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HomeMy WebLinkAboutDecember 2018_Indoor Air Assessment February 28, 2019 Anchor QEA of North Carolina, PLLC 231 Haywood Street Asheville, North Carolina 28801 828.281.3350 \\Asheville1\Asheville\Projects\Jedhy LLC\Ticar Chemical Phase II ESA\Reports\Indoor Air - 2018-12\2018 Indoor Air Assessment - Former Ticar Chemical Co.docx Mr. David Ramey Inactive Hazardous Sites Branch North Carolina Department of Environmental Quality Mooresville Regional Office 610 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 Ms. Joselyn Harriger Brownfields Program North Carolina Department of Environmental Quality Mooresville Regional Office 610 East Center Avenue, Suite 301 Mooresville, North Carolina 28115 Re: 2018 Indoor Air Assessment Former Ticar Chemical Co. 32 Old Brevard Road Asheville, North Carolina Mr. David Ramey and Ms. Joselyn Harriger, Anchor QEA of North Carolina, PLLC (Anchor QEA), on behalf of Ticar Chemical Company and at the request of the North Carolina Department of Environmental Quality (DEQ) Brownfields Program, prepared this indoor air assessment letter report for the above-referenced property (Site). A Site map is attached as Figure 1. This report documents the results of indoor air samples collected in December 2018. Project Background In April 2016, Altamont Environmental, Inc. (Altamont), which became Anchor QEA on December 29, 2016, performed sub-slab soil gas sampling in the Site building. The results of sub-slab soil-gas sampling activities indicated that there may be a risk of vapor intrusion occurring in the Site building. Based on these results, an indoor air assessment and chemical inventory were performed in June and July 2016. The results of the June 2016 sampling event indicated elevated concentrations of trichloroethene (TCE) in indoor air. As a result, Altamont implemented temporary mitigation measures, including modifying the existing heating ventilation and air conditioning (HVAC) units and installing industrial fans to provide fresh air and a positive pressure atmosphere in the building. February 28, 2019 Page 2 Following implementation of mitigation measures, two rounds of indoor air sampling were performed on July 25 and July 29, 2016. The results of these sampling events indicated that mitigation measures were successful at reducing or eliminating indoor air concentration of TCE. Interim mitigation measures were operated from approximately July 20 to October 3, 2016. Although the interim mitigation efforts were successful, a pre-mitigation comparison of sub-slab soil-gas results to indoor air results had indicated a disparity between the sub-slab concentrations of TCE and tetrachloroethene (PCE). As a result, the attenuation factors of similar contaminants were further evaluated, and the chemical inventory was revisited. For one of the products stored on Site (ProMaster Spot Lite), neither a material safety data sheet/safety data sheet (SDS) nor a label disclosing the formula were available; however, through additional assessment, Altamont determined that this product is composed of approximately 40% TCE. In order to evaluate whether the ProMaster Spot Lite product was a primary or contributing source of the TCE previously detected in indoor air, Altamont performed an additional indoor air assessment on October 6, 2016. The assessment followed the removal of chemicals, carpet samples, and sections of carpet stored on Site and the termination of interim mitigation measures. The results of the October 6, 2016 sampling indicated that the ProMaster Spot Lite product had been the primary source of TCE detected in indoor air during the June 2016 sampling event. The results of the October 6, 2016 assessment are detailed in an Indoor Air Assessment and Interim Mitigation letter report dated October 24, 2016. Altamont performed a third round of confirmation sampling on November 1, 2016. During this sampling event, no concentrations of constituents exceeded the DEQ’s one-in-one million increased lifetime target risk (1x10-6) Non-Residential, Indoor Air Screening Levels (IASLs)1. Following this sampling event, on November 14, 2016, an email was sent from Ms. Carol Jones Van Buren (the property owner’s attorney) to Jocelyn Harriger and Bruce Nicholson of the DEQ Brownfields program regarding the sampling event’s results. Following receipt of Ms. Van Buren’s email, the Brownfields Program granted re-occupancy of the building without mitigation measures. Anchor QEA performed the fourth round of confirmation sampling on July 6, 2017. During this sampling event, TCE was not detected above the 1x10-6 Non-Residential IASL. Only one sample, IA-14, contained a concentration of TCE above the laboratory reporting limit, but below the 1x10-6 Non-Residential IASL of 2.75 micrograms per cubic meter (µg/m³). Only one chemical was detected at a concentration in excess of the 1x10-6 Non-Residential IASL. Chloroform collected in sample IA-13, in the eastern portion of the warehouse, was detected at a concentration of 0.65 µg/m³, which 1 North Carolina Department of Environmental Quality, 2018. Non-Residential Vapor Intrusion Screening Levels. February 2018. Available at: https://files.nc.gov/ncdeq/Waste%20Management/DWM/SF/RiskBasedRemediation/Feb2018_NonRes_VISLs.pdf February 28, 2019 Page 3 is compared to the 1x10-6 Non-Residential IASL for chloroform of 0.533 µg/m³. Chloroform is a common laboratory contaminant and is likely not associated with vapor intrusion. Building Details During the December 2018 assessment, Delong Equipment Company was occupying the building. According to Buncombe County Tax Department GIS, the building footprint is 21,905 square feet. The building’s ceiling height ranges from approximately 16 feet at the north and south walls to 22 feet at the apex of the roof. The building’s roof is improved by four roof vents along the centerline. The warehouse spaces are separated by a non-structural wall with access provided by two doors from the eastern and western portions. One bay door is located in the western warehouse space, and five bay doors are located in the eastern warehouse space. One of the bay doors in the eastern warehouse space is partially boarded up. The western warehouse space has a drop ceiling approximately 12 feet in height. The office space has an 8-foot-tall drop ceiling. A mezzanine space is located above the office and includes a conference room and storage. The occupied office space is climate-controlled with a dedicated HVAC unit. The remaining office space has a separate HVAC unit. There are three HVAC units connected to the western warehouse space. Three roof-mounted HVAC units were observed in the eastern warehouse space. During the December 2018 sampling event, all roof vents and bay doors in the building were closed and HVAC in all spaces was operational. Employees of Delong Equipment Company were packing, sorting, and storing turbo charger components. 2018 Assessment Activities Assessment activities included indoor air sampling and a chemical inventory, as described in the following sub-sections. Chemical Inventory On December 13, 2018, Anchor QEA mobilized to the Site to meet with Ricky Anderson (the current tenant) to conduct a chemical inventory. The purpose of this inventory was to identify products within the building that could potentially emit chemicals into the indoor air. During the Site visit, Anchor QEA recognized and identified three products within the Site’s building: • Rubbing alcohol (isopropyl alcohol or isopropynol) • Lubricant oil (Castrol Techniclean 3602) • Rust inhibitor (Madison Chemical Compound RP-26) Containers of paint and household cleaning products were also observed on Site. Container labels were reviewed, and SDSs were located and reviewed for the products observed. February 28, 2019 Page 4 Review of the SDSs of these products indicated the following chemicals in each product: • Castrol Techniclean 3602 – Contains between 10% and 25% triethanolamine • Madison Chemical Compound RP-26 – Contains between 70% and 80% hydrotreated light petroleum distillates Indoor Air Assessment To evaluate indoor air quality, Anchor QEA collected three indoor air samples and one ambient air sample using summa cannisters. Indoor and ambient air samples were collected using 6-liter summa canisters with 8-hour minimum collection valves. Summa canister samples were collected on December 13, 2018. Each sample was collected using a stainless-steel sampling port elevated at a representative “breathing zone” height, in this case approximately 4 feet above the building floor (grade). The indoor air samples were submitted for analysis using U.S. Environmental Protection Agency Method TO-15 for volatile organic compound constituents. The summa canister sample locations were selected to provide an ambient air sample and coverage of the three main spaces in the building: • IA-13: the eastern portion of the warehouse • IA-14: the western portion of the warehouse • IA-15: the office space (which adjoins the western warehouse space) • A-4: outside of the building, near the door that enters the western portion of the warehouse Sample locations are shown in Figure 2 and the analytical laboratory results are summarized in Table 1. Indoor Air Results TCE was not detected above laboratory reporting limits in the indoor air samples collected on December 13, 2018. Samples IA-13, IA-14, and IA-15 contained concentrations of PCE above the laboratory reporting limit, but below the 1x10-6 Non-Residential IASL of 35 µg/m³. Two chemicals, isopropanol and benzene, were detected at concentrations greater than the 1x10-6 Non-Residential IASLs, which are 180 µg/m³ for isopropanol and 1.6 µg/m³ for benzene. Isopropanol was detected at a concentration of 680 µg/m³ and 190 µg/m³ in sample IA-13 (eastern portion of the warehouse) and IA-14 (western portion of the building), respectively. Benzene was detected at a concentration of 1.8 µg/m³ in sample IA-14. Isopropanol is stored within the warehouse, so is likely not associated with vapor intrusion. Benzene was not previously detected in indoor air or sub-slab soil gas samples. Therefore, the detected concentration of benzene in sample IA-14 is also likely not associated with vapor intrusion. February 28, 2019 Page 5 For a summary of analytical results, see Table 1. For the complete list of analytical results, see the attached laboratory analytical report. The analytical results from the four previous sampling events in 2017 and 2016 are included on Tables 2 and 3, respectively. Conclusions and Recommendations Historical results indicate that there is likely no unacceptable vapor intrusion risk at the Site. Although benzene and isopropanol were detected at concentrations above the 1x10-6 Non- Residential IASLs in the December 2018 samples, the constituents are most likely not attributable to vapor intrusion. Benzene is likely associated with a constituent or impurity present in chemical products used by the current building occupant including, potentially, cigarettes smoked by employees of the building occupant. Additionally, although isopropanol was detected in indoor air above the 1x10-6 Non-Residential IASL during the July 25, 2016 sampling event, this detected concentration was attributed to a building occupant cleaning a desk surface with rubbing alcohol (isopropanol) during the sampling event. Further, isopropanol has not been detected in soil gas at the Site, other than trace detections, likely associated with laboratory contamination. Because benzene and isopropanol are associated with occupational usage or other occupant sources and not vapor intrusion from impacted media, these concentrations most likely should be compared to limits enforced by the Occupational Safety and Health Administration (OSHA), not the DEQ. Based on the 2018 analytical data, Anchor QEA recommends that indoor air sampling be continued annually for the next 2 years to demonstrate that indoor air concentrations of constituents of concern (particularly TCE and PCE) remain stable and below the 1x10-6 Non-Residential IASL criteria. After two additional annual monitoring events with results similar to this event (which will result in 5 years of indoor air monitoring at the Site), Anchor QEA recommends that indoor air monitoring be discontinued at the Site. February 28, 2019 Page 6 If you have any questions or concerns, please feel free to contact me. Sincerely, Christopher F. Gilbert, PE Principal Engineer cc: Carol Jones Van Buren—Van Buren Law, PLLC Billy Clarke—Roberts & Stevens, P.A. Attachments Table 1 2018 Indoor Air Analytical Results Table 2 2017 Indoor Air Analytical Results Table 3 2016 Indoor Air Analytical Results Figure 1 Site Location Map Figure 2 Sample Location Map Attachment 1 Laboratory Analytical Results Tables Table 1 2018 Indoor Air Analytical Results Sample ID:IA-13 IA-14 IA-15 A-4 Sample Height Above Grade:4 feet 4 feet 4 feet 4 feet Date Collected:12/13/2018 12/13/2018 12/13/2018 12/13/2018 IASL µg/m3 µg/m3 µg/m3 µg/m3 4,400 0.096 J <0.41 <0.20 <0.41 4,400 0.45 J <0.93 <0.46 <0.93 53 1.6 <0.63 1.4 <0.63 53 0.47 <0.62 0.46 J <0.62 4,400 0.84 J <0.92 2.1 J 3.8 J NL 0.42 <0.20 1.1 <0.20 2,600 <0.069 <0.39 <0.20 <0.39 27,000 <1.2 16 J 18 12 J 1.6 1.4 1.8 1.6 <0.26 610 <0.075 <0.43 <0.21 <0.43 2.0 0.32 <0.41 <0.21 <0.41 0.53 <0.064 <0.36 <0.18 <0.36 79 1.0 <0.28 <0.14 <0.28 5,300 1.2 2.5 <0.24 <0.49 88 0.86 3.5 L-05 3.2 L-05 3.7 L-05 NL 26 34 190 26 61 <0.094 <0.54 <0.27 26 4.9 0.68 0.68 J 0.63 <0.50 350 1.2 2.4 1.2 <0.48 610 2.4 J <1.2 <0.62 <1.2 180 1,700 480 58 17 J 530 0.37 J <0.84 0.98 J 2.9 J 88 2.60 2.60 1.9 3.1 88 0.98 1.10 <0.27 1.3 880 <0.092 <0.53 <0.26 2.5 1.8 <0.076 <0.43 <0.22 <0.43 35 7.6 11.0 5.2 <0.75 4,400 3.9 4.4 3.5 22 NL <0.056 <0.32 <0.16 <0.32 NL 1.2 1.8 J 2.2 J 1.6 J 2.8 <0.057 <0.32 <0.16 <0.32 Bold indicates a constituent was detected above the laboratory reporting limit. Blue shading indicates a constituent was detected at a concentration in excess of the respective IASL. <0.20: indicates a constituent was not detected above the laboratory reporting limit NL: indicates that there is no IASL guidance value listed in the March 2016 table. VOCs: volatile organic compounds by U.S. Environmental Protection Agency (EPA) Method TO-15 IASL: Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Non-Residential Indoor Air Screening Level (IASL A), updated February 2018.J: indicates a constituent was detected at a level greater than the method detection limit but below the laboratory reporting limit, and is therefore considered an estimate.L-05: indicates that the laboratory fortified blank/laboratory control sample recovery is outside of control limits. The reported value is likely to be biased on the high side. VOCs 1,1,1-Trichloroethane 1,1,2-Trichloro-1,2,2-trifluoroethane 1,2,4-Trimethylbenzene 1,3,5-Trimethylbenzene 2-Butanone (MEK) 4-Ethyltoluene 4-Methyl-2-pentanone (MIBK) Acetone Benzene Carbon disulfide Carbon tetrachloride Chloroform Chloromethane Cyclohexane Dichlorodifluouomethane Ethanol Ethyl acetate Ethylbenzene Heptane Hexane Isopropanol Methylene Chloride m-Xylene & p-Xylene o-Xylene Styrene Trichloroethene (TCE) Tetrachloroethene (PCE) Toluene µg/m³: micrograms per cubic meter trans-1,2-Dichloroethene Trichlorofluoromethane Vinyl Chloride Notes: 2018 Indoor Air Assessment ReportFormer Ticar Chemical Company Page 1 of 1January 2019 Table 2 2017 Indoor Air Analytical Results Sample ID:IA-13 IA-14 IA-15 A-4 Sample Height Above Grade:4 feet 4 feet 4 feet 4 feet Date Collected:7/6/2017 7/6/2017 7/6/2017 7/6/2017 IASL µg/m3 µg/m3 µg/m3 µg/m3 4,380 <0.19 1.9 <0.19 <0.19 26,300 0.49 J 0.26 J 0.42 J 0.40 J 7.67 <0.14 2.5 <0.14 <0.14 175 <0.14 1.2 <0.14 <0.14 2,630 0.52 <0.14 0.48 0.32 613 0.17 J 0.13 J 0.14 J 0.10 J 0.533 0.65 0.15 J 0.47 <0.17 NL <0.14 <0.14 <0.14 <0.14 4.91 0.49 <0.15 0.32 0.47 613 8.5 0.40 J 3.3 J 0.84 J 175 5.0 2.6 J 4.1 7.4 526 0.56 J 0.29 J 0.20 J 0.30 J 87.6 1.4 <0.30 0.96 1.6 87.6 0.76 <0.15 0.46 0.52 35 2.6 <0.24 4.1 <0.24 4,380 7.2 <0.13 4.3 42 NL <0.14 <0.14 0.12 J <0.14 2.75 <0.19 0.21 <0.19 <0.19 NL 1.1 0.89 1.0 1.1 3.79 <0.090 <0.090 <0.090 <0.090 Bold indicates a constituent was detected above the laboratory reporting limit. Blue shading indicates a constituent was detected at a concentration in excess of the respective IASL. <0.19: indicates a constituent was not detected above the laboratory reporting limit 0.49 J: indicates a constituent was detected at a level greater than the method detection limit but below the laboratory reporting limit, and is therefore considered an estimate. IASL: Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Non-Residential Indoor Air Screening Level (IASL A), updated March 2016. NL: indicates that there is no IASL guidance value listed in the March 2016 table. VOCs: volatile organic compounds by U.S. Environmental Protection Agency (EPA) Method TO-15 VOCs 1,1,1-Trichloroethane 1,1,2-Trichloro-1,2,2-trifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene 4-Methyl-2-pentanone (MIBK) Carbon disulfide Chloroform cis-1,2-Dichloroethene Ethylbenzene Hexane Isopropyl alcohol Methylene Chloride m-Xylene & p-Xylene µg/m³: micrograms per cubic meter Trichlorofluoromethane Vinyl Chloride Notes: o-Xylene Tetrachloroethene (PCE) Toluene trans-1,2-Dichloroethene Trichloroethene (TCE) 2018 Indoor Air Assessment ReportFormer Ticar Chemical Company Page 1 of 1January 2019 Table 3 2016 Indoor Air Analytical Results Sample ID:IA-7 IA-7 IA-8 IA-8 IA-9 IA-9 IA-10 IA-10 IA-11 IA-11 IA-12 IA-12 IA-13 IA-14 IA-15 A-4 Date Collected:10/6/2016 11/1/2016 10/6/2016 11/1/2016 10/6/2016 11/1/2016 10/6/2016 11/1/2016 10/6/2016 11/1/2016 10/6/2016 11/1/2016 7/6/2017 7/6/2017 7/6/2017 7/6/2017 IASL 4,380 0.05 L-03 J 0.073 J 0.057 L-03 J 0.12 J 0.061 L-03 J 0.088 J 0.057 L-03 J 0.14 J 0.073 L-03 J 0.21 0.077 L-03 J 0.13 J <0.19 1.9 <0.19 <0.19 26,300 0.45 J 0.56 J 0.64 J 0.56 J 0.64 J 0.58 J 0.52 J 0.58 J 0.72 J 0.73 J 0.40 J 0.77 J 0.49 J 0.26 J 0.42 J 0.40 J 7.67 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 2.5 <0.14 <0.14 175 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 1.2 <0.14 <0.14 2,630 <0.14 <0.14 <0.14 0.14 J 0.069 J 0.50 0.10 J 0.17 0.12 J <0.14 1.1 0.19 0.52 <0.14 0.48 0.32 613 <1.1 <1.1 <1.1 <1.1 <1.1 0.16 J <1.1 0.070 J <1.1 <1.1 0.17 J <1.1 0.17 J 0.13 J 0.14 J 0.10 J 0.533 0.089 J 0.082 J 0.18 0.12 J 0.20 0.16 J 0.22 0.23 0.29 0.29 0.29 0.29 0.65 0.15 J 0.47 <0.17 NL <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 4.91 0.12 J 0.11 J 0.20 0.15 J 0.22 0.48 0.28 0.22 0.36 0.27 34 0.27 0.49 <0.15 0.32 0.47 613 0.54 J 0.51 J 0.47 J 0.47 J 0.69 J 5.1 0.61 J 1.3 J 0.49 J 0.45 J 8.2 0.55 J 8.5 0.40 J 3.3 J 0.84 J 175 1.2 J 1.4 J 0.95 J 1.9 J 2.0 J 4.7 1.2 J 2.8 J 1.6 J 2.8 J 3.0 J 2.2 J 5.0 2.6 J 4.1 7.4 526 0.41 J 0.42 J 0.41 J 0.43 J 0.95 J 14 0.54 J 2.6 0.45 J 0.54 J 0.45 J 0.49 J 0.56 J 0.29 J 0.20 J 0.30 J 87.6 0.44 0.28 J 0.67 0.48 0.77 1.4 0.99 0.82 1.3 1.0 120 1.0 1.4 <0.30 0.96 1.6 87.6 0.17 0.16 0.41 0.38 0.48 0.75 0.49 0.51 0.53 0.60 90 0.59 0.76 <0.15 0.46 0.52 35 3.0 4.3 1.6 3.3 1.6 2.6 1.1 2.5 1.1 4.1 1.5 3.2 2.6 <0.24 4.1 <0.24 4,380 1.5 0.82 1.3 0.95 1.3 14 1.4 0.99 1.4 1.4 5.6 1.1 7.2 <0.13 4.3 42 NL <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 <0.14 0.12 J <0.14 1.75 0.064 J <0.19 <0.19 <0.19 <0.19 0.10 J <0.19 <0.19 0.060 J <0.19 0.48 <0.19 <0.19 0.21 <0.19 <0.19 Trichlorofluoromethane NL 1.1 0.99 1.1 1.2 1.4 1.3 1.0 1.2 1.1 1.8 1.1 1.3 1.1 0.89 1.0 1.1 2.79 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 <0.090 Notes: Bold indicates a constituent was detected above the laboratory reporting limit. Blue shading indicates a constituent was detected at a concentration in excess of the respective IASL. Sample height is 4 feet above grade. µg/m³: All results are in micrograms per cubic meter <0.19: indicates a constituent was not detected above the laboratory reporting limit 0.17 J: indicates a constituent was detected at a level greater than the method detection limit but below the laboratory reporting limit, and is therefore considered an estimate. ft: feet IASL: North Carolina Department of Environmental Quality (DEQ) Division of Waste Management (DWM) Non-Residential Indoor Air Screening Level (IASL A), updated March 2016. L-03: flag indicates the laboratory control sample recovery is outside of the control limits; therefore, the reported value for this compound is likely to be on the low side. NL: indicates that there is no IASL guidance value listed in the March 2016 table. VOCs: volatile organic compounds by U.S. Environmental Protection Agency (EPA) Method TO-15. VOCs cis-1,2-Dichloroethene µg/m³ Trichloroethene (TCE) Vinyl Chloride Tetrachloroethene (PCE) 4-Methyl-2-pentanone (MIBK) Carbon disulfide Chloroform Ethylbenzene Hexane trans-1,2-Dichloroethene Toluene 1,1,1-Trichloroethane 1,1,2-Trichloro-1,2,2-trifluoroethane 1,1-Dichloroethane 1,1-Dichloroethene Isopropyl alcohol Methylene Chloride m-Xylene & p-Xylene o-Xylene 2018 Indoor Air Assessment ReportFormer Ticar Chemical Company Page 1 of 1January 2019 Figures Site [0 2,000 Feet DATA SOURCE:USGS Topographic Map - National GeographicSociety 2013 NOTE:Subject Site property boundary isapproximate. LEGEND: Property Boundary Publish Date: 2019/01/30, 4:12 PM | User: alesueurFilepath: \\Asheville1\Asheville\Projects\Jedhy LLC\Ticar Chemical Phase II ESA\Reports\Indoor Air - 2018-12\Figures\Figure 1 - Site Location Map.mxd Figure 1Site Location Map2018 Indoor Air Assessment ReportFormer Ticar Chemical Company X X GF GF GF GF GF GF GF GFGF GF GF GF GF GFGF X XX                  [0 20 Feet DATA SOURCES:Site Boundary - Buncombe County GIS 2015Aerial Imagery - NC OneMap 2015 NOTE:Sample locations and Site features are approximate. LEGEND: X Sub-Slab Sample Location GF Indoor Air Sample Location X Ambient Air Sample Locations Interior Walls Building Footprint Publish Date: 2017/07/24, 2:24 PM | User: ecruteFilepath: P:\Jedhy LLC\Ticar Chemical Phase II ESA\Reports\Indoor Air - 2017-07\Figures\Figure 2 - Sample Location Map.mxd Figure 2Sample Location Map2018 Indoor Air Assessment ReportFormer Ticar Chemical Company Attachment 1 Laboratory Analytical Results Page 1 of 33 Page 2 of 33 Page 3 of 33 Page 4 of 33 Page 5 of 33 Page 6 of 33 Page 7 of 33 Page 8 of 33 Page 9 of 33 Page 10 of 33 Page 11 of 33 Page 12 of 33 Page 13 of 33 Page 14 of 33 Page 15 of 33 Page 16 of 33 Page 17 of 33 Page 18 of 33 Page 19 of 33 Page 20 of 33 Page 21 of 33 Page 22 of 33 Page 23 of 33 Page 24 of 33 Page 25 of 33 Page 26 of 33 Page 27 of 33 Page 28 of 33 Page 29 of 33 Page 30 of 33 Page 31 of 33 Page 32 of 33 Page 33 of 33