5802_Madison_MSWLF_GW_FID1281704_20190220

N.f i1Y [-]PaperReport [:]Electronic Data -Email CD data loaded: Yes /Noy Doc/Event #:
' NC DENR Environmental Monitoring
Division of Waste Management - Solid Waste Reporting Form
Notice: This form and any information attached to it are "Public Records" as defined in NC General Statute 132-1. As such, these documents are
available for inspection and examination by any person upon request (NC General Statute 132-6).
Instructions:
• Prepare one form for each individually monitored unit
• Please type or print legibly.
Attach a notification table with values that attain or exceed NC 2L groundwater standards or NC 2B surface water standards. The notification
must include a preliminary analysis of the cause and significance of each value. (e.g. naturally occurring, off -site source, pre-existing
condition, etc.).
Attach a notification table of any groundwater or surface water values that equal or exceed the reporting limits.
Attach a notification table of any methane gas values that attain or exceed explosive gas levels. This includes any structures on or nearby the
facility (NCAC 13B .1629 (4)(a)(i).
Send the original signed and sealed fonn, any tables, and Electronic Data Deliverable to: Compliance Unit, NCDENR-DWM, Solid Waste
Section, 1646 Mail Service Center, Raleigh, NC 27699-1646.
Solid Waste Monitoring Data Submittal Information
Name of entity submitting data (laboratory, consultant, facility owner):
Anchor QEA of North Carolina, PLLC
Contact for questions about data formatting. Include data preparers name, telephone number and E-mail address:
Name: Brian Gant
E-mail: [e-mail]
Facility name: Facility Address:
Madison County Closed Solid 389 Long Branch Road
Waste Facility Marshall, NC 28753
Environmental Status: (Check all that apply)
Initial/Background Monitoring ❑X Detection Monitoring
Type of data submitted: (Check all that apply)
p( Groundwater monitoring data from monitoring wells
Groundwater monitoring data from private water supply wells
I Leachate monitoring data
X� Surface water monitoring data
Phone: [phone]
NC Landfill Rule:
Facility Permit # (.0500 or .1600)
58-02 .0500
Assessment Monitoring
❑
Methane gas monitoring data
Corrective action data (specify)
Other(specify)
Actual sampling dates (e.g.,
October 20-24, 2006)
ctober 24 and 25, 2018
Corrective Action
Notification attached?
No. No groundwater or surface water standards were exceeded.
X Yes, a notification of values exceeding a groundwater or surface water standard is attached. It includes a list of groundwater and surface water
monitoring points, dates, analytical values, NC 2L groundwater standard, NC 213 surface water standard or NC Solid Waste GWPS and
preliminary analysis of the cause and significance of any concentration.
❑ Yes, a notification of values exceeding an explosive methane gas limit is attached. It includes the methane monitoring points, dates, sample
values and explosive methane gas limits.
Certification
To the best of my knowledge, the Informatbin reported and statements made on this data submittal and attachments are true and correct
Furthermore, I have attached complete notification of any sampling values meeting or exceeding groundwater standards or explosive gas
levels, and a preliminary analysis of the cause and significance of concentrations exceeding groundwater standards. I am aware that there
are significant penalties for making any false statement, representation, or certification including the possibility of a fine and imprisonment
Alec Macbeth, PG Projec tGeologis t
Facility Representative Name (Print) Title
OL-0_'� a z & , 7' -7-, `c
828-281-3350
(Area Code) Telephone Number
February 19, 2018 Affix NC Licensed/ Professional Geologist Seal
Signature Date
231 Haywood Street Asheville, North Carolina 28806
Facility Representative Address
P-1649
NC PE Firm License Number (if applicable effective May 1, 2009)
Revised 6/2009

February 2019
Madison County Closed Solid Waste Facility, Permit No. 58-02
ti9
kzANCHOR
QEA
Fall 2018
Semiannual Water Quality Monitoring Report
Prepared for Madison County, North Carolina

February 2019
Madison County Closed Solid Waste Facility, Permit No. 58-02
Fall 2018
Semiannual Water Quality Monitoring Report
Prepared for
Madison County, North Carolina
Post Office Box 579
Marshall, North Carolina 28753
Alec Macbeth, PG
Prepared by
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Number: C81500-01.01
\\ashevillel\asheville\Projects\Madison County\Reports\2018\Fall\58-02 - Closed\Fall 2018 Semiannual Water Quality Report.docx

TABLE OF CONTENTS
1 Introduction
2 Methods
1
2
2.1 Monitoring Well Sampling Methods...........................................................................................................2
2.1.1 Monitoring Wells MW-01 OLD, MW-02 OLD, and BG SPRING OLD...............................2
2.1.2 Monitoring Wells MW-03 OLD and MW-04 OLD...................................................................2
2.2 Surface Water Sampling Methods................................................................................................................3
2.3 Domestic Well Sampling Methods...............................................................................................................3
2.4 Sample Handling, Documentation, and Analysis....................................................................................3
3 Findings........................................................................................................................................5
3.1 Groundwater.........................................................................................................................................................6
3.1.1 Field Parameters..................................................................................................................................6
3.1.2 RCRA Metals..........................................................................................................................................6
3.1.3 Appendix I VOCs..................................................................................................................................6
3.2 Surface Water.......................................................................................................................................................7
3.2.1 Field Parameters..................................................................................................................................7
3.2.2 RCRA Metals..........................................................................................................................................7
3.2.3 Appendix I VOCs..................................................................................................................................7
3.3 Site Hydrogeology..............................................................................................................................................7
4 Summary......................................................................................................................................9
4.1 Future Activities...................................................................................................................................................9
5 References.................................................................................................................................10
TABLES
Table 1 Summary of Laboratory Analyses Performed on Samples
Table 2 Summary of Detected Constituents
FIGURES
Figure 1 Site Location Map
Figure 2 Sample Location Map
Fall 2018 Semiannual
Water Quality Monitoring Report i February 2019

APPENDICES
Appendix A Sampling Logs and Equipment Documentation and Instrument Calibration Data
Sheets
Appendix B Report of Laboratory Analysis and Chain -of -Custody Documentation
Fall 2018 Semiannual
Water Quality Monitoring Report ii February 2019

ABBREVIATIONS
µg/L
micrograms per liter
µS/cm
microsiemens per centimeter
213 standard
surface water quality standards defined in 15A NCAC 213
2L standard
groundwater quality standards defined in 15A NCAC 2L .0202
CFR
Code of Federal Regulations
Closed Landfill
closed MSW landfill
DEQ
North Carolina Department of Environmental Quality
DO
dissolved oxygen
DWM
Division of Waste Management
EDD
Electronic Data Deliverable
EPA
U.S. Environmental Protection Agency
IMAC
interim maximum allowable concentrations
MDL
method detection limit
mg/L
milligrams per liter
MRL
method reporting limit
MSW
Municipal Solid Waste
mV
millivolt
NCAC
North Carolina Administrative Code
NTU
Nephelometric turbidity units
ORP
oxidation reduction potential
PVC
polyvinyl chloride
RCRA
Resource Conservation and Recovery Act
SC
specific conductivity
SESD
Science and Ecosystem Support Division
SU
Standard Units
SWS
Solid Waste Section
SWSL
Solid Waste Section Limit
TestAmerica
TestAmerica Laboratories, Inc.
TOC
top of well casing
VOC
volatile organic compound
Fall 2018 Semiannual
Water Quality Monitoring Report iii February 2019

Introduction
The Madison County Solid Waste Department maintains a closed municipal solid waste (MSW)
landfill (Closed Landfill), located near the intersection of U.S. Highway 25/70 Bypass and Long Branch
Road (State Route 1582) in Madison County, North Carolina. The site location is presented in
Figure 1.
The Closed Landfill is permitted by the North Carolina Department of Environmental Quality (DEQ),
Division of Waste Management (DWM), under Permit No. 58-02, which requires semiannual
monitoring of groundwater and surface water quality.
This report, prepared by Anchor QEA of North Carolina, PLLC (Anchor QEA), is being submitted in
accordance with monitoring requirements for closed landfills as stipulated in DEQ DWM Permit
No. 58-02 issued to the Madison County Solid Waste Department, with regulations codified in the
DEQ Solid Waste Management Rules, Title 15A, Subchapter 13B, Section .1600 of the North Carolina
Administrative Code (15A NCAC 13B .1600).
This report describes the second semiannual groundwater and surface water quality monitoring
event performed in 2018.
The water quality monitoring network for the Closed Landfill consists of four monitoring wells
(MW-01 OLD, MW-02 OLD, MW-03 OLD, and MW-04 OLD), a background groundwater quality
sampling location (BG SPRING OLD), and two surface water sampling locations (SW-01 OLD
[upstream] and SW-02 OLD [downstream]) located along Profitt Branch. Monitoring wells
MW-03 OLD and MW-04 OLD are installed in bedrock near the top of a ridge in the western part of
the landfill parcel. Monitoring wells MW-01 OLD and MW-02 OLD are at lower elevations within
topographic drainages in the southern part of the landfill parcel and are screened in the upper
saturated zone.
The water sample collected from background sampling location BG SPRING OLD is treated as a
groundwater sample for the following reasons:
• Groundwater does not discharge to the ground surface at the sampling point.
• Construction of the sampling point is similar to that of a temporary monitoring well and is
located upslope and upgradient of a springhead.
• The sampling point consists of a polyvinyl chloride (PVC) casing extending below ground
surface with a screened interval from which groundwater is collected and recharges.
See Figure 2 for a map of these approximate sampling locations.
Fall 2018 Semiannual
Water Quality Monitoring Report 1 February 2019

2 Methods
Groundwater samples and surface water samples were collected at the Closed Landfill by
Anchor QEA personnel on October 24 and 25, 2018.
2.1 Monitoring Well Sampling Methods
Prior to groundwater sample collection from the monitoring wells, the static water level was
measured and recorded to calculate the well's volume. At each sample location, an initial round of
field parameters (consisting of pH, specific conductivity [SC], dissolved oxygen [DO], oxidation
reduction potential [ORP], turbidity, and temperature) was measured and recorded. Water level
measurements, field parameters, and observations pertaining to water quality are included in the
sampling logs in Appendix A.
2.1.1 Monitoring Wells MW-01 OLD, MW-02 OLD, and BG SPRING OLD
Following initial field parameter collection, groundwater monitoring wells MW-01 OLD and
MW-02 OLD and sampling point BG SPRING OLD were each purged using a new disposable
polyethylene bailer. MW-01 OLD and BG SPRING OLD were purged and sampled with a disposable
bailer due to poor well access. MW-02 OLD was purged and sampled with a disposable bailer,
because this monitoring well recharges too slowly to be sampled via low -flow methods. As each
consecutive well volume was removed with the bailer, an additional round of groundwater
parameters was recorded. Each well was purged until a minimum of three well volumes had been
removed and field parameters had stabilized, or until the well had been bailed dry. Monitoring well
MW-02 OLD, which was bailed dry after about 1.8 well volumes had been purged, was allowed to
recharge prior to collecting one final round of field parameters and the groundwater sample.
A technician wearing a new pair of non -reactive nitrile gloves collected each groundwater sample
and placed it directly into a laboratory -supplied sample container.
2.1.2 Monitoring Wells MW-03 OLD and MW-04 OLD
Monitoring wells MW-03 OLD and MW-04 OLD were purged and sampled with a bladder pump
using low -flow techniques in accordance with the procedures described in Low -Flow (Minimal
Drawdown) Ground -Water Sampling Procedures (Puls and Barcelona 1996). During purging, pH, SC,
DO, ORP, turbidity, and temperature were measured and recorded approximately every 3 minutes.
Well purging continued until these parameters had stabilized for three consecutive readings. The
following required stabilization criteria have been established by the U.S. Environmental Protection
Agency (EPA) Region 4 Science and Ecosystem Support Division Operating Procedure: Groundwater
Sampling (EPA 2017):
• pH values within ± 0.1 unit
Fall 2018 Semiannual
Water Quality Monitoring Report 2 February 2019

• SC values within ± 5%
Temperature, DO, and turbidity values within ± 10%
After these parameters had stabilized, a technician wearing a new pair of non -reactive nitrile gloves
collected a groundwater sample. Each sample was placed directly into laboratory -supplied sample
containers.
2.2 Surface Water Sampling Methods
Surface water samples SW-01 OLD and SW-02 OLD were collected at designated locations along
Profitt Branch, which flows adjacent to the Closed Landfill's southern boundary in a westerly direction
(Figure 2). The surface water sample collected at the SW-01 OLD location is interpreted to represent
surface water quality upstream of the Closed Landfill, and the surface water sample collected at the
SW-02 OLD location is interpreted to represent surface water quality downstream of the Closed
Landfill. One set of field parameters including temperature, pH, SC, DO, ORP, and turbidity was
measured and recorded at each surface water sampling location prior to sample collection
(Appendix A). One surface water sample was collected from each sampling location and transferred
into laboratory -supplied sample containers by a technician wearing a new pair of disposable nitrile
gloves.
2.3 Domestic Well Sampling Methods
Anchor QEA personnel attempted to contact the resident of the property owned by Ms. J.V. Edwards
but was not able to make contact. As such, Anchor QEA was unable to collect a sample from the
water supply well (DW-01) owned by Ms. Edwards during the fall 2018 sampling event.
2.4 Sample Handling, Documentation, and Analysis
Field parameters and additional observations pertaining to water quality sampling at the
Closed Landfill sampling locations are provided in the sampling logs in Appendix A. Following
sample collection, groundwater and surface water samples were immediately placed on ice in sample
coolers for transport to TestAmerica Laboratories, Inc. (TestAmerica), a laboratory certified in North
Carolina and located in Nashville, Tennessee. Anchor QEA submitted all collected groundwater and
surface water samples to TestAmerica for the following analyses:
• Appendix I volatile organic compounds (VOCs), using EPA Method 8260B
— Appendix I parameters are identified in Appendix I of the Code of Federal Regulations,
Title 40, Part 258 (40 CFR 258).
• Eight Resource Conservation and Recovery Act (RCRA) metals, using EPA Methods 601 OD and
7470A
• 1,4-Dioxane, using method 8260SIM
Fall 2018 Semiannual
Water Quality Monitoring Report 3 February 2019

The SWS issued the memorandum "1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory
Analytical Methods" dated May 29, 2018, which requires the analysis of 1,4-dioxane at landfills after
July 1, 2018 (DEQ 2018a). Per this memorandum, 1,4-dioxane was included in the sampling suite for
Site monitoring wells and surface water samples during the September 2018 sampling event.
A summary of laboratory analyses performed on the samples is provided in Table 1. Trip blanks,
provided by the laboratory and stored in each sample cooler, were analyzed for Appendix I VOCs,
including 1,4 dioxane. Proper chain -of -custody documentation procedures were followed during
collection and transport of each sample. The laboratory analytical reports and chain -of -custody
documentation are included in Appendix B.
Fall 2018 Semiannual
Water Quality Monitoring Report 4 February 2019

3 Findings
The field parameter data and laboratory analytical results for the groundwater, surface water, and
trip blank samples collected at the Closed Landfill are included in Appendices A and B, respectively,
and are also submitted separately to the DEQ DWM Solid Waste Section (SWS) in the Electronic Data
Deliverable (EDD) format (updated on May 5, 2010).
All laboratory analytical results were reported and appropriately qualified as follows:
• Non -Detections: Non -detections (non -detects) are values reported by the laboratory as
"below method detection limits (MDLs)" and are flagged with a "U" qualifier in Table 2. The
MDL is the minimum concentration of a substance that can be measured and reported by a
laboratory with 99% confidence that the constituent concentration is greater than zero.
• Estimated or "J" Qualified: A "Y' qualifier is used by the laboratory for parameters that are
detected at estimated concentrations greater than the MDL but less than the laboratory's
method reporting limit (MRL). The MRL is the minimum concentration of a target analyte that
can be accurately determined by the referenced method.
• 2L Standard: Detected concentrations of constituents in groundwater samples were
compared to applicable North Carolina groundwater quality standards. For most constituents,
this standard is the 2L standard, defined in 15A NCAC 02L .0202. Detected concentrations of
analytes in groundwater with no established 2L standard were compared either to the interim
maximum allowable concentrations (IMACs) for Class GA and GSA groundwater (in
accordance with 15A NCAC 02L .0202 [c]) or to the Groundwater Protection Standards
(pursuant to 15A NCAC 13B .1634). For the purposes of this report, groundwater standards
were taken from the October 15, 2018 list published by the NC Solid Waste Section (DEQ
2018b).
• 2B Standard: Detections of analytes in surface water samples were compared to the surface
water quality standards described in 15A NCAC 02B (213 standards). Hardness -dependent
2B surface water standards were calculated using the average analyzed hardness value
(calculated from the upstream and downstream surface water sampling location results) via
the most stringent hardness -dependent metal calculation.
Laboratory analytical data was previously qualified with a comparison to constituent -specific Solid
Waste Section Limits (SWSLs), established by DEQ in 2006. The SWSL was defined as the lowest
concentration of a constituent in a sample that can be quantitatively determined with suitable
precision and accuracy. The May 29, 2018 SWS memorandum "1,4-Dioxane Analysis, Solid Waste
Section Limits, and Laboratory Analytical Methods" states the discontinuation of SWSLs. Per this
memorandum, comparison of the analysis results to the former SWSLs is not addressed in this report
(DEQ 2018a).
Fall 2018 Semiannual
Water Quality Monitoring Report 5 February 2019

Table 2 summarizes the field parameter results and laboratory analytical results for detected
constituents. The following discussion outlines constituents detected at concentrations that
exceeded their respective 2L standards (including IMACs, if applicable) or 2B standards.
3.1 Groundwater
The following sections summarize the results of field parameter and laboratory analyses of
groundwater samples collected on October 24 and 25, 2018.
3.1.1 Field Parameters
The pH readings obtained from monitoring wells MW-01 OLD, MW-03 OLD, MW-04 OLD, and
BG-SPRING OLD (5.86 Standard Units [SU] to 6.23 SU) were below the range for pH (6.5 to 8.5 SU)
specified in the 2L standard (see Table 2). The pH from monitoring well MW-02 OLD (6.84) was
within the 2L standard.
Turbidity in the monitoring wells ranged from 2.96 nephelometric turbidity units (NTUs) in
monitoring well MW-03 OLD to 159 NTUs in BG-Spring OLD. Measured DO values ranged from
0.23 milligrams per liter (mg/L) in MW-03 OLD to 7.08 mg/L in MW-02 OLD. Specific conductivity
values ranged from 156.7 microsiemens per centimeter (pS/cm) in BG-Spring OLD to 1,132 pS/cm in
MW-03 OLD. ORP values in the monitoring wells ranged from -62.0 millivolts (mV) in MW-03 OLD to
237.3 mV in BG-Spring OLD (Table 2). These parameters do not have established groundwater
quality standards. Concentrations of field parameters are generally consistent with historical
concentrations.
3.1.2 RCRA Metals
Five metals were detected in groundwater samples collected from one or more monitoring wells
(Table 2). Two of these metals, barium and chromium, were detected at concentrations above their
applicable groundwater standard. Barium exceeded its 2L standard of 700 micrograms per liter (pg/L)
in the sample collected from one monitoring well, MW-03 OLD (956 pg/L). Chromium was detected
at a concentration above its 2L standard (10 pg/L) in the sample collected from monitoring well
BG-SPRING OLD (11.3 pg/L).
3.1.3 Appendix 1 VOCs
Thirteen VOCs were detected in groundwater samples collected from one or more of the
monitoring wells (Table 2). Benzene was detected at a concentration above its 2L standard (1 pg/L) in
one monitoring well, MW-03 OLD (1.20 pg/L). 1,4-dioxane was detected at a concentration above its
2L standard (3 pg/L) in monitoring well MW-01 OLD (4.56 pg/L). Vinyl chloride was detected in
MW-01 OLD at an estimated concentration (0.995 J pg/L) that exceeded the compound's 2L standard
(0.03 pg/L). The VOC detections are generally consistent with historical data.
Fall 2018 Semiannual
Water Quality Monitoring Report 6 February 2019

3.2 Surface Water
The following sections summarize the results of laboratory and field parameter analyses of surface
water samples SW-01 OLD and SW-02 OLD.
3.2.1 Field Parameters
The pH readings collected from SW-01 OLD and SW-02 OLD were 6.90 SU and 7.51 SU, respectively.
Both readings were within the 2B standard range established at 6.0 to 9.0 SU.
The turbidity readings collected from SW-01 OLD and SW-02 OLD were 20.8 NTUs and 5.08 NTUs,
respectively. Both readings were below the 2B standard of 50 NTUs.
The DO readings collected from SW-01 OLD and SW-02 OLD were 11.41 mg/L and 12.16 mg/L,
respectively. Both of these values are within the 2B standard for Class C waters (greater than or equal
to 5.0 mg/L).
SC measurements in SW-01 OLD and SW-02 OLD were recorded at 212.6 pS/cm and 229.2 pS/cm,
respectively. ORP values for these samples were recorded at 205.9 mV and 166.1 mV, respectively
(Table 2). These parameters do not have established surface water quality standards.
3.2.2 RCRA Metals
Barium was the only metal detected in the surface water samples at concentrations above the
applicable MDL. This metal was detected at concentrations below the metal's 2B standard in both
SW-01 OLD and SW-02 OLD (Table 2).
3.2.3 Appendix 1 VOCs
1,4 dioxane was the only VOC detected in the surface water samples at a concentration above the
applicable MDL. This estimated detection occurred in SW-02-OLD at 0.389 J pg/L, well below the
associated 2B standard of 80 pg/L (Table 2).
3.3 Site Hydrogeology
Groundwater levels were measured in the four monitoring wells, MW-01 OLD, MW-02 OLD, MW-03
OLD, and MW-04 OLD, at the Closed Landfill at depths of 6.28 feet below the top of the well casing
(TOC), 7.87 feet below TOC, 43.40 feet below TOC, and 44.28 feet below TOC, respectively
(Appendix A).
The spatial distributions and screened intervals of the monitoring wells at the Closed Landfill prohibit
an accurate calculation of groundwater flow direction. However, within the upper saturated zone, the
shallow groundwater is interpreted to generally mimic topography, flowing primarily southward
toward Profitt Branch. The Closed Landfill is situated on the southwest side of a knoll with an
Fall 2018 Semiannual
Water Quality Monitoring Report 7 February 2019

elevation of approximately 2,100 feet above mean sea level and slopes downward toward Profitt
Branch.
Fall 2018 Semiannual
Water Quality Monitoring Report 8 February 2019

4 Summary
Anchor QEA completed the second semiannual water quality monitoring event of 2018 at the Closed
Landfill on October 24 and 25, 2018. Table 1 summarizes the sampling and analyses that were
performed. Table 2, the field sampling logs (Appendix A), and the TestAmerica Reports of Laboratory
Analysis (Appendix B) provide detailed analytical results and field data related to groundwater and
surface water quality at the Closed Landfill. The following bullets summarize the results of the
sampling event:
• The concentration of barium exceeded its 2L standard of 700 pg/L in the sample collected
from monitoring well MW-03 OLD at 956 pg/L.
• Chromium was detected above its 2L standard of 10 pg/L in monitoring well BG SPRING OLD
at 11.3 pg/L.
• Benzene was detected at a concentration above its 2L standard of 1 pg/L in MW-03 OLD at
1.20 pg/L.
• The concentration of 1,4-dioxane exceeded its 2L standard of 3 pg/L in the sample collected
from monitoring well MW-01 OLD at 4.56 pg/L.
• Vinyl chloride was detected at an estimated concentration of 0.995 J pg/L in the sample
collected from MW-01 OLD, which exceeds the 2L standard of 0.03 pg/L.
• The measured depths to groundwater in the upper saturated zone within the topographic
drainages at the landfill ranged from 6.28 to 7.87 feet below TOC. The groundwater depths in
the bedrock monitoring wells at top of the ridge ranged from 43.40 to 44.28 feet TOC. The
shallow groundwater is interpreted to generally mimic topography, flowing primarily
southward toward Profitt Branch.
4.1 Future Activities
Anchor QEA will continue to measure field parameters and collect water quality samples from
groundwater and surface water monitoring points associated with the Closed Landfill. Water quality
samples will be submitted to a North Carolina -certified laboratory for analysis of RCRA metals and
Appendix I VOCs on a semiannual basis. The next sampling event is scheduled for March 2019.
Fall 2018 Semiannual
Water Quality Monitoring Report 9 February 2019

5 References
DEQ (North Carolina Department of Environmental Quality), 2018b. "Groundwater Protection
Compliance Standards — Constituents List". Last modified October 15, 2018. Available at:
https://edocs.deq.nc.gov/WasteManagement/0/edoc/l257181/SWS EnviroMonitoring Const
ituents List.pdf?searchid=13f8efbl-eel 1-485a-b03f-718f2287b271
DEQ (North Carolina Department of Environmental Quality), 2018a. Memorandum to: Solid Waste
Directors, Landfill Owners/Operators, and North Carolina Certified Laboratories. Regarding:
1,4-Dioxane Analysis, Solid Waste Section Limits, and Laboratory Analytical Methods.
May 29, 2018.
EPA SESD (U.S Environmental Protection Agency Science and Ecosystem Support Division), 2017.
Operating Procedure: Groundwater Sampling. April 26, 2017.
Puls, Robert W. and Michael J. Barcelona, 1996. Low -Flow (Minimal Drawdown) Ground -Water
Sampling Procedures. EPA/540/5-95/504. April 1996.
Fall 2018 Semiannual
Water Quality Monitoring Report 10 February 2019

Tables

Table 1
Summary of Laboratory Analyses Performed on Samples
Groundwater Samples
Facility Permit
Well ID
Collect Date
VOCs
RCRA Metals
EPA 8260B &
8260B SIM
EPA 6010D
EPA 7470A
58-02
MW-01 OLD
10/25/2018
X
X
58-02
MW-02 OLD
10/24/2018
X
X
58-02
MW-03 OLD
10/25/2018
X
X
58-02
MW-04 OLD
10/25/2018
X
X
58-02
BG SPRING OLD
10/25/2018
X
X
Surface Water Samples
Facility Permit
Sample ID
Collect Date
VOCs
RCRA Metals
Total Hardness
EPA 8260B &
8260B SIM
EPA 6010D
EPA 7470A
EPA SM 2340B
58-02
SW-01 OLD
10/24/2018
X
X
X
58-02
SW-02 OLD
10/24/2018
X
X
X
Quality Control Samples
Facility Permit
Sample ID
Collect Date
VOCs
EPA 8260B &
8260B SIM
58-02
TRIP BLANK (MW OLD)
10/25/2018
X
58-02
TRIP BLANK (SW OLD)
10/24/2018
X
Notes:
Analyses include Appendix I constituents per the Code of Federal Regulations (40 CFR Part 258).
A sample could not be collected from the Edwards's residence domestic water supply sample, DW-01 OLD, during this sampling event.
RCRA: Resource Conservation and Recovery Act
VOC: volatile organic compound
EPA: U.S. Environmental Protection Agency
SIM: selective ion monitoring
Fall 2018 Semiannual Water Quality Monitoring Report Page 1 of 1
Madison County Closed Municipal Solid Waste Landfill, Permit Number 58-02 February 2019

Table 2
Summary of Detected Constituents
Lab Certification
Metals
387
vw
387
Lab Method
EPA 601OD & 7470A
SM 2340B
EPA 8260B & 8260B SIM
Parameter
Barium
Chromium
Lead
Mercury
Selenium
Hardness
Acetone
Benzene
Chlorobenzene
Chloroethane
cis-1,2-
Dichloroethene
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
CAS Number
7440-39-3
7440-47-3
7439-92-1
7439-97-6
7782-49-2
NA
67-64-1
71-43-2
108-90-7
75-00-3
156-59-2
95-50-1
106-46-7
75-34-3
SWS ID
15
51
131
132
183
NA
3
16
39
41
78
69
71
75
Units
Ng/L
pg/L
Ng/L
pg/L
I Ng/L
pg/L
Ng/L
pg/L
pg/L
pg/L
pg/L
Ng/L
pg/L
Ng/L
Sample ID
Collect Date
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Monitoring Well Samples
MW-01 OLD
10/25/2018
438
4.10 J
2.10 J
0.0700 U
15.4
NA
2.66 U
0.548 J
2.92
1.40
4.26
0.339 J
4.33
1.01
MW-02 OLD
10/24/2018
62.7
3.00 J
3.00 J
0.0800 J
5.00 U
NA
2.66 U
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.823 J
MW-03 OLD
10/25/2018
956
3.60 J
2.00 U
0.0700 U
11.9
NA
2.66 U
1.20
5.26
0.651 J
0.210 U
0.190 U
2.31
0.240 U
MW-04 OLD
10/25/2018
691
5.00
4.50 J
0.0700 U
15.1
NA
2.66 U
0.200 U
3.31
0.733 J
0.210 U
0.190 U
1.12
0.240 U
BG SPRING OLD
1 10/25/2018
203
11.3
4.50 J
0.0700 U
5.50 J
NA
2.66 U
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.240 U
Surface Water Samples
SW-01 OLD
10/24/2018
62.5
2.00 U
2.00 U
0.0700 U
4.00 U
52,500
2.66 U
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.240 U
SW-02 OLD
10/24/2018
49.2
2.00 U
2.00 U
0.0700 U
4.00 U
64,200
2.66 U
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.240 U
Quality Control Sample
TRIP BLANK (MW OLD)
10/25/2018
NA
NA
NA
NA
NA
NA
21.2 J
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.240 U
TRIP BLANK (SW OLD)
10/24/2018
NA
NA
NA
NA
NA
NA
22.0 J
0.200 U
0.180 U
0.360 U
0.210 U
0.190 U
0.170 U
0.240 U
MDL
5
3
2
0.100
5
NA
2.66
0.200
0.180
0.360
0.210
0.190
0.170
0.240
MRL
10
5
5
0.200
10
3,300
25.0
1.00
1.00
1.00
1.00
1.00
1.00
1.00
2L
700
10
15
1
20
NE
6,000
1
50
3,000
70
20
6
6
IMAC
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
GWPS
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
2B
21,000
47.68*
1.39*
0.012
5
NE
2,000
51
800
NE
720
3,000
900
100
Fall 2018 Semiannual Water Quality Monitoring Report Page 1 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 February 2019

Table 2
Summary of Detected Constituents
Lab Certification
VOCs (Appendix 1)
387
Total Hardness
387
Field Parameters
5445 (pH only)
Lab Method
EPA 8260B & 8260B SIM
SM2340B
Parameter
1,2-Dichloropropane
1,4-Dioxane
Toluene
trans-1,2-
Dichloroethene
Trichloroethene
Vinyl Chloride
Hardness
pH
Turbidity
Dissolved
Oxygen
Temperature
Specific
Conductivity
Oxidation
Reduction
Potential
CAS Number
78-87-5
123-91-1
108-88-3
156-60-5
79-01-6
75-01-4
NA
SW320
SW330
SW356
7782-44-7
SW323
SW336
SWSID
82
422
196
79
201
211
NA
320
330
356
325
323
336
Units
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
pg/L
SU
NTU
mg/L
°C
PS/cm
mV
Sample ID
Collect Date
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Result
Monitoring Well Samples
MW-01 OLD
10/25/2018
0.354 J
4.56
0.170 U
0.342 J
0.529 J
0.995 J
NA
6.09
44.0
2.51
15.5
713
70.6
MW-02 OLD
10/24/2018
0.250 U
0.443 J
0.170 U
0.230 U
0.200 U
0.180 U
NA
6.84
36.2
7.08
14.0
224.6
221.6
MW-03 OLD
10/25/2018
0.250 U
0.254 U
0.170 U
0.230 U
0.200 U
0.180 U
NA
6.23
2.96
0.23
13.9
1,132
-62.0
MW-04 OLD
10/25/2018
0.250 U
0.488 J
0.449 J
0.230 U
0.200 U
0.180 U
NA
6.17
6.94
2.08
12.7
917
91.8
BG SPRING OLD
10/25/2018
0.250 U
0.254 U
0.170 U
0.230 U
0.200 U
0.180 U
NA
5.86
159
1.80
16.3
156.7
237.3
Surface Water Samples
SW-01 OLD
10/24/2018
0.250 U
0.254 U
0.170 U
0.230 U
0.200 U
0.180 U
52,500
6.90
20.8
11.41
10.7
212.6
205.9
SW-02 OLD
10/24/2018
0.250 U
0.389 J
0.170 U
0.230 U
0.200 U
0.180 U
64,200
7.51
5.08
12.16
10.1
229.2
166.1
Quality Control Sample
TRIP BLANK (MW OLD)
10/25/2018
0.250 U
0.254 U
0.170 U
0.230 U
0.200 U
0.180 U
NA
NA
NA
NA
NA
NA
NA
TRIP BLANK (SW OLD)
10/24/2018
0.250 U
0.254 U
0.170 U
0.230 U
0.200 U
0.180 U
NA
NA
NA
NA
NA
NA
NA
MDL
0.250
NA
0.170
0.230
0.200
0.180
NA
NA
NA
NA
NA
NA
NA
MRL
1.00
0.254
1.00
1.00
1.00
1.00
3300
NA
NA
NE
NE
NE
NE
2L
0.6
3
600
100
3
0.03
NE
6.5-8.5
NE
NE
NE
NE
NE
IMAC
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
GWPS
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
NE
2B
31
80
11
4,000
30
2.4
NE
6.0-9.0
50
>_ 5.0
NE
NE
NE
Fall 2018 Semiannual Water Quality Monitoring Report Page 2 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 February 2019

Table 2
Summary of Detected Constituents
Notes:
Only detected constituents are listed in this table. Please refer to the TestAmerica laboratory analysis reports for further details.
Shaded cell: indicates a result in exceedance of the 2L, IMAC, GWPS, or 2B standard
pg/L: micrograms per liter
pS/cm: microsiemens per centimeter
213: surface water standard, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017), or standard obtained from National Criteria per EPA table (current
as of May 15, 2013)
2L: groundwater standard, per North Carolina Administrative Code, Title 15A: Department of Environmental Quality, Subchapter 2L - Groundwater Classifications and Standards (last amended October 15, 2018)
CAS Number: a unique number assigned by the Chemical Abstracts Service (CAS) to all identified parameters
Collect Date: the date on which the sample was collected in the field
EPA: U.S. Environmental Protection Agency (method)
GWPS: Groundwater Protection Standard, per 15A NCAC 13B .1634. Current standards were obtained from the North Carolina Department of Environmental Quality, Solid Waste Section Environmental Monitoring List (last updated June 13, 2011). GWPS is used only if the
2L or IMAC standards are not established for a specific constituent.
IMAC: interim maximum allowable concentration, per Appendix 1 of the 2L standards
1: a laboratory data qualifier used for parameters detected at estimated concentrations above MDL but below MRL
Lab Method: the analytical method used to analyze the constituents
MDL: method detection limit, which is the minimum concentration of a substance that can be measured and reported with 99 percent confidence that the analyte concentration is greater than zero
mg/L: milligrams per liter
MRL: method reporting limit, which is the minimum concentration of a target analyte that can be accurately determined by the referenced method
mV: millivolt
NA: not applicable
NE: not established
NTU: nephelometric turbidity unit
Result: analytical data reported by the laboratory, or field data collected by Anchor QEA
SU: Standard Unit
SWS ID: Solid Waste Section identification number
SWSL: Solid Waste Section Limit (established by the North Carolina Department of Environmental Quality); the lowest amount of analyte in a sample that can be quantitatively determined with suitable precision and accuracy
U: laboratory data qualifier used for parameters not detected at concentrations above MDL
VOC: volatile organic compound
*: 2B surface water standard calculated using average analyzed hardness value (calculated from the upstream and downstream sampling location results) via the most stringent hardness -dependent metal calculation, per North Carolina Administrative Code, Title 15A:
Department of Environmental Quality, Subchapter 2B - Surface Water and Wetland Standards (last amended September 2017).
Fall 2018 Semiannual Water Quality Monitoring Report Page 3 of 3
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02 February 2019

Figures

��� �. /��� !� � v � >•_ '-��`', -- ��\,�1�!'C )ter'` �'I}�� a m , �`
t'
000
�.t2ov
`�"
Sri
IN
t I I J _ 1 e ('' J��1 ♦_
LEGEND: SOURCES:
Basemap: USGS 1:24,000 Scale Topo Maps, Marshall 0 2,000
® Landfill Parcel Quadrangle, 1990
Parcels: Madison County GIS Feet
Publish Date: 2019/02/13, 8:29 AM I User: alesueur
Filepath: \\AsheviIlel\Asheville\GIS_Projects\MadisonCounty\Maps\2018\2018_FallWaterQuality\AQ_F01_SiteLocationMap_ClosedLF.mxd
kZANCHOR
QEA
Anchor QEA of North Carolina, PLLC
Figure 1
Site Location Map
Fall 2018 Semiannual Water Quality Monitoring Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02, Marshall, North Carolina

- R =* M. .
• MW-04 OI
DW-01 OLD
NCH
LEGEND: NOTE:
Monitoring well and surface water
Monitoring Well Location Roads samples are approximate.
Surface Water Sample Location — Streams SOURCES. 0
0 Landfill Parcel Boundary Basemap: NC OneMap 2010
Contours and Roads: NCDOT 0 400
Elevation Contours (10-Foot Interval) Streams: NC OneMap
Parcel Boundary: Madison County GIS Feet
Publish Date: 2019/02/13, 8:37 AM I User: alesueur
Filepath: \\Ashevillel\Asheville\GIS_Projects\MadisonCounty\Maps\2018\2018_FallWaterQuality\AQ_F02_SampleLocationMap_ClosedLF.mxd
j� ANCHOR Figure 2
lam► OEA— Sample Location Map
Anchor QEA of North Carolina, PLLC
Fall 2018 Semiannual Water Quality Monitoring Report
Madison County Closed Municipal Solid Waste Landfill, Permit No. 58-02, Marshall, North Carolina

Appendix A
Sampling Logs and Equipment
Documentation and Instrument
Calibration Data Sheets

ANCHOR
QEA
Well Sampling Log
Project Name: aA( SU,0 & ,D�Cd
Project Number Soo —6 t of U
Sampling Personnel: �^;
Well Number. _G' i' O t U D
Well Diameter. J� if
P
Type of Casing: U G —
Measuring Point (�
Flush Mount /'Stick -Up
Comments
Anchor QEA of North Carolina, PLL
231 Haywood Strei
Asheville, North Carolina 2880
Date:
Weather.
Sample Time:
Well Depth in Feet (WD):
Water Level in Feet (WL):
Length of Water Column:
z feet
(WD) - (WL) =. (LWC)
One Casing Volume.—
gallons
(LWC) x (WCV)
Three Casing Volumes:'
. rt * gallons
Actual Volume Purged:
p V gallons
Well Casing Volumes (WCV)
1" = 0.04 Gal/Ft 2" = 0.16 Gal/8t 3" = 0.37 Gal/Ft 4" = 0.65 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft
Purge Method:
Sample Method:
iler-Disp. Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
. Bailer-Disp.:• Bailer -Teflon Dedicated Pump Whale Pump Grundfos Other.
Reading Time
' -
Gall3ns r
Purged emp Dissolved Speafic{ond pH'(S.UJ Reduc#on 'yurbidit�i
g (°Ci OxY9en an9/L) (NS/tm) reporE tb 01,'S�A Potential; (m16� . _ �(NTU.) Comments
1 r� 1 TI �— �� 3
Get­1
2
t %
LJ
t.L
3
cl g
�L'
J
.6'
l
2_ - q
5
6
7
8
9
10
Sampling contalner.
Number of containers Requested llnatysis"
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 ml. Glass
1 L Glass
Other
-
7 _ ��Q O 'vt, -k l aS611- (I\L
W�
Protective Casing: io-�
Pad: _ Lock: .. Vegetation: i Access:
11 /
Sampling Personnel Signature:
Date: 1 0 7— j 11
Notes:
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedure -
Groundwater Sampling last revised April 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization.
"C: degrees Celsius mV: millivolt
p5/cm: micro-Siemen per centimeter NTU: nephelometric turbidity units
mg/L: milligrams per liter S.U.: Standard Units
Method Reference: Specific conductivity: EPA Method 120.1, Rev. 1982
Temperature: SM 2550 B-2010 pH: SM 4500-H' B-2011
DO: SM 4500 O G-2011
Dom.... 9 ..F 9

, 7, ANCHOR
QEA
Well Sampling Log
Anchor QEA of North Carolina, PLL
231 Haywood Stre(
Asheville, North Carolina 2880
Project Name: 4 A - m n
Date:
Project Number. t5 _
Weather.
-
Sampling Personnel:
Sample Time:
Well Number.
Well Depth in Feet (WD):
Well Diameter._ 11
Water Level in Feet (WL):
�.-
Type of Casing: B U C'
Length of Water Column:
3 5 : -t� feet
Measuring Point: Ty
(WD) - (WL) =. (LWC)
Flush Mount Stick-U
One Casing Volume:
( gallons
Comments:
(LWC) x (WCV)
Three Casing Volumes:
gallons
Actual Volume Purged:
gallons
Well Casing Volumes (WCV)
1" = 0.04 Gal/F 2" = 0.16 3" = 0.37 Gal/Ft
4" = 0.65 Gal/Ft 6" = 1.5 Gal/Ft 8" = 2.6 Gal/Ft 12" = 5.9 Gal/Ft
Purge Method: er-Disp. Bailer -Teflon Dedicated Pump
Whale Pump Grundfos
Other.
Sample Method:(Bai'ler-Dis Bailer -Teflon Dedicated Pump
Whale Pump Grundfos
Other.
s
xi inn
-
Gallons + Temp Dissolved Specific Cond. pli(SJJ)
itiliduttion Turbidity
i2eading iime Purged E°C) 0?tygen4 g 1) CpS/cm) report;ia`0.7`S17 .
Pbteniial; m1!)... (SITU)
_I
Comments,
4
(�
( .bed
5
6
7
I
8
9
10
Sampling Container Number of Containers-
. .. _..
Requested.Analysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass
9'>6-40, SO-4e) S Ili
1 L Glass
Other
Protective Casing: � ' Pad: Lock Vegetation:
� 9
7 ` Access: r --
Sampling Personnel Signature: ..
Date:
1vt>A
Notes:
1,.
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedure
Groundwater Sampling last revised April 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization.
°C: degrees Celsius
mv: millivolt
PS/cm: micro-Siemen per centimeter
NTU: nephelometric turbidity units
mg/L: milligrams per liter
S.U.: Standard Units
Method Reference:
Specific conductivity: EPA Method 120.1, Rev. 1982
Temperature: SM 2550 B-2010
pH: SM 4500-H' B-2011
DO: SM 4500 O G-2011
D--^ 1 -F 1

Anchor QEA of North Carolina, PLLC
tZANCHOR
IDEA
Low -Flow Sampling Log
231 Haywood Street
Asheville, North Carolina 28801
Project Name: _mad, Qst; o co �U0S--J
Location: Y f��tCd. a G
Sampling Personnel: �l,
Well ID: (,� 3 ���
Screen Interval: !.�/ 1=f ' bgs
Depth to Water. _d itoc
Stickup:
Depth of Pump Intake: v 7 toc
Drawdown Set: '+ toc
Pump Used (circle): 11 11 Peristaltic ladd Other (description):
Comments: r — 20 / 7 i'D
Project Number.
Date:
Weather.
Arrive at Well:
Start Time:
Sample Time:
Finish Sample Time:
Leave Well:
Well Diameter.
Cs(r�oo , ©t QI
t ++
C_ . TF
0
j
Z
032
i
Time
DT1N (feet)
Temp ('C)
" DO (mg/L) _
: Specific Cond. (AS)
pH (S.U.)
import to D.7 S.U.
oko (ml)1
'
` Turbidity (NTU)
l
N 3. 52,
Let 't-0
F
3 �:
�' .
6.1. Z. Z
i C�
-
13 •v
Z
2.Ci
. 2-4
ki
��
2-1
r
- Z
� � r
Z
11 IL
13 6
I fn
3,5-Z-
0.
Sampling Personnel Signature:
Date:
Notes:
Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.7 pH unit +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drowdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection.
NS: micro-Siemen .
°C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 0 G-2011
mv: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
S.U.: standard units
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1982
pH: SM 4500-Hi B-2011
Page 1 of 1

H. ANCHOR
-►A QEA
Low -Flow Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name: j1nCVA(W (..(.Ct.d L�—_
Location: _(rl ,2 iK6L
Sampling Personnel: '" y--
Well ID: l {/�"1n;liu -01-f 01,0
Screen Interval: bgs
Depth to Water �toc
Stickup: �S
Depth of Pump Intake: n,. far �toc
Drawdown Set: toc
Pump Used (circle): Peristaltic Bladder Other (degcription):
Comments: 0(]w
Project Number Ca -(Goo
Date: "I Z
Weather.
Arrive at Well: t
Start Time:
Sample Time: Z
Finish Sample Time: L
Leave Well:
Well Diameter. t
Time
DTIN (feet)
Temp (C'
DO (mg/L)
S.pedfic'Cond. (pS)
report to 0.1 S U ,
ORP (mV)
Turbrdiiy (NTU) ,.
/12-
571
r7
�i
i3 3
Jlr
■z
��
ea
n 3
I
, 'Ls
311
�.0
4-
2■
�.•
FIN
Sampling Personnel Signature:
Date:/-d
Notes: }[ J ---
Stabilization (3 successive readings, 3 minutes apart): within +/- 70% DO and turbidity, +/- 3% Conductivity, +/- 0.1 pH uni;• +/- 10 mV for ORP
from EPA - Low -Flow (Minimal Drawdown) Groundwater Sampling Procedures, April 1996 (Rev 2010)
Samples are analyzed immediately upon collection,
pS: micro-Siemen
'C: degrees Celsius
bgs: below ground surface
DO: dissolved oxygen
mg/L: milligrams per liter
Method Reference:
Temperature: SM 2550 B-2010
DO: SM 4500 O G-2011
mV: millivolt
NTU: nephelometric turbidity units
ORP: oxidation reduction potential
S.U.: standard units
toc: top of casing
Specific conductivity: EPA Method 120.1, Rev. 1982
pH: SM 4500-H* B-2011
Page 1 of 1

ANCHOR
QEA
Well Sampling Log
Project Name:
Project Number. Yj`�-( lsoc) , o I
Sampling Personnel: A s 4
Well Number. (�)Q,&j9 1 N6 O (J-)
Well Diameter.. a r r I
Type of Casing:
Pvc-
Measuring Point:
Flush Mount tick -Up
Comments:
Anchor QEA of North Carolina, PLL
231 Haywood Stre(
Asheville, North Carolina 2880
Date:
Weather a
Sample Time:
Well Depth in Feet (WD):
Water Level in Feet (WL):
Length of Water Column:
"
feet
6
(WD) - (WQ = (LWC)
One Casing Volume:
gallons
(LWC) x (WCV)
Three Casing Volumes:
gallons
Actual Volume Purged:.,. afy
gallons
Sampling Container, , I Number of Containers, Regpested Malysis
500 mL Plastic
250 mL Plastic
125 mL Plastic
40 mL Glass l
1 L Glass
Other
Protective Casing: _VZPad: 1 Lock Vegetation: tlY! ccess h
Sampling Personnel Signature: i �- Date: l� j��' l 1
f [ / j I ✓I
Notes:
Well Casing Volumes defined in Table 2 of the Region 4 Environmental Protection Agency (EPA) Science and Ecosystem Support Division (SESD) document titled Operating Procedure -
Groundwater Sampling last revised April 26, 2017.
Samples are analyzed immediately upon collection.
Minimum volume purged: 3 well volumes. Sample time determined by parameter stabilization.
°C: degrees Celsius mV: millivolt
pS/cm: micro-Siemen per centimeter NTU: nephelometric turbidity units
mg/L: milligrams per liter S.U.: Standard Units
Method Reference: Specific conductivity: EPA Method 120.1, Rev. 1982
Temperature: SM 2550 B-2010 pH: SM 4500-H' B-2011
DO: SM 4500 O G-2011
Dom,... '! -4 1

ANCHOR
QEA �.�..
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:ffl
Project.Number:
Sampling Personnel:
Sample Name:
Comments:
oA �� Cd. Vl Dd� d �
1 _ 0
Ai., —
0
Date:
Weather:
rarlc aJ,10--de, Ilvel, e,.oe,n
rI V
Sample Method:
Grab Syrin a Pump
Bailer-Disp.
Other:
Time
-
Temp (°C)
-
Dissolved
oxygen (mgA)
Specific Cond.
(IS/cm)
- s
pii (S U.).= .
report to 01 S.0 :
Oxidation
Reduction
Potential (m1/)
Turbidity
(NTU) ,_
Comments
y
IN
'�mpling Container
Number of Containers J
Requested Analysis . • :,
jUO mL Plastic
All I
il
03 kk
250 mL Plastic
Z
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: A �. � Access: k 4
A
Sampling Personnel Signature: Date:
(((
ni,.a,.... AAu4nr4 Q.F.-
-
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L milligrams per liter
mv. millivolt=
NTU: nephelometric turbidity units
S.0 : standard units
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
PH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
QEA.v
Surface Water Sampling Log
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Project Name:
r:
Project Numbeq(
Sampling Personnel:
Sample Name:
Comments:
r;�� /'r: � C]p�d+ (;- G
j' - a �W� I
pK��
vlsrpm lah
Date:
Weather:
'DI *(Cl
n S
twnT
Sample Method:
Grab
Syringe Pump
Bailer-Disp.
Other:
Time' ,
•Temp (°C)
Dissolved'
Oxygen (mg/L)
Specific Cond.'
(PSLcm) -
3 -
pH (S.U.)
report to 0 1 S.0
r'CIA dation
= Reduction
Potential (MV)
Turbidity .
(NTU);,
Comments
0�6
��-�
��c�
" �mpiing Containers
Number a Containers
Requested Analysis `y
.,u0 mL Plastic
250 mL Plastic
1
cl/�1e1
125 mL Plastic
40 mL Glass
1 L Glass
Other
Vegetation: O ` �;tv� towvvv S
Access:
Sampling Personnel Signature: Date.
Notes: Method Reference:
Samples are analyzed immediately upon collection.
°C: degrees Celsius
pS/cm: micro-Siemen per cubic centimeter
mg/L: milligrams per liter
mv: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Page 1 of 1

ANCHOR
QEA
Sampling Log
Project Name: Maaj S-p,n co,c,ow� ("F
Project Number: CVSQ0 C)
Sampling Personnel: �SG
Sample Name: Dw—o + 0
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Date: _kol 2-SI i�
Weather. CLL5hAMr CJVs ~
Comments: PSL CJ ; W b 00 Q L � _ _��r CfzyLd- L Q:L CQ I(.CC.k—
Sample Method: Grab Syringe Pump Bailer-Disp. Other:
Vegetation: Access:
Sampling Personnel Signature:
Notes:
pS: micro-Siemen per cubic centimeter
°C: degrees Celsius
mg/L: milligrams per liter
mV: millivolt
NTU: nephelometric turbidity units
S.U.: standard units
Date:
Method Reference:
Temperature: SM 2550 B-2010
Specific conductivity: EPA Method 120.1, Rev. 1982
DO: SM 4500 O G-2011
pH: SM 4500-H' B-2011
Ibl2--s 1� K/
Page 1 of 1

4,)2, ANCHOR
-v IDEA
Equipment Documentation and Instrument Calibration Data Sheet
r- CALIBRATION DOCUMENTATION
Project Name: Q(t�ylC p_ (,Q L�1 Person Conducting Calibration: (�
Project Number.._0d_q0, 0 Date of Calibration: LU '
Project Location: ! ► I r� Date of Field Measurements: �+
G1{✓1r IrI G1 ✓✓\.✓M&1V 1N11V1Y
Equipment or meters used to take measurements (e.g., water level meters, survey equipment):
EgtiipeaentType- ,
Serial Nu"er,
. Brat N
i)ate of ise "
150-ft Water Level
26154
Solinist
;
150-ft Water Level
22754
Solinist
150-ft Water Level
150
Testwell
150-ft Drawdown
MP30-1527
QED
Other
Select Turbidimeter. Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
instrtrment°Reading
tHach 211fDQ)
Callibration _ 2t1NTU 100NTU BOO:NTU Ii000-MT
Cal:; jI, y
Cal: )1
Cah W
Cal:
Cal:
Cal:
Tim L .I
Time- (J 3
Time-
Time:
Time:
Time:
�,
Verification (10 NTU):
Verification:
Verification:
Verification:
Time-
10 NTU Cal. xpiration Date:
Time:
Time:
Time:
Anchor QEA of North Carolina, PLLC
231 Haywood Street
Asheville, North Carolina 28801
Y3,1 Professionals]u;1V11u13iparameter;Meter{3�ri
18131D180Z) ' • �
�=ins#riI entReadingsT. ;
CalibratiorifxpiratioltDate
Dissolved Oxygen
Initial:
D t, VL)
Cal:
mmHg.
- r �y�
Vi
Temperature (°C):
C
Time:
6
NA
PH 7 S.U.
report to 0.7 S.U.
Initial: 1 j
_ (J 1
pHmV:
��"
Ca`l:
- 00
pHmV:
X
Time: _
o�
J)lam
PH 4 S.U.
report toaiS.U.
Initial•
�.UU
pHmV:
IS���
Cal,: (
4,00
QQ�
1Z3 (o
Time:
6�5
1pHmV:
/�
() l ?n1q
PH 0
reportto0.1 S.U.
Initial: `
pHiV:,
Cal
` C U
pHmV(
Time:
QC* pH 7 S.U.
reportto O.l S.U.
AM Time:
Meas:
(0
Mid Day Time:
Check:
PM Time:
Check:
y
© O �
Spec.Cond.
I06v
Initial:
0(,�T
Cal:.
q
Time:
0 �j
Q
pS/cm**
6 r
!
u`
QC*:
I OO�NS/cm
AM Time:
d&D(a
Meas:
a
Mid Day Time:
Check:
PM Time:
Check:
ORP �� mV
Initial:
alit 1y,,3-
Cal:
^1l CEO`
Temperature (°C):
Time:
Signature: Date: 10 / )V 1 CY
Notes:
1, Electronic equipment calibrated according to the manufacturer's operation manual.
2. Specific Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, PH 7, pH 4, pH 10, DO, ORP, QC checks.
4. QC Acceptable Ranges: pH +/- 0.1 S.U. and Specific Conductivity 10% of the true value. If QC readings are out of range, the instrument needs to be recalibrated.
5. * Indicates that a QC check must be performed in the morning, afternoon, and the end of the day, or every four hours.
6. ** Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location.
Method Reference: Temperature: SM 2550 B-2070 I Specific conductivity: EPA Method 120.7, Rev. 7982 1 DO: SM 4500 0 G-2011 I pH: SM 4500-H+ B-2071
Page 1 of 1

ANCHOR OR Anchor QEA of North Carolina, PLLC
CffA<.cry 231 Haywood Street
Asheville, North Carolina 28801
Equipment Documentation and Instrument Calibration Data Sheet
CALIBRATION DOCUMENTATION
Project Name: �A QA,( � - Q . L F Person Conducting Calibration:
6
Project Number
f_.qf.5 0o � 6l. 0 I _ Date of Calibration:
C
I ��
Project Location:�� A �l Date of Field Measurements:
►C ( j 1`) E1MP�
EQUIPMENT DOCUMENTATION
Equipment or meters used to take measurements (eg., water level meters, surrey equipment):
uip+i
; ow -
Br�ji�
tist�erai�
150-ft Water Level
26154
Solinist
15)-ft Water Level
22754
Solinist
150-ft' Water Level
ISO
Testweil
150-ft Drawdown
MP30-1527
QED •`
Other
Select Turbidimeter.
Hach 2100Q (s/n 151006045207)
HF Scientific MicroTPW (s/n 200601045)
Dissolved Oxygen
Initial:
C r
Cal:G? II
mmHg:
Temperature (°C):
4
Time:
f �1
PH 7 S.U.
report to 0.1 S. U.
Initial: C
(�2. b
pHmV:
�� ✓
Call;
�'. Q ()
pHmV:
�- 3
Time:
. 9 _
�%�O
PH 4 S.U.
report toais.U.
Iniiia :
��
pHmV:
C' i .-d-
Cal:
q.0U
pHmV:
Time:
PH 10 S.U.
report to a7 S.U.
Initial:
to, 6
pHmV: 5
Cal �' 0 1
pHmV:
'
Tirpe
fvl�
QC' pH 7 S.U.
AM Time:
Meas.
Mid Day Time:
Check:
PM Time:
report to 0. I &U. ) 0 V I, ! -) , Q o
Spec. Cond.
Initial:
Cal:
lov v psftm-
100-t
1000
W:hf
d r� V pS/cm
AM,,LLTii0 Vmee;
U --�
Meas:
t o o
ORP 0 mV 1In'Ria o' 110 r I • U
Gr35
Mid Day Time:
MY Time:
asV5
Time: I Check:
'"M
oC�I'a-oav
va W«
sav-
Signature: - � Date:
Notes:
1. Electronic equipment calibrated aocording to the manufacturer's operation manual,
2. Speck Conductivity should be calibrated according to values representative of historic range.
3. Order of Calibration is as follows: Specific Conductivity, pH 7, pH 4, pH 10, DO, ORP, CIC checks.
4. QC Acceptable Ranges: PH +/- 0.1 S.U. and Spedf c Conductivity 10% of the true value. If C1C readings are out of range, the instrument needs to be recalibrated.
S. • Indicates that a QC check must be performed in the moming, afternoon, and the end of the day, or every four hours.
6. " Indicates to choose a Specific Conductivity buffer of 1413, 447, 84, or 23 mS which is closest to historical readings from the project location.
Method Reference: Temperature: SM 2550 B-2010 I Specific conductivity. EPA Method 120 r, Rev. 79W 1 DO: SM 45000 G-2017 I PH: SM 4500-H+ B-2011
Page 1 of 1

Appendix B
Report of Laboratory Analysis and
Chain -of -Custody Documentation

TestAmerica °
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-161987-1
Client Project/Site: Madison Co Closed Landfill MW
Foi
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by.
1112912018 6:31:01 PM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.

Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Table of Contents
TestAmerica Job ID: 490-161987-1
CoverPage ..............................................
1
Table of Contents .........................................
2
Sample Summary .........................................
3
Case Narrative ...........................................
4
Definitions...............................................
5
Client Sample Results ......................................
6
QC Sample Results ........................................
18
QC Association ...........................................
27
Chronicle ................................................
29
Method Summary .........................................
31
Certification Summary ......................................
32
Chain of Custody ..........................................
33
Receipt Checklists .........................................
37
TestAmerica Nashville
Page 2 of 37 11 /29/2018

Sample Summary
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site:
Madison Co Closed Landfill MW
Lab Sample ID
Client Sample ID
Matrix
Collected
Received
490-161987-1
MW-01 OLD
Water
10/26/18 09:48
10/26/18 10:00
490-161987-2
MW-02 OLD
Water
10/25/18 12:49
10/26/18 10:00
490-161987-3
MW-03 OLD
Water
10/25/18 11:24
10/26/18 10:00
490-161987-4
MW-04 OLD
Water
10/25/18 12:16
10/26/18 10:00
490-161987-5
BG SPRING OLD
Water
10/25/18 13:30
10/26/18 10:00
490-161987-6
Trip Blank
Water
10/25/18 01:01
10/26/18 10:00
TestAmerica Nashville
Page 3 of 37 11 /29/2018

Case Narrative C
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Job ID: 490-161987-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-161987-1
Comments
No additional comments.
Receipt
The samples were received on 10/26/2018 10:00 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 0.81 C.
Receipt Exceptions
The following Trip Blank sample was received with headspace in 1 of 4 vials: Trip Blank (490-161987-6).
GC/MS VOA
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
Metals
Method 601 OD: High Internal standard due to low volume in tube: (CCB 490-557822/100) F
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica Nashville
Page 4 of 37 11 /29/2018

Definitions/Glossary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Qualifiers
GC/MS VOA
Qualifier Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Metals
Qualifier Qualifier Description
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
F1 MS and/or MSD Recovery is outside acceptance limits.
4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not
applicable.
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Nashville
Page 5 of 37 11 /29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: MW-01 OLD
Lab Sample ID: 490-161987-1
Date Collected: 10/26/18 09:48
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
4.56
1.00
0.254
ug/L
10/30/1816:18
1
•
Surrogate %Recovery
Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10130118 16:18
1
4-Bromofluorobenzene (Surr)
102
70 - 130
10130118 16:18
1
Dibromofluoromethane (Surr)
102
70 - 130
10130118 16:18
1
Toluene-d8 (Surr)
99
70 - 130
10130118 16:18
1
Method: 8260B - Volatile Organic Compounds
(GC/MS)
C
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 07:38
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 07:38
1
Benzene
0.548
J
1.00
0.200
ug/L
10/27/18 07:38
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 07:38
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 07:38
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 07:38
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 07:38
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 07:38
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 07:38
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 07:38
1
Chlorobenzene
2.92
1.00
0.180
ug/L
10/27/18 07:38
1
Chloroethane
1.40
1.00
0.360
ug/L
10/27/18 07:38
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 07:38
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 07:38
1
cis-1,2-Dichloroethene
4.26
1.00
0.210
ug/L
10/27/18 07:38
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 07:38
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 07:38
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 07:38
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 07:38
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 07:38
1
1,2-Dichlorobenzene
0.339
J
1.00
0.190
ug/L
10/27/18 07:38
1
1,4-Dichlorobenzene
4.33
1.00
0.170
ug/L
10/27/18 07:38
1
1,1-Dichloroethane
1.01
1.00
0.240
ug/L
10/27/18 07:38
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 07:38
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 07:38
1
1,2-Dichloropropane
0.354
J
1.00
0.250
ug/L
10/27/18 07:38
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 07:38
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 07:38
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 07:38
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 07:38
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 07:38
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 07:38
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 07:38
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 07:38
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 07:38
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 07:38
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 07:38
1
trans-1,2-Dichloroethene
0.342
J
1.00
0.230
ug/L
10/27/18 07:38
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 07:38
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 07:38
1
TestAmerica Nashville
Page 6 of 37 11 /29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-01 OLD Lab Sample ID: 490-161987-1
Date Collected: 10/26/18 09:48 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 07:38
1
Trichloroethene
0.529
J
1.00
0.200
ug/L
10/27/18 07:38
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/27/18 07:38
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/27/18 07:38
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/27/18 07:38
1
Vinyl chloride
0.995
J
1.00
0.180
ug/L
10/27/18 07:38
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/27/18 07:38
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
88
70 - 130
10127118 07:38
1
Dibromofluoromethane (Surr)
103
70 - 130
10127118 07:38
1
1,2-Dichloroethane-d4 (Surr)
99
70- 130
10127118 07:38
1
Toluene-d8 (Surr)
97
70- 130
10127118 07:38
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Silver
<0.00300
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1821:09
1
Arsenic
<0.00860
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1821:09
1
Barium
0.438
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1821:09
1
Cadmium
<0.000500
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1821:09
1
Chromium
0.00410
J
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1821:09
1
Lead
0.00210
J
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1821:09
1
Selenium
0.0154
0.0100
0.00500
mg/L
11/13/18 13:27
11/15/18 21:09
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/05/1811:03
11/06/1814:38
1
TestAmerica Nashville
Page 7 of 37 11 /29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: MW-02 OLD
Lab Sample ID: 490-161987-2
Date Collected: 10/25/18 12:49
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
0.443 J
1.00
0.254
ug/L
10/30/1816:46
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10130118 16:46
1
4-Bromofluorobenzene (Surr)
102
70 - 130
10130118 16:46
1
Dibromofluoromethane (Surr)
100
70 - 130
10130118 16:46
1
Toluene-d8 (Surr)
99
70 - 130
10130118 16:46
1
Method: 8260B - Volatile Organic Compounds
(GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 08:04
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 08:04
1
Benzene
<0.200
1.00
0.200
ug/L
10/27/18 08:04
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 08:04
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 08:04
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 08:04
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 08:04
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 08:04
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 08:04
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 08:04
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/27/18 08:04
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/27/18 08:04
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 08:04
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 08:04
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 08:04
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:04
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 08:04
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 08:04
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 08:04
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 08:04
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:04
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/27/18 08:04
1
1,1-Dichloroethane
0.823 J
1.00
0.240
ug/L
10/27/18 08:04
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 08:04
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 08:04
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 08:04
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:04
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 08:04
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 08:04
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 08:04
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 08:04
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 08:04
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 08:04
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:04
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 08:04
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 08:04
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 08:04
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 08:04
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:04
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:04
1
TestAmerica Nashville
Page 8 of 37 11 /29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-02 OLD Lab Sample ID: 490-161987-2
Date Collected: 10/25/18 12:49 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result Qualifier
RL
MDL
Unit D
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
Trichloroethene
<0.200
1.00
0.200
ug/L
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
Vinyl acetate
<1.71
10.0
1.71
ug/L
Vinyl chloride
<0.180
1.00
0.180
ug/L
Xylenes, Total
<0.580
3.00
0.580
ug/L
Surrogate
4-Bromofluorobenzene (Surr)
Dibromofluoromethane (Surr)
1,2-Dichloroethane-d4 (Surr)
Toluene-d8 (Surr)
Method: 6010D - Metals (ICP)
Analyte
Silver
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Prepared Analyzed
Dil Fac
10/27/18 08:04
1
10/27/18 08:04
1
10/27/18 08:04
1
10/27/18 08:04
1
10/27/18 08:04
1
10/27/18 08:04
1
10/27/18 08:04
1
0
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
88
70 - 130
10127118 08:04
1
104
70 - 130
10127118 08:04
1
100
70 - 130
10127118 08:04
1
95
70 - 130
10127118 08:04
1
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
<0.00300
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1821:14
1
<0.00860
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1821:14
1
0.0627
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1821:14
1
<0.000500
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1821:14
1
0.00300
J
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1821:14
1
0.00300
J
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1821:14
1
<0.00500
0.0100
0.00500
mg/L
11/13/18 13:27
11/15/18 21:14
1
Method: 7470A - Mercury (CVAA)
Analyte
Mercury
Result Qualifier RL MDL Unit D Prepared Analyzed Dil Fac
0.0800 J 0.200 0.0700 ug/L 11/05/1811:03 11/06/1814:40 1
TestAmerica Nashville
Page 9 of 37 11 /29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: MW-03 OLD
Lab Sample ID: 490-161987-3
Date Collected: 10/25/18 11:24
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
<0.254
1.00
0.254
ug/L
10/30/1815:51
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10130118 15:51
1
4-Bromofluorobenzene (Surr)
103
70 - 130
10130118 15:51
1
Dibromofluoromethane (Surr)
102
70 - 130
10130118 15:51
1
Toluene-d8 (Surr)
99
70 - 130
10130118 15:51
1
Method: 8260B - Volatile Organic Compounds
(GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 08:29
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 08:29
1
Benzene
1.20
1.00
0.200
ug/L
10/27/18 08:29
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 08:29
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 08:29
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 08:29
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 08:29
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 08:29
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 08:29
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 08:29
1
Chlorobenzene
5.26
1.00
0.180
ug/L
10/27/18 08:29
1
Chloroethane
0.651 J
1.00
0.360
ug/L
10/27/18 08:29
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 08:29
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 08:29
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 08:29
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:29
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 08:29
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 08:29
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 08:29
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 08:29
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:29
1
1,4-Dichlorobenzene
2.31
1.00
0.170
ug/L
10/27/18 08:29
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/27/18 08:29
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 08:29
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 08:29
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 08:29
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:29
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 08:29
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 08:29
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 08:29
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 08:29
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 08:29
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 08:29
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:29
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 08:29
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 08:29
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 08:29
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 08:29
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:29
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:29
1
TestAmerica Nashville
Page 10 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-03 OLD Lab Sample ID: 490-161987-3
Date Collected: 10/25/18 11:24 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:29
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/27/18 08:29
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/27/18 08:29
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/27/18 08:29
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/27/18 08:29
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/27/18 08:29
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/27/18 08:29
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
89
70 - 130
10127118 08:29
1
Dibromofluoromethane (Surr)
104
70 - 130
10127118 08:29
1
1,2-Dichloroethane-d4 (Surr)
99
70- 130
10127118 08:29
1
Toluene-d8 (Surr)
97
70- 130
10127118 08:29
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Silver
<0.00300
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:53
1
Arsenic
<0.00860
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1820:53
1
Barium
0.956
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1820:53
1
Cadmium
<0.000500
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1820:53
1
Chromium
0.00360
J
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:53
1
Lead
<0.00200
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1820:53
1
Selenium
0.0119
0.0100
0.00500
mg/L
11/13/18 13:27
11/15/18 20:53
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/05/1811:03
11/06/1814:42
1
TestAmerica Nashville
Page 11 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: MW-04 OLD
Lab Sample ID: 490-161987-4
Date Collected: 10/25/18 12:16
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
0.488
J
1.00
0.254
ug/L
10/30/1817:13
1
•
Surrogate %Recovery
Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10130118 17:13
1
4-Bromofluorobenzene (Surr)
103
70 - 130
10130118 17:13
1
Dibromofluoromethane (Surr)
100
70 - 130
10130118 17:13
1
Toluene-d8 (Surr)
99
70 - 130
10130118 17:13
1
Method: 8260B - Volatile Organic Compounds
(GC/MS)
C
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 08:55
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 08:55
1
Benzene
<0.200
1.00
0.200
ug/L
10/27/18 08:55
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 08:55
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 08:55
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 08:55
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 08:55
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 08:55
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 08:55
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 08:55
1
Chlorobenzene
3.31
1.00
0.180
ug/L
10/27/18 08:55
1
Chloroethane
0.733
J
1.00
0.360
ug/L
10/27/18 08:55
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 08:55
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 08:55
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 08:55
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:55
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 08:55
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 08:55
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 08:55
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 08:55
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:55
1
1,4-Dichlorobenzene
1.12
1.00
0.170
ug/L
10/27/18 08:55
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/27/18 08:55
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 08:55
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 08:55
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 08:55
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 08:55
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 08:55
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 08:55
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 08:55
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 08:55
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 08:55
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 08:55
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:55
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 08:55
1
Toluene
0.449
J
1.00
0.170
ug/L
10/27/18 08:55
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 08:55
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 08:55
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 08:55
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:55
1
TestAmerica Nashville
Page 12 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-04 OLD Lab Sample ID: 490-161987-4
Date Collected: 10/25/18 12:16 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 08:55
1 w
Trichloroethene
<0.200
1.00
0.200
ug/L
10/27/18 08:55
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/27/18 08:55
1 Y
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/27/18 08:55
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/27/18 08:55
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/27/18 08:55
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/27/18 08:55
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
88
70 - 130
10127118 08:55
1
Dibromofluoromethane (Surr)
105
70 - 130
10127118 08:55
1
1,2-Dichloroethane-d4 (Surr)
98
70- 130
10127118 08:55
1
Toluene-d8 (Surr)
96
70 - 130
10127118 08:55
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Silver
<0.00300
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:48
1
Arsenic
<0.00860
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1820:48
1
Barium
0.691
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1820:48
1
Cadmium
<0.000500
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1820:48
1
Chromium
0.00500
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:48
1
Lead
0.00450
J
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1820:48
1
Selenium
0.0151
0.0100
0.00500
mg/L
11/13/18 13:27
11/15/18 20:48
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/05/1811:03
11/06/1814:44
1
TestAmerica Nashville
Page 13 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: BG SPRING
OLD
Lab Sample ID: 490-161987-5
Date Collected: 10/25/18 13:30
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
<0.254
1.00
0.254
ug/L
10/30/1817:41
1
•
Surrogate
%Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
105
70- 130
10130118 17:41
1
4-Bromofluorobenzene (Surr)
103
70 - 130
10130118 17:41
1
Dibromofluoromethane (Surr)
101
70 - 130
10130118 17:41
1
Toluene-d8 (Surr)
99
70 - 130
10130118 17:41
1
Method: 8260B - Volatile Organic Compounds (GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 09:20
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 09:20
1
Benzene
<0.200
1.00
0.200
ug/L
10/27/18 09:20
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 09:20
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 09:20
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 09:20
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 09:20
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 09:20
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 09:20
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 09:20
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/27/18 09:20
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/27/18 09:20
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 09:20
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 09:20
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 09:20
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 09:20
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 09:20
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 09:20
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 09:20
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 09:20
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 09:20
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/27/18 09:20
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/27/18 09:20
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 09:20
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 09:20
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 09:20
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 09:20
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 09:20
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 09:20
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 09:20
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 09:20
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 09:20
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 09:20
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 09:20
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 09:20
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 09:20
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 09:20
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 09:20
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 09:20
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 09:20
1
TestAmerica Nashville
Page 14 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: BG SPRING OLD Lab Sample ID: 490-161987-5
Date Collected: 10/25/18 13:30 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 09:20
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/27/18 09:20
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/27/18 09:20
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/27/18 09:20
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/27/18 09:20
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/27/18 09:20
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/27/18 09:20
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
89
70 - 130
10127118 09:20
1
Dibromofluoromethane (Surr)
105
70 - 130
10127118 09:20
1
1,2-Dichloroethane-d4 (Surr)
99
70- 130
10127118 09:20
1
Toluene-d8 (Surr)
96
70 - 130
10127118 09:20
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Silver
<0.00300
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:10
1
Arsenic
<0.00860
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1820:10
1
Barium
0.203
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1820:10
1
Cadmium
<0.000500
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1820:10
1
Chromium
0.0113
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1820:10
1
Lead
0.00450
J
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1820:10
1
Selenium
0.00550
J
0.0100
0.00500
mg/L
11/13/18 13:27
11/15/18 20:10
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/05/1811:03
11/06/1814:46
1
TestAmerica Nashville
Page 15 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: Trip Blank
Lab Sample ID: 490-161987-6
Date Collected: 10/25/18 01:01
Matrix:
Water
Date Received: 10/26/18 10:00
Method: 8260B SIM - Volatile Organic
Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
<0.254
1.00
0.254
ug/L
10/30/1815:23
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10130118 15:23
1
4-Bromofluorobenzene (Surr)
103
70 - 130
10130118 15:23
1
Dibromofluoromethane (Surr)
101
70 - 130
10130118 15:23
1
Toluene-d8 (Surr)
99
70 - 130
10130118 15:23
1
Method: 8260B - Volatile Organic Compounds (GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
21.2 J
25.0
2.66
ug/L
10/27/18 01:40
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 01:40
1
Benzene
<0.200
1.00
0.200
ug/L
10/27/18 01:40
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 01:40
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 01:40
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 01:40
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 01:40
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 01:40
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 01:40
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 01:40
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/27/18 01:40
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/27/18 01:40
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 01:40
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 01:40
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 01:40
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 01:40
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 01:40
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 01:40
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 01:40
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 01:40
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 01:40
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/27/18 01:40
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/27/18 01:40
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 01:40
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 01:40
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 01:40
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 01:40
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 01:40
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 01:40
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 01:40
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 01:40
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 01:40
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 01:40
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 01:40
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 01:40
1
Tetrahydrofuran
<0.820
10.0
0.820
ug/L
10/27/18 01:40
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 01:40
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 01:40
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 01:40
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 01:40
1
TestAmerica Nashville
Page 16 of 37 11/29/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Client Sample ID: Trip Blank Lab Sample ID: 490-161987-6
Date Collected: 10/25/18 01:01 Matrix: Water
Date Received: 10/26/18 10:00
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result Qualifier
RL
MDL
Unit D
1, 1, 1 -Trichloroethane
<0.190
1.00
0.190
ug/L
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
Trichloroethene
<0.200
1.00
0.200
ug/L
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
Vinyl acetate
<1.71
10.0
1.71
ug/L
Vinyl chloride
<0.180
1.00
0.180
ug/L
Xylenes, Total
<0.580
3.00
0.580
ug/L
1,4-Dioxane
<72.0
200
72.0
ug/L
Surrogate %Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 88 70 - 130
Dibromofluoromethane (Surr) 102 70 - 130
1,2-Dichloroethane-d4 (Surr) 99 70- 130
Toluene-d8 (Surr) 95 70 - 130
Prepared Analyzed
Dil Fac
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
10/27/18 01:40
1
Prepared Analyzed
Dil Fac
10127118 01:40
1
10127118 01:40
1
10127118 01:40
1
10127118 01:40
1
TestAmerica Nashville
Page 17 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Method: 8260B - Volatile Organic Compounds (GC/MS)
Lab Sample ID: MB 490-553151/6
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553151
MB MB
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/27/18 01:14
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/27/18 01:14
1
Benzene
<0.200
1.00
0.200
ug/L
10/27/18 01:14
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/27/18 01:14
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/27/18 01:14
1
Bromoform
<0.290
1.00
0.290
ug/L
10/27/18 01:14
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/27/18 01:14
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/27/18 01:14
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/27/18 01:14
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/27/18 01:14
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/27/18 01:14
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/27/18 01:14
1
Chloroform
<0.230
1.00
0.230
ug/L
10/27/18 01:14
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/27/18 01:14
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/27/18 01:14
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 01:14
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/27/18 01:14
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/27/18 01:14
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/27/18 01:14
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/27/18 01:14
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/27/18 01:14
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/27/18 01:14
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/27/18 01:14
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/27/18 01:14
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/27/18 01:14
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/27/18 01:14
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/27/18 01:14
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/27/18 01:14
1
lodomethane
<1.50
10.0
1.50
ug/L
10/27/18 01:14
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/27/18 01:14
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/27/18 01:14
1
Styrene
<0.280
1.00
0.280
ug/L
10/27/18 01:14
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/27/18 01:14
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/27/18 01:14
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/27/18 01:14
1
Tetrahydrofuran
<0.820
10.0
0.820
ug/L
10/27/18 01:14
1
Toluene
<0.170
1.00
0.170
ug/L
10/27/18 01:14
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/27/18 01:14
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/27/18 01:14
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/27/18 01:14
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 01:14
1
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/27/18 01:14
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/27/18 01:14
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/27/18 01:14
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/27/18 01:14
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/27/18 01:14
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/27/18 01:14
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/27/18 01:14
1
TestAmerica Nashville
Page 18 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: MB 490-55315116
Matrix: Water
Analysis Batch: 553151
MB MB
Analyte Result Qualifier RL MDL Unit
1,4-Dioxane <72.0 200 72.0 ug/L
MB MB
F
TestAmerica Job ID: 490-161987-1
Client Sample ID: Method Blank
Prep Type: Total/NA
D Prepared Analyzed Dil Fac
10/27/18 01:14 1
Surrogate
%Recovery Qualifier
Limits
Prepared Analyzed
4-Bromofluorobenzene (Surr)
89
70 - 130
10127118 01:14
Dibromofluoromethane (Surr)
102
70 - 130
10127118 01:14
1,2-Dichloroethane-d4 (Surr)
99
70- 130
10127118 01:14
Toluene-d8 (Surr)
93
70 - 130
10127118 01:14
Lab Sample ID: LCS 490-553151/3
Matrix: Water
Analysis Batch: 553151
Analyte
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
1,1-Dichloroethane
1,2-Dichloroethane
1,1-Dichloroethene
1,2-Dichloropropane
Ethylbenzene
2-Hexanone
lodomethane
Methylene Chloride
4-Methyl-2-pentanone (MIBK)
Styrene
1,1,1,2-Tetrachloroethane
1,1,2,2-Tetrachloroethane
Tetrachloroethene
Dil Fac 9
1
1
1
1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Spike
Added
LCS LCS
Result Qualifier
Unit
D %Rec
%Rec.
Limits
100
119.1
ug/L
119
39 -150
200
224.8
ug/L
112
63-135
20.0
21.96
ug/L
110
70 -130
20.0
21.98
ug/L
110
70 -130
20.0
20.89
ug/L
104
70 -130
20.0
21.80
ug/L
109
70 -137
20.0
17.98
ug/L
90
53-150
100
110.6
ug/L
ill
55-143
20.0
18.99
ug/L
95
64 -135
20.0
21.10
ug/L
106
70 -147
20.0
17.54
ug/L
88
70 -130
20.0
21.78
ug/L
109
60 -138
20.0
19.83
ug/L
99
70 -130
20.0
23.86
ug/L
119
33 -150
20.0
22.27
ug/L
111
70 -130
20.0
19.26
ug/L
96
70 -133
20.0
19.44
ug/L
97
70 -133
20.0
19.22
ug/L
96
45 -138
20.0
18.14
ug/L
91
70 -130
20.0
20.19
ug/L
101
70 -130
20.0
15.64
ug/L
78
70 -130
20.0
15.40
ug/L
77
70 -130
20.0
20.24
ug/L
101
70 -130
20.0
21.37
ug/L
107
70 -130
20.0
21.13
ug/L
106
70 -132
20.0
20.41
ug/L
102
70 -130
20.0
17.19
ug/L
86
70 -130
100
105.4
ug/L
105
54 -142
20.0
20.61
ug/L
103
40 -150
20.0
21.26
ug/L
106
70 -130
100
107.9
ug/L
108
60 -137
20.0
17.46
ug/L
87
70 -130
20.0
19.35
ug/L
97
70 -130
20.0
17.89
ug/L
89
69 -131
20.0
18.39
ug/L
92
70 -130
TestAmerica Nashville
Page 19 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: LCS 490-553151/3
Matrix: Water
Analysis Batch: 553151
TestAmerica Job ID: 490-161987-1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Analyte
Spike
Added
LCS LCS
Result Qualifier
Unit
D %Rec
%Rec.
Limits
Tetrahydrofuran
40.0
42.66
ug/L
107
51 -136
Toluene
20.0
17.64
ug/L
88
70 -130
trans- 1,4-Dichloro-2-butene
20.0
17.72
ug/L
89
41-150
trans- 1,2-Dichloroethene
20.0
18.94
ug/L
95
70-130
trans- 1,3-Dichloropropene
20.0
18.75
ug/L
94
63-142
1,1,1-Trichloroethane
20.0
20.10
ug/L
100
70-135
1,1,2-Trichloroethane
20.0
19.32
ug/L
97
70-130
Trichloroethene
20.0
21.47
ug/L
107
70 -130
Trichlorofluoromethane
20.0
21.45
ug/L
107
59 -150
1,2,3-Trichloropropane
20.0
16.79
ug/L
84
70-131
Vinyl acetate
40.0
44.35
ug/L
111
54 -146
Vinyl chloride
20.0
21.01
ug/L
105
57 -137
Xylenes, Total
40.0
33.85
ug/L
85
70 -132
1,4-Dioxane
400
421.1
ug/L
105
18 -150
LCS LCS
Surrogate
%Recovery Qualifier
Limits
4-Bromofluorobenzene (Surr)
90
70 - 130
Dibromofluoromethane (Surr)
102
70 - 130
1,2-Dichloroethane-d4 (Surr)
95
70- 130
Toluene-d8 (Surr)
96
70 - 130
Lab Sample ID: LCSD 490-553151/4
Matrix: Water
Analysis Batch: 553151
Analyte
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Bromoform
Bromomethane
2-Butanone (MEK)
Carbon disulfide
Carbon tetrachloride
Chlorobenzene
Chloroethane
Chloroform
Chloromethane
cis-1,2-Dichloroethene
cis-1,3-Dichloropropene
Dibromochloromethane
1,2-Dibromo-3-Chloropropane
1,2-Dibromoethane (EDB)
Dibromomethane
1,2-Dichlorobenzene
1,4-Dichlorobenzene
Client Sample ID: Lab Control Sample Dup
Prep Type: Total/NA
Spike
Added
LCSD LCSD
Result Qualifier
Unit
D %Rec
%Rec.
Limits
RPD
RPD
Limit
100
126.7
ug/L
127
39 -150
6
23
200
228.3
ug/L
114
63 -135
2
16
20.0
21.80
ug/L
109
70 -130
1
12
20.0
21.19
ug/L
106
70 -130
4
16
20.0
20.83
ug/L
104
70 -130
0
14
20.0
21.41
ug/L
107
70 -137
2
14
20.0
16.81
ug/L
84
53 -150
7
19
100
118.0
ug/L
118
55 -143
6
19
20.0
19.14
ug/L
96
64 -135
1
16
20.0
21.52
ug/L
108
70 -147
2
16
20.0
17.36
ug/L
87
70 -130
1
12
20.0
20.21
ug/L
101
60 -138
7
15
20.0
19.57
ug/L
98
70 -130
1
14
20.0
23.06
ug/L
115
33 -150
3
20
20.0
22.01
ug/L
110
70 -130
1
15
20.0
18.64
ug/L
93
70 -133
3
15
20.0
19.19
ug/L
96
70 -133
1
13
20.0
19.62
ug/L
98
45 -138
2
19
20.0
18.25
ug/L
91
70 -130
1
13
20.0
20.23
ug/L
101
70 -130
0
14
20.0
15.74
ug/L
79
70 -130
1
12
20.0
15.62
ug/L
78
70 -130
1
12
TestAmerica Nashville
Page 20 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: LCSD 490-553151/4 Client Sample ID: Lab Control Sample Dup
Matrix: Water Prep Type: Total/NA
Analysis Batch: 553151
Spike LCSD LCSD %Rec. RPD
Analyte Added Result Qualifier Unit D %Rec Limits RPD Limit
1,1-Dichloroethane
20.0
19.93
ug/L
100
70-130
2
17
1,2-Dichloroethane
20.0
21.38
ug/L
107
70 -130
0
13
1,1-Dichloroethene
20.0
21.03
ug/L
105
70-132
0
20
1,2-Dichloropropane
20.0
19.90
ug/L
100
70 -130
3
15
Ethylbenzene
20.0
16.83
ug/L
84
70 -130
2
12
2-Hexanone
100
106.0
ug/L
106
54-142
1
17
lodomethane
20.0
20.04
ug/L
100
40 -150
3
20
Methylene Chloride
20.0
21.17
ug/L
106
70 -130
0
15
4-Methyl-2-pentanone (MIBK)
100
108.6
ug/L
109
60-137
1
21
Styrene
20.0
17.33
ug/L
87
70 -130
1
12
1,1,1,2-Tetrachloroethane
20.0
18.88
ug/L
94
70-130
2
13
1,1,2,2-Tetrachloroethane
20.0
17.59
ug/L
88
69-131
2
15
Tetrachloroethene
20.0
18.05
ug/L
90
70 -130
2
17
Tetrahydrofuran
40.0
46.11
ug/L
115
51 -136
8
20
Toluene
20.0
17.49
ug/L
87
70 -130
1
13
trans- 1,4-Dichloro-2-butene
20.0
17.52
ug/L
88
41-150
1
20
trans- 1,2-Dichloroethene
20.0
18.68
ug/L
93
70-130
1
15
trans- 1,3-Dichloropropene
20.0
18.94
ug/L
95
63 -142
1
13
1,1,1-Trichloroethane
20.0
20.11
ug/L
101
70-135
0
15
1,1,2-Trichloroethane
20.0
18.67
ug/L
93
70-130
3
13
Trichloroethene
20.0
21.23
ug/L
106
70 -130
1
14
Trichlorofluoromethane
20.0
21.32
ug/L
107
59 -150
1
22
1,2,3-Trichloropropane
20.0
17.06
ug/L
85
70-131
2
14
Vinyl acetate
40.0
40.45
ug/L
101
54 -146
9
20
Vinyl chloride
20.0
21.47
ug/L
107
57 -137
2
15
Xylenes, Total
40.0
33.38
ug/L
83
70 -132
1
11
1,4-Dioxane
400
374.6
ug/L
94
18-150
12
34
LCSD LCSD
Surrogate
%Recovery Qualifier
Limits
4-Bromofluorobenzene (Surr)
91
70 - 130
Dibromofluoromethane (Surr)
102
70 - 130
1,2-Dichloroethane-d4 (Surr)
98
70- 130
Toluene-d8 (Surr)
93
70 - 130
Lab Sample ID: 490-161987-4 MS
Client Sample ID:
MW-04
OLD
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553151
Sample Sample
Spike
MS
MS
%Rec.
Analyte
Result Qualifier
Added
Result
Qualifier Unit
D %Rec
Limits
Acetone
<2.66
100
113.3
ug/L
113
39-150
Acrylonitrile
<0.500
200
224.4
ug/L
112
50 -135
Benzene
<0.200
20.0
23.04
ug/L
115
55 -147
Bromochloromethane
<0.150
20.0
21.46
ug/L
107
59 -132
Bromodichloromethane
<0.170
20.0
20.68
ug/L
103
70 -140
Bromoform
<0.290
20.0
20.62
ug/L
103
53 -150
Bromomethane
<0.350
20.0
13.42
ug/L
67
30 -150
2-Butanone (MEK)
<2.64
100
107.4
ug/L
107
50 -143
Carbon disulfide
<0.220
20.0
20.54
ug/L
103
35 -150
TestAmerica Nashville
Page 21 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161987-4 MS
Matrix: Water
Analysis Batch: 553151
Client Sample ID: MW-04 OLD
Prep Type: Total/NA
Sample
Sample
Spike
MS MS
%Rec.
Analyte
Result
Qualifier
Added
Result Qualifier
Unit
D %Rec
Limits
Carbon tetrachloride
<0.180
20.0
22.75
ug/L
114
56 -150
Chlorobenzene
3.31
20.0
20.94
ug/L
88
70 -130
Chloroethane
0.733
J
20.0
23.18
ug/L
112
58 -141
Chloroform
<0.230
20.0
20.61
ug/L
103
66 -138
Chloromethane
<0.360
20.0
24.07
ug/L
120
10 -150
cis-1,2-Dichloroethene
<0.210
20.0
22.25
ug/L
ill
68 -131
cis-1,3-Dichloropropene
<0.170
20.0
18.55
ug/L
93
70 -133
Dibromochloromethane
<0.250
20.0
19.13
ug/L
96
66 -140
1,2-Dibromo-3-Chloropropane
<0.940
20.0
18.24
ug/L
91
38-138
1,2-Dibromoethane(EDB)
<0.210
20.0
17.79
ug/L
89
65-137
Dibromomethane
<0.450
20.0
19.76
ug/L
99
70 -130
1,2-Dichlorobenzene
<0.190
20.0
15.52
ug/L
78
70 -130
1,4-Dichlorobenzene
1.12
20.0
16.34
ug/L
76
70 -130
1,1-Dichloroethane
<0.240
20.0
20.64
ug/L
103
61-139
1,2-Dichloroethane
<0.200
20.0
21.10
ug/L
106
64 -136
1,1-Dichloroethene
<0.250
20.0
22.49
ug/L
112
54-150
1,2-Dichloropropane
<0.250
20.0
20.08
ug/L
100
67 -130
Ethylbenzene
<0.190
20.0
17.56
ug/L
88
65 -139
2-Hexanone
<1.28
100
98.63
ug/L
99
44.150
lodomethane
<1.50
20.0
18.15
ug/L
91
34.150
Methylene Chloride
<1.00
20.0
20.97
ug/L
105
64.130
4-Methyl-2-pentanone (MIBK)
<0.810
100
103.7
ug/L
104
50-140
Styrene
<0.280
20.0
17.55
ug/L
88
70 -130
1,1,1,2-Tetrachloroethane
<0.150
20.0
19.30
ug/L
96
70-131
1,1,2,2-Tetrachloroethane
<0.190
20.0
17.12
ug/L
86
56-145
Tetrachloroethene
<0.140
20.0
19.03
ug/L
95
57 -138
Tetrahydrofuran
<0.820
40.0
46.25
ug/L
116
40 -136
Toluene
0.449
J
20.0
18.46
ug/L
90
64 -136
trans- 1,4-Dichloro-2-butene
<0.460
20.0
16.27
ug/L
81
39-150
trans- 1,2-Dichloroethene
<0.230
20.0
19.77
ug/L
99
59-143
trans- 1,3-Dichloropropene
<0.170
20.0
18.00
ug/L
90
63 -142
1,1,1-Trichloroethane
<0.190
20.0
21.69
ug/L
108
68-144
1,1,2-Trichloroethane
<0.190
20.0
18.59
ug/L
93
70-130
Trichloroethene
<0.200
20.0
22.05
ug/L
110
63 -135
Trichlorofluoromethane
<0.210
20.0
22.46
ug/L
112
44.150
1,2,3-Trichloropropane
<0.230
20.0
16.49
ug/L
82
65-131
Vinyl acetate
<1.71
40.0
37.87
ug/L
95
43 -146
Vinyl chloride
<0.180
20.0
23.01
ug/L
115
57 -150
Xylenes, Total
<0.580
40.0
34.58
ug/L
86
69 -132
1,4-Dioxane
<72.0
400
365.1
ug/L
91
11-150
MS
MS
Surrogate
%Recovery
Qualifier
Limits
4-Bromofluorobenzene (Surr)
89
70 - 130
Dibromofluoromethane (Surr)
101
70 - 130
1,2-Dichloroethane-d4 (Surr)
99
70- 130
Toluene-d8 (Surr)
93
70 - 130
TestAmerica Nashville
Page 22 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
TestAmerica Job ID: 490-161987-1
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161987-4
MSD
Client Sample ID:
MW-04
OLD
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553151
Sample Sample
Spike
MSD MSD
%Rec.
RPD
Analyte
Result Qualifier
Added
Result Qualifier
Unit
D %Rec
Limits
RPD
Limit
Acetone
<2.66
100
105.6
ug/L
106
39 -150
7
28
Acrylonitrile
<0.500
200
212.5
ug/L
106
50 -135
5
23
Benzene
<0.200
20.0
22.29
ug/L
111
55 -147
3
22
Bromochloromethane
<0.150
20.0
20.55
ug/L
103
59 -132
4
21
Bromodichloromethane
<0.170
20.0
20.53
ug/L
103
70 -140
1
196
Bromoform
<0.290
20.0
20.16
ug/L
101
53 -150
2
20
Bromomethane
<0.350
20.0
15.43
ug/L
77
30 -150
14
44
2-Butanone (MEK)
<2.64
100
103.2
ug/L
103
50 -143
4
28
Carbon disulfide
<0.220
20.0
19.91
ug/L
100
35 -150
3
34
Carbon tetrachloride
<0.180
20.0
22.41
ug/L
112
56 -150
2
18
Chlorobenzene
3.31
20.0
20.50
ug/L
86
70 -130
2
15
Chloroethane
0.733 J
20.0
22.11
ug/L
107
58 -141
5
31
Chloroform
<0.230
20.0
19.65
ug/L
98
66 -138
5
21
Chloromethane
<0.360
20.0
23.17
ug/L
116
10 -150
4
43
cis-1,2-Dichloroethene
<0.210
20.0
21.90
ug/L
109
68 -131
2
21
cis-1,3-Dichloropropene
<0.170
20.0
17.91
ug/L
90
70 -133
4
19
Dibromochloromethane
<0.250
20.0
18.34
ug/L
92
66 -140
4
19
1,2-Dibromo-3-Chloropropane
<0.940
20.0
17.48
ug/L
87
38-138
4
26
1,2-Dibromoethane(EDB)
<0.210
20.0
17.13
ug/L
86
65-137
4
21
Dibromomethane
<0.450
20.0
19.05
ug/L
95
70 -130
4
19
1,2-Dichlorobenzene
<0.190
20.0
15.10
ug/L
76
70 -130
3
15
1,4-Dichlorobenzene
1.12
20.0
15.81
ug/L
73
70 -130
3
14
1,1-Dichloroethane
<0.240
20.0
19.96
ug/L
100
61-139
3
23
1,2-Dichloroethane
<0.200
20.0
19.93
ug/L
100
64 -136
6
22
1,1-Dichloroethene
<0.250
20.0
21.84
ug/L
109
54-150
3
24
1,2-Dichloropropane
<0.250
20.0
19.85
ug/L
99
67 -130
1
19
Ethylbenzene
<0.190
20.0
16.99
ug/L
85
65 -139
3
18
2-Hexanone
<1.28
100
95.56
ug/L
96
44-150
3
21
lodomethane
<1.50
20.0
18.89
ug/L
94
34 -150
4
37
Methylene Chloride
<1.00
20.0
20.77
ug/L
104
64 -130
1
22
4-Methyl-2-pentanone (MIBK)
<0.810
100
102.5
ug/L
102
50-140
1
24
Styrene
<0.280
20.0
16.80
ug/L
84
70 -130
4
16
1,1,1,2-Tetrachloroethane
<0.150
20.0
18.35
ug/L
92
70-131
5
16
1,1,2,2-Tetrachloroethane
<0.190
20.0
16.55
ug/L
83
56-145
3
19
Tetrachloroethene
<0.140
20.0
18.49
ug/L
92
57 -138
3
17
Tetrahydrofuran
<0.820
40.0
44.49
ug/L
111
40 -136
4
27
Toluene
0.449 J
20.0
17.96
ug/L
88
64 -136
3
18
trans- 1,4-Dichloro-2-butene
<0.460
20.0
15.02
ug/L
75
39-150
8
28
trans- 1,2-Dichloroethene
<0.230
20.0
18.92
ug/L
95
59-143
4
25
trans- 1,3-Dichloropropene
<0.170
20.0
17.49
ug/L
87
63-142
3
18
1,1,1-Trichloroethane
<0.190
20.0
21.46
ug/L
107
68-144
1
17
1,1,2-Trichloroethane
<0.190
20.0
17.61
ug/L
88
70-130
5
18
Trichloroethene
<0.200
20.0
21.86
ug/L
109
63 -135
1
17
Trichlorofluoromethane
<0.210
20.0
23.05
ug/L
115
44 -150
3
32
1,2,3-Trichloropropane
<0.230
20.0
15.72
ug/L
79
65-131
5
19
Vinyl acetate
<1.71
40.0
35.19
ug/L
88
43 -146
7
20
Vinyl chloride
<0.180
20.0
22.45
ug/L
112
57.150
2
37
Xylenes, Total
<0.580
40.0
33.28
ug/L
83
69 -132
4
17
TestAmerica Nashville
Page 23 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161987-4 MSD
Matrix: Water
Analysis Batch: 553151
Sample Sample Spike MSD MSD
Analyte Result Qualifier Added Result Qualifier Unit
1,4-Dioxane <72.0 400 376.2 ug/L
MSD MSD
Surrogate %Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 90 70 - 130
Dibromofluoromethane (Surr) 103 70 - 130
1,2-Dichloroethane-d4 (Surr) 96 70- 130
Toluene-d8 (Surr) 95 70 - 130
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Lab Sample ID: MB 490-553750/8
Matrix: Water
Analysis Batch: 553750
MB MB
Analyte Result Qualifier RL
1,4-Dioxane <0.254 1.00
MB MB
Surrogate %Recovery Qualifier
Limits
1,2-Dichloroethane-d4 (Surr)
104
70- 130
4-Bromofluorobenzene (Surr)
103
70 - 130
Dibromofluoromethane (Surr)
101
70 - 130
Toluene-d8 (Surr)
99
70 - 130
Lab Sample ID: LCS 490-553750/4
Matrix: Water
Analysis Batch: 553750
LCS
LCS
Surrogate %Recovery Qualifier Limits
1,2-Dichloroethane-d4 (Surr) 100 70- 130
4-Bromofluorobenzene (Surr) 100 70 - 130
Dibromofluoromethane (Surr) 100 70 - 130
Toluene-d8 (Surr) 99 70 - 130
Lab Sample ID: LCSD 490-553750/5
Matrix: Water
Analysis Batch: 553750
LCSD LCSD
Surrogate %Recovery Qualifier
1,2-Dichloroethane-d4 (Surr) 100
4-Bromofluorobenzene (Surr) 101
Dibromofluoromethane (Surr) 99
Toluene-d8 (Surr) 100
Limits
70-130
70-130
70-130
70-130
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-04 OLD
Prep Type: Total/NA
%Rec. RPD C
D %Rec Limits RPD Limit
94 11-150 3 50
Client Sample ID: Method Blank
Prep Type: Total/NA
MDL Unit D Prepared Analyzed
Dil Fac
0.254 ug/L 10/30/1814:56
1
Prepared Analyzed
Dil Fac
10130118 14:56
1
10130118 14:56
1
10130118 14:56
1
10130118 14:56
1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Client Sample ID: Lab Control Sample Dup
Prep Type: Total/NA
TestAmerica Nashville
Page 24 of 37 11/29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Method: 8260B SIM - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161987-3 MS
Matrix: Water
Analysis Batch: 553750
MS MS
Surrogate %Recovery Qualifier Limits
1,2-Dichloroethane-d4 (Surr) 101 70- 130
4-Bromofluorobenzene (Surr) 99 70 - 130
Dibromofluoromethane (Surr) 101 70 - 130
Toluene-d8 (Surr) 99 70 - 130
Lab Sample ID: 490-161987-3 MSD
Matrix: Water
Analysis Batch: 553750
MSD MSD
Surrogate %Recovery Qualifier Limits
1,2-Dichloroethane-d4 (Surr) 102 70- 130
4-Bromofluorobenzene (Surr) 101 70 - 130
Dibromofluoromethane (Surr) 100 70 - 130
Toluene-d8 (Surr) 99 70 - 130
Method: 6010D - Metals (ICP)
Lab Sample ID: MB 490-557067/1-A
Matrix: Water
Analysis Batch: 557822
MB MB
Analyte Result Qualifier
Silver <0.0 3300
Arsenic <0.00860
Barium <0.00500
Cadmium <0.000500
Chromium <0.00300
Lead <0.00200
Selenium <0.00500
Lab Sample ID: LCS 490-557067/2-A
Matrix: Water
Analysis Batch: 557822
Analyte
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Lab Sample ID: LCS 490-557067/2-A
Matrix: Water
Analysis Batch: 558908
Analyte
Silver
TestAmerica Job ID: 490-161987-1
Client Sample ID: MW-03 OLD
Prep Type: Total/NA
0
Client Sample ID: MW-03 OLD
Prep Type: Total/NA
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 557067
RL
MDL
Unit
D Prepared
Analyzed Dil Fac
0.00500
0.00300
mg1
11/13/1813:27
11/15/1819:27 1
0.0100
0.00860
mg/L
11/13/1813:27
11/15/1819:27 1
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1819:27 1
0.00100
0.000500
mg/L
11/13/1813:27
11/15/1819:27 1
0.00500
0.00300
mg/L
11/13/1813:27
11/15/1819:27 1
0.00500
0.00200
mg/L
11/13/1813:27
11/15/1819:27 1
0.0100
0.00500
mg/L
11/13/1813:27
11/15/1819:27 1
Client Sample ID:
Lab Control Sample
Prep Type: Total/NA
Prep Batch: 557067
Spike
LCS LCS
%Rec.
Added
Result Qualifier
Unit
D %Rec
Limits
0.100
0.09220
mg/L
92
80 -120
0.100
0.09520
mg/L
95
80 -120
0.100
0.09350
mg/L
94
80 -120
0.100
0.09400
mg/L
94
80 -120
0.100
0.09500
mg/L
95
80 -120
0.100
0.09580
mg/L
96
80 -120
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 557067
Spike LCS LCS %Rec.
Added Result Qualifier Unit D %Rec Limits
0.100 0.08770 mg188 80 -120
Page 25 of 37
TestAmerica Nashville
11 /29/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Lab Sample ID: 490-163075-D-2-B MS
Matrix: Water
Analysis Batch: 557822
Analyte
Silver
Arsenic
Barium
Cadmium
Chromium
Lead
Selenium
Sample Sample
Result Qualifier
<0.00300
<0.00860 F1
0.816
0.0325
0.00690
0.0173
<0.00500 F1
Lab Sample ID: 490-163075-D-2-C MSD
Matrix: Water
Analysis Batch: 557822
Analyte
Sample
Result
Sample
Qualifier
Silver
<0.00300
Arsenic
<0.00860
F1
Barium
0.816
Cadmium
0.0325
Chromium
0.00690
Lead
0.0173
Selenium
<0.00500
F1
Method: 7470A - Mercury (CVAA)
Lab Sample ID: MB 400-418329/14-A
Matrix: Water
Analysis Batch: 418545
Analyte
Mercury
Spike
Added
MS
Result
MS
Qualifier
0.100
0.07610
0.100
0.07200
F1
0.100
0.9169
4
0.100
0.1239
0.100
0.09770
0.100
0.1045
0.100
0.01350
F1
Spike
Added
MSD
Result
MSD
Qualifier
0.100
0.07650
0.100
0.07090
F1
0.100
0.9483
4
0.100
0.1240
0.100
0.09750
0.100
0.1040
0.100
0.01520
F1
MB MB
Result Qualifier RL MDL Unit
<-0 0700 0.200 0.0700 ug/L
Lab Sample ID: LCS 400-418329/15-A
Matrix: Water
Analysis Batch: 418545
Analyte
Mercury
Lab Sample ID: 490-161980-H-2-C MS
Matrix: Water
Analysis Batch: 418545
Sample Sample
Analyte Result Qualifier
Mercury <0.0700
Lab Sample ID: 490-161980-H-2-D MSD
Matrix: Water
Analysis Batch: 418545
Analyte
Mercury
Sample Sample
Result Qualifier
<0.0700
TestAmerica Job ID: 490-161987-1
Client Sample ID: Matrix Spike
Prep Type: Total/NA
Prep Batch: 557067
%Rec.
Unit
D %Rec
Limits
mg/L
76
75 -125
mg/L
72
75 -125
mg/L
101
75 -125
mg/L
91
75 -125
mg/L
91
75 -125
mg/L
87
75 -125
mg/L
14
75 -125
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Prep Batch: 557067
%Rec. RPD
Unit
D %Rec
Limits RPD Limit
mg/L
77
75 -125 1 20
mg/L
71
75 -125 2 20
mg/L
132
75 -125 3 20
mg/L
92
75 -125 0 20
mg/L
91
75 -125 0 20
mg/L
87
75 -125 0 20
mg/L
15
75 -125 12 20
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 418329
D Prepared Analyzed Dil Fac
11 /05/18 10:54 11 /06/18 13:45 1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 418329
Spike LCS LCS %Rec.
Added Result Qualifier Unit D %Rec Limits
1.01 1.096 ug/L 109 80 -120
Client Sample ID: Matrix Spike
Prep Type: Total/NA
Prep Batch: 418329
Spike MS MS %Rec.
Added Result Qualifier Unit D %Rec Limits
2.01 2.172 ug/L 108 80 -120
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Prep Batch: 418329
Spike MSD MSD %Rec. RPD
Added Result Qualifier Unit D %Rec Limits RPD Limit
2.01 2.147 ug/L 107 80 -120 1 20
TestAmerica Nashville
Page 26 of 37 11/29/2018

QC Association Summary
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
GC/MS VOA
Analysis Batch: 553151
TestAmerica Job ID: 490-161987-1
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
490-161987-1
MW-01OLD
Total/NA
Water
8260B
490-161987-2
MW-02 OLD
Total/NA
Water
8260B
490-161987-3
MW-03 OLD
Total/NA
Water
8260B
490-161987-4
MW-04 OLD
Total/NA
Water
8260B
490-161987-5
BG SPRING OLD
Total/NA
Water
8260B
490-161987-6
Trip Blank
Total/NA
Water
8260B
MB 490-553151/6
Method Blank
Total/NA
Water
8260B
LCS 490-553151/3
Lab Control Sample
Total/NA
Water
8260B
LCSD 490-553151/4
Lab Control Sample Dup
Total/NA
Water
8260B
490-161987-4 MS
MW-04 OLD
Total/NA
Water
8260B
490-161987-4 MSD
MW-04 OLD
Total/NA
Water
8260B
Analysis Batch: 553750
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
490-161987-1
MW-01 OLD
Total/NA
Water
8260B SIM
490-161987-2
MW-02 OLD
Total/NA
Water
8260B SIM
490-161987-3
MW-03 OLD
Total/NA
Water
8260B SIM
490-161987-4
MW-04 OLD
Total/NA
Water
8260B SIM
490-161987-5
BG SPRING OLD
Total/NA
Water
8260B SIM
490-161987-6
Trip Blank
Total/NA
Water
8260B SIM
MB 490-553750/8
Method Blank
Total/NA
Water
8260B SIM
LCS 490-553750/4
Lab Control Sample
Total/NA
Water
8260B SIM
LCSD 490-553750/5
Lab Control Sample Dup
Total/NA
Water
8260B SIM
490-161987-3 MS
MW-03 OLD
Total/NA
Water
8260B SIM
490-161987-3 MSD
MW-03 OLD
Total/NA
Water
8260B SIM
Metals
Prep Batch: 418329
Prep Batch
Prep Batch
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method Prep Batch
490-161987-1
MW-01 OLD
Total/NA
Water
7470A
490-161987-2
MW-02 OLD
Total/NA
Water
7470A
490-161987-3
MW-03 OLD
Total/NA
Water
7470A
490-161987-4
MW-04 OLD
Total/NA
Water
7470A
490-161987-5
BG SPRING OLD
Total/NA
Water
7470A
MB 400-418329/14-A
Method Blank
Total/NA
Water
7470A
LCS 400-418329/15-A
Lab Control Sample
Total/NA
Water
7470A
490-161980-H-2-C MS
Matrix Spike
Total/NA
Water
7470A
490-161980-H-2-D MSD
Matrix Spike Duplicate
Total/NA
Water
7470A
Analysis Batch: 418545
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161987-1
MW-01 OLD
Total/NA
Water
7470A
418329
490-161987-2
MW-02 OLD
Total/NA
Water
7470A
418329
490-161987-3
MW-03 OLD
Total/NA
Water
7470A
418329
490-161987-4
MW-04 OLD
Total/NA
Water
7470A
418329
490-161987-5
BG SPRING OLD
Total/NA
Water
7470A
418329
MB 400-418329/14-A
Method Blank
Total/NA
Water
7470A
418329
LCS 400-418329/15-A
Lab Control Sample
Total/NA
Water
7470A
418329
490-161980-H-2-C MS
Matrix Spike
Total/NA
Water
7470A
418329
0
TestAmerica Nashville
Page 27 of 37 11/29/2018

QC Association Summary
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Metals (Continued)
Analysis Batch: 418545 (Continued)
Lab Sample ID Client Sample ID
490-161980-H-2-D MSD Matrix Spike Duplicate
Prep Batch: 557067
TestAmerica Job ID: 490-161987-1
Prep Type Matrix Method Prep Batch
Total/NA Water 7470A 418329
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method Prep Batch
490-161987-1
MW-01OLD
Total/NA
Water
3010A
490-161987-2
MW-02 OLD
Total/NA
Water
3010A
490-161987-3
MW-03 OLD
Total/NA
Water
3010A
490-161987-4
MW-04 OLD
Total/NA
Water
3010A
490-161987-5
BG SPRING OLD
Total/NA
Water
3010A
MB 490-557067/1-A
Method Blank
Total/NA
Water
3010A
LCS 490-557067/2-A
Lab Control Sample
Total/NA
Water
3010A
490-163075-D-2-B MS
Matrix Spike
Total/NA
Water
3010A
490-163075-D-2-C MSD
Matrix Spike Duplicate
Total/NA
Water
3010A
Analysis Batch: 557822
0
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161987-1
MW-01OLD
Total/NA
Water
6010D
557067
490-161987-2
MW-02 OLD
Total/NA
Water
6010D
557067
490-161987-3
MW-03 OLD
Total/NA
Water
6010D
557067
490-161987-4
MW-04 OLD
Total/NA
Water
6010D
557067
490-161987-5
BG SPRING OLD
Total/NA
Water
6010D
557067
MB 490-557067/1-A
Method Blank
Total/NA
Water
6010D
557067
LCS 490-557067/2-A
Lab Control Sample
Total/NA
Water
6010D
557067
490-163075-D-2-B MS
Matrix Spike
Total/NA
Water
6010D
557067
490-163075-D-2-C MSD
Matrix Spike Duplicate
Total/NA
Water
6010D
557067
Analysis Batch: 558908
Lab Sample ID Client Sample ID
LCS 490-557067/2-A Lab Control Sample
Prep Type
Total/NA
Matrix Method Prep Batch
Water 6010D 557067
Page 28 of 37
TestAmerica Nashville
11 /29/2018

Lab Chronicle
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: MW-01 OLD
Date Collected: 10/26/18 09:48
Date Received: 10/26/18 10:00
Batch
Batch
Prep Type
Type
Method Run
Total/NA
Analysis
8260B
Total/NA
Analysis
8260B SIM
Total/NA
Prep
3010A
Total/NA
Analysis
6010D
Total/NA
Prep
7470A
Total/NA
Analysis
7470A
TestAmerica Job ID: 490-161987-1
Lab Sample ID: 490-161987-1
Matrix: Water
Dil
Initial
Final
Batch
Prepared
Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
1
10 mL
10 mL
553151
10/27/18 07:38
RP
TAL NSH
1
10 mL
10 mL
553750
10/30/18 16:18
S1S
TAL NSH
50 mL
50 mL
557067
11/13/18 13:27
MNC
TAL NSH
1
557822
11/15/18 21:09
RDH
TAL NSH
40 mL
40 mL
418329
11/05/18 11:03
JAP
TAL PEN
1
418545
11/06/18 14:38
JAP
TAL PEN
Client Sample ID: MW-02 OLD Lab Sample ID: 490-161987-2
Date Collected: 10/25/18 12:49 Matrix: Water
Date Received: 10/26/18 10:00
Batch
Batch
Prep Type
Type
Method Run
Total/NA
Analysis
8260B
Total/NA
Analysis
8260B SIM
Total/NA
Prep
3010A
Total/NA
Analysis
6010D
Total/NA
Prep
7470A
Total/NA
Analysis
7470A
Dil
Initial
Final
Batch
Prepared
Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
1
10 mL
10 mL
553151
10/27/18 08:04
RP
TAL NSH
1
10 mL
10 mL
553750
10/30/18 16:46
S1S
TAL NSH
50 mL
50 mL
557067
11/13/18 13:27
MNC
TAL NSH
1
557822
11/15/18 21:14
RDH
TAL NSH
40 mL
40 mL
418329
11/05/18 11:03
JAP
TAL PEN
1
418545
11/06/18 14:40
JAP
TAL PEN
Client Sample ID: MW-03 OLD
Lab Sample ID: 490-161987-3
Date Collected: 10/25/18 11:24
Matrix: Water
Date Received: 10/26/18 10:00
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Analysis 8260B
1
10 mL
10 mL
553151
10/27/18 08:29
RP TAL NSH
Total/NA Analysis 8260B SIM
1
10 mL
10 mL
553750
10/30/18 15:51
S1S TAL NSH
Total/NA Prep 3010A
50 mL
50 mL
557067
11/13/18 13:27
MNC TAL NSH
Total/NA Analysis 6010D
1
557822
11/15/18 20:53
RDH TAL NSH
Total/NA Prep 7470A
40 mL
40 mL
418329
11/05/18 11:03
JAP TAL PEN
Total/NA Analysis 7470A
1
418545
11/06/18 14:42
JAP TAL PEN
Client Sample ID: MW-04 OLD
Date Collected: 10/25/18 12:16
Date Received: 10/26/18 10:00
Lab Sample ID: 490-161987-4
Matrix: Water
Batch
Batch
Dil
Initial
Final
Batch
Prepared
Prep Type
Type
Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst
Lab
Total/NA
Analysis
8260B
1
10 mL
10 mL
553151
10/27/18 08:55
RP
TAL NSH
Total/NA
Analysis
8260B SIM
1
10 mL
10 mL
553750
10/30/18 17:13
S1S
TAL NSH
Total/NA
Prep
3010A
50 mL
50 mL
557067
11/13/18 13:27
MNC
TAL NSH
Total/NA
Analysis
6010D
1
557822
11/15/18 20:48
RDH
TAL NSH
Total/NA
Prep
7470A
40 mL
40 mL
418329
11/05/18 11:03
JAP
TAL PEN
Total/NA
Analysis
7470A
1
418545
11/06/18 14:44
JAP
TAL PEN
Page 29 of 37
TestAmerica Nashville
11 /29/2018

Lab Chronicle
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill MW
Client Sample ID: BG SPRING OLD
Date Collected: 10/25/18 13:30
Date Received: 10/26/18 10:00
Batch Batch
Dil
Initial
Prep Type Type Method Run
Factor
Amount
Total/NA Analysis 8260B
1
10 mL
Total/NA Analysis 8260B SIM
1
10 mL
Total/NA Prep 3010A
50 mL
Total/NA Analysis 6010D
1
Total/NA Prep 7470A
40 mL
Total/NA Analysis 7470A
1
Client Sample ID: Trip Blank
Date Collected: 10/25/18 01:01
Date Received: 10/26/18 10:00
F
TestAmerica Job ID: 490-161987-1
Lab Sample ID: 490-161987-5
Matrix: Water
Final
Batch
Prepared
Amount
Number
or Analyzed
Analyst Lab
10 mL
553151
10/27/18 09:20
RP TAL NSH
10 mL
553750
10/30/18 17:41
S1S TAL NSH
50 mL
557067
11/13/18 13:27
MNC TAL NSH
557822
11/15/18 20:10
RDH TAL NSH
40 mL
418329
11/05/18 11:03
JAP TAL PEN
418545
11/06/18 14:46
JAP TAL PEN
•
Lab
Sample ID: 490-161987-6
Matrix: Water
Prep Type
Batch Batch Dil Initial Final
Type Method Run Factor Amount Amount
Batch
Number
Prepared
or Analyzed Analyst Lab
Total/NA
Analysis 8260B 1 10 mL 16-rnL
553151
10/27/18 01:40 RP TAL NSH
Total/NA
Analysis 8260B SIM 1 10 mL 10 mL
553750
10/30/18 15:23 S1S TAL NSH
Laboratory References:
TAL NSH =
TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TAL PEN =
TestAmerica Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
Page 30 of 37
TestAmerica Nashville
11 /29/2018

Method Summary
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161987-1
Project/Site:
Madison Co Closed Landfill MW
Method
Method Description
Protocol
Laboratory
8260B
Volatile Organic Compounds (GC/MS)
SW846
TAL NSH
8260B SIM
Volatile Organic Compounds (GC/MS)
SW846
TAL NSH
6010D
Metals (ICP)
SW846
TAL NSH
7470A
Mercury (CVAA)
SW846
TAL PEN
3010A
Preparation, Total Metals
SW846
TAL NSH
5030B
Purge and Trap
SW846
TAL NSH
7470A
Preparation, Mercury
SW846
TAL PEN
Protocol References:
SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TAL PEN = TestAmerica Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
TestAmerica Nashville
Page 31 of 37 11/29/2018

Accreditation/Certification Summary C
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161987-1
Project/Site: Madison Co Closed Landfill MW
Laboratory: TestAmerica Nashville
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program
North Carolina (WW/SW) State Program
EPA Region Identification Number Expiration Date
4 387 12-31-18
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
8260B SIM Water 1,4-Dioxane
Laboratory: TestAmerica Pensacola
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
EPA Region
Identification Number
Expiration Date
Alabama
State Program
4
40150
06-30-19
ANAB
ISO/IEC 17025
L2471
02-22-20
Arizona
State Program
9
AZ0710
01-12-19
Arkansas DEQ
State Program
6
88-0689
09-01-19
California
State Program
9
2510
06-30-19
Florida
NELAP
4
E81010
06-30-19
Georgia
State Program
4
E81010 (FL)
06-30-19
Illinois
NELAP
5
200041
10-09-19
Iowa
State Program
7
367
08-01-20
Kansas
NELAP
7
E-10253
10-31-18 "
Kentucky (UST)
State Program
4
53
06-30-19
Kentucky (WW)
State Program
4
98030
12-31-18
Louisiana
NELAP
6
30976
06-30-19
Louisiana (DW)
NELAP
6
LA180023
12-31-18
Maryland
State Program
3
233
09-30-19
Massachusetts
State Program
1
M-FL094
06-30-19
Michigan
State Program
5
9912
06-30-19
New Jersey
NELAP
2
FL006
06-30-19
North Carolina (WW/SW)
State Program
4
314
12-31-18
Oklahoma
State Program
6
9810
08-31-19
Pennsylvania
NELAP
3
68-00467
01-31-19
Rhode Island
State Program
1
LAO00307
12-30-18
South Carolina
State Program
4
96026
06-30-19
Tennessee
State Program
4
TN02907
06-30-19
Texas
NELAP
6
T104704286-18-15
09-30-19
US Fish & Wildlife
Federal
LE058448-0
07-31-19
USDA
Federal
P330-18-00148
05-17-21
Virginia
NELAP
3
460166
06-14-19
Washington
State Program
10
C915
05-15-19
West Virginia DEP
State Program
3
136
06-30-19
" Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 32 of 37
TestAmerica Nashville
11 /29/2018

THE LEADER IN ENVIRONMENTAL TESTING
Nashville, TN COOLER RECEIPT FORM
490-161987 Chain of Custody
11111111111111111111111111
Cooler Received/Opened On 10126/2018 @ 10:00
9 f
Time Samples Removed From Cooler l3r Time Samples Placed In Storage �i(2 Hour Window)
1. Tracking # !'1 6 1 (last 4 digits, FedEx) Courier: FedEx
IR Gun ID 17960358 pH Strip Lot Ch�rine�..Strip Lot
J (f�J 1
2. Temperature of rep. sample or temp blank when opened: t Degrees Celsius
3. If Item #2 temperature is 0°C or less, was the representative sample or temp blank frozen?
4. Were custody seals on outside of cooler?
If yes, how many and
YES No.�9
Inn ...
NO ... NA
r
5. Were the seals intact, signed, and dated correctly?
... NO ... NA
6. Were custody papers inside cooler?
"S...NO...NA
i
Pr.
_
I certify that I opened the cooler and answered questions 1-6 (intial) rr
7. Were custody seals on containers: YES and ntact
YES...NO !.�
`
Were these signed and dated correctly? (1
YES ... N �.
8. Packing mat'I used? bblew p Plastic bag Peanuts Vermiculite Foam Insert Paper Other None
9. Cooling process: ee--�I a -pack Ice (direct contact)
Dry ice Other None
10. Did all containers arrive in good condition (unbroken)?
&..NO ... NA
11. Were all container labels complete (#, date, signed, pres., etc)?...
NO ... NA
12. Did all container labels and tags agree with custody papers?
Y ..NO ... NA
13a. Were VOA vials received?
... NO ... NA
b. Was there any observable headspace present in any VOA vial?
&PI -NO ... NA
0 00 Larger than this.
14. Was there a Trip Blank in this cooler? 40?...NO... NA If multiple coolers, sequence #
I certify that I unloaded the cooler and answered questions 7-14 (intial)
15a. On pres'd bottles, did pH test strips suggest preservation reached the correct pH level?
YES ... NO...I
b. Did the bottle labels indicate that the correct preservatives were used
NO ... NA
16. Was residual chlorine present?
YES ... NOAM"
certify that I checked for chlorine and pH as per SOP and answered questions 15-16 (intial)
17. Were custody papers properly filled out (ink, signed, etc)?
C..NO...NA
18. Did you sign the custody papers in the appropriate place?
1
... NO ... NA 1
19. Were correct containers used for the analysis requested?
&...NO...NA
20. Was sufficient amount of sample sent in each container?
...NO ... NA
I certify that I entered this protect into LIMS and answered questions 17-20 intial
certify that I attached a label with the unique LIM`S,nnuumber to each container intial
21. Were there Non -Conformance issues at login/YE _NO Was a NCM generated ...NO...#
t�
i
BIS = Broken in shipment
Cooler Receipt Foim.doc LF-1
Revised 8/23/17 i
End of Fonn
Page 33 of 37
11/29/2018

00
r
QD
O
d
a
T
G
N
C O O dcl
X mZN�Uf/1 ❑. Nm
m
m
A
m O m m N V U=
C)
=ZaZ Z Z21N4 m'o
U
r^..
C
FE
o
E
CM
N
O o
U
c v .� a
L
•f0
C
s
tea`
N
N
orn
p
+-
R = UO= a «a
2 Jo¢;�=0�3 3ra
N
y
�+
Z a0
N
a
y U m m m E yy O p ••
N S Z N Z Z G¢ a 8 p w w d
` O
LL
d
U 0)
a0-
s
00.
amUO W LL(72 YJ �'j
?
' saame;u63 IQ iaquwnN Mal
e
'�,
t:IP
1>4
i
w
E
E
m
a
m
�
m
°f
1
1
w y
d
M
N
U-6,
N
ix
An
f
�
E
0
C
y
"`
Q
v
CY
U
c
U
N
•�
auexoia-VP WOW)- W!S aO8Z8o-
m
o
O.
SO!pe!oA! x!puaddtl(OOW)- 9O9Z8
N
V.
°'
U
tlOL4L 00408.v
(pldXQs�j } O3NUSNC uuRAac�
\
Yco
y
vim)
T
i-
(ON Jo.
sa l) 0I1w¢S.P04071ld:Rlal�
a
� C
I
O
O.
O
k
O
A
m.N
O
0
m
U
U
U
a
�
a
VV„11
CL d
E
o
�a
v
E
c
M
v
❑
LIP
ro
:+.f!
�C!
ICJ
m
j
m
W
y
d
0
0
A
hl
ry
Iv
-•®
d•
v
F
u
(D
N
sv
r
i
�.
m
aim
m
ad
3
a`v
N
0
0
0
0
0
m_
c
aa))
O
N
Z
�
U
O
�
iL
:3
C
O
U
w
E
m
c'
°
ca
v
m
p
(n
c�
f6
a
N
fd
N
Z
cu
c
Z
•p
N
2-
N
o
O
L
❑
a a
D-
V
c
N
d
'�-
�
ii ..
(Cl
c
"' U
a
❑
❑
O
❑
O
Z
Y
T T
W
d
a
m
CU
E�
� O
T>-
�
N
a�
NN
c
a
O
O
0>>
o
Cl
co
h Z>
.N
d W
o c
w
m U
E o�
-
7
C7
�"
o
E
ciUm
U¢
¢N
UQ
nZ
.��c
a
w n
a`2
F.
m
F
a
❑
w
Page 34 of 37
11 /29/2018

A
0
M
N
d �
_ 10
t ,>_ U Q LLm
z O p It
W rn n q
U y M co
U FZ.. r
ui
o m �
LL 'j y
T (a if
N Z a
C A
m
o E
E
t•
Z
Q�0 OaON
O
O
S
c6
c
¢ ZZ
=
ON
�Z
nmOON
m 2z oadC VJH»
N
C
U
U
U
by
9
9
o
0
Va
c a
.�
Y
o
cr)o
m
m
0 o
w
A oa m
x
�N
v
rn
uo
x O N ISm aCL
cJiO¢5mmE"
a xznSz Z�aa mpww t
o
V,
UCO
o
Uv
m
rn N
as
a
ov
m
a am UO wu_COx_�Y�
-Z)
d
siou!e7uoo jo jagwnN !e101
0
r
E�
E
E
o
d
E
_a
E
h'v
m
d
o
?
t<
m m
co
rn
m
c
E
me
-�
a
c
�O
Ea
N
O
w n
N m
ur
w
`
a`
�` c
w
y ca
�i,
E
N
U
o
y Z
05
d
m
m O
Z
y
E
m
m
129
N
0
�� •
w m
c�
Q
N
m
.. C
5.�m
YO/
C
K
U
>,
O
c 01
Iq
N
d
U
C
y r
p
^
I
N
c
O
2
`m
cOi
^p
°oE
O
a c
e
s
a
n
E
E
.1Z
�
*
m w H
c
v
a
(VVA)) A,—. r dOld_ VOLVLIVOLVL
X
X
X
X
X
d
coo
m E m
�
•a
m
o
U
slepw V80H VOWCAM09
X
X
X
X
X
ago-
Eg
o r
m
a
CD
(ON A0 seA) USW/SW WJOyed
(ON sa11) a!dweS Pe1ai!Id PIe1d
m
a in
c 5 0
O_
t
�Y
>.
d
x
C if
8
'o
0
d
d
uc o
a
O
XN y
U
U
C O. `
00 $
~vie°
Em�
c
m _�
N
Y
C m
E E
WEal
O
eV
st
N
u1
CV
O
M
L
w m U
N
�
N
\
W
o
m
J
m
N~
O m m
mid
m
p
CD
YA
m
CO
CO
CO
00
N
OL
A CD
d
0000
#
CL
O
O
O
O
CD
E
m
E
o
o,_
o
O
I
m
m E o
m
m
n
La
a
3
a`a
IIni
a`o m t
� U
J
V N �
N w
E o` a
� m
� o
S
m O
rn y
w
U
J
=�
N
w
o
_ v
Z
r
N
0
...
O
t0
h
w 20
C
co
d
N
co
R
�
a c m
V
U
N
vi
'o
U
r
c0
co00
r
r
OD
iO
3 E
o E
G
..
N
o
CO
c
m
'
0
0>
T
^
m
O>
1O6
mOo
O
a
wrnrnrnrn
v
wa
AID
a
cCD�
Z
<'
ID
O
E-
m
E
IDo
@
o
`o
bi o
aci
O
O
O
O
Z—a.
E,
C
c� a
`�, s
J
2
m
l C*4
m e
? v0
0
0
0
0
c o
m` o
y ��
CL
`
U
d L
o 0>
d�
v co
c
= N
J
o
ROD
-
E
N
y
m
a
Z UJ
O C
4
N
O
E
W
m
K
m
m
K
U
UV>
UI-
co
Ua
VJLL
W
a`�
Page 35 of 37
11 /29/2018

&I
W
r
J
1
d
I
0
j
Z
W
�!
'^ c J
W
•�
�
~
k
K
_
�O U
z=
�I�
a ..
�.
JVDI/LJW.,IJISS
"�'1U5D9UUlll�ll'
C� may,
Wm
LPL
M
11
o oA
W
N
Z
Z�
¢
CDEN
=>
_
F-®W
D
a y
LL CO)OU z
(VO\ W
~
Q
.. O N
d Z
�-
cwM _
H~ O
L)
0�m
— —ter_
lL
Z
r o
LAJ
O i�
1 w
?
-
_r— -
d' n ue r
14--
Z
(D
N
Q
W
U-
J
�j
Z
zo
LL
C
Q w
m M C7 w J
CO
G
Q c
— J
OO
LN
_
o -r
U' W.
wr
Z <
_
L
=
zCo
Z�Q�
d
__, U.)
5 o
> w = w CM
r
NJ '
— -
H
(9�H0
N f0
2r
(71 .+ y~�
o
tD o
-
�
Y O
S N
-
_
Ot=AFN Z7 ��
O
~ O
-- - 71 i i `-'ill'
t
Page 36 of 37

Client: Anchor QEA of North Carolina PLLC
Login Number: 161987
List Number: 2
Creator: Shannon, Jonathon W
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
N/A
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
N/A
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
2.5°C IR7
Job Number: 490-161987-1
List Source: TestAmerica Pensacola
List Creation: 10/30/18 12:51 PM
TestAmerica Nashville
Page 37 of 37 11/29/2018

TestAmerica °
THE LEADER IN ENVIRONMENTAL TESTING
ANALYTICAL REPORT
TestAmerica Laboratories, Inc.
TestAmerica Nashville
2960 Foster Creighton Drive
Nashville, TN 37204
Tel: [phone]
TestAmerica Job ID: 490-161924-1
Client Project/Site: Madison Co Closed Landfill SW DW
Foi
Anchor QEA of North Carolina PLLC
231 W Haywood Street
Asheville, North Carolina 28801
Attn: Brian Gant
Authorized for release by.
1112012018 11:12:54 AM
Ken Hayes, Project Manager II
[phone]
[e-mail]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accredited
parameters, exceptions are noted in this report. This report may not be reproduced except in full,
and with written approval from the laboratory. For questions please contact the Project Manager
at the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature is
intended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.

Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
Table of Contents
TestAmerica Job ID: 490-161924-1
CoverPage ..............................................
1
Table of Contents .........................................
2
Sample Summary .........................................
3
Case Narrative ...........................................
4
Definitions...............................................
5
Client Sample Results ......................................
6
QC Sample Results ........................................
12
QC Association ...........................................
21
Chronicle................................................
23
Method Summary .........................................
24
Certification Summary ......................................
25
Chain of Custody ..........................................
26
Receipt Checklists .........................................
29
TestAmerica Nashville
Page 2 of 29 11 /20/2018

Sample Summary
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Lab Sample ID
Client Sample ID
Matrix
Collected
Received
490-161924-1
490-161924-2
490-161924-3
SW-01 OLD
SW-02 OLD
Trip Blank
Water
Water
Water
10/24/18 1416
10/24/18 14:43
10/24/18 01:01
10/25/18 09:25
10/25/18 09:25
10/25/18 09:25
TestAmerica Nashville
Page 3 of 29 11 /20/2018

Case Narrative C
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Job ID: 490-161924-1
Laboratory: TestAmerica Nashville
Narrative
Job Narrative
490-161924-1
Comments
No additional comments.
Receipt
The samples were received on 10/25/2018 9:25 AM; the samples arrived in good condition, properly preserved and, where required, on
ice. The temperature of the cooler at receipt was 1.31 C.
GC/MS VOA
Method 8260B: The RPD of the laboratory control sample (LCS) and laboratory control sample duplicate (LCSD) for batch analytical batch
490-553044 recovered outside control limits for the following analytes: Carbon disulfide.
Method 8260B SIM: MS/MSD was analyzed outside 12 hrs clock. Data not impacted. LCSD was also analyzed.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Metals C
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
VOA Prep
No analytical or quality issues were noted, other than those described in the Definitions/Glossary page.
TestAmerica Nashville
Page 4 of 29 11 /20/2018

Definitions/Glossary
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Qualifiers
GC/MS VOA
Qualifier Qualifier Description
RPD of the LCS and LCSD exceeds the control limits
J Result is less than the RL but greater than or equal to the MDL and the concentration is an approximate value.
Glossary
Abbreviation These commonly used abbreviations may or may not be present in this report.
a Listed under the "D" column to designate that the result is reported on a dry weight basis
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re -analysis, Re -extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
TestAmerica Nashville
Page 5 of 29 11 /20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Client Sample ID: SW-01 OLD
Lab Sample ID: 490-161924-1
Date Collected: 10/24/18 14:16
Matrix:
Water
Date Received: 10/25/18 09:25
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
<0.254
1.00
0.254
ug/L
10/31/1821:34
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
104
70- 130
10131118 21:34
1
4-Bromofluorobenzene (Surr)
102
70 - 130
10131118 21:34
1
Dibromofluoromethane (Surr)
101
70 - 130
10131118 21:34
1
Toluene-d8 (Surr)
98
70 - 130
10131118 21:34
1
Method: 8260B - Volatile Organic Compounds (GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/26/18 22:17
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/26/18 22:17
1
Benzene
<0.200
1.00
0.200
ug/L
10/26/18 22:17
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/26/18 22:17
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/26/18 22:17
1
Bromoform
<0.290
1.00
0.290
ug/L
10/26/18 22:17
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/26/18 22:17
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/26/18 22:17
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/26/18 22:17
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/26/18 22:17
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/26/18 22:17
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/26/18 22:17
1
Chloroform
<0.230
1.00
0.230
ug/L
10/26/18 22:17
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/26/18 22:17
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/26/18 22:17
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 22:17
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/26/18 22:17
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/26/18 22:17
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/26/18 22:17
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/26/18 22:17
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/26/18 22:17
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/26/18 22:17
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/26/18 22:17
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/26/18 22:17
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/26/18 22:17
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/26/18 22:17
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/26/18 22:17
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/26/18 22:17
1
lodomethane
<1.50
10.0
1.50
ug/L
10/26/18 22:17
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/26/18 22:17
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/26/18 22:17
1
Styrene
<0.280
1.00
0.280
ug/L
10/26/18 22:17
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/26/18 22:17
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:17
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/26/18 22:17
1
Toluene
<0.170
1.00
0.170
ug/L
10/26/18 22:17
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/26/18 22:17
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/26/18 22:17
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 22:17
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:17
1
TestAmerica Nashville
Page 6 of 29 11 /20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Client Sample ID: SW-01 OLD Lab Sample ID: 490-161924-1
Date Collected: 10/24/18 14:16 Matrix: Water
Date Received: 10/25/18 09:25
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:17
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/26/18 22:17
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/26/18 22:17
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/26/18 22:17
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/26/18 22:17
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/26/18 22:17
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/26/18 22:17
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
95
70 - 130
10126118 22:17
1
Dibromofluoromethane (Surr)
103
70 - 130
10126118 22:17
1
1,2-Dichloroethane-d4 (Surr)
105
70- 130
10126118 22:17
1
Toluene-d8 (Surr)
94
70 - 130
10126118 22:17
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Arsenic
<0.00400
0.0100
0.00400
mg/L
11/16/1815:27
1
Barium
0.0625
0.0100
0.00200
mg/L
11/16/1815:27
1
Cadmium
<0.00100
0.00500
0.00100
mg/L
11/16/1815:27
1
Chromium
<0.00200
0.0100
0.00200
mg/L
11/16/1815:27
1
Lead
<0.00200
0.0100
0.00200
mg/L
11/16/1815:27
1
Selenium
<0.00400
0.0200
0.00400
mg/L
11/16/1815:27
1
Silver
<0.00200
0.00500
0.00200
mg/L
11/16/1815:27
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/02/18 11:13
11/06/18 09:24
1
Method: SM 2340B - Total Hardness (as CaCO3) by
calculation
Analyte
Result
Qualifier
RL
RL
Unit
D Prepared
Analyzed
Dil Fac
Hardness as calcium carbonate
52.5
3.30
3.30
mg/L
11/16/18 15:27
1
TestAmerica Nashville
Page 7 of 29 11 /20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Client Sample ID: SW-02 OLD
Lab Sample ID: 490-161924-2
Date Collected: 10/24/18 14:43
Matrix:
Water
Date Received: 10/25/18 09:25
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
0.389 J
1.00
0.254
ug/L
10/31/18 22:01
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
105
70- 130
10131118 22:01
1
4-Bromofluorobenzene (Surr)
102
70 - 130
10131118 22:01
1
Dibromofluoromethane (Surr)
100
70 - 130
10131118 22:01
1
Toluene-d8 (Surr)
98
70 - 130
10131118 22:01
1
Method: 8260B - Volatile Organic Compounds (GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/26/18 22:43
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/26/18 22:43
1
Benzene
<0.200
1.00
0.200
ug/L
10/26/18 22:43
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/26/18 22:43
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/26/18 22:43
1
Bromoform
<0.290
1.00
0.290
ug/L
10/26/18 22:43
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/26/18 22:43
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/26/18 22:43
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/26/18 22:43
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/26/18 22:43
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/26/18 22:43
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/26/18 22:43
1
Chloroform
<0.230
1.00
0.230
ug/L
10/26/18 22:43
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/26/18 22:43
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/26/18 22:43
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 22:43
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/26/18 22:43
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/26/18 22:43
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/26/18 22:43
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/26/18 22:43
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/26/18 22:43
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/26/18 22:43
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/26/18 22:43
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/26/18 22:43
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/26/18 22:43
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/26/18 22:43
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/26/18 22:43
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/26/18 22:43
1
lodomethane
<1.50
10.0
1.50
ug/L
10/26/18 22:43
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/26/18 22:43
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/26/18 22:43
1
Styrene
<0.280
1.00
0.280
ug/L
10/26/18 22:43
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/26/18 22:43
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:43
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/26/18 22:43
1
Toluene
<0.170
1.00
0.170
ug/L
10/26/18 22:43
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/26/18 22:43
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/26/18 22:43
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 22:43
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:43
1
TestAmerica Nashville
Page 8 of 29 11 /20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Client Sample ID: SW-02 OLD Lab Sample ID: 490-161924-2
Date Collected: 10/24/18 14:43 Matrix: Water
Date Received: 10/25/18 09:25
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 22:43
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/26/18 22:43
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/26/18 22:43
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/26/18 22:43
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/26/18 22:43
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/26/18 22:43
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/26/18 22:43
1
Surrogate
%Recovery
Qualifier
Limits
Prepared
Analyzed
Dil Fac
C
4-Bromofluorobenzene (Surr)
94
70 - 130
10126118 22:43
1
Dibromofluoromethane (Surr)
104
70 - 130
10126118 22:43
1
1,2-Dichloroethane-d4 (Surr)
108
70- 130
10126118 22:43
1
Toluene-d8 (Surr)
94
70 - 130
10126118 22:43
1
Method: 6010D - Metals (ICP)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Arsenic
<0.00400
0.0100
0.00400
mg/L
11/16/1815:30
1
Barium
0.0492
0.0100
0.00200
mg/L
11/16/1815:30
1
Cadmium
<0.00100
0.00500
0.00100
mg/L
11/16/1815:30
1
Chromium
<0.00200
0.0100
0.00200
mg/L
11/16/1815:30
1
Lead
<0.00200
0.0100
0.00200
mg/L
11/16/1815:30
1
Selenium
<0.00400
0.0200
0.00400
mg/L
11/16/1815:30
1
Silver
<0.00200
0.00500
0.00200
mg/L
11/16/1815:30
1
Method: 7470A - Mercury (CVAA)
Analyte
Result
Qualifier
RL
MDL
Unit
D Prepared
Analyzed
Dil Fac
Mercury
<0.0700
0.200
0.0700
ug/L
11/02/18 11:13
11/06/18 09:26
1
Method: SM 2340B - Total Hardness (as CaCO3) by
calculation
Analyte
Result
Qualifier
RL
RL
Unit
D Prepared
Analyzed
Dil Fac
Hardness as calcium carbonate
64.2
3.30
3.30
mg/L
11/16/18 15:30
1
TestAmerica Nashville
Page 9 of 29 11 /20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Client Sample ID: Trip Blank
Lab Sample ID: 490-161924-3
Date Collected: 10/24/18 01:01
Matrix:
Water
Date Received: 10/25/18 09:25
Method: 8260B SIM - Volatile Organic
Compounds (GC/MS)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,4-Dioxane
<0.254
1.00
0.254
ug/L
10/31/1822:29
1
•
Surrogate %Recovery Qualifier
Limits
Prepared Analyzed
Dil Fac
1,2-Dichloroethane-d4 (Surr)
105
70- 130
10131118 22:29
1
4-Bromofluorobenzene (Surr)
102
70 - 130
10131118 22:29
1
Dibromofluoromethane (Surr)
102
70 - 130
10131118 22:29
1
Toluene-d8 (Surr)
99
70 - 130
10131118 22:29
1
Method: 8260B - Volatile Organic Compounds (GC/MS)
C
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
22.0 J
25.0
2.66
ug/L
10/26/18 21:50
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/26/18 21:50
1
Benzene
<0.200
1.00
0.200
ug/L
10/26/18 21:50
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/26/18 21:50
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/26/18 21:50
1
Bromoform
<0.290
1.00
0.290
ug/L
10/26/18 21:50
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/26/18 21:50
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/26/18 21:50
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/26/18 21:50
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/26/18 21:50
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/26/18 21:50
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/26/18 21:50
1
Chloroform
<0.230
1.00
0.230
ug/L
10/26/18 21:50
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/26/18 21:50
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/26/18 21:50
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 21:50
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/26/18 21:50
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/26/18 21:50
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/26/18 21:50
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/26/18 21:50
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/26/18 21:50
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/26/18 21:50
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/26/18 21:50
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/26/18 21:50
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/26/18 21:50
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/26/18 21:50
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/26/18 21:50
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/26/18 21:50
1
lodomethane
<1.50
10.0
1.50
ug/L
10/26/18 21:50
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/26/18 21:50
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/26/18 21:50
1
Styrene
<0.280
1.00
0.280
ug/L
10/26/18 21:50
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/26/18 21:50
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/26/18 21:50
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/26/18 21:50
1
Toluene
<0.170
1.00
0.170
ug/L
10/26/18 21:50
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/26/18 21:50
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/26/18 21:50
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 21:50
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 21:50
1
TestAmerica Nashville
Page 10 of 29 11/20/2018

Client Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Client Sample ID: Trip Blank
Lab Sample ID: 490-161924-3
Date Collected: 10/24/18 01:01
Matrix:
Water
Date Received: 10/25/18 09:25
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 21:50
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/26/18 21:50
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/26/18 21:50
1 Y
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/26/18 21:50
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/26/18 21:50
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/26/18 21:50
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/26/18 21:50
1
Surrogate %Recovery
Qualifier
Limits
Prepared Analyzed
Dil Fac C
4-Bromofluorobenzene (Surr)
94
70 - 130
10126118 21:50
1
Dibromofluoromethane (Surr)
103
70 - 130
10126118 21:50
1
1,2-Dichloroethane-d4 (Surr)
107
70- 130
10126118 21:50
1
Toluene-d8 (Surr)
95
70 - 130
10126118 21:50
1
TestAmerica Nashville
Page 11 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Method: 8260B - Volatile Organic Compounds (GC/MS)
Lab Sample ID: MB 490-553044/6
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553044
MB MB
Analyte
Result Qualifier
RL
MDL
Unit
D Prepared Analyzed
Dil Fac
Acetone
<2.66
25.0
2.66
ug/L
10/26/1815:11
1
Acrylonitrile
<0.500
10.0
0.500
ug/L
10/26/18 15:11
1
Benzene
<0.200
1.00
0.200
ug/L
10/26/18 15:11
1
Bromochloromethane
<0.150
1.00
0.150
ug/L
10/26/18 15:11
1
Bromodichloromethane
<0.170
1.00
0.170
ug/L
10/26/18 15:11
1
Bromoform
<0.290
1.00
0.290
ug/L
10/26/18 15:11
1
Bromomethane
<0.350
1.00
0.350
ug/L
10/26/18 15:11
1
2-Butanone (MEK)
<2.64
50.0
2.64
ug/L
10/26/18 15:11
1
Carbon disulfide
<0.220
1.00
0.220
ug/L
10/26/18 15:11
1
Carbon tetrachloride
<0.180
1.00
0.180
ug/L
10/26/18 15:11
1
Chlorobenzene
<0.180
1.00
0.180
ug/L
10/26/18 15:11
1
Chloroethane
<0.360
1.00
0.360
ug/L
10/26/18 15:11
1
Chloroform
<0.230
1.00
0.230
ug/L
10/26/18 15:11
1
Chloromethane
<0.360
1.00
0.360
ug/L
10/26/18 15:11
1
cis-1,2-Dichloroethene
<0.210
1.00
0.210
ug/L
10/26/18 15:11
1
cis-1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 15:11
1
Dibromochloromethane
<0.250
1.00
0.250
ug/L
10/26/18 15:11
1
1,2-Dibromo-3-Chloropropane
<0.940
10.0
0.940
ug/L
10/26/18 15:11
1
1,2-Dibromoethane (EDB)
<0.210
1.00
0.210
ug/L
10/26/18 15:11
1
Dibromomethane
<0.450
1.00
0.450
ug/L
10/26/18 15:11
1
1,2-Dichlorobenzene
<0.190
1.00
0.190
ug/L
10/26/18 15:11
1
1,4-Dichlorobenzene
<0.170
1.00
0.170
ug/L
10/26/18 15:11
1
1,1-Dichloroethane
<0.240
1.00
0.240
ug/L
10/26/18 15:11
1
1,2-Dichloroethane
<0.200
1.00
0.200
ug/L
10/26/18 15:11
1
1,1-Dichloroethene
<0.250
1.00
0.250
ug/L
10/26/18 15:11
1
1,2-Dichloropropane
<0.250
1.00
0.250
ug/L
10/26/18 15:11
1
Ethylbenzene
<0.190
1.00
0.190
ug/L
10/26/18 15:11
1
2-Hexanone
<1.28
10.0
1.28
ug/L
10/26/18 15:11
1
lodomethane
<1.50
10.0
1.50
ug/L
10/26/18 15:11
1
Methylene Chloride
<1.00
5.00
1.00
ug/L
10/26/18 15:11
1
4-Methyl-2-pentanone (MIBK)
<0.810
10.0
0.810
ug/L
10/26/18 15:11
1
Styrene
<0.280
1.00
0.280
ug/L
10/26/18 15:11
1
1,1,1,2-Tetrachloroethane
<0.150
1.00
0.150
ug/L
10/26/18 15:11
1
1,1,2,2-Tetrachloroethane
<0.190
1.00
0.190
ug/L
10/26/18 15:11
1
Tetrachloroethene
<0.140
1.00
0.140
ug/L
10/26/18 15:11
1
Toluene
<0.170
1.00
0.170
ug/L
10/26/18 15:11
1
trans- 1,4-Dichloro-2-butene
<0.460
5.00
0.460
ug/L
10/26/18 15:11
1
trans- 1,2-Dichloroethene
<0.230
1.00
0.230
ug/L
10/26/18 15:11
1
trans- 1,3-Dichloropropene
<0.170
1.00
0.170
ug/L
10/26/18 15:11
1
1,1,1-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 15:11
1
1,1,2-Trichloroethane
<0.190
1.00
0.190
ug/L
10/26/18 15:11
1
Trichloroethene
<0.200
1.00
0.200
ug/L
10/26/18 15:11
1
Trichlorofluoromethane
<0.210
1.00
0.210
ug/L
10/26/18 15:11
1
1,2,3-Trichloropropane
<0.230
1.00
0.230
ug/L
10/26/18 15:11
1
Vinyl acetate
<1.71
10.0
1.71
ug/L
10/26/18 15:11
1
Vinyl chloride
<0.180
1.00
0.180
ug/L
10/26/18 15:11
1
Xylenes, Total
<0.580
3.00
0.580
ug/L
10/26/18 15:11
1
TestAmerica Nashville
Page 12 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: MB 490-55304416
Matrix: Water
Analysis Batch: 553044
Client Sample ID: Method Blank
Prep Type: Total/NA
MB MB
Surrogate %Recovery Qualifier
Limits
Prepared
Analyzed DR Fac
4-Bromofluorobenzene (Surr)
98
70 - 130
10126118 15:11 1
Dibromofluoromethane (Surr)
103
70 - 130
10126118 15:11 1
1,2-Dichloroethane-d4 (Surr)
107
70- 130
10126118 15:11 1
Toluene-d8 (Surr)
95
70 - 130
10126118 15:11 1
Lab Sample ID: LCS 490-553044/4
Client Sample ID:
Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553044
Spike
LCS LCS
%Rec.
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Acetone
100
120.2
ug/L
126
39 -150
Acrylonitrile
200
233.0
ug/L
117
63 -135
Benzene
20.0
22.36
ug/L
112
70 -130
Bromochloromethane
20.0
21.29
ug/L
106
70 -130
Bromodichloromethane
20.0
22.40
ug/L
112
70 -130
Bromoform
20.0
18.40
ug/L
92
70 -137
Bromomethane
20.0
18.55
ug/L
93
53 -150
2-Butanone (MEK)
100
113.5
ug/L
113
55 -143
Carbon disulfide
20.0
19.64
ug/L
98
64 -135
Carbon tetrachloride
20.0
23.15
ug/L
116
70 -147
Chlorobenzene
20.0
19.96
ug/L
100
70 -130
Chloroethane
20.0
23.89
ug/L
119
60 -138
Chloroform
20.0
21.85
ug/L
109
70 -130
Chloromethane
20.0
23.36
ug/L
117
33 -150
cis-1,2-Dichloroethene
20.0
20.99
ug/L
105
70 -130
cis-1,3-Dichloropropene
20.0
19.09
ug/L
95
70 -133
Dibromochloromethane
20.0
18.36
ug/L
92
70 -133
1,2-Dibromo-3-Chloropropane
20.0
16.96
ug/L
85
45-138
1,2-Dibromoethane(EDB)
20.0
18.74
ug/L
94
70-130
Dibromomethane
20.0
22.37
ug/L
112
70 -130
1,2-Dichlorobenzene
20.0
17.59
ug/L
88
70 -130
1,4-Dichlorobenzene
20.0
19.39
ug/L
97
70 -130
1,1-Dichloroethane
20.0
21.59
ug/L
108
70-130
1,2-Dichloroethane
20.0
22.23
ug/L
ill
70 -130
1,1-Dichloroethene
20.0
21.63
ug/L
108
70-132
1,2-Dichloropropane
20.0
22.18
ug/L
ill
70 -130
Ethylbenzene
20.0
19.84
ug/L
99
70 -130
2-Hexanone
100
98.47
ug/L
98
54 -142
lodomethane
20.0
16.74
ug/L
84
40 -150
Methylene Chloride
20.0
22.16
ug/L
111
70 -130
4-Methyl-2-pentanone (MIBK)
100
97.06
ug/L
97
60-137
Styrene
20.0
19.57
ug/L
98
70 -130
1,1,1,2-Tetrachloroethane
20.0
18.61
ug/L
93
70-130
1,1,2,2-Tetrachloroethane
20.0
19.12
ug/L
96
69-131
Tetrachloroethene
20.0
18.88
ug/L
94
70 -130
Toluene
20.0
19.32
ug/L
97
70 -130
trans- 1,4-Dichloro-2-butene
20.0
18.11
ug/L
91
41-150
trans- 1,2-Dichloroethene
20.0
21.11
ug/L
106
70-130
TestAmerica Nashville
Page 13 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: LCS 490-553044/4 Client Sample ID: Lab Control Sample
Matrix: Water Prep Type: Total/NA
Analysis Batch: 553044
Spike LCS LCS %Rec.
Analyte Added Result Qualifier Unit D %Rec Limits
trans- 1,3-Dichloropropene
20.0
18.93
ug/L
95
63-142
1,1,1-Trichloroethane
20.0
22.81
ug/L
114
70-135
1,1,2-Trichloroethane
20.0
19.33
ug/L
97
70-130
Trichloroethene
20.0
22.21
ug/L
111
70 -130
Trichlorofluoromethane
20.0
23.36
ug/L
117
59 -150
1,2,3-Trichloropropane
20.0
18.87
ug/L
94
70-131
Vinyl acetate
40.0
42.78
ug/L
107
54 -146
Vinyl chloride
20.0
23.18
ug/L
116
57 -137
Xylenes, Total
40.0
38.91
ug/L
97
70 -132
LCS LCS
Surrogate %Recovery Qualifier
Limits
4-Bromofluorobenzene (Surr) 94
70 - 130
Dibromofluoromethane (Surr) 101
70 - 130
1,2-Dichloroethane-d4 (Surr) 106
70- 130
Toluene-d8 (Surr) 93
70 - 130
Lab Sample ID: LCSD 490-55304417
Client Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553044
Spike
LCSD
LCSD
%Rec.
RPD
Analyte
Added
Result
Qualifier Unit
D %Rec
Limits
RPD
Limit
Acetone
100
108.1
ug/L
108
39 - 550
11
23
Acrylonitrile
200
248.0
ug/L
124
63 -135
6
16
Benzene
20.0
24.77
ug/L
124
70-130
10
12
Bromochloromethane
20.0
23.39
ug/L
117
70 -130
9
16
Bromodichloromethane
20.0
24.46
ug/L
122
70 -130
9
14
Bromoform
20.0
19.86
ug/L
99
70 -137
8
14
Bromomethane
20.0
18.58
ug/L
93
53 -150
0
19
2-Butanone (MEK)
100
119.1
ug/L
119
55 -143
5
19
Carbon disulfide
20.0
23.43
ug/L
117
64 -135
18
16
Carbon tetrachloride
20.0
25.28
ug/L
126
70 -147
9
16
Chlorobenzene
20.0
20.97
ug/L
105
70-130
5
12
Chloroethane
20.0
24.93
ug/L
125
60 -138
4
15
Chloroform
20.0
23.98
ug/L
120
70 -130
9
14
Chloromethane
20.0
24.70
ug/L
124
33 -150
6
20
cis-1,2-Dichloroethene
20.0
22.16
ug/L
ill
70 -130
5
15
cis-1,3-Dichloropropene
20.0
20.42
ug/L
102
70 -133
7
15
Dibromochloromethane
20.0
19.71
ug/L
99
70 -133
7
13
1,2-Dibromo-3-Chloropropane
20.0
16.24
ug/L
81
45-138
4
19
1,2-Dibromoethane(EDB)
20.0
19.63
ug/L
98
70-130
5
13
Dibromomethane
20.0
23.47
ug/L
117
70 -130
5
14
1,2-Dichlorobenzene
20.0
18.48
ug/L
92
70 -130
5
12
1,4-Dichlorobenzene
20.0
20.59
ug/L
103
70 -130
6
12
1,1-Dichloroethane
20.0
23.78
ug/L
119
70-130
10
17
1,2-Dichloroethane
20.0
23.80
ug/L
119
70 -130
7
13
1,1-Dichloroethene
20.0
24.09
ug/L
120
70-132
11
20
1,2-Dichloropropane
20.0
24.15
ug/L
121
70 -130
9
15
Ethylbenzene
20.0
21.34
ug/L
107
70 -130
7
12
TestAmerica Nashville
Page 14 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed
Landfill SW DW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: LCSD 490-553044/7
Client Sample ID: Lab Control Sample Dup
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553044
Spike
LCSD
LCSD
%Rec.
RPD
Analyte
Added
Result
Qualifier Unit
D %Rec
Limits
RPD
Limit
2-Hexanone
100
98.73
ug/L
99
54-142
0
17
lodomethane
20.0
18.00
ug/L
90
40 -150
7
20
Methylene Chloride
20.0
23.77
ug/L
119
70 -130
7
15
4-Methyl-2-pentanone (MIBK)
100
100.1
ug/L
100
60-137
3
21
Styrene
20.0
21.02
ug/L
105
70 -130
7
12
1,1,1,2-Tetrachloroethane
20.0
19.58
ug/L
98
70-130
5
13
1,1,2,2-Tetrachloroethane
20.0
19.72
ug/L
99
69-131
3
15
Tetrachloroethene
20.0
20.08
ug/L
100
70 -130
6
17
Toluene
20.0
20.93
ug/L
105
70 -130
8
13
trans- l,4-Dichloro-2-butene
20.0
19.51
ug/L
98
41-150
7
20
trans- l,2-Dichloroethene
20.0
23.56
ug/L
118
70-130
11
15
trans- 1,3-Dichloropropene
20.0
19.94
ug/L
100
63-142
5
13
1,1,1-Trichloroethane
20.0
24.91
ug/L
125
70-135
9
15
1,1,2-Trichloroethane
20.0
20.58
ug/L
103
70-130
6
13
Trichloroethene
20.0
24.13
ug/L
121
70 -130
8
14
Trichlorofluoromethane
20.0
24.42
ug/L
122
59 -150
4
22
1,2,3-Trichloropropane
20.0
18.67
ug/L
93
70-131
1
14
Vinyl acetate
40.0
47.30
ug/L
118
54 -146
10
20
Vinyl chloride
20.0
24.16
ug/L
121
57 -137
4
15
Xylenes, Total
40.0
41.89
ug/L
105
70 -132
7
11
LCSD LCSD
Surrogate
%Recovery Qualifier
Limits
4-Bromofluorobenzene (Surr)
93
70 - 130
Dibromofluoromethane (Surr)
105
70 - 130
1,2-Dichloroethane-d4 (Surr)
108
70- 130
Toluene-d8 (Surr)
92
70 - 130
Lab Sample ID: 490-161980-B-9 MS
Client Sample
ID: Matrix Spike
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 553044
Sample Sample
Spike
MS
MS
%Rec.
Analyte
Result Qualifier
Added
Result
Qualifier Unit
D %Rec
Limits
Acetone
<2.66
100
105.3
ug/L
105
39 -150
Acrylonitrile
<0.500
200
223.8
ug/L
112
50 -135
Benzene
<0.200
20.0
24.34
ug/L
122
55 -147
Bromochloromethane
<0.150
20.0
22.15
ug/L
ill
59 -132
Bromodichloromethane
<0.170
20.0
23.31
ug/L
117
70 -140
Bromoform
<0.290
20.0
18.10
ug/L
91
53 -150
Bromomethane
<0.350
20.0
16.72
ug/L
84
30 -150
2-Butanone (MEK)
<2.64
100
100.0
ug/L
100
50 -143
Carbon disulfide
<0.220
20.0
24.03
ug/L
120
35 -150
Carbon tetrachloride
<0.180
20.0
26.47
ug/L
132
56 -150
Chlorobenzene
<0.180
20.0
20.93
ug/L
105
70 -130
Chloroethane
<0.360
20.0
24.42
ug/L
122
58 -141
Chloroform
<0.230
20.0
23.61
ug/L
118
66 -138
Chloromethane
<0.360
20.0
24.20
ug/L
121
10 -150
cis-1,2-Dichloroethene
<0.210
20.0
22.76
ug/L
114
68 -131
cis-1,3-Dichloropropene
<0.170
20.0
19.05
ug/L
95
70 -133
TestAmerica Nashville
Page 15 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161980-B-9 MS
Matrix: Water
Analysis Batch: 553044
Client Sample ID: Matrix Spike
Prep Type: Total/NA
Analyte
Sample Sample
Result Qualifier
Spike
Added
MS MS
Result Qualifier
Unit
D %Rec
%Rec.
Limits
Dibromochloromethane
<0.250
20.0
18.67
ug/L
93
66 -140
1,2-Dibromo-3-Chloropropane
<0.940
20.0
14.75
ug/L
74
38-138
1,2-Dibromoethane(EDB)
<0.210
20.0
18.51
ug/L
93
65-137
Dibromomethane
<0.450
20.0
22.64
ug/L
113
70 -130
1,2-Dichlorobenzene
<0.190
20.0
18.03
ug/L
90
70 -130
1,4-Dichlorobenzene
<0.170
20.0
20.30
ug/L
101
70 -130
1,1-Dichloroethane
<0.240
20.0
22.09
ug/L
110
61-139
1,2-Dichloroethane
<0.200
20.0
22.67
ug/L
113
64 -136
1,1-Dichloroethene
<0.250
20.0
24.26
ug/L
121
54-150
1,2-Dichloropropane
<0.250
20.0
23.20
ug/L
116
67 -130
Ethylbenzene
<0.190
20.0
21.42
ug/L
107
65 -139
2-Hexanone
<1.28
100
86.99
ug/L
87
44-150
lodomethane
<1.50
20.0
16.50
ug/L
82
34-150
Methylene Chloride
<1.00
20.0
23.11
ug/L
116
64 -130
4-Methyl-2-pentanone (MIBK)
<0.810
100
89.03
ug/L
89
50-140
Styrene
<0.280
20.0
20.65
ug/L
103
70 -130
1,1,1,2-Tetrachloroethane
<0.150
20.0
19.01
ug/L
95
70-131
1,1,2,2-Tetrachloroethane
<0.190
20.0
18.19
ug/L
91
56-145
Tetrachloroethene
<0.140
20.0
21.28
ug/L
106
57 -138
Toluene
<0.170
20.0
20.93
ug/L
105
64 -136
trans- 1,4-Dichloro-2-butene
<0.460
20.0
17.52
ug/L
88
39-150
trans- 1,2-Dichloroethene
<0.230
20.0
23.45
ug/L
117
59-143
trans- 1,3-Dichloropropene
<0.170
20.0
18.66
ug/L
93
63-142
1,1,1-Trichloroethane
<0.190
20.0
25.74
ug/L
129
68-144
1,1,2-Trichloroethane
<0.190
20.0
19.36
ug/L
97
70-130
Trichloroethene
<0.200
20.0
23.69
ug/L
118
63 -135
Trichlorofluoromethane
<0.210
20.0
25.78
ug/L
129
44 -150
1,2,3-Trichloropropane
<0.230
20.0
17.96
ug/L
90
65-131
Vinyl acetate
<1.71
40.0
42.77
ug/L
107
43 -146
Vinyl chloride
<0.180
20.0
25.04
ug/L
125
57 -150
Xylenes, Total
<0.580
40.0
41.38
ug/L
103
69 -132
MS MS
Surrogate
%Recovery Qualifier
Limits
4-Bromofluorobenzene (Surr)
91
70 - 130
Dibromofluoromethane (Surr)
103
70 - 130
1,2-Dichloroethane-d4 (Surr)
103
70- 130
Toluene-d8 (Surr)
91
70 - 130
Lab Sample ID: 490-161980-C-9 MSD
Matrix: Water
Analysis Batch: 553044
Analyte
Acetone
Acrylonitrile
Benzene
Bromochloromethane
Bromodichloromethane
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Sample Sample
Result Qualifier
Spike
Added
MSD MSD
Result Qualifier
Unit
D %Rec
%Rec.
Limits
RPD
RPD
Limit
<2.66
100
93.58
ug/L
94
39-150
12
28
<0.500
200
219.5
ug/L
110
50-135
2
23
<0.200
20.0
23.62
ug/L
118
55 -147
3
22
<0.150
20.0
21.22
ug/L
106
59 -132
4
21
<0.170
20.0
21.79
ug/L
109
70 -140
7
196
TestAmerica Nashville
Page 16 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Method: 8260B - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161980-C-9 MSD Client Sample ID: Matrix Spike Duplicate
Matrix: Water Prep Type: Total/NA
Analysis Batch: 553044
Sample Sample Spike MSD MSD %Rec. RPD
Analyte Result Qualifier Added Result Qualifier Unit D %Rec Limits RPD Limit
Bromoform
<0.290
20.0
17.37
ug/L
87
53 -150
4
20
Bromomethane
<0.350
20.0
17.72
ug/L
89
30 -150
6
44
2-Butanone (MEK)
<2.64
100
103.0
ug/L
103
50 -143
3
28
Carbon disulfide
<0.220
20.0
23.59
ug/L
118
35 -150
2
34
Carbon tetrachloride
<0.180
20.0
25.69
ug/L
128
56 -150
3
18
Chlorobenzene
<0.180
20.0
20.19
ug/L
101
70 -130
4
15
Chloroethane
<0.360
20.0
25.07
ug/L
125
58 -141
3
31
Chloroform
<0.230
20.0
22.45
ug/L
112
66 -138
5
21
Chloromethane
<0.360
20.0
24.12
ug/L
121
10 -150
0
43
cis-1,2-Dichloroethene
<0.210
20.0
21.94
ug/L
110
68 -131
4
21
cis-1,3-Dichloropropene
<0.170
20.0
18.74
ug/L
94
70 -133
2
19
Dibromochloromethane
<0.250
20.0
18.25
ug/L
91
66 -140
2
19
1,2-Dibromo-3-Chloropropane
<0.940
20.0
14.51
ug/L
73
38-138
2
26
1,2-Dibromoethane(EDB)
<0.210
20.0
17.66
ug/L
88
65-137
5
21
Dibromomethane
<0.450
20.0
21.14
ug/L
106
70 -130
7
19
1,2-Dichlorobenzene
<0.190
20.0
17.40
ug/L
87
70 -130
4
15
1,4-Dichlorobenzene
<0.170
20.0
19.74
ug/L
99
70 -130
3
14
1,1-Dichloroethane
<0.240
20.0
21.07
ug/L
105
61-139
5
23
1,2-Dichloroethane
<0.200
20.0
21.98
ug/L
110
64 -136
3
22
1,1-Dichloroethene
<0.250
20.0
23.95
ug/L
120
54-150
1
24
1,2-Dichloropropene
<0.250
20.0
22.65
ug/L
113
67 -130
2
19
Ethylbenzene
<0.190
20.0
20.59
ug/L
103
65 -139
4
18
2-Hexanone
<1.28
100
85.17
ug/L
85
44 -150
2
21
lodomethane
<1.50
20.0
17.25
ug/L
86
34 -150
4
37
Methylene Chloride
<1.00
20.0
21.36
ug/L
107
64 -130
8
22
4-Methyl-2-pentanone (MIBK)
<0.810
100
85.80
ug/L
86
50-140
4
24
Styrene
<0.280
20.0
19.87
ug/L
99
70 -130
4
16
1,1,1,2-Tetrachloroethane
<0.150
20.0
18.51
ug/L
93
70-131
3
16
1,1,2,2-Tetrachloroethane
<0.190
20.0
17.63
ug/L
88
56-145
3
19
Tetrachloroethene
<0.140
20.0
20.38
ug/L
102
57 -138
4
17
Toluene
<0.170
20.0
20.44
ug/L
102
64 -136
2
18
trans- 1,4-Dichloro-2-butene
<0.460
20.0
17.03
ug/L
85
39-150
3
28
trans- 1,2-Dichloroethene
<0.230
20.0
22.71
ug/L
114
59-143
3
25
trans- 1,3-Dichloropropene
<0.170
20.0
18.20
ug/L
91
63 -142
2
18
1,1,1-Trichloroethane
<0.190
20.0
24.65
ug/L
123
68-144
4
17
1,1,2-Trichloroethane
<0.190
20.0
18.81
ug/L
94
70-130
3
18
Trichloroethene
<0.200
20.0
23.91
ug/L
120
63 -135
1
17
Trichlorofluoromethane
<0.210
20.0
25.14
ug/L
126
44 -150
3
32
1,2,3-Trichloropropane
<0.230
20.0
17.44
ug/L
87
65-131
3
19
Vinyl acetate
<1.71
40.0
42.09
ug/L
105
43 -146
2
20
Vinyl chloride
<0.180
20.0
25.37
ug/L
127
57 -150
1
37
Xylenes, Total
<0.580
40.0
40.23
ug/L
101
69 -132
3
17
MSD MSD
Surrogate %Recovery Qualifier Limits
4-Bromofluorobenzene (Surr) 93 70 - 130
Dibromofluoromethane (Surr) 103 70 - 130
1,2-Dichloroethane-d4 (Surr) 105 70- 130
Toluene-d8 (Surr) 91 70 - 130
TestAmerica Nashville
Page 17 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
Method: 8260B SIM - Volatile Organic Compounds (GC/MS)
Lab Sample ID: MB 490-554017/8
Matrix: Water
Analysis Batch: 554017
MB MB
Analyte Result Qualifier
1,4-Dioxane <0.254
MB MB
Surrogate %Recovery Qualifier
1,2-Dichloroethane-d4 (Surr)
105
4-Bromofluorobenzene (Surr)
101
Dibromofluoromethane (Surr)
101
Toluene-d8 (Surr)
98
Lab Sample ID: LCS 490-554017/4
Matrix: Water
Analysis Batch: 554017
RL MDL Unit D
1.00 0.254 ug/L
Limits
70-130
70-130
70-130
70-130
LCS LCS
Surrogate
%Recovery Qualifier
Limits
1,2-Dichloroethane-d4 (Surr)
99
70- 130
4-Bromofluorobenzene (Surr)
101
70 - 130
Dibromofluoromethane (Surr)
100
70 - 130
Toluene-d8 (Surr)
100
70 - 130
Lab Sample ID: LCSD 490-554017/5
Matrix: Water
Analysis Batch: 554017
LCSD LCSD
Surrogate
%Recovery Qualifier
Limits
1,2-Dichloroethane-d4 (Surr)
101
70- 130
4-Bromofluorobenzene (Surr)
101
70 - 130
Dibromofluoromethane (Surr)
102
70 - 130
Toluene-d8 (Surr)
100
70 - 130
Lab Sample ID: 490-161980-D-6 MS
Matrix: Water
Analysis Batch: 554017
MS MS
Surrogate %Recovery Qualifier Limits
1,2-Dichloroethane-d4 (Surr) 100 70- 130
4-Bromofluorobenzene (Surr) 102 70 - 130
Dibromofluoromethane (Surr) 101 70 - 130
Toluene-d8 (Surr) 99 70 - 130
Lab Sample ID: 490-161980-E-6 MSD
Matrix: Water
Analysis Batch: 554017
MSD MSD
Surrogate %Recovery Qualifier Limits
1,2-Dichloroethane-d4 (Surr) 101 70- 130
4-Bromofluorobenzene (Surr) 101 70 - 130
Dibromofluoromethane (Surr) 100 70 - 130
TestAmerica Job ID: 490-161924-1
Client Sample ID: Method Blank
Prep Type: Total/NA
Prepared Analyzed
Dil Fac
10/31/18 16:31
1
Prepared Analyzed
Dil Fac
10131118 16:31
1
10131118 16:31
1
10131118 16:31
1
10131118 16:31
1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Client Sample ID: Lab Control Sample Dup
Prep Type: Total/NA
Client Sample ID: Matrix Spike
Prep Type: Total/NA
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Page 18 of 29
TestAmerica Nashville
11 /20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Method: 8260B SIM - Volatile Organic Compounds (GC/MS) (Continued)
Lab Sample ID: 490-161980-E-6 MSD
Client Sample ID: Matrix Spike Duplicate
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 554017
MSD MSD
Surrogate %Recovery Qualifier
Limits
Toluene-d8 (Surr) 99
70 - 130
Method: 6010D - Metals (ICP)
Lab Sample ID: MB 400-418239/1-A
Client Sample ID: Method Blank
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 420004
Prep Batch: 418239
MB MB
Analyte Result Qualifier
RL
MDL
Unit
D
Prepared
Analyzed Dil Fac
Arsenic <0.00400
0.0100
0.00400
mg/L
11/03/1819:10
11/16/1813:58 1
Barium <0.00200
0.0100
0.00200
mg/L
11/03/1819:10
11/16/1813:58 1
Cadmium <0.00100
0.00500
0.00100
mg/L
11/03/1819:10
11/16/1813:58 1
Chromium <0.00200
0.0100
0.00200
mg/L
11/03/1819:10
11/16/1813:58 1
Lead <0.00200
0.0100
0.00200
mg/L
11 /03/18 19:10
11 /16/18 13:58 1
Selenium <0.00400
0.0200
0.00400
mg/L
11/03/1819:10
11/16/1813:58 1
Silver <0.00200
0.00500
0.00200
mg/L
11/03/1819:10
11/16/1813:58 1
Lab Sample ID: LCS 400-418239/2-A
Client Sample ID:
Lab Control Sample
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 420004
Prep Batch: 418239
Spike
LCS LCS
%Rec.
Analyte
Added
Result Qualifier
Unit
D %Rec
Limits
Arsenic
1.00
0.9522
mg/L
95
80 -120
Barium
1.00
0.9924
mg/L
99
80-120
Cadmium
0.500
0.4838
mg/L
97
80 -120
Chromium
1.00
0.9729
mg/L
97
80 -120
Lead
1.00
1.003
mg/L
100
80 -120
Selenium
1.00
0.8896
mg/L
89
80 -120
Silver
0.500
0.4753
mg/L
95
80 -120
Lab Sample ID: 400-161100-G-1-B MS
Client Sample ID: Matrix Spike
Matrix: Water
Prep Type: Total/NA
Analysis Batch: 420004
Prep Batch: 418239
Sample Sample
Spike
MS MS
%Rec.
Analyte Result Qualifier
Added
Result Qualifier
Unit
D %Rec
Limits
Arsenic 0.00408 J
1.00
0.9263
mg/L
92
75 -125
Barium 0.277
1.00
1.229
mg/L
95
75-125
Cadmium <0.00100
0.500
0.4691
mg/L
94
75 -125
Chromium <0.00200
1.00
0.9193
mg/L
92
75 -125
Lead <0.00200
1.00
0.9925
mg/L
99
75 -125
Selenium <0.00400 L
1.00
0.7463
mg/L
75
75 -125
Silver <0.00200
0.500
0.4560
mg/L
91
75 -125
TestAmerica Nashville
Page 19 of 29 11/20/2018

QC Sample Results
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
Method: 6010D - Metals (ICP) (Continued)
Lab Sample ID: 400-161100-G-1-C MSD
Matrix: Water
Analysis Batch: 420004
Sample
Sample
Spike
MSD MSD
Analyte
Result
Qualifier
Added
Result Qualifier
Arsenic
0.00408
J
1.00
0.9377
Barium
0.277
1.00
1.251
Cadmium
<0.00100
0.500
0.4736
Chromium
<0.00200
1.00
0.9303
Lead
<0.00200
1.00
0.9961
Selenium
<0.00400
L
1.00
0.7544
Silver
<0.00200
0.500
0.4612
Method: 7470A - Mercury (CVAA)
Lab Sample ID: MB 400-418102/14-A
Matrix: Water
Analysis Batch: 418545
MB MB
Analyte Result Qualifier
Mercury <0.0700
Lab Sample ID: LCS 400-418102/15-A
Matrix: Water
Analysis Batch: 418545
LAna
lyte
Mercury
FLab Sample ID: 400-161102-1-6-E MS
Matrix: Water
Analysis Batch: 418545
Sample
Sample
Analyte
Result
Qualifier
Mercury
<0.0700
FLab Sample ID: 400-161102-1-6-F
MSD
Matrix: Water
Analysis Batch: 418545
Sample
Sample
Analyte
Result
Qualifier
Mercury
<0.0700
Spike
Added
1.01
TestAmerica Job ID: 490-161924-1
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Prep Batch: 418239
%Rec. RPD
Unit
D %Rec
Limits RPD Limit
mg/L
93
75 - 225 1 20
mg/L
97
75 -125 2 20
mg/L
95
75 -125 1 20
mg/L
93
75 -125 1 20
mg/L
100
75 -125 0 20
mg/L
75
75 -125 1 20
mg/L
92
75 -125 1 20
Client Sample ID: Method Blank
Prep Type: Total/NA
Prep Batch: 418102
RL MDL Unit D Prepared Analyzed Dil Fac
0.200 0.0700 ug/L 11/02/18 11:10 11/06/18 09:11 1
Client Sample ID: Lab Control Sample
Prep Type: Total/NA
Prep Batch: 418102
LCS LCS %Rec.
Result Qualifier Unit D %Rec Limits
1.115 ug/L 111 80 -120
Client Sample ID: Matrix Spike
Prep Type: Total/NA
Prep Batch: 418102
Spike MS MS %Rec.
Added Result Qualifier Unit D %Rec Limits
2.01 2.286 ug/L 114 80 -120
Client Sample ID: Matrix Spike Duplicate
Prep Type: Total/NA
Prep Batch: 418102
Spike MSD MSD %Rec. RPD
Added Result Qualifier Unit D %Rec Limits RPD Limit
2.01 2.236 ug/L 111 80 -120 2 20
Page 20 of 29
TestAmerica Nashville
11 /20/2018

QC Association Summary
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co
Closed Landfill SW DW
GC/MS VOA
Analysis Batch: 553044
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161924-1
SW-01 OLD
Total/NA
Water
8260B
490-161924-2
SW-02 OLD
Total/NA
Water
8260B
490-161924-3
Trip Blank
Total/NA
Water
8260B
MB 490-553044/6
Method Blank
Total/NA
Water
8260B
LCS 490-553044/4
Lab Control Sample
Total/NA
Water
8260B
LCSD 490-553044/7
Lab Control Sample Dup
Total/NA
Water
8260B
490-161980-B-9 MS
Matrix Spike
Total/NA
Water
8260B
490-161980-C-9 MSD
Matrix Spike Duplicate
Total/NA
Water
8260B
Analysis Batch: 554017
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161924-1
SW-01 OLD
Total/NA
Water
8260B SIM
490-161924-2
SW-02 OLD
Total/NA
Water
8260B SIM
490-161924-3
Trip Blank
Total/NA
Water
8260B SIM
MB 490-554017/8
Method Blank
Total/NA
Water
8260B SIM
LCS 490-554017/4
Lab Control Sample
Total/NA
Water
8260B SIM
LCSD 490-554017/5
Lab Control Sample Dup
Total/NA
Water
8260B SIM
490-161980-D-6 MS
Matrix Spike
Total/NA
Water
8260B SIM
490-161980-E-6 MSD
Matrix Spike Duplicate
Total/NA
Water
8260B SIM
Metals
Prep Batch: 418102
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161924-1
SW-01 OLD
Total/NA
Water
7470A
490-161924-2
SW-02 OLD
Total/NA
Water
7470A
MB 400-418102/14-A
Method Blank
Total/NA
Water
7470A
LCS 400-418102/15-A
Lab Control Sample
Total/NA
Water
7470A
400-161102-1-6-E MS
Matrix Spike
Total/NA
Water
7470A
400-161102-1-6-F MSD
Matrix Spike Duplicate
Total/NA
Water
7470A
Prep Batch: 418239
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method Prep Batch
MB 400-418239/1-A
Method Blank
Total/NA
Water
3010A
LCS 400-418239/2-A
Lab Control Sample
Total/NA
Water
3010A
400-161100-G-1-B MS
Matrix Spike
Total/NA
Water
3010A
L400-161 1 00-G- 1 -C MSD
Matrix Spike Duplicate
Total/NA
Water
3010A
Analysis Batch: 418545
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161924-1
SW-01 OLD
Total/NA
Water
7470A
418102
490-161924-2
SW-02 OLD
Total/NA
Water
7470A
418102
MB 400-418102/14-A
Method Blank
Total/NA
Water
7470A
418102
LCS 400-418102/15-A
Lab Control Sample
Total/NA
Water
7470A
418102
400-161102-1-6-E MS
Matrix Spike
Total/NA
Water
7470A
418102
400-161102-1-6-F MSD
Matrix Spike Duplicate
Total/NA
Water
7470A
418102
Analysis Batch: 420004
Lab Sample ID
Client Sample ID
Prep Type
Matrix
Method
Prep Batch
490-161924-1
SW-01 OLD
Total/NA
Water
6010D
TestAmerica Nashville
Page 21 of 29 11/20/2018

QC Association Summary
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
Metals (Continued)
Analysis Batch: 420004 (Continued)
Lab Sample ID
Client Sample ID
490-161924-1
SW-01 OLD
490-161924-2
SW-02 OLD
490-161924-2
SW-02 OLD
MB 400-418239/1-A
Method Blank
LCS 400-418239/2-A
Lab Control Sample
400-161100-G-1-B MS
Matrix Spike
400-161100-G-1-C MSD Matrix Spike Duplicate
TestAmerica Job ID: 490-161924-1
Prep Type
Matrix
Method
Total/NA
Water
SM 2340B
Total/NA
Water
6010D
Total/NA
Water
SM 2340B
Total/NA
Water
6010D
Total/NA
Water
6010D
Total/NA
Water
6010D
Total/NA
Water
6010D
Prep Batch
418239
418239
418239
418239
Page 22 of 29
TestAmerica Nashville
11 /20/2018

Lab Chronicle
Client: Anchor QEA of North Carolina PLLC
Project/Site: Madison Co Closed Landfill SW DW
TestAmerica Job ID: 490-161924-1
Client Sample ID: SW-01 OLD
Lab Sample ID: 490-161924-1
Date Collected: 10/24/18 14:16
Matrix: Water
Date Received: 10/25/18 09:25
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Analysis 8260B
1
10 mL
10 mL
553044
10/26/18 22:17
SW1 TAL NSH
Total/NA Analysis 8260B SIM
1
10 mL
10 mL
554017
10/31/18 21:34
S1S TAL NSH
Total/NA Analysis 6010D
1
420004
11/16/18 15:27
GESP TAL PEN
Total/NA Prep 7470A
40 mL
40 mL
418102
11/02/18 11:13
JAP TAL PEN
Total/NA Analysis 7470A
1
418545
11/06/18 09:24
JAP TAL PEN
Total/NA Analysis SM 2340B
1
420004
11/16/18 15:27
GESP TAL PEN
•
Client Sample ID: SW-02 OLD
Lab Sample ID: 490-161924-2
Date Collected: 10/24/18 14:43
Matrix: Water
Date Received: 10/25/18 09:25
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Analysis 8260B
1
10 mL
10 mL
553044
10/26/18 22:43
SW1 TAL NSH
Total/NA Analysis 8260B SIM
1
10 mL
10 mL
554017
10/31/18 22:01
S1S TAL NSH
Total/NA Analysis 6010D
1
420004
11/16/18 15:30
GESP TAL PEN
Total/NA Prep 7470A
40 mL
40 mL
418102
11/02/18 11:13
JAP TAL PEN
Total/NA Analysis 7470A
1
418545
11/06/18 09:26
JAP TAL PEN
Total/NA Analysis SM 2340B
1
420004
11/16/18 15:30
GESP TAL PEN
Client Sample ID: Trip Blank
Lab Sample ID: 490-161924-3
Date Collected: 10/24/18 01:01
Matrix: Water
Date Received: 10/25/18 09:25
Batch Batch
Dil
Initial
Final
Batch
Prepared
Prep Type Type Method
Run Factor
Amount
Amount
Number
or Analyzed
Analyst Lab
Total/NA Analysis 8260B
1
10 mL
10 mL
553044
10/26/18 21:50
SW1 TAL NSH
Total/NA Analysis 8260B SIM
1
10 mL
10 mL
554017
10/31/18 22:29
S1S TAL NSH
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TAL PEN = TestAmerica Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
TestAmerica Nashville
Page 23 of 29 11/20/2018

Method Summary
Client: Anchor QEA of North Carolina PLLC
TestAmerica Job ID: 490-161924-1
Project/Site:
Madison Co Closed Landfill SW DW
Method
Method Description
Protocol
Laboratory
8260B
Volatile Organic Compounds (GC/MS)
SW846
TAL NSH
8260B SIM
Volatile Organic Compounds (GC/MS)
SW846
TAL NSH
6010D
Metals (ICP)
SW846
TAL PEN
7470A
Mercury (CVAA)
SW846
TAL PEN
SM 2340B
Total Hardness (as CaCO3) by calculation
SM
TAL PEN
3010A
Preparation, Total Metals
SW846
TAL PEN
5030B
Purge and Trap
SW846
TAL NSH
7470A
Preparation, Mercury
SW846
TAL PEN
Protocol References:
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 ='Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL NSH = TestAmerica Nashville, 2960 Foster Creighton Drive, Nashville, TN 37204, TEL [phone]
TAL PEN = TestAmerica Pensacola, 3355 McLemore Drive, Pensacola, FL 32514, TEL [phone]
TestAmerica Nashville
Page 24 of 29 11/20/2018

Accreditation/Certification Summary C
Client: Anchor QEA of North Carolina PLLC TestAmerica Job ID: 490-161924-1
Project/Site: Madison Co Closed Landfill SW DW
Laboratory: TestAmerica Nashville
Unless otherwise noted, all analytes for this laboratory were covered under each accreditation/certification below.
Authority Program
North Carolina (WW/SW) State Program
EPA Region Identification Number Expiration Date
4 387 12-31-18
The following analytes are included in this report, but the laboratory is not certified by the governing authority. This list may include analytes for which
the agency does not offer certification.
Analysis Method Prep Method Matrix Analyte
8260B SIM Water 1,4-Dioxane
Laboratory: TestAmerica Pensacola
All accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority
Program
EPA Region
Identification Number
Expiration Date
Alabama
State Program
4
40150
06-30-19
ANAB
ISO/IEC 17025
L2471
02-22-20
Arizona
State Program
9
AZ0710
01-12-19
Arkansas DEQ
State Program
6
88-0689
09-01-19
California
State Program
9
2510
06-30-19
Florida
NELAP
4
E81010
06-30-19
Georgia
State Program
4
E81010 (FL)
06-30-19
Illinois
NELAP
5
200041
10-09-19
Iowa
State Program
7
367
08-01-20
Kansas
NELAP
7
E-10253
10-31-18 "
Kentucky (UST)
State Program
4
53
06-30-19
Kentucky (WW)
State Program
4
98030
12-31-18
Louisiana
NELAP
6
30976
06-30-19
Louisiana (DW)
NELAP
6
LA180023
12-31-18
Maryland
State Program
3
233
09-30-19
Massachusetts
State Program
1
M-FL094
06-30-19
Michigan
State Program
5
9912
06-30-19
New Jersey
NELAP
2
FL006
06-30-19
North Carolina (WW/SW)
State Program
4
314
12-31-18
Oklahoma
State Program
6
9810
08-31-19
Pennsylvania
NELAP
3
68-00467
01-31-19
Rhode Island
State Program
1
LAO00307
12-30-18
South Carolina
State Program
4
96026
06-30-19
Tennessee
State Program
4
TN02907
06-30-19
Texas
NELAP
6
T104704286-18-15
09-30-19
US Fish & Wildlife
Federal
LE058448-0
07-31-19
USDA
Federal
P330-18-00148
05-17-21
Virginia
NELAP
3
460166
06-14-19
Washington
State Program
10
C915
05-15-19
West Virginia DEP
State Program
3
136
06-30-19
" Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 25 of 29
TestAmerica Nashville
11 /20/2018

Test medca
THE LEADER IN ENVIRONMENTAL TESTING
Nashville, TN COOLER RECEIPT FORM
490-161924 Chain of Custody
Cooler Received/Opened On 10125/2018 9- 0925
j L,
1�i
Time Samples Removed From Cooler r � Time Samples Placed In Storage
(2 Hour Window)
1. Tracking # (last 4 digits, FedEx) Courier: FedEx
IR Gun ID 17610176 Strip Lot
pH Chlorine Strip Lot
2. Temperature of rep. sample or temp blank when o ened: 'r __Degrees; Celsius
3. If Item #2 temperature is 0°C or less, was the representative sample or temp blank frozen?
YES N ...NA
4. Were custody seals on outside of cooler?
YE ...NO ... NA
If yes, how many and where:
5. Were the seals intact, signed, and dated correctly?
E ...NO...NA
6. Were custody papers inside cooler? �Q
YE ...NO...NA
I certify that I opened the cooler and answered questions 1-6 (intial)
7. Were custody seals on containers: YES and Intact
Were these signed and dated correctly?
YES ... NO.. 11�A
8. Packing mat'I used? B iewra)p Plastic bag Peanuts Vermiculite Foam Insert Paper
Other None
9. Cooling process: /Icy'�Ice-pack Ice (direct contact) Dry ice
is
Other None
10. Did all containers arrive in good condition (unbroken)?
E _NO ... NA
11. Were all container labels complete (#, date, signed, pres., etc)?
..NO ... NA
12. Did all container labels and tags agree with custody papers?
&E�..NO... NA
13a. Were VOA vials received?
�... NO ... NA
b. Was there any observable headspace present in any VOA vial?
YES..,Ko... NA
40
Larger than this.
14. Was there a Trip Blank in this cooler? ...
NO ... NA If multiple coolers, sequence #
I certify that I unloaded the cooler and answered questions 7-14 (intiall
15a. On pres'd bottles, did pH test strips suggest preservation reached the corre t level? YES ... NO&
b. Did the bottle labels indicate that the correct preservatives were used W..NO... NA
16. Was residual chlorine present? YES ... NO.. PYA�
I certify that I checked for chlorine and pH as per SOP and answered questions 15-16 (intial) v
17. Were custody papers properly filled out (ink, signed, etc)? ...NO ... NA
18. Did you sign the custody papers in the appropriate place? Y,L4 ... NO ... NA
19. Were correct containers used for the analysis requested? GCdFySd ...NO...NA
20. Was sufficient amount of sample sent in each container? ...
NO ... NA
I certify that I entered this proiect into LIMS and answered questions 17-20 intial tJ
1 —fifv fhaf I nff—h—f a I.h.1 .ifh fho nninnn I IRAQ n—h— fn —1, /L,4hn /ll
21. Were there Non -Conformance issues at login? YES.. Was a NCM generated? YF�&I ...#
BIS = Broken in shipment
Cooler Receipt Fonn.doc LF-1 Revised 8/23/17
End of Form
Page 26 of 29 11/20/2018

a
y
v
?
O
X CZNNNfALL ^�
=Z'�ZZ Z2 Q� ao
u-
C
oaf\
E
E
2 Z 0 CL 0 w c)r7>N
d
N
0
!_
V"
U
U
N
o
0
U p
G
J
r
n
C
of
N
O
o
Q O
N
L
Zm
»m.
Q
w UO �CC •c, m0 E 3��
O
N
••
SZNZ Z�Q Q ow W L
'
C
O lL
.l
\\V...)
U'tp_O
d
w Qm Uo WLLU'S �Y p
e u
t
\
- s�airleauoo;o JagwnN telnl
IZI
y
i
�
m
u
d
d
E
E
o
0
0
Z
m It
\
N
H o
U
N
yyj .y
ro
CD
C
E
>
is
E
0
J17? -•
0
;9n ia6ue1 WiS (aow) - WIS 809L9
a
sa.JelOA I xlpueddtl- 809L8
Q-
�.
4 c?
y
n
r
n
T
E
Wlu 8o9L9'8o9L8
d.
7�q
>
%
N
IY
c
a
U
0!
0
VOLK'0ows
o"
,
Y
U
m
6�
in
vai
, r (oN ap•,eaA) a$ oad
.(oN
ia:saA)
eldweS
palamld Plaid
a
1g a„
(D,
N
J=
WY
[�
E
m
T
E
3 m a F
>
o
E
E
�
m
�
•@
U
U
U
F" U a7
ro_
YJ
o
�}
,Iv
TT73
�
aro
x
`9
w F-
MWO
u
U)
c
co
30
A
m
y�
O
O
✓
m
m
a
N
#-t
a
g
E
E
LE
ff
o
m
r
O(�.
a tL
3
a v
ai
w
o
y
a
0"
ro
C
N
CL
0
�
o
m
ro
c
O
o
U
E
8
=
mC
c
=
cIl
-
ro
e'
C
v
g
aLJ
y
B o
Zcy
n
O
O
%h
O
U
C
N
n
54
O
00
a
v
.. �
n O7
/ro��
G
m c
Z O
!
O
O
N
m
ro o
Y
r
w
w
o}
•
m
o G
'O
L•
E rn
ro
a
U 00
U Q
M
Q N
U Q
6 Z
a
w n
E
LL�
m
N
UJ
n
F
R
0
W
�
of
of
Page 27 of 29
11 /20/2018

N
m
O
U
d m
o E
$
T
y
_
ag
CO
N O Z O N N O a d V x t
O
N O
n
6
6
S Z Q Z Z Z 2
O
O
v i � Z O a 0 m U) > N
N
U
U
U
c
o
c
O
? o
0
�
N
O
O m v r
q x ma �2 n Q
oy
a
1
CD
s�
xo 0 3�<
Q Q NO�� w
U.O
u_
UO
P OI
p
SZ NZZ� u
o m
O rn
m
o
ap
N V
m
sj8u!8ju00 j0 jagwnN lejoi
?o D
Q N
)
'
6
E
E
E
E
z
m u
a T
w
!
m
EE
-
o
o
iJ
o
a
Z
y
@
c
Qo
E
m
0
N
'
E
E >
N ti
o
M
` 1
d
Q
v o
y
O
-
o
mr
a)
rD
V O O
E
E
VI
�z°
F75c
mN
o o
a
O
52-
o
to
ma
m
Q
a�
m
.o
� -
U
T
E
m
S@
m
o b
Q
Q
c
6
.0
c
=
N
d 0
(pajeholeo) £OOeO se ssaupJeH VOLO£180V£ZWS
X
X
o'
S E
0
-
On ms
h
c
>
o
F
(VtlhO) runways dad VOL7LM014L
X
X
U o
O
c
d
u
m
o p
A E m
�Ow
If
b
U
slelaW V210?1100W) VOLO£I00L09
X
X
o a
o m u
ii
cu
u�
d m
O Lo se woo a
( N A) GSW/SW iJ d
(ON JO saA) eldweS pajajl!d plaid
N@
6
o, o
r
a Q
L
� O
_ _
m
�T
u
0
f6
>>
I9
>
D
m a
m
O
O
5.t y
U
U
o
U
M
N
O a
O ti 0
a d O N
o
tE�
o U(�
E 2
a�o
O
E
n�A
N
s
a N
cD N
,a
y �
w .0
co
m r
-
T
(n
w�
w
o m rn
y N w T O
m
O@
a
N
V
C
N
K O
W
N
V
V
O
O
F
tt
y
D
T
~
o
o
O
'-
it
#
m o
p
m
E
O
O
o�
U
o` m
D_
3
a` o
0
J T m
� A N
U O U
N O C
E o
gmm
o �
D
9
rno �
u
f0
c m D
N
r
0
U
U C
g o a
v
Z
@
X
.0
m U N
L
N
C
LL
O
J
y
O
T
U
n=
c
o
o
N o m
O
-
w
c
m
d
N
o
E
m
-
U
90
O
-
N
o
Ln
co
N
J
c
O
m
rn
U= E
2c
N a 0
c
41
N
L
u
N
O
O
(D
u)
O
C
fC6
N
N
U
O c
Q
Q
N
U
J
0
p
~
O
U
'C
Y
O)
V
J
A
t0 a
N
�`
D
D
0
(n N
N
C"d
0)
m
aEi
o
EU
J
J
O
u Ea'
a �
w
m
t
�T
—=
o c
E
cJi
✓�
U
n to
Z O
N
� Tm
N a
�
T
j
c
y
U a
nm)
E
m d o
y cCa
n
c
E
(J
y L
o
a m
>' N
J
O u7
a.0
E
o t0
a�
R
m
(n
(n
(n
2 u
4
O
W
K
d
U
C)
Ur
are
�d
yLL
w
Page 28 of 29
11 /20/2018

Client: Anchor QEA of North Carolina PLLC
Login Number: 161924
List Number: 2
Creator: Perez, Trina M
Question
Login Sample Receipt Checklist
Answer Comment
Radioactivity wasn't checked or is </= background as measured by a survey
N/A
meter.
The cooler's custody seal, if present, is intact.
True
Sample custody seals, if present, are intact.
N/A
The cooler or samples do not appear to have been compromised or
True
tampered with.
Samples were received on ice.
True
Cooler Temperature is acceptable.
True
Cooler Temperature is recorded.
True
COC is present.
True
COC is filled out in ink and legible.
True
COC is filled out with all pertinent information.
True
Is the Field Sampler's name present on COC?
True
There are no discrepancies between the containers received and the COC.
True
Samples are received within Holding Time (excluding tests with immediate
True
HTs)
Sample containers have legible labels.
True
Containers are not broken or leaking.
True
Sample collection date/times are provided.
True
Appropriate sample containers are used.
True
Sample bottles are completely filled.
True
Sample Preservation Verified.
True
There is sufficient vol. for all requested analyses, incl. any requested
True
MS/MSDs
Containers requiring zero headspace have no headspace or bubble is
N/A
<6mm (1/4").
Multiphasic samples are not present.
True
Samples do not require splitting or compositing.
True
Residual Chlorine Checked.
N/A
3.0°C IR-7
Job Number: 490-161924-1
List Source: TestAmerica Pensacola
List Creation: 10/27/18 11:19 AM
TestAmerica Nashville
Page 29 of 29 11/20/2018