 0.0047 1 3/29/2019 11:50 KB Pyruvic Acid 0.10 U mg/I 0.10 0.0057 1 3/29/2019 11:50 KB i-Pentanoic Acid 0.10 U mg/I 0.10 0.0075 1 3/29/2019 11:50 KB Pentanoic Acid 0.10 U mg/I 0.10 0.012 1 3/29/2019 11:50 KB 1-HexanoicAcid 0.20 U mg/I 0.20 0.0049 1 3/29/2019 11:50 KB Hexanolc Acid 0.20 U mg/I 0.20 0.012 1 3/29/2019 11:50 KB Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS . �e�� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 9 of 23 aceAnalytical I Workorder: 29815 9030367 ANALYTICAL RESULTS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150006 Date Received: 3/26/2019 10:35 Matrix: Bubble Strip Sample ID: MW-06 Date Collected: 3/21/2019 09:58 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc:AM20GAX Analylical Method- Methane 0.45 ugli 0.20 0.044 2 4/3/2019 06.22 TD Ethane 0.020 U ugll 0.020 0.0060 2 41M019 06:22 TD Ethane 0.020 U ugll 0.020 0.010 2 4/3/2019 06:22 TD Carbon Dioxide 160 mg/I 4.0 1.6 2 4/3/2019 06.22 TD Hydrogen 4.8 nM 2.0 1.5 2 413/2019 06:22 T❑ Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. d,n d,n d,n d,n d,n Page 10 of 23 PceAnalytical I Workorder: 29815 9030367 ANALYTICAL RESULTS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 298150007 Date Received 3/26/2019 10:35 Matrix: Water Sample 10: MW-07 Date Collected 3/19/2019 12:35 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical N ell'i0d: AM23G. LacticAcld 0.20 U mg/I 0.20 0.014 1 3/29/2019 12:47 KB Acetic Acid 0.10 U mg/1 0.10 0.024 1 3/29/2019 12:47 KB Propionlc Acid 0.10 U mg/I 0.10 0.0044 1 3/29/2019 12:47 KB Formic Acid 0.20 U mg/I 0.20 0.048 1 3/29/2019 12:47 KB Butyric Acid 0.10 U mg/l 0.10 0.0047 1 3/29/2019 12:47 KB Pyruvic Acid 0.10 U mg/l 0.10 0.0057 1 3/29/2019 12:47 KB i-Pentanolc Acid 0.10 U mg/l 0.10 0.0075 1 3/29/2019 12:47 KB Pentanoic Acid 0.10 U mg/l 0.10 0.012 1 3/29/2019 12:47 KB i-HexanoicAcid 0.20 U mg/l 0.20 0.0049 1 3/29/2019 12:47 KB Hexanoic Acid 0.20 U mg/I 0.20 0.012 1 3/29/2019 12:47 KB Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS TI ��LC This report shall not be reproduced. except in full. without the written consent of Pare Analytical Energy Services LLC. A B Page 11 of 23 IceAnalytical ANALYTICAL RESULTS Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Workorder: 29815 9030367 Lab ID: 298150008 Date Received: 3/26/2019 10:35 Matrix: Bubble Strip Sample ID: MW-07 Date Collected: 3/19/2019 12:35 Parameters Results Units PQL MDL OF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 190 ug/I 0.20 0.044 2 4/3/2019 06:36 TD Ethane 0.081 ug/I 0.020 0.0060 2 4/3/2019 06:36 TO Ethane 0.10 ug/I 0.020 0.010 2 4/3/2019 06:36 TO Carbon Dioxide 210 mg/I 4.0 1.6 2 4/3/2019 06'36 TD Hydrogen 46 nM 2.0 1.5 2 413/2019 0636 TD Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS �IE��C ; This re" rtshrall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. d,n d,n d,n d,n d,n Page 12 of 23 aceAnalytical ANALYTICAL RESULTS QUALIFIERS Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. d The analyte concentration was determined from a dilution. Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS l���C� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC Page 16 of 23 aceAnalytical QUALITY CONTROL DATA Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4019 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 298150001, 298150003, 298150005, 298150007, 298150009, 298150010, 298150011 METHOD BLANK: 60387 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.20 U 0.20 Acetic Acid mg/I 0.10 U 0.10 Propionic Acid mg/I 0.10 U 0.10 Formic Acid mg/I 0.20 U 0.20 B Butyric Acid mg/I 0.10 U 0.10 Pyruvic Acid mg/I 0.10 U 0.10 i-PentanoicAcid mg/I 0.10 U 0.10 PentanoicAcid mg/I 0.10 U 0.10 i-HexanoicAcid mg/l 0.20 U 0.20 HexanoicAcid mg/l 0.20 U 0.20 LABORATORY CONTROL SAMPLE: 60388 Parameter Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers Lactic Acid mg/I 2 2.0 102 70-130 Acetic Acid mg/I 2 20 99 70-130 Propionic Acid mg/I 2 19 97 70-130 Formic Acid mg/I 2 1 9 95 70-130 B Butyric Acid mg/I 2 2.0 98 70-130 PyruvicAcid mg/I 2 2.0 102 70-130 i-Pentanoic Acid mg/I 2 1.9 95 70-130 PentanoicAcid mg/I 2 1.9 95 70-130 i-HexanoicAcid mg/I 2 1.7 86 70-130 HexanoicAcid mg/I 2 1.7 86 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 60389 60390 Original: 298150001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mgA 0.014 2 2.1 2.0 103 102 70-130 0.53 30 Acetic Acid mgA 0.059 2 2.0 2.0 99 98 70-130 0.32 30 Report ID: 29815 - 1154846 Page 17 of 23 CERTIFICATE OF ANALYSIS ���� - This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way aceAnalytical Pittsburgh. PA 15238 Phone: (412) 826-5245 II Fax: (412) 826-3433 QUALITY CONTROL DATA Workorder: 29815 9030367 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 60389 60390 Original: 298150001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers PropionicAcid mg/I 0.002 2 2.0 2.0 98 98 70-130 0.06 30 Formic Acid mg/I 0.55 2 2.2 2.1 83 79 70-130 4.2 30 B Butyric Acid mg/I 0 2 2.0 2.0 99 99 70-130 0.21 30 Pyruvic Acid mg/I 0.0077 2 2.1 21 104 104 70-130 0.13 30 i-Pentanoic Acid mg/I 0 2 2.0 20 98 98 70-130 0.1 30 Pentanoic Acid mg/I 0 2 2.0 20 100 101 70-130 0.66 30 i-HexanoicAcid mg/I 0 2 2.0 20 101 101 70-130 0.05 30 Hexanoic Acid mg/I 0 2 1.9 20 97 98 70-130 0.46 30 Report ID: 29815 - 1154846 Page 18 of 23 CERTIFICATE OF ANALYSIS lelav This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. aceAnalXical I QUALITY CONTROL DATA Workorder: 29815 9030367 QC Batch: DISG/7454 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 298150009, 298150010, 298150011 METHOD BLANK: 60476 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ugh 0.50 U 0.50 n Ethane ug/1 0.10 U 0.10 n Ethene ug/Y 0.10 U 0.10 n METHOD BLANK: 60477 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 5.0 U 5.0 n LABORATORY CONTROL SAMPLE & LCSD: 60478 60480 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 740 750 99 100 80-120 0.5 20 n Ethane ug/I 38 38 38 101 100 80-120 0.68 20 n Ethene ug/1 35 35 35 99 100 80-120 0.82 20 n LABORATORY CONTROL SAMPLE & LCSD: 60479 60481 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 130 130 109 108 80-120 0.41 20 n Report ID: 29815 - 1154846 nelac CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC Page 19 of 23 'y rN Pace Analytical Energy Services LLC 220 William Pitt Way f ccAnalytical Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QUALITY CONTROL DATA Workorder: 29815 9030367 QC Batch: DISG/7458 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 298150002, 298150004, 298150006, 298150008 METHOD BLANK: 60503 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ugA 0.10 U 0.10 n Ethane ug/I 0.010 U 0.010 n Ethene ug/l 0.010 U 0.010 n METHOD BLANK: 60504 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/1 2.0 U 2.0 n METHOD BLANK: 60505 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 1.0 U 1.0 n LABORATORY CONTROL SAMPLE & LCSD: 60506 60509 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 8.1 8.2 8.5 102 105 80-120 12 20 n Ethane ug/I 6.4 6.4 6.6 100 104 80-120 3.2 20 n Ethene ug/I 16 16 17 101 104 80-120 3.2 20 n LABORATORY CONTROL SAMPLE & LCSD: 60507 60510 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 97 91 94 94 97 80-120 3 20 n Report ID: 29815 - 1154846 Page 20 of 23 • �, CERTIFICATE OF ANALYSIS nelac~; This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC ceAnalytical QUALITY CONTROL DATA Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE & LCSD: 60508 60511 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 26 26 106 109 80-120 2.7 20 n Report ID: 29815 - 1154846 Page 21 of 23 CERTIFICATE OF ANALYSIS x �E�e . This report shall not be reproduced. except in full, without the written consent of Pace Analytical Energy Services LLC. ,�-',PkeAnalytical QUALITY CONTROL DATA QUALIFIERS Workorder: 29815 9030367 QUALITY CONTROL PARAMETER QUALIFIERS The analyte was detected In the associated blank. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 29815 - 1154846 -k CERTIFICATE OF ANALYSIS i1��C�� This report shall not be reproduced, except In full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 22 of 23 aceAnalytical r I QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 29815 9030367 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15236 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 298150001 MW-03 AM23G EDON/4019 298150003 MW-04 AM23G EDON/4019 298150005 MW-06 AM23G EDON/4019 298150007 MW-07 AM23G EDON/4019 298150009 MW-05R AM23G EDON/4019 298150010 MW-01 AM23G EDON/4019 298150011 MW-02 AM23G EDON/4019 298150009 MW-05R AM20GAX DISG/7454 298150010 MW-01 AM20GAX DISG/7454 298150011 MW-02 AM20GAX DISG/7454 298150002 MW-03 AM20GAX DISG/7458 298150004 MW-04 AM20GAX DISG/7458 298150006 MW-06 AM20GAX DISG/7458 298150008 MW-07 AM20GAX DISG/7458 Report ID: 29815 - 1154846 CERTIFICATE OF ANALYSIS �� '��..-� This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 23 of 23 Full -Service Analytical & d 0fiF R I S M �• Environmental Solutions IM SUBCONTRACT ORDER CerlificaliVn: NELAC_ USACE_ Prism Lahoi-atorles, Inc. NC ;� SC_ 0111111. 9030367 NIA SE LqD r; 1,6 R 0 R AT01RY.. RE ETVING LATIORATORV: Prism Laboratories, Inc. MicroseepslPace P. 0. Box 240543 220 William Pitt Way Charlotte, NC 28224-0543 Pittsburgh, PA 15238 Phone:800-529-6364 Pllonc:(412)826-5245 Fax:704-525-0409 Fax: (412) 826-3433 Project Manager: Robbi A. Jones Analysis Due Expires Laboratory 1D Comments Sample ID: 90311367-111 Water Smnpled: 03/20l19 12:02 m-v3 Dissolved Hydiogcn (Sub)FhF9 1z' fF2 Methane, Ethane, Ethcnc (AM20GP .03L3�H+?+i flZ Volatile Fatty Acids (Sub) 'H}h19-tyH9 Carbon Dioxide AM20GAX Cmrrnirrcrs ,Supplied: _7 G A K Sample ID: 9030367-02 Water Sampled: 03119/19 10:57 Carbon DioxideAM20GAX .44'"^11" 1^'`O Dissolved I1)•drogen (Sub) Methane, Ethane, Ethcnc (AMMU IIS:S2. Volatile Fatty Acids (Sub) .113L1a1 hJ-Fti f7. Conlablerx supplied, Sample ID: 9030367-03 Water St —pled: 03121/19 09:58 Volatile Fatty Acids (Sub) �}31i5 CaibonDiuxidcAM20CiAX `44+N+f•F 4948 Dissolved Hydrogen (Sub) Methane, Ethcnc, Etbenc IAM20(it h •� Conndncry suppiicrr: 3 9A K f Sample ID:9030367-04 NImer S:unplcd:0311911912:35 Dissolved I lydrogen (Sub) �:as Metb:mc, F..Ihunc, F..11tcnc (AM_Nri del' t ,.}5 Rclenscd IN r // - C Da(c Received By D.uc _ Rcicascd By I7ate 1'lcceivcd By Atc I7x(r Rcicascd 13y Diu Received 19}• _ 17.t(c• _ Rcicascd IL), D.nc Received 13y Datc SUBCONTRACT ORDER l t- Cslaif:ctlian• NELAC USACE_ Prism Laboratories, Inc. NC R� SC_ Other 9030367 NIA Analysls Due Expires LaboratotyID rComments Sample ID:9030367-04 Water Sampled ;0311911912:35 W 0 Volatile Fatty Acids (Sub) 0?P464tr3T Carbon Dioxide AM20GAX OYOb491M Containers Supplied; 3 6 A K Sample ID:9030367-05 Water Sampled; 03/20/19 10.40 rn Carbon DioxideAM20GAX r4A3:+°`R Methane, Ethane, Ethcne (AM20W 43f297Iv1V:3b Volatile Fatty Acids (Sub) 03fi7tf9'f B i9 Contufaers Supplied; mt~i—c:i Sample ID: 9030367-06 Wxtcr Spmplcd; 03/21/19 13:33 Carbon DioxideAM20GAX j 1-. 3 Methane, Ethane, Ethenc (AM20GA VTrA"ZT1 f . 3 Volatile Fatty Acids (Sub) 01*&1 -M.13 Confuirwrs Supplied: V Sample III:9030.167-07 Water Sampled; 03121/19 11:29 Volatile Fatty Acids (Sub) M7n7PJT"- Calton Dioxide AM20GAX it ) 11.28 Methano, Ethane, Ethcne (AM20Gp 4vr2TTTI M8 Conlafnevs Supplied; r-j r Released By Date Acce'ivcd By Date Rdea�cU 11y Dole Received By Dole Released By Dow Rereivacl By _ Dole Released By Da.c Received By Mm. / Cooler Receipt Form Client Name: j'-P( :.rr Project: / %, )-s > Lab Work Order: _ A. Shipping/Container Information (circle appropriate response) Courier: i FedEx UPS USPS Client Other: Air bill Present:,' Yes No Tracking Number: '7 7Y %.�r..l'l S f( Y Custody Seal on Cooler/Box Present: Y.e ,l O ] Seals Intact: Yes No Cooler/Box Packing Material: bid ie Wrap 1 Absorbent Foam Other: Type of Ice: 6t, Blue None lce Intact: Yes , Melted Cooler Temperature: I L1� T Radiation Screened: Yes f No Chain of Custody Present: Yes No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES NO N/A Comment Reference non -Conformance Chain of Custody properly filled out Chain of Custody relinquished Sampler Name & Signature on COC Containers intact Were samples in separate bags lam' Sample container labels match COC Sample name/date and time collected Sufficient volume provided " �x• PAES containers used Are containers properly preserved for the requested testing? (as labeled) If an unknown preservation state, were containers checked? Exception: VOA's coliform If yes, see pH form. Was volume for dissolved testing field filtered, as noted on the COC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by: ` 1 Date: Project Manager Review: AA1 Date: -5 F-PAE-Q-009-rev.01, 30ct2017 Date: -1 NON-CONFORMANCE FORM PASS Work Order M - :12 i Y / Time of Receipt: Receiver: Client: P/-, ""-)? REASON FOR NON-CONFORMANCE: a < ACTION ON TAKEN' CljeDt name: 4 CustomerCustomerService Initials:: .F-PAE-Q-0 I 4-rev-00., 20 No)72014 Date: Date: Time: Page 1 of 1 Joseph Ward - 9030367 From: Joseph Ward To: rjones@prismlabs.com Subject: 9030367 Upon receiving your samples for the project referenced above, We only received 1 vial for samples MW-05R, MW-01, and MW-02. We still have sufficient volume to run the analysis but no extra if needed. Joseph Ward Customer Service Pace Analytical Energy Services 220 William Pitt Way Pittsburgh PA 15238 412-826-5245/412-826-2384(Direct) about:blank 3/26/2019 Page 1 of 1 Ruth Welsh - Needing Confirm of Receipt From: "Robbi Jones" <rjones@prismlabs.com> To: "'Ruth Welsh"' <Ruth.Welsh@pacelabs.com> Date: 3/26/2019 3:34 PM Subject: Needing Confirm of Receipt Hi Ruth, did you receive Prism Project 9030367 today? 7 Samples. Also, please use Laboratory Sample ID that is highlighted (MW-03, etc.) Thankyoul &RISM I rolM�tns�„r+rcn.a ElW YBwn41nl8d).4enc (Ms.) Robbi A. Jones When You Need RESULTS ....... President rjones@..prismlabs.com Cell 803.448.6005 ivy,iv.prismlabs.com Fax 704.529.0405 Office: 704.529.6364 449 Springbrook Rd., Charlotte, NC 28217 / Mail: P.O. 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