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1302_Cabarrus_Units2and3_MSWLF_GW_FID1323364_20190627
Cabarrus County Sanitary Landfill -Units 2 and 3 Semi -Annual Sampling Report Facility Permit # 1302-MSWLF- CDLF-1998 (May 2019 Sampling Event) repared June 2019 i I pENRI/SE DNLY� I I ]Paper Repod ]Electronic Data -Email CD (data loaded: Yes/No) DorJEvent#: CC DI'� Environmental Monitoring Division of Waste Management -Solid Waste RepoRing Form Nogce: This form antl any information agachetl to it are "Public Recortls" as defined in NC General Statute 132-1. As such, these documents are available for Inspection antl examination by any person upon request (NC General Statute 132-8). Instructions: • Prepare one form for each intlivltlually moniloretl unit. • Please type or print legibly. • Attach a notifcaticn table with values that attain or exceetl NC 2L groundwater standards or NC 2B surface water smndartls. The ngtiflca8on must include a preliminary analysis of the cause and signifcance of each value. (e.g. naturelty oxurting, off -site source, pre-existing contlidon, etc.). • Altacha notification table of any grgundwater or surface water values that equal or exceetl the repgNng limits. ANach a notifcation table of any methane gas values that attain or exceed explosive gas levels. This Includes any stmctures on or nearby the facility (NCAC 13B .1829 (4)(a)(I). • Sentl the original signetl antl sealetl form, any tables, and Eledronlc Data DelNerable b: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1848 Mail Service Center, Raleigh, NC 2]699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner) Consultant - CDM Smith Inc. Confect for questions about data formatting. Inclutle data prepareYs name, telephone number and E-mall address: Name: Mathew F. Calorie Phone: (9191325-3500 E-mail: coloneml(dcdmsm'th com NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Faculty Permit# (.0500 or.1800) October 20-24, 200fi) Cabarrus County Landfgl Units2 4441 Irish Potato Road 1902-MSWLF- .O500 and .1600 May]-10, 2019 antl 3 Concord, North Carolina 28025 CDLF-1998 Environmental Status: (Check all that apply) InifiallBackgrountl Monitoring %� Detection Monitoring � Assessment Monitoring � Cortecgve Action TTTyyypppe of data submlltetl: (Check all that apply) Grgundwater monitoring tlata from monibdng wells �X Methane gas monitoring tlata Groundwater monitoring data from private watersupply wells ❑X Cortective action date (specify) MNA DaIa Leachate monitoring data � Others f X Surface water monitoring tlata (pact y) Notification attached? Ng. No grountlwa[eror surface water standards were exceetletl. X Ves, a notifcation of values exceeding a groundwater or sudace water standard Is attached. I[ Includes a Ilst of groundwater antl surface water onitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surtace water standard or NC Solid Waste GWPS antl preliminary analysis of the cause and signifcance of any cencentretion. Yes, a notification of values exceeding an explosive methane gas limit is attached. It inclutles Me methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowletlge, the information reponetl antl statements matle on this dale submittal antl attachments are true antl correct. Furthermore, I have altachetl complete notification of any sampling values meeting or ezceetling groundwater standards or explosive gas levels, and a preliminary analysis of the cause antl significance of conceniraligns exceetling groundwater stantlartls. 1 am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine antl imprisonment. MathewF Colone Consultant (9191325-3500 Fac li Pepresenta�tive�Na}� lPrintl TI[e I (Area Cgde)Telephgn `{4 p /l/ J7 // _ - G /,r `I � (� Affx N(>'iit'�EFR �ary61. • logist Seal Signature 'I �u`� Date111 /A � (�°�- V( y 5400 Glenwood Avenue Su le 400 Raleigh North Carolina 2]612 ` Fadllty Repmaentative Atldress � � - 5� F-0412 NC PE Firm License Number (If applicable effective May i, 2009) - - / /s '� � nn" Revisetl 6I2009 � Gl%�/ Zo ('t Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 26, 2019 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: May 2019 Semi -Annual Sampling Report Cabarrus County Landfill Units 2 and 3 Facility Permit Numbers 1302-MSWLF-CDLF-1998 Dear Ms. Drummond: CDM Smith Inc. (CDM Smith), on behalf of Cabarrus County, is submitting an electronic copy of the May 2019 semi-annual sampling event report. This letter report presents the results of the recently completed sampling at Units 2 and 3 of the Cabarrus County Landfill and constitutes the first semi- annual sampling event for 2019. The approved groundwater monitoring network consists of the following wells: MW-1, -3, -3 deep, -A, -B, -C, -D, -E Rep, -E deep, -F, -G, -H, -H deep, -I, -J, -K, -L, -L deep, -M, -X, CD-4 Rep, assessment wells AMW-1s, -1d, -2s, and -2d, and background wells CD -Is and CD-1d. Surface water sample locations include SW-1 and -2, which also monitor the Unit 1 Landfill. Assessment wells AMW-1s, -1d, -2s, and -2d were added to the groundwater monitoring network in October 2009 as part of the Corrective Action Plan (CAP) implementation. CD-4 Rep was installed in January 2009 as part of the proposed Phase I C&D Landfill expansion. Assessment wells CD-4, -5, and -6 were added to the groundwater monitoring network in September 2006 during the Phase I C&D Landfill expansion. Assessment wells CD-4 and -5 were abandoned in July 2010 in preparation of the Phase 2 C&D Landfill expansion. Assessment well CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Field activities, sampling and landfill gas screening results, and an evaluation of corrective action activities are discussed below. Field Activities Groundwater and surface water samples from Units 2 and 3 of the Cabarrus County Landfill were collected on May 7-10, 2019. Samples are collected from MW-3 deep, -L deep, and -M annually during the spring event. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated TeflonT' bailers or a QED bladder pump system using low -flow sampling Of WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond June 26, 2019 Page 2 techniques. Monitoring well and surface water locations for Units 2 and 3 are provided on Figure 1. Construction details for each monitoring well are summarized in Table 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 2. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. The groundwater elevations and potentiometric contours were used to estimate groundwater velocities at each well, which are presented in Table 3. After depth to groundwater was measured, three well volumes of water were removed from each well prior to sampling to provide fresh formation water within the well water column. Low -flow sampling techniques were used to purge and sample wells used to monitor natural attenuation. Each well volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen (DO), and oxidation-reduction potential (ORP) using a YSI Pro Plus multi -parameter water quality meter and Micro TPI or TPW turbidity meters. Wells with elevated turbidity were allowed to settle prior to sampling. The water quality parameters at the time of sampling are presented in Table 4. The headspace of each monitoring well was screened for methane gas using a RKI Eagle multi -gas monitor. Screening results are provided in Appendix A. Sampling Results Pace Analytical Services, Inc., located in Peachtree Corners, Georgia, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs), including 1,4-dioxane, and metals. Samples collected from CD-1s and -1d were also analyzed for tetrahydrofuran, iron, mercury, manganese, alkalinity, chloride, sulfate, and total dissolved solids (TDS). Samples for the North Carolina Appendix II constituent, bis (2-ethylhexyl) phthalate, are collected annually during the spring sampling event. Additional groundwater samples were collected to evaluate the effectiveness of natural attenuation and the Phase II injection event and are discussed in the Corrective Action Evaluation section of this letter report. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for Units 2 and 3 with detections of analytes above the MDL but below the MRL were qualified as estimated or "J" flags. The following list indicates the analytes detected above the MRL at each sampling location. No "J" flag or general chemistry detections are provided. Underlined analytes exceeded the 15A NCAC 02L .020 (NC 2L) Groundwater Quality Standard, Interim Maximum Allowable Concentration (IMAC), or the 15A NCAC 02B or North Carolina Protective Value Surface Water Quality Standard for Class C Waters. CD-1s (Background) Metals: Barium, Iron, Manganese Volatile Organic Compounds: None Detected 0 Smith Ms. Jadynne Drummond June 26, 2019 Page 3 CD-1d (Background) Metals: Barium, Iron Volatile Organic Compounds: None Detected CD-4 Rep Metals: Barium, Cobalt, Lead, Nickel, Zinc Volatile Organic Compounds: None Detected AMW-1s Metals: Barium, Beryllium Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethene AMW-1d Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: Benzene, Chloroethane, 1,1-Dichloroethane, 1,1-Dichloroethene, cis- 1,2-Dichloroethene, Trichloroethene, Vinyl Chloride AMW-2s Metals: Barium, Beryllium Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethene, Trichloroethene AMW-2d Metals: Barium, Zinc Volatile Organic Compounds: 1,1-Dichloroethane, cis- 1,2-Dichloroethene, Tetrachloroethene, Trichloroethene MW-1 Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: 1,1-Dichloroethane, 1,4-Dioxane MW-3 Metals: Barium Volatile Organic Compounds: 1,1-Dichloroethane, 1,1-Dichloroethene, cis-1,2-Dichloroethene, Tetra chloroethene, Trichloroethene MW-3 Deep Metals: Barium Volatile Organic Compounds: 1,1-Dichloroethane 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 4 MW-A Metals: Barium, Chromium, Cobalt, Nickel Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, Dichloroethane, 1,1-Dichloroethene, cis-1,2-Dichloroethene, Dichloropropane, Methylene Chloride, Tetrachloroethene, Total Xylenes, Trichloroethene MW-8 Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: 1,4-Dioxane MW-C Metals: Barium, Chromium, Nickel Volatile Organic Compounds: None Detected MW-D Metals: Barium, Cobalt, Nickel, Vanadium Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, cis-1,2- Dichloroethene, Trichloroethene MW-E Rep Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, 1,1- Dichloroethane, cis- 1,2-Dichloroethene, 1,4-Dioxane, Vinyl Chloride MW-E deep Metals: Barium, Cobalt, Lead, Nickel Volatile Organic Compounds: Benzene, Chlorobenzene, Chloroethane, 1,4-Dichlorobenzene, Dioxane MW-F Metals: Barium, Cobalt, Copper, Nickel Volatile Organic Compounds: 1,4-Dioxane MW-G Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: Chlorobenzene, 1,4-Dichlorobenzene, 1,4-Dioxane MW-H Metals: Barium Volatile Organic Compounds: None Detected 0 Smith Ms. Jadynne Drummond June 26, 2019 Page 5 MW-H deep Metals: Barium Volatile Organic Compounds: None Detected MW-1 Metals: Barium Volatile Organic Compounds: 1,1-Dichloroethan Trichloroethene MW-J Metals: Barium Volatile Organic Compounds: None Detected MW-K Metals: Barium Volatile Organic Compounds: None Detected MW-L Metals: Barium Volatile Organic Compounds: None Detected MW-L Deep Metals: Volatile Organic Compounds: MW-M Metals: Volatile Organic Compounds: MW-X Metals: Volatile Organic Compounds: SW-1 Metals: Volatile Organic Compounds: SW-2 Metals: Volatile Organic Compounds: cis- 1,2-Dichloroethene, Tetrachloroethe Barium, Zinc 1,1-Dichloroethane, cis-1,2-Dichloroethene, Tetrachloroethene Barium 1,1-Dichloroethane, 1,4-Dioxane Barium None Detected Barium, Nickel 1,4-Dioxane Barium, Nickel 1,4-Dioxane 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 6 "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Cobalt: MW-C Vanadium: CD-1s, -1d, -4 Rep, AMW-1s, -2s, -2d, MW-1, -3, -A, -C, -G, -H, -H Deep, -I, -J, -K, -L Deep, -M, and -X Bis(2-Ethylhexyl)Phthalate: MW-C Vinyl Chloride: MW-A and -D A trip blank, equipment blank, and duplicate sample were analyzed for quality control. No analytes were detected in the trip blank above the MDLs. Copper, zinc, acetone, and tetrahydrofuran were detected in the equipment blank as estimated detections below their respective NC 2L Standards. Chloroform and methylene chloride were also detected in the equipment blank below their respective NC 2L Standards. The duplicate sample, identified as Dup, was collected from MW-1 and had similar analyte concentrations as those detected in MW-1, with the exceptions of estimated detections of antimony, tetrahydrofuran, and trichloroethene below their respective NC 2L or IMAC Standards in the parent sample. Additionally, vanadium was an estimated detection in the parent sample above its IMAC Standard and cis-1,2-dichloroethene was an estimated detection in the duplicate sample below its NC 2L Standard. Metals detected above the standards are likely natural occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. A summary of detected constituents from the May 2011 to the May 2019 sampling events is presented in Table S. Laboratory analytical reports are provided in Appendix A. Corrective Action Evaluation In December 2008, CDM Smith, on behalf of the County, submitted an Assessment of Corrective Measures Report to the Solid Waste Section (SWS) for the closed landfill Units 2 and 3 in accordance with North Carolina Solid Waste Management Rule 15 NCAC 13B .1635. Monitored natural attenuation and institutional controls paired with in situ remediation by enhanced bioremediation was selected as the remedy to address groundwater contamination by select VOCs at the facility. In situ remediation efforts were to be focused on the bedrock contamination near monitoring wells MW-E Rep and -E deep. Groundwater contamination in the area of MW-E deep is caused by migration of leachate from the closed landfill Units 2 and 3 downward into the shallow fractured bedrock, thereby allowing low-level VOCs to migrate into this area prior to being attenuated below NC 2L Standards. Following approval of the CAP in September 2009 and the Phase I injection permit, six injection wells were installed upgradient of the MW-E cluster in October 2009 as shown on Figure 2. A 3% solution of potable water and EOS® 450, which is an emulsion of soybean oil and water, was injected 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 7 simultaneously into the injection wells from November 2-6, 2009. A total of 38,100 gallons of the solution were injected with each well receiving approximately 6,350 gallons. The initial injection of EOS®450 successfully degraded PCE and TCE to daughter products in the injection area and neither compound has been detected above the NC 2L Standards in MW-E deep since the Phase I injection in November 2009. It was assumed that the EOS® 450 would be viable for a period of 3 to 5 years. However, samples collected from the MW-E cluster and wells downgradient of the injection area during the November 2013 sampling event showed that groundwater contaminant concentrations had increased and levels exceeding the applicable NC 2L Standards had been detected in monitoring wells near the property line. Due to the increasing downgradient contaminant concentrations and NC 2L exceedances near the property line, the groundwater conditions were re-evaluated in accordance with the CAP and a Phase II injection was implemented. In order to assess the biological conditions in the injection area prior to initiating the Phase II injection, groundwater samples were collected from MW-E Rep, -E deep, AMW-1s, -1d, -2s, and -2d in January 2014 and analyzed for Deholococcoides spp (DHC), the bacteria responsible for degrading the chlorinated ethene species of VOCs. The specific genes of the bacteria that promote dechlorination were also analyzed. Analytical results for the DHC analyses are summarized in Table 7 and show that a sufficient population exists at monitoring wells MW-E, -E deep, and assessment monitoring well AMW-2s for reductive dechlorination by enhanced anaerobic bioremediation. DHC was detected at low concentrations in assessment monitoring wells AMW-1d and -2d and was not detected at AMW-1s. The absence of DHC at AMW-1s is likely associated with relatively low VOC concentrations. Following approval of the injection permit in January 2014, the Phase II injection was completed from February 10-18, 2014, using potable water and a 10% solution of 60% SRS®-FR large droplet emulsified vegetable oil substrate. SRS®-FR is specifically designed for use in fractured bedrock environments and is a mixture of 60% emulsified vegetable oil, 20% water, 5-15% of proprietary emulsifiers and nutrients, and 5% sodium lactate. The nutrient component of SRS®-FR further enhances the microbial population growth. A total of 9,966 gallons of the solution were injected during the Phase II event with each well receiving approximately 1,661 gallons. In order to monitor the progress of the Phase II injection and the geochemical and biological response of the aquifer, groundwater samples were collected quarterly from monitoring wells MW-E Rep and -E deep and assessment wells AMW-1s, -1d, -2s, and -2d. The first and third quarterly sampling events were completed in conjunction with the May and November 2014 semi-annual sampling events respectively. The second quarterly sampling event was completed in August 2014 and the fourth quarterly sampling event was completed in March 2015. A 15-month post -injection sampling event was completed in May 2015. 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 8 Water quality measurements of pH, temperature, ORP, DO, conductivity, turbidity, and ferrous iron were collected during each sampling event. In addition, the quarterly samples were submitted to an analytical laboratory for analysis of nitrate, sulfate, alkalinity, chloride, chemical oxygen demand (COD), VOCs, dissolved gases (i.e. methane, ethane, ethene, carbon dioxide), and metabolic acids (i.e. acetic acid, butyric acid, lactic acid, propionic acid, and pyruvic acid). North Carolina Appendix I metals were collected during events that corresponded with the semi-annual sampling program. Additional samples were collected during the fourth quarterly sampling event (March 2015) from monitoring wells MW-E Rep and -E deep and assessment wells AMW-1s, -1d, -2s, and -2d and analyzed for DHC to assess the biological conditions in the injection area after initiating the Phase II injection. A sufficient population of DHC existed at assessment monitoring well AMW-1d for reductive dechlorination by enhanced anaerobic bioremediation and DHC was detected at low concentrations in monitoring well MW-E deep. Detections of DHC in AMW-1d indicated a healthy population of DHC in the primary bedrock treatment zone surrounding the injection wells. DHC detections in MW-E deep was an indication that active treatment in bedrock was also occurring downgradient. DHC was not detected at MW-E Rep, AMW-1s, -2s, or -2d and was likely due to reduced VOC concentrations from upgradient treatment. Analytical results for the DHC analyses are summarized in Table 7. On September 28, 2015, a report summarizing the results of the Phase II injection was submitted to the SWS. The report stated that the Phase II injection of emulsified vegetable oil replenished the carbon source and complete reductive dechlorination is occurring at MW-E, -E Deep, and AMW-1d. The presence of DHC populations and functional genes in MW-E Deep and AMW-1d demonstrate that the treatment process is capable of achieving complete chlorinated VOC degradation as long as a sufficient carbon donor is present. As part of the semi-annual monitoring program, additional groundwater samples were collected from the background well CD-1s; monitoring wells MW-A, -E Rep, -E deep, -L, and -3; and assessment wells AMW-1s, -1d, -2s, and -2d. Samples were analyzed for alkalinity, biochemical oxygen demand, COD, carbon dioxide, chloride, dissolved hydrogen, ethane, ethene, volatile fatty acids (i.e. acetic, butyric, hexanoic, lactic, pentanoic, propionic, and pyruvic), ferrous iron, methane, nitrate, sulfate, sulfide, and total organic carbon. Note that ferrous iron was analyzed in the field using a Hach test kit due to the short hold time of 15 minutes. These additional samples were collected to evaluate natural attenuation and the effectiveness of the Phase II injection as part of the CAP. A complete summary of the geochemical results is provided in Table 5. Contaminant concentration trends for MW-A, -3, -E Rep, -E deep, AMW-1s, -1d, -2s, and -2d were evaluated to determine the effectiveness of natural attenuation and the Phase II injection. Figures 3 through 10 present total VOC contaminant concentration data for each well. An isoconcentration contour map with data from the May 2019 sampling event is provided on Figure 11. 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 9 The total VOC trend analysis for MW-A is presented on Figure 3. Total VOC concentrations increased in MW-A between June 1995 and April 2003 and decreased after the April 2003 event. Between the May 2011 and May 2019 events, total VOC concentrations show a fluctuating trend. Figure 4 presents the total VOC trend analysis for MW-3. Total VOC concentrations show an increasing trend. 1,1-Dichloroethane, PCE, and TCE are the only analytes that have been detected in MW-3 above the NC 2L Standards. The geochemical data indicates aerobic conditions at MW-3. VOC concentrations in MW-3 deep have never been detected above the standards. The total VOC trend analyses for MW-E Rep and -E deep are presented on Figures 5 and 6, respectively. Total VOC concentrations in MW-E Rep and -E deep have decreased since the November 2009 Phase I injection. PCE and TCE have not been detected above the NC 2L Standards in MW-E deep since the Phase I injection and have not been detected above the MDL since the August 2010 sampling event. Delivery of the carbon substrate (i.e. SRS®-FR) during the Phase II injection was effective based on the increase in COD at MW-E deep. Historical geochemical data shows reducing conditions exist at the MW-E cluster based on low DO, a negative ORP, and high methane concentrations. The increase in metabolic acids and ferrous iron at MW-E deep also indicates that a reducing subsurface environment exists. A geochemically reducing environment is favorable for anaerobic reductive dechlorination. Figures 7 and 8 present the total VOC trend analyses for assessment wells AMW-1s and -1d, respectively. Total VOC concentrations in AMW-1s show an increasing trend from November 2010 to May 2013 but show a decreasing trend from the May 2013 to the April 2019 sampling event. Total VOC concentrations in AMW-Id show a decreasing trend from the initial sampling in October 2009 to the May 2017 sampling event and have fluctuated since then. Historical data shows reducing conditions existed at AMW-1d but DO and ORP have fluctuated since the November 2017 sampling event. The concentration of vinyl chloride generally increased from the Phase II injection to the November 2017 sampling event while TCE concentrations decreased, indicating anaerobic reductive dichlorination is occurring as vinyl chloride is a daughter product of TCE. However, since the November 2017 sampling event, TCE concentrations have increased and the concentration of vinyl chloride decreased. VOC concentrations at AMW-1d will be monitored. The total VOC trend analyses for AMW-2s and -2d are presented on Figures 9 and 10, respectively. Total VOC concentrations at AMW-2s show an increasing trend between the initial sampling event in October 2009 and November 2014 but have fluctuated since the November 2014 sampling event. Total VOC concentrations show an increasing trend at AMW-2d since the November 2010 sampling event but have fluctuated since the Phase II injection was completed in February 2014. The AMW-2 cluster is located farthest downgradient of the injection area and the shallow well is screened in partially weathered rock. Geochemical results indicate an aerobic subsurface environment. 0 Smith Ms. Jaclynne Drummond June 26, 2019 Page 10 Landfill Gas Monitoring The approved landfill gas monitoring network consists of monitoring wells MGW-1 through -16. Site structures that are monitored on the property include the scale house, maintenance shop, electricity building, and recycling facility. Quarterly landfill gas monitoring of Units 2 and 3 was completed on February 25 and June 4, 2019, using a GEM 2000 landfill gas analyzer. Methane was detected in MGW-3 during both monitoring events at 3.3 and 1.0 percent, respectively. No hydrogen sulfide was detected in any monitoring wells or site structures during the monitoring events. Copies of the quarterly landfill gas monitoring results and equipment calibration data have been placed in the landfill operating record and are provided in Appendix B. Recommendations Units 2 and 3 of the Cabarrus County Landfill are unlined and are the source of VOC concentrations that are above the NC 2L Standards in downgradient monitoring wells. The injection remedy successfully reduced the contaminant concentrations in bedrock monitoring well MW-E deep and developed a primary VOC treatment zone in the vicinity of the injection wells and MW-E Rep. Downgradient VOC concentrations in bedrock and saprolite should continue to decrease due to reduced VOC concentrations in the primary treatment zone. Additional injections will be necessary in the future once all electron donors have been consumed and complete dechlorination stalls. The County will continue with the semi-annual assessment monitoring program. In addition to sampling for Appendix I VOCs, including 1,4-dioxane, and metals, and the Appendix II constituent, bis(2- ethylhexyl) phthalate (sampled at CD-1s, -1d, MW-C, -E deep, -H, -I, and AMW-2d during the spring sampling event), samples collected from CD-1s, MW-A, -E Rep, -E deep, -L, -3, AMW-1s, -1d, -2s, and -2d will continue to be analyzed for natural attenuation parameters during the semi-annual sampling events. Future analytical results will be monitored to evaluate if another injection will be needed. The next sampling event will be completed in the fall of 2019. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County 0 Table 1 Monitoring Well Construction Summary Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 DepthMonitoring Well Installation Geology of Total Facility Permit Number I Latitude Longitude Screened Diameter Code Date Interval (feet BTOC) 6-inch Screen, Filter Seal (inches) 1302-MSWLF-CDLF-1998 CD -Is 8/7/2006 35.47788 80.52334 Saprolite 29.53 18.0-28.0 16.0-28.0 14.0-16.0 2.0 (background well) 1302-MSWLF-CDLF-1998 CD-1d (background well) 7/21/2004 35.47788 80.52340 PWR 52.15 40.0-50.0 38.0-50.0 36.0-38.0 2.0 1302-MSWLF-CDLF-1998 AMW-1 10/6/2009 35.46915 80.52225 PWR 67.57 50.0-65.0 48.0-65.0 46.0-48.0 2.0 1302-MSWLF-CDLF-1998 AMW-1d 10/8/2009 35.46914 80.52227 Bedrock 96.93 0-78.0 84.0-94.0 82.0-94.0 80.0-82.0 2.0 1302-MSWLF-CDLF-1998 AMW-2 10/6/2009 35.46829 80.52232 PWR 39.90 -- 22.0-37.0 20.0-37.0 18.0-20.0 2.0 1302-MSWLF-CDLF-1998 AMW-2d 10/8/2009 35.46831 80.52233 Bedrock 63.55 0-51.0 55.0-60.0 53.0-60.0 51.0-53.0 2.0 1302-MSWLF-CDLF-1998 CD-4 Rep 1/15/2009 35.47656 80.52210 Saprolite 19.41 -- 6.0-16.0 4.0-16.0 2.0-4.0 2.0 1302-MSWLF-CDLF-1998 MW-1 1990s 35.47355 80.52105 Saprolite/PWR 29.93 18.0-28.0 16.0-28.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-3 2/17/1992 35.46794 80.52120 Saprolite/PWR 35.10 19.0-34.0 17.0-34.0 15.0-17.0 2.0 1302-MSWLF-CDLF-1998 MW-3 deep 6/3/2003 35.46785 80.52133 Bedrock 93.76 0-44.0 75.0-90.0 71.0-75.0 68.0-71.0 2.0 1302-MSWLF-CDLF-1998 MW-9 1990s 35.47706 80.51740 Saprolite/PWR 51.15 -- 39.0-49.0 37.0-49.0 35.0-37.0 2.0 1302-MSWLF-CDLF-1998 MW-A 9/16/1994 35.47289 80.52524 Saprolite/PWR 50.42 33.0-48.0 31.0-49.9 29.0-31.0 2.0 1302-MSWLF-CDLF-1998 MW-B 9/16/1994 35.47165 80.52081 Saprolite/PWR 15.22 2.5-12.5 2.0-13.0 1.0-2.0 2.0 1302-MSWLF-CDLF-1998 MW-C 9/16/1994 35.47042 80.52556 Saprolite/PWR 18.50 2.5-15.0 2.0-15.0 1.0-2.0 2.0 1302-MSWLF-CDLF-1998 MW-D 9/16/1994 35.47021 80.52394 Saprolite/PWR 30.15 18.0-28.0 16.0-28.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-E Rep 4/9/1996 35.46983 80.52212 PWR/Bedrock 45.65 28.0-43.0 25.0-45.0 23.0-25.0 2.0 1302-MSWLF-CDLF-1998 MW-E deep 9/2/1999 35.46974 80.52220 Bedrock 59.57 41.0-56.0 39.0-56.0 37.0-39.0 2.0 1302-MSWLF-CDLF-1998 MW-F 9/15/1994 35.47050 80.52040 Saprolite/PWR 20.08 3.0-18.0 1.5-18.0 0.5-1.5 2.0 1302-MSWLF-CDLF-1998 MW-G 9/15/1994 35.47290 80.52121 Saprolite/PWR 20.25 3.0-18.0 1.5-18.0 0.5-1.5 2.0 1302-MSWLF-CDLF-1998 MW-H 9/3/1999 35.46861 80.52310 Saprolite/PWR 32.70 19.5-29.5 17.5-29.5 15.5-17.5 2.0 1302-MSWLF-CDLF-1998 MW-H deep 9/2/1999 35.46851 80.52317 Bedrock 59.67 41.0-56.0 39.0-56.0 37.0-39.0 2.0 1302-MSWLF-CDLF-1998 MW-1 9/3/1999 35.46928 80.52076 Saprolite/PWR 65.18 47.0-62.0 45.0-62.0 43.0-45.0 2.0 1302-MSWLF-CDLF-1998 MW-J 9/3/1999 35.47403 80.52647 Saprolite/PWR 34.90 29.0-32.0 28.0-32.0 25.0-28.0 2.0 1302-MSWLF-CDLF-1998 MW-K 9/3/1999 35.46978 80.52467 Saprolite/PWR 36.08 18.0-33.0 16.0-33.0 14.0-16.0 2.0 1302-MSWLF-CDLF-1998 MW-L 9/2/1999 35.46771 80.52168 Saprolite/PWR 26.90 14.0-24.0 12.0-24.0 10.0-12.0 2.0 1302-MSWLF-CDLF-1998 MW-L deep 6/3/2003 35.46778 80.52168 Bedrock 65.20 0-48.0 53.0-63.0 50.0-63.0 47.0-50.0 2.0 1302-MSWLF-CDLF-1998 MW-M 6/2/2003 35.46743 80.52026 PWR 39.80 -- 21.0-36.0 18.0-36.0 16.0-18.0 2.0 1302-MSWLF-CDLF-1998 MW-X 12/1/1993 35.47225 80.52664 Saprolite/PWR 31.79 -- 20.0-30.0 18.0-30.0 16.0-18.0 2.0 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock 4. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Smith Page 1 of 1 June 2019 Table 2 Groundwater Elevations May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 it Monitoring Well Code Top of Casing Elevation Groundwater Elevation (AMSL) MW-1 (AM5L) 701.37 689.08 689.35 689.82 688.87 690.81 689.03 689.32 690.73 689.22 688.97 688.94 688.76 689.10 688.48 688.76 689.90 689.49 MW-3 670.37 652.20 651.67 654.06 652.48 654.70 654.34 656.75 652.60 655.97 654.26 657.31 655.78 657.56 655.20 656.52 659.53 658.47 MW-3 deep 668.33 655.15 NS 656.74 NS 657.43 NS 659.63 NS 658.99 657.48 660.27 659.10 661.06 658.68 660.09 660.36 660.70 MW-9 780.25 736.07 734.92 735.84 NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 746.80 703.02 702.39 703.59 703.09 702.45 703.45 705.01 702.49 703.28 702.60 704.73 704.39 703.58 703.50 702.71 703.45 707.23 MW-B 681.66 679.04 679.56 678.34 677.44 679.71 678.96 678.96 675.25 679.06 678.86 678.89 678.77 679.21 676.88 678.38 679.68 679.20 MW-C 694.98 686.66 683.43 684.58 682.88 690.12 683.78 688.55 682.14 688.33 682.70 688.74 683.29 689.03 682.63 683.75 690.09 682.94 MW-D 720.28 692.88 691.48 693.12 691.60 692.15 692.58 696.21 692.98 692.78 691.53 694.50 693.39 693.40 692.14 691.86 695.70 697.52 MW-E Rep 712.58 679.94 679.07 682.38 NS 680.25 682.53 685.83 682.49 683.00 680.93 684.97 683.18 682.85 678.66 682.76 683.49 688.28 MW-E deep 705.70 669.66 668.80 671.10 669.31 670.05 672.21 675.55 672.75 672.71 670.65 674.67 672.88 672.51 675.20 672.38 673.22 677.97 1302 - -1998 CDLF-1998 MW-F 681.06 672.27 672.60 671.61 667.86 673.91 671.41 672.51 668.38 672.66 671.66 672.46 670.61 672.84 669.57 671.73 674.33 672.97 MW-G 695.19 685.79 686.40 685.46 685.72 686.74 685.69 685.78 685.11 685.68 685.68 685.62 685.65 685.82 685.37 685.50 686.41 685.96 MW-H 699.23 670.19 669.25 671.30 669.74 670.32 672.62 675.66 672.74 672.67 671.03 674.90 673.29 672.50 671.87 671.92 672.52 671.88 MW-H deep 699.17 669.30 668.54 670.81 669.32 669.72 672.17 675.17 672.33 672.32 670.62 674.52 672.96 672.16 671.66 671.85 672.22 677.41 MW-1 709.30 661.43 660.65 662.40 660.82 662.70 662.90 665.83 662.00 664.00 662.17 665.50 663.72 665.28 662.95 664.52 665.01 667.47 MW-J 728.47 698.68 697.11 698.49 696.45 698.77 698.02 700.14 696.55 699.10 696.77 699.52 698.05 699.37 697.55 698.15 700.16 700.85 MW-K 702.91 679.22 676.91 679.73 676.51 679.51 679.09 682.24 677.86 680.25 676.84 681.21 678.35 680.15 677.33 678.94 680.58 683.30 MW-L 669.54 653.13 651.96 654.24 652.71 655.24 654.74 657.83 654.03 656.54 654.39 657.90 655.72 657.89 655.10 655.62 658.22 659.66 MW-L deep 672.51 654.62 NS 655.81 NS 656.74 NS 659.35 NS 658.15 656.14 659.50 657.51 660.49 656.95 658.43 660.66 661.16 MW-M 668.49 647.85 NS 648.19 NS 649.98 NS 650.69 NS 649.52 648.01 649.94 648.79 650.25 648.36 649.12 651.25 650.93 MW-X 710.28 697.62 700.80 697.38 695.25 699.28 696.54 698.95 695.53 698.02 696.14 698.64 696.83 698.46 695.93 696.67 700.50 697.07 smith Page 1 of 2 June 2019 Table 2 Groundwater Elevations May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 7Fa�.,H.ty Monitoring Well Code CD -Is (background well) Top of Casing Elevation 755.00 730.81 729.60 730.65 728.94 729.28 730.20 731.82 Groundwater 730.20 Elevation 730.42 (AMSL) 728.55 731.10 729.77 730.00 728.89 730.00 730.05 726.89 CD -Id (background well) 757.40 730.49 729.46 730.96 728.75 729.09 730.00 731.54 729.95 730.20 728.33 730.89 729.57 729.82 728.67 729.57 729.88 730.51 CD-4 Rep 739.15 727.71 728.74 727.35 730.70 728.69 730.69 727.97 729.45 728.68 730.45 728.90 730.38 728.00 729.24 731.83 728.50 1302-MSWLF- CD-6 741.40 707.71 706.81 707.55 706.10 706.02 704.04 710.20 709.30 707.64 706.65 708.75 708.44 -- -- -- -- -- CDLF-1998 AMW-Is 725.30 670.87 670.00 672.32 670.00 671.30 673.57 676.79 674.05 674.06 672.00 676.07 674.31 673.89 671.16 673.75 674.20 679.25 AMW-ld 725.80 670.58 669.77 672.03 670.34 671.05 673.31 676.62 673.02 673.85 671.73 675.85 674.09 673.67 672.91 672.60 674.05 679.12 AMW-2s 694.50 668.16 667.10 669.38 667.78 671.47 670.43 673.40 670.29 671.07 669.09 672.97 671.18 671.15 670.19 670.72 671.41 675.55 AMW-2d 694.50 668.49 667.68 669.90 668.32 669.12 671.05 673.95 670.70 671.60 669.65 673.53 671.82 671.60 670.74 671.20 671.72 676.32 Notes: 1. AMSL - Above Mean Sea Level 2. Blank Cells - Well not installed 3. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells. 4. MW-9 was removed from the monitoring program in November 2012. 5. MW-E Rep was not sampled during the Novemver 2012 sampling event due to laboratory oversight. 6. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. smith Page 2 of 2 June 2019 Table 3 Summary of Groundwater Velocities May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 03 Facility Permit Number Monitoring Well Code MW-A Gradient I 0.0157 Average Linear Velocity feet/day 6.12E+00 Gradient 0.0162 Average Linear Velocity feet/day 6.31E+00 Gradient 0.0164 Average Linear Velocity feet/day 6.40E+00 Gradient 0.0181 Average Linear Velocity feet/day 7.06E+00 Gradient 0.0143 Average Linear Velocity feet/day 5.56E+00 Gradient 0.0165 Average Linear Velocity feet/day 6.43E+00 MW-B 0.0171 1.27E+00 0.0163 1.20E+00 0.0180 1.33E+00 0.0183 1.35E+00 0.0162 1.20E+00 0.0175 1.29E+00 MW-C 0.0182 3.98E+00 0.0211 4.61E+00 0.0211 4.62E+00 0.0225 4.91E+00 0.0137 3.00E+00 0.0219 4.78E+00 MW-D 0.0097 3.42E+00 0.0104 3.68E+00 0.0100 3.53E+00 0.0109 3.88E+00 0.0098 3.47E+00 0.0104 3.67E+00 MW-E Rep 0.0154 5.36E+01 0.0155 5.42E+01 0.0141 4.93E+01 0.0148 5.16E+01 0.0139 4.86E+01 1302-MSWLF- CDLF-1998 MW-F 0.0181 1.65E+00 0.0175 1.60E+00 0.0188 1.72E+00 0.0207 1.89E+00 0.0168 1.53E+00 0.0188 1.72E+00 MW-G 0.0265 2.92E+00 0.0255 2.82E+00 0.0265 2.93E+00 0.0227 2.51E+00 0.0224 2.47E+00 0.0234 2.59E+00 MW-1 0.0276 6.05E+00 0.0268 5.87E+00 0.0271 5.92E+00 0.0236 5.16E+00 0.0226 4.95E+00 0.0242 5.30E+00 MW-9 0.0185 4.05E+00 0.0187 4.08E+00 0.0190 4.16E+00 CD -Is 0.0196 2.35E-02 0.0163 1.96E-02 0.0183 2.20E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-ls are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 1 of 3 June 2019 Table 3 Summary of Groundwater Velocities May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 0. 0. 0.10/31/2016 Facility Permit Number Monitoring Well Code MW-A Gradient I 0.0154 Average Linear Velocity feet/day 6.02E+00 Gradient 0.0169 Average Linear Velocity feet/day 6.59E+00 Gradient 0.0151 Average Linear Velocity feet/day 5.88E+00 Gradient 0.0165 Average Linear Velocity feet/day 6.42E+00 Gradient 0.0156 Average Linear Velocity feet/day 6.09E+00 Gradient 0.0172 Average Linear Velocity feet/day 6.73E+00 MW-B 0.0186 1.37E+00 0.0195 1.44E+00 0.0173 1.28E+00 0.0170 1.25E+00 0.0185 1.36E+00 0.0183 1.35E+00 MW-C 0.0183 4.00E+00 0.0226 4.95E+00 0.0166 3.63E+00 0.0221 4.84E+00 0.0178 3.89E+00 0.0234 5.13E+00 MW-D 0.0084 2.97E+00 0.0091 3.21E+00 0.0100 3.54E+00 0.0105 3.73E+00 0.0097 3.45E+00 0.0105 3.71E+00 MW-E Rep 0.0128 4.46E+01 0.0133 4.65E+01 0.0135 4.71E+01 0.0144 5.03E+01 0.0132 4.59E+01 0.0141 4.93E+01 1302-MSWLF- CDLF-1998 MW-F 0.0191 1.74E+00 0.0201 1.83E+00 0.0180 1.64E+00 0.0182 1.66E+00 0.0190 1.73E+00 0.0199 1.81E+00 MW-G 0.0242 2.68E+00 0.0237 2.62E+00 0.0235 2.60E+00 0.0226 2.49E+00 0.0239 2.64E+00 0.0232 2.56E+00 MW-1 0.0250 5.47E+00 0.0232 5.08E+00 0.0242 5.30E+00 0.0233 5.09E+00 0.0248 5.43E+00 0.0241 5.28E+00 M W-9 CD -Is 0.0177 2.13E-02 0.0185 2.23E-02 0.0173 2.07E-02 0.0181 2.17E-02 0.0178 2.14E-02 0.0189 2.26E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-ls are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 2 of 3 June 2019 Table 3 Summary of Groundwater Velocities May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 0: 0: 0• Facility Permit Number Monitoring Well Code MW-A Gradient I 0.0150 Average Linear Velocity feet/day 5.86E+00 GradienTVelocity 0.0180 Average Linear feet/day 7.01E+00 Gradient 0.0161 Average Linear Velocity feet/day 6.26E+00 Gradient 0.0139 Average Linear Velocity feet/day 5.43E+00 Gradient 0.0178 Average Linear Velocity feet/day 6.95E+00 MW-B 0.0174 1.29E+00 0.0191 1.41E+00 0.0174 1.28E+00 0.0170 1.25E+00 0.0200 1.48E+00 MW-C 0.0162 3.54E+00 0.0233 5.09E+00 0.0211 4.61E+00 0.0148 3.25E+00 0.0270 5.91E+00 MW-D 0.0097 3.43E+00 0.0109 3.86E+00 0.0103 3.66E+00 0.0074 2.61E+00 0.0092 3.28E+00 MW-E Rep 0.0138 4.82E+01 0.0166 5.79E+01 0.0133 4.63E+01 0.0133 4.64E+01 0.0126 4.40E+01 1302-MSWLF- CDLF-1998 MW-F 0.0181 1.65E+00 0.0200 1.82E+00 0.0182 1.66E+00 0.0171 1.56E+00 0.0202 1.84E+00 MW-G 0.0233 2.57E+00 0.0240 2.65E+00 0.0234 2.59E+00 0.0230 2.54E+00 0.0215 2.38E+00 MW-1 0.0241 5.26E+00 0.0244 5.34E+00 0.0243 5.31E+00 0.0236 5.17E+00 0.0220 4.81E+00 M W-9 CD -Is 0.0172 2.06E-02 0.0195 2.34E-02 0.0180 2.16E-02 0.0163 1.95E-02 0.0188 2.26E-02 (background well) Notes: 1. Blanks indicate no data. 2. Hydraulic conductivity and effective porosity values are estimated from previously performed slug tests and grain size analyses. 3. The gradient and linear velocity values shown for MW-9 and CD-ls are based on the average of all the listed wells. 4. The gradient and linear velocity values shown for MW-A are based on the average of MW-B, -C, -D, -E, and -F. 5. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 6. MW-9 was removed from the monitoring program in November 2012. 7. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. SmithPage 3 of 3 June 2019 Table 4 May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 32 No. 33 No. 34 No. 35 CD -Is (background well) 5.58 158 16.0 5.96 191 87 5.65 120 ,17.5 3.83 182 59 5.86 111 ,16.3 1.51 181 10 6.06 116 ,13.8 15.50 139 7 CD-ld (background well) 5.55 171 16.2 8.22 191 280 5.80 132 17.9 2.70 171 84 6.27 121 17.3 1.41 150 73 6.16 125 16.4 9.53 140 5 CD-4 Rep NS NS NS NS NS NS 5.84 284 17.9 1.40 145 18 6.37 390 15.4 0.00 156 13 6.47 207 15.6 0.00 -1 2 CD-6 5.55 257 16.8 3.19 130 55 5.49 269 16.4 4.19 183 13 5.76 208 18.4 0.78 202 7 6.03 221 16.2 0.00 71 1 AMW-ls 5.23 225 21.9 1.22 176 10 6.36 237 17.8 0.17 12 7 5.67 292 27.4 0.02 121 9 5.89 230 15.5 3.81 44 5 AMW-1d 6.09 569 22.0 0.01 89 4 7.60 638 17.3 0.00 -112 3 6.00 651 24.1 0.24 95 8 6.47 573 14.5 7.00 169 5 AMW-2s 5.65 135 17.8 2.10 128 36 7.72 148 17.0 2.47 -30 10 5.74 171 18.6 0.42 195 29 6.16 149 15.0 5.36 38 5 AMW-2d 6.24 241 19.1 0.75 107 3 6.96 167 13.9 1.07 -29 3 5.78 195 17.4 0.00 195 4 6.37 183 15.0 3.47 149 1 MW-1 6.03 1,870 16.6 2.96 -77 78 6.01 1,570 16.3 2.44 139 4 6.37 1,794 16.1 0.00 -22 2 6.57 1,480 15.4 0.00 31 9 MW-3 5.57 127 18.1 2.60 164 27 6.01 174 17.8 4.05 198 32 5.73 155 19.5 2.76 113 9 6.19 160 15.8 12.31 73 8 MW-3 deep 7.09 469 18.3 3.98 81 242 NS NS NS NS NS NS 7.93 329 17.1 0.39 21 191 NS NS NS NS NS NS MW-9 6.08 90 18.9 3.45 139 4 5.91 107 18.9 4.70 212 0 6.05 106 19.1 1.82 127 3 NS NS NS NS NS NS MW-A 5.01 292 17.3 1.08 113 4 5.47 324 17.9 0.06 205 1 5.47 411 17.1 0.00 103 3 5.47 371 14.7 2.66 140 2 1302-MSWLF- MW-13 6.45 1,350 14.2 3.70 -116 25 6.26 1,070 15.8 2.39 -78 5 6.70 1,097 14.8 0.00 -49 7 6.87 958 15.2 0.00 -82 10 CDLF-1998 MW-C 5.37 152 13.8 5.23 136 54 5.79 394 16.9 4.01 130 12 5.89 200 18.3 0.83 -16 46 5.93 187 15.2 0.00 28 4 MW-D 5.36 610 16.7 3.14 87 135 5.26 501 16.5 1.99 79 4 5.36 460 16.9 0.00 79 4 5.66 467 15.6 0.00 90 8 MW-E Rep 5.73 586 17.7 0.01 34 9 5.69 659 19.0 0.00 -115 4 5.96 785 19.3 0.00 13 6 DRY DRY DRY DRY DRY DRY MW-E deep 6.40 738 15.9 0 -51 7 6.54 823 18.7 0.00 -67 3 6.50 842 21.1 2.51 -76 9 6.50 822 16.5 1.70 78 >800 MW-F 6.35 1,120 14.3 2.43 -139 10 6.40 979 16.9 1.53 -95 4 6.30 826 16.2 0.00 -57 7 6.81 1,050 15.4 0.00 -92 12 MW-G 6.11 1,110 16.5 5.79 -99 29 5.91 917 17.4 2.85 -61 2 6.21 861 14.1 0.00 -63 3 6.51 997 16.1 0.00 -84 2 MW-H 5.29 230 14.5 9.03 197 212 5.82 176 14.9 6.13 193 7 5.20 145 15.0 3.90 74 13 6.45 171 14.6 0.00 -22 2 MW-H deep 5.53 369 15.1 5.97 192 43 5.83 263 15.1 6.91 186 6 5.74 270 14.6 0.96 35 11 6.40 251 16.1 6.27 17 1 MW-1 5.46 99 16.2 3.44 164 10 5.67 113 15.8 4.67 114 3 5.92 109 17.9 2.58 147 3 6.14 116 14.4 0.00 84 8 1AW-J 6.25 341 16.2 4.62 156 86 5.78 343 16.9 6.14 111 1 6.49 247 16.1 1.09 21 4 6.57 251 14.1 0.00 125 1 MW-K 5.47 269 15.6 4.74 153 38 5.09 311 16.4 4.32 47 8 5.75 200 15.8 1.90 143 8 6.00 235 14.8 0.00 103 9 MW-L 5.38 91 14.3 2.31 206 4 5.66 106 16.4 2.59 222 3 5.44 112 16.4 0.04 214 5 6.70 227 14.9 3.03 3 5 MW-Ldeep 6.65 368 18.7 3.49 103 18 NS NS NS NS NS NS 6.20 279 18.5 0.87 75 14 NS NS NS NS NS NS MW-M 5.53 301 14.4 6.58 194 26 NS NS NS NS NS NS 6.09 221 15.4 1.47 91 59 NS NS NS NS NS NS MW-X 5.93 338 15.3 1 4.29 174 51 6.01 260 16.6 6.51 33 20 5.13 241 14.9 0.91 69 4 6.37 253 14.3 0.00 145 1 Surface Water Sam 1302-MSWLF- SW-1 6.14 685 10.5 6.58 78 18 6.14 424 16.8 6.01 170 2 DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY DRY CDLF-1998 SW-2 5.05 667.00 9.67 6.06 121 196 DRY DRY DRY DRY DRY DRY 6.36 455 22.3 2.49 114 13 DRY DRY DRY DRY DRY DRY Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 13. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. Smith Page 1 of 5 June 2019 Table 4 May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 36 No. 37 No. 38 No. 39 0 CD -Is (background well) 6.7 02 104 15.1 1.96 206 5 6.06 100 ,13.0 1.74 348 42 6.15 119 ,15.9 0.02 353 9 6.10 129 ,15.1 6.06 135 2 CD -Id (background well) 6.06 117 16.9 1.11 242 27 6.03 119 14.5 1.71 320 32 6.21 134 19.2 4.56 293 9 6.18 139 16.5 4.68 109 14 CD-4 Rep 5.54 256 13.7 0.62 29 30 6.14 177 16.9 1.20 -45 26 6.10 259 13.3 2.19 -7 3 6.15 126 15.9 2.69 58 7 CD-6 5.75 223 16.9 0.60 166 11 6.15 994 17.1 1.24 -17 60 5.84 217 17.7 2.86 137 4 5.77 253 16.4 3.35 45 67 AMW-is 5.56 256 16.4 0.34 523 1 5.72 249 17.9 1.05 149 9 5.83 251 16.8 0.02 400 10 5.72 251 17.5 3.25 132 8 AMW-1d 6.20 755 17.9 0.46 -53 2 6.08 727 19.6 1.40 -23 9 6.04 650 20.1 2.05 -28 604 6.13 643 18.0 1.36 -68 29 AMW-2s 5.60 157 16.7 0.88 153 9 5.69 159 17.7 1.51 75 9 5.76 178 18.8 2.08 114 6 5.77 182 15.2 3.48 121 6 AMW-2d 5.83 192 17.1 0.36 126 0 6.26 203 18.5 1.40 138 1 6.30 231 16.9 3.88 95 1 6.26 252 16.0 4.19 104 1 MW-1 6.19 1,817 15.0 0.77 43 1 6.30 1,381 15.7 1.99 144 22 6.36 1,361 15.0 2.84 37 3 6.34 1,511 15.4 2.59 -37 0 MW-3 5.76 149 16.0 1.88 188 40 5.87 160 17.0 1.99 301 40 6.05 180 18.5 0.04 150 8 5.97 202 16.3 5.94 466 4 MW-3 deep 7.76 348 16.4 0.39 -153 2 NS NS NS NS NS NS 7.75 385 16.5 4.04 -65 4 NS NS NS NS NS NS MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 5.42 309 16.5 0.25 -34 0 5.40 333 15.3 1.89 291 1 5.42 432 16.9 0.04 -17 1 5.47 451 16.4 1.70 45 2 1302-MSWLF- MW-13 6.44 1,037 13.1 1.09 -88 1 6.33 817 16.4 1.35 -67 15 6.66 1,033 12.6 2.58 -67 10 6.62 922 16.6 3.00 -101 1 CDLF-1998 MW-C 5.35 100 13.2 1.06 104 43 5.90 206 16.7 1.31 233 72 5.64 108 12.3 2.23 44 4 6.02 428 16.0 2.58 47 3 MW-D 5.48 462 16.7 0.26 60 9 5.66 490 16.1 1.04 295 51 5.85 705 17.2 1.85 -17 2 5.71 471 15.7 3.39 35 4 MW-E Rep 6.17 991 16.8 0.47 -81 0 6.11 959 16.5 1.64 -40 3 5.99 831 19.0 0.07 -24 2 6.25 1,180 17.6 1.62 -54 3 MW-E deep 6.51 803 18.1 0.51 -80 3 6.35 836 17.1 1.21 -82 3 5.60 1,042 20.2 0.09 -41 800 6.34 1,198 18.0 1.09 -82 13 MW-F 6.30 745 13.7 0.64 -89 3 6.52 877 15.8 1.47 -100 10 6.57 726 13.8 2.74 -81 5 6.46 919 15.4 2.18 -104 6 MW-G 6.10 930 14.0 0.49 -98 0 6.15 1,430 16.7 1.60 -83 23 6.27 1,542 13.7 2.29 -106 8 6.30 1,794 16.3 1.97 -124 14 MW-H 5.79 149 15.7 1.77 60 9 6.04 160 15.2 2.04 335 96 5.92 161 14.5 2.39 230 19 5.92 199 14.2 3.70 466 11 MW-H deep 6.13 255 16.0 1.23 130 2 6.14 259 15.1 2.75 332 15 6.25 269 15.4 2.10 260 4 6.24 317 14.3 3.81 427 4 MW-1 5.74 112 15.3 0.21 159 1 5.97 116 15.1 1.61 311 1 5.95 118 15.3 2.59 84 3 6.11 133 14.4 4.12 199 3 MW-J 6.40 236 15.5 1.45 223 14 6.42 242 14.7 1.64 346 37 6.39 259 15.8 2.05 36 5 6.53 245 14.2 3.75 155 14 MW-K 5.72 207 15.2 0.66 175 1 5.79 199 15.2 1.40 266 33 5.81 202 16.0 2.88 96 6 5.83 229 14.6 2.65 187 10 MW-L 5.30 96 15.1 1.09 188 8 5.54 106 14.6 1.39 258 68 5.80 99 16.6 2.12 379 4 5.78 122 16.4 4.03 59 3 MW-Ldeep 6.02 208 17.1 1.49 133 2 NS NS NS NS NS NS 6.88 201 17.5 2.70 380 3 NS NS NS NS NS NS MW-M 6.34 297 15.3 1.51 54 1 NS NS NS NS NS NS 6.31 271 15.3 2.45 211 4 NS NS NS NS NS NS MW-X 6.15 222 14.6 120 117 2 6.25 236 1 15.4 1 1.45 1 348 36 6.28 216 1 15.2 12.07 106 1 21 16.31 228 1 14.5 4.53 131 2 Surface Water Sam 6.16 560 11.0 2.12 341 11 7.24 502 24.6 1 0.07 -26 22 DRY DRY DRY DRY DRY DRY 1302-MSWLF- SW-1 7.02 466 16.0 4!0 -17 15 CDLF-1998 SW-2 7.10 333 15.5 4.46 -7 6 DRY DRY DRY 1 DRY I DRY DRY 7.50 604 25.4 4.48 3 8 6.50 325 10.4 -69.80 2 43 Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. Smith Page 2 of 5 June 2019 Table 4 May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: Sampling Date: No. 40 5/4-7/15 No. 41 No. 42 CD-1s (back7Rep6.29 115 ,15.5 3.99 281 7 5.73 132 '15.0 3.84 519 3 5.91 103 ,15.7 3.45 245 4 7CD-ld (back 123 16.4 4.84 186 13 5.81 136 14.5 6.96 507 7 6.06 115 15.8 4.50 210 20 CD-4 495 13.5 2.75 70.4 4 6.06 231 16.4 3.19 31.2 3 6.90 242 14.2 2.68 -54 28 C 372 17.4 2.04 142 5 5.90 244 16.3 3.92 111 >800 6.20 271 16.9 1.50 -48 23 AM 243 14.9 2.00 592 6 5.80 443 16.0 2.68 253 3 6.07 224 16.5 3.77 222 8 AMW-1d 5.94 518 15.9 1.78 -52 16 6.11 1,004 15.8 2.55 -42 5 6.13 477 18.1 1.51 -28 4 AMW-2s 5.07 160 14.2 3.50 562 6 5.92 173 16.2 4.19 187 3 5.78 154 15.8 3.22 51 7 AMW-2d 5.77 230 15.2 2.51 391 1 6.36 260 17.2 3.90 158 2 6.04 229 15.9 2.69 88 1 MW-1 6.29 2,379 14.9 2.69 -19 6 6.31 1,743 15.5 1.94 21 7 8.05 1,515 15.4 3.48 94 4 MW-3 5.42 166 17.6 2.29 260 14 6.20 178 19.5 3.85 166 3 6.04 167 16.5 3.18 101 1 MW-3 deep 7.49 368 20.5 1.50 -198 4 7.63 387 19.5 1.67 -165 3 7.48 362 15.6 2.26 -130 0 MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 4.78 390 15.6 2.34 27 2 5.30 402 15.5 1.41 29 3 5.48 394 16.1 1.27 -55 1 1302-MSWLF- MW-B 6.70 1,485 13.0 3.03 -68 9 6.00 833 16.9 3.91 -51 6 8.32 976 14.0 3.73 53 17 CDLF-1998 MW-C 5.94 162 12.9 3.89 -181 8 5.21 186 16.7 1.73 153 37 6.50 126 14.0 3.48 -78 6 MW-D 5.86 745 16.8 3.66 15 3 5.19 520 16.5 2.60 85 14 7.26 617 16.3 1.23 -84 4 MW-E Rep 6.04 1,095 17.3 3.61 -38 9 6.10 1,076 16.2 1.25 -36 3 6.27 1,088 17.1 1.40 -59 1 MW-E deep 6.41 1,027 18.4 0.88 -100 15 6.44 979 16.2 1.21 -71 5 6.63 1,017 17.5 3.08 -95 9 MW-F 6.51 1,270 13.9 3.58 -58 3 6.61 1,134 15.5 2.71 -136 3 8.12 796 14.4 2.65 -47 6 MW-G 6.31 2,445 13.9 2.66 -78 6 6.32 1,372 16.8 2.28 -135 0 7.96 1,671 15.0 2.40 49 12 MW-H 5.51 174 15.0 2.71 136-5 10 5.15 203 15.3 0.81 168 43 6.06 162 14.2 5.40 204 38 MW-H deep 6.12 285 15.4 1.62 137 4 5.72 280 15.3 0.64 146 4 6.82 272 14.9 4.99 145 18 MW-1 5.64 134 15.3 2.82 132 3 5.13 128 15.2 0.76 104 3 6.86 127 15.0 4.40 164 7 MW-J 6.54 402 14.9 3.13 137 7 6.48 274 14.3 0.38 210 7 6.92 265 14.8 4.20 28 58 MW-K 5.56 239 14.9 1.50 95 5 4.93 253 15.2 3.43 167 6 7.03 208 15.0 4.34 21 14 MW-L 5.29 97 17.5 4.15 131 3 5.92 93 18.5 3.80 89 4 5.80 95 14.2 3.66 192 2 MW-L deep 6.61 341 17.5 4.79 190 3 5.49 395 15.8 0.80 155 2 6.82 209 15.0 3.88 149 2 MW-M 6.31 334 15.4 1.49 116 4 5.67 334 15.7 0.49 151 10 7.97 320 15.3 4.02 -3 8 MW-X 6,19 341 13.5 3.23 140 1 4 5.03 234 15.3 2.53 342 3 7.19 210 13.9 3.98 20 6 Surface Water Samp DRY DRY DRY 6.83 840 16.0 1.04 -54 0 6.99 15.4 4.99 360.3 >800 1302-MSWLF- SW-1 DRY DRY DRY 342 CDLF-1998 SW-2 6.89 520 24.7 2.19 4 7 I 5.55 788 15.4 1.34 158 7 6.80 241 15.6 3.51 181 590 Notes: 1. NS - Not Sampled 2. µs/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential S. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. -Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. Smith Page 3 of 5 June 2019 Table 4 May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 43 No. 44 No. 45 7C.D-'I-sbackground well) 5.05 113 16.1 4.49 360 6 5.32 117 15.7 1.69 274.6 8 5.35 121 16.1 1.87 57.7 8.09 background well) 5.34 124 15.9 3.10 330 8 5.46 129 14.3 1.51 257.2 4 5.64 132 17.3 2.85 36.9 2.89 CD-4 Rep 5.28 209 17.0 1.35 79 3 5.65 211 14.3 5.00 29.0 9 5.94 156 15.9 1.31 218.4 5.19 CD-6 5.62 292 16.9 1.38 -4 29 -- -- -- -- -- -- -- -- -- -- -- -- AMW-1s 5.02 297 18.8 1.65 377 6 5.46 258 15.7 1.54 148.6 0 5.17 198 16.7 2.39 226.6 0.87 AMW-1d 5.00 583 13.3 1.73 199 8 5.92 496 17.9 1.59 -6.7 4 5.94 454 23.2 3.51 158.9 4.24 AMW-2s 4.92 164 16.4 3.38 235 8 5.79 172 18.9 1.55 48.2 4 4.40 159 17.2 4.42 280.1 4.39 AMW-2d 5.52 356 16.5 2.15 346 4 5.98 264 18.5 1.47 37.0 0 5.17 258 15.5 3.20 151.0 3.79 MW-1 6.13 1,812 16.2 1.03 34 8 5.49 1,545 15.7 3.44 53.2 7 6.28 1,533 15.0 2.44 210.9 10.0 MW-3 5.52 246 20.6 3.50 439 5 5.61 179 17.9 1.75 229.6 1 5.86 172 17.3 1.60 325.4 1.36 MW-3 deep NS NS NS NS NS NS 6.60 381 17.2 4.03 95.7 4 7.68 360 17.3 2.29 67 0.20 MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 4.77 412 16.5 1.65 205 4 5.23 412 15.6 1.31 140.9 3 5.06 423 16.8 3.21 70.1 4.42 1302-MSWLF- MW-B 6.44 1,085 17.5 2.11 -79 9 5.53 991 14.2 4.71 -18.3 22 6.53 904 16.1 1.94 -74.6 57.0 CDLF-1998 MW-C 5.52 243 17.4 2.58 49 7 5.40 103 14.0 4.92 34.6 8 5.55 145 15.7 3.71 320.5 9.17 MW-D 5.43 627 16.5 1.51 69 6 5.98 824 16.9 5.10 10.0 9 5.73 530 15.0 2.33 201.5 21.0 MW-E Rep 5.59 1,139 17.6 3.79 48 5 6.31 1,117 18.1 1.35 -50.7 8 6.33 1,116 18.0 2.48 65.1 4.25 MW-E deep 5.89 959 18.1 2.30 -39 8 6.34 929 18.1 1.65 -78.5 9 5.59 890 17.5 2.45 151.8 8.61 MW-F 6.25 1,141 16.6 1.23 -71 6 5.23 911 14.6 3.59 -16.3 5 6.38 934 15.0 2.03 -82.3 20.0 MW-G 6.07 2,320 17.6 1.09 -80 1 5.32 1,733 15.5 3.78 -60.0 13 6.17 1,760 16.2 3.20 -85.7 48.0 MW-H 5.53 211 15.3 1.63 118 59 4.50 174 14.9 4.17 124.6 43 5.80 162 13.9 1.57 272.2 15.0 MW-H deep 5.91 337 15.0 2.21 105 16 5.47 276 15.8 4.80 66.7 7 6.12 264 13.7 1.52 332.9 3.17 MW-1 5.65 164 15.0 1.35 68 9 4.56 136 15.7 5.05 119.1 7 5.79 126 13.7 1.15 251.2 7.00 MW-J 6.05 311 14.8 2.65 21 36 6.47 254 14.8 4.87 111.6 18 6.41 256 13.6 2.66 428.9 28.0 MW-K 5.47 283 15.4 1.89 149 21 4.53 215 15.4 5.03 123.1 8 5.72 218 14.2 1.30 327.3 11.0 MW-L 5.11 146 18.1 3.49 486 5 4.97 100 17.8 1.70 128.9 3 5.65 104 15.8 1.61 360.8 2.07 MW-Ldeep NS NS NS NS NS NS 6.17 223 16.5 1.58 72.4 0 6.54 211 15.7 2.63 211 0.61 MW-M NS NS NS NS NS NS 6.24 304 16.0 5.29 55.4 4 6.30 305 14.7 2.46 326 14.0 MW-X 5.94 275 15.3 1.62 78 2 6.39 202 508 14.3 21.1 5.19 82.2 6 .18 207 DRY 14.1 1.45 466.4 5.58 1302-MSWLF- SW-1 DRY DRY DRY DRY DRY DRY 6.73 5.13 11.0 4 RY rD DRY DRY DRY DRY CDLF-1998 SW-2 DRY DRY DRY DRY DRY DRY 5.86 528 20.1 5.23 36.7 7 RY DRY DRY DRY DRY DRY Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced M W-9 as the background monitoring wells. 11. MW-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Smith Page 4 of 5 June 2019 Table 4 May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Sampling Event: No. 46 No.47 No. 48 CD-15 (background well) 6.2 110 31.5 3.8 124.1 5 6.3 110 16.7 5.6 38.6 9 5.26 116 •15.0 1.82 242.4 7 CD-ld lbackground we 6.2 117 18.3 2.9 54.2 11 6.1 116 15.8 3.6 25.1 10 5.67 114 18.3 1.61 183.2 9 CD-4 Rep 6.0 156 16.3 4.5 50.7 153 6.0 139 12.5 5.3 48.9 101 5.98 191 14.7 2.46 45.4 10 CD-6 -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- -- AMW-1s 5.8 218 18.0 0.5 566.1 2 5.9 219 14.5 0.7 510.5 0 5.23 205 15.5 1.80 90.3 2 AMW-1d 6.0 429 20.4 3.2 21.3 109 6.0 412 14.6 0.5 1.8 10 5.56 372 17.9 1.71 91.1 9 AMW-2s 5.8 154 22.4 2.2 162.6 4 5.8 144 13.7 2.9 101.3 2 5.24 154 16.2 1.74 201.1 7 AMW-2d 5.9 244 22.9 0.6 13.9 2 6.0 274 13.2 0.9 65.3 0 6.08 256 20.2 2.55 165.2 9 MW-1 6.4 1,385 15.2 3.4 75.4 47 6.4 1,355 12.4 2.0 224.6 7 6.51 140 15.9 1.52 22.4 5 MW-3 6.0 166 22.3 3.7 130.6 2 6.0 178 15.3 2.8 48.8 8 5.47 170 15.2 1.81 114.5 6 MW-3 deep 7.6 341 24.1 0.4 109.8 2 NS NS NS NS NS NS 6.98 343 16.0 1.76 17.9 8 MW-9 NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS NS MW-A 5.6 373 21.2 0.4 63.5 1 5.7 372 9.3 0.6 32.4 1 5.27 449 13.7 1.91 76.7 2 1302-MSWLF- MW-B 6.6 701 18.5 3.4 -18.7 31 6.7 795 9.3 1.3 -64.8 18 6.67 784 16.0 1.05 -64.5 5 CDLF-1998 MW-C 5.7 109 15.0 5.4 64.2 225 5.8 102 12.3 4.8 162.6 11 5.74 98 15.0 1.37 104.3 3 MW-D 5.9 490 17.2 2.9 62.9 23 6.2 858 15.1 1.1 35.4 1 5.92 620 13.8 1.93 36.4 3 MW-E Rep 6.4 999 23.7 1.3 -26.2 11 6.2 1,012 13.4 0.3 -16.1 4 6.05 984 17.3 1.68 -1.9 2 MW-E deep 6.5 857 29.0 0.4 -83.5 5 6.3 1,031 11.6 0.4 -56.2 4 6.29 1,123 16.4 1.88 -30.9 9 MW-F 6.5 526 14.9 3.4 -69.3 20 6.1 481 11.6 2.5 11.0 4 6.57 478 14.3 1.55 -69.4 5 VW-G 6.3 1,035 15.9 2.60 -38.7 49 6.1 586 11.3 2.10 -2.8 15 6.39 1,576 15.0 2.28 -82.9 S MW-H 6.2 159 14.8 5.3 46.8 49 6.5 242 14.7 9.9 -2.6 10 6.23 161 15.0 4.74 118.5 5 MW-H deep 6.5 267 15.2 3.0 47.0 28 6.2 165 14.1 5.8 -8.3 173 6.47 261 16.2 2.75 95.2 6 NW-1 6.3 155 15.5 3.9 26.1 29 6.1 143 14.8 4.5 -2.9 11 6.15 130 15.8 5.96 115.9 6 MW-J 6.2 243 15.9 3.0 104.2 97 6.6 241 14.1 3.3 143.7 67 5.68 245 16.1 2.45 154.5 9 MW-K 6.0 192 15.8 4.6 61.8 27 6.0 173 15.1 3.9 129.8 5 6.06 181 15.9 2.45 140.0 4 MW-L 5.9 95 18.8 1.2 141.2 4 5.8 86 12.5 2.7 100.4 3 5.12 91 14.4 1.87 142.9 7 MW-Ldeep 6.7 207 24.0 0.3 146.7 3 NS NS NS NS NS NS 6.10 203 13.7 1.90 160.7 5 MW-M 6.6 286 16.1 3.1 91.5 18 NS NS NS NS NS NS 6.53 287 15.7 2.84 324.7 2 MW-X 6.4 195 15.0 1 4.0 102.1 20 6.3 185 13.6 3.2 167.5 1 6.28 181 14.7 1.33 137.0 4 Surface Water Sample Loc 1302-MSWLF- SW-1 DRY 7.6 336 6.2 10.1 -73.4 18 7.17 357 18.9 4.06 120.1 11 CDLF-1998 SW-2 7.5 306 21.1 1 4.1 70.2 50 7.2 267 6.4 9.8 21.1 19 6.74 473 1 19.8 5.07 174.1 9 Notes: 1. NS - Not Sampled 2. ps/cm- Microsiemens per centimeter 3. mg/L- milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. Turb. -Turbidity; NTUs - Nephelometric Turbidity Units 6. mVs - millivolts 7. DO - Dissolved Oxygen 8. S.U. - Standard Units 9. Temp. -Temperature; Deg. C - Degrees Celsius 10. The November 2012 sampling event was the first event that CD-is/CD-1d replaced MW-9 as the background monitoring wells. 11. M W-9 was removed from the monitoring program in November 2012. 12. MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 13. (--) CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Smith Page 5 of 5 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, ,,, CD-ls 3-May-11 81.4J 0.191 5.45JB 4.231 16.0 2.32J 5.93J 0.14J 20.61 26.5 CD -Is 8-Nov-11 59.71 0.25JB 4.46J 2.67J 12.4 1.91 4.41J 0.08J 11.21 18.2 CD-ls 7-May-12 45.5J 3.30J 1.191 8.75J 1.12J 3.01J 12.71 12.68 CD-Is 28-Nov-12 63.8J 0.111 5.65J 3.051 11.6 1.43J 4.66J 17.11 16.9 CD-1s 7-May-13 0.94J 2.418 35.6J 0.881 0.67J 4.04J 0.39J 1.781 0.13J 6.061 5.08J CD-Is 5-Nov-13 46.8J 0.12J 3.59J 1.63J 10.2 1.35J 3.SOJ 18.418 15.46 CD-ls 6-May-14 28.81 4.14JB 1.48J 0.111 1.03J 0.311 3.40J 2.981E CD-Is 4-Nov-14 28.7J 0.13J 1.311 0.06J 1.04J 0.11J 2.5718 1.58J 1302-MSWLF- CD-ls 5-May-15 1.631 29.5JB 1.33J 371 0.15J 13.8 0.103JB 1.17J 2.40J 2.7518 CDLF-1998 CD -Is 27-Oct-15 28.4J 0.80J 0.39J 0.75J 234 0.12J 35.9 1.21J 4.19CN,J 0.15J 4.101 3.36E-01,1 CD-ls 17-May-16 29.3J 0.94J 0.991 446 0.12J 17.OJ 1.OlJ 4.701 1.93J CD-Is 1-Nov-16 30.5J 1.23J 1.36J 647 0.28J 1.35J 4.301 CD-1s 9-May-17 34.31 1.17J 1.26J 522 0.201 24.4J 0.97J 6.691 1.82J CD-ls 31-Ott-17 0.52J 36.3J 1.81J 0.54J 2.87J 1,270 0.37J 31.2J 1.41J 6.911 4.001 CD-ls 11-Jun-18 29.51 1981 6.7J 0.051J 5.7J 4.01 CD-ls 17-Dec-18 26.7J 5 . 0.60J 3.6J 498 16.6 15.01 7.OJ 9.51 CD-ls 7-May-19 29.8 638 17.6 1.3J 7.OJ 5.1J CD Id 3-May-11 2.441 231 2.03 16.7 18.6 112 14.0 22.3J 0.111 101 103 CD-ld 8-Nov-11 74.51 0.51J 4.08J 4.271 27 2.84J 5.68J 24.61 26.3 CD -Id 7-May-12 72.4J 0.581 3.91J 4.671 25 2.81J S.S81 26 27.9E CD-1d 28-Nov-12 0.331 37.71 0.07J 2.381 0.94J 12.6 1.14J 2.50J 8.901 13 CD -Id 8-May-13 0.881 1.0216 31.2J 0.07J 0.78J 4.5J 0.49J 1.92J 6.181 13.1 CD-ld 5-Nov-13 35J 0.86J 4.34J 1.13J 1.901 17.11E 10.88 CD -Id 6-May-14 1.14J 37.8J 0.07J 0.05J 3.22JB 1.16J 7.34J 0.81J 2.74J 0.12J 6.161 9.41JB CD-1d 4-Nov-14 43.11 0.161 0.111 2.251 9.09J 0.87J 2.881 10.21E 10.7 1302-MSWLF- CD Id 5-May-15 34.5JB 0.84J 3.63J 1,320 0.39J 32.5 1.42J 5.181 3.68JB CDLF-1998 CD-ld 27-Oct-15 0.421 42.31 0.13J 1.87J 2.151 8.18J 3,170 0.97J 87.4 2.49J 4.37CN,J 0.06J 10.91 14.08-01 CD -Id 17-May-16 81.3J 0.46J 4.86J 7.42J 26.0 12,000 3.13J 281M 7.11J 2.11J 0.07J 29.3 29.7 CD-1d 1-Nov-16 32.61 1.191 0.77J 2.82J 1,200 0.331 31.3J 1.24J 7.961 4.291 CD -Id 9-May-17 33.9J 1.27J 0.52J 1.81J 720 6.92J 25.81 1.091 6.951 3.12J CD-1d 31-Oct-17 29.51 0.68J 0.611 226J 0.111 11.81 0.64J 5.83J 1.24 1 CD-ld 12-Jun-18 32.41 2.5J 432 13.2J 1.0J 6.9J 3.21 CD-ld 17-Dec-18 31.91 9.3J 2.31 591 0.411 18.1 3.OJ 6.81 4.11 CD-ld 7-May-19 30.7 1.41 517 9.7J 2.91 CD-4 Rep 3-May-11 206 0.916 17.6 0.621 8.39J 2.72JB CD-4 Rep (dup) 3-May-11 0.211 206 17.9 0.68J 8.981 0.17J 2.85J CD-4 Rep 8-Nov-11 0.141 191 0.93J 18.2 1.001 8.861 9.441 CD-4 Rep 9-May-12 184 1.69J 18.1 1.70J 0.17J 11.3J 3.03J 16.1E CD-4 Rep 29-Nov-12 172 13.7 0.621 7.03J 2.84J 2.14113 CD-4 Rep 30-May-13 75.5J 0.5J 2.71J 7.871 1.94J 0.88J 11.2J 11.11 10.3 CD-4 Rep 7-Nov-13 1.361 60.41 0.351 0.07J 0.77J 5.311 1.831 0.571 5.11J 0.13J 32 4.40113 CD-4 Rep 7-May-14 62.41 0.31J 0.05J 3.25JB 5.02J 1.70J 0.32J 6.52J 22.2J 2.971E 1302-MSWLF- CD-4 Rep 5-Nov-14 70.01 0.311 2.591 1.461 0.72J 4.29J 14.8JB 6.851 CDLF-1998 CD-4 Rep 6-May-15 58.41 0.39J 1.13J 5.941 1.90J 0.53J 4.72J 14.OJ 2.991 CD-4 Rep 28-Oct-15 0.791 57.91 0.32J 2.181 5.861 8.951 1.261 10.7J 4.14CN,J 13.9J 8.348-01,1 CD-4 Rep 18-May-16 1.091 56.2J 0.46J 1.24J 7.31J 1.02J 0.66J 5.43J 18.01 3.701 CD-4 Rep 2-Nov-16 46.31 0.27J 1.35J 1.591 1.18J 0.901 4.18J 1.11J 18.11 8.811 CD-4 Rep 9-May-17 53.8J 0.46J 0.951 5.911 1.72J 0.52J 4.381 10.51 3.731 CD-4 Rep 31-Oct-17 45.01 0.18J 0.97J 0.82J 0.581 0.451 2.75J 1.88J 7.68J 2.761 CD-4 Rep 6-Jun-18 52.9J 0.41J 3.41 0.74J 3.3J 13.3J 4.OJ CD-4 Rep 19-Dec-18 1.11 50.9J 0.96J 4.6J 5.51 2.6J 2.9J 7.OJ 1.4J 15.51 11.6 CD-4 Rep 8-May-19 45.9 0.38J 2.3J 7.0 1.4J 1.1 5.8 6.2J 13.7 CD-6 4-May-11 66.6J 0.42J 6.74J 4.081 4.6J 2.01J 5.34J 0.11 24.71 14 CD-6 9-Nov-11 59.6J 0.26J 4.71J 2.621 7.89J 1.31J 5.22J 15.81 9.62J CD-6 9-May-12 57.8J 0.20J 4.20J 2.081 3.63J 1.21J 4.48J 17.21 17.78 CD-6 29-Nov-12 50.81 0.13J 2.25J 1.801 1.86J 0.73J 3.73J 12.3J 6.63JB CD-6 10-May-13 61.4J 0.36J 5.891 3.021 4.12J 1.43J 4.77J 20.41 13.8 1302-MSWLF- CD-6 7-Nov-13 0.57J 3.771 298 0.14J 18.3 36.9 2.13J 11.7J 1.07J 14.6J 6.88JB CDLF-1998 CD-6 7-May-14 38.5J 0.101 3.42113 1.04J 0.07J 2.30J 4.391 2.40113 CD-6 5-Nov-14 120 0.88J 7.64J 8.021 8.02J 3.83J 9.04J 0.14J 50.613 25.7 CD-6 6-May-15 47.4J 0.20J 1.601 1.841 2.77J 0.81J 3.29J 10.51 5.401 CD-6 28-Oct-15 4.971 215 2.03 32.3 19.5 25.6 16.1 21.6J 8.64J 4.05CN,J 0.37J 107 73.913-01 CD-6 18-May-16 1.921 62.21 0.23JJ 3.461 13.2 2.57J 1.581 8.70J 1.OL 12.61 7.941 CD-6 2-Nov-16 1.89J 63.7J 0.331 6.181 13.3 3.121 2.87J 9.12J 1.29J 17.31 10.1 Smith Page 1 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, „ ,,, AMW-ls 3-May-11 104 0.921 1.4JB 0.31J 2.08J 0.51 3.59J 0.081 8.116 AMW-ls 8-Nov-11 105 0.901 1.43J 0.46J 1.94J 0.44J 3.671 0.101 8.471 AMW-1s 7-May-12 103 0.861 2.39J 1.87J 0.22J 3.87J 2.981 8.4918 AMW-ls 28-Nov-12 0.191 97.4J 0.83J 0.78J 0.78J 0.111 3.31J 2.411 4.791 AMW-ls 8-May-13 101 0.87J 1.981 0.091 4.05J 2.241 6.13J AMW-ls 6-Nov-13 981 0.911 0.22J 2.91J 0.32J 4.061 16.71E 6.70JB AMW-ls 7-May-14 93.0J 0.95J 2.44JB 0.28J 2.27J 0.47J 3.91J 1.39J 6.3518 AMW-ls 5-Nov-14 89.2J 1.06 0.50J 3.37J 0.78J 4.151 4.0118 7.601 1302-MSWLF- CDLF-1998 AMW-ls 7-May-15 87.6J 0.97J 3.78J 0.31J 2.72J 0.681 5.861 3.311 6.51J AMW-ls 29-Oct-15 82.5J 0.78J 1.03J 0.71J 0.191 4.031 3.18CN,1 4.221 9.82E-01,J AMW-ls 18-May-16 0.27J 0.82J 85.4J 1.03 1.43J 0.38J 2.47J 0.921 4.16J 5.181 7.43J AMW-ls 2-Nov-16 71.7J 0.56J 0.551 3.191 5.781 AMW-ls 10-May-17 92.41 0.73J 0.61J 0.36J 3.91J 2.601 5.45J AMW-ls 1-Nov-17 68.21 0.66J 0.891 0.54J 0.14J 2.71J 3.34J 6.371 AMW-ls 8-Jun-18 91.91 0.77J 5.21 3.9J 4.41 17.7 AMW-ls 19-Dec-18 86.41 0.89J 3.91 3.11 5.91 AMW-ls 8-May-19 80.9 0.70 3.6J 2.41 6.5J AMW-1d 3-May-11 0.241 129 0.12J 4.671 2.08J 0.25J 9.161 0.191 9.17JB AMW-ld 8-Nov-11 0.181 140 0.07J 0.94J 5.781 1.64J 0.211 10.2J 0.251 7J AMW-Id 7-May-12 0.291 135 5.20J 2.17J 0.27J 9.171 2.691 8.981B AMW-1d 28-Nov-12 0.41J 106 0.14J 1.38JB 3.271 2.26J 0.521 6.21J 5.50J AMW-Id 8-May-13 1.0516 133 4.53.1 1.63J 0.25J 7.81J 3.081 AMW-1d 6-Nov-13 133 1.881 4.311 1.77J 0.451 7.45J 20.518 4.3016 AMW-Id 7-May-14 143 0.50J 0.051 5.48.1 4.90J 3.01J 9.841 5.891 27.9E AMW-1d 5-Nov-14 1.461 168 0.691 0.051 4.49J 6.701 6.531 4.141 11.81 13.81E 20.8 1302-MSWLF- AMW-Id 7-May-15 133 0.401 4.081 5.51J 3.58J 2.14J 9.831 5.471 10.3 CDLF-1998 AMW-ld 29-Oct-15 1.411 123 0.181 3.02J 5.321 1.061 0.931 8.61J 3.57CN,J 4.001 6.798-01,1 AMW-1d 18-May-16 1.011 131 0.191 2.091 6.06J 1.52J 0.84J 9.031 2.521 6.841 AMW-1d 3-Nov-16 128 0.17J 2.20J 6.091 1.12J 0.811 9.30J 6.65J AMW-Id 10-May-17 0.62B-01,J 131 0.12J 1.301 5.50J 0.66J 0.49J 8.071 1.391 5.111 AMW-1d 1-Nov-17 0.851 128 0.14J 0.93J 6.071 1.391 0.451 9.60J 5.491 AMW-1d 8-Jun-18 1.21 153 0.261 2.9J 7.3J 2.0J 1.41 12.4J 4.21 14.2 AMW-1d 19-Dec-18 0.711 127 0.161 6.61 0.311 10.11 2.21 5.0J AMW-Id 8-May-19 167 0.14J 6.3 9.8 6.11 AMW-2s 3-May-11 52.11 0.92J 2.49JB 1.10J 1.411 2.21 2.54J 7.171 6.471B AMW-2s 8-Nov-11 42.3J 0.50J 1.36J 0.291 0.82J 2.19J 1.36J 5.081 AMW-2s 8-May-12 42.81 0.45J 1.48J 0.23J 2.851 0.661 1.47J 3.771 5.921B AMW-2s 29-Nov-12 45.3J 0.481 1.02J 0.23J 0.62J 0.32J 1.191 1.41J AMW-2s 9-May-13 42.61 0.57J 1.11J 0.521 1.061 0.631 1.95J 3.091 3.631 AMW-2s 6-Nov-13 40.1J 0.54J 0.27J 0.64J 0.42J 1.481 16.81B 3.51J6 AMW-2s 7-May-14 43.71 0.56J 2.161E 0.301 0.871 0.351 1.41J 1.961B AMW-2s 5-Nov-14 46.0J 0.69J 0.44J 1.01J 0.591 1.881 2.84J 1302-MSWLF- AMW-2s 6-May-15 2.721 43.41 0.51J 1.071 0.391 1.46J 2.071 2.371 CDLF-1998 AMW-25 28-Oct-15 1.021 50.61 0.88J 1.56J 0.75J 0.50J 1.23J 1.96J 6.12CN,J 6.23J 6.14E-01,J AMW-2s(dup) 28-Oct-15 1.001 51.11 0.85J 1.79J 0.871 0.571 1.341 2.10J 3.34CN,J 7.011 7.018-01,1 AMW-2s 17-May-16 45.8J 0.69J 1.151 0.65J 0.48J 0.71J 1.63J 0.30J 4.51J 3.931 AMW-2s 1-Nov-16 46.51 0.73J 1.60J 0.581 0.571 0.741 1.811 5.171 AMW-2s 30-May-17 0.62B-01,1 42.7J 0.47J 0.951 0.17J 1.02J 3.58J 1.621 AMW-2s 1-Nov-17 43.61 0.54J 0.881 0.531 0.261 1.17J 3.64J 3.211 AMW-2s 8-Jun-18 45.9J 0.47J 1.4J 3.7J 3.0J AMW-2s 20-Dec-18 39.0J 0.39J 9.81 3.7J 5.8J AMW-2s 7-May-19 "A 0.55 1.6J 1.4J 4.31 3.4J AMW-2d 3-May-11 55.2J 2.86113 0.83J 1.03J AMW-2d 8-Nov-11 47.5J 1.081 0.12J 0.77J 1.23J AMW-2d 8-May-12 78.2J 1.26J 3.20J 0.33J 1.22J 2.791 10.58 AMW-2d 28-Nov-12 69.1J 0.88J 2.34J 0.39J 2.56J 4.76J AMW-2d 9-May-13 54.7J 1.75J 0.06J 1.42J 4.031 2.41 AMW-2d 6-Nov-13 71.1J 2.43J 2.69J 18.5JB 7.86JB AMW-2d 7-May-14 57.0J 0.101 2.08113 0.84J 1.24J 0.76113 AMW-2d 5-Nov-14 60.4J 0.07J 1.25J 2.33J 1.09JB 5.04J 1302-MSWLF- AMW-2d 6-May-15 1.281 67.4J 0.85J 1.67J CDLF-1998 AMW-2d 28-Oct-15 0.25J 63.9J 0.45J 0.14J 1.501 2.79CN,J 2.65J 7.41B-01,J AMW-2d 17-May-16 64.5J 0.13J 1.37J 1.07J 1.381 AMW-2d 2-Nov-16 67.7J 0.101 0.66J 1.901 5.02J AMW-2d 10-May-17 0.65B-01,1 70.11 0.14J 3.63J 0.24J 1.32J 4.531 AMW-2d 2-Nov-17 74.2J 0.16J 1.48J 2.00J AMW-2d 8-Jun-18 75.7J 0.17J 2.1J 3.8) 3.1J AMW-2d 20-Dec-18 75.3J 0.20J 0.58J 4.1J AMW-2d I 7-May-19 1 1 1 74.6 1 0.181 I I I I 2.71 I I I I I 2.71 I I I I 3.31 1 11.6 Smith Page 2 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, „ ,,, MW-1 4-May-11 0.46J 5.081 360 0.91 0.091 9.05J 19.7 11.8 4.59J 20.81 2.39J 0.09J 35.7 40.4 MW-1 9-Nov-11 2.22J 187 0.52J 1% 6.67J 0.64J 37.71 3.351 3.71J MW-1 9-May-12 201 0.161 0.061 2.26J 17.8 17.0 3.611 42.4J 6.90J 12.2J 13.98 MW-1 28-Nov-12 153 1.03J 0.751 12.6 5.54J 0.75J 29.91 5.751 4.96) 3.551 MW-1 10-May-13 172 0.121 0.261 0.87J 15.9 9.48J 0.3J 35.1J 8.861 8.67J MW-1 6-Nov-13 127 0.31J 11.5 8.66J 1.12J 29J 5.89J 11.918 2.641B MW-1 7-May-14 1.991 120 0.061 0.281 10.3 10.2 0.281 28.2J 5.61J 0.10J 6.99.1 1.93J MW-1(dup) 7-May-14 119 0.051 0.311 10.5 10.2 0.29J 28.01 5.701 6.161 1.911 MW-1 4-Nov-14 2.271 126 0.05J 0.44J 12.5 9.07J 0.951 31.1J 2.40J 5.47.18 1.72J 1302-MSWLF- MW-1 5-May-15 0.831 128 0.17J 11.6 7.74J 0.23J 29.91 2.991 3.771 1.881 CDLF-1998 MW-1 28-Oct-15 144 0.36J 1.52J 14.4 8.261 1.15J 33.3J 4.32CN,J 3.63.1 4.246-01,1 MW-1 19-May-16 144 0.34J 0.511 12.8 12.0 0.28J 29.41 2.591 1.991 MW-1 2-Nov-16 143 0.391 13.7 8.641 0.631 30.4J 3.02J MW-1 10-May-17 150 0.17J 0.511 12.5 6.82J 0.32J 29.41 3.29J 2.051 MW-1 31-Oct-17 132 0.431 0.76J 12.4 7.781 0.781 29.01 3.15J 3.05J MW-1 7-Jun-18 0.931 1.2J 146 0.21J 13.1 7.8J 0.48J 29.61 4.21 MW-1 (dup) 7-Jun-18 0.871 148 0.34J 13.6 8.31 0.551 31.3J 7.0J MW-1 19-Dec-18 136 0.68J 12.2 6.3J 0.68J 30.01 2.6J 3.01 MW-1 9-May-19 0.461 133 12.7 3.11 0.131 28.9 1.5J 2.5J MW-1(dup) 9-May-19 1 135 1 1 1 12.3 1 2.71 1 0.121 1 1 27.8 1 1 1 2.5J MW-3 4-May-11 36.21 0.32J 4.19JB 1.56.1 1.64J 1.14J 2.341 0.111 6.81 7.681 MW-3 9-Nov-11 35.21 0.251 2.56J 1.221 1.60J 11 2.03J 8.11 MW-3 (dup) 9-Nov-11 37.1J 0.241E 2.301 1.201 1.551 LOU2.001 6.291 MW-3 8-May-12 30.11 2.07J 0.64J 1.69J 0.79J 2.23J 3.76J 7.6316 MW-3 28-Nov-12 28.6J 2.301 0.32J 0.84J 0.43J 1.201 3.54J 1.981 MW-3 9-May-13 37.91 0.51J 3.28J 1.531 1.81J 2.21J 2.361 6.15J 8.11 MW-3 7-Nov-13 0.50J 37.9J 0.47J 0.09J 3.931 1.781 3.55J 4.17J 4.471 24.7J 82B MW-3 8-May-14 56.21 0.70J 3.32J 2.451 3.081 3.28J 3.54J 8.62J 36.6 1302-MSWLF- MW-3 6-Nov-14 30.8J 0.05J 1.14JB 0.40J 1.03J 0.42J 1.561 3.851 3.571B CDLF-1998 MW-3 6-May-15 0.811 55.41 0.71J 4.14JB 2.591 3.171 3.69J 4.361 0.07J 11.3J 15.3 MW-3 28-Oct-15 25.01 1.23J 0.25J 0.83J 4.17CN,J 3.121 5.43E-01,1 MW-3 18-May-16 1.46J 0.351 0.991 3.481 2.101 MW-3 2-Nov-16 27.41 1.60J 0.25J 1.00J 2.361 MW-3 11-May-17 32.01 0.13J 2.00J 0.63J 0.551 1.29J 3.65J 2.931 MW-3 1-Nov-17 27.61 1.45J 0.07J 0.891 2.401 MW-3 7-Jun-18 0.631 28.01 0.0511 1.3J 2.4J 3.5J MW-3 19-Dec-18 31.11 0.14J 1.81 0.31J 1.01 2.71 2.31 MW-3 8-May-19 32.5 0.074J 1.6J 2.7J 2.3J MW-3 Deep 5-May-11 2.47.1 3.11J 195 1.73 1.24 52.1 _ 16 26 14 55.4 0.17J 0.551 77.3 81 MW-3 Deep 9-May-12 0.351 38.31 0.931 2.12J 1.71113 MW-3 Deep 30-May-13 0.411 37.71 0.12J 0.09J 2.181B 0.131 1.32J 0.17J 2.49J 2.57J MW-3 Deep 8-May-14 40.81 0.13J 4.10J 1.591 0.981 2.78J 5.441 1302-MSWLF- MW-3 Deep 6-May-15 0.261 2.161 44.01 0.13J 0.29J 1.901 1.72J 2.47J 33.2 CDLF-1998 MW-3 Deep 28-Oct-15 1.021 42.21 0.70J 0.501 0.641 0.57J 3.000N,J 5.8713-01) MW-3 Deep 19-May-16 1.501 43.01 0.69J 0.61J 0.40J 0.581 2.37J 3.26J MW-3 Deep 11-May-17 0.761 0.711 44.11 0.55J 0.801 0.431 0.68J 2.061 MW-3 Deep 7-Jun-18 0.811 50.31 3.6J MW-3 Deep 8-May-19 0.731 56.9 5.71 MW-9 3-May-11 11.81 1.44JB 0.27J 3.87J 0.611 5.87J 4.621B 1302-MSWLF- CDLF-1998 MW-9 9-Nov-11 9.87J 1.73J 0.16J 2.04J 0.54J 4.771 MW-9 9-May-12 13.7J 1.33J 0.341 5.65J 0.091 0.801 8.37J 6.191B MW-A 3-May-11 40J 0.151 1.38113 3.481 0.87J 12.5J 3.86113 MW-A 9-Nov-11 0.36JB 44.2J 0.13J 1.811 0.76J 9.32J 2.821 MW-A 9-May-12 42.4J 0.101 1.14J 8.201 0.91J 15.51 4.53113 MW-A 27-Nov-12 0.36JB 45.6J 0.13J 0.97J 2.86.1 1.17J 11.61 1.86J 2.63J MW-A 7-May-13 43.7J 0.14J 0.64J 1.481 1.48J 0.07J 9.14J 1.09J 2.311 MW-A 5-Nov-13 43.4J 1.65J 2.05J 0.76J 9.931 20.3JB 3.371B MW-A 6-May-14 44.2J 0.14J 3.73113 8.881 0.84J 16.6J 1.15J 2.10113 MW-A 4-Nov-14 45.1J 0.20J 6.141 0.94J 18.7J 1.41J 1.87J 1302-MSWLF- MW-A 5-May-15 46.9J 0.15J 3.441 0.84J 13.4J 1.41J 1.821 CDLF-1998 MW-A 27-Oct-15 0.26J 47.2J 0.14J 3.151 1.18J 0.17J 12.9J 2.25CN,J 2.14J 5.23B-01,J MW-A 17-May-16 0.351 1.011 44.3J 0.17J 9.541 0.48J 19.81 2.40) 1.641 MW-A 1-Nov-16 48.6J 0.17J 7.251 19.2J 3.85J MW-A 9-May-17 0.4513-01,1 48.9J 0.16J 4.691 0.40J 14.7J 1.80J MW-A 31-Oct-17 50.9J 0.15J 4.83J 0.27J 15.11 1.97J MW-A 7-Jun-18 52.8J 0.14J 4.61 2.7J 29.8J 22.0 MW-A 20-Dec-18 52.3J 0.090J 5.51 16.8J 2.9J MW-A 1 9-May-19 1 1 1 56.0 1 0.191 1 1 11.2 1 25.2 1 1.5J 31.9 6.0J Smith Page 3 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-B 4-May-11 2.351 269 0.281 ,,, 3.781B 18 3.451 1.36176.35J 181 0.141 ,,, 9.951 MW-B 9-Nov-11 2.591 249 0.06J 8.751 1.51J 0.70J541 0.13J 3.6J MW-B 9-May-12 191 8.681 0.891 0.091F 15.98MW-B 29-Nov-12 5.881 268 23.5 1.081 0.20J291 3.58J MW-B 10-May-13 2.551 197 9.391 1.11 0.29J.89J 10.7 MW-B 6-Nov-13 2.02J 225 11.7 0.97J 0.23J.491 15.918 3.771B MW-B 8-May-14 2.731 236 0.081 11.5 1.25J 0.55J.48J 5.811 3.14J MW-B 4-Nov-14 6.041 226 0.06J 21.0 1.12J 0.181.751 2.6218 1.521 1302-MSWLF- CDLF-1998 MW-B 5-May-15 0.30J 1.501 160 8.501 1.25J 0.34J 7.05J 2.25J 1.97J MW-B 29-Oct-15 2.61J 171 0.521 16.5 0.53J 0.31J 5.451 2.39CN,1 0.07J 7.39B-01,1 MW-B 19-May-16 0.308-01,1 2.16J 225 1.05J 11.7 0.81J 0.39J 6.53J 0.061 4.64J 3.54J MW-B 3-Nov-16 2.431 196 13.5 0.24J 6.841 2.711 MW-B 10-May-17 1.73E-01,1 258 0.58J 9.20J 0.451 0.351 5.54J 0.06J 3.151 2.03J MW-B 31-0tt-17 3.551 256 0.771 14.9 0.29J 0.091 7.28J 2.081 MW-B 6-Jun-18 4.81 251 0.191 2.3J 15.8 2.11 0.971 7.8J 0.151 4.91 6.3J MW-B 19-Dec-18 0.781 172 0.071J 9.6J 0.36J 5.51 15.1 MW-B 9-May-19 0.381 175 7.3 0.271 0.10J 5.5 2.5J MW-C 4-May-11 42.3J 0.44J 0.07J 7.321 5.63J 2.58J 1.45J 4.141 0.081 7.261 9.971 MW-C 9-Nov-11 15.51 0.151 0.10J 0.62J 3.43J 1.06J 0.431 4.19J 8.62J MW-C 9-May-12 43.5J 0.43J 7.451 17 3.94J 2.30J 6.851 10.4J 22.28 MW-C 29-Nov-12 35.81 0.13J 2.75J 9.05J 1.17J 0.711 3.94J 4.871 8.07J MW-C 9-May-13 19.7J 0.24J 2.961 0.751 1.36J 0.81 1.771 3.481 10.1 MW-C 6-Nov-13 31.71 0.26J 3.77J 9.541 1.791 0.821 3.74J 23.518 18.88 MW-C 7-May-14 19.6J 0.17J 2.98JB 3.20J 0.79J 0.26J 1.651 3.08JB 1302-MSWLF- MW-C 5-Nov-14 47.21 0.10J 0.57J 1.68J 4.20J 1.301 0.291 4.74J 2.111E 3.06J MW-C 6-May-15 20.4J 0.30J 2.381 2.26J 1.66J 0.911 2.341 3.531 3.431 CDLF-1998 MW-C 29-Oct-15 1.421 47.91 0.681 11.6 7.47.1 4.52J 3.041 9.28J 1.15J 3.79CN,J 0.101 19.4J 14.48-01 MW-C 18-May-16 21.4J 0.21J 0.71J 1.78.1 0.47J 0.25J 1.691 4.11J 2.011 MW-C 2-Nov-16 2.16J 34.01 0.181 1.30J 10.3 0.55J 0.331 3.79J 3.51J MW-C 9-May-17 22.51 0.141 1.081 0.43J 0.30J 1.181 1.94J 1.36J MW-C 1-Nov-17 0.60J 31.91 0.331 4.971 7.81J 1.381 1.201 3.92J 8.391 5.701 MW-C 7-Jun-18 2.01 52.5J 0.81J 16.5 8.2J 4.1J 4.0J 8.81 1.5J 25.8 17.7 MW-C 19-Dec-18 22.01 0.14J 0.11J 0.97J 0.331 1.2J 3.0J MW-C 30-May-19 19.6 0.16J 28.7 1.3.1 1 3.11 0.181 1 9.7 1.7J 4.51 MW-D 4-May-11 193 0.811 0.12J 2.3 11.7 30.2 5.281 30.4J 0.25J 41.7 37.3 MW-D 9-Nov-11 0.361B 118 0.25J 8.02J 3.05J 8.5J 1.47J 15.3J 0.07J 5.68J 12.1 MW-D 9-May-12 124 3J 8.97J 3.941 0.611 15.7J 5.121 9.331B MW-D 28-Nov-12 0.981 1.831 117 0.11J 0.06J 2.31J 3.01J 3.63J 0.611 13.8J 12.1J 5.1116 MW-D 9-May-13 140 0.211 0.08J 6.41 6.72.1 7.781 0.941 17.3J 25.8 10.8 MW-D 6-Nov-13 194 0.86J 0.25J 28.6 12.8 35.5 7.32J 27J 105B 37.9E MW-D 7-May-14 169 0.211 3.74JB 19.0 1.16J 20.7J 8.021 1.43113 MW-D 5-Nov-14 121 0.11J 0.06J 1.62J 7.61.1 3.41J 0.72J 18.3J 0.95JB 7.001 1302-MSWLF- CDLF-1998 MW-D 5-May-15 1.791 164 14.2 1.061 21.7J 4.511 1.621 MW-D 29-Oct-15 0.301 5.111 199 0.74J 0.121 F39.0 20.4 32.7 6.25J 37.0J 5.92J 3.91CN,J 0.371 50.7 48.5E-01 MW-D 18-May-16 1.651 157 0.111 0.851 17.0 0.92J 0.191 21.0J 3.92J 1.721 MW-D 3-Nov-16 134 0.091 8.75.1 0.85J 0.21J 19.91 3.641 MW-D 9-May-17 0.9413-01,1 242 0.07J 0.56J 18.8 0.421 0.091 24.3J 8.271 5.681 MW-D 1-Nov-17 1.231 151 0.30J 9.17J 6.69J 7.62J 1.60J 20.4J 1.87J 0.06J 12.8J 14.5 MW-D 7-Jun-18 1.21 139 0.111 1.7J 3.41 1.41 0.361 15.7J 6.81 15.8 MW-D 19-Dec-18 214 0.111 18.6 14.8J 14.0J MW-D 10-May-19 140 0.22J 0.64J 12.1 0.47J 18.1 18.7 6.31 MW-E Rep 4-May-11 262 0.571 1.181B 12.4 1.091 0.621 15.11 6.41 MW-E Rep 8-Nov-11 1.07J8 267 0.41J 9.281 0.83J 13.2J 0.07J 2.881 MW-E Rep 8-May-12 303 0.311 12.6 0.851 0.321 15.2J 1.721 10.313 MW-E Rep 8-May-13 286 0.34J 8.291 1.08J 0.081 14J 0.891 3.711 MW-E Rep 5-Nov-13 294 15.5 0.841 0.221 15.81 14JB 6.38JB MW-E Rep 6-May-14 342 0.44J 16.8 1.45J 0.67J 15.9J 7.581 6.461B MW-E Rep 4-Nov-14 326 0.21J 8391 0.891 0.281 15.9J 1.57J 2.9918 4.311 1302-MSWLF- MW-E Rep 5-May-15 348 0.30J 7.481 1.02J 0.62J 14.5J 1.44J 12.21 4.461 CDLF-1998 MW-E Rep 27-Oct-15 0.91) 294 0.261 1.12J 10.2 0.391 12.3J 2.07CN,J 4.84B-01,1 MW-E Rep 18-May-16 1.111 365 0.27J 12.0 0.32J 12.9J 2.311 2.991 MW-E Rep 1-Nov-16 297 0.151 5.441 0.171 11.4J 5.131 MW-E Rep 9-May-17 0.71B-01,J 353 0.20J 7.581 0.13J 12.1J 1.431 3.401 MW-E Rep 31-Oct-17 0.861 3" 0.221 6.81 0.341 12.2J 4.451 3.711 MW-E Rep 11-Jun-18 0.661 350 0.23J 9.11 13.1J 4.6J MW-E Rep 20-Dec-18 321 0.111 7.11 13.3J MW-E Rep 7-May-19 0.571 344 0.231 7,4 11.7 3.4J Smith Page 4 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, „ ,,, MW-E Deep 4-May-11 2.96J 2,530 0.25J 0.18J 1.14JB 66.4 3.11J 20 30.8J 57.9 MW-E Deep 8-Nov-11 3.661 2,280 0.16J 0.22J 54.2 1.38J 16.4 26J 43.5 MW-E Deep 8-May-12 2.51J 2,210 0.53J 0.36J 50.1 31.6 94 24.9J 7.651 60.98 MW-E Deep 28-Nov-12 0.711 3.86J 1,820 0.84J 1.99 4.561 39.6 22.3 213 26.1J 0.18J 9.201 67.2 MW-E Deep 8-May-13 4.5618 1,730 0.34J 0.71J 37.9 4.7J 74.5 201 43 MW-E Deep 6-Nov-13 1.091 2,240 0.19J 0.321 39.7 2.341 39.3 20.51 1618 41.2E MW-E Deep 6-May-14 2.691 2,080 0.601 0.441 63.4 6.291 60.9 32.7J 2.491 32.28 MW-E Deep 4-Nov-14 3.291 2,000 0.311 0.471 43.6 6.411 55.6 20.41 3.7518 30.0 1302-MSWLF- MW-E Deep 5-May-15 2.42J 2,040 0.25J 0.19JJ 34.4 2.701 22.2 17.3J 0.87J 2.54J 19.3 CDLF-1998 MW-E Deep 27-Oct-15 2.551 1,900 0.28J 0.23J 34.3 4.34J 38.2 14.2J 2.81CN,1 0 2.971 24.36-01 MW-E Deep 18-May-16 3.54J 2,150 0.48J 0.67J 0.93J 37.0 8.73J 76.4 16.0J 1.07J 8.521 30.6 MW-E Deep 1-Nov-16 2.431 1,960 0.22J 0.18J 34.5 2.34J 18.5 14.61 19.3 MW-E Deep 9-May-17 1.68B-01,1 2,010 0.23J 32.9 0.591 3.96J 14.5J 8.05J MW-E Deep 1-Nov-17 1.651 2,100 0.261 0.461 32.3 1.63J 9.69J 15.2J 0.06J 1.311 8.011 MW-E Deep 11-Jun-18 2.11 2,310 0.211 33.5 2.11 13.9J 4.8J MW-E Deep 20-Dec-18 1.31 2,640 0.261 1.61 39.1 6.7J 21.2J 5.21 MW-E Deep 8-May-19 2.11 2,910 0.37J 42.1 2.9 24.9 5.41 MW-F 4-May-11 136 0.14J 0.75JB 1.291 0.91J 3.151 2.241 MW-F 9-Nov-11 0.171 5.421 219 0.06J 10.6 1.061 4.44J 1.57J MW-F 9-May-12 3.191 242 8.351 1.27J 3.331 0.921 2.851 2.34JB MW-F 29-Nov-12 283 0.15J 1.86J 8.501 1.071 0.59J 5.00J 1.52J 3.761 4.46J MW-F 10-May-13 1.171 154 0.21J 1.63JB 5.161 1.56J 0.15J 2.78J 21 0.12J 4.861 MW-F 6-Nov-13 2.011 255 11.2 0.821 0.191 3.45J 0.83J 12.718 2.43113 MW-F 8-May-14 5.171 213 0.16J 10.4 0.97J 0.54J 4.88J 1.041 6.84J 1.771 MW-F 4-Nov-14 2.921 262 0.23J 11.3 0.801 0.451 5.51J 3.09J 1.25J 1302-MSWLF- MW-F 5-May-15 0.311 2.291 129 0.111 1.391 0.73J 0.101 4.571 1.851 CDLF-1998 MW-F 28-Oct-15 5.941 262 0.45J 13.0 0.791 0.14J 4.80J 1.92CN,J 3.676-01,1 MW-F 18-May-16 3.401 214 9.62J 3.841 MW-F 3-Nov-16 231 0.14J 7.641 4.63J MW-F 11-May-17 0.87B-01,J 190 0.12J 4.101 0.08J 5.001 MW-F 31-Oct-17 0.801 363 13.4 4.31J 1.331 MW-F 6-Jun-18 2.4J 149 0.481 3.11 3.61 1.81 7.1J 6.41 MW-F 19-Dec-18 0.811 103 0.101 1.31 S.SJ MW-F(dup) 19-Dec-18 1.01 107 0.101 1.31 6.1J MW-F 9-May-19 2.41 188 7.2 6.6 4.5 8.91 MW-G 4-May-11 148 0.08J 0.19J 1.07JB 14.6 12.6 1.15J 32.5J 8.16J 6.12J 4.01J MW-G 9-Nov-11 0.141 2.751 420 0.12J 4.991 0.87JB 3.17J 2.79J 2.511 MW-G 9-May-12 4.45J 302 2.191 0.86J 4.40J 1.41J 4.251 13.7B MW-G 29-Nov-12 2.031 385 0.15J 2.141 0.961 0.121 3.69J 3.03J 2.791 2.861 MW-G 30-May-13 354 0.18J 5.081 1.191 0.14J 2.43J 1.51J 2.111 5.141 MW-G 6-Nov-13 5.441 346 3.091 0.811 0.091 4.81J 2.75J 12.41E 2.49113 MW-G 8-May-14 4.421 373 0.20J 6.691 1.31J 0.27J 5.00J 2.95J 7.991 4.081 MW-G 4-Nov-14 480 0.26J 7.021 2.571 0.611 9.32J 2.96J 0.171 10.61E 6.721 1302-MSWLF- MW-G 5-May-15 2.13J 340 0.181 5.62J 2.30J 0.37J 5.29J 4.79J 4.851 4.161 CDLF-1998 MW-G 28-Oct-15 4.451 387 0.141 1.23J 5.011 0.741 0.191 4.88J 2.09CN,J 2.761 3.698-01,1 MW-G 19-May-16 3.19J 412 0.151 1.31J 6.071 0.89J 0.26J 5.07J 4.721 4.621 MW-G (dup) 19-May-16 0.31B-01,J 3.511 417 0.111 1.05J 5.371 0.091 3.64J 2.551 2.081 MW-G 3-Nov-16 6.65J 418 0.091 1.23J 3.671 1.001 5.36J 5.041 MW-G 11-May-17 0.461 2.211 448 0.35J 2.75J 7.451 2.82J 1.14J 5.53J 1.72J 0.091 13.21 10.5 MW-G 1-Nov-17 5.931 488 0.101 0.95J 5.96J 0.091 5.39J 2.41J 2.66J MW-G 6-Jun-18 5.21 448 0.0911 6.31 4.5J 2.21 MW-G 19-Dec-18 1.41 331 0.201 6.11 2.5J 3.1J 3.81 MW-G 9-May-19 2.41 464 0.13J 0.79J 14.6 0.43J 0.111 10.9 0.061J 0.741 3.81 MW-H 5-May-11 62.21 0.311 9.05J 2.051 6.941 1.681 6.89J 0.081 9.85J 16.9 MW-H 9-Nov-11 0.141 32.6J 0.13J 2.69J 0.71J 2.93J 0.591 2.83J 7.371 MW-H 9-May-12 ".91 0.131 3.58J 0.89J 4.231 1.17J 3.17J 5.79J 12.113 MW-H 29-Nov-12 37.8J 1.68J 0.25J 1.62J 0.29J 1.13J 2.891 5.651 MW-H 9-May-13 27.91 1.94J 0.211 1.331 0.221 1.1J 2.68J 5.451 MW-H 7-Nov-13 72J 0.38J 4.94J 2.51J 6.39J 2.65J 5.96J 15.41 16.48 MW-H 8-May-14 67.OJ 0.471 3.48J 1.731 6.341 2.121 4.49J 9.00J 14.2 MW-H 6-Nov-14 49.8J 0.17J 2.04113 0.95J 3.67J 0.95J 2.97J 5.331 7.55113 1302-MSWLF- MW-H 5-May-15 1.201 52.51 0.201 0.501E 0.891 4.341 1.271 2.94J 4.63J 7.651 CDLF-1998 MW-H 29-Oct-15 1.851 78.11 0.48J 8.22J 2.56J 8.56J 2.51J 7.19J 2.57J 4.20CN,J 0.091 14.71 22.98-01 MW-H 19-May-16 1.241 52.31 0.251 4.01J 1.161 3.621 1.261 3.27J 1.52J 8.62J 9.431 MW-H 3-Nov-16 67.8J 0.33J 5.811 1.961 5.86J 1.78J 5.59J 2.87J 10.71 15.7 MW-H 11-May-17 0.851 64.81 0.281 6.82J 1.83J 4.761 1.681 6.28J 2.39J 0.091 10.2J 12.5 MW-H 1-Nov-17 0.62J 59.5J 0.23J 4.10J 1.201 4.29J 1.29J 3.51J 3.11J 8.681 9.691 MW-H 7-Jun-18 1.21 56.6J 0.26J 3.8J 1.21 4.7J 1.3J 3.2J 8.11 9.6J MW-H 19-Dec-18 1.11 74.7J 0.53J 7.8J 2.61 9.81 2.8J 6.6J 1.81 15.01 17.9 MW-H 9-May-19 32.7 0.13J 1.3J 0.47J 2.9J 0.48J 2.81 4.71 7.31 Smith Page 5 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, ,,, MW-H Deep 5-May-11 57.5J 0.221 4.33JB 0.82J 4.35J 1.57J 2.651 7.231 7.841 MW-H Deep 9-Nov-11 29.2J 0.051 1.17J 0.711 2.071 0.451 1.62J 2.551 MW-H Deep 9-May-12 0.74J 49.6J 0.181 3.41J 0.95J 5.67J 1.42J 2.91J 7.531 13.28 MW-H Deep 28-Nov-12 52.4J 1.28J 1.591 0.961 2.44J 2.621 MW-H Deep 9-May-13 0.831 43J 0.471 2.21 0.221 1.451 6.981 MW-H Deep (dup) 9-May-13 0.241 44.1J 1.051 0.19J 1.72J 0.22J 1.41 3.34J 13.3 MW-H Deep 7-Nov-13 40.9J 0.28J 1.85J 0.23J 1.39J 12.11 5.2918 MW-H Deep 8-May-14 55.01 0.101 0.32J 2.03J 0.37J 1.63J 3.891 MW-H Deep 6-Nov-14 49.9J 0.08J 1.33JB 1.45J 0.191 2.00J 4.181 9.2518 1302-MSWLF- MW-H Deep (dup) 6-Nov-14 49.4J 1.5416 0.50J 1.74J 0.27J 1.93J 6.32JB CDLF-1998 MW-H Deep 5-May-15 1.841 44.4J 0.291 2.691 0.38J 1.97J 2.001 2.00J MW-H Deep (dup) 5-May-15 REINEIR 39.81 0.13J 1.08J 0.31J 2.88J 0.37J 2.26J 3.231 MW-H Deep 29-Oct-15 45.91 0.64J 1.49JB 0.231 1.57J 3.82CN,J 4.801 3.066-01,1 MW-H Deep 19-May-16 1.10B-01,J 55.91 0.12J 0.87J 2.36J 0.45J 1.33J 0.30J 5.451 2.271 MW-H Deep 3-Nov-16 54.71 1.14J 0.251 0.891 MW-H Deep 11-May-17 50.51 0.76J 1.34J 0.44J 1.23J 3.841 7.301 MW-H Deep 1-Nov-17 53.01 0.381 0.82J 0.181 0.801 4.121 1.83J MW-H Deep 7-Jun-18 0.791 61.91 0.066J 1.41 0.28J 5.01 2.21 MW-H Deep 19-Dec-18 47.41 0.059J 0.291 3.41 MW-H Deep 9-May-19 42.0 0.52J 1.11 0.17J 0.831 4.4J 3.21 MW-I 4-May-11 26.31 0.16J 4.87JB 0.291 0.94J 0.441 2.44J 4.151 3.14J MW-I 9-Nov-11 0.301B 12J 0.12JB 0.66J 0.111 0.811 1.24J 0.281 3.361 MW-1 9-May-12 0.25J 17.61 0.33J 1.801 0.201 1.651 0.271 3.01J 3.531 11.58 MW-1(dup) 9-May-12 16.21 0.31J 1.71J 1.111 0.23J 2.39J 8.561E MW-I 28-Nov-12 0.301 14.31 0.73J 0.441 0.94J 2.491 1.0516 MW-1 10-May-13 0.491 17.81 0.22J 0.07J 1.38JB 0.34J 0.79J 0.31J 1.32J 3.391 MW-1 7-Nov-13 14.21 0.121 0.211 0.591 0.201 1.41J 6.831 2.6116 MW-I 7-May-14 13.91 0.13J 3.44JB 0.77J 0.191 1.31J 1.311 1.531E 1302-MSWLF- MW-1 5-Nov-14 20.71 0.16J 0.05J 0.82J 0.261 0.901 0.311 1.561 2.5518 1.70J CDLF-1998 MW-1 5-May-15 0.501 15.41 0.17J 1.81J 1.71J 0.33J 1.851 1.861 MW-1 29-Oct-15 21.11 0.21J 1.10J 0.621 0.281 1.57J 4.40CN,J 4.711 4.328-01,1 MW-1 19-May-16 0.37E-01,1 20.71 0.20J 1.07J 0.33J 1.75J 3.091 2.421 MW-1 3-Nov-16 24.21 0.291 0.07J 1.30J 0.551 0.841 1.43J 3.581 MW-1 11-May-17 26.31 0.23J 0.08J 1.25J 0.55J 0.79J 1.48J 3.641 2.451 MW-1 31-Oct-17 23.41 0.231 1.30J 0.391 0.511 1.21J 3.951 3.011 MW-1 7-Jun-18 24.41 0.18J 0.35J 1.01 3.11 2.61 MW-1 18-Dec-18 31.01 0.231 0.15J 2.3J 0.641 1.6J 3.91 4.6J MW-1 9-May-19 17.8 0.18J 1.2J 0.24J 1.2J 4.91 3.31 MW-J 4-May-11 38.41 0.31J 6.14J 2.01J 31 2.41 5.47J 0.08J 13J 11.2 MW-1 9-Nov-11 0.161B 35.31 1.551 0.441 1.26J 0.27JB 5.84J 0.12J 5.981 MW-J 9-May-12 15.21 1.64J 0.38J 1.411 0.521 2.76J 3.351 15B MW-1 29-Nov-12 16.41 1.39J 0.30J 2.54J 0.30J 1.20J 3.93J 4.891 MW-J 8-May-13 10.61 0.86J 0.311 1.16J 0.271 1.38J 4.811 2.7J MW-1 6-Nov-13 17.8J 0.79J 1.43J 0.911 2.28J 21.41E 4.731E MW-J 7-May-14 31.61 3.021E 0.52J 1.411 0.831 2.03J 3.401 4.241B MW-1 4-Nov-14 27.41 0.17J 1.45J 1.241 2.00J 1.16J 3.54J 9.58JB 6.381E 1302-MSWLF- CDLF-1998 MW-1 6-May-15 10.71 1.38J 0.51J 2.001 0.631 2.48J 3.511 3.361 MW-1 28-Oct-15 11.01 0.58E-01,J 0.451 1.64J 0.38J 2.06J 3.59CN,J 2.47J 5.911 MW-1 18-May-16 0.961 28.21 0.25J 3.11J 1.40J 1.621 1.991 3.55J 0.90J 12.01 6.861 MW-1 2-Nov-16 32.2J 0.281 4.86J 2.511 2.381 2.741 5.69J 1.66J 14.9J 11.0 MW-1 9-May-17 18.8J 0.111 1.66J 0.73J 0.97J 1.02J 2.04J 6.18) 4.411 MW-1 1-Nov-17 18.71 0.131 2.59J 0.921 0.981 1.241 2.21J 8.181 6.221 MW-1 7-Jun-18 1.21 37.8J 0.35J 5.6J 2.5J 3.3J 6.OJ 19.11 14.6 0.911 MW-1 19-Dec-18 16.71 0.14J 2.1J 1.31 2.5J 7.21 6.91 MW-1 10-May-19 0.481 19.0 0.111 1.6J 0.70J 0.82J 0.93J 1.61 7.41 6.31 MW-K 4-May-11 25.21 0.261 6.52J 1.571 2.251 1.531 3.65J 111 7.961 MW-K 9-Nov-11 17.7J 0.14JB 2.51J 0.73J 3.67J 0.73J 2.07J 0.07J 4.961 4.091 MW-K 9-May-12 35.21 0.221 7.59J 2.981 3.661 1.921 6.06J 13.8J 20.113 MW-K 28-Nov-12 16.11 1.35J 0.28J 0.74J 0.28J 1.42J 2.53J 4.441B MW-K 8-May-13 1.021B 17J 0.151 1.911 0.711 1.331 0.691 2.24J 6.05J 5.281 MW-K 6-Nov-13 13.9J 2.68J 0.76J 1.26J 0.43J 1.94J 23JB 4.68JB MW-K 7-May-14 17.51 0.121 4.271B 0.491 1.301 0.701 1.831 3.49J 2.461B MW-K 5-Nov-14 13.3J 0.13J 1.21J 0.53J 1.20J 0.43J 1.97J 3.8218 3.191 1302-MSWLF- MW-K 5-May-15 1.161 1.421 15.31 0.14J 0.491 1.991 0.711 2.54J 4.66J 2.951 CDLF-1998 MW-K 29-Oct-15 0.35J 26.2J 0.191 2.54E-01,J 1.16) 2.41J 1.04J 4.17J 2.87CN,J 6.18) 5.601 MW-K 18-May-16 1.431 17.81 0.161 3.25J 0.89J 1.031 0.831 2.28J 1.18J 8.68J 5.351 MW-K 2-Nov-16 17.8J 0.16J 2.60J 0.87J 0.94J 0.72J 2.04J 1.78J 4.01J MW-K(dup) 2-Nov-16 4.05J 1.311 0.63J 0.18J 1.17J 1.08J 2.18J MW-K 9-May-17 0.47B-01,1 13.9J 0.101 1.901 0.47J 0.62J 0.41J 1.591 4.411 1.92J MW-K 1-Nov-17 0.821 20.2J 0.16J 3.28J 1.23) 1.03J 0.87J 2.20J 8.12J 4.57J MW-K 7-Jun-18 0.941 0.88J 13.8J 0.13J 2.2J 0.59J 1.3J 6.21 2.2J MW-K 19-Dec-18 15.7J 0.311 0.12J 2.01 0.491 1.11 0.22.1 4.0J 2.6J MW-K 10-May-19 15.8 0.0891 1.81 1.01 0.23J 1.21 5.11 3.71 Smith Page 6 of 18 June 2019 Table 5a Detected Groundwater Constituents - Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 ,,, ,,, MW-L 4-May-11 45.7J 2.67JB 0.35J 0.7J 0.21 1.64J 3.96J MW-L 9-Nov-11 0.191 40.9J 0.06J 1.64J 0.41J 0.93J 0.37J 1.491 3.72J MW-L 9-May-12 43.8J 1.20J 0.52J 0.091 1.27J 1.931 2.161E MW-L 28-Nov-12 0.82J 23.0J 1.74J 0.32J 0.39J 2.211 6.47J 3.75J MW-L 9-May-13 1.24JB 43.5J 1.121 0.49J 0.83J 0.221 1.951 2.91 3.29J MW-L 7-Nov-13 49.2J 0.191 0.881 1.201 2.49J 0.85J 3.62J 11.&1 11.56 MW-L 8-May-14 43.7J 0.07J 0.67J 0.14J 1.281 1.951 MW-L 5-Nov-14 38.6J 0.76J 0.14J 1.32J 2.44J 2.28JB 1302-MSWLF- CDLF-1998 MW-L 6-May-15 40J 0.811 0.161 1.27J 2.23J MW-L 28-Oct-15 33.5J 1.051 0.29J 0.31J 1.071 4.04CN,1 2.87J 6.06E-01-J MW-L 19-May-16 38.4J 0.881 1.011 2.231 1.48J MW-L 2-Nov-16 35.2J 1.00J 1.041 2.46J MW-L 10-May-17 0.56B-01,J 33.3J 1.01J 0.49J 0.111 0.951 2.341 2.80J MW-L 1-Nov-17 33.9J 1.231 1.30J 0.12J 0.851 1.46J 1.87J MW-L 7-Jun-18 32.7J 2.7J 60.9 MW-L 19-Dec-18 34.4J 0.079J MW-L 8-May-19 41.0 2.9J MW-L Deep 4-May-11 0.44J 56.8J 0.34J 14.7 2.861 3.62J 3.391 13.61 15.2J 12.7 MW-L Deep 9-May-12 0.62J 23J 2.03J 0.83J 1.60J 0.681 3.14J 8.531 7.991B MW-L Deep 10-May-13 0.41J 19.2J 0.24J 1.891 0.27J 1.631 2.081 21.8 MW-L Deep 8-May-14 27.9J 1.34JB 0.111 1.32J 6.06J MW-L Deep 6-May-15 0.36J 23.11 0.901 1.24J 1.501 2.45J 45.1 1302-MSWLF- CDLF-1998 MW-L Deep 29-Oct-15 0.581 23.0J 0.47E-01,J 1.23J 0.091 1.62J 3.73CN,J 81.1 MW-L Deep 19-May-16 0.46J 30.8J 0.441 1.87J 0.17J 1.271 4.59J 116 MW-L Deep 10-May-17 0.9313-01,1 34.4J 0.081 0.42J 0.66J 0.14J 1.27J 4.731 128 MW-L Deep (dup) 10-May-17 0.91B-01,J 33.9J 0.07J 0.401 0.82J 0.151 1.28J 4.70J 123 MW-L Deep 7-Jun-18 32.1J 1.4J 2.41 352 MW-L Deep 8-May-19 0.901 34.3 1.81 3.6J 396 MW-M 5-May-11 0.921 64.2J 0.561 2.681 2.64J 15.6 4.83J 5.84J 0.14J 18.21 15.2 MW-M 9-May-12 40.3J 0.261 2.461 1.38J 8.56J 3.07J 3.801 11.81 15.28 MW-M 10-May-13 34.9J 0.161 1.44JB 0.69J 2.21J 0.5J 1.68J 2.2J MW-M 8- May -14 37.11 0.101 0.801 0.30J 2.00J 0.63J 1.911 2.42J 1302-MSWLF- MW-M 5-May-15 1.931 39.4J 0.88J 2.02J 0.51J 2.18J 4.071 1.71J CDLF-1998 MW-M 29-Ott-15 38.91 0.101 1.56E-01,J 0.39J 2.10J 0.62J 2.10J 3.09CN,J 1.78J 4.96J MW-M 18-May-16 0.921 38.8J 0.60J 0.46J 1.60J 0.58J 1.47J 6.841 1.54J MW-M 9-May-17 40.41 0.081 0.65J 1.501 0.57J 1.181 4.65J 1.981 MW-M 7-Jun-18 37.9J 0.31J 0.991 4.01 MW-M 30-May-19 1 49.1 1 1 1 1.7J 0.097J 0.901 5.11 1.81 MW-X 4-May-11 0.32J 51.51 0.211 7.8J 2.79J 2.91J 1.49JB 11J 0.08J 12.21 12.3 MW-X 9-Nov-11 23.11 0.22JB 2.97J 1.21J 2.46J 1.77J 4.34J 0.07J 10.5J 6.751 MW-X 9-May-12 34.9J 1.52J 1.37J 5.63J 8.771B MW-X 29-Nov-12 29.3J 1.801 0.331 1.311 0.25J 4.74J 5.191 2.171E MW-X 29-Nov-12 32.0J 3.20J 0.75J 1.54J 0.39J 5.79J 5.631 4.821B MW-X 8-May-13 1.53JB 35.4J 0.77J 0.731 1.8J 0.24J 6.37J 3.12J 4.551 MW-X 6-Nov-13 24.11 1.12J 0.35J 1.04J 0.32J 4.27J 18.21E 3.961B MW-X 7-May-14 37.01 0.05J 4.911E 0.731 1.25J 0.44J 5.74J 4.70J 3.841E 1302-MSWLF- MW-X 5-Nov-14 26.8J 2.58JB 0.36J 0.97J 0.191 3.67J 11.21 2.101B CDLF-1998 MW-X 6-May-15 28.9J 1.86J 0.32J 2.68J 0.211 4.33J 2.51J 1.421 MW-X 29-Oct-15 27.8J 2.08E-01,J 1.29J 4.65J 3.24CN,J 1.74J MW-X 18-May-16 0.861 32.01 1.71J 0.521 0.681 0.341 4.38J 6.501 2.221 MW-X 2-Nov-16 32.3J 1.70J 1.60J 0.29J 3.56J 2.69J MW-X 9-May-17 30.41 1.31J 0.711 0.281 4.03J 3.84) 3.221 MW-X 1-Nov-17 29.6J 1.78J 0.68J 0.23J 2.64J 5.37J 2.68J MW-X 7-Jun-18 37.41 0.121 4.3J 0.901 1.51 0.621 5.01 11.7J 4.51 MW-X 19-Dec-18 28.51 3.2J 3.31 M. 10-May-19 27.3 1.01 2.4J o.191 3.11 5.51 Notes: 1. All units are in micrograms per liter (parts per billion). 2. Monitoring wells MW-3 Deep, -L Deep, -and -M are sampled annually during the spring event. 3. • - Interim Maximum Allowable Concentration (IMAC) 4. (dup) - Duplicate S. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 6. B/e-01- Indicates constituent was detected in the batch blank above the method detection limit. 7. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used. 8. The November 2012 sampling event was the first event that CD-1s/CD-1d replaced MW-9 as the background monitoring wells. 9. MW-9 was removed from the monitoring program in November 2012. 10. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. 11. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit or not analyzed. Smith Page 7 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 CD-ls 3-May-11 CD-ls 8-Nov-11 CD-ls ]-May-12 CD-ls 27-Nov-12 0.41 O.JJ CD-ls ]-May-13 CD-ls 5-Nov-13 CD-ls &May-14 1302-MSWLF- CD-ls 4-Nov-14 CDLF-1998 CD-ls 5-May-15 CD-ls 27-0ct-15 CD-ls 17-May-16 CD-ls 1-Nov-16 CD-ls 9-May-17 CD-ls 31-01t-17 CD-ls 11-tun-18 CD-ls 1J-Dec-18 1.2 CD-ls 7-May-19 CD-ld 3-May-11 CD-ld 8-Nov-11 CD-ld 7-May-12 CD-ld 27-Nov-12 CD-ld 7-May-13 CD-ld 5-Nov-13 CD-ld 6-May-14 1302-MSWLF- CD-ld 4-Nov-14 CDLF-1998 CD-ld CD-ld 5-May-15 27-0ct-15 CD-ld 17-May-16 CD-ld 1-Nov-16 CD-ld &May-17 CD-ld 31-0ct-17 CD-ld 124 -18 CD-ld 17-Dec-18 CD-ld 7-M2y-19 CD-4 Rep 3-May-11 CD-4 Rep(dup) 3-May-11 CD-4 Rep 8-Nov-11 CD-4 Rep 8-May-12 CD-4 Rep 28-Nov-12 0.31 CD-4 Rep ?May-13 CD-4 Rep J-Nov-13 0.61 CD-4 Rep &May-14 1302-MSWLF- CO-4 Rep 4-Nov-14 CDLF-1998 CD-4 Rep &May-15 CD-4 Rep 27-Oct-15 CD-4 Rep 17-May-16 CD Rep 2-Nov-I6 C0-4 Rep 9-May-1] CD Rep 31-Oct-I] CD-4 Rep 6-1un-I8 CD-4 Rep 19-Dec-I8 CD-4 Rep 7-May-19 CD-6 3-May-11 O.JI 0 CD-6 8-Nov-11 l.Jl CD-6 &May-12 2.21 1.] 0.91 CD-6 2&Nov-12 2.81 0.41 1.2 0.81 CD-6 &May-13 3.61 1.6 1.3 1302-MSWLF- CD-6 ]-Nov-13 361 0.61 1 41 1 0.61 57 0.51 1. 4.6 2.4 2.7 5.2 CDLF-1998 CD-6 6-May-14 0.31 1.1 1.2 CD-6 4-Nov-14 4.J1 0.31 1.4 1.2 CD-6 6-May-15 3.J1 1.5 1.1 CD-6 27-0ct-15 3.11 1.0 0.91 CD-6 17-May-16 1.51 0.51 O.J1 CD-6 1-Nov-16 2.21 I I7 1 0.61 0.91 AMW-ls 3-May-11 0.51 11 0.91 9.2 11 15 O.JI 3.0 3.8 AMW-ls 8-Nov-11 0.51 OX 0.91 11 O.J1 15 O.JI 3.1 3.1 AMW-Ss 7-May-12 0.]1 11 1 12 0.81 16 0.81 3.5 3.9 AMW-Ss 2&Nov-12 0.61 0.81 1.1 10 0.]1 14 0.61 3.2 3.9 AMW-Ss &May-13 0.91 0.91 1.4 13 0.91 IB L 4.1 4.3 AMW-Ss 6-Nov-13 0.91 0.91 1.3 13 0.91 11 I1 3.8 3.9 AMW-Ss 7-May-14 0.91 0.91 1.1 9.8 0.]1 12 1.4 3.6 2.1 1302-M5WLF- AMW-Ss 5-Nov-14 0.61 1.01 9.0 0.51 10 2.5 2.8 CDLF-1998 AMW-Ss AMW-Ss 7-May-15 29-Oct-15 0.81 0.41 0.81 1.3 0.81 8.1 5.8 0.51 9.9 6.1 0.91 3.1 1.6 2.6 1 4 AMW-Ss 18-May-16 0.61 0.51 0.91 5.J ].6 0.61 1.8 1.7 AMW-Ss 2-Nov-16 0.21 1.11 24 2.81 15 10 1.1 0.91 AMW-Ss 10-May-17 0.]1 0.91 8.3 0.91 2.1 1.8 AMW-Ss 1-Nov-1] 0.31 2.81 3.21 1.3 0.91 AMW-Ss &Jun-18 0.551 0.7OJ 4.21 5.] 1.1 1.1 AMW-Ss 19-Dec-18 0.631 0.541 5.7 6.9 1.6 1.6 l.J AMW-Ss &May-19 0.801 3 4 6.3 0.7Ol 1.2 0.881 AMW-Sd 3-May-11 1.1 21 1.11,8 0.81 24 1.91 28 0.31 4.2 4.] 0.31 AMW-Sd 8-Nov-11 1.2 1.41 0.81 28 1.81 30 0.51 0.61 5.8 0.31 O Q AMW-Sd 7-May-12 1.2 1.]1 0.91 27 1.81 35 0.41 0.41 1.] 4.8 O, AMW-Sd 2&Nov-12 1.2 5.01 1.31 0.91 29 1.91 36 0.61 0.41 2.0 5.0 AMW-Sd &May-13 1.1 21 1.] 26 0.21 21 40 0.61 6.2 0.41 AMW-Sd 6-Nov-13 1.1 2.61 0.81 29 2.21 38 0.41 0.51 5.2 0.51 AMW-Sd ]-May-14 1.2 2.21 1.0 30 2.31 36 0.61 1.6 ].3 0.61 1302-M5WLF- AMW-Sd 5-Nov-14 1.3 1.]1 1.01 31 1.31 13 0.51 OX 3.2 0.31 29 CDLF-1998 AMW-Sd AZ 7-May-15 29-0ct-15 1.2 1.0 1.21 2.01 1.1 0.71 24 23 0.71 7.1 2.81 0.41 2.2 1.9 1: 20 AMW-Sd 18-May-36 1.1 0.91 23 9.] 1.6 8.0 AMW-Sd 3-Nav-36 1.4 2.21 1.0 26 0.81 ].0 0.51 13 AMW-Sd 10-May-1] 1.0 1.41 22 3.81 ].4 AMW-Sd 1-Nav-1] 1.4 3.01 27 0.71 SO 2.81 2.2 8.0 AMW-Sd &Jun-18 1.1 1.51 0.891 18.2 11.] 4.0 2.6 AMW-Sd 19-Dec-38 1.] 2.21 1.] 24A 0.]91 13.0 O.SL 5.2 3.1 AMW-ld 8, -19 1.6 2.6 22.1 1.3 18.9 6.] 3.0 Smith Page 8 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 AMW-2s 3-May-11 0.81 SO 81 2.5 5.4 AMW-2s 8-Nov-11 0.81 11 81 2.9 5 3.2 081 AMW-2s 8-May-12 0.81 12 31 2.J 5.8 3.8 0.91 AMW-2s 29-Nov-12 0.]1 12 91 2.2 6.4 4.1 0.81 AMW-2s 9-May-13 9 ]1 1.4 5.3. 0.AMW-2s 6-Nov-13 30 81 7�64 1.3 4.9 3.0.]J AMW-2s ]-May-14 0.51 12 1 1.2 4.6 3.3 0.51 AMW-2s5-Nov-14 12 4 0.91 5.5 4.2 0.611302-MSWLF-AMW-2s 6-May-15 9.3 .5 0.61 4.2 3.1 0.41CDLF-1998 AMW-2s 28-Oc[-15 6.4.] O.JI 3.3 2.6AMW-2s)dup) 28-Oc[-15 6.4 .9 O.JI 3.1 2.9 AMW-2s 1]-May-16 6.5 6.4 O.JI 3.5 3.0 AMW-21 1-Nov-16 30 0.81 8.0 0.9) 4.1 AMW-2s 10-May-1J B.0 6.3 0.6) 2.5 2.2 AMW-2, 1-Nov-17 B.J 0.71 7.5 1 2.9 AMW-2s 8-Jun-18 3.4 6.3 5.9 1.5 1.] AMW-2s 20-Dec-18 5.5 5.3 1.8 1.8 AMW-2s ]-May-19 B.J 9.6 0.741 2.6 3.1 AMW-2d 3-May-11 5.6 0.91 1.41 2 4.0 2.3 1.4 AMW-2d 8-Nov-11 B.8 D 1.91 1.2 6.5 2.8 1.3 AMW-2d &May-12 9.7 D 2J 1 6.1 3.1 1.1 AMW-2d 2&Nw-12 11 1.21 2.5J 6.6 3.2 0.11 AMW-2d &May-13 12 1.21 4.61 1.1 J.8 9 1.2 AMW-2d 6-Nov-13 9.4 0.61 9.1 O.J1 2.9 1.9 0..6 AMW-2d 7-May-14 0.1J 6.J 2 .4 5.6 14 1302-MSWLF AMW-2d 5-No14 4.J 4.2 0.91 CDLF-1998 AMW-2d &May-15 19 1.51 8.4 1.3 9.8 6.3 0.81 AMW-2d 2&Oc[-15 14 0.81 6.3 1.3 4.3 3.7 0.61 AMW-2d 1]-May-16 0.51 0.31 IJ 1.01 9.2 1.3 J.6 5.2 0.]1 AMW-2d 2-Nov-16 0.41 0.51 5.0 6.2 2.0 1.2 AMW-2d 10-May-17 22 13 J.9 6.6 AMW-2d 2-Nov-1J 0.61 1.5J 2J 2.61 19 B.J B.J 0.61 AMW-2d &Jun-18 0.281 0.]2J 20.1 1.51 15.3 4.5 5.9 AMW-2d 2&Dec-18 0.]]1 0.721 1.0 33.3 1].8 4.2 6.8 AMW-2d ]-May-19 18.2J 0.9]1 0.651 8k 0.81J 13.5 3.1 3.9 MW-1 3-May-11 O.JI MW-1 8-Nov-11 0.41 MW-1 &May-12 0.41 0.71 MW-1 27-Nov-12 0.41 0.81 MW-1 &May-13 MW-1 5-Nov-13 1.01 0.41 MW-1 ]-May-14 0.41 0.41 2.41 0.91 0.51 0.41 MW-1(dup) 7-May-14 0.3J 0.41 2.41 0.91 0.51 0.4) MW-1 3-Nov-14 1.31 0.41 0.4) 1302-MSWLF- MW-1 5-May-15 0.41 1.11 0.41 CDLF-1998 MW-1 27-Oc[-15 0.51 MW-1 18-May-16 1.21 0.61 MW-1 1-Nov-16 1.01 MW-1 10-May-17 1.11 MW-1 31-Oc[-1J 1.11 MW-1 7-Jun-18 1.31 MW-1 (dup) 7-Jun-18 1.41 0.601 MW-1 1&Dec-18 1.91 0.741 MW-1 &May-19 1.9 1.41 0.381 MW-1 (dup) &May-19 1.9 0.]]1 MW-3 4-May-ll 7.4 1.41 0.81 1 4 1.1 MW-3 9-Nov-11 12 1.J1 1.81 O.JI 36 5.3 1.2 MW-3 Wp) 9-Nov-11 13 2J 1.81 O.J1 35 5.3 1.6 MW-3 &May-12 9.6 1.J1 1.21 0.5) V 5.4 1.3 MW-3 2&Nov-12 12 1.41 1.91 0.91 35 5.2 MW-3 &May-13 10 1.41 1.J1 0.61 38 S.J 1.1 MW-3 ]-Nov-13 12 1.51 1.J1 0.6) 35 5.1 1.0 MW-3 &May-14 35 2.01 2.61 O.J1 IJ 6.1 1.0 1302-MSWLF- MW-3 6-Nov-14 36 1.81 3.61 O.J1 38 J.4 1.2 CDLF-1998 MW-3 &May-15 14 0.81 3.11 0.6) IJ 5.9 0.91 MW-3 2&0c[-15 13 1.41 3.81 13 5.2 0.81 MW-3 I8-May-16 13 1.31 4.31 0.. 35 6.0 0.81 MW-3 2-Nov-16 14 2.41 4.81 0.61 14 1.7 1.2 MW-3 11-May-1J 13 1.31 4.01 0.61 13 5.8 0.91 MW-3 1-Nov-1J 0.81 36 2.l1 5.91 13 6.6 1.2 MW-3 7-Jun-18 35.6 2.31 5.] O.SL 6.3 5.7 0.831 MW-3 19-Dec-18 21.3 1.91 10.4 0.591 14.1 7.0 0.951 MW-3 &May-19 8.71 19.0 1.9 8.8 0.]21 11.9 6.5 0.801 MW-3 Deep 4May-11 0.51 MW-3 Deep &May-12 0.41 MW-3 Deep 10-May-13 a 0.61 0.4) MW-3 Deep &May-14 0.41 1302-MSWLF- MW-3 Deep &May-15 1.21 0.4) 0.41 CDLF-1998 MW-3 Deep 2&0c[-15 1.41 0.41 MW-3 Deep 19-May-16 1.21 MW-3 Deep ll-May-17 1.01 MW-3 Deep 7-Jun-18 1.41 MW-3 Deep &May-19 10.01 1.1 1302-MSWLF- MW-9 3-May-11 0.81 CDLF-1996 MW-9 9-Nov-11 1.1 MW-9 9-Ma -12 1.4 Smith Page 9 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-A 3-May-11 11 4.71 12 14 2.2 110 0.41 2.2 0.81 3.9 3.11 3.2 0.>l 9.2 la MW-A 9-Nov-11 1.41 6.51 16 16 2.6 120 0.61 2A 2 6.5 5.2 3.8 SJ MW-A 9-May-12 1.11 6.51 1] 16 3.8 0.51 130 0.41 2 0.91 6.5 2.61 0.5J 4.5 02J 1.1 MW-A 2J-Nov-12 9.3 1.61 6.91 15 25 3.9 0.61 130 0.51 2.2 0.41 0.51 4.] 1.]1 0.41 4.4 0.81 MW-A J-May-13 9.1 1.31 5.11 22 23 3 0 41 120 0.51 2A 0.61 0.81 6.2 0.31 8.0 4.3 MW-A 5-Nov-13 11 1.41 S.J1 0.41 25 22 4.1 130 1.4 6.2 6.0 3.8 1.0 MW-A 6-May-14 11 1.3J 5.61 0.31 26 16 3.6 0.21 120 0.41 2.2 0.]1 4.6 5.3 0.41 5.8 3.3 1.0 1302-MSWLF- MW-A 4-Nov-14 9.5 1.61 5.61 0.31 31 21 2.6 130 0.51 0.41 1.1 5.] 2.01 4.5 1.OJ CDLF-1998 MW-A 5-May-15 9.3 1.4J 5.0J 0.31 24 16 2.5 130 0.51 2.2 0.81 0.81 5.6 0.41 5.3 3.6 0.6J MW-A 2J-Oc[-15 9.1 1.4J 5.4J 28 15 2.3 Hoe 0.71 0.81 5.9 0.31 4.41 3.4 0.7J MW-A lJ-May-16 9.7 1.51 31 15 1.3 120 2.2 1.1 1.4 4.8 0.61 5.2 3.] 0.81 MW-A 1-Nov-16 11 1.6J 5.]1 36 V 1.6 140 0.5J 2.6 0.]1 1.4 5.] 4.]1 3.8 0.9J MW-A 9-May-1] 9.5 1.41 4.51 30 13 1.0 120 0.51 1.9 0.81 1.6 4.8 0.41 4.81 3.1 0.71 MW-A 31-Oc[-1] 12 1.41 4.41 35 15 1.J 11 2A 0.91 2.6 5.3 3.J MW-A J-Jun-18 8.3 4.5J 0.911 2.91 16.6 30.6 300 0.661 1.5 1.5 2.8 MW-A 20-Dec-18 11.0 1.41 4.21 20.3 13.3 1.] 133 0.521 2.1 3.1 2.61 2.8 MW-A 9-May-19 9.71 5.7 1.3 2.7 36.0 12.7 1.7 86.2 0 491 2A 0.49J 2.5 2.3 3.8 2.9 0.11J MW-B 3-May-11 MW-B 8-Nov-11 MW-B 8-May-12 MW-B 28-Nov-12 0.91 MW-B 9-May-13 MW-B 5-Nov-13 MW-B 7-May-14 1302-MSWLF- MW-B 3-Nov-14 CDLF-1998 MW-B 5-May-15 MW-B 28-0c[-15 MW-B 18-May-16 MW-B 2-Nov-16 MW-B 10-May-17 MW-B 31-0c[-17 MW-B 6-Jun-18 MW-B 1&Dec-18 0.531 MW-B B-May-19 4.01 MW-C 3-May-11 MW-C 8-Nov-11 1.41 MW-C B-May-12 MW-C 28-Nm-12 0.61 0.51 MW-C B-May-13 MW-C 5-Nov-13 11 MW-C 6-May-14 1302-MSWLF- MW-C 4-Nov-14 0.3J 4.61 CDLF-1998 MW-C &May-15 MW-C 28-0c[-15 0.71 MW-C 17-May-16 MW-C 1-Nov-16 MW-C 9-May-1] MW-C 1-Nov-17 MW-C 7-Jun-18 MW-C 19-Dec-18 O.671 MW-C &M2y-19 ].1J MW-D 3-May-11 5.5 3.]J 1.9 1.91 3] O.IJ 1.61 5.5 0.81 MW-D 8-Nov-11 5.] 3.JJ 2.9 1.81 5] 0.41 O.J1 0.91 1.51 3.9 0.91 MW-D &May-12 J 0.31 2.71 1.31 56 1 1J 1.Jl 5.3 0.8J MW-D 2]-Nw-12 6.5 0.31 1.L 6. 1.31 54 1.5 0.7J 0.21 5.3 4.0 0.61 MW-D &May-13 6.8 0.41 1.61 8.4 1.21 56 0.81 2.2 2.J1 5.9 0.71 MW-D 5-Nov-13 J.2 0.51 1.81 9.3 1.01 SJ 0.81 1.81 4.6 0.9J MW-D &May-14 5.1 0.41 1.11 7.1 0.]1 39 3.31 3.9 0.61 1302-MSWLF- MW-D 4-Nov-14 6.9 0.51 0.91 10 0.91 53 0M 0.41 1.51 4.1 0.61 CDLF-1998 MW-D 5-May-15 5.9 0.61 1.3 0.51 38 0.21 1.81 0.5J MW-D 28-0c[-15 5.3 0.91 B.1 0.51 37 1.51 2.7 0.61 MW-D 17-May-16 5.0 0.7J 9.9 39 1.Jl 2.8 MW-D 2-Nov-16 6.5 0.81 1.31 12 0.51 48 3.21 1.6 1.1 MW-D 9-May-1] 5.1 0.91 8.8 35 2.5 0.81 MW-D 1-Nov-lJ 5.9 0.81 1.51 30 0.41 41 3.91 2.3 MW-D 7-Jun-18 SA 0.931 10.1 31.1 0.621 2.6 MW-D 19-Dec-18 2.] 0.]21 0.691 10.9 0.411 30.5 1.6 0.801 MW-D 9-May-19 4.2 1.0 1.1 9.1 23.4 1.3 MW-E Rep 4-May-11 6 2.51 4.51 14 20 1J 15 0.91 11 3.6 6.3 MW-E Rep 8-Nov-11 3.3 0.J1 2.11 4.21 11 20 0.81 54 0.81 1.1 2.2 5 MW-E Rep &May-12 2.5 2.41 5.71 13 33 1.1 47 0.91 1.1 0.41 0.31 1.8 6.6 MW-E Rep &May-13 1.3 2.J81 3.71 14 19 0.J1 21 0.J1 1.2 0.51 C.4 MW-E Rep 5-Nov-13 2.3 3.2 3.]1 36 19 1.2 41 O.J1 1.0 7.6 MW-E Rep &May-14 2.9 3.2 2.91 36 3q 1.0 53 0.]1 1.0 0.21 1.4 9.3 MW-E Rep 4-Nov-14 1.5 4.1 3.61 36 35 1.1 43 0.J1 1.0 7.5 1302-MSWLF- MW-E Rep 5-May-15 3AJ 0.81 3.1 4.21 0.31 IS B.8 1., 25 0.41 1.1 0.51 3.8 CDLF-1998 MW-E Rep 2]-Oc[-15 1.IL 3.9 5.11 0.31 . 9.0 1.1 2] 0.41 0.6) 4.3 MW-E Rep 18-May-16 0.81 2.31 J.61 8.2 0.9J 12 3.2 MW-E Rep 1-Nov-16 0.61 3.2 8.01 35 11 1.1 IB 0.51 4.5 MW-E Rep 9-May-1] 0.]1 3.0 6.21 34 5.9 0.71 IB 0.51 3.5 MW-E Rep 31-0c[-1] 0.61 3.1 8.21 35 5 1.2 21 4.4 MW-E Rep 114 -18 O.J3J 2.81 6.51 10.0 2.51 I6.J 2.9 MW-E Rep 24Dec-18 0.661 3.8 6.31 12.3 2.61 22.1 0.531 2.0 3.6 MW-E Re ]-Ma -19 0.J61 4.2 5.3 16.9 2.8 28.3 0.70J 0.63J 2.5 .0 Smith Page 10 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-EDeep 4-May-11 1.9 11 3.9 IIMIRII 32 0.91 D 0.51 1.1 1.8 MW-EDeep 8-Nov-11 1.5 0.61 9.51 3.9 34 0.81 1.11 0.61 1.3 1.3 MW-EDeep 8-May-12 1 0.51 12 4.3 29 0.91 0.41 0.51 1.2 0.31 0.61 MW-EDeep 2]-Nov-12 0.91 1.21 14 4.5 30 0.91 1.01 0.41 1.1 0.41 0.91 MW-E Deep 8-May-13 0.81 0.]1 6.81 4.1 30 0.81 0.51 1.3 0.41 0.51 MW-E Deep 6-Nov-13 1.2 0.8J 12 5.1 26 0.]1 0.41 1.2 MW-E Deep 6-May-14 851 2.L 181 151 1.0J 9.5J 9.3 8.9 0.81 2.01 0.]l 101 1.1 3.11 OAl 1302-MSWLF- MW-E Deep 4-Nov-14 181 0.71 4.3J 5.41 0.9J 17 4A 10 0.61 0.31 3.4 1.01 CDLF-1998 MW-E Deep 5-May-15 0.]1 I u 14 5.9 8.5 0.]1 1.9 1.41 MW-EDeep 2]-Oc[-15 0.41 0.91 16 4.9 ].0 0.61 0.81 1.01 MW-EDeep 18-May-16 0.41 0.81 11 4.2 1.01 0.51 0.51 0.51 0.81 MW-EDeep 1-Nov-16 0.61 l.11 26 5.9 1.]l 0.81 0.11 4.81 MW-EDeep 9-May-1] 1.]I l.11 19 6.1 O 1 0.]1 MW-EDeep 1-Nov-1] 0.81 1.21 26 ].4 1.0 0.]1 3.61 MW-EDeep 114 -18 0.611 63 0.921 19.0 3.8 4.1 0.5]l MW-EDeep 20-Dec-18 1.3 1.5J 13.5 1.4 0.941 0.611 2.31 0.351 MW-EDeep 8-May-19 2.4 1.2 5.9 1.4 0.44J MW-F 3-May-11 MW-F 8-Nov-11 MW-F &May-12 MW-F 2&Nov-12 0.61 MW-F &May-13 MW-F 5-Nov-13 MW-F 7-May-14 MW-F 3-Nov-14 1302-M5WLF- MW-F 5-May-15 3.11 CDLF-1998 MW-F 2]-0c[-15 0.1J MW-F 17-May-16 MW-F 2-Nov-16 0.61 MW-F 10-May-17 MW-F 31-0c[-1] MW-F 6-Jun-18 MW-F 19-Dec-18 MW-F)dup) 1&Dec-18 0.801 MW-F &May-19 MW-G 3-May-11 0.61 1.61 MW-G 8-Nov-11 1.5 2.11 MW-G &May-12 0.61 1.11 0.31 MW-G 2&Nov-12 1.61 1.1 0.71 MW-G &May-13 2.81 0.51 1.61 MW-G 5-Nov-13 3.11 2.3J 0.911.5 0.41 MW-G ]-May-14 0.21 2.41 0.81 0.41 1.4 0.51 MW-G 3-Nov-14 0.31 2.61 1.01 0.51 2.0 0.61 0.41 1302-MSWLF- MW-G 5-May-15 0.21 2.41 0.4J 1.9 0.51 CDLF-1998 MW-G 2]-0c[-15 1.0 5.5 0.61 2.9 MW-G 19-May-16 0.21 2.21 0.]J 1.4 0.61 MW-G Wp) 19-May-16 0.21 2.11 1.3 0.51 MW-G 2-Nov-16 0.61 5.6 1.21 0.]1 3.4 0.61 MW-G 10-May-1] 2.31 1.3 0.41 MW-G 1-Nov-17 0.41 4.2 1.1J 0.6J 2.3 0.71 MW-G bJun-18 3.1 0.851 MW-G 19-Dec-18 8.2 2.3J 13.3 MW-G &May-19 0.251 3.9 0.801 1.5 0.931 83.9 1.51 MW-H 4-May-11 MW-H 8-Nov-11 MW-H &May-12 MW-H 2&Nov-12 0.71 MW-H &May-13 MW-H 7-Nov-13 MW-H 7-May-14 1302-MSWLF- MW-H 5-Nov-14 CDLF-1998 MW-H 5-May-15 MW-H 2&0c[-15 MW-H 18-May-16 2.71 MW-H 2-Nov-16 MW-H 10-May-1] MW-H 1-Nov-17 MW-H ]-Jun-18 MW-H 19-Dec-18 MW-H &May-19 1.41 MW-H Deep 4-May-11 MW-H Deep 8-Nov-11 MW-H Deep &May-12 MW-H Deep 2&Nov-12 0.41 MW-H Deep &May-13 MW-H Deep (dup) &May-13 MW-H Deep ]-Nov-13 MW-H Deep 7-May-14 MW-H Deep 5-Nov-14 1302-M5WLF- MW-H Deep (dup) 5-Nov-14 CDLI1998 MW-H Deep 5-May-15 MW-H Deep (dup) 5-May-15 MW-H Deep 2&0c[-15 MW-H Deep 18-May-16 MW-H Deep 2-Nov-16 MW-H Deep 10-May-17 MW-H Deep 1-Nov-17 MW-H Deep 7-Jun-18 0.511 MW-H Deep 19-Dec-18 0.94J MW-H D,,p &Ma -19 0.521 Smith Page 11 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 MW-I 4-May-11 0.81 2.9 1.3 0.11 MW-I 8-Nov-11 101 3.51 0.81 2.5 1 0.61 MW-I 8-May-12 3.31 0.21 0.81 041 2.8 1.1 0.]1 MW-I (dup) 8-May-12 3.31 0.31 0.91 041 2.6 1.1 0.11 MW-I 2]-Nov-12 4.01 0.31 0.91 1.2 2.4 1.1 MW-I &May-13 74J 3.61 1.31 0.41 2.8 1.4 0.61 MW-I ]-Nov-13 3.91 1.31 0.41 2.8 1.4 0.61 MW-I &May-14 4.]1 0.21 1.41 2.9 1.4 0.61 1302-MSWLF- MW-I 4-Nov-14 4.91 0.41 1.]1 3.4 1.] 0.61 CDLF-1998 MW-I 5-May-15 4.41 1.41 0.41 3.1 1.5 0.61 MW-I 28-Oc[-15 4.61 1.91 3.2 1.5 0.51 MW-I 18-May-16 3.91 1.81 2.9 1.5 0.51 2.91 MW-I 2-Nov-16 4.61 1.01 2.01 0.61 3.5 1.3 0.81 MW-I 10-May-17 4.31 2.11 0.51 2.9 1.6 0.61 MW-I 31-Oc[-1] 5.5 2.]1 3.0 2.0 0.]1 MW-I ]-Jun-18 5.] 1.11 3.61 1.0 1.8 1.] MW-I 1&Dec-18 5.2 1.1 3.3 2.1 MW-I &May-19 4.5 0.61J 3.6 2.4 MW-J 3-May-11 MW-1 8-Nov-11 MW-1 &May-12 MW-1 2&Nov-12 0.81 MW-1 7-May-13 MW-1 5-Nov-13 MW-1 6-May-14 1302-MSWLF- MW-1 4-Nov-14 CDLF-1998 MW-1 6-May-15 MW-1 2]-0c[-15 MW-1 17-May-16 MW-1 1-Nov-16 MW-1 9-May-17 MW-1 1-Nov-17 MW-1 7-Jun-18 0.651 MW-1 1&Dec-18 MW-1 &May-19 MW-K 3-Nov-30 0.]I MW-K 3-May-11 0.61 MW-K 8-Nov-11 5.11 L MW-K &May-12 0.41 MW-K 2]-Nov-12 1.61 0.31 0.7I 0.31 0.31 MW-K 7-May-13 1.31 0.4) MW-K 5-Nov-13 MW-K &May-14 0.51 1302-MSWLF- MW-K 4-Nov-14 1.11 0.51 CDLF-1998 MW-K 5-May-15 0.61 MW-K 2&0c[-15 1.41 0.81 0.41 MW-K 1]-May-16 MW-K 1-Nov-16 0.61 0.61 MW-K (dup) 1-Nov-16 0.51 0.91 0.61 MW-K 9-May-17 8.61 MW-K 1-Nov-17 MW-K 7-Jun-18 0.131 MW-K 1&Dec-18 MW-K &May-19 MW-L 4-May-11 MW-L 9-Nov-11 MW-L &May-12 MW-L 2&Nov-12 1.01 1.11 1.2 2.4 MW-L &May-13 MW-L 7-Nov-13 MW-L &May-14 1302-MSWLF- MW-L 5-Nov-14 CDLF-1998 MW-L &May-15 MW-L 2&0c[-15 MW-L19-May-16 2-Nov-16 ZL L 10-May-17 MW-L 1-Nov-17 D.BJ 0.41 MW-L ]-Jun-18 0.561 MW-L 19-Dec-18 MW-L &May-19 MW-LDeep 4-May-11 1.41 1.21 O.JJ 13 1.6 MW-L Deep &May-12 5.8 0.41 0.61 0.41 1.4 1.2 0.61 MW-L Deep 9-May-13 1.21 1.81 0.91 36 1.5 MW-L Deep &May-14 o. 0.51 0.81 2.2 1.7 0.41 1302-MSWLF- MW-L Deep &May-15 5.6 0.51 0.61 0.41 3.5 1.8 0.61 CDLI1998 MW-L Deep 29-0c[-15 4.61 0.61 2.2 1.5 0.51 MW-L Deep 19-May-16 3.21 2.0 0.91 MWADeep 10-May-1] 3.81 2.1 1.0 MWA Deep(dup) 10-May-17 3.11 2.7 1.1 MW-L Deep 7-Jun-18 0.971 5.3 1.0 0.381 MW-L Deep &May-19 5.4 3.3 1.0 0.651 MW-M 4-May-" 0.41 MW-M &May-12 0.91 0.31 MW-M 9-May-130.51 MW-M &May-14 1.11 1302-MSWLF- MW-M 5-May-15 1.01 0.41 CDLI1998 MW-M 2&0c[-15 0.91 MW-M 17-May-16 0.81 MW-M 9-May-17 0.61 MW-M 7-Jun-18 0.641 0.531 MW-M 9-Ma -19 1.2 2.2 0.381 Smith Page 12 of 18 June 2019 Table 5b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 Notes: 1. All units are in micrograms per liter (parts per billion). 2. Monitoring wells MW-3 Deep, ADeep, -and -M are sampled annually during the spring event. 3.1-Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 4. B - Indicates constituent was detected in the batch blank above the method detection limit. 5. (dup) - Duplicate 6. The November 2012 sampling event was the first event that CD-1s/CD-Id replaced MW-9 as the background monitoring wells. 7. MW-9 was removed from the monitoring program in November 2012. g. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. 9. CD-6 was abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill expansion. Concentration exceeds the 15A NCAC 02L.0202 (North Carolina 2L) Standard - Indicates the result is below the detection limit. Smith Page 13 of 18 June 2019 Table Sc Detected Surface Water Constituents - Volatile Organic Compounds and Metals May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 SW-1 5-May-11 0.0002J 0.07181 0.00121 0.003811 0.00115J 0.006231 0.002481 0.00369.1 SW-1 9-Nov-11 0.094J 0.000771 0.00261 0.000231 0.005321 0.001741 SW-1 30-May-13 0.08211 0.00006J 0.003791 0.00201J 0.00016J 0.00631 0.002051 0.004931 SW-1 5-Nov-13 0.00106J 0.139 0.009521 0.00175J 0.00009J 0.008511 0.002851 0.000121 0.007551B 0.00938JB 21 0.3J SW-1 5-May-14 0.00180J 0.146 0.000371 0.004631B 0.00117 0.00634J 0.003581E 0.009791 0.002831 0.01441 0.0343 SW-1 5-May-15 1302-MSWLF- SW-1 29-Oct-15 0.00089J 0.06921 0.001011 0.00172J 0.005091 0.00439J 0.00293CN,J 0.002371 CDLF-1998 SW-1 19-May-16 0.00352J 0.157 0.00144 0.0372 0.0156 0.0251 0.0148 0.01721 0.005331 0.000081 0.0652 SW-1 3-Nov-16 DRY DRY SW-1 30-May-17 0.06661 0.003691 0.002041 0.00104.11 0.000071 1 0.005921 SW-1 30-Oct-17 DRY DRY SW-1 6-Jun-18 DRY DRY SW-1 18-Dec-18 0.000701 0.05761 0.0000521 0.0018.1 0.00261 0.0020J 0.00034J 0.00441 0.0032.1 0.0049.1 4.4 2.1 SW-1 9-May-19 0.0669 0.000761 0.00301 0.00131 0.000161 0.0051 0.00131 0.00391 8.7 SW-2 5-May-11 0.000191 0.0911 0.000181 0.0025E 0.004251 0.0034.1 0.0013JB 0.006261 0.003881 0.003841 0.006391 SW-2 9-May-12 0.06531 0.001061 0.000881 0.001681 0.00085.1 0.003331 0.00133J 0.003011 0.00267J,B SW-2 10-May-13 0.000971 0.07891 0.000631 0.002531 0.00221 0.00084.1 0.006361 0.00302J 0.006051 SW-2 6-May-14 0.001451 0.137 0.000051 0.003291 0.003651 0.001521B 0.006991 0.00368J 0.007111 0.0245 SW-2 3-Nov-14 0.001881 0.067J 0.0127 0.000571 0.000051 0.00142J 0.00108J 0.00515JB 6.01 2 SW-2 5-May-15 0.00732JB 0.003161 0.00121J 0.00634J 0.00340J 0.001361 1302-MSWLF- SW-2 29-Oct-15 0.001681 0.08111 0.000101 0.000691 0.00364J 0.00095.1 0.00460J 0.00650J 0.00328CN,1 0.00193.1 0.00548J CDLF-1998 SW-2 19-May-16 0.002351 0.08901 0.000941 0.0122 0.007211 0.0119 1 0.00873.1 0.00833J 0.00340J 0.0327 0.0350 SW-2 3-Nov-16 DRY DRY SW-2 10-May-17 0.09471 0.002221 0.000891 0.0003E 0.00481J 0.00174.1 SW-2 30-Oct-17 DRY DRY SW-2 6-Jun-18 0.00099J 0.0429J 0.00141 0.000371 0.00251 SW-2 18-Dec-18 0.00063J 0.071. 0.000111 0.0019J 0.00181 0.00191 0.000911 0.003E 0.0043.1 0.0036.1 2.5 1.8 SW-2 9-Mav-19 0.0838 0.00231 0.00171 0.0051 0.00281 7.3 Notes: 1. All units for metals are in milligrams per liter (parts per million). All untis for volatile organic compounds are in micrograms per liter (parts per billion). 2. Standards obtained from 15A NCAC 02B .0211 (North Carolina 2B) or Protective Value Surface Water quality Standards for Class C Waters - September 2017. 3. Isl -A Standard for total chromium has not been established. The value provided is for chromium (III). 4.' - North Carolina Protective Value S. NS - No Standard 6.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 7. B - Indicates constituent was detected in the batch blank above the method detection limit. 8. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used. 9. SW-1 was dry during the Fall 2007, Fall 2009, Spring 2010, Fall 2011, Spring 2012, Fall 2012, Fall 2014, Spring 2015, and Fall 2016 sampling events. 10. SW-2 was dry during the Fall 2009, Spring 2010, Fall 2010, Fall 2011, Fall 2012, Fall 2013, and Fall 2016 sampling events. Concentration exceeds North Carolina Freshwater Aquatic Life Standard for Class C Waters. - Indicates the result is below the detection limit. Smith Page 14 of 18 June2019 Table Sd Geochemical Constituents in Groundwater May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 1302-MSWLF- MW-9 3-May-11 3.45 139 <0.010 0.004 1.7 0.088 <0.05 <0.1 <0.05 <0.05 <0.15 0.14 <0.07 0.1 <0.15 0.65 37 50 <0.5 <6 1.3 0.161 0.0911 0.411 <0.6 3.1 CDLF-1998 MW-9 9-Nov-11 4.70 212 0.062 0.078 3.5 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.033 <0.07 <0.05 <0.15 1.4 53 35 <2 11 1.3 0.91H 0.094J 0.261 <1 0.4B MW-9 9-May-1 1.82 127 0.11 0.012 6.7 0.038 <0.05 0.051 <0.05 <0.05 <0.15 0.086 <0.07 <0.05 <0.15 2.8 41 36 <0.002 <10 1.6 <0.2H 0.1801 <5 <0.2 0.484 CD-ls 3-May-11 47 3.6 1.21 CD-ls 8-Nov-11 40 4 1.11 CD-ls 7-May-12 46 3.9 CD-ls 27-Nov-12 15.56 139 <0.025 0.019 1.1 <0.07 0.029 0.019 <0.30 <0.05 <0.15 <0.30 <0.07 <0.05 <0.15 0.94 54 39 <2 <10 4.1 0 0.061 <5 <0.2 <1 CD-ls 7-May-13 1.96 206 0.21 0.14 3.8 <0.07 <0.05 0.062 <0.30 <0.05 <0.15 0.055 <0.07 <0.05 <0.15 0.82 30 42 <2 0.64 4 0.22 0.066J <5 <0.2 <1 CD-ls 5-Nov-13 1.74 348 0.0033 0.0037 0.33 0.034 0.056 <0.5 <0.1 <0.15 0.20 <0.07 <0.05 <0.15 0.74 15 30 <2 <10 3.8 2.42 0.082J <5 <0.2 <1 CD-1s 6-May-14 0.02 353 0.0032 0.010 3.4 0.037 <0.05 <0.5 <0.1 <0.15 <0.30 <0.07 <0.05 <0.15 0.94 54 42 <2 <10 3.8 0 0.077J <5 <0.2 1.07 1302-MSWLF- CD-ls 4-Nov-14 6.06 135 0.0061 0.011 1.8 0.041 <0.05 <0.5 <0.2 <0.15 0.037 <0.07 0.052 <0.15 1.7 62 41 <2 <10 3.9 0 0.065J <5 <0.2 <1 CDLF-1998 CD-1s 5-May-15 3.99 281 0.0034 0.016 0.060 0.081 <0.05 0.10 <0.5 <0.2 <0.15 0.019 <0.07 <0.05 0.034 26 42 38 <2 <10 3.8 0 0.120J <5 <0.2 3.48 CD-1s 27-Oct-15 3.84 519 <0.30 0.012 0.12 0.036 0.0094 0.03 <0.20 <0.20 <0.10 <0.20 <0.30 0.0024 <0.30 40 61 43 <2 30.6 3.8 0 0.130J <5 <0.2 <1 CD-ls 17-May-16 3.45 245 <0.30 <0.10 0.048 0.020 <0.10 0.045 <0.20 <0.20 <0.10 0.011 <0.30 <0.30 <0.30 22 46 43 <2 <10 3.7 0 0.079J 1 <0.2 <1 CD-ls 1-Nov-16 4.49 360.2 0.0031 0.0099 0.84 0.038 0.0076 0.059 <0.20 <0.20 <0.10 0.0090 <0.30 <0.30 <0.30 3.1 60 46 <2 26.5 4.2 0 0.067J,H-02 <5 <0.2 <1 CD-1s 9-May-17 1.69 274.6 0.0035 0.0026 0.50 0.035 <0.10 0.038 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 7.8 48 49 <2 <10 3.6 0 0.076J 1.31 <0.2 <1 CD-ls 31-Oct-17 1.87 58 <0.10 <0.10 0.18J <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 14 58 50 <2 14.6 4.2 0 0.066 1.01 <0.2 <1 CD-ls 11-Jun-18 3.8 124.1 0.036J 0.0311 15.00 0.031J <0.10 <0.20 <0.20 <0.20 <0.10 0.021J 0.0531 <0.30 <0.30 6.4 44 49 <2 <10 3.89 0 0.0820 0.9041 <0.2 <1 CD-1s 17-Dec-18 5.6 38.6 <0.10 <0.10 3.50 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 420 46 46 <2 <10 3.72 0 0.146 0.9911 <0.2 <1 CD-15 7-May-19 1 5.26 1 242.4 <0.0050 1 <0.0040 1 0.0531 0.032J I <0.011 0.171 <0.030 1 <0.029 <0.0060 1 <0.043 <0.0070 1 <0.0040 1 <0.0050 2.5 1 50 1 43 <2 1 <10 1 2.93 0 1 0.359 1 12.6 <0.2 <1 CD-ld 3-May-11 57 2.6 31 CD-ld 8- Nov-1 30 2.9 31 CD-ld 7-May-12 50 2.8 <5 CD-ld 27-Nov-12 9.53 140 46 3 0 0.071 <5 CD-ld 7-May-13 1.11 242 0.015 0.015 0.31 0.021 <0.05 0.052 <0.30 <0.05 <0.15 0.06 <0.07 <0.05 <0.15 0.61 40 52 4 6.05 3 0.56 0.069J <5 <0.2 1.42 CD-ld 5-Nov-13 1.71 320.1 42 3 <5 CD-ld 6-May-14 4.56 293 46 2.9 0.077J <5 1302-MSWLF- CD-ld 4-Nov-14 4.68 108.7 43 3.1 0 <5 CD-ld 5-May-15 4.84 186 44 2.9 0 0.086J <5 CDLF-1998 CD-ld 27-Oct-15 4.30 507 46 2.9 0 <5 CD-ld 17-May-16 4.50 210 96 18.0 0 <0.05 14 CD-ld 1-Nov-16 3.10 330 52 3.4 0 <5 CD-ld 9-May-10 1.51 257.2 53 2.8 0 3.71 CD-ld 31-0ct-17 2.85 37 52 3.3 0 0.0791 3.31 CD-ld 12-Jun-18 2.9 54.2 51 3.2 0 3.331 CD-ld 17-Dec-18 3.6 25.1 53 3.11 0 3.361 CD-1d 7-May-19 1.61 183.2 52 2.84 0 0.0808 3.141 AMW-1s 3- May-1 1.22 176 0.007 0.004 810 0.57 <0.05 <0.1 <0.05 <0.05 <0.15 0.13 <0.07 0.63 <0.15 1 250 114 <0.5 <6 3.2 0.13J <0.006 0.361 <0.6 1 AMW-1s 8-Nov-11 0.17 12 0.031 0.068 1,100 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.08 <0.07 <0.05 <0.15 1.1 320 95 3 9 3.1 <0.2 <0.05 0.261 <1 0.7B AMW-1s 7-May-12 0.02 121 0.043 0.047 1,300 0.061 <0.05 0.055 <0.05 <0.05 <0.15 0.089 <0.07 <0.05 <0.15 82 300 105 <0.002 <10 3.2 <0.2H <0.004 <0.18 <0.2 0.524 AMW-1s 28-Nov-12 3.81 44 0.064 0.031 1,000 <0.07 <0.05 0.036 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 1.1 280 92 <2 <10 3.1 0.3 <0.05 <5 <0.2 <1 AMW-ls 8-May-13 0.34 523 0.11 0.054 1,600 0.029 <0.05 0.064 <0.10 <0.05 <0.15 0.073 <0.07 <0.05 <0.15 0.19 210 87 <2 14.4 3.5 0.11 <0.05 <5 <0.2 <1 AMW-ls 6-Nov-13 1.05 149 0.11 <0.025 1,400 0.041 0.061 <0.5 <0.1 <0.15 0.15 <0.07 0.015 <0.15 0.85 270 107 <2 <10 3.6 0.34 <0.05 <5 <0.2 <1 AMW-1s 7-May-14 0.02 400 0.095 <0.025 1,200 0.054 <0.05 <0.5 <0.1 <0.15 0.026 <0.07 0.036 <0.15 0.86 280 105 <2 <10 3.4 0 <0.05 <5 <0.2 <1 1302-MSWLF- AMW-ls 5-Nov-14 3.25 132.2 0.15 0.015 1,000 0.055 <0.05 <0.5 <0.2 <0.15 0.031 <0.07 0.053 <0.15 1.7 280 120 <2 <10 3.7 0 <0.05 <5 <0.2 <1 CDLF-1998 AMW-ls 7-May-15 2.00 592 0.2 0.0073 1,600 <0.07 <0.05 0.11 <0.5 <0.2 <0.15 0.031 <0.07 <0.05 <0.15 12 310 96 <2 <10 3.5 0 <0.5 <5 <0.2 <1 AMW-1s 29-Oct-15 2.68 253 0.21 0.0064 1,100 0.021 0.0012 0.036 <0.20 <0.20 <0.10 0.0094 <0.10 0.0022 <0.10 8.2 300 10.5 <2 <10 3.7 0 <0.05 0.221 <0.2 <1 AMW-ls 18-May-16 3.77 222 0.17 <0.10 1,000 0.015 <0.10 0.030 <0.20 <0.20 <0.10 0.0072 0.012 <0.10 <0.10 1.5 210 85 <2 <10 3.8 0 <0.05 <5 <0.2 1.44 AMW-1s 2-Nov-16 1.65 377.2 0.13 0.0064 820 0.044 <0.10 0.048 <0.20 <0.20 <0.10 0.0092 <0.10 <0.10 <0.10 6 270 100 <2 23.6 3.3 0 <0.05 <5 <0.2 <1 AMW-ls 10-May-17 1.54 148.6 0.25 0.0046 1,400 0.062 <0.10 0.047 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.0 280 121 <2 25.1 4.2 0 <0.05 0.231 <0.2 <1 AMW-11 1-Nov-17 2.39 227 0.097J 0.0301 600 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 3.1 200 93 <2 <10 3.5 0 <0.05 0.421 <0.2 <1 AMW-ls 8-Jun-18 0.5 566.1 0.14 <0.10 1,200 0.038J <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 0.0601 <0.10 <0.10 5A 280 383 <2 <10 2.99 0 <0.0500 <0.5 <0.2 <1 AMW-ls 19-Dec-18 0.7 510.5 0.24 <0.10 1,600 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 5.6 260 115 2.28 <10 3.51 0 0.03601 0.291J <0.2 <1 AMW-ls 8-May-19 1.80 90.3 0.21 <0.0040 1,300 <0.025 <0.0070 0.131 <0.032 <0.011 <0.0050 <0.048 <0.011 <0.0020 <0.0050 1.6 230 92 Q <10 3.92 0 0.137 1 0.3361 1 <0.2 1 <1 Smith Page 15 of 18 June 2019 Table Sd Geochemical Constituents in Groundwater May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 E do o o o E wE It 10 . AMW-1d 3-May-11 0.01 89 0.059 0.71 1,100 0.11 <0.05 <0.1 <0.05 <0.05 <0.15 <0.1 <0.07 0.29 <0.15 0.89 170 295 1.8 <6 7.3 0.14J <0.006 31J 3 1.3 AMW-ld 8-Nov-11 0.00 -112 0.18 1.4 2,900 01.23 <0.05 <0.1 <0.05 <0.05 <0.15 0.2 <0.07 <0.05 <0.15 0.89 280 320 4 19 6.8 1 <0.05 27J <1 4.6 AMW-ld 7-May-12 0.24 95 0.17 1.7 2,500 0.097 <0.05 0.058 <0.05 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 480 270 230 6 <10 6.6 1.91H 0.0061 151 <0.2 4.11 AMW-ld 28-Nov-12 7.00 169 0.15 1.8 2,000 1.9 <0.05 0.039 <0.10 <0.05 <0.15 <0.10 <0.07 0.039 <0.15 0.511 240 265 4 30.2 6.4 1.8 <0.05 9.21 0.434J 3.02 AMW-1d 8-May-13 0.46 -53 0.32 1.6 3,800 0.054 <0.05 0.079 <0.10 <0.05 <0.15 0.089 <0.07 0.028 <0.15 1 300 375 4 8.99 7.1 3.3 <0.05 12J <0.2 4.95 AMW-1d 6-Nov-13 1.40 -22.7 0.28 1.1 3,400 0.033 0.066 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.96 290 315 <2 19.7 5.6 2.91 <0.05 6.41 <0.2 3.4 AMW-ld 7-May-14 2.05 -28 0.32 0.82 3,700 0.082 <0.05 <0.5 <0.1 <0.15 0.047 <0.07 0.032 <0.15 1.3 330 230 2 <10 5.6 5 <0.05 <5 <0.2 2.16 1302-MSWLF- AMW-1d 5-Nov-14 1.36 -67.7 0.33 1.3 3,000 0.34 <0.05 <0.5 <0.2 <0.15 0.042 <0.07 0.077 <0.15 2.0 320 375 2 44.9 5.4 4.0 <0.05 <5 0.241J 2.15 CDLF-1998 AMW-ld 7-May-15 1.78 -52 0.5 2.2 3,400 0.15 <0.05 0.11 <0.5 <0.2 <0.15 0.014 <0.07 <0.05 0.035 7.3 320 230 2 35.2 5.4 2.0 <0.5 <5 <0.2 3.41 AMW-1d 29-0ct-15 2.55 -42 0.79 4.0 4,000 0.27 0.0061 0.038 <0.20 <0.20 <0.10 0.011 <0.30 0.0050 <0.30 8.2 330 255 9BOD-3 <10 5.5 2.5 <0.05 <5 <0.2 2.67 AMW-1d 18-May-16 1.51 -28 2 2.2 3,700 0.021 <0.10 0.040 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 1.8 300 225 <2 13.2 5.9 3.0 <0.05 <5 <0.2 2.93 AMW-ld 3-Nov-16 1.73 199.2 2.2 3.4 3,900 0.045 <0.10 0.054 <0.20 <0.20 <0.10 0.0083 <0.30 <0.30 <0.30 19.0 350 215 10 41.6 5.9 2.0 <0.05 <5 <0.2 3.42 AMW-1d 10-May-17 1.59 -6.7 3.9 2.2 3,700 0.047 <0.10 0.046 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 2.5 280 225 10 29.6 6.1 7.0 <0.05 0.065J <0.2 2.27 AMW-ld 1-Nov-17 3.51 159 3.6 1.6 4,000 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 2.9 280 230 <2 20.0 6.3 3.0 <0.05 0.471 <0.2 2.64 AMW-ld 8-Jun-18 3.2 21.3 1.3 0.75 1,900 0.043J <0.10 0.071J <0.20 <0.20 <0.10 <0.20 0.052J <0.30 <0.30 1.7 260 223 <2 <10 5.26 0 <0.0500 0.579J <0.2 1.02 AMW-ld 19-Dec-18 0.5 1.8 2.6 1.5 3,500 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 11 360 202 <2 <10 7.18 6.0 0.0170J 0.573J <0.2 1.02 AMW-1d 8-May-19 1 1.71 1 91.1 1.4 1 0.73 1 2,700 0.038J 1 <0.0070 0.261 <0.032 <0.011 <0.0050 <0.048 <0.011 I 0.00651 <0.0050 1.3 300 145 2.12 <10 7.15 1 2.0 1 0.0220J 0.4801 1 <0.2 1 1.04 AMW-2s 3-May-11 2.10 128 0.003 0.014 0.240 0.098 <0.05 <0.1 <0.05 <0.05 <0.15 0.12 <0.07 0.063 <0.15 1.2 130 77 <0.5 20 3.2 <0.07 0.086 0.21 <0.6 1.2 AMW-2s 8-Nov-11 2.47 -30 0.016 0.076 4 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.092 <0.07 <0.05 <0.15 0.68 170 70 11 10 3.2 0.21H 0.11 0.097J <1 0.6B AMW-2s 8-May-12 0.42 195 0.014 0.022 0.34 0.042 <0.05 0.066 <0.05 <0.05 <0.15 0.53 <0.07 <0.05 <0.15 9.7 170 70 1.29 <10 3.4 <0.2H 0.121 <5 <0.2 0.418 AMW-2s 29-Nov-12 5.36 38 <0.025 0.026 0.86 <0.07 0.025 0.023 <0.30 <0.05 <0.15 <0.30 <0.07 <0.05 <0.15 0.411 170 8 <2 <10 3.3 <0.2H 0.111 <5 <0.2 <1 AMW-2s 9-May-13 0.88 153 0.008 0.022 4.30 0.047 <0.05 0.066 0.068 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 0.87 160 46 4 13.5 3.5 0.43 0.131 <5 <0.2 1.52 AMW-2s 6-Nov-13 1.51 75.1 0.0045 <0.025 0.58 0.020 0.068 <0.5 <0.1 <0.15 0.10 <0.07 <0.05 <0.15 0.94 140 63 <2 15.8 3.5 0.55 0.161 <5 <0.2 12.3 AMW-2s 7-May-14 2.08 114 0.022 0.0081 0.31 0.062 0.033 <0.5 <0.1 <0.15 0.032 <0.07 0.032 <0.15 25 180 60.6 <2 <10 3.6 0 0.161 <5 <0.2 1.07 1302-MSWLF- AMW-2s 5-Nov-14 3.48 120.5 0.0054 0.014 0.20 0.036 <0.05 <0.5 <0.2 <0.15 <0.30 <0.07 0.048 0.046 1.4 180 95 <2 <10 3.6 0 0.171 <5 <0.2 <1 CDLF-1998 AMW-2s 6-May-15 3.50 562 0.0044 0.020 1.10 <0.07 <0.05 0.088 <0.5 <0.2 <0.15 0.013 <0.07 <0.05 <0.15 52.0 180 53 <2 <10 3.5 0 0.221 <5 <0.2 1.05 AMW-2s 28-Oct-15 4.19 187 0.0048 0.056 0.26 0.026 0.0050 0.044 <0.20 <0.20 <0.10 0.0087 <0.30 0.0016 <0.30 8.0 160 64 <2 <10 3.7 0 0.241 <5 <0.2 1.15 AMW-2s 17-May-16 3.22 51 <0.10 0.012 4.60 0.017 <0.10 0.038 <0.20 <0.20 <0.10 <0.20 <0.30 <0.10 <0.30 1.9 180 65 <2 <10 3.4 0 0.291 <5 <0.2 <1 AMW-2s 1-Nov-16 3.38 235.1 0.0087 0.014 3.80 0.027 0.0073 0.051 <0.20 <0.20 <0.10 0.0077 <0.30 <0.30 <0.30 2.9 200 69 <2 25.8 3.7 0 0.31J,H-02 <5 <0.2 1.02 AMW-2s 10-May-17 1.55 48.2 0.078 0.018 0.82 0.019 <0.10 0.043 <0.20 <0.20 <0.10 0.019 <0.30 <0.30 <0.30 7.3 160 720 <2 14 3.5 0.5 0.411 0.331 <0.2 <1 AMW-2s 1-Nov-17 4.42 280 0.00951 0.0181 0.50J <0.10 <0.10 0.072J <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 8.5 150 74.0 <2 10 3.6 0 0.43 0.38 <0.2 <1 AMW-2s 8-Jun-18 2.2 162.2 0.14 0.0661 1.2 0.028J <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 0.0591 <0.30 <0.30 2.9 150 257 <2 <10 2.79 0 0.362 <0.5 <0.2 <1 AMW-25 20-Dec-18 2.9 101.3 <0.10 <0.10 <0.50 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 12 160 71 <2 <10 3.22 0 0.452 0.797J <0.2 1.31 AMW-2s 7-May-19 1 1.74 1 201.1 0.0701 1 0.36 1 17 0.0361 0.00781 I 0.191 <0.032 <0.011 1 <0.0050 1 <0.048 <0.011 <0.0020 <0.0050 1.5 190 1 79 1 <2 <10 2.78 0 0.342 1 0.306J <0.2 <1 AMW-2d 3-May-11 0.75 107 0.005 0.037 0.41 0.052 <0.05 <0.1 <0.05 <0.05 <0.15 0.12 <0.07 0.066 <0.15 0.86 44 129 <0.5 <6 3.1 0.081 0.017J 4.31 <0.6 0.8 AMW-2d 8-Nov-11 1.07 -29 0.03 0.19 7.10 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.032 <0.07 <0.05 <0.15 1.4 96 75 <2 7 2.9 <0.2H 0.0111 3.51 <1 0.7B AMW-2d 8-May-12 0.00 195 0.053 0.073 1 0.037 <0.05 0.053 <0.05 <0.05 <0.15 0.087 <0.07 <0.05 <0.15 31 98 80 <0.002 <10 3 <0.2H <0.05 <5 <0.2 0.932 AMW-2d 28-Nov-12 3.47 149 0.10 0.69 30 0.99 <0.05 0.031 <0.10 <0.05 <0.15 <0.10 <0.07 0.030 <0.15 0.68 110 79 <2 13.5 3.2 0.3 <0.05 <5 <0.2 <1 AMW-2d 9-May-13 0.36 126 0.013 0.049 1.1 0.1 <0.05 0.064 <0.10 <0.05 <0.15 0.08 <0.07 <0.05 <0.15 1.5 110 65 1.48 11.7 3 0.06 <0.05 <5 <0.2 <1 AMW-2d 6-Nov-13 1.40 137.7 0.0072 0.048 0.48 0.027 0.061 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.65 68 85 20.4 <10 3.1 0.16 0.181 <5 <0.2 <1 AMW-2d 7-May-14 3.88 95 0.0068 0.021 0.36 0.073 <0.05 <0.5 <0.1 <0.15 0.033 <0.07 0.030 <0.15 18 170 78.8 <2 <10 3.2 0.5 <0.05 <5 <0.2 <1 1302-MSWLF- AMW-2d 5-Nov-14 4.19 103.5 0.016 0.016 0.27 0.04 <0.05 <0.5 <0.2 <0.15 0.016 0.082 0.048 <0.15 1.3 100 130 <2 <10 3.3 0 <0.05 <5 <0.2 <1 CDLF-1998 AMW-2d 6-May-15 2.51 391 0.011 0.035 0.97 <0.07 <0.05 0.098 <0.5 <0.2 <0.15 <0.1 <0.07 <0.05 <0.15 23.0 200 90 <2 <10 3.4 0 <0.5 <5 <0.2 <1 AMW-2d 28-Oct-15 3.90 158 0.013 0.039 0.20 0.030 0.0075 0.038 <0.20 <0.20 <0.10 0.0051 <0.10 0.0024 <0.10 9.0 120 98 <2 <10 3.3 0 <0.05 <5 <0.2 <1 AMW-2d 17-May-11 2.69 88 0.023 0.012 0.49 0.036 <0.10 0.095 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 1.0 160 110 <2 <10 3.5 0 <0.05 <5 <0.2 <1 AMW-2d 2-Nov-16 2.15 345.8 0.015 0.2 2.00 0.020 <0.10 0.046 <0.20 <0.20 <0.10 0.075 <0.10 <0.10 <0.10 2.3 230 110 <2 31.2 4.2 0 <0.05 <5 <0.2 <1 AMW-2d 10-May-17 1.47 37.0 0.080 0.29 6.9 0.020 <0.10 0.035 <0.20 <0.20 <0.10 0.013 <0.10 <0.10 <0.10 7.7 200 121 <2 <10 3.7 0 <0.05 0.321 <0.2 <1 AMW-2d 2-Nov-17 3.20 151.0 0.020J 0.27 9.2 0.0211 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.9 190 131 <2 <10 3.9 0 <0.05 0.521 <0.2 <1 AMW-2d 8-tun-18 0.6 13.9 0.014J 0.28 12.0 0.0461 <0.10 0.089J <0.20 <0.20 <0.10 <0.20 0.0581 <0.10 <0.10 3.2 200 374 <2 <10 2.86 0 <0.0500 <0.5 <0.2 <1 AMW-2d 20-Dec-18 0.9 65.3 <0.10 <0.10 72 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 16 240 137 <2 <10 3.4 1.5 <0.050 0.819J 0.272 <1 AMW-2d I 7-May-19 1 2.55 165.2 0.037J 0.050J 0.25J <0.025 <0.0070 0.17J <0.032 <0.011 <0.0050 <0.048 <0.011 1 <0.0020 1 <0.0050 1 1.7 1 150 132 <2 1 <10 1 3.59 1 0 1 <0.050 0.6181 <0.2 1.04 Smith Page 16 of 18 June 2019 Table Sd Geochemical Constituents in Groundwater May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 MW-3 4-May-11 2.60 164 0.003 0.006 0.5 0.24 0.098 <0.1 <0.05 <0.05 <0.15 0.19 <0.07 0.094 <0.15 1.1 69 69 <0.5 <6 2.8 0.181 0.022J 0.251 <0.6 0.3 MW-3 9-Nov-11 4.05 198 0.04 0.059 1.6 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.043 <0.07 <0.05 <0.15 0.8 120 65 <2 <10 2.9 0.181H 0.0191 0.151 <1 0.4B MW-3 8-May-12 2.76 113 <0.025 0.021 0.14 0.072 <0.05 0.094 <0.05 <0.05 <0.15 0.13 <0.07 <0.05 <0.15 1.5 100 60 <0.002 <10 3.6 0.3H <0.05 <5 <0.2 0.303 MW-3 28-Nov-12 12.31 73 0.044 0.022 0.83 <0.07 <0.05 0.038 <0.10 <0.05 <0.15 <0.10 <0.07 <0.05 <0.15 1.1 120 91 <2 <10 3.2 <0.2H <0.05 <5 <0.2 <1 MW-3 9-May-13 1.88 111 0.118 0.1079 0.40 0.125 <0.05 1.118 <0.10 <0.05 <0.15 0.112 <0.07 <0.05 <0.15 1.6 82 52 <2 11.1 3.1 1.11 <0.05 <5 <0.2 <1 MW-3 7-Nov-13 1.99 301.1 0.0035 0.0075 0.34 0.049 <0.05 <0.5 <0.1 <0.15 0.22 <0.07 0.015 <0.15 1.4 110 69 26 28.1 3.4 0.83 <0.05 <5 <0.2 9.12 MW-3 8-May-14 0.04 150 0.0062 0.030 0.16 0.080 <0.05 <0.5 <0.1 <0.15 0.053 <0.07 0.034 <0.15 1.1 140 63.6 6 <10 3.2 0 <0.05 <5 <0.2 1.67 1302-MSWLF- MW-3 6-Nov-14 5.94 465.6 0.0040 0.015 0.30 0.045 <0.05 <0.5 <0.2 <0.15 0.040 0.068 0.048 <0.15 1.6 140 61 <2 <10 3.3 0 <0.05 <5 <0.2 <1 CDLF-1998 MW-3 6-May-15 2.29 260 0.00851 0.016 0.11 <0.07 <0.05 1.177 <0.05 <0.02 <0.15 0.114 <0.07 <0.05 <0.15 14 141 65 <2 76.2 3.4 0 <0.5 <5 <0.2 1,43 MW-3 28-Oct-15 3.85 166 0.23 0.022 0.20 0.026 0.0058 0.043 <0.20 <0.20 <0.10 <0.20 <0.30 0.0016 <0.30 11 130 69 <2 <10 3.4 0 <0.05 <5 <0.2 <1 MW-3 18-May-16 3.18 101 <0.30 <0.10 0.87 0.015 <0.10 0.079 <0.20 <0.20 <0.10 0.0092 <0.30 <0.30 <0.30 9.6 120 75 <2 <10 3.7 0 <0.05 <5 <0.2 1.32 MW-3 2-Nov-16 3.50 438.8 0.020 0.021 0.72 0.031 <0.10 0.1 <0.20 <0.20 <0.10 0.0082 <0.30 <0.30 <0.30 1.9 130 60 <2 14.9 4.1 0 <0.05 <5 <0.2 <1 MW-3 11-May-17 1.75 229.6 0.0045 0.0087 0.33 0.052 <.010 0.040 <0.20 <0.20 <0.10 0.0095 <0.30 0.022 <0.30 9.1 140 78 <2 <10 3.9 0 <0.05 0.61 <0.2 <1 MW-3 1-Nov-17 1.60 325 0.011J 0.0221 0.64 <0.10 <0.10 0.083J <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 2.4 120 80 <2 <10 4.2 0 <0.05 0.221 <0.2 <1 MW-3 7-Jun-18 3.7 130.6 <0.30 0.0171 0.35J 0.034J <0.10 0.077J <0.20 <0.20 <0.10 <0.20 0.047J <0.30 <0.30 3.9 110 79 2.31 <10 3.89 0 0.0180J 0.137J <0.2 <1 MW-3 19-Dec-18 2.8 48.8 <0.30 <0.10 <0.20 <0.10 <0.10 <0.30 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 9.5 160 89 <2 <10 3.34 0 27.OJ 0.222J 0.381 <1 MW-3 8-May-19 1.81 114.5 0.070J 0.0151 0.13J 0.027J <0.0070 0.221 <0.032 <0.011 <0.0050 <0.048 <0.011 0.00631 <0.0050 1.1 160 77 <2 <10 3.92 0.5 0.0250J 0.239J <0.2 <1 MW-A 3-May-11 1.08 113 0.018 10.010 3,100 0.085 0.12 <0.1 <0.05 <0.05 <0.15 0.13 <0.07 0.163 <0.15 1.3 470 134 6 7 11 1.141 <0.006 4.51 <0.6 7.6 MW-A 9-Nov-11 0.06 205 0.084 0.057 9,300 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.22 <0.07 <0.05 <0.15 1.3 610 115 2 <10 11 0.6H <0.05 4.31 <1 2.6 MW-A 9-May-12 0.00 103 0.11 0.027 8,000 0.16 <0.05 0,016 <0.05 <0.05 <0.15 0,11 <0.07 1,02 <0.15 3.2 560 146 6 <10 14 2.22H <0.01 <5 <0.2 0.364 MW-A 27-Nov-12 2.66 140 0.073 0.018 9,000 <0.07 <0.05 0.016 <0.30 <0.05 <0.15 0.043 <0.07 <0.05 0.071 4 530 127 8 13.3 19 0.60 <0.05 <5 0.228J 2.52 MW-A 7-May-13 0.25 -34 0.11 0.033 7,500 0.03 <0.05 0.07 <0.30 <0.05 <0.15 0.07 <0.07 <0.05 <0.15 0.541 470 131 5 5.15 16 0.28 <0.05 <5 <0.2 2.62 MW-A 5-Nov-13 1.89 290.8 0.051 <0.025 8,000 0.028 0.044 <0.5 <0.1 <0.15 0.11 <0.07 <0.05 <0.15 0.84 530 128 6 <10 20 0.60 <0.05 31 <0.2 2.53 MW-A 6-May-14 0.04 -17 0.048 <0.025 11,000 0.21 0.077 <0.5 <0.1 <0.15 0.026 <0.07 0.050 <0.15 0.90 580 131 4 <10 29 2 <0.05 3.51 0.232J 3.1 1302-MSWLF- MW-A 4-Nov-14 1.70 45 0.082 0.019 10,000 0.038 <0.05 <0.5 <0.2 <0.15 <0.1 <0.07 0.048 <0.15 4.8 640 111 2 <10 32 1 <0.05 4.41 <0.2 2.32 MW-A 5-May-15 2.34 26 0.0801 0.015 10,000 <0.07 <0.05 0.090 <0.5 <0.2 <0.15 0.027 <0.07 <0.05 <0.15 14.0 580 117 4 <10 28 1 <0.05 5.91 <0.2 3.15 CDLF-1998 MW-A 27-Oct-15 1.41 29 0.084 0.011 9,900 0.032 0.0066 0.022 <0.20 <0.20 <0.10 0.013 <0.30 0.0033 <0.30 7.2 600 123 11 <10 25 0.5 <0.05 7.41 <0.2 4.18 MW-A 17-May-16 1.27 -55 0.094 <0.10 11,000 0.21 0.084 0.032 <0.20 <0.20 <0.10 0.0075 <0.30 <0.30 <0.30 1.3 540 85 6 <10 18 1.0 <0.05 13J <0.2 3.68 MW-A 1-Nov-16 1.65 205 0.087 0.015 9,500 0.040 <0.10 0.057 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 1.8 640 129 12BOD-4 33.8 27 1.5 <0.05 191 <0.2 3.28 MW-A 9-May-17 1.31 140.9 0.084 0.0087 8,300 0.088 0.0095 0.053 <0.20 <0.20 <0.10 0.0078 <0.30 0.0090 <0.30 8.0 530 143 14 42.9 27 1.0 <0.05 17J <0.2 3.22 MW-A 31-Oct-17 3.21 70 0.085J 0.00651 9,300 <0.20 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 1.9 450 132 13 35.2 27 0.5 <0.05 24 <0.2 3.22 MW-A 7-Jun-18 0.4 635 <0.10 0.011 6,100 0.026J <0.10 <0.20 <0.20 <0.20 <0.10 0.0501 0.0681 <0.30 <0.30 73 480 136 <2 <10 24.1 1.5 0.01001 15.5 <0.2 20.5 MW-A 20-Dec-18 0.6 32.4 <0.10 <0.10 7,600 0.22 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 110 600 135 8.06 <10 2.39 3.5 0.01901 1.24 2.03 2.09 MW-A 9-May-19 1 1.91 1 76.7 0.0381 I 0.0141 1 5,100 1.0 1 0.011 1 0.151 <0.010 0.0291 0.00851 1 0.043 <0.0070 0.0191 <0.0050 1.3 290 109 6.96 <10 26.9 3.5 0.0230J 31.5 0.652 4.38 MW-E Rep 4-May-11 0.01 34 0.37 0.38 5,000 0.22 0.086 <0.1 10.05 <0.05 0.092 0.13 10.07 0.092 0.18 1.4 410 261 5 13 30 <0.07H <0.006 13J <0.6 4.2 MW-E Rep 8-Nov-11 0.00 -115 4.9 0.36 4,300 <0.07 <0.05 <0.1 <0.05 <0.05 <0.15 0.21 <0.07 <0.05 <0.15 1.4 460 275 5 34 32 5.89H <0.05 111 <1 4 MW-E Rep 8- May -12 0.00 13 4.6 0.33 2,200 0.048 <0.05 0.052 <0.05 <0.05 <0.15 0.086 <0.07 <0.05 <0.15 2.1 430 285 4 <10 30 8.22H <0.05 8.11 <0.2 0.317 MW-E Rep 8-May-13 0.47 -81 6.6 0.5 1,600 0.048 <0.05 0.074 <0.05 <0.05 <0.15 0.072 <0.07 <0.05 <0.15 0.561 350 405 2 16.9 52 3.3 <0.05 <5 <0.2 4.89 MW-E Rep 5-Nov-13 1.64 -39.8 4.2 0.36 1,700 0.038 0.058 <0.5 <0.1 <0.15 0.11 <0.07 <0.05 <0.15 0.81 330 320 4.09 24.6 31 2.77 <0.05 51 <0.2 4.18 MW-E Rep 6-May-14 0.07 -24 2.6 0.27 2,400 0.095 0.091 <0.5 <0.1 <0.15 0.15 <0.07 0.048 <0.15 0.97 400 285 3 <10 28 5 <0.05 8.51 <0.2 4.08 MW-E Rep 4-Nov-14 1.62 -54 3.7 0.56 2,800 0.038 <0.05 <0.5 <0.2 <0.15 0.051 0.070 <0.05 <0.15 1.4 430 610 3 <10 45 3.5 <0.05 111 <0.2 4.44 1302-MSWLF- MW-E Rep 5-May-15 3.61 -38 3.4 0.47 1,700 <0.07 <0.05 0.12 <0.5 <0.2 <0.15 0.036 0.028 <0.05 0.044 13 340 415 4 11 48 2.5 <0.05 111 <0.2 6.14 CDLF-1998 MW-E Rep 27-Oct-15 1.25 -36 4.1 0.73 2,300 0.038 0.0062 0.049 <0.20 <0.20 <0.10 0.011 0.011 0.0021 10.10 7.3 380 365 5 <10 48 2.0 <0.05 8.31 <0.2 4.82 MW-E Rep 18-May-16 1.40 -59 3.3 0.63 680 0.21 1 0.12 <0.20 <0.20 <0.10 <0.20 0.024 0.021 0.014 1 250 425 3 <10 55 0.5 <0.05 61 <0.2 4.49 MW-E Rep 1-Nov-16 3.79 48.1 4.8 0.73 660 0.035 <0.10 0.056 <0.20 <0.20 <0.10 0.0060 0.0086 <0.10 0.012 2.3 370 475 <2 33.4 50 3.0 <0.05 781 <0.2 5.06 MW-E Rep 9-May-17 1.35 -50.7 3.2 0.55 730 0.077 <0.10 0.058 <0.20 <0.20 <0.10 <0.20 0.0067 <0.10 0.010 2.6 340 457 2 38 65 4.5 <0.05 6.41 <0.2 4.38 MW-E Rep 31-Oct-17 2.48 65 4.0 0.58 600 0.0201 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 3.8 280 484 <2 32 54 2.5 <0.05 6.6 <0.2 4.46 MW-E Rep 11-Jun-18 1.3 -26.2 2.1 0.44 420 0.0581 <0.10 0.101 <0.20 <0.20 <0.10 0.0261 0.0451 <0.10 <0.10 120 280 462 6 <10 56.4 4.5 <0.0050 5.87 <0.2 3.33 MW-E Rep 20-Dec-18 0.3 -16.1 2.9 0.63 830 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 13 380 495 3.59 <10 49 6.0 0.0170J 6.81 <0.2 3.78 MW-E Rep 7-May-19 1.68 -1.9 3.0 0.60 930 0.0351 <0.0070 0.241 <0.032 <0.011 <0.0050 <0.048 <0.011 <0.0020 0.0141 1.7 420 1 510 <2 <10 46.6 4.25 <0.050 7.12 <0.2 1 3.65 Smith Page 17 of 18 June 2019 Table 5d Geochemical Constituents in Groundwater May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facilty Permit Number 1302-MSWLF-CDLF-1998 MW-E Deep 4-May-11 0.00 -51 3.3 0.14 6,900 4.3 0.13 <0.1 <0.05 <0.05 <0.15 <0.1 <0.07 0.25 <0.15 2.3 100 401 7 37 27 2.7 <0.006 0.0961 <0.6 5.4 MW-E Deep 8-Nov-11 0.00 -67 10 0.29 19,000 2.2 0.021 <0.1 <0.05 <0.05 <0.15 0.076 <0.07 <0.05 <0.15 2 160 345 16 33 26 2.2 0.0071 <5 <1 2.9 MW-E Deep 8-May-12 2.51 -76 7.5 0.11 14,000 0.84 <0.05 0.090 <0.05 <0.05 <0.15 0.10 <0.07 0.024 <0.15 3.3 160 305 24 22.6 27 4.03H <0.05 <5 <0.2 0.207 MW-E Deep 27-Nov-12 1.70 78 9.8 0.14 16,000 0.19 <0.05 0.058 <0.30 <0.05 <0.15 0.034 <0.07 <0.05 0.11 1.1 160 255 10 39.2 28 7H <0.05 <5 <0.2 1.37 MW-E Deep 8-May-13 0.51 -80 13 0.13 16,000 0.25 <0.05 0.12 <0.30 <0.05 <0.15 0.066 <0.07 0.028 <0.15 0.99 140 370 5 26.4 28 3.3 <0.05 <5 <0.2 2.3 MW-E Deep 6-Nov-13 1.21 -82.2 13 0.18 15,000 0.11 <0.05 <0.5 <0.1 <0.15 0.16 <0.07 <0.05 <0.15 1.5 170 345 5.97 23.1 31 3.3 <0.05 <5 <0.2 2.51 MW-E Deep 6-May-14 0.09 -41 4.6 0.13 19,000 120 20 2.9 <0.1 1.9 <1 20 100 4.0 1.3 480 320 1,580 2,410 20 5.5 <0.05 <5 <0.2 432 MW-E Deep 4-Nov-14 1.09 -82.3 2.8 0.056 22,000 52 2.3 0.44 <0.2 0.18 0.046 0.37 5.4 0.21 6.7 310 625 208 355 30 1.5 <0.05 <5 <0.2 41.6 1302-MSWLF- MW-E Deep 5-May-15 0.88 -100 9 0.059 22,000 7.1 0.092 0.23 <0.5 <0.2 0.029 0.019 <0.07 0.12 0.042 17 220 410 47 59.2 35 1 <0.50 <5 <2 8.26 CDLF-1998 MW-E Deep 27-Oct-15 1.20 -71 8.1 <0.50 26,000 2.4 0.085 0.035 0.012 <0.20 <0.10 <0.20 <0.30 0.026 <0.30 8.7 170 415 36 22.4 34 3.0 0.131 <5 <0.2 4.52 MW-E Deep 18-May-16 3.08 -95 3.9 0.021 16,000 2.8 0.2 0.064 <0.20 <0.20 <0.10 <0.20 <0.30 0.064 0.012 2.3 130 <3 28 63.8 37 3.0 <0.05 <5 <0.2 6.34 MW-E Deep 1-Nov-16 2.30 -39 12 0.063 29,000 0.12 <0.10 0.072 <0.20 <0.20 <0.20 <0.20 <0.30 <0.30 <0.30 2.7 211 411 62.5 44 2.0 <0.5 <5 <0.2 3.16 MW-E Deep 9-May-17 1.65 -78.5 8.2 0.067 21,000 0.073 <0.10 0.081 <0.20 <0.20 <0.10 <0.20 0.0095 <0.30 0.0099 3.6 190 395 26 70.7 49 5.0 0.51 0.151 <0.2 3.39 MW-E Deep 1-Nov-17 2.45 152 6.8 0.0481 17,000 0.18 <0.10 0.13J <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 2.1 170 407 8 60.6 53 3.0 <0.05 0.071J <0.2 5.22 MW-E Deep 114un-18 0.4 -84 5.5 0.0471 13,000 0.089J <0.10 0.13J <0.20 <0.20 <0.10 <0.20 0.069J 0.00981 <0.30 2.0 160 398 25.4 16.9 49.2 5.5 <0.0050 <0.0170 <0.2 2.37 MW-E Deep 20-Dec-18 0.4 -56.2 6.6 0.10 11,000 <0.10 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 7.7 320 451 7.59 303 5.62 6.0 0.01701 <5 <0.2 5.34 MW-E Deep 8-May-19 1 1.88 -30.9 5.3 0.076J 10,000 0.0821 1<0.0070 <0.098 <0.032 <0.011 1 <0.0050 1 <0.048 0.044J <0.0020 0.022J 2.7 360 468 129 <10 66.2 6.0 0.0210J 0.0920J <0.2 8.1 MW-L 4-May-11 2.31 206 <0.01 0.003 0.3 0.22 0.11 <0.1 <0.05 <0.05 <0.15 0.32 <0.07 0.097 <0.15 0.7 72 44 <0.5 <6 2.2 0.16J 0.13J 1.81 <0.6 0.5 MW-L 9-Nov-11 2.59 222 <0.025 0.066 0.3 <0.07 0.019 <0.1 <0.05 <0.05 <0.15 0.16 <0.07 <0.05 <0.15 1.4 83 30 <2 101 2.6 <0.211 0.0961 1.81 <1 0.58 MW-L 9-May-12 0.04 214 <0.025 0.014 0.69 0.049 <0.05 0.062 <0.05 <0.05 <0.15 0.11 <0.07 <0.05 <0.15 1.1 98 37 <0.002 <10 2.6 <0.2H 0.0961 <5 <0.2 0.342 MW-L 28-Nov-12 3.03 3 0.22 0.037 2.8 <0.07 0.033 0.031 <0.10 <0.05 <0.15 0.066 <0.07 <0.05 <0.15 0.43J 72 90 <2 <10 2.7 <0.211 0.052J <5 <0.2 <1 MW-L 9-May-13 1.09 188 <0.025 0,024 0,51 0,024 <0.05 0,056 0,044 <0.05 <0.15 0,085 <0.07 <0.05 <0.15 1.2 79 28 1,91 2,22 2.7 0 0.06J <5 <0.2 <1 MW-L 7-Nov-13 1.39 258.1 <0.025 <0.025 0.059 0.034 <0.05 <0.5 <0.1 <0.15 0.12 <0.07 <0.05 <0.15 0.78 90 35 2 <10 2.8 0.61 0.065J <5 <0.2 1.43 MW-L 8-May-14 2.12 379 0.0030 0.0038 0.042 0.063 <0.05 <0.5 <0.1 <0.15 0.033 <0.07 0.034 <0.15 0.79 100 34.3 <2 <10 2.8 0.5 0.061J <5 <0.2 <1 1302-MSWLF- MW-L 5-Nov-14 4.03 59.2 0.0037 0.014 0.63 0.042 <0.05 <0.5 <0.2 <0.15 0.058 <0.07 0.049 <0.15 1.3 100 31 <2 <10 3.1 0 0.0811 2.81 <0.2 <1 CDLF-1998 MW-L 6-May-15 4.15 131 0.005 0.016 0.055 <0.07 <0.05 0.12 <0.5 <0.2 <0.15 0.014 <0.07 <0.05 <0.15 26 100 31 <2 11 2.7 0 <0.5 1.91 <0.2 <1 MW-L 28-0ct-15 3.80 89 0.0058 0.019 0.077 0.029 0.0081 0.033 <0.20 <0.20 <0.10 <0.20 <0.10 0.0022 <0.10 8.9 94 39 <2 <10 3 0 0.054J 1.51 <0.2 <1 MW-L 19-May-16 3.66 192 <0.10 <0.30 0.031 0.012 <0.10 0.033 <0.20 <0.20 <0.10 0.0063 <0.10 <0.10 <0.10 0.63 98 35 <2 30 2.8 0 <0.05 1.41 <0.2 <10 MW-L 2-Nov-16 3.49 486 0.028 0.013 0.8 0.029 0.0079 0.046 <0.20 <0.20 <0.10 0.0062 <0.10 <0.10 <0.10 1.7 87 40 <2 12.9 3.2 0 0.085J <5 <0.2 <1 MW-L 10-May-17 1.40 128.9 0.046 0.011 0.24 0.021 <0.10 0.044 <0.20 <0.20 <0.10 0.030 <0.10 <0.10 <0.10 2.3 89 41 <2 <10 3 0 <0.05 0.951 <0.2 <1 MW-L 1-Nov-17 1.61 361 0.00981 0.016J 0.25J 0.0231 <0.10 <0.20 <0.20 <0.20 <0.10 <0.20 <0.10 <0.10 <0.10 2.3 89 45 <2 <10 3.2 0 0.085 1.81 <0.2 <1 MW-L 7-Jun-18 1.2 141.2 0.011J 0.017J 0.23J 0.044J <0.10 0.073J <0.20 <0.20 <0.10 <0.20 0.0661 <0.10 <0.10 13 94 34 <2 <10 2.94 0 0.0840 0.984J <0.2 <1 MW-L 19-Dec-18 2.7 100.4 <0.30 <0.10 0.93 <0.10 <0.10 <0 0.20.201 <0.20 <0.20 <0.10 <0.20 <0.30 <0.30 <0.30 13 95 41 <2 <10 2.95 0 0.0770 0.9881 <0.2 <1 MW-L 8-May-19 1.87 142.9 <W111D <0.0040 0.0571 0.0441 <0.0070 <0.032 <0.011 <0.0050 <0.048 <0.011 <0.0020 <0.0050 1.6 77 36 <2 <10 2.68 1 0 1 0.0840 1 1.481 1 <0.2 1 <1 Noter 1. Blank cells indicate parameter was not analyzed or the result was below the detection limit. 2. Assessment wells AM W-ls, -ld, 25, and 2d were installed in October 2009. 3.1 - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 4. BOD-1- Indicates the dilutions selected for the BOD analysis based on screening COD values did not meet the oxygen depletion criteria of at least 2 mg/L dissolved oxygen depletion. The result is reported as an estimated value or non -detect at the elevated reporting limit. 5. H, H-02 - Sample was analyzed outside the U.S. Environmental Protection Agency recommended holding time. 6. B- Indicates constituent was detected in the batch blank above the method detection limit. 7. BOD-3 - Lab control recovery was outside control limits biased low. Samples could not be reanalyzed due to holding time requirements. Sample values are reported as estimated values with possible low bias. 8. BOD-4- Lab control recovery was outside control limits biased high. Samples are reported as estimated with possible high bias. 9. mg/I - milligrams per liter/µg/I - micrograms per liter/mVolts - millivolts/Nm - nanomoles 10. HIBA - Hydroxyisobutyric Acid 11. Alkalinity, chloride, ferrous iron, sulfate, and total dissolved solids were added to the sampling program in May 2010 for CD-ls and CD -Id. 12. The November 2012 sampling event was the first event that CD-is/CD-ld replaced MW-9 as the background monitoring wells. 13. MW-9 was removed from the monitoring program in November 2012. 14. MW-E Rep was not sampled during the November 2012 sampling event due to laboratory oversight. Smith Page 18 of 18 June 2019 Table 6 Constituents Detected Above Standards May 2019 Semi -Annual Sampling Event Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 PERMIT MONITORING PARAMETERS EXCEEDING NORTH CAROLINA 2L OR IMAC MONITORING PARAMETERS EXCEEDING NORTH CAROLINA 2L OR IMAC STANDARDFACILITY NUMBER WELL .. ASSESSMENT MONITORING - MAY 2019 1302-MSWLF- MW-9 Not Sampled MW-D Cobalt*, Vanadium*, Benzene, 1,4-Dichlorobenzene, Vinyl Chloride CDLF-1998 1302-MSWLF- CD-1s Iron, Vanadium* MW-E Rep Cobalt*, 1,4-Dichlorobenzene, Vinyl Chloride CDLF-1998 (background well) 1302-MSWLF- CD-1d Iron, Vanadium* MW-E deep Barium, Cobalt*, Benzene, 1,4-Dichlorobenzene, 1,4-Dioxane CDLF-1998 (background well) 1302-MSWLF- CD-4 Rep Cobalt*, Vanadium* MW-F Cobalt*, 1,4-Dioxane CDLF-1998 1302-MSWLF- AMW-1s Vanadium*, Tetrachloroethene MW-G Cobalt*, Vanadium*, 1,4-Dioxane CDLF-1998 1302-MSWLF- AMW-1d Cobalt*, Benzene, 1,1-Dichloroethane, Trichloroethene, Vinyl Chloride MW-H Vanadium* CDLF-1998 1302-MSWLF- AMW-2s Vanadium*, 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene MW-H deep Vanadium* CDLF-1998 1302-MSWLF- AMW-2d Vanadium*, 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene MW-1 Vanadium*, 1,1-Dichloroethane, Tetrachloroethene CDLF-1998 1302-MSWLF- MW-1 Cobalt*, Vanadium*, 1,4-Dioxane MW-J Vanadium* CDLF-1998 1302-MSWLF- MW-3 Vanadium*, 1,1-Dichloroethane, Tetrachloroethene, Trichloroethene MW-K Vanadium* CDLF-1998 1302-MSWLF- MW-3 deep None Detected MW-L None Detected CDLF-1998 Chromium, Cobalt*, Vanadium*, Benzene, 1,4-Dichlorobenzene, - 1302 MW-A 1,1-Dichloroethane, cis-1,2-Dichloroethene, 1,2-Dichloropropane, MW-L deep Vanadium*, Tetrachloroethene CDLF-1998 -1998 Tetrachloroethene, Vinyl Chloride 1302-MSWLF- MW-B Cobalt*, 1,4-Dioxane MW-M Vanadium* CDLF-1998 1302-MSWLF- MW-C Chromium, Cobalt*, Vanadium*, bis(2-Ethylhexyl)Phthalate MW-X Vanadium* CDLF-1998 Notes: 1. Monitoring wells MW-3 deep, -L deep, -and -M are sampled annually during the spring event. 2. * - Constituents exceed the Interim Maximum Allowable Concentration (IMAC) 3. Bold -J Flag - Indicates the analytical result is an estimated concentration between the method detection limit and the method reporting limit. 4. The November 2012 sampling event was the first event that CD-1s and -1d replaced MW-9 as the background monitoring wells. MW-9 was removed from the monitoring program in November 2012. Smith Page 1 of 1 June 2019 Table 7 DHC Sampling Summary Cabarrus County Landfill Units 2 and 3 Facility Permit Number 1302-MSWLF-CDLF-1998 .. .. .. MW-E Rep 9-Jan-14 1,958 + 1.37E+06 + 1.81E+05 9.48E+05 + 8.02E+04 0.00E+00 + 0.00E+00 5.46E+02 + 1.02E+02 MW-E Rep 4-Mar-15 328 + 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 MW-E deep 9-Jan-14 3,524 + 1.38E+07 + 2.23E+06 7.85E+05 + 1.10E+05 0.00E+00 + 0.00E+00 2.84E+06 + 4.53E+05 MW-E deep 4-Mar-15 6,848 + 5.20E+03 ± 6.72E+02 9.00E+03 ± 8.24E+01 0.00E+00 ± 0.00E+00 7.06E+02 ± 1.28E02 AMW-1s 9-Jan-14 8,214 + 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-1s 4-Mar-15 538 + 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 AMW-1d 9-Jan-14 2,648 + 3.53E+03 + 3.17E+03 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-1d 4-Mar-15 1,716 + 1.03E+06 ± 1.12E+05 6.18E06 ± 2.89+05 0.00E+00 ± 0.00E+00 3.13E+04 ± 2.79+03 AMW-2s 9-Jan-14 1,917 + 3.09E+05 + 5.12E+04 1.24E+06 + 2.26E+05 9.61E+04 + 1.86E+04 5.66E+04 + 1.12E+04 AMW-2s 4-Mar-15 1,564 + 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 AMW-2d 9-Jan-14 1,320 + 8.81E+03 + 3.15E+02 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 0.00E+00 + 0.00E+00 AMW-2d 4-Mar-15 108 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 0.00E+00 ± 0.00E+00 Notes: 1. PCR - Polymearse chain reaction 2. DHC - Dehalococcoides spp 3. * - A "+" inidicates that amplication of bacteria was successful. "-" indicates that ampification was not successful. 4. ng/L - Nanogram per liter S. copy/L - Copy per liter Indicates the result is between the laboratory method detection limit and the reporting limit. Smith Page 1 of 1 June 2019 n I n I n I n I WE I n I n I n GW 0. 1� Z� / ITC-15 � /%1 � \ M-1 GW 726.89y xI EXIS"ING \ P ��0 &D, LANDFALL COVER MATERIAL m,PH ES I AND II STOCKPILE o S CTIVE) P-2 0 ERMIT 1-, 2 CDLF-2008 _8 MW�s IN > ° r $CD1 ABANDON9° CD-3 AB D ' A. .-7 $ , BAB�ND I D NED SEDIMENTATION POND4ZO ...� LAN FI'F`L PA SI ,., 200 0 400 MOW-13 ° \ 7 I ABA DON �� I ' ,,,., >_ °'°'° w, °• _ IRISH POTATO R AD ANDF L APPROX LIMI E EXPANSION ' P ROXq=WASTE B U R OLD FILL 'A / CATEGORY 2 II a UNIT 1 / ,x CLOSURE A E MS 41DFILL' UNIT 2 (INACTIVE/ CDLF OVER PE MIT 1302-MSWLF-19 NAnIV o c PE IT 2- S SRM1T 02-C L 1 9 MW J 1 2 GW 700.851 8i► GW 12 CMG W GW N _ � 8 x X ° $9.4 NM x ,.,.z 0 I 93.51 i ; W MW A B-4 � ° ri MW-7 GW 707 3 / � h6W G o MW-5 G1111681.10 LEGEND I 69 .17 ORR nn I '69 - -� ■M-1 MONITORING WELL \\ > w PROJE TE BO DA Y - ( "I d' / • �P-1 \\ i E 8 OF P, T 6 ° \ / OCT OB 9 9 3 M METHANE PROBE MW-5 MONITORING WELL WITH GROUNDWATER ELEVATIONS U MGW 679. 2. 7 ORROW AR Sv MSED) n AL I \ 9�t (INACTIVE ' / OMW-6 ABANDONED GROUNDWATER MONITORING WELL I PERMIT 1302- r n I / ) SW-1 SURFACE WATER SAMPLING STATION PERMIT 1392-CDL 9987 I SW'1 / / -�- - -� ---- ��/ MGW-3 1 m (713) ESTIMATED ELEVATION OF WATER TABLE \ / ----- ,•,, -0 0P-1 PIEZOMETER - �- POTENTIOMETRIC CONTOUR m- O 2.9 8 _ 7, � r _ /' _ MGW-1 METHANE GAS MONITORING WELL GW ¢ 8.28 MW M DEEP GW 67 . 7_ M -I D 667 47 AMW-1 S AMW-1 IIII' NOTE: D GW 679.25 : ,e 679.12 -SW-2 \, a) - 1. MW-A THROUGH M, ALONG WITH MW-1-3 AND M-3 DEEP COMPRISE THE GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED MONITORING SYSTEM. CD-4, CD-5, AND CD-6 WERE ADDED TO THE GROUNDWATER MONTORING NETWORK IN SEPTEMBER 2006. 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. 3. MW-517, 8A, 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS FOR UNIT 1. CD-iS AND CD-iD SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND • ° M HD P AMyy_2s yy 6Z,5,5r� ° °°°' °0 ° AMW-2D n' ° ;n, THE C&D LANDFILL. W 67 32 :,;, j 'ate 0 4. CD S, CD-i D, CD-2, AND CD-3 ARE THE APPROVED MONITORING WELLS FOR THE C&D LANDFILL AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. e '- _a° W-L DEEP -M� 5. GROUNDWATER ELEVATIONS MEASURED ON MAY 6, 2019. \\\ G Iv56.47 I M DEEP ! "� ry• y, 6. ASSESSMENT WELLS AMW-i S, -lD, -2S, AND -2D WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN OCTOBER 2009. 6 _60. 7 \ J ,� \ 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. 60 6 \ 8. MW-9 WAS REMOVED FROM THE MONITORING PROGRAM. mw-m \ 9. CD-7 AND CD-8, FORMERLY PIEZOMETERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE - MONITORING PROGRAM IN JULY 2014. 6 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY : J. KIUINcswoRTH SHEET CHK'D BY: D. FORBEs CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES DATE_ JUNE 2019 CDM. ��'�� GDM GI.-.e. Av MOO Glerrxootl e, Suite 490 INGF-h,NC2]812Te1:(919)32535900.12 NCR- CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 POTENTIOMETRIC SURFACE MAP PROJECT NO. 1278-231402 FILE NAME: CAB-S-I9.DWG FIGURE N0. DATE DRWREV N CHKD REMARKS fry �r..,,�•�. ' IF. LEGEND E Regolith Monitoring Well E Bedrock Monitoring Well Injection Well CDM_ Smith f 1" = Approximately 100' Notes. 1. The injection wells were installed using air -rotary drilling methods from October 5-9, 2009. 2. The injection wells are spaced approximately 30 feet apart perpendicular to groundwater flow and have a radius of influence of approximately 15 feet. 3. Surface area of the injection well network is approximately 5,400 feet. 4. The Phase I injection event was completed from November 2-6, 2009. 5. The Phase II injection event was completed from February 10-18, 2014. Figure 2: Injection Area Overview Closed Landfill Units 2 and 3 Cabarrus County, North Carolina Figure 3 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 M W-A 450.0 400.0 350.0 _ 300.0 Mo 0 UO 250.0 a U +; 200.0 v 0 M 41 0 �- 150.0 100.0 50.0 �1:T M Ln W W I, r- W W M M O O rl .-I N N M M V-tT M Ln w w I, r, w W m m O O rl ri N N M M:t -,t off Ln w w I, r, W W Ol Ol 01 01 01 Ol O� 01 01 01 01 Ol T O O O O O O O O O O O O O O O O O O O O ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ri ca O ca O to O ca O ro O to O co O ro O to O co O ro O ca O co O O ca O co O O ca O co O O ca O ca O O ca O ca O to g z g z g z g z g z g z g z g z g z g z g z z g z g z z g z g z z g z g z z g z g z g z g z g Date Smith Note: Only detections above laboratory method detection limits represented in figure. Figure 3 (MW-A) 70.0 .e I 50.0 3 u 40.0 O v u a 30.0 0 M 41 0 20.0 10.0 Figure 4 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 M W-3 w w M M O O -1 r-I N N M M I:t IZT M Ln l0 110 I, N w W M M O O -1 r-I N N M M M M l0 l0 I, N w W M a> Ol a> Ol O O O O O O O O O O O O O O O O O O O O r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I r-I ca O M O to O M O M O ca O M O to O M O M O ca O M O to O M O M O ca O O to O M O M O ca O M g z g z 2 z g z g z g z g z 2 z g z g z g z g z 2 z g z g z g z g z 2 z g z g z g z g Date Smith Note: Only detections above laboratory method detection limits represented in figure. Figure 4 (MW-3) Figure 5 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 MW-E Rep 200.0 Phase I Emulsified Oil Injection - November 2009 I Phase II Injection - February 2014 180.0 I I I 160.0 I I I 140.0 I I a�a 120.0 I o I I 100.0 v I I 0 80.0 o ~ 60.0 40.0 dv I I I I 20.0 I I 0.0 ' �I:zr Ln Ln 110 l0 I- r" w w M M O O r-I -1 . N M M�T Ln Lnt.0 l0 r- r- w W M M O O r-I r-I N N M MZT 1:T Ln Ln 1.0 110 I" r� w W M ca O ca O ca O ca O ca O ca O ca O co O ca O co O ca O co O ca O co O ca O O ro O O ca O O ca O O ro O O ro O Date CDM Notes: Only detections above laboratory method detection limits represented in figure. Smith MW-E was not sampled during the November 2012 sampling event due to laboratory oversight. Figure 5 (MW-E Rep) 180.0 160.0 140.0 —120.0 J dD 3 0 100.0 v 80.0 C M -W 0 ~ 60.0 40.0 20.0 Me Figure 6 Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 MW-E deep ra O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to O to g z Z> z Z> z Z> z Z> z Z. z 2 z Z> z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 z 2 Date Total VOC �PCE fTCE f DCE PVC Smith Note: Only detections above laboratory method detection Imits represented in figure. Figure 6 (MW-E deep) Quell LY111; ova 3 u 40.0 O v U w v 30.0 0 M 0 M 10.0 bMeM Figure 7 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-1s Phase I Emulsified Oil Injection - November 2009 Phase II - February 2014 I 01 a) O O r-1 r-1 fV N M M u1 Lr) l0 lD n n 00 00 01 O O cI cI cI cI rI . I cI cI T > T > ? > T > T > T > T > T > T > T > T M O M O to O to O M O co O to O to O M O c0 O to Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 7 (AMW-1s) M8a1111111 100.0 80.0 3 V 0 i co O �- 40.0 20.0 MeM Figure 8 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-1d I Phase I Emulsified Oil Injection - November 2009 I Phase II - February 2014 I I I I I I I I I I I I I I I I I I I I I I I I I I I I I i I I I I I I I I 01 a) O O r-1 r-1 fV N M M u1 Lr) l0 lD n r- 00 00 01 O O cI cI cI cI cI T > T > ? > T > T > T > T > T > T > T > T M O M O to O to O M O co O to O to O co O r0 O to Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 8 (AMW-1d) 35.0 30.0 25.0 u 20.0 M 41 0 H 10.0 5.0 STD Figure 9 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-2s Phase I Emulsified Oil Injection - November 2009 i Phase II - February 2014 I M M o O r-1 N N m m r- r, 00 00 m 0 0 ra O ro O co O co O ro O co O co O ro O r0 O ro O ca z z g z g z g z g z g z g z 2 z 2 z 2 Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 9 (AMW-2s) 80.0 70.0 3 50.0 v 40.0 30.0 0 IWIXII 10.0 .wM-M Figure 10 Total Detected Volatile Organic Compounds Cabarrus County Landfill Units 2 and 3 AMW-2d Phase I Emulsified Oil Injection - November 2009 Phase II - February 2014 I I I rn am O O —1 -A N N m m �t Ln Ln �.D �.D r- r, 00 00 m 0 0 M o (U o M o M o (U o M o M o (U o M o M o (U z z g z g z z g z g z z g z z Date Notes: Only detections above laboratory method detection limits represented in figure. Smith Figure 10 (AMW-2d) n n n n n n n n / �1_1 OC 00TVOC 01 M-4 M-1 EXI G P-4 P ° "CBL DFI L , PH E I AN II COVER MATERIAL STOCKPILE o TIVE) I P-2 ERMIT 1 2`611 F 2 Q _ I _g "\ NOG= I r ,..a „o J �CD-4 ABAN D GW-1 ,� / 16 ........... ,w. / ,ate x ,Q/y' • C 7 Q ABANDONED N e FIVL P D SEDIMENTATION POND co SI �., A\\ / DINED BA 1 — / \ MGWY2 . „ \` ,: 200 0 400 p9 IRISH POTATO ROAD �c E RO R APPROX LIMI � ANDFILL EXP SI INP �� OLD FILL 'A CATEGORY 2 CLOSURE E 2 I �, x �<I S UNIT 1 - MSW LAND ' INACTIVE/CLOSED) / B DLF OVER / I I �_ —° �� ( NACtIVE/C 0 a I x PE MIT 1302—MSWLF=1974 0 n PE IT 1302— S h o a ER T `'302—C L 1 9 I I M A b.. P jlo C 0 w W- +e � MW 6 B-4 . TVO =171. I ,x,,/ a / MW �VO W_6 — _ � i I maw Oc=94.8 \ .a _ MW- LEGEND 1�vl'�� 1 °_ / / \�\ "\ ■M-1 MONITORING WELL �` PROJE TE BOU DAY W 3 v1\ I� Mw 1 � j 1 •P-1 METHANE PROBE OF E P T M OOTOB 9, '�^� 3 1 1 \ U 3 \ 0MW-5 MONITORING WELL WITH TOTAL VOLATILE ORGANIC ORROW AREA I i CDLF 0 MSx„ I ° n / : COMPOUNDS (TVOC) DATA IN PARTS PER BILLION (RED) \ (INAC'TIVE SED� RMIT 1302- F- „x. Ls / � I "\ OMW-6 ABANDONED GROUNDWATER MONITORING WELL I w / a 1 SW-1 SURFACE WATER SAMPLING STATION PER 13fi2—CDL �, 996"=¢ I __-- ��� "� 's GW-3 - �� � ESTIMATED ELEVATION OF WATER TABLE a (713) nv ° 0 x P-1 PIEZOMETER MN/-C � 1 � � � ��� INu CTION AREA � .o_.'M - 11.5 °" arK \ J \ - - 8 M W-9 ,w TVOC ISOCONTOUR (PPB) TVOC T 1 b MGW-1 METHANE GAS MONITORING WELL ® INJECTION AREA '/' OC= 0.8 a 3, _�-..,, - r. 1I n M K _ NOOC=66.1 N C=0 MW-E���°EP) � ss l � D E AT ON As PO D MSEDIMENTATIO 14i. GN' 4 NO =18.0 NOTE: A D a° a - SW-2 �% 1. MW-A THROUGH M, ALONG WITH FOR U AND M-3 DEEP COMPRISE THE GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED _7 MONITORING SYSTEM. CD-4, CD-5, AND CD-6 WERE ADDED TO THE GROUNDWATER OC- � wa MONITORING NETWORK IN SEPTEMBER 2006. 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. � 3. MW-5, 7, 8A, 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS OC- .7 * FOR UNIT 1. CD-iS AND CD-iD SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND THE C&D LANDFILL. 4. CDD, CD-2, AND CD-3 ARE THE APPROVED MONITORING WELLS FOR p) THE C AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. THE &D LANDFILL 58. / / 5. TVOC DATA FROM MAY 7-9, 2019. ALL VALUES ARE REPORTED IN PARTS PER BILLION (PH 3) AND DETECTIONS ARE AT OR ABOVE LABORATORY REPORTING LIMITS. \ '\ 6. ASSESSMENT WELLS AMW-1S, -1D, -2S, AND -2D WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN OCTOBER 2009. C 10 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. --. - 8. MW-9 WAS REMOVED FROM THE MONITORING PROGRAM. 9. CD-7 AND CD-8, FORMERLY PIE70METERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE �\ MONITORING PROGRAM IN JULY 2014. �JJ�� (( 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY: J. KILLINGSWORTH CDM. ��' CDM Smith Im.MOOG,e..e A-, Suite400 Releigh,NO27612Td:(919)3253500 NCF 2 CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 TVOC ISOCONCENTRATION CONTOUR MAP PROJECT NO. 1278-231402 FILE NAME: CAB-ISO-S19.DWG STEEL CHK•D BY: D. FORBES CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES GATE: JUNE 2012 FIGURE EV NO. DATE DRWN CHKD REMARKS Appendix A Client Name: Client Contact: Project: Site: Note: MONITORING WELL DATA SUMMARY Camp, Dresser, & McKee Mr. Mat Colone Semi-annual Ground Water Monitoring Cabarrus Co. Landfill - Units 2 & 3 Report No. Sampling Date 2618294 05/06/19-05/10/19 Well ID DTW 1 Well ID DTW 1 Well ID DTW Well ID DTW 1302-CD-4 Rep 10.65 1302-MW-E DEEP 27.73 1302-MW-K 19.61 1302-AMW-2S 18.95 1302-MW-1 11.88 1302-MW-E R 24.30 1302-MW-L 9.88 1302-CD-1S 28.11 1302-MW-3 11.90 1302-MW-F 8.09 1302-MW-L Deep 11.35 1302-CD-1 D 26.89 1302-MW-3 Deep 7.63 1302-MW-G 9.23 1302-MW-M 17.56 1302-MW-A 39.57 1302-MW-H 27.35 1302-MW-X 13.21 1302-MW-B 2.46 1302-MW-H DEEP 21.76 1302-AMW-1D 46.68 1302-MW-C 12.04 1302-MW-1 41.83 1302-AMW-1S 46.05 1302-MW-D 1 22.76 11302-MW-J 27.62 11302-AMW-2D 18.18 Sampled By: W.Flammer-J.Mueller Field Specialist(s) 1 DTW - Depth to Water From Top of Casing (ft.) Reviewed By: (51 Field Servioes Manager MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitoring Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: 2618294 Sampling Date: 05/06/19-05/10/19 Well ID % Vol Well ID % Vol Well ID % Vol Well ID %Vol 1302-CD-4 Rep 0 1302-MW-E DEEP 0 1302-MW-K 0 1302-AMW-2S 0 1302-MW-1 0 1302-MW-E R 0 1302-MW-L 0 1302-CD-1S 0 1302-MW-3 0 1302-MW-F 0 1302-MW-L Deep 0 1302-CD-1 D 0 1302-MW-3 Deep 0 1302-MW-G 0 1302-MW-X 0 1302-MW-A 45.0 1302-MW-H 0 1302-AMW-1 D 0 1302-MW-B 0 1302-MW-H DEEP 0 1302-AMW-1S 0 1302-MW-C 0 1302-MW-1 0 1302-AMW-2D 0 1302-MW-D 0 1302-MW-J 0 11302-AMW-2D 0 Note: 1 % Vol - Volume of Methane Gas in Headspace Page 1 of ! Sampled By: W.Flammer, J.Mueller Field Specialist(s) Reviewed By: Fi d Services Manager MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitoring Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: 2618294 Sampling Date: 05/06/19-05/10/19 Well ID BOC' I DTW Well V013 Purge V014 pHs I SC9 Temp' Turbe DO9 ORP10 Comments 1302-CD-1 D 52.32 26.89 - 24.20 5.67 114 18.3 9.14 1.61 183.2 Clear, no odor 1302-CD-1 S 29.91 28.11 - 11.201- 5.26 116 15.0 7.13 1.82 242.4 Clear, no odor 1302-CD4 Rep 19.08 10.65 4.25 4.25G 5.98 191 14.7 9.87 2.46 48.4 No odor 1302-MW-1 30.51 11.88 9.11 9.25G 6.51 140 15.9 5.47 1.52 22.4 No odor 1302-MW-3 35.49 11.90 - 7.001- 5.47 170 15.2 5.50 1.81 114.5 No odor Fe2+ =0.5 1302-MW-3 Deep 94.74 7.63 - 5.001- 6.98 343 16.0 8.00 1.76 17.9 Clear, odor 1302-MW-A 50.36 39.57 - 9.201- 5.27 449 13.7 1.79 1.91 76.7 Clear, odor Fe2+ =3.5 1302-MW-B 15.48 2.46 6.36 6.50G 6.67 784 16.0 5.23 1.05 -64.5 Cloudy, slight odor 1320-MW-C 17.93 12.04 2.88 3.00G 5.74 98 15.0 3.22 1.37 104.3 Cloudy, odor 1302-MW-D 30.60 22.76 3.83 4.00G 5.92 620 13.8 3.14 1.93 36.4 Cloudy, no odor 1302-MW-E R 41.89 24.30 - 6.801- 6.05 984 17.3 2.25 1.68 -1.9 Clear, odor Fe2+ =4.25 1302-MW-E DEEP 59.94 27.73 - 8.201- 6.29 1123 16.4 8.83 1.88 -30.9 Odor Fe1+ =6.0 1302-MW-F 20.32 8.09 5.98 6.00G 6.57 478 14.3 4.78 1.55 -69.4 No odor Client Name: Cama. Dresser, & McKeee Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: 2618294 Sampling Date: 05/06/19-05/10/19 Well ID BOCt DTWZ e11 1 Vol' Purge Vol° pHs SCS Temp' Turbe DO's 0RP10 Comments 1302-MW-G 20.46 9.23 5.50 3.25G 6.39 1576 15.0 7.72 2.28 -82.9 Cloudy, sli ht odor 1302-MW-H Deep 59.95 21.76 18.67 18.75G 6.47 261 16.2 6.31 2.75 95.2 No Odor 1302-MW-H 33.25 27.35 2.88 3.00G 6.23 161 15.0 5.12 4.74 118.5 Slight Odor 1032-MW-1 65.48 41.83 11.56 11.75G 6.15 130 15.8 5.52 5.96 115.9 Cloudy, no odor 1302-MW-J 35.13 27.62 3.75 1.75G 6.58 245 16.1 8.72 2.45 154.5 Cloudy, odor 1302-MW-K 36.49 19.61 8.25 8.50G 6.06 181 15.9 4.21 2.45 140 No Odor 1302-MW-L 27.36 9.88 - 8.20L 5.12 91 14.4 6.87 1.87 142.9 Faint Odor 1302-MW-L Deep 64.29 11.35 - 4.00L 6.10 203 13.7 4.52 1.90 160.7 Faint Odor 1302-MW-M 39.71 17.56 10.83 11.00G 6.53 287 15.7 2.13 2.84 324.7 No Odor 1302-MW-X 32.36 1 13.21 9.36 9.50G 1 6.28 181 14.7 4.37 1.33 1 137 Faint Odor 1302-AMW-1D 96.94 46.68 - 10.001- 5.56 372 17.9 9.37 1.71 91.1 Odor Fe2+=2.0 1302-AMWA S 67.78 46.05 - 9.80L 5.23 205 15.5 2.28 1.80 90.3 Faint Odor Fe2+ =0 1302-AMW-2D 62.88 18.18 - 7.60L 6.08 256 20.2 9.10 2.55 165.2 Faint Odor Fe2+ =0 1302-AMW-2S 40.09 18.95 - 7.20L 5.24 154 16.2 6.95 1.74 201.1 Faint Odor Fe2+ =0 Notes: Il BOC - Bottom of Casing (Ft.) 2 DTW - Depth to Water from Top of Casing (Ft.) 3 Well Vol - Calculated at 3 Times One Well Volume (Gal.) 4 Actual Volume Evacuated Prior to Sample Collection (Gal.) 5 pH - Reported in Standard Units 6 SC - Specific Conductance (uS/cm) 7 Temp - Temperature (`C) 8 Turb - Turbidity (NTU) 9 DO - Dissolved Oxygen (mg/L) Il0 ORP - Oxidation/Reduction Potential (mV) Sampled By: W.Flammer, J.Mueller Field Specialist(s) Reviewed By: field Services Manager Client Name: Client Contact: Project: Site: Notes: SURFACE WATER SAMPLING DATA SUMMARY Camp, Dresser, & McKee Mr. Mat Colone Semi-annual Surface Water Monitoring Cabarrus Co. Landfill - Unit 1 Report No.: 2618286 2618294 Sampling Date: 05/06/19-05/10/19 Point ID pH SC Temp Turb DO ORP Comments 1302-SW-1 7.17 357 18.9 11.2 4.06 120.1 1 No comment 1302-SW-21 6.74 1 473 1 19.8 1 8.78 1 5.07 1 174.1 1 No comment 1 pH - Reported in Standard Units 2 SC - Specific Conductance (uS/cm) 3 Temp - Temperature (°C) 4 Turb - Turbidity (NTU) 5 DO - Dissolved Oxygen (mg/L) 6 ORP - Oxidation/Reduction Potential (mV) Sampled By: W.Flammer, Mueller Field Specialist(s) Reviewed By: Q el ices Manager WELL INTEGRITY AND WATER LEVEL FORM Project Name: Cabarrus County Landfill Units 2 and 3 Date: Site Location: Concord North Carolina Weather: Field Personnel: W. L. Measuring Method: M v Page of �J L 3 >. C'. a m u, C• Q w N hO Water Level Sounded T C'. m y e w m C' m s w o C'' � o m .. f6 c m a " Well ID TIME (BTOC) Depith P (BTOC) m m m y w m �, o m 2- c o i'o c m o rn c n c m 3 n o c m m> s 3 Comments feet (feet) (feet) o f6 _ m U > > o n n >a� f6 m -_ > N o o Q 75 y Q - 0 u, N y > N Y c U C > c t Q3 N p �.. J LL N N 6Y N N N N N � Y N J�S� �'J MW 1 NA NA NA NA IJ& 19A N& N NA NA bIA LEL= O 2_qb Y 1 `� b O ^A b CII "f N N ® N N N N N N LEL= 05 O 7 o MW 3 Dee A NA NA 2_ Y Y Yw Y Y N N N N N © �I N MW-B L tip NA NA NA NA NA NA NA LEL= O 2 7b Y Y Y Y Y MW C J N NA N NA N NA N N4 N NA I NA N NA N NA N A Ir� NA N NA N NA LEL=r6 O 2_'Ib b l 3p b N (� N N NN Q) N N N N d MW D ` J NA NA NA NA NA NA NA A NA NA LEL= O 2_`)-L Y YMWF ✓ \ 10 ' S N ,,Y� A NA NA N y W NA LEL=,O O 2= 20 O a, CoMBO l J J �, �A 1 ty/ N N -ty)- N -*- N T N 7N y 4(y) . w N MW-G NA -NA I NA NA I NA A NA PA NA N6 NA LEL= 4S O 2=ZA •`k Y Y Y Y ;! Z 2 �} ?JS J 3 J Zc_; N & N N N N N �Y l'J N N MW-H b ✓✓ NA NA NA NA NA t4A N4 1JA NA NA NA I NA LEL= b O 2=7U .� 2 �N 1' Y Y N Y N N N Y Y 0 Q C� O MW H DEEP I A NA NA A NA NA NA M N NA A LEL= 2_70• I i N N Y � N N Y N N Y Y N r. MW t 11 ��J O v NA NA A NA NA NA NA NA NA NA A NA LEL= O 2_ (A .� I have received this Well Integrity and Water Level Formm(s): Signature Project Name: Cabarrus County Landfill Units 2 and 3 Site Location: Concord North Carolina Field Personnel: utV_ke •' swQ\ WELL INTEGRITY AND WATER LEVEL FORM Date: 4 Page � of 3 Weather: UeCti' i W. L. Measuring Method: ov w o w w aD > " NMm Water Level c = -0 r• a ' mC, omSounded , m omv°i' ID TIME (BTOC) (BTOC) aim yZ N u o Eo oo a crn aDepth 0 >�> Comments a as `(fit) a)(feet) ow 'a mtWell m o c Zi0 U > Q 3 2i n Y Y Y Y Y Y Y Y Y MW-J I� (Ja. , C� ASS • 13 NA N MN N A N M NA NA (Y� NA NA LEL= 0 02= OlJ�� Y Y Y Y Y Y Y Y -1 I 3b � N LEL= 0 02= �Q MW-K 5 b . !� .('I-1 NA NA Ncf NA NNAA Y Y Y Y Y Y 'NA, MW-L Dee `% '� ,��J ���I �[Y,� v NA /Y� v NA NA NA oY N N r LEL= 02=YY© ;NA Y Y MW-M �, 1 I , ��p �NA NA NA NA N NA N NA N NA LEL= Q 02=Qy) , Y Y Y Y Y Y Y Y MW-X �^ t J g'V t� ,;l �13 G NA ®Y NA RA NA N N N NA N �/� LEL= 02=1-V , Y Y Y Y Y Y Y Y Y CD-4Re 1l354 io.IA5 \`'111 NA � No NA NA N NA N NA NA N NA NA NA NA N NA LEL= V Oz= , S 90 Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N I N N CD-6 ABANDONED NA NA NA NA NA NA NA NA NA NA NA LEL= 02= oc�s C D-1 S `(� I ` 1 R p 0 1 G 1 1 NA N NA N NA N NA N tLA ® NA N NA N NA N (IVN NA NA NA _ LEL= 02= b �dfs CD-1 D rrll V� v ��U, 1CI �/ J �, 3a N NA N NA NA N N NA N4 N bLA N NA o NA ® N LEL= 02= Q, Y Y Y Y Y l r CY I' 3 S I �Y / LEL= 02= MW-3 4 V� J �� NA NA IQA NA NA NA NA NA NA NA NA k� I have received this Well Integrity and Water Level Form(s): Signature 0 Date Project Name: Cabarrus County Landfill Units 2 and 3 Site Location: Concord North Carolina Field Personnel: wflomer WELL INTEGRITY AND WATER LEVEL FORM Date: 5 16f IC1 Page of 3 Weather: F i W. L. Measuring Method: Cn(tn St '�3 -7-7?u L 3 T w r` o v a) o (M c c- 5 N c' -0 C, a) 0 C' N C 'y v Water Level Sounded c ' c' T N v d 'o °' c` - a D c d. c.. d t w `9 t o C, .- o C Well ID TIME (BTOC) Depth (BTOC) a; `� •� — o 0 o u, 0 � o o o �' °' c a 'c o a� 3 o. o c r � Comments (feet) (feet) m CL �a —m — c asy —> o w G v w mm 3 N m a-. aoi Yv, U as c a� o cc d cc 0 m a -J Y Y Y Y Y Y Y Y Y N N Kok MW A I,�'( �i _ S . 3 6 N A N NA NA N NA N NA N N NA N NA NA LEL= Q 02= �e b<C1F1f: MW E LP _ �6 5 �` IIll -1 30 1, �y N N N NA CR NA N NA NA (?N A N NA N A J A A N N4 1LEL= 02=0'4l 1< Y Y Y Y Y Y Y Y MW-E Dee t ` ` � `t `' 1 NA NA NA N NA NA / NA NA NA tJA LEL= to 02= � Y LY) Y Y Y Y Y Y MW-L I%� v C DS 9�• 3� A NA ETA N NA N NA NA N NA 9. NA N NA ^n LEL= 02= d-k-/ Y Y Y� Y Y Y Y Y Y AMW-1 S / ���0 NA N NA NA NA NA NA NA n� LEL= Q 02= O 'Cl IV Y Y Ca�eq "z l r��6.CIq q 0 � �� N � �Y N N N N N N AMWA D \o NA NA NA NA LEL= 02= Y Y Y Y Y Y Y Y Y Y `6 1 O� (Yy © 0 AMW-2S `C� ` NA NA NA NA NA NA NA NA NA LEL= 02= <<( Y Y Y YY Y Y t r y� `� �. W NA JLEL= AMW-2D S � V, NA NA A NA WA NA NA NA NA NA in 02= 1� Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= 02= I have received this Well Integrity and Water Level Form(s): Signature Ful Date 117��acoeAnalytical Site Name: Field Personnel: Sugeee-Water4P4: 'k So - C 4) - FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Camp, Dresser & McKee Inc. - Raleigh Cabarrus County Sanitary Landfilj4Jnits 2 & 3 W. Flammer J.Mueller U i, C $ Date: G .-'A, \6\ Weather Conditions: U\-4-m+.o- Q C—'6 f. n , Total Well Depth in feet (TWD) = ':)1.3Z Depth to Ground Water in feet (DGW) = ZL -$`\ Length of Water Column (LWC) = TWD - DGW = 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (g U@w&4: L L-) - ,,`A .2J Casing Diameter: 2 Casing Material: V\lc- Dedicated Pump: Nn Method of Well Evacuation: Vj Method of Sample Collection: Well Yield (subjective): Sample Date and Time: Gj . • l L I- L -I • Z-s 1Z o Time (military) '' 0 `� iUJi i0'q,�1 1i7'1cj i05� �l®q it\� 1�� 12c�2 1La Volume Purged (Galle+j 0 r �' r) . �; it S ') i .ti I.p 15000 �7 � 1 . ��- L l' `i c g c k 1 5 �l `� i�`� kA r\ \el .00 (.� . �o l a i� 10 11 Ob r ^ ` �� i. Tt7 $ 3 it 10 13 �A _ � � t •:.1' 5 11 l� `S•00 _ ^ ^ [ • �5 5 �16 11S k�.Qo LZ t)O _ � • bb �i tv'7 �� �� 5 �Z y u'} ��.i>J t l- t • �P`) J• t it L •11C� L t . io`j lk-3 ib i�.�cD [^. � • �i7 N 1 l Water Level (ft.) stable pH (s.u.) t 2 Sp. Cond. (µmhos/cm) to Water Temp. ('C) constant Turbidity (NTU) t10%or55NTu 11o, zoo.. i06 5i . '1 �. 2i • ��. t2 �b 10 �i•ii1 Dissolved Oxygen (mg/L) ±10% 'L•S� i,•%' i-S6 '�•ioZ i•h5 i•bJ 1•b3 \ h'6 S`b (�`� �-VA �.co RedOx Potential/ORP (mV) tiomv Ici(o. 0 1��1 .ti 1 � �1 G(r'J LVO \t,b•� i0-0 i'�3 (, Lvc� •1 LL-a 11 booi.Vi7 � }.i- J CUp -L(U'J �16 ' ZUp ?ov C'N1 !t�n��� COMMENTS/OBSERVATIONS: Vlj cl%' W o 1, +Vk va-a n Fit -kJ%11�I Date: _ By: ��• Page of aceAnalytical " FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: .2 " Site Name: Gabarrus County Sanitary Landfil nits 2 & 3 Casing Material: PVC Field Personnel: �J{{ 1 I`�— ` j ,\ . Fl1ammerC 1.Mueller U L C $c j> Dedicated Pump: y�o #: 7'�'—j`�' 1 J0 I• - vD - A V Date: 5. + , \ "\ Weather Conditions: C; o, \� '1111A Total Well Depth in feet (TWD) = "L C\ - h \ Depth to Ground Water in feet (DGW) = Z 3 • \ � Length of Water Column (LWC) = TWD - DGW = 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = x Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gafluns)— Ci-1'. i,l - It) L Method of Well Evacuation: (� Method of Sample Collection: I Well Yield (subjective): Goa a Sample Date and Time:- P5 i 31 rt I Time (military) ^ ?," 0 g r, a Q SS' MOO 0`%c5 OYilO C)"iIS ©` 10 C`I13 C) CAILo Volume Purged (Ga•Hons� 0 • o 0 5 oe • oc ��`� `� oo •uo kO.ec t�� (00 i t •La Water Level (ft.) stable `� �I i`b.'�3 2`b %'� 2� �+S 1� �� i ib:�� pH(s.u.) t2 5 VA S-10 5 to ej-t(, 5-i,(D Sp. Cond. (µmhos/cm) io Water Temp. (°C) constant \ L., . iS -o iy .�j ILA -I m • b 1 `i.r\ � 5 .b i G _� 1 S . � 15 Turbidity (NTU) ±10%at<5NTU -L1 35 1`b • iS yc'` . l� . 'a �. �, ��.+AS Dissolved Oxygen (mg/L) tio% Z =�`1 `b2 iA? 1 As i ` 1k l •� � 1 • $i i.`br1- i.�s \ � L RedOx Potential/ORP (mV) tiomv L L-VA .L� 1'j (P 2't0.,; 1y5 io ILA 3.3, iVi3•6 An ®D 'Loo l,ov 'too ioc I �w 2uo 2uo COMMENTS/OBSERVATIONS: UL \-k0 O L. Il st-tt : O`33 Date: '1 By: 1 --�--E Page of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: �k Site Name: Cabarrus County Sanit Landfill UnitsnO Casing Material: N(C Field Personnel: ��•V�l�vlet'. Dedicated Pump: k) Surface Water ID #: \30), C, _y Date: S �4 Weather Conditions: S It" #A Method of Well Evacuation: ViA p-d' Total Well Depth in feet (TWD) _ \ Method of Sample Collection: e(- Depth to Ground Water in feet (DGW) Well Yield (subjective): 6 Length of Water Column (LWC) = TWD - DGW Sample Date and Time:. 7 10;5' 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = \ , 3- 1.S g k j4 ,3 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = —� TU — �(, 9 Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gallons): Lk. Time (military) ' It 1 iV t% ' o 4 10 a Volume Purged (Gallons) 0 Water Level (ft.) stable — -- -- pH (s.u.) = 2 03 CA Sp. Cond. (µmhos/cm) = io % ?S� 1 rl,h l�\, 3 m . k Water Temp. (°C) constant �A.Cf K• Turbidity(NTU) *10%or-5NnJ g -r Dissolved Oxygen (mg/L) tto^i I �k RedOx Potential/ORP (mV) tio.v �3, �3 Li 3 A COMMENTS/OBSERVATIONS: (� �UPtNO 06 06 G l Dater (l By. C • Page of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabatrus County Smitary Landfill Units 2 & 3 Casing Material: Field Personnel: W. Flammer J.Mueller Dedicated Pump: fl� Surface Water ID #: M Date: KA Weather Conditions: Sri, Method of Well Evacuation: r Q� Total Well Depth in feet (TWD) = 30 • o Method of Sample Collection: ' of Depth to Ground Water in feet (DGW) _ � J,V Well Yield (subjective): Length of Water Column (LWC) = TWD - DGW = ,O Sample Date and Time: S ,,� ) y 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = '3 , 3 , S eE wit tic 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = — kf � " S-, Standard Evacuation Volume (3 casing volumes) _ , t1 , aj Total Volume of Water Removed (gallons): S Time (military) i ko I'PN 11)-SNI Volume Purged (Gallons) 0 `�.5� "1 q 135 Water Level (ft.) stable — y — pH (s.u.) i s ( • i� G. G 1 S-( Sp. Cond. (µmhos/cm) t to^io �,ct 13�16 lS�aO 1 ua9 Water Temp. (°C) coestattt Turbidity (NTU) flO or:55NW O(� r } p ,� Dissolved Oxygen (mg/L) tlo % v9f RedOx PotentiaUORP (mV) tlomv COMMENTS/OBSERVATIONS: Date: `� By: jidL=,.- Page of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: .1 Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Pv L Field Personnel: 1W. Flammer J.Mueller Dedicated Pump: No ID #: ISO i- Date: 5 S ti Weather Conditions: Method of Well Evacuation: T, Total Well Depth in feet (TWD) Method of Sample Collection: pp Depth to Ground Water in feet (DGW) Well Yield (subjective): Ck. , A Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: 5. 1 'k 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Standard Evacuation Volume (3 casing volumes) _ Total Volume of Water Removed (go4on4 L 00 Time (military)�52 i355 135e 1'a0 i iLioy i4o� Volume Purged f6$HOW4(L) 0 Z1•oo Ii•�O 5.zo 5'160 fo''td -oJ Water Level (ft.) stable f\ • tic) 12.5i 12.5� i2 S6 12.56 pH (s.u.) 5- U Z S. 5 y' S S o 5 •L- -" 5 `%-�- Sp. Cond. (µmhos/cm) t to% 'E o Water Temp. (°C) coost 15 l53 I 1S 2 t2 tS Z ttoio.<srru LID . 4.(,] I -3'STurbidity(NTU) Dissolved Oxygen (mg/L) tto % 1.14 \. r{ i. l i b 1 $1 \ • i RedOx PotentiaUORP (mV) :tomv 52. 5 S6 _o 1t,-to cio 3 lob - 10% 1 kkts M` + 14 70. 2o0 `l,J Zbo 'LJJ COMMENTS/OBSERVATIONS: 0 kov Fee -. O.So o ? L- -A A vstc Date: '� `O�N By: Page —94-- of aceAnalyt' FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Z `' Site Name: gLbarrus County Sanitary Landfill Units 2 & 3 Casing Material: PVC, Field Personnel: V. Flammer 7.Mueller Dedicated Pump: mo ID#: 1SO2-Mw 3 DEEP Date: 5 -1 . i Weather Conditions: PX M-UA Method of Well Evacuation: Q Total Well Depth in feet (TWD) = y .,"t4 Method of Sample Collection: Q Depth to Ground Water in feet (DGW) = A • 6 j Well Yield (subjective): GOA Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: 5 $ . Cv �, 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = E �.k W l— % % 0q, 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = X Standard Evacuation Volume (3 casing volumes) _ Total Volume of Water Removed (gaU@m): �-) Time (military) kLk 2(, 1 "1 '6 t 1`131 ILiLi i 1 44 q 14S t Volume Purged 4QUens) L,. 0 i• o o i• G o Z. (, 0 3 Lk u y •4l) 5 Water Level (ft.) stable • b 3 . v�ti %. oy pH (s.u.) f.z l�.o� i7 �.�R e `�`� •°�� 6 `15 e `1`b Sp. Cond. (µmhos/cm) + 10% yi? DyZ 5t{ 2 �L, Z- 3 `i 3 Water Temp. (°C) constant }b. Ili 3 .y \S } 15 Turbidity(NTU) +10%or:55NTu (�.52 �.o'� '.�. \Z 10• `d•1'� `�.00 Dissolved Oxygen (mg/L) do% 1.1-1- 1 \- 6 1•1vio RedOx Potential/ORP (mV) fiomv 10y.11. (o u 3 Sy.� ;L\ • I- 2L1 1 16.'I. 4 .(1yv�l. yKivV —, 2(p 2-Lv 20-b 20L2 20'D Zoo COMMENTS/OBSERVATIONS: 0 &0 bo FP �A� VA Date: CD 4 - � � By: I -b Page ` C) of aceAnalyt/Cal ® FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: CAMP, DRESSER, & MCKEE, INC. - RALEIGH Casing Diameter: " Site Name: CABARRUS CO. SANITARY LF UNIT Field Personnel: Casing Material: C Dedicated Pump: No Well ID #: 1302 - Mw • E� Dater S 1 l - Weather Conditions: mod\ Method of Well Evacuation: Grundfos/Bailer/PeristalticABMV Total Well Depth in feet (TWD) = So, Method of Sample Collection: GrundfosBailer/Peristaltic Depth to Ground Water in feet (DGW) Well Yield (subjective): G b * 1 Sample Date and Time: 0 `t I 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = / PSI: sjp? 1 k- tT Recharge: Standard Evacuation Volume (3 casing volumes) / Discharge: 2 •� Total Volume of Water Removed ( ( • 9.2 o L Time (military) B °o -) ti-- J$SZ Q Is o'10 0 050-3 p'909 061;.7- vt5 01 Volume Purged (GaUens)t- 0 Oki 5 • 5 . (, u G . -to & `t o -I .Kp S. , wj Water Level (ft.) stable " "A - 35 . '+- b 3� • 3`\ '� ?I.'k I. 3'i I-1- 3`' �"k 3�•i3 '.:`i •�� '� h � � pH (s.u.) *.2 S'� (o S. a\ S. `A S S• `1 u S -3O) S `t c S 3o S •i L S S Z Sp. Cond. (µmhos/cm) t io % Li y 2. LAy °\ yS 3 k5 4%5 O list 415 0 Lis I '-tti 9 Water Temp. (°C) constant ki . -L 1 L' . l 1 '3 . 1p -b \'1 -I v" I \ 3,1�- Turbidity (NTU) t10%or:55NTu C; '-t lil Z • LA l 2.141 2.35 `j.-t \ .'k Dissolved Oxygen (mg/L) fiov 1. . -bl r) l \ . C\1 RedOx Potential/ORP (mV) fio,nv _11 \'3 1 Z v�l. 1bS • Z Z-� •`\ 1 �`?. lug ,� xi _o �3 1"b '% b } l.� ��-••— V Z o. 2. U L. p Z. U. 2 U Z o?. Z (U 2 COMMENTS/OBSERVATIONS: v o �v, UY/�, U ,55 TIrSTM� V$•�2 U�SL Fe2+ _ ,S mg/L Date: 5, 1 - \ By: ) \j 25 Page I S of acneAnalytical r FIELD DATA INFORMA TION L OG FOR GROUND -WATER SAMPLING Client: Camp,_ Dresser & McKee Inc. - Ralei h Casing Diameter: a" Site Name: Cabarrus Coun SphM Landfill Units 2 & 3 Casing Material: Field Personnel: W. Flammer J.Mueller Dedicated Pump: N0 Surface Water ID #: Date: Weather Conditions: -'AkVI q 0t Method of Well Evacuation: Total Well Depth in feet (TWD) _ (S,y Method of Sample Collection: : e( Depth to Ground Water in feet (DGW) _ (p Well Yield (subjective): 0 Length of Water Column (LWC) = TWD - DGW Sample Date and Time: 4SLS)f I 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = ,�• (� ( GQ01YA3 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.651 = —•All 1) Standard Evacuation Volume (3 casing volumes) _ , SC, (,5Q Total Volume of Water Removed (gallons): Time (military) Volume Purged (Gallons) 0 Water Level (ft.) stable pH (s.u.) t z Sp. Cond. (µmhos/cm) t io % t 9 Water Temp. (°C) constant I �'( ,0 Turbidity (NTU) *10%or55NTU (,{- 60+ Dissolved Oxygen (mg/L) do a ( 0 RedOx PotentiaUORP (mV) tto my - f 7 (, `% —23 COMMENTS/OBSERVATIONS: v pf— Date: qc1 By:1 /-1 q" A Page of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: -t " Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: f� Field Personnel: TV. Flamm 7.Mueller Dedicated Pump: t�Tp Surfhm'*'atef ID #: I3O Z - M k,s L- Date: S e1 , � n Weather Conditions: Ctt` (�( Method of Well Evacuation: jaI C &.&- Total Well Depth in feet (TWD) _ ,eA Method of Sample Collection: 1(.4({L Depth to Ground Water in feet (DGW) =12.0 `t Well Yield (subjective): -.s Length of Water Column (LWC) = TWD - DGW Sample Date and Time: IS. el _ vz,�, j L) 5 d 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 `t P013 3 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 Standard Evacuation Volume (3 casing volumes) Total Volume of Water Removed (gallons): 3 , o a Time (military) ;b Q'A' (wi—+ � O50 Volume Purged (Gallons) 0 j . o v Z • �'� ? ' Water Level (ft.) stable - pH (s.u.) t.z Sp. Cond. (µmhos/cm) t to % j u o Water Temp. (°C) constant ILA . 1 �t.Li i5 O Turbidity (NTU) tlo ioof<5NW Lre $ 00 } 0 v .4 6 e t Dissolved Oxygen (mg/L) tlo% . v 3 1.3 p .-i I k. 0; q RedOx Potentiat/ORP (mV) tlomv 1,31 1 y'}, 2 ITq - 3 ` o `'1 COMMENTS/OBSERVATIONS: o Date: By:_� Page of ane Analytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2`' Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: fvc Field Personnel: . Flammer Mueller Dedicated Pump: N ij ID#: t Date: S ti . %,°\ Weather Conditions: Method of Well Evacuation: At L . ¢ Total Well Depth in feet (TWD) = ")o 16 0 Method of Sample Collection: i L& Depth to Ground Water in feet (DGW) =1.1. -} 4. Well Yield (subjective): G o o.( Length of Water Column (LWC) = TWD - DGW = '� - Sample Date and Time: 5 , I ck F '1O ( S 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = o 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = )r i 3. t Li Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gallons): Time (military) (V o �� f u k u I v l t ( p 1 5 Volume Purged (Gallons) 0 I - SO 3. o • 0 0 Water Level (ft.) ale 1— — pH (s.u.) t.z Sp. Cond. (µmhos/cm) t 10% L(� 'L (, 7,'2 Water Temp. (°C) cons,t l 1 "3 a t Z • °t \. $ Turbidity(NTU) d0%or55rrru <600 S ca� %per Dissolved Oxygen (mg/L) tio^i I V (, 6 1 - C\,5 RedOx Potential/ORP (mV) tiomv COMMENTS/OBSERVATIONS: {CIOy Date: /((q Page aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: C batrus County Sanitary Landfill Units 2 & 3 Casing Material: Field Personnel: 4V. F er J.Mueller Dedicated Pump: i\rb SoFfese ID #: Date: Weather Conditions: I aA 1&lk Method of Well Evacuation: Total Well Depth in feet (TWD) = yl . `i Method of Sample Collection: Depth to Ground Water in feet (DGW) =Z'-1 • 3d 1 Well Yield (subjective): C^ o Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: S . a • �55 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = -FS*% '• b ,4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = )e— 12 Standard Evacuation Volume (3 casing volumes) _ Total Volume of Water Removed4gogom�- �L •. Time (military) ` ti (StA3 lS4 $ Is st t'S-Sy `ss-} Volume Purged 4QaUon4 f L� 0 oU ca 0-0 ," fo•LO 6 .%o Water Level (ft.) ale 24. 3o 1 .(0 2y • ^cul.t, IL -vi pH (s.u.) t.z • ��60 5 %-5 5 `i°I b 5 ^ (� v5 (o - oS Sp. Cond. (µmhos/cm) t 10 °}'} \ "k'klo 011'L `�S�b °I�� "\,%Lk Water Temp. (°C) co"stw, 20.y 1�.q i �- \'� 'J k -3 Turbidity (NTU) do i orn:5 NTU 1 S . 1'Z.. •35 `\ -lb 3 \ 2.2-S Dissolved Oxygen (mg/L) Nova 1 Sz) %AD 4 1 • �S 1.i.q .6`b h `-b RedOx Potential/ORP (mV) t,omv C3 V Tj 1-0 1-1.-4tA ' 1.� " i •'� L Z v Q I'Lu-o t o a i.l-b COMMENTS/OBSERVATIONS: p C,- 15'i Date: 5. "4- . N. I _ By: I )(�( Page 5 of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2 k., Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: QV L Field Personnel: 4. Flammer J.Mueller Dedicated Pump: k,Zo Swfece"WaterID #: % So 2 - Mvv - �E Date: (; % _ �� Weather Conditions: ;,,. Method of Well Evacuation: 7 Total Well Depth in feet (TWD) Method of Sample Collection: Depth to Ground Water in feet (DGW) = 2-V .Z 3 Well Yield (subjective): CA 4 Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: S. ,,tom C] Z 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = `35 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = yCF i Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gageas�- LL J L E�� t..r B "•17 Time (military) b ` y'5 bCjos'j OA to oe�k5 uq ?. 0 0123 bq'Lb Volume Purged * L 0 y . oU 1 4 "o (, o-a -+ . v b -A .60 ib.16 Water Level (ft.) stable '�3 mv; Z$ Nv Z$ 1:4 Z-2•\i 11% -i 2%.%-k- pH(s.u.) t.2 to �v 6.2a1 (D•30 4.21 b u; � 33 6--0\ Sp. Cond. (µmhos/cm) t io % q titi 1 Z(o `d'L i0 2 ;z Water Temp. (°C) constant i b• j b L 16 1 io +� I i, 1 la • y Turbidity (NTU) *10%or:55NM 'LS- 'Zt• 1 0• A -o L S �`� S• �� Dissolved Oxygen (mg/L) tio^i 2•'Io 2•Z-A- 2.01 1 A "5 1 qLA RedOx Potential/ORP (mV) tiomv ks6A, N-lb o %5 3 -h b -13 C4 "200.l COMMENTS/OBSERVATIONS: OX0 0 610S Date: Cn - Y, . \, By: �d -6 Page � of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: �.' Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Pd (- Field Personnel: W. Flammer J.Mueller Dedicated Pump: /)e) Surface Water ID #: �Oa-- Date: Weather Conditions: Method of Well Evacuation: ,Ae(' Total Well Depth in feet (TWD) = 3 A Method of Sample Collection: &Ae/i Depth to Ground Water in feet (DGW) = V, (31 Well Yield (subjective): Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: S /C, (& f 0 ` 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = k ACA a.00 ftL (am-r1r1hq00Mq 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 Standard Evacuation Volume (3 casing volumes) = 6,U0 Total Volume of Water Removed (gallons): Time (military) 1'1 Ll , "' .�> ; low(� Volume Purged (Gallons) 0 1- 00 LAI 00 6.0o Water Level (ft.) stable pH (s.u.) t.z 3� S G.S C 7 Sp. Cond. (µmhos/cm) fio Water Temp. (°C) constant � 4 , 3 1q, 3 U.3 Turbidity (NTU) t10vvor:55Y u 9004Wat SO�- � t Dissolved Oxygen (mg/L) do % X I U, Ct p • )- RedOx Potential/ORP (mV) ftoa,v - - - ;C1 COMMENTS/OBSERVATIONS: 60 NO 0 j Date: Page l of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2" Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Wc Field Personnel: W. Flammer 7.Mueller Dedicated Pump: 00 Surface Water ID #: Date: l`l Weather Conditions: `ou3, ve Method of Well Evacuation: Total Well Depth in feet (TWD) _ .-iI Method of Sample Collection: j j z(` Depth to Ground Water in feet (DGW) _ q,'9-3 Well Yield (subjective): PvQC Length of Water Column (LWC) = TWD - DGW = I I ,)- Sample Date and Time: v 11 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = .Ml00 5 — S 4 1 ( dny 4" Well: 1 Casing Volume in gallons CV = LWC x 0.653 = — "( Standard Evacuation Volume (3 casing volumes) = l D Total Volume of Water Removed (gallons): IfHr�,+YI Time (military) N Volume Purged (Gallons) 0 bb _ v 5 _ "' a•5 I Water Level (ft.) stable pH (s.u.) t.2 D c Sp. Cond. (µmhos/cm) t io % Water Temp. (°C) constant 1 j , Turbidity(NTU) ±10%or55NCU o-v Dissolved Oxygen (mg/L) tto % A d- RedOx Potential/ORP (mV) tlomv .. '` COMMENTS/OBSERVATIONS: CI�v,0�q o�� '1 Date: By' & of 1 6 Page aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Pvc Field Personnel: W. Flammer J.Mueller Dedicated Pump: A)8 Surface Water ID #: 1 O Date: Weather Conditions: Senn Method of Well Evacuation: Total Well Depth in feet (TWD) = 319a Method of Sample Collection: ; el" Depth to Ground Water in feet (DGW) _ '-Z 3S Well Yield (subjective): Length of Water Column (LWC) = TWD - DGW = S, Sample Date and Time: Q 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = t .00 M S - S" -"qPR,0-y 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = — Standard Evacuation Volume (3 casing volumes) = Q6 Total Volume of Water Removed (gallons): Time (military) �j 5 S� Volume Purged (Gallons) 0 l , 00 00 Water Level (ft.) stank — pH (s.u.) t.z 6, 1 r Sp. Cond. (µmhos/cm) t io % Water Temp. (°C) constant . Turbidity (NTU) :El0 or:55N U Q 06 goc�+ Dissolved Oxygen (mg/L) do % -3Ybr 35 30 41 RedOx Potential/ORP (mV) do env A0 IlLkA COMMENTS/OBSERVATIONS: Sti Ix- 6p� Date: By: e5 1 Page of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: (� Field Personnel: W. Flammer J.Mueller Dedicated Pump: d Surface Water ID Date: Weather Conditions: S",%kAq, Method of Well Evacuation: ai �ei Total Well Depth in feet (TWD) _ Method of Sample Collection: ' er Depth to Ground Water in feet (DGW) Well Yield (subjective): (-(q Length of Water Column (LWC) = TWD - DGW = 3 , t j Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Standard Evacuation Volume (3 casing volumes) Total Volume of Water Removed (gallons): Time (military) Volume Purged (Gallons) 0 Water Level (ft.) ale —-- pH (s.u.) t 2 6.31 , S 1 (. l,l- Sp. Cond. (µmhos/cm) t io % a3, 9,(� Water Temp. ('C) conStant tj .R Turbidity (NTU) ±10 or<sxru YQ Q Ot U0� 00 Dissolved Oxygen (mg/L) do % EA g 3 a. RedOx Potential/ORP (mV) domy j .. COMMENTS/OBSERVATIONS: Date: 5LC6 �( By: Page of ac�eAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: '' Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: VqU Field Personnel: W. Flammer 7.Mueller Dedicated Pump: 40 Surface Water ID #: - Date: S �1 Weather Conditions: 5,,,A t Method of Well Evacuation: SoAt ' Total Well Depth in feet (TWD) _ Method of Sample Collection: Depth to Ground Water in feet (DGW) _ Lk (,q3 Well Yield (subjective): G c- d Length of Water Column (LWC) = TWD - DGW = 13. GS- Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = Aj coo Mke-t5 sam6A-- 5" 4 ��Q 05L4 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = S Standard Evacuation Volume (3 casing volumes) _ \ , a Total Volume of Water Removed (gallons): \, Time (military) lLA 06 ` �- Volume Purged (Gallons) 0 4,OD _ Water Level (ft.) stable — — - pH (s.u.) t.2 1. 3� 6.33 Sp. Cond. (µmhos/cm) t to % kW 0 \3� Water Temp. (°C) constant \ 6. 3 , 1 Turbidity (NTU) ±10 or:55NW k-k q U�'f' 0 g � Dissolved Oxygen (mg/L) tlo% -I.S3 0 6,3w RedOx Potential/ORP (mV) tlomv LAq �?-7,9 COMMENTS/OBSERVATIONS: 1 Date: �l f By: Page —h— of 2 aecAnaiytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: i ' Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Field Personnel: W. Flammer J.Mueller Dedicated Pump: tab SurFwe4Av,eF ID #: 0 2 - M vim► Date: S ek . � Weather Conditions: Method of Well Evacuation: L60-- Total Well Depth in feet (TWD) Method of Sample Collection: F-- Depth to Ground Water in feet (DGW) Length of Water Column (LWC) = TWD - DGW Well Yield (subjective): Sample Date and Time: S `1 . @ j \2 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = .1 1 S• w , VC O O ( 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Y U' Standard Evacuation Volume (3 casing volumes) = 3 io 1 3 IS Total Volume of Water Removed (gallons): (. 15 C,,X Time (military) m5 i m Lj D 11 Volume Purged (Gallons) 0 i • i.TSib CA Water Level (ft.) stable — — -- pH (s.u.) t.z (o S� Sp. Cond. (µmhos/cm) t to % 14-5 Water Temp. (°C) constant < S - i S . "L J 1, • \ Turbidity (NTU) :H0 o<<_slaru SOO c g at -< %UD -+- Dissolved Oxygen (mg/L) tlo^i IN - v5 2 • `11 2 - � S RedOx Potential/ORP (mV) tlomv \,-\C1.2 1Su • 5� 5 COMMENTS/OBSERVATIONS: f OA (Sr, Date: �� (� By: Page ^�' �' of aceAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: (" Site Name: C barrus Couroy Sanitary Landfill Units 2 & 3 Casing Material: C. Field Personnel: V. Flammer 7.Mueller Dedicated Pump: ID#: k'�)OZ-MW-IL Date: Weather Conditions: Method of Well Evacuation: Total Well Depth in feet (TWD) ,.41 Method of Sample Collection: 13 c-\i L-6 (— Depth to Ground Water in feet (DGW) = I q. 6 I Well Yield (subjective): (Ao Q Length of Water Column (LWC) = TWD - DGW =' b . (.1 Sample Date and Time: 5 , 5, �\ [� lU l 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 =,-L. -1- 6 `\ s., S - (:'0 7 uZ7 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 =5e Standard Evacuation Volume (3 casing volumes) _ 'tg % .S 0 Total Volume of Water Removed (gallons): $ . S O Time (military) Volume Purged (Gallons) 0 b 8 -S a Water Level (ft.) stable — — pH (s.u.) t .z , 1 1 5 `1 b 5.10 . o Sp. Cond. (µmhos/cm) f 10% 720, 111 18t Water Temp. (°C) constant iS . 7- i s- 0 1 S-L Turbidity (NTU) t10%or55NM &43@;bX 1� 0-,Y- IL)4 Dissolved Oxygen (mg/L) tio% 1 • �'5 Z •4,; RedOx Potential/ORP (mV) tiomV C\ .4(. G. L 110 .5 '1 �o . v COMMENTS/OBSERVATIONS: n 0 v A6C . Date: By: Page �� of aceAnaiyticai FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Z" Site Name: Qpbarrus County Sanitary Landfill Units 2 & 3 Casing Material: pvt, Field Personnel: 4V. Flammer 7.Mueller Dedicated Pump: Nl? ID #: I')ol - rt�,., - 1. Date: 5 - x t--, Weather Conditions: 0.�\ , � Method of Well Evacuation: TIC' Total Well Depth in feet (TWD) = 11- - 3 t, Method of Sample Collection: P(' Depth to Ground Water in feet (DGW) = 13\. � `e I Well Yield (subjective): pp Length of Water Column (LWC) = TWD - DGW = - - Sample Date and Time: 5 • $ - i 15 S 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 =— i, '• IO.t!)' 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = )( Standard Evacuation Volume (3 casing volumes) = -- Total Volume of Water Removed (gallettsj: (0'. Time(military) ['S l-4- 15314 15610 I94115y(, i5yq iSSZ IS55 IsS$ Volume Purged (•6a{Heesj- (L 0 4v1 o 5.21 5 $O b�0 '�.00 `j •60 1 "Lo Water Level (ft.) stable 0 .Ns \n.0 io.ol IOK I IV.iu io•lu tc•ko \u.w tD to pH(s.u.) t.z =r.Vti G $y f..bi c) •toy ..3"6 5-lti 5.1°1 5-i8 1 5.i2 Sp. Cond. (µmhos/cm) f 10 MIS rv� `� 3 C\\ �61 `� `� `i t °\ \ �t Water Temp.(°C) constant �i�.� �b 0 [S 0 1K.S \w 5 1•'i Turbidity (NTU) do % er <s Nru Dissolved Oxygen (mg/L) :io % -k ci i • `b L 1- $-5 %S \ . b,3 1 • `b � k 10 RedOx Potentiat/ORP (mV) do my `S 2°t •O CS . s 16.1 rr 3.1� 13 \ . `\ 13' j N 0 %� -L- l� 1, fv�,v_ — S b o Zt� Zov 2o-o 2 o u "wv COMMENTS/OBSERVATIONS: hi�ii olt b� Date- 5 ' \05.. By: ' X —� ` Page 11 1 of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Cam , Dresser & McKee Inc. - Raleigh Casing Diameter: -" Site Name: C barrus County Sanitary Landfill Units 2 & 3 Casing Material: wc- Field Personnel: 4. Fla nmer J.Mueller Dedicated Pump: N0 Sw ID #: 1307.- Mw - t DEE F Date: 5. 16. Weather Conditions: Method of Well Evacuation: Total Well Depth in feet (TWD) = (o`l.2cj Method of Sample Collection: Q (' Depth to Ground Water in feet (DGW) = 1\.35 Well Yield (subjective): L,Oa) Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: 5 $ . lc\ 2 �vjj 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 1q • S l 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (g&Hcrmj- ( L) : 'k. b O Time (military) ILO 1rp I lO w \ q t (.1-L, \ 6 "t5 1 bi i Volume Purged 0 1• u 0 1 \. (* 0 2• t v 1. ' 0 3 `16 �. 0 u Water Level (ft.) ale k1 .%< II.yy \1 •si- I1.gS i-1,51 II pH(s.u.) t.z L Vol (-oI (,•o3 G.0( �•0� � 1D Sp. Cond. (µmhos/cm) t 10 `I 1ti 'to 3 10 �s rW -!> Water Temp. (°C) con-stant y.5 14. 0 13 k3. 13.,+ 1'S • 13 Dr Turbidity (NTU) do io or = s NTT (� S S 10. G •2t �J. i 2 •5 to �} .y9 y 5 z Dissolved Oxygen (mg/L) do % I m 1. 11 k - o 1 • � 1 l 5 i \ • d \ q 0 RedOx Potential/ORP (mV) tiomv 1,515 •3 kvL-krA ,n.� 2vu 2vo 2�v 2uro �� 2v'b COMMENTS/OBSERVATIONS: U,0 ;, r, X, Date: r� �� By: Page { 2--of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: '1 Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: 1�(i Field Personnel: W. Flammer 7.Mueller Dedicated Pump: QUO Surface Water ID #: Date: .0 g 1 ,C1 Weather Conditions: cloady,cte Method of Well Evacuation: r Total Well Depth in feet (TWD) = 30(, i ( Method of Sample Collection: Depth to Ground Water in feet (DGW) = '-1. S 6 Well Yield (subjective): Length of Water Column (LWC) = TWD - DGW = , (S Sample Date and Time: R (& 0 f 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = '3, 6 ( 3_?S pAetcxS avID1 nj - Q ! 5 667 /a 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = — - Standard Evacuation Volume (3 casing volumes) _ ().(t ,Do Total Volume of Water Removed (gallons): R .00 M Time (military) 01 3q Dcf Volume Purged (Gallons) 0 3."2S -7, SrQ it, 00 Water Level (ft.) stable - -` -- - pH (s.u.) f z �S� C. r -3 Sp: Cond. (µmhos/cm) = io^i 3 )D ',2G ;( ;LY-7 Water Temp. (°C) constant 6A i S. `r I -,-7 Turbidity (NTU) *10%or!:5NW voov SDO} V + Dissolved Oxygen (mg/L) do % 2 , RedOx Potential/ORP (mV) tiomv IN 0 ULi , COMMENTS/OBSERVATIONS: AJO 40" Date: Page J-7— of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2 `' Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: Pv C, Field Personnel: Ytf Flammer Mueller Dedicated Pump: 00 ID #: i ;o L. - IA Date: S t , l A Weather Conditions: 'kLM , ML(C� Method of Well Evacuation: $Ki L_6 a_ Total Well Depth in feet (TWD) = V2 b Method of Sample Collection: 13KtLev -. Depth to Ground Water in feet (DGW) = %3.21 Well Yield (subjective): G o,)r% Length of Water Column (LWC) = TWD - DGW Sample Date and Time: S • 11 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 =' kt CEO �+ 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = ,3 Standard Evacuation Volume (3 casing volumes) _ .g b I •Sb Total Volume of Water Removed (gallons): I • SD C,,), Time (military) SUS 6 IIOZ i 10 1111 Volume Purged (Gallons) 0 3 iS 050 1-S 5 Water Level (ft.) stable pH (s.u.) t z Sp. Cond. (µmhos/cm) t to% Water Temp. (°C) constant �� _ a- 3 . i i 3 •°l `� Turbidity (NTU) t10%or_ 5 N7U � 0-0 � ob F �d�'�►-� `� u Dissolved Oxygen (mg/L) tto% • 15 2 l 'Z•4.- 0 1 •'�3 RedOx Potential/ORP (mV) ttomv II COMMENTS/OBSERVATIONS: Date: � � L By: V� Page �` of ac+eAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 'Z`• Site Name: Cabarrus County Sanitary Landfill Units 2 & 3 Casing Material: �"3 V Field Personnel: Flammer J.Mueller Dedicated Pump: lvo D#: 1'S07- v,&-1.0 Date: lb $ .\c-\ Weather Conditions: CVcA . 4 Method of Well Evacuation: (C C' Total Well Depth in feet (TWD) = Method of Sample Collection: Fyp Depth to Ground Water in feet (DGW) = Lit,. 6% Well Yield (subjective): w4 Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = leg\ SO 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = ('.ef tk.5 Standard Evacuation Volume (3 casing volumes) = vol, $•S Total Volume of Water Removed Fgegen*. to >ip Ev.A i.' Lt \ - 0 � Time (military) \1�0\ ILS°I M)4 i1Jct ► 21y 1 -41104 \22'i 'A729 Volume Purged 0 k 0 u 5 u is po '4 .00 `� 00 .uo ib.ao Water Level (ft.) stable y(,. -e\0 14 0, % �•1'E !�5 41.0 i Lkcl\.0!" 11R•Vi- yq.cZ PH (s.u.) *,2 5 J\ �i (VIA S. (Do 5 S'l 5 5 k 5.5 3 5 5 b 5- S b Sp. Cond. (µmhos/cm) * 10 j Lo M 'bq \ ' V\ `1-10 5%0 1^05 S �2 Water Temp. ('C) constant 1'14 is -to \ 5 •S 1 b. 3 1 °� . u '� C \ •� Turbidity(NTU) t10iors5NTu 10: %.`6`b i�, ��= 1Z• 1�. Ib• 9.3� Dissolved Oxygen (mg/L) =io % 2.1 % 1.1 0, 1-14 1 • vi 1. io 5 1 • I N RedOx Potential/ORP (mV) tiotnv \ 13q.6 %I\- \ 1 \ \ •S low •1 1Z. % �1�• M✓ — 20: 2ov 2vo w� �w �o a Zoo COMMENTS/OBSERVATIONS: oho 1 1 o V'i t o 'S's 2 id L Date: 5 • o By: PY\(.9 � tPage 9 of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Z" Site Name: C barrus County Sanitary Landfill Units 2 & 3 Casing Material: @v C, Field Personnel: . Flammer J.Mueller Dedicated Pump: %->a D#: 13�2- MW-i Date: 5 ? , k-`\ Weather Conditions: �o.,�, r • Method of Well Evacuation: �F Total Well Depth in feet (TWD) = Cam-- -N% Method of Sample Collection: Depth to Ground Water in feet (DGW) = b. vS Well Yield (subjective): Goy Length of Water Column (LWC) = TWD - DGW = I Sample Date and Time: S. 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = IF S Lio 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = )0-" 1;-!LF \2 Standard Evacuation Volume (3 casing volumes) = 16 • 3 Total Volume of Water Removed 4gal wsu -. Z. 'A '� 0 L C.. w L '• - o ��� Time (military) \o ,t S \ 03% Wi(o WW1 It 105'Z \055 to��$ 1�01 1104{ Volume Purged (Gallen+ L 0 A• ,Do S. o Q 5 .6 o ro 2 0 b o o i % boa Water Level (ft.) stable 1% .05 LI-A i-�-0,A `n .o°t �1 .0°� h-, Oct `i, 09 y-v.oq y-1.05 4-4.ol 'A-1.c)i pH (s.u.) t 2 io • `i° 10 b - 51 C9 .'A 1 5 • $ k 511 5. i 5.5 5 5 - 2,1 S-v-\ s • z 3 Sp. Cond. (µmhos/cm) t 10 % 21 \ N Io 20 Z- to L' 10(, 10 "- 20 b 20 C. Zo`i Water Temp. (°C) constant I6 .`t �b .3 i5 1S.q t5 - (0 �7 .i, �S •"} i5 .5 �S S 15.5 15 •� Turbidlty(NTU) flo"het<srrru %p • i .S �- 5-53 505 `1 -4u I 3.52 Z 35 1`b Dissolved Oxygen (mg/L) do % -L, C\"1 '1. `b i . S A 2.36 7 -' 4 2 •3 ` 1.1 1 j `t 1. 50 `.50 RedOx Potential/0" (mV) tiomv "'1-�b.^ ` b`� •S - S%.5 `b 2%•k 'k Is4.\ 10.3 ��1.5 %'+-3 ab.5 ML- "Lo 3 1 200 200 200 ` ov 1 100 IOU 2vo �,uU COMMENTS/OBSERVATIONS: 0(� ► 02, Date: rj . ti BY '4 Page of aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2 it Site Name: C arrus County Sanitary Landfill Units 2 & 3 Casing Material: PvC— Field Personnel: Flammer J.Mueller Dedicated Pump: N J ID #: JkM N - -40 Date: S -+ , � Weather Conditions: Method of Well Evacuation: eq Total Well Depth in feet (TWD) =& 2 . $c4 Method of Sample Collection: Depth to Ground Water in feet (DGW) _ i p. i Y Well Yield (subjective): CAoo Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: S . t , lO� 1 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = MA: 30 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 Uf I 12 Standard Evacuation Volume (3 casing volumes) = 1 S • 3 Total Volume of Water Removed (.galloaes \.- '} . (.o p l_ ", V )3 , Time (military) k255b 14 `: O ILAIs 1 14LS 1 4Z� Volume Purged 46allep0 �L 0 . o 0 Water Level (ft.) stable l I q • �� 9 3 3 `� ZJ°J l q •3 3 ``i • 33 pH (s.u.) t.2 S . S I S oq l�•l0 (.., l0 Sp. Cond. (µmhos/cm) f 10 T-i 0% 15 3 'LsQ 25 � "cS Io 15 to Water Temp. (°C) constant 1 S 2 2S • O 20 �— Zo 1 20 •2 -20 . Turbidity (NTU) t1o%or_<5NTU 1� • $ . `0 • 10. . } 6� .1v Dissolved Oxygen (mg/L) fioio 1; I•5 2.5b 2.5� i•5S RedOx Potential/ORP (mV) fiomv x "V Li -'L t \6'l.2 i ( 1..0 \162.s tro COMMENTS/OBSERVATIONS:" CJ k I \V "X Date: � � By: _ Page of aceAnalytica! FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Z Site Name: C arrus County Sanitary Landfill Units 2 & 3 Casing Material: PVC.' Field Personnel: VV. Flammer J.Mueller Dedicated Pump: Nv ID#: 1302-1 W-2 Date: 5 , l Weather Conditions: Method of Well Evacuation: Total Well Depth in feet (TWD) _ 4i O, 01 Method of Sample Collection: Depth to Ground Water in feet (DGW) = k $ `l Well Yield (subjective). Length of Water Column (LWC) = TWD - DGW = Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = PS) 2jb 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = >C I -L . Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gallons): 1 • 20 l-- Time (military) 03 Volume Purged (G4lom4 t. 0 'i • 00 5• 00 LO Water Level (ft.) stable l ej 1 i O IR •t0 \°l• 1'2 1\� .13 (a1.1 pH(s.u.) f.z 5. q b S.y\ S.Z,S� S•2} S.2j6 Sp. Cond. (µmhos/cm) f io % tti Z. 15 Water Temp. (°C) constant 1 •� .O \ t� \ to . 2 b . 16. 1- Turbidity (NTU) do io or <- s NTT 40, �'� • l fo -20 G 6 `�� Dissolved Oxygen (mg/L) fio^i - (,'Z \ • b U •%t7 1.�5 �3 1 }� RedOx Potential/ORP (mV) do tnv \ ,b 1 `15 .i, V\`b .L 2b o • i Zs l \ COMMENTS/OBSERVATIONS: 4e,,.. 0 TOO—' = W r C r.3• •• � 3 Date: ^ 6 Page 'S of / � aceAnalyt' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: NA Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: NA Field Personnel: W.Flammer J.Mueller Dedicated Pump: NA Surface Water ID Date: Weather Conditions: Method of Well Evacuation: NA Total Well Depth in feet (TWD) = NA Method of Sample Collection: NA Depth to Ground Water in feet (DGW) = NA Well Yield (subjective): NA Length of Water Column (LWC) = TWD - DGW = NA Sample Date and Time: 1 ti j S 2" Well: I Casing Volume in gallons (CV) = LWC x (NA 4" Well: I Casing Volume in gallons (CV) = LWC x (NA Standard Evacuation Volume (3 casing volumes) = NA Total Volume of Water Removed (gallons): NA Time (military) it Volume Purged (Gallons) 0 Water Level (ft.) stable pH (s.u.) t 2 Sp. Cond. (µmhos/cm) t io % 3S'� Water Temp. (°C) constant Turbidity (NTU) do %o.<srw 10 Dissolved Oxygen (mg/L) fio % . 0 G RedOx Potential/ORP (mV) tiotnv Z p , n COMMENTS/OBSERVATIONS: `,b-&-/l Ro C) Date: By: � - --- �% Page L of acreAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: NA Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: NA Field Personnel: W.Flammer J.Mueller Dedicated Pump: NA Surface Water ID #: Date: Weather Conditions: Method of Well Evacuation: NA Total Well Depth in feet (TWD) = NA Method of Sample Collection: NA Depth to Ground Water in feet (DGW) = NA Well Yield (subjective): NA Length of Water Column (LWC) = TWD - DGW = NA Sample Date and Time: ( 2" Well: 1 Casing Volume in gallons (CV) = LWC x (NA 4" Well: 1 Casing Volume in gallons (CV) = LWC x (NA Standard Evacuation Volume (3 casing volumes) = NA Total Volume of Water Removed (gallons): NA Time (military) Volume Purged (Gallons) 0 Water Level (ft.) ale -- pH (s.u.) t .z Sp. Cond. (µmhos/cm) t io% iA13 Water Temp. (°C) constant 1c1 . q Turbidity (NTU) +10 or:55NTu Dissolved Oxygen (mg/L) tio^i Ste, RedOx PotentiaUORP (mV) tiotav 'lL _ COMMENTS/OBSERVATIONS: I ( 0( 1 �'d1nJ r t Date: ,S ?ci 1 By: lr- Page 11!;a'ceAna1j&a( wmpacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 04, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County CD-1 s and CD1 d Pace Project No.: 2618286 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory between May 08, 2019 and May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 46 11!;a'ceAna1j&a1" wmpacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Matrix Date Collected Date Received 2618286001 1302-CD-1S Water 05/07/19 09:06 05/08/19 10:00 2618286002 1302-CD-1D Water 05/07/1912:05 05/08/1910:00 2618427010 1302-CD-1S Water 05/07/19 08:50 05/10/19 09:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618286001 1302-CD-1S EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618286002 1302-CD-1D EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.26 Std. Units 1 Field Temperature 15.0 deg C 1 Field Specific Conductance 116 umhos/cm 1 Field Turbidity 7.13 NTU 1 Field Oxidation Potential 242.4 mV 1 Oxygen, Dissolved 1.82 mg/L 1 Depth to Water 28.11 feet 1 Iron, Ferrous 0.0 mg/L 1 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) Date: 06/04/2019 02:17 PM ND ug/L 5.0 1 ND ug/L 5.0 1 29.8 ug/L 5.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 638 ug/L 40.0 1 ND ug/L 1.0 1 17.6 ug/L 10.0 1 1.3J ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 1.0 1 7.OJ ug/L 10.0 1 5.11 uq/L 10.0 1 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 7782-44-7 N2 05/23/19 13:38 05/23/19 13:38 05/13/1918:04 05/14/1916:38 7440-36-0 05/13/1918:04 05/14/1916:38 7440-38-2 05/13/1918:04 05/14/1916:38 7440-39-3 05/13/1918:04 05/14/1916:38 7440-41-7 05/13/1918:04 05/14/1916:38 7440-43-9 05/13/1918:04 05/14/1916:38 7440-47-3 05/13/1918:04 05/14/1916:38 7440-48-4 05/13/1918:04 05/14/1916:38 7440-50-8 05/13/1918:04 05/14/1916:38 7439-89-6 05/13/1918:04 05/14/1916:38 7439-92-1 05/13/1918:04 05/14/1916:38 7439-96-5 05/13/1918:04 05/14/1916:38 7440-02-0 05/13/1918:04 05/14/1916:38 7782-49-2 05/13/1918:04 05/14/1916:38 7440-22-4 05/13/1918:04 05/14/1916:38 7440-28-0 05/13/1918:04 05/14/1916:38 7440-62-2 05/13/1918:04 05/14/1916:38 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:02 7439-97-6 Analytical Method: EPA 8260D ND ug/L 1.0 1 05/15/1917:05 630-20-6 ND ug/L 1.0 1 05/15/1917:05 71-55-6 ND ug/L 1.0 1 05/15/1917:05 79-34-5 ND ug/L 1.0 1 05/15/1917:05 79-00-5 ND ug/L 1.0 1 05/15/1917:05 75-34-3 ND ug/L 1.0 1 05/15/1917:05 75-35-4 ND ug/L 1.0 1 05/15/1917:05 96-18-4 ND ug/L 2.0 1 05/15/1917:05 96-12-8 ND ug/L 2.0 1 05/15/1917:05 106-93-4 ND ug/L 1.0 1 05/15/1917:05 95-50-1 ND ug/L 1.0 1 05/15/1917:05 107-06-2 ND ug/L 1.0 1 05/15/1917:05 78-87-5 ND ug/L 1.0 1 05/15/1917:05 106-46-7 ND ug/L 5.0 1 05/15/1917:05 78-93-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 2-Hexanone ND ug/L 5.0 1 05/15/19 17:05 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:05 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:05 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:05 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:05 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:05 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:05 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:05 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:05 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:05 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:05 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:05 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:05 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:05 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:05 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:05 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:05 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:05 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:05 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:05 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:05 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:05 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:05 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:05 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:05 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:05 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:05 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:05 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:05 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 05/15/19 17:05 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:05 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/17/19 20:27 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 104 % 50-150 1 05/17/19 20:27 17060-07-0 Toluene-d8 (S) 122 % 50-150 1 05/17/19 20:27 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 43000 ug/L 20000 1 05/09/19 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 158000 ug/L 10000 1 05/14/19 19:16 D6 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 11:30 05/13/19 15:51 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1914:25 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/08/19 13:00 05/13/19 13:10 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 359 ug/L 50.0 1 05/09/19 13:23 14797-55-8 H1 9056 IC Anions Analytical Method: EPA 9056A Chloride 2930 ug/L 1000 1 05/23/19 04:21 16887-00-6 Sulfate 12600 ug/L 5000 1 05/23/19 04:21 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.69 Std. Units 1 05/23/19 13:38 Field Temperature 18.3 deg C 1 05/23/19 13:38 Field Specific Conductance 114 umhos/cm 1 05/23/19 13:38 Field Turbidity 9.14 NTU 1 05/23/19 13:38 Field Oxidation Potential 183.2 mV 1 05/23/19 13:38 Oxygen, Dissolved 1.61 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 26.89 feet 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-36-0 Arsenic ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-38-2 Barium 30.7 ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-39-3 Beryllium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-43-9 Chromium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-47-3 Cobalt ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-48-4 Copper 1.4J ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-50-8 Iron 517 ug/L 40.0 1 05/13/1918:04 05/14/1916:43 7439-89-6 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7439-92-1 Manganese 9.7J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7439-96-5 Nickel ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7440-28-0 Vanadium 7AJ ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-62-2 Zinc 2.9J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:04 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 17:31 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 17:31 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 17:31 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 17:31 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 17:31 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 17:31 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:31 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:31 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:31 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:31 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:31 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:31 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:31 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:31 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:31 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:31 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:31 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:31 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:31 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:31 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:31 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:31 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:31 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:31 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:31 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:31 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:31 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:31 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:31 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:31 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:31 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:31 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:31 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:31 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:31 1868-53-7 4-Bromofluorobenzene (S) 95 %. 82-120 1 05/15/19 17:31 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/19/19 11:24 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 128 % 50-150 1 05/19/19 11:24 17060-07-0 Toluene-d8 (S) 115 % 50-150 1 05/19/19 11:24 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 52000 ug/L 20000 1 05/09/19 15:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 134000 ug/L 10000 1 05/14/19 19:16 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 80.8 ug/L 50.0 1 05/09/19 11:55 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 2840 ug/L 1000 1 05/30/19 07:20 16887-00-6 Sulfate 3140J ug/L 5000 1 05/30/19 07:20 14808-79-8 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28287 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127417 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/13/1919:46 LABORATORY CONTROL SAMPLE: 127418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127419 127420 MS MSD 2618405004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.2 2.2 88 87 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28295 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127445 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L ND 5.0 05/14/1915:22 Arsenic ug/L ND 5.0 05/14/1915:22 Barium ug/L ND 5.0 05/14/1915:22 Beryllium ug/L ND 0.50 05/14/1915:22 Cadmium ug/L ND 0.50 05/14/1915:22 Chromium ug/L ND 5.0 05/14/1915:22 Cobalt ug/L ND 5.0 05/14/1915:22 Copper ug/L ND 5.0 05/14/1915:22 Iron ug/L ND 40.0 05/14/1915:22 Lead ug/L ND 1.0 05/14/1915:22 Manganese ug/L ND 10.0 05/14/1915:22 Nickel ug/L ND 5.0 05/14/1915:22 Selenium ug/L ND 5.0 05/14/1915:22 Silver ug/L ND 5.0 05/14/1915:22 Thallium ug/L ND 1.0 05/14/1915:22 Vanadium ug/L ND 10.0 05/14/1915:22 Zinc ug/L ND 10.0 05/14/1915:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 127446 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 96.7 97 80-120 Arsenic ug/L 100 97.1 97 80-120 Barium ug/L 100 95.6 96 80-120 Beryllium ug/L 100 99.5 99 80-120 Cadmium ug/L 100 97.0 97 80-120 Chromium ug/L 100 98.1 98 80-120 Cobalt ug/L 100 98.9 99 80-120 Copper ug/L 100 99.2 99 80-120 Iron ug/L 1000 988 99 80-120 Lead ug/L 100 95.9 96 80-120 Manganese ug/L 100 101 101 80-120 Nickel ug/L 100 97.5 98 80-120 Selenium ug/L 100 98.8 99 80-120 Silver ug/L 100 99.0 99 80-120 Thallium ug/L 100 95.8 96 80-120 Vanadium ug/L 100 99.9 100 80-120 Zinc ug/L 100 102 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127447 127448 MS MSD 2618227008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.0 93.7 98 94 75-125 5 20 Arsenic ug/L ND 100 100 92.7 92.9 93 93 75-125 0 20 Barium ug/L 37.6 100 100 131 127 93 89 75-125 3 20 Beryllium ug/L ND 100 100 104 101 103 101 75-125 3 20 Cadmium ug/L ND 100 100 95.7 94.7 96 95 75-125 1 20 Chromium ug/L ND 100 100 98.9 98.4 98 98 75-125 1 20 Cobalt ug/L ND 100 100 98.0 97.3 98 97 75-125 1 20 Copper ug/L ND 100 100 98.0 101 97 100 75-125 3 20 Iron ug/L 517 1000 1000 1010 1900 49 139 75-125 61 20 M1,R1 Lead ug/L ND 100 100 94.0 91.4 94 91 75-125 3 20 Manganese ug/L 80.7 100 100 180 187 99 107 75-125 4 20 Nickel ug/L ND 100 100 97.6 95.5 97 95 75-125 2 20 Selenium ug/L ND 100 100 95.7 95.1 96 95 75-125 1 20 Silver ug/L ND 100 100 101 98.1 101 98 75-125 3 20 Thallium ug/L ND 100 100 94.2 91.9 94 92 75-125 2 20 Vanadium ug/L ND 100 100 100 98.8 99 98 75-125 2 20 Zinc ug/L ND 100 100 102 103 98 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28431 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127981 Associated Lab Samples: 2618286001, 2618286002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,1-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethene ug/L ND 1.0 05/15/19 11:28 1,2,3-Trichloropropane ug/L ND 1.0 05/15/19 11:28 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/15/19 11:28 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/15/19 11:28 1,2-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 1,2-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,2-Dichloropropane ug/L ND 1.0 05/15/19 11:28 1,4-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 2-Butanone (MEK) ug/L ND 5.0 05/15/19 11:28 2-Hexanone ug/L ND 5.0 05/15/19 11:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/15/19 11:28 Acetone ug/L ND 25.0 05/15/19 11:28 Acrylonitrile ug/L ND 50.0 05/15/19 11:28 Benzene ug/L ND 1.0 05/15/19 11:28 Bromochloromethane ug/L ND 1.0 05/15/19 11:28 Bromodichloromethane ug/L ND 1.0 05/15/19 11:28 Bromoform ug/L ND 1.0 05/15/19 11:28 Bromomethane ug/L ND 2.0 05/15/19 11:28 Carbon disulfide ug/L ND 10.0 05/15/19 11:28 Carbon tetrachloride ug/L ND 1.0 05/15/19 11:28 Chlorobenzene ug/L ND 1.0 05/15/19 11:28 Chloroethane ug/L ND 1.0 05/15/19 11:28 Chloroform ug/L ND 1.0 05/15/19 11:28 Chloromethane ug/L ND 1.0 05/15/19 11:28 cis-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 cis-1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Dibromochloromethane ug/L ND 1.0 05/15/19 11:28 Dibromomethane ug/L ND 1.0 05/15/19 11:28 Ethylbenzene ug/L ND 1.0 05/15/19 11:28 lodomethane ug/L ND 10.0 05/15/19 11:28 Methylene Chloride ug/L ND 1.0 05/15/19 11:28 Styrene ug/L ND 1.0 05/15/19 11:28 Tetrachloroethene ug/L ND 1.0 05/15/19 11:28 Tetrahydrofuran ug/L ND 10.0 05/15/19 11:28 Toluene ug/L ND 1.0 05/15/19 11:28 trans-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 V1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 METHOD BLANK: 127981 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Trichloroethene ug/L ND 1.0 05/15/19 11:28 Trichlorofluoromethane ug/L ND 1.0 05/15/19 11:28 Vinyl acetate ug/L ND 2.0 05/15/19 11:28 Vinyl chloride ug/L ND 1.0 05/15/19 11:28 Xylene (Total) ug/L ND 2.0 05/15/19 11:28 1,2-Dichloroethane-d4 (S) %. 93 81-119 05/15/19 11:28 4-Bromofluorobenzene (S) %. 96 82-120 05/15/19 11:28 Dibromofluoromethane (S) %. 98 82-114 05/15/19 11:28 Toluene-d8 (S) %. 100 82-109 05/15/19 11:28 LABORATORY CONTROL SAMPLE: 127982 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.3 113 68-137 1,1,1-Trichloroethane ug/L 50 57.8 116 72-134 1,1,2,2-Tetrachloroethane ug/L 50 59.1 118 51-158 1,1,2-Trichloroethane ug/L 50 57.5 115 78-131 1,1-Dichloroethane ug/L 50 60.8 122 69-151 1,1-Dichloroethene ug/L 50 63.8 128 64-158 1,2,3-Trichloropropane ug/L 50 45.1 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 48.6 97 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.5 113 71-134 1,2-Dichlorobenzene ug/L 50 54.9 110 70-135 1,2-Dichloroethane ug/L 50 54.2 108 72-129 1,2-Dichloropropane ug/L 50 60.3 121 64-135 1,4-Dichlorobenzene ug/L 50 52.8 106 70-131 2-Butanone (MEK) ug/L 100 101 101 52-143 2-Hexanone ug/L 100 87.1 87 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 71-129 Acetone ug/L 100 88.7 89 48-224 Acrylonitrile ug/L 200 205 103 66-154 Benzene ug/L 50 57.5 115 68-132 Bromochloromethane ug/L 50 58.6 117 73-133 Bromodichloromethane ug/L 50 56.8 114 67-121 Bromoform ug/L 50 56.6 113 57-125 Bromomethane ug/L 50 48.0 96 35-156 Carbon disulfide ug/L 100 103 103 47-141 Carbon tetrachloride ug/L 50 64.4 129 66-122 L1,v1 Chlorobenzene ug/L 50 56.6 113 71-126 Chloroethane ug/L 50 47.3 95 43-143 Chloroform ug/L 50 51.3 103 71-136 Chloromethane ug/L 50 53.0 106 47-123 cis-1,2-Dichloroethene ug/L 50 61.1 122 74-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 LABORATORY CONTROL SAMPLE: Parameter 127982 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.9 116 78-120 Dibromochloromethane ug/L 50 56.4 113 65-115 Dibromomethane ug/L 50 62.9 126 79-129 Ethylbenzene ug/L 50 58.5 117 68-129 lodomethane ug/L 100 97.3 97 49-154 Methylene Chloride ug/L 50 56.8 114 61-147 Styrene ug/L 50 61.4 123 77-128 Tetrachloroethene ug/L 50 53.1 106 51-139 Tetrahydrofuran ug/L 100 101 101 56-147 Toluene ug/L 50 54.7 109 60-133 trans-1,2-Dichloroethene ug/L 50 63.4 127 69-144 trans- 1,3-Dichloropropene ug/L 50 50.0 100 74-128 Trichloroethene ug/L 50 54.2 108 73-126 Trichlorofluoromethane ug/L 50 59.1 118 55-132 Vinyl acetate ug/L 50 54.2 108 52-141 Vinyl chloride ug/L 50 51.5 103 50-133 Xylene (Total) ug/L 150 181 121 78-132 1,2-Dichloroethane-d4 (S) %. 92 81-119 4-Bromofluorobenzene (S) %. 95 82-120 Dibromofluoromethane (S) %. 95 82-114 Toluene-d8 (S) %. 97 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 55.2 48.8 110 98 68-137 12 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 61.0 53.7 122 107 66-142 13 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 60.5 50.2 121 100 39-171 19 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 56.6 50.8 113 102 73-136 11 12 1,1-Dichloroethane ug/L ND 50 50 57.6 54.2 115 108 66-155 6 15 1,1-Dichloroethene ug/L ND 50 50 66.9 63.4 134 127 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 43.4 35.3 87 71 78-133 21 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 47.2 38.4 94 77 58-124 21 15 R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.6 47.5 113 95 71-134 17 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 56.2 46.9 112 94 69-135 18 10 R1 1,2-Dichloroethane ug/L ND 50 50 54.3 49.3 109 99 36-159 10 10 1,2-Dichloropropane ug/L ND 50 50 60.0 53.0 120 106 68-132 12 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 54.0 47.7 108 95 49-153 12 9 R1 2-Butanone (MEK) ug/L ND 100 100 96.5 82.0 97 82 10-189 16 23 2-Hexanone ug/L ND 100 100 83.2 67.8 83 68 40-135 20 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 98.2 83.6 98 84 30-177 16 10 R1 (MIBK) Acetone ug/L ND 100 100 86.0 75.6 80 70 44-223 13 14 Acrylonitrile ug/L ND 200 200 191 160 95 80 13-189 18 12 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L ND 50 50 57.6 52.4 115 105 66-139 9 10 Bromochloromethane ug/L ND 50 50 59.4 53.3 119 107 73-133 11 13 Bromodichloromethane ug/L ND 50 50 55.5 49.5 111 99 57-120 11 13 Bromoform ug/L ND 50 50 53.5 44.4 107 89 48-128 18 13 R1 Bromomethane ug/L ND 50 50 37.8 39.3 76 79 10-187 4 32 Carbon disulfide ug/L ND 100 100 111 101 111 101 47-141 9 322 Carbon tetrachloride ug/L ND 50 50 72.2 64.1 144 128 58-127 12 14 MOM Chlorobenzene ug/L ND 50 50 55.2 48.2 110 96 63-137 14 10 R1 Chloroethane ug/L ND 50 50 50.6 45.5 101 91 52-146 11 16 Chloroform ug/L ND 50 50 50.5 46.5 101 93 74-137 8 9 Chloromethane ug/L ND 50 50 53.7 49.1 107 98 41-127 9 10 cis-1,2-Dichloroethene ug/L ND 50 50 60.1 54.4 120 109 71-138 10 16 cis-1,3-Dichloropropene ug/L ND 50 50 56.5 51.6 113 103 32-145 9 12 Dibromochloromethane ug/L ND 50 50 54.9 47.6 110 95 52-116 14 13 R1 Dibromomethane ug/L ND 50 50 60.9 52.8 122 106 79-129 14 14 Ethylbenzene ug/L ND 50 50 57.7 51.3 115 103 31-174 12 10 R1 lodomethane ug/L ND 100 100 95.6 107 96 107 49-154 12 30 Methylene Chloride ug/L ND 50 50 56.0 51.0 112 102 61-146 9 15 Styrene ug/L ND 50 50 60.2 52.4 120 105 77-128 14 14 Tetrachloroethene ug/L ND 50 50 56.5 50.9 113 102 36-155 10 14 Tetrahydrofuran ug/L ND 100 100 98.8 83.6 99 84 56-147 17 12 R1 Toluene ug/L ND 50 50 57.1 50.1 114 100 52-146 13 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 65.9 58.5 132 117 61-152 12 14 trans-1,3-Dichloropropene ug/L ND 50 50 48.6 41.7 97 83 37-146 15 12 R1 Trichloroethene ug/L ND 50 50 53.7 49.4 107 99 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.3 61.4 135 123 51-141 9 13 Vinyl acetate ug/L ND 50 50 49.9 44.4 100 89 52-141 12 14 Vinyl chloride ug/L ND 50 50 58.8 54.6 118 109 22-156 7 26 Xylene (Total) ug/L ND 150 150 179 159 119 106 78-132 12 7 RS 1,2-Dichloroethane-d4 (S) %. 96 95 81-119 4-Bromofluorobenzene (S) %. 98 96 82-120 Dibromofluoromethane (S) %. 97 98 82-114 Toluene-d8 (S) %. 98 98 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 475936 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286001 METHOD BLANK: 2578807 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/17/19 12:15 1,2-Dichloroethane-d4 (S) % 100 50-150 05/17/19 12:15 Toluene-d8 (S) % 114 50-150 05/17/19 12:15 LABORATORY CONTROL SAMPLE: 2578808 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578809 2578810 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.3 20.2 96 101 50-150 5 30 1,2-Dichloroethane-d4 (S) % 92 90 50-150 30 Toluene-d8 (S) % 82 81 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286002 METHOD BLANK: 2579453 Associated Lab Samples: 2618286002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/19/1910:45 102 50-150 05/19/1910:45 113 50-150 05/19/1910:45 LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 25.7 20.3 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28076 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126363 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/09/19 13:54 LABORATORY CONTROL SAMPLE: 126364 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 101000 101 85-115 SAMPLE DUPLICATE: 126365 2618202009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 123 mg/L 124000 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28369 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 2618286001, 2618286002 LABORATORY CONTROL SAMPLE: 127730 Parameter Units Total Dissolved Solids ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 400000 403000 101 84-108 SAMPLE DUPLICATE: 127731 2618286001 Dup Parameter Units Result Result Total Dissolved Solids ug/L 158000 133000 Max RPD RPD Qualifiers 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28239 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2618286001 METHOD BLANK: 127270 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 05/13/19 15:36 LABORATORY CONTROL SAMPLE: 127271 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 203000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127272 127273 MS MSD 2618152001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 11400 5000000 5000000 1630000 1610000 99 96 90-110 1 10 mg/L 0 0 MATRIX SPIKE SAMPLE: 127274 2618152003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 11200 mg/L 5000000 16200000 100 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28184 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2618286001 METHOD BLANK: 126976 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide ug/L ND 200 05/10/1914:19 LABORATORY CONTROL SAMPLE: 126977 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 452 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126978 126979 MS MSD 2618407004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 ND ND 39 38 30-129 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28001 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618286001 METHOD BLANK: 125904 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/13/19 12:52 1A LABORATORY CONTROL SAMPLE: 125906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 205000 104 85-115 1A SAMPLE DUPLICATE: 125957 2618270001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1110 mg/L 1270000 13 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28053 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126307 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L ND 50.0 05/09/19 14:29 LABORATORY CONTROL SAMPLE: 126308 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9630 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126309 126310 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 359 10000 10000 9640 9600 93 92 90-110 0 15 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28932 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001 METHOD BLANK: 130388 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 81.OJ 1000 05/23/19 03:39 Sulfate ug/L 23.OJ 5000 05/23/19 03:39 LABORATORY CONTROL SAMPLE: 130389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10500 105 90-110 Sulfate ug/L 10000 11000 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130390 130391 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2930 10000 10000 13300 13200 104 103 90-110 1 15 Sulfate ug/L 12600 10000 10000 22300 22300 97 98 90-110 0 15 MATRIX SPIKE SAMPLE: 130392 2618688001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L ND 5000000 5160000 101 90-110 Sulfate ug/L ND 5000000 5420000 107 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 29257 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286002 METHOD BLANK: 131872 Matrix: Water Associated Lab Samples: 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 78.OJ 1000 05/30/19 06:38 Sulfate ug/L 35.OJ 5000 05/30/19 06:38 LABORATORY CONTROL SAMPLE: 131873 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9910 99 90-110 Sulfate ug/L 10000 9940 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 131874 131875 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2840 10000 10000 12600 12400 98 95 90-110 2 15 Sulfate ug/L 3140J 10000 10000 12800 12700 97 95 90-110 1 15 MATRIX SPIKE SAMPLE: 131888 2619009001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L 11.6 mg/L 10000 21200 96 90-110 Sulfate ug/L ND 10000 10900 104 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28426 Analysis Method: EPA 9060A QC Batch Method: EPA 9060A Analysis Description: 9060A Total Organic Carbon Associated Lab Samples: 2618286001 METHOD BLANK: 127954 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 LABORATORY CONTROL SAMPLE: 127955 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19100 96 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 18900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127956 127957 MS MSD 2618406001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20000 19800 84 83 85-115 1 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19900 19600 84 82 85-115 2 10 M1 Total Organic Carbon ug/L 3.3 mg/L 20000 20000 20300 19800 85 82 85-115 3 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20100 20100 84 85 85-115 0 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19500 19800 81 83 85-115 2 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127958 127959 MS MSD 2618294001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 1040 20000 20000 19000 18900 90 89 85-115 1 10 Total Organic Carbon ug/L 1040 20000 20000 19000 19000 90 90 85-115 0 10 Total Organic Carbon ug/L 1020 20000 20000 18200 18800 86 89 85-115 3 10 Total Organic Carbon ug/L 1030 20000 20000 19400 19100 92 90 85-115 2 10 Total Organic Carbon ug/L 1060 20000 20000 19300 18600 91 88 85-115 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 46 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW'pacalabsxom (770)734-4200 QUALIFIERS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA BATCH QUALIFIERS Batch: 28232 The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. ANALYTE QUALIFIERS 1A The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618286001 1302-C D-1 S 28595 2618286002 1302-CD-1 D 28595 2618286001 1302-CD-IS EPA3005A 28295 EPA6020B 28307 2618286002 1302-CD-ID EPA3005A 28295 EPA6020B 28307 2618286001 1302-CD-1S EPA 7470A 28287 EPA 7470A 28296 2618286002 1302-CD-1 D EPA 7470A 28287 EPA 7470A 28296 2618286001 1302-CD-1 S EPA 8260D 28431 2618286002 1302-CD-1 D EPA 8260D 28431 2618286001 1302-CD-1S EPA 8260D Mod. 475936 2618286002 1302-CD-ID EPA 8260D Mod. 476071 2618286001 1302-CD-1S SM 2320E 28076 2618286002 1302-CD-1D SM 2320E 28076 2618286001 1302-CD-IS SM 2540C 28369 2618286002 1302-CD-ID SM 2540C 28369 2618286001 1302-CD-1S EPA410.4 28239 EPA410.4 28257 2618286001 1302-CD-IS SM 4500-S2 D 28184 2618286001 1302-CD-1S SM 5210E 28001 SM 5210B 28232 2618286001 1302-CD-1 S EPA 9056A 28053 2618286002 1302-CD-1 D EPA 9056A 28053 2618286001 1302-CD-1S EPA 9056A 28932 2618286002 1302-CD-1 D EPA 9056A 29257 2618286001 1302-CD-1S EPA 9060A 28426 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 46 INIA� kaelul saldweg NIA JekOOa PaIE05 R sn I NIA) eel U uo pOA100e8 S s iN1A1 ew�oluO Ienplsatl O ul dW31 cl euexolu-• r [ WIso9Ze x x uC yr ro 0. VOSRiIUIIBMktl 'SOS x x esoueBurtp4'uoi1'R3Nokav4 slaloiN I ddV x x (ue6olpRH] seseO s10 x w. r (Vjnk seseD par.{ossip x (3'3'W'Zoo)sase0 sl❑ x uogioO aluebio lelol x �c ❑-ZS-OO,trWS Rq ap111nS x Qvv x y EON REPS COG �C � Sr2 6 a d 3r11d 09Z9 OOA I ddV x x NIA JsaJL sas,Sjei1y m iayko c E ° C W a w laueykeynJ 7 U g EOZSZ10N HOUN z 13H n n v u� £ONH E4 POSZH s m 2 pa+uasaidun H G. StJ:i NfV iND�i�• 'n G L L) L a (1 6 a NOl1D3110) IV dN31 3ldvm, � W N ¢ ❑ uwi u! W E 1[ z � a uuii a W F Ix ¢ Ix a 0 O C7 C � WW C W O N ❑ o c tJ r � p L1 x m 7 _ {dkN OO=7 9VtsEJ•O1 3dA131dWt'S f w c} svpv p•le• Ycsj V 30077CIZj1:'6 F a W `m v m w [C a m$ p �L° o m T a $$ w y °n 7 V (0 00 � N 0 � O C as f E p W a s 1 N C N E m a Q y O V O �� V d a o z w f Y ■` [� Page 31 of 46 # W311 •- rt ro •r In ua ti m m c ,.. N .- N d' U Q 2 13J 0. Q: ConditionSample .. r FaceAnaOicaf Client Name: LD M Wo# : i 28 1 8285 FM: SMM Due Date: 05 CL"NT: �DM-Raleigh I21/4 g Courier: _mod Ex �] UPS [15P� � Client ❑ Commercial Pace Other Tracking #: / [ If Custody Seal on CoolerlBox Present: J�Ys i] no Seals intact: ,W yes no Proj. Due Date: Proj. Name: Packing Material: Bubble Wrap '�ubble Baas —1 None 7 Other I -r L.-._w. ..-....-4. i i--a (I }i - � 7,,-., -f Ira- /11 od R1i.n Nnnp F—i irr rrmlino orocess has henun Cooler Temperature Temp should be above freezing to 6 C Biological Tissue is Frozen: rras ran Comments: Date nd Initial of ers mining c6 tents: Chain of Custody Present: rr:, ❑r•lo ❑N+A 4 Chain of Custody Filled Out: LJ�ZNG EN;A 2- Chain of Custody Relinquished: "+G =N A 3. Sampler Name & Signature on COC: r ONc, ❑N;A 4. Samples Arrived within Hold Time: ,o ]NSA 5. Short Hold Time Analysis (<72hr): r—" '1•, LE A 6. Rush Turn Around Time Requested: ElYes L�' J A 7. Sufficient Volume. —N 4 S. Correct Containers Used• -Pace Containers Used: '=':• Uk,67GNn DNA DNIA 9. Containers Intact: s E]N0 LN+A 11-0 Filtered volume received for Dissolved tests `lvrrs Sample Labels match COC: -Includes dalelt,melld/Analysis Matrix:__� Grin _ -Nra. 12 All Containers needing pre+servalisn have been checked. Ail containers needing preservation are found to be in es ❑No compliance with EPA recommendation. e:ceptons. ! A. ^,ri'nnr., 0 .OSG 1".'!•DR4 'rra!erl IGNc ❑N±A Initial when Lot 4 added completed preser alive Samples checked for dechlonnalion: ores ONO 'W 14- Headspace In VOA Vials ( >6mm): Gyes a EX (. i" 0MZ12 Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): =yes 'Grwr, ❑Yes ONv 2 . A ,3'A 16 Client Notification) Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: DatelTime Field data Requ,recP Y 11 t•i Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be Con itication Office { i.e out of hold- incorrect preservalive, out of temp. incorrecl containers) lu the North Carolina 0EHNR Page 32 of 46 F-AGLCO03rev 3, 1lSeplember2006 ?ceAnalytical i May 23, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618286 Pace Workorder. 30306 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Friday, May 10, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/23/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 14 Page 1 of 10 Page 33 of 46 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 10 Page 34 of 46 ?ceAnalytical @ SAMPLE SUMMARY Workorder: 30306 CABARRUS COUNTY / 2618286 Lab ID Report ID: 30306 - 1167062 �rtiecp Sample ID 1302-CD-1 S Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Matrix Date Collected Date Received 19V= CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. 5/7/2019 09:06 5/10/2019 10:30 Page 3 of 10 Page 35 of 46 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303060001 Sample ID: 1302-CD-1S Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 09:06 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0431.11 mg/I 0.20 0.043 1 5/15/2019 16:29 KB Acetic Acid 0.032J mg/I 0.10 0.028 1 5/15/2019 16:29 KB Propionic Acid 0.00401.11 mg/I 0.10 0.0040 1 5/15/2019 16:29 KB Formic Acid 0.17J mg/I 0.50 0.086 1 5/15/2019 16:29 KB Butyric Acid 0.0111,11 mg/I 0.10 0.011 1 5/15/2019 16:29 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/15/2019 16:29 KB i-Pentanoic Acid 0.00601.11 mg/I 0.10 0.0060 1 5/15/2019 16:29 KB Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/15/2019 16:29 KB i-Hexanoic Acid 0.0291.11 mg/I 0.20 0.029 1 5/15/2019 16:29 KB Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/15/2019 16:29 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.053J ug/I 0.50 0.046 1 5/15/201911:53 BW n Ethane 0.00501.11 ug/I 0.10 0.0050 1 5/15/201911:53 BW n Ethene 0.00401.11 ug/I 0.10 0.0040 1 5/15/201911:53 BW n Carbon Dioxide 50 mg/I 5.0 0.45 1 5/15/2019 11:53 BW n Report ID: 30306 - 1167062 Page 4 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 36 of 46 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 5 of 10 Page 37 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: DISG/7535 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303060001 METHOD BLANK: 61187 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.046U 0.046 n Ethane ug/I 0.0050U 0.0050 n Ethene ug/I 0.0040U 0.0040 n METHOD BLANK: 61188 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 0.45U 0.45 n LABORATORY CONTROL SAMPLE & LCSD: 61189 61191 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 760 740 101 99 80-120 1.7 20 n Ethane ug/I 38 39 38 104 101 80-120 3.1 20 n Ethene ug/I 35 36 35 103 98 80-120 4.9 20 n LABORATORY CONTROL SAMPLE & LCSD: 61190 61192 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 120 110 106 97 80-120 9.1 20 n Report ID: 30306 - 1167062 Page 6 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 38 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: EDON/4075 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 303060001 METHOD BLANK: 61209 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028U 0.028 Propionic Acid mg/I 0.0040U 0.0040 Formic Acid mg/I 0.086U 0.086 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 61210 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 109 70-130 Acetic Acid mg/I 2 2.1 103 70-130 Propionic Acid mg/I 2 2.0 102 70-130 Formic Acid mg/I 2 2.0 101 70-130 Butyric Acid mg/I 2 2.0 103 70-130 Pyruvic Acid mg/I 2 2.1 106 70-130 i-Pentanoic Acid mg/I 2 2.0 99 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 i-Hexanoic Acid mg/I 2 1.8 91 70-130 Hexanoic Acid mg/I 2 1.9 94 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.22 20 22 22 107 108 70-130 1.3 30 d Acetic Acid mg/I 29 20 50 50 104 105 70-130 0.29 30 d Report ID: 30306 - 1167062 Page 7 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 39 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Propionic Acid mg/I 5.6 20 26 26 104 103 70-130 0.53 30 d Formic Acid mg/I 1.6 20 21 21 99 99 70-130 0.23 30 d Butyric Acid mg/I 0.84 20 22 22 107 106 70-130 1.1 30 d Pyruvic Acid mg/I 0.29 20 22 22 107 107 70-130 0.01 30 d i-Pentanoic Acid mg/I 0.38 20 21 21 105 103 70-130 1.9 30 d Pentanoic Acid mg/I 0.57 20 22 22 107 105 70-130 2 30 d i-Hexanoic Acid mg/I 0 20 21 20 106 101 70-130 4.9 30 d Hexanoic Acid mg/I 0.15 20 22 22 108 107 70-130 0.69 30 d Report ID: 30306 - 1167062 Page 8 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 40 of 46 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 QUALITY CONTROL PARAMETER QUALIFIERS The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 9 of 10 Page 41 of 46 ?ceAnalytical QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 303060001 1302-CD-1S AM20GAX DISG/7535 303060001 1302-CD-1 S AM23G EDON/4075 Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 10 Page 42 of 46 I I 0 G) fl) 0 CD CD (a 3 3(D 0 w w w 0 E CD :3 0 (D (D > M 0 =1 0 ;y 0 Ey (D 40(a O o D N 3 w 3-, CD ro 0 -01 (D -U —04 51 (D N) N 0 CD a) 0 (D > w , (@ w 0 0 Q) 0 X CD (c) z (0D PI) (D 0 3 Z) -D a 0 0 0 0 S U) 0 00 cr CL 00 CAI (D O c� 0 CD ro t CD CL 71) z 0 lot HCL Unpreser,,ed 0 CD 0 0 SD < CD (D >< Sub Dissolved Carbon Dioxide A z cn A) 0 3 (D (D fJ2,1 f z m 0 z 9 R 0 0 0 0 c:) ro Page 43Pof 46 Cooler Receipt Forte_ ~e C .- Lab Work Order: Client Name. �" Project: A. Shipping/Container tnformation (circle appropriate response) Courier: FedEx UPS USPS Client Other: Air bill Present: Yes,' No Tracking Number Custody Seal on Cooler/Box Present: Yes',No Seals lntac Yes No Cooler/Box Packing Material: bubble Wrap Absorbent Foam Other: Type of lce (Wet; Blue None Ice Intact: l'es, Melted �_.. Cooler Temperature: t,- Radiation Screene€�: Yes �o Chain of Custody Present: Yes' No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES I NO I N/A Comment Reference non -Conformance Chain of Custody properly filled out I Chain of Custody relinquished It . Sampler Name & Signature on CDC Containers intact Were samples in separate bags i Sample container labels match CDC Sample name/date and time collected Sufficient volume provided PAES containers used Are containers properly preserved for the requested testing? (as labeled) L`yes, see pH form• if an unknown preservation state, were containers checked? Exception: VOA's coliform i Was volume for dissolved testing field filtered, as noted on the CDC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by Date, Project Manager Review : Date: J 30ct2017 Page 44 of 46 Xjoj-CONFoyo,/ LkNCE FORT✓ M W, )k- PAn_ ES WDTY Order =l '� Ti-nt of ReCeTl: cum tp'� FOR !,one xr ACTJON TAKEN": ch u--n4i- curoms so -ice Whals: _aw-- 20 T�ov'—)014 Dattl T =, e: - Page 45 of 46 Page 1 of 2 Emma Louis - CDM Sub outs, in Summary (3 Pace Atlanta Projects) From: Sakina Mckenzie To: Louis, Emma Date: 5/10/2019 1:16 PM Subject: CDM Sub outs, in Summary (3 Pace Atlanta Projects) C K",. Cc: Welsh, Ruth Hi Emma, Just in Summary, there are 10 samples total, for Dissolved Carbon Dioxide, Dissolved Hydrogen, Methane/Ethane/ Ethene, and Volatile Fatty Acids. Well 1302-CD-1S is separate on one project, #2618286 The other Wells are split between 2618294 (Dissolved Carbon Dioxide, Methane/Ethane/Ethene and Volatile Fatty Acids) and 2618427 Dissolved Hydrogen only. Thank you, I am so sorry. It must be hot in the field, I can't figure out what these field guys are doing with this event. Sakina Sakina -Af.-AfcXenzie Senior Project Manager Pace Analytical Services LLC. 110 Technology Pkwy NW Peachtree Corners, GA 30092 Main: 770-734-4200 ( Direct: 770-734-4204 Internal: 264204 Sakina.McKenzie@pacelabs.com >>> Sakina Mckenzie 5/10/2019 12:43 PM >>> Hi Emma, Not sure what our field samplers did, but they sampled all of the Dissolved Hydrogen separate from the rest of the parameters that we shipped to you (Carbon Dioxide, Volatile Fatty Acids, and M/E/E). I am logging the Dissolved Hydrogen now (2618427), so disregard this analysis when the samples arrive today for the rest of those parameters. Page 46 of 46 file:///C:/Users/elouis/AppData/Local/Temp/XPgrpwise/5CD579COPACE DOMAINPAE... 5/10/2019 11!;a'ceAna1j&a( wmpacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 May 31, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory between May 08, 2019 and May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 182 11!;a'ceAna1j&a1" wmpacelabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID Matrix Date Collected Date Received 2618294001 1302-AMW-2D Water 05/07/1914:28 05/08/1910:00 2618294002 1302-AMW-2S Water 05/07/1913:18 05/08/1910:00 2618294003 1302-MW-E Water 05/07/1915:57 05/08/1910:00 2618294004 1302-AMW-1d Water 05/08/19 12:29 05/09/19 09:40 2618294005 1302-AMW-1s Water 05/08/19 11:07 05/09/19 09:40 2618294006 1302-MW-3 Water 05/08/19 14:07 05/09/19 09:40 2618294007 1302-MW-3 deep Water 05/08/19 14:52 05/09/19 09:40 2618294008 1302-MW-E deep Water 05/08/19 09:26 05/09/19 09:40 2618294009 1302-MW-L Water 05/08/19 15:58 05/09/19 09:40 2618294010 1302-MW-L deep Water 05/08/19 16:28 05/09/19 09:40 2618294011 1302-MW-A Water 05/09/19 09:18 05/10/19 09:20 2618294012 1302-CD-4 Rep Water 05/07/19 10:25 05/10/19 14:10 2618294013 1302-CD-4 Rep Water 05/08/19 08:43 05/10/19 14:10 2618294014 1302-MW-1 Water 05/08/1912:54 05/10/19 14:10 2618294015 1302-MW-1 Water 05/09/19 08:34 05/10/19 14:10 2618294016 1302-MW-B Water 05/08/1911:45 05/10/19 14:10 2618294017 1302-MW-B Water 05/09/19 08:23 05/10/19 14:10 2618294018 1302-MW-C Water 05/09/1910:50 05/10/19 14:10 2618294019 1302-MW-C Water 05/10/19 07:33 05/10/19 14:10 2618294020 1302-MW-D Water 05/09/1910:15 05/10/19 14:10 2618294021 1302-MW-D Water 05/10/19 07:20 05/10/19 14:10 2618294022 1302-MW-F Water 05/08/1910:52 05/10/19 14:10 2618294023 1302-MW-F Water 05/09/19 08:14 05/10/19 14:10 2618294024 1302-MW-G Water 05/08/1912:16 05/10/19 14:10 2618294025 1302-MW-G Water 05/09/19 08:29 05/10/19 14:10 2618294026 1302-MW-H Water 05/08/1916:05 05/10/19 14:10 2618294027 1302-MW-H Water 05/09/19 08:59 05/10/19 14:10 2618294028 1302-MW-H DEEP Water 05/08/19 15:43 05/10/19 14:10 2618294029 1302-MW-H DEEP Water 05/09/19 08:56 05/10/19 14:10 2618294030 1302-MW-1 Water 05/08/1914:27 05/10/19 14:10 2618294031 1302-MW-1 Water 05/09/19 08:47 05/10/19 14:10 2618294032 1302-MW-J Water 05/09/1910:35 05/10/19 14:10 2618294033 1302-MW-J Water 05/10/19 08:01 05/10/19 14:10 2618294034 1302-MW-K Water 05/09/1910:35 05/10/19 14:10 2618294035 1302-MW-K Water 05/10/19 07:27 05/10/19 14:10 2618294036 1302-MW-M Water 05/09/19 09:41 05/10/19 14:10 2618294037 1302-MW-M Water 05/10/19 07:12 05/10/19 14:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 182 11!;a'ceAna1j&a1" WNW'pecalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID Matrix Date Collected Date Received 2618294038 1302-MW-X Water 05/09/1911:11 05/10/19 14:10 2618294039 1302-MW-X Water 05/10/19 07:49 05/10/19 14:10 2618294040 1302-DUPLICATE Water 05/08/19 00:00 05/10/19 14:10 2618294041 1302-DUPLICATE Water 05/09/19 00:00 05/10/19 14:10 2618294042 1302-Equipment Blank Water 05/10/19 13:05 05/10/19 14:10 2618294043 1302-Trip Blank Water 05/07/19 00:00 05/10/19 14:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 182 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618294001 1302-AMW-2D EPA 6020E CSW 15 PASI-GA EPA 8270E MKI 7 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294002 1302-AMW-2S EPA 6020E CSW 15 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294003 1302-MW-E EPA 6020E CSW 15 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294004 1302-AMW-1d EPA6020B KLH 15 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA EPA410.4 ANB 1 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 182 11!;a'ceAna1j&a1" WNW'pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID Method Analysts Analytes Reported Laboratory SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294005 1302-AMW-1s EPA6020B KLH 15 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294006 1302-MW-3 EPA 6020E KLH 15 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A MWB 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294007 1302-MW-3 deep EPA 6020E KLH 15 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294008 1302-MW-E deep EPA 6020E KLH 15 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8270E MKI 7 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 182 11!;a'ceAna1j&a1" WNW'pacelabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID Method Analysts Analytes Reported Laboratory EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B KN 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A MWB, RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294009 1302-MW-L EPA 6020E KLH 15 PASI-GA EPA 7470A DRB 1 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA EPA410.4 ANB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294010 1302-MW-L deep EPA 6020E KLH 15 PASI-GA EPA 7470A DRB 1 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294011 1302-MW-A EPA 6020E KLH 15 PASI-GA EPA 7470A DRB 1 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A MWB 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618294012 1302-CD-4 Rep EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294013 1302-CD-4 Rep EPA 6020E KLH 15 PASI-GA 2618294014 1302-MW-1 EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 182 11!;a'ceAna1j&a1" wrvw.pacelabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 2618294015 1302-MW-1 EPA 6020E KLH 15 PASI-GA 2618294016 1302-MW-B EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294017 1302-MW-B EPA 6020E KLH 15 PASI-GA 2618294018 1302-MW-C EPA 8270E JRS 7 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294019 1302-MW-C EPA 6020E KLH 15 PASI-GA 2618294020 1302-MW-D EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294021 1302-MW-D EPA 6020E KLH 15 PASI-GA 2618294022 1302-MW-F EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294023 1302-MW-F EPA 6020E KLH 15 PASI-GA 2618294024 1302-MW-G EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294025 1302-MW-G EPA 6020E KLH 15 PASI-GA 2618294026 1302-MW-H EPA 8270E JRS 7 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294027 1302-MW-H EPA 6020E KLH 15 PASI-GA 2618294028 1302-MW-H DEEP EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294029 1302-MW-H DEEP EPA 6020E KLH 15 PASI-GA 2618294030 1302-MW-1 EPA 8270E JRS 7 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294031 1302-MW-1 EPA 6020E KLH 15 PASI-GA 2618294032 1302-MW-J EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294033 1302-MW-J EPA 6020E KLH 15 PASI-GA 2618294034 1302-MW-K EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294035 1302-MW-K EPA 6020E KLH 15 PASI-GA 2618294036 1302-MW-M EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294037 1302-MW-M EPA 6020E KLH 15 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 8 of 182 11!;a'ceAna1j&a1" WNW'pacelabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 2618294038 1302-MW-X EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294039 1302-MW-X EPA 6020E KLH 15 PASI-GA 2618294040 1302-DUPLICATE EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294041 1302-DUPLICATE EPA 6020E KLH 15 PASI-GA 2618294042 1302-Equipment Blank EPA 6020E KLH 15 PASI-GA EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618294043 1302-Trip Blank EPA 8260D LIH 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2D Lab ID: 2618294001 Collected: 05/07/19 14:28 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.08 Std. Units 1 05/22/19 11:39 Field Temperature 20.2 deg C 1 05/22/19 11:39 Field Specific Conductance 256 umhos/cm 1 05/22/19 11:39 Field Turbidity 9.10 NTU 1 05/22/19 11:39 Field Oxidation Potential 165.2 mV 1 05/22/19 11:39 Oxygen, Dissolved 2.55 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 18.18 feet 1 05/22/19 11:39 Iron, Ferrous 0.0 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-36-0 Arsenic ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-38-2 Barium 74.6 ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-39-3 Beryllium 0.18J ug/L 0.50 1 05/13/1918:04 05/14/1916:49 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:49 7440-43-9 Chromium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-47-3 Cobalt ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-48-4 Copper 2.7J ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-50-8 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1916:49 7439-92-1 Nickel 2.7J ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1916:49 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1916:49 7440-28-0 Vanadium 3.3J ug/L 10.0 1 05/13/1918:04 05/14/1916:49 7440-62-2 Zinc 11.6 ug/L 10.0 1 05/13/1918:04 05/14/1916:49 7440-66-6 8270E MSSV Water Analytical Method: EPA 8270E Preparation Method: EPA 3510C bis(2- Ethyl hexyl)phthalate ND ug/L 15.0 1 05/10/19 15:45 05/11/19 02:47 117-81-7 Surrogates Nitrobenzene-d5 (S) 63 %. 13-107 1 05/10/19 15:45 05/11/19 02:47 4165-60-0 2-Fluorobiphenyl (S) 69 %. 12-129 1 05/10/19 15:45 05/11/19 02:47 321-60-8 Phenol-d6 (S) 20 %. 10-46 1 05/10/19 15:45 05/11/19 02:47 13127-88-3 2-Fluorophenol (S) 36 %. 10-64 1 05/10/19 15:45 05/11/19 02:47 367-12-4 2,4,6-Tribromophenol (S) 83 %. 10-148 1 05/10/19 15:45 05/11/19 02:47 118-79-6 p-Terphenyl-d14 (S) 83 %. 14-147 1 05/10/19 15:45 05/11/19 02:47 1718-51-0 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/1917:56 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/1917:56 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/1917:56 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/1917:56 79-00-5 1,1-Dichloroethane 18.8 ug/L 1.0 1 05/15/1917:56 75-34-3 1,1-Dichloroethene 0.81J ug/L 1.0 1 05/15/1917:56 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/1917:56 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/1917:56 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 17:56 106-93-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2D Lab ID: 2618294001 Collected: 05/07/19 14:28 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:56 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 17:56 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 17:56 78-87-5 1,4-Dichlorobenzene 0.65J ug/L 1.0 1 05/15/19 17:56 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 17:56 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 17:56 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:56 108-10-1 Acetone 18.2J ug/L 25.0 1 05/15/19 17:56 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:56 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:56 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:56 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:56 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:56 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:56 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:56 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:56 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:56 75-00-3 Chloroform 0.97J ug/L 1.0 1 05/15/19 17:56 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:56 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:56 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:56 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:56 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:56 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:56 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:56 100-42-5 Tetrachloroethene 3.1 ug/L 1.0 1 05/15/19 17:56 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:56 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:56 108-88-3 Trichloroethene 3.9 ug/L 1.0 1 05/15/19 17:56 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:56 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:56 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:56 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:56 1330-20-7 cis-1,2-Dichloroethene 13.5 ug/L 1.0 1 05/15/19 17:56 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:56 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:56 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:56 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:56 17060-07-0 Dibromofluoromethane (S) 99 %. 82-114 1 05/15/19 17:56 1868-53-7 4-Bromofluorobenzene (S) 98 %. 82-120 1 05/15/19 17:56 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:56 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/17/19 19:08 123-91-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2D Lab ID: 2618294001 Collected: 05/07/19 14:28 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV SIM Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 410.4 COD Chemical Oxygen Demand 4500S2D Sulfide Water Sulfide 5210B BOD, 5 day BOD, 5 day 9056 IC Anions 48hr Nitrate as N 9056 IC Anions Chloride Sulfate 9060A Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D Mod. 101 % 50-150 1 05/17/1919:08 17060-07-0 120 % 50-150 1 05/17/1919:08 2037-26-5 Analytical Method: SM 2320B 132000 ug/L 20000 1 05/09/1915:38 Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 ND ug/L 10000 1 05/13/1913:20 05/13/1916:05 Analytical Method: SM 4500-S2 D ND ug/L 200 1 05/10/1914:25 18496-25-8 Analytical Method: SM 5210B Preparation Method: SM 5210B ND ug/L 2000 1 05/08/1913:00 05/13/1913:27 3A Analytical Method: EPA 9056A ND ug/L 50.0 1 05/09/1912:39 14797-55-8 Analytical Method: EPA 9056A 3590 ug/L 1000 1 05/10/19 23:47 16887-00-6 618J ug/L 5000 1 05/10/19 23:47 14808-79-8 Analytical Method: EPA 9060A 1030 ug/L 1000 1 05/16/1917:28 7440-44-0 1040 ug/L 1000 1 05/16/1917:28 7440-44-0 1060 ug/L 1000 1 05/16/1917:28 7440-44-0 1020 ug/L 1000 1 05/16/1917:28 7440-44-0 1040 ug/L 1000 1 05/16/1917:28 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2S Lab ID: 2618294002 Collected: 05/07/19 13:18 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.24 Std. Units 1 05/22/19 11:39 Field Temperature 16.2 deg C 1 05/22/19 11:39 Field Specific Conductance 154 umhos/cm 1 05/22/19 11:39 Field Turbidity 6.95 NTU 1 05/22/19 11:39 Field Oxidation Potential 201.1 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.74 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 18.95 feet 1 05/22/19 11:39 Iron, Ferrous 0.0 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-36-0 Arsenic ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-38-2 Barium 44.1 ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-39-3 Beryllium 0.55 ug/L 0.50 1 05/13/1918:04 05/14/1916:55 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:55 7440-43-9 Chromium 1.6J ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-47-3 Cobalt ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-48-4 Copper ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-50-8 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1916:55 7439-92-1 Nickel 1.4J ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1916:55 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1916:55 7440-28-0 Vanadium 4.3J ug/L 10.0 1 05/13/1918:04 05/14/1916:55 7440-62-2 Zinc 3.4J ug/L 10.0 1 05/13/1918:04 05/14/1916:55 7440-66-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 18:21 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 18:21 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 18:21 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 18:21 79-00-5 1,1-Dichloroethane 8.7 ug/L 1.0 1 05/15/19 18:21 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 18:21 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 18:21 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 18:21 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 18:21 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 18:21 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 18:21 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 18:21 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 18:21 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 18:21 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 18:21 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 18:21 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 18:21 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 18:21 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 18:21 71-43-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2S Lab ID: 2618294002 Collected: 05/07/19 13:18 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromochloromethane ND ug/L 1.0 1 05/15/19 18:21 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 18:21 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 18:21 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 18:21 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 18:21 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 18:21 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/15/19 18:21 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 18:21 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 18:21 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 18:21 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 18:21 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 18:21 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 18:21 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 18:21 74-88-4 Methylene Chloride 0.74J ug/L 1.0 1 05/15/19 18:21 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 18:21 100-42-5 Tetrachloroethene 2.6 ug/L 1.0 1 05/15/19 18:21 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 18:21 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 18:21 108-88-3 Trichloroethene 3.1 ug/L 1.0 1 05/15/19 18:21 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 18:21 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 18:21 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 18:21 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 18:21 1330-20-7 cis-1,2-Dichloroethene 9.6 ug/L 1.0 1 05/15/19 18:21 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 18:21 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 18:21 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 18:21 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 18:21 17060-07-0 Dibromofluoromethane (S) 97 %. 82-114 1 05/15/19 18:21 1868-53-7 4-Bromofluorobenzene (S) 94 %. 82-120 1 05/15/19 18:21 460-00-4 Toluene-d8 (S) 99 %. 82-109 1 05/15/19 18:21 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/17/19 19:48 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 113 % 50-150 1 05/17/19 19:48 17060-07-0 Toluene-d8 (S) 120 % 50-150 1 05/17/19 19:48 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 79000 ug/L 20000 1 05/09/19 15:41 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:05 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 14 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-2S Lab ID: 2618294002 Collected: 05/07/19 13:18 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S21) Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1914:26 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/08/19 13:00 05/13/19 13:19 3A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 342 ug/L 50.0 1 05/09/19 12:17 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 2780 ug/L 1000 1 05/11/19 00:08 16887-00-6 Sulfate 306J ug/L 5000 1 05/11/19 00:08 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 18:29 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 18:29 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 18:29 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 18:29 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 18:29 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E Lab ID: 2618294003 Collected: 05/07/19 15:57 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.05 Std. Units 1 05/22/19 11:39 Field Temperature 17.3 deg C 1 05/22/19 11:39 Field Specific Conductance 984 umhos/cm 1 05/22/19 11:39 Field Turbidity 2.25 NTU 1 05/22/19 11:39 Field Oxidation Potential -1.9 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.68 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 24.30 feet 1 05/22/19 11:39 Iron, Ferrous 4.25 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-36-0 Arsenic 0.57J ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-38-2 Barium 344 ug/L 10.0 2 05/13/1918:04 05/15/1915:04 7440-39-3 Beryllium 0.23J ug/L 0.50 1 05/13/1918:04 05/14/1917:00 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1917:00 7440-43-9 Chromium ND ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-47-3 Cobalt 7.4 ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-48-4 Copper ND ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-50-8 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1917:00 7439-92-1 Nickel 11.7 ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1917:00 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1917:00 7440-28-0 Vanadium ND ug/L 10.0 1 05/13/1918:04 05/14/1917:00 7440-62-2 Zinc 3.4J ug/L 10.0 1 05/13/1918:04 05/14/1917:00 7440-66-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 18:46 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 18:46 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 18:46 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 18:46 79-00-5 1,1-Dichloroethane 2.8 ug/L 1.0 1 05/15/19 18:46 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 18:46 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 18:46 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 18:46 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 18:46 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 18:46 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 18:46 107-06-2 1,2-Dichloropropane 0.63J ug/L 1.0 1 05/15/19 18:46 78-87-5 1,4-Dichlorobenzene 16.9 ug/L 1.0 1 05/15/19 18:46 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 18:46 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 18:46 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 18:46 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 18:46 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 18:46 107-13-1 Benzene 0.76J ug/L 1.0 1 05/15/19 18:46 71-43-2 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E Lab ID: 2618294003 Collected: 05/07/19 15:57 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromochloromethane ND ug/L 1.0 1 05/15/19 18:46 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 18:46 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 18:46 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 18:46 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 18:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 18:46 56-23-5 Chlorobenzene 4.2 ug/L 1.0 1 05/15/19 18:46 108-90-7 Chloroethane 5.3 ug/L 1.0 1 05/15/19 18:46 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 18:46 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 18:46 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 18:46 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 18:46 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 18:46 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 18:46 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 18:46 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 18:46 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 18:46 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 18:46 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 18:46 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 18:46 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 18:46 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 18:46 108-05-4 Vinyl chloride 4.0 ug/L 1.0 1 05/15/19 18:46 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 18:46 1330-20-7 cis-1,2-Dichloroethene 28.3 ug/L 1.0 1 05/15/19 18:46 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 18:46 10061-01-5 trans-1,2-Dichloroethene 0.70J ug/L 1.0 1 05/15/19 18:46 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 18:46 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 %. 81-119 1 05/15/19 18:46 17060-07-0 Dibromofluoromethane (S) 99 %. 82-114 1 05/15/19 18:46 1868-53-7 4-Bromofluorobenzene (S) 95 %. 82-120 1 05/15/19 18:46 460-00-4 Toluene-d8 (S) 95 %. 82-109 1 05/15/19 18:46 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 2.5 ug/L 2.0 1 05/17/19 20:08 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 112 % 50-150 1 05/17/19 20:08 17060-07-0 Toluene-d8 (S) 121 % 50-150 1 05/17/19 20:08 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 510000 ug/L 20000 1 05/09/19 15:44 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:05 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 17 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E Lab ID: 2618294003 Collected: 05/07/19 15:57 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 4500S21) Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1914:27 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/08/19 13:00 05/13/19 13:16 3A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N ND ug/L 50.0 1 05/09/19 13:01 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 46600 ug/L 1000 1 05/11/19 00:28 16887-00-6 Sulfate 7210 ug/L 5000 1 05/11/19 00:28 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 3790 ug/L 1000 1 05/16/19 18:50 7440-44-0 Total Organic Carbon 3700 ug/L 1000 1 05/16/19 18:50 7440-44-0 Total Organic Carbon 3530 ug/L 1000 1 05/16/19 18:50 7440-44-0 Total Organic Carbon 3600 ug/L 1000 1 05/16/19 18:50 7440-44-0 Mean Total Organic Carbon 3650 ug/L 1000 1 05/16/19 18:50 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1d Lab ID: 2618294004 Collected: 05/08/19 12:29 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.56 Std. Units 1 05/22/19 11:39 Field Temperature 17.9 deg C 1 05/22/19 11:39 Field Specific Conductance 372 umhos/cm 1 05/22/19 11:39 Field Turbidity 9.37 NTU 1 05/22/19 11:39 Field Oxidation Potential 91.1 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.71 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 46.68 feet 1 05/22/19 11:39 Iron, Ferrous 2.00 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-38-2 Barium 167 ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-39-3 Beryllium 0.14J ug/L 0.50 1 05/15/1915:29 05/16/1917:59 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1917:59 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-47-3 Cobalt 6.3 ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1917:59 7439-92-1 Nickel 9.8 ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1917:59 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1917:59 7440-28-0 Vanadium ND ug/L 10.0 1 05/15/1915:29 05/16/1917:59 7440-62-2 Zinc 6.1J ug/L 10.0 1 05/15/1915:29 05/16/1917:59 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/09/1916:25 05/10/1917:28 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 19:11 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 19:11 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 19:11 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 19:11 79-00-5 1,1-Dichloroethane 22.1 ug/L 1.0 1 05/15/19 19:11 75-34-3 1,1-Dichloroethene 1.3 ug/L 1.0 1 05/15/19 19:11 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 19:11 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 19:11 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 19:11 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 19:11 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 19:11 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 19:11 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 19:11 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 19:11 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 19:11 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 19:11 108-10-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1d Lab ID: 2618294004 Collected: 05/08/19 12:29 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 25.0 1 05/15/19 19:11 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 19:11 107-13-1 Benzene 1.6 ug/L 1.0 1 05/15/19 19:11 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 19:11 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 19:11 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 19:11 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 19:11 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 19:11 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 19:11 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/15/19 19:11 108-90-7 Chloroethane 2.6 ug/L 1.0 1 05/15/19 19:11 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 19:11 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 19:11 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 19:11 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 19:11 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 19:11 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 19:11 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 19:11 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 19:11 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 19:11 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 19:11 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 19:11 108-88-3 Trichloroethene 6.7 ug/L 1.0 1 05/15/19 19:11 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 19:11 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 19:11 108-05-4 Vinyl chloride 3.0 ug/L 1.0 1 05/15/19 19:11 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 19:11 1330-20-7 cis-1,2-Dichloroethene 18.9 ug/L 1.0 1 05/15/19 19:11 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 19:11 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 19:11 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 19:11 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 94 %. 81-119 1 05/15/19 19:11 17060-07-0 Dibromofluoromethane (S) 101 %. 82-114 1 05/15/19 19:11 1868-53-7 4-Bromofluorobenzene (S) 92 %. 82-120 1 05/15/19 19:11 460-00-4 Toluene-d8 (S) 98 %. 82-109 1 05/15/19 19:11 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/18/19 18:21 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 111 % 50-150 1 05/18/19 18:21 17060-07-0 Toluene-d8 (S) 112 % 50-150 1 05/18/19 18:21 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 145000 ug/L 20000 1 05/13/19 17:46 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1.v1 Page 20 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1d Lab ID: 2618294004 Collected: 05/08/19 12:29 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:10 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1915:25 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 2120 ug/L 2000 1 05/10/19 10:10 05/15/19 09:18 2A,L2 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 22.OJ ug/L 50.0 1 05/10/19 02:48 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 7150 ug/L 1000 1 05/11/19 00:49 16887-00-6 Sulfate 480J ug/L 5000 1 05/11/19 00:49 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 1000 ug/L 1000 1 05/16/19 19:12 7440-44-0 Total Organic Carbon 1010 ug/L 1000 1 05/16/19 19:12 7440-44-0 Total Organic Carbon 1010 ug/L 1000 1 05/16/19 19:12 7440-44-0 Total Organic Carbon 1150 ug/L 1000 1 05/16/19 19:12 7440-44-0 Mean Total Organic Carbon 1040 ug/L 1000 1 05/16/19 19:12 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1s Lab ID: 2618294005 Collected: 05/08/19 11:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.23 Std. Units 1 05/22/19 11:39 Field Temperature 15.5 deg C 1 05/22/19 11:39 Field Specific Conductance 205 umhos/cm 1 05/22/19 11:39 Field Turbidity 2.28 NTU 1 05/22/19 11:39 Field Oxidation Potential 90.3 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.80 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 46.05 feet 1 05/22/19 11:39 Iron, Ferrous 0.0 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-38-2 Barium 80.9 ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-39-3 Beryllium 0.70 ug/L 0.50 1 05/15/1915:29 05/16/1918:05 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:05 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-47-3 Cobalt ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:05 7439-92-1 Nickel 3.6J ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:05 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:05 7440-28-0 Vanadium 2AJ ug/L 10.0 1 05/15/1915:29 05/16/1918:05 7440-62-2 Zinc 6.5J ug/L 10.0 1 05/15/1915:29 05/16/1918:05 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/09/1916:25 05/10/1917:31 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 19:36 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 19:36 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 19:36 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 19:36 79-00-5 1,1-Dichloroethane 3.4 ug/L 1.0 1 05/15/19 19:36 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 19:36 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 19:36 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 19:36 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 19:36 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 19:36 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 19:36 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 19:36 78-87-5 1,4-Dichlorobenzene 0.80J ug/L 1.0 1 05/15/19 19:36 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 19:36 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 19:36 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 19:36 108-10-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1s Lab ID: 2618294005 Collected: 05/08/19 11:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acetone ND ug/L 25.0 1 05/15/19 19:36 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 19:36 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 19:36 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 19:36 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 19:36 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 19:36 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 19:36 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 19:36 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 19:36 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/15/19 19:36 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 19:36 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 19:36 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 19:36 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 19:36 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 19:36 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 19:36 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 19:36 74-88-4 Methylene Chloride 0.70J ug/L 1.0 1 05/15/19 19:36 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 19:36 100-42-5 Tetrachloroethene 1.2 ug/L 1.0 1 05/15/19 19:36 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 19:36 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 19:36 108-88-3 Trichloroethene 0.88J ug/L 1.0 1 05/15/19 19:36 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 19:36 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 19:36 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 19:36 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 19:36 1330-20-7 cis-1,2-Dichloroethene 6.3 ug/L 1.0 1 05/15/19 19:36 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 19:36 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 19:36 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 19:36 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 94 %. 81-119 1 05/15/19 19:36 17060-07-0 Dibromofluoromethane (S) 97 %. 82-114 1 05/15/19 19:36 1868-53-7 4-Bromofluorobenzene (S) 95 %. 82-120 1 05/15/19 19:36 460-00-4 Toluene-d8 (S) 99 %. 82-109 1 05/15/19 19:36 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/18/19 18:40 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 50-150 1 05/18/19 18:40 17060-07-0 Toluene-d8 (S) 112 % 50-150 1 05/18/19 18:40 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 92000 ug/L 20000 1 05/13/19 17:50 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1.v1 Page 23 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-AMW-1s Lab ID: 2618294005 Collected: 05/08/19 11:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:10 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1915:26 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/10/19 10:10 05/15/19 09:16 2A,L2 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 137 ug/L 50.0 1 05/10/19 02:27 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 3920 ug/L 1000 1 05/11/19 01:10 16887-00-6 Sulfate 336J ug/L 5000 1 05/11/19 01:10 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 19:33 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 19:33 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 19:33 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 19:33 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 19:33 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-3 Lab ID: 2618294006 Collected: 05/08/19 14:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.47 Std. Units 1 05/22/19 11:39 Field Temperature 15.2 deg C 1 05/22/19 11:39 Field Specific Conductance 170 umhos/cm 1 05/22/19 11:39 Field Turbidity 5.50 NTU 1 05/22/19 11:39 Field Oxidation Potential 114.5 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.81 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 11.90 feet 1 05/22/19 11:39 Iron, Ferrous 0.5 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-38-2 Barium 32.5 ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-39-3 Beryllium 0.074J ug/L 0.50 1 05/15/1915:29 05/16/1918:10 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:10 7440-43-9 Chromium 1.6J ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-47-3 Cobalt ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:10 7439-92-1 Nickel ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:10 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:10 7440-28-0 Vanadium 2.7J ug/L 10.0 1 05/15/1915:29 05/16/1918:10 7440-62-2 Zinc 2.3J ug/L 10.0 1 05/15/1915:29 05/16/1918:10 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/09/1916:25 05/10/1917:33 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 20:01 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 20:01 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 20:01 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 20:01 79-00-5 1,1-Dichloroethane 19.0 ug/L 1.0 1 05/15/19 20:01 75-34-3 1,1-Dichloroethene 1.9 ug/L 1.0 1 05/15/19 20:01 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 20:01 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 20:01 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 20:01 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 20:01 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 20:01 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 20:01 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 20:01 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 20:01 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 20:01 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 20:01 108-10-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-3 Lab ID: 2618294006 Collected: 05/08/19 14:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acetone 8.7J ug/L 25.0 1 05/15/19 20:01 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 20:01 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 20:01 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 20:01 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 20:01 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 20:01 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 20:01 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 20:01 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 20:01 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/15/19 20:01 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 20:01 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 20:01 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 20:01 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 20:01 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 20:01 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 20:01 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 20:01 74-88-4 Methylene Chloride 0.72J ug/L 1.0 1 05/15/19 20:01 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 20:01 100-42-5 Tetrachloroethene 11.9 ug/L 1.0 1 05/15/19 20:01 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 20:01 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 20:01 108-88-3 Trichloroethene 6.5 ug/L 1.0 1 05/15/19 20:01 79-01-6 Trichlorofluoromethane 0.801 ug/L 1.0 1 05/15/19 20:01 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 20:01 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 20:01 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 20:01 1330-20-7 cis-1,2-Dichloroethene 8.8 ug/L 1.0 1 05/15/19 20:01 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 20:01 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 20:01 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 20:01 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 97 %. 81-119 1 05/15/19 20:01 17060-07-0 Dibromofluoromethane (S) 97 %. 82-114 1 05/15/19 20:01 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 05/15/19 20:01 460-00-4 Toluene-d8 (S) 99 %. 82-109 1 05/15/19 20:01 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/18/19 19:00 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 106 % 50-150 1 05/18/19 19:00 17060-07-0 Toluene-d8 (S) 112 % 50-150 1 05/18/19 19:00 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 77000 ug/L 20000 1 05/13/19 17:54 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1.v1 Page 26 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-3 Lab ID: 2618294006 Collected: 05/08/19 14:07 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:11 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1915:27 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/10/19 10:10 05/15/19 09:19 2A,L2 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 25.OJ ug/L 50.0 1 05/10/19 03:09 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 3920 ug/L 1000 1 05/11/19 02:54 16887-00-6 Sulfate 239J ug/L 5000 1 05/11/19 02:54 14808-79-8 B 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 20:35 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 20:35 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 20:35 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 20:35 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 20:35 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 27 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-3 deep Lab ID: 2618294007 Collected: 05/08/19 14:52 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.98 Std. Units 1 05/22/19 11:39 Field Temperature 16.0 deg C 1 05/22/19 11:39 Field Specific Conductance 343 umhos/cm 1 05/22/19 11:39 Field Turbidity 8.00 NTU 1 05/22/19 11:39 Field Oxidation Potential 17.9 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.76 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 7.63 feet 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-36-0 Arsenic 0.73J ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-38-2 Barium 56.9 ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-39-3 Beryllium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:27 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:27 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-47-3 Cobalt ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:27 7439-92-1 Nickel ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:27 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:27 7440-28-0 Vanadium ND ug/L 10.0 1 05/15/1915:29 05/16/1918:27 7440-62-2 Zinc 5.7J ug/L 10.0 1 05/15/1915:29 05/16/1918:27 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/09/1916:25 05/10/1917:35 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 20:26 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 20:26 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 20:26 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 20:26 79-00-5 1,1-Dichloroethane 1.1 ug/L 1.0 1 05/15/19 20:26 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 20:26 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 20:26 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 20:26 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 20:26 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 20:26 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 20:26 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 20:26 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 20:26 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 20:26 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 20:26 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 20:26 108-10-1 Acetone 10.0J ug/L 25.0 1 05/15/19 20:26 67-64-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-3 deep Lab ID: 2618294007 Collected: 05/08/19 14:52 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acrylonitrile ND ug/L 50.0 1 05/15/19 20:26 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 20:26 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 20:26 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 20:26 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 20:26 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 20:26 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 20:26 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 20:26 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/15/19 20:26 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 20:26 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 20:26 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 20:26 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 20:26 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 20:26 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 20:26 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 20:26 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 20:26 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 20:26 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 20:26 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 20:26 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 20:26 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 20:26 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 20:26 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 20:26 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 20:26 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 20:26 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 20:26 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 20:26 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 20:26 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 20:26 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 %. 81-119 1 05/15/19 20:26 17060-07-0 Dibromofluoromethane (S) 99 %. 82-114 1 05/15/19 20:26 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 05/15/19 20:26 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 20:26 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/18/19 19:20 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 108 % 50-150 1 05/18/19 19:20 17060-07-0 Toluene-d8 (S) 111 % 50-150 1 05/18/19 19:20 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1,v1 Page 29 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E deep Lab ID: 2618294008 Collected: 05/08/19 09:26 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.29 Std. Units 1 05/22/19 11:39 Field Temperature 16.4 deg C 1 05/22/19 11:39 Field Specific Conductance 1173 umhos/cm 1 05/22/19 11:39 Field Turbidity 8.83 NTU 1 05/22/19 11:39 Field Oxidation Potential -30.9 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.88 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 27.73 feet 1 05/22/19 11:39 Iron, Ferrous 6.0 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-36-0 Arsenic 2.1J ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-38-2 Barium 2910 ug/L 25.0 5 05/15/1915:29 05/17/1919:09 7440-39-3 Beryllium 0.37J ug/L 0.50 1 05/15/1915:29 05/16/1918:33 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:33 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-47-3 Cobalt 42.1 ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-50-8 Lead 2.9 ug/L 1.0 1 05/15/1915:29 05/16/1918:33 7439-92-1 Nickel 24.9 ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:33 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:33 7440-28-0 Vanadium ND ug/L 10.0 1 05/15/1915:29 05/16/1918:33 7440-62-2 Zinc 5AJ ug/L 10.0 1 05/15/1915:29 05/16/1918:33 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/09/1916:25 05/10/1917:38 7439-97-6 8270E MSSV Water Analytical Method: EPA 8270E Preparation Method: EPA 3510C bis(2- Ethyl hexyl)phthalate ND ug/L 15.0 1 05/10/19 15:45 05/11/19 03:09 117-81-7 Surrogates Nitrobenzene-d5 (S) 62 %. 13-107 1 05/10/19 15:45 05/11/19 03:09 4165-60-0 2-Fluorobiphenyl (S) 65 %. 12-129 1 05/10/19 15:45 05/11/19 03:09 321-60-8 Phenol-d6 (S) 20 %. 10-46 1 05/10/19 15:45 05/11/19 03:09 13127-88-3 2-Fluorophenol (S) 34 %. 10-64 1 05/10/19 15:45 05/11/19 03:09 367-12-4 2,4,6-Tribromophenol (S) 84 %. 10-148 1 05/10/19 15:45 05/11/19 03:09 118-79-6 p-Terphenyl-d14 (S) 78 %. 14-147 1 05/10/19 15:45 05/11/19 03:09 1718-51-0 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/1917:33 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/1917:33 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/1917:33 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/1917:33 79-00-5 1,1-Dichloroethane 0.44J ug/L 1.0 1 05/17/1917:33 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/1917:33 75-35-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E deep Lab ID: 2618294008 Collected: 05/08/19 09:26 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 17:33 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 17:33 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 17:33 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 17:33 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 17:33 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 17:33 78-87-5 1,4-Dichlorobenzene 7.4 ug/L 1.0 1 05/17/19 17:33 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 17:33 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 17:33 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 17:33 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 17:33 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 17:33 107-13-1 Benzene 2.4 ug/L 1.0 1 05/17/19 17:33 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 17:33 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 17:33 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 17:33 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 17:33 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 17:33 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 17:33 56-23-5 L1 Chlorobenzene 1.2 ug/L 1.0 1 05/17/19 17:33 108-90-7 Chloroethane 5.9 ug/L 1.0 1 05/17/19 17:33 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 17:33 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 17:33 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 17:33 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 17:33 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 17:33 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 17:33 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 17:33 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 17:33 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 17:33 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 17:33 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 17:33 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 17:33 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 17:33 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 17:33 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 17:33 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 17:33 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 17:33 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:33 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 17:33 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:33 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 %. 81-119 1 05/17/19 17:33 17060-07-0 Dibromofluoromethane (S) 108 %. 82-114 1 05/17/19 17:33 1868-53-7 4-Bromofluorobenzene (S) 88 %. 82-120 1 05/17/19 17:33 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 17:33 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 31 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-E deep Lab ID: 2618294008 Collected: 05/08/19 09:26 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 410.4 COD Chemical Oxygen Demand 450OS2D Sulfide Water Sulfide 5210B BOD, 5 day BOD, 5 day 9056 IC Anions 48hr Nitrate as N 9056 IC Anions Chloride Sulfate 9060A Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Total Organic Carbon Mean Total Organic Carbon Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D Mod 9.8 ug/L 2.0 1 05/20/1915:25 123-91-1 94 % 50-150 1 05/20/1915:25 17060-07-0 78 % 50-150 1 05/20/1915:25 2037-26-5 Analytical Method: SM 2320B 468000 ug/L 20000 1 05/13/1917:57 Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 ND ug/L 10000 1 05/13/1913:20 05/13/1916:11 Analytical Method: SM 4500-S2 D ND ug/L 200 1 05/10/1915:28 18496-25-8 Analytical Method: SM 521OB Preparation Method: SM 521 OB 129000 ug/L 17200 12 05/09/1915:00 05/14/1911:56 1A,3A, R6 Analytical Method: EPA 9056A 21.OJ ug/L 50.0 1 05/10/19 01:23 14797-55-8 B Analytical Method: EPA 9056A 66200 ug/L 5000 5 05/22/1918:49 16887-00-6 92.OJ ug/L 5000 1 05/11/19 03:14 14808-79-8 B Analytical Method: EPA 9060A 8120 ug/L 1000 1 05/16/19 20:56 7440-44-0 8080 ug/L 1000 1 05/16/19 20:56 7440-44-0 8200 ug/L 1000 1 05/16/19 20:56 7440-44-0 8000 ug/L 1000 1 05/16/19 20:56 7440-44-0 8100 ug/L 1000 1 05/16/19 20:56 7440-44-0 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 32 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-L Lab ID: 2618294009 Collected: 05/08/19 15:58 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.12 Std. Units 1 05/22/19 11:39 Field Temperature 14.4 deg C 1 05/22/19 11:39 Field Specific Conductance 91 umhos/cm 1 05/22/19 11:39 Field Turbidity 6.87 NTU 1 05/22/19 11:39 Field Oxidation Potential 142.9 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.87 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 9.88 feet 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-38-2 Barium 41.0 ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-39-3 Beryllium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:39 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:39 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-47-3 Cobalt ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:39 7439-92-1 Nickel ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:39 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:39 7440-28-0 Vanadium ND ug/L 10.0 1 05/15/1915:29 05/16/1918:39 7440-62-2 Zinc 2.9J ug/L 10.0 1 05/15/1915:29 05/16/1918:39 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:16 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 17:59 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 17:59 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 17:59 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 17:59 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 17:59 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 17:59 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 17:59 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 17:59 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 17:59 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 17:59 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 17:59 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 17:59 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 17:59 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 17:59 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 17:59 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 17:59 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 17:59 67-64-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-L Lab ID: 2618294009 Collected: 05/08/19 15:58 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acrylonitrile ND ug/L 50.0 1 05/17/19 17:59 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 17:59 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 17:59 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/17/19 17:59 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 17:59 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 17:59 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 17:59 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 17:59 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 17:59 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 17:59 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 17:59 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 17:59 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 17:59 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 17:59 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 17:59 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 17:59 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 17:59 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 17:59 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 17:59 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 17:59 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 17:59 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 17:59 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 17:59 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 17:59 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 17:59 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 17:59 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 17:59 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:59 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 17:59 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:59 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 101 %. 81-119 1 05/17/19 17:59 17060-07-0 Dibromofluoromethane (S) 103 %. 82-114 1 05/17/19 17:59 1868-53-7 4-Bromofluorobenzene (S) 87 %. 82-120 1 05/17/19 17:59 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 17:59 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/20/19 15:45 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 89 % 50-150 1 05/20/19 15:45 17060-07-0 Toluene-d8 (S) 76 % 50-150 1 05/20/19 15:45 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 36000 ug/L 20000 1 05/13/19 18:05 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 L1 Page 34 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-L Lab ID: 2618294009 Collected: 05/08/19 15:58 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 13:20 05/13/19 16:13 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1915:28 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/10/19 10:10 05/15/19 09:23 2A,L2 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 84.0 ug/L 50.0 1 05/10/19 03:31 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 2680 ug/L 1000 1 05/22/1919:11 16887-00-6 Sulfate 1480J ug/L 5000 1 05/22/1919:11 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 21:14 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 21:14 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 21:14 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 21:14 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 21:14 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 35 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-L deep Lab ID: 2618294010 Collected: 05/08/19 16:28 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.10 Std. Units 1 05/22/19 11:39 Field Temperature 13.7 deg C 1 05/22/19 11:39 Field Specific Conductance 203 umhos/cm 1 05/22/19 11:39 Field Turbidity 4.52 NTU 1 05/22/19 11:39 Field Oxidation Potential 160.7 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.90 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 11.35 feet 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony 0.901 ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-38-2 Barium 34.3 ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-39-3 Beryllium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:45 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:45 7440-43-9 Chromium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-47-3 Cobalt ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-48-4 Copper ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:45 7439-92-1 Nickel 1.8J ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:45 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:45 7440-28-0 Vanadium 3.6J ug/L 10.0 1 05/15/1915:29 05/16/1918:45 7440-62-2 Zinc 396 ug/L 10.0 1 05/15/1915:29 05/16/1918:45 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:19 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 18:25 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 18:25 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 18:25 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 18:25 79-00-5 1,1-Dichloroethane 5.4 ug/L 1.0 1 05/17/19 18:25 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 18:25 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 18:25 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 18:25 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 18:25 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 18:25 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 18:25 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 18:25 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 18:25 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 18:25 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 18:25 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 18:25 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 18:25 67-64-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 36 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-L deep Lab ID: 2618294010 Collected: 05/08/19 16:28 Received: 05/09/19 09:40 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acrylonitrile ND ug/L 50.0 1 05/17/19 18:25 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 18:25 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 18:25 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/17/19 18:25 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 18:25 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 18:25 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 18:25 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 18:25 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 18:25 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 18:25 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 18:25 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 18:25 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 18:25 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 18:25 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 18:25 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 18:25 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 18:25 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 18:25 100-42-5 Tetrachloroethene 1.0 ug/L 1.0 1 05/17/19 18:25 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 18:25 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 18:25 108-88-3 Trichloroethene 0.65J ug/L 1.0 1 05/17/19 18:25 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 18:25 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 18:25 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 18:25 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 18:25 1330-20-7 cis-1,2-Dichloroethene 3.3 ug/L 1.0 1 05/17/19 18:25 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 18:25 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 18:25 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 18:25 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 98 %. 81-119 1 05/17/19 18:25 17060-07-0 Dibromofluoromethane (S) 105 %. 82-114 1 05/17/19 18:25 1868-53-7 4-Bromofluorobenzene (S) 85 %. 82-120 1 05/17/19 18:25 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 18:25 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/20/19 16:04 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 88 % 50-150 1 05/20/19 16:04 17060-07-0 Toluene-d8 (S) 76 % 50-150 1 05/20/19 16:04 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 L1 Page 37 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-A Lab ID: 2618294011 Collected: 05/09/19 09:18 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.27 Std. Units 1 05/22/19 11:39 Field Temperature 13.7 deg C 1 05/22/19 11:39 Field Specific Conductance 449 umhos/cm 1 05/22/19 11:39 Field Turbidity 1.79 NTU 1 05/22/19 11:39 Field Oxidation Potential 76.7 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.91 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 39.57 feet 1 05/22/19 11:39 Iron, Ferrous 3.50 mg/L 1 05/22/19 11:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-36-0 Arsenic ND ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-38-2 Barium 56.0 ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-39-3 Beryllium 0.191 ug/L 0.50 1 05/15/1915:29 05/16/1918:50 7440-41-7 Cadmium ND ug/L 0.50 1 05/15/1915:29 05/16/1918:50 7440-43-9 Chromium 11.2 ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-47-3 Cobalt 25.2 ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-48-4 Copper 1.5J ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-50-8 Lead ND ug/L 1.0 1 05/15/1915:29 05/16/1918:50 7439-92-1 Nickel 31.9 ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-02-0 Selenium ND ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7782-49-2 Silver ND ug/L 5.0 1 05/15/1915:29 05/16/1918:50 7440-22-4 Thallium ND ug/L 1.0 1 05/15/1915:29 05/16/1918:50 7440-28-0 Vanadium 3.8J ug/L 10.0 1 05/15/1915:29 05/16/1918:50 7440-62-2 Zinc 6.OJ ug/L 10.0 1 05/15/1915:29 05/16/1918:50 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:21 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:05 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 00:05 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:05 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 00:05 79-00-5 1,1-Dichloroethane 12.7 ug/L 1.0 1 05/23/19 00:05 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 00:05 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 00:05 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 00:05 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 00:05 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 00:05 95-50-1 1,2-Dichloroethane 1.7 ug/L 1.0 1 05/23/19 00:05 107-06-2 1,2-Dichloropropane 2.4 ug/L 1.0 1 05/23/19 00:05 78-87-5 1,4-Dichlorobenzene 36.0 ug/L 1.0 1 05/23/19 00:05 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 00:05 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 00:05 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 00:05 108-10-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 38 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-A Lab ID: 2618294011 Collected: 05/09/19 09:18 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Acetone 9.7J ug/L 25.0 1 05/23/19 00:05 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 00:05 107-13-1 Benzene 5.7 ug/L 1.0 1 05/23/19 00:05 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 00:05 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 00:05 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 00:05 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 00:05 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 00:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 00:05 56-23-5 Chlorobenzene 1.3 ug/L 1.0 1 05/23/19 00:05 108-90-7 Chloroethane 2.7 ug/L 1.0 1 05/23/19 00:05 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 00:05 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 00:05 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 00:05 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 00:05 74-95-3 Ethylbenzene 0.49J ug/L 1.0 1 05/23/19 00:05 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 00:05 74-88-4 Methylene Chloride 2.5 ug/L 1.0 1 05/23/19 00:05 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 00:05 100-42-5 Tetrachloroethene 2.3 ug/L 1.0 1 05/23/19 00:05 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 00:05 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 00:05 108-88-3 Trichloroethene 2.9 ug/L 1.0 1 05/23/19 00:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/23/19 00:05 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/23/19 00:05 108-05-4 Vinyl chloride 0.77J ug/L 1.0 1 05/23/19 00:05 75-01-4 Xylene (Total) 3.8 ug/L 2.0 1 05/23/19 00:05 1330-20-7 cis-1,2-Dichloroethene 86.2 ug/L 1.0 1 05/23/19 00:05 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/23/19 00:05 10061-01-5 trans-1,2-Dichloroethene 0.49J ug/L 1.0 1 05/23/19 00:05 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/23/19 00:05 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 103 %. 81-119 1 05/23/19 00:05 17060-07-0 Dibromofluoromethane (S) 104 %. 82-114 1 05/23/19 00:05 1868-53-7 4-Bromofluorobenzene (S) 107 %. 82-120 1 05/23/19 00:05 460-00-4 Toluene-d8 (S) 98 %. 82-109 1 05/23/19 00:05 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/20/19 19:17 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 92 % 50-150 1 05/20/19 19:17 17060-07-0 Toluene-d8 (S) 75 % 50-150 1 05/20/19 19:17 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 109000 ug/L 20000 1 05/13/19 18:09 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 39 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-A Lab ID: 2618294011 Collected: 05/09/19 09:18 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/22/19 10:30 05/22/19 15:33 450OS2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide 652 ug/L 200 1 05/10/1915:34 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day 6960 ug/L 3640 2 05/10/19 16:25 05/15/19 10:19 2A,L2 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 23.OJ ug/L 50.0 1 05/11/19 08:47 14797-55-8 B 9056 IC Anions Analytical Method: EPA 9056A Chloride 26900 ug/L 1000 1 05/23/19 05:46 16887-00-6 Sulfate 31500 ug/L 5000 1 05/23/19 05:46 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon 4420 ug/L 1000 1 05/16/19 21:35 7440-44-0 Total Organic Carbon 4300 ug/L 1000 1 05/16/19 21:35 7440-44-0 Total Organic Carbon 4430 ug/L 1000 1 05/16/19 21:35 7440-44-0 Total Organic Carbon 4360 ug/L 1000 1 05/16/19 21:35 7440-44-0 Mean Total Organic Carbon 4380 ug/L 1000 1 05/16/19 21:35 7440-44-0 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294012 Collected: 05/07/19 10:25 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.98 Std. Units 1 05/22/19 11:39 Field Temperature 14.7 deg C 1 05/22/19 11:39 Field Specific Conductance 191.1 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 48.4 my 1 05/22/19 11:39 Oxygen, Dissolved 24.6 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 10.65 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:56 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 14:56 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:56 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 14:56 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 14:56 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 14:56 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 14:56 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 14:56 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 14:56 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:56 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 14:56 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 14:56 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:56 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 14:56 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 14:56 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 14:56 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 14:56 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 14:56 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 14:56 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 14:56 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 14:56 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 14:56 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 14:56 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 14:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 14:56 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 14:56 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 14:56 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 14:56 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 14:56 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 14:56 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 14:56 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 14:56 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 14:56 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 14:56 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 14:56 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 14:56 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 14:56 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 14:56 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294012 Collected: 05/07/19 10:25 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 95 %. 106 %. 88 %. 83 %. Analytical Method: EPA 8260D Mod. ND ug/L 109 % 115 % 1.0 1 05/17/19 14:56 79-01-6 1.0 1 05/17/19 14:56 75-69-4 2.0 1 05/17/19 14:56 108-05-4 1.0 1 05/17/19 14:56 75-01-4 2.0 1 05/17/19 14:56 1330-20-7 1.0 1 05/17/19 14:56 156-59-2 1.0 1 05/17/19 14:56 10061-01-5 1.0 1 05/17/19 14:56 156-60-5 1.0 1 05/17/19 14:56 10061-02-6 81-119 1 05/17/19 14:56 17060-07-0 82-114 1 05/17/19 14:56 1868-53-7 82-120 1 05/17/19 14:56 460-00-4 82-109 1 05/17/19 14:56 2037-26-5 2.0 1 05/19/19 13:03 123-91-1 50-150 1 05/19/19 13:03 17060-07-0 50-150 1 05/19/19 13:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294013 Collected: 05/08/19 08:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 9.87 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-38-2 45.9 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-39-3 0.38J ug/L 0.50 1 05/16/1914:34 05/20/1915:14 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:14 7440-43-9 2.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-47-3 7.0 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-48-4 1.4J ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-50-8 1.1 ug/L 1.0 1 05/16/1914:34 05/20/1915:14 7439-92-1 5.8 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1915:14 7440-28-0 6.2J ug/L 10.0 1 05/16/1914:34 05/20/1915:14 7440-62-2 13.7 ug/L 10.0 1 05/16/1914:34 05/20/1915:14 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 43 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294014 Collected: 05/08/19 12:54 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.51 Std. Units 1 05/22/19 11:39 Field Temperature 15.9 deg C 1 05/22/19 11:39 Field Specific Conductance 1408 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 22.4 my 1 05/22/19 11:39 Oxygen, Dissolved 15.2 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 11.88 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 12:48 630-20-6 R1 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 12:48 71-55-6 M1,R1 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 12:48 79-34-5 R1 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 12:48 79-00-5 R1 1,1-Dichloroethane 1.9 ug/L 1.0 1 05/22/19 12:48 75-34-3 R1 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 12:48 75-35-4 R1 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 12:48 96-18-4 M1,R1 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 12:48 96-12-8 M1,R1 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 12:48 106-93-4 R1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 12:48 95-50-1 R1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 12:48 107-06-2 R1 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 12:48 78-87-5 R1 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 12:48 106-46-7 R1 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 12:48 78-93-3 R1 2-Hexanone ND ug/L 5.0 1 05/22/19 12:48 591-78-6 R1 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 12:48 108-10-1 R1 Acetone ND ug/L 25.0 1 05/22/19 12:48 67-64-1 R1 Acrylonitrile ND ug/L 50.0 1 05/22/19 12:48 107-13-1 R1 Benzene ND ug/L 1.0 1 05/22/19 12:48 71-43-2 R1 Bromochloromethane ND ug/L 1.0 1 05/22/19 12:48 74-97-5 M1,R1 Bromodichloromethane ND ug/L 1.0 1 05/22/19 12:48 75-27-4 M1,R1 Bromoform ND ug/L 1.0 1 05/22/19 12:48 75-25-2 R1 Bromomethane ND ug/L 2.0 1 05/22/19 12:48 74-83-9 R1 Carbon disulfide ND ug/L 10.0 1 05/22/19 12:48 75-15-0 M1 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 12:48 56-23-5 M1,R1 Chlorobenzene ND ug/L 1.0 1 05/22/19 12:48 108-90-7 R1 Chloroethane ND ug/L 1.0 1 05/22/19 12:48 75-00-3 R1 Chloroform ND ug/L 1.0 1 05/22/19 12:48 67-66-3 M1,R1 Chloromethane ND ug/L 1.0 1 05/22/19 12:48 74-87-3 R1 Dibromochloromethane ND ug/L 1.0 1 05/22/19 12:48 124-48-1 M1,R1 Dibromomethane ND ug/L 1.0 1 05/22/19 12:48 74-95-3 M1,R1 Ethylbenzene ND ug/L 1.0 1 05/22/19 12:48 100-41-4 R1 lodomethane ND ug/L 10.0 1 05/22/19 12:48 74-88-4 R1 Methylene Chloride ND ug/L 1.0 1 05/22/19 12:48 75-09-2 R1 Styrene ND ug/L 1.0 1 05/22/19 12:48 100-42-5 M1,R1 Tetrachloroethene ND ug/L 1.0 1 05/22/19 12:48 127-18-4 R1 Tetrahydrofuran 1.4J ug/L 10.0 1 05/22/19 12:48 109-99-9 R1 Toluene ND ug/L 1.0 1 05/22/19 12:48 108-88-3 R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294014 Collected: 05/08/19 12:54 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D 0.38J ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 106 %. 102 %. 110 %. 105 %. Analytical Method: EPA 8260D Mod. 66.4 ug/L 94 % 77 % 1.0 1 05/22/19 12:48 79-01-6 R1 1.0 1 05/22/19 12:48 75-69-4 M 1, R 1 2.0 1 05/22/19 12:48 108-05-4 M 1, R 1 1.0 1 05/22/19 12:48 75-01-4 R1 2.0 1 05/22/19 12:48 1330-20-7 RS 1.0 1 05/22/19 12:48 156-59-2 R1 1.0 1 05/22/19 12:48 10061-01-5 R1 1.0 1 05/22/19 12:48 156-60-5 R1 1.0 1 05/22/19 12:48 10061-02-6 R1 81-119 1 05/22/19 12:48 17060-07-0 82-114 1 05/22/19 12:48 1868-53-7 82-120 1 05/22/19 12:48 460-00-4 82-109 1 05/22/19 12:48 2037-26-5 2.0 1 05/20/19 16:23 123-91-1 50-150 1 05/20/19 16:23 17060-07-0 50-150 1 05/20/19 16:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 45 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294015 Collected: 05/09/19 08:34 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 5.47 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A 0.46J ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-38-2 133 ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:37 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:37 7440-43-9 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-47-3 12.7 ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-48-4 3.1J ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-50-8 0.13J ug/L 1.0 1 05/16/1914:34 05/20/1915:37 7439-92-1 28.9 ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:37 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1915:37 7440-28-0 1.51 ug/L 10.0 1 05/16/1914:34 05/20/1915:37 7440-62-2 2.5J ug/L 10.0 1 05/16/1914:34 05/20/1915:37 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 46 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-B Lab ID: 2618294016 Collected: 05/08/19 11:45 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.67 Std. Units 1 05/22/19 11:39 Field Temperature 16.0 deg C 1 05/22/19 11:39 Field Specific Conductance 784 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential -64.5 my 1 05/22/19 11:39 Oxygen, Dissolved 10.5 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 2.46 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:43 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 19:43 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:43 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 19:43 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 19:43 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 19:43 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 19:43 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 19:43 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 19:43 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:43 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 19:43 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 19:43 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:43 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 19:43 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 19:43 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 19:43 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 19:43 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 19:43 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 19:43 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 19:43 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 19:43 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 19:43 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 19:43 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 19:43 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 19:43 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 19:43 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 19:43 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 19:43 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 19:43 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 19:43 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 19:43 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 19:43 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 19:43 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 19:43 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 19:43 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 19:43 127-18-4 Tetrahydrofuran 4.OJ ug/L 10.0 1 05/17/19 19:43 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 19:43 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-B Lab ID: 2618294016 Collected: 05/08/19 11:45 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 %. 104 %. 85 %. 83 %. Analytical Method: EPA 8260D Mod. 54.3 ug/L 92 % 75 % 1.0 1 05/17/19 19:43 79-01-6 1.0 1 05/17/19 19:43 75-69-4 2.0 1 05/17/19 19:43 108-05-4 1.0 1 05/17/19 19:43 75-01-4 2.0 1 05/17/19 19:43 1330-20-7 1.0 1 05/17/19 19:43 156-59-2 1.0 1 05/17/19 19:43 10061-01-5 1.0 1 05/17/19 19:43 156-60-5 1.0 1 05/17/19 19:43 10061-02-6 81-119 1 05/17/19 19:43 17060-07-0 82-114 1 05/17/19 19:43 1868-53-7 82-120 1 05/17/19 19:43 460-00-4 82-109 1 05/17/19 19:43 2037-26-5 2.0 1 05/20/19 16:43 123-91-1 50-150 1 05/20/19 16:43 17060-07-0 50-150 1 05/20/19 16:43 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 48 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-B Lab ID: 2618294017 Collected: 05/09/19 08:23 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 5.23 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-36-0 0.38J ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-38-2 175 ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:42 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:42 7440-43-9 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-47-3 7.3 ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-48-4 0.27J ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-50-8 0.10J ug/L 1.0 1 05/16/1914:34 05/20/1915:42 7439-92-1 5.5 ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:42 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1915:42 7440-28-0 ND ug/L 10.0 1 05/16/1914:34 05/20/1915:42 7440-62-2 2.5J ug/L 10.0 1 05/16/1914:34 05/20/1915:42 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 49 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-C Lab ID: 2618294018 Collected: 05/09/19 10:50 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.74 Std. Units 1 05/22/19 11:39 Field Temperature 15.0 deg C 1 05/22/19 11:39 Field Specific Conductance 98 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 104.3 mV 1 05/22/19 11:39 Oxygen, Dissolved 1.37 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 12.04 feet 1 05/22/19 11:39 8270E MSSV Water Analytical Method: EPA 8270E Preparation Method: EPA 3510C bis(2- Ethyl hexyl)phthalate 7.1J ug/L 15.0 1 05/15/19 11:30 05/15/19 19:20 117-81-7 Surrogates Nitrobenzene-d5 (S) 47 %. 13-107 1 05/15/19 11:30 05/15/19 19:20 4165-60-0 2-Fluorobiphenyl (S) 65 %. 12-129 1 05/15/19 11:30 05/15/19 19:20 321-60-8 Phenol-d6 (S) 18 %. 10-46 1 05/15/19 11:30 05/15/19 19:20 13127-88-3 2-Fluorophenol (S) 25 %. 10-64 1 05/15/19 11:30 05/15/19 19:20 367-12-4 2,4,6-Tribromophenol (S) 74 %. 10-148 1 05/15/19 11:30 05/15/19 19:20 118-79-6 p-Terphenyl-d14 (S) 86 %. 14-147 1 05/15/19 11:30 05/15/19 19:20 1718-51-0 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:31 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 00:31 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:31 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 00:31 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 00:31 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 00:31 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 00:31 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 00:31 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 00:31 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 00:31 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 00:31 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 00:31 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 00:31 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 00:31 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 00:31 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 00:31 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 00:31 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 00:31 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 00:31 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 00:31 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 00:31 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 00:31 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 00:31 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 00:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 00:31 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 00:31 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 00:31 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 50 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-C Lab ID: 2618294018 Collected: 05/09/19 10:50 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Chloroform ND ug/L 1.0 1 05/23/19 00:31 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 00:31 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 00:31 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 00:31 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 00:31 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 00:31 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 00:31 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 00:31 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 00:31 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 00:31 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 00:31 108-88-3 Trichloroethene ND ug/L 1.0 1 05/23/19 00:31 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/23/19 00:31 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/23/19 00:31 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/23/19 00:31 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/23/19 00:31 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/23/19 00:31 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/23/19 00:31 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/23/19 00:31 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/23/19 00:31 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 106 %. 81-119 1 05/23/19 00:31 17060-07-0 Dibromofluoromethane (S) 100 %. 82-114 1 05/23/19 00:31 1868-53-7 4-Bromofluorobenzene (S) 106 %. 82-120 1 05/23/19 00:31 460-00-4 Toluene-d8 (S) 94 %. 82-109 1 05/23/19 00:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/20/19 19:36 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 89 % 50-150 1 05/20/19 19:36 17060-07-0 Toluene-d8 (S) 75 % 50-150 1 05/20/19 19:36 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 51 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-C Lab ID: 2618294019 Collected: 05/10/19 07:33 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method: 5.74 Std. Units 1 05/22/19 11:39 15.0 deg C 1 05/22/19 11:39 98 umhos/cm 1 05/22/19 11:39 800+ NTU 1 05/22/19 11:39 104.3 mV 1 05/22/19 11:39 1.37 mg/L 1 05/22/19 11:39 7782-44-7 N2 12.04 feet 1 05/22/19 11:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-38-2 19.6 ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-39-3 0.16J ug/L 0.50 1 05/16/1914:34 05/20/1916:00 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1916:00 7440-43-9 28.7 ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-47-3 1.3J ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-48-4 3.1J ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-50-8 0.18J ug/L 1.0 1 05/16/1914:34 05/20/1916:00 7439-92-1 9.7 ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:00 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1916:00 7440-28-0 1.7J ug/L 10.0 1 05/16/1914:34 05/20/1916:00 7440-62-2 4.5J ug/L 10.0 1 05/16/1914:34 05/20/1916:00 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 52 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-D Lab ID: 2618294020 Collected: 05/09/19 10:15 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.92 Std. Units 1 05/22/19 11:39 Field Temperature 13.8 deg C 1 05/22/19 11:39 Field Specific Conductance 620 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 36.4 my 1 05/22/19 11:39 Oxygen, Dissolved 1.93 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 22.76 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:57 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 00:57 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 00:57 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 00:57 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 00:57 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 00:57 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 00:57 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 00:57 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 00:57 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 00:57 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 00:57 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 00:57 78-87-5 1,4-Dichlorobenzene 9.1 ug/L 1.0 1 05/23/19 00:57 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 00:57 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 00:57 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 00:57 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 00:57 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 00:57 107-13-1 Benzene 4.2 ug/L 1.0 1 05/23/19 00:57 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 00:57 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 00:57 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 00:57 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 00:57 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 00:57 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 00:57 56-23-5 Chlorobenzene 1.0 ug/L 1.0 1 05/23/19 00:57 108-90-7 Chloroethane 1.1 ug/L 1.0 1 05/23/19 00:57 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 00:57 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 00:57 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 00:57 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 00:57 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 00:57 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 00:57 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 00:57 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 00:57 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 00:57 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 00:57 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 00:57 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 53 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-D Lab ID: 2618294020 Collected: 05/09/19 10:15 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D 1.3 ug/L ND ug/L ND ug/L 0.67J ug/L ND ug/L 23.4 ug/L ND ug/L ND ug/L ND ug/L 103 %. 101 %. 110 %. 122 %. Analytical Method: EPA 8260D Mod. ND ug/L 91 % 76 % 1.0 1 05/23/19 00:57 79-01-6 1.0 1 05/23/19 00:57 75-69-4 2.0 1 05/23/19 00:57 108-05-4 1.0 1 05/23/19 00:57 75-01-4 2.0 1 05/23/19 00:57 1330-20-7 1.0 1 05/23/19 00:57 156-59-2 1.0 1 05/23/19 00:57 10061-01-5 1.0 1 05/23/19 00:57 156-60-5 1.0 1 05/23/19 00:57 10061-02-6 81-119 1 05/23/19 00:57 17060-07-0 82-114 1 05/23/19 00:57 1868-53-7 82-120 1 05/23/19 00:57 460-00-4 82-109 1 05/23/19 00:57 2037-26-5 SO 2.0 1 05/20/19 19:56 123-91-1 50-150 1 05/20/19 19:56 17060-07-0 50-150 1 05/20/19 19:56 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 54 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-D Lab ID: 2618294021 Collected: 05/10/19 07:20 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 3.14 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-38-2 140 ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-39-3 0.22J ug/L 0.50 1 05/16/1914:34 05/20/1916:06 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1916:06 7440-43-9 0.64J ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-47-3 12.1 ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-48-4 0.47J ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-50-8 ND ug/L 1.0 1 05/16/1914:34 05/20/1916:06 7439-92-1 18.1 ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:06 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1916:06 7440-28-0 18.7 ug/L 10.0 1 05/16/1914:34 05/20/1916:06 7440-62-2 6.3J ug/L 10.0 1 05/16/1914:34 05/20/1916:06 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 55 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-F Lab ID: 2618294022 Collected: 05/08/19 10:52 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.57 Std. Units 1 05/22/19 11:39 Field Temperature 14.3 deg C 1 05/22/19 11:39 Field Specific Conductance 478.3 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential -69.4 my 1 05/22/19 11:39 Oxygen, Dissolved 15.5 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 8.09 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 13:14 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 13:14 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 13:14 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 13:14 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/22/19 13:14 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 13:14 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 13:14 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 13:14 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 13:14 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 13:14 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 13:14 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 13:14 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 13:14 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 13:14 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 13:14 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 13:14 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 13:14 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 13:14 107-13-1 Benzene ND ug/L 1.0 1 05/22/19 13:14 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 13:14 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 13:14 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 13:14 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 13:14 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 13:14 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 13:14 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/22/19 13:14 108-90-7 Chloroethane ND ug/L 1.0 1 05/22/19 13:14 75-00-3 Chloroform ND ug/L 1.0 1 05/22/19 13:14 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 13:14 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 13:14 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 13:14 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 13:14 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 13:14 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/22/19 13:14 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 13:14 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/22/19 13:14 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/22/19 13:14 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 13:14 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 56 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-F Lab ID: 2618294022 Collected: 05/08/19 10:52 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 103 %. 102 %. 95 %. 106 %. Analytical Method: EPA 8260D Mod. 11.5 ug/L 90 % 75 % 1.0 1 05/22/19 13:14 79-01-6 1.0 1 05/22/19 13:14 75-69-4 2.0 1 05/22/19 13:14 108-05-4 1.0 1 05/22/19 13:14 75-01-4 2.0 1 05/22/19 13:14 1330-20-7 1.0 1 05/22/19 13:14 156-59-2 1.0 1 05/22/19 13:14 10061-01-5 1.0 1 05/22/19 13:14 156-60-5 1.0 1 05/22/19 13:14 10061-02-6 81-119 1 05/22/19 13:14 17060-07-0 82-114 1 05/22/19 13:14 1868-53-7 82-120 1 05/22/19 13:14 460-00-4 82-109 1 05/22/19 13:14 2037-26-5 2.0 1 05/20/19 17:02 123-91-1 50-150 1 05/20/19 17:02 17060-07-0 50-150 1 05/20/19 17:02 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 57 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-F Lab ID: 2618294023 Collected: 05/09/19 08:14 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 6.57 Std. Units 1 05/22/19 11:39 14.3 deg C 1 05/22/19 11:39 478.3 umhos/cm 1 05/22/19 11:39 800+ NTU 1 05/22/19 11:39 -69.4 mV 1 05/22/19 11:39 15.5 mg/L 1 05/22/19 11:39 7782-44-7 N2 8.09 feet 1 05/22/19 11:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-36-0 2AJ ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-38-2 188 ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/20/1916:11 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1916:11 7440-43-9 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-47-3 7.2 ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-48-4 6.6 ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-50-8 ND ug/L 1.0 1 05/16/1914:34 05/20/1916:11 7439-92-1 4.5J ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1916:11 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1916:11 7440-28-0 ND ug/L 10.0 1 05/16/1914:34 05/20/1916:11 7440-62-2 8.9J ug/L 10.0 1 05/16/1914:34 05/20/1916:11 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 58 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-G Lab ID: 2618294024 Collected: 05/08/19 12:16 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.39 Std. Units 1 05/22/19 11:39 Field Temperature 15.0 deg C 1 05/22/19 11:39 Field Specific Conductance 1576 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential -82.9 my 1 05/22/19 11:39 Oxygen, Dissolved 22.8 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 9.23 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 13:40 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 13:40 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 13:40 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 13:40 79-00-5 1,1-Dichloroethane 0.93J ug/L 1.0 1 05/22/19 13:40 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 13:40 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 13:40 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 13:40 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 13:40 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 13:40 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 13:40 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 13:40 78-87-5 1,4-Dichlorobenzene 1.5 ug/L 1.0 1 05/22/19 13:40 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 13:40 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 13:40 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 13:40 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 13:40 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 13:40 107-13-1 Benzene 0.25J ug/L 1.0 1 05/22/19 13:40 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 13:40 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 13:40 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 13:40 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 13:40 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 13:40 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 13:40 56-23-5 Chlorobenzene 3.9 ug/L 1.0 1 05/22/19 13:40 108-90-7 Chloroethane 0.80J ug/L 1.0 1 05/22/19 13:40 75-00-3 Chloroform ND ug/L 1.0 1 05/22/19 13:40 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 13:40 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 13:40 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 13:40 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 13:40 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 13:40 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/22/19 13:40 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 13:40 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/22/19 13:40 127-18-4 Tetrahydrofuran 1.51 ug/L 10.0 1 05/22/19 13:40 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 13:40 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-G Lab ID: 2618294024 Collected: 05/08/19 12:16 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 %. 97 %. 97 %. 107 %. Analytical Method: EPA 8260D Mod. 85.9 ug/L 92 % 76 % 1.0 1 05/22/19 13:40 79-01-6 1.0 1 05/22/19 13:40 75-69-4 2.0 1 05/22/19 13:40 108-05-4 1.0 1 05/22/19 13:40 75-01-4 2.0 1 05/22/19 13:40 1330-20-7 1.0 1 05/22/19 13:40 156-59-2 1.0 1 05/22/19 13:40 10061-01-5 1.0 1 05/22/19 13:40 156-60-5 1.0 1 05/22/19 13:40 10061-02-6 81-119 1 05/22/19 13:40 17060-07-0 82-114 1 05/22/19 13:40 1868-53-7 82-120 1 05/22/19 13:40 460-00-4 82-109 1 05/22/19 13:40 2037-26-5 2.0 1 05/20/19 17:21 123-91-1 50-150 1 05/20/19 17:21 17060-07-0 50-150 1 05/20/19 17:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 60 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-G Lab ID: 2618294025 Collected: 05/09/19 08:29 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method: 6.23 Std. Units 1 05/22/19 11:39 15.0 deg C 1 05/22/19 11:39 161 umhos/cm 1 05/22/19 11:39 800+ NTU 1 05/22/19 11:39 118.5 mV 1 05/22/19 11:39 47.4 mg/L 1 05/22/19 11:39 7782-44-7 27.35 feet 1 05/22/19 11:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-36-0 2AJ ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-38-2 464 ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-39-3 0.13J ug/L 0.50 1 05/16/1914:34 05/21/1918:08 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:08 7440-43-9 0.79J ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-47-3 14.6 ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-48-4 0.43J ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-50-8 0.11J ug/L 1.0 1 05/16/1914:34 05/21/1918:08 7439-92-1 10.9 ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:08 7440-22-4 0.061J ug/L 1.0 1 05/16/1914:34 05/21/1918:08 7440-28-0 0.74J ug/L 10.0 1 05/16/1914:34 05/21/1918:08 7440-62-2 3.8J ug/L 10.0 1 05/16/1914:34 05/21/1918:08 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 Page 61 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H Lab ID: 2618294026 Collected: 05/08/19 16:05 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 5.12 NTU 1 05/22/19 11:39 8270E MSSV Water Analytical Method: EPA 8270E Preparation Method: EPA 3510C bis(2- Ethyl hexyl)phthalate ND ug/L 15.0 1 05/15/19 11:30 05/15/19 19:43 117-81-7 Surrogates Nitrobenzene-d5 (S) 45 %. 13-107 1 05/15/19 11:30 05/15/19 19:43 4165-60-0 2-Fluorobiphenyl (S) 65 %. 12-129 1 05/15/19 11:30 05/15/19 19:43 321-60-8 Phenol-d6 (S) 19 %. 10-46 1 05/15/19 11:30 05/15/19 19:43 13127-88-3 2-Fluorophenol (S) 26 %. 10-64 1 05/15/19 11:30 05/15/19 19:43 367-12-4 2,4,6-Tribromophenol (S) 69 %. 10-148 1 05/15/19 11:30 05/15/19 19:43 118-79-6 p-Terphenyl-d14 (S) 86 %. 14-147 1 05/15/19 11:30 05/15/19 19:43 1718-51-0 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:06 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 14:06 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:06 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 14:06 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/22/19 14:06 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 14:06 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 14:06 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 14:06 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 14:06 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:06 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 14:06 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 14:06 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:06 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 14:06 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 14:06 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 14:06 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 14:06 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 14:06 107-13-1 Benzene ND ug/L 1.0 1 05/22/19 14:06 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 14:06 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 14:06 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 14:06 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 14:06 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 14:06 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 14:06 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/22/19 14:06 108-90-7 Chloroethane ND ug/L 1.0 1 05/22/19 14:06 75-00-3 Chloroform ND ug/L 1.0 1 05/22/19 14:06 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 14:06 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 14:06 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 14:06 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 14:06 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 14:06 74-88-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H Lab ID: 2618294026 Collected: 05/08/19 16:05 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Methylene Chloride ND ug/L 1.0 1 05/22/19 14:06 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 14:06 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/22/19 14:06 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/22/19 14:06 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 14:06 108-88-3 Trichloroethene ND ug/L 1.0 1 05/22/19 14:06 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/22/19 14:06 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/22/19 14:06 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/22/19 14:06 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/22/19 14:06 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/22/19 14:06 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 14:06 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/22/19 14:06 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 14:06 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 103 %. 81-119 1 05/22/19 14:06 17060-07-0 Dibromofluoromethane (S) 97 %. 82-114 1 05/22/19 14:06 1868-53-7 4-Bromofluorobenzene (S) 108 %. 82-120 1 05/22/19 14:06 460-00-4 Toluene-d8 (S) 107 %. 82-109 1 05/22/19 14:06 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 1.4J ug/L 2.0 1 05/20/19 17:41 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 90 % 50-150 1 05/20/19 17:41 17060-07-0 Toluene-d8 (S) 75 % 50-150 1 05/20/19 17:41 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 63 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H Lab ID: 2618294027 Collected: 05/09/19 08:59 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method: 6.23 Std. Units 1 05/22/19 11:39 15.0 deg C 1 05/22/19 11:39 161 umhos/cm 1 05/22/19 11:39 800+ NTU 1 05/22/19 11:39 118.5 mV 1 05/22/19 11:39 47.4 mg/L 1 05/22/19 11:39 7782-44-7 27.35 feet 1 05/22/19 11:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-38-2 32.7 ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-39-3 0.13J ug/L 0.50 1 05/16/1914:34 05/21/1918:13 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:13 7440-43-9 1.3J ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-47-3 0.47J ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-48-4 2.9J ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-50-8 0.48J ug/L 1.0 1 05/16/1914:34 05/21/1918:13 7439-92-1 2.8J ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:13 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:13 7440-28-0 4.7J ug/L 10.0 1 05/16/1914:34 05/21/1918:13 7440-62-2 7.3J ug/L 10.0 1 05/16/1914:34 05/21/1918:13 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 Page 64 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H DEEP Lab ID: 2618294028 Collected: 05/08/19 15:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.47 Std. Units 1 05/22/19 11:39 Field Temperature 16.2 deg C 1 05/22/19 11:39 Field Specific Conductance 261 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 95.2 my 1 05/22/19 11:39 Oxygen, Dissolved 27.5 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 21.76 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:32 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 14:32 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:32 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 14:32 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/22/19 14:32 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 14:32 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 14:32 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 14:32 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 14:32 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:32 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 14:32 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 14:32 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:32 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 14:32 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 14:32 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 14:32 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 14:32 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 14:32 107-13-1 Benzene ND ug/L 1.0 1 05/22/19 14:32 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 14:32 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 14:32 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 14:32 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 14:32 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 14:32 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 14:32 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/22/19 14:32 108-90-7 Chloroethane ND ug/L 1.0 1 05/22/19 14:32 75-00-3 Chloroform ND ug/L 1.0 1 05/22/19 14:32 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 14:32 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 14:32 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 14:32 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 14:32 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 14:32 74-88-4 Methylene Chloride 0.52J ug/L 1.0 1 05/22/19 14:32 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 14:32 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/22/19 14:32 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/22/19 14:32 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 14:32 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 65 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H DEEP Lab ID: 2618294028 Collected: 05/08/19 15:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 %. 98 %. 113 %. 106 %. Analytical Method: EPA 8260D Mod. ND ug/L 90 % 75 % 1.0 1 05/22/19 14:32 79-01-6 1.0 1 05/22/19 14:32 75-69-4 2.0 1 05/22/19 14:32 108-05-4 1.0 1 05/22/19 14:32 75-01-4 2.0 1 05/22/19 14:32 1330-20-7 1.0 1 05/22/19 14:32 156-59-2 1.0 1 05/22/19 14:32 10061-01-5 1.0 1 05/22/19 14:32 156-60-5 1.0 1 05/22/19 14:32 10061-02-6 81-119 1 05/22/19 14:32 17060-07-0 82-114 1 05/22/19 14:32 1868-53-7 82-120 1 05/22/19 14:32 460-00-4 82-109 1 05/22/19 14:32 2037-26-5 2.0 1 05/20/19 18:00 123-91-1 50-150 1 05/20/19 18:00 17060-07-0 50-150 1 05/20/19 18:00 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 66 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-H DEEP Lab ID: 2618294029 Collected: 05/09/19 08:56 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 6.31 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-38-2 42.0 ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:19 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:19 7440-43-9 0.52J ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-47-3 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-48-4 1.1J ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-50-8 0.17J ug/L 1.0 1 05/16/1914:34 05/21/1918:19 7439-92-1 0.83J ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:19 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:19 7440-28-0 4AJ ug/L 10.0 1 05/16/1914:34 05/21/1918:19 7440-62-2 3.2J ug/L 10.0 1 05/16/1914:34 05/21/1918:19 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 67 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294030 Collected: 05/08/19 14:27 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.15 Std. Units 1 05/22/19 11:39 Field Temperature 15.8 deg C 1 05/22/19 11:39 Field Specific Conductance 130 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 115.9 mV 1 05/22/19 11:39 Oxygen, Dissolved 59.6 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 41.83 feet 1 05/22/19 11:39 8270E MSSV Water Analytical Method: EPA 8270E Preparation Method: EPA 3510C bis(2- Ethyl hexyl)phthalate ND ug/L 15.0 1 05/15/19 11:30 05/15/19 20:05 117-81-7 Surrogates Nitrobenzene-d5 (S) 41 %. 13-107 1 05/15/19 11:30 05/15/19 20:05 4165-60-0 2-Fluorobiphenyl (S) 65 %. 12-129 1 05/15/19 11:30 05/15/19 20:05 321-60-8 Phenol-d6 (S) 13 %. 10-46 1 05/15/19 11:30 05/15/19 20:05 13127-88-3 2-Fluorophenol (S) 20 %. 10-64 1 05/15/19 11:30 05/15/19 20:05 367-12-4 2,4,6-Tribromophenol (S) 67 %. 10-148 1 05/15/19 11:30 05/15/19 20:05 118-79-6 p-Terphenyl-d14 (S) 88 %. 14-147 1 05/15/19 11:30 05/15/19 20:05 1718-51-0 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:58 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 14:58 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 14:58 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 14:58 79-00-5 1,1-Dichloroethane 6.9 ug/L 1.0 1 05/22/19 14:58 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 14:58 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 14:58 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 14:58 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 14:58 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:58 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 14:58 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 14:58 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 14:58 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 14:58 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 14:58 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 14:58 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 14:58 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 14:58 107-13-1 Benzene ND ug/L 1.0 1 05/22/19 14:58 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 14:58 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 14:58 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 14:58 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 14:58 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 14:58 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 14:58 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/22/19 14:58 108-90-7 Chloroethane ND ug/L 1.0 1 05/22/19 14:58 75-00-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 68 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294030 Collected: 05/08/19 14:27 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Chloroform ND ug/L 1.0 1 05/22/19 14:58 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 14:58 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 14:58 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 14:58 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 14:58 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 14:58 74-88-4 Methylene Chloride 0.61J ug/L 1.0 1 05/22/19 14:58 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 14:58 100-42-5 Tetrachloroethene 3.6 ug/L 1.0 1 05/22/19 14:58 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/22/19 14:58 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 14:58 108-88-3 Trichloroethene 2.4 ug/L 1.0 1 05/22/19 14:58 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/22/19 14:58 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/22/19 14:58 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/22/19 14:58 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/22/19 14:58 1330-20-7 cis-1,2-Dichloroethene 4.5 ug/L 1.0 1 05/22/19 14:58 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 14:58 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/22/19 14:58 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 14:58 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 103 %. 81-119 1 05/22/19 14:58 17060-07-0 Dibromofluoromethane (S) 101 %. 82-114 1 05/22/19 14:58 1868-53-7 4-Bromofluorobenzene (S) 99 %. 82-120 1 05/22/19 14:58 460-00-4 Toluene-d8 (S) 106 %. 82-109 1 05/22/19 14:58 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/20/19 18:19 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 90 % 50-150 1 05/20/19 18:19 17060-07-0 Toluene-d8 (S) 77 % 50-150 1 05/20/19 18:19 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 69 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-1 Lab ID: 2618294031 Collected: 05/09/19 08:47 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 5.52 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-38-2 17.8 ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-39-3 0.18J ug/L 0.50 1 05/16/1914:34 05/21/1918:25 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:25 7440-43-9 1.2J ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-47-3 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-48-4 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-50-8 0.24J ug/L 1.0 1 05/16/1914:34 05/21/1918:25 7439-92-1 1.2J ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:25 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:25 7440-28-0 4.9J ug/L 10.0 1 05/16/1914:34 05/21/1918:25 7440-62-2 3.3J ug/L 10.0 1 05/16/1914:34 05/21/1918:25 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 70 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-J Lab ID: 2618294032 Collected: 05/09/19 10:35 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.58 Std. Units 1 05/22/19 11:39 Field Temperature 16.1 deg C 1 05/22/19 11:39 Field Specific Conductance 245 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 154.5 my 1 05/22/19 11:39 Oxygen, Dissolved 2.45 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 27.62 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 01:23 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 01:23 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 01:23 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 01:23 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 01:23 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 01:23 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 01:23 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 01:23 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 01:23 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 01:23 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 01:23 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 01:23 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 01:23 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 01:23 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 01:23 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 01:23 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 01:23 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 01:23 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 01:23 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 01:23 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 01:23 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 01:23 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 01:23 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 01:23 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 01:23 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 01:23 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 01:23 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 01:23 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 01:23 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 01:23 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 01:23 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 01:23 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 01:23 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 01:23 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 01:23 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 01:23 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 01:23 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 01:23 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-J Lab ID: 2618294032 Collected: 05/09/19 10:35 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 105 %. 98 %. 107 %. 106 %. Analytical Method: EPA 8260D Mod. ND ug/L 88 % 75 % 1.0 1 05/23/19 01:23 79-01-6 1.0 1 05/23/19 01:23 75-69-4 2.0 1 05/23/19 01:23 108-05-4 1.0 1 05/23/19 01:23 75-01-4 2.0 1 05/23/19 01:23 1330-20-7 1.0 1 05/23/19 01:23 156-59-2 1.0 1 05/23/19 01:23 10061-01-5 1.0 1 05/23/19 01:23 156-60-5 1.0 1 05/23/19 01:23 10061-02-6 81-119 1 05/23/19 01:23 17060-07-0 82-114 1 05/23/19 01:23 1868-53-7 82-120 1 05/23/19 01:23 460-00-4 82-109 1 05/23/19 01:23 2037-26-5 2.0 1 05/20/19 20:15 123-91-1 50-150 1 05/20/19 20:15 17060-07-0 50-150 1 05/20/19 20:15 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 72 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-J Lab ID: 2618294033 Collected: 05/10/19 08:01 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 8.72 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-36-0 0.48J ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-38-2 19.0 ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-39-3 0.11J ug/L 0.50 1 05/16/1914:34 05/21/1918:30 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:30 7440-43-9 1.6J ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-47-3 0.70J ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-48-4 0.82J ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-50-8 0.93J ug/L 1.0 1 05/16/1914:34 05/21/1918:30 7439-92-1 1.6J ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:30 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:30 7440-28-0 7AJ ug/L 10.0 1 05/16/1914:34 05/21/1918:30 7440-62-2 6.3J ug/L 10.0 1 05/16/1914:34 05/21/1918:30 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 73 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-K Lab ID: 2618294034 Collected: 05/09/19 10:35 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.06 Std. Units 1 05/22/19 11:39 Field Temperature 15.9 deg C 1 05/22/19 11:39 Field Specific Conductance 181 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 140.0 my 1 05/22/19 11:39 Oxygen, Dissolved 2.45 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 19.61 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 01:49 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 01:49 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 01:49 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 01:49 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 01:49 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 01:49 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 01:49 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 01:49 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 01:49 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 01:49 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 01:49 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 01:49 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 01:49 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 01:49 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 01:49 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 01:49 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 01:49 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 01:49 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 01:49 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 01:49 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 01:49 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 01:49 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 01:49 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 01:49 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 01:49 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 01:49 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 01:49 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 01:49 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 01:49 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 01:49 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 01:49 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 01:49 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 01:49 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 01:49 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 01:49 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 01:49 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 01:49 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 01:49 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 74 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-K Lab ID: 2618294034 Collected: 05/09/19 10:35 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 106 %. 102 %. 99 %. Analytical Method: EPA 8260D Mod. ND ug/L 91 % 75 % 1.0 1 05/23/19 01:49 79-01-6 1.0 1 05/23/19 01:49 75-69-4 2.0 1 05/23/19 01:49 108-05-4 1.0 1 05/23/19 01:49 75-01-4 2.0 1 05/23/19 01:49 1330-20-7 1.0 1 05/23/19 01:49 156-59-2 1.0 1 05/23/19 01:49 10061-01-5 1.0 1 05/23/19 01:49 156-60-5 1.0 1 05/23/19 01:49 10061-02-6 81-119 1 05/23/19 01:49 17060-07-0 82-114 1 05/23/19 01:49 1868-53-7 82-120 1 05/23/19 01:49 460-00-4 82-109 1 05/23/19 01:49 2037-26-5 2.0 1 05/20/19 20:34 123-91-1 50-150 1 05/20/19 20:34 17060-07-0 50-150 1 05/20/19 20:34 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 75 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-K Lab ID: 2618294035 Collected: 05/10/19 07:27 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 4.21 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-38-2 15.8 ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-39-3 0.0891 ug/L 0.50 1 05/16/1914:34 05/21/1918:36 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:36 7440-43-9 1.8J ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-47-3 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-48-4 1.0J ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-50-8 0.23J ug/L 1.0 1 05/16/1914:34 05/21/1918:36 7439-92-1 1.2J ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:36 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:36 7440-28-0 5.1J ug/L 10.0 1 05/16/1914:34 05/21/1918:36 7440-62-2 3.7J ug/L 10.0 1 05/16/1914:34 05/21/1918:36 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 76 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-M Lab ID: 2618294036 Collected: 05/09/19 09:41 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.53 Std. Units 1 05/22/19 11:39 Field Temperature 15.7 deg C 1 05/22/19 11:39 Field Specific Conductance 287 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 324.7 my 1 05/22/19 11:39 Oxygen, Dissolved 28.4 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 17.56 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 02:15 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 02:15 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 02:15 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 02:15 79-00-5 1,1-Dichloroethane 1.2 ug/L 1.0 1 05/23/19 02:15 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 02:15 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 02:15 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 02:15 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 02:15 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 02:15 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 02:15 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 02:15 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 02:15 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 02:15 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 02:15 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 02:15 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 02:15 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 02:15 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 02:15 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 02:15 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 02:15 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 02:15 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 02:15 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 02:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 02:15 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 02:15 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 02:15 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 02:15 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 02:15 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 02:15 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 02:15 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 02:15 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 02:15 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 02:15 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 02:15 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 02:15 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 02:15 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 02:15 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 77 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-M Lab ID: 2618294036 Collected: 05/09/19 09:41 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D 0.38J ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 108 %. 104 %. 118 %. 108 %. Analytical Method: EPA 8260D Mod. 2.2 ug/L 89 % 76 % 1.0 1 05/23/19 02:15 79-01-6 1.0 1 05/23/19 02:15 75-69-4 2.0 1 05/23/19 02:15 108-05-4 1.0 1 05/23/19 02:15 75-01-4 2.0 1 05/23/19 02:15 1330-20-7 1.0 1 05/23/19 02:15 156-59-2 1.0 1 05/23/19 02:15 10061-01-5 1.0 1 05/23/19 02:15 156-60-5 1.0 1 05/23/19 02:15 10061-02-6 81-119 1 05/23/19 02:15 17060-07-0 82-114 1 05/23/19 02:15 1868-53-7 82-120 1 05/23/19 02:15 460-00-4 82-109 1 05/23/19 02:15 2037-26-5 2.0 1 05/20/19 20:53 123-91-1 50-150 1 05/20/19 20:53 17060-07-0 50-150 1 05/20/19 20:53 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 78 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-M Lab ID: 2618294037 Collected: 05/10/19 07:12 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field pH Field Temperature Field Specific Conductance Field Turbidity Field Oxidation Potential Oxygen, Dissolved Depth to Water 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method: 6.53 Std. Units 1 05/22/19 11:39 15.7 deg C 1 05/22/19 11:39 287 umhos/cm 1 05/22/19 11:39 800+ NTU 1 05/22/19 11:39 324.7 mV 1 05/22/19 11:39 28.4 mg/L 1 05/22/19 11:39 7782-44-7 17.56 feet 1 05/22/19 11:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-38-2 49.1 ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:42 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:42 7440-43-9 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-47-3 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-48-4 1.7J ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-50-8 0.097J ug/L 1.0 1 05/16/1914:34 05/21/1918:42 7439-92-1 0.901 ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:42 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:42 7440-28-0 5.1J ug/L 10.0 1 05/16/1914:34 05/21/1918:42 7440-62-2 1.81 ug/L 10.0 1 05/16/1914:34 05/21/1918:42 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. N2 Page 79 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-X Lab ID: 2618294038 Collected: 05/09/19 11:11 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.28 Std. Units 1 05/22/19 11:39 Field Temperature 14.7 deg C 1 05/22/19 11:39 Field Specific Conductance 181 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 137.0 my 1 05/22/19 11:39 Oxygen, Dissolved 1.33 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 13.21 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 02:41 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 02:41 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 02:41 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 02:41 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 02:41 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 02:41 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 02:41 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 02:41 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 02:41 106-93-4 v1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 02:41 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 02:41 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 02:41 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 02:41 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 02:41 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 02:41 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 02:41 108-10-1 Acetone ND ug/L 25.0 1 05/23/19 02:41 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 02:41 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 02:41 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 02:41 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 02:41 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 02:41 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 02:41 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 02:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 02:41 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 02:41 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 02:41 75-00-3 Chloroform ND ug/L 1.0 1 05/23/19 02:41 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 02:41 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 02:41 124-48-1 Dibromomethane ND ug/L 1.0 1 05/23/19 02:41 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/23/19 02:41 100-41-4 lodomethane ND ug/L 10.0 1 05/23/19 02:41 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/23/19 02:41 75-09-2 Styrene ND ug/L 1.0 1 05/23/19 02:41 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/23/19 02:41 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/23/19 02:41 109-99-9 Toluene ND ug/L 1.0 1 05/23/19 02:41 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 80 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-X Lab ID: 2618294038 Collected: 05/09/19 11:11 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 108 %. 102 %. 109 %. 118 %. Analytical Method: EPA 8260D Mod. 1.51 ug/L 103 % 101 % 1.0 1 05/23/19 02:41 79-01-6 1.0 1 05/23/19 02:41 75-69-4 2.0 1 05/23/19 02:41 108-05-4 1.0 1 05/23/19 02:41 75-01-4 2.0 1 05/23/19 02:41 1330-20-7 1.0 1 05/23/19 02:41 156-59-2 1.0 1 05/23/19 02:41 10061-01-5 1.0 1 05/23/19 02:41 156-60-5 1.0 1 05/23/19 02:41 10061-02-6 81-119 1 05/23/19 02:41 17060-07-0 82-114 1 05/23/19 02:41 1868-53-7 82-120 1 05/23/19 02:41 460-00-4 82-109 1 05/23/19 02:41 2037-26-5 S3 2.0 1 05/21 /19 13:07 123-91-1 50-150 1 05/21 /19 13:07 17060-07-0 50-150 1 05/21/1913:07 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 81 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-MW-X Lab ID: 2618294039 Collected: 05/10/19 07:49 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 4.37 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-38-2 27.3 ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:48 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1918:48 7440-43-9 1.0J ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-47-3 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-48-4 2AJ ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-50-8 0.191 ug/L 1.0 1 05/16/1914:34 05/21/1918:48 7439-92-1 3.1J ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1918:48 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1918:48 7440-28-0 5.51 ug/L 10.0 1 05/16/1914:34 05/21/1918:48 7440-62-2 ND ug/L 10.0 1 05/16/1914:34 05/21/1918:48 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 82 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-DUPLICATE Lab ID: 2618294040 Collected: 05/08/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 15:24 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/22/19 15:24 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/22/19 15:24 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/22/19 15:24 79-00-5 1,1-Dichloroethane 1.9 ug/L 1.0 1 05/22/19 15:24 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/22/19 15:24 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/22/19 15:24 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/22/19 15:24 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/22/19 15:24 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/22/19 15:24 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/22/19 15:24 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/22/19 15:24 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/22/19 15:24 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/22/19 15:24 78-93-3 2-Hexanone ND ug/L 5.0 1 05/22/19 15:24 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/22/19 15:24 108-10-1 Acetone ND ug/L 25.0 1 05/22/19 15:24 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/22/19 15:24 107-13-1 Benzene ND ug/L 1.0 1 05/22/19 15:24 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/22/19 15:24 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/22/19 15:24 75-27-4 Bromoform ND ug/L 1.0 1 05/22/19 15:24 75-25-2 Bromomethane ND ug/L 2.0 1 05/22/19 15:24 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/22/19 15:24 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/22/19 15:24 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/22/19 15:24 108-90-7 Chloroethane ND ug/L 1.0 1 05/22/19 15:24 75-00-3 Chloroform ND ug/L 1.0 1 05/22/19 15:24 67-66-3 Chloromethane ND ug/L 1.0 1 05/22/19 15:24 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/22/19 15:24 124-48-1 Dibromomethane ND ug/L 1.0 1 05/22/19 15:24 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/22/19 15:24 100-41-4 lodomethane ND ug/L 10.0 1 05/22/19 15:24 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/22/19 15:24 75-09-2 Styrene ND ug/L 1.0 1 05/22/19 15:24 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/22/19 15:24 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/22/19 15:24 109-99-9 Toluene ND ug/L 1.0 1 05/22/19 15:24 108-88-3 Trichloroethene ND ug/L 1.0 1 05/22/19 15:24 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/22/19 15:24 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/22/19 15:24 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/22/19 15:24 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/22/19 15:24 1330-20-7 cis-1,2-Dichloroethene 0.77J ug/L 1.0 1 05/22/19 15:24 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 15:24 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/22/19 15:24 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/22/19 15:24 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 83 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-DUPLICATE Lab ID: 2618294040 Collected: 05/08/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Surrogates 1,2-Dichloroethane-d4 (S) 108 %. 81-119 1 05/22/19 15:24 17060-07-0 Dibromofluoromethane (S) 105 %. 82-114 1 05/22/19 15:24 1868-53-7 4-Bromofluorobenzene (S) 107 %. 82-120 1 05/22/19 15:24 460-00-4 Toluene-d8 (S) 100 %. 82-109 1 05/22/19 15:24 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 65.4 ug/L 2.0 1 05/20/19 18:39 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 92 % 50-150 1 05/20/19 18:39 17060-07-0 Toluene-d8 (S) 76 % 50-150 1 05/20/19 18:39 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 84 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-DUPLICATE Lab ID: 2618294041 Collected: 05/09/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-38-2 135 ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-39-3 ND ug/L 0.50 1 05/16/1914:34 05/21/1919:05 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/21/1919:05 7440-43-9 ND ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-47-3 12.3 ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-48-4 2.7J ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-50-8 0.12J ug/L 1.0 1 05/16/1914:34 05/21/1919:05 7439-92-1 27.8 ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/21/1919:05 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/21/1919:05 7440-28-0 ND ug/L 10.0 1 05/16/1914:34 05/21/1919:05 7440-62-2 2.5J ug/L 10.0 1 05/16/1914:34 05/21/1919:05 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 85 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-1 Lab ID: 2618430014 Collected: 05/09/19 11:58 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 7.17 Std. Units 1 05/23/19 13:38 Field Temperature 18.9 deg C 1 05/23/19 13:38 Field Specific Conductance 357 umhos/cm 1 05/23/19 13:38 Field Turbidity 10 NTU 1 05/23/19 13:38 Field Oxidation Potential 120.1 mV 1 05/23/19 13:38 Oxygen, Dissolved 4.06 mg/L 1 05/23/19 13:38 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-38-2 Barium 66.9 ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:02 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:02 7440-43-9 Chromium 0.76J ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-47-3 Cobalt 3.OJ ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-48-4 Copper 1.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-50-8 Lead 0.16J ug/L 1.0 1 05/16/1914:34 05/20/1915:02 7439-92-1 Nickel 5.1 ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1915:02 7440-28-0 Vanadium 1.3J ug/L 10.0 1 05/16/1914:34 05/20/1915:02 7440-62-2 Zinc 3.9J ug/L 10.0 1 05/16/1914:34 05/20/1915:02 7440-66-6 B 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:18 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 19:18 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:18 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 19:18 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 19:18 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 19:18 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 19:18 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 19:18 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:18 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 19:18 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 19:18 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:18 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 19:18 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 19:18 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 19:18 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 19:18 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 19:18 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 19:18 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 19:18 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 19:18 75-27-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-1 Lab ID: 2618430014 Collected: 05/09/19 11:58 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromoform ND ug/L 1.0 1 05/17/19 19:18 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 19:18 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 19:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 19:18 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 19:18 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 19:18 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 19:18 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 19:18 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 19:18 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 19:18 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 19:18 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 19:18 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 19:18 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 19:18 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 19:18 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 19:18 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 19:18 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 19:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 19:18 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 19:18 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 19:18 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 19:18 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 19:18 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 19:18 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 19:18 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 94 %. 81-119 1 05/17/19 19:18 17060-07-0 Dibromofluoromethane (S) 106 %. 82-114 1 05/17/19 19:18 1868-53-7 4-Bromofluorobenzene (S) 87 %. 82-120 1 05/17/19 19:18 460-00-4 Toluene-d8 (S) 83 %. 82-109 1 05/17/19 19:18 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 8.7 ug/L 2.0 1 05/19/19 17:59 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 50-150 1 05/19/19 17:59 17060-07-0 Toluene-d8 (S) 123 % 50-150 1 05/19/19 17:59 2037-26-5 Date: 06/04/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 Page 26 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-2 Lab ID: 2618430015 Collected: 05/09/19 11:47 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.74 Std. Units 1 05/23/19 13:38 Field Temperature 19.8 deg C 1 05/23/19 13:38 Field Specific Conductance 473 umhos/cm 1 05/23/19 13:38 Field Turbidity 8.78 NTU 1 05/23/19 13:38 Field Oxidation Potential 174.1 mV 1 05/23/19 13:38 Oxygen, Dissolved 5.07 mg/L 1 05/23/19 13:38 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-38-2 Barium 83.8 ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:08 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:08 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-47-3 Cobalt 2.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-48-4 Copper 1.7J ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-50-8 Lead ND ug/L 1.0 1 05/16/1914:34 05/20/1915:08 7439-92-1 Nickel 5.1 ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1915:08 7440-28-0 Vanadium ND ug/L 10.0 1 05/16/1914:34 05/20/1915:08 7440-62-2 Zinc 2.8J ug/L 10.0 1 05/16/1914:34 05/20/1915:08 7440-66-6 B 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 20:10 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 20:10 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 20:10 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 20:10 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 20:10 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 20:10 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 20:10 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 20:10 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 20:10 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 20:10 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 20:10 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 20:10 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 20:10 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 20:10 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 20:10 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 20:10 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 20:10 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 20:10 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 20:10 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 20:10 75-27-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-2 Lab ID: 2618430015 Collected: 05/09/19 11:47 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromoform ND ug/L 1.0 1 05/17/19 20:10 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 20:10 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 20:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 20:10 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 20:10 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 20:10 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 20:10 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 20:10 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 20:10 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 20:10 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 20:10 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 20:10 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 20:10 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 20:10 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 20:10 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 20:10 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 20:10 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 20:10 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 20:10 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 20:10 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 20:10 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 20:10 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 20:10 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 20:10 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 20:10 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 101 %. 81-119 1 05/17/19 20:10 17060-07-0 Dibromofluoromethane (S) 107 %. 82-114 1 05/17/19 20:10 1868-53-7 4-Bromofluorobenzene (S) 89 %. 82-120 1 05/17/19 20:10 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 20:10 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 7.3 ug/L 2.0 1 05/19/19 18:18 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 108 % 50-150 1 05/19/19 18:18 17060-07-0 Toluene-d8 (S) 125 % 50-150 1 05/19/19 18:18 2037-26-5 Date: 06/04/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 Page 28 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-Equipment Blank Lab ID: 2618294042 Collected: 05/10/19 13:05 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-38-2 Barium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:11 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:11 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-47-3 Cobalt ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-48-4 Copper 0.98J ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-50-8 Lead ND ug/L 1.0 1 05/16/1914:34 05/21/1919:11 7439-92-1 Nickel ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/21/1919:11 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/21/1919:11 7440-28-0 Vanadium ND ug/L 10.0 1 05/16/1914:34 05/21/1919:11 7440-62-2 Zinc 1.7J ug/L 10.0 1 05/16/1914:34 05/21/1919:11 7440-66-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 03:07 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/23/19 03:07 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/23/19 03:07 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/23/19 03:07 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/23/19 03:07 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/23/19 03:07 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/23/19 03:07 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/23/19 03:07 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/23/19 03:07 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/23/19 03:07 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/23/19 03:07 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/23/19 03:07 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/23/19 03:07 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/23/19 03:07 78-93-3 2-Hexanone ND ug/L 5.0 1 05/23/19 03:07 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/23/19 03:07 108-10-1 Acetone 8.7J ug/L 25.0 1 05/23/19 03:07 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/23/19 03:07 107-13-1 Benzene ND ug/L 1.0 1 05/23/19 03:07 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/23/19 03:07 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/23/19 03:07 75-27-4 Bromoform ND ug/L 1.0 1 05/23/19 03:07 75-25-2 Bromomethane ND ug/L 2.0 1 05/23/19 03:07 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/23/19 03:07 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/23/19 03:07 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/23/19 03:07 108-90-7 Chloroethane ND ug/L 1.0 1 05/23/19 03:07 75-00-3 Chloroform 6.3 ug/L 1.0 1 05/23/19 03:07 67-66-3 Chloromethane ND ug/L 1.0 1 05/23/19 03:07 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/23/19 03:07 124-48-1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. v1 Page 86 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-Equipment Blank Lab ID: 2618294042 Collected: 05/10/19 13:05 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Tetrahydrofuran Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L 1.0 1 05/23/19 03:07 74-95-3 ND ug/L 1.0 1 05/23/19 03:07 100-41-4 ND ug/L 10.0 1 05/23/19 03:07 74-88-4 2.6 ug/L 1.0 1 05/23/19 03:07 75-09-2 ND ug/L 1.0 1 05/23/19 03:07 100-42-5 ND ug/L 1.0 1 05/23/19 03:07 127-18-4 1.91 ug/L 10.0 1 05/23/19 03:07 109-99-9 ND ug/L 1.0 1 05/23/19 03:07 108-88-3 ND ug/L 1.0 1 05/23/19 03:07 79-01-6 ND ug/L 1.0 1 05/23/19 03:07 75-69-4 ND ug/L 2.0 1 05/23/19 03:07 108-05-4 ND ug/L 1.0 1 05/23/19 03:07 75-01-4 ND ug/L 2.0 1 05/23/19 03:07 1330-20-7 ND ug/L 1.0 1 05/23/19 03:07 156-59-2 ND ug/L 1.0 1 05/23/19 03:07 10061-01-5 ND ug/L 1.0 1 05/23/19 03:07 156-60-5 ND ug/L 1.0 1 05/23/19 03:07 10061-02-6 98 %. 81-119 1 05/23/19 03:07 17060-07-0 99 %. 82-114 1 05/23/19 03:07 1868-53-7 108 %. 82-120 1 05/23/19 03:07 460-00-4 106 %. 82-109 1 05/23/19 03:07 2037-26-5 Analytical Method: EPA 8260D Mod. ND ug/L 2.0 1 05/21/1913:26 123-91-1 99 % 50-150 1 05/21/1913:26 17060-07-0 100 % 50-150 1 05/21/1913:26 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 87 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-Trip Blank Lab ID: 2618294043 Collected: 05/07/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 15:22 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 15:22 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 15:22 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 15:22 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 15:22 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 15:22 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 15:22 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 15:22 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 15:22 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 15:22 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 15:22 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 15:22 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 15:22 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 15:22 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 15:22 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 15:22 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 15:22 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 15:22 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 15:22 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 15:22 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 15:22 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 15:22 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 15:22 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 15:22 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 15:22 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 15:22 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 15:22 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 15:22 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 15:22 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 15:22 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 15:22 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 15:22 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 15:22 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 15:22 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 15:22 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 15:22 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 15:22 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 15:22 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 15:22 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 15:22 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 15:22 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 15:22 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 15:22 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 15:22 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 15:22 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 15:22 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 15:22 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 88 of 182 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-Trip Blank Lab ID: 2618294043 Collected: 05/07/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Surrogates 1,2-Dichloroethane-d4 (S) 98 %. 81-119 1 05/17/19 15:22 17060-07-0 Dibromofluoromethane (S) 103 %. 82-114 1 05/17/19 15:22 1868-53-7 4-Bromofluorobenzene (S) 90 %. 82-120 1 05/17/19 15:22 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 15:22 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/19/19 13:23 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 110 % 50-150 1 05/19/19 13:23 17060-07-0 Toluene-d8 (S) 115 % 50-150 1 05/19/19 13:23 2037-26-5 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 89 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28114 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007, 2618294008 METHOD BLANK: 126553 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007, 2618294008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/L ND 0.00020 05/10/1916:02 METHOD BLANK: 126625 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007, 2618294008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/L ND 0.00020 05/10/1916:04 LABORATORY CONTROL SAMPLE: 126554 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/L 0.0025 0.0025 102 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126555 126556 MS MSD 2618227008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/L ND 0.0025 0.0025 0.0025 0.0025 100 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 90 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28368 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618294009, 2618294010, 2618294011 METHOD BLANK: 127725 Matrix: Water Associated Lab Samples: 2618294009, 2618294010, 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/L ND 0.00020 05/15/1911:08 LABORATORY CONTROL SAMPLE: 127726 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/L 0.0025 0.0027 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127727 127728 MS MSD 2618406039 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/L ND 0.0025 0.0025 0.0026 0.0026 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 91 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28295 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618294001, 2618294002, 2618294003 METHOD BLANK: 127445 Associated Lab Samples: Parameter Matrix: Water 2618294001,2618294002,2618294003 Blank Reporting Units Result Limit Antimony ug/L ND Arsenic ug/L ND Barium ug/L ND Beryllium ug/L ND Cadmium ug/L ND Chromium ug/L ND Cobalt ug/L ND Copper ug/L ND Lead ug/L ND Nickel ug/L ND Selenium ug/L ND Silver ug/L ND Thallium ug/L ND Vanadium ug/L ND Zinc ug/L ND Analyzed 5.0 05/14/1915:22 5.0 05/14/1915:22 5.0 05/14/1915:22 0.50 05/14/1915:22 0.50 05/14/1915:22 5.0 05/14/1915:22 5.0 05/14/1915:22 5.0 05/14/1915:22 1.0 05/14/1915:22 5.0 05/14/1915:22 5.0 05/14/1915:22 5.0 05/14/1915:22 1.0 05/14/1915:22 10.0 05/14/1915:22 10.0 05/14/1915:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 127446 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 96.7 97 80-120 Arsenic ug/L 100 97.1 97 80-120 Barium ug/L 100 95.6 96 80-120 Beryllium ug/L 100 99.5 99 80-120 Cadmium ug/L 100 97.0 97 80-120 Chromium ug/L 100 98.1 98 80-120 Cobalt ug/L 100 98.9 99 80-120 Copper ug/L 100 99.2 99 80-120 Lead ug/L 100 95.9 96 80-120 Nickel ug/L 100 97.5 98 80-120 Selenium ug/L 100 98.8 99 80-120 Silver ug/L 100 99.0 99 80-120 Thallium ug/L 100 95.8 96 80-120 Vanadium ug/L 100 99.9 100 80-120 Zinc ug/L 100 102 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 92 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127447 127448 MS MSD 2618227008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.0 93.7 98 94 75-125 5 20 Arsenic ug/L ND 100 100 92.7 92.9 93 93 75-125 0 20 Barium ug/L 37.6 100 100 131 127 93 89 75-125 3 20 Beryllium ug/L ND 100 100 104 101 103 101 75-125 3 20 Cadmium ug/L ND 100 100 95.7 94.7 96 95 75-125 1 20 Chromium ug/L ND 100 100 98.9 98.4 98 98 75-125 1 20 Cobalt ug/L ND 100 100 98.0 97.3 98 97 75-125 1 20 Copper ug/L ND 100 100 98.0 101 97 100 75-125 3 20 Lead ug/L ND 100 100 94.0 91.4 94 91 75-125 3 20 Nickel ug/L ND 100 100 97.6 95.5 97 95 75-125 2 20 Selenium ug/L ND 100 100 95.7 95.1 96 95 75-125 1 20 Silver ug/L ND 100 100 101 98.1 101 98 75-125 3 20 Thallium ug/L ND 100 100 94.2 91.9 94 92 75-125 2 20 Vanadium ug/L ND 100 100 100 98.8 99 98 75-125 2 20 Zinc ug/L ND 100 100 102 103 98 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 93 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28444 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007, 2618294008, 2618294009, 2618294010, 2618294011 METHOD BLANK: 128034 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007, 2618294008, 2618294009, 2618294010, 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony ug/L ND 5.0 05/16/1915:55 Arsenic ug/L ND 5.0 05/16/1915:55 Barium ug/L ND 5.0 05/16/1915:55 Beryllium ug/L ND 0.50 05/16/1915:55 Cadmium ug/L ND 0.50 05/16/1915:55 Chromium ug/L ND 5.0 05/16/1915:55 Cobalt ug/L ND 5.0 05/16/1915:55 Copper ug/L ND 5.0 05/16/1915:55 Lead ug/L ND 1.0 05/16/1915:55 Nickel ug/L ND 5.0 05/16/1915:55 Selenium ug/L ND 5.0 05/16/1915:55 Silver ug/L ND 5.0 05/16/1915:55 Thallium ug/L ND 1.0 05/16/1915:55 Vanadium ug/L ND 10.0 05/16/1915:55 Zinc ug/L ND 10.0 05/16/1915:55 LABORATORY CONTROL SAMPLE: 128035 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 101 101 80-120 Arsenic ug/L 100 97.8 98 80-120 Barium ug/L 100 99.6 100 80-120 Beryllium ug/L 100 99.4 99 80-120 Cadmium ug/L 100 99.2 99 80-120 Chromium ug/L 100 97.7 98 80-120 Cobalt ug/L 100 93.7 94 80-120 Copper ug/L 100 94.5 95 80-120 Lead ug/L 100 95.0 95 80-120 Nickel ug/L 100 94.8 95 80-120 Selenium ug/L 100 102 102 80-120 Silver ug/L 100 103 103 80-120 Thallium ug/L 100 95.3 95 80-120 Vanadium ug/L 100 97.8 98 80-120 Zinc ug/L 100 95.7 96 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 94 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128036 128037 MS MSD 2618406060 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 104 104 104 104 75-125 0 20 Arsenic ug/L ND 100 100 100 101 100 101 75-125 1 20 Barium ug/L ND 100 100 109 109 103 103 75-125 0 20 Beryllium ug/L ND 100 100 103 103 101 100 75-125 0 20 Cadmium ug/L ND 100 100 103 103 103 103 75-125 1 20 Chromium ug/L ND 100 100 106 103 104 101 75-125 3 20 Cobalt ug/L ND 100 100 100 99.0 100 99 75-125 1 20 Copper ug/L ND 100 100 101 101 100 100 75-125 0 20 Lead ug/L ND 100 100 97.1 100 97 100 75-125 3 20 Nickel ug/L ND 100 100 105 104 99 98 75-125 1 20 Selenium ug/L ND 100 100 105 104 104 104 75-125 0 20 Silver ug/L ND 100 100 106 105 106 105 75-125 1 20 Thallium ug/L ND 100 100 98.6 100 99 100 75-125 1 20 Vanadium ug/L ND 100 100 106 103 105 102 75-125 3 20 Zinc ug/L ND 100 100 107 104 102 99 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 95 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28518 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618294013, 2618294015, 2618294017, 2618294019, 2618294021, 2618294023 METHOD BLANK: 128448 Associated Lab Samples: Parameter Matrix: Water 2618294013, 2618294015, 2618294017, 2618294019, 2618294021, 2618294023 Blank Reporting Units Result Limit Analyzed Antimony ug/L ND 5.0 05/20/1913:39 Arsenic ug/L ND 5.0 05/20/1913:39 Barium ug/L ND 5.0 05/20/1913:39 Beryllium ug/L ND 0.50 05/20/1913:39 Cadmium ug/L ND 0.50 05/20/1913:39 Chromium ug/L ND 5.0 05/20/1913:39 Cobalt ug/L ND 5.0 05/20/1913:39 Copper ug/L ND 5.0 05/20/1913:39 Lead ug/L ND 1.0 05/20/1913:39 Nickel ug/L ND 5.0 05/20/1913:39 Selenium ug/L ND 5.0 05/20/1913:39 Silver ug/L ND 5.0 05/20/1913:39 Thallium ug/L ND 1.0 05/20/1913:39 Vanadium ug/L ND 10.0 05/20/1913:39 Zinc ug/L 1.6J 10.0 05/20/1913:39 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 128449 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 100 100 80-120 Arsenic ug/L 100 99.2 99 80-120 Barium ug/L 100 96.3 96 80-120 Beryllium ug/L 100 99.1 99 80-120 Cadmium ug/L 100 98.6 99 80-120 Chromium ug/L 100 99.1 99 80-120 Cobalt ug/L 100 96.7 97 80-120 Copper ug/L 100 99.3 99 80-120 Lead ug/L 100 96.9 97 80-120 Nickel ug/L 100 97.3 97 80-120 Selenium ug/L 100 99.1 99 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 99.5 100 80-120 Vanadium ug/L 100 100 100 80-120 Zinc ug/L 100 99.6 100 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 96 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128450 128451 MS MSD 2618294013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.2 98.6 98 98 75-125 0 20 Arsenic ug/L ND 100 100 96.5 99.2 96 99 75-125 3 20 Barium ug/L 45.9 100 100 142 140 96 94 75-125 2 20 Beryllium ug/L 0.38J 100 100 94.7 96.3 94 96 75-125 2 20 Cadmium ug/L ND 100 100 97.8 100 98 100 75-125 3 20 Chromium ug/L 2.3J 100 100 98.3 102 96 100 75-125 4 20 Cobalt ug/L 7.0 100 100 101 104 94 97 75-125 3 20 Copper ug/L 1 AJ 100 100 98.8 102 97 100 75-125 3 20 Lead ug/L 1.1 100 100 94.3 95.9 93 95 75-125 2 20 Nickel ug/L 5.8 100 100 100 105 95 99 75-125 5 20 Selenium ug/L ND 100 100 94.8 98.4 95 98 75-125 4 20 Silver ug/L ND 100 100 98.1 101 98 101 75-125 3 20 Thallium ug/L ND 100 100 94.5 95.6 94 96 75-125 1 20 Vanadium ug/L 6.2J 100 100 106 109 99 103 75-125 3 20 Zinc ug/L 13.7 100 100 105 109 92 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 97 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28521 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618294025, 2618294027, 2618294029, 2618294031, 2618294033, 2618294035, 2618294037, 2618294039, 2618294041,2618294042 METHOD BLANK: 128457 Matrix: Water Associated Lab Samples: 2618294025, 2618294027, 2618294029, 2618294031, 2618294033, 2618294035, 2618294037, 2618294039, 2618294041,2618294042 Parameter Blank Units Result Antimony ug/L Arsenic ug/L Barium ug/L Beryllium ug/L Cadmium ug/L Chromium ug/L Cobalt ug/L Copper ug/L Lead ug/L Nickel ug/L Selenium ug/L Silver ug/L Thallium ug/L Vanadium ug/L Zinc ug/L Reporting Limit Analyzed Qualifiers ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 0.50 05/21/1917:56 ND 0.50 05/21/1917:56 ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 1.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 5.0 05/21/1917:56 ND 1.0 05/21/1917:56 ND 10.0 05/21/1917:56 ND 10.0 05/21/1917:56 LABORATORY CONTROL SAMPLE: Parameter 128458 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 100 100 80-120 Arsenic ug/L 100 97.5 97 80-120 Barium ug/L 100 97.7 98 80-120 Beryllium ug/L 100 99.8 100 80-120 Cadmium ug/L 100 97.4 97 80-120 Chromium ug/L 100 98.5 99 80-120 Cobalt ug/L 100 99.0 99 80-120 Copper ug/L 100 99.9 100 80-120 Lead ug/L 100 98.4 98 80-120 Nickel ug/L 100 98.0 98 80-120 Selenium ug/L 100 93.4 93 80-120 Silver ug/L 100 104 104 80-120 Thallium ug/L 100 99.1 99 80-120 Vanadium ug/L 100 99.3 99 80-120 Zinc ug/L 100 101 101 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 98 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128459 128460 MS MSD 2618455008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 103 102 103 102 75-125 1 20 Arsenic ug/L ND 100 100 102 101 102 101 75-125 1 20 Barium ug/L 147 100 100 252 250 105 103 75-125 1 20 Beryllium ug/L 0.36J 100 100 96.1 97.6 96 97 75-125 2 20 Cadmium ug/L ND 100 100 99.7 101 100 101 75-125 1 20 Chromium ug/L 0.88J 100 100 103 103 102 103 75-125 0 20 Cobalt ug/L 5AJ 100 100 106 105 101 100 75-125 1 20 Copper ug/L 9.91 100 100 112 111 102 101 75-125 1 20 Lead ug/L 0.31J 100 100 98.4 98.0 98 98 75-125 0 20 Nickel ug/L 13.5J 100 100 112 113 99 99 75-125 0 20 Selenium ug/L ND 100 100 96.6 98.3 96 98 75-125 2 20 Silver ug/L ND 100 100 102 102 102 102 75-125 0 20 Thallium ug/L ND 100 100 98.6 99.0 99 99 75-125 0 20 Vanadium ug/L 4.7J 100 100 111 110 107 105 75-125 1 20 Zinc ug/L 8.8J 100 100 106 110 97 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 99 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28431 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294007 METHOD BLANK: 127981 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,1-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethene ug/L ND 1.0 05/15/19 11:28 1,2,3-Trichloropropane ug/L ND 1.0 05/15/19 11:28 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/15/19 11:28 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/15/19 11:28 1,2-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 1,2-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,2-Dichloropropane ug/L ND 1.0 05/15/19 11:28 1,4-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 2-Butanone (MEK) ug/L ND 5.0 05/15/19 11:28 2-Hexanone ug/L ND 5.0 05/15/19 11:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/15/19 11:28 Acetone ug/L ND 25.0 05/15/19 11:28 Acrylonitrile ug/L ND 50.0 05/15/19 11:28 Benzene ug/L ND 1.0 05/15/19 11:28 Bromochloromethane ug/L ND 1.0 05/15/19 11:28 Bromodichloromethane ug/L ND 1.0 05/15/19 11:28 Bromoform ug/L ND 1.0 05/15/19 11:28 Bromomethane ug/L ND 2.0 05/15/19 11:28 Carbon disulfide ug/L ND 10.0 05/15/19 11:28 Carbon tetrachloride ug/L ND 1.0 05/15/19 11:28 Chlorobenzene ug/L ND 1.0 05/15/19 11:28 Chloroethane ug/L ND 1.0 05/15/19 11:28 Chloroform ug/L ND 1.0 05/15/19 11:28 Chloromethane ug/L ND 1.0 05/15/19 11:28 cis-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 cis-1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Dibromochloromethane ug/L ND 1.0 05/15/19 11:28 Dibromomethane ug/L ND 1.0 05/15/19 11:28 Ethylbenzene ug/L ND 1.0 05/15/19 11:28 lodomethane ug/L ND 10.0 05/15/19 11:28 Methylene Chloride ug/L ND 1.0 05/15/19 11:28 Styrene ug/L ND 1.0 05/15/19 11:28 Tetrachloroethene ug/L ND 1.0 05/15/19 11:28 Tetrahydrofuran ug/L ND 10.0 05/15/19 11:28 Toluene ug/L ND 1.0 05/15/19 11:28 trans-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 V1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 100 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 METHOD BLANK: 127981 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Trichloroethene ug/L ND 1.0 05/15/19 11:28 Trichlorofluoromethane ug/L ND 1.0 05/15/19 11:28 Vinyl acetate ug/L ND 2.0 05/15/19 11:28 Vinyl chloride ug/L ND 1.0 05/15/19 11:28 Xylene (Total) ug/L ND 2.0 05/15/19 11:28 1,2-Dichloroethane-d4 (S) %. 93 81-119 05/15/19 11:28 4-Bromofluorobenzene (S) %. 96 82-120 05/15/19 11:28 Dibromofluoromethane (S) %. 98 82-114 05/15/19 11:28 Toluene-d8 (S) %. 100 82-109 05/15/19 11:28 LABORATORY CONTROL SAMPLE: 127982 Parameter Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.3 113 68-137 1,1,1-Trichloroethane ug/L 50 57.8 116 72-134 1,1,2,2-Tetrachloroethane ug/L 50 59.1 118 51-158 1,1,2-Trichloroethane ug/L 50 57.5 115 78-131 1,1-Dichloroethane ug/L 50 60.8 122 69-151 1,1-Dichloroethene ug/L 50 63.8 128 64-158 1,2,3-Trichloropropane ug/L 50 45.1 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 48.6 97 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.5 113 71-134 1,2-Dichlorobenzene ug/L 50 54.9 110 70-135 1,2-Dichloroethane ug/L 50 54.2 108 72-129 1,2-Dichloropropane ug/L 50 60.3 121 64-135 1,4-Dichlorobenzene ug/L 50 52.8 106 70-131 2-Butanone (MEK) ug/L 100 101 101 52-143 2-Hexanone ug/L 100 87.1 87 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 71-129 Acetone ug/L 100 88.7 89 48-224 Acrylonitrile ug/L 200 205 103 66-154 Benzene ug/L 50 57.5 115 68-132 Bromochloromethane ug/L 50 58.6 117 73-133 Bromodichloromethane ug/L 50 56.8 114 67-121 Bromoform ug/L 50 56.6 113 57-125 Bromomethane ug/L 50 48.0 96 35-156 Carbon disulfide ug/L 100 103 103 47-141 Carbon tetrachloride ug/L 50 64.4 129 66-122 L1,v1 Chlorobenzene ug/L 50 56.6 113 71-126 Chloroethane ug/L 50 47.3 95 43-143 Chloroform ug/L 50 51.3 103 71-136 Chloromethane ug/L 50 53.0 106 47-123 cis-1,2-Dichloroethene ug/L 50 61.1 122 74-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 101 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 LABORATORY CONTROL SAMPLE: Parameter 127982 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.9 116 78-120 Dibromochloromethane ug/L 50 56.4 113 65-115 Dibromomethane ug/L 50 62.9 126 79-129 Ethylbenzene ug/L 50 58.5 117 68-129 lodomethane ug/L 100 97.3 97 49-154 Methylene Chloride ug/L 50 56.8 114 61-147 Styrene ug/L 50 61.4 123 77-128 Tetrachloroethene ug/L 50 53.1 106 51-139 Tetrahydrofuran ug/L 100 101 101 56-147 Toluene ug/L 50 54.7 109 60-133 trans-1,2-Dichloroethene ug/L 50 63.4 127 69-144 trans- 1,3-Dichloropropene ug/L 50 50.0 100 74-128 Trichloroethene ug/L 50 54.2 108 73-126 Trichlorofluoromethane ug/L 50 59.1 118 55-132 Vinyl acetate ug/L 50 54.2 108 52-141 Vinyl chloride ug/L 50 51.5 103 50-133 Xylene (Total) ug/L 150 181 121 78-132 1,2-Dichloroethane-d4 (S) %. 92 81-119 4-Bromofluorobenzene (S) %. 95 82-120 Dibromofluoromethane (S) %. 95 82-114 Toluene-d8 (S) %. 97 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 55.2 48.8 110 98 68-137 12 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 61.0 53.7 122 107 66-142 13 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 60.5 50.2 121 100 39-171 19 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 56.6 50.8 113 102 73-136 11 12 1,1-Dichloroethane ug/L ND 50 50 57.6 54.2 115 108 66-155 6 15 1,1-Dichloroethene ug/L ND 50 50 66.9 63.4 134 127 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 43.4 35.3 87 71 78-133 21 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 47.2 38.4 94 77 58-124 21 15 R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.6 47.5 113 95 71-134 17 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 56.2 46.9 112 94 69-135 18 10 R1 1,2-Dichloroethane ug/L ND 50 50 54.3 49.3 109 99 36-159 10 10 1,2-Dichloropropane ug/L ND 50 50 60.0 53.0 120 106 68-132 12 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 54.0 47.7 108 95 49-153 12 9 R1 2-Butanone (MEK) ug/L ND 100 100 96.5 82.0 97 82 10-189 16 23 2-Hexanone ug/L ND 100 100 83.2 67.8 83 68 40-135 20 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 98.2 83.6 98 84 30-177 16 10 R1 (MIBK) Acetone ug/L ND 100 100 86.0 75.6 80 70 44-223 13 14 Acrylonitrile ug/L ND 200 200 191 160 95 80 13-189 18 12 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 102 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L ND 50 50 57.6 52.4 115 105 66-139 9 10 Bromochloromethane ug/L ND 50 50 59.4 53.3 119 107 73-133 11 13 Bromodichloromethane ug/L ND 50 50 55.5 49.5 111 99 57-120 11 13 Bromoform ug/L ND 50 50 53.5 44.4 107 89 48-128 18 13 R1 Bromomethane ug/L ND 50 50 37.8 39.3 76 79 10-187 4 32 Carbon disulfide ug/L ND 100 100 111 101 111 101 47-141 9 322 Carbon tetrachloride ug/L ND 50 50 72.2 64.1 144 128 58-127 12 14 MOM Chlorobenzene ug/L ND 50 50 55.2 48.2 110 96 63-137 14 10 R1 Chloroethane ug/L ND 50 50 50.6 45.5 101 91 52-146 11 16 Chloroform ug/L ND 50 50 50.5 46.5 101 93 74-137 8 9 Chloromethane ug/L ND 50 50 53.7 49.1 107 98 41-127 9 10 cis-1,2-Dichloroethene ug/L ND 50 50 60.1 54.4 120 109 71-138 10 16 cis-1,3-Dichloropropene ug/L ND 50 50 56.5 51.6 113 103 32-145 9 12 Dibromochloromethane ug/L ND 50 50 54.9 47.6 110 95 52-116 14 13 R1 Dibromomethane ug/L ND 50 50 60.9 52.8 122 106 79-129 14 14 Ethylbenzene ug/L ND 50 50 57.7 51.3 115 103 31-174 12 10 R1 lodomethane ug/L ND 100 100 95.6 107 96 107 49-154 12 30 Methylene Chloride ug/L ND 50 50 56.0 51.0 112 102 61-146 9 15 Styrene ug/L ND 50 50 60.2 52.4 120 105 77-128 14 14 Tetrachloroethene ug/L ND 50 50 56.5 50.9 113 102 36-155 10 14 Tetrahydrofuran ug/L ND 100 100 98.8 83.6 99 84 56-147 17 12 R1 Toluene ug/L ND 50 50 57.1 50.1 114 100 52-146 13 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 65.9 58.5 132 117 61-152 12 14 trans-1,3-Dichloropropene ug/L ND 50 50 48.6 41.7 97 83 37-146 15 12 R1 Trichloroethene ug/L ND 50 50 53.7 49.4 107 99 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.3 61.4 135 123 51-141 9 13 Vinyl acetate ug/L ND 50 50 49.9 44.4 100 89 52-141 12 14 Vinyl chloride ug/L ND 50 50 58.8 54.6 118 109 22-156 7 26 Xylene (Total) ug/L ND 150 150 179 159 119 106 78-132 12 7 RS 1,2-Dichloroethane-d4 (S) %. 96 95 81-119 4-Bromofluorobenzene (S) %. 98 96 82-120 Dibromofluoromethane (S) %. 97 98 82-114 Toluene-d8 (S) %. 98 98 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 103 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28582 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618294008, 2618294009, 2618294010, 2618294012, 2618294016, 2618294043 METHOD BLANK: 128690 Matrix: Water Associated Lab Samples: 2618294008, 2618294009, 2618294010, 2618294012, 2618294016, 2618294043 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 1,1,1-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 v2 1,1,2-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethene ug/L ND 1.0 05/17/19 11:54 1,2,3-Trichloropropane ug/L ND 1.0 05/17/19 11:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/17/19 11:54 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/17/19 11:54 1,2-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 1,2-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,2-Dichloropropane ug/L ND 1.0 05/17/19 11:54 1,4-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 2-Butanone (MEK) ug/L ND 5.0 05/17/19 11:54 2-Hexanone ug/L ND 5.0 05/17/19 11:54 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/17/19 11:54 Acetone ug/L ND 25.0 05/17/19 11:54 Acrylonitrile ug/L ND 50.0 05/17/19 11:54 Benzene ug/L ND 1.0 05/17/19 11:54 Bromochloromethane ug/L ND 1.0 05/17/19 11:54 Bromodichloromethane ug/L ND 1.0 05/17/19 11:54 Bromoform ug/L ND 1.0 05/17/19 11:54 Bromomethane ug/L ND 2.0 05/17/19 11:54 Carbon disulfide ug/L ND 10.0 05/17/19 11:54 Carbon tetrachloride ug/L ND 1.0 05/17/19 11:54 Chlorobenzene ug/L ND 1.0 05/17/19 11:54 Chloroethane ug/L ND 1.0 05/17/19 11:54 Chloroform ug/L ND 1.0 05/17/19 11:54 Chloromethane ug/L ND 1.0 05/17/19 11:54 cis-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 cis-1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 Dibromochloromethane ug/L ND 1.0 05/17/19 11:54 Dibromomethane ug/L ND 1.0 05/17/19 11:54 Ethylbenzene ug/L ND 1.0 05/17/19 11:54 lodomethane ug/L ND 10.0 05/17/19 11:54 Methylene Chloride ug/L ND 1.0 05/17/19 11:54 Styrene ug/L ND 1.0 05/17/19 11:54 Tetrachloroethene ug/L ND 1.0 05/17/19 11:54 Tetrahydrofuran ug/L ND 10.0 05/17/19 11:54 Toluene ug/L ND 1.0 05/17/19 11:54 trans-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 104 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 METHOD BLANK: 128690 Associated Lab Samples: Parameter Matrix: Water 2618294008, 2618294009, 2618294010, 2618294012, 2618294016, 2618294043 Blank Reporting Units Result Limit Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 Trichloroethene ug/L ND 1.0 05/17/19 11:54 Trichlorofluoromethane ug/L ND 1.0 05/17/19 11:54 Vinyl acetate ug/L ND 2.0 05/17/19 11:54 Vinyl chloride ug/L ND 1.0 05/17/19 11:54 Xylene (Total) ug/L ND 2.0 05/17/19 11:54 1,2-Dichloroethane-d4 (S) %. 97 81-119 05/17/19 11:54 4-Bromofluorobenzene (S) %. 86 82-120 05/17/19 11:54 Dibromofluoromethane (S) %. 103 82-114 05/17/19 11:54 Toluene-d8 (S) %. 83 82-109 05/17/19 11:54 LABORATORY CONTROL SAMPLE: Parameter 128691 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.2 106 68-137 1,1,1-Trichloroethane ug/L 50 65.3 131 72-134 1,1,2,2-Tetrachloroethane ug/L 50 42.8 86 51-158 v2 1,1,2-Trichloroethane ug/L 50 58.5 117 78-131 1,1-Dichloroethane ug/L 50 61.1 122 69-151 1,1-Dichloroethene ug/L 50 65.8 132 64-158 1,2,3-Trichloropropane ug/L 50 43.1 86 78-133 1,2-Dibromo-3-chloropropane ug/L 50 41.9 84 58-124 1,2-Dibromoethane (EDB) ug/L 50 57.7 115 71-134 1,2-Dichlorobenzene ug/L 50 51.2 102 70-135 1,2-Dichloroethane ug/L 50 60.2 120 72-129 1,2-Dichloropropane ug/L 50 53.9 108 64-135 1,4-Dichlorobenzene ug/L 50 48.5 97 70-131 2-Butanone (MEK) ug/L 100 93.2 93 52-143 2-Hexanone ug/L 100 80.2 80 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 88.3 88 71-129 Acetone ug/L 100 103 103 48-224 Acrylonitrile ug/L 200 184 92 66-154 Benzene ug/L 50 59.7 119 68-132 Bromochloromethane ug/L 50 71.5 143 73-133 L1 Bromodichloromethane ug/L 50 52.8 106 67-121 Bromoform ug/L 50 51.4 103 57-125 Bromomethane ug/L 50 48.2 96 35-156 Carbon disulfide ug/L 100 119 119 47-141 Carbon tetrachloride ug/L 50 65.2 130 66-122 L1 Chlorobenzene ug/L 50 49.3 99 71-126 Chloroethane ug/L 50 45.8 92 43-143 Chloroform ug/L 50 62.7 125 71-136 Chloromethane ug/L 50 43.0 86 47-123 cis-1,2-Dichloroethene ug/L 50 62.3 125 74-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 105 of 182 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW pacalabs.com (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 LABORATORY CONTROL SAMPLE: Parameter 128691 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers cis-1,3-Dichloropropene ug/L 50 52.3 105 78-120 Dibromochloromethane ug/L 50 57.8 116 65-115 L1 Dibromomethane ug/L 50 65.8 132 79-129 L1 Ethylbenzene ug/L 50 49.1 98 68-129 lodomethane ug/L 100 129 129 49-154 Methylene Chloride ug/L 50 61.4 123 61-147 Styrene ug/L 50 56.6 113 77-128 Tetrachloroethene ug/L 50 67.0 134 51-139 Tetrahydrofuran ug/L 100 94.9 95 56-147 Toluene ug/L 50 56.5 113 60-133 trans-1,2-Dichloroethene ug/L 50 63.8 128 69-144 trans- 1,3-Dichloropropene ug/L 50 52.2 104 74-128 Trichloroethene ug/L 50 51.4 103 73-126 Trichlorofluoromethane ug/L 50 57.7 115 55-132 Vinyl acetate ug/L 50 40.5 81 52-141 Vinyl chloride ug/L 50 49.6 99 50-133 Xylene (Total) ug/L 150 156 104 78-132 1,2-Dichloroethane-d4 (S) %. 100 81-119 4-Bromofluorobenzene (S) %. 89 82-120 Dibromofluoromethane (S) %. 114 82-114 Toluene-d8 (S) %. 81 82-109 SO MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 MS 2618430001 Spike Parameter Units Result Conc. MSD Spike Conc. 128693 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 35.9 51.3 72 103 68-137 35 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 52.0 70.2 104 140 66-142 30 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 28.6 40.1 57 80 39-171 34 13 R1,v2 1,1,2-Trichloroethane ug/L ND 50 50 40.5 55.7 81 111 73-136 32 12 R1 1,1-Dichloroethane ug/L ND 50 50 45.4 60.9 91 122 66-155 29 15 R1 1,1-Dichloroethene ug/L ND 50 50 56.1 75.8 112 152 33-181 30 34 1,2,3-Trichloropropane ug/L ND 50 50 27.8 39.6 56 79 78-133 35 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 28.5 39.4 57 79 58-124 32 15 M1,R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 40.4 55.0 81 110 71-134 31 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 34.5 48.8 68 97 69-135 34 10 M1,R1 1,2-Dichloroethane ug/L ND 50 50 42.2 57.8 84 116 36-159 31 10 R1 1,2-Dichloropropane ug/L ND 50 50 38.8 52.7 78 105 68-132 30 11 R1 1,4-Dichlorobenzene ug/L 9.9 50 50 42.6 56.1 65 92 49-153 27 9 R1 2-Butanone (MEK) ug/L ND 100 100 63.1 75.9 63 76 10-189 18 23 2-Hexanone ug/L ND 100 100 58.9 80.7 59 81 40-135 31 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 63.7 86.4 64 86 30-177 30 10 R1 (MIBK) Acetone ug/L ND 100 100 65.5 78.9 65 79 44-223 19 14 R1 Acrylonitrile ug/L ND 200 200 131 175 65 87 13-189 29 12 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 106 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 MS 2618430001 Spike Parameter Units Result Conc. MSD Spike Conc. 128693 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L 1.2 50 50 45.3 61.2 88 120 66-139 30 10 R1 Bromochloromethane ug/L ND 50 50 49.7 67.9 99 136 73-133 31 13 M0,R1 Bromodichloromethane ug/L ND 50 50 36.6 50.6 73 101 57-120 32 13 R1 Bromoform ug/L ND 50 50 33.0 46.0 66 92 48-128 33 13 R1 Bromomethane ug/L ND 50 50 28.6 45.9 57 92 10-187 47 32 R1 Carbon disulfide ug/L ND 100 100 97.4 130 97 130 47-141 29 322 Carbon tetrachloride ug/L ND 50 50 53.9 73.5 108 147 58-127 31 14 M0,R1 Chlorobenzene ug/L 18.2 50 50 52.2 65.6 68 95 63-137 23 10 R1 Chloroethane ug/L ND 50 50 37.3 50.6 75 101 52-146 30 16 R1 Chloroform ug/L ND 50 50 44.3 60.2 89 120 74-137 31 9 R1 Chloromethane ug/L ND 50 50 34.8 44.7 70 89 41-127 25 10 R1 cis-1,2-Dichloroethene ug/L ND 50 50 44.7 60.2 89 120 71-138 30 16 R1 cis-1,3-Dichloropropene ug/L ND 50 50 33.9 46.5 68 93 32-145 32 12 R1 Dibromochloromethane ug/L ND 50 50 38.8 53.9 78 108 52-116 33 13 R1 Dibromomethane ug/L ND 50 50 43.8 60.2 88 120 79-129 32 14 R1 Ethylbenzene ug/L ND 50 50 35.7 48.7 71 97 31-174 31 10 R1 lodomethane ug/L ND 100 100 102 138 102 138 49-154 30 30 Methylene Chloride ug/L ND 50 50 45.1 62.5 90 125 61-146 32 15 R1 Styrene ug/L ND 50 50 37.7 52.6 75 105 77-128 33 14 M1,R1 Tetrachloroethene ug/L ND 50 50 52.1 66.3 104 133 36-155 24 14 R1 Tetrahydrofuran ug/L ND 100 100 69.4 89.6 69 90 56-147 25 12 R1 Toluene ug/L ND 50 50 42.3 56.2 84 112 52-146 28 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 48.3 64.1 97 128 61-152 28 14 R1 trans-1,3-Dichloropropene ug/L ND 50 50 33.6 46.4 67 93 37-146 32 12 R1 Trichloroethene ug/L ND 50 50 38.0 49.6 76 99 61-141 26 12 R1 Trichlorofluoromethane ug/L ND 50 50 57.3 75.3 115 151 51-141 27 13 M1,R1 Vinyl acetate ug/L ND 50 50 50.5 30.5 101 61 52-141 49 14 R1 Vinyl chloride ug/L ND 50 50 42.9 57.3 85 114 22-156 29 26 R1 Xylene (Total) ug/L ND 150 150 112 152 74 102 78-132 31 7 RS 1,2-Dichloroethane-d4 (S) %. 98 97 81-119 4-Bromofluorobenzene (S) %. 88 89 82-120 Dibromofluoromethane (S) %. 110 113 82-114 Toluene-d8 (S) %. 80 81 82-109 SO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 107 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28799 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618294011, 2618294014, 2618294018, 2618294020, 2618294022, 2618294024, 2618294026, 2618294028, 2618294030, 2618294032, 2618294034, 2618294036, 2618294038, 2618294040, 2618294042 METHOD BLANK: 129715 Matrix: Water Associated Lab Samples: 2618294011, 2618294014, 2618294018, 2618294020, 2618294022, 2618294024, 2618294026, 2618294028, 2618294030, 2618294032, 2618294034, 2618294036, 2618294038, 2618294040, 2618294042 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/22/19 12:22 1,1,1-Trichloroethane ug/L ND 1.0 05/22/19 12:22 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/22/19 12:22 1,1,2-Trichloroethane ug/L ND 1.0 05/22/19 12:22 1,1-Dichloroethane ug/L ND 1.0 05/22/19 12:22 1,1-Dichloroethene ug/L ND 1.0 05/22/19 12:22 1,2,3-Trichloropropane ug/L ND 1.0 05/22/19 12:22 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/22/19 12:22 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/22/19 12:22 1,2-Dichlorobenzene ug/L ND 1.0 05/22/19 12:22 1,2-Dichloroethane ug/L ND 1.0 05/22/19 12:22 1,2-Dichloropropane ug/L ND 1.0 05/22/19 12:22 1,4-Dichlorobenzene ug/L ND 1.0 05/22/19 12:22 2-Butanone (MEK) ug/L ND 5.0 05/22/19 12:22 2-Hexanone ug/L ND 5.0 05/22/19 12:22 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/22/19 12:22 Acetone ug/L ND 25.0 05/22/19 12:22 Acrylonitrile ug/L ND 50.0 05/22/19 12:22 Benzene ug/L ND 1.0 05/22/19 12:22 Bromochloromethane ug/L ND 1.0 05/22/19 12:22 Bromodichloromethane ug/L ND 1.0 05/22/19 12:22 Bromoform ug/L ND 1.0 05/22/19 12:22 Bromomethane ug/L ND 2.0 05/22/19 12:22 Carbon disulfide ug/L ND 10.0 05/22/19 12:22 Carbon tetrachloride ug/L ND 1.0 05/22/19 12:22 Chlorobenzene ug/L ND 1.0 05/22/19 12:22 Chloroethane ug/L ND 1.0 05/22/19 12:22 Chloroform ug/L ND 1.0 05/22/19 12:22 Chloromethane ug/L ND 1.0 05/22/19 12:22 cis-1,2-Dichloroethene ug/L ND 1.0 05/22/19 12:22 cis-1,3-Dichloropropene ug/L ND 1.0 05/22/19 12:22 Dibromochloromethane ug/L ND 1.0 05/22/19 12:22 Dibromomethane ug/L ND 1.0 05/22/19 12:22 Ethylbenzene ug/L ND 1.0 05/22/19 12:22 lodomethane ug/L ND 10.0 05/22/19 12:22 Methylene Chloride ug/L ND 1.0 05/22/19 12:22 Styrene ug/L ND 1.0 05/22/19 12:22 Tetrachloroethene ug/L ND 1.0 05/22/19 12:22 Tetrahydrofuran ug/L ND 10.0 05/22/19 12:22 Toluene ug/L ND 1.0 05/22/19 12:22 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 108 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 METHOD BLANK: 129715 Matrix: Water Associated Lab Samples: 2618294011, 2618294014, 2618294018, 2618294020, 2618294022, 2618294024, 2618294026, 2618294028, 2618294030, 2618294032, 2618294034, 2618294036, 2618294038, 2618294040, 2618294042 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 05/22/19 12:22 trans- 1,3-Dichloropropene ug/L ND 1.0 05/22/19 12:22 Trichloroethene ug/L ND 1.0 05/22/19 12:22 Trichlorofluoromethane ug/L ND 1.0 05/22/19 12:22 Vinyl acetate ug/L ND 2.0 05/22/19 12:22 Vinyl chloride ug/L ND 1.0 05/22/19 12:22 Xylene (Total) ug/L ND 2.0 05/22/19 12:22 1,2-Dichloroethane-d4 (S) %. 101 81-119 05/22/19 12:22 4-Bromofluorobenzene (S) %. 108 82-120 05/22/19 12:22 Dibromofluoromethane (S) %. 97 82-114 05/22/19 12:22 Toluene-d8 (S) %. 105 82-109 05/22/19 12:22 LABORATORY CONTROL SAMPLE: Parameter 129716 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 65.0 130 68-137 1,1,1-Trichloroethane ug/L 50 64.2 128 72-134 1,1,2,2-Tetrachloroethane ug/L 50 48.2 96 51-158 1,1,2-Trichloroethane ug/L 50 60.5 121 78-131 1,1-Dichloroethane ug/L 50 63.3 127 69-151 1,1-Dichloroethene ug/L 50 58.6 117 64-158 1,2,3-Trichloropropane ug/L 50 46.9 94 78-133 1,2-Dibromo-3-chloropropane ug/L 50 49.0 98 58-124 1,2-Dibromoethane (EDB) ug/L 50 62.6 125 71-134 1,2-Dichlorobenzene ug/L 50 58.3 117 70-135 1,2-Dichloroethane ug/L 50 59.4 119 72-129 1,2-Dichloropropane ug/L 50 61.7 123 64-135 1,4-Dichlorobenzene ug/L 50 56.9 114 70-131 2-Butanone (MEK) ug/L 100 88.3 88 52-143 2-Hexanone ug/L 100 89.7 90 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 93.5 94 71-129 Acetone ug/L 100 108 108 48-224 Acrylonitrile ug/L 200 187 93 66-154 Benzene ug/L 50 61.5 123 68-132 Bromochloromethane ug/L 50 61.8 124 73-133 Bromodichloromethane ug/L 50 58.4 117 67-121 Bromoform ug/L 50 55.0 110 57-125 Bromomethane ug/L 50 40.7 81 35-156 Carbon disulfide ug/L 100 124 124 47-141 Carbon tetrachloride ug/L 50 59.7 119 66-122 Chlorobenzene ug/L 50 59.1 118 71-126 Chloroethane ug/L 50 44.4 89 43-143 Chloroform ug/L 50 58.1 116 71-136 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 109 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 LABORATORY CONTROL SAMPLE: 129716 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloromethane ug/L 50 53.2 106 47-123 cis-1,2-Dichloroethene ug/L 50 63.7 127 74-131 cis-1,3-Dichloropropene ug/L 50 57.2 114 78-120 Dibromochloromethane ug/L 50 56.7 113 65-115 Dibromomethane ug/L 50 63.1 126 79-129 Ethylbenzene ug/L 50 62.0 124 68-129 lodomethane ug/L 100 112 112 49-154 Methylene Chloride ug/L 50 52.5 105 61-147 Styrene ug/L 50 59.8 120 77-128 Tetrachloroethene ug/L 50 56.9 114 51-139 Tetrahydrofuran ug/L 100 99.4 99 56-147 Toluene ug/L 50 59.2 118 60-133 trans-1,2-Dichloroethene ug/L 50 61.1 122 69-144 trans- 1,3-Dichloropropene ug/L 50 57.2 114 74-128 Trichloroethene ug/L 50 54.3 109 73-126 Trichlorofluoromethane ug/L 50 46.3 93 55-132 Vinyl acetate ug/L 50 55.1 110 52-141 Vinyl chloride ug/L 50 48.6 97 50-133 Xylene (Total) ug/L 150 185 123 78-132 1,2-Dichloroethane-d4 (S) %. 98 81-119 4-Bromofluorobenzene (S) %. 109 82-120 Dibromofluoromethane (S) %. 104 82-114 Toluene-d8 (S) %. 105 82-109 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 129717 129718 MS MSD 2618294014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 37.6 65.3 75 131 68-137 54 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 43.3 77.6 87 155 66-142 57 11 M1,R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 27.3 52.5 55 105 39-171 63 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 36.6 63.5 73 127 73-136 54 12 R1 1,1-Dichloroethane ug/L 1.9 50 50 41.7 71.5 80 139 66-155 53 15 R1 1,1-Dichloroethene ug/L ND 50 50 45.3 77.0 91 154 33-181 52 34 R1 1,2,3-Trichloropropane ug/L ND 50 50 24.4 46.5 49 93 78-133 62 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 25.8 45.5 52 91 58-124 55 15 M1,R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 37.1 65.8 74 132 71-134 56 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 34.6 62.6 69 125 69-135 58 10 R1 1,2-Dichloroethane ug/L ND 50 50 37.9 63.9 76 128 36-159 51 10 R1 1,2-Dichloropropane ug/L ND 50 50 37.1 64.7 74 129 68-132 54 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 35.4 62.5 71 125 49-153 55 9 R1 2-Butanone (MEK) ug/L ND 100 100 50.5 89.1 50 89 10-189 55 23 R1 2-Hexanone ug/L ND 100 100 52.9 89.6 53 90 40-135 51 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 51.8 92.4 52 92 30-177 56 10 R1 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 110 of 182 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 129717 MS Parameter Acetone Acrylonitrile Benzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane Carbon disulfide Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane cis-1,2-Dichloroethene cis-1,3-Dichloropropene Dibromochloromethane Dibromomethane Ethylbenzene lodomethane Methylene Chloride Styrene Tetrachloroethene Tetrahydrofuran Toluene trans-1,2-Dichloroethene trans-1,3-Dichloropropene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Dibromofluoromethane (S) Toluene-d8 (S) Units ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2618294014 Spike Result Conc. ND 100 ND 200 ND 50 ND 50 ND 50 ND 50 ND 50 ND 100 ND 50 ND 50 ND 50 ND 50 ND 50 ND 50 ND 50 ND 50 ND 50 ND 50 ND 100 ND 50 ND 50 ND 50 1.4J 100 ND 50 ND 50 ND 50 0.38J 50 ND 50 ND 50 ND 50 ND 150 MSD Spike Conc. 100 200 50 50 50 50 50 100 50 50 50 50 50 50 50 50 50 50 100 50 50 50 100 50 50 50 50 50 50 50 150 129718 MS Result 63.5 118 38.4 38.7 35.1 31.4 31.4 94.9 43.8 35.9 32.6 35.5 38.0 41.9 32.7 34.4 38.3 36.7 73.7 37.5 36.3 38.0 58.9 38.5 43.6 32.7 34.0 41.1 38.6 35.9 112 MSD Result MS % Rec MSD % Rec % Rec Limits 97.3 59 93 44-223 200 59 100 13-189 66.3 77 133 66-139 68.3 77 137 73-133 63.0 70 126 57-120 55.2 63 110 48-128 51.8 63 104 10-187 157 95 157 47-141 79.2 88 158 58-127 63.3 71 126 63-137 53.8 65 108 52-146 62.0 71 124 74-137 59.0 76 118 41-127 69.5 83 138 71-138 56.1 65 112 32-145 60.3 69 121 52-116 65.0 77 130 79-129 66.3 73 133 31-174 133 74 133 49-154 60.1 74 119 61-146 65.2 73 130 77-128 63.7 75 127 36-155 106 57 104 56-147 65.8 77 132 52-146 69.6 87 139 61-152 56.1 65 112 37-146 60.1 67 119 61-141 71.6 82 143 51-141 72.5 77 145 52-141 58.1 72 116 22-156 200 75 133 78-132 103 100 81-119 98 112 82-120 104 105 82-114 105 97 82-109 Max RPD RPD Qual Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. 42 14 R1 52 12 R1 53 10 R1 55 13 M1,R1 57 13 M1,R1 55 13 R1 49 32 R1 49 322 M1 58 14 M1,R1 55 10 R1 49 16 R1 54 9 M1,R1 43 10 R1 50 16 R1 53 12 R1 55 13 M1,R1 52 14 M1,R1 57 10 R1 57 30 R1 46 15 R1 57 14 M1,R1 51 14 R1 57 12 R1 53 11 R1 46 14 R1 53 12 R1 56 12 R1 54 13 M1,R1 61 14 M1,R1 47 26 R1 56 7 RS Page 111 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 475932 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294001 METHOD BLANK: 2578793 Matrix: Water Associated Lab Samples: 2618294001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/17/19 12:34 1,2-Dichloroethane-d4 (S) % 97 50-150 05/17/19 12:34 Toluene-d8 (S) % 113 50-150 05/17/19 12:34 LABORATORY CONTROL SAMPLE: 2578794 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.6 98 70-130 1,2-Dichloroethane-d4 (S) % 98 50-150 Toluene-d8(S) % 115 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578795 2578796 MS MSD 92428710002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 57.0 20 20 69.9 77.7 65 104 50-150 11 30 1,2-Dichloroethane-d4 (S) % 106 103 50-150 30 Toluene-d8 (S) % 122 119 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 112 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 475936 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294002, 2618294003 METHOD BLANK: 2578807 Associated Lab Samples: 2618294002, 2618294003 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed ND 2.0 05/17/1912:15 100 50-150 05/17/1912:15 114 50-150 05/17/1912:15 Qualifiers LABORATORY CONTROL SAMPLE: 2578808 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578809 2578810 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.3 20.2 96 101 50-150 5 30 1,2-Dichloroethane-d4 (S) % 92 90 50-150 30 Toluene-d8 (S) % 82 81 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 113 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294012, 2618294043 METHOD BLANK: 2579453 Associated Lab Samples: 2618294012, 2618294043 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed ND 2.0 05/19/1910:45 102 50-150 05/19/1910:45 113 50-150 05/19/1910:45 Qualifiers LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 25.7 20.3 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 114 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 476078 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007 METHOD BLANK: 2579489 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/18/19 15:23 1,2-Dichloroethane-d4 (S) % 99 50-150 05/18/19 15:23 Toluene-d8 (S) % 106 50-150 05/18/19 15:23 LABORATORY CONTROL SAMPLE: 2579490 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 97 50-150 Toluene-d8(S) % 104 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579491 2579492 MS MSD 92428734005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 8.7 20 20 27.4 28.1 93 97 50-150 2 30 1,2-Dichloroethane-d4 (S) % 114 117 50-150 30 Toluene-d8 (S) % 116 115 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 115 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 476081 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294008, 2618294009, 2618294010, 2618294011, 2618294014, 2618294016, 2618294018, 2618294020, 2618294022, 2618294024, 2618294026, 2618294028, 2618294030, 2618294032, 2618294034, 2618294036, 2618294040 METHOD BLANK: 2579514 Matrix: Water Associated Lab Samples: 2618294008, 2618294009, 2618294010, 2618294011, 2618294014, 2618294016, 2618294018, 2618294020, 2618294022, 2618294024, 2618294026, 2618294028, 2618294030, 2618294032, 2618294034, 2618294036, 2618294040 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/20/19 11:14 1,2-Dichloroethane-d4 (S) % 91 50-150 05/20/19 11:14 Toluene-d8 (S) % 83 50-150 05/20/19 11:14 LABORATORY CONTROL SAMPLE: 2579515 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.0 100 70-130 1,2-Dichloroethane-d4 (S) % 96 50-150 Toluene-d8(S) % 86 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579516 2579517 MS MSD 2618294008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 9.8 20 20 27.4 32.0 88 111 50-150 16 30 1,2-Dichloroethane-d4 (S) % 104 104 50-150 30 Toluene-d8(S) % 101 102 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 116 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 476479 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618294038, 2618294042 METHOD BLANK: 2581075 Associated Lab Samples: 2618294038, 2618294042 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed ND 2.0 05/21/1911:11 100 50-150 05/21/1911:11 101 50-150 05/21/1911:11 Qualifiers LABORATORY CONTROL SAMPLE: 2581076 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.4 97 70-130 1,2-Dichloroethane-d4 (S) % 104 50-150 Toluene-d8(S) % 102 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2581077 2581078 MS MSD 92429154005 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 380 100 100 459 475 79 95 50-150 3 30 1,2-Dichloroethane-d4 (S) % 104 105 50-150 30 Toluene-d8 (S) % 102 101 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 117 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28193 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV Associated Lab Samples: 2618294001, 2618294008 METHOD BLANK: 127042 Associated Lab Samples: 2618294001, 2618294008 Parameter Units bis(2-Ethylhexyl)phthalate ug/L 2,4,6-Tribromophenol (S) %. 2-Fluorobiphenyl (S) %. 2-Fluorophenol (S) %. Nitrobenzene-d5 (S) %. p-Terphenyl-d14 (S) %. Phenol-d6 (S) %. LABORATORY CONTROL SAMPLE: 127043 Parameter Units bis(2-Ethylhexyl)phthalate ug/L 2,4,6-Tribromophenol (S) %. 2-Fluorobiphenyl (S) %. 2-Fluorophenol (S) %. Nitrobenzene-d5 (S) %. p-Terphenyl-d14 (S) %. Phenol-d6 (S) %. Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 15.0 05/10/19 23:48 67 10-148 05/10/19 23:48 66 12-129 05/10/19 23:48 34 10-64 05/10/19 23:48 64 13-107 05/10/19 23:48 94 14-147 05/10/19 23:48 20 10-46 05/10/19 23:48 Spike LCS LCS Conc. Result % Rec % Rec Limits Qualifiers 80 65.4 82 40-156 79 10-148 69 12-129 33 10-64 64 13-107 94 14-147 20 10-46 MATRIX SPIKE SAMPLE: Parameter 127078 Units 2618294001 Spike MS MS Result Conc. Result % Rec % Rec Limits Qualifiers bis(2-Ethylhexyl)phthalate ug/L ND 80 62.7 75 40-156 2,4,6-Tribromophenol (S) %. 72 10-148 2-Fluorobiphenyl (S) %. 55 12-129 2-Fluorophenol (S) %. 26 10-64 Nitrobenzene-d5 (S) %. 49 13-107 p-Terphenyl-d14 (S) %. 76 14-147 Phenol-d6 (S) %. 16 10-46 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 118 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28409 Analysis Method: EPA 8270E QC Batch Method: EPA 3510C Analysis Description: 8270E Water MSSV Associated Lab Samples: 2618294018, 2618294026, 2618294030 METHOD BLANK: 127909 Matrix: Water Associated Lab Samples: 2618294018, 2618294026, 2618294030 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers bis(2-Ethylhexyl)phthalate ug/L ND 15.0 05/15/19 18:13 2,4,6-Tribromophenol (S) %. 64 10-148 05/15/19 18:13 2-Fluorobiphenyl (S) %. 68 12-129 05/15/19 18:13 2-Fluorophenol (S) %. 18 10-64 05/15/19 18:13 Nitrobenzene-d5 (S) %. 41 13-107 05/15/19 18:13 p-Terphenyl-d14 (S) %. 98 14-147 05/15/19 18:13 Phenol-d6 (S) %. 13 10-46 05/15/19 18:13 LABORATORY CONTROL SAMPLE: Parameter 127910 Units Spike LCS LCS Conc. Result % Rec % Rec Limits Qualifiers bis(2-Ethylhexyl)phthalate ug/L 80 64.1 80 40-156 2,4,6-Tribromophenol (S) %. 96 10-148 2-Fluorobiphenyl (S) %. 78 12-129 2-Fluorophenol (S) %. 19 10-64 Nitrobenzene-d5 (S) %. 52 13-107 p-Terphenyl-d14 (S) %. 77 14-147 Phenol-d6 (S) %. 13 10-46 MATRIX SPIKE SAMPLE: Parameter 127942 Units 2618294030 Spike MS MS Result Conc. Result % Rec % Rec Limits Qualifiers bis(2-Ethylhexyl)phthalate ug/L ND 80 67.3 84 40-156 2,4,6-Tribromophenol (S) %. 98 10-148 2-Fluorobiphenyl (S) %. 70 12-129 2-Fluorophenol (S) %. 23 10-64 Nitrobenzene-d5 (S) %. 52 13-107 p-Terphenyl-d14 (S) %. 77 14-147 Phenol-d6 (S) %. 19 10-46 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 119 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28076 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618294001, 2618294002, 2618294003 METHOD BLANK: 126363 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/09/19 13:54 LABORATORY CONTROL SAMPLE: 126364 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 101000 101 85-115 SAMPLE DUPLICATE: 126365 2618202009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 123 mg/L 124000 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 120 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28286 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 METHOD BLANK: 127414 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/13/19 16:23 LABORATORY CONTROL SAMPLE: 127415 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 105000 105 85-115 SAMPLE DUPLICATE: 127416 2618406001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 77.0 mg/L 77000 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 121 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28241 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 METHOD BLANK: 127275 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 05/13/19 15:54 LABORATORY CONTROL SAMPLE: 127276 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 203000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127277 127278 MS MSD 2618291001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 9160 mg/L 5000000 5000000 1460000 1390000 109 96 90-110 5 10 0 0 MATRIX SPIKE SAMPLE: 127279 2618315007 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 7840 mg/L 5000000 12800000 99 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 122 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28861 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2618294011 METHOD BLANK: 130085 Matrix: Water Associated Lab Samples: 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 05/22/19 15:33 LABORATORY CONTROL SAMPLE: 130086 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 191000 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130087 130088 MS MSD 2618294011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L ND 200000 200000 191000 209000 96 105 90-110 9 10 MATRIX SPIKE SAMPLE: 130089 2618739010 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L ND 200000 193000 97 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 123 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28184 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2618294001, 2618294002, 2618294003 METHOD BLANK: 126976 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide ug/L ND 200 05/10/1914:19 LABORATORY CONTROL SAMPLE: 126977 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 452 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126978 126979 MS MSD 2618407004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 ND ND 39 38 30-129 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 124 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28185 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 METHOD BLANK: 126980 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide ug/L ND 200 05/10/1915:20 LABORATORY CONTROL SAMPLE: 126981 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 451 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126982 126983 MS MSD 2618340006 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 428 424 86 85 30-129 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 125 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28001 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618294001, 2618294002, 2618294003 METHOD BLANK: 125904 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/13/19 12:52 3A LABORATORY CONTROL SAMPLE: 125906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 205000 104 85-115 3A SAMPLE DUPLICATE: 125957 2618270001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1110 mg/L 1270000 13 20 3A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 126 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28070 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618294008 METHOD BLANK: 126351 Matrix: Water Associated Lab Samples: 2618294008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/14/19 11:21 3A LABORATORY CONTROL SAMPLE: 126353 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 190000 96 85-115 3A SAMPLE DUPLICATE: 126354 2618336001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1560 mg/L 1570000 0 20 3A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 127 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28156 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294009 METHOD BLANK: 126833 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/15/19 09:16 2A LABORATORY CONTROL SAMPLE: 126835 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 167000 84 85-115 2A, L2 SAMPLE DUPLICATE: 126851 2618379001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 93.0 mg/L 91500 2 20 2A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 128 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28197 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618294011 METHOD BLANK: 127074 Matrix: Water Associated Lab Samples: 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/15/19 09:41 2A LABORATORY CONTROL SAMPLE: 127076 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 154000 78 85-115 2A, L2 SAMPLE DUPLICATE: 127077 2618386003 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 272 mg/L 269000 1 20 2A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 129 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28053 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618294001, 2618294002, 2618294003 METHOD BLANK: 126307 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L ND 50.0 05/09/19 14:29 LABORATORY CONTROL SAMPLE: 126308 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9630 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126309 126310 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 359 10000 10000 9640 9600 93 92 90-110 0 15 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 130 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28134 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 METHOD BLANK: 126690 Matrix: Water Associated Lab Samples: 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L 20.OJ 50.0 05/10/19 00:39 LABORATORY CONTROL SAMPLE: 126691 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 10400 104 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126692 126693 MS MSD 2618294008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 21.OJ 10000 10000 10700 10600 107 106 90-110 0 15 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 131 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28212 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618294011 METHOD BLANK: 127151 Matrix: Water Associated Lab Samples: 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L 22.OJ 50.0 05/11/19 08:05 LABORATORY CONTROL SAMPLE: 127152 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 10300 103 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127153 127154 MS MSD 2618294011 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 23.OJ 10000 10000 10400 10500 104 104 90-110 0 15 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 132 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28159 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 METHOD BLANK: 126846 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 53.OJ 1000 05/10/1916:10 Sulfate ug/L 26.OJ 5000 05/10/1916:10 LABORATORY CONTROL SAMPLE: 126847 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10600 106 90-110 Sulfate ug/L 10000 10100 101 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 133 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28932 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618294011 METHOD BLANK: 130388 Matrix: Water Associated Lab Samples: 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 81.OJ 1000 05/23/19 03:39 Sulfate ug/L 23.OJ 5000 05/23/19 03:39 LABORATORY CONTROL SAMPLE: 130389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10500 105 90-110 Sulfate ug/L 10000 11000 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130390 130391 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2930 10000 10000 13300 13200 104 103 90-110 1 15 Sulfate ug/L 12600 10000 10000 22300 22300 97 98 90-110 0 15 MATRIX SPIKE SAMPLE: 130392 2618688001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L ND 5000000 5160000 101 90-110 Sulfate ug/L ND 5000000 5420000 107 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 134 of 182 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 QC Batch: 28426 Analysis Method: EPA 9060A QC Batch Method: EPA 9060A Analysis Description: 9060A Total Organic Carbon Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 METHOD BLANK: 127954 Matrix: Water Associated Lab Samples: 2618294001, 2618294002, 2618294003, 2618294004, 2618294005, 2618294006, 2618294008, 2618294009, 2618294011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 LABORATORY CONTROL SAMPLE: 127955 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19100 96 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 18900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127956 127957 MS MSD 2618406001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20000 19800 84 83 85-115 1 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19900 19600 84 82 85-115 2 10 M1 Total Organic Carbon ug/L 3.3 mg/L 20000 20000 20300 19800 85 82 85-115 3 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20100 20100 84 85 85-115 0 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19500 19800 81 83 85-115 2 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127958 127959 MS MSD 2618294001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 1040 20000 20000 19000 18900 90 89 85-115 1 10 Total Organic Carbon ug/L 1040 20000 20000 19000 19000 90 90 85-115 0 10 Total Organic Carbon ug/L 1020 20000 20000 18200 18800 86 89 85-115 3 10 Total Organic Carbon ug/L 1030 20000 20000 19400 19100 92 90 85-115 2 10 Total Organic Carbon ug/L 1060 20000 20000 19300 18600 91 88 85-115 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 135 of 182 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW'pacalabsxom (770)734-4200 QUALIFIERS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA BATCH QUALIFIERS Batch: 28232 The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. Batch: 28325 The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. Batch: 28363 Ill The seed correction factor was below the desired range of 0.60-1.0 mg/L. Batch: 28364 Ill The seed correction factor was below the desired range of 0.60-1.0 mg/L. ANALYTE QUALIFIERS 1A Sample showed evidence of toxcity 2A The seed correction factor was below the desired range of 0.60-1.0 mg/L. 3A The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. B Analyte was detected in the associated method blank. H1 Analysis conducted outside the EPA method holding time. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 136 of 182 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW'pacalabsxom (770)734-4200 QUALIFIERS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 ANALYTE QUALIFIERS L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated samples may be biased low. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. R6 The RPD between valid sample dilutions exceeded 30%. RS The RPD value in one of the constituent analytes was outside the control limits. SO Surrogate recovery outside laboratory control limits. S3 Surrogate recovery exceeded laboratory control limits. Analyte presence below reporting limits in associated sample. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 137 of 182 aceAnaVical "m..pacetabS.cnm Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County Units 2/3 MSW 2618294 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618294001 1302-AMW-2D 28595 2618294002 1302-AMW-2S 28595 2618294003 1302-MW-E 28595 2618294004 1302-AMW-1d 28595 2618294005 1302-AMW-1s 28595 2618294006 1302-MW-3 28595 2618294007 1302-MW-3 deep 28595 2618294008 1302-MW-E deep 28595 2618294009 1302-MW-L 28595 2618294010 1302-MW-L deep 28595 2618294011 1302-MW-A 28595 2618294012 1302-C D-4 Rep 28595 2618294013 1302-C D-4 Rep 28595 2618294014 1302-MW-1 28595 2618294015 1302-MW-1 28595 2618294016 1302-MW-B 28595 2618294017 1302-MW-B 28595 2618294018 1302-MW-C 28595 2618294019 1302-MW-C 28595 2618294020 1302-MW-D 28595 2618294021 1302-MW-D 28595 2618294022 1302-MW-F 28595 2618294023 1302-MW-F 28595 2618294024 1302-MW-G 28595 2618294025 1302-MW-G 28595 2618294026 1302-MW-H 28595 2618294027 1302-MW-H 28595 2618294028 1302-MW-H DEEP 28595 2618294029 1302-MW-H DEEP 28595 2618294030 1302-MW-1 28595 2618294031 1302-MW-1 28595 2618294032 1302-MW-J 28595 2618294033 1302-MW-J 28595 2618294034 1302-MW-K 28595 2618294035 1302-MW-K 28595 2618294036 1302-MW-M 28595 2618294037 1302-MW-M 28595 2618294038 1302-MW-X 28595 2618294039 1302-MW-X 28595 2618294001 1302-AMW-2D EPA 3005A 28295 EPA 6020B 28307 2618294002 1302-AMW-2S EPA 3005A 28295 EPA 6020B 28307 2618294003 1302-MW-E EPA 3005A 28295 EPA 6020B 28307 2618294004 1302-AMW-1d EPA 3005A 28444 EPA 6020B 28470 2618294005 1302-AMW-1s EPA 3005A 28444 EPA 6020B 28470 2618294006 1302-MW-3 EPA 3005A 28444 EPA 6020B 28470 2618294007 1302-MW-3 deep EPA 3005A 28444 EPA 6020B 28470 2618294008 1302-MW-E deep EPA 3005A 28444 EPA 6020B 28470 2618294009 1302-MW-L EPA 3005A 28444 EPA 6020B 28470 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 138 of 182 11!;a'ceAna1j&a1" WNW'pecalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618294010 1302-MW-L deep EPA 3005A 28444 EPA 6020B 28470 2618294011 1302-MW-A EPA 3005A 28444 EPA 6020B 28470 2618294013 1302-CD-4 Rep EPA 3005A 28518 EPA 6020B 28525 2618294015 1302-MW-1 EPA 3005A 28518 EPA 6020B 28525 2618294017 1302-MW-B EPA 3005A 28518 EPA 6020B 28525 2618294019 1302-MW-C EPA 3005A 28518 EPA 6020B 28525 2618294021 1302-MW-D EPA 3005A 28518 EPA 6020B 28525 2618294023 1302-MW-F EPA 3005A 28518 EPA 6020B 28525 2618294025 1302-MW-G EPA 3005A 28521 EPA 6020B 28523 2618294027 1302-MW-H EPA 3005A 28521 EPA 6020B 28523 2618294029 1302-MW-H DEEP EPA 3005A 28521 EPA 6020B 28523 2618294031 1302-MW-1 EPA 3005A 28521 EPA 6020B 28523 2618294033 1302-MW-J EPA 3005A 28521 EPA 6020B 28523 2618294035 1302-MW-K EPA 3005A 28521 EPA 6020B 28523 2618294037 1302-MW-M EPA 3005A 28521 EPA 6020B 28523 2618294039 1302-MW-X EPA 3005A 28521 EPA 6020B 28523 2618294041 1302-DUPLICATE EPA 3005A 28521 EPA 6020B 28523 2618294042 1302-Equipment Blank EPA 3005A 28521 EPA 6020B 28523 2618294004 1302-AMW-1 d EPA 7470A 28114 EPA 7470A 28138 2618294005 1302-AMW-1 s EPA 7470A 28114 EPA 7470A 28138 2618294006 1302-MW-3 EPA 7470A 28114 EPA 7470A 28138 2618294007 1302-MW-3 deep EPA 7470A 28114 EPA 7470A 28138 2618294008 1302-MW-E deep EPA 7470A 28114 EPA 7470A 28138 2618294009 1302-MW-L EPA 7470A 28368 EPA 7470A 28423 2618294010 1302-MW-L deep EPA 7470A 28368 EPA 7470A 28423 2618294011 1302-MW-A EPA 7470A 28368 EPA 7470A 28423 2618294001 1302-AMW-2D EPA 3510C 28193 EPA 8270E 28216 2618294008 1302-MW-E deep EPA 3510C 28193 EPA 8270E 28216 2618294018 1302-MW-C EPA 3510C 28409 EPA 8270E 28472 2618294026 1302-MW-H EPA 3510C 28409 EPA 8270E 28472 2618294030 1302-MW-1 EPA 3510C 28409 EPA 8270E 28472 2618294001 1302-AMW-2D EPA 8260D 28431 2618294002 1302-AMW-2S EPA 8260D 28431 2618294003 1302-MW-E EPA 8260D 28431 2618294004 1302-AMW-1 d EPA 8260D 28431 2618294005 1302-AMW-1 s EPA 8260D 28431 2618294006 1302-MW-3 EPA 8260D 28431 2618294007 1302-MW-3 deep EPA 8260D 28431 2618294008 1302-MW-E deep EPA 8260D 28582 2618294009 1302-MW-L EPA 8260D 28582 2618294010 1302-MW-L deep EPA 8260D 28582 2618294011 1302-MW-A EPA 8260D 28799 2618294012 1302-CD-4 Rep EPA 8260D 28582 Date: 05/31 /2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 139 of 182 aceAnaVical "m..pacetabS.cnm Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID QC Batch Method QC Batch 2618294014 1302-MW-1 EPA 8260D 28799 2618294016 1302-MW-B EPA 8260D 28582 2618294018 1302-MW-C EPA 8260D 28799 2618294020 1302-MW-D EPA 8260D 28799 2618294022 1302-MW-F EPA 8260D 28799 2618294024 1302-MW-G EPA 8260D 28799 2618294026 1302-MW-H EPA 8260D 28799 2618294028 1302-MW-H DEEP EPA 8260D 28799 2618294030 1302-MW-1 EPA 8260D 28799 2618294032 1302-MW-J EPA 8260D 28799 2618294034 1302-MW-K EPA 8260D 28799 2618294036 1302-MW-M EPA 8260D 28799 2618294038 1302-MW-X EPA 8260D 28799 2618294040 1302-DUPLICATE EPA 8260D 28799 2618294042 1302-Equipment Blank EPA 8260D 28799 2618294043 1302-Trip Blank EPA 8260D 28582 2618294001 1302-AMW-2D EPA 8260D Mod. 475932 2618294002 1302-AMW-2S EPA 8260D Mod. 475936 2618294003 1302-MW-E EPA 8260D Mod. 475936 2618294004 1302-AMW-1d EPA 8260D Mod. 476078 2618294005 1302-AMW-1s EPA 8260D Mod. 476078 2618294006 1302-MW-3 EPA 8260D Mod. 476078 2618294007 1302-MW-3 deep EPA 8260D Mod. 476078 2618294008 1302-MW-E deep EPA 8260D Mod. 476081 2618294009 1302-MW-L EPA 8260D Mod. 476081 2618294010 1302-MW-L deep EPA 8260D Mod. 476081 2618294011 1302-MW-A EPA 8260D Mod. 476081 2618294012 1302-CD-4 Rep EPA 8260D Mod. 476071 2618294014 1302-MW-1 EPA 8260D Mod. 476081 2618294016 1302-MW-B EPA 8260D Mod. 476081 2618294018 1302-MW-C EPA 8260D Mod. 476081 2618294020 1302-MW-D EPA 8260D Mod. 476081 2618294022 1302-MW-F EPA 8260D Mod. 476081 2618294024 1302-MW-G EPA 8260D Mod. 476081 2618294026 1302-MW-H EPA 8260D Mod. 476081 2618294028 1302-MW-H DEEP EPA 8260D Mod. 476081 2618294030 1302-MW-1 EPA 8260D Mod. 476081 2618294032 1302-MW-J EPA 8260D Mod. 476081 2618294034 1302-MW-K EPA 8260D Mod. 476081 2618294036 1302-MW-M EPA 8260D Mod. 476081 2618294038 1302-MW-X EPA 8260D Mod. 476479 2618294040 1302-DUPLICATE EPA 8260D Mod. 476081 2618294042 1302-Equipment Blank EPA 8260D Mod. 476479 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Analytical Analytical Method Batch Page 140 of 182 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618294043 1302-Trip Blank EPA 8260D Mod. 476071 2618294001 1302-AMW-2D SM 2320E 28076 2618294002 1302-AMW-2S SM 2320E 28076 2618294003 1302-MW-E SM 2320B 28076 2618294004 1302-AMW-1d SM 2320E 28286 2618294005 1302-AMW-1s SM 2320E 28286 2618294006 1302-MW-3 SM 2320B 28286 2618294008 1302-MW-E deep SM 2320B 28286 2618294009 1302-MW-L SM 2320B 28286 2618294011 1302-MW-A SM 2320B 28286 2618294001 1302-AMW-2D EPA 410.4 28241 2618294002 1302-AMW-2S EPA 410.4 28241 2618294003 1302-MW-E EPA 410.4 28241 2618294004 1302-AMW-1 d EPA 410.4 28241 2618294005 1302-AMW-1 s EPA 410.4 28241 2618294006 1302-MW-3 EPA 410.4 28241 2618294008 1302-MW-E deep EPA 410.4 28241 2618294009 1302-MW-L EPA 410.4 28241 2618294011 1302-MW-A EPA 410.4 28861 2618294001 1302-AMW-2D SM 4500-S2 D 28184 2618294002 1302-AMW-2S SM 4500-S2 D 28184 2618294003 1302-MW-E SM 4500-S2 D 28184 2618294004 1302-AMW-1d SM 4500-S2 D 28185 2618294005 1302-AMW-1s SM 4500-S2 D 28185 2618294006 1302-MW-3 SM 4500-S2 D 28185 2618294008 1302-MW-E deep SM 4500-S2 D 28185 2618294009 1302-MW-L SM 4500-S2 D 28185 2618294011 1302-MW-A SM 4500-S2 D 28185 2618294001 1302-AMW-2D SM 5210E 28001 2618294002 1302-AMW-2S SM 5210E 28001 2618294003 1302-MW-E SM 5210B 28001 2618294004 1302-AMW-1d SM 5210E 28156 2618294005 1302-AMW-1s SM 5210E 28156 2618294006 1302-MW-3 SM 5210B 28156 2618294008 1302-MW-E deep SM 5210B 28070 2618294009 1302-MW-L SM 5210B 28156 2618294011 1302-MW-A SM 5210B 28197 2618294001 1302-AMW-2D EPA 9056A 28053 2618294002 1302-AMW-2S EPA 9056A 28053 2618294003 1302-MW-E EPA 9056A 28053 2618294004 1302-AMW-1 d EPA 9056A 28134 2618294005 1302-AMW-1 s EPA 9056A 28134 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 EPA 410.4 SM 5210B SM 5210B SM 5210B SM 5210B SM 5210B SM 5210B SM 5210B SM 5210B SM 5210B 28268 28268 28268 28268 28268 28268 28268 28268 28876 28232 28232 28232 28363 28363 28363 28325 28363 28364 Page 141 of 182 aceAnaVical "m..pacetabS.cnm Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Lab ID Sample ID QC Batch Method QC Batch 2618294006 1302-MW-3 EPA 9056A 28134 2618294008 1302-MW-E deep EPA 9056A 28134 2618294009 1302-MW-L EPA 9056A 28134 2618294011 1302-MW-A EPA 9056A 28212 2618294001 1302-AMW-2D EPA 9056A 28159 2618294002 1302-AMW-2S EPA 9056A 28159 2618294003 1302-MW-E EPA 9056A 28159 2618294004 1302-AMW-1 d EPA 9056A 28159 2618294005 1302-AMW-1 s EPA 9056A 28159 2618294006 1302-MW-3 EPA 9056A 28159 2618294008 1302-MW-E deep EPA 9056A 28159 2618294009 1302-MW-L EPA 9056A 28159 2618294011 1302-MW-A EPA 9056A 28932 2618294001 1302-AMW-2D EPA 9060A 28426 2618294002 1302-AMW-2S EPA 9060A 28426 2618294003 1302-MW-E EPA 9060A 28426 2618294004 1302-AMW-1 d EPA 9060A 28426 2618294005 1302-AMW-1 s EPA 9060A 28426 2618294006 1302-MW-3 EPA 9060A 28426 2618294008 1302-MW-E deep EPA 9060A 28426 2618294009 1302-MW-L EPA 9060A 28426 2618294011 1302-MW-A EPA 9060A 28426 Date: 05/31/2019 05:08 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Analytical Method Analytical Batch Page 142 of 182 a c m a -4 a► ul A W a .. ITEM # mmm C; Doan, n 3 ID m - r m o N N 0 0 0 �' 0 0 0 N N N N N N 3 N tooN <) N 3 ;N o� j M 3 D m mA q u n 9 a .. m cZi 3 o _ 0' a tQD 0 ((DD Fr T n ? = C 3 3 g 0 m m - C x — N ° — N m r m m o m m S) 'p - 0 J! y O m m O O m 3 m m m 3 m 0 a v o y VKT VYT VYT VYT VYT VYT VYT WT WT WT I WT WT MATRIX CODE (see valid codes to left) 0 0 0 0 0 6) 6) 6) 6) SAMPLE TYPE (G=GRAB C=COMP) c d 3 Cr m ° o o ^' �^ CD m 22 o m (T� _ !1 '� G D C > 3 n O Z r m ••Fl vG Q(t 6^ In D D m n m d m O m -4% ym In m 9 SAMPLE TEMP AT COLLECTION OQ M OF CONTAINERS -0 m M- m m D a 0 D o y m m -0 m v m p n mq 3 ID 3. St d o m o 7 W Unpreserved H2SO4 O O (3 c ° D N > > � �+ n m o r HNO3 m 3 HCI oA ° m 00 14a0 Zh�C- N m Na2S203 y r m Methanol t Other y t S s Analyses Test YM > )( x x X App. I VOC by 8260 + THE � M n 8270 SVOC (Bis-2-eh)phthalate 7C BOD 5-day, Alk, Cl, NO3, SO4 �c x x COD ' r SL �i Sulfide by SM4500-S2-D �( Alk, Cl. SO4, TDS o m iL K X Dissolved Gases (CO2, M, E, E) jr Dissolved Gases (VFA) / TOC Dissolved Gases (Hydrogen) 1 m X 7C 7� App. I Metals + Fe, Mn, Hg pWCON/Temp/TudvDO/ORP ,ly a)m X )C pWCON/Temp/Turb/DO/ORP/Fe � Residual Chlorine (YM) v Z o r 0 e o1 _ 1 1-4 -��7- j— P --I o m = 0a Z o 5 c Q N a N VI SD m Gv O \ C � ty m 5 z --I F. D � < co (gyp CL (p W rF �v O Cr n n r 03 3 co � a n n c d m ge 143 of 182 . FaceAnalytical Sample Condition Upon Rim PM: SMM . Due Date: 05/24/19 _ CLIENT: CDM-Raleigh Courier: e Ex ❑ UPS ❑ USP ❑ Client ❑ Commercial ❑ Pace Tracking #: 6 Custody Seal on Cooler/Box Present: no Seals intact: yes ❑ no Packing Material: ❑ Bubble Wrap ubble Bags ❑ None ❑ Other Thermometer Used D Type of Ice: �We�% Blue None vroi. uue uate: Proj. Name: F-7 Samples on ice. cooling process has begun f Cooler Temperature Temp should be above freezing to 6 C Biological Tissue is Frozen: Yes No Comments: Date and Initial, of 5ers amining contents: Chain of Custody Present: ❑N/A 1. Chain of Custody Filled Out: _Y�sONo LrYes ONO ❑NiA 2. Chain of Custody Relinquished: I>>re sNo ❑N/A 3. Sampler Name & Signature on COC: es ❑No ❑N!A 4. Samples Arrived within Hold Time: es ONO ❑NIA 5. Short Hold Time Analysis (<72hr): i Y6s__0Noo ON/A 6. Rush Turn Around Time Requested: ❑Yes EK ❑N/A 7. Sufficient Volume: 0YOT—❑No ❑N/A 8. Correct Containers Used: -Pace Containers Used: es ❑No j,1^zzs '❑No ❑N/A ❑N/A g. Containers Intact: s ❑No ❑NIA Filtered volume received for Dissolved tests ❑Yes ONO !A 11. Sample Labels match COC: -Includes date/time/ID/Analysis Matrix: 0res ONO ❑N/A 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance with EPA recommendation. ,ram+ . exceptions: vOA, iformO , O&G. WI-DRO (water) ,� E> s ONO 0 e�❑No � ONO E3NiA ❑N/A 13. Initial when completed Lot # of added preservative Samples checked for dechlorination: ❑Yes ONO 14. Headspace in VOA Vials ( >6mm): ❑Yes o S v Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): ❑Yes ONO ❑Yes ONO A A 16. Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y 1 N Date: Note Whenever there is a discrepancy affecting North Carolina compliance samples. a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Page 144 of 182 F-ALLC003rev.3 11 September2006 M 3 a o �p p G to Co V 0 c" A ca 111 �+ ITEM # 0 L. a C m mm ym d O 1n � a 7 N p N N p N p N N W s W s W s rp r G O 0 p •• a M a n 3 3 ���so3 3 o o 0 3 a = 3 ca t4i� 3 czi N � 0 m co s T w r 3 s ro M 0 Rr 2i� g a x v X s �SPFoa�FaF9i m F m m 0 1i a O m m y� m 0 m 0' m c C N v v .0 3 C 0 # m 7 O O m m 3 sa�nrr m O WT WT WT WT WT WT WT jwr WT WT WT WT MATRIX CODE (see valid codes to left) m 2 a 3 m m F 3, G) G) G) G) G) G) G) I G) G) G) G) G) SAMPLE TYPE (G=GRAB C COMP) m`•� m 0 o `�'rl ` Y� Q W K, e.c . eO y � m o � m m o m 9-' O n 3 m 0 r ,r D Z r n n =_ m' m �= 3 m z � 0 i m SAMPLE TEMP AT COLLECTION o a Xt q OF CONTAINERS m m m a 0 m 0 m mo n 3 m 0 3 Unpreserved m m O y o$ H2SO4 HNO3 m a m 2 m o !" �? n m o m T r i HCI o o d N NaOH z`T Na2S2 3 M m Methanol Other Analyses Test YM x• Tt 71 >-, - \ x App. I VOC by 8260 + THFt ( L(9'wwg z ?c f ]( �C 8270 SVOC (13is-2-eh)phthalate a X- k X BOD 5-day, Alk, Cl. NO3. SO4 e X X X X COD K X X x Sulfide by SM4500-S2-D Alk, CI, SO4, TDS o Dissolved Gases (CO2. M. E. E) a %i X X Dissolved Gases (VFA) / TOC Dissolved Gases (Hydrogen) m�• K X X App. I Metals + Fe, Mn, Hg pH/CON/Temp/Turb/DO/ORP m 0 7" K I IX x pH/CON/Temp/furb/DOlORPlFe y N Residual Chlorine (Y/N) z e o 3 � p < M fD (p a y W r„F cv a m n n i 0 3 3 v � m 3 m "* a d cc d m )e 145 of 182 FaceAnalytical WO#:2618294 Client Name: Vjn PM: SMM Due Date: 05/24/19 CLIENT• CDR -Raleigh Courier: R<ed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial ❑ Pace Other Tracking #: I'roj. uue uaie: - — Proj. Name: Custody Seal on Cooler/Box Present: yes ❑ no Seals intact: ff yes n no Packing Material: ❑ Bubble rap ubble Bags ❑ None `` Other Thermometer Used %)91— Type of Ice: (WP'Blue None Samples on ice, coolinq process has bequn Cooler Temperature 'S L Biological Tissue is Frozen: Yes No Date and Initial of p e� amining contents: Temp should be above freezing to 6`C Comments: Chain of Custody Present: Oles ONO ❑NIA 1. Chain of Custody Filled Out: 15Yes ❑No ❑NIA 2. Chain of Custody Relinquished: ETYZs ❑No ❑NIA 3. Sampler Name & Signature on COC: es No ❑NIA 4. Samples Arrived within Hold Time: es ❑No ❑NIA 5. Short Hold Time Analysis (<72hr): e�❑No ❑N/A 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: RK-sl❑No ❑NIA 8. Correct Containers Used: es ❑No ❑NIA g. -Pace Containers Used: es ❑No ❑NIA Containers Intact: es ❑No ❑NIA 1 . Filtered volume received for Dissolved tests ❑Yes ❑No A 11. Sample Labels match COC: esCoj ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. es ❑No ❑NIA 13. All containers needing preservation are found to be in es ❑No ❑NIA compliance with EPA recommendation. Initial when Lot # of added exceptions: J��A2 colifo ,TO , O&G, WI-DRO (water) Yes []No completed preservative Samples checked for dechlorination: ❑Yes ❑Noo l WA 14. Headspace in VOA Vials ( >6mm): ❑Yes gK0 ❑N1A 15. Trip Blank Present: ❑Yes QTo�C]NIA 16. Trip Blank Custody Seals Present ❑Yes ❑No /A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Date/Ti me: Field Data Required? Y / N Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) Page 146 of 182 F-ALLC003rev.3, 11September2006 D m m Q O m a o m a -4 0 N A W a � ITEM # .; m 3 e 2 w w r N 'G 6 ' N n D w w w w w w 0 0 0 0 0 0 0 0 w 0 � o o w O 3 w 5, N 0 p 5 C w 3 L7 to 3 C, D '° N 0 a ff 3O m. 3 N m c- s d x v m �m w w m f 91 o Op O O '0 D f ONaf f Oo N y D V r r y O y m O w N O O 6 3 a 3 0 V WT WT WT WT WT WT wr WT WT WT WT WT MATRIX CODE (see valid codes to left) m m C) G) G) G) G) G) G) G) G) G) G) G) L7 SAMPLE TYPE (G-GRAB C=COMP) d O o l31 v 3 m J 2 w O t m o w v 0 g 0 oC 3 m r r 0 m p z D m m n ' m' m v � m Z v CA c 3 N m m SAMPLE TEMP AT COLLECTION m 0 m 0 m o a a o X' w 4 OF CONTAINERS G m v a v O yd 3 St S$ 0 ` Unpreserved H2SO4 o 0 HNO3 d mz N i HCI m o m 00 N Na0 obi s � Na2S203 y Methanol c Other J- Analyses Test YM App. I VOC by 8260 + TH = 8270 SVOC (Bis-2-eh)phthalate �C BOD 5-day, Alk, Cl. NO3, SO4 it COD X Sulfide by SM4500-S2-D L Alk, Cl, SO4, TDS CS o 7C Dissolved Gases (CO2, M. E. E) � 31 7�. Dissolved Gases (VFA) / TOC a Dissolved Gases (Hydrogen) z mx App. I Metals + Fe, Mn, Hg pH/CON/Tem p1Turb1DO/0RP �p obi ;0. pH/CONITemplTurb/DO/ORP/Fe d) Residual Chlorine (Y/N) Z c o v �n p 2 n 2 ZO N Pjj -1n m n = �a � Z O� H O 00 C ,CA to N 07 r 0 IT! �v r O \ C 3 9 0) Z D F. = O1 < CD (D (p a y rn rt �v a O 0 o i 0 3 3 N 3 m ^� a 0 R c m e 147 of 182 Sample' ' ' Upon WO# : 2618294 �aceAnalytica/ Client Name: PM: SMM Due Date: 05/24/19 CLIENT: CON -Raleigh Courier: El Fed Ex ❑lUPS ] USPS ❑ Client ❑ Commercial �] Pace Oth, Tracking #: 7 7 1 Lj �— � 3 Cf Pro). uv ue avw. --I ^ `Proj. Name: Custody Seal on Cooler/Box Present: �s� ❑ no Seals intact: —,—ryes ❑ no ' Packing Material: aglubble Wrap []Bubble Bags ❑ None ❑ Other r► e..,......e�e. 114 / 1 rC Tvno of Icp- Wit' RhiP None n Samoles on ice coolmo process has beoun a• Cooler Temperature �c 3 Biological Tissue is Frozen: vas No Date and Initi Is of p rson xa ing contents: Temp should be above freezing to 6'C Comments: Chain of Custody Present: Yes No DN•A 1. Chain of Custody Filled Out: Yes ❑No DNA 2. Chain of Custody Relinquished: ®'l'e�s ❑NO ❑KA 3. Sampler Name & Signature on COC: 0<s ONO ❑N;A 4. Samples Arrived within Hold Time: Yes ONO ❑N+A 5. Short Hold Time Analysis (<72hr): ©<e s_❑No ❑NIA 6. Rush Turn Around Time Requested: ❑Yes Ef5o DMA 7. Sufficient Volume: C7Yes ONO ❑NrA 8. Correct Containers Used: ONO ❑NIA g. C�Yes -Pace Containers Used: CYes ON ❑NIA Containers Intact: ZTYes ONO ❑N;A 10. Filtered volume received for Dissolved tests ❑Yes ONO IA 11. Sample Labels match COC: es C> ❑NIA / 12. -Includes date/time/ID/Analysis Matrix: w- All containers needing preservation have been checked. Afe? L�7re8 ONO ❑NIA 13. All containers needing preservation are found to be In �❑No ❑wA compliance with EPA recommendation. exceptions: VO colifo TO &G. WI-DRO (water) Yes ❑No Initial when completed Lot tf of added preservative Samples checked for dechlorination: ❑Yes ONO _; v A 14. Headspace in VOA Vials ( >6mm): ❑Yes R6, ❑NIA 15. Trip Blank Present: ❑Yes No ❑7NfA 16. Trip Blank Custody Seals Present ❑Yes ❑No Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Reguired7 Y / N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) F-ALLC003rev.3, 11 4eR"UPN2 0 3 d a° A )S 0 a n C4 a -+ ITEM # m m m T. T m N v� c as z y '� J1� S N1 N JN1� N y C O 0 M n r n N O C CS CSC 0 01 mN� 3 N 7 p_ v n m ' Cl) r, G7ti 3 ° 3 Mbomoug a^ m�'a� a �3� .. Nm, CiWA 0 -1 m _ d m C S E 3 a co `m N y pro sFFs� f � a a r o m$ m a C ° 3 O a, d # o 2 MATRIX CODE (see velid codes to left) F! n m ; V7 V7 V7 V7 SAMPLETYPE (G=GRAB C=COMP) x cr q OD py py OD D d 01 S m S m m m m m 0) m m n 3 m 7 3 ,'7D1� c `Z po N NN VI O to A Ut N pp� W Nd0 Ut (Ap D A m O jNN m n z fi c3 Ciz 0 > ;10m m -Di m o z 3 o m SAMPLE TEMP AT COLLECTION A A M 0) M M 0) 0)°. D n ° D g 4 _ m m w m m m # OF CONTAINERS S m 101 101p> CL 3 > o, m N Unpreserved m m c n H2SO4 # m m HNO3 D ` S 0 c � m m m m m m HCI NeOH z o; 41 al Ne2S203 N x < n x Analyses Test Y/N z U. M x x x x x x NC App. I VOC 1 Dioxane + 4 x x x x x x NC App I Metals A d x x x x x x T � pH, SC. TEMP, TURB, DO, ORP (on C d x x x x x x TURB (on site) 3 ft x (B2) BNAis- $ $i 0 3 (J' S d 3 m z � TEMP in Cto Residual Chlorine (YIN) E Received on Ice g 3 D m (Y/N) Gusli>dy Sealed O Cooler o Y/N Samples Intact (YIN) � ci Page 149 of 182, ;a -0 3 AA) a o m �+ N o 0ao .t oh CR .1► w a + ITEM # N m d. T m Qc N J z a D m d d 3 V N m g o m m N 3 c �T V/ W N m 3 3 m m �r s < d .D, $ I11 m m �...� X v n3 v C m m C() T Obi A_ ' x N N s o m A io v c yy S 4 iii m ik N m O m CL W 3 m O v T MATRIX CODE (see velid codes to left) y m G7 SAMPLE TYPE (G=GRAB C=COMP) 0) G o y0 °< m N m y GS �T i i D i � 0 o •F V O O N Q�pp A V _ A v N 0I fn AW N �O O) ON N �O N m 1 z -4 X' D v z oZ D 1 1 m m m m v v1 (fir vR O i 0 3 3 M ' A d m SAMPLE TEMP AT COLLECTION A A _ 0) CD ao rn ao rn # OF CONTAINERS m 0)) m a m yyy (J m 'U'U O m N .� 2. o A N N Unpreserved H2SO4 m m d J 0 m 5� HNO3 ' rn rn rn rn rn rn ? HCI m NeOH N Ne2S203 N N N x 3 m Analyses Test YIN G � � N N. x x x x x x NC App. I VOC + 1, 4 Dioxene x x x x x x NC App. I Metals A IN x x x x x x pH, SC, TEMP, TURB, DO, ORP (on N (O N tin x x x x x x TURB (on site) x x BNA (Bis-2) 3 N Ic m v TEMP in C X Residual Chlorine (YIN) a Received on Ice S s (Y/N) Custody Sealed Cooler (YIN) Samples Intact (Y/N)LJ �V. Page 150 of 182 A S V 3 3 m a p m 0 a a z a O eo co -4 w a 41, 0 ITEM # m m m =ro m ?. 3 m y S o >> i z n D m s� n m `�� S• i d o s�3Ng3 3 r X 3 9 m CA m I?i — to C () tp 3 m D m D D w `� �' m 3 z Z m g !V m 3 U.0 mH '_ c ` m g m rfl m a v e.. C S O x 3QD y m Q % a a �_ap st op N°� C;v Fo m R R 0); c o m (Q N m m to ma° a MATRIX CODE (see valid codes to left) � y D C,10 m CT 0 0 0 0 0 0 0 SAMPLE TYPE (G=GRAB C=COMP) m �, � A n c C m m n rR v3 .D1 C Z m jJ` m m m m m m s o 3 p m SAMPLE TEMP AT COLLECTION m m m # OF CONTAINERS y m m n 2 Unpreserved 3 v v p N g m Q m m 0 .n H2SO4 m m, 0 HNO3 D m m HCI rn rn rn rn rn M NaOH c; Na2S203 y y F d x Analyses Test Y!N G � N to x x x x x NC App. I VOC r 1, 4 Dioxane (6 is m x x x x NC App I Metals A x x x pH, SC, TEMP, TURB DO ORP (on to IG d x x x TURB (on site) g CA BNA (Bis-2) 3 g _ Q � s m m •o � TEMP in C A Residual Chlorine (Y/N) 8 r' Received on Ice 3 g D (Y/N) Custody Sealed 0 Cooler Y/N Samples Intact (Y/N) ). J S' =n Page 151 of 182 -.FaceAnaoical Client Name: Courier: ❑ Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial LfJ Pace Other Tracking #: Custody Seal on Cooler/Box Present: yes ❑ no Seals intact: yes Packing Material: ❑ Bubble%�r l Bubble Bags El None ❑ Other Thermometer Used (/f-� Type of Ice: Blue None WO#:2618294 PM: SMM Due Date: 05/24/19 CLIENT: CDM-Raleigh Proj. Due Date: Proj. Name: El no ❑ Samples on ice. coolmq process has begun Cooler Temperature t Biological Tis us a is Frozen: Yes No Date and Initials of p rson acamining contents: r Temp should be above freezing to 6°C Comments: Chain of Custody Present: Yes ONO ❑N/A 1. Chain of Custody Filled Out: I. es ❑No ❑N/A 2. Chain of Custody Relinquished: Ole. ONO ❑N/A 3. Sampler Name & Signature on COC: es ❑No ❑N/A 4. Samples Arrived within Hold Time: Yes ONO ❑N/A 5. Short Hold Time Analysis <72hr): ❑Yes OK'o ❑NIA 6. Rush Turn Around Time Requested: ❑Yes o ❑NIA 7. Sufficient Volume: E VY"e's'- ❑No ❑NIA 8. Correct Containers Used: Yeses ONO ❑NIA 9. -Pace Containers Used: 'Yes ONO ❑NIA Containers Intact: Yes ONO ❑NIA 0. Filtered volume received for Dissolved tests❑Yews ONO A 11. Sample Labels match COC: moire ONO ❑NIA 12, -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. �� 'I'_,JYes ONO ❑NIA 13. All containers needing preservation are found to be in IDYes ONO ❑NIA compliance with EPA recommendation. Initial when Lot # of added exceptions: OA oliform, TOC, O&G, WI-DRO (water) Yes ONO completed preservative Samples checked for dechlorination: ❑Yes ONO +A 14. Headspace in VOA Vials ( >6mm): ❑Yes No ❑NIA 15. Trip Blank Present: @Ie"s' ONO ❑NIA 16. Trip Blank Custody Seals Present I] a ❑No ❑NIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y / N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) Page 152 of 182 F-ALLC003rev.3, 11September2006 INFORMATION SHEET SCHEDULE: May 2019 CLIENT NAME: CAMP, DRESSER, & MCKEE, INC. - RALEIGH CLIENT ADDRESS: 5400 GLENWOOD AVE., RALEIGH, NC 27612 CLIENT PHONE: 919/787-5620 CLIENT CONTACT: MAT COLONE SITE NAME: CABARRUS COUNTY SANITARY LANDFILL SITE ADDRESS: 4441 IRISH POTATO ROAD, CONCORD, NC 28206 SITE PHONE: 704/920-2951 SITE CONTACT: Kevin Grant Randal PROJECT NAME: CABARRUS CO LANDFILL UNITS 2 & 3 SEMI-ANNUAL EQUIPMENT NEEDED: ATV NEEDED,KEYS(Get Onsite), ROPE, BAILERS, GW KIT, CH4 METER, DO METER, GRUNDFOS, TUBING, BATTERY, AIR COMPRESSOR, CONTROL BOX, HOSES, CYLINDER,BLADDER PUMP, FLOW CELL,TURB. METER, MICRO SEEP KIT, FE2+ KIT, TEFLON,LINED BLADDER TUBING NOTES: Sample MNA wells using Bladder and low flow stabilization procedures. Review hydrogen sampling instructions. Enter additional data on additional data sheet needed for MNA wells. MNA wells: Use dedicated tubing left at site. MNA wells: Bring additional tubing for new/additional wells FedEx World Service Center 4542 Enterprise Dr Concord, NC 28027 SHIP SAMPLES ASAP Volatile Fatty Acid (2 Turquoise Cap) Must be in correct container ONLYI Methane Ethane Ethene, CO2 (2 White Cap) Must be in correct container ONLY► E* - is considered MW-E(R) BOC-43' SW-3 is the sediment pond outfall located near CD-2 BP - Bladder Pump Low Flow PPump - Peristaltic Pump Low Flow Bailer - 3 Well Volumes DIRECTIONS: • I-85 North into North Carolina, go through Charlotte, Take Exit 63, turn right off the exit (Lane St.) • Go to the stop sign, turn left onto Old Concord -Salisbury Rd. • Turn right onto the first paved road - Irish Potato Road • Landfill is 3-1/2 miles on the right SAMPLER S)/DATE(S): J 1 Page 1 of 4 page 153 of 182 Vt A W N O (0 OD V 0) (T AS W N S ro�nc7�m�v� � � �� Vs AS Nwc.9wcn �� � d) A <X a) -'Qv z Q A ii (i + — D= CA K>z MD v O M _ V � * A I >1 ZQ dv m >i A °v x) ch >ch C a m d< na c S 7_. 2. > (a u. m m d mi»1N N 0 Or 0)2 O m N N s J1 Ul ti x v O 4� LL GO T CL z u C n N Q Q nZB a l W W d do do W v -0 d d W W W W cn (D m ( 1 ( 3 3 fD v v v v �-3 C•7 H ['7 H C•7 H m H ['7 H ['7 H m H m �-3 m H ['7 �-3 m �-3 m H ['7 H H-n is' x ro ►j! m ro x ro x ro x ro � ro� ►2! x ro x ro h1 x m ro ro ro� h1 x ro V� ro� '►j! ro� h1 3 ro a ro ororororo oro. ororo 0 0 0 03 Oro 0 0 %0, %oro %oro %0 or0r0ror0% m ro 7d ro 7d ro ro 7d ro 7d ro ro ro ro ro ro ro 7d ro ro ,O ro� H C H C H C �-3 C �-3 C H C �-3 C �-3 C H C H C �-3 C �-3 C H C H C H C to W 7d to 7d W w W 7d to W w 7d W W W t7 to 7d to t7 to 7d to I J O r- UQ a x a w' PaV 154 of 182 x a v a) N A W N N O t0 00 �I 00H00mm p n nN 9 cJN a (D 9 Ili*, 3cY g (n x _ y v o <D m m n � N n ZW xv m 0 0 v CA F; n � r m C c a m H -n c w n� o p hi N m CL �. N m m O N N .. D. N O. y tQ W Vi ND '1 o 0 c� 3 a W� WO m m c C m w d d m lu co m 3 3 co co co co co co v v ro x ro x ro x ro x ro x ro x ro x ro x ro x ro x ro x ro x n n n n H t1i H - t1i H t1i H t1i H t1i H t1i H m H t+i H m H m H t1i H t1i 21 m +o+or00P. P. grororgrorgrg3 Toro 0 0 0ro �- 0 0 0 0 0 0a ID PU ro ro ro ro ro ro ro ro ro ro ro ro H H H H Page bd 55 of 182 ?ceAnalytical i May 23, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618294 Pace Workorder. 30305 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory between Friday, May 10, 2019 and Monday, May 13, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/23/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30305 - 1167051 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 27 Page 1 of 21 Page 156 of 182 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30305 - 1167051 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 21 Page 157 of 182 ?ceAnalytical i SAMPLE SUMMARY Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 303050001 1302-AMW-2D Water 5/7/201914:28 5/10/2019 10:30 303050002 1302-AMW-2S Water 5/7/201913:18 5/10/2019 10:30 303050003 1302-MW-E Water 5/7/201915:57 5/10/2019 10:30 303050004 1302-AMW-1 D Water 5/8/2019 12:29 5/10/2019 10:30 303050005 1302-AMW-1S Water 5/8/201911:07 5/10/2019 10:30 303050006 1302-MW-3 Water 5/8/201914:07 5/10/2019 10:30 303050007 1302-MW-E DEEP Water 5/8/2019 09:26 5/10/2019 10:30 303050008 1302-MW-L Water 5/8/201915:58 5/10/2019 10:30 303050009 1302-MW-A Water 5/9/2019 09:18 5/13/2019 07:30 Report ID: 30305 - 1167051 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 21 Page 158 of 182 ?ceAnalytical @ PROJECT SUMMARY Workorder: 30305 CABARRUS COUNTY / 2618294 Batch Comments Batch: EDON/4070 -Low Level Volatile Fatty Acids Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 The matrix spike and/or spike duplicate, recovery or relative percent difference; accuracy influenced by the reference sample 302810001. Analyte Pentanoic, iso-Hexanoic and Hexanoic acids. Batch acceptance based on laboratory control sample recovery. Report ID: 30305 - 1167051 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 4 of 21 Page 159 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050001 Sample ID: 1302-AMW-2D Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 14:28 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 03:38 KB Acetic Acid 0.0251.11 mg/I 0.10 0.025 1 5/12/2019 03:38 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 03:38 KB B Formic Acid 0.17J mg/I 0.50 0.098 1 5/12/2019 03:38 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 03:38 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 03:38 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 03:38 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 03:38 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 03:38 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 03:38 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.25J ug/I 0.50 0.046 1 5/15/2019 09:13 BW n Ethane 0.037J ug/I 0.10 0.0050 1 5/15/2019 09:13 BW n Ethene 0.050J ug/I 0.10 0.0040 1 5/15/2019 09:13 BW n Carbon Dioxide 150 mg/I 5.0 0.45 1 5/15/2019 09:13 BW n Report ID: 30305 - 1167051 Page 5 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 160 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050002 Sample ID: 1302-AMW-2S Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 13:18 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 04:34 KB Acetic Acid 0.036J mg/I 0.10 0.025 1 5/12/2019 04:34 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 04:34 KB B Formic Acid 0.19J mg/I 0.50 0.098 1 5/12/2019 04:34 KB B Butyric Acid 0.0078J mg/I 0.10 0.0070 1 5/12/2019 04:34 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 04:34 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 04:34 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 04:34 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 04:34 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 04:34 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 17 ug/I 0.50 0.046 1 5/15/2019 09:24 BW n Ethane 0.070J ug/I 0.10 0.0050 1 5/15/2019 09:24 BW n Ethene 0.36 ug/I 0.10 0.0040 1 5/15/2019 09:24 BW n Carbon Dioxide 190 mg/I 5.0 0.45 1 5/15/2019 09:24 BW n Report ID: 30305 - 1167051 Page 6 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 161 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050003 Sample ID: 1302-MW-E Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 15:57 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 05:31 KB Acetic Acid 0.035J mg/I 0.10 0.025 1 5/12/2019 05:31 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 05:31 KB B Formic Acid 0.24J mg/I 0.50 0.098 1 5/12/2019 05:31 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 05:31 KB Pyruvic Acid 0.014J mg/I 0.10 0.0050 1 5/12/2019 05:31 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 05:31 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 05:31 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 05:31 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 05:31 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 930 ug/I 0.50 0.046 1 5/15/2019 09:36 BW n Ethane 3.0 ug/I 0.10 0.0050 1 5/15/2019 09:36 BW n Ethene 0.60 ug/I 0.10 0.0040 1 5/15/2019 09:36 BW n Carbon Dioxide 420 mg/I 5.0 0.45 1 5/15/2019 09:36 BW n Report ID: 30305 - 1167051 Page 7 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 162 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050004 Sample ID: 1302-AMW-1D Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/8/2019 12:29 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 06:27 KB Acetic Acid 0.038J mg/I 0.10 0.025 1 5/12/2019 06:27 KB B Propionic Acid 0.0065J mg/I 0.10 0.0020 1 5/12/2019 06:27 KB B Formic Acid 0.26J mg/I 0.50 0.098 1 5/12/2019 06:27 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 06:27 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 06:27 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 06:27 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 06:27 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 06:27 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 06:27 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 2700 ug/I 0.50 0.046 1 5/15/2019 09:49 BW n Ethane 1.4 ug/I 0.10 0.0050 1 5/15/2019 09:49 BW n Ethene 0.73 ug/I 0.10 0.0040 1 5/15/2019 09:49 BW n Carbon Dioxide 300 mg/I 5.0 0.45 1 5/15/2019 09:49 BW n Report ID: 30305 - 1167051 Page 8 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 163 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050005 Sample ID: 1302-AMW-1S Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/8/2019 11:07 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 07:23 KB Acetic Acid 0.0251.11 mg/I 0.10 0.025 1 5/12/2019 07:23 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 07:23 KB B Formic Acid 0.13J mg/I 0.50 0.098 1 5/12/2019 07:23 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 07:23 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 07:23 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 07:23 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 07:23 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 07:23 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 07:23 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 1300 ug/I 0.50 0.046 1 5/15/201911:03 BW n Ethane 0.21 ug/I 0.10 0.0050 1 5/15/201911:03 BW n Ethene 0.00401.11 ug/I 0.10 0.0040 1 5/15/201911:03 BW n Carbon Dioxide 230 mg/I 5.0 0.45 1 5/15/2019 11:03 BW n Report ID: 30305 - 1167051 Page 9 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 164 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050006 Sample ID: 1302-MW-3 Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/8/2019 14:07 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 08:20 KB Acetic Acid 0.027J mg/I 0.10 0.025 1 5/12/2019 08:20 KB B Propionic Acid 0.0063J mg/I 0.10 0.0020 1 5/12/2019 08:20 KB B Formic Acid 0.22J mg/I 0.50 0.098 1 5/12/2019 08:20 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 08:20 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 08:20 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 08:20 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 08:20 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 08:20 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 08:20 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.13J ug/I 0.50 0.046 1 5/15/201911:12 BW n Ethane 0.070J ug/I 0.10 0.0050 1 5/15/201911:12 BW n Ethene 0.015J ug/I 0.10 0.0040 1 5/15/201911:12 BW n Carbon Dioxide 160 mg/I 5.0 0.45 1 5/15/2019 11:12 BW n Report ID: 30305 - 1167051 Page 10 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 165 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050007 Sample ID: 1302-MW-E DEEP Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/8/2019 09:26 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 09:16 KB Acetic Acid 0.082J mg/I 0.10 0.025 1 5/12/2019 09:16 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 09:16 KB B Formic Acid 0.0981.11 mg/I 0.50 0.098 1 5/12/2019 09:16 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 09:16 KB Pyruvic Acid 0.022J mg/I 0.10 0.0050 1 5/12/2019 09:16 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 09:16 KB Pentanoic Acid 0.044J mg/I 0.10 0.011 1 5/12/2019 09:16 KB M3,M5 i-Hexanoic Acid 0.0111,11 mg/I 0.20 0.011 1 5/12/2019 09:16 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 09:16 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 10000 ug/I 0.50 0.046 1 5/15/201911:21 BW n Ethane 5.3 ug/I 0.10 0.0050 1 5/15/201911:21 BW n Ethene 0.076J ug/I 0.10 0.0040 1 5/15/201911:21 BW n Carbon Dioxide 360 mg/I 5.0 0.45 1 5/15/2019 11:21 BW n Report ID: 30305 - 1167051 Page 11 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 166 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050008 Sample ID: 1302-MW-L Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/8/2019 15:58 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0481.11 mg/I 0.20 0.048 1 5/12/2019 10:12 KB Acetic Acid 0.044J mg/I 0.10 0.025 1 5/12/2019 10:12 KB B Propionic Acid 0.00201.11 mg/I 0.10 0.0020 1 5/12/2019 10:12 KB B Formic Acid 0.20J mg/I 0.50 0.098 1 5/12/2019 10:12 KB B Butyric Acid 0.00701.11 mg/I 0.10 0.0070 1 5/12/2019 10:12 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 10:12 KB i-Pentanoic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/12/2019 10:12 KB Pentanoic Acid 0.0111,11 mg/I 0.10 0.011 1 5/12/2019 10:12 KB M3,M5 i-Hexanoic Acid 0.011U mg/I 0.20 0.011 1 5/12/2019 10:12 KB M3,M5 Hexanoic Acid 0.0321.11 mg/I 0.20 0.032 1 5/12/2019 10:12 KB M3,M5 RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.057J ug/I 0.50 0.046 1 5/15/201911:32 BW n Ethane 0.00501.11 ug/I 0.10 0.0050 1 5/15/201911:32 BW n Ethene 0.00401.11 ug/I 0.10 0.0040 1 5/15/201911:32 BW n Carbon Dioxide 77 mg/I 5.0 0.45 1 5/15/2019 11:32 BW n Report ID: 30305 - 1167051 Page 12 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 167 of 182 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303050009 Sample ID: 1302-MW-A Date Received: 5/13/2019 07:30 Matrix: Water Date Collected: 5/9/2019 09:18 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0431.11 mg/I 0.20 0.043 1 5/15/2019 15:32 KB Acetic Acid 1.0 mg/I 0.10 0.028 1 5/15/2019 15:32 KB Propionic Acid 0.019J mg/I 0.10 0.0040 1 5/15/2019 15:32 KB Formic Acid 0.15J mg/I 0.50 0.086 1 5/15/2019 15:32 KB Butyric Acid 0.0111,11 mg/I 0.10 0.011 1 5/15/2019 15:32 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/15/2019 15:32 KB i-Pentanoic Acid 0.0085J mg/I 0.10 0.0060 1 5/15/2019 15:32 KB Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/15/2019 15:32 KB i-Hexanoic Acid 0.0291.11 mg/I 0.20 0.029 1 5/15/2019 15:32 KB Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/15/2019 15:32 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 5100 ug/I 0.50 0.046 1 5/15/201911:42 BW n Ethane 0.038J ug/I 0.10 0.0050 1 5/15/201911:42 BW n Ethene 0.014J ug/I 0.10 0.0040 1 5/15/201911:42 BW n Carbon Dioxide 290 mg/I 5.0 0.45 1 5/15/2019 11:42 BW n Report ID: 30305 - 1167051 Page 13 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 168 of 182 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. B The analyte was detected in the associated blank. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. M3 The matrix spike sample recovery was outside laboratory control limits. Report ID: 30305 - 1167051 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 14 of 21 Page 169 of 182 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: EDON/4070 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 303050001, 303050002, 303050003, 303050004, 303050005, 303050006, 303050007, 303050008 METHOD BLANK: 61168 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.048U 0.048 Acetic Acid mg/I 0.046J 0.025 B Propionic Acid mg/I 0.0059J 0.0020 B Formic Acid mg/I 0.20J 0.098 B Butyric Acid mg/I 0.0070U 0.0070 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0050U 0.0050 Pentanoic Acid mg/I 0.011 U 0.011 M3,M5 i-Hexanoic Acid mg/I 0.011 U 0.011 M3,M5 Hexanoic Acid mg/I 0.032U 0.032 M3,M5 LABORATORY CONTROL SAMPLE: 61169 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 113 70-130 Acetic Acid mg/I 2 2.1 105 70-130 B Propionic Acid mg/I 2 2.1 104 70-130 B Formic Acid mg/I 2 2.1 107 70-130 B Butyric Acid mg/I 2 2.1 104 70-130 Pyruvic Acid mg/I 2 1.9 94 70-130 i-Pentanoic Acid mg/I 2 2.0 99 70-130 Pentanoic Acid mg/I 2 2.0 102 70-130 M3,M5 i-Hexanoic Acid mg/I 2 2.1 104 70-130 M3,M5 Hexanoic Acid mg/I 2 1.9 95 70-130 M3,M5 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61170 61171 Original: 302810001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.066 2 2.0 2.2 97 106 70-130 8.7 30 Acetic Acid mg/I 0.055 2 2.3 2.2 112 110 70-130 1.8 30 B Report ID: 30305 - 1167051 Page 15 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 170 of 182 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61170 61171 Original: 302810001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Propionic Acid mg/I 0 2 2.3 2.3 116 113 70-130 2.4 30 B Formic Acid mg/I 0.12 2 2.5 2.4 121 113 70-130 6.5 30 B Butyric Acid mg/I 0.0091 2 2.6 2.4 129 119 70-130 7.6 30 Pyruvic Acid mg/I 0 2 2.3 2.3 114 115 70-130 1.2 30 i-Pentanoic Acid mg/I 0 2 2.4 2.3 121 115 70-130 5.5 30 Pentanoic Acid mg/I 0 2 2.9 2.7 144 135 70-130 6.9 30 M3,M5 i-Hexanoic Acid mg/I 0 2 2.8 2.7 140 134 70-130 4.1 30 M3,M5 Hexanoic Acid mg/I 0 2 2.9 2.6 146 132 70-130 10 30 M3,M5 Report ID: 30305 - 1167051 Page 16 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 171 of 182 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7535 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303050001, 303050002, 303050003, 303050004, 303050005, 303050006, 303050007, 303050008, 303050009 METHOD BLANK: 61187 Blank Reporting Parameter Units Result Limit Qualifiers RISK Methane ug/I 0.046U 0.046 n Ethane ug/I 0.0050U 0.0050 n Ethene ug/I 0.0040U 0.0040 n METHOD BLANK: 61188 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 0.45U 0.45 n LABORATORY CONTROL SAMPLE & LCSD: 61189 61191 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 760 740 101 99 80-120 1.7 20 n Ethane ug/I 38 39 38 104 101 80-120 3.1 20 n Ethene ug/I 35 36 35 103 98 80-120 4.9 20 n LABORATORY CONTROL SAMPLE & LCSD: 61190 61192 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 120 110 106 97 80-120 9.1 20 n Report ID: 30305 - 1167051 Page 17 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 172 of 182 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30305 CABARRUS COUNTY / 2618294 QC Batch: EDON/4075 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 303050009 METHOD BLANK: 61209 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028U 0.028 Propionic Acid mg/I 0.0040U 0.0040 Formic Acid mg/I 0.086U 0.086 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 61210 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 109 70-130 Acetic Acid mg/I 2 2.1 103 70-130 Propionic Acid mg/I 2 2.0 102 70-130 Formic Acid mg/I 2 2.0 101 70-130 Butyric Acid mg/I 2 2.0 103 70-130 Pyruvic Acid mg/I 2 2.1 106 70-130 i-Pentanoic Acid mg/I 2 2.0 99 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 i-Hexanoic Acid mg/I 2 1.8 91 70-130 Hexanoic Acid mg/I 2 1.9 94 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.22 20 22 22 107 108 70-130 1.3 30 d Acetic Acid mg/I 29 20 50 50 104 105 70-130 0.29 30 d Report ID: 30305 - 1167051 Page 18 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 173 of 182 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Propionic Acid mg/I 5.6 20 26 26 104 103 70-130 0.53 30 d Formic Acid mg/I 1.6 20 21 21 99 99 70-130 0.23 30 d Butyric Acid mg/I 0.84 20 22 22 107 106 70-130 1.1 30 d Pyruvic Acid mg/I 0.29 20 22 22 107 107 70-130 0.01 30 d i-Pentanoic Acid mg/I 0.38 20 21 21 105 103 70-130 1.9 30 d Pentanoic Acid mg/I 0.57 20 22 22 107 105 70-130 2 30 d i-Hexanoic Acid mg/I 0 20 21 20 106 101 70-130 4.9 30 d Hexanoic Acid mg/I 0.15 20 22 22 108 107 70-130 0.69 30 d Report ID: 30305 - 1167051 Page 19 of 21 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 174 of 182 ?ceAnalytical QUALITY CONTROL DATA QUALIFIERS Workorder: 30305 CABARRUS COUNTY / 2618294 QUALITY CONTROL PARAMETER QUALIFIERS B The analyte was detected in the associated blank. M3 The matrix spike sample recovery was outside laboratory control limits. M5 The matrix spike duplicate sample recovery was outside laboratory control limits. d The analyte concentration was determined from a dilution. n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30305 - 1167051 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 20 of 21 Page 175 of 182 ?ceAnalytical i QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30305 CABARRUS COUNTY / 2618294 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 303050001 1302-AMW-2D AM23G EDON/4070 303050002 1302-AMW-2S AM23G EDON/4070 303050003 1302-MW-E AM23G EDON/4070 303050004 1302-AMW-1 D AM23G EDON/4070 303050005 1302-AMW-1 S AM23G EDON/4070 303050006 1302-MW-3 AM23G EDON/4070 303050007 1302-MW-E DEEP AM23G EDON/4070 303050008 1302-MW-L AM23G EDON/4070 303050001 1302-AMW-2D AM20GAX DISG/7535 303050002 1302-AMW-2S AM20GAX DISG/7535 303050003 1302-MW-E AM20GAX DISG/7535 303050004 1302-AMW-1D AM20GAX DISG/7535 303050005 1302-AMW-1S AM20GAX DISG/7535 303050006 1302-MW-3 AM20GAX DISG/7535 303050007 1302-MW-E DEEP AM20GAX DISG/7535 303050008 1302-MW-L AM20GAX DISG/7535 303050009 1302-MW-A AM20GAX DISG/7535 303050009 1302-MW-A AM23G EDON/4075 Report ID: 30305 - 1167051 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 21 of 21 Page 176 of 182 ff 111,-" (1) T T -t T Ct) (;Do =r ID 111 0 10 1 w !M 0 7— 0 Dv 0 0 0' -4 M (D N. ID 0 C.) 7-Ih 'D CI 0 (D (D 10 0) o (D-rh. N) R� 0 ID I a—) Z3 OD 0 IN 0 IN) . (0 (D > U) C:) 0 N)(D Z (D cn cn 0 cn cn 0 cn Q co �3 �3 63 a3 �O ::1 -4 00 N N N N N N R3 N N tD c) O N cn 00 00 00 00 00 00 w w w 0 0 C) 0 0 (D (D 0 0 CO 00 0) 01 4 W N) AD HCL Unpreserved 0 0 0 0 .9 tD z O (D c M (D 0 '75' 00)7 > 0) (D (cn (D (n 0 0 c c IN) w _J Sub Dissolved Carbon Dioxide Ir w .f. wt, O W E V O O CL (n IN) -DL N O Page 177 8f 182 [-. � OrJ8r Receipt ^0[m . 'Lab VVorkOrder Project~ -- Client Name: c A. Shipping/Container |nfurmation(circle appropriate response) AJr6@Present mo Courier: UPS USPS Client Otheri Tracking Number: / Custody Sea[ onComie present: Yes Seals intact: Yes No Absorbent Foam Otheri Cmm|er/BoxPacking��a1eha{: Type ofIce: et, Blue None {ce|ntact: e|ted �--~ Chain �_ f[usto6yPre�en��/ Ye� No Radiation Screened: YesCooler Ternperature:1 /No � ~ comments. B. Laboratory Assignment/Log-in (check appropriate response) Chain of Custody properly filled out Chain of Custody relinquished Containers intact -Were ----�samples inseparate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided -- �\ PAEScon containers Are containers properly preserved for the requested testing? (as labeled) if an unknown ' preservat�on state, were containers checked? Was volume for dissolved testing field filtered, as noted on the CDC? was volume recetved in a preserved Container? Headspace present? Comments: _� Reference non -Conformance YES I NO I N/A Comment if yes, see pH form. ate' Cooler contents ex�� a|no6/received by u . ' D�te^^ project K�anagerReviem/ � . F_p/%E-[l_0O9-rc-,Ol, 3[}ct2017 Page 1raor1oc 0 cc 00 -4 0) cn -N w N) m 3 3(D 0) 0) (D 0 0 0 c 0 0) 0 X V m o 0 co (D > 0 U) 0 c -asCL CD =r (D Z3 0 > m (D 0 0 0 0 :3. 0 V 3 c) 3 c- ' N — a (D a m rI> rI> 0 (D (D 77 rQ a) ch m (D cn 0 hj �n 0 (D C> c Z3 9 O CL <D G) ZD-> CD Im c) 0) <D 00 C ;U 0 (0 (D -a CD 0 ty CD M U) 44 0 --j 0 0 60 60 60 60 co 0 P—) N—) C? 0 co co co co co co co co Vl 0 p A .. :t .. i� .. ;� Z� :I a) co r") 0) C:) -.4 0 --J N) CD cri --J 11 CO j'� CO cr Q Na 0) NJ 0) N) 0) CL 00 m 00 PI) w m w PI) 00 m 00 PI) w m W -04 w CD w CD W CD (0 (D 0 0 CD co 0) cn 4, co PQ Ct Z :0 (D co m CD z cp HCL Unpreserved CL ;U 0 Z, m CL X X X >< >< >< >< >< Sub Dissolved Carbon Dioxide (D solve -n z 0 o — — — — — — — — — — — 0 0 > U) '0 O (D z CA m 0 o I.A I z C) Page 179 of 182 Cooler Receipt Form b Work order Client Name: Project' A. Shipping/Container Information (circle appropriate response) Air bill ?resent: Yes N0 Courier: Fed Ex UPS USPS Client Other. Tracking ''Number: I f�FlSeals in�act:� Yesy No Custody Seal on Caoier/Box Present: � es , o- P CoalerjBax Paci'ing'10ateriai. ubble At�ira'p Absorbent Poarr! Other; Type o kce:(,NeL�Blue P�ione ice intact* . es!' fVeited it- C `' i� o �. Chain of Custody Present: e/ Cooler TemperEt,ire: — Radiation Screened: 1 e Comments: B. Laboratory P_ssigr rent%Log-in (check appropriate response) YES NO �J/� 1 Comment I I R.eierence non -Conformance Chain of Custody properly �iI! d out ! Chair, of Custody relinquished I Sampler Name G Signature on COC i j I L i I Containers intact — ""ere samples In separate bags Sample container labels match COC Sample name/date and time collected Sufficient volume provided PP.ES containers used /I Are containers properly preserved for the requested testing. (as labeled) 1 .`yes, see pN �o If an unknOVJr! preservation state, v,+e-e CO aIr erS checked? � c011fOrrn Exception; `JOa s j Was v iume -0r dlss01'ved testln{ Held it tered; as noted on the COC, Vf/as volume recer d In pre SeNen OOritainerr Heaospace present, comments: -.(� Caaier contents examined/rece'��'ed b'y J Date:' p_rOj&ct N,�anager Ravtew Date: � .r-Pp. P.-Q-OC)9-re17, 01. 3 act �� l Page 180 of 182 NON-CONFORMANCE Fo'U✓ pAES Work Order Time of Receipt: Date: c REASON FOR NION-COT-,TFOKMLANCE� ;4" 'z�t AC TION TAKEN: Ch ent na-me Customer Service llldlials� T--P,�-E-Q-014-rev-00-20 N 0v2C) 1 A Date: Date: 5 a Time: Page 181 of 182 Page 1 of 2 Emma Louis - CDM Sub outs, in Summary (3 Pace Atlanta Projects) From: Sakina Mckenzie To: Louis, Emma Date: 5/10/2019 1:16 PM Subject: CDM Sub outs, in Summary (3 Pace Atlanta Projects) Cc: Welsh, Ruth Just in Summary, there are 10 samples total, for Dissolved Carbon Dioxide, Dissolved Hydrogen, Methane/Ethane/ Ethene, and Volatile Fatty Acids. Well 1302-CD-1S is separate on one project, #2618286 The other Wells are split between 2618294 (Dissolved Carbon Dioxide, Methane/Ethane/Ethene and Volatile Fatty Acids) and 2618427 Dissolved Hydrogen only. Thank you, I am so sorry. It must be hot in the field, I can't figure out what these field guys are doing with this event. Sakina Sakina N. McXenzie Senior Project Manager Pace Analytical Services LLC. 110 Technology Pkwy NW Peachtree Corners, GA 30092 Main: 770-734-4200 1 Direct: 770-734-4204 Internal: 264204 Sakina. NfcKenzie(a�pacelabs. com >>> Sakina Mckenzie 5/10/2019 12:43 PM >>> Hi Emma, Not sure what our field samplers did, but they sampled all of the Dissolved Hydrogen separate from the rest of the parameters that we shipped to you (Carbon Dioxide, Volatile Fatty Acids, and M/E/E). I am logging the Dissolved Hydrogen now (2618427), so disregard this analysis when the samples arrive today for the rest of those parameters. Page 182 of 182 file:///C:/tJsers/elouis/AppData/Local/Temp/XPgrpwise/5 CD579COPACE_DOMAINPAE... 5/10/2019 11!;a'ceAna1j&a( wmpacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 May 30, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618427 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 22 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618427 Lab ID Sample ID Matrix Date Collected Date Received 2618427001 1302-AMW-1 D Water 05/08/19 11:59 05/10/19 09:20 2618427002 1302-AMW-1S Water 05/08/19 10:38 05/10/19 09:20 2618427003 1302-AMW-2D Water 05/07/19 14:10 05/10/19 09:20 2618427004 1302-AMW-2S Water 05/07/19 13:03 05/10/19 09:20 2618427005 1302-MW-3 Water 05/08/19 13:52 05/10/19 09:20 2618427006 1302-MW-A Water 05/09/19 08:52 05/10/19 09:20 2618427007 1302-MW-E Water 05/07/19 15:43 05/10/19 09:20 2618427008 1302-MW-E Deep Water 05/08/19 09:05 05/10/19 09:20 2618427009 1302-MW-L Water 05/08/19 15:37 05/10/19 09:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 22 N x o O - a n O a y � N iz N (N1,4) eulaal4:) IUVN':31J v r. ti o 3jdHOlOO19jn jld wa.UNDOMd a dHo/OC]jqjdildwGjMooMd _ 6H'ury'aj *s[uloyy I ddV q (ua6dipR}{) snsvE) ponlossrCl p tl OOj 1 (V:IM S-eo PaAMs 10 p (3 -3 'Yi 'zoo) S-co pemos a a a-ZS-005r"s 4q ep31n5 Cc:) l'OS 'EON 'IO -NV 'AuP•9 ❑09 1'1 ulv1u4l4d{ya•Z•st91 OCAS CLZ9 _111- o9Z8A4 QOA I .ddV WA Jaal96841ouy i8ylp m >7 µt n 1 lauuuiary m i�aszErr W U HOuN IUH �', :'. y a C �r a. EONH rOSZH z .2 c .. m' m S a o am pavesaiduH Yo_ iAY s Q U DQ a pi°, a '•� SkiJNtl1NV;)JU. tu O z ~ a w = F U ti IL o tp U) {P wo to Oil 4r; {d WU:J=O E1tl1J�=`.71 3dA1 3ldNlVS Lry C7 C7 C7 C7 [J 0 L7 U' 0 0 L7 m U of sopon pyen 0es1 30V'J X1111Vri jM I IM JM IM I♦A JIN 1A1 I L4l M 1JJV JM JM cf>!at z m 4 m� F � pm W [W❑[❑)) E LL r:- fi y 3ai$h4J€a V N m - k r^ r C7 d Uj W U3 iJ +/} GCGC .- d U Y] U R m N ` J f 3 7 7 a g = eai e�i m Q E o LL crCL �a oa # W311 �+ r� a In to r- w m n » ,fir+ 3 oN wo# FaceAna#tal Client Name: PM: 5M CLIENT: Courier: J�,dx❑ UPS :] USPS J Client Commercial ] Pace Other Tracking Custody Seal on Cooler/Box Present: no Seals intact: yes no Packing Material: E-9,bble Wrap ElBubble Bagsj cone Other Thermometer Used ( Type of Ice: Blue None L 5amp :2618427 Dire Date: 05/29/19 CDM-Raleigh j` riuj. rJue uatt: j Proj. Name: on iceccoltnq process has becun Cooler Temperature r 3 [ Biological Tissue is Frozen: ves too to and Init' Is of p rson xa ing f - Temp should be above freezing to 6 C Comments: ontents:. Chain of Custody Present: LIti A , Chain of Custody Pilled Out: rNs += -1NeA 2• Chain of Custody Relinquished: 2•:—N.A 3. Sampler Name & Signature on COC: a <1 i Samples Arrived within Hold Time: " res CNo :;i 4 5- Short Hold Time Analysis (<72hr): ❑Yes ?< Rush Turn Around Time Requested: rJ' Yes or vQ -J. ; 7• Sufficient Volume: ZY—ea ` •+r. Correct Containers Used: (res ❑uo -Pace Containers Used: Z_ess Cr+a ❑WA Containers Intact: as �Pi0 ❑N,A 10. Filtered volume received for Dissolved tests ❑Yes ❑N❑ �a 11. Sample Labels match COC: es ❑r;o ❑N+'A 12. -Includes dateltimeJiD/Analysis Matrix,. - All containers needing preservation have been checked. Yefo ❑7 Gr ,,,�+ L�r.l 13 All containers needing preservation are found to be in 111Y65 ENO NrA compliance with EPA recommendation. Initial when Lot 9 e added exceptions: VOA. coliform, TOC. O&G- WI-DRD (water) ©Yes r!o completed Prese alive Samples checked for dechlorination: ❑Yes ❑No � 14- Headspace in VOA Vials ( >6mm}: CIYes El No N•a 15 Trip Blank Present: ©Yes ©Na NiA. 15- Trip Blank Custody Seats Present ❑Yes ❑No -C A Pace Trip Blank Lot # (if purchased): Client Notificatioril Resolution: Person Contacted: Comments) Resolution: Project Manager Review: DateMme: Field ❑�to Required? Y 1 N Now Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be ser{t to the North Carolina i]EHNR Certification Office t i.e out of hold, incorrect preservative, out of temp, incorrect ccnimnersl jl F-ALLCg03rev.3 11 Sept Page 400 22 ?ceAnalytical i May 24, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618427 Pace Workorder. 30310 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Monday, May 13, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/24/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30310 - 1168512 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 188 Page 1 of 16 Page 5 of 22 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30310 - 1168512 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 16 Page 6 of 22 ?ceAnalytical i SAMPLE SUMMARY Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Matrix Date Collected Date Received 303100001 1302-AMW-1 D Bubble Strip 5/8/2019 11:59 5/13/2019 07:30 303100002 1302-AMW-1S Bubble Strip 5/8/2019 10:38 5/13/2019 07:30 303100003 1302-AMW-2D Bubble Strip 5/7/2019 14:10 5/13/2019 07:30 303100004 1302-AMW-2S Bubble Strip 5/7/2019 13:03 5/13/2019 07:30 303100005 1302-MW-3 Bubble Strip 5/8/2019 13:52 5/13/2019 07:30 303100006 1302-MW-A Bubble Strip 5/9/2019 08:52 5/13/2019 07:30 303100007 1302-MW-E Bubble Strip 5/7/2019 15:43 5/13/2019 07:30 303100008 1302-MW-E DEEP Bubble Strip 5/8/2019 09:05 5/13/2019 07:30 303100009 1302-MW-L Bubble Strip 5/8/2019 15:37 5/13/2019 07:30 Report ID: 30310 - 1168512 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 16 Page 7 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100001 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-AMW-1D Date Collected: 5/8/2019 11:59 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.3 nM 1.0 0.75 1 5/20/201910:23 TD n Report ID: 30310 - 1168512 Page 4 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 8 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100002 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-AMW-1S Date Collected: 5/8/2019 10:38 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.6 nM 1.0 0.75 1 5/20/201910:35 TD n Report ID: 30310 - 1168512 Page 5 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 9 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100003 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-AMW-2D Date Collected: 5/7/2019 14:10 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.7 nM 1.0 0.75 1 5/20/201910:47 TD n Report ID: 30310 - 1168512 Page 6 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100004 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-AMW-2S Date Collected: 5/7/2019 13:03 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.5 nM 1.0 0.75 1 5/20/201911:00 TD n Report ID: 30310 - 1168512 Page 7 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 11 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100005 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-MW-3 Date Collected: 5/8/2019 13:52 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.1 nM 1.0 0.75 1 5/20/201911:12 TD n Report ID: 30310 - 1168512 Page 8 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 12 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100006 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-MW-A Date Collected: 5/9/2019 08:52 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.3 nM 1.0 0.75 1 5/20/201911:24 TD n Report ID: 30310 - 1168512 Page 9 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 13 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100007 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-MW-E Date Collected: 5/7/2019 15:43 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.7 nM 1.0 0.75 1 5/20/201911:37 TD n Report ID: 30310 - 1168512 Page 10 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 14 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100008 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-MW-E DEEP Date Collected: 5/8/2019 09:05 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 2.7 nM 1.0 0.75 1 5/20/201911:51 TD n Report ID: 30310 - 1168512 Page 11 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 15 of 22 ?ceAnalytical Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303100009 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-MW-L Date Collected: 5/8/2019 15:37 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 1.6 nM 1.0 0.75 1 5/20/201912:05 TD n Report ID: 30310 - 1168512 Page 12 of 16 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 16 of 22 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30310 - 1168512 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 13 of 16 Page 17 of 22 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7545 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303100001, 303100002, 303100003, 303100004, 303100005, 303100006, 303100007, 303100008, 303100009 METHOD BLANK: 61287 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 0.75U 0.75 n LABORATORY CONTROL SAMPLE & LCSD: 61288 61289 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 25 25 102 102 80-120 0.092 20 n Report ID: 30310 - 1168512 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 14 of 16 Page 18 of 22 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 30310 CABARRUS COUNTY / 2618427 QUALITY CONTROL PARAMETER QUALIFIERS The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30310 - 1168512 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 15 of 16 Page 19 of 22 ?ceAnalytical QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30310 CABARRUS COUNTY / 2618427 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID Sample ID Prep Method Prep Batch Analysis Method Analysis Batch 303100001 1302-AMW-1D AM20GAX DISG/7545 303100002 1302-AMW-1S AM20GAX DISG/7545 303100003 1302-AMW-2D AM20GAX DISG/7545 303100004 1302-AMW-2S AM20GAX DISG/7545 303100005 1302-MW-3 AM20GAX DISG/7545 303100006 1302-MW-A AM20GAX DISG/7545 303100007 1302-MW-E AM20GAX DISG/7545 303100008 1302-MW-E DEEP AM20GAX DISG/7545 303100009 1302-MW-L AM20GAX DISG/7545 Report ID: 30310 - 1168512 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 16 of 16 Page 20 of 22 -n M cn A w IQ 0 m -V -V -V cn X 3 ::1 ID W W 0 ro fD r C-D' CD C=D) =o 0 0 q- o ID ch - c) K 0 M ID :1 Oco v o C4,' ea (D 3 3 < -04 0 0 0 0 0 a (D 0 o ID (D (D CD 0 o G) CD Dv v 'a 0 0) 0 z 0 Q0 CD K) 0 ni CY 0 0 HLL 03 65 � ::I ao 00 (o co cn C-) (D CA 0- w w w 4 0 cn w K) N w o co W 0 cr Cy- CD 0, M —W 0) C� 1 CD A CC) co w C. co cy- C C) C:) C) C) C) C) 0 0 0 C) 0 0 0 C) ON C) co 00 --4 0) cn -N w 70 Unpreserved N77 z m Oi YD x x is is is is is is is Dissolved Gases (HVdrouen) z m 0 z PR 0 a CD OD 4h. &I O Page 2Pof 22 -„ 7 L ?ceAnalytical i May 24, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618286 Pace Workorder. 30311 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Monday, May 13, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/24/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30311 - 1166737 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 9 Page 1 of 8 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30311 - 1166737 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 8 ?ceAnalytical @ Workorder: 30311 CABARRUS COUNTY / 2618286 Lab ID Ki1x1`11i11i11 Report ID: 30311 - 1166737 Sample ID 1302-CD-1 S SAMPLE SUMMARY Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Matrix Date Collected Date Received Bubble Strip 5/7/2019 08:50 5/13/2019 07:30 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 3 of 8 ?ceAnalytical Workorder: 30311 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303110001 Date Received: 5/13/2019 07:30 Matrix: Bubble Strip Sample ID: 1302-CD-1S Date Collected: 5/7/2019 08:50 Parameters Results Units PQL MDL DF Analyzed By Qualifiers RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Hydrogen 2.5 nM 1.0 0.75 1 5/15/201914:26 TD n Report ID: 30311 - 1166737 Page 4 of 8 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30311 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30311 - 1166737 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 5 of 8 ?ceAnalytical QUALITY CONTROL DATA Workorder: 30311 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 QC Batch: DISG/7537 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303110001 METHOD BLANK: 61221 Blank Reporting Parameter Units Result Limit Qualifiers RISK Hydrogen nM 0.75U 0.75 n LABORATORY CONTROL SAMPLE & LCSD: 61222 61223 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Hydrogen nM 24 25 26 105 106 80-120 0.95 20 n Report ID: 30311 - 1166737 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 6 of 8 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 30311 CABARRUS COUNTY / 2618286 QUALITY CONTROL PARAMETER QUALIFIERS The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30311 - 1166737 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 7 of 8 ?ceAnalytical @ QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30311 CABARRUS COUNTY / 2618286 Lab ID Sample ID 303110001 1302-CD-1 S Report ID: 30311 - 1166737 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Prep Method Prep Batch Analysis Method Batch CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. AM20GAX DISG/7537 Page 8 of 8 0 (A M 4l 0 9M =01 IDO .0 (D (OD r (D > F- CD CA 0 �,T� 0 w --A @ - E (D M , 0 r C- ID :3 o :3 , (') — , 3 o 3 9) -Zj 0 ID (,13 (ao = V V 3 < N. 0 (D M (D (D 04 fl ai) U) m 0 M ;.7 Z, (D " :3 0 G) ir, 06 t2 6 (D > "a 0 0 0 (.0 (D N) 0 0 3 CO 0 9? -0 Ovl LrI w 0 C, Cr (D 4D 0 0 (D IT! z c cf) 04, cn CD N) 0 -4 —1. 0 C c c (D (D 0 (D 0 0 (D CD M J" HCL Unpreserved CL (D 0 (D 0 < (D Sub Dissolved Gases (Hvdroqen) (D O 0 z x A 11070 Appendix B NC Notice: This brio and am, intbr•nrarron available for hurivetion and ex Facility Name: Sampling Date: —� 5` I Sample Collector Name & Position: Gas Meter Type & Serial Number:1 �sion of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form tv a are "Public Recor dy"as• elefined rrr NC General Statrne 132.1. ; is _:tilt, the'v • rinr,isrernr are ,t Air anti' lrerson ryinn request tNC Gener al Stature 132-6) Number: / 3 `or� NC Landfill Role (.0500 or.] 600]: ►1 3 a ! T' Gas Meter Calibration Date: Field Calibration Date & Time: Field Calibration Gas Type (15/15 oi 35/50): Field Calibration Gas Canister Expiration hate: Gas Meter Pump Rate: Ambient Air Temperattire: a Barometric Pressure (in. or turn Hg): ! r 7 Weather Conditions: Instructions: Under "Location or LFG ell", list monitoring well # UT describe monitoring location (e.g., inside field offiee). Attach a test location ma or drawing. Report methane readings as both % LEL and % CI-14 by volume. Convert % CHa (by volu e) to '% LEL as follows: % methane (by volume)120 = % LEL. *Hydrogen Sulfide (H2S) gas monitoring maY he required for Construction & Demolition Landfills (CDLFs). See individual permit conditiorts andlar Facility LFG nionitnring plug. Location or LAG Well i❑ Sample Tube Purge Time of Day Time Pumpe (see) Initial % LEL Stabilized % LEL %Cti4 (volume) °j0 p2 (volume) %CQ3 (volume) %Ei2S• (volume) ?;{7T)i5 'v t r- v 0 V CIO J I o c �► L� [� � �] o C) 3.5 Q,1 f1 ec. ' 09 3o Eb dat,- /9, - - 2 ec. S Z) ` 34) 3 ; 3 9r N r7r V.: r D �•� •I f A107F if needed. anareh additional data farms to i chide additional LFG atouitoring data locations for the facility. ACTION LEVELS: Methane: >1.25% b volume (inside structures) AND ?5% by volume (at facility boundary) Hydrogen Sulfide: > % by volume (inside structures) AND >4% by volume (at facility boundary) Certification To the best of my knowledge, the are true and correct. I am aware or certification including the pus! SIGNATURE rmation reported and statements made on this data submittal and attachments there are significant penalties for making any false statement, representation, ty of a fine and imprisonment. TITLE Revised — March 6, Ia17 NC Division of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form Notice: This form and anv ru%urn arrurt atrarh ro a are "Public Recor cfs"as defined tit NC Gettrral Steatite 13 °-1. efs such. these ducirenews are ainri@rhle for inspectran and awor ra inn hr errtYlrervon iolso i request (NYC General Statute 132-6) Facility Name: Sampling Sample Collector Name & Position: Gas Meter Type & Serial Number: Field Calibration Date & Time: Permit Number: NC Landfill Rule (.0540 or.1600): Gas Meter Calibration Date: Field Calibration Gas Type (15/15 otf 35150) Field Calibration G:tsCanister Fxpiration Date: Gas Meter Pump Rate: Ambient Air Temperature: Instructions: Under "Location or LFG Attach a test location ma Convert % C1I4 (by *Hydrogen .Sulfide individual permit cc Pressure (in. or mm Hg): Weather Conditions: Veil", list monitoring well # or describe monitoring location (e.g., inside field otiicc), or drawing. Report methane readings as both % LEL and % Cl la by volume. ej to % LEL as follows: % methane (by volume)120 = % LEL. gars monitoring mat, be requiredfor Construction c& Demolition LanfUill s (CDLFs). See is and/or Facility LFG monitoring plan. Laraziun or Lrf, Well ID Sample Tube Purge Time of Day Time PuMpec isec) I Initial 9 �o LEL Stabilized % LEL % CHJ (volume) % 02 (volume.) % CO3 Ivolume) % I12S• (volume) NOTES to b arD O r 10 o ' 3 S 101 1p 19 1,3 o e IF. 0 0 13b 36 D fIrn 6),3 a 13 a 3:IS 31) ), btu% a 1 30 1,4 30 p 0 i s 50 o 6 C),4 1 D NOTE: tf needed, ariach additional data fortrrs to i�clnde additional LFG monitoring dara locations for she facility,. ACTION LEVELS: Methane: >1.25% h volume (inside structures) AND ? % by volume (at facility boundary) Hydrogen Sulfide: % by volume (inside structures) AND ?4116 by volume (at facility boundary) Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. l am aware th t there are significant penalties for malting any false statement, representation, or certification including the possi 'lity of a fine and imprisonment. SIGNATURE TITLE Revised — March 6, 2017 INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 4037 Darling Court Lilbum, GA 30047 To]] -Free: (800) 842-1088 Pine Environmental Services, Inc. Instrument ID 13898 Description Gem 2000+ Calibrated 2/21/2019 3:54:26PM Manufacturer CES Landtec State Certified Model Number GEM2000+ Status Pass Serial Number/ Lot GM 11217/08 Temp °C 21.3 Number Location Georgia Humidity % 49.0 Department Calibration . Specifications Group # l Group Name CH4 Stated Accy Pit of Reading Nom In Val I In Val In Tyne Out Val 50.0150.0 I/aVolume 50.0 ❑ut Type %Volume Range Ace % Reading Ace % PiuslMinus Fnd As 50.0 0.0000 3.0000 0.0 Lft As 50.0 Dev% 0.00% Pass/Fail Pass Group # 2 Range Ace % 0,0000 Group Name CO2 Reading Ace % 3.0000 Stated Aecy Pet of Reading Plus/Minus 0.0 Nam In Val 1 In Val In Type Out Val Out'rype Fnd As Lft As Dev% Pass/Fail 35.0135.0 %Volume 35.0 %Volume 35.0 35A 0.00% Pass Group # 3 Range Ace % 0.0000 Group Name 02 Reading Ace % 3.0000 Stated Accy Pct of Reading P1uslMinus 0.0 Nam In Val / 1n Val In Type Out Val Qut Type Fnd As Lft As Dev% Pass/Fail 4.0 / 4.0 %Volume 4.0 %Volume 4.0 4.0 0.00% Pass 20.9 / 20.9 %Volume 20.9 %Volume 20,9 20.9 0.00% Pass Group '# 4 Range Ace % 0.0000 Group Name 1-12S Reading Ace % 3.0000 Stated Accy Pet of Reading Plus/Minus 0 Nom 1n Val / In Val In Type out Val Out Tyne Fnd As Lft As Dev% Pass/Fail 25/25 PPM 25 PPM 25 25 0.00% Pass Group # 5 Range Ace % 3.0000 Group Name CO Reading Ace % 0.0000 Stated Accy Pet of Reading Range Plus/Minus 0.00 Nom In Val / In Val In Tyne Out Val out Type Fnd As Lft As Dev% Pass/Fail 50.00 / 50.00 PPM 50,00 PPM 50.00 50.00 0.00% Pass Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 900-301-9663 www.pine-environmental.com INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 4037 Farling Court Li [bum, GA 30047 Toll -free: (800) 842-1088 Pine Environmental Services, Inc. instrument I❑ 13998 Description Gem 2000+ Calibrated 2/21 /2019 3:54:26PM Test Instruments Used Durinz the Calibration (As Of Cal Entry Date) Serial Number/ Next CAI Date 1 Test Standard ID_ Description Manufacturer Model Number Lot Number Last Cal Date/ Expiration Date Opened Date GA 4% 02 GA 4% OXY Liquid UN 1956 LBH-161-4-3 l 1/2/2021 LBH-161-4-3 Technology GA 4-GAS MIX 4 GAS MIX Spec Air CAP-412- l 1 9/30/2020 GA 50/35 LOT GA 50 CH4135 Cat Liquid UN 1954 EAQ-399-3 7/ 18/2020 EAQ-399-3 Technology Notes about this calibration Calibration Result Calibration Successful Who Calibrated Angelo Pace All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the manufacturer's specifications and/or the customer's own specific needs. Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment Please call 800-301-9663 for Technical Assistance Pine Environmental Services LLC Windsor'Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663 www.pine-environmental.com NC of Waste Management - Solid Waste Section Notice: Thts,la nr rrrrd mrr- a fr�rnrarnut rry rilahle.for inspechan and ev Facility Name:4&/-A2YW Sampling Date: Sample Collector Name & Position: Gas Meter Type & Serial Number: Field Calibration Date & Time: Landfill Gas Monitoring Data Form to it are Pubhe Revords"as defined in NC Gener al Srruale 132-1. As such, there 419A rnnerua air r hi anti- person upon regnest W General Stahue 131-6t Field Calibration Gas Type (15/ 15 0� 35150): Gas Meter Pump Rate: Ambient Air Temperature: Instructions: Under "Location or LFG Attach a test location ma Convert % C114 (Ity *11ydrogen Sulfide i► diridrrallrernrit cc Number: , j —0, { Landfill Rule (,0500 or.1600): 1 Gas Meter Calibration hate: Field Calibration Gas Canister Expiration Dalc. Pressure (in. ormm I[g): �),ZWeather Conditions: 5&[11 Veil", list monitoring well # or describe monitoring location (e.g., inside field Office), or drawing. Report methane readings as both % LE and % Clia by volume, e) to %LEL as follows: % methane (by volume)1201 % LEL. gas monitoring ntat- he required for Construction R Demolition Lundlillc (0.)LI-'rj. See is atdlor Facility LFG n►oniroring plat. NMI= M'. WIMMMM MM • • • . ' ■riif�f/. ffl mmm i� • � r�o r� MFW rF M & - M'a == , �� , M =1®©® • A MM ��� • If:! III I =M© Mmm NOTE: If needed, at►urh additional do to formes to h P e hide additional LFG ninrutnr•ing data lucarons for the facilirz,. :%L'T[ON LEVELS: Methane: >1.25% by volume (inside structures) AND >_5"/ by volume (at lbolity boundary) Hydrogen Sulfide: > I % by volume (inside structures) AND Via% by volume (at facility boundary) Certification To the best of my knowledge, the are true and correct. I am aware ovewtificstion including-Oc pas! E rmation reported and statements made tin this data submittal and attachments there are significant penalties for making any faise statement, representation, ty of a fine and imprisonment. Revised - March 6, 2017 j NC 1lotice: This (i+rm a+rd u+�r irrjw a+unurr awrilahle forinspecvron and ei Facility Name: Sampling Date: 6? - y —% Sample Collector Nante & Position: Gas Meter Type & Serial Nuniber:� �sion of Waste Management - Solid Waste Section Landfill Gas Monitoring Data Form h+ it are "Public Records" as dejined no NC General Stenae !32- I As sin•h. these den-stax-jas are u hi- ❑"v person upon request WC General Smnde 13 i-6) Permit Number: 13- b NC Landfill Rule (,0500 or.16001: tA_ � � v / Gas Meter Calibralion Date: Field Calibration Date & Time: Field Calibration Gas Type (15115 oi 35154): Field Calibration Gas Canister Expiration hale: Gas Meter rump Rate: Ambient Air Temperature: Barometric Pressure (in. or min fig): Weather Conditions: Instructions: Linder "Location or LFG ell", list monitoring well N or describe monitoring location (e.g., inside field office). Attach a test location man or drawing. Report methane readings as both % LEL and % CHa by volume. Convert % C114 (bv volu e) to % LEL as follows: % methane (by vofume)120 = % LEL. *Hydrogen Su ffi'de (H2S gas ►noniloring ntrry be t-erluired for Construelion & Demolition Landfills fCDLFs1. See individual permit conditi r.s a►rdlur Facilitir LFG monitoring plan. Location or LFG Well l❑ Sample Tube Purge Time cn!• Day Time Pump (sec) Initial % LEL Stabilized %t-1.1 % L'f-1; (volume) °j° U? !volume) % CU? (volume) % 1125• (volume! tiUTl:S C> / 9 r C� { / V •r f JO v kl7. a ec_ 4_rd 1 010 0 CxXer- D o 0 o' & L) C, CSC a ,VOTE If needed, altar!+ ❑ddinonal data fnrn+s to I11alIC: cheele additional LFG ninournringdara locarionsfor thefacildi-. m-fmN LF.4 ELS: Mel�1.25% bvolume ( inside structures) AND >5% by volume (al facility boundary) Hydrogen Sulfide: % by volume (inside structures) AND tea% by volume {at facility boundaryI Certification To the best of my knowledge, the in ormation reported and statements made on this data submittal and attachments are true and correct. l am aware that there are significant penalties for making any false statement, representation, or certification incl in the possibility of a fine and imprisonment. NATUR Tf E Revised - March 6, 2017 INSTRUMENT CALIBRATION REPORT Pine Environmental Services LLC 8411 Garvey Drive, Suite 113 Raleigh, NC 27614 Toll -free: (866) 646-PINE (7463) Pine Environmental Services, Inc. Instrument ID 13898 Description Gem 2000+ Calibrated 530/2019 10:06:19AM Manufacturer CES Landlec State Certified Model Number GEM2000+ Status Pass Serial !Number/ Lot GM 11217/08 Temp °C 24 Number Location North Carolina Humidity % 57 Department Calibration Specifications Group # I Range Ace % 0.0000 Group Name CH4 Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Minus 0.0 Nam In Val 1 In Val In 'Type Out Val Out Type Fnd As 111 As Dev% Pass/Fail. 50.0 :' 50.0 %Volume 50.0 %Volume 50.4 50.0 0.00% Pass Group # 2 Range Acc % 0.0000 Group Name CO2 Reading Ace % 3.0000 Stated Accy Pet of Reading Plus/Minus 0.0 Nom In Val 1 In Val In. Type Out Val Out Type Fud As Lft As De%r% Pass/Fail 35.0 35.0 %Volume 35.0 %V0111me 35,7 35.0 0.00% Pass Group # 3 Range Ace % 0.0000 Group Name 02 Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Nlinus 0.0 Nom In Val 1 In Val In�p Out Val ❑ut Type Fnd As Lft As Dev% Pass/Fail 20.9 , 20.9 %Volume 20.9 %Volume 20.9 20.9 0.000/0 Pass Group # 4 Range Are % 0,0000 Group Name H2S Reading Ace % 3.0000 Stated Accy Pct of Reading Plus/Minus 0 Nom In Val i In Val In Type Out Val Out Type Fnd As Lit As Dev% Pass/Fail 25 215 PPM 25 PPM 32 25 0.00% Pass Group # 5 Range Ace % 3.0000 Group Name CO Reading Ace % 0.0000 Stated Accy Pet of Reading Range Plus/Minus 0.00 Nom In Val 1 In Val In Type Out Val Out Type Fnd As Lft As Dev% Pass/Fail 50.00150.00 PPM 50.00 PPVI 49.00 50.00 0A0% Pass Pine Environmental Services LLC Windsor Industrial Park, 92 North Main Street, $ldg?0, Windsor, NJ 08561, 800-301-9663 %vww.p i ne-e nvi ro nmcnta l . c om INSTRUMENT CALIBRATION REPORT Pine Environmental Services, Inc. Instrument ID 13898 Description Gem 2000-F Calibrated 5 3012019 10:06:19AM 'Zest Instruments Used During, the Calibration Test Standard ID Description Manufacturer Motel Number NC 4 GAS 20.V0 11 /20 NC 50135 MAP-399-5 1120 NC 4 GAS ?0.9% LBI-412-2 11 i9i2020 NC 50 CH4/35 CO2 Votes about this calibration Gasco 32211 Pine Environmental Services LLC 8411 Garvey Drive, Suite 113 Raleigh, NC 27614 -loll-free: (866) 646-PINE (7463) As Of Cal Entry Date Serial Number 1 Next Ca] Date Lot Number Last Cal Date/ Expiration Date Opened Date 11 /912020 Gasco GP 12 i 26 - 31803 MAP-399-5 Calibration Result Calibration Successful Who Calibrated Ryan Williamson 1 /20/2020 All instruments are calibrated by Pine Environmental Services LLC according to the manufacturer's specifications, but it is the customer's responsibility to calibrate and maintain this unit in accordance with the manufacturer's specifications and/or the customer's own specific needs. Notify Pine Environmental Services LLC of any defect within 24 hours of receipt of equipment Please call 800-301-9663 for Technical Assistance Pinc Environmental Services LLC Windsor Industrial Park, 92 North Main Street, Bldg 20, Windsor, NJ 08561, 800-301-9663 www,p ine-environmental.com