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HomeMy WebLinkAbout1302_Cabarrus_CDLF_GW_FID1323278_20190624Cabarrus County C&D Landfill Semi -Annual Sampling Report Facility Permit # 1302-CDLF-2006 (May 2019 Sampling Event) 179: /prepared June 2019 PENRUSEONLY: DPaper RePod �Eleclronic Dote-EmaiW (data loaded: Ves/No) DptlEvent#: D DENR Environmental Monitoring Division of Waste Management -Solid. Waste Repotting Form Nonce: This form and any Intortnallon atWchetl to It are'Public Records" as tleAned In NC General Statute 132-1. As such, these documents are evallable for Inspection and examination by any person upon request (NC General Statute 132-6). Instructions: • Prepare one form for each intlivitlually monitored unit. - Please type or print legibly. • Attach a notification table with values that attain cr exceetl NC 2L grountlwater stantlartls or NC 20 sudace water stantlartls. The no[iFlcetlon must inclutle a preliminary analysis of the cause antl significance of each value. (e.g. naturelly occurring, off -site source, pre-existing ponditian, etc.). • Attach enotificetlon table of any groundwater or surface water values that equal of exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any sWctures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the odglnel signed end sealed form, any tables, end Electronic Date Dellvereble to: Compliance Unit, NCDENR-DWM, Solitl Waste Section, 1646 Mall Service Center, Raleigh, NC 2]699-1646. Solid Waste Monitorinu Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner) Consultant - CDM Smith Inc. Contact for questions about tlata formatting. Inclutle tlata preparer's name, telephone number antl E-mail adtlress: Name: Mathew F. Colone Phone: (919) 325-3500 E-mail: colanemf®cdmsmith.com NC Lendflll Rule: ACWaI sampling dates (e.g., Facility name: Facility Atltlress: Facility Permit# (.O500 or.1800) October 20-24, 2006) Cabarrus County C&D Landfill C nlcordhNodh Ca ollna 2&125 2006 CDLF- .0500 May ], 2019 Environmental Status: (Check all that apply) Initial/Backgrountl Monitoring QX Detection Manitodng � Assessment Monitoring � Conective Action Tyyypppe of date submlt[etl: (Cheek ell that apply) IXI Groundwater monitoring tlata from monitoring wells � Methane gas monitoring tlata IIII—yell Grountlwaler monitoring data fmm private water supply wells � Cortective action data (speciy) Leachate monitoring tlata � Other(speci(y) Surface water monitoring tleta NOSgcallon atlached9 No. No grcuntlwater or sudace water stantlartls were exceeded. X Ves, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater end surface water monitoring points, tlates, analytical values, NC 2L grountlwater standard, NC 2B surface water standard or NC Solitl Waste GWPS and preliminary analysis of the cause and significance of any concenVagon. Ves, a notification of values exceeding an explosive methane gas limit is attached. It inGutles the methane monitoring points, tlates, sample values and explosive methane gas limits. Certification To the best of my knowledge, [he Information reportetl antl statements matle on this tlata submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding grountlwater stantlartls or explosive gas levels, antl a preliminary analysis of the cause and significance of concentrations exceeding grountlwater standards. I am aware that there are slgnigcant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Mathew F. Colone Consultant 919325-3500 Fa`� e(P' ) Title / (Area Codel Telephone Number G Zy �(y Affix NC Licer�®ed1p�b}e$sltln sGeologisl Seal Signature Da�� At,�tY{t:',5,`, C/+n 5400 Glenwood Avenue. Suite 400. Raleloh. North Carolina 2]612 S i Faulity Representative Atldress t 1��:�'�'�u 6 F-0412 br��, -� 4. NC PE Fum License Number (rf applicable egecgva May 1, 2(K5) 5�('(,:a � .�, Revised BY2009 - � //Q/��y �v��(� Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 24, 2019 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: May 2019 Semi -Annual Sampling Report Cabarrus County C&D Landfill Facility Permit No. 1302-CDLF-2006 Dear Ms. Drummond: CDM Smith Inc., on behalf of Cabarrus County, is submitting an electronic copy of the May 2019 semi- annual sampling event report for the Cabarrus County C&D Landfill. This letter report presents the results of the recently completed sampling at the C&D Landfill and constitutes the first semi-annual sampling event for 2019. The approved monitoring well network for the C&D Landfill consists of background wells CD -Is and -1d; compliance wells CD-2, -4 Rep, -7, and -9; and surface water sample location SW-3. CD-4 Rep was installed in January 2009 as part of the proposed Phase 1 C&D Landfill expansion. Monitoring well CD-7, formerly piezometer B-7, was added to the monitoring program in July 2014 as part of the Phase 2 C&D Landfill expansion. Monitoring well CD-9 was installed on March 19, 2017, as part of the Phase 3 C&D Landfill expansion. Field activities and sampling results for the groundwater and surface water samples are discussed below. Field Activities Groundwater samples from the Cabarrus County C&D Landfill were collected on May 7, 2019. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated TeflonT" bailers or a QED bladder pump system using low -flow sampling techniques. Monitoring well locations and the surface water location for the C&D Landfill are provided on Figure 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 1. Well construction details for each monitoring well are also provided in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. After depth to groundwater was measured, each well was purged prior to sampling to provide fresh formation water within the well water column. Each purge volume was measured for pH, Of WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond June 24, 2019 Page 2 conductivity, turbidity, temperature, dissolved oxygen, and oxidation-reduction potential using a YSI Pro Plus multi -parameter water quality meter and Micro TPI or TPW turbidity meters. The water quality parameters at the time of sampling are presented in Table 2. The headspace of each monitoring well was screened for methane gas using a RKI Eagle multi -gas monitor. Screening results are provided in Appendix A. Sampling Results Pace Analytical Services, Inc., located in Peachtree Corners, Georgia, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs) plus tetrahydrofuran and 1,4-dioxane, North Carolina Appendix I metals plus iron, mercury, and manganese, alkalinity, total dissolved solids (TDS), chloride, and sulfate with the exception of CD-4 Rep. Samples collected from CD-4 Rep were analyzed for North Carolina Appendix I VOCs, 1,4-dioxane, and metals. SW-3 was dry during the May 2019 sampling event. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for the C&D Landfill had detections of analytes above the MDL but below the MRL. These detections were qualified as estimated or "J" flags. The following list indicates the analytes detected above the MRL at each sampling location. No "J" flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .0202 (NC 2L) or Interim Maximum Allowable Concentration (IMAC) Standard. CD-1s (Background) General Chemistry: Metals: Volatile Organic Compounds: CD-1d (Background) General Chemistry: Metals: Volatile Organic Compounds: CD-2 General Chemistry: Metals: Volatile Organic Compounds: Alkalinity, Chloride, Nitrate, Sulfate, TDS Barium, Iron, Manganese None Detected Alkalinity, Chloride, Nitrate, TDS Barium, Iron None Detected Alkalinity, Chloride, Sulfate, TDS Barium, Iron, Manganese 1,1-Dichloroethane to Smith Ms. Jaclynne Drummond June 24, 2019 Page 3 CD-4 Rep Metals: Volatile Organic Compounds: CD-7 Barium, Cobalt, Lead, Nickel, Zinc None Detected General Chemistry: Alkalinity, Chloride, Sulfate, TDS Metals: Barium, Cobalt, Copper, Iron, Manganese, Nickel Volatile Organic Compounds: Chloroethane, cis-1,2-Dichloroethene, Methylene Chloride, Tetra chloroethene, Tetra hydrofu ran, Trichlorofluoromethane, Vinyl Chloride General Chemistry: Alkalinity, Chloride, Sulfate, TDS Metals: Barium, Iron, Manganese, Nickel Volatile Organic Compounds: 1,4-DichIorobenzene, 1,1-Dichloroethane, cis-1,2-Dichloroethene, Trichlorofluoromethane SW-3 General Chemistry: Dry Metals: Dry Volatile Organic Compounds: Dry "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Cobalt: CD-2 and -9 Vanadium: CD-1s, -1d, -2, -4 Rep, -7, and -9 A duplicate sample was analyzed for quality control. The duplicate sample, identified as Dup, was collected from CD-7. The duplicate sample had similar analyte concentrations as those detected in CD-7, with the exception of an estimated detection of cadmium in the parent sample below its NC 2L Standard. Additionally, lead and trichloroethene were detected in the duplicate sample as estimated concentrations below their respective NC 2L Standards. Metals detected above the standards are likely natural occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. Tetra chloroethene and vinyl chloride were detected in monitoring well CD-7 above their respective NC 2L Standards. These analytes have not been detected in CD-7 during previous sampling events above their MDLs, with the exception of the January 2019 sampling event. A groundwater monitoring well will be installed at the compliance boundary near CD-7 in order to determine if further assessment is needed. A complete summary of all detected constituents from the May 2019 sampling event is to Smith Ms. Jaclynne Drummond June 24, 2019 Page 4 presented in Table 3. The laboratory analytical report is provided in Appendix A. The next semi-annual sampling event will be completed in the fall of 2019. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County to Table 1 Monitoring Well Construction Summary and Groundwater Elevations May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Permit Number Monitoring Well Code Installation Date Longitude Geology of I Screened Interva DepthFacility Total (feet BTOC) Screen F Seal DiameterLatitude TOC. CD -Is Interva I 7te e al Interval Elevation d (feet TOC) Elevation 1302-CDLF-2006 8/7/2006 35.47788 80.52334 Saprolite 29.53 18.0-28.0 16.0-28.0 14.0-16.0 2.0 755.00 28.11 726.89 (background well) CD-1d 1302-CDLF-2006 7/21/2004 35.47788 80.52340 PWR 52.15 40.0-50.0 38.0-50.0 36.0-38.0 2.0 757.40 26.89 730.51 (background well) 1302-CDLF-2006 CD-2 9/12/2006 35.47698 80.52494 Saprolite 25.69 9.0-24.0 7.0-24.0 5.0-7.0 2.0 733.00 14.52 718.48 1302-CDLF-2006 CD-4 Rep 1/15/2009 35.47656 80.52210 Saprolite 19.41 6.0-16.0 4.0-16.0 2.0-4.0 2.0 739.15 10.65 728.50 1302-CDLF-2006 CD-7 11/25/2002 35.47567 80.52551 Bedrock 46.31 34.0-44.0 32.0-44.0 30.0-32.0 2.0 744.81 38.04 706.77 1302-CDLF-2006 CD-9 3/9/2017 35.47488 80.52564 PWR 51.00 36.0-51.0 34.0-51.0 32.0-36.0 2.0 748.13 41.26 706.87 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock 4. CD-4 Rep was installed as part of the proposed Phase 1 C&D Landfill expansion in November 2010. 5. CD-7 (formerly piezometer B-7) was added to the monitoring program in July 2014 as part of the Phase 2 C&D Landfill expansion. 6. CD-9 was installed as part of the Phase 3 C&D Landfill expansion in March 2017. Smith Page 1 of 1 June 2019 Table 2 Water Quality Measurements May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Water Quality Measurements Monitoring Well Code pH ConductivityTurbidity Oxygen CD-15 5.26 116 15.0 1.82 242.4 7 (background well) CD-1d 5.69 114 18.3 1.61 183.2 2 (background well) CD-2 5.67 143 16.1 2.08 106.4 2 CD-4 Rep 5.98 191 14.7 2.46 48.4 10 CD-7 5.81 397 17.1 1.92 65.4 2 CD-9 6.03 281 17.2 2.93 121.5 19 Surface Water Sample Location SW-3 DRY Notes: 1. Water quality measurements were collected on May 7, 2019. 2. CD-4 Rep was installed as part of the proposed Phase 1 C&D Landfill expansion in November 2010. 3. CD-7 (formerly piezometer B-7) was added to the monitoring program in July 2014 as part of the Phase 2 C&D Landfill expansion. 4. CD-9 was installed as part of the Phase 3 C&D Landfill expansion in March 2017. 5. µS/cm - Microsiemens per centimeter 6. mg/L - Milligrams per liter 7. ORP - Oxidation -Reduction Potential 8. NTUs - Nephelometric Turbidity Units 9. mvs - Millivolts 10. S.U. - Standard Unit Smith Page 1 of 1 June 2019 Table 3a Detected Groundwater Constituents - General Chemistry and Metals May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 CD-1s 3-May-11 47,000 3,600 1,200J 146,000 81.4J 0.19J 5.45JB 4.23J 16.0 2.32J 7,770 190 5.93J 0.14J 20.6J 26.5 CD-1s 8-Nov-11 40,000 4,000 1,1001 65,000 59.7J 0.25JB 4.46J 2.67J 12.4 1.9J 5,350 127 4.411 0.081 11.21 18.2 CD-1s 7-May-12 46,000 3,900 158,000 45.5J 3.30J 1.19J 8.75J 1.12J 3,120 63.4 3.011 12.7J 12.6E CD-1s 28-Nov-12 39,000 4,100 0 110,000 63.8J 0.11J 5.65J 3.05J 11.6 1.43J 5,210 139 4.661 17.1J 16.9 CD-1s 7-May-13 42,000 4,000 220 120,000 0.94J 2.4JB 35.6J 0.881 0.67J 4.04J 0.39J 1,340 37.7 1.781 0.13J 6.06J 5.08J CD-1s 5-Nov-13 30,000 3,900 2,420 80,500 46.8J 0.121 3.59J 1.63J 10.2 1.35J 4,200 82.2 3.50J 18.4JB 15.4E CD-1s 6-May-14 42,000 3,900 0 111,000 28.8J 4.14JB 1.48J 0.11J 347B 10.1B 1.03J 0.31J 3.40J 2.98JB CD-1s 4-Nov-14 41,000 3,900 0 102,000 28.7J 0.13J 1.31J 0.06J 118 6.6J 1.04J 0.11J 2.57JB 1.58J 1302-CDLF-2006 CD-1s 5-May-15 38,000 3,900 0 <5,000 113,000 1.63J 29.5JB 1.33J 0.15J 371 13.8 0.103JB 1.17J 2.40J 2.75JB CD-1s 27-Ott-15 43,000 30,600 3,800 0 130J 110,000 28.4J 0.801 0.39J 0.75J 0.12J 234 35.9 1.211 4.19CN,1 0.15J 4.10J 3.36E-01,J CD-1s 17-May-16 43,000 <10,000 3,700 0 79J 1,0001 130,000 23.9J 0.94J 0.99J 0.12J 446 17.0J 1.011 4.70J 1.93J CD-1s 1-Nov-16 46,000 26,500 4,200 0 67J,H-02 <5,000 71,000 30.5J 1.23J J,32J 1.36J 0.28J 647 1.351 4.30J CD-1s 9-May-17 49,000 <10,000 3,600 0 76J 1,300J 120,000 34.3J 1.17J 1.26J 0.20J 522 24.4 0.971 6.69J 1.82J CD-1s 31-Ott-17 50,000 14,600 4,200 0 66J 1,0001 161,000 0.52J 36.3J 1.81J 0.54J 2.87J 0.37J 1,270 31.2J 1.411 6.91J 4.00J CD-1s 11-Jun-18 49,000 3,890 0 82.OJ 904J (1) 28.9J 214J 8.1J 0.051J 4.3J 4.4J CD-1s 17-Dec-18 46,000 3,720 0 146 9911 119,000 26.71 0.60J 3.61 498 16.6 15.01 7.OJ 9.5J CD-1s 7-May-19 43,000 1 2,930 1 0 1 359 12,600 158,000 29.8 1 1 638 17.6 1.3J 7.OJ 5.11 CD-1d 3-May-11 57,000 2,600 3,OOOJ 206,000 2.44J 231 2.03 16.7 18.6 112 14.0 49,400 659 22.3J 0.111 101 103 CD-1d 8-Nov-11 30,000 2,900 3,OOOJ 98,000 74.5J 0.51J 4.08J 4.27J 27 2.84J 9,190 144 5.681 24.6J 26.3 CD-1d 7-May-12 50,000 2,800 150,000 72.4J 0.58J 3.91J 4.671 25 2.81J 9,380 170 5.581 26 27.9B CD-1d 28-Nov-12 46,000 3,000 0 128,000 0.33J 37.7J 0.07J 2.38J 0.94J 12.6 1.14J 1,900 41.4 2.501 8.901 13 CD-1d 7-May-13 52,000 3,000 560 125,000 0.88J 1.02JB 31.2J 0.07J 0.78J 4.5J 0.49J 1,080 25.5 1.921 6.18J 13.1 CD-1d 5-Nov-13 42,000 3,000 700 104,000 35.01 0.861 4.341 1.13J 1.90J 812 46.2 17.1J6 10.8E CD-1d 6-May-14 46,000 2,900 119,000 1.14J 37.81 0.071 0.051 3.221B 1.161 7.341 0.81J 1,610E 49.6B 2.741 0.12J 6.16J 9.411B CD-1d 4-Nov-14 43,000 3,100 0 101,000 43.11 0.161 0.111 2.251 9.091 0.87J 3,400 88.5 2.881 10.2JB 10.7 1302-CDLF-2006 CD-1d 5-May-15 44,000 2,900 0 <5000 115,000 34.51E 0.84J 3.631 0.39J 1,320 32.5 1.421 5.181 3.681B CD-1d 27-Oct-15 46,000 2,900 0 120,000 0.421 42.31 0.131 1.871 2.151 8.181 0.97J 3,170 87.4 2.491 4.37CN,1 0.06J 10.9J 14.OB-01 CD-1d 17-May-16 96,000 18,000 0 <50 14,OOO1 202,000 81.3J 0.461 4.861 7.421 26.0 3.13J 12,000 287 7.111 2.111 0.07J 29.3 29.7 CD-1d 1-Nov-16 52,000 3,400 0 <5,000 99,000 32.6J 1.191 0.771 2.821 0.33J 1,200 31.3J 1.241 7.96J 4.291 CD-1d 9-May-17 53,000 2,800 0 3,7001 167,000 33.9J 1.271 0.52J 1.811 6.92J 720 25.8J 1.091 6.95J 3.121 CD-1d 31-Oct-17 52,000 3,300 0 79J 3,3001 154,000 29.5J 0.681 0.611 0.11J 226J 11.81 0.641 5.38J 1.241 CD-1d 12-Jun-18 51,000 3,200 0 3,3301 117,000 32.4J 2.51 13.21 1.01 6.9J 3.21 CD-1d 17-Dec-18 53,000 3,110 0 3,3601 121,000 31.9J 9.31 2.31 0.41Jq18.1 3.01 6.8J 4.11 CD-1d 7-May-19 52,000 2,840 0 80.8 3,1401 134,000 30.7 1.41 9.7J 7.4J 2.91 $m ath Page 1 of 9 June 2019 Table 3a Detected Groundwater Constituents - General Chemistry and Metals May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 CD-2 3-May-11 2,850 6,800 1,300J 209,000 1.78J 55.91 0.23J 3.041B 3.62J 7.911 2.75J 5,560 92.2 0.031J 3.60J 22.2J 12B CD-2 8-Nov-11 9,000 7,500 1,400J 41,500 22.1J 0.21JB 1.41J 2.15J 3.53J 1.07J 1,660 47.4 1.91 4.99J CD-2 7-May-12 21,000 7,200 104,000 36.4J 0.19J 2.71J 3.38J 5.03J 1.94J 2,760 74.1 2.95J 9.81 16.5E CD-2 28-Nov-12 25,000 6,700 (1) 39.5J 0.13J 2.89J 2.95J 4.40J 1.42J 2,720 67.2 2.72J 10.1J 7.92J CD-2 7-May-13 20,000 7,200 80,000 0.34J 1.25JB 39.4J 0.23J 1.32J 2.8J 4.44J 1.34J 2,450 57.8 2.59J 0.08J 9.02J 8.79J CD-2 5-Nov-13 28,000 6,600 55,000 45.1J 0.20J 0.64J 3.31J 4.01J 1.60J 1,600 68.8 0.087J 2.381 14J 7.77JB CD-2 7-May-14 16,000 8,200 135,000 37.5J 0.10J 1.98JB 2.48J 2.26J 0.781B 1,130B 49.3 0.105J 2.001 5.00J CD-2 5-Nov-14 25,000 7,500 330,000 0.07J 46.0J 2.21JB 2.69J 3.59J 1.10J 2,000B 59.6 (1) 2.47J 7.21P 6.92JB CD-2 6-May-15 16,000 8,100 136,000 52.0JB 0.18J 2.10JB 2.90J 5.91J 1.37J 2240 57.6 0.158JB 3.74J 6.97J 8.02JB 1302-CDLF-2006 CD-2 27-Ott-15 7,750 7,300 5,9001 178,000 0.83J 60.0J 0.42J 3.94B-01,J 3.71J 8.71J 2.67J 5,150 83.8 0.073J 5.501 4.05CN,J 0.08J 16.3J 13.3 CD-2 18-May-16 20,000 7,900 <5,000 147,000 49.8J 0.22J 2.32J 3.41J 3.56J 1.20J 2,350 71.7 0.189J 2.681 8.34J 7.62J CD-2 1-Nov-16 20,000 8,100 <5,000 850,000H-02 64.5J 0.26J 3.10J 4.15J 5.48J 2.55J 4,010 99.5 0.056J 3.111 15.3J 13.9 CD-2 9-May-17 12,500 9,100 2,5001 125,000 54.5J 0.28J 2.40J 3.49J 3.71J 1.71J 2,550E-01 68.1 0.115J 2.801 0.05J 8.63J 7.26J CD-2 1-Nov-17 15,000 7,900 2,9001 635,000 54.0J 0.16J 1.79J 3.10J 2.78J 1.02J 1,630 62.3 0.079J 2.581 7.10J 7.22J CD-2 (dup) 1-Nov-17 16,000 7,400 1,6001 885,000 57.6J 0.17J 2.05J 3.00J 4.01J 1.08J 1,840 64.1 0.070J 2.776J 8.04J 8.191 CD-2 12-Jun-18 29,000 7,250 4,8201 88,000 58.5J 0.17J 2.2J 2.8J 2.6J 0.63J 1,280 51.6 0.12J 3.1J 6.6J 8.7J CD-2 (dup) 12-Jun-18 27,000 7,460 4,620J 91,000 56.3J 0.17J 1.91 2.6J 2.6J 0.63J 1,200 48.3 0.11J 2.8J 9.01 8.81 CD-2 18-Jan-19 40,000 10,500 18,700 107,000 27.2J 0.081J 1.4J 0.31J 300 30.6 0.15J 1.2J 4.2J CD-2 7-May-19 40,000 8,400 10,500 161,000 0.42J 41.7 0.081J 0.981 1.9J 1.3J 0.44J 782 49.7 2.2J 4.7J 5.4J CD-3 3-May-11 105,000 4,300 3,200J 404,000 48.9J 0.11J 2.36J 7.57J 1.30J 3,580 93.6 2.481 12.2J 8.64JB CD-3 8-Nov-11 85,000 5,400 3,900J 144,000 25.5J 0.65J 1.01J 178 24.9 1.481 5.16J CD-3 7-May-12 75,000 4,500 177,000 41.7J 0.84J 1.27J 3.84J 0.54J 1,170 32.6 3.371 6.18J 6.81J,B CD-3 28-Nov-12 104,000 5,100 (1) 46.7J 1.411 1.90J 4.351 0.82J 1,740 68.9 1.861 9.52J 6.931 CD-3 7-May-13 122,000 4,800 181,000 33.8J 1.201 2.351 0.42J 880 56.3 1.411 5.86J 2.891 1302-CDLF-2006 CD-3 5-Nov-13 CD-3 7-May-14 59,000 61,600 4,500 4,200 121,000 127,000 64J 28.71 0.211 0.741 1.661B 3.471 10.6 0.721 2.06J 5,170 83.28 139 4.4J 3.251 1.14J 21.2J 12.2E 2.42J CD-3 5-Nov-14 82,000 13,000 13,0001 425,000 162 0.141 1.851B 3.00J 6.22J 1.21J 3,770E 1,030 (1) 8.651 12.9J 9.941B CD-3 6-May-15 89,000 13,000 22,0001 280,000 1.38J 159 0.111 1.26J 2.84J 0.42J 1,230E 1,090 0.102JB 7.251 5.29J 5.931 CD-3 27-Oct-15 95,000 13,000 23,0001 255,000 155 0.101 1.02B-01,J 1.82J 3.91J 0.68J 2,010 936 7.721 2.60CN,1 6.03J 6.811 CD-3 18-May-16 100,000 14,000 26,0001 311,000 194 0.121 1.60J 1.35J 0.24J 607 1,010 7.881 1.191 4.02J 3.731 CD-3 1-Nov-16 95,000 14,000 27,0001 162,000 158 1 0.131 2.07J 2.771 0.49J 1,400 922 6.811 6.82J Smith Page 2 of 9 June 2019 Table 3a Detected Groundwater Constituents - General Chemistry and Metals May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 206 CD-4 Rep 3-May-11 124,000 9,700 0.9JB 17.6 0.62J 8.39J 2.72JB CDA Rep (dup) 3-May-11 0.21J 206 17.9 0.68J 8.98J 0.17J 2.85J CD-4 Rep 8-Nov-11 0.14J 191 0.93J 18.2 1.00J 8.86J 9.44J CD-4 Rep 9-May-12 184 1.69J 18.1 1.70J 0.17J 11.3J 3.03J 16.1E CDA Rep 29-Nov-12 172 13.7 0.62J 7.03J 2.84J 2.14JB CD-4 Rep 10-May-13 75.5J 0.5J 2.71J 7.87J 1.94J 0.88J 11.2J 11.11 10.3 CDA Rep 7-Nov-13 1.36J 60.4J 0.35J 0.07J 0.77J 5.31J 1.83J 0.57J 5.11J 0.13J 32 4.40JB CDA Rep 7-May-14 62.4J 0.31J 0.05J 3.25JB 5.02J 1.70J 0.32J 6.52J 22.2J 2.97JB 1302-CDLF-2006 CD-4 Rep 5-Nov-14 70.0J 0.31J 2.59J 1.46J 0.72J 4.29J 14.8JB 6.85J CD-4 Rep 6-May-15 58.41 0.391 1.131 5.94J 1.901 0.53J 4.721 14.0J 2.991 CD-4 Rep 27-Oct-15 0.79J 57.9J 0.32J 2.18J 5.86J 8.95J 1.26J 10.7J 4.14CN,J 13.9J 8.34E-01,J CD-4 Rep 18-May-16 1.09J 56.2J 0.46J 1.24J 7.31J 1.02J 0.66J 5.43J 18.01 3.70J CD-4 Rep 2-Nov-16 46.3J 0.27J 1.35J 1.59J 1.18J 0.90J 4.18J 1.11J 18.11 8.811 CD-4 Rep 9-May-17 53.8J 0.46J 0.95J 5.91J 1.72J 0.52J 4.38J 10.5J 3.73J CD-4 Rep 31-Oct-17 45.0J 0.18J 0.97J 0.82J 0.58J 0.45J 2.75J 1.88J 7.68J 2.76J CD-4 Rep 6-Jun-18 52.9J 0.41J 3.4J 0.74J 3.3J 13.3J 4.0J CD-4 Rep 19-Dec-18 1.1J 50.9J 0.96J 4.6J 5.5J 2.6J 2.9J 7.0J 1.4J 15.5J 11.6 CD-4 Rep 7-May-19 45.9 0.38J 2.3J 7.0 1.4J 1.1 5.8 6.2J 13.7 CD-7 1-Jul-14 66,000 7,600 15,000J 420,000 53.1J 0.131J 669 8.74J 4.11J 4.06J CD-7 5-Nov-14 77,000 8,500 18,000J 1,170,000 1.321 118 3.74 3.71J 40.0 13.6 21,100B 341 (1) 8.911 0.241 75.8 19.46 CD-7 6-May-15 86,000 9,800 25,000J 660,000 1.711 66.81 0.281 0.45J 4.361 0.86J 1,630E 43.4 3.361 4.14J 3.331 CD-7 27-Oct-15 81,000 11,000 28,0001 291,000 87.21 1.12 5.33E-01,J 1.52J 16.6 4.69J 6,560 145 0.1381 6.611 3.81CN,1 23.41 11.3 CD-7 18-May-16 90,000 10,000 29,0001 282,000 74.81 0.431 2.18J 0.36J 4.741 1.20J 2,160 59.4 0.1641 4.901 30.2J 4.031 1302-CDLF-2006 CD-7 1-Nov-16 100,000 13,000 34,000 413,000 82.61 0.281 1.21J 3.451 1.06J 1,200 170 5.581 4.981 CD-7 9-May-17 120,000 14,000 35,000 667,000 86.81 0.341 1.851 4.641 1.70J 1,880E-01 123 5.501 8.70J 4.131 CD-7 31-Oct-17 114,000 15,000 39,000 1,100,000 94.51 0.271 1.301 0.441 3.851 1.13J 1,300 219 6.261 8.57J 4.181 CD-7 12-Jun-18 112,000 16,900 44,3001 350,000 1.01 97.91 0.131 3.11 231J 215 7.61 6.3J 6.31 CD-7 18-Jan-19 126,000 17,600 50,400 280,000 152 0.241 2.01 12.5 7.81 178 3,930 17.51 5.11 CD-7 7-May-19 130,000 19,400 47,400 359,000 141 0.321 0.12J 0.411 5.0 6.3 64.9 2,570 13.7 1.91 7.21 CD-7 (dup) 7-May-19 129,0001 19,100 1 1 48,000 1 391,000 1 147 1 0.361 1 0.881 5.4 1 9.9 1 0.31J 1 847 4,8601 13.5 1 1 4.7J 1 8.81 CD-8 1-Jul-14 75,000 3,900 3,7001 120,000 0.256J 421 0.1911 14.4 12.6 78 6.55J 26,600 1,360 13.81 0.238J 93.3 79.6 CD-8 5-Nov-14 86,000 3,500 253,000 83.41 1.64JB 1.20J 7.151 0.59J 2,360E 131 (1) 3.341 8.18J 11.06 CD-8 6-May-15 57,000 3,300 <5000 138,000 0.361 53.816 0.48J 4.131 0.27J 1,030 58.5 0.095JB 2.431 4.03J 9.731E CD-8 27-Oct-15 72,000 3,600 1,1001 132,000 0.751 1.79J 162 0.321 0.211 5.88B-01,J 1.90J 38.6 2.29J 2,960 95.2 9.531 3.65CN,J 11.2J 1,430 1302-CDLF-2006 CD-8 (dup) 27-Oct-15 70,000 3,500 130,000 0.401 1.721 160 0.331 0.211 5.54B-01,J 1.801 36.3 2.12J 2,630 82.4 8.69J 4.20CN,1 10.61 1,310 CD-8 19-May-16 115,000 2,000 <5,000 205,000 0.49J 1.52J 133 0.201 3.54J 1.40J 28.1 1.28J 2,320 123 8.72J 13.2J 1,250 CD-8 (dup) 19-May-16 110,000 2,000 <5,000 215,000 1.27711.55J 136 0.231 0.10J 4.41J 1.63J 31.2 1.87J 3,230 129 9.76J 14.8J 1,600 CD-8 1-Nov-16 90,000 3,400 <5,000 517,000H-02 94.61 0.171 2.27J 2.52J 15.6 1.06J 3,350 433 3.96J 18.1J 244 CD-8 (dup) 1-Nov-16 80,000 3,500 2,1001 428,000H-02 96.71 1 0.211 1 3.111 2.471 18.8 1.18J 4,640 412 4.09J 22.2J 247 DWI Page 3 of 9 June 2019 Table 3a Detected Groundwater Constituents - General Chemistry and Metals May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Notes: 1. All units are in micrograms per liter (parts per billion). 2.' - Interim Maximum Allowable Concentration (IMAC) 3. NE - Standard Not Established; dup - Duplicate Sample 4. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. S. B, B-01 - The analyte concentration detected in the method blank was greater than the method detection limit. 6. CN - Detected silver concentrations were determined to be the result of contamination from the preservative acid used. 7. H-02 - Analysis was completed outside of hold time. B. CD-4 Rep was installed as part of the proposed Phase 1 C&D Landfill expansion in January 2009. Beginning November 2011 samples collected from CD-4 Rep are only analyzed for Appendix I metals. 9. Alkalinity, chloride, ferrous iron, sulfate, and total dissolved solids were added to the sampling program in May 2010. 10. (1) - Not analyzed due to laboratory oversight. 11. CD-3 was relocated on July 1, 2014, as part of the Phase 2 C&D Landfill expansion. 12. CD-7 and -B (formerly piezometers B-7 and -19) were added to the monitoring program in July 2014 as part of the Phase 2 C&D Landfill expansion. 13. CD-3 and -B were abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill Expansion. 14. CD-9 was installed on March 9, 2017, as part of the Phase 3 C&D Landfill Expansion. 15. Ferrous iron results for CD-1s and -1d are based on field testing. Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) or IMAC Standard - Indicates the result is below the detection limit or not analyzed. Smith Page 4 of 9 June 2019 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 CD-1s 3-May-11 CD -Is 8-Nov-11 CD-1s 7-May-12 CD -Is 27-Nov-12 0.4J 0.2J CD-1s 7-May-13 CD-1s 5-Nov-13 CD-1s 6-May-14 CD-1s 4-Nov-14 1302-CDLF-2006 CD-1s 5-May-15 CD-1s 27-Oct-15 CD-1s 17-May-16 CD-1s 1-Nov-16 CD-1s 9-May-17 CD-1s 31-Oct-17 CD-1s 11-Jun-18 CD-1s 17-Dec-18 1.2 CD-1s 7-May-19 CD-1d 3-May-11 CD-1d 8-Nov-11 CD-ld 7-May-12 CD -id 27-Nov-12 CD-ld 7-May-13 CD -id 5-Nov-13 CD-1d 6-May-14 CD -id 4-Nov-14 1302-CDLF-2006 CD-ld 5-May-15 CD-1d 27-Oct-15 CD -id 17-May-16 CD-ld 1-Nov-16 CD -id 9-May-17 CD-1d 31-Oct-17 CD -id 12-Jun-18 CD-ld 17-Dec-18 CD -id I 7-May-19 CD-2 3-May-11 CD-2 8-Nov-11 CD-2 7-May-12 CD-2 27-Nov-12 0.4J CD-2 7-May-13 CD-2 5-Nov-13 CD-2 6-May-14 CD-2 4-Nov-14 CD-2 7-May-15 1302-CDLF-2006 CD-2 27-Oct-15 CD-2 17-May-16 CD-2 1-Nov-16 CD-2 9-May-17 CD-2 1-Nov-17 0.5J CD-2 (dup) 1-Nov-17 0.5J CD-2 12-Jun-18 1.6J CD-2 (dup) 12-Jun-18 1.6J CD-2 18-Jan-19 0.57J 0.76J CD-2 I 7-May-19 1 3.5 Smith Page 5 of 9 June 2019 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 CD-3 3-May-11 CD-3 8-Nov-11 16J CD-3 7-May-12 CD-3 27-Nov-12 0.41 CD-3 7-May-13 1302-CDLF-2006 CD-3 5-Nov-13 CD-3 6-May-14 CD-3 4-Nov-14 CD-3 6-May-15 2.4 CD-3 27-Oct-15 1.6 CD-3 17-May-16 2.1 0.61 CD-3 1-Nov-16 5.9 0.6J CD-4 Rep 3-May-11 CD-4 Rep (dup) 3-May-11 CD-4 Rep 8-Nov-11 CD-4 Rep 8-May-12 CD-4 Rep 28-Nov-12 0.3J CD-4 Rep 9-May-13 CD-4 Rep 7-Nov-13 0.61 CD-4 Rep 6-May-14 1302-CDLF-2006 CD-4 Rep 4-Nov-14 CD-4 Rep 6-May-15 CD-4 Rep 27-Oct-15 CD-4 Rep 17-May-16 CD-4 Rep 2-Nov-16 CD-4 Rep 10-May-17 CD-4 Rep 31-Oct-17 CD-4 Rep 6-Jun-18 1.2 CD-4 Rep 19-Dec-18 CD-4 Rep 7-May-19 CD-7 (B-7) 22-Mar-12 CD-7 (B-7) 3-May-12 0.65J 0.671 CD-7 1-Jul-14 CD-7 4-Nov-14 CD-7 6-May-15 0.4.1 CD-7 27-Oct-15 0.41 0.51 1302-CDLF-2006 CD-7 17-May-16 0.7J 1.0.1 1.9 CD-7 1-Nov-16 1.21 1.7J 5.8 CD-7 9-May-17 1.0.1 1.4.1 3.5 CD-7 31-Oct-17 0.91 1.01 7.1 CD-7 12-Jun-18 1.3 7.1 0.901 CD-7 18-Jan-19 0.71J 1.9 2.3 25.0 1.0.1 7.1 1.2 CD-7 7-May-19 0.91.1 1.2 0.56.1 1.8 1.1 1.5 27.3 5.7 1.9 CD-7 (dup) 1 7-May-19 I 0.92J I 1 1 1.4 1 1 1 0.62J 1 1 1.9 1 1.1 1 1.5 1 24.5 1 1 0.37.1 1 6.0 1 2.0 Smith Page 6 of 9 June 2019 Table 3b Detected Groundwater Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Notes: 1. All units are in micrograms per liter (parts per billion). 2. dup - Duplicate Sample 3. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 4. B - The analyte concentration detected in the method blank was greater than the method detection limit. 5. NE - Standard Not Established 6. CD-4 Rep was installed as part of the proposed Phase 1 C&D Landfill expansion in January 2009. 7. CD-3 was relocated on July 1, 2014, as part of the Phase 2 C&D Landfill expansion. 8. CD-7 and -8 (formerly piezometers B-7 and -19) were added to the monitoring program in July 2014 as part of the Phase 2 C&D Landfill expansion. 9. CD-3 and -8 were abandoned on February 2, 2017, as part of the Phase 3 C&D Landfill Expansion. 10. CD-9 was installed on March 9, 2017, as part of the Phase 3 C&D Landfill Expansion. Concentration exceeds the 15A NCAC 02L .0202 (North Carolina 2L) Standard. Indicates the result is below the detection limit. Smith Page 7 of 9 June 2019 Table 3c Detected Surface Water Constituents - Metals and General Chemistry May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Notes: 1. Metal concentrations are in micrograms per liter (parts per billion). 2. General chemistry concentrations are in milligrams per liter (parts per million). 3. Standards obtained from section 15A NCAC 02B .0211 (North Carolina 213) or Protective Value Surface Water Standards for Class C Waters (September 2017). 4. (4) - A Standard for total chromium has not been established. The value provided is for chromium (III). 5. * - North Carolina Protective Value 6. NS - No Standard 7. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. 8. B, B-01- The analyte concentration detected in the method blank was greater than the method detection limit. 9. H-02 - Total dissolved solids analysis was analyzed outside of hold time for SW-3. Concentration exceeds the North Carolina 2B or Protective Value Freshwater Aquatic Life Standard for Class C Waters Indicates the result is below the detection limit. Smith Page 8 of 9 June 2019 Table 3d Detected Surface Water Constituents - Volatile Organic Compounds May 2019 Semi -Annual Sampling Event Cabarrus County C&D Landfill Facility Permit Number 1302-CDLF-2006 Facility Permit Number Surface Water Code 2B or Protective Life Standard Sample Date Value GJ C c a c ^ 41 N to 0 °; 3 c Q m C? -0 N L U 2,000* NS 26,000* 100* v C c v i0 L C C 7 X c a. C N M -o o x ^' s c v v s x s ;° r-I' W N 41 ++ � H NS 97* NS 26,000* 110,000* 11 North Carolina Freshwater Aquatic 1 11. Notes: 1. Volatile organic compound concentrations are in micrograms per liter (parts per billion). 2. Standards obtained from section 15A NCAC 02B .0211 (North Carolina 26) or Protective Value Surface Water Standards for Class C Waters (September 2017). 3. * - North Carolina Protective Value 4. NS - No Standard 5. J - Indicates the analytical result is an estimated concentration between the method detection limit and the adjusted reporting limit. - Concentration exceeds the North Carolina 2B or Protective Value Freshwater Aquatic Life Standard for Class C Waters - Indicates the result is below the detection limit. DM Page 9 of 9 June 2019 n I n I n I n I WE I n I n I n GW 0. 1� Z� / ITC-15 � /%1 � \ M-1 GW 726.89y xI EXIS"ING \ P ��0 &D, LANDFALL COVER MATERIAL m,PH ES I AND II STOCKPILE o S CTIVE) P-2 0 ERMIT 1-, 2 CDLF-2008 _8 MW�s IN > ° r $CD1 ABANDON9° CD-3 AB D ' A. .-7 $ , BAB�ND I D NED SEDIMENTATION POND4ZO ...� LAN FI'F`L PA SI ,., 200 0 400 MOW-13 ° \ 7 I ABA DON �� I ' ,,,., >_ °'°'° w, °• _ IRISH POTATO R AD ANDF L APPROX LIMI E EXPANSION ' P ROXq=WASTE B U R OLD FILL 'A / CATEGORY 2 II a UNIT 1 / ,x CLOSURE A E MS 41DFILL' UNIT 2 (INACTIVE/ CDLF OVER PE MIT 1302-MSWLF-19 NAnIV o c PE IT 2- S SRM1T 02-C L 1 9 MW J 1 2 GW 700.851 8i► GW 12 CMG W GW N _ � 8 x X ° $9.4 NM x ,.,.z 0 I 93.51 i ; W MW A B-4 � ° ri MW-7 GW 707 3 / � h6W G o MW-5 G1111681.10 LEGEND I 69 .17 ORR nn I '69 - -� ■M-1 MONITORING WELL \\ > w PROJE TE BO DA Y - ( "I d' / • �P-1 \\ i E 8 OF P, T 6 ° \ / OCT OB 9 9 3 M METHANE PROBE MW-5 MONITORING WELL WITH GROUNDWATER ELEVATIONS U MGW 679. 2. 7 ORROW AR Sv MSED) n AL I \ 9�t (INACTIVE ' / OMW-6 ABANDONED GROUNDWATER MONITORING WELL I PERMIT 1302- r n I / ) SW-1 SURFACE WATER SAMPLING STATION PERMIT 1392-CDL 9987 I SW'1 / / -�- - -� ---- ��/ MGW-3 1 m (713) ESTIMATED ELEVATION OF WATER TABLE \ / ----- ,•,, -0 0P-1 PIEZOMETER - �- POTENTIOMETRIC CONTOUR m- O 2.9 8 _ 7, � r _ /' _ MGW-1 METHANE GAS MONITORING WELL GW ¢ 8.28 MW M DEEP GW 67 . 7_ M -I D 667 47 AMW-1 S AMW-1 IIII' NOTE: D GW 679.25 : ,e 679.12 -SW-2 \, a) - 1. MW-A THROUGH M, ALONG WITH MW-1-3 AND M-3 DEEP COMPRISE THE GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED MONITORING SYSTEM. CD-4, CD-5, AND CD-6 WERE ADDED TO THE GROUNDWATER MONTORING NETWORK IN SEPTEMBER 2006. 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. 3. MW-517, 8A, 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS FOR UNIT 1. CD-iS AND CD-iD SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND • ° M HD P AMyy_2s yy 6Z,5,5r� ° °°°' °0 ° AMW-2D n' ° ;n, THE C&D LANDFILL. W 67 32 :,;, j 'ate 0 4. CD S, CD-i D, CD-2, AND CD-3 ARE THE APPROVED MONITORING WELLS FOR THE C&D LANDFILL AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. e '- _a° W-L DEEP -M� 5. GROUNDWATER ELEVATIONS MEASURED ON MAY 6, 2019. \\\ G Iv56.47 I M DEEP ! "� ry• y, 6. ASSESSMENT WELLS AMW-i S, -lD, -2S, AND -2D WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN OCTOBER 2009. 6 _60. 7 \ J ,� \ 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. 60 6 \ 8. MW-9 WAS REMOVED FROM THE MONITORING PROGRAM. mw-m \ 9. CD-7 AND CD-8, FORMERLY PIEZOMETERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE - MONITORING PROGRAM IN JULY 2014. 6 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY : J. KIUINcswoRTH SHEET CHK'D BY: D. FORBEs CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES DATE_ JUNE 2019 CDM. ��'�� GDM GI.-.e. Av MOO Glerrxootl e, Suite 490 INGF-h,NC2]812Te1:(919)32535900.12 NCR- CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 POTENTIOMETRIC SURFACE MAP PROJECT NO. 1278-231402 FILE NAME: CAB-S-I9.DWG FIGURE N0. DATE DRWREV N CHKD REMARKS Appendix A *A ■J nnsa enaaannce MARY nmw% A%.&nnn n MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitoring Site: Cabarrus Co. Landfill - Units 2 & 3 Report No.: 2618294 Sampling Date: 05/06/19-05/10/19 Well ID BOC' I DTW Well V013 Purge V014 pHs I SC9 Temp' Turbe DO9 ORP10 Comments 1302-CD-1 D 52.32 26.89 - 24.20 5.67 114 18.3 9.14 1.61 183.2 Clear, no odor 1302-CD-1 S 29.91 28.11 - 11.201- 5.26 116 15.0 7.13 1.82 242.4 Clear, no odor 1302-CD4 Rep 19.08 10.65 4.25 4.25G 5.98 191 14.7 9.87 2.46 48.4 No odor 1302-MW-1 30.51 11.88 9.11 9.25G 6.51 140 15.9 5.47 1.52 22.4 No odor 1302-MW-3 35.49 11.90 - 7.001- 5.47 170 15.2 5.50 1.81 114.5 No odor Fe2+ =0.5 1302-MW-3 Deep 94.74 7.63 - 5.001- 6.98 343 16.0 8.00 1.76 17.9 Clear, odor 1302-MW-A 50.36 39.57 - 9.201- 5.27 449 13.7 1.79 1.91 76.7 Clear, odor Fe2+ =3.5 1302-MW-B 15.48 2.46 6.36 6.50G 6.67 784 16.0 5.23 1.05 -64.5 Cloudy, slight odor 1320-MW-C 17.93 12.04 2.88 3.00G 5.74 98 15.0 3.22 1.37 104.3 Cloudy, odor 1302-MW-D 30.60 22.76 3.83 4.00G 5.92 620 13.8 3.14 1.93 36.4 Cloudy, no odor 1302-MW-E R 41.89 24.30 - 6.801- 6.05 984 17.3 2.25 1.68 -1.9 Clear, odor Fe2+ =4.25 1302-MW-E DEEP 59.94 27.73 - 8.201- 6.29 1123 16.4 8.83 1.88 -30.9 Odor Fe1+ =6.0 1302-MW-F 20.32 8.09 5.98 6.00G 6.57 478 14.3 4.78 1.55 -69.4 No odor .■ __ ` ■A1 ■� ■ At a on 191 f+ �T'� � � it .• ■ � � � _■ m W !2 dO M160r INN iL = I Elm ■i ii i it ■r EL or ■r 1&..: ■i i mm�_. ■ ' w a` + ` �. ■ ■ r %mow= mmm6z a a or—� 0 --*a pal �l Y, 6 EMEMEMENIF MMMU --"H MhMM-m 'Li k-Kim i A&6031' it � *., dWJL%i& 7.4150p, 1.1 A"A UL mot". MI& Am wpm* ■ a d ■ I J *JOLIW. W, A MM*,x mmVA —va O r 39 aceAna/ytica/ FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp Dressser and Mckee Inc. Casing Diameter: ;Z Site Name: Cabarrus County Landfill C4-'3% Casing Material: UC Field Personnel: W. Flammer J. Mueller Dedicated Pump: �c7 Well ID - C. 9 Method of Well Evacuation: er Date: It Method of Sample Collection: Weather Conditions: Qw-r ktsea qe<ta Depth to Ground Water in feet (DGW) = ! k �,'� (o Sample Date and Time: 7 ICt ) 3 Total Well Depth in feet (TWD) Me�aA (,,fQ6A - 5-gis ' 0900 e A : X9 PS Q ell - 1 Uv ai Ilo,4 6x 0 = 3 D ILL 00 CHARGE jEnWater Total Volume of Water Removed (biter$) u� oot C� Level: Time (military) 1 -11 �-a"\ 1 a-3 S \ Li 3 Volume Purged (Liters) 0 5 .00 -1,00 Water Level (ft.) stable — r _ pH (s.u.) t.z , a �( Cx-1 ,(�3 Sp. Cond. (µmhos/cm) t to % 303,5 Water Temp. (°C) cons=t \-I • is R . o Turbidity (NTU) tlo%m<staro ko �00t Dissolved Oxygen (mg/L) tlo 2. 2 3 2. 93 O.R.P. (mV) tlomv COMMENTS/OBSERVATIONS: 0 Date: S� (� By:(j XAZ tPage --I— of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: �k Site Name: Cabarrus County Sanit Landfill UnitsnO Casing Material: N(C Field Personnel: ��•V�l�vlet'. Dedicated Pump: k) Surface Water ID #: \30), C, _y Date: S �4 Weather Conditions: S It" #A Method of Well Evacuation: ViA p-d' Total Well Depth in feet (TWD) _ \ Method of Sample Collection: e(- Depth to Ground Water in feet (DGW) Well Yield (subjective): 6 Length of Water Column (LWC) = TWD - DGW Sample Date and Time:. 7 10;5' 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = \ , 3- 1.S g k j4 ,3 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = —� TU — �(, 9 Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gallons): Lk. Time (military) ' It 1 iV t% ' o 4 10 a Volume Purged (Gallons) 0 Water Level (ft.) stable — -- -- pH (s.u.) = 2 03 CA Sp. Cond. (µmhos/cm) = io % ?S� 1 rl,h l�\, 3 m . k Water Temp. (°C) constant �A.Cf K• Turbidity(NTU) *10%or-5NnJ g -r Dissolved Oxygen (mg/L) tto^i I �k RedOx Potential/ORP (mV) tio.v �3, �3 Li 3 A COMMENTS/OBSERVATIONS: (� �UPtNO 06 06 G l Dater (l By. C • Page of aceAnalytical A FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Carnp Dressser and Mckee Inc. Casing Diameter: NA Site Name: Cabarrus County Landfill Casing Material: NA Field Personnel: W. Flammer J. Mueller Dedicated Pump: NA Well ID #: C&D SW-3 Method of Well Evacuation: NA Date: S .4\, Method of Sample Collection: NA Weather Conditions: Depth to Ground Water in feet (DGW) = NA Sample Date and Time: Total Well Depth in feet (TWD) = NA PSI NA Purge Rate (mLm) NA REFILL NA DISCHARGE NA Total Volume of Water Removed (Liters): NA jEnd Water Level: NA Time (military) Volume Purged (Liters) 0 Water Level (ft.) ale pH (s.u.) t 2 Sp. Cond. (µmhos/cm) t io Water Temp. ('C) con=nt o i or5NW Turbidity (NTU) d< Dissolved Oxygen (mg/L) do O.R.P. (mV) t10mv COMMENTS/OBSERVATIONS: Sw S r r o 1Nc t �►o cv., , v n. rL� — ��' S �" " Date: 5 r1 B / Page � of 1 aceAna1yAcal www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 04, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County CD-1 s and CD1 d Pace Project No.: 2618286 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory between May 08, 2019 and May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Matrix Date Collected Date Received 2618286001 1302-CD-1S Water 05/07/19 09:06 05/08/19 10:00 2618286002 1302-CD-1D Water 05/07/1912:05 05/08/1910:00 2618427010 1302-CD-1S Water 05/07/19 08:50 05/10/19 09:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618286001 1302-CD-1S EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618286002 1302-CD-1D EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.26 Std. Units 1 Field Temperature 15.0 deg C 1 Field Specific Conductance 116 umhos/cm 1 Field Turbidity 7.13 NTU 1 Field Oxidation Potential 242.4 mV 1 Oxygen, Dissolved 1.82 mg/L 1 Depth to Water 28.11 feet 1 Iron, Ferrous 0.0 mg/L 1 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) Date: 06/04/2019 02:17 PM ND ug/L 5.0 1 ND ug/L 5.0 1 29.8 ug/L 5.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 638 ug/L 40.0 1 ND ug/L 1.0 1 17.6 ug/L 10.0 1 1.3J ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 1.0 1 7.OJ ug/L 10.0 1 5.11 uq/L 10.0 1 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 7782-44-7 N2 05/23/19 13:38 05/23/19 13:38 05/13/1918:04 05/14/1916:38 7440-36-0 05/13/1918:04 05/14/1916:38 7440-38-2 05/13/1918:04 05/14/1916:38 7440-39-3 05/13/1918:04 05/14/1916:38 7440-41-7 05/13/1918:04 05/14/1916:38 7440-43-9 05/13/1918:04 05/14/1916:38 7440-47-3 05/13/1918:04 05/14/1916:38 7440-48-4 05/13/1918:04 05/14/1916:38 7440-50-8 05/13/1918:04 05/14/1916:38 7439-89-6 05/13/1918:04 05/14/1916:38 7439-92-1 05/13/1918:04 05/14/1916:38 7439-96-5 05/13/1918:04 05/14/1916:38 7440-02-0 05/13/1918:04 05/14/1916:38 7782-49-2 05/13/1918:04 05/14/1916:38 7440-22-4 05/13/1918:04 05/14/1916:38 7440-28-0 05/13/1918:04 05/14/1916:38 7440-62-2 05/13/1918:04 05/14/1916:38 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:02 7439-97-6 Analytical Method: EPA 8260D ND ug/L 1.0 1 05/15/1917:05 630-20-6 ND ug/L 1.0 1 05/15/1917:05 71-55-6 ND ug/L 1.0 1 05/15/1917:05 79-34-5 ND ug/L 1.0 1 05/15/1917:05 79-00-5 ND ug/L 1.0 1 05/15/1917:05 75-34-3 ND ug/L 1.0 1 05/15/1917:05 75-35-4 ND ug/L 1.0 1 05/15/1917:05 96-18-4 ND ug/L 2.0 1 05/15/1917:05 96-12-8 ND ug/L 2.0 1 05/15/1917:05 106-93-4 ND ug/L 1.0 1 05/15/1917:05 95-50-1 ND ug/L 1.0 1 05/15/1917:05 107-06-2 ND ug/L 1.0 1 05/15/1917:05 78-87-5 ND ug/L 1.0 1 05/15/1917:05 106-46-7 ND ug/L 5.0 1 05/15/1917:05 78-93-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 2-Hexanone ND ug/L 5.0 1 05/15/19 17:05 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:05 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:05 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:05 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:05 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:05 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:05 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:05 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:05 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:05 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:05 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:05 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:05 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:05 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:05 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:05 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:05 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:05 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:05 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:05 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:05 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:05 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:05 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:05 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:05 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:05 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:05 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:05 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:05 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 05/15/19 17:05 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:05 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/17/19 20:27 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 104 % 50-150 1 05/17/19 20:27 17060-07-0 Toluene-d8 (S) 122 % 50-150 1 05/17/19 20:27 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 43000 ug/L 20000 1 05/09/19 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 158000 ug/L 10000 1 05/14/19 19:16 D6 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 11:30 05/13/19 15:51 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1914:25 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/08/19 13:00 05/13/19 13:10 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 359 ug/L 50.0 1 05/09/19 13:23 14797-55-8 H1 9056 IC Anions Analytical Method: EPA 9056A Chloride 2930 ug/L 1000 1 05/23/19 04:21 16887-00-6 Sulfate 12600 ug/L 5000 1 05/23/19 04:21 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.69 Std. Units 1 05/23/19 13:38 Field Temperature 18.3 deg C 1 05/23/19 13:38 Field Specific Conductance 114 umhos/cm 1 05/23/19 13:38 Field Turbidity 9.14 NTU 1 05/23/19 13:38 Field Oxidation Potential 183.2 mV 1 05/23/19 13:38 Oxygen, Dissolved 1.61 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 26.89 feet 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-36-0 Arsenic ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-38-2 Barium 30.7 ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-39-3 Beryllium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-43-9 Chromium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-47-3 Cobalt ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-48-4 Copper 1.4J ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-50-8 Iron 517 ug/L 40.0 1 05/13/1918:04 05/14/1916:43 7439-89-6 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7439-92-1 Manganese 9.7J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7439-96-5 Nickel ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7440-28-0 Vanadium 7AJ ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-62-2 Zinc 2.9J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:04 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 17:31 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 17:31 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 17:31 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 17:31 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 17:31 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 17:31 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:31 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:31 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:31 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:31 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:31 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:31 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:31 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:31 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:31 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:31 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:31 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:31 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:31 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:31 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:31 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:31 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:31 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:31 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:31 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:31 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:31 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:31 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:31 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:31 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:31 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:31 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:31 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:31 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:31 1868-53-7 4-Bromofluorobenzene (S) 95 %. 82-120 1 05/15/19 17:31 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/19/19 11:24 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 128 % 50-150 1 05/19/19 11:24 17060-07-0 Toluene-d8 (S) 115 % 50-150 1 05/19/19 11:24 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 52000 ug/L 20000 1 05/09/19 15:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 134000 ug/L 10000 1 05/14/19 19:16 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 80.8 ug/L 50.0 1 05/09/19 11:55 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 2840 ug/L 1000 1 05/30/19 07:20 16887-00-6 Sulfate 3140J ug/L 5000 1 05/30/19 07:20 14808-79-8 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28287 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127417 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/13/1919:46 LABORATORY CONTROL SAMPLE: 127418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127419 127420 MS MSD 2618405004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.2 2.2 88 87 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28295 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127445 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L ND 5.0 05/14/1915:22 Arsenic ug/L ND 5.0 05/14/1915:22 Barium ug/L ND 5.0 05/14/1915:22 Beryllium ug/L ND 0.50 05/14/1915:22 Cadmium ug/L ND 0.50 05/14/1915:22 Chromium ug/L ND 5.0 05/14/1915:22 Cobalt ug/L ND 5.0 05/14/1915:22 Copper ug/L ND 5.0 05/14/1915:22 Iron ug/L ND 40.0 05/14/1915:22 Lead ug/L ND 1.0 05/14/1915:22 Manganese ug/L ND 10.0 05/14/1915:22 Nickel ug/L ND 5.0 05/14/1915:22 Selenium ug/L ND 5.0 05/14/1915:22 Silver ug/L ND 5.0 05/14/1915:22 Thallium ug/L ND 1.0 05/14/1915:22 Vanadium ug/L ND 10.0 05/14/1915:22 Zinc ug/L ND 10.0 05/14/1915:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 127446 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 96.7 97 80-120 Arsenic ug/L 100 97.1 97 80-120 Barium ug/L 100 95.6 96 80-120 Beryllium ug/L 100 99.5 99 80-120 Cadmium ug/L 100 97.0 97 80-120 Chromium ug/L 100 98.1 98 80-120 Cobalt ug/L 100 98.9 99 80-120 Copper ug/L 100 99.2 99 80-120 Iron ug/L 1000 988 99 80-120 Lead ug/L 100 95.9 96 80-120 Manganese ug/L 100 101 101 80-120 Nickel ug/L 100 97.5 98 80-120 Selenium ug/L 100 98.8 99 80-120 Silver ug/L 100 99.0 99 80-120 Thallium ug/L 100 95.8 96 80-120 Vanadium ug/L 100 99.9 100 80-120 Zinc ug/L 100 102 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127447 127448 MS MSD 2618227008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.0 93.7 98 94 75-125 5 20 Arsenic ug/L ND 100 100 92.7 92.9 93 93 75-125 0 20 Barium ug/L 37.6 100 100 131 127 93 89 75-125 3 20 Beryllium ug/L ND 100 100 104 101 103 101 75-125 3 20 Cadmium ug/L ND 100 100 95.7 94.7 96 95 75-125 1 20 Chromium ug/L ND 100 100 98.9 98.4 98 98 75-125 1 20 Cobalt ug/L ND 100 100 98.0 97.3 98 97 75-125 1 20 Copper ug/L ND 100 100 98.0 101 97 100 75-125 3 20 Iron ug/L 517 1000 1000 1010 1900 49 139 75-125 61 20 M1,R1 Lead ug/L ND 100 100 94.0 91.4 94 91 75-125 3 20 Manganese ug/L 80.7 100 100 180 187 99 107 75-125 4 20 Nickel ug/L ND 100 100 97.6 95.5 97 95 75-125 2 20 Selenium ug/L ND 100 100 95.7 95.1 96 95 75-125 1 20 Silver ug/L ND 100 100 101 98.1 101 98 75-125 3 20 Thallium ug/L ND 100 100 94.2 91.9 94 92 75-125 2 20 Vanadium ug/L ND 100 100 100 98.8 99 98 75-125 2 20 Zinc ug/L ND 100 100 102 103 98 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28431 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127981 Associated Lab Samples: 2618286001, 2618286002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,1-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethene ug/L ND 1.0 05/15/19 11:28 1,2,3-Trichloropropane ug/L ND 1.0 05/15/19 11:28 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/15/19 11:28 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/15/19 11:28 1,2-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 1,2-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,2-Dichloropropane ug/L ND 1.0 05/15/19 11:28 1,4-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 2-Butanone (MEK) ug/L ND 5.0 05/15/19 11:28 2-Hexanone ug/L ND 5.0 05/15/19 11:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/15/19 11:28 Acetone ug/L ND 25.0 05/15/19 11:28 Acrylonitrile ug/L ND 50.0 05/15/19 11:28 Benzene ug/L ND 1.0 05/15/19 11:28 Bromochloromethane ug/L ND 1.0 05/15/19 11:28 Bromodichloromethane ug/L ND 1.0 05/15/19 11:28 Bromoform ug/L ND 1.0 05/15/19 11:28 Bromomethane ug/L ND 2.0 05/15/19 11:28 Carbon disulfide ug/L ND 10.0 05/15/19 11:28 Carbon tetrachloride ug/L ND 1.0 05/15/19 11:28 Chlorobenzene ug/L ND 1.0 05/15/19 11:28 Chloroethane ug/L ND 1.0 05/15/19 11:28 Chloroform ug/L ND 1.0 05/15/19 11:28 Chloromethane ug/L ND 1.0 05/15/19 11:28 cis-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 cis-1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Dibromochloromethane ug/L ND 1.0 05/15/19 11:28 Dibromomethane ug/L ND 1.0 05/15/19 11:28 Ethylbenzene ug/L ND 1.0 05/15/19 11:28 lodomethane ug/L ND 10.0 05/15/19 11:28 Methylene Chloride ug/L ND 1.0 05/15/19 11:28 Styrene ug/L ND 1.0 05/15/19 11:28 Tetrachloroethene ug/L ND 1.0 05/15/19 11:28 Tetrahydrofuran ug/L ND 10.0 05/15/19 11:28 Toluene ug/L ND 1.0 05/15/19 11:28 trans-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 V1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 METHOD BLANK: 127981 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Trichloroethene ug/L ND 1.0 05/15/19 11:28 Trichlorofluoromethane ug/L ND 1.0 05/15/19 11:28 Vinyl acetate ug/L ND 2.0 05/15/19 11:28 Vinyl chloride ug/L ND 1.0 05/15/19 11:28 Xylene (Total) ug/L ND 2.0 05/15/19 11:28 1,2-Dichloroethane-d4 (S) %. 93 81-119 05/15/19 11:28 4-Bromofluorobenzene (S) %. 96 82-120 05/15/19 11:28 Dibromofluoromethane (S) %. 98 82-114 05/15/19 11:28 Toluene-d8 (S) %. 100 82-109 05/15/19 11:28 LABORATORY CONTROL SAMPLE: 127982 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.3 113 68-137 1,1,1-Trichloroethane ug/L 50 57.8 116 72-134 1,1,2,2-Tetrachloroethane ug/L 50 59.1 118 51-158 1,1,2-Trichloroethane ug/L 50 57.5 115 78-131 1,1-Dichloroethane ug/L 50 60.8 122 69-151 1,1-Dichloroethene ug/L 50 63.8 128 64-158 1,2,3-Trichloropropane ug/L 50 45.1 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 48.6 97 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.5 113 71-134 1,2-Dichlorobenzene ug/L 50 54.9 110 70-135 1,2-Dichloroethane ug/L 50 54.2 108 72-129 1,2-Dichloropropane ug/L 50 60.3 121 64-135 1,4-Dichlorobenzene ug/L 50 52.8 106 70-131 2-Butanone (MEK) ug/L 100 101 101 52-143 2-Hexanone ug/L 100 87.1 87 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 71-129 Acetone ug/L 100 88.7 89 48-224 Acrylonitrile ug/L 200 205 103 66-154 Benzene ug/L 50 57.5 115 68-132 Bromochloromethane ug/L 50 58.6 117 73-133 Bromodichloromethane ug/L 50 56.8 114 67-121 Bromoform ug/L 50 56.6 113 57-125 Bromomethane ug/L 50 48.0 96 35-156 Carbon disulfide ug/L 100 103 103 47-141 Carbon tetrachloride ug/L 50 64.4 129 66-122 L1,v1 Chlorobenzene ug/L 50 56.6 113 71-126 Chloroethane ug/L 50 47.3 95 43-143 Chloroform ug/L 50 51.3 103 71-136 Chloromethane ug/L 50 53.0 106 47-123 cis-1,2-Dichloroethene ug/L 50 61.1 122 74-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 LABORATORY CONTROL SAMPLE: Parameter 127982 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.9 116 78-120 Dibromochloromethane ug/L 50 56.4 113 65-115 Dibromomethane ug/L 50 62.9 126 79-129 Ethylbenzene ug/L 50 58.5 117 68-129 lodomethane ug/L 100 97.3 97 49-154 Methylene Chloride ug/L 50 56.8 114 61-147 Styrene ug/L 50 61.4 123 77-128 Tetrachloroethene ug/L 50 53.1 106 51-139 Tetrahydrofuran ug/L 100 101 101 56-147 Toluene ug/L 50 54.7 109 60-133 trans-1,2-Dichloroethene ug/L 50 63.4 127 69-144 trans- 1,3-Dichloropropene ug/L 50 50.0 100 74-128 Trichloroethene ug/L 50 54.2 108 73-126 Trichlorofluoromethane ug/L 50 59.1 118 55-132 Vinyl acetate ug/L 50 54.2 108 52-141 Vinyl chloride ug/L 50 51.5 103 50-133 Xylene (Total) ug/L 150 181 121 78-132 1,2-Dichloroethane-d4 (S) %. 92 81-119 4-Bromofluorobenzene (S) %. 95 82-120 Dibromofluoromethane (S) %. 95 82-114 Toluene-d8 (S) %. 97 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 55.2 48.8 110 98 68-137 12 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 61.0 53.7 122 107 66-142 13 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 60.5 50.2 121 100 39-171 19 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 56.6 50.8 113 102 73-136 11 12 1,1-Dichloroethane ug/L ND 50 50 57.6 54.2 115 108 66-155 6 15 1,1-Dichloroethene ug/L ND 50 50 66.9 63.4 134 127 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 43.4 35.3 87 71 78-133 21 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 47.2 38.4 94 77 58-124 21 15 R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.6 47.5 113 95 71-134 17 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 56.2 46.9 112 94 69-135 18 10 R1 1,2-Dichloroethane ug/L ND 50 50 54.3 49.3 109 99 36-159 10 10 1,2-Dichloropropane ug/L ND 50 50 60.0 53.0 120 106 68-132 12 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 54.0 47.7 108 95 49-153 12 9 R1 2-Butanone (MEK) ug/L ND 100 100 96.5 82.0 97 82 10-189 16 23 2-Hexanone ug/L ND 100 100 83.2 67.8 83 68 40-135 20 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 98.2 83.6 98 84 30-177 16 10 R1 (MIBK) Acetone ug/L ND 100 100 86.0 75.6 80 70 44-223 13 14 Acrylonitrile ug/L ND 200 200 191 160 95 80 13-189 18 12 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L ND 50 50 57.6 52.4 115 105 66-139 9 10 Bromochloromethane ug/L ND 50 50 59.4 53.3 119 107 73-133 11 13 Bromodichloromethane ug/L ND 50 50 55.5 49.5 111 99 57-120 11 13 Bromoform ug/L ND 50 50 53.5 44.4 107 89 48-128 18 13 R1 Bromomethane ug/L ND 50 50 37.8 39.3 76 79 10-187 4 32 Carbon disulfide ug/L ND 100 100 111 101 111 101 47-141 9 322 Carbon tetrachloride ug/L ND 50 50 72.2 64.1 144 128 58-127 12 14 MOM Chlorobenzene ug/L ND 50 50 55.2 48.2 110 96 63-137 14 10 R1 Chloroethane ug/L ND 50 50 50.6 45.5 101 91 52-146 11 16 Chloroform ug/L ND 50 50 50.5 46.5 101 93 74-137 8 9 Chloromethane ug/L ND 50 50 53.7 49.1 107 98 41-127 9 10 cis-1,2-Dichloroethene ug/L ND 50 50 60.1 54.4 120 109 71-138 10 16 cis-1,3-Dichloropropene ug/L ND 50 50 56.5 51.6 113 103 32-145 9 12 Dibromochloromethane ug/L ND 50 50 54.9 47.6 110 95 52-116 14 13 R1 Dibromomethane ug/L ND 50 50 60.9 52.8 122 106 79-129 14 14 Ethylbenzene ug/L ND 50 50 57.7 51.3 115 103 31-174 12 10 R1 lodomethane ug/L ND 100 100 95.6 107 96 107 49-154 12 30 Methylene Chloride ug/L ND 50 50 56.0 51.0 112 102 61-146 9 15 Styrene ug/L ND 50 50 60.2 52.4 120 105 77-128 14 14 Tetrachloroethene ug/L ND 50 50 56.5 50.9 113 102 36-155 10 14 Tetrahydrofuran ug/L ND 100 100 98.8 83.6 99 84 56-147 17 12 R1 Toluene ug/L ND 50 50 57.1 50.1 114 100 52-146 13 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 65.9 58.5 132 117 61-152 12 14 trans-1,3-Dichloropropene ug/L ND 50 50 48.6 41.7 97 83 37-146 15 12 R1 Trichloroethene ug/L ND 50 50 53.7 49.4 107 99 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.3 61.4 135 123 51-141 9 13 Vinyl acetate ug/L ND 50 50 49.9 44.4 100 89 52-141 12 14 Vinyl chloride ug/L ND 50 50 58.8 54.6 118 109 22-156 7 26 Xylene (Total) ug/L ND 150 150 179 159 119 106 78-132 12 7 RS 1,2-Dichloroethane-d4 (S) %. 96 95 81-119 4-Bromofluorobenzene (S) %. 98 96 82-120 Dibromofluoromethane (S) %. 97 98 82-114 Toluene-d8 (S) %. 98 98 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 475936 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286001 METHOD BLANK: 2578807 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/17/19 12:15 1,2-Dichloroethane-d4 (S) % 100 50-150 05/17/19 12:15 Toluene-d8 (S) % 114 50-150 05/17/19 12:15 LABORATORY CONTROL SAMPLE: 2578808 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578809 2578810 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.3 20.2 96 101 50-150 5 30 1,2-Dichloroethane-d4 (S) % 92 90 50-150 30 Toluene-d8 (S) % 82 81 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286002 METHOD BLANK: 2579453 Associated Lab Samples: 2618286002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/19/1910:45 102 50-150 05/19/1910:45 113 50-150 05/19/1910:45 LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 25.7 20.3 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28076 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126363 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/09/19 13:54 LABORATORY CONTROL SAMPLE: 126364 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 101000 101 85-115 SAMPLE DUPLICATE: 126365 2618202009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 123 mg/L 124000 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28369 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 2618286001, 2618286002 LABORATORY CONTROL SAMPLE: 127730 Parameter Units Total Dissolved Solids ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 400000 403000 101 84-108 SAMPLE DUPLICATE: 127731 2618286001 Dup Parameter Units Result Result Total Dissolved Solids ug/L 158000 133000 Max RPD RPD Qualifiers 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28239 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2618286001 METHOD BLANK: 127270 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 05/13/19 15:36 LABORATORY CONTROL SAMPLE: 127271 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 203000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127272 127273 MS MSD 2618152001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 11400 5000000 5000000 1630000 1610000 99 96 90-110 1 10 mg/L 0 0 MATRIX SPIKE SAMPLE: 127274 2618152003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 11200 mg/L 5000000 16200000 100 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28184 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2618286001 METHOD BLANK: 126976 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide ug/L ND 200 05/10/1914:19 LABORATORY CONTROL SAMPLE: 126977 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 452 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126978 126979 MS MSD 2618407004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 ND ND 39 38 30-129 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28001 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618286001 METHOD BLANK: 125904 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/13/19 12:52 1A LABORATORY CONTROL SAMPLE: 125906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 205000 104 85-115 1A SAMPLE DUPLICATE: 125957 2618270001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1110 mg/L 1270000 13 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28053 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126307 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L ND 50.0 05/09/19 14:29 LABORATORY CONTROL SAMPLE: 126308 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9630 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126309 126310 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 359 10000 10000 9640 9600 93 92 90-110 0 15 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28932 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001 METHOD BLANK: 130388 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 81.OJ 1000 05/23/19 03:39 Sulfate ug/L 23.OJ 5000 05/23/19 03:39 LABORATORY CONTROL SAMPLE: 130389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10500 105 90-110 Sulfate ug/L 10000 11000 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130390 130391 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2930 10000 10000 13300 13200 104 103 90-110 1 15 Sulfate ug/L 12600 10000 10000 22300 22300 97 98 90-110 0 15 MATRIX SPIKE SAMPLE: 130392 2618688001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L ND 5000000 5160000 101 90-110 Sulfate ug/L ND 5000000 5420000 107 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 29257 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286002 METHOD BLANK: 131872 Matrix: Water Associated Lab Samples: 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 78.OJ 1000 05/30/19 06:38 Sulfate ug/L 35.OJ 5000 05/30/19 06:38 LABORATORY CONTROL SAMPLE: 131873 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9910 99 90-110 Sulfate ug/L 10000 9940 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 131874 131875 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2840 10000 10000 12600 12400 98 95 90-110 2 15 Sulfate ug/L 3140J 10000 10000 12800 12700 97 95 90-110 1 15 MATRIX SPIKE SAMPLE: 131888 2619009001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L 11.6 mg/L 10000 21200 96 90-110 Sulfate ug/L ND 10000 10900 104 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28426 Analysis Method: EPA 9060A QC Batch Method: EPA 9060A Analysis Description: 9060A Total Organic Carbon Associated Lab Samples: 2618286001 METHOD BLANK: 127954 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 LABORATORY CONTROL SAMPLE: 127955 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19100 96 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 18900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127956 127957 MS MSD 2618406001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20000 19800 84 83 85-115 1 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19900 19600 84 82 85-115 2 10 M1 Total Organic Carbon ug/L 3.3 mg/L 20000 20000 20300 19800 85 82 85-115 3 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20100 20100 84 85 85-115 0 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19500 19800 81 83 85-115 2 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127958 127959 MS MSD 2618294001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 1040 20000 20000 19000 18900 90 89 85-115 1 10 Total Organic Carbon ug/L 1040 20000 20000 19000 19000 90 90 85-115 0 10 Total Organic Carbon ug/L 1020 20000 20000 18200 18800 86 89 85-115 3 10 Total Organic Carbon ug/L 1030 20000 20000 19400 19100 92 90 85-115 2 10 Total Organic Carbon ug/L 1060 20000 20000 19300 18600 91 88 85-115 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 46 Pace Analytical Services, LLC ,_�ceAnalXicallp 11 Technology Parkway Peachtree e Corners, GA 30092 www.pacolabs.com (770)734-4200 QUALIFIERS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA BATCH QUALIFIERS Batch: 28232 The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. ANALYTE QUALIFIERS 1A The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 46 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618286001 1302-C D-1 S 28595 2618286002 1302-CD-1 D 28595 2618286001 1302-CD-IS EPA3005A 28295 EPA6020B 28307 2618286002 1302-CD-ID EPA3005A 28295 EPA6020B 28307 2618286001 1302-CD-1S EPA 7470A 28287 EPA 7470A 28296 2618286002 1302-CD-1 D EPA 7470A 28287 EPA 7470A 28296 2618286001 1302-CD-1 S EPA 8260D 28431 2618286002 1302-CD-1 D EPA 8260D 28431 2618286001 1302-CD-1S EPA 8260D Mod. 475936 2618286002 1302-CD-ID EPA 8260D Mod. 476071 2618286001 1302-CD-1S SM 2320E 28076 2618286002 1302-CD-1D SM 2320E 28076 2618286001 1302-CD-IS SM 2540C 28369 2618286002 1302-CD-ID SM 2540C 28369 2618286001 1302-CD-1S EPA410.4 28239 EPA410.4 28257 2618286001 1302-CD-IS SM 4500-S2 D 28184 2618286001 1302-CD-1S SM 5210E 28001 SM 5210B 28232 2618286001 1302-CD-1 S EPA 9056A 28053 2618286002 1302-CD-1 D EPA 9056A 28053 2618286001 1302-CD-1S EPA 9056A 28932 2618286002 1302-CD-1 D EPA 9056A 29257 2618286001 1302-CD-1S EPA 9060A 28426 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 46 INIAr sa,dweg NIA �aiooO O palEeg A lsn (NIA) a�1 � uo Pon103e8 S s INOO OU-JO D IRnPisald O ul dMi euexQip•ti l W15+75ZB x x � GC rn f ro 0. 405'fO Riiuil2M4tl'SOS x x �� ti asoueubuupy'uoi,'Ajrniayq x to s1919IN I ddV x XI I g fua6olpRHj WWO tlO x ' Y1 r {VJAI saseo Par.,ossip x (3'3'YV'ZOO) SOSOO s1O x uogioO alu05JO Ielol x Fg ❑-ZS-00,4W5 Rq apilln5 x ❑DD K U N CQN REIrS cog x Sr2 O y� L] n snld 09N OOA I d(JV x x NIA 1861 sasliOW m iayi0 o E n C w a yJ lauey,eyf �! EoZSzlnN HOeN is IOH n 0 u� £ONH � 0. POSZH n P—saiduO r v °i 8 NG L VF L a a 6 Sl13NfViNDDior NO!i D3110D LV dN31 3ldWd5 d & a c7 a a � V7 N O O Q p u1 W 4 W E C x a v O C7 � Q � W C W o m a T1 O N ❑ qj o c v � r � p v m 7 Z {d Y40D=7 9Vts`1.01 3dA131dWt'S f ai ci sips» p•le• ucs) V 30077CItii:'N a V `m v m w [C a p ti o �n;3aa$3a`a� 00 � N 00 r� Q _ as J�o� C m iL tsd 4 F N N a (} FE m 6 C p N im Q M a z a w Page 31 of 46 e �S # W3J o Sample... r FaceAnaOicaf Client Name:LM - ti Wo# : i 28 1 8285 PM: SMM Due Date: 05 CIL"NT: �DM-Raleigh I2 1/4 g Courier: Ex ❑ UPS 7Client ❑ Commercial ] Pace Other Tracking #: I USP �f Custody Seat on CoolerlBox Present: `' i] no Seals intact: yes J no Packing Material: Bubble /Wrap �e Baas -1 None f7 Other ..-.,... _ i i.- A 11 ?f -) T..nn of Ira• /Wai) Rli iw Nnnp Proj. Due Date: Proj, Name: F—I 5,amnlnc hn ic.e. rnolino oracess has beoun Cooler Temperature Temp should be above freezing to 6'C Biological Tissue is Frozen: r >5 No Comments: Datc nd Initial of ers mining Ca tents: Chain of Custody Present: _ ves ❑No ❑N+A 1. Chain of Custody Filled Out: _ 7-It _No L-1N;A 2- Chain of Custody Relinquished. I;; e L-N❑ ❑N A 3- Sampler Name & Signature on COG: .? 0N❑ ❑N;A 4, Samples Arrived within Hold Time: us [No ❑N A 5. Short Hold Time Analysis (<72hr): ❑No ❑N+A 6. Rush Turn Around Time Requested: ❑Yes FXo__nN1A 7 Sufficient Volume: -RCN❑ DNA S. Correct Containers used -Pace Containers Used: 2177 L:N41 UY157-ONO ❑N a 01,11A 9. Containers Intact: s C'iNo ❑N,A Filtered volume received for Dissolved tests ❑Yes --,No Dr, 11. Sample Labels match COC: -Includes dateltimellD/Anal sis Matrix: ET < GN❑ CNiA 12, All containers needing preservatiDn have been checked- All containers needing preservation are found to be in compliance with EPA recommendation. e.ceptpons. A- . nform,9-65G 11'!•'3RO3 waled � �- ►rf-s ❑Nc es ❑No � � — '-1. CNQ DNA DNA 13. Initial when Lot 4 added completed preser ative Samples checked for dedilorinalion: ❑Yes ❑No 14, Headspace in VOA Vials t >6mmy: Gres ❑ - b 1 Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased):___ ❑Yes C>uo ❑Yes CNo Z . a uA 16. Client Notification) Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date,'Time: Field 6ata Required? Y ! N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be Coflitrcation Office ( i.e out of hold, incorrect preservalive. out of temp. mcorrecl containers) to the North Carolina DEHNP, Page 32 of 46 F-A(LCO03rev 3. 1 iSeplember2006 ?ceAnalytical i May 23, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618286 Pace Workorder. 30306 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Friday, May 10, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/23/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS nel""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 14 Page 1 of 10 Page 33 of 46 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 10 Page 34 of 46 ?ceAnalytical @ SAMPLE SUMMARY Workorder: 30306 CABARRUS COUNTY / 2618286 Lab ID Report ID: 30306 - 1167062 �rtiecp Sample ID 1302-CD-1 S Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Matrix Date Collected Date Received 19V= CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. 5/7/2019 09:06 5/10/2019 10:30 Page 3 of 10 Page 35 of 46 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303060001 Sample ID: 1302-CD-1S Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 09:06 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0431.11 mg/I 0.20 0.043 1 5/15/2019 16:29 KB Acetic Acid 0.032J mg/I 0.10 0.028 1 5/15/2019 16:29 KB Propionic Acid 0.00401.11 mg/I 0.10 0.0040 1 5/15/2019 16:29 KB Formic Acid 0.17J mg/I 0.50 0.086 1 5/15/2019 16:29 KB Butyric Acid 0.0111,11 mg/I 0.10 0.011 1 5/15/2019 16:29 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/15/2019 16:29 KB i-Pentanoic Acid 0.00601.11 mg/I 0.10 0.0060 1 5/15/2019 16:29 KB Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/15/2019 16:29 KB i-Hexanoic Acid 0.0291.11 mg/I 0.20 0.029 1 5/15/2019 16:29 KB Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/15/2019 16:29 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.053J ug/I 0.50 0.046 1 5/15/201911:53 BW n Ethane 0.00501.11 ug/I 0.10 0.0050 1 5/15/201911:53 BW n Ethene 0.00401.11 ug/I 0.10 0.0040 1 5/15/201911:53 BW n Carbon Dioxide 50 mg/I 5.0 0.45 1 5/15/2019 11:53 BW n Report ID: 30306 - 1167062 Page 4 of 10 CERTIFICATE OF ANALYSIS nel""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 36 of 46 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 nelaet. CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 5 of 10 Page 37 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: DISG/7535 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303060001 METHOD BLANK: 61187 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.046U 0.046 n Ethane ug/I 0.0050U 0.0050 n Ethene ug/I 0.0040U 0.0040 n METHOD BLANK: 61188 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 0.45U 0.45 n LABORATORY CONTROL SAMPLE & LCSD: 61189 61191 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 760 740 101 99 80-120 1.7 20 n Ethane ug/I 38 39 38 104 101 80-120 3.1 20 n Ethene ug/I 35 36 35 103 98 80-120 4.9 20 n LABORATORY CONTROL SAMPLE & LCSD: 61190 61192 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 120 110 106 97 80-120 9.1 20 n Report ID: 30306 - 1167062 Page 6 of 10 CERTIFICATE OF ANALYSIS nel""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 38 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: EDON/4075 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 303060001 METHOD BLANK: 61209 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028U 0.028 Propionic Acid mg/I 0.0040U 0.0040 Formic Acid mg/I 0.086U 0.086 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 61210 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 109 70-130 Acetic Acid mg/I 2 2.1 103 70-130 Propionic Acid mg/I 2 2.0 102 70-130 Formic Acid mg/I 2 2.0 101 70-130 Butyric Acid mg/I 2 2.0 103 70-130 Pyruvic Acid mg/I 2 2.1 106 70-130 i-Pentanoic Acid mg/I 2 2.0 99 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 i-Hexanoic Acid mg/I 2 1.8 91 70-130 Hexanoic Acid mg/I 2 1.9 94 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.22 20 22 22 107 108 70-130 1.3 30 d Acetic Acid mg/I 29 20 50 50 104 105 70-130 0.29 30 d Report ID: 30306 - 1167062 Page 7 of 10 CERTIFICATE OF ANALYSIS nel""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 39 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Propionic Acid mg/I 5.6 20 26 26 104 103 70-130 0.53 30 d Formic Acid mg/I 1.6 20 21 21 99 99 70-130 0.23 30 d Butyric Acid mg/I 0.84 20 22 22 107 106 70-130 1.1 30 d Pyruvic Acid mg/I 0.29 20 22 22 107 107 70-130 0.01 30 d i-Pentanoic Acid mg/I 0.38 20 21 21 105 103 70-130 1.9 30 d Pentanoic Acid mg/I 0.57 20 22 22 107 105 70-130 2 30 d i-Hexanoic Acid mg/I 0 20 21 20 106 101 70-130 4.9 30 d Hexanoic Acid mg/I 0.15 20 22 22 108 107 70-130 0.69 30 d Report ID: 30306 - 1167062 Page 8 of 10 CERTIFICATE OF ANALYSIS nel""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 40 of 46 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 QUALITY CONTROL PARAMETER QUALIFIERS The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 9 of 10 Page 41 of 46 ?ceAnalytical QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 303060001 1302-CD-1S AM20GAX DISG/7535 303060001 1302-CD-1 S AM23G EDON/4075 Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 10 Page 42 of 46 I I 0 G) fl) 0 CD CD (a 3 3(D 0 w w w 0 E CD :3 0 (D (D > M 0 =1 0 ;y 0 Ey (D 40(a O o D N 3 w 3-, CD ro 0 -01 (D -U —04 51 (D N) N 0 CD a) 0 (D > w , (@ w 0 0 Q) 0 X CD (c) z (0D PI) (D 0 3 Z) -D a 0 0 0 0 S U) 0 00 cr CL 00 CAI (D O c� 0 CD ro t CL 71) z 0 lot HCL Unpreser,,ed 0 CD 0 0 SD < CD (D >< Sub Dissolved Carbon Dioxide A z cn A) 0 3 (D (D fJ2,1 f z m 0 z 9 R 0 0 0 0 c:) ro Page 43Pof 46 Cooler Receipt Forte_ ~ -,"Lai Work Order: r, . Client Name. '" Project: t,N A. Shipping/Container tnformation (circle appropriate response) Courier: FedEx UPS USPS Client Other: Air bill Present: Yes,' No Tracking Number: r Custody Seal on Cooler/Box Present: Yes',No Seals lntac Yes No Cooler/Box Packing Material: bubble Wrap Absorbent Foam Other: Type of lce (Wet; Blue None Ice Intact: l'es, Melted �_.. Cooler Temperature: t Radiation Screened: Yes �o Chain of Custody Present: Yes' No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES I NO I N/A Comment Reference non -Conformance Chain of Custody properly filled out I Chain of Custody relinquished It . Sampler Name & Signature on CDC Containers intact Were samples in separate bags i Sample container labels match CDC Sample name/date and time collected Sufficient volume provided PAES containers used Are containers properly preserved for the requested testing? (as labeled) L`yes, see pH form• if an unknown preservation state, were containers checked? Exception: VOA's coliform i Was volume for dissolved testing field filtered, as noted on the CDC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by Date, Project Manager Review : Date: J 30ct2017 Page 44 of 46 Xjoj-CONFoyo,/ LkNCE FORT✓ M W, )k- PAn_ ES WDTY Order =l '� Ti-nt of ReCeTl: cum tp'� FOR !,one xr ACTJON TAKEN": ch u--n4i- curoms so -ice Whals: _aw-- 20 T�ov'—)014 Dattl T =, e: - Page 45 of 46 Page 1 of 2 Emma Louis - CDM Sub outs, in Summary (3 Pace Atlanta Projects) From: Sakina Mckenzie To: Louis, Emma Date: 5/10/2019 1:16 PM Subject: CDM Sub outs, in Summary (3 Pace Atlanta Projects) C K",. Cc: Welsh, Ruth Hi Emma, Just in Summary, there are 10 samples total, for Dissolved Carbon Dioxide, Dissolved Hydrogen, Methane/Ethane/ Ethene, and Volatile Fatty Acids. Well 1302-CD-1S is separate on one project, #2618286 The other Wells are split between 2618294 (Dissolved Carbon Dioxide, Methane/Ethane/Ethene and Volatile Fatty Acids) and 2618427 Dissolved Hydrogen only. Thank you, I am so sorry. It must be hot in the field, I can't figure out what these field guys are doing with this event. Sakina Sakina -Af.-AfcXenzie Senior Project Manager Pace Analytical Services LLC. 110 Technology Pkwy NW Peachtree Corners, GA 30092 Main: 770-734-4200 ( Direct: 770-734-4204 Internal: 264204 Sakina.McKenzie@pacelabs.com >>> Sakina Mckenzie 5/10/2019 12:43 PM >>> Hi Emma, Not sure what our field samplers did, but they sampled all of the Dissolved Hydrogen separate from the rest of the parameters that we shipped to you (Carbon Dioxide, Volatile Fatty Acids, and M/E/E). I am logging the Dissolved Hydrogen now (2618427), so disregard this analysis when the samples arrive today for the rest of those parameters. Page 46 of 46 file:///C:/Users/elouis/AppData/Local/Temp/XPgrpwise/5CD579COPACE DOMAINPAE... 5/10/2019 aceAna1yAcal www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 04, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Lab ID Sample ID Matrix Date Collected Date Received 2618455001 1302-CD-2 Water 05/07/19 08:28 05/10/19 14:10 2618455002 1302-CD-2 Water 05/07/19 08:28 05/10/19 14:10 2618455003 1302-CD-7 Water 05/07/1911:19 05/10/19 14:10 2618455004 1302-CD-7 Water 05/08/19 08:53 05/10/19 14:10 2618455005 1302-CD-9 Water 05/07/1912:43 05/10/19 14:10 2618455006 1302-CD-9 Water 05/08/19 09:00 05/10/19 14:10 2618455007 1302-CD-DUPLICATE Water 05/07/19 09:00 05/10/19 14:10 2618455008 1302-CD-DUPLICATE Water 05/08/19 00:00 05/10/19 14:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618455001 1302-CD-2 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA 2618455002 1302-CD-2 EPA 6020E KLH 17 PASI-GA EPA 7470A DRB 1 PASI-GA 2618455003 1302-CD-7 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A MWB, RLC 2 PASI-GA 2618455004 1302-CD-7 EPA 6020E CSW, KLH 17 PASI-GA EPA 7470A DRB 1 PASI-GA 2618455005 1302-CD-9 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA 2618455006 1302-CD-9 EPA 6020E KLH 17 PASI-GA EPA 7470A DRB 1 PASI-GA 2618455007 1302-CD-DUPLICATE EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B KN 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A MWB, RLC 2 PASI-GA 2618455008 1302-CD-DUPLICATE EPA 6020E CSW, KLH 17 PASI-GA EPA 7470A DRB 1 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-2 Lab ID: 2618455001 Collected: 05/07/19 08:28 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.67 Std. Units 1 05/23/19 13:39 Field Temperature 16.1 deg C 1 05/23/19 13:39 Field Specific Conductance 143.2 umhos/cm 1 05/23/19 13:39 Field Turbidity 800+ NTU 1 05/23/19 13:39 Field Oxidation Potential 106.4 my 1 05/23/19 13:39 Oxygen, Dissolved 20.8 mg/L 1 05/23/19 13:39 7782-44-7 N2 Depth to Water 14.52 feet 1 05/23/19 13:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 15:48 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 15:48 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 15:48 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 15:48 79-00-5 1,1-Dichloroethane 3.5 ug/L 1.0 1 05/17/19 15:48 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 15:48 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 15:48 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 15:48 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 15:48 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 15:48 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 15:48 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 15:48 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 15:48 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 15:48 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 15:48 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 15:48 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 15:48 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 15:48 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 15:48 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 15:48 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 15:48 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 15:48 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 15:48 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 15:48 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 15:48 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 15:48 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 15:48 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 15:48 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 15:48 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 15:48 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 15:48 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 15:48 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 15:48 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 15:48 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 15:48 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 15:48 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 15:48 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 15:48 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-2 Lab ID: 2618455001 Collected: 05/07/19 08:28 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Trichloroethene ND ug/L 1.0 1 05/17/19 15:48 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 15:48 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 15:48 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 15:48 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 15:48 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 15:48 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 15:48 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 15:48 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 15:48 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 15:48 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 %. 81-119 1 05/17/19 15:48 17060-07-0 Dibromofluoromethane (S) 103 %. 82-114 1 05/17/19 15:48 1868-53-7 4-Bromofluorobenzene (S) 86 %. 82-120 1 05/17/19 15:48 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 15:48 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND mg/L 0.0020 1 05/19/19 11:44 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 112 % 50-150 1 05/19/19 11:44 17060-07-0 Toluene-d8 (S) 115 % 50-150 1 05/19/19 11:44 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 40000 ug/L 20000 1 05/13/19 16:49 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 161000 ug/L 10000 1 05/14/19 19:16 9056 IC Anions Analytical Method: EPA 9056A Chloride 8400 ug/L 1000 1 05/23/19 06:08 16887-00-6 Sulfate 10500 ug/L 5000 1 05/23/19 06:08 14808-79-8 Date: 06/04/2019 11:07 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-2 Lab ID: 2618455002 Collected: 05/07/19 08:28 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 2.25 NTU 1 05/23/19 13:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-36-0 Arsenic 0.42J ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-38-2 Barium 41.7 ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-39-3 Beryllium 0.081J ug/L 0.50 1 05/16/1914:34 05/21/1919:16 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:16 7440-43-9 Chromium 0.98J ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-47-3 Cobalt 1.91 ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-48-4 Copper 1.3J ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-50-8 Iron 782 ug/L 40.0 1 05/16/1914:34 05/21/1919:16 7439-89-6 Lead 0.44J ug/L 1.0 1 05/16/1914:34 05/21/1919:16 7439-92-1 Manganese 49.7 ug/L 10.0 1 05/16/1914:34 05/21/1919:16 7439-96-5 Nickel 2.2J ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/21/1919:16 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/21/1919:16 7440-28-0 Vanadium 4.7J ug/L 10.0 1 05/16/1914:34 05/21/1919:16 7440-62-2 Zinc 5AJ ug/L 10.0 1 05/16/1914:34 05/21/1919:16 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:35 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-7 Lab ID: 2618455003 Collected: 05/07/19 11:19 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.81 Std. Units 1 05/23/19 13:39 Field Temperature 17.1 deg C 1 05/23/19 13:39 Field Specific Conductance 397.1 umhos/cm 1 05/23/19 13:39 Field Turbidity 800+ NTU 1 05/23/19 13:39 Field Oxidation Potential 65.4 my 1 05/23/19 13:39 Oxygen, Dissolved 19.2 mg/L 1 05/23/19 13:39 7782-44-7 N2 Depth to Water 38.04 feet 1 05/23/19 13:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 16:15 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 16:15 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 16:15 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 16:15 79-00-5 1,1-Dichloroethane 0.56J ug/L 1.0 1 05/17/19 16:15 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 16:15 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 16:15 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 16:15 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 16:15 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 16:15 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 16:15 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 16:15 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 16:15 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 16:15 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 16:15 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 16:15 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 16:15 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 16:15 107-13-1 Benzene 0.911 ug/L 1.0 1 05/17/19 16:15 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 16:15 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 16:15 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 16:15 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 16:15 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 16:15 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 16:15 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 16:15 108-90-7 Chloroethane 1.2 ug/L 1.0 1 05/17/19 16:15 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 16:15 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 16:15 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 16:15 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 16:15 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 16:15 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 16:15 74-88-4 Methylene Chloride 1.1 ug/L 1.0 1 05/17/19 16:15 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 16:15 100-42-5 Tetrachloroethene 1.5 ug/L 1.0 1 05/17/19 16:15 127-18-4 Tetrahydrofuran 27.3 ug/L 10.0 1 05/17/19 16:15 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 16:15 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-7 Lab ID: 2618455003 Collected: 05/07/19 11:19 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Trichloroethene ND ug/L 1.0 1 05/17/19 16:15 79-01-6 Trichlorofluoromethane 5.7 ug/L 1.0 1 05/17/19 16:15 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 16:15 108-05-4 Vinyl chloride 1.9 ug/L 1.0 1 05/17/19 16:15 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 16:15 1330-20-7 cis-1,2-Dichloroethene 1.8 ug/L 1.0 1 05/17/19 16:15 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 16:15 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 16:15 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 16:15 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 16:15 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 99 %. 81-119 1 05/17/19 16:15 17060-07-0 Dibromofluoromethane (S) 105 %. 82-114 1 05/17/19 16:15 1868-53-7 4-Bromofluorobenzene (S) 87 %. 82-120 1 05/17/19 16:15 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 16:15 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND mg/L 0.0020 1 05/19/19 12:04 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 112 % 50-150 1 05/19/19 12:04 17060-07-0 Toluene-d8 (S) 116 % 50-150 1 05/19/19 12:04 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 130000 ug/L 20000 1 05/13/19 16:56 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 359000 ug/L 10000 1 05/14/19 19:16 9056 IC Anions Analytical Method: EPA 9056A Chloride 19400 ug/L 1000 1 05/23/19 06:29 16887-00-6 Sulfate 47400 ug/L 25000 5 05/29/1911:01 14808-79-8 Date: 06/04/2019 11:07 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-7 Lab ID: 2618455004 Collected: 05/08/19 08:53 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 2.17 NTU 1 05/23/19 13:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-38-2 Barium 141 ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-39-3 Beryllium 0.32J ug/L 0.50 1 05/16/1914:34 05/21/1919:22 7440-41-7 Cadmium 0.12J ug/L 0.50 1 05/16/1914:34 05/21/1919:22 7440-43-9 Chromium 0.41J ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-47-3 Cobalt 5.0 ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-48-4 Copper 6.3 ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-50-8 Iron 64.9 ug/L 40.0 1 05/16/1914:34 05/21/1919:22 7439-89-6 Lead ND ug/L 1.0 1 05/16/1914:34 05/21/1919:22 7439-92-1 Manganese 2570 ug/L 100 10 05/16/19 14:34 05/23/19 21:06 7439-96-5 Nickel 13.7 ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/21/1919:22 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/21/1919:22 7440-28-0 Vanadium 1.91 ug/L 10.0 1 05/16/1914:34 05/21/1919:22 7440-62-2 Zinc 7.2J ug/L 10.0 1 05/16/1914:34 05/21/1919:22 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:37 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-9 Lab ID: 2618455005 Collected: 05/07/19 12:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.03 Std. Units 1 05/23/19 13:39 Field Temperature 17.2 deg C 1 05/23/19 13:39 Field Specific Conductance 281.3 umhos/cm 1 05/23/19 13:39 Field Turbidity 800+ NTU 1 05/23/19 13:39 Field Oxidation Potential 121.5 my 1 05/23/19 13:39 Oxygen, Dissolved 2.93 mg/L 1 05/23/19 13:39 7782-44-7 N2 Depth to Water 41.26 feet 1 05/23/19 13:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 16:41 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 16:41 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 16:41 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 16:41 79-00-5 1,1-Dichloroethane 3.5 ug/L 1.0 1 05/17/19 16:41 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 16:41 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 16:41 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 16:41 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 16:41 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 16:41 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 16:41 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 16:41 78-87-5 1,4-Dichlorobenzene 1.7 ug/L 1.0 1 05/17/19 16:41 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 16:41 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 16:41 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 16:41 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 16:41 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 16:41 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 16:41 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 16:41 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 16:41 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 16:41 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 16:41 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 16:41 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 16:41 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 16:41 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 16:41 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 16:41 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 16:41 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 16:41 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 16:41 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 16:41 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 16:41 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 16:41 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 16:41 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 16:41 127-18-4 Tetrahydrofuran 4.7J ug/L 10.0 1 05/17/19 16:41 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 16:41 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-9 Lab ID: 2618455005 Collected: 05/07/19 12:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 2540C Total Dissolved Solids Total Dissolved Solids 9056 IC Anions Chloride Sulfate Date: 06/04/2019 11:07 AM Analytical Method: EPA 8260D 0.87J ug/L 2.6 ug/L ND ug/L ND ug/L ND ug/L 14.6 ug/L ND ug/L ND ug/L ND ug/L ND ug/L 92 %. 102 %. 85 %. 82 %. Analytical Method: EPA 8260D Mod. ND mg/L 111 % 118 % Analytical Method: SM 2320B 118000 ug/L Analytical Method: SM 2540C 214000 ug/L Analytical Method: EPA 9056A 6460 ug/L 6340 ug/L 1.0 1 05/17/19 16:41 79-01-6 1.0 1 05/17/19 16:41 75-69-4 2.0 1 05/17/19 16:41 108-05-4 1.0 1 05/17/19 16:41 75-01-4 2.0 1 05/17/19 16:41 1330-20-7 1.0 1 05/17/19 16:41 156-59-2 1.0 1 05/17/19 16:41 10061-01-5 1.0 1 05/17/19 16:41 156-60-5 1.0 1 05/17/19 16:41 10061-02-6 5.0 1 05/17/19 16:41 110-57-6 81-119 1 05/17/19 16:41 17060-07-0 82-114 1 05/17/19 16:41 1868-53-7 82-120 1 05/17/19 16:41 460-00-4 82-109 1 05/17/19 16:41 2037-26-5 0.0020 1 05/19/19 12:23 123-91-1 50-150 1 05/19/19 12:23 17060-07-0 50-150 1 05/19/19 12:23 2037-26-5 20000 1 10000 1 1000 1 5000 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/13/19 17:03 05/14/19 19:17 05/23/19 06:50 16887-00-6 05/23/19 06:50 14808-79-8 Page 12 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-9 Lab ID: 2618455006 Collected: 05/08/19 09:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 19 NTU 1 05/23/19 13:39 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-38-2 Barium 96.8 ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:28 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:28 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-47-3 Cobalt 1.1J ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-48-4 Copper 2.5J ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-50-8 Iron 162 ug/L 40.0 1 05/16/1914:34 05/21/1919:28 7439-89-6 Lead ND ug/L 1.0 1 05/16/1914:34 05/21/1919:28 7439-92-1 Manganese 188 ug/L 10.0 1 05/16/1914:34 05/21/1919:28 7439-96-5 Nickel 6.6 ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/21/1919:28 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/21/1919:28 7440-28-0 Vanadium 4.1J ug/L 10.0 1 05/16/1914:34 05/21/1919:28 7440-62-2 Zinc 2.9J ug/L 10.0 1 05/16/1914:34 05/21/1919:28 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:40 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-DUPLICATE Lab ID: 2618455007 Collected: 05/07/19 09:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 17:07 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 17:07 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 17:07 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 17:07 79-00-5 1,1-Dichloroethane 0.62J ug/L 1.0 1 05/17/19 17:07 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 17:07 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 17:07 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 17:07 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 17:07 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 17:07 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 17:07 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 17:07 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 17:07 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 17:07 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 17:07 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 17:07 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 17:07 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 17:07 107-13-1 Benzene 0.92J ug/L 1.0 1 05/17/19 17:07 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 17:07 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 17:07 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 17:07 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 17:07 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 17:07 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 17:07 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 17:07 108-90-7 Chloroethane 1.4 ug/L 1.0 1 05/17/19 17:07 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 17:07 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 17:07 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 17:07 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 17:07 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 17:07 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 17:07 74-88-4 Methylene Chloride 1.1 ug/L 1.0 1 05/17/19 17:07 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 17:07 100-42-5 Tetrachloroethene 1.5 ug/L 1.0 1 05/17/19 17:07 127-18-4 Tetrahydrofuran 24.5 ug/L 10.0 1 05/17/19 17:07 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 17:07 108-88-3 Trichloroethene 0.37J ug/L 1.0 1 05/17/19 17:07 79-01-6 Trichlorofluoromethane 6.0 ug/L 1.0 1 05/17/19 17:07 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 17:07 108-05-4 Vinyl chloride 2.0 ug/L 1.0 1 05/17/19 17:07 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 17:07 1330-20-7 cis-1,2-Dichloroethene 1.9 ug/L 1.0 1 05/17/19 17:07 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:07 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 17:07 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 17:07 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-DUPLICATE Lab ID: 2618455007 Collected: 05/07/19 09:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) 2320B Alkalinity Alkalinity, Total as CaCO3 2540C Total Dissolved Solids Total Dissolved Solids 9056 IC Anions Chloride Sulfate Date: 06/04/2019 11:07 AM Analytical Method: EPA 8260D ND ug/L 99 %. 106 %. 88 %. 82 %. Analytical Method: EPA 8260D Mod. ND mg/L 109 % 117 % Analytical Method: SM 2320B 129000 ug/L Analytical Method: SM 2540C 391000 ug/L Analytical Method: EPA 9056A 19100 ug/L 48000 ug/L 5.0 1 05/17/19 17:07 110-57-6 81-119 1 05/17/19 17:07 17060-07-0 82-114 1 05/17/19 17:07 1868-53-7 82-120 1 05/17/19 17:07 460-00-4 82-109 1 05/17/19 17:07 2037-26-5 0.0020 1 05/19/19 12:43 123-91-1 50-150 1 05/19/19 12:43 17060-07-0 50-150 1 05/19/19 12:43 2037-26-5 20000 1 10000 1 1000 1 25000 5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 05/13/19 17:17 05/14/19 19:17 05/23/19 07:11 16887-00-6 05/29/19 11:23 14808-79-8 Page 15 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 Sample: 1302-CD-DUPLICATE Lab ID: 2618455008 Collected: 05/08/19 00:00 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-38-2 Barium 147 ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-39-3 Beryllium 0.36J ug/L 0.50 1 05/16/1914:34 05/21/1919:33 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/21/1919:33 7440-43-9 Chromium 0.88J ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-47-3 Cobalt 5.4 ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-48-4 Copper 9.9 ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-50-8 Iron 847 ug/L 40.0 1 05/16/1914:34 05/21/1919:33 7439-89-6 Lead 0.31J ug/L 1.0 1 05/16/1914:34 05/21/1919:33 7439-92-1 Manganese 4860 ug/L 100 10 05/16/1914:34 05/22/1914:57 7439-96-5 Nickel 13.5 ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/21/1919:33 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/21/1919:33 7440-28-0 Vanadium 4.7J ug/L 10.0 1 05/16/1914:34 05/21/1919:33 7440-62-2 Zinc 8.8J ug/L 10.0 1 05/16/1914:34 05/21/1919:33 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND mg/L 0.00020 1 05/15/19 08:19 05/15/19 12:42 7439-97-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294012 Collected: 05/07/19 10:25 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 5.98 Std. Units 1 05/22/19 11:39 Field Temperature 14.7 deg C 1 05/22/19 11:39 Field Specific Conductance 191.1 umhos/cm 1 05/22/19 11:39 Field Turbidity 800+ NTU 1 05/22/19 11:39 Field Oxidation Potential 48.4 my 1 05/22/19 11:39 Oxygen, Dissolved 24.6 mg/L 1 05/22/19 11:39 7782-44-7 N2 Depth to Water 10.65 feet 1 05/22/19 11:39 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:56 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 14:56 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:56 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 14:56 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 14:56 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 14:56 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 14:56 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 14:56 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 14:56 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:56 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 14:56 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 14:56 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:56 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 14:56 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 14:56 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 14:56 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 14:56 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 14:56 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 14:56 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 14:56 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 14:56 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 14:56 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 14:56 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 14:56 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 14:56 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 14:56 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 14:56 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 14:56 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 14:56 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 14:56 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 14:56 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 14:56 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 14:56 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 14:56 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 14:56 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 14:56 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 14:56 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 14:56 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 05/31 /2019 05:08 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 182 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294012 Collected: 05/07/19 10:25 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 05/31 /2019 05:08 PM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 95 %. 106 %. 88 %. 83 %. Analytical Method: EPA 8260D Mod. ND ug/L 109 % 115 % 1.0 1 05/17/19 14:56 79-01-6 1.0 1 05/17/19 14:56 75-69-4 2.0 1 05/17/19 14:56 108-05-4 1.0 1 05/17/19 14:56 75-01-4 2.0 1 05/17/19 14:56 1330-20-7 1.0 1 05/17/19 14:56 156-59-2 1.0 1 05/17/19 14:56 10061-01-5 1.0 1 05/17/19 14:56 156-60-5 1.0 1 05/17/19 14:56 10061-02-6 81-119 1 05/17/19 14:56 17060-07-0 82-114 1 05/17/19 14:56 1868-53-7 82-120 1 05/17/19 14:56 460-00-4 82-109 1 05/17/19 14:56 2037-26-5 2.0 1 05/19/19 13:03 123-91-1 50-150 1 05/19/19 13:03 17060-07-0 50-150 1 05/19/19 13:03 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 42 of 182 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Units 2/3 MSW Pace Project No.: 2618294 Sample: 1302-CD-4 Rep Lab ID: 2618294013 Collected: 05/08/19 08:43 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Field Turbidity 6020B MET ICPMS Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Vanadium Zinc Date: 05/31 /2019 05:08 PM Analytical Method 9.87 NTU 1 05/22/1911:39 Analytical Method: EPA 6020E Preparation Method: EPA 3005A ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-36-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-38-2 45.9 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-39-3 0.38J ug/L 0.50 1 05/16/1914:34 05/20/1915:14 7440-41-7 ND ug/L 0.50 1 05/16/1914:34 05/20/1915:14 7440-43-9 2.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-47-3 7.0 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-48-4 1.4J ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-50-8 1.1 ug/L 1.0 1 05/16/1914:34 05/20/1915:14 7439-92-1 5.8 ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-02-0 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7782-49-2 ND ug/L 5.0 1 05/16/1914:34 05/20/1915:14 7440-22-4 ND ug/L 1.0 1 05/16/1914:34 05/20/1915:14 7440-28-0 6.2J ug/L 10.0 1 05/16/1914:34 05/20/1915:14 7440-62-2 13.7 ug/L 10.0 1 05/16/1914:34 05/20/1915:14 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. B Page 43 of 182 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28368 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618455002, 2618455004, 2618455006, 2618455008 METHOD BLANK: 127725 Matrix: Water Associated Lab Samples: 2618455002, 2618455004, 2618455006, 2618455008 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury mg/L ND 0.00020 05/15/1911:08 LABORATORY CONTROL SAMPLE: 127726 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury mg/L 0.0025 0.0027 106 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127727 127728 MS MSD 2618406039 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury mg/L ND 0.0025 0.0025 0.0026 0.0026 102 102 75-125 0 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28521 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618455002, 2618455004, 2618455006, 2618455008 METHOD BLANK: 128457 Associated Lab Samples: Parameter Matrix: Water 2618455002, 2618455004, 2618455006, 2618455008 Blank Reporting Units Result Limit Analyzed Antimony ug/L ND 5.0 05/21/1917:56 Arsenic ug/L ND 5.0 05/21/1917:56 Barium ug/L ND 5.0 05/21/1917:56 Beryllium ug/L ND 0.50 05/21/1917:56 Cadmium ug/L ND 0.50 05/21/1917:56 Chromium ug/L ND 5.0 05/21/1917:56 Cobalt ug/L ND 5.0 05/21/1917:56 Copper ug/L ND 5.0 05/21/1917:56 Iron ug/L ND 40.0 05/21/1917:56 Lead ug/L ND 1.0 05/21/1917:56 Manganese ug/L ND 10.0 05/21/1917:56 Nickel ug/L ND 5.0 05/21/1917:56 Selenium ug/L ND 5.0 05/21/1917:56 Silver ug/L ND 5.0 05/21/1917:56 Thallium ug/L ND 1.0 05/21/1917:56 Vanadium ug/L ND 10.0 05/21/1917:56 Zinc ug/L ND 10.0 05/21/1917:56 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 128458 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 100 100 80-120 Arsenic ug/L 100 97.5 97 80-120 Barium ug/L 100 97.7 98 80-120 Beryllium ug/L 100 99.8 100 80-120 Cadmium ug/L 100 97.4 97 80-120 Chromium ug/L 100 98.5 99 80-120 Cobalt ug/L 100 99.0 99 80-120 Copper ug/L 100 99.9 100 80-120 Iron ug/L 1000 1000 100 80-120 Lead ug/L 100 98.4 98 80-120 Manganese ug/L 100 100 100 80-120 Nickel ug/L 100 98.0 98 80-120 Selenium ug/L 100 93.4 93 80-120 Silver ug/L 100 104 104 80-120 Thallium ug/L 100 99.1 99 80-120 Vanadium ug/L 100 99.3 99 80-120 Zinc ug/L 100 101 101 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 18 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County C&D Landfill 2618455 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128459 128460 MS MSD 2618455008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 103 102 103 102 75-125 1 20 Arsenic ug/L ND 100 100 102 101 102 101 75-125 1 20 Barium ug/L 147 100 100 252 250 105 103 75-125 1 20 Beryllium ug/L 0.36J 100 100 96.1 97.6 96 97 75-125 2 20 Cadmium ug/L ND 100 100 99.7 101 100 101 75-125 1 20 Chromium ug/L 0.88J 100 100 103 103 102 103 75-125 0 20 Cobalt ug/L 5.4 100 100 106 105 101 100 75-125 1 20 Copper ug/L 9.9 100 100 112 111 102 101 75-125 1 20 Iron ug/L 847 1000 1000 1970 1920 113 108 75-125 3 20 Lead ug/L 0.31J 100 100 98.4 98.0 98 98 75-125 0 20 Manganese ug/L 4860 100 100 4960 5160 102 299 75-125 4 20 Nickel ug/L 13.5 100 100 112 113 99 99 75-125 0 20 Selenium ug/L ND 100 100 96.6 98.3 96 98 75-125 2 20 Silver ug/L ND 100 100 102 102 102 102 75-125 0 20 Thallium ug/L ND 100 100 98.6 99.0 99 99 75-125 0 20 Vanadium ug/L 4.7J 100 100 111 110 107 105 75-125 1 20 Zinc ug/L 8.8J 100 100 106 110 97 101 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28582 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 METHOD BLANK: 128690 Matrix: Water Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 Blank Reporting Parameter Units Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 1,1,1-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 1,1,2-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethene ug/L ND 1.0 05/17/19 11:54 1,2,3-Trichloropropane ug/L ND 1.0 05/17/19 11:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/17/19 11:54 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/17/19 11:54 1,2-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 1,2-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,2-Dichloropropane ug/L ND 1.0 05/17/19 11:54 1,4-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 2-Butanone (MEK) ug/L ND 5.0 05/17/19 11:54 2-Hexanone ug/L ND 5.0 05/17/19 11:54 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/17/19 11:54 Acetone ug/L ND 25.0 05/17/19 11:54 Acrylonitrile ug/L ND 50.0 05/17/19 11:54 Benzene ug/L ND 1.0 05/17/19 11:54 Bromochloromethane ug/L ND 1.0 05/17/19 11:54 Bromodichloromethane ug/L ND 1.0 05/17/19 11:54 Bromoform ug/L ND 1.0 05/17/19 11:54 Bromomethane ug/L ND 2.0 05/17/19 11:54 Carbon disulfide ug/L ND 10.0 05/17/19 11:54 Carbon tetrachloride ug/L ND 1.0 05/17/19 11:54 Chlorobenzene ug/L ND 1.0 05/17/19 11:54 Chloroethane ug/L ND 1.0 05/17/19 11:54 Chloroform ug/L ND 1.0 05/17/19 11:54 Chloromethane ug/L ND 1.0 05/17/19 11:54 cis-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 cis-1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 Dibromochloromethane ug/L ND 1.0 05/17/19 11:54 Dibromomethane ug/L ND 1.0 05/17/19 11:54 Ethylbenzene ug/L ND 1.0 05/17/19 11:54 lodomethane ug/L ND 10.0 05/17/19 11:54 Methylene Chloride ug/L ND 1.0 05/17/19 11:54 Styrene ug/L ND 1.0 05/17/19 11:54 Tetrachloroethene ug/L ND 1.0 05/17/19 11:54 Tetrahydrofuran ug/L ND 10.0 05/17/19 11:54 Toluene ug/L ND 1.0 05/17/19 11:54 trans-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 v2 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 31 Pace Analytical Services, LLC ,_�ceAnalXicallp 11 Technology Parkway Peachtree e Corners, GA 30092 www.pacolabs.com+ (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 METHOD BLANK: 128690 Matrix: Water Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers trans- 1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 trans-1,4-Dichloro-2-butene ug/L ND 5.0 05/17/19 11:54 Trichloroethene ug/L ND 1.0 05/17/19 11:54 Trichlorofluoromethane ug/L ND 1.0 05/17/19 11:54 Vinyl acetate ug/L ND 2.0 05/17/19 11:54 Vinyl chloride ug/L ND 1.0 05/17/19 11:54 Xylene (Total) ug/L ND 2.0 05/17/19 11:54 1,2-Dichloroethane-d4 (S) %. 97 81-119 05/17/19 11:54 4-Bromofluorobenzene (S) %. 86 82-120 05/17/19 11:54 Dibromofluoromethane (S) %. 103 82-114 05/17/19 11:54 Toluene-d8 (S) %. 83 82-109 05/17/19 11:54 LABORATORY CONTROL SAMPLE: 128691 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.2 106 68-137 1,1,1-Trichloroethane ug/L 50 65.3 131 72-134 1,1,2,2-Tetrachloroethane ug/L 50 42.8 86 51-158 v2 1,1,2-Trichloroethane ug/L 50 58.5 117 78-131 1,1-Dichloroethane ug/L 50 61.1 122 69-151 1,1-Dichloroethene ug/L 50 65.8 132 64-158 1,2,3-Trichloropropane ug/L 50 43.1 86 78-133 1,2-Dibromo-3-chloropropane ug/L 50 41.9 84 58-124 1,2-Dibromoethane (EDB) ug/L 50 57.7 115 71-134 1,2-Dichlorobenzene ug/L 50 51.2 102 70-135 1,2-Dichloroethane ug/L 50 60.2 120 72-129 1,2-Dichloropropane ug/L 50 53.9 108 64-135 1,4-Dichlorobenzene ug/L 50 48.5 97 70-131 2-Butanone (MEK) ug/L 100 93.2 93 52-143 2-Hexanone ug/L 100 80.2 80 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 88.3 88 71-129 Acetone ug/L 100 103 103 48-224 Acrylonitrile ug/L 200 184 92 66-154 Benzene ug/L 50 59.7 119 68-132 Bromochloromethane ug/L 50 71.5 143 73-133 L1 Bromodichloromethane ug/L 50 52.8 106 67-121 Bromoform ug/L 50 51.4 103 57-125 Bromomethane ug/L 50 48.2 96 35-156 Carbon disulfide ug/L 100 119 119 47-141 Carbon tetrachloride ug/L 50 65.2 130 66-122 L1 Chlorobenzene ug/L 50 49.3 99 71-126 Chloroethane ug/L 50 45.8 92 43-143 Chloroform ug/L 50 62.7 125 71-136 Chloromethane ug/L 50 43.0 86 47-123 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 21 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 LABORATORY CONTROL SAMPLE: 128691 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers cis-1,2-Dichloroethene ug/L 50 62.3 125 74-131 cis-1,3-Dichloropropene ug/L 50 52.3 105 78-120 Dibromochloromethane ug/L 50 57.8 116 65-115 L1 Dibromomethane ug/L 50 65.8 132 79-129 L1 Ethylbenzene ug/L 50 49.1 98 68-129 lodomethane ug/L 100 129 129 49-154 Methylene Chloride ug/L 50 61.4 123 61-147 Styrene ug/L 50 56.6 113 77-128 Tetrachloroethene ug/L 50 67.0 134 51-139 Tetrahydrofuran ug/L 100 94.9 95 56-147 Toluene ug/L 50 56.5 113 60-133 trans-1,2-Dichloroethene ug/L 50 63.8 128 69-144 trans- 1,3-Dichloropropene ug/L 50 52.2 104 74-128 trans-1,4-Dichloro-2-butene ug/L 100 68.5 68 61-139 Trichloroethene ug/L 50 51.4 103 73-126 Trichlorofluoromethane ug/L 50 57.7 115 55-132 Vinyl acetate ug/L 50 40.5 81 52-141 Vinyl chloride ug/L 50 49.6 99 50-133 Xylene (Total) ug/L 150 156 104 78-132 1,2-Dichloroethane-d4 (S) %. 100 81-119 4-Bromofluorobenzene (S) %. 89 82-120 Dibromofluoromethane (S) %. 114 82-114 Toluene-d8 (S) %. 81 82-109 SO MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 128693 MS MSD 2618430001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 35.9 51.3 72 103 68-137 35 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 52.0 70.2 104 140 66-142 30 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 28.6 40.1 57 80 39-171 34 13 R1,v2 1,1,2-Trichloroethane ug/L ND 50 50 40.5 55.7 81 111 73-136 32 12 R1 1,1-Dichloroethane ug/L ND 50 50 45.4 60.9 91 122 66-155 29 15 R1 1,1-Dichloroethene ug/L ND 50 50 56.1 75.8 112 152 33-181 30 34 1,2,3-Trichloropropane ug/L ND 50 50 27.8 39.6 56 79 78-133 35 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 28.5 39.4 57 79 58-124 32 15 M1,R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 40.4 55.0 81 110 71-134 31 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 34.5 48.8 68 97 69-135 34 10 M1,R1 1,2-Dichloroethane ug/L ND 50 50 42.2 57.8 84 116 36-159 31 10 R1 1,2-Dichloropropane ug/L ND 50 50 38.8 52.7 78 105 68-132 30 11 R1 1,4-Dichlorobenzene ug/L 9.9 50 50 42.6 56.1 65 92 49-153 27 9 R1 2-Butanone (MEK) ug/L ND 100 100 63.1 75.9 63 76 10-189 18 23 2-Hexanone ug/L ND 100 100 58.9 80.7 59 81 40-135 31 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 63.7 86.4 64 86 30-177 30 10 R1 (MIBK) Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 128693 MS MSD 2618430001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Acetone ug/L ND 100 100 65.5 78.9 65 79 44-223 19 14 R1 Acrylonitrile ug/L ND 200 200 131 175 65 87 13-189 29 12 R1 Benzene ug/L 1.2 50 50 45.3 61.2 88 120 66-139 30 10 R1 Bromochloromethane ug/L ND 50 50 49.7 67.9 99 136 73-133 31 13 M0,R1 Bromodichloromethane ug/L ND 50 50 36.6 50.6 73 101 57-120 32 13 R1 Bromoform ug/L ND 50 50 33.0 46.0 66 92 48-128 33 13 R1 Bromomethane ug/L ND 50 50 28.6 45.9 57 92 10-187 47 32 R1 Carbon disulfide ug/L ND 100 100 97.4 130 97 130 47-141 29 322 Carbon tetrachloride ug/L ND 50 50 53.9 73.5 108 147 58-127 31 14 M0,R1 Chlorobenzene ug/L 18.2 50 50 52.2 65.6 68 95 63-137 23 10 R1 Chloroethane ug/L ND 50 50 37.3 50.6 75 101 52-146 30 16 R1 Chloroform ug/L ND 50 50 44.3 60.2 89 120 74-137 31 9 R1 Chloromethane ug/L ND 50 50 34.8 44.7 70 89 41-127 25 10 R1 cis-1,2-Dichloroethene ug/L ND 50 50 44.7 60.2 89 120 71-138 30 16 R1 cis-1,3-Dichloropropene ug/L ND 50 50 33.9 46.5 68 93 32-145 32 12 R1 Dibromochloromethane ug/L ND 50 50 38.8 53.9 78 108 52-116 33 13 R1 Dibromomethane ug/L ND 50 50 43.8 60.2 88 120 79-129 32 14 R1 Ethylbenzene ug/L ND 50 50 35.7 48.7 71 97 31-174 31 10 R1 lodomethane ug/L ND 100 100 102 138 102 138 49-154 30 30 Methylene Chloride ug/L ND 50 50 45.1 62.5 90 125 61-146 32 15 R1 Styrene ug/L ND 50 50 37.7 52.6 75 105 77-128 33 14 M1,R1 Tetrachloroethene ug/L ND 50 50 52.1 66.3 104 133 36-155 24 14 R1 Tetrahydrofuran ug/L ND 100 100 69.4 89.6 69 90 56-147 25 12 R1 Toluene ug/L ND 50 50 42.3 56.2 84 112 52-146 28 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 48.3 64.1 97 128 61-152 28 14 R1 trans-1,3-Dichloropropene ug/L ND 50 50 33.6 46.4 67 93 37-146 32 12 R1 trans-1,4-Dichloro-2-butene ug/L ND 100 100 43.3 57.3 43 57 61-139 28 12 M1,R1 Trichloroethene ug/L ND 50 50 38.0 49.6 76 99 61-141 26 12 R1 Trichlorofluoromethane ug/L ND 50 50 57.3 75.3 115 151 51-141 27 13 M1,R1 Vinyl acetate ug/L ND 50 50 50.5 30.5 101 61 52-141 49 14 R1 Vinyl chloride ug/L ND 50 50 42.9 57.3 85 114 22-156 29 26 R1 Xylene (Total) ug/L ND 150 150 112 152 74 102 78-132 31 7 RS 1,2-Dichloroethane-d4 (S) %. 98 97 81-119 4-Bromofluorobenzene (S) %. 88 89 82-120 Dibromofluoromethane (S) %. 110 113 82-114 Toluene-d8 (S) %. 80 81 82-109 SO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 METHOD BLANK: 2579453 Matrix: Water Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) mg/L ND 0.0020 05/19/19 10:45 1,2-Dichloroethane-d4 (S) % 102 50-150 05/19/19 10:45 Toluene-d8 (S) % 113 50-150 05/19/19 10:45 LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) mg/L 0.02 0.020 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) mg/L ND 0.02 0.02 0.026 0.020 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 24 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28286 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 METHOD BLANK: 127414 Matrix: Water Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/13/19 16:23 LABORATORY CONTROL SAMPLE: 127415 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 105000 105 85-115 SAMPLE DUPLICATE: 127416 2618406001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 77.0 mg/L 77000 0 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28369 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 LABORATORY CONTROL SAMPLE: 127730 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Total Dissolved Solids ug/L 400000 403000 101 84-108 SAMPLE DUPLICATE: 127731 2618286001 Dup Max Parameter Units Result Result RPD RPD Qualifiers Total Dissolved Solids ug/L 158000 133000 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 26 of 31 aceAna1yAcal www.pacolabs.com+ Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 QC Batch: 28932 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 METHOD BLANK: 130388 Matrix: Water Associated Lab Samples: 2618455001, 2618455003, 2618455005, 2618455007 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 81.OJ 1000 05/23/19 03:39 Sulfate ug/L 23.OJ 5000 05/23/19 03:39 LABORATORY CONTROL SAMPLE: 130389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10500 105 90-110 Sulfate ug/L 10000 11000 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130390 130391 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2930 10000 10000 13300 13200 104 103 90-110 1 15 Sulfate ug/L 12600 10000 10000 22300 22300 97 98 90-110 0 15 MATRIX SPIKE SAMPLE: 130392 2618688001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L ND 5000000 5160000 101 90-110 Sulfate ug/L ND 5000000 5420000 107 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Cabarrus County C&D Landfill Pace Project No.: 2618455 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS D6 The precision between the sample and sample duplicate exceeded laboratory control limits. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. SO Surrogate recovery outside laboratory control limits. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:07 AM without the written consent of Pace Analytical Services, LLC. Page 28 of 31 aceAna1yAca1 www.pacolabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County C&D Landfill 2618455 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618455001 1302-CD-2 28595 2618455002 1302-CD-2 28595 2618455003 1302-CD-7 28595 2618455004 1302-CD-7 28595 2618455005 1302-CD-9 28595 2618455006 1302-CD-9 28595 2618455002 1302-CD-2 EPA 3005A 28521 EPA 6020B 28523 2618455004 1302-CD-7 EPA 3005A 28521 EPA 6020B 28523 2618455006 1302-CD-9 EPA 3005A 28521 EPA 6020B 28523 2618455008 1302-CD-DUPLICATE EPA 3005A 28521 EPA 6020B 28523 2618455002 1302-CD-2 EPA 7470A 28368 EPA 7470A 28423 2618455004 1302-CD-7 EPA 7470A 28368 EPA 7470A 28423 2618455006 1302-CD-9 EPA 7470A 28368 EPA 7470A 28423 2618455008 1302-CD-DUPLICATE EPA 7470A 28368 EPA 7470A 28423 2618455001 1302-CD-2 EPA 8260D 28582 2618455003 1302-CD-7 EPA 8260D 28582 2618455005 1302-CD-9 EPA 8260D 28582 2618455007 1302-CD-DUPLICATE EPA 8260D 28582 2618455001 1302-CD-2 EPA 8260D Mod. 476071 2618455003 1302-CD-7 EPA 8260D Mod. 476071 2618455005 1302-CD-9 EPA 8260D Mod. 476071 2618455007 1302-CD-DUPLICATE EPA 8260D Mod. 476071 2618455001 1302-CD-2 SM 2320E 28286 2618455003 1302-CD-7 SM 2320E 28286 2618455005 1302-CD-9 SM 2320E 28286 2618455007 1302-CD-DUPLICATE SM 2320B 28286 2618455001 1302-CD-2 SM 2540C 28369 2618455003 1302-CD-7 SM 2540C 28369 2618455005 1302-CD-9 SM 2540C 28369 2618455007 1302-CD-DUPLICATE SM 2540C 28369 2618455001 1302-CD-2 EPA 9056A 28932 2618455003 1302-CD-7 EPA 9056A 28932 2618455005 1302-CD-9 EPA 9056A 28932 2618455007 1302-CD-DUPLICATE EPA 9056A 28932 Date: 06/04/2019 11:07 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 29 of 31 salduyeg (NIA) yalooO ❑ Mugs a< ysn (NIA) 0 Z u ¢ 0 3 aol uo panrasaa p J fJ N �Njh] auuol40 tenpisea m m K Ix �n u' dW31 A tY � F } J a oP _ O �� (aus uo) aan-i x uo) da❑ 'OO '98ni 'dW31 'OS 'Hd '9 'SIIV 'ap+ial4;1 o � Sai aleAnS a C N o J 'uyy '8}{ + s!elaW I dd<J ON au"Ora q-[ O FFF d �, a v_ dOea903 JH L - OOA I ddV ON 17 i N NIA JSOJ SeSAIVUV a U } c £QZSZoN y } a NOUN IOH w rn WL w cn � � EONH E R J rOSZH W n x ° _ - pan�aea�duO n ry �, uQ�❑ a`. F o 3 fap ? a sa3NrdLNoydo: oo m s N 01 L03»aO IV dPY3L 31d NYS _ a a ¢ J J a a F V, 2 N N z w a E u LU ¢ a z r 7 w a x z o c� U A n v n n cn r- c m z (driaa•O $Yli�=`Jl 3dA13ldYYtlS [7 ;� ti i. �] �y- ti wS" a [YP! pi sopoa Plsn aar! 3570$ Xlyl!'ri S S (. 0 a 9 q EE vS x ) a a a �s 2H'a-:Ra5 r�♦ L! ~ v N 0 LL L w ,s � W G QD h a s o e o$ n m N 0 V � Y � 4 J �� w o= a y Page 30 of 31 a N '� 0 v # Willi l+l ly a In IA oo m Sample Condition .. FaceAnaokai Client Name: Courier: ❑Fed Ex -UPS 1 USPS 1 Client ❑I Commercial Lrl Pace Othe. 7 8455 Pfi: SM CLIENT: Due Cps -Raleigh Date: 05/29/19 Tracking #:� Custody Seal on Cooler/Box Present: es ❑ no Seals intact: yes Packing Material: ❑ Bubble Wrap ubble Bags ❑ None ❑ Other Thermometer Used � — Type of Ice: We Blue None Cooler Temperature t Biological Tissue is Frozen: r,,s N7 Temp should be above freezing to 6'C Comments: no ❑ sampl oat Prot. Name: 1 s on Ice. cooling process has begun + �oee n+ ntentSin. Chain of Custody Present: Yes ❑No ❑NIA 1. Chain of Custody Filled Out: Yes ❑No ❑NIA 2. Chain of Custody Relinquished: 2fes ❑No ❑NIA 3. Sampler Name & Signature on COC: 22!E: No ❑WA 4. Samples Arrived within Hold Time: i2< ❑Na ❑NIA 5. Short Hold Time Analysis (<72hr): ❑Yes 2vo ❑NIA 6- Rush Turn Around Time Requested: ❑yes klNo ❑NIA 7. Sufficient Volume: yew/s El No ❑NrA 8. Correct Containers Used: -Pace Containers Used: 2' es 94ill ❑No ❑Ova ❑NIA ❑NIA 9, Containers Intact: 04. ❑No ❑N!A 10. Filtered volume received for Dissolved tests ❑Yes ❑Na ErNIA 11. Sample Labels match COC -includes dateitime/lDlAnalysis Matrix: es GNo ❑WA 12. All containers needing preservation have been checked. All containers needing preservation are found to be in compliance vrith EPA recommendation. exceptions' A coliform. TOC, O&G. NJI-DRO (waler) es ❑No IXes ❑No JN° {]NIA ❑N14 13, Initial when C mpleted Lot # o prese added ative Samples checked for dechlorination: ❑Y05 ❑No EWA 14. Headspace in VOA Vials >5mm : ❑Yes o ❑NIA 15. Trip Blank Present: Trip Blank Custody Seals Present Race Trip Blank Lot # (if purchased): Dyes ❑yes C9b-_ ❑NI ❑iNo N'A 16, Client Notification/ Resolution: Person Contacted: Comments/ Resolution: DatelTime: Field Cita Required? Y ! N Project Manager Review: Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form wnll be sei it to the North Carolina DEHNR Certification Office ( i.e out of hold. incorrect preservative, out of temp. Incorrect containers) F-ALLC003rev.3, 11 SeptKage'I?%� 31