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MO-4269_13403_CA_MRP_20190228_Monitoring Report
MONITORING REPORT CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, CABARRUS COUNTY, NORTH CAROLINA, 28025 FACILITY ID #0-002137 GROUNDWATER INCIDENT NO. 13403 SHIELD PROJECT NO. 1120116 UST Consultant: Property Owner: Property Analytical Laboratory: Owner/Operator: Occupant: Carolina Oil Shield Engineering, Inc. Carolina Oil BP Fueling Pace Analytical Services, LLC Company 4301 Taggart Creek Road Company Station 9800 Kincey Ave. Suite 100 P.O. Box 5010 Charlotte, North Carolina 28208 P.O. Box 5010 Huntersville, NC 28078 Concord, NC Concord, NC State Certification # 5342 28207 28207 Contact: Contact: Contact: Contact: Contact: Mr. Robbie Matthew T. Smith Mr. Robbie Unknown Nicole Gasiorowski Barbour (704) 394-6913 Barbour (704) 875-9092 (704) 782-3196 msmith@shieldengineering.com (704) 782-3196 Nicole.gasiorowski@pacelabs. barbour@CTE.net barbour@CTE.net com Site Risk Classification: High Risk Site Latitude: 35.370603 N Land Use Category: Commercial Site Longitude: 80.665629 W Description of Geographical Data Point: Location Method: Google EarthTM Middle of Site Canopy Release Discovered: November 1997 Quantity Released: Unknown Potential Release Source(s): Former UST System Release Cause: Unknown ate s,.t1i'ii;. Matthew T. Smith David A. Ston �v. P. E.4�`,x Project Manager Senior Principa fl • Registered, NC # y�' •t .►ti'' February 28, 2019 `WIELD Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GW I#: 13403 Executive Summary Monitoring Report February 28, 2019 Page i The Carolina Fast Mart #4 Pit Stop site is considered a High Risk site assigned groundwater incident #20117 and is located in Cabarrus County, North Carolina. The site currently operates as a BP petroleum filling station and convenience store. The site does not have an active remedial system and is monitored via groundwater sampling events that are conducted semi-annually in June and December. Mobile Multi -Phase Extraction (MMPE) events have been conducted historically prior to sampling events. However, the most recent MMPE event was conducted within 30 days following the routine sampling event. A mid-MMPE sampling event was also conducted. The following information pertains to the findings of the January 2019 sampling event(s): ■ Free product was not present at the site during this monitoring period and has never been present in any of the site wells. • Dissolved phase petroleum constituent compounds were detected in concentrations above the 15A NCAC 2L Groundwater Standards (2L Standards) in monitoring wells MW-1OB, MW-16, and MW-17. • The contaminant plume appears to be relatively stable. Constituent concentrations have overall decreased since the initial September 2013 sampling event. ■ During the previous sampling event (June 2018), the benzene plume size was approximately 125 feet in length and 45 feet in width. The current benzene plume size prior to the most recent MMPE event was approximately 110 feet in length and 45 feet in width. The methyl tertiary butyl ether (MTBE) plume size, above the 2L Standards in June 2018 was approximately 40 feet in length and 20 feet in width. The MTBE plume size prior to the most recent MMPE event was approximately 25 feet in length and 18 feet in width. The naphthalene plume prior to the most recent MMPE event was similar in size when compared to the previous sampling event, approximately 45 feet in length and 30 feet in width. The diisopropyl ether (IPE) plume size, above 2L Standards prior to the most recent MMPE event was is limited to one small area immediately around monitoring well MW-16. • The contaminant levels previously above the 2L Standards in MW-lOB (benzene, MTBE, IPE, naphthalene, and 1,2,4-trimethylbenzene) decreased since the June 2018 routine sampling event. The contaminant level of IPE and 1,2,4-trimethylbenzene were below the 2L Standards during the January 2019 sampling event. ■ The contaminant level above the 2L Standards in MW-13 (benzene) decreased to a non -detect concentration since the June 2018 sampling event. • The contaminant levels above the 2L Standards in MW-16 (benzene, MTBE, and naphthalene) decreased since the June 2018 routine sampling event. IPE increased to a concentration above the 2L Standards in response to the July 2018 MMPE event but dropped below the 2L Standards during the January 2019 MMPE event. • The January 3, 2019 maximum concentration of benzene at this site was 560 micrograms per liter (ug/L) [MW-16] and the cleanup goal is 1 ug/L. The January 3, 2019 maximum concentration of MTBE is 45.7 ug/L [MW-16] and the cleanup goal is 20 ug/L. The January 3, 2019 maximum concentration of IPE is 104 ug/L [MW-16] and the cleanup goal is 70 ug/L. The January 3, 2019 maximum concentration of naphthalene is 59.5 ug/L [MW-IOB] and the cleanup goal is 6 ug/L. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report February 28, 2019 Page ii • The historic maximum benzene concentration in groundwater (MW-1 OB) was 17,800 ug/L. The historic maximum total xylenes concentration in groundwater (MW-10B) was 3,300 ug/L. The historic maximum MTBE concentration in groundwater (MW-1 OB) was 3,720 ug/L. The historic maximum IPE concentration in groundwater (MW-10B) was 1,200 ug/L. The historic maximum naphthalene concentration in groundwater (MW-10B) was 632 ug/L. • Due to a leak in the water supply well piping and power being temporarily turned off, WSW-1 was not sampled during the January 2019 sampling event. The owner told Shield personnel that he plans to have the leaking pipe repaired before the next routine sampling event. • Previous active remediation at the site consisted of soil excavation at the time of the UST removal. Soil delineation sampling was conducted in association with Comprehensive Site Assessment (CSA) addendum activities in September 2013. Based on information presented in the CSA Addendum, soil contamination in the form of benzene only was found near one former sidewall of the large UST excavation above the Soil -to -Groundwater (STG) maximum soil contaminant concentration levels (MSCCs) but not above the Residential MSCCs. No soil contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related constituents of concern (COCs) but none of these samples exceeded the Residential MSCCs. A 96-hour MMPE event was conducted using monitoring wells MW-10B and MW-16 from January 28 through February 1, 2019, in an effort to reduce the dissolved -phase petroleum constituent concentrations at the site. MMPE events have previously been conducted in March 2014, April 2015, January 2016, October 2016, June 2017, November 2017, and July 2018. ■ Two groundwater samples were collected from MW-1 OB and MW-16 on January 30, 2019 during the MMPE event. These grab samples were collected following the removal of and during the change out of one tanker volume. Dissolved phase petroleum constituent concentrations in MW- 10B were drastically higher than concentrations during the January 3, 2019 sampling event. Benzene, total xylenes, MTBE, IPE, and naphthalene exceeded the 2L Standards in MW-1 OB at that time. The benzene, IPE, and MTBE concentrations in MW-16 were lower during the January MMPE event than the concentrations during the January routine sampling event, with the IPE concentration below the 2L Standards. The naphthalene concentration was slightly higher in MW-16 during the MMPE event than the concentration during the January routine sampling event. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 TABLE OF CONTENTS Monitoring Report February 28, 2019 Page iii Page No. 1.0 SITE HISTORY AND CHARACTERIZATION ............................ ................................. I 2.0 PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT INFORMATION............................................................................................................... 4 3.0 FREE PRODUCT REMOVAL........................................................................................8 4.0 MONITORED NATURAL ATTENUATION.................................................................8 5.0 CONCLUSIONS AND RECOMMENDATIONS.........................................................10 6.0 STATEMENTS & CERTIFICATION............................................................................12 7.0 LIMITATIONS...............................................................................................................13 LIST OF FIGURES Figure 1: Site Location Map Figure 2: Site Map Figure 3: 1,500 Foot Radius Map Figure 4: Groundwater Elevation Contour Map (01/03/2019) Figure 5: Benzene Isoconcentration Map Figure 6: MTBE Isoconcentration Map Figure 7: Diisopropyl Ether (IPE) Isoconcentration Map Figure 8: Naphthalene Isoconcentration Map LIST OF TABLES Table 1: Water Supply Well and Receptor Information Table 2: Summary of Well Construction and Groundwater Elevation Data Table 3: Summary of Analytical Results — Groundwater Samples Table 4: Summary of Historical Analytical Results — Groundwater Samples APPENDICES Appendix A: Geologic Logs for Borings - Not Applicable or Not Available (NA) Appendix B: Copies of any NORR, NOV, etc. related to submittal of Site Closure Report (NA) Appendix C: Natural Attenuation Parameters (NA) Appendix D: Remedial System Performance Tables and Graphs (NA) Appendix E: Contaminant Mass vs Time Graph and Constituent Concentration vs Time/Hydrograph(s) Appendix F: Compilation of Costs for Performance of Remedial Plan (NA) Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report February 28, 2019 Page iv Appendix G: Chronology of Remediation Activities (NA) Appendix H: Proposed Remediation Schedule and Cleanup Progress Milestones (NA) Appendix I: Laboratory Analytical Results Appendix J: Groundwater Calculations Appendix K: Mobile Multi -Phase Extraction Report Appendix L: Applicable Historical Figure(s) and Table(s) H: IProjects1201211120116-01 Carolina Fast Mart Pit StoplReportslMR January 20191Monitoring Report 2019-02.doc Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 1.0 SITE HISTORY AND CHARACTERIZATION 1.1 Historical Information on Release Monitoring Report February 28, 2019 Page 1 According to the August 2002 Pre -CAP Monitoring Report prepared by Engineering Tectonics, P.A. (ETPA), three 10,000 gallon gasoline underground storage tanks (USTs), and one 8,000 gallon diesel UST were removed in November 1997. Upon the removal of the USTs, soil contamination was detected and associated with the UST system. The exact source of the release is unknown and can be one or a combination of the USTs, the piping, and/or the dispensers. Carolina Oil Company was the owner and/or operator of the USTs. The site was historically classified as an Intermediate Risk site by the North Carolina Department of Environmental Quality (NCDEQ). Ongoing semi-annual monitoring and reporting was being conducted by others during this time. A Notice of Regulatory Requirements (NORR) dated May 3, 2012 indicated that the Pit Stop BP site, of Intermediate Risk, was determined by the NCDEQ to be of sufficiently high priority to allow funding by the State Trust Fund Program. Pursuant to the NORR and a Notice of Violation (NOV) dated July 26, 2012, a Natural Attenuation Monitoring Report (NAMR) was submitted by Shield Engineering, Inc. (Shield) to the NCDEQ on December 20, 2012. The December 2012 NAMR found that dissolved phase petroleum constituent concentrations exceeded the NCDEQ Gross Contaminant Levels (GCLs) in monitoring well MW-1 OB. Additional soil sampling was performed in September 2013 in order to further delineate soil contamination and was presented in a Comprehensive Site Assessment (CSA) Addendum. It was noted that no soil contamination was found to be above the Residential Maximum Soil Contaminant Concentration levels (MSCCs). Based on groundwater results from the April 2014 sampling event, methyl tertiary butyl ether (MTBE) and diisopropyl ether (IPE) was detected in water supply well WSW-1. MTBE was detected at 29.9 micrograms per liter (ug/L) which was above the 15A NCAC 2L Groundwater Standards (2L Standards) of 20 ug/L. Since MTBE was detected above the 2L Standards and according to a NORR dated May 16, 2014, the Pit Stop BP site was reclassified as High Risk. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-1. No Corrective Action Plan was ever conducted nor implemented for this site. Semi-annual Mobile Multi -Phase Extraction (MMPE) events along with routine sampling and reporting are ongoing. No non-USTs are believed to have added to the site contamination. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina G W I#: 13403 1.2 Site Characteristics Monitoring Report February 28, 2019 Page 2 The site is located at 3690 Concord Parkway South in Concord, North Carolina (See Figures 1 & 2). The property currently operates as a BP petroleum filling station and convenience store. The surrounding properties are residential, commercial, or agricultural in use. Groundcover at the site is comprised of asphalt/concrete paved surfaces and landscaped areas of grass. A one-story convenience store building along with a canopy is also located on the site. Geology and hydrogeology information can be seen in Section 2.5 1.3 Existing Area Receptors: Refer to the following figure for information and locations of property owners/occupants and area receptors. Refer to Table: Table 1 Refer to Figure(s): Figure 3 Pursuant to NCDEQ requirements in 2012, a Site Reconnaissance and Receptor Survey (receptor survey) was conducted by Shield by walking and/or driving publicly accessible roads within a 1,500-foot radius of the site. During the survey, Shield personnel observed supply wells and/or water meters from the streets and interviewed available occupants. Figure 3 depicts the subject site and all properties within 1,500 feet of the site. Refer to Table 1 for specific information. Locations of addresses are approximate, based on perceived locations, using a topographic map, a tax map, and observations in the field. There may be other supply wells or water meters that were not readily visible at the time of our survey. Seven water supply wells were observed within 1,500 feet of source area. According to the property owner of WSW -I, located approximately 430 feet from the source area, the water supply well is used for washing vehicles and they are connected to municipal water for other water uses. The property owner of WSW-2 approximately 530 feet from the source stated that they did not use the water supply well. No one was home at WSW-3, WSW-4, and WSW-5 at the time of the supply well survey. WSW-3 is approximately 740 feet from the site. WSW-4 is approximately 840 feet from the site. WSW-5 is approximately 940 feet from the site. The property owner at WSW-6 located approximately 890 feet from the site stated that they did not use the well. WSW-7 is approximately 1,290 feet from the site and is located on undeveloped land. Water supply well survey letters were left at residences of WSW-4, WSW-5, and mailed to the residences at WSW-3 and WSW-7. The survey letters from the residents of WSW-4 and WSW-5 stated that they did not use the wells. The survey letter from the residents of WSW-3 stated they use the well for washing vehicles. No information was returned by the residents of WSW-7. All other parcels shown on Figure 3 are either connected to municipal water or are undeveloped. The NCDEQ's request for Water Supply Well Information Survey letter was hand delivered to all other property owners within 1,000 feet of the site. Regarding the interviews and survey letter responses, we can only report what the interviewed parties told us and what was Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report February 28, 2019 Page 3 reported on the returned survey letters; we are not validating whether the information is correct. Figure 3 and Table 1 should not be used separately from this portion of the report. If any additional information is obtained regarding the water usage within 1,500 feet of the site, Shield reserves the right to amend this portion of the report. There is an unnamed intermittent drainage feature approximately 50 feet west of the site that ultimately flows into Rocky River and another unnamed intermittent drainage feature approximately 900 feet west of the site that flows into Coddle Creek. Because of the receptor information and previous groundwater contaminant level(s) being detected in supply well WSW-1, the site has been ranked by the NCDEQ as a "High Risk" site. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-1. • Proximity of Plume to Nearest Receptor(s): There is an unnamed intermittent drainage feature approximately 50 feet west of the site that ultimately flows into Rocky River. The closest active water supply well (WSW-1) is located approximately 430 feet west southwest from the source area of release. WSW-1 is used for washing cars; the residents have municipal water for other water uses. Interviews with the owner(s) of the well were not successful in getting them to abandon their well and connect their car washing station to municipal water. We previously advised the property owners of concerns relative to drinking water from this well. 1.4 Implementation of Remedial Plan: Corrective Action Plan activities have not been conducted at this site. Based on information presented in the CSA Addendum, soil contamination in the form of benzene only was found near one former sidewall of the large UST excavation above the Soil -to -Groundwater (STG) MSCCS but not above the Residential MSCCS. No soil contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCS for gasoline related constituents of concern (COCs) but none of these samples exceeded the Residential MSCCS. MMPE events are currently being conducted semi-annually utilizing monitoring wells MW- I OB and MW-16 in July and January. MMPE events have been conducted in March 2014, April 2015, January 2016, October 2016, June 2017, November 2017, July 2018, and January 2019. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GW I#: 13403 Monitoring Report February 28, 2019 Page 4 2.0 PRESENTATION OF CURRENT AND HISTORICAL ASSESSMENT INFORMATION 2.1 Groundwater Elevation and Flow Directions • No free product is present at the site. • Current groundwater flow is predominantly toward the northwest. The current groundwater elevation data are included in the following table(s) and figure(s): Refer to Table(s): Table 1 Refer to Figure(s): Figure 4 2.2 Free Product Free Product Detected during this Reporting Period?: No 2.3 Discussion of MMPE Event: A 96-hour MMPE event was conducted using monitoring wells MW-1 OB and MW-16 from January 28 through February 1, 2019 in an effort to reduce the dissolved -phase petroleum constituent concentrations at the site. A total of 8,190 gallons of petroleum -impacted groundwater were recovered during the MMPE event. Based on the 96 hours of operation and a total of 8,190 gallons of contaminated groundwater recovered, the average groundwater recovery rate was calculated to be approximately 85.31 gallons per hour. Based on mass - removal calculations 14.11 pounds (2.29 gallons) of volatile organic compounds (VOCs) were removed as vapor. No measurable free product was recovered as a liquid. Refer to Appendix K for the MMPE event report. Two groundwater samples were collected from MW-10B and MW-16 on January 30, 2019 during the MMPE event. These grab samples were collected following the removal of one tanker volume and during the tanker volume change out. Dissolved phase petroleum constituent concentrations in MW-1 OB were drastically higher than concentrations during the January 3, 2019 sampling event. Benzene, total xylenes, MTBE, IPE, and naphthalene exceeded the 2L Standards in MW-10B at that time. The benzene, IPE, and MTBE concentrations in MW-16 were lower than the concentrations during the January 3, 2019 sampling event, with the IPE concentration below the 2L Standards. The naphthalene concentration was slightly higher in MW-16 during the MMPE event than the concentration during the January 3, 2019 sampling event. Refer to Appendix: Appendix K Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 2.4 Discussion of Groundwater Monitoring Event Monitoring well construction information can be seen in Table 2. 2.4.1 Site Monitoring Requirements: Site Location Map: See Figure 1 Site Map: See Figure 2 Monitoring Report February 28, 2019 Page 5 Site Monitoring Requirements Based on CAP and/or NORR(I) Sample Point Total Quantity of Existing Sample Required by NCDEQ to be Type Points and Their Identification Monitored and Sampled per NORR and/or TA 13403-13 Monitoring 9 9 Wells (MW-2, MW-6, MW-l0B, MW-13, (MW-2, MW-6, MW-l0B, MW-13, throu h MW-17, and TW-2) through MW-17, and TW-2 Water Supply 1 1 Wells (WSW-1) (WSW-1) NOTES: (1) Site monitoring requirements are in accordance with the November 18, 2014 Notice of Regulatory Requirements. 2.4.2 Groundwater Analytical Methods: Sampled Points and Analytical Methods: The following monitoring and supply wells were sampled on January 3, 2019. Sampled Points and Analytical Methods for this Reporting Period Based on CAP and Pre -Approval Task Authorization Sampling Requirements Type Points Sampled during this Analytical Method(s) Reporting Period Monitoring Wells (9) Wells EPA Method 6200B (MW-2, MW-6, MW-IOB, MW-13, through MW-17, and TW-2) Surface Water No surface water sampling has ever No analysis for this reporting period. been required for this site. Water Supply (0) Water Supply Well • EPA Method 6200B Wells (WSW-1) 1.) Due to a leak in the water supply well piping, the power has been temporarily turned off. Therefore, WSW-1 was not sampled during this routine sampling event. 0 Laboratory Used: Pace Analytical Services, LLC Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 • Date(s) of Sampling Event(s): January 3, 2019 2.5 Summarization of Current and Historical Assessment Information ■ Current Groundwater Analytical Data: Monitoring Report February 28, 2019 Page 6 Refer to the following table(s) and Appendix for current groundwater analytical data. Refer to Table(s): Table 2 Refer to Appendix: Appendix E & Appendix I Historical Groundwater Analytical Data: Refer to the following table and appendix for historical groundwater analytical data. Refer to Table: Table 3 Refer to Appendix: Appendix E ■ Surface water and soil are not required to be sampled. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina G W I#: 13403 2.6 Site and Region Geology and Hydrogeologry Monitoring Report February 28, 2019 Page 7 The project site is located in the Charlotte Belt Litho -Tectonic Province of the Piedmont Physiographic Province. The Piedmont Province is approximately 20,000 square miles located in the State of North Carolina and lies between the Coastal Plain to the east and the Blue Ridge Province to the west. The topography is characterized as a plateau with ridges and valleys formed as a result of stream erosion. Elevations within the Piedmont Province vary from approximately 400 feet above sea level in the east to approximately 1,800 feet above sea level near the foot of the Blue Ridge Province to the west. The soil overburden in the Piedmont Plateau consists of predominately fine grained sediments transitioning into saprolites. The residual saprolites are predominately underlain by northeast/southwest trending metamorphic and igneous rocks. Based on soil classifications (Unified Soil Classification system), the soil lithology at the site generally consists of silty sands, sands, clays, sandy clays, clayey silts, and sandy silts. According to the Geologic Map of North Carolina (1985), the site soils should be underlain by Gabbro of the Concord Plutonic Suite. Hydrogeological investigations were to be performed during the CSA by others. Shield does not have information pertaining to the CSA. CSA addendum activities were performed by Shield in September and October 2013, however, no hydrogeological investigation was performed as a part of those activities. 2.7 Evaluation of Site Assessment Information • Groundwater — The following Groundwater Summary and referenced figures are based on the January 3, 2019 routine sampling event prior to the most recent MMPE event: • Dissolved phase petroleum constituent compounds were detected in concentrations above the 2L Standards in monitoring wells MW-IOB, MW-16, and MW-17. • The benzene plume greater than the 2L Standards is approximately 110 feet in length and approximately 45 feet in width. The areal extent of the benzene plume is approximately 4,950 square feet. • The MTBE plume greater than the 2L Standards is approximately 25 feet in length and 18 feet in width. The areal extent of the MTBE plume is approximately 450 square feet. Refer to Figures: Figures 5 through 8 Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 • Predictive Rate of Contaminant Transport: 0 Soil Monitoring Report February 28, 2019 Page 8 MTBE was detected at a concentration of 1 micrograms per liter (ug/1) in supply well WSW-1 during the previous sampling event on June 26, 2018. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-l. Refer to the following Tables and Figures: Refer to Tables: Tables 3 and 4 Refer to Figures: Figures 5 through 8 • Based on information presented in the CSA Addendum dated December 3, 2013, soil contamination in the form of benzene only was found near one former sidewall of the large UST excavation above the STG MSCCs but not above the Residential MSCCs. No soil contamination was found near the former diesel UST area above the STG or Residential MSCCS. All four samples collected from around the smaller UST excavation area exceeded the STG MSCCs for gasoline related COCs but none of these samples exceeded the Residential MSCCs. • Soil monitoring was not required by the NCDEQ during this reporting period. Refer to Appendix: Appendix L 3.0 FREE PRODUCT REMOVAL ■ Free product has not been historically encountered nor remediated at this site. Free product was also not encountered during this reporting period. 4.0 MONITORED NATURAL ATTENUATION • Refer to Section 2.3.1 Site Monitoring Requirements and Section 2.3.2 Groundwater Analytical Methods for information pertaining to the established monitoring plan. For Historical Groundwater Analytical Data, refer to Section 2.4 and Table 4. ■ The current contaminant mass, as calculated from the January 3, 2019 routine sampling event prior to the most recent MMPE event and areal plume area (combination of benzene and MTBE plumes) is approximately 537 grams and 4,950 square feet, respectively. • Dissolved phase petroleum constituent compounds were detected in concentrations above 2L Standards in MW-1OB, MW-16, and MW-17. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report February 28, 2019 Page 9 • Due to a leak in the water supply well piping, WSW-1 was not sampled during the January 2019 sampling event since power to the well has been temporarily turned off. The owner told Shield personnel that he plans to have the leaking pipe repaired before the next routine sampling event. • No CAP was ever completed, so no progress milestones or schedule were ever established. • During the January 3, 2019 sampling event prior to the most recent MMPE event, the total VOC concentrations for the monitoring wells with select contaminant levels above the 2L Standards decreased in MW-1 OB, MW-13, MW-16 and slightly increased in MW- 17 since the previous routine sampling event. However, total VOC concentrations for MW-10B increased dramatically as a response to the January 28 to February 1, 2019 MMPE event. ■ Previous active remediation at the site consisted of soil excavation at the time of UST removal and 96-hour MMPE events (March 2014, April 2015, January 2016, October 2016, June 2017, November 2017, and July 2018). A 96-hour MMPE event was conducted using monitoring wells MW-10B and MW-16 from January 28 through February 1, 2019, in an effort to reduce the dissolved -phase petroleum constituent concentrations at the site. Refer to Table(s): Tables 3 and 4 Refer to Figure(s): Figures 5 through 8 Refer to Appendix: Appendix E Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 5.0 CONCLUSIONS AND RECOMMENDATIONS 5.1 Interpretations of Submitted Data: Monitoring Report February 28, 2019 Page 10 • The site is a High Risk site because of supply well WSW-1 being located within 500 feet of the site. WSW-1 has also been historically impacted with MTBE. There are other petroleum fueling stations at this traffic intersection so we are uncertain of the true source of the MTBE in WSW-1. • Dissolved phase petroleum constituent compounds were detected in concentrations above 2L Standards in MW-IOB, MW-16, and MW-17. • The contaminant plume appears to be relatively stable. Constituent concentrations have overall decreased since the initial September 2013 sampling event. • The current contaminant mass, as calculated from the January 3, 2019 routine sampling event and areal plume area (combination of benzene and MTBE plumes prior to the January 2019 MMPE event) is approximately 537 grams and 4,950 square feet, respectively. • The total VOC concentrations prior to the most recent MMPE event for the monitoring wells with select contaminant levels above the 2L Standards decreased in MW-IOB, MW-13, MW-16 and slightly increased in MW-17 since the previous routine sampling event. • Two groundwater samples were collected from MW-1OB and MW-16 on January 30, 2019 during the MMPE event. These grab samples were collected following the removal of one tanker volume and during the tanker volume change out. Dissolved phase petroleum constituent concentrations in MW-10B were drastically higher than concentrations during the January 3, 2019 sampling event. Benzene, total xylenes, MTBE, IPE, and naphthalene exceeded the 2L Standards in MW-1 OB at that time. The benzene, IPE, and MTBE concentrations in MW-16 were lower during the MMPE event than the concentrations during the January 3, 2019 sampling event, with the IPE concentration below the 2L Standards. The naphthalene concentration was slightly higher in MW-16 during the MMPE event than the concentration during the January 3, 2019 sampling event. ■ Due to a leak in the water supply well piping, WSW-1 was not sampled during the January 2019 sampling event since power to the well has been temporarily turned off. The owner told Shield personnel that he plans to have the leaking pipe repaired before the next routine sampling event. 5.2 Recommendations • Shield recommends continuing the semi-annual MMPE events in June and December utilizing the monitoring wells MW-1 OB and MW-16. • Per the NCDEQ Memo dated December 21, 2017 regarding MMPE events, Shield recommends continued semi-annual sampling of the monitoring and supply wells in June and December prior to the recommended MMPE in July and January until contaminant levels are below 2L Standards. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 Monitoring Report February 28, 2019 Page 11 • We now know that contaminant concentrations increase during the MMPE events, demonstrating that the MMPE events are pulling contamination to the extraction wells, so there is no need to sample mid-MMPE in the future. Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GW I#: 13403 STATEMENTS & CERTIFICATION Monitoring Report February 28, 2019 Page 12 1 Enter the date the monitoring report was due. 02/28/19. Will this report be submitted YES NO after the established due date? 2 Was any required information from the standardized template missing from this report? E NO IF the answer to question #1 or# 2 is "YES", please provide additional information in this cell to explain what was missing and why. 1) The sections and discussions pertaining to the historical contaminant mass and projected milestones have been omitted since these were never calculated to our knowledge. CAP activities were never conducted at this site. 3 If applicable, will any of the proposed attenuation milestones under the schedule YES � approved in the Corrective Action Plan not be met? (within a reasonable margin of error) IF the answer to question #3 is "NO", skip to the certification under #6 below. IF the answer to question #3 is "YES", please generally describe in this cell the possible reason(s) and outline proposed remedies. (This should be described in more detail in the report text above.) *The CSA report (if ever completed) is currently not available to Shield. No milestones were previously established to our knowledge. CAP activities were never conducted at this site. 4 Does any known or suspected source zone soil contamination or free product remain YES NO outside of the assessed area that could be inhibiting natural attenuation? 5 Has there been an unexpected increase in contaminant mass sufficient to suggest a YES NO potential new release from a separate onsite or offsite source? IF the answer to either question #4 or #5 is "YES", generally describe in this cell any actions recommended to further assess or clean up this known or suspected source. (This should be described in more detail in the report text above.) 6 Certification: I, David A. Stoner, a Professional Geologist for Shield Engineering, Inc., do certify that the information cant,gi,gedsinitbis report is correct and accurate to the best of my knowledge. a,, `t CAI�,�{:; (Affix Seal an'� Si Shield Engineering, Inc. is icenseci to practice geology and engineering in North Carolina. The certification number of the company.or corporation is C- I 70(Geology) and F-0856 (Engineering). Carolina Fast Mart #4 Pit Stop Cabarrus County, North Carolina GWI#: 13403 7.0 LIMITATIONS Monitoring Report February 28, 2019 Page 13 Shield has performed environmental services at the subject site on behalf of Carolina Oil Company. Shield has performed this scope of work as an independent contractor/consultant using reasonable care and skill in accordance and consistent with customary industry standards of engineering, geology, and hydrogeology practices. This standard of care is the sole and exclusive standard of care that can be applied to measure Shield's performance of the work. No other warranty, expressed or implied is made or intended by Shield. The report has been prepared for the exclusive use by Carolina Oil Company. All recommendations, findings, and conclusions, made by Shield have been made to the best of Shield's knowledge, opinion and belief, based upon information obtained during this scope of work, and is limited by the scope nature and type of services as agreed upon between Carolina Oil Company and Shield. Conclusions are provided with the understanding that Shield is presenting information and not rendering legal advice. If such advice is needed, legal counsel should be consulted. It is the responsibility of Carolina Oil Company under advice of its counsel to notify the appropriate federal, state, or local public agencies as required by law; or otherwise to disclose in a timely manner, any information that may be necessary to prevent damage to human health, safety, or the environment. Compliance with recommendations provided as part of this report in no way assures compliance with federal, state and/or local laws, regulations, and/or requirements. Analytical data has been obtained from Pace Analytical Services, LLC. Information and calculations pertaining to the MMPE event were obtained from Advanced Environmental Services, Inc. This information, to the extent that it was relied on to generate this report, is assumed to be correct and complete. The work performed in conjunction with this report and the data developed are intended as a description of available information at the dates and specific locations given. Shield is not responsible for inspecting, examining, or reporting findings or recommendations with respect to any conditions that were knowingly or unknowingly withheld, concealed, hidden, or in anyway not disclosed or observable at the time of this scope of work. FIGURES H:\PROJECTS\2012\1120116-01 CAROLINA FAST MART PIT STOP\FIGURES\SITE LOCATION MAP 4-15-14.DWG 3 0 a s N O� LEGEND 0 ' J04 — EAR R, 0 SITE SOURCE 55093440760000 PARCEL IDENTIFICATION NUMBER WATER SUPPLY WELL - USED FOR NON -POTABLE PURPOSES WATER SUPPLY WELL - WELL USE UNCERTAIN WATER SUPPLY WELL - NOT IN USE CONNECTED TO MUNICIPAL WATER WATER SUPPLY WELL - WELL LIKELY NOT IN USE (VACANT LAND) --------- INTERMITTENT DRAINAGE FEATURE NOTES: 1. REFERENCE CABARRUS COUNTY GIS. 2. ALL LOCATIONS ARE APPROXIMATE. GRAPHIC SCALE 100' 200' 300' SCALE: 1 in. = 300 ft. SHIELD.4 CHI.0913 C ROAD ENGINEERING, INC. Nnvshie1dena"�"� °" 1,500' RADIUS MAP CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONDORD, NORTH CAROLINA SHIELD N 1120116.01 DATE : 04/15/14 DRAWN BY: RBS SCALE : AS SHOWN I FIGURE : 3 WSW-1 -430' FROM CAROLINA FAST MART #4 f R R-O-W EXXON STATION �f PUMP ISLAND CANOPY f MW-14 e (92.44) ti 1 i It r I rl v , 3 r7,y ' y U , l 92..93 I)p l 1 12 MW-17 q", / /— (93.85) 1 / E 94.80' CAROLJN)(,N e �/ / MW-2 .(94.98) UST ' / 1 I (94.48] PIT ' &MW-15' 3 : 94.00'.�(93.82) —� MW-106 (94.37) / � �, p3.52] i — �1 r� / ' (i qA —-------- —-- W J-y .�y y W y V' -V --V W W W V W V _ V --- V .--- V- V ®MW-15 (94.73) MW 8 U.S. HIGHWAY29 —-- ----- ----__ __ LEGEND 4 TYPE II MONITORING WELL ® TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED i WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION — W — — WATER LINE GAS — GAS GAS LINE E — E ELECTRIC POWER - - - DRAINAGE FEATURE -- - PROPERTY BOUNDARY —R-O-W — - - — RIGHT-OF-WAY i LIGHT POLE (ft) FEET (91.19) GROUNDWATER ELEVATION (ft) [90.77] GROUNDWATER ELEVATION (ft) NOT USED IN CONTOURING - — — — — — GROUNDWATER POTENTIOMETRIC CONTOUR LINE �- ESTIMATED GROUNDWATER FLOW DIRECTION (NM) NOT MEASURED NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. DEPTHS TO GROUNDWATER MEASURED ON 01/03/2019. 4. CONTOUR INTERVAL AS SHOWN. GRAPHIC SCALE 0 10 z0 30 40 SCALE: 1 in. = 40 ft. a ROADSD-zELD ENGINEERING, INC. GROUNDWATER ELEVATION CONTOUR MAP 01 /03/ 19 CAROLINA FAST MART #4 PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD # 1120116 DATE : 1 /14/19 1 DRAWN BY: MTS SCALE : AS SHOWN I FIGURE : 4 WSW-1 -430' FROM CAROLINA (ND) FAST MART #4 'Elm PUMP ISLAND CANOPY �f ' f E MW-14 EXXON STATION �X 5` h LIGHT P E✓ 7- MW.17 - / + rrAST MART �TW-1 / PIT STOP MW-13 �MW-2 :(ND) (ND) i �MW-1.6 'I_. ..................... 3 i.I (560) MW10B LEGEND y TYPE II MONITORING WELL ® TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION y —y WATER LINE GAS -GAS- GAS LINE e --s -- ELECTRIC POWER OVERHEAD ELECTRIC POWER -� PROPERTY BOUNDARY —R-O-W — - - — RIGHT-OF-WAY O LIGHT POLE (ug/L) MICROGRAMS PER LITER —_`_—_ I (6,280) BENZENE CONCENTRATION (ug/L) 12 [ND] BENZENE CONCENTRATION (ug/L) NOT / USED IN CONTOURING — — — — — — BENZENE ISOCONCENTRATION LINE (ug/L) I ' (ND) NOT DETECTED AT OR ABOVE 1 / ' LABORATORY DETECTION LIMITS 1 1 [ 148) ry 10�� / / -(ND] J 1 , W J_ V V --v V V V V / V �. V_ y y y (&MW-15 - (ND) MW-8 U.S. HIGHWAY29---------------------- --- NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 01/03/2019. 4. CONTOUR INTERVAL AS SHOWN, GRAPHIC SCALE D 10 20 30 40 SCALE: 1 in. =40 ft. SMELD.'......GGART CREEK ROAD 0953 ENGINEERING, INC. ""�hwlda gin-nw BENZENE ISOCONCENTRATION MAP CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD # 1120116 DATE: 1 /14/2019 1 DRAWN BY: MTS SCALE : AS SHOWN FIGURE: 5 WSW-1 -430' FROM CAROLINA (ND) FAST MART #4 9 R-O-W H 1`�wu PUMP r ISLAND CANOPY ' 7 / r 5 f �E MW-14 ® r 4 EXXON STATION '� / U ' 1' F 11 �' v 1 � MW-6 5--1 {ND) .-�_�__ _, / 12 1 7ly/ j LIGHT POLE 1 / f MW-17 / - (12) CAROLINA 1 r FAST MART TW ' a� PIT STOP MW-13 / MW-2 (N0) UST (4.4) ,...,. PIT ' r i 4 ................... -16 M (104) ........... r r MW 10B 1 rI (6.8) 103K ®TW-2 ' / [ND] I — / � �-',-}\ �� �~ � fP[ L�.➢IE-- �.0 a1L {1NE��_ ❑NE 9%� 9HE 9H� 9H`E— / +� MW-15 - {1.1) �` f w MW-8 R-O-W — - - U.S. HIGHWAY 29 - - _ LEGEND TYPE II MONITORING WELL ® TW TYPE III MONITORING WELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION -- w - WATER LINE GAS LINE ELECTRIC POWER - - - DRAINAGE FEATURE --- PROPERTY BOUNDARY — - R-O-W - - — RIGHT-OF-WAY O LIGHT POLE (ug/L) MICROGRAMS PER LITER (414) DIISOPROPYL ETHER CONCENTRATION (ug/L) [ND] DIISOPROPYL ETHER CONCENTRATION (ug/L) NOT USED IN CONTOURING - — — — — — DIISOPROPYL ETHER ISOCONCENTRATION LINE (ug/L) (ND) NOT DETECTED AT OR ABOVE LABORATORY DETECTION LIMITS NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02, 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 01/03/2019. 4. CONTOUR INTERVAL AS SHOWN. GRAPHIC SCALE ♦] 10 20 30 40 w — w SCALE: 1 in. = 40 ft. CREEK ROAD SHIELDCHARLOTTE, HP.R OTTART ENC 28208 ENGINEERING INC W s"1,ld-gmwnN DIISOPROPYL ETHER O(PE ISOCONCENTRATION MAP CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD # 1120116 DATE : 1/14/2019 1 DRAWN BY: MTS SCALE : AS SHOWN I FIGURE: 7-1 WSW-1 —430' FROM CAROLINA (ND) FAST MART #4 f f f \ f EXXON STATION X 9 X 11 PUMP ISLAND CANOPY f \f MW-141 R-O-W— _--------------= LIGHT POLE / / !f / Q �1 ti l l ,Cl / 3 N , 5 / i u� a N V 64 ' 7 5 �MjNi; ' �.J / �} 12 r h ' LIGH POLE2 ; M D)17 + CAROLINA 1 FAST MART TW 1 / PIT STOP MW.2, N[ij UST 1 (ND) Prr MW-16 �� 4 / i [ (12.3) / 0 MW 9 OB '&T -2 I / / [ND] 1 v -v g MW-15 —" —V `w — IND) MW-8 --------R-O-W — — — -— ------ U.S.HIGHWAY29 —- �—--�—--- LEGEND TYPE WATER LINE GAS LINE — c — ELECTRIC POWER DRAINAGE FEATURE --- PROPERTY BOUNDARY — — R-O-W — — — RIGHT-OF-WAY C' LIGHT POLE (ug/L) MICROGRAMS PER LITER (465) NAPHTHALENE CONCENTRATION (ug/L) [ND] NAPHTHALENE CONCENTRATION (ug/L) NOT USED IN CONTOURING — — — — — NAPHTHALENE ISOCONCENTRATION LINE (ug/L) (ND) NOT DETECTED AT OR ABOVE LABORATORY DETECTION LIMITS NOTES: 1. REFERENCE SITE PLAN BY ENGINEERING TECTONICS, P.A. DATED 07-02. 2. ALL LOCATIONS ARE APPROXIMATE. 3. GROUNDWATER SAMPLES COLLECTED ON 01/03/2019. 4. CONTOUR INTERVAL AS SHOWN. GRAPHIC SCALE 0 10 2D 30 4o V - y y - . V SCALE: 1 in. = 40 Ft. SHIELD O91WFE R �K ROAD ENGIIiIEa RING. INC. � s"1eld-gi—nng °^ NAPHTHALENE ISOCONCENTRATION MAP CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHIELD # 1120116 DATE : 1 /14/2019 1 DRAWN BY: MTS SCALE : AS SHOWN I FIGURE : 8 TABLES Table 1: Water Supply Well and Receptor Information Carolina Fast Mart #4 Pit Stop Concord, NC Date Information/Sum ey Compiled: October 2012 Already Parcel No. Name Property Address connected to Supply Well on Date Phone Number Well use Depth of Depth of Diameter of Screened Willing to connect Distance from City or County property? Installed Well Casing Well Interval to city water'? source area of water? release WSW-1 Blackwelder 3213 Perry Street, Conocrd NC 704-634-8664 Yes Yes Washing Vehicles 1982 N/A N/A N/A N/A N/A 430 feet WSW-2 Carpenter 60 Pitts School Road NW, Concord NC N/A Yes Well House Not in Use N/A N/A N/A N/A N/A N/A 530 feet Observed WSW-3 Strickland 80 Pitts School Road NW, Concord NC N/A Yes Yes Washing Vehicles N/A N/A N/A N/A N/A N/A 740 feet WSW-4 Furr 84, 88 Pitts School Road N W, Concord NC N/A Yes Yes Not in Use N/A N/A N/A N/A N/A N/A 840 feet WSW-5 Gordon 99 Pitts School Road NW, Concord NC N/A Yes Yes Not in Use N/A N/A N/A N/A N/A N/A 990 feet WSW-6 Mauney 91 Pitts School Road NW, Concord NC N/A Yes Yes Not in Use 1900 30'-40' N/A N/A N/A N/A 940 feet WSW-7 Carpenter Vacant Lot N/A N/A Well House N/A N/A N/A N/A N/A N/A N/A 1290 feet Observed HAProjects\1999\19900MTable 1 Supply Well Survey Table Page 1 of 1 Table 2: Summary of Well Construction and Groundwater Elevation Data Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County NCDEQ GWI#: 13403 Well ID Date Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth to Free Product (feet) Depth to Static Water (feet) Diff. Between As -built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) MW-2 NA 100.00 2 NA 09/07/01 NA ND 10.1 NM NM 89.90 06/27/02 NA ND 10.85 NM NM 89.15 10/31/12 26.85 ND 11.24 NM 15.61 88.76 04/01/14 26.85 ND 6.60 NM 20.25 93.40 10/21/14 26.85 ND 9.50 NM 17.35 90.50 06/08/15 26.85 ND 8.55 NM 18.30 91.45 02/17/16 26.85 ND 6.43 NM 20.42 93.57 11/30/16 26.85 ND 11.20 NM 15.65 88.80 07/19/17 26.85 ND 8.80 NM 18.05 91.20 12/13/17 26.85 ND 990 NM 16.95 90.10 06/26/18 26.85 ND 8.81 NM 18-04 91-19 01/03/19 26.85 ND 5.82 NM 21-03 94.18 MW-6 NA 94.77 2 NA 09/07/01 NA ND 5.3 NM NM 89.47 06/27/02 NA ND 6-41 NM NM 88.36 10/31/12 8.84 ND 6.26 NM 2.58 88.51 04/01/14 8.84 ND 3.36 NM 5.48 91.41 10/21/14 8.84 ND 5.16 NM 3.68 89.61 06/08/15 8.84 ND 4.20 NM 4.64 90.57 02/17/16 8.84 ND 293 NM 5.91 91.84 11/30/16 8.84 ND 5.84 NM 3.00 88.93 07/19/17 8.84 ND 4-28 NM 4.56 90.49 12/13/17 8.84 ND 4.81 NM 4.03 89.96 06/26/18 8.84 ND 4.37 NM 4.47 90.40 01/03/19 8.84 ND 2.82 NM 6.02 91.95 MW-lOB NA 98.82 2 NA 09/07/01 NA ND 8.93 NM NM 89.89 06/27/02 NA ND 9.25 NM NM 89-57 10/31/12 20.20 ND 9.57 NM 10.63 99.25 04/01/14 20.20 ND 5.22 NM 14.98 93.60 10/21/14 20.20 ND 8.05 NM 12.15 90.77 06/08/15 20.20 ND 7-02 NM 13.18 91.80 02/17/16 20-20 ND 5.17 NM 15.03 93.65 11/30/16 20.20 ND %64 NM 10.56 89.18 07/19/17 20.20 ND 7.15 NM 13.05 91.67 12/13/17 20.20 ND 8.49 NM 11.71 90.33 06/26/18 20.20 ND 7.98 NM 12.22 9084 01/03/19 1 20.20 1 ND 4.45 NM 15.75 94 37 H\Projecls\201 A1120116 Summary of Well Construction and Historical Groundwater Elevation Data- Carolina Fast Mart Pit Slop Page 1 of 3 Table 2: Summary of Well Construction and Groundwater Elevation Data Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County NCDEQ GWI#: 13403 Well ID Date Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth to Free Prod6ct (feet) Depth to Static Water (feet) Diff. Between As -built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) MW-13 NA 99.32 2 NA 09/07/01 NA ND 9.3 NM NM 90.02 06/27/02 NA ND 10.28 NM NM 89.04 10/31/12 15.20 ND 10.48 NM 4.72 88.84 04/01/14 15.20 ND 5.19 NM 10.01 94.13 10/21/14 15.20 ND 9.36 NM 5.84 89.96 06/08/15 15.20 ND 7.49 NM 7.71 91.83 02/17/16 15.20 ND 5.36 NM 9.84 93.96 11/30/16 15.20 ND 10.54 NM 4.66 88.78 07/19/17 15.20 ND 7.71 NM 7.49 91.61 12/13/17 15.20 ND 9.11 NM 6.09 90.21 06/26/18 15.20 ND 7.73 NM 7.47 91.59 01/03/19 15.20 ND 4.34 NM 10.86 94.99 MW-14 NA 93.24 2 NA 09/07/01 NA ND 4.74 NM NM 88.50 06/27/02 NA ND 5 86 NM NM 87.38 10/31/12 19.21 ND 5.02 NM 14.19 88.22 04/01/14 19.21 ND 2.76 NM 16.45 90.48 10/21/14 19.21 ND 1.42 NM 17.79 91.82 06/08/15 19.21 ND 2.68 NM 16.53 90.56 02/17/16 19.21 ND 1.91 NM 17.30 91.33 11/30/16 19.21 ND 4.52 NM 14.69 88.72 07/19/17 19.21 ND 2.64 NM 16.57 90.60 12/13/17 19.21 ND 3.71 NM 15.50 89.53 06/26/18 19.21 ND 3.53 NM 15.68 89.71 01/03/19 19.21 ND 0.80 NM 18.41 92,44 MW-15 09/04/13 98 93 2 20 09/04/13 20.25 ND 8.62 -0.25 11,63 90.31 04/01/14 20.25 ND 4.83 -0.25 15.42 94.10 10/21/14 20.25 ND 8.25 -0.25 12.00 90.68 06/08/15 20.25 ND 6.91 -0-25 13.34 92.02 02/17/16 20,25 ND 4.8 -0.25 15.45 94.13 11/30/16 20,25 ND 9.62 -0.25 10.63 89,31 07/19/17 20,25 ND 7.02 -0.25 13.23 91.91 12/13/17 20.25 ND 8.48 -0.25 11.77 90.45 06/26/18 20.25 ND 8.03 -0.25 12.22 90.90 01/03/19 20.25 ND 4.2 -0.25 16.05 94.73 MW-16 09/04/13 98.36 2 20 09/04/13 19.96 ND 8.15 0.04 11.81 90.21 04/01/14 19.96 ND 5.31 0.04 14.65 93.05 10/21/14 19.96 ND 7.85 0.04 12.11 90.51 06/08/15 19.96 ND 6.72 0.04 13.24 91.64 02/17/16 19.96 ND 5.21 0.04 14.75 93.15 11/30/16 19.96 ND 9.25 0.04 10.71 8911 07/19/17 19.96 ND 6.72 0.04 13.24 91.64 12/13/17 19.96 ND 7.84 0.04 12.12 90.52 06/26/18 1 19.96 1 ND 7.01 0.04 12.95 91.35 01/03/19 19.96 ND 4.54 0.04 1 15.42 93.82 HAPro/'ec1sV01211120116 Summary o1 Well Construction and "W.rical Groundwater Elevation Data- C-1ma Fast Mart Pit Stop Page 2 of 3 Table 2: Summary of Well Construction and Groundwater Elevation Data Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County NCDEQ GWI#: 13403 Well ID Date Installed Top of Casing Elevation (feet) Well Diameter (inches) As -built Depth (feet) Screened Interval (feet) Field Measurements Field Calculations Gauging Date Total Depth (feet) Depth to Free Product (feet) Depth to Static Water (feet) DifC Between As -built and Measured Total Depth (feet) Measured Water Column in Well (feet) Groundwater Elevation (feet) MW-17 09/04/13 98.00 2 20 09/04/13 1 19.94 ND 6.0 0.06 13.94 92.00 04/01/14 19.94 ND 4.94 0.06 15.00 93.06 10/21/14 19.94 ND 8.42 0.06 11.52 89.58 06/08/15 19.94 ND 3.84 0.06 16.10 94.16 02/17/16 19.94 ND 4.74 0.06 15.20 93.26 11/30/16 19.94 ND 9.37 0.06 10.57 88.63 07/19/17 19.94 ND 7.04 0.06 12.90 90.96 12/13/17 19.94 ND 7.99 0.06 11.95 90.01 06/26/18 19.94 ND 7.12 0.06 12.82 90.88 01/03/19 19.94 ND 4.15 0.06 15.79 93.85 TW-2 NA 99.18 2 NA 09/07/01 NA ND 9.5 NM NM 89.68 06/27/02 NA ND 8.57 NM NM 90.61 10/31/12 51.06 ND 7.96 NM 43.10 91,22 04/01/14 51.06 ND 5.63 NM 45.43 93.55 10/21/14 51.06 ND 7.94 NM 43.12 91.24 06/08/15 51.06 ND 4.08 NM 46.98 95.10 02/17/16 51.06 ND 5.43 NM 45.63 93.75 11/30/16 51.06 ND 9.74 NM 41.32 89.44 07/19/17 51.06 ND 7.18 NM 43.88 9100 12/13/17 51.06 ND 8.62 NM 42.44 90.56 06/26/18 51.06 ND 9.41 NM 42.65 90.77 01/03/19 51.06 ND 5.66 NM 45.40 93.52 Notes: I. Elevations are relative to a temporary benchmark set with an assumed datum of 100.00 feet; data reported in feet. 2. NA = Not Available 3. ND = Not Detected 4. 2001and 2002 data from NCDEQ files measured by previous consultant H.\Projecls\2012\1120116 Summary of Well Construction and Historical Groundwater Elevation Data Carolina Fast Mart Pit Slop Page 3 of 3 Table 3: Summary of Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCDEQ GWI # 13403 Analytical Method ---- > EPA Method 6200B/602 � C d c N Nd L71 is F w 1 O L i L L y G w E~ = z o a E~ A N ri Location Date Sampled ug/L' ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards2 1 600 600 500 20 70 6 70 70 400 GCL' 5,000 260,000 84,500 85,500 20,000 70,000 6,000 25,000 30,000 28,500 MW-2 1/3/2019 ND ND ND ND 1.2 4.4 ND ND ND ND MW-6 1/3/2019 ND ND ND ND 1 ND ND ND ND ND MW-10B 1/3/2019 148 2.4 54.7 33.9 12.3 6.8 59.5 12.4 ND 104 MW-13 1/3/2019 ND ND ND ND ND ND ND ND ND ND MW-14 1/3/2019 ND ND ND ND 3.9 2.8 ND ND ND ND MW-15 1/3/2019 ND ND ND ND 3.7 1.1 ND ND ND ND MW-16 1/3/2019 560 5.3 8.7 ND 45.7 104 12.3 2.3 2.7 ND MW-17 1/3/2019 6 ND ND ND 2.7 12 ND ND ND ND TW-2 1/3/2019 ND ND ND ND ND ND ND ND ND ND WSW-1 1/3/2019 NS - No power to well; Owner states there is a leak in well piping that will need to be repaired. Trip Blank 1/3/2019 ND ND ND ND ND ND ND ND ND ND Notes: 1. Micrograms per liter 2. NCDEQ - North Carolina Administrative Code Title 15A Subchapter 2L Class GA Groundwater Standards 3. NCDEQ Gross Contaminant Levels.for groundwater Bold data was detected at or above 2L Standards ND - Not detected NA= Not Analyzed NS - Not Sampled Italicized was detected at or above the NCDEQ Gross Contaminant Levels Other detected analytes may be seen in the attached laboratory analytical report. H:\Projects\2012\1120116-01 Carolina Fast Mart Pit Stop\Reports\MR January 2019\Table 3 Summary of Analytical Results -Carolina Fast Mart Pit Stop Page 1 Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCD EQ G W 1 # 13403 Analltical Method --- > EPA Method 6200E m F 4 F E — C Z _ o E F Location Dale Sampled ug/L' ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards' 1 600 600 500 20 70 6 70 70 400 GCL' 5.000 260,000 84,500 85,500 20,000 70,000 6,000 25,000 30,000 28,500 MW-2 6/27/2002 NO NO NO NO NO NO NA NA NA NA 10/31/2012 NO NO NO NO 2.3 NO NO NO NO NO 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/1/2014 NO NO NO NO 1.3 NO NO NO NO ND 10/21/2014 NO NO NO NO 1.5 NO NO NO NO NO 6/8/2015 NO NO NO NO 1.7 NO NO NO NO NO 2/17/2016 NO NO NO NO 1.3 NO NO NO NO NO 11/30/2016 NO NO NO NO 1.1 NO NO NO NO NO 7/19/2017 NO NO NO NO 1.2 NO NO NO NO ND 12/13/2017 NO NO NO NO 1.4 NO NO NO NO NO 6/26/2018 NO NO NO NO 1.3 NO NO NO NO NO P3/2019 NO NO NO NO 1.2 4.4 NO NO NO NO MW-6 6/27/2002 NO NO ND NO NO NO NA NA NA NA 10/31/2012 NO NO NO NO 1.4 NO NO NO NO NO 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/1/2014 ND NO NO NO 2.5 NO NO NO NO NO 10/21/2014 NO NO NO NO 3.6 NO NO NO NO NO 6/8/2015 NO NO NO NO 26.9 0.54 NO NO NO NO 2/17/2016 NO NO NO NO 19.2 0.74 NO NO NO NO 11/30/2016 NO NO NO ND 1.9 NO NO NO NO NO 7/19/2017 NO NO NO ND IM ND NO NO NO NO 12/13/2017 NO NO NO NO 4.4 NO NO NO NO NO 6/26/2018 NO NO NO NO 7.7 NO NO NO NO NO 1/3/2019 NO NO NO NO I NO NO NO NO NO III—) nszolznzonsrame 4 summary orwvonoai aaaiN��a veswis-cn.mma razr man vn srop Page t of 5 Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCDEQ GWI # 13403 Analytical Method--> EPA Method 6200B m` us/Lt F a C � - c E n Location =..I� ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards' t 600 600 500 20 70 6 70 70 400 GCL'' 5,000 260,000 84,500 85,500 20,000 70,000 6,000 25,000 30,000 28500 MW-10B 6/27/2002 14.0M 1,200 860 3,300 800 1,200 NA NA NA NA 10/31/2012 17,M 277 987 706-3 3,720 834 632 62-0 152 207 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/l/2014 3,670 I85 222 612 563 148 134 23 52.2 276 10/21/2014 ,Qd�p 229 487 896 1,120 290 376 48 5 117 362 6/8/2015 R,4'7 335 549 1,401 637 249 415 ND 117 545 2/17/2016 1,970 91 9 170 703 230 79.5 160 23 6 61.2 434 11/30/2016 1,040 29 4 106 257.7 156 55 1 158 196 51.1 244 7/19/2017 3,530 82.4 240 518 429 134 239 28.6 ND 302 12/13/2017 1,120 31.4 165 535 145 70.6 258 22.4 ND 370 6/26/2018 6; IM0, 50.2 380 501 988 414 465 43.2 ND 499 7/25/2018 994 15.3 94.1 202.7 178 62.6 82.6 ND NA NA 1/3/2019 148 2-4 54.7 33.9 12.3 6.8 59.5 12-4 ND ND 1/30/2019 1,790 54.8 179 959 266 80.5 182 17-9 NA NA MW-13 6/27/2002 720 19 24 93 130 ND NA NA NA NA 10/31/2012 19.5 10 1.2 1.9 3.2 ND 2-4 1.9 3A ND 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/1/2014 17.6 0.65 M5 1.6 ND ND ND 1-7 3.4 ND 10/21/2014 5.5 0.66 076 2 31 1.1 ND ND 45 ND ND 6/8/2015 ND ND ND ND ND ND ND ND ND ND 2/17/2016 5.7 ND ND ND ND ND ND 0 57 0.89 ND 11/30/2016 ND ND ND - 063 ND ND 0.55 ND ND 7/19/2017 13.5 1 ND 231 ND ND ND 24 2.9 ND 12/13/2017 35.5 2.1 1 5.05 ND ND 3 3.6 4.3 ND 6/26/2018 19.1 1.9 057 3-94 ND ND ND 3.2 5.2 ND 1/3/2019 ND ND ND ND ND ND ND ND ND ND rrw.o�..-rsomanzonernme ara,or„a I—ur n 11., Page 2 of Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC %C D EQ G W I # 13403 Analytical Method----> EPA Method 6200B G — e Location Date Sampled ug/Lr ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards' 1 600 600 500 20 70 6 70 70 400 GCL' 5,000 260,000 84,500 85,500 20,000 70,000 6,000 25,000 30,000 28500 MW-14 6/27/2002 ND ND ND ND 1,800 ND NA NA NA NA 10/31/2012 ND ND ND ND 87.6 6.8 ND ND ND ND 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/1/2014 ND ND ND ND 5-6 2.6 ND ND ND ND 10/2P2014 ND ND ND ND 96 7-0 ND ND ND ND 6/8/2015 ND ND ND ND 49 41 ND ND ND ND 2/17/2016 ND ND ND ND 38 42 ND ND ND ND 11/30/2016 ND ND ND ND 12 3 15 6 ND ND ND ND 7/19/2017 ND ND ND ND 14 10 9 ND ND ND ND 12/13/2017 ND ND ND ND 13.4 17 ND ND ND ND 6/26/2018 ND ND ND ND 15.6 10.8 ND ND ND ND 1/3/2019 ND ND ND ND 3 9 2.8 ND ND ND ND MW-15 9/4/2013 ND ND ND 1 3 0 86 ND 14.9 2.8 4.0 92 4/l/2014 ND ND ND ND 19.7 73 ND 1.9 U6 ND 10/21/2014 ND ND ND ND 6 9 4.5 ND 15 0-54 ND 6/8/2015 ND ND ND ND 7.9 5-2 ND ND ND ND 2/17/2016 ND ND ND ND 12 6 6 ND 0.99 ND ND 11/30/2016 ND ND ND ND 0-8 0-51 ND ND ND ND 7/19/2017 ND ND ND ND 6 2-8 ND ND ND ND 12/13/2017 ND ND ND ND 0,66 ND ND ND ND ND 6/26/2018 ND ND ND ND 4.9 2.3 ND ND ND ND 1/3/2019 ND ND ND ND 3.7 IA ND ND ND ND 111.*n11o,z11mr1- 4 sum ,orwaoncrrFarr. a, soo Page 3 of 5 Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCDEQ GWI n 13403 Analytical Method-> EPA Method 6200B _ _ F C n � c Location Date Sampled ug/L' ug/L u•/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards' 1 600 600 500 20 70 6 70 70 400 GCL" 5,000 260,000 84,500 85,500 20,000 7000 6,000 25,000 30,000 28,500 MW-16 9/4/2013 ,S I.v 5910 402 1278 244 216 603 70.2 151 106 4/l/2014 963 89.1 ND 48 90.4 115 96.1 16 35.7 21 10/21/2014 3,740 54 225 625 72.6 43.5 716 76.2 181 14.1 6/8/2015 1,640 21,3 132 53-1 220 73 568 362 73.4 27.1 2/17/2016 1360 17 127 68.6 108 135 88.8 185 39.5 40.4 11/30/2016 302 5.7 54.6 31.6 51.2 17.4 337 12 8 243 10.7 7/19/2017 416 9.4 90.5 33.6 128 25.1 231 127 17 7.9 12/13/2017 129 2.1 8.7 8.3 7.7 4.9 75.7 26 34 2 6/26/2018 1,120 10.7 29.1 16 7 132 20.5 268 6 8 104 ND 7/25/2018 Nit ND 34.9 ND 39.2 114 ND ND NA NA 1/3/2019 560 5 3 9.7 ND 45.7 104 12.3 23 2.7 ND 1/30/2019 516 9 685 21.4 27.6 67 19.6 6.1 NA NA MW-17 9/4/2013 4.1 ND ND ND 5.3 0.58 ND ND ND ND 4/1/2014 4.8 ND ND ND 3 ND ND ND ND ND 10/21/2014 ND ND ND ND 26.1 0.91 ND ND ND ND 6/8/2015 5.7 ND ND ND 4.7 ND 14D ND ND ND 2/17/2016 8.3 ND ND ND 2 7 0.61 ND ND ND ND 11/30/2016 ND ND ND ND IS 081 ND ND ND ND 7/19/2017 0-94 ND ND ND 29 063 ND ND ND ND 12/13/2017 ND ND ND ND 0.93 ND ND ND ND ND 6/26/2018 5.5 ND ND ND 3.2 06 ND ND ND ND 1/3/2019 6 ND ND ND 2.7 12 ND ND ND ND TNV-2 6/27/2002 ND ND ND ND ND ND NA NA NA NA 10/31/2012 ND ND ND ND 0.57 ND ND ND ND ND 9/4/2013 NS NS NS NS NS NS NS NS NS NS 4/1/2014 ND ND ND ND ND ND ND ND ND ND 10/21/2014 ND ND ND ND ND ND ND ND ND ND 6/8/2015 ND ND ND ND ND ND ND ND ND ND 2/17/2016 ND ND ND ND ND ND ND ND ND ND 1./30/201fi ND ND ND ND ND ND ND ND ND ND 1 Iwoµ tstzma 1-1-.1s ..'r-'Ot Pil Sop Page 4 of Table 4: Summary of Historical Analytical Results - Groundwater Samples Carolina Fast Mart #4 Pit Stop Concord, Cabarrus County, NC NCDEQ CWI # 13403 Analytical Method—> EPA Method 6200B oe Y m G & _ X e - E q n Location Date Sampled ug/L' ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L ug/L 2L Standards' 1 600 600 500 20 70 6 70 70 400 OCL' 5,000 260,000 84,500 85,500 20,000 70,000 6,000 25,000 30,000 29.500 TW-2 7/19/2017 ND NO ND ND NO ND NO NO NO ND CONT. 12/13/2017 ND ND NO ND NO NO ND NO ND NO 6/26/2018 ND ND ND ND NO NO NO NO ND ND 1/3/2019 ND ND ND ND NO ND ND NO ND ND WSIV-1 4/1/2014 NO NO ND ND 1 29.9 087 ND NO ND ND 10/21/2014 ND NO NO ND 27.9 0.99 ND ND ND ND 6/8/2015 NO NO ND ND 40 0.57 ND ND ND ND 2/17/2016 NO NO ND ND 10.5 0.55 NO ND ND ND I1/30/2016 NO NO ND ND 9 ND ND NO ND NO 7/19/2017 ND ND ND ND LI ND NO NO NO ND 12/13/2017 NO NO ND NO 1.4 ND ND ND ND ND 6/26/2018 NO NO ND ND I ND ND NO NID NO 1 /3/2019 NS - No power to well; Owner states there is a leak in well piping that will need to be repaired, Trip Blank 11/30/2016 ND ND ND NO NO ND ND ND ND ND 7/19/2017 ND ND ND ND ND NO NO ND ND NO 12/13/2017 ND ND ND ND ND ND NO ND NO ND 6/26/2018 ND ND NO NO ND NO ND NO ND ND 1/3/2019 ND ND ND NO ND NO NO ND ND NO Notes: 1; miorogranu per' lire'.. 2. NCOE.Q- NarTh Cnrblioa Ad Wiv-6ve Carle Title 19ASd5,hnprer2L Class CA Grmardwaler Standards 3. NCDEQ Gross Cnulnminani L. Is,far'.grn ndwa(e., Bold dean wn,e rlereerer' nr nr nbve 2L.4a Wllr is )nm detected m orahave GCL.s NU -Nnl rlemcied NA -Nor Annly-1 NS- Nnr Samples' 2002 data from NCDEQ files presenred by previous consultant Other detected analytes can be seen in the analytical data Page 5 of 5 Appendix A Geologic Logs for Borings Not Applicable or Not Available (NA) Appendix S Copies of NORR, NOV, etc. related to Submittal of Site Closure Report (NA) Appendix C Natural Attenuation Parameters (NA) Appendix D Remedial System Perfvrmanee Tables &. Graphs (NA) Appendix E Constituent Concentration vs Tinie/Hydrograph(s) 20,000 18,000 16,000 J 14,000 0 12,000 c 10,000 �o+ c 8,000 N c O u 6,000 4,000 2,000 0 4/19/2001 Constituent Concentrations vs Time/Hydrograph: MW-10B Carolina Fast Mart #4 - Pit Stop 1/14/2004 10/10/2006 7/6/2009 4/1/2012 12/27/2014 9/22/2017 Date 95 94 93 90 89 88 6/18/2020 W —*—Benzene M—Total Xylenes MTBE —0<—Diisopropyl ether --*—Naphthalene Groundwater Elevation 6,000 5,000 J e� 4,000 c 0 m 2,000 c 0 U 1,000 0 1/1/2013 Constituent Concentrations vs Time: MW-16 Carolina Fast Mart #4 - Pit Stop 5/16/2014 9/28/2015 2/9/2017 6/24/2018 Date 95 94 93 c 0 A 92 —Benzene 3 • .7 — MTBE 91 e -Naphthalene i c� Groundwater Elevation 90 89 88 11/6/2019 Appendix F Compilation of Costs for Performance of Remedial Plan (NA) Appendix G Chronology of .Remed.iation Activities (NA) Appendix H Proposed Remediation Schedule and Cleanup Progress Milestones (NA) Appendix Y Laboratory Analytical Results aceAnalj4ica!® + www.pacelabs.com i January 08, 2019 Matt Smith Shield Engineering 4301 Taggart Creek Road Charlotte, NC 28208 RE: Project: PIT STOP BP Pace Project No.: 92412854 Dear Matt Smith: Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on January 04, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: James Gamertsfelder, Shield Engineering, Inc. Mr. Tom Witner, Shield Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 1 of 36 aceAnalytical www.pacelabs.com Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: PIT STOP BP Pace Project No.: 92412854 Charlotte Certification IDs 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification #: 84 North Carolina Field Services Certification #: 5342 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 2 of 36 laceAnalytical www.pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pace Project No.: PIT STOP BP 92412854 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92412854001 MW-2 SM 6200B CL 63 PASI-C 92412854002 MW-6 SM 6200B CL 63 PASI-C 92412854003 MW-10B SM 6200B CL 63 PASI-C 92412854004 MW-13 SM 6200B CL 63 PASI-C 92412854005 MW-14 SM 6200B CL 63 PASI-C 92412854006 MW-15 SM 6200B CL 63 PASI-C 92412854007 MW-16 SM 6200B CL 63 PASI-C 92412854008 MW-17 SM 6200B CL 63 PASI-C 92412854009 TW-2 SM 6200E CL 63 PASI-C 92412854010 TRIP BLANK SM 6200B CL 63 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 3 of 36 lacmnalyti'01" www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-2 Lab ID: 92412854001 Collected: 01/03/19 11:50 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/0411918:50 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 18:50 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 18:50 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 18:50 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 18:50 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 18:50 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 18:50 104-51-8 sec- Butylbenzene ND ug/L 0.50 1 01/0411918:50 135-98-8 tert- B utyl benzene ND ug/L 0.50 1 01/04/19 18:50 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 18:50 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 18:50 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 18:50 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 18:50 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 18:50 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/04/19 18:50 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 18:50 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 18:50 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 18:50 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 18:50 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 18:50 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:50 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:50 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:50 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 18:50 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 18:50 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 18:50 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 18:50 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 18:50 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 18:50 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 18:50 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 18:50 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 18:50 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 18:50 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 18:50 10061-01-5 trans- 1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 18:50 10061-02-6 Diisopropyl ether 4.4 ug/L 0.50 1 01/04/19 18:50 108-20-3 Ethylbenzene ND ug/L 0.50 1 01/04/19 18:50 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 18:50 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 18:50 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 18:50 75-09-2 Methyl-tert-butyl ether 1.2 ug/L 0.50 1 01/04/19 18:50 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 18:50 91-20-3 n-Propylbenzene ND ug/L 050 1 01/04/19 18:50 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 18:50 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 18:50 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 18:50 79-34-5 Tetra chloroethene ND ug/L 0,50 1 01/04/19 18:50 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 4 of 36 aceAnalylrcal www.pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-2 Lab ID: 92412854001 Collected: 01/03/19 11:50 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Tri chloroflu oro metha ne 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3, 5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L NO ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 % 96 % 101 % 0.50 1 01/04/19 18:50 108-88-3 2.0 1 01/04/19 18:50 87-61-6 2.0 1 01/04/19 18:50 120-82-1 0.50 1 01/04/19 18:50 71-55-6 0.50 1 01/04/19 18:50 79-00-5 0.50 1 01/04/19 18:50 79-01-6 1.0 1 01/04/19 18:50 75-69-4 0.50 1 01/04/19 18:50 96-18-4 0.50 1 01/04/19 18:50 95-63-6 0.50 1 01/04/19 18:50 108-67-8 1.0 1 01/04/19 18:50 75-01-4 1 0 1 01/04/19 18:50 179601-23-1 0.50 1 01/04/19 18:50 95-47-6 70-130 1 01/04/19 18:50 17060-07-0 70-130 1 01/04/19 18:50 460-00-4 70-130 1 01/04/19 18:50 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent or Pace Analytical Services, LLC. Page 5 of 36 aceAnalyflcal -pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-6 Lab ID: 92412854002 Collected: 01/03/19 12:20 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/04/19 19:06 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 19:06 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/0411919:06 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 19:06 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 19:06 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 19:06 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 19:06 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/04/19 19:06 135-98-8 tert-Butyl benzene ND ug/L 0.50 1 01/04/19 19:06 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 19:06 56-23-5 Chlorobenzene ND ug/L 050 1 01/04/19 19:06 108-90-7 Chloroethane ND ug/L 10 1 01/04/19 19:06 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 19:06 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 19:06 74-87-3 2-Chlorotoluene ND ug/L 050 1 01/04/19 19:06 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:06 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 19:06 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 19:06 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 19:06 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 19:06 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01104/1919:06 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:06 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:06 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/0411919:06 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 19:06 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 19:06 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 19:06 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:06 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:06 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01104/1919:06 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 19:06 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:06 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 19:06 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:06 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:06 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 01/04/19 19:06 108-20-3 Ethylbenzene ND ug/L 0.50 1 01/04/19 19:06 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 19:06 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 19:06 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 19:06 75-09-2 Methyl-tert-butyl ether 1.0 ug/L 0.50 1 01/04/19 19:06 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 19:06 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 19:06 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 19:06 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:06 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:06 79-34-5 Tetrachloroethene ND ug/L 0.50 1 01/04/19 19:06 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 6 of 36 aceAnalytical —pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-6 Lab ID: 92412854002 Collected: 01/03/19 12:20 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1, 2, 3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 99 % 97 % 104 % 0.50 1 01 /04/19 19:06 108-88-3 2.0 1 01/04/1919:06 87-61-6 2.0 1 01 /04/19 19:06 120-82-1 0.50 1 01/04/1919:06 71-55-6 0.50 1 01/04/1919:06 79-00-5 0.50 1 01/04/1919:06 79-01-6 1.0 1 01/04/1919:06 75-69-4 0.50 1 01/04/1919:06 96-18-4 0.50 1 01/04/1919:06 95-63-6 0.50 1 01 /04/19 19:06 108-67-8 1.0 1 01/04/1919:06 75-01-4 1.0 1 01 /04/19 19:06 179601-23-1 0.50 1 01 /04/19 19:06 95-47-6 70-130 1 01 /04/19 19:06 17060-07-0 70-130 1 01/04/1919:06 460-00-4 70-130 1 01/04/1919:06 2037-26-5 REPORT OF LABORATORY ANALYSIS - This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 7 of 36 aceAnalXical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-10B Lab ID: 92412854003 Collected: 01/03/19 12:58 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene 148 ug/L 0.50 1 01/07/19 15:58 71-43-2 Bromobenzene ND ug/L 0.50 1 01/07/19 15:58 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/07/19 15:58 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/07/19 15:58 75-27-4 Bromoform ND ug/L 0.50 1 01/07/19 15:58 75-25-2 Bromomethane ND ug/L 5.0 1 01/07/19 15:58 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/07/19 15:58 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/07/19 15:58 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 01/07/19 15:58 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/07/19 15:58 56-23-5 Chlorobenzene ND ug/L 0.50 I 01/07/19 15:58 108-90-7 Chloroethane ND ug/L 1.0 1 01/07/19 15:58 75-00-3 Chloroform ND ug/L 0.50 1 01/07/19 15:58 67-66-3 Chloromethane ND ug/L 1.0 1 01/07/19 15:58 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/07/19 15:58 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/07/19 15:58 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/07/19 15:58 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/07/19 15:58 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/07/19 15:58 106-93-4 Dibromomethane ND ug/L 0.50 1 01/07/19 15:58 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/07/19 15:58 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/07/19 15:58 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/07/19 15:58 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/07/19 15:58 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/07/19 15:58 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/07/19 15:58 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/07/19 15:58 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/07/19 15:58 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/07/19 15:58 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/07/19 15:58 78-87-5 1,3-Dichloropropane ND ug/L 0,50 1 01/07/19 15:58 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/07/19 15:58 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01107/1915:58 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 01/07/19 15:58 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/07/19 15:58 10061-02-6 Diisopropyl ether 6.8 ug/L 0.50 1 01/07/19 15:58 108-20-3 Ethylbenzene 54.7 ug/L 0.50 1 01/07/19 15:58 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/07/19 15:58 87-68-3 Isopropylbenzene (Cumene) 12.4 ug/L 0.50 1 01/07/19 15:58 98-82-8 Methylene Chloride ND ug/L 2,0 1 01/07/19 15:58 75-09-2 Methyl-tert-butyl ether 12.3 ug/L 0.50 1 01/07/19 15:58 1634-04-4 Naphthalene 59.5 ug/L 2.0 1 01/07/19 15:58 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/07/19 15:58 103-65-1 Styrene ND ug/L 0.50 1 01/07/19 15:58 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/07/19 15:58 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/07/19 15:58 79-34-5 Tetra chIoroethene ND ug/L 0.50 1 01/07/19 15:58 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 36 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-10B Lab ID: 92412854003 Collected: 01/03/19 12:58 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B 2.4 ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 104 ug/L ND ug/L ND ug/L 31.5 ug/L 2.4 ug/L 105 % 102 % 99 % 0.50 1 01/07/19 15:58 108-88-3 2.0 1 01/07/19 15:58 87-61-6 2.0 1 01/07/19 15:58 120-82-1 0.50 1 01/07/19 15:58 71-55-6 0.50 1 01/07/19 15:58 79-00-5 0.50 1 01/07/19 15:58 79-01-6 1.0 1 01/07/19 15:58 75-69-4 0.50 1 01/07/19 15:58 96-18-4 0.50 I 01/07/19 15:58 95-63-6 0.50 1 01/07/19 15:58 108-67-8 1.0 1 01/07/19 15:58 75-01-4 1.0 1 01/07/19 15:58 179601-23-1 0.50 1 01/07/19 15:58 95-47-6 70-130 1 01/07/19 15:58 17060-07-0 70-130 1 01/07/19 15:58 460-00-4 70-130 1 01/07/19 15:58 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 9 of 36 aceAnalytical / www.pacelabs com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-13 Lab ID: 92412854004 Collected: 01/03/19 12:00 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/04/19 19:23 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 19:23 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 19:23 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 19:23 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 19:23 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 19:23 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 19:23 104-51-8 sec -Butyl benzene ND ug/L 0,50 1 01/04/19 19:23 135-98-8 tert- Butyl benzene ND ug/L 0.50 1 01/04/19 19:23 98-06-6 Carbon tetrachloride ND ug/L 0.50 i 01/04/19 19:23 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 19:23 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 19:23 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 19:23 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 19:23 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:23 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:23 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 i 01/04/19 19:23 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 19:23 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 19:23 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 19:23 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:23 95-50-1 1,3-Dichlorobenzene ND ug/L 0,50 1 01/04/19 19:23 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:23 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 19:23 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 19:23 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 19:23 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 19:23 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:23 156-59-2 trans- 1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:23 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:23 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 19:23 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:23 594-20-7 1,1-Dichloropropene ND ug/L 0,50 1 01/04/19 19:23 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:23 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:23 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 01/04/19 19:23 108-20-3 Ethylbenzene ND ug/L 0.50 1 01104/1919:23 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 19:23 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 19:23 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 19:23 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 01/04/19 19:23 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 19:23 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 19:23 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 19:23 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:23 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:23 79-34-5 Tetrachloroethene ND ug/L 0.50 1 01/04/19 19:23 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01 /08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 36 _ aceAnalytical —pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-13 Lab ID: 92412854004 Collected: 01/03/19 12:00 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L NO ug/L 101 % 99 % 103 % 0.50 1 01/04/19 19:23 108-88-3 2.0 1 01/04/19 19:23 87-61-6 2.0 1 01/04/19 19:23 120-82-1 0.50 1 01/04/19 19:23 71-55-6 0.50 1 01/04/19 19:23 79-00-5 0.50 1 01/04/19 19:23 79-01-6 1.0 1 01/04/19 19:23 75-69-4 0.50 1 01/04/19 19:23 96-18-4 0.50 1 01/04/19 19:23 95-63-6 0.50 1 01/04/19 19:23 108-67-8 1.0 1 01/04/19 19:23 75-01-4 1.0 1 01/04/19 19:23 179601-23-1 0.50 1 01/04/19 19:23 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/04/19 19:23 17060-07-0 01/04/19 19:23 460-00-4 01/04/19 19:23 2037-26-5 Page 11 of 36 laceAnalXicalo www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-14 Lab ID: 92412854005 Collected: 01/03/19 12:30 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/04/19 19:39 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 19:39 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 19:39 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 19:39 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 19:39 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 19:39 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 19:39 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/04/19 19:39 135-98-8 tent-Butylbenzene ND ug/L 0.50 1 01/04/19 19:39 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 19:39 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 19:39 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 19:39 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 19:39 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 19:39 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/0411919:39 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:39 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 19:39 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 19:39 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 19:39 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 19:39 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:39 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:39 541-73-1 1,4-Dichlorobenzene ND ug/L 0,50 1 01/04/19 19:39 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 19:39 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 19:39 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 19:39 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 19:39 75-35-4 cis- 1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:39 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:39 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:39 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 19:39 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:39 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 19:39 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:39 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:39 10061-02-6 Diisopropyl ether 2.8 ug/L 0.50 1 01/04/19 19:39 108-20-3 Ethylbenzene ND ug/L 0.50 1 01/04/19 19:39 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 19:39 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 19:39 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 19:39 75-09-2 Methyl -tent -butyl ether 3.9 ug/L 0.50 1 01/04/19 19:39. 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 19:39 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 19:39 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 19:39 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:39 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:39 79-34-5 Tetra chloroethene ND ug/L 0.50 1 01/04/19 19:39 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC Page 12 of 36 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-14 Lab ID: 92412854005 Collected: 01/03/19 12:30 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroetha ne 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 97 % 97 % 100 % 0.50 1 01/04/19 19:39 108-88-3 2.0 1 01/04/19 19:39 87-61-6 2.0 1 01/04/19 19:39 120-82-1 0.50 1 01/04/19 19:39 71-55-6 0.50 1 01/04/19 19:39 79-00-5 0.50 1 01/04/19 19:39 79-01-6 110 1 01/04/19 19:39 75-69-4 0.50 1 01/04/19 19:39 96-18-4 0.50 1 01/04/19 19:39 95-63-6 0.50 1 01/04/19 19:39 108-67-8 1.0 1 01/04/19 19:39 75-01-4 1.0 1 01/04/19 19:39 179601-23-1 0.50 1 01/04/19 19:39 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/04/19 19:39 17060-07-0 01/04/19 19:39 460-00-4 01/04/19 19:39 2037-26-5 Page 13 of 36 aceAnalytical xnYlY.ppppla5s-cam I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No. 92412854 Sample: MW-15 Lab ID: 92412854006 Collected: 01/03/19 12:40 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/04/19 19:55 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 19:55 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 19:55 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 19:55 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 19:55 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 19:55 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 19:55 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/04/19 19:55 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 01/04/19 19:55 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 19:55 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 19:55 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 19:55 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 19:55 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 19:55 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:55 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 19:55 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 19:55 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 19:55 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 19:55 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 19:55 74-95-3 1.2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:55 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:55 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 19:55 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 19:55 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 19:55 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 19:55 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 19:55 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:55 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 19:55 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:55 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 19:55 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 19:55 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 19:55 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:55 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 19:55 10061-02-6 Diisopropyl ether 1.1 ug/L 0.50 1 01/04/19 19:55 108-20-3 Ethylbenzene ND ug/L 0.50 1 01/04/19 19:55 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 19:55 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 19:55 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 19:55 75-09-2 Methyl-tert-butyl ether 3.7 ug/L 0.50 1 01/04/19 19:55 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 19:55 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 19:55 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 19:55 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 19:55 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 050 1 01/04/19 19:55 79-34-5 Tetra chloroethene ND ug/L 0.50 1 01/04/19 19:55 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC, Page 14 of 36 _ ace Analytical —pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.. 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-15 Lab ID: 92412854006 Collected: 01/03/19 12:40 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 101 % 97 % 102 % 0.50 1 01 /04/19 19:55 108-88-3 2.0 1 01 /04119 19:55 87-61-6 2.0 1 01 /04/19 19:55 120-82-1 0.50 1 01/04/1919:55 71-55-6 0.50 1 01/04/1919:55 79-00-5 0.50 1 01/04/1919:55 79-01-6 1,0 1 01/04/1919:55 75-69-4 0.50 1 01/04/1919:55 96-18-4 0.50 1 01/04/1919:55 95-63-6 0.50 1 01 /04/19 19:55 108-67-8 1.0 1 01/04/1919:55 75-01-4 1.0 1 01 /04/19 19:55 179601-23-1 0.50 1 01/04/1919:55 95-47-6 70-130 1 01 /04/19 19:55 17060-07-0 70-130 1 01/04/1919:55 460-00-4 70-130 1 01/04/1919:55 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in Full, without the written consent of Pace Analytical Services, LLC. Page 15 of 36 (� aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-16 Lab ID: 92412854007 Collected: 01/03/19 13:10 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene 560 ug/L 2.0 4 01/07/19 16:30 71-43-2 Bromobenzene ND ug/L 2,0 4 01/07/19 16:30 108-86-1 Bromochloromethane ND ug/L 2.0 4 01/07/19 16:30 74-97-5 Bromodichloromethane ND ug/L 2.0 4 01/07/19 16:30 75-27-4 Bromoform ND ug/L 2.0 4 01/07/19 16:30 75-25-2 Bromomethane ND ug/L 20.0 4 01/07/19 16:30 74-83-9 n-Butylbenzene ND ug/L 2.0 4 01/07/19 16:30 104-51-8 sec-Butylbenzene ND ug/L 2.0 4 01/07/19 16:30 135-98-8 tert- Butyl benzene ND ug/L 2.0 4 01/07/19 16:30 98-06-6 Carbon tetrachloride ND ug/L 2.0 4 01/07/19 16:30 56-23-5 Chlorobenzene ND ug/L 2.0 4 01/07/19 16:30 108-90-7 Chloroethane ND ug/L 4.0 4 01/07/19 16:30 75-00-3 Chloroform ND ug/L 2.0 4 01/07/19 16:30 67-66-3 Chloromethane ND ug/L 4.0 4 01/07/19 16:30 74-87-3 2-Chlorotoluene ND ug/L 2.0 4 01/07/19 16:30 95-49-8 4-Chlorotoluene ND ug/L 2.0 4 01/07/19 16:30 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 4.0 4 01/07/19 16:30 96-12-8 Dibromochloromethane ND ug/L 2.0 4 01/0711916:30 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 2.0 4 01/07/19 16:30 106-93-4 Dibromomethane ND ug/L 2.0 4 01/07/19 16:30 74-95-3 1,2-Dichlorobe nzene ND ug/L 2.0 4 01/07/19 16:30 95-50-1 1,3-Dichlorobenzene ND ug/L 2.0 4 01/07/19 16:30 541-73-1 1,4-Dichlorobenzene ND ug/L 2.0 4 01/07/19 16:30 106-46-7 Dichlorodifluoromethane ND ug/L 2.0 4 01/07/19 16:30 75-71-8 1,1-Dichloroethane ND ug/L 2.0 4 01/07/19 16:30 75-34-3 1,2-Dichloroethane ND ug/L 2.0 4 01/07/19 16:30 107-06-2 1,1-Dichloroethene ND ug/L 2.0 4 01/07/19 16:30 75-35-4 cis-1,2-Dichloroethene ND ug/L 2.0 4 01/07/19 16:30 156-59-2 trans-1,2-Dichloroethene ND ug/L 2.0 4 01/07/19 16:30 156-60-5 1,2-Dichloropropane ND ug/L 2.0 4 01/07/19 16:30 78-87-5 1,3-Dichloropropane ND ug/L 2.0 4 01/07/19 16:30 142-28-9 2,2-Dichloropropane ND ug/L 2.0 4 01/07/19 16:30 594-20-7 1,1-Dichloropropene ND ug/L 2.0 4 01/07/19 16:30 563-58-6 cis-1,3-Dichloropropene ND ug/L 2.0 4 01/07/19 16:30 10061-01-5 trans-1,3-Dichloropropene ND ug/L 2.0 4 01/07/19 16:30 10061-02-6 Diisopropyl ether 104 ug/L 2.0 4 01/07/19 16:30 108-20-3 Ethylbenzene 8.7 ug/L 2.0 4 01/07/19 16:30 100-41-4 Hexachlorp-1,3-butadiene ND ug/L 8.0 4 01/07/19 16:30 87-68-3 Isopropylbenzene (Cumene) 2.3 ug/L 2.0 4 01/07/19 16:30 98-82-8 Methylene Chloride ND ug/L 8.0 4 01/07/19 16:30 75-09-2 Methyl-tert-butyl ether 45.7 ug/L 2.0 4 01/07/19 16:30 1634-04-4 Naphthalene 12.3 ug/L 8.0 4 01/07/19 16:30 91-20-3 n-Propylbenzene 2.7 ug/L 2.0 4 01/07/19 16:30 103-65-1 Styrene ND ug/L 2.0 4 01/07/19 16:30 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 2.0 4 01/07/19 16:30 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 2.0 4 01/07/19 16:30 79-34-5 Tetrachloroethene ND ug/L 2.0 4 01/07/19 16:30 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 16 of 36 aceAnalytical " rwwr.pa0s1.7b8x= ANALYTICAL RESULTS Pace Analytical Services, LLC 9B00 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-16 Lab ID: 92412854007 Collected: 01/03/19 13:10 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene 5.3 ug/L 2.0 4 01/07/19 16:30 108-88-3 1,2,3-Trichlorobenzene ND ug/L 8.0 4 01/07/19 16:30 87-61-6 1,2,4-Trichlorobenzene ND ug/L 8.0 4 01/07/19 16:30 120-82-1 1,1,1-Trichloroethane ND ug/L 2.0 4 01/07/19 16:30 71-55-6 1,1,2-Trichloroethane ND ug/L 2.0 4 01/07/19 16:30 79-00-5 Trichloroethene ND ug/L 2.0 4 01/07/19 16:30 79-01-6 Trichlorofluoromethane ND ug/L 4.0 4 01/07/19 16:30 75-69-4 1,2,3-Trichloropropane ND ug/L 2.0 4 01/07/19 16:30 96-18-4 1,2,4-Trimethylbenzene ND ug/L 2.0 4 01/07/19 16:30 95-63-6 1,3,5-Trimethylbenzene ND ug/L 2.0 4 01/07/19 16:30 108-67-8 Vinyl chloride ND ug/L 4.0 4 01/07/19 16:30 75-01-4 m&p-Xylene ND ug/L 4.0 4 01107/1916:30 179601-23-1 o-Xylene ND ug/L 2.0 4 01/07/19 16:30 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 105 % 70-130 4 01/07/19 16:30 17060-07-0 4-Bromofluorobenzene (S) 97 % 70-130 4 01/07/19 16:30 460-00-4 Toluene-d8 (S) 101 % 70-130 4 01/07/19 16:30 2037-26-5 Date: 01/08/2019 12:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 17 of 36 aceAnalytical www.pacelabs.com I ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: MW-17 Lab ID: 92412854008 Collected: 01/03/19 12:10 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units. Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene 6.0 ug/L 0.50 1 01/04/19 20:11 71-43-2 Bromobenzene ND ug/L 0.50 1 01/04/19 20:11 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 20:11 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 20:11 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 20:11 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 20:11 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 20:11 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/04/19 20:11 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 01/04/19 20:11 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 20:11 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 20:11 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 20:11 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 20:11 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 20:11 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/04/19 20:11 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 01/04/19 20:11 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 20:11 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 20:11 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 20:11 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 20:11 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 20:11 95-50-1 1,3-Dichlorobe nzene ND ug/L 0.50 1 01/04/19 20:11 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 20:11 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 20:11 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 20:11 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 20:11 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 20:11 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 20:11 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 20:11 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 20:11 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 20:11 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 20:11 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 20:11 563-58-6 cis-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 20:11 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 20:11 10061-02-6 Diisopropyl ether 12.0 ug/L 0.50 1 01/04/19 20:11 108-20-3 Ethylbenzene ND ug/L 0,50 1 01/04/19 20:11 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 20:11 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 20:11 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 20:11 75-09-2 Methyl-tert-butyl ether 2.7 ug/L 0.50 1 01/04/19 20:11 1634-04-4 Naphthalene ND ug/L 2.0 1 01/04/19 20:11 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 20:11 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 20:11 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 20:11 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 20:11 79-34-5 Tetrachloroethene ND ug/L 0.50 1 01/04/19 20:11 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 18 of 36 aceAnalytrcal —pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-17 Lab ID: 92412854008 Collected: 01/03/19 12:10 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroetha ne 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3, 5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 100 % 98 % 104 % 0.50 1 01/04/19 20:11 108-88-3 2.0 1 01/04/19 20:11 87-61-6 2.0 1 01/04/19 20:11 120-82-1 0.50 1 01/04/19 20:11 71-55-6 0.50 1 01/04/19 20:11 79-00-5 0.50 1 01/04/19 20:11 79-01-6 1.0 1 01/04/19 20:11 75-69-4 0.50 1 01/04/19 20:11 96-18-4 0.50 1 01/04/19 20:11 95-63-6 0.50 1 01/04/19 20:11 108-67-8 1.0 1 01/04/19 20:11 75-01-4 1.0 1 01/04/19 20:11 179601-23-1 0.50 1 01/04/19 20:11 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/04/19 20:11 17060-07-0 01/04/19 20:11 460-00-4 01/04/19 20:11 2037-26-5 Page 19 of 36 _ . aceAnalytical j www.pacelabs.com i f I ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: TW-2 Lab ID: 92412854009 Collected: 01/03/19 12:48 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Benzene Bromobenzene Bromochloromethane Bromodichloromethane Bromoform Bromomethane n-Butylbenzene sec-Butylbenzene tert-Butylbenzene Carbon tetrachloride Chlorobenzene Chloroethane Chloroform Chloromethane 2-Chlorotoluene 4-Chlorotoluene 1,2-Dibromo-3-chloropropane Dibromochloromethane 1,2-Dibromoethane (EDB) Dibromomethane 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Dichlorodifluoromethane 1,1-Dichloroethane 1,2-Dichloroethane 1,1-Dichloroethene cis-1,2-Dichloroethene trans-1,2-Dichloroethene 1,2-Dichloropropane 1,3-Dichloropropane 2,2-Dichloropropane 1,1-Dichloropropene cis-1,3-Dichloropropene trans-1,3-Dichloropropene Diisopropyl ether Ethylbenzene Hexachloro-1,3-butadiene Isopropylbenzene (Cumene) Methylene Chloride Methyl-tert-butyl ether Naphthalene n-Propylbenzene Styrene 1,1,1,2-Tetrachloroethane 1,1,2,2-Tetrachloroethane Tetra chi oroethene Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 0.50 0.50 0.50 0.50 0.50 5.0 0.50 0.50 0.50 0,50 0.50 10 0.50 1.0 0.50 0.50 1.0 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0,50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 2.0 0.50 2.0 0.50 2.0 0.50 0.50 0.50 0.50 0.50 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 f 1 1 1 1 1 1 1 1 3 1 1 1 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/04/19 20:27 71-43-2 01/04/19 20:27 108-86-1 01/04/19 20:27 74-97-5 01/04/19 20:27 75-27-4 01/04/19 20:27 75-25-2 01/04/19 20:27 74-83-9 01/04/19 20:27 104-51-8 01/04/19 20:27 135-98-8 01/04/19 20:27 98-06-6 01/04/19 20:27 56-23-5 01/04/19 20:27 108-90-7 01/04/19 20:27 75-00-3 01/04/19 20:27 67-66-3 01/04/19 20:27 74-87-3 01/04/19 20:27 95-49-8 01/04/19 20:27 106-43-4 01/04/19 20:27 96-12-8 01/04/19 20:27 124-48-1 01/04/19 20:27 106-93-4 01/04/19 20:27 74-95-3 01/04/19 20:27 95-50-1 01/04/19 20:27 541-73-1 01/04/19 20:27 106-46-7 01/04/19 20:27 75-71-8 01/04/19 20:27 75-34-3 01/04/19 20:27 107-06-2 01/04/19 20:27 75-35-4 01/04/19 20:27 156-59-2 01/04/19 20:27 156-60-5 01/04/19 20:27 78-87-5 01/04/19 20:27 142-28-9 01/04/19 20:27 594-20-7 01/04/19 20:27 563-58-6 01/04/19 20:27 10061-01-5 01/04/19 20:27 10061-02-6 01/04/19 20:27 108-20-3 01/04/19 20:27 100-41-4 01/04/19 20:27 87-68-3 01/04/19 20:27 98-82-8 01/04/19 20:27 75-09-2 01/04/19 20:27 1634-04-4 01/04/19 20:27 91-20-3 01/04/19 20:27 103-65-1 01/04/19 20:27 100-42-5 01/04/19 20:27 630-20-6 01/04/19 20:27 79-34-5 01/04/19 20:27 127-18-4 Page 20 of 36 aceAnalytical www.pacelabs.com ANALYTICAL RESULTS Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: TW-2 Lab ID: 92412854009 Collected: 01/03/19 12:48 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Toluene 1,2,3-Trichlorobenzene 1,2,4-Trichlorobenzene 1,1,1-Trichloroethane 1,1,2-Trichloroethane Trichloroethene Trichlorofluoromethane 1,2,3-Trichloropropane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene Vinyl chloride m&p-Xylene o-Xylene Surrogates 1,2-Dichloroethane-d4 (S) 4-Bromofluorobenzene (S) Toluene-d8 (S) Date: 01/08/2019 12:47 PM Analytical Method: SM 6200B ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L ND ug/L 99 % 99 % 103 % 0.50 1 01/04/19 20:27 108-88-3 2.0 1 01/04/19 20:27 87-61-6 2.0 1 01/04/19 20:27 120-82-1 0.50 1 01/04/19 20:27 71-55-6 0.50 1 01/04/19 20:27 79-00-5 0.50 1 01/04/19 20:27 79-01-6 1.0 1 01 /04119 20:27 75-69-4 0.50 1 01/04/19 20:27 96-18-4 0.50 1 01/04/19 20:27 95-63-6 0.50 1 01/04/19 20:27 108-67-8 1.0 1 01/04/19 20:27 75-01-4 1.0 1 01/04/19 20:27 179601-23-1 0.50 1 01/04/19 20:27 95-47-6 70-130 1 70-130 1 70-130 1 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. 01/04/19 20:27 17060-07-0 01/04/19 20:27 460-00-4 01/04/19 20:27 2037-26-5 Page 21 of 36 lacmnalyficalo www.pacejabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: TRIP BLANK Lab ID: 92412854010 Collected: 01/03/19 00:00 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Benzene ND ug/L 0.50 1 01/04/19 18:34 71-43-2 Bromobenzene ND ug/L 0.50 I 01/04/19 18:34 108-86-1 Bromochloromethane ND ug/L 0.50 1 01/04/19 18:34 74-97-5 Bromodichloromethane ND ug/L 0.50 1 01/04/19 18:34 75-27-4 Bromoform ND ug/L 0.50 1 01/04/19 18:34 75-25-2 Bromomethane ND ug/L 5.0 1 01/04/19 18:34 74-83-9 n-Butylbenzene ND ug/L 0.50 1 01/04/19 18:34 104-51-8 sec-Butylbenzene ND ug/L 0.50 1 01/04/19 18:34 135-98-8 tert-Butylbenzene ND ug/L 0.50 1 01/04/19 18:34 98-06-6 Carbon tetrachloride ND ug/L 0.50 1 01/04/19 18:34 56-23-5 Chlorobenzene ND ug/L 0.50 1 01/04/19 18:34 108-90-7 Chloroethane ND ug/L 1.0 1 01/04/19 18:34 75-00-3 Chloroform ND ug/L 0.50 1 01/04/19 18:34 67-66-3 Chloromethane ND ug/L 1.0 1 01/04/19 18:34 74-87-3 2-Chlorotoluene ND ug/L 0.50 1 01/04/19 18:34 95-49-8 4-Chlorotoluene ND ug/L 0.50 1 0110411918:34 106-43-4 1,2-Dibromo-3-chloropropane ND ug/L 1.0 1 01/04/19 18:34 96-12-8 Dibromochloromethane ND ug/L 0.50 1 01/04/19 18:34 124-48-1 1,2-Dibromoethane (EDB) ND ug/L 0.50 1 01/04/19 18:34 106-93-4 Dibromomethane ND ug/L 0.50 1 01/04/19 18:34 74-95-3 1,2-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:34 95-50-1 1,3-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:34 541-73-1 1,4-Dichlorobenzene ND ug/L 0.50 1 01/04/19 18:34 106-46-7 Dichlorodifluoromethane ND ug/L 0.50 1 01/04/19 18:34 75-71-8 1,1-Dichloroethane ND ug/L 0.50 1 01/04/19 18:34 75-34-3 1,2-Dichloroethane ND ug/L 0.50 1 01/04/19 18:34 107-06-2 1,1-Dichloroethene ND ug/L 0.50 1 01/04/19 18:34 75-35-4 cis-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 18:34 156-59-2 trans-1,2-Dichloroethene ND ug/L 0.50 1 01/04/19 18:34 156-60-5 1,2-Dichloropropane ND ug/L 0.50 1 01/04/19 18:34 78-87-5 1,3-Dichloropropane ND ug/L 0.50 1 01/04/19 18:34 142-28-9 2,2-Dichloropropane ND ug/L 0.50 1 01/04/19 18:34 594-20-7 1,1-Dichloropropene ND ug/L 0.50 1 01/04/19 18:34 563-58-6 cis- 1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 18:34 10061-01-5 trans-1,3-Dichloropropene ND ug/L 0.50 1 01/04/19 18:34 10061-02-6 Diisopropyl ether ND ug/L 0.50 1 01/04/19 18:34 108-20-3 Ethylbenzene ND ug/L 0.50 1 01/04/19 18:34 100-41-4 Hexachloro-1,3-butadiene ND ug/L 2.0 1 01/04/19 18:34 87-68-3 Isopropylbenzene (Cumene) ND ug/L 0.50 1 01/04/19 18:34 98-82-8 Methylene Chloride ND ug/L 2.0 1 01/04/19 18:34 75-09-2 Methyl-tert-butyl ether ND ug/L 0.50 1 01/04/19 18:34 1634-04-4 Naphthalene ND ug/L 2,0 1 01/04/19 18:34 91-20-3 n-Propylbenzene ND ug/L 0.50 1 01/04/19 18:34 103-65-1 Styrene ND ug/L 0.50 1 01/04/19 18:34 100-42-5 1,1,1,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 18:34 630-20-6 1,1,2,2-Tetrachloroethane ND ug/L 0.50 1 01/04/19 18:34 79-34-5 Tetra chi oroethene ND ug/L 0.50 1 01/04/19 18:34 127-18-4 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC, Page 22 of 36 ace Analytical —pacelabs.com ANALYTICAL RESULTS Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 Sample: TRIP BLANK Lab ID: 92412854010 Collected: 01/03/19 00:00 Received: 01/04/19 12:33 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 6200B MSV Analytical Method: SM 6200B Toluene ND ug/L 0.50 1 01/04/19 18:34 108-88-3 1,2,3-Trichlorobenzene ND ug/L 2.0 1 01/04/19 18:34 87-61-6 1,2,4-Trichlorobenzene ND ug/L 2.0 1 01/04/19 18:34 120-82-1 1,1,1-Trichloroethane ND ug/L 0.50 1 01/04/19 18:34 71-55-6 1,1,2-Trichloroethane ND ug/L 0.50 1 01/04/19 18:34 79-00-5 Trichloroethene ND ug/L 0.50 1 01/04/19 18:34 79-01-6 Trichlorofluoromethane ND ug/L 10 1 01/04/19 18:34 75-69-4 1,2,3-Trichloropropane ND ug/L 0.50 l 01/04/19 18:34 96-18-4 1,2,4-Trimethylbenzene ND ug/L 0.50 l 01/04/19 18:34 95-63-6 1,3,5-Trimethylbenzene ND ug/L 0.50 1 01/04/19 18:34 108-67-8 Vinyl chloride ND ug/L 1.0 1 01/04/19 18:34 75-01-4 m&p-Xylene ND ug/L 1.0 1 01/04/19 18:34 179601-23-1 o-Xylene ND ug/L 0.50 1 01/04/19 18:34 95-47-6 Surrogates 1,2-Dichloroethane-d4 (S) 96 % 70-130 1 01/04/19 18:34 17060-07-0 4-Bromofluorobenzene (S) 97 % 70-130 1 01/04/19 18:34 460-00-4 Toluene-d8 (S) 101 % 70-130 1 01/04/19 18:34 2037-26-5 Date: 01/08/2019 12:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 23 of 36 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No . 92412854 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 QC Batch: 450895 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200E MSV Associated Lab Samples: 92412854001, 92412854002, 92412854004, 92412854005, 92412854006, 92412854008, 92412854009, 92412854010 METHOD BLANK: 2466636 Matrix: Water Associated Lab Samples: 92412854001, 92412854002, 92412854004, 92412854005, 92412854006, 92412854008, 92412854009, 92412854010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers 1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/04/19 18:18 1,1,1-Trichloroethane ug/L ND 0.50 01/04/19 18:18 1,1,2,2-Tetrachloroethane ug/L ND 0.50 01/04/19 18:18 1,1,2-Trichloroethane ug/L ND 0.50 01/04/19 18:18 1,1-Dichloroethane ug/L ND 0.50 01/04/19 18:18 1,1-Dichloroethene ug/L ND 0.50 01/04/19 18:18 1,1-Dichloropropene ug/L ND 0.50 01/04/19 18:18 1,2,3-Trichlorobenzene ug/L ND 2.0 01/04/19 18:18 1,2,3-Trichloropropane ug/L ND 0.50 01/04/19 18:18 1,2,4-Trichlorobenzene ug/L ND 2.0 01/04/19 18:18 1,2,4-Trimethylbenzene ug/L ND 0.50 01/04/19 18:18 1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/04/19 18:18 1,2-Dibromoethane (EDB) ug/L ND 0.50 01/04/19 18:18 1,2-Dichlorobenzene ug/L ND 0.50 01/04/19 18:18 1,2-Dichloroethane ug/L ND 0.50 01/04/19 18:18 1,2-Dichloropropane ug/L ND 0.50 01/04/19 18:18 1,3,5-Trimethylbenzene ug/L ND 0.50 01/04/19 18:18 1,3-Dichlorobenzene ug/L ND 0.50 01/04/19 18:18 1,3-Dichloropropane ug/L ND 0.50 01/04/19 18:18 1,4-Dichlorobenzene ug/L ND 0.50 01/04/19 18:18 2,2-Dichloropropane ug/L ND 0.50 01/04/19 18:18 2-Chlorotoluene ug/L ND 0.50 01/04/19 18:18 4-Chlorotoluene ug/L ND 0.50 01/04/19 18:18 Benzene ug/L ND 0.50 01/04/19 18:18 Bromobenzene ug/L ND 0.50 01/04/19 18:18 Bromochloromethane ug/L ND 0.50 01/04/19 18:18 Bromodichloromethane ug/L ND 0.50 01/04/19 18:18 Bromoform ug/L ND 0.50 01/04/19 18:18 Bromomethane ug/L ND 5.0 01/04/19 18:18 Carbon tetrachloride ug/L ND 0.50 01/04/19 18:18 Chlorobenzene ug/L ND 0.50 01/04/19 18:18 Chloroethane ug/L ND 1.0 01/04/19 18:18 Chloroform ug/L ND 0.50 01/04/19 18:18 Chloromethane ug/L ND 1.0 01/04/19 18:18 cis-1,2-Dichloroethene ug/L ND 0.50 01/04/19 18:18 cis-1,3-Dichloropropene ug/L ND 0.50 01/04/19 18:18 Dibromochloromethane ug/L ND 0.50 01/04/19 18:18 Dibromomethane ug/L ND 0.50 01/04/19 18:18 Dichlorodifluoromethane ug/L ND 0.50 01/04/19 18:18 Diisopropyl ether ug/L ND 0.50 01/04/19 18:18 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC, Page 24 of 36 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 METHOD BLANK: 2466636 Matrix: Water Associated Lab Samples: 92412854001, 92412854002, 92412854004, 92412854005, 92412854006, 92412854008, 92412854009, 92412854010 Blank Reporting Parameter Units Result Limit Analyzed Qualifiers Ethylbenzene ug/L ND 0.50 01/04/19 18:18 Hexachloro-1,3-butadiene ug/L ND 2.0 01/04/19 18:18 Isopropylbenzene (Cumene) ug/L ND 0.50 01/04/19 18:18 m&p-Xylene ug/L ND 1.0 01/04/19 18:18 Methyl-tert-butyl ether ug/L ND 0.50 01/04/19 18:18 Methylene Chloride ug/L ND 2.0 01/04/19 18:18 n-Butylbenzene ug/L ND 0.50 01/04/19 18:18 n-Propylbenzene ug/L ND 0.50 01/0411918:18 Naphthalene ug/L ND 2.0 01/0411918:18 o-Xylene ug/L ND 0.50 01/04/19 18:18 sec-Butylbenzene ug/L ND 0.50 01/04/19 18:18 Styrene ug/L ND 0.50 01/04/19 18:18 tert-Butylbenzene ug/L ND 0.50 01/04/19 18:18 Tetra chloroethene ug/L ND 0.50 01/04/19 18:18 Toluene ug/L ND 0.50 01/04/19 18:18 trans-1,2-Dichloroethene ug/L ND 0.50 01/04/19 18:18 trans-1,3-Dichloropropene ug/L ND 0.50 01/04/19 18:18 Trichloroethene ug/L ND 0,50 01/04/19 18:18 Trichlorofluoromethane ug/L ND 1.0 01/04/19 18:18 Vinyl chloride ug/L ND 1.0 01/04/19 18:18 1,2-Dichloroethane-d4 (S) % 102 70-130 01/04/19 18:18 4-Bromofluorobenzene (S) % 99 70-130 01/04/19 18:18 Toluene-d8 (S) % 103 70-130 01/04/19 18:18 LABORATORY CONTROL SAMPLE: Parameter 2466637 Units Spike Cone. LCS Result LCS % Rec % Rec Limits Qualifiers 1,1,1,2-Tetrachloroethane ug/L 50 51.1 102 60-140 1,1,1-Trichloroethane ug/L 50 46.4 93 60-140 1,1,2,2-Tetrachloroethane ug/L 50 50.3 101 60-140 1,1,2-Trichloroethane ug/L 50 50,3 101 60-140 1,1-Dichloroethane ug/L 50 50.6 101 60-140 1,1-Dichloroethene ug/L 50 47.5 95 60-140 1,1-Dichloropropene ug/L 50 43.6 87 60-140 1,2,3-Trichlorobenzene ug/L 50 55.2 110 60-140 1,2,3-Trichloropropane ug/L 50 51.2 102 60-140 1,2,4-Trichlorobenzene ug/L 50 53.8 108 60-140 1,2,4-Trimethylbenzene ug/L 50 48.3 97 60-140 1,2-Dibromo-3-chloropropane ug/L 50 53.5 107 60-140 1,2-Dibromoethane (EDB) ug/L 50 50.9 102 60-140 1,2-Dichlorobenzene ug/L 50 49.5 99 60-140 1,2-Dichloroethane ug/L 50 46.8 94 60-140 1,2-Dichloropropane ug/L 50 47.8 96 60-140 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 25 of 36 (�IaneAnalXicalo www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 LABORATORY CONTROL SAMPLE: Parameter 2466637 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,3,5-Trimethylbenzene ug/L 50 47.2 94 60-140 1,3-Dichlorobenzene ug/L 50 48.6 97 60-140 1,3-Dichloropropane ug/L 50 50.3 101 60-140 1,4-Dichlorobenzene ug/L 50 47.1 94 60-140 2,2-Dichloropropane ug/L 50 54.7 109 60-140 2-Chlorotoluene ug/L 50 46.9 94 60-140 4-Chlorotoluene ug/L 50 48.0 96 60-140 Benzene ug/L 50 46.3 93 60-140 Bromobenzene ug/L 50 48.0 96 60-140 Bromochloromethane ug/L 50 50.0 100 60-140 Bromodichloromethane ug/L 50 48.8 98 60-140 Bromoform ug/L 50 49.8 100 60-140 Bromomethane ug/L 50 50.1 100 60-140 Carbon tetrachloride ug/L 50 51.0 102 60-140 Chlorobenzene ug/L 50 46.8 94 60-140 Chloroethane ug/L 50 36.9 74 60-140 Chloroform ug/L 50 48.1 96 60-140 Chloromethane ug/L 50 44.5 89 60-140 cis- 1,2-Dichloroethene ug/L 50 47.0 94 60-140 cis- 1,3-Dichloropropene ug/L 50 53.2 106 60-140 Dibromochloromethane ug/L 50 53.2 106 60-140 Dibromomethane ug/L 50 50.3 101 60-140 Dichlorodifluoromethane ug/L 50 39.1 78 60-140 Diisopropyl ether ug/L 50 47.0 94 60-140 Ethylbenzene ug/L 50 46.3 93 60-140 Hexachloro-1,3-butadiene ug/L 50 54.0 108 60-140 Isopropylbenzene (Cumene) ug/L 50 47.9 96 60-140 m&p-Xylene ug/L 100 93.2 93 60-140 Methyl-tert-butyl ether ug/L 50 48.5 97 60-140 Methylene Chloride ug/L 50 47.3 95 60-140 n-Butylbenzene ug/L 50 49.2 98 60-140 n-Propylbenzene ug/L 50 48.7 97 60-140 Naphthalene ug/L 50 54.3 109 60-140 o-Xylene ug/L 50 47.9 96 60-140 sec-Butylbenzene ug/L 50 49.2 98 60-140 Styrene ug/L 50 48.6 97 60-140 tert-Butylbenzene ug/L 50 41.5 83 60-140 Tetrachloroethene ug/L 50 45.3 91 60-140 Toluene ug/L 50 45.3 91 60-140 trans-1,2-Dichloroethene ug/L 50 50.0 100 60-140 trans-1,3-Dichloropropene ug/L 50 54.5 109 60-140 Trichloroethene ug/L 50 44.8 90 60-140 Trichlorofluoromethane ug/L 50 46.2 92 60-140 Vinyl chloride ug/L 50 50.5 101 60-140 1,2-Dichloroethane-d4 (S) % 100 70-130 4-Bromofluorobenzene (S) % 98 70-130 Toluene-d8 (S) % 98 70-130 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 26078 (704)875-9092 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full. Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 26 of 36 laceAnalXicaf' www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 KinceyAve, Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2466638 2466639 MS MSD 92412854004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD 1,1,1,2-Tetrachloroethane ug/L i ND 20 20 21.7 22.2 109 111 60-140 2 1,1,1-Trichloroethane ug/L ND 20 20 21.6 22.0 108 110 60-140 2 1,1,2,2-Tetrachloroethane ug/L ND 20 20 20.9 21.0 104 105 60-140 0 1,1,2-Trichloroethane ug/L ND 20 20 21.5 21.0 107 105 60-140 2 1,1-Dichloroethane ug/L ND 20 20 22.3 23.0 111 115 60-140 3 1,1-Dichloroethene ug/L ND 20 20 22.5 23.1 112 116 60-140 3 1,1-Dichloropropene ug/L ND 20 20 20.3 20.3 102 101 60-140 0 1,2,3-Trichlorobenzene ug/L ND 20 20 22.3 22.0 111 110 60-140 1 1,2,3-Trichloropropane ug/L ND 20 20 21.2 21.2 106 106 60-140 0 1,2,4-Trichlorobenzene ug/L ND 20 20 21.6 21.2 108 106 60-140 2 1,2,4-Trimethylbenzene ug/L ND 20 20 20.2 20.1 101 100 60-140 1 1,2-Dibromo-3-chloropropane ug/L ND 20 20 20.4 20.8 102 104 60-140 2 1,2-Dibromoethane (EDB) ug/L ND 20 20 21.1 21.6 105 108 60-140 3 1,2-Dichlorobenzene ug/L ND 20 20 20.5 20.6 103 103 60-140 0 1,2-Dichloroethane ug/L ND 20 20 19,9 20.4 100 102 60-140 2 1,2-Dichloropropane ug/L ND 20 20 21.1 21.0 105 105 60-140 1 1,3,5-Trimethylbenzene ug/L ND 20 20 20.0 19.9 100 100 60-140 0 1,3-Dichlorobenzene ug/L ND 20 20 20.1 20.3 101 102 60-140 1 1,3-Dichloropropane ug/L ND 20 20 21.1 20.8 105 104 60-140 1 1,4-Dichlorobenzene ug/L ND 20 20 19.6 19.9 98 99 60-140 1 2,2-Dichloropropane ug/L ND 20 20 24.2 25.0 121 125 60-140 3 2-Chlorotoluene ug/L ND 20 20 20,2 20.1 101 100 60-140 1 4-Chlorotoluene ug/L ND 20 20 19.7 20.0 99 100 60-140 2 Benzene ug/L ND 20 20 21.7 21.5 108 108 60-140 1 Bromobenzene ug/L ND 20 20 20.4 20.4 102 102 60-140 0 Bromochloromethane ug/L ND 20 20 21.9 22.1 109 110 60-140 1 Bromodichloromethane ug/L ND 20 20 21.1 20.4 105 102 60-140 3 Bromoform ug/L ND 20 20 20.3 21.0 101 105 60-140 3 Bromomethane ug/L ND 20 20 23,3 23,4 117 117 60-140 0 Carbon tetrachloride ug/L ND 20 20 24.0 24.2 120 121 60-140 1 Chlorobenzene ug/L ND 20 20 20.4 20.6 102 103 60-140 1 Chloroethane ug/L ND 20 20 24.5 23.3 123 117 60-140 5 Chloroform ug/L ND 20 20 21.2 21.2 106 106 60-140 0 Chloromethane ug/L ND 20 20 22.6 23.0 113 115 .60-140 2 cis-1,2-Dichloroethene ug/L ND 20 20 20.8 21.3 104 106 60-140 2 cis- 1,3-Dichloropropene ug/L ND 20 20 23.0 22.6 115 113 60-140 2 Dibromochloromethane ug/L ND 20 20 22.3 21.7 111 108 60-140 3 Dibromomethane ug/L ND 20 20 22.1 21.5 110 108 60-140 2 Dichlorodifluoromethane ug/L ND 20 20 20.9 21.1 104 105 60-140 1 Diisopropyl ether ug/L ND 20 20 20.2 20.5 101 103 60-140 1 Ethylbenzene ug/L ND 20 20 20.5 20.8 102 104 60-140 1 Hexachloro-1,3-butadiene ug/L ND 20 20 24.1 22.3 120 112 60-140 8 Isopropylbenzene (Cumene) ug/L ND 20 20 21.1 21.2 106 106 60-140 0 m&p-Xylene ug/L ND 40 40 41.8 41.5 105 104 60-140 1 Methyl-tert-butyl ether ug/L ND 20 20 21.3 21.5 107 108 60-140 1 Methylene Chloride ug/L ND 20 20 19.5 19.9 98 100 60-140 2 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS Qual This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 27 of 36 aceAnalytica! www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: PIT STOP BP Pace Project No.: 92412854 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2466638 2466639 MS MSD 92412854004 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 20 20 21.2 20.7 106 103 60-140 2 n-Propylbenzene ug/L ND 20 20 20.9 21.0 104 105 60-140 1 Naphthalene ug/L ND 20 20 19.7 21.0 99 105 60-140 7 o-Xylene ug/L ND 20 20 21.0 20.5 105 103 60-140 3 sec -Butyl benzene ug/L ND 20 20 21.6 21.3 108 107 60-140 1 Styrene ug/L ND 20 20 21.0 21.0 105 105 60-140 0 tert-Butylbenzene ug/L ND 20 20 18.2 18.1 91 90 60-140 1 Tetra chloroethene ug/L ND 20 20 20.5 20.1 103 101 60-140 2 Toluene ug/L ND 20 20 20.5 20.3 102 102 60-140 1 trans- 1,2-Dichloroethene ug/L ND 20 20 22.5 22.9 113 114 60-140 2 trans- 1,3-Dichloropropene ug/L ND 20 20 22.5 22.2 113 111 60-140 2 Trichloroethene ug/L ND 20 20 20.8 20.2 104 101 60-140 3 Trichlorofluoromethane ug/L ND 20 20 24.4 24.9 122 125 60-140 2 Vinyl chloride ug/L ND 20 20 25.3 26.2 126 131 60-140 4 1,2-Dichloroethane-d4 (S) % 99 97 70-130 4-Bromofluorobenzene (S) % 101 99 70-130 Toluene-d8 (S) % 100 100 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 28 of 36 aceAnalj6cal® www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 QC Batch: 451065 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 6200B MSV Associated Lab Samples: 92412854003, 92412854007 METHOD BLANK: 2467189 Associated Lab Samples: 92412854003, 92412854007 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,1,1,2-Tetrachloroethane ug/L ND 0.50 01/07/19 13:33 1,1,1-Trichloroethane ug/L ND 0.50 01/07/19 13:33 1,1,2,2-Tetrachloroethane ug/L NO 0.50 01/07/19 13:33 1,1,2-Trichloroethane ug/L ND 0.50 01/07/19 13:33 1,1-Dichloroethane ug/L ND 0.50 01/07/19 13:33 1,1-Dichloroethene ug/L ND 0.50 01/07/19 13:33 1,1-Dichloropropene ug/L ND 0.50 01/07/19 13:33 1,2,3-Trichlorobenzene ug/L ND 2.0 01/07/19 13:33 1,2,3-Trichloropropane ug/L ND 0.50 01/07/19 13:33 1,2,4-Trichlorobenzene ug/L ND 2.0 01/07/19 13:33 1,2,4-Trimethylbenzene ug/L ND 0.50 01/07/19 13:33 1,2-Dibromo-3-chloropropane ug/L ND 1.0 01/07/19 13:33 1,2-Dibromoethane (EDB) ug/L ND 0.50 01/07/19 13:33 1,2-Dichlorobenzene ug/L ND 0.50 01/07/19 13:33 1,2-Dichloroethane ug/L ND 0.50 01/07/19 13:33 1,2-Dichloropropane ug/L ND 0.50 01/07/19 13:33 1,3,5-Trimethylbenzene ug/L ND 0.50 01/07/19 13:33 1,3-Dichlorobenzene ug/L ND 0.50 01/07/19 13:33 1,3-Dichloropropane ug/L ND 0.50 01/07/19 13:33 1,4-Dichlorobenzene ug/L ND 0.50 01/07/19 13:33 2,2-Dichloropropane ug/L ND 0.50 01/07/19 13:33 2-Chlorotoluene ug/L ND 0.50 01/07/19 13:33 4-Chlorotoluene ug/L ND 0.50 01/07/19 13:33 Benzene ug/L ND 0.50 01/07/19 13:33 Bromobenzene ug/L ND 0,50 01/07/19 13:33 Bromochloromethane ug/L ND 0.50 01/07/19 13:33 Bromodichloromethane ug/L ND 0.50 01/07/19 13:33 Bromoform ug/L ND 0.50 01/07/19 13:33 Bromomethane ug/L ND 5.0 01/07/19 13:33 Carbon tetrachloride ug/L ND 0.50 01/07/19 13:33 Chlorobenzene ug/L ND 0.50 01/07/19 13:33 Chloroethane ug/L ND 1.0 01/07/19 13:33 Chloroform ug/L ND 0.50 01/07/19 13:33 Chloromethane ug/L ND 1.0 01/07/19 13:33 cis- 1,2-Dichloroethene ug/L ND 0.50 01/07/19 13:33 cis- 1,3-Dichloropropene ug/L ND 0.50 01/07/19 13:33 Dibromochloromethane ug/L ND 0.50 01/07/19 13:33 Dibromomethane ug/L ND 0.50 01/07/19 13:33 Dichlorodifluoromethane ug/L ND 0.50 01/07/19 13:33 Diisopropyl ether ug/L ND 0.50 01/07/19 13:33 Ethylbenzene ug/L ND 0.50 01/07/19 13:33 Qualifiers Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 29 of 36 aceAnalytical -pacela6s.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 METHOD BLANK: 2467189 Associated Lab Samples: 92412854003, 92412854007 Parameter Units Matrix: Blank Result Water Reporting Limit Analyzed Hexachloro-1,3-butadiene ug/L ND 2.0 01/07/19 13:33 Isopropylbenzene (Cumene) ug/L ND 0.50 01/07/19 13:33 m&p-Xylene ug/L ND 1.0 01/07/19 13:33 Methyl-tert-butyl ether ug/L ND 0.50 01/07/19 13:33 Methylene Chloride ug/L ND 2.0 01/07/19 13:33 n-Butylbenzene ug/L ND 0.50 01/07/19 13:33 n-Propylbenzene ug/L ND 0.50 01/07/19 13:33 Naphthalene ug/L ND 2.0 01/07/19 13:33 o-Xylene ug/L ND 0.50 01/07/19 13:33 sec-Butylbenzene ug/L ND 0.50 01/07/19 13:33 Styrene ug/L ND 0.50 01/07/19 13:33 tert-Butylbenzene ug/L ND 0.50 01/07/19 13:33 Tetrachloroethene ug/L ND 0.50 01/07/19 13:33 Toluene ug/L ND 0.50 01/07/19 13:33 trans-1,2-Dichloroethene ug/L ND 0.50 01/07/19 13:33 trans-1,3-Dichloropropene ug/L ND 0.50 01/07/19 13:33 Trichloroethene ug/L ND 0.50 01/07/19 13:33 Trichlorofluoromethane ug/L ND 1.0 01/07/19 13:33 Vinyl chloride ug/L ND 1.0 01/07/19 13:33 1,2-Dichloroethane-d4 (S) % 101 70-130 01/07/19 13:33 4-Bromofluorobenzene (S) % 94 70-130 01/07/19 13:33 Toluene-d8 (S) % 103 70-130 01/07/19 13:33 Qualifiers LABORATORY CONTROL SAMPLE: Parameter 2467190 Units Spike Conc. LCS Result LCS % Rec % Rec Limits 1,1,1,2-Tetrachloroethane ug/L 50 52.6 105 60-140 1,1,1-Trichloroethane ug/L 50 47.1 94 60-140 1,1,2,2-Tetrachloroethane ug/L 50 50.8 102 60-140 1,1,2-Trichloroethane ug/L 50 48.4 97 60-140 1,1-Dichloroethane ug/L 50 49.9 100 60-140 1,1-Dichloroethene ug/L 50 46.7 93 60-140 1,1-Dichloropropene ug/L 50 43.2 86 60-140 1,2,3-Trichlorobenzene ug/L 50 56.9 114 60-140 1,2,3-Trichloropropane ug/L 50 51.4 103 60-140 1,2,4-Trichlorobenzene ug/L 50 54.5 109 60-140 1,2,4-Trimethylbenzene ug/L 50 49.3 99 60-140 1,2-Dibromo-3-chloropropane ug/L 50 53.8 108 60-140 1,2-Dibromoethane (EDB) ug/L 50 52.9 106 60-140 1,2-Dichlorobenzene ug/L 50 49.9 100 60-140 1,2-Dichloroethane ug/L 50 46.8 94 60-140 1,2-Dichloropropane ug/L 50 47.5 95 60-140 1,3,5-Trimethylbenzene ug/L 50 474 95 60-140 1,3-Dichlorobenzene ug/L 50 49.5 99 60-140 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC, Page 30 of 36 _ aceAnalytical " -pacelabs.com I QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 LABORATORY CONTROL SAMPLE: 2467190 Parameter Units Spike Conc. LCS Result 1,3-Dichloropropane ug/L 50 50.8 1,4-Dichlorobenzene ug/L 50 48.6 2,2-Dichloropropane ug/L 50 54.3 2-Chlorotoluene ug/L 50 47.9 4-Chlorotoluene ug/L 50 47.7 Benzene ug/L 50 46.5 Bromobenzene ug/L 50 48.9 Bromochloromethane ug/L 50 49.6 Bromodichloromethane ug/L 50 48.7 Bromoform ug/L 50 52.5 Bromomethane ug/L 50 47.0 Carbon tetrachloride ug/L 50 52.0 Chlorobenzene ug/L 50 47.6 Chloroethane ug/L 50 42.1 Chloroform ug/L 50 48.1 Chloromethane ug/L 50 42.2 cis-1,2-Dichloroethene ug/L 50 46.0 cis- 1,3-Dichloropropene ug/L 50 52.8 Dibromochloromethane ug/L 50 54.6 Dibromomethane ug/L 50 50.4 Dichlorodifluoromethane ug/L 50 36.1 Diisopropyl ether ug/L 50 46.1 Ethylbenzene ug/L 50 47.2 Hexachloro-1,3-butadiene ug/L 50 54.2 Isopropylbenzene (Cumene) ug/L 50 48.9 m&p-Xylene ug/L 100 94.3 Methyl-tert-butyl ether ug/L 50 47.7 Methylene Chloride ug/L 50 46.3 n-Butylbenzene ug/L 50 49.5 n-Propylbenzene ug/L 50 48.7 Naphthalene ug/L 50 54.5 o-Xylene ug/L 50 48.8 sec-Butylbenzene ug/L 50 49.4 Styrene ug/L 50 50.3 tert-Butylbenzene ug/L 50 42.5 Tetra chloroethene ug/L 50 46.2 Toluene ug/L 50 45.6 trans-1,2-Dichloroethene ug/L 50 49.2 trans- 1,3-Dichloropropene ug/L 50 54.2 Trichloroethene ug/L 50 45.1 Trichlorofluoromethane ug/L 50 46.7 Vinyl chloride ug/L 50 49.3 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec % Rec Limits 102 60-140 97 60-140 109 60-140 96 60-140 95 60-140 93 60-140 98 60-140 99 60-140 97 60-140 105 60-140 94 60-140 104 60-140 95 60-140 84 60-140 96 60-140 84 60-140 92 60-140 106 60-140 109 60-140 101 60-140 72 60-140 92 60-140 94 60-140 108 60-140 98 60-140 94 60-140 95 60-140 93 60-140 99 60-140 97 60-140 109 60-140 98 60-140 99 60-140 101 60-140 85 60-140 92 60-140 91 60-140 98 60-140 108 60-140 90 60-140 93 60-140 99 60-140 99 70-130 98 70-130 99 70-130 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC, Page 31 of 36 aceAnalytical www.pacelabs com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467191 MS 92412854007 Spike Parameter Units Result Conc. MSD Spike Conc. 2467192 MS Result MSD Result MS % Rec MSD % Rec % Rec Limits RPD Qual 1.1,1,2-Tetrachloroethane ug/L ND 80 80 84.2 84.4 105 106 60-140 0 1,1,1-Trichloroethane ug/L ND 80 80 86.4 86.1 108 108 60-140 0 1,1,2,2-Tetrachloroethane ug/L ND 80 80 81.0 83.1 101 104 60-140 2 1,1,2-Trichloroethane ug/L ND 80 80 81.8 83.4 102 104 60-140 2 1,1-Dichloroethane ug/L ND 80 80 92.7 90.9 116 114 60-140 2 1,1-Dichloroethene ug/L ND 80 80 90.2 91.7 113 115 60-140 2 1,1-Dichloropropene ug/L ND 80 80 80.2 78.9 100 99 60-140 2 1,2,3-Trichlorobenzene ug/L ND 80 80 83.0 89.5 104 112 60-140 8 1,2,3-Trichloropropane ug/L ND 80 80 81.9 80.5 102 101 60-140 2 1,2,4-Trichlorobenzene ug/L ND 80 80 83.4 84.1 104 105 60-140 1 1,2,4-Trimethylbenzene ug/L ND 80 80 80.6 80.8 99 99 60-140 0 1,2-Dibromo-3-chloropropane ug/L ND 80 80 80.9 84.2 101 105 60-140 4 1,2-Dibromoethane (EDB) ug/L ND 80 80 81.1 83.4 101 104 60-140 3 1,2-Dichlorobenzene ug/L ND 80 80 80.8 79.1 101 99 60-140 2 1,2-Dichloroethane ug/L ND 80 80 82.8 83.0 104 104 60-140 0 1,2-Dichloropropane ug/L ND 80 80 82.3 81.8 103 102 60-140 1 1,3,5-Trimethylbenzene ug/L ND 80 80 79.1 782 99 98 60-140 1 1,3-Dichlorobenzene ug/L ND 80 80 77.5 78.4 97 98 60-140 1 1,3-Dichloropropane ug/L ND 80 80 82,6 81.3 103 102 60-140 2 1,4-Dichlorobenzene ug/L ND 80 80 77.4 78 5 97 98 60-140 1 2,2-Dichloropropane ug/L ND 80 80 95.9 95.4 120 119 60-140 1 2-Chlorotoluene ug/L ND 80 80 78.8 78.0 99 98 60-140 1 4-Chlorotoluene ug/L ND 80 80 77.6 76.8 97 96 60-140 1 Benzene ug/L 560 80 80 629 621 87 77 60-140 1 Bromobenzene ug/L ND 80 80 80.7 812 101 102 60-140 1 Bromochloromethane ug/L ND 80 80 88,0 87.3 110 109 60-140 1 Bromodichloromethane ug/L ND 80 80 80.6 81.2 101 101 60-140 1 Bromoform ug/L ND 80 80 77.5 78.0 97 97 60-140 1 Bromomethane ug/L ND 80 80 76.7 82,2 96 103 60-140 7 Carbon tetrachloride ug/L ND 80 80 93.8 91,2 117 114 60-140 3 Chlorobenzene ug/L ND 80 80 77.8 78.1 97 98 60-140 0 Chloroethane ug/L ND 80 80 95.8 98.6 120 123 60-140 3 Chloroform ug/L ND 80 80 86.1 85.2 108 107 60-140 1 Chloromethane ug/L ND 80 80 92.7 92.5 116 116 60-140 0 cis-1,2-Dichloroethene ug/L ND 80 80 85.2 84.5 106 106 60-140 1 cis-1,3-Dichloropropene ug/L ND 80 80 89.1 88.9 111 111 60-140 0 Dibromochloromethane ug/L ND 80 80 81.5 85.2 102 106 60-140 4 Dibromomethane ug/L ND 80 80 84.3 85.8 105 107 60-140 2 Dichlorodifluoromethane ug/L ND 80 80 82.1 81.9 103 102 60-140 0 Diisopropyl ether ug/L 104 80 80 191 187 108 104 60-140 2 Ethylbenzene ug/L 8.7 80 80 86.6 88.3 97 100 60-140 2 Hexachloro-1,3-butadiene ug/L ND 80 80 87.1 85.9 109 107 60-140 1 Isopropylbenzene (Cumene) ug/L 2.3 80 80 82.4 84.2 100 102 60-140 2 m&p-Xylene ug/L ND 160 160 161 162 98 99 60-140 1 Methyl-tert-butyl ether ug/L 45.7 80 80 130 131 106 107 60-140 1 Methylene Chloride ug/L ND 80 80 85.3 84.9 107 106 60-140 0 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right or the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 32 of 36 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA Project: PIT STOP BP Pace Project No.: 92412854 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2467191 2467192 MS MSD 92412854007 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual n-Butylbenzene ug/L ND 80 80 82.2 79.7 103 100 60-140 3 n-Propylbenzene ug/L 2.7 80 80 82.2 82.8 99 100 60-140 1 Naphthalene ug/L 12.3 80 80 93.2 96.9 101 106 60-140 4 o-Xylene ug/L ND 80 80 81.6 82.8 101 102 60-140 1 sec-Butylbenzene ug/L ND 80 80 83.9 84.4 105 105 60-140 1 Styrene ug/L ND 80 80 80.8 82.2 101 103 60-140 2 tert-Butylbenzene ug/L NO 80 80 70.2 70.1 88 88 60-140 0 Tetrachloroethene ug/L ND 80 80 77.4 77.4 97 97 60-140 0 Toluene ug/L 5.3 80 80 84.9 85.4 100 100 60-140 0 trans- 1,2-Dichloroethene ug/L ND 80 80 92.7 90.5 116 113 60-140 2 trans-1,3-Dichloropropene ug/L ND 80 80 87.9 87.9 110 110 60-140 0 Trichloroethene ug/L ND 80 80 81.8 79.8 102 100 60-140 2 Trichlorofluoromethane ug/L ND 80 80 99.3 98.9 124 124 60-140 0 Vinyl chloride ug/L ND 80 80 99.2 104 124 130 60-140 4 1,2-Dichloroethane-d4 (S) % 102 102 70-130 4-Bromofluorobenzene (S) % 98 100 70-130 Toluene-d8 (S) % 102 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 33 of 36 aceAnalylical® ww Imelabs.com QUALIFIERS Project: PIT STOP BP Pace Project No.: 92412854 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 01/08/2019 12:47 PM without the written consent of Pace Analytical Services, LLC. Page 34 of 36 lacieAnalj4ical" www.pecelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: PIT STOP BP Pace Project No.. 92412854 Lab ID Sample ID QC Batch Method QC Batch 92412854001 MW-2 SM 6200B 450895 92412854002 MW-6 SM 6200B 450895 92412854003 MW-10B SM 6200B 451065 92412854004 MW-13 SM 6200B 450895 92412854005 MW-14 SM 6200B 450895 92412854006 MW-15 SM 6200B 450895 92412854007 MW-16 SM 6200B 451065 92412854008 MW-17 SM 6200B 450895 92412854009 TW-2 SM 6200B 450895 92412854010 TRIP BLANK SM 6200B 450895 Date: 01/08/2019 12:47 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Analytical Method Analytical Batch Page 35 of 36 v ` CHAIN -OF -CUSTODY / Analytical Request Document eo i , aCeMarytrcal' f The Chain -of -Custody is a LEGAL DOCUMENT. All relevant fields must be completed accurately. m Section A I Section B Section C Required Client Information: Required Project Information: Invoice Information: pa e ' 1 Of 1 I Report To: Matthew Smith Allaniton: Matthew Smith Copy To: Company Name: Shield Company, Shield Address', 43C1 Taggarl Creek {toad Charlotte, NC 2.8208 IAddress: 4301 Taggart Creek Rd Charlotte NC 28208 Re ulato A en¢ Email msmith(Dshieldengin6erino.com PUfCrlase Order n: ace Quote: NCDEQ - UST Phone, (704 t394-6913 1 JF"ax:j704)394-6968 Project Name: Pit Stop SP Pace Project Manager: n lcole.ea siofewsMQDa Beta; &Com. Stale 1 Loral; on Requested Due Date SlanArd(1CDavi Project#: 1120116 Pace Profile #: INC Requested An l ysls Filtered IN Z MATRIX CODE — o COLLECTED Z Preservatives 3 D'. W,J Wak, OW "al", WT U U SAMPLE n,tx1`cl P ID n;;" °° a e d O ? START END U v n N _ V One Character I box. Al,re w w Z N a) I!r AR rL 7 . Olnu* 07 U - , p U # Sample Ids must be unique T1ssuc Ts X w w z0 c Ta C r a w � O cn t a � Q m U O> _ ~ ¢ DATE TIME DATE TIME N � = 2 S z z O 1 MW-2 WT G lfj�yY f, J 4 a x 2 MW-6 WT G I l �. r'_G; 4 4 X 3 MW-10B ` WT G I I l.r 1%t�3 4 4 X 4 MW-13 V WT G I t7 -'-'" 4 4 X S MW-14 WT G <<--%E7 4 4 X 6 tow-15 WT G ELT" 4 4 X ' 7 MW-16 WT G -�C' 4 4 X - 8 AAW-17 WT G 1If i h-.1� 4 4 x - 9 TW-2 WT G I y 1z.IT� 4 4 X J 10 4 — 11 Trip Blank IWT G 1 2 2 X 12 ADDITIONA COMMENTS RELINQUISHED B ( AFFILIATION DATE TIME ACCEPTED BY I AFFILIATION DATE TIME SAMPLE CONDITIONS WO24 QC SAMPLER NAME AMD SIGNATURE VJ PRINTNome of SAMPLER: r—. L c a I� I I� IIII III SIGNATURE of SAMPLF f f - DATE Signed: w aDi m } v v o } m r� } aceAnalytical www.pacelabs.com February 12, 2019 Matt Smith Shield Engineering 4301 Taggart Creek Road Charlotte, NC 28208 RE: Project: Pit Stop BP-MMPE Pace Project No.: 92416208 Dear Matt Smith: Pace Analytical Services, LLC 9800 Kincey Ave Suite 100 Huntersville, NC 28078 (704)875-9092 Enclosed are the analytical results for sample(s) received by the laboratory on February 01, 2019. The results relate only to the samples included in this report. Results reported herein conform to the most current, applicable TNI/NELAC standards and the laboratory's Quality Assurance Manual, where applicable, unless otherwise noted in the body of the report. If you have any questions concerning this report, please feel free to contact me. Sincerely, Nicole Gasiorowski nicole.gasiorowski@pacelabs.com (704)875-9092 Project Manager Enclosures cc: James Gamertsfelder, Shield Engineering, Inc Mr. Tom Witner, Shield Engineering REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Page 1 of 12 ace Analytical www.pecelabs.cam r Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 CERTIFICATIONS Project: Pit Stop BP-MMPE Pace Project No.: 92416208 Charlotte Certification IDS 9800 Kincey Ave. Ste 100, Huntersville, NC 28078 South Carolina Certification #: 99006001 Louisiana/NELAP Certification # LA170028 Florida/NELAP Certification #: E87627 North Carolina Drinking Water Certification #: 37706 Kentucky UST Certification M 84 North Carolina Field Services Certification #: 5342 VirginiaNELAP Certification #: 460221 North Carolina Wastewater Certification #: 12 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 2 of 12 aceAnalj cal —pacelabs.com SAMPLE ANALYTE COUNT Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pit Stop BP-MMPE Pace Project No.: 92416208 Analytes Lab ID Sample ID Method Analysts Reported Laboratory 92416208001 MW-10B SM 6200B GAW 16 PASI-C 92416208002 MW-16 SM 6200B GAW 16 PASI-C REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 3 of 12 aceAnalytical J * WwpacelabS.CGm I ANALYTICAL RESULTS Project: Pit Stop BP-MMPE Pace Project No.: 92416208 Pace Analytical Services, LLC 9800 KinceyAve. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-10B Lab ID: 92416208001 Collected: 01/30/19 11:25 Received: 02/01/19 13:52 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 602 Volatiles by Method 6200 Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Diisopropyl ether Ethylbenzene Isopropylbenzene (Cumene) Methyl-tert-butyl ether Naphthalene Toluene m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/12/2019 04:59 PM Analytical Method: SM 6200B 1790 ug/L ND ug/L ND ug/L ND ug/L ND ug/L 80.5 ug/L 179 ug/L 17.9 ug/L 266 ug/L 182 ug/L 54.8 ug/L 747 ug/L 212 ug/L 99 % 101 % 102 % 10.0 10 02/05/19 18:04 71-43-2 10.0 10 02/05/19 18:04 108-90-7 10.0 10 02/05/19 18:04 95-50-1 10.0 10 02/05/19 18:04 541-73-1 10.0 10 02/05/19 18:04 106-46-7 10.0 10 02/05/19 18:04 108-20-3 10.0 10 02/05/19 18:04 100-41-4 10.0 10 02/05/19 18:04 98-82-8 10.0 10 02/05/19 18:04 1634-04-4 200 10 02/05/19 18:04 91-20-3 10.0 10 02/05/19 18:04 108-88-3 20.0 10 02/05/19 18:04 179601-23-1 10.0 10 02/05/19 18:04 95-47-6 70-130 10 02/05/19 18:04 460-00-4 70-130 10 02/05/19 18:04 17060-07-0 70-130 10 02/05/19 18:04 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC. Page 4 of 12 lacmnalyfical" www.pacelabs.com ANALYTICAL RESULTS Project: Pit Stop BP-MMPE Pace Project No 92416208 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Sample: MW-16 Lab ID: 92416208002 Collected: 01/30/19 11:40 Received: 02/01/19 13:52 Matrix: Water Parameters Results Units Report Limit DF Prepared Analyzed CAS No. Qual 602 Volatiles by Method 6200 Benzene Chlorobenzene 1,2-Dichlorobenzene 1,3-Dichlorobenzene 1,4-Dichlorobenzene Diisopropyl ether Ethylbenzene Isopropylbenzene (Cumene) Methyl-tert-butyl ether Naphthalene Toluene m&p-Xylene o-Xylene Surrogates 4-Bromofluorobenzene (S) 1,2-Dichloroethane-d4 (S) Toluene-d8 (S) Date: 02/12/2019 04:59 PM Analytical Method: SM 6200B 516 ug/L ND ug/L ND ug/L ND ug/L ND ug/L 67.0 ug/L 68.5 ug/L 6.1 ug/L 27.6 ug/L 19.6 ug/L 9.0 ug/L 21.4 ug/L ND ug/L 98 % 101 % 100 % 4.0 4 02/10/1914:23 71-43-2 4.0 4 02/10/1914:23 108-90-7 4.0 4 02/10/1914:23 95-50-1 4.0 4 02/10/1914:23 541-73-1 4.0 4 02/10/1914:23 106-46-7 4.0 4 02/10/1914:23 108-20-3 4.0 4 02/10/1914:23 100-41-4 4.0 4 02/10/1914:23 98-82-8 4.0 4 02/10/1914:23 1634-04-4 8.0 4 02/10/1914:23 91-20-3 4.0 4 02/10/1914:23 108-88-3 8.0 4 02/10/1914:23 179601-23-1 4.0 4 02/10/1914:23 95-47-6 70-130 4 02/10/1914:23 460-00-4 70-130 4 02/10/1914:23 17060-07-0 70-130 4 02/10/1914:23 2037-26-5 REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC, Page 5 of 12 aceMalytical www.pacelabs.com QUALITY CONTROL DATA Project: Pit Stop BP-MMPE Pace Project No.: 92416208 QC Batch: 456397 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 602 by 6200B Associated Lab Samples: 92416208001 METHOD BLANK: 2490012 Associated Lab Samples: 92416208001 Matrix: Water Parameter Units Blank Result 1,2-Dichlorobenzene ug/L ND 1,3-Dichlorobenzene ug/L ND 1,4-Dichlorobenzene ug/L ND Benzene ug/L ND Chlorobenzene ug/L ND Diisopropyl ether ug/L ND Ethylbenzene ug/L ND Isopropyl benzene (Cumene) ug/L ND m&p-Xylene ug/L ND Methyl-tert-butyl ether ug/L ND Naphthalene ug/L ND o-Xylene ug/L ND Toluene ug/L ND 1,2-Dichloroethane-d4 (S) % 99 4-Bromofluorobenzene (S) % 99 Toluene-d8 (S) % 101 Reporting Limit Analyzed 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 2.0 02/05/1913:30 1.0 02/05/1913:30 2.0 02/05/1913:30 1.0 02/05/1913:30 1.0 02/05/1913:30 70-130 02/05/1913:30 70-130 02/05/1913:30 70-130 02/05/1913:30 LABORATORY CONTROL SAMPLE: Parameter 2490013 Units Spike Conc. LCS Result 1,2-Dichlorobenzene ug/L 50 47,3 1,3-Dichlorobenzene ug/L 50 47.2 1,4-Dichlorobenzene ug/L 50 46.6 Benzene ug/L 50 51.0 Chlorobenzene ug/L 50 47.7 Diisopropyl ether ug/L 50 51:5 Ethylbenzene ug/L 50 48.4 Isopropylbenzene (Cumene) ug/L 50 49.6 m&p-Xylene ug/L 100 97.0 Methyl -tert-butyl ether ug/L 50 51.9 Naphthalene ug/L 50 45.8 o-Xylene ug/L 50 49.1 Toluene ug/L 50 483 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % LCS % Rec Qualifiers % Rec Limits 95 60-140 94 60-140 93 60-140 102 60-140 95 60-140 103 60-140 97 60-140 99 60-140 97 60-140 104 60-140 92 60-140 98 60-140 97 60-140 102 70-130 102 70-130 99 70-130 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units Indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:59 PM without the written consent of Pace Analytical Services, LLC, Page 6 of 12 aceAnalyfical —pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pit Stop BP-MMPE Pace Project No.: 92416208 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2490014 2490015 MS MSD 92415612003 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,2-Dichlorobenzene ug/L ND 2000 2000 1900 1890 95 94 60-140 0 1,3-Dichlorobenzene ug/L ND 2000 2000 1870 1860 93 93 60-140 0 1,4-Dichlorobenzene ug/L ND 2000 2000 1920 1870 96 93 60-140 3 Benzene ug/L ND 2000 2000 2120 2140 106 107 60-140 1 Chlorobenzene ug/L ND 2000 2000 2000 2000 100 100 60-140 0 Diisopropyl ether ug/L ND 2000 2000 2110 2060 105 103 60-140 2 Ethylbenzene ug/L ND 2000 2000 2030 2010 101 101 60-140 1 Isopropylbenzene (Cumene) ug/L ND 2000 2000 2020 2040 101 102 60-140 1 m&p-Xylene ug/L ND 4000 4000 4020 4050 101 101 60-140 1 Methyl-tert-butyl ether ug/L ND 2000 2000 2060 2050 103 103 60-140 0 Naphthalene ug/L ND 2000 2000 1650 1880 82 94 60-140 13 o-Xylene ug/L ND 2000 2000 2020 1990 101 99 60-140 2 Toluene ug/L 10400 2000 2000 14000 13900 178 174 60-140 0 M1 1,2-Dichloroethane-d4 (S) % 100 99 70-130 4-Bromofluorobenzene(S) % 99 101 70-130 Toluene-d8 (S) % 101 102 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:59 PM without the written consent of Pace Analytical Services, LLC Page 7 of 12 aceAnalytieal www.pacelabs.com QUALITY CONTROL DATA Project: Pit Stop BP-MMPE Pace Project No.: 92416208 QC Batch: 457350 Analysis Method: SM 6200B QC Batch Method: SM 6200B Analysis Description: 602 by 6200B Associated Lab Samples: 92416208002 METHOD BLANK: 2494575 Associated Lab Samples: 92416208002 Parameter Units Matrix: Water Blank Reporting Result Limit Analyzed 1,2-Dichlorobenzene ug/L ND 1.0 02/10/19 12:46 1,3-Dichlorobenzene ug/L ND 1.0 02/10/19 12:46 1,4-Dichlorobenzene ug/L ND 1.0 02/10/19 12:46 Benzene ug/L ND 1.0 02/10/19 12:46 Chlorobenzene ug/L ND 1.0 02/10/19 12:46 Diisopropyl ether ug/L ND 1.0 02/10/19 12:46 Ethylbenzene ug/L ND 1.0 02/10/19 12:46 Isopropylbenzene (Cumene) ug/L ND 1.0 02/10/19 12:46 m&p-Xylene ug/L ND 2.0 02/10/19 12:46 Methyl-tert-butyl ether ug/L ND 1.0 02/10/19 12:46 Naphthalene ug/L ND 2.0 02/10/19 12:46 o-Xylene ug/L ND 1.0 02/10/19 12:46 Toluene ug/L ND 1.0 02/10/19 12:46 1,2-Dichloroethane-d4 (S) % 96 70-130 02/10/19 12:46 4-Bromofluorobenzene (S) % 99 70-130 02/10/19 12:46 Toluene-d8 (S) % 101 70-130 02/10/19 12:46 LABORATORY CONTROL SAMPLE: 2494576 Spike LCS LCS Parameter Units Conc. Result % Rec 1,2-Dichlorobenzene ug/L 50 48.3 1,3-Dichlorobenzene ug/L 50 48.1 1,4-Dichlorobenzene ug/L 50 46.9 Benzene ug/L 50 46.0 Chlorobenzene ug/L 50 47.1 Diisopropyl ether ug/L 50 47.1 Ethylbenzene ug/L 50 47.9 Isopropylbenzene (Cumene) ug/L 50 48.5 m&p-Xylene ug/L 100 95.9 Methyl-tert-butyl ether ug/L 50 47.0 Naphthalene ug/L 50 46.1 o-Xylene ug/L 50 47.8 Toluene ug/L 50 44.2 1,2-Dichloroethane-d4 (S) % 4-Bromofluorobenzene (S) % Toluene-d8 (S) % Qualifiers % Rec Limits 97 60-140 96 60-140 94 60-140 92 60-140 94 60-140 94 60-140 96 60-140 97 60-140 96 60-140 94 60-140 92 60-140 96 60-140 88 60-140 100 70-130 101 70-130 97 70-130 Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Qualifiers Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 8 of 12 acmnalytical www.pacelabs.com QUALITY CONTROL DATA Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 Project: Pit Stop BP-MMPE Pace Project No.: 92416208 MATRIX SPIKE & MATRIX SPIKE DUPLICATE: 2494577 2494578 MS MSD 92415612006 Spike Spike MS MSD MS MSD % Rec Parameter Units Result Conc. Conc. Result Result % Rec % Rec Limits RPD Qual 1,2-Dichlorobenzene ug/L ND 100 100 103 103 i 103 103 60-140 ^ 0 1,3-Dichlorobenzene ug/L ND 100 100 100 101 100 101 60-140 1 1,4-Dichlorobenzene ug/L ND 100 100 99.1 101 99 101 60-140 2 Benzene ug/L ND 100 100 103 103 103 103 60-140 0 Chlorobenzene ug/L ND 100 100 102 103 102 103 60-140 0 Diisopropyl ether ug/L ND 100 100 102 102 102 102 60-140 0 Ethylbenzene ug/L ND 100 100 105 104 105 104 60-140 0 Isopropylbenzene (Cumene) ug/L ND 100 100 105 107 105 107 60-140 1 m&p-Xylene ug/L ND 200 200 208 211 104 106 60-140 2 Methyl-tert-butyl ether ug/L ND 100 100 102 102 102 102 60-140 0 Naphthalene ug/L ND 100 100 96.1 97.9 96 98 60-140 2 o-Xylene ug/L ND 100 100 106 104 106 104 60-140 2 Toluene ug/L 513 100 100 610 604 97 91 60-140 1 1,2-Dichloroethane-d4 (S) % 98 99 70-130 4-Bromofluorobenzene (S) % 102 99 70-130 Toluene-d8 (S) % 98 98 70-130 Results presented on this page are in the units indicated by the "Units" column except where an alternate unit is presented to the right of the result. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 9 of 12 aceAnaljdical www.pacelabs.com QUALIFIERS Project: Pit Stop BP-MMPE Pace Project No.: 92416208 DEFINITIONS DF - Dilution Factor, if reported, represents the factor applied to the reported data due to dilution of the sample aliquot. ND - Not Detected at or above adjusted reporting limit. TNTC - Too Numerous To Count J - Estimated concentration above the adjusted method detection limit and below the adjusted reporting limit. MDL -Adjusted Method Detection Limit. Pace Analytical Services, LLC 9800 Kincey Ave, Suite 100 Huntersville, NC 28078 (704)875-9092 PQL - Practical Quantitation Limit. RL - Reporting Limit - The lowest concentration value that meets project requirements for quantitative data with known precision and bias for a specific analyte in a specific matrix. S - Surrogate 1,2-Diphenylhydrazine decomposes to and cannot be separated from Azobenzene using Method 8270. The result for each analyte is a combined concentration. Consistent with EPA guidelines, unrounded data are displayed and have been used to calculate % recovery and RPD values. LCS(D) - Laboratory Control Sample (Duplicate) MS(D) - Matrix Spike (Duplicate) DUP - Sample Duplicate RPD - Relative Percent Difference NC - Not Calculable. SG - Silica Gel - Clean -Up U - Indicates the compound was analyzed for, but not detected. Acid preservation may not be appropriate for 2 Chloroethylvinyl ether. A separate vial preserved to a pH of 4-5 is recommended in SW846 Chapter 4 for the analysis of Acrolein and Acrylonitrile by EPA Method 8260. N-Nitrosodiphenylamine decomposes and cannot be separated from Diphenylamine using Method 8270. The result reported for each analyte is a combined concentration. Pace Analytical is TNI accredited. Contact your Pace PM for the current list of accredited analytes. TNI - The NELAC Institute. LABORATORIES PASI-C Pace Analytical Services - Charlotte ANALYTE QUALIFIERS M1 Matrix spike recovery exceeded QC limits. Batch accepted based on laboratory control sample (LCS) recovery. REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, Date: 02/12/2019 04:59 PM without the written consent of Pace Analytical Services, LLC. Page 10 of 12 aceAnalytical www.pacelabs.com QUALITY CONTROL DATA CROSS REFERENCE TABLE Project: Pit Stop BP-MMPE Pace Project No.: 92416208 Pace Analytical Services, LLC 9800 Kincey Ave. Suite 100 Huntersville, NC 28078 (704)875-9092 Lab ID Sample ID QC Batch Method QC Batch Analytical Method 92416208001 92416208002 MW-10B MW-16 SM 6200B SM 6200B 456397 457350 Date: 02/12/2019 04:59 PM REPORT OF LABORATORY ANALYSIS This report shall not be reproduced, except in full, without the written consent of Pace Analytical Services, LLC Analytical Batch Page 11 of 12 ��A.Vicat I CHAIN -OF -CUSTODY 1 Analytical Request Document The Chain -of -Custody is a LEGAL DOCUMENT All relevant fields must be completed accurately. Section A Section B Section C Required Client Information_ Required Project Information- Invoice Information: Page : f Of 1 Report To: Matt Smith Attention: Copy To: Company Name: Company: Shield Address: 4301 Taaaart Creek Road Charlotte, NC 28208 Address: Re ulato Aaencv Email: rnsmilh shieldengineering com Purchase Order 0, Pre Ouore. Phone: (704j394: 913 Fax Project Name: Pit Slap BP • MMPE Paco Project l6=Wr,, nlcole.gasiorowrki pacelaps.ca'n, Statel Locatfart Requesled Dve Date: j : - ,. Proioct C Pace Profile #: 6821 NC R lae_sted Anal Is Ritemd !N M -rmx CODE — COLLECTED = Preservatives } D,l q Weln DW - Ct Woler Wi We.t," a O SAMPLE ID ww Prod.d P = JO H z Y 00 OL START END One Character per box, wipe VJP (A-Zr 0-9 1, other oT W Z Samplo Ids must bo unlquc m W 4 i U +z fJl 0 0 = O ry L C Q ry m r• �y NT.ATETI.EDATE TIME h _ = = z z I o yffti �� 3 4 5 s 7 s 9 10 11 12 ADOITIONRL COMMENT$ RELWOUMED 8Yf AFFII.IAT" OATE TIME AC;IUT�ED BY f AFFILIATION DATE 'nME SAMPLE CONDITIONS ILI e E �y{v' � . � � � W o � � /� � SAMPt,ER NAME AND SIGNATURE v 0 PRINT Name of SAMPLER: % L m N SIGNATURE of SAMPLER: -�- DATE Signed: � f w — z %frrz (�ii i r IS 1 } A o z Nc�} E _ Z . c} m m Co d 92416208 Appendix J Groundwater Calculations Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contamination Calculations NCGWI #13403 Date of Sampling 7/19/2017 Mass of Groundwater Contamination (mgW) mgW=Volume (v) x Concentration (C) V(L)= 1,102,953.52 C (VOCs in ug/L)= 6,542.25 mgw(ug)= 7,215,797,655.75 mgw(g)= 7,215.80 V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n) A(ft2)= 11,290.00 D (ft)= 7.50 n= 0.46 V (ft3)= 38,950.50 V(L)= 1,102,953.52 Notes: - Area (A) = Approximate area of the combined benzene and IVITBE plumes -Concentration is based on Total VOCs for each specific sampling event -Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water level in all site monitoring wells during sampling event (7.5 ft) -Porosity (n) = Total Porosity (Using a total porosity of 0.46*) 1 ft3 = 28.3168 L -mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L = micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n =Porosity; ft = feet *Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W. (1994). Applied Hydrogelogy (3rd ed.). New York, NY: Macmillan College Publishing Company, Inc.] 12/13/2017 540,730.53 3,055.00 1,651,931,780.15 1,651.93 5,535.00 7.50 0.46 19,095.75 540,730.53 Carolina Fast Mart #4 - Pit Stop - Mass of Groundwater Contz NCGWI#13403 Date of Sampling Mass of Groundwater Contamination (mgW) mgW=Volume (v) x Concentration (C) V(L)= C (VOCs in ug/L)= mgw(ug)= mgw(g)= V=Contaminant Area (A) x Depth of Plume (D) x Porosity (n) A(ft2)= D (ft)= n= V (ft)= V(L)= Notes: - Area (A) = Approximate area of the combined benzene and MTBE plumes -Concentration is based on Total VOCs for each specific sampling event -Depth (D)=Terminal depth of monitoring well (MW-10B) screen (-20 ft)- average static water level in all site monitoring wells during sampling event (7.5 ft) -Porosity (n) = Total Porosity (Using a total porosity of 0.46*) 1 ft3 = 28.3168 L -mgw = Mass of Groundwater Contamination; v = volume; c = concentration; L = Liter; ug/L = micrograms per liter; g = grams; A = Contaminant Area; D = Depth/Thickness of Plume; n =Porosity; ft = feet *Based on the midpoint of the ranges (33%-60%) of porosities for Silt and clay. [Fetter, C. W. (1994). Applied Hydrogelogy (3rd ed.). New York, NY: Macmillan College Publishing Company, Inc.] 6/26/2018 561,734.52 11,319.00 6,358,273,031.88 6,358.27 5,750.00 7.50 0.46 19,837.50 561,734.52 1/3/2019 483,580.15 1,110.00 536,773,968.72 536.77 4,950.00 7.50 0.46 17,077.50 483,580.15 Appendix K Mobile Multi --Phase Extraction Report ADVANCED ENVIRONMENTAL SERVICES, INC. "Your Environmental Solutions Partner" MOBILE MULTI -PHASE EXTRACTION REPORT Site Location: Pit Stop BP 3690 Highway 29 South Concord, North Carolina Prepared for: Shield Engineering 4301 Taggart Creek Rd. Charlotte, North Carolina 28208 PM — Mr. Matthew Smith February 6, 2019 TABLE OF CONTENTS EVENT SUMMARY MMPE FIELD LOG MASS -REMOVAL CALCULATION FIELD NOTES DISPOSAL MANIFEST MOBILE MULTI -PHASE EXTRACTION EVENT SUMMARY February 6, 2019 Location: Pit Stop BP 3690 Highway 29 South Concord, North Carolina Client: Shield Engineering 4301 Taggart Creek Rd. Charlotte, North Carolina 28208 Event Dates: January 28 - February 1, 2019 Advanced Job # 01 - 1906 Advanced Personnel: Scott Crook, Gary McDaniel and Lee Heilig MMPE System: MMPE system rated 24"hg at 140 CFM 4' discharge stack - 2" diameter 5,500 - gallon tanker Approximately 160'of 1.5" hose to 2 wells Extraction Well: MW-16 and MW-IOB Well Initial FP/WL(ft) Final FP/WL(ft) Stinger depth(ft) Run Time MW-16 4.82 11.24 5/7 96.0 hours MW-10B 4.72 11.21 5/7 96.0 hours Description of Event: The MMPE event ran from 11:00 January 28, through 11:00 February 1, 2019. The MMPE system was active for 96.0 hours. During the event vacuum at the recovery pump ranged from 22.5 to 23.0 inches of mercury (hg) and stabilized at approximately 23.0 inches of mercury. Airflow rates ranged from 2,800 to 2,900 feet per minute and stabilized at 2,800 feet per minute. System temperature ranged from 110 — 120 degrees (F) and humidity ranged from 68 to 99 percent. Field gauged volatile organic compounds (VOC's) decreased from 1,400 parts per - million (PPM) to 900 (PPM) throughout the event. Groundwater / Product Mix Recovered: During the event, a total of 8,190 gallons of product/water mix were removed from the site and properly disposed at a certified North Carolina disposal facility. No measurable free product was recovered as liquid. Total fluids recovered, was measured based on stick readings conducted during and following the event. Based on 96.0 hours of operation and a total of 8,190 gallons recovered, the average groundwater recovery rate was calculated to be approximately 85.31 gallons per hour. Events Results: Based on mass -removal calculations 14.11 pounds or 2.29 gallons of VOC's were removed as vapor. Using Dwyer Magnehelic gauges, vacuum influence (inches of water) was measured at monitoring points MW-2, MW-15 and MW-17. No measurable vacuum influence was observed at monitoring point. Draw -down was observed in MW-2, MW-15 and MW-17 at 1.46, 1.29 and 0.98 feet respectively. Following the event, no free product was identified in any well. MMPE FIELD LOG: CLIENT. Shield Engineering JOB NAME: Pit Stop BP LOCATION: Concord, NC MMPE EVENT DATES: January 28 through February 1, 2019 EXTRACTION POINTS: MW-16 and MW-10B AES JOB NUMBER: 01 - 1906 DATE TIME FLOW flm HUM. % TEMP. F VOC's(p m) VAC. (hg") GALLONS STINGERIWL's EXTRACTION POINTS h ' MW-16 MW-10B Stinger(ft) 5,7 5,7 Start 11:00 Initial WL's 4.82 4.72 01/28/19 12:55 2,900 99.0 118 1,000 22.5 128 gal. 20.0 20.0 14.10 2,900 99.0 118 1,000 22.5 20.0 20.0 18:20 2,900 99.0 116 1,200 22.5 20.0 20.0 19:20 2,900 99.0 116 1,200 22.5 20.0 20.0 01/29/19 10:10 2,900 99.0 114 1,400 22.5 20.0 20.0 11:30 2,900 99.0 114 1,400 22.5 2,220 gal. 20.0 20.0 15:50 2,900 99.0 116 19400 1 22.5 20.0 20.0 16:30 2,900 99.0 116 1,400 22.5 20.0 20.0 01/30/19 10:20 2,800 99.0 112 1,200 23.0 20.0 20.0 11.10 2 800 99.0 112 1,200 23.0 plo 4,230 20.0 20.0 16:10 2,800 99.0 112 1200 23.0 20.0 20.0 16:50 2,800 99.0 112 1,200 23.0 20.0 20.0 01/31/19 9:50 2,800 99.0 110 1,100 23.0 1,800 gal. 20.0 20.0 10:40 2,800 99.0 112 1,100 23.0 20.0 20.0 11:20 2,800 99.0 112 1,100 23.0 20.0 20.0 19:50 2,800 99.0 110 1,000 23.0 20.0 20.0 02/01/19 9:00 2,800 72.0 112 1,100 23.0 3,710 al. 20.0 20.0 10:15 2,800 68.0 120 900 23.0 20.0 20.0 End 11:00 Final WL's 11.24 11.21 'Total fluids: 8,190 gal. 'Total free product: 0 --- -------- ------- ---- ------------ ------- ---- ------------ ------------ ---------- - ------------ Page 1 of 1 ]MOBILE MULTI -PHASE EXTRACTION EVENT :SITE NAME: PIT STOP BP I CLIENT. SHIELD ENGINEERING INCIDENT NUMBER: AVERAGE DEPTH TO GROUNDWATER: 44 - 7 ft. DESCRIBE SOILINTHE SATURATED ZONE: AVERAGE Hy oWmaic coWc ICTfVriY {if known EXTRACTION WELLS USED FOR MMPE: 1vTW-16 AND M_W-10B SPECIFICATIONS OF THE MMPE SYSTEM Jrn @. in H : 140 cfm Q 24," DRY STANDARD CUBIC FEET PER MINUTE (DSCFM) AIR FLOW CALCULATIONS Qstd Date Hours Vacuum Valocy Pie ID Temp Rel Humid Water Water m (inches of H) (ft/min) (in) °F) (%) Vapor (Wl%�- Va or Vol% (flow 1/28/19 24.00 22.50 2900.00 2 11-7 99.0 U;072 0.103 52 1129/19 48.00 22.50 2900.00 2 its 99.0 0,068 0.098 52 1130119 72,00 23.00 2800.00 2 112 99.0 0, 2 0.090 51 1/31/19 96.00 23.00 2800.00 2 113 89.0 0.057 0.084 52 211/19 INOTES Qstd = Flow at DSCFM acuum =The level of vacuum being appAed should he rrecorded from the MAAPE sy em�(inches o�H 'Velocity = The rate at whWh air flows is measuretl at the blower discharga ' ma anemomeler or Otot lube PI ID -The inside diameter of the blower di aae PIPin9�(from the AAMPE, sem_ j L T Temperaiure = The tgmperaftlre of the atr stream ex�ling. the blower discharge piPin�(dry bulb temic deg.' j - Retdtive humidity = The g% selative humidify of the air stream exiting the plower discharge piping 1 1- = water Vapor 96 by weight, he„pounds of water r pound of pry air, delved from the Psychrometric chart (temp V4 reiative humidity Er. = water vapor % q. volume j EQUATIONS f _ 1$ I(rmole. kf 1128.84 lb moue d air + t8 fh owls Q -_ _ = 0. 1-Water Vapor)` v9 1 ' dlarneler124} • {528'RI(T:_ +45Q I EMISSION CALCULATIONS Elapsed ! Time Flow PPM_d PPM.W PPMdv IKI PPK„ Cam C PMR° PMR, PMR hour SCFM m C - as' m /dsm) Idsc b%hour /hour 24 52 1100 1100 1227 1 1227 612 3, 218E-05 012 0,14 3.31 48 52 1400 1400 1553 1 ism 775 4.83616E-D 0.15 0.18 4.22 72 51 1200 1200 1319 1 1319 668 1410935E-05 0.13 0.15 3.51 96 52 1050 1050 1146 1 1146 572 3.56947E-05 0,11 0.13 3.07 - J•_ Total emissions Total emissions as gallq ng NOTES PPM ..... a Actual measurements (ppm) taken with a OVA or TVA at the blower discharge piping PPM„r= y_ cancemratran 1 -- PPM "dry" concentration)- K =Number of carbons in calibration gas: (figelhane l{ = 1, or Prtipa 1e K 3, or Hexane 4f = 6] in pounds. pounds 16.152) 14.11 2.29 I T� 'PM = PPM . Volumetric concentration of VOC emissions as carbon, dry basis at STP Gam= mgldsm', mass concentration of VOC emissions as carbon ! M1�= 12.01 mglmg_mote, rimoieculaf waig!Cf- K3 = 24.07 dselt r mg -mole, mass to volume cotwersion [actor st ST'P _ i = Ibldcsf, mass c'anrerftra[ion of VOC emissions. as CefbaR, dry b&sus st &TP rbo P R� = IWIv pnlWfant mass removal rate of VOC's as can 1 _ PMR,= %Mr. pollutant mass rQnloyal rate of of VOVS as gasoline - - - AMfR= lb. pollutant mass removal of:9- s a_s �esWine EQUATIONS PPM, = PPMme . a.- PPM" = PPM.",.li(1-B�) -� 'C� = [Cr fit-43x t6 N R hrlg,R-x, PMIi _ (Q(Q„d)(60 minutelhour) IPMRa = (PMR,)(M./M I r 1- - - PMR = (PMR.)(Ohours)-- MMPE Field Log Client: job Number: C ! - t Site Dame: Event ]Dates: t f zS — Extraction Wells: M w_ 1 b 3, t'ram`' 14--� A,, Y rr - LOAa LJ h r] r F 1, r e:-T re- S A-r i 1 . I .� ,A 7-6D 6AJ C 1 1 t_ —' 'r4r�� ��,� , ? r 7 �' d�1 '� .� r�..• IMPS Held Log Site Namem Extraction '_�,JE� _ Page'# Job Number:,f--�/, - 1-7ey_ Event Dates: )/2,p -. MATERIAL : Manifest Doc�erlt No. MANIFEST�'�ir� Page of .040 f,-k-mmAw d Indoldol $.W..qw 1 [ EMERGENCY PHONE NO. POST OFFICE BOX 357 TEL (336) 841-5276 Zebra Job No.:, (336) 841-5276 HIGH POINT, NC 27261 FAX (336) 841-5509 .;,.. GENERATOR INFORMATION Name JUS EPA ID No. Street Address Mailing Address Phone No. 9ca l ti .figs 3.3(� C. rq_ 9_ 0s /'!�Contact DESCRIPTION OF MATERIALS USDOT Proper Shipping Name HMI (Complete All Items for Hazardous Materials) Hazard Class or Div UN / NA ID No. Packing Group Containers Qty. Type Total Quantity Unit Wt./Vol. a. f�Cri�t l ��i9✓=� �l.t�j �[ f�c..o �d �`fi /�� � rj- l %� �-�� �� b. c. ADDITIONAL INFORMATION ERG No. 2abra,Proiila•Code- a. b. C. GENERATOR'S CERTIFICATION This is to certify that the above -described materials are properly classified, described, packaged, marked and labeled, and are in proper condition for transportation according to the applicable regulations of the Department of Transportation. I further certify that none of the materials described above are a hazardous waste as defined by EPA 40 CFR Part 261 or any applicable state law, and unless specifically identified above, the materials contain less than 1, 000 ppm total halogens and do not contain quantifiable levels (2 ppm) of PCBs as defined by EPA 40 CFR Parts 279 and 761. TRANSPORTER INFORMATION Transporter Zebra Environmental & Industrial Services Inc I hereby acknowledge receipt of the above -described materials for transport from the gen at ar site listed above. Address 901 East Springfield Road d V J `� High Point, NC 27263 Slgnature�~ Shipment Date I hereby acknowledge receipt of the above -described materials were received from the generator site and were transported to the facility listed below. Transporter or Unit-NS. NC0991302669 _!! EPA ID No. Signature �. 4 �3 o- 0 Delivery Date Phone (336) 841-5276 FACILITY INFORMATION F,6L,y Zebra Environmental & Industrial Services, Inc. i hereby acknowled a receipt of the materials covered by this manifest except for any cre ancy noted below. ��I� Y.: Address 901 East Springfield Road High Point, NC 27263 Signatur �/Y�/YII� C Date rf ancies l Routin Codes 1. Handiri Methods Facility or NC0991302669 EPA ID No. a' Phone (336) 841-5276 b' Contact David Tedder C. ORIGINAL - Facility Retain COPY 2 - Return to Generator COPY 3 - Transporter Retain COPY 4 - Generator Retain MATERIALManifest Document No. I ebra MANIFEST Page of Fnveanm lnlol Afn 7 EMERGENCY PHONE NO. POST OFFICE BOX 357 TEL (336) 841-5276 Zebra. Job No, (336) 841.5276 HIGH POINT, NC 27261 FAX (336) 841-5509a GENERATOR INFORMATION Name S—m p j US EPA ID No. Street Address 3(1-lb All Ai s CU V.'it C*-4 )r• , tL DESCRIPTION OF MATERIAL Mailing Address Phone No. 3 . [o L -7 44 Q 5- Contact USDt]7 Proper Shipping Name HM (Complete All Items for Hazardous Materials) Hazard Class or Div UN / NA ID No. Packing Group Containers City. Type Total Quantity Unit a. Jr 3111100 /Wt./Vol. l-T b. c. ADDITIONAL INFORMATION ERG No. . 9braRrofile-Code. " Facility.11s'a . ,,. •-::..::.. a. r �cQ Pe G'Lea"D w b. C. GENERATOR'S CERTIFICATION This is to certify that the above -described materials are properly classified, described, packaged, marked and labeled, and are in proper condition for transportation according to the applicable regulations of the Department of Transportation. / furthercertify that none of the materials described above are a hazardous waste as defined by EPA 40 CFI4 Part 261 orany applicable state law, and unless specifically identified above, the materials contain less than 1,000 ppm total halogens and do not contain quantifiable levels (2 ppm) of PCBs as defined by EPA 40 CFR Parts 279 and 761. P nted I Typedam S g tur Mo Day( r. TRANSPORTER 119FORMATION Transporter Zebra Environmental & Industrial Services Inc I hereby acknowledge receipt of the,above-described materials for transport from the general site listed above. �] �►rt r *� !• 1Q Address 901 East Springfield Road High Point, NC 27263 Signature S ipment Date I hereby acknowledge receipt of the above -described materials were received from the generator site and were transported to the facility listed below. Transporter or NC0991302669 Unit No. EPA ID ! o Phone (336)841-5276 Signature Delivery Date FACILITY INFORMATION Facility Zebra Environmental & Industrial Services, Inc. I hereby acknowledge receipt of the materials covered by this manifest except for any W. Z'my noted below. p� / f Address 901 East Springfield Road High Point, NC 27263 Signature ec .t Date -Q scre ancles: I Routing Codes l•Handin •Methods Facility or EPA ID No. NCO991302669 a' Phone (336) 841-5276 tj_ _ Contact David Tedder c ORIGINAL - Facility Retain COPY 2 - Return to Generator COPY 3 - Transporter Retain COPY 4 - Generator Retain Quality Inn & Suites (NC864) 5301 Equipment Drive Charlotte, NC 28262 (704) 596-9390 GM.NC864@choicehotels.com CROOK, TIMOTHY 306 BRADLEY ST BURLINGTON BURLINGTON, NC 27215 Account: 631687196 Date: 2/14/19 Room: 127 LSTATE Arrival Date: 1/28/19 Departure Date: 1/29/19 Check In Time: 1/28/19 2:16 PM Check Out Time: 1/29/19 10:57 AM Rewards Program ID: GP-TSC4503 You were checked out by: sdhana You were checked in by: sdhana Total Balance Due: 0.00 ,Post Date Description Comment 1/28/19 Visa Payment (394.12) XXXXXXXXXXXX9650 1/28/19 Room Charge #127 CROOK, TIMOTHY 85.49 1/28/19 State Tax 6.20 1/28/19 Occupancy Tax 6.84 1/29/19 Visa Payment 295.59 XXXXXXXXXXXX9650 -- - Folio Summary 1/28/19 - 1/29/19 Room Charge 85.49 State Tax 6.20 Occupancy Tax 6.84 Visa Payment (98.53) Balance Due: 0.00 4AP CHOICE privileges. QUALITY INN & SUITES' W CROOK, TIMOTHY 306 BRADLEY ST BURLINGTON BURLINGTON, NC 27215 1/29/19 Visa Payment Quality Inn & Suites (NC511) 3100 Queen City Drive Charlotte, NC 28208 (704) 393-5306 GM.NC511 @choicehotels.com 1/29119 Room Charge 1/29/19 State Tax 1/29/19 City / County Tax 1/30/19 Room Charge 1 /30/19 State Tax 1 /30/19 City / County Tax 1/31/19 Room Charge 1/31/19 State Tax 1/31/19 City / County Tax Room Charge State Tax City / County Tax Visa Payment Comment XXXXXXXXXXXX9650 #114 CROOK, TIMOTHY #114 CROOK. TIMOTHY #114 CROOK. TIMOTHY Account: 632499737 Date: 2/14/19 Room: 114 scpm Arrival Date: 1/29/19 Departure Date: 2/1 /19 Check In Time: 1/29/19 12:58 PM Check Out Time: 2/1 /19 12:44 PM Rewards Program ID: GP-TSC4503 You were checked out by: swhite You were checked in by: gm Total Balance Due: 0.00 Folio Summary 1/29/19 - 1/31/19 This rate is eligible for partner rewards. If this rate is changed, you may no longer be entitled to Choice Privileges points. If payment by credit card, I agree to pay the above total charge amount according to the card issuer agreement. Ii CHOICE privileges- " —Ana Congratulations. You are earning Choice Privileges Points for this stay. (278.67) 83.70 6.07 6.70 79.05 5.73 6.32 79.05 5.73 6.32 241.80 17.53 19.34 (278.67) Balance Due: 0.00 •�r` 71i Mr!'ar rr<,in hrr•t�wp., ��� {-10 7-:7S �: �3 .�;. ...f A+,, Z• /, 1 . i` a ry Luoe a I:rWr11a1rl1 ► Hi 11811ly's No a Steak WillMart • LTlIkaienvll.e Rd. HIIIBil1Y's BBO a Steak 1 l : � ry•rIL•LIIS llar:ElLlt[s 2AXSY S Lowel1. NC maPO Ncadenvllrye Ad. rt,, 1111 coots mill}, irrr. r ph 7(14-124- Iowa I 1, NC t 11rial AL Nair f ph 704-824-8f138 I . • :�,.ys' E ntn 111 44p11e IDe1 to. 4ar .. �riAu• , t i[ mllteeee7liil fF.s12.9 1 Therk you Far viaitlrlp E Iuto-eept+at 1 For: 9COTT 336 28 SM Th,rk Yal tar Yleltlrp lj`tls. iE 11RN111]il1 r 7,1a r For: SCOTT -- - att m1111 it aW001141 F 5.11 t .•-�-- - _ _ __ ' Ailr HNra..... f ..� 2.111 7A8L1 : %1117T 336 2604M - T �t � tmttsE Ilnlelelast F 1.N A r -, 3915 Corcoro Pkry S Your Salver was eriama Goopevn TABLE: SCOTT - 1 6=1 ` �� telrtsn 11_le Coreord NC 28GRi Your Server waa Adair Ashley ■ ' t l3 TAY 1 i.ill t y I.!! 1,78/2019 8:43:22 PM E ' 1 tA1 y t.1fr L 1.1T T0/-721-0592 Scouarice 1: 0000158 'ru.+.. - 1/31/2019 2:39:41 Fill +rSMd6 r T111L Wes � 10 /: 0341532 Ik"rlce 1: Olx)0083 3 ` } RLI lFEie 1il.1m 2 „• ATY PRICE 10 1:• 0342113 r ' tal11 Il1l• 111111111 t lllle111ra1 ITEM i lEF a alrululne -- i leas se • S41r11LSles1311 ..•._..-_.�"_..----•---...---"------- ITEM � OTY PRICE _ 1 �• ro1L11►tlmr • srlr +sy Ctk 9694 JanIB'19 11:4SAH Chopped Steak IaltEar sElrl[E • E 1 $11.99 •a: `� _ its IpN1111131111 Ileli Owls T • "tr -.7r - D 1 ne in Chapped steak 1 ;11,98 lCEECS1p1El41EE4 �- ' 1' IFI fllllial[f1i1Y1lEI '� •� 1 TLC Sand HL 5.49 1 DI aunlny $,9- Onions $0.99 r, � Isl71rH 11:11:17 + 1 Mae N Cheese. - Mac N Chasse. " 1 01111 on 41.aa Fries - Meshed Potatoes. Naanad Potatoes. i ,� +��, ■ [T[wl iris m Hli - 22 tk Uri Gravy TCI IISE Slur SLse 14/7 - _- * �'. a�l11A�q��p��•ap [��4I�yRya��y�W"qp� IIIguEI1r}1�1f ApI�11l� 1 Plate Neal G.w Open Ite11 A - t $0,00 A� l I�ttY111N1ilIllr FN1 �WgMIFCll1lll�li L 5 F1rp Plate 0.89 an 1,99 Tea 1 51.29. A Fries Mtotal' :15.96 Subtotal $14.97 t� WATCH OYM6,00". a Iie Arlek Total Texea 31.12 Total Taxes $1.05 i >r FOR FREE ,� MOVIES&TV 096 ISKIBMI It •'- - ..-.-.____ s tis,o2 3 ' Y Visa � Grand local SI7,1)e Credit Purchase + ' Only at Vudu.com/WatchFree Thus Payment $17.IT8 Name :CApo1[/T11tE1TNY Sbtotal 15.39 ilv' 00 CC Type =VISA Total Charsed: $20.OR EA'�,, Tax 1,08 "•, CC Num :xxxx xxxx wxxx 9850 Payment Paid by -------- �. Check "Tfi.4B Credit Putr3w+ae a* m@t Reference 4951OU .*� ---Jz Check Closed----,.-,--- Tx Trt1e :YiSA Approval :D5107D Gm ►rina yaq tma rrqu. E�eer qx_ . - anZB'19 t1:44AH -- Server :Adair Ashley Itr1111! It:11:4r . CC !gym .x x xxxx xxxx 9a'S. 0 Ticket Name :SCOTT .r 4 aKRTIMEI [la}an '�'*- Reterarlr;4gt14L { } Wit P Cassam ' r { ■ r �♦ - t a9aSn! Approya[ 063701i Payment Arrant: $16.02 t 1 li t Your check * is Please Come Blew Tip: I- ti'js • •: SuEalestmdLtID q1 =}5,98 -- �"" �77m m■+i' -I -'D"' : 1 v You could wrN1 15s 18f1 -T, ` Retelve 10 CRAhas t III $2.39H 5�2I.87 _ $3 19 1 r II Allai►wM - • 1WIr4 DAILYPlus Other great fYG i�III�II(I� Il19NNi�l x `',t ��� II�lIIIIII�IIIIIII INSTANT PRIZ>~S1. y 2fe° to LbY thek shown above, J z'JZ Ildl a r it 5 • + by coil itnp ourPlease Came Barhf �w 4 ^ Y Guest Satlsractlon Surrey at 'Cra[ker Barrel Store . 7`1 L f wagaetedltt1P eh $14.97 Charlotte, IC.81 i WI%I P.'BBIE B � iNEy ENTRY CoDEtwl Ik $2,25 S2.69 1112.99 �� lnwfzP]vwgSfOvl !!l CIA TM 10TT 1 __ _ bies 0�31 1�� � 4 1 I k1 3 + 4 l JAit30'19 12: �1eta rules, 11g if South Blvd 1 - ._.:.----• t3kes�perl` F ' 1 1 FF d10PS 3 YEG 1 ' 1J- t - mw•mYldxhY5vlalt.tam Ptorle:784 586-9100 •� , +Avarape retail value o}•rm+4trYI1omles,r 1 Ism fEA�MEEi z.59�•_ i ; 1 hl •l' i ; t, •; ' - c' 9M,33g Instant Arlias 1s;1,5D0 } % 1 rticu srLYE111A9E t 0.001r. Na str#wse/survey Web Pick U �] Sntah 14.38 rewired to enter. S■UMakea p Order 51 T1v # 2.00 OPMred by trvalhlca Irt. row iota, aair]�1 ti across multiple clients.` TTh�arHY CROa °� r 4 1i TChaaroed Tip 9, �2 THIS Inays RESTALRANT IS 336-25Q-45Q3 1 I ' E• ,~_ REF:207482 r �F► !A[1EKNIXNTty 0060 All} •3, `r l r -x AUp ro Aaonocoao31D1EIEI�iENt r11HAJAAMI NEW CUSTOMER !,. �' i:rl= t �' t t t TSI:E L� � FRAOIsj% LLC -• .. - 1COD000MOp(igTi50 `r�4► "�: MA 17.Si } 1 La s lip, Plrn %; •1736 :5 CLOSED JAH30 1:03R{ 410r191ne1 Cruat+a {.'• 9,99 1 Trraw* you ii ¢` ' PmPPeren4 1.79 r; 1- a + t ;y please Come Beck a +* :.- Beat 1.19 m1mr.0 asker8arrel.wm [ST.99 LARGE C+Y1ifYA. GlT) • , • u ; �. rr 1 1 i IL Wei s :! �,` ~' fi .a 911htdtal r t i Tax D..65 Tot1l g v , ' �'t . •; 1 'yt , CredltGrd 96% Pa .tia�' 4 . , r;• •- .. ti.. r r + r''1• `++; 17ent -aO y� •=��'' 5• •_} �.. l.� {` pa aunt Cepy 1;1 +•' _ i!•• 1 • •' •� `.',f-. Flay, •:ti �' ,. ....wa�i�� � ►- .f.4' 7:22 PIl 4 ; •; `. . 1 • 4 `. fUjj ,, YOU! i' Appendix L Applicable Historical Figure(s) and Table(s) EXXON° STATION 1 C3 0 pp� 8 ' lr r 1 7 41 To 1r� ra i r r 1 i 'rl;1 & 0 -- 5. --- - �.1z f SB-3(ND) 1ga' a • Se,2(NO) J LIGHT PALE "6SB-1(ND) MYd-17 ( .56.4(TID} CAROLINA FAST MART PIT STOP MI,V- ss-6 tNop MW-93: MW 1ti SB-7 (ND)fI s {Noj . aB ND S low f 1 � MW-10B CANOPY f i r AD) 10* (3TW-2 (ND) —.L— Si "F — �� Gi;— 7�:[ ...� �� �---- A.0 �i, SI U-E— C+E U-E— •YID. —. u ---._- v— v -- v *MW-15 �i Irtiw•a ---------R-O-W--------- U.S. HIGHWAY 29 LEGEND ® TYPE 11 MONITORING WELL TW TYPE III MONITORING NVELL FORMER MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED 3KTW TYPE III MONITORING WELL PAVED OVER OR UNABLE TO BE LOCATED WELL -CASING DAMAGED - ABANDONED UST UNDERGROUND STORAGE TANK FORMER UST LOCATION -- v -- WATER LINE U,+t-yes- GAS LINE -- E --- ELECTRIC POWER — OVIEWEAD ELECTRIC POWER' DRAINAGE FEATURE PROPERTY BOUNDARY -- —R=O-W — - — RIGHT-OF-WAY O LIGHT POLE a SOIL BORING 04309 CONSTITUENT CONCENTRATION ABOVE SOIL -TO -GROUNDWATER MSCC (rngfkg) (ND) CONSTITUENTS ANALYZED WERE BELOW METHOD DETECTION LIAIIITS AND/OR BELOW THE SITE APLICABLE RESIDENTIAL MAXIMUM SOIL CONTAMINANT CONCENTRATIONS (MSCCs) NOTES: 1.1 REFERENCE SITE -PLAN BY ENGINEERING TECTONICS,:P.A, DATED 07.07. 2. ALL LOCATIONS ARE APPROXIMATE, 3. SOIL BORINGS COLLECTED ON 09/04113. GROPHOC SCALE 0 10 20 30 .0 SCALE.- 1 In. _ 1A ft. C.4EEN ROADENGINEERING, SHIELDM9,".,- 39403OPR INC. "" "° r" "0`"' SOIL BORING CONSTITUENTS OF CONCERN CAROLINA FAST MART PIT STOP 3690 CONCORD PARKWAY SOUTH CONCORD, NORTH CAROLINA SHI£f-D s 1120116.01 DATE : 10/04/13 DRAWN BY: RBS SCALE: AS SHOWN FIGURE: 6 rA ID Ch w ccC7 ED G7 © GJ w� '3 ^ � tib VU it G1 w b GJ N — Cj C CA 9, a A A A a A J ? ? .F t•. C, "�' 7 u vi m n o Ln v i � rn 3 Ij Y." a' r: n I r N 01 ��, rn sJ Aliphatic C5-CS VPH In Z Z a ZZ Z Z Z Aliph, lit; C9-C12 (VPH) = a A W. o* 0 cr 0 O tS O.G Z .'� z r� C Z F L G7 G of i�o c. a Aliphatic CO-C19 (EP,H) = b Combined Allphics C9-Cl$ _ i C C v G v y a+b m O o z m Z 7' v. 'z X z z 0 zz z z z z z G z t� z C m AliphatiG C19•C3G (EPH) o o °7 X z 7 z= ra Aromatic`� c r.) * a rn * T c- -' eL •� c i7 Z ..-a 7 � Z � z x 7 z � L x Z a Z O Z C 'y 4 ,i ro Aromatic G11-C22 (EPH) = d w Combined Aromatics Cg-C22 c.d o N Z z z Acetone ' .� y • t7 a' r< F � x [3cn'r,.cne E 5 N x C ;J V, n-13 UI)'IbCll%ene p••r — C/) _ O vscu-13unaben2cnc: o v, n to > o z Z z z o tert-l3ulylb4nzr;nu n O. ^' ZXS tn t, t.+ z t7 o N N "z G z G Z ^v C O p aP N_] I'6:Ilunu - O w z O z Z z z z o L"th}'Ib nzene Z Z;C G a x Total Xylencs y • a, — -4 4 N bo N :� Z o z i Z 2 3 ]sn rp>, I p I v benzene o c v C. X W z _ o 0 x a p-lsopropylloluene Z o z 7 z z Mcthyl-Icrt-butyl cthcr C 7-= C 0 p x Methylene Chloride w z C C z j� Naphthalene u z a c o a `a 7- `3 n-['ropylbcnxcnc v. z z z L ro 1,2,4_T'rimrtlrylbcn-runc o W d T � rOO 1:3,5-Trimethylbenzenu m a z z z z z x Z p Y � z x zz x 0 z 0 z 0 tp s All Constituents D NO 0