Loading...
HomeMy WebLinkAbout1403_Caldwell_Foothills_MSWLF_Permit_WQMP_Phases1-5_FID1286868_20190325RUNNELS � LAMM113NS ENGINEERING March 20, 2019 North Carolina Department of Environmental Quality Division of Waste Management Asheville Regional Office 2090 U.S. Hwy 70 Swannanoa, North Carolina 28778 Attention: Ms. Jaclynne Drummond, Hydrogeologist Subject: Water Quality Monitoring Plan Submittal Foothills Regional MSW Landfill Facility Permit Number 1403-MSWLF-1998 Caldwell County, North Carolina BLE North Carolina Business Licenses C-284 & C-1538 BLE Project Number J15-1235-78/78A/78C Dear Ms. Drummond: Please find attached the Water Quality Monitoring Plan (WQMP) that includes the proposed Phase 5 development at the facility. Our original version of this document from October 2017 has been revised to include review comments from your March 8, 2018 NCDEQ letter and the comments we discussed during telephone conversations in January 2019. Language regarding laboratory testing for 1,4-dioxane has not been included in this WQMP. In accordance with the NCDEQ May 29, 2018 memorandum, sampling for two consecutive sampling events for 1,4-dioxane has been completed (Second Semi -Annual Event of 2018 and First Semi - Annual Event of 2019) and neither sampling event detected concentrations of 1,4-dioxane. Per a November 28, 2018 NCDEQ letter, if 1,4-dioxane was reported as non -detect in January 2019 at the facility, then the site could cease monitoring of the groundwater and surface water samples for 1,4- dioxane. Therefore, 1,4-dioxane will no longer be tested in the groundwater and surface water samples collected at the facility. However, in accordance with the November 28, 2018 NCDEQ letter, 1,4-dioxane will be analyzed annually in the leachate sample. If you have any questions concerning the project, please do not hesitate in contacting us at (864) 288- 1265. Sincerely, BUNNELL LAMMONs ENGINEERING INC. kd'e Mark S. Preddy, P.G. Senior Geologist Registered, North Carolina No. 1043 '6004 Ponders Court. Greenville, SC 29515 1,864.288.1265 44864.2B8.4430 ' info@bleCorPxorn BLECORPLOM WATER QUALITY MONITORING PLAN LANDFILL PHASES 1, 29 314, & 5 FOOTHILLS REGIONAL MSW LANDFILL CALDWELL COUNTY, NORTH CAROLINA FACILITY PERMIT NUMBER 1403-MSWLF-1998 qm7� REPUBLIC �a SERVICES i� Prepared For: Republic Services of North Carolina, LLC 1070 Riverside Drive Asheville, North Carolina 28804 BLE North Carolina Business Licenses C-284 & C-1538 BLE Project Number J15-1235-78/78A/78C October 20, 2017 (Revised March 20, 2019) CrA,,lppj�f = 1043 - YZof14 is in IM I BUNNELL LAMMONS ENGINEERING 6004 Ponders Court I Greenville, 5C 29615 864.288,1265 Fall 864,288,4330 Z info@blecorp.com BLECORP.COM � CANNONS ENGINEERING October 20, 2017 (Revised March 20, 2019) Republic Services of North Carolina, LLC 1070 Riverside Drive Asheville, North Carolina 28804 Attention: Mr. Derek Bouchard Environmental Manager Western North Carolina/Eastern Tennessee Subject: Water Quality Monitoring Plan: Landfill Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill Facility Permit Number 1403-MSWLF-1998 Caldwell County, North Carolina BLE North Carolina Business Licenses C-284 & C-1538 BLE Project Number J15-1235-78/78A/78C Mr. Bouchard: Bunnell-Lammons Engineering, Inc. (BLE) is pleased to present this Water Quality Monitoring Plan for the Foothills Regional MSW Landfill located in Caldwell County, North Carolina. This Plan is being submitted in general accordance with North Carolina Rules for Solid Waste Management, 15A NCAC 13B .0601, and .1630 through .1637 (groundwater) and 15A NCAC 13B .0602 (surface water). The Plan contained herein includes procedures performed at the facility in the past and incorporates the future development of landfill waste disposal area Phase 5. We appreciate the opportunity to serve as your geological consultant on this project and look forward to continue working with you at the Foothills Regional MSW Landfill. If you have any questions, please contact us at (864) 288-1265. Sincerely, e! CA Rf�� --*,es BUNNELL LANIMONS �,e�A �/ /'/ •O 1443 .e • s Mark S. Preddy, P.G. r�•�j ••,„ Q �,-Z Senior GeologistS. Registered, North Carolina I�b!Jl 43 r�"i I ` I �✓ (y///w/// Timothy J. Daniel Staff Geologist cc: Mr. K. Matthew Cheek, P.E. — Hodges, Harbin, Newberry & Tribble, Inc. Mr. Kevin Berry, P.E. — Hodges, Harbin, Newberry & Tribble, Inc. s:101 msp projects foothills mswlfncl1235-78c dhr-emp updatel3 wgmp11235-78cfoothil1s wgmpph 5 report revl.0.docx ' 6004 Ponders Court, Greenville, Sr 29615 °,-864.288J265 �']864.286.4430 P—MinfoCahleoorp.com BLECORRIMM 1s 1m 11 Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC TABLE OF CONTENTS October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C 1.0 INTRODUCTION......................................................................................................................... I 2.0 GEOLOGIC CONDITIONS.........................................................................................................2 3.0 WATER QUALITY MONITORING PLAN.............................................................................. 3 3.1 Groundwater Monitoring..............................................................................................................3 3.1.1 Monitoring Well Network.................................................................................................... 3 3.1.2 Changes in Groundwater Elevations................................................................................... 5 3.1.3 Monitoring Well Construction............................................................................................. 6 3.1.4 Monitoring Well Development............................................................................................. 6 3.1.5 Maintenance and Recordkeeping........................................................................................ 7 3.1.6 Monitoring Well Abandonment........................................................................................... 7 3.1.7 Detection Monitoring Program........................................................................................... 8 3.1.7.1 Sampling Frequency......................................................................................................... 9 3.1.7.2 Establishment of Background Data.................................................................................. 9 3.1.7.3 Evaluation of Detection Monitoring Data........................................................................ 9 3.1.8 Assessment Monitoring Program......................................................................................10 3.1.9 Groundwater Sampling Methodology...............................................................................11 3.1.9.1 Sample Collection...........................................................................................................11 3.1.9.1.1 Sampling Frequency.................................................................................................11 3.1.9.1.2 Static Water Elevations............................................................................................. 11 3.1.9.1.3 Well Evacuation........................................................................................................ 11 3.1.9.1.4 Sample Collection.....................................................................................................14 3.1.9.1.5 Decontamination.......................................................................................................14 3.1.9.2 Sample Preservation and Handling................................................................................ 15 3.1.9.3 Chain -of -Custody Program............................................................................................. 15 3.1.9. 3.1 Sample Labels...........................................................................................................15 3.1.9.3.2 Sample Seal...............................................................................................................15 3.1.9.3.3 Field Logbook...........................................................................................................15 3.1.9.3.4 Chain -of -Custody Record..........................................................................................16 3.1.9.4 Analytical Procedures.....................................................................................................16 3.1.9.5 Quality Assurance and Quality Control Program.......................................................... 17 3.1.10 Statistical Methods (Optional)...........................................................................................18 3.2 Surface Water Monitoring..........................................................................................................18 3.2.1 Sampling Locations............................................................................................................ 18 3.2.2 Monitoring Frequency.......................................................................................................18 3.2.3 Surface Water Sampling Methodology..............................................................................19 3.2.3.1 Sample Collection...........................................................................................................19 3.2.3.1.1 Dipper Method..........................................................................................................19 3.2.3.1.2 Direct Method...........................................................................................................19 3.2.3.1.3 Decontamination.......................................................................................................19 3.2.3.2 Sample Preservation and Handling................................................................................ 19 3.2.3.3 Chain -of -Custody Program............................................................................................. 20 3.2.3.3.1 Sample Labels........................................................................................................... 20 3.2.3.3.2 Sample Seal............................................................................................................... 20 3.2.3.3.3 Field Logbook........................................................................................................... 20 i of ii 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C 3.2.3.3.4 Chain -of -Custody Record.......................................................................................... 20 3.2.3.4 Analytical Procedures..................................................................................................... 20 3.2.3.5 Quality Assurance and Quality Control Program.......................................................... 20 3.3 Reporting......................................................................................................................................20 3.3.1 Monitoring Well Installation and Abandonment Reports ................................................ 20 3.3.2 Water Quality Reports........................................................................................................ 21 4.0 REFERENCES.............................................................................................................................22 TABLES Table 1 Summary of Groundwater Monitoring Well Construction Information Table 2 Sampling and Preservation Procedures FIGURES Figure 1 Site Location Map Figure 2 Environmental Monitoring System Figure 3 Groundwater Monitoring Well Detail APPENDICES Appendix A SWS Correspondence Regarding MW-3 and MW-3R Appendix B Existing Well Construction Records Appendix C NCDEQ Water Quality Analytical and Reporting Requirements Appendix D Environmental Monitoring Reporting Form Appendix E Low -Flow Groundwater Purging and Sampling Guidance ii of ii 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 1.0 INTRODUCTION October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C The existing Foothills Regional Municipal Solid Waste (MSW) Landfill is located on Cheraw Road approximately two miles northwest of Lenoir, North Carolina (Figure 1). The landfill is owned by Caldwell County and operated by Republic Services of North Carolina, LLC (Republic). The existing site consists of about 281.8 acres, which was formerly hardwood forest and abandoned plant nursery. Currently, Phases 1, 2, 3, and 4 at the landfill consists of Cells No. IAB, 2AB, 3AB/C, 4, 5A/B, and 8A. Republic now plans to develop Phase 5, which will consist of Cells No. 6, 7, and 8B at the facility. This Water Quality Monitoring Plan (WQMP) has been prepared to include procedures and locations for groundwater, underdrain, and surface water monitoring as required by the following North Carolina Solid Waste Management Rules (NCSWMR): • Groundwater —North Carolina Rules for Solid Waste Management, 15A NCAC 13B Rules .0601, and .1630 through .1637. • Surface Water —North Carolina Rules for Solid Waste Management, 15A NCAC 13B Rule. 0602. The WQMP contained herein is designed to detect and quantify contamination, as well as to measure the effectiveness of engineered disposal systems. The groundwater, underdrain, and surface water monitoring networks for this site have been designed to provide an early warning of a potential disposal system failure. The locations of the groundwater, underdrain, and surface water monitoring points are indicated on the attached Figure 2 titled Environmental Monitoring System. 1 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 2.0 GEOLOGIC CONDITIONS October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Geologic conditions for this site summarized herein are described in the Design Hydrogeologic Report (DHR), Phase 5 (Cells No. 6, 7, and 8B), Foothills Regional MSW Landfill, Caldwell County, North Carolina dated October 20, 2017 (BLE Project Number J15-1235-78/78A). The subject site is located within the Inner Piedmont Belt of the Piedmont Physiographic Province. The crystalline rocks of the Inner Piedmont Belt occur in generally northeast -southwest trending geologic belts in the Carolinas and consist of a stack of highly metamorphosed thrust sheets bound on the northwest by the Brevard Shear Zone and to the southeast by the Kings Mountain Shear Zone. The Inner Piedmont includes high-grade metamorphosed sedimentary and igneous rocks that have been exposed to multiple deformations (Horton and Zullo, 1991). Rock types that resulted from the multiple metamorphisms include gneiss, schist and amphibolite with northeast/southwest trending foliation with varying degrees of dip. Quaternary -age sediments consisting of sand and gravel fill the stream valleys. The geologic conditions encountered while drilling were often variable with boulders and seams of partially weathered rock occurring throughout the subsurface soil overburden profile. In general, four zones were encountered: 1) alluvial sediments in the lower elevation areas; 2) the residual soils from the weathered gneiss and schist; 3) the partially weathered rock; and 4) the fractured gneiss and schist bedrock. The alluvial soils were derived from the transport and deposition of sediment from on -site drainage features. The residual soil units were derived from the in -place chemical weathering of the underlying gneiss and schist bedrock in the surrounding region. Groundwater is present above the bedrock surface in the lower elevation areas of the site but occurs at or below the bedrock surface in higher elevation areas. The water -table aquifer across much of the site consists of the residual saprolitic soil, partially weathered rock, and fractured gneiss and schist bedrock. These units are hydraulically connected and thus comprise a single unconfined aquifer, although recharge rates, flow rates and storativity differ between the units based on the unique geologic conditions of each zone. The configuration of the water table surface is a subdued replica of the ground surface. The number, location, and placement of monitoring locations are recommended herein based on the site specific geologic and hydrogeologic site characteristics described in the current and prior DHR reports for the facility. 2 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.0 WATER QUALITY MONITORING PLAN October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C This Water Quality Monitoring Plan (WQMP) will serve as a guidance document for collecting and analyzing groundwater samples, evaluating the associated analytical results, and monitoring for any potential releases to the underlying unconfined aquifer from the Foothills Regional MSW Landfill. This WQMP complies with NCSWMR, Title 15A, Subchapter 13B Rules .0601, and .1630 through .1637 pertaining to groundwater monitoring, and the requirements for surface water monitoring specified in Rule .0602. 3.1 Groundwater Monitoring 3.1.1 Monitoring Well Network The proposed groundwater monitoring network for the Foothills Regional MSW Landfill is designed to monitor for potential releases to the uppermost aquifer at the site. The proposed network will consist of one upgradient well (MW-1R2), fourteen downgradient wells (MW-2R, MW-3R2, MW-4, MW-5, MW-6, MW-7, MW-8, MW-9, MW-10, MW-11, MW-12, MW-13, MW-14, and MW-15) and two downgradient underdrain monitoring points (UD-1 and UD-2). All monitoring locations currently exist except for MW- 12, MW-13, MW-14, and MW-15 (which will be installed in conjunction with Phase 5 development). The location of each well and underdrain is indicated on the Environmental Monitoring System (Figure 2). A description of each groundwater monitoring point in the network and the proposed sequence of installation is provided below. Monitoring Proposed and Existing Monitoring Well Location and Justification Location MW-1R2 Existing upgradient monitoring well set to intersect the groundwater in the bedrock unit (existing) upgradient and north of the facility's waste disposal units. MW-2R Existing downgradient monitoring well set to intersect the groundwater in the bedrock (existing) unit south of Cell No. 113. The well location is based on the local southward radial flow direction. The well is located approximately 90 feet from the waste footprint and intersects groundwater flow from the Cell No. I area. MW-3R2 Existing downgradient monitoring well set to intersect the groundwater in the bedrock (existing) unit south of Cell No. 113. The well location is based on the local southwestward radial flow direction. The well is located approximately 95 feet from the waste footprint and intersects groundwater flow from the Cells No. I and I areas. MW-4 Existing downgradient monitoring well set to intersect the groundwater in the saprolitic (existing) soil and bedrock units west of Cell No. IA. The well location is based on the local westward convergent flow direction and the sump location for Cell No. IA. The well is located approximately 70 feet from the waste footprint and intersects groundwater flow from the Cells No. 1A, 113, and 5A areas. MW-5 Existing downgradient monitoring well set to intersect the groundwater in the saprolitic (existing) soil unit west of Cell No. 2A. The well location is based on the local westward convergent flow direction and the sump location for Cell No. 2A. The well is located approximately 95 feet from the waste footprint and intersects groundwater flow from the Cells No. IA, 1B, 2A, 2B, and 5A areas. 3 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Monitoring Proposed and Existing Monitoring Well Location and Justification Location MW-6 Existing downgradient monitoring well set to intersect the groundwater in the saprolitic (existing) soil unit west of Cell No. 3A. The well location is based on the local westward convergent flow direction and the sump location for Cell No. 3A. The well is located approximately 75 feet from the waste footprint and intersects groundwater flow from Cells No. 3A, 313, 3C, and future Cell No. 5B. MW-7 Existing downgradient monitoring well set to intersect the groundwater west of Cell No. (existing) 4. The well location is based on the local convergent westward groundwater flow direction and the Cell No. 4 sump location. The well location is located approximately 130 feet from the waste footprint and intersects groundwater flow from Cells No. 4, 8A, and future Cells No. 6 and 7. MW-8 Existing downgradient monitoring well set to intersect the groundwater west of Cell No. (existing) 8A. The well location is based on the local westward groundwater flow direction. The well is located approximately 220 feet from the waste footprint for Cell No. 8A and 130 feet from the future Cell No. 8B. The well intersects groundwater flow from Cell No. 8A and future Cell No. 8B. MW-9 Existing downgradient monitoring well set to intersect the groundwater south of Cell No. (existing) 5A. The well location is based on the local southward groundwater flow direction and the Cell No. 5A sump location. The well location is approximately 70 feet from the waste boundary and intersects groundwater flow from Cell No. 5A, and future Cells No. 5B and 6. MW-10 Existing downgradient monitoring well set to intersect the groundwater southeast of Cell (existing) No. 5A. The well location is based on the local southeastward groundwater flow direction. The well location is approximately 85 feet from the waste boundary and intersects groundwater flow from Cell No. 5A and future Cells No. 5B and 6. MW-11 Existing downgradient monitoring well set to intersect the water table east of Cell No. (existing) 5B. The well location is based on the local convergent southeastward groundwater flow direction. The well location is approximately 70 feet from the waste boundary and intersects roundwater flow from Cells No. 5B and 6. MW-12 Proposed downgradient monitoring well set to intersect the water table east of Cell No. (proposed) 6. The well location is based on the local convergent southeastward groundwater flow direction. The well location will intersect groundwater flow from Cells No. 6 and 7. The well will be installed in conjunction with Cell No. 6 construction. MW-13 Proposed downgradient monitoring well set to intersect the water table east of Cell No. (proposed) 7. The well location is based on the local southeastward groundwater flow direction. The well location will intersect groundwater flow from Cell No. 7. The well will be installed in conjunction with Cell No. 7 construction. MW-14 Proposed sidegradient monitoring well set to intersect the water table north of Cell No. (proposed) 7. The well location is based on the local westward groundwater flow direction. The well location will intersect groundwater flow from Cell No. 7. The well will be installed in conjunction with Cell No. 7 construction. MW-15 Proposed sidegradient monitoring well set to intersect the water table north of Cell No. (proposed) 8B. The well location is based on the local westward groundwater flow direction. The well location will intersect groundwater flow from Cell No. 8B. The well will be installed in conjunction with Cell No. 8B construction. 4 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Monitoring I Proposed and Existing Monitoring Well Location and Justification Location UD-1 Existing underdrain downgradient monitoring point set to monitor an existing French (existing) drain discharge point. The monitoring point is located at the discharge outlet of the existing French drain west of Cell No. IA and near the outfall of Sediment Basin No. 1. This point monitors groundwater which is collected in the existing French drain piping network located under Cells No. IA, 1B, 2A, and 2B. UD-2 Existing underdrain downgradient monitoring point set to monitor an existing French (existing) drain discharge point. The monitoring point is located at the discharge outlet of the existing French drain west of Cell No. 4. This point monitors groundwater which is collected in the existing French drain piping network located under Cells No. 4 and 8A. The existing and proposed well locations are selected to yield groundwater samples representative of the conditions in the uppermost aquifer underlying the facility, and to monitor for potential releases from the landfill unit. Well placement, well construction methods, well development, well maintenance, and well abandonment procedures are discussed in the following sections. Groundwater monitoring wells shall be sampled during the active life of the landfill as well as the post -closure period, in accordance with 15A NCAC 13B Rule .1630 of the NCSWMR. Where accessible and practical, the new monitoring wells are proposed to be installed approximately halfway between the waste boundary and the relevant point of compliance (250 feet from the waste boundary). This midway distance of approximately 125 feet is informally referred to as the "review boundary". The purpose of the review boundary is to provide a method for early detection ahead of the relevant point of compliance limit in accordance with 15A NCAC 2L .0108. Monitoring wells MW-3 and MW-3R will remain on -site for water level monitoring in accordance with correspondence received from the North Carolina Solid Waste Section (SWS) on December 14, 2006. Approval for these two wells to be removed from the compliance network was included in the same correspondence. A copy of this letter is included in Appendix A of this report. 3.1.2 Changes in Groundwater Elevations After each sampling event, groundwater surface elevations will be evaluated to determine whether the monitoring system remains adequate, and to determine the rate and direction of groundwater flow. The direction of groundwater flow will be determined semiannually by comparing the groundwater surface elevations among the monitoring wells and constructing a groundwater surface elevation contour map. The groundwater flow rate shall be determined using the following modified Darcy equation: V= Ki n e where V = the groundwater flow rate (feet/day) K = the hydraulic conductivity (feet/day) i = the hydraulic gradient, Ah/Al (foot/foot) ne = the effective porosity of the host medium (unitless) Ah = the change in groundwater elevation between two wells or groundwater contours (feet) Al = the distance between the same two wells or groundwater contours (feet) 5 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C If the evaluation shows that the groundwater monitoring system does not satisfy the requirements of the NCSWMR, the monitoring system will be modified accordingly. These modifications may include a change in the number, location, and/or depth of the monitoring wells. 3.1.3 Monitoring Well Construction The well completion information for the existing groundwater monitoring wells are included on Table 1. The completed boring and well construction logs for the existing wells are included in the Appendix B. Boring logs/well construction records for proposed monitoring wells will be submitted to the SWS following installation. Drilling and installation of any new monitoring wells will be performed in accordance with the specifications outlined in 15A NCAC Subchapter 2C, Section .0100. Further guidance is provided in the Draft North Carolina Water Quality Monitoring Guidance Document for Solid Waste Facilities; Solid Waste Section, Division of Solid Waste Management; Department of Environment, Health and Natural Resources (March 1995). Each groundwater monitoring well will consist of 2-inch diameter polyvinyl chloride (PVC, Schedule 40 ASTM 480, NSF -rated) casing with flush -threaded joints installed in a 6.0-inch (or larger) nominal diameter borehole in soil or bedrock. The bottom 15-foot section of each well will be a manufactured well screen with 0.010-inch wide machined slots with a 0.20-foot long sediment trap threaded onto the bottom of the screen section. The screen section of each well will be set to intersect the water table in the residual soil or the water -producing fractures in the bedrock. Silica filter sand will be placed around the outside of the pipe up to approximately 2-feet above the top of the well screen. A hydrated bentonite seal will be installed on top of the filter sand backfill to seal the monitoring well at the desired level. The borehole will then be grouted with a bentonite-cement grout mixture up to the ground surface. The surface completion of each well consisted of a PVC cap and a lockable 4" x 4" x 5' standup protective steel cover, with a 3-foot by 3-foot concrete pad at the base of the steel cover. Each well will be constructed with a vent hole in the PVC casing near the top of the well and a weep hole near the base of the outer protective steel cover. An identification plate will be fastened to the protective steel cover that specifies the well identification number, drilling contractor, date installed, total depth, and construction details. A typical groundwater monitoring well construction detail is attached as Figure 3. A geologist or engineer will oversee drilling activities and prepare boring and well construction logs for each newly installed well. As -built locations of new wells will be located by a surveyor licensed in North Carolina to within +0.1 foot on the horizontal plane and +0.01 foot vertically in reference to existing survey points. A boring log, well construction log, groundwater monitoring network map, and well installation certification will be submitted to the SWS upon completion. 3.1.4 Monitoring Well Development Newly constructed wells will be developed to remove particulates that are present in the well due to construction activities, and to interconnect the well with the aquifer. Development of new monitoring wells will be performed no sooner than 24 hours after well construction. Wells may be developed with disposable bailers, a mechanical well developer, or other approved method. A surge block may be used as a means of assessing the integrity of the well screen and riser. In the event a pump is employed, the design of the pump 6 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C will be such that any groundwater that has come into contact with air is not allowed to drain back into the well. Each well will be developed until sediment -free water with stabilized field parameters (i.e., turbidity, temperature, pH, and specific conductance) is obtained. Well development equipment (bailers, pumps, surge blocks) and any additional equipment that contacts subsurface formations will be decontaminated prior to on -site use, between consecutive on -site uses, and/or between consecutive well installations. The purge water will be disposed on the ground surface at least 10 feet downgradient of the monitoring well being purged, unless field characteristics suggest the water will need to be otherwise disposed. If field characteristics suggest, the purge water will be containerized and disposed in the facility's leachate collection system, or by other approved disposal means. Samples withdrawn from the facility's monitoring wells should be clay- and silt -free; therefore, existing wells may require re -development from time to time based upon observed turbidity levels during sampling activities. If re -development of an existing monitoring well is required, it will be performed in a manner similar to that used for a new well. 3.1.5 Maintenance and Recordkeeping The existing monitoring wells will be used and maintained in accordance with design specifications throughout the life of the monitoring program. Routine well maintenance will include inspection and conrection/repair, as necessary, of identification labels, concrete aprons, locking caps and locks, and access to the wells. Should it be determined that background or compliance monitoring wells no longer provide samples representative of the quality of groundwater passing the relevant point of compliance, the SWS will be notified. The owner will re-evaluate the monitoring network, and provide recommendations to the SWS for modifying, rehabilitating, abandoning, or installing replacement or additional monitoring wells, as appropriate. Laboratory analytical results will be submitted to the SWS semiannually, along with sample collection field logs, statistical analyses (if used), groundwater flow rate and direction calculations, and a groundwater contour map as described in the following sections. Analytical data, calculations, and other relevant groundwater monitoring records will be kept throughout the active life of the facility and the post -closure care period, including notices and reports of any groundwater quality standards (15A NCAC 2L, .0202) exceedances, re -sampling notifications, and re -sampling results. 3.1.6 Monitoring Well Abandonment Piezometers and wells installed within the proposed landfill footprint will be properly abandoned in accordance with the procedures for permanent abandonment, as described in 15A NCAC 2C Rule .0113(b). The piezometers and wells will be progressively abandoned as necessary to complete construction activities. The piezometers and wells that are within the proposed footprint will be over -drilled to remove well construction materials, and then grouted with a cement-bentonite grout. Other piezometers and wells that will potentially interfere with clearing and construction activities will be grouted in place without over - drilling by grouting the well in place with a cement-bentonite grout and removing all surface features, such as concrete aprons, protective casings, and stickups. In each case, the bentonite content of the cement- 7 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C bentonite grout shall be approximately 5%, and a tremie pipe will be used to ensure that grout is continuously placed from the bottom of the borehole/monitoring well upward. If a monitoring well becomes unusable during the monitoring period of the landfill, the well will be abandoned in accordance with the procedures described above. Approval from the SWS will be obtained prior to abandoning any monitoring well. For each monitoring well abandoned, the following information will be provided to the SWS in a report sealed by a licensed geologist in accordance with 15A NCAC 13B Rule .1623 of the NCSWMR: the monitoring well name, a description of the procedure by which the monitoring well was abandoned, the date when the monitoring well was considered to be taken out of service, and the date when the monitoring well was abandoned. 3.1.7 Detection Monitoring Program Groundwater samples will be obtained and analyzed semiannually for the NCAppendix I list of constituents, as defined in the Detection Monitoring Program (15A NCAC 13B .1633), during the life of the facility and the post -closure care period. The SWS has issued six (6) memoranda concerning guidelines for electronic submittal of monitoring data and environmental reporting limits and standards for constituents. Those memoranda include: • New Guidelines for Electronic Submittal of Environmental Monitoring Data (dated October 27, 2006). • Addendum to the October 27, 2006 North Carolina Solid Waste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data (dated February 23, 2007). • Environmental Monitoring Data for North Carolina Solid Waste Facilities (dated October 16, 2007). • Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal (dated November 5, 2014). • North Carolina Solid Waste Section Memorandum Regarding Guidelines for 14-Day Notification of Groundwater Exceedances Form Submittal per rule: 15A NCAC IB .1633(c)(1) (dated September 9, 2016). The SWS has also issued a Solid Waste Environmental Monitoring Reporting Limits and Standards — Constituent List which consolidates reporting standards and limits for each required constituent. Copies of the memoranda and constituent list are included in Appendix C. The results of the groundwater data (and statistical analysis, if the owner so chooses to perform) will be submitted to the SWS semiannually. The reports will be submitted in electronic format (pdf format via CD-ROM or email, or other NCDEQ appropriate electronic method) in accordance with applicable guidance to the SWS and accompanied by the required Environmental Monitoring Reporting Form, which will be signed and sealed by a licensed geologist in the State of North Carolina. A copy of this form is also included in Appendix D for reference. 8 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.1.7.1 Sampling Frequency October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Groundwater samples will be collected semiannually and analyzed for NC Appendix I Detection Monitoring constituents (Appendix C) plus required field parameters, including but not limited to, turbidity, pH, conductivity, and temperature. Once a new monitoring well is installed, it will be sampled four times during a six-month period; a minimum of one of the four background sampling events will be collected prior to waste placement in the new cell that the new monitoring well is associated with. After the initial four sampling events during the six-month period, a new monitoring well then be sampled one time during each semiannual period thereafter. If the facility's groundwater monitoring program must progress to Assessment Monitoring, notification and sampling will be conducted according to the schedule specified in 15A NCAC 13B Rule .1634. 3.1.7.2 Establishment of Background Data As mentioned in Section 3.1.7.1, once a new monitoring well is installed, it will be sampled four times during a six-month period; a minimum of one of the four background sampling events will be collected prior to waste placement in the new cell that the new monitoring well is associated with as specified in the Permit, once issued by the SWS. Samples collected from these wells will be analyzed for the NCAppendix I constituents. The intent of background sampling is to collect data to more accurately reflect the natural fluctuations that may occur with these constituents. The data will be submitted to the SWS after completing the fourth background sampling event. 3.1.7.3 Evaluation of Detection Monitoring Data If the owner or operator determines that there is an exceedance of a groundwater protection standard (i.e., the groundwater protection standards (15A NCAC 2L, .0202); a 2L Interim Maximum Allowable Concentration; a groundwater protection standard calculated by the SWS; or a site -specific statistical background level approved by the SWS) for one or more of the constituents in the NC Appendix I list of constituents (Appendix C) at any monitoring well, the following procedures will be performed: 1) Follow the guidance and notification procedures in NCDEQ's September 2016 memorandum regarding Guidelines for 14-Day Notification of Groundwater Exceedances (included in Appendix C). 2) Within 90 days, establish an Assessment Monitoring Program meeting the requirements of 15A NCAC 13B Rule .1634, except as discussed below. The data may be re-evaluated within 90 days to determine that a source other than a landfill unit caused the exceedance, or the exceedance resulted from an error in sampling, analysis, or natural variation in groundwater quality. If it can be demonstrated that one of these factors occurred, a report (Alternate Source Demonstration) certified by a North Carolina licensed geologist or engineer will be submitted to the SWS within 90 days. A copy of this report will be placed in the operating record. If the SWS approves the demonstration, the Detection Monitoring Program will be resumed with the required semiannual sampling and analysis. If the SWS does not accept the demonstration within 90 days, the Assessment Monitoring Program will be initiated. 9 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.1.8 Assessment Monitoring Program October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Assessment Monitoring (15A NCAC 13B .1634) is required whenever a violation of the groundwater quality standards (15A NCAC 2L, .0202) has occurred, and no source of error, alternate source, or naturally occurring condition can be identified. Within 90 days of triggering the Assessment Monitoring Program, and annually thereafter, groundwater will be sampled for analysis of the NC Appendix II list of constituents. A minimum of one groundwater sample will be collected from each well and submitted for analysis during each Assessment Monitoring sampling event. However, the NCSWMR allow for petitions to the SWS for an appropriate subset of wells or a reduction in the NC Appendix II sampling list. If any NC Appendix II constituents are detected in groundwater from the downgradient wells, a minimum of four independent samples will be collected from each background and downgradient well to establish background concentrations for the detected NC Appendix II constituents. Within 14 days after receipt of the initial or subsequent sampling analytical data, a report identifying the detected NC Appendix II constituents will be submitted to the SWS in accordance with the guidance and notification requirements in NCDEQ's September 9, 2016 memorandum included in Appendix C, and a notice will be placed in the operating record. Background concentrations of any detected NC Appendix II constituents will be established and reported to the SWS. Within 90 days, and on at least a semiannual basis thereafter, the wells will be sampled and analyzed for the NC Appendix I list plus any additional detected NC Appendix II constituents. An analytical results report of each sampling event will be submitted to the SWS and placed in the landfill facility operating record. The SWS will determine whether Groundwater Protection Standards must be established for the facility (15 NCAC 13B .1634(g) and (h)) and may specify a more appropriate alternate sampling frequency for repeated sampling and analysis for the full set of NC Appendix II constituents. Groundwater monitoring will continue in one of two ways, based on the results of the water quality analyses: 1) If the NC Appendix II constituent concentrations are equal to or less than the approved Groundwater Protection Standards for two consecutive sampling events, the facility may return to Detection Monitoring with the approval of SWS. 2) If one or more NC Appendix II constituents are detected in excess of the approved Groundwater Protection Standards, and no source of error can be identified, within 14 days the SWS will be notified in accordance with the guidance and notification requirements in NCDEQ's September 9, 2016 memorandum included in Appendix C, a notice will be placed in the operating record, and appropriate local government officials will be notified. In addition, the facility will initiate an Assessment of Corrective Measures, conduct a public meeting, submit a North Carolina Solid Waste Groundwater Corrective Action Permit Modification Application selection of remedy, and submit a Corrective Action Plan in accordance with the NC Solid Waste Section Guidance for Corrective Action at Solid Waste Facilities. Refer to Appendix C of this WQMP for a list of the required constituents, analytical methods, and reporting limits. These lists were updated in the October 27, 2006 memorandum and February 23, 2007, addendum, from the SWS. The results of the groundwater data will be submitted to the SWS semiannually. The reports 10 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C will be submitted in electronic format (pdf format via CD-ROM or email, or other NCDEQ appropriate electronic method) with analytical data submitted in the required format and be accompanied by the required Environmental Monitoring Reporting Form, which will be signed and sealed by a licensed geologist or engineer in the State of North Carolina. A copy of this form is also included in Appendix D. 3.1.9 Groundwater Sampling Methodology Groundwater samples will be collected in accordance with Solid Waste Management Rules 15A NCAC 13B Rule .1632 and guidance provided in the Solid Waste Section Guidelines For Groundwater, Soil, and Surface Water Sampling (Rev 4-08). Procedures for well purging, sample withdrawal, and decontamination methods as well as chain -of -custody procedures are outlined below. Field parameter measurements will be submitted electronically to the SWS in a format consistent with that required in the October 27, 2006, memorandum and February 23, 2007 addendum. 3.1.9.1 Sample Collection The procedures for collecting groundwater samples are presented below, which include sampling frequency, water level measurements, well evacuation, low -flow purging, sample collection, and decontamination. The background well (MW-1R2) will be sampled first, followed by the downgradient compliance wells. The downgradient wells will be sampled so that the most contaminated well, if one is identified from the previous sampling event, is sampled last. Samples will also be collected from the underdrain drain discharge points (UD-1 and UD-2). Sampling procedures for the underdrain drain discharge points should follow surface water sampling procedures specified in Section 3.Z3 below. 3.1.9.1.1 Sampling Frequency The above -mentioned samples will be collected on a semiannual basis during the Detection and/or Assessment Monitoring programs. 3.1.9.1.2 Static Water Elevations The static water level and total well depth will be measured with an electronic water level indicator, to the nearest 0.01 foot, in each well prior to sampling. Static water elevations will be calculated from water depth measurements and top of casing elevations. A reference point will be marked on the top of casing of each well to ensure the same measuring point is used each time static water levels are measured. If a monitoring well contains a dedicated pump, the depth to water shall be measured without removing the pump. Depth to bottom measurements should be taken from the well construction data and updated when pumps are removed for maintenance. 3.1.9.1.3 Well Evacuation The preferred well evacuation and sampling procedure for the site is a low -flow purge (micropurge) and sample methodology. However, in the event of a pump malfunction or other field condition that will not allow this type of purging, standard evacuation procedures are presented below. 11 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.1.9.1.3.1 Standard Evacuation Procedures October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C In the event that low -flow purging and sampling cannot be employed, monitoring wells will be evacuated with a submersible pump or a disposable bailer. If the pump is used for multiple wells, it and any other non -dedicated equipment will be decontaminated before use and between each well. A low -yield well (one that yields less than 0.5 gallon per minute) will be purged so that water is removed from the bottom of the screened interval. Low -yield wells will be evacuated to dryness once. However, at no time will a well be evacuated to dryness if the recharge rate causes the formation water to vigorously cascade down the sides of the screen and cause an accelerated loss of volatiles. Upon recharging of the well and no longer than a time period of 24 hours after purging, the first sample will be field-tested for turbidity, pH, temperature, and specific conductivity. Samples will then be collected and containerized in the order of the volatilization sensitivity of the target constituents. A high -yield well (one that yields 0.5 gallon per minute or more) will be purged so that water is drawn down from above the screen in the uppermost part of the water column to ensure that fresh water from the formation will move upward in the screen. If a pump is used for purging, a high -yield well should be purged at less than 4 gallons per minute to prevent further well development. A minimum of three casing volumes will be evacuated from each well prior to sampling. An alternative purge will be considered complete if the monitoring well goes dry before removing the calculated minimum purge volume. The well casing volume for a 2 inch well will be calculated using the following formula: where: Vc (gallons) = 0.163 x hW V, = volume in the well casing = (dc2/4) x 3.14 x hW x 7.48 gallons/cubic foot) dc = casing diameter in feet (dc = 0.167) hW = height of the water column (i.e., well depth minus depth to water) The purge water will be disposed by pouring on the ground surface at least 10 feet downgradient of the monitoring well being purged, unless field characteristics suggest the purge water may be contaminated. In that case, the purged water will be containerized and disposed in the facility's leachate collection system (or by other approved disposal means). The monitoring wells will be sampled using disposable bailers within 24 hours of completing the purge. The bailers will be equipped with a check valve and bottom -emptying device. The bailer will be lowered gently into the well to minimize the possibility of degassing the water. Field measurements of turbidity, pH, temperature, and specific conductivity will be made before and after sample collection as a check on the stability of the groundwater sampled over time. The direct -reading equipment used at each well will be calibrated in the field according to the manufacturer's specifications prior to each day's use. Calibration information should be documented in the instrument's calibration logbook and the field book. 3.1.9.1.3.2 Low -Flow Procedures Under normal conditions, monitoring wells will be purged and sampled using the low -flow sampling method in accordance with the United States Environmental Protection Agency's (EPA) Low -Flow 12 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C (Minimal Dawwdown) Sampling Procedures (April 1996), as allowed under the NCSWMR. A summary of these procedures is listed below, and a copy of the procedures is presented in Appendix E. Depth -to -water measurements will be obtained using an electronic water level indicator capable of recording the depth to an accuracy of 0.01 foot. A determination of whether or not the water table is located within the screened interval of the well will be made. If the water table is not within the screened interval, the amount of drawdown that can be achieved before the screen is intersected will be calculated. If the water table is within the screened interval, total drawdown should not exceed 1 foot so as to minimize the amount of aeration and turbidity. If the water table is above the top of the screened interval, the amount of drawdown should be minimized to keep the screen from being exposed. If the purging equipment is non -dedicated, the equipment will be lowered into the well, taking care to minimize the disturbance to the water column. If conditions (i.e., water column height and well yield) allow, the pump will be placed in the uppermost portion of the water column (minimum of 18 inches of pump submergence is recommended). The minimum volume/time period for obtaining independent Water Quality Parameter Measurements (WQPM) will be determined. The minimum volume/time period is determined based on the stabilized flow rate and the amount of volume in the pump and the discharge tubing (alternatively, the volume of the flow cell can be used, provided it is greater than the volume of the pump and discharge tubing). Volume of the bladder pump should be obtained from the manufacturer. Volume of the discharge tubing is as follows: 3/8-inch inside diameter tubing: 20 milliliters per foot 1/4-inch inside diameter tubing: 10 milliliters per foot 3/16-inch inside diameter tubing: 5 milliliters per foot Once the volume of the flow -cell or the pump and the discharge tubing has been calculated, the well purge will begin. The flow rate should be based on historical data for that well (if available) and should not exceed 500 milliliters per minute. The initial round of WQPM should be recorded and the flow rate adjusted until drawdown in the well stabilizes. Water levels should be measured periodically to maintain a stabilized water level. The water level should not fall within 1 foot of the top of the well screen. If the purge rate has been reduced to 100 milliliters or less and the head level in the well continues to decline, the required water samples should be collected following stabilization of the WQPM, based on the criteria presented below. If neither the head level nor the WQPM stabilize, a passive sample should be collected. Passive sampling is defined as sampling before WQPM have stabilized if the well yield is low enough that the well will purge dry at the lowest possible purge rate (generally 100 milliliters per minute or less). WQPM stabilization is defined as follows: • pH (+/- 0.2 S.U.); • conductance (+/- 10% of reading); • temperature (+/- 10% of reading or 0.20C); • Optional: dissolved oxygen (DO) may also be measured and ideally should fall within +/- 10% of reading or 0.2 mg/L (whichever is greater); however, this is not a required field parameter; and • Optional: oxidation reduction potential (ORP) may also be measured and ideally should also fall within +/- 10% of reading; however, this is not a required field parameter. 13 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C Stabilization of the WQPM should occur in most wells within five to six rounds of measurements. If stabilization does not occur following the removal of a purge volume equal to three well volumes, a passive sample will be collected. At a minimum, turbidity measurements should also be recorded at the beginning of purging, following the stabilization of the WQPM, and following the collection of the samples. The optimal turbidity range for micropurging is 25 NTU or less. Turbidity measurements above 25 NTU are generally indicative of an excessive purge rate or natural conditions related to excessive fines in the aquifer matrix. The direct -reading equipment used at each well will be calibrated in the field according to the manufacturer's specifications prior to each day's use and checked at a minimum at the end of each sampling day. Calibration information should be documented in the instrument's calibration logbook and the field book. Each well is to be sampled immediately following stabilization of the WQPM. The sampling flow rate must be maintained at a rate that is less than or equal to the purging rate. For volatile organic compounds, lower sampling rates (100 - 200 milliliters/minute) should be used. Final field parameter readings should be recorded prior to and after sampling. 3.1.9.1.4 Sample Collection Samples will be collected and containerized in the order described below. • Volatile Organic Compounds (SW-846 Method 8260); • Semi -Volatile Organic Compounds (SW-846 Method 8270); • Herbicides (SW-846 Method 8151); • Pesticides (SW-846 Method 8080); • Polychlorinated Biphenyls (PCBs; SW-846 Method 8082); • Cyanide and Sulfide; and • Total Metals. Total metals samples may be collected out of sequence if the turbidity increases during sample collection. Samples will be transferred directly from field sampling equipment into pre -preserved, laboratory -supplied containers. Containers for volatile organic analyses will be filled in such a manner that no headspace remains after filling. 3.1.9.1.5 Decontamination Non -dedicated field equipment that is used for purging or sample collection shall be cleaned with a phosphate -free detergent, and triple -rinsed with distilled water. Any disposable polyethylene tubing used with non -dedicated pumps should be discarded after use at each well. Clean, chemical -resistant nitrile gloves will be worn by sampling personnel during well evacuation and sample collection. Measures will be taken to prevent surface soils, which could introduce contaminants into the well being sampled, from coming in contact with the purging and sampling equipment. 14 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.1.9.2 Sample Preservation and Handling October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Upon containerizing the water samples, the samples will be packed into pre -chilled, ice -filled coolers and either hand -delivered or shipped overnight by a commercial carrier to the laboratory for analysis. Sample preservation methods will be used to retard biological action and hydrolysis, as well as to reduce sorption effects. These methods will include chemical preservation, cooling/refrigeration at 4° C, and protection from light. The type of sample container, minimum volume, chemical preservative, and holding times for each analysis type are provided in Table 2. 3.1.9.3 Chain -of -Custody Program The chain -of -custody program will allow for tracing sample possession and handling from the time of field collection through laboratory analysis. The chain -of -custody program includes sample labels, sample seal, field logbook, and chain -of -custody record. 3.1.9.3.1 Sample Labels Legible labels sufficiently durable to remain legible when wet will contain the following information: • Site identification; • Sampling location identifier; • Date and time of collection; • Name of collector; • Parameters to be analyzed; and • Preservative, if applicable. 3.1.9.3.2 Sample Seal The shipping container will be sealed to ensure that the samples have not been disturbed during transport to the laboratory. The tape used to seal the shipping container will be labeled with instructions to notify the shipper if the seal is broken prior to receipt at the laboratory. 3.1.9.3.3 Field Logbook The field logbook will contain sheets documenting the following information: • Identification of the well; • Well depth; • Field meter calibration information; • Static water level depth and measurement technique; • Purge volume (given in gallons); • Time well was purged; • Date and time of collection; • Well sampling sequence; • Types of sample containers used and sample identification numbers; • Preservative used; • Field analysis data and methods; • Field observations on sampling event; 15 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C Name of collector(s); and Climatic conditions including air temperatures and precipitation. 3.1.9.3.4 Chain -of -Custody Record The chain -of -custody record is required for tracing sample possession from time of collection to time of receipt at the laboratory. A chain -of -custody record will accompany each individual shipment. The record will contain the following information: • Sample destination and transporter; • Sample identification numbers; • Signature of collector; • Date and time of collection; • Sample type; • Identification of well; • Number of sample containers in shipping container; • Parameters requested for analysis; • Signature of person(s) involved in the chain of possession; • Inclusive dates of possession; and • Internal temperature of shipping container upon opening in laboratory (noted by the laboratory). A copy of the completed chain -of -custody form will accompany the shipment and will be returned to the shipper after the shipping container reaches its destination. The chain -of -custody record will also be used as the analysis request sheet. 3.1.9.4 Analytical Procedures A laboratory certified by the North Carolina Department of Environmental Quality (DEQ) will be utilized for analysis of groundwater and surface water samples from the facility. Analyses will be performed in accordance with U.S. EPA SW 846 methods detailed in the EPA guidance document (EPA, 2014). For Detection Monitoring, method numbers and reporting limits to be used will be those listed in the October 27, 2006, SWS memorandum, which is titled New Guidelines for Electronic Submittal of Environmental Monitoring Data, is included in Appendix C of this WQMP. Alternate SW 846 methods may be used if they have the same or lower reporting limit. The laboratory must report any detection of any constituent even if it is detected below the solid waste reporting limit (as revised in the October 27, 2006, memorandum). Monitoring parameters are also included in Appendix C of this WQMP, along with the proposed analytical methods and reporting limits. The laboratory certificates -of -analyses shall, at a minimum, include the following information: Narrative: Must include a brief description of the sample group (number and type of samples, field and associated lab sample identification numbers, preparation and analytical methods used). The data reviewer shall also include a statement that all holding times and Quality Control (QC) criteria were met, samples were received intact and properly preserved, with a brief discussion of any deviations potentially affecting data usability. This includes, but is not limited to, test method deviation(s), holding time violations, out -of -control incidents occurring during the processing of QC or field samples and corrective actions taken, and repeated analyses and reasons for the re- analyses (including, for example, contamination, failing surrogate recoveries, matrix effects, or 16 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C dilutions). The narrative shall be signed by the laboratory director or authorized laboratory representative, signifying that all statements are true to the best of the reviewer's knowledge, and that the data meet the data quality objectives as described in this plan (except as noted). One narrative is required for each sample group. • Original Chain -of Custody Form. • Analyte List: The laboratory shall list all analytes for which the samples were analyzed. The list is typically included as part of the analytical reporting forms. • Dilution factors with a narrative of the sample results, including the reasons for the dilution (if any). • Blank Data: For organic analyses, the laboratory shall report the results of any method blanks, reagent blanks, trip blanks, field blanks, and any other blanks associated with the sample group. For inorganic analyses, the laboratory shall provide the results of any preparation or initial calibration blanks associated with the sample group. • QC Summary: The laboratory will provide summary forms detailing laboratory QC sample results, which include individual recoveries and relative percent differences (if appropriate) for the following Quality Assurance (QA)/QC criteria: surrogates, MS analyses, MSD analyses, LCS, and sample duplicate analyses. QC control limits shall also be reported; if any QC limits are exceeded, a flag or footnote shall be placed to indicate the affected samples. Additional QA data and/or other pertinent data may be reported as requested by the owner/operator of the facility. 3.1.9.5 Quality Assurance and Quality Control Program Trip and field blanks will be collected and analyzed during each monitoring event to verify that the sample collection and handling process has not affected the quality of the samples. The trip blank will be prepared in the laboratory each time a group of VOA bottles is prepared for use in the field. The appropriate number of bottles for VOA analysis will be filled with Type II reagent grade water, transported to the site, handled like the samples, and shipped to the laboratory for analysis. The field blank will be prepared in the field and exposed to the sampling environment. As with all other samples, the time of the blank exposure will be recorded so that the sampling sequence is documented. The field blank will be analyzed for the same list of constituents as the groundwater samples. The trip blank will be analyzed for volatile organic compounds only. A minimum of one trip blank per cooler or one trip blank per cooler that contains volatile organic compounds should be utilized. A minimum on one field blank per sampling event should be utilized. The assessment of blank analysis results will be in general accordance with EPA guidance documents (EPA, 1993 and 1994). No positive sample results will be relied upon unless the concentration of the compound in the sample exceeds 10 times the amount in any blank for common laboratory contaminants (see next paragraph), or five times the amount for other compounds. If necessary, re -sampling will be performed as necessary to confirm or refute suspect data; such re -sampling will occur within the individual compliance monitoring period. 17 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C Concentrations of any contaminants found in the blanks will be used to qualify the groundwater data. Any compound (other than those listed below) detected in the sample, which was also detected in any associated blank, will be qualified `B" when the sample concentration is less than five times the blank concentration. For common laboratory contaminants (methylene chloride, acetone, 2-butanone, and common phthalate esters), the results will be qualified `B" when the reported sample concentration is less than 10 times the blank concentration. The `B" qualifier designates that the reported detection is considered to represent cross -contamination and that the reported constituent is not considered to be present in the sample at the reported concentration. 3.1.10 Statistical Methods (Optional) If the landfill owner or operator chooses, groundwater monitoring data for landfill compliance wells screened in the uppermost aquifer may be evaluated using statistical procedures for inorganics. However as specified in the NCSWMR, this is optional (not required) under 15A NCAC 13B .1632(g). The statistical test used to evaluate the groundwater monitoring data will be the prediction interval procedure unless the test is inappropriate with the data collected. If statistical evaluation of groundwater monitoring data is selected, it will be performed in compliance with 15A NCAC 13B Rule .1632 (g), (h), and (i) and the USEPA's Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities, Unified Guidance, Office of Solid Waste, Waste Management Division, US EPA, dated March 2009. 3.2 Surface Water Monitoring 3.2.1 Sampling Locations In accordance with 15A NCAC 13B Rule .0602 of the NCSWMR, seven surface water monitoring locations have been established for the facility to monitor water quality surrounding the proposed and existing waste footprint. There are five existing surface water sampling locations associated with Phases 1, 2, 3, and 4. Two additional surface water location (SW-6 and SW-7) will be added with the development of Phase 5. These seven locations are sufficient to monitor the upgradient (SW-1 and SW-3) and downgradient (SW- 2, SW-4, SW-5, SW-6, and SW-7) surface water for landfill Phases 1 through 5 and will be sampled as part of the monitoring network for this facility. The locations of these monitoring points are shown on the attached Figure 2 titled Environmental Monitoring System. 3.2.2 Monitoring Frequency The surface water sampling locations will be sampled semiannually for analysis of the NC Appendix I list of constituents (Appendix C) and required water quality parameters (pH, specific conductivity, temperature, and turbidity). The results of the analysis of the surface water data will be submitted to the SWS semiannually in conjunction with the groundwater data. 18 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.Z3 Surface Water Sampling Methodology October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C The surface water samples should be collected using the Dipper Method or the Direct Method described below. In surface water sampling, extreme care must be used to obtain a representative sample. The greatest potential source of inadvertent sample contamination is incorrect handling by field personnel. Therefore, extreme care should be used during sample collection to minimize the potential for inadvertent contamination. 3.2.3.1 Sample Collection Surface water samples will be obtained from areas of minimal turbulence and aeration. Samples will only be collected if flowing water is observed during the sampling event. 3.2.3.1.1 Dipper Method A dip sampler is useful for situations where a sample is to be recovered from an outfall pipe or where direct access is limited. The long handle on such a device allows sample collection from a discrete location. Sampling procedures are as follows: 1. Assemble the dip sampler device in accordance with the manufacturer's instructions. 2. Extend the device to the sample location and collect the sample. 3. Retrieve the sampler and transfer the sample to the appropriate sample container. 3.2.3.1.2 Direct Method The sampler should face upstream and collect the sample without disturbing the sediment. The collector submerses the closed sample container, opens the bottle to collect the sample and then caps the bottle while sub -surface. The collection bottle may be rinsed two times by the sample water. Collect the sample under the water surface avoiding surface debris. When using the direct method, pre -preserved sample bottles should not be used because the collection method may dilute the concentration of preservative necessary for proper sample preservation. Samples will be collected using dedicated, clean, laboratory -provided bottles, and then the samples are carefully transferred into the pre -preserved bottles for transport to the laboratory. 3.2.3.1.3 Decontamination Non -dedicated field equipment that is used for sample collection shall be cleaned with a phosphate -free detergent, and triple -rinsed with distilled water. Clean, chemical -resistant nitrile gloves will be worn by sampling personnel during sample collection. Measures will be taken to prevent surface soils, which could introduce contaminants into the location being sampled, from coming in contact with the sampling equipment. 3.2.3.2 Sample Preservation and Handling The procedures for sample preservation and handling are specified above in Section 3.1.9.2. 19 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 3.2.3.3 Chain -of -Custody Program October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C The chain -of -custody program will allow for tracing sample possession and handling from the time of field collection through laboratory analysis. The chain -of -custody program includes sample labels, sample seal, field logbook, and chain -of -custody record. 3.2.3.3.1 Sample Labels The procedures for labeling sample containers are specified above in Section 3.1.9.3.1. 3.2.3.3.2 Sample Seal The procedures for shipping container sealing are specified above in Section 3.1.9.3.2. 3.2.3.3.3 Field Logbook The field logbook will contain sheets documenting the following information: • Sampling location identifier; • Flow conditions observations; • Field meter calibration information; • Date and time of collection; • Sequence of sampling locations; • Types of sample containers used and sample identification numbers; • Preservative used; • Field analysis data and methods; • Field observations on sampling event; • Name of collector(s); and • Climatic conditions including air temperatures and precipitation. 3.2.3.3.4 Chain -of -Custody Record The chain -of -custody record requirements are specified above in Section 3.1.9.3.4. 3.2.3.4 Analytical Procedures Laboratory analytical requirements are specified above in Section 3.1.9.4. 3.2.3.5 Quality Assurance and Quality Control Program The Quality Assurance and Quality Control Program is specified above in Section 3.1.9.5. 3.3 Reporting 3.3.1 Monitoring Well Installation and Abandonment Reports Groundwater monitoring well installation and abandonment reports will be prepared upon completion of well installation or abandonment prior to waste disposal into a new cell in accordance with the phased 20 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 October 20, 2017 (Revised March 20, 2019) Foothills Regional MSW Landfill — Caldwell Co., NC BLE Project No. J15-1235-78178AI78C landfill construction for Phase 5. The monitoring well installation reports will include documentation of boring logs, probe diagrams, development results, and field procedures. The abandonment reports will include documentation of abandonment logs and field procedures. Monitoring well installation and abandonment reports will be submitted in electronic format (pdf format via CD-ROM or email, or other NCDEQ appropriate electronic method) in accordance with applicable guidance to the SWS, and if physical copies are required, they will be sent to the SWS at the following address: North Carolina Department of Environmental Quality Division of Waste Management — Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 Additionally, copies of all installation and abandonment reports will be kept at the landfill as part of the facility's operating record. 3.3.2 Water Quality Reports Copies of all laboratory analytical data will be forwarded to the SWS within 120 calendar days of the sampling event (15A NCAC 13B .1632(i)), or as specified in the facility's permit, whichever is less. The analytical data submitted will specify the date of sample collection, the sampling point identification, and include a map of sampling locations. Should a concentration be detected above a North Carolina groundwater or surface water action level as defined in North Carolina Solid Waste Management Rules, Groundwater Quality Standards, or Surface Water Quality Standards, the owner/operator of the landfill shall notify the SWS and will place a notice in the landfill facility operating record as to which constituents were detected; these notification and reporting requirements are specified in the SWS memoranda in Appendix C. All monitoring reports will be submitted with the following: 1. A USGS map showing the location of the site; 2. A potentiometric surface map for the current sampling event that also includes surface water sampling locations; 3. Analytical laboratory reports and summary tables; 4. An Environmental Monitoring Reporting Form (included in Appendix D); and 5. Laboratory Data submitted in accordance with the Electronic Data Deliverable Template. Monitoring reports may be submitted electronically by e-mail or in paper copy form. Copies of all laboratory results and water quality reports for the Foothills Regional MSW Landfill will be kept at the landfill office at part of the facility's operating record. Reports summarizing all groundwater quality results and data evaluation will be submitted in electronic format (pdf format via CD-ROM or email, or other NCDEQ appropriate electronic method) in accordance with applicable guidance to the SWS for each sampling event, and if physical copies are required, they will be sent to the SWS at the following address: North Carolina Department of Environmental Quality Division of Waste Management — Solid Waste Section 1646 Mail Service Center Raleigh, North Carolina 27699-1646 21 of 22 1t 1m 1i Water Quality Monitoring Plan — Phases 1, 2, 3, 4, and 5 Foothills Regional MSW Landfill — Caldwell Co., NC 4.0 REFERENCES October 20, 2017 (Revised March 20, 2019) BLE Project No. J15-1235-78178AI78C Bunnell-Lammons Engineering, Inc., October 20, 2017 (Revised March 20, 2019). Foothills Regional Landfill, Design Hydrogeologic Report, Phase 5 (Cells No. 6, 7, & 8B), BLE Project Number J15-1235- 78/78A. Horton, J.W. and Zullo, V.A., 1991, The Geology of the Carolinas: Carolina Geological Society fifteenth anniversary volume: The University of Tennessee Press, Knoxville, TN. North Carolina Dept. of Environment and Natural Resources (NCDENR), Division of Solid Waste. 1995. Water Quality Monitoring Guidance Document for Solid Waste Facilities. North Carolina Dept. of Environment and Natural Resources, Division of Solid Waste. 2006. New Guidelines for Electronic Submittal of Environmental Monitoring Data. North Carolina Dept. of Environment and Natural Resources, Division of Solid Waste. 2007. Addendum to October 27, 2006, North Carolina Solid Waste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Monitoring Data. North Carolina Dept. Environment and Natural Resources. April 2008. Solid Waste Section, Guidelines for Groundwater, Soil, and Surface Water Sampling. North Carolina Dept. of Environment and Natural Resources, Division of Solid Waste. 2014. Memorandum. Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal. North Carolina Solid Waste Section. September 2016. Memorandum Regarding Guidelines for 14-Day Notification of Groundwater Exceedances Form Submittal per rule: 15A NCAC IB .1633(c)(1). USEPA. September 1986. Ground Water Monitoring Technical Enforcement Guidance Document (TEGD). USEPA. 1996. Low -Flow (Minimal Drawdown) Ground -Water Sampling Procedures. Puls, Robert W. and Barcelona, Michael J. USEPA. April 1993. Region III Modifications to Laboratory Data Validation Functional Guidelines for Evaluating Inorganic Analyses, EPA 540/R-01-008. USEPA, September 1994. Region III Modifications to National Functional Guidelines for Organic Data Review Multi -Media, Multi -Concentration (OLMOL 0-OLM00.9), EPA 540/R-99-008. USEPA. July 2014. Test Methods for Evaluating Solid Waste: Physical/Chemical Methods Compendium (SW-846), Update V. USEPA. 2009. Statistical Analysis of Groundwater Monitoring Data at RCRA Facilities — Unified Guidance. EPA/530-R-09-007. Office of Solid Waste. Washington, D.C. 22 of 22 TABLES TABLE I SUMMARY OF GROUNDWATER MONITORING WELL CONSTRUCTION INFORMATION FOOTHILLS REGIONAL MUNICIPAL SOLID WASTE LANDFILL, PERMIT NO. 1403-MSWLF-1998 REPUBLIC SERVICES OF NC, LLC Well Identification Construction Date Ground Surface Elevation (ft AMSL) Measuring Point Elevation (ft AMSL) Well Depth (feet) Well Diameter (inches) Screened Interval (ft AMSL) Screened Geologic Formation MW-lR2 9/5/2018 1512.84 1516.22 40.2 2 1472.88 - 1487.88 Bedrock MW-2R 8/l/2002 1250.18 1253.36 60.5 2 1189.68 - 1204.68 Bedrock MW-3 3/25/1999 1239.53 1241.95 76.4 2 1163.33 - 1173.33 Bedrock MW-3R 8/l/2002 1239.80 1242.69 74.9 2 1164.90 - 1179.90 Bedrock MW-3R2 8/17/2006 1238.42 1240.83 69.0 2 1169.42 - 1179.42 Bedrock MW-4 3/25/1999 1168.95 1171.18 50.0 2 1118.95 - 1128.95 Residuum/Bedrock MW-5 7/23/2001 1172.26 1175.07 52.0 2 1120.59 - 1130.59 Residuum/Partially Weathered Rock MW-6 10/12/2005 1173.75 1176.82 50.6 2 1123.40 - 1138.40 Residuum MW-7 4/19/2010 1180.36 1183.13 37.6 2 1147.99 - 1157.99 Bedrock MW-8 4/9/2013 1192.35 1195.18 43.9 2 1148.65 - 1163.65 Residuum MW-9 7/6/2016 1288.10 1290.79 74.9 2 1213.49 - 1228.49 Partially Weathered Rock/Bedrock MW-10 10/19/2015 1355.08 1358.53 84.8 2 1270.52 - 1285.52 Bedrock MW-11 9/7/2018 1398.66 1401.71 105.4 2 1293.51 - 1308.51 Bedrock Notes: ft AMSL = feet above mean sea level MW-3 and MW-3R are used for collection of water level data only TABLE 2 SAMPLING AND PRESERVATION PROCEDURES FOOTHILLS REGIONAL MUNICIPAL SOLID WASTE LANDFILL, PERMIT NO. 1403-MSWLF-1998 REPUBLIC SERVICES OF NC, LLC Parameter Container & Volume Preservative Maximum Holding Time Cyanide P,G; 500 mL 4°C, NaOH to pH>12, 0.6 g Ascorbic Acid 14 days Sulfide P,G; 500 mL 4°C, add Zinc Acetate 7 days Mercury (total) P; 300 mL HNO3 to pH<2 28 days Metals (total) except mercury P; 1000 mL HNO3 to pH<2 6 months 2-40 ml VOA w/G, 4°C, 0.008% Na2S2O3, adjust pH to 4-5 Acrolein and acrylonitrile Teflon -lined septum 14 days G, Teflon -lined cap 4°C, 0.008% Na2S2O3, adjust pH to 4-5 7 days to extraction, 40 days Benzidines 1000 mL after extraction G, Teflon -lined cap 7 days to extraction, 40 days Haloethers 1000 mL 4°C, 0.008% Na2S2O3 after extraction G 7 days to extraction, 40 days Phthalate esters 1000 mL 40C after extraction G, Teflon -lined cap 4°C, store in dark, 0.008% Na2S2O3 7 days to extraction, 40 days Nitrosamines 1000 mL after extraction Nitroaromatics and cyclic G, Teflon -lined cap 4°C, store in dark, 0.008% Na2S2O3 7 days to extraction, 40 days ketones 1000 mL after extraction G, Teflon -lined cap 7 days to extraction, 40 days PCBs 1000 mL 40C after extraction G, Teflon -lined cap 7 days to extraction, 40 days Phenols 1000 mL 4°C, 0.008% Na2S2O3 after extraction Purgeable Aromatic 2-40 ml VOA w/G, 4°C, 0.008% Na2S2O3, HCl to pH 2 Hydrocarbons Teflon -lined septum 14 days 2-40 ml VOA w/G, Purgeable Halocarbons Teflon -lined septum 4°C, 0.008% Na2S2O3 14 days Polynuclear Aromatic G, Teflon -lined cap 4°C, store in dark, 0.008% Na2S2O3 7 days to extraction, 40 days Hydrocarbons 1000 mL after extraction G, Teflon -lined cap 7 days to extraction, 40 days Chlorinated Hydrocarbons 1000 mL 40C after extraction G, Teflon -lined cap 7 days to extraction, 40 days Pesticides 1000 mL 4°C, pH 5-9 after extraction Notes: P - Plastic, G - Glass, T - Fluorocarbon Resin (PTFE, Teflon(&, FEP, etc.) No headspace should be allowed in the volatile organic compound containers. FIGURES 'oaoF_�+ jii r (S+164 Ir �j � `� � � , - ] �' it 7 � ti r �'��.: _ - � �� � � ��--� � ; ' , � � L_, �_�---• � 1 cl �,� - 'r• r� �^ :, � I�--- _.. ��� ��y �~1l `;4���4 f, �,r Lj i� � jl q •3)r51�- - I ��4,.J ` 11��' - �+ j •j 1. ` �� ' ����'� �� � L � � \'. � ,j..i' _ _ - � -_ '' 1 11 EXISTING FACILITY L 1 � 200 .At3ingdon ��:• � �`�t�: '���_ �f `=.1`�.-�+,off., •._r.�- '� • ` . E . Q � • .. ":�•, •1cb`� 4 Ronk k ZAf -1'n r'Z 2000 1000 0 2000 4000 APPROXIMATE SCALE IN FEET DRAWN: ACE DATE: 10-20-17 NIL 13 BUNNELL-LAMMONS ENGINEERING, INC. CHECKED: MSP CAD: FHLF78-SLM APPROVED: JOB NO: J15-1235-78 6004 PONDERS COURT GREENMLLE, SOUTH CAROLINA 29615 PHONE: (864)288-1265 FAX: (864)288-4430 REFERENCE: USGS TOPOGRAPHIC MAP, 7.5 MINUTE SERIES, LENOIR, N.C. QUADRANGLE, 1956. FIGURE SITE LOCATION MAP FOOTHILLS REGIONAL MSW LANDFILL CALDWELL COUNTY, NORTH CAROLINA \\1 0 SW-6 N � r CCD I �� PZ-75B 1210.43 PZ-75A 1 ! / 1212.98 L� f I / // \ I \ J N ENV ROPOSED 4. I �S7- *4 - - VNN)r 1 , C � `4 � t o� S ��co PZ-78C 1365.00 " V V 1319.97 MW-10 ' MW-12 MW 11 ,4 Vim PZ-129C MW 1 a 1332.11 1310.29 PZ-132C 1291.73 / PZ-130AB PZ-126C CELL NO. 5P ABAND 1379.44 N CELL NO. 5A PZ-127 ABAND PZ-133B 1273.46 PZ-131AB 1280.91) -� -UD� J� 11 1 \ CELL NO. 4 PZ-103C PZ-102C 1208.55 a 1224.94 ` \ o ' „4/CELL N0. 8A � a PROPOSED PZ-101C � a 124s.25 CELL NO. 8B PZ-99 \ FR10 DRY %` o DRY G\ MW-15 s I PZ-63B ABAND CELL NO. 3C CELL NO. CELL NO. 3A \G CELL NO. 2A 00�ZpO W DETE A NNO.5 PZ-134B 1243.36 G CELL NO. 1A lum m I J T MW-3 v 1187.42 MWs 3 o i CELL NO. 1B cl - � �MW 3R 1211.44 G D a MW-4 MW-5 1129.38 T D NT1 1127.03 UD-1 MW-6 : BAS NV.112 . ,I SEDIMENT 1132.14 BASIN 1110'1�1 GP-5R SW-3 ■ +4061 eOGW \ Olew GP-3 on r MONITORING LOCATION LEGEND PZ-42 0 SURVEYED LOCATION OF PIEZOMETER OR BORING PERFORMED BY BLE FR17 SURVEYED LOCATION OF PIEZOMETER AND BORING PERFORMED BY FRONT ROYAL PZ-55 X ABANDONED WELL, PIEZOMETER, OR BORING WW-1 ® SURVEYED LOCATION OF WATER SUPPLY WELL NW-1 . SURVEYED LOCATION OF GROUNDWATER MONITORING WELL OP-1 - SURVEYED LOCATION OF METHANE MONITORING PROBE SW-1 ■ APPROXIMATE LOCATION OF SURFACE WATER MONITORING POINT UD-1 . APPROXIMATE LOCATION OF UNDERDRAIN MONITORING POINT NW-13 Q PROPOSED LOCATION OF GROUNDWATER MONITORING WELL SW-6 PROPOSED LOCATION OF SURFACE WATER MONITORING POINT OP-16 OQ PROPOSED LOCATION OF METHANE MONITORING PROBE TOPOGRAPHIC & GEOLOGIC LEGEND ��116o TOPOGRAPHIC SURFACE CONTOUR IN FEET ABOVE MSL CONTOUR INTERVAL = 2 FEET STREAM OR CREEK ROAD - - LID - - LID - - UD - EXISTING UNDERDRAIN PROPERTY BOUNDARY 300 FOOT BUFFER 1100 GROUNDWATER EOUIPOTENIIAL CONTOUR (FEET MSQ CONTOUR INTERVAL = 20 FEET GROUNDWATER FLOW DIRECTION 1190.30 GROUNDWATER ELEVATION (FEET MSQ ABAND PIEZOMETER HAD BEEN ABANDONED AT THAT TIME NP NOT PRESENT AT TIME OF MEASUREMENT NOTES: 1. THE WATER LEVELS REPRESENT THE MEASUREMENTS COLLECTED ON MARCH 4, 2013. SW-4 2. THE CONFIGURATION OF THE GROUNWATER CONTOURS BENEATH THE EXISTING CELL FOOTPRINT IS BASED CN HISTORICAL WATER TABLE MAPS OF THE SITE. ■ 3. MEAN SEA LEVEL ELEVATION (M5L) IS REFERENCED TO THE NATIONAL GEODETIC VERTICAL DATUM OF 1929 (NGVD). II GENERAL MAP REFERENCE I 200 100 0 200 400 APPROXIMATE SCALE IN FEET REFERENCES:- 1 . TOPOGRAPHIC INFORMATION SHOWN FROM AN AERIAL SURVEY BY COOPER AERIAL SURVEYS CO., DATE OF PHOTOGRAPHY FEBRUARY 10, 2016. MAPPING CONTROL BASED ON HISTORICAL LANDFILL CONTROL POINTS. 2. WETLAND AND STREAM BOUNDARIES IN LANDFILL AREA BASED ON SURVEY BY DONALDSON. GARRETT & ASSOCIATES, INC. DATED AUGUST 28, 2002. �ryd�tiif0/Aft' ?k,A:� 3. WETLAND AND STREAM BOUNDARIES IN CONSERVATION AREA BASED ON SURVEY BY DONALDSON, GARRETT & ASSOCIATES, INC. DATED OCTOBER 7, 2002. m 4. PROPERTY BOUNDARY TAKEN FROM A BOUNDARY SURVEY PREPARED BY iO4 a ;' WRIGHT & FIELDS LAND SURVEYING, DATED AUGUST 14. 2007. %"�°'t:O{,QCt�•4`}'®°® 5. CELL BOUNDARIES FOR CELLS 1-8A WERE TAKEN FROM THE ENGINEERING �®®� DRAWINGS - PHASE NO. 3 PLANS PREPARED BY HODGES. HARBIN, rr�ls 11��®� NEWBERRY. & TRIBBLE. INC., DATED JULY 2008. % / '�6 Z O(« 6. PHASE 5 WASTE LIMITS WERE TAKEN FROM PRELIMINARY (MARCH 2017) PERMIT TO CONSTRUCT PLANS BEING PREPARED BY HODGES, HARBIN, NEWBERRY, & TRIBBLE. INC. REVISIONS No. DESCRIPTION BY 1 MARCH 2O19 - ADDED NEW WELLS MW-1R2 AND MW-11 INSTALLED IN 2018, AND REMOVED MW-1R ABANDONED 2018 MSP WELL CAP WITH LOCK WELL ID PLATE WELL CAP STEEL PROTECTOR CAP 1/4" GAS VENT DRAIN/WEEP HOLE SURVEYOR'S PIN (FLUSH MOUNT) GROUND SURFACE 3' x Tx 4" CONCRETE PAD - SLOPE TO DRAIN T c~n w CONTINUOUS POUR CONCRETE CAP 3 FEET MIN. w p AND WELL APRON I.L. N NEAT CEMENT GROUT, CEMENT/BENTONITE GROUT, OR HIGH SOLIDS SODIUM BENTONITE GROUT WELL DIAMETER 2" PVC THREADED BOREHOLE DIAMETER 6 INCHES MINIMUM BENTONITE LAYER (NOMINAL DIMENSION) (1.0 FEET MIN.) = SILICA FILTER PACK SAND —_ POTENTIOMETRIC SURFACE w SCREENED INTERVAL 0.010 INCH SLOT — w = MANUFACTURED SCREEN (NOT TO EXCEED n ZO =_ 15 FEET WITHOUT AMPLE JUSTIFICATION Q N = WELL INSTALLATION.) = U) BOTTOM CAP NOTES: 1. IF THE WELL IS SET IN SOIL, THE SCREEN WILL BE SET TO BRACKET THE 24-HOUR WATER LEVEL WITH APPROXIMATELY 12-FT OF WATER IN THE WELL. IF THE WELL IS SET INTO BEDROCK, THE SCREEN WILL BE SET TO ENCOUNTER WATER -PRODUCING FRACTURES. 2. PLACE PEA GRAVEL IN ANNULAR SPACE BETWEEN PVC STICK UP AND STEEL PROTECTIVE CASING. GROUNDWATER MONITORING WELL JOB NO.: FIGURE J15-1235-78 NIL E INC. GROUNDWATER MONITORING WELL DETAIL DATE: FOOTHILLS REGIONAL MSW LANDFILL 10-20-17 BUNNELL-LAMMONS ENGINEERING, INC. CALDWELL COUNTY, NORTH CAROLINA SCALE: 6004 PONDERS COURT NOT TO SCALE PHONE: E864 288- 265H FAX: OSI64)288- 430 APPENDIX A SWS Correspondence Regarding MW-3 and MW-3R * "r NCDENR North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director Dlvlslon of waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary December 14, 2006 Mr. Ray Hoffman Republic Services of NC 1220 Commerce Street, SW Conover, NC 28613 Re: Alternate Source Demonstration: MW-3 and MW-3R Foothills Regional Municipal Solid Waste Landfill, #14-03, Caldwell County Dear Mr. Hofftnan, Contaminants in concentrations exceeding North Carolina Groundwater Standards are being detected at the Foothills Regional Municipal Solid Waste Landfill, and as a result, an Alternate Source Demonstration (ASD) was prepared by Hull and Associates and submitted on October 6, 2004 on behalf of Republic Services of NC, LLC, In response, the Solid Waste Section requested additional information in order to justify the conclusions that the landfill is not the source of the volatile organic contaminants being detected at downgradient monitoring wells. The Solid Waste Section then reviewed the Alternate Source Demonstration: Anomalous Detections of volatile Organic Detections prepared by Golder Associates, Inc, and submitted on May 22, 2006 on behalf of Republic Services of NC, LLC. Golder Associates Inc, concluded that the landfill was not the source of the groundwater contamination. The Solid Waste Section finally requested that Republic install a new well approximately 150 to 200 feet downgradient of MW-3 and MW-3R in order to delineate the horizontal extent of contamination that was detected at both MW-3 and MW-3R, The new well, MW-3R2, was screened in bedrock and was sampled two times (August and October). Both sampling events showed no exceedances of metals or Appendix I VOCs in the new well. Based on the data submitted, Republic is requesting that the Solid Waste Section allow the Foothills Regional Municipal Solid Waste Landfill to revert back to detection monitoring per 15A NCAC 13B .1633. As a result, the Solid Waste Section approves the request, and Republic may now resume routine detection monitoring at the site. Also, Republic is requesting that the Solid Waste Section approve the removal of MW-3 and MW-3R from the compliance monitoring network and allow for proper abandonment of these two wells. The Section Waste Section denies the request of abandonment of MW-3 and MW-3R at this time, however, these two wells may be removed from the compliance monitoring network, and MW-3R2 may replace these wells becoming the new compliance well. Please record the changes in the water quality, monitoring plan. 1646 Moll Service Center, Rolelgh, North Carollna 276994640 Phone 919.50H4001 FAX 919-715.36051 Internet htlp,llwastenotmorg An Equal Opportunity I Afflrmdve Action Employer— Printed on Dual Purpose Recycled Paper Please call me at 9I9-508-8500 if you have any questions or concems regarding this correspondence. Thank you in advance for your anticipated cooperation in this matter. Sincerely, f y faclynne Drummond Hydrogeologist Environmental Compliance Solid Waste Section cc: Rachel Kirkman, Golder Associates George Gibbons, Foothills Environmental Mark Poindexter, Solid Waste Section Al Hetzell, Solid Waste Section Solid Waste Section Central Files 1648 Mall 8er0ce Center, Raielgh, North Carolina 27699-1646 Phone 9tM08-1340M FAX 919-715-360511nternal http:/Iwastenolnc.org An Equal Opportunity l Aff€rmalive Action Employer.- Printed on Dual Purpose Recycled paper APPENDIX B Existing Well Construction Records It ' IMMINC. MONITORING WELL NO. MW-1R2 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 CLIENT: Republic Services of NC, LLC START: 9-5-18 END: 9-5-18 BUNNELL-LAMMONS ENGINEERING, INC. LOCATION: Caldwell County, NC ELEVATION: 1512.84 DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel GEOTECHNICAL AND EN VIRONMENTAL CONSULTANTS DRILLING METHOD: Schramm 6" O.D. DEPTH TO - WATER> INITIAL: V 14.65 AFTER 24 HOURS:1 14.9 CAVING>3m ELEVATION/ DESCRIPTION SOIL MONITOR WELL INSTALLATION DEPTH (FT) TYPE rjjj DETAILS Light brown, slightly moist, slightly micaceous, clayey, fine to coarse sandy SURFACE COMPLETION SILT (residuum) 3.05 feet of stickup with 4"x4" stand up looking steel protective cover with a TxT concrete pad at 1510 the base with a survey pin. 1/4 inch weephole installed at the base of the steel cover. 5 1/4 inch vent hole in top of PVC casing. Pea gravel installed inside the steel cover between the cover and PVC casing. 1505 Grout, 0 to 11.9 feet 10 Top of PVC casing elev.= 1516.22 1500 feet Ground elevation = 1512.84 feet Survey Pin Elevation = 1513.10 feet 15 Northing = 801,247.51 feet Easting = 1,232,215.64 feet 1495 Bentonite seal, 11.9 to 23.0 feet 20 1490 #0 Filter pack sand, 23.0 to 42.2 feet 25 -inch diameter, 0.010-inch slotted 2 Light tan, weathered gneiss BEDROCK Schedule 40 PVC well screen, 25.08 to 40.08 feet 1485 30 1480 35 Grey, gneiss BEDROCK Fracture at 35 feet 1475 MONITORING WELL NO. MW-1R2 Sheet 1 of 2 It ' IMMINC. MONITORING WELL NO. MW-1R2 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 BUNNELL-LAMMONS CLIENT: Republic Services of NC, LLC START: 9-5-18 END: 9-5-18 ENGINEERING, INC. LOCATION: Caldwell County, NC ELEVATION: 1512.84 DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel GEOTECHNICAL AND EN VIRONMENTAL CONSULTANTS DRILLING METHOD: Schramm 6" O.D. DEPTH TO - WATER> INITIAL: V 14.65 AFTER 24 HOURS: 1 14.9 CAVING>77 ELEVATION/ DESCRIPTION SOIL MONITOR WELL INSTALLATION DEPTH (FT) TYPE DETAILS Pipe cap Total well depth, 40.16 feet 1470 Boring terminated at 42.2 feet below ground surface. Groundwater initially encountered at 14.65 feet below ground surface. Groundwater encountered after 24 hours at 14.9 feet below ground surface. 45 1465 50 1460 55 1455 60 1450 65 1445 70 1440 75 1435 MONITORING WELL NO. MW-1R2 Sheet 2 of 2 0 W INNNNINEW IBLEINCs GROUND WATER MONITORING WELL NO. MW=2R PROJECT: Foothills MSW Landfill PROJECT NO.. J02-1235-26 BUNNELL-CANNONS CLIENT: HHNT START: 8-1-02 END: 8-1-02 News LOCATION: Caldwell County, North Carolina ELEVATION: 1250.18 E111GINEERING, INC. DRILLER: Lee &Sims LOGGED BY: M. Preddy GEOTecHNicALAt�ENwtowau►L CONSULTANTS DRILLING METHOD: Ingersoll-Rand T3W DEPTH TO No WATER> INITIAL: SZ56.25 AFTER 24 HOURS: 45.92 CAVING> ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE n DETAILS AMMMEP No topsoil - (fill) SURFACE COMPLETION INS4" x 4" steel stand-up cover with a 4' x 4' concrete pad WED AME Ground surface elev.=1,250.18' MSL Top of casing elev.=1,253.36' MSL Men Stiff to hard, light brown, slightly moist, micaceous, fine sandy SILT - Northing INEM - 798,219.93' Men ANN (residuum) Easting INEW ,629.74' 1245 5 WED ANN Men ANN MEW ANN Mee ANN 1240 ammummeeeeeelo AMEMEN Now amm NEW OEM INS mum 1235 15 OMMMMIM Sea emm Men Amm Neat cement, 0 to 35 feet MEN MEN Very firm to very dense, light brownish -gray, slightly moist, micaceous, a 94 0 00 0 *lee 0 9 a Emm silty, fine to medium SAND Men we 0 1230 20 NEW AME WED AME WED ANN Wee dew 1225 25 . dam Men new See Men INS MEN 1220 30 MMME Gray GNEISS bedrock and weathered bedrock WED Men Amm Ema MEN mob MEN 1215 35 REN WED Amm OWN 00M NEW Bentonite seal, 35 to 42 feet MEM GROUND WATER MONITORING WELL NO. MW-2R Sheet 1 of 2 a C; MILMINQ GROUND WATER MONITORING WELL NO. MW=2R PROJECT: Foothills MSW Landfill PROJECT NO.. J02-1235-26 BUNNELL=LAMMONS CLIENT: HHNT START: 8-1=02 END: 8-1-02 E INEERINGi INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1250.18 GEorECHHtcALAwEtrvutowmn%L DRILLER: Lee &Sims LOGGED BY: M. Preddy CONSULTANTS DRILLING METHOD: Ingersoll-Rand T3W DEPTH TO - WATER> INITIAL: 56.25 AFTER 24 HOURS: Z 45.92 CAVING> ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE DETAILS Gray GNEISS bedrock and weathered bedrock ti Bentonite seal, 35 to 42 feet Filter pack, sand 42 to 60.5 feet 1205 45 ' 1200 50 Yellowish -brown, weathered GNEISS bedrock .010-1nch slotted Schedule 40 PVC well screen, 45.6 to 60.5 feet 1195 55 1190 60 Total well depth, 60.5 feet Boring terminated at 60.5 feet. Ground water encountered at 56.25 feet at Borehole diameter, 6.0-inches time of drilling and at 45.92 feet after 24 hours. PVC diameter, 2.04nches 1185 65 1180 70 1175 75 GROUND WATER MONITORING WELL NO. MW=2R Sheet 2of2 a c; c 0 LL 0 W MILI13INCm MONITORING WELL NO. MW-3 PROJECT: Foothills Landfill PROJECT NO.. J99-1235-06 BUNNELL-L.AMMONS CLIENT: HHNT START: 3-25-99 END: 3-25-99 ENGINEERIN INC. LOCATION: Lenoir, North Carolina ELEVATION: 1239.53 GEOTECHNICALAmENwtommm DRILLER: AE Drilling, M. King LOGGED BY: MSP CONSULTANTS DRILLING METHOD: CME 750 Truck mounted air hammer DEPTH TO - WATER> INITIAL: 73.61 AFTER 24 HOURS. Z 67.63 CAVING> ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE n DETAILS No topsoil SURFACE COMPLETION Stiff, brown, moist, micaceous, slightly clayey, fine to medium sandy SILT 4-inch by 4-inch steel stand-up cover - (fill) with a 4400t by 4-foot concrete pad 1235 5 1230 10 1225 Firm to stiff, reddish -brown, moist, micaceous, clayey SILT - (residuum) 15 1220 20 Stiff to hard, brown, moist, micaceous, fine to medium sandy SILT 1215 25 Neat cement, 0 to 58.5 feet 1210 30 1205 35 Very firm to very dense, brown, moist, very micaceous, silty, fine to medium SAND 1200 MONITORING WELL NO. MW-3 Sheet 1 of 3 INC. N N O ENGINEERING, INC. GEOTECHNICALANDEmvm%%#�Vw CONSULTANTS PROJECT: Foothills Landfill CLIENT: HHNT LOCATION: Lenoir, North Carolina DRILLER: AE Drilling, M. King PROJECT NO.: J99-1235-06 START: 3=25-99 END: 3=25-99 ELEVATION: 1239.53 LOGGED BY: MSP DRILLING METHOD: CME 750 Truck mounted air hammer DEPTH TO = WATER> INITIAL: 73.61 AFTER 24 HOURS: Z 67.63 CAVING>3M DEPTH T(Ow I DESCRIPTION I TYPE I MONITOR DETAILSTALLATION WEATHERED ROCK at 42 to 44 feet at soil seams 1195 WEATHERED ROCK, cuttings area light brown, slightly moist, micaceous, 45 silty, fine SAND 55 60 65 70 75 BEDROCK, cuttings are gray GNEISS rock fragments Boring terminated at 76.4 feet. Ground water encountered at 73.61 feet at time of boring. its Bentonite seal, 58.5 to 62.3 feet Filter pack, sand 62.3 to 76.4 feet .010-inch slotted Schedule 40 PVC well screen, 66.2 to 76.2 feet Pipe cap Total well depth, 76.4 feet MONITORING WELL NO. MW-3 Sheet 2 of 3 a L 0 W OBLISINCm MONITORING WELL NO. MW=3 PROJECT: Foothills Landfill PROJECT NO.. J99-1235-06 BUNNEL.L-CANNONS CLIENT: HHNT START: 3-25-99 END: 3-25-99 ENGINEERING, INC. LOCATION: Lenoir, North Carolina ELEVATION: 1239.53 GEaMCHNICALAwENvutowan%L DRILLER: AE Drilling, M. King LOGGED BY: MSP CONSULTANTS DRILLING METHOD: CME 750 Truck mounted air hammer DEPTH TO - WATER> INITIAL: 73.61 AFTER 24 HOURS: V. 67.63 CAVING> ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE DETAILS 6-inch O.D. borehole advanced by air -rotary drilling from the ground surface to 76.4 feet. 1155 Northing = 798097.54 85 Easting=1231308.42 Top of PVC=1241.95' Concrete=1239.53' 1150 90 1145 95 1140 100 1135 105 1130 110 1125 115 1120 MONITORING WELL NO. MW=3 Sheet 3 of 3 MILISINCm GROUND WATER MONITORING WELL NO. MW=3R PROJECT: Foothills MSW Landfill PROJECT NO.: 102-1235-26 A MEND BUNNELL=LAMMONS CLIENT: HHNT START: 8-1=02 END: 8-1-02 EMMM ENGINEERING INC. LOCATION: Caldwell County, North go Carolina ELEVATION: 1239.80 DRILLER: Lee & Sims LOGGED BY: M. Preddy GEOTECHNICALAND ENVIRowENTAL CONSULTANTS DRILLING METHOD: Ingersoll-Rand T3W DEPTH TO - WATER> INITIAL: 72.71 AFTER 24 HOURS. Z 60.39 CAVING>M ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE I —I DETAILS No topsoil SURFACE COMPLETION MIM Stiff, brown and reddish -brown, slightly moist, micaceous, fine to medium 4" x 4" steel stand-up cover with a 4' ago sandy, clayey SILT - (fill) x 4' concrete pad MIM ago Ground surface elev.=1,239.80' MSL Top of casing elev.=1,242.69' MSLago Northing = 798,085.97' Egg Easting=112311333.90' 1235MONOW ommoo 5 AMMMIM go goo Egg goo Mom Emn 1230 10 WIMMMM MIM ago Emn ago MIN ago NEW MEN 12250MMEN ggggg15 MEMENE Firm to stiff, reddish -brown, moist, micaceous, clayey SILT - (residuum) IRS MEN ENO AME 1220googg googg20 Stiff to hard, brown, moist, micaceous, slightly clayey, fine to medium Emm sandy SILT OWN ago gin Neat cement, 0 to 47 feet MEN 12150MMME ggggg25 gin MEN END MEN WED OWN Own 1210 ommmm ggggg30 OMMMME MIM Now MEN MIM MIN MEN 1205 MEMEN googg35 Very firm to dense, brown, moist, very micaceous, silty, fine to medium SAND MEN Egg MIS OWN GROUND WATER MONITORING WELL NO. MW=3R Sheet 1 of 2 INC. c� CV M N Tam Z J J man w D ENGWEERING, INC. GEOTECHNICALAHDENVIRO�IAL 'J k Lal k, 7-1 PROJECT: Foothills MSW Landfill CLIENT: HHNT LOCATION: Caldwell County, North Carolina DRILLER: Lee & Sims PROJECT NO.: J02-1235-26 START: 8-1-02 END: 8-1-02 ELEVATION: 1239.80 LOGGED BY: M. Preddy DRILLING METHOD: Ingersoll-Rand T3W mammalian DEPTH TO - WATER> INITIAL: 72.71 AFTER 24 HOURS:1 60.39 CAVING> 3M William ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE DETAILS Very firm to dense, brown, moist, very micaceous, silty, fine to medium Neat cement, 0 to 47 feet SAND WEATHERED ROCK; cuttings are light brown, slightly moist, micaceous, silty, fine to medium SAND 1195 45 1190 AMMIN ====50 am Bentonite seal, 47 to 55 feet am mm Min 1185 MIMME aam=55 ma GNEISS Bedrock; cuttings are gray rock fragments Min 1180MIMME ===m60 ' am Filter pack, sand 55 to 74.9 feet 1175=aam65 mimmomme mm Manama mm Emammme mm • MUMMIMME 0 d .010-inch slotted Schedule 40 PVC well screen, 59.9 to 74.9 feet 1170====70 Min am ma MIMMIMMIM ma 1165 mamm75 Total well depth, 74.9 feet ma Boring terminated at 74.9 feet. Ground water encountered at 72.71 feet at time of drilling and at 60.39 feet after 24 hours. Borehole diameter, 6.0-inches PVC diameter, 2.0-inches GROUND WATER MONITORING WELL NO. MW-3R Sheet 2 of 2 Project ,NameK&,aAkI;cv* Project No. , 0, male Spa tJFiW Mrinbig Rig TYrpe % Trilling Method(s) tIs rn Ariller 14amelCompany " c, A.ppxox. Ground Elevation4t BaRiNG NO. 41n 0029 —O �a Total Depth . 1D� s c Page _..,� of OV r S`� �' Qu ��• 1 "' 1 r 1a�r�� Diameter of Borehole o San le : r, Elev. Depth[7U flows > Remarks = Soil and Rook Desmiptions Re €�. Type & No. per b" E'en in. Reo % � � O�.. �"'�, �,�x J �t11 •t':v.Y�:..v+aoi� c�ak� C[iy , ,�-l�lrly +�►afs�' �; i •1�)e► t cam. ��U � �� � i�1�d'Gf"► g4'l:�Jr► i �bi�'�� �Ga/r1iSd���t�1 j yy�itlil { �`�"s3 't'ih�Tlc`r►� Zvi ff �kn& to 6IdW cite hammer at lityr rrre-�ru�� $lotii's per C in. -14o1b hamnYer i'ail�n5 90 irs, to drive a �jgfies. {�i�'1'jpe, dr311ing nielho�, bit auger siie, PSI. lrc��►i}�ment Fa'st�res, passible contamination, devi�tior�s from driifin� pion, dritling dii]icutties� Z,{� in. �?A split spoon sampler. ec�� � �-• f )�4 � � �N-S ��'� i'at - Penctratioz� Length of Samp9cr or Corc Z3arrdi Rec - Z�ecavcry l�engiii of Sampl4 RQQ - i.cnght of Sound Cores >4W.A.Angth Cored °/S S - Split Spoon Sample U - Undisturbed Samples 1'cojectldamtr,�n��1,'�,-�.� ;f �� ,,� l-li.3� Iriller�iaineICornpany s BORING 1110. Project No. 7W* 0 [ - Approx. Ground Elevation rASP � �+ Date Start/Finish %= Total Depth ` Dril4infi RigType 1�� page Of � fr Drilling iv ethod(�) Diameter of 13orehole S Ie E• leer. Depth Blows > Remarks Soil and Rock Descriptions Pt. ft. Tyne � No. per fi" Pen me Ree % Fiac { t 624'0 61) � ,,,, 65� a'r) TI) MASS Blows per 6 in. - 1401b hamrnsr falling 30 in. is dri<<e a }odrilling , PSI E vi ment Failtires, possible contamination, deitiMions from drilling plan, drilling Wfiiaulties, sty YP� �gu bit auger sire, q p 2,0 in. OD split spoon sampler. eCL) � .. � o Qr-A f pen - Pcnetradon LimA of Sampler or Core Bwell y�novs� i V64 j x io' due +4 �a i �N�'� l ew e �•�� . �� � Rec - Recovety Lengelt of Sample RQD -M WPM NOW Leright of Sotind Cores >4inAeopli Cored ID/6MW � � ' ' S - Split Spoon Sample U lUndisturW Samples ENGINEERING, INC - Subcontractor: gged 13y: un 0 0 Depth ar l�exght (l~t) Pram Crvnnd Surface ' { hold i115,r'7 $ f Pip SS r+ 69� Iva :,.: •, I. •:• .:[ : �. .� :0.1 .•. •. .•:; ; :• pa:• �: :•; �- 14 ;:am � I�CPR IN EUL4 XIS ALJ�A I IVII s� �JIr 1pn it4rirt%�14.: Date/time of Well bstallatlow. Depth to l�otto�m a� Well fi�ror� Top o Ivlonflormg Well Pipe. �.D. of cuter Protect€ve �asxng Type of Surface Seal r Diameter of borehole Size of Screen )pcning aP6 010� ! n�� Type of Screen Y e,.; Ic:�'' - Sire flf k^iiter Sand /�Q, • s .r. � a. �++�w. �yw�wly] , .v.v w. ia•r� �v v/..�w w..•^-'..4�� - / ■/'\j -/{� + r Depth from TOC q. 06 2 INC. PROJECT: Foothills Landfill LI 1_ '_ PROJECT NO.: J99-1235-06 N N O .J J_ 2 0 0 m z J 0 W ENGA�IEERING, INC. GEo�rECHNICALA�m ENv�oNME�uu. • _ _-,It= CLIENT: HHNT LOCATION: Lenoir, North Carolina DRILLER: AE Drilling, M. King DRILLING METHOD: CME 750 Truck mounted air hammer DEPTH TO - WATER> INITIAL: � ELEVATION/ I DESCRIPTION DEPTH (FT) 1165 1160 1155 1150 1145 1140 1135 1130 5 10 15 20 25 30 35 40.80 AFTER 24 HOURS: Z No topsoil Stiff to very stiff, brown, moist, micaceous, clayey, fine sandy SILT - (fill} Firm to hard, reddish -brown and brown, moist, micaceous, clayey, fine to medium sandy SILT with gravel size fragments - (residuum) START: 3-25-99 END: 3-25-99 ELEVATION: 1168.95 LOGGED BY: MSP 41.05 ����� ������ • • •- � � • - � ':I I: 4-inch by 4-inch steel stand-up cover with a 4-foot by 4-foot concrete pad. Neat cement, 0 to 32 feet Bentonite seal, 32 to 35 feet MONITORING WELL NO..MW,4 Sheet 1 of 2 a C: MILMINCo MONITORING WELL NO. MW=4 PROJECT: Foothills Landfill PROJECT NO.: J99=1235=06 BUNNELL=LAMMONS CLIENT: HHNT START: 3-25-99 END: 3=25-99 ENGINEERING, INC. LOCATION: Lenoir, North Carolina ELEVATION: 1168.95 GEO'TECHNWALAwENVIROI mn%L DRILLER: AE Drilling, M. King LOGGED BY: MSP CONSULTANTS DRILLING METHOD: CME 750 Truck mounted air hammer DEPTH TO = WATER> INITIAL: 40.80 AFTER 24 HOURS: V. 41.05 CAVING> ELEVATION/ SOIL MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE DETAILS Filter pack, sand 35 to 50.2 feet Hard to very hard, brown, wet, micaceous, slightly clayey, fine to medium '. sandy SILT 1125 45 WEATHERED GNEISS BEDROCK .010-inch slotted Schedule 40 PVC well screen, 40 to 50 feet 1120 ' 50 . • . • Pipe cap Le 0 Boring terminated at 51 feet. Ground water encountered at 40.80 feet at time of boring. Total well depth, 51 feet 8.25-inch O.D. borehole advanced by 1115 auger drilling from ground surface to 42 feet. 6-inch O.D. borehole 55 advanced by air -rotary drilling from 42 to 51 feet. Northing = 798361.75 1110 Easting=1230578080 Top of PVC=1171.18' 60 Concrete=1168.95' 1105 65 1100 70 1095 75 1090 MONITORING WELL NO. MW=4 Sheet 2 of 2 MILEINCo MONITORING WELL NO. MW=5 PROJECT: Foothills MSW Landfill PROJECT NO.: J01-1235-23 a Removal BUNNELL-LAMM CLIENT: HHNT START: 7-23-01 END:7-23-01 SINS ENGINEERING, INC. LOCATION: Lenoir, North Carolina ELEVATION: 1172.26 DRILLER: Superior Drilling, Inc., F. Cox LOGGED BY: MSP GEOTECHNic�►LA�roENvetow� CONSULTANTS DRILLING METHOD: CME 650 ATV Hollow stem auger DEPTH TO - WATER> INITIAL: 46.60 AFTER 24 HOURS:1 45.67 CAVING> Moslem ELEVATION/ SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE a BLOWS/FOOT n DETAILS co 2 5 10 20 30 40 50 70 90 Stiff, brown and gray, dry, micaceous, SURFACE COMPLETION ease clayey, fine to medium sandy SILT -ORION .....:...:....:...:...:.....:..............:..:..... standup steel cover Real (fill) 1170 : : : : : : : : : : : : seem 4m1m : : : : : : : : : Northing = 798,613607 Emma mesa .....:... No ....: ...:...:.....:... map ...:...:...:..:...:. a Easting = 1,230,537.21 memo 9 _ Mongolia5 ....:...:....:...:.. fee ... oSao Top of PVC casing elev.—1175.07' : : : : : : : : : : Ground surface elev. =1172.26' 1165 Stiff to firm, brown, moist, micaceous, ease slightly clayey, fine to coarse sandySamoa .....:...:....: :..:...:.... so* ...:....:.. me* ..:..:...:. 0 Seem SILT - (fill) 10 10 ....:...:....:...:.......:....:....:...:...:..:...00 1160 : : : : : : : : : mesa mage .............................................._......... mass 15...........:...:...:.....:....:....:...:...:..:...:. 1155 Bentonite (5%) cement, 0 to 34 feet ....................am* ... so* ................_......... 7 .� 20....:...:....:...:...:.....:....:....:...:...:..:...00 4 seasonal 1150_...._..................:....:......:..:...:. 8 ayyyyyyyyyyy 25 x �4 4 0 0 a a 0 4 me a a a * op a 0 #90 a age & a a #09 6 a go* 4 & 006 0 099 a 0 my a *4* * 000 4 seasonal (refusal at 26 feet, move rig 10 feet and re -drill) ago, .....:...:.... _...:..:.....:....:....:...:...:..:...:. 0 seem 1145 Very firm, gray and white, slightly WE*moist, micaceous, silty, fine SAND -9 No 0 mesa, .....:...:.... _ ...:.. of* ... go* ...:....:...:...:..:...:. on 9 (residuum) 04 • 30 yyyyyyyyyyN30 ....:...:....:...:...:.....:....:....:...:...:..:...0a 1140yeassomma Very dense, gray and white, slightly Ronmoist, micaceous, silty, fine to....:...:....:...:...:.....:...*we .. fee ..:...:. off ..:. medium SAND mass 0 mays 7s a a a a 4 044 seem 00 94 4: s 35...:...:....:...:...:.....:....:....:...:...:..:...00 00 Bentonite seal, 34 to 38 feet 1135 PARTIALLY WEATHERED ROCK : : : : : which sampled as gray and white,mesa .....:...:....:...:...:.....:....:....:...:.....:...:a . 8111 moist, micaceous, silty, fine to : 50/5�� •• medium SAND 50/5mean .....:...:....:...:...:.....:....:....:...:...:..:...:. ONE i small MONITORING WELL NO. MW=5 Sheet 1 of 2 BUIVNEI.L-LAMM%M% ENGINEERING, INC. GEOTECHNICALAND ENvIROwmmL � LiNte-111ITMI A t= PROJECT: Foothills MSW Landfill CLIENT: HHNT LOCATION: Lenoir, North Carolina DRILLER: Superior Drilling, Inc., F. Cox PROJECT NO.: J01-1235-23 START: 7-23-01 END:7-23-01 ELEVATION: 1172.26 LOGGED BY: MSP DRILLING METHOD: CME 550 ATV Hollow stem auger DEPTH TO = WATER> INITIAL: 46.60 AFTER 24 HOURS: Z 45.67 CAVING>3M ELEVATION/ SOIL a STANDARD PENETRATION RESULTS DEPTH (FT) DESCRIPTION TYPE a BLOWS/FOOT Cn 2 5 10 20 30 40 50 70 90 Dense, brown, gray and white, moist, 0 4 0 F 0'. MEN micaceous, silty, fine to medium0 0 4 MMMMM .....:...:....:...:...:.....:....:....:...:...:..:.... 1130 SAND 38 a 45:...:....:...:...:.....:....:....:......:..:...:. 1125 PARTIALLY WEATHERED ROCK '. which sampled as brown and gray,:...:....:...:...:.....:....:...doe ..:...:..:...oe moist, micaceous, silty, fine to : 50*/4.611 MEN medium SAND 0/4.5.....:...:....:...:..:.....:....:....:...:...:..:...:. 50:...:....:...:...:.....:....:....:...:...:..:...oa 1120doge . _...._ ..................:... doe .....:.....:. MIND Auger refusal at 52 feet. Ground :...:.... _...:...:.....:....:....:...:...:..:...:. water encountered at 46.60 feet at MEMO time of drilling. :...:... 0 _ .. go* . .... goo ...:....:...:...:..:..goo 55:...:....:...:...:.....:....:....:...:...:..:...:.M do 60:...:....:...:...:.....:....:....:...:...:..:...:.. 1110.....:...:....:...:...:.....:....:....:...:...:.....:.. 65...........:...:...:.....:....:...am ...:...:..:...:.. 1105 70..:..:....:...:...:.....:....:....:...:...:..:...:.. 1100MEMO ..:...:....:...:...:.....:....:....:......:.....:.. 75:...:....:...:...:.....:....:....:...:...:..:...:.. 1095 J J D 0 J MONITOR WELL INSTALLATION DETAILS Filter pack, sand 38 to 52 feet .010-inch slotted Schedule 40 PVC well screen, 41.67 to 51.67 feet Pipe cap Total well depth, 51.97 feet Borehole diameter, 8.25-inches Well diameter, 2-inches MONITORING WELL NO. MW-5 Sheet 2 of 2 0 w NILMINCe GROUND WATER MONITORING WELL NO. MW=6 PROJECT: Foothills MSW Landfill PROJECT NO.: J05-1235-38 BIINNELL-LAMMONS CLIENT: Republic/HHNT START: 10-12=05 ENDS 10=12=05 ENGINEERING, INC. LOCATION: Lenoir, North Carolina ELEVATION: 1173.75 GEOTECHNICALANDENVIRONMENTAL DRILLER: Metro Drill, Inc., T. Brown LOGGED BY: M. Preddy CONSULTANTS DRILLING METHOD: Acker Truck -mount hollow stem auger DEPTH TO No WATER> INITIAL: 42.25 AFTER 24 HOURS: Y. 40.80 CAVING> w ELEVATION/ SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE a n BLOWS/FOOT DETAILS co 2 5 10 20 30 40 50 70 90 No topsoil SURFACE COMPLETION EweReddish-brown, slightly moist, 3.07-foot stick-up with a 4" x 4" x 5' micaceous, gravelly, fine to coarse long stand-up locking steel , goo sandy, clayey SILT - (fill)..........see ............:....:....:... 000 protective cover with a Tx 3 x 4 thick concrete pad 1170 a 0eveeveage a a 1/40minch weep and vent holes 5me ...........:...:...: ................... do ..:.... 9 installed in steel cover and PVC Very firm, grayish -brown, slightly : : casing, respectively Owe moist, micaceous, clayey, silty, fine 4 00POO a ...:.. add ....:....:... . to coarse SAND - (fill) 4,_ Northing = 798, 998.77 feet own • owe 0 4 :...:....:...:...:.....:....:....:...:.. aft ..:...:. Easting = 1,230,460.41 feetgoo 1165 8 : : : : : : : 11 ` Ground surface elev.=1,173.75 10 12....:...:....:..add . ads ....:....:... moo ..:...:..:...00 0 feet MSL so 0 Survey pin elev.=1,173.81 feet ....:...:....:...:...:.....:....:....:...:...:..:...00 0 MSL gem 1160 09 0 0 0 a 0 0 09 Top of casing elev.=1,176.82 feet MSL 00 15...:...:....:...:...:.....:....:....:...:...:..:...:. 1155 4 01 4 a 4, X 8 1200060 gem 20 13 ... 0 ... 49 .... ...:...:.....:.... as ...:...:... ad .0:..00a Neat cement grout, 0 to 22 feet 1150 25---------------....was .:...............:....:.....:...:..:..:. Very firm, gray, moist, micaceous, Owe slightly clayey, silty, fine to coarse .. pad woo : :m • • SAND - (fill) : : : : : : : : : : : : Bentonite seal, 22 to 30 feet owe 0 MOO woo go owe amoo see@ 1145 9 : 11was................................... 30 16..:...:....:...:...:.....:....:....:...:..:..:...o0 Filter pack, sand 30 to 53.5 feet ago---------------........................................................ WE Firm to loose, gray, very moist, : : : : : : : : : : : : •• micaceous, slightly clayey, silty, 1140 fine to coarse SAND - (fill) 0 0 g : OWE G :...:....::...:.....:....:....:......:.....0 '. 35 7 ....:..:.... " .. see . woo ....:... woe .. age ..:...:..:...00 1135 4 : : : : : : : : : : : : NO 5:...:.....:...:.....:....:....:......:.....:.WOE GROUND WATER MONITORING WELL NO. MW=6 Sheet 1 of 2 N N a MILMINCs GROUND WATER MONITORING WELL NO. MW=6 PROJECT: Foothills MSW Landfill PROJECT NO.. J054235-38 BUNNELL-LAMMONS A Needs CLIENT: Republic/HHNT START: 1042-05 END: 90-12-05 ENGINEERING, INC. LOCATION: Lenoir, North Carolina ELEVATION: 1173.75 DRILLER: Metro Drill, Inc., T. Brown LOGGED BY: M. Preddy GeOTecHNicALAt�ENvutoNMENr�►L CONSULTANTS DRILLING METHOD: Acker Truck -mount hollow stem auger DEPTH TO - WATER> INITIAL: downs 42.25 ON AFTER 24 HOURS: Z 40.80 CAVING>M w ELEVATION/ SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE Q BLOWS/FOOT DETAILS 0 2 5 10 20 30 40 50 70 90 Dark gray TOPSOIL `11' •`` ' Dark gray TOPSOIL ........:....:......:.............:...:.....:.... Now Firm, yellowish -brown and gray, NEED .....:...:....:...:.. s :....:... :...:. a ONE wet, micaceous, slightly clayey, 2-inch diameter, 0.010-inch slotted silty, fine to medium SAND - :....:....:... Schedule 40 PVC well screen,ago 1130 (residuum) 6 : : : : : : : : : : : : 35.35 to 50.35 feet Nor a 5........................:......:...... 45 7 ....:...:....:...:.. .....:....:... ...:... .0:.0.o4 9 damaged Very dense, gray, very moist, ads micaceous, silty, fine to medium .....: 1125 SAND 15 : : : : : : : : : : : : ONE, aged23:...:....:...:...:.....:....:....:.�...:.....:. 50 33....:...:....:...:...:.....:....:... ...:...:..:...00 • • . • Pipe cap game 4 • Total well depth, 50.55 feet 1120 a 6 a a a a a 4 0 a Boring terminated at 53.5 feet. ddddddd55 Ground water encountered at 42.25 feet at time of drilling. : 1115 60....:...:....:...:...:.....:....:....:...:...:....:. OWN Now, 0 ......---...................................._......... sea 1110 65...:...:....:...:...:.....:....:....:...:...:..:...da add1105adds 0 e 70....:...:....:..see . doe ....:....:... ...:..:..:...00 ........ _..... ..................:........:............. ago Eggs 9 ............._..............................._......... Ago 1100seasonal NNNNNNN75 foe ..:..:.....:. 1095dead == 0 04 4 0 4ads a 0 0 NowGROUND WATER MONITORING WELL NO, MW-6 Sheet 2 of 2 MAR. flue Vin"JYMAGAM N N O Que LO INO LO N J J 0 W ENGINEERING, INC. CaEorEcHNicALANDEorvu. PROJECT: Foothills Regional MSW Landfill CLIENT: ublic LOCATION: Caldwell Cou DRILLER: Land North Carolina PROJECT NO.: J09-1235-55 a damage START: 4-19-10 ENDER 4=19=10 ELEVATION: 1,180.36 LOGGED BY: M. Preddy CONSULTANTS DRILLING METHOD: CME 750 ATV; 6-inch air hammer DEPTH TO - WATER> INITIAL: 30.0 AFTER 24 HOURS: V. 23.29 CAVING> w ELEVATION/ SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE M BLOWS/FOOT DETAILS Cn 2 5 10 20 30 40 50 70 90 n 11011 1180doodded PARTIALLY WEATHERED ROCK SURFACE COMPLETION which sampled as brown and gray, 16 2.77-foot stick-up with a 4" x 4" ago slightly moist, micaceous, slightly 23 50/5" standup locking steel protective clayey, silty, fine to medium SAND 50/3"h cover with�3' x 3' concrete pad atdop adds with gravel size rock fragments - e base with a survey pin (residuum) 4 installed t th 18 a e :...:....:...:...:.....:....:....:...:..._..:.. . 50/2 0 1/ -inch weep hole ins a ed 1175 5...:.......:...:.....:...:...:...:..:..:...:. 0 emotional base of the steel cover NOUN aged .....:...:....:...:..:.....:....:...:...:. 7 ..:.....:. Pea gravel installed inside theOff 20 : : : : : so/a if steel cover between the cover and 50/5":...:....:...:...:.....:....:....:......:.....: the PVC casing dow Auger refusal at 8.0 feet.dead ........ ad ............................. NO ...... 0 NOW Brown and gray gneiss BEDROCKNow :.... NO ......:.....0....:....:...:...:..:... Grout, 0 to 17.9 feet NOW 1170 damages10:...:....:...:...:.....:....:....:...:...:..:..:. NOW adds 4 ........_.............................................. ONE of 0 damaged 1165 NNNNNNN 15:...:....:...:...:.....:....:....:.....:..:..:. 1101, Maps ........_..... ......................................... ONO ONE, adds 0 ....:...:....: ...:.. *as ....:....... .0.:.00:.0:.40*6 0 Bentonite seal, 17.9 to 20.0 feet ago 1160 damaged20 Filter pack, #1 sand 20.0 to 45.0 Now adds 9 ....:...:....:...:...:.... add ...:... fee ..:...:..:...:. 0 feetsea Now adds 4 ............................................._......... age am 1155 NONNON25:...:....:...:.......:....:....:...:..:.:..:. 2-inch diameter, 0.01010inch slotted 0 Schedule 40 PVC well screen, 1150 30does :...:....:...:...:.....:....:....:...:.....:..:.go 0 22.37 to 37.37 feet ease a ........_.............................................. ONE 1145 35:...:....:...:.........:....:....:...:...:..:...:. .... a...:....:.00:.04:.044.:.0909 ..0.9 .009 .00:.0:.0.00 • .. Pipe capsea dead 9 ....:...:....:...:...:.....:....:....:...:...:..:...:0 a: '. •.' . Total well depth, 37.62 feet GROUNDWATER MONITORING WELL NO. MW-7 Sheet 1 of 2 INC. ENGINEERINIG, INC. GEOTECHNICALAND ENVIRONMEIif iAL ELEVATION/ DEPTH (FT) N N O CONSULTANTs PROJECT: Foothills Tonal MOW Landfill CLIENT: Republic LOCATION: Caldwell County, North Carolina DRILLER: Land DRILLING METHOD: CME 750 ATV; 6-inch air hammer DEPTH TO - WATER> INITIAL: 4. W SOIL -J DESCRIPTION CL TYPE a co Brown and gray gneiss BEDROCK Boring terminated at 45.0 feet. Groundwater encountered at 30.0 feet at time of drilling and at 23.29 feet after 24 hours. 30.0 AFTER 24 HOURS: � STANDARD PENETRATION RESULTS BLOWS/FOOT 2 5 10 20 30 40 50 70 90 .:...:...................................._ ......... _...................................._......... :............:....................................9 _._ ............................................ PROJECT NO.: J09-1235-55 START: 4-19-10 END:4-19-10 ELEVATION: 1,180.36 LOGGED BY: M. Preddy 23.29 MONITOR WELL INSTALLATION DETAILS Ground surface elev.=1,180.36 feet Top of PVC pipe elev.=1,183.13 feet Northing = 799,591.48' Fasting = 1,230,261.an, J J 0 w D GROUNDWATER MONITORING WELL NO. MW-7 Sheet 2 of 2 3 11 CilIL 0 i ENGINEERING, INC. GEOTEton IC %16 MW ENVIROI CJMTAL PROJECT: Foothills Regional MOW Landfi CLIENT: Republic Services of North Carolina, LLC LOCATION: Caldwell County, North Carolina DRILLER: Land R. Banks PROJECT NO.: J13-1235-62 START: 4-8-13 END: 4-9-13 ELEVATION: 1192.35 LOGGED BY: P. VanHeest DRILLING METHOD: CME 750; 8.25-inch auger DEPTH TO - WATER> INITIAL: 31.55 AFTER 24 HOURS: V. 30.90 CAVING>3M DEPTH (FT) I DESCRIPTION TYPE ICI BLOWS/FOOT TIN RESULTS "' 2 5 10 20 30 40 50 70 90 Very loose, brown, slightly moist, MOM micaceous, silty, fine to coarse .. • ...... _ . . . . _ ............ . ...:.......:...:....:. . SAND - (fill) 2 1190 2 * ...:...:...:.....:....:....:...:...:..:...:.. MOM Made ........._.............................................. MOMMENO 5 1..........:...:.....:....:....:...:...:..:...:.. statements attendants statements Very loose, brown, moist, — — — 1MEMO ........ as ....: ... sea ...... so* .............. sea ..:. . micaceous, silty, clayey, fine to 2 1185MED coarse SAND - (fill) 2 :. !....:...:...:.....:....:....:...... . .....:. . Firm, gray, moist, slightly :...:....:.: ...:........:....:....:........... . MON,i2 caceous, fine to medium sandy, 2 - m 10 clayey SILT - (residuum) 3 :.. �...:...:.....:........:...:...:.....:. . ........_............................................. a 1180 Very firm, gray, slightly moist, 9 so 0 so 1101, micaceous, silty, fine to medium dead a • • • • : • • • d • • = SAND a 0 P 0 5 9 MOMMEND 15 13.....NO .... NO .. add ..:.................... eat .... ad 1175 PARTIALLY WEATHERED ROCK which sampled as gray, slightly moist, micaceous, silty, fine to 400/„ coarse SAND with some gravel 50/5" 20 (weathered GNEISS) ....... _ .... NO ...........:..............:...... . MOD dead .................................................:...... 1170 a 0 4 a 0 a 0 a 50/5 25.............:.....:....:....:...:...:..:.... 1165 Dense, gray, slightly moist, :...:....:...:...:.....:....:....:......:.....:. . micaceous, silty, fine to coarse SAND and some gravel (weathered 5 MOMM GNEISS) 39 :...:....:...:...:.....:....:.. ..:...:.....:. . 30 10....:...:....:...:...:.....:....:....::..:...:..:...:.. 1160 Very firm, gray, wet, micaceous, silty, fine to coarse SAND (weathered GNEESS) 7 35 14....:...:.......:...:.....:....:....:...:...:..:...00 1155 Very firm, gray, wet, micaceous, clayey, silty, fine to coarse SAND (weathered GNEISS) of d 0 0 P 0 7 13:...:....:..add ..:... WON .. add .. add .....:.....:. 15 MONITOR WELL INSTALLATION DETAILS SURFACE COMPLETION 2.83-foot stick-up with a 4" x 4" standup locking steel protective cover with a 3' x 3' concrete pad at the base with a survey pin 1/4-inch weep hole installed at the base of the steel cover Pea gravel installed inside the steel cover between the cover and the PVC casing Top of PVC casing elev.=1,195.18 feet Ground surface elev.=1,192.35 feet Survey pin elev.=1,192.33 feet Northing = 800,317.45' Fasting = 1,230,064.42' Grout, 0 to 17.4 feet Bentonite seal, 17.4 to 28.35 feet Filter pack, sand 28.35 to 48.5 feet 2-inch diameter, 0.010-inch slotted Schedule 40 PVC well screen, 28.7 to 43.7 feet GROUNDWATER MONITORING WELL NO. MW-8 Sheet 1 of 2 N N a IBLEINCo GROUNDWATER MONITORING WELL NO. MW=8 PROJECT: Foothills Regional MSW Landfill PROJECT NO.. J13-1235-62 CLIENT: Republic Services of North Carolina, LLC START: 4-8-13 END: 4-9-13 BUNNELL-CANNONS ENGINEERING, INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1192.35 GEarECHNicALAmEHvuto DRILLER: Landprobe, R. Banks LOGGED BY: P. VanHeest CONSULTANTS DRILLING METHOD: CME 750; 8.25-inch auger DEPTH TO - WATER> INITIAL: V MEN 31.55 AFTER 24 HOURS: Z 30.90 CAVING> w ELEVATION/ SOIL � STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) DESCRIPTION TYPE M BLOWS/FOOT DETAILS 0 2 5 10 20 30 40 50 70 90 Very firm, gray, wet, micaceous, :. :::: ..........:...:.....:....:....:...:...:..:.... 0. Add clayey, silty, fine to coarse SAND 0. 2-inch diameter,010-inch slotted NOW (weathered GNEISS).....:...:....:...:...:.....:....:....:...:...:..:...:. Schedule 40 PVC well screen, 28.7 ded 1150 to 43.7 feet NobVery firm, grayish -brown, wet, — — 7 : ...:.... do ...:...:.....:........:...:...:..:0 13 Pipe cap ONE micaceous, silty, fine to coarse 13NNNNNNN• ' 45 SAND (weathered GNEISS) : '• . Total well depth, 43.9 feet Boring terminated at 48.5 feet. 50 Groundwater encountered at 31.55 a 0 a 0 a Nodded" ...:...:.....:....:....:...:...:..:...d0 . feet at time of drilling and at 30.90 :...:....:...:...:................:...:.....:. 0 Add feet after 24 hours. 1140 led_..... ..............................._......... ANN 55eye eve .....:....:....:...:...:..:...:. ................................:............_ ..:...... Add 60:...:....:...:...:.....:....:....:...:...:..:...o0 .......a _..... ..............................._......... Add 1130 65:...:....:...:...:.....:....:....:...:...:..:...:. good 0 .... .... ............ ON* ... *ON ................_ ......... add 1125 : : : 70:...:....:...:...:.....:....:....:...:...:..ON ..:. ........._...................................._......... add 1120 NONNON75 ..:...:....:...:...:.....:....:....:...:...:..:..:. 0 Eugene 1115 GROUNDWATER MONITORING WELL NO. MW=8 Sheet 2 of 2 „LMINC. GROUNDWATER MONITORING WELL NO. MW-9 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J16-1235-83 BUNNELL-LAMMONS CLIENT: Republic Services of NC, LLC START: 6-29-16 END: 7-6-16 ENGINEERING, INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1288.10 GEOTECHNICAL AND EN VIRONMENTAL DRILLER: Landprobe, J. Gorman LOGGED BY: M. Preddy CONSULTANTS DRILLING METHOD: CME 75 Marooka; 8.25-inch OD hollow stem auger DEPTH TO - WATER> INITIAL: 66.5 AFTER 24 HOURS:1 61.2 CAVING>3M CO w ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE 2 BLOWS/FOOT DETAILS a N 2 5 10 20 30 40 50 70 90 Firm to stiff, brown, slightly moist, SURFACE COMPLETION micaceous, clayey, fine to 2.69-foot stick-up with a 4” x 4" medium sandy SILT - (compacted standup locking steel protective structural fill cover with a Tx 3' concrete pad at the base with a survey pin 1285 2 Top of PVC casing elev. = 1,290.79 3 3 ..... feet 5 ... ........................................................ Ground surface elev. = 1,288.10 feet Survey pin elev. = 1,288.10 feet 1280 Northing = 798,515.11' 3 5 Easting = 1,231,973.00' 10 6 .. 1275 2 3 3 ...:. 15 ... 1270 3 4 9 20 .... Neat cement grout, 0 to 42.3 feet Dense, light gray and black, 1265 slightly moist, very micaceous, silty, fine to coarse SAND - (fill) 12 16 25 17 - - - - - - - - - - - - - - Dense, dark gray, moist, very .... 1260 micaceous, silty, fine to medium SAND - (fill) 19 23 23 .... 30 ..... Firm, gray, slightly moist, 1255 micaceous, silty, fine to medium SAND with saprolite foliation 3 banding - (residuum) 4 • 35 70 1250 17 24 •,... 22 GROUNDWATER MONITORING WELL NO. MW-9 Sheet 1 of 2 „LMINC. GROUNDWATER MONITORING WELL NO. MW-9 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J16-1235-83 BUNNELL-LAMMONS CLIENT: Republic Services of NC, LLC START: 6-29-16 END: 7-6-16 ENGINEERING, INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1288.10 GEOTECHNICAL AND EN VIRONMENTAL DRILLER: Landprobe, J. Gorman LOGGED BY: M. Preddy CONSULTANTS DRILLING METHOD: CME 75 Marooka; 8.25-inch OD hollow stem auger DEPTH TO - WATER> INITIAL: 66.5 AFTER 24 HOURS:1 61.2 CAVING>3M C0 w ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE 2 BLOWS/FOOT DETAILS a N 2 5 10 20 30 40 50 70 90 Firm, gray, Slightly moist, Neat cement grout, 0 to 42.3 feet micaceous, silty, fine to medium SAND with saprolite foliation banding - (residuum) Firm, brown, slightly moist, very 1245 micaceous, slightly clayey, silty, 4 fine to medium SAND 8 45 ..... Dense, gray, slightly moist, 1240 micaceous, silty, fine to medium Bentonite seal, 42.3 to 55.9 feet SAND with saprolite foliation 12 banding 22 • .. 50 20 1235 3 12 30 55 ... Filter pack, #0 sand, 55.9 to 75.0 feet PARTIALLY WEATHERED ROCK 1230 which sampled as gray, slightly moist, micaceous, silty, fine to 32 50/4^ medium SAND with saprolite 50/4” 60 foliation banding 1225 .... 30 50/2" .... 65 ... 2-inch diameter, 0.010-inch slotted ... ...:. Schedule 40 PVC well screen, PARTIALLY WEATHERED ROCK 59.61 to 74.61 feet 1220 which sampled as brown, wet, - slightly clayey, silty, fine to coarse 50/3" : : SAND 70 Auger refusal at 69.0 feet Gray, fine to medium, very micaceous, SCHIST BEDROCK 1215 .... 75 Pipe cap Boring terminated at 75.0 feet. Total well depth, 74.86 feet Groundwater encountered at 66.5 feet at time of drilling and at 61.2 1210 feet after 24 hours. GROUNDWATER MONITORING WELL NO. MW-9 Sheet 2 of 2 ,ILMINC. GROUNDWATER MONITORING WELL NO. MW-10 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J15-1235-74 CLIENT: Republic Services of NC, LLC START: 10-7-15 END: 10-19-15 BUNNELL-LAMMONS ENGINEERING, INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1355.08 GEOTECHNICALANDENVIRONMENTAL DRILLER: Landprobe, J. Gorman LOGGED BY: I. Irizarry CONSULTANTS DRILLING METHOD: CME 75; 8-1/4 inch OD hollow stem auger and 6-inch OD air rotary bit DEPTH TO - WATER> INITIAL: V dry AFTER 24 HOURS: 1 73.5 CAVING>3W w ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE BLOWS/FOOT DETAILS U) 2 5 10 20 30 40 50 70 90 MH Hard, gray, dry, slightly SURFACE COMPLETION micaceous, fine sandy SILT - .....:.........:.. = = 3.45-foot stick-up with a 4" x 4" (residuum) standup locking steelprotective pad a cover with a 3' x 3' concrete a t the base with a survey pin 8 - - installed at th 1l4 inch weep hole insta e 16 base of the steel cover 1350 5 34 ..........:......:..:..:... vent hole in p of PVC 1/4 inch to casing Stiff, yellowish -brown, dry, slightly micaceous, fine sandy .....:... Pea gravel installed inside the steel SILT 6 the d th cover between a cover an e 7 .....:...:....:............:......: PVC casing 1345 10 7 .... Top of PVC casing elev. = 1,358.53 fee ....:...:....:............:......:..:..:... Ground 13 d surface elev. _ 55.08 PARTIALLY WEATHERED ROCK feet which sampled as brown to .....:.........7.. Su pin elev. = 1,356.08 feet y grayish -brown, dry, micaceous, 11 silty, fine to medium SAND 16 ...:..:..50' . 1340 15 5014" :. _... Northing = 799,077.81' ....:...:....:............:......:..:..:... 1 Easti'n g = 2324 05.55 Stiff to very stiff, brown and gray, dry, micaceous, fine to ..... :......... :............:......:..:..:... medium sandy SILT 7 5 12 ............� ....................:..:..:.:.. 1335 20 :...:.. Grout, 0 to 60.2 feet 3 5 7 ..............:� .. .... ....:...:...: 1330 25 Hard, dark grayish -brown, dry, ...... micaceous, fine to medium .....:...:....:.. = = sandy SILT 11 15 17 ..........:..:..:.:.. 1325 30 PARTIALLY WEATHERED ROCK which sampled as dark .....:...:....:.. grayish -brown, dry, micaceous, 32 fine to medium sandy SILT 38 . .... 1320 35 50151, 46 50l3" .....:...:....:..:..:....:....................... GROUNDWATER MONITORING WELL NO. MW-10 Sheet 1 of 3 ,ILMINC. GROUNDWATER MONITORING WELL NO. MW-10 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J15-1235-74 CLIENT: Republic Services of NC, LLC START: 10-7-15 END: 10-19-15 BUNNELL-LAMMONS ENGINEERING, INC. LOCATION: Caldwell County, North Carolina ELEVATION: 1355.08 DRILLER: Landprobe, J. Gorman LOGGED BY: I. Irizarry GEOTECHNICALANDENVIRONMENTAL CONSULTANTS DRILLING METHOD: CME 75; 8-1/4 inch OD hollow stem auger and 6-inch OD air rotary bit DEPTH TO - WATER> INITIAL: V dry AFTER 24 HOURS: 1 73.5 CAVING>3W rn w ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE BLOWS/FOOT DETAILS in 2 5 10 20 30 40 50 70 90 PARTIALLY WEATHERED ROCK Grout, 0 to 60.2 feet which sampled as dark "" ......... grayish -brown, dry, micaceous, fine to medium sandy SILT Very hard, gray, moist, micaceous, fine to medium 21 sandy SILT 21 :...:...... 1310 45 .... :......... ..:..:.......... :..:... :..:....:....:.............W, 5013" PARTIALLY WEATHERED ROCK which sampled as gray and 1305 50 brown, slightly moist, micaceous, silty, fine to medium ..........:......:..:..:... SAND Auger refusal at 54.0 feet. Air 50/1.. drilled to 94.5 feet. 130055 ..................................................... Gray GNEISS BEDROCK 1295 60 ......... .....:...:....:..:..:....:....:...:...:..:..:.:.. Bentonite seal, 60.2 to 68.5 feet 1290 fi5 ......... ..........:......:..:..:... #0 Filter sand 68.5 to 94.5 1285 70 ..........:... ". Brown, slightly weathered GNEISS BEDROCK ................:..:..:... 1280 75 ......... " .....:...:....:..:..:....:....................:.. 2-inch diameter, 0.010-inch slotted ....:...:....:.. .. .... ....:.............. .. II scree , Schedule 40 PVC we n 69.56 to 84.56 feet GROUNDWATER MONITORING WELL NO. MW-10 Sheet 2 of 3 ,I L MINC. GROUNDWATER MONITORING WELL NO. MW-10 BUNNELL-LAMMONS ENGINEERING, INC. GEOTECHNICALAND EN V IRONMENTAL CONSULTANTS ELEVATION/ DESCRIPTION DEPTH (FT) PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J15-1235-74 CLIENT: Republic Services of NC, LLC START: 10-7-15 END: 10-19-15 LOCATION: Caldwell County, North Carolina ELEVATION: 1355.08 DRILLER: Landprobe, J. Gorman LOGGED BY: I. Irizarry DRILLING METHOD: CME 75; 8-1/4 inch OD hollow stem auger and 6-inch OD air rotary bit DEPTH TO - WATER> INITIAL: V dry AFTER 24 HOURS: 1 73.5 CAVING>= SOIL ICI STANDARD P PENETRATION RESULTS I MONITOR DEL INSTALLATION TYPE BLOWS/FOOT 2 5 10 20 30 40 50 70 90 Gray GNEISS BEDROCK .....:...:....:..:..:....:....:...:...:..:..:.:.. 2-inch diameter, 0.010-inch slotted ....:...:....:............:......:..:..:... Schedule 40 PVC we n II scree , 69.56 to 84.56 feet 1270 85 ..................... .... ....:......: Pipe p cap ....:...:....:.. .. .... ....:... ........... .. Total well depth, 84.76 feet 1265 90 . . . _.. . #O Filter sand, 68.5 to 94.5 1260 95 .... :......... :............:... Boring terminated at 94.5 feet. No groundwater encountered at...... :......... 7... = = time of drilling, but was encountered at 73.5 feet after 24 hours. .....:...:....:............:................ 1255 100 ........................... 1250 105 ..........................:......:..:..:... 1245 110 ........... .. .... ....:.............. .. 1240 115 ..........:......:..:..:... GROUNDWATER MONITORING WELL NO. MW-10 Sheet 3 of 3 It ' IMMINC. MONITORING WELL NO. MW-11 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 CLIENT: Republic Services of NC, LLC START: 9-6-18 END: 9-7-18 BUNNELL-LAMMONS ENGINEERING, INC. LOCATION: Caldwell County, NC ELEVATION: 1398.66 GEOTECHNICAL AND EN VIRONMENTAL DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel CONSULTANTS DRILLING METHOD: CME 750 8114" O.D., Schramm 6" O.D. DEPTH TO - WATER> INITIAL: V 120.16 AFTER 24 HOURS: 1 77.89 CAVING>3m y W ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE 2 BLOWS/FOOT DETAILS a 2 5 10 20 30 40 50 70 90 rIll Stiff, reddish brown, slightly moist, slightly micaceous, clayey, ................ SURFACE COMPLETION fine sandy, SILT (FILL) 3.38 feet of stickup with 4"x4" ........................................................ stand up looking steel protective cover with a TxT concrete pad at ........... ............................. ......... the base with a survey pin. rve i . 1395 5 6 1/4 inch weephole installed at the 5 7 base of the steel cover. ......... :....: ........................ .:....... 1/4 inch vent hole in top of PVC casing. Firm, tan to light grey, slightly 1390 moist, silty, fine to medium SAND 6 Pea gravel installed inside the (FILL) 6 e steel cover between the cover and 7 ing. PVC casing. 10 .....:............:...:.....................:...... Ground elevation = 1398.66 feet Stiff, reddish brown, slightly . . . 'n 1385 moist, slightly micaceous, clayey, 6 Top o f PVC casing e lev.= 1401.71 fine to coarse sandy, SILT (FILL) 6 feet u Elevation = 76 feet rveyPin7 S EI t' 1398 et 15 8 Of t Northing = 99,549.2 feet .....: ... :....:........................ .:....... Easting = 1,232,383.56 feet Very firm, light brown to light 1380 grey, slightly moist, slightly 7 micaceous, clayey, silty, fine to 14 x • 20 coarse SAND (FILL) 12 G 83 o feet Grout, 0 to ee 1375 9 12 • 25 ........................................................ Very hard, brown, slightly moist, 1370 slightly micaceous, clayey, fine to 11 coarse sandy SILT (FILL) 15 5 / o' 30 50/2" Very firm, greyish brown, slightly 1365 moist, slightly micaceous, silty 9 fine to coarse SAND (FILL) 12 35 15 ........................................................ Very stiff, light brown, slightly 1360 moist, micaceous, clayey, fine to 7 medium sandy, SILT (FILL) 8 22 MONITORING WELL NO. MW-11 Sheet 1 of 4 It ' IMMINC. MONITORING WELL NO. MW-11 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 BUNNELL-LAMMONS CLIENT: Republic Services of NC, LLC START: 9-6-18 END: 9-7-18 ENGINEERING, INC. LOCATION: Caldwell County, NC ELEVATION: 1398.66 GEOTECHNICAL AND EN VIRONMENTAL DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel CONSULTANTS DRILLING METHOD: CME 750 8114" O.D., Schramm 6" O.D. DEPTH TO - WATER> INITIAL: V 120.16 AFTER 24 HOURS: 1 77.89 CAVING>3m y W ELEVATION/ DESCRIPTION SOIL ii STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE a BLOWS/FOOT DETAILS 2 5 10 20 30 40 50 70 90 Auger refusal at 40 feet, air rotary drilled to 121.1 feet .................... Brown, slightly moist, clayey, 1355 silty, fine SAND (FILL) 45..... ............................. ......... .................................: Brown, slightly moist, clayey, fine 1350 sandy, SILT (FILL) 50 ...................................................... ----------------- Brown, slightly moist, slightly ......................................... 1345 micaceous, gravelly, clayey, fine to coarse sandy SILT (FILL) ................................................... 55 ......... ............................. ......... ----------------- Reddish brown, slightly moist, ........................................................ 1340 slightly micaceous, clayey, fine to medium sandy, SILT (FILL) 60 .................................................... 1335 65 ......... .................................. ......... ----------------- Brown, slightly moist, slightly . .............................. . 1330 micaceous, gravelly, clayey, fine to coarse sandy, SILT (FILL) ................................................... 70 ......... ............................. ......... . ........................ . Greyish brown, slightly moist, 1325 slightly micaceous, clayey, fine to coarse sandy, SILT (residuum) 75 ..:........................................: 1320 MONITORING WELL NO. MW-11 Sheet 2 of 4 It ' IMMINC. MONITORING WELL NO. MW-11 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 BUNNELL-LAMMONS CLIENT: Republic Services of NC, LLC START: 9-6-18 END: 9-7-18 ENGINEERING, INC. LOCATION: Caldwell County, NC ELEVATION: 1398.66 GEOTECHNICAL AND EN VIRONMENTAL DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel CONSULTANTS DRILLING METHOD: CME 750 8114" O.D., Schramm 6" O.D. DEPTH TO - WATER> INITIAL: V 120.16 AFTER 24 HOURS:1 77.89 CAVING>'TM ELEVATION/ DESCRIPTION SOIL ii STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE Q BLOWS/FOOT DETAILS N 2 5 10 20 30 40 50 70 90 ............ Bentonite seal, 83.0 to 88.0 feet 1315 .................................................... Greyish brown, weathered gneiss 85 BEDROCK .................................................. Fracture at 87.0 feet ........................................................ ..... ............................. . .......... #0 Filter pack sand, 88.0 to 121.1 1310 ......................................... feet 90 ....:................................................. 2-inch diameter, 0.010-inch slotted ..........................................:...:.. well screen, Schedule 40 PVC we 90.15 to 105.15 feet Fracture at 92.0 feet -- ....................................................... .• . Grey, gneiss BEDROCK 1305 ................................................... .• . 95 ....:................................................. ................................................... .• . Fracture at 97.0 feet ..................................................... ....................................................... 1300 ........................................................ .• . 100 ..:... ..... .......................... ....:...:. .................................................. 1295 Fracture at 103.0 feet ....................................................... ................................................... .• . 105 ......... ............................. ......... Pipe cap ........................................................ Total well depth, 105.35 feet 1290 110 ....:............................................ 1285 115 ... ..... ....................................... 1280 MONITORING WELL NO. MW-11 Sheet 3 of 4 It ' IMMINC. MONITORING WELL NO. MW-11 PROJECT: Foothills Regional MSW Landfill PROJECT NO.: J18-1235-89 CLIENT: Republic Services of NC, LLC START: 9-6-18 END: 9-7-18 BUNNELL-LAMMONS ENGINEERING, INC. LOCATION: Caldwell County, INC ELEVATION: 1398.66 DRILLER: Landprobe R. Banks LOGGED BY: T.J. Daniel GEOTECHNICAL AND EN VIRONMENTAL CONSULTANTS DRILLING METHOD: CME 750 81/4" O.D., Schramm 6" O.D. DEPTH TO - WATER> INITIAL: a 120.16 AFTER 24 HOURS:1 77.89 CAVING>77 N W ELEVATION/ DESCRIPTION SOIL a STANDARD PENETRATION RESULTS MONITOR WELL INSTALLATION DEPTH (FT) TYPE a BLOWS/FOOT DETAILS 2 5 10 20 30 40 50 70 90 ...... ..... . ............... Boring terminated at 121.1 feet below ground surface. .......... ................................... ........... Groundwater initially encountered .......................... . ......... 1275 at 120.16 feet below ground ......................... surface. Groundwater ....... ............. encountered after 24 hours at 125 77.89 feet below ground surface. .................................................. 1270 130 ...................................................... 1265 135 ...................................................... 1260 140 .................................................... 1255 145 ...................................................... 1250 150 ...................................................... 1245 155 ... :....:...................................... 1240 MONITORING WELL NO. MW-11 Sheet 4 of 4 APPENDIX C NCDEQ Water Quality Analytical and Reporting Requirements e;A NCDENR North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director Division of Waste Management Michael F. Easley, Governor William G. Ross Jr., Secretary October 27, 2006 To: SW Director/County Manager/Consultant/Laboratory From: NC DENR-DWM, Solid Waste Section Re: New Guidelines for Electronic Submittal of Environmental Monitoring Data The Solid Waste Section receives and reviews a wide variety of environmental monitoring data from permitted solid waste management facilities, including the results from groundwater and surface water analyses, leachate samples, methane gas readings, potentiometric measurements, and corrective action data. We are in the process of developing a database to capture the large volume of data submitted by facilities. To maintain the integrity of the database, it is critical that facilities, consultants, and laboratories work with the Solid Waste Section to ensure that environmental samples are collected and analyzed properly with the resulting data transferred to the Solid Waste Section in an accurate manner. In order to better serve the public and to expedite our review process, the Solid Waste Section is requesting specific formatting for environmental monitoring data submittals for all solid waste management facilities. Effective, December 1, 2006, please submit a Solid Waste Environmental Monitoring Data Form in addition to your environmental monitoring data report. This form will be sent in lieu of your current cover letter to the Solid Waste Section. The Solid Waste Environmental Monitoring Data Form must be filled out completely, signed, and stamped with a Board Certified North Carolina Geologist License Seal. The solid waste environmental monitoring data form will include the following: 1. Contact Information 2. Facility Name 3. Facility Permit Number 4. Facility Address 5. Monitoring Event Date (MM/DD/YYYY) 6. Water Quality Status: Monitoring, Detection Monitoring, or Assessment Monitoring 7. Type of Data Submitted: Groundwater Monitoring Wells, Groundwater Potable Wells, Leachate, Methane Gas, or Corrective Action Data 8. Notification of Exceedance of Groundwater, Surface Water, or Methane Gas (in table form) a. Signature 10. North Carolina Geologist Seal 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone: 919-508-84001 FAX: 919-733-48101 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer — Printed on Dual Purpose Recycled Paper Page 2 of 2 Most of these criteria are already being included or can be added with little effort. The Solid Waste Environmental Monitoring Data Form can be downloaded from our website: hllp://www.wastenotnc.org/swhome/enviro monitoring.asp. The Solid Waste Section is also requesting a new format for monitoring wells, potable wells, surface water sampling locations, and methane probes. This format is essential in the development and maintenance of the database. The Solid Waste Section is requesting that each sampling location at all North Carolina solid waste management facilities have its own unique identification number. We are simply asking for the permit number to be placed directly in front of the sampling location number (example: 9901-MW1 = Permit Number 99-01 and Monitoring Well MW-1). No changes will need to be made to the well tags, etc. This unique identification system will enable us to accurately report data not only to NCDENR, but to the public as well. We understand that this new identification system will take some time to implement, but we feel that this will be beneficial to everyone involved in the long term. Additionally, effective December 1, 2006, the Practical Quantitation Limits (PQLs) established in 1994 will change. The Solid Waste Section is requiring that all solid waste management facilities use the new Solid Waste Reporting Limits (SWRL) for all groundwater analyses by a North Carolina Certified Laboratory. Laboratories must also report any detection of a constituent even it is detected below the new SWRL (e.g., J values where the constituent was detected above the detection limit, but below the quantitation limit). PQLs are technology -based analytical levels that are considered achievable using the referenced analytical method. The PQL is considered the lowest concentration of a contaminant that the lab can accurately detect and quantify. PQLs provided consistency and available numbers that were achievable by the given analytical method. However, PQLs are not health -based, and analytical instruments have improved over the years resulting in lower achievable PQLs for many of the constituents. As a result, the Solid Waste Section has established the SWRLs as the new reporting limits eliminating the use of the PQLs. We would also like to take this opportunity to encourage electronic submittal of the reports. This option is intended to save resources for both the public and private sectors. The Solid Waste Section will accept the entire report including narrative text, figures, tables, and maps on CD-ROM. The CD-ROM submittal shall contain a CD-ROM case and both CD-ROM and the case shall be labeled with the site name, site address, permit number, and the monitoring event date (MM/DD/YYYY). The files maybe a .pdf, .txt, .csv, .xls, or .doc type. Also, analytical lab data should be reported in an .xls file. We have a template for analytical lab data available on the web at the address listed above. If you have any questions or concerns, please call (919) 508-8400. Thank you for your anticipated cooperation in this matter. North Carolina Dexter R. Matthews, Director MEMORANDUM 4 'A ,A_�79 0 . NCDENR Department of Environment and Division of Waste Management February 23, 2007 Natural Resources Michael F. Easley, Governor William G. Ross Jr., Secretary To: Solid Waste Directors, Landfill Operators, North Carolina Certified Laboratories, and Consultants From: North Carolina Division of Waste Management, Solid Waste Section Re: Addendum to October 27, 2006, North Carolina Solid Waste Section Memorandum Regarding New Guidelines for Electronic Submittal of Environmental Data. The purpose of this addendum memorandum is to provide further clarification to the October 27, 2006, North Carolina Solid Waste Section memo titled, "New Guidelines for Electronic Submittal of Environmental Data." The updated guidelines is in large part due to questions and concerns from laboratories, consultants, and the regulated community regarding the detection of constituents in groundwater at levels below the previous practical quantitation limits (PQLs). The North Carolina Solid Waste Section solicited feedback from the regulated community, and, in conjunction with the regulated community, developed new limits. The primary purpose of these changes was to improve the protection of public health and the environment. The North Carolina Solid Waste Section is concerned about analytical data at these low levels because the earliest possible detection of toxic or potentially carcinogenic chemicals in the environment is paramount in the North Carolina Solid Waste Section's mission to protect human health and the environment. Low level analytical data are critical for making the correct choices when designing site remediation strategies, alerting the public to health threats, and protecting the environment from toxic contaminants. The revised limits were updated based on readily available laboratory analytical methodology and current health -based groundwater protection standards. Definitions Many definitions relating to detection limits and quantitation limits are used in the literature and by government agencies, and commonly accepted procedures for calculating these limits exist. Except for the Solid Waste Section Limit and the North Carolina 2L Standards, the definitions listed below are referenced from the Environmental Protection Agency (EPA). The definitions are also an attempt to clarify the meaning of these terms as used by the North Carolina Solid Waste Section. Method Detection Limit (MDL) is the minimum concentration of a substance that can be measured and reported with 99% confidence that the analyte concentration is greater than zero. Method Reporting Limit or Method Quantitation Limit (MRL or MQL) is the minimum concentration of a target analyte that can be accurately determined by the referenced method. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper Practical Quantitation Limit (PQL) is a quantitation limit that represents a practical and routinely achievable quantitation limit with a high degree of certainty (>99.9% confidence) in the results. Per EPA Publication Number SW-846, the PQL is the lowest concentration that can be reliably measured within specified limits of precision and accuracy for a specific laboratory analytical method during routine laboratory operating conditions in accordance with "Test Methods for Evaluating Solid Wastes, Physical/Chemical Methods. The PQL appears in older NCDENR literature; however, it is no longer being used by the North Carolina Solid Waste Section. Solid Waste Section Limit (SWSL) is the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy. The SWSL is the concentration below which reported analytical results must be qualified as estimated. The SWSL is the updated version of the PQL that appears in older North Carolina Solid Waste Section literature. The SWSL is the limit established by the laboratory survey conducted by the North Carolina Solid Waste Section. The nomenclature of the SWRL described in the October 27, 2006, memorandum has changed to the SWSL. North Carolina 2L Standards (2L) are water quality standards for the protection of groundwaters of North Carolina as specified in 15A NCAC 2L .0200, Classifications and Water Quality Standards Applicable to the Groundwaters of North Carolina. Method Detection Limits (MDLs) Clarification of detection limits referenced in the October 27, 2006, memorandum needed to be addressed because of concerns raised by the regulated community. The North Carolina Solid Waste Section is now requiring laboratories to report to the method detection limit. Method detection limits are statistically determined values that define the concentration at which measurements of a substance by a specific analytical protocol can be distinguished from measurements of a blank (background noise). Method detection limits are matrix -specific and require a well defined analytical method. In the course of routine operations, laboratories generally report the highest method detection limit for all the instruments used for a specific method. In many instances, the North Carolina Solid Waste Section gathers data from many sources prior to evaluating the data or making a compliance decision. Standardization in data reporting significantly enhances the ability to interpret and review data because the reporting formats are comparable. Reporting a method detection limit alerts data users of the known uncertainties and limitations associated with using the data. Data users must understand these limitations in order to minimize the risk of making poor environmental decisions. Censoring data below unspecified or non -statistical reporting limits severely biases data sets and restricts their usefulness. Solid Waste Section Limits (SWSLs Due to comments from the regulated community, the North Carolina Solid Waste Section has changed the nomenclature of the new limits referenced on Page 2 of the October 27, 2006, memorandum, from the North Carolina Solid Waste Reporting Limits (SWRL) to the Solid Waste Section Limits (SWSL). Data must be reported to the laboratory specific method detection limits and must be quantifiable at or below the SWSL. The SWSLs must be used for both groundwater and surface water data reported to the North Carolina Solid Waste Section. The PQLs will no longer be used. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper The North Carolina Solid Waste Section has considered further feedback from laboratories and the regulated community and has made some additional changes to the values of the SWSLs. These changes may be viewed on our webpage: http://www.wastenotnc.org/sw/swenvmonitoringlist.asp Analytical Data Reporting Requirements The strategy for implementing the new analytical data reporting requirements involves reporting the actual laboratory method detection limit with all analytical laboratory results along with the following requirements: 1) Any analyte detected at a concentration greater than the MDL but less than the SWSL is known to be present, but the uncertainty in the value is higher than a value reported above the SWSL. As a result, the actual concentration is estimated. The estimated concentration is reported along with a qualifier ("J" flag) to alert data users that the result is between the MDL and the SWSL. Any analytical data below quantifiable levels should be examined closely to evaluate whether the analytical data should be included in any statistical analysis. A statistician should make this determination. If an analyte is detected below the North Carolina 2L Standards, even if it is a quantifiable concentration, compliance action may not be taken unless it is statistically significant increase over background. These analytical results may require additional confirmation. 2) Any analyte detected at a concentration greater than the SWSL is present, and the quantitated value can be reported with a high degree of confidence. These analytes are reported without estimated qualification. The laboratory's MDL and SWSL must be included in the analytical laboratory report. Any reported concentration of an organic or inorganic constituent at or above the North Carolina 2L Standards will be used for compliance purposes, unless the inorganic constituent is not statistically significant). Exceedance of the North Carolina 2L Standards or a statistically significant increase over background concentrations define when a violation has occurred. Any reported concentration of an organic or inorganic constituent at or above the SWSL that is not above an North Carolina 2L Standard will be used as a tool to assess the integrity of the landfill system and predict the possibility that a constituent concentration may exceed the North Carolina 2L Standards in the future. These analytical results may be used for compliance without further confirmation. Failure to comply with the requirements described in the October 27, 2006, memorandum and this addendum to the October 27, 2006, memorandum will constitute a violation of 15A NCAC 13B .0601, .0602, or .1632(b), and the analytical data will be returned and deemed unacceptable. Submittal of unacceptable data may lead to enforcement action. Electronic Data Deliverable (EDD) Submittal The North Carolina Solid Waste Section would also like to take this opportunity to encourage electronic submittal of the reports in addition to the analytical laboratory data. This option is intended to save resources for both the public and private sectors. The North Carolina Solid Waste Section will accept the entire report including narrative text, figures, tables, and maps on CD-ROM. Please separate the figures and tables from the report when saving in order to keep the 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 3 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper size of the files smaller. The CD-ROM submittal shall contain a CD-ROM case and both CD-ROM and the case shall be labeled with the site name, site address, permit number, and the monitoring event date (MM/DD/YYYY). The reporting files maybe submitted as a .pdf, .txt, .csv, .xls,. or .doc type. Also, analytical lab data and field data should be reported in .xls files. The North Carolina Solid Waste Section has a template for analytical lab data and field data. This template is available on our webpage: http://www.wastenotnc.org/swhome/enviro_monitoring.asp. Methane monitoring data may also be submitted electronically in this format. Pursuant to the October 27, 2006, memorandum, please remember to submit a Solid Waste Section Environmental Monitoring Reporting Form in addition to your environmental monitoring data report. This form should be sealed by a geologist or engineer licensed in North Carolina if hydrogeologic or geologic calculations, maps, or interpretations are included with the report. Otherwise, any representative that the facility owner chooses may sign and submit the form. Also, if the concentration of methane generated by the facility exceeds 100% of the lower explosive limits (LEL) at the property boundary or exceeds 25% of the LEL in facility structures (excluding gas control or recovery system components), include the exceedance(s) on the North Carolina Solid Waste Section Environmental Monitoring Reporting Form. If you have any questions or concerns, please feel free to contact Jaclynne Drummond (919-508-8500) or Ervin Lane (919-508-8520). Thank you for your continued cooperation with this matter. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 4 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper 46PA NCDENR North Carolina Department of Environment and Natural Resources Dexter R. Matthews, Director MEMORANDUM Division of Waste Management October 16, 2007 Michael F. Easley, Governor William G. Ross Jr., Secretary To: Solid Waste Directors, Landfill Operators, North Carolina Certified Laboratories, and Consultants From: North Carolina Division of Waste Management, Solid Waste Section Re: Environmental Monitoring Data for North Carolina Solid Waste Management Facilities The purpose of this memorandum is to provide a reiteration of the use of the Solid Waste Section Limits (SWSLs), provide new information on the Groundwater Protection Standards, and provide a reminder of formats for environmental monitoring data submittals. The updated guidelines are in large part due to questions and concerns from laboratories, consultants, and the regulated community regarding the detection of constituents in groundwater at levels below the previous Practical Quantitation Limits (PQLs). The North Carolina Solid Waste Section solicited feedback from the regulated community, and, in conjunction with the regulated community, developed new limits. The primary purpose of these changes was to improve the protection of public health and the environment. Data must be reported to the laboratory specific method detection limits and must be quantifiable at or below the SWSLs. The SWSLs must be used for both groundwater and surface water data reported to the North Carolina Solid Waste Section. The PQLs will no longer be used. In June 2007, we received new information regarding changes to the Groundwater Protection Standards. If a North Carolina 2L Groundwater Standard does not exist, then a designated Groundwater Protection Standard is used pursuant to 15A NCAC 13B .1634. Toxicologists with the North Carolina Department of Health and Human Services calculated these new Groundwater Protection Standards. Questions regarding how the standards were calculated can be directed to the North Carolina Department of Health and Human Services. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org 1 An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper We have reviewed the new results from the North Carolina Department of Public Health and have updated our webpage accordingly. The list of Groundwater Protection Standards, North Carolina 2L Standards and SWSLs are subject to change and will be reviewed every year or sooner if new scientific and toxicological data become available. Please review our website periodically for any changes to the 2L NC Standards, Groundwater Protection Standards, or SWSLs. Specific updates will be noted on our website. http://www.wastenotnc.org/sw/swenvmonitorin lig st.asp In addition, the following should be included with environmental monitoring data submittals: 1. Environmental Monitoring Data Form as a cover sheet: http://www.wastenotnc. org/swhome/EnvMonitoring/NCEnvMonRptFonn.pdf 2. Copy of original laboratory results. 3. Table of detections and discussion of 2L exceedances. 4. Electronic files on CD or sent by email. These files should include the written report as a Portable Document Format (PDF) file and the laboratory data as an excel file following the format of the updated Electronic Data Deliverable (EDD) template on our website: http://www.wastenotnc.org/swhome/enviro monitoring.asp If you have any questions or concerns, please feel free to contact Donald Herndon (919- 508-8502), Ervin Lane (919-508-8520) or Jaclynne Drummond (919-508-8500). Thank you for your continued cooperation with these matters. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2 Phone 919-508-84001 FAX 919-715-36051 Internet http://wastenotnc.org An Equal Opportunity / Affirmative Action Employer— Printed on Dual Purpose Recycled Paper A� L&� NCDENR North Carolina Department of Environment and Natural Resources Division of Waste Management Pat McCrory John E. Skvarla, III Governor Secretary November 5, 2014 MEMORANDUM To: Solid Waste Directors, Public Works Directors, Landfill Operators, and Landfill Owners From: Solid Waste Section Re: Groundwater, Surface Water, Soil, Sediment, and Landfill Gas Electronic Document Submittal The Solid Waste Section is continuing its efforts to improve efficiencies in document management. All groundwater, surface water, soil, sediment, and landfill gas documents submitted to the Solid Waste Section are stored electronically and are made readily available for the public to view on our webpage. Please remember that hard copies/paper copies are not required, and should not be submitted. The submittal of these electronic documents following a consistent electronic document protocol will also assist us in our review. Please follow these procedures when submitting all groundwater, surface water, soil, sediment, and landfill gas documents to the Solid Waste Section. Submittal Method and Formatting • All files must be in portable document format (pdf) except for Electronic Data Deliverables (EDDs) unless otherwise specified by the Solid Waste Section. All pdf files should meet these requirements: o Optical Characteristic Recognition (OCR) applied; o Minimum of 300 dpi; o Free of password protections and/or encryption (applies to EDDs as well); o Optimized to reduce file size; and o Please begin using the following naming convention when submitting all electronic files: Permit Number (00-00)_Date of Document (YYYYMMDD). For example: 00-00_20140101. • Please submit all files via email or by file transfer protocol (FTP) via email to the appropriate Hydrogeologist unless otherwise specified by the Solid Waste Section. If the electronic file is greater than 20 MB, please submit the file via FTP or on a CD. If submitting a CD, please mail the CD to the appropriate Hydrogeologist. The CD should be labeled with the facility name, permit number, county, name of document, date of monitoring event (if applicable), and the date of document. • Please be sure a signed Environmental Monitoring Data Form is submitted as part of the electronic file for all water quality and landfill gas documents (monitoring, alternate source demonstration, assessment, investigation, corrective action). This completed form should be the first page of the document before the cover/title page and should not be submitted as an individual file. Blank forms can be downloaded at http://www.wastenotnc.org/swhome/EnvMonitoring/NCEnvMonRptForrnpdf Monitoring Data Monitoring data documents may include any or all of the following: 1) groundwater and surface water monitoring; 2) soil and sediment, and 3) landfill gas monitoring. In addition to the above procedures, at a minimum, please include the following: Groundwater and Surface Water Monitoring • A copy of the laboratory report(s). • A copy of the sampling log(s). • A separate table of detections and exceedances for each monitoring location. 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2090 US Highway 70, Swannanoa, North Carolina 28778-82111 Phone: 919-707-8200 Phone: 828-296-4500 http://portal.ncdenr.org/web/wm/ An Equal Opportunity / Affirmative Action Employer o All analytical results should be reported in micrograms per liter (ug/L) except for field parameters and specific Monitored Natural Attenuation (MNA) parameters. o Please also include the laboratory's method detection limit (MDL) in ug/L, the Solid Waste Section Limit (SWSL) in ug/L, the appropriate NC regulatory standard in ug/L (2L, 213, GWPS, IMAC), and the Federal Maximum Contaminant Level (MCL) in ug/L. o Please BOLD each exceedance result. • A separate table of field parameters for each monitoring location. • An Electronic Data Deliverable (EDD) spreadsheet for each monitoring event submitted in the correct format. All analytical results should be reported in micrograms per liter (ug/L) except for field parameters and specific Monitored Natural Attenuation (MNA) parameters. The blank EDD template can be downloaded at hqp://www.wastenotnc.org,/swhome/enviro_monitoring.asp. Please pay attention to the formats within the spreadsheet. Any EDD received that is not formatted correctly will be emailed back to be resubmitted via email within five (5) days. • A separate groundwater monitoring well construction table. o Please also include the date the well was drilled, well diameter, total well depth, depth to top of screened interval (in feet), screened interval (in feet), geology of screened interval, TOC elevation, ground elevation, groundwater elevation, GPS coordinates (latitude and longitude), and depth to water (in feet). • A separate groundwater table with groundwater flow rate(s). • A recent facility figure that includes labeled groundwater and surface water monitoring locations. • A groundwater flow map with an arrow(s) indicating flow direction(s), including date the measurements were taken. Soil and Sediment Sampling • A copy of the laboratory report(s). • A copy of the sampling log(s). • A separate table of detections and exceedances for each sampling location. o Please also include the results in micrograms per liter (ug/L), the laboratory's method detection limit (MDL) in ug/L, and the appropriate NC regulatory standard (PSRG) in ug/L. o Please BOLD each exceedance result. • A separate table of soil and/or sediment characteristics. • A recent facility figure that includes labeled sampling locations. Landfill Gas Monitoring • A blank Landfill Gas Monitoring Data Form can be found within the Landfill Gas Monitoring Guidance document and can be downloaded at http://portal.ncdenr.org/c/document_librar/get file?uuid=da699f7e-8cl3-4249-9012- 16af8aefdc7b&groupId=3 8361. • A separate table of landfill gas detections and exceedances for each monitoring location. Please BOLD each exceedance result. • A recent facility figure that includes labeled landfill gas monitoring locations (both permanent and temporary). If you have any questions or concerns regarding electronic submittals, please feel free to contact the Hydrogeologist overseeing your facility. The Solid Waste Section greatly appreciates your assistance on this matter. Working together, we can continue to provide excellent customer service to you and to the public. • Jackie Drummond, Asheville Regional Office, 828-296-4706, jaclynne.drummond a,ncdenr.gov • Ervin Lane, Raleigh Central Office, 919-707-8288, ervin.lane(a),ncdenngov • Elizabeth Werner, Raleigh Central Office, 919-707-8253, elizabeth.werner(a),ncdenngov • Christine Ritter, Raleigh Central Office, 919-707-8254, christine.ritter(d),ncdenngov • Perry Sugg, Raleigh Central Office, 919-707-8258, perry.sugg(a)ncdenr.gov 2 1646 Mail Service Center, Raleigh, North Carolina 27699-1646 2090 US Highway 70, Swannanoa, North Carolina 28778-82111 Phone: 919-707-8200 Phone: 828-296-4500 http://poftal.ncdenr.org/web/wm/ An Equal Opportunity / Affirmative Action Employer Waste Management ENVIRONMENTAL QUALITY September 9, 2016 MEMORANDUM PAT MCCRORY Governor DONALD R. VAN DER VAART Secretary MICHAEL SCOTT Director To: Solid Waste Directors, Public Works Directors, Landfill Operators, and Landfill Owners From: The Solid Waste Section Reference: Guidelines for 14-Day Notification of Groundwater Exceedances Form Submittal per rule: 15A NCAC 13B .1633(c)(1) • The 14-day notification form should be submitted whenever a groundwater protection standard (GWPS) is exceeded for the first time. o As defined in 13B .1634(g)(h), a GWPS will be either of the following: the 2L standard (most cases); 2L Interim Maximum Allowable Concentration; a groundwater protection standard calculated by the SWS; or a site -specific statistical background level approved by the SWS. • If a facility is undergoing assessment or corrective action, the 14-day notification form should be submitted ONLY when the constituent with the reported exceedance is not being addressed through assessment or corrective action. • If a facility plans to conduct a re -sampling event to confirm the initial exceedance, the 14-day notification form should be submitted .ONLY. when the re -sampling event analytical data confirms the initial exceedance. State of North Carolina I Environmental Quality I Waste Management 1646 Mail Service Center 1217 West Jones Street I Raleigh, NC 27699-1646 919 707 8200 T NCDWM Solid Waste Section 14-Day Notification of GWPS Exceedances Flowchart [per Rule 15A NCAC 13B .1633(c)(1)] No 14-Day Notification STOP / Is Facility Groundwater Currently in Protection Assessment 7 � YES Standard YES or Corrective Exceedance* Action? No No '< Does Verification Sampling Confirm GWPS Exceedance(s)? I YES NOTE: *GWPS = see Rule 15A NCAC 13B .1634(g)(h) No Will verification resampling & Analysis be conducted? No Submit 14-Day Notification Form to SWS Is Assessment or CA addressing the Constituent w/ current exceedance value(s)? No 14-Day Notification STOP Proceed with Alternative Source Demonstration (ASD) or Assessment YES August 2016 NC DEQ 14-Day Notification of Groundwater Division of Waste Management - Solid Waste Protection Standard Exceedance(s) per rule: 15A NCAC 136.1633(c)(1) Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed applicable groundwater protection standards. Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDEQ-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Phone: E-mail: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # October 20-24, 2006) Environmental Status: (Check all that apply) ❑ Initial/Background Monitoring ❑ Detection Monitoring ❑ Assessment Monitoring ❑ Corrective Action Additional Information: ❑ A notification of values exceeding a groundwater protection standard as defined in 15A NCAC 13B .1634(g)(h) is attached. It includes a list of groundwater monitoring points, dates, analytical values, NC 2L groundwater standard, NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. ❑ A re -sampling event was conducted to confirm the exceedances. ❑ Alternate Source Demonstration(s) have been approved for the following constituents with report date: Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Facility Representative Name (Print) Signature Facility Representative Address Title NC PG/PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2016 Date (Area Code) Telephone Number Affix NC Licensed/Professional Geologist or Professional Engineer Seal All units are in (ug/L) unless noted. NE = Not Established CAS numbers that begin with "SW" are not real CAS numbers, instead this represents the Solid Waste Section's ID number * GWP = Groundwater Protection ** SWSL = Solid Waste Section Limit CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App 1 630-20-6 1,1,1,2-Tetrachloroethane Ethane, 1,1,1,2-tetrachloro- NE 1.3 5 190 1 71-55-6 1,1,1-Trichloroethane; Meth (chloroform Ethane, 1,1,1-trichloro- 200 -- 1 200 1 79-34-5 1,1,2,2-Tetrachloroethane Ethane, 1,1,2,2-tetrachloro- NE 0.18 3 191 1 79-00-5 1,1,2-Trichloroethane Ethane, 1,1,2-trichloro- NE 0.6 1 202 1 75-34-3 1,1-Dichloroethane; Ethyldidene chloride Ethane, 1,1-dichloro- 70 -- 5 75 1 75-35-4 1,1-Dichloroeth lene; 1,1-Dichloroethene; Ethene, 1,1-dichloro- 7 -- 5 77 1 563-58-6 1,1-Dichloropropene 1-Propene, 1,1-dichloro- NE NE 5 85 II 96-18-4 1,2,3-Trichloro ro ane Propane, 1,2,3-trichloro- 0.005 -- 1 206 1 95-94-3 1,2,4,5-Tetrachlorobenzene Benzene, 1,2,4,5-tetrachloro- NE NE 10 189 II 120-82-1 1,2,4-Trichlorobenzene Benzene, 1,2,4-trichloro- NE 70 10 199 II 96-12-8 1,2-Dibromo-3-chloropropane; DBCP Propane, 1,2-dibromo-3-chloro- 0.025 -- 13 67 1 106-93-4 1,2-Dibromoethane; Ethylene dibromide; EDB Ethane, 1,2-dibromo- 0.0004 -- 1 6811 107-06-2 1,2-Dichloroethane; Ethylene dichloride Ethane, 1,2-dichloro- 0.38 -- 1 76 1 78-87-5 1,2-Dichloropropane Propane,1,2-dichloro- 0.51 -- 1 82 I 142-28-9 1,3-Dichloropropane; Trimethylene dichloride Propane, 1,3-dichloro- NE NE 1 83 II 130-15-4 1,4-Na htho uinone 1,4-Na hthalenedione NE NE 10 149 II 134-32-7 1-Naphthylamine 1-Naphthalenamine NE NE 10 15011 594-20-7 2,2-Dichloropropane; Isopropylidene chloride Propane, 2,2-dichloro- NE NE 15 84,11 58-90-2 2,3,4,6-Tetrachloro henol Phenol, 2,3,4,6-tetrachloro- 210 -- 10 193 II 93-76-5 2,4,5-T; 2,4,5-Trichlorophenoxyacetic acid Acetic acid, (2,4,5-trichlorophenoxy)- NE NE 2 188 II 95-95-4 2,4,5-Trichloro henol Phenol, 2,4,5-trichloro- NE 700 10 204 II 88-06-2 2,4,6-Trichlorophenol Phenol, 2,4,6-trichloro- NE NE 10 205 II 94-75-7 2,4-D; 2,4-Dichloro henox acetic acid Acetic acid, 2,4-dichloro henox - 70 -- 2 59 II 120-83-2 2,4-Dichlorophenol Phenol, 2,4-dichloro- NE NE 10 80 II 105-67-9 2,4-Dimethylphenol; m-X lenol Phenol, 2,4-dimeth I- 140 -- 10 95 II 51-28-5 2,4-Dinitrophenol Phenol, 2,4-dinitro- NE NE 50 99 II 121-14-2 2,4-Dinitrotoluene Benzene, 1-meth I-2,4-dinitro- NE NE 10 100 II 87-65-0 2,6-Dichlorophenol Phenol, 2,6-dichloro- NE NE 10 81 II 606-20-2 2,6-Dinitrotoluene Benzene, 2-meth I-1,3-dinitro- NE NE 10 101 II 53-96-3 2-Acetylaminofluorene; 2-AAF Acetamide, N-9H-fluoren-2-yl- NE NE 20 6 II 91-58-7 2-Chlorona hthalene Naphthalene, 2-chloro- NE NE 10 47,11 95-57-8 2-Chlorophenol Phenol, 2-chloro- 0.36 -- 10 48 II 591-78-6 2-Hexanone; Methyl butyl ketone 2-Hexanone NE 280 50 124 1 91-57-6 2-Methyl naphthalene Naphthalene, 2-methyl- 14 -- 10 145 II 91-59-8 2-Na hth lamine 2-Na hthalenamine NE NE 10 151 II 91-94-1 3,3'-Dichlorobenzidine [1,1'-Biphenyl]-4,4'-diamine,3,3'-dichloro- NE NE 1 20 7211 119-93-7 3,3'-Dimeth Ibenzidine [1,1'-Bi hen I-4,4'-diamine,3,3'-dimeth I- NE NE 10 94 II 56-49-5 3-Meth Icholanthrene Benz']aceanth lene,1,2-dih dro-3-meth I- NE NE 101 138 II 72-54-8 4,4'-DDD Benzene 1,1'-(2,2-dichloroethylidene)bis[4- chloro- 0.14 -- 0.1 60 II 72-55-9 4,4'-DDE Benzene, 1,1'-(dichloroethenylidene)bis[4- chloro- NE NE 0.1 61 II 50-29-3 4,4'-DDT Benzene, 1,1'-(2,2,2- trichloroeth lidene)bis 4-chloro- 0.1 -- 0.1 62 II 534-52-1 4,6-Dinitro-o-cresol; 4,6-Dinitro-2- meth I henol Phenol, 2-meth I-4,6-dinitro- NE NE 50 98 II 92-67-1 4-Aminobiphenyl [1,1'-Biphenyl]-4-amine NE NE 20 11 II 101-55-3 4-Bromo hen I phenyl ether Benzene, 1-bromo-4- henox - NE NE 10 31.11 7005-72-3 4-Chlorophenyl phenyl ether Benzene, 1-chloro-4-phenoxy- NE NE 10 49 II 108-10-1 4-Methyl-2-pentanone; Methyl isobutyl ketone 2-Pentanone, 4-methyl- NE 5601 100 147 1 99-55-8 5-Nitro-o-toluidine Benzenamine, 2-methyl-5-nitro- NE NE 10 157 II 57-97-6 7,12-Dimethylbenz[a]anthracene Benz[a]anthracene, 7,12-dimethyl- NE NE 10 93 II 83-32-9 Acena hthene Acena hth lene, 1,2-dih dro- 80 -- 10 1 II 208-96-8 Acenaphthylene Acenaphthylene 210 -- 10 2,11 67-64-1 Acetone 2-Pro anone 700 -- 100 3 1 75-05-8 Acetonitrile; Methyl cyanide lAcetonitrile NE 42 55 4 1 98-86-2 Aceto henone lEthanone, 1-ph nI- NE 700 10 5 II 107-02-8 Acrolein 2-Propenal NE 3.51 53 711 107-13-1 jAcrylonitrile 2-Pro enenitrile NE INE 1 200 8 II Page 1 of 5 All units are in (ug/L) unless noted. NE = Not Established CAS numbers that begin with "SW" are not real CAS numbers, instead this represents the Solid Waste Section's ID number * GWP = Groundwater Protection ** SWSL = Solid Waste Section Limit CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App 1 309-00-2 Aldrin 1,4:5,8- Dimethanonaphthalene,1,2,3,4,10,10 - hexachloro-1,4,4a,5,8,8a-hexahydro- (1,4,4a,5,8,8a)- NE NE 0.05 911 107-05-1 All I chloride 1-Propene, 3-chloro- NE NE 10 10 11 319-84-6 al ha-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- 1a,2a,3 ,4a,5',6° - NE 0.006 0.05 2411 120-12-7 Anthracene Anthracene 2100 -- 10 12111 7440-36-0 Antimony Antimony NE 1.4 6 131 7440-38-2 Arsenic Arsenic 50 -- 10 14 1 7440-39-3 Barium Barium 2000 -- 100 15 1 71-43-2 Benzene Benzene 1 -- 1 16 1 56-55-3 Benzo a anthracene; Benzanthracene Benz a anthracene 0.0479 -- 10 17 11 50-32-8 Benzo[a]pyrene Benzo[a]pyrene 0.00479 -- 10 21 11 205-99-2 Benzo b fluoranthene Benz[e]acephenanthrylene 0.0479 -- 10 18,11 191-24-2 Benzo[ghi]perylene Benzo[ghi]perylene 210 -- 10 20 11 207-08-9 Benzo k fluoranthene Benzo k fluoranthene 0.479 -- 10 19 11 100-51-6 Benzyl alcohol Benzenemethanol NE 3500 20 22 11 7440-41-7 Beryllium Beryllium NE 4 1 231 319-85-7 beta-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- 1a,2' ,3a,4' ,5a,6' - NE 0.019 0.05 25 11 SW316 Biological Oxygen Demand BOD NE NE NE 316 108-60-1 Bis(2-chloro-1-methylethyl) ether; 2,2'- Dichlorodiisopropyl ether; DCIP, See footnote 4 Propane, 2,2'-oxybis[1-chloro- NE NE 10 46 11 111-91-1 Bis(2-chloroethoxy)methane Ethane, 1,1'-[methylenebis(oxy)]bis [2- chloro- NE NE 10 4211 111-44-4 Bis(2-chloroethyl)ether; Dichloroethyl ether Ethane, 1,1'-oxybis[2-chloro- NE 0.031 10 43,11 117-81-7 Bis(2-ethylhexyl) phthalate 1,2-Benzenedicarboxylic acid, bis(2- ethylhexyl)ester NE NE 15 111 11 74-97-5 Bromochloromethane; Chlorobromethane Methane, bromochloro- NE 0.6 3 28 1 75-27-4 Bromodich Ioromethane; Dichlorobromomethane Methane, bromodichloro- 0.56 -- 1 29 1 75-25-2 Bromoform; Tribromomethane Methane, tribromo- 4.43 -- 3 30 1 85-68-7 Butyl benzyl phthalate; Benzyl butyl phthalate 1,2-Benzenedicarboxylicacid, butyl phenylmethyl ester 100 -- 10 32111 7440-43-9 Cadmium Cadmium 1.75 -- 1 34 1 75-15-0 Carbon disulfide Carbon disulfide 700 -- 100 35 1 56-23-5 Carbon tetrachloride Methane, tetrachloro- 0.269 -- 1 36 1 SW317 Chemical Oxygen Demand COD NE NE NE 317 57-74-9 Chlordane 4,7-Methano-1 H-indene,1,2,4,5,6,7,8,8- octachloro-2,3,3a,4,7,7a-hexahydro- 0.1 -- 0.5 339 11 108-90-7 Chlorobenzene Benzene, chloro- 50 -- 3 39 1 510-15-6 Chlorobenzilate Benzeneacetic acid, 4-chloro-(4- chloro hen I)--h drox -, ethyl ester NE NE 10 40 11 75-00-3 Chloroethane; Ethyl chloride Ethane, chloro- 2800 -- 10 41 1 67-66-3 Chloroform; Trichloromethane Methane, trichloro- 70 -- 5 44 1 126-99-8 Chloroprene 1,3-Butadiene, 2-chloro- NE NE 20 50 11 7440-47-3 Chromium Chromium 50-- 10 5111 218-01-9 Chrysene Chrysene 4.79 -- 10 52 11 156-59-2 cis-1,2-Dichloroethylene; cis-1,2- Dichloroethene Ethene, 1,2-dichloro-,(Z)- 70 -- 5 78 1 10061-01-5 cis- 1,3-Dichloro ro ene 1-Propene, 1,3-dichloro-, Z - 0.19 -- 1 86 1 7440-48-4 Cobalt Cobalt NE 70 10 531 7440-50-8 Copper Copper 1000 -- 10 54 1 57-12-5 Cyanide Cyanide 70 1-- 10 58 11 319-86-8 delta-BHC Cyclohexane,1,2,3,4,5,6-hexachloro- (la,2a,3a,4' ,5a,6' )- NE 0.019 0.05 26 11 2303-16-4 Diallate Carbamothioic acid,bis(1-methylethyl)-, S- (2,3-dichloro-2-propenyl) ester NE NE 10 63 11 53-70-3 Dibenz a,h anthracene Dibenz a,h anthracene 0.0047 -- 10 64 11 132-64-9 Dibenzofuran Dibenzofuran NE 28 10 6511 Page 2 of 5 All units are in (ug/L) unless noted. NE = Not Established CAS numbers that begin with "SW" are not real CAS numbers, instead this represents the Solid Waste Section's ID number * GWP = Groundwater Protection ** SWSL = Solid Waste Section Limit CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App I Dibromochloromethane; 124-48-1 Chlorodibromomethane Methane, dibromochloro- NE 0.41 3 66 1 75-71-8 Dichlorodifluoromethane; CFC 12 Methane,dichlorodifluoro- 1400 -- 5 74 11 2,7:3,6-Dimethanonaphth[2,3- b]oxirene,3,4,5,6,9,9-hexachloro - 1 a,2,2a,3,6,6a,7,7a-octahydro-, 60-57-1 Dieldrin 1aa,2° ,2aa,3° ,6° ,6aa,7° ,7aa - 0.0022 -- 0.075 88,11 84-66-2 Diethyl phthalate 1,2-Benzenedicarbox licacid, diethyl ester 5000 -- 10 90111 Phosphorodithioic acid,O,O-dimethyl S-[2- 60-51-5 Dimethoate -oxoethyll ester NE NE 20 91111 131-11-3 Dimeth I phthalate 1,2-Benzenedicarbox licacid, dimeth I ester NE NE 10 96 II 84-74-2 Di-n-butyl phthalate 1,2-Benzenedicarbox lic acid, dibut I ester 700 -- 10 33 II 117-84-0 Di-n-oct I phthalate 1,2-Benzenedicarbox licacid, dioct I ester 140 -- 10 168 II Dinoseb; DNBP; 2-sec-Butyl-4,6- 88-85-7 dinitro henol Phenol, 2-(1 -methI ro I -4,6-dinitro- NE 7 1 102 II 122-39-4 Diphenylamine Benzenamine, N-phenyl- NE NE 10 103 II Phosphorodithioic acid, O,O-diethyl S-[2- 298-04-4 Disulfoton (ethylthio)ethyl]ester 0.28 -- 10 104 II 6,9-Methano-2,4,3-benzodiox- athiepin,6,7,8,9,10,10 -hexachloro- 959-98-8 Endosulfan I 1,5,5a,6,9,9a-hexahydro-, 3-oxide, NE NE 0.1 105 II 6,9-Methano-2,4,3- benzodioxathiepin,6,7,8,9,10,10 -hexachloro 1,5,5a,6,9,9a-hexahydro-, 3- 33213-65-9 Endosulfan II oxide, 3a,5aa,6° ,9° ,9aa - 42 -- 1 0.1 106,11 6,9-Methano-2,4,3- benzodioxathiepin,6,7,8,9,10,10 -hexachloro 1031-07-8 Endosulfan sulfate 1,5,5a,6,9,9a-hexahydro-, 3,3-dioxide NE NE 0.1 107 II 2,7:3,6-Di methanonaphth[2, 3-b]oxi rene, 3,4,5,6,9,9-hexachloro-1 a,2,2a,3,6,6a,7,7a- 72-20-8 Endrin octah dro-, 1aa,2° ,2a° ,3a,6a,6a° ,7° ,7aa - 2 -- 0.1 108 II 1,2,4-Methenocyclo-penta[cd]pentalene-5- carboxaldehyde,2,2a,3,3,4,7 - hexach lorodecahyd ro- 7421-93-4 Endrin aldehyde (1a,2` ,2a` ,4` ,4a` ,5` ,6a` ,6b` ,7R*)- 2.1 -- 0.1 109 II 97-63-2 Ethyl methac late 2-Pro enoic acid, 2-meth I-, ethyl ester NE NE 10 112 II 62-50-0 Ethyl methanesulfonate Methanesulfonic acid,ethyl ester NE NE 20 113 II 100-41-4 Eth (benzene Benzene, ethyl- 550 -- 1 110 1 Phosphorothioic acid, 0-[4- [(dimethylamino)sulfonyl]phenyl]-O, 0- 52-85-7 Fam hur dimeth I ester NE NE 20 114 II 206-44-0 Fluoranthene Fluoranthene 280 -- 10 115 11 86-73-7 Fluorene 9H-Fluorene 280 -- 10 116,11 Cyclohexane,1,2,3,4,5,6-hexachloro- 58-89-9gamma-BHC; Lindane la,2a,3',4a,5a,6° - 0.2 -- 0.05 27 11 4,7-Methano-1 H-indene,1,4,5,6,7,8,8- 76-44-8 Heptachlor he tachloro- 3a,4,7,7a-tetrah dro- 0.0078 -- 0.05 117 11 2,5-Methano-2H-indeno[1,2- b]oxirene,2,3,4,5,6,7,7-heptachloro- 1a,1b,5,5a,6,6a, -hexahydro- 1024-57-3 Heptachlor epoxide (1 aa,1 b` ,2a,5a,5a° ,6` ,6aa) 0.0038 -- 0.075 118111 118-74-1 Hexachlorobenzene Benzene, hexachloro- 0.02 -- 10 119 11 87-68-3 Hexachlorobutadiene 1,3-Butadiene,1,1,2,3,4,4-hexachloro- NE 0.44 10 12011 77-47-4 Hexachlorocyclopentadiene 1,3-Cyclopentadiene,1,2,3,4,5,5-hexachloro- NE 50 10 121 II 67-72-1 Hexachloroethane Ethane, hexachloro- NE 2.5 10 122 11 1888-71-7 Hexachloropropene 1-Propene, 1,1,2,3,3,3-hexachloro- NE NE 10 123 II 193-39-5 Indeno 1,2,3-cd rene Indeno 1,2,3-cd rene 0.0479 -- 10 125,11 Page 3 of 5 All units are in (ug/L) unless noted. NE = Not Established CAS numbers that begin with "SW" are not real CAS numbers, instead this represents the Solid Waste Section's ID number * GWP = Groundwater Protection ** SWSL = Solid Waste Section Limit CAS Number Name Other Names 2L Std. GWP* Std. SWSL** SW ID App 1 78-83-1 Isobutyl alcohol 1-Propanol, 2-methyl- NE NE 100 126 II 465-73-6 Isodrin 1,4,5,8-Dimethanonaphthalene,1,2,3,4,1 0,10-hexachloro-1,4,4a,5,8,8a hexahydro- (1 a,4a,4a` ,5` ,8` ,8a` )- NE NE 20 127 II 78-59-1 Iso horone 2-C clohexen-1-one,3,5,5-trimeth I- 36.8 -- 10 128 II 120-58-1 Isosafrole 1,3-Benzodioxole, 5-(1-propenyl)- NE NE 10 129 II 143-50-0 Kepone 1,3,4-Metheno-2H-cyclobuta-[cd]pentalen-2- one, 1,1a,3,3a,4,5,5,5a,5b,6- decachlorooctahydro- NE NE 20 13011 7439-92-1 Lead Lead 15 -- 10 131 1 108-39-4 m-Cresol; 3-Methylphenol Phenol, 3-methyl- 35 -- 10 345 11 541-73-1 m-Dichlorobenzene; 1,3-Dichlorobenzene Benzene, 1,3-dichloro- 170 -- 5 70,11 99-65-0 m-Dinitrobenzene Benzene, 1,3-dinitro- NE NE 20 97 11 7439-97-6 Mercury Mercury 1.05 -- 0.2 132 11 126-98-7 Methacrylonitrile 2-Propenenitrile, 2-methyl- NE NE 100 133 II 91-80-5 Methapyrilene 1,2,Ethanediamine, N,N-dimethyl-N'-2- pyridinyl-N'-( 2-thienylmethyl)- NE NE 100 134 II 72-43-5 Methoxychlor Benzene, 1,1'-(2,2,2,trichloroethylidene)bis [4-methoxy- 35 -- 1 135,11 74-83-9 Methyl bromide; Bromomethane Methane, bromo- NE NE 10 136 1 74-87-3 Methyl chloride; Chloromethane Methane, chloro- 2.6 -- 1 137 1 78-93-3 Methyl ethyl ketone; MEK; 2-Butanone 2-Butanone 4200 -- 100 141 1 74-88-4 Methyl iodide; Iodomethane Methane, iodo- NE NE 10 142 1 80-62-6 Methyl methac late 2-Pro enoic acid, 2-meth I-, methyl ester NE NE 30 143 11 66-27-3 Methyl methanesulfonate Methanesulfonic acid,methyl ester NE NE 10 144 11 298-00-0 Methylparathion; Parathion methyl Phosphorothioic acid,O,O-dimeth 1 NE NE 10 146 II 74-95-3 Methylene bromide; Dibromomethane Methane, dibromo- NE NE 10 139 1 75-09-2 Methylene chloride; Dichloromethane Methane, dichloro- 4.6 -- 1 140 1 99-09-2 m-Nitroaniline; 3-Nitroaniline Benzenamine, 3-nitro- NE NE 50 153 II 91-20-3 Naphthalene Naphthalene 21 -- 10 148 11 7440-02-0 Nickel Nickel 100 -- 50 152,1 SW303 Nitrate as N 10000 -- 10000 303 98-95-3 Nitrobenzene Benzene, nitro- NE NE 10 156 II 55-18-5 N-Nitrosodieth famine Ethanamine, N-ethyl-N-nitroso- NE NE 20 160 11 62-75-9 N-Nitrosodimethylamine Methanamine, N-methyl-N-nitroso- 0.0007 -- 10 161 II 924-16-3 N-Nitrosodi-n-bu famine 1-Butanamine, N-but I-N-nitroso- NE NE 10 162 11 86-30-6 N-Nitrosodiphenylamine Benzenamine, N-nitroso-N-phenyl- NE NE 10 163 II 621-64-7 N-Nitrosodipropylamine; N-Nitroso-N- dipropylamine; Di-n-propylnitrosamine 1-Propanamine, N-nitroso-N-propyl- NE NE 10 164 II 10595-95-6 N-Nitrosometh lethalamine Ethanamine, N-meth I-N-nitroso- NE NE 10 165 11 100-75-4 N-Nitrosopiperidine Piperidine, 1-nitroso- NE NE 20 166 11 930-55-2 N-Nitrosopyrrolidine P rrolidine, 1-nitroso- NE NE 10 167 11 126-68-1 0,0,0-Triethyl phosphorothioate Phosphorothioic acid, O,O,O-triethyl ester NE NE 10 207 II 297-97-2 O,O-Diethyl 0-2-pyrazinyl phosphorothioate; Thionazin Phosphorothioic acid, O,O-diethyl 0- pyrazinyl ester NE NE 20 89 II 95-48-7 o-Cresol; 2-Meth I henol Phenol, 2-methyl- NE 35 10 56,11 95-50-1 o-Dichlorobenzene; 1,2-Dichlorobenzene Benzene, 1,2-dichloro- 24 -- 5 69 1 88-74-4 o-Nitroaniline; 2-Nitroaniline Benzenamine, 2-nitro- NE NE 50 154 11 88-75-5 o-Nitrophenol; 2-Nitrophenol Phenol, 2-nitro- NE NE 10 158 II 95-53-4 o-Toluidine Benzenamine, 2-methyl- NE NE 10 197 11 60-11-7 Dimeth lamino azobenzene Benzenamine, N,N-dimeth I-4-(phen lazo)- NE NE 10 92 11 56-38-2 Parathion Phosphorothioic acid, O,O-diethyl-O-(4- nitro hen I ester NE NE 101 169 11 106-47-8 p-Chloroaniline Benzenamine, 4-chloro- NE NE 20 38 II 59-50-7 p-Chloro-m-cresol; 4-Chloro-3-methylphenol Phenol, 4-chloro-3-methyl- NE NE 20 45 II 106-44-5 -Cresol; 4-Meth I henol Phenol, 4-methyl- 3.5 NE-- 10 344 11 106-46-7 p-Dichlorobenzene; 1,4-Dichlorobenzene Benzene, 1,4-dichloro- 1.4 -- 1 71 1 608-93-5 Pentachlorobenzene Benzene, entachloro- NE NE 10 171,11 82-68-8 Pentachloronitrobenzene Benzene, pentachloronitro- NE NE 20 17211 87-86-5 Pentachloro henol Phenol, entachloro- 0.29 -- 25 173 II 62-44-2 Phenacetin Acetamide, N-(4-ethoxyphenyl) NE NE 20 174111 85-01-8 Phenanthrene Phenanthrene 210 -- 10 175111 Page 4 of 5 All units are in (ug/L) unless noted. NE = Not Established CAS numbers that begin with "SW" are not real CAS * GWP = Groundwater Protection ** SWSL = Solid Waste Section Limit CAS Number Name 108-95-2 Phenol 298-02-2 Phorate SW412 Total Phosphorus Pronamide Selenium Silver Silvex; 2,4,5-TP Styrene Sulfate Sulfide 1,2-Dichloroethylene;trans-1,2- iroethene 1,3-Dichloropropene 1.4-Dichloro-2-butene orofluoromethane; CFC-11 dium acetate chloride: Chloroethene instead this represents the Solid Waste Section's ID number Phenol 300 -- Phosphorodithioic acid, O,O-diethyl S- [(ethylthio)methyl]ester 1.4 -- Total Phosphorus NE NE Benzenamine, 4-nitro- NE NE Phenol, 4-nitro- NE NE 1,1'-Biphenyl,chloro derivatives Method 1016/1242 NE 1,4-Benzenediamine NE NE Benzamide, 3,5-dichloro-N-(1,1-dimethyl-2- propynyl)- NE NE Pro anenitrile NE NE Pyrene 210 -- 1,3-Benzodioxole, 5- 2- ro en I - NE NE Selenium 50-- Silver 17.5 -- Propanoic acid, 2-(2,4,5-trichlorophenoxy)- 50 -- Benzene, ethen I- 100 -- 250000 -- Sulfide NE NE Benzene, 1,3,5-trinitro- NE NE Ethene,tetrachloro- 0.7 -- Thallium NE Tin NE NE Benzene, methyl- 1000 -- Toxaphene 0.031 -- Ethene, 1,2-dichloro-,(E)- 100 1-Propene, 1,3-dichloro-, E - 0.19 -- 2-Butene, 1,4-dichloro-, (E)- NE NE Ethene, trichloro- 2.8 -- Methane,trichlorofluoro- 2100 -- Vanadium NE Acetic acid, ethenylester NE Ethene, chloro- 0.015 -- Benzene, dimethyl- 530 -- Zinc 1050 -- 3.5 10 177 II 10 178 II NE 412 10 176 II 10 179 II 50 180 II 10 181 II 10 182 II 10 18311 0 n�1M 1 87 1 00 731 1 201 1 1 203 I 25 2091 50 210 I 11 21111 51 3461 101 21311 Page 5 of 5 APPENDIX D Environmental Monitoring Reporting Form DEN R USE ONLY ❑Paper Report ❑Electronic Data - Email CD (data loaded: Yes / No Doc/Event #: NC DENR I IEnvironmental Monitoring Division of Waste Management - Solid Waste Reporting Form Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are available for inspection and examination by any person upon request (NC General Statute 132-6). Instructions: Prepare one form for each individually monitored unit. Please type or print legibly. Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing condition, etc.). Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits. Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the facility (NCAC 13B .1629 (4)(a)(i). Send the original signed and sealed form, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste Section, 1646 Mail Service Center, Raleigh, NC 27699-1646. Solid Waste Monitoring Data Submittal Information Name of entity submitting data (laboratory, consultant, facility owner): Contact for questions about data formatting. Include data preparer's name, telephone number and E-mail address: Name: Phone: E-mail: NC Landfill Rule: Actual sampling dates (e.g., Facility name: Facility Address: Facility Permit # (.0500 or .1600) October 20-24, 2006) Environmental Status: (Check all that apply) Initial/Background Monitoring Detection Monitoring Assessment Monitoring Corrective Action of data submitted: (Check all that apply) Groundwater monitoring data from monitoring wells Groundwater monitoring data from private water supply wells El Leachate monitoring data El water monitoring data Methane gas monitoring data Corrective action data (specify) Other(specify) Notification attached? e No. No groundwater or surface water standards were exceeded. Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water monitoring points, dates, analytical values, NC 2L groundwater standard, NC 2B surface water standard or NC Solid Waste GWPS and preliminary analysis of the cause and significance of any concentration. El Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample values and explosive methane gas limits. Certification To the best of my knowledge, the information reported and statements made on this data submittal and attachments are true and correct. Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment. Facility Representative Name (Print) Title (Area Code) Telephone Number Signature Facility Representative Address Date Affix NC Licensed/ Professional Geologist Seal NC PE Firm License Number (if applicable effective May 1, 2009) Revised 6/2009 APPENDIX E Low -Flow Groundwater Purging and Sampling Guidance United States Office of Office of Solid Waste EPA/540/S-95/504 Environmental Protection Research and and Emergency April 1996 Agency Development Response %=,EPA Ground Water Issue LOW -FLOW (MINIMAL DRAWDOWN) GROUND -WATER SAMPLING PROCEDURES by Robert W. Puls' and Michael J. Barcelona' Background The Regional Superfund Ground Water Forum is a group of ground -water scientists, representing EPA's Regional Superfund Offices, organized to exchange information related to ground -water remediation at Superfund sites. One of the major concerns of the Forum is the sampling of ground water to support site assessment and remedial performance monitoring objectives. This paper is intended to provide background information on the development of low -flow sampling procedures and its application under a variety of hydrogeologic settings. It is hoped that the paper will support the production of standard operating procedures for use by EPA Regional personnel and other environmental professionals engaged in ground -water sampling. For further information contact: Robert Puls, 405-436-8543, Subsurface Remediation and Protection Division, NRMRL, Ada, Oklahoma. I. Introduction The methods and objectives of ground -water sampling to assess water quality have evolved over time. Initially the emphasis was on the assessment of water quality of aquifers as sources of drinking water. Large water -bearing units were identified and sampled in keeping with that objective. These were highly productive aquifers that supplied drinking water via private wells or through public water supply systems. Gradually, with the increasing aware- ness of subsurface pollution of these water resources, the understanding of complex hydrogeochemical processes which govern the fate and transport of contaminants in the subsurface increased. This increase in understanding was also due to advances in a number of scientific disciplines and improvements in tools used for site characterization and ground -water sampling. Ground -water quality investigations where pollution was detected initially borrowed ideas, methods, and materials for site characterization from the water supply field and water analysis from public health practices. This included the materials and manner in which monitoring wells were installed and the way in which water was brought to the surface, treated, preserved and analyzed. The prevailing conceptual ideas included convenient generali- zations of ground -water resources in terms of large and relatively homogeneous hydrologic units. With time it became apparent that conventional water supply generalizations of homogeneity did not adequately represent field data regard- ing pollution of these subsurface resources. The important role of heterogeneity became increasingly clear not only in geologic terms, but also in terms of complex physical, 'National Risk Management Research Laboratory, U.S. EPA 'University of Michigan —I- ATlON y Superfund Technology Support Center for s r, Ground Water echnology upport National Risk Management Research Laboratory • roject Subsurface Protection and Remediation Division Robert S. Kerr Environmental Research Center t-a;) 5`yAda, Oklahoma Technology Innovation Office Office of Solid Waste and Emergency Response, US EPA, Washington, DC Walter W. Kovalick, Jr., Ph.D. Director chemical and biological subsurface processes. With greater appreciation of the role of heterogeneity, it became evident that subsurface pollution was ubiquitous and encompassed the unsaturated zone to the deep subsurface and included unconsolidated sediments, fractured rock, and aquitards or low -yielding or impermeable formations. Small-scale pro- cesses and heterogeneities were shown to be important in identifying contaminant distributions and in controlling water and contaminant flow paths. It is beyond the scope of this paper to summarize all the advances in the field of ground -water quality investiga- tions and remediation, but two particular issues have bearing on ground -water sampling today: aquifer heterogeneity and colloidal transport. Aquifer heterogeneities affect contaminant flow paths and include variations in geology, geochemistry, hydrology and microbiology. As methods and the tools available for subsurface investigations have become increas- ingly sophisticated and understanding of the subsurface environment has advanced, there is an awareness that in most cases a primary concern for site investigations is characterization of contaminant flow paths rather than entire aquifers. In fact, in many cases, plume thickness can be less than well screen lengths (e.g., 3-6 m) typically installed at hazardous waste sites to detect and monitor plume movement over time. Small-scale differences have increasingly been shown to be important and there is a general trend toward smaller diameter wells and shorter screens. The hydrogeochemical significance of colloidal -size particles in subsurface systems has been realized during the past several years (Gschwend and Reynolds, 1987; McCarthy and Zachara, 1989; Puls, 1990; Ryan and Gschwend, 1990). This realization resulted from both field and laboratory studies that showed faster contaminant migration over greater distances and at higher concentrations than flow and trans- port model predictions would suggest (Buddemeier and Hunt, 1988; Enfield and Bengtsson, 1988; Penrose et al., 1990). Such models typically account for interaction between the mobile aqueous and immobile solid phases, but do not allow for a mobile, reactive solid phase. It is recognition of this third phase as a possible means of contaminant transport that has brought increasing attention to the manner in which samples are collected and processed for analysis (Puts et al., 1990; McCarthy and Degueldre, 1993; Backhus et al., 1993; U. S. EPA, 1995). If such a phase is present in sufficient mass, possesses high sorption reactivity, large surface area, and remains stable in suspension, it can serve as an important mechanism to facilitate contaminant transport in many types of subsurface systems. Colloids are particles that are sufficiently small so that the surface free energy of the particle dominates the bulk free energy. Typically, in ground water, this includes particles with diameters between 1 and 1000 nm. The most commonly observed mobile particles include: secondary clay minerals; hydrous iron, aluminum, and manganese oxides; dissolved and particulate organic materials, and viruses and bacteria. These reactive particles have been shown to be mobile under a variety of conditions in both field studies and laboratory column experiments, and as such need to be included in monitoring programs where identification of the total mobile contaminant loading (dissolved + naturally suspended particles) at a site is an objective. To that end, sampling methodologies must be used which do not artificially bias naturally suspended particle concentrations. Currently the most common ground -water purging and sampling methodology is to purge a well using bailers or high speed pumps to remove 3 to 5 casing volumes followed by sample collection. This method can cause adverse impacts on sample quality through collection of samples with high levels of turbidity. This results in the inclusion of otherwise immobile artifactual particles which produce an overestima- tion of certain analytes of interest (e.g., metals or hydrophobic organic compounds). Numerous documented problems associated with filtration (Danielsson, 1982; Laxen and Chandler, 1982; Horowitz et al., 1992) make this an undesir- able method of rectifying the turbidity problem, and include the removal of potentially mobile (contaminant -associated) particles during filtration, thus artificially biasing contaminant concentrations low. Sampling -induced turbidity problems can often be mitigated by using low -flow purging and sampling techniques. Current subsurface conceptual models have under- gone considerable refinement due to the recent development and increased use of field screening tools. So-called hydraulic push technologies (e.g., cone penetrometer, Geoprobe®, QED HydroPunch®) enable relatively fast screening site characterization which can then be used to design and install a monitoring well network. Indeed, alternatives to conventional monitoring wells are now being considered for some hydrogeologic settings. The ultimate design of any monitoring system should however be based upon adequate site characterization and be consistent with established monitoring objectives. If the sampling program objectives include accurate assessment of the magnitude and extent of subsurface contamination over time and/or accurate assessment of subsequent remedial performance, then some information regarding plume delineation in three-dimensional space is necessary prior to monitoring well network design and installation. This can be accomplished with a variety of different tools and equipment ranging from hand -operated augers to screening tools mentioned above and large drilling rigs. Detailed information on ground -water flow velocity, direction, and horizontal and vertical variability are essential baseline data requirements. Detailed soil and geologic data are required prior to and during the installation of sampling points. This includes historical as well as detailed soil and geologic logs which accumulate during the site investigation. The use of borehole geophysical techniques is also recom- mended. With this information (together with other site characterization data) and a clear understanding of sampling objectives, then appropriate location, screen length, well diameter, slot size, etc. for the monitoring well network can be decided. This is especially critical for new in situ remedial approaches or natural attenuation assessments at hazardous waste sites. In general, the overall goal of any ground -water sampling program is to collect water samples with no alter- ation in water chemistry; analytical data thus obtained may be used for a variety of specific monitoring programs depending on the regulatory requirements. The sampling methodology described in this paper assumes that the monitoring goal is to sample monitoring wells for the presence of contaminants and it is applicable whether mobile colloids are a concern or not and whether the analytes of concern are metals (and metal- loids) or organic compounds. II. Monitoring Objectives and Design Considerations The following issues are important to consider prior to the design and implementation of any ground -water monitoring program, including those which anticipate using low -flow purging and sampling procedures. A. Data Quality Objectives (DQOs) Monitoring objectives include four main types: detection, assessment, corrective -action evaluation and resource evaluation, along with hybrid variations such as site - assessments for property transfers and water availability investigations. Monitoring objectives may change as contami- nation or water quality problems are discovered. However, there are a number of common components of monitoring programs which should be recognized as important regard- less of initial objectives. These components include: 1) Development of a conceptual model that incorporates elements of the regional geology to the local geologic framework. The conceptual model development also includes initial site characterization efforts to identify hydrostratigraphic units and likely flow -paths using a minimum number of borings and well completions; 2) Cost-effective and well documented collection of high quality data utilizing simple, accurate, and reproduc- ible techniques; and 3) Refinement of the conceptual model based on supplementary data collection and analysis. These fundamental components serve many types of monitor- ing programs and provide a basis for future efforts that evolve in complexity and level of spatial detail as purposes and objectives expand. High quality, reproducible data collection is a common goal regardless of program objectives. High quality data collection implies data of sufficient accuracy, precision, and completeness (i.e., ratio of valid analytical results to the minimum sample number called for by the program design) to meet the program objectives. Accu- racy depends on the correct choice of monitoring tools and procedures to minimize sample and subsurface disturbance from collection to analysis. Precision depends on the repeatability of sampling and analytical protocols. It can be assured or improved by replication of sample analyses including blanks, field/lab standards and reference standards. B. Sample Representativeness An important goal of any monitoring program is collection of data that is truly representative of conditions at the site. The term representativeness applies to chemical and hydrogeologic data collected via wells, borings, piezometers, geophysical and soil gas measurements, lysimeters, and temporary sampling points. It involves a recognition of the statistical variability of individual subsurface physical proper- ties, and contaminant or major ion concentration levels, while explaining extreme values. Subsurface temporal and spatial variability are facts. Good professional practice seeks to maximize representativeness by using proven accurate and reproducible techniques to define limits on the distribution of measurements collected at a site. However, measures of representativeness are dynamic and are controlled by evolving site characterization and monitoring objectives. An evolutionary site characterization model, as shown in Fig- ure 1, provides a systematic approach to the goal of consis- tent data collection. r — --1 Dal my Pmgrarn Ohlarl ivx Erlshliph Dala ❑uallry 1� --1W aVFI'D 5A' plirl!l Urld Evolullonory $Ile Aimlyllca l PI VIouol% Crluras lei iral Karl 1 Apply P rratoca Is 1 4 . RoilnoPratocola 4.. . _y MalooSilo Decmions Figure 1. Evolutionary Site Characterization Model The model emphasizes a recognition of the causes of the variability (e.g., use of inappropriate technology such as using bailers to purge wells; imprecise or operator -dependent methods) and the need to control avoidable errors. 1) Questions of Scale A sampling plan designed to collect representative samples must take into account the potential scale of changes in site conditions through space and time as well as the chemical associations and behavior of the parameters that are targeted for investigation. In subsurface systems, physical (i.e., aquifer) and chemical properties over time or space are not statistically independent. In fact, samples taken in close proximity (i.e., within distances of a few meters) or within short time periods (i.e., more frequently than monthly) are highly auto -correlated. This means that designs employing high -sampling frequency (e.g., monthly) or dense spatial monitoring designs run the risk of redundant data collection and misleading inferences regarding trends in values that aren't statistically valid. In practice, contaminant detection and assessment monitoring programs rarely suffer these over -sampling concerns. In corrective -action evaluation programs, it is also possible that too little data may be collected over space or time. In these cases, false interpreta- tion of the spatial extent of contamination or underestimation of temporal concentration variability may result. 2) Target Parameters Parameter selection in monitoring program design is most often dictated by the regulatory status of the site. However, background water quality constituents, purging indicator parameters, and contaminants, all represent targets for data collection programs. The tools and procedures used in these programs should be equally rigorous and applicable to all categories of data, since all may be needed to deter- mine or support regulatory action. C. Sampling Point Design and Construction Detailed site characterization is central to all decision -making purposes and the basis for this characteriza- tion resides in identification of the geologic framework and major hydro-stratigraphic units. Fundamental data for sample point location include: subsurface lithology, head -differences and background geochemical conditions. Each sampling point has a proper use or uses which should be documented at a level which is appropriate for the program's data quality objectives. Individual sampling points may not always be able to fulfill multiple monitoring objectives (e.g., detection, assessment, corrective action). 1) Compatibility with Monitoring Program and Data Quality Objectives Specifics of sampling point location and design will be dictated by the complexity of subsurface lithology and variability in contaminant and/or geochemical conditions. It should be noted that, regardless of the ground -water sam- pling approach, few sampling points (e.g., wells, drive -points, screened augers) have zones of influence in excess of a few feet. Therefore, the spatial frequency of sampling points should be carefully selected and designed. 2) Flexibility of Sampling Point Design In most cases well -point diameters in excess of 1 7/8 inches will permit the use of most types of submersible pumping devices for low -flow (minimal drawdown) sampling. It is suggested that short (e.g., less than 1.6 m) screens be incorporated into the monitoring design where possible so that comparable results from one device to another might be expected. Short, of course, is relative to the degree of vertical water quality variability expected at a site. 3) Equilibration of Sampling Point Time should be allowed for equilibration of the well or sampling point with the formation after installation. Place- ment of well or sampling points in the subsurface produces some disturbance of ambient conditions. Drilling techniques (e.g., auger, rotary, etc.) are generally considered to cause more disturbance than direct -push technologies. In either case, there may be a period (i.e., days to months) during which water quality near the point may be distinctly different from that in the formation. Proper development of the sam- pling point and adjacent formation to remove fines created during emplacement will shorten this water quality recovery period. III. Definition of Low -Flow Purging and Sampling It is generally accepted that water in the well casing is non -representative of the formation water and needs to be purged prior to collection of ground -water samples. However, the water in the screened interval may indeed be representa- tive of the formation, depending upon well construction and site hydrogeology. Wells are purged to some extent for the following reasons: the presence of the air interface at the top of the water column resulting in an oxygen concentration gradient with depth, loss of volatiles up the water column, leaching from or sorption to the casing or filter pack, chemical changes due to clay seals or backfill, and surface infiltration. Low -flow purging, whether using portable or dedi- cated systems, should be done using pump -intake located in the middle or slightly above the middle of the screened interval. Placement of the pump too close to the bottom of the well will cause increased entrainment of solids which have collected in the well over time. These particles are present as a result of well development, prior purging and sampling events, and natural colloidal transport and deposition. Therefore, placement of the pump in the middle or toward the top of the screened interval is suggested. Placement of the pump at the top of the water column for sampling is only recommended in unconfined aquifers, screened across the water table, where this is the desired sampling point. Low- flow purging has the advantage of minimizing mixing between the overlying stagnant casing water and water within the screened interval. A. Low -Flow Purging and Sampling Low -flow refers to the velocity with which water enters the pump intake and that is imparted to the formation pore water in the immediate vicinity of the well screen. It does not necessarily refer to the flow rate of water discharged at the surface which can be affected by flow regulators or restrictions. Water level drawdown provides the best indica- tion of the stress imparted by a given flow -rate for a given hydrological situation. The objective is to pump in a manner that minimizes stress (drawdown) to the system to the extent practical taking into account established site sampling objectives. Typically, flow rates on the order of 0.1 - 0.5 L/min are used, however this is dependent on site -specific hydrogeology. Some extremely coarse -textured formations have been successfully sampled in this manner at flow rates to 1 L/min. The effectiveness of using low -flow purging is intimately linked with proper screen location, screen length, and well construction and development techniques. The reestablishment of natural flow paths in both the vertical and horizontal directions is important for correct interpretation of the data. For high resolution sampling needs, screens less than 1 m should be used. Most of the need for purging has been found to be due to passing the sampling device through the overlying casing water which causes mixing of these stagnant waters and the dynamic waters within the screened interval. Additionally, there is disturbance to suspended sediment collected in the bottom of the casing and the displacement of water out into the formation immediately adjacent to the well screen. These disturbances and impacts can be avoided using dedicated sampling equipment, which precludes the need to insert the sampling device prior to purging and sampling. Isolation of the screened interval water from the overlying stagnant casing water may be accomplished using low -flow minimal drawdown techniques. If the pump intake is located within the screened interval, most of the water pumped will be drawn in directly from the formation with little mixing of casing water or disturbance to the sampling zone. However, if the wells are not constructed and developed properly, zones other than those intended may be sampled. At some sites where geologic heterogeneities are sufficiently different within the screened interval, higher conductivity zones may be preferentially sampled. This is another reason to use shorter screened intervals, especially where high spatial resolution is a sampling objective. B. Water Quality Indicator Parameters It is recommended that water quality indicator parameters be used to determine purging needs prior to sample collection in each well. Stabilization of parameters such as pH, specific conductance, dissolved oxygen, oxida- tion-reduction potential, temperature and turbidity should be used to determine when formation water is accessed during purging. In general, the order of stabilization is pH, tempera- ture, and specific conductance, followed by oxidation- reduction potential, dissolved oxygen and turbidity. Tempera- ture and pH, while commonly used as purging indicators, are actually quite insensitive in distinguishing between formation water and stagnant casing water; nevertheless, these are important parameters for data interpretation purposes and should also be measured. Performance criteria for determi- nation of stabilization should be based on water -level draw - down, pumping rate and equipment specifications for measur- ing indicator parameters. Instruments are available which utilize in -line flow cells to continuously measure the above parameters. It is important to establish specific well stabilization criteria and then consistently follow the same methods thereafter, particularly with respect to drawdown, flow rate and sampling device. Generally, the time or purge volume required for parameter stabilization is independent of well depth or well volumes. Dependent variables are well diam- eter, sampling device, hydrogeochemistry, pump flow rate, and whether the devices are used in a portable or dedicated manner. If the sampling device is already in place (i.e., dedicated sampling systems), then the time and purge volume needed for stabilization is much shorter. Other advantages of dedicated equipment include less purge water for waste disposal, much less decontamination of equipment, less time spent in preparation of sampling as well as time in the field, and more consistency in the sampling approach which probably will translate into less variability in sampling results. The use of dedicated equipment is strongly recom- mended at wells which will undergo routine sampling over time. If parameter stabilization criteria are too stringent, then minor oscillations in indicator parameters may cause purging operations to become unnecessarily protracted. It should also be noted that turbidity is a very conservative parameter in terms of stabilization. Turbidity is always the last parameter to stabilize. Excessive purge times are invariably related to the establishment of too stringent turbidity stabilization criteria. It should be noted that natural turbidity levels in ground water may exceed 10 nephelometric turbidity units (NTU). C. Advantages and Disadvantages of Low -Flow (Minimum Drawdown) Purging In general, the advantages of low -flow purging include: • samples which are representative of the mobile load of contaminants present (dissolved and colloid-assock ated); • minimal disturbance of the sampling point thereby minimizing sampling artifacts; • less operator variability, greater operator control; • reduced stress on the formation (minimal drawdown); • less mixing of stagnant casing water with formation water; • reduced need for filtration and, therefore, less time required for sampling; • smaller purging volume which decreases waste disposal costs and sampling time; • better sample consistency; reduced artificial sample variability. Some disadvantages of low -flow purging are: • higher initial capital costs, • greater set-up time in the field, • need to transport additional equipment to and from the site, • increased training needs, • resistance to change on the part of sampling practitio- ners, concern that new data will indicate a change in conditions and trigger an action. IV. Low -Flow (Minimal Drawdown) Sampling Protocols The following ground -water sampling procedure has evolved over many years of experience in ground -water sampling for organic and inorganic compound determinations and as such summarizes the authors' (and others) experi- ences to date (Barcelona et al., 1984, 1994; Barcelona and Helfrich, 1986; Puls and Barcelona, 1989; Puls et. al. 1990, 1992; Puls and Powell, 1992; Puls and Paul, 1995). High - quality chemical data collection is essential in ground -water monitoring and site characterization. The primary limitations to the collection of representative ground -water samples include: mixing of the stagnant casing and fresh screen waters during insertion of the sampling device or ground- water level measurement device; disturbance and resuspension of settled solids at the bottom of the well when using high pumping rates or raising and lowering a pump or bailer; introduction of atmospheric gases or degassing from the water during sample handling and transfer, or inappropri- ate use of vacuum sampling device, etc. A. Sampling Recommendations Water samples should not be taken immediately following well development. Sufficient time should be allowed for the ground -water flow regime in the vicinity of the monitor- ing well to stabilize and to approach chemical equilibrium with the well construction materials. This lag time will depend on site conditions and methods of installation but often exceeds one week. Well purging is nearly always necessary to obtain samples of water flowing through the geologic formations in the screened interval. Rather than using a general but arbitrary guideline of purging three casing volumes prior to sampling, it is recommended that an in -line water quality measurement device (e.g., flow -through cell) be used to establish the stabilization time for several parameters (e.g. , pH, specific conductance, redox, dissolved oxygen, turbidity) on a well -specific basis. Data on pumping rate, drawdown, and volume required for parameter stabilization can be used as a guide for conducting subsequent sampling activities. The following are recommendations to be considered before, during and after sampling: • use low -flow rates (<0.5 L/min), during both purging and sampling to maintain minimal drawdown in the well; • maximize tubing wall thickness, minimize tubing length; • place the sampling device intake at the desired sampling point; • minimize disturbances of the stagnant water column above the screened interval during water level measurement and sampling device insertion; • make proper adjustments to stabilize the flow rate as soon as possible; • monitor water quality indicators during purging; • collect unfiltered samples to estimate contaminant loading and transport potential in the subsurface system. B. Equipment Calibration Prior to sampling, all sampling device and monitoring equipment should be calibrated according to manufacturer's recommendations and the site Quality Assurance Project Plan (QAPP) and Field Sampling Plan (FSP). Calibration of pH should be performed with at least two buffers which bracket the expected range. Dissolved oxygen calibration must be corrected for local barometric pressure readings and eleva- tion. C. Water Level Measurement and Monitoring It is recommended that a device be used which will least disturb the water surface in the casing. Well depth should be obtained from the well logs. Measuring to the bottom of the well casing will only cause resuspension of settled solids from the formation and require longer purging times for turbidity equilibration. Measure well depth after sampling is completed. The water level measurement should be taken from a permanent reference point which is surveyed relative to ground elevation. D. Pump Type The use of low -flow (e.g., 0.1-0.5 L/min) pumps is suggested for purging and sampling all types of analytes. All pumps have some limitation and these should be investigated with respect to application at a particular site. Bailers are inappropriate devices for low -flow sampling. 1) General Considerations There are no unusual requirements for ground -water sampling devices when using low -flow, minimal drawdown techniques. The major concern is that the device give consistent results and minimal disturbance of the sample across a range of low flow rates (i.e., < 0.5 L/min). Clearly, pumping rates that cause minimal to no drawdown in one well could easily cause significant drawdown in another well finished in a less transmissive formation. In this sense, the pump should not cause undue pressure or temperature changes or physical disturbance on the water sample over a reasonable sampling range. Consistency in operation is critical to meet accuracy and precision goals. 2) Advantages and Disadvantages of Sampling Devices A variety of sampling devices are available for low - flow (minimal drawdown) purging and sampling and include peristaltic pumps, bladder pumps, electrical submersible pumps, and gas -driven pumps. Devices which lend them- selves to both dedication and consistent operation at defin- able low -flow rates are preferred. It is desirable that the pump be easily adjustable and operate reliably at these lower flow rates. The peristaltic pump is limited to shallow applications and can cause degassing resulting in alteration of pH, alkalinity, and some volatiles loss. Gas -driven pumps should be of a type that does not allow the gas to be in direct contact with the sampled fluid. Clearly, bailers and other grab type samplers are ill - suited for low -flow sampling since they will cause repeated disturbance and mixing of stagnant water in the casing and the dynamic water in the screened interval. Similarly, the use of inertial lift foot -valve type samplers may cause too much disturbance at the point of sampling. Use of these devices also tends to introduce uncontrolled and unacceptable operator variability. Summaries of advantages and disadvantages of various sampling devices are listed in Herzog et al. (1991), U. S. EPA (1992), Parker (1994) and Thurnblad (1994). E. Pump Installation Dedicated sampling devices (left in the well) capable of pumping and sampling are preferred over any other type of device. Any portable sampling device should be slowly and carefully lowered to the middle of the screened interval or slightly above the middle (e.g., 1-1.5 m below the top of a 3 m screen). This is to minimize excessive mixing of the stagnant water in the casing above the screen with the screened interval zone water, and to minimize resuspension of solids which will have collected at the bottom of the well. These two disturbance effects have been shown to directly affect the time required for purging. There also appears to be a direct correlation between size of portable sampling devices relative to the well bore and resulting purge volumes and times. The key is to minimize disturbance of water and solids in the well casing. F. Filtration Decisions to filter samples should be dictated by sampling objectives rather than as a fix for poor sampling practices, and field -filtering of certain constituents should not be the default. Consideration should be given as to what the application of field -filtration is trying to accomplish. For assessment of truly dissolved (as opposed to operationally dissolved [i.e., samples filtered with 0.45 pm filters]) concen- trations of major ions and trace metals, 0.1 pm filters are recommended although 0.45 pm filters are normally used for most regulatory programs. Alkalinity samples must also be filtered if significant particulate calcium carbonate is sus- pected, since this material is likely to impact alkalinity titration results (although filtration itself may alter the CO2 composition of the sample and, therefore, affect the results). Although filtration may be appropriate, filtration of a sample may cause a number of unintended changes to occur (e.g. oxidation, aeration) possibly leading to filtration -induced artifacts during sample analysis and uncertainty in the results. Some of these unintended changes may be unavoidable but the factors leading to them must be recognized. Deleterious effects can be minimized by consistent application of certain filtration guidelines. Guidelines should address selection of filter type, media, pore size, etc. in order to identify and minimize potential sources of uncertainty when filtering samples. In -line filtration is recommended because it provides better consistency through less sample handling, and minimizes sample exposure to the atmosphere. In -line filters are available in both disposable (barrel filters) and non - disposable (in -line filter holder, flat membrane filters) formats and various filter pore sizes (0.1-5.0 pm). Disposable filter cartridges have the advantage of greater sediment handling capacity when compared to traditional membrane filters. Filters must be pre -rinsed following manufacturer's recom- mendations. If there are no recommendations for rinsing, pass through a minimum of 1 L of ground water following purging and prior to sampling. Once filtration has begun, a filter cake may develop as particles larger than the pore size accumulate on the filter membrane. The result is that the effective pore diameter of the membrane is reduced and particles smaller than the stated pore size are excluded from the filtrate. Possible corrective measures include prefiltering (with larger pore size filters), minimizing particle loads to begin with, and reducing sample volume. G. Monitoring of Water Level and Water Quality Indicator Parameters Check water level periodically to monitor drawdown in the well as a guide to flow rate adjustment. The goal is minimal drawdown (<0.1 m) during purging. This goal may be difficult to achieve under some circumstances due to geologic heterogeneities within the screened interval, and may require adjustment based on site -specific conditions and personal experience. In -line water quality indicator parameters should be continuously monitored during purging. The water quality indicator parameters monitored can include pH, redox potential, conductivity, dissolved oxygen (DO) and turbidity. The last three parameters are often most sensitive. Pumping rate, drawdown, and the time or volume required to obtain stabilization of parameter readings can be used as a future guide to purge the well. Measurements should be taken every three to five minutes if the above suggested rates are used. Stabilization is achieved after all parameters have stabilized for three successive readings. In lieu of measuring all five parameters, a minimum subset would include pH, conductivity, and turbidity or DO. Three successive readings should be within ± 0.1 for pH, ± 3% for conductivity, ± 10 my for redox potential, and ± 10% for turbidity and DO. Stabilized purge indicator parameter trends are generally obvious and follow either an exponential or asymptotic change to stable values during purging. Dissolved oxygen and turbidity usually require the longest time for stabilization. The above stabiliza- tion guidelines are provided for rough estimates based on experience. H. Sampling, Sample Containers, Preservation and Decontamination Upon parameter stabilization, sampling can be initiated. If an in -line device is used to monitor water quality parameters, it should be disconnected or bypassed during sample collection. Sampling flow rate may remain at estab- lished purge rate or may be adjusted slightly to minimize aeration, bubble formation, turbulent filling of sample bottles, or loss of volatiles due to extended residence time in tubing. Typically, flow rates less than 0.5 L/min are appropriate. The same device should be used for sampling as was used for purging. Sampling should occur in a progression from least to most contaminated well, if this is known. Generally, volatile (e.g., solvents and fuel constituents) and gas sensitive (e.g., Fe", CH4, H2S/HS-, alkalinity) parameters should be sampled first. The sequence in which samples for most inorganic parameters are collected is immaterial unless filtered (dis- solved) samples are desired. Filtering should be done last and in -line filters should be used as discussed above. During both well purging and sampling, proper protective clothing and equipment must be used based upon the type and level of contaminants present. The appropriate sample container will be prepared in advance of actual sample collection for the analytes of interest and include sample preservative where necessary. Water samples should be collected directly into this container from the pump tubing. Immediately after a sample bottle has been filled, it must be preserved as specified in the site (QAPP). Sample preservation requirements are based on the analyses being performed (use site QAPP, FSP, RCRA guidance document [U. S. EPA, 1992] or EPA SW-846 [U. S. EPA, 1982] ). It may be advisable to add preservatives to sample bottles in a controlled setting prior to entering the field in order to reduce the chances of improperly preserving sample bottles or introducing field contaminants into a sample bottle while adding the preservatives. The preservatives should be transferred from the chemical bottle to the sample container using a disposable polyethylene pipet and the disposable pipet should be used only once and then discarded. After a sample container has been filled with ground water, a Teflon TM (or tin) -lined cap is screwed on tightly to prevent the container from leaking. A sample label is filled out as specified in the FSP. The samples should be stored inverted at 4°C. Specific decontamination protocols for sampling devices are dependent to some extent on the type of device used and the type of contaminants encountered. Refer to the site QAPP and FSP for specific requirements. I. Blanks The following blanks should be collected: (1) field blank: one field blank should be collected from each source water (distilled/deionized water) used for sampling equipment decontamination or for assisting well development procedures. (2) equipment blank: one equipment blank should be taken prior to the commencement of field work, from each set of sampling equipment to be used for that day. Refer to site QAPP or FSP for specific require- ments. (3) trip blank: a trip blank is required to accompany each volatile sample shipment. These blanks are prepared in the laboratory by filling a 40-mL volatile organic analysis (VOA) bottle with distilled/deionized water. V. Low -Permeability Formations and Fractured Rock The overall sampling program goals or sampling objectives will drive how the sampling points are located, installed, and choice of sampling device. Likewise, site - specific hydrogeologic factors will affect these decisions. Sites with very low permeability formations or fractures causing discrete flow channels may require a unique monitor- ing approach. Unlike water supply wells, wells installed for ground -water quality assessment and restoration programs are often installed in low water -yielding settings (e.g., clays, silts). Alternative types of sampling points and sampling methods are often needed in these types of environments, because low -permeability settings may require extremely low - flow purging (<0.1 L/min) and may be technology -limited. Where devices are not readily available to pump at such low flow rates, the primary consideration is to avoid dewatering of the well screen. This may require repeated recovery of the water during purging while leaving the pump in place within the well screen. Use of low -flow techniques may be impractical in these settings, depending upon the water recharge rates. The sampler and the end -user of data collected from such wells need to understand the limitations of the data collected; i.e., a strong potential for underestimation of actual contami- nant concentrations for volatile organics, potential false negatives for filtered metals and potential false positives for unfiltered metals. It is suggested that comparisons be made between samples recovered using low -flow purging tech- niques and samples recovered using passive sampling techniques (i.e., two sets of samples). Passive sample collection would essentially entail acquisition of the sample with no or very little purging using a dedicated sampling system installed within the screened interval or a passive sample collection device. A. Low -Permeability Formations (<O.1 L/min recharge) 1. Low -Flow Purging and Sampling with Pumps "portable or non -dedicated mode" - Lower the pump (one capable of pumping at <0.1 L/min) to mid -screen or slightly above and set in place for minimum of 48 hours (to lessen purge volume requirements). After 48 hours, use procedures listed in Part IV above regard- ing monitoring water quality parameters for stabiliza- tion, etc., but do not dewater the screen. If excessive drawdown and slow recovery is a problem, then alternate approaches such as those listed below may be better. b. "dedicated mode" - Set the pump as above at least a week prior to sampling; that is, operate in a dedicated pump mode. With this approach significant reductions in purge volume should be realized. Water quality parameters should stabilize quite rapidly due to less disturbance of the sampling zone. 2. Passive Sample Collection Passive sampling collection requires insertion of the device into the screened interval for a sufficient time period to allow flow and sample equilibration before extraction for analysis. Conceptually, the extraction of water from low yielding formations seems more akin to the collection of water from the unsaturated zone and passive sampling techniques may be more appropriate in terms of obtaining "representa- tive" samples. Satisfying usual sample volume requirements is typically a problem with this approach and some latitude will be needed on the part of regulatory entities to achieve sampling objectives. B. Fractured Rock In fractured rock formations, a low -flow to zero purging approach using pumps in conjunction with packers to isolate the sampling zone in the borehole is suggested. Passive multi -layer sampling devices may also provide the most "representative" samples. It is imperative in these settings to identify flow paths or water -producing fractures prior to sampling using tools such as borehole flowmeters and/or other geophysical tools. After identification of water -bearing fractures, install packer(s) and pump assembly for sample collection using low -flow sampling in "dedicated mode" or use a passive sampling device which can isolate the identified water -bearing fractures. VI. Documentation The usual practices for documenting the sampling event should be used for low -flow purging and sampling techniques. This should include, at a minimum: information on the conduct of purging operations (flow -rate, drawdown, water -quality parameter values, volumes extracted and times for measurements), field instrument calibration data, water sampling forms and chain of custody forms. See Figures 2 and 3 and "Ground Water Sampling Workshop -- A Workshop Summary" (U. S. EPA, 1995) for example forms and other documentation suggestions and information. This information coupled with laboratory analytical data and validation data are needed to judge the "useability" of the sampling data. VII. Notice The U.S. Environmental Protection Agency through its Office of Research and Development funded and managed the research described herein as part of its in-house research program and under Contract No. 68-C4-0031 to Dynamac Corporation. It has been subjected to the Agency's peer and administrative review and has been approved for publication as an EPA document. Mention of trade names or commercial products does not constitute endorsement or recommenda- tion for use. VIII. References Backhus, D,A., J.N. Ryan, D.M. Groher, J.K. McFarlane, and P.M. Gschwend. 1993. Sampling Colloids and Colloid - Associated Contaminants in Ground Water. Ground Water, 31(3):466-479. Barcelona, M.J., J.A. Helfrich, E.E. Garske, and J.P. Gibb. 1984. A laboratory evaluation of groundwater sampling mechanisms. Ground Water Monitoring Review, 4(2):32-41. Barcelona, M.J. and J.A. Helfrich. 1986. Well construction and purging effects on ground -water samples. Environ. Sci. Technol., 20(11):1179-1184. Barcelona, M.J., H.A. Wehrmann, and M.D. Varljen. 1994. Reproducible well purging procedures and VOC stabilization criteria for ground -water sampling. Ground Water, 32(1):12- 22. Buddemeier, R.W. and J.R. Hunt. 1988. Transport of Colloidal Contaminants in Ground Water: Radionuclide Migration at the Nevada Test Site. Applied Geochemistry, 3: 535-548. Danielsson, L.G. 1982. On the Use of Filters for Distinguish- ing Between Dissolved and Particulate Fractions in Natural Waters. Water Research, 16:179. Enfield, C.G. and G. Bengtsson. 1988. Macromolecular Transport of Hydrophobic Contaminants in Aqueous Environ- ments. Ground Water, 26(1): 64-70. Gschwend, P.M. and M.D. Reynolds. 1987. Monodisperse Ferrous Phosphate Colloids in an Anoxic Groundwater Plume, J. of Contaminant Hydrol., 1: 309-327. Herzog, B., J. Pennino, and G. Nielsen. 1991. Ground -Water Sampling. In Practical Handbook of Ground -Water Moni- toring (D.M. Nielsen, ed.). Lewis Publ., Chelsea, MI, pp. 449- 499. Horowitz, A.J., K.A. Elrick, and M.R. Colberg. 1992. The effect of membrane filtration artifacts on dissolved trace element concentrations. Water Res., 26(6):753-763. Laxen, D.P.H. and I.M. Chandler. 1982. Comparison of Filtration Techniques for Size Distribution in Freshwaters Analytical Chemistry, 54(8):1350. McCarthy, J.F. and J.M. Zachara. 1989. Subsurface Transport of Contaminants, Environ. Sci. Technol., 5(23):496-502. McCarthy, J.F. and C. Degueldre. 1993. Sampling and Characterization of Colloids and Ground Water for Studying Their Role in Contaminant Transport. In: Environmental Particles (J. Buffle and H.P. van Leeuwen, eds.), Lewis Publ., Chelsea, MI, pp. 247-315. Parker, L.V. 1994. The Effects of Ground Water Sampling Devices on Water Quality: A Literature Review. Ground Water Monitoring and Remediation, 14(2):130-141. Penrose, W.R., W.L. Polzer, E.H. Essington, D.M. Nelson, and K.A. Orlandini. 1990. Mobility of Plutonium and Ameri- cium through a Shallow Aquifer in a Semiarid Region, Environ. Sci. Technol., 24:228-234. Puls, R.W. and M.J. Barcelona. 1989. Filtration of Ground Water Samples for Metals Analyses. Hazardous Waste and Hazardous Materials, 6(4):385-393. Puls, R.W., J.H. Eychaner, and R.M. Powell. 1990. Colloidal - Facilitated Transport of Inorganic Contaminants in Ground Water: Part I. Sampling Considerations. EPA/600/M-90/023, NTIS PB 91-168419. Puls, R.W. 1990. Colloidal Considerations in Groundwater Sampling and Contaminant Transport Predictions. Nuclear Safety, 31(1):58-65. Puls, R.W. and R.M. Powell. 1992. Acquisition of Representa- tive Ground Water Quality Samples for Metals. Ground Water Monitoring Review, 12(3):167-176. Puls, R.W., D.A. Clark, B.Bledsoe, R.M. Powell, and C.J. Paul. 1992. Metals in Ground Water: Sampling Artifacts and Reproducibility. Hazardous Waste and Hazardous Materials, 9(2): 149-162. Puls, R.W. and C.J. Paul. 1995. Low -Flow Purging and Sampling of Ground -Water Monitoring Wells with Dedicated Systems. Ground Water Monitoring and Remediation, 15(1):116-123. Ryan, J.N. and P.M. Gschwend. 1990. Colloid Mobilization in Two Atlantic Coastal Plain Aquifers. Water Resour. Res., 26: 307-322. Thurnblad, T. 1994. Ground Water Sampling Guidance: Development of Sampling Plans, Sampling Protocols, and Sampling Reports. Minnesota Pollution Control Agency. U. S. EPA. 1992. RCRA Ground -Water Monitoring: Draft Technical Guidance. Office of Solid Waste, Washington, DC EPA/530/R-93/001, NTIS PB 93-139350. U. S. EPA. 1995. Ground Water Sampling Workshop -- A Workshop Summary, Dallas, TX, November 30 - December 2, 1993. EPA/600/R-94/205, NTIS PB 95-193249, 126 pp. U. S. EPA. 1982. Test Methods for Evaluating Solid Waste, Physical/Chemical Methods, EPA SW-846. Office of Solid Waste and Emergency Response, Washington, D.C. 10 Figure 2. Ground Water Sampling Log Project Well Depth Sampling Device Measuring Point Sampling Personnel Type of Samples Collected Site Screen Length Tubing type Well No. Otherinfor Well Diameter Information: 2 in = 617 ml/ft, 4 in = 2470 ml/ft: Vol,y, = rrrzh, Volsphe e = 4/3rr r3 Date Casing Type Water Level Is Figure 3. Ground Water Sampling Log (with automatic data logging for most water quality parameters) Project Well Depth Sampling Device Measuring Point Sampling Personnel Type of Samples Collected Site Screen Length Tubing type Well No. Otherinfor Well Diameter Information: 2 in = 617 ml/ft, 4 in = 2470 ml/ft: Vol,Y, = rrrzh, Volsphe e = 4/3rr r3 Date Casing Type Water Level 12