3902_Granville_Butner_MSWLF_GW_FID1321758_20190529

pENR USE ONL_Y_.t ❑Paper Report ❑E_lectronic Data - Email CD (data loaded: Yes / No Doc/Event #:
NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
Prepare one form for each individually monitored unit.
Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 213 surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section. 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
LaBella Associates
Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address:
Name: G. Van Ness Burbach, Ph.D., P.G. Phone: [phone]
E-mail: [e-mail]
NC Landfill Rule: Actual sampling dates (e.g.,
Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006)
State Road 1004 February 04, 2019
Butner Landfill Butner, NC 39 02 .1600
Environmental Status: (Check all that apply)
❑ Initial/Background Monitoring Detection Monitoring X Assessment Monitoring Corrective Action
of data submitted: (Check all that apply)
Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells a
Leachate monitoring data ❑
Surface water monitoring data
Methane gas monitoring data
Corrective action data (specify) MNA Data
Other(specify)
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct.
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment.
G. VanNess Burbach. Ph.D., PG Technical Consultant [phone]
Facility Rygceseg�aWe Nawwa Title (Area Code) Telephone Number
2211 W. Meadowview Rd., Ste. 101 Greensboro, NC 27407
Facility Representative Address
C-07s2
NC PE Firm License Number (if applicable effective May 1, 2009)
Affix NC Licensed/ Professional Geologist Seal
9
SEAL
134�
9y FCC 0G1`fi P;
Revised 6/2009

Prepared For:
Granville County
Solid Waste Department
P.O. Box go6
Oxford, North Carolina 27565
4"'
'77t
Submitted by:
LaBeL a Associates
2211 West Meadowview Rd.
Suite 1o1
Greensboro, NC 27407
[phone]
NC License No. C-0782
LaBeRa
Powered by partnership.
FEBRUARY 2019 SEMIANNUAL WATER QUALITY
MONITORING REPORT
BUTNER LANDFILL
Permit NO. 39-02
MAY 2019
PROJECT NO. 2182022.01.07

February 2019 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS
1.0
INTRODUCTION....................................................................................................................1
1.1
Site Information..................................................................................................................1
1.2
Site Geology.........................................................................................................................1
1.3
Regulatory Status................................................................................................................1
2.0
FACILITY MONITORING PROGRAM.....................................................................................2
2.1
Groundwater Monitoring Program.....................................................................................2
2.2
Surface Water Monitoring Program...................................................................................3
3.0
February 2018 SEMIANNUAL SAMPLING EVENT.............................................................3
3.1
Field Work............................................................................................................................3
3.2
Laboratory Analyses and Quality Control...........................................................................4
4.0
ANALYTICAL RESULTS AND STATISTICAL ANALYSES........................................................5
4.1
Analytical Results for Groundwater and Comparisons to Standards ..............................5
4.1.1 Inorganic Analyses...................................................................................................
5
4.1.2 Organic Analyses......................................................................................................
5
4.2
Statistical Analyses.............................................................................................................5
4.2.1 Statistical Methods..................................................................................................
5
4.2.2 Results of Statistical Analyses................................................................................
6
4.3
Analytical Results for Surface Water and Comparisons to Standards
............................6
5.0
HYDROGEOLOGICAL CONDITIONS.....................................................................................6
6.0
CORRECTIVE ACTION EVALUATION....................................................................................7
6.1
Monitored Natural Attenuation Parameters......................................................................7
6.2
Phytoremediation................................................................................................................7
6.3
Evaluation of Plume Stability and Trends..........................................................................8
7.0
CONCLUSIONS.....................................................................................................................8
8.0
ACRONYMS..........................................................................................................................8
9.0
REFERENCES.....................................................................................................................10
Granville County - Butner Landfill, Permit No. 39-02 LaBella Associates
February 2019 Semiannual Water Quality Monitoring Report April 2019
i

February 2019 Semiannual Water Quality Monitoring Report
Butner Landfill, Permit No. 39-02
Granville County, North Carolina
TABLE OF CONTENTS (CONTINUED)
Tables
Table 1
February 2019 Groundwater Elevations
Table 2
February 2019 Field Parameters
Table 3
Detected Constituents in Groundwater and Surface Water
Table 4
Exceedances of Groundwater Standards
Table 5
Hydraulic Gradients and Groundwater Flow Velocities
Table 6
Monitored Natural Attenuation Parameters
Charts
Chart 1
Benzene Concentrations vs. Time
Chart 2
Cobalt Concentrations vs. Time
Figure
Figure 1
Site Location Map
Drawings
Drawing 1 Groundwater Potentiometric Surface Map
Appendices
Appendix A
Monitoring Well Construction Data
Appendix B
Field Data Logs
Appendix C
Laboratory Analytical Reports and Chains of Custody
Appendix D
Historical Groundwater Elevations
Appendix E
Historical Constituents in Groundwater
Appendix F
Statistical Analysis Calculation Sheets
Appendix G
Historical Constituents in Surface Water
Granville County - Butner Landfill, Permit No. 39-02 La Bella Associates
February 2019 Semiannual Water Quality Monitoring Report April 2019
ii

1.0 INTRODUCTION
1.1 Site Information
The Butner Landfill is a closed municipal solid waste (MSW) landfill, located off State Route 1004
near the town of Butner, in Granville County, North Carolina (Figure 1). The Butner facility started
receiving solid waste prior to May 1973. Permit Number 39-02, was issued by the State of North
Carolina on March 3, 1982. The facility stopped receiving solid waste in August 1998. At the
present, a small recycling center and transfer station are operated by the County of Granville at the
entrance of the closed landfill.
In accordance with North Carolina Solid Waste Management Regulations (NCSWMR), the Butner
Landfill entered an Assessment Monitoring Program in December of 1997 as a result of detections
of volatile organic compounds and pesticides above Title 15A of the North Carolina Administrative
Code Subchapter 2L (NC2L) Groundwater Standards. An Assessment of Corrective Measures (ACM)
was initiated in 2003, and then suspended by North Carolina Department of Environment and
Natural Resources (NCDENR) [now the North Carolina Department of Environmental Quality
(NCDEQ)] since there had been no more NC2L exceedances. The Nature and Extent Study (NES) and
ACM recommenced in 2007 when apparent volatile organic compound (VOC) exceedances of the
NC2L Standards began to appear; however, they were again suspended when it was determined that
the apparent exceedances were not statistically significant increases (SSTs) above background. An
ACM was reinitiated after an exceedance of benzene in MW-2R in December 2012, and was
submitted to NCDENR in May 2013. Approval of the ACM was granted in a letter from NCDENR
dated June 27, 2013. A Corrective Action Plan (CAP) for monitored natural attenuation (MNA) plus
phytoremediation was submitted to NCDENR on May 23, 2014, and was approved by NCDENR on
June 18, 2014.
1.2 Site Geology
The Butner Landfill lies within the Piedmont physiographic province. The topography of the area
consists of rolling hills that support farmland and forest. The majority of the landfill area is underlain
by Carolina Slate Belt felsic volcanic rocks, which have been metamorphosed into greenish grey
foliated tuffs. The southeastern portion of the site is underlain by Triassic Sanford Formation
(conglomerate, sandstone, and mudstone), which unconformably overlies the Carolina Slate Belt
felsic volcanic rocks. There is no exposure of the Sanford Formation at the site; however, float
material consisting of grey, coarse -grained sandstone with quartz pebbles was observed. Diabase
dikes have also been observed in the vicinity of the site. Geologic descriptions were taken from GAI
Consultants' Groundwater and Surface Water Monitoring System report (GAI, 1994).
1.3 Regulatory Status
Groundwater and surface water monitoring at the Butner Landfill is completed in accordance with
NCSWMR §.1634-.1637. The site is currently in Assessment Monitoring and a Corrective Action
Monitoring Program. Groundwater samples are collected semiannually and analyzed in accordance
with the approved Corrective Action Plan. Surface water samples are collected and sampled for
Appendix I of 40 CFR Part 258, from here on known as North Carolina (NC) Appendix I list of
constituents during each sampling event.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
1

2.0 FACILITY MONITORING PROGRAM
2.1 Groundwater Monitoring Program
Seven active groundwater monitoring wells comprise the monitoring network at the Butner Landfill:
MW-1R (facility background well), MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1(which was
installed as part of a Nature and Extent Study on November 14, 2007). The following table
summarizes the monitoring network and required analytical parameters. A summary of well
construction details is provided in Appendix A.
Groundwater Monitoring Network
Total
Lithology
1st SA
2nd SA
Monitoring
Date
Classification
Monitoring
Depth
of
Event
Event
Well
Installed
Program
(ft)
Screened
Analyses
Analyses
Interval
App. I +
MW-1R
4/21/94
Background
Assessment/
45.1
Saprolite
App. I*,
Det. plus
CAMP
MNA
1,4-
Dioxane
App. I +
Compliance/
Assessment/
App. 11,
Det. plus
MW-2R
4/12/94
Performance
CAMP
19.0
Saprolite
MNA
1,4-
Dioxane,
MNA
App. I +
Compliance/
Assessment/
App. 11,
Det. plus
MW-3R
4/14/94
Performance
CAMP
37.2
Bedrock
MNA
1,4-
Dioxane,
MNA
App. I
MW-4
4/18/94
Compliance
Detection
31.5
Bedrock
App. I
plus 1,4-
Dioxane
App. I
MW-5
4/18/94
Compliance
Detection
23.4
Saprolite
App. I
plus 1,4-
Dioxane
Saprolite/
App. I
MW-6
4/19/94
Compliance
Detection
31.7
Bedrock
App. I
plus 1,4-
Dioxane
NES-1
11/14/07
Nature &
Sentinel
33.0
Saprolite/
COCs,
COCs
Extent
Bedrock
MNA*
Notes:
Ft = Feet
Amp. I = NCSWMR Appendix I list of constituents plus 1,4-Dioxane.
App.11= NCSWMR Appendix II list of constituents plus 1,4-Dioxane.
App. I + Det. = App. I list plus detected App. II constituents.
COCs = Constituents of Concern.
MNA = Monitored Natural Attenuation parameters.
CAMP = Corrective Action Monitoring Plan.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
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Current Appendix II detected constituents: Tin.
Current COC: Benzene.
MNA Field Parameters: Temperature, pH, specific conductance, oxidation reduction
potential, turbidity, dissolved oxygen, and ferrous iron. Dissolved carbon dioxide will be
tested during both events every third year (next in 2019).
MNA Laboratory Parameters: Dissolved methane, alkalinity, sulfate, nitrate, chloride,
biological oxygen demand (BOD), chemical oxygen demand (COD), and total organic carbon
(TOC). Dissolved hydrogen, volatile fatty acids, sulfide, ethane and ethene are analyzed
during both events every third year (next in 2022).
*Note: MNA parameters are only required annually for MW-1R & NES-1.
2.2 Surface Water Monitoring Program
Two surface water samples have been collected semiannually since September 1994, at the Butner
Landfill. The surface water sample points SW-1 and SW-2 are located respectively upstream and
downstream of the facility, along an unnamed tributary of Picture Creek. The surface water samples
are analyzed for the NC Appendix I list of constituents plus 1,4-Dioxane during both semiannual
events.
3.0 February 2019 SEMIANNUAL SAMPLING EVENT
3.1 Field Work
On February 4, 2019, LaBella Associates PC (LaBella) personnel visited the Butner Landfill to purge
and sample monitoring wells MW-1R, MW-2R, MW-3R, MW-4, MW-5, MW-6, and NES-1. All
monitoring wells were purged and sampled using new, disposable bailers or a submersible pump.
An electronic water level meter was used to take the depth to water to 0.01 foot. Calculated
groundwater elevations can be found in Table 1. Measurements of temperature, pH, turbidity,
dissolved oxygen, oxidation reduction potential (ORP), and conductivity were recorded in a field log.
Ferrous Iron was also measured for monitoring wells MW-2R and MW-3R for this sampling event and
recorded in the field log. Prior to sampling, laboratory -supplied containers were prepared with the
following information:
• Monitoring well number (completed by laboratory/field personnel),
• Date and time of sample collection (completed by laboratory/field personnel),
• Initials of sampling personnel (completed by laboratory/field personnel),
• Project name and number (completed by the laboratory/field personnel),
• Chemical preservative (completed by the laboratory/field personnel); and
• Requested chemical analysis (completed by the laboratory/field personnel).
Groundwater samples from each monitoring well were collected directly from the bailers or tubing
into the provided laboratory containers, within 24 hours of the final purge volume. Immediately after
collection, the samples were placed in a laboratory provided cooler and preserved on ice. Field Logs
are provided in Appendix B and field parameters are summarized in Table 2.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
3

Surface water points SW-1 and SW-2 were also sampled during the February 4, 2019, event. Field
Logs are included in Appendix B and field parameters are summarized in Table 2.
3.2 Laboratory Analyses and Quality Control
Pace Analytical Services, Inc. of Huntersville, North Carolina, analyzed the February 2019,
groundwater and surface water samples under chain -of -custody control. The groundwater samples
from monitoring wells MW-1R, MW-2R, and MW-3R were analyzed for the Appendix 11 of 4CFR part
258 from here on known as NC Appendix II list of constituents, plus 1,4-Dioxane. Groundwater
samples from monitoring wells MW-1R, MW-2R, MW-3R, and NES-1 were analyzed for MNA
parameters. Additionally, groundwater from monitoring well NES-1 was analyzed for benzene as a
constituent of concern. The groundwater samples from monitoring wells MW-4, MW-5, and MW-6
were analyzed for the NC Appendix I list of constituents plus 1,4-Dioxane.
The surface water samples from SW-1 and SW-2 were analyzed for NC Appendix I constituents plus
1,4- Dioxane. According to the Laboratory Sample Conditions and Verification reports, the samples
were received by the laboratory on February 5, 2019 in good condition, properly preserved, at proper
temperatures, and within analysis hold times.
In addition to samples collected for compliance monitoring at the Butner Landfill, LaBella personnel
collected a Field Blank for the February 2019 Semiannual Sampling Event as part of the Quality
Control/Quality Assurance program. The Field Blank was analyzed for the NC Appendix II
constituents plus 1,4-Dioxane. Also, a Trip Blank that was prepared by the laboratory accompanied
the volatile sampling containers to and from the laboratory. The Trip Blank was analyzed for the NC
Appendix II volatile organic compounds plus 1,4-dioxane. The complete laboratory analytical reports
are included in Appendix C.
Upon receipt of the laboratory data package, LaBella personnel reviewed the following data for:
• General typographical errors;
• Correct analyses performed and within method specified hold times;
• Biased data results based on Matrix Spike, Matrix Spike Duplicate, and Laboratory Control
Samples;
• Blank qualified data (B-flags);
• Detections above Groundwater Protection Standards (GPS) as defined in NCSWMR §
.1634(g), which are generally either the NC21- Groundwater Standards or the NCDEQ Solid
Waste Section (SWS) Groundwater Water Protection Standards (GWPS);
• Detections above NC Surface Water Standards established in 15A NCAC 2B (NC2B); and
• Detections that are above historical levels.
The complete laboratory analytical reports and the chains of custody from the February 2019
Semiannual Sampling Event are included in Appendix C. The historical groundwater elevation data
are presented in Appendix D. Respectively, historical analytical results for groundwater and surface
water are presented in Appendices E and F.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
4

4.0 ANALYTICAL RESULTS AND STATISTICAL ANALYSES
4.1 Analytical Results for Groundwater and Comparisons to Standards
4.1.1 Inorganic Analyses
The following inorganic constituents were detected at quantified concentrations above the method
detection limit (MDL) or practical quantitation limit (PQL) in one or more wells during the February
2019, Semiannual Sampling Event: arsenic, barium, cobalt, copper, iron, manganese, nickel,
vanadium, tin, and zinc. Table 3 summarizes all of the detections from the February 2019
Semiannual Sampling Event.
Cobalt was detected in exceedance of the GWPS in MW-2R and MW-5. Vanadium was detected in
exceedance of the GWPS in MW-4. The result for cobalt in MW-5 is consistent with historical data.
Iron was detected in exceedance of the NC2L in MW-2R. Manganese was detected in exceedance of
the NC2L in MW-1R, MW-2R, and MW-3R. Exceedances of groundwater standards from the February
2019 Semiannual Sampling Event are summarized in Table 4.
No other inorganic constituents were detected above their NC2L/GWPS during the February 2019
Semiannual Sampling Event. The laboratory analytical reports and the chains of custody are
included in Appendix C. Complete historical analytical results for inorganic constituents are included
in Appendix E.
4.1.2 Organic Analyses
Benzene, chlorobenzene, chloroethane, endosulfane I, naphthalene, and 1,4-dioxane were detected
in one or more monitoring wells at quantified concentrations above the MRL or PQL. Benzene and
1,4-dioxane were detected above their respective NC2L standards. Table 3 summarizes all of the
quantified detections from the February 2019 Semiannual Sampling Event. These results are
consistent with historical data as shown in Appendix E.
1,4-dioxane was detected in exceedance of the NC2L standard in MW, 2R, MW-3R, and MW-4.
Benzene was detected above the NC2L Standard in MW-2R. The benzene in MW-2R is consistent
with historical data and has been addressed in the ACM, approved in June 2013, and the CAP,
approved in June 2014. Exceedances of groundwater standards from the February 2019
Semiannual Sampling Event are summarized in Table 4.
No other organic constituents were detected above their GPS during the February 2019 Semiannual
Sampling Event. The laboratory analytical reports and the chains of custody are included in
Appendix C. Historical analytical results for organic constituents are presented in Appendix E.
4.2 Statistical Analyses
4.2.1 Statistical Methods
Monitoring well MW-1R is designated as the up -gradient background well for the facility. Data from
MW-1R between September 1994 and February 2019 have been used to determine interwell
statistical background concentrations for constituents detected at the facility.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
5

The background data was evaluated using the Shapiro-Francia Test of Normality, Parametric
Prediction Limits, Parametric Tolerance Intervals, Aitchison's Adjustment, Non -Parametric Prediction
Limits, and Poisson Prediction Limits, as appropriate. Background data, tests for normality, outliers,
Aitchison's adjustment, tolerance interval, or prediction limits are used, as appropriate based on the
background data. The statistical test by which downgradient data are compared to facility
background data is based upon the nature of the data and the number of data values that are less
than the laboratory limit of detection. All statistical tests are evaluated at the 0.05 level of
significance, 95% confidence level, and are conducted as one -tailed tests. The data set was
evaluated to determine the appropriate procedure for calculation of the background value for each
parameter.
4.2.2 Results of Statistical Analyses
The background data for cobalt was first evaluated for normality using the original data with no
transformation. The analysis indicated that the data distribution was not normal. Therefore, the
data was transformed logarithmically to test normality. The data analysis indicated that the
background data has a non -normal distribution. Accordingly, the background concentration for the
background well was calculated using a non -parametric approach. The Non -Parametric Tolerance
Level analysis indicated that the maximum background concentration of cobalt is 130 µg/L. The
statistical analysis sheets are included as Appendix F.
Cobalt in MW-5 was the only inorganic constituents detected in exceedance of the GPS during the
February 2019 sampling event at concentration of 24 µg/L. Comparing the Cobalt concentration in
monitoring well MW-5 to the background level, it was determine that the cobalt concentration in
monitoring well MW-5 is below the background level.
4.3 Analytical Results for Surface Water and Comparisons to Standards
Surface water points SW-1 and SW-2 were sampled during the February 2019 Semiannual Sampling
Event. No Appendix I organic or inorganic constituents were detected above the MRL or PQL during
the February 2019 Semiannual Sampling Event. Historical surface water data are presented in
Appendix G.
5.0 HYDROGEOLOGICAL CONDITIONS
Groundwater in the saprolite feeds the fractures in the bedrock and discharges into creeks northeast
of the landfill. Groundwater flow direction at deeper levels within the fractured bedrock is controlled
by fracture orientation.
Depth to groundwater was measured in the compliance monitoring wells at the site prior to purging.
The groundwater elevations were calculated relative to the surveyed measuring point (top of casing)
for each monitoring well. A groundwater surface contour map, developed with static water level data
obtained on February 4, 2019, is presented as Drawing 1. The static water elevations depict
groundwater flow to the southeast. The historical groundwater elevations are summarized in
Table 1.
Horizontal groundwater gradients along a representative flow path was estimated from the February
2019 groundwater contours shown on Drawing 1 and are summarized in Table 5. The average
horizontal hydraulic gradient across the site was approximately 0.0510.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
6

Linear groundwater flow velocities were computed using the modified Darcy equation:
Where:
V = K►/ne
V = average linear velocity (feet/year),
K = hydraulic conductivity (feet/day),
i = horizontal hydraulic gradient, and
ne = effective porosity.
The average of hydraulic conductivities (K = 2.18x10-05 cm/sec = 6.18x10-02 feet/day) from single
well aquifer test commonly known as slug -tests conducted in 1994 (GAI, 1994) was used in these
calculations. The average effective porosity (ne = 18%) based on 90% of reported total porosity for
soils (GAI, 1994), and ne = 10% for fractured bedrock were also used. Although the regolith and
bedrock are hydraulically connected, the effective porosity generally decreases with depth into the
underlying fractured bedrock. Groundwater flow direction beneath the landfill is predominantly to
the south and southeast. The calculated flow velocity was 6.40 ft/yr.
Because of our conservative estimate of effective porosity, actual groundwater velocities may be
significantly less than the calculated values. Also, the modified Darcy equation makes the
simplifying assumptions of a homogeneous and isotropic aquifer, which may not be accurate for this
site.
6.0 CORRECTIVE ACTION EVALUATION
6.1 Monitored Natural Attenuation Parameters
Monitoring wells MW-1R, MW-2R, MW-3R and NES-1 were analyzed for the following MNA
parameters during the February 2019 sampling event:
MNA Field Parameters: Temperature, pH, conductivity, oxidation reduction potential,
turbidity, dissolved oxygen, dissolved carbon dioxide and ferrous iron.
MNA Laboratory Parameters: Alkalinity, sulfide, sulfate, nitrate, chloride, biological oxygen
demand (BOD), chemical oxygen demand (COD), and total organic carbon (TOC), Volatile
Fatty Acids, methane, ethane, ethane, and dissolved hydrogen.
The current and historical MNA parameter data are presented in Table 6, and the laboratory
analytical report for MNA parameters for the February 2019 Semiannual Sampling Event is included
in Appendix C. Based on response from NCSWMR to the first Corrective Action Evaluation Report
(CAER) submitted in December 2016, changes to the CAP were implemented starting with the
February 2017 event and the following parameters are now monitored during both sampling events
every third year: Dissolved carbon dioxide, dissolved hydrogen, sulfide, volatile fatty acids, dissolved
methane, ethene, and ethane. The next time these parameters will be monitored will be in
February 2022.
6.2 Phytoremediation
The sixth phytoremediation tree survey for the Butner Landfill was conducted on July 26, 2018 and
the results are presented in the August 2018 Semiannual Water Quality Monitoring Report dated
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
7

December 2018. The CAP requires annual tree surveys and the next survey is scheduled for
summer 2019.
6.3 Evaluation of Plume Stability and Trends
Chart 1 presents a plot of the benzene concentrations versus time in all monitoring wells where it
has been detected (MW-2R, MW-3R, and MW-4). There were no benzene detections prior to
December 2006; however, from December 2006 to present, benzene in MW-2R has fluctuated
between 1pg/1 and 2 pg/l and shows a slight downward trend and a possible seasonal fluctuation.
From December 2007 to present, benzene in MW-3R has fluctuated between 0.3 pg/1 and 0.7 pg/l.
Benzene in MW-4 has fluctuated between non -detect and 0.4 pg/1.
The benzene concentrations from the February 2019 Semiannual Sampling Event are within the
range of historical fluctuations. Since there have been no detections of benzene in either the
surface water or sentinel well NES-1, there is no indication that the plume in migrating toward the
property boundary. The plume appears to be stable or decreasing.
Chart 2 presents a plot of the cobalt concentrations versus time in the monitoring wells where it has
been detected in exceedance of the GPS (MW-2R and MW-5). Cobalt in MW-2R has ranged between
non -detection and 38.0 pg/l, but has been consistently between 8.3 and 10.7 pg/l since August
2014. Cobalt in MW-5 has fluctuated between non -detection and 251 pg/l, with large fluctuations
that appear to have a seasonal component (lower in winter and higher in summer); however, there
are inconsistencies (the highest historical concentration was in June 2002). There is no apparent
increasing or decreasing trend for cobalt in either well.
7.0 CONCLUSIONS
The groundwater flow regime is consistent with previous events and the groundwater monitoring
network remains adequate to monitor the site.
Cobalt was detected in MW-2R and MW-5 above its corresponding GWPS. This exceedance is
consistent with historical detections. We recommend that cobalt be added to the constituents of
concern for this facility, and that we begin to sample the sentinel well, NES-1, for cobalt with the next
semiannual event.
Benzene was detected above the NC2L in MW-2R during the February 2019 Semiannual Sampling
Event. Review of MNA parameter data, plume stability, and benzene trends indicate that the
selected remedies of natural attenuation and phytoremediation are adequately controlling the
plume.
1,4-dioxane was detected above the NC2L standard in MW-2R, MW-3R, and MW-4. 1,4-dioxane is
not a constituent required by the NCSWMR, so it is unclear what the appropriate regulatory response
to these detections should be. We recommend continuing to monitor 1,4-dioxane in the
groundwater and surface water semiannually as well as a constituents of concern for NES-1.
The next semiannual sampling event is tentatively scheduled for August 2019.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
8

8.0 ACRONYMS
ACM Assessment of Corrective Measures (Report)
AOC Area of Concern
C&D Construction and Demolition Waste
CAP Corrective Action Plan (Report)
CAER Corrective Action Evaluation Report (Report)
COC Constituent of Concern
DENR See NCDENR
DL Detection Limit (for laboratory data)
DO Dissolved Oxygen
EPA United States Environmental Protection Agency
GPS Site -specific Groundwater Protection Standards per NCSWMR §1634.g-h
GWPS Groundwater Protection Standards (established by DENR-SWS)
JOYCE Joyce Engineering
LFG Landfill Gas
MNA Monitored Natural Attenuation
MSW Municipal Solid Waste
NC2B North Carolina Surface Water Standards found in 15A NCAC 2B
NC21L North Carolina Groundwater Standards found in 15A NCAC 2L
NCAC North Carolina Administrative Code
NCDENR North Carolina Department of Environment and Natural Resources (now NCDEQ)
NCDEQ North Carolina Department of Environmental Quality (formerly NCDENR)
NCSWMR North Carolina Solid Waste Management Regulations (15A NCAC 13B.1600)
ND Not Detected (for laboratory data)
NES Nature and Extent Study (Report)
0&M Operations and Maintenance
QL Quantitation Limit (for laboratory data)
QRA Quantitative Risk Assessment (Report)
RL Reporting Limit (for laboratory data)
SWQS Surface Water Quality Standards
SWS Solid Waste Section (of NCDENR/NCDEQ)
VOC Volatile Organic Compound
WQMP Water Quality Monitoring Plan (Report)
WQMR Water Quality Monitoring Report (Report)
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
9

9.0 REFERENCES
GAI Consultants - NC, Inc. (GAI), 1994. Ground and Surface Water Monitoring System, Granville
County, Butner Landfill, NC Permit No. 39-02. June, 1994.
Joyce Engineering (JOYCE), 2013. Assessment of Corrective Action, Butner Landfill, Granville
County, Permit No. 39-02. May 2013.
Joyce Engineering (JOYCE), 2014. Corrective Action Plan, Butner Landfill, Granville County, Permit
No. 39-02. May 2014.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1996. BIOSCREEN Natural
Attenuation Decision Support System User's Manual, Version 1.3. United States
Environmental Protection Agency, Office of Research and Development, Washington DC.
EPA/600/R-96/087. August 1996.
Newell, Charles J., Ph.D., P.E., R. Kevin McLeod, and James R. Gonzales, 1997. BIOSCREEN Natural
Attenuation Decision Support System, Version 1.4 Revisions. United States Environmental
Protection Agency, Office of Research and Development, Washington DC. July 1997.
North Carolina Department of Environment and Natural Resources (NC-DENR), 2011. North
Carolina Solid Waste Management Rules. 15 NCAC 13B. Amended April 2011.
NC-DENR, 2007. North Carolina Solid Waste Section Guidelines for Corrective Action at Solid Waste
Management Facilities. March 2007.
February 2019 Semiannual Water Quality Monitoring Report LaBella Associates
Granville County - Butner Landfill, Permit No. 39-02 April 2019
10

TABLES
Table 1 February 2019 Groundwater Elevations
Table 2 February 2019 Field Parameters
Table 3 Detected Constituents in Groundwater and Surface Water
Table 4 Exceedances of Groundwater Standards
Table 5 Hydraulic Gradients and Groundwater Flow Velocities
Table 6 Monitored Natural Attenuation Parameters

TABLE 1: February 2019 Groundwater Elevations
Location
Date
TOC Elevation
(Ft AMSL)
Depth to
Groundwater
(Ft BTOC)
Lithology
Well Depth
(Ft BTOC)
Groundwater
Elevation
(Ft AMSL)
MW-1R
2/4/2019
460.51
39.65
Bedrock
56
420.86
MW-2R
2/4/2019
331.60
1.93
Alluvial/
18.85
329.67
Residual
MW-31R
2/4/2019
330.96
1.68
Saprolite
35.83
329.28
MW-4
2/4/2019
340.80
5.18
Bedrock
31.43
335.62
MW-5
2/4/2019
343.88
8.46
Saprolite
23.52
335.42
MW-6
2/4/2019
362.53
7.23
Bedrock
32.63
355.3
NES-1
2/4/2019
328.40
12.38
Bedrock
32.8
316.02
Notes:
Butner Landfill, Granville County
Permit # 39-02
TOC = Top of casing
Ft = feet
BTOC = Below TOC AMSL = Above mean sea level
BGS = Below ground surface
LaBella Associates

TABLE 2: February 2019 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
3902-MW1R
pH
6.17
S.U.
2/4/2019
3902-MWlR
Temperature
13.2
°C
2/4/2019
3902-MWlR
Conductivity
107.9
PS/Cm
2/4/2019
3902-MW1R
Turbidity
10.20
NTU
2/4/2019
3902-MWlR
Dissolved Carbon Dioxide
75
mg/I
2/4/2019
3902-MWlR
Dissolved Oxygen
1.26
mg/I
2/4/2019
3902-MWlR
Ferrous Iron
0.0
mg/I
2/4/2019
3902-MWlR
Oxidation Reduction Potential
197.7
my
2/4/2019
3902-MWlR
Static Water Level
39.65
ft
2/4/2019
3902-MWlR
Well Depth
56.00
ft
2/4/2019
3902-MW2R
pH
6.44
S.U.
2/4/2019
3902-MW2R
Temperature
15.5
°C
2/4/2019
3902-MW2R
Conductivity
1,692
PS/Cm
2/4/2019
3902-MW2R
Turbidity
5.99
NTU
2/4/2019
3902-MW2R
Dissolved Carbon Dioxide
nm
mg/I
2/4/2019
3902-MW2R
Dissolved Oxygen
1.82
mg/I
2/4/2019
3902-MW2R
Ferrous Iron
nm
mg/I
2/4/2019
3902-MW2R
Oxidation Reduction Potential
-64.3
my
2/4/2019
3902-MW2R
Static Water Level
1.93
ft
2/4/2019
3902-MW2R
Well Depth
18.85
ft
2/4/2019
3902-MW3R
pH
7.16
S.U.
2/4/2019
3902-MW3R
Temperature
16.5
°C
2/4/2019
3902-MW3R
Conductivity
1,266
PS/Cm
2/4/2019
3902-MW3R
Turbidity
2.82
NTU
2/4/2019
3902-MW3R
Dissolved Carbon Dioxide
130
mg/I
2/4/2019
3902-MW3R
Dissolved Oxygen
4.17
mg/I
2/4/2019
3902-MW3R
Ferrous Iron
0.0
mg/I
2/4/2019
3902-MW3R
Oxidation Reduction Potential
132.2
my
2/4/2019
3902-MW3R
Static Water Level
1.68
ft
2/4/2019
3902-MW3R
Well Depth
35.83
ft
2/4/2019
3902-MW4
pH
6.87
S.U.
2/4/2019
3902-MW4
Temperature
14.9
°C
2/4/2019
3902-MW4
Conductivity
1,364
PS/Cm
2/4/2019
3902-MW4
Turbidity
4.42
NTU
2/4/2019
3902-MW4
Static Water Level
5.18
ft
2/4/2019
3902-MW4
Well Depth
31.43
ft
2/4/2019
Butner Landfill, Granville Co.
Permit No. 39-02
1of2
LaBella Associates

TABLE 2: February 2019 Field Parameters
WELL ID
PARAMETER
RESULT
UNITS
SAMPLE DATE
3902-MW5
pH
6.07
S.U.
2/4/2019
3902-MW5
Temperature
14.5
°C
2/4/2019
3902-MW5
Conductivity
276.1
PS/Cm
2/4/2019
3902-MW5
Turbidity
25.7
NTU
2/4/2019
3902-MW5
Dissolved Oxygen
4.17
mg/1
2/4/2019
3902-MW5
Oxidation Reduction Potential
9.6
my
2/4/2019
3902-MW5
Static Water Level
8.46
ft
2/4/2019
3902-MW5
Well Depth
23.52
ft
2/4/2019
3902-MW6
pH
7.02
S.U.
2/4/2019
3902-MW6
Temperature
15.4
°C
2/4/2019
3902-MW6
Conductivity
546
PS/Cm
2/4/2019
3902-MW6
Turbidity
4.72
NTU
2/4/2019
3902-MW6
Static Water Level
7.23
ft
2/4/2019
3902-MW6
Well Depth
32.63
ft
2/4/2019
3902-NES1
pH
5.13
S.U.
2/4/2019
3902-NES1
Temperature
13.7
°C
2/4/2019
3902-NES1
Conductivity
91.6
PS/Cm
2/4/2019
3902-NES1
Turbidity
24.50
NTU
2/4/2019
3902-NES1
Dissolved Carbon Dioxide
nm
mg/l
2/4/2019
3902-NES1
Dissolved Oxygen
1.63
mg/l
2/4/2019
3902-NES1
Ferrous Iron
nm
mg/l
2/4/2019
3902-NES1
Oxidation Reduction Potential
281.2
my
2/4/2019
3902-NES1
Static Water Level
12.38
ft
2/4/2019
3902-NES1
Well Depth
36.10
ft
2/4/2019
3902-SW1
pH
7.01
S.U.
2/4/2019
3902-SW1
Temperature
9.1
°C
2/4/2019
3902-SW1
Conductivity
107.4
PS/Cm
2/4/2019
3902-SW1
Turbidity
13.2
NTU
2/4/2019
3902-SW2
pH
6.61
S.U.
2/4/2019
3902-SW2
Temperature
9.3
°C
2/4/2019
3902-SW2
Conductivity
144
PS/Cm
2/4/2019
3902-SW2
Turbidity
11.1
NTU
2/4/2019
Units: °C = degrees Centigrade
S.U. = Standard Units
pS/cm = micro-Seimens per centimeter
NTU = Nephelometric Turbidity Units
my = milivolts
mg/l = miligrams per liter
Butner Landfill, Granville Co.
Permit No. 39-02
2of2
LaBella Associates

TABLE 3: Detected Constituents in Groundwater and Surface Water
SAMPLE
NC2L/*GWPS/
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
NC2B
DATE
3902-MWlR
Iron
230
ug/L
25
50
300
2/4/2019
3902-MWlR
Manganese
121
ug/L
2.50
5.0
50
2/4/2019
3902-MWlR
Zinc
6.8 J
ug/L
5
10.0
1000
2/4/2019
3902-MW2R
1,2-Dichlorobenzene
0.95 J
ug/L
0.29
1.0
20
2/4/2019
3902-MW2R
1,4-Dioxane (p-Dioxane)
132
ug/L
4.8
5.0
3
2/4/2019
3902-MW2R
Arsenic
5.7 J
ug/L
5
10
10
2/4/2019
3902-MW2R
Barium
104
ug/L
2.5
5.0
700
2/4/2019
3902-MW2R
Benzene
1.6
ug/L
0.15
1.0
1
2/4/2019
3902-MW2R
Chlorobenzene
13.6
ug/L
0.23
1.0
50
2/4/2019
3902-MW2R
Chloroethane
1.3
ug/L
0.49
1.0
3000
2/4/2019
3902-MW2R
Cobalt
9.9
ug/L
2.5
5.0
1*
2/4/2019
3902-MW2R
Copper
3.0 J
ug/L
2.5
5.0
1000
2/4/2019
3902-MW2R
Diethyl phthalate
7.1 J
ug/L
2
10.0
6000
2/4/2019
3902-MW2R
Endosulfan 1
0.078
ug/L
0.05
0
40
2/4/2019
3902-MW2R
Iron
9420
ug/L
25
50.0
300
2/4/2019
3902-MW2R
Manganese
7640
ug/L
2.50
5.0
50
2/4/2019
3902-MW2R
Naphthalene
4.2
ug/L
0.35
1.0
6
2/4/2019
3902-MW2R
Nickel
85.7
ug/L
2.5
5.0
100
2/4/2019
3902-MW2R
Tin
24.8
ug/L
2.5
5
2000*
2/4/2019
3902-MW2R
Vanadium
3.5 J
ug/L
2.5
5.0
0.3*
2/4/2019
3902-MW3R
1,4-Dioxane (p-Dioxane)
49.6
ug/L
1.9
2.0
3
2/4/2019
3902-MW3R
Barium
44.3
ug/L
2.5
5.0
700
2/4/2019
3902-MW3R
Chlorobenzene
0.35 J
ug/L
0.23
1.00
50
2/4/2019
3902-MW3R
Copper
5.4
ug/L
2.5
5.00
1000
2/4/2019
3902-MW3R
Endosulfan 1
0.19
ug/L
0.05
0.05
6000
2/4/2019
3902-MW3R
Iron
184
ug/L
25
50.0
300
2/4/2019
3902-MW3R
Manganese
51.8
ug/L
2.5
5.0
50
2/4/2019
3902-MW3R
Nickel
17.4
ug/L
2.5
5.0
100
2/4/2019
3902-MW3R
Tin
5.5
ug/L
2.5
5.0
2000*
2/4/2019
3902-MW3R
Zinc
5.0 J
ug/L
5
10.0
1000
2/4/2019
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 1 of 2

TABLE 3: Detected Constituents in Groundwater and Surface Water
SAMPLE
NC2L/*GWPS/
SAMPLE
PARAMETER
RESULT
UNITS
MDL
MRL
ID
NC2B
DATE
3902-MW4
1,1-Dichloroethane
0.36 J
ug/L
0.27
1.0
6
2/4/2019
3902-MW4
1,4-Dioxane (p-Dioxane)
49.8
ug/L
1.9
2.0
3
2/4/2019
3902-MW4
Chlorobenzene
1.3
ug/L
0.23
1.0
50
2/4/2019
3902-MW4
Chloroethane
0.79 J
ug/L
0.49
1.0
3000
2/4/2019
3902-MW4
Copper
8.0
ug/L
2.5
5.0
1000
2/4/2019
3902-MW4
Nickel
10.7
ug/L
2.5
5
100
2/4/2019
3902-MW4
Vanadium
12
ug/L
2.5
5.0
0.3*
2/4/2019
3902-MW5
Barium
110
ug/L
2.5
5.0
700
2/4/2019
3902-MW5
Cobalt
24
ug/L
2.5
5.0
1*
2/4/2019
3902-MW5
Copper
4.3 J
ug/L
2.5
5.0
1000
2/4/2019
3902-MW5
Nickel
5.5
ug/L
2.5
5
100
2/4/2019
3902-SW1
Barium
29.1
ug/L
2.5
5.0
NS
2/4/2019
3902-SW1
Hardness, Total(SM 2340B)
57100
ug/L
662
662.00
NS
2/4/2019
3902-SW1
Vanadium
2.9 J
ug/L
2.5
5.0
NS
2/4/2019
3902-SW2
Barium
33.1
ug/L
2.5
5
NS
2/4/2019
3902-SW2
Hardness, Total(SM 2340B)
85300
ug/L
662
662.0
NS
2/4/2019
3902-SW2
Nickel
2.7 J
ug/L
2.5
5.0
45.46
2/4/2019
3902-SW2
Vanadium
2.7 J
ug/L
2.5
5.0
NS
2/4/2019
NOTES: All Results in micorgrams per liter (pg/1).
NC2L = NC Groundwater Standard from 15A NCAC 2L.0202.
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L)
NC2B = NC Surface Water Standard from 15A NCAC 2B (lowest of the Aquatic Life or Fish Consumption Standards)
For select metals, the NC2B is dependant on hardness.
NS = No standard established.
MDL = Method Detection Level .
MRL = Method Reporting Limit.
NA= Not applicable.
J = Estimated concentration below the MRL.
Bold = GPS Exceedance.
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02 2 of 2

TABLE 4: Exceedances of Groundwater Standards
W L
SAMPL
D
PARAMETER
RESULT
UNITS
MDL
MRL
NC2L/*GWPS
DATEE
3902-MWlR
Manganese
121.0
ug/L
2.5
5.0
50
2/4/2019
3902-MW2R
1,4-Dioxane (p-Dioxane)
132.0
ug/L
4.8
5.0
3
2/4/2019
3902-MW2R
Benzene
1.6
ug/L
0.15
1.0
1
2/4/2019
3902-MW2R
Cobalt
9.9
ug/L
2.5
5.0
1*
2/4/2019
3902-MW2R
Iron
9420
ug/L
25
50.0
300
2/4/2019
3902-MW2R
Manganese
7640.0
ug/L
2.5
5.0
50
2/4/2019
3902-MW3R
1,4-Dioxane (p-Dioxane)
49.6
ug/L
1.9
2.0
3
2/4/2019
3902-MW3R
Manganese
51.8
ug/L
2.5
5.0
50
2/4/2019
3902-MW4
1,4-Dioxane (p-Dioxane)
49.8
ug/L
1.9
2.0
3
2/4/2019
3902-MW4
Vanadium
12
ug/L
2.5
5.0
0.3*
2/4/2019
3902-MW5
Cobalt
1 24
ug/L
2.5
5.0
1*
2/4/2019
NOTES: All Results in micorgrams per liter (pg/1).
NC21- = NC Groundwater Standard from 15A NCAC 2L.0202.
*GWPS = NC Solid Waste Section Groundwater Protection Standard (for constituents with no NC2L).
MDL = Method Detection Limit.
MRL = Method Reporting Limit.
Bold = GPS Exceedance.
Butner Landfill, Granville Co. LaBella Associates
Permit No. 39-02

TABLE 5: Hydraulic Gradients and Groundwater Flow Velocities
Based on Water Level Data obtained on: February 4, 2019
GROUND-
HORIZ.
HYDRAULIC
EFFECTIVE
LINEAR
GRADIENT
FLOW LINE
FLOW
WATER
GRADIENT
CONDUCTIVITY
POROSITY
VELOCITY
CALCULATION
LENGTH
DIRECTION
ELEVATION
1
K
n e
V
SEGMENT
(feet)
(feet)
(ft/day)
(ft/year)
420
11
1960
SE
0.0510
6.18E-02
0.18
6.40
20
Notes:
Hydraulic conductivity (K) value is the average of results from slug -tests conducted in 1994 (GAI, 1994).
Effective Porosity (n e ) based on average of 90% of reported Total Porosity (GAI, 1995) for site soils.
Linear flow velocity: V = Kiln e (modified Darcy equation).
See Drawing 1 for Flow Segments.
Granville County, Butner Landfill LaBella Associates
Permit No. 39-02

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-31R MW-4 MW-5 MW-6
NES-1
Temperature
12/30/03
°C
15.4
11.1 11.2 12.5 13.6 14.2
-
(FP)
12/19/07
°C
12.3
12.5 13.1 14.4 14.9 14.4
13.3
05/01/13
°C
15.7
13.7 15.1 14.4 14.2 14.2
12.5
08/14/14
°C
17.8
18.0 19.2 19.4 16.8 17.2
16.0
03/10/15
°C
17.3
16.0 15.9 13.8 13.3 13.7
16.1
08/18/15
°C
16.43
17.78 17.79 17.25 16.47 16.64
16.05
02/16/16
°C
14.6
13.8 14.4 14.0 12.0 13.4
13.1
08/09/16
°C
16.4
17.3 19.4 18.2 17.1 16.8
17.9
02/13/17
°C
14.8
14.4 14.9 15.7 14.1 15.3
15.2
08/22/17
°C
17.4
17.9 17.9 17.5 17.4 16.6
17.8
02/05/18
°C
13.06
11.66 13.05 14.46 13.83 14.53
12.25
08/13/18
°C
17.4
21.1 18.2 19.3 20.6 18.4
16.6
02/04/19
°C
13.2
15.5 16.5 14.9 14.5 15.4
13.7
pH
12/30/03
SU
7.31
6.54 6.81 6.90 7.24 7.29
-
(FP)
12/19/07
SU
6.89
6.90 7.07 6.87 7.39 6.67
7.64
05/01/13
SU
7.32
6.37 6.61 6.42 6.92 7.13
6.10
08/14/14
SU
5.84
6.36 6.96 6.79 7.00 6.48
5.59
03/10/15
SU
6.11
6.37 6.56 6.30 6.25 6.55
5.68
08/18/15
SU
5.12
6.68 6.48 6.76 7.03 6.78
4.94
02/16/16
SU
6.15
6.15 6.61 6.69 7.14 6.10
6.52
08/09/16
SU
4.79
5.05 5.30 5.06 4.41 5.75
6.46
02/13/17
SU
6.10
6.55 6.76 6.78 6.24 7.37
6.23
08/22/17
SU
6.58
6.46 6.45 6.98 7.53 7.16
7.16
02/05/18
SU
7.11
6.80 7.01 7.33 7.22 7.54
5.53
08/13/18
SU
6.30
6.45 6.64 6.38 7.15 7.03
5.54
02/04/19
SU
6.17
6.44 7.16 6.87 6.07 7.02
5.13
Conductivity
12/19/07
pS/cm
96
1,964 1,591 1,245 - -
510
(FP)
05/01/13
pS/cm
111
1,587 1,357 1,150 195 594
69.6
08/14/14
pS/cm
231
1,897 1,534 1,413 522 565
172.6
03/10/15
pS/cm
90
996 1,277 1,186 106 504
114
08/18/15
pS/cm
134
1,630 1,680 1,244 617 534
83
02/16/16
pS/cm
72.4
1,611 1,369 1,234 164 474
78.2
08/09/16
pS/cm
100.7
1,924 1,535 1,475 660 600
95.6
02/13/17
pS/cm
68.0
1,535 1,314 1,155 272 508
89.6
08/22/17
pS/cm
77.1
1,752 1,350 1,446 755 560
175
02/05/18
pS/cm
80.0
1,460 1,247 1,230 676 633
50.0
08/13/18
pS/cm
101.2
2,013 1,608 1,569 870 620
131.2
02/04/19
pS/cm
107.9
1692.0 1266.0 1364.0 276.1 546.0
91.6
Redox Potential
12/30/03
mV
257.2
76.2 207.6 212.7 187.3 123.6
-
ORP
12/19/07
mV
146
45.0 142 134 - -
138
(FP)
05/01/13
mV
111.7
-26.7 55.2 120.5
227.1
08/14/14
mV
115.8
-37.2 86.9 -
-
03/10/15
mV
87.0
0.8 56.3 -
96.7
08/18/15
mV
134.7
-96.3 -68.8 -33.9 -49.9
182.8
02/16/16
mV
111.7
-47.3 16.9 NS NS
173.4
08/09/16
mV
56.0
-43.1 -6.9 NS NS NS
NS
02/13/17
mV
87.4
0.8 -16.5 NS NS NS
NS
08/22/17
mV
102.9
-37.1 87.0 NS NS NS
116.7
02/05/18
mV
57.1
29.5 49.4 NS NS NS
109.2
08/13/18
mV
117.9
-60.5 -49.3 NS NS 64.4
28.4
02/04/19
mV
197.7
-64.3 132.2 NS 9.6 NS
281.2
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 1 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL RL
MW-1R
MW-2R MW-3R MW-4 MW-5 MW-6
NES-1
Dissolved Oxygen
12/30/03
mg/L
9.49
4.84 26.19 24.19 15.31 20.17
-
DO
12/19/07
mg/L
-
1.88 1.44 3.21 - -
0.70
(FP)
05/01/13
mg/L
4.40
1.37 1.79 4.65
2.90
08/14/14
mg/L
4.44
3.26 2.48 -
2.80
03/10/15
mg/L
3.84
1.47 1.80
1.85
08/18/15
mg/L
4.95
5.75 1.30 3.79
1.77
02/16/16
mg/L
4.45
3.66 2.51 -
3.72
08/09/16
mg/L
3.17
2.87 2.29 NS NS NS
NS
02/13/17
mg/L
5.37
3.16 2.14 NS NS NS
NS
08/22/17
mg/L
5.43
2.24 4.02 NS NS NS
5.86
02/05/18
mg/L
8.08
6.61 9.16 NS NS NS
8.36
08/13/18
mg/L
6.31
3.20 2.35 NS NS 4.80
3.91
02/04/19
mg/L
1.26
1.82 4.17 NS 4.17 NS
1.63
Dissolved CO2
12/19/07
mg/L
25
365 175 295 -
60
(FP)
05/01/13
mg/L
30.0
245 125 225
45
08/14/14
mg/L
60.0
390 185 -
75
03/10/15
mg/L
50.0
110 75
50
08/18/15
mg/L
30.0
275 125
60
02/16/16
mg/L
30.0
210 230
20
08/09/16
mg/L
NS
185 210 NS NS NS
NS
02/13/17
mg/L
NS
NS NS NS NS NS
NS
08/22/17
mg/L
NS
NS NS NS NS NS
NS
02/05/18
mg/L
NS
NS NS NS NS NS
NS
08/13/18
mg/L
NS
NS NS NS NS NS
NS
02/04/19
mg/L
75.0
NS 130.0 NS NS NS
NS
Fe, Ferrous (+2)
12/30/03
mg/L
ND
1.5 ND ND 0.22 ND
-
(FP)
12/19/07
mg/L
ND
7.2 ND ND -
0.2
05/01/13
mg/L
0.0
1.0 0.0 0.0
0.0
08/14/14
mg/L
0.0
2.5 0.0 -
0.0
03/10/15
mg/L
0.0
5.3 0.0
0.0
08/18/15
mg/L
0.0
4.5 1.0
0.0
02/16/16
mg/L
0.0
4.0 1.3
0.0
08/09/16
mg/L
NS
3.1 1.0 NS NS NS
NS
02/13/17
mg/L
0.0
3.0 1.5 NS NS NS
NS
08/22/17
mg/L
0.0
3.5 1.5 NS NS NS
0.0
02/05/18
mg/L
0.0
4.0 0.5 NS NS NS
0.0
08/13/18
mg/L
0.0
5.5 0.2 NS NS NS
NS
02/04/19
mg/L
0.0
NS 0.0 NS NS NS
NS
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 2 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-213
MW-3R
MW-4
MW-5
MW-6
NES-1
Alkalinity (as CaCO3)
12/30/03
mg/L
9.00
10.0
37.0
800
690
640
68.0
350
-
12/19/07
mg/L
-
5.00
39.0
763
726
619
-
-
190
05/01/13
mg/L
1.00
5.00
43.4
757
660
645
10.4
08/14/14
mg/L
1.00
5.00
41.1
784
661
-
14.5
03/10/15
mg/L
1.00
5.00
38.0
744
653
8.8
08/18/15
mg/L
1.00
5.00
37.8
772
664
10.3
02/16/16
mg/L
1.00
5.00
41.2
792
741
8.73
08/09/16
mg/L
1.00
5.00
-
783
629
-
02/13/17
mg/L
1.00
5.00
37.9
753
654
NS
NS
NS
8.79
08/22/17
mg/L
1.00
5.00
42.4
766
678
NS
NS
NS
10.20
02/05/18
mg/L
1.00
5.00
44.4
821
752
NS
NS
NS
7.52
08/13/18
mg/L
1.00
5.00
NS
768
722
NS
NS
NS
NS
02/04/19
mg/L
1.00
5.00
62.0
856
638
7.02
Chloride
12/30/03
mg/L
0.200
1.00
3.50
280
170
82.0
13.0
44.0
-
12/19/07
mg/L
-
5.00
ND
13.1
297
89.1
-
-
7.90
INC 2L = 250,000 ug/L
05/01/13
mg/L
0.50
1.00
3.54
258
180
123
2.85
(250 mg/L)
08/14/14
mg/L
0.50
1.00
5.53
264
144
-
5.00
03/10/15
mg/L
0.50
1.00
3.80
266
194
4.09
08/18/15
mg/L
0.50
1.00
4.69
267
178
3.90
02/16/16
mg/L
0.50
1.00
3.92
274
186
3.24
08/09/16
mg/L
0.50
1.00
-
269
191
-
02/13/17
mg/L
0.50
1.00
3.45
309
215
NS
NS
NS
5.09
08/22/17
mg/L
0.50
1.00
3.73
318
214
NS
NS
NS
5.86
02/05/18
mg/L
0.50
1.00
3.92
280
205
NS
NS
NS
2.52
08/13/18
mg/L
0.50
1.00
NS
221
165
NS
NS
NS
NS
02/04/19
mg/L
0.50
1.00
3.42
221
147
NS
NS
NS
4.52
Dissolved Hydrogen
05/01/13
nM
0.074
0.60
0.400
0.630
0.610
0.500
0.470
08/14/14
nM
0.13
0.60
1.4
1.6
5.4
-
1.4
03/10/15
nM
0.13
0.60
1.2
1.4
1.4
1.0
1.4
08/18/15
nM
0.13
0.60
1.7
2.2
1.7
-
1.5
02/16/16
nM
0.13
0.60
2.0
1.7
1.9
1.5
08/09/16
nM
0.13
0.60
-
1.5
1.6
-
02/13/17
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
nM
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
nM
0.65
1
6.7
7.6
7.4
NS
NS
NS
6.8
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 3 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Nitrate-N
12/30/03
mg/L
0.020
0.050
0.120
ND
ND
ND
ND
0.13
-
12/19/07
mg/L
-
0.100
ND
ND
ND
ND
-
13.0
05/01/13
mg/L
0.001
10.0
0.163
ND
ND
ND
3.58
08/14/14
mg/L
0.001
10.0
0.115 J
ND
ND
2.02 J
03/10/15
mg/L
0.001
10.0
0.252 J
ND
ND
2.56 J
08/18/15
mg/L
0.001
10.0
0.124 J
ND
ND
3.27 J
02/16/16
mg/L
0.001
10.0
0.36 J
ND
ND
2.54 J
08/09/16
mg/L
0.001
10.0
-
ND
ND
-
02/13/17
mg/L
0.001
10.0
0.248 J
0.189 J
ND
NS
NS
NS
2.63 J
08/22/17
mg/L
0.001
10.0
0.118 J
0.0186 J
0.0451 J
NS
NS
NS
4.06 J
02/05/18
mg/L
0.010
10.0
0.310 J
ND
0.0120 J
NS
NS
NS
1.15 J
08/13/18
mg/L
0.050
0.1
NS
ND
ND
NS
NS
NS
NS
02/04/19
mg/L
0.050
0.1
0.196
ND
0.113
NS
NS
NS
6.5
Sulfate
12/30/03
mg/L
0.0600
2.00
ND
ND
ND
2.60
9.60
9.00
-
12/19/07
mg/L
-
5.00
ND
ND
ND
ND
-
-
36.8
INC 2L = 250,000 ug/L
05/01/13
mg/L
1.00
250
ND
ND
ND
4.69
10.7
(250 mg/L)
08/14/14
mg/L
1.00
250
1.08 J
1.2 J
ND
-
5.84 J
03/10/15
mg/L
1.00
250
1.52 J
1.13 J
1.52 J
7.04 J
08/18/15
mg/L
1.00
250
1.56 J
1.31 J
2.49 J
524 J
02/16/16
mg/L
1.0
250
1.5 J
1.7 J
1.8 J
10.0 J
08/09/16
mg/L
1.00
250
-
1.22 J
1.75 J
-
02/13/17
mg/L
1.00
250
1.53 J
1.59 J
1.78 J
NS
NS
NS
11.9 J
08/22/17
mg/L
1.00
250
ND
ND
0.626 J
NS
NS
NS
11.2 J
02/05/18
mg/L
0.500
250
ND
ND
0.627 J
NS
NS
NS
7.48 J
08/13/18
mg/L
0.500
250
ND
ND
0.630J
NS
NS
NS
NS
02/04/19
mg/L
0.500
250
1.15
ND
1.10
NS
NS
NS
6.75
Sulfide
08/14/14
mg/L
0.05
1.00
ND
ND
ND
ND
03/10/15
mg/L
0.05
1.00
ND
ND
ND
ND
08/18/15
mg/L
0.05
1.00
ND
ND
ND
1.0
02/16/16
mg/L
0.05
1.00
ND
ND
ND
ND
08/09/16
mg/L
0.05
1.00
-
ND
ND
02/13/17
mg/L
0.05
1.00
ND
ND
ND
NS
NS
NS
NS
08/22/17
mg/L
0.05
1.00
ND
ND
ND
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
0.05
1
ND
ND
ND
NS
NS
NS
ND
Total Organic Carbon
12/19/07
mg/L
-
1.0 *
2.9
54.3
23.2
17.2
7.20
05/01/13
mg/L
0.50
1.00
2.24
29.5
30.0
19.4
5.74
08/14/14
mg/L
0.50
1.00
ND
229.00
25.5
-
8.39
03/10/15
mg/L
0.50
1.00
0.781J
34.8
9.5
1.88
08/18/15
mg/L
0.50
1.00
0.917J
32.9
9.86
27.80
02/16/16
mg/L
0.50
1.00
1.500
27.6
8.46
40.90
08/09/16
mg/L
0.50
1.00
-
29.4
9.53
-
02/13/17
mg/L
0.50
1.00
ND
28.5
9.72
NS
NS
NS
1.36
08/22/17
mg/L
0.50
1.00
ND
29.1
9.92
NS
NS
NS
1.71
02/05/18
mg/L
0.50
1.00
ND
25.9
11.4
NS
NS
NS
4.24
08/13/18
mg/L
0.50
1.00
ND
25.8
10.2
NS
NS
NS
ND
02/04/19
mg/L
0.50
1.00
ND
27.9
8.02
NS
NS
NS
1.6
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 4 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-213
MW-3R
MW-4
MW-5
MW-6
NES-1
Biochemical Oxygen Demand
08/14/14
mg/L
2.00
2.00
ND
83.4
2.49
BOD
03/10/15
mg/L
2.00
2.00
2.55
10.6
ND
ND
08/18/15
mg/L
2.00
2.00
2.22
11.8
2.0
2.00
02/16/16
mg/L
2.00
2.00
ND
60.0
6.6
ND
08/09/16
mg/L
2.00
2.00
-
11.6
ND
02/13/17
mg/L
2.00
2.00
ND
9.50J
ND
NS
NS
NS
ND
08/22/17
mg/L
2.00
2.00
ND
ND
ND
NS
NS
NS
ND
02/05/18
mg/L
2.00
2.00
ND
5.6
ND
NS
NS
NS
ND
08/13/18
mg/L
2.00
2.00
ND
71.8
3.56
NS
NS
NS
ND
02/04/19
mg/L
2.00
2.00
ND
7.5
ND
NS
NS
NS
ND
Chemical Oxygen Demand
08/14/14
mg/L
12.5
25.0
ND
132.0
ND
50.00
COD
03/10/15
mg/L
12.5
25.0
15.01
235.0
96.0
ND
08/18/15
mg/L
12.5
25.0
25.0
110.0
756.0
25.00
02/16/16
mg/L
12.5
25.0
ND
295.0
50.0
ND
08/09/16
mg/L
12.5
25.0
-
131.0
50.0
-
02/13/17
mg/L
12.5
25.0
17.0 J
119.0
43.0
NS
NS
NS
22.0 J
08/22/17
mg/L
12.5
25.0
ND
121.0
74.0
NS
NS
NS
16.0 J
02/05/18
mg/L
12.5
25.0
ND
113.0
51.0
NS
NS
NS
46.0
08/13/18
mg/L
12.5
25.0
ND
112.0
73.9
NS
NS
NS
ND
02/04/19
mg/L
12.5
25.0
ND
101.0
26.5
NS
NS
NS
ND
Dissolved Ethane
12/30/03
mg/L
0.0002
0.0010
ND
ND
ND
ND
ND
ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/13
mg/L
0.0031
0.0062
ND
ND
ND
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
0.0036J
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
-
1.6 J
2.6 J
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND
ND
ND
Dissolved Ethene
12/01/03
mg/L
0.0003
0.0010
ND
ND
ND
ND
ND
ND
12/19/07
mg/L
-
20.0
ND
ND
ND
ND
ND
05/01/1-3
mg/L
0.0031
0.0062
ND
ND
0.0017
ND
ND
08/14/14
mg/L
0.0031
0.0062
ND
ND
ND
ND
03/10/15
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/18/15
mg/L
0.0031
0.0062
0.01
0.01
0.01
0.01
02/16/16
mg/L
0.0031
0.0062
ND
ND
ND
ND
08/09/16
mg/L
0.0031
0.0062
-
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
0.001
0.0010
ND
ND
ND
ND
ND
ND
ND
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 5 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Dissolved Methane
12/30/03
mg/L
0.0002
0.0010
ND
0.660
0.130
0.0099
0.0010
ND
12/19/07
mg/L
-
10.0
ND
0.116
0.186
ND
-
ND
05/01/13
mg/L
0.0033
0.0066
ND
0.0379
0.100
0.0337
ND
08/14/14
mg/L
0.0033
0.0066
ND
1.2900
0.284
-
ND
03/10/15
mg/L
0.0033
0.0066
0.0072
0.9960
0.158
ND
08/18/15
mg/L
0.0033
0.0066
0.0027
2.16
0.316
0.0013
02/16/16
mg/L
0.0033
0.0066
0.007 J
0.87
0.098
0.0016 J
08/09/16
mg/L
0.0033
0.0066
-
1.85
0.206
-
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
0.001
0.0010
ND
27.2
ND
ND
ND
ND
ND
Pyruvic Acid
12/19/07
mg/L
2.50
ND
1.50
2.00
1.20
05/01/13
mg/L
2
10
ND
ND
ND
ND
ND
08/14/14
mg/L
0.77
10
ND
ND
ND
ND
03/10/15
mg/L
0.77
10
0.41J
0.41J
0.41J
0.41J
08/18/15
mg/L
0.77
10
ND
ND
ND
ND
02/16/16
mg/L
0.77
10
ND
ND
ND
ND
08/09/16
mg/L
0.77
10
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Lactic Acid
12/19/07
mg/L
ND
5.40
11.9
3.10
ND
05/01/13
mg/L
2.3
25
ND
ND
ND
ND
ND
08/14/14
mg/L
2.5
25
4.2 J
ND
ND
ND
03/10/15
mg/L
2.5
25
ND
ND
ND
ND
08/18/15
mg/L
2.5
25
ND
ND
ND
ND
02/16/16
mg/L
2.5
25
ND
ND
ND
ND
08/09/16
mg/L
2.5
25
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Acetic Acid
12/19/07
mg/L
ND
ND
ND
ND
ND
05/01/13
mg/L
1.8
5
ND
ND
ND
ND
ND
08/14/14
mg/L
0.81
5.0
ND
ND
ND
ND
03/10/15
mg/L
0.81
5.0
ND
ND
ND
ND
08/18/15
mg/L
0.81
5.0
ND
ND
0.97 J
ND
02/16/16
mg/L
0.81
5.0
ND
ND
ND
ND
08/09/16
mg/L
0.81
5.0
-
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 6 of 7

TABLE 6: Monitored Natural Attenuation Parameters
Parameter
Date
Units
DL
RL
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Propionic Acid
12/19/07
mg/L
ND
63.7
38.3
12.8
ND
05/01/13
mg/L
1
5
ND
ND
ND
ND
ND
08/14/1-4
mg/L
0.66
5.0
ND
ND
ND
ND
03/10/15
mg/L
0.66
5.0
ND
ND
ND
ND
08/18/15
mg/L
0.66
5.0
ND
ND
ND
ND
02/16/16
mg/L
0.66
5.0
ND
ND
ND
ND
08/09/16
mg/L
0.66
5.0
-
ND
ND
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Butyric Acid
12/19/07
mg/L
ND
ND
ND
ND
ND
05/01/13
mg/L
0.87
5
ND
ND
ND
ND
ND
08/14/1-4
mg/L
0.70
5.0
ND
ND
ND
ND
03/10/15
mg/L
0.70
5.0
ND
ND
ND
ND
08/18/15
mg/L
0.70
5.0
ND
ND
ND
ND
02/16/16
mg/L
0.70
5.0
ND
ND
ND
ND
08/09/16
mg/L
0.70
5.0
-
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
Total Volatile Fatty Acids
12/19/07
mg/L
2.50
69.10
51.70
17.90
1.20
(sum of above 5 acids)
05/01/1-3
mg/L
ND
ND
ND
-
ND
08/14/14
mg/L
4.2 J
ND
ND
ND
03/10/1-5
mg/L
ND
ND
ND
ND
08/18/15
mg/L
ND
ND
0.97 J
ND
02/16/16
mg/L
ND
ND
ND
ND
08/09/16
mg/L
ND
ND
02/13/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/22/17
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/05/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
08/13/18
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
02/04/19
mg/L
NS
NS
NS
NS
NS
NS
NS
NS
NS
NOTES:
DL = laboratory detection limit. mg/L = milligrams per liter °C = degress Celcius
RL = laboratory reporting limit. my = millivolt pS/cm = micro-Siemen per centimeter
ND = not detected above detection limit. SU = standard unit ntu = nephelometric turbidity units
J = estimated concentration between the DL and the RL. nM = nano -Molar
- = not analyzed.
DL and RL for Alkalinity for Dec. 03 event was 1 and 2 respectively for wells MW-2R, -3R, and -4 due to different methods used by the labrotory.
* Alkalinity RL for: MW-1R = 1.0, MW-2R = 5.0, MW-3R = 5.0, MW-4 = 2.0, NES-1= 5.0 mg/I.
Methane in December 2007 was out of hold time for MW-2R, MW-3R, MW-4, and NES-1.
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02 Page 7 of 7

CHARTS
Chart 1 Benzene Concentrations vs. Time
Chart 2 Cobalt Concentrations vs. Time

2.0
1.8
1.6
1.4
m 0.8
0.6
0.4
0.2
Chart 1: Benzene Concentration vs. Time in MW-2R, MW-3R, & MWA
fMW-7R
lD r� n r- 00 00 00 0) 0) 0) O O O 1-1 r-1 ri N N N M M M Kt -;t Ln V1 Ln lD lD lD I, n n 00 00 00
O O O O O O O O O O ci c-I IV c-I ri ri ri ri ri r-1 r-1 ri c-I c-I IV c-I ri ri ri ri ri c-I c-I ri ri ri ri
U ao u on U ao U on U on U - w U wU w U a0 U tin U wU L ao U
a Q 7 a 7 a Q 7 a Q 7 av Q 7 a Q 7 a Q Z3 a 7 a Q 7 a Q 7 a Q M a Q 7 a
0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0 Q Q 0
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02

«,I,X.I
250.0
J
200.0
50.0
'e,
Chart 2: Cobalt Concentration vs. Time in MW-213 & MW-5
MW-2R
M W-5
11
Ln r- 00 rn o � N M � Ln ko r" 00 am o �I N m �t Ln (.0 r- 00
rn rn rn rn T o 0 0 0 0 0 0 0 0 0 rV r� rV r� r� rV
v a, a) (U a) a, a, v a, (U (, a) w a) v w v w a) w a, a, v a,
Butner Landfill, Granville Co. La Bella Associates
Permit No. 39-02

FIGURE
Figure 1 Site Location Map

I,\GmdAIe\Ewa\ButneI Site location Mape.dwa

DRAWING
Drawing 1 Groundwater Potentiometric Surface Map

LaBeLLa
Powered by partnership.
\ r / / \ \ \ \ \ \ /
2211 W. MEADOWVIEW ROAD
GREENSBORO, NC 27407
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PHONE: [phone]
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\ \ \ \ \ �// l I \ �� // / APPROXIMATE LIMITS OF WASTE
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GROUNDWATER SURFACE CONTOUR
380 (FEET ABOVE MEAN SEA LEVEL)
GROUNDWATER FLOW DIRECTION WITH
GRADIENT CALCULATION SEGMENT
��
,�\�c�\ �\ EXISTING ROAD
\
CENTERLINE OF STREAM
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BUTNER LANDFILL
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GAS PROBE LOCATION AND
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NO:
DATE:
DESCRIPTION:
Revisions
1,960LF Z�=
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PROJECT NUMBER:
2182022.01
l( \ 1 \ \ \ \
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_
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w \ I 1 \ \ \ \ \ \ I I I I \ \ \ \ \ \
I I I ( ~ 1Y00
DRAWN BY:
RH
REVIEWED BY:
\
GE
ISSUED FOR:
GROUNDWATER REPORT
NOTES
DATE.
05/23/19
1. TOPOGRAPHIC CONTOUR INTERVAL = 2 FEET
/ rl-4 / / / I I I \ \\ \ \ 1 I I \ \ 2. GROUNDWATER SURFACE CONTOUR INTERVAL 10 FEET
DRAWING NAME:
I\ \ \ \ \ \ 3. STATIC WATER LEVELS MEASURED ON 2/4/19.
-
POTENTIOMETRIC
GP-5\
Li(`' �� \ \ \ \ \ \ \ \ \ \\ �\ \ 4. GROUNDWATER CONTOURS BASED ON KNOWN DATA,
�IJ\F\ T \ \ \\ \ \ \ \ \ TOPOGRAPHIC CONTOURS, LINEAR INTERPOLATION AND
EXTRAPOLATION FROM KNOWN FIELD CONDITIONS.
SURFACE MAP
5. ELEVATION RELATIVE TO MEAN SEA LEVEL.
FEBRUARY 4, 2019
6. GROUNDWATER ELEVATION IS BASED ON A WELL SURVEY
PERFORMED IN APRIL 2008
7. TOPOGRAPHIC CONTOURS SHOWN IN THIS MAP ARE BASED ON
DRAWING NUMBER:
\
\ \\ \ \ 2007 DATA OBTAINED FROM NCDOT WEBSITE.
GRAp�I S6A
1 0 20 \ 8. BOUNDARY SURVEY PROVIDED BY BATEMAN CIVIL SURVEY
COMPANY DATED MARCH 15, 2013.

APPENDICES
Appendix A
Monitoring Well Construction Data
Appendix B
Field Data Logs
Appendix C
Laboratory Analytical Reports
Appendix D
Historical Groundwater Elevations
Appendix E
Historical Constituents in Groundwater
Appendix F
Statistical Analysis Calculation Sheets
Appendix G
Historical Constituents in Surface Water

Appendix
Monitoring Well Construction Data

Well Construction Details
WELL ID
5LOCATION
DEPTH in FEET from top of casing
Other Information
Surface
Top of
Top of
Bottom of
Total
WWater
Depth to
2Geologic
3Construction
Driller's
Permit #
Well #
Lat.
Long.
Comments
Elevation
Casing
Screen
Screen
Depth
Level
Bedrock
Unit
Date
Reg. #
Fractured
background well
39-02
MW-1 R
N360 09' 55.49"
W780 45' 37.80"
461.01
0.00
-41.00
-56.00
-56.00
-41.0
-30
4/21/1994
446
Bedrock
replacement
Weathered
compliance well
39-02
MW-2 R
N360 09' 38.57"
W780 45' 34.97"
326.60
+2.34
-3.85
-18.85
-18.85
-2.6
-13
4/12/1994
446
Bedrock
replacement
Fractured
compliance well
39-02
MW-3 R
N360 09' 38.58"
W780 45' 34.85"
328.77
+2.18
-25.83
-35.83
-35.83
-3.0
-13
4/14/1994
446
Bedrock
replacement
Fractured
39-02
MW-4
N360 09' 38.93"
W780 45' 30.15"
338.97
+1.95
-16.43
-31.43
-31.43
-9.8
-13
4/18/1994
446
compliance well
Bedrock
Fractured
39-02
MW-5
N360 09' 39.35"
W780 45' 23.77"
341.88
+2.12
-8.52
-23.52
-23.5
-12.8
-17
446
compliance well
Bedrock4/18/1994
Fractured
39 02
MW-6
N360 09' 47.00"
W780 45' 25.47"
360.80
+2.00
-17.63
-32.63
-32.6
-11.7
-21.2
4/19/1994
446
compliance well
Bedrock
Fractured
nature & extent
39 02
NES-1
N360 09' 35.65"
W780 45' 31.59"
326.22
+2.5
15
30.0
30.0
-22
26
11/14/2007
2675
I
Bedrock
stud well
Notes:
Water Level from TOC, approx. 24 hours after drilling.
Geology where well bore ends, documented as fractured metavolcanic bedrock of Carolina slate belt.
Typical Montoring Well Construction, materials are 2 inch SCH40 PVC casing and screen with 0.010 inch slot, sand pack, bentonite seal, grout pad, & steel outer casing.
Montoring Well Summary data is from well construction records, GAI Consultants June 1994, & Joyce Engineering November 2007 and field observations.
Locations and elevations from March 2013 survey.
Butner Landfill, Granville County LaBella Associates
Permit # 39-02

Appendix B
Field Data Logs

Q
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7
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C

LaBelLa DATE: 2lq 2ot9
GROUND WATER SAMPLING LOG
Project Name: Cicw,v; Ile 6. JWner 1.-f Project No. /Task No.: ZISZOZZ.ol phasc d y
Well ID: Mw- I/ Sampler(s):_!_& S n /s. sleboafln� k
Well Location: 50,Ak OP Ll� ,n5,'
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT)
2 inches
571 S feet
t5)• N3 feet
26, 26- feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 = `7. 2g gallons
For 4" Well: WCT X 0.653 = _ gallons
For THREE Well Volumes: WV X 3 = gallons
Actual Amount Purged/Bailed: gallons
Purged with: CBailer Pump Other:
Sampled with: cjBailer Pump Other:
Depth to Water before Sampling: — feet
Gallons
Time
Temp
(°C)
pH
Cond.
(US/cm)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
0
II SS
13. 5
(o. & 3
1 Z3(,
1.03
63.7
1.76
%H
�.3
1159
)(.2
6,7Z
)3y9
I.S(v
87,0
43
Tit
dr
a+ � (o
a�lons
Date of sample:
Before Sampling
150g
1 �.
�, g7
'/
% 31P 7
r!v. 00
,J
97. z
''
/V
Comments (weather conditions, odor, color, silt, etc.):
we,4 � "s -t-yU' en2
FM
RA
Signature: Date: 2/y/2o 1q
QA/QC Sign Off: `J/_,1Z__Date:5/z
6

LaBelLa - DATE: 9
GROUND WATER SAMPLING LOG
Project Name: 67,-A,1y; lie_ 6. - ZvJnG% LF Project No. /Task No.: 94202z. U) phase Cry
Well ID: / •lW- Jr Sampler(s): 1-8uk-A5on / 5• Qe66-4nt' k
Well Location: � ao% Si& o� 61A 5CA Ofln-A . 61Sin In 44 v,..)C> dS
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
Calculation for One Well Volume (WV):
riches
9. q(0 feet
Z-3. SZ feet
)5- 0(v feet [DTB-DTW]
For 2" Well:
WCT
X
0.163 =
Z, yS gallons
For 4" Well:
WCT
X
0.653 =
gallons
For THREE Well Volumes: WV X 3
Actual Amount Purged/Bailed:
Purged with:
Sampled witl
Depth to Water before Sampling:
_ . Ll gallons
47• 0 gallons
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
O
113(
13.9l
(. 3N
I q Z, 5
1- 33
1q q ►
56o. Z
1" H
Z.5
Ily2
1q,q
I 5q 1
251,q
Z,20
-qi,3
>1000
"11
ca
Date of sample:
Before Sampling
1,5 Z&
)q, j
�, O
27(o.1
y, 1
q•
ZS• -7
TN
Comments (weather conditions, odor, color, silt, etc.):
Signature: IM� A=M_v,0A1.1 Date:
• - e55/

La BelLa DATE: ZO 1 g
up GROUND WATER SAMPLING LOG
Project Name: 6_7re%A�� keP — 9u)-ne— LF Project No. /Task No.: ZI? ZOZZ.0) Qha-
z� 0 q
Well ID: MW —(o
Well Location:
Sampler(s):,A+J-son /S. S1eLn_Jr1,'1e_
Well Diameter:
Initial Depth to Water (DTW):
Depth to Bottom (DTB):
Water Column Thickness (WCT):
U
2 inches
03 feet
3Z. (03 feet
feet [DTB-DTW]
Calculation for One Well Volume (WV):
For 2" Well: WCT X 0.163 gallons
For 4" Well: WCT X 0.653 = gallons
For THREE Well Volumes: WV X 3 = 12 • I'i Z gallons
Actual Amount Purged/Bailed: 70 gallons
Purged with: Pump Other:
Sampled with: ailer Pump Other:
Depth to Water before Sampling:
Gallons
Time
Temp
(°C)
pH
Cond.
(US/CM)
Dis.02
mg/L
ORP
my
Turb.
(ntu)
Initials
C�
11 D 7
M (o
%,qS
qq,l
Z07, Z
1111
IS-3
. I S
sag
D
ZO 7. (o
2l. 7
SS
4� ai
79
1 o ris
Date of sample:
Before Sampling
I5LIp
i S I7,
p Z
sy
2. Q Z
�9. R
7• %Z
r� i
Comments (weather conditions, odor, color, silt, etc.):
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QA/QC Sign Off: Date: Y
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DATE: 2/4/2019
�^ LaBeRa
Povi .reti by p.irtner5hip
SURFACE WATER MONITORING LOG
Project Name: Granville Co. —Butner LF Project/Phase No.: 2182022.01 phase 04
Surface Point ID: 3902-SW-1 Sampler(s): T. Hudson / S. Slebodnik
Location: Near Sed. pond, Basin
Field Parameters:
Time of Sampling: 1801
pH: 7.01
Temperature: 9.10 (° C)
Conductivity: 107.4 (uS/cm)
Turbidity: 13.2 (NTU)
Comments/Sample Description (weather conditions, odor, color, silt, etc.):
The weather was sunny with temperatures in the 40's on 2/4/2019. FB @ 1900.
TB @ 0530.
Sketch of Sample Location (include flow
u
Lwar;PED)
Signature:l i���� •. •
• • Off:

DATE: 2/4/2019
SURFACE WATER MONITORING LOG
Project Name: Granville Co. —Butner LF Project/Phase No.:2182022.01 phase 04
Surface Point ID: 3902-SW-2 Sampler(s):T. Hudson/ S. Slebodnik
Location: Down from MW-2R & MW-3R
Field Parameters:
Time of Sampling:
1747
pH:
6.61
Temperature:
9.30 (° C)
Conductivity:
144.0 (uS/cm)
Turbidity:
11.1 (NTU)
Comments/Sample Description (weather conditions, odor, color, silt, etc.): The
weather was sunny and 40's on 2/4/2019.
Sketch of Sample Location (include flow direction, drainage pathways, etc.):
rI iV
Mw--ZR MW -3K
Signature: Date: 2lzl1 zOl9
QA/QC Sign Off:

Appendix C
Laboratory Analytical Reports

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 15, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Compliance
Pace Project No.: 92416424
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Compliance
Pace Project No.: 92416424
Atlanta Certification IDs
110 Technology Parkway Peachtree Corners, GA 30092
Florida DOH Certification #: E87315
Georgia DW Inorganics Certification #: 812
Georgia DW Microbiology Certification #: 812
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
North Carolina Certification #: 381
South Carolina Certification #: 98011001
Virginia Certification #: 460204
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Compliance
Pace Project No.: 92416424
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92416424001
3902-MW4
Water
02/04/1915:09
02/05/19 10:10
92416424002
3902-MW5
Water
02/04/1915:26
02/05/19 10:10
92416424003
3902-MW6
Water
02/04/1915:46
02/05/19 10:10
92416424004
3902-NES-1
Water
02/04/1917:37
02/05/19 10:10
92416424005
FIELD BLANK
Water
02/04/19 19:00
02/05/19 10:10
92416424006
3902-MW1R
Water
02/04/19 08:34
02/05/19 10:10
92416424007
3902-MW2R
Water
02/04/1914:52
02/05/19 10:10
92416424008
3902-MW3R
Water
02/04/1913:02
02/05/19 10:10
92416424009
TRIP BLANK
Water
02/04/19 15:30
02/05/19 10:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Compliance
92416424
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92416424001
3902-MW4
EPA 6010D
DS
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CL
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92416424002
3902-MW5
EPA 6010D
DS
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CL
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92416424003
3902-MW6
EPA 6010D
DS
14
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CL
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92416424004
3902-NES-1
EPA 8260E
CL
4
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92416424005
FIELD BLANK
EPA 8081B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA8151A
MZP
5
PASI-GA
EPA 6010D
DS
17
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 7470A
RDT
1
PASI-A
EPA 8270D
PKS
112
PASI-C
EPA 8260E
CL
67
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
SM 4500-S2D-2011
GC
1
PASI-A
SM 4500-CN-E-2011
DMN
1
PASI-A
92416424006
3902-MW1 R
EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA8151A
MZP
5
PASI-GA
EPA 6010D
DS
17
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 7470A
RDT
1
PASI-A
EPA 8270D
PKS
112
PASI-C
EPA 8260E
CL
67
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
SM 4500-S2D-2011
GC
1
PASI-A
SM 4500-CN-E-2011
DMN
1
PASI-A
92416424007
3902-MW2R
EPA 8081 B
SEM
21
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project: Butner Compliance
Pace Project No.: 92416424
Lab ID Sample ID Method
Analysts
Analytes
Reported
Laboratory
EPA 8082A
SEM
8
PASI-C
EPA8151A
MZP
5
PASI-GA
EPA 6010D
IDS
17
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 7470A
RDT
1
PASI-A
EPA 8270D
PKS
112
PASI-C
EPA 8260E
CL
67
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
SM 4500-S2D-2011
GC
1
PASI-A
SM 4500-CN-E-2011
DMN
1
PASI-A
92416424008 3902-MW3R EPA 8081 B
SEM
21
PASI-C
EPA 8082A
SEM
8
PASI-C
EPA8151A
MZP
5
PASI-GA
EPA 6010D
IDS
17
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 7470A
RDT
1
PASI-A
EPA 8270D
PKS
112
PASI-C
EPA 8260E
CL
67
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
SM 4500-S2D-2011
GC
1
PASI-A
SM 4500-CN-E-2011
DMN
1
PASI-A
92416424009 TRIP BLANK EPA 8260E
CL
67
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Compliance
92416424
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92416424001
3902-MW4
EPA 6010D
Copper
8.0
ug/L
5.0
02/07/19 18:27
EPA 6010D
Nickel
10.7
ug/L
5.0
02/07/19 18:27
EPA 6010D
Vanadium
12.0
ug/L
5.0
02/07/19 18:27
EPA 8260B
Chlorobenzene
1.3
ug/L
1.0
02/06/19 20:19
EPA 8260B
Chloroethane
0.79J
ug/L
1.0
02/06/19 20:19
EPA 8260B
1,1-Dichloroethane
0.36J
ug/L
1.0
02/06/19 20:19
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
49.8
ug/L
2.0
02/13/19 16:41
92416424002
3902-MW5
EPA 6010D
Barium
110
ug/L
5.0
02/07/19 18:36
EPA 6010D
Cobalt
24.0
ug/L
5.0
02/07/19 18:36
EPA 6010D
Copper
4.3J
ug/L
5.0
02/07/19 18:36
EPA 6010D
Nickel
5.5
ug/L
5.0
02/07/19 18:36
92416424006
3902-MW1 R
EPA 6010D
Iron
230
ug/L
50.0
02/07/19 18:46
EPA 6010D
Manganese
121
ug/L
5.0
02/07/19 18:46
EPA 6010D
Zinc
6.8J
ug/L
10.0
02/07/19 18:46
92416424007
3902-MW2R
EPA 8081 B
Endosulfan 1
0.078
ug/L
0.050
02/07/19 17:18
EPA 6010D
Arsenic
5.7J
ug/L
10.0
02/07/19 18:49
EPA 6010D
Barium
104
ug/L
5.0
02/07/19 18:49
EPA 6010D
Cobalt
9.9
ug/L
5.0
02/07/19 18:49
EPA 6010D
Copper
3.OJ
ug/L
5.0
02/07/19 18:49
EPA 6010D
Iron
9420
ug/L
50.0
02/07/19 18:49
EPA 6010D
Manganese
7640
ug/L
5.0
02/07/19 18:49
EPA 6010D
Nickel
85.7
ug/L
5.0
02/07/19 18:49
EPA 6010D
Tin
24.8
ug/L
5.0
02/07/19 18:49
EPA 6010D
Vanadium
3.5J
ug/L
5.0
02/07/19 18:49
EPA 8270D
Diethylphthalate
7.1 J
ug/L
10.0
02/13/19 12:50
EPA 8260B
Benzene
1.6
ug/L
1.0
02/06/19 22:10
EPA 8260B
Chlorobenzene
13.6
ug/L
1.0
02/06/19 22:10
EPA 8260B
Chloroethane
1.3
ug/L
1.0
02/06/19 22:10
EPA 8260B
1,2-Dichlorobenzene
0.95J
ug/L
1.0
02/06/19 22:10
EPA 8260B
Naphthalene
4.2
ug/L
1.0
02/06/19 22:10
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
132
ug/L
5.0
02/15/19 14:59
92416424008
3902-MW3R
EPA 8081 B
Endosulfan 1
0.19
ug/L
0.050
02/07/19 17:31
EPA 6010D
Barium
44.3
ug/L
5.0
02/07/19 18:52
EPA 6010D
Copper
5.4
ug/L
5.0
02/07/19 18:52
EPA 6010D
Iron
184
ug/L
50.0
02/07/19 18:52
EPA 6010D
Manganese
51.8
ug/L
5.0
02/07/19 18:52
EPA 6010D
Nickel
17.4
ug/L
5.0
02/07/19 18:52
EPA 6010D
Tin
5.5
ug/L
5.0
02/07/19 18:52
EPA 6010D
Zinc
5.OJ
ug/L
10.0
02/07/19 18:52
EPA 8260B
Chlorobenzene
0.35J
ug/L
1.0
02/06/19 22:29
EPA 8260B Mod.
1,4-Dioxane (p-Dioxane)
49.6
ug/L
2.0
02/14/19 17:59
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 6 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW4 Lab ID: 92416424001 Collected: 02/04/19 15:09 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:27
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:27
7440-38-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-39-3
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:27
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:27
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-48-4
8.0
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-50-8
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7439-92-1
10.7
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:27
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-22-4
12.0
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:27
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:27
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:32 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
25.0
6.2
1
02/06/19 20:19
67-64-1
ND
ug/L
10.0
0.90
1
02/06/19 20:19
107-13-1
ND
ug/L
1.0
0.15
1
02/06/19 20:19
71-43-2
ND
ug/L
1.0
0.34
1
02/06/19 20:19
74-97-5
ND
ug/L
1.0
0.26
1
02/06/19 20:19
75-27-4
ND
ug/L
1.0
0.62
1
02/06/19 20:19
75-25-2
ND
ug/L
2.0
0.62
1
02/06/19 20:19
74-83-9
ND
ug/L
5.0
3.3
1
02/06/19 20:19
78-93-3
ND
ug/L
2.0
0.40
1
02/06/19 20:19
75-15-0
ND
ug/L
1.0
0.22
1
02/06/19 20:19
56-23-5
1.3
ug/L
1.0
0.23
1
02/06/19 20:19
108-90-7
0.79J
ug/L
1.0
0.49
1
02/06/19 20:19
75-00-3
ND
ug/L
5.0
2.3
1
02/06/19 20:19
67-66-3
ND
ug/L
1.0
0.39
1
02/06/19 20:19
74-87-3
ND
ug/L
2.0
0.26
1
02/06/19 20:19
96-12-8
ND
ug/L
1.0
0.41
1
02/06/19 20:19
124-48-1
ND
ug/L
1.0
0.26
1
02/06/19 20:19
106-93-4
ND
ug/L
1.0
0.46
1
02/06/19 20:19
74-95-3
ND
ug/L
1.0
0.29
1
02/06/19 20:19
95-50-1
ND
ug/L
1.0
0.26
1
02/06/19 20:19
106-46-7
ND
ug/L
1.0
0.54
1
02/06/19 20:19
110-57-6
0.36J
ug/L
1.0
0.27
1
02/06/19 20:19
75-34-3
ND
ug/L
1.0
0.34
1
02/06/19 20:19
107-06-2
ND
ug/L
1.0
0.24
1
02/06/19 20:19
75-35-4
ND
ug/L
1.0
0.29
1
02/06/19 20:19
156-59-2
ND
ug/L
1.0
0.25
1
02/06/19 20:19
156-60-5
ND
ug/L
1.0
0.19
1
02/06/19 20:19
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 7 of 76

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW4 Lab ID: 92416424001 Collected: 02/04/19 15:09 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
0.30
1
02/06/19 20:19
10061-01-5
ND
ug/L
1.0
0.31
1
02/06/19 20:19
10061-02-6
ND
ug/L
1.0
0.26
1
02/06/19 20:19
100-41-4
ND
ug/L
5.0
0.57
1
02/06/19 20:19
591-78-6
ND
ug/L
20.0
12.5
1
02/06/19 20:19
74-88-4
ND
ug/L
5.0
3.7
1
02/06/19 20:19
75-09-2
ND
ug/L
5.0
4.5
1
02/06/19 20:19
108-10-1
ND
ug/L
1.0
0.27
1
02/06/19 20:19
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 20:19
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 20:19
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 20:19
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 20:19
108-88-3
ND
ug/L
1.0
0.18
1
02/06/19 20:19
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 20:19
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 20:19
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 20:19
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 20:19
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 20:19
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 20:19
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 20:19
1330-20-7
98
%
70-130
1
02/06/19 20:19
460-00-4
101
%
70-130
1
02/06/19 20:19
17060-07-0
100
%
70-130
1
02/06/19 20:19
2037-26-5
Analytical Method: EPA 8260E Mod.
49.8
ug/L
2.0
1.9
1
02/13/1916:41
123-91-1
92
%
50-150
1
02/13/1916:41
17060-07-0
97
%
50-150
1
02/13/1916:41
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW5 Lab ID: 92416424002 Collected: 02/04/19 15:26 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
1,2-Dichloropropane
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:36
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:36
7440-38-2
110
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-39-3
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:36
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:36
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-47-3
24.0
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-48-4
4.3J
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-50-8
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7439-92-1
5.5
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:36
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-22-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:36
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:36
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:35 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
25.0
6.2
1
02/06/19 20:56
67-64-1
ND
ug/L
10.0
0.90
1
02/06/19 20:56
107-13-1
ND
ug/L
1.0
0.15
1
02/06/19 20:56
71-43-2
ND
ug/L
1.0
0.34
1
02/06/19 20:56
74-97-5
ND
ug/L
1.0
0.26
1
02/06/19 20:56
75-27-4
ND
ug/L
1.0
0.62
1
02/06/19 20:56
75-25-2
ND
ug/L
2.0
0.62
1
02/06/19 20:56
74-83-9
ND
ug/L
5.0
3.3
1
02/06/19 20:56
78-93-3
ND
ug/L
2.0
0.40
1
02/06/19 20:56
75-15-0
ND
ug/L
1.0
0.22
1
02/06/19 20:56
56-23-5
ND
ug/L
1.0
0.23
1
02/06/19 20:56
108-90-7
ND
ug/L
1.0
0.49
1
02/06/19 20:56
75-00-3
ND
ug/L
5.0
2.3
1
02/06/19 20:56
67-66-3
ND
ug/L
1.0
0.39
1
02/06/19 20:56
74-87-3
ND
ug/L
2.0
0.26
1
02/06/19 20:56
96-12-8
ND
ug/L
1.0
0.41
1
02/06/19 20:56
124-48-1
ND
ug/L
1.0
0.26
1
02/06/19 20:56
106-93-4
ND
ug/L
1.0
0.46
1
02/06/19 20:56
74-95-3
ND
ug/L
1.0
0.29
1
02/06/19 20:56
95-50-1
ND
ug/L
1.0
0.26
1
02/06/19 20:56
106-46-7
ND
ug/L
1.0
0.54
1
02/06/19 20:56
110-57-6
ND
ug/L
1.0
0.27
1
02/06/19 20:56
75-34-3
ND
ug/L
1.0
0.34
1
02/06/19 20:56
107-06-2
ND
ug/L
1.0
0.24
1
02/06/19 20:56
75-35-4
ND
ug/L
1.0
0.29
1
02/06/19 20:56
156-59-2
ND
ug/L
1.0
0.25
1
02/06/19 20:56
156-60-5
ND
ug/L
1.0
0.19
1
02/06/19 20:56
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 9 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW5 Lab ID: 92416424002 Collected: 02/04/19 15:26 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
0.30
1
02/06/19 20:56
10061-01-5
ND
ug/L
1.0
0.31
1
02/06/19 20:56
10061-02-6
ND
ug/L
1.0
0.26
1
02/06/19 20:56
100-41-4
ND
ug/L
5.0
0.57
1
02/06/19 20:56
591-78-6
ND
ug/L
20.0
12.5
1
02/06/19 20:56
74-88-4
ND
ug/L
5.0
3.7
1
02/06/19 20:56
75-09-2
ND
ug/L
5.0
4.5
1
02/06/19 20:56
108-10-1
ND
ug/L
1.0
0.27
1
02/06/19 20:56
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 20:56
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 20:56
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 20:56
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 20:56
108-88-3
ND
ug/L
1.0
0.18
1
02/06/19 20:56
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 20:56
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 20:56
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 20:56
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 20:56
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 20:56
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 20:56
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 20:56
1330-20-7
97
%
70-130
1
02/06/19 20:56
460-00-4
103
%
70-130
1
02/06/19 20:56
17060-07-0
100
%
70-130
1
02/06/19 20:56
2037-26-5
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
1.9
1
02/13/1917:01
123-91-1
94
%
50-150
1
02/13/1917:01
17060-07-0
99
%
50-150
1
02/13/1917:01
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 10 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW6 Lab ID: 92416424003 Collected: 02/04/19 15:46 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP Analytical Method: EPA 6010D Preparation Method: EPA 3010A
Antimony
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:40
7440-36-0
Arsenic
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:40
7440-38-2
Barium
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-39-3
Beryllium
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:40
7440-41-7
Cadmium
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:40
7440-43-9
Chromium
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-47-3
Cobalt
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-48-4
Copper
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-50-8
Lead
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7439-92-1
Nickel
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-02-0
Selenium
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:40
7782-49-2
Silver
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-22-4
Vanadium
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:40
7440-62-2
Zinc
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:40
7440-66-6
6020 MET ICPMS
Analytical Method: EPA 6020E Preparation Method:
EPA
3010A
Thallium
ND
ug/L
0.10
0.060
1
02/06/19 04:28
02/06/19 13:46
7440-28-0
8260 MSV Low Level Landfill
Analytical Method: EPA 8260E
Acetone
ND
ug/L
25.0
6.2
1
02/06/19 21:15
67-64-1
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 21:15
107-13-1
Benzene
ND
ug/L
1.0
0.15
1
02/06/19 21:15
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 21:15
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 21:15
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 21:15
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 21:15
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 21:15
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 21:15
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 21:15
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/06/19 21:15
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/06/19 21:15
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 21:15
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 21:15
74-87-3
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 21:15
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 21:15
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 21:15
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 21:15
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/06/19 21:15
95-50-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 21:15
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 21:15
110-57-6
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 21:15
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 21:15
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 21:15
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 21:15
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 21:15
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 21:15
78-87-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW6 Lab ID: 92416424003 Collected: 02/04/19 15:46 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
0.30
1
02/06/19 21:15
10061-01-5
ND
ug/L
1.0
0.31
1
02/06/19 21:15
10061-02-6
ND
ug/L
1.0
0.26
1
02/06/19 21:15
100-41-4
ND
ug/L
5.0
0.57
1
02/06/19 21:15
591-78-6
ND
ug/L
20.0
12.5
1
02/06/19 21:15
74-88-4
ND
ug/L
5.0
3.7
1
02/06/19 21:15
75-09-2
ND
ug/L
5.0
4.5
1
02/06/19 21:15
108-10-1
ND
ug/L
1.0
0.27
1
02/06/19 21:15
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 21:15
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 21:15
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 21:15
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 21:15
108-88-3
ND
ug/L
1.0
0.18
1
02/06/19 21:15
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 21:15
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 21:15
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 21:15
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 21:15
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 21:15
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 21:15
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 21:15
1330-20-7
102
%
70-130
1
02/06/19 21:15
460-00-4
103
%
70-130
1
02/06/19 21:15
17060-07-0
99
%
70-130
1
02/06/19 21:15
2037-26-5
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
1.9
1
02/13/1917:20
123-91-1
94
%
50-150
1
02/13/1917:20
17060-07-0
99
%
50-150
1
02/13/1917:20
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-NES-1
Lab ID:
92416424004
Collected:
02/04/19 17:37
Received: 02/05/19 10:10 Matrix: Water
Report
Parameters
Results
Units
Limit
MDL DF
Prepared Analyzed
CAS No. Qual
8260 MSV Low Level Landfill
Analytical
Method: EPA 8260E
Benzene
ND
ug/L
1.0
0.15 1
02/06/19 21:33
71-43-2
Surrogates
4-Bromofluorobenzene (S)
98
%
70-130
1
02/06/19 21:33
460-00-4
1,2-Dichloroethane-d4 (S)
103
%
70-130
1
02/06/19 21:33
17060-07-0
Toluene-d8 (S)
99
%
70-130
1
02/06/19 21:33
2037-26-5
8260 MSV SIM
Analytical
Method: EPA 8260E
Mod.
1,4-Dioxane (p-Dioxane)
ND
ug/L
2.0
1.9 1
02/14/19 17:01
123-91-1
Surrogates
1,2-Dichloroethane-d4 (S)
98
%
50-150
1
02/14/19 17:01
17060-07-0
Toluene-d8 (S)
97
%
50-150
1
02/14/19 17:01
2037-26-5
Date: 02/15/2019 06:14 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 13 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
8151A Cl Acid Herbicide Waters
2,4-D
Dinoseb
2,4,5-T
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP
Antimony
Arsenic
Barium
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
309-00-2
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
319-84-6
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
319-85-7
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
319-86-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
58-89-9
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1916:53
57-74-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
72-54-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
72-55-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
50-29-3
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
60-57-1
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
959-98-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
33213-65-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
1031-07-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
72-20-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
7421-93-4
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
76-44-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1916:53
1024-57-3
ND
ug/L
0.15
0.15
1
02/06/1911:27
02/07/1916:53
72-43-5
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1916:53
8001-35-2
88
%
10-130
1
02/06/1911:27
02/07/1916:53
877-09-8
62
%
10-130
1
02/06/1911:27
02/07/1916:53
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
12674-11-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
11104-28-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
11141-16-5
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
53469-21-9
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
12672-29-6
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
11097-69-1
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:08
11096-82-5
59
%
10-130
1
02/06/19 15:28
02/07/19 21:08
2051-24-3
Analytical Method: EPA8151A Preparation Method: EPA8151A
ND
ug/L
5.0
1.6
1
02/11/19 08:50
02/12/19 00:42
94-75-7
ND
ug/L
5.0
1.2
1
02/11/19 08:50
02/12/19 00:42
88-85-7
ND
ug/L
5.0
1.1
1
02/11/19 08:50
02/12/19 00:42
93-76-5
ND
ug/L
10.0
1.0
1
02/11/19 08:50
02/12/19 00:42
93-72-1
108
%.
10-155
1
02/11/19 08:50
02/12/19 00:42
19719-28-9
Analytical Method: EPA 601 OD Preparation Method:
EPA
3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:43
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:43
7440-38-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-39-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 14 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
1400111 �41 :4111 9 [y :2 61.9
Thallium
7470 Mercury
Mercury
8270 APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Diallate
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:43
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:43
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-48-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-50-8
ND
ug/L
50.0
25.0
1
02/06/19 03:58
02/07/19 18:43
7439-89-6
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7439-92-1
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7439-96-5
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:43
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-22-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-31-5
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:43
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:43
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:49 7440-28-0
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.10 1 02/05/1914:45 02/06/1912:47 7439-97-6
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1911:59
83-32-9
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1911:59
208-96-8
ND
ug/L
10.0
4.3
1
02/11/1919:54
02/13/1911:59
98-86-2
ND
ug/L
20.0
0.84
1
02/11/1919:54
02/13/1911:59
53-96-3
ND
ug/L
10.0
0.92
1
02/11/1919:54
02/13/1911:59
92-67-1
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1911:59
120-12-7
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1911:59
56-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1911:59
50-32-8
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1911:59
205-99-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1911:59
191-24-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1911:59
207-08-9
ND
ug/L
20.0
7.0
1
02/11/1919:54
02/13/1911:59
100-51-6
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1911:59
101-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1911:59
85-68-7
ND
ug/L
20.0
4.6
1
02/11/1919:54
02/13/1911:59
59-50-7
ND
ug/L
20.0
6.8
1
02/11/1919:54
02/13/1911:59
106-47-8
ND
ug/L
10.0
0.72
1
02/11/1919:54
02/13/1911:59
510-15-6
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1911:59
111-91-1
ND
ug/L
10.0
3.1
1
02/11/1919:54
02/13/1911:59
111-44-4
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1911:59
91-58-7
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1911:59
95-57-8
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1911:59
7005-72-3
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1911:59
218-01-9
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1911:59
2303-16-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L2
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Huntersville, NC 28078
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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Dibenz(a,h)anthracene
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 11:59
53-70-3
Dibenzofuran
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 11:59
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
2.8
1
02/11/19 19:54
02/13/19 11:59
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 11:59
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 11:59
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 11:59
84-66-2
Dimethoate
ND
ug/L
10.0
0.92
1
02/11/19 19:54
02/13/19 11:59
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
0.35
1
02/11/19 19:54
02/13/19 11:59
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
0.77
1
02/11/19 19:54
02/13/19 11:59
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
10.0
2.1
1
02/11/19 19:54
02/13/19 11:59
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 11:59
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.3
1
02/11/19 19:54
02/13/19 11:59
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 11:59
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
4.4
1
02/11/19 19:54
02/13/19 11:59
534-52-1
1,3-Dinitrobenzene
ND
ug/L
20.0
1.5
1
02/11/19 19:54
02/13/19 11:59
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
10.1
1
02/11/19 19:54
02/13/19 11:59
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 11:59
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
2.9
1
02/11/19 19:54
02/13/19 11:59
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 11:59
117-84-0
Diphenylamine
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 11:59
122-39-4
Disulfoton
ND
ug/L
10.0
1.4
1
02/11/19 19:54
02/13/19 11:59
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1.4
1
02/11/19 19:54
02/13/19 11:59
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
1.8
1
02/11/19 19:54
02/13/19 11:59
62-50-0
Famphur
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 11:59
52-85-7
Fluoranthene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 11:59
206-44-0
Fluorene
ND
ug/L
10.0
3.0
1
02/11/19 19:54
02/13/19 11:59
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 11:59
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.5
1
02/11/19 19:54
02/13/19 11:59
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 11:59
77-47-4
Hexachloroethane
ND
ug/L
10.0
4.0
1
02/11/19 19:54
02/13/19 11:59
67-72-1
Hexachloropropene
ND
ug/L
10.0
1.6
1
02/11/19 19:54
02/13/19 11:59
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 11:59
193-39-5
Isodrin
ND
ug/L
20.0
2.0
1
02/11/19 19:54
02/13/19 11:59
465-73-6
Isophorone
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 11:59
78-59-1
Isosafrole
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 11:59
120-58-1
Kepone
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 11:59
143-50-0
Methapyrilene
ND
ug/L
50.0
2.7
1
02/11/19 19:54
02/13/19 11:59
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
0.82
1
02/11/19 19:54
02/13/19 11:59
56-49-5
Methyl methanesulfonate
ND
ug/L
5.0
1.3
1
02/11/19 19:54
02/13/19 11:59
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
2.8
1
02/11/19 19:54
02/13/19 11:59
91-57-6
Methyl parathion
ND
ug/L
10.0
1.1
1
02/11/19 19:54
02/13/19 11:59
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
3.6
1
02/11/19 19:54
02/13/19 11:59
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 11:59
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
0.96
1
02/11/19 19:54
02/13/19 11:59
134-32-7
2-Naphthalenamine
ND
ug/L
5.0
0.98
1
02/11/19 19:54
02/13/19 11:59
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
1.8
1
02/11/19 19:54
02/13/19 11:59
130-15-4
REPORT OF LABORATORY ANALYSIS
L2
L2
L2
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O,O,O-Triethylphosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV Low Level Landfill
Acetone
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
50.0
5.5
1
02/11/1919:54
02/13/1911:59
88-74-4
ND
ug/L
50.0
5.0
1
02/11/1919:54
02/13/1911:59
99-09-2
ND
ug/L
20.0
3.6
1
02/11/1919:54
02/13/1911:59
100-01-6
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1911:59
98-95-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1911:59
88-75-5
ND
ug/L
50.0
7.8
1
02/11/1919:54
02/13/1911:59
100-02-7
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1911:59
99-55-8
ND
ug/L
20.0
2.8
1
02/11/1919:54
02/13/1911:59
55-18-5
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1911:59
62-75-9
ND
ug/L
10.0
2.2
1
02/11/1919:54
02/13/1911:59
924-16-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1911:59
621-64-7
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1911:59
86-30-6
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1911:59
10595-95-6
ND
ug/L
20.0
1.9
1
02/11/1919:54
02/13/1911:59
100-75-4
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1911:59
930-55-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1911:59
126-68-1
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1911:59
108-60-1
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1911:59
56-38-2
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1911:59
608-93-5
ND
ug/L
20.0
1.0
1
02/11/1919:54
02/13/1911:59
82-68-8
ND
ug/L
25.0
3.1
1
02/11/1919:54
02/13/1911:59
87-86-5
ND
ug/L
20.0
0.97
1
02/11/1919:54
02/13/1911:59
62-44-2
ND
ug/L
10.0
2.4
1
02/11/1919:54
02/13/1911:59
85-01-8
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1911:59
108-95-2
ND
ug/L
10.0
0.96
1
02/11/1919:54
02/13/1911:59
106-50-3
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1911:59
298-02-2
ND
ug/L
10.0
0.97
1
02/11/1919:54
02/13/1911:59
23950-58-5
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1911:59
129-00-0
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1911:59
94-59-7
ND
ug/L
10.0
1.7
1
02/11/1919:54
02/13/1911:59
95-94-3
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1911:59
58-90-2
ND
ug/L
20.0
1.2
1
02/11/1919:54
02/13/1911:59
297-97-2
ND
ug/L
10.0
1.6
1
02/11/1919:54
02/13/1911:59
95-53-4
ND
ug/L
10.0
2.3
1
02/11/1919:54
02/13/1911:59
95-95-4
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1911:59
88-06-2
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1911:59
99-35-4
53
%
13-130
1
02/11/1919:54
02/13/1911:59
4165-60-0
48
%
13-130
1
02/11/1919:54
02/13/1911:59
321-60-8
48
%
25-130
1
02/11/1919:54
02/13/1911:59
1718-51-0
21
%
10-130
1
02/11/1919:54
02/13/1911:59
13127-88-3
31
%
10-130
1
02/11/1919:54
02/13/1911:59
367-12-4
53
%
10-137
1
02/11/1919:54
02/13/1911:59
118-79-6
Analytical Method: EPA 8260E
ND ug/L 25.0 6.2 1
REPORT OF LABORATORY ANALYSIS
02/06/1919:24 67-64-1
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 17 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetonitrile
ND
ug/L
50.0
30.4
1
02/06/19 19:24
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
02/06/19 19:24
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 19:24
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
02/06/19 19:24
107-05-1
Benzene
ND
ug/L
1.0
0.15
1
02/06/19 19:24
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 19:24
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 19:24
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 19:24
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 19:24
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 19:24
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 19:24
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 19:24
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/06/19 19:24
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/06/19 19:24
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 19:24
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 19:24
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
02/06/19 19:24
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 19:24
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 19:24
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 19:24
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 19:24
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/06/19 19:24
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
02/06/19 19:24
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 19:24
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 19:24
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
02/06/19 19:24
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 19:24
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 19:24
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 19:24
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 19:24
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 19:24
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 19:24
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
02/06/19 19:24
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
02/06/19 19:24
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.21
1
02/06/19 19:24
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
02/06/19 19:24
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.31
1
02/06/19 19:24
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.26
1
02/06/19 19:24
100-41-4
Ethyl methacrylate
ND
ug/L
1.0
0.51
1
02/06/19 19:24
97-63-2
Hexachloro-1,3-butadiene
ND
ug/L
1.0
0.44
1
02/06/19 19:24
87-68-3
2-Hexanone
ND
ug/L
5.0
0.57
1
02/06/19 19:24
591-78-6
lodomethane
ND
ug/L
20.0
12.5
1
02/06/19 19:24
74-88-4
Isobutanol
ND
ug/L
100
66.4
1
02/06/19 19:24
78-83-1
Methacrylonitrile
ND
ug/L
10.0
1.9
1
02/06/19 19:24
126-98-7
Methylene Chloride
ND
ug/L
5.0
3.7
1
02/06/19 19:24
75-09-2 C9
Methyl methacrylate
ND
ug/L
2.0
0.46
1
02/06/19 19:24
80-62-6
REPORT OF LABORATORY ANALYSIS
This report
shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM
without the written consent of Pace Analytical Services, LLC.
Page 18 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: FIELD BLANK Lab ID: 92416424005 Collected: 02/04/19 19:00 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S2D Sulfide Water
Sulfide
4500CNE Cyanide, Total
Cyanide
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
5.0
4.5
1
02/06/1919:24
108-10-1
ND
ug/L
1.0
0.35
1
02/06/1919:24
91-20-3
ND
ug/L
20.0
1.8
1
02/06/1919:24
107-12-0
ND
ug/L
1.0
0.27
1
02/06/1919:24
100-42-5
ND
ug/L
1.0
0.34
1
02/06/1919:24
630-20-6
ND
ug/L
1.0
0.22
1
02/06/1919:24
79-34-5
ND
ug/L
1.0
0.16
1
02/06/1919:24
127-18-4
ND
ug/L
1.0
0.24
1
02/06/1919:24
108-88-3
ND
ug/L
1.0
0.22
1
02/06/1919:24
120-82-1
ND
ug/L
1.0
0.18
1
02/06/1919:24
71-55-6
ND
ug/L
1.0
0.24
1
02/06/1919:24
79-00-5
ND
ug/L
1.0
0.22
1
02/06/1919:24
79-01-6
ND
ug/L
1.0
0.31
1
02/06/1919:24
75-69-4
ND
ug/L
1.0
0.35
1
02/06/1919:24
96-18-4
ND
ug/L
2.0
1.4
1
02/06/1919:24
108-05-4
ND
ug/L
1.0
0.24
1
02/06/1919:24
75-01-4
ND
ug/L
1.0
0.63
1
02/06/1919:24
1330-20-7
99
%
70-130
1
02/06/1919:24
460-00-4
103
%
70-130
1
02/06/1919:24
17060-07-0
100
%
70-130
1
02/06/1919:24
2037-26-5
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
1.9
1
02/13/1911:51
123-91-1
91
%
50-150
1
02/13/1911:51
17060-07-0
99
%
50-150
1
02/13/1911:51
2037-26-5
Analytical Method: SM 4500-S2D-2011
ND ug/L 100 50.0 1 02/08/1918:58 18496-25-8
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
ND ug/L 8.0 6.0 1 02/12/19 09:33 02/12/19 16:46 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
8151A Cl Acid Herbicide Waters
2,4-D
Dinoseb
2,4,5-T
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP
Antimony
Arsenic
Barium
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
309-00-2
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
319-84-6
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
319-85-7
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
319-86-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
58-89-9
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:06
57-74-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
72-54-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
72-55-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
50-29-3
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
60-57-1
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
959-98-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
33213-65-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
1031-07-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
72-20-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
7421-93-4
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
76-44-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:06
1024-57-3
ND
ug/L
0.15
0.15
1
02/06/1911:27
02/07/1917:06
72-43-5
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:06
8001-35-2
111
%
10-130
1
02/06/1911:27
02/07/1917:06
877-09-8
55
%
10-130
1
02/06/1911:27
02/07/1917:06
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
12674-11-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
11104-28-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
11141-16-5
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
53469-21-9
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
12672-29-6
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
11097-69-1
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:21
11096-82-5
59
%
10-130
1
02/06/19 15:28
02/07/19 21:21
2051-24-3
Analytical Method: EPA8151A Preparation Method: EPA8151A
ND
ug/L
5.0
1.6
1
02/11/19 08:50
02/12/19 01:03
94-75-7
ND
ug/L
5.0
1.2
1
02/11/19 08:50
02/12/19 01:03
88-85-7
ND
ug/L
5.0
1.1
1
02/11/19 08:50
02/12/19 01:03
93-76-5
ND
ug/L
10.0
1.0
1
02/11/19 08:50
02/12/19 01:03
93-72-1
136
%.
10-155
1
02/11/19 08:50
02/12/19 01:03
19719-28-9
Analytical Method: EPA 601 OD Preparation Method:
EPA
3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:46
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:46
7440-38-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-39-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 20 of 76

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Pace Analytical Services, LLC
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[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
1400111 �41 :4111 9 [y :2 61.9
Thallium
7470 Mercury
Mercury
8270 APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Diallate
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:46
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:46
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-48-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-50-8
230
ug/L
50.0
25.0
1
02/06/19 03:58
02/07/19 18:46
7439-89-6
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7439-92-1
121
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7439-96-5
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:46
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-22-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-31-5
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:46
7440-62-2
6.8J
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:46
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:53 7440-28-0
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.10 1 02/05/1914:45 02/06/1913:22 7439-97-6
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1912:25
83-32-9
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1912:25
208-96-8
ND
ug/L
10.0
4.3
1
02/11/1919:54
02/13/1912:25
98-86-2
ND
ug/L
20.0
0.84
1
02/11/1919:54
02/13/1912:25
53-96-3
ND
ug/L
10.0
0.92
1
02/11/1919:54
02/13/1912:25
92-67-1
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:25
120-12-7
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:25
56-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:25
50-32-8
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1912:25
205-99-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:25
191-24-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:25
207-08-9
ND
ug/L
20.0
7.0
1
02/11/1919:54
02/13/1912:25
100-51-6
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1912:25
101-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:25
85-68-7
ND
ug/L
20.0
4.6
1
02/11/1919:54
02/13/1912:25
59-50-7
ND
ug/L
20.0
6.8
1
02/11/1919:54
02/13/1912:25
106-47-8
ND
ug/L
10.0
0.72
1
02/11/1919:54
02/13/1912:25
510-15-6
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1912:25
111-91-1
ND
ug/L
10.0
3.1
1
02/11/1919:54
02/13/1912:25
111-44-4
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:25
91-58-7
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:25
95-57-8
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:25
7005-72-3
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:25
218-01-9
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:25
2303-16-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L2
Page 21 of 76

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Dibenz(a,h)anthracene
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 12:25
53-70-3
Dibenzofuran
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 12:25
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
2.8
1
02/11/19 19:54
02/13/19 12:25
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 12:25
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 12:25
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 12:25
84-66-2
Dimethoate
ND
ug/L
10.0
0.92
1
02/11/19 19:54
02/13/19 12:25
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
0.35
1
02/11/19 19:54
02/13/19 12:25
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
0.77
1
02/11/19 19:54
02/13/19 12:25
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
10.0
2.1
1
02/11/19 19:54
02/13/19 12:25
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 12:25
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.3
1
02/11/19 19:54
02/13/19 12:25
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 12:25
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
4.4
1
02/11/19 19:54
02/13/19 12:25
534-52-1
1,3-Dinitrobenzene
ND
ug/L
20.0
1.5
1
02/11/19 19:54
02/13/19 12:25
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
10.1
1
02/11/19 19:54
02/13/19 12:25
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 12:25
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
2.9
1
02/11/19 19:54
02/13/19 12:25
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 12:25
117-84-0
Diphenylamine
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 12:25
122-39-4
Disulfoton
ND
ug/L
10.0
1.4
1
02/11/19 19:54
02/13/19 12:25
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1.4
1
02/11/19 19:54
02/13/19 12:25
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
1.8
1
02/11/19 19:54
02/13/19 12:25
62-50-0
Famphur
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:25
52-85-7
Fluoranthene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:25
206-44-0
Fluorene
ND
ug/L
10.0
3.0
1
02/11/19 19:54
02/13/19 12:25
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 12:25
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.5
1
02/11/19 19:54
02/13/19 12:25
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 12:25
77-47-4
Hexachloroethane
ND
ug/L
10.0
4.0
1
02/11/19 19:54
02/13/19 12:25
67-72-1
Hexachloropropene
ND
ug/L
10.0
1.6
1
02/11/19 19:54
02/13/19 12:25
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:25
193-39-5
Isodrin
ND
ug/L
20.0
2.0
1
02/11/19 19:54
02/13/19 12:25
465-73-6
Isophorone
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 12:25
78-59-1
Isosafrole
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 12:25
120-58-1
Kepone
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 12:25
143-50-0
Methapyrilene
ND
ug/L
50.0
2.7
1
02/11/19 19:54
02/13/19 12:25
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
0.82
1
02/11/19 19:54
02/13/19 12:25
56-49-5
Methyl methanesulfonate
ND
ug/L
5.0
1.3
1
02/11/19 19:54
02/13/19 12:25
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
2.8
1
02/11/19 19:54
02/13/19 12:25
91-57-6
Methyl parathion
ND
ug/L
10.0
1.1
1
02/11/19 19:54
02/13/19 12:25
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
3.6
1
02/11/19 19:54
02/13/19 12:25
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 12:25
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
0.96
1
02/11/19 19:54
02/13/19 12:25
134-32-7
2-Naphthalenamine
ND
ug/L
5.0
0.98
1
02/11/19 19:54
02/13/19 12:25
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
1.8
1
02/11/19 19:54
02/13/19 12:25
130-15-4
REPORT OF LABORATORY ANALYSIS
L2
L2
L2
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 22 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O,O,O-Triethylphosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV Low Level Landfill
Acetone
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
50.0
5.5
1
02/11/1919:54
02/13/1912:25
88-74-4
ND
ug/L
50.0
5.0
1
02/11/1919:54
02/13/1912:25
99-09-2
ND
ug/L
20.0
3.6
1
02/11/1919:54
02/13/1912:25
100-01-6
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1912:25
98-95-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1912:25
88-75-5
ND
ug/L
50.0
7.8
1
02/11/1919:54
02/13/1912:25
100-02-7
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:25
99-55-8
ND
ug/L
20.0
2.8
1
02/11/1919:54
02/13/1912:25
55-18-5
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1912:25
62-75-9
ND
ug/L
10.0
2.2
1
02/11/1919:54
02/13/1912:25
924-16-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1912:25
621-64-7
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:25
86-30-6
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:25
10595-95-6
ND
ug/L
20.0
1.9
1
02/11/1919:54
02/13/1912:25
100-75-4
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1912:25
930-55-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:25
126-68-1
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1912:25
108-60-1
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:25
56-38-2
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:25
608-93-5
ND
ug/L
20.0
1.0
1
02/11/1919:54
02/13/1912:25
82-68-8
ND
ug/L
25.0
3.1
1
02/11/1919:54
02/13/1912:25
87-86-5
ND
ug/L
20.0
0.97
1
02/11/1919:54
02/13/1912:25
62-44-2
ND
ug/L
10.0
2.4
1
02/11/1919:54
02/13/1912:25
85-01-8
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1912:25
108-95-2
ND
ug/L
10.0
0.96
1
02/11/1919:54
02/13/1912:25
106-50-3
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:25
298-02-2
ND
ug/L
10.0
0.97
1
02/11/1919:54
02/13/1912:25
23950-58-5
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:25
129-00-0
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1912:25
94-59-7
ND
ug/L
10.0
1.7
1
02/11/1919:54
02/13/1912:25
95-94-3
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:25
58-90-2
ND
ug/L
20.0
1.2
1
02/11/1919:54
02/13/1912:25
297-97-2
ND
ug/L
10.0
1.6
1
02/11/1919:54
02/13/1912:25
95-53-4
ND
ug/L
10.0
2.3
1
02/11/1919:54
02/13/1912:25
95-95-4
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1912:25
88-06-2
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:25
99-35-4
56
%
13-130
1
02/11/1919:54
02/13/1912:25
4165-60-0
50
%
13-130
1
02/11/1919:54
02/13/1912:25
321-60-8
61
%
25-130
1
02/11/1919:54
02/13/1912:25
1718-51-0
23
%
10-130
1
02/11/1919:54
02/13/1912:25
13127-88-3
33
%
10-130
1
02/11/1919:54
02/13/1912:25
367-12-4
56
%
10-137
1
02/11/1919:54
02/13/1912:25
118-79-6
Analytical Method: EPA 8260E
ND ug/L 25.0 6.2 1
REPORT OF LABORATORY ANALYSIS
02/06/19 21:52 67-64-1
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 23 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetonitrile
ND
ug/L
50.0
30.4
1
02/06/19 21:52
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
02/06/19 21:52
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 21:52
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
02/06/19 21:52
107-05-1
Benzene
ND
ug/L
1.0
0.15
1
02/06/19 21:52
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 21:52
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 21:52
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 21:52
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 21:52
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 21:52
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 21:52
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 21:52
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/06/19 21:52
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/06/19 21:52
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 21:52
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 21:52
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
02/06/19 21:52
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 21:52
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 21:52
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 21:52
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 21:52
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/06/19 21:52
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
02/06/19 21:52
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 21:52
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 21:52
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
02/06/19 21:52
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 21:52
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 21:52
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 21:52
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 21:52
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 21:52
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 21:52
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
02/06/19 21:52
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
02/06/19 21:52
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.21
1
02/06/19 21:52
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
02/06/19 21:52
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.31
1
02/06/19 21:52
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.26
1
02/06/19 21:52
100-41-4
Ethyl methacrylate
ND
ug/L
1.0
0.51
1
02/06/19 21:52
97-63-2
Hexachloro-1,3-butadiene
ND
ug/L
1.0
0.44
1
02/06/19 21:52
87-68-3
2-Hexanone
ND
ug/L
5.0
0.57
1
02/06/19 21:52
591-78-6
lodomethane
ND
ug/L
20.0
12.5
1
02/06/19 21:52
74-88-4
Isobutanol
ND
ug/L
100
66.4
1
02/06/19 21:52
78-83-1
Methacrylonitrile
ND
ug/L
10.0
1.9
1
02/06/19 21:52
126-98-7
Methylene Chloride
ND
ug/L
5.0
3.7
1
02/06/19 21:52
75-09-2
Methyl methacrylate
ND
ug/L
2.0
0.46
1
02/06/19 21:52
80-62-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 24 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW1R Lab ID: 92416424006 Collected: 02/04/19 08:34 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S213 Sulfide Water
Sulfide
4500CNE Cyanide, Total
Cyanide
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
5.0
4.5
1
02/06/19 21:52
108-10-1
ND
ug/L
1.0
0.35
1
02/06/19 21:52
91-20-3
ND
ug/L
20.0
1.8
1
02/06/19 21:52
107-12-0
ND
ug/L
1.0
0.27
1
02/06/19 21:52
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 21:52
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 21:52
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 21:52
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 21:52
108-88-3
ND
ug/L
1.0
0.22
1
02/06/19 21:52
120-82-1
ND
ug/L
1.0
0.18
1
02/06/19 21:52
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 21:52
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 21:52
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 21:52
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 21:52
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 21:52
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 21:52
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 21:52
1330-20-7
100
%
70-130
1
02/06/19 21:52
460-00-4
100
%
70-130
1
02/06/19 21:52
17060-07-0
101
%
70-130
1
02/06/19 21:52
2037-26-5
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
1.9
1
02/14/1917:20
123-91-1
91
%
50-150
1
02/14/1917:20
17060-07-0
98
%
50-150
1
02/14/1917:20
2037-26-5
Analytical Method: SM 4500-S2D-2011
ND ug/L 100 50.0 1 02/08/1918:59 18496-25-8
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
ND ug/L 8.0 6.0 1 02/12/19 09:33 02/12/19 16:47 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 25 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
8151A Cl Acid Herbicide Waters
2,4-D
Dinoseb
2,4,5-T
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP
Antimony
Arsenic
Barium
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
309-00-2
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
319-84-6
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
319-85-7
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
319-86-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
58-89-9
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:18
57-74-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
72-54-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
72-55-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
50-29-3
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
60-57-1
0.078
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
959-98-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
33213-65-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
1031-07-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
72-20-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
7421-93-4
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
76-44-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:18
1024-57-3
ND
ug/L
0.15
0.15
1
02/06/1911:27
02/07/1917:18
72-43-5
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:18
8001-35-2
89
%
10-130
1
02/06/1911:27
02/07/1917:18
877-09-8
52
%
10-130
1
02/06/1911:27
02/07/1917:18
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
12674-11-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
11104-28-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
11141-16-5
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
53469-21-9
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
12672-29-6
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
11097-69-1
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:33
11096-82-5
49
%
10-130
1
02/06/19 15:28
02/07/19 21:33
2051-24-3
Analytical Method: EPA8151A Preparation Method: EPA8151A
ND
ug/L
5.0
1.6
1
02/11/19 08:50
02/12/19 01:25
94-75-7
ND
ug/L
5.0
1.2
1
02/11/19 08:50
02/12/19 01:25
88-85-7
ND
ug/L
5.0
1.1
1
02/11/19 08:50
02/12/19 01:25
93-76-5
ND
ug/L
10.0
1.0
1
02/11/19 08:50
02/12/19 01:25
93-72-1
137
%.
10-155
1
02/11/19 08:50
02/12/19 01:25
19719-28-9
Analytical Method: EPA 601 OD Preparation Method:
EPA
3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:49
7440-36-0
5.7J
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:49
7440-38-2
104
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-39-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 26 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
1400111 �41 :4111 9 [y :2 61.9
Thallium
7470 Mercury
Mercury
8270 APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Diallate
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 601 OD Preparation Method: EPA 301 OA
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:49
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:49
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-47-3
9.9
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-48-4
3.OJ
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-50-8
9420
ug/L
50.0
25.0
1
02/06/19 03:58
02/07/19 18:49
7439-89-6
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7439-92-1
7640
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7439-96-5
85.7
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:49
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-22-4
24.8
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-31-5
3.5J
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:49
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:49
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:56 7440-28-0
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.10 1 02/05/1914:45 02/06/1913:25 7439-97-6
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1912:50
83-32-9
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1912:50
208-96-8
ND
ug/L
10.0
4.3
1
02/11/1919:54
02/13/1912:50
98-86-2
ND
ug/L
20.0
0.84
1
02/11/1919:54
02/13/1912:50
53-96-3
ND
ug/L
10.0
0.92
1
02/11/1919:54
02/13/1912:50
92-67-1
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:50
120-12-7
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:50
56-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:50
50-32-8
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1912:50
205-99-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:50
191-24-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:50
207-08-9
ND
ug/L
20.0
7.0
1
02/11/1919:54
02/13/1912:50
100-51-6
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1912:50
101-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:50
85-68-7
ND
ug/L
20.0
4.6
1
02/11/1919:54
02/13/1912:50
59-50-7
ND
ug/L
20.0
6.8
1
02/11/1919:54
02/13/1912:50
106-47-8
ND
ug/L
10.0
0.72
1
02/11/1919:54
02/13/1912:50
510-15-6
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1912:50
111-91-1
ND
ug/L
10.0
3.1
1
02/11/1919:54
02/13/1912:50
111-44-4
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:50
91-58-7
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:50
95-57-8
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1912:50
7005-72-3
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:50
218-01-9
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1912:50
2303-16-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L2
Page 27 of 76

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[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Dibenz(a,h)anthracene
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 12:50
53-70-3
Dibenzofuran
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 12:50
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
2.8
1
02/11/19 19:54
02/13/19 12:50
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 12:50
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 12:50
87-65-0
Diethylphthalate
7.1J
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 12:50
84-66-2
Dimethoate
ND
ug/L
10.0
0.92
1
02/11/19 19:54
02/13/19 12:50
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
0.35
1
02/11/19 19:54
02/13/19 12:50
60-11-7
7,12-Dimethyl benz(a)anth racene
ND
ug/L
10.0
0.77
1
02/11/19 19:54
02/13/19 12:50
57-97-6
3,3'-Dimethyl benzidine
ND
ug/L
10.0
2.1
1
02/11/19 19:54
02/13/19 12:50
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 12:50
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.3
1
02/11/19 19:54
02/13/19 12:50
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 12:50
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
4.4
1
02/11/19 19:54
02/13/19 12:50
534-52-1
1,3-Dinitrobenzene
ND
ug/L
20.0
1.5
1
02/11/19 19:54
02/13/19 12:50
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
10.1
1
02/11/19 19:54
02/13/19 12:50
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 12:50
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
2.9
1
02/11/19 19:54
02/13/19 12:50
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 12:50
117-84-0
Diphenylamine
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 12:50
122-39-4
Disulfoton
ND
ug/L
10.0
1.4
1
02/11/19 19:54
02/13/19 12:50
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1.4
1
02/11/19 19:54
02/13/19 12:50
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
1.8
1
02/11/19 19:54
02/13/19 12:50
62-50-0
Famphur
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:50
52-85-7
Fluoranthene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:50
206-44-0
Fluorene
ND
ug/L
10.0
3.0
1
02/11/19 19:54
02/13/19 12:50
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 12:50
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.5
1
02/11/19 19:54
02/13/19 12:50
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 12:50
77-47-4
Hexachloroethane
ND
ug/L
10.0
4.0
1
02/11/19 19:54
02/13/19 12:50
67-72-1
Hexachloropropene
ND
ug/L
10.0
1.6
1
02/11/19 19:54
02/13/19 12:50
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 12:50
193-39-5
Isodrin
ND
ug/L
20.0
2.0
1
02/11/19 19:54
02/13/19 12:50
465-73-6
Isophorone
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 12:50
78-59-1
Isosafrole
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 12:50
120-58-1
Kepone
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 12:50
143-50-0
Methapyrilene
ND
ug/L
50.0
2.7
1
02/11/19 19:54
02/13/19 12:50
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
0.82
1
02/11/19 19:54
02/13/19 12:50
56-49-5
Methyl methanesulfonate
ND
ug/L
5.0
1.3
1
02/11/19 19:54
02/13/19 12:50
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
2.8
1
02/11/19 19:54
02/13/19 12:50
91-57-6
Methyl parathion
ND
ug/L
10.0
1.1
1
02/11/19 19:54
02/13/19 12:50
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
3.6
1
02/11/19 19:54
02/13/19 12:50
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 12:50
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
0.96
1
02/11/19 19:54
02/13/19 12:50
134-32-7
2-Naphthalenamine
ND
ug/L
5.0
0.98
1
02/11/19 19:54
02/13/19 12:50
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
1.8
1
02/11/19 19:54
02/13/19 12:50
130-15-4
REPORT OF LABORATORY ANALYSIS
L2
L2
L2
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
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[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O,O,O-Triethylphosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV Low Level Landfill
Acetone
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
50.0
5.5
1
02/11/1919:54
02/13/1912:50
88-74-4
ND
ug/L
50.0
5.0
1
02/11/1919:54
02/13/1912:50
99-09-2
ND
ug/L
20.0
3.6
1
02/11/1919:54
02/13/1912:50
100-01-6
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1912:50
98-95-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1912:50
88-75-5
ND
ug/L
50.0
7.8
1
02/11/1919:54
02/13/1912:50
100-02-7
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:50
99-55-8
ND
ug/L
20.0
2.8
1
02/11/1919:54
02/13/1912:50
55-18-5
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1912:50
62-75-9
ND
ug/L
10.0
2.2
1
02/11/1919:54
02/13/1912:50
924-16-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1912:50
621-64-7
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:50
86-30-6
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:50
10595-95-6
ND
ug/L
20.0
1.9
1
02/11/1919:54
02/13/1912:50
100-75-4
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1912:50
930-55-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1912:50
126-68-1
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1912:50
108-60-1
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:50
56-38-2
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:50
608-93-5
ND
ug/L
20.0
1.0
1
02/11/1919:54
02/13/1912:50
82-68-8
ND
ug/L
25.0
3.1
1
02/11/1919:54
02/13/1912:50
87-86-5
ND
ug/L
20.0
0.97
1
02/11/1919:54
02/13/1912:50
62-44-2
ND
ug/L
10.0
2.4
1
02/11/1919:54
02/13/1912:50
85-01-8
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1912:50
108-95-2
ND
ug/L
10.0
0.96
1
02/11/1919:54
02/13/1912:50
106-50-3
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:50
298-02-2
ND
ug/L
10.0
0.97
1
02/11/1919:54
02/13/1912:50
23950-58-5
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1912:50
129-00-0
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1912:50
94-59-7
ND
ug/L
10.0
1.7
1
02/11/1919:54
02/13/1912:50
95-94-3
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1912:50
58-90-2
ND
ug/L
20.0
1.2
1
02/11/1919:54
02/13/1912:50
297-97-2
ND
ug/L
10.0
1.6
1
02/11/1919:54
02/13/1912:50
95-53-4
ND
ug/L
10.0
2.3
1
02/11/1919:54
02/13/1912:50
95-95-4
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1912:50
88-06-2
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1912:50
99-35-4
54
%
13-130
1
02/11/1919:54
02/13/1912:50
4165-60-0
51
%
13-130
1
02/11/1919:54
02/13/1912:50
321-60-8
85
%
25-130
1
02/11/1919:54
02/13/1912:50
1718-51-0
22
%
10-130
1
02/11/1919:54
02/13/1912:50
13127-88-3
35
%
10-130
1
02/11/1919:54
02/13/1912:50
367-12-4
56
%
10-137
1
02/11/1919:54
02/13/1912:50
118-79-6
Analytical Method: EPA 8260E
ND ug/L 25.0 6.2 1
REPORT OF LABORATORY ANALYSIS
02/06/19 22:10 67-64-1
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetonitrile
ND
ug/L
50.0
30.4
1
02/06/19 22:10
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
02/06/19 22:10
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 22:10
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
02/06/19 22:10
107-05-1
Benzene
1.6
ug/L
1.0
0.15
1
02/06/19 22:10
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 22:10
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 22:10
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 22:10
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 22:10
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 22:10
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 22:10
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 22:10
56-23-5
Chlorobenzene
13.6
ug/L
1.0
0.23
1
02/06/19 22:10
108-90-7
Chloroethane
1.3
ug/L
1.0
0.49
1
02/06/19 22:10
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 22:10
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 22:10
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
02/06/19 22:10
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 22:10
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 22:10
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 22:10
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 22:10
74-95-3
1,2-Dichlorobenzene
0.95J
ug/L
1.0
0.29
1
02/06/19 22:10
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
02/06/19 22:10
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 22:10
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 22:10
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
02/06/19 22:10
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 22:10
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 22:10
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 22:10
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 22:10
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 22:10
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 22:10
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
02/06/19 22:10
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
02/06/19 22:10
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.21
1
02/06/19 22:10
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
02/06/19 22:10
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.31
1
02/06/19 22:10
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.26
1
02/06/19 22:10
100-41-4
Ethyl methacrylate
ND
ug/L
1.0
0.51
1
02/06/19 22:10
97-63-2
Hexachloro-1,3-butadiene
ND
ug/L
1.0
0.44
1
02/06/19 22:10
87-68-3
2-Hexanone
ND
ug/L
5.0
0.57
1
02/06/19 22:10
591-78-6
lodomethane
ND
ug/L
20.0
12.5
1
02/06/19 22:10
74-88-4
Isobutanol
ND
ug/L
100
66.4
1
02/06/19 22:10
78-83-1
Methacrylonitrile
ND
ug/L
10.0
1.9
1
02/06/19 22:10
126-98-7
Methylene Chloride
ND
ug/L
5.0
3.7
1
02/06/19 22:10
75-09-2
Methyl methacrylate
ND
ug/L
2.0
0.46
1
02/06/19 22:10
80-62-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 30 of 76

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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW2R Lab ID: 92416424007 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S213 Sulfide Water
Sulfide
4500CNE Cyanide, Total
Cyanide
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
5.0
4.5
1
02/06/19 22:10
108-10-1
4.2
ug/L
1.0
0.35
1
02/06/19 22:10
91-20-3
ND
ug/L
20.0
1.8
1
02/06/19 22:10
107-12-0
ND
ug/L
1.0
0.27
1
02/06/19 22:10
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 22:10
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 22:10
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 22:10
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 22:10
108-88-3
ND
ug/L
1.0
0.22
1
02/06/19 22:10
120-82-1
ND
ug/L
1.0
0.18
1
02/06/19 22:10
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 22:10
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 22:10
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 22:10
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 22:10
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 22:10
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 22:10
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 22:10
1330-20-7
100
%
70-130
1
02/06/19 22:10
460-00-4
105
%
70-130
1
02/06/19 22:10
17060-07-0
99
%
70-130
1
02/06/19 22:10
2037-26-5
Analytical Method: EPA 8260E Mod.
132
ug/L
5.0
4.8
2.5
02/15/1914:59
123-91-1
97
%
50-150
2.5
02/15/1914:59
17060-07-0
94
%
50-150
2.5
02/15/1914:59
2037-26-5
Analytical Method: SM 4500-S2D-2011
ND ug/L 100 50.0 1 02/08/1918:59 18496-25-8
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
ND ug/L 8.0 6.0 1 02/12/19 09:33 02/12/19 16:48 57-12-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 31 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8081 OC Pesticides RVE
Aldrin
alpha-BHC
beta-BHC
delta-BHC
gamma-BHC (Lindane)
Chlordane (Technical)
4,4'-DDD
4,4'-DDE
4,4'-DDT
Dieldrin
Endosulfan I
Endosulfan 11
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
Methoxychlor
Toxaphene
Surrogates
Tetrachloro-m-xylene (S)
Decachlorobiphenyl (S)
8082 GCS PCB RVE
PCB-1016 (Aroclor 1016)
PCB-1221 (Aroclor 1221)
PCB-1232 (Aroclor 1232)
PCB-1242 (Aroclor 1242)
PCB-1248 (Aroclor 1248)
PCB-1254 (Aroclor 1254)
PCB-1260 (Aroclor 1260)
Surrogates
Decachlorobiphenyl (S)
8151A Cl Acid Herbicide Waters
2,4-D
Dinoseb
2,4,5-T
2,4,5-TP (Silvex)
Surrogates
2,4-DCAA (S)
6010 MET ICP
Antimony
Arsenic
Barium
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8081 B Preparation Method: EPA 3510C
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
309-00-2
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
319-84-6
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
319-85-7
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
319-86-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
58-89-9
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:31
57-74-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
72-54-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
72-55-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
50-29-3
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
60-57-1
0.19
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
959-98-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
33213-65-9
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
1031-07-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
72-20-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
7421-93-4
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
76-44-8
ND
ug/L
0.050
0.050
1
02/06/1911:27
02/07/1917:31
1024-57-3
ND
ug/L
0.15
0.15
1
02/06/1911:27
02/07/1917:31
72-43-5
ND
ug/L
0.20
0.20
1
02/06/1911:27
02/07/1917:31
8001-35-2
84
%
10-130
1
02/06/1911:27
02/07/1917:31
877-09-8
84
%
10-130
1
02/06/1911:27
02/07/1917:31
2051-24-3
Analytical Method: EPA 8082A Preparation Method: EPA 3510C
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
12674-11-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
11104-28-2
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
11141-16-5
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
53469-21-9
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
12672-29-6
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
11097-69-1
ND
ug/L
0.50
0.50
1
02/06/19 15:28
02/07/19 21:46
11096-82-5
74
%
10-130
1
02/06/19 15:28
02/07/19 21:46
2051-24-3
Analytical Method: EPA8151A Preparation Method: EPA8151A
ND
ug/L
5.0
1.6
1
02/11/19 08:50
02/12/19 01:47
94-75-7
ND
ug/L
5.0
1.2
1
02/11/19 08:50
02/12/19 01:47
88-85-7
ND
ug/L
5.0
1.1
1
02/11/19 08:50
02/12/19 01:47
93-76-5
ND
ug/L
10.0
1.0
1
02/11/19 08:50
02/12/19 01:47
93-72-1
122
%.
10-155
1
02/11/19 08:50
02/12/19 01:47
19719-28-9
Analytical Method: EPA 601 OD Preparation Method:
EPA
3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:52
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:52
7440-38-2
44.3
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-39-3
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 32 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Beryllium
Cadmium
Chromium
Cobalt
Copper
Iron
Lead
Manganese
Nickel
Selenium
Silver
Tin
Vanadium
Zinc
1400111 �41 :4111 9 [y :2 61.9
Thallium
7470 Mercury
Mercury
8270 APP9 RV
Acenaphthene
Acenaphthylene
Acetophenone
2-Acetylaminofluorene
4-Aminobiphenyl
Anthracene
Benzo(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Benzyl alcohol
4-Bromophenylphenyl ether
Butylbenzylphthalate
4-ChIoro-3-methyl phenol
4-Chloroaniline
Chlorobenzilate
bis(2-Chloroethoxy)methane
bis(2-Chloroethyl) ether
2-Chloronaphthalene
2-Chlorophenol
4-Chlorophenylphenyl ether
Chrysene
Diallate
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:52
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:52
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-48-4
5.4
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-50-8
184
ug/L
50.0
25.0
1
02/06/19 03:58
02/07/19 18:52
7439-89-6
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7439-92-1
51.8
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7439-96-5
17.4
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:52
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-22-4
5.5
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-31-5
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:52
7440-62-2
5.OJ
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:52
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 14:00 7440-28-0
Analytical Method: EPA 7470A Preparation Method: EPA 7470A
ND ug/L 0.20 0.10 1 02/05/1914:45 02/06/1913:27 7439-97-6
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1913:16
83-32-9
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1913:16
208-96-8
ND
ug/L
10.0
4.3
1
02/11/1919:54
02/13/1913:16
98-86-2
ND
ug/L
20.0
0.84
1
02/11/1919:54
02/13/1913:16
53-96-3
ND
ug/L
10.0
0.92
1
02/11/1919:54
02/13/1913:16
92-67-1
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1913:16
120-12-7
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1913:16
56-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1913:16
50-32-8
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1913:16
205-99-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1913:16
191-24-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1913:16
207-08-9
ND
ug/L
20.0
7.0
1
02/11/1919:54
02/13/1913:16
100-51-6
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1913:16
101-55-3
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1913:16
85-68-7
ND
ug/L
20.0
4.6
1
02/11/1919:54
02/13/1913:16
59-50-7
ND
ug/L
20.0
6.8
1
02/11/1919:54
02/13/1913:16
106-47-8
ND
ug/L
10.0
0.72
1
02/11/1919:54
02/13/1913:16
510-15-6
ND
ug/L
10.0
3.0
1
02/11/1919:54
02/13/1913:16
111-91-1
ND
ug/L
10.0
3.1
1
02/11/1919:54
02/13/1913:16
111-44-4
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1913:16
91-58-7
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1913:16
95-57-8
ND
ug/L
10.0
2.9
1
02/11/1919:54
02/13/1913:16
7005-72-3
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1913:16
218-01-9
ND
ug/L
10.0
1.3
1
02/11/1919:54
02/13/1913:16
2303-16-4
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
L2
Page 33 of 76

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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV Analytical Method: EPA 8270D Preparation Method: EPA 3510C
Dibenz(a,h)anthracene
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 13:16
53-70-3
Dibenzofuran
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 13:16
132-64-9
3,3'-Dichlorobenzidine
ND
ug/L
20.0
2.8
1
02/11/19 19:54
02/13/19 13:16
91-94-1
2,4-Dichlorophenol
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 13:16
120-83-2
2,6-Dichlorophenol
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 13:16
87-65-0
Diethylphthalate
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 13:16
84-66-2
Dimethoate
ND
ug/L
10.0
0.92
1
02/11/19 19:54
02/13/19 13:16
60-51-5
P-Dimethylaminoazobenzene
ND
ug/L
5.0
0.35
1
02/11/19 19:54
02/13/19 13:16
60-11-7
7,12-Dimethylbenz(a)anthracene
ND
ug/L
10.0
0.77
1
02/11/19 19:54
02/13/19 13:16
57-97-6
3,3'-Dimethylbenzidine
ND
ug/L
10.0
2.1
1
02/11/19 19:54
02/13/19 13:16
119-93-7
2,4-Dimethylphenol
ND
ug/L
10.0
1.9
1
02/11/19 19:54
02/13/19 13:16
105-67-9
Dimethylphthalate
ND
ug/L
10.0
2.3
1
02/11/19 19:54
02/13/19 13:16
131-11-3
Di-n-butylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 13:16
84-74-2
4,6-Dinitro-2-methyl phenol
ND
ug/L
20.0
4.4
1
02/11/19 19:54
02/13/19 13:16
534-52-1
1,3-Dinitrobenzene
ND
ug/L
20.0
1.5
1
02/11/19 19:54
02/13/19 13:16
99-65-0
2,4-Dinitrophenol
ND
ug/L
50.0
10.1
1
02/11/19 19:54
02/13/19 13:16
51-28-5
2,4-Dinitrotoluene
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 13:16
121-14-2
2,6-Dinitrotoluene
ND
ug/L
10.0
2.9
1
02/11/19 19:54
02/13/19 13:16
606-20-2
Di-n-octylphthalate
ND
ug/L
10.0
1.2
1
02/11/19 19:54
02/13/19 13:16
117-84-0
Diphenylamine
ND
ug/L
10.0
2.0
1
02/11/19 19:54
02/13/19 13:16
122-39-4
Disulfoton
ND
ug/L
10.0
1.4
1
02/11/19 19:54
02/13/19 13:16
298-04-4
bis(2- Ethyl hexyl)phthalate
ND
ug/L
6.0
1.4
1
02/11/19 19:54
02/13/19 13:16
117-81-7
Ethyl methanesulfonate
ND
ug/L
20.0
1.8
1
02/11/19 19:54
02/13/19 13:16
62-50-0
Famphur
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 13:16
52-85-7
Fluoranthene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 13:16
206-44-0
Fluorene
ND
ug/L
10.0
3.0
1
02/11/19 19:54
02/13/19 13:16
86-73-7
Hexachloro-1,3-butadiene
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 13:16
87-68-3
Hexachlorobenzene
ND
ug/L
10.0
2.5
1
02/11/19 19:54
02/13/19 13:16
118-74-1
Hexachlorocyclopentadiene
ND
ug/L
10.0
3.4
1
02/11/19 19:54
02/13/19 13:16
77-47-4
Hexachloroethane
ND
ug/L
10.0
4.0
1
02/11/19 19:54
02/13/19 13:16
67-72-1
Hexachloropropene
ND
ug/L
10.0
1.6
1
02/11/19 19:54
02/13/19 13:16
1888-71-7
Indeno(1,2,3-cd)pyrene
ND
ug/L
10.0
1.7
1
02/11/19 19:54
02/13/19 13:16
193-39-5
Isodrin
ND
ug/L
20.0
2.0
1
02/11/19 19:54
02/13/19 13:16
465-73-6
Isophorone
ND
ug/L
10.0
2.7
1
02/11/19 19:54
02/13/19 13:16
78-59-1
Isosafrole
ND
ug/L
10.0
1.8
1
02/11/19 19:54
02/13/19 13:16
120-58-1
Kepone
ND
ug/L
10.0
3.1
1
02/11/19 19:54
02/13/19 13:16
143-50-0
Methapyrilene
ND
ug/L
50.0
2.7
1
02/11/19 19:54
02/13/19 13:16
91-80-5
3-Methylcholanthrene
ND
ug/L
10.0
0.82
1
02/11/19 19:54
02/13/19 13:16
56-49-5
Methyl methanesulfonate
ND
ug/L
5.0
1.3
1
02/11/19 19:54
02/13/19 13:16
66-27-3
2-Methylnaphthalene
ND
ug/L
10.0
2.8
1
02/11/19 19:54
02/13/19 13:16
91-57-6
Methyl parathion
ND
ug/L
10.0
1.1
1
02/11/19 19:54
02/13/19 13:16
298-00-0
2-Methylphenol(o-Cresol)
ND
ug/L
10.0
3.6
1
02/11/19 19:54
02/13/19 13:16
95-48-7
3&4-Methyl phenol (m&p Cresol)
ND
ug/L
10.0
2.4
1
02/11/19 19:54
02/13/19 13:16
15831-10-4
1-Naphthalenamine
ND
ug/L
5.0
0.96
1
02/11/19 19:54
02/13/19 13:16
134-32-7
2-Naphthalenamine
ND
ug/L
5.0
0.98
1
02/11/19 19:54
02/13/19 13:16
91-59-8
1,4-Naphthoquinone
ND
ug/L
5.0
1.8
1
02/11/19 19:54
02/13/19 13:16
130-15-4
REPORT OF LABORATORY ANALYSIS
L2
L2
L2
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 76

aceAnalytical
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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8270 APP9 RV
2-Nitroaniline
3-Nitroaniline
4-Nitroaniline
Nitrobenzene
2-Nitrophenol
4-Nitrophenol
5-Nitro-o-toluidine
N-Nitrosodiethylamine
N-Nitrosodimethylamine
N-Nitroso-di-n-butylamine
N-Nitroso-di-n-propylamine
N-Nitrosodiphenylamine
N-Nitrosomethylethylamine
N-Nitrosopiperidine
N-Nitrosopyrrolidine
O,O,O-Triethylphosphorothioate
2,2'-Oxybis(1-chloropropane)
Parathion (Ethyl parathion)
Pentachlorobenzene
Pentachloronitrobenzene
Pentachlorophenol
Phenacetin
Phenanthrene
Phenol
p-Phenylenediamine
Phorate
Pronamide
Pyrene
Safrole
1,2,4,5-Tetrachlorobenzene
2,3,4,6-Tetrachlorophenol
Thionazin
O-Toluidine
2,4,5-Trichlorophenol
2,4,6-Trichlorophenol
1,3,5-Trinitrobenzene
Surrogates
Nitrobenzene-d5 (S)
2-Fluorobiphenyl (S)
Terphenyl-d14 (S)
Phenol-d6 (S)
2-Fluorophenol (S)
2,4,6-Tribromophenol (S)
8260 MSV Low Level Landfill
Acetone
Analytical Method: EPA 8270D Preparation Method: EPA 3510C
ND
ug/L
50.0
5.5
1
02/11/1919:54
02/13/1913:16
88-74-4
ND
ug/L
50.0
5.0
1
02/11/1919:54
02/13/1913:16
99-09-2
ND
ug/L
20.0
3.6
1
02/11/1919:54
02/13/1913:16
100-01-6
ND
ug/L
10.0
3.4
1
02/11/1919:54
02/13/1913:16
98-95-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1913:16
88-75-5
ND
ug/L
50.0
7.8
1
02/11/1919:54
02/13/1913:16
100-02-7
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1913:16
99-55-8
ND
ug/L
20.0
2.8
1
02/11/1919:54
02/13/1913:16
55-18-5
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1913:16
62-75-9
ND
ug/L
10.0
2.2
1
02/11/1919:54
02/13/1913:16
924-16-3
ND
ug/L
10.0
2.6
1
02/11/1919:54
02/13/1913:16
621-64-7
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1913:16
86-30-6
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1913:16
10595-95-6
ND
ug/L
20.0
1.9
1
02/11/1919:54
02/13/1913:16
100-75-4
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1913:16
930-55-2
ND
ug/L
10.0
1.8
1
02/11/1919:54
02/13/1913:16
126-68-1
ND
ug/L
10.0
2.5
1
02/11/1919:54
02/13/1913:16
108-60-1
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1913:16
56-38-2
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1913:16
608-93-5
ND
ug/L
20.0
1.0
1
02/11/1919:54
02/13/1913:16
82-68-8
ND
ug/L
25.0
3.1
1
02/11/1919:54
02/13/1913:16
87-86-5
ND
ug/L
20.0
0.97
1
02/11/1919:54
02/13/1913:16
62-44-2
ND
ug/L
10.0
2.4
1
02/11/1919:54
02/13/1913:16
85-01-8
ND
ug/L
10.0
2.7
1
02/11/1919:54
02/13/1913:16
108-95-2
ND
ug/L
10.0
0.96
1
02/11/1919:54
02/13/1913:16
106-50-3
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1913:16
298-02-2
ND
ug/L
10.0
0.97
1
02/11/1919:54
02/13/1913:16
23950-58-5
ND
ug/L
10.0
1.2
1
02/11/1919:54
02/13/1913:16
129-00-0
ND
ug/L
10.0
1.5
1
02/11/1919:54
02/13/1913:16
94-59-7
ND
ug/L
10.0
1.7
1
02/11/1919:54
02/13/1913:16
95-94-3
ND
ug/L
10.0
2.0
1
02/11/1919:54
02/13/1913:16
58-90-2
ND
ug/L
20.0
1.2
1
02/11/1919:54
02/13/1913:16
297-97-2
ND
ug/L
10.0
1.6
1
02/11/1919:54
02/13/1913:16
95-53-4
ND
ug/L
10.0
2.3
1
02/11/1919:54
02/13/1913:16
95-95-4
ND
ug/L
10.0
2.8
1
02/11/1919:54
02/13/1913:16
88-06-2
ND
ug/L
10.0
1.1
1
02/11/1919:54
02/13/1913:16
99-35-4
46
%
13-130
1
02/11/1919:54
02/13/1913:16
4165-60-0
41
%
13-130
1
02/11/1919:54
02/13/1913:16
321-60-8
53
%
25-130
1
02/11/1919:54
02/13/1913:16
1718-51-0
21
%
10-130
1
02/11/1919:54
02/13/1913:16
13127-88-3
30
%
10-130
1
02/11/1919:54
02/13/1913:16
367-12-4
61
%
10-137
1
02/11/1919:54
02/13/1913:16
118-79-6
Analytical Method: EPA 8260E
ND ug/L 25.0 6.2 1
REPORT OF LABORATORY ANALYSIS
02/06/19 22:29 67-64-1
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 35 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetonitrile
ND
ug/L
50.0
30.4
1
02/06/19 22:29
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
02/06/19 22:29
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 22:29
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
02/06/19 22:29
107-05-1
Benzene
ND
ug/L
1.0
0.15
1
02/06/19 22:29
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 22:29
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 22:29
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 22:29
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 22:29
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 22:29
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 22:29
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 22:29
56-23-5
Chlorobenzene
0.35J
ug/L
1.0
0.23
1
02/06/19 22:29
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/06/19 22:29
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 22:29
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 22:29
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
02/06/19 22:29
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 22:29
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 22:29
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 22:29
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 22:29
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/06/19 22:29
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
02/06/19 22:29
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 22:29
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 22:29
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
02/06/19 22:29
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 22:29
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 22:29
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 22:29
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 22:29
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 22:29
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 22:29
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
02/06/19 22:29
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
02/06/19 22:29
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.21
1
02/06/19 22:29
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
02/06/19 22:29
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.31
1
02/06/19 22:29
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.26
1
02/06/19 22:29
100-41-4
Ethyl methacrylate
ND
ug/L
1.0
0.51
1
02/06/19 22:29
97-63-2
Hexachloro-1,3-butadiene
ND
ug/L
1.0
0.44
1
02/06/19 22:29
87-68-3
2-Hexanone
ND
ug/L
5.0
0.57
1
02/06/19 22:29
591-78-6
lodomethane
ND
ug/L
20.0
12.5
1
02/06/19 22:29
74-88-4
Isobutanol
ND
ug/L
100
66.4
1
02/06/19 22:29
78-83-1
Methacrylonitrile
ND
ug/L
10.0
1.9
1
02/06/19 22:29
126-98-7
Methylene Chloride
ND
ug/L
5.0
3.7
1
02/06/19 22:29
75-09-2
Methyl methacrylate
ND
ug/L
2.0
0.46
1
02/06/19 22:29
80-62-6
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 36 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: 3902-MW3R Lab ID: 92416424008 Collected: 02/04/19 13:02 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
4500S213 Sulfide Water
Sulfide
4500CNE Cyanide, Total
Cyanide
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
5.0
4.5
1
02/06/19 22:29
108-10-1
ND
ug/L
1.0
0.35
1
02/06/19 22:29
91-20-3
ND
ug/L
20.0
1.8
1
02/06/19 22:29
107-12-0
ND
ug/L
1.0
0.27
1
02/06/19 22:29
100-42-5
ND
ug/L
1.0
0.34
1
02/06/19 22:29
630-20-6
ND
ug/L
1.0
0.22
1
02/06/19 22:29
79-34-5
ND
ug/L
1.0
0.16
1
02/06/19 22:29
127-18-4
ND
ug/L
1.0
0.24
1
02/06/19 22:29
108-88-3
ND
ug/L
1.0
0.22
1
02/06/19 22:29
120-82-1
ND
ug/L
1.0
0.18
1
02/06/19 22:29
71-55-6
ND
ug/L
1.0
0.24
1
02/06/19 22:29
79-00-5
ND
ug/L
1.0
0.22
1
02/06/19 22:29
79-01-6
ND
ug/L
1.0
0.31
1
02/06/19 22:29
75-69-4
ND
ug/L
1.0
0.35
1
02/06/19 22:29
96-18-4
ND
ug/L
2.0
1.4
1
02/06/19 22:29
108-05-4
ND
ug/L
1.0
0.24
1
02/06/19 22:29
75-01-4
ND
ug/L
1.0
0.63
1
02/06/19 22:29
1330-20-7
100
%
70-130
1
02/06/19 22:29
460-00-4
104
%
70-130
1
02/06/19 22:29
17060-07-0
98
%
70-130
1
02/06/19 22:29
2037-26-5
Analytical Method: EPA 8260E Mod.
49.6
ug/L
2.0
1.9
1
02/14/1917:59
123-91-1
97
%
50-150
1
02/14/1917:59
17060-07-0
97
%
50-150
1
02/14/1917:59
2037-26-5
Analytical Method: SM 4500-S2D-2011
ND ug/L 100 50.0 1 02/08/1919:00 18496-25-8
Analytical Method: SM 4500-CN-E-2011 Preparation Method: SM 4500-CN-E-2011
ND ug/L 8.0 6.0 1 02/12/19 09:33 02/12/19 16:49 57-12-5
REPORT OF LABORATORY ANALYSIS
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without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: TRIP BLANK Lab ID: 92416424009 Collected: 02/04/19 15:30 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill Analytical Method: EPA 8260E
Acetone
ND
ug/L
25.0
6.2
1
02/06/19 19:05
67-64-1
Acetonitrile
ND
ug/L
50.0
30.4
1
02/06/19 19:05
75-05-8
Acrolein
ND
ug/L
10.0
2.7
1
02/06/19 19:05
107-02-8
Acrylonitrile
ND
ug/L
10.0
0.90
1
02/06/19 19:05
107-13-1
Allyl chloride
ND
ug/L
2.0
0.28
1
02/06/19 19:05
107-05-1
Benzene
ND
ug/L
1.0
0.15
1
02/06/19 19:05
71-43-2
Bromochloromethane
ND
ug/L
1.0
0.34
1
02/06/19 19:05
74-97-5
Bromodichloromethane
ND
ug/L
1.0
0.26
1
02/06/19 19:05
75-27-4
Bromoform
ND
ug/L
1.0
0.62
1
02/06/19 19:05
75-25-2
Bromomethane
ND
ug/L
2.0
0.62
1
02/06/19 19:05
74-83-9
2-Butanone (MEK)
ND
ug/L
5.0
3.3
1
02/06/19 19:05
78-93-3
Carbon disulfide
ND
ug/L
2.0
0.40
1
02/06/19 19:05
75-15-0
Carbon tetrachloride
ND
ug/L
1.0
0.22
1
02/06/19 19:05
56-23-5
Chlorobenzene
ND
ug/L
1.0
0.23
1
02/06/19 19:05
108-90-7
Chloroethane
ND
ug/L
1.0
0.49
1
02/06/19 19:05
75-00-3
Chloroform
ND
ug/L
5.0
2.3
1
02/06/19 19:05
67-66-3
Chloromethane
ND
ug/L
1.0
0.39
1
02/06/19 19:05
74-87-3
Chloroprene
ND
ug/L
5.0
1.7
1
02/06/19 19:05
126-99-8
1,2-Dibromo-3-chloropropane
ND
ug/L
2.0
0.26
1
02/06/19 19:05
96-12-8
Dibromochloromethane
ND
ug/L
1.0
0.41
1
02/06/19 19:05
124-48-1
1,2-Dibromoethane (EDB)
ND
ug/L
1.0
0.26
1
02/06/19 19:05
106-93-4
Dibromomethane
ND
ug/L
1.0
0.46
1
02/06/19 19:05
74-95-3
1,2-Dichlorobenzene
ND
ug/L
1.0
0.29
1
02/06/19 19:05
95-50-1
1,3-Dichlorobenzene
ND
ug/L
1.0
0.22
1
02/06/19 19:05
541-73-1
1,4-Dichlorobenzene
ND
ug/L
1.0
0.26
1
02/06/19 19:05
106-46-7
trans-1,4-Dichloro-2-butene
ND
ug/L
1.0
0.54
1
02/06/19 19:05
110-57-6
Dichlorodifluoromethane
ND
ug/L
1.0
0.23
1
02/06/19 19:05
75-71-8
1,1-Dichloroethane
ND
ug/L
1.0
0.27
1
02/06/19 19:05
75-34-3
1,2-Dichloroethane
ND
ug/L
1.0
0.34
1
02/06/19 19:05
107-06-2
1,1-Dichloroethene
ND
ug/L
1.0
0.24
1
02/06/19 19:05
75-35-4
cis-1,2-Dichloroethene
ND
ug/L
1.0
0.29
1
02/06/19 19:05
156-59-2
trans-1,2-Dichloroethene
ND
ug/L
1.0
0.25
1
02/06/19 19:05
156-60-5
1,2-Dichloropropane
ND
ug/L
1.0
0.19
1
02/06/19 19:05
78-87-5
1,3-Dichloropropane
ND
ug/L
1.0
0.16
1
02/06/19 19:05
142-28-9
2,2-Dichloropropane
ND
ug/L
1.0
0.27
1
02/06/19 19:05
594-20-7
1,1-Dichloropropene
ND
ug/L
1.0
0.21
1
02/06/19 19:05
563-58-6
cis-1,3-Dichloropropene
ND
ug/L
1.0
0.30
1
02/06/19 19:05
10061-01-5
trans- 1,3-Dichloropropene
ND
ug/L
1.0
0.31
1
02/06/19 19:05
10061-02-6
Ethylbenzene
ND
ug/L
1.0
0.26
1
02/06/19 19:05
100-41-4
Ethyl methacrylate
ND
ug/L
1.0
0.51
1
02/06/19 19:05
97-63-2
Hexachloro-1,3-butadiene
ND
ug/L
1.0
0.44
1
02/06/19 19:05
87-68-3
2-Hexanone
ND
ug/L
5.0
0.57
1
02/06/19 19:05
591-78-6
lodomethane
ND
ug/L
20.0
12.5
1
02/06/19 19:05
74-88-4
Isobutanol
ND
ug/L
100
66.4
1
02/06/19 19:05
78-83-1
Methacrylonitrile
ND
ug/L
10.0
1.9
1
02/06/19 19:05
126-98-7
Methylene Chloride
ND
ug/L
5.0
3.7
1
02/06/19 19:05
75-09-2
REPORT OF LABORATORY ANALYSIS
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
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ANALYTICAL RESULTS
Project: Butner Compliance
Pace Project No.: 92416424
Sample: TRIP BLANK Lab ID: 92416424009 Collected: 02/04/19 15:30 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
Methyl methacrylate
4-Methyl-2-pentanone (MIBK)
Naphthalene
Propionitrile
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,2,4-Trichlorobenzene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 06:14 PM
Analytical Method: EPA 8260E
ND
ug/L
2.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
20.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
97
%
70-130
104
%
70-130
98
%
70-130
Analytical Method: EPA 8260E Mod.
ND
ug/L
2.0
97
%
50-150
99
%
50-150
0.46
1
02/06/19 19:05
80-62-6
4.5
1
02/06/19 19:05
108-10-1
0.35
1
02/06/19 19:05
91-20-3
1.8
1
02/06/19 19:05
107-12-0
0.27
1
02/06/19 19:05
100-42-5
0.34
1
02/06/19 19:05
630-20-6
0.22
1
02/06/19 19:05
79-34-5
0.16
1
02/06/19 19:05
127-18-4
0.24
1
02/06/19 19:05
108-88-3
0.22
1
02/06/19 19:05
120-82-1
0.18
1
02/06/19 19:05
71-55-6
0.24
1
02/06/19 19:05
79-00-5
0.22
1
02/06/19 19:05
79-01-6
0.31
1
02/06/19 19:05
75-69-4
0.35
1
02/06/19 19:05
96-18-4
1.4
1
02/06/19 19:05
108-05-4
0.24
1
02/06/19 19:05
75-01-4
0.63
1
02/06/19 19:05
1330-20-7
1
02/06/19 19:05
460-00-4
1
02/06/19 19:05
17060-07-0
1
02/06/19 19:05
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/13/19 12:10 123-91-1
02/ 13/ 19 12:10 17060-07-0
02/13/1912:10 2037-26-5
Page 39 of 76

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QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456505
Analysis Method: EPA 7470A
QC Batch Method: EPA 7470A
Analysis Description: 7470 Mercury
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
METHOD BLANK: 2490562
Matrix: Water
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed Qualifiers
Mercury ug/L
ND 0.20 0.10 02/06/1912:28
LABORATORY CONTROL SAMPLE: 2490563
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Mercury ug/L
2.5 2.2 87
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490564 2490565
MS MSD
92416340001
Spike Spike MS MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec Limits RPD RPD Qual
Mercury ug/L ND
2.5 2.5 2.4 2.1
93 84 75-125 10 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 40 of 76

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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456556 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424005, 92416424006, 92416424007, 92416424008
METHOD BLANK: 2490699 Matrix: Water
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.9
02/07/1917:43
Arsenic
ug/L
ND
10.0
5.0
02/07/1917:43
Barium
ug/L
ND
5.0
2.5
02/07/1917:43
Beryllium
ug/L
ND
1.0
0.50
02/07/1917:43
Cadmium
ug/L
ND
1.0
0.50
02/07/1917:43
Chromium
ug/L
ND
5.0
2.5
02/07/1917:43
Cobalt
ug/L
ND
5.0
2.5
02/07/1917:43
Copper
ug/L
ND
5.0
2.5
02/07/1917:43
Iron
ug/L
ND
50.0
25.0
02/07/1917:43
Lead
ug/L
ND
5.0
2.5
02/07/1917:43
Manganese
ug/L
ND
5.0
2.5
02/07/1917:43
Nickel
ug/L
ND
5.0
2.5
02/07/1917:43
Selenium
ug/L
ND
10.0
5.0
02/07/1917:43
Silver
ug/L
ND
5.0
2.5
02/07/1917:43
Tin
ug/L
ND
5.0
2.5
02/07/1917:43
Vanadium
ug/L
ND
5.0
2.5
02/07/1917:43
Zinc
ug/L
ND
10.0
5.0
02/07/1917:43
LABORATORY CONTROL SAMPLE:
Parameter
2490700
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Antimony
ug/L
500
475
95
80-120
Arsenic
ug/L
500
439
88
80-120
Barium
ug/L
500
492
98
80-120
Beryllium
ug/L
500
494
99
80-120
Cadmium
ug/L
500
464
93
80-120
Chromium
ug/L
500
471
94
80-120
Cobalt
ug/L
500
462
92
80-120
Copper
ug/L
500
484
97
80-120
Iron
ug/L
5000
4770
95
80-120
Lead
ug/L
500
454
91
80-120
Manganese
ug/L
500
464
93
80-120
Nickel
ug/L
500
464
93
80-120
Selenium
ug/L
500
450
90
80-120
Silver
ug/L
250
248
99
80-120
Tin
ug/L
500
474
95
80-120
Vanadium
ug/L
500
475
95
80-120
Zinc
ug/L
500
446
89
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 41 of 76

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QUALITY CONTROL DATA
Project:
Pace Project No.:
Butner Compliance
92416424
MATRIX SPIKE &
MATRIX SPIKE DUPLICATE: 2490701
2490702
MS
MSD
92416496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
467
471
93
94
75-125
1
20
Arsenic
ug/L
ND
500
500
439
440
88
88
75-125
0
20
Barium
ug/L
14.8
500
500
501
494
97
96
75-125
1
20
Beryllium
ug/L
ND
500
500
487
481
97
96
75-125
1
20
Cadmium
ug/L
ND
500
500
464
465
93
93
75-125
0
20
Chromium
ug/L
ND
500
500
467
464
93
93
75-125
1
20
Cobalt
ug/L
ND
500
500
452
453
90
91
75-125
0
20
Copper
ug/L
0.010
500
500
485
481
95
94
75-125
1
20
mg/L
Iron
ug/L
265
5000
5000
4950
4910
94
93
75-125
1
20
Lead
ug/L
ND
500
500
449
449
90
90
75-125
0
20
Manganese
ug/L
7.7
500
500
462
463
91
91
75-125
0
20
Nickel
ug/L
ND
500
500
461
459
92
91
75-125
0
20
Selenium
ug/L
ND
500
500
471
479
94
96
75-125
2
20
Silver
ug/L
ND
250
250
246
246
98
98
75-125
0
20
Tin
ug/L
ND
500
500
460
460
92
92
75-125
0
20
Vanadium
ug/L
ND
500
500
463
465
93
93
75-125
0
20
Zinc
ug/L
0.013
500
500
458
459
89
89
75-125
0
20
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 42 of 76

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456560
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92416424001, 92416424002,
92416424003, 92416424005, 92416424006, 92416424007, 92416424008
METHOD BLANK: 2490711
Matrix: Water
Associated Lab Samples: 92416424001, 92416424002,
92416424003, 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units
Result Limit MDL Analyzed Qualifiers
Thallium ug/L
ND 0.10 0.060 02/06/1913:04
LABORATORY CONTROL SAMPLE: 2490712
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Thallium ug/L
10 10.4 104 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490713 2490714
MS MSD
92416422001
Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Thallium ug/L ND
10 10 10.4 10.4 104 104 75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 43 of 76

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Pace Analytical Services, LLC
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Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456738 Analysis Method: EPA 8260B
QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424004, 92416424005, 92416424006, 92416424007,
92416424008,92416424009
METHOD BLANK: 2491742 Matrix: Water
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424004, 92416424005, 92416424006, 92416424007,
92416424008,92416424009
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
02/06/19 18:28
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
02/06/19 18:28
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
02/06/19 18:28
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
02/06/19 18:28
1,1-Dichloroethane
ug/L
ND
1.0
0.27
02/06/19 18:28
1,1-Dichloroethene
ug/L
ND
1.0
0.24
02/06/19 18:28
1,1-Dichloropropene
ug/L
ND
1.0
0.21
02/06/19 18:28
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
02/06/19 18:28
1,2,4-Trichlorobenzene
ug/L
ND
1.0
0.22
02/06/19 18:28
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.26
02/06/19 18:28
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
02/06/19 18:28
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
02/06/19 18:28
1,2-Dichloroethane
ug/L
ND
1.0
0.34
02/06/19 18:28
1,2-Dichloropropane
ug/L
ND
1.0
0.19
02/06/19 18:28
1,3-Dichlorobenzene
ug/L
ND
1.0
0.22
02/06/19 18:28
1,3-Dichloropropane
ug/L
ND
1.0
0.16
02/06/19 18:28
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
02/06/19 18:28
2,2-Dichloropropane
ug/L
ND
1.0
0.27
02/06/19 18:28
2-Butanone (MEK)
ug/L
ND
5.0
3.3
02/06/19 18:28
2-Hexanone
ug/L
ND
5.0
0.57
02/06/19 18:28
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
02/06/19 18:28
Acetone
ug/L
ND
25.0
6.2
02/06/19 18:28
Acetonitrile
ug/L
ND
50.0
30.4
02/06/19 18:28
Acrolein
ug/L
ND
10.0
2.7
02/06/19 18:28
Acrylonitrile
ug/L
ND
10.0
0.90
02/06/19 18:28
Allyl chloride
ug/L
ND
2.0
0.28
02/06/19 18:28
Benzene
ug/L
ND
1.0
0.15
02/06/19 18:28
Bromochloromethane
ug/L
ND
1.0
0.34
02/06/19 18:28
Bromodichloromethane
ug/L
ND
1.0
0.26
02/06/19 18:28
Bromoform
ug/L
ND
1.0
0.62
02/06/19 18:28
Bromomethane
ug/L
ND
2.0
0.62
02/06/19 18:28
Carbon disulfide
ug/L
ND
2.0
0.40
02/06/19 18:28
Carbon tetrachloride
ug/L
ND
1.0
0.22
02/06/19 18:28
Chlorobenzene
ug/L
ND
1.0
0.23
02/06/19 18:28
Chloroethane
ug/L
ND
1.0
0.49
02/06/19 18:28
Chloroform
ug/L
ND
5.0
2.3
02/06/19 18:28
Chloromethane
ug/L
ND
1.0
0.39
02/06/19 18:28
Chloroprene
ug/L
ND
5.0
1.7
02/06/19 18:28
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
02/06/19 18:28
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
02/06/19 18:28
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 44 of 76

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
METHOD BLANK: 2491742 Matrix: Water
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424004, 92416424005, 92416424006, 92416424007,
92416424008,92416424009
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
Dibromochloromethane
ug/L
ND
1.0
0.41
02/06/19 18:28
Dibromomethane
ug/L
ND
1.0
0.46
02/06/19 18:28
Dichlorodifluoromethane
ug/L
ND
1.0
0.23
02/06/19 18:28
Ethyl methacrylate
ug/L
ND
1.0
0.51
02/06/19 18:28
Ethylbenzene
ug/L
ND
1.0
0.26
02/06/19 18:28
Hexachloro-1,3-butadiene
ug/L
ND
1.0
0.44
02/06/19 18:28
lodomethane
ug/L
ND
20.0
12.5
02/06/19 18:28
Isobutanol
ug/L
ND
100
66.4
02/06/19 18:28
Methacrylonitrile
ug/L
ND
10.0
1.9
02/06/19 18:28
Methyl methacrylate
ug/L
ND
2.0
0.46
02/06/19 18:28
Methylene Chloride
ug/L
ND
5.0
3.7
02/06/19 18:28
Naphthalene
ug/L
ND
1.0
0.35
02/06/19 18:28
Propionitrile
ug/L
ND
20.0
1.8
02/06/19 18:28
Styrene
ug/L
ND
1.0
0.27
02/06/19 18:28
Tetrachloroethene
ug/L
ND
1.0
0.16
02/06/19 18:28
Toluene
ug/L
ND
1.0
0.24
02/06/19 18:28
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
02/06/19 18:28
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
02/06/19 18:28
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
0.54
02/06/19 18:28
Trichloroethene
ug/L
ND
1.0
0.22
02/06/19 18:28
Trichlorofluoromethane
ug/L
ND
1.0
0.31
02/06/19 18:28
Vinyl acetate
ug/L
ND
2.0
1.4
02/06/19 18:28
Vinyl chloride
ug/L
ND
1.0
0.24
02/06/19 18:28
Xylene (Total)
ug/L
ND
1.0
0.63
02/06/19 18:28
1,2-Dichloroethane-d4 (S)
%
102
70-130
02/06/19 18:28
4-Bromofluorobenzene (S)
%
96
70-130
02/06/19 18:28
Toluene-d8 (S)
%
100
70-130
02/06/19 18:28
LABORATORY CONTROL SAMPLE:
2491743
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
50
48.2
96
70-130
1,1,1-Trichloroethane
ug/L
50
50.8
102
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.6
99
70-130
1,1,2-Trichloroethane
ug/L
50
50.1
100
70-130
1,1-Dichloroethane
ug/L
50
51.2
102
70-130
1,1-Dichloroethene
ug/L
50
54.2
108
70-130
1,1-Dichloropropene
ug/L
50
47.9
96
70-130
1,2,3-Trichloropropane
ug/L
50
47.9
96
70-130
1,2,4-Trichlorobenzene
ug/L
50
49.5
99
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.0
98
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.1
100
70-130
1,2-Dichlorobenzene
ug/L
50
51.2
102
70-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 45 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE:
Parameter
2491743
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,2-Dichloroethane
ug/L
50
50.5
101
70-130
1,2-Dichloropropane
ug/L
50
48.8
98
70-130
1,3-Dichlorobenzene
ug/L
50
49.6
99
70-130
1,3-Dichloropropane
ug/L
50
49.4
99
70-131
1,4-Dichlorobenzene
ug/L
50
50.4
101
70-130
2,2-Dichloropropane
ug/L
50
51.6
103
69-130
2-Butanone (MEK)
ug/L
100
111
111
64-135
2-Hexanone
ug/L
100
103
103
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
104
104
70-130
Acetone
ug/L
100
109
109
61-157
Acetonitrile
ug/L
500
544
109
62-130
Acrolein
ug/L
250
476
190
10-200
Acrylonitrile
ug/L
250
286
115
61-143
Allyl chloride
ug/L
50
53.1
106
70-130
Benzene
ug/L
50
48.8
98
70-130
Bromochloromethane
ug/L
50
59.1
118
70-130
Bromodichloromethane
ug/L
50
48.4
97
70-130
Bromoform
ug/L
50
41.8
84
70-130
Bromomethane
ug/L
50
47.6
95
38-130
Carbon disulfide
ug/L
50
53.5
107
68-130
Carbon tetrachloride
ug/L
50
48.9
98
70-130
Chlorobenzene
ug/L
50
48.1
96
70-130
Chloroethane
ug/L
50
46.3
93
37-142
Chloroform
ug/L
50
51.0
102
70-130
Chloromethane
ug/L
50
51.4
103
48-130
Chloroprene
ug/L
50
52.3
105
70-130
cis-1,2-Dichloroethene
ug/L
50
52.0
104
70-130
cis-1,3-Dichloropropene
ug/L
50
49.5
99
70-130
Dibromochloromethane
ug/L
50
49.0
98
70-130
Dibromomethane
ug/L
50
47.2
94
70-130
Dichlorodifluoromethane
ug/L
50
59.1
118
53-134
Ethyl methacrylate
ug/L
50
51.4
103
70-130
Ethylbenzene
ug/L
50
48.7
97
70-130
Hexachloro-1,3-butadiene
ug/L
50
47.3
95
68-132
lodomethane
ug/L
100
103
103
40-130
Isobutanol
ug/L
1000
1020
102
44-144
Methacrylonitrile
ug/L
500
536
107
66-130
Methyl methacrylate
ug/L
50
51.6
103
69-130
Methylene Chloride
ug/L
50
48.6
97
67-132
Naphthalene
ug/L
50
55.0
110
70-130
Propionitrile
ug/L
500
560
112
70-130
Styrene
ug/L
50
49.1
98
70-130
Tetrachloroethene
ug/L
50
45.0
90
69-130
Toluene
ug/L
50
47.8
96
70-130
trans-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
trans- 1,3-Dichloropropene
ug/L
50
50.0
100
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
49.8
100
35-189
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 46 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE:
2491743
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Trichloroethene
ug/L
50
48.7
97
70-130
Trichlorofluoromethane
ug/L
50
54.1
108
63-130
Vinyl acetate
ug/L
100
113
113
55-143
Vinyl chloride
ug/L
50
56.0
112
70-131
Xylene (Total)
ug/L
150
146
98
70-130
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8(S)
%
101
70-130
MATRIX SPIKE SAMPLE:
2491745
92416424002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.4
107
73-134
1,1,1-Trichloroethane
ug/L
ND
20
22.2
111
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
21.7
108
70-136
1,1,2-Trichloroethane
ug/L
ND
20
22.2
111
70-135
1,1-Dichloroethane
ug/L
ND
20
22.9
115
70-139
1,1-Dichloroethene
ug/L
ND
20
24.2
121
70-154
1,1-Dichloropropene
ug/L
ND
20
21.5
108
70-149
1,2,3-Trichloropropane
ug/L
ND
20
25.2
126
71-137
1,2,4-Trichlorobenzene
ug/L
ND
20
19.6
98
73-140
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20.3
101
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.7
109
70-137
1,2-Dichlorobenzene
ug/L
ND
20
21.6
108
70-133
1,2-Dichloroethane
ug/L
ND
20
21.5
107
70-137
1,2-Dichloropropane
ug/L
ND
20
22.4
112
70-140
1,3-Dichlorobenzene
ug/L
ND
20
21.5
108
70-135
1,3-Dichloropropane
ug/L
ND
20
21.9
110
70-143
1,4-Dichlorobenzene
ug/L
ND
20
21.4
107
70-133
2,2-Dichloropropane
ug/L
ND
20
19.1
95
61-148
2-Butanone (MEK)
ug/L
ND
40
51.0
128
60-139
2-Hexanone
ug/L
ND
40
44.1
110
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
45.3
113
65-135
Acetone
ug/L
ND
40
50.3
126
60-148
Acetonitrile
ug/L
ND
200
235
117
65-141
Acrolein
ug/L
ND
100
176
176
28-162 M1
Acrylonitrile
ug/L
ND
100
121
121
64-147
Allyl chloride
ug/L
ND
20
23.5
118
70-133
Benzene
ug/L
ND
20
22.8
114
70-151
Bromochloromethane
ug/L
ND
20
24.1
121
70-141
Bromodichloromethane
ug/L
ND
20
20.9
105
70-138
Bromoform
ug/L
ND
20
17.8
89
63-130
Bromomethane
ug/L
ND
20
17.5
88
15-152
Carbon disulfide
ug/L
ND
20
23.6
118
69-149
Carbon tetrachloride
ug/L
ND
20
21.9
109
70-143
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 47 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
MATRIX SPIKE SAMPLE:
Parameter
2491745
Units
92416424002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Chlorobenzene
ug/L
ND
20
21.6
108
70-138
Chloroethane
ug/L
ND
20
27.3
137
52-163
Chloroform
ug/L
ND
20
21.7
108
70-139
Chloromethane
ug/L
ND
20
22.5
112
41-139
Chloroprene
ug/L
ND
20
21.7
108
70-135
cis-1,2-Dichloroethene
ug/L
ND
20
22.5
112
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
21.3
106
70-137
Dibromochloromethane
ug/L
ND
20
21.0
105
70-134
Dibromomethane
ug/L
ND
20
20.2
101
70-138
Dichlorodifluoromethane
ug/L
ND
20
25.3
127
47-155
Ethyl methacrylate
ug/L
ND
20
22.2
111
70-132
Ethylbenzene
ug/L
ND
20
22.1
110
66-153
Hexachloro-1,3-butadiene
ug/L
ND
20
18.5
93
65-149
lodomethane
ug/L
ND
40
41.7
104
20-138
Isobutanol
ug/L
ND
400
432
108
41-152
Methacrylonitrile
ug/L
ND
200
236
118
67-134
Methyl methacrylate
ug/L
ND
20
22.5
112
70-130
Methylene Chloride
ug/L
ND
20
20.3
101
42-159
Naphthalene
ug/L
ND
20
22.6
113
61-148
Propionitrile
ug/L
ND
200
241
120
70-131
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
20.4
102
59-143
Toluene
ug/L
ND
20
22.1
110
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
23.1
115
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.7
104
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
16.7
84
47-135
Trichloroethene
ug/L
ND
20
22.3
111
70-147
Trichlorofluoromethane
ug/L
ND
20
24.7
124
70-148
Vinyl acetate
ug/L
ND
40
38.7
97
49-151
Vinyl chloride
ug/L
ND
20
25.5
128
70-156
Xylene (Total)
ug/L
ND
60
66.0
110
63-158
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8 (S)
%
102
70-130
SAMPLE DUPLICATE: 2491744
92416424001
Dup
Max
Parameter
Units
Result
Result RPD
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.36J
0.36J
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,1-Dichloropropene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 48 of 76

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
SAMPLE DUPLICATE: 2491744
Parameter
Units
92416424001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2,4-Trichlorobenzene
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,3-Dichlorobenzene
ug/L
ND
ND
30
1,3-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
2,2-Dichloropropane
ug/L
ND
ND
30
2-Butanone (MEK)
ug/L
ND
ND
30
2-Hexanone
ug/L
ND
ND
30
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
30
Acetone
ug/L
ND
ND
30
Acetonitrile
ug/L
ND
ND
30
Acrolein
ug/L
ND
ND
30
Acrylonitrile
ug/L
ND
ND
30
Allyl chloride
ug/L
ND
ND
30
Benzene
ug/L
ND
ND
30
Bromochloromethane
ug/L
ND
ND
30
Bromodichloromethane
ug/L
ND
ND
30
Bromoform
ug/L
ND
ND
30
Bromomethane
ug/L
ND
ND
30
Carbon disulfide
ug/L
ND
ND
30
Carbon tetrachloride
ug/L
ND
ND
30
Chlorobenzene
ug/L
1.3
1.3 5
30
Chloroethane
ug/L
0.79J
1.01
30
Chloroform
ug/L
ND
ND
30
Chloromethane
ug/L
ND
ND
30
Chloroprene
ug/L
ND
ND
30
cis-1,2-Dichloroethene
ug/L
ND
ND
30
cis-1,3-Dichloropropene
ug/L
ND
ND
30
Dibromochloromethane
ug/L
ND
ND
30
Dibromomethane
ug/L
ND
ND
30
Dichlorodifluoromethane
ug/L
ND
ND
30
Ethyl methacrylate
ug/L
ND
ND
30
Ethylbenzene
ug/L
ND
ND
30
Hexachloro-1,3-butadiene
ug/L
ND
ND
30
lodomethane
ug/L
ND
ND
30
Isobutanol
ug/L
ND
ND
30
Methacrylonitrile
ug/L
ND
ND
30
Methyl methacrylate
ug/L
ND
ND
30
Methylene Chloride
ug/L
ND
ND
30
Naphthalene
ug/L
ND
ND
30
Propionitrile
ug/L
ND
ND
30
Styrene
ug/L
ND
ND
30
Results presented on this page are in the units
indicated by the "Units" column except where an alternate unit is presented
to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 49 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
SAMPLE DUPLICATE: 2491744
Parameter
Units
92416424001
Result
Dup
Result
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
101
103
4-Bromofluorobenzene (S)
%
98
100
Toluene-d8(S)
%
100
101
Max
RPD RPD Qualifiers
2
1
2
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 50 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 457598 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92416424001, 92416424002, 92416424003, 92416424005, 92416424009
METHOD BLANK: 2495501
Matrix:
Water
Associated Lab Samples:
92416424001, 92416424002, 92416424003, 92416424005, 92416424009
Blank
Reporting
Parameter
Units
Result
Limit MDL
Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0 1.9
02/13/19 11:31
1,2-Dichloroethane-d4 (S)
%
94
50-150
02/13/19 11:31
Toluene-d8 (S)
%
98
50-150
02/13/19 11:31
LABORATORY CONTROL SAMPLE: 2495502
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 23.1 115 71-125
1,2-Dichloroethane-d4 (S) % 96 50-150
Toluene-d8(S) % 100 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2495503
2495504
MS
MSD
50215972001 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 22.0
21.7 110
109
50-150
1 30
1,2-Dichloroethane-d4 (S)
%
101
99
50-150
30
Toluene-d8 (S)
%
101
100
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 51 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 458172 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92416424004, 92416424006, 92416424008
METHOD BLANK: 2498108
Matrix:
Water
Associated Lab Samples:
92416424004, 92416424006, 92416424008
Blank
Reporting
Parameter
Units
Result
Limit
MDL Analyzed Qualifiers
1,4-Dioxane (p-Dioxane)
ug/L
ND
2.0
1.9 02/14/19 12:49
1,2-Dichloroethane-d4 (S)
%
92
50-150
02/14/19 12:49
Toluene-d8 (S)
%
95
50-150
02/14/19 12:49
LABORATORY CONTROL SAMPLE: 2498109
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 21.2 106 71-125
1,2-Dichloroethane-d4 (S) % 94 50-150
Toluene-d8 (S) % 98 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2498110
2498111
MS
MSD
92416941003 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 24.0
25.0 116
121
50-150
4 30
1,2-Dichloroethane-d4 (S)
%
92
97
50-150
30
Toluene-d8 (S)
%
96
100
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 52 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 458371 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92416424007
METHOD BLANK: 2498941
Associated Lab Samples: 92416424007
Parameter
Units
1,4-Dioxane (p-Dioxane)
ug/L
1,2-Dichloroethane-d4 (S)
%
Toluene-d8 (S)
%
Matrix: Water
Blank Reporting
Result Limit
ND 2.0
91 50-150
94 50-150
MDL Analyzed
1.9 02/15/19 11:26
02/15/19 11:26
02/15/19 11:26
Qualifiers
LABORATORY CONTROL SAMPLE: 2498942
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.2 101 71-125
1,2-Dichloroethane-d4 (S) % 94 50-150
Toluene-d8 (S) % 96 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2498943
2498944
MS
MSD
92416935003 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 21.0
20.4 105
102
50-150
3 30
1,2-Dichloroethane-d4 (S)
%
92
94
50-150
30
Toluene-d8 (S)
%
95
96
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 53 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456609
Analysis Method:
EPA 8081 B
QC Batch Method: EPA 3510C
Analysis Description:
8081 OC Pesticides Red Vol
Associated Lab Samples: 92416424005, 92416424006, 92416424007,
92416424008
METHOD BLANK: 2490854
Matrix: Water
Associated Lab Samples: 92416424005, 92416424006, 92416424007,
92416424008
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed
Qualifiers
4,4'-DDD
ug/L
ND
0.050
0.050
02/07/19 18:22
4,4'-DDE
ug/L
ND
0.050
0.050
02/07/19 18:22
4,4'-DDT
ug/L
ND
0.050
0.050
02/07/19 18:22
Aldrin
ug/L
ND
0.050
0.050
02/07/19 18:22
alpha-BHC
ug/L
ND
0.050
0.050
02/07/19 18:22
beta-BHC
ug/L
ND
0.050
0.050
02/07/19 18:22
Chlordane (Technical)
ug/L
ND
0.20
0.20
02/07/19 18:22
delta-BHC
ug/L
ND
0.050
0.050
02/07/19 18:22
Dieldrin
ug/L
ND
0.050
0.050
02/07/19 18:22
Endosulfan I
ug/L
ND
0.050
0.050
02/07/19 18:22
Endosulfan 11
ug/L
ND
0.050
0.050
02/07/19 18:22
Endosulfan sulfate
ug/L
ND
0.050
0.050
02/07/19 18:22
Endrin
ug/L
ND
0.050
0.050
02/07/19 18:22
Endrin aldehyde
ug/L
ND
0.050
0.050
02/07/19 18:22
gamma-BHC (Lindane)
ug/L
ND
0.050
0.050
02/07/19 18:22
Heptachlor
ug/L
ND
0.050
0.050
02/07/19 18:22
Heptachlor epoxide
ug/L
ND
0.050
0.050
02/07/19 18:22
Methoxychlor
ug/L
ND
0.15
0.15
02/07/19 18:22
Toxaphene
ug/L
ND
0.20
0.20
02/07/19 18:22
Decachlorobiphenyl (S)
%
58
10-130
02/07/19 18:22
Tetrachloro-m-xylene (S)
%
110
10-130
02/07/19 18:22
LABORATORY CONTROL SAMPLE & LCSD:
2490855
2491275
Spike
LCS
LCSD
LCS
LCSD
% Rec
Max
Parameter
Units
Conc.
Result
Result
% Rec % Rec
Limits RPD
RPD Qualifiers
4,4'-DDD
ug/L
0.25
0.25
0.28
99
111
49-130
12
30
4,4'-DDE
ug/L
0.25
0.23
0.27
92
108
56-130
16
30
4,4'-DDT
ug/L
0.25
0.24
0.27
95
109
45-130
14
30
Aldrin
ug/L
0.25
0.24
0.27
96
109
25-130
12
30
alpha-BHC
ug/L
0.25
0.25
0.27
101
107
53-130
6
30
beta-BHC
ug/L
0.25
0.26
0.28
103
113
46-130
9
30
delta-BHC
ug/L
0.25
0.25
0.29
100
114
54-130
14
30
Dieldrin
ug/L
0.25
0.24
0.28
97
113
54-130
15
30
Endosulfan I
ug/L
0.25
0.25
0.28
98
114
43-130
15
30
Endosulfan II
ug/L
0.25
0.26
0.29
104
116
64-130
10
30
Endosulfan sulfate
ug/L
0.25
0.25
0.30
100
119
66-130
18
30
Endrin
ug/L
0.25
0.25
0.29
101
116
56-130
15
30
Endrin aldehyde
ug/L
0.25
0.23
0.26
92
106
59-130
14
30
gamma-BHC (Lindane)
ug/L
0.25
0.25
0.28
101
112
57-130
10
30
Heptachlor
ug/L
0.25
0.25
0.28
98
112
37-130
13
30
Results presented on this page are in the units indicated by the "Units"
column except where an alternate unit is
presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 54 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE & LCSD:
2490855
2491275
Spike
LCS LCSD
LCS
LCSD
% Rec Max
Parameter
Units
Conc.
Result Result
% Rec
% Rec
Limits RPD RPD Qualifiers
Heptachlor epoxide
ug/L
0.25
0.24 0.27
96
110
56-130 13 30
Methoxychlor
ug/L
0.75
0.73 0.86
97
115
46-130 16 30
Decachlorobiphenyl (S)
%
55
50
10-130
Tetrachloro-m-xylene (S)
%
105
85
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 55 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 456686 Analysis Method: EPA 8082A
QC Batch Method: EPA 3510C Analysis Description: 8082 GCS PCB
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
METHOD BLANK: 2491382
Matrix:
Water
Associated Lab Samples:
92416424005, 92416424006, 92416424007, 92416424008
Blank
Reporting
Parameter
Units
Result
Limit
MDL
Analyzed Qualifiers
PCB-1016 (Aroclor 1016)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1221 (Aroclor 1221)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1232 (Aroclor 1232)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1242 (Aroclor 1242)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1248 (Aroclor 1248)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1254 (Aroclor 1254)
ug/L
ND
0.50
0.50
02/07/19 22:50
PCB-1260 (Aroclor 1260)
ug/L
ND
0.50
0.50
02/07/19 22:50
Decachlorobiphenyl (S)
%
57
10-130
02/07/19 22:50
LABORATORY CONTROL SAMPLE & LCSD:
2491383
2491418
Spike
LCS LCSD LCS
LCSD
% Rec Max
Parameter
Units Conc.
Result Result % Rec
% Rec
Limits RPD RPD Qualifiers
PCB-1016 (Aroclor 1016)
ug/L 5
6.0 6.1 119
123
41-130 3 30
PCB-1260 (Aroclor 1260)
ug/L 5
4.1 3.9 83
77
42-130 7 30
Decachlorobiphenyl (S)
%
47
63
10-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 56 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 22144
Analysis Method: EPA 8151A
QC Batch Method: EPA8151A
Analysis Description: 8151AGCS Herbicides
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
METHOD BLANK: 99841
Matrix: Water
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
Blank Reporting
Parameter
Units
Result Limit
MDL
Analyzed
Qualifiers
2,4,5-T
ug/L
ND 5.0
1.1 02/11/19 22:54
2,4,5-TP (Silvex)
ug/L
ND 10.0
1.0 02/11/19 22:54
2,4-D
ug/L
ND 5.0
1.6 02/11/19 22:54
Dinoseb
ug/L
ND 5.0
1.2 02/11/19 22:54
2,4-DCAA (S)
%.
133 10-155
02/11/19 22:54
LABORATORY CONTROL SAMPLE: 99842
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits Qualifiers
2,4,5-T
ug/L
10 8.6
86
31-150
2,4,5-TP (Silvex)
ug/L
10 8.6J
86
35-138
2,4-D
ug/L
10 9.0
90
29-145
Dinoseb
ug/L
10 5.2
52
10-182
2,4-DCAA (S)
%.
116
10-155
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 99843
99844
MS MSD
35445988006
Spike Spike MS
MSD
MS MSD
% Rec
Max
Parameter Units
Result
Conc. Conc. Result
Result
% Rec % Rec
Limits
RPD RPD Qual
2,4,5-T ug/L
1 A U
10 10 11.2
11.7
112 117
10-158
4 48
2,4,5-TP (Silvex) ug/L
1.0U
10 10 11.4
11.9
114 119
10-156
4 46
2,4-D ug/L
1.6U
10 10 11.9
12.4
119 124
10-156
4 49
Dinoseb ug/L
1.2U
10 10 9.7
10.1
97 101
10-174
5 56
2,4-DCAA (S) %.
137 138
10-155
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 57 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 457539 Analysis Method: EPA 8270D
QC Batch Method: EPA 3510C Analysis Description: 8270 WaterAPP9 RV MSSV
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
METHOD BLANK: 2495381 Matrix: Water
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
1,2,4,5-Tetrachlorobenzene
ug/L
ND
10.0
1.7
02/13/19 11:09
1,3,5-Trinitrobenzene
ug/L
ND
10.0
1.1
02/13/19 11:09
1,3-Dinitrobenzene
ug/L
ND
20.0
1.5
02/13/19 11:09
1,4-Naphthoquinone
ug/L
ND
5.0
1.8
02/13/19 11:09
1-Naphthalenamine
ug/L
ND
5.0
0.96
02/13/19 11:09
2,2'-Oxybis(1-chloropropane)
ug/L
ND
10.0
2.5
02/13/19 11:09
2,3,4,6-Tetrachlorophenol
ug/L
ND
10.0
2.0
02/13/19 11:09
2,4,5-Trichlorophenol
ug/L
ND
10.0
2.3
02/13/19 11:09
2,4,6-Trichlorophenol
ug/L
ND
10.0
2.8
02/13/19 11:09
2,4-Dichlorophenol
ug/L
ND
10.0
2.7
02/13/19 11:09
2,4-Dimethylphenol
ug/L
ND
10.0
1.9
02/13/19 11:09
2,4-Dinitrophenol
ug/L
ND
50.0
10.1
02/13/19 11:09
2,4-Dinitrotoluene
ug/L
ND
10.0
2.4
02/13/19 11:09
2,6-Dichlorophenol
ug/L
ND
10.0
1.8
02/13/19 11:09
2,6-Dinitrotoluene
ug/L
ND
10.0
2.9
02/13/19 11:09
2-Acetylaminofluorene
ug/L
ND
20.0
0.84
02/13/19 11:09
2-Chloronaphthalene
ug/L
ND
10.0
2.9
02/13/19 11:09
2-Chlorophenol
ug/L
ND
10.0
2.9
02/13/19 11:09
2-Methylnaphthalene
ug/L
ND
10.0
2.8
02/13/19 11:09
2-Methylphenol(o-Cresol)
ug/L
ND
10.0
3.6
02/13/19 11:09
2-Naphthalenamine
ug/L
ND
5.0
0.98
02/13/19 11:09
2-Nitroaniline
ug/L
ND
50.0
5.5
02/13/19 11:09
2-Nitrophenol
ug/L
ND
10.0
2.6
02/13/19 11:09
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
10.0
2.4
02/13/19 11:09
3,3'-Dichlorobenzidine
ug/L
ND
20.0
2.8
02/13/19 11:09
3,3'-Dimethylbenzidine
ug/L
ND
10.0
2.1
02/13/19 11:09
3-Methylcholanthrene
ug/L
ND
10.0
0.82
02/13/19 11:09
3-Nitroaniline
ug/L
ND
50.0
5.0
02/13/19 11:09
4,6-Dinitro-2-methyl phenol
ug/L
ND
20.0
4.4
02/13/19 11:09
4-Aminobiphenyl
ug/L
ND
10.0
0.92
02/13/19 11:09
4-Bromophenylphenyl ether
ug/L
ND
10.0
2.7
02/13/19 11:09
4-ChIoro-3-methyl phenol
ug/L
ND
20.0
4.6
02/13/19 11:09
4-Chloroaniline
ug/L
ND
20.0
6.8
02/13/19 11:09
4-Chlorophenylphenyl ether
ug/L
ND
10.0
2.9
02/13/19 11:09
4-Nitroaniline
ug/L
ND
20.0
3.6
02/13/19 11:09
4-Nitrophenol
ug/L
ND
50.0
7.8
02/13/19 11:09
5-Nitro-o-toluidine
ug/L
ND
10.0
1.2
02/13/19 11:09
7,12-Dimethylbenz(a)anthracene
ug/L
ND
10.0
0.77
02/13/19 11:09
Acenaphthene
ug/L
ND
10.0
3.4
02/13/19 11:09
Acenaphthylene
ug/L
ND
10.0
3.0
02/13/19 11:09
Acetophenone
ug/L
ND
10.0
4.3
02/13/19 11:09
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 58 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
METHOD BLANK: 2495381 Matrix: Water
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed
Anthracene
ug/L
ND
10.0
2.0
02/13/19 11:09
Benzo(a)anthracene
ug/L
ND
10.0
1.3
02/13/19 11:09
Benzo(a)pyrene
ug/L
ND
10.0
1.3
02/13/19 11:09
Benzo(b)fluoranthene
ug/L
ND
10.0
1.5
02/13/19 11:09
Benzo(g,h,i)perylene
ug/L
ND
10.0
1.8
02/13/19 11:09
Benzo(k)fluoranthene
ug/L
ND
10.0
1.8
02/13/19 11:09
Benzyl alcohol
ug/L
ND
20.0
7.0
02/13/19 11:09
bis(2-Chloroethoxy)methane
ug/L
ND
10.0
3.0
02/13/19 11:09
bis(2-Chloroethyl) ether
ug/L
ND
10.0
3.1
02/13/19 11:09
bis(2-Ethylhexyl)phthalate
ug/L
ND
6.0
1.4
02/13/19 11:09
Butylbenzylphthalate
ug/L
ND
10.0
1.3
02/13/19 11:09
Chlorobenzilate
ug/L
ND
10.0
0.72
02/13/19 11:09
Chrysene
ug/L
ND
10.0
1.2
02/13/19 11:09
Di-n-butylphthalate
ug/L
ND
10.0
1.2
02/13/19 11:09
Di-n-octylphthalate
ug/L
ND
10.0
1.2
02/13/19 11:09
Diallate
ug/L
ND
10.0
1.3
02/13/19 11:09
Dibenz(a,h)anthracene
ug/L
ND
10.0
1.9
02/13/19 11:09
Dibenzofuran
ug/L
ND
10.0
3.4
02/13/19 11:09
Diethylphthalate
ug/L
ND
10.0
2.0
02/13/19 11:09
Dimethoate
ug/L
ND
10.0
0.92
02/13/19 11:09
Dimethylphthalate
ug/L
ND
10.0
2.3
02/13/19 11:09
Diphenylamine
ug/L
ND
10.0
2.0
02/13/19 11:09
Disulfoton
ug/L
ND
10.0
1.4
02/13/19 11:09
Ethyl methanesulfonate
ug/L
ND
20.0
1.8
02/13/19 11:09
Famphur
ug/L
ND
10.0
1.7
02/13/19 11:09
Fluoranthene
ug/L
ND
10.0
1.7
02/13/19 11:09
Fluorene
ug/L
ND
10.0
3.0
02/13/19 11:09
Hexachloro-1,3-butadiene
ug/L
ND
10.0
3.1
02/13/19 11:09
Hexachlorobenzene
ug/L
ND
10.0
2.5
02/13/19 11:09
Hexachlorocyclopentadiene
ug/L
ND
10.0
3.4
02/13/19 11:09
Hexachloroethane
ug/L
ND
10.0
4.0
02/13/19 11:09
Hexachloropropene
ug/L
ND
10.0
1.6
02/13/19 11:09
Indeno(1,2,3-cd)pyrene
ug/L
ND
10.0
1.7
02/13/19 11:09
Isodrin
ug/L
ND
20.0
2.0
02/13/19 11:09
Isophorone
ug/L
ND
10.0
2.7
02/13/19 11:09
Isosafrole
ug/L
ND
10.0
1.8
02/13/19 11:09
Kepone
ug/L
ND
10.0
3.1
02/13/19 11:09
Methapyrilene
ug/L
ND
50.0
2.7
02/13/19 11:09
Methyl methanesulfonate
ug/L
ND
5.0
1.3
02/13/19 11:09
Methyl parathion
ug/L
ND
10.0
1.1
02/13/19 11:09
N-Nitroso-di-n-butylamine
ug/L
ND
10.0
2.2
02/13/19 11:09
N-Nitroso-di-n-propylamine
ug/L
ND
10.0
2.6
02/13/19 11:09
N-Nitrosodiethylamine
ug/L
ND
20.0
2.8
02/13/19 11:09
N-Nitrosodimethylamine
ug/L
ND
10.0
2.8
02/13/19 11:09
N-Nitrosodiphenylamine
ug/L
ND
10.0
2.0
02/13/19 11:09
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 59 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
METHOD BLANK: 2495381 Matrix: Water
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units Result Limit
MDL
Analyzed Qualifiers
N-Nitrosomethylethylamine
ug/L
ND
10.0
1.8
02/13/19 11:09
N-Nitrosopiperidine
ug/L
ND
20.0
1.9
02/13/19 11:09
N-Nitrosopyrrolidine
ug/L
ND
10.0
2.5
02/13/19 11:09
Nitrobenzene
ug/L
ND
10.0
3.4
02/13/19 11:09
O,O,O-Triethylphosphorothioate
ug/L
ND
10.0
1.8
02/13/19 11:09
O-Toluidine
ug/L
ND
10.0
1.6
02/13/19 11:09
P-Dimethylaminoazobenzene
ug/L
ND
5.0
0.35
02/13/19 11:09
p-Phenylenediamine
ug/L
ND
10.0
0.96
02/13/19 11:09
Parathion (Ethyl parathion)
ug/L
ND
10.0
1.1
02/13/19 11:09
Pentachlorobenzene
ug/L
ND
10.0
2.0
02/13/19 11:09
Pentachloronitrobenzene
ug/L
ND
20.0
1.0
02/13/19 11:09
Pentachlorophenol
ug/L
ND
25.0
3.1
02/13/19 11:09
Phenacetin
ug/L
ND
20.0
0.97
02/13/19 11:09
Phenanthrene
ug/L
ND
10.0
2.4
02/13/19 11:09
Phenol
ug/L
ND
10.0
2.7
02/13/19 11:09
Phorate
ug/L
ND
10.0
1.1
02/13/19 11:09
Pronamide
ug/L
ND
10.0
0.97
02/13/19 11:09
Pyrene
ug/L
ND
10.0
1.2
02/13/19 11:09
Safrole
ug/L
ND
10.0
1.5
02/13/19 11:09
Thionazin
ug/L
ND
20.0
1.2
02/13/19 11:09
2,4,6-Tribromophenol (S)
%
60
10-137
02/13/19 11:09
2-Fluorobiphenyl (S)
%
58
13-130
02/13/19 11:09
2-Fluorophenol (S)
%
41
10-130
02/13/19 11:09
Nitrobenzene-d5 (S)
%
62
13-130
02/13/19 11:09
Phenol-d6 (S)
%
27
10-130
02/13/19 11:09
Terphenyl-d14 (S)
%
84
25-130
02/13/19 11:09
LABORATORY CONTROL SAMPLE:
Parameter
2495382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
50
23.0
46
10-130
1,3,5-Trinitrobenzene
ug/L
50
58.0
116
50-130
1,3-Dinitrobenzene
ug/L
50
32.6
65
30-130
1,4-Naphthoquinone
ug/L
50
26.3
53
30-130
1-Naphthalenamine
ug/L
50
11.4
23
30-130 L2
2,2'-Oxybis(1-chloropropane)
ug/L
50
25.8
52
20-130
2,3,4,6-Tetrachlorophenol
ug/L
50
54.9
110
40-200
2,4,5-Trichlorophenol
ug/L
50
24.8
50
40-130
2,4,6-Trichlorophenol
ug/L
50
25.7
51
40-130
2,4-Dichlorophenol
ug/L
50
25.9
52
31-130
2,4-Dimethylphenol
ug/L
50
24.6
49
30-130
2,4-Dinitrophenol
ug/L
250
155
62
30-130
2,4-Dinitrotoluene
ug/L
50
31.3
63
49-130
2,6-Dichlorophenol
ug/L
50
32.0
64
50-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 60 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE:
Parameter
2495382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
2,6-Dinitrotoluene
ug/L
50
30.4
61
50-130
2-Acetylaminofluorene
ug/L
50
32.2
64
70-150 L2
2-Chloronaphthalene
ug/L
50
30.4
61
30-130
2-Chlorophenol
ug/L
50
25.8
52
30-130
2-Methylnaphthalene
ug/L
50
24.2
48
30-130
2-Methylphenol(o-Cresol)
ug/L
50
25.1
50
30-130
2-Naphthalenamine
ug/L
50
20.8
42
30-130
2-Nitroaniline
ug/L
100
57.4
57
40-130
2-Nitrophenol
ug/L
50
26.1
52
20-130
3&4-Methyl phenol (m&p Cresol)
ug/L
50
19.8
40
20-130
3,3'-Dichlorobenzidine
ug/L
100
59.7
60
10-150
3,3'-Dimethylbenzidine
ug/L
100
ND
1
10-150 L2
3-Methylcholanthrene
ug/L
50
51.4
103
40-130
3-Nitroaniline
ug/L
100
61.4
61
40-130
4,6-Dinitro-2-methyl phenol
ug/L
100
69.1
69
40-130
4-Aminobiphenyl
ug/L
50
13.6
27
20-130
4-Bromophenylphenyl ether
ug/L
50
27.2
54
30-130
4-Chloro-3-methylphenol
ug/L
100
49.3
49
30-130
4-Chloroaniline
ug/L
100
52.2
52
20-130
4-Chlorophenylphenyl ether
ug/L
50
24.7
49
20-130
4-Nitroaniline
ug/L
100
70.0
70
40-130
4-Nitrophenol
ug/L
250
87.4
35
10-130
5-Nitro-o-toluidine
ug/L
50
30.5
61
50-150
7,12-Dimethylbenz(a)anthracene
ug/L
50
31.7
63
50-130
Acenaphthene
ug/L
50
25.8
52
30-130
Acenaphthylene
ug/L
50
28.4
57
30-130
Acetophenone
ug/L
50
27.7
55
20-130
Anthracene
ug/L
50
32.2
64
50-130
Benzo(a)anthracene
ug/L
50
35.4
71
50-130
Benzo(a)pyrene
ug/L
50
34.8
70
50-130
Benzo(b)fluoranthene
ug/L
50
36.8
74
50-130
Benzo(g,h,i)perylene
ug/L
50
31.8
64
50-130
Benzo(k)fluoranthene
ug/L
50
36.2
72
50-130
Benzyl alcohol
ug/L
100
49.6
50
20-130
bis(2-Chloroethoxy)methane
ug/L
50
26.5
53
30-130
bis(2-Chloroethyl) ether
ug/L
50
27.1
54
30-130
bis(2-Ethylhexyl)phthalate
ug/L
50
38.1
76
50-130
Butylbenzylphthalate
ug/L
50
37.8
76
50-150
Chlorobenzilate
ug/L
50
40.6
81
50-130
Chrysene
ug/L
50
34.5
69
50-130
Di-n-butylphthalate
ug/L
50
35.5
71
50-130
Di-n-octylphthalate
ug/L
50
38.5
77
50-130
Diallate
ug/L
50
37.6
75
50-130
Dibenz(a,h)anthracene
ug/L
50
32.9
66
40-130
Dibenzofuran
ug/L
50
24.2
48
40-130
Diethylphthalate
ug/L
50
34.3
69
40-130
Dimethoate
ug/L
50
44.5
89
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 61 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE:
Parameter
2495382
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits Qualifiers
Dimethylphthalate
ug/L
50
29.3
59
40-130
Diphenylamine
ug/L
50
30.8
62
30-130
Disulfoton
ug/L
50
37.1
74
40-150
Ethyl methanesulfonate
ug/L
50
40.6
81
40-130
Famphur
ug/L
100
76.4
76
30-150
Fluoranthene
ug/L
50
33.4
67
30-130
Fluorene
ug/L
50
27.0
54
20-130
Hexachloro-1,3-butadiene
ug/L
50
17.8
36
10-130
Hexachlorobenzene
ug/L
50
28.6
57
30-130
Hexachlorocyclopentadiene
ug/L
50
18.5
37
10-150
Hexachloroethane
ug/L
50
18.6
37
10-130
Hexachloropropene
ug/L
50
18.1
36
10-150
Indeno(1,2,3-cd)pyrene
ug/L
50
33.0
66
40-130
Isodrin
ug/L
50
33.0
66
40-130
Isophorone
ug/L
50
27.6
55
30-130
Isosafrole
ug/L
50
22.9
46
40-130
Kepone
ug/L
100
63.9
64
10-130
Methapyrilene
ug/L
50
ND
1
10-150 L2
Methyl methanesulfonate
ug/L
50
36.1
72
20-130
Methyl parathion
ug/L
50
43.4
87
50-130
N-Nitroso-di-n-butylamine
ug/L
50
23.4
47
30-130
N-Nitroso-di-n-propylamine
ug/L
50
28.6
57
30-130
N-Nitrosodiethylamine
ug/L
50
28.0
56
40-130
N-Nitrosodimethylamine
ug/L
50
21.0
42
10-130
N-Nitrosodiphenylamine
ug/L
50
30.8
62
30-130
N-Nitrosomethylethylamine
ug/L
50
29.2
58
30-130
N-Nitrosopiperidine
ug/L
50
25.8
52
30-130
N-Nitrosopyrrolidine
ug/L
50
28.4
57
30-130
Nitrobenzene
ug/L
50
27.6
55
20-130
O,O,O-Triethylphosphorothioate
ug/L
50
27.9
56
40-130
O-Toluidine
ug/L
50
24.3
49
20-130
P-Dimethylaminoazobenzene
ug/L
50
17.0
34
10-130
p-Phenylenediamine
ug/L
50
42.3
85
70-140
Parathion (Ethyl parathion)
ug/L
50
42.1
84
50-150
Pentachlorobenzene
ug/L
50
23.5
47
30-150
Pentachloronitrobenzene
ug/L
50
36.7
73
60-130
Pentachlorophenol
ug/L
100
60.6
61
10-140
Phenacetin
ug/L
50
42.3
85
60-130
Phenanthrene
ug/L
50
31.5
63
50-130
Phenol
ug/L
50
13.6
27
10-130
Phorate
ug/L
50
41.3
83
50-130
Pronamide
ug/L
50
40.0
80
70-130
Pyrene
ug/L
50
36.0
72
50-130
Safrole
ug/L
50
26.2
52
30-130
Thionazin
ug/L
50
35.0
70
60-130
2,4,6-Tribromophenol (S)
%
62
10-137
2-Fluorobiphenyl (S)
%
49
13-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 62 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
LABORATORY CONTROL SAMPLE:
2495382
Spike LCS
LCS
% Rec
Parameter
Units
Conc. Result
% Rec
Limits
Qualifiers
2-Fluorophenol (S)
%
38
10-130
Nitrobenzene-d5 (S)
%
55
13-130
Phenol-d6 (S)
%
26
10-130
Terphenyl-d14 (S)
%
70
25-130
MATRIX SPIKE SAMPLE:
2495383
92416941007
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
ND
50
20.7
41
10-130
1,3,5-Trinitrobenzene
ug/L
ND
50
69.2
138
50-130 M1
1,3-Dinitrobenzene
ug/L
ND
50
33.7
67
30-130
1,4-Naphthoquinone
ug/L
ND
50
25.7
51
30-130
1-Naphthalenamine
ug/L
ND
50
16.7
33
30-130
2,2'-Oxybis(1-chloropropane)
ug/L
ND
50
24.4
49
20-130
2,3,4,6-Tetrachlorophenol
ug/L
ND
50
58.4
117
40-200
2,4,5-Trichlorophenol
ug/L
ND
50
24.6
49
40-130
2,4,6-Trichlorophenol
ug/L
ND
50
24.9
50
40-130
2,4-Dichlorophenol
ug/L
ND
50
24.1
48
31-130
2,4-Dimethylphenol
ug/L
ND
50
23.3
47
30-130
2,4-Dinitrophenol
ug/L
ND
250
157
63
30-130
2,4-Dinitrotoluene
ug/L
ND
50
34.0
68
49-130
2,6-Dichlorophenol
ug/L
ND
50
30.3
61
50-130
2,6-Dinitrotoluene
ug/L
ND
50
30.8
62
50-130
2-Acetylaminofluorene
ug/L
ND
50
38.6
77
70-150
2-Chloronaphthalene
ug/L
ND
50
28.9
58
30-130
2-Chlorophenol
ug/L
ND
50
24.3
49
30-130
2-Methylnaphthalene
ug/L
ND
50
23.6
47
30-130
2-Methylphenol(o-Cresol)
ug/L
ND
50
23.8
48
30-130
2-Naphthalenamine
ug/L
ND
50
22.1
44
30-130
2-Nitroaniline
ug/L
ND
100
58.4
58
40-130
2-Nitrophenol
ug/L
ND
50
24.6
49
20-130
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
50
18.8
38
20-130
3,3'-Dichlorobenzidine
ug/L
ND
100
73.8
74
10-150
3,3'-Dimethylbenzidine
ug/L
ND
100
35.2
35
10-150
3-Methylcholanthrene
ug/L
ND
50
58.3
117
40-130
3-Nitroaniline
ug/L
ND
100
67.2
67
40-130
4,6-Dinitro-2-methyl phenol
ug/L
ND
100
77.0
77
40-130
4-Aminobiphenyl
ug/L
ND
50
20.0
40
20-130
4-Bromophenylphenyl ether
ug/L
ND
50
28.5
57
30-130
4-ChIoro-3-methyl phenol
ug/L
ND
100
48.7
49
30-130
4-Chloroaniline
ug/L
ND
100
53.3
53
20-130
4-Chlorophenylphenyl ether
ug/L
ND
50
24.5
49
20-130
4-Nitroaniline
ug/L
ND
100
79.1
79
40-130
4-Nitrophenol
ug/L
ND
250
101
41
10-130
5-Nitro-o-toluidine
ug/L
ND
50
33.9
68
50-150
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 63 of 76

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
MATRIX SPIKE SAMPLE:
2495383
92416941007
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
7,12-Dimethylbenz(a)anthracene
ug/L
ND
50
36.2
72
50-130
Acenaphthene
ug/L
ND
50
25.2
50
30-130
Acenaphthylene
ug/L
ND
50
27.5
55
30-130
Acetophenone
ug/L
ND
50
26.4
53
20-130
Anthracene
ug/L
ND
50
35.1
70
50-130
Benzo(a)anthracene
ug/L
ND
50
41.0
82
50-130
Benzo(a)pyrene
ug/L
ND
50
39.5
79
50-130
Benzo(b)fluoranthene
ug/L
ND
50
42.4
85
50-130
Benzo(g,h,i)perylene
ug/L
ND
50
37.0
74
50-130
Benzo(k)fluoranthene
ug/L
ND
50
40.9
82
50-130
Benzyl alcohol
ug/L
ND
100
47.0
47
20-130
bis(2-Chloroethoxy)methane
ug/L
ND
50
24.9
50
30-130
bis(2-Chloroethyl) ether
ug/L
ND
50
25.3
51
30-130
bis(2-Ethylhexyl)phthalate
ug/L
ND
50
44.2
88
50-130
Butylbenzylphthalate
ug/L
ND
50
46.0
92
50-150
Chlorobenzilate
ug/L
ND
50
48.2
96
50-130
Chrysene
ug/L
ND
50
39.8
80
50-130
Di-n-butylphthalate
ug/L
ND
50
42.4
85
50-130
Di-n-octylphthalate
ug/L
ND
50
44.7
89
50-130
Diallate
ug/L
ND
50
39.3
79
50-130
Dibenz(a,h)anthracene
ug/L
ND
50
38.7
77
40-130
Dibenzofuran
ug/L
ND
50
23.9
48
40-130
Diethylphthalate
ug/L
ND
50
35.5
71
40-130
Dimethoate
ug/L
ND
50
53.2
106
50-150
Dimethylphthalate
ug/L
ND
50
30.1
60
40-130
Diphenylamine
ug/L
ND
50
32.5
65
30-130
Disulfoton
ug/L
ND
50
38.2
76
40-150
Ethyl methanesulfonate
ug/L
ND
50
37.7
75
40-130
Famphur
ug/L
ND
100
65.1
65
30-150
Fluoranthene
ug/L
ND
50
39.3
79
30-130
Fluorene
ug/L
ND
50
27.0
54
20-130
Hexachloro-1,3-butadiene
ug/L
ND
50
17.1
34
10-130
Hexachlorobenzene
ug/L
ND
50
29.7
59
30-130
Hexachlorocyclopentadiene
ug/L
ND
50
17.2
34
10-150
Hexachloroethane
ug/L
ND
50
17.6
35
10-130
Hexachloropropene
ug/L
ND
50
16.4
33
10-150
Indeno(1,2,3-cd)pyrene
ug/L
ND
50
38.1
76
40-130
Isodrin
ug/L
ND
50
35.5
71
40-130
Isophorone
ug/L
ND
50
26.5
53
30-130
Isosafrole
ug/L
ND
50
21.7
43
40-130
Kepone
ug/L
ND
100
47.1
47
10-130
Methapyrilene
ug/L
ND
50
12.3J
25
10-150
Methyl methanesulfonate
ug/L
ND
50
33.6
67
20-130
Methyl parathion
ug/L
ND
50
52.3
105
50-130
N-Nitroso-di-n-butylamine
ug/L
ND
50
22.5
45
30-130
N-Nitroso-di-n-propylamine
ug/L
ND
50
26.9
54
30-130
N-Nitrosodiethylamine
ug/L
ND
50
25.6
51
40-130
Results presented on this page are in the units indicated
by the "Units" column except where
an alternate unit is
presented to the right
of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 64 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
MATRIX SPIKE SAMPLE:
Parameter
2495383
Units
92416941007
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
N-Nitrosodimethylamine
ug/L
ND
50
19.8
40
10-130
N-Nitrosodiphenylamine
ug/L
ND
50
32.5
65
30-130
N-Nitrosomethylethylamine
ug/L
ND
50
25.7
51
30-130
N-Nitrosopiperidine
ug/L
ND
50
24.4
49
30-130
N-Nitrosopyrrolidine
ug/L
ND
50
26.9
54
30-130
Nitrobenzene
ug/L
ND
50
26.6
53
20-130
O,O,O-Triethylphosphorothioate
ug/L
ND
50
26.5
53
40-130
O-Toluidine
ug/L
ND
50
25.9
52
20-130
P-Dimethylaminoazobenzene
ug/L
ND
50
18.9
38
10-130
p-Phenylenediamine
ug/L
ND
50
49.4
99
70-140
Parathion (Ethyl parathion)
ug/L
ND
50
50.4
101
50-150
Pentachlorobenzene
ug/L
ND
50
22.5
45
30-150
Pentachloronitrobenzene
ug/L
ND
50
41.4
83
60-130
Pentachlorophenol
ug/L
ND
100
70.1
70
10-140
Phenacetin
ug/L
ND
50
49.4
99
60-130
Phenanthrene
ug/L
ND
50
34.5
69
50-130
Phenol
ug/L
ND
50
13.5
27
10-130
Phorate
ug/L
ND
50
42.3
85
50-130
Pronamide
ug/L
ND
50
47.3
95
70-130
Pyrene
ug/L
ND
50
40.9
82
50-130
Safrole
ug/L
ND
50
24.8
50
30-130
Thionazin
ug/L
ND
50
38.0
76
60-130
2,4,6-Tribromophenol (S)
%
67
10-137
2-Fluorobiphenyl (S)
%
46
13-130
2-Fluorophenol (S)
%
35
10-130
Nitrobenzene-d5 (S)
%
52
13-130
Phenol-d6 (S)
%
25
10-130
Terphenyl-d14 (S)
%
72
25-130
SAMPLE DUPLICATE: 2495384
Parameter
Units
92416964002
Result
Dup
Result RPD
Max
RPD Qualifiers
1,2,4,5-Tetrachlorobenzene
ug/L
ND
ND
30
1,3,5-Trinitrobenzene
ug/L
ND
ND
30
1,3-Dinitrobenzene
ug/L
ND
ND
30
1,4-Naphthoquinone
ug/L
ND
ND
30
1-Naphthalenamine
ug/L
ND
ND
30
2,2'-Oxybis(1-chloropropane)
ug/L
ND
ND
30
2,3,4,6-Tetrachlorophenol
ug/L
ND
ND
30
2,4,5-Trichlorophenol
ug/L
ND
ND
30
2,4,6-Trichlorophenol
ug/L
ND
ND
30
2,4-Dichlorophenol
ug/L
ND
ND
30
2,4-Dimethylphenol
ug/L
ND
ND
30
2,4-Dinitrophenol
ug/L
ND
ND
30
2,4-Dinitrotoluene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 65 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
SAMPLE DUPLICATE: 2495384
Parameter
Units
92416964002
Result
Dup
Result RPD
Max
RPD
2,6-Dichlorophenol
ug/L
ND
ND
30
2,6-Dinitrotoluene
ug/L
ND
ND
30
2-Acetylaminofluorene
ug/L
ND
ND
30
2-Chloronaphthalene
ug/L
ND
ND
30
2-Chlorophenol
ug/L
ND
ND
30
2-Methylnaphthalene
ug/L
ND
ND
30
2-Methylphenol(o-Cresol)
ug/L
ND
ND
30
2-Naphthalenamine
ug/L
ND
ND
30
2-Nitroaniline
ug/L
ND
ND
30
2-Nitrophenol
ug/L
ND
ND
30
3&4-Methyl phenol (m&p Cresol)
ug/L
ND
ND
30
3,3'-Dichlorobenzidine
ug/L
ND
ND
30
3,3'-Dimethylbenzidine
ug/L
ND
ND
30
3-Methylcholanthrene
ug/L
ND
ND
30
3-Nitroaniline
ug/L
ND
ND
30
4,6-Dinitro-2-methyl phenol
ug/L
ND
ND
30
4-Aminobiphenyl
ug/L
ND
ND
30
4-Bromophenylphenyl ether
ug/L
ND
ND
30
4-ChIoro-3-methyl phenol
ug/L
ND
ND
30
4-Chloroaniline
ug/L
ND
ND
30
4-Chlorophenylphenyl ether
ug/L
ND
ND
30
4-Nitroaniline
ug/L
ND
ND
30
4-Nitrophenol
ug/L
ND
ND
30
5-Nitro-o-toluidine
ug/L
ND
ND
30
7,12-Dimethylbenz(a)anthracene
ug/L
ND
ND
30
Acenaphthene
ug/L
ND
ND
30
Acenaphthylene
ug/L
ND
ND
30
Acetophenone
ug/L
ND
ND
30
Anthracene
ug/L
ND
ND
30
Benzo(a)anthracene
ug/L
ND
ND
30
Benzo(a)pyrene
ug/L
ND
ND
30
Benzo(b)fluoranthene
ug/L
ND
ND
30
Benzo(g,h,i)perylene
ug/L
ND
ND
30
Benzo(k)fluoranthene
ug/L
ND
ND
30
Benzyl alcohol
ug/L
ND
ND
30
bis(2-Chloroethoxy)methane
ug/L
ND
ND
30
bis(2-Chloroethyl) ether
ug/L
ND
ND
30
bis(2-Ethylhexyl)phthalate
ug/L
ND
ND
30
Butylbenzylphthalate
ug/L
ND
ND
30
Chlorobenzilate
ug/L
ND
ND
30
Chrysene
ug/L
ND
ND
30
Di-n-butylphthalate
ug/L
ND
ND
30
Di-n-octylphthalate
ug/L
ND
ND
30
Diallate
ug/L
ND
ND
30
Dibenz(a,h)anthracene
ug/L
ND
ND
30
Dibenzofuran
ug/L
ND
ND
30
Diethylphthalate
ug/L
ND
ND
30
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 66 of 76

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
SAMPLE DUPLICATE: 2495384
Parameter
Units
92416964002
Result
Dup
Result RPD
Max
RPD Qualifiers
Dimethoate
ug/L
ND
ND
30
Dimethylphthalate
ug/L
ND
ND
30
Diphenylamine
ug/L
ND
ND
30
Disulfoton
ug/L
ND
ND
30
Ethyl methanesulfonate
ug/L
ND
ND
30
Famphur
ug/L
ND
ND
30
Fluoranthene
ug/L
ND
ND
30
Fluorene
ug/L
ND
ND
30
Hexachloro-1,3-butadiene
ug/L
ND
ND
30
Hexachlorobenzene
ug/L
ND
ND
30
Hexachlorocyclopentadiene
ug/L
ND
ND
30
Hexachloroethane
ug/L
ND
ND
30
Hexachloropropene
ug/L
ND
ND
30
Indeno(1,2,3-cd)pyrene
ug/L
ND
ND
30
Isodrin
ug/L
ND
ND
30
Isophorone
ug/L
ND
ND
30
Isosafrole
ug/L
ND
ND
30
Kepone
ug/L
ND
ND
30
Methapyrilene
ug/L
ND
ND
30
Methyl methanesulfonate
ug/L
ND
ND
30
Methyl parathion
ug/L
ND
ND
30
N-Nitroso-di-n-butylamine
ug/L
ND
ND
30
N-Nitroso-di-n-propylamine
ug/L
ND
ND
30
N-Nitrosodiethylamine
ug/L
ND
ND
30
N-Nitrosodimethylamine
ug/L
ND
ND
30
N-Nitrosodiphenylamine
ug/L
ND
ND
30
N-Nitrosomethylethylamine
ug/L
ND
ND
30
N-Nitrosopiperidine
ug/L
ND
ND
30
N-Nitrosopyrrolidine
ug/L
ND
ND
30
Nitrobenzene
ug/L
ND
ND
30
O,O,O-Triethylphosphorothioate
ug/L
ND
ND
30
O-Toluidine
ug/L
ND
ND
30
P-Dimethylaminoazobenzene
ug/L
ND
ND
30
p-Phenylenediamine
ug/L
ND
ND
30
Parathion (Ethyl parathion)
ug/L
ND
ND
30
Pentachlorobenzene
ug/L
ND
ND
30
Pentachloronitrobenzene
ug/L
ND
ND
30
Pentachlorophenol
ug/L
ND
ND
30
Phenacetin
ug/L
ND
ND
30
Phenanthrene
ug/L
ND
ND
30
Phenol
ug/L
ND
ND
30
Phorate
ug/L
ND
ND
30
Pronamide
ug/L
ND
ND
30
Pyrene
ug/L
ND
ND
30
Safrole
ug/L
ND
ND
30
Thionazin
ug/L
ND
ND
30
2,4,6-Tribromophenol (S)
%
56
46 19
Results presented on this page are in the units
indicated by the "Units" column except where an alternate unit is presented
to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 67 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
SAMPLE DUPLICATE: 2495384
92416964002
Dup
Max
Parameter
Units
Result
Result
RPD RPD
2-Fluorobiphenyl (S)
%
50
45
11
2-Fluorophenol(S)
%
36
26
32
Nitrobenzene-d5 (S)
%
52
49
5
Phenol-d6 (S)
%
24
18
29
Terphenyl-d14 (S)
%
58
58
1
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 68 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 457232
Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011
Analysis Description: 4500S2D Sulfide
Water
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
METHOD BLANK: 2493961
Matrix: Water
Associated Lab Samples: 92416424005, 92416424006,
92416424007, 92416424008
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Sulfide ug/L
ND 100
50.0 02/08/1918:55
LABORATORY CONTROL SAMPLE: 2493962
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Sulfide ug/L
500 502 100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2493963 2493964
MS MSD
92416412001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Sulfide ug/L ND
500 500 312 348
58 65
80-120 11 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2493965 2493966
MS MSD
92416553004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 476 485 95 97 80-120 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 69 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Compliance
Pace Project No.: 92416424
QC Batch: 457380 Analysis Method: SM 4500-CN-E-2011
QC Batch Method: SM 4500-CN-E-2011 Analysis Description: 450OCNE Cyanide, Total
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
METHOD BLANK: 2494655 Matrix: Water
Associated Lab Samples: 92416424005, 92416424006, 92416424007, 92416424008
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Cyanide ug/L ND 8.0 6.0 02/12/1916:37
LABORATORY CONTROL SAMPLE: 2494656
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
Cyanide ug/L 100 89.7 90 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2494657 2494658
MS MSD
92416934001 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 21.8 58.6 21 58 80-120 91 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2494659 2494660
MS MSD
92416379002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Cyanide ug/L ND 100 100 90.8 76.4 87 73 80-120 17 10 M1,R1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC.
Page 70 of 76

Pace Analytical Services, LLC
ceAnalX cal ® 9800 Kiney Ave. Suite 100
Huntersville, NC 28078078
www.pacelabs.com [phone]
QUALIFIERS
Project: Butner Compliance
Pace Project No.: 92416424
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
PASI-GA Pace Analytical Services - Atlanta, GA
ANALYTE QUALIFIERS
C9 Common Laboratory Contaminant.
L2 Analyte recovery in the laboratory control sample (LCS) was below QC limits. Results for this analyte in associated
samples may be biased low.
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 06:14 PM without the written consent of Pace Analytical Services, LLC. Page 71 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Compliance
92416424
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92416424005
FIELD BLANK
EPA 3510C
456609
EPA 8081 B
456928
92416424006
3902-MW1 R
EPA 3510C
456609
EPA 8081 B
456928
92416424007
3902-MW2R
EPA 3510C
456609
EPA 8081 B
456928
92416424008
3902-MW3R
EPA 3510C
456609
EPA 8081 B
456928
92416424005
FIELD BLANK
EPA 3510C
456686
EPA 8082A
456930
92416424006
3902-MW1 R
EPA 3510C
456686
EPA 8082A
456930
92416424007
3902-MW2R
EPA 3510C
456686
EPA 8082A
456930
92416424008
3902-MW3R
EPA 3510C
456686
EPA 8082A
456930
92416424005
FIELD BLANK
EPA 8151A
22144
EPA 8151A
22232
92416424006
3902-MW1 R
EPA 8151 A
22144
EPA 8151 A
22232
92416424007
3902-MW2R
EPA 8151A
22144
EPA 8151A
22232
92416424008
3902-MW3R
EPA 8151A
22144
EPA 8151A
22232
92416424001
3902-MW4
EPA 3010A
456556
EPA 6010D
456578
92416424002
3902-MW5
EPA 3010A
456556
EPA 6010D
456578
92416424003
3902-MW6
EPA 3010A
456556
EPA 6010D
456578
92416424005
FIELD BLANK
EPA 3010A
456556
EPA 6010D
456578
92416424006
3902-MW1 R
EPA 3010A
456556
EPA 6010D
456578
92416424007
3902-MW2R
EPA 3010A
456556
EPA 6010D
456578
92416424008
3902-MW3R
EPA 3010A
456556
EPA 6010D
456578
92416424001
3902-MW4
EPA 3010A
456560
EPA 6020B
456581
92416424002
3902-MW5
EPA 3010A
456560
EPA 6020B
456581
92416424003
3902-MW6
EPA 3010A
456560
EPA 6020B
456581
92416424005
FIELD BLANK
EPA 3010A
456560
EPA 6020B
456581
92416424006
3902-MW1 R
EPA 3010A
456560
EPA 6020B
456581
92416424007
3902-MW2R
EPA 3010A
456560
EPA 6020B
456581
92416424008
3902-MW3R
EPA 3010A
456560
EPA 6020B
456581
92416424005
FIELD BLANK
EPA 7470A
456505
EPA 7470A
456519
92416424006
3902-MW1 R
EPA 7470A
456505
EPA 7470A
456519
92416424007
3902-MW2R
EPA 7470A
456505
EPA 7470A
456519
92416424008
3902-MW3R
EPA 7470A
456505
EPA 7470A
456519
92416424005
FIELD BLANK
EPA 3510C
457539
EPA 8270D
457821
92416424006
3902-MW1 R
EPA 3510C
457539
EPA 8270D
457821
92416424007
3902-MW2R
EPA 3510C
457539
EPA 8270D
457821
92416424008
3902-MW3R
EPA 3510C
457539
EPA 8270D
457821
92416424001
3902-MW4
EPA 8260B
456738
92416424002
3902-MW5
EPA 8260B
456738
92416424003
3902-MW6
EPA 8260B
456738
92416424004
3902-NES-1
EPA 8260B
456738
92416424005
FIELD BLANK
EPA 8260B
456738
92416424006
3902-MW1 R
EPA 8260B
456738
92416424007
3902-MW2R
EPA 8260B
456738
92416424008
3902-MW3R
EPA 8260B
456738
92416424009
TRIP BLANK
EPA 8260B
456738
92416424001
3902-MW4
EPA 8260B Mod.
457598
92416424002
3902-MW5
EPA 8260B Mod.
457598
REPORT OF LABORATORY
ANALYSIS
This report shall not be reproduced, except
in full,
Date: 02/15/2019 06:14 PM
without the written consent of Pace Analytical Services, LLC.
Page 72 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Compliance
92416424
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92416424003
3902-MW6
EPA 8260B Mod.
457598
92416424004
3902-NES-1
EPA 8260B Mod.
458172
92416424005
FIELD BLANK
EPA 8260B Mod.
457598
92416424006
3902-MW1 R
EPA 8260B Mod.
458172
92416424007
3902-MW2R
EPA 8260B Mod.
458371
92416424008
3902-MW3R
EPA 8260B Mod.
458172
92416424009
TRIP BLANK
EPA 8260B Mod.
457598
92416424005
FIELD BLANK
SM 4500-S2D-2011
457232
92416424006
3902-MW1R
SM 4500-S2D-2011
457232
92416424007
3902-MW2R
SM 4500-S2D-2011
457232
92416424008
3902-MW3R
SM 4500-S2D-2011
457232
92416424005
FIELD BLANK
SM 4500-CN-E-2011
457380
SM 4500-CN-E-2011
457631
92416424006
3902-MW1R
SM 4500-CN-E-2011
457380
SM 4500-CN-E-2011
457631
92416424007
3902-MW2R
SM 4500-CN-E-2011
457380
SM 4500-CN-E-2011
457631
92416424008
3902-MW3R
SM 4500-CN-E-2011
457380
SM 4500-CN-E-2011
457631
Date: 02/15/2019 06:14 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 73 of 76

=f 7CCf�MIY Cal
Document Name:
Sample Condition Upon Recelpt(SCUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville © Eden[] Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
Sample C. ondition Clie t Name: WO# : 92416424
Upon Receipt
ProjE
Courier: / F�d'Ex ❑UPS❑U5P5 �1❑Client
El commercial ❑Fare ` ❑Other: 92416424
Custody Seal Present? ❑Yes DNo Seals Intact? ZI-Yes ❑ No
-T .-
Date/initials Person Examining Contents:K'
Packing Material: Bubble Wrap ❑Bubble Bags ❑None ❑ Other Biological Tissue Frozen?
Thermometer: Type of Ice: [,-,� Net ❑Blue ❑None Dyes ❑No ffN/A
DIR Gun ID;
ry
ll � U r
Cooler Temp [°[}; f' 5 � 0 Co rectivn Factor: Add/subtract {°C}
, v Tempshould be above freezing to 6°C
Cooler Temp Corrected (°Cj:`I' Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil (/N/A, water sample}
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)? Did samples originate from a foreign source (internationally,
[]Yes RNo —Lirinu HAwnli Ami Piiprtn Riral? nYes F­lNo
Comments/Discrepancy:
Chain of Custody Present?
Q1es
❑No
❑N/A
1.
Samples Arrived within Hold Time?
[Iles
❑No
❑NIA
2.
Short Hold Time Analysis (<72 hr.)?
[:]Yes[ri
❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
r No
❑N/A
4.
Sufficient Volume?
[)Yes
❑No
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
❑JYes
YYes
❑No
[]No
❑N/A
❑N/A
6.
Containers Intact?
❑i '-
❑Nn
❑N/A
7.
Dissolved analysis: Samples Field Filtered? [--]Yes
❑No
[TN/A
8.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis
[]Yes
Matrix: 1
❑N❑
❑1WA
9.
Headspace in VOA Vials (n5-6mm)?
❑Yes
[//No
❑NIA
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
Yes
[dyes
❑No
❑No
❑NIA
©NIA
11.
COMMENTS/SAMPLE DISCREPANCY Field Data Required? Dyes ❑No
Scl�!llct
� Lw��11
�11-
.,�;�ai4�ti`S
51 �xA C--,, U{
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: AIW6 Date; ZM0
Project Manager SRF Review: � Date: Z f U119
Page 74 of 76

�-
!
Document Name:
Document Revised: February 7, 2018
�. �c?CBA11c1lmf
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Proje WO# : 92416424
PM: NMG Due Date: 02/19/19
CLIENT: 92-Joyce En9
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot#
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this Form will be sent to the North Carolina DEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of tamp, incorrect containers.
Page 75 of 76

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Page 76 of 76

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 15, 2019
Van Burbach
Joyce Engineering -NC
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Landfill MNA
Pace Project No.: 92416412
Dear Van Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
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REPORT OF LABORATORY ANALYSIS
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9e0 without the written consent of Pace Analytical Services, LLC.
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Project: Butner Landfill MNA
Pace Project No.: 92416412
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
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SAMPLE SUMMARY
Project: Butner Landfill MNA
Pace Project No.: 92416412
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92416412001
3902-MW2R
Water
02/04/1914:52
02/05/1910:10
92416412002
3902-MW3R
Water
02/04/1913:02
02/05/1910:10
92416412003
MWA R
Water
02/04/19 08:34
02/05/19 10:10
92416412004
NES-1
Water
02/04/1917:37
02/05/1910:10
REPORT OF LABORATORY ANALYSIS
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SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Landfill MNA
92416412
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92416412001
3902-MW2R
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
92416412002
3902-MW3R
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
92416412003
MW-1R
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
92416412004
NES-1
RSK 175 Modified
LMB
3
PASI-C
SM 2320B-2011
ECH
1
PASI-A
SM 4500-S2D-2011
GC
1
PASI-A
SM 5210B-2011
SMK
1
PASI-A
EPA 300.0 Rev 2.1 1993
CDC
2
PASI-A
EPA 353.2 Rev 2.0 1993
DMN
1
PASI-A
SM 5220D-2011
GC
1
PASI-A
SM 5310B-2011
ECH
1
PASI-A
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SUMMARY OF DETECTION
Project: Butner Landfill MNA
Pace Project No.: 92416412
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92416412001
3902-MW2R
RSK 175 Modified
Methane
2720
ug/L
10.0
02/06/19 13:35
SM 2320B-2011
Alkalinity, Total as CaCO3
856000
ug/L
5000
02/07/19 21:16
SM 521OB-2011
BOD, 5 day
7500
ug/L
2000
02/10/19 14:21
EPA 300.0 Rev 2.1 1993
Chloride
221000
ug/L
4000
02/08/19 05:21
SM 5220D-2011
Chemical Oxygen Demand
101000
ug/L
25000
02/06/19 22:49
SM 531OB-2011
Total Organic Carbon
27900
ug/L
10000
02/07/19 03:52
92416412002
3902-MW3R
SM 2320B-2011
Alkalinity, Total as CaCO3
638000
ug/L
5000
02/07/19 21:36
EPA 300.0 Rev 2.1 1993
Chloride
147000
ug/L
3000
02/08/19 05:36
EPA 300.0 Rev 2.1 1993
Sulfate
1100
ug/L
1000
02/08/19 00:28
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
113
ug/L
20.0
02/05/19 14:25
SM 5220D-2011
Chemical Oxygen Demand
26500
ug/L
25000
02/06/19 22:50
SM 531OB-2011
Total Organic Carbon
8020
ug/L
1000
02/07/19 04:07
92416412003
MWA R
SM 2320B-2011
Alkalinity, Total as CaCO3
62000
ug/L
5000
02/07/19 21:45
EPA 300.0 Rev 2.1 1993
Chloride
3420
ug/L
1000
02/08/19 00:43
EPA 300.0 Rev 2.1 1993
Sulfate
1150
ug/L
1000
02/08/19 00:43
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
196
ug/L
20.0
02/05/19 14:22
92416412004
NES-1
SM 2320B-2011
Alkalinity, Total as CaCO3
7020
ug/L
5000
02/07/19 21:52
EPA 300.0 Rev 2.1 1993
Chloride
4520
ug/L
1000
02/08/19 00:59
EPA 300.0 Rev 2.1 1993
Sulfate
6750
ug/L
1000
02/08/19 00:59
EPA 353.2 Rev 2.0 1993
Nitrogen, Nitrate
6500
ug/L
80.0
02/05/19 14:40
SM 531OB-2011
Total Organic Carbon
1580
ug/L
1000
02/07/19 04:36
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ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92416412
Sample: 3902-MW2R Lab ID: 92416412001 Collected: 02/04/19 14:52 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
RSK 175 Headspace
Ethane
Ethene
Methane
2320B Alkalinity
Alkalinity, Total as CaCO3
4500S2D Sulfide Water
Sulfide
5210B BOD, 5 day
BOD, 5 day
300.0 IC Anions 28 Days
Chloride
Sulfate
353.2 Nitrogen, NO2/NO3 unpres
Nitrogen, Nitrate
5220D COD
Chemical Oxygen Demand
5310B TOC
Total Organic Carbon
Date: 02/15/2019 04:29 PM
Analytical Method: RSK 175 Modified
ND ug/L 10.0
10.0
1
02/06/1913:35
74-84-0
ND ug/L 10.0
10.0
1
02/06/1913:35
74-85-1
2720 ug/L 10.0
10.0
1
02/06/1913:35
74-82-8
Analytical Method: SM 2320B-2011
856000 ug/L 5000
1000
1
02/07/19 21:16
Analytical Method: SM 4500-S2D-2011
ND ug/L 100
50.0
1
02/08/1918:56
18496-25-8 M1,R1
Analytical Method: SM 521OB-2011
7500 ug/L 2000
2000
1
02/05/1918:29 02/10/1914:21
Analytical Method: EPA 300.0 Rev 2.1 1993
221000 ug/L 4000
2400
4
02/08/19 05:21
16887-00-6
ND ug/L 1000
500
1
02/08/19 00:12
14808-79-8
Analytical Method: EPA 353.2 Rev 2.0 1993
ND ug/L 20.0
10.0
1
02/05/1914:29
14797-55-8
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
101000 ug/L 25000
12500
1
02/06/19 17:00 02/06/19 22:49
Analytical Method: SM 531OB-2011
27900 ug/L 10000
5000
10
02/07/19 03:52
7440-44-0
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92416412
Sample: 3902-MW3R
Lab ID: 92416412002 Collected:
02/04/19 13:02
Received: 02/05/19 10:10 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Ethane
ND ug/L 10.0
10.0
1
02/06/1912:34
74-84-0
Ethene
ND ug/L 10.0
10.0
1
02/06/1912:34
74-85-1
Methane
ND ug/L 10.0
10.0
1
02/06/1912:34
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
638000 ug/L 5000
1000
1
02/07/19 21:36
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Sulfide
ND ug/L 100
50.0
1
02/08/1918:57
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
ND ug/L 2000
2000
1
02/05/19 18:29 02/10/19 14:00
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Chloride
147000 ug/L 3000
1800
3
02/08/19 05:36
16887-00-6
Sulfate
1100 ug/L 1000
500
1
02/08/19 00:28
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Nitrogen, Nitrate
113 ug/L 20.0
10.0
1
02/05/19 14:25
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
26500 ug/L 25000
12500
1
02/06/19 17:00 02/06/19 22:50
5310B TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
8020 ug/L 1000
500
1
02/07/19 04:07
7440-44-0
Date: 02/15/2019 04:29 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92416412
Sample: MWAR
Lab ID: 92416412003 Collected:
02/04/19 08:34
Received: 02/05/19 10:10 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Ethane
ND ug/L 10.0
10.0
1
02/06/1912:50
74-84-0
Ethene
ND ug/L 10.0
10.0
1
02/06/1912:50
74-85-1
Methane
ND ug/L 10.0
10.0
1
02/06/1912:50
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
62000 ug/L 5000
1000
1
02/07/19 21:45
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Sulfide
ND ug/L 100
50.0
1
02/08/1918:58
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
ND ug/L 2000
2000
1
02/05/19 18:29 02/10/19 13:41
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Chloride
3420 ug/L 1000
600
1
02/08/19 00:43
16887-00-6
Sulfate
1150 ug/L 1000
500
1
02/08/19 00:43
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Nitrogen, Nitrate
196 ug/L 20.0
10.0
1
02/05/19 14:22
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
ND ug/L 25000
12500
1
02/06/19 17:00 02/06/19 22:50
5310B TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
ND ug/L 1000
500
1
02/07/19 04:21
7440-44-0
Date: 02/15/2019 04:29 PM
REPORT OF LABORATORY ANALYSIS
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ANALYTICAL RESULTS
Project: Butner Landfill MNA
Pace Project No.: 92416412
Sample: NES-1
Lab ID: 92416412004 Collected:
02/04/19 17:37
Received: 02/05/19 10:10 Matrix: Water
Report
Parameters
Results Units Limit
MDL
DF
Prepared Analyzed
CAS No. Qual
RSK 175 Headspace
Analytical Method: RSK 175 Modified
Ethane
ND ug/L 10.0
10.0
1
02/06/1913:20
74-84-0
Ethene
ND ug/L 10.0
10.0
1
02/06/1913:20
74-85-1
Methane
ND ug/L 10.0
10.0
1
02/06/1913:20
74-82-8
2320B Alkalinity
Analytical Method: SM 2320B-2011
Alkalinity, Total as CaCO3
7020 ug/L 5000
1000
1
02/07/19 21:52
4500S2D Sulfide Water
Analytical Method: SM 4500-S2D-2011
Sulfide
ND ug/L 100
50.0
1
02/08/1918:58
18496-25-8
5210B BOD, 5 day
Analytical Method: SM 521 OB-2011
BOD, 5 day
ND ug/L 2000
2000
1
02/05/19 18:29 02/10/19 14:30
300.0 IC Anions 28 Days
Analytical Method: EPA 300.0 Rev 2.1
1993
Chloride
4520 ug/L 1000
600
1
02/08/19 00:59
16887-00-6
Sulfate
6750 ug/L 1000
500
1
02/08/19 00:59
14808-79-8
353.2 Nitrogen, NO2/NO3 unpres
Analytical Method: EPA 353.2 Rev 2.0
1993
Nitrogen, Nitrate
6500 ug/L 80.0
40.0
4
02/05/19 14:40
14797-55-8
5220D COD
Analytical Method: SM 5220D-2011 Preparation
Method: SM 5220D-2011
Chemical Oxygen Demand
ND ug/L 25000
12500
1
02/06/19 17:00 02/06/19 22:50
5310B TOC
Analytical Method: SM 531 OB-2011
Total Organic Carbon
1580 ug/L 1000
500
1
02/07/19 04:36
7440-44-0
Date: 02/15/2019 04:29 PM
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456594 Analysis Method: RSK 175 Modified
QC Batch Method: RSK 175 Modified Analysis Description: RSK 175 HEADSPACE
Associated Lab Samples: 92416412001, 92416412002, 92416412003, 92416412004
METHOD BLANK: 2490791
Matrix:
Water
Associated Lab Samples: 92416412001, 92416412002, 92416412003, 92416412004
Blank
Reporting
Parameter
Units
Result
Limit
Ethane
ug/L
ND
10.0
Ethene
ug/L
ND
10.0
Methane
ug/L
ND
10.0
LABORATORY CONTROL SAMPLE:
2490792
Spike
LCS
Parameter
Units
Conc.
Result
Ethane
ug/L
658
692
Ethene
ug/L
1120
1170
Methane
ug/L
396
407
MDL Analyzed
10.0 02/06/19 08:29
10.0 02/06/19 08:29
10.0 02/06/19 08:29
Qualifiers
LCS % Rec
% Rec Limits Qualifiers
105 70-130
105 70-130
103 70-130
MATRIX SPIKE SAMPLE:
2490793
2614382001
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
Ethane
ug/L
ND
658
680
103
70-130
Ethene
ug/L
ND
1120
1280
114
70-130
Methane
ug/L
2700
396
2550
-38
70-130 M1
SAMPLE DUPLICATE: 2490794
2614382001
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
ND
ND
20
Ethene
ug/L
ND
ND
20
Methane
ug/L
2700
ND
20
SAMPLE DUPLICATE: 2490984
92416412003
Dup
Max
Parameter
Units
Result
Result
RPD
RPD
Qualifiers
Ethane
ug/L
ND
ND
20
Ethene
ug/L
ND
ND
20
Methane
ug/L
ND
ND
20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 37

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QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456867
Analysis Method: SM 2320B-2011
QC Batch Method: SM 2320B-2011
Analysis Description: 2320E Alkalinity
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
METHOD BLANK: 2492198
Matrix: Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
Blank Reporting
Parameter Units
Result Limit MDL Analyzed
Qualifiers
Alkalinity, Total as CaCO3 ug/L
ND 5000 1000 02/07/19 20:34
LABORATORY CONTROL SAMPLE: 2492199
Spike LCS LCS % Rec
Parameter Units
Conc. Result % Rec Limits Qualifiers
Alkalinity, Total as CaCO3 ug/L
50000 51700 103 80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2492200 2492201
MS MSD
92416756010
Spike Spike MS MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result % Rec % Rec
Limits RPD RPD Qual
Alkalinity, Total as CaCO3 ug/L 73.9 mg/L
50000 50000 127000 124000 105 100
80-120 2 25
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC.
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QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 457232
Analysis Method: SM 4500-S2D-2011
QC Batch Method: SM 4500-S2D-2011
Analysis Description: 4500S2D Sulfide
Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
METHOD BLANK: 2493961
Matrix: Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Sulfide ug/L
ND 100
50.0 02/08/1918:55
LABORATORY CONTROL SAMPLE: 2493962
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Sulfide ug/L
500 502 100
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2493963 2493964
MS MSD
92416412001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Sulfide ug/L ND
500 500 312 348
58 65
80-120 11 10 M1,R1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2493965 2493966
MS MSD
92416553004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Sulfide ug/L ND 500 500 476 485 95 97 80-120 2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
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QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456439
Analysis Method: SM 521 OB-2011
QC Batch Method: SM 521OB-2011
Analysis Description: 5210E BOD, 5 day
Associated Lab Samples: 92416412001,
92416412002, 92416412003, 92416412004
METHOD BLANK: 2490179
Matrix: Water
Associated Lab Samples: 92416412001,
92416412002, 92416412003, 92416412004
Blank Reporting
Parameter
Units
Result Limit MDL Analyzed Qualifiers
BOD, 5 day
ug/L
ND 2000 2000 02/10/19 13:01
LABORATORY CONTROL SAMPLE: 2490180
Spike LCS LCS % Rec
Parameter
Units
Conc. Result % Rec Limits Qualifiers
BOD, 5 day
ug/L
198000 179000 91 84.6-115
SAMPLE DUPLICATE: 2490181
92416303001 Dup Max
Parameter
Units
Result Result RPD RPD Qualifiers
BOD, 5 day
ug/L
ND ND 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 37

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456887 Analysis Method: EPA 300.0 Rev 2.1 1993
QC Batch Method: EPA 300.0 Rev 2.1 1993 Analysis Description: 300.0 IC Anions
Associated Lab Samples: 92416412001, 92416412002, 92416412003, 92416412004
METHOD BLANK: 2492322 Matrix: Water
Associated Lab Samples: 92416412001, 92416412002, 92416412003, 92416412004
Blank Reporting
Parameter Units Result Limit MDL Analyzed Qualifiers
Chloride ug/L ND 1000 600 02/07/19 21:22
Sulfate ug/L ND 1000 500 02/07/19 21:22
LABORATORY CONTROL SAMPLE: 2492323
Spike
LCS LCS
% Rec
Parameter Units
Conc.
Result % Rec
Limits Qualifiers
Chloride ug/L
50000
50600 101
90-110
Sulfate ug/L
50000
51800 104
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2492324
2492325
MS
MSD
92416554002
Spike
Spike
MS
MSD MS
MSD % Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec Limits
RPD RPD Qual
Chloride ug/L
38.9 mg/L
50000
50000
90500
95200 103
113 90-110
5 10 M1
Sulfate ug/L
55.8 mg/L
50000
50000
101000
91400 90
71 90-110
10 10 M1
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2492326
2492327
MS
MSD
92416686001
Spike
Spike
MS
MSD MS
MSD
% Rec
Max
Parameter Units
Result
Conc.
Conc.
Result
Result % Rec
% Rec
Limits
RPD RPD Qual
Chloride ug/L
5.3 mg/L
50000
50000
57700
58500 105
106
90-110
1 10
Sulfate ug/L
2.9 mg/L
50000
50000
55700
56800 106
108
90-110
2 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC.
Page 14 of 37

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456438
Analysis Method: EPA 353.2 Rev 2.0 1993
QC Batch Method: EPA 353.2 Rev 2.0 1993
Analysis Description: 353.2 Nitrate
+ Nitrite, Unpres.
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
METHOD BLANK: 2490174
Matrix: Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Nitrogen, Nitrate ug/L
ND 20.0
10.0 02/05/19 14:20
LABORATORY CONTROL SAMPLE: 2490175
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Nitrogen, Nitrate ug/L
1500 1410 94
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490176 2490177
MS MSD
92416412003
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Nitrogen, Nitrate ug/L 196
1500 1500 1850 1660
110 98
90-110 11 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC.
Page 15 of 37

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456770
Analysis Method: SM 5220D-2011
QC Batch Method: SM 5220D-2011
Analysis Description: 5220D COD
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
METHOD BLANK: 2491890
Matrix: Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
Blank Reporting
Parameter Units
Result Limit
MDL Analyzed
Qualifiers
Chemical Oxygen Demand ug/L
ND 25000
12500 02/06/19 22:46
LABORATORY CONTROL SAMPLE: 2491891
Spike LCS
LCS % Rec
Parameter Units
Conc. Result
% Rec Limits Qualifiers
Chemical Oxygen Demand ug/L
750000 765000
102 90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2491892 2491893
MS MSD
92416314001
Spike Spike MS
MSD MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result
Result % Rec % Rec
Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 1540 mg/L
100000 100000 1630000
1640000 93 98
90-110 0 3
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2491894 2491895
MS MSD
92416496004 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Chemical Oxygen Demand ug/L 526 mg/L 100000 100000 559000 555000 33 29 90-110 1 3 M1
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 37

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Landfill MNA
Pace Project No.: 92416412
QC Batch: 456618
Analysis Method: SM 531 OB-2011
QC Batch Method: SM 531 OB-2011
Analysis Description: 5310E TOC
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
METHOD BLANK: 2490876
Matrix: Water
Associated Lab Samples: 92416412001, 92416412002,
92416412003, 92416412004
Blank Reporting
Parameter Units
Result Limit
MDL
Analyzed Qualifiers
Total Organic Carbon ug/L
ND 1000
500 02/06/19 21:35
LABORATORY CONTROL SAMPLE: 2490877
Spike LCS
LCS
% Rec
Parameter Units
Conc. Result
% Rec
Limits Qualifiers
Total Organic Carbon ug/L
25000 26800
107
90-110
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490878 2490879
MS MSD
92416172003
Spike Spike MS
MSD
MS MSD % Rec Max
Parameter Units Result
Conc. Conc. Result
Result
% Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L 2.7 mg/L
25000 25000 29200
28900
106 105 90-110 1 10
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490880 2490881
MS MSD
92416331002 Spike Spike MS MSD MS MSD % Rec Max
Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD RPD Qual
Total Organic Carbon ug/L ND 25000 25000 25800 25900 103 104 90-110 1 10
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 37

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Landfill MNA
Pace Project No.: 92416412
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
ANALYTE QUALIFIERS
M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery.
R1 RPD value was outside control limits.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 04:29 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 37

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project:
Pace Project No.:
Butner Landfill MNA
92416412
Analytical
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Batch
92416412001
3902-MW2R
RSK 175 Modified
456594
92416412002
3902-MW3R
RSK 175 Modified
456594
92416412003
MWA R
RSK 175 Modified
456594
92416412004
NES-1
RSK 175 Modified
456594
92416412001
3902-MW2R
SM 2320B-2011
456867
92416412002
3902-MW3R
SM 2320B-2011
456867
92416412003
MWA R
SM 2320E-2011
456867
92416412004
NES-1
SM 2320E-2011
456867
92416412001
3902-MW2R
SM 4500-S2D-2011
457232
92416412002
3902-MW3R
SM 4500-S2D-2011
457232
92416412003
MWA R
SM 4500-S2D-2011
457232
92416412004
NES-1
SM 4500-S2D-2011
457232
92416412001
3902-MW2R
SM 5210B-2011
456439
SM 5210B-2011
456528
92416412002
3902-MW3R
SM 5210B-2011
456439
SM 5210B-2011
456528
92416412003
MWA R
SM 5210E-2011
456439
SM 5210B-2011
456528
92416412004
NES-1
SM 5210E-2011
456439
SM 5210B-2011
456528
92416412001
3902-MW2R
EPA 300.0 Rev 2.1 1993
456887
92416412002
3902-MW3R
EPA 300.0 Rev 2.1 1993
456887
92416412003
MWA R
EPA 300.0 Rev 2.1 1993
456887
92416412004
NES-1
EPA 300.0 Rev 2.1 1993
456887
92416412001
3902-MW2R
EPA 353.2 Rev 2.0 1993
456438
92416412002
3902-MW3R
EPA 353.2 Rev 2.0 1993
456438
92416412003
MWA R
EPA 353.2 Rev 2.0 1993
456438
92416412004
NES-1
EPA 353.2 Rev 2.0 1993
456438
92416412001
3902-MW2R
SM 5220D-2011
456770
SM 5220D-2011
456801
92416412002
3902-MW3R
SM 5220D-2011
456770
SM 5220D-2011
456801
92416412003
MWA R
SM 5220D-2011
456770
SM 5220D-2011
456801
92416412004
NES-1
SM 5220D-2011
456770
SM 5220D-2011
456801
92416412001
3902-MW2R
SM 5310B-2011
456618
92416412002
3902-MW3R
SM 5310B-2011
456618
92416412003
MWA R
SM 5310E-2011
456618
92416412004
NES-1
SM 5310E-2011
456618
Date: 02/15/2019 04:29 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 19 of 37

Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
aceAnalytii
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ❑ Eden❑ Greenwood ❑ Huntersville ❑ Raleigh❑ Mechanicsville❑
Sample Condition ;.F
t Name:Upon Receipt Project #: WO# : 92416412
Courier: Ex ❑UPS ❑USPS Client
❑ Commercial ❑Pace ❑other: 111111111111111111111
92416412
Custody Seal Present? ❑Yes E3No [ Seals Intact? Yes ❑No I�7
Date/Initials Person Examining Contents:
Packing Material: DBubble Wrap [—]Bubble Bags ❑None ❑ Other
Thermometer. u i ❑IRGun ID: Type of Ice: ❑wet []Blue
Cooler Temp (°C): J.�Correction Factor: Add/Subtract (°C)
r 1
Cooler Temp Corrected ('C): _.�
USDA Regulated Soil ([�(i water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
Biological Tissuee, {Frozen?
❑Yes ❑[J No N/A
❑None
Temp should be above freezing to i
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
❑Yes [:]No
including Hawaii ano f'uerio nicola i uivu
Comments/Discrepancy:
Chain of Custody Present?
Des
❑No
❑N/A
1.
Samples Arrived within Hold Time?
[ lles
❑No
El
2.
Short Hold Time Analysis (<72 hi
Yes
❑No
❑N/A
3.
Rush Turn Around Time Requested?
Des
ONo
❑N/A
4.
Sufficient Volume?
[f]Yes
❑i
❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
DYes
[Yes
❑Na
❑No
[]N/A
DNA
6.
Containers Intact?
[3 es
❑N❑
El N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No
D`N/A
8-
Sample Labels Match COC?
❑No
El N/A
9.
-Includes Date/Time/ID/Analysis Matrix:
1�DYes
1W I
Headspace in VOA Vials (>5-6mi
❑Yes
[]No
❑N/A
10.
Trip Blank Present?
❑Yes
ENo
❑N/A
11.
Trip Blank Custody Seals Present?
❑Yes
❑No
N/A
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Project Manager SCURF Review:
Project Manager SRF Review:
Date/Time:
Field Data Required? ❑Yes O'No
Lot ID of split containers:
Date: Z &b q
Date:
Page 20 of 37

`-
Document Name:
Sample Condition Upon Receipt(5CUR)
Document Revised: February 7, 2018
Page 1 of 2
Document No.:
Issuing Authority:
c?CE�i>7aj,,frCr?�
y`
F-CAR-CS-033-ReVA6
Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, ?OC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project # i WQ# : 92416412
PM: NMG Due Date: 02/19/19
CLIENT: 92-Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
-F
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form wilihe sent to the North Carolina DFHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 21 of 37

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age 22 of 37

lacmnalyficalo
February 15, 2019
Nicole Gasiorowski
Pace Analytical Services, Inc.
9800 Kincey Avenue
Suite 100
Huntersville, NC 28078
RE: 92416412 / BUTNER LF
Pace Workorder. 29413
Dear Nicole Gasiorowski:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, February 06, 2019.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 02/15/2019
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 29413 - 1138441
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 15
Page 1 of 11
Page 23 of 37

Pace Analytical Energy Services LLC
220 William Pitt Way
.,-- A__1.X__1 o Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 29413 - 1138441
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 11
Page 24 of 37

lacmnalyficalo
SAMPLE SUMMARY
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Matrix
Date Collected
Date Received
294130001
3902-MW2R
Water
2/4/201914:52
2/6/201913:03
294130002
3902-MW3R
Water
2/4/201913:02
2/6/201913:03
294130003
MW-1R
Water
2/4/201908:34
2/6/201913:03
294130004
NES-1
Water
2/4/201917:37
2/6/201913:03
Report ID: 29413 - 1138441
4nela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 3 of 11
Page 25 of 37

lacmnalyficalo
PROJECT SUMMARY
Workorder: 29413 92416412 / BUTNER LF
Workorder Comments
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
The analysis for volatile fatty acids, method AM23G, was reported at dilution for samples 29413 (0001-0002) due to the measured
chloride concentration within the sample; matrix interfering compound.
Report ID: 29413 - 1138441
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 4 of 11
Page 26 of 37

lacmnalyficalo
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294130001
Sample ID: 3902-MW2R
Date Received: 2/6/2019 13:03
Date Collected: 2/4/2019 14:52
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.26J mg/I
2.0
0.14 10
2/7/2019 22:21
KB
d
Acetic Acid
0.24U mg/I
1.0
0.24 10
2/7/2019 22:21
KB
d
Propionic Acid
0.044U mg/I
1.0
0.044 10
2/7/2019 22:21
KB
d
Formic Acid
2.9 mg/I
2.0
0.48 10
2/7/2019 22:21
KB
d,B
Butyric Acid
0.047U mg/I
1.0
0.047 10
2/7/2019 22:21
KB
d
i-Pentanoic Acid
0.075U mg/I
1.0
0.075 10
2/7/2019 22:21
KB
d
Pentanoic Acid
0.12U mg/I
1.0
0.12 10
2/7/2019 22:21
KB
d
Report ID: 29413 - 1138441 Page 5 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 27 of 37

lacmnalyficalo
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294130002
Sample ID: 3902-MW3R
Date Received: 2/6/2019 13:03
Date Collected: 2/4/2019 13:02
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By
Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.80J mg/I
2.0
0.14 10
2/7/2019 23:17
KB
d
Acetic Acid
0.65J mg/I
1.0
0.24 10
2/7/2019 23:17
KB
d
Propionic Acid
0.044U mg/I
1.0
0.044 10
2/7/2019 23:17
KB
d
Formic Acid
17 mg/I
2.0
0.48 10
2/7/2019 23:17
KB
d,B
Butyric Acid
0.047U mg/I
1.0
0.047 10
2/7/2019 23:17
KB
d
i-Pentanoic Acid
0.075U mg/I
1.0
0.075 10
2/7/2019 23:17
KB
d
Pentanoic Acid
0.12U mg/I
1.0
0.12 10
2/7/2019 23:17
KB
d
Report ID: 29413 - 1138441 Page 6 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 28 of 37

lacmnalyficalo
ANALYTICAL RESULTS
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294130003
Sample ID: MW-1R
Date Received: 2/6/2019 13:03
Date Collected: 2/4/2019 08:34
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.028J mg/I
0.20
0.014 1
2/8/2019 00:13
KB
Acetic Acid
0.024U mg/I
0.10
0.024 1
2/8/2019 00:13
KB
Propionic Acid
0.0044U mg/I
0.10
0.0044 1
2/8/2019 00:13
KB
Formic Acid
0.073J mg/I
0.20
0.048 1
2/8/2019 00:13
KB B
Butyric Acid
0.0047U mg/I
0.10
0.0047 1
2/8/2019 00:13
KB
i-Pentanoic Acid
0.0075U mg/I
0.10
0.0075 1
2/8/2019 00:13
KB
Pentanoic Acid
0.012U mg/I
0.10
0.012 1
2/8/2019 00:13
KB
Report ID: 29413 - 1138441 Page 7 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 29 of 37

lacmnalyficalo
ANALYTICAL RESULTS
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294130004
Sample ID: NES-1
Date Received: 2/6/2019 13:03
Date Collected: 2/4/2019 17:37
Matrix: Water
Parameters
Results Units
PQL
MDL DF
Analyzed
By Qualifiers
EDonors - PAES
Analysis Desc: AM23G
Analytical Method: AM23G
Lactic Acid
0.030J mg/I
0.20
0.014 1
2/8/2019 01:10
KB
Acetic Acid
0.024U mg/I
0.10
0.024 1
2/8/2019 01:10
KB
Propionic Acid
0.0044U mg/I
0.10
0.0044 1
2/8/2019 01:10
KB
Formic Acid
0.15J mg/I
0.20
0.048 1
2/8/2019 01:10
KB B
Butyric Acid
0.0047U mg/I
0.10
0.0047 1
2/8/2019 01:10
KB
i-Pentanoic Acid
0.0075U mg/I
0.10
0.0075 1
2/8/2019 01:10
KB
Pentanoic Acid
0.012U mg/I
0.10
0.012 1
2/8/2019 01:10
KB
Report ID: 29413 - 1138441 Page 8 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 30 of 37

lacmnalyficalo
ANALYTICAL RESULTS QUALIFIERS
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
B The analyte was detected in the associated blank.
d The analyte concentration was determined from a dilution.
Report ID: 29413 - 1138441
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 9 of 11
Page 31 of 37

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 29413 92416412 / BUTNER LF
QC Batch: EDON/3987 Analysis Method: AM23G
QC Batch Method: AM23G
Associated Lab Samples: 294130001, 294130002, 294130003, 294130004
METHOD BLANK: 59741
Blank Reporting
Parameter Units Result Limit Qualifiers
EDonors
Lactic Acid
mg/I
0.014U
0.014
Acetic Acid
mg/I
0.024U
0.024
Propionic Acid
mg/I
0.0044U
0.0044
Formic Acid
mg/I
0.056J
0.048 B
Butyric Acid
mg/I
0.0047U
0.0047
i-Pentanoic Acid
mg/I
0.0075U
0.0075
Pentanoic Acid
mg/I
0.012U
0.012
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY CONTROL SAMPLE: 59742
Spike
LCS
LCS
% Rec
Parameter Units
Conc.
Result
% Rec
Limits Qualifiers
EDonors
Lactic Acid mg/I
2
2.1
106
70-130
Acetic Acid mg/I
2
2.0
101
70-130
Propionic Acid mg/I
2
2.0
99
70-130
Formic Acid mg/I
2
2.1
107
70-130 B
Butyric Acid mg/I
2
2.0
100
70-130
i-Pentanoic Acid mg/I
2
1.9
97
70-130
Pentanoic Acid mg/I
2
1.9
97
70-130
Report ID: 29413 - 1138441
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 10 of 11
Page 32 of 37

lacmnalyficalo
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 29413 92416412 / BUTNER LF
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Prep Method Prep Batch Analysis Method
Analysis
Batch
294130001
3902-MW2R
AM23G
EDON/3987
294130002
3902-MW3R
AM23G
EDON/3987
294130003
MW-1 R
AM23G
EDON/3987
294130004
NES-1
AM23G
EDON/3987
Report ID: 29413 - 1138441
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 11 of 11
Page 33 of 37

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Page 34 of 37

Cooler Receipt Form
064-f cr-
Client Name: 1 r�� Project: Lab Work Order:
A. Shipping/Container Information (circle appropriate response)
Courier: Fed Ex UPS USPS Client Other: Air bill Present: Yes No
Tracking Number: " �% ef- 1 C, O6
Custody Seat on Cooler/Box Present: I Yes No Seals Intact: Yes) No
Cooler/Box Packing Material: BVfble Wra ' Absorbent Foam Other:
Type of Ice: Wet Blue None Ice Intact:,/ Ye Melted
rU
Cooler Temperature:_ Radiation Screened: Yes No Chain of Custody Present: es No
Comments:
B. Laboratory Assignment/tog-in (check appropriate response)
YES
NO
N/A
Comment
Reference non -Conformance
Chain of Custody properly filled out
r
Chain of Custody relinquished
-i
Sampler Name & Signature on COC
Containers intact
Were samples in separate bags
Sample container labels match COC
Sample name/date and time collected
L/
Sufficient volume provided
PAES containers used
Are containers properly preserved for the requested testing?
(as labeled)
If an unknown preservation state, were containers checked?
Exception: VOA's coliform
If yes, see pH form.
Was volume for dissolved testing field filtered, as noted on
the COC? Was volume received in a preserved container?
v
Headspace present?
Comments:
Cooler contents examines!/received by: Date: ` ��
Project Manager Review : Date:
F-PAE-C�-009-rev.01, 30�ct2017
Page 35 of 37

Date: 6 - / cr
NON-CONFORMANCE FORM
PAES Work Order #: 02
Time of Receipt: 1 " 0-0 Receiver: /" '-f
C i i enl:
REASON FOR NON-COMFORMANCE:
lie-e. S PC I
ACTION TAKEN:
Client name: Cif
datf n
Customer Service Initials:
.F-PAE-Q-014-re-v.00, 20 Nov2014
/C.. , f I r,
Date: j Time: qt)
Date: 2,/-
Page 36 of 37

Page 1 of 1
Emma Louis - 92416412 Sample Login
From: Emma Louis
To: Nicole Gasiorowski
Subject: 92416412 Sample Login
Hi Nicole,
Please see the attached sample login acknowledgment for the project above. Additionally, head space was
noted in 2 vials for sample NES-1. We will qualify if necessary and proceed.
Thank you
Emma Louis
Project Coordinator
Pace Analytical Energy Services, LLC
220 William Pitt Way
Pittsburgh, PA 15238
412-826-2378 (0) l 412-826-5245 (Main)
www.pacelabs.com
Page 37 of 37
about:blank 2/6/2019

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 15, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Dissolved Hydrogen
Pace Project No.: 92416420
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
Some analyses have been subcontracted outside of the Pace Network. The subcontracted
laboratory report has been attached.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
�pQ ACrfFO
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
9e0 without the written consent of Pace Analytical Services, LLC.
Page 1 of 17

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Dissolved Hydrogen
Pace Project No.: 92416420
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92416420001
3902-MW1R
Water
02/04/1910:24
02/05/1910:10
92416420002
3902-MW2R
Water
02/04/1915:52
02/05/1910:10
92416420003
3902-MW3R
Water
02/04/1914:15
02/05/1910:10
92416420004
3902-NES-1
Water
02/04/1918:30
02/05/1910:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 2 of 17

Document Name:
Document Revised: February 7, 2018
,,,
Sample Condition Upon Rece€pt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
:-f c7Cr'gf18��/hC�l
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving samples:
Asheville ® Eden[] Greenwood [] Huntersville ❑ Raleigh❑ Mechanicsville❑
Sample Condition Clie t Name: W0# : 92416420
a7 � Project 1#:
Ul ;L l Y Le,e)r 1 110
Courier: Fed'Ex ❑UPS /❑USPS Client
❑ INCommercial [--]pace f ❑1111111111111111111
Other:
L92415420
Custody Seal Present? ❑Yes DINo Seals Intact? 7(�Yes ❑No
. bate/Initials Person Examining Contents:-TD�- t
Packing Material: OBubble Wrap Bubble Bags []None ❑ Other
Thermometer;
i•' `~ '' 1 Type of Ice: Diver❑Blue
❑IRGun ID: f. ��`t
Cooler Temp (°C): /V//t Correction Factor: Add/Subtract (°C)
Cooler Temp Corrected (°C): IV /A
USDA Regulated Soil (dN/A, w seer• sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC (check maps)?
[-]Yes ❑No
Biological Tissue Frozen?
EfN�ne ❑Yes ❑No ffN/A
Temp should be above freezing to 6°C
❑Samples out of temp criteria. Samples on ice, cooling process
has begun
Did samples originate from a foreign source (internationally,
including Hawaii and Puerto Rico)? ❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
Des
❑No ❑N/A
1.
Samples Arrived within Hold Time?[r]�es
❑No []N/A
2.
Short Hold Time Analysis (<72 hr.)?
Des
o ❑N/A
3.
Rush Turn Around Time Requested?
❑Yes
[?]No ❑N/A
4.
Sufficient Volume?
f,Yes
[:]No ❑N/A
5.
Correct Containers Used?
-Pace Containers Used?
O'Yes
ffYes
❑No [I NIA
❑No ❑N/A
6.
Containers Intact?
121 e-
❑No El N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
❑No ErN/A
S.
Sample Labels Match COC?
-Includes Date/Time/ID/Analysis Matrix:
[]Yes
W-
[]No ❑N/A
9.
Headspace in VOA Vials (>5-6mm)?
[-]Yes
❑No
N/A
10,
Trip Blank Present?
Trip Blank Custody Seals Present?
❑Yes
❑Yes
❑i
❑No
N/A
id/A
11.
COMMENTS/SAMPLE DISCREPANCY
Lot ID of split containers:
CLIENT NOTIFICATION/RESOLUTION
Person contacted: Date/Time:
Project Manager SCURF Review: Nt zi�
Project Manager SRF Review: Nffl-&
Field Data Required? I]Yes �JC No
Date: 7-15 )!g
Date; Z-S_I t 1
Page 3of17

1 Document Name: Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR) Page 1 of 2
2'acaCB�llalyta( Document l Issuing Authorlty;
F-CAR-CS-033-Rev.06 pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
"Bottom half of box is to list number of bottle
Project # W0# ; 92416424
PM: NMG Due Date: 02/19/19
CLIENT: 92-Joyce Eng
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Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form W1ill he sent to the North Carolina DE}IpiR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 4 of 17

TEMP in C
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Page
5 of 17

lacmnalyficalo
February 15, 2019
Nicole Gasiorowski
Pace Analytical Services, Inc.
9800 Kincey Avenue
Suite 100
Huntersville, NC 28078
RE: 92416420 / BUTNER
Pace Workorder. 29406
Dear Nicole Gasiorowski:
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Enclosed are the analytical results for sample(s) received by the laboratory on Wednesday, February 06, 2019.
Results reported herein conform to the most current NELAC standards, where applicable, unless otherwise
narrated in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
Ruth Welsh 02/15/2019
[e-mail]
Customer Service Representative
Enclosures
As a valued client we would appreciate your comments on our service.
Please email [e-mail].
Report ID: 29406 - 1139074
F` CERTIFICATE OF ANALYSIS
ne"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Total Number of Pages 122
Page 1 of 11
Page 6 of 17

Pace Analytical Energy Services LLC
220 William Pitt Way
.,-- A__1.X__1 o Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
LABORATORY ACCREDITATIONS & CERTIFICATIONS
Accreditor: Pennsylvania Department of Environmental Protection, Bureau of Laboratories
Accreditation ID: 02-00538
Scope: NELAP Non -Potable Water
Accreditor:
West Virginia Department of Environmental Protection, Division of Water and Waste
Management
Accreditation ID:
395
Scope:
Non -Potable Water
Accreditor:
South Carolina Department of Health and Environmental Control, Office of Environmental
Laboratory Certification
Accreditation ID:
89009003
Scope:
Clean Water Act (CWA); Resource Conservation and Recovery Act (RCRA)
Accreditor:
State of Virginia
Accreditation ID:
460201
Scope:
Non -Potable Water
Accreditor:
NELAP: New Jersey, Department of Environmental Protection
Accreditation ID:
PA026
Scope:
Non -Potable Water
Accreditor:
NELAP: New York, Department of Health Wadsworth Center
Accreditation ID:
11815
Scope:
Non -Potable Water
Accreditor:
State of Connecticut, Department of Public Health, Division of Environmental Health
Accreditation ID:
PH-0263
Scope:
Clean Water Act (CWA) Resource Conservation and Recovery Act (RCRA)
Accreditor:
NELAP: Texas, Commission on Environmental Quality
Accreditation ID:
T104704453-09-TX
Scope:
Non -Potable Water
Accreditor:
State of New Hampshire
Accreditation ID:
299409
Scope:
Non -potable water
Accreditor:
State of Georgia
Accreditation ID:
Chapter 391-3-26
Scope:
As per the Georgia EPD Rules and Regulations for Commercial Laboratories, PAES is
accredited by the Pennsylvania Department of Environmental Protection Bureau of
Laboratories under the National Environmental Laboratory Approval Program (NELAC).
Report ID: 29406 - 1139074
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 2 of 11
Page 7 of 17

lacmnalyficalo
SAMPLE SUMMARY
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Matrix
Date Collected
Date Received
294060001
3902-MW1R
Bubble Strip
2/4/2019 10:24
2/6/2019 11:00
294060002
3902-MW2R
Bubble Strip
2/4/2019 15:52
2/6/2019 11:00
294060003
3902-MW3R
Bubble Strip
2/4/2019 14:15
2/6/2019 11:00
294060004
3902-NES-1
Bubble Strip
2/4/2019 18:30
2/6/2019 11:00
Report ID: 29406 - 1139074
4nela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 3 of 11
Page 8 of 17

lacmnalyficalo
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294060001 Date Received: 2/6/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-MW1R Date Collected: 2/4/2019 10:24
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 6.7 nM 1.0 0.65 1 2/13/2019 08:50 TD n
Report ID: 29406 - 1139074 Page 4 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 9 of 17

lacmnalyficalo
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294060002 Date Received: 2/6/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-MW2R Date Collected: 2/4/2019 15:52
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 7.6 nM 1.0 0.65 1 2/13/2019 09:02 TD n
Report ID: 29406 - 1139074 Page 5 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 10 of 17

lacmnalyficalo
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294060003 Date Received: 2/6/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-MW3R Date Collected: 2/4/2019 14:15
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 7.4 nM 1.0 0.65 1 2/13/2019 09:14 TD n
Report ID: 29406 - 1139074 Page 6 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 11 of 17

lacmnalyficalo
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID: 294060004 Date Received: 2/6/2019 11:00 Matrix: Bubble Strip
Sample ID: 3902-NES-1 Date Collected: 2/4/2019 18:30
Parameters Results Units PQL MDL DF Analyzed By Qualifiers
RISK - PAES
Analysis Desc: AM20GAX Analytical Method: AM20GAX
Hydrogen 6.8 nM 1.0 0.65 1 2/13/2019 09:27 TD n
Report ID: 29406 - 1139074 Page 7 of 11
F` CERTIFICATE OF ANALYSIS
nei"`~ This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 12 of 17

lacmnalyficalo
ANALYTICAL RESULTS QUALIFIERS
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
DEFINITIONS/QUALIFIERS
MDL Method Detection Limit. Can be used synonymously with LOD; Limit Of Detection.
PQL Practical Quanitation Limit. Can be used synonymously with LOQ; Limit Of Quantitation.
ND Not detected at or above reporting limit.
DF Dilution Factor.
S Surrogate.
RPD Relative Percent Difference.
% Rec Percent Recovery.
U Indicates the compound was analyzed for, but not detected at or above the noted concentration.
J Estimated concentration greater than the set method detection limit (MDL) and less than the set reporting limit (PQL).
n The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 29406 - 1139074
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 8 of 11
Page 13 of 17

lacmnalyficalo
QUALITY CONTROL DATA
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
QC Batch: DISG/7367 Analysis Method: AM20GAX
QC Batch Method: AM20GAX
Associated Lab Samples: 294060001, 294060002, 294060003, 294060004
METHOD BLANK: 59777
Blank Reporting
Parameter Units Result Limit Qualifiers
RISK
Hydrogen nM 0.65U 0.65 n
LABORATORY CONTROL SAMPLE & LCSD: 59778 59779
Spike LCS LCSD LCS LCSD % Rec Max
Parameter Units Conc. Result Result % Rec % Rec Limit RPD RPD Qualifiers
RISK
Hydrogen nM 24 22 21 89 88 80-120 1.1 20 n
Report ID: 29406 - 1139074
.4r-tielac�,
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 9 of 11
Page 14 of 17

lacmnalyficalo
QUALITY CONTROL DATA QUALIFIERS
Workorder: 29406 92416420 / BUTNER
QUALITY CONTROL PARAMETER QUALIFIERS
The laboratory does not hold NELAP/TNI accreditation for this method or analyte.
Report ID: 29406 - 1139074
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Page 10 of 11
Page 15 of 17

lacmnalyficalo
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Workorder: 29406 92416420 / BUTNER
Pace Analytical Energy Services LLC
220 William Pitt Way
Pittsburgh, PA 15238
Phone: [phone]
Fax: [phone]
Lab ID
Sample ID
Prep Method Prep Batch Analysis Method
Analysis
Batch
294060001
3902-MW1R
AM20GAX
DISG/7367
294060002
3902-MW2R
AM20GAX
DISG/7367
294060003
3902-MW3R
AM20GAX
DISG/7367
294060004
3902-NES-1
AM20GAX
DISG/7367
Report ID: 29406 - 1139074
4r-tiela(f
CERTIFICATE OF ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Energy Services LLC.
Page 11 of 11
Page 16 of 17

Q,.;t.:
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Page 17 of 17

aceAnalytical
_pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
February 15, 2019
Mr. Van Burbach
Joyce Engineering -Greensboro
2211 West Meadowview Rd
Boone Bldg, Suite 101
Greensboro, NC 27407
RE: Project: Butner Surface Water
Pace Project No.: 92416422
Dear Mr. Burbach:
Enclosed are the analytical results for sample(s) received by the laboratory on February 05, 2019.
The results relate only to the samples included in this report. Results reported herein conform to the
most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual,
where applicable, unless otherwise noted in the body of the report.
If you have any questions concerning this report, please feel free to contact me.
Sincerely,
��i Flo _ _.1I , .�:
Nicole Gasiorowski
[e-mail]
[phone]
Project Manager
Enclosures
cc: Van Burbach, Joyce Engineering -NC
Gretta Eller, LaBella Associates, D.P.C.
Daniel Girdner, LaBella Associates, D.P.C.
Rochelle Mesubed, Joyce Engineering
Miguel Vazquez, Joyce Engineering
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 1 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
Project: Butner Surface Water
Pace Project No.: 92416422
Charlotte Certification IDs
9800 Kincey Ave. Ste 100, Huntersville, NC 28078
Louisiana/NELAP Certification # LA170028
North Carolina Drinking Water Certification #: 37706
North Carolina Field Services Certification #: 5342
North Carolina Wastewater Certification #: 12
Asheville Certification IDs
2225 Riverside Drive, Asheville, NC 28804
Florida/NELAP Certification #: E87648
Massachusetts Certification #: M-NC030
North Carolina Drinking Water Certification #: 37712
CERTIFICATIONS
South Carolina Certification #: 99006001
Florida/NELAP Certification #: E87627
Kentucky UST Certification #: 84
Virginia/VELAP Certification #: 460221
North Carolina Wastewater Certification #: 40
South Carolina Certification #: 99030001
Virginia/VELAP Certification #: 460222
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 2 of 24

aceAnalytical
—pacelabsxom
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE SUMMARY
Project: Butner Surface Water
Pace Project No.: 92416422
Lab ID
Sample ID
Matrix
Date Collected
Date Received
92416422001
92416422002
3902-SW1
3902-SW2
Water
Water
02/04/1918:01
02/04/1917:47
02/05/1910:10
02/05/1910:10
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 3 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SAMPLE ANALYTE COUNT
Project:
Pace Project No.:
Butner Surface Water
92416422
Analytes
Lab ID
Sample ID
Method
Analysts
Reported
Laboratory
92416422001
3902-SW1
EPA 6010D
IDS
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CL
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
92416422002
3902-SW2
EPA 6010D
DS
15
PASI-A
EPA6020B
JMW1
1
PASI-A
EPA 8260E
CL
50
PASI-C
EPA 8260B Mod.
DLK
3
PASI-C
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 4 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
SUMMARY OF DETECTION
Project:
Pace Project No.:
Butner Surface Water
92416422
Lab Sample ID
Client Sample ID
Method
Parameters
Result
Units
Report Limit
Analyzed Qualifiers
92416422001
3902-SW1
EPA 601 OD
Barium
29.1
ug/L
5.0
02/07/19 18:21
EPA 601 OD
Hardness, Total(SM 2340B)
57100
ug/L
662
02/07/19 18:21
EPA 601 OD
Vanadium
2.9J
ug/L
5.0
02/07/19 18:21
92416422002
3902-SW2
EPA 601 OD
Barium
33.1
ug/L
5.0
02/07/19 18:24
EPA 601 OD
Nickel
2.7J
ug/L
5.0
02/07/19 18:24
EPA 601 OD
Hardness, Total(SM 2340B)
85300
ug/L
662
02/07/19 18:24
EPA 601 OD
Vanadium
2.7J
ug/L
5.0
02/07/19 18:24
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC. Page 5 of 24

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Surface Water
Pace Project No.: 92416422
Sample: 3902-SW1 Lab ID: 92416422001 Collected: 02/04/19 18:01 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 02/15/2019 01:08 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:21
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:21
7440-38-2
29.1
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-39-3
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:21
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:21
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-48-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-50-8
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7439-92-1
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:21
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-22-4
57100
ug/L
662
662
1
02/06/19 03:58
02/07/19 18:21
2.9J
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:21
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:21
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:11 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
25.0
6.2
1
02/06/1919:42
67-64-1
ND
ug/L
10.0
0.90
1
02/06/1919:42
107-13-1
ND
ug/L
1.0
0.15
1
02/06/1919:42
71-43-2
ND
ug/L
1.0
0.34
1
02/06/1919:42
74-97-5
ND
ug/L
1.0
0.26
1
02/06/1919:42
75-27-4
ND
ug/L
1.0
0.62
1
02/06/1919:42
75-25-2
ND
ug/L
2.0
0.62
1
02/06/1919:42
74-83-9
ND
ug/L
5.0
3.3
1
02/06/1919:42
78-93-3
ND
ug/L
2.0
0.40
1
02/06/1919:42
75-15-0
ND
ug/L
1.0
0.22
1
02/06/1919:42
56-23-5
ND
ug/L
1.0
0.23
1
02/06/1919:42
108-90-7
ND
ug/L
1.0
0.49
1
02/06/1919:42
75-00-3
ND
ug/L
5.0
2.3
1
02/06/1919:42
67-66-3
ND
ug/L
1.0
0.39
1
02/06/1919:42
74-87-3
ND
ug/L
2.0
0.26
1
02/06/1919:42
96-12-8
ND
ug/L
1.0
0.41
1
02/06/1919:42
124-48-1
ND
ug/L
1.0
0.26
1
02/06/1919:42
106-93-4
ND
ug/L
1.0
0.46
1
02/06/1919:42
74-95-3
ND
ug/L
1.0
0.29
1
02/06/1919:42
95-50-1
ND
ug/L
1.0
0.26
1
02/06/1919:42
106-46-7
ND
ug/L
1.0
0.54
1
02/06/1919:42
110-57-6
ND
ug/L
1.0
0.27
1
02/06/1919:42
75-34-3
ND
ug/L
1.0
0.34
1
02/06/1919:42
107-06-2
ND
ug/L
1.0
0.24
1
02/06/1919:42
75-35-4
ND
ug/L
1.0
0.29
1
02/06/1919:42
156-59-2
ND
ug/L
1.0
0.25
1
02/06/1919:42
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 6 of 24

aceAnalytical
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9800 Kincey Ave. Suite 100
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ANALYTICAL RESULTS
Project: Butner Surface Water
Pace Project No.: 92416422
Sample: 3902-SW1 Lab ID: 92416422001 Collected: 02/04/19 18:01 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 01:08 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
5.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
102
%
70-130
103
%
70-130
99
%
70-130
Analytical Method: EPA 8260E Mod
ND ug/L 2.0
90 % 50-150
98 % 50-150
0.19
1
02/06/19 19:42
78-87-5
0.30
1
02/06/19 19:42
10061-01-5
0.31
1
02/06/19 19:42
10061-02-6
0.26
1
02/06/19 19:42
100-41-4
0.57
1
02/06/19 19:42
591-78-6
12.5
1
02/06/19 19:42
74-88-4
3.7
1
02/06/19 19:42
75-09-2
4.5
1
02/06/19 19:42
108-10-1
0.27
1
02/06/19 19:42
100-42-5
0.34
1
02/06/19 19:42
630-20-6
0.22
1
02/06/19 19:42
79-34-5
0.16
1
02/06/19 19:42
127-18-4
0.24
1
02/06/19 19:42
108-88-3
0.18
1
02/06/19 19:42
71-55-6
0.24
1
02/06/19 19:42
79-00-5
0.22
1
02/06/19 19:42
79-01-6
0.31
1
02/06/19 19:42
75-69-4
0.35
1
02/06/19 19:42
96-18-4
1.4
1
02/06/19 19:42
108-05-4
0.24
1
02/06/19 19:42
75-01-4
0.63
1
02/06/19 19:42
1330-20-7
1
02/06/19 19:42
460-00-4
1
02/06/19 19:42
17060-07-0
1
02/06/19 19:42
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/14/19 14:26 123-91-1
02/ 14/ 19 14:26 17060-07-0
02/14/1914:26 2037-26-5
Page 7 of 24

aceAnalytical
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ANALYTICAL RESULTS
Project: Butner Surface Water
Pace Project No.: 92416422
Sample: 3902-SW2 Lab ID: 92416422002 Collected: 02/04/19 17:47 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
6010 MET ICP
Antimony
Arsenic
Barium
Beryllium
Cadmium
Chromium
Cobalt
Copper
Lead
Nickel
Selenium
Silver
Hardness, Total(SM 2340B)
Vanadium
Zinc
6020 MET ICPMS
Thallium
8260 MSV Low Level Landfill
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
1,2-Dibromo-3-chloropropane
Dibromochloromethane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
trans-1,4-Dichloro-2-butene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
cis-1,2-Dichloroethene
trans-1,2-Dichloroethene
Date: 02/15/2019 01:08 PM
Analytical Method: EPA 6010D Preparation Method: EPA 3010A
ND
ug/L
5.0
3.9
1
02/06/19 03:58
02/07/19 18:24
7440-36-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:24
7440-38-2
33.1
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-39-3
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:24
7440-41-7
ND
ug/L
1.0
0.50
1
02/06/19 03:58
02/07/19 18:24
7440-43-9
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-47-3
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-48-4
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-50-8
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7439-92-1
2.7J
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-02-0
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:24
7782-49-2
ND
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-22-4
85300
ug/L
662
662
1
02/06/19 03:58
02/07/19 18:24
2.7J
ug/L
5.0
2.5
1
02/06/19 03:58
02/07/19 18:24
7440-62-2
ND
ug/L
10.0
5.0
1
02/06/19 03:58
02/07/19 18:24
7440-66-6
Analytical Method: EPA 6020E Preparation Method: EPA 3010A
ND ug/L 0.10 0.060 1 02/06/19 04:28 02/06/19 13:28 7440-28-0
Analytical Method: EPA 8260E
ND
ug/L
25.0
6.2
1
02/06/19 20:01
67-64-1
ND
ug/L
10.0
0.90
1
02/06/19 20:01
107-13-1
ND
ug/L
1.0
0.15
1
02/06/19 20:01
71-43-2
ND
ug/L
1.0
0.34
1
02/06/19 20:01
74-97-5
ND
ug/L
1.0
0.26
1
02/06/19 20:01
75-27-4
ND
ug/L
1.0
0.62
1
02/06/19 20:01
75-25-2
ND
ug/L
2.0
0.62
1
02/06/19 20:01
74-83-9
ND
ug/L
5.0
3.3
1
02/06/19 20:01
78-93-3
ND
ug/L
2.0
0.40
1
02/06/19 20:01
75-15-0
ND
ug/L
1.0
0.22
1
02/06/19 20:01
56-23-5
ND
ug/L
1.0
0.23
1
02/06/19 20:01
108-90-7
ND
ug/L
1.0
0.49
1
02/06/19 20:01
75-00-3
ND
ug/L
5.0
2.3
1
02/06/19 20:01
67-66-3
ND
ug/L
1.0
0.39
1
02/06/19 20:01
74-87-3
ND
ug/L
2.0
0.26
1
02/06/19 20:01
96-12-8
ND
ug/L
1.0
0.41
1
02/06/19 20:01
124-48-1
ND
ug/L
1.0
0.26
1
02/06/19 20:01
106-93-4
ND
ug/L
1.0
0.46
1
02/06/19 20:01
74-95-3
ND
ug/L
1.0
0.29
1
02/06/19 20:01
95-50-1
ND
ug/L
1.0
0.26
1
02/06/19 20:01
106-46-7
ND
ug/L
1.0
0.54
1
02/06/19 20:01
110-57-6
ND
ug/L
1.0
0.27
1
02/06/19 20:01
75-34-3
ND
ug/L
1.0
0.34
1
02/06/19 20:01
107-06-2
ND
ug/L
1.0
0.24
1
02/06/19 20:01
75-35-4
ND
ug/L
1.0
0.29
1
02/06/19 20:01
156-59-2
ND
ug/L
1.0
0.25
1
02/06/19 20:01
156-60-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 8 of 24

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
ANALYTICAL RESULTS
Project: Butner Surface Water
Pace Project No.: 92416422
Sample: 3902-SW2 Lab ID: 92416422002 Collected: 02/04/19 17:47 Received: 02/05/19 10:10 Matrix: Water
Report
Parameters Results Units Limit MDL DF Prepared Analyzed CAS No. Qual
8260 MSV Low Level Landfill
1,2-Dichloropropane
cis-1,3-Dichloropropene
trans- 1,3-Dichloropropene
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Toluene
1,1,1-Trichloroethane
1,1,2-Trichloroethane
Trichloroethene
Trichlorofluoromethane
1,2,3-Trichloropropane
Vinyl acetate
Vinyl chloride
Xylene (Total)
Surrogates
4-Bromofluorobenzene (S)
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
8260 MSV SIM
1,4-Dioxane (p-Dioxane)
Surrogates
1,2-Dichloroethane-d4 (S)
Toluene-d8 (S)
Date: 02/15/2019 01:08 PM
Analytical Method: EPA 8260E
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
5.0
ND
ug/L
20.0
ND
ug/L
5.0
ND
ug/L
5.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
1.0
ND
ug/L
2.0
ND
ug/L
1.0
ND
ug/L
1.0
98
%
70-130
103
%
70-130
100
%
70-130
Analytical Method: EPA 8260E Mod
ND ug/L 2.0
93 % 50-150
98 % 50-150
0.19
1
02/06/19 20:01
78-87-5
0.30
1
02/06/19 20:01
10061-01-5
0.31
1
02/06/19 20:01
10061-02-6
0.26
1
02/06/19 20:01
100-41-4
0.57
1
02/06/19 20:01
591-78-6
12.5
1
02/06/19 20:01
74-88-4
3.7
1
02/06/19 20:01
75-09-2
4.5
1
02/06/19 20:01
108-10-1
0.27
1
02/06/19 20:01
100-42-5
0.34
1
02/06/19 20:01
630-20-6
0.22
1
02/06/19 20:01
79-34-5
0.16
1
02/06/19 20:01
127-18-4
0.24
1
02/06/19 20:01
108-88-3
0.18
1
02/06/19 20:01
71-55-6
0.24
1
02/06/19 20:01
79-00-5
0.22
1
02/06/19 20:01
79-01-6
0.31
1
02/06/19 20:01
75-69-4
0.35
1
02/06/19 20:01
96-18-4
1.4
1
02/06/19 20:01
108-05-4
0.24
1
02/06/19 20:01
75-01-4
0.63
1
02/06/19 20:01
1330-20-7
1
02/06/19 20:01
460-00-4
1
02/06/19 20:01
17060-07-0
1
02/06/19 20:01
2037-26-5
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
02/13/19 16:22 123-91-1
02/ 13/ 19 16:22 17060-07-0
02/13/1916:22 2037-26-5
Page 9 of 24

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9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
QC Batch: 456556 Analysis Method: EPA 6010D
QC Batch Method: EPA 3010A Analysis Description: 6010 MET
Associated Lab Samples: 92416422001, 92416422002
METHOD BLANK: 2490699
Associated Lab Samples: 92416422001, 92416422002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed Qualifiers
Antimony
ug/L
ND
5.0
3.9
02/07/1917:43
Arsenic
ug/L
ND
10.0
5.0
02/07/1917:43
Barium
ug/L
ND
5.0
2.5
02/07/1917:43
Beryllium
ug/L
ND
1.0
0.50
02/07/1917:43
Cadmium
ug/L
ND
1.0
0.50
02/07/1917:43
Chromium
ug/L
ND
5.0
2.5
02/07/1917:43
Cobalt
ug/L
ND
5.0
2.5
02/07/1917:43
Copper
ug/L
ND
5.0
2.5
02/07/1917:43
Hardness, Total(SM 2340B)
ug/L
ND
662
662
02/07/19 17:43
Lead
ug/L
ND
5.0
2.5
02/07/1917:43
Nickel
ug/L
ND
5.0
2.5
02/07/1917:43
Selenium
ug/L
ND
10.0
5.0
02/07/1917:43
Silver
ug/L
ND
5.0
2.5
02/07/1917:43
Vanadium
ug/L
ND
5.0
2.5
02/07/1917:43
Zinc
ug/L
ND
10.0
5.0
02/07/1917:43
LABORATORY CONTROL SAMPLE:
2490700
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits Qualifiers
Antimony
ug/L
500
475
95
80-120
Arsenic
ug/L
500
439
88
80-120
Barium
ug/L
500
492
98
80-120
Beryllium
ug/L
500
494
99
80-120
Cadmium
ug/L
500
464
93
80-120
Chromium
ug/L
500
471
94
80-120
Cobalt
ug/L
500
462
92
80-120
Copper
ug/L
500
484
97
80-120
Hardness, Total(SM 2340B)
ug/L
33100
31400
95
80-120
Lead
ug/L
500
454
91
80-120
Nickel
ug/L
500
464
93
80-120
Selenium
ug/L
500
450
90
80-120
Silver
ug/L
250
248
99
80-120
Vanadium
ug/L
500
475
95
80-120
Zinc
ug/L
500
446
89
80-120
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 10 of 24

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
MATRIX SPIKE & MATRIX SPIKE
DUPLICATE:
2490701
2490702
MS
MSD
92416496001
Spike
Spike
MS
MSD
MS
MSD
% Rec
Max
Parameter
Units
Result
Conc.
Conc.
Result
Result
% Rec
% Rec
Limits
RPD
RPD Qual
Antimony
ug/L
ND
500
500
467
471
93
94
75-125
1
20
Arsenic
ug/L
ND
500
500
439
440
88
88
75-125
0
20
Barium
ug/L
14.8
500
500
501
494
97
96
75-125
1
20
Beryllium
ug/L
ND
500
500
487
481
97
96
75-125
1
20
Cadmium
ug/L
ND
500
500
464
465
93
93
75-125
0
20
Chromium
ug/L
ND
500
500
467
464
93
93
75-125
1
20
Cobalt
ug/L
ND
500
500
452
453
90
91
75-125
0
20
Copper
ug/L
0.010
500
500
485
481
95
94
75-125
1
20
mg/L
Hardness, Total(SM 2340B)
ug/L
893
33100
33100
32600
32300
96
95
75-125
1
Lead
ug/L
ND
500
500
449
449
90
90
75-125
0
20
Nickel
ug/L
ND
500
500
461
459
92
91
75-125
0
20
Selenium
ug/L
ND
500
500
471
479
94
96
75-125
2
20
Silver
ug/L
ND
250
250
246
246
98
98
75-125
0
20
Vanadium
ug/L
ND
500
500
463
465
93
93
75-125
0
20
Zinc
ug/L
0.013
500
500
458
459
89
89
75-125
0
20
mg/L
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 11 of 24

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
QC Batch: 456560
Analysis Method: EPA 6020B
QC Batch Method: EPA 3010A
Analysis Description: 6020 MET
Associated Lab Samples: 92416422001, 92416422002
METHOD BLANK: 2490711
Matrix: Water
Associated Lab Samples: 92416422001, 92416422002
Blank Reporting
Parameter Units
Result Limit MDL
Analyzed
Qualifiers
Thallium ug/L
ND 0.10 0.060
02/06/1913:04
LABORATORY CONTROL SAMPLE: 2490712
Spike LCS LCS
% Rec
Parameter Units
Conc. Result % Rec
Limits Qualifiers
Thallium ug/L
10 10.4 104
80-120
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490713
2490714
MS MSD
92416422001
Spike Spike MS MSD
MS MSD
% Rec Max
Parameter Units Result
Conc. Conc. Result Result
% Rec % Rec
Limits RPD RPD Qual
Thallium ug/L ND
10 10 10.4 10.4
104 104
75-125 0 20
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 12 of 24

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
QC Batch: 456738 Analysis Method: EPA 8260B
QC Batch Method: EPA 8260E Analysis Description: 8260 MSV Low Level Landfill
Associated Lab Samples: 92416422001, 92416422002
METHOD BLANK: 2491742
Associated Lab Samples: 92416422001, 92416422002
Parameter Units
Matrix:
Blank
Result
Water
Reporting
Limit
MDL
Analyzed
1,1,1,2-Tetrachloroethane
ug/L
ND
1.0
0.34
02/06/19 18:28
1,1,1-Trichloroethane
ug/L
ND
1.0
0.18
02/06/19 18:28
1,1,2,2-Tetrachloroethane
ug/L
ND
1.0
0.22
02/06/19 18:28
1,1,2-Trichloroethane
ug/L
ND
1.0
0.24
02/06/19 18:28
1,1-Dichloroethane
ug/L
ND
1.0
0.27
02/06/19 18:28
1,1-Dichloroethene
ug/L
ND
1.0
0.24
02/06/19 18:28
1,2,3-Trichloropropane
ug/L
ND
1.0
0.35
02/06/19 18:28
1,2-Dibromo-3-chloropropane
ug/L
ND
2.0
0.26
02/06/19 18:28
1,2-Dibromoethane (EDB)
ug/L
ND
1.0
0.26
02/06/19 18:28
1,2-Dichlorobenzene
ug/L
ND
1.0
0.29
02/06/19 18:28
1,2-Dichloroethane
ug/L
ND
1.0
0.34
02/06/19 18:28
1,2-Dichloropropane
ug/L
ND
1.0
0.19
02/06/19 18:28
1,4-Dichlorobenzene
ug/L
ND
1.0
0.26
02/06/19 18:28
2-Butanone (MEK)
ug/L
ND
5.0
3.3
02/06/19 18:28
2-Hexanone
ug/L
ND
5.0
0.57
02/06/19 18:28
4-Methyl-2-pentanone (MIBK)
ug/L
ND
5.0
4.5
02/06/19 18:28
Acetone
ug/L
ND
25.0
6.2
02/06/19 18:28
Acrylonitrile
ug/L
ND
10.0
0.90
02/06/19 18:28
Benzene
ug/L
ND
1.0
0.15
02/06/19 18:28
Bromochloromethane
ug/L
ND
1.0
0.34
02/06/19 18:28
Bromodichloromethane
ug/L
ND
1.0
0.26
02/06/19 18:28
Bromoform
ug/L
ND
1.0
0.62
02/06/19 18:28
Bromomethane
ug/L
ND
2.0
0.62
02/06/19 18:28
Carbon disulfide
ug/L
ND
2.0
0.40
02/06/19 18:28
Carbon tetrachloride
ug/L
ND
1.0
0.22
02/06/19 18:28
Chlorobenzene
ug/L
ND
1.0
0.23
02/06/19 18:28
Chloroethane
ug/L
ND
1.0
0.49
02/06/19 18:28
Chloroform
ug/L
ND
5.0
2.3
02/06/19 18:28
Chloromethane
ug/L
ND
1.0
0.39
02/06/19 18:28
cis-1,2-Dichloroethene
ug/L
ND
1.0
0.29
02/06/19 18:28
cis-1,3-Dichloropropene
ug/L
ND
1.0
0.30
02/06/19 18:28
Dibromochloromethane
ug/L
ND
1.0
0.41
02/06/19 18:28
Dibromomethane
ug/L
ND
1.0
0.46
02/06/19 18:28
Ethylbenzene
ug/L
ND
1.0
0.26
02/06/19 18:28
lodomethane
ug/L
ND
20.0
12.5
02/06/19 18:28
Methylene Chloride
ug/L
ND
5.0
3.7
02/06/19 18:28
Styrene
ug/L
ND
1.0
0.27
02/06/19 18:28
Tetrachloroethene
ug/L
ND
1.0
0.16
02/06/19 18:28
Toluene
ug/L
ND
1.0
0.24
02/06/19 18:28
trans-1,2-Dichloroethene
ug/L
ND
1.0
0.25
02/06/19 18:28
trans- 1,3-Dichloropropene
ug/L
ND
1.0
0.31
02/06/19 18:28
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 13 of 24

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
METHOD BLANK: 2491742
Matrix:
Water
Associated Lab Samples:
92416422001, 92416422002
Blank
Reporting
Parameter
Units
Result
Limit MDL
trans-1,4-Dichloro-2-butene
ug/L
ND
1.0
Trichloroethene
ug/L
ND
1.0
Trichlorofluoromethane
ug/L
ND
1.0
Vinyl acetate
ug/L
ND
2.0
Vinyl chloride
ug/L
ND
1.0
Xylene (Total)
ug/L
ND
1.0
1,2-Dichloroethane-d4 (S)
%
102
70-130
4-Bromofluorobenzene (S)
%
96
70-130
Toluene-d8 (S)
%
100
70-130
Analyzed
0.54
02/06/19 18:28
0.22
02/06/19 18:28
0.31
02/06/19 18:28
1.4
02/06/19 18:28
0.24
02/06/19 18:28
0.63
02/06/19 18:28
02/06/19 18:28
02/06/19 18:28
02/06/19 18:28
LABORATORY CONTROL SAMPLE:
Parameter
2491743
Units
Spike
Conc.
LCS
Result
LCS
% Rec
% Rec
Limits
1,1,1,2-Tetrachloroethane
ug/L
50
48.2
96
70-130
1,1,1-Trichloroethane
ug/L
50
50.8
102
70-130
1,1,2,2-Tetrachloroethane
ug/L
50
49.6
99
70-130
1,1,2-Trichloroethane
ug/L
50
50.1
100
70-130
1,1-Dichloroethane
ug/L
50
51.2
102
70-130
1,1-Dichloroethene
ug/L
50
54.2
108
70-130
1,2,3-Trichloropropane
ug/L
50
47.9
96
70-130
1,2-Dibromo-3-chloropropane
ug/L
50
49.0
98
70-130
1,2-Dibromoethane (EDB)
ug/L
50
50.1
100
70-130
1,2-Dichlorobenzene
ug/L
50
51.2
102
70-130
1,2-Dichloroethane
ug/L
50
50.5
101
70-130
1,2-Dichloropropane
ug/L
50
48.8
98
70-130
1,4-Dichlorobenzene
ug/L
50
50.4
101
70-130
2-Butanone (MEK)
ug/L
100
111
111
64-135
2-Hexanone
ug/L
100
103
103
66-135
4-Methyl-2-pentanone (MIBK)
ug/L
100
104
104
70-130
Acetone
ug/L
100
109
109
61-157
Acrylonitrile
ug/L
250
286
115
61-143
Benzene
ug/L
50
48.8
98
70-130
Bromochloromethane
ug/L
50
59.1
118
70-130
Bromodichloromethane
ug/L
50
48.4
97
70-130
Bromoform
ug/L
50
41.8
84
70-130
Bromomethane
ug/L
50
47.6
95
38-130
Carbon disulfide
ug/L
50
53.5
107
68-130
Carbon tetrachloride
ug/L
50
48.9
98
70-130
Chlorobenzene
ug/L
50
48.1
96
70-130
Chloroethane
ug/L
50
46.3
93
37-142
Chloroform
ug/L
50
51.0
102
70-130
Chloromethane
ug/L
50
51.4
103
48-130
cis-1,2-Dichloroethene
ug/L
50
52.0
104
70-130
cis-1,3-Dichloropropene
ug/L
50
49.5
99
70-130
Qualifiers
Qualifiers
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 14 of 24

aceAnalytical
-pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
LABORATORY CONTROL SAMPLE:
2491743
Spike
LCS
LCS
% Rec
Parameter
Units
Conc.
Result
% Rec
Limits
Qualifiers
Dibromochloromethane
ug/L
50
49.0
98
70-130
Dibromomethane
ug/L
50
47.2
94
70-130
Ethylbenzene
ug/L
50
48.7
97
70-130
lodomethane
ug/L
100
103
103
40-130
Methylene Chloride
ug/L
50
48.6
97
67-132
Styrene
ug/L
50
49.1
98
70-130
Tetrachloroethene
ug/L
50
45.0
90
69-130
Toluene
ug/L
50
47.8
96
70-130
trans-1,2-Dichloroethene
ug/L
50
52.5
105
70-130
trans- 1,3-Dichloropropene
ug/L
50
50.0
100
70-130
trans-1,4-Dichloro-2-butene
ug/L
50
49.8
100
35-189
Trichloroethene
ug/L
50
48.7
97
70-130
Trichlorofluoromethane
ug/L
50
54.1
108
63-130
Vinyl acetate
ug/L
100
113
113
55-143
Vinyl chloride
ug/L
50
56.0
112
70-131
Xylene (Total)
ug/L
150
146
98
70-130
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
100
70-130
Toluene-d8(S)
%
101
70-130
MATRIX SPIKE SAMPLE:
2491745
92416424002
Spike
MS
MS
% Rec
Parameter
Units
Result
Conc.
Result
% Rec
Limits Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
20
21.4
107
73-134
1,1,1-Trichloroethane
ug/L
ND
20
22.2
111
82-143
1,1,2,2-Tetrachloroethane
ug/L
ND
20
21.7
108
70-136
1,1,2-Trichloroethane
ug/L
ND
20
22.2
111
70-135
1,1-Dichloroethane
ug/L
ND
20
22.9
115
70-139
1,1-Dichloroethene
ug/L
ND
20
24.2
121
70-154
1,2,3-Trichloropropane
ug/L
ND
20
25.2
126
71-137
1,2-Dibromo-3-chloropropane
ug/L
ND
20
20.3
101
65-134
1,2-Dibromoethane (EDB)
ug/L
ND
20
21.7
109
70-137
1,2-Dichlorobenzene
ug/L
ND
20
21.6
108
70-133
1,2-Dichloroethane
ug/L
ND
20
21.5
107
70-137
1,2-Dichloropropane
ug/L
ND
20
22.4
112
70-140
1,4-Dichlorobenzene
ug/L
ND
20
21.4
107
70-133
2-Butanone (MEK)
ug/L
ND
40
51.0
128
60-139
2-Hexanone
ug/L
ND
40
44.1
110
65-138
4-Methyl-2-pentanone (MIBK)
ug/L
ND
40
45.3
113
65-135
Acetone
ug/L
ND
40
50.3
126
60-148
Acrylonitrile
ug/L
ND
100
121
121
64-147
Benzene
ug/L
ND
20
22.8
114
70-151
Bromochloromethane
ug/L
ND
20
24.1
121
70-141
Bromodichloromethane
ug/L
ND
20
20.9
105
70-138
Bromoform
ug/L
ND
20
17.8
89
63-130
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 15 of 24

aceAnalytical
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Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
MATRIX SPIKE SAMPLE:
Parameter
2491745
Units
92416424002
Result
Spike
Conc.
MS
Result
MS
% Rec
% Rec
Limits Qualifiers
Bromomethane
ug/L
ND
20
17.5
88
15-152
Carbon disulfide
ug/L
ND
20
23.6
118
69-149
Carbon tetrachloride
ug/L
ND
20
21.9
109
70-143
Chlorobenzene
ug/L
ND
20
21.6
108
70-138
Chloroethane
ug/L
ND
20
27.3
137
52-163
Chloroform
ug/L
ND
20
21.7
108
70-139
Chloromethane
ug/L
ND
20
22.5
112
41-139
cis-1,2-Dichloroethene
ug/L
ND
20
22.5
112
70-141
cis-1,3-Dichloropropene
ug/L
ND
20
21.3
106
70-137
Dibromochloromethane
ug/L
ND
20
21.0
105
70-134
Dibromomethane
ug/L
ND
20
20.2
101
70-138
Ethylbenzene
ug/L
ND
20
22.1
110
66-153
lodomethane
ug/L
ND
40
41.7
104
20-138
Methylene Chloride
ug/L
ND
20
20.3
101
42-159
Styrene
ug/L
ND
20
21.6
108
70-135
Tetrachloroethene
ug/L
ND
20
20.4
102
59-143
Toluene
ug/L
ND
20
22.1
110
59-148
trans-1,2-Dichloroethene
ug/L
ND
20
23.1
115
70-146
trans- 1,3-Dichloropropene
ug/L
ND
20
20.7
104
70-135
trans-1,4-Dichloro-2-butene
ug/L
ND
20
16.7
84
47-135
Trichloroethene
ug/L
ND
20
22.3
111
70-147
Trichlorofluoromethane
ug/L
ND
20
24.7
124
70-148
Vinyl acetate
ug/L
ND
40
38.7
97
49-151
Vinyl chloride
ug/L
ND
20
25.5
128
70-156
Xylene (Total)
ug/L
ND
60
66.0
110
63-158
1,2-Dichloroethane-d4 (S)
%
103
70-130
4-Bromofluorobenzene (S)
%
101
70-130
Toluene-d8(S)
%
102
70-130
SAMPLE DUPLICATE: 2491744
Parameter
Units
92416424001
Result
Dup
Result RPD
Max
RPD Qualifiers
1,1,1,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,1-Trichloroethane
ug/L
ND
ND
30
1,1,2,2-Tetrachloroethane
ug/L
ND
ND
30
1,1,2-Trichloroethane
ug/L
ND
ND
30
1,1-Dichloroethane
ug/L
0.36J
0.36J
30
1,1-Dichloroethene
ug/L
ND
ND
30
1,2,3-Trichloropropane
ug/L
ND
ND
30
1,2-Dibromo-3-chloropropane
ug/L
ND
ND
30
1,2-Dibromoethane (EDB)
ug/L
ND
ND
30
1,2-Dichlorobenzene
ug/L
ND
ND
30
1,2-Dichloroethane
ug/L
ND
ND
30
1,2-Dichloropropane
ug/L
ND
ND
30
1,4-Dichlorobenzene
ug/L
ND
ND
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 16 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
SAMPLE DUPLICATE: 2491744
Parameter
Units
92416424001
Result
Dup
Result RPD
2-Butanone (MEK)
ug/L
ND
ND
2-Hexanone
ug/L
ND
ND
4-Methyl-2-pentanone (MIBK)
ug/L
ND
ND
Acetone
ug/L
ND
ND
Acrylonitrile
ug/L
ND
ND
Benzene
ug/L
ND
ND
Bromochloromethane
ug/L
ND
ND
Bromodichloromethane
ug/L
ND
ND
Bromoform
ug/L
ND
ND
Bromomethane
ug/L
ND
ND
Carbon disulfide
ug/L
ND
ND
Carbon tetrachloride
ug/L
ND
ND
Chlorobenzene
ug/L
1.3
1.3 5
Chloroethane
ug/L
0.79J
1.0J
Chloroform
ug/L
ND
ND
Chloromethane
ug/L
ND
ND
cis-1,2-Dichloroethene
ug/L
ND
ND
cis-1,3-Dichloropropene
ug/L
ND
ND
Dibromochloromethane
ug/L
ND
ND
Dibromomethane
ug/L
ND
ND
Ethylbenzene
ug/L
ND
ND
lodomethane
ug/L
ND
ND
Methylene Chloride
ug/L
ND
ND
Styrene
ug/L
ND
ND
Tetrachloroethene
ug/L
ND
ND
Toluene
ug/L
ND
ND
trans-1,2-Dichloroethene
ug/L
ND
ND
trans- 1,3-Dichloropropene
ug/L
ND
ND
trans-1,4-Dichloro-2-butene
ug/L
ND
ND
Trichloroethene
ug/L
ND
ND
Trichlorofluoromethane
ug/L
ND
ND
Vinyl acetate
ug/L
ND
ND
Vinyl chloride
ug/L
ND
ND
Xylene (Total)
ug/L
ND
ND
1,2-Dichloroethane-d4 (S)
%
101
103 2
4-Bromofluorobenzene (S)
%
98
100 1
Toluene-d8(S)
%
100
101 2
Max
RPD Qualifiers
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 17 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
QC Batch: 457598 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92416422002
METHOD BLANK: 2495501
Associated Lab Samples: 92416422002
Parameter
Units
1,4-Dioxane (p-Dioxane)
ug/L
1,2-Dichloroethane-d4 (S)
%
Toluene-d8 (S)
%
Matrix: Water
Blank Reporting
Result Limit
ND 2.0
94 50-150
98 50-150
MDL Analyzed
1.9 02/13/19 11:31
02/13/19 11:31
02/13/19 11:31
Qualifiers
LABORATORY CONTROL SAMPLE: 2495502
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 23.1 115 71-125
1,2-Dichloroethane-d4 (S) % 96 50-150
Toluene-d8(S) % 100 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2495503
2495504
MS
MSD
50215972001 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 22.0
21.7 110
109
50-150
1 30
1,2-Dichloroethane-d4 (S)
%
101
99
50-150
30
Toluene-d8 (S)
%
101
100
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 18 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA
Project: Butner Surface Water
Pace Project No.: 92416422
QC Batch: 457599 Analysis Method: EPA 8260B Mod.
QC Batch Method: EPA 8260E Mod. Analysis Description: 8260 MSV SIM
Associated Lab Samples: 92416422001
METHOD BLANK: 2495505
Associated Lab Samples: 92416422001
Parameter
Units
1,4-Dioxane (p-Dioxane)
ug/L
1,2-Dichloroethane-d4 (S)
%
Toluene-d8 (S)
%
Matrix: Water
Blank Reporting
Result Limit
ND 2.0
89 50-150
96 50-150
MDL Analyzed
1.9 02/14/19 12:30
02/14/19 12:30
02/14/19 12:30
Qualifiers
LABORATORY CONTROL SAMPLE: 2495506
Spike LCS LCS % Rec
Parameter Units Conc. Result % Rec Limits Qualifiers
1,4-Dioxane (p-Dioxane) ug/L 20 20.2 101 71-125
1,2-Dichloroethane-d4 (S) % 94 50-150
Toluene-d8 (S) % 98 50-150
MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2495507
2495508
MS
MSD
92416422001 Spike
Spike MS
MSD MS
MSD
% Rec
Max
Parameter
Units Result Conc.
Conc. Result
Result % Rec
% Rec
Limits
RPD RPD Qual
1,4-Dioxane (p-Dioxane)
ug/L ND 20
20 20.3
20.6 102
103
50-150
1 30
1,2-Dichloroethane-d4 (S)
%
95
92
50-150
30
Toluene-d8 (S)
%
97
98
50-150
30
Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result.
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC.
Page 19 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALIFIERS
Project: Butner Surface Water
Pace Project No.: 92416422
DEFINITIONS
DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot.
ND - Not Detected at or above adjusted reporting limit.
TNTC - Too Numerous To Count
J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit.
MDL -Adjusted Method Detection Limit.
PQL - Practical Quantitation Limit.
RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and
bias for a specific analyte in a specific matrix.
S - Surrogate
1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is
a combined concentration.
Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values.
LCS(D) - Laboratory Control Sample (Duplicate)
MS(D) - Matrix Spike (Duplicate)
DUP - Sample Duplicate
RPD - Relative Percent Difference
NC - Not Calculable.
SG - Silica Gel - Clean -Up
U - Indicates the compound was analyzed for, but not detected.
Acid preservation may not be appropriate for 2 Chloroethylvinyl ether.
A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA
Method 8260.
N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for
each analyte is a combined concentration.
Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes.
TNI -The NELAC Institute.
LABORATORIES
PASI-A Pace Analytical Services - Asheville
PASI-C Pace Analytical Services - Charlotte
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
Date: 02/15/2019 01:08 PM without the written consent of Pace Analytical Services, LLC. Page 20 of 24

aceAnalytical
—pacelabs.com
Pace Analytical Services, LLC
9800 Kincey Ave. Suite 100
Huntersville, NC 28078
[phone]
QUALITY CONTROL DATA CROSS REFERENCE TABLE
Project: Butner Surface Water
Pace Project No.: 92416422
Lab ID
Sample ID
QC Batch Method
QC Batch
Analytical Method
Analytical
Batch
92416422001
3902-SW1
EPA 3010A
456556
EPA 6010D
456578
92416422002
3902-SW2
EPA 3010A
456556
EPA 6010D
456578
92416422001
3902-SW1
EPA 3010A
456560
EPA 6020B
456581
92416422002
3902-SW2
EPA 3010A
456560
EPA 6020B
456581
92416422001
3902-SW1
EPA 8260B
456738
92416422002
3902-SW2
EPA 8260B
456738
92416422001
3902-SW1
EPA 8260B Mod.
457599
92416422002
3902-SW2
EPA 8260B Mod.
457598
Date: 02/15/2019 01:08 PM
REPORT OF LABORATORY ANALYSIS
This report shall not be reproduced, except in full,
without the written consent of Pace Analytical Services, LLC.
Page 21 of 24

dP-
Document Name:
Document Revised: February 7, 2018
Sample Condition Upon Receipt(SCUR)
Page 1 of 2
Document No.:
Issuing Authority:
f dCeAnalytical
F-CAR-CS-033-Rev.06
Pace Carolinas Quality Office
Laboratory receiving sapples:
Asheville ® Eden❑ Greenwood ❑ Fluntersville ❑ Raleigh❑ Mechanicsville❑
Sample Condition Client Name: • pProject WO# : 924 6422
� #: i
Courier: l FeAx ❑UPS ! /❑LISPS ❑Client
❑ Commercial ❑Pace ❑Other:
92416422
Custody Seal Present? ❑Yes No Seals Intact? [Dyes ❑No
Date/Initials Person Examining Contents; ��-' U r,%j J-9
Packing Material• ZBubble wrap ❑Bubble Bags []None ❑ Other Biological Tissue Frozen?
Thermometer: �%"' Type of Ice: Olivet ❑slue ❑None ❑Yes ❑No ffN/A
❑€RGun ID: 1��� 1
Cooler Temp (°C}; 1) t Correction Factor: Add/Subtract (°C) ❑
Temp should be above freezing to fi°C
Cooler Temp Corrected (°C): C \ []Samples out of temp criteria. Samples on ice, cooling process
has begun
USDA Regulated Soil ([2fN/A, water sample)
Did samples originate in a quarantine zone within the United States: CA, NY, or SC {check maps)? Did samples originate from a foreign source (internationally,
❑Yes [-7mn inrludin2 Hawaii and Puerto Rico)? ❑Yes ❑No
Comments/Discrepancy:
Chain of Custody Present?
L3r.s
❑No
[]N/A
1.
Samples Arrived within Hold Time?
E3es
❑No
❑N/A
2.
Short Hold Time Analysis (e72 hr.)?
❑Yes
ffN�
❑N'A
3.
Rush Turn Around Time Requested?
[I Yes
[3o
❑N/A
4.
Sufficient Volume?
QYes
❑No
❑N/A
S.
CorrectContainers Used?
-Pace Containers Used?
QYes
[Yes
[:]No
❑iNo
❑N/A
❑N/A
6.
Containers Intact?
2es
❑No
❑N/A
7.
Dissolved analysis: Samples Field Filtered?
❑Yes
[-]No
[fN/A
S.
Sample Labels Match COC?
-Includes Date/Time/iD/Analysis Matrix:
2]Yes
{
❑No
❑N/A
9.
Headspace in VOA Vials (>5-Smm)?
❑Yes
dNo
❑N/A
10.
Trip Blank Present?
Trip Blank Custody Seals Present?
[]Yes
❑Yes
[2 o
❑No
❑N/A
[fN/A
11.
COMMENTS/SAMPLE DISCREPANCY
CLIENT NOTIFICATION/RESOLUTION
Person contacted:
Date/Time:
Project Manager SCURF Review: fr
Project Manager SRF Review: A/Az
Field Data Required? ❑Yes []NO
Lot ID of SDFt containers:
Date: Z r1
Date: ZI5�9
Page 22 of 24

Document Name: Document Revised: February 7, 2018
1:-�ace�krlalyticat
Sample Condition Upon Receipt(SCUR) Page 1 of 2
Document No.: ; Issuing Authority:
F-CAR-CS-033-Rev.06 Pace Carolinas Quality Office
*Check mark top half of box if pH and/or dechlorination is
verified and within the acceptance range for preservation
samples.
Exceptions: VOA, Coliform, TOC, Oil and Grease, DRO/8015 (water) DOC, LLHg
**Bottom half of box is to list number of bottle
Project# W0# ; 92416422
PM: NMG Due Date: 02/19/19
CLIENT: 92-Joyce Eng
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pH Adjustment Log for Preserved Samples
Sample ID
Type of Preservative
pH upon receipt
Date preservation adjusted
Time preservation
adjusted
Amount of Preservative
added
Lot #
Note: Whenever there is a discrepancy affecting North Carolina compliance samples, a copy of this form MI be sent to the North Carolina OEHNR Certification Office (i.e.
Out of hold, incorrect preservative, out of temp, incorrect containers.
Page 23 of 24

z Z m
y -q a
R n 3
m n m
a O a
n z
_ a m
r3v m Q
Z
m
w
m
m
TEMP in C
Received an
Ice 3
v
(YIN) Fn
Gustoy p
Sealed z
0
Cooler C
Y1N 0
N
Sr
Inlact
(Y1N)
1.1
o
m w v
w
A
w
fv
.s
ITEM #
to �
N N
ti rn
ro
a s
N N
0
3 o n
10
� i
cr M
3
m
xv
n s
Nop�g011 on
MATRI%CODE (see valid codes to left)
SAMPLETYPE (G=GRAB C=COMP)
n
m co
D
1
rn
m
z
SAMPLE TEMP AT COLLECTION
i{
# OF CONTAINERS
Unpreserved
H2504
�(
HNO3 =
x
G
HCI a
NaOH `a
Na2S203 a
u
Methanol
Other
Analyses Test 1
x
NC App I Metals, Hardness
x
NC AppIVOC
t
x
NC 1,4-Cioxane by SIM
Rpgidi ial r'.hlnrina MHA
�n
1
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Page 24 of 24

Appendix D
Historical Groundwater Elevations

APPENDIX D: Historical Groundwater Elevations
Well ID:
Background
Downgradient
MW-1R
MW-2R
MW-3R
MW-4
MW-5
MW-6
NES-1
Well TOC Elev.:
460.51
331.60
330.96
340.80
343.88
362.53
328.40
Well Depth:
56.00
18.85
35.83
31.43
23.52
32.63
32.80
21-Aug-99
418.68
329.13
328.06
330.50
330.83
352.10
NI
16-Nov-99
419.75
325.38
324.51
331.53
334.33
352.97
NI
10-May-00
424.53
329.60
328.83
334.15
334.49
355.72
NI
26-Oct-00
419.21
329.26
328.15
331.33
330.94
352.78
NI
18-Apr-01
418.76
329.42
328.63
333.57
334.36
354.22
NI
26-Oct-01
412.53
329.04
327.94
330.57
330.23
350.92
NI
13-Jun-02
413.70
328.38
327.41
330.21
330.29
351.04
NI
19-Nov-02
413.40
329.25
328.35
331.57
337.17
350.94
NI
27-Jun-03
423.61
329.57
328.93
334.24
333.99
355.21
NI
29-Dec-03
420.23
329.70
329.11
334.49
334.78
354.92
NI
30-Jun-04
418.81
329.38
328.48
332.26
331.39
353.10
NI
28-Dec-04
418.02
329.50
328.91
333.45
334.14
355.14
NI
29-Jun-05
418.81
329.10
329.26
331.62
330.90
352.76
NI
29-Dec-05
413.38
329.29
328.71
332.78
334.27
351.52
NI
27-Jun-06
414.75
329.17
328.40
332.18
333.56
353.43
NI
28-Dec-06
415.54
329.40
328.86
333.57
335.24
354.02
NI
12-Jul-07
438.64
328.69
327.97
331.31
330.52
352.30
NI
18-Dec-07
412.59
328.94
328.08
330.32
327.92
347.90
306.54
8-Jul-08
414.52
329.20
326.00
331.46
330.85
351.03
NM
17-Dec-08
412.79
329.39
328.84
333.15
335.03
350.82
NM
9-Jul-09
417.16
329.17
329.48
332.30
331.36
352.17
310.12
16-Dec-09
418.11
329.55
329.09
334.57
336.94
352.87
NM
24-Jun-10
422.42
329.41
328.77
333.65
333.15
353.62
NM
13-Dec-10
415.96
329.49
328.85
332.81
330.34
350.08
NM
20-Jun-11
416.00
328.95
328.18
336.77
331.38
351.83
NM
5-Dec-11
412.94
329.31
328.65
332.32
329.51
349.87
NM
11-Jun-12
414.56
329.10
328.35
332.52
331.33
351.75
312.50
12-Dec-12
412.83
329.19
328.36
331.67
330.35
349.48
NM
1-May-13
415.69
329.65
329.13
334.49
335.15
353.63
317.11
5-Aug-13
417.97
329.02
328.41
333.32
332.83
353.01
NM
24-Feb-14
415.81
329.68
329.17
334.48
331.63
351.78
316.15
11-Aug-14
416.23
329.38
328.48
332.04
329.08
350.08
310.93
10-Mar-15
417.09
329.87
329.45
335.07
336.42
353.13
317.55
17-Aug-15
417.71
328.65
327.81
331.05
327.73
347.63
308.80
17-Feb-16
418.51
330.10
329.71
335.05
337.53
353.44
317.87
9-Aug-16
418.59
329.50
328.61
332.95
330.95
352.03
312.65
13-Feb-17
415.21
329.45
328.96
333.10
333.03
350.83
313.45
22-Aug-17
414.68
328.55
327.61
331.60
329.78
350.38
310.55
5-Feb-18
412.31
329.41
328.21
332.07
328.87
348.18
317.10
14-Aug-18
415.86
328.96
327.96
331.97
329.68
350.12
312.51
4-Feb-19
420.86
329.67
329.28
335.62
335.42
355.30
316.02
Notes: TOC = Top of casing.
Elevations in feet above mean sea level
Granville County -Butner Landfill
Permit No. 39-02
NM = Water level not measured.
NI = Well not yet installed.
La Bella Associates

Appendix E
Historical Constituents in Groundwater

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
blanks
INORGANICS
Antimony
&Sep-94
-
30
ND
ND
ND
ND
ND
ND
-
--
1-Dec-94
-
30
ND
ND
ND
ND
ND
ND
-
--
9-Fetr95
-
30
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
30
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
30
ND
ND
ND
ND
ND
ND
-
--
23May-96
-
30
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
30
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
30
ND
ND
ND
ND
ND
ND
-
--
1-Dec-97
-
30
ND
ND
ND
ND
ND
ND
-
--
20-May-98
-
30
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
30
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
30
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
30
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
30
ND
80.0
38.0
32.0
33.0
31.0
-
--
26-0ct-00
-
30
30.0
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
30
ND
ND
ND
ND
ND
ND
-
--
27-0ct-01
-
30
ND
ND
ND
ND
ND
ND
-
---
13-Jun-02
-
30
ND
ND
ND
ND
ND
ND
-
-
19-Nov-02
-
30
ND
ND
ND
ND
ND
ND
-
-
27-Jun-03
-
30
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
30
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
30
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
30
ND
ND
ND
ND
ND
ND
-
ND
un 29-J-05
-
30
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
30
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
30
ND
ND
ND
ND
ND
ND
-
ND
29-D-06
-
6
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
6
ND
ND
ND
ND
ND
ND
ND
GWPS= 1.4 uWL(10/23/07)
19-Deo-07
-
6
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
6
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
2.6
6.0
ND
ND
ND
ND
ND
ND
ND
ND
16-D-09
2.6
6.0
ND
ND
ND
ND
ND
ND
-
ND
NC 28=NE(03/24/10)
24-Jun-10
2.6
6.0
ND
ND
ND
2.9 1
ND
ND
-
ND
GWPS = 1 upJL (8/1/10)
13Deo-10
2.6
6.0
ND
ND
3.0 J
ND
2.8 J
ND
-
ND
20-Jun-11
5.0
6.0
ND
ND
ND
ND
6.0
ND
-
ND
5-Dec-11
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
12-D-12
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
6.0
ND
ND
ND
ND
ND
ND
ND
24-Feb14
5.0
6.0
8.8
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
6.0
ND
10.5
8.0
ND
ND
ND
-
ND
10-Ma'15
3.8
6.0
ND
7.1
6.5
3.9 J
ND
ND
-
ND
18-Aug-15
3.8
6.0
ND
6.2
4.8 J
4.1 J
ND
ND
-
ND
16-Feb
3.8
6.0
ND
9.9
6.5
4.3 J
ND
ND
-
ND
9-AUR-16
3.8
6.0
ND
7.7
ND
ND
ND
ND
-
ND
13Feb17
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
3.9
6.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb
3.9
5.0
ND
ND
ND
ND
ND
ND
-
ND
Arsenic
SSep-94
-
SO
ND
ND
ND
ND
ND
ND
-
-
1-Dec-94
-
SO
ND
ND
ND
ND
ND
ND
-
---
9-Fetr95
-
SO
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
SO
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
SO
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
10
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
10
6.0 J
15.0
ND
ND
ND
ND
-
--
1-Dec-97
-
10
ND
5.0 1
ND
ND
ND
ND
-
--
20-Mav-98
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
-
--
27-0ct-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov02
-
SO
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
SO
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
SO
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
SO
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
SO
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
SO
2.0 J
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
SO
ND
ND
ND
ND
ND
ND
ND
NC A 50 u91L (10/23/07)
19-Dec-07
-
SO
ND
4.1 1
ND
ND
ND
ND
ND
ND
&Jul-08
SO
ND
4.9 1
ND
ND
ND
ND
-
ND
17-Dec-08
2.7
10.0
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
2.7
50.0
ND
13.5
10.9
5.6 J
ND
4.0 J
ND
ND
16-Dec-09
2.7
10.0
ND
10.6
6.4 J
5.0 J
ND
3.6 J
-
ND
NC 2L =10 uWL (02/05/10)
24-Jun-10
2.7
10.0
ND
11.8
8.1 J
8.2 1
3.3 J
3.1 1
-
ND
Resample>
12-Aug-10
2.7
10.0
-
72 J
-
-
-
-
ND
Resample>
31-Aug-10
2.7
10.0
15.4
-
ND
13-Dec-10
2.7
10.0
ND
4.9 J
2.7 J
5.4 J
ND
ND
-
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-D-11
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.0
10.0
ND
5.4 1
ND
ND
ND
ND
ND
ND
12-D-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
10.0
ND
ND
5.6 1
ND
ND
ND
ND
24-Feb-14
5.0
10.0
ND
6.4 1
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
2.5
10.0
4.1 J
5.4 1
ND
ND
3.1 1
3.2 1
-
3.0 l
18-Aug-15
2.5
1ED
ND
5.1 1
ND
ND
ND
ND
-
ND
16-Feb
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
9-AUR-16
2.5
10.0
ND
ND
ND
ND
ND
ND
-
5.1 l
13-Fetr17
5.0
50.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
5.0
1ED
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
5.0
10.0
ND
5.4 1
ND
ND
ND
ND
-
ND
4-Feb
5.0
50.0
ND
5.7 J
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanka
Barium
8-Se"94
-
500
ND
270
ND
ND
830
860
-
--
1-Dec-94
-
500
ND
ND
ND
ND
ND
ND
-
--
9-Fetr95
-
500
ND
ND
ND
ND
510
ND
-
--
2-Mar-95
-
500
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
500
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
500
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
500
ND
82.0
30.0
ND
15.0
ND
-
--
17-Jun-97
-
500
200
320
37.0
17.0
210
31.0
-
--
1-Dec-97
-
500
61.0
180
43.0
46.0
220
33.0
-
--
20-May-98
-
500
30.0
150
45.0
13.0
180
22.0
-
--
19-Nov-98
-
500
48.0
120
42.0
ND
380
12.0
-
--
21-Ju1-99
-
500
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
500
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
500
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
500
ND
ND
ND
ND
ND
ND
-
--
18-AP,01
-
500
ND
ND
ND
ND
ND
ND
-
--
27-0ct-01
-
500
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
500
ND
ND
ND
ND
ND
ND
-
---
19-Nov-02
-
500
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
500
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
500
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
500
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
500
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
100
5.2 1
120
64.9
1.5 1
64.1
1.8 1
-
0.20 l
12-Jul-07
-
100
2.5 J
129
65.7 1
1.1 1
77.0 1
1.3 1
ND
NC A 2,000 u91L (10/23/07)
19-Dec-07
-
100
2.8 B
99.2
50.0 B
1.4 B
49.6 B
1.7 B
87.8
11.7
8-Jul-08
100
5.8 1
102
58.4 1
1.1 B
57.9 1
1.2 B
-
0.29 l
17-Dec-08
0.20
100
2.7 B
92.9 1
53.1 B
1.2 B
55.5 1
1.1 B
10.7 l
9-Jul-09
0.20
100
4.6 B
121
63.4 B
0.37 B
81.4 B
0.94 B
72.4 B
17.6 J
16-Dec-09
0.20
100
2.9 B
108
62.8 B
0.61 B
56.8 B
0.87 B
-
1% l
NC 2L = 700 moJL (02/05/10)
24-Jun-10
0.20
100
2.5 B
115 B
61.1 B
1.6 B
93.5 B
1.4 B
-
27.3 l
13-Dec-10
0.20
100
4.3 B
122
67.9 J
1.3 B
90.6 1
1.5 B
-
12.1 l
20-Jun-11
5.0
100
ND
108
70.7 J
ND
84.7 J
ND
-
ND
5-Dec-11
5.0
100
ND
118
73.0 J
ND
90.6 J
ND
ND
11-Jun-12
5.0
100
ND
138
65.2 J
ND
76.4 1
ND
61.3 J
ND
12-Dec-12
5.0
100
ND
113
64.7 J
ND
73.6 J
ND
ND
1-Mav-13
5.0
100
ND
118
69.1 1
ND
84.2 1
ND
81.2 J
ND
5-Aug-13
5.0
100
ND
111
65.1 J
ND
95.6 J
ND
ND
24-Feb14
5.0
100
ND
93.8 J
44.8 J
ND
139
ND
ND
ND
12-Aug-14
5.0
100
ND
125
66.4 J
ND
121
ND
-
ND
10-Ma,15
2.5
100
3.0 1
109
61.8 J
ND
116
ND
-
ND
18-AuF-15
2.5
100
4.4 J
119
63.1 J
ND
81.3 J
ND
-
ND
16-Fell
2.5
100
5.2 J
123
72.7 J
3.0 1
126
ND
-
ND
9-AuR-16
2.5
100
4.5 J
123
73.3 1
ND
109
ND
-
ND
13-Feb
2.5
100
7.8 J
112
68.3 J
ND
151
5.6 1
-
ND
22-AuF-17
2.5
100
ND
102
64.5 J
ND
99.9 J
ND
-
ND
5-Feb
2.5
100
8.0 J
117
73.5 J
ND
161
ND
-
ND
13-Aug-18
2.5
100
3.8 J
116
67.6 J
ND
103
ND
-
ND
4-Feb19
2.5
5
ND
104
44.3
ND
110
ND
-
ND
Beryllium
"e"94
-
2
ND
ND
ND
ND
ND
ND
-
---
1-Dec-94
-
2
ND
ND
ND
ND
4.0
ND
-
---
9-Felr95
-
2
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
2
ND
ND
ND
ND
2.0
ND
-
--
15-Nov-95
-
2
ND
ND
ND
ND
ND
ND
-
--
28-May-96
-
2
ND
ND
ND
ND
6.0
ND
-
--
22-Nov-96
-
2
ND
ND
ND
ND
3.0
ND
-
--
17-Jun-97
-
2
2.0
3.0
ND
ND
1.0
ND
-
--
1-D-97
-
2
ND
ND
ND
ND
ND
ND
-
--
20-Mav-98
-
2
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
2
ND
ND
ND
ND
2.0
ND
-
--
21-Jul-99
-
2
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
2
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
2
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
2
ND
ND
ND
ND
ND
ND
-
--
18-AP,01
-
2
ND
12.0
ND
ND
ND
ND
-
--
27-W-01
-
2
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
2
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
2
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
2
ND
ND
ND
ND
ND
ND
-
30-De,03
-
2
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
2
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-06
-
1
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
1
ND
ND
ND
ND
ND
ND
ND
GWPS=4 uFJL(10/23/07)
19-D-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
1
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
0.10
1.0
ND
ND
ND
ND
0.14 J
ND
ND
9-Jul-09
0.10
1.0
ND
0.18 J
0.22 J
0.17 J
ND
ND
0.23 J
ND
16-Dec-09
0.10
1.0
ND
0.15 1
0.17 J
0.15 J
0.25 1
ND
-
ND
NC 2B = 6.5 uFJL (02/05/10)
24-Jun-10
0.10
1.0
ND
ND
0.27 J
0.16 J
ND
ND
-
ND
13-Dec-10
0.10
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-D-11
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
II-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-D-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
10-Ma'15
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
16-Feb16
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Feb17
0.50
1.0
ND
ND
ND
ND
0.57 J
ND
-
ND
22-AuF-17
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb18
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-21R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cadmium
8-Se694
-
1
ND
ND
ND
ND
ND
4.0
-
--
1-Dec-94
-
1
ND
ND
ND
ND
ND
ND
-
--
9-Fetr95
-
1
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
1
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
1
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
1
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
1
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
1
ND
3.0
1.0
ND
ND
ND
-
--
1-Dec-97
-
1
ND
2.0
ND
ND
ND
ND
-
--
20-Mav-98
-
1
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
1
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
1
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
1
ND
3.0
3.0
ND
2.0
ND
-
--
10-Mav-00
-
1
5.0
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
1
ND
2.0
ND
ND
ND
ND
-
--
18-Apr-01
-
1
ND
11.0
ND
ND
ND
ND
-
--
27-0ct-01
-
1
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
1
ND
2.0
ND
ND
ND
ND
-
---
19-Nov-02
-
1
2.0
2.0
ND
ND
2.0
ND
-
-
27-Jun-03
-
1
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
1
ND
1.0
ND
ND
ND
ND
-
ND
30-Jun-04
-
1
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-04
-
1
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
1
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-05
-
1
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
1
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-06
-
1
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
1
ND
ND
ND
ND
ND
ND
ND
NC 1.75 upJL(10/23/07)
19-Deo-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
1
ND
ND
ND
ND
ND
ND
-
ND
17-Dec08
0.50
1.0
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
0.50
1.0
ND
1.4
ND
ND
ND
ND
ND
ND
16-Dec09
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
NC A= 2 upJL (02/05/10)
24-Jun-10
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Deo-11
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Deo-12
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.0
1.0
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
16-Feb-16
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Feb
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb18
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb
0.50
1.0
ND
ND
ND
ND
ND
ND
-
ND
Chromium
8Se"94
-
10
8.0
44.0
ND
6.0
48.0
80.0
-
--
1-Dec-94
-
10
14.0
ND
ND
ND
18.0
ND
-
--
9-Felr95
-
10
14.0
ND
ND
10.0
ND
ND
-
--
2-Mar-95
-
10
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
10
13.0
13.0
ND
ND
ND
ND
-
--
28-May-96
-
10
33.0
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
10
3.0
ND
ND
ND
ND
3.0
-
--
17-Jun-97
-
10
57.0
43.0
ND
3.0
2.0
6.0
-
--
1-Dec-97
-
10
29.0
ND
ND
ND
ND
ND
-
--
20-Mav-98
-
10
50.0
3.0
ND
ND
12.0
ND
-
--
19-Nov-98
-
10
17.0
3.0
ND
ND
5.0
ND
-
--
21-Ju1-99
-
10
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
12.0
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
-
---
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC A 50 uWL 00/23/07)
19-Dec-07
-
10
ND
2.0 B
ND
ND
ND
ND
1.1 B
1.4 1
8-Jul-08
10
ND
0.54 J
0.58 J
ND
ND
ND
-
ND
17-Deo-08
0.40
10.0
0.73 1
1.8 1
0.96 J
ND
0.96 1
0.70 1
ND
9-Jul-09
0.40
10.0
1.2 1
2.4 1
1.1 1
1.6 J
0.68 1
0.53 1
4.8 J
ND
16-Deo-09
0.40
10.0
1.3 J
ND
ND
ND
0.95 J
ND
-
ND
NC 2L = 10 uWL (02/05/10)
24-Jun-10
0.40
10.0
1.1 B
3.5 B
2.8 B
2.4 B
1.2 B
1.4 B
-
0.71 1
13-Deo-10
0.40
50.0
2.5 J
1.3 J
1.8 1
0.69 J
0.57 1
1.2 1
-
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec11
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.0
10.0
ND
8.6 1
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
5.2 J
ND
ND
ND
ND
ND
1-May-13
5.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.0
15
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
5.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
15
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
2.5
10.0
ND
2.7 1
ND
ND
ND
6.7 1
-
ND
16-Feb
2.5
50.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
2.8 B
2.8 B
ND
ND
ND
ND
-
2.9 1
13-Feb
2.5
50.0
ND
2.6 J
ND
ND
ND
ND
-
ND
22-Aug-17
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb
2.5
50.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Cobalt
8-Se694
-
10
ND
ND
ND
ND
ND
ND
-
--
1-Dec-94
-
10
11.0
ND
13.0
16.0
22.0
ND
-
--
9-Feb-95
-
10
20.0
14.0
ND
48.0
39.0
ND
-
--
2-Mar-95
-
10
16.0
21.0
ND
29.0
121.0
ND
-
--
15-Nov-95
-
10
20.0
21.0
ND
ND
27.0
ND
-
--
28-May-96
-
10
30.0
16.0
ND
ND
122
ND
-
--
22-Nov-96
-
10
6.0
13.0
ND
4.7
93.0
ND
-
--
17-Jun-97
-
10
130
38.0
ND
6.0
45.0
3.0
-
--
1-Dec-97
-
10
32.0
21.0
ND
12.0
36.0
4.0
-
--
20-May-98
-
10
15.0
16.0
2.0
9.0
100
3.0
-
--
19-Nov-98
-
10
21.0
16.0
2.0
7.0
180
3.0
-
--
21-Ju1-99
-
10
ND
16.0
ND
ND
100
ND
-
--
16-Nov-99
-
10
ND
15.0
ND
ND
38.0
ND
-
--
10-May-00
-
10
ND
17.0
ND
ND
61.0
ND
-
--
26-0ct-00
-
10
ND
15.0
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
27.0
ND
ND
74.0
ND
-
--
27-0ct-01
-
10
ND
12.0
ND
ND
47.0
ND
-
--
13-Jun-02
-
10
ND
14.0
ND
ND
251
ND
-
---
19-Nov-02
-
10
ND
10.0
ND
ND
57.0
ND
-
---
27-Jun-03
-
10
ND
15.0
ND
ND
75.0
ND
-
30-Dec-03
-
10
ND
17.0
ND
ND
52.0
ND
-
ND
30-Jun-04
-
10
ND
16.0
ND
ND
31.0
ND
-
ND
29-Dec-04
-
10
ND
11.0
ND
ND
46.0
ND
-
ND
29-Jun-05
-
10
ND
11.0
ND
ND
43.0
ND
-
ND
29-Dec-05
-
10
ND
12.0
ND
ND
30.0
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
72.5
ND
-
ND
29-Dec-06
-
10
ND
11.4
ND
ND
37.5
ND
-
ND
12-Jul-07
-
10
ND
11.8
ND
2.7
58.4
ND
ND
GWPS= 70 uWL(10/23/07)
19-Dec-07
-
10
2.5 B
ND
ND
2.0 B
103
2.6 B
8.0 B
1.8 l
8-Jul-08
SO
10.3 B
12.1 B
2.0 B
9.0 B
130
4.8 B
-
6.2 l
17-Dec-08
0.60
10.0
2.1 B
11.8 B
2.3 B
3.6 B
43.7
1.6 B
2.5 l
9-Jul-09
0.60
1ED
ND
6.2 1
ND
ND
100
ND
2.2 1
ND
16-Dec-09
0.60
10.0
ND
4.7 J
ND
ND
6.6 J
ND
-
ND
24-Jun-10
0.60
10.0
ND
16.3
ND
ND
25.0
ND
-
ND
GWPS = 1 uOl (2/05/10)
13-Dec-10
0.60
10.0
2.5 B
15.5
ND
ND
(1291
(ND)
-
1.6 I1.01) l
20-Jun-11
5.0
1ED
ND
14.2
ND
ND
81.8
ND
-
ND
5-Dec-11
5.0
50.0
ND
12.7
ND
ND
146
ND
-
ND
Resemple>
25-Jan-12
5.0
50.0
47.5
ND
11-Jun-12
5.0
10.0
ND
14.2
ND
ND
SOS
ND
ND
ND
12-Dec-12
5.0
10.0
ND
11.3
ND
ND
113
ND
ND
1-Mav-13
5.0
10.0
ND
24.3
ND
ND
34.0
ND
ND
ND
5-Aug-13
5.0
10.0
ND
24.7
ND
ND
50.9
ND
ND
24-Feb-14
5.0
10.0
ND
18.4
ND
ND
9.6 J
ND
ND
ND
12-Aug-14
5.0
10.0
ND
9.4 1
ND
ND
46.3
ND
-
ND
10-Mar-15
2.5
10.0
ND
8.7 1
ND
ND
39.2
ND
-
ND
18-Aug-15
2.5
10.0
ND
9.3 1
ND
ND
116
ND
-
ND
16-Feb
2.5
10.0
ND
10.0
ND
ND
13.1
ND
-
ND
9-Aug-16
2.5
50.0
ND
50.0 J
ND
ND
144
ND
-
ND
13-Feb-17
2.5
10.0
ND
8.3 1
ND
ND
78.7
ND
-
ND
22-Aug-17
2.5
50.0
ND
7.4 1
ND
ND
El
ND
-
ND
5-Feb-18
2.5
10.0
ND
8.3 1
ND
ND
172
ND
-
ND
13-Aug-18
2.5
10.0
ND
10.7
ND
ND
98
ND
-
ND
4-Feb-19
2.5
5.0
ND
9.9
ND
ND
24
ND
-
ND
Copper
8Se"94
-
200
ND
ND
ND
ND
ND
660
-
-
1-Dec-94
-
200
ND
ND
ND
ND
ND
ND
-
---
9-Feb-95
-
200
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
200
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
200
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
200
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
200
ND
ND
32.0
13.0
100
ND
-
--
17-Jun-97
-
200
34.0
350
13.0
37.0
28.0
77.0
-
--
1-Dec-97
-
200
19.0
72.0
14.0
88.0
15.0
34.0
-
--
20-Mav-98
-
200
12.0
48.0
380
41.0
53.0
28.0
-
--
19-Nov-98
-
200
10.0
ND
410
28.0
53.0
14.0
-
--
21-Ju1-99
-
200
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
200
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
200
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
200
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
200
ND
ND
ND
ND
ND
ND
-
--
27-0ct-01
-
200
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
200
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
200
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
200
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
200
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
200
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
200
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
200
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
200
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
200
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
10
ND
ND
113
5.50 J
10.4
1.90 B
-
0.60 J
12-Jul-07
-
10
ND
ND
13.4
7.90
2.6 J
ND
ND
NC 2L= 1,000 uWL(10/23/07)
19-Dec-07
-
10
2.0 B
ND
8.6 B
3.8 B
7.0 B
0.73 B
5.8 B
9.8
8-Jul-08
10
0.64 1
ND
12.1
3.7 J
8.5 1
ND
-
ND
17-Dec-08
0.30
10.0
0.80 J
13.6
10.2
3.9 J
11.9
0.37 1
ND
9-Jul-09
0.30
50.0
ND
ND
6.3 J
ND
5.7 1
ND
8.8 J
ND
16-Dec-09
0.30
10.0
ND
ND
9.2 J
1.6 J
5.7 1
ND
-
ND
24-Jun-10
0.30
10.0
ND
ND
10
1.2 J
5.1 1
ND
-
ND
13-Dec-10
0.30
10.0
1.1 B
ND
13.6
5.8 J
5.6 J
0.59 B
-
0.49 l
20-Jun-11
5.0
10.0
ND
ND
15.3
8.1 J
8.7 1
ND
-
ND
5-Dec-11
5.0
10.0
ND
ND
16.9
10.0 1
7.6 J
ND
ND
11-Jun-12
5.0
10.0
ND
10.7
122
6.3 J
7.4 1
ND
ND
ND
12-Dec-12
5.0
50.0
ND
ND
11.6
8.5 J
10.4
ND
ND
1-Mav-13
5.0
10.0
ND
ND
13.6
5.8 J
9.6 1
ND
ND
ND
5-Aug-13
5.0
50.0
ND
ND
14.3
ND
10.2
ND
ND
24-Feb-14
5.0
10.0
ND
ND
122
ND
5.1 1
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
10.5
ND
ND
ND
-
ND
10-Mar-15
2.5
10.0
ND
ND
8.7 J
ND
15.5
ND
-
ND
18-Aug-15
2.5
50.0
ND
ND
6.7 J
5.6 J
10.1
ND
-
ND
NC 50 uWL(06/01/2016)
16-Feb16
2.5
50.0
ND
ND
7.8 1
ND
5.1 J
ND
-
ND
9-Aug-16
2.5
50.0
ND
ND
5.4 J
ND
7.8 1
ND
-
ND
13-Feb-17
2.5
50.0
ND
ND
6.8 J
4.3 J
14.5
9.4 1
-
ND
22-Aug-17
2.5
50.0
ND
ND
6.5 J
ND
5.7 1
4.4 1
-
ND
5-Feb-18
2.5
10.0
ND
6.5 J
9.0 J
5.5 J
12.4
2.6 1
-
ND
13-Aug-18
2.5
10.0
ND
5.5 1
12.2
3.7 J
48.8
ND
-
ND
4-Feb-19
2.5
5.0
ND
3 J
5.4
8
4.3 J
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
81anke
Lead
8-Sen94
-
10
ND
13.0
ND
ND
30.0
36.0
-
--
1-Dec-94
-
10
11.0
ND
ND
ND
36.0
ND
-
--
9-Felr95
-
10
ND
ND
ND
10.0
37.0
ND
-
--
2-Mar-95
-
10
ND
ND
ND
ND
44.0
ND
-
--
15-Nov-95
-
10
ND
ND
ND
ND
ND
ND
-
--
28-May-96
-
10
ND
ND
ND
ND
42.0
ND
-
--
22-Nov-96
-
10
ND
ND
ND
ND
13.0
ND
-
--
17-Jun-97
-
10
20.0
29.0
ND
ND
13.0
ND
-
--
1-Dec-97
-
10
8.0
14.0
ND
5.0
14.0
ND
-
--
20-May-98
-
10
ND
6.0
ND
6.0
21.0
ND
-
--
19-Nov-98
-
10
5.0
ND
ND
ND
58.0
ND
-
--
21-Jul-99
-
10
ND
12.0
14.0
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-A"'01
-
10
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
11.0
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
10
ND
ND
ND
ND
12.0
ND
-
--
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
-
--
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
10
ND
ND
ND
ND
ND
2.1 J
-
ND
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC 2L = 15 uWL (10/23/07)
19-Dec-07
-
10
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
10
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
4.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
4.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
4.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
4.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
5.0
1ED
ND
ND
ND
ND
ND
ND
ND
24-Feb14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
10-Ma'15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
16-Febl6
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
ND
5.1 1
ND
ND
ND
ND
-
ND
13-Feb17
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
2.5
50.0
ND
2.8 1
ND
ND
ND
ND
-
ND
5-Feb18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
4.6 1
ND
-
ND
4-Feb19
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
MemuN
1-D-97
-
0.5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
0.5
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
0.5
ND
0.59
0.65
0.65
0.76
ND
-
--
10-Mav-00
-
0.5
-
ND
ND
ND
ND
-
-
--
26-W-00
-
0.5
-
ND
ND
ND
ND
-
-
--
18-Apr-01
ND
ND
ND
ND
-
-
--
13-Jun-02
-
0.5
-
ND
ND
ND
ND
-
-
--
27-Jun-03
-
0.5
-
ND
ND
ND
ND
-
-
---
30-Dec-03
-
0.5
-
30-Jun-04
-
0.5
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
-
29-Jun-05
-
0.5
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
-
28-Jun-06
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
-
12-Jul-07
-
0.2
ND
NO
ND
ND
ND
ND
ND
NC 2L = 1.05 upJL (10/23/07)
19-Dec-07
-
ND
8-Jul-08
-
0.2
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
-
9-Jul-09
0.070
0.2
ND
ND
ND
ND
ND
ND
-
ND
16-Dec-09
-
NC 2L = 1 upJL (02/05/10)
24-Jun-10
0.070
0.20
ND
ND
ND
ND
ND
0.098 J
-
ND
13-Dec-SO
-
20-Jun-11
0.10
0.20
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
11-Jun-12
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
-
1-Mav-13
0.10
0.20
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
24-Feb14
0.10
0.20
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.10
0.20
ND
ND
ND
-
-
-
-
ND
16-Feb16
0.10
0.20
ND
ND
ND
-
-
-
-
ND
13-Feb17
0.10
0.20
ND
ND
ND
-
-
-
-
ND
22-Aug-17
0.10
0.20
ND
ND
ND
-
-
-
-
ND
5-Feb
0.10
0.20
ND
ND
ND
-
-
-
-
ND
4-Feb
0.10
0.20
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
Ml
MW-4
MW-5
MW-6
NES-1
Blanka
Nickel
8-Se"94
-
50
NO
NO
ND
NO
ND
ND
-
--
1-Dec-94
-
50
ND
ND
ND
NO
NO
NO
-
---
9-Fetr95
-
50
ND
72
ND
ND
ND
ND
-
---
2-Mar-95
-
50
ND
100
ND
ND
ND
ND
-
---
15-Nov-95
-
50
ND
61.0
ND
ND
ND
ND
-
---
28-Mav-96
-
50
ND
85.0
ND
ND
ND
ND
-
---
22-Nov-96
-
50
ND
72.0
ND
ND
ND
ND
-
---
17-Jun-97
-
50
75
98.0
ND
ND
ND
ND
-
---
1-Dec-97
-
50
ND
89.0
ND
ND
ND
ND
-
---
20-Mav-98
-
50
ND
91.0
ND
ND
ND
ND
-
---
19-Nov-98
-
50
ND
83.0
ND
ND
ND
ND
-
---
21-Jull
-
50
ND
109
ND
ND
ND
ND
-
---
16-Nov-99
-
50
NO
122
ND
NO
ND
NO
-
---
10-Mav-00
-
50
ND
104
ND
ND
ND
ND
-
---
26-0ct-00
-
50
ND
93.0
ND
ND
ND
ND
-
---
18-Ap"01
-
50
ND
107
ND
ND
ND
ND
-
---
27-0ct-01
-
50
ND
92.0
ND
ND
ND
ND
-
---
13-Jun-02
-
50
ND
98.0
ND
ND
ND
ND
-
---
19-Nov-02
-
50
ND
74.0
ND
ND
ND
ND
-
-
27-Jun-03
-
50
ND
85.0
ND
ND
ND
ND
-
30-Dec-03
-
50
ND
100
ND
ND
ND
ND
-
ND
30-Jun-04
-
50
ND
120 (81.0)
ND
ND
ND
ND
-
ND
29-Dec-04
-
50
ND
100
ND
ND
ND
ND
-
ND
29-Jun-05
-
50
ND
150
ND
ND
ND
ND
-
ND
29-Dec-05
-
50
ND
96.0
ND
ND
ND
ND
-
ND
28-Juni
-
50
ND
88.7
ND
ND
ND
ND
-
ND
29-Dec-06
-
50
ND
94.7
30.1
14.2
8.9 1
ND
-
ND
12-Jull
-
50
ND
99.0
30.6 J
13.9 1
13.7 J
ND
ND
NC A= 100 mi (10/23/07)
19-Dec-07
-
50
ND
83.4
23.7
11-0
18.3
ND
11.4
NO
8-Jull
50
ND
76.0
28.1 1
11.5 J
27.0 J
ND
-
ND
17-Dec-08
1.7
50.0
ND
75.5
27.8 J
12.2 1
11.0 B
ND
2.4 l
9-Jul-09
1.7
50.0
2.2 J
93.5
29.4 J
11.7 1
23.2 1
ND
13.1 J
ND
16-Dec-09
1.7
50.0
ND
81.2
28.2 J
11.8 B
2.6 B
NO
-
3.0 l
24-Jun-10
1.7
50.0
ND
76.3
191 J
9.0 1
7.0 1
4.5 1
-
ND
13-Dec-10
1.7
50.0
ND
83.0
23.5 J
6.8 B
20.7 1
ND
-
2.7 l
20-Jun-11
5.0
50.0
ND
78.8
30.1 1
11.2 J
1053 J
ND
-
ND
5-Dec-11
5.0
50.0
ND
89.1
32.8 1
11.7 J
24.3 J
ND
NO
11-Jun-12
5.0
50.0
ND
91.8
28.9 1
10.0 J
17.3 J
ND
ND
NO
12-Dec-12
5.0
50.0
ND
91.8
29.2 1
9.3 J
21.1 J
ND
NO
1-Mav-13
5.0
50.0
ND
89.6
31.9 1
10.4 J
5.7 J
ND
NO
NO
5-AuR-13
5.0
50.0
ND
87.9
28.1 J
9.0 J
8.4 J
ND
NO
24-Feb
5.0
50.0
NO
83.1
16.7 J
10.4 J
ND
ND
NO
NO
12-Aul
5.0
50.0
ND
97.9
29 J
12.9 J
13.2 J
ND
-
NO
10-Ma,15
2.5
50.0
ND
91.9
32.9 J
12.3 J
8.2 J
ND
-
NO
18-Aul
2.5
50.0
ND
98.0
28.0 J
11.9 1
26.2 1
5.4 1
-
ND
16-Feb
2.5
50.0
ND
92.0
35.4 1
12.7 J
3.7 J
ND
-
NO
9-Aug-16
2.5
50.0
3.3 J
88.9
29.0 J
12.2 J
30.7 J
ND
-
NO
13-Feb-17
2.5
50.0
ND
89.6
30.4 1
13.5 J
16.2 J
ND
-
NO
22-Aul
2.5
50.0
ND
84.2
28.2 1
12.3 J
13.5 J
ND
-
NO
5-Feb
2.5
50.0
NO
87.6
29.8 J
11.7 J
28.5 J
ND
-
NO
13-Aul
2.5
50.0
NO
88.9
29.0 J
12.3 J
21.9 J
ND
-
NO
4-Feb
2.5
5.0
NO
85.7
17.4
10.7
5.5
ND
-
IND
Selenium
8Se"94
-
20
NO
ND
ND
ND
ND
ND
-
---
1-Dec-94
-
20
NO
ND
ND
ND
ND
ND
-
---
9-Fetr95
-
20
NO
ND
ND
ND
ND
ND
-
---
2-Ma,95
-
20
NO
ND
ND
NO
ND
ND
-
---
15-Nov-95
-
20
ND
ND
ND
ND
ND
ND
-
---
28-Mav-96
-
20
NO
ND
ND
NO
ND
ND
-
---
22-Nov-96
-
20
ND
ND
ND
ND
ND
ND
-
---
17-Jun-97
-
20
ND
ND
ND
NO
ND
ND
-
---
1-Dec-97
-
20
ND
ND
ND
NO
ND
NO
-
---
20-May-98
-
20
ND
ND
ND
NO
ND
NO
-
---
19-Nov-98
-
20
ND
ND
ND
ND
ND
ND
-
---
21-Jul-99
-
20
ND
ND
ND
NO
36.0
ND
-
---
16-Nov-99
-
20
ND
ND
ND
ND
ND
ND
-
---
10-Mav-00
-
20
ND
ND
ND
NO
ND
NO
-
---
26-0ct-00
-
20
ND
ND
ND
NO
ND
ND
-
---
18-Apr-OS
-
20
ND
ND
ND
NO
ND
NO
-
---
27-0ct-01
-
20
ND
ND
ND
NO
ND
ND
-
---
13-Jun-02
-
20
ND
ND
ND
NO
ND
ND
-
---
19-Nov-02
-
20
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
20
ND
ND
ND
NO
ND
ND
-
---
30-Dec-03
-
20
ND
ND
ND
NO
ND
ND
-
ND
30-Jun-04
-
20
ND
ND
ND
ND
ND
ND
-
NO
29-Dec-04
-
20
ND
ND
ND
ND
ND
ND
-
NO
29-Jun-05
-
20
ND
ND
ND
ND
ND
ND
-
NO
29-Dec-05
-
20
ND
ND
ND
ND
ND
ND
-
ND
28-Juni
-
20
ND
ND
ND
ND
ND
ND
-
NO
29-Dec-06
-
10
ND
ND
ND
NO
ND
ND
-
ND
12-Jull
-
10
ND
ND
ND
NO
ND
ND
ND
NC A 50 uWL 00/23/07)
19-Dec-07
-
10
ND
11.5
ND
ND
ND
ND
ND
ND
8-Jul-08
10
ND
ND
ND
NO
ND
ND
-
ND
17-Dec-08
3.8
10
4.8 B
5.1 B
4.8 B
ND
ND
ND
4.9 1
9-Jul-09
3.8
10
ND
ND
4.2 1
ND
ND
ND
ND
ND
16-D-09
3.8
10
ND
ND
ND
5.1 1
ND
NO
-
ND
INC 2L = 20 uFJL (02/05/10)
24-Jun-10
3.8
10
NO
ND
ND
ND
ND
NO
-
ND
13-Dec-10
3.8
10
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
50.0
10
ND
ND
ND
ND
ND
ND
-
ND
5-Deo-11
10.0
10
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10
ND
ND
ND
ND
ND
ND
ND
1-May-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
10.0
10
ND
ND
ND
ND
ND
ND
ND
24-Feb14
10.0
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aul
10.0
10
ND
ND
ND
ND
ND
ND
-
NO
10-Ma'15
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
18-Aul
5.0
10
ND
ND
ND
ND
ND
ND
-
NO
16-Feb16
5.0
10
ND
ND
ND
ND
ND
ND
-
NO
9-AuR-16
5.0
10
ND
ND
ND
NO
ND
NO
-
NO
.Feb-17
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
22-Aul
5.0
10
ND
ND
ND
NO
ND
ND
-
ND
5-Feb18
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
13-Aul
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
4-Feb19
5.0
10
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Silver
8-Se"94
-
10
ND
ND
ND
ND
ND
ND
-
--
1-Dec-94
-
10
ND
ND
ND
ND
ND
ND
-
--
9-Felr95
-
10
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
10
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
10
ND
ND
ND
ND
ND
ND
-
--
28-May-96
-
10
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
10
ND
ND
ND
ND
ND
ND
-
--
1-Dec-97
-
10
ND
8.0
ND
ND
ND
3
-
--
20-May-98
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
15.0
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
-
--
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC A= 17.5 upJL (10/23/07)
19-Dec-07
-
10
ND
0.57 1
0.60 J
0.55 J
ND
0.33 1
ND
ND
8-Jul-08
10
ND
2.7 1
2.3 J
1.1 J
0.22 1
0.69 1
-
0.12 J
17-Dec-08
0.10
10.0
0.13 J
1.8 1
1.4 J
0.85 J
0.72 1
0.51 1
ND
9-Jul-09
0.10
10.0
ND
0.84 1
0.63 J
0.45 J
ND
0.11 1
ND
ND
16-Dec-09
0.10
10.0
0.12 J
2.0 1
1.6 1
1.0 J
0.12 1
0.52 1
-
ND
NC A 20 uWL (02/05/10)
24-Jun-10
0.10
10.0
ND
0.38 J
0.33 J
0.35 J
ND
ND
-
ND
13-Dec-10
0.10
50.0
0.15 B
1.3 1
0.99 J
0.45 B
INDI
INDI
-
0.21 I0.19J l
20-Jun-11
5.0
50.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
5.0
50.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.0
50.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
5.0
50.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
5.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
5.0
1ED
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
16-Febl6
2.5
50.0
ND
ND
ND
ND
ND
ND
-
ND
9-Aug-16
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Feb17
2.5
50.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
2.5
50.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
2.5
10.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb19
2.5
5.0
ND
ND
ND
ND
ND
ND
-
ND
Thallium
"e"94
-
10
ND
ND
ND
ND
ND
ND
-
--
1-Dec-94
-
10
ND
ND
ND
ND
ND
ND
-
--
9-Felr95
-
10
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
10
ND
ND
ND
ND
ND
ND
-
--
15-Nov-95
-
10
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
10
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
10
ND
3.0
ND
ND
ND
ND
-
--
1-Dec-97
-
10
ND
ND
ND
ND
ND
ND
-
--
20-Mav-98
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
-
---
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
SOJ
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
22.0
13.0
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
23.0
20.0
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
25.7
12.6
ND
ND
ND
-
ND
29-D-06
-
6
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
5.5
ND
ND
ND
ND
ND
ND
ND
GWPS= 0.28 woJL(10/23/07)
19-D-07
-
5.5
ND
4.0 J
ND
ND
ND
ND
ND
ND
8-Jul-08
5.5
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
3.0
5.5
ND
3.2 J
3.2 J
ND
ND
ND
ND
9-Jul-09
3.0
5.5
ND
ND
ND
4.1 1
ND
ND
ND
ND
16-D-09
3.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
3.0
5.5
ND
ND
5.2 J
3.1 1
ND
ND
-
ND
GWPS= 0.2 u91L(10/1/10)
13-Dec-10
3.0
5.5
ND
ND
7.7
ND
ND
ND
-
ND
20-Jun-11
5.4
5.5
ND
ND
ND
ND
ND
ND
-
ND
5-D-11
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-D-12
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
5-Aug-13
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
24-Feb14
5.4
5.5
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
5.4
5.5
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
5.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
18-Aug-15
5.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
16-Feb
5.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
9-AuR-16
5.0
5.5
ND
ND
ND
ND
ND
ND
-
ND
.Fe
0.02
5.5
0.023 J
0.040 1
ND
ND
0.035 1
ND
-
ND
b-17
22-Auk-17
0.02
5.5
ND
ND
ND
ND
0.033 1
ND
-
ND
5-FeG18
0.03
0.1
ND
ND
ND
ND
0.047 1
ND
-
ND
13-Aug-18
0.02
5.5
ND
ND
ND
ND
0.037 1
ND
-
ND
4-Feb
0.06
0.1
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Tin
1-Dec-97
-
100
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
100
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
100
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
I
-
ND
ND
ND
ND
-
-
--
18-Ap"01
-
100
-
ND
ND
ND
ND
-
-
--
27-0ct-01
-
100
-
---
13-Jun-02
-
100
ND
ND
ND
ND
ND
ND
-
---
19-Nov-02
-
100
-
-
27-Jun-03
-
100
ND
149
127
ND
ND
ND
-
30-D-03
-
100
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Jun05
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
100
ND
41.1
14.4
3.2 J
ND
ND
-
ND
12-Ju1-07
-
100
ND
35.2 J
13.9 J
5.2 J
ND
ND
ND
NC 2L=NE uWL(10/23/07)
19-Deo-07
-
100
ND
33.6
7.4
ND
ND
ND
ND
ND
8-Jul-08
100
4.4 J
28.6 J
15.1 J
5.4 1
3.0 J
3.6 J
-
ND
17-D-08
1.8
100
ND
22.5 J
9.2 J
ND
ND
ND
-
ND
9-Jul-09
L8
100
ND
21.4 J
8.6 J
ND
ND
ND
-
ND
16-D-09
1.8
100
ND
26.3 J
10.7 J
ND
ND
ND
-
ND
GWPS= 2100 uWL(02/05/10)
24-Jun-10
1.8
100
ND
23.4 1
10.7 J
3.2 J
2.2 1
1.9 1
-
ND
13-Dec-10
1.8
100
ND
30.3 J
12.1 J
5.8 J
ND
ND
-
ND
20-Jun-11
5.0
100
ND
26.8 J
13.8 J
ND
ND
ND
-
ND
5-Dec-11
5.0
100
ND
25.8 J
13.9 J
ND
ND
ND
ND
11-Jun-12
5.0
100
ND
22.2 J
9.0 J
ND
ND
ND
ND
ND
12-Dec-12
5.0
100
ND
30.0 J
13.2 J
ND
ND
ND
-
ND
1-Mav-13
5.0
100
ND
25.8 J
12.2 J
ND
ND
ND
-
ND
5-Aug-13
5.0
100
ND
22.7 J
12.5 J
ND
ND
ND
ND
24-Feb14
5.0
100
ND
26.7 J
11.7 J
9.8 J
ND
ND
ND
ND
12-Aug-14
5.0
100
ND
30.7 J
8.2 J
ND
ND
ND
-
ND
10-Mar-15
2.5
100
ND
28.7 J
11.1 J
ND
ND
ND
-
ND
18-Aug-15
2.5
100
ND
27.7 J
7.5 J
ND
ND
ND
-
ND
16-Feb
2.5
100
ND
28.6 1
10.4 J
-
-
-
-
ND
9-AUR-16
2.5
100
ND
20.9 1
5.4 J
-
-
-
-
ND
13-Feb
2.5
100
ND
25.5 B
7.8 B
-
-
-
-
3.6 J.
22-Aug-17
2.5
100
ND
17.2 J
5.3 J
-
-
-
-
ND
5-Feb18
2.5
100
ND
20.3 1
9.5 J
-
-
-
ND
13-Aug-18
2.5
100
ND
22.2 J
7.4 1
-
-
ND
-
ND
4-Feb
2.5
5
ND
24.8
5.5
-
-
-
-
ND
Vanadium
"e"94
-
40
ND
ND
ND
ND
ND
130
-
-
1-Dec-94
-
40
63.0
ND
ND
45.0
ND
ND
-
---
9-Fetr95
-
40
ND
ND
ND
ND
ND
ND
-
--
2-Mar-95
-
40
41.0
ND
ND
45.0
ND
ND
-
--
15-Nov-95
-
40
ND
ND
ND
ND
ND
ND
-
--
28-Mav-96
-
40
83.0
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
40
7.0
17
ND
21.0
ND
ND
-
--
17-Jun-97
-
40
450
560
ND
19.0
ND
ND
-
--
1-Dec-97
-
40
62.0
88.0
ND
41.0
ND
10.0
-
--
20-May-98
-
40
25.0
15.0
ND
50.0
5.0
ND
-
--
19-Nov-98
-
40
33.0
29.0
5.0
16.0
9.0
5.0
-
--
21-Jul-99
-
40
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
40
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
40
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
40
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
40
ND
ND
ND
ND
ND
ND
-
--
27-0ct-01
-
40
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
40
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
40
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
40
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
40
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
40
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
40
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
40
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
40
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
40
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
25
2.7 J
ND
ND
14.5
ND
1.0 J
-
ND
12-Ju1-07
-
25
ND
ND
ND
19.4 1
ND
ND
ND
GWPS= 3.5 uWL 00/23/07)
19-Dec-07
-
25
2.2 B
2.2 B
ND
15.7 J
3.0 B
1.2 B
4.0 J
0.62 J
8-Jul-08
25
2.6 1
2.4 1
ND
14.6 J
1.4 1
1.2 1
-
0.20 J
17-Dec-08
0.20
25.0
1.9 B
2.3 B
ND
13.9 J
2.5 B
1.2 B
0.76 J
9-Jul-09
0.20
25.0
3.9 B
9.7 1
2.5 B
18.4 J
2.9 B
2.2 B
8.5 J
1.30 J
16-Dec-09
0.20
25.0
2.0 B
4.4 1
1.3 B
14.0 J
2.2 B
1.5 B
-
0.53 J
24-Jun-10
0.20
25.0
1.8 1
4.4 1
1.5 1
13.3 J
2.2 1
1.3 1
-
ND
GWPS=0.3 uWL(10/1/10)
13-Dec-10
0.20
25.0
12 1
3.6 1
0.35 B
16.6 J
1.8 B
1.0 B
-
0.36 J
20-Jun-11
5.0
25.0
ND
ND
ND
14.5 J
ND
ND
-
ND
5-Dec-11
5.0
25.0
ND
ND
ND
13.5 1
ND
ND
ND
11-Jun-12
5.0
25.0
ND
18.0 J
ND
12.8 J
ND
ND
ND
ND
12-Dec-12
5.0
25.0
ND
ND
ND
13.6 J
ND
ND
ND
1-May-13
5.0
25.0
ND
ND
ND
6.3 J
ND
ND
ND
ND
5-Aug-13
5.0
25.0
ND
ND
ND
10.2 1
ND
ND
ND
24-Feb
5.0
25.0
ND
ND
ND
12.9 J
ND
ND
ND
ND
12-Aug-14
5.0
25.0
ND
ND
ND
18.6 1
ND
ND
-
ND
10-Mar-15
2.5
25.0
3.1 J
11.6 J
6.2 1
13.4 1
ND
ND
-
ND
18-Aug-15
2.5
25.0
3.4 J
6.8 1
3.6 J
19.6 1
2.8 1
ND
-
ND
16-Feb
2.5
25.0
2.7 1
3.3 J
ND
14.4 1
ND
ND
-
ND
9-AUR-16
2.5
25.0
2.5 J
3.5 1
ND
21.2 1
ND
ND
-
ND
13-Feb-17
2.5
25.0
4.4 1
4.1 1
ND
18.4 J
3.0 1
2.9 1
-
ND
22-Auk-17
2.5
25.0
ND
6.6 1
ND
20.6 1
2.6 J
ND
-
ND
5-Feb18
2.5
25.0
3.6 1
4.4 J
ND
17.6 1
ND
2.5 J
-
ND
13-Aug-18
2.5
25.0
ND
5.3 1
ND
20.4 1
2.9 J
ND
-
ND
4-Feb
2.5
5.0
ND
3.5 J
ND
12
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Zinc
8-Sen94
-
50
110
160
ND
ND
320
430
-
--
1-Dec-94
-
50
132
ND
ND
70
164
ND
-
--
9-Felr95
-
50
144
89
ND
91
79
74
-
--
2-Mar-95
-
50
67
ND
ND
ND
111
ND
-
--
15-Nov-95
-
50
ND
50
ND
ND
ND
ND
-
--
28-May-96
-
50
136
ND
ND
ND
122
ND
-
--
22-Nov-96
-
50
79.0
48.0
28.0
ND
38.0
ND
-
--
17-Jun-97
-
50
370
410
33.0
39.0
36.0
69.0
-
--
1-Dec-97
-
50
140
110
110
45.0
3%
30.0
-
--
20-May-98
-
50
70.0
63.0
23.0
31.0
47.0
34.0
-
--
19-Nov-98
-
50
61.0
33.0
210
17.0
53.0
10.0
-
--
21-Ju1-99
-
50
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
50
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
50
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
50
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
50
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
50
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
50
ND
ND
ND
ND
382
ND
-
---
19-Nov-02
-
50
ND
ND
ND
ND
ND
ND
-
-
27-Jun-03
-
50
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
50
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
50
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
50
ND
ND
ND
66.0
ND
ND
-
ND
29-Jun-05
-
50
ND
54.0
56.0
ND
ND
ND
-
ND
29-Dec-05
-
50
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
50
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
50
8.0 J
ND
ND
4.1 J
4.3 J
4.1 J
-
ND
12-Jul-07
-
10
9.6 1
ND
ND
ND
ND
ND
ND
NC 2L = 1,050 uWL (10/23/07)
19-Dec-07
-
10
4.3 B
14.3 S
6.3 S
ND
ND
ND
2.4 B
102
8-Jul-08
10
5.9 B
ND
ND
ND
4.1 B
ND
-
1.2 1
17-Dec-08
0.40
10.0
2.4 B
6.3 1
ND
ND
4.6 1
0.60 B
0.49 1
9-Jul-09
0.40
50.0
3.4 B
ND
ND
ND
ND
ND
6.1 B
1.6 1
16-Dec-09
0.40
10.0
4.6 B
ND
ND
ND
7.4 B
ND
-
7.7 J
NC 2L = 1,000 uWL (02/05/10)
24-Jun-10
0.40
10.0
0.58 J
ND
ND
ND
ND
1.3 1
-
ND
13-Dec-10
0.40
50.0
4.5 B
ND
ND
ND
ND
ND
-
6.7 l
20-Jun-II
10.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-II
10.0
10.0
ND
ND
ND
ND
ND
ND
12.4
II-Jun-12
10.0
10.0
ND
20.9
ND
ND
ND
ND
ND
ND
12-Dec-12
10.0
10.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
50.0
50.0
ND
ND
ND
ND
11.8
ND
10.0
ND
5-Aug-13
10.0
50.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
50.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
10.0
10.0
ND
ND
ND
ND
16.9
ND
-
ND
18-Aug-15
5.0
10.0
7.4 J
ND
ND
ND
5.2 1
ND
-
ND
16-Feb
5.0
10.0
1 14.5
16.7
17.8
46.1
5.9 1
ND
-
ND
9-Aug-16
5.0
10.0
12.0
7.7 J
ND
ND
ND
ND
-
ND
13-Feb-17
5.0
10.0
12.3
ND
ND
ND
9.8 1
6.0 J
-
ND
22-Aug-17
5.0
10.0
ND
6.3 1
ND
ND
ND
ND
-
ND
5-Feb-18
5.0
10.0
6.7 J
17.9
ND
ND
ND
ND
-
ND
13-Aug-18
5.0
10.0
ND
ND
ND
ND
8.1 1
ND
-
ND
4-Feb
5.0
10.0
6.8 1
ND
5.0 J
ND
ND
ND
-
ND
Iron
4-Feb-19
25.0
50.0
230.0
9420
184.0
-
-
-
-
---
Manganese
4-Feb19
2.5
5.0
121.0
7640
51.8
-
-
-
-
---
Cyanide
9-Jul-09
5.0
10
ND
ND
ND
ND
46.9
ND
ND
ND
Resample>
28Sep-09
5.0
10
-
-
-
-
ND
-
-
ND
NC 2L = 70 pg/L (10/23/07)
16-Dec-09
-
-
-
-
-
-
-
-
-
-
24-Jun-10
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
-
-
-
-
-
-
-
-
-
-
Resample>
20-Jun-II
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
-
-
-
-
-
-
-
-
-
11-Jun-12
5.0
10.0
ND
6.4 1
ND
ND
8.7 1
ND
-
ND
12-Dec-12
-
-
-
-
-
-
-
-
-
-
1-May-13
5.0
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
-
-
-
-
-
-
-
-
-
24-Feb14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
5.5 1
12-Aug-14
5.0
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
5.0
10.0
9.5 B
7.5 B
8.5 B
8.8 B
11.8 B
6.6 B
-
5.6 l
16-Feb-16
4.0
10.0
ND
ND
ND
-
-
-
-
ND
13-Feb
4.0
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
4.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb
4.0
50.0
ND
ND
ND
-
-
-
-
ND
4-Feb19
6.0
8.0
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 9 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
ORGANICS
Acetone
27-0ct-01
-
100
244 B
109 B
NO
130 B
128 B
476 B
-
479
13-Jun-02
-
100
ND
NO
ND
NO
NO
NO
-
---
13-Jun-02
-
100
ND
NO
ND
NO
NO
NO
-
---
19-Nov02
-
100
ND
NO
NO
NO
NO
NO
-
---
27-Jun-03
-
100
ND
NO
ND
NO
NO
NO
-
---
30-Dec-03
-
100
ND
NO
ND
NO
NO
NO
-
NO
30-Jun-04
-
100
ND
NO
ND
NO
NO
NO
-
NO
29-Dec-04
-
100
ND
ND
ND
ND
ND
ND
-
NO
29-Jun05
-
100
ND
ND
ND
ND
ND
ND
-
NO
29-Dec-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
100
ND
NO
ND
NO
NO
NO
-
NO
29-Dec-06
-
100
ND
NO
ND
NO
NO
NO
-
NO
12-Jul-07
-
100
ND
NO
ND
NO
NO
NO
NO
NC 2L=700 woJL(10/23/07)
19-Deo-07
-
100
ND
ND
ND
NO
NO
NO
NO
4.5 l
8-Jul-08
100
ND
ND
ND
NO
NO
NO
-
NO
17-Deo-08
20.0
100
ND
ND
ND
ND
NO
NO
NO
9-Jul-09
20.0
100
ND
ND
ND
ND
NO
NO
NO
NO
16-Deo-09
2.2
100
ND
ND
NO
NO
NO
NO
-
2.8 l
NC 2L=6.000 uWL(02/05/10)
24-Jun-10
2.2
100
NO
18.5 B
6.5 B
NO
2.2 B
NO
-
7.7 l
13-Dec-10
2.2
100
ND
ND
ND
ND
NO
NO
-
NO
20-Jun-11
2.2
100
ND
NO
NO
NO
NO
2.4 B
-
3.9 J
5-Dec-11
2.2
100
NO
2.3 B
NO
NO
NO
NO
8.8 l
11-Jun-12
2.2
100
ND
3.5 B
ND
ND
ND
ND
NO
4.7 l
12-Dec-12
10.0
100
ND
ND
ND
ND
ND
ND
NO
1-Mav-13
10.0
100
ND
ND
ND
ND
ND
ND
NO
14.6 l
5-AuR-13
10.0
100
ND
ND
ND
ND
ND
ND
NO
24-Feb
50.0
100
ND
ND
ND
ND
ND
ND
NO
25.7 l
12-Aug-14
10.0
100
ND
ND
ND
ND
ND
ND
NO
22.0 J
10-Mar-15
10.0
100
ND
ND
NO
ND
ND
ND
NO
NO
18-Aug-15
10.0
100
ND
ND
NO
ND
ND
ND
NO
NO
16-Feb
10.0
100
ND
ND
NO
ND
ND
ND
NO
NO
9-AuR-16
10.0
100
ND
ND
NO
ND
ND
ND
-
NO
13-Feb17
50.0
100
ND
ND
ND
ND
ND
ND
-
NO
22-Aug-17
10.0
100
ND
ND
NO
ND
ND
ND
-
NO
5-Feb18
50.0
100
ND
ND
ND
ND
ND
ND
-
NO
13-Aug-18
50.0
100
ND
ND
NO
ND
ND
ND
-
NO
4-Feb
6.2
25
ND
ND
ND
ND
ND
ND
-
NO
Benzene
"e"94
-
5
NO
NO
NO
NO
NO
NO
-
---
1-Deo-94
-
5
NO
NO
NO
NO
NO
NO
-
---
9-Fetr95
-
5
ND
ND
NO
NO
NO
NO
-
---
2-Mar-95
-
5
NO
NO
NO
NO
NO
NO
-
---
15-Nov-95
-
5
ND
NO
NO
NO
NO
NO
-
---
28-Mav-96
-
5
NO
NO
NO
NO
NO
NO
-
---
22-Nov-96
-
5
ND
NO
NO
NO
NO
NO
-
---
17-Jun-97
-
5
ND
ND
ND
ND
NO
NO
-
---
1-Deo-97
-
5
NO
NO
NO
NO
NO
NO
-
---
20-Mav-98
-
5
NO
NO
NO
NO
NO
NO
-
---
19-Nov-98
-
5
ND
NO
NO
NO
NO
NO
-
---
21-Jul-99
-
5
ND
NO
NO
NO
NO
NO
-
---
16-Nov-99
-
5
ND
NO
NO
NO
NO
NO
-
---
10-Mav-00
-
5
NO
NO
NO
NO
NO
NO
-
---
26-0ct-00
-
5
NO
NO
NO
NO
NO
NO
-
---
18-Apr-OS
-
5
NO
NO
NO
NO
NO
NO
-
---
27-0ct-01
-
5
NO
NO
NO
NO
NO
NO
-
---
13-Jun-02
-
5
ND
ND
NO
NO
NO
NO
-
---
19-Nov-02
-
5
NO
NO
NO
NO
NO
NO
-
---
27-Jun-03
-
5
ND
ND
NO
NO
NO
NO
-
30-Deo-03
-
5
ND
NO
NO
NO
NO
NO
-
NO
30-Jun-04
-
5
ND
NO
NO
NO
NO
NO
-
NO
29-Deo-04
-
5
ND
ND
ND
ND
ND
ND
-
NO
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
NO
29-Deo-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
5
ND
NO
NO
NO
NO
NO
-
NO
29-Deo-06
-
3
NO
1.5
NO
NO
NO
NO
-
NO
Resemple>
23-Feb07
-
3
1.2
-
NO
12-Jul-07
-
1
NO
1.9
NO
NO
NO
NO
NO
NC 2L = 1 moJL (10/23/07)
19-Deo-07
-
1
NO
1.8
0.48 J
0.26 J
NO
NO
NO
NO
8-Jul-08
1
NO
1.4
0.5J
0.32 J
NO
NO
-
NO
17-Dec-08
0.25
10
NO
1.7
0.54 1
NO
NO
NO
NO
9-Jul-09
0.25
1.0
NO
1.7
0.34 1
NO
NO
NO
NO
NO
16-Dec-09
0.25
10
NO
1.7
0.60 J
0.29 1
NO
NO
-
NO
24-Jun-10
0.25
1.0
NO
0.77 J
0.49 J
0.33 1
NO
NO
-
NO
13-Dec-10
0.25
10
NO
1.8
0.59 J
0.37 1
NO
NO
-
NO
Resample>
8-FeG11
0.25
1-01.4
-
NO
20-Jun-11
0.25
1-0
NO
1.7
0.60 J
0.39 J
NO
NO
-
NO
5-Dec-11
0.25
1.0
NO
1.4
0.69 J
0.40 J
NO
NO
NO
11-Jun-12
0.25
1.0
ND
NO
0.51 J
ND
NO
NO
NO
NO
12-Dec-12
0.25
1-0
NO
1.6
0.73 J
0.32 J
NO
NO
NO
Resample>
10-Jan-13
0.25
10
NO
1.4
NO
NO
1-Mav-13
0.25
10
NO
1.3
0.56 J
0.27 J
NO
NO
NO
NO
5-AuR-13
0.25
10
NO
1.6
0.64 J
0.44 J
NO
NO
NO
24-Feb-14
0.25
10
NO
1.4
NO
NO
NO
NO
NO
NO
12-Aug-14
0.25
10
NO
1.7
0.61 J
0.25 J
NO
NO
NO
NO
10-Mar-15
0.25
10
NO
1.3
0.54 1
NO
NO
NO
NO
NO
18-Aug-'5
0.25
10
NO
1.5
0.66 J
0.32 J
NO
NO
NO
16-Feb
0.25
10
NO
1.3
0.56 1
NO
NO
NO
NO
NO
9-AuR-16
0.25
10
NO
1.4
0.53 J
0.29 1
NO
NO
NO
NO
13-Feb-17
0.25
10
NO
1.2
0.61 J
NO
NO
NO
NO
NO
22-Aug-17
0.25
10
NO
1.3
0.54 J
NO
NO
NO
NO
NO
5-Feb-18
0.25
10
NO
1.2
0.67 1
NO
NO
NO
NO
NO
13-Aug-18
0.25
10
NO
1.3
0.61 J
0.29 J
NO
NO
NO
ND
4-Feb-19
0.15
10
NO
1.6
NO
NO
NO
NO
NO
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 10 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Bromomethane
17-Dec-08
0.29
10.0
ND
ND
0.58 J
ND
ND
ND
ND
NC 2L=NE UFJL (10/23/07)
9Ju1-09
0.29
50.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
GWPS = 10 uWL (8/1/10)
13-Dec-10
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
5-Dec-11
0.29
500
ND
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.29
1ED
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
5-Aup-13
0.29
50.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.29
1ED
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.29
10.0
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.29
1ED
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.62
2.0
ND
ND
ND
ND
ND
ND
-
ND
2-Butanone (MEK)
17-Dec-08
0.96
100
ND
ND
ND
ND
1.2 J
ND
ND
NC 2L=4,200 uFJL (10/23/07)
9-Jul-09
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
NC 2L= 4,000 uWL(02/05/10)
24-Jun-10
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.96
100
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.96
100
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Mav-13
0.96
100
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.96
100
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.96
100
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.96
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
3.30
5
ND
ND
ND
ND
ND
ND
-
ND
Carbon Disulfide
17-Jun-97
-
100
ND
64.0
ND
ND
ND
ND
-
---
1-Dec-97
-
100
ND
5.0
8.0
ND
ND
ND
-
--
20-Mav-98
-
100
ND
7.5
6.2
ND
ND
ND
-
--
19-Nov-98
-
100
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
100
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
100
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
100
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
100
ND
ND
ND
ND
ND
ND
-
--
18-Apr-OS
-
100
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
100
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
100
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
100
ND
ND
ND
ND
ND
ND
-
30-De,03
-
100
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
100
ND
ND
ND
ND
ND
ND
ND
NC 2L=700 woJL(10/23/07)
19-Dec-07
-
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
100
ND
ND
ND
ND
ND
ND
-
ND
17-Deo-08
1.2
100
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
L2
100
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
1.2
100
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
L2
100
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
1.2
100
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.2
100
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
1.2
100
ND
ND
ND
ND
ND
ND
ND
ND
9-Aug-16
1.2
1Do
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
1.2
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.4
2
ND
ND
ND
ND
ND
I ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 11 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
81anke
Chlombenzene
8-Se"94
-
5
ND
10.0
7.0
ND
ND
ND
-
--
1-Dec-94
-
5
ND
ND
7.0
ND
ND
ND
-
--
9-Feb-95
-
5
ND
13.0
8.0
6.0
ND
ND
-
--
2-Mar-95
-
5
ND
12.0
9.0
ND
ND
ND
-
--
15-Nov-95
-
5
ND
14.0
8.0
9.0
ND
ND
-
--
28-Mav-96
-
5
ND
15.0
9.0
10.0
ND
ND
-
--
22-Nov-96
-
5
ND
15.0
ND
11.0
ND
ND
-
--
17-Jun-97
-
5
ND
19.0
110
14.0
ND
ND
-
--
1-Dec-97
-
5
ND
17.0
9.0
14.0
ND
ND
-
--
20-Mav-98
-
5
ND
20.0
8.6
12.0
ND
ND
-
--
19-Nov-98
-
5
ND
17.2
9.2
10.0
ND
ND
-
--
21-Jul-99
-
5
ND
14.0
10.0
11.0
ND
ND
-
--
16-Nov-99
-
5
ND
16.0
50.0
8.0
ND
ND
-
--
10-Mav-00
-
5
ND
17.0
110
10.0
ND
ND
-
--
26-0ct-00
-
5
ND
16.0
12.0
9.0
ND
ND
-
--
18-Apr-OS
-
5
ND
16.0
13.0
6.0
ND
ND
-
--
27-0ct-01
-
0.5
ND
17.0
12.0
9.0
ND
ND
-
--
13-Jun-02
-
0.5
ND
16.0
11.0
8.0
ND
ND
-
---
19-Nov-02
-
0.5
ND
18.0
15.0
9.0
ND
ND
-
-
27-Jun-03
-
0.5
ND
17.7
13.3
7.4
ND
ND
-
ND
30-D-03
-
5
ND
20.0
15.0
6.1
ND
ND
-
ND
30-Jun-04
-
5
ND
18.0
15.0
9.9
ND
ND
-
ND
29-Dec-04
-
5
ND
19.0
16.0
9.4
ND
ND
-
ND
29-Jun-05
-
5
ND
15.0
13.0
8.0
ND
ND
-
ND
29-Dec-05
-
5
ND
18.0
16.0
5.0
ND
ND
-
ND
28-Jun-06
-
5
ND
16.5
10.8
7.8
ND
ND
-
ND
29-D-06
-
3
ND
17.0
17.0
4.2
ND
ND
-
ND
12-Jul-07
-
3
ND
17.0
16.0
ND
ND
ND
ND
NC A 50 uWL (10/23/07)
19-D-07
-
3
ND
17.3
16.9
4.7
ND
ND
ND
ND
8-Jul-08
3
ND
17.2
17.4
6.5
ND
ND
-
ND
17-D-08
0.23
3.0
ND
15.9
15.6
2.6 J
ND
ND
ND
9-Jul-09
0.23
3.0
ND
16.1
17.2
6.1
ND
ND
ND
ND
16-D-09
0.23
3.0
ND
15.5
17.7
4.8
ND
ND
-
ND
24-Jun-10
0.23
3.0
ND
8.3
15.7
6.3
ND
ND
-
ND
13-Dec-10
0.23
3.0
ND
17.7
18.2
6.4
ND
ND
-
0.28 l
20-Jun-11
0.23
3.0
ND
16.3
17.2
6.7
ND
ND
-
ND
5-Dec-11
0.23
3.0
ND
14.2
17.0
5.8
ND
ND
ND
11-Jun-12
0.23
3.0
ND
12
14.8
4.4
ND
ND
ND
ND
12-Dec-12
0.23
3.0
ND
15.8
17.9
4.5
ND
ND
ND
1-May-13
0.23
3.0
ND
14.0
16.6
3.0 1
ND
ND
ND
ND
5-AuR-13
0.23
3.0
ND
14.4
15.9
4.6
ND
ND
ND
24-Feb-14
0.23
3.0
ND
16.3
2.5 J
1.4 J
ND
ND
ND
ND
12-Aug-14
0.23
3.0
ND
15.6
18.3
3.6
ND
ND
ND
ND
10-Mar-15
0.23
3.0
ND
16.0
17.0
2.1 J
ND
ND
ND
ND
18-Aug-15
0.23
3.0
ND
12.8
17.6
4.3
ND
ND
ND
16-Feb-16
0.23
3.0
ND
13.5
16.4
1.5 J
ND
ND
ND
ND
9-AuR-16
0.23
3.0
ND
13.5
16.9
4.2
ND
ND
-
ND
13-Feb-17
0.23
3.0
ND
13.6
18.0
1.3 J
ND
ND
-
ND
22-Aug-17
0.23
3.0
ND
14.2
19.9
4.2
ND
ND
-
ND
5-Feb-18
0.23
3.0
ND
13.5
17.3
0.54 1
ND
ND
-
ND
13-Aug-18
0.23
3.0
ND
14.5
22.2
3.40
ND
ND
-
ND
4-Feb-19
0.23
1.0
ND
13.6
0.4 J
1.30
ND
ND
-
ND
Chloroethane
1-Dec-97
-
SO
ND
5.0
2.0
2.0
ND
ND
-
--
20-Mav-98
-
SO
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
SO
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
SO
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
SO
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
SO
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov02
-
SO
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
SO
ND
ND
ND
ND
ND
ND
-
30-Dec-03
-
SO
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
SO
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
SO
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-O6
-
10
ND
2.2
1.9
ND
ND
ND
-
ND
12-Jul-07
-
SO
ND
ND
ND
ND
ND
ND
ND
NC A 2,800 uWL (10/23/07)
19-Dec-07
-
SO
ND
1.9
1.9
1.5
ND
ND
ND
ND
8-Jul-08
10
ND
2.2 J
2.5 J
1.8 J
ND
ND
-
ND
17-Dec-08
0.54
50.0
ND
1.6 J
ND
ND
ND
ND
ND
9-Jul-09
0.54
10.0
ND
ND
ND
3.8 1
ND
ND
ND
ND
16-Dec-09
0.54
10.0
ND
ND
2.2 J
2.0 J
ND
ND
-
ND
NC 2L= 3,000 uWL(02/05/10)
24-Jun-10
0.54
10.0
ND
ND
2.1 J
2.0 J
ND
ND
-
ND
13-Dec-10
0.54
10.0
ND
1.8 J
2.0 J
1.7 J
ND
ND
-
ND
20-Jun-11
0.54
50.0
ND
L2 J
2.2 J
2.0 J
ND
ND
-
ND
5-Dec-11
0.54
10.0
ND
1.3 J
2.0 J
1.7 J
ND
ND
ND
11-Jun-12
0.54
50.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.54
10.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.54
10.0
ND
ND
1.9 1
2.7 J
ND
ND
ND
ND
5-AuR-13
0.54
50.0
ND
ND
2.0 J
2.2 J
ND
ND
ND
24-Feb-14
0.54
10.0
ND
1.1 J
0.82 J
ND
ND
ND
ND
ND
12-Aug-14
0.54
10.0
ND
1.1 J
1.50 1
1.1 1
ND
ND
ND
ND
10-Mar-15
0.54
10.0
ND
1.0 1
1.80 J
0.81 J
ND
ND
ND
ND
18-Aug-15
0.54
1ED
ND
1.2 J
2.0 J
3.7 J
ND
ND
ND
16-Feb-16
0.54
10.0
ND
1.1 J
1.8 J
0.79 J
ND
ND
ND
ND
9-AuR-16
0.54
10.0
ND
0.68 J
2.4 J
1.5 1
ND
ND
-
ND
13-Feb-17
0.54
10.0
ND
0.76 J
1.6 J
1.1 1
ND
ND
-
ND
22-Aug-17
0.54
10.0
ND
1.3 1
2.0 1
1.6 J
ND
ND
-
ND
5-Feb-18
0.54
10.0
ND
L7 J
1.7 J
0.68 1
ND
ND
-
ND
13-Aug-18
0.54
10.0
ND
1.2 1
2.4 1
1.40 J
ND
ND
-
ND
4-Feb-19
0.49
1.0
ND
1.3
ND
0.79 J
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 12 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Chlommethane
9-Jul-09
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
NCA= 2.6 uFJL(10/23/07)
16-Dec-09
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
0.11
1.0
ND
ND
ND
ND
ND
0.11 1
-
ND
NC A= 3 uFJL (02/05/10)
13-Dec-10
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.11
10
ND
ND
ND
ND
ND
ND
ND
0.25 l
12-Aug-14
0.11
10
ND
ND
ND
ND
ND
ND
ND
ND
10-Ma-15
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.11
1-0
ND
ND
ND
ND
ND
ND
ND
16-Feb
0.11
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.11
10
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0. 11
1.0
0.20 B
ND
0.22 B
0.23 B
0.19 B
0.32 B
-
0.18 1
22-Aug-17
0.11
10
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.11
1.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.39
1.0
ND
ND
ND
ND
ND
ND
-
ND
1,2-Dichlombenzene
1-Dec-97
-
5
ND
3.0
2.0
1.0
ND
ND
-
---
20-Mav-98
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
5
ND
2.4
2.3
ND
ND
ND
-
--
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
5
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
5
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
5
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
---
30-De,03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
5
ND
1.5
2.3
ND
ND
ND
-
ND
12-Ju1-07
-
5
ND
1.4 1
1.7 J
0.31 1
ND
ND
ND
NC 2L= 24 uFJL(10/23/07)
19-D-07
-
5
ND
1.6
2.0
0.37 J
ND
ND
ND
ND
8-Jul-08
5
ND
1.6 1
2.0 J
0.39 J
ND
ND
-
ND
17-D-08
0.30
5.0
ND
1.4 J
1.9 J
ND
ND
ND
ND
9-Jul-09
0.30
5.0
ND
1.6 1
2.0 J
0.36 J
ND
ND
ND
ND
16-D-09
0.30
5.0
ND
1.6 1
2.0 1
0.33 1
ND
ND
-
ND
NC 2L= 20 u91L(02/05/10)
24-Jun-10
0.30
5.0
ND
0.96 1
1.7 1
0.31 J
ND
ND
-
ND
13-Dec-10
0.30
5.0
ND
1.9 J
1.9 J
0.43 1
ND
ND
-
ND
20-Jun-11
0.30
5.0
ND
1.5 1
L7 1
0.37 1
ND
ND
-
ND
5-Dec-11
0.30
5.0
ND
1.3 J
1.6 J
ND
ND
ND
ND
11-Jun-12
DID
5.0
ND
1.0 1
1.5 1
ND
ND
ND
ND
ND
12-Dec-12
0.30
5.0
ND
1.3 J
1.7 J
ND
ND
ND
ND
1-May-13
0.30
5.0
ND
12 1
L6 J
ND
ND
ND
ND
ND
5-AuR-13
0.30
5.0
ND
1.2 1
1.6 1
0.30 J
ND
ND
ND
24-Feb-14
0.30
5.0
ND
1.4 J
0.64 1
ND
ND
ND
ND
ND
12-AuF-14
0.30
5.0
ND
1.2 1
1.5 J
ND
ND
ND
ND
ND
10-Ma-15
0.30
5.0
ND
1.1 1
1.1 1
ND
ND
ND
ND
ND
18-Aug-15
0.30
5.0
ND
0.88 1
1.3 1
ND
ND
ND
ND
16-Feb-16
0.30
5.0
ND
1.1 1
1.4 1
ND
ND
ND
ND
ND
9-AuR-16
0.30
5.0
ND
1.2 1
1.4 J
ND
ND
ND
-
ND
13-Feb-17
0.30
5.0
ND
1.2 J
1.4 1
ND
ND
ND
-
ND
22-AuF-17
0.30
5.0
ND
1.2 1
1.5 J
ND
ND
ND
-
ND
5-Feb-18
0.30
5.0
ND
1.0 J
L4 J
ND
ND
ND
-
ND
13-Aug-18
0.30
5.0
ND
1.2 1
1.6 J
ND
ND
ND
-
ND
4-Feb-19
0.29
1.0
ND
1.0 J
ND
I ND
ND
ND
-
ND
1,4Dichlombenzene
8Sel,94
-
5
ND
ND
5.0
ND
ND
ND
-
---
1-Dec-94
-
5
ND
ND
5.0
ND
ND
ND
-
--
9-Feb-95
-
5
ND
6.0
ND
ND
ND
-
--
2-Mar-95
-
5
ND
7.0
6.0
ND
ND
ND
-
--
15-Nov-95
-
5
ND
7.0
6.0
ND
ND
ND
-
--
28-Mav-96
-
5
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
5
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
5
ND
7.6
6.2
ND
ND
ND
-
--
1-Dec-97
-
5
ND
6.0
5.0
4.0
ND
ND
-
--
20-Mav-98
-
5
ND
7.6
ND
ND
ND
ND
-
--
19-Nov-98
-
5
ND
3.7
2.8
ND
ND
ND
-
--
21-Ju1-99
-
5
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
5
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
5
ND
5.0
6.0
ND
ND
ND
-
--
18-Apr-OS
-
5
ND
ND
5.0
6.0
ND
ND
-
--
27-W-01
-
5
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
---
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
30-De,03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
3
ND
3.0
3.3
ND
ND
ND
-
ND
Resample>
23-Feb-07
-
3
3.2
3.3
-
ND
12-Jul-07
-
1
ND
3.3
2.9
0.31 J
ND
ND
ND
NC 2L = 1.4 uVL (10/23/07)
19-D-07
-
1
ND
3.0
2.7
ND
ND
ND
ND
ND
&Jul-08
1
ND
3.0
2.4
ND
ND
ND
-
ND
17-Dec-08
0.33
10
ND
2.9
2.5
ND
ND
ND
ND
9-Jul-09
0.33
10
ND
ND
ND
ND
ND
ND
ND
ND
16-Dec-09
0.33
10
ND
2.8
2.2
ND
ND
ND
-
ND
NC A 6 uFJL (02/05/10)
24-Jun-10
0.33
1.0
ND
1.6
ND
ND
ND
ND
-
ND
13-Dec-10
0.33
1.0
ND
3.1
1.9
ND
ND
ND
-
ND
20-Jun-11
0.33
1.0
ND
2.7
L6
ND
ND
ND
-
ND
5-Dec-11
0.33
1.0
ND
2.2
1.4
ND
ND
ND
ND
11-Jun-12
0.33
10
ND
1.8
1.4
ND
ND
ND
ND
ND
12-Dec-12
0.33
1.0
ND
2.4
1.3
ND
ND
ND
ND
1-May-13
013
10
ND
2.1
1.2
ND
ND
ND
ND
ND
5-AuR-13
0.33
10
ND
2.0
1.3
ND
ND
ND
ND
24-Feb-14
013
1-0
ND
2.2
1.8
ND
ND
ND
ND
ND
12-Aug-14
0.33
10
ND
2.4
1.3
ND
ND
ND
ND
ND
10-Ma-15
0.33
10
ND
2.2
1.1
ND
ND
ND
ND
ND
18-Aug-15
0.33
10
ND
1.5
1.1
ND
ND
ND
ND
16-Feb-16
0.33
1-0
ND
2.0
1.0
ND
ND
ND
ND
ND
9-AuR-16
013
10
ND
1.9
1.0
ND
ND
ND
-
ND
13-Feb-17
0.33
1.0
ND
1.9
0.90 J
ND
ND
ND
-
ND
22-AuF-17
0.33
10
ND
1.9
0.96 J
ND
ND
ND
-
ND
5-Feb-18
0.33
1.0
ND
1.6
1.1
ND
ND
ND
-
ND
13-Aug-18
0.33
10
ND
1.9
1.1
ND
ND
ND
-
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 13 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Trans-1,4Dichloro-2-Butene
20-May-98
-
100
ND
ND
5.1
ND
ND
ND
-
--
19-Nov-98
-
100
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
100
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
100
ND
ND
ND
ND
ND
ND
---
--
10-Mav-00
-
100
ND
ND
ND
ND
ND
ND
---
--
26-0ct-00
-
100
ND
ND
ND
ND
ND
ND
---
--
18-Apr-01
-
100
ND
ND
ND
ND
ND
ND
---
--
27-0ct-01
-
100
ND
ND
ND
ND
ND
ND
---
--
19-Nov02
-
100
ND
ND
ND
ND
ND
ND
---
---
27-Jun-03
-
100
ND
ND
ND
ND
ND
ND
-
30-De,03
-
100
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
100
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
29-D-06
-
100
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
100
ND
ND
ND
ND
ND
ND
ND
NC 2L=NE UWL(10/23/07)
19-Deo-07
-
100
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
100
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
1.0
100
ND
ND
ND
ND
ND
ND
ND
9-Jul-09
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
1"-09
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
1.0
100
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
1.0
100
ND
ND
ND
ND
ND
ND
ND
1-Mav-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
1.0
100
ND
ND
ND
ND
ND
ND
ND
24-Feb14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
12-AuF-14
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
1.0
100
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
1.0
100
ND
ND
ND
ND
ND
ND
ND
ND
9-AUR-16
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
13-Feb
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
1.0
100
ND
ND
ND
ND
ND
ND
-
ND
4-Feb19
0.5
1
ND
ND
ND
ND
ND
ND
-
ND
1,4-Dioxane (p-Dioxane)
13-Aug-18
1.9
10
ND
88
53.1
40.7
2.0 1
ND
ND
4-Feb
1.9
2
ND
132
49.6
498
ND
ND
ND
ND
1,1-Dichloroethane
1-D-97
-
5
ND
ND
1.0
ND
ND
ND
-
---
20-Mav-98
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
5
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
-
--
10-Mav-00
-
5
ND
ND
ND
ND
ND
ND
-
--
26-0ct-00
-
5
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
5
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
---
30-De,03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-D-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
5
ND
ND
0.36 J
0.52 1
ND
ND
ND
NC 2L = 70 uWL (10/23/07)
19-D-07
-
5
ND
ND
ND
0.57 J
ND
ND
ND
ND
8-Jul-08
5
ND
ND
ND
0.60 1
ND
ND
-
ND
17-D-08
0.32
5.0
ND
ND
ND
0.51 J
ND
ND
ND
9-Jul-09
0.32
5.0
ND
ND
ND
0.84 J
ND
ND
ND
ND
16-D-09
0.32
5.0
ND
ND
ND
0.73 J
ND
ND
-
ND
NC 6uFJL(02/05/10)
24-Jun-10
012
5.0
ND
ND
ND
0.53 J
ND
ND
-
ND
13-Dec-10
0.32
5.0
ND
ND
ND
0.60 J
ND
ND
-
ND
20-Jun-11
012
5.0
ND
ND
ND
0.63 J
ND
ND
-
ND
5-Dec-11
032
5.0
ND
ND
ND
0.67 J
ND
ND
ND
11-Jun-12
012
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.32
5.0
ND
ND
ND
0.61 1
ND
ND
ND
1-Mav-13
0.32
5.0
ND
ND
ND
0.62 J
ND
ND
ND
ND
8-Mav-13
0.32
5.0
ND
ND
ND
0.53 J
ND
ND
ND
24-Feb
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
12-Aug-14
0.32
5.0
ND
ND
ND
0.47 J
ND
ND
ND
ND
10-Mar-15
0.32
5.0
ND
ND
ND
0.50 J
ND
ND
ND
ND
18-Aug-15
0.32
5.0
ND
ND
ND
0.49 J
ND
ND
ND
16-Feb-16
0.32
5.0
ND
ND
ND
0.45 J
ND
ND
ND
ND
9-AuR-16
0.32
5.0
ND
ND
ND
0.34 J
ND
ND
-
ND
13-Feb
0.32
5.0
ND
ND
ND
0.33 1
ND
ND
-
ND
22-Aug-17
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
-
ND
5-Feb18
0.32
5.0
ND
ND
ND
0.38 1
ND
ND
-
ND
13-Aug-18
0.32
5.0
ND
ND
ND
0.37 J
ND
ND
-
ND
4-Feb
0.27
1.0
ND
ND
ND
0.36 1
ND
ND
-
ND
1,2-Dichloroethane
17-D-08
0.12
1.0
ND
ND
0.15 J
ND
ND
ND
ND
NCA= 0.38 uFJL(10/23/07)
9-Jul-09
0.12
1.0
ND
ND
ND
ND
ND
ND
ND
0.19 1
16-D-09
0.12
1.0
ND
ND
0.14 J
ND
ND
ND
-
ND
NC A= 0.4 uFJL (02/05/10)
24-Jun-10
0.12
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
0.12
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
092
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.12
1.0
ND
ND
ND
ND
0.18 J
ND
ND
11-Jun-12
092
1-0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.12
10
ND
ND
ND
ND
-0.20 J
ND
0.20(ND) 1
1-Mav-13
092
10
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
0.12
10
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.12
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.12
10
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.12
10
ND
ND
ND
ND
ND
ND
ND
ND
18-AuF-15
0.24
10
ND
ND
0.33 J
0.29 J
0.36 J
ND
16-Feb-16
0.24
10
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.24
10
ND
ND
ND
ND
ND
ND
-
ND
13-Feb17
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-AuF-17
0.24
10
ND
ND
ND
ND
ND
ND
-
ND
5-Feb18
0.24
1.0
0.25 J
ND
0.37 J
ND
0.43 J
ND
-
ND
13-Aug-18
0.24
1-0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb19
0.34
1.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 14 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Ethylbenzene
17-Dec-08
0.30
1.0
ND
0.31 J
ND
ND
ND
ND
ND
NCA= 550 uF✓L(10/23/07)
9-Ju1-09
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
16-Deo-09
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
NC 2L=600 woJL(02/05/10)
24-Jun-10
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-10
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-AuQ-13
0.30
10
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.30
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.30
10
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.30
10
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.30
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.30
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.30
10
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
Isobutanol
24-Jun-10
35.0
100
ND
59.0 J
ND
ND
ND
ND
-
ND
NC A= NE uFJL (02/05/10)
13-Dec-10
-
20-Jun-11
35.0
100
ND
39.5 J
ND
ND
NO
ND
-
ND
5-Dec-11
11-Jun-12
35.0
100.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
-
1-May-13
35.0
100
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
35.0
100
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
35.0
100
ND
ND
ND
ND
ND
ND
-
ND
10-Mar-15
35.0
100
ND
ND
ND
-
-
-
-
ND
16-Fe116
35.0
100
ND
42.5 J
ND
-
-
-
-
ND
13-Feb-17
35.0
100
ND
ND
ND
-
-
-
-
ND
22-Aug-17
35.0
100
ND
ND
ND
-
-
-
-
ND
5-Feb-18
35.0
100
ND
ND
ND
-
-
-
-
ND
4-Feb-19
66.4
100
ND
ND
ND
-
-
-
-
ND
Methylene Chloride
9-Jul-09
0.97
2.0
ND
ND
ND
ND
ND
ND
ND
9.6
NCA= 4.3 uFJL(10/23/07)
16-Deo-09
0.97
2.0
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
0.97
1.0
ND
19.0
ND
ND
ND
ND
-
ND
NC 2L = 5 woJL (02/05/10) Re.
12-Aug-10
0.97
1.0
ND
-
ND
13-Dec-10
0.97
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.97
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.97
1.0
1.0
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.97
1.0
1.3
1.1
1.6
ND
ND
ND
ND
ND
16-Feb-16
0.97
1.0
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.97
1.0
ND
ND
1.0 B
ND
ND
ND
-
2.2 B
13-Feb-17
0.97
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.97
1.0
ND
ND
ND
ND
ND
ND
-
1.4 C
5-Feb-18
0.97
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.97
1.0
ND
ND
ND
ND
ND
ND
-
6.6
4-Feb-19
3.70
5.0
ND
ND
ND
ND
ND
ND
-
ND
Naphthalene
8-Jul-08
-
10
ND
3.8 J
ND
ND
ND
ND
-
ND
NCA= 21 uVL(10/23/07)
17-Dec-08
-
9-Jul-09
0.24
10.0
ND
2.4 J
ND
ND
ND
ND
-
ND
16-Dec-09
-
NC 2L = 6 moJL (02/05/10)
24-Jun-10
0.24
10.0
ND
7.4 J
ND
ND
ND
ND
-
ND
13-Dec-SO
-
20-Jun-11
0.24
10.0
ND
4.6 1
ND
ND
ND
ND
-
0.39 J
5-Dec-11
11-Jun-12
0.2
10.0
ND
4.6 J
ND
ND
ND
ND
ND
ND
12-Dec-12
-
1-May-13
0.24
10.0
ND
5.1 1
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.24
10.0
ND
5.8 J
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.2
10
ND
5.4 J
ND
-
-
-
-
ND
16-Feb
0.2
10
ND
5.7 1
ND
-
-
-
-
ND
13-Feb-17
0.2
10
ND
6.1 1
ND-
-
-
-
ND
22-Aug-17
0.2
10
ND
7.0 1
0.45 J
-
-
-
-
ND
5-Feb-18
0.2
10
ND
5.7 1
ND
-
-
-
-
ND
4-Feb-19
0.4
1
ND
4.2
ND
-
-
-
-
ND
Toluene
20-May-98
-
5
ND
ND
8.1
ND
ND
ND
-
-
19-Nov-98
-
5
ND
ND
ND
ND
ND
ND
-
---
21-Jul-99
-
5
ND
ND
ND
ND
ND
ND
-
---
16-Nov-99
-
5
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
5
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
5
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
5
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
5
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
5
ND
ND
ND
ND
ND
ND
-
---
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
-
30-Deo-03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-04
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-05
-
5
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-06
-
5
ND
ND
ND
ND
ND
ND
-
ND
12-Ju1-07
-
1
ND
0.49 B
ND
ND
ND
ND
0.34 J
NC A= 1,000 uVL (10/23/07)
19-Deo-07
-
1
ND
0.51 1
ND
ND
ND
ND
ND
ND
8-Jul-08
1
ND
0.39 J
ND
ND
1.3
ND
-
ND
17-Deo-08
0.26
1.0
1.4
1.6
ND
ND
11.7
ND
ND
9-Jul-09
0.26
1.0
ND
0.46 J
ND
ND
ND
ND
ND
ND
16-Deo-09
0.26
1.0
ND
0.42 J
ND
ND
ND
ND
-
ND
NC A= 600 woJL (02/05/10)
24-Jun-10
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Deo-10
0.26
1.0
ND
0.54 J
ND
ND
ND
ND
-
ND
20-Jun-11
0.26
1.0
ND
0.34 J
ND
ND
ND
ND
-
ND
5-Dec-11
0.26
1.0
ND
0.28 J
ND
ND
0.30 1
ND
ND
11-Jun-12
0.26
1.0
ND
0.28 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.26
1.0
ND
0.29 J
ND
ND
0.36 1
ND
ND
1-May-13
0.26
10
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
0.26
10
ND
0.29 1
ND
ND
ND
ND
ND
24-Feb-14
0.26
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.26
10
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.26
10
ND
ND
ND
ND
ND
ND
ND
ND
18-AuF-15
0.26
10
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.26
10
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.26
10
ND
0.33 1
ND
ND
ND
ND
-
ND
13-Feb-17
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-AuF-17
0.26
10
ND
ND
ND
ND
ND
ND
-
ND
5-Feb-18
0.26
1.0
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.26
10
ND
ND
ND
ND
0.44 1
ND
-
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 15 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Vinyl Chloride
8-So"94
-
10
ND
ND
12.0
ND
ND
ND
-
--
1-Dec-94
-
10
ND
ND
13.0
ND
ND
ND
-
--
9-Feb-95
-
10
ND
ND
150
ND
ND
ND
-
--
2-Mar-95
-
10
ND
ND
14.0
ND
ND
ND
-
--
1SNov-95
-
10
ND
ND
11.0
ND
ND
ND
-
--
28-May-96
-
10
ND
ND
ND
ND
ND
ND
-
--
22-Nov-96
-
10
ND
ND
ND
ND
ND
ND
-
--
17-Jun-97
-
10
ND
ND
ND
ND
ND
ND
-
--
1-Dec-97
-
10
ND
ND
7.0
4.0
ND
ND
-
--
20-May-98
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-98
-
10
ND
ND
ND
ND
ND
ND
-
--
21-Jul-99
-
10
ND
ND
ND
ND
ND
ND
-
--
16-Nov-99
-
10
ND
ND
ND
ND
ND
ND
-
--
10-May-00
-
10
ND
ND
ND
ND
ND
ND
-
--
26-W-00
-
10
ND
ND
ND
ND
ND
ND
-
--
18-Apr-01
-
10
ND
ND
ND
ND
ND
ND
-
--
27-W-01
-
10
ND
ND
ND
ND
ND
ND
-
--
13-Jun-02
-
10
ND
ND
ND
ND
ND
ND
-
--
19-Nov-02
-
10
ND
ND
ND
ND
ND
ND
-
--
27-Jun-03
-
10
ND
ND
ND
ND
ND
ND
-
--
30-Dec-03
-
10
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Deo-06
ND
ND
0.98 J
ND
ND
ND
-
ND
Resample>
23-Feb-07
-
5.5
1.0
-
ND
12-Ju1-07
-
1
ND
ND
ND
ND
ND
ND
ND
NC 0.015 uWL(10/23/07)
19-Deo-07
-
1
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
1
ND
ND
0.76 J
ND
ND
ND
-
ND
17-Deo-08
0.62
1.0
ND
ND
0.76 J
ND
ND
ND
ND
9-Jul-09
0.62
1.0
ND
ND
0.99 J
ND
ND
ND
ND
ND
16-Deo-09
0.62
1.0
ND
ND
0.81 J
ND
ND
ND
-
ND
NC 2L=0.03 upJL(02/05/10)
24-Jun-10
0.62
1.0
ND
ND
0.77 J
ND
ND
ND
-
ND
13-Dec-10
0.62
1.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.62
1.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
11-Jun-12
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Dec-12
0.62
1.0
ND
ND
ND
ND
ND
ND
ND
1-May-13
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
5-AuR-13
0.62
10
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.62
10
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.62
10
ND
ND
ND
ND
ND
ND
ND
ND
9-AuR-16
0.62
10
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0.62
1.0
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.62
10
ND
ND
ND
ND
ND
ND
-
ND
SFeb-18
0.62
1.0
ND
ND
0.63 J
ND
ND
ND
-
ND
13-Aug-18
0.62
10
ND
ND
0.72 1
ND
ND
ND
-
ND
4-Feb-19
0.24
1.0
ND
ND
ND
ND
ND
ND
-
ND
%ylene (Total)
29-Dec-06
-
5
ND
1.4
ND
ND
ND
ND
-
ND
12-Jul-07
-
4
ND
1.2 J
ND
ND
ND
ND
ND
NC A= 530 upJL (10/23/07)
19-Dec-07
-
4
ND
2.0
ND
ND
ND
ND
ND
ND
8-Jul-08
4
ND
1.1 J
ND
ND
ND
ND
-
ND
17-Deo-08
0.66
2.0
1.4 J
2.7
ND
ND
ND
ND
ND
9-Jul-09
0.66
2.0
ND
1.5 1
ND
ND
ND
ND
ND
ND
16-Dec09
0.66
2.0
ND
2.2
ND
ND
ND
ND
-
ND
NC 2L=500 upJL(02/05/10)
24-Jun-10
0.66
2.0
ND
0.73 J
ND
ND
ND
ND
-
ND
13-Deo-10
0.66
2.0
ND
2.0
ND
ND
ND
ND
-
ND
20-Jun-11
0.66
2.0
ND
1.4 J
ND
ND
ND
ND
-
ND
SDec-11
0.66
2.0
ND
1.1 1
ND
ND
ND
ND
ND
11-Jun-12
0.66
2.0
ND
0.91 J
ND
ND
ND
ND
ND
ND
12-Dec-12
0.66
5.0
ND
0.97 J
ND
ND
ND
ND
ND
1-Mav-13
0.66
5.0
ND
0.68 1
ND
ND
ND
ND
ND
ND
5-AUR-13
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
24-Feb-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
10-Mar-15
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
18-Aug-15
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
16-Feb-16
0.66
5.0
ND
ND
ND
ND
ND
ND
ND
ND
9-16-16
0.66
50
ND
ND
ND
ND
ND
ND
-
ND
13-Feb-17
0.66
ED
ND
ND
ND
ND
ND
ND
-
ND
22-Aug-17
0.66
50
ND
ND
ND
ND
ND
ND
-
ND
SFeb-18
0.66
ED
ND
ND
ND
ND
ND
ND
-
ND
13-Aug-18
0.66
5.0
ND
ND
ND
ND
ND
ND
-
ND
4-Feb-19
0.63
1.0
ND
ND
ND
ND
ND
ND
-
ND
Bis(2-Ethylhexvl)phthalate
24-Feb-14
0.79
15.0
2.6 1
ND
ND
ND
ND
ND
ND
ND
NC A= 3 upJL (2/5/10)
15-Apr-14
0.79
15.0
ND
ND
ND
ND
ND
ND
ND
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.5
15
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.9
15
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.9
15
ND
ND
ND
-
-
-
-
ND
22-Aug-17
2.3
15
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.4
16
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.4
6
ND
ND
ND
-
-
-
-
ND
N-Nltroso-di-n-butylamine
24-Feb-14
7.5
10.0
ND
ND
ND
8.6 J
ND
ND
ND
ND
12-Au9-14
-
-
-
-
10-Mar-15
1.3
10
ND
ND
ND
-
-
-
-
ND
16-Feb-16
2.2
10
ND
ND
ND
-
-
-
-
ND
13-Feb-17
2.2
10
ND
ND
ND
-
-
-
-
ND
22-Aug-17
1.6
10
ND
ND
ND
-
-
-
-
ND
SFeb-18
1.6
10
ND
ND
ND
-
-
-
-
ND
4-Feb-19
2.2
10
ND
ND
ND
-
-
-
-
ND
Benzo(R,h,i)perylene
20-Jun-11
0.4
10.0
ND
ND
ND
ND
ND
1.4 1
-
ND
INC A= 200 upJL (2/5/10)
5-Dec-11
-
11-Jun-12
0.38
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
0.38
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-AUR-13
-
24-Feb-14
0.38
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.4
50.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.4
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
2.1
50.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.2
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.8
50.0
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 16 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Diben4a,h)anthracene
20-Jun-11
0.55
10.0
ND
ND
ND
ND
ND
1.5 J
-
ND
NC 2L= 0.005 WL(2/5/10)
5-Dec-11
-
11-Jun-12
0.55
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
0.55
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Mg-13
-
24-Feb-14
0.55
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.6
50.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.6
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
2.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.1
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.9
10.0
ND
ND
ND
-
-
-
-
ND
Fluorene
24-Jun-10
3.8
12.2
ND
4.3 J
ND
ND
ND
ND
-
ND
Resemple>
12-Aug-10
3.1
10.0
-
ND
-
-
-
-
-
ND
NC 2L = 300 uPJL (2/5/10)
13-Dec-10
-
20-Jun-11
0.2
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
11-Jun-12
0.21
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
0.21
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.21
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
1.0
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.2
50.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.2
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
1.6
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
1.6
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
3.0
10.0
ND
ND
ND
-
-
-
-
ND
Indeno(1,2,3cd)pvrene
20-Jun-11
0.29
10.0
ND
ND
ND
ND
ND
1.3 J
-
ND
NC 2L = 0.05 upJL (2/5/10)
5-Dec-11
-
11-Jun-12
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.29
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.5
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.3
50.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.3
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
2.0
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
2.1
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.7
10.0
ND
ND
ND
-
-
-
-
ND
2-Methvinaphthalene
24-Jun-10
5.1
12.2
ND
38.9
ND
ND
ND
ND
-
ND
Resample>
12-Aug-10
4.2
10
-
ND
-
-
-
-
-
ND
NC 2L=30 WL(02/05/10)
13-Dec-10
-
20-Jun-11
0.3
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
11-Jun-12
0.28
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
0.28
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.28
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
1.0
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.3
50.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.3
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
1.4
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
1.5
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
2.8
10.0
ND
ND
ND
-
-
-
-
ND
Phorate
18-Apr-01
-
10
3.2
ND
ND
ND
-
---
27-0ct-01
-
5
ND
8.1
ND
ND
ND
ND
-
---
27-W-01
-
0.5
8.1
1.3
ND
ND
-
--
13-Jun-02
-
5
ND
ND
ND
ND
ND
ND
-
---
13-Jun-02
-
0.5
ND
ND
ND
ND
-
---
19-Nov02
-
5
ND
ND
ND
ND
ND
ND
-
27-Jun-03
-
5
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
-
28-Jun-06
-
10
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
-
12-Ju1-07
-
10
ND
ND
ND
ND
ND
ND
ND
NC 2L= 1.4 WL(10/23/07)
19-Dec-07
-
ND
8-Jul-08
-
10
ND
ND
ND
ND
ND
ND
-
ND
17-Dec-08
-
9-Jul-09
6.6
22.2
ND
ND
ND
ND
ND
ND
-
ND
16Dec-09
-
NC 2L = 1 upJL (02/05/10)
24-Jun-10
6.5
24.1
ND
ND
ND
ND
ND
ND
-
ND
13-Dec-SO
-
20-Jun-11
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
-
11-Jun-12
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
-
1-Mav-13
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
5.4
10.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.8
10.0
ND
ND
ND
-
-
-
-
ND
16-Feb-16
1.1
10.0
ND
ND
ND
-
-
-
-
ND
13-Feb-17
1.1
10.0
ND
ND
ND
-
-
-
-
ND
22-Aug-17
1.7
10.0
ND
ND
ND
-
-
-
-
ND
5-Feb-18
1.8
10.4
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.1
10.0
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 17 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
I MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
Beta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.16
ND
ND
ND
-
ND
NC 0.019 uFJL(10/23/07)
19-Jul-12
0.050
0.050
-
-
ND
-
-
-
-
-
12-Dec-12
-
1-Mav-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.050
0.050
ND
0.052
ND
ND
ND
ND
-
ND
Resample>
15-Apr-14
0.050
0.050
-
ND
-
-
-
-
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.1
0.1
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.1
0.1
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.1
0.1
ND
ND
ND
-
-
-
-
ND
5-Feb-18
0.1
0.1
ND
ND
ND
-
-
-
-
ND
4-Feb-19
0.1
0.1
ND
ND
ND
-
-
-
-
ND
Delta-BHC
11-Jun-12
0.050
0.050
ND
ND
0.090
ND
ND
ND
-
ND
NC 0.019 uFJL(10/23/07)
19-Jul-12
0.050
0.050
-
-
ND
-
-
-
-
-
12-Dec-12
-
1-May-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
-
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.050
0.050
ND
ND
ND
-
-
-
-
ND
5-Feb-18
0.052
0.052
ND
ND
ND
-
-
-
-
ND
4-Feb-19
0.050
0.050
ND
ND
ND
-
-
-
-
ND
gamma-BHC(Undane)
27-Jun-03
-
1.05
ND
0.085
ND
ND
ND
ND
-
ND
30-Dec-03
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
NC 2L= 0.2 u91L(10/23/07)
19-Dec-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
0.50
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
9-Jul-09
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
16-D-09
0.01
0.1
ND
ND
ND
ND
ND
ND
-
ND
NC 2L = 0.03 uFJL (02/05/10)
24-Jun-10
0.00021
0.010
ND
ND
0.052
ND
ND
ND
-
ND
Resample>
12-Aug-10
0.00020
0.010
ND
-
ND
13-Dec-10
0.00020
0.050
ND
ND
0.013 J
ND
ND
ND
-
ND
20-Jun-11
0.00020
0.050
ND
ND
0.066
ND
ND
ND
-
ND
Resample>
2&Jul-11
0.00020
0.010
ND
-
ND
5-Dec-11
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
1-Mav-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
0.050
0.050
ND
ND
ND
-
-
-
-
ND
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
18-Aug-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
9-AuR-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
13-Fe117
0.050
0.050
ND
ND
ND
-
-
-
-
ND
5-Feb-18
0.052
0.052
ND
ND
ND
-
-
-
-
ND
4-Feb-19
0.050
0.050
ND
ND
ND
-
-
-
-
ND
Heptachlor
27-Jun-03
-
1.05
ND
0.03
0.17
ND
ND
ND
-
ND
30-Dec-03
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-05
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-06
-
0.05
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
NC 2L = 0.0078 uFJL (10/23/07)
19-Dec-07
-
0.05
ND
ND
ND
ND
ND
ND
ND
ND
8-Jul-08
0.05
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
9-Jul-0 9
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
16-Dec-09
0.02
0.1
ND
ND
ND
ND
ND
ND
-
ND
NC 2L= 0.008 u91L(02/05/10)
24-Jun-10
0.0015
0.010
ND
ND
ND
ND
ND
ND
-
ND
13-D-10
0.0500
0.0015
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.050
0.0015
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.050
0.056
ND
0.062
ND
ND
ND
ND
-
ND
Resample>
25-Jan-12
0.050
0.0500
ND
-
ND
11-Jun-12
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
12-De,12
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
1-Mav-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.050
0.050
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
0.050
0.050
ND
ND
ND
-
-
-
-
ND
10-Mar-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
18-Aug-15
0.050
0.050
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
9-Aup-16
0.050
0.050
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.050
0.050
ND
ND
ND
-
-
-
-
ND
5-Feb-18
0.052
0,052
ND
ND
ND
-
-
-
-
ND
4Feb-19
0.050
0.050
ND
ND
ND
-
-
-
-
ND
2,4-D
27-Jun-03
-
3
5.9
ND
ND
ND
-
30-Dec-03
-
2
ND
ND
ND
ND
ND
ND
-
ND
30-Jun-04
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-Dec-04
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-Jun-05
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-05
-
2
ND
ND
ND
ND
ND
ND
-
ND
28-Jun-06
-
2
ND
ND
ND
ND
ND
ND
-
ND
29-D-06
-
2
ND
ND
ND
ND
ND
ND
-
ND
12-Jul-07
-
2
ND
ND
ND
ND
ND
ND
ND
NC 70 uWL(10/23/07)
19-D-07
-
2
ND
ND
ND
ND
ND
ND
ND
ND
8-Apr-08
-
2
ND
ND
ND
ND
ND
ND
-
ND
17-D-08
-
2.0
ND
ND
ND
ND
ND
ND
-
ND
9-Jul-09
2.0
ND
ND
ND
ND
ND
ND
-
ND
16-Dec-09
0.11
5.0
ND
ND
ND
ND
ND
ND
-
ND
24-Jun-10
0.23
2.1
ND
ND
ND
ND
ND
ND
-
ND
10-Dec-10
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
20-Jun-11
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
5-Dec-11
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
11-1un-12
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
12-Dec-12
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
1-Mav-13
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
5-AuR-13
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
24-Feb-14
0.22
2.0
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
0.22
2.0
ND
ND
ND
-
-
-
-
ND
10-Mar-15
0.24
2.1
ND
ND
ND
-
-
-
-
ND
18-Aug-15
0.24
2.1
ND
ND
ND
-
-
-
-
ND
16-Feb-16
0.23
1.0
ND
ND
ND
-
-
-
-
ND
9-Aup-16
0.24
10
ND
ND
ND
-
-
-
-
ND
13-Feb-17
0.22
0.9
ND
ND
ND
-
-
-
-
ND
22-Aug-17
0.24
10
ND
ND
ND
-
-
-
-
ND
5-Feb-18
0.24
1.0
ND
ND
ND
-
-
-
-
ND
4-Feb-19
1.60
5.0
ND
ND
ND
-
-
-
-
ND
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 18 of 19

APPENDIX E: Historical Constituents in Groundwater
Analyte
Sample Date
DL
RL
MW-1R
MW-2R
MW3R
MW-4
MW-5
MW-6
NES-1
Blanks
4,4'-DDD
11-Jun-12
0.05
0.05
ND
ND
0.13
ND
ND
ND
-
ND
Resamp,,
19-Jul-12
0.05
0.10
-
-
ND
-
-
-
-
-
NC 2L = 0.1 uWL (2/5/10)
12-Dec-12
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
24Feb14
0.050
0.10
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.050
0.10
ND
ND
ND
-
-
-
-
ND
16-Feb16
0.050
0.10
ND
ND
ND
-
-
-
-
ND
13-Feb17
0.050
0.10
ND
ND
ND
-
-
-
-
ND
5-Feb
0.052
0.10
NO
NO
ND
-
-
-
-
NO
4Feb19
0.050
0.05
NO
NO
ND
-
-
-
-
NO
4,4'-DDT
11-Jun-12
0.05
0.05
ND
ND
0.10
ND
ND
ND
-
ND
Resample>
19-Jul-12
0.05
0.10
-
-
0.063 J
-
-
-
-
-
NC 2L = 0.1 uFJL (2/5/10)
12-Dec-12
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
-
ND
5-Aug-13
-
24Feb14
0.050
0.10
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
-
-
-
-
10-Mar-15
0.050
0.10
ND
NO
ND
-
-
-
-
ND
16-Feb16
0.050
0.10
ND
ND
ND
-
-
-
-
ND
13-Feb17
0.050
0.10
ND
ND
ND
-
-
-
-
ND
5-Feb
0.052
0.10
NO
NO
ND
-
-
-
-
ND
4Feb19
0.050
0.05
ND
NO
ND
-
-
-
-
ND
Dinoseb
10-Mar-15
0.061
1.1
ND
ND
0.11 1
-
-
-
-
ND
16-Feb16
0.058
0.19
ND
ND
ND
-
-
-
-
ND
13-Feb17
0.057
0.19
ND
ND
ND
-
-
-
-
ND
22-Aug-17
0.062
0.20
NO
ND
ND
-
-
-
-
NO
5-Feb
0.061
0.20
ND
ND
ND
-
-
-
-
ND
4Feb19
1.200
5.00
ND
ND
ND
-
-
-
-
ND
Endrin aldehyde
11-Jun-12
0.050
0.050
ND
ND
0.14
NO
ND
ND
-
-
NC2L=2(2/5/10)
12-Dec-12
0.050
0.10
ND
ND
ND
ND
ND
ND
-
1-May-13
0.050
0.10
ND
ND
ND
ND
ND
ND
-
NO
5-Aug-13
0.050
0.10
ND
ND
ND
ND
ND
ND
-
NO
24Feb14
0.050
0.10
ND
ND
ND
ND
ND
ND
-
ND
12-Aug-14
0.050
0.10
ND
ND
ND
-
-
-
-
ND
10-Mar-15
0.050
0.10
ND
ND
ND
-
-
-
-
ND
18-Aug-15
0.050
0.10
ND
ND
ND
-
-
-
-
ND
16-Feb16
0.050
0.10
ND
ND
ND
-
-
-
-
ND
9-Aug-16
0.050
0.10
NO
ND
ND
-
-
-
-
NO
13-Feb17
0.050
0.10
ND
ND
ND
-
-
-
-
ND
5-Feb
0.052
0.10
ND
ND
ND
-
-
-
-
ND
4Feb19
0.050
0.05
ND
ND
ND
-
-
-
-
ND
Diethylphthalate
4Feb19
2.00
10.00
ND
7.1 J
ND
-
-
-
-
ND
Endosulfan I
4Feb19
0.05
0.05
-
0.078
0.19
-
-
-
-
-
Dichlorodi luoromethane
5-Feb-18
0.21
5.0
ND
0.36 J
ND
-
-
-
-
ND
4Feb19
0.23
1.0
NO
ND
ND
-
-
-
-
ND
Notes:
All concentrations are in micrograms per liter (uFJL).
RL Reporting Limit (SWSL for December 2006 - present).
DL = Labomtory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above labo story reporting limit.
NC 2L = North Carolina Groundwater Standards from 15A NCAC 2L.0202.
GW PS = Groundwater Protection Standards established by the DENR Solid Waste Section (SWS).
When the NC 2L has not been established, the GWPS will be used.
Bold values for groundwater are above the NC 2L Standards or G WPS.
-= Well was not monitored and/or not reported.
Granville County LaBella Associates
Butner Landfill, Permit No. 39-02 Page 19 of 19

Appendix F
Statistical Analysis Calculation Sheets

Concentrations (Ng/L)
Parameter: Cobalt
Original Data (Not Transformed)
Non -Detects Replaced with Detection Limit
Total Measurements: 52
Total Non -Detect: 0
Percent Non -Detects: 0%
Total Background Measurements: 52
There is 1 background location
Loc.
MW-1 R
Meas. ND Date
Conc.
Original
52 0 (0%) 9/8/1994
9.5
9.5
12/1 /1994
11
11
2/9/1995
20
20
3/2/1995
16
16
11/15/1995
20
20
5/28/1996
30
30
11/22/1996
6
6
6/17/1997
130
130
12/1 /1997
32
32
5/20/1998
15
15
11/19/1998
21
21
7/21/1999
9.5
9.5
11/16/1999
9.5
9.5
5/10/2000
9.5
9.5
10/26/2000
9.5
9.5
4/18/2001
9.5
9.5
10/27/2001
9.5
9.5
6/13/2002
9.5
9.5
11/19/2002
9.5
9.5
6/27/2003
9.5
9.5
12/30/2003
9.5
9.5
6/30/2004
9.5
9.5
12/29/2004
9.5
9.5
6/29/2005
9.5
9.5
12/29/2005
9.5
9.5
6/28/2006
9.5
9.5
12/29/2006
9.5
9.5
7/12/2007
9.5
9.5
12/19/2007
2.5
2.5
7/8/2008
10.3
10.3
12/17/2008
2.1
2.1
7/9/2009
9.5
9.5
12/16/2009
9.5
9.5
6/24/2010
9.5
9.5
12/13/2010
2.5
2.5
6/20/2011
9.5
9.5
12/5/2011
9.5
9.5
6/11 /2012
9.5
9.5
12/12/2012
9.5
9.5
5/1/2013
9.5
9.5
8/5/2013
9.5
9.5
2/24/2014
9.5
9.5
8/12/2014
9.5
9.5
3/10/2015
9.5
9.5
8/18/2015
9.5
9.5
Page 1

2/16/2016
9.5
9.5
8/9/2016
9.5
9.5
2/13/2017
9.5
9.5
8/22/2017
9.5
9.5
2/5/2018
9.5
9.5
8/13/2018
9.5
9.5
2/4/2019
4.5
4.5
There are 0 compliance locations
Loc. Meas. ND Date Conc. Original
There are 0 unused locations
Loc. Meas. ND Date Conc. Original
Page 2

Shapiro-Francia Test of Normality
Parameter: Cobalt
All Locations
Normality Test of Parameter Concentrations
Original Data (Not Transformed)
Non -Detects Replaced with Detection Limit
Total Number of Measurements = 52
i
x(i)
m(i)
sum(m^2)
sum(mx)
1
2.1
-2.09693
4.39712
-4.40356
2
2.5
-1.78661
7.5891
-8.87008
3
2.5
-1.58927
10.1149
-12.8433
4
4.5
-1.43953
12.1871
-19.3211
5
6
-1.31652
13.9204
-27.2203
6
9.5
-1.21073
15.3862
-38.7222
7
9.5
-1.11699
16.6339
-49.3336
8
9.5
-1.03643
17.7081
-59.1797
9
9.5
-0.958125
18.6261
-68.2819
10
9.5
-0.885291
19.4098
-76.6921
11
9.5
-0.816874
20.0771
-84.4524
12
9.5
-0.752084
20.6427
-91.5972
13
9.5
-0.690309
21.1192
-98.1552
14
9.5
-0.631062
21.5175
-104.15
15
9.5
-0.573953
21.8469
-109.603
16
9.5
-0.521527
22.1189
-114.557
17
9.5
-0.467699
22.3376
-119
18
9.5
-0.415193
22.51
-122.945
19
9.5
-0.363809
22.6424
-126.401
20
9.5
-0.31337
22.7406
-129.378
21
9.5
-0.263715
22.8101
-131.883
22
9.5
-0.214702
22.8562
-133.923
23
9.5
-0.168741
22.8847
-135.526
24
9.5
-0.12061
22.8992
-136.672
25
9.5
-0.0727562
22.9045
-137.363
26
9.5
-0.0250691
22.9052
-137.601
27
9.5
0,0250691
22.9058
-137.363
28
9.5
0.0727562
22.9111
-136.672
29
9.5
0.12061
22.9256
-135.526
30
9.5
0.168741
22.9541
-133.923
31
9.5
0.214702
23.0002
-131.883
32
9.5
0.263715
23.0698
-129.378
33
9.5
0.31337
23.168
-126.401
34
9.5
0.363809
23.3003
-122.945
35
9.5
0.415193
23.4727
-119
36
9.5
0.467699
23.6914
-114.557
37
9.5
0.521527
23.9634
-109.603
38
9.5
0.573953
24.2929
-104.15
39
9.5
0.631062
24.6911
-98.1552
40
9.5
0.690309
25.1676
-91.5972
41
9.5
0.752084
25.7332
-84.4524
42
9.5
0.816874
26.4005
-76.6921
43
10.3
0.885291
27.1843
-67.5736
44
11
0.958125
28.1023
-57.0343
45
15
1.03643
29.1765
-41.4878
46
16
1.11699
30,4241
-23.616
47
20
1.21073
31.89
0.598598
Page 1

48
20
1.31652
33.6232
26.929
49
21
1.43953
35.6955
57.1591
50
30
1.58927
38.2212
104.837
51
32
1.78661
41.4132
162.009
52
130
2.09693
45.8103
434.61
Data Set Standard Deviation = 17.399
Numerator = 188886
Denominator = 707268
W Statistic = 0.267064 = 188886 / 707268
5% Critical value of 0.957 exceeds 0.267064
Evidence of non -normality at 95% level of significance
1% Critical value of 0.938 exceeds 0.267064
Evidence of non -normality at 99% level of significance
Page 2

Shapiro-Francia Test of Normality
Parameter: Cobalt
All Locations
Normality Test of Parameter Concentrations
Natural Logarithm Transformation
Non -Detects Replaced with Detection Limit
Total Number of Measurements = 52
i
x(i)
m(i)
sum(m^2)
sum(mx)
1
0.741937
-2.09693
4.39712
-1.55579
2
0.916291
-1.78661
7.5891
-3.19285
3
0.916291
-1.58927
10.1149
-4.64908
4
1.50408
-1.43953
12.1871
-6.81424
5
1.79176
-1.31652
13.9204
-9.17313
6
2.25129
-1.21073
15.3862
-11.8988
7
2.25129
-1.11699
16.6339
-14.4135
8
2.25129
-1.03643
17.7081
-16.7468
9
2.25129
-0.958125
18.6261
-18.9038
10
2.25129
-0.885291
19.4098
-20.8969
11
2.25129
-0.816874
20.0771
-22.7359
12
2.25129
-0.752084
20.6427
-24.4291
13
2.25129
-0.690309
21.1192
-25.9831
14
2.25129
-0.631062
21.5175
-27.4039
15
2.25129
-0.573953
21.8469
-28.696
16
2.25129
-0.521527
22.1189
-29.8701
17
2.25129
-0.467699
22.3376
-30.923
18
2.25129
-0.415193
22.51
-31.8577
19
2.25129
-0.363809
22.6424
-32.6768
20
2.25129
-0.31337
22.7406
-33.3823
21
2.25129
-0.263715
22.8101
-33.976
22
2.25129
-0.214702
22.8562
-34.4593
23
2.25129
-0.168741
22.8847
-34.8392
24
2.25129
-0.12061
22.8992
-35.1107
25
2.25129
-0.0727562
22.9045
-35.2745
26
2.25129
-0.0250691
22.9052
-35.331
27
2.25129
0.0250691
22.9058
-35.2745
28
2.25129
0.0727562
22.9111
-35.1107
29
2.25129
0.12061
22,9256
-34.8392
30
2.25129
0.168741
22.9541
-34.4593
31
2.25129
0.214702
23.0002
-33.976
32
2.25129
0.263715
23.0698
-33.3823
33
2.25129
0.31337
23.168
-32.6768
34
2.25129
0.363809
23.3003
-31.8577
35
2.25129
0.415193
23.4727
-30.923
36
2.25129
0.467699
23.6914
-29.8701
37
2.25129
0.521527
23.9634
-28.696
38
2.25129
0.573953
24.2929
-27.4039
39
2.25129
0.631062
24.6911
-25.9831
40
2.25129
0.690309
25.1676
-24.4291
41
2.25129
0.752084
25.7332
-22.7359
42
2.25129
0.816874
26.4005
-20.8969
43
2.33214
0.885291
27.1843
-18.8323
44
2.3979
0.958125
28.1023
-16.5348
45
2.70805
1.03643
29.1765
-13.7281
46
2.77259
1.11699
30.4241
-10.6311
47
2.99573
1.21073
31.89
-7.00409
Page 1

48
2.99573
1.31652
33.6232
-3.06015
49
3.04452
1.43953
35.6955
1.32253
50
3.4012
1.58927
38.2212
6.72795
51
3.46574
1.78661
41.4132
12.9199
52
4.86753
2.09693
45.8103
23.1268
Data Set Standard Deviation = 0.599302
Numerator = 534.847
Denominator = 839.122
W Statistic = 0.637388 = 534.847 / 839.122
5% Critical value of 0.957 exceeds 0.637388
Evidence of non -normality at 95% level of significance
1% Critical value of 0.938 exceeds 0.637388
Evidence of non -normality at 99% level of significance
Page 2

Rosner's Test for Outliers
Parameter: Cobalt
All Locations
Original Data (Not Transformed)
Non -Detects Replaced with Detection Limit
Data set mean = 12.9692
10 most extreme of 52 measurements
by order of magnitude difference from the mean
1
6/17/1997
MW-1 R
130
117.031
2
12/1/1997
MW-1 R
32
19.0308
3
5/28/1996
MW-1 R
30
17.0308
4
12/17/2008
MW-1 R
2.1
-10.8692
5
12/13/2010
MW-1 R
2.5
-10.4692
6
12/19/2007
MW-1 R
2.5
-10.4692
7
2/4/2019
MW-1 R
4.5
-8.46923
8
11/19/1998
MW-1 R
21
8.03077
9
11/15/1995
MW-1R
20
7.03077
10
2/9/1995
MW-1 R
20
7.03077
Iteration i = 9
Mean of 43 measurements = 9.99535
Std Dev = 2.11198
x(i+1) = 20 from measurement 2/9/1995 from location MW-1 R
Rosner Statistic R = 120 - 9.995351/2.11198 = 4.7371
Lambda(52, 10, 0.05) = 3.068
4.7371 > 3.068 -- Measurement 2/9/1995 for location MW-1 R is an outlier
Iteration i = 8
Mean of 44 measurements = 10.2227
Std Dev = 2.57518
x(i+1) = 20 from measurement 11/15/1995 from location MW-1 R
Rosner Statistic R = 120 - 10.22271/2.57518 = 3.79673
Lambda(52, 9, 0.05) = 3.0756
3.79673 > 3.0756 -- Measurement 11/15/1995 for location MW-1 R is an outlier
Iteration i = 7
Mean of 45 measurements = 10.4622
Std Dev = 3.01031
x(i+1) = 21 from measurement 11/19/1998 from location MW-1 R
Rosner Statistic R = 121 - 10.46221/3.01031 = 3.50057
Lambda(52, 8, 0.05) = 3.0832
3.50057 > 3.0832 -- Measurement 11/19/1998 for location MW-1 R is an outlier
Iteration i = 6
Mean of 46 measurements = 10.3326
Std Dev = 3.10377
x(i+1) = 4.5 from measurement 2/4/2019 from location MW-1 R
Rosner Statistic R = I4.5 - 10.33261/3.10377 = 1.8792
Lambda(52, 7, 0.05) = 3.0908
1.8792 < 3.0908 -- No outliers detected for i = 6
Page 1

Iteration i = 5
Mean of 47 measurements = 10.166
Std Dev = 3.27555
x(i+1) = 2.5 from measurement 12/19/2007 from location MW-1 R
Rosner Statistic R = 12.5 - 10.1661/3.27555 = 2.34035
Lambda(52, 6, 0.05) = 3.0984
2.34035 < 3.0984 -- No outliers detected for i = 5
Iteration i = 4
Mean of 48 measurements = 10.0063
Std Dev = 3.42422
x(i+1) = 2.5 from measurement 12/13/2010 from location MW-1 R
Rosner Statistic R = 12.5 - 10.00631/3.42422 = 2.19211
Lambda(52, 5, 0.05) = 3.106
2.19211 < 3.106 -- No outliers detected for i = 4
Iteration i = 3
Mean of 49 measurements = 9.8449
Std Dev = 3.57165
x(i+1) = 2.1 from measurement 12/17/2008 from location MW-1 R
Rosner Statistic R = 12.1 - 9.84491/3.57165 = 2.16844
Lambda(52, 4, 0.05) = 3.116
2.16844 < 3.116 -- No outliers detected for i = 3
Iteration i = 2
Mean of 50 measurements = 10.248
Std Dev = 4.54103
x(i+1) = 30 from measurement 5/28/1996 from location MW-1 R
Rosner Statistic R = 130 - 10.2481/4.54103 = 4.34968
Lambda(52, 3, 0.05) = 3.126
4.34968 > 3.126 -- Measurement 5/28/1996 for location MW-1 R is an outlier
Iteration i = 1
Mean of 51 measurements = 10.6745
Std Dev = 5.4301
x(i+1) = 32 from measurement 12/1/1997 from location MW-1 R
Rosner Statistic R = 132 - 10.67451/5.4301 = 3.92728
Lambda(52, 2, 0.05) = 3.134
3.92728 > 3.134 -- Measurement 12/1/1997 for location MW-1 R is an outlier
Iteration i = 0
Mean of 52 measurements = 12.9692
Std Dev = 17.399
x(i+1) = 130 from measurement 6/17/1997 from location MW-1 R
Rosner Statistic R = 1130 - 12.96921/17.399 = 6.72628
Lambda(52, 1, 0.05) = 3.144
6.72628 > 3.144 -- Measurement 6/17/1997 for location MW-1 R is an outlier
Page 2

Non -Parametric Tolerance Interval
Parameter: Cobalt
Original Data (Not Transformed)
Non -Detects Replaced with Detection Limit
Total Percent Non -Detects = 0%
Background measurements (n) = 52
Maximum Background Concentration = 130
Minimum Coverage = 94.7%
Average Coverage = 98.1132%
Location Date Value Significant
Page 1

Non -Parametric Prediction Interval
Inter -Well Comparison
Parameter: Cobalt
Original Data (Not Transformed)
Non -Detects Replaced with Detection Limit
Total Percent Non -Detects = 0%
Number of comparisons = 0
Future Samples (k) = 0
Recent Dates = 1
Background Measurements (n) = 52
Maximum Background Value = 130
Confidence Level = 0%
False Positive Rate = 100%
Location Date Count Mean Significant
Page 1

Appendix G
Historical Constituents in Surface Water

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
INORGANICS
Arsenic
06/24/10
2.7
10.00
4.30 J
2.90 J
ND
NC 2B = 10 pg/L(03/28/08)
12/13/10
2.7
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
3.0 J
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
3.10 B
ND
5.1 J
02/13/17
EPA 6010
5.0
10.0
ND
ND
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
ND
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
-
Barium
11/22/96
-
500
37.0
37.0
-
06/17/97
-
500
37.0
62.0
-
12/01/97
-
500
53.0
45.0
-
05/20/98
-
500
24.0
69.0
-
11/19/98
-
500
ND
100.0
-
07/21/99
-
500
ND
ND
-
11/16/99
-
500
ND
ND
-
05/10/00
-
500
ND
ND
-
10/26/00
-
500
ND
ND
-
04/18/01
-
500
ND
ND
-
10/27/01
-
500
ND
ND
-
06/13/02
-
500
-
-
-
11/19/02
-
500
ND
ND
-
06/27/03
-
500
ND
ND
-
12/30/03
-
500
ND
ND
ND
06/30/04
-
500
ND
ND
ND
12/29/04
-
500
ND
ND
ND
12/29/04
-
500
ND
ND
ND
06/29/05
-
500
ND
ND
ND
12/29/05
-
500
ND
ND
ND
06/28/06
-
500
ND
ND
ND
12/29/06
-
100
37.5
40.6
0.20 J
07/12/07
-
100
33.3 J
-
ND
12/19/07
-
100
52.6 B
149.0
11.7
NC 2B = 1,000 pg/L(03/28/08)
07/08/08
-
100
33.8 J
161.0
0.3 J
12/17/08
0.2
100
30.2 B
33.5 B
10.7 J
07/09/09
0.2
100
36.8 B
78.4 B
17.6 J
12/16/09
0.2
100
31.2 B
36.2 B
17.1 J
06/24/10
0.2
100
34.5 B
71.3 B
27.3 J
12/13/10
0.2
100
36.1 B
91.0 J
12.1 J
06/20/11
5.0
100
40.3 J
93.0 J
ND
12/05/11
5.0
100
32.9 J
59.0 J
ND
06/11/12
5.0
100
40.0 J
95.6 J
ND
12/12/12
5.0
100
45.0 J
97.8 J
ND
05/01/13
5.0
100
32.7 J
43.1 J
ND
08/05/13
5.0
100
49.9 J
79.8 J
ND
02/24/14
5.0
100
29.0 J
30.4 J
ND
08/12/14
EPA 6010
5.0
100
-
121
ND
03/10/15
EPA 6010
2.5
100
29.0 J
32.1 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
100
33.1 J
33.5 J
ND
08/09/16
EPA 6010
2.5
100
43.3 J
105
ND
02/13/17
EPA 6010
2.5
100
45.3 J
60.4 J
ND
08/22/17
EPA 6010
2.5
100
39.7 J
88.7 J
ND
02/05/18
EPA 6010
2.5
100
32.5 J
29.1 J
ND
08/13/18
EPA 6010D
2.5
100
70.0 J
86.6 J
ND
02/04/19
EPA 6010D
2.5
5
29.1
33.1
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 1 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Beryllium
07/08/08
-
1.0
0.32 J
ND
ND
12/17/08
0.1
1.0
ND
ND
ND
07/09/09
0.1
1.0
ND
ND
ND
12/16/09
0.1
1.0
0.12 J
ND
ND
NC 2B = 6.5 pg/L (02/05/10)
06/24/10
0.1
1.0
ND
ND
ND
12/13/10
0.1
1.0
ND
ND
ND
06/20/11
1.0
1.0
ND
ND
ND
12/05/11
1.0
1.0
ND
ND
ND
06/11/12
1.0
1.0
ND
ND
ND
12/12/12
1.0
1.0
ND
ND
ND
05/01/13
1.0
1.0
ND
ND
ND
08/05/13
1.0
1.0
ND
ND
ND
02/24/14
1.0
1.0
ND
ND
ND
08/12/14
EPA 6010
1.0
1.0
-
ND
ND
03/10/15
EPA 6010
0.50
1.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
0.50
1.0
ND
ND
ND
08/09/16
EPA 6010
0.50
1.0
ND
ND
ND
02/13/17
EPA 6010
0.50
1.0
ND
ND
ND
08/22/17
EPA 6010
0.50
1.0
ND
ND
ND
02/05/18
EPA 6010
0.50
1.0
ND
ND
ND
08/13/18
EPA 6010D
0.50
1.0
ND
ND
ND
02/04/19
EPA 6010D
0.50
1.0
ND
ND
-
Chromium
06/17/97
-
10.0
ND
3.00
-
12/01/97
-
10.0
ND
ND
-
05/20/98
-
10.0
ND
ND
-
11/19/98
-
10.0
ND
ND
-
07/21/99
-
10.0
ND
ND
-
11/16/99
-
10.0
ND
ND
-
05/10/00
-
10.0
ND
ND
-
10/26/00
-
10.0
ND
ND
-
04/18/01
-
10.0
ND
ND
-
10/27/01
-
10.0
ND
ND
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
ND
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
2.20 B
2.60 B
1.40 J
NC 2B = 50 pg/L(03/28/08)
07/08/08
-
10.0
2.50 J
2.20 J
ND
12/17/08
0.4
10.0
1.40 J
2.60 J
ND
07/09/09
0.4
10.0
2.6 J
1.2 J
ND
12/16/09
0.4
10.0
4.1 J
3.4 J
ND
06/24/10
0.4
10.0
3.3 B
7.3 J
0.71 J
12/13/10
0.4
10.0
1.4 J
1.5 J
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
7.2 J
ND
12/12/12
5.0
10.0
ND
8.2 J
ND
05/01/13
5.0
10.0
5.7 J
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
4.4 J
3.6 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
4.6 J
6.8 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
2.90 J
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
6.9 J
7.9 J
ND
08/13/18
EPA 6010D
2.5
10.0
5.9 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 2 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Cobalt
05/20/98
-
10
2.0
2.0
-
11/19/98
-
10
ND
3.0
-
07/21/99
-
10
ND
ND
-
11/16/99
-
10
ND
ND
-
05/10/00
-
10
ND
ND
-
10/26/00
-
10
ND
ND
-
04/18/01
-
10
ND
ND
-
10/27/01
-
10.0
ND
22.0
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
10.0
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
4.2 B
1.20 B
1.8 J
07/08/08
-
10.0
4.80 B
10.5 B
6.20 J
12/17/08
0.6
10.0
1.70 B
1.1 B
2.50 J
07/09/09
0.6
10.0
ND
ND
ND
12/16/09
0.6
10.0
ND
1.0 J
ND
NC 2B = NE pg/L (03/24/10)
06/24/10
0.6
10.0
ND
ND
ND
12/13/10
0.6
10.0
(4.4) B
{ND)
1.6 (1.0 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
Resample>
01/25/12
5.0
10.0
-
-
ND
06/11/12
5.0
10.0
ND
5.10 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
Copper
12/29/06
-
10.0
1.3 B
1.10 B
0.60 J
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
5.3 B
ND
9.8
NC 2B = 7 pWL (03/28/08)
07/08/08
-
10.0
1.7 J
4.20 J
ND
12/17/08
0.3
10.0
1.40 J
1.50 J
ND
07/09/09
0.3
10.0
ND
ND
ND
12/16/09
0.3
10.0
1.90 J
2.00 J
ND
06/24/10
0.3
10.0
ND
3.10 J
ND
12/13/10
0.3
10.0
0.31 B
ND
0.49 J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
5.50 J
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
2.90 J
3.40 J
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
3.8 J
3.8 J
ND
08/13/18
EPA 6010D
2.5
10.0
4.1 J
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 3 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Lead
05/20/98
-
10.0
ND
8.00
-
11/19/98
-
10.0
ND
ND
-
07/21/99
-
10.0
ND
10.0
-
11/16/99
-
10.0
ND
ND
-
05/10/00
-
10.0
ND
ND
-
10/26/00
-
10.0
ND
ND
-
04/18/01
-
10.0
ND
ND
-
10/27/01
-
10.0
ND
ND
-
06/13/02
-
10.0
-
-
-
11/19/02
-
10.0
ND
ND
-
06/27/03
-
10.0
ND
ND
-
12/30/03
-
10.0
ND
ND
ND
06/30/04
-
10.0
ND
ND
ND
12/29/04
-
10.0
ND
ND
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
10.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
ND
ND
ND
NC 2B = 25 Ug/L(03/28/08)
07/08/08
-
10.0
ND
ND
ND
12/17/08
4.0
10.0
ND
ND
ND
07/09/09
4.0
10.0
ND
ND
ND
12/16/09
4.0
10.0
ND
ND
ND
06/24/10
4.0
10.0
ND
ND
ND
12/13/10
4.0
10.0
ND
ND
ND
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
Nickel
12/29/04
-
50.0
ND
50.0 (ND)
ND
06/29/05
-
50.0
ND
ND
ND
12/29/05
-
50.0
ND
ND
ND
06/28/06
-
50.0
ND
ND
ND
12/29/06
-
50.0
ND
2.9 J
ND
07/12/07
-
50.0
3.8 J
-
ND
12/19/07
-
50.0
6.0
31.5
ND
NC 2B = 25 Ug/L(03/28/08)
07/08/08
-
50.0
3.2 J
29.8 J
ND
12/17/08
1.7
50.0
2.4 B
4.0 B
2.4 J
07/09/09
1.7
50.0
4.1 J
12.3 J
ND
12/16/09
1.7
50.0
3.8 B
4.4 B
3.0 J
06/24/10
1.7
50.0
ND
2.0 J
ND
12/13/10
1.7
50.0
ND
14.2 J
2.7 J
06/20/11
5.0
50.0
ND
7.8 J
ND
12/05/11
5.0
50.0
ND
5.3 J
ND
06/11/12
5.0
50.0
ND
11.0 J
ND
12/12/12
5.0
50.0
ND
13.8 J
ND
05/01/13
5.0
50.0
ND
ND
ND
08/05/13
5.0
50.0
ND
5.6 J
ND
02/24/14
5.0
50.0
ND
ND
ND
08/12/14
EPA 6010
5.0
50.0
-
20.3 J
ND
03/10/15
EPA 6010
2.5
50.0
3.0 J
3.8 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
50.0
2.9 J
4.7 J
ND
08/09/16
EPA 6010
2.5
50.0
3.3 J
15.2 J
ND
02/13/17
EPA 6010
2.5
50.0
ND
7.3 J
ND
08/22/17
EPA 6010
2.5
50.0
ND
16.3 J
ND
02/05/18
EPA 6010
2.5
50.0
5.3 J
4.4 J
ND
08/13/18
EPA 6010D
2.5
50.0
7.3 J
12.4 J
ND
02/04/19
EPA 6010D
2.5
5.0
ND
2.7 J
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 4 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Silver
07/12/07
-
10.0
2.20 J
-
ND
12/19/07
-
10.0
ND
0.34 J
ND
NC 2B = 0.06 ug/L(03/28/08)
07/08/08
-
10.0
0.35 B
1.00 J
0.12 J
12/17/08
0.1
10.0
ND
ND
ND
07/09/09
0.1
10.0
ND
0.10 J
ND
12/16/09
0.1
10.0
ND
0.16 J
ND
06/24/10
0.1
10.0
ND
0.26 J
ND
12/13/10
0.1
10.0
(ND)
(0.28) B
0.21 (0.19 J) J
06/20/11
5.0
10.0
ND
ND
ND
12/05/11
5.0
10.0
ND
ND
ND
06/11/12
5.0
10.0
ND
ND
ND
12/12/12
5.0
10.0
ND
ND
ND
05/01/13
5.0
10.0
ND
ND
ND
08/05/13
5.0
10.0
ND
ND
ND
02/24/14
5.0
10.0
ND
ND
ND
08/12/14
EPA 6010
5.0
10.0
-
ND
ND
03/10/15
EPA 6010
2.5
10.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
10.0
ND
ND
ND
08/09/16
EPA 6010
2.5
10.0
ND
ND
ND
02/13/17
EPA 6010
2.5
10.0
ND
ND
ND
08/22/17
EPA 6010
2.5
10.0
ND
ND
ND
02/05/18
EPA 6010
2.5
10.0
ND
ND
ND
08/13/18
EPA 6010D
2.5
10.0
ND
ND
ND
02/04/19
EPA 6010D
2.5
5.0
ND
ND
-
Thallium
12/29/04
-
10.0
ND
10.0 (ND)
ND
06/29/05
-
10.0
ND
ND
ND
12/29/05
-
10.0
ND
ND
ND
06/28/06
-
10.0
ND
ND
ND
12/29/06
-
6.00
ND
ND
ND
07/12/07
-
5.5
ND
-
ND
12/19/07
-
5.5
3.60 J
ND
ND
07/08/08
-
5.5
3.40 J
ND
ND
12/17/08
3.0
5.5
ND
ND
ND
07/09/09
3.0
5.5
ND
ND
ND
12/16/09
3.0
5.5
ND
ND
ND
NC 2B = NE (03/24/10)
06/24/10
3.0
5.5
ND
ND
ND
12/13/10
3.0
5.5
3.80 J
ND
ND
06/20/11
5.4
5.5
ND
ND
ND
12/05/11
5.4
5.5
ND
ND
ND
06/11/12
5.4
5.5
ND
ND
ND
12/12/12
5.4
5.5
ND
ND
ND
05/01/13
5.4
5.5
ND
ND
ND
08/05/13
5.4
5.5
ND
ND
ND
02/24/14
5.4
5.5
ND
ND
ND
08/12/14
EPA 6010
5.4
5.5
-
ND
ND
03/10/15
EPA 6010
5.0
5.5
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
5.0
5.5
ND
ND
ND
08/09/16
EPA 6010
5.0
5.5
ND
ND
ND
02/13/17
EPA 60208
0.020
5.5
ND
ND
ND
08/22/17
EPA 6020E
0.020
5.5
ND
ND
ND
02/05/18
EPA 6020E
0.028
0.10
ND
ND
ND
08/13/18
EPA 6020E
0.020
5.50
ND
ND
ND
02/04/19
EPA 6020E
0.060
0.10
ND
ND
-
Vanadium
12/29/06
-
25.0
1.60 J
2.00 J
ND
07/12/07
-
25.0
4.60 J
-
ND
12/19/07
-
25.0
3.30 J
1.40 B
0.62 J
NC 2B = NE ug/L (03/28/08)
07/08/08
-
25.0
5.20 J
2.30 J
0.20 J
12/17/08
0.2
25.0
1.80 B
2.70 B
0.76 J
07/09/09
0.2
25.0
5.00 B
3.40 B
1.30 J
12/16/09
0.2
25.0
3.60 J
3.50 J
0.53 J
06/24/10
0.2
25.0
5.80 J
2.60 J
ND
12/13/10
0.2
25.0
1.60 B
0.67 B
0.36 J
06/20/11
5.0
25.0
ND
ND
ND
12/05/11
5.0
25.0
ND
ND
ND
06/11/12
5.0
25.0
ND
11.50 J
ND
12/12/12
5.0
25.0
ND
ND
ND
05/01/13
5.0
25.0
ND
ND
ND
08/05/13
5.0
25.0
ND
ND
ND
02/24/14
5.0
25.0
ND
ND
ND
08/12/14
EPA 6010
5.0
25.0
-
ND
ND
03/10/15
EPA 6010
2.5
25.0
3.9 J
4.7 J
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
2.5
25.0
4.1 J
5.8 J
ND
08/09/16
EPA 6010
2.5
25.0
2.9 J
2.8 J
ND
02/13/17
EPA 6010
2.5
25.0
ND
ND
ND
08/22/17
EPA 6010
2.5
25.0
2.8 J
ND
ND
02/05/18
EPA 6010
2.5
25.0
6.6 J
5.9 J
ND
08/13/18
EPA 6010D
2.5
25.0
8.3 J
3.1 J
ND
02/04/19
EPA 6010D
2.5
5.0
2.9 J
2.7 J
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 5 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Zinc
11/22/96
-
50.0
11.0
ND
-
06/17/97
-
50.0
ND
ND
-
12/01/97
-
50.0
20.0
ND
-
05/20/98
-
50.0
20.0
28.0
-
11/19/98
-
50.0
ND
ND
-
07/21/99
-
50.0
ND
ND
-
11/16/99
-
50.0
ND
ND
-
05/10/00
-
50.0
ND
ND
-
10/26/00
-
50.0
ND
ND
-
04/18/01
-
50.0
ND
ND
-
10/27/01
-
50.0
ND
ND
-
06/13/02
-
50.0
-
-
-
11/19/02
-
50.0
ND
ND
-
06/27/03
-
50.0
ND
ND
-
12/30/03
-
50.0
ND
ND
ND
06/30/04
-
50.0
ND
ND
ND
12/29/04
-
50.0
ND
ND
ND
06/29/05
-
50.0
ND
ND
ND
12/29/05
-
50.0
ND
ND
ND
06/28/06
-
50.0
ND
ND
ND
12/29/06
-
50.0
ND
ND
ND
07/12/07
-
10.0
ND
-
ND
12/19/07
-
10.0
24.6 B
ND
102
NC 2B = 50 pg/L (03/28/08)
07/08/08
-
10.0
ND
ND
1.20 J
12/17/08
0.4
10.0
ND
0.89 B
0.49 J
07/09/09
0.4
10.0
ND
4.90 B
1.60 J
12/16/09
0.4
10.0
2.60 B
2.60 B
7.70 J
06/24/10
0.4
10.0
ND
14.9
ND
12/13/10
0.4
10.0
ND
9.80 B
6.70 J
06/20/11
10.0
10.0
ND
ND
ND
12/05/11
10.0
10.0
ND
ND
12.4
06/11/12
10.0
10.0
ND
ND
ND
12/12/12
10.0
10.0
ND
ND
ND
05/01/13
10.0
10.0
ND
16.80
ND
08/05/13
10.0
10.0
ND
ND
ND
02/24/14
10.0
10.0
ND
ND
ND
08/12/14
EPA 6010
10.0
10.0
-
ND
ND
03/10/15
EPA 6010
5.0
10.0
7.7 B
7.8 B
5.6 J
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 6010
5.0
10.0
7.0 J
ND
ND
08/09/16
EPA 6010
5.0
10.0
ND
ND
ND
02/13/17
EPA 6010
5.0
10.0
ND
5.2 J
ND
08/22/17
EPA 6010
5.0
10.0
ND
ND
ND
02/05/18
EPA 6010
5.0
10.0
ND
ND
ND
08/13/18
EPA 6010D
5.0
10.0
6.0 J
ND
ND
02/04/19
EPA 6010D
5.0
10.0
ND
ND
-
Hardness, Total(SM 2340B)
02/04/19
EPA 6010D
662
j 662
57.1
85.3
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 6 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
ORGANICS
Acetone
10/27/01
-
100
168.0 B
337.0 B
479.0
06/13/02
-
100
-
-
-
06/13/02
-
100
-
-
-
11/19/02
-
100
ND
ND
-
06/27/03
-
100
ND
ND
-
12/30/03
-
100
ND
ND
ND
06/30/04
-
100
ND
ND
ND
12/29/04
-
100
ND
ND
ND
06/29/05
-
100
ND
ND
ND
12/29/05
-
100
ND
ND
ND
06/28/06
-
100
ND
ND
ND
12/29/06
-
100
ND
ND
ND
07/12/07
-
100
ND
-
ND
12/19/07
-
100
12.70 B
ND
4.50 J
NC 2B = 2,000 pg/L(03/28/08)
07/08/08
-
100
ND
ND
ND
12/17/08
20
100
ND
ND
ND
07/09/09
20
100
ND
ND
ND
NC 2B = NE (03/24/10)
12/16/09
2.2
100
ND
ND
2.80 J
06/24/10
2.2
100
2.80 B
ND
7.70 J
12/13/10
2.2
100
ND
3.00 J
ND
06/20/11
2.2
100
ND
3.80 B
3.90 J
12/05/11
2.2
100
ND
7.20 B
8.80 J
06/11/12
2.2
100
ND
5.50 B
4.70 J
12/12/12
10.0
100
ND
ND
ND
05/01/13
10.0
100
ND
ND
14.6 J
08/05/13
10.0
100
ND
ND
ND
02/24/14
10.0
100
ND
ND
25.7 J
08/12/14
EPA 8260
10.0
100
-
ND
22.0 J
03/10/15
EPA 8260
10.0
100
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 8260
10.0
100
ND
ND
ND
08/09/16
EPA 8260
10.0
100
ND
ND
ND
02/13/17
EPA 8260
10.0
100
ND
ND
ND
08/22/17
EPA 8260
10.0
100
ND
ND
ND
02/05/18
EPA 8260
10.0
100
ND
ND
ND
08/13/18
EPA 8260E
10.0
100
ND
ND
ND
02/04/19
EPA 8260E
6.2
25
ND
ND
-
Chlorobenzene
06/27/03
-
5.0
ND
7.20
ND
12/30/03
-
5.0
ND
ND
ND
06/30/04
-
5.0
ND
ND
ND
12/29/04
-
5.0
ND
ND
ND
06/29/05
-
5.0
ND
ND
ND
12/29/05
-
5.0
ND
ND
ND
06/28/06
-
5.0
ND
ND
ND
12/29/06
-
3.0
ND
ND
ND
07/12/07
-
3.0
ND
-
ND
12/19/07
-
3.0
ND
ND
ND
NC 2B = 130 pg/L(03/28/08)
07/08/08
-
3.0
ND
ND
ND
12/17/08
0.23
3.0
ND
ND
ND
07/09/09
0.23
3.0
ND
ND
ND
12/16/09
0.23
3.0
ND
ND
ND
06/24/10
0.23
3.0
ND
ND
ND
12/13/10
0.23
3.0
ND
ND
0.28 J
06/20/11
0.23
3.0
ND
ND
ND
12/05/11
0.23
3.0
ND
ND
ND
06/11/12
0.23
3.0
ND
ND
ND
12/12/12
0.23
3.0
ND
ND
ND
05/01/13
0.23
3.0
ND
ND
ND
08/05/13
0.23
3.0
ND
ND
ND
02/24/14
0.23
3.0
ND
ND
ND
08/12/14
EPA 8260
0.23
3.0
-
ND
ND
03/10/15
EPA 8260
0.23
3.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 8260
0.23
3.0
ND
ND
ND
08/09/16
EPA 8260
0.23
3.0
ND
ND
ND
02/13/17
EPA 8260
0.23
3.0
ND
ND
ND
08/22/17
EPA 8260
0.23
3.0
ND
ND
ND
02/05/18
EPA 8260
0.23
3.0
ND
ND
ND
08/13/18
EPA 8260E
0.23
3.0
ND
ND
ND
02/04/19
EPA 8260E
0.23
1.0
ND
ND
-
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 7 of 8

APPENDIX G: Historical Constituents in Surface Water
Analytes
Sample Date
EPA Method
DL
RL
SW-1
SW-2
Blanks
Chloromethane
07/09/09
0.11
1.0
ND
0.19 J
ND
12/16/09
0.11
1.0
ND
ND
ND
NC 2B = NE (03/24/10)
06/24/10
0.11
1.0
ND
ND
ND
12/13/10
0.11
1.0
ND
ND
ND
06/20/11
0.11
1.0
ND
ND
ND
12/05/11
0.11
1.0
ND
ND
ND
06/11/12
0.11
1.0
ND
ND
ND
12/12/12
0.11
1.0
ND
ND
ND
05/01/13
0.11
1.0
ND
ND
ND
08/05/13
0.11
1.0
ND
ND
ND
02/24/14
0.11
1.0
ND
ND
0.25 J
08/12/14
EPA 8260
0.11
1.0
-
ND
ND
03/10/15
EPA 8260
0.11
1.0
ND
ND
ND
08/18/15
-
-
Dry
Dry
-
02/16/16
EPA 8260
0.11
1.0
ND
ND
ND
08/09/16
EPA 8260
0.11
1.0
ND
ND
ND
02/13/17
EPA 8260
0.11
1.0
0.17 J
0.19 J
0.18 J
08/22/17
EPA 8260
0.11
1.0
ND
ND
ND
02/05/18
EPA 8260
0.11
1.0
ND
ND
ND
08/13/18
EPA 8260E
0.11
1.0
ND
ND
ND
02/04/19
EPA 8260E
0.39
1.0
ND
ND
-
1,4-Dioxane (p-Dioxane)
08/13/18
EPA 8260B Mod.
1.9
2.0
ND
14.1
ND
02/04/19
EPA 8260B Mod.
1.9
2.0
ND
ND
-
Methylene Chloride
08/09/16
EPA 8260
0.97
1.0
ND
ND
2.20 J
02/13/17
EPA 8260
0.97
1.0
ND
ND
ND
NC 2L = 5 pg/L (2/5/10)
08/22/17
EPA 8260
0.97
1.0
ND
ND
1.4 C9
02/05/18
EPA 8260
0.97
1.0
ND
ND
ND
08/13/18
EPA 8260E
0.97
1.0
ND
ND
6.60
02/04/19
EPA 82606
3.7
5.0
ND
ND
-
Notes:
All concentrations are in micrograms per liter (pg/L).
RL = Reporting Limit (SWSL for December 2006 - present).
DL = Laboratory detection limit.
J = Estimated value between the DL and the RL.
B = Blank -qualified data; result is expected to be biased high based on concentrations in the blanks.
ND = Not detected above laboratory reporting limit.
NS = Not sampled.
NR = Not Reported.
Dry =Surface water point considered to be dry.
NC 2B = North Carolina Surface Water Standards from 15A NCAC 2B.0101
NE = Not established.
Granville County La Bella Associates
Butner Landfill, Permit No. 39-02 Page 8 of 8