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HomeMy WebLinkAbout1302_Cabarrus_Unit1_MSWLF_GW_FID1323277_20190624Cabarrus County Sanitary Landfill — Unit 1 Semi -Annual Sampling Report Facilit� Permit # 1302-MSWLF-1974 (May 2019 Sampling Event) 1792 repared June 2019 pENR USE ONLY OP p R p N i]EI t IC Data-EmaII CD (tlata oaded'Yes/No DOGEvent#: C DENR Environmental Monitormg Division of Waste Management- Solid Waste RepO1'dng Form Notice: This form antl any information attached to It are "Public Rewrtls° as defined In NC Geneal Statute 732-1. As such, these tlacuments are available far inspecNlon antl examfna8on by any person upon request (NC General Statute 132-6). Instructions: • Prepare pnetorm ror aeon malmaaany mommrea nmt. PleaseType or print legibly. • Attach a notl8cetion [able with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standeMs. The notification must include a preliminary analysts of the cause and significance of each value. (e.g. naturally occurring, oR-site source, pre-existing wndition, etc.). • Attach anoti8cation table of any grountlwater or sudaca water values that equal or exceed [he reporting limits. • Attach a notigcagon table of any methane gas values that again or exceed explosive gas levels. This includes any sWctures on or nearby the facility (NCAC 13B .1629 (4)(a)(I). • Send the original signed antl sealed form, any tables, and ElecUonic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1848 Mall Service Center, Raleigh, NC 2]699-1646. Solid Waste Monitoring Dafa Submittal Information Name of entity submltting tlata (laboratory, consu.Un[, facility owner) Consultant - CDM Smith Inc. Contact (or questions about data formalgng. Include data preparer's name, telephone number and E-mail address: Name: Mathew F. Colone Phone: (919) 3253500 E-mail: I mffdcd gh NC Lantlflll Rule: Actual sampling tlates (e.g., Facility name: Facility Address: Facility Permit# (.05000 1800) October 20-24, 2008) Cabarrus County Landfill Unitl Conlwrd�NarthtCarol na 2a025 1974 MSWLF- .0500 May]-8, 2019 Environmental Statue: (Check all that apply) ❑ Initialleackgrcund Monitoring ❑X Detection Monitoring ❑ Assessment Monitodng ❑ Corrective Action Tyyypppe of tlata submlltetl: (Check all that apply) IXI Grountlwater monitoring data from monitodng wells ❑ Methane gas monitodng date Illr—ylll Grountlwater monitoring tlata from pdvate water supply wells ❑ Corrective action data (speGfy) Leachate monioring data ❑ Other(specify) S rt t t 9d t Notification attachetll No. No groundwater or surface water standards were exceeded. e Ves, a notigcaUon of values excelling a gmundwater or surface water standard is attached. It inclutles a Ilst G groundwater and surface water onitoring points, dates, analytical values, NC 2L grountlwater standartl, NC 28 surface water standard w NC Solitl Waste GWPS and preliminary analysis of the cause end significance of any wncen[ragon. ❑ Ves, a notifwtion of values exceetling an explosive methane gas Ilmit is atlacM1ed. I[ Inclutles the methane monitoring points, dates, sample values and explosive methane gas limits. CeHification Tc the best of my knowletlge, the informallon reported antl statements made on this tlata submittal antl attachments are true antl correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding grountlwater s[antlartls ar explosive gas levels, antl a preliminary analysis of [he cause and significance of concentrations exceeaing groundwater standards. I am aware [hat there are significant penalties for making any false statement, represanlation, or certiFlcation including the pocsibility of a fine antl imprisonment. Affix NC LicgA�eQ,jP(We_sk'�oj,p��C2plogist Seal F 5400 GI d A Su � 400 Ralei h N rth Carolina 2]612 Faulity Representative Adtlress NC PE Firm License Number (if applicable a#ecgve May 7, 2W9) _ F. t Revisetl 612009 / y��5(' Smith 5400 Glenwood Avenue, Suite 400 Raleigh, North Carolina 27612 tel: 919 325-3500 fax: 919 781-5730 June 24, 2019 Ms. Jaclynne Drummond North Carolina Department of Environmental Quality Division of Waste Management Solid Waste Section 2090 U.S. 70 Highway Swannanoa, North Carolina 28778 Subject: May 2019 Semi -Annual Sampling Report Cabarrus County Unit 1 Landfill Facility Permit No. 1302-MSWLF-1974 Dear Ms. Drummond: CDM Smith Inc., on behalf of Cabarrus County, is submitting an electronic copy of the May 2019 semi- annual sampling report for the recent event completed at the Cabarrus County Unit 1 Landfill. This letter report constitutes the first semi-annual sampling event for 2019. The approved monitoring well network consists of compliance wells MW-5, -7, -8A, -10, -11, and background wells CD-1s and -1d. The monitoring network also includes surface water sample locations SW-1 and -2. Field activities and sampling results for the groundwater and surface water samples are discussed below. Field Activities Groundwater and surface water samples from the Cabarrus County Unit 1 Landfill were collected on May 7-9, 2019. Groundwater samples were collected from the monitoring wells by use of disposable, laboratory decontaminated TeflonT" bailers or a QED bladder pump system using low -flow sampling techniques. Monitoring well and surface water sample locations for the Unit 1 landfill are provided on Figure 1. Groundwater elevations were measured at each well prior to sampling and are presented in Table 1. Well construction details for each monitoring well are also provided in Table 1. These groundwater elevations were used to construct potentiometric contours for this sampling event and are presented on Figure 1. After depth to groundwater was measured, each well was purged prior to sampling to provide fresh formation water within the well water column. Each purge volume was measured for pH, conductivity, turbidity, temperature, dissolved oxygen, and oxidation-reduction potential using a YSI Pro Plus multi -parameter water quality meter and Micro TPI or TPW turbidity meters. The water quality parameters at the time of sampling are presented in Table 2. The headspace of each monitoring well was screened for methane gas using a RKI Eagle multi -gas monitor. Screening results are provided in Appendix A. Of WATER + ENVIRONMENT +TRANSPORTATION + ENERGY + FACILITIES Smith Ms. Jaclynne Drummond June 24, 2019 Page 2 Sampling Results Pace Analytical Services, Inc., located in Peachtree Corners, Georgia, analyzed the groundwater samples for North Carolina Appendix I volatile organic compounds (VOCs), including 1,4-dioxane, and metals. Samples collected from CD -Is and -1d were also analyzed for tetrahydrofuran, iron, mercury, manganese, alkalinity, total dissolved solids (TDS), chloride, and sulfate. The analytical results were reported to the laboratory specific method detection limit (MDL) and are quantifiable at or below the method reporting limit (MRL). All monitoring wells for the Unit I Landfill had detections of analytes above the MDL but below the MRL. These detections were qualified as estimated or "J" flags. The following list indicates the VOCs and metals detected above the MRL at each sampling location. No "J" flag detections are provided. Underlined analytes exceeded the 15A NCAC 02L .020 (NC 2L) Groundwater Quality Standard, Interim Maximum Allowable Concentration (IMAC), or 15A NCAC 02B or North Carolina Protective Value Surface Water Quality Standards for Class C Waters. CD-1s (Background) General Chemistry: Metals: Volatile Organic Compounds CD-1d (Background) General Chemistry: Metals: Volatile Organic Compounds MW-5 Metals: Volatile Organic Compounds MW-7 Metals: Volatile Organic Compounds MW-8A Metals: Volatile Organic Compounds Alkalinity, Chloride, Nitrate, Sulfate, TDS Barium, Iron, Manganese None Detected Alkalinity, Chloride, Nitrate, TDS Barium, Iron None Detected Barium, Cobalt, Nickel 1,4-Dichlorobenzene, Benzene, Chlorobenzene, 1,4-Dioxane Barium, Cobalt, Nickel 1,4-Dichlorobenzene, Benzene, Chlorobenzene, cis-1,2- Dichloroethene, 1,4-Dioxane Barium, Cadmium, Cobalt, Copper, Lead, Nickel, Zinc 1,4-Dioxane 0 Smith Ms. Jaclynne Drummond June 24, 2019 Page 3 MW-10 Metals: Arsenic, Barium, Cobalt, Nickel Volatile Organic Compounds: 1,2-Dichlorobenzene, 1,4-Dichlorobe nzene, Benzene, Chlorobenzene, Tetra hydrofuran, 1,4-Dioxane MW-11 Metals: Barium, Cobalt, Nickel Volatile Organic Compounds: 1,4-Dichlorobenzene, Chlorobenzene, 1,4-Dioxane SW-1 Metals: Barium, Nickel Volatile Organic Compounds: 1,4-Dioxane SW-2 Metals: Barium, Nickel Volatile Organic Compounds: 1,4-Dioxane "J" flags were not included in the previous list, but several locations had "J" flag detections that exceeded the standards. These constituents along with their location are listed below. Antimony: MW-8A Vanadium: CD-1s, -1d, -5, -7, -8A, and -10 A trip blank and duplicate sample were analyzed for quality control. The trip blank had estimated detections of acetone and 1,4-dioxane below their respective NC 2L Standards. The duplicate sample, identified as Dup, was collected from MW-7 and had similar analyte concentrations as those detected in MW-7, with the exception of an estimated detection of selenium below its NC 2L Standard in the duplicate sample. Metals detected above the standards are likely natural occurring based on concentrations in the background monitoring wells or are from elevated turbidity at the time of sample collection. VOCs detected above the standards in several of the compliance monitoring wells will be compared to future detections to determine if any trends appear. A summary of detected constituents above the standards from the May 2019 sampling event is presented in Table 3. The laboratory analytical report is provided in Appendix A. The next semi-annual sampling event will be completed in the fall of 2019. If you have any questions or require further explanation, do not hesitate to call me at (919) 325-3500 or by email at colonemf@cdmsmith.com. 0 cSmith Ms. Jaclynne Drummond June 24, 2019 Page 4 Very truly yours, Mathew F. Colone, P.G. CDM Smith Inc. cc: Kevin Grant, Cabarrus County iD Table 1 Monitoring Well Construction Summary and Groundwater Elevations May 2019 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Notes: 1. BTOC - Below Top of Casing 2. bgs - Below Ground Surface 3. PWR - Partially Weathered Rock Smith Page 1 of 1 June 2019 Table 2 Water Quality Measurements May 2019 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Water Quality Measurements Facility Permit Monitoring Well .. ..Number pH Conductivity Temperature .• Oxygen CD-1s 1302-MSWLF-1974 5.26 116 15.0 7 1.82 242.4 (background well) CD-1d 1302-MSWLF-1974 5.69 114 18.3 9 1.61 183.2 (background well) 1302-MSWLF-1974 MW-5 6.41 188 15.5 9 3.42 -0.1 1302-MSWLF-1974 MW-7 6.56 2,541 16.1 10 1.22 -29.1 1302-MSWLF-1974 MW-8A 6.52 366 15.1 6 4.45 -27.7 1302-MSWLF-1974 MW-10 6.62 2,021 16.1 10 1.73 -51.2 1302-MSWLF-1974 MW-11 6.01 499 14.3 3 1.63 82.8 Surface Water Sample Locations 1302-MSWLF-1974 SW-1 7.17 357 18.9 11 4.06 120.1 1302-MSWLF-1974 SW-2 6.74 473 19.8 9 5.07 174.1 Notes: 1. Water quality measurements were taken on May 7-9, 2019. 2. µS/cm - Microsiemens per centimeter 3. mg/L - Milligrams per liter 4. ORP - Oxidation -Reduction Potential 5. NTUs - Nephelometric Turbidity Units 6. mVs - Millivolts 7. S.U. - Standard Units Smith Page 1 of 1 June 2019 Table 3 Constituents Detected Above Standards May 2019 Semi -Annual Sampling Event Unit 1- Cabarrus County Landfill Facility Permit Number 1302-MSWLF-1974 Above.. StandardsFacility Permit Number Monitoring Well Code Constituents I I Maximum Allowable Concentration .. . CD-1s 1302-MSWLF-1974 Iron Vanadium* (background well) CD-1d 1302-MSWLF-1974 Iron Vanadium* (background well) 1302-MSWLF-1974 MW-5 Cobalt*, 1,4-Dichlorobenzene, Benzene, 1,4-Dioxane Vanadium* 1302-MSWLF-1974 MW-7 Cobalt*, 1,4-Dichlorobenzene, Benzene, 1,4-Dioxane Vanadium* 1302-MSWLF-1974 MW-8A Cobalt* Antimony*, Vanadium* Arsenic, Cobalt*, Nickel, 1,4-Dichlorobenzene, 1302-MSWLF-1974 MW-10 Vanadium* Benzene, 1,4-Dioxane 1302-MSWLF-1974 MW-11 Cobalt*, 1,4-Dioxane None Detected Notes: 1. * - Exceeds the Interim Maximum Allowable Concentration for Subtitle D Landfills closed after 1993. 2. Estimated detections above the standards are "J" flag detections that indicate the analytical result is between the method detection limit and the method reporting limit. Smith Page 1 of 1 June 2019 n I n I n I n I WE I n I n I n GW 0. 1� Z� / ITC-15 � /%1 � \ M-1 GW 726.89y xI EXIS"ING \ P ��0 &D, LANDFALL COVER MATERIAL m,PH ES I AND II STOCKPILE o S CTIVE) P-2 0 ERMIT 1-, 2 CDLF-2008 _8 MW�s IN > ° r $CD1 ABANDON9° CD-3 AB D ' A. .-7 $ , BAB�ND I D NED SEDIMENTATION POND4ZO ...� LAN FI'F`L PA SI ,., 200 0 400 MOW-13 ° \ 7 I ABA DON �� I ' ,,,., >_ °'°'° w, °• _ IRISH POTATO R AD ANDF L APPROX LIMI E EXPANSION ' P ROXq=WASTE B U R OLD FILL 'A / CATEGORY 2 II a UNIT 1 / ,x CLOSURE A E MS 41DFILL' UNIT 2 (INACTIVE/ CDLF OVER PE MIT 1302-MSWLF-19 NAnIV o c PE IT 2- S SRM1T 02-C L 1 9 MW J 1 2 GW 700.851 8i► GW 12 CMG W GW N _ � 8 x X ° $9.4 NM x ,.,.z 0 I 93.51 i ; W MW A B-4 � ° ri MW-7 GW 707 3 / � h6W G o MW-5 G1111681.10 LEGEND I 69 .17 ORR nn I '69 - -� ■M-1 MONITORING WELL \\ > w PROJE TE BO DA Y - ( "I d' / • �P-1 \\ i E 8 OF P, T 6 ° \ / OCT OB 9 9 3 M METHANE PROBE MW-5 MONITORING WELL WITH GROUNDWATER ELEVATIONS U MGW 679. 2. 7 ORROW AR Sv MSED) n AL I \ 9�t (INACTIVE ' / OMW-6 ABANDONED GROUNDWATER MONITORING WELL I PERMIT 1302- r n I / ) SW-1 SURFACE WATER SAMPLING STATION PERMIT 1392-CDL 9987 I SW'1 / / -�- - -� ---- ��/ MGW-3 1 m (713) ESTIMATED ELEVATION OF WATER TABLE \ / ----- ,•,, -0 0P-1 PIEZOMETER - �- POTENTIOMETRIC CONTOUR m- O 2.9 8 _ 7, � r _ /' _ MGW-1 METHANE GAS MONITORING WELL GW ¢ 8.28 MW M DEEP GW 67 . 7_ M -I D 667 47 AMW-1 S AMW-1 IIII' NOTE: D GW 679.25 : ,e 679.12 -SW-2 \, a) - 1. MW-A THROUGH M, ALONG WITH MW-1-3 AND M-3 DEEP COMPRISE THE GROUNDWATER MONITORING WELLS FOR UNITS 2 AND 3 WHICH ARE PART OF THE APPROVED MONITORING SYSTEM. CD-4, CD-5, AND CD-6 WERE ADDED TO THE GROUNDWATER MONTORING NETWORK IN SEPTEMBER 2006. 2. MGW-1 THROUGH MGW-14 ARE METHANE GAS MONITORING WELLS. 3. MW-517, 8A, 10, AND 11 ARE THE APPROVED GROUNDWATER MONITORING WELLS FOR UNIT 1. CD-iS AND CD-iD SERVE AS THE BACKGROUND WELL FOR UNITS 1, 2, 3, AND • ° M HD P AMyy_2s yy 6Z,5,5r� ° °°°' °0 ° AMW-2D n' ° ;n, THE C&D LANDFILL. W 67 32 :,;, j 'ate 0 4. CD S, CD-i D, CD-2, AND CD-3 ARE THE APPROVED MONITORING WELLS FOR THE C&D LANDFILL AND CD-4 REP WAS INSTALLED AS PART OF THE C&D PHASE I EXPANSION. e '- _a° W-L DEEP -M� 5. GROUNDWATER ELEVATIONS MEASURED ON MAY 6, 2019. \\\ G Iv56.47 I M DEEP ! "� ry• y, 6. ASSESSMENT WELLS AMW-i S, -lD, -2S, AND -2D WERE ADDED TO THE GROUNDWATER MONITORING NETWORK IN OCTOBER 2009. 6 _60. 7 \ J ,� \ 7. CD-4 AND CD-5 WERE ABANDONED IN JULY 2010. 60 6 \ 8. MW-9 WAS REMOVED FROM THE MONITORING PROGRAM. mw-m \ 9. CD-7 AND CD-8, FORMERLY PIEZOMETERS B-7 AND 8-19 RESPECTIVELY, WERE ADDED TO THE - MONITORING PROGRAM IN JULY 2014. 6 10. CD-3 WAS RELOCATED IN JULY 2014. DESIGNED BY: A. WEISPFENNING DRAWN BY : J. KIUINcswoRTH SHEET CHK'D BY: D. FORBEs CROSS CHK'D BY: M. COLONE APPROVED BY: D. FORBES DATE_ JUNE 2019 CDM. ��'�� GDM GI.-.e. Av MOO Glerrxootl e, Suite 490 INGF-h,NC2]812Te1:(919)32535900.12 NCR- CABARRUS COUNTY NORTH CAROLINA SEMI-ANNUAL GROUNDWATER MONITORING CABARRUS COUNTY LANDFILL FACILITY PERMIT #13-02 POTENTIOMETRIC SURFACE MAP PROJECT NO. 1278-231402 FILE NAME: CAB-S-I9.DWG FIGURE N0. DATE DRWREV N CHKD REMARKS Appendix A Client Name: Client Contact: Project: Site: Note: MONITORING WELL DATA SUMMARY Camp, Dresser, & McKee Mr. Mat Colone Semi-annual Ground Water Monitoring Cabarrus Co. Landfill - Unit 1 1 DTW - Depth to Water From Top of Casing (ft.) Well ID DTW 1302-MW-5 11.97 1302-MW-7 1.34 1302-MW-8A 4.63 1302-MW-10 7.20 1302-MW-11 12.15 1302-CD-1 S 28.11 1302-CD-1 D 26.89 Page 1 of 1 Report No.: 2618286 2618294 Sampling Date: 05/06/19-05/10/19 Sampled By: W.Flammer, J.Mueller Field Specialist(s) Reviewed By: r�c�, iel ices Manager MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitoring Site: Cabarrus Co. Landfill - Unit 1 Note: 1 % Vol - Volume of Methane Gas in Headspace Well ID % Vol 1302-MW-5 0 1302-MW-7 0 1302-MW-8A 0 1302-MW-10 0 1302-MW-11 0 1302-CD-1 S 0 1302-CD-1 D 0 Page 1 of 1 Report No.: 2618286 2618294 Sampling Date: 05/06/19-05/10/19 Sampled By: W.Flammer, J.Mueller Field Specialist(s) Reviewed By: i Services Manager MONITORING WELL DATA SUMMARY Client Name: Camp, Dresser, & McKee Client Contact: Mr. Mat Colone Project: Semi-annual Ground Water Monitoring Site: Cabarrus Co. Landfill - Unit 1 Report No.: Sampling Date: 2618286 2618294 05/06/19-05/10/19 Well ID BOCK DTW2 -Wellurge V013 4 VO1 pHs SCS Temp Turb" D09 ORP10 F Comments 1302-MW-5 32.12 11.97 9.85 6.50G 6.41 188 15.5 8.72 3.42 -0.1 No odor 1302-MW-7 22.03 1.34 10.11 10.25G 6.56 2541 16.1 9.81 1.22 -29.1 No odor 1302-MW-8A 25.24 4.63 10.07 9.00G 6.52 366 15.1 5.71 4.45 -27.7 No odor 1302-MW-10 35.38 7.20 13.78 10.50G 6.62 2021 16.1 9.73 1.73 -51.2 No odor 1302-MW-11 25.58 12.15 6.56 6.75G 6.01 499 14.3 3.17 1.63 82.8 No odor 1302-CD-1 D 52.32 26.89 - 24.20L 5.69 114 18.3 9.14 1.61 183.2 No odor 1302-CD-1 S 29.91 28.11 - 11.201- 5.26 116 15.0 7.13 1.82 242.4 No odor Notes: 1 BOC - Bottom of Casing (Ft.) 2 DTW - Depth to Water from Top of Casing (Ft.) 3 Well Vol - Calculated at 3 Times One Well Volume (Gal.) 4 Actual Volume Evacuated Prior to Sample Collection (Gal.) 5 pH - Reported in Standard Units 6 SC - Specific Conductance (uS/cm) 7 Temp - Temperature (°C) 8 Turb - Turbidity (NTU) 9 Dissolved Oxygen (mg/L) 10 ORP mV Page 1 of 2 Sampled By: W.Flammer, J.Mueller Field Specialist(s) Reviewed By: Services Manager Client Name: Client Contact: Project: Site: Notes: SURFACE WATER SAMPLING DATA SUMMARY Camp, Dresser, & McKee Mr. Mat Colone Semi-annual Surface Water Monitoring Cabarrus Co. Landfill - Unit 1 Report No.: 2618286 2618294 Sampling Date: 05/06/19-05/10/19 Point ID pH SC Temp Turb DO ORP Comments 1302-SW-1 7.17 357 18.9 11.2 4.06 120.1 1 No comment 1302-SW-21 6.74 1 473 1 19.8 1 8.78 1 5.07 1 174.1 1 No comment 1 pH - Reported in Standard Units 2 SC - Specific Conductance (uS/cm) 3 Temp - Temperature (°C) 4 Turb - Turbidity (NTU) 5 DO - Dissolved Oxygen (mg/L) 6 ORP - Oxidation/Reduction Potential (mV) Sampled By: W.Flammer, Mueller Field Specialist(s) Reviewed By: Q el ices Manager WELL INTEGRITY AND WATER LEVEL FORM Project Name: Site Location: Field Personnel: Cabarrus County Landfill Units 1 Concord North Carolina Date: � e ,1 1 Weather: W. L. Measuring Method: 23 'r"v Page i of Z` •+ O� 16 C n• N N (A a Water Level Sounded C-. m m 3 y c C.. s '~ o c� w m w- f6 f6 c m Well ID TIME BTOC ( ) De th F (BTOC) m -• m f6 .c �' y M u; m y 0 o 2 — CL N o y •a ca o �` c' O o N a) 3 C- O O 'a mts 0 > O w+ =° � C U Comments (feet) (feet) o f6 coi " o a —� m f6 m e 0 ca _ o 0 _ n v " r- m m t n °: a) 0 y — c o U O U m C > C t a 3 N O o 0 J t�oi N N N N N (Ty N N N PyA NCD-1D ILEL=(O �P •l ✓ Ja NA NA NA NA NA NA NA NA NA A A O 2= �� •7 Lg C �c� iG G` \ N N 4 Y N -7Y 4 YU N N N Yeov QJ N N fCZE �i�ouk5 PS CD-1 S 1 \ V 1 NA NA A NA NA NA N NA NA O LEL= 2_ T%> '[ N N (B) N N N N N N A N N ZO MW 5 ✓ 1 NA NA NA N6 NA NA NA NA W NA NA LEL= Cr O 2 Y Y Y Y Y N O Mw 7 NA NA NA NA N©A NA NA kA NA LEL= f� 2=.,`� 2 (�� ` N N N N N N LEL= v O _ MW 8A .�j3 •2 NA NA ► z=�tb, Y Y Y Y Y `JU7 J 2� 3 N N V� N N N N LEL= 05 O MW 10 0 NA NA NA NA NA NA NA 2=70.0 IryY Y Y Y N N to NA N ® N N N N(,� N N GU MW 11 b v U NA NA A NA NA NA NA NA NA NA NA LEL= S� O 2= Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= O 2= Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N N N NA NA NA NA NA NA NA NA NA NA NA NA LEL= O 2= Y Y Y Y Y Y Y Y Y Y Y Y N N N N N N N N N N N N NA I NA I NA I NA NA NA NA I NA NA NA I NA NA LEL= O 2= I have received this Well Integrity and Water Level Form(s): Signature Date 7 TO aceAnalytfcal FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: 2 " Site Name: barrus County Sanitary LandfillAJnits 2 & 3 Casing Material: PVC Field Personnel: vW. Flammer 1.Mueller Ul 'L,c t) Dedicated Pump: �o Sw&, e, ID#: ' 130i.-LD-1 Date: S. +.\0\ Weather Conditions: C`e,,,'��3 o,^KL� Total Well Depth in feet (TWD) = 1 `\ - `� \ Depth to Ground Water in feet (DGW) = 2 -tZ Length of Water Column (LWC) = TWD - DGW = 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: l Casing Volume in gallons (CV) = LWC x 0.653 = ' Standard Evacuation Volume (3 casing volumes) = Total Volume of Water Removed (gaHans)-- Cc-1-. (1 • to L, Method of Well Evacuation: Method of Sample Collection: T5 Well Yield (subjective): Goal Sample Date and Time: 5.1 - V �5 i '• 31 ��5 3 ,2 Time (military) U3;a 0 5S� OS�� a`�e5 �`1�� C'�itS o`�tO C`1L� Q'1'L� 0 • o b 5 ob 6 . o�� 00 `� oo °1 •oo ��.ec IQ (n� i •2� Volume Purged (OaHons� L 1 Water Level (ft.) stable S 7} 5 •�`" 5•�u 5.�� 5 1l0 �-t� S�tCo pH(s.u.) t2 1 t v l� . y ►3 1 l b 1S -0 tl 11 1cl .�j 1A .c \2 0 1`1 b �"� 1l a� `i 1�. 111 l3• jk 5 `� 11 i Ut i l b + 13 Sp. Cond. (µmhos/cm) t +0 Water Temp. (°C) constant Turbidity(NTU) f+0%or,5NTU Dissolved Oxygen (mg/L) tio% RedOxPotential/ORP(mV) t+otnv L • =�`1 L�l�.N 1 `d"t Z,�l •io `� 1. 2��o.S 1 `b3 �L`15 in 1 'b'� 2y3.1 l �3 i`i3•� i $ Z`1'1•� (`b1 2y� I I.�S iyl. ` Q1 �"t�11.'� YV1L�tM t'tr -- L ®D lot) l00 '1 LAC jJ1i L174 (Vl? LOB COMMENTS/OBSERVATIONS: UL4 , rio O To 2-1 - Q7 . 00 V'.ci /L Date: CJ A r Page of aceAnalytical ' Client: Site Name: Field Personnel: C4)- FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Camp, Dresser & McKee Inc. - Raleigh lCasing Diameter: 2 Cabarrus County Sanitary Landfilj4Jnits 2 & 3 1 Casing Material: Wc, ,W. Flammer J.Mueller U y C $ Dedicated Pump: No Date: G a • \'A Weather Conditions: Li-A.V C.ia A , Total Well Depth in feet (TWD) = ":) 1.3L Depth to Ground Water in feet (DGW) _ ILL $`1 Length of Water Column (LWC) = TWD - DGW = 2" Well: I Casing Volume in gallons (CV) = LWC x 0.163 = 4" Well: I Casing Volume in gallons (CV) = LWC x 0.653 = �C Standard Evacuation Volume (3 casing volumes) _ Total Volume of Water Removed (gales): L 1— Method of Well Evacuation: Method of Sample Collection: Well Yield (subjective): bt o s Sample Date and Time: 5 . " 1� L ITime(military) `oo \ IOJi 10'9.�1 \i7`t�} iu5f'1 #�®q i \� t^�� it�,y 15fA 12c�2 ila; Volume Purged (Gam} V-) 0 1.001 i3 00 �S -Lx 2Z Ja n oD •��v LFi .'� Water Level (ft.) stable (, . 2� 1} L1 `'(� b`I L�.(,•� Z•}•b'J 'i pH(s.u.) t z rj cif 5• t'+ � (a J log 5 %L Fj. f� rj I LA�•(,'� Sp. Cond. (µmhos/cm) t to i l l S �t 't\ `� i to ilia t1QS t22) 1 itQ L 1 \`3 Water Temp. (°C) constant Z,t .'L % 1`1 •IDA 0 1 $ `11 `'1. (() s 1 `l� • IAt 1 1 l \ Ql� .I Turbidity(NTU) tloiot<_srrru %2p. 200 51%. 10 �•i�l Dissolved Oxygen (mg/L) tloi 1.S\ %l i 56 i•ioZ i.i>r3 i.l,j 1 b3 \ b`6 1 S`d + 6y 6`t i.lo RedOxPotential/ORP(mV) tlonv 1�\(o.0 l"a,I ��� `�t 1l,(,.� 1'I3.b i��•1 1�(� 't��•2 i�0 J \t3 AliZ- ^ LVO ZOO iu �� 2cro l ub ZuJ LUO 2U'J 2u p ZocS COMMENTS/OBSERVATIONS: W C.-W ON +s-f n() 0./ (� s.J�v, nt jilt J 5.- Date: �.\r` By: Page 2 of 7 aceAnalytical FIELD DATA INFORMATIONLOG FOR GROUND -RATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: ' Site Name: Cabarrus County Sanitaiy Landfill Unit 1 Casing Material: Field Personnel: ; er e_� Dedicated Pump: (� Surface Water ID #: Sol - Date: S" Z (cl Weather Conditions: SLkv Method of Well Evacuation: ; R�_ Total Well Depth in feet (TWD) = 3),. \a Method of Sample Collection: er Depth to Ground Water in feet (DGW) _ k\ Cil Well Yield (subjective): �6- Length of Water Column (LWC) = TWD - DGW = �Q, (5 Sample Date and Time: 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = @ o tW 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Standard Evacuation Volume (3 casing volumes)_ Total Volume of Water Removed (gallons): C. SO Time (military) Volume Purged (Gallons) 0 S.sO r 5 U .S oa, Water Level (ft.) stable - — - pH (s.u.) t z Sp. Cond. (µmhos/cm) t 10% lu-1 Water Temp.(°C) constant Turbidity (NTU) :k10 or:55N u 10O.'r oo r Dissolved Oxygen (mg/L) tlo % 3, RedOx Potential/ORP (mV) tlomv - i _ , a. - 001 COMMENTS/OBSERVATIONS: m0 o Date: jkh By: Page of aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: Q Field Personnel: Dedicated Pump: ► D Surface Water ID #: 'jp - .Z Date: 5 Weather Conditions: Method of Well Evacuation: 40'r Total Well Depth in feet (TWD) Method of Sample Collection: c Depth to Ground Water in feet (DGW) _ , 3H Well Yield (subjective): N 6u 0 Length of Water Column (LWC) = TWD - DGW = oti7. 69 Sample Date and Time: o -1ft • Jt4 / 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 3.3'i 3 so ' lq oCOS3O 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = — I N Standard Evacuation Volume (3 casing volumes) = 10, \.k1C�, S Total Volume of Water Removed (gallons): `0 a Time (military) tvl3O ' W35' 14 q Volume Purged (Gallons) 0 'S So -1.00 l . ")Is - Water Level (ft.) stable - — pH (s.u.) t z (, .3� , J� , ��� �O • S(O Sp. Cond. (µmhos/cm) t io % Water Temp. (°C) constant ( lS Turbidity (NTU) ±10 or:5 5 NM S� 007 k Uo-r Dissolved Oxygen (mg/L) jj ^ , RedOx Potential/ORP (mV) tiomv - � - -�,� - R. COMMENTS/OBSERVATIONS: lead p o Date: �' „ ;' _ By: Page 6 of a ce Analytical t{al FIELD DATA INFORMATIONLOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: (, Field Personnel: w .1 \1 Dedicated Pump: J�J Surface Water ID Date: Weather Conditions: S-kitrAl jvkJ Method of Well Evacuation:` Total Well Depth in feet (TWD) = aS , N Method of Sample Collection: ed' Depth to Ground Water in feet (DGW) _ 14,6.3 Well Yield (subjective): o0 Length of Water Column (LWC) = TWD - DGW = Q61 Sample Date and Time: I \ 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = 3, h-S- oj,a 7 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = Ll 2T -- 5 ,rl 1 Standard Evacuation Volume (3 casing volumes) = (Q Total Volume of Water Removed (gallons): v C(, Time (military) 90 13 1-7 3 3S 1.3 1 f Volume Purged (Gallons) 0 , j c7 "� ,©� iv q. 06 00 Water Level (ft.) stable pH (s.u.) t.2 .30 , ,3 C . 3r Sp. Cond. (µmhos/cm) t io % Lk 1� Water Temp. (°C) constant Turbidity (NTU) tto %or<5taro n0 OO+ 8 ." Dissolved Oxygen (mg/L) fto % 3 V 41S RedOx Potential/ORP (mV) doenv q .0 - COMMENTS/OBSERVATIONS: CI0UA\ Kxi Q Date: 13 . Page S— of 7 aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Cam , Dresser & McKee Inc. - Raleigh Casing Diameter: a `' Site Name: Cabarrus County Sani Landfill Unit 1 Casing Material: v!✓ Field Personnel: W7cooklne, Dedicated Pump: O0 Surface Water ID #: Q 10 Date: S 1 kc, Weather Conditions: Method of Well Evacuation: ; Total Well Depth in feet (TWD) = 3 S Method of Sample Collection: ; e Depth to Ground Water in feet (DGW) _ "� , ).Q Well Yield (subjective): boo( - Length of Water Column (LWC) = TWD - DGW = )IRF11. \i Sample Date and Time: VhAqa(C lg 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = Lk.S ,pv) C1 P, (D75-3 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = — A1jr0 - q Standard Evacuation Volume (3 casing volumes) = m,pO Total Volume of Water Removed (gallons): a, 0 Time (military) (S S� V.01 i (01 1 !' Volume Purged (Gallons) 0 5 QJ `0 00 'v 10 ro 10. 6qca Water Level (ft.) stable — — -- — pH (s.u.) t.z 6.11 61-1U 6.10 G. 60 a Sp. Cond. (µmhos/cm) t 10 WZ PI -w2 1091 Water Temp. (°C) constant (�, k&, Turbidity(NTU) ±10%or:55N u icy) � t �00} , Soo�- Dissolved Oxygen (mg/L) do % Q RedOx Potential/ORP (mV) :io.v COMMENTS/OBSERVATIONS: Ova 0 Date: Page �; of -tk-�r �< aceAnalytical FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: PC Field Personnel: O,h Q,( Dedicated Pump: AID Surface Water ID #: Date: Weather Conditions: Method of Well Evacuation: Total Well Depth in feet (TWD) _ Method of Sample Collection: &1er Depth to Ground Water in feet (DGW) = j Well Yield (subjective): Cymcj Length of Water Column (LWC) = TWD - DGW = I 3 Sample Date and Time: S c(101-7 2" Well: 1 Casing Volume in gallons (CV) = LWC x 0.163 = ( a.;2S e —4-141lig 0 y 4" Well: 1 Casing Volume in gallons (CV) = LWC x 0.653 = / Standard Evacuation Volume (3 casing volumes) _ C' S ( - Total Volume of Water Removed (gallons): 6,-7j Time (military) ,;,� 0�� 1 1 Volume Purged (Gallons) 0 Water Level (ft.) stable — — — pH (s.u.) i s (�(a 7 6, o Sp. Cond. (µmhos/cm) t io Water Temp. (°C) constant Turbidity (NTU) fio ^i at <s NW �f�O r Q'QQ + 0D �t Dissolved Oxygen (mg/L) tio^i ' 3 RedOx Potential/ORP (mV) COMMENTS/OBSERVATIONS: d o(J Date: By: &a4 25, Page I of / � aceAnalyt' FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: NA Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: NA Field Personnel: W.Flammer J.Mueller Dedicated Pump: NA Surface Water ID Date: Weather Conditions: Method of Well Evacuation: NA Total Well Depth in feet (TWD) = NA Method of Sample Collection: NA Depth to Ground Water in feet (DGW) = NA Well Yield (subjective): NA Length of Water Column (LWC) = TWD - DGW = NA Sample Date and Time: 1 ti j S 2" Well: I Casing Volume in gallons (CV) = LWC x (NA 4" Well: I Casing Volume in gallons (CV) = LWC x (NA Standard Evacuation Volume (3 casing volumes) = NA Total Volume of Water Removed (gallons): NA Time (military) it Volume Purged (Gallons) 0 Water Level (ft.) stable pH (s.u.) t 2 Sp. Cond. (µmhos/cm) t io % 3S'� Water Temp. (°C) constant Turbidity (NTU) do %o.<srw 10 Dissolved Oxygen (mg/L) fio % . 0 G RedOx Potential/ORP (mV) tiotnv Z p , n COMMENTS/OBSERVATIONS: `,b-&-/l Ro C) Date: By: � - --- �% Page L of acreAnaiyticai FIELD DATA INFORMATION LOG FOR GROUND -WATER SAMPLING Client: Camp, Dresser & McKee Inc. - Raleigh Casing Diameter: NA Site Name: Cabarrus County Sanitary Landfill Unit 1 Casing Material: NA Field Personnel: W.Flammer J.Mueller Dedicated Pump: NA Surface Water ID #: Date: Weather Conditions: Method of Well Evacuation: NA Total Well Depth in feet (TWD) = NA Method of Sample Collection: NA Depth to Ground Water in feet (DGW) = NA Well Yield (subjective): NA Length of Water Column (LWC) = TWD - DGW = NA Sample Date and Time: ( 2" Well: 1 Casing Volume in gallons (CV) = LWC x (NA 4" Well: 1 Casing Volume in gallons (CV) = LWC x (NA Standard Evacuation Volume (3 casing volumes) = NA Total Volume of Water Removed (gallons): NA Time (military) Volume Purged (Gallons) 0 Water Level (ft.) ale -- pH (s.u.) t .z Sp. Cond. (µmhos/cm) t io% iA13 Water Temp. (°C) constant 1c1 . q Turbidity (NTU) +10 or:55NTu Dissolved Oxygen (mg/L) tio^i Ste, RedOx PotentiaUORP (mV) tiotav 'lL _ COMMENTS/OBSERVATIONS: I ( 0( 1 �'d1nJ r t Date: ,S ?ci 1 By: lr- Page 11!;a'ceAna1j&a( wmpacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 04, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County CD-1 s and CD1 d Pace Project No.: 2618286 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory between May 08, 2019 and May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. Some analyses have been subcontracted outside of the Pace Network. The subcontracted laboratory report has been attached. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 46 11!;a'ceAna1j&a1" wmpacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Matrix Date Collected Date Received 2618286001 1302-CD-1S Water 05/07/19 09:06 05/08/19 10:00 2618286002 1302-CD-1D Water 05/07/1912:05 05/08/1910:00 2618427010 1302-CD-1S Water 05/07/19 08:50 05/10/19 09:20 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618286001 1302-CD-1S EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA410.4 RNB 1 PASI-GA SM 4500-S2 D KN 1 PASI-GA SM 5210B RNB 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA EPA 9060A FDS 5 PASI-GA 2618286002 1302-CD-1D EPA6020B CSW 17 PASI-GA EPA 7470A JRB 1 PASI-GA EPA 8260D RAC 51 PASI-GA EPA 8260D Mod. SAS 3 PASI-C SM 2320B JAD 1 PASI-GA SM 2540C RLC 1 PASI-GA EPA 9056A RLC 1 PASI-GA EPA 9056A RLC 2 PASI-GA REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.26 Std. Units 1 Field Temperature 15.0 deg C 1 Field Specific Conductance 116 umhos/cm 1 Field Turbidity 7.13 NTU 1 Field Oxidation Potential 242.4 mV 1 Oxygen, Dissolved 1.82 mg/L 1 Depth to Water 28.11 feet 1 Iron, Ferrous 0.0 mg/L 1 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Iron Lead Manganese Nickel Selenium Silver Thallium Vanadium Zinc 7470 Mercury Mercury 8260D MSV 1,1,1,2-Tetrachloroethane 1,1,1-Trichloroethane 1,1,2,2-Tetrachloroethane 1,1,2-Trichloroethane 1,1-Dichloroethane 1,1-Dichloroethene 1,2,3-Trichloropropane 1,2-Dibromo-3-chloropropane 1,2-Dibromoethane (EDB) 1,2-Dichlorobenzene 1,2-Dichloroethane 1,2-Dichloropropane 1,4-Dichlorobenzene 2-Butanone (MEK) Date: 06/04/2019 02:17 PM ND ug/L 5.0 1 ND ug/L 5.0 1 29.8 ug/L 5.0 1 ND ug/L 0.50 1 ND ug/L 0.50 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 638 ug/L 40.0 1 ND ug/L 1.0 1 17.6 ug/L 10.0 1 1.3J ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 5.0 1 ND ug/L 1.0 1 7.OJ ug/L 10.0 1 5.11 uq/L 10.0 1 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 05/23/19 13:38 7782-44-7 N2 05/23/19 13:38 05/23/19 13:38 05/13/1918:04 05/14/1916:38 7440-36-0 05/13/1918:04 05/14/1916:38 7440-38-2 05/13/1918:04 05/14/1916:38 7440-39-3 05/13/1918:04 05/14/1916:38 7440-41-7 05/13/1918:04 05/14/1916:38 7440-43-9 05/13/1918:04 05/14/1916:38 7440-47-3 05/13/1918:04 05/14/1916:38 7440-48-4 05/13/1918:04 05/14/1916:38 7440-50-8 05/13/1918:04 05/14/1916:38 7439-89-6 05/13/1918:04 05/14/1916:38 7439-92-1 05/13/1918:04 05/14/1916:38 7439-96-5 05/13/1918:04 05/14/1916:38 7440-02-0 05/13/1918:04 05/14/1916:38 7782-49-2 05/13/1918:04 05/14/1916:38 7440-22-4 05/13/1918:04 05/14/1916:38 7440-28-0 05/13/1918:04 05/14/1916:38 7440-62-2 05/13/1918:04 05/14/1916:38 7440-66-6 Analytical Method: EPA 7470A Preparation Method: EPA 7470A ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:02 7439-97-6 Analytical Method: EPA 8260D ND ug/L 1.0 1 05/15/1917:05 630-20-6 ND ug/L 1.0 1 05/15/1917:05 71-55-6 ND ug/L 1.0 1 05/15/1917:05 79-34-5 ND ug/L 1.0 1 05/15/1917:05 79-00-5 ND ug/L 1.0 1 05/15/1917:05 75-34-3 ND ug/L 1.0 1 05/15/1917:05 75-35-4 ND ug/L 1.0 1 05/15/1917:05 96-18-4 ND ug/L 2.0 1 05/15/1917:05 96-12-8 ND ug/L 2.0 1 05/15/1917:05 106-93-4 ND ug/L 1.0 1 05/15/1917:05 95-50-1 ND ug/L 1.0 1 05/15/1917:05 107-06-2 ND ug/L 1.0 1 05/15/1917:05 78-87-5 ND ug/L 1.0 1 05/15/1917:05 106-46-7 ND ug/L 5.0 1 05/15/1917:05 78-93-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 5 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 2-Hexanone ND ug/L 5.0 1 05/15/19 17:05 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:05 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:05 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:05 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:05 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:05 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:05 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:05 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:05 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:05 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:05 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:05 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:05 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:05 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:05 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:05 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:05 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:05 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:05 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:05 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:05 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:05 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:05 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:05 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:05 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:05 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:05 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:05 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:05 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:05 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:05 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:05 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:05 1868-53-7 4-Bromofluorobenzene (S) 96 %. 82-120 1 05/15/19 17:05 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:05 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/17/19 20:27 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 104 % 50-150 1 05/17/19 20:27 17060-07-0 Toluene-d8 (S) 122 % 50-150 1 05/17/19 20:27 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 43000 ug/L 20000 1 05/09/19 15:30 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1S Lab ID: 2618286001 Collected: 05/07/19 09:06 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 158000 ug/L 10000 1 05/14/19 19:16 D6 410.4 COD Analytical Method: EPA 410.4 Preparation Method: EPA 410.4 Chemical Oxygen Demand ND ug/L 10000 1 05/13/19 11:30 05/13/19 15:51 4500S2D Sulfide Water Analytical Method: SM 4500-S2 D Sulfide ND ug/L 200 1 05/10/1914:25 18496-25-8 5210B BOD, 5 day Analytical Method: SM 5210B Preparation Method: SM 5210B BOD, 5 day ND ug/L 2000 1 05/08/19 13:00 05/13/19 13:10 1A 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 359 ug/L 50.0 1 05/09/19 13:23 14797-55-8 H1 9056 IC Anions Analytical Method: EPA 9056A Chloride 2930 ug/L 1000 1 05/23/19 04:21 16887-00-6 Sulfate 12600 ug/L 5000 1 05/23/19 04:21 14808-79-8 9060A Total Organic Carbon Analytical Method: EPA 9060A Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Mean Total Organic Carbon ND ug/L 1000 1 05/16/19 16:45 7440-44-0 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 5.69 Std. Units 1 05/23/19 13:38 Field Temperature 18.3 deg C 1 05/23/19 13:38 Field Specific Conductance 114 umhos/cm 1 05/23/19 13:38 Field Turbidity 9.14 NTU 1 05/23/19 13:38 Field Oxidation Potential 183.2 mV 1 05/23/19 13:38 Oxygen, Dissolved 1.61 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 26.89 feet 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-36-0 Arsenic ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-38-2 Barium 30.7 ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-39-3 Beryllium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-41-7 Cadmium ND ug/L 0.50 1 05/13/1918:04 05/14/1916:43 7440-43-9 Chromium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-47-3 Cobalt ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-48-4 Copper 1.4J ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-50-8 Iron 517 ug/L 40.0 1 05/13/1918:04 05/14/1916:43 7439-89-6 Lead ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7439-92-1 Manganese 9.7J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7439-96-5 Nickel ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-02-0 Selenium ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7782-49-2 Silver ND ug/L 5.0 1 05/13/1918:04 05/14/1916:43 7440-22-4 Thallium ND ug/L 1.0 1 05/13/1918:04 05/14/1916:43 7440-28-0 Vanadium 7AJ ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-62-2 Zinc 2.9J ug/L 10.0 1 05/13/1918:04 05/14/1916:43 7440-66-6 7470 Mercury Analytical Method: EPA 7470A Preparation Method: EPA 7470A Mercury ND ug/L 0.20 1 05/13/19 16:00 05/14/19 09:04 7439-97-6 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/15/19 17:31 79-34-5 1,1,2-Trichloroethane ND ug/L 1.0 1 05/15/19 17:31 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/15/19 17:31 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/15/19 17:31 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/15/19 17:31 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/15/19 17:31 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/15/19 17:31 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/15/19 17:31 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/15/19 17:31 78-93-3 2-Hexanone ND ug/L 5.0 1 05/15/19 17:31 591-78-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/15/19 17:31 108-10-1 Acetone ND ug/L 25.0 1 05/15/19 17:31 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/15/19 17:31 107-13-1 Benzene ND ug/L 1.0 1 05/15/19 17:31 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/15/19 17:31 74-97-5 Bromodichloromethane ND ug/L 1.0 1 05/15/19 17:31 75-27-4 Bromoform ND ug/L 1.0 1 05/15/19 17:31 75-25-2 Bromomethane ND ug/L 2.0 1 05/15/19 17:31 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/15/19 17:31 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/15/19 17:31 56-23-5 L1,v1 Chlorobenzene ND ug/L 1.0 1 05/15/19 17:31 108-90-7 Chloroethane ND ug/L 1.0 1 05/15/19 17:31 75-00-3 Chloroform ND ug/L 1.0 1 05/15/19 17:31 67-66-3 Chloromethane ND ug/L 1.0 1 05/15/19 17:31 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/15/19 17:31 124-48-1 Dibromomethane ND ug/L 1.0 1 05/15/19 17:31 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/15/19 17:31 100-41-4 lodomethane ND ug/L 10.0 1 05/15/19 17:31 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/15/19 17:31 75-09-2 Styrene ND ug/L 1.0 1 05/15/19 17:31 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/15/19 17:31 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/15/19 17:31 109-99-9 Toluene ND ug/L 1.0 1 05/15/19 17:31 108-88-3 Trichloroethene ND ug/L 1.0 1 05/15/19 17:31 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/15/19 17:31 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/15/19 17:31 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/15/19 17:31 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/15/19 17:31 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/15/19 17:31 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/15/19 17:31 10061-02-6 Surrogates 1,2-Dichloroethane-d4 (S) 93 %. 81-119 1 05/15/19 17:31 17060-07-0 Dibromofluoromethane (S) 98 %. 82-114 1 05/15/19 17:31 1868-53-7 4-Bromofluorobenzene (S) 95 %. 82-120 1 05/15/19 17:31 460-00-4 Toluene-d8 (S) 97 %. 82-109 1 05/15/19 17:31 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) ND ug/L 2.0 1 05/19/19 11:24 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 128 % 50-150 1 05/19/19 11:24 17060-07-0 Toluene-d8 (S) 115 % 50-150 1 05/19/19 11:24 2037-26-5 2320B Alkalinity Analytical Method: SM 2320B Alkalinity, Total as CaCO3 52000 ug/L 20000 1 05/09/19 15:34 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 Sample: 1302-CD-1D Lab ID: 2618286002 Collected: 05/07/19 12:05 Received: 05/08/19 10:00 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 2540C Total Dissolved Solids Analytical Method: SM 2540C Total Dissolved Solids 134000 ug/L 10000 1 05/14/19 19:16 9056 IC Anions 48hr Analytical Method: EPA 9056A Nitrate as N 80.8 ug/L 50.0 1 05/09/19 11:55 14797-55-8 9056 IC Anions Analytical Method: EPA 9056A Chloride 2840 ug/L 1000 1 05/30/19 07:20 16887-00-6 Sulfate 3140J ug/L 5000 1 05/30/19 07:20 14808-79-8 Date: 06/04/2019 02:17 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 10 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28287 Analysis Method: EPA 7470A QC Batch Method: EPA 7470A Analysis Description: 7470 Mercury Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127417 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mercury ug/L ND 0.20 05/13/1919:46 LABORATORY CONTROL SAMPLE: 127418 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mercury ug/L 2.5 2.4 98 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127419 127420 MS MSD 2618405004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mercury ug/L ND 2.5 2.5 2.2 2.2 88 87 75-125 2 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 11 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28295 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127445 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed Antimony ug/L ND 5.0 05/14/1915:22 Arsenic ug/L ND 5.0 05/14/1915:22 Barium ug/L ND 5.0 05/14/1915:22 Beryllium ug/L ND 0.50 05/14/1915:22 Cadmium ug/L ND 0.50 05/14/1915:22 Chromium ug/L ND 5.0 05/14/1915:22 Cobalt ug/L ND 5.0 05/14/1915:22 Copper ug/L ND 5.0 05/14/1915:22 Iron ug/L ND 40.0 05/14/1915:22 Lead ug/L ND 1.0 05/14/1915:22 Manganese ug/L ND 10.0 05/14/1915:22 Nickel ug/L ND 5.0 05/14/1915:22 Selenium ug/L ND 5.0 05/14/1915:22 Silver ug/L ND 5.0 05/14/1915:22 Thallium ug/L ND 1.0 05/14/1915:22 Vanadium ug/L ND 10.0 05/14/1915:22 Zinc ug/L ND 10.0 05/14/1915:22 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 127446 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Antimony ug/L 100 96.7 97 80-120 Arsenic ug/L 100 97.1 97 80-120 Barium ug/L 100 95.6 96 80-120 Beryllium ug/L 100 99.5 99 80-120 Cadmium ug/L 100 97.0 97 80-120 Chromium ug/L 100 98.1 98 80-120 Cobalt ug/L 100 98.9 99 80-120 Copper ug/L 100 99.2 99 80-120 Iron ug/L 1000 988 99 80-120 Lead ug/L 100 95.9 96 80-120 Manganese ug/L 100 101 101 80-120 Nickel ug/L 100 97.5 98 80-120 Selenium ug/L 100 98.8 99 80-120 Silver ug/L 100 99.0 99 80-120 Thallium ug/L 100 95.8 96 80-120 Vanadium ug/L 100 99.9 100 80-120 Zinc ug/L 100 102 102 80-120 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 12 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127447 127448 MS MSD 2618227008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.0 93.7 98 94 75-125 5 20 Arsenic ug/L ND 100 100 92.7 92.9 93 93 75-125 0 20 Barium ug/L 37.6 100 100 131 127 93 89 75-125 3 20 Beryllium ug/L ND 100 100 104 101 103 101 75-125 3 20 Cadmium ug/L ND 100 100 95.7 94.7 96 95 75-125 1 20 Chromium ug/L ND 100 100 98.9 98.4 98 98 75-125 1 20 Cobalt ug/L ND 100 100 98.0 97.3 98 97 75-125 1 20 Copper ug/L ND 100 100 98.0 101 97 100 75-125 3 20 Iron ug/L 517 1000 1000 1010 1900 49 139 75-125 61 20 M1,R1 Lead ug/L ND 100 100 94.0 91.4 94 91 75-125 3 20 Manganese ug/L 80.7 100 100 180 187 99 107 75-125 4 20 Nickel ug/L ND 100 100 97.6 95.5 97 95 75-125 2 20 Selenium ug/L ND 100 100 95.7 95.1 96 95 75-125 1 20 Silver ug/L ND 100 100 101 98.1 101 98 75-125 3 20 Thallium ug/L ND 100 100 94.2 91.9 94 92 75-125 2 20 Vanadium ug/L ND 100 100 100 98.8 99 98 75-125 2 20 Zinc ug/L ND 100 100 102 103 98 99 75-125 1 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28431 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 127981 Associated Lab Samples: 2618286001, 2618286002 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,1-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/15/19 11:28 1,1,2-Trichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,1-Dichloroethene ug/L ND 1.0 05/15/19 11:28 1,2,3-Trichloropropane ug/L ND 1.0 05/15/19 11:28 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/15/19 11:28 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/15/19 11:28 1,2-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 1,2-Dichloroethane ug/L ND 1.0 05/15/19 11:28 1,2-Dichloropropane ug/L ND 1.0 05/15/19 11:28 1,4-Dichlorobenzene ug/L ND 1.0 05/15/19 11:28 2-Butanone (MEK) ug/L ND 5.0 05/15/19 11:28 2-Hexanone ug/L ND 5.0 05/15/19 11:28 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/15/19 11:28 Acetone ug/L ND 25.0 05/15/19 11:28 Acrylonitrile ug/L ND 50.0 05/15/19 11:28 Benzene ug/L ND 1.0 05/15/19 11:28 Bromochloromethane ug/L ND 1.0 05/15/19 11:28 Bromodichloromethane ug/L ND 1.0 05/15/19 11:28 Bromoform ug/L ND 1.0 05/15/19 11:28 Bromomethane ug/L ND 2.0 05/15/19 11:28 Carbon disulfide ug/L ND 10.0 05/15/19 11:28 Carbon tetrachloride ug/L ND 1.0 05/15/19 11:28 Chlorobenzene ug/L ND 1.0 05/15/19 11:28 Chloroethane ug/L ND 1.0 05/15/19 11:28 Chloroform ug/L ND 1.0 05/15/19 11:28 Chloromethane ug/L ND 1.0 05/15/19 11:28 cis-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 cis-1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Dibromochloromethane ug/L ND 1.0 05/15/19 11:28 Dibromomethane ug/L ND 1.0 05/15/19 11:28 Ethylbenzene ug/L ND 1.0 05/15/19 11:28 lodomethane ug/L ND 10.0 05/15/19 11:28 Methylene Chloride ug/L ND 1.0 05/15/19 11:28 Styrene ug/L ND 1.0 05/15/19 11:28 Tetrachloroethene ug/L ND 1.0 05/15/19 11:28 Tetrahydrofuran ug/L ND 10.0 05/15/19 11:28 Toluene ug/L ND 1.0 05/15/19 11:28 trans-1,2-Dichloroethene ug/L ND 1.0 05/15/19 11:28 V1 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 METHOD BLANK: 127981 Associated Lab Samples: Parameter 2618286001, 2618286002 Units Matrix: Blank Result Water Reporting Limit Analyzed trans- 1,3-Dichloropropene ug/L ND 1.0 05/15/19 11:28 Trichloroethene ug/L ND 1.0 05/15/19 11:28 Trichlorofluoromethane ug/L ND 1.0 05/15/19 11:28 Vinyl acetate ug/L ND 2.0 05/15/19 11:28 Vinyl chloride ug/L ND 1.0 05/15/19 11:28 Xylene (Total) ug/L ND 2.0 05/15/19 11:28 1,2-Dichloroethane-d4 (S) %. 93 81-119 05/15/19 11:28 4-Bromofluorobenzene (S) %. 96 82-120 05/15/19 11:28 Dibromofluoromethane (S) %. 98 82-114 05/15/19 11:28 Toluene-d8 (S) %. 100 82-109 05/15/19 11:28 LABORATORY CONTROL SAMPLE: 127982 Parameter Qualifiers Spike LCS LCS % Rec Units Conc. Result % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 56.3 113 68-137 1,1,1-Trichloroethane ug/L 50 57.8 116 72-134 1,1,2,2-Tetrachloroethane ug/L 50 59.1 118 51-158 1,1,2-Trichloroethane ug/L 50 57.5 115 78-131 1,1-Dichloroethane ug/L 50 60.8 122 69-151 1,1-Dichloroethene ug/L 50 63.8 128 64-158 1,2,3-Trichloropropane ug/L 50 45.1 90 78-133 1,2-Dibromo-3-chloropropane ug/L 50 48.6 97 58-124 1,2-Dibromoethane (EDB) ug/L 50 56.5 113 71-134 1,2-Dichlorobenzene ug/L 50 54.9 110 70-135 1,2-Dichloroethane ug/L 50 54.2 108 72-129 1,2-Dichloropropane ug/L 50 60.3 121 64-135 1,4-Dichlorobenzene ug/L 50 52.8 106 70-131 2-Butanone (MEK) ug/L 100 101 101 52-143 2-Hexanone ug/L 100 87.1 87 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 104 104 71-129 Acetone ug/L 100 88.7 89 48-224 Acrylonitrile ug/L 200 205 103 66-154 Benzene ug/L 50 57.5 115 68-132 Bromochloromethane ug/L 50 58.6 117 73-133 Bromodichloromethane ug/L 50 56.8 114 67-121 Bromoform ug/L 50 56.6 113 57-125 Bromomethane ug/L 50 48.0 96 35-156 Carbon disulfide ug/L 100 103 103 47-141 Carbon tetrachloride ug/L 50 64.4 129 66-122 L1,v1 Chlorobenzene ug/L 50 56.6 113 71-126 Chloroethane ug/L 50 47.3 95 43-143 Chloroform ug/L 50 51.3 103 71-136 Chloromethane ug/L 50 53.0 106 47-123 cis-1,2-Dichloroethene ug/L 50 61.1 122 74-131 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 LABORATORY CONTROL SAMPLE: Parameter 127982 Units Spike Conc. LCS Result LCS % Rec % Rec Limits cis-1,3-Dichloropropene ug/L 50 57.9 116 78-120 Dibromochloromethane ug/L 50 56.4 113 65-115 Dibromomethane ug/L 50 62.9 126 79-129 Ethylbenzene ug/L 50 58.5 117 68-129 lodomethane ug/L 100 97.3 97 49-154 Methylene Chloride ug/L 50 56.8 114 61-147 Styrene ug/L 50 61.4 123 77-128 Tetrachloroethene ug/L 50 53.1 106 51-139 Tetrahydrofuran ug/L 100 101 101 56-147 Toluene ug/L 50 54.7 109 60-133 trans-1,2-Dichloroethene ug/L 50 63.4 127 69-144 trans- 1,3-Dichloropropene ug/L 50 50.0 100 74-128 Trichloroethene ug/L 50 54.2 108 73-126 Trichlorofluoromethane ug/L 50 59.1 118 55-132 Vinyl acetate ug/L 50 54.2 108 52-141 Vinyl chloride ug/L 50 51.5 103 50-133 Xylene (Total) ug/L 150 181 121 78-132 1,2-Dichloroethane-d4 (S) %. 92 81-119 4-Bromofluorobenzene (S) %. 95 82-120 Dibromofluoromethane (S) %. 95 82-114 Toluene-d8 (S) %. 97 82-109 Qualifiers MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 55.2 48.8 110 98 68-137 12 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 61.0 53.7 122 107 66-142 13 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 60.5 50.2 121 100 39-171 19 13 R1 1,1,2-Trichloroethane ug/L ND 50 50 56.6 50.8 113 102 73-136 11 12 1,1-Dichloroethane ug/L ND 50 50 57.6 54.2 115 108 66-155 6 15 1,1-Dichloroethene ug/L ND 50 50 66.9 63.4 134 127 33-181 5 34 1,2,3-Trichloropropane ug/L ND 50 50 43.4 35.3 87 71 78-133 21 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 47.2 38.4 94 77 58-124 21 15 R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 56.6 47.5 113 95 71-134 17 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 56.2 46.9 112 94 69-135 18 10 R1 1,2-Dichloroethane ug/L ND 50 50 54.3 49.3 109 99 36-159 10 10 1,2-Dichloropropane ug/L ND 50 50 60.0 53.0 120 106 68-132 12 11 R1 1,4-Dichlorobenzene ug/L ND 50 50 54.0 47.7 108 95 49-153 12 9 R1 2-Butanone (MEK) ug/L ND 100 100 96.5 82.0 97 82 10-189 16 23 2-Hexanone ug/L ND 100 100 83.2 67.8 83 68 40-135 20 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 98.2 83.6 98 84 30-177 16 10 R1 (MIBK) Acetone ug/L ND 100 100 86.0 75.6 80 70 44-223 13 14 Acrylonitrile ug/L ND 200 200 191 160 95 80 13-189 18 12 R1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127983 MS 2618237001 Spike Parameter Units Result Conc. MSD Spike Conc. 127984 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual Benzene ug/L ND 50 50 57.6 52.4 115 105 66-139 9 10 Bromochloromethane ug/L ND 50 50 59.4 53.3 119 107 73-133 11 13 Bromodichloromethane ug/L ND 50 50 55.5 49.5 111 99 57-120 11 13 Bromoform ug/L ND 50 50 53.5 44.4 107 89 48-128 18 13 R1 Bromomethane ug/L ND 50 50 37.8 39.3 76 79 10-187 4 32 Carbon disulfide ug/L ND 100 100 111 101 111 101 47-141 9 322 Carbon tetrachloride ug/L ND 50 50 72.2 64.1 144 128 58-127 12 14 MOM Chlorobenzene ug/L ND 50 50 55.2 48.2 110 96 63-137 14 10 R1 Chloroethane ug/L ND 50 50 50.6 45.5 101 91 52-146 11 16 Chloroform ug/L ND 50 50 50.5 46.5 101 93 74-137 8 9 Chloromethane ug/L ND 50 50 53.7 49.1 107 98 41-127 9 10 cis-1,2-Dichloroethene ug/L ND 50 50 60.1 54.4 120 109 71-138 10 16 cis-1,3-Dichloropropene ug/L ND 50 50 56.5 51.6 113 103 32-145 9 12 Dibromochloromethane ug/L ND 50 50 54.9 47.6 110 95 52-116 14 13 R1 Dibromomethane ug/L ND 50 50 60.9 52.8 122 106 79-129 14 14 Ethylbenzene ug/L ND 50 50 57.7 51.3 115 103 31-174 12 10 R1 lodomethane ug/L ND 100 100 95.6 107 96 107 49-154 12 30 Methylene Chloride ug/L ND 50 50 56.0 51.0 112 102 61-146 9 15 Styrene ug/L ND 50 50 60.2 52.4 120 105 77-128 14 14 Tetrachloroethene ug/L ND 50 50 56.5 50.9 113 102 36-155 10 14 Tetrahydrofuran ug/L ND 100 100 98.8 83.6 99 84 56-147 17 12 R1 Toluene ug/L ND 50 50 57.1 50.1 114 100 52-146 13 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 65.9 58.5 132 117 61-152 12 14 trans-1,3-Dichloropropene ug/L ND 50 50 48.6 41.7 97 83 37-146 15 12 R1 Trichloroethene ug/L ND 50 50 53.7 49.4 107 99 61-141 8 12 Trichlorofluoromethane ug/L ND 50 50 67.3 61.4 135 123 51-141 9 13 Vinyl acetate ug/L ND 50 50 49.9 44.4 100 89 52-141 12 14 Vinyl chloride ug/L ND 50 50 58.8 54.6 118 109 22-156 7 26 Xylene (Total) ug/L ND 150 150 179 159 119 106 78-132 12 7 RS 1,2-Dichloroethane-d4 (S) %. 96 95 81-119 4-Bromofluorobenzene (S) %. 98 96 82-120 Dibromofluoromethane (S) %. 97 98 82-114 Toluene-d8 (S) %. 98 98 82-109 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 475936 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286001 METHOD BLANK: 2578807 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/17/19 12:15 1,2-Dichloroethane-d4 (S) % 100 50-150 05/17/19 12:15 Toluene-d8 (S) % 114 50-150 05/17/19 12:15 LABORATORY CONTROL SAMPLE: 2578808 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.6 103 70-130 1,2-Dichloroethane-d4 (S) % 101 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2578809 2578810 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 19.3 20.2 96 101 50-150 5 30 1,2-Dichloroethane-d4 (S) % 92 90 50-150 30 Toluene-d8 (S) % 82 81 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618286002 METHOD BLANK: 2579453 Associated Lab Samples: 2618286002 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/19/1910:45 102 50-150 05/19/1910:45 113 50-150 05/19/1910:45 LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 25.7 20.3 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 19 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28076 Analysis Method: SM 2320B QC Batch Method: SM 2320B Analysis Description: 2320E Alkalinity Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126363 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Alkalinity, Total as CaCO3 ug/L ND 20000 05/09/19 13:54 LABORATORY CONTROL SAMPLE: 126364 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Alkalinity, Total as CaCO3 ug/L 100000 101000 101 85-115 SAMPLE DUPLICATE: 126365 2618202009 Dup Max Parameter Units Result Result RPD RPD Qualifiers Alkalinity, Total as CaCO3 ug/L 123 mg/L 124000 1 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28369 Analysis Method: SM 2540C QC Batch Method: SM 2540C Analysis Description: 2540C Total Dissolved Solids Associated Lab Samples: 2618286001, 2618286002 LABORATORY CONTROL SAMPLE: 127730 Parameter Units Total Dissolved Solids ug/L Spike LCS LCS % Rec Conc. Result % Rec Limits Qualifiers 400000 403000 101 84-108 SAMPLE DUPLICATE: 127731 2618286001 Dup Parameter Units Result Result Total Dissolved Solids ug/L 158000 133000 Max RPD RPD Qualifiers 17 10 D6 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 21 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28239 Analysis Method: EPA 410.4 QC Batch Method: EPA 410.4 Analysis Description: 410.4 COD Associated Lab Samples: 2618286001 METHOD BLANK: 127270 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chemical Oxygen Demand ug/L ND 10000 05/13/19 15:36 LABORATORY CONTROL SAMPLE: 127271 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 200000 203000 101 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127272 127273 MS MSD 2618152001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chemical Oxygen Demand ug/L 11400 5000000 5000000 1630000 1610000 99 96 90-110 1 10 mg/L 0 0 MATRIX SPIKE SAMPLE: 127274 2618152003 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chemical Oxygen Demand ug/L 11200 mg/L 5000000 16200000 100 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28184 Analysis Method: SM 4500-S2 D QC Batch Method: SM 4500-S2 D Analysis Description: 4500S2D Sulfide Water Associated Lab Samples: 2618286001 METHOD BLANK: 126976 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Sulfide ug/L ND 200 05/10/1914:19 LABORATORY CONTROL SAMPLE: 126977 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Sulfide ug/L 500 452 90 80-120 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126978 126979 MS MSD 2618407004 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Sulfide ug/L ND 500 500 ND ND 39 38 30-129 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28001 Analysis Method: SM 5210B QC Batch Method: SM 5210B Analysis Description: 5210E BOD, 5 day Associated Lab Samples: 2618286001 METHOD BLANK: 125904 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers BOD, 5 day ug/L ND 2000 05/13/19 12:52 1A LABORATORY CONTROL SAMPLE: 125906 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers BOD, 5 day ug/L 198000 205000 104 85-115 1A SAMPLE DUPLICATE: 125957 2618270001 Dup Max Parameter Units Result Result RPD RPD Qualifiers BOD, 5 day ug/L 1110 mg/L 1270000 13 20 1A Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 24 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28053 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001, 2618286002 METHOD BLANK: 126307 Matrix: Water Associated Lab Samples: 2618286001, 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Nitrate as N ug/L ND 50.0 05/09/19 14:29 LABORATORY CONTROL SAMPLE: 126308 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Nitrate as N ug/L 10000 9630 96 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 126309 126310 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Nitrate as N ug/L 359 10000 10000 9640 9600 93 92 90-110 0 15 H1 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28932 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286001 METHOD BLANK: 130388 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 81.OJ 1000 05/23/19 03:39 Sulfate ug/L 23.OJ 5000 05/23/19 03:39 LABORATORY CONTROL SAMPLE: 130389 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 10500 105 90-110 Sulfate ug/L 10000 11000 110 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 130390 130391 MS MSD 2618286001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2930 10000 10000 13300 13200 104 103 90-110 1 15 Sulfate ug/L 12600 10000 10000 22300 22300 97 98 90-110 0 15 MATRIX SPIKE SAMPLE: 130392 2618688001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L ND 5000000 5160000 101 90-110 Sulfate ug/L ND 5000000 5420000 107 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 29257 Analysis Method: EPA 9056A QC Batch Method: EPA 9056A Analysis Description: 9056 IC Anions Associated Lab Samples: 2618286002 METHOD BLANK: 131872 Matrix: Water Associated Lab Samples: 2618286002 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Chloride ug/L 78.OJ 1000 05/30/19 06:38 Sulfate ug/L 35.OJ 5000 05/30/19 06:38 LABORATORY CONTROL SAMPLE: 131873 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Chloride ug/L 10000 9910 99 90-110 Sulfate ug/L 10000 9940 99 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 131874 131875 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Chloride ug/L 2840 10000 10000 12600 12400 98 95 90-110 2 15 Sulfate ug/L 3140J 10000 10000 12800 12700 97 95 90-110 1 15 MATRIX SPIKE SAMPLE: 131888 2619009001 Spike MS MS % Rec Parameter Units Result Conc. Result % Rec Limits Qualifiers Chloride ug/L 11.6 mg/L 10000 21200 96 90-110 Sulfate ug/L ND 10000 10900 104 90-110 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 QC Batch: 28426 Analysis Method: EPA 9060A QC Batch Method: EPA 9060A Analysis Description: 9060A Total Organic Carbon Associated Lab Samples: 2618286001 METHOD BLANK: 127954 Matrix: Water Associated Lab Samples: 2618286001 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Mean Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 Total Organic Carbon ug/L ND 1000 05/16/19 10:52 LABORATORY CONTROL SAMPLE: 127955 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Mean Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19100 96 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 19000 95 90-110 Total Organic Carbon ug/L 20000 18900 95 90-110 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127956 127957 MS MSD 2618406001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20000 19800 84 83 85-115 1 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19900 19600 84 82 85-115 2 10 M1 Total Organic Carbon ug/L 3.3 mg/L 20000 20000 20300 19800 85 82 85-115 3 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 20100 20100 84 85 85-115 0 10 M1 Total Organic Carbon ug/L 3.2 mg/L 20000 20000 19500 19800 81 83 85-115 2 10 M1 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 127958 127959 MS MSD 2618294001 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Mean Total Organic Carbon ug/L 1040 20000 20000 19000 18900 90 89 85-115 1 10 Total Organic Carbon ug/L 1040 20000 20000 19000 19000 90 90 85-115 0 10 Total Organic Carbon ug/L 1020 20000 20000 18200 18800 86 89 85-115 3 10 Total Organic Carbon ug/L 1030 20000 20000 19400 19100 92 90 85-115 2 10 Total Organic Carbon ug/L 1060 20000 20000 19300 18600 91 88 85-115 4 10 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 46 Pace Analytical Services, LLC 1p 110 Technology Parkway aceAnalj&al Peachtree Corners, GA 30092 WNW'pacalabsxom (770)734-4200 QUALIFIERS Project: Cabarrus County CD-1s and CD1d Pace Project No.: 2618286 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA BATCH QUALIFIERS Batch: 28232 The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. ANALYTE QUALIFIERS 1A The seed correction factor was below the desired range of 0.60-1.0 mg/L. All other quality control indicators including the LCS, were within accepted limits. D6 The precision between the sample and sample duplicate exceeded laboratory control limits. H1 Analysis conducted outside the EPA method holding time. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. v1 The continuing calibration verification was above the method acceptance limit. Any detection for the analyte in the associated samples may have a high bias. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County CD-1s and CD1d 2618286 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618286001 1302-C D-1 S 28595 2618286002 1302-CD-1 D 28595 2618286001 1302-CD-IS EPA3005A 28295 EPA6020B 28307 2618286002 1302-CD-ID EPA3005A 28295 EPA6020B 28307 2618286001 1302-CD-1S EPA 7470A 28287 EPA 7470A 28296 2618286002 1302-CD-1 D EPA 7470A 28287 EPA 7470A 28296 2618286001 1302-CD-1 S EPA 8260D 28431 2618286002 1302-CD-1 D EPA 8260D 28431 2618286001 1302-CD-1S EPA 8260D Mod. 475936 2618286002 1302-CD-ID EPA 8260D Mod. 476071 2618286001 1302-CD-1S SM 2320E 28076 2618286002 1302-CD-1D SM 2320E 28076 2618286001 1302-CD-IS SM 2540C 28369 2618286002 1302-CD-ID SM 2540C 28369 2618286001 1302-CD-1S EPA410.4 28239 EPA410.4 28257 2618286001 1302-CD-IS SM 4500-S2 D 28184 2618286001 1302-CD-1S SM 5210E 28001 SM 5210B 28232 2618286001 1302-CD-1 S EPA 9056A 28053 2618286002 1302-CD-1 D EPA 9056A 28053 2618286001 1302-CD-1S EPA 9056A 28932 2618286002 1302-CD-1 D EPA 9056A 29257 2618286001 1302-CD-1S EPA 9060A 28426 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 02:17 PM without the written consent of Pace Analytical Services, LLC. Page 30 of 46 INIA� kaelul saldweg NIA JekOOa PaIE05 R sn I NIA) eel U uo pOA100e8 S s iN1A1 ew�oluO Ienplsatl O ul dW31 cl euexolu-• r [ WIso9Ze x x uC yr ro 0. VOSRiIUIIBMktl 'SOS x x esoueBurtp4'uoi1'R3Nokav4 slaloiN I ddV x x (ue6olpRH] seseO s10 x w. r (Vjnk seseD par.{ossip x (3'3'W'Zoo)sase0 sl❑ x uogioO aluebio lelol x �c ❑-ZS-OO,trWS Rq ap111nS x Qvv x y EON REPS COG �C � Sr2 6 a d 3r11d 09Z9 OOA I ddV x x NIA JsaJL sas,Sjei1y m iayko c E ° C W a w laueykeynJ 7 U g EOZSZ10N HOUN z 13H n n v u� £ONH E4 POSZH s m 2 pa+uasaidun H G. StJ:i NfV iND�i�• 'n G L L) L a (1 6 a NOl1D3110) IV dN31 3ldvm, � W N ¢ ❑ uwi u! W E 1[ z � a uuii a W F Ix ¢ Ix a 0 O C7 C � WW C W O N ❑ o c tJ r � p L1 x m 7 _ {dkN OO=7 9VtsEJ•O1 3dA131dWt'S f w c} svpv p•le• Ycsj V 30077CIZj1:'6 F a W `m v m w [C a m$ p �L° o m T a $$ w y °n 7 V (0 00 � N 0 � O C as f E p W a s 1 N C N E m a Q y O V O �� V d a o z w f Y ■` [� Page 31 of 46 # W311 •- rt ro •r In ua ti m m c ,.. N .- N d' U Q 2 13J 0. Q: ConditionSample .. r FaceAnaOicaf Client Name: LD M Wo# : i 28 1 8285 FM: SMM Due Date: 05 CL"NT: �DM-Raleigh I21/4 g Courier: _mod Ex �] UPS [15P� � Client ❑ Commercial Pace Other Tracking #: / [ If Custody Seal on CoolerlBox Present: J�Ys i] no Seals intact: ,W yes no Proj. Due Date: Proj. Name: Packing Material: Bubble Wrap '�ubble Baas —1 None 7 Other I -r L.-._w. ..-....-4. i i--a (I }i - � 7,,-., -f Ira- /11 od R1i.n Nnnp F—i irr rrmlino orocess has henun Cooler Temperature Temp should be above freezing to 6 C Biological Tissue is Frozen: rras ran Comments: Date nd Initial of ers mining c6 tents: Chain of Custody Present: rr:, ❑r•lo ❑N+A 4 Chain of Custody Filled Out: LJ�ZNG EN;A 2- Chain of Custody Relinquished: "+G =N A 3. Sampler Name & Signature on COC: r ONc, ❑N;A 4. Samples Arrived within Hold Time: ,o ]NSA 5. Short Hold Time Analysis (<72hr): r—" '1•, LE A 6. Rush Turn Around Time Requested: ElYes L�' J A 7. Sufficient Volume. —N 4 S. Correct Containers Used• -Pace Containers Used: '=':• Uk,67GNn DNA DNIA 9. Containers Intact: s E]N0 LN+A 11-0 Filtered volume received for Dissolved tests `lvrrs Sample Labels match COC: -Includes dalelt,melld/Analysis Matrix:__� Grin _ -Nra. 12 All Containers needing pre+servalisn have been checked. Ail containers needing preservation are found to be in es ❑No compliance with EPA recommendation. e:ceptons. ! A. ^,ri'nnr., 0 .OSG 1".'!•DR4 'rra!erl IGNc ❑N±A Initial when Lot 4 added completed preser alive Samples checked for dechlonnalion: ores ONO 'W 14- Headspace In VOA Vials ( >6mm): Gyes a EX (. i" 0MZ12 Trip Blank Present: Trip Blank Custody Seals Present Pace Trip Blank Lot # (if purchased): =yes 'Grwr, ❑Yes ONv 2 . A ,3'A 16 Client Notification) Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: DatelTime Field data Requ,recP Y 11 t•i Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be Con itication Office { i.e out of hold- incorrect preservalive, out of temp. incorrecl containers) lu the North Carolina 0EHNR Page 32 of 46 F-AGLCO03rev 3, 1lSeplember2006 ?ceAnalytical i May 23, 2019 Sakina McKenzie Pace Analytical Services 110 Technology Parkway Peachtree Corners, GA 30092 RE: CABARRUS COUNTY / 2618286 Pace Workorder. 30306 Dear Sakina McKenzie: Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Enclosed are the analytical results for sample(s) received by the laboratory on Friday, May 10, 2019. Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise narrated in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Emma Louis 05/23/2019 Emma.Louis@pacelabs.com Customer Service Representative Enclosures As a valued client we would appreciate your comments on our service. Please email PAESfeedback@pacelabs.com. Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Total Number of Pages 14 Page 1 of 10 Page 33 of 46 Pace Analytical Energy Services LLC 220 William Pitt Way 2ceAnalyfica(. Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY ACCREDITATIONS & CERTIFICATIONS Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories Accreditation ID: 02-00538 Scope: NELAP Non -Potable Water Accreditor: West Virginia Department of Environmental Protection, Division of Water and Waste Management Accreditation ID: 395 Scope: Non -Potable Water Accreditor: South Carolina Department of Health and Environmental Control, Office of Environmental Laboratory Certification Accreditation ID: 89009003 Scope: Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA) Accreditor: State of Virginia Accreditation ID: 460201 Scope: Non -Potable Water Accreditor: NELAP: New Jersey, Department of Environmental Protection Accreditation ID: PA026 Scope: Non -Potable Water Accreditor: NELAP: New York, Department of Health Wadsworth Center Accreditation ID: 11815 Scope: Non -Potable Water Accreditor: State of Connecticut, Department of Public Health, Division of Environmental Health Accreditation ID: PH-0263 Scope: Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA) Accreditor: NELAP: Texas, Commission on Environmental Quality Accreditation ID: T104704453-09-TX Scope: Non -Potable Water Accreditor: State of New Hampshire Accreditation ID: 299409 Scope: Non -potable water Accreditor: State of Georgia Accreditation ID: Chapter 391-3-26 Scope: As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is accredited by the Pennsylvania Department of Environmental Protection Bureau of Laboratories under the National Environmental Laboratory Approval Program (NELAC). Report ID: 30306 - 1167062 CERTIFICATE OF ANALYSIS �rl`p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 2 of 10 Page 34 of 46 ?ceAnalytical @ SAMPLE SUMMARY Workorder: 30306 CABARRUS COUNTY / 2618286 Lab ID Report ID: 30306 - 1167062 �rtiecp Sample ID 1302-CD-1 S Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Matrix Date Collected Date Received 19V= CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. 5/7/2019 09:06 5/10/2019 10:30 Page 3 of 10 Page 35 of 46 ?ceAnalytical i ANALYTICAL RESULTS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Lab ID: 303060001 Sample ID: 1302-CD-1S Date Received: 5/10/2019 10:30 Matrix: Water Date Collected: 5/7/2019 09:06 Parameters Results Units PQL MDL DF Analyzed By Qualifiers EDonors - PAES Analysis Desc: AM23G Analytical Method: AM23G Lactic Acid 0.0431.11 mg/I 0.20 0.043 1 5/15/2019 16:29 KB Acetic Acid 0.032J mg/I 0.10 0.028 1 5/15/2019 16:29 KB Propionic Acid 0.00401.11 mg/I 0.10 0.0040 1 5/15/2019 16:29 KB Formic Acid 0.17J mg/I 0.50 0.086 1 5/15/2019 16:29 KB Butyric Acid 0.0111,11 mg/I 0.10 0.011 1 5/15/2019 16:29 KB Pyruvic Acid 0.00501.11 mg/I 0.10 0.0050 1 5/15/2019 16:29 KB i-Pentanoic Acid 0.00601.11 mg/I 0.10 0.0060 1 5/15/2019 16:29 KB Pentanoic Acid 0.00701.11 mg/I 0.10 0.0070 1 5/15/2019 16:29 KB i-Hexanoic Acid 0.0291.11 mg/I 0.20 0.029 1 5/15/2019 16:29 KB Hexanoic Acid 0.0101.11 mg/I 0.20 0.010 1 5/15/2019 16:29 KB RISK - PAES Analysis Desc: AM20GAX Analytical Method: AM20GAX Methane 0.053J ug/I 0.50 0.046 1 5/15/201911:53 BW n Ethane 0.00501.11 ug/I 0.10 0.0050 1 5/15/201911:53 BW n Ethene 0.00401.11 ug/I 0.10 0.0040 1 5/15/201911:53 BW n Carbon Dioxide 50 mg/I 5.0 0.45 1 5/15/2019 11:53 BW n Report ID: 30306 - 1167062 Page 4 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 36 of 46 ?ceAnalytical i ANALYTICAL RESULTS QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 DEFINITIONS/QUALIFIERS MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection. PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation. ND Not detected at or above reporting limit. DF Dilution Factor. S Surrogate. RPD Relative Percent Difference. % Rec Percent Recovery. U Indicates the compound was analyzed for, but not detected at or above the noted concentration. J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL). n The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 nelacp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 5 of 10 Page 37 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: DISG/7535 Analysis Method: AM20GAX QC Batch Method: AM20GAX Associated Lab Samples: 303060001 METHOD BLANK: 61187 Blank Reporting Parameter Units Result Limit Qualifiers Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 RISK Methane ug/I 0.046U 0.046 n Ethane ug/I 0.0050U 0.0050 n Ethene ug/I 0.0040U 0.0040 n METHOD BLANK: 61188 Blank Reporting Parameter Units Result Limit Qualifiers RISK Carbon Dioxide mg/I 0.45U 0.45 n LABORATORY CONTROL SAMPLE & LCSD: 61189 61191 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Methane ug/I 750 760 740 101 99 80-120 1.7 20 n Ethane ug/I 38 39 38 104 101 80-120 3.1 20 n Ethene ug/I 35 36 35 103 98 80-120 4.9 20 n LABORATORY CONTROL SAMPLE & LCSD: 61190 61192 Spike LCS LCSD LCS LCSD % Rec Max Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers Carbon Dioxide mg/I 120 120 110 106 97 80-120 9.1 20 n Report ID: 30306 - 1167062 Page 6 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 38 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 QC Batch: EDON/4075 Analysis Method: AM23G QC Batch Method: AM23G Associated Lab Samples: 303060001 METHOD BLANK: 61209 Blank Reporting Parameter Units Result Limit Qualifiers EDonors Lactic Acid mg/I 0.043U 0.043 Acetic Acid mg/I 0.028U 0.028 Propionic Acid mg/I 0.0040U 0.0040 Formic Acid mg/I 0.086U 0.086 Butyric Acid mg/I 0.011 U 0.011 Pyruvic Acid mg/I 0.0050U 0.0050 i-Pentanoic Acid mg/I 0.0060U 0.0060 Pentanoic Acid mg/I 0.0070U 0.0070 i-Hexanoic Acid mg/I 0.029U 0.029 Hexanoic Acid mg/I 0.010U 0.010 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 LABORATORY CONTROL SAMPLE: 61210 Spike LCS LCS % Rec Parameter Units Cone. Result % Rec Limits Qualifiers Lactic Acid mg/I 2 2.2 109 70-130 Acetic Acid mg/I 2 2.1 103 70-130 Propionic Acid mg/I 2 2.0 102 70-130 Formic Acid mg/I 2 2.0 101 70-130 Butyric Acid mg/I 2 2.0 103 70-130 Pyruvic Acid mg/I 2 2.1 106 70-130 i-Pentanoic Acid mg/I 2 2.0 99 70-130 Pentanoic Acid mg/I 2 2.0 100 70-130 i-Hexanoic Acid mg/I 2 1.8 91 70-130 Hexanoic Acid mg/I 2 1.9 94 70-130 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers EDonors Lactic Acid mg/I 0.22 20 22 22 107 108 70-130 1.3 30 d Acetic Acid mg/I 29 20 50 50 104 105 70-130 0.29 30 d Report ID: 30306 - 1167062 Page 7 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 39 of 46 ?ceAnalytical i QUALITY CONTROL DATA Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 61211 61212 Original: 302960001 Original Spike MS MSD MS MSD % Rec Max Parameter Units Result Cone. Result Result % Rec % Rec Limit RPD RPD Qualifiers Propionic Acid mg/I 5.6 20 26 26 104 103 70-130 0.53 30 d Formic Acid mg/I 1.6 20 21 21 99 99 70-130 0.23 30 d Butyric Acid mg/I 0.84 20 22 22 107 106 70-130 1.1 30 d Pyruvic Acid mg/I 0.29 20 22 22 107 107 70-130 0.01 30 d i-Pentanoic Acid mg/I 0.38 20 21 21 105 103 70-130 1.9 30 d Pentanoic Acid mg/I 0.57 20 22 22 107 105 70-130 2 30 d i-Hexanoic Acid mg/I 0 20 21 20 106 101 70-130 4.9 30 d Hexanoic Acid mg/I 0.15 20 22 22 108 107 70-130 0.69 30 d Report ID: 30306 - 1167062 Page 8 of 10 CERTIFICATE OF ANALYSIS ne""p This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 40 of 46 ?ceAnalytical @ QUALITY CONTROL DATA QUALIFIERS Workorder: 30306 CABARRUS COUNTY / 2618286 QUALITY CONTROL PARAMETER QUALIFIERS The analyte concentration was determined from a dilution. The laboratory does not hold NELAP/TNI accreditation for this method or analyte. Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Page 9 of 10 Page 41 of 46 ?ceAnalytical QUALITY CONTROL DATA CROSS REFERENCE TABLE Workorder: 30306 CABARRUS COUNTY / 2618286 Pace Analytical Energy Services LLC 220 William Pitt Way Pittsburgh, PA 15238 Phone: (412) 826-5245 Fax: (412) 826-3433 Analysis Lab ID Sample ID Prep Method Prep Batch Analysis Method Batch 303060001 1302-CD-1S AM20GAX DISG/7535 303060001 1302-CD-1 S AM23G EDON/4075 Report ID: 30306 - 1167062 �rtiecp CERTIFICATE OF ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Energy Services LLC. Page 10 of 10 Page 42 of 46 I I 0 G) fl) 0 CD CD (a 3 3(D 0 w w w 0 E CD :3 0 (D (D > M 0 =1 0 ;y 0 Ey (D 40(a O o D N 3 w 3-, CD ro 0 -01 (D -U —04 51 (D N) N 0 CD a) 0 (D > w , (@ w 0 0 Q) 0 X CD (c) z (0D PI) (D 0 3 Z) -D a 0 0 0 0 S U) 0 00 cr CL 00 CAI (D O c� 0 CD ro t CD CL 71) z 0 lot HCL Unpreser,,ed 0 CD 0 0 SD < CD (D >< Sub Dissolved Carbon Dioxide A z cn A) 0 3 (D (D fJ2,1 f z m 0 z 9 R 0 0 0 0 c:) ro Page 43Pof 46 Cooler Receipt Forte_ ~e C .- Lab Work Order: Client Name. �" Project: A. Shipping/Container tnformation (circle appropriate response) Courier: FedEx UPS USPS Client Other: Air bill Present: Yes,' No Tracking Number Custody Seal on Cooler/Box Present: Yes',No Seals lntac Yes No Cooler/Box Packing Material: bubble Wrap Absorbent Foam Other: Type of lce (Wet; Blue None Ice Intact: l'es, Melted �_.. Cooler Temperature: t,- Radiation Screene€�: Yes �o Chain of Custody Present: Yes' No Comments: B. Laboratory Assignment/Log-in (check appropriate response) YES I NO I N/A Comment Reference non -Conformance Chain of Custody properly filled out I Chain of Custody relinquished It . Sampler Name & Signature on CDC Containers intact Were samples in separate bags i Sample container labels match CDC Sample name/date and time collected Sufficient volume provided PAES containers used Are containers properly preserved for the requested testing? (as labeled) L`yes, see pH form• if an unknown preservation state, were containers checked? Exception: VOA's coliform i Was volume for dissolved testing field filtered, as noted on the CDC? Was volume received in a preserved container? Headspace present? Comments: Cooler contents examined/received by Date, Project Manager Review : Date: J 30ct2017 Page 44 of 46 Xjoj-CONFoyo,/ LkNCE FORT✓ M W, )k- PAn_ ES WDTY Order =l '� Ti-nt of ReCeTl: cum tp'� FOR !,one xr ACTJON TAKEN": ch u--n4i- curoms so -ice Whals: _aw-- 20 T�ov'—)014 Dattl T =, e: - Page 45 of 46 Page 1 of 2 Emma Louis - CDM Sub outs, in Summary (3 Pace Atlanta Projects) From: Sakina Mckenzie To: Louis, Emma Date: 5/10/2019 1:16 PM Subject: CDM Sub outs, in Summary (3 Pace Atlanta Projects) C K",. Cc: Welsh, Ruth Hi Emma, Just in Summary, there are 10 samples total, for Dissolved Carbon Dioxide, Dissolved Hydrogen, Methane/Ethane/ Ethene, and Volatile Fatty Acids. Well 1302-CD-1S is separate on one project, #2618286 The other Wells are split between 2618294 (Dissolved Carbon Dioxide, Methane/Ethane/Ethene and Volatile Fatty Acids) and 2618427 Dissolved Hydrogen only. Thank you, I am so sorry. It must be hot in the field, I can't figure out what these field guys are doing with this event. Sakina Sakina -Af.-AfcXenzie Senior Project Manager Pace Analytical Services LLC. 110 Technology Pkwy NW Peachtree Corners, GA 30092 Main: 770-734-4200 ( Direct: 770-734-4204 Internal: 264204 Sakina.McKenzie@pacelabs.com >>> Sakina Mckenzie 5/10/2019 12:43 PM >>> Hi Emma, Not sure what our field samplers did, but they sampled all of the Dissolved Hydrogen separate from the rest of the parameters that we shipped to you (Carbon Dioxide, Volatile Fatty Acids, and M/E/E). I am logging the Dissolved Hydrogen now (2618427), so disregard this analysis when the samples arrive today for the rest of those parameters. Page 46 of 46 file:///C:/Users/elouis/AppData/Local/Temp/XPgrpwise/5CD579COPACE DOMAINPAE... 5/10/2019 11!;a'ceAna1j&a( wmpacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 June 04, 2019 Mathew Colone CDM Smith Inc. - Raleigh 5400 Glenwood Avenue Suite 400 Raleigh, NC 27612 RE: Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Dear Mathew Colone: Enclosed are the analytical results for sample(s) received by the laboratory on May 10, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Sakina Mckenzie sakina.mckenzie@pacelabs.com (770)734-4200 Project Manager Enclosures cc: Ms. Janelle B. Farley REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 1 of 46 11!;a'ceAna1j&a1" wmpacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Atlanta Certification IDs 110 Technology Parkway Peachtree Corners, GA 30092 Florida DOH Certification #: E87315 Georgia DW Inorganics Certification #: 812 Georgia DW Microbiology Certification #: 812 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 Louisiana/NELAP Certification # LA170028 North Carolina Drinking Water Certification #: 37706 North Carolina Field Services Certification #: 5342 North Carolina Wastewater Certification #: 12 CERTIFICATIONS North Carolina Certification #: 381 South Carolina Certification #: 98011001 Virginia Certification #: 460204 South Carolina Certification #: 99006001 Florida/NELAP Certification #: E87627 Kentucky UST Certification #: 84 Virginia/VELAP Certification #: 460221 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE SUMMARY Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Lab ID Sample ID Matrix Date Collected Date Received 2618430001 1302-MW-5 Water 05/07/19 15:25 05/10/19 09:20 2618430002 1302-MW-5 Water 05/08/19 09:44 05/10/19 09:20 2618430003 1302-MW-7 Water 05/07/19 14:41 05/10/19 09:20 2618430004 1302-MW-7 Water 05/08/19 09:30 05/10/19 09:20 2618430005 1302-MW-8A Water 05/07/19 13:41 05/10/19 09:20 2618430006 1302-MW-8A Water 05/08/19 09:25 05/10/19 09:20 2618430007 1302-MW-10 Water 05/07/19 16:18 05/10/19 09:20 2618430008 1302-MW-10 Water 05/08/19 09:53 05/10/19 09:20 2618430009 1302-MW-11 Water 05/08/19 10:17 05/10/19 09:20 2618430010 1302-MW-11 Water 05/09/19 08:05 05/10/19 09:20 2618430011 1302-Duplicate Water 05/07/19 00:00 05/10/19 09:20 2618430012 1302-Duplicate Water 05/08/19 00:00 05/10/19 09:20 2618430013 1302-Trip Blank Water 05/07/19 00:00 05/10/19 09:20 2618430014 1302-SW-1 Water 05/09/1911:58 05/10/1914:10 2618430015 1302-SW-2 Water 05/09/1911:47 05/10/1914:10 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 3 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 SAMPLE ANALYTE COUNT Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Lab ID Sample ID Method Analysts Analytes Reported Laboratory 2618430001 1302-MW-5 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430002 1302-MW-5 EPA 6020E KLH 15 PASI-GA 2618430003 1302-MW-7 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430004 1302-MW-7 EPA 6020E KLH 15 PASI-GA 2618430005 1302-MW-8A EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430006 1302-MW-8A EPA 6020E KLH 15 PASI-GA 2618430007 1302-MW-10 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430008 1302-MW-10 EPA 6020E KLH 15 PASI-GA 2618430009 1302-MW-11 EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430010 1302-MW-11 EPA 6020E KLH 15 PASI-GA 2618430011 1302-Duplicate EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430012 1302-Duplicate EPA 6020E KLH 15 PASI-GA 2618430013 1302-Trip Blank EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430014 1302-SW-1 EPA 6020E KLH 15 PASI-GA EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C 2618430015 1302-SW-2 EPA 6020E KLH 15 PASI-GA EPA 8260D LIH 52 PASI-GA EPA 8260D Mod. SAS 3 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-5 Lab ID: 2618430001 Collected: 05/07/19 15:25 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.41 Std. Units 1 05/23/19 13:38 Field Temperature 15.5 deg C 1 05/23/19 13:38 Field Specific Conductance 1887 umhos/cm 1 05/23/19 13:38 Field Turbidity 800+ NTU 1 05/23/19 13:38 Field Oxidation Potential -0.1 my 1 05/23/19 13:38 Oxygen, Dissolved 34.2 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 11.97 feet 1 05/23/19 13:38 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 12:20 630-20-6 R1 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 12:20 71-55-6 R1 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 12:20 79-34-5 R1,v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 12:20 79-00-5 R1 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 12:20 75-34-3 R1 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 12:20 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 12:20 96-18-4 M1,R1 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 12:20 96-12-8 M1,R1 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 12:20 106-93-4 R1 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 12:20 95-50-1 M1,R1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 12:20 107-06-2 R1 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 12:20 78-87-5 R1 1,4-Dichlorobenzene 9.9 ug/L 1.0 1 05/17/19 12:20 106-46-7 R1 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 12:20 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 12:20 591-78-6 R1 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 12:20 108-10-1 R1 Acetone ND ug/L 25.0 1 05/17/19 12:20 67-64-1 R1 Acrylonitrile ND ug/L 50.0 1 05/17/19 12:20 107-13-1 R1 Benzene 1.2 ug/L 1.0 1 05/17/19 12:20 71-43-2 R1 Bromochloromethane ND ug/L 1.0 1 05/17/19 12:20 74-97-5 L1,M0, R1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 12:20 75-27-4 R1 Bromoform ND ug/L 1.0 1 05/17/19 12:20 75-25-2 R1 Bromomethane ND ug/L 2.0 1 05/17/19 12:20 74-83-9 R1 Carbon disulfide ND ug/L 10.0 1 05/17/19 12:20 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 12:20 56-23-5 L1,M0, R1 Chlorobenzene 18.2 ug/L 1.0 1 05/17/19 12:20 108-90-7 R1 Chloroethane ND ug/L 1.0 1 05/17/19 12:20 75-00-3 R1 Chloroform ND ug/L 1.0 1 05/17/19 12:20 67-66-3 R1 Chloromethane ND ug/L 1.0 1 05/17/19 12:20 74-87-3 R1 Dibromochloromethane ND ug/L 1.0 1 05/17/19 12:20 124-48-1 L1,R1 Dibromomethane ND ug/L 1.0 1 05/17/19 12:20 74-95-3 L1,R1 Ethylbenzene ND ug/L 1.0 1 05/17/19 12:20 100-41-4 R1 lodomethane ND ug/L 10.0 1 05/17/19 12:20 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 12:20 75-09-2 R1 Styrene ND ug/L 1.0 1 05/17/19 12:20 100-42-5 M1,R1 Tetrachloroethene ND ug/L 1.0 1 05/17/19 12:20 127-18-4 R1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 5 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-5 Lab ID: 2618430001 Collected: 05/07/19 15:25 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Tetrahydrofuran Toluene Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 92 %. 107 %. 88 %. 83 %. Analytical Method: EPA 8260D Mod 142 ug/L 92 % 77 % 10.0 1 05/17/19 12:20 109-99-9 R1 1.0 1 05/17/19 12:20 108-88-3 R1 1.0 1 05/17/19 12:20 79-01-6 R1 1.0 1 05/17/19 12:20 75-69-4 M1,R1 2.0 1 05/17/19 12:20 108-05-4 R1 1.0 1 05/17/19 12:20 75-01-4 R1 2.0 1 05/17/19 12:20 1330-20-7 RS 1.0 1 05/17/19 12:20 156-59-2 R1 1.0 1 05/17/19 12:20 10061-01-5 R1 1.0 1 05/17/19 12:20 156-60-5 R1 1.0 1 05/17/19 12:20 10061-02-6 R1 5.0 1 05/17/19 12:20 110-57-6 M1,R1 81-119 1 05/17/19 12:20 17060-07-0 82-114 1 05/17/19 12:20 1868-53-7 82-120 1 05/17/19 12:20 460-00-4 82-109 1 05/17/19 12:20 2037-26-5 4.0 2 05/20/1914:08 123-91-1 50-150 2 05/20/1914:08 17060-07-0 50-150 2 05/20/1914:08 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 6 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-5 Lab ID: 2618430002 Collected: 05/08/19 09:44 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 8.72 NTU 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-36-0 Arsenic 0.62J ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-38-2 Barium 144 ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-39-3 Beryllium 0.13J ug/L 0.50 1 05/16/1914:34 05/20/1914:13 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:13 7440-43-9 Chromium 0.901 ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-47-3 Cobalt 19.3 ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-48-4 Copper 4.8J ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-50-8 Lead 0.29J ug/L 1.0 1 05/16/1914:34 05/20/1914:13 7439-92-1 Nickel 41.3 ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:13 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:13 7440-28-0 Vanadium 1.7J ug/L 10.0 1 05/16/1914:34 05/20/1914:13 7440-62-2 Zinc 9.51 ug/L 10.0 1 05/16/1914:34 05/20/1914:13 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 7 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-7 Lab ID: 2618430003 Collected: 05/07/19 14:41 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.56 Std. Units 1 05/23/19 13:38 Field Temperature 16.1 deg C 1 05/23/19 13:38 Field Specific Conductance 2541 umhos/cm 1 05/23/19 13:38 Field Turbidity 800+ NTU 1 05/23/19 13:38 Field Oxidation Potential -29.1 my 1 05/23/19 13:38 Oxygen, Dissolved 12.2 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 1.34 feet 1 05/23/19 13:38 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 12:46 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 12:46 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 12:46 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 12:46 79-00-5 1,1-Dichloroethane 0.54J ug/L 1.0 1 05/17/19 12:46 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 12:46 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 12:46 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 12:46 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 12:46 106-93-4 1,2-Dichlorobenzene 0.74J ug/L 1.0 1 05/17/19 12:46 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 12:46 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 12:46 78-87-5 1,4-Dichlorobenzene 9.8 ug/L 1.0 1 05/17/19 12:46 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 12:46 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 12:46 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 12:46 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 12:46 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 12:46 107-13-1 Benzene 1.0 ug/L 1.0 1 05/17/19 12:46 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 12:46 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 12:46 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 12:46 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 12:46 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 12:46 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 12:46 56-23-5 L1 Chlorobenzene 20.9 ug/L 1.0 1 05/17/19 12:46 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 12:46 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 12:46 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 12:46 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 12:46 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 12:46 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 12:46 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 12:46 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 12:46 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 12:46 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 12:46 127-18-4 Tetrahydrofuran 9.7J ug/L 10.0 1 05/17/19 12:46 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 12:46 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 8 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-7 Lab ID: 2618430003 Collected: 05/07/19 14:41 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 1.7 ug/L ND ug/L ND ug/L ND ug/L ND ug/L 96 %. 104 %. 88 %. 82 %. Analytical Method: EPA 8260D Mod. 130 ug/L 92 % 78 % 1.0 1 05/17/19 12:46 79-01-6 1.0 1 05/17/19 12:46 75-69-4 2.0 1 05/17/19 12:46 108-05-4 1.0 1 05/17/19 12:46 75-01-4 2.0 1 05/17/19 12:46 1330-20-7 1.0 1 05/17/19 12:46 156-59-2 1.0 1 05/17/19 12:46 10061-01-5 1.0 1 05/17/19 12:46 156-60-5 1.0 1 05/17/19 12:46 10061-02-6 5.0 1 05/17/19 12:46 110-57-6 81-119 1 05/17/19 12:46 17060-07-0 82-114 1 05/17/19 12:46 1868-53-7 82-120 1 05/17/19 12:46 460-00-4 82-109 1 05/17/19 12:46 2037-26-5 4.0 2 05/20/1914:27 123-91-1 50-150 2 05/20/1914:27 17060-07-0 50-150 2 05/20/1914:27 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 9 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-7 Lab ID: 2618430004 Collected: 05/08/19 09:30 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 9.81 NTU 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-36-0 Arsenic 1.6J ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-38-2 Barium 606 ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:19 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:19 7440-43-9 Chromium 0.61J ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-47-3 Cobalt 35.1 ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-48-4 Copper 0.35J ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-50-8 Lead 0.12J ug/L 1.0 1 05/16/1914:34 05/20/1914:19 7439-92-1 Nickel 77.6 ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:19 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:19 7440-28-0 Vanadium 1.1J ug/L 10.0 1 05/16/1914:34 05/20/1914:19 7440-62-2 Zinc 4.6J ug/L 10.0 1 05/16/1914:34 05/20/1914:19 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 10 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-8A Lab ID: 2618430005 Collected: 05/07/19 13:41 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.52 Std. Units 1 05/23/19 13:38 Field Temperature 15.1 deg C 1 05/23/19 13:38 Field Specific Conductance 366.2 umhos/cm 1 05/23/19 13:38 Field Turbidity 800+ NTU 1 05/23/19 13:38 Field Oxidation Potential -27.7 my 1 05/23/19 13:38 Oxygen, Dissolved 44.5 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 4.63 feet 1 05/23/19 13:38 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 13:12 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 13:12 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 13:12 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 13:12 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 13:12 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 13:12 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 13:12 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 13:12 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 13:12 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 13:12 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 13:12 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 13:12 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 13:12 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 13:12 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 13:12 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 13:12 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 13:12 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 13:12 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 13:12 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 13:12 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 13:12 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 13:12 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 13:12 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 13:12 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 13:12 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 13:12 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 13:12 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 13:12 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 13:12 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 13:12 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 13:12 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 13:12 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 13:12 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 13:12 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 13:12 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 13:12 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 13:12 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 13:12 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 11 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-8A Lab ID: 2618430005 Collected: 05/07/19 13:41 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 98 %. 105 %. 86 %. 82 %. Analytical Method: EPA 8260D Mod. 2.4 ug/L 103 % 116 % 1.0 1 05/17/19 13:12 79-01-6 1.0 1 05/17/19 13:12 75-69-4 2.0 1 05/17/19 13:12 108-05-4 1.0 1 05/17/19 13:12 75-01-4 2.0 1 05/17/19 13:12 1330-20-7 1.0 1 05/17/19 13:12 156-59-2 1.0 1 05/17/19 13:12 10061-01-5 1.0 1 05/17/19 13:12 156-60-5 1.0 1 05/17/19 13:12 10061-02-6 5.0 1 05/17/19 13:12 110-57-6 81-119 1 05/17/19 13:12 17060-07-0 82-114 1 05/17/19 13:12 1868-53-7 82-120 1 05/17/19 13:12 460-00-4 82-109 1 05/17/19 13:12 2037-26-5 2.0 1 05/19/19 14:22 123-91-1 50-150 1 05/19/19 14:22 17060-07-0 50-150 1 05/19/19 14:22 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 12 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-8A Lab ID: 2618430006 Collected: 05/08/19 09:25 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 5.71 NTU 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony 3.5J ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-36-0 Arsenic 2.3J ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-38-2 Barium 77.9 ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:25 7440-41-7 Cadmium 0.67 ug/L 0.50 1 05/16/1914:34 05/20/1914:25 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-47-3 Cobalt 6.1 ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-48-4 Copper 11.8 ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-50-8 Lead 2.2 ug/L 1.0 1 05/16/1914:34 05/20/1914:25 7439-92-1 Nickel 33.2 ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:25 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:25 7440-28-0 Vanadium 3.6J ug/L 10.0 1 05/16/1914:34 05/20/1914:25 7440-62-2 Zinc 88.1 ug/L 10.0 1 05/16/1914:34 05/20/1914:25 7440-66-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 13 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-10 Lab ID: 2618430007 Collected: 05/07/19 16:18 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.62 Std. Units 1 05/23/19 13:38 Field Temperature 16.1 deg C 1 05/23/19 13:38 Field Specific Conductance 2021 umhos/cm 1 05/23/19 13:38 Field Turbidity 800+ NTU 1 05/23/19 13:38 Field Oxidation Potential -51.2 my 1 05/23/19 13:38 Oxygen, Dissolved 17.3 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 7.20 feet 1 05/23/19 13:38 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 13:39 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 13:39 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 13:39 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 13:39 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 13:39 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 13:39 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 13:39 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 13:39 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 13:39 106-93-4 1,2-Dichlorobenzene 1.1 ug/L 1.0 1 05/17/19 13:39 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 13:39 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 13:39 78-87-5 1,4-Dichlorobenzene 8.6 ug/L 1.0 1 05/17/19 13:39 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 13:39 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 13:39 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 13:39 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 13:39 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 13:39 107-13-1 Benzene 1.1 ug/L 1.0 1 05/17/19 13:39 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 13:39 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 13:39 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 13:39 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 13:39 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 13:39 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 13:39 56-23-5 L1 Chlorobenzene 43.8 ug/L 1.0 1 05/17/19 13:39 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 13:39 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 13:39 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 13:39 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 13:39 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 13:39 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 13:39 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 13:39 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 13:39 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 13:39 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 13:39 127-18-4 Tetrahydrofuran 24.6 ug/L 10.0 1 05/17/19 13:39 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 13:39 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 14 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-10 Lab ID: 2618430007 Collected: 05/07/19 16:18 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 97 %. 102 %. 87 %. 82 %. Analytical Method: EPA 8260D Mod. 104 ug/L 90 % 76 % 1.0 1 05/17/19 13:39 79-01-6 1.0 1 05/17/19 13:39 75-69-4 2.0 1 05/17/19 13:39 108-05-4 1.0 1 05/17/19 13:39 75-01-4 2.0 1 05/17/19 13:39 1330-20-7 1.0 1 05/17/19 13:39 156-59-2 1.0 1 05/17/19 13:39 10061-01-5 1.0 1 05/17/19 13:39 156-60-5 1.0 1 05/17/19 13:39 10061-02-6 5.0 1 05/17/19 13:39 110-57-6 81-119 1 05/17/19 13:39 17060-07-0 82-114 1 05/17/19 13:39 1868-53-7 82-120 1 05/17/19 13:39 460-00-4 82-109 1 05/17/19 13:39 2037-26-5 4.0 2 05/20/1914:47 123-91-1 50-150 2 05/20/1914:47 17060-07-0 50-150 2 05/20/1914:47 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 15 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-10 Lab ID: 2618430008 Collected: 05/08/19 09:53 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 9.73 NTU 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-36-0 Arsenic 14.1 ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-38-2 Barium 116 ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-39-3 Beryllium 0.22J ug/L 0.50 1 05/16/1914:34 05/20/1914:31 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:31 7440-43-9 Chromium 1.3J ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-47-3 Cobalt 20.9 ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-48-4 Copper 3.6J ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-50-8 Lead 0.10J ug/L 1.0 1 05/16/1914:34 05/20/1914:31 7439-92-1 Nickel 123 ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:31 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:31 7440-28-0 Vanadium 1.6J ug/L 10.0 1 05/16/1914:34 05/20/1914:31 7440-62-2 Zinc 4.OJ ug/L 10.0 1 05/16/1914:34 05/20/1914:31 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 16 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-11 Lab ID: 2618430009 Collected: 05/08/19 10:17 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field pH 6.01 Std. Units 1 05/23/19 13:38 Field Temperature 14.3 deg C 1 05/23/19 13:38 Field Specific Conductance 499.7 umhos/cm 1 05/23/19 13:38 Field Turbidity 800+ NTU 1 05/23/19 13:38 Field Oxidation Potential 82.8 my 1 05/23/19 13:38 Oxygen, Dissolved 16.3 mg/L 1 05/23/19 13:38 7782-44-7 N2 Depth to Water 12.15 feet 1 05/23/19 13:38 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 18:51 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 18:51 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 18:51 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 18:51 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 18:51 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 18:51 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 18:51 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 18:51 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 18:51 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 18:51 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 18:51 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 18:51 78-87-5 1,4-Dichlorobenzene 2.1 ug/L 1.0 1 05/17/19 18:51 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 18:51 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 18:51 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 18:51 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 18:51 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 18:51 107-13-1 Benzene 0.57J ug/L 1.0 1 05/17/19 18:51 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 18:51 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 18:51 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 18:51 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 18:51 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 18:51 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 18:51 56-23-5 L1 Chlorobenzene 6.8 ug/L 1.0 1 05/17/19 18:51 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 18:51 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 18:51 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 18:51 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 18:51 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 18:51 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 18:51 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 18:51 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 18:51 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 18:51 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 18:51 127-18-4 Tetrahydrofuran 3AJ ug/L 10.0 1 05/17/19 18:51 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 18:51 108-88-3 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 17 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-11 Lab ID: 2618430009 Collected: 05/08/19 10:17 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Trichloroethene Trichlorofluoromethane Vinyl acetate Vinyl chloride Xylene (Total) cis-1,2-Dichloroethene cis-1,3-Dichloropropene trans-1,2-Dichloroethene trans- 1,3-Dichloropropene trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 97 %. 103 %. 88 %. 82 %. Analytical Method: EPA 8260D Mod. 26.2 ug/L 91 % 76 % 1.0 1 05/17/19 18:51 79-01-6 1.0 1 05/17/19 18:51 75-69-4 2.0 1 05/17/19 18:51 108-05-4 1.0 1 05/17/19 18:51 75-01-4 2.0 1 05/17/19 18:51 1330-20-7 1.0 1 05/17/19 18:51 156-59-2 1.0 1 05/17/19 18:51 10061-01-5 1.0 1 05/17/19 18:51 156-60-5 1.0 1 05/17/19 18:51 10061-02-6 5.0 1 05/17/19 18:51 110-57-6 81-119 1 05/17/19 18:51 17060-07-0 82-114 1 05/17/19 18:51 1868-53-7 82-120 1 05/17/19 18:51 460-00-4 82-109 1 05/17/19 18:51 2037-26-5 2.0 1 05/20/19 18:58 123-91-1 50-150 1 05/20/19 18:58 17060-07-0 50-150 1 05/20/19 18:58 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 18 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-MW-11 Lab ID: 2618430010 Collected: 05/09/19 08:05 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method: Field Turbidity 3.17 NTU 1 05/23/19 13:38 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-38-2 Barium 191 ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-39-3 Beryllium 0.084J ug/L 0.50 1 05/16/1914:34 05/20/1914:51 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:51 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-47-3 Cobalt 12.5 ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-48-4 Copper 1.6J ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-50-8 Lead 0.191 ug/L 1.0 1 05/16/1914:34 05/20/1914:51 7439-92-1 Nickel 12.8 ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:51 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:51 7440-28-0 Vanadium ND ug/L 10.0 1 05/16/1914:34 05/20/1914:51 7440-62-2 Zinc 8.1J ug/L 10.0 1 05/16/1914:34 05/20/1914:51 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 19 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-Duplicate Lab ID: 2618430011 Collected: 05/07/19 00:00 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:04 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 14:04 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:04 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 14:04 79-00-5 1,1-Dichloroethane 0.54J ug/L 1.0 1 05/17/19 14:04 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 14:04 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 14:04 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 14:04 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 14:04 106-93-4 1,2-Dichlorobenzene 0.83J ug/L 1.0 1 05/17/19 14:04 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 14:04 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 14:04 78-87-5 1,4-Dichlorobenzene 10.3 ug/L 1.0 1 05/17/19 14:04 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 14:04 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 14:04 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 14:04 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 14:04 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 14:04 107-13-1 Benzene 1.2 ug/L 1.0 1 05/17/19 14:04 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 14:04 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 14:04 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 14:04 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 14:04 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 14:04 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 14:04 56-23-5 L1 Chlorobenzene 21.1 ug/L 1.0 1 05/17/19 14:04 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 14:04 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 14:04 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 14:04 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 14:04 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 14:04 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 14:04 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 14:04 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 14:04 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 14:04 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 14:04 127-18-4 Tetrahydrofuran 9AJ ug/L 10.0 1 05/17/19 14:04 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 14:04 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 14:04 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 14:04 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 14:04 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 14:04 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 14:04 1330-20-7 cis-1,2-Dichloroethene 1.4 ug/L 1.0 1 05/17/19 14:04 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 14:04 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 14:04 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 14:04 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 20 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-Duplicate Lab ID: 2618430011 Collected: 05/07/19 00:00 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L 93 %. 100 %. 88 %. 82 %. Analytical Method: EPA 8260D Mod. 131 ug/L 91 % 77 % 5.0 1 05/17/19 14:04 110-57-6 81-119 1 05/17/19 14:04 17060-07-0 82-114 1 05/17/19 14:04 1868-53-7 82-120 1 05/17/19 14:04 460-00-4 82-109 1 05/17/19 14:04 2037-26-5 4.0 2 05/20/1915:06 123-91-1 50-150 2 05/20/1915:06 17060-07-0 50-150 2 05/20/1915:06 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 21 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-Duplicate Lab ID: 2618430012 Collected: 05/08/19 00:00 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-36-0 Arsenic 1.2J ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-38-2 Barium 603 ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:57 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1914:57 7440-43-9 Chromium 0.851 ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-47-3 Cobalt 34.0 ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-48-4 Copper 0.75J ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-50-8 Lead 0.27J ug/L 1.0 1 05/16/1914:34 05/20/1914:57 7439-92-1 Nickel 77.1 ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-02-0 Selenium 1.7J ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1914:57 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1914:57 7440-28-0 Vanadium 1.8J ug/L 10.0 1 05/16/1914:34 05/20/1914:57 7440-62-2 Zinc 7.2J ug/L 10.0 1 05/16/1914:34 05/20/1914:57 7440-66-6 B REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 22 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-Trip Blank Lab ID: 2618430013 Collected: 05/07/19 00:00 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:30 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 14:30 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 14:30 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 14:30 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 14:30 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 14:30 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 14:30 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 14:30 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 14:30 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:30 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 14:30 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 14:30 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 14:30 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 14:30 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 14:30 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 14:30 108-10-1 Acetone 8.3J ug/L 25.0 1 05/17/19 14:30 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 14:30 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 14:30 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 14:30 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 14:30 75-27-4 Bromoform ND ug/L 1.0 1 05/17/19 14:30 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 14:30 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 14:30 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 14:30 56-23-5 L1 Chlorobenzene ND ug/L 1.0 1 05/17/19 14:30 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 14:30 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 14:30 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 14:30 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 14:30 124-48-1 L1 Dibromomethane ND ug/L 1.0 1 05/17/19 14:30 74-95-3 L1 Ethylbenzene ND ug/L 1.0 1 05/17/19 14:30 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 14:30 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 14:30 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 14:30 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 14:30 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 14:30 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 14:30 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 14:30 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 14:30 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 14:30 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 14:30 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 14:30 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 14:30 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 14:30 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 14:30 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 14:30 10061-02-6 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 23 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-Trip Blank Lab ID: 2618430013 Collected: 05/07/19 00:00 Received: 05/10/19 09:20 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV trans-1,4-Dichloro-2-butene Surrogates 1,2-Dichloroethane-d4 (S) Dibromofluoromethane (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) 8260D MSV SIM 1,4-Dioxane (p-Dioxane) Surrogates 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 06/04/2019 11:05 AM Analytical Method: EPA 8260D ND ug/L 96 %. 102 %. 85 %. 82 %. Analytical Method: EPA 8260D Mod. 2.7 ug/L 108 % 118 % 5.0 1 05/17/19 14:30 110-57-6 81-119 1 05/17/19 14:30 17060-07-0 82-114 1 05/17/19 14:30 1868-53-7 82-120 1 05/17/19 14:30 460-00-4 82-109 1 05/17/19 14:30 2037-26-5 2.0 1 05/19/19 15:21 123-91-1 50-150 1 05/19/19 15:21 17060-07-0 50-150 1 05/19/19 15:21 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 24 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-1 Lab ID: 2618430014 Collected: 05/09/19 11:58 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 7.17 Std. Units 1 05/23/19 13:38 Field Temperature 18.9 deg C 1 05/23/19 13:38 Field Specific Conductance 357 umhos/cm 1 05/23/19 13:38 Field Turbidity 10 NTU 1 05/23/19 13:38 Field Oxidation Potential 120.1 mV 1 05/23/19 13:38 Oxygen, Dissolved 4.06 mg/L 1 05/23/19 13:38 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-38-2 Barium 66.9 ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:02 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:02 7440-43-9 Chromium 0.76J ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-47-3 Cobalt 3.OJ ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-48-4 Copper 1.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-50-8 Lead 0.16J ug/L 1.0 1 05/16/1914:34 05/20/1915:02 7439-92-1 Nickel 5.1 ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1915:02 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1915:02 7440-28-0 Vanadium 1.3J ug/L 10.0 1 05/16/1914:34 05/20/1915:02 7440-62-2 Zinc 3.9J ug/L 10.0 1 05/16/1914:34 05/20/1915:02 7440-66-6 B 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:18 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 19:18 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 19:18 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 19:18 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 19:18 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 19:18 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 19:18 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 19:18 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:18 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 19:18 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 19:18 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 19:18 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 19:18 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 19:18 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 19:18 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 19:18 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 19:18 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 19:18 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 19:18 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 19:18 75-27-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 25 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-1 Lab ID: 2618430014 Collected: 05/09/19 11:58 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromoform ND ug/L 1.0 1 05/17/19 19:18 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 19:18 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 19:18 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 19:18 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 19:18 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 19:18 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 19:18 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 19:18 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 19:18 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 19:18 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 19:18 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 19:18 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 19:18 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 19:18 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 19:18 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 19:18 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 19:18 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 19:18 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 19:18 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 19:18 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 19:18 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 19:18 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 19:18 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 19:18 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 19:18 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 19:18 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 94 %. 81-119 1 05/17/19 19:18 17060-07-0 Dibromofluoromethane (S) 106 %. 82-114 1 05/17/19 19:18 1868-53-7 4-Bromofluorobenzene (S) 87 %. 82-120 1 05/17/19 19:18 460-00-4 Toluene-d8 (S) 83 %. 82-109 1 05/17/19 19:18 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 8.7 ug/L 2.0 1 05/19/19 17:59 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 103 % 50-150 1 05/19/19 17:59 17060-07-0 Toluene-d8 (S) 123 % 50-150 1 05/19/19 17:59 2037-26-5 Date: 06/04/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 Page 26 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-2 Lab ID: 2618430015 Collected: 05/09/19 11:47 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual Field Data Analytical Method Field pH 6.74 Std. Units 1 05/23/19 13:38 Field Temperature 19.8 deg C 1 05/23/19 13:38 Field Specific Conductance 473 umhos/cm 1 05/23/19 13:38 Field Turbidity 8.78 NTU 1 05/23/19 13:38 Field Oxidation Potential 174.1 mV 1 05/23/19 13:38 Oxygen, Dissolved 5.07 mg/L 1 05/23/19 13:38 7782-44-7 N2 6020B MET ICPMS Analytical Method: EPA 6020E Preparation Method: EPA 3005A Antimony ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-36-0 Arsenic ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-38-2 Barium 83.8 ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-39-3 Beryllium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:08 7440-41-7 Cadmium ND ug/L 0.50 1 05/16/1914:34 05/20/1915:08 7440-43-9 Chromium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-47-3 Cobalt 2.3J ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-48-4 Copper 1.7J ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-50-8 Lead ND ug/L 1.0 1 05/16/1914:34 05/20/1915:08 7439-92-1 Nickel 5.1 ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-02-0 Selenium ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7782-49-2 Silver ND ug/L 5.0 1 05/16/1914:34 05/20/1915:08 7440-22-4 Thallium ND ug/L 1.0 1 05/16/1914:34 05/20/1915:08 7440-28-0 Vanadium ND ug/L 10.0 1 05/16/1914:34 05/20/1915:08 7440-62-2 Zinc 2.8J ug/L 10.0 1 05/16/1914:34 05/20/1915:08 7440-66-6 B 8260D MSV Analytical Method: EPA 8260D 1,1,1,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 20:10 630-20-6 1,1,1-Trichloroethane ND ug/L 1.0 1 05/17/19 20:10 71-55-6 1,1,2,2-Tetrachloroethane ND ug/L 1.0 1 05/17/19 20:10 79-34-5 v2 1,1,2-Trichloroethane ND ug/L 1.0 1 05/17/19 20:10 79-00-5 1,1-Dichloroethane ND ug/L 1.0 1 05/17/19 20:10 75-34-3 1,1-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 75-35-4 1,2,3-Trichloropropane ND ug/L 1.0 1 05/17/19 20:10 96-18-4 1,2-Dibromo-3-chloropropane ND ug/L 2.0 1 05/17/19 20:10 96-12-8 1,2-Dibromoethane (EDB) ND ug/L 2.0 1 05/17/19 20:10 106-93-4 1,2-Dichlorobenzene ND ug/L 1.0 1 05/17/19 20:10 95-50-1 1,2-Dichloroethane ND ug/L 1.0 1 05/17/19 20:10 107-06-2 1,2-Dichloropropane ND ug/L 1.0 1 05/17/19 20:10 78-87-5 1,4-Dichlorobenzene ND ug/L 1.0 1 05/17/19 20:10 106-46-7 2-Butanone (MEK) ND ug/L 5.0 1 05/17/19 20:10 78-93-3 2-Hexanone ND ug/L 5.0 1 05/17/19 20:10 591-78-6 4-Methyl-2-pentanone (MIBK) ND ug/L 5.0 1 05/17/19 20:10 108-10-1 Acetone ND ug/L 25.0 1 05/17/19 20:10 67-64-1 Acrylonitrile ND ug/L 50.0 1 05/17/19 20:10 107-13-1 Benzene ND ug/L 1.0 1 05/17/19 20:10 71-43-2 Bromochloromethane ND ug/L 1.0 1 05/17/19 20:10 74-97-5 L1 Bromodichloromethane ND ug/L 1.0 1 05/17/19 20:10 75-27-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 27 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 ANALYTICAL RESULTS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 Sample: 1302-SW-2 Lab ID: 2618430015 Collected: 05/09/19 11:47 Received: 05/10/19 14:10 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 8260D MSV Analytical Method: EPA 8260D Bromoform ND ug/L 1.0 1 05/17/19 20:10 75-25-2 Bromomethane ND ug/L 2.0 1 05/17/19 20:10 74-83-9 Carbon disulfide ND ug/L 10.0 1 05/17/19 20:10 75-15-0 Carbon tetrachloride ND ug/L 1.0 1 05/17/19 20:10 56-23-5 Chlorobenzene ND ug/L 1.0 1 05/17/19 20:10 108-90-7 Chloroethane ND ug/L 1.0 1 05/17/19 20:10 75-00-3 Chloroform ND ug/L 1.0 1 05/17/19 20:10 67-66-3 Chloromethane ND ug/L 1.0 1 05/17/19 20:10 74-87-3 Dibromochloromethane ND ug/L 1.0 1 05/17/19 20:10 124-48-1 Dibromomethane ND ug/L 1.0 1 05/17/19 20:10 74-95-3 Ethylbenzene ND ug/L 1.0 1 05/17/19 20:10 100-41-4 lodomethane ND ug/L 10.0 1 05/17/19 20:10 74-88-4 Methylene Chloride ND ug/L 1.0 1 05/17/19 20:10 75-09-2 Styrene ND ug/L 1.0 1 05/17/19 20:10 100-42-5 Tetrachloroethene ND ug/L 1.0 1 05/17/19 20:10 127-18-4 Tetrahydrofuran ND ug/L 10.0 1 05/17/19 20:10 109-99-9 Toluene ND ug/L 1.0 1 05/17/19 20:10 108-88-3 Trichloroethene ND ug/L 1.0 1 05/17/19 20:10 79-01-6 Trichlorofluoromethane ND ug/L 1.0 1 05/17/19 20:10 75-69-4 Vinyl acetate ND ug/L 2.0 1 05/17/19 20:10 108-05-4 Vinyl chloride ND ug/L 1.0 1 05/17/19 20:10 75-01-4 Xylene (Total) ND ug/L 2.0 1 05/17/19 20:10 1330-20-7 cis-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 156-59-2 cis-1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 20:10 10061-01-5 trans-1,2-Dichloroethene ND ug/L 1.0 1 05/17/19 20:10 156-60-5 trans- 1,3-Dichloropropene ND ug/L 1.0 1 05/17/19 20:10 10061-02-6 trans-1,4-Dichloro-2-butene ND ug/L 5.0 1 05/17/19 20:10 110-57-6 Surrogates 1,2-Dichloroethane-d4 (S) 101 %. 81-119 1 05/17/19 20:10 17060-07-0 Dibromofluoromethane (S) 107 %. 82-114 1 05/17/19 20:10 1868-53-7 4-Bromofluorobenzene (S) 89 %. 82-120 1 05/17/19 20:10 460-00-4 Toluene-d8 (S) 82 %. 82-109 1 05/17/19 20:10 2037-26-5 8260D MSV SIM Analytical Method: EPA 8260D Mod. 1,4-Dioxane (p-Dioxane) 7.3 ug/L 2.0 1 05/19/19 18:18 123-91-1 Surrogates 1,2-Dichloroethane-d4 (S) 108 % 50-150 1 05/19/19 18:18 17060-07-0 Toluene-d8 (S) 125 % 50-150 1 05/19/19 18:18 2037-26-5 Date: 06/04/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. L1 L1 L1 Page 28 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 28518 Analysis Method: EPA 6020B QC Batch Method: EPA 3005A Analysis Description: 6020E MET Associated Lab Samples: 2618430002, 2618430004, 2618430006, 2618430008, 2618430010, 2618430012, 2618430014, 2618430015 METHOD BLANK: 128448 Matrix: Water Associated Lab Samples: 2618430002, 2618430004, 2618430006, 2618430008, 2618430010, 2618430012, 2618430014, 2618430015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Antimony ug/L ND 5.0 05/20/1913:39 Arsenic ug/L ND 5.0 05/20/1913:39 Barium ug/L ND 5.0 05/20/1913:39 Beryllium ug/L ND 0.50 05/20/1913:39 Cadmium ug/L ND 0.50 05/20/1913:39 Chromium ug/L ND 5.0 05/20/1913:39 Cobalt ug/L ND 5.0 05/20/1913:39 Copper ug/L ND 5.0 05/20/1913:39 Lead ug/L ND 1.0 05/20/1913:39 Nickel ug/L ND 5.0 05/20/1913:39 Selenium ug/L ND 5.0 05/20/1913:39 Silver ug/L ND 5.0 05/20/1913:39 Thallium ug/L ND 1.0 05/20/1913:39 Vanadium ug/L ND 10.0 05/20/1913:39 Zinc ug/L 1.6J 10.0 05/20/1913:39 LABORATORY CONTROL SAMPLE: 128449 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers Antimony ug/L 100 100 100 80-120 Arsenic ug/L 100 99.2 99 80-120 Barium ug/L 100 96.3 96 80-120 Beryllium ug/L 100 99.1 99 80-120 Cadmium ug/L 100 98.6 99 80-120 Chromium ug/L 100 99.1 99 80-120 Cobalt ug/L 100 96.7 97 80-120 Copper ug/L 100 99.3 99 80-120 Lead ug/L 100 96.9 97 80-120 Nickel ug/L 100 97.3 97 80-120 Selenium ug/L 100 99.1 99 80-120 Silver ug/L 100 101 101 80-120 Thallium ug/L 100 99.5 100 80-120 Vanadium ug/L 100 100 100 80-120 Zinc ug/L 100 99.6 100 80-120 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 29 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Pace Project No.: Cabarrus County Unit 1 MSW 2618430 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128450 128451 MS MSD 2618294013 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual Antimony ug/L ND 100 100 98.2 98.6 98 98 75-125 0 20 Arsenic ug/L ND 100 100 96.5 99.2 96 99 75-125 3 20 Barium ug/L 45.9 100 100 142 140 96 94 75-125 2 20 Beryllium ug/L 0.38J 100 100 94.7 96.3 94 96 75-125 2 20 Cadmium ug/L ND 100 100 97.8 100 98 100 75-125 3 20 Chromium ug/L 2.3J 100 100 98.3 102 96 100 75-125 4 20 Cobalt ug/L 7.0 100 100 101 104 94 97 75-125 3 20 Copper ug/L 1 AJ 100 100 98.8 102 97 100 75-125 3 20 Lead ug/L 1.1 100 100 94.3 95.9 93 95 75-125 2 20 Nickel ug/L 5.8 100 100 100 105 95 99 75-125 5 20 Selenium ug/L ND 100 100 94.8 98.4 95 98 75-125 4 20 Silver ug/L ND 100 100 98.1 101 98 101 75-125 3 20 Thallium ug/L ND 100 100 94.5 95.6 94 96 75-125 1 20 Vanadium ug/L 6.2J 100 100 106 109 99 103 75-125 3 20 Zinc ug/L 13.7 100 100 105 109 92 95 75-125 3 20 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 30 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 28582 Analysis Method: EPA 8260D QC Batch Method: EPA 8260D Analysis Description: 8260D MSV Associated Lab Samples: 2618430001, 2618430003, 2618430005, 2618430007, 2618430009, 2618430011, 2618430013, 2618430014, 2618430015 METHOD BLANK: 128690 Matrix: Water Associated Lab Samples: 2618430001, 2618430003, 2618430005, 2618430007, 2618430009, 2618430011, 2618430013, 2618430014, 2618430015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 1,1,1-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1,2,2-Tetrachloroethane ug/L ND 1.0 05/17/19 11:54 v2 1,1,2-Trichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,1-Dichloroethene ug/L ND 1.0 05/17/19 11:54 1,2,3-Trichloropropane ug/L ND 1.0 05/17/19 11:54 1,2-Dibromo-3-chloropropane ug/L ND 2.0 05/17/19 11:54 1,2-Dibromoethane (EDB) ug/L ND 2.0 05/17/19 11:54 1,2-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 1,2-Dichloroethane ug/L ND 1.0 05/17/19 11:54 1,2-Dichloropropane ug/L ND 1.0 05/17/19 11:54 1,4-Dichlorobenzene ug/L ND 1.0 05/17/19 11:54 2-Butanone (MEK) ug/L ND 5.0 05/17/19 11:54 2-Hexanone ug/L ND 5.0 05/17/19 11:54 4-Methyl-2-pentanone (MIBK) ug/L ND 5.0 05/17/19 11:54 Acetone ug/L ND 25.0 05/17/19 11:54 Acrylonitrile ug/L ND 50.0 05/17/19 11:54 Benzene ug/L ND 1.0 05/17/19 11:54 Bromochloromethane ug/L ND 1.0 05/17/19 11:54 Bromodichloromethane ug/L ND 1.0 05/17/19 11:54 Bromoform ug/L ND 1.0 05/17/19 11:54 Bromomethane ug/L ND 2.0 05/17/19 11:54 Carbon disulfide ug/L ND 10.0 05/17/19 11:54 Carbon tetrachloride ug/L ND 1.0 05/17/19 11:54 Chlorobenzene ug/L ND 1.0 05/17/19 11:54 Chloroethane ug/L ND 1.0 05/17/19 11:54 Chloroform ug/L ND 1.0 05/17/19 11:54 Chloromethane ug/L ND 1.0 05/17/19 11:54 cis-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 cis-1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 Dibromochloromethane ug/L ND 1.0 05/17/19 11:54 Dibromomethane ug/L ND 1.0 05/17/19 11:54 Ethylbenzene ug/L ND 1.0 05/17/19 11:54 lodomethane ug/L ND 10.0 05/17/19 11:54 Methylene Chloride ug/L ND 1.0 05/17/19 11:54 Styrene ug/L ND 1.0 05/17/19 11:54 Tetrachloroethene ug/L ND 1.0 05/17/19 11:54 Tetrahydrofuran ug/L ND 10.0 05/17/19 11:54 Toluene ug/L ND 1.0 05/17/19 11:54 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 31 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 METHOD BLANK: 128690 Matrix: Water Associated Lab Samples: 2618430001, 2618430003, 2618430005, 2618430007, 2618430009, 2618430011, 2618430013, 2618430014, 2618430015 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers trans-1,2-Dichloroethene ug/L ND 1.0 05/17/19 11:54 trans- 1,3-Dichloropropene ug/L ND 1.0 05/17/19 11:54 trans-1,4-Dichloro-2-butene ug/L ND 5.0 05/17/19 11:54 Trichloroethene ug/L ND 1.0 05/17/19 11:54 Trichlorofluoromethane ug/L ND 1.0 05/17/19 11:54 Vinyl acetate ug/L ND 2.0 05/17/19 11:54 Vinyl chloride ug/L ND 1.0 05/17/19 11:54 Xylene (Total) ug/L ND 2.0 05/17/19 11:54 1,2-Dichloroethane-d4 (S) %. 97 81-119 05/17/19 11:54 4-Bromofluorobenzene (S) %. 86 82-120 05/17/19 11:54 Dibromofluoromethane (S) %. 103 82-114 05/17/19 11:54 Toluene-d8 (S) %. 83 82-109 05/17/19 11:54 LABORATORY CONTROL SAMPLE: Parameter 128691 Units Spike Conc. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 53.2 106 68-137 1,1,1-Trichloroethane ug/L 50 65.3 131 72-134 1,1,2,2-Tetrachloroethane ug/L 50 42.8 86 51-158 v2 1,1,2-Trichloroethane ug/L 50 58.5 117 78-131 1,1-Dichloroethane ug/L 50 61.1 122 69-151 1,1-Dichloroethene ug/L 50 65.8 132 64-158 1,2,3-Trichloropropane ug/L 50 43.1 86 78-133 1,2-Dibromo-3-chloropropane ug/L 50 41.9 84 58-124 1,2-Dibromoethane (EDB) ug/L 50 57.7 115 71-134 1,2-Dichlorobenzene ug/L 50 51.2 102 70-135 1,2-Dichloroethane ug/L 50 60.2 120 72-129 1,2-Dichloropropane ug/L 50 53.9 108 64-135 1,4-Dichlorobenzene ug/L 50 48.5 97 70-131 2-Butanone (MEK) ug/L 100 93.2 93 52-143 2-Hexanone ug/L 100 80.2 80 61-136 4-Methyl-2-pentanone (MIBK) ug/L 100 88.3 88 71-129 Acetone ug/L 100 103 103 48-224 Acrylonitrile ug/L 200 184 92 66-154 Benzene ug/L 50 59.7 119 68-132 Bromochloromethane ug/L 50 71.5 143 73-133 L1 Bromodichloromethane ug/L 50 52.8 106 67-121 Bromoform ug/L 50 51.4 103 57-125 Bromomethane ug/L 50 48.2 96 35-156 Carbon disulfide ug/L 100 119 119 47-141 Carbon tetrachloride ug/L 50 65.2 130 66-122 L1 Chlorobenzene ug/L 50 49.3 99 71-126 Chloroethane ug/L 50 45.8 92 43-143 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 32 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 LABORATORY CONTROL SAMPLE: Parameter 128691 Units Spike Conc. LCS LCS Result % Rec Chloroform ug/L 50 62.7 Chloromethane ug/L 50 43.0 cis-1,2-Dichloroethene ug/L 50 62.3 cis-1,3-Dichloropropene ug/L 50 52.3 Dibromochloromethane ug/L 50 57.8 Dibromomethane ug/L 50 65.8 Ethylbenzene ug/L 50 49.1 lodomethane ug/L 100 129 Methylene Chloride ug/L 50 61.4 Styrene ug/L 50 56.6 Tetrachloroethene ug/L 50 67.0 Tetrahydrofuran ug/L 100 94.9 Toluene ug/L 50 56.5 trans-1,2-Dichloroethene ug/L 50 63.8 trans- 1,3-Dichloropropene ug/L 50 52.2 trans-1,4-Dichloro-2-butene ug/L 100 68.5 Trichloroethene ug/L 50 51.4 Trichlorofluoromethane ug/L 50 57.7 Vinyl acetate ug/L 50 40.5 Vinyl chloride ug/L 50 49.6 Xylene (Total) ug/L 150 156 1,2-Dichloroethane-d4 (S) %. 4-Bromofluorobenzene (S) %. Dibromofluoromethane (S) %. Toluene-d8 (S) %. % Rec Limits Qualifiers 125 71-136 86 47-123 125 74-131 105 78-120 116 65-115 L1 132 79-129 L1 98 68-129 129 49-154 123 61-147 113 77-128 134 51-139 95 56-147 113 60-133 128 69-144 104 74-128 68 61-139 103 73-126 115 55-132 81 52-141 99 50-133 104 78-132 100 81-119 89 82-120 114 82-114 81 82-109 SO MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 MS 2618430001 Spike Parameter Units Result Conc. MSD Spike Conc. 128693 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 1,1,1,2-Tetrachloroethane ug/L ND 50 50 35.9 51.3 72 103 68-137 35 11 R1 1,1,1-Trichloroethane ug/L ND 50 50 52.0 70.2 104 140 66-142 30 11 R1 1,1,2,2-Tetrachloroethane ug/L ND 50 50 28.6 40.1 57 80 39-171 34 13 R1,v2 1,1,2-Trichloroethane ug/L ND 50 50 40.5 55.7 81 111 73-136 32 12 R1 1,1-Dichloroethane ug/L ND 50 50 45.4 60.9 91 122 66-155 29 15 R1 1,1-Dichloroethene ug/L ND 50 50 56.1 75.8 112 152 33-181 30 34 1,2,3-Trichloropropane ug/L ND 50 50 27.8 39.6 56 79 78-133 35 14 M1,R1 1,2-Dibromo-3- ug/L ND 50 50 28.5 39.4 57 79 58-124 32 15 M1,R1 chloropropane 1,2-Dibromoethane (EDB) ug/L ND 50 50 40.4 55.0 81 110 71-134 31 12 R1 1,2-Dichlorobenzene ug/L ND 50 50 34.5 48.8 68 97 69-135 34 10 M1,R1 1,2-Dichloroethane ug/L ND 50 50 42.2 57.8 84 116 36-159 31 10 R1 1,2-Dichloropropane ug/L ND 50 50 38.8 52.7 78 105 68-132 30 11 R1 1,4-Dichlorobenzene ug/L 9.9 50 50 42.6 56.1 65 92 49-153 27 9 R1 2-Butanone (MEK) ug/L ND 100 100 63.1 75.9 63 76 10-189 18 23 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 33 of 46 11!;a'ceAna1j&a( WNW pacalabs.com Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 128692 MS 2618430001 Spike Parameter Units Result Conc. MSD Spike Conc. 128693 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Max RPD Qual 2-Hexanone ug/L ND 100 100 58.9 80.7 59 81 40-135 31 18 R1 4-Methyl-2-pentanone ug/L ND 100 100 63.7 86.4 64 86 30-177 30 10 R1 (MIBK) Acetone ug/L ND 100 100 65.5 78.9 65 79 44-223 19 14 R1 Acrylonitrile ug/L ND 200 200 131 175 65 87 13-189 29 12 R1 Benzene ug/L 1.2 50 50 45.3 61.2 88 120 66-139 30 10 R1 Bromochloromethane ug/L ND 50 50 49.7 67.9 99 136 73-133 31 13 MO, R1 Bromodichloromethane ug/L ND 50 50 36.6 50.6 73 101 57-120 32 13 R1 Bromoform ug/L ND 50 50 33.0 46.0 66 92 48-128 33 13 R1 Bromomethane ug/L ND 50 50 28.6 45.9 57 92 10-187 47 32 R1 Carbon disulfide ug/L ND 100 100 97.4 130 97 130 47-141 29 322 Carbon tetrachloride ug/L ND 50 50 53.9 73.5 108 147 58-127 31 14 M0,R1 Chlorobenzene ug/L 18.2 50 50 52.2 65.6 68 95 63-137 23 10 R1 Chloroethane ug/L ND 50 50 37.3 50.6 75 101 52-146 30 16 R1 Chloroform ug/L ND 50 50 44.3 60.2 89 120 74-137 31 9 R1 Chloromethane ug/L ND 50 50 34.8 44.7 70 89 41-127 25 10 R1 cis-1,2-Dichloroethene ug/L ND 50 50 44.7 60.2 89 120 71-138 30 16 R1 cis-1,3-Dichloropropene ug/L ND 50 50 33.9 46.5 68 93 32-145 32 12 R1 Dibromochloromethane ug/L ND 50 50 38.8 53.9 78 108 52-116 33 13 R1 Dibromomethane ug/L ND 50 50 43.8 60.2 88 120 79-129 32 14 R1 Ethylbenzene ug/L ND 50 50 35.7 48.7 71 97 31-174 31 10 R1 lodomethane ug/L ND 100 100 102 138 102 138 49-154 30 30 Methylene Chloride ug/L ND 50 50 45.1 62.5 90 125 61-146 32 15 R1 Styrene ug/L ND 50 50 37.7 52.6 75 105 77-128 33 14 M1,R1 Tetrachloroethene ug/L ND 50 50 52.1 66.3 104 133 36-155 24 14 R1 Tetrahydrofuran ug/L ND 100 100 69.4 89.6 69 90 56-147 25 12 R1 Toluene ug/L ND 50 50 42.3 56.2 84 112 52-146 28 11 R1 trans-1,2-Dichloroethene ug/L ND 50 50 48.3 64.1 97 128 61-152 28 14 R1 trans-1,3-Dichloropropene ug/L ND 50 50 33.6 46.4 67 93 37-146 32 12 R1 trans-1,4-Dichloro-2-butene ug/L ND 100 100 43.3 57.3 43 57 61-139 28 12 M1,R1 Trichloroethene ug/L ND 50 50 38.0 49.6 76 99 61-141 26 12 R1 Trichlorofluoromethane ug/L ND 50 50 57.3 75.3 115 151 51-141 27 13 M1,R1 Vinyl acetate ug/L ND 50 50 50.5 30.5 101 61 52-141 49 14 R1 Vinyl chloride ug/L ND 50 50 42.9 57.3 85 114 22-156 29 26 R1 Xylene (Total) ug/L ND 150 150 112 152 74 102 78-132 31 7 RS 1,2-Dichloroethane-d4 (S) %. 98 97 81-119 4-Bromofluorobenzene (S) %. 88 89 82-120 Dibromofluoromethane (S) %. 110 113 82-114 Toluene-d8 (S) %. 80 81 82-109 SO Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 34 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 476071 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618430005, 2618430013 METHOD BLANK: 2579453 Associated Lab Samples: 2618430005, 2618430013 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed ND 2.0 05/19/1910:45 102 50-150 05/19/1910:45 113 50-150 05/19/1910:45 Qualifiers LABORATORY CONTROL SAMPLE: 2579454 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.1 100 70-130 1,2-Dichloroethane-d4 (S) % 99 50-150 Toluene-d8(S) % 112 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579455 2579456 MS MSD 2618286002 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L ND 20 20 25.7 20.3 129 101 50-150 24 30 1,2-Dichloroethane-d4 (S) % 109 109 50-150 30 Toluene-d8 (S) % 128 129 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 35 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 476081 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618430009 METHOD BLANK: 2579514 Associated Lab Samples: 2618430009 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed Qualifiers ND 2.0 05/20/1911:14 91 50-150 05/20/1911:14 83 50-150 05/20/1911:14 LABORATORY CONTROL SAMPLE: 2579515 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 20.0 100 70-130 1,2-Dichloroethane-d4 (S) % 96 50-150 Toluene-d8 (S) % 86 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579516 2579517 MS MSD 2618294008 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 9.8 20 20 27.4 32.0 88 111 50-150 16 30 1,2-Dichloroethane-d4 (S) % 104 104 50-150 30 Toluene-d8 (S) % 101 102 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 36 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 476082 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618430014, 2618430015 METHOD BLANK: 2579529 Associated Lab Samples: 2618430014, 2618430015 Parameter Units 1,4-Dioxane (p-Dioxane) ug/L 1,2-Dichloroethane-d4 (S) % Toluene-d8 (S) % Matrix: Water Blank Reporting Result Limit Analyzed ND 2.0 05/19/1911:05 102 50-150 05/19/1911:05 114 50-150 05/19/1911:05 Qualifiers LABORATORY CONTROL SAMPLE: 2579530 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.4 97 70-130 1,2-Dichloroethane-d4 (S) % 106 50-150 Toluene-d8(S) % 113 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2579531 2579532 MS MSD 2618430014 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane(p-Dioxane) ug/L 8.7 20 20 27.4 23.7 94 75 50-150 14 30 1,2-Dichloroethane-d4 (S) % 113 118 50-150 30 Toluene-d8 (S) % 129 130 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 37 of 46 11!;a'ceAna1j&a( wNW Pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 QC Batch: 476323 Analysis Method: EPA 8260D Mod. QC Batch Method: EPA 8260D Mod. Analysis Description: 8260D MSV SIM Associated Lab Samples: 2618430001, 2618430003, 2618430007, 2618430011 METHOD BLANK: 2580465 Matrix: Water Associated Lab Samples: 2618430001, 2618430003, 2618430007, 2618430011 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,4-Dioxane (p-Dioxane) ug/L ND 2.0 05/20/19 10:54 1,2-Dichloroethane-d4 (S) % 93 50-150 05/20/19 10:54 Toluene-d8 (S) % 84 50-150 05/20/19 10:54 LABORATORY CONTROL SAMPLE: 2580466 Spike LCS LCS % Rec Parameter Units Conc. Result % Rec Limits Qualifiers 1,4-Dioxane (p-Dioxane) ug/L 20 19.8 99 70-130 1,2-Dichloroethane-d4 (S) % 95 50-150 Toluene-d8 (S) % 87 50-150 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2580467 2580468 MS MSD 92428710003 Spike Spike MS MSD MS MSD % Rec Max Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual 1,4-Dioxane (p-Dioxane) ug/L 128 40 40 183 178 137 125 50-150 3 30 1,2-Dichloroethane-d4 (S) % 94 93 50-150 30 Toluene-d8 (S) % 80 79 50-150 30 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 38 of 46 11!;a'ceAna1j&a1" WNW'pacalabsxom Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALIFIERS Project: Cabarrus County Unit 1 MSW Pace Project No.: 2618430 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI -The NELAC Institute. IW_1.101Ica] NI*i PASI-C Pace Analytical Services - Charlotte PASI-GA Pace Analytical Services - Atlanta, GA ANALYTE QUALIFIERS B Analyte was detected in the associated method blank. L1 Analyte recovery in the laboratory control sample (LCS) was above QC limits. Results for this analyte in associated samples may be biased high. MO Matrix spike recovery and/or matrix spike duplicate recovery was outside laboratory control limits. M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. N2 The lab does not hold NELAC/TNI accreditation for this parameter but other accreditations/certifications may apply. A complete list of accreditations/certifications is available upon request. R1 RPD value was outside control limits. RS The RPD value in one of the constituent analytes was outside the control limits. SO Surrogate recovery outside laboratory control limits. v2 The continuing calibration verification was below the method acceptance limit. The analyte was not detected in the associated samples and the sensitivity of the instrument was verified with a reporting limit check standard. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 06/04/2019 11:05 AM without the written consent of Pace Analytical Services, LLC. Page 39 of 46 11!;a'ceAna1j&a1" WNW'pacalabs.cam Pace Analytical Services, LLC 110 Technology Parkway Peachtree Corners, GA 30092 (770)734-4200 QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pace Project No.: Cabarrus County Unit 1 MSW 2618430 Analytical Lab ID Sample ID QC Batch Method QC Batch Analytical Method Batch 2618430001 1302-MW-5 28595 2618430002 1302-MW-5 28595 2618430003 1302-MW-7 28595 2618430004 1302-MW-7 28595 2618430005 1302-MW-8A 28595 2618430006 1302-MW-8A 28595 2618430007 1302-MW-10 28595 2618430008 1302-MW-10 28595 2618430009 1302-MW-11 28595 2618430010 1302-MW-11 28595 2618430014 1302-SW-1 28595 2618430015 1302-SW-2 28595 2618430002 1302-MW-5 EPA 3005A 28518 EPA 6020B 28525 2618430004 1302-MW-7 EPA 3005A 28518 EPA 6020B 28525 2618430006 1302-MW-8A EPA 3005A 28518 EPA 6020B 28525 2618430008 1302-MW-10 EPA 3005A 28518 EPA 6020B 28525 2618430010 1302-MW-11 EPA 3005A 28518 EPA 6020B 28525 2618430012 1302-Duplicate EPA 3005A 28518 EPA 6020B 28525 2618430014 1302-SW-1 EPA 3005A 28518 EPA 6020B 28525 2618430015 1302-SW-2 EPA 3005A 28518 EPA 6020B 28525 2618430001 1302-MW-5 EPA 8260D 28582 2618430003 1302-MW-7 EPA 8260D 28582 2618430005 1302-MW-8A EPA 8260D 28582 2618430007 1302-MW-10 EPA 8260D 28582 2618430009 1302-MW-11 EPA 8260D 28582 2618430011 1302-Duplicate EPA 8260D 28582 2618430013 1302-Trip Blank EPA 8260D 28582 2618430014 1302-SW-1 EPA 8260D 28582 2618430015 1302-SW-2 EPA 8260D 28582 2618430001 1302-MW-5 EPA 8260D Mod. 476323 2618430003 1302-MW-7 EPA 8260D Mod. 476323 2618430005 1302-MW-8A EPA 8260D Mod. 476071 2618430007 1302-MW-10 EPA 8260D Mod. 476323 2618430009 1302-MW-11 EPA 8260D Mod. 476081 2618430011 1302-Duplicate EPA 8260D Mod. 476323 2618430013 1302-Trip Blank EPA 8260D Mod. 476071 2618430014 1302-SW-1 EPA 8260D Mod. 476082 2618430015 1302-SW-2 EPA 8260D Mod. 476082 Date: 06/04/2019 11:05 AM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 40 of 46 i i i D 3 OD. O O 1D ro i o to ao .t o► C" A. c) tJ i ITEM # _ 0 c 2 3fq N 7 D pW p N N N W W W pW pW W pW 0 0 Ci � O ry c� N a �N0�3 3 r C 10 8 3 D Y} g v M m C g x v m X N � X (D N a d _ y-la yr y 0 C 3 0 T m N N O a m 3 3 0 9 wr wr WT WT WT WT WT WT WT WT WT WT MATRIX CODE (see valid codes to left) m Ian = y cg m S F G !) G) G) G) G) G) G) G) !7 G) G) G'm SAMPLETYPE (G=GRAB C=COMP) 0 m G m tr a 0 0 cll V, Cil Clt CA a Cif -3U l7 m 1D s S3 0 U f 1 �� �1 m cr 0 m � l r0 r n D m j m m m o m o s m m m SAMPLE TEMP AT COLLECTION 3 o 2 a OF CONTAINERS 0 $ y $ y $ a Unpreserved p H b $ H2SO4 o �• o 0z '� ? no � HNO3 c� HCI m o 0 N NaOH czi Na2S203 N m Methanol 04 Other Analyses Test YIN App. I VOC by 8260 + &4f a /� 8270 SVOC (Bis-2-eh)phthalate = BOD 5-day, Alk, Cl. NO3. SO4 COD Sulfide by SM4500-S2-D Li Alk, Cl, SO4, TDS Q m Dissolved Gases (CO2. M. E. E) a m Dissolved Gases (VFA) / TOC 3 Dissolved Gases (Hydrogen) % X. x f jc, x App. I Metals + Fe, Mn, Hg ?1 =. X pH/CON/Temp/Turb/DO/ORP N xJst I Ik xplygoliffe I(TurbjOd to Residual Chlorine (Y/N) r o 0 � D O 3 � °z mw t I m L--p age 41 of 46 fa CD v m k 0 M 0 w ; o 0 co .t of rr A. w ro .+ ITEM # ; d c 3 � _ N N W3 C 7 a ` D m m m m m m m m m m w c 0 g m 3 ® �' o 0 3 0 3 1 .O N m Na m N 3 N c N 3 m ► o .� ��I m m m m to ?I T �gtiO�aFF�� 8 S�mFa m m m 0 m M 0 0' O D O N a F F 7 T m Z m 0 0 3 s 3 0 9 WT WT WT WT WT WT WT WT WT WT WT WT MATRIX CODE (see valid codes to left) 3 = m SAMPLE TYPE (G=GRAB C=COMP) m` c 0 i 3, 41 m w o O D m m m_ r^ o m ' :U Q n m r0 r- m z n m n m m M m o m zz m y m e y D n 0 D o SAMPLE TEMP AT COLLECTION # OF CONTAINERS m m m 0.3 m. M Unpreserved v-0 p N ° 3 02 O O O .. .0 7 n H2SO4 HNO3 w � m m o' 3 o IFN HCI o m w N ' NaOH �t Na2S203 (D m Methanol 0 Other Analyses Test Y/N r x App. I VOC by 8260 + 0 z 8270 SVOC (Bis-2-eh)phthalate � BOD 5-day, Alk, Cl, NO3, SO4 COD Sulfide by SM4500-S2-D Alk, Cl. SO4, TDS Q s � Dissolved Gases (CO2, M. E. E) a M Dissolved Gases (VFA) / TOC Dissolved Gases (Hydrogen) LAN I App. I Metals + Fe, Mn, Hg p WCON/Temp/Tu rb/DO/ORP y d pWCON/Temp/Turb/DO/ORP/Fe m rp Residual Chlorine (WN) z 0 c � � n -1n age 42 of 46 rFSample Conditionpon Re" WO# : 2618430 FaceAn O"y al Client Name: PM: SMM Due Date: 05/29/19 IV CLIENT: CDM-Raleigh Courier: E<Fed Ex ❑ UPS ❑ USPS ❑ Client ❑ Commercial ❑ Pace Ott Tracking #: % 71 �, �— g Lf �'3 Custody Seal on Cooler/Box Present: DTfs-___E1 no Seals intact: yes Packing Material: ubbleeA Wrap ❑Bubble Bags ❑ None El Other Tharmnmetar Used (l �? _�' Tvoe of Ice: �D Blue None t'm. uue Liam El no I Proj. Name: I ❑ Samples on ice. cooling process has begun C Cooler Temperature 2-c 3 Biological Tissue is Frozen: Yes No Date and Initi I of p rson xa ing contents: Temp should be above freezing to 6 C Comments: Chain of Custody Present: 9Yes ONO ❑N/A 1. Chain of Custody Filled Out: Yes ONO ❑N/A 2. Chain of Custody Relinquished: 0 r�❑No ❑N/A 3. Sampler Name & Signature on COC: Bles ❑No ❑N/A 4. Samples Arrived within Hold Time: ElYes ONO ❑N/A 5. Short Hold Time Analysis (<72hr): ❑Yes o ❑N/A 6. Rush Turn Around Time Requested: ❑Yes No ❑MA 7. Sufficient Volume: KrYes ONO ❑NIA 8. Correct Containers Used: Yes ONO ❑NIA g. -Pace Containers Used: Yes ONO ❑N/A Containers Intact: es ONO ❑NIA 10. Filtered volume received for Dissolved tests ❑Yes ONO /A 11. Sample Labels match COC: En es No ❑NIA 12. -Includes date/time/ID/Analysis Matrix: All containers needing preservation have been checked. // 'f���Yes ❑No ❑WA 13. All containers needing preservation are found to be in es ONO ❑NIA compliance with EPA recommendation. Initial when Lot # of added ❑No exceptions:Ocoliform, TOC, O&G, WI-DRO (water) Yes completed preservative Samples checked for dechlorination: ❑Yes ONO E N:A 14. Headspace in VOA Vials ( >6mm): ❑Yes o ❑N!A 15. Trip Blank Present: ZYes ONO ON A 16. Trip Blank Custody Seals Present Oles ONO ❑N,A Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y / N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office ( i.e out of hold, incorrect preservative, out of temp, incorrect containers) F-ALLC003rev.3, 11Septier28fd646 $ g m m a o . FFm w o m 00 .t w N a w IN ITEM # m d. e c O m N j � 7 4 8 n n D N� r V o`�m'o.. N �_ N 3 CO) 62 y O o n ma 3 `� f c. w� a 0 n CI C i0 3 N 5 O (ta- tt,_ _ $ ° g v a x 3 4Phb �_ 0 0 c i eS ngg o m -p � )5 yy AOrr v20 R QQ 3 N o G 3 C• O SN� V < m # d O n W m O a v MATRIX CODE (see valid codes to left) m itCr0 w w C m o SAMPLE TYPE (G=GRAB C=COMP) o 0 v m m o m D C C 5 v i m C W V � A Z r- r 0 2 nn 1 O N m m m m m P. P. z o cn c O � m m mr SAMPLE TEMP AT COLLECTION w w w a o < g v v g OF CONTAINERS 8 8 8 a 3 0 c f ; m Unpreserved v v p y> o > o� G H2SO4 m _o I z c -0 r— HNO3 s, HCI g w m o rn rn m NaOH 4 Ne2S203 M y e1 ut 'Sot ci x Analyses Test YIN x x NC App I VOC EDBDBCP C co D o " " 1A Dioxane a z o x x NC App I Metals C m y x x pH, SC, TEMP. TURB, DO, ORP (on n o 3 Ln r9 3 m m TEMP in C N Residual Chlorine (Y/N) D >3 c o Received on Ice 3 g (YIN) Custody Sealed O Cooler o Y/N Samples Intact (Y/N) ILI Q, i 9 Page 44 of 46 SAMPLING INFORMATION SHEET SCHEDULE: May 2019 CLIENT NAME: CAMP, DRESSER, & MCKEE, INC. - RALEIGH CLIENT ADDRESS: 5400 GLENWOOD AVE., RALEIGH, NC 27612 CLIENT PHONE: 919/787-5620 CLIENT CONTACT: MAT COLONE SITE NAME: CABARRUS COUNTY SANITARY LANDFILL SITE ADDRESS: 4441 IRISH POTATO ROAD, CONCORD, NC 28206 SITE PHONE: 704/920-2951 SITE CONTACT: Kevin Grant Randal PROJECT NAME: CABARRUS CO LANDFILL UNIT 1 SEMI-ANNUAL EQUIPMENT NEEDED: KEYS (onsite), ROPE, BAILERS, YSI 556 KIT, CH4 METER, TURB METER NOTES: SHIP SAMPLES ASAP The State is coming down on inorganic exceedances and is looking closer at the correlations of turbidity and metal detections. Looking at previous data, your team does a good job of keeping turbidity to a minimum. Please continue to do SO. DIRECTIONS: • I-85 North into North Carolina, go through Charlotte, Take Exit 63, turn right off the exit (Lane St.) • Go to the stop sign, turn left onto Old Concord -Salisbury Rd. • Turn right onto the first paved road - Irish Potato Road • Landfill is 3-1/2 miles on the right SAMPLER (S) /DATE (S) : 5 . to. � � Page 1 of 3 Page 45 of 46 Sample Condition Upon ' WOC 2618430 PaceAw&ftal Client Name: PM: SMM Due Date: 05/29/19 ��/ CLIENT: CDM-Raleigh Courier: �Ex El ups ElUSPS El Client El Commercial L"J Pace Other g Proj. Due uaic. Tracking #: I 5 Proj. Name: Custody Seal on Cooler/Box Present: es ❑ no Seals intact es ❑ no Packing Material: ❑ Bubble Wrap ubble Bags ❑ None � ❑ Other U Thermometer Used ,? ) Tvpe of Ice: / Wet,) Blue None ❑ Samples on ice coolmq process has bequn Cooler Tem erature `__ Biological Tissue is Frozen: Yes No Date and IniY s per o examining p contents: � Temp should be above freezing to 6°C Comments: Chain of Custody Present: es ONO ❑N/A 1. Chain of Custody Filled Out: es ONO ❑NIA 2. Chain of Custody Relinquished: SdTeS ONO ❑N/A 3. Sampler Name & Signature on COC: es ONO ❑N/A 4. Samples Arrived within Hold Time: Prg—s ONO ❑N/A 5. Short Hold Time Analysis <72hr): ❑Yes 9 o ❑N/A 6, Rush Turn Around Time Requested: ❑Yes 6No ❑N/A 7. Sufficient Volume: Yes ❑No ❑N/A g. Correct Containers Used: Yes ONO ❑N/A g. -Pace Containers Used: Yes ONO ❑N/A Containers Intact: es ONO ❑N/A 10. Filtered volume received for Dissolved tests ❑Yes ONO f 511A' 11. Sample Labels match COC: es ❑No ❑N:A 12 -Includes date/time/ID/Analysis Matri S V All containers needing preservation have been checke . es ❑No ON+A 13. All containers needing preservation are found to be in yes El ❑NIA compliance with EPA recommendation. Initial when Lot t# of added exception v0 coliform, TOC, O&G, WI-DRO (water) Yes ❑No completed preservative Samples checked for dechlorination: ❑Yes ONO ErNIA 14. Headspace in VOA Vials ( >6mm): ❑Yes QI�❑NrA 15. Trip Blank Present: ❑Yes No ❑NIA Trip Blank Custody Seals Present ❑Yes ONO ZNIA Pace Trip Blank Lot # (if purchased): Client Notification/ Resolution: Person Contacted: Comments/ Resolution: Project Manager Review: Date/Time: Field Data Required? Y / N Date: Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form will be sent to the North Carolina DEHNR Certification Office (Le out of hold, incorrect preservative, out of temp, incorrect containers) F-ALLC003rev.3, 11SeptgMff6r460Ef46