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HomeMy WebLinkAbout22065_ATCO Rubber Products_PIIR_20150515TM SOIL AND GROUNDWATER ASSESSMENT REPORT ATCO PROPERTY 2806 PATTERSON STREET GREENSBORO, GUILFORD COUNTY, NORTH CAROLINA ECS PROJECT 09.25395 PREPARED FOR: JE CAPITAL, LLC GREENSBORO, NORTH CAROLINA MAY 15, 2015 9i ECS CAROLINAS, LLP "Setting the Standard for Service" Geotechnicai • Construction Materials • Environmental • Facilities NC Registered Engineering Fi rm F- 1078 May 15, 2015 Mr. Eddie Krusch JE Capital, LLC P. O. Box 1195 Greensboro, North Carolina 27402 Reference: Soil and Groundwater Assessment Report ATCO Property 2806 Patterson Street Greensboro, Guilford County, North Carolina ECS Project 09.25395 Dear Mr. Krusch: As authorized by your acceptance of our Proposal 09.22984-P dated April 17, 2015, ECS Carolinas, LLP (ECS) has completed our Limited Soil and Groundwater Assessment Report for the above referenced site. Included in this report is a description of the field activities, the results obtained, and our conclusions and recommendations. We appreciate the opportunity to provide our services to you. If there are questions regarding this report, or a need for further information, please contact us at (336) 856-7150. Respectfully Submitted, ECS CAROLINAS, LLP RakrEnvironmental Cavallier SeProject Manager Jo n M. Stewart, P.G. •-Sief Geologist 4811 Koger Blvd., Greensboro, NC 27407 • T. 336-856-7150 • F: 336-856-7160 • www.ecsiimited.com ECS Capitol Services, PLLC • ECS Carolinas, LLP • ECS Central, PLLC • ECS Florida, LLC • ECS Mid -Atlantic, LLC • ECS Midwest, LLC • ECS Southeast, LLC • ECS Texas, LLP TABLE OF CONTENTS 1.0 PROJECT INFORMATION...........................................................................................................1 2.0 FIELD ACTIVITIES.......................................................................................................................2 2.1 Soil Assessment................................................................................................................. 2 2.2 Groundwater Assessment................................................................................................... 2 3.0 LABORATORY ANALYSIS...........................................................................................................3 3.2 Groundwater Sample Analysis............................................................................................ 3 4.0 CONCLUSIONS...........................................................................................................................3 5.0 RECOMMENDATIONS................................................................................................................3 FIGURES Figure 1 Site Location Map Figure 2 Site Map Figure 3 Soil Sample Location Map — Diesel and Gasoline USTs Figure 3A Soil Sample Location Map — Heating Oil UST Figure 4 Groundwater Sample Location Map TABLES Table 1 Summary of Soil Analytical Results Table 2 Summary of Groundwater Analytical Results APPENDIX Appendix A Laboratory Data Sheets and Chain of Custody Records Soil and Groundwater Assessment Report ATCO Property 2806 Patterson Street Greensboro, Guilford County, North Carolina ECS Project 09.25395 May 15, 2015 1.0 PROJECT INFORMATION The site is the former ATCO Rubber Products, Inc. (ATCO) facility located at 2806 Patterson Street in Greensboro, Guilford County, North Carolina (Figure 1 and Figure 2). Based on the records search, site reconnaissance and interviews, the building was originally constructed as a potato chip manufacturing facility. The potato chip manufacturing business operated at the site until the early 1980s. The building was reportedly vacant for several years. In the mid-1980s, ATCO moved into the building. There was is no evidence that hazardous chemicals have been utilized at the site by ATCO during flexible ductwork production. The subject site is currently occupied by two buildings which were recently used to manufacture flexible ductwork and as a warehouse. A portion of the main building is currently used as an used automobile sales business. An old boiler is located in a room on the southeast side of the main building. The building boiler is no longer in use. It appears that the boiler last operated on natural gas; however, there is a copper line running from the boiler to the outside of the building indicating the use of fuel oil. There was no evidence that underground storage tanks (USTs) were registered at the subject site with the North Carolina Department of Environment and Natural Resources (NCDENR). However, our review of records at the Greensboro Safety and Fire Prevention Bureau identified documentation of several petroleum USTs that were previously located at the site. During our site reconnaissance, an area north of the building contained a concrete area, adjacent to the asphalt pavement. This area is believed to be the former location of a diesel UST. A second UST was believed to be located near the northwest corner of the warehouse and a third UST believed to be a heating oil UST is located south of the warehouse, near the former boiler room. The site is located in a light industrial/commercial area of Greensboro. The site is bound on the north by the Norfolk Southern railway property, on the east by light industrial/commercial properties, on the south by a light industrial/commercial building and Patterson Street and on the west by South Holden Road. Two properties (former Chemical & Solvent, Inc. and former Ashland Chemical) that previously contained chemical manufacturing/storage facilities are located on adjoining properties east of the site. Based on proximity, the releases form these properties are considered RECs of the site. Releases are identified at the Norfolk Southern railway property north of the site. Based on proximity and groundwater flow direction inferred from the surface topography, releases at this property could impact the property. ECS was contracted by Mr. Eddie Krusch to conduct a soil and groundwater assessment at the site to determine if the identified RECs could have impacted the site. Project information is based on a conversation between Mr. Krusch and Mr. Randy Cavallier of ECS, the previous Phase I ESA, and a recent site visit. Soil and Groundwater Assessment Report ATCO Property 2806 Patterson Street Greensboro, Guilford County, North Carolina ECS Project 09.25395 May 15, 2015 2.0 FIELD ACTIVITIES 2.1 Soil Assessment On April 28, 2015, nine soil borings were drilled at the site to assess whether the suspect USTs had had a release. Soil borings UST-1 A, UST-1 B and UST-1 C were drilled in the vicinity of the concrete patched area on the northern portion of the site (suspected former diesel UST location). Soil borings UST-2A, UST-213, UST-2C, and UST-2D were drilled in the vicinity of a second concrete patched area (suspected gasoline UST location) and soil borings UST-3A and UST-313 were drilled in the vicinity of the suspected fuel oil UST. The approximate locations of the soil borings are shown on Figure 3 and Figure 3A. ECS proposed drilling the borings to a depth of 15 feet below the ground surface (bgs); however, groundwater was detected at a depth of approximately 11 to 12 feet bgs, so the borings were terminated at 10 feet bgs. The soil borings were drilled using a track -mounted Geoprobe® drill rig. The Geoprobe® is capable of driving various forms of soil and groundwater sampling probes into the ground to depths equivalent to auger refusal. The Geoprobe® subcontractor used for this project was 3D Environmental Investigations, LLC (3D). The field activities were observed by an ECS professional. Prior to initiating the first boring and between each subsequent boring, the Geoprobe® down -hole equipment was decontaminated with a high-pressure steam cleaner. Soil samples were collected continuously from the ground surface to the termination depth of each boring. The soil from each boring was screened for relative levels of volatile organic vapors using the probe of a Thermo Model 2020 flame ionization detector (FID). To screen the samples, the soil from the borings was placed in resealable plastic bags and placed in a warm location for approximately ten minutes to allow the headspace in the bag to equilibrate with the soil. The probe of the FID was then inserted into the bag and the reading recorded. The soil sample from each boring with the highest reading on the FID was submitted for chemical analysis. Because the purpose of the assessment was to determine presence or absence of contamination, one sample from the gasoline UST area and one sample from the heating oil UST area were not submitted for analysis, since field conditions indicated the presence of a release. The sampler, wearing a new pair of nitrile gloves, placed the samples in laboratory prepared containers. Each container was labeled and placed in a cooler containing ice to maintain the samples at approximately 4° Celsius. The samples were transported to Research and Analytical Laboratories (R&A) in Kernersville, North Carolina to be analyzed for diesel range and gasoline range total petroleum hydrocarbons (TPH) EPA Methods 8015/3550 and 8015/5035, respectively. Chain of Custody Records were maintained and included in Appendix A. 2.2 Groundwater Assessment To determine if the groundwater beneath the site has been impacted from the USTs and off -site sources, four groundwater samples (GW-1 through GW-4) were collected at the site (Figure 4). The groundwater samples were collected by pushing a groundwater -sampling probe to the desired 2 Soil and Groundwater Assessment Report ATCO Property 2806 Patterson Street Greensboro, Guilford County, North Carolina ECS Project 09.25395 May 15, 2015 depth (generally five feet below the water table) and pulling back on the probe, exposing the sampling screen. A piece of dedicated polyethylene tubing was inserted down the probe to the depth of the screen. The tubing was connected to a peristaltic pump that was used to collect the sample. The groundwater samples were submitted to R&A and analyzed for volatile organic compounds (VOCs) and semi -volatile organic compounds (SVOCs) using Standard Method 6200B and EPA Method 625BNA, respectively. Upon completion of groundwater sampling activities, the temporary monitoring points were properly abandoned. A Chain of Custody Record was maintained and is included in Appendix A. 3.0 LABORATORY ANALYSIS 3.1 Soil Sample Results Laboratory analysis of soil samples UST-2A, UST-213, and UST-313 detected gasoline and diesel range TPH above the North Carolina Department of Environment and Natural Resources (NCDENR), State Action Level of 10 parts per million (ppm). The laboratory analytical results are summarized in Table 1. The laboratory data sheets are included in Appendix A. 3.2 Groundwater Sample Analysis Laboratory analysis of the samples GW-1, GW-2 and GW-4 detected 1,2-dichloropropane at concentrations that exceed the North Carolina 2L Groundwater Quality Standard (NC2LGWQS). Laboratory analysis of the samples GW-3 and GW-4 detected tetrachloroethene (PCE) at concentrations that exceed the NC2LGWQS. Ten additional VOCs were detected in sample GW-4 at concentrations that exceed their respective NC2LGWQS. The laboratory analytical results are summarized in Table 2. The laboratory data sheets are included in Appendix A. 4.0 CONCLUSIONS Based on the results of the limited soil and groundwater assessment, it is ECS's opinion that soil in the vicinity of the former gasoline UST and the heating oil UST have been impacted from releases or spills of petroleum products associated with the USTs. It is our opinion that the hydrocarbons detected in the groundwater are associated with releases from the off -site sources. 5.0 RECOMMENDATIONS Based on the laboratory analytical results of the samples collected during the recent soil and groundwater assessment, ECS understands that a reporting obligation exists. ECS recommended that a copy of the report be provided to the property owner and that they consult legal counsel regarding their reporting obligation. 3 Soil and Groundwater Assessment Report ATCO Property 2806 Patterson Street Greensboro, Guilford County, North Carolina ECS Project 09.25395 May 15, 2015 6.0 QUALIFICATIONS The activities and evaluative approaches used in this assessment are consistent with those normally employed in limited environmental assessment projects of this type. Our evaluation of site conditions has been based on our understanding of the site project information and the data obtained during our field activities on the date the samples were collected and from a limited number of sample locations. This report was prepared for the express use of JE Capital, LLC. Use of this report by any other individual or company implies their acceptance to the General Conditions of Service of the original contract. 4 FIGURES Hamiton Lakes ~ `. ; , - z to 'mount For St se H - Urlyl�r / I y SITE I r = - • east `'iiz tU'-nJ rk •. �. ' L,' r Ht— Se COtta BBI Post •• Q69�4 F z - `` ' • \ J � '• 1 •-r r r' r RM 7 • � mil` �,;�••� •ice `'�� � ; •i � �f ' : _ ��;�, � i i �� I �' _ `bsn -�% ••. } i ° V f -.I f' '...� '' f `i.` /� � 1, �( \�t 7 u , . � fP Y' i �... � , / ` r �b I 1 � •' •! 1 d its L' 4,� r • ' / � � f \� i \ Souib" } �I+ 1 Z_ ' �6Y •• \, \ rdt+ r, _ •� .. - r * . , -„� ` ,.. -•c;� Y a Ch, • • e>s �i � r � Y r ' Pd k "� 'F� '!t •i-�-��9TT�f'�f�.----=�v� � { . �_ SOURCE: w Eg FIGURE 1 USGS TOPOGRAPHIC MAP S SITE LOCATION MAP GREENSBORO, NC QUADRANGLE ATCO PROPERTY DATED 1951 AND REVISED 1994 2806 PATTERSON STREET GREENSBORO, NORTH CAROLINA SCALE 1"=2,000' �T ECS PROJECT NO. 09.25395 } Q77 AKLAND AV See Figure 3 Pal,..�• See Figure 3A -mow- # — R fir! 1! r f *1.r ' • !! MAN( Lt RD a T T FIGURE 2 SOURCE: S SITE MAP GUILFORD COUNTY GIS ATCO PROPERTY AERIAL PHOTOGRAPH, DATED 2010 2806 PATTERSON STREET GREENSBORO, NORTH CAROLINA SCALE: 1 " = 200' TM ECS PROJECT NO. 09.25395 0, r ,` x ,r`L ', V Rai •'� �� y�• ' � w,I - ✓ i 41:5 T r 1 r Ilk � I C I' N i w Eg SOURCE: FIGURE 4 GROUNDWATER SAMPLE LOCATION MAP GUILFORD COUNTY GIS ATCO PROPERTY AERIAL PHOTOGRAPH, DATED 2010 2806 PATTERSON STREET GREENSBORO, NORTH CAROLINA SCALE: NOT TO SCALE ECS PROJECT NO. 09.25395 Fence Former Diesel UST Excavation (Concrete) ----------- \ - -------------------- ------------------- UST-1 A • UST-1 C _._._._._._.-._.� _._ UST-1 B UST-2B1 ' UST-2A ± UST-2C • i Former Gasoline UST Excavation • i UST-2D ± i Grass N SOURCE: FIGURE 3 ECS FIELD NOTES s SOIL SAMPLE LOCATION MAP AND DRAWINGS ATCO PROPERTY 2806 PATTERSON STREET LLP GREENSBORO, NORTH CAROLINA SCALE: 1 INCH = 10 FEET ICIAR(OLLUH kls ECS PROJECT NO. 09.25395 Warehouse Building UST-3B • - - - - - - - - - - - I Vent Pipe 0 UST-3A 10,000 Gallon Fuel Oil UST Main— — — — — — — — — — — -- Building Debris N SOURCE: FIGURE 3A ECS FIELD NOTES s SOIL SAMPLE LOCATION MAP AND DRAWINGS ATCO PROPERTY 2806 PATTERSON STREET LLP GREENSBORO, NORTH CAROLINA SCALE: 1 INCH = 10 FEET ICIAR(OLLUM/I&IS1 ECS PROJECT NO. 09.25395 TABLES ATCO Property Greensboro, North Carolina TABLE 1: SUMMARY OF SOIL ANALYTICAL RESULTS ECS Project 09.25395 Parameter SOIL SAMPLING Comparison Criteria Sample Location Former Diesel UST Former Gasoline UST Heating Oil UST Sample ID UST-1 A UST-1 B UST-1 C UST-2A UST-213 UST-2C UST-211) UST-3A UST-313 StateAction Collection Depth (feet b g) 10 5 10 5 5 10 5 10 10 Collection Date 4/28/15 Total Petroleum Hydrocarbons by EPA Method 8015 following 3550/5035 Preparations GRO BQL 338 169 NA BQL 56.4 10 DRO BQL BQL BQL 2,210 654 NA NA BQL 447 10 Notes: Results presented in milligrams per kilogram (mg/kg), analogous to parts per million (ppm) Feet bgs = Feet below ground surface GRO = Gasoline Range Organics DRO = Diesel Range Organics BQL = Compound not detected at a concentration above the method quantitation limit Bold = concentration exceeds Action Level NA = Sample not submitted for analysis ATCO Property Greensboro, North Carolina ECS Project 09.25395 TABLE 2: SUMMARY OF GROUNDWATER ANALYTICAL RESULTS Parameter ANALYTICAL RESULTS NC2LGWQS GCL Location GW-1 GW-2 GW-3 GW-4 Date Sampled 4/28/15 Volatile Organic Compounds By EPA Method 8260 Benzene BQL BQL BQL 477 1 5,000 Chloroform BQL BQL BQL 2_B7 70 70,000 Cis 1,2-Dichloroethene BQL BQL BQL 574 60 60,000 Trans 1,2-Dichloroethene BQL BQL BQL 9 Fq 100 100,000 1,2-Dichlorobenzene BQL BQL BQL 42.0 20 20,000 1,3-Dichlorobenzene BQL BQL BQL 1.21 200 61,500 1,4-Dichlorobenzene BQL BQL BQL 7.94 6 6,000 1,1-Dichloroethane BQL BQL BQL 124 6 6,000 1,2-Dichloroethane BQL BQL BQL 9.08 0.4 400 1,1-Dichloroethene BQL BQL BQL 964 7 7,000 1,2-Dichloropropane 2.67 2.85 BQL 1.06 0.6 600 Isopropyl Ether (IPE) U�� BQL BQL V..., 70 70,000 I-Propylbenzene BQL BQL BQL 46 70 70,000 Naphthalene BQL BQL 3.13 1.57 6.0 6,000 Sec-Butylbenzene BQL BQL 0.71 BQL 70 8,500 Tetrachloroethene BQL BQL 1.45 68.5 0.7 700 Toluene BQL BQL BQL 45 600 260,000 Trans 1,2-Dichloroethene BQL BQL BQL 2.63 100 100,000 Trichloroethene BQL BQL BQL 117 3 3,000 1,2,4-Trichlorobenzene BQL BQL BQL 0.92 70 70,000 1,1,1-Trichloroethane BQL BQL BQL ).6 200 200,000 1,1,2-Trichloroethane BQL BQL BQL 23.9 0.6 600 Vinyl Chloride BQL BQL BQL 2.27 0.03 30 Total Xylenes BQL BQL BQL 64.0 500 500 Semi -Volatile Organic Compounds By EPA Method 8270BNA 1,2-Dichlorobenzene I BQL I BQL I BQL 33.2 20 20,000 Notes: Concentrations are presented in micrograms per liter, analagous to parts per billion NC2LGWQS= 15 A NCAC 2L.0202 Water Quality Standard GCL = Gross Contaminant Level Bold = Concentration exceeds the NC2LGWQS BQL = Below the reporting limit of the method of analysis APPENDIX A (Laboratory Data Sheets and Chain of Custody Records) 6 d v, O asZ pp O O e y � a O � � s 00 F a en Ir a 00 O , v en O Q a ` ^ O O M O � L w O a Q t M d O O N to d t} a w e 0 e a w ;,a 0 m w a n n n of n n 0 0 0 0 0 0 0 a _ _ 0 N N N N N i * to �o f` w 0, o " o 0 0 o O — a M M M M M M M f a � L C Uo U w ¢ m u ¢ m ¢ m w a w N N M M (= t= F d ° : > 0 > > E Q r _� Q Z� 0 � Q r1 W .� U i� Q 0 W O ° U Q a U U 'c tn ol U 1 e mCL F w Ix a� � � o o � o o � �+ o 00 0000 OMO DO 00 0000 0 � z 4 u Oc z to r4 O1 �o M O [� en O CD O_ N_ E N N N O O O O p O O O O 8 4 O O O O O O O O O O O C C II I - v C-0 C O d N 'o � y �Oli 3 M .� m ?A Vi m (� is Vj lCq) cc CD O m v') CI d 'O C es �r a E o 0 0 0 0 0 0 a rn � .o a d M h 6 N N r. E" N VJ O N •� O •a ml n 2 2 n n n 2 o f u Q 00 0 0 0 0 0 2 a L 00 eq 0 6V �N• N0 e`� O N O Neq O g is 'O O O O -tj •� _ E o � d ar � �' o 0 0 0 0 - y y •� a 00 00It 1 4 4 00 00e I ,; FQr M M en M M M M 0. .a a •y W II v a % •L e H £ � C en � eA Q O O U Ir Q 00 U Q W Q L1a II w G4 M M CE d � il FL U Q > > > > n¢ m 8 RESEARCH & ANALyTICAt LAbORATORIES, INC. AnaWal/Process Cortsultotlone Chemical Ail dysts jor Selected Parameters and Sampling Location IdendJied as Patterson 1, VoletQeOrganics Quantitation (.,W-1 GW-2 GW-s GWA EPA Method 82t50 B Llrnli Pruamda:r " UMN t"At) 1R1FJt) LUM Aiaaac 75 BQL BQL BQL BQL Acrolcin 501 BQL BQL BQL BQL Aayimikile 100 BQL BQL BQL BQL Bin 0 5 BQL I5Q1, BQL 47, Dtw^ - 0.5 BQL BQL BQL BQL Bromochlmamghmie C + Bizl. BQL UQL BQL Smmetihloaoorrtf`.me 0.5 BQL k1Q1. BQL BQL Bromofm]n 1.0 BQL BQL BQL BQL Bmniw=dwc 1.0 BQL BQL BQL BQL 2-Butmo¢e 35 HQS BQL LIQ3, BQL Carbon Dmdfide 5.0 BQL BQL BQL BQL Carbon Tcaaeblondo 05 BQL BQL BQL BQL Chlaobarme 0.5 BQL BQL BQL BQL. Chloroodume 1.9 BQL BQL BA�L BQL 2-0doroethyl vinyl ether 5.0 BQL BQL BQL BQL Chloroform 0.5 BOL. BQL BQL 2.67 CLH. q .&+ -.e 1.0 BQL BQL BQL 2-Qdoromtueae 0.5 BQJ- BQL BQL. BQL 4 Cldorna.-jrnr 0.5 BQI- BQL BQL BQL Cis-1,2-Diddoroetlfau 0 5 BQL U(U[- BQL 5.74 Cis-1,3-Dichlmopropene 05 BQL BQL BQL BQL 1.2-Ihkolro-S.Cld¢opvpone?!}IIfd�} 5.0 BQL BQL 1HQ1. 9Q1, 1,2-Dibtonrocthax (EDB) 0.5 BQL BQL BQL BQL ELwar^sch�oramelhox 0.5 BQL BQL BQL BQL Ltk:urrtmrihmrc 0.5 BQL HQ1. BQL BQL 1,2-DiehlorobeKene 0.5 BQL F1Q1. BQL ILO 1,3-Diclilmbentta r `. BQL BQL BQL 1.21 1,1-Dichlorobmmre 0.5 BQL BQL BQL 734 1,1-Dicblorodhene 0.5 BQL BQL BQL 124 1,2-Diehloroethane 0.5 BQL BQL BQL 4-41111 1,1-Dicb1oroatl ma 0.5 BQL BQL BQL 9M DiddoroBoummahmw 0.5 BQL BQL 9i?L, 31Qi. 1,2-DicItlotapropena 0.5 2.67 3M i. 3 A6 0-Diddorvpropmm 0.5 HQ2 BQL BQL BQL 2,2-Dieblomprvpmw 0.5 fiQ3. BQL BQL BQL 1,1-Dic6lmopropma 0.5 BQl. H-x I BQL BQ1, Ethyl Bermme R5 BQL BQL BQL BQL 2-Hasanaee 5.0 BQL BQL BQL BQL IPE AS BQL BQL BQL 030 1-Propy@mzme 0.5 BQL BQL BQL 1.46 4-Medryl-2-Partmone 5.0 BQL BQL Hf%Vl, BQL Methyl Iodide 1.0 BQL BQL BQL BQL Mahy2®a Chloride 5.0 BQL BQL 9Qi- BQL "ME 0.5 BQL RQi. BQL 00L NapWWeue 0.5 BQL BQL 3.13 1.57 N-Bulylbm teae 0.5 BQL 1101. 13QL n1ji . N-Prapylb®me 0.5 BQL BQL BQL BQL P-bowopyltolune 0.5 HQL BQL BQL BQL See-BuWbcu= 0.5 BQL BQL R71 BQL SiyC 0.3 BQL BQL BQL BQL Tert-Butyl6etuara 0.5 100L BQL BQL BQL 1,1,1,2-Tatra ltlorocthara D 4 BQI- BQL BQL BQL 1,1,2,2-TentWorceadu a 0.5 HQ1. BQL BQL GQL 'ria'rw?.ircaedxe 0.5 BQL BQL 1.45 M5 Toluene 0.5 BQL BQL BQL 1.44 Trars-1,2-Dicbloroethmm 0.5 BQL BQL BQL r.ba Ttars-0-Diebloropropenc 0.5 BQL BQL BQL BQL Trap-1,4-Dichloro-2-butene 5 0 BQL BQL BQL BQL 1,2,3 Triddorebmzme 0.5 BQL, BQL BQL BQL 1,2,4-Triahlorobmmu 415 BQL BQL BQL 0-92 l,l,l-Trirbloroah®a 0.5 BQL BQL BQL 10A 1,1,2-Tricidaroethaoe 0.5 BQL Hs r7 HQI . 23.9 Triddoroethme 0.5 BQL BQL BQL 117 TriddoruP,rormwlic; 0.5 BQL BQL BQL BQL 1,2,3Trichloropn4w 0.5 BQL BQL BQL BQI. 1,2,44rhuethylbeazaoa 0.5 BQL BQI. BQL BQL 1,3,5-Trimahylbamme u '- BQL 11Qi BQL BQL Vinyl Acetate 1.0 BQL BQL SOL BQL Vinyl Cblcrida f3 ` BQL BQL F3Q1 2.27 ToW Xylem I 0 BQL BQL BQL 64.0 Dilution Faaror I I i I Sample Number 3594-01 3594-02 3584-03 3594.04 Sample Date 0428/15 0429115 04/29/15 0428/15 Sample Time (hn) 1100 1130 1220 1330 Date Analyzed 04/30/15 04/30/15 04/30/15 04/30/15 Time Analyzed 1541 1613 1645 1717 Surrogate Recovery (DBFM) Range (70-130%) 103% 102% 109% 104% Surrogate Recovery (Toluene-d8) Range (70-130%) 98% 98% 98% 123% Surrogate Recovery (4-BFB) Range (70-1301/6) 93% 96% 93% 93% BQL - &low QmodMdw Limit ppb - Pub Per bM- RESEARCh & ANA1yTiCAL LABORATORIES, INC. Analytical/Process Consultations Chemical Analysis for Selected Parameters and Sampling Location Identified as Pagerson �,�'(Irolltras. LIPFraka[. rol�rcted.��r�p.,#QI _ - II, Semi-VolatileOMBuics Quamtlltation GW-2 (;W.3 G'W4 a EPA Method 8270 BNA haft PyrsmgU &W b-2h1) t224) (22bl 4-Chloro-3-methylphoW 10.0 BQL BQL BQL 2-0lorophmol 10,0 BQL 6QL E [QL. 2,4-DicLioropheool 10.0 BQL BQL BQL 2,4-1)i nedylphemol 10.0 BQL 0Q1. BQL 2,4-DWtrophmo1 50.0 BQL Bt tl, BQL 2-Methyl-4,64khropheaol 50.0 BQL BQL BQL 2-Nitropbmol 10.0 BQL BQL BQL 4-Nitrop6mol 50.0 BQL BQL BQL Pcmtuhlorophcaol 50.0 BQL 9Q1. BQL 19Mm1 10.0 BQL BQL BQL 2,4,6-Trichlorophemo1 10.0 BQL BQL BQL &WWM m 10.0 BQL HQ1. BQL Apmzpb ft1cflc 10.0 BQL BQL BOL AMP E 10.0 BQL BQL BQL HeU&M 50.0 8QL BQL BQL OgP*MPMditU g 10.0 HQL BQL BQL Be1z4!4a1M=C 10.0 BQL BQL BQL benw*)Oufthurthmc 10.0 BQL BOL BQL Betat(gbd)pray'leee 10.0 BQL BQL BQL Boteo(O T^ M&� 10.0 BQL BQL BQL B--A butyl ph&Bb to 10,0 BQL BQL BQL BI�2chltlhiktitJWyime�r�r. 10.0 BQL 13rl . BQL Bis(2-ddomdhy4)Cthc+ 10.0 WiL HQL BQL Bis(2-ch1oroisttpw"1)cthcr 10.0 LIQt. i1Q1. BQL Bis(2-c&ybhezyl)phth&l- 10.0 BQL BQL BQL 4-Hromophemyl pbemyl ether 10.0 BQL BQL BQL 2-ChlmomephdWeme 10.0 BQL BQL BQL 4-Chloroph®yl phemyl ether 10.0 BQL BQL BQL i2nywe 10.0 BQL BQL BQL Dibe=0 hjtmlt rz=nc 10.0 BQL BQL BQL 1,2-Dichlorobeni me 10.0 1JQL BQL 33.2 1,3-Dichlorobmeemc 10.0 BQL BQL BQL l,4-Dkh1orobmuae 10.0 BQL BQL BQL 3,3-DichlorobeaMinc 20.0 0Q1. BQL BQL Diethyl phthalate 10.0 13QL BQL BQL Dimethyl phthmleu 10.0 BQL BQL BQL DI-N-BOA phthalate 10.0 BQL BQL BQL 2,4-Ditrimotmlucac 10.0 BQL BQL BQL 2,6-OWUntotune 10.0 BQL BQL BQ1, Di-N-Ouyl phth-I 10.0 BQL BQL UQq- 1.2-DiphenyMydnizice 50.0 BQL BQL BQL fl: rmrd= 10.0 BQL BQL BQL FLu 10.0 BQL BQL BQL Hw=Morobmrmo 10.0 BQL BQL BQL Hexarhlombun dkme 10.0 BQL BQL Aql, �Itrdoe�e 10.0 BQL Hql . BQL HaoeehGoroeO��e 10.0 BQL BQL BQL Imdmo(1,2,3-od) pyreme 10.0 BQL BQL BQL Isophacae 10.0 BQL BQL BQL Naphtheleme 10.0 BQL BQL BQL Nmo 10.0 BQL BQL BQL N-Niuosodimethylemime 10.0 BQL BQL BQL N-nimosodi-m�brume 10.0 BQL BQL BQL N-NimosodkphmybMine 10.0 F3gl . BQL BQL Phm"locnp 10.0 L3{ZL BQL BQL Fyraee 10.0 BQJ. VQL. BQL 1,2,4-Triddorobenzmo 10.0 IIQI . BQL BQL 2-MethyhtaphthOwe 10.0 13UL BQL BQL 1-Me1hyhmphdWcoe 10.0 BQL BQL OM Muctiam Facinr I I I Sample Number 3584-02 3584-03 3584-04 Sample Date 04/28/15 04/28/15 04/28/15 Sample Time (bra) 1130 1220 1330 Date Ertratxed 04/30/15 04/30/15 04/30/15 Date Analyzed 05/04/15 05/04/15 05/04/15 Time Analyzed 0236 0304 0333 Surrogate Recovery Range (2-FlmorophenoQ (21-110%) 39% 42% 46% (Phemol-d6) (10-I 10%) 26% 29% 36% (Nltrobenzeae-d5) (35-114%) 82% 87% 83% (2,4,6-Tribromophenol) (10-123%) 85% 73% 79% (2-FtuoroblphenyQ (43-116%) 82% 69% 95% (4-Terpheny"14) (33-141%) 69% 63% 65% BNA - Bsse Namd Acid lictramblm ppb - pats per btmw pl;. it 0 I dos _5!H'H ')dV 4 � \ o u cc f — 7—� 2 IL . [CIL:let , cc co) d m M N W CO o ) to CU M r.Tu O H a \� I. cc C9 Z06Z'ON 0 );Iuao Aaa,ans uiys id0�:� MZ '66 �dy RESEARCh & ANA[yTICAI LABORATORIES, INC. Analytical/Process Consultations Four (4) water and seven (7) soil samples were received in good condition on 29 April 2015. The samples were analyzed without difficulties unless noted below. Sidney L. Champion Director of Laboratory Services 5-5-[5 Date P.O. Box 473 • 106 Short Street • Kernersville, North Carolina 27284. 336-996-2841 • Fax 336-996-0326 www.randalabs.com QA/QC Summary Method: ZOOB 5/10 20/ 0 001000 PPB C FILE NAME: W C0430 CLIENT: ECS CAROLINAS(PROJECT: PATTERSON Sample ID: 3584 - 01- 04 INSTUMENT: MS-2 Page 1 of 2 Extraction Method NIA Date Extracted N/A Weight Extracted 25ML Final Extract Volume 25ML Date Anglyzed 04/30/15 % Surrogate Recovery 99 97 94 Acceptance Range (70-130) (70-130) (70-130) LCS Acceptance Range MS MSD RPD QC LIMITS Compound MDL Method LCS % % Rec. % Rec. RPD % REC u Blank Recovery DICHLORODIFLUOROMETHANE 0.12 ND 84 70-130 CHL-OROMETHANE 0.07 ND 72 70-130 VINYL CHLORIDE 0.11 NV 96 70-130 BROMOMETHANE 0.18 ND 77 70-130 CHLOROETHANE 0.11 ND 95 70-130 TRICHLOROFLUOROMETHANE 0.09 ND 100 70-130 ACETONE 1.18 ND 90 70-130 ACRYLONITRILE 12.38 ND 110 70-130 2-BUTANONE 0.88 ND 88 70-130 IJ-DICHLOROETHENE 0.09 ND 99 70-130 102 110 7 14 70-130 METHYL IODIDE 0.19 ND 84 70-130 CARBON DISULFIDE 0.45 ND 100 70-130 MEniYLENECHLORIDE 0.57 ND 97 70-130 TRANS-1,2-DICHLOROETHENE 0.10 ND 97 70-130 I,1-DICHLOROETHANE 0.17 ND 101 70-130 ISOPROPYLETHER(IPE) 0.12 ND 96 70-130 M> TIM-TRT-Burn ETHERO.ME) 0.16 N D 88 70-130 VINYL ACETATE 0.24 ND 84 70-130 CIS-1,2-DICHLOROETHENE 0.09 ND 95 70-130 ,2-DICHLOROPROPANE 0.09 ND 99 70-130 BROMOCHLOROMETHANE 0.12 ND 87 70-130 CHLOROFORM 0.05 ND 96 70-130 1.1.1-TRICHLOROETHANE 0.12 ND 103 70-130 CARBON TETRACHLORIDE 0.10 ND 104 70- 1 3 0 l,l-DICHLOROPROPENE 0.12 ND 102 70-130 BENZENE 0.05 ND 99 70-130 100 lI}2 2 11 70-130 ETHYLACETATE 0.35 ND 88 70-130 1,2-DICHLOROETHANE 0.09 ND 97 70-00 TRICHLOROETHENE(TCE) 0.12 ND 101 70-130 98 100 2 14 70-130 11,2-DICHLOROPROPANE 0.10 ND 99 70-130 DIBROMOETHANE 0.25 ND 96 70-130 COMMENTS: QA/QC Summary Method: QW&MMOLUMMIM0 PP FILE NAME: W C0430 Page 2 of 2 CLIENT: ECS CAROLINASPROJECT: PATTERSO SAMPLE ID: 3584 - 01- 04 LCS Acceptr ange MS MSD RPD QC LIMITS Compound MDL Method LCS % RPD % REC ug/L Blank Recovery % Rec. % Rec. BROMODICHLOROMETHANE 0,07 ND 101 70-130 4-METHYL-2-PENTANONE 1.01 ND 95 70-130 CIS-1,3-DICHLOROPROPENE 0.10 j ND 99 70-130 TOLUENE 0.26 1 ND 90 70-130 87 90 3 13 70-130 TRANS-1,3-DICKOROPROPENE 0.12 ND 96 70-130 1,1,2-TRICHLOROETHANE 0.20 ND 92 70-130 TETRACHLOROETHENE(PCE) 0.17 ND 102 70-130 •HEXANONE 1.42 ND 95 70-130 DIBROMOCHLOROMETHANE 0.07 ND 93 70-130 1,3-DICHLOROPROPANE 0.13 ND 98 70-130 1,2-DI13ROMOETHANE(EDB) 0.15 ND 90 70-130 CHLOROBENZENE 0.10 ND 96 70-130 97 96 1 13 70-130 1,1,1,2-TETRACHLOROETHANE 0.10 ND 95 70-130 EMYL9ENZENE 0.07 ND 98 70-130 TOTAL XYLENES(M&P, 0) 0.29 ND 95 70-130 STYUNE 0.04 ND 98 70-130 BROMOFORM 0.29 ND 91 70-130 ISOPROPYLBENZENE 0.08 ND 98 70-130 BROMOBENZENE 0.07 ND 92 70-130 1,2,3-TRICHLOROPROPANE 0,11 ND 90 70-130 rR,ANS-1,4-DICHLORO-2-BUTENE 0,52 ND 90 70-130 N-PROPYLBENZENE 0.08 ND 99 70-130 2-CHLOROTOLUENE 0.10 ND 98 70-130 4-CHLOROTOLUENE 0.09 ND 98 70-130 1,3,5-TRQNETHYLBENZENE 0.07 ND 98 70-130 TERT-BUTYLBENZENE 0.08 ND 96 70-130 1,2,4-TRIMETHYLBENZENE 0.07 ND 96 70-130 SEC-BUTYLBENZENE 0.12 ND 100 70-130 1,3-DICHLOROBENZENE 0.12 ND 93 70-130 1,1,2,2-TETRACHLOROETHANE 0.08 ND 96 70-130 P-ISOPROPYLTOLUENE 0.09 ND 102 70-130 1,4-DICHLOROBENZENE 0.08 ND 98 70-130 1,2-DICHLOROBENZENE 0.09 ND 97 70-130 N-BUTYLBENZENE 0.10 ND 99 70-130 1,2-DIBR0M0.3-0WR0PR0PANE(DPCP) 0.49 ND 94 70-130 1,2,4-TRICHLOROBENZENE 0.47 ND 95 70-130 f4AYRTHALENE 0.18 ND 93 70-130 11,2,3-TRICHLOROBENZENE 0.18 ND 94 70-130 COMMENTS: QA/QC Summary Method: 625 100/200 PPB QCJ IFILE NAME: WLC0503-MS1 Page 1 of 2 CLIENT:ECS (PROJECT:PATTERSOl1� SAMPLE ID: 3584-02-04 INSTRUMENT:MS-1 Extraction Method 3510 Date Extracted OU30115 Weight Extracted 1L Final Extract Volume 1M1. - Date Analyzed OSM/15 % Surrogate Recovery 60 36 73 81 1 67 69 Acceptance Range (5 - 77) (7 - 64) (29 -149) (12 -123) (10 -133) (20 -133) LCS Range MS MSD RPD QC LIMITS Compound MDL Method LCS % %Rec. %Rec. UG/L Blank Recoveryg RPD /o REC �N-Nitrosodimcthylamine 0.970 ND 60 8-104 Bis(2-c1loroethy1)ether 0.430 ND 80 45-111 rt]enai 0.460 ND 43 D-76 27 26 1 42 12-110 2-Chlorophenol 0.300 ND 79 30-107 65 67 3 40 27-123 1,3-Dichlorobenzene 0.250 ND 68 48-90 1,4-Dichlorobonzene 0.200 ND 70 50-90 51 50 2 28 36-97 1,2-Dichlorobenzene 0.100 ND 68 50-93 Bis(2-chloroisopropyl)ether 0.380 ND 70 50-107 N-nitrosodi-n-propylamine 0.500 ND 68 47-111 74 67 10 38 41-116 HexachloroW=e 0.220 ND 66 36-90 2-Nitrophenot 0.670 ND 76 33-110 2,4-Dimethylphenol 1,550 ND 71 43-100 Nitrobenzene 0.500 ND 71 46-112 Isophorone 0.510 ND 67 50-104 Bis(2-chloroethoxy)methane 0.420 ND 62 49-105 2,4-Dichlorcphenol 0.540 ND 76 33-108 1,2,4-Trichlorobenzene 0.560 ND 66 47-95 66 64 3 28 39-90 4-Chloro-3-methylphenol 1.830 ND 72 44-107 85 74 14 42 23-97 Naphthalene 0,710 ND 75 50-96 Hexachlorobutadiene 0.770 ND 62 24-100 2,4,6-Trichlorophenol 0.540 ND 79 22-124 2-Methyl4,6-Dinitrophenol 3.250 ND 86 16-115 4-Nitrophenol 6.670 ND 42 1-69 22 21 8 50 10-80 Hexachlorocyclopentadiene 0.970 ND 52 16-85 N/A a = Data Not Available " - FAILED QA/QC Summary Method: 625 100/200 PPB FILE NAME: WLC0503-MSI Page 2 of 2 CLIENT:ECS (PROJECT:PATTERSOi LCS Acceptr ange C LIMITS Compound MDL Method LCS % MS MSD �2PD UG/L Blank Recovery % Rec. % Rec. 2-Chloronaphthalene 0.420 ND 76 51-100 RPD 0 /oREC Dimethyl phthalate 0.400 ND 76 47-107 Acenaphthylene 0.150 ND 75 49-100 2,6-Dinitrotoluene 0.670 ND 82 49-106 Acenaphthene 0.280 ND 80 48-102 71 55 25 31 46-118 2,4-Dinitrotolume 0.670 ND 70 50-106 69 63 10 38 24-96 Diethyl phthalate 0.820 ND 79 49-107 4-Chlorophenyl phenyl ether 0.730 ND 86 43-112 2,4-Dinitrophenol 4.190 ND 68 D-118 Pwtachlorophenol 5.220 ND 89 15-123 17 15 16 50 9-103 N Nitrosadiphenylamine 1.150 ND 82 35-121 4-Bromophenyl phenyl ether 0.670 ND 81 48-107 ~ Hexachlorobenzene 0.390 ND 76 50-102 PhMMOOM 0.280 ND 83 42-105 Antivacene 0.200 ND 72 44-104 Di-N-Butyl phthalate 0.650 ND 1 79 44-111 Benzidine 3.370 ND I D48 �>Yne 1.920 ND 79 39-107 69 63 ' 31 26-127 Beryl butyl phthalate 1.220 ND 79 39-116 Baua(0)OWhMmm 0.380 ND 80 36-114 3,3-Dichlcrobenzidinc 5.050 ND 25 6-52 Chrysene 0.700 ND 80 45-99 Bis(2-ethyl-hexyl)phthalate 1.140 ND 77 30-134 Di-N-Octyl phthalate 0.740 ND 89 37-131 Benzo(b)lluoradhene 0.770 ND 87 49-107 Benzo(k)fluoranthene 0.600 ND 79 37-112 Berm(a)pyr-e 0.430 ND 80 49-105 Indeno(1,2,3-ed)pyrene 1.210 ND 48 38-122 Dibenzo(a,h)anthmme 1.680 ND 53 43-118 Benzo(g,h,i)Mlene 1.780 ND 43 42-119 N/A = Data Not Available " = FAILED rl w 0 d rn m a en ^ °° d 4 $ v a f+1 as � 0. o A a w A a z w 0 m rn 0 a 1f1 tn in M o O ono v M a a L a p d eV o a